File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. 0.21335E+01 0.79186E-01 0.7408 0.00000000E+00 H2O 2 0. 0.66220E+02 0.10000E+01 0.9917 0.00000000E+00 Cl- 3 -1. 0.11814E+00 0.95360E-01 0.7278 0.00000000E+00 SO4-- 4 -2. 0.95485E-01 0.44992E-10 0.3093 0.00000000E+00 HCO3- 5 -1. 0.14460E+01 0.41321E-05 0.7310 0.00000000E+00 HS- 6 -1. 0.39054E+00 0.39945E-06 0.7281 0.00000000E+00 Al+++ 7 3. 0.47754E-05 0.38852E-05 0.0708 0.00000000E+00 H4SiO4 8 0. 0.12153E-01 0.10078E-02 1.0000 0.00000000E+00 Ca++ 9 2. 0.20808E-06 0.16211E-06 0.3024 0.00000000E+00 Mg++ 10 2. 0.83683E-10 0.65523E-10 0.2983 0.00000000E+00 Fe++ 11 2. 0.32592E-07 0.25437E-07 0.2993 0.00000000E+00 K+ 12 1. 0.14123E-03 0.11511E-03 0.7313 0.00000000E+00 Na+ 13 1. 0.20032E-01 0.16073E-01 0.7272 0.00000000E+00 Mn++ 14 2. 0.22519E-08 0.15630E-08 0.3000 0.00000000E+00 F- 15 -1. 0.80001E-02 0.22376E-04 0.7238 0.00000000E+00 HPO4-- 16 -2. 0.41688E-07 0.43016E-14 0.3095 0.00000000E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1181E-04 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 50.0000 SLIM = 0.400000E+02 TEMP = 100.0000 SINC = 0.1000E+01 TEMPC = 0.0000 TOTMIX = 0.200000E+02 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 400.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 3 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) SiF6-2 17 -2. -24.5019 Mn+3 70 3. 19.1453 HSiO3- 18 -1. 9.0298 MnF+ 71 1. -1.2264 Ca(HSiO3)+ 19 1. 7.6723 MnO,aq 72 0. 17.9848 Mg(HSiO3)+ 20 1. 7.5773 MnOH+ 73 1. 8.5194 NaHSiO3,aq 21 0. 7.8210 MnO2-2 74 -2. 40.4638 AlO+ 22 1. 6.8663 HMnO2- 75 -1. 29.1232 AlOH+2 23 2. 3.1691 MnO4- 76 -1. 83.3111 HAlO2,aq 24 0. 10.5671 MnO4-2 77 -2. 81.3005 AlO2- 25 -1. 16.2221 MnCl+ 78 1. -0.7894 CH4,aq 26 0. 6.0126 MnSO4,aq 79 0. -2.4604 C2H6,aq 27 0. 12.3733 NaCl,aq 80 0. 0.4796 C3H8,aq 28 0. 17.3707 NaF,aq 81 0. 0.6306 C4H10,aq 29 0. 22.3757 NaOH,aq 82 0. 12.3669 ethanol,aq 30 0. 15.3258 O2,aq 83 0. 53.5502 CO,aq 31 0. 4.6892 OH- 84 -1. 12.2382 CO2,aq 32 0. -6.3298 HO2- 85 -1. 50.8010 CO3-2 33 -2. 10.0588 H2O2,aq 86 0. 40.0166 CaCO3,aq 34 0. 5.9605 H3PO2,aq 87 0. 24.3066 Ca(HCO3)+ 35 1. -1.4070 H2PO2- 88 -1. 26.5366 CaCl+ 36 1. -0.2091 HPO3-2 89 -2. 11.9254 CaCl2,aq 37 0. 0.4151 H3PO3,aq 90 0. 3.5792 CaF+ 38 1. -1.1644 H2PO3- 91 -1. 5.6232 CaOH+ 39 1. 10.1471 H3PO4,aq 92 0. -9.8447 CaSO4,aq 40 0. -2.5018 H2PO4- 93 -1. -7.2659 HCl,aq 41 0. 0.7370 PO4-3 94 -3. 12.0884 HClO,aq 42 0. 32.4260 H4P2O7,aq 95 0. -17.8095 ClO- 43 -1. 39.6530 H3P2O7- 96 -1. -15.9156 HClO2,aq 44 0. 70.1812 H2P2O7-2 97 -2. -13.4262 HF,aq 45 0. -3.8354 HP2O7-3 98 -3. -6.7266 HF2- 46 -1. -3.3639 P2O7-4 99 -4. 2.8952 Fe+3 47 3. 8.3809 H2S,aq 100 0. -6.4900 FeCl+ 48 1. -0.1994 S2-2 101 -2. 1.2355 FeCl2,aq 49 0. 4.3001 S3-2 102 -2. -8.8031 FeCl+2 50 2. 6.5269 S3- 103 -1. -16.3389 FeF+ 51 1. -1.7084 S4-2 104 -2. -18.6615 FeF+2 52 2. 1.4309 S5-2 105 -2. -28.3439 FeO,aq 53 0. 16.4104 SO2,aq 106 0. -0.2309 FeOH+ 54 1. 7.4874 SO3-2 107 -2. 10.3052 HFeO2- 55 -1. 24.3908 HSO3- 108 -1. 2.5086 FeO+ 56 1. 11.4004 HSO4- 109 -1. -2.9839 FeOH+2 57 2. 9.1194 HSO5- 110 -1. 38.8366 FeO2- 58 -1. 24.0895 S2O3-2 111 -2. -4.5600 HFeO2,aq 59 0. 15.9850 HS2O3- 112 -1. -6.8123 H2,aq 60 0. 9.4190 H2S2O3,aq 113 0. -8.0173 KCl,aq 61 0. 1.7417 S2O4-2 114 -2. 10.5541 KHSO4,aq 62 0. -0.4514 HS2O4- 115 -1. 7.6551 KOH,aq 63 0. 12.3695 H2S2O4,aq 116 0. 6.6259 KSO4- 64 -1. -1.1908 S2O5-2 117 -2. 10.0741 MgCO3,aq 65 0. 6.5614 S2O6-2 118 -2. 11.5521 Mg(HCO3)+ 66 1. -1.4164 S2O8-2 119 -2. 42.0620 MgCl+ 67 1. -0.1664 S3O6-2 120 -2. 3.7866 MgF+ 68 1. -1.7331 S4O6-2 121 -2. -17.8657 MgOH+ 69 1. 9.4041 S5O6-2 122 -2. -14.1333 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.696 0.2719E-01 osumilite(1) 126 21.717 0.0000E+00 CO2,gas 2 -6.660 0.9484E+00 osumilite(2) 127 20.667 0.0000E+00 CH4,gas 3 4.544 0.1744E-05 osumilite-Fe 128 14.390 0.0000E+00 H2,gas 4 8.000 0.2386E-06 pargasite 129 65.092 0.0000E+00 H2S,gas 5 -6.230 0.3534E-01 periclase 130 16.138 0.0000E+00 S2,gas 6 -7.335 0.1085E-10 periclase-Fe 131 11.627 0.0000E+00 CO,gas 7 3.215 0.2690E-08 perovskite-Al 132 12.344 0.0000E+00 SO3,gas 8 17.121 0.3691E-30 perovskite-Ca 133 23.807 0.0000E+00 SO2,gas 9 0.832 0.1755E-12 perovskite-Fe 134 21.143 0.0000E+00 HF,gas 10 0.473 0.3229E-06 perovskite-Mg 135 23.119 0.0000E+00 HCl,gas 11 5.189 0.2662E-07 phase_A 136 80.189 0.0000E+00 acmite 12 7.710 0.0000E+00 phlogopite-Na 137 29.647 0.0000E+00 akermanite 13 36.442 0.0000E+00 piemontite(ordered) 138 33.776 0.0000E+00 akimotoite 14 16.591 0.0000E+00 prehnite 139 19.372 0.0000E+00 akimotoite-Fe 15 13.067 0.0000E+00 prehnite-Fe 140 22.498 0.0000E+00 albite-high 16 0.693 0.0000E+00 pumpellyite-Fe 141 46.269 0.0000E+00 albite 17 -0.384 0.0000E+00 pumpellyite-Mg 142 48.995 0.0000E+00 almandine 18 24.442 0.0000E+00 px-Mg-tschermaks 143 19.616 0.0000E+00 pyrope 19 37.248 0.0000E+00 px-Ca-tschermaks 144 18.610 0.0000E+00 spessartine 20 24.457 0.0000E+00 pyrite 145 -21.247 0.0000E+00 analcite 21 3.322 0.0000E+00 pyrrhotite 146 -4.260 0.0000E+00 andalusite 22 5.002 0.0000E+00 pyrrhotiteFe0.875 147 -6.017 0.0000E+00 andradite 23 39.009 0.0000E+00 pyroxmangite 148 7.399 0.0000E+00 grossular 24 32.731 0.0000E+00 pyrophyllite 149 -6.176 0.0000E+00 anhydrite 25 -5.317 0.0000E+00 quartz 150 -2.989 0.1092E-01 ankerite 26 -2.135 0.0000E+00 rankinite 151 40.713 0.0000E+00 annite 27 20.123 0.0000E+00 ringwoodite-Fe 152 15.456 0.0000E+00 phlogopite 28 27.065 0.0000E+00 ringwoodite-Mg 153 27.575 0.0000E+00 biotite-Mn 29 32.960 0.0000E+00 rhodochrosite 154 -0.976 0.0000E+00 anorthite 30 12.710 0.0000E+00 rhodonite 155 7.446 0.0000E+00 anthophyllite 31 51.852 0.0000E+00 sanidine 156 -1.275 0.0000E+00 anthophyllite-Fe 32 29.306 0.0000E+00 sapphirine(351) 157 78.899 0.0000E+00 apatite-OH 33 -18.153 0.0000E+00 siderite 158 -2.608 0.0000E+00 apatite-F 34 -34.301 0.0000E+00 sillimanite 159 5.262 0.0000E+00 apatite-OH-zs 35 -12.736 0.0000E+00 sodalite 160 49.976 0.0000E+00 apatite-F-zs 36 -27.774 0.0000E+00 spinel 161 20.870 0.0000E+00 apatite-Cl-zs 37 -16.674 0.0000E+00 spurrite 162 59.482 0.0000E+00 aragonite 38 0.967 0.0000E+00 staurolite-Fe 163 73.598 0.0000E+00 brucite 39 12.569 0.0000E+00 staurolite-Mg 164 89.802 0.0000E+00 calcite 40 0.812 0.0000E+00 staurolite-Mn 165 83.909 0.0000E+00 carnegieite-low 41 9.023 0.0000E+00 stilbite 166 -7.522 0.0000E+00 carnegieite-high 42 10.093 0.0000E+00 stilpnomelane-Fe 167 13.017 0.0000E+00 carpholite-Mg 43 8.582 0.0000E+00 stilpnomelane-Mg 168 27.441 0.0000E+00 carpholite-Fe 44 6.713 0.0000E+00 stishovite 169 2.720 0.0000E+00 celadonite 45 5.342 0.0000E+00 sudoite-Fe 170 18.296 0.0000E+00 celadonite-Fe 46 3.877 0.0000E+00 sudoite 171 21.077 0.0000E+00 chrysotile 47 23.892 0.0000E+00 sulfur 172 -9.152 0.3819E+00 chondrodite 48 56.475 0.0000E+00 sylvite 173 1.338 0.0000E+00 clinochlore 49 39.070 0.0000E+00 talc 174 16.491 0.0000E+00 daphnite 50 28.965 0.0000E+00 talc-Fe 175 13.448 0.0000E+00 chlorite-Mn 51 46.869 0.0000E+00 talc-tschermaks 176 19.091 0.0000E+00 chlorite-Al-free 52 47.173 0.0000E+00 tephroite 177 18.086 0.0000E+00 chloritoid-Mg 53 13.198 0.0000E+00 tilleyite 178 41.377 0.0000E+00 chloritoid-Fe 54 9.174 0.0000E+00 titanite-CaSi 179 15.479 0.0000E+00 chloritoid-Mn 55 11.401 0.0000E+00 topaz-H 180 4.618 0.0000E+00 clinohumite 56 97.128 0.0000E+00 tridymite 181 -2.626 0.0000E+00 coesite 57 -2.376 0.0000E+00 tremolite 182 47.869 0.0000E+00 cordierite-H 58 23.715 0.0000E+00 ferroactinolite 183 38.452 0.0000E+00 cordierite 59 24.049 0.0000E+00 troilite-low 184 -4.411 0.0000E+00 cordierite-Fe 60 20.450 0.0000E+00 tschermakite 185 48.210 0.0000E+00 cordierite-Mn 61 25.066 0.0000E+00 vesuvianite 186 223.471 0.0000E+00 corundum 62 8.383 0.0000E+00 wadeite-Si 187 20.216 0.0000E+00 corundum-MgSi 63 18.891 0.0000E+00 wadsleyite-Fe 188 15.680 0.0000E+00 cristobalite 64 -2.560 0.0000E+00 wadsleyite-Mg 189 25.850 0.0000E+00 cummingtonite 65 52.099 0.0000E+00 wairakite 190 3.950 0.0000E+00 cymrite-K 66 1.685 0.0000E+00 walstromite 191 11.509 0.0000E+00 deerite 67 95.671 0.0000E+00 wollastonite 192 10.461 0.0000E+00 diaspore 68 2.874 0.0000E+00 pseudo-wollastonite 193 11.000 0.0000E+00 diamond 69 -3.102 0.0000E+00 zoisite 194 22.849 0.0000E+00 diopside 70 16.181 0.0000E+00 akaganeite 195 7.755 0.0000E+00 hedenbergite 71 14.208 0.0000E+00 beidellite-Ca 196 -1.646 0.0000E+00 dolomite,ordered 72 0.546 0.0000E+00 beidellite-H 197 -2.326 0.0000E+00 eastonite 73 28.489 0.0000E+00 beidellite-K 198 -1.520 0.0000E+00 enstatite 74 17.265 0.0000E+00 beidellite-Mg 199 -1.790 0.0000E+00 clinoenstatite-HiP 75 18.354 0.0000E+00 beidellite-Na 200 -1.342 0.0000E+00 clinoenstatite 76 17.166 0.0000E+00 calcium 201 84.026 0.0000E+00 protoenstatite 77 17.824 0.0000E+00 chalcedony 202 -2.802 0.0000E+00 epidote 78 24.670 0.0000E+00 dawsonite 203 1.682 0.0000E+00 clinozoisite 79 22.806 0.0000E+00 montmorillonite-Ca 204 -2.291 0.0000E+00 epidote-Fe 80 29.841 0.0000E+00 montmorillonite-K 205 -2.237 0.0000E+00 fayalite 81 14.046 0.0000E+00 montmorillonite-Mg 206 -2.480 0.0000E+00 ferrosilite 82 11.149 0.0000E+00 montmorillonite-Na 207 -2.038 0.0000E+00 forsterite 83 21.016 0.0000E+00 nontronite-Ca 208 3.215 0.0000E+00 gedrite 84 50.522 0.0000E+00 nontronite-H 209 2.533 0.0000E+00 gehlenite 85 36.628 0.0000E+00 nontronite-K 210 3.341 0.0000E+00 gibbsite 86 4.079 0.0000E+00 nontronite-Mg 211 3.075 0.0000E+00 glaucophane 87 22.975 0.0000E+00 nontronite-Na 212 3.520 0.0000E+00 glaucophane-Fe 88 17.276 0.0000E+00 sepiolite 213 24.118 0.0000E+00 graphite 89 -3.546 0.0000E+00 topaz 214 -16.546 0.0000E+00 greenalite 90 16.140 0.0000E+00 alite 215 57.999 0.0000E+00 grunerite 91 31.215 0.0000E+00 belite 216 30.433 0.0000E+00 halite 92 1.575 0.0000E+00 ettringite 217 43.232 0.0000E+00 hematite 93 12.566 0.0000E+00 gypsum 218 -4.955 0.0000E+00 heulandite 94 -5.827 0.0000E+00 hemicarboaluminate 219 70.954 0.0000E+00 hercynite 95 17.279 0.0000E+00 hydrogarnet 220 60.662 0.0000E+00 hollandite 96 25.673 0.0000E+00 hydrogarnet-Si 221 50.586 0.0000E+00 iron 97 19.086 0.0000E+00 jennite 222 24.367 0.0000E+00 jadeite 98 4.215 0.0000E+00 monosulfoaluminate 223 53.400 0.0000E+00 julgoldite 99 70.427 0.0000E+00 monocarboaluminate 224 61.898 0.0000E+00 kalsilite 100 7.584 0.0000E+00 portlandite 225 18.272 0.0000E+00 kaolinite 101 -1.333 0.0000E+00 stratlingite 226 36.502 0.0000E+00 kyanite 102 4.876 0.0000E+00 tricarboaluminate 227 70.370 0.0000E+00 larnite-bredigite 103 30.686 0.0000E+00 tobermorite 228 9.823 0.0000E+00 laumontite 104 2.883 0.0000E+00 C4AH13 229 81.816 0.0000E+00 lawsonite 105 9.616 0.0000E+00 C2AH8 230 45.203 0.0000E+00 leucite 106 4.119 0.0000E+00 C3A 231 86.953 0.0000E+00 lime 107 25.998 0.0000E+00 C4AF 232 117.416 0.0000E+00 lizardite 108 23.244 0.0000E+00 CAH10 233 28.335 0.0000E+00 magnesite 109 0.691 0.0000E+00 alabandite 234 -0.978 0.0000E+00 magnetite 110 20.087 0.0000E+00 alunite 235 -10.435 0.0000E+00 minnesotaite 111 10.388 0.0000E+00 artinite 236 15.121 0.0000E+00 minnesotaite-Mg 112 20.602 0.0000E+00 boehmite 237 4.406 0.0000E+00 magnesioferrite 113 26.212 0.0000E+00 dolomite,disordered 238 1.247 0.0000E+00 majorite 114 53.251 0.0000E+00 ferrous-oxide 239 9.812 0.0000E+00 manganosite 115 14.058 0.0000E+00 fluorite 240 -9.931 0.0000E+00 margarite 116 17.324 0.0000E+00 huntite 241 3.770 0.0000E+00 meionite 117 44.874 0.0000E+00 hydromagnesite 242 19.995 0.0000E+00 merwinite 118 55.930 0.0000E+00 nesquehonite 243 4.723 0.0000E+00 microcline 119 -2.486 0.0000E+00 potassium-oxide 244 69.038 0.0000E+00 monticellite 120 24.339 0.0000E+00 silica-amorphous 245 -2.091 0.0000E+00 mullite-Al 121 363.148 0.0000E+00 sodium-oxide 246 55.169 0.0000E+00 mullite-Si 122 7.264 0.0000E+00 an20ab80 247 2.018 0.0000E+00 muscovite 123 2.582 0.0000E+00 an25ab75 248 2.646 0.0000E+00 paragonite 124 4.239 0.0000E+00 an30ab70 249 3.279 0.0000E+00 nepheline 125 8.339 0.0000E+00 tr.625ac.25prg.125 250 45.165 0.0000E+00 Initial composition of reactant (mole%): H2O 88.87 HCl 0.5900 CO2 7.070 CO 0.1600 H2 1.540 S2 0.8000E-01 SO2 1.150 HF 0.4000E-01 H2S 1.120 0.000 Sum of wt% of reactants: 100.6200 Reactant consumed: 19.9999900 moles log = 1.3010 Original solution: 1000.0103000 g Original solution / Rock added: 50.00 (Water/Rock Ratio), log = 1.6990 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HF,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 20 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 19.9999900 Water: Moles liquid = 0.6804E+02 kg liquid = 0.1226E+01 Moles total = 0.6622E+02 kg total = 0.1193E+01 Activity = 0.9917 Stoichiometric ionic strength = .2928547E+00 Osmotic coef. = 0.9147 True ionic strength = .9539850E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1181E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.79186E-01 -1.1013 0.58658E-01 -1.2317 0.74076E+00 -0.1303 2 H2O 0.99175E+00 -0.0036 0.99175E+00 -0.0036 3 Cl- 0.95360E-01 -1.0206 0.69406E-01 -1.1586 0.72784E+00 -0.1380 4 SO4-- 0.44992E-10 -10.3469 0.13918E-10 -10.8564 0.30934E+00 -0.5096 5 HCO3- 0.41321E-05 -5.3838 0.30204E-05 -5.5199 0.73096E+00 -0.1361 6 HS- 0.39945E-06 -6.3985 0.29086E-06 -6.5363 0.72814E+00 -0.1378 7 Al+++ 0.38852E-05 -5.4106 0.27523E-06 -6.5603 0.70842E-01 -1.1497 8 H4SiO4 0.10078E-02 -2.9966 0.10078E-02 -2.9966 0.10000E+01 0.0000 9 Ca++ 0.16211E-06 -6.7902 0.49020E-07 -7.3096 0.30238E+00 -0.5195 10 Mg++ 0.65523E-10 -10.1836 0.19547E-10 -10.7089 0.29832E+00 -0.5253 11 Fe++ 0.25437E-07 -7.5945 0.76127E-08 -8.1185 0.29928E+00 -0.5239 12 K+ 0.11511E-03 -3.9389 0.84179E-04 -4.0748 0.73131E+00 -0.1359 13 Na+ 0.16073E-01 -1.7939 0.11688E-01 -1.9322 0.72721E+00 -0.1383 14 Mn++ 0.15630E-08 -8.8060 0.46893E-09 -9.3289 0.30001E+00 -0.5229 15 F- 0.22376E-04 -4.6502 0.16196E-04 -4.7906 0.72380E+00 -0.1404 16 HPO4-- 0.43016E-14 -14.3664 0.13312E-14 -14.8758 0.30947E+00 -0.5094 17 SiF6-2 0.22999E-11 -11.6383 0.70702E-12 -12.1506 0.30741E+00 -0.5123 18 HSiO3- 0.22224E-10 -10.6532 0.16176E-10 -10.7911 0.72784E+00 -0.1380 19 Ca(HSiO3)+ 0.24677E-16 -16.6077 0.18058E-16 -16.7433 0.73178E+00 -0.1356 20 Mg(HSiO3)+ 0.12246E-19 -19.9120 0.89614E-20 -20.0476 0.73178E+00 -0.1356 21 NaHSiO3,aq 0.30579E-11 -11.5146 0.30579E-11 -11.5146 0.10000E+01 0.0000 22 AlO+ 0.14748E-10 -10.8313 0.10792E-10 -10.9669 0.73178E+00 -0.1356 23 AlOH+2 0.10477E-07 -7.9798 0.31523E-08 -8.5014 0.30087E+00 -0.5216 24 HAlO2,aq 0.36339E-13 -13.4396 0.36339E-13 -13.4396 0.10000E+01 0.0000 25 AlO2- 0.18935E-17 -17.7227 0.13713E-17 -17.8629 0.72424E+00 -0.1401 26 CH4,aq 0.64668E-07 -7.1893 0.60808E-07 -7.2160 0.94032E+00 -0.0267 27 C2H6,aq 0.72812E-16 -16.1378 0.68466E-16 -16.1645 0.94032E+00 -0.0267 31 CO,aq 0.89271E-10 -10.0493 0.89271E-10 -10.0493 0.10000E+01 0.0000 32 CO2,aq 0.40595E+00 -0.3915 0.38172E+00 -0.4183 0.94032E+00 -0.0267 33 CO3-2 0.14630E-13 -13.8347 0.44976E-14 -14.3470 0.30741E+00 -0.5123 34 CaCO3,aq 0.27645E-17 -17.5584 0.27645E-17 -17.5584 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.51646E-11 -11.2870 0.37794E-11 -11.4226 0.73178E+00 -0.1356 36 CaCl+ 0.75240E-08 -8.1235 0.55060E-08 -8.2592 0.73178E+00 -0.1356 37 CaCl2,aq 0.90790E-10 -10.0420 0.90790E-10 -10.0420 0.10000E+01 0.0000 38 CaF+ 0.15840E-10 -10.8003 0.11591E-10 -10.9359 0.73178E+00 -0.1356 39 CaOH+ 0.80717E-16 -16.0930 0.59067E-16 -16.2287 0.73178E+00 -0.1356 40 CaSO4,aq 0.21665E-15 -15.6643 0.21665E-15 -15.6643 0.10000E+01 0.0000 41 HCl,aq 0.74604E-03 -3.1272 0.74604E-03 -3.1272 0.10000E+01 0.0000 45 HF,aq 0.65036E-02 -2.1868 0.65036E-02 -2.1868 0.10000E+01 0.0000 46 HF2- 0.48860E-07 -7.3110 0.35562E-07 -7.4490 0.72784E+00 -0.1380 47 Fe+3 0.52785E-17 -17.2775 0.37739E-18 -18.4232 0.71496E-01 -1.1457 48 FeCl+ 0.11428E-08 -8.9420 0.83632E-09 -9.0776 0.73178E+00 -0.1356 49 FeCl2,aq 0.18377E-14 -14.7357 0.18377E-14 -14.7357 0.10000E+01 0.0000 50 FeCl+2 0.62202E-17 -17.2062 0.18715E-17 -17.7278 0.30087E+00 -0.5216 51 FeF+ 0.86098E-11 -11.0650 0.63005E-11 -11.2006 0.73178E+00 -0.1356 52 FeF+2 0.18106E-15 -15.7422 0.54475E-16 -16.2638 0.30087E+00 -0.5216 54 FeOH+ 0.57252E-14 -14.2422 0.41896E-14 -14.3778 0.73178E+00 -0.1356 56 FeO+ 0.14212E-18 -18.8473 0.10400E-18 -18.9830 0.73178E+00 -0.1356 57 FeOH+2 0.38721E-17 -17.4121 0.11650E-17 -17.9337 0.30087E+00 -0.5216 60 H2,aq 0.98187E-08 -8.0079 0.92327E-08 -8.0347 0.94032E+00 -0.0267 61 KCl,aq 0.10589E-06 -6.9751 0.10589E-06 -6.9751 0.10000E+01 0.0000 62 KHSO4,aq 0.19430E-15 -15.7115 0.19430E-15 -15.7115 0.10000E+01 0.0000 63 KOH,aq 0.60780E-15 -15.2162 0.60780E-15 -15.2162 0.10000E+01 0.0000 64 KSO4- 0.24978E-13 -13.6024 0.18180E-13 -13.7404 0.72784E+00 -0.1380 66 Mg(HCO3)+ 0.21043E-14 -14.6769 0.15399E-14 -14.8125 0.73178E+00 -0.1356 67 MgCl+ 0.27192E-11 -11.5656 0.19899E-11 -11.7012 0.73178E+00 -0.1356 68 MgF+ 0.23397E-13 -13.6308 0.17122E-13 -13.7665 0.73178E+00 -0.1356 69 MgOH+ 0.17810E-18 -18.7493 0.13033E-18 -18.8849 0.73178E+00 -0.1356 71 MnF+ 0.17481E-12 -12.7574 0.12792E-12 -12.8931 0.73178E+00 -0.1356 73 MnOH+ 0.32761E-16 -16.4846 0.23974E-16 -16.6203 0.73178E+00 -0.1356 78 MnCl+ 0.27388E-09 -9.5624 0.20042E-09 -9.6981 0.73178E+00 -0.1356 79 MnSO4,aq 0.18841E-17 -17.7249 0.18841E-17 -17.7249 0.10000E+01 0.0000 80 NaCl,aq 0.26885E-03 -3.5705 0.26885E-03 -3.5705 0.10000E+01 0.0000 81 NaF,aq 0.44319E-07 -7.3534 0.44319E-07 -7.3534 0.10000E+01 0.0000 82 NaOH,aq 0.84906E-13 -13.0711 0.84906E-13 -13.0711 0.10000E+01 0.0000 84 OH- 0.13488E-10 -10.8701 0.97685E-11 -11.0102 0.72424E+00 -0.1401 90 H3PO3,aq 0.29487E-19 -19.5304 0.29487E-19 -19.5304 0.10000E+01 0.0000 92 H3PO4,aq 0.32035E-07 -7.4944 0.32035E-07 -7.4944 0.10000E+01 0.0000 93 H2PO4- 0.19736E-08 -8.7047 0.14405E-08 -8.8415 0.72985E+00 -0.1368 95 H4P2O7,aq 0.13643E-16 -16.8651 0.13643E-16 -16.8651 0.10000E+01 0.0000 96 H3P2O7- 0.40797E-17 -17.3894 0.29694E-17 -17.5273 0.72784E+00 -0.1380 97 H2P2O7-2 0.53365E-18 -18.2727 0.16405E-18 -18.7850 0.30741E+00 -0.5123 100 H2S,aq 0.56076E-01 -1.2512 0.52729E-01 -1.2779 0.94032E+00 -0.0267 101 S2-2 0.66044E-15 -15.1802 0.20303E-15 -15.6924 0.30741E+00 -0.5123 102 S3-2 0.50817E-14 -14.2940 0.15622E-14 -14.8063 0.30741E+00 -0.5123 103 S3- 0.87831E-09 -9.0564 0.63927E-09 -9.1943 0.72784E+00 -0.1380 104 S4-2 0.25829E-13 -13.5879 0.79402E-14 -14.1002 0.30741E+00 -0.5123 105 S5-2 0.87540E-13 -13.0578 0.26911E-13 -13.5701 0.30741E+00 -0.5123 106 SO2,aq 0.20076E-11 -11.6973 0.20076E-11 -11.6973 0.10000E+01 0.0000 107 SO3-2 0.52507E-19 -19.2798 0.16837E-19 -19.7737 0.32067E+00 -0.4939 108 HSO3- 0.84963E-13 -13.0708 0.61839E-13 -13.2087 0.72784E+00 -0.1380 109 HSO4- 0.10718E-08 -8.9699 0.78677E-09 -9.1042 0.73407E+00 -0.1343 111 S2O3-2 0.28276E-13 -13.5486 0.86924E-14 -14.0609 0.30741E+00 -0.5123 112 HS2O3- 0.12526E-12 -12.9022 0.91168E-13 -13.0402 0.72784E+00 -0.1380 113 H2S2O3,aq 0.85731E-13 -13.0669 0.85731E-13 -13.0669 0.10000E+01 0.0000 Charge balance for all species = -.4493E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7918650E-01 0.5484638E+00 0.5399252E+03 0.0000 2 H2O 0.1000000E+01 0.5510230E+02 0.9695320E+06 0.0000 3 Cl- 0.9535968E-01 0.9637468E-01 0.3337082E+04 0.0731 4 SO4-- 0.4499206E-10 -.6547690E-07 -.6143117E-02 -8.3931 5 HCO3- 0.4132081E-05 0.4059557E+00 0.2419256E+05 -4.2883 6 HS- 0.3994484E-06 0.5607657E-01 0.1811310E+04 -5.3047 7 Al+++ 0.3885154E-05 0.3895646E-05 0.1026589E+00 -2.8653 8 H4SiO4 0.1007779E-02 0.1007779E-02 0.9460392E+02 -2.9966 9 Ca++ 0.1621149E-06 0.1697508E-06 0.6644598E-02 -4.8463 10 Mg++ 0.6552257E-10 0.6826731E-10 0.1621005E-05 -8.2456 11 Fe++ 0.2543672E-07 0.2658819E-07 0.1450239E-02 -5.6551 12 K+ 0.1151065E-03 0.1152124E-03 0.4399964E+01 -2.8431 13 Na+ 0.1607297E-01 0.1634187E-01 0.3669338E+03 -0.7006 14 Mn++ 0.1563040E-08 0.1837091E-08 0.9857221E-04 -6.8656 15 F- 0.2237629E-04 0.6526071E-02 0.1210906E+03 -3.5589 16 HPO4-- 0.4301569E-14 0.3400847E-07 0.3187970E-02 -12.4124 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.2133472E+01 0.6723167E+00 0.4774343E+00 0.9837214E+00 2 H2O 0.6622040E+02 0.6754538E+02 -.4037827E+00 -.9211927E+00 3 Cl- 0.1181378E+00 0.1181378E+00 0.0000000E+00 0.2661530E-07 4 SO4-- 0.9548497E-01 -.8026274E-07 0.9548685E-01 -.1804551E-05 5 HCO3- 0.1446012E+01 0.4976277E+00 0.0000000E+00 0.9483846E+00 6 HS- 0.3905403E+00 0.6873966E-01 0.2864606E+00 0.3534008E-01 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1235353E-02 0.1091767E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.8000096E-02 0.7999773E-02 0.0000000E+00 0.3228547E-06 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4489E-16 Mass of aqueous solution: 0.125509E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 19.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.2719E-01 -1.566 0.4897 -0.310 1.127 10.80 CO2,gas 0.9484 -0.023 41.74 1.621 96.10 510.8 CH4,gas 0.1744E-05 -5.758 0.2798E-04 -4.553 0.6442E-04 0.1126E-02 H2,gas 0.2386E-06 -6.622 0.4820E-06 -6.317 0.1110E-05 0.1520E-03 H2S,gas 0.3534E-01 -1.452 1.204 0.081 2.773 17.99 S2,gas 0.1085E-10 -10.964 0.6958E-09 -9.157 0.1602E-08 0.6734E-08 CO,gas 0.2690E-08 -8.570 0.7534E-07 -7.123 0.1735E-06 0.1669E-05 SO3,gas 0.3691E-30 -30.433 0.2955E-28 -28.529 0.6805E-28 0.2290E-27 SO2,gas 0.1755E-12 -12.756 0.1124E-10 -10.949 0.2589E-10 0.1089E-09 HF,gas 0.3229E-06 -6.491 0.6457E-05 -5.190 0.1487E-04 0.2003E-03 HCl,gas 0.2662E-07 -7.575 0.9704E-06 -6.013 0.2234E-05 0.1651E-04 quartz 0.1092E-01 -1.962 0.6559 -0.183 5.084 0.2477 sulfur 0.3819 -0.418 12.25 1.088 94.92 5.924 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2689E-01 0.1345E+01 0.7419 -0.001 CO2,gas 0.9381E+00 0.4691E+02 0.8707 1.611 CH4,gas 0.1725E-05 0.8627E-04 1.0375 -4.048 H2,gas 0.2361E-06 0.1180E-04 1.0270 -4.916 H2S,gas 0.3496E-01 0.1748E+01 0.8293 0.161 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.2661E-08 0.1330E-06 1.0000 -6.876 SO3,gas 0.3651E-30 0.1826E-28 1.0000 -28.739 SO2,gas 0.1736E-12 0.8682E-11 1.0000 -11.061 HF,gas 0.3194E-06 0.1597E-04 1.0000 -4.797 HCl,gas 0.2633E-07 0.1316E-05 1.0000 -5.881 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 3.311847 % Solid products produced: Mass = 12.901167 g Volume = 6.171867 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 19.9999900 moles log = 1.3010 Original solution: 1000.0103000 g Original solution / Rock added: 50.00 (Water/Rock Ratio), log = 1.6990 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 0.15165E-10 2 CO2,gas -6.66 -6.66 0.00 0.000 0.00000E+00 3 CH4,gas 4.54 4.54 0.00 0.000 -0.50046E-10 4 H2,gas 8.00 8.00 0.00 0.000 0.00000E+00 5 H2S,gas -6.23 -6.23 0.00 0.000 0.00000E+00 6 S2,gas -7.34 -7.34 0.00 0.000 0.00000E+00 7 CO,gas 3.21 3.21 0.00 0.000 0.75827E-12 8 SO3,gas 17.12 17.12 0.00 0.000 -0.60662E-11 9 SO2,gas 0.83 0.83 0.00 0.000 -0.37914E-12 10 HF,gas 0.47 0.47 0.00 0.000 0.37914E-12 11 HCl,gas 5.19 5.19 0.00 0.000 0.00000E+00 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 172 sulfur -9.15 -9.15 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.97 -0.87 -0.248 0.14850E+04 89 graphite -3.55 -3.97 -0.43 -0.122 0.72728E+03 92 halite 1.57 -3.09 -4.67 -2.333 0.79661E+04 145 pyrite -21.25 -22.58 -1.33 -0.313 0.22684E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 214 topaz -16.55 -20.77 -4.23 -0.469 0.72149E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 19.9999900 MOLES New total amount of reactant added: 20.9999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 23 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 20.9999900 Water: Moles liquid = 0.6895E+02 kg liquid = 0.1242E+01 Moles total = 0.6704E+02 kg total = 0.1208E+01 Activity = 0.9917 Stoichiometric ionic strength = .2950258E+00 Osmotic coef. = 0.9147 True ionic strength = .9881743E-01 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1240E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.82826E-01 -1.0818 0.61167E-01 -1.2135 0.73850E+00 -0.1316 2 H2O 0.99173E+00 -0.0036 0.99173E+00 -0.0036 3 Cl- 0.98779E-01 -1.0053 0.71651E-01 -1.1448 0.72536E+00 -0.1394 4 SO4-- 0.39925E-10 -10.3988 0.12181E-10 -10.9143 0.30511E+00 -0.5155 5 HCO3- 0.39732E-05 -5.4009 0.28947E-05 -5.5384 0.72854E+00 -0.1375 6 HS- 0.39075E-06 -6.4081 0.28356E-06 -6.5474 0.72568E+00 -0.1393 7 Al+++ 0.38346E-05 -5.4163 0.26315E-06 -6.5798 0.68625E-01 -1.1635 8 H4SiO4 0.10077E-02 -2.9966 0.10077E-02 -2.9966 0.10000E+01 0.0000 9 Ca++ 0.15983E-06 -6.7964 0.47643E-07 -7.3220 0.29809E+00 -0.5256 10 Mg++ 0.64607E-10 -10.1897 0.18995E-10 -10.7214 0.29402E+00 -0.5316 11 Fe++ 0.25079E-07 -7.6007 0.73978E-08 -8.1309 0.29498E+00 -0.5302 12 K+ 0.11359E-03 -3.9447 0.82793E-04 -4.0820 0.72889E+00 -0.1373 13 Na+ 0.15854E-01 -1.7999 0.11489E-01 -1.9397 0.72471E+00 -0.1398 14 Mn++ 0.15377E-08 -8.8131 0.45470E-09 -9.3423 0.29571E+00 -0.5291 15 F- 0.22315E-04 -4.6514 0.16095E-04 -4.7933 0.72128E+00 -0.1419 16 HPO4-- 0.39666E-14 -14.4016 0.12107E-14 -14.9169 0.30524E+00 -0.5154 17 SiF6-2 0.26564E-11 -11.5757 0.80534E-12 -12.0940 0.30317E+00 -0.5183 18 HSiO3- 0.21385E-10 -10.6699 0.15512E-10 -10.8093 0.72536E+00 -0.1394 19 Ca(HSiO3)+ 0.23076E-16 -16.6368 0.16831E-16 -16.7739 0.72937E+00 -0.1371 20 Mg(HSiO3)+ 0.11450E-19 -19.9412 0.83512E-20 -20.0783 0.72937E+00 -0.1371 21 NaHSiO3,aq 0.28825E-11 -11.5402 0.28825E-11 -11.5402 0.10000E+01 0.0000 22 AlO+ 0.13010E-10 -10.8857 0.94892E-11 -11.0228 0.72937E+00 -0.1371 23 AlOH+2 0.97451E-08 -8.0112 0.28902E-08 -8.5391 0.29658E+00 -0.5279 24 HAlO2,aq 0.30639E-13 -13.5137 0.30639E-13 -13.5137 0.10000E+01 0.0000 25 AlO2- 0.15363E-17 -17.8135 0.11088E-17 -17.9551 0.72172E+00 -0.1416 26 CH4,aq 0.69051E-07 -7.1608 0.64911E-07 -7.1877 0.94005E+00 -0.0269 27 C2H6,aq 0.81638E-16 -16.0881 0.76744E-16 -16.1150 0.94005E+00 -0.0269 31 CO,aq 0.90699E-10 -10.0424 0.90699E-10 -10.0424 0.10000E+01 0.0000 32 CO2,aq 0.40582E+00 -0.3917 0.38149E+00 -0.4185 0.94005E+00 -0.0269 33 CO3-2 0.13634E-13 -13.8654 0.41335E-14 -14.3837 0.30317E+00 -0.5183 34 CaCO3,aq 0.24693E-17 -17.6074 0.24693E-17 -17.6074 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.48265E-11 -11.3164 0.35203E-11 -11.4534 0.72937E+00 -0.1371 36 CaCl+ 0.75742E-08 -8.1207 0.55244E-08 -8.2577 0.72937E+00 -0.1371 37 CaCl2,aq 0.94040E-10 -10.0267 0.94040E-10 -10.0267 0.10000E+01 0.0000 38 CaF+ 0.15350E-10 -10.8139 0.11196E-10 -10.9509 0.72937E+00 -0.1371 39 CaOH+ 0.75480E-16 -16.1222 0.55053E-16 -16.2592 0.72937E+00 -0.1371 40 CaSO4,aq 0.18429E-15 -15.7345 0.18429E-15 -15.7345 0.10000E+01 0.0000 41 HCl,aq 0.80311E-03 -3.0952 0.80311E-03 -3.0952 0.10000E+01 0.0000 45 HF,aq 0.67396E-02 -2.1714 0.67396E-02 -2.1714 0.10000E+01 0.0000 46 HF2- 0.50491E-07 -7.2968 0.36624E-07 -7.4362 0.72536E+00 -0.1394 47 Fe+3 0.54754E-17 -17.2616 0.37929E-18 -18.4210 0.69271E-01 -1.1594 48 FeCl+ 0.11503E-08 -8.9392 0.83900E-09 -9.0762 0.72937E+00 -0.1371 49 FeCl2,aq 0.19032E-14 -14.7205 0.19032E-14 -14.7205 0.10000E+01 0.0000 50 FeCl+2 0.65471E-17 -17.1839 0.19417E-17 -17.7118 0.29658E+00 -0.5279 51 FeF+ 0.83424E-11 -11.0787 0.60847E-11 -11.2158 0.72937E+00 -0.1371 52 FeF+2 0.18346E-15 -15.7365 0.54409E-16 -16.2643 0.29658E+00 -0.5279 54 FeOH+ 0.53530E-14 -14.2714 0.39043E-14 -14.4085 0.72937E+00 -0.1371 56 FeO+ 0.13179E-18 -18.8801 0.96123E-19 -19.0172 0.72937E+00 -0.1371 57 FeOH+2 0.37859E-17 -17.4218 0.11228E-17 -17.9497 0.29658E+00 -0.5279 60 H2,aq 0.99846E-08 -8.0007 0.93860E-08 -8.0275 0.94005E+00 -0.0269 61 KCl,aq 0.10752E-06 -6.9685 0.10752E-06 -6.9685 0.10000E+01 0.0000 62 KHSO4,aq 0.17442E-15 -15.7584 0.17442E-15 -15.7584 0.10000E+01 0.0000 63 KOH,aq 0.57326E-15 -15.2417 0.57326E-15 -15.2417 0.10000E+01 0.0000 64 KSO4- 0.21575E-13 -13.6660 0.15650E-13 -13.8055 0.72536E+00 -0.1394 66 Mg(HCO3)+ 0.19663E-14 -14.7063 0.14342E-14 -14.8434 0.72937E+00 -0.1371 67 MgCl+ 0.27370E-11 -11.5627 0.19963E-11 -11.6998 0.72937E+00 -0.1371 68 MgF+ 0.22670E-13 -13.6445 0.16535E-13 -13.7816 0.72937E+00 -0.1371 69 MgOH+ 0.16652E-18 -18.7785 0.12146E-18 -18.9156 0.72937E+00 -0.1371 71 MnF+ 0.16901E-12 -12.7721 0.12327E-12 -12.9091 0.72937E+00 -0.1371 73 MnOH+ 0.30565E-16 -16.5148 0.22293E-16 -16.6518 0.72937E+00 -0.1371 78 MnCl+ 0.27507E-09 -9.5606 0.20062E-09 -9.6976 0.72937E+00 -0.1371 79 MnSO4,aq 0.15990E-17 -17.7961 0.15990E-17 -17.7961 0.10000E+01 0.0000 80 NaCl,aq 0.27282E-03 -3.5641 0.27282E-03 -3.5641 0.10000E+01 0.0000 81 NaF,aq 0.43294E-07 -7.3636 0.43294E-07 -7.3636 0.10000E+01 0.0000 82 NaOH,aq 0.80036E-13 -13.0967 0.80036E-13 -13.0967 0.10000E+01 0.0000 84 OH- 0.12980E-10 -10.8867 0.93677E-11 -11.0284 0.72172E+00 -0.1416 90 H3PO3,aq 0.29648E-19 -19.5280 0.29648E-19 -19.5280 0.10000E+01 0.0000 92 H3PO4,aq 0.31682E-07 -7.4992 0.31682E-07 -7.4992 0.10000E+01 0.0000 93 H2PO4- 0.18781E-08 -8.7263 0.13662E-08 -8.8645 0.72741E+00 -0.1382 95 H4P2O7,aq 0.13344E-16 -16.8747 0.13344E-16 -16.8747 0.10000E+01 0.0000 96 H3P2O7- 0.38398E-17 -17.4157 0.27853E-17 -17.5551 0.72536E+00 -0.1394 97 H2P2O7-2 0.48675E-18 -18.3127 0.14757E-18 -18.8310 0.30317E+00 -0.5183 100 H2S,aq 0.57024E-01 -1.2439 0.53605E-01 -1.2708 0.94005E+00 -0.0269 101 S2-2 0.62609E-15 -15.2034 0.18981E-15 -15.7217 0.30317E+00 -0.5183 102 S3-2 0.48174E-14 -14.3172 0.14605E-14 -14.8355 0.30317E+00 -0.5183 103 S3- 0.85214E-09 -9.0695 0.61811E-09 -9.2089 0.72536E+00 -0.1394 104 S4-2 0.24486E-13 -13.6111 0.74234E-14 -14.1294 0.30317E+00 -0.5183 105 S5-2 0.82987E-13 -13.0810 0.25159E-13 -13.5993 0.30317E+00 -0.5183 106 SO2,aq 0.19424E-11 -11.7117 0.19424E-11 -11.7117 0.10000E+01 0.0000 107 SO3-2 0.47333E-19 -19.3248 0.14982E-19 -19.8244 0.31652E+00 -0.4996 108 HSO3- 0.79102E-13 -13.1018 0.57378E-13 -13.2413 0.72536E+00 -0.1394 109 HSO4- 0.98137E-09 -9.0082 0.71807E-09 -9.1438 0.73170E+00 -0.1357 111 S2O3-2 0.25512E-13 -13.5933 0.77345E-14 -14.1116 0.30317E+00 -0.5183 112 HS2O3- 0.11662E-12 -12.9332 0.84591E-13 -13.0727 0.72536E+00 -0.1394 113 H2S2O3,aq 0.82949E-13 -13.0812 0.82949E-13 -13.0812 0.10000E+01 0.0000 Charge balance for all species = -.4434E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8282647E-01 0.5532099E+00 0.5445159E+03 0.0000 2 H2O 0.1000000E+01 0.5510243E+02 0.9693893E+06 0.0000 3 Cl- 0.9877899E-01 0.9985504E-01 0.3457076E+04 0.0687 4 SO4-- 0.3992477E-10 -.7001435E-07 -.6567844E-02 -8.4873 5 HCO3- 0.3973221E-05 0.4058208E+00 0.2418090E+05 -4.3249 6 HS- 0.3907482E-06 0.5702431E-01 0.1841647E+04 -5.3339 7 Al+++ 0.3834578E-05 0.3844336E-05 0.1012916E+00 -2.9394 8 H4SiO4 0.1007750E-02 0.1007750E-02 0.9458702E+02 -2.9966 9 Ca++ 0.1598265E-06 0.1675150E-06 0.6556100E-02 -4.8950 10 Mg++ 0.6460652E-10 0.6736815E-10 0.1599415E-05 -8.2944 11 Fe++ 0.2507933E-07 0.2623799E-07 0.1430923E-02 -5.7039 12 K+ 0.1135874E-03 0.1136949E-03 0.4341362E+01 -2.8685 13 Na+ 0.1585376E-01 0.1612663E-01 0.3620468E+03 -0.7262 14 Mn++ 0.1537660E-08 0.1812895E-08 0.9725935E-04 -6.9153 15 F- 0.2231502E-04 0.6762102E-02 0.1254514E+03 -3.5798 16 HPO4-- 0.3966553E-14 0.3356054E-07 0.3145511E-02 -12.4900 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.2241147E+01 0.6871855E+00 0.5013106E+00 0.1052651E+01 2 H2O 0.6703910E+02 0.6844706E+02 -.4228509E+00 -.9851133E+00 3 Cl- 0.1240378E+00 0.1240378E+00 0.0000000E+00 0.3065899E-07 4 SO4-- 0.1002600E+00 -.8697033E-07 0.1002621E+00 -.2058012E-05 5 HCO3- 0.1518312E+01 0.5041019E+00 0.0000000E+00 0.1014210E+01 6 HS- 0.4100653E+00 0.7083438E-01 0.3007863E+00 0.3844457E-01 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1251805E-02 0.1090122E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.8400096E-02 0.8399738E-02 0.0000000E+00 0.3580186E-06 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1214E-16 Mass of aqueous solution: 0.127203E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 20.