File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.53194E-04 0.71223E-07 0.9615 0.00000000E+00 H2O 2 0. 0.55508E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13796E-03 0.9614 0.00000000E+00 SO4-- 4 -2. 0.25615E-04 0.25146E-04 0.9014 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.11516E-04 0.9614 0.00000000E+00 HS- 6 -1. -0.11085E-06 0.19678E-06 0.9614 0.00000000E+00 Al+++ 7 3. 0.13043E-04 0.31232E-18 0.8094 0.00000000E+00 H4SiO4 8 0. 0.41651E-04 0.41041E-04 1.0000 0.00000000E+00 Ca++ 9 2. 0.19072E-04 0.18921E-04 0.9013 0.00000000E+00 Mg++ 10 2. 0.31746E-05 0.31561E-05 0.9012 0.00000000E+00 Fe++ 11 2. 0.28520E-05 0.44753E-07 0.9012 0.00000000E+00 K+ 12 1. 0.84926E-06 0.84895E-06 0.9614 0.00000000E+00 Na+ 13 1. 0.16509E-03 0.16508E-03 0.9614 0.00000000E+00 Mn++ 14 2. 0.69354E-07 0.66121E-07 0.9012 0.00000000E+00 HPO4-- 15 -2. 0.23670E-07 0.11135E-07 0.9014 0.00000000E+00 Chg. balance for total moles = 0.9762E-15 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 100.0000 SLIM = 0.800000E-02 TEMP = 100.0000 SINC = 0.2000E-03 TEMPC = 0.0000 TOTMIX = 0.400000E-02 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 1.0016 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0107 MnO2-2 65 -2. 40.4376 Ca(HSiO3)+ 17 1. 7.6603 HMnO2- 66 -1. 29.1018 Mg(HSiO3)+ 18 1. 7.5653 MnO4- 67 -1. 83.3383 NaHSiO3,aq 19 0. 7.8098 MnO4-2 68 -2. 81.3024 AlO+ 20 1. 6.8891 MnCl+ 69 1. -0.7819 AlOH+2 21 2. 3.1893 MnSO4,aq 70 0. -2.4524 HAlO2,aq 22 0. 10.5878 NaCl,aq 71 0. 0.4861 AlO2- 23 -1. 16.2390 NaOH,aq 72 0. 12.3571 CH4,aq 24 0. 6.0082 O2,aq 73 0. 53.5759 C2H6,aq 25 0. 12.3556 OH- 74 -1. 12.2220 C3H8,aq 26 0. 17.3423 HO2- 75 -1. 50.7897 C4H10,aq 27 0. 22.3397 H2O2,aq 76 0. 40.0297 ethanol,aq 28 0. 15.3114 H3PO2,aq 77 0. 24.3310 CO,aq 29 0. 4.7087 H2PO2- 78 -1. 26.5491 CO2,aq 30 0. -6.3045 HPO3-2 79 -2. 11.9246 CO3-2 31 -2. 10.0340 H3PO3,aq 80 0. 3.5932 CaCO3,aq 32 0. 5.9460 H2PO3- 81 -1. 5.6314 Ca(HCO3)+ 33 1. -1.4013 H3PO4,aq 82 0. -9.8087 CaCl+ 34 1. -0.2023 H2PO4- 83 -1. -7.2438 CaCl2,aq 35 0. 0.4306 PO4-3 84 -3. 12.0588 CaOH+ 36 1. 10.1517 H4P2O7,aq 85 0. -17.7539 CaSO4,aq 37 0. -2.4936 H3P2O7- 86 -1. -15.8646 HCl,aq 38 0. 0.7256 H2P2O7-2 87 -2. -13.3812 HClO,aq 39 0. 32.4377 HP2O7-3 88 -3. -6.6931 ClO- 40 -1. 39.6416 P2O7-4 89 -4. 2.9147 HClO2,aq 41 0. 70.2060 H2S,aq 90 0. -6.4778 Fe+3 42 3. 8.3763 S2-2 91 -2. 1.2336 FeCl+ 43 1. -0.1924 S3-2 92 -2. -8.7963 FeCl2,aq 44 0. 4.3160 S3- 93 -1. -16.3178 FeCl+2 45 2. 6.5223 S4-2 94 -2. -18.6473 FeO,aq 46 0. 16.4029 S5-2 95 -2. -28.3223 FeOH+ 47 1. 7.4795 SO2,aq 96 0. -0.1980 HFeO2- 48 -1. 24.3713 SO3-2 97 -2. 10.2895 FeO+ 49 1. 11.3812 HSO3- 98 -1. 2.5222 FeOH+2 50 2. 9.1115 HSO4- 99 -1. -2.9675 FeO2- 51 -1. 24.0877 HSO5- 100 -1. 38.8657 HFeO2,aq 52 0. 15.9903 S2O3-2 101 -2. -4.5491 H2,aq 53 0. 9.4241 HS2O3- 102 -1. -6.8007 KCl,aq 54 0. 1.7519 H2S2O3,aq 103 0. -7.9944 KHSO4,aq 55 0. -0.4275 S2O4-2 104 -2. 10.5639 KOH,aq 56 0. 12.3606 HS2O4- 105 -1. 7.6762 KSO4- 57 -1. -1.1877 H2S2O4,aq 106 0. 6.6566 MgCO3,aq 58 0. 6.5483 S2O5-2 107 -2. 10.0891 Mg(HCO3)+ 59 1. -1.4098 S2O6-2 108 -2. 11.5737 MgCl+ 60 1. -0.1603 S2O8-2 109 -2. 42.1139 MgOH+ 61 1. 9.4082 S3O6-2 110 -2. 3.8101 Mn+3 62 3. 19.1332 S4O6-2 111 -2. -17.8301 MnO,aq 63 0. 17.9765 S5O6-2 112 -2. -14.1051 MnOH+ 64 1. 8.5115 113 0. 10.3157 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.984 0.0000E+00 osumilite(2) 124 20.895 0.0000E+00 CO2,gas 2 -6.363 0.0000E+00 osumilite-Fe 125 14.657 0.0000E+00 CH4,gas 3 4.809 0.0000E+00 pargasite 126 65.279 0.0000E+00 H2,gas 4 8.287 0.0000E+00 periclase 127 16.149 0.0000E+00 H2S,gas 5 -5.943 0.0000E+00 periclase-Fe 128 11.639 0.0000E+00 S2,gas 6 -7.033 0.0000E+00 perovskite-Al 129 12.395 0.0000E+00 CO,gas 7 3.510 0.0000E+00 perovskite-Ca 130 23.818 0.0000E+00 SO3,gas 8 17.427 0.0000E+00 perovskite-Fe 131 21.158 0.0000E+00 SO2,gas 9 1.136 0.0000E+00 perovskite-Mg 132 23.132 0.0000E+00 HCl,gas 10 5.479 0.0000E+00 phase_A 133 80.267 0.0000E+00 acmite 11 7.737 0.0000E+00 phlogopite-Na 134 29.731 0.0000E+00 akermanite 12 36.495 0.0000E+00 piemontite(ordered) 135 33.876 0.0000E+00 akimotoite 13 16.606 0.0000E+00 prehnite 136 19.466 0.0000E+00 akimotoite-Fe 14 13.083 0.0000E+00 prehnite-Fe 137 22.587 0.0000E+00 albite-high 15 0.750 0.0000E+00 pumpellyite-Fe 138 46.471 0.0000E+00 albite 16 -0.328 0.0000E+00 pumpellyite-Mg 139 49.194 0.0000E+00 almandine 17 24.545 0.0000E+00 px-Mg-tschermaks 140 19.687 0.0000E+00 pyrope 18 37.348 0.0000E+00 px-Ca-tschermaks 141 18.679 0.0000E+00 spessartine 19 24.550 0.0000E+00 pyrite 142 -21.225 0.0000E+00 analcite 20 3.371 0.0000E+00 pyrrhotite 143 -4.244 0.0000E+00 andalusite 21 5.062 0.0000E+00 pyrrhotiteFe0.875 144 -6.001 0.0000E+00 andradite 22 39.088 0.0000E+00 pyroxmangite 145 7.416 0.0000E+00 grossular 23 32.828 0.0000E+00 pyrophyllite 146 -6.098 0.0000E+00 anhydrite 24 -5.280 0.0000E+00 quartz 147 -2.982 0.0000E+00 ankerite 25 -2.093 0.0000E+00 rankinite 148 40.765 0.0000E+00 annite 26 20.209 0.0000E+00 riebeckite 149 20.593 0.0000E+00 phlogopite 27 27.147 0.0000E+00 ringwoodite-Fe 150 15.486 0.0000E+00 biotite-Mn 28 33.034 0.0000E+00 ringwoodite-Mg 151 27.602 0.0000E+00 anorthite 29 12.798 0.0000E+00 rhodochrosite 152 -0.959 0.0000E+00 anthophyllite 30 51.988 0.0000E+00 rhodonite 153 7.462 0.0000E+00 anthophyllite-Fe 31 29.455 0.0000E+00 sanidine 154 -1.221 0.0000E+00 apatite-OH 32 -17.989 0.0000E+00 sapphirine(351) 155 79.204 0.0000E+00 apatite-OH-zs 33 -12.572 0.0000E+00 siderite 156 -2.588 0.0000E+00 apatite-Cl-zs 34 -16.504 0.0000E+00 sillimanite 157 5.321 0.0000E+00 aragonite 35 0.986 0.0000E+00 sodalite 158 50.255 0.0000E+00 brucite 36 12.577 0.0000E+00 spinel 159 20.934 0.0000E+00 calcite 37 0.833 0.0000E+00 spurrite 160 59.566 0.0000E+00 carnegieite-low 38 9.065 0.0000E+00 staurolite-Fe 161 74.138 0.0000E+00 carnegieite-high 39 10.134 0.0000E+00 staurolite-Mg 162 90.336 0.0000E+00 carpholite-Mg 40 8.650 0.0000E+00 staurolite-Mn 163 84.438 0.0000E+00 carpholite-Fe 41 6.783 0.0000E+00 stilbite 164 -7.406 0.0000E+00 celadonite 42 5.401 0.0000E+00 stilpnomelane-Fe 165 13.179 0.0000E+00 celadonite-Fe 43 3.937 0.0000E+00 stilpnomelane-Mg 166 27.596 0.0000E+00 chrysotile 44 23.937 0.0000E+00 stishovite 167 2.721 0.0000E+00 chondrodite 45 56.542 0.0000E+00 sudoite-Fe 168 18.437 0.0000E+00 clinochlore 46 39.193 0.0000E+00 sudoite 169 21.216 0.0000E+00 daphnite 47 29.094 0.0000E+00 sulfur 170 -9.141 0.0000E+00 chlorite-Mn 48 46.985 0.0000E+00 sylvite 171 1.345 0.0000E+00 chlorite-Al-free 49 47.262 0.0000E+00 talc 172 16.553 0.0000E+00 chloritoid-Mg 50 13.261 0.0000E+00 talc-Fe 173 13.516 0.0000E+00 chloritoid-Fe 51 9.239 0.0000E+00 talc-tschermaks 174 