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.2909E-01 -1.536 0.5240 -0.281 1.128 11.56 CO2,gas 1.014 0.006 44.64 1.650 96.05 546.2 CH4,gas 0.1992E-05 -5.701 0.3196E-04 -4.495 0.6877E-04 0.1286E-02 H2,gas 0.2596E-06 -6.586 0.5244E-06 -6.280 0.1128E-05 0.1654E-03 H2S,gas 0.3844E-01 -1.415 1.310 0.117 2.819 19.57 S2,gas 0.1161E-10 -10.935 0.7446E-09 -9.128 0.1602E-08 0.7206E-08 CO,gas 0.2924E-08 -8.534 0.8191E-07 -7.087 0.1763E-06 0.1814E-05 SO3,gas 0.3759E-30 -30.425 0.3010E-28 -28.521 0.6477E-28 0.2333E-27 SO2,gas 0.1817E-12 -12.741 0.1164E-10 -10.934 0.2505E-10 0.1128E-09 HF,gas 0.3580E-06 -6.446 0.7160E-05 -5.145 0.1541E-04 0.2221E-03 HCl,gas 0.3066E-07 -7.513 0.1118E-05 -5.952 0.2406E-05 0.1902E-04 quartz 0.1090E-01 -1.963 0.6549 -0.184 4.847 0.2473 sulfur 0.4010 -0.397 12.86 1.109 95.15 6.220 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2689E-01 0.1345E+01 0.7419 -0.001 CO2,gas 0.9376E+00 0.4688E+02 0.8707 1.611 CH4,gas 0.1842E-05 0.9209E-04 1.0375 -4.020 H2,gas 0.2400E-06 0.1200E-04 1.0270 -4.909 H2S,gas 0.3554E-01 0.1777E+01 0.8293 0.168 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.2703E-08 0.1352E-06 1.0000 -6.869 SO3,gas 0.3475E-30 0.1738E-28 1.0000 -28.760 SO2,gas 0.1680E-12 0.8400E-11 1.0000 -11.076 HF,gas 0.3310E-06 0.1655E-04 1.0000 -4.781 HCl,gas 0.2834E-07 0.1417E-05 1.0000 -5.849 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 3.488659 % Solid products produced: Mass = 13.512558 g Volume = 6.467758 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 20.9999900 moles log = 1.3222 Original solution: 1000.0103000 g Original solution / Rock added: 47.62 (Water/Rock Ratio), log = 1.6778 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 0.37914E-12 2 CO2,gas -6.66 -6.66 0.00 0.000 0.00000E+00 3 CH4,gas 4.54 4.54 0.00 0.000 -0.15165E-11 4 H2,gas 8.00 8.00 0.00 0.000 -0.15165E-11 5 H2S,gas -6.23 -6.23 0.00 0.000 0.15165E-11 6 S2,gas -7.34 -7.34 0.00 0.000 0.00000E+00 7 CO,gas 3.21 3.21 0.00 0.000 -0.75827E-12 8 SO3,gas 17.12 17.12 0.00 0.000 0.60662E-11 9 SO2,gas 0.83 0.83 0.00 0.000 -0.37914E-12 10 HF,gas 0.47 0.47 0.00 0.000 0.37914E-12 11 HCl,gas 5.19 5.19 0.00 0.000 0.00000E+00 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 172 sulfur -9.15 -9.15 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.96 -0.86 -0.244 0.14610E+04 89 graphite -3.55 -3.96 -0.41 -0.118 0.70329E+03 92 halite 1.57 -3.08 -4.66 -2.330 0.79552E+04 145 pyrite -21.25 -22.62 -1.37 -0.322 0.23395E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 214 topaz -16.55 -20.89 -4.34 -0.483 0.74150E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 20.9999900 MOLES New total amount of reactant added: 21.9999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 23 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 21.9999900 Water: Moles liquid = 0.6986E+02 kg liquid = 0.1259E+01 Moles total = 0.6786E+02 kg total = 0.1222E+01 Activity = 0.9966 Stoichiometric ionic strength = .2970961E+00 Osmotic coef. = 0.9147 True ionic strength = .1021463E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1299E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.86370E-01 -1.0636 0.63601E-01 -1.1965 0.73638E+00 -0.1329 2 H2O 0.99660E+00 -0.0015 0.99660E+00 -0.0015 3 Cl- 0.10211E+00 -0.9909 0.73828E-01 -1.1318 0.72304E+00 -0.1408 4 SO4-- 0.36459E-10 -10.4382 0.10980E-10 -10.9594 0.30116E+00 -0.5212 5 HCO3- 0.38492E-05 -5.4146 0.27956E-05 -5.5535 0.72626E+00 -0.1389 6 HS- 0.38275E-06 -6.4171 0.27687E-06 -6.5577 0.72336E+00 -0.1406 7 Al+++ 0.37852E-05 -5.4219 0.25206E-06 -6.5985 0.66590E-01 -1.1766 8 H4SiO4 0.10177E-02 -2.9924 0.10177E-02 -2.9924 0.10000E+01 0.0000 9 Ca++ 0.15760E-06 -6.8024 0.46350E-07 -7.3339 0.29409E+00 -0.5315 10 Mg++ 0.63717E-10 -10.1957 0.18478E-10 -10.7334 0.28999E+00 -0.5376 11 Fe++ 0.24732E-07 -7.6067 0.71961E-08 -8.1429 0.29096E+00 -0.5362 12 K+ 0.11211E-03 -3.9504 0.81459E-04 -4.0891 0.72661E+00 -0.1387 13 Na+ 0.15641E-01 -1.8057 0.11298E-01 -1.9470 0.72237E+00 -0.1412 14 Mn++ 0.15132E-08 -8.8201 0.44139E-09 -9.3552 0.29170E+00 -0.5351 15 F- 0.22267E-04 -4.6523 0.16008E-04 -4.7957 0.71891E+00 -0.1433 16 HPO4-- 0.36758E-14 -14.4346 0.11075E-14 -14.9557 0.30129E+00 -0.5210 17 SiF6-2 0.30150E-11 -11.5207 0.90212E-12 -12.0447 0.29921E+00 -0.5240 18 HSiO3- 0.20734E-10 -10.6833 0.14992E-10 -10.8242 0.72304E+00 -0.1408 19 Ca(HSiO3)+ 0.21764E-16 -16.6623 0.15825E-16 -16.8007 0.72710E+00 -0.1384 20 Mg(HSiO3)+ 0.10798E-19 -19.9667 0.78511E-20 -20.1051 0.72710E+00 -0.1384 21 NaHSiO3,aq 0.27395E-11 -11.5623 0.27395E-11 -11.5623 0.10000E+01 0.0000 22 AlO+ 0.11619E-10 -10.9348 0.84483E-11 -11.0732 0.72710E+00 -0.1384 23 AlOH+2 0.91449E-08 -8.0388 0.26755E-08 -8.5726 0.29257E+00 -0.5338 24 HAlO2,aq 0.26363E-13 -13.5790 0.26363E-13 -13.5790 0.10000E+01 0.0000 25 AlO2- 0.12755E-17 -17.8943 0.91756E-18 -18.0374 0.71935E+00 -0.1431 26 CH4,aq 0.72613E-07 -7.1390 0.68241E-07 -7.1660 0.93979E+00 -0.0270 27 C2H6,aq 0.88898E-16 -16.0511 0.83545E-16 -16.0781 0.93979E+00 -0.0270 31 CO,aq 0.91566E-10 -10.0383 0.91566E-10 -10.0383 0.10000E+01 0.0000 32 CO2,aq 0.40564E+00 -0.3919 0.38121E+00 -0.4188 0.93979E+00 -0.0270 33 CO3-2 0.12831E-13 -13.8917 0.38393E-14 -14.4158 0.29921E+00 -0.5240 34 CaCO3,aq 0.22313E-17 -17.6514 0.22313E-17 -17.6514 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.45490E-11 -11.3421 0.33075E-11 -11.4805 0.72710E+00 -0.1384 36 CaCl+ 0.76163E-08 -8.1183 0.55378E-08 -8.2567 0.72710E+00 -0.1384 37 CaCl2,aq 0.97133E-10 -10.0126 0.97133E-10 -10.0126 0.10000E+01 0.0000 38 CaF+ 0.14898E-10 -10.8269 0.10833E-10 -10.9653 0.72710E+00 -0.1384 39 CaOH+ 0.71190E-16 -16.1476 0.51762E-16 -16.2860 0.72710E+00 -0.1384 40 CaSO4,aq 0.16161E-15 -15.7915 0.16161E-15 -15.7915 0.10000E+01 0.0000 41 HCl,aq 0.86044E-03 -3.0653 0.86044E-03 -3.0653 0.10000E+01 0.0000 45 HF,aq 0.69696E-02 -2.1568 0.69696E-02 -2.1568 0.10000E+01 0.0000 46 HF2- 0.52096E-07 -7.2832 0.37668E-07 -7.4240 0.72304E+00 -0.1408 47 Fe+3 0.56633E-17 -17.2469 0.38074E-18 -18.4194 0.67229E-01 -1.1724 48 FeCl+ 0.11565E-08 -8.9368 0.84092E-09 -9.0752 0.72710E+00 -0.1384 49 FeCl2,aq 0.19656E-14 -14.7065 0.19656E-14 -14.7065 0.10000E+01 0.0000 50 FeCl+2 0.68646E-17 -17.1634 0.20084E-17 -17.6972 0.29257E+00 -0.5338 51 FeF+ 0.80959E-11 -11.0917 0.58865E-11 -11.2301 0.72710E+00 -0.1384 52 FeF+2 0.18566E-15 -15.7313 0.54319E-16 -16.2651 0.29257E+00 -0.5338 54 FeOH+ 0.50481E-14 -14.2969 0.36705E-14 -14.4353 0.72710E+00 -0.1384 56 FeO+ 0.12335E-18 -18.9089 0.89685E-19 -19.0473 0.72710E+00 -0.1384 57 FeOH+2 0.37232E-17 -17.4291 0.10893E-17 -17.9628 0.29257E+00 -0.5338 60 H2,aq 0.10140E-07 -7.9940 0.95292E-08 -8.0209 0.93979E+00 -0.0270 61 KCl,aq 0.10900E-06 -6.9626 0.10900E-06 -6.9626 0.10000E+01 0.0000 62 KHSO4,aq 0.16084E-15 -15.7936 0.16084E-15 -15.7936 0.10000E+01 0.0000 63 KOH,aq 0.54511E-15 -15.2635 0.54511E-15 -15.2635 0.10000E+01 0.0000 64 KSO4- 0.19196E-13 -13.7168 0.13879E-13 -13.8576 0.72304E+00 -0.1408 66 Mg(HCO3)+ 0.18530E-14 -14.7321 0.13473E-14 -14.8705 0.72710E+00 -0.1384 67 MgCl+ 0.27519E-11 -11.5604 0.20009E-11 -11.6988 0.72710E+00 -0.1384 68 MgF+ 0.22001E-13 -13.6576 0.15997E-13 -13.7960 0.72710E+00 -0.1384 69 MgOH+ 0.15704E-18 -18.8040 0.11418E-18 -18.9424 0.72710E+00 -0.1384 71 MnF+ 0.16368E-12 -12.7860 0.11901E-12 -12.9244 0.72710E+00 -0.1384 73 MnOH+ 0.28764E-16 -16.5411 0.20915E-16 -16.6796 0.72710E+00 -0.1384 78 MnCl+ 0.27599E-09 -9.5591 0.20067E-09 -9.6975 0.72710E+00 -0.1384 79 MnSO4,aq 0.13991E-17 -17.8541 0.13991E-17 -17.8541 0.10000E+01 0.0000 80 NaCl,aq 0.27643E-03 -3.5584 0.27643E-03 -3.5584 0.10000E+01 0.0000 81 NaF,aq 0.42342E-07 -7.3732 0.42342E-07 -7.3732 0.10000E+01 0.0000 82 NaOH,aq 0.76064E-13 -13.1188 0.76064E-13 -13.1188 0.10000E+01 0.0000 84 OH- 0.12586E-10 -10.9001 0.90535E-11 -11.0432 0.71935E+00 -0.1431 90 H3PO3,aq 0.29622E-19 -19.5284 0.29622E-19 -19.5284 0.10000E+01 0.0000 92 H3PO4,aq 0.31332E-07 -7.5040 0.31332E-07 -7.5040 0.10000E+01 0.0000 93 H2PO4- 0.17920E-08 -8.7467 0.12994E-08 -8.8863 0.72512E+00 -0.1396 95 H4P2O7,aq 0.12987E-16 -16.8865 0.12987E-16 -16.8865 0.10000E+01 0.0000 96 H3P2O7- 0.36057E-17 -17.4430 0.26070E-17 -17.5839 0.72304E+00 -0.1408 97 H2P2O7-2 0.44396E-18 -18.3527 0.13284E-18 -18.8767 0.29921E+00 -0.5240 100 H2S,aq 0.57909E-01 -1.2373 0.54423E-01 -1.2642 0.93979E+00 -0.0270 101 S2-2 0.59571E-15 -15.2250 0.17824E-15 -15.7490 0.29921E+00 -0.5240 102 S3-2 0.45837E-14 -14.3388 0.13715E-14 -14.8628 0.29921E+00 -0.5240 103 S3- 0.82842E-09 -9.0818 0.59898E-09 -9.2226 0.72304E+00 -0.1408 104 S4-2 0.23297E-13 -13.6327 0.69709E-14 -14.1567 0.29921E+00 -0.5240 105 S5-2 0.78960E-13 -13.1026 0.23626E-13 -13.6266 0.29921E+00 -0.5240 106 SO2,aq 0.19031E-11 -11.7205 0.19031E-11 -11.7205 0.10000E+01 0.0000 107 SO3-2 0.43639E-19 -19.3601 0.13643E-19 -19.8651 0.31264E+00 -0.5050 108 HSO3- 0.75141E-13 -13.1241 0.54329E-13 -13.2650 0.72304E+00 -0.1408 109 HSO4- 0.92258E-09 -9.0350 0.67300E-09 -9.1720 0.72947E+00 -0.1370 111 S2O3-2 0.23540E-13 -13.6282 0.70434E-14 -14.1522 0.29921E+00 -0.5240 112 HS2O3- 0.11078E-12 -12.9555 0.80097E-13 -13.0964 0.72304E+00 -0.1408 113 H2S2O3,aq 0.81667E-13 -13.0880 0.81667E-13 -13.0880 0.10000E+01 0.0000 Charge balance for all species = -.4376E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8637033E-01 0.5577449E+00 0.5489010E+03 0.0000 2 H2O 0.1000000E+01 0.5510262E+02 0.9692537E+06 0.0000 3 Cl- 0.1021082E+00 0.1032452E+00 0.3573934E+04 0.0648 4 SO4-- 0.3645910E-10 -.7369244E-07 -.6911885E-02 -8.5663 5 HCO3- 0.3849238E-05 0.4056390E+00 0.2416661E+05 -4.3570 6 HS- 0.3827525E-06 0.5790977E-01 0.1869976E+04 -5.3612 7 Al+++ 0.3785214E-05 0.3794370E-05 0.9996076E-01 -3.0089 8 H4SiO4 0.1017676E-02 0.1017676E-02 0.9550501E+02 -2.9924 9 Ca++ 0.1576048E-06 0.1653377E-06 0.6469962E-02 -4.9409 10 Mg++ 0.6371682E-10 0.6649255E-10 0.1578401E-05 -8.3403 11 Fe++ 0.2473232E-07 0.2589697E-07 0.1412123E-02 -5.7498 12 K+ 0.1121082E-03 0.1122172E-03 0.4284322E+01 -2.8925 13 Na+ 0.1564055E-01 0.1591702E-01 0.3572900E+03 -0.7505 14 Mn++ 0.1513181E-08 0.1789332E-08 0.9598150E-04 -6.9621 15 F- 0.2226658E-04 0.6992013E-02 0.1296982E+03 -3.5991 16 HPO4-- 0.3675839E-14 0.3312435E-07 0.3104183E-02 -12.5626 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.2348822E+01 0.7019421E+00 0.5251868E+00 0.1121693E+01 2 H2O 0.6785780E+02 0.6934863E+02 -.4418939E+00 -.1048938E+01 3 Cl- 0.1299378E+00 0.1299378E+00 0.0000000E+00 0.3500678E-07 4 SO4-- 0.1050350E+00 -.9274459E-07 0.1050374E+00 -.2303203E-05 5 HCO3- 0.1590612E+01 0.5105114E+00 0.0000000E+00 0.1080101E+01 6 HS- 0.4295903E+00 0.7288154E-01 0.3151121E+00 0.4159667E-01 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1280782E-02 0.1087224E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.8800096E-02 0.8799701E-02 0.0000000E+00 0.3945713E-06 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.3639E-17 Mass of aqueous solution: 0.128897E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 21.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.3116E-01 -1.506 0.5612 -0.251 1.133 12.38 CO2,gas 1.080 0.033 47.54 1.677 96.00 581.7 CH4,gas 0.2232E-05 -5.651 0.3580E-04 -4.446 0.7231E-04 0.1441E-02 H2,gas 0.2809E-06 -6.551 0.5674E-06 -6.246 0.1146E-05 0.1789E-03 H2S,gas 0.4159E-01 -1.381 1.418 0.152 2.863 21.18 S2,gas 0.1238E-10 -10.907 0.7935E-09 -9.100 0.1603E-08 0.7679E-08 CO,gas 0.3146E-08 -8.502 0.8812E-07 -7.055 0.1780E-06 0.1952E-05 SO3,gas 0.3885E-30 -30.411 0.3111E-28 -28.507 0.6283E-28 0.2411E-27 SO2,gas 0.1898E-12 -12.722 0.1216E-10 -10.915 0.2455E-10 0.1177E-09 HF,gas 0.3946E-06 -6.404 0.7891E-05 -5.103 0.1594E-04 0.2448E-03 HCl,gas 0.3501E-07 -7.456 0.1276E-05 -5.894 0.2578E-05 0.2172E-04 quartz 0.1087E-01 -1.964 0.6532 -0.185 4.625 0.2467 sulfur 0.4201 -0.377 13.47 1.129 95.37 6.517 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2703E-01 0.1351E+01 0.7419 0.001 CO2,gas 0.9369E+00 0.4684E+02 0.8707 1.611 CH4,gas 0.1936E-05 0.9681E-04 1.0375 -3.998 H2,gas 0.2436E-06 0.1218E-04 1.0270 -4.903 H2S,gas 0.3608E-01 0.1804E+01 0.8293 0.175 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.2729E-08 0.1365E-06 1.0000 -6.865 SO3,gas 0.3370E-30 0.1685E-28 1.0000 -28.773 SO2,gas 0.1646E-12 0.8230E-11 1.0000 -11.085 HF,gas 0.3423E-06 0.1711E-04 1.0000 -4.767 HCl,gas 0.3037E-07 0.1518E-05 1.0000 -5.819 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 3.660633 % Solid products produced: Mass = 14.123196 g Volume = 6.763365 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 21.9999900 moles log = 1.3424 Original solution: 1000.0103000 g Original solution / Rock added: 45.46 (Water/Rock Ratio), log = 1.6576 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 0.00000E+00 2 CO2,gas -6.66 -6.66 0.00 0.000 0.00000E+00 3 CH4,gas 4.54 4.54 0.00 0.000 -0.15165E-11 4 H2,gas 8.00 8.00 0.00 0.000 -0.30331E-11 5 H2S,gas -6.23 -6.23 0.00 0.000 -0.15165E-11 6 S2,gas -7.34 -7.34 0.00 0.000 0.00000E+00 7 CO,gas 3.21 3.21 0.00 0.000 0.22748E-11 8 SO3,gas 17.12 17.12 0.00 0.000 0.00000E+00 9 SO2,gas 0.83 0.83 0.00 0.000 -0.34122E-11 10 HF,gas 0.47 0.47 0.00 0.000 0.18957E-11 11 HCl,gas 5.19 5.19 0.00 0.000 0.00000E+00 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 172 sulfur -9.15 -9.15 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.95 -0.85 -0.242 0.14464E+04 89 graphite -3.55 -3.95 -0.40 -0.115 0.68864E+03 92 halite 1.57 -3.08 -4.65 -2.327 0.79454E+04 145 pyrite -21.25 -22.66 -1.41 -0.332 0.24067E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 214 topaz -16.55 -20.99 -4.45 -0.494 0.75954E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 21.9999900 MOLES New total amount of reactant added: 22.9999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 23 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 22.9999900 Water: Moles liquid = 0.7077E+02 kg liquid = 0.1275E+01 Moles total = 0.6868E+02 kg total = 0.1237E+01 Activity = 0.9965 Stoichiometric ionic strength = .2991328E+00 Osmotic coef. = 0.9147 True ionic strength = .1053881E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1358E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89821E-01 -1.0466 0.65962E-01 -1.1807 0.73437E+00 -0.1341 2 H2O 0.99649E+00 -0.0015 0.99649E+00 -0.0015 3 Cl- 0.10535E+00 -0.9774 0.75941E-01 -1.1195 0.72085E+00 -0.1422 4 SO4-- 0.32883E-10 -10.4830 0.97814E-11 -11.0096 0.29746E+00 -0.5266 5 HCO3- 0.37200E-05 -5.4295 0.26937E-05 -5.5696 0.72411E+00 -0.1402 6 HS- 0.37542E-06 -6.4255 0.27074E-06 -6.5674 0.72117E+00 -0.1420 7 Al+++ 0.37371E-05 -5.4275 0.24185E-06 -6.6165 0.64715E-01 -1.1890 8 H4SiO4 0.10175E-02 -2.9925 0.10175E-02 -2.9925 0.10000E+01 0.0000 9 Ca++ 0.15545E-06 -6.8084 0.45133E-07 -7.3455 0.29035E+00 -0.5371 10 Mg++ 0.62852E-10 -10.2017 0.17990E-10 -10.7450 0.28623E+00 -0.5433 11 Fe++ 0.24395E-07 -7.6127 0.70063E-08 -8.1545 0.28720E+00 -0.5418 12 K+ 0.11067E-03 -3.9560 0.80173E-04 -4.0960 0.72446E+00 -0.1400 13 Na+ 0.15433E-01 -1.8115 0.11114E-01 -1.9541 0.72016E+00 -0.1426 14 Mn++ 0.14895E-08 -8.8269 0.42890E-09 -9.3676 0.28794E+00 -0.5407 15 F- 0.22229E-04 -4.6531 0.15931E-04 -4.7978 0.71667E+00 -0.1447 16 HPO4-- 0.34215E-14 -14.4658 0.10182E-14 -14.9922 0.29759E+00 -0.5264 17 SiF6-2 0.34322E-11 -11.4644 0.10142E-11 -11.9939 0.29550E+00 -0.5294 18 HSiO3- 0.20051E-10 -10.6979 0.14453E-10 -10.8400 0.72085E+00 -0.1422 19 Ca(HSiO3)+ 0.20492E-16 -16.6884 0.14856E-16 -16.8281 0.72496E+00 -0.1397 20 Mg(HSiO3)+ 0.10166E-19 -19.9929 0.73696E-20 -20.1326 0.72496E+00 -0.1397 21 NaHSiO3,aq 0.25981E-11 -11.5853 0.25981E-11 -11.5853 0.10000E+01 0.0000 22 AlO+ 0.10394E-10 -10.9832 0.75352E-11 -11.1229 0.72496E+00 -0.1397 23 AlOH+2 0.85693E-08 -8.0671 0.24750E-08 -8.6064 0.28882E+00 -0.5394 24 HAlO2,aq 0.22670E-13 -13.6445 0.22670E-13 -13.6445 0.10000E+01 0.0000 25 AlO2- 0.10609E-17 -17.9743 0.76077E-18 -18.1187 0.71712E+00 -0.1444 26 CH4,aq 0.76817E-07 -7.1145 0.72173E-07 -7.1416 0.93954E+00 -0.0271 27 C2H6,aq 0.98070E-16 -16.0085 0.92141E-16 -16.0355 0.93954E+00 -0.0271 31 CO,aq 0.92825E-10 -10.0323 0.92825E-10 -10.0323 0.10000E+01 0.0000 32 CO2,aq 0.40552E+00 -0.3920 0.38101E+00 -0.4191 0.93954E+00 -0.0271 33 CO3-2 0.12071E-13 -13.9183 0.35670E-14 -14.4477 0.29550E+00 -0.5294 34 CaCO3,aq 0.20186E-17 -17.6949 0.20186E-17 -17.6949 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.42808E-11 -11.3685 0.31034E-11 -11.5082 0.72496E+00 -0.1397 36 CaCl+ 0.76511E-08 -8.1163 0.55467E-08 -8.2560 0.72496E+00 -0.1397 37 CaCl2,aq 0.10007E-09 -9.9997 0.10007E-09 -9.9997 0.10000E+01 0.0000 38 CaF+ 0.14480E-10 -10.8392 0.10497E-10 -10.9789 0.72496E+00 -0.1397 39 CaOH+ 0.67030E-16 -16.1737 0.48593E-16 -16.3134 0.72496E+00 -0.1397 40 CaSO4,aq 0.14019E-15 -15.8533 0.14019E-15 -15.8533 0.10000E+01 0.0000 41 HCl,aq 0.91793E-03 -3.0372 0.91793E-03 -3.0372 0.10000E+01 0.0000 45 HF,aq 0.71936E-02 -2.1431 0.71936E-02 -2.1431 0.10000E+01 0.0000 46 HF2- 0.53675E-07 -7.2702 0.38692E-07 -7.4124 0.72085E+00 -0.1422 47 Fe+3 0.58420E-17 -17.2334 0.38176E-18 -18.4182 0.65347E-01 -1.1848 48 FeCl+ 0.11617E-08 -8.9349 0.84217E-09 -9.0746 0.72496E+00 -0.1397 49 FeCl2,aq 0.20249E-14 -14.6936 0.20249E-14 -14.6936 0.10000E+01 0.0000 50 FeCl+2 0.71720E-17 -17.1444 0.20714E-17 -17.6837 0.28882E+00 -0.5394 51 FeF+ 0.78677E-11 -11.1042 0.57037E-11 -11.2438 0.72496E+00 -0.1397 52 FeF+2 0.18767E-15 -15.7266 0.54203E-16 -16.2660 0.28882E+00 -0.5394 54 FeOH+ 0.47525E-14 -14.3231 0.34453E-14 -14.4628 0.72496E+00 -0.1397 56 FeO+ 0.11531E-18 -18.9381 0.83593E-19 -19.0778 0.72496E+00 -0.1397 57 FeOH+2 0.36459E-17 -17.4382 0.10530E-17 -17.9776 0.28882E+00 -0.5394 60 H2,aq 0.10286E-07 -7.9877 0.96643E-08 -8.0148 0.93954E+00 -0.0271 61 KCl,aq 0.11035E-06 -6.9572 0.11035E-06 -6.9572 0.10000E+01 0.0000 62 KHSO4,aq 0.14626E-15 -15.8349 0.14626E-15 -15.8349 0.10000E+01 0.0000 63 KOH,aq 0.51724E-15 -15.2863 0.51724E-15 -15.2863 0.10000E+01 0.0000 64 KSO4- 0.16882E-13 -13.7726 0.12169E-13 -13.9147 0.72085E+00 -0.1422 66 Mg(HCO3)+ 0.17435E-14 -14.7586 0.12640E-14 -14.8983 0.72496E+00 -0.1397 67 MgCl+ 0.27641E-11 -11.5584 0.20039E-11 -11.6981 0.72496E+00 -0.1397 68 MgF+ 0.21381E-13 -13.6700 0.15500E-13 -13.8097 0.72496E+00 -0.1397 69 MgOH+ 0.14785E-18 -18.8302 0.10718E-18 -18.9699 0.72496E+00 -0.1397 71 MnF+ 0.15875E-12 -12.7993 0.11509E-12 -12.9390 0.72496E+00 -0.1397 73 MnOH+ 0.27027E-16 -16.5682 0.19593E-16 -16.7079 0.72496E+00 -0.1397 78 MnCl+ 0.27667E-09 -9.5580 0.20057E-09 -9.6977 0.72496E+00 -0.1397 79 MnSO4,aq 0.12111E-17 -17.9168 0.12111E-17 -17.9168 0.10000E+01 0.0000 80 NaCl,aq 0.27971E-03 -3.5533 0.27971E-03 -3.5533 0.10000E+01 0.0000 81 NaF,aq 0.41452E-07 -7.3825 0.41452E-07 -7.3825 0.10000E+01 0.0000 82 NaOH,aq 0.72139E-13 -13.1418 0.72139E-13 -13.1418 0.10000E+01 0.0000 84 OH- 0.12172E-10 -10.9147 0.87284E-11 -11.0591 0.71712E+00 -0.1444 90 H3PO3,aq 0.29713E-19 -19.5271 0.29713E-19 -19.5271 0.10000E+01 0.0000 92 H3PO4,aq 0.30985E-07 -7.5088 0.30985E-07 -7.5088 0.10000E+01 0.0000 93 H2PO4- 0.17138E-08 -8.7660 0.12390E-08 -8.9069 0.72295E+00 -0.1409 95 H4P2O7,aq 0.12703E-16 -16.8961 0.12703E-16 -16.8961 0.10000E+01 0.0000 96 H3P2O7- 0.34108E-17 -17.4672 0.24586E-17 -17.6093 0.72085E+00 -0.1422 97 H2P2O7-2 0.40877E-18 -18.3885 0.12079E-18 -18.9180 0.29550E+00 -0.5294 100 H2S,aq 0.58746E-01 -1.2310 0.55195E-01 -1.2581 0.93954E+00 -0.0271 101 S2-2 0.56873E-15 -15.2451 0.16806E-15 -15.7745 0.29550E+00 -0.5294 102 S3-2 0.43761E-14 -14.3589 0.12931E-14 -14.8884 0.29550E+00 -0.5294 103 S3- 0.80685E-09 -9.0932 0.58162E-09 -9.2354 0.72085E+00 -0.1422 104 S4-2 0.22242E-13 -13.6528 0.65727E-14 -14.1823 0.29550E+00 -0.5294 105 S5-2 0.75384E-13 -13.1227 0.22276E-13 -13.6522 0.29550E+00 -0.5294 106 SO2,aq 0.18498E-11 -11.7329 0.18498E-11 -11.7329 0.10000E+01 0.0000 107 SO3-2 0.39894E-19 -19.3991 0.12327E-19 -19.9091 0.30900E+00 -0.5100 108 HSO3- 0.70630E-13 -13.1510 0.50913E-13 -13.2932 0.72085E+00 -0.1422 109 HSO4- 0.85485E-09 -9.0681 0.62179E-09 -9.2064 0.72737E+00 -0.1382 111 S2O3-2 0.21537E-13 -13.6668 0.63642E-14 -14.1963 0.29550E+00 -0.5294 112 HS2O3- 0.10413E-12 -12.9824 0.75060E-13 -13.1246 0.72085E+00 -0.1422 113 H2S2O3,aq 0.79373E-13 -13.1003 0.79373E-13 -13.1003 0.10000E+01 0.0000 Charge balance for all species = -.4320E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8982140E-01 0.5622017E+00 0.5532095E+03 0.0000 2 H2O 0.1000000E+01 0.5510273E+02 0.9691195E+06 0.0000 3 Cl- 0.1053503E+00 0.1065481E+00 0.3687748E+04 0.0612 4 SO4-- 0.3288311E-10 -.7801763E-07 -.7316532E-02 -8.6482 5 HCO3- 0.3720032E-05 0.4055262E+00 0.2415650E+05 -4.3889 6 HS- 0.3754216E-06 0.5874670E-01 0.1896735E+04 -5.3867 7 Al+++ 0.3737097E-05 0.3745677E-05 0.9866410E-01 -3.0744 8 H4SiO4 0.1017454E-02 0.1017454E-02 0.9547080E+02 -2.9925 9 Ca++ 0.1554460E-06 0.1632159E-06 0.6386036E-02 -4.9841 10 Mg++ 0.6285201E-10 0.6563925E-10 0.1557927E-05 -8.3836 11 Fe++ 0.2439507E-07 0.2556463E-07 0.1393805E-02 -5.7931 12 K+ 0.1106668E-03 0.1107771E-03 0.4228748E+01 -2.9153 13 Na+ 0.1543301E-01 0.1571276E-01 0.3526553E+03 -0.7734 14 Mn++ 0.1489543E-08 0.1766370E-08 0.9473646E-04 -7.0062 15 F- 0.2222869E-04 0.7216006E-02 0.1338343E+03 -3.6171 16 HPO4-- 0.3421549E-14 0.3269926E-07 0.3063917E-02 -12.6307 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.2456497E+01 0.7167492E+00 0.5490632E+00 0.1190685E+01 2 H2O 0.6867650E+02 0.7025030E+02 -.4609623E+00 -.1112832E+01 3 Cl- 0.1358378E+00 0.1358378E+00 0.0000000E+00 0.3964248E-07 4 SO4-- 0.1098100E+00 -.9946443E-07 0.1098126E+00 -.2582418E-05 5 HCO3- 0.1662912E+01 0.5170041E+00 0.0000000E+00 0.1145908E+01 6 HS- 0.4491153E+00 0.7489598E-01 0.3294379E+00 0.4478136E-01 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1297149E-02 0.1085587E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.9200096E-02 0.9199664E-02 0.0000000E+00 0.4323017E-06 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1312E-15 Mass of aqueous solution: 0.130591E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 22.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.3307E-01 -1.481 0.5956 -0.225 1.133 13.14 CO2,gas 1.146 0.059 50.43 1.703 95.96 617.2 CH4,gas 0.2506E-05 -5.601 0.4020E-04 -4.396 0.7649E-04 0.1618E-02 H2,gas 0.3024E-06 -6.519 0.6108E-06 -6.214 0.1162E-05 0.1926E-03 H2S,gas 0.4478E-01 -1.349 1.526 0.184 2.904 22.80 S2,gas 0.1314E-10 -10.881 0.8424E-09 -9.075 0.1603E-08 0.8152E-08 CO,gas 0.3386E-08 -8.470 0.9483E-07 -7.023 0.1804E-06 0.2101E-05 SO3,gas 0.3952E-30 -30.403 0.3164E-28 -28.500 0.6021E-28 0.2452E-27 SO2,gas 0.1958E-12 -12.708 0.1254E-10 -10.902 0.2387E-10 0.1215E-09 HF,gas 0.4323E-06 -6.364 0.8646E-05 -5.063 0.1645E-04 0.2682E-03 HCl,gas 0.3964E-07 -7.402 0.1445E-05 -5.840 0.2750E-05 0.2460E-04 quartz 0.1086E-01 -1.964 0.6522 -0.186 4.426 0.2463 sulfur 0.4393 -0.357 14.08 1.149 95.57 6.813 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2702E-01 0.1351E+01 0.7419 0.001 CO2,gas 0.9364E+00 0.4682E+02 0.8707 1.610 CH4,gas 0.2048E-05 0.1024E-03 1.0375 -3.974 H2,gas 0.2471E-06 0.1235E-04 1.0270 -4.897 H2S,gas 0.3659E-01 0.1830E+01 0.8293 0.181 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.2767E-08 0.1383E-06 1.0000 -6.859 SO3,gas 0.3230E-30 0.1615E-28 1.0000 -28.792 SO2,gas 0.1600E-12 0.7999E-11 1.0000 -11.097 HF,gas 0.3533E-06 0.1766E-04 1.0000 -4.753 HCl,gas 0.3239E-07 0.1620E-05 1.0000 -5.791 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 3.827063 % Solid products produced: Mass = 14.734595 g Volume = 7.059260 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 22.9999900 moles log = 1.3617 Original solution: 1000.0103000 g Original solution / Rock added: 43.48 (Water/Rock Ratio), log = 1.6383 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 -0.37914E-12 2 CO2,gas -6.66 -6.66 0.00 0.000 0.15165E-11 3 CH4,gas 4.54 4.54 0.00 0.000 0.15165E-11 4 H2,gas 8.00 8.00 0.00 0.000 0.00000E+00 5 H2S,gas -6.23 -6.23 0.00 0.000 -0.15165E-11 6 S2,gas -7.34 -7.34 0.00 0.000 -0.60662E-11 7 CO,gas 3.21 3.21 0.00 0.000 -0.75827E-12 8 SO3,gas 17.12 17.12 0.00 0.000 0.00000E+00 9 SO2,gas 0.83 0.83 0.00 0.000 0.26539E-11 10 HF,gas 0.47 0.47 0.00 0.000 -0.11374E-11 11 HCl,gas 5.19 5.19 0.00 0.000 0.00000E+00 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 172 sulfur -9.15 -9.15 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.94 -0.84 -0.239 0.14258E+04 89 graphite -3.55 -3.94 -0.39 -0.112 0.66800E+03 92 halite 1.57 -3.07 -4.65 -2.324 0.79367E+04 145 pyrite -21.25 -22.69 -1.45 -0.340 0.24701E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 214 topaz -16.55 -21.10 -4.55 -0.506 0.77722E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 22.9999900 MOLES New total amount of reactant added: 23.9999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 21 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 23.9999900 Water: Moles liquid = 0.7168E+02 kg liquid = 0.1291E+01 Moles total = 0.6950E+02 kg total = 0.1252E+01 Activity = 0.9964 Stoichiometric ionic strength = .3011073E+00 Osmotic coef. = 0.9147 True ionic strength = .1085464E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1417E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93184E-01 -1.0307 0.68255E-01 -1.1659 0.73248E+00 -0.1352 2 H2O 0.99639E+00 -0.0016 0.99639E+00 -0.0016 3 Cl- 0.10851E+00 -0.9645 0.77993E-01 -1.1079 0.71877E+00 -0.1434 4 SO4-- 0.29866E-10 -10.5248 0.87801E-11 -11.0565 0.29399E+00 -0.5317 5 HCO3- 0.36030E-05 -5.4433 0.26016E-05 -5.5848 0.72208E+00 -0.1414 6 HS- 0.36865E-06 -6.4334 0.26509E-06 -6.5766 0.71910E+00 -0.1432 7 Al+++ 0.36902E-05 -5.4330 0.23241E-06 -6.6337 0.62982E-01 -1.2008 8 H4SiO4 0.10172E-02 -2.9926 0.10172E-02 -2.9926 0.10000E+01 0.0000 9 Ca++ 0.15335E-06 -6.8143 0.43985E-07 -7.3567 0.28683E+00 -0.5424 10 Mg++ 0.62011E-10 -10.2075 0.17530E-10 -10.7562 0.28270E+00 -0.5487 11 Fe++ 0.24067E-07 -7.6186 0.68272E-08 -8.1658 0.28367E+00 -0.5472 12 K+ 0.10926E-03 -3.9615 0.78934E-04 -4.1027 0.72243E+00 -0.1412 13 Na+ 0.15231E-01 -1.8173 0.10937E-01 -1.9611 0.71807E+00 -0.1438 14 Mn++ 0.14667E-08 -8.8337 0.41715E-09 -9.3797 0.28442E+00 -0.5460 15 F- 0.22199E-04 -4.6537 0.15863E-04 -4.7996 0.71456E+00 -0.1460 16 HPO4-- 0.31975E-14 -14.4952 0.94044E-15 -15.0267 0.29412E+00 -0.5315 17 SiF6-2 0.38820E-11 -11.4109 0.11336E-11 -11.9455 0.29202E+00 -0.5346 18 HSiO3- 0.19431E-10 -10.7115 0.13966E-10 -10.8549 0.71877E+00 -0.1434 19 Ca(HSiO3)+ 0.19352E-16 -16.7133 0.13990E-16 -16.8542 0.72293E+00 -0.1409 21 NaHSiO3,aq 0.24705E-11 -11.6072 0.24705E-11 -11.6072 0.10000E+01 0.0000 22 AlO+ 0.93541E-11 -11.0290 0.67624E-11 -11.1699 0.72293E+00 -0.1409 23 AlOH+2 0.80559E-08 -8.0939 0.22983E-08 -8.6386 0.28529E+00 -0.5447 24 HAlO2,aq 0.19659E-13 -13.7064 0.19659E-13 -13.7064 0.10000E+01 0.0000 25 AlO2- 0.89170E-18 -18.0498 0.63758E-18 -18.1955 0.71501E+00 -0.1457 26 CH4,aq 0.80939E-07 -7.0918 0.76027E-07 -7.1190 0.93930E+00 -0.0272 27 C2H6,aq 0.10744E-15 -15.9688 0.10092E-15 -15.9960 0.93930E+00 -0.0272 31 CO,aq 0.94009E-10 -10.0268 0.94009E-10 -10.0268 0.10000E+01 0.0000 32 CO2,aq 0.40542E+00 -0.3921 0.38081E+00 -0.4193 0.93930E+00 -0.0272 33 CO3-2 0.11401E-13 -13.9431 0.33293E-14 -14.4776 0.29202E+00 -0.5346 34 CaCO3,aq 0.18362E-17 -17.7361 0.18362E-17 -17.7361 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.40405E-11 -11.3936 0.29210E-11 -11.5345 0.72293E+00 -0.1409 36 CaCl+ 0.76794E-08 -8.1147 0.55516E-08 -8.2556 0.72293E+00 -0.1409 37 CaCl2,aq 0.10287E-09 -9.9877 0.10287E-09 -9.9877 0.10000E+01 0.0000 38 CaF+ 0.14091E-10 -10.8511 0.10187E-10 -10.9920 0.72293E+00 -0.1409 39 CaOH+ 0.63300E-16 -16.1986 0.45761E-16 -16.3395 0.72293E+00 -0.1409 40 CaSO4,aq 0.12263E-15 -15.9114 0.12263E-15 -15.9114 0.10000E+01 0.0000 41 HCl,aq 0.97549E-03 -3.0108 0.97549E-03 -3.0108 0.10000E+01 0.0000 45 HF,aq 0.74120E-02 -2.1301 0.74120E-02 -2.1301 0.10000E+01 0.0000 46 HF2- 0.55228E-07 -7.2578 0.39696E-07 -7.4012 0.71877E+00 -0.1434 47 Fe+3 0.60122E-17 -17.2210 0.38242E-18 -18.4175 0.63607E-01 -1.1965 48 FeCl+ 0.11658E-08 -8.9334 0.84282E-09 -9.0743 0.72293E+00 -0.1409 49 FeCl2,aq 0.20812E-14 -14.6817 0.20812E-14 -14.6817 0.10000E+01 0.0000 50 FeCl+2 0.74697E-17 -17.1267 0.21311E-17 -17.6714 0.28529E+00 -0.5447 51 FeF+ 0.76553E-11 -11.1160 0.55343E-11 -11.2569 0.72293E+00 -0.1409 52 FeF+2 0.18951E-15 -15.7224 0.54066E-16 -16.2671 0.28529E+00 -0.5447 54 FeOH+ 0.44875E-14 -14.3480 0.32442E-14 -14.4889 0.72293E+00 -0.1409 56 FeO+ 0.10817E-18 -18.9659 0.78199E-19 -19.1068 0.72293E+00 -0.1409 57 FeOH+2 0.35728E-17 -17.4470 0.10193E-17 -17.9917 0.28529E+00 -0.5447 60 H2,aq 0.10424E-07 -7.9820 0.97916E-08 -8.0091 0.93930E+00 -0.0272 61 KCl,aq 0.11158E-06 -6.9524 0.11158E-06 -6.9524 0.10000E+01 0.0000 62 KHSO4,aq 0.13375E-15 -15.8737 0.13375E-15 -15.8737 0.10000E+01 0.0000 63 KOH,aq 0.49209E-15 -15.3080 0.49209E-15 -15.3080 0.10000E+01 0.0000 64 KSO4- 0.14962E-13 -13.8250 0.10754E-13 -13.9684 0.71877E+00 -0.1434 66 Mg(HCO3)+ 0.16455E-14 -14.7837 0.11896E-14 -14.9246 0.72293E+00 -0.1409 67 MgCl+ 0.27740E-11 -11.5569 0.20054E-11 -11.6978 0.72293E+00 -0.1409 68 MgF+ 0.20804E-13 -13.6819 0.15040E-13 -13.8228 0.72293E+00 -0.1409 69 MgOH+ 0.13960E-18 -18.8551 0.10092E-18 -18.9960 0.72293E+00 -0.1409 71 MnF+ 0.15418E-12 -12.8120 0.11146E-12 -12.9529 0.72293E+00 -0.1409 73 MnOH+ 0.25472E-16 -16.5939 0.18414E-16 -16.7348 0.72293E+00 -0.1409 78 MnCl+ 0.27713E-09 -9.5573 0.20035E-09 -9.6982 0.72293E+00 -0.1409 79 MnSO4,aq 0.10574E-17 -17.9758 0.10574E-17 -17.9758 0.10000E+01 0.0000 80 NaCl,aq 0.28269E-03 -3.5487 0.28269E-03 -3.5487 0.10000E+01 0.0000 81 NaF,aq 0.40617E-07 -7.3913 0.40617E-07 -7.3913 0.10000E+01 0.0000 82 NaOH,aq 0.68596E-13 -13.1637 0.68596E-13 -13.1637 0.10000E+01 0.0000 84 OH- 0.11796E-10 -10.9283 0.84344E-11 -11.0739 0.71501E+00 -0.1457 90 H3PO3,aq 0.29774E-19 -19.5262 0.29774E-19 -19.5262 0.10000E+01 0.0000 92 H3PO4,aq 0.30642E-07 -7.5137 0.30642E-07 -7.5137 0.10000E+01 0.0000 93 H2PO4- 0.16426E-08 -8.7845 0.11841E-08 -8.9266 0.72091E+00 -0.1421 95 H4P2O7,aq 0.12424E-16 -16.9057 0.12424E-16 -16.9057 0.10000E+01 0.0000 96 H3P2O7- 0.32332E-17 -17.4904 0.23240E-17 -17.6338 0.71877E+00 -0.1434 97 H2P2O7-2 0.37786E-18 -18.4227 0.11034E-18 -18.9573 0.29202E+00 -0.5346 100 H2S,aq 0.59535E-01 -1.2252 0.55921E-01 -1.2524 0.93930E+00 -0.0272 101 S2-2 0.54458E-15 -15.2639 0.15903E-15 -15.7985 0.29202E+00 -0.5346 102 S3-2 0.41902E-14 -14.3778 0.12236E-14 -14.9123 0.29202E+00 -0.5346 103 S3- 0.78713E-09 -9.1040 0.56577E-09 -9.2474 0.71877E+00 -0.1434 104 S4-2 0.21298E-13 -13.6717 0.62194E-14 -14.2063 0.29202E+00 -0.5346 105 S5-2 0.72182E-13 -13.1416 0.21079E-13 -13.6762 0.29202E+00 -0.5346 106 SO2,aq 0.18017E-11 -11.7443 0.18017E-11 -11.7443 0.10000E+01 0.0000 107 SO3-2 0.36691E-19 -19.4354 0.11212E-19 -19.9503 0.30559E+00 -0.5149 108 HSO3- 0.66665E-13 -13.1761 0.47917E-13 -13.3195 0.71877E+00 -0.1434 109 HSO4- 0.79618E-09 -9.0990 0.57754E-09 -9.2384 0.72539E+00 -0.1394 111 S2O3-2 0.19822E-13 -13.7028 0.57885E-14 -14.2374 0.29202E+00 -0.5346 112 HS2O3- 0.98284E-13 -13.0075 0.70644E-13 -13.1509 0.71877E+00 -0.1434 113 H2S2O3,aq 0.77299E-13 -13.1118 0.77299E-13 -13.1118 0.10000E+01 0.0000 Charge balance for all species = -.4265E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9318350E-01 0.5665247E+00 0.5573874E+03 0.0000 2 H2O 0.1000000E+01 0.5510283E+02 0.9689893E+06 0.0000 3 Cl- 0.1085089E+00 0.1097672E+00 0.3798650E+04 0.0579 4 SO4-- 0.2986560E-10 -.8224923E-07 -.7712324E-02 -8.7248 5 HCO3- 0.3602965E-05 0.4054224E+00 0.2414702E+05 -4.4189 6 HS- 0.3686461E-06 0.5953541E-01 0.1921938E+04 -5.4107 7 Al+++ 0.3690153E-05 0.3698218E-05 0.9740072E-01 -3.1361 8 H4SiO4 0.1017238E-02 0.1017238E-02 0.9543754E+02 -2.9926 9 Ca++ 0.1533476E-06 0.1611479E-06 0.6304264E-02 -5.0250 10 Mg++ 0.6201110E-10 0.6480758E-10 0.1537978E-05 -8.4245 11 Fe++ 0.2406722E-07 0.2524072E-07 0.1375958E-02 -5.8340 12 K+ 0.1092620E-03 0.1093735E-03 0.4174599E+01 -2.9369 13 Na+ 0.1523095E-01 0.1551367E-01 0.3481396E+03 -0.7952 14 Mn++ 0.1466700E-08 0.1743989E-08 0.9352337E-04 -7.0480 15 F- 0.2219944E-04 0.7434322E-02 0.1378646E+03 -3.6338 16 HPO4-- 0.3197493E-14 0.3228495E-07 0.3024683E-02 -12.6949 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.2564172E+01 0.7315294E+00 0.5729397E+00 0.1259703E+01 2 H2O 0.6949520E+02 0.7115195E+02 -.4800308E+00 -.1176718E+01 3 Cl- 0.1417378E+00 0.1417378E+00 0.0000000E+00 0.4457058E-07 4 SO4-- 0.1145850E+00 -.1062049E-06 0.1145879E+00 -.2874734E-05 5 HCO3- 0.1735212E+01 0.5235047E+00 0.0000000E+00 0.1211708E+01 6 HS- 0.4686403E+00 0.7687556E-01 0.3437638E+00 0.4800089E-01 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1313517E-02 0.1083950E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.9600096E-02 0.9599625E-02 0.0000000E+00 0.4712408E-06 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2222E-16 Mass of aqueous solution: 0.132285E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 23.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.3498E-01 -1.456 0.6301 -0.201 1.133 13.90 CO2,gas 1.212 0.083 53.33 1.727 95.92 652.6 CH4,gas 0.2793E-05 -5.554 0.4480E-04 -4.349 0.8058E-04 0.1803E-02 H2,gas 0.3241E-06 -6.489 0.6547E-06 -6.184 0.1178E-05 0.2065E-03 H2S,gas 0.4800E-01 -1.319 1.636 0.214 2.942 24.44 S2,gas 0.1390E-10 -10.857 0.8912E-09 -9.050 0.1603E-08 0.8624E-08 CO,gas 0.3627E-08 -8.440 0.1016E-06 -6.993 0.1828E-06 0.2251E-05 SO3,gas 0.4019E-30 -30.396 0.3218E-28 -28.492 0.5788E-28 0.2494E-27 SO2,gas 0.2017E-12 -12.695 0.1292E-10 -10.889 0.2325E-10 0.1252E-09 HF,gas 0.4712E-06 -6.327 0.9425E-05 -5.026 0.1695E-04 0.2924E-03 HCl,gas 0.4457E-07 -7.351 0.1625E-05 -5.789 0.2923E-05 0.2766E-04 quartz 0.1084E-01 -1.965 0.6512 -0.186 4.244 0.2459 sulfur 0.4584 -0.339 14.69 1.167 95.76 7.109 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2702E-01 0.1351E+01 0.7419 0.001 CO2,gas 0.9359E+00 0.4680E+02 0.8707 1.610 CH4,gas 0.2157E-05 0.1079E-03 1.0375 -3.951 H2,gas 0.2503E-06 0.1252E-04 1.0270 -4.891 H2S,gas 0.3707E-01 0.1854E+01 0.8293 0.187 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.2802E-08 0.1401E-06 1.0000 -6.854 SO3,gas 0.3104E-30 0.1552E-28 1.0000 -28.809 SO2,gas 0.1558E-12 0.7791E-11 1.0000 -11.108 HF,gas 0.3640E-06 0.1820E-04 1.0000 -4.740 HCl,gas 0.3443E-07 0.1721E-05 1.0000 -5.764 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 3.988636 % Solid products produced: Mass = 15.345996 g Volume = 7.355156 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 23.9999900 moles log = 1.3802 Original solution: 1000.0103000 g Original solution / Rock added: 41.67 (Water/Rock Ratio), log = 1.6198 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 0.37914E-12 2 CO2,gas -6.66 -6.66 0.00 0.000 0.00000E+00 3 CH4,gas 4.54 4.54 0.00 0.000 -0.30331E-11 4 H2,gas 8.00 8.00 0.00 0.000 0.00000E+00 5 H2S,gas -6.23 -6.23 0.00 0.000 0.00000E+00 6 S2,gas -7.34 -7.34 0.00 0.000 0.00000E+00 7 CO,gas 3.21 3.21 0.00 0.000 -0.75827E-12 8 SO3,gas 17.12 17.12 0.00 0.000 0.00000E+00 9 SO2,gas 0.83 0.83 0.00 0.000 0.26539E-11 10 HF,gas 0.47 0.47 0.00 0.000 -0.11374E-11 11 HCl,gas 5.19 5.19 0.00 0.000 0.00000E+00 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 172 sulfur -9.15 -9.15 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.93 -0.82 -0.235 0.14066E+04 89 graphite -3.55 -3.93 -0.38 -0.109 0.64882E+03 92 halite 1.57 -3.07 -4.64 -2.322 0.79288E+04 145 pyrite -21.25 -22.73 -1.48 -0.349 0.25303E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 214 topaz -16.55 -21.20 -4.65 -0.517 0.79390E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 23.9999900 MOLES New total amount of reactant added: 24.9999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 21 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 24.9999900 Water: Moles liquid = 0.7258E+02 kg liquid = 0.1308E+01 Moles total = 0.7031E+02 kg total = 0.1267E+01 Activity = 0.9963 Stoichiometric ionic strength = .3030230E+00 Osmotic coef. = 0.9147 True ionic strength = .1116245E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1476E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.96460E-01 -1.0157 0.70482E-01 -1.1519 0.73069E+00 -0.1363 2 H2O 0.99629E+00 -0.0016 0.99629E+00 -0.0016 3 Cl- 0.11159E+00 -0.9524 0.79987E-01 -1.0970 0.71681E+00 -0.1446 4 SO4-- 0.27295E-10 -10.5639 0.79352E-11 -11.1004 0.29072E+00 -0.5365 5 HCO3- 0.34964E-05 -5.4564 0.25180E-05 -5.5990 0.72016E+00 -0.1426 6 HS- 0.36236E-06 -6.4409 0.25986E-06 -6.5853 0.71714E+00 -0.1444 7 Al+++ 0.36443E-05 -5.4384 0.22368E-06 -6.6504 0.61376E-01 -1.2120 8 H4SiO4 0.10170E-02 -2.9927 0.10170E-02 -2.9927 0.10000E+01 0.0000 9 Ca++ 0.15131E-06 -6.8201 0.42899E-07 -7.3676 0.28352E+00 -0.5474 10 Mg++ 0.61193E-10 -10.2133 0.17096E-10 -10.7671 0.27938E+00 -0.5538 11 Fe++ 0.23748E-07 -7.6244 0.66580E-08 -8.1767 0.28035E+00 -0.5523 12 K+ 0.10789E-03 -3.9670 0.77737E-04 -4.1094 0.72050E+00 -0.1424 13 Na+ 0.15034E-01 -1.8229 0.10766E-01 -1.9680 0.71609E+00 -0.1450 14 Mn++ 0.14446E-08 -8.8402 0.40608E-09 -9.3914 0.28110E+00 -0.5511 15 F- 0.22177E-04 -4.6541 0.15803E-04 -4.8013 0.71257E+00 -0.1472 16 HPO4-- 0.29988E-14 -14.5231 0.87220E-15 -15.0594 0.29085E+00 -0.5363 17 SiF6-2 0.43645E-11 -11.3601 0.12602E-11 -11.8995 0.28874E+00 -0.5395 18 HSiO3- 0.18867E-10 -10.7243 0.13524E-10 -10.8689 0.71681E+00 -0.1446 19 Ca(HSiO3)+ 0.18325E-16 -16.7370 0.13212E-16 -16.8790 0.72101E+00 -0.1421 21 NaHSiO3,aq 0.23548E-11 -11.6281 0.23548E-11 -11.6281 0.10000E+01 0.0000 22 AlO+ 0.84641E-11 -11.0724 0.61027E-11 -11.2145 0.72101E+00 -0.1421 23 AlOH+2 0.75955E-08 -8.1194 0.21418E-08 -8.6692 0.28198E+00 -0.5498 24 HAlO2,aq 0.17179E-13 -13.7650 0.17179E-13 -13.7650 0.10000E+01 0.0000 25 AlO2- 0.75670E-18 -18.1211 0.53954E-18 -18.2680 0.71302E+00 -0.1469 26 CH4,aq 0.84979E-07 -7.0707 0.79801E-07 -7.0980 0.93907E+00 -0.0273 27 C2H6,aq 0.11697E-15 -15.9319 0.10984E-15 -15.9592 0.93907E+00 -0.0273 31 CO,aq 0.95125E-10 -10.0217 0.95125E-10 -10.0217 0.10000E+01 0.0000 32 CO2,aq 0.40532E+00 -0.3922 0.38063E+00 -0.4195 0.93907E+00 -0.0273 33 CO3-2 0.10807E-13 -13.9663 0.31204E-14 -14.5058 0.28874E+00 -0.5395 34 CaCO3,aq 0.16785E-17 -17.7751 0.16785E-17 -17.7751 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.38242E-11 -11.4175 0.27573E-11 -11.5595 0.72101E+00 -0.1421 36 CaCl+ 0.77017E-08 -8.1134 0.55530E-08 -8.2555 0.72101E+00 -0.1421 37 CaCl2,aq 0.10553E-09 -9.9766 0.10553E-09 -9.9766 0.10000E+01 0.0000 38 CaF+ 0.13728E-10 -10.8624 0.98978E-11 -11.0045 0.72101E+00 -0.1421 39 CaOH+ 0.59940E-16 -16.2223 0.43217E-16 -16.3643 0.72101E+00 -0.1421 40 CaSO4,aq 0.10810E-15 -15.9662 0.10810E-15 -15.9662 0.10000E+01 0.0000 41 HCl,aq 0.10331E-02 -2.9859 0.10331E-02 -2.9859 0.10000E+01 0.0000 45 HF,aq 0.76248E-02 -2.1178 0.76248E-02 -2.1178 0.10000E+01 0.0000 46 HF2- 0.56754E-07 -7.2460 0.40682E-07 -7.3906 0.71681E+00 -0.1446 47 Fe+3 0.61742E-17 -17.2094 0.38277E-18 -18.4171 0.61995E-01 -1.2076 48 FeCl+ 0.11691E-08 -8.9321 0.84294E-09 -9.0742 0.72101E+00 -0.1421 49 FeCl2,aq 0.21347E-14 -14.6707 0.21347E-14 -14.6707 0.10000E+01 0.0000 50 FeCl+2 0.77577E-17 -17.1103 0.21875E-17 -17.6600 0.28198E+00 -0.5498 51 FeF+ 0.74571E-11 -11.1274 0.53766E-11 -11.2695 0.72101E+00 -0.1421 52 FeF+2 0.19118E-15 -15.7186 0.53910E-16 -16.2683 0.28198E+00 -0.5498 54 FeOH+ 0.42488E-14 -14.3717 0.30635E-14 -14.5138 0.72101E+00 -0.1421 56 FeO+ 0.10179E-18 -18.9923 0.73395E-19 -19.1343 0.72101E+00 -0.1421 57 FeOH+2 0.35034E-17 -17.4555 0.98789E-18 -18.0053 0.28198E+00 -0.5498 60 H2,aq 0.10555E-07 -7.9766 0.99116E-08 -8.0039 0.93907E+00 -0.0273 61 KCl,aq 0.11270E-06 -6.9481 0.11270E-06 -6.9481 0.10000E+01 0.0000 62 KHSO4,aq 0.12293E-15 -15.9104 0.12293E-15 -15.9104 0.10000E+01 0.0000 63 KOH,aq 0.46927E-15 -15.3286 0.46927E-15 -15.3286 0.10000E+01 0.0000 64 KSO4- 0.13354E-13 -13.8744 0.95722E-14 -14.0190 0.71681E+00 -0.1446 66 Mg(HCO3)+ 0.15572E-14 -14.8076 0.11228E-14 -14.9497 0.72101E+00 -0.1421 67 MgCl+ 0.27818E-11 -11.5557 0.20057E-11 -11.6977 0.72101E+00 -0.1421 68 MgF+ 0.20265E-13 -13.6933 0.14611E-13 -13.8353 0.72101E+00 -0.1421 69 MgOH+ 0.13218E-18 -18.8788 0.95303E-19 -19.0209 0.72101E+00 -0.1421 71 MnF+ 0.14991E-12 -12.8242 0.10809E-12 -12.9662 0.72101E+00 -0.1421 73 MnOH+ 0.24073E-16 -16.6185 0.17357E-16 -16.7605 0.72101E+00 -0.1421 78 MnCl+ 0.27741E-09 -9.5569 0.20002E-09 -9.6989 0.72101E+00 -0.1421 79 MnSO4,aq 0.93026E-18 -18.0314 0.93026E-18 -18.0314 0.10000E+01 0.0000 80 NaCl,aq 0.28538E-03 -3.5446 0.28538E-03 -3.5446 0.10000E+01 0.0000 81 NaF,aq 0.39830E-07 -7.3998 0.39830E-07 -7.3998 0.10000E+01 0.0000 82 NaOH,aq 0.65383E-13 -13.1845 0.65383E-13 -13.1845 0.10000E+01 0.0000 84 OH- 0.11454E-10 -10.9410 0.81670E-11 -11.0879 0.71302E+00 -0.1469 90 H3PO3,aq 0.29808E-19 -19.5257 0.29808E-19 -19.5257 0.10000E+01 0.0000 92 H3PO4,aq 0.30304E-07 -7.5185 0.30304E-07 -7.5185 0.10000E+01 0.0000 93 H2PO4- 0.15773E-08 -8.8021 0.11340E-08 -8.9454 0.71897E+00 -0.1433 95 H4P2O7,aq 0.12152E-16 -16.9153 0.12152E-16 -16.9153 0.10000E+01 0.0000 96 H3P2O7- 0.30709E-17 -17.5127 0.22013E-17 -17.6573 0.71681E+00 -0.1446 97 H2P2O7-2 0.35053E-18 -18.4553 0.10121E-18 -18.9948 0.28874E+00 -0.5395 100 H2S,aq 0.60280E-01 -1.2198 0.56607E-01 -1.2471 0.93907E+00 -0.0273 101 S2-2 0.52283E-15 -15.2816 0.15097E-15 -15.8211 0.28874E+00 -0.5395 102 S3-2 0.40229E-14 -14.3955 0.11616E-14 -14.9349 0.28874E+00 -0.5395 103 S3- 0.76902E-09 -9.1141 0.55124E-09 -9.2587 0.71681E+00 -0.1446 104 S4-2 0.20447E-13 -13.6894 0.59040E-14 -14.2289 0.28874E+00 -0.5395 105 S5-2 0.69300E-13 -13.1593 0.20010E-13 -13.6988 0.28874E+00 -0.5395 106 SO2,aq 0.17579E-11 -11.7550 0.17579E-11 -11.7550 0.10000E+01 0.0000 107 SO3-2 0.33927E-19 -19.4695 0.10259E-19 -19.9889 0.30238E+00 -0.5195 108 HSO3- 0.63158E-13 -13.1996 0.45272E-13 -13.3442 0.71681E+00 -0.1446 109 HSO4- 0.74498E-09 -9.1279 0.53900E-09 -9.2684 0.72351E+00 -0.1406 111 S2O3-2 0.18342E-13 -13.7366 0.52962E-14 -14.2760 0.28874E+00 -0.5395 112 HS2O3- 0.93113E-13 -13.0310 0.66744E-13 -13.1756 0.71681E+00 -0.1446 113 H2S2O3,aq 0.75415E-13 -13.1225 0.75415E-13 -13.1225 0.10000E+01 0.0000 Charge balance for all species = -.4212E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9646003E-01 0.5707206E+00 0.5614413E+03 0.0000 2 H2O 0.1000000E+01 0.5510293E+02 0.9688628E+06 0.0000 3 Cl- 0.1115873E+00 0.1129059E+00 0.3906750E+04 0.0549 4 SO4-- 0.2729516E-10 -.8638647E-07 -.8099192E-02 -8.7966 5 HCO3- 0.3496380E-05 0.4053266E+00 0.2413812E+05 -4.4470 6 HS- 0.3623598E-06 0.6027998E-01 0.1945717E+04 -5.4333 7 Al+++ 0.3644343E-05 0.3651946E-05 0.9616933E-01 -3.1946 8 H4SiO4 0.1017028E-02 0.1017028E-02 0.9540517E+02 -2.9927 9 Ca++ 0.1513069E-06 0.1591317E-06 0.6224562E-02 -5.0637 10 Mg++ 0.6119309E-10 0.6399672E-10 0.1518534E-05 -8.4633 11 Fe++ 0.2374834E-07 0.2492491E-07 0.1358562E-02 -5.8728 12 K+ 0.1078924E-03 0.1080051E-03 0.4121822E+01 -2.9575 13 Na+ 0.1503415E-01 0.1531957E-01 0.3437383E+03 -0.8160 14 Mn++ 0.1444608E-08 0.1722168E-08 0.9234100E-04 -7.0875 15 F- 0.2217734E-04 0.7647174E-02 0.1417931E+03 -3.6493 16 HPO4-- 0.2998787E-14 0.3188101E-07 0.2986444E-02 -12.7555 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.2671847E+01 0.7462847E+00 0.5968163E+00 0.1328746E+01 2 H2O 0.7031390E+02 0.7205360E+02 -.4990993E+00 -.1240596E+01 3 Cl- 0.1476378E+00 0.1476378E+00 0.0000000E+00 0.4978833E-07 4 SO4-- 0.1193600E+00 -.1129605E-06 0.1193633E+00 -.3179587E-05 5 HCO3- 0.1807512E+01 0.5300125E+00 0.0000000E+00 0.1277500E+01 6 HS- 0.4881653E+00 0.7882320E-01 0.3580898E+00 0.5125232E-01 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1329884E-02 0.1082314E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1000010E-01 0.9999585E-02 0.0000000E+00 0.5113435E-06 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2069E-16 Mass of aqueous solution: 0.133978E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 24.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.3690E-01 -1.433 0.6645 -0.177 1.133 14.66 CO2,gas 1.277 0.106 56.22 1.750 95.89 688.0 CH4,gas 0.3092E-05 -5.510 0.4960E-04 -4.305 0.8459E-04 0.1996E-02 H2,gas 0.3461E-06 -6.461 0.6991E-06 -6.155 0.1192E-05 0.2205E-03 H2S,gas 0.5125E-01 -1.290 1.747 0.242 2.979 26.09 S2,gas 0.1466E-10 -10.834 0.9400E-09 -9.027 0.1603E-08 0.9097E-08 CO,gas 0.3872E-08 -8.412 0.1084E-06 -6.965 0.1850E-06 0.2402E-05 SO3,gas 0.4086E-30 -30.389 0.3272E-28 -28.485 0.5580E-28 0.2535E-27 SO2,gas 0.2076E-12 -12.683 0.1330E-10 -10.876 0.2269E-10 0.1288E-09 HF,gas 0.5113E-06 -6.291 0.1023E-04 -4.990 0.1744E-04 0.3173E-03 HCl,gas 0.4979E-07 -7.303 0.1815E-05 -5.741 0.3096E-05 0.3089E-04 quartz 0.1082E-01 -1.966 0.6503 -0.187 4.075 0.2456 sulfur 0.4775 -0.321 15.31 1.185 95.93 7.405 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2702E-01 0.1351E+01 0.7419 0.001 CO2,gas 0.9355E+00 0.4677E+02 0.8707 1.610 CH4,gas 0.2264E-05 0.1132E-03 1.0376 -3.930 H2,gas 0.2534E-06 0.1267E-04 1.0270 -4.886 H2S,gas 0.3753E-01 0.1876E+01 0.8293 0.192 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.2835E-08 0.1418E-06 1.0000 -6.848 SO3,gas 0.2992E-30 0.1496E-28 1.0000 -28.825 SO2,gas 0.1520E-12 0.7602E-11 1.0000 -11.119 HF,gas 0.3744E-06 0.1872E-04 1.0000 -4.728 HCl,gas 0.3646E-07 0.1823E-05 1.0000 -5.739 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 4.145560 % Solid products produced: Mass = 15.957398 g Volume = 7.651053 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 24.9999900 moles log = 1.3979 Original solution: 1000.0103000 g Original solution / Rock added: 40.00 (Water/Rock Ratio), log = 1.6021 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 0.00000E+00 2 CO2,gas -6.66 -6.66 0.00 0.000 -0.15165E-11 3 CH4,gas 4.54 4.54 0.00 0.000 0.15165E-11 4 H2,gas 8.00 8.00 0.00 0.000 0.00000E+00 5 H2S,gas -6.23 -6.23 0.00 0.000 0.00000E+00 6 S2,gas -7.34 -7.34 0.00 0.000 0.00000E+00 7 CO,gas 3.21 3.21 0.00 0.000 -0.75827E-12 8 SO3,gas 17.12 17.12 0.00 0.000 0.00000E+00 9 SO2,gas 0.83 0.83 0.00 0.000 -0.37914E-12 10 HF,gas 0.47 0.47 0.00 0.000 0.18957E-11 11 HCl,gas 5.19 5.19 0.00 0.000 0.15165E-11 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 172 sulfur -9.15 -9.15 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.92 -0.81 -0.232 0.13887E+04 89 graphite -3.55 -3.92 -0.37 -0.106 0.63096E+03 92 halite 1.57 -3.06 -4.64 -2.320 0.79218E+04 145 pyrite -21.25 -22.76 -1.52 -0.357 0.25875E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 214 topaz -16.55 -21.29 -4.74 -0.527 0.80969E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 24.9999900 MOLES New total amount of reactant added: 25.9999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 21 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 25.9999900 Water: Moles liquid = 0.7349E+02 kg liquid = 0.1324E+01 Moles total = 0.7113E+02 kg total = 0.1281E+01 Activity = 0.9962 Stoichiometric ionic strength = .3048826E+00 Osmotic coef. = 0.9148 True ionic strength = .1146253E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1535E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.99654E-01 -1.0015 0.72646E-01 -1.1388 0.72898E+00 -0.1373 2 H2O 0.99619E+00 -0.0017 0.99619E+00 -0.0017 3 Cl- 0.11459E+00 -0.9409 0.81925E-01 -1.0866 0.71495E+00 -0.1457 4 SO4-- 0.25087E-10 -10.6006 0.72159E-11 -11.1417 0.28764E+00 -0.5412 5 HCO3- 0.33989E-05 -5.4687 0.24416E-05 -5.6123 0.71834E+00 -0.1437 6 HS- 0.35651E-06 -6.4479 0.25500E-06 -6.5935 0.71529E+00 -0.1455 7 Al+++ 0.35996E-05 -5.4437 0.21556E-06 -6.6664 0.59883E-01 -1.2227 8 H4SiO4 0.10168E-02 -2.9928 0.10168E-02 -2.9928 0.10000E+01 0.0000 9 Ca++ 0.14932E-06 -6.8259 0.41871E-07 -7.3781 0.28041E+00 -0.5522 10 Mg++ 0.60397E-10 -10.2190 0.16685E-10 -10.7777 0.27625E+00 -0.5587 11 Fe++ 0.23438E-07 -7.6301 0.64977E-08 -8.1872 0.27723E+00 -0.5572 12 K+ 0.10656E-03 -3.9724 0.76580E-04 -4.1159 0.71868E+00 -0.1435 13 Na+ 0.14842E-01 -1.8285 0.10601E-01 -1.9747 0.71421E+00 -0.1462 14 Mn++ 0.14232E-08 -8.8467 0.39562E-09 -9.4027 0.27798E+00 -0.5560 15 F- 0.22161E-04 -4.6544 0.15749E-04 -4.8027 0.71068E+00 -0.1483 16 HPO4-- 0.28215E-14 -14.5495 0.81195E-15 -15.0905 0.28777E+00 -0.5410 17 SiF6-2 0.48800E-11 -11.3116 0.13940E-11 -11.8557 0.28566E+00 -0.5442 18 HSiO3- 0.18350E-10 -10.7364 0.13120E-10 -10.8821 0.71495E+00 -0.1457 19 Ca(HSiO3)+ 0.17395E-16 -16.7596 0.12510E-16 -16.9027 0.71920E+00 -0.1432 21 NaHSiO3,aq 0.22493E-11 -11.6479 0.22493E-11 -11.6479 0.10000E+01 0.0000 22 AlO+ 0.76967E-11 -11.1137 0.55354E-11 -11.2568 0.71920E+00 -0.1432 23 AlOH+2 0.71805E-08 -8.1438 0.20024E-08 -8.6985 0.27886E+00 -0.5546 24 HAlO2,aq 0.15117E-13 -13.8205 0.15117E-13 -13.8205 0.10000E+01 0.0000 25 AlO2- 0.64772E-18 -18.1886 0.46061E-18 -18.3367 0.71113E+00 -0.1481 26 CH4,aq 0.88932E-07 -7.0509 0.83494E-07 -7.0783 0.93885E+00 -0.0274 27 C2H6,aq 0.12662E-15 -15.8975 0.11888E-15 -15.9249 0.93885E+00 -0.0274 31 CO,aq 0.96179E-10 -10.0169 0.96179E-10 -10.0169 0.10000E+01 0.0000 32 CO2,aq 0.40523E+00 -0.3923 0.38045E+00 -0.4197 0.93885E+00 -0.0274 33 CO3-2 0.10277E-13 -13.9881 0.29356E-14 -14.5323 0.28566E+00 -0.5442 34 CaCO3,aq 0.15412E-17 -17.8121 0.15412E-17 -17.8121 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.36284E-11 -11.4403 0.26095E-11 -11.5834 0.71920E+00 -0.1432 36 CaCl+ 0.77187E-08 -8.1125 0.55512E-08 -8.2556 0.71920E+00 -0.1432 37 CaCl2,aq 0.10805E-09 -9.9664 0.10805E-09 -9.9664 0.10000E+01 0.0000 38 CaF+ 0.13387E-10 -10.8733 0.96279E-11 -11.0165 0.71920E+00 -0.1432 39 CaOH+ 0.56897E-16 -16.2449 0.40920E-16 -16.3881 0.71920E+00 -0.1432 40 CaSO4,aq 0.95942E-16 -16.0180 0.95942E-16 -16.0180 0.10000E+01 0.0000 41 HCl,aq 0.10906E-02 -2.9623 0.10906E-02 -2.9623 0.10000E+01 0.0000 45 HF,aq 0.78324E-02 -2.1061 0.78324E-02 -2.1061 0.10000E+01 0.0000 46 HF2- 0.58253E-07 -7.2347 0.41648E-07 -7.3804 0.71495E+00 -0.1457 47 Fe+3 0.63284E-17 -17.1987 0.38284E-18 -18.4170 0.60496E-01 -1.2183 48 FeCl+ 0.11716E-08 -8.9312 0.84258E-09 -9.0744 0.71920E+00 -0.1432 49 FeCl2,aq 0.21855E-14 -14.6605 0.21855E-14 -14.6605 0.10000E+01 0.0000 50 FeCl+2 0.80362E-17 -17.0949 0.22410E-17 -17.6496 0.27886E+00 -0.5546 51 FeF+ 0.72713E-11 -11.1384 0.52295E-11 -11.2815 0.71920E+00 -0.1432 52 FeF+2 0.19271E-15 -15.7151 0.53738E-16 -16.2697 0.27886E+00 -0.5546 54 FeOH+ 0.40328E-14 -14.3944 0.29003E-14 -14.5376 0.71920E+00 -0.1432 56 FeO+ 0.96070E-19 -19.0174 0.69093E-19 -19.1606 0.71920E+00 -0.1432 57 FeOH+2 0.34374E-17 -17.4638 0.95855E-18 -18.0184 0.27886E+00 -0.5546 60 H2,aq 0.10678E-07 -7.9715 0.10025E-07 -7.9989 0.93885E+00 -0.0274 61 KCl,aq 0.11371E-06 -6.9442 0.11371E-06 -6.9442 0.10000E+01 0.0000 62 KHSO4,aq 0.11350E-15 -15.9450 0.11350E-15 -15.9450 0.10000E+01 0.0000 63 KOH,aq 0.44846E-15 -15.3483 0.44846E-15 -15.3483 0.10000E+01 0.0000 64 KSO4- 0.11994E-13 -13.9210 0.85750E-14 -14.0668 0.71495E+00 -0.1457 66 Mg(HCO3)+ 0.14774E-14 -14.8305 0.10625E-14 -14.9737 0.71920E+00 -0.1432 67 MgCl+ 0.27877E-11 -11.5548 0.20049E-11 -11.6979 0.71920E+00 -0.1432 68 MgF+ 0.19760E-13 -13.7042 0.14212E-13 -13.8474 0.71920E+00 -0.1432 69 MgOH+ 0.12546E-18 -18.9015 0.90229E-19 -19.0447 0.71920E+00 -0.1432 71 MnF+ 0.14593E-12 -12.8359 0.10495E-12 -12.9790 0.71920E+00 -0.1432 73 MnOH+ 0.22810E-16 -16.6419 0.16405E-16 -16.7850 0.71920E+00 -0.1432 78 MnCl+ 0.27751E-09 -9.5567 0.19959E-09 -9.6999 0.71920E+00 -0.1432 79 MnSO4,aq 0.82415E-18 -18.0840 0.82415E-18 -18.0840 0.10000E+01 0.0000 80 NaCl,aq 0.28781E-03 -3.5409 0.28781E-03 -3.5409 0.10000E+01 0.0000 81 NaF,aq 0.39087E-07 -7.4080 0.39087E-07 -7.4080 0.10000E+01 0.0000 82 NaOH,aq 0.62455E-13 -13.2044 0.62455E-13 -13.2044 0.10000E+01 0.0000 84 OH- 0.11141E-10 -10.9531 0.79229E-11 -11.1011 0.71113E+00 -0.1481 90 H3PO3,aq 0.29820E-19 -19.5255 0.29820E-19 -19.5255 0.10000E+01 0.0000 92 H3PO4,aq 0.29970E-07 -7.5233 0.29970E-07 -7.5233 0.10000E+01 0.0000 93 H2PO4- 0.15173E-08 -8.8189 0.10881E-08 -8.9633 0.71713E+00 -0.1444 95 H4P2O7,aq 0.11887E-16 -16.9249 0.11887E-16 -16.9249 0.10000E+01 0.0000 96 H3P2O7- 0.29220E-17 -17.5343 0.20891E-17 -17.6800 0.71495E+00 -0.1457 97 H2P2O7-2 0.32624E-18 -18.4865 0.93194E-19 -19.0306 0.28566E+00 -0.5442 100 H2S,aq 0.60984E-01 -1.2148 0.57254E-01 -1.2422 0.93885E+00 -0.0274 101 S2-2 0.50315E-15 -15.2983 0.14373E-15 -15.8425 0.28566E+00 -0.5442 102 S3-2 0.38715E-14 -14.4121 0.11059E-14 -14.9563 0.28566E+00 -0.5442 103 S3- 0.75231E-09 -9.1236 0.53786E-09 -9.2693 0.71495E+00 -0.1457 104 S4-2 0.19678E-13 -13.7060 0.56210E-14 -14.2502 0.28566E+00 -0.5442 105 S5-2 0.66691E-13 -13.1759 0.19051E-13 -13.7201 0.28566E+00 -0.5442 106 SO2,aq 0.17181E-11 -11.7650 0.17181E-11 -11.7650 0.10000E+01 0.0000 107 SO3-2 0.31524E-19 -19.5014 0.94365E-20 -20.0252 0.29935E+00 -0.5238 108 HSO3- 0.60035E-13 -13.2216 0.42922E-13 -13.3673 0.71495E+00 -0.1457 109 HSO4- 0.69998E-09 -9.1549 0.50519E-09 -9.2965 0.72173E+00 -0.1416 111 S2O3-2 0.17054E-13 -13.7682 0.48717E-14 -14.3123 0.28566E+00 -0.5442 112 HS2O3- 0.88509E-13 -13.0530 0.63280E-13 -13.1987 0.71495E+00 -0.1457 113 H2S2O3,aq 0.73697E-13 -13.1326 0.73697E-13 -13.1326 0.10000E+01 0.0000 Charge balance for all species = -.4160E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9965422E-01 0.5747956E+00 0.5653774E+03 0.0000 2 H2O 0.1000000E+01 0.5510302E+02 0.9687399E+06 0.0000 3 Cl- 0.1145884E+00 0.1159669E+00 0.4012153E+04 0.0522 4 SO4-- 0.2508679E-10 -.9042914E-07 -.8477124E-02 -8.8641 5 HCO3- 0.3398913E-05 0.4052381E+00 0.2412975E+05 -4.4735 6 HS- 0.3565071E-06 0.6098400E-01 0.1968189E+04 -5.4547 7 Al+++ 0.3599630E-05 0.3606819E-05 0.9496875E-01 -3.2501 8 H4SiO4 0.1016823E-02 0.1016823E-02 0.9537367E+02 -2.9928 9 Ca++ 0.1493215E-06 0.1571653E-06 0.6146854E-02 -5.1005 10 Mg++ 0.6039698E-10 0.6320590E-10 0.1499576E-05 -8.5001 11 Fe++ 0.2343807E-07 0.2461691E-07 0.1341602E-02 -5.9097 12 K+ 0.1065567E-03 0.1066704E-03 0.4070365E+01 -2.9771 13 Na+ 0.1484242E-01 0.1513026E-01 0.3394470E+03 -0.8359 14 Mn++ 0.1423226E-08 0.1700887E-08 0.9118821E-04 -7.1251 15 F- 0.2216120E-04 0.7854765E-02 0.1456235E+03 -3.6639 16 HPO4-- 0.2821519E-14 0.3148705E-07 0.2949161E-02 -12.8129 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.2779522E+01 0.7610173E+00 0.6206929E+00 0.1397812E+01 2 H2O 0.7113260E+02 0.7295524E+02 -.5181679E+00 -.1304467E+01 3 Cl- 0.1535378E+00 0.1535378E+00 0.0000000E+00 0.5529270E-07 4 SO4-- 0.1241350E+00 -.1197263E-06 0.1241386E+00 -.3496429E-05 5 HCO3- 0.1879812E+01 0.5365268E+00 0.0000000E+00 0.1343286E+01 6 HS- 0.5076903E+00 0.8074154E-01 0.3724158E+00 0.5453301E-01 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1346252E-02 0.1080677E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1040010E-01 0.1039954E-01 0.0000000E+00 0.5525669E-06 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1002E-15 Mass of aqueous solution: 0.135672E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 25.