19.189 0.0000E+00 chloritoid-Mn 52 11.463 0.0000E+00 tephroite 175 18.113 0.0000E+00 clinohumite 53 97.255 0.0000E+00 tilleyite 176 41.473 0.0000E+00 coesite 54 -2.369 0.0000E+00 titanite-CaSi 177 15.497 0.0000E+00 cordierite-H 55 23.898 0.0000E+00 topaz-H 178 4.668 0.0000E+00 cordierite 56 24.245 0.0000E+00 tridymite 179 -2.615 0.0000E+00 cordierite-Fe 57 20.649 0.0000E+00 tremolite 180 48.003 0.0000E+00 cordierite-Mn 58 25.261 0.0000E+00 ferroactinolite 181 38.596 0.0000E+00 corundum 59 8.433 0.0000E+00 troilite-low 182 -4.394 0.0000E+00 corundum-MgSi 60 18.905 0.0000E+00 tschermakite 183 48.414 0.0000E+00 cristobalite 61 -2.549 0.0000E+00 vesuvianite 184 224.056 0.0000E+00 cummingtonite 62 52.233 0.0000E+00 wadeite-Si 185 20.233 0.0000E+00 cymrite-K 63 1.731 0.0000E+00 wadsleyite-Fe 186 15.711 0.0000E+00 deerite 64 95.982 0.0000E+00 wadsleyite-Mg 187 25.878 0.0000E+00 diaspore 65 2.896 0.1233E-04 wairakite 188 4.058 0.0000E+00 diamond 66 -3.107 0.0000E+00 walstromite 189 11.528 0.0000E+00 diopside 67 16.215 0.0000E+00 wollastonite 190 10.482 0.0000E+00 hedenbergite 68 14.244 0.0000E+00 pseudo-wollastonite 191 11.020 0.0000E+00 dolomite,ordered 69 0.587 0.0000E+00 zoisite 192 22.964 0.0000E+00 eastonite 70 28.605 0.0000E+00 akaganeite 193 7.768 0.0000E+00 enstatite 71 17.301 0.0000E+00 beidellite-Ca 194 -1.560 0.0000E+00 clinoenstatite-HiP 72 18.388 0.0000E+00 beidellite-H 195 -2.241 0.0000E+00 clinoenstatite 73 17.202 0.0000E+00 beidellite-K 196 -1.435 0.0000E+00 protoenstatite 74 17.860 0.0000E+00 beidellite-Mg 197 -1.707 0.0000E+00 epidote 75 24.775 0.0000E+00 beidellite-Na 198 -1.257 0.0000E+00 clinozoisite 76 22.921 0.0000E+00 calcium 199 84.043 0.0000E+00 epidote-Fe 77 29.937 0.0000E+00 chalcedony 200 -2.794 0.0000E+00 fayalite 78 14.079 0.0000E+00 dawsonite 201 1.714 0.0000E+00 ferrosilite 79 11.188 0.0000E+00 montmorillonite-Ca 202 -2.214 0.0000E+00 forsterite 80 21.047 0.0000E+00 montmorillonite-K 203 -2.161 0.0000E+00 gedrite 81 50.725 0.0000E+00 montmorillonite-Mg 204 -2.402 0.0000E+00 gehlenite 82 36.717 0.0000E+00 montmorillonite-Na 205 -1.961 0.0000E+00 gibbsite 83 4.097 0.0000E+00 nontronite-Ca 206 3.280 0.0000E+00 glaucophane 84 23.111 0.0000E+00 nontronite-H 207 2.596 0.0000E+00 glaucophane-Fe 85 17.417 0.0000E+00 nontronite-K 208 3.404 0.0000E+00 graphite 86 -3.549 0.0000E+00 nontronite-Mg 209 3.139 0.0000E+00 greenalite 87 16.194 0.0000E+00 nontronite-Na 210 3.583 0.0000E+00 grunerite 88 31.364 0.0000E+00 sepiolite 211 24.194 0.0000E+00 halite 89 1.582 0.0000E+00 alite 212 58.043 0.0000E+00 hematite 90 12.598 0.1393E-05 belite 213 30.461 0.0000E+00 heulandite 91 -5.707 0.0000E+00 ettringite 214 43.354 0.0000E+00 hercynite 92 17.345 0.0000E+00 gypsum 215 -4.924 0.0000E+00 hollandite 93 25.702 0.0000E+00 hemicarboaluminate 216 71.028 0.0000E+00 iron 94 19.095 0.0000E+00 hydrogarnet 217 60.721 0.0000E+00 jadeite 95 4.251 0.0000E+00 hydrogarnet-Si 218 50.654 0.0000E+00 julgoldite 96 70.573 0.0000E+00 jennite 219 24.386 0.0000E+00 kalsilite 97 7.620 0.0000E+00 monosulfoaluminate 220 53.497 0.0000E+00 kaolinite 98 -1.273 0.0000E+00 monocarboaluminate 221 61.966 0.0000E+00 kyanite 99 4.932 0.0000E+00 portlandite 222 18.282 0.0000E+00 larnite-bredigite 100 30.714 0.0000E+00 stratlingite 223 36.573 0.0000E+00 laumontite 101 2.975 0.0000E+00 tricarboaluminate 224 70.427 0.0000E+00 lawsonite 102 9.678 0.0000E+00 tobermorite 225 9.839 0.0000E+00 leucite 103 4.168 0.0000E+00 C4AH13 226 81.870 0.0000E+00 lime 104 26.009 0.0000E+00 C2AH8 227 45.260 0.0000E+00 lizardite 105 23.287 0.0000E+00 C3A 228 87.049 0.0000E+00 magnesite 106 0.709 0.0000E+00 C4AF 229 117.550 0.0000E+00 magnetite 107 20.133 0.0000E+00 CAH10 230 28.373 0.0000E+00 minnesotaite 108 10.461 0.0000E+00 alabandite 231 -0.962 0.0000E+00 minnesotaite-Mg 109 20.669 0.0000E+00 alunite 232 -10.224 0.0000E+00 magnesioferrite 110 26.257 0.0000E+00 artinite 233 15.139 0.0000E+00 majorite 111 53.314 0.0000E+00 boehmite 234 4.430 0.0000E+00 manganosite 112 14.068 0.0000E+00 dolomite,disordered 235 1.288 0.0000E+00 margarite 113 17.452 0.0000E+00 ferrous-oxide 236 9.824 0.0000E+00 meionite 114 45.158 0.0000E+00 huntite 237 3.850 0.0000E+00 merwinite 115 55.988 0.0000E+00 hydromagnesite 238 20.077 0.0000E+00 microcline 116 -2.432 0.0000E+00 nesquehonite 239 4.735 0.0000E+00 monticellite 117 24.371 0.0000E+00 potassium-oxide 240 69.039 0.0000E+00 mullite-Al 118 363.258 0.0000E+00 silica-amorphous 241 -2.080 0.0000E+00 mullite-Si 119 7.324 0.0000E+00 sodium-oxide 242 55.173 0.0000E+00 muscovite 120 2.679 0.0000E+00 an20ab80 243 2.079 0.0000E+00 paragonite 121 4.337 0.0000E+00 an25ab75 244 2.709 0.0000E+00 nepheline 122 8.378 0.0000E+00 an30ab70 245 3.344 0.0000E+00 osumilite(1) 123 21.978 0.0000E+00 tr.625ac.25prg.125 246 45.308 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 0.0040000 g log = -2.3979 Original solution: 1000.0103000 g Original solution / Rock added: 250002.58 (Water/Rock Ratio), log = 5.3979 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0040000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2571513E-03 Osmotic coef. = 0.9903 True ionic strength = .2578094E-03 Chg. balance for total moles = 0.9762E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.71223E-07 -7.1474 0.68479E-07 -7.1644 0.96147E+00 -0.0171 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13263E-03 -3.8773 0.96136E+00 -0.0171 4 SO4-- 0.25146E-04 -4.5995 0.22667E-04 -4.6446 0.90141E+00 -0.0451 5 HCO3- 0.11516E-04 -4.9387 0.11071E-04 -4.9558 0.96139E+00 -0.0171 6 HS- 0.19678E-06 -6.7060 0.18918E-06 -6.7231 0.96137E+00 -0.0171 7 Al+++ 0.31232E-18 -18.5054 0.25279E-18 -18.5972 0.80940E+00 -0.0918 8 H4SiO4 0.41041E-04 -4.3868 0.41041E-04 -4.3868 0.10000E+01 0.0000 9 Ca++ 0.18921E-04 -4.7231 0.17053E-04 -4.7682 0.90129E+00 -0.0451 10 Mg++ 0.31561E-05 -5.5008 0.28444E-05 -5.5460 0.90121E+00 -0.0452 11 Fe++ 0.44753E-07 -7.3492 0.40333E-07 -7.3943 0.90123E+00 -0.0452 12 K+ 0.84895E-06 -6.0711 0.81618E-06 -6.0882 0.96139E+00 -0.0171 13 Na+ 0.16508E-03 -3.7823 0.15870E-03 -3.7994 0.96136E+00 -0.0171 14 Mn++ 0.66121E-07 -7.1797 0.59591E-07 -7.2248 0.90124E+00 -0.0452 15 HPO4-- 0.11135E-07 -7.9533 0.10037E-07 -7.9984 0.90142E+00 -0.0451 16 HSiO3- 0.60824E-06 -6.2159 0.58474E-06 -6.2330 0.96136E+00 -0.0171 17 Ca(HSiO3)+ 0.23239E-09 -9.6338 0.22342E-09 -9.6509 0.96140E+00 -0.0171 18 Mg(HSiO3)+ 0.48238E-10 -10.3166 0.46376E-10 -10.3337 0.96140E+00 -0.0171 19 NaHSiO3,aq 0.14739E-08 -8.8315 0.14739E-08 -8.8315 0.10000E+01 0.0000 20 AlO+ 0.72386E-11 -11.1403 0.69592E-11 -11.1574 0.96140E+00 -0.0171 21 AlOH+2 0.26488E-14 -14.5769 0.23873E-14 -14.6221 0.90126E+00 -0.0451 