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.3881E-01 -1.411 0.6990 -0.156 1.133 15.42 CO2,gas 1.343 0.128 59.12 1.772 95.85 723.5 CH4,gas 0.3403E-05 -5.468 0.5459E-04 -4.263 0.8851E-04 0.2197E-02 H2,gas 0.3682E-06 -6.434 0.7438E-06 -6.129 0.1206E-05 0.2346E-03 H2S,gas 0.5453E-01 -1.263 1.858 0.269 3.013 27.76 S2,gas 0.1542E-10 -10.812 0.9889E-09 -9.005 0.1603E-08 0.9569E-08 CO,gas 0.4118E-08 -8.385 0.1153E-06 -6.938 0.1870E-06 0.2555E-05 SO3,gas 0.4153E-30 -30.382 0.3325E-28 -28.478 0.5391E-28 0.2577E-27 SO2,gas 0.2135E-12 -12.671 0.1367E-10 -10.864 0.2217E-10 0.1325E-09 HF,gas 0.5526E-06 -6.258 0.1105E-04 -4.957 0.1792E-04 0.3429E-03 HCl,gas 0.5529E-07 -7.257 0.2016E-05 -5.696 0.3269E-05 0.3431E-04 quartz 0.1081E-01 -1.966 0.6493 -0.188 3.919 0.2452 sulfur 0.4966 -0.304 15.92 1.202 96.08 7.702 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2702E-01 0.1351E+01 0.7419 0.001 CO2,gas 0.9350E+00 0.4675E+02 0.8707 1.610 CH4,gas 0.2369E-05 0.1184E-03 1.0376 -3.910 H2,gas 0.2563E-06 0.1282E-04 1.0270 -4.881 H2S,gas 0.3796E-01 0.1898E+01 0.8293 0.197 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.2866E-08 0.1433E-06 1.0000 -6.844 SO3,gas 0.2891E-30 0.1445E-28 1.0000 -28.840 SO2,gas 0.1486E-12 0.7430E-11 1.0000 -11.129 HF,gas 0.3846E-06 0.1923E-04 1.0000 -4.716 HCl,gas 0.3849E-07 0.1924E-05 1.0000 -5.716 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 4.298031 % Solid products produced: Mass = 16.568803 g Volume = 7.946950 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 25.9999900 moles log = 1.4150 Original solution: 1000.0103000 g Original solution / Rock added: 38.46 (Water/Rock Ratio), log = 1.5850 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 -0.37914E-12 2 CO2,gas -6.66 -6.66 0.00 0.000 0.00000E+00 3 CH4,gas 4.54 4.54 0.00 0.000 -0.30331E-11 4 H2,gas 8.00 8.00 0.00 0.000 -0.15165E-11 5 H2S,gas -6.23 -6.23 0.00 0.000 -0.15165E-11 6 S2,gas -7.34 -7.34 0.00 0.000 0.00000E+00 7 CO,gas 3.21 3.21 0.00 0.000 -0.22748E-11 8 SO3,gas 17.12 17.12 0.00 0.000 0.00000E+00 9 SO2,gas 0.83 0.83 0.00 0.000 -0.37914E-12 10 HF,gas 0.47 0.47 0.00 0.000 0.37914E-12 11 HCl,gas 5.19 5.19 0.00 0.000 0.00000E+00 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 172 sulfur -9.15 -9.15 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.91 -0.80 -0.230 0.13720E+04 89 graphite -3.55 -3.91 -0.36 -0.103 0.61428E+03 92 halite 1.57 -3.06 -4.64 -2.318 0.79155E+04 145 pyrite -21.25 -22.79 -1.55 -0.364 0.26420E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 214 topaz -16.55 -21.38 -4.83 -0.537 0.82466E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 25.9999900 MOLES New total amount of reactant added: 26.9999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 21 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 26.9999900 Water: Moles liquid = 0.7440E+02 kg liquid = 0.1340E+01 Moles total = 0.7195E+02 kg total = 0.1296E+01 Activity = 0.9961 Stoichiometric ionic strength = .3066890E+00 Osmotic coef. = 0.9148 True ionic strength = .1175518E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1594E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10277E+00 -0.9881 0.74751E-01 -1.1264 0.72737E+00 -0.1382 2 H2O 0.99609E+00 -0.0017 0.99609E+00 -0.0017 3 Cl- 0.11752E+00 -0.9299 0.83810E-01 -1.0767 0.71319E+00 -0.1468 4 SO4-- 0.23175E-10 -10.6350 0.65985E-11 -11.1806 0.28473E+00 -0.5456 5 HCO3- 0.33094E-05 -5.4802 0.23716E-05 -5.6250 0.71661E+00 -0.1447 6 HS- 0.35104E-06 -6.4546 0.25048E-06 -6.6012 0.71352E+00 -0.1466 7 Al+++ 0.35560E-05 -5.4490 0.20800E-06 -6.6819 0.58492E-01 -1.2329 8 H4SiO4 0.10166E-02 -2.9928 0.10166E-02 -2.9928 0.10000E+01 0.0000 9 Ca++ 0.14739E-06 -6.8315 0.40895E-07 -7.3883 0.27746E+00 -0.5568 10 Mg++ 0.59622E-10 -10.2246 0.16294E-10 -10.7880 0.27329E+00 -0.5634 11 Fe++ 0.23136E-07 -7.6357 0.63457E-08 -8.1975 0.27428E+00 -0.5618 12 K+ 0.10525E-03 -3.9778 0.75461E-04 -4.1223 0.71695E+00 -0.1445 13 Na+ 0.14656E-01 -1.8340 0.10441E-01 -1.9813 0.71243E+00 -0.1473 14 Mn++ 0.14025E-08 -8.8531 0.38573E-09 -9.4137 0.27502E+00 -0.5606 15 F- 0.22150E-04 -4.6546 0.15702E-04 -4.8041 0.70888E+00 -0.1494 16 HPO4-- 0.26625E-14 -14.5747 0.75845E-15 -15.1201 0.28486E+00 -0.5454 17 SiF6-2 0.54285E-11 -11.2653 0.15348E-11 -11.8139 0.28274E+00 -0.5486 18 HSiO3- 0.17876E-10 -10.7477 0.12749E-10 -10.8945 0.71319E+00 -0.1468 19 Ca(HSiO3)+ 0.16549E-16 -16.7812 0.11873E-16 -16.9254 0.71747E+00 -0.1442 21 NaHSiO3,aq 0.21529E-11 -11.6670 0.21529E-11 -11.6670 0.10000E+01 0.0000 22 AlO+ 0.70306E-11 -11.1530 0.50443E-11 -11.2972 0.71747E+00 -0.1442 23 AlOH+2 0.68049E-08 -8.1672 0.18775E-08 -8.7264 0.27591E+00 -0.5592 24 HAlO2,aq 0.13386E-13 -13.8733 0.13386E-13 -13.8733 0.10000E+01 0.0000 25 AlO2- 0.55883E-18 -18.2527 0.39640E-18 -18.4019 0.70933E+00 -0.1491 26 CH4,aq 0.92800E-07 -7.0325 0.87105E-07 -7.0600 0.93863E+00 -0.0275 27 C2H6,aq 0.13639E-15 -15.8652 0.12802E-15 -15.8927 0.93863E+00 -0.0275 31 CO,aq 0.97175E-10 -10.0124 0.97175E-10 -10.0124 0.10000E+01 0.0000 32 CO2,aq 0.40515E+00 -0.3924 0.38029E+00 -0.4199 0.93863E+00 -0.0275 33 CO3-2 0.98011E-14 -14.0087 0.27712E-14 -14.5573 0.28274E+00 -0.5486 34 CaCO3,aq 0.14210E-17 -17.8474 0.14210E-17 -17.8474 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.34505E-11 -11.4621 0.24756E-11 -11.6063 0.71747E+00 -0.1442 36 CaCl+ 0.77308E-08 -8.1118 0.55466E-08 -8.2560 0.71747E+00 -0.1442 37 CaCl2,aq 0.11044E-09 -9.9569 0.11044E-09 -9.9569 0.10000E+01 0.0000 38 CaF+ 0.13067E-10 -10.8838 0.93750E-11 -11.0280 0.71747E+00 -0.1442 39 CaOH+ 0.54131E-16 -16.2666 0.38837E-16 -16.4107 0.71747E+00 -0.1442 40 CaSO4,aq 0.85688E-16 -16.0671 0.85688E-16 -16.0671 0.10000E+01 0.0000 41 HCl,aq 0.11480E-02 -2.9401 0.11480E-02 -2.9401 0.10000E+01 0.0000 45 HF,aq 0.80350E-02 -2.0950 0.80350E-02 -2.0950 0.10000E+01 0.0000 46 HF2- 0.59726E-07 -7.2238 0.42596E-07 -7.3706 0.71319E+00 -0.1468 47 Fe+3 0.64751E-17 -17.1888 0.38267E-18 -18.4172 0.59099E-01 -1.2284 48 FeCl+ 0.11733E-08 -8.9306 0.84180E-09 -9.0748 0.71747E+00 -0.1442 49 FeCl2,aq 0.22337E-14 -14.6510 0.22337E-14 -14.6510 0.10000E+01 0.0000 50 FeCl+2 0.83053E-17 -17.0806 0.22915E-17 -17.6399 0.27591E+00 -0.5592 51 FeF+ 0.70967E-11 -11.1489 0.50917E-11 -11.2931 0.71747E+00 -0.1442 52 FeF+2 0.19409E-15 -15.7120 0.53552E-16 -16.2712 0.27591E+00 -0.5592 54 FeOH+ 0.38363E-14 -14.4161 0.27525E-14 -14.5603 0.71747E+00 -0.1442 56 FeO+ 0.90905E-19 -19.0414 0.65222E-19 -19.1856 0.71747E+00 -0.1442 57 FeOH+2 0.33745E-17 -17.4718 0.93106E-18 -18.0310 0.27591E+00 -0.5592 60 H2,aq 0.10795E-07 -7.9668 0.10132E-07 -7.9943 0.93863E+00 -0.0275 61 KCl,aq 0.11463E-06 -6.9407 0.11463E-06 -6.9407 0.10000E+01 0.0000 62 KHSO4,aq 0.10524E-15 -15.9778 0.10524E-15 -15.9778 0.10000E+01 0.0000 63 KOH,aq 0.42943E-15 -15.3671 0.42943E-15 -15.3671 0.10000E+01 0.0000 64 KSO4- 0.10834E-13 -13.9652 0.77267E-14 -14.1120 0.71319E+00 -0.1468 66 Mg(HCO3)+ 0.14048E-14 -14.8524 0.10079E-14 -14.9966 0.71747E+00 -0.1442 67 MgCl+ 0.27918E-11 -11.5541 0.20030E-11 -11.6983 0.71747E+00 -0.1442 68 MgF+ 0.19286E-13 -13.7148 0.13837E-13 -13.8590 0.71747E+00 -0.1442 69 MgOH+ 0.11935E-18 -18.9232 0.85629E-19 -19.0674 0.71747E+00 -0.1442 71 MnF+ 0.14219E-12 -12.8471 0.10201E-12 -12.9913 0.71747E+00 -0.1442 73 MnOH+ 0.21663E-16 -16.6643 0.15543E-16 -16.8085 0.71747E+00 -0.1442 78 MnCl+ 0.27747E-09 -9.5568 0.19907E-09 -9.7010 0.71747E+00 -0.1442 79 MnSO4,aq 0.73479E-18 -18.1338 0.73479E-18 -18.1338 0.10000E+01 0.0000 80 NaCl,aq 0.29000E-03 -3.5376 0.29000E-03 -3.5376 0.10000E+01 0.0000 81 NaF,aq 0.38382E-07 -7.4159 0.38382E-07 -7.4159 0.10000E+01 0.0000 82 NaOH,aq 0.59777E-13 -13.2235 0.59777E-13 -13.2235 0.10000E+01 0.0000 84 OH- 0.10854E-10 -10.9644 0.76990E-11 -11.1136 0.70933E+00 -0.1491 90 H3PO3,aq 0.29811E-19 -19.5256 0.29811E-19 -19.5256 0.10000E+01 0.0000 92 H3PO4,aq 0.29641E-07 -7.5281 0.29641E-07 -7.5281 0.10000E+01 0.0000 93 H2PO4- 0.14620E-08 -8.8351 0.10459E-08 -8.9805 0.71539E+00 -0.1455 95 H4P2O7,aq 0.11629E-16 -16.9345 0.11629E-16 -16.9345 0.10000E+01 0.0000 96 H3P2O7- 0.27849E-17 -17.5552 0.19861E-17 -17.7020 0.71319E+00 -0.1468 97 H2P2O7-2 0.30454E-18 -18.5164 0.86106E-19 -19.0650 0.28274E+00 -0.5486 100 H2S,aq 0.61650E-01 -1.2101 0.57867E-01 -1.2376 0.93863E+00 -0.0275 101 S2-2 0.48525E-15 -15.3140 0.13720E-15 -15.8626 0.28274E+00 -0.5486 102 S3-2 0.37337E-14 -14.4279 0.10557E-14 -14.9765 0.28274E+00 -0.5486 103 S3- 0.73685E-09 -9.1326 0.52551E-09 -9.2794 0.71319E+00 -0.1468 104 S4-2 0.18978E-13 -13.7218 0.53657E-14 -14.2704 0.28274E+00 -0.5486 105 S5-2 0.64319E-13 -13.1917 0.18186E-13 -13.7403 0.28274E+00 -0.5486 106 SO2,aq 0.16815E-11 -11.7743 0.16815E-11 -11.7743 0.10000E+01 0.0000 107 SO3-2 0.29419E-19 -19.5314 0.87223E-20 -20.0594 0.29648E+00 -0.5280 108 HSO3- 0.57241E-13 -13.2423 0.40823E-13 -13.3891 0.71319E+00 -0.1468 109 HSO4- 0.66018E-09 -9.1803 0.47535E-09 -9.3230 0.72004E+00 -0.1426 111 S2O3-2 0.15926E-13 -13.7979 0.45030E-14 -14.3465 0.28274E+00 -0.5486 112 HS2O3- 0.84389E-13 -13.0737 0.60185E-13 -13.2205 0.71319E+00 -0.1468 113 H2S2O3,aq 0.72123E-13 -13.1419 0.72123E-13 -13.1419 0.10000E+01 0.0000 Charge balance for all species = -.4109E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1027691E+00 0.5787554E+00 0.5692013E+03 0.0000 2 H2O 0.1000000E+01 0.5510310E+02 0.9686204E+06 0.0000 3 Cl- 0.1175151E+00 0.1189533E+00 0.4114958E+04 0.0497 4 SO4-- 0.2317472E-10 -.9437751E-07 -.8846153E-02 -8.9278 5 HCO3- 0.3309429E-05 0.4051563E+00 0.2412187E+05 -4.4986 6 HS- 0.3510410E-06 0.6165072E-01 0.1989458E+04 -5.4749 7 Al+++ 0.3555980E-05 0.3562792E-05 0.9379781E-01 -3.3028 8 H4SiO4 0.1016622E-02 0.1016622E-02 0.9534299E+02 -2.9928 9 Ca++ 0.1473891E-06 0.1552468E-06 0.6071066E-02 -5.1356 10 Mg++ 0.5962188E-10 0.6243438E-10 0.1481087E-05 -8.5352 11 Fe++ 0.2313603E-07 0.2431643E-07 0.1325060E-02 -5.9448 12 K+ 0.1052537E-03 0.1053684E-03 0.4020178E+01 -2.9959 13 Na+ 0.1465554E-01 0.1494558E-01 0.3352617E+03 -0.8549 14 Mn++ 0.1402517E-08 0.1680126E-08 0.9006389E-04 -7.1610 15 F- 0.2215002E-04 0.8057287E-02 0.1493595E+03 -3.6777 16 HPO4-- 0.2662527E-14 0.3110270E-07 0.2912799E-02 -12.8673 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.2887197E+01 0.7757288E+00 0.6445696E+00 0.1466899E+01 2 H2O 0.7195130E+02 0.7385687E+02 -.5372365E+00 -.1368332E+01 3 Cl- 0.1594378E+00 0.1594378E+00 0.0000000E+00 0.6108034E-07 4 SO4-- 0.1289100E+00 -.1264979E-06 0.1289139E+00 -.3824731E-05 5 HCO3- 0.1952112E+01 0.5430470E+00 0.0000000E+00 0.1409065E+01 6 HS- 0.5272153E+00 0.8263291E-01 0.3867418E+00 0.5784063E-01 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1362619E-02 0.1079040E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1080010E-01 0.1079950E-01 0.0000000E+00 0.5948704E-06 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1028E-15 Mass of aqueous solution: 0.137366E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 26.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.4073E-01 -1.390 0.7335 -0.135 1.133 16.18 CO2,gas 1.409 0.149 62.01 1.792 95.82 758.9 CH4,gas 0.3726E-05 -5.429 0.5977E-04 -4.224 0.9235E-04 0.2406E-02 H2,gas 0.3906E-06 -6.408 0.7889E-06 -6.103 0.1219E-05 0.2488E-03 H2S,gas 0.5784E-01 -1.238 1.971 0.295 3.046 29.44 S2,gas 0.1618E-10 -10.791 0.1038E-08 -8.984 0.1604E-08 0.1004E-07 CO,gas 0.4366E-08 -8.360 0.1223E-06 -6.913 0.1890E-06 0.2709E-05 SO3,gas 0.4220E-30 -30.375 0.3379E-28 -28.471 0.5221E-28 0.2619E-27 SO2,gas 0.2193E-12 -12.659 0.1405E-10 -10.852 0.2170E-10 0.1361E-09 HF,gas 0.5949E-06 -6.226 0.1190E-04 -4.925 0.1838E-04 0.3691E-03 HCl,gas 0.6108E-07 -7.214 0.2227E-05 -5.652 0.3441E-05 0.3790E-04 quartz 0.1079E-01 -1.967 0.6483 -0.188 3.773 0.2448 sulfur 0.5157 -0.288 16.53 1.218 96.23 7.998 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2701E-01 0.1351E+01 0.7419 0.001 CO2,gas 0.9346E+00 0.4673E+02 0.8707 1.609 CH4,gas 0.2471E-05 0.1236E-03 1.0376 -3.892 H2,gas 0.2591E-06 0.1295E-04 1.0270 -4.876 H2S,gas 0.3836E-01 0.1918E+01 0.8293 0.202 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.2896E-08 0.1448E-06 1.0000 -6.839 SO3,gas 0.2799E-30 0.1400E-28 1.0000 -28.854 SO2,gas 0.1454E-12 0.7272E-11 1.0000 -11.138 HF,gas 0.3946E-06 0.1973E-04 1.0000 -4.705 HCl,gas 0.4051E-07 0.2026E-05 1.0000 -5.693 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 4.446233 % Solid products produced: Mass = 17.180208 g Volume = 8.242848 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 26.9999900 moles log = 1.4314 Original solution: 1000.0103000 g Original solution / Rock added: 37.04 (Water/Rock Ratio), log = 1.5686 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 0.00000E+00 2 CO2,gas -6.66 -6.66 0.00 0.000 -0.15165E-11 3 CH4,gas 4.54 4.54 0.00 0.000 -0.15165E-11 4 H2,gas 8.00 8.00 0.00 0.000 0.00000E+00 5 H2S,gas -6.23 -6.23 0.00 0.000 0.15165E-11 6 S2,gas -7.34 -7.34 0.00 0.000 0.00000E+00 7 CO,gas 3.21 3.21 0.00 0.000 -0.75827E-12 8 SO3,gas 17.12 17.12 0.00 0.000 0.00000E+00 9 SO2,gas 0.83 0.83 0.00 0.000 0.26539E-11 10 HF,gas 0.47 0.47 0.00 0.000 0.37914E-12 11 HCl,gas 5.19 5.19 0.00 0.000 0.00000E+00 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 172 sulfur -9.15 -9.15 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.90 -0.79 -0.227 0.13564E+04 89 graphite -3.55 -3.90 -0.35 -0.100 0.59867E+03 92 halite 1.57 -3.06 -4.63 -2.316 0.79099E+04 145 pyrite -21.25 -22.82 -1.58 -0.371 0.26940E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 214 topaz -16.55 -21.46 -4.91 -0.546 0.83889E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 26.9999900 MOLES New total amount of reactant added: 27.9999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 21 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 27.9999900 Water: Moles liquid = 0.7531E+02 kg liquid = 0.1357E+01 Moles total = 0.7277E+02 kg total = 0.1311E+01 Activity = 0.9960 Stoichiometric ionic strength = .3084447E+00 Osmotic coef. = 0.9148 True ionic strength = .1204067E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1653E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10581E+00 -0.9755 0.76799E-01 -1.1146 0.72583E+00 -0.1392 2 H2O 0.99599E+00 -0.0017 0.99599E+00 -0.0017 3 Cl- 0.12037E+00 -0.9195 0.85644E-01 -1.0673 0.71151E+00 -0.1478 4 SO4-- 0.21507E-10 -10.6674 0.60646E-11 -11.2172 0.28198E+00 -0.5498 5 HCO3- 0.32270E-05 -5.4912 0.23072E-05 -5.6369 0.71497E+00 -0.1457 6 HS- 0.34592E-06 -6.4610 0.24624E-06 -6.6086 0.71185E+00 -0.1476 7 Al+++ 0.35134E-05 -5.4543 0.20094E-06 -6.6969 0.57193E-01 -1.2427 8 H4SiO4 0.10164E-02 -2.9929 0.10164E-02 -2.9929 0.10000E+01 0.0000 9 Ca++ 0.14551E-06 -6.8371 0.39968E-07 -7.3983 0.27468E+00 -0.5612 10 Mg++ 0.58867E-10 -10.2301 0.15924E-10 -10.7980 0.27050E+00 -0.5678 11 Fe++ 0.22842E-07 -7.6413 0.62012E-08 -8.2075 0.27148E+00 -0.5663 12 K+ 0.10398E-03 -3.9830 0.74378E-04 -4.1286 0.71530E+00 -0.1455 13 Na+ 0.14473E-01 -1.8394 0.10287E-01 -1.9877 0.71073E+00 -0.1483 14 Mn++ 0.13824E-08 -8.8594 0.37635E-09 -9.4244 0.27223E+00 -0.5651 15 F- 0.22143E-04 -4.6548 0.15659E-04 -4.8052 0.70718E+00 -0.1505 16 HPO4-- 0.25192E-14 -14.5987 0.71070E-15 -15.1483 0.28211E+00 -0.5496 17 SiF6-2 0.60099E-11 -11.2211 0.16827E-11 -11.7740 0.27998E+00 -0.5529 18 HSiO3- 0.17439E-10 -10.7585 0.12408E-10 -10.9063 0.71151E+00 -0.1478 19 Ca(HSiO3)+ 0.15777E-16 -16.8020 0.11294E-16 -16.9472 0.71583E+00 -0.1452 21 NaHSiO3,aq 0.20643E-11 -11.6852 0.20643E-11 -11.6852 0.10000E+01 0.0000 22 AlO+ 0.64489E-11 -11.1905 0.46163E-11 -11.3357 0.71583E+00 -0.1452 23 AlOH+2 0.64634E-08 -8.1895 0.17653E-08 -8.7532 0.27312E+00 -0.5636 24 HAlO2,aq 0.11922E-13 -13.9236 0.11922E-13 -13.9236 0.10000E+01 0.0000 25 AlO2- 0.48563E-18 -18.3137 0.34364E-18 -18.4639 0.70763E+00 -0.1502 26 CH4,aq 0.96581E-07 -7.0151 0.90634E-07 -7.0427 0.93842E+00 -0.0276 27 C2H6,aq 0.14623E-15 -15.8350 0.13722E-15 -15.8626 0.93842E+00 -0.0276 31 CO,aq 0.98120E-10 -10.0082 0.98120E-10 -10.0082 0.10000E+01 0.0000 32 CO2,aq 0.40508E+00 -0.3925 0.38013E+00 -0.4201 0.93842E+00 -0.0276 33 CO3-2 0.93721E-14 -14.0282 0.26240E-14 -14.5810 0.27998E+00 -0.5529 34 CaCO3,aq 0.13150E-17 -17.8811 0.13150E-17 -17.8811 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.32882E-11 -11.4830 0.23538E-11 -11.6282 0.71583E+00 -0.1452 36 CaCl+ 0.77386E-08 -8.1113 0.55395E-08 -8.2565 0.71583E+00 -0.1452 37 CaCl2,aq 0.11271E-09 -9.9480 0.11271E-09 -9.9480 0.10000E+01 0.0000 38 CaF+ 0.12765E-10 -10.8940 0.91375E-11 -11.0392 0.71583E+00 -0.1452 39 CaOH+ 0.51606E-16 -16.2873 0.36941E-16 -16.4325 0.71583E+00 -0.1452 40 CaSO4,aq 0.76969E-16 -16.1137 0.76969E-16 -16.1137 0.10000E+01 0.0000 41 HCl,aq 0.12053E-02 -2.9189 0.12053E-02 -2.9189 0.10000E+01 0.0000 45 HF,aq 0.82326E-02 -2.0845 0.82326E-02 -2.0845 0.10000E+01 0.0000 46 HF2- 0.61173E-07 -7.2134 0.43525E-07 -7.3613 0.71151E+00 -0.1478 47 Fe+3 0.66148E-17 -17.1795 0.38229E-18 -18.4176 0.57794E-01 -1.2381 48 FeCl+ 0.11744E-08 -8.9302 0.84064E-09 -9.0754 0.71583E+00 -0.1452 49 FeCl2,aq 0.22794E-14 -14.6422 0.22794E-14 -14.6422 0.10000E+01 0.0000 50 FeCl+2 0.85652E-17 -17.0673 0.23394E-17 -17.6309 0.27312E+00 -0.5636 51 FeF+ 0.69321E-11 -11.1591 0.49622E-11 -11.3043 0.71583E+00 -0.1452 52 FeF+2 0.19535E-15 -15.7092 0.53353E-16 -16.2728 0.27312E+00 -0.5636 54 FeOH+ 0.36571E-14 -14.4369 0.26178E-14 -14.5821 0.71583E+00 -0.1452 56 FeO+ 0.86226E-19 -19.0644 0.61723E-19 -19.2096 0.71583E+00 -0.1452 57 FeOH+2 0.33144E-17 -17.4796 0.90525E-18 -18.0432 0.27312E+00 -0.5636 60 H2,aq 0.10905E-07 -7.9624 0.10234E-07 -7.9900 0.93842E+00 -0.0276 61 KCl,aq 0.11545E-06 -6.9376 0.11545E-06 -6.9376 0.10000E+01 0.0000 62 KHSO4,aq 0.97946E-16 -16.0090 0.97946E-16 -16.0090 0.10000E+01 0.0000 63 KOH,aq 0.41194E-15 -15.3852 0.41194E-15 -15.3852 0.10000E+01 0.0000 64 KSO4- 0.98376E-14 -14.0071 0.69996E-14 -14.1549 0.71151E+00 -0.1478 66 Mg(HCO3)+ 0.13386E-14 -14.8733 0.95824E-15 -15.0185 0.71583E+00 -0.1452 67 MgCl+ 0.27944E-11 -11.5537 0.20003E-11 -11.6989 0.71583E+00 -0.1452 68 MgF+ 0.18839E-13 -13.7249 0.13485E-13 -13.8701 0.71583E+00 -0.1452 69 MgOH+ 0.11377E-18 -18.9440 0.81441E-19 -19.0892 0.71583E+00 -0.1452 71 MnF+ 0.13867E-12 -12.8580 0.99264E-13 -13.0032 0.71583E+00 -0.1452 73 MnOH+ 0.20618E-16 -16.6858 0.14759E-16 -16.8309 0.71583E+00 -0.1452 78 MnCl+ 0.27728E-09 -9.5571 0.19848E-09 -9.7023 0.71583E+00 -0.1452 79 MnSO4,aq 0.65891E-18 -18.1812 0.65891E-18 -18.1812 0.10000E+01 0.0000 80 NaCl,aq 0.29196E-03 -3.5347 0.29196E-03 -3.5347 0.10000E+01 0.0000 81 NaF,aq 0.37712E-07 -7.4235 0.37712E-07 -7.4235 0.10000E+01 0.0000 82 NaOH,aq 0.57318E-13 -13.2417 0.57318E-13 -13.2417 0.10000E+01 0.0000 84 OH- 0.10589E-10 -10.9751 0.74930E-11 -11.1253 0.70763E+00 -0.1502 90 H3PO3,aq 0.29784E-19 -19.5260 0.29784E-19 -19.5260 0.10000E+01 0.0000 92 H3PO4,aq 0.29317E-07 -7.5329 0.29317E-07 -7.5329 0.10000E+01 0.0000 93 H2PO4- 0.14107E-08 -8.8506 0.10069E-08 -8.9970 0.71373E+00 -0.1465 95 H4P2O7,aq 0.11377E-16 -16.9440 0.11377E-16 -16.9440 0.10000E+01 0.0000 96 H3P2O7- 0.26582E-17 -17.5754 0.18914E-17 -17.7232 0.71151E+00 -0.1478 97 H2P2O7-2 0.28506E-18 -18.5451 0.79811E-19 -19.0979 0.27998E+00 -0.5529 100 H2S,aq 0.62283E-01 -1.2056 0.58447E-01 -1.2332 0.93842E+00 -0.0276 101 S2-2 0.46891E-15 -15.3289 0.13129E-15 -15.8818 0.27998E+00 -0.5529 102 S3-2 0.36080E-14 -14.4427 0.10102E-14 -14.9956 0.27998E+00 -0.5529 103 S3- 0.72249E-09 -9.1412 0.51406E-09 -9.2890 0.71151E+00 -0.1478 104 S4-2 0.18338E-13 -13.7366 0.51344E-14 -14.2895 0.27998E+00 -0.5529 105 S5-2 0.62152E-13 -13.2065 0.17402E-13 -13.7594 0.27998E+00 -0.5529 106 SO2,aq 0.16480E-11 -11.7830 0.16480E-11 -11.7830 0.10000E+01 0.0000 107 SO3-2 0.27565E-19 -19.5596 0.80977E-20 -20.0916 0.29377E+00 -0.5320 108 HSO3- 0.54726E-13 -13.2618 0.38938E-13 -13.4096 0.71151E+00 -0.1478 109 HSO4- 0.62477E-09 -9.2043 0.44885E-09 -9.3479 0.71843E+00 -0.1436 111 S2O3-2 0.14931E-13 -13.8259 0.41805E-14 -14.3788 0.27998E+00 -0.5529 112 HS2O3- 0.80682E-13 -13.0932 0.57406E-13 -13.2410 0.71151E+00 -0.1478 113 H2S2O3,aq 0.70677E-13 -13.1507 0.70677E-13 -13.1507 0.10000E+01 0.0000 Charge balance for all species = -.4060E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1058077E+00 0.5826055E+00 0.5729182E+03 0.0000 2 H2O 0.1000000E+01 0.5510317E+02 0.9685042E+06 0.0000 3 Cl- 0.1203702E+00 0.1218676E+00 0.4215261E+04 0.0473 4 SO4-- 0.2150744E-10 -.9823231E-07 -.9206352E-02 -8.9879 5 HCO3- 0.3226972E-05 0.4050805E+00 0.2411443E+05 -4.5223 6 HS- 0.3459214E-06 0.6228304E-01 0.2009619E+04 -5.4940 7 Al+++ 0.3513358E-05 0.3519828E-05 0.9265544E-01 -3.3530 8 H4SiO4 0.1016427E-02 0.1016427E-02 0.9531311E+02 -2.9929 9 Ca++ 0.1455073E-06 0.1533747E-06 0.5997126E-02 -5.1690 10 Mg++ 0.5886691E-10 0.6168147E-10 0.1463049E-05 -8.5687 11 Fe++ 0.2284189E-07 0.2402319E-07 0.1308922E-02 -5.9782 12 K+ 0.1039823E-03 0.1040977E-03 0.3971216E+01 -3.0139 13 Na+ 0.1447334E-01 0.1476535E-01 0.3311786E+03 -0.8731 14 Mn++ 0.1382447E-08 0.1659865E-08 0.8896700E-04 -7.1951 15 F- 0.2214301E-04 0.8254923E-02 0.1530045E+03 -3.6906 16 HPO4-- 0.2519228E-14 0.3072763E-07 0.2877324E-02 -12.9190 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.2994872E+01 0.7904211E+00 0.6684463E+00 0.1536005E+01 2 H2O 0.7277000E+02 0.7475850E+02 -.5563051E+00 -.1432191E+01 3 Cl- 0.1653378E+00 0.1653378E+00 0.0000000E+00 0.6714771E-07 4 SO4-- 0.1336850E+00 -.1332718E-06 0.1336893E+00 -.4163986E-05 5 HCO3- 0.2024412E+01 0.5495728E+00 0.0000000E+00 0.1474840E+01 6 HS- 0.5467403E+00 0.8449943E-01 0.4010678E+00 0.6117307E-01 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1378987E-02 0.1077403E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1120010E-01 0.1119946E-01 0.0000000E+00 0.6382150E-06 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4389E-15 Mass of aqueous solution: 0.139059E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 27.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.4264E-01 -1.370 0.7679 -0.115 1.133 16.95 CO2,gas 1.475 0.169 64.91 1.812 95.79 794.3 CH4,gas 0.4060E-05 -5.392 0.6512E-04 -4.186 0.9610E-04 0.2621E-02 H2,gas 0.4131E-06 -6.384 0.8344E-06 -6.079 0.1231E-05 0.2631E-03 H2S,gas 0.6117E-01 -1.213 2.085 0.319 3.076 31.14 S2,gas 0.1695E-10 -10.771 0.1087E-08 -8.964 0.1604E-08 0.1052E-07 CO,gas 0.4617E-08 -8.336 0.1293E-06 -6.888 0.1908E-06 0.2865E-05 SO3,gas 0.4287E-30 -30.368 0.3433E-28 -28.464 0.5066E-28 0.2660E-27 SO2,gas 0.2250E-12 -12.648 0.1441E-10 -10.841 0.2127E-10 0.1396E-09 HF,gas 0.6382E-06 -6.195 0.1276E-04 -4.894 0.1884E-04 0.3960E-03 HCl,gas 0.6715E-07 -7.173 0.2448E-05 -5.611 0.3613E-05 0.4166E-04 quartz 0.1077E-01 -1.968 0.6473 -0.189 3.638 0.2445 sulfur 0.5348 -0.272 17.14 1.234 96.36 8.294 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2701E-01 0.1351E+01 0.7419 0.001 CO2,gas 0.9342E+00 0.4671E+02 0.8707 1.609 CH4,gas 0.2572E-05 0.1286E-03 1.0376 -3.875 H2,gas 0.2617E-06 0.1308E-04 1.0270 -4.872 H2S,gas 0.3875E-01 0.1937E+01 0.8293 0.206 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.2924E-08 0.1462E-06 1.0000 -6.835 SO3,gas 0.2716E-30 0.1358E-28 1.0000 -28.867 SO2,gas 0.1425E-12 0.7127E-11 1.0000 -11.147 HF,gas 0.4043E-06 0.2021E-04 1.0000 -4.694 HCl,gas 0.4253E-07 0.2127E-05 1.0000 -5.672 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 4.590342 % Solid products produced: Mass = 17.791615 g Volume = 8.538747 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 27.9999900 moles log = 1.4472 Original solution: 1000.0103000 g Original solution / Rock added: 35.71 (Water/Rock Ratio), log = 1.5528 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 0.00000E+00 2 CO2,gas -6.66 -6.66 0.00 0.000 0.15165E-11 3 CH4,gas 4.54 4.54 0.00 0.000 -0.15165E-11 4 H2,gas 8.00 8.00 0.00 0.000 -0.15165E-11 5 H2S,gas -6.23 -6.23 0.00 0.000 -0.15165E-11 6 S2,gas -7.34 -7.34 0.00 0.000 -0.60662E-11 7 CO,gas 3.21 3.21 0.00 0.000 0.22748E-11 8 SO3,gas 17.12 17.12 0.00 0.000 0.60662E-11 9 SO2,gas 0.83 0.83 0.00 0.000 -0.37914E-12 10 HF,gas 0.47 0.47 0.00 0.000 0.18957E-11 11 HCl,gas 5.19 5.19 0.00 0.000 0.00000E+00 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 172 sulfur -9.15 -9.15 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.89 -0.79 -0.225 0.13418E+04 89 graphite -3.55 -3.89 -0.34 -0.098 0.58402E+03 92 halite 1.57 -3.06 -4.63 -2.315 0.79049E+04 145 pyrite -21.25 -22.85 -1.61 -0.378 0.27438E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 214 topaz -16.55 -21.54 -4.99 -0.555 0.85244E+04 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 27.9999900 MOLES New total amount of reactant added: 28.9999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 21 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 28.9999900 Water: Moles liquid = 0.7622E+02 kg liquid = 0.1373E+01 Moles total = 0.7359E+02 kg total = 0.1326E+01 Activity = 0.9959 Stoichiometric ionic strength = .3101520E+00 Osmotic coef. = 0.9148 True ionic strength = .1231925E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1712E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10877E+00 -0.9635 0.78792E-01 -1.1035 0.72437E+00 -0.1400 2 H2O 0.99590E+00 -0.0018 0.99590E+00 -0.0018 3 Cl- 0.12316E+00 -0.9095 0.87430E-01 -1.0583 0.70991E+00 -0.1488 4 SO4-- 0.20044E-10 -10.6980 0.55997E-11 -11.2518 0.27937E+00 -0.5538 5 HCO3- 0.31507E-05 -5.5016 0.22477E-05 -5.6483 0.71340E+00 -0.1467 6 HS- 0.34111E-06 -6.4671 0.24228E-06 -6.6157 0.71025E+00 -0.1486 7 Al+++ 0.34717E-05 -5.4595 0.19434E-06 -6.7114 0.55977E-01 -1.2520 8 H4SiO4 0.10162E-02 -2.9930 0.10162E-02 -2.9930 0.10000E+01 0.0000 9 Ca++ 0.14367E-06 -6.8426 0.39085E-07 -7.4080 0.27204E+00 -0.5654 10 Mg++ 0.58131E-10 -10.2356 0.15571E-10 -10.8077 0.26785E+00 -0.5721 11 Fe++ 0.22555E-07 -7.6468 0.60637E-08 -8.2173 0.26884E+00 -0.5705 12 K+ 0.10274E-03 -3.9883 0.73329E-04 -4.1347 0.71373E+00 -0.1465 13 Na+ 0.14296E-01 -1.8448 0.10137E-01 -1.9941 0.70912E+00 -0.1493 14 Mn++ 0.13630E-08 -8.8655 0.36745E-09 -9.4348 0.26959E+00 -0.5693 15 F- 0.22140E-04 -4.6548 0.15621E-04 -4.8063 0.70555E+00 -0.1515 16 HPO4-- 0.23895E-14 -14.6217 0.66786E-15 -15.1753 0.27950E+00 -0.5536 17 SiF6-2 0.66241E-11 -11.1789 0.18373E-11 -11.7358 0.27737E+00 -0.5569 18 HSiO3- 0.17034E-10 -10.7687 0.12093E-10 -10.9175 0.70991E+00 -0.1488 19 Ca(HSiO3)+ 0.15070E-16 -16.8219 0.10764E-16 -16.9680 0.71426E+00 -0.1461 21 NaHSiO3,aq 0.19827E-11 -11.7027 0.19827E-11 -11.7027 0.10000E+01 0.0000 22 AlO+ 0.59378E-11 -11.2264 0.42412E-11 -11.3725 0.71426E+00 -0.1461 23 AlOH+2 0.61519E-08 -8.2110 0.16640E-08 -8.7789 0.27048E+00 -0.5679 24 HAlO2,aq 0.10676E-13 -13.9716 0.10676E-13 -13.9716 0.10000E+01 0.0000 25 AlO2- 0.42482E-18 -18.3718 0.29992E-18 -18.5230 0.70601E+00 -0.1512 26 CH4,aq 0.10028E-06 -6.9988 0.94080E-07 -7.0265 0.93822E+00 -0.0277 27 C2H6,aq 0.15612E-15 -15.8065 0.14648E-15 -15.8342 0.93822E+00 -0.0277 31 CO,aq 0.99015E-10 -10.0043 0.99015E-10 -10.0043 0.10000E+01 0.0000 32 CO2,aq 0.40501E+00 -0.3925 0.37999E+00 -0.4202 0.93822E+00 -0.0277 33 CO3-2 0.89836E-14 -14.0465 0.24918E-14 -14.6035 0.27737E+00 -0.5569 34 CaCO3,aq 0.12212E-17 -17.9132 0.12212E-17 -17.9132 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.31396E-11 -11.5031 0.22425E-11 -11.6493 0.71426E+00 -0.1461 36 CaCl+ 0.77424E-08 -8.1111 0.55301E-08 -8.2573 0.71426E+00 -0.1461 37 CaCl2,aq 0.11487E-09 -9.9398 0.11487E-09 -9.9398 0.10000E+01 0.0000 38 CaF+ 0.12480E-10 -10.9038 0.89138E-11 -11.0499 0.71426E+00 -0.1461 39 CaOH+ 0.49293E-16 -16.3072 0.35208E-16 -16.4534 0.71426E+00 -0.1461 40 CaSO4,aq 0.69499E-16 -16.1580 0.69499E-16 -16.1580 0.10000E+01 0.0000 41 HCl,aq 0.12623E-02 -2.8988 0.12623E-02 -2.8988 0.10000E+01 0.0000 45 HF,aq 0.84255E-02 -2.0744 0.84255E-02 -2.0744 0.10000E+01 0.0000 46 HF2- 0.62593E-07 -7.2035 0.44436E-07 -7.3523 0.70991E+00 -0.1488 47 Fe+3 0.67475E-17 -17.1709 0.38173E-18 -18.4182 0.56572E-01 -1.2474 48 FeCl+ 0.11748E-08 -8.9300 0.83914E-09 -9.0762 0.71426E+00 -0.1461 49 FeCl2,aq 0.23228E-14 -14.6340 0.23228E-14 -14.6340 0.10000E+01 0.0000 50 FeCl+2 0.88161E-17 -17.0547 0.23846E-17 -17.6226 0.27048E+00 -0.5679 51 FeF+ 0.67767E-11 -11.1690 0.48403E-11 -11.3151 0.71426E+00 -0.1461 52 FeF+2 0.19648E-15 -15.7067 0.53143E-16 -16.2746 0.27048E+00 -0.5679 54 FeOH+ 0.34929E-14 -14.4568 0.24948E-14 -14.6030 0.71426E+00 -0.1461 56 FeO+ 0.81969E-19 -19.0864 0.58547E-19 -19.2325 0.71426E+00 -0.1461 57 FeOH+2 0.32570E-17 -17.4872 0.88095E-18 -18.0550 0.27048E+00 -0.5679 60 H2,aq 0.11011E-07 -7.9582 0.10330E-07 -7.9859 0.93822E+00 -0.0277 61 KCl,aq 0.11620E-06 -6.9348 0.11620E-06 -6.9348 0.10000E+01 0.0000 62 KHSO4,aq 0.91476E-16 -16.0387 0.91476E-16 -16.0387 0.10000E+01 0.0000 63 KOH,aq 0.39582E-15 -15.4025 0.39582E-15 -15.4025 0.10000E+01 0.0000 64 KSO4- 0.89755E-14 -14.0469 0.63718E-14 -14.1957 0.70991E+00 -0.1488 66 Mg(HCO3)+ 0.12781E-14 -14.8935 0.91286E-15 -15.0396 0.71426E+00 -0.1461 67 MgCl+ 0.27955E-11 -11.5535 0.19967E-11 -11.6997 0.71426E+00 -0.1461 68 MgF+ 0.18417E-13 -13.7348 0.13154E-13 -13.8809 0.71426E+00 -0.1461 69 MgOH+ 0.10866E-18 -18.9639 0.77615E-19 -19.1101 0.71426E+00 -0.1461 71 MnF+ 0.13535E-12 -12.8685 0.96678E-13 -13.0147 0.71426E+00 -0.1461 73 MnOH+ 0.19662E-16 -16.7064 0.14044E-16 -16.8525 0.71426E+00 -0.1461 78 MnCl+ 0.27697E-09 -9.5576 0.19783E-09 -9.7037 0.71426E+00 -0.1461 79 MnSO4,aq 0.59401E-18 -18.2262 0.59401E-18 -18.2262 0.10000E+01 0.0000 80 NaCl,aq 0.29372E-03 -3.5321 0.29372E-03 -3.5321 0.10000E+01 0.0000 81 NaF,aq 0.37073E-07 -7.4309 0.37073E-07 -7.4309 0.10000E+01 0.0000 82 NaOH,aq 0.55051E-13 -13.2592 0.55051E-13 -13.2592 0.10000E+01 0.0000 84 OH- 0.10344E-10 -10.9853 0.73028E-11 -11.1365 0.70601E+00 -0.1512 90 H3PO3,aq 0.29741E-19 -19.5266 0.29741E-19 -19.5266 0.10000E+01 0.0000 92 H3PO4,aq 0.28998E-07 -7.5376 0.28998E-07 -7.5376 0.10000E+01 0.0000 93 H2PO4- 0.13631E-08 -8.8655 0.97074E-09 -9.0129 0.71215E+00 -0.1474 95 H4P2O7,aq 0.11132E-16 -16.9534 0.11132E-16 -16.9534 0.10000E+01 0.0000 96 H3P2O7- 0.25409E-17 -17.5950 0.18038E-17 -17.7438 0.70991E+00 -0.1488 97 H2P2O7-2 0.26749E-18 -18.5727 0.74193E-19 -19.1296 0.27737E+00 -0.5569 100 H2S,aq 0.62883E-01 -1.2015 0.58998E-01 -1.2292 0.93822E+00 -0.0277 101 S2-2 0.45393E-15 -15.3430 0.12590E-15 -15.9000 0.27737E+00 -0.5569 102 S3-2 0.34927E-14 -14.4568 0.96876E-15 -15.0138 0.27737E+00 -0.5569 103 S3- 0.70912E-09 -9.1493 0.50341E-09 -9.2981 0.70991E+00 -0.1488 104 S4-2 0.17752E-13 -13.7507 0.49239E-14 -14.3077 0.27737E+00 -0.5569 105 S5-2 0.60166E-13 -13.2206 0.16688E-13 -13.7776 0.27737E+00 -0.5569 106 SO2,aq 0.16171E-11 -11.7913 0.16171E-11 -11.7913 0.10000E+01 0.0000 107 SO3-2 0.25921E-19 -19.5864 0.75481E-20 -20.1222 0.29120E+00 -0.5358 108 HSO3- 0.52454E-13 -13.2802 0.37237E-13 -13.4290 0.70991E+00 -0.1488 109 HSO4- 0.59311E-09 -9.2269 0.42520E-09 -9.3714 0.71689E+00 -0.1445 111 S2O3-2 0.14049E-13 -13.8523 0.38968E-14 -14.4093 0.27737E+00 -0.5569 112 HS2O3- 0.77332E-13 -13.1116 0.54899E-13 -13.2604 0.70991E+00 -0.1488 113 H2S2O3,aq 0.69344E-13 -13.1590 0.69344E-13 -13.1590 0.10000E+01 0.0000 Charge balance for all species = -.4011E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1087728E+00 0.5863508E+00 0.5765332E+03 0.0000 2 H2O 0.1000000E+01 0.5510324E+02 0.9683911E+06 0.0000 3 Cl- 0.1231562E+00 0.1247124E+00 0.4313152E+04 0.0452 4 SO4-- 0.2004419E-10 -.1019946E-06 -.9557825E-02 -9.0448 5 HCO3- 0.3150736E-05 0.4050102E+00 0.2410740E+05 -4.5447 6 HS- 0.3411139E-06 0.6288356E-01 0.2028756E+04 -5.5122 7 Al+++ 0.3471730E-05 0.3477888E-05 0.9154060E-01 -3.4009 8 H4SiO4 0.1016236E-02 0.1016236E-02 0.9528398E+02 -2.9930 9 Ca++ 0.1436743E-06 0.1515472E-06 0.5924967E-02 -5.2010 10 Mg++ 0.5813129E-10 0.6094651E-10 0.1445445E-05 -8.6007 11 Fe++ 0.2255532E-07 0.2373694E-07 0.1293173E-02 -6.0102 12 K+ 0.1027411E-03 0.1028573E-03 0.3923434E+01 -3.0312 13 Na+ 0.1429565E-01 0.1458941E-01 0.3271938E+03 -0.8906 14 Mn++ 0.1362982E-08 0.1640087E-08 0.8789653E-04 -7.2278 15 F- 0.2213950E-04 0.8447850E-02 0.1565619E+03 -3.7028 16 HPO4-- 0.2389490E-14 0.3036150E-07 0.2842703E-02 -12.9683 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3102547E+01 0.8050954E+00 0.6923231E+00 0.1605129E+01 2 H2O 0.7358870E+02 0.7566012E+02 -.5753738E+00 -.1496045E+01 3 Cl- 0.1712378E+00 0.1712378E+00 0.0000000E+00 0.7349107E-07 4 SO4-- 0.1384600E+00 -.1400448E-06 0.1384646E+00 -.4513705E-05 5 HCO3- 0.2096712E+01 0.5561037E+00 0.0000000E+00 0.1540609E+01 6 HS- 0.5662653E+00 0.8634297E-01 0.4153939E+00 0.6452846E-01 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1395355E-02 0.1075767E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1160010E-01 0.1159941E-01 0.0000000E+00 0.6825639E-06 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1927E-16 Mass of aqueous solution: 0.140753E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 28.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.4455E-01 -1.351 0.8024 -0.096 1.133 17.71 CO2,gas 1.541 0.188 67.80 1.831 95.76 829.8 CH4,gas 0.4404E-05 -5.356 0.7063E-04 -4.151 0.9976E-04 0.2843E-02 H2,gas 0.4357E-06 -6.361 0.8801E-06 -6.055 0.1243E-05 0.2776E-03 H2S,gas 0.6452E-01 -1.190 2.199 0.342 3.106 32.85 S2,gas 0.1771E-10 -10.752 0.1136E-08 -8.945 0.1604E-08 0.1099E-07 CO,gas 0.4868E-08 -8.313 0.1364E-06 -6.865 0.1926E-06 0.3021E-05 SO3,gas 0.4355E-30 -30.361 0.3487E-28 -28.458 0.4924E-28 0.2702E-27 SO2,gas 0.2307E-12 -12.637 0.1478E-10 -10.830 0.2087E-10 0.1432E-09 HF,gas 0.6826E-06 -6.166 0.1365E-04 -4.865 0.1928E-04 0.4235E-03 HCl,gas 0.7349E-07 -7.134 0.2679E-05 -5.572 0.3784E-05 0.4560E-04 quartz 0.1076E-01 -1.968 0.6463 -0.190 3.512 0.2441 sulfur 0.5539 -0.257 17.76 1.249 96.49 8.591 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2701E-01 0.1350E+01 0.7419 0.001 CO2,gas 0.9339E+00 0.4669E+02 0.8707 1.609 CH4,gas 0.2669E-05 0.1335E-03 1.0376 -3.859 H2,gas 0.2641E-06 0.1321E-04 1.0270 -4.868 H2S,gas 0.3911E-01 0.1956E+01 0.8293 0.210 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.2951E-08 0.1476E-06 1.0000 -6.831 SO3,gas 0.2640E-30 0.1320E-28 1.0000 -28.879 SO2,gas 0.1399E-12 0.6993E-11 1.0000 -11.155 HF,gas 0.4138E-06 0.2069E-04 1.0000 -4.684 HCl,gas 0.4455E-07 0.2227E-05 1.0000 -5.652 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 4.730524 % Solid products produced: Mass = 18.403024 g Volume = 8.834646 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 28.9999900 moles log = 1.4624 Original solution: 1000.0103000 g Original solution / Rock added: 34.48 (Water/Rock Ratio), log = 1.5376 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 0.37914E-12 2 CO2,gas -6.66 -6.66 0.00 0.000 0.00000E+00 3 CH4,gas 4.54 4.54 0.00 0.000 0.00000E+00 4 H2,gas 8.00 8.00 0.00 0.000 0.00000E+00 5 H2S,gas -6.23 -6.23 0.00 0.000 0.00000E+00 6 S2,gas -7.34 -7.34 0.00 0.000 0.00000E+00 7 CO,gas 3.21 3.21 0.00 0.000 -0.22748E-11 8 SO3,gas 17.12 17.12 0.00 0.000 0.00000E+00 9 SO2,gas 0.83 0.83 0.00 0.000 -0.37914E-12 10 HF,gas 0.47 0.47 0.00 0.000 0.37914E-12 11 HCl,gas 5.19 5.19 0.00 0.000 0.00000E+00 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 172 sulfur -9.15 -9.15 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.88 -0.78 -0.222 0.13280E+04 89 graphite -3.55 -3.88 -0.33 -0.095 0.57026E+03 92 halite 1.57 -3.05 -4.63 -2.313 0.79004E+04 145 pyrite -21.25 -22.88 -1.63 -0.385 0.27914E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 28.9999900 MOLES New total amount of reactant added: 29.9999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 21 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 29.9999900 Water: Moles liquid = 0.7712E+02 kg liquid = 0.1389E+01 Moles total = 0.7441E+02 kg total = 0.1340E+01 Activity = 0.9958 Stoichiometric ionic strength = .3118130E+00 Osmotic coef. = 0.9148 True ionic strength = .1259118E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1771E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11167E+00 -0.9521 0.80733E-01 -1.0930 0.72298E+00 -0.1409 2 H2O 0.99581E+00 -0.0018 0.99581E+00 -0.0018 3 Cl- 0.12588E+00 -0.9001 0.89169E-01 -1.0498 0.70839E+00 -0.1497 4 SO4-- 0.18752E-10 -10.7269 0.51923E-11 -11.2846 0.27689E+00 -0.5577 5 HCO3- 0.30800E-05 -5.5114 0.21927E-05 -5.6590 0.71190E+00 -0.1476 6 HS- 0.33659E-06 -6.4729 0.23855E-06 -6.6224 0.70873E+00 -0.1495 7 Al+++ 0.34311E-05 -5.4646 0.18815E-06 -6.7255 0.54837E-01 -1.2609 8 H4SiO4 0.10161E-02 -2.9931 0.10161E-02 -2.9931 0.10000E+01 0.0000 9 Ca++ 0.14189E-06 -6.8481 0.38244E-07 -7.4174 0.26953E+00 -0.5694 10 Mg++ 0.57414E-10 -10.2410 0.15234E-10 -10.8172 0.26534E+00 -0.5762 11 Fe++ 0.22276E-07 -7.6522 0.59327E-08 -8.2267 0.26633E+00 -0.5746 12 K+ 0.10153E-03 -3.9934 0.72312E-04 -4.1408 0.71223E+00 -0.1474 13 Na+ 0.14122E-01 -1.8501 0.99926E-02 -2.0003 0.70758E+00 -0.1502 14 Mn++ 0.13441E-08 -8.8716 0.35898E-09 -9.4449 0.26708E+00 -0.5734 15 F- 0.22139E-04 -4.6548 0.15586E-04 -4.8073 0.70401E+00 -0.1524 16 HPO4-- 0.22715E-14 -14.6437 0.62927E-15 -15.2012 0.27702E+00 -0.5575 17 SiF6-2 0.72711E-11 -11.1384 0.19987E-11 -11.6993 0.27488E+00 -0.5608 18 HSiO3- 0.16659E-10 -10.7784 0.11801E-10 -10.9281 0.70839E+00 -0.1497 19 Ca(HSiO3)+ 0.14420E-16 -16.8410 0.10278E-16 -16.9881 0.71277E+00 -0.1471 21 NaHSiO3,aq 0.19072E-11 -11.7196 0.19072E-11 -11.7196 0.10000E+01 0.0000 22 AlO+ 0.54866E-11 -11.2607 0.39107E-11 -11.4077 0.71277E+00 -0.1471 23 AlOH+2 0.58666E-08 -8.2316 0.15721E-08 -8.8035 0.26797E+00 -0.5719 24 HAlO2,aq 0.96063E-14 -14.0174 0.96063E-14 -14.0174 0.10000E+01 0.0000 25 AlO2- 0.37389E-18 -18.4273 0.26339E-18 -18.5794 0.70446E+00 -0.1521 26 CH4,aq 0.10388E-06 -6.9835 0.97445E-07 -7.0112 0.93803E+00 -0.0278 27 C2H6,aq 0.16605E-15 -15.7798 0.15576E-15 -15.8075 0.93803E+00 -0.0278 31 CO,aq 0.99866E-10 -10.0006 0.99866E-10 -10.0006 0.10000E+01 0.0000 32 CO2,aq 0.40494E+00 -0.3926 0.37985E+00 -0.4204 0.93803E+00 -0.0278 33 CO3-2 0.86302E-14 -14.0640 0.23723E-14 -14.6248 0.27488E+00 -0.5608 34 CaCO3,aq 0.11376E-17 -17.9440 0.11376E-17 -17.9440 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.30031E-11 -11.5224 0.21405E-11 -11.6695 0.71277E+00 -0.1471 36 CaCl+ 0.77426E-08 -8.1111 0.55187E-08 -8.2582 0.71277E+00 -0.1471 37 CaCl2,aq 0.11691E-09 -9.9321 0.11691E-09 -9.9321 0.10000E+01 0.0000 38 CaF+ 0.12210E-10 -10.9133 0.87026E-11 -11.0604 0.71277E+00 -0.1471 39 CaOH+ 0.47167E-16 -16.3264 0.33619E-16 -16.4734 0.71277E+00 -0.1471 40 CaSO4,aq 0.63056E-16 -16.2003 0.63056E-16 -16.2003 0.10000E+01 0.0000 41 HCl,aq 0.13191E-02 -2.8797 0.13191E-02 -2.8797 0.10000E+01 0.0000 45 HF,aq 0.86139E-02 -2.0648 0.86139E-02 -2.0648 0.10000E+01 0.0000 46 HF2- 0.63988E-07 -7.1939 0.45328E-07 -7.3436 0.70839E+00 -0.1497 47 Fe+3 0.68738E-17 -17.1628 0.38099E-18 -18.4191 0.55426E-01 -1.2563 48 FeCl+ 0.11748E-08 -8.9300 0.83734E-09 -9.0771 0.71277E+00 -0.1471 49 FeCl2,aq 0.23639E-14 -14.6264 0.23639E-14 -14.6264 0.10000E+01 0.0000 50 FeCl+2 0.90580E-17 -17.0430 0.24273E-17 -17.6149 0.26797E+00 -0.5719 51 FeF+ 0.66294E-11 -11.1785 0.47252E-11 -11.3256 0.71277E+00 -0.1471 52 FeF+2 0.19750E-15 -15.7044 0.52924E-16 -16.2764 0.26797E+00 -0.5719 54 FeOH+ 0.33419E-14 -14.4760 0.23820E-14 -14.6231 0.71277E+00 -0.1471 56 FeO+ 0.78081E-19 -19.1075 0.55654E-19 -19.2545 0.71277E+00 -0.1471 57 FeOH+2 0.32020E-17 -17.4946 0.85804E-18 -18.0665 0.26797E+00 -0.5719 60 H2,aq 0.11111E-07 -7.9543 0.10422E-07 -7.9820 0.93803E+00 -0.0278 61 KCl,aq 0.11686E-06 -6.9323 0.11686E-06 -6.9323 0.10000E+01 0.0000 62 KHSO4,aq 0.85705E-16 -16.0670 0.85705E-16 -16.0670 0.10000E+01 0.0000 63 KOH,aq 0.38091E-15 -15.4192 0.38091E-15 -15.4192 0.10000E+01 0.0000 64 KSO4- 0.82249E-14 -14.0849 0.58264E-14 -14.2346 0.70839E+00 -0.1497 66 Mg(HCO3)+ 0.12224E-14 -14.9128 0.87128E-15 -15.0598 0.71277E+00 -0.1471 67 MgCl+ 0.27954E-11 -11.5536 0.19925E-11 -11.7006 0.71277E+00 -0.1471 68 MgF+ 0.18017E-13 -13.7443 0.12842E-13 -13.8914 0.71277E+00 -0.1471 69 MgOH+ 0.10397E-18 -18.9831 0.74106E-19 -19.1301 0.71277E+00 -0.1471 71 MnF+ 0.13222E-12 -12.8787 0.94241E-13 -13.0258 0.71277E+00 -0.1471 73 MnOH+ 0.18785E-16 -16.7262 0.13389E-16 -16.8732 0.71277E+00 -0.1471 78 MnCl+ 0.27655E-09 -9.5582 0.19711E-09 -9.7053 0.71277E+00 -0.1471 79 MnSO4,aq 0.53811E-18 -18.2691 0.53811E-18 -18.2691 0.10000E+01 0.0000 80 NaCl,aq 0.29529E-03 -3.5298 0.29529E-03 -3.5298 0.10000E+01 0.0000 81 NaF,aq 0.36463E-07 -7.4382 0.36463E-07 -7.4382 0.10000E+01 0.0000 82 NaOH,aq 0.52956E-13 -13.2761 0.52956E-13 -13.2761 0.10000E+01 0.0000 84 OH- 0.10116E-10 -10.9950 0.71266E-11 -11.1471 0.70446E+00 -0.1521 90 H3PO3,aq 0.29684E-19 -19.5275 0.29684E-19 -19.5275 0.10000E+01 0.0000 92 H3PO4,aq 0.28685E-07 -7.5423 0.28685E-07 -7.5423 0.10000E+01 0.0000 93 H2PO4- 0.13188E-08 -8.8798 0.93717E-09 -9.0282 0.71065E+00 -0.1483 95 H4P2O7,aq 0.10894E-16 -16.9628 0.10894E-16 -16.9628 0.10000E+01 0.0000 96 H3P2O7- 0.24320E-17 -17.6140 0.17228E-17 -17.7638 0.70839E+00 -0.1497 97 H2P2O7-2 0.25159E-18 -18.5993 0.69157E-19 -19.1602 0.27488E+00 -0.5608 100 H2S,aq 0.63454E-01 -1.1975 0.59522E-01 -1.2253 0.93803E+00 -0.0278 101 S2-2 0.44014E-15 -15.3564 0.12099E-15 -15.9173 0.27488E+00 -0.5608 102 S3-2 0.33866E-14 -14.4702 0.93093E-15 -15.0311 0.27488E+00 -0.5608 103 S3- 0.69663E-09 -9.1570 0.49348E-09 -9.3067 0.70839E+00 -0.1497 104 S4-2 0.17213E-13 -13.7641 0.47317E-14 -14.3250 0.27488E+00 -0.5608 105 S5-2 0.58339E-13 -13.2340 0.16037E-13 -13.7949 0.27488E+00 -0.5608 106 SO2,aq 0.15885E-11 -11.7990 0.15885E-11 -11.7990 0.10000E+01 0.0000 107 SO3-2 0.24456E-19 -19.6116 0.70617E-20 -20.1511 0.28876E+00 -0.5395 108 HSO3- 0.50391E-13 -13.2976 0.35696E-13 -13.4474 0.70839E+00 -0.1497 109 HSO4- 0.56466E-09 -9.2482 0.40398E-09 -9.3936 0.71543E+00 -0.1454 111 S2O3-2 0.13263E-13 -13.8774 0.36457E-14 -14.4382 0.27488E+00 -0.5608 112 HS2O3- 0.74290E-13 -13.1291 0.52626E-13 -13.2788 0.70839E+00 -0.1497 113 H2S2O3,aq 0.68111E-13 -13.1668 0.68111E-13 -13.1668 0.10000E+01 0.0000 Charge balance for all species = -.3964E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1116668E+00 0.5899959E+00 0.5800506E+03 0.0000 2 H2O 0.1000000E+01 0.5510331E+02 0.9682810E+06 0.0000 3 Cl- 0.1258757E+00 0.1274903E+00 0.4408717E+04 0.0432 4 SO4-- 0.1875237E-10 -.1056657E-06 -.9900702E-02 -9.0987 5 HCO3- 0.3080034E-05 0.4049449E+00 0.2410074E+05 -4.5661 6 HS- 0.3365888E-06 0.6345463E-01 0.2046944E+04 -5.5295 7 Al+++ 0.3431063E-05 0.3436935E-05 0.9045230E-01 -3.4466 8 H4SiO4 0.1016050E-02 0.1016050E-02 0.9525558E+02 -2.9931 9 Ca++ 0.1418880E-06 0.1497627E-06 0.5854527E-02 -5.2315 10 Mg++ 0.5741423E-10 0.6022885E-10 0.1428261E-05 -8.6313 11 Fe++ 0.2227603E-07 0.2345743E-07 0.1277799E-02 -6.0408 12 K+ 0.1015293E-03 0.1016462E-03 0.3876789E+01 -3.0478 13 Na+ 0.1412229E-01 0.1441762E-01 0.3233039E+03 -0.9074 14 Mn++ 0.1344094E-08 0.1620774E-08 0.8685155E-04 -7.2590 15 F- 0.2213894E-04 0.8636232E-02 0.1600348E+03 -3.7143 16 HPO4-- 0.2271546E-14 0.3000398E-07 0.2808907E-02 -13.0153 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3210222E+01 0.8197532E+00 0.7161999E+00 0.1674269E+01 2 H2O 0.7440740E+02 0.7656174E+02 -.5944425E+00 -.1559894E+01 3 Cl- 0.1771378E+00 0.1771377E+00 0.0000000E+00 0.8010654E-07 4 SO4-- 0.1432350E+00 -.1468142E-06 0.1432400E+00 -.4873424E-05 5 HCO3- 0.2169012E+01 0.5626392E+00 0.0000000E+00 0.1606373E+01 6 HS- 0.5857903E+00 0.8816524E-01 0.4297200E+00 0.6790509E-01 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1411722E-02 0.1074130E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1200010E-01 0.1199937E-01 0.0000000E+00 0.7278816E-06 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.8624E-16 Mass of aqueous solution: 0.142447E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 29.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.4647E-01 -1.333 0.8369 -0.077 1.133 18.47 CO2,gas 1.606 0.206 70.70 1.849 95.73 865.2 CH4,gas 0.4758E-05 -5.323 0.7631E-04 -4.117 0.1033E-03 0.3072E-02 H2,gas 0.4585E-06 -6.339 0.9262E-06 -6.033 0.1254E-05 0.2921E-03 H2S,gas 0.6790E-01 -1.168 2.314 0.364 3.134 34.57 S2,gas 0.1847E-10 -10.733 0.1184E-08 -8.926 0.1604E-08 0.1146E-07 CO,gas 0.5122E-08 -8.291 0.1435E-06 -6.843 0.1943E-06 0.3178E-05 SO3,gas 0.4422E-30 -30.354 0.3541E-28 -28.451 0.4794E-28 0.2744E-27 SO2,gas 0.2364E-12 -12.626 0.1514E-10 -10.820 0.2051E-10 0.1467E-09 HF,gas 0.7279E-06 -6.138 0.1456E-04 -4.837 0.1971E-04 0.4516E-03 HCl,gas 0.8011E-07 -7.096 0.2921E-05 -5.535 0.3955E-05 0.4971E-04 quartz 0.1074E-01 -1.969 0.6453 -0.190 3.394 0.2437 sulfur 0.5730 -0.242 18.37 1.264 96.61 8.887 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2701E-01 0.1350E+01 0.7419 0.001 CO2,gas 0.9335E+00 0.4668E+02 0.8707 1.609 CH4,gas 0.2765E-05 0.1382E-03 1.0376 -3.843 H2,gas 0.2665E-06 0.1332E-04 1.0270 -4.864 H2S,gas 0.3946E-01 0.1973E+01 0.8293 0.214 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.2976E-08 0.1488E-06 1.0000 -6.827 SO3,gas 0.2570E-30 0.1285E-28 1.0000 -28.891 SO2,gas 0.1374E-12 0.6869E-11 1.0000 -11.163 HF,gas 0.4230E-06 0.2115E-04 1.0000 -4.675 HCl,gas 0.4655E-07 0.2328E-05 1.0000 -5.633 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 4.866935 % Solid products produced: Mass = 19.014433 g Volume = 9.130546 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 29.9999900 moles log = 1.4771 Original solution: 1000.0103000 g Original solution / Rock added: 33.33 (Water/Rock Ratio), log = 1.5229 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 -0.37914E-12 2 CO2,gas -6.66 -6.66 0.00 0.000 0.00000E+00 3 CH4,gas 4.54 4.54 0.00 0.000 0.00000E+00 4 H2,gas 8.00 8.00 0.00 0.000 0.00000E+00 5 H2S,gas -6.23 -6.23 0.00 0.000 0.15165E-11 6 S2,gas -7.34 -7.34 0.00 0.000 0.00000E+00 7 CO,gas 3.21 3.21 0.00 0.000 0.22748E-11 8 SO3,gas 17.12 17.12 0.00 0.000 0.00000E+00 9 SO2,gas 0.83 0.83 0.00 0.000 0.26539E-11 10 HF,gas 0.47 0.47 0.00 0.000 0.37914E-12 11 HCl,gas 5.19 5.19 0.00 0.000 0.00000E+00 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 172 sulfur -9.15 -9.15 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.87 -0.77 -0.220 0.13151E+04 89 graphite -3.55 -3.87 -0.33 -0.093 0.55730E+03 92 halite 1.57 -3.05 -4.62 -2.312 0.78965E+04 145 pyrite -21.25 -22.91 -1.66 -0.391 0.28372E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 29.9999900 MOLES New total amount of reactant added: 30.9999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 21 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 30.9999900 Water: Moles liquid = 0.7803E+02 kg liquid = 0.1406E+01 Moles total = 0.7523E+02 kg total = 0.1355E+01 Activity = 0.9957 Stoichiometric ionic strength = .3134299E+00 Osmotic coef. = 0.9148 True ionic strength = .1285669E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1830E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11449E+00 -0.9412 0.82623E-01 -1.0829 0.72164E+00 -0.1417 2 H2O 0.99572E+00 -0.0019 0.99572E+00 -0.0019 3 Cl- 0.12853E+00 -0.8910 0.90863E-01 -1.0416 0.70693E+00 -0.1506 4 SO4-- 0.17606E-10 -10.7543 0.48333E-11 -11.3158 0.27453E+00 -0.5614 5 HCO3- 0.30143E-05 -5.5208 0.21416E-05 -5.6693 0.71048E+00 -0.1484 6 HS- 0.33232E-06 -6.4784 0.23504E-06 -6.6289 0.70728E+00 -0.1504 7 Al+++ 0.33913E-05 -5.4696 0.18233E-06 -6.7391 0.53764E-01 -1.2695 8 H4SiO4 0.10159E-02 -2.9932 0.10159E-02 -2.9932 0.10000E+01 0.0000 9 Ca++ 0.14015E-06 -6.8534 0.37441E-07 -7.4267 0.26715E+00 -0.5732 10 Mg++ 0.56715E-10 -10.2463 0.14913E-10 -10.8264 0.26295E+00 -0.5801 11 Fe++ 0.22004E-07 -7.6575 0.58077E-08 -8.2360 0.26394E+00 -0.5785 12 K+ 0.10035E-03 -3.9985 0.71326E-04 -4.1468 0.71080E+00 -0.1483 13 Na+ 0.13953E-01 -1.8553 0.98524E-02 -2.0065 0.70611E+00 -0.1511 14 Mn++ 0.13258E-08 -8.8775 0.35092E-09 -9.4548 0.26470E+00 -0.5773 15 F- 0.22141E-04 -4.6548 0.15555E-04 -4.8081 0.70253E+00 -0.1533 16 HPO4-- 0.21639E-14 -14.6648 0.59436E-15 -15.2260 0.27467E+00 -0.5612 17 SiF6-2 0.79504E-11 -11.0996 0.21667E-11 -11.6642 0.27253E+00 -0.5646 18 HSiO3- 0.16310E-10 -10.7875 0.11530E-10 -10.9382 0.70693E+00 -0.1506 19 Ca(HSiO3)+ 0.13821E-16 -16.8595 0.98312E-17 -17.0074 0.71135E+00 -0.1479 21 NaHSiO3,aq 0.18373E-11 -11.7358 0.18373E-11 -11.7358 0.10000E+01 0.0000 22 AlO+ 0.50862E-11 -11.2936 0.36181E-11 -11.4415 0.71135E+00 -0.1479 23 AlOH+2 0.56045E-08 -8.2515 0.14885E-08 -8.8272 0.26559E+00 -0.5758 24 HAlO2,aq 0.86834E-14 -14.0613 0.86834E-14 -14.0613 0.10000E+01 0.0000 25 AlO2- 0.33093E-18 -18.4803 0.23264E-18 -18.6333 0.70298E+00 -0.1531 26 CH4,aq 0.10741E-06 -6.9690 0.10073E-06 -6.9968 0.93784E+00 -0.0279 27 C2H6,aq 0.17600E-15 -15.7545 0.16506E-15 -15.7824 0.93784E+00 -0.0279 31 CO,aq 0.10067E-09 -9.9971 0.10067E-09 -9.9971 0.10000E+01 0.0000 32 CO2,aq 0.40488E+00 -0.3927 0.37971E+00 -0.4205 0.93784E+00 -0.0279 33 CO3-2 0.83075E-14 -14.0805 0.22640E-14 -14.6451 0.27253E+00 -0.5646 34 CaCO3,aq 0.10629E-17 -17.9735 0.10629E-17 -17.9735 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.28773E-11 -11.5410 0.20467E-11 -11.6889 0.71135E+00 -0.1479 36 CaCl+ 0.77395E-08 -8.1113 0.55054E-08 -8.2592 0.71135E+00 -0.1479 37 CaCl2,aq 0.11885E-09 -9.9250 0.11885E-09 -9.9250 0.10000E+01 0.0000 38 CaF+ 0.11953E-10 -10.9225 0.85028E-11 -11.0704 0.71135E+00 -0.1479 39 CaOH+ 0.45207E-16 -16.3448 0.32158E-16 -16.4927 0.71135E+00 -0.1479 40 CaSO4,aq 0.57464E-16 -16.2406 0.57464E-16 -16.2406 0.10000E+01 0.0000 41 HCl,aq 0.13757E-02 -2.8615 0.13757E-02 -2.8615 0.10000E+01 0.0000 45 HF,aq 0.87979E-02 -2.0556 0.87979E-02 -2.0556 0.10000E+01 0.0000 46 HF2- 0.65358E-07 -7.1847 0.46204E-07 -7.3353 0.70693E+00 -0.1506 47 Fe+3 0.69939E-17 -17.1553 0.38011E-18 -18.4201 0.54349E-01 -1.2648 48 FeCl+ 0.11742E-08 -8.9303 0.83526E-09 -9.0782 0.71135E+00 -0.1479 49 FeCl2,aq 0.24028E-14 -14.6193 0.24028E-14 -14.6193 0.10000E+01 0.0000 50 FeCl+2 0.92914E-17 -17.0319 0.24677E-17 -17.6077 0.26559E+00 -0.5758 51 FeF+ 0.64896E-11 -11.1878 0.46164E-11 -11.3357 0.71135E+00 -0.1479 52 FeF+2 0.19841E-15 -15.7024 0.52695E-16 -16.2782 0.26559E+00 -0.5758 54 FeOH+ 0.32028E-14 -14.4945 0.22783E-14 -14.6424 0.71135E+00 -0.1479 56 FeO+ 0.74519E-19 -19.1277 0.53009E-19 -19.2757 0.71135E+00 -0.1479 57 FeOH+2 0.31492E-17 -17.5018 0.83640E-18 -18.0776 0.26559E+00 -0.5758 60 H2,aq 0.11206E-07 -7.9506 0.10509E-07 -7.9784 0.93784E+00 -0.0279 61 KCl,aq 0.11746E-06 -6.9301 0.11746E-06 -6.9301 0.10000E+01 0.0000 62 KHSO4,aq 0.80534E-16 -16.0940 0.80534E-16 -16.0940 0.10000E+01 0.0000 63 KOH,aq 0.36709E-15 -15.4352 0.36709E-15 -15.4352 0.10000E+01 0.0000 64 KSO4- 0.75673E-14 -14.1211 0.53496E-14 -14.2717 0.70693E+00 -0.1506 66 Mg(HCO3)+ 0.11711E-14 -14.9314 0.83304E-15 -15.0793 0.71135E+00 -0.1479 67 MgCl+ 0.27941E-11 -11.5538 0.19876E-11 -11.7017 0.71135E+00 -0.1479 68 MgF+ 0.17637E-13 -13.7536 0.12546E-13 -13.9015 0.71135E+00 -0.1479 69 MgOH+ 0.99641E-19 -19.0016 0.70879E-19 -19.1495 0.71135E+00 -0.1479 71 MnF+ 0.12925E-12 -12.8886 0.91941E-13 -13.0365 0.71135E+00 -0.1479 73 MnOH+ 0.17978E-16 -16.7453 0.12788E-16 -16.8932 0.71135E+00 -0.1479 78 MnCl+ 0.27603E-09 -9.5590 0.19635E-09 -9.7070 0.71135E+00 -0.1479 79 MnSO4,aq 0.48966E-18 -18.3101 0.48966E-18 -18.3101 0.10000E+01 0.0000 80 NaCl,aq 0.29668E-03 -3.5277 0.29668E-03 -3.5277 0.10000E+01 0.0000 81 NaF,aq 0.35879E-07 -7.4452 0.35879E-07 -7.4452 0.10000E+01 0.0000 82 NaOH,aq 0.51014E-13 -13.2923 0.51014E-13 -13.2923 0.10000E+01 0.0000 84 OH- 0.99049E-11 -11.0042 0.69630E-11 -11.1572 0.70298E+00 -0.1531 90 H3PO3,aq 0.29614E-19 -19.5285 0.29614E-19 -19.5285 0.10000E+01 0.0000 92 H3PO4,aq 0.28377E-07 -7.5470 0.28377E-07 -7.5470 0.10000E+01 0.0000 93 H2PO4- 0.12773E-08 -8.8937 0.90591E-09 -9.0429 0.70921E+00 -0.1492 95 H4P2O7,aq 0.10663E-16 -16.9721 0.10663E-16 -16.9721 0.10000E+01 0.0000 96 H3P2O7- 0.23307E-17 -17.6325 0.16476E-17 -17.7831 0.70693E+00 -0.1506 97 H2P2O7-2 0.23713E-18 -18.6250 0.64625E-19 -19.1896 0.27253E+00 -0.5646 100 H2S,aq 0.63998E-01 -1.1938 0.60020E-01 -1.2217 0.93784E+00 -0.0279 101 S2-2 0.42741E-15 -15.3692 0.11648E-15 -15.9337 0.27253E+00 -0.5646 102 S3-2 0.32887E-14 -14.4830 0.89626E-15 -15.0476 0.27253E+00 -0.5646 103 S3- 0.68494E-09 -9.1643 0.48421E-09 -9.3150 0.70693E+00 -0.1506 104 S4-2 0.16716E-13 -13.7769 0.45554E-14 -14.3415 0.27253E+00 -0.5646 105 S5-2 0.56652E-13 -13.2468 0.15439E-13 -13.8114 0.27253E+00 -0.5646 106 SO2,aq 0.15619E-11 -11.8063 0.15619E-11 -11.8063 0.10000E+01 0.0000 107 SO3-2 0.23144E-19 -19.6356 0.66291E-20 -20.1785 0.28643E+00 -0.5430 108 HSO3- 0.48511E-13 -13.3142 0.34294E-13 -13.4648 0.70693E+00 -0.1506 109 HSO4- 0.53898E-09 -9.2684 0.38486E-09 -9.4147 0.71404E+00 -0.1463 111 S2O3-2 0.12558E-13 -13.9011 0.34224E-14 -14.4657 0.27253E+00 -0.5646 112 HS2O3- 0.71519E-13 -13.1456 0.50559E-13 -13.2962 0.70693E+00 -0.1506 113 H2S2O3,aq 0.66968E-13 -13.1741 0.66968E-13 -13.1741 0.10000E+01 0.0000 Charge balance for all species = -.3918E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1144925E+00 0.5935453E+00 0.5834749E+03 0.0000 2 H2O 0.1000000E+01 0.5510337E+02 0.9681737E+06 0.0000 3 Cl- 0.1285310E+00 0.1302035E+00 0.4502038E+04 0.0413 4 SO4-- 0.1760565E-10 -.1092471E-06 -.1023513E-01 -9.1500 5 HCO3- 0.3014278E-05 0.4048842E+00 0.2409443E+05 -4.5864 6 HS- 0.3323201E-06 0.6399837E-01 0.2064253E+04 -5.5460 7 Al+++ 0.3391326E-05 0.3396935E-05 0.8938960E-01 -3.4904 8 H4SiO4 0.1015869E-02 0.1015869E-02 0.9522789E+02 -2.9932 9 Ca++ 0.1401466E-06 0.1480197E-06 0.5785744E-02 -5.2609 10 Mg++ 0.5671502E-10 0.5952790E-10 0.1411481E-05 -8.6606 11 Fe++ 0.2200373E-07 0.2318443E-07 0.1262787E-02 -6.0702 12 K+ 0.1003457E-03 0.1004632E-03 0.3831242E+01 -3.0639 13 Na+ 0.1395311E-01 0.1424982E-01 0.3195055E+03 -0.9236 14 Mn++ 0.1325756E-08 0.1601911E-08 0.8583116E-04 -7.2890 15 F- 0.2214087E-04 0.8820228E-02 0.1634261E+03 -3.7252 16 HPO4-- 0.2163914E-14 0.2965479E-07 0.2775906E-02 -13.0602 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3317897E+01 0.8343955E+00 0.7400768E+00 0.1743425E+01 2 H2O 0.7522610E+02 0.7746335E+02 -.6135113E+00 -.1623738E+01 3 Cl- 0.1830378E+00 0.1830377E+00 0.0000000E+00 0.8699011E-07 4 SO4-- 0.1480100E+00 -.1535777E-06 0.1480154E+00 -.5242698E-05 5 HCO3- 0.2241312E+01 0.5691791E+00 0.0000000E+00 0.1672133E+01 6 HS- 0.6053153E+00 0.8996779E-01 0.4440461E+00 0.7130142E-01 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1428090E-02 0.1072493E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1240010E-01 0.1239932E-01 0.0000000E+00 0.7741346E-06 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4837E-15 Mass of aqueous solution: 0.144140E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 30.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.4838E-01 -1.315 0.8714 -0.060 1.133 19.23 CO2,gas 1.672 0.223 73.59 1.867 95.71 900.6 CH4,gas 0.5121E-05 -5.291 0.8214E-04 -4.085 0.1068E-03 0.3306E-02 H2,gas 0.4814E-06 -6.317 0.9725E-06 -6.012 0.1265E-05 0.3067E-03 H2S,gas 0.7130E-01 -1.147 2.430 0.386 3.160 36.30 S2,gas 0.1924E-10 -10.716 0.1233E-08 -8.909 0.1604E-08 0.1194E-07 CO,gas 0.5376E-08 -8.270 0.1506E-06 -6.822 0.1958E-06 0.3336E-05 SO3,gas 0.4490E-30 -30.348 0.3595E-28 -28.444 0.4675E-28 0.2786E-27 SO2,gas 0.2421E-12 -12.616 0.1551E-10 -10.810 0.2017E-10 0.1502E-09 HF,gas 0.7741E-06 -6.111 0.1548E-04 -4.810 0.2014E-04 0.4803E-03 HCl,gas 0.8699E-07 -7.061 0.3172E-05 -5.499 0.4125E-05 0.5398E-04 quartz 0.1072E-01 -1.970 0.6444 -0.191 3.283 0.2433 sulfur 0.5921 -0.228 18.98 1.278 96.72 9.183 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2700E-01 0.1350E+01 0.7419 0.001 CO2,gas 0.9332E+00 0.4666E+02 0.8707 1.609 CH4,gas 0.2858E-05 0.1429E-03 1.0376 -3.829 H2,gas 0.2687E-06 0.1343E-04 1.0270 -4.860 H2S,gas 0.3979E-01 0.1989E+01 0.8293 0.217 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.3001E-08 0.1500E-06 1.0000 -6.824 SO3,gas 0.2506E-30 0.1253E-28 1.0000 -28.902 SO2,gas 0.1351E-12 0.6754E-11 1.0000 -11.170 HF,gas 0.4320E-06 0.2160E-04 1.0000 -4.666 HCl,gas 0.4855E-07 0.2427E-05 1.0000 -5.615 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 4.999725 % Solid products produced: Mass = 19.625844 g Volume = 9.426447 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 30.9999900 moles log = 1.4914 Original solution: 1000.0103000 g Original solution / Rock added: 32.26 (Water/Rock Ratio), log = 1.5086 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 0.37914E-12 2 CO2,gas -6.66 -6.66 0.00 0.000 0.15165E-11 3 CH4,gas 4.54 4.54 0.00 0.000 -0.15165E-11 4 H2,gas 8.00 8.00 0.00 0.000 0.00000E+00 5 H2S,gas -6.23 -6.23 0.00 0.000 -0.15165E-11 6 S2,gas -7.34 -7.34 0.00 0.000 0.00000E+00 7 CO,gas 3.21 3.21 0.00 0.000 -0.75827E-12 8 SO3,gas 17.12 17.12 0.00 0.000 0.60662E-11 9 SO2,gas 0.83 0.83 0.00 0.000 -0.37914E-12 10 HF,gas 0.47 0.47 0.00 0.000 0.37914E-12 11 HCl,gas 5.19 5.19 0.00 0.000 0.15165E-11 150 quartz -2.99 -2.99 0.00 0.000 -0.75827E-12 172 sulfur -9.15 -9.15 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.87 -0.76 -0.218 0.13028E+04 89 graphite -3.55 -3.87 -0.32 -0.091 0.54507E+03 92 halite 1.57 -3.05 -4.62 -2.311 0.78930E+04 145 pyrite -21.25 -22.93 -1.69 -0.397 0.28811E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 30.9999900 MOLES New total amount of reactant added: 31.9999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 21 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 31.9999900 Water: Moles liquid = 0.7894E+02 kg liquid = 0.1422E+01 Moles total = 0.7604E+02 kg total = 0.1370E+01 Activity = 0.9956 Stoichiometric ionic strength = .3150045E+00 Osmotic coef. = 0.9148 True ionic strength = .1311600E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1889E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11725E+00 -0.9309 0.84465E-01 -1.0733 0.72037E+00 -0.1424 2 H2O 0.99563E+00 -0.0019 0.99563E+00 -0.0019 3 Cl- 0.13112E+00 -0.8823 0.92514E-01 -1.0338 0.70554E+00 -0.1515 4 SO4-- 0.16583E-10 -10.7803 0.45153E-11 -11.3453 0.27229E+00 -0.5650 5 HCO3- 0.29530E-05 -5.5297 0.20940E-05 -5.6790 0.70911E+00 -0.1493 6 HS- 0.32829E-06 -6.4837 0.23173E-06 -6.6350 0.70589E+00 -0.1513 7 Al+++ 0.33525E-05 -5.4746 0.17686E-06 -6.7524 0.52755E-01 -1.2777 8 H4SiO4 0.10157E-02 -2.9932 0.10157E-02 -2.9932 0.10000E+01 0.0000 9 Ca++ 0.13845E-06 -6.8587 0.36673E-07 -7.4356 0.26489E+00 -0.5769 10 Mg++ 0.56033E-10 -10.2516 0.14607E-10 -10.8354 0.26068E+00 -0.5839 11 Fe++ 0.21738E-07 -7.6628 0.56883E-08 -8.2450 0.26167E+00 -0.5822 12 K+ 0.99189E-04 -4.0035 0.70368E-04 -4.1526 0.70944E+00 -0.1491 13 Na+ 0.13788E-01 -1.8605 0.97164E-02 -2.0125 0.70470E+00 -0.1520 14 Mn++ 0.13079E-08 -8.8834 0.34324E-09 -9.4644 0.26243E+00 -0.5810 15 F- 0.22145E-04 -4.6547 0.15526E-04 -4.8089 0.70112E+00 -0.1542 16 HPO4-- 0.20653E-14 -14.6850 0.56266E-15 -15.2498 0.27243E+00 -0.5647 17 SiF6-2 0.86618E-11 -11.0624 0.23411E-11 -11.6306 0.27028E+00 -0.5682 18 HSiO3- 0.15984E-10 -10.7963 0.11277E-10 -10.9478 0.70554E+00 -0.1515 19 Ca(HSiO3)+ 0.13266E-16 -16.8773 0.94189E-17 -17.0260 0.70998E+00 -0.1488 21 NaHSiO3,aq 0.17723E-11 -11.7515 0.17723E-11 -11.7515 0.10000E+01 0.0000 22 AlO+ 0.47294E-11 -11.3252 0.33578E-11 -11.4739 0.70998E+00 -0.1488 23 AlOH+2 0.53631E-08 -8.2706 0.14122E-08 -8.8501 0.26332E+00 -0.5795 24 HAlO2,aq 0.78822E-14 -14.1034 0.78822E-14 -14.1034 0.10000E+01 0.0000 25 AlO2- 0.29444E-18 -18.5310 0.20657E-18 -18.6849 0.70157E+00 -0.1539 26 CH4,aq 0.11085E-06 -6.9553 0.10394E-06 -6.9832 0.93765E+00 -0.0280 27 C2H6,aq 0.18594E-15 -15.7306 0.17435E-15 -15.7586 0.93765E+00 -0.0280 31 CO,aq 0.10145E-09 -9.9938 0.10145E-09 -9.9938 0.10000E+01 0.0000 32 CO2,aq 0.40482E+00 -0.3927 0.37959E+00 -0.4207 0.93765E+00 -0.0280 33 CO3-2 0.80117E-14 -14.0963 0.21654E-14 -14.6645 0.27028E+00 -0.5682 34 CaCO3,aq 0.99575E-18 -18.0019 0.99575E-18 -18.0019 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.27610E-11 -11.5589 0.19602E-11 -11.7077 0.70998E+00 -0.1488 36 CaCl+ 0.77334E-08 -8.1116 0.54906E-08 -8.2604 0.70998E+00 -0.1488 37 CaCl2,aq 0.12068E-09 -9.9184 0.12068E-09 -9.9184 0.10000E+01 0.0000 38 CaF+ 0.11709E-10 -10.9315 0.83133E-11 -11.0802 0.70998E+00 -0.1488 39 CaOH+ 0.43394E-16 -16.3626 0.30809E-16 -16.5113 0.70998E+00 -0.1488 40 CaSO4,aq 0.52583E-16 -16.2792 0.52583E-16 -16.2792 0.10000E+01 0.0000 41 HCl,aq 0.14319E-02 -2.8441 0.14319E-02 -2.8441 0.10000E+01 0.0000 45 HF,aq 0.89777E-02 -2.0468 0.89777E-02 -2.0468 0.10000E+01 0.0000 46 HF2- 0.66703E-07 -7.1759 0.47062E-07 -7.3273 0.70554E+00 -0.1515 47 Fe+3 0.71079E-17 -17.1483 0.37910E-18 -18.4212 0.53334E-01 -1.2730 48 FeCl+ 0.11732E-08 -8.9306 0.83295E-09 -9.0794 0.70998E+00 -0.1488 49 FeCl2,aq 0.24397E-14 -14.6127 0.24397E-14 -14.6127 0.10000E+01 0.0000 50 FeCl+2 0.95163E-17 -17.0215 0.25059E-17 -17.6010 0.26332E+00 -0.5795 51 FeF+ 0.63567E-11 -11.1968 0.45132E-11 -11.3455 0.70998E+00 -0.1488 52 FeF+2 0.19922E-15 -15.7007 0.52459E-16 -16.2802 0.26332E+00 -0.5795 54 FeOH+ 0.30741E-14 -14.5123 0.21826E-14 -14.6610 0.70998E+00 -0.1488 56 FeO+ 0.71244E-19 -19.1473 0.50582E-19 -19.2960 0.70998E+00 -0.1488 57 FeOH+2 0.30985E-17 -17.5088 0.81591E-18 -18.0884 0.26332E+00 -0.5795 60 H2,aq 0.11297E-07 -7.9471 0.10592E-07 -7.9750 0.93765E+00 -0.0280 61 KCl,aq 0.11799E-06 -6.9282 0.11799E-06 -6.9282 0.10000E+01 0.0000 62 KHSO4,aq 0.75880E-16 -16.1199 0.75880E-16 -16.1199 0.10000E+01 0.0000 63 KOH,aq 0.35423E-15 -15.4507 0.35423E-15 -15.4507 0.10000E+01 0.0000 64 KSO4- 0.69882E-14 -14.1556 0.49305E-14 -14.3071 0.70554E+00 -0.1515 66 Mg(HCO3)+ 0.11237E-14 -14.9494 0.79778E-15 -15.0981 0.70998E+00 -0.1488 67 MgCl+ 0.27917E-11 -11.5541 0.19821E-11 -11.7029 0.70998E+00 -0.1488 68 MgF+ 0.17276E-13 -13.7626 0.12266E-13 -13.9113 0.70998E+00 -0.1488 69 MgOH+ 0.95638E-19 -19.0194 0.67902E-19 -19.1681 0.70998E+00 -0.1488 71 MnF+ 0.12643E-12 -12.8981 0.89764E-13 -13.0469 0.70998E+00 -0.1488 73 MnOH+ 0.17232E-16 -16.7637 0.12234E-16 -16.9124 0.70998E+00 -0.1488 78 MnCl+ 0.27542E-09 -9.5600 0.19554E-09 -9.7088 0.70998E+00 -0.1488 79 MnSO4,aq 0.44742E-18 -18.3493 0.44742E-18 -18.3493 0.10000E+01 0.0000 80 NaCl,aq 0.29790E-03 -3.5259 0.29790E-03 -3.5259 0.10000E+01 0.0000 81 NaF,aq 0.35319E-07 -7.4520 0.35319E-07 -7.4520 0.10000E+01 0.0000 82 NaOH,aq 0.49208E-13 -13.3080 0.49208E-13 -13.3080 0.10000E+01 0.0000 84 OH- 0.97075E-11 -11.0129 0.68105E-11 -11.1668 0.70157E+00 -0.1539 90 H3PO3,aq 0.29532E-19 -19.5297 0.29532E-19 -19.5297 0.10000E+01 0.0000 92 H3PO4,aq 0.28075E-07 -7.5517 0.28075E-07 -7.5517 0.10000E+01 0.0000 93 H2PO4- 0.12386E-08 -8.9071 0.87670E-09 -9.0571 0.70784E+00 -0.1501 95 H4P2O7,aq 0.10437E-16 -16.9814 0.10437E-16 -16.9814 0.10000E+01 0.0000 96 H3P2O7- 0.22361E-17 -17.6505 0.15777E-17 -17.8020 0.70554E+00 -0.1515 97 H2P2O7-2 0.22396E-18 -18.6498 0.60531E-19 -19.2180 0.27028E+00 -0.5682 100 H2S,aq 0.64516E-01 -1.1903 0.60494E-01 -1.2183 0.93765E+00 -0.0280 101 S2-2 0.41563E-15 -15.3813 0.11234E-15 -15.9495 0.27028E+00 -0.5682 102 S3-2 0.31980E-14 -14.4951 0.86437E-15 -15.0633 0.27028E+00 -0.5682 103 S3- 0.67397E-09 -9.1714 0.47551E-09 -9.3228 0.70554E+00 -0.1515 104 S4-2 0.16255E-13 -13.7890 0.43933E-14 -14.3572 0.27028E+00 -0.5682 105 S5-2 0.55090E-13 -13.2589 0.14890E-13 -13.8271 0.27028E+00 -0.5682 106 SO2,aq 0.15373E-11 -11.8133 0.15373E-11 -11.8133 0.10000E+01 0.0000 107 SO3-2 0.21963E-19 -19.6583 0.62424E-20 -20.2046 0.28422E+00 -0.5463 108 HSO3- 0.46791E-13 -13.3298 0.33013E-13 -13.4813 0.70554E+00 -0.1515 109 HSO4- 0.51571E-09 -9.2876 0.36755E-09 -9.4347 0.71270E+00 -0.1471 111 S2O3-2 0.11924E-13 -13.9236 0.32227E-14 -14.4918 0.27028E+00 -0.5682 112 HS2O3- 0.68984E-13 -13.1613 0.48671E-13 -13.3127 0.70554E+00 -0.1515 113 H2S2O3,aq 0.65904E-13 -13.1811 0.65904E-13 -13.1811 0.10000E+01 0.0000 Charge balance for all species = -.3873E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1172522E+00 0.5970029E+00 0.5868099E+03 0.0000 2 H2O 0.1000000E+01 0.5510343E+02 0.9680692E+06 0.0000 3 Cl- 0.1311243E+00 0.1328542E+00 0.4593193E+04 0.0395 4 SO4-- 0.1658259E-10 -.1127407E-06 -.1056129E-01 -9.1987 5 HCO3- 0.2952959E-05 0.4048277E+00 0.2408845E+05 -4.6057 6 HS- 0.3282854E-06 0.6451671E-01 0.2080745E+04 -5.5617 7 Al+++ 0.3352488E-05 0.3357856E-05 0.8835161E-01 -3.5324 8 H4SiO4 0.1015691E-02 0.1015691E-02 0.9520086E+02 -2.9932 9 Ca++ 0.1384483E-06 0.1463168E-06 0.5718560E-02 -5.2890 10 Mg++ 0.5603298E-10 0.5884308E-10 0.1395090E-05 -8.6888 11 Fe++ 0.2173816E-07 0.2291771E-07 0.1248123E-02 -6.0984 12 K+ 0.9918945E-04 0.9930744E-04 0.3786754E+01 -3.0793 13 Na+ 0.1378796E-01 0.1408589E-01 0.3157954E+03 -0.9392 14 Mn++ 0.1307941E-08 0.1583483E-08 0.8483449E-04 -7.3178 15 F- 0.2214491E-04 0.8999990E-02 0.1667386E+03 -3.7356 16 HPO4-- 0.2065346E-14 0.2931364E-07 0.2743672E-02 -13.1031 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3425572E+01 0.8490235E+00 0.7639537E+00 0.1812595E+01 2 H2O 0.7604480E+02 0.7836496E+02 -.6325801E+00 -.1687578E+01 3 Cl- 0.1889378E+00 0.1889377E+00 0.0000000E+00 0.9413768E-07 4 SO4-- 0.1527850E+00 -.1603334E-06 0.1527907E+00 -.5621104E-05 5 HCO3- 0.2313612E+01 0.5757230E+00 0.0000000E+00 0.1737889E+01 6 HS- 0.6248403E+00 0.9175199E-01 0.4583722E+00 0.7471605E-01 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1444458E-02 0.1070856E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1280010E-01 0.1279927E-01 0.0000000E+00 0.8212907E-06 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1967E-16 Mass of aqueous solution: 0.145833E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 31.