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.68977E-06 -6.1613 0.66310E-06 -6.1784 0.96133E+00 -0.0171 24 CH4,aq 0.90675E-13 -13.0425 0.90667E-13 -13.0425 0.99992E+00 0.0000 29 CO,aq 0.27701E-15 -15.5575 0.27701E-15 -15.5575 0.10000E+01 0.0000 30 CO2,aq 0.15287E-05 -5.8157 0.15286E-05 -5.8157 0.99992E+00 0.0000 31 CO3-2 0.16584E-07 -7.7803 0.14948E-07 -7.8254 0.90138E+00 -0.0451 32 CaCO3,aq 0.31221E-08 -8.5056 0.31221E-08 -8.5056 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.49482E-08 -8.3056 0.47571E-08 -8.3227 0.96140E+00 -0.0171 34 CaCl+ 0.37489E-08 -8.4261 0.36042E-08 -8.4432 0.96140E+00 -0.0171 35 CaCl2,aq 0.11130E-12 -12.9535 0.11130E-12 -12.9535 0.10000E+01 0.0000 36 CaOH+ 0.18265E-07 -7.7384 0.17560E-07 -7.7555 0.96140E+00 -0.0171 37 CaSO4,aq 0.12044E-06 -6.9192 0.12044E-06 -6.9192 0.10000E+01 0.0000 38 HCl,aq 0.17084E-11 -11.7674 0.17084E-11 -11.7674 0.10000E+01 0.0000 43 FeCl+ 0.86664E-11 -11.0622 0.83318E-11 -11.0793 0.96140E+00 -0.0171 44 FeCl2,aq 0.34273E-19 -19.4650 0.34273E-19 -19.4650 0.10000E+01 0.0000 46 FeO,aq 0.34011E-09 -9.4684 0.34011E-09 -9.4684 0.10000E+01 0.0000 47 FeOH+ 0.20310E-07 -7.6923 0.19526E-07 -7.7094 0.96140E+00 -0.0171 48 HFeO2- 0.55569E-10 -10.2552 0.53421E-10 -10.2723 0.96136E+00 -0.0171 49 FeO+ 0.58921E-12 -12.2297 0.56647E-12 -12.2468 0.96140E+00 -0.0171 50 FeOH+2 0.80091E-17 -17.0964 0.72183E-17 -17.1416 0.90126E+00 -0.0451 51 FeO2- 0.24696E-10 -10.6074 0.23742E-10 -10.6245 0.96136E+00 -0.0171 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.70368E-08 -8.1526 0.70363E-08 -8.1527 0.99992E+00 0.0000 54 KCl,aq 0.19168E-11 -11.7174 0.19168E-11 -11.7174 0.10000E+01 0.0000 55 KHSO4,aq 0.33902E-17 -17.4698 0.33902E-17 -17.4698 0.10000E+01 0.0000 56 KOH,aq 0.51959E-11 -11.2843 0.51959E-11 -11.2843 0.10000E+01 0.0000 57 KSO4- 0.29648E-09 -9.5280 0.28503E-09 -9.5451 0.96136E+00 -0.0171 58 MgCO3,aq 0.13012E-09 -9.8857 0.13012E-09 -9.8857 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.84160E-09 -9.0749 0.80911E-09 -9.0920 0.96140E+00 -0.0171 60 MgCl+ 0.56765E-09 -9.2459 0.54574E-09 -9.2630 0.96140E+00 -0.0171 61 MgOH+ 0.16877E-07 -7.7727 0.16226E-07 -7.7898 0.96140E+00 -0.0171 63 MnO,aq 0.13415E-10 -10.8724 0.13415E-10 -10.8724 0.10000E+01 0.0000 64 MnOH+ 0.27876E-08 -8.5548 0.26800E-08 -8.5719 0.96140E+00 -0.0171 65 MnO2-2 0.10975E-18 -18.9596 0.98930E-19 -19.0047 0.90138E+00 -0.0451 66 HMnO2- 0.15268E-14 -14.8162 0.14678E-14 -14.8333 0.96136E+00 -0.0171 69 MnCl+ 0.49756E-10 -10.3032 0.47835E-10 -10.3203 0.96140E+00 -0.0171 70 MnSO4,aq 0.38281E-09 -9.4170 0.38281E-09 -9.4170 0.10000E+01 0.0000 71 NaCl,aq 0.68731E-08 -8.1628 0.68731E-08 -8.1628 0.10000E+01 0.0000 72 NaOH,aq 0.10183E-08 -8.9921 0.10183E-08 -8.9921 0.10000E+01 0.0000 74 OH- 0.91117E-05 -5.0404 0.87594E-05 -5.0575 0.96133E+00 -0.0171 79 HPO3-2 0.24748E-18 -18.6065 0.22307E-18 -18.6515 0.90138E+00 -0.0451 81 H2PO3- 0.31213E-19 -19.5057 0.30007E-19 -19.5228 0.96136E+00 -0.0171 82 H3PO4,aq 0.30303E-12 -12.5185 0.30303E-12 -12.5185 0.10000E+01 0.0000 83 H2PO4- 0.12535E-07 -7.9019 0.12051E-07 -7.9190 0.96138E+00 -0.0171 84 PO4-3 0.15800E-12 -12.8013 0.12801E-12 -12.8928 0.81016E+00 -0.0914 87 H2P2O7-2 0.12609E-16 -16.8993 0.11366E-16 -16.9444 0.90138E+00 -0.0451 88 HP2O7-3 0.42047E-16 -16.3763 0.34033E-16 -16.4681 0.80940E+00 -0.0918 89 P2O7-4 0.17600E-18 -18.7545 0.12260E-18 -18.9115 0.69660E+00 -0.1570 90 H2S,aq 0.38927E-07 -7.4098 0.38924E-07 -7.4098 0.99992E+00 0.0000 91 S2-2 0.12411E-15 -15.9062 0.11187E-15 -15.9513 0.90138E+00 -0.0451 96 SO2,aq 0.31336E-17 -17.5040 0.31336E-17 -17.5040 0.10000E+01 0.0000 97 SO3-2 0.24119E-13 -13.6176 0.21747E-13 -13.6626 0.90163E+00 -0.0450 98 HSO3- 0.90653E-13 -13.0426 0.87150E-13 -13.0597 0.96136E+00 -0.0171 99 HSO4- 0.14981E-08 -8.8245 0.14403E-08 -8.8416 0.96141E+00 -0.0171 101 S2O3-2 0.11536E-13 -13.9379 0.10398E-13 -13.9830 0.90138E+00 -0.0451 102 HS2O3- 0.13219E-18 -18.8788 0.12708E-18 -18.8959 0.96136E+00 -0.0171 Charge balance for all species = 0.9762E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7122329E-07 -.1097113E-04 -.1105808E-01 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9999832E+06 0.0000 3 Cl- 0.1379631E-03 0.1379744E-03 0.4891534E+01 3.2871 4 SO4-- 0.2514618E-04 0.2526707E-04 0.2427159E+01 9.6843 5 HCO3- 0.1151571E-04 0.1307002E-04 0.7974843E+00 2.2086 6 HS- 0.1967815E-06 0.2374390E-06 0.7852466E-02 0.4413 7 Al+++ 0.3123218E-18 0.7101129E-06 0.1915963E-01 2.8961 8 H4SiO4 0.4104120E-04 0.4165120E-04 0.4003262E+01 -4.3868 9 Ca++ 0.1892090E-04 0.1907166E-04 0.7643427E+00 9.5607 10 Mg++ 0.3156143E-05 0.3174608E-05 0.7717993E-01 8.7829 11 Fe++ 0.4475319E-07 0.6569643E-07 0.3668895E-02 6.9345 12 K+ 0.8489546E-06 0.8492582E-06 0.3320721E-01 1.0762 13 Na+ 0.1650829E-03 0.1650922E-03 0.3795381E+01 3.3650 14 Mn++ 0.6612089E-07 0.6935449E-07 0.3810141E-02 7.1041 15 HPO4-- 0.1113511E-07 0.2367034E-07 0.2271822E-02 6.3305 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5319406E-04 -.1097111E-04 -.4222295E-04 0.0000000E+00 2 H2O 0.5550820E+02 0.5550817E+02 0.2745205E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2561532E-04 0.2526703E-04 0.3482923E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1108536E-06 0.2374386E-06 -.3482923E-06 0.0000000E+00 7 Al+++ 0.1304297E-04 0.7101118E-06 0.1233285E-04 0.0000000E+00 8 H4SiO4 0.4165113E-04 0.4165113E-04 0.0000000E+00 0.0000000E+00 9 Ca++ 0.1907163E-04 0.1907163E-04 0.0000000E+00 0.0000000E+00 10 Mg++ 0.3174603E-05 0.3174603E-05 0.0000000E+00 0.0000000E+00 11 Fe++ 0.2852034E-05 0.6569633E-07 0.2786338E-05 0.0000000E+00 12 K+ 0.8492569E-06 0.8492569E-06 0.0000000E+00 0.0000000E+00 13 Na+ 0.1650920E-03 0.1650920E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6935438E-07 0.6935438E-07 0.0000000E+00 0.0000000E+00 15 HPO4-- 0.2367031E-07 0.2367031E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.0000E+00 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0040000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) diaspore 0.1233E-04 -4.909 0.7398E-03 -3.131 76.88 0.2203E-03 hematite 0.1393E-05 -5.856 0.2225E-03 -3.653 23.12 0.4217E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.000962 g Volume = 0.000262 cm3 Porosity: 99.9738% V(tot) - V(min): 0.10013E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0040000 g log = -2.3979 Original solution: 1000.0103000 g Original solution / Rock added: 250002.58 (Water/Rock Ratio), log = 5.3979 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9998E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1651E-03 1.0073 0.1750E-03 0.1737E-03 CH4,gas 0.1345E-09 1.0129 0.1434E-09 0.1416E-09 H2,gas 0.9168E-05 1.0006 0.9651E-05 0.9645E-05 H2S,gas 0.1083E-05 0.9959 