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.5030E-01 -1.298 0.9059 -0.043 1.133 19.99 CO2,gas 1.738 0.240 76.48 1.884 95.68 936.0 CH4,gas 0.5494E-05 -5.260 0.8812E-04 -4.055 0.1102E-03 0.3547E-02 H2,gas 0.5045E-06 -6.297 0.1019E-05 -5.992 0.1275E-05 0.3214E-03 H2S,gas 0.7471E-01 -1.127 2.546 0.406 3.185 38.03 S2,gas 0.2000E-10 -10.699 0.1282E-08 -8.892 0.1604E-08 0.1241E-07 CO,gas 0.5632E-08 -8.249 0.1578E-06 -6.802 0.1974E-06 0.3495E-05 SO3,gas 0.4558E-30 -30.341 0.3649E-28 -28.438 0.4565E-28 0.2828E-27 SO2,gas 0.2477E-12 -12.606 0.1587E-10 -10.800 0.1985E-10 0.1537E-09 HF,gas 0.8213E-06 -6.086 0.1643E-04 -4.784 0.2055E-04 0.5096E-03 HCl,gas 0.9414E-07 -7.026 0.3432E-05 -5.464 0.4294E-05 0.5841E-04 quartz 0.1071E-01 -1.970 0.6434 -0.192 3.179 0.2430 sulfur 0.6112 -0.214 19.59 1.292 96.82 9.479 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2700E-01 0.1350E+01 0.7419 0.001 CO2,gas 0.9329E+00 0.4664E+02 0.8707 1.609 CH4,gas 0.2949E-05 0.1474E-03 1.0376 -3.815 H2,gas 0.2708E-06 0.1354E-04 1.0270 -4.857 H2S,gas 0.4010E-01 0.2005E+01 0.8293 0.221 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.3023E-08 0.1512E-06 1.0000 -6.821 SO3,gas 0.2447E-30 0.1223E-28 1.0000 -28.912 SO2,gas 0.1330E-12 0.6648E-11 1.0000 -11.177 HF,gas 0.4409E-06 0.2204E-04 1.0000 -4.657 HCl,gas 0.5053E-07 0.2527E-05 1.0000 -5.597 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 5.129035 % Solid products produced: Mass = 20.237256 g Volume = 9.722348 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 31.9999900 moles log = 1.5051 Original solution: 1000.0103000 g Original solution / Rock added: 31.25 (Water/Rock Ratio), log = 1.4949 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 0.00000E+00 2 CO2,gas -6.66 -6.66 0.00 0.000 0.00000E+00 3 CH4,gas 4.54 4.54 0.00 0.000 -0.15165E-11 4 H2,gas 8.00 8.00 0.00 0.000 0.00000E+00 5 H2S,gas -6.23 -6.23 0.00 0.000 -0.15165E-11 6 S2,gas -7.34 -7.34 0.00 0.000 -0.60662E-11 7 CO,gas 3.21 3.21 0.00 0.000 -0.75827E-12 8 SO3,gas 17.12 17.12 0.00 0.000 0.00000E+00 9 SO2,gas 0.83 0.83 0.00 0.000 -0.34122E-11 10 HF,gas 0.47 0.47 0.00 0.000 -0.11374E-11 11 HCl,gas 5.19 5.19 0.00 0.000 -0.15165E-11 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 172 sulfur -9.15 -9.15 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.86 -0.76 -0.216 0.12913E+04 89 graphite -3.55 -3.86 -0.31 -0.089 0.53352E+03 92 halite 1.57 -3.05 -4.62 -2.310 0.78900E+04 145 pyrite -21.25 -22.96 -1.71 -0.403 0.29234E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 31.9999900 MOLES New total amount of reactant added: 32.9999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 21 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 32.9999900 Water: Moles liquid = 0.7985E+02 kg liquid = 0.1439E+01 Moles total = 0.7686E+02 kg total = 0.1385E+01 Activity = 0.9955 Stoichiometric ionic strength = .3165387E+00 Osmotic coef. = 0.9148 True ionic strength = .1336934E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.1948E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11995E+00 -0.9210 0.86261E-01 -1.0642 0.71915E+00 -0.1432 2 H2O 0.99555E+00 -0.0019 0.99555E+00 -0.0019 3 Cl- 0.13366E+00 -0.8740 0.94123E-01 -1.0263 0.70421E+00 -0.1523 4 SO4-- 0.15666E-10 -10.8051 0.42321E-11 -11.3734 0.27015E+00 -0.5684 5 HCO3- 0.28956E-05 -5.5383 0.20496E-05 -5.6883 0.70781E+00 -0.1501 6 HS- 0.32446E-06 -6.4888 0.22861E-06 -6.6409 0.70456E+00 -0.1521 7 Al+++ 0.33145E-05 -5.4796 0.17170E-06 -6.7652 0.51803E-01 -1.2856 8 H4SiO4 0.10155E-02 -2.9933 0.10155E-02 -2.9933 0.10000E+01 0.0000 9 Ca++ 0.13679E-06 -6.8639 0.35939E-07 -7.4444 0.26273E+00 -0.5805 10 Mg++ 0.55367E-10 -10.2567 0.14314E-10 -10.8443 0.25852E+00 -0.5875 11 Fe++ 0.21479E-07 -7.6680 0.55740E-08 -8.2538 0.25951E+00 -0.5858 12 K+ 0.98060E-04 -4.0085 0.69439E-04 -4.1584 0.70813E+00 -0.1499 13 Na+ 0.13627E-01 -1.8656 0.95844E-02 -2.0184 0.70336E+00 -0.1528 14 Mn++ 0.12906E-08 -8.8892 0.33590E-09 -9.4738 0.26026E+00 -0.5846 15 F- 0.22151E-04 -4.6546 0.15501E-04 -4.8097 0.69978E+00 -0.1550 16 HPO4-- 0.19748E-14 -14.7045 0.53377E-15 -15.2726 0.27029E+00 -0.5682 17 SiF6-2 0.94049E-11 -11.0266 0.25218E-11 -11.5983 0.26814E+00 -0.5716 18 HSiO3- 0.15680E-10 -10.8047 0.11042E-10 -10.9570 0.70421E+00 -0.1523 19 Ca(HSiO3)+ 0.12752E-16 -16.8944 0.90373E-17 -17.0440 0.70868E+00 -0.1495 21 NaHSiO3,aq 0.17116E-11 -11.7666 0.17116E-11 -11.7666 0.10000E+01 0.0000 22 AlO+ 0.44099E-11 -11.3556 0.31252E-11 -11.5051 0.70868E+00 -0.1495 23 AlOH+2 0.51400E-08 -8.2890 0.13424E-08 -8.8721 0.26116E+00 -0.5831 24 HAlO2,aq 0.71830E-14 -14.1437 0.71830E-14 -14.1437 0.10000E+01 0.0000 25 AlO2- 0.26324E-18 -18.5797 0.18433E-18 -18.7344 0.70023E+00 -0.1548 26 CH4,aq 0.11420E-06 -6.9423 0.10706E-06 -6.9704 0.93748E+00 -0.0280 27 C2H6,aq 0.19587E-15 -15.7080 0.18363E-15 -15.7361 0.93748E+00 -0.0280 31 CO,aq 0.10218E-09 -9.9906 0.10218E-09 -9.9906 0.10000E+01 0.0000 32 CO2,aq 0.40477E+00 -0.3928 0.37946E+00 -0.4208 0.93748E+00 -0.0280 33 CO3-2 0.77398E-14 -14.1113 0.20753E-14 -14.6829 0.26814E+00 -0.5716 34 CaCO3,aq 0.93523E-18 -18.0291 0.93523E-18 -18.0291 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.26531E-11 -11.5762 0.18802E-11 -11.7258 0.70868E+00 -0.1495 36 CaCl+ 0.77246E-08 -8.1121 0.54743E-08 -8.2617 0.70868E+00 -0.1495 37 CaCl2,aq 0.12241E-09 -9.9122 0.12241E-09 -9.9122 0.10000E+01 0.0000 38 CaF+ 0.11477E-10 -10.9402 0.81334E-11 -11.0897 0.70868E+00 -0.1495 39 CaOH+ 0.41713E-16 -16.3797 0.29561E-16 -16.5293 0.70868E+00 -0.1495 40 CaSO4,aq 0.48299E-16 -16.3161 0.48299E-16 -16.3161 0.10000E+01 0.0000 41 HCl,aq 0.14878E-02 -2.8275 0.14878E-02 -2.8275 0.10000E+01 0.0000 45 HF,aq 0.91533E-02 -2.0384 0.91533E-02 -2.0384 0.10000E+01 0.0000 46 HF2- 0.68024E-07 -7.1673 0.47903E-07 -7.3196 0.70421E+00 -0.1523 47 Fe+3 0.72163E-17 -17.1417 0.37797E-18 -18.4225 0.52377E-01 -1.2809 48 FeCl+ 0.11718E-08 -8.9312 0.83042E-09 -9.0807 0.70868E+00 -0.1495 49 FeCl2,aq 0.24746E-14 -14.6065 0.24746E-14 -14.6065 0.10000E+01 0.0000 50 FeCl+2 0.97330E-17 -17.0118 0.25419E-17 -17.5948 0.26116E+00 -0.5831 51 FeF+ 0.62301E-11 -11.2055 0.44152E-11 -11.3551 0.70868E+00 -0.1495 52 FeF+2 0.19994E-15 -15.6991 0.52216E-16 -16.2822 0.26116E+00 -0.5831 54 FeOH+ 0.29548E-14 -14.5295 0.20940E-14 -14.6790 0.70868E+00 -0.1495 56 FeO+ 0.68225E-19 -19.1661 0.48349E-19 -19.3156 0.70868E+00 -0.1495 57 FeOH+2 0.30497E-17 -17.5157 0.79648E-18 -18.0988 0.26116E+00 -0.5831 60 H2,aq 0.11383E-07 -7.9437 0.10671E-07 -7.9718 0.93748E+00 -0.0280 61 KCl,aq 0.11846E-06 -6.9264 0.11846E-06 -6.9264 0.10000E+01 0.0000 62 KHSO4,aq 0.71674E-16 -16.1446 0.71674E-16 -16.1446 0.10000E+01 0.0000 63 KOH,aq 0.34224E-15 -15.4657 0.34224E-15 -15.4657 0.10000E+01 0.0000 64 KSO4- 0.64756E-14 -14.1887 0.45602E-14 -14.3410 0.70421E+00 -0.1523 66 Mg(HCO3)+ 0.10797E-14 -14.9667 0.76518E-15 -15.1162 0.70868E+00 -0.1495 67 MgCl+ 0.27884E-11 -11.5547 0.19761E-11 -11.7042 0.70868E+00 -0.1495 68 MgF+ 0.16932E-13 -13.7713 0.11999E-13 -13.9208 0.70868E+00 -0.1495 69 MgOH+ 0.91928E-19 -19.0366 0.65147E-19 -19.1861 0.70868E+00 -0.1495 71 MnF+ 0.12375E-12 -12.9075 0.87700E-13 -13.0570 0.70868E+00 -0.1495 73 MnOH+ 0.16542E-16 -16.7814 0.11723E-16 -16.9310 0.70868E+00 -0.1495 78 MnCl+ 0.27472E-09 -9.5611 0.19469E-09 -9.7107 0.70868E+00 -0.1495 79 MnSO4,aq 0.41040E-18 -18.3868 0.41040E-18 -18.3868 0.10000E+01 0.0000 80 NaCl,aq 0.29896E-03 -3.5244 0.29896E-03 -3.5244 0.10000E+01 0.0000 81 NaF,aq 0.34781E-07 -7.4587 0.34781E-07 -7.4587 0.10000E+01 0.0000 82 NaOH,aq 0.47525E-13 -13.3231 0.47525E-13 -13.3231 0.10000E+01 0.0000 84 OH- 0.95228E-11 -11.0212 0.66681E-11 -11.1760 0.70023E+00 -0.1548 90 H3PO3,aq 0.29441E-19 -19.5311 0.29441E-19 -19.5311 0.10000E+01 0.0000 92 H3PO4,aq 0.27778E-07 -7.5563 0.27778E-07 -7.5563 0.10000E+01 0.0000 93 H2PO4- 0.12022E-08 -8.9200 0.84937E-09 -9.0709 0.70652E+00 -0.1509 95 H4P2O7,aq 0.10219E-16 -16.9906 0.10219E-16 -16.9906 0.10000E+01 0.0000 96 H3P2O7- 0.21477E-17 -17.6680 0.15124E-17 -17.8203 0.70421E+00 -0.1523 97 H2P2O7-2 0.21191E-18 -18.6739 0.56821E-19 -19.2455 0.26814E+00 -0.5716 100 H2S,aq 0.65011E-01 -1.1870 0.60946E-01 -1.2151 0.93748E+00 -0.0280 101 S2-2 0.40469E-15 -15.3929 0.10851E-15 -15.9645 0.26814E+00 -0.5716 102 S3-2 0.31139E-14 -14.5067 0.83495E-15 -15.0783 0.26814E+00 -0.5716 103 S3- 0.66365E-09 -9.1781 0.46735E-09 -9.3304 0.70421E+00 -0.1523 104 S4-2 0.15827E-13 -13.8006 0.42438E-14 -14.3722 0.26814E+00 -0.5716 105 S5-2 0.53640E-13 -13.2705 0.14383E-13 -13.8421 0.26814E+00 -0.5716 106 SO2,aq 0.15143E-11 -11.8198 0.15143E-11 -11.8198 0.10000E+01 0.0000 107 SO3-2 0.20896E-19 -19.6799 0.58952E-20 -20.2295 0.28211E+00 -0.5496 108 HSO3- 0.45213E-13 -13.3447 0.31840E-13 -13.4970 0.70421E+00 -0.1523 109 HSO4- 0.49453E-09 -9.3058 0.35182E-09 -9.4537 0.71143E+00 -0.1479 111 S2O3-2 0.11350E-13 -13.9450 0.30434E-14 -14.5166 0.26814E+00 -0.5716 112 HS2O3- 0.66658E-13 -13.1762 0.46941E-13 -13.3284 0.70421E+00 -0.1523 113 H2S2O3,aq 0.64913E-13 -13.1877 0.64913E-13 -13.1877 0.10000E+01 0.0000 Charge balance for all species = -.3829E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1199482E+00 0.6003725E+00 0.5900593E+03 0.0000 2 H2O 0.1000000E+01 0.5510348E+02 0.9679673E+06 0.0000 3 Cl- 0.1336578E+00 0.1354447E+00 0.4682256E+04 0.0379 4 SO4-- 0.1566558E-10 -.1161483E-06 -.1087934E-01 -9.2451 5 HCO3- 0.2895638E-05 0.4047751E+00 0.2408276E+05 -4.6242 6 HS- 0.3244645E-06 0.6501139E-01 0.2096477E+04 -5.5767 7 Al+++ 0.3314521E-05 0.3319666E-05 0.8733748E-01 -3.5727 8 H4SiO4 0.1015517E-02 0.1015518E-02 0.9517449E+02 -2.9933 9 Ca++ 0.1367916E-06 0.1446527E-06 0.5652920E-02 -5.3161 10 Mg++ 0.5536746E-10 0.5817383E-10 0.1379077E-05 -8.7159 11 Fe++ 0.2147904E-07 0.2265706E-07 0.1233797E-02 -6.1255 12 K+ 0.9805952E-04 0.9817798E-04 0.3743288E+01 -3.0942 13 Na+ 0.1362669E-01 0.1392568E-01 0.3121705E+03 -0.9542 14 Mn++ 0.1290625E-08 0.1565473E-08 0.8386073E-04 -7.3454 15 F- 0.2215072E-04 0.9175663E-02 0.1699752E+03 -3.7455 16 HPO4-- 0.1974783E-14 0.2898024E-07 0.2712179E-02 -13.1443 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3533247E+01 0.8636382E+00 0.7878307E+00 0.1881778E+01 2 H2O 0.7686350E+02 0.7926656E+02 -.6516490E+00 -.1751415E+01 3 Cl- 0.1948378E+00 0.1948377E+00 0.0000000E+00 0.1015451E-06 4 SO4-- 0.1575600E+00 -.1670797E-06 0.1575661E+00 -.6008238E-05 5 HCO3- 0.2385912E+01 0.5822705E+00 0.0000000E+00 0.1803642E+01 6 HS- 0.6443653E+00 0.9351913E-01 0.4726984E+00 0.7814774E-01 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1460826E-02 0.1069219E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1320010E-01 0.1319923E-01 0.0000000E+00 0.8693193E-06 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.9101E-16 Mass of aqueous solution: 0.147527E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 32.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.5221E-01 -1.282 0.9404 -0.027 1.133 20.75 CO2,gas 1.804 0.256 79.38 1.900 95.66 971.4 CH4,gas 0.5875E-05 -5.231 0.9423E-04 -4.026 0.1136E-03 0.3793E-02 H2,gas 0.5277E-06 -6.278 0.1066E-05 -5.972 0.1284E-05 0.3361E-03 H2S,gas 0.7814E-01 -1.107 2.663 0.425 3.209 39.78 S2,gas 0.2076E-10 -10.683 0.1331E-08 -8.876 0.1604E-08 0.1288E-07 CO,gas 0.5890E-08 -8.230 0.1650E-06 -6.783 0.1988E-06 0.3655E-05 SO3,gas 0.4626E-30 -30.335 0.3704E-28 -28.431 0.4464E-28 0.2871E-27 SO2,gas 0.2533E-12 -12.596 0.1623E-10 -10.790 0.1955E-10 0.1572E-09 HF,gas 0.8693E-06 -6.061 0.1739E-04 -4.760 0.2095E-04 0.5394E-03 HCl,gas 0.1015E-06 -6.993 0.3702E-05 -5.432 0.4462E-05 0.6301E-04 quartz 0.1069E-01 -1.971 0.6424 -0.192 3.081 0.2426 sulfur 0.6303 -0.200 20.21 1.305 96.92 9.776 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2700E-01 0.1350E+01 0.7419 0.001 CO2,gas 0.9326E+00 0.4663E+02 0.8707 1.609 CH4,gas 0.3038E-05 0.1519E-03 1.0376 -3.802 H2,gas 0.2728E-06 0.1364E-04 1.0270 -4.854 H2S,gas 0.4040E-01 0.2020E+01 0.8293 0.224 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.3045E-08 0.1523E-06 1.0000 -6.817 SO3,gas 0.2392E-30 0.1196E-28 1.0000 -28.922 SO2,gas 0.1310E-12 0.6548E-11 1.0000 -11.184 HF,gas 0.4495E-06 0.2247E-04 1.0000 -4.648 HCl,gas 0.5251E-07 0.2625E-05 1.0000 -5.581 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 5.254999 % Solid products produced: Mass = 20.848669 g Volume = 10.018250 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 32.9999900 moles log = 1.5185 Original solution: 1000.0103000 g Original solution / Rock added: 30.30 (Water/Rock Ratio), log = 1.4815 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 0.37914E-12 2 CO2,gas -6.66 -6.66 0.00 0.000 0.00000E+00 3 CH4,gas 4.54 4.54 0.00 0.000 0.15165E-11 4 H2,gas 8.00 8.00 0.00 0.000 -0.15165E-11 5 H2S,gas -6.23 -6.23 0.00 0.000 -0.15165E-11 6 S2,gas -7.34 -7.34 0.00 0.000 0.00000E+00 7 CO,gas 3.21 3.21 0.00 0.000 -0.75827E-12 8 SO3,gas 17.12 17.12 0.00 0.000 0.00000E+00 9 SO2,gas 0.83 0.83 0.00 0.000 0.26539E-11 10 HF,gas 0.47 0.47 0.00 0.000 -0.11374E-11 11 HCl,gas 5.19 5.19 0.00 0.000 0.00000E+00 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 172 sulfur -9.15 -9.15 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.85 -0.75 -0.214 0.12803E+04 89 graphite -3.55 -3.85 -0.31 -0.087 0.52258E+03 92 halite 1.57 -3.04 -4.62 -2.310 0.78873E+04 145 pyrite -21.25 -22.98 -1.74 -0.408 0.29641E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 32.9999900 MOLES New total amount of reactant added: 33.9999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 21 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 33.9999900 Water: Moles liquid = 0.8076E+02 kg liquid = 0.1455E+01 Moles total = 0.7768E+02 kg total = 0.1399E+01 Activity = 0.9955 Stoichiometric ionic strength = .3180340E+00 Osmotic coef. = 0.9148 True ionic strength = .1361690E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2007E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12258E+00 -0.9116 0.88012E-01 -1.0555 0.71798E+00 -0.1439 2 H2O 0.99546E+00 -0.0020 0.99546E+00 -0.0020 3 Cl- 0.13613E+00 -0.8660 0.95693E-01 -1.0191 0.70294E+00 -0.1531 4 SO4-- 0.14840E-10 -10.8286 0.39788E-11 -11.4002 0.26812E+00 -0.5717 5 HCO3- 0.28419E-05 -5.5464 0.20080E-05 -5.6972 0.70656E+00 -0.1509 6 HS- 0.32084E-06 -6.4937 0.22564E-06 -6.6466 0.70329E+00 -0.1529 7 Al+++ 0.32774E-05 -5.4845 0.16683E-06 -6.7777 0.50903E-01 -1.2933 8 H4SiO4 0.10153E-02 -2.9934 0.10153E-02 -2.9934 0.10000E+01 0.0000 9 Ca++ 0.13517E-06 -6.8691 0.35236E-07 -7.4530 0.26067E+00 -0.5839 10 Mg++ 0.54718E-10 -10.2619 0.14033E-10 -10.8529 0.25645E+00 -0.5910 11 Fe++ 0.21226E-07 -7.6731 0.54645E-08 -8.2624 0.25744E+00 -0.5893 12 K+ 0.96955E-04 -4.0134 0.68535E-04 -4.1641 0.70687E+00 -0.1507 13 Na+ 0.13469E-01 -1.8707 0.94563E-02 -2.0243 0.70207E+00 -0.1536 14 Mn++ 0.12738E-08 -8.8949 0.32889E-09 -9.4829 0.25820E+00 -0.5880 15 F- 0.22158E-04 -4.6545 0.15477E-04 -4.8103 0.69849E+00 -0.1558 16 HPO4-- 0.18913E-14 -14.7232 0.50735E-15 -15.2947 0.26825E+00 -0.5715 17 SiF6-2 0.10179E-10 -10.9923 0.27087E-11 -11.5672 0.26610E+00 -0.5750 18 HSiO3- 0.15394E-10 -10.8126 0.10821E-10 -10.9657 0.70294E+00 -0.1531 19 Ca(HSiO3)+ 0.12275E-16 -16.9110 0.86835E-17 -17.0613 0.70743E+00 -0.1503 21 NaHSiO3,aq 0.16550E-11 -11.7812 0.16550E-11 -11.7812 0.10000E+01 0.0000 22 AlO+ 0.41229E-11 -11.3848 0.29167E-11 -11.5351 0.70743E+00 -0.1503 23 AlOH+2 0.49333E-08 -8.3069 0.12782E-08 -8.8934 0.25910E+00 -0.5865 24 HAlO2,aq 0.65697E-14 -14.1825 0.65697E-14 -14.1825 0.10000E+01 0.0000 25 AlO2- 0.23641E-18 -18.6263 0.16523E-18 -18.7819 0.69894E+00 -0.1556 26 CH4,aq 0.11748E-06 -6.9300 0.11011E-06 -6.9582 0.93730E+00 -0.0281 27 C2H6,aq 0.20578E-15 -15.6866 0.19288E-15 -15.7147 0.93730E+00 -0.0281 31 CO,aq 0.10288E-09 -9.9877 0.10288E-09 -9.9877 0.10000E+01 0.0000 32 CO2,aq 0.40472E+00 -0.3928 0.37935E+00 -0.4210 0.93730E+00 -0.0281 33 CO3-2 0.74890E-14 -14.1256 0.19928E-14 -14.7005 0.26610E+00 -0.5750 34 CaCO3,aq 0.88045E-18 -18.0553 0.88045E-18 -18.0553 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.25530E-11 -11.5930 0.18061E-11 -11.7433 0.70743E+00 -0.1503 36 CaCl+ 0.77134E-08 -8.1128 0.54567E-08 -8.2631 0.70743E+00 -0.1503 37 CaCl2,aq 0.12406E-09 -9.9064 0.12406E-09 -9.9064 0.10000E+01 0.0000 38 CaF+ 0.11255E-10 -10.9487 0.79621E-11 -11.0990 0.70743E+00 -0.1503 39 CaOH+ 0.40150E-16 -16.3963 0.28403E-16 -16.5466 0.70743E+00 -0.1503 40 CaSO4,aq 0.44519E-16 -16.3515 0.44519E-16 -16.3515 0.10000E+01 0.0000 41 HCl,aq 0.15433E-02 -2.8115 0.15433E-02 -2.8115 0.10000E+01 0.0000 45 HF,aq 0.93251E-02 -2.0303 0.93251E-02 -2.0303 0.10000E+01 0.0000 46 HF2- 0.69320E-07 -7.1591 0.48728E-07 -7.3122 0.70294E+00 -0.1531 47 Fe+3 0.73192E-17 -17.1355 0.37674E-18 -18.4240 0.51473E-01 -1.2884 48 FeCl+ 0.11700E-08 -8.9318 0.82770E-09 -9.0821 0.70743E+00 -0.1503 49 FeCl2,aq 0.25076E-14 -14.6007 0.25076E-14 -14.6007 0.10000E+01 0.0000 50 FeCl+2 0.99416E-17 -17.0025 0.25759E-17 -17.5891 0.25910E+00 -0.5865 51 FeF+ 0.61093E-11 -11.2140 0.43219E-11 -11.3643 0.70743E+00 -0.1503 52 FeF+2 0.20057E-15 -15.6977 0.51967E-16 -16.2843 0.25910E+00 -0.5865 54 FeOH+ 0.28439E-14 -14.5461 0.20119E-14 -14.6964 0.70743E+00 -0.1503 56 FeO+ 0.65433E-19 -19.1842 0.46289E-19 -19.3345 0.70743E+00 -0.1503 57 FeOH+2 0.30028E-17 -17.5225 0.77802E-18 -18.1090 0.25910E+00 -0.5865 60 H2,aq 0.11466E-07 -7.9406 0.10747E-07 -7.9687 0.93730E+00 -0.0281 61 KCl,aq 0.11886E-06 -6.9249 0.11886E-06 -6.9249 0.10000E+01 0.0000 62 KHSO4,aq 0.67858E-16 -16.1684 0.67858E-16 -16.1684 0.10000E+01 0.0000 63 KOH,aq 0.33104E-15 -15.4801 0.33104E-15 -15.4801 0.10000E+01 0.0000 64 KSO4- 0.60197E-14 -14.2204 0.42315E-14 -14.3735 0.70294E+00 -0.1531 66 Mg(HCO3)+ 0.10389E-14 -14.9834 0.73495E-15 -15.1337 0.70743E+00 -0.1503 67 MgCl+ 0.27841E-11 -11.5553 0.19696E-11 -11.7056 0.70743E+00 -0.1503 68 MgF+ 0.16604E-13 -13.7798 0.11746E-13 -13.9301 0.70743E+00 -0.1503 69 MgOH+ 0.88479E-19 -19.0532 0.62593E-19 -19.2035 0.70743E+00 -0.1503 71 MnF+ 0.12120E-12 -12.9165 0.85739E-13 -13.0668 0.70743E+00 -0.1503 73 MnOH+ 0.15901E-16 -16.7986 0.11249E-16 -16.9489 0.70743E+00 -0.1503 78 MnCl+ 0.27396E-09 -9.5623 0.19381E-09 -9.7126 0.70743E+00 -0.1503 79 MnSO4,aq 0.37779E-18 -18.4228 0.37779E-18 -18.4228 0.10000E+01 0.0000 80 NaCl,aq 0.29989E-03 -3.5230 0.29989E-03 -3.5230 0.10000E+01 0.0000 81 NaF,aq 0.34265E-07 -7.4652 0.34265E-07 -7.4652 0.10000E+01 0.0000 82 NaOH,aq 0.45953E-13 -13.3377 0.45953E-13 -13.3377 0.10000E+01 0.0000 84 OH- 0.93498E-11 -11.0292 0.65349E-11 -11.1848 0.69894E+00 -0.1556 90 H3PO3,aq 0.29340E-19 -19.5325 0.29340E-19 -19.5325 0.10000E+01 0.0000 92 H3PO4,aq 0.27486E-07 -7.5609 0.27486E-07 -7.5609 0.10000E+01 0.0000 93 H2PO4- 0.11680E-08 -8.9326 0.82373E-09 -9.0842 0.70527E+00 -0.1516 95 H4P2O7,aq 0.10006E-16 -16.9997 0.10006E-16 -16.9997 0.10000E+01 0.0000 96 H3P2O7- 0.20649E-17 -17.6851 0.14515E-17 -17.8382 0.70294E+00 -0.1531 97 H2P2O7-2 0.20085E-18 -18.6971 0.53446E-19 -19.2721 0.26610E+00 -0.5750 100 H2S,aq 0.65484E-01 -1.1839 0.61378E-01 -1.2120 0.93730E+00 -0.0281 101 S2-2 0.39450E-15 -15.4039 0.10498E-15 -15.9789 0.26610E+00 -0.5750 102 S3-2 0.30355E-14 -14.5178 0.80773E-15 -15.0927 0.26610E+00 -0.5750 103 S3- 0.65393E-09 -9.1845 0.45967E-09 -9.3376 0.70294E+00 -0.1531 104 S4-2 0.15428E-13 -13.8117 0.41055E-14 -14.3866 0.26610E+00 -0.5750 105 S5-2 0.52290E-13 -13.2816 0.13914E-13 -13.8565 0.26610E+00 -0.5750 106 SO2,aq 0.14928E-11 -11.8260 0.14928E-11 -11.8260 0.10000E+01 0.0000 107 SO3-2 0.19929E-19 -19.7005 0.55821E-20 -20.2532 0.28010E+00 -0.5527 108 HSO3- 0.43761E-13 -13.3589 0.30761E-13 -13.5120 0.70294E+00 -0.1531 109 HSO4- 0.47519E-09 -9.3231 0.33748E-09 -9.4717 0.71021E+00 -0.1486 111 S2O3-2 0.10830E-13 -13.9654 0.28818E-14 -14.5403 0.26610E+00 -0.5750 112 HS2O3- 0.64516E-13 -13.1903 0.45350E-13 -13.3434 0.70294E+00 -0.1531 113 H2S2O3,aq 0.63987E-13 -13.1939 0.63987E-13 -13.1939 0.10000E+01 0.0000 Charge balance for all species = -.3786E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1225827E+00 0.6036578E+00 0.5932267E+03 0.0000 2 H2O 0.1000000E+01 0.5510353E+02 0.9678679E+06 0.0000 3 Cl- 0.1361336E+00 0.1379769E+00 0.4769300E+04 0.0363 4 SO4-- 0.1484006E-10 -.1194718E-06 -.1118949E-01 -9.2893 5 HCO3- 0.2841932E-05 0.4047261E+00 0.2407735E+05 -4.6418 6 HS- 0.3208400E-06 0.6548400E-01 0.2111499E+04 -5.5911 7 Al+++ 0.3277397E-05 0.3282335E-05 0.8634638E-01 -3.6114 8 H4SiO4 0.1015348E-02 0.1015348E-02 0.9514875E+02 -2.9934 9 Ca++ 0.1351748E-06 0.1430260E-06 0.5588771E-02 -5.3421 10 Mg++ 0.5471786E-10 0.5751964E-10 0.1363427E-05 -8.7419 11 Fe++ 0.2122616E-07 0.2240227E-07 0.1219796E-02 -6.1515 12 K+ 0.9695505E-04 0.9707392E-04 0.3700810E+01 -3.1086 13 Na+ 0.1346916E-01 0.1376908E-01 0.3086281E+03 -0.9688 14 Mn++ 0.1273788E-08 0.1547869E-08 0.8290908E-04 -7.3720 15 F- 0.2215803E-04 0.9347384E-02 0.1731383E+03 -3.7549 16 HPO4-- 0.1891321E-14 0.2865435E-07 0.2681402E-02 -13.1838 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3640922E+01 0.8782404E+00 0.8117077E+00 0.1950974E+01 2 H2O 0.7768220E+02 0.8016817E+02 -.6707178E+00 -.1815248E+01 3 Cl- 0.2007378E+00 0.2007377E+00 0.0000000E+00 0.1092081E-06 4 SO4-- 0.1623350E+00 -.1738152E-06 0.1623415E+00 -.6403718E-05 5 HCO3- 0.2458212E+01 0.5888216E+00 0.0000000E+00 0.1869391E+01 6 HS- 0.6638903E+00 0.9527035E-01 0.4870246E+00 0.8159531E-01 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1477194E-02 0.1067583E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1360010E-01 0.1359918E-01 0.0000000E+00 0.9181911E-06 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2623E-15 Mass of aqueous solution: 0.149220E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 33.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.5413E-01 -1.267 0.9749 -0.011 1.133 21.51 CO2,gas 1.869 0.272 82.27 1.915 95.63 1007. CH4,gas 0.6264E-05 -5.203 0.1005E-03 -3.998 0.1168E-03 0.4045E-02 H2,gas 0.5510E-06 -6.259 0.1113E-05 -5.954 0.1294E-05 0.3510E-03 H2S,gas 0.8159E-01 -1.088 2.781 0.444 3.232 41.54 S2,gas 0.2153E-10 -10.667 0.1380E-08 -8.860 0.1604E-08 0.1336E-07 CO,gas 0.6148E-08 -8.211 0.1722E-06 -6.764 0.2002E-06 0.3815E-05 SO3,gas 0.4695E-30 -30.328 0.3759E-28 -28.425 0.4369E-28 0.2913E-27 SO2,gas 0.2589E-12 -12.587 0.1658E-10 -10.780 0.1928E-10 0.1606E-09 HF,gas 0.9182E-06 -6.037 0.1836E-04 -4.736 0.2135E-04 0.5697E-03 HCl,gas 0.1092E-06 -6.962 0.3982E-05 -5.400 0.4628E-05 0.6776E-04 quartz 0.1068E-01 -1.972 0.6414 -0.193 2.989 0.2422 sulfur 0.6494 -0.188 20.82 1.318 97.01 10.07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2700E-01 0.1350E+01 0.7419 0.001 CO2,gas 0.9323E+00 0.4662E+02 0.8707 1.608 CH4,gas 0.3124E-05 0.1562E-03 1.0376 -3.790 H2,gas 0.2748E-06 0.1374E-04 1.0270 -4.850 H2S,gas 0.4069E-01 0.2035E+01 0.8293 0.227 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.3066E-08 0.1533E-06 1.0000 -6.814 SO3,gas 0.2341E-30 0.1171E-28 1.0000 -28.932 SO2,gas 0.1291E-12 0.6455E-11 1.0000 -11.190 HF,gas 0.4579E-06 0.2290E-04 1.0000 -4.640 HCl,gas 0.5446E-07 0.2723E-05 1.0000 -5.565 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 5.377746 % Solid products produced: Mass = 21.460083 g Volume = 10.314152 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 33.9999900 moles log = 1.5315 Original solution: 1000.0103000 g Original solution / Rock added: 29.41 (Water/Rock Ratio), log = 1.4685 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 0.00000E+00 2 CO2,gas -6.66 -6.66 0.00 0.000 0.00000E+00 3 CH4,gas 4.54 4.54 0.00 0.000 0.15165E-11 4 H2,gas 8.00 8.00 0.00 0.000 0.00000E+00 5 H2S,gas -6.23 -6.23 0.00 0.000 0.15165E-11 6 S2,gas -7.34 -7.34 0.00 0.000 0.00000E+00 7 CO,gas 3.21 3.21 0.00 0.000 0.22748E-11 8 SO3,gas 17.12 17.12 0.00 0.000 0.00000E+00 9 SO2,gas 0.83 0.83 0.00 0.000 -0.37914E-12 10 HF,gas 0.47 0.47 0.00 0.000 0.37914E-12 11 HCl,gas 5.19 5.19 0.00 0.000 0.00000E+00 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 172 sulfur -9.15 -9.15 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.85 -0.74 -0.213 0.12700E+04 89 graphite -3.55 -3.85 -0.30 -0.086 0.51221E+03 92 halite 1.57 -3.04 -4.62 -2.309 0.78850E+04 145 pyrite -21.25 -23.01 -1.76 -0.414 0.30034E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 33.9999900 MOLES New total amount of reactant added: 34.9999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 21 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 34.9999900 Water: Moles liquid = 0.8167E+02 kg liquid = 0.1471E+01 Moles total = 0.7850E+02 kg total = 0.1414E+01 Activity = 0.9954 Stoichiometric ionic strength = .3194921E+00 Osmotic coef. = 0.9148 True ionic strength = .1385888E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2066E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12516E+00 -0.9025 0.89721E-01 -1.0471 0.71686E+00 -0.1446 2 H2O 0.99538E+00 -0.0020 0.99538E+00 -0.0020 3 Cl- 0.13855E+00 -0.8584 0.97225E-01 -1.0122 0.70171E+00 -0.1538 4 SO4-- 0.14094E-10 -10.8510 0.37513E-11 -11.4258 0.26617E+00 -0.5748 5 HCO3- 0.27915E-05 -5.5542 0.19690E-05 -5.7057 0.70536E+00 -0.1516 6 HS- 0.31740E-06 -6.4984 0.22283E-06 -6.6520 0.70207E+00 -0.1536 7 Al+++ 0.32411E-05 -5.4893 0.16222E-06 -6.7899 0.50052E-01 -1.3006 8 H4SiO4 0.10152E-02 -2.9935 0.10152E-02 -2.9935 0.10000E+01 0.0000 9 Ca++ 0.13360E-06 -6.8742 0.34562E-07 -7.4614 0.25870E+00 -0.5872 10 Mg++ 0.54084E-10 -10.2669 0.13763E-10 -10.8613 0.25448E+00 -0.5943 11 Fe++ 0.20979E-07 -7.6782 0.53596E-08 -8.2709 0.25547E+00 -0.5927 12 K+ 0.95875E-04 -4.0183 0.67657E-04 -4.1697 0.70567E+00 -0.1514 13 Na+ 0.13315E-01 -1.8757 0.93318E-02 -2.0300 0.70083E+00 -0.1544 14 Mn++ 0.12574E-08 -8.9005 0.32219E-09 -9.4919 0.25623E+00 -0.5914 15 F- 0.22167E-04 -4.6543 0.15456E-04 -4.8109 0.69725E+00 -0.1566 16 HPO4-- 0.18142E-14 -14.7413 0.48312E-15 -15.3159 0.26630E+00 -0.5746 17 SiF6-2 0.10985E-10 -10.9592 0.29015E-11 -11.5374 0.26414E+00 -0.5782 18 HSiO3- 0.15126E-10 -10.8203 0.10614E-10 -10.9741 0.70171E+00 -0.1538 19 Ca(HSiO3)+ 0.11829E-16 -16.9270 0.83544E-17 -17.0781 0.70623E+00 -0.1511 21 NaHSiO3,aq 0.16020E-11 -11.7953 0.16020E-11 -11.7953 0.10000E+01 0.0000 22 AlO+ 0.38640E-11 -11.4130 0.27289E-11 -11.5640 0.70623E+00 -0.1511 23 AlOH+2 0.47414E-08 -8.3241 0.12191E-08 -8.9139 0.25713E+00 -0.5898 24 HAlO2,aq 0.60292E-14 -14.2197 0.60292E-14 -14.2197 0.10000E+01 0.0000 25 AlO2- 0.21320E-18 -18.6712 0.14875E-18 -18.8275 0.69770E+00 -0.1563 26 CH4,aq 0.12068E-06 -6.9184 0.11309E-06 -6.9466 0.93714E+00 -0.0282 27 C2H6,aq 0.21564E-15 -15.6663 0.20209E-15 -15.6945 0.93714E+00 -0.0282 31 CO,aq 0.10355E-09 -9.9848 0.10355E-09 -9.9848 0.10000E+01 0.0000 32 CO2,aq 0.40468E+00 -0.3929 0.37924E+00 -0.4211 0.93714E+00 -0.0282 33 CO3-2 0.72570E-14 -14.1392 0.19169E-14 -14.7174 0.26414E+00 -0.5782 34 CaCO3,aq 0.83071E-18 -18.0805 0.83071E-18 -18.0805 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.24597E-11 -11.6091 0.17371E-11 -11.7602 0.70623E+00 -0.1511 36 CaCl+ 0.76999E-08 -8.1135 0.54379E-08 -8.2646 0.70623E+00 -0.1511 37 CaCl2,aq 0.12561E-09 -9.9010 0.12561E-09 -9.9010 0.10000E+01 0.0000 38 CaF+ 0.11043E-10 -10.9569 0.77990E-11 -11.1080 0.70623E+00 -0.1511 39 CaOH+ 0.38694E-16 -16.4124 0.27327E-16 -16.5634 0.70623E+00 -0.1511 40 CaSO4,aq 0.41170E-16 -16.3854 0.41170E-16 -16.3854 0.10000E+01 0.0000 41 HCl,aq 0.15985E-02 -2.7963 0.15985E-02 -2.7963 0.10000E+01 0.0000 45 HF,aq 0.94929E-02 -2.0226 0.94929E-02 -2.0226 0.10000E+01 0.0000 46 HF2- 0.70593E-07 -7.1512 0.49536E-07 -7.3051 0.70171E+00 -0.1538 47 Fe+3 0.74169E-17 -17.1298 0.37542E-18 -18.4255 0.50617E-01 -1.2957 48 FeCl+ 0.11679E-08 -8.9326 0.82480E-09 -9.0837 0.70623E+00 -0.1511 49 FeCl2,aq 0.25389E-14 -14.5954 0.25389E-14 -14.5954 0.10000E+01 0.0000 50 FeCl+2 0.10143E-16 -16.9939 0.26079E-17 -17.5837 0.25713E+00 -0.5898 51 FeF+ 0.59939E-11 -11.2223 0.42331E-11 -11.3733 0.70623E+00 -0.1511 52 FeF+2 0.20112E-15 -15.6965 0.51714E-16 -16.2864 0.25713E+00 -0.5898 54 FeOH+ 0.27406E-14 -14.5622 0.19355E-14 -14.7132 0.70623E+00 -0.1511 56 FeO+ 0.62845E-19 -19.2017 0.44383E-19 -19.3528 0.70623E+00 -0.1511 57 FeOH+2 0.29575E-17 -17.5291 0.76047E-18 -18.1189 0.25713E+00 -0.5898 60 H2,aq 0.11545E-07 -7.9376 0.10819E-07 -7.9658 0.93714E+00 -0.0282 61 KCl,aq 0.11922E-06 -6.9237 0.11922E-06 -6.9237 0.10000E+01 0.0000 62 KHSO4,aq 0.64383E-16 -16.1912 0.64383E-16 -16.1912 0.10000E+01 0.0000 63 KOH,aq 0.32055E-15 -15.4941 0.32055E-15 -15.4941 0.10000E+01 0.0000 64 KSO4- 0.56125E-14 -14.2508 0.39384E-14 -14.4047 0.70171E+00 -0.1538 66 Mg(HCO3)+ 0.10009E-14 -14.9996 0.70685E-15 -15.1507 0.70623E+00 -0.1511 67 MgCl+ 0.27791E-11 -11.5561 0.19627E-11 -11.7071 0.70623E+00 -0.1511 68 MgF+ 0.16290E-13 -13.7881 0.11505E-13 -13.9391 0.70623E+00 -0.1511 69 MgOH+ 0.85265E-19 -19.0692 0.60217E-19 -19.2203 0.70623E+00 -0.1511 71 MnF+ 0.11876E-12 -12.9253 0.83874E-13 -13.0764 0.70623E+00 -0.1511 73 MnOH+ 0.15304E-16 -16.8152 0.10809E-16 -16.9662 0.70623E+00 -0.1511 78 MnCl+ 0.27313E-09 -9.5636 0.19289E-09 -9.7147 0.70623E+00 -0.1511 79 MnSO4,aq 0.34892E-18 -18.4573 0.34892E-18 -18.4573 0.10000E+01 0.0000 80 NaCl,aq 0.30068E-03 -3.5219 0.30068E-03 -3.5219 0.10000E+01 0.0000 81 NaF,aq 0.33767E-07 -7.4715 0.33767E-07 -7.4715 0.10000E+01 0.0000 82 NaOH,aq 0.44481E-13 -13.3518 0.44481E-13 -13.3518 0.10000E+01 0.0000 84 OH- 0.91872E-11 -11.0368 0.64099E-11 -11.1931 0.69770E+00 -0.1563 90 H3PO3,aq 0.29232E-19 -19.5341 0.29232E-19 -19.5341 0.10000E+01 0.0000 92 H3PO4,aq 0.27200E-07 -7.5654 0.27200E-07 -7.5654 0.10000E+01 0.0000 93 H2PO4- 0.11357E-08 -8.9447 0.79962E-09 -9.0971 0.70406E+00 -0.1524 95 H4P2O7,aq 0.97994E-17 -17.0088 0.97994E-17 -17.0088 0.10000E+01 0.0000 96 H3P2O7- 0.19872E-17 -17.7018 0.13944E-17 -17.8556 0.70171E+00 -0.1538 97 H2P2O7-2 0.19068E-18 -18.7197 0.50368E-19 -19.2978 0.26414E+00 -0.5782 100 H2S,aq 0.65936E-01 -1.1809 0.61791E-01 -1.2091 0.93714E+00 -0.0282 101 S2-2 0.38500E-15 -15.4145 0.10169E-15 -15.9927 0.26414E+00 -0.5782 102 S3-2 0.29623E-14 -14.5284 0.78248E-15 -15.1065 0.26414E+00 -0.5782 103 S3- 0.64475E-09 -9.1906 0.45243E-09 -9.3444 0.70171E+00 -0.1538 104 S4-2 0.15057E-13 -13.8223 0.39771E-14 -14.4004 0.26414E+00 -0.5782 105 S5-2 0.51030E-13 -13.2922 0.13479E-13 -13.8703 0.26414E+00 -0.5782 106 SO2,aq 0.14727E-11 -11.8319 0.14727E-11 -11.8319 0.10000E+01 0.0000 107 SO3-2 0.19048E-19 -19.7201 0.52987E-20 -20.2758 0.27817E+00 -0.5557 108 HSO3- 0.42419E-13 -13.3724 0.29766E-13 -13.5263 0.70171E+00 -0.1538 109 HSO4- 0.45747E-09 -9.3396 0.32436E-09 -9.4890 0.70903E+00 -0.1493 111 S2O3-2 0.10356E-13 -13.9848 0.27355E-14 -14.5630 0.26414E+00 -0.5782 112 HS2O3- 0.62538E-13 -13.2039 0.43884E-13 -13.3577 0.70171E+00 -0.1538 113 H2S2O3,aq 0.63120E-13 -13.1998 0.63120E-13 -13.1998 0.10000E+01 0.0000 Charge balance for all species = -.3744E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1251577E+00 0.6068622E+00 0.5963155E+03 0.0000 2 H2O 0.1000000E+01 0.5510357E+02 0.9677710E+06 0.0000 3 Cl- 0.1385535E+00 0.1404528E+00 0.4854391E+04 0.0349 4 SO4-- 0.1409390E-10 -.1227133E-06 -.1149192E-01 -9.3316 5 HCO3- 0.2791505E-05 0.4046803E+00 0.2407219E+05 -4.6586 6 HS- 0.3173962E-06 0.6593599E-01 0.2125858E+04 -5.6049 7 Al+++ 0.3241088E-05 0.3245834E-05 0.8537755E-01 -3.6486 8 H4SiO4 0.1015182E-02 0.1015182E-02 0.9512360E+02 -2.9935 9 Ca++ 0.1335965E-06 0.1414355E-06 0.5526064E-02 -5.3672 10 Mg++ 0.5408358E-10 0.5687999E-10 0.1348129E-05 -8.7671 11 Fe++ 0.2097927E-07 0.2215315E-07 0.1206109E-02 -6.1767 12 K+ 0.9587520E-04 0.9599441E-04 0.3659285E+01 -3.1226 13 Na+ 0.1331526E-01 0.1361596E-01 0.3051652E+03 -0.9829 14 Mn++ 0.1257406E-08 0.1530656E-08 0.8197882E-04 -7.3977 15 F- 0.2216661E-04 0.9515286E-02 0.1762305E+03 -3.7638 16 HPO4-- 0.1814185E-14 0.2833570E-07 0.2651316E-02 -13.2217 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3748597E+01 0.8928309E+00 0.8355848E+00 0.2020182E+01 2 H2O 0.7850090E+02 0.8106976E+02 -.6897867E+00 -.1879077E+01 3 Cl- 0.2066378E+00 0.2066377E+00 0.0000000E+00 0.1171225E-06 4 SO4-- 0.1671100E+00 -.1805389E-06 0.1671170E+00 -.6807178E-05 5 HCO3- 0.2530512E+01 0.5953758E+00 0.0000000E+00 0.1935137E+01 6 HS- 0.6834153E+00 0.9700669E-01 0.5013509E+00 0.8505774E-01 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1493562E-02 0.1065946E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1400010E-01 0.1399913E-01 0.0000000E+00 0.9678780E-06 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1523E-15 Mass of aqueous solution: 0.150913E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 34.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.5605E-01 -1.251 1.009 0.004 1.133 22.28 CO2,gas 1.935 0.287 85.17 1.930 95.61 1042. CH4,gas 0.6662E-05 -5.176 0.1069E-03 -3.971 0.1200E-03 0.4301E-02 H2,gas 0.5743E-06 -6.241 0.1160E-05 -5.935 0.1302E-05 0.3659E-03 H2S,gas 0.8505E-01 -1.070 2.899 0.462 3.254 43.30 S2,gas 0.2229E-10 -10.652 0.1429E-08 -8.845 0.1604E-08 0.1383E-07 CO,gas 0.6408E-08 -8.193 0.1795E-06 -6.746 0.2015E-06 0.3976E-05 SO3,gas 0.4763E-30 -30.322 0.3814E-28 -28.419 0.4281E-28 0.2956E-27 SO2,gas 0.2644E-12 -12.578 0.1694E-10 -10.771 0.1902E-10 0.1641E-09 HF,gas 0.9679E-06 -6.014 0.1936E-04 -4.713 0.2173E-04 0.6006E-03 HCl,gas 0.1171E-06 -6.931 0.4270E-05 -5.370 0.4794E-05 0.7267E-04 quartz 0.1066E-01 -1.972 0.6404 -0.194 2.902 0.2419 sulfur 0.6685 -0.175 21.43 1.331 97.10 10.37 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2699E-01 0.1350E+01 0.7419 0.001 CO2,gas 0.9320E+00 0.4660E+02 0.8707 1.608 CH4,gas 0.3209E-05 0.1604E-03 1.0376 -3.779 H2,gas 0.2766E-06 0.1383E-04 1.0270 -4.848 H2S,gas 0.4096E-01 0.2048E+01 0.8293 0.230 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.3086E-08 0.1543E-06 1.0000 -6.812 SO3,gas 0.2294E-30 0.1147E-28 1.0000 -28.940 SO2,gas 0.1274E-12 0.6368E-11 1.0000 -11.196 HF,gas 0.4662E-06 0.2331E-04 1.0000 -4.632 HCl,gas 0.5641E-07 0.2821E-05 1.0000 -5.550 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 5.497395 % Solid products produced: Mass = 22.071499 g Volume = 10.610055 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 34.9999900 moles log = 1.5441 Original solution: 1000.0103000 g Original solution / Rock added: 28.57 (Water/Rock Ratio), log = 1.4559 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 0.37914E-12 2 CO2,gas -6.66 -6.66 0.00 0.000 0.00000E+00 3 CH4,gas 4.54 4.54 0.00 0.000 -0.15165E-11 4 H2,gas 8.00 8.00 0.00 0.000 0.00000E+00 5 H2S,gas -6.23 -6.23 0.00 0.000 0.00000E+00 6 S2,gas -7.34 -7.34 0.00 0.000 0.00000E+00 7 CO,gas 3.21 3.21 0.00 0.000 -0.75827E-12 8 SO3,gas 17.12 17.12 0.00 0.000 0.00000E+00 9 SO2,gas 0.83 0.83 0.00 0.000 0.26539E-11 10 HF,gas 0.47 0.47 0.00 0.000 0.37914E-12 11 HCl,gas 5.19 5.19 0.00 0.000 0.00000E+00 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 172 sulfur -9.15 -9.15 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.84 -0.74 -0.211 0.12601E+04 89 graphite -3.55 -3.84 -0.29 -0.084 0.50237E+03 92 halite 1.57 -3.04 -4.62 -2.308 0.78831E+04 145 pyrite -21.25 -23.03 -1.78 -0.419 0.30413E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 34.9999900 MOLES New total amount of reactant added: 35.9999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 21 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 35.9999900 Water: Moles liquid = 0.8257E+02 kg liquid = 0.1488E+01 Moles total = 0.7932E+02 kg total = 0.1429E+01 Activity = 0.9953 Stoichiometric ionic strength = .3209145E+00 Osmotic coef. = 0.9148 True ionic strength = .1409546E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2125E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12768E+00 -0.8939 0.91389E-01 -1.0391 0.71579E+00 -0.1452 2 H2O 0.99530E+00 -0.0020 0.99530E+00 -0.0020 3 Cl- 0.14092E+00 -0.8510 0.98720E-01 -1.0056 0.70054E+00 -0.1546 4 SO4-- 0.13417E-10 -10.8723 0.35461E-11 -11.4502 0.26430E+00 -0.5779 5 HCO3- 0.27441E-05 -5.5616 0.19324E-05 -5.7139 0.70421E+00 -0.1523 6 HS- 0.31412E-06 -6.5029 0.22017E-06 -6.6572 0.70090E+00 -0.1543 7 Al+++ 0.32056E-05 -5.4941 0.15786E-06 -6.8017 0.49245E-01 -1.3076 8 H4SiO4 0.10150E-02 -2.9935 0.10150E-02 -2.9935 0.10000E+01 0.0000 9 Ca++ 0.13206E-06 -6.8792 0.33914E-07 -7.4696 0.25682E+00 -0.5904 10 Mg++ 0.53464E-10 -10.2719 0.13505E-10 -10.8695 0.25260E+00 -0.5976 11 Fe++ 0.20738E-07 -7.6832 0.52589E-08 -8.2791 0.25359E+00 -0.5959 12 K+ 0.94819E-04 -4.0231 0.66802E-04 -4.1752 0.70452E+00 -0.1521 13 Na+ 0.13165E-01 -1.8806 0.92107E-02 -2.0357 0.69965E+00 -0.1551 14 Mn++ 0.12415E-08 -8.9061 0.31576E-09 -9.5006 0.25435E+00 -0.5946 15 F- 0.22176E-04 -4.6541 0.15436E-04 -4.8115 0.69607E+00 -0.1573 16 HPO4-- 0.17427E-14 -14.7588 0.46084E-15 -15.3365 0.26444E+00 -0.5777 17 SiF6-2 0.11820E-10 -10.9274 0.31002E-11 -11.5086 0.26228E+00 -0.5812 18 HSiO3- 0.14874E-10 -10.8276 0.10420E-10 -10.9821 0.70054E+00 -0.1546 19 Ca(HSiO3)+ 0.11414E-16 -16.9426 0.80477E-17 -17.0943 0.70508E+00 -0.1518 21 NaHSiO3,aq 0.15522E-11 -11.8090 0.15522E-11 -11.8090 0.10000E+01 0.0000 22 AlO+ 0.36297E-11 -11.4401 0.25593E-11 -11.5919 0.70508E+00 -0.1518 23 AlOH+2 0.45627E-08 -8.3408 0.11646E-08 -8.9338 0.25524E+00 -0.5930 24 HAlO2,aq 0.55508E-14 -14.2556 0.55508E-14 -14.2556 0.10000E+01 0.0000 25 AlO2- 0.19303E-18 -18.7144 0.13445E-18 -18.8714 0.69651E+00 -0.1571 26 CH4,aq 0.12380E-06 -6.9073 0.11599E-06 -6.9356 0.93697E+00 -0.0283 27 C2H6,aq 0.22546E-15 -15.6469 0.21125E-15 -15.6752 0.93697E+00 -0.0283 31 CO,aq 0.10419E-09 -9.9822 0.10419E-09 -9.9822 0.10000E+01 0.0000 32 CO2,aq 0.40463E+00 -0.3929 0.37913E+00 -0.4212 0.93697E+00 -0.0283 33 CO3-2 0.70419E-14 -14.1523 0.18469E-14 -14.7336 0.26228E+00 -0.5812 34 CaCO3,aq 0.78540E-18 -18.1049 0.78540E-18 -18.1049 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.23726E-11 -11.6248 0.16729E-11 -11.7765 0.70508E+00 -0.1518 36 CaCl+ 0.76844E-08 -8.1144 0.54181E-08 -8.2661 0.70508E+00 -0.1518 37 CaCl2,aq 0.12708E-09 -9.8959 0.12708E-09 -9.8959 0.10000E+01 0.0000 38 CaF+ 0.10840E-10 -10.9650 0.76432E-11 -11.1167 0.70508E+00 -0.1518 39 CaOH+ 0.37334E-16 -16.4279 0.26324E-16 -16.5797 0.70508E+00 -0.1518 40 CaSO4,aq 0.38189E-16 -16.4181 0.38189E-16 -16.4181 0.10000E+01 0.0000 41 HCl,aq 0.16532E-02 -2.7817 0.16532E-02 -2.7817 0.10000E+01 0.0000 45 HF,aq 0.96571E-02 -2.0152 0.96571E-02 -2.0152 0.10000E+01 0.0000 46 HF2- 0.71844E-07 -7.1436 0.50329E-07 -7.2982 0.70054E+00 -0.1546 47 Fe+3 0.75096E-17 -17.1244 0.37402E-18 -18.4271 0.49806E-01 -1.3027 48 FeCl+ 0.11655E-08 -8.9335 0.82175E-09 -9.0853 0.70508E+00 -0.1518 49 FeCl2,aq 0.25684E-14 -14.5903 0.25684E-14 -14.5903 0.10000E+01 0.0000 50 FeCl+2 0.10336E-16 -16.9857 0.26382E-17 -17.5787 0.25524E+00 -0.5930 51 FeF+ 0.58834E-11 -11.2304 0.41483E-11 -11.3821 0.70508E+00 -0.1518 52 FeF+2 0.20159E-15 -15.6955 0.51456E-16 -16.2886 0.25524E+00 -0.5930 54 FeOH+ 0.26441E-14 -14.5777 0.18643E-14 -14.7295 0.70508E+00 -0.1518 56 FeO+ 0.60441E-19 -19.2187 0.42616E-19 -19.3704 0.70508E+00 -0.1518 57 FeOH+2 0.29139E-17 -17.5355 0.74375E-18 -18.1286 0.25524E+00 -0.5930 60 H2,aq 0.11621E-07 -7.9348 0.10888E-07 -7.9630 0.93697E+00 -0.0283 61 KCl,aq 0.11952E-06 -6.9225 0.11952E-06 -6.9225 0.10000E+01 0.0000 62 KHSO4,aq 0.61210E-16 -16.2132 0.61210E-16 -16.2132 0.10000E+01 0.0000 63 KOH,aq 0.31070E-15 -15.5077 0.31070E-15 -15.5077 0.10000E+01 0.0000 64 KSO4- 0.52473E-14 -14.2801 0.36759E-14 -14.4346 0.70054E+00 -0.1546 66 Mg(HCO3)+ 0.96539E-15 -15.0153 0.68068E-15 -15.1671 0.70508E+00 -0.1518 67 MgCl+ 0.27734E-11 -11.5570 0.19555E-11 -11.7087 0.70508E+00 -0.1518 68 MgF+ 0.15990E-13 -13.7962 0.11274E-13 -13.9479 0.70508E+00 -0.1518 69 MgOH+ 0.82265E-19 -19.0848 0.58004E-19 -19.2365 0.70508E+00 -0.1518 71 MnF+ 0.11644E-12 -12.9339 0.82098E-13 -13.0857 0.70508E+00 -0.1518 73 MnOH+ 0.14748E-16 -16.8313 0.10399E-16 -16.9830 0.70508E+00 -0.1518 78 MnCl+ 0.27224E-09 -9.5650 0.19195E-09 -9.7168 0.70508E+00 -0.1518 79 MnSO4,aq 0.32326E-18 -18.4905 0.32326E-18 -18.4905 0.10000E+01 0.0000 80 NaCl,aq 0.30134E-03 -3.5209 0.30134E-03 -3.5209 0.10000E+01 0.0000 81 NaF,aq 0.33287E-07 -7.4777 0.33287E-07 -7.4777 0.10000E+01 0.0000 82 NaOH,aq 0.43099E-13 -13.3655 0.43099E-13 -13.3655 0.10000E+01 0.0000 84 OH- 0.90343E-11 -11.0441 0.62925E-11 -11.2012 0.69651E+00 -0.1571 90 H3PO3,aq 0.29117E-19 -19.5359 0.29117E-19 -19.5359 0.10000E+01 0.0000 92 H3PO4,aq 0.26919E-07 -7.5699 0.26919E-07 -7.5699 0.10000E+01 0.0000 93 H2PO4- 0.11053E-08 -8.9565 0.77691E-09 -9.1096 0.70290E+00 -0.1531 95 H4P2O7,aq 0.95986E-17 -17.0178 0.95986E-17 -17.0178 0.10000E+01 0.0000 96 H3P2O7- 0.19142E-17 -17.7180 0.13409E-17 -17.8726 0.70054E+00 -0.1546 97 H2P2O7-2 0.18130E-18 -18.7416 0.47551E-19 -19.3228 0.26228E+00 -0.5812 100 H2S,aq 0.66368E-01 -1.1780 0.62185E-01 -1.2063 0.93697E+00 -0.0283 101 S2-2 0.37610E-15 -15.4247 0.98644E-16 -16.0059 0.26228E+00 -0.5812 102 S3-2 0.28939E-14 -14.5385 0.75901E-15 -15.1198 0.26228E+00 -0.5812 103 S3- 0.63607E-09 -9.1965 0.44559E-09 -9.3511 0.70054E+00 -0.1546 104 S4-2 0.14709E-13 -13.8324 0.38578E-14 -14.4137 0.26228E+00 -0.5812 105 S5-2 0.49851E-13 -13.3023 0.13075E-13 -13.8836 0.26228E+00 -0.5812 106 SO2,aq 0.14538E-11 -11.8375 0.14538E-11 -11.8375 0.10000E+01 0.0000 107 SO3-2 0.18244E-19 -19.7389 0.50413E-20 -20.2975 0.27633E+00 -0.5586 108 HSO3- 0.41177E-13 -13.3853 0.28846E-13 -13.5399 0.70054E+00 -0.1546 109 HSO4- 0.44118E-09 -9.3554 0.31232E-09 -9.5054 0.70791E+00 -0.1500 111 S2O3-2 0.99231E-14 -14.0034 0.26026E-14 -14.5846 0.26228E+00 -0.5812 112 HS2O3- 0.60707E-13 -13.2168 0.42528E-13 -13.3713 0.70054E+00 -0.1546 113 H2S2O3,aq 0.62306E-13 -13.2055 0.62306E-13 -13.2055 0.10000E+01 0.0000 Charge balance for all species = -.3702E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1276753E+00 0.6099887E+00 0.5993286E+03 0.0000 2 H2O 0.1000000E+01 0.5510362E+02 0.9676764E+06 0.0000 3 Cl- 0.1409195E+00 0.1428742E+00 0.4937595E+04 0.0335 4 SO4-- 0.1341694E-10 -.1258749E-06 -.1178684E-01 -9.3720 5 HCO3- 0.2744061E-05 0.4046375E+00 0.2406728E+05 -4.6748 6 HS- 0.3141191E-06 0.6636869E-01 0.2139598E+04 -5.6181 7 Al+++ 0.3205569E-05 0.3210135E-05 0.8443023E-01 -3.6844 8 H4SiO4 0.1015020E-02 0.1015020E-02 0.9509904E+02 -2.9935 9 Ca++ 0.1320553E-06 0.1398800E-06 0.5464749E-02 -5.3914 10 Mg++ 0.5346409E-10 0.5625442E-10 0.1333171E-05 -8.7913 11 Fe++ 0.2073816E-07 0.2190951E-07 0.1192727E-02 -6.2009 12 K+ 0.9481913E-04 0.9493865E-04 0.3618683E+01 -3.1361 13 Na+ 0.1316484E-01 0.1346621E-01 0.3017792E+03 -0.9966 14 Mn++ 0.1241461E-08 0.1513821E-08 0.8106921E-04 -7.4224 15 F- 0.2217626E-04 0.9679493E-02 0.1792541E+03 -3.7724 16 HPO4-- 0.1742706E-14 0.2802406E-07 0.2621898E-02 -13.2582 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3856272E+01 0.9074105E+00 0.8594619E+00 0.2089400E+01 2 H2O 0.7931960E+02 0.8197136E+02 -.7088557E+00 -.1942903E+01 3 Cl- 0.2125378E+00 0.2125377E+00 0.0000000E+00 0.1252840E-06 4 SO4-- 0.1718850E+00 -.1872497E-06 0.1718924E+00 -.7218273E-05 5 HCO3- 0.2602812E+01 0.6019331E+00 0.0000000E+00 0.2000879E+01 6 HS- 0.7029403E+00 0.9872913E-01 0.5156771E+00 0.8853404E-01 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1509929E-02 0.1064309E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1440010E-01 0.1439908E-01 0.0000000E+00 0.1018353E-05 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1970E-16 Mass of aqueous solution: 0.152607E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 35.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.5796E-01 -1.237 1.044 0.019 1.133 23.04 CO2,gas 2.001 0.301 88.06 1.945 95.59 1078. CH4,gas 0.7067E-05 -5.151 0.1134E-03 -3.946 0.1231E-03 0.4563E-02 H2,gas 0.5978E-06 -6.223 0.1208E-05 -5.918 0.1311E-05 0.3808E-03 H2S,gas 0.8853E-01 -1.053 3.017 0.480 3.275 45.07 S2,gas 0.2305E-10 -10.637 0.1478E-08 -8.830 0.1605E-08 0.1430E-07 CO,gas 0.6668E-08 -8.176 0.1868E-06 -6.729 0.2028E-06 0.4138E-05 SO3,gas 0.4832E-30 -30.316 0.3869E-28 -28.412 0.4200E-28 0.2998E-27 SO2,gas 0.2700E-12 -12.569 0.1730E-10 -10.762 0.1878E-10 0.1675E-09 HF,gas 0.1018E-05 -5.992 0.2037E-04 -4.691 0.2211E-04 0.6319E-03 HCl,gas 0.1253E-06 -6.902 0.4568E-05 -5.340 0.4959E-05 0.7774E-04 quartz 0.1064E-01 -1.973 0.6394 -0.194 2.819 0.2415 sulfur 0.6876 -0.163 22.04 1.343 97.18 10.66 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2699E-01 0.1350E+01 0.7419 0.001 CO2,gas 0.9318E+00 0.4659E+02 0.8707 1.608 CH4,gas 0.3291E-05 0.1646E-03 1.0376 -3.768 H2,gas 0.2784E-06 0.1392E-04 1.0270 -4.845 H2S,gas 0.4123E-01 0.2061E+01 0.8293 0.233 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.3105E-08 0.1553E-06 1.0000 -6.809 SO3,gas 0.2250E-30 0.1125E-28 1.0000 -28.949 SO2,gas 0.1257E-12 0.6287E-11 1.0000 -11.202 HF,gas 0.4742E-06 0.2371E-04 1.0000 -4.625 HCl,gas 0.5834E-07 0.2917E-05 1.0000 -5.535 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 5.614062 % Solid products produced: Mass = 22.682915 g Volume = 10.905958 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 35.9999900 moles log = 1.5563 Original solution: 1000.0103000 g Original solution / Rock added: 27.78 (Water/Rock Ratio), log = 1.4437 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 0.00000E+00 2 CO2,gas -6.66 -6.66 0.00 0.000 0.15165E-11 3 CH4,gas 4.54 4.54 0.00 0.000 -0.30331E-11 4 H2,gas 8.00 8.00 0.00 0.000 0.00000E+00 5 H2S,gas -6.23 -6.23 0.00 0.000 0.00000E+00 6 S2,gas -7.34 -7.34 0.00 0.000 0.60662E-11 7 CO,gas 3.21 3.21 0.00 0.000 -0.75827E-12 8 SO3,gas 17.12 17.12 0.00 0.000 0.00000E+00 9 SO2,gas 0.83 0.83 0.00 0.000 0.26539E-11 10 HF,gas 0.47 0.47 0.00 0.000 0.18957E-11 11 HCl,gas 5.19 5.19 0.00 0.000 0.15165E-11 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 172 sulfur -9.15 -9.15 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.83 -0.73 -0.209 0.12508E+04 89 graphite -3.55 -3.83 -0.29 -0.082 0.49301E+03 92 halite 1.57 -3.04 -4.62 -2.308 0.78815E+04 145 pyrite -21.25 -23.05 -1.80 -0.424 0.30780E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 35.9999900 MOLES New total amount of reactant added: 36.9999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 21 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 36.9999900 Water: Moles liquid = 0.8348E+02 kg liquid = 0.1504E+01 Moles total = 0.8014E+02 kg total = 0.1444E+01 Activity = 0.9952 Stoichiometric ionic strength = .3223025E+00 Osmotic coef. = 0.9148 True ionic strength = .1432684E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2184E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13014E+00 -0.8856 0.93016E-01 -1.0314 0.71476E+00 -0.1458 2 H2O 0.99522E+00 -0.0021 0.99522E+00 -0.0021 3 Cl- 0.14323E+00 -0.8440 0.10018E+00 -0.9992 0.69942E+00 -0.1553 4 SO4-- 0.12801E-10 -10.8928 0.33604E-11 -11.4736 0.26252E+00 -0.5808 5 HCO3- 0.26993E-05 -5.5687 0.18979E-05 -5.7217 0.70311E+00 -0.1530 6 HS- 0.31100E-06 -6.5072 0.21763E-06 -6.6623 0.69978E+00 -0.1550 7 Al+++ 0.31708E-05 -5.4988 0.15372E-06 -6.8133 0.48479E-01 -1.3144 8 H4SiO4 0.10149E-02 -2.9936 0.10149E-02 -2.9936 0.10000E+01 0.0000 9 Ca++ 0.13055E-06 -6.8842 0.33292E-07 -7.4777 0.25502E+00 -0.5934 10 Mg++ 0.52859E-10 -10.2769 0.13257E-10 -10.8776 0.25079E+00 -0.6007 11 Fe++ 0.20503E-07 -7.6882 0.51622E-08 -8.2872 0.25178E+00 -0.5990 12 K+ 0.93786E-04 -4.0279 0.65970E-04 -4.1807 0.70341E+00 -0.1528 13 Na+ 0.13018E-01 -1.8855 0.90930E-02 -2.0413 0.69851E+00 -0.1558 14 Mn++ 0.12259E-08 -8.9115 0.30960E-09 -9.5092 0.25254E+00 -0.5977 15 F- 0.22187E-04 -4.6539 0.15418E-04 -4.8120 0.69493E+00 -0.1581 16 HPO4-- 0.16763E-14 -14.7756 0.44029E-15 -15.3563 0.26265E+00 -0.5806 17 SiF6-2 0.12686E-10 -10.8967 0.33045E-11 -11.4809 0.26049E+00 -0.5842 18 HSiO3- 0.14636E-10 -10.8346 0.10237E-10 -10.9898 0.69942E+00 -0.1553 19 Ca(HSiO3)+ 0.11025E-16 -16.9576 0.77613E-17 -17.1101 0.70398E+00 -0.1524 21 NaHSiO3,aq 0.15055E-11 -11.8223 0.15055E-11 -11.8223 0.10000E+01 0.0000 22 AlO+ 0.34170E-11 -11.4664 0.24055E-11 -11.6188 0.70398E+00 -0.1524 23 AlOH+2 0.43961E-08 -8.3569 0.11141E-08 -8.9531 0.25344E+00 -0.5961 24 HAlO2,aq 0.51256E-14 -14.2903 0.51256E-14 -14.2903 0.10000E+01 0.0000 25 AlO2- 0.17541E-18 -18.7559 0.12198E-18 -18.9137 0.69537E+00 -0.1578 26 CH4,aq 0.12684E-06 -6.8967 0.11883E-06 -6.9251 0.93682E+00 -0.0283 27 C2H6,aq 0.23522E-15 -15.6285 0.22035E-15 -15.6569 0.93682E+00 -0.0283 31 CO,aq 0.10481E-09 -9.9796 0.10481E-09 -9.9796 0.10000E+01 0.0000 32 CO2,aq 0.40459E+00 -0.3930 0.37903E+00 -0.4213 0.93682E+00 -0.0283 33 CO3-2 0.68418E-14 -14.1648 0.17822E-14 -14.7490 0.26049E+00 -0.5842 34 CaCO3,aq 0.74399E-18 -18.1284 0.74399E-18 -18.1284 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.22911E-11 -11.6400 0.16129E-11 -11.7924 0.70398E+00 -0.1524 36 CaCl+ 0.76670E-08 -8.1154 0.53974E-08 -8.2678 0.70398E+00 -0.1524 37 CaCl2,aq 0.12846E-09 -9.8912 0.12846E-09 -9.8912 0.10000E+01 0.0000 38 CaF+ 0.10646E-10 -10.9728 0.74944E-11 -11.1253 0.70398E+00 -0.1524 39 CaOH+ 0.36062E-16 -16.4430 0.25387E-16 -16.5954 0.70398E+00 -0.1524 40 CaSO4,aq 0.35525E-16 -16.4495 0.35525E-16 -16.4495 0.10000E+01 0.0000 41 HCl,aq 0.17076E-02 -2.7676 0.17076E-02 -2.7676 0.10000E+01 0.0000 45 HF,aq 0.98178E-02 -2.0080 0.98178E-02 -2.0080 0.10000E+01 0.0000 46 HF2- 0.73071E-07 -7.1363 0.51107E-07 -7.2915 0.69942E+00 -0.1553 47 Fe+3 0.75975E-17 -17.1193 0.37255E-18 -18.4288 0.49036E-01 -1.3095 48 FeCl+ 0.11628E-08 -8.9345 0.81856E-09 -9.0869 0.70398E+00 -0.1524 49 FeCl2,aq 0.25962E-14 -14.5857 0.25962E-14 -14.5857 0.10000E+01 0.0000 50 FeCl+2 0.10522E-16 -16.9779 0.26666E-17 -17.5740 0.25344E+00 -0.5961 51 FeF+ 0.57776E-11 -11.2383 0.40673E-11 -11.3907 0.70398E+00 -0.1524 52 FeF+2 0.20200E-15 -15.6947 0.51194E-16 -16.2908 0.25344E+00 -0.5961 54 FeOH+ 0.25539E-14 -14.5928 0.17979E-14 -14.7452 0.70398E+00 -0.1524 56 FeO+ 0.58201E-19 -19.2351 0.40972E-19 -19.3875 0.70398E+00 -0.1524 57 FeOH+2 0.28717E-17 -17.5419 0.72781E-18 -18.1380 0.25344E+00 -0.5961 60 H2,aq 0.11693E-07 -7.9321 0.10955E-07 -7.9604 0.93682E+00 -0.0283 61 KCl,aq 0.11978E-06 -6.9216 0.11978E-06 -6.9216 0.10000E+01 0.0000 62 KHSO4,aq 0.58301E-16 -16.2343 0.58301E-16 -16.2343 0.10000E+01 0.0000 63 KOH,aq 0.30144E-15 -15.5208 0.30144E-15 -15.5208 0.10000E+01 0.0000 64 KSO4- 0.49184E-14 -14.3082 0.34400E-14 -14.4634 0.69942E+00 -0.1553 66 Mg(HCO3)+ 0.93219E-15 -15.0305 0.65624E-15 -15.1829 0.70398E+00 -0.1524 67 MgCl+ 0.27670E-11 -11.5580 0.19479E-11 -11.7104 0.70398E+00 -0.1524 68 MgF+ 0.15702E-13 -13.8040 0.11054E-13 -13.9565 0.70398E+00 -0.1524 69 MgOH+ 0.79457E-19 -19.0999 0.55937E-19 -19.2523 0.70398E+00 -0.1524 71 MnF+ 0.11421E-12 -12.9423 0.80403E-13 -13.0947 0.70398E+00 -0.1524 73 MnOH+ 0.14229E-16 -16.8468 0.10017E-16 -16.9993 0.70398E+00 -0.1524 78 MnCl+ 0.27130E-09 -9.5665 0.19099E-09 -9.7190 0.70398E+00 -0.1524 79 MnSO4,aq 0.30035E-18 -18.5224 0.30035E-18 -18.5224 0.10000E+01 0.0000 80 NaCl,aq 0.30189E-03 -3.5202 0.30189E-03 -3.5202 0.10000E+01 0.0000 81 NaF,aq 0.32823E-07 -7.4838 0.32823E-07 -7.4838 0.10000E+01 0.0000 82 NaOH,aq 0.41801E-13 -13.3788 0.41801E-13 -13.3788 0.10000E+01 0.0000 84 OH- 0.88900E-11 -11.0511 0.61819E-11 -11.2089 0.69537E+00 -0.1578 90 H3PO3,aq 0.28996E-19 -19.5377 0.28996E-19 -19.5377 0.10000E+01 0.0000 92 H3PO4,aq 0.26643E-07 -7.5744 0.26643E-07 -7.5744 0.10000E+01 0.0000 93 H2PO4- 0.10765E-08 -8.9680 0.75549E-09 -9.1218 0.70179E+00 -0.1538 95 H4P2O7,aq 0.94034E-17 -17.0267 0.94034E-17 -17.0267 0.10000E+01 0.0000 96 H3P2O7- 0.18454E-17 -17.7339 0.12907E-17 -17.8892 0.69942E+00 -0.1553 97 H2P2O7-2 0.17263E-18 -18.7629 0.44968E-19 -19.3471 0.26049E+00 -0.5842 100 H2S,aq 0.66783E-01 -1.1753 0.62563E-01 -1.2037 0.93682E+00 -0.0283 101 S2-2 0.36777E-15 -15.4344 0.95800E-16 -16.0186 0.26049E+00 -0.5842 102 S3-2 0.28298E-14 -14.5482 0.73712E-15 -15.1325 0.26049E+00 -0.5842 103 S3- 0.62784E-09 -9.2022 0.43912E-09 -9.3574 0.69942E+00 -0.1553 104 S4-2 0.14383E-13 -13.8422 0.37466E-14 -14.4264 0.26049E+00 -0.5842 105 S5-2 0.48746E-13 -13.3121 0.12698E-13 -13.8963 0.26049E+00 -0.5842 106 SO2,aq 0.14361E-11 -11.8428 0.14361E-11 -11.8428 0.10000E+01 0.0000 107 SO3-2 0.17506E-19 -19.7568 0.48066E-20 -20.3182 0.27457E+00 -0.5614 108 HSO3- 0.40024E-13 -13.3977 0.27993E-13 -13.5529 0.69942E+00 -0.1553 109 HSO4- 0.42617E-09 -9.3704 0.30123E-09 -9.5211 0.70683E+00 -0.1507 111 S2O3-2 0.95261E-14 -14.0211 0.24815E-14 -14.6053 0.26049E+00 -0.5842 112 HS2O3- 0.59007E-13 -13.2291 0.41270E-13 -13.3844 0.69942E+00 -0.1553 113 H2S2O3,aq 0.61541E-13 -13.2108 0.61541E-13 -13.2108 0.10000E+01 0.0000 Charge balance for all species = -.3662E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1301373E+00 0.6130403E+00 0.6022690E+03 0.0000 2 H2O 0.1000000E+01 0.5510366E+02 0.9675840E+06 0.0000 3 Cl- 0.1432334E+00 0.1452430E+00 0.5018974E+04 0.0322 4 SO4-- 0.1280060E-10 -.1289586E-06 -.1207444E-01 -9.4107 5 HCO3- 0.2699342E-05 0.4045976E+00 0.2406259E+05 -4.6903 6 HS- 0.3109963E-06 0.6678332E-01 0.2152758E+04 -5.6308 7 Al+++ 0.3170814E-05 0.3175214E-05 0.8350373E-01 -3.7190 8 H4SiO4 0.1014861E-02 0.1014861E-02 0.9507504E+02 -2.9936 9 Ca++ 0.1305499E-06 0.1383583E-06 0.5404780E-02 -5.4148 10 Mg++ 0.5285884E-10 0.5564246E-10 0.1318541E-05 -8.8147 11 Fe++ 0.2050262E-07 0.2167116E-07 0.1179638E-02 -6.2243 12 K+ 0.9378608E-04 0.9390586E-04 0.3578973E+01 -3.1492 13 Na+ 0.1301780E-01 0.1331972E-01 0.2984676E+03 -1.0098 14 Mn++ 0.1225935E-08 0.1497353E-08 0.8017959E-04 -7.4463 15 F- 0.2218681E-04 0.9840128E-02 0.1822113E+03 -3.7805 16 HPO4-- 0.1676304E-14 0.2771920E-07 0.2593126E-02 -13.2934 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.3963947E+01 0.9219799E+00 0.8833390E+00 0.2158629E+01 2 H2O 0.8013830E+02 0.8287295E+02 -.7279246E+00 -.2006727E+01 3 Cl- 0.2184378E+00 0.2184377E+00 0.0000000E+00 0.1336883E-06 4 SO4-- 0.1766600E+00 -.1939469E-06 0.1766678E+00 -.7636675E-05 5 HCO3- 0.2675112E+01 0.6084931E+00 0.0000000E+00 0.2066619E+01 6 HS- 0.7224653E+00 0.1004385E+00 0.5300034E+00 0.9202336E-01 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1526297E-02 0.1062672E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1480010E-01 0.1479903E-01 0.0000000E+00 0.1069591E-05 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.4420E-15 Mass of aqueous solution: 0.154300E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 36.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.5988E-01 -1.223 1.078 0.033 1.133 23.80 CO2,gas 2.067 0.315 90.95 1.959 95.57 1113. CH4,gas 0.7480E-05 -5.126 0.1200E-03 -3.921 0.1261E-03 0.4829E-02 H2,gas 0.6214E-06 -6.207 0.1255E-05 -5.901 0.1319E-05 0.3958E-03 H2S,gas 0.9202E-01 -1.036 3.136 0.496 3.295 46.84 S2,gas 0.2382E-10 -10.623 0.1527E-08 -8.816 0.1605E-08 0.1478E-07 CO,gas 0.6930E-08 -8.159 0.1941E-06 -6.712 0.2040E-06 0.4300E-05 SO3,gas 0.4901E-30 -30.310 0.3924E-28 -28.406 0.4123E-28 0.3041E-27 SO2,gas 0.2755E-12 -12.560 0.1765E-10 -10.753 0.1855E-10 0.1710E-09 HF,gas 0.1070E-05 -5.971 0.2139E-04 -4.670 0.2248E-04 0.6637E-03 HCl,gas 0.1337E-06 -6.874 0.4874E-05 -5.312 0.5122E-05 0.8295E-04 quartz 0.1063E-01 -1.974 0.6385 -0.195 2.741 0.2411 sulfur 0.7067 -0.151 22.66 1.355 97.26 10.96 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2699E-01 0.1349E+01 0.7419 0.001 CO2,gas 0.9315E+00 0.4658E+02 0.8707 1.608 CH4,gas 0.3371E-05 0.1686E-03 1.0376 -3.757 H2,gas 0.2801E-06 0.1400E-04 1.0270 -4.842 H2S,gas 0.4148E-01 0.2074E+01 0.8293 0.235 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.3124E-08 0.1562E-06 1.0000 -6.806 SO3,gas 0.2209E-30 0.1105E-28 1.0000 -28.957 SO2,gas 0.1242E-12 0.6210E-11 1.0000 -11.207 HF,gas 0.4821E-06 0.2411E-04 1.0000 -4.618 HCl,gas 0.6026E-07 0.3013E-05 1.0000 -5.521 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 5.727857 % Solid products produced: Mass = 23.294332 g Volume = 11.201862 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 36.9999900 moles log = 1.5682 Original solution: 1000.0103000 g Original solution / Rock added: 27.03 (Water/Rock Ratio), log = 1.4318 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 0.37914E-12 2 CO2,gas -6.66 -6.66 0.00 0.000 -0.15165E-11 3 CH4,gas 4.54 4.54 0.00 0.000 0.15165E-11 4 H2,gas 8.00 8.00 0.00 0.000 0.00000E+00 5 H2S,gas -6.23 -6.23 0.00 0.000 -0.15165E-11 6 S2,gas -7.34 -7.34 0.00 0.000 0.00000E+00 7 CO,gas 3.21 3.21 0.00 0.000 -0.75827E-12 8 SO3,gas 17.12 17.12 0.00 0.000 0.00000E+00 9 SO2,gas 0.83 0.83 0.00 0.000 0.26539E-11 10 HF,gas 0.47 0.47 0.00 0.000 -0.11374E-11 11 HCl,gas 5.19 5.19 0.00 0.000 -0.15165E-11 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 172 sulfur -9.15 -9.15 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.83 -0.73 -0.208 0.12419E+04 89 graphite -3.55 -3.83 -0.28 -0.081 0.48411E+03 92 halite 1.57 -3.04 -4.62 -2.308 0.78801E+04 145 pyrite -21.25 -23.07 -1.82 -0.429 0.31134E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 36.9999900 MOLES New total amount of reactant added: 37.9999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 21 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 37.9999900 Water: Moles liquid = 0.8439E+02 kg liquid = 0.1520E+01 Moles total = 0.8096E+02 kg total = 0.1458E+01 Activity = 0.9951 Stoichiometric ionic strength = .3236574E+00 Osmotic coef. = 0.9148 True ionic strength = .1455317E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2243E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13255E+00 -0.8776 0.94606E-01 -1.0241 0.71376E+00 -0.1464 2 H2O 0.99515E+00 -0.0021 0.99515E+00 -0.0021 3 Cl- 0.14550E+00 -0.8371 0.10161E+00 -0.9931 0.69833E+00 -0.1559 4 SO4-- 0.12238E-10 -10.9123 0.31916E-11 -11.4960 0.26081E+00 -0.5837 5 HCO3- 0.26571E-05 -5.5756 0.18654E-05 -5.7292 0.70205E+00 -0.1536 6 HS- 0.30802E-06 -6.5114 0.21521E-06 -6.6671 0.69870E+00 -0.1557 7 Al+++ 0.31368E-05 -5.5035 0.14979E-06 -6.8245 0.47752E-01 -1.3210 8 H4SiO4 0.10147E-02 -2.9937 0.10147E-02 -2.9937 0.10000E+01 0.0000 9 Ca++ 0.12908E-06 -6.8891 0.32694E-07 -7.4855 0.25329E+00 -0.5964 10 Mg++ 0.52267E-10 -10.2818 0.13018E-10 -10.8855 0.24906E+00 -0.6037 11 Fe++ 0.20272E-07 -7.6931 0.50692E-08 -8.2951 0.25005E+00 -0.6020 12 K+ 0.92775E-04 -4.0326 0.65160E-04 -4.1860 0.70235E+00 -0.1534 13 Na+ 0.12874E-01 -1.8903 0.89785E-02 -2.0468 0.69741E+00 -0.1565 14 Mn++ 0.12108E-08 -8.9169 0.30369E-09 -9.5176 0.25081E+00 -0.6007 15 F- 0.22198E-04 -4.6537 0.15402E-04 -4.8124 0.69384E+00 -0.1587 16 HPO4-- 0.16145E-14 -14.7920 0.42129E-15 -15.3754 0.26094E+00 -0.5835 17 SiF6-2 0.13580E-10 -10.8671 0.35143E-11 -11.4542 0.25878E+00 -0.5871 18 HSiO3- 0.14411E-10 -10.8413 0.10064E-10 -10.9972 0.69833E+00 -0.1559 19 Ca(HSiO3)+ 0.10660E-16 -16.9722 0.74932E-17 -17.1253 0.70292E+00 -0.1531 21 NaHSiO3,aq 0.14614E-11 -11.8352 0.14614E-11 -11.8352 0.10000E+01 0.0000 22 AlO+ 0.32233E-11 -11.4917 0.22657E-11 -11.6448 0.70292E+00 -0.1531 23 AlOH+2 0.42403E-08 -8.3726 0.10673E-08 -8.9717 0.25171E+00 -0.5991 24 HAlO2,aq 0.47462E-14 -14.3237 0.47462E-14 -14.3237 0.10000E+01 0.0000 25 AlO2- 0.15995E-18 -18.7960 0.11105E-18 -18.9545 0.69428E+00 -0.1585 26 CH4,aq 0.12981E-06 -6.8867 0.12159E-06 -6.9151 0.93666E+00 -0.0284 27 C2H6,aq 0.24491E-15 -15.6110 0.22940E-15 -15.6394 0.93666E+00 -0.0284 31 CO,aq 0.10539E-09 -9.9772 0.10539E-09 -9.9772 0.10000E+01 0.0000 32 CO2,aq 0.40456E+00 -0.3930 0.37893E+00 -0.4214 0.93666E+00 -0.0284 33 CO3-2 0.66554E-14 -14.1768 0.17223E-14 -14.7639 0.25878E+00 -0.5871 34 CaCO3,aq 0.70604E-18 -18.1512 0.70604E-18 -18.1512 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.22148E-11 -11.6547 0.15568E-11 -11.8078 0.70292E+00 -0.1531 36 CaCl+ 0.76480E-08 -8.1165 0.53759E-08 -8.2695 0.70292E+00 -0.1531 37 CaCl2,aq 0.12977E-09 -9.8868 0.12977E-09 -9.8868 0.10000E+01 0.0000 38 CaF+ 0.10459E-10 -10.9805 0.73519E-11 -11.1336 0.70292E+00 -0.1531 39 CaOH+ 0.34869E-16 -16.4576 0.24510E-16 -16.6107 0.70292E+00 -0.1531 40 CaSO4,aq 0.33135E-16 -16.4797 0.33135E-16 -16.4797 0.10000E+01 0.0000 41 HCl,aq 0.17614E-02 -2.7541 0.17614E-02 -2.7541 0.10000E+01 0.0000 45 HF,aq 0.99749E-02 -2.0011 0.99749E-02 -2.0011 0.10000E+01 0.0000 46 HF2- 0.74277E-07 -7.1291 0.51870E-07 -7.2851 0.69833E+00 -0.1559 47 Fe+3 0.76808E-17 -17.1146 0.37102E-18 -18.4306 0.48305E-01 -1.3160 48 FeCl+ 0.11598E-08 -8.9356 0.81525E-09 -9.0887 0.70292E+00 -0.1531 49 FeCl2,aq 0.26226E-14 -14.5813 0.26226E-14 -14.5813 0.10000E+01 0.0000 50 FeCl+2 