0.1135E-05 0.1140E-05 S2,gas 0.4926E-21 1.0000 0.5183E-21 0.5183E-21 CO,gas 0.4157E-12 1.0000 0.4374E-12 0.4374E-12 SO3,gas 0.3777E-34 1.0000 0.3974E-34 0.3974E-34 SO2,gas 0.1379E-16 1.0000 0.1451E-16 0.1451E-16 HCl,gas 0.2867E-14 1.0000 0.3017E-14 0.3017E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.12 -5.76 -1.919 0.98300E+04 -3.757 3 CH4,gas 4.81 -7.03 -11.84 -2.961 0.20222E+05 -9.844 4 H2,gas 8.29 1.27 -7.02 -4.009 0.11979E+05 -5.015 5 H2S,gas -5.94 -13.89 -7.94 -3.972 0.13566E+05 -5.945 6 S2,gas -7.03 -30.32 -23.29 -3.582 0.39759E+05 -21.285 7 CO,gas 3.51 -10.85 -14.36 -4.418 0.24518E+05 -12.359 8 SO3,gas 17.43 -18.97 -36.40 -9.100 0.62153E+05 -34.401 9 SO2,gas 1.14 -17.70 -18.84 -5.024 0.32166E+05 -16.838 10 HCl,gas 5.48 -11.04 -16.52 -8.260 0.28208E+05 -14.520 21 andalusite 5.06 1.41 -3.66 -0.366 0.62442E+04 24 anhydrite -5.28 -9.41 -4.13 -2.067 0.70571E+04 32 apatite-OH -17.99 -19.18 -1.19 -0.092 0.20312E+04 35 aragonite 0.99 -2.56 -3.55 -1.182 0.60543E+04 36 brucite 12.58 8.78 -3.79 -0.759 0.64777E+04 37 calcite 0.83 -2.56 -3.39 -1.131 0.57930E+04 40 carpholite-Mg 8.65 5.80 -2.85 -0.190 0.48644E+04 41 carpholite-Fe 6.78 3.95 -2.83 -0.189 0.48317E+04 46 clinochlore 39.19 36.55 -2.65 -0.083 0.45195E+04 47 daphnite 29.09 27.30 -1.79 -0.056 0.30558E+04 50 chloritoid-Mg 13.26 10.19 -3.07 -0.205 0.52470E+04 51 chloritoid-Fe 9.24 8.34 -0.90 -0.060 0.15346E+04 52 chloritoid-Mn 11.46 8.51 -2.95 -0.197 0.50434E+04 54 coesite -2.37 -4.39 -2.02 -0.672 0.34447E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.39 -1.84 -0.613 0.31376E+04 78 fayalite 14.08 9.48 -4.60 -0.657 0.78487E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.03 -4.16 -0.347 0.71102E+04 92 hercynite 17.34 12.73 -4.62 -0.308 0.78848E+04 98 kaolinite -1.27 -2.98 -1.71 -0.155 0.29168E+04 99 kyanite 4.93 1.41 -3.53 -0.353 0.60210E+04 102 lawsonite 9.68 6.58 -3.10 -0.207 0.52916E+04 106 magnesite 0.71 -3.34 -4.05 -1.349 0.69096E+04 107 magnetite 20.13 19.53 -0.60 -0.049 0.10256E+04 110 magnesioferrite 26.26 21.38 -4.88 -0.398 0.83270E+04 128 periclase-Fe 11.64 6.93 -4.70 -1.176 0.80330E+04 142 pyrite -21.23 -22.11 -0.89 -0.209 0.15141E+04 143 pyrrhotite -4.24 -6.95 -2.71 -0.903 0.46263E+04 144 pyrrhotiteFe0.875 -6.00 -7.98 -1.98 -0.727 0.33748E+04 145 pyroxmangite 7.42 2.72 -4.70 -0.940 0.80230E+04 147 quartz -2.98 -4.39 -1.40 -0.468 0.23986E+04 152 rhodochrosite -0.96 -5.02 -4.06 -1.353 0.69283E+04 153 rhodonite 7.46 2.72 -4.75 -0.949 0.81022E+04 156 siderite -2.59 -5.19 -2.60 -0.866 0.44361E+04 157 sillimanite 5.32 1.41 -3.92 -0.392 0.66864E+04 178 topaz-H 4.67 1.41 -3.26 -0.297 0.55701E+04 179 tridymite -2.61 -4.39 -1.77 -0.591 0.30259E+04 182 troilite-low -4.39 -6.95 -2.56 -0.853 0.43695E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.39 -1.59 -0.531 0.27189E+04 206 nontronite-Ca 3.28 -0.97 -4.25 -0.276 0.72538E+04 209 nontronite-Mg 3.14 -1.10 -4.24 -0.275 0.72333E+04 215 gypsum -4.92 -9.41 -4.49 -1.122 0.76638E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.93 -2.89 -0.722 0.49340E+04 241 silica-amorphous -2.08 -4.39 -2.31 -0.769 0.39391E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0040000 g New total amount of reactant added: 0.0042000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.9761E-15 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0042000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2583240E-03 Osmotic coef. = 0.9903 True ionic strength = .2592270E-03 Chg. balance for total moles = 0.9761E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.65455E-07 -7.1841 0.62930E-07 -7.2011 0.96142E+00 -0.0171 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13262E-03 -3.8774 0.96131E+00 -0.0171 4 SO4-- 0.25132E-04 -4.5998 0.22649E-04 -4.6450 0.90121E+00 -0.0452 5 HCO3- 0.11624E-04 -4.9346 0.11175E-04 -4.9518 0.96133E+00 -0.0171 6 HS- 0.21058E-06 -6.6766 0.20243E-06 -6.6937 0.96131E+00 -0.0171 7 Al+++ 0.24250E-18 -18.6153 0.19618E-18 -18.7073 0.80898E+00 -0.0921 8 H4SiO4 0.43038E-04 -4.3662 0.43038E-04 -4.3662 0.10000E+01 0.0000 9 Ca++ 0.19147E-04 -4.7179 0.17253E-04 -4.7631 0.90108E+00 -0.0452 10 Mg++ 0.33124E-05 -5.4799 0.29845E-05 -5.5251 0.90100E+00 -0.0453 11 Fe++ 0.38532E-07 -7.4142 0.34718E-07 -7.4594 0.90102E+00 -0.0453 12 K+ 0.89140E-06 -6.0499 0.85694E-06 -6.0670 0.96134E+00 -0.0171 13 Na+ 0.16533E-03 -3.7816 0.15894E-03 -3.7988 0.96130E+00 -0.0171 14 Mn++ 0.69180E-07 -7.1600 0.62334E-07 -7.2053 0.90104E+00 -0.0453 15 HPO4-- 0.12217E-07 -7.9130 0.11010E-07 -7.9582 0.90121E+00 -0.0452 16 HSiO3- 0.69412E-06 -6.1586 0.66726E-06 -6.1757 0.96131E+00 -0.0171 17 Ca(HSiO3)+ 0.26831E-09 -9.5714 0.25794E-09 -9.5885 0.96134E+00 -0.0171 18 Mg(HSiO3)+ 0.57761E-10 -10.2384 0.55528E-10 -10.2555 0.96134E+00 -0.0171 19 NaHSiO3,aq 0.16844E-08 -8.7736 0.16844E-08 -8.7736 0.10000E+01 0.0000 20 AlO+ 0.66524E-11 -11.1770 0.63952E-11 -11.1941 0.96134E+00 -0.0171 21 AlOH+2 0.22374E-14 -14.6503 0.20160E-14 -14.6955 0.90105E+00 -0.0452 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.75064E-06 -6.1246 0.72157E-06 -6.1417 0.96127E+00 -0.0172 24 CH4,aq 0.98015E-13 -13.0087 0.98007E-13 -13.0087 0.99992E+00 0.0000 29 CO,aq 0.26697E-15 -15.5735 0.26697E-15 -15.5735 0.10000E+01 0.0000 30 CO2,aq 0.14180E-05 -5.8483 0.14178E-05 -5.8484 0.99992E+00 0.0000 31 CO3-2 0.18219E-07 -7.7395 0.16419E-07 -7.7847 0.90117E+00 -0.0452 32 CaCO3,aq 0.34694E-08 -8.4597 0.34694E-08 -8.4597 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.50534E-08 -8.2964 0.48580E-08 -8.3135 0.96134E+00 -0.0171 34 CaCl+ 0.37929E-08 -8.4210 0.36462E-08 -8.4382 0.96134E+00 -0.0171 35 CaCl2,aq 0.11260E-12 -12.9485 0.11260E-12 -12.9485 0.10000E+01 0.0000 36 CaOH+ 0.20110E-07 -7.6966 0.19332E-07 -7.7137 0.96134E+00 -0.0171 37 CaSO4,aq 0.12175E-06 -6.9145 0.12175E-06 -6.9145 0.10000E+01 0.0000 38 HCl,aq 0.15699E-11 -11.8041 0.15699E-11 -11.8041 0.10000E+01 0.0000 43 FeCl+ 0.74600E-11 -11.1273 0.71716E-11 -11.1444 0.96134E+00 -0.0171 44 FeCl2,aq 0.29499E-19 -19.5302 0.29499E-19 -19.5302 0.10000E+01 0.0000 46 FeO,aq 0.34668E-09 -9.4601 0.34668E-09 -9.4601 0.10000E+01 0.0000 47 FeOH+ 0.19026E-07 -7.7207 0.18290E-07 -7.7378 0.96134E+00 -0.0171 48 HFeO2- 0.61640E-10 -10.2101 0.59255E-10 -10.2273 0.96131E+00 -0.0171 49 FeO+ 0.54150E-12 -12.2664 0.52056E-12 -12.2835 0.96134E+00 -0.0171 50 FeOH+2 0.67652E-17 -17.1697 0.60958E-17 -17.2150 0.90105E+00 -0.0452 51 FeO2- 0.26875E-10 -10.5706 0.25835E-10 -10.5878 0.96131E+00 -0.0171 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.73113E-08 -8.1360 0.73107E-08 -8.1360 0.99992E+00 0.0000 54 KCl,aq 0.20124E-11 -11.6963 0.20124E-11 -11.6963 0.10000E+01 0.0000 55 KHSO4,aq 0.32684E-17 -17.4857 0.32684E-17 -17.4857 0.10000E+01 