0.10701E-16 -16.9706 0.26935E-17 -17.5697 0.25171E+00 -0.5991 51 FeF+ 0.56760E-11 -11.2460 0.39898E-11 -11.3991 0.70292E+00 -0.1531 52 FeF+2 0.20233E-15 -15.6939 0.50929E-16 -16.2930 0.25171E+00 -0.5991 54 FeOH+ 0.24693E-14 -14.6074 0.17357E-14 -14.7605 0.70292E+00 -0.1531 56 FeO+ 0.56110E-19 -19.2510 0.39441E-19 -19.4041 0.70292E+00 -0.1531 57 FeOH+2 0.28309E-17 -17.5481 0.71258E-18 -18.1472 0.25171E+00 -0.5991 60 H2,aq 0.11763E-07 -7.9295 0.11018E-07 -7.9579 0.93666E+00 -0.0284 61 KCl,aq 0.11999E-06 -6.9208 0.11999E-06 -6.9208 0.10000E+01 0.0000 62 KHSO4,aq 0.55629E-16 -16.2547 0.55629E-16 -16.2547 0.10000E+01 0.0000 63 KOH,aq 0.29271E-15 -15.5336 0.29271E-15 -15.5336 0.10000E+01 0.0000 64 KSO4- 0.46212E-14 -14.3352 0.32272E-14 -14.4912 0.69833E+00 -0.1559 66 Mg(HCO3)+ 0.90108E-15 -15.0452 0.63339E-15 -15.1983 0.70292E+00 -0.1531 67 MgCl+ 0.27600E-11 -11.5591 0.19400E-11 -11.7122 0.70292E+00 -0.1531 68 MgF+ 0.15427E-13 -13.8117 0.10844E-13 -13.9648 0.70292E+00 -0.1531 69 MgOH+ 0.76825E-19 -19.1145 0.54002E-19 -19.2676 0.70292E+00 -0.1531 71 MnF+ 0.11208E-12 -12.9505 0.78783E-13 -13.1036 0.70292E+00 -0.1531 73 MnOH+ 0.13742E-16 -16.8619 0.96596E-17 -17.0150 0.70292E+00 -0.1531 78 MnCl+ 0.27032E-09 -9.5681 0.19001E-09 -9.7212 0.70292E+00 -0.1531 79 MnSO4,aq 0.27982E-18 -18.5531 0.27982E-18 -18.5531 0.10000E+01 0.0000 80 NaCl,aq 0.30233E-03 -3.5195 0.30233E-03 -3.5195 0.10000E+01 0.0000 81 NaF,aq 0.32375E-07 -7.4898 0.32375E-07 -7.4898 0.10000E+01 0.0000 82 NaOH,aq 0.40578E-13 -13.3917 0.40578E-13 -13.3917 0.10000E+01 0.0000 84 OH- 0.87537E-11 -11.0578 0.60775E-11 -11.2163 0.69428E+00 -0.1585 90 H3PO3,aq 0.28869E-19 -19.5396 0.28869E-19 -19.5396 0.10000E+01 0.0000 92 H3PO4,aq 0.26372E-07 -7.5789 0.26372E-07 -7.5789 0.10000E+01 0.0000 93 H2PO4- 0.10493E-08 -8.9791 0.73524E-09 -9.1336 0.70072E+00 -0.1545 95 H4P2O7,aq 0.92138E-17 -17.0356 0.92138E-17 -17.0356 0.10000E+01 0.0000 96 H3P2O7- 0.17805E-17 -17.7494 0.12434E-17 -17.9054 0.69833E+00 -0.1559 97 H2P2O7-2 0.16459E-18 -18.7836 0.42593E-19 -19.3707 0.25878E+00 -0.5871 100 H2S,aq 0.67181E-01 -1.1728 0.62926E-01 -1.2012 0.93666E+00 -0.0284 101 S2-2 0.35994E-15 -15.4438 0.93144E-16 -16.0308 0.25878E+00 -0.5871 102 S3-2 0.27695E-14 -14.5576 0.71669E-15 -15.1447 0.25878E+00 -0.5871 103 S3- 0.62003E-09 -9.2076 0.43299E-09 -9.3635 0.69833E+00 -0.1559 104 S4-2 0.14077E-13 -13.8515 0.36427E-14 -14.4386 0.25878E+00 -0.5871 105 S5-2 0.47709E-13 -13.3214 0.12346E-13 -13.9085 0.25878E+00 -0.5871 106 SO2,aq 0.14194E-11 -11.8479 0.14194E-11 -11.8479 0.10000E+01 0.0000 107 SO3-2 0.16828E-19 -19.7740 0.45920E-20 -20.3380 0.27287E+00 -0.5640 108 HSO3- 0.38951E-13 -13.4095 0.27201E-13 -13.5654 0.69833E+00 -0.1559 109 HSO4- 0.41229E-09 -9.3848 0.29099E-09 -9.5361 0.70579E+00 -0.1513 111 S2O3-2 0.91611E-14 -14.0381 0.23707E-14 -14.6251 0.25878E+00 -0.5871 112 HS2O3- 0.57425E-13 -13.2409 0.40102E-13 -13.3968 0.69833E+00 -0.1559 113 H2S2O3,aq 0.60821E-13 -13.2159 0.60821E-13 -13.2159 0.10000E+01 0.0000 Charge balance for all species = -.3623E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1325456E+00 0.6160200E+00 0.6051395E+03 0.0000 2 H2O 0.1000000E+01 0.5510369E+02 0.9674938E+06 0.0000 3 Cl- 0.1454969E+00 0.1475608E+00 0.5098587E+04 0.0310 4 SO4-- 0.1223760E-10 -.1319668E-06 -.1235493E-01 -9.4478 5 HCO3- 0.2657116E-05 0.4045602E+00 0.2405810E+05 -4.7051 6 HS- 0.3080165E-06 0.6718098E-01 0.2165373E+04 -5.6431 7 Al+++ 0.3136801E-05 0.3141044E-05 0.8259735E-01 -3.7523 8 H4SiO4 0.1014706E-02 0.1014706E-02 0.9505158E+02 -2.9937 9 Ca++ 0.1290790E-06 0.1368694E-06 0.5346115E-02 -5.4374 10 Mg++ 0.5226736E-10 0.5504366E-10 0.1304229E-05 -8.8373 11 Fe++ 0.2027246E-07 0.2143795E-07 0.1166834E-02 -6.2469 12 K+ 0.9277531E-04 0.9289530E-04 0.3540126E+01 -3.1619 13 Na+ 0.1287402E-01 0.1317638E-01 0.2952279E+03 -1.0227 14 Mn++ 0.1210811E-08 0.1481239E-08 0.7930930E-04 -7.4694 15 F- 0.2219811E-04 0.9997305E-02 0.1851044E+03 -3.7883 16 HPO4-- 0.1614475E-14 0.2742090E-07 0.2564979E-02 -13.3273 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4071622E+01 0.9365396E+00 0.9072161E+00 0.2227867E+01 2 H2O 0.8095700E+02 0.8377454E+02 -.7469936E+00 -.2070548E+01 3 Cl- 0.2243378E+00 0.2243377E+00 0.0000000E+00 0.1423312E-06 4 SO4-- 0.1814350E+00 -.2006300E-06 0.1814432E+00 -.8062071E-05 5 HCO3- 0.2747412E+01 0.6150558E+00 0.0000000E+00 0.2132357E+01 6 HS- 0.7419903E+00 0.1021357E+00 0.5443297E+00 0.9552487E-01 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1542665E-02 0.1061035E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1520010E-01 0.1519897E-01 0.0000000E+00 0.1121567E-05 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1814E-15 Mass of aqueous solution: 0.155993E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 37.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.6179E-01 -1.209 1.113 0.046 1.133 24.56 CO2,gas 2.132 0.329 93.84 1.972 95.55 1148. CH4,gas 0.7899E-05 -5.102 0.1267E-03 -3.897 0.1290E-03 0.5100E-02 H2,gas 0.6450E-06 -6.190 0.1303E-05 -5.885 0.1327E-05 0.4109E-03 H2S,gas 0.9552E-01 -1.020 3.255 0.513 3.314 48.63 S2,gas 0.2458E-10 -10.609 0.1576E-08 -8.802 0.1605E-08 0.1525E-07 CO,gas 0.7192E-08 -8.143 0.2015E-06 -6.696 0.2051E-06 0.4463E-05 SO3,gas 0.4970E-30 -30.304 0.3979E-28 -28.400 0.4052E-28 0.3084E-27 SO2,gas 0.2811E-12 -12.551 0.1801E-10 -10.745 0.1833E-10 0.1744E-09 HF,gas 0.1122E-05 -5.950 0.2243E-04 -4.649 0.2284E-04 0.6959E-03 HCl,gas 0.1423E-06 -6.847 0.5189E-05 -5.285 0.5284E-05 0.8832E-04 quartz 0.1061E-01 -1.974 0.6375 -0.196 2.667 0.2407 sulfur 0.7258 -0.139 23.27 1.367 97.33 11.26 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2699E-01 0.1349E+01 0.7419 0.000 CO2,gas 0.9313E+00 0.4656E+02 0.8707 1.608 CH4,gas 0.3450E-05 0.1725E-03 1.0376 -3.747 H2,gas 0.2817E-06 0.1409E-04 1.0270 -4.840 H2S,gas 0.4172E-01 0.2086E+01 0.8293 0.238 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.3141E-08 0.1571E-06 1.0000 -6.804 SO3,gas 0.2171E-30 0.1085E-28 1.0000 -28.964 SO2,gas 0.1228E-12 0.6138E-11 1.0000 -11.212 HF,gas 0.4898E-06 0.2449E-04 1.0000 -4.611 HCl,gas 0.6216E-07 0.3108E-05 1.0000 -5.508 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 5.838884 % Solid products produced: Mass = 23.905750 g Volume = 11.497766 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 37.9999900 moles log = 1.5798 Original solution: 1000.0103000 g Original solution / Rock added: 26.32 (Water/Rock Ratio), log = 1.4202 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 -0.37914E-12 2 CO2,gas -6.66 -6.66 0.00 0.000 -0.15165E-11 3 CH4,gas 4.54 4.54 0.00 0.000 -0.15165E-11 4 H2,gas 8.00 8.00 0.00 0.000 0.00000E+00 5 H2S,gas -6.23 -6.23 0.00 0.000 -0.15165E-11 6 S2,gas -7.34 -7.34 0.00 0.000 -0.60662E-11 7 CO,gas 3.21 3.21 0.00 0.000 -0.75827E-12 8 SO3,gas 17.12 17.12 0.00 0.000 -0.60662E-11 9 SO2,gas 0.83 0.83 0.00 0.000 -0.37914E-12 10 HF,gas 0.47 0.47 0.00 0.000 0.37914E-12 11 HCl,gas 5.19 5.19 0.00 0.000 0.00000E+00 150 quartz -2.99 -2.99 0.00 0.000 0.75827E-12 172 sulfur -9.15 -9.15 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.82 -0.72 -0.206 0.12334E+04 89 graphite -3.55 -3.82 -0.28 -0.080 0.47562E+03 92 halite 1.57 -3.04 -4.61 -2.307 0.78790E+04 145 pyrite -21.25 -23.09 -1.84 -0.434 0.31478E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 37.9999900 MOLES New total amount of reactant added: 38.9999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 21 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 38.9999900 Water: Moles liquid = 0.8530E+02 kg liquid = 0.1537E+01 Moles total = 0.8178E+02 kg total = 0.1473E+01 Activity = 0.9951 Stoichiometric ionic strength = .3249805E+00 Osmotic coef. = 0.9148 True ionic strength = .1477461E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2302E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13490E+00 -0.8700 0.96159E-01 -1.0170 0.71281E+00 -0.1470 2 H2O 0.99507E+00 -0.0021 0.99507E+00 -0.0021 3 Cl- 0.14771E+00 -0.8306 0.10300E+00 -0.9872 0.69729E+00 -0.1566 4 SO4-- 0.11722E-10 -10.9310 0.30379E-11 -11.5174 0.25916E+00 -0.5864 5 HCO3- 0.26172E-05 -5.5822 0.18347E-05 -5.7364 0.70102E+00 -0.1543 6 HS- 0.30517E-06 -6.5155 0.21290E-06 -6.6718 0.69766E+00 -0.1564 7 Al+++ 0.31035E-05 -5.5081 0.14605E-06 -6.8355 0.47060E-01 -1.3274 8 H4SiO4 0.10146E-02 -2.9937 0.10146E-02 -2.9937 0.10000E+01 0.0000 9 Ca++ 0.12764E-06 -6.8940 0.32119E-07 -7.4932 0.25163E+00 -0.5992 10 Mg++ 0.51689E-10 -10.2866 0.12788E-10 -10.8932 0.24740E+00 -0.6066 11 Fe++ 0.20047E-07 -7.6979 0.49797E-08 -8.3028 0.24840E+00 -0.6049 12 K+ 0.91786E-04 -4.0372 0.64372E-04 -4.1913 0.70132E+00 -0.1541 13 Na+ 0.12733E-01 -1.8951 0.88670E-02 -2.0522 0.69636E+00 -0.1572 14 Mn++ 0.11961E-08 -8.9222 0.29801E-09 -9.5258 0.24915E+00 -0.6035 15 F- 0.22210E-04 -4.6535 0.15387E-04 -4.8129 0.69278E+00 -0.1594 16 HPO4-- 0.15568E-14 -14.8078 0.40367E-15 -15.3940 0.25930E+00 -0.5862 17 SiF6-2 0.14504E-10 -10.8385 0.37293E-11 -11.4284 0.25713E+00 -0.5898 18 HSiO3- 0.14198E-10 -10.8478 0.99005E-11 -11.0043 0.69729E+00 -0.1566 19 Ca(HSiO3)+ 0.10318E-16 -16.9864 0.72419E-17 -17.1401 0.70190E+00 -0.1537 21 NaHSiO3,aq 0.14199E-11 -11.8478 0.14199E-11 -11.8478 0.10000E+01 0.0000 22 AlO+ 0.30464E-11 -11.5162 0.21382E-11 -11.6699 0.70190E+00 -0.1537 23 AlOH+2 0.40943E-08 -8.3878 0.10238E-08 -8.9898 0.25006E+00 -0.6020 24 HAlO2,aq 0.44065E-14 -14.3559 0.44065E-14 -14.3559 0.10000E+01 0.0000 25 AlO2- 0.14633E-18 -18.8347 0.10144E-18 -18.9938 0.69323E+00 -0.1591 26 CH4,aq 0.13271E-06 -6.8771 0.12429E-06 -6.9056 0.93652E+00 -0.0285 27 C2H6,aq 0.25452E-15 -15.5943 0.23837E-15 -15.6228 0.93652E+00 -0.0285 31 CO,aq 0.10596E-09 -9.9749 0.10596E-09 -9.9749 0.10000E+01 0.0000 32 CO2,aq 0.40452E+00 -0.3931 0.37884E+00 -0.4215 0.93652E+00 -0.0285 33 CO3-2 0.64813E-14 -14.1883 0.16666E-14 -14.7782 0.25713E+00 -0.5898 34 CaCO3,aq 0.67118E-18 -18.1732 0.67118E-18 -18.1732 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.21431E-11 -11.6690 0.15042E-11 -11.8227 0.70190E+00 -0.1537 36 CaCl+ 0.76274E-08 -8.1176 0.53537E-08 -8.2713 0.70190E+00 -0.1537 37 CaCl2,aq 0.13101E-09 -9.8827 0.13101E-09 -9.8827 0.10000E+01 0.0000 38 CaF+ 0.10280E-10 -10.9880 0.72154E-11 -11.1417 0.70190E+00 -0.1537 39 CaOH+ 0.33748E-16 -16.4717 0.23688E-16 -16.6255 0.70190E+00 -0.1537 40 CaSO4,aq 0.30984E-16 -16.5089 0.30984E-16 -16.5089 0.10000E+01 0.0000 41 HCl,aq 0.18149E-02 -2.7411 0.18149E-02 -2.7411 0.10000E+01 0.0000 45 HF,aq 0.10129E-01 -1.9944 0.10129E-01 -1.9944 0.10000E+01 0.0000 46 HF2- 0.75461E-07 -7.1223 0.52618E-07 -7.2789 0.69729E+00 -0.1566 47 Fe+3 0.77598E-17 -17.1102 0.36943E-18 -18.4325 0.47609E-01 -1.3223 48 FeCl+ 0.11566E-08 -8.9368 0.81184E-09 -9.0905 0.70190E+00 -0.1537 49 FeCl2,aq 0.26474E-14 -14.5772 0.26474E-14 -14.5772 0.10000E+01 0.0000 50 FeCl+2 0.10872E-16 -16.9637 0.27187E-17 -17.5656 0.25006E+00 -0.6020 51 FeF+ 0.55784E-11 -11.2535 0.39155E-11 -11.4072 0.70190E+00 -0.1537 52 FeF+2 0.20260E-15 -15.6934 0.50662E-16 -16.2953 0.25006E+00 -0.6020 54 FeOH+ 0.23898E-14 -14.6216 0.16774E-14 -14.7754 0.70190E+00 -0.1537 56 FeO+ 0.54155E-19 -19.2664 0.38011E-19 -19.4201 0.70190E+00 -0.1537 57 FeOH+2 0.27915E-17 -17.5542 0.69802E-18 -18.1561 0.25006E+00 -0.6020 60 H2,aq 0.11830E-07 -7.9270 0.11079E-07 -7.9555 0.93652E+00 -0.0285 61 KCl,aq 0.12017E-06 -6.9202 0.12017E-06 -6.9202 0.10000E+01 0.0000 62 KHSO4,aq 0.53166E-16 -16.2744 0.53166E-16 -16.2744 0.10000E+01 0.0000 63 KOH,aq 0.28448E-15 -15.5460 0.28448E-15 -15.5460 0.10000E+01 0.0000 64 KSO4- 0.43518E-14 -14.3613 0.30345E-14 -14.5179 0.69729E+00 -0.1566 66 Mg(HCO3)+ 0.87187E-15 -15.0595 0.61197E-15 -15.2133 0.70190E+00 -0.1537 67 MgCl+ 0.27524E-11 -11.5603 0.19319E-11 -11.7140 0.70190E+00 -0.1537 68 MgF+ 0.15161E-13 -13.8193 0.10642E-13 -13.9730 0.70190E+00 -0.1537 69 MgOH+ 0.74353E-19 -19.1287 0.52188E-19 -19.2824 0.70190E+00 -0.1537 71 MnF+ 0.11004E-12 -12.9585 0.77234E-13 -13.1122 0.70190E+00 -0.1537 73 MnOH+ 0.13286E-16 -16.8766 0.93252E-17 -17.0303 0.70190E+00 -0.1537 78 MnCl+ 0.26929E-09 -9.5698 0.18901E-09 -9.7235 0.70190E+00 -0.1537 79 MnSO4,aq 0.26135E-18 -18.5828 0.26135E-18 -18.5828 0.10000E+01 0.0000 80 NaCl,aq 0.30267E-03 -3.5190 0.30267E-03 -3.5190 0.10000E+01 0.0000 81 NaF,aq 0.31942E-07 -7.4956 0.31942E-07 -7.4956 0.10000E+01 0.0000 82 NaOH,aq 0.39424E-13 -13.4042 0.39424E-13 -13.4042 0.10000E+01 0.0000 84 OH- 0.86248E-11 -11.0643 0.59789E-11 -11.2234 0.69323E+00 -0.1591 90 H3PO3,aq 0.28738E-19 -19.5415 0.28738E-19 -19.5415 0.10000E+01 0.0000 92 H3PO4,aq 0.26106E-07 -7.5833 0.26106E-07 -7.5833 0.10000E+01 0.0000 93 H2PO4- 0.10234E-08 -8.9900 0.71607E-09 -9.1450 0.69969E+00 -0.1551 95 H4P2O7,aq 0.90294E-17 -17.0443 0.90294E-17 -17.0443 0.10000E+01 0.0000 96 H3P2O7- 0.17193E-17 -17.7646 0.11989E-17 -17.9212 0.69729E+00 -0.1566 97 H2P2O7-2 0.15713E-18 -18.8037 0.40404E-19 -19.3936 0.25713E+00 -0.5898 100 H2S,aq 0.67562E-01 -1.1703 0.63273E-01 -1.1988 0.93652E+00 -0.0285 101 S2-2 0.35257E-15 -15.4528 0.90657E-16 -16.0426 0.25713E+00 -0.5898 102 S3-2 0.27128E-14 -14.5666 0.69756E-15 -15.1564 0.25713E+00 -0.5898 103 S3- 0.61262E-09 -9.2128 0.42717E-09 -9.3694 0.69729E+00 -0.1566 104 S4-2 0.13789E-13 -13.8605 0.35455E-14 -14.4503 0.25713E+00 -0.5898 105 S5-2 0.46732E-13 -13.3304 0.12016E-13 -13.9202 0.25713E+00 -0.5898 106 SO2,aq 0.14036E-11 -11.8528 0.14036E-11 -11.8528 0.10000E+01 0.0000 107 SO3-2 0.16204E-19 -19.7904 0.43952E-20 -20.3570 0.27125E+00 -0.5666 108 HSO3- 0.37950E-13 -13.4208 0.26463E-13 -13.5774 0.69729E+00 -0.1566 109 HSO4- 0.39944E-09 -9.3986 0.28152E-09 -9.5505 0.70479E+00 -0.1519 111 S2O3-2 0.88246E-14 -14.0543 0.22691E-14 -14.6441 0.25713E+00 -0.5898 112 HS2O3- 0.55950E-13 -13.2522 0.39013E-13 -13.4088 0.69729E+00 -0.1566 113 H2S2O3,aq 0.60141E-13 -13.2208 0.60141E-13 -13.2208 0.10000E+01 0.0000 Charge balance for all species = -.3584E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1349019E+00 0.6189303E+00 0.6079426E+03 0.0000 2 H2O 0.1000000E+01 0.5510373E+02 0.9674057E+06 0.0000 3 Cl- 0.1477115E+00 0.1498292E+00 0.5176492E+04 0.0298 4 SO4-- 0.1172174E-10 -.1349013E-06 -.1262851E-01 -9.4834 5 HCO3- 0.2617177E-05 0.4045252E+00 0.2405382E+05 -4.7194 6 HS- 0.3051697E-06 0.6756270E-01 0.2177477E+04 -5.6548 7 Al+++ 0.3103504E-05 0.3107602E-05 0.8171045E-01 -3.7845 8 H4SiO4 0.1014554E-02 0.1014555E-02 0.9502864E+02 -2.9937 9 Ca++ 0.1276413E-06 0.1354121E-06 0.5288711E-02 -5.4592 10 Mg++ 0.5168916E-10 0.5445762E-10 0.1290225E-05 -8.8592 11 Fe++ 0.2004749E-07 0.2120970E-07 0.1154305E-02 -6.2688 12 K+ 0.9178609E-04 0.9190626E-04 0.3502114E+01 -3.1743 13 Na+ 0.1273340E-01 0.1303610E-01 0.2920579E+03 -1.0352 14 Mn++ 0.1196071E-08 0.1465469E-08 0.7845771E-04 -7.4918 15 F- 0.2221004E-04 0.1015113E-01 0.1879354E+03 -3.7958 16 HPO4-- 0.1556777E-14 0.2712895E-07 0.2537438E-02 -13.3599 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4179297E+01 0.9510904E+00 0.9310933E+00 0.2297114E+01 2 H2O 0.8177570E+02 0.8467613E+02 -.7660626E+00 -.2134366E+01 3 Cl- 0.2302378E+00 0.2302377E+00 0.0000000E+00 0.1512085E-06 4 SO4-- 0.1862100E+00 -.2072985E-06 0.1862187E+00 -.8494165E-05 5 HCO3- 0.2819712E+01 0.6216209E+00 0.0000000E+00 0.2198091E+01 6 HS- 0.7615153E+00 0.1038214E+00 0.5586560E+00 0.9903785E-01 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1559033E-02 0.1059399E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1560010E-01 0.1559892E-01 0.0000000E+00 0.1174258E-05 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.6850E-15 Mass of aqueous solution: 0.157686E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 38.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.6371E-01 -1.196 1.147 0.060 1.133 25.32 CO2,gas 2.198 0.342 96.74 1.986 95.53 1184. CH4,gas 0.8325E-05 -5.080 0.1335E-03 -3.874 0.1319E-03 0.5375E-02 H2,gas 0.6687E-06 -6.175 0.1351E-05 -5.869 0.1334E-05 0.4260E-03 H2S,gas 0.9903E-01 -1.004 3.375 0.528 3.333 50.41 S2,gas 0.2534E-10 -10.596 0.1625E-08 -8.789 0.1605E-08 0.1573E-07 CO,gas 0.7455E-08 -8.128 0.2088E-06 -6.680 0.2062E-06 0.4626E-05 SO3,gas 0.5040E-30 -30.298 0.4035E-28 -28.394 0.3985E-28 0.3127E-27 SO2,gas 0.2866E-12 -12.543 0.1836E-10 -10.736 0.1813E-10 0.1778E-09 HF,gas 0.1174E-05 -5.930 0.2349E-04 -4.629 0.2319E-04 0.7286E-03 HCl,gas 0.1512E-06 -6.820 0.5513E-05 -5.259 0.5444E-05 0.9382E-04 quartz 0.1059E-01 -1.975 0.6365 -0.196 2.596 0.2404 sulfur 0.7449 -0.128 23.88 1.378 97.40 11.55 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2699E-01 0.1349E+01 0.7419 0.000 CO2,gas 0.9311E+00 0.4655E+02 0.8707 1.608 CH4,gas 0.3526E-05 0.1763E-03 1.0376 -3.738 H2,gas 0.2833E-06 0.1416E-04 1.0270 -4.837 H2S,gas 0.4195E-01 0.2097E+01 0.8293 0.240 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.3158E-08 0.1579E-06 1.0000 -6.802 SO3,gas 0.2135E-30 0.1067E-28 1.0000 -28.972 SO2,gas 0.1214E-12 0.6070E-11 1.0000 -11.217 HF,gas 0.4974E-06 0.2487E-04 1.0000 -4.604 HCl,gas 0.6405E-07 0.3202E-05 1.0000 -5.495 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 5.947242 % Solid products produced: Mass = 24.517169 g Volume = 11.793670 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 38.9999900 moles log = 1.5911 Original solution: 1000.0103000 g Original solution / Rock added: 25.64 (Water/Rock Ratio), log = 1.4089 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 0.37914E-12 2 CO2,gas -6.66 -6.66 0.00 0.000 0.00000E+00 3 CH4,gas 4.54 4.54 0.00 0.000 0.15165E-11 4 H2,gas 8.00 8.00 0.00 0.000 0.00000E+00 5 H2S,gas -6.23 -6.23 0.00 0.000 0.00000E+00 6 S2,gas -7.34 -7.34 0.00 0.000 0.60662E-11 7 CO,gas 3.21 3.21 0.00 0.000 -0.75827E-12 8 SO3,gas 17.12 17.12 0.00 0.000 0.00000E+00 9 SO2,gas 0.83 0.83 0.00 0.000 0.26539E-11 10 HF,gas 0.47 0.47 0.00 0.000 0.37914E-12 11 HCl,gas 5.19 5.19 0.00 0.000 0.00000E+00 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 172 sulfur -9.15 -9.15 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.82 -0.72 -0.205 0.12253E+04 89 graphite -3.55 -3.82 -0.27 -0.078 0.46752E+03 92 halite 1.57 -3.04 -4.61 -2.307 0.78782E+04 145 pyrite -21.25 -23.11 -1.86 -0.438 0.31810E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 38.9999900 MOLES New total amount of reactant added: 39.9999900 MOLES Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5508E-08 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 21 Loop limit = 400 Temperature = 100.00 C Pressure = 50.00 bar Mixer fraction = 39.9999900 Water: Moles liquid = 0.8621E+02 kg liquid = 0.1553E+01 Moles total = 0.8259E+02 kg total = 0.1488E+01 Activity = 0.9950 Stoichiometric ionic strength = .3262730E+00 Osmotic coef. = 0.9148 True ionic strength = .1499134E+00 Chg. balance for total moles = -.5508E-08 Max. difference allowed = 0.2361E-04 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13721E+00 -0.8626 0.97676E-01 -1.0102 0.71189E+00 -0.1476 2 H2O 0.99500E+00 -0.0022 0.99500E+00 -0.0022 3 Cl- 0.14988E+00 -0.8243 0.10436E+00 -0.9815 0.69629E+00 -0.1572 4 SO4-- 0.11248E-10 -10.9489 0.28973E-11 -11.5380 0.25759E+00 -0.5891 5 HCO3- 0.25793E-05 -5.5885 0.18056E-05 -5.7434 0.70004E+00 -0.1549 6 HS- 0.30245E-06 -6.5194 0.21070E-06 -6.6763 0.69666E+00 -0.1570 7 Al+++ 0.30709E-05 -5.5127 0.14249E-06 -6.8462 0.46401E-01 -1.3335 8 H4SiO4 0.10144E-02 -2.9938 0.10144E-02 -2.9938 0.10000E+01 0.0000 9 Ca++ 0.12624E-06 -6.8988 0.31564E-07 -7.5008 0.25004E+00 -0.6020 10 Mg++ 0.51124E-10 -10.2914 0.12567E-10 -10.9008 0.24581E+00 -0.6094 11 Fe++ 0.19828E-07 -7.7027 0.48935E-08 -8.3104 0.24680E+00 -0.6076 12 K+ 0.90818E-04 -4.0418 0.63603E-04 -4.1965 0.70033E+00 -0.1547 13 Na+ 0.12596E-01 -1.8998 0.87584E-02 -2.0576 0.69535E+00 -0.1578 14 Mn++ 0.11817E-08 -8.9275 0.29255E-09 -9.5338 0.24756E+00 -0.6063 15 F- 0.22222E-04 -4.6532 0.15373E-04 -4.8132 0.69177E+00 -0.1600 16 HPO4-- 0.15028E-14 -14.8231 0.38731E-15 -15.4119 0.25772E+00 -0.5888 17 SiF6-2 0.15455E-10 -10.8109 0.39495E-11 -11.4035 0.25555E+00 -0.5925 18 HSiO3- 0.13997E-10 -10.8540 0.97460E-11 -11.0112 0.69629E+00 -0.1572 19 Ca(HSiO3)+ 0.99952E-17 -17.0002 0.70058E-17 -17.1545 0.70091E+00 -0.1543 21 NaHSiO3,aq 0.13806E-11 -11.8599 0.13806E-11 -11.8599 0.10000E+01 0.0000 22 AlO+ 0.28843E-11 -11.5400 0.20217E-11 -11.6943 0.70091E+00 -0.1543 23 AlOH+2 0.39574E-08 -8.4026 0.98328E-09 -9.0073 0.24846E+00 -0.6047 24 HAlO2,aq 0.41013E-14 -14.3871 0.41013E-14 -14.3871 0.10000E+01 0.0000 25 AlO2- 0.13427E-18 -18.8720 0.92945E-19 -19.0318 0.69221E+00 -0.1598 26 CH4,aq 0.13554E-06 -6.8679 0.12692E-06 -6.8965 0.93637E+00 -0.0286 27 C2H6,aq 0.26406E-15 -15.5783 0.24726E-15 -15.6068 0.93637E+00 -0.0286 30 ethanol,aq 0.10029E-19 -19.9987 0.93910E-20 -20.0273 0.93637E+00 -0.0286 31 CO,aq 0.10650E-09 -9.9727 0.10650E-09 -9.9727 0.10000E+01 0.0000 32 CO2,aq 0.40449E+00 -0.3931 0.37875E+00 -0.4216 0.93637E+00 -0.0286 33 CO3-2 0.63183E-14 -14.1994 0.16147E-14 -14.7919 0.25555E+00 -0.5925 34 CaCO3,aq 0.63906E-18 -18.1945 0.63906E-18 -18.1945 0.10000E+01 0.0000 35 Ca(HCO3)+ 0.20756E-11 -11.6829 0.14548E-11 -11.8372 0.70091E+00 -0.1543 36 CaCl+ 0.76055E-08 -8.1189 0.53308E-08 -8.2732 0.70091E+00 -0.1543 37 CaCl2,aq 0.13217E-09 -9.8789 0.13217E-09 -9.8789 0.10000E+01 0.0000 38 CaF+ 0.10107E-10 -10.9954 0.70845E-11 -11.1497 0.70091E+00 -0.1543 39 CaOH+ 0.32694E-16 -16.4855 0.22916E-16 -16.6399 0.70091E+00 -0.1543 40 CaSO4,aq 0.29040E-16 -16.5370 0.29040E-16 -16.5370 0.10000E+01 0.0000 41 HCl,aq 0.18679E-02 -2.7286 0.18679E-02 -2.7286 0.10000E+01 0.0000 45 HF,aq 0.10279E-01 -1.9880 0.10279E-01 -1.9880 0.10000E+01 0.0000 46 HF2- 0.76624E-07 -7.1156 0.53353E-07 -7.2728 0.69629E+00 -0.1572 47 Fe+3 0.78345E-17 -17.1060 0.36780E-18 -18.4344 0.46945E-01 -1.3284 48 FeCl+ 0.11532E-08 -8.9381 0.80833E-09 -9.0924 0.70091E+00 -0.1543 49 FeCl2,aq 0.26707E-14 -14.5734 0.26707E-14 -14.5734 0.10000E+01 0.0000 50 FeCl+2 0.11038E-16 -16.9571 0.27425E-17 -17.5619 0.24846E+00 -0.6047 51 FeF+ 0.54846E-11 -11.2609 0.38442E-11 -11.4152 0.70091E+00 -0.1543 52 FeF+2 0.20282E-15 -15.6929 0.50392E-16 -16.2976 0.24846E+00 -0.6047 54 FeOH+ 0.23150E-14 -14.6354 0.16226E-14 -14.7898 0.70091E+00 -0.1543 56 FeO+ 0.52323E-19 -19.2813 0.36674E-19 -19.4356 0.70091E+00 -0.1543 57 FeOH+2 0.27533E-17 -17.5602 0.68409E-18 -18.1649 0.24846E+00 -0.6047 60 H2,aq 0.11894E-07 -7.9247 0.11137E-07 -7.9532 0.93637E+00 -0.0286 61 KCl,aq 0.12030E-06 -6.9197 0.12030E-06 -6.9197 0.10000E+01 0.0000 62 KHSO4,aq 0.50891E-16 -16.2934 0.50891E-16 -16.2934 0.10000E+01 0.0000 63 KOH,aq 0.27669E-15 -15.5580 0.27669E-15 -15.5580 0.10000E+01 0.0000 64 KSO4- 0.41067E-14 -14.3865 0.28595E-14 -14.5437 0.69629E+00 -0.1572 66 Mg(HCO3)+ 0.84440E-15 -15.0735 0.59185E-15 -15.2278 0.70091E+00 -0.1543 67 MgCl+ 0.27444E-11 -11.5616 0.19236E-11 -11.7159 0.70091E+00 -0.1543 68 MgF+ 0.14907E-13 -13.8266 0.10448E-13 -13.9810 0.70091E+00 -0.1543 69 MgOH+ 0.72027E-19 -19.1425 0.50485E-19 -19.2968 0.70091E+00 -0.1543 71 MnF+ 0.10807E-12 -12.9663 0.75750E-13 -13.1206 0.70091E+00 -0.1543 73 MnOH+ 0.12857E-16 -16.8909 0.90114E-17 -17.0452 0.70091E+00 -0.1543 78 MnCl+ 0.26822E-09 -9.5715 0.18800E-09 -9.7258 0.70091E+00 -0.1543 79 MnSO4,aq 0.24469E-18 -18.6114 0.24469E-18 -18.6114 0.10000E+01 0.0000 80 NaCl,aq 0.30291E-03 -3.5187 0.30291E-03 -3.5187 0.10000E+01 0.0000 81 NaF,aq 0.31522E-07 -7.5014 0.31522E-07 -7.5014 0.10000E+01 0.0000 82 NaOH,aq 0.38333E-13 -13.4164 0.38333E-13 -13.4164 0.10000E+01 0.0000 84 OH- 0.85026E-11 -11.0704 0.58856E-11 -11.2302 0.69221E+00 -0.1598 90 H3PO3,aq 0.28603E-19 -19.5436 0.28603E-19 -19.5436 0.10000E+01 0.0000 92 H3PO4,aq 0.25844E-07 -7.5876 0.25844E-07 -7.5876 0.10000E+01 0.0000 93 H2PO4- 0.99884E-09 -9.0005 0.69789E-09 -9.1562 0.69870E+00 -0.1557 95 H4P2O7,aq 0.88503E-17 -17.0530 0.88503E-17 -17.0530 0.10000E+01 0.0000 96 H3P2O7- 0.16614E-17 -17.7795 0.11568E-17 -17.9367 0.69629E+00 -0.1572 97 H2P2O7-2 0.15019E-18 -18.8234 0.38381E-19 -19.4159 0.25555E+00 -0.5925 100 H2S,aq 0.67929E-01 -1.1679 0.63607E-01 -1.1965 0.93637E+00 -0.0286 101 S2-2 0.34562E-15 -15.4614 0.88326E-16 -16.0539 0.25555E+00 -0.5925 102 S3-2 0.26594E-14 -14.5752 0.67962E-15 -15.1677 0.25555E+00 -0.5925 103 S3- 0.60556E-09 -9.2178 0.42164E-09 -9.3751 0.69629E+00 -0.1572 104 S4-2 0.13517E-13 -13.8691 0.34543E-14 -14.4616 0.25555E+00 -0.5925 105 S5-2 0.45811E-13 -13.3390 0.11707E-13 -13.9315 0.25555E+00 -0.5925 106 SO2,aq 0.13887E-11 -11.8574 0.13887E-11 -11.8574 0.10000E+01 0.0000 107 SO3-2 0.15626E-19 -19.8061 0.42142E-20 -20.3753 0.26969E+00 -0.5691 108 HSO3- 0.37015E-13 -13.4316 0.25773E-13 -13.5888 0.69629E+00 -0.1572 109 HSO4- 0.38749E-09 -9.4117 0.27273E-09 -9.5643 0.70383E+00 -0.1525 111 S2O3-2 0.85135E-14 -14.0699 0.21757E-14 -14.6624 0.25555E+00 -0.5925 112 HS2O3- 0.54571E-13 -13.2630 0.37997E-13 -13.4202 0.69629E+00 -0.1572 113 H2S2O3,aq 0.59499E-13 -13.2255 0.59499E-13 -13.2255 0.10000E+01 0.0000 Charge balance for all species = -.3546E-08 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1372079E+00 0.6217739E+00 0.6106810E+03 0.0000 2 H2O 0.1000000E+01 0.5510376E+02 0.9673196E+06 0.0000 3 Cl- 0.1498788E+00 0.1520498E+00 0.5252742E+04 0.0287 4 SO4-- 0.1124771E-10 -.1377644E-06 -.1289538E-01 -9.5176 5 HCO3- 0.2579344E-05 0.4044924E+00 0.2404971E+05 -4.7332 6 HS- 0.3024467E-06 0.6792943E-01 0.2189100E+04 -5.6661 7 Al+++ 0.3070904E-05 0.3074864E-05 0.8084241E-01 -3.8156 8 H4SiO4 0.1014406E-02 0.1014406E-02 0.9500621E+02 -2.9938 9 Ca++ 0.1262358E-06 0.1339856E-06 0.5232527E-02 -5.4804 10 Mg++ 0.5112378E-10 0.5388393E-10 0.1276519E-05 -8.8804 11 Fe++ 0.1982753E-07 0.2098627E-07 0.1142042E-02 -6.2900 12 K+ 0.9081776E-04 0.9093806E-04 0.3464909E+01 -3.1863 13 Na+ 0.1259582E-01 0.1289876E-01 0.2889552E+03 -1.0474 14 Mn++ 0.1181700E-08 0.1450031E-08 0.7762422E-04 -7.5134 15 F- 0.2222249E-04 0.1030172E-01 0.1907063E+03 -3.8030 16 HPO4-- 0.1502822E-14 0.2684316E-07 0.2510482E-02 -13.3915 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ 0.4286972E+01 0.9656326E+00 0.9549706E+00 0.2366369E+01 2 H2O 0.8259440E+02 0.8557771E+02 -.7851317E+00 -.2198182E+01 3 Cl- 0.2361378E+00 0.2361377E+00 0.0000000E+00 0.1603158E-06 4 SO4-- 0.1909850E+00 -.2139521E-06 0.1909941E+00 -.8932676E-05 5 HCO3- 0.2892012E+01 0.6281882E+00 0.0000000E+00 0.2263824E+01 6 HS- 0.7810403E+00 0.1054963E+00 0.5729823E+00 0.1025616E+00 7 Al+++ 0.4775352E-05 0.4775352E-05 0.0000000E+00 0.0000000E+00 8 H4SiO4 0.1215302E-01 0.1575401E-02 0.1057762E-01 0.0000000E+00 9 Ca++ 0.2080835E-06 0.2080835E-06 0.0000000E+00 0.0000000E+00 10 Mg++ 0.8368328E-10 0.8368328E-10 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3259227E-07 0.3259227E-07 0.0000000E+00 0.0000000E+00 12 K+ 0.1412294E-03 0.1412294E-03 0.0000000E+00 0.0000000E+00 13 Na+ 0.2003215E-01 0.2003215E-01 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2251939E-08 0.2251939E-08 0.0000000E+00 0.0000000E+00 15 F- 0.1600010E-01 0.1599887E-01 0.0000000E+00 0.1227641E-05 16 HPO4-- 0.4168819E-07 0.4168819E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1333E-16 Mass of aqueous solution: 0.159379E+04 g Temperature = 100.00 C Pressure = 50.00 bar Mixer frac. = 39.9999900 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) H2O,gas 0.6562E-01 -1.183 1.182 0.073 1.133 26.08 CO2,gas 2.264 0.355 99.63 1.998 95.52 1219. CH4,gas 0.8758E-05 -5.058 0.1405E-03 -3.852 0.1347E-03 0.5655E-02 H2,gas 0.6925E-06 -6.160 0.1399E-05 -5.854 0.1341E-05 0.4411E-03 H2S,gas 0.1026 -0.989 3.495 0.543 3.351 52.21 S2,gas 0.2611E-10 -10.583 0.1674E-08 -8.776 0.1605E-08 0.1620E-07 CO,gas 0.7719E-08 -8.112 0.2162E-06 -6.665 0.2073E-06 0.4790E-05 SO3,gas 0.5109E-30 -30.292 0.4091E-28 -28.388 0.3922E-28 0.3170E-27 SO2,gas 0.2921E-12 -12.534 0.1871E-10 -10.728 0.1794E-10 0.1812E-09 HF,gas 0.1228E-05 -5.911 0.2455E-04 -4.610 0.2354E-04 0.7617E-03 HCl,gas 0.1603E-06 -6.795 0.5845E-05 -5.233 0.5604E-05 0.9948E-04 quartz 0.1058E-01 -1.976 0.6355 -0.197 2.529 0.2400 sulfur 0.7640 -0.117 24.49 1.389 97.47 11.85 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity H2O,gas 0.2698E-01 0.1349E+01 0.7419 0.000 CO2,gas 0.9308E+00 0.4654E+02 0.8707 1.608 CH4,gas 0.3601E-05 0.1800E-03 1.0376 -3.729 H2,gas 0.2848E-06 0.1424E-04 1.0270 -4.835 H2S,gas 0.4217E-01 0.2108E+01 0.8293 0.243 S2,gas 0.1074E-10 0.5368E-09 1.0000 -9.270 CO,gas 0.3174E-08 0.1587E-06 1.0000 -6.799 SO3,gas 0.2101E-30 0.1050E-28 1.0000 -28.979 SO2,gas 0.1201E-12 0.6005E-11 1.0000 -11.221 HF,gas 0.5048E-06 0.2524E-04 1.0000 -4.598 HCl,gas 0.6592E-07 0.3296E-05 1.0000 -5.482 quartz 0.1000E+01 0.1000E+01 1.0000 0.000 sulfur 0.1000E+01 0.1000E+01 1.0000 0.000 Current weight percent of gas: 6.053026 % Solid products produced: Mass = 25.128588 g Volume = 12.089575 cm3 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 39.9999900 moles log = 1.6021 Original solution: 1000.0103000 g Original solution / Rock added: 25.00 (Water/Rock Ratio), log = 1.3979 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.70 1.70 0.00 0.000 0.00000E+00 2 CO2,gas -6.66 -6.66 0.00 0.000 0.00000E+00 3 CH4,gas 4.54 4.54 0.00 0.000 0.00000E+00 4 H2,gas 8.00 8.00 0.00 0.000 -0.15165E-11 5 H2S,gas -6.23 -6.23 0.00 0.000 0.00000E+00 6 S2,gas -7.34 -7.34 0.00 0.000 0.00000E+00 7 CO,gas 3.21 3.21 0.00 0.000 -0.22748E-11 8 SO3,gas 17.12 17.12 0.00 0.000 0.00000E+00 9 SO2,gas 0.83 0.83 0.00 0.000 -0.37914E-12 10 HF,gas 0.47 0.47 0.00 0.000 0.37914E-12 11 HCl,gas 5.19 5.19 0.00 0.000 -0.15165E-11 150 quartz -2.99 -2.99 0.00 0.000 0.00000E+00 172 sulfur -9.15 -9.15 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 57 coesite -2.38 -2.99 -0.61 -0.204 0.10473E+04 64 cristobalite -2.56 -2.99 -0.43 -0.143 0.73267E+03 69 diamond -3.10 -3.82 -0.71 -0.204 0.12175E+04 89 graphite -3.55 -3.82 -0.27 -0.077 0.45979E+03 92 halite 1.57 -3.04 -4.61 -2.307 0.78776E+04 145 pyrite -21.25 -23.13 -1.88 -0.443 0.32133E+04 181 tridymite -2.63 -2.99 -0.36 -0.121 0.61998E+03 202 chalcedony -2.80 -2.99 -0.19 -0.062 0.31930E+03 245 silica-amorphous -2.09 -2.99 -0.90 -0.299 0.15335E+04 Calculations done for 100.0000 Deg. C; 50.0000 bar Next reactant titration increment of: 1.0000000 MOLES Current total amount of reactant added: 39.9999900 MOLES New total amount of reactant added: 40.9999900 MOLES Mixing fraction reached given limit of 0.4000E+02 TOTMIX = 0.4100E+02 Execution stopped.