0.0000 56 KOH,aq 0.59365E-11 -11.2265 0.59365E-11 -11.2265 0.10000E+01 0.0000 57 KSO4- 0.31105E-09 -9.5072 0.29902E-09 -9.5243 0.96131E+00 -0.0171 58 MgCO3,aq 0.14996E-09 -9.8240 0.14996E-09 -9.8240 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.89138E-09 -9.0499 0.85692E-09 -9.0671 0.96134E+00 -0.0171 60 MgCl+ 0.59561E-09 -9.2250 0.57259E-09 -9.2422 0.96134E+00 -0.0171 61 MgOH+ 0.19271E-07 -7.7151 0.18526E-07 -7.7322 0.96134E+00 -0.0171 63 MnO,aq 0.16616E-10 -10.7795 0.16616E-10 -10.7795 0.10000E+01 0.0000 64 MnOH+ 0.31733E-08 -8.4985 0.30506E-08 -8.5156 0.96134E+00 -0.0171 65 MnO2-2 0.16102E-18 -18.7931 0.14511E-18 -18.8383 0.90117E+00 -0.0452 66 HMnO2- 0.20581E-14 -14.6865 0.19784E-14 -14.7037 0.96131E+00 -0.0171 69 MnCl+ 0.52046E-10 -10.2836 0.50034E-10 -10.3007 0.96134E+00 -0.0171 70 MnSO4,aq 0.40011E-09 -9.3978 0.40011E-09 -9.3978 0.10000E+01 0.0000 71 NaCl,aq 0.68828E-08 -8.1622 0.68828E-08 -8.1622 0.10000E+01 0.0000 72 NaOH,aq 0.11098E-08 -8.9548 0.11098E-08 -8.9548 0.10000E+01 0.0000 74 OH- 0.99158E-05 -5.0037 0.95318E-05 -5.0208 0.96127E+00 -0.0172 79 HPO3-2 0.28212E-18 -18.5496 0.25424E-18 -18.5948 0.90117E+00 -0.0452 81 H2PO3- 0.32693E-19 -19.4855 0.31428E-19 -19.5027 0.96131E+00 -0.0171 82 H3PO4,aq 0.28071E-12 -12.5517 0.28071E-12 -12.5517 0.10000E+01 0.0000 83 H2PO4- 0.12636E-07 -7.8984 0.12147E-07 -7.9155 0.96132E+00 -0.0171 84 PO4-3 0.18870E-12 -12.7242 0.15280E-12 -12.8159 0.80975E+00 -0.0917 87 H2P2O7-2 0.12815E-16 -16.8923 0.11549E-16 -16.9375 0.90117E+00 -0.0452 88 HP2O7-3 0.46517E-16 -16.3324 0.37631E-16 -16.4245 0.80898E+00 -0.0921 89 P2O7-4 0.21197E-18 -18.6737 0.14752E-18 -18.8311 0.69596E+00 -0.1574 90 H2S,aq 0.38278E-07 -7.4170 0.38275E-07 -7.4171 0.99992E+00 0.0000 91 S2-2 0.13680E-15 -15.8639 0.12328E-15 -15.9091 0.90117E+00 -0.0452 96 SO2,aq 0.27473E-17 -17.5611 0.27473E-17 -17.5611 0.10000E+01 0.0000 97 SO3-2 0.25046E-13 -13.6013 0.22577E-13 -13.6463 0.90142E+00 -0.0451 98 HSO3- 0.86491E-13 -13.0630 0.83144E-13 -13.0802 0.96131E+00 -0.0171 99 HSO4- 0.13756E-08 -8.8615 0.13225E-08 -8.8786 0.96136E+00 -0.0171 101 S2O3-2 0.11337E-13 -13.9455 0.10217E-13 -13.9907 0.90117E+00 -0.0452 102 HS2O3- 0.11937E-18 -18.9231 0.11475E-18 -18.9403 0.96131E+00 -0.0171 Charge balance for all species = 0.9763E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6545502E-07 -.1222758E-04 -.1232449E-01 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9999830E+06 0.0000 3 Cl- 0.1379631E-03 0.1379744E-03 0.4891533E+01 3.3238 4 SO4-- 0.2513181E-04 0.2525385E-04 0.2425889E+01 9.7573 5 HCO3- 0.1162428E-04 0.1307002E-04 0.7974842E+00 2.2494 6 HS- 0.2105806E-06 0.2506580E-06 0.8289638E-02 0.5074 7 Al+++ 0.2425024E-18 0.7709853E-06 0.2080203E-01 2.8961 8 H4SiO4 0.4303763E-04 0.4373376E-04 0.4203425E+01 -4.3662 9 Ca++ 0.1914724E-04 0.1930169E-04 0.7735616E+00 9.6392 10 Mg++ 0.3312373E-05 0.3333339E-05 0.8103892E-01 8.8772 11 Fe++ 0.3853223E-07 0.5820465E-07 0.3250506E-02 6.9428 12 K+ 0.8914022E-06 0.8917212E-06 0.3486756E-01 1.1341 13 Na+ 0.1653336E-03 0.1653433E-03 0.3801152E+01 3.4024 14 Mn++ 0.6918019E-07 0.7282222E-07 0.4000647E-02 7.1970 15 HPO4-- 0.1221722E-07 0.2485386E-07 0.2385413E-02 6.4441 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5650576E-04 -.1222756E-04 -.4427820E-04 0.0000000E+00 2 H2O 0.5550820E+02 0.5550817E+02 0.2878469E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2562087E-04 0.2525381E-04 0.3670539E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1163963E-06 0.2506576E-06 -.3670539E-06 0.0000000E+00 7 Al+++ 0.1369511E-04 0.7709840E-06 0.1292413E-04 0.0000000E+00 8 H4SiO4 0.4373369E-04 0.4373369E-04 0.0000000E+00 0.0000000E+00 9 Ca++ 0.1930166E-04 0.1930166E-04 0.0000000E+00 0.0000000E+00 10 Mg++ 0.3333333E-05 0.3333333E-05 0.0000000E+00 0.0000000E+00 11 Fe++ 0.2994636E-05 0.5820456E-07 0.2936432E-05 0.0000000E+00 12 K+ 0.8917197E-06 0.8917197E-06 0.0000000E+00 0.0000000E+00 13 Na+ 0.1653430E-03 0.1653430E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.7282210E-07 0.7282210E-07 0.0000000E+00 0.0000000E+00 15 HPO4-- 0.2485382E-07 0.2485382E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1694E-20 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0042000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) diaspore 0.1292E-04 -4.889 0.7753E-03 -3.111 76.78 0.2308E-03 hematite 0.1468E-05 -5.833 0.2345E-03 -3.630 23.22 0.4444E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.001010 g Volume = 0.000275 cm3 Porosity: 99.9725% V(tot) - V(min): 0.10014E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0042000 g log = -2.3768 Original solution: 1000.0103000 g Original solution / Rock added: 238097.69 (Water/Rock Ratio), log = 5.3768 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9998E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1531E-03 1.0073 0.1623E-03 0.1611E-03 CH4,gas 0.1454E-09 1.0129 0.1550E-09 0.1530E-09 H2,gas 0.9525E-05 1.0006 0.1003E-04 0.1002E-04 H2S,gas 0.1065E-05 0.9959 0.1116E-05 0.1121E-05 S2,gas 0.4412E-21 1.0000 0.4642E-21 0.4642E-21 CO,gas 0.4007E-12 1.0000 0.4215E-12 0.4215E-12 SO3,gas 0.3187E-34 1.0000 0.3353E-34 0.3353E-34 SO2,gas 0.1209E-16 1.0000 0.1272E-16 0.1272E-16 HCl,gas 0.2635E-14 1.0000 0.2772E-14 0.2772E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.15 -5.79 -1.930 0.98857E+04 -3.790 3 CH4,gas 4.81 -7.00 -11.81 -2.952 0.20165E+05 -9.810 4 H2,gas 8.29 1.29 -7.00 -3.999 0.11950E+05 -4.999 5 H2S,gas -5.94 -13.89 -7.95 -3.976 0.13578E+05 -5.952 6 S2,gas -7.03 -30.37 -23.33 -3.590 0.39841E+05 -21.333 7 CO,gas 3.51 -10.86 -14.38 -4.423 0.24545E+05 -12.375 8 SO3,gas 17.43 -19.05 -36.47 -9.119 0.62279E+05 -34.475 9 SO2,gas 1.14 -17.76 -18.90 -5.039 0.32264E+05 -16.896 10 HCl,gas 5.48 -11.08 -16.56 -8.279 0.28271E+05 -14.557 21 andalusite 5.06 1.43 -3.64 -0.364 0.62090E+04 24 anhydrite -5.28 -9.41 -4.13 -2.064 0.70490E+04 32 apatite-OH -17.99 -18.89 -0.90 -0.069 0.15314E+04 35 aragonite 0.99 -2.51 -3.50 -1.167 0.59761E+04 36 brucite 12.58 8.88 -3.70 -0.740 0.63167E+04 37 calcite 0.83 -2.51 -3.35 -1.116 0.57148E+04 40 carpholite-Mg 8.65 5.94 -2.71 -0.181 0.46330E+04 41 carpholite-Fe 6.78 4.00 -2.78 -0.185 0.47471E+04 46 clinochlore 39.19 37.08 -2.11 -0.066 0.36089E+04 47 daphnite 29.09 27.41 -1.69 -0.053 0.28792E+04 50 chloritoid-Mg 13.26 10.30 -2.96 -0.197 0.50508E+04 51 chloritoid-Fe 9.24 8.37 -0.87 -0.058 0.14852E+04 52 chloritoid-Mn 11.46 8.62 -2.84 -0.189 0.48495E+04 54 coesite -2.37 -4.37 -2.00 -0.666 0.34095E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.37 -1.82 -0.606 0.31024E+04 78 fayalite 14.08 9.52 -4.56 -0.651 0.77851E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.10 -4.10 -0.341 0.69972E+04 92 hercynite 17.34 12.74 -4.61 -0.307 0.78706E+04 98 kaolinite -1.27 -2.94 -1.67 -0.152 0.28463E+04 99 kyanite 4.93 1.43 -3.51 -0.351 0.59857E+04 102 lawsonite 9.68 6.70 -2.98 -0.199 0.50871E+04 106 magnesite 0.71 -3.28 -3.99 -1.328 0.68044E+04 107 magnetite 20.13 19.54 -0.59 -0.048 0.10114E+04 110 magnesioferrite 26.26 21.47 -4.78 -0.390 0.81660E+04 113 margarite 17.45 12.49 -4.96 -0.198 0.84701E+04 128 periclase-Fe 11.64 6.94 -4.70 -1.174 0.80188E+04 142 pyrite -21.23 -22.13 -0.91 -0.214 0.15532E+04 143 pyrrhotite -4.24 -6.95 -2.71 -0.903 0.46246E+04 144 pyrrhotiteFe0.875 -6.00 -7.98 -1.98 -0.728 0.33784E+04 145 pyroxmangite 7.42 2.83 -4.59 -0.917 0.78291E+04 147 quartz -2.98 -4.37 -1.38 -0.461 0.23634E+04 152 rhodochrosite -0.96 -4.96 -4.00 -1.332 0.68254E+04 153 rhodonite 7.46 2.83 -4.63 -0.926 0.79083E+04 156 siderite -2.59 -5.21 -2.62 -0.874 0.44777E+04 157 sillimanite 5.32 1.43 -3.90 -0.390 0.66511E+04 169 sudoite 21.22 16.24 -4.98 -0.161 0.84963E+04 178 topaz-H 4.67 1.43 -3.24 -0.295 0.55348E+04 179 tridymite -2.61 -4.37 -1.75 -0.584 0.29907E+04 182 troilite-low -4.39 -6.95 -2.56 -0.853 0.43678E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.37 -1.57 -0.524 0.26837E+04 206 nontronite-Ca 3.28 -0.88 -4.16 -0.270 0.71025E+04 209 nontronite-Mg 3.14 -1.01 -4.14 -0.269 0.70774E+04 210 nontronite-Na 3.58 -1.35 -4.93 -0.316 0.84187E+04 215 gypsum -4.92 -9.41 -4.48 -1.121 0.76558E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.94 -2.88 -0.720 0.49199E+04 241 silica-amorphous -2.08 -4.37 -2.29 -0.762 0.39039E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0042000 g New total amount of reactant added: 0.0044000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.9762E-15 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0044000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2595031E-03 Osmotic coef. = 0.9903 True ionic strength = .2606488E-03 Chg. balance for total moles = 0.9762E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.60495E-07 -7.2183 0.58158E-07 -7.2354 0.96136E+00 -0.0171 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13262E-03 -3.8774 0.96125E+00 -0.0172 4 SO4-- 0.25118E-04 -4.6000 0.22631E-04 -4.6453 0.90100E+00 -0.0453 5 HCO3- 0.11719E-04 -4.9311 0.11265E-04 -4.9483 0.96128E+00 -0.0172 6 HS- 0.22418E-06 -6.6494 0.21550E-06 -6.6666 0.96125E+00 -0.0172 7 Al+++ 0.19151E-18 -18.7178 0.15485E-18 -18.8101 0.80856E+00 -0.0923 8 H4SiO4 0.45028E-04 -4.3465 0.45028E-04 -4.3465 0.10000E+01 0.0000 9 Ca++ 0.19374E-04 -4.7128 0.17453E-04 -4.7581 0.90087E+00 -0.0453 10 Mg++ 0.34684E-05 -5.4599 0.31243E-05 -5.5052 0.90079E+00 -0.0454 11 Fe++ 0.33508E-07 -7.4749 0.30184E-07 -7.5202 0.90081E+00 -0.0454 12 K+ 0.93385E-06 -6.0297 0.89769E-06 -6.0469 0.96128E+00 -0.0171 13 Na+ 0.16558E-03 -3.7810 0.15917E-03 -3.7981 0.96125E+00 -0.0172 14 Mn++ 0.72214E-07 -7.1414 0.65053E-07 -7.1867 0.90083E+00 -0.0454 15 HPO4-- 0.13313E-07 -7.8757 0.11995E-07 -7.9210 0.90100E+00 -0.0453 16 HSiO3- 0.78585E-06 -6.1047 0.75540E-06 -6.1218 0.96125E+00 -0.0172 17 Ca(HSiO3)+ 0.30729E-09 -9.5125 0.29539E-09 -9.5296 0.96129E+00 -0.0171 18 Mg(HSiO3)+ 0.68460E-10 -10.1646 0.65809E-10 -10.1817 0.96129E+00 -0.0171 19 NaHSiO3,aq 0.19096E-08 -8.7190 0.19096E-08 -8.7190 0.10000E+01 0.0000 20 AlO+ 0.61483E-11 -11.2112 0.59103E-11 -11.2284 0.96129E+00 -0.0171 21 AlOH+2 0.19114E-14 -14.7186 0.17219E-14 -14.7640 0.90084E+00 -0.0454 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.81228E-06 -6.0903 0.78078E-06 -6.1075 0.96122E+00 -0.0172 24 CH4,aq 0.10527E-12 -12.9777 0.10526E-12 -12.9777 0.99992E+00 0.0000 29 CO,aq 0.25772E-15 -15.5889 0.25772E-15 -15.5889 0.10000E+01 0.0000 30 CO2,aq 0.13210E-05 -5.8791 0.13209E-05 -5.8791 0.99992E+00 0.0000 31 CO3-2 0.19878E-07 -7.7016 0.17910E-07 -7.7469 0.90096E+00 -0.0453 32 CaCO3,aq 0.38283E-08 -8.4170 0.38283E-08 -8.4170 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.51536E-08 -8.2879 0.49541E-08 -8.3050 0.96129E+00 -0.0171 34 CaCl+ 0.38368E-08 -8.4160 0.36883E-08 -8.4332 0.96129E+00 -0.0171 35 CaCl2,aq 0.11389E-12 -12.9435 0.11389E-12 -12.9435 0.10000E+01 0.0000 36 CaOH+ 0.22013E-07 -7.6573 0.21161E-07 -7.6745 0.96129E+00 -0.0171 37 CaSO4,aq 0.12307E-06 -6.9099 0.12307E-06 -6.9099 0.10000E+01 0.0000 38 HCl,aq 0.14507E-11 -11.8384 0.14507E-11 -11.8384 0.10000E+01 0.0000 43 FeCl+ 0.64858E-11 -11.1880 0.62347E-11 -11.2052 0.96129E+00 -0.0171 44 FeCl2,aq 0.25644E-19 -19.5910 0.25644E-19 -19.5910 0.10000E+01 0.0000 46 FeO,aq 0.35290E-09 -9.4523 0.35290E-09 -9.4523 0.10000E+01 0.0000 47 FeOH+ 0.17899E-07 -7.7472 0.17206E-07 -7.7643 0.96129E+00 -0.0171 48 HFeO2- 0.67898E-10 -10.1681 0.65267E-10 -10.1853 0.96125E+00 -0.0172 49 FeO+ 0.50046E-12 -12.3006 0.48109E-12 -12.3178 0.96129E+00 -0.0171 50 FeOH+2 0.57794E-17 -17.2381 0.52063E-17 -17.2835 0.90084E+00 -0.0454 51 FeO2- 0.29082E-10 -10.5364 0.27955E-10 -10.5535 0.96125E+00 -0.0172 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.75759E-08 -8.1206 0.75753E-08 -8.1206 0.99992E+00 0.0000 54 KCl,aq 0.21080E-11 -11.6761 0.21080E-11 -11.6761 0.10000E+01 0.0000 55 KHSO4,aq 0.31617E-17 -17.5001 0.31617E-17 -17.5001 0.10000E+01 0.0000 56 KOH,aq 0.67291E-11 -11.1720 0.67291E-11 -11.1720 0.10000E+01 0.0000 57 KSO4- 0.32561E-09 -9.4873 0.31299E-09 -9.5045 0.96125E+00 -0.0172 58 MgCO3,aq 0.17125E-09 -9.7664 0.17125E-09 -9.7664 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.94077E-09 -9.0265 0.90435E-09 -9.0437 0.96129E+00 -0.0171 60 MgCl+ 0.62353E-09 -9.2051 0.59939E-09 -9.2223 0.96129E+00 -0.0171 61 MgOH+ 0.21831E-07 -7.6609 0.20986E-07 -7.6781 0.96129E+00 -0.0171 63 MnO,aq 0.20303E-10 -10.6924 0.20303E-10 -10.6924 0.10000E+01 0.0000 64 MnOH+ 0.35836E-08 -8.4457 0.34449E-08 -8.4628 0.96129E+00 -0.0171 65 MnO2-2 0.23042E-18 -18.6375 0.20760E-18 -18.6828 0.90096E+00 -0.0453 66 HMnO2- 0.27213E-14 -14.5652 0.26158E-14 -14.5824 0.96125E+00 -0.0172 69 MnCl+ 0.54316E-10 -10.2651 0.52213E-10 -10.2822 0.96129E+00 -0.0171 70 MnSO4,aq 0.41723E-09 -9.3796 0.41723E-09 -9.3796 0.10000E+01 0.0000 71 NaCl,aq 0.68924E-08 -8.1616 0.68924E-08 -8.1616 0.10000E+01 0.0000 72 NaOH,aq 0.12026E-08 -8.9199 0.12026E-08 -8.9199 0.10000E+01 0.0000 74 OH- 0.10730E-04 -4.9694 0.10314E-04 -4.9866 0.96122E+00 -0.0172 79 HPO3-2 0.31856E-18 -18.4968 0.28701E-18 -18.5421 0.90096E+00 -0.0453 81 H2PO3- 0.34110E-19 -19.4671 0.32788E-19 -19.4843 0.96125E+00 -0.0172 82 H3PO4,aq 0.26120E-12 -12.5830 0.26120E-12 -12.5830 0.10000E+01 0.0000 83 H2PO4- 0.12724E-07 -7.8954 0.12231E-07 -7.9125 0.96127E+00 -0.0172 84 PO4-3 0.22256E-12 -12.6526 0.18012E-12 -12.7444 0.80933E+00 -0.0919 87 H2P2O7-2 0.12995E-16 -16.8862 0.11708E-16 -16.9315 0.90096E+00 -0.0453 88 HP2O7-3 0.51053E-16 -16.2920 0.41279E-16 -16.3843 0.80857E+00 -0.0923 89 P2O7-4 0.25183E-18 -18.5989 0.17510E-18 -18.7567 0.69532E+00 -0.1578 90 H2S,aq 0.37659E-07 -7.4241 0.37656E-07 -7.4242 0.99992E+00 0.0000 91 S2-2 0.14965E-15 -15.8249 0.13483E-15 -15.8702 0.90096E+00 -0.0453 96 SO2,aq 0.24294E-17 -17.6145 0.24294E-17 -17.6145 0.10000E+01 0.0000 97 SO3-2 0.25937E-13 -13.5861 0.23375E-13 -13.6312 0.90122E+00 -0.0452 98 HSO3- 0.82764E-13 -13.0822 0.79557E-13 -13.0993 0.96125E+00 -0.0172 99 HSO4- 0.12704E-08 -8.8961 0.12212E-08 -8.9132 0.96130E+00 -0.0171 101 S2O3-2 0.11148E-13 -13.9528 0.10044E-13 -13.9981 0.90096E+00 -0.0453 102 HS2O3- 0.10845E-18 -18.9648 0.10425E-18 -18.9819 0.96125E+00 -0.0172 Charge balance for all species = 0.9762E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6049513E-07 -.1348887E-04 -.1359577E-01 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9999827E+06 0.0000 3 Cl- 0.1379630E-03 0.1379744E-03 0.4891533E+01 3.3580 4 SO4-- 0.2511759E-04 0.2524081E-04 0.2424635E+01 9.8255 5 HCO3- 0.1171901E-04 0.1307002E-04 0.7974840E+00 2.2871 6 HS- 0.2241839E-06 0.2637077E-06 0.8721209E-02 0.5688 7 Al+++ 0.1915134E-18 0.8326223E-06 0.2246506E-01 2.8961 8 H4SiO4 0.4502819E-04 0.4581632E-04 0.4403587E+01 -4.3465 9 Ca++ 0.1937352E-04 0.1953172E-04 0.7827804E+00 9.7127 10 Mg++ 0.3468434E-05 0.3492070E-05 0.8489790E-01 8.9655 11 Fe++ 0.3350804E-07 0.5206778E-07 0.2907785E-02 6.9506 12 K+ 0.9338498E-06 0.9341842E-06 0.3652791E-01 1.1885 13 Na+ 0.1655844E-03 0.1655944E-03 0.3806923E+01 3.4372 14 Mn++ 0.7221449E-07 0.7628995E-07 0.4191154E-02 7.2840 15 HPO4-- 0.1331335E-07 0.2603738E-07 0.2499004E-02 6.5498 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5981747E-04 -.1348885E-04 -.4632862E-04 0.0000000E+00 2 H2O 0.5550820E+02 0.5550816E+02 0.3011445E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2562641E-04 0.2524076E-04 0.3856463E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1219390E-06 0.2637073E-06 -.3856463E-06 0.0000000E+00 7 Al+++ 0.1434726E-04 0.8326209E-06 0.1351464E-04 0.0000000E+00 8 H4SiO4 0.4581625E-04 0.4581625E-04 0.0000000E+00 0.0000000E+00 9 Ca++ 0.1953169E-04 0.1953169E-04 0.0000000E+00 0.0000000E+00 10 Mg++ 0.3492063E-05 0.3492063E-05 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3137238E-05 0.5206769E-07 0.3085170E-05 0.0000000E+00 12 K+ 0.9341826E-06 0.9341826E-06 0.0000000E+00 0.0000000E+00 13 Na+ 0.1655941E-03 0.1655941E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.7628982E-07 0.7628982E-07 0.0000000E+00 0.0000000E+00 15 HPO4-- 0.2603734E-07 0.2603734E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2541E-20 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0044000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) diaspore 0.1351E-04 -4.869 0.8107E-03 -3.091 76.70 0.2414E-03 hematite 0.1543E-05 -5.812 0.2464E-03 -3.608 23.30 0.4669E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.001057 g Volume = 0.000288 cm3 Porosity: 99.9712% V(tot) - V(min): 0.10015E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0044000 g log = -2.3565 Original solution: 1000.0103000 g Original solution / Rock added: 227275.07 (Water/Rock Ratio), log = 5.3566 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9998E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1427E-03 1.0073 0.1512E-03 0.1501E-03 CH4,gas 0.1562E-09 1.0129 0.1665E-09 0.1643E-09 H2,gas 0.9870E-05 1.0006 0.1039E-04 0.1038E-04 H2S,gas 0.1048E-05 0.9959 0.1098E-05 0.1103E-05 S2,gas 0.3978E-21 1.0000 0.4185E-21 0.4185E-21 CO,gas 0.3868E-12 1.0000 0.4069E-12 0.4069E-12 SO3,gas 0.2720E-34 1.0000 0.2862E-34 0.2862E-34 SO2,gas 0.1069E-16 1.0000 0.1125E-16 0.1125E-16 HCl,gas 0.2435E-14 1.0000 0.2562E-14 0.2562E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.18 -5.82 -1.940 0.99382E+04 -3.820 3 CH4,gas 4.81 -6.97 -11.78 -2.945 0.20112E+05 -9.779 4 H2,gas 8.29 1.30 -6.98 -3.991 0.11924E+05 -4.983 5 H2S,gas -5.94 -13.90 -7.96 -3.980 0.13590E+05 -5.959 6 S2,gas -7.03 -30.41 -23.38 -3.597 0.39918E+05 -21.378 7 CO,gas 3.51 -10.88 -14.39 -4.428 0.24571E+05 -12.390 8 SO3,gas 17.43 -19.12 -36.54 -9.136 0.62397E+05 -34.543 9 SO2,gas 1.14 -17.81 -18.95 -5.053 0.32355E+05 -16.949 10 HCl,gas 5.48 -11.11 -16.59 -8.296 0.28330E+05 -14.591 21 andalusite 5.06 1.45 -3.62 -0.362 0.61754E+04 24 anhydrite -5.28 -9.40 -4.12 -2.062 0.70411E+04 32 apatite-OH -17.99 -18.61 -0.62 -0.048 0.10642E+04 35 aragonite 0.99 -2.47 -3.46 -1.152 0.59031E+04 36 brucite 12.58 8.97 -3.61 -0.722 0.61658E+04 37 calcite 0.83 -2.47 -3.30 -1.101 0.56418E+04 40 carpholite-Mg 8.65 6.06 -2.59 -0.172 0.44150E+04 41 carpholite-Fe 6.78 4.05 -2.73 -0.182 0.46668E+04 46 clinochlore 39.19 37.58 -1.61 -0.050 0.27537E+04 47 daphnite 29.09 27.51 -1.59 -0.050 0.27128E+04 50 chloritoid-Mg 13.26 10.41 -2.85 -0.190 0.48664E+04 51 chloritoid-Fe 9.24 8.40 -0.84 -0.056 0.14384E+04 52 chloritoid-Mn 11.46 8.73 -2.73 -0.182 0.46674E+04 54 coesite -2.37 -4.35 -1.98 -0.659 0.33760E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.35 -1.80 -0.599 0.30688E+04 78 fayalite 14.08 9.55 -4.52 -0.646 0.77252E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.16 -4.04 -0.336 0.68906E+04 92 hercynite 17.34 12.74 -4.60 -0.307 0.78574E+04 98 kaolinite -1.27 -2.90 -1.63 -0.148 0.27793E+04 99 kyanite 4.93 1.45 -3.49 -0.349 0.59522E+04 101 laumontite 2.97 -1.88 -4.86 -0.324 0.82911E+04 102 lawsonite 9.68 6.81 -2.87 -0.191 0.48946E+04 106 magnesite 0.71 -3.22 -3.93 -1.309 0.67059E+04 107 magnetite 20.13 19.55 -0.58 -0.048 0.99819E+03 110 magnesioferrite 26.26 21.56 -4.69 -0.383 0.80151E+04 113 margarite 17.45 12.60 -4.85 -0.194 0.82775E+04 128 periclase-Fe 11.64 6.95 -4.69 -1.172 0.80056E+04 142 pyrite -21.23 -22.16 -0.93 -0.219 0.15905E+04 143 pyrrhotite -4.24 -6.95 -2.71 -0.903 0.46235E+04 144 pyrrhotiteFe0.875 -6.00 -7.98 -1.98 -0.729 0.33822E+04 145 pyroxmangite 7.42 2.94 -4.48 -0.896 0.76469E+04 147 quartz -2.98 -4.35 -1.36 -0.455 0.23299E+04 152 rhodochrosite -0.96 -4.90 -3.94 -1.314 0.67293E+04 153 rhodonite 7.46 2.94 -4.52 -0.905 0.77261E+04 156 siderite -2.59 -5.23 -2.65 -0.882 0.45170E+04 157 sillimanite 5.32 1.45 -3.88 -0.388 0.66176E+04 169 sudoite 21.22 16.48 -4.74 -0.153 0.80939E+04 178 topaz-H 4.67 1.45 -3.22 -0.293 0.55013E+04 179 tridymite -2.61 -4.35 -1.73 -0.577 0.29572E+04 182 troilite-low -4.39 -6.95 -2.56 -0.852 0.43667E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.35 -1.55 -0.517 0.26502E+04 206 nontronite-Ca 3.28 -0.80 -4.08 -0.264 0.69587E+04 207 nontronite-H 2.60 -2.40 -4.99 -0.335 0.85273E+04 209 nontronite-Mg 3.14 -0.92 -4.06 -0.263 0.69295E+04 210 nontronite-Na 3.58 -1.26 -4.85 -0.311 0.82760E+04 215 gypsum -4.92 -9.40 -4.48 -1.120 0.76478E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.95 -2.87 -0.718 0.49067E+04 241 silica-amorphous -2.08 -4.35 -2.27 -0.756 0.38704E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0044000 g New total amount of reactant added: 0.0046000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.9762E-15 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0046000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2606871E-03 Osmotic coef. = 0.9903 True ionic strength = .2620738E-03 Chg. balance for total moles = 0.9762E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.56198E-07 -7.2503 0.54024E-07 -7.2674 0.96131E+00 -0.0171 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13261E-03 -3.8774 0.96120E+00 -0.0172 4 SO4-- 0.25103E-04 -4.6003 0.22613E-04 -4.6456 0.90079E+00 -0.0454 5 HCO3- 0.11802E-04 -4.9280 0.11344E-04 -4.9452 0.96122E+00 -0.0172 6 HS- 0.23762E-06 -6.6241 0.22840E-06 -6.6413 0.96120E+00 -0.0172 7 Al+++ 0.15359E-18 -18.8136 0.12412E-18 -18.9062 0.80814E+00 -0.0925 8 H4SiO4 0.47013E-04 -4.3278 0.47013E-04 -4.3278 0.10000E+01 0.0000 9 Ca++ 0.19600E-04 -4.7077 0.17653E-04 -4.7532 0.90067E+00 -0.0454 10 Mg++ 0.36243E-05 -5.4408 0.32640E-05 -5.4862 0.90059E+00 -0.0455 11 Fe++ 0.29404E-07 -7.5316 0.26481E-07 -7.5771 0.90061E+00 -0.0455 12 K+ 0.97630E-06 -6.0104 0.93844E-06 -6.0276 0.96123E+00 -0.0172 13 Na+ 0.16584E-03 -3.7803 0.15940E-03 -3.7975 0.96119E+00 -0.0172 14 Mn++ 0.75224E-07 -7.1236 0.67749E-07 -7.1691 0.90062E+00 -0.0455 15 HPO4-- 0.14421E-07 -7.8410 0.12990E-07 -7.8864 0.90079E+00 -0.0454 16 HSiO3- 0.88333E-06 -6.0539 0.84906E-06 -6.0711 0.96120E+00 -0.0172 17 Ca(HSiO3)+ 0.34936E-09 -9.4567 0.33581E-09 -9.4739 0.96123E+00 -0.0172 18 Mg(HSiO3)+ 0.80392E-10 -10.0948 0.77275E-10 -10.1120 0.96123E+00 -0.0172 19 NaHSiO3,aq 0.21495E-08 -8.6677 0.21495E-08 -8.6677 0.10000E+01 0.0000 20 AlO+ 0.57116E-11 -11.2432 0.54901E-11 -11.2604 0.96123E+00 -0.0172 21 AlOH+2 0.16497E-14 -14.7826 0.14858E-14 -14.8280 0.90064E+00 -0.0455 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.87449E-06 -6.0582 0.84053E-06 -6.0754 0.96116E+00 -0.0172 24 CH4,aq 0.11245E-12 -12.9491 0.11244E-12 -12.9491 0.99992E+00 0.0000 29 CO,aq 0.24921E-15 -15.6034 0.24921E-15 -15.6034 0.10000E+01 0.0000 30 CO2,aq 0.12358E-05 -5.9081 0.12357E-05 -5.9081 0.99992E+00 0.0000 31 CO3-2 0.21555E-07 -7.6665 0.19416E-07 -7.7118 0.90075E+00 -0.0454 32 CaCO3,aq 0.41977E-08 -8.3770 0.41977E-08 -8.3770 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.52495E-08 -8.2799 0.50460E-08 -8.2971 0.96123E+00 -0.0172 34 CaCl+ 0.38807E-08 -8.4111 0.37302E-08 -8.4283 0.96123E+00 -0.0172 35 CaCl2,aq 0.11518E-12 -12.9386 0.11518E-12 -12.9386 0.10000E+01 0.0000 36 CaOH+ 0.23970E-07 -7.6203 0.23041E-07 -7.6375 0.96123E+00 -0.0172 37 CaSO4,aq 0.12438E-06 -6.9053 0.12438E-06 -6.9053 0.10000E+01 0.0000 38 HCl,aq 0.13475E-11 -11.8705 0.13475E-11 -11.8705 0.10000E+01 0.0000 43 FeCl+ 0.56900E-11 -11.2449 0.54694E-11 -11.2621 0.96123E+00 -0.0172 44 FeCl2,aq 0.22495E-19 -19.6479 0.22495E-19 -19.6479 0.10000E+01 0.0000 46 FeO,aq 0.35880E-09 -9.4451 0.35880E-09 -9.4451 0.10000E+01 0.0000 47 FeOH+ 0.16906E-07 -7.7720 0.16251E-07 -7.7891 0.96123E+00 -0.0172 48 HFeO2- 0.74321E-10 -10.1289 0.71437E-10 -10.1461 0.96120E+00 -0.0172 49 FeO+ 0.46491E-12 -12.3326 0.44689E-12 -12.3498 0.96123E+00 -0.0172 50 FeOH+2 0.49881E-17 -17.3021 0.44925E-17 -17.3475 0.90064E+00 -0.0455 51 FeO2- 0.31309E-10 -10.5043 0.30095E-10 -10.5215 0.96120E+00 -0.0172 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.78314E-08 -8.1062 0.78307E-08 -8.1062 0.99992E+00 0.0000 54 KCl,aq 0.22035E-11 -11.6569 0.22035E-11 -11.6569 0.10000E+01 0.0000 55 KHSO4,aq 0.30678E-17 -17.5132 0.30678E-17 -17.5132 0.10000E+01 0.0000 56 KOH,aq 0.75728E-11 -11.1207 0.75728E-11 -11.1207 0.10000E+01 0.0000 57 KSO4- 0.34014E-09 -9.4683 0.32694E-09 -9.4855 0.96120E+00 -0.0172 58 MgCO3,aq 0.19395E-09 -9.7123 0.19395E-09 -9.7123 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.98979E-09 -9.0045 0.95142E-09 -9.0216 0.96123E+00 -0.0172 60 MgCl+ 0.65140E-09 -9.1862 0.62615E-09 -9.2033 0.96123E+00 -0.0172 61 MgOH+ 0.24554E-07 -7.6099 0.23602E-07 -7.6270 0.96123E+00 -0.0172 63 MnO,aq 0.24505E-10 -10.6108 0.24505E-10 -10.6108 0.10000E+01 0.0000 64 MnOH+ 0.40180E-08 -8.3960 0.38622E-08 -8.4132 0.96123E+00 -0.0172 65 MnO2-2 0.32236E-18 -18.4917 0.29037E-18 -18.5370 0.90075E+00 -0.0454 66 HMnO2- 0.35359E-14 -14.4515 0.33987E-14 -14.4687 0.96120E+00 -0.0172 69 MnCl+ 0.56567E-10 -10.2474 0.54374E-10 -10.2646 0.96123E+00 -0.0172 70 MnSO4,aq 0.43417E-09 -9.3623 0.43417E-09 -9.3623 0.10000E+01 0.0000 71 NaCl,aq 0.69021E-08 -8.1610 0.69021E-08 -8.1610 0.10000E+01 0.0000 72 NaOH,aq 0.12965E-08 -8.8872 0.12965E-08 -8.8872 0.10000E+01 0.0000 74 OH- 0.11552E-04 -4.9373 0.11103E-04 -4.9546 0.96116E+00 -0.0172 79 HPO3-2 0.35669E-18 -18.4477 0.32129E-18 -18.4931 0.90075E+00 -0.0454 81 H2PO3- 0.35472E-19 -19.4501 0.34095E-19 -19.4673 0.96120E+00 -0.0172 82 H3PO4,aq 0.24407E-12 -12.6125 0.24407E-12 -12.6125 0.10000E+01 0.0000 83 H2PO4- 0.12800E-07 -7.8928 0.12303E-07 -7.9100 0.96121E+00 -0.0172 84 PO4-3 0.25959E-12 -12.5857 0.20999E-12 -12.6778 0.80891E+00 -0.0921 87 H2P2O7-2 0.13153E-16 -16.8810 0.11847E-16 -16.9264 0.90075E+00 -0.0454 88 HP2O7-3 0.55643E-16 -16.2546 0.44967E-16 -16.3471 0.80815E+00 -0.0925 89 P2O7-4 0.29559E-18 -18.5293 0.20534E-18 -18.6875 0.69468E+00 -0.1582 90 H2S,aq 0.37076E-07 -7.4309 0.37073E-07 -7.4309 0.99992E+00 0.0000 91 S2-2 0.16266E-15 -15.7887 0.14652E-15 -15.8341 0.90075E+00 -0.0454 96 SO2,aq 0.21653E-17 -17.6645 0.21653E-17 -17.6645 0.10000E+01 0.0000 97 SO3-2 0.26797E-13 -13.5719 0.24144E-13 -13.6172 0.90101E+00 -0.0453 98 HSO3- 0.79415E-13 -13.1001 0.76333E-13 -13.1173 0.96120E+00 -0.0172 99 HSO4- 0.11792E-08 -8.9284 0.11335E-08 -8.9456 0.96125E+00 -0.0172 101 S2O3-2 0.10969E-13 -13.9598 0.98803E-14 -14.0052 0.90075E+00 -0.0454 102 HS2O3- 0.99109E-19 -19.0039 0.95263E-19 -19.0211 0.96120E+00 -0.0172 Charge balance for all species = 0.9763E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5619800E-07 -.1475385E-04 -.1487077E-01 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9999825E+06 0.0000 3 Cl- 0.1379629E-03 0.1379744E-03 0.4891532E+01 3.3900 4 SO4-- 0.2510349E-04 0.2522789E-04 0.2423394E+01 9.8892 5 HCO3- 0.1180208E-04 0.1307002E-04 0.7974839E+00 2.3222 6 HS- 0.2376208E-06 0.2766258E-06 0.9148426E-02 0.6261 7 Al+++ 0.1535859E-18 0.8948330E-06 0.2414356E-01 2.8961 8 H4SiO4 0.4701298E-04 0.4789889E-04 0.4603750E+01 -4.3278 9 Ca++ 0.1959973E-04 0.1976175E-04 0.7919993E+00 9.7816 10 Mg++ 0.3624331E-05 0.3650800E-05 0.8875688E-01 9.0486 11 Fe++ 0.2940379E-07 0.4698390E-07 0.2623869E-02 6.9578 12 K+ 0.9762973E-06 0.9766472E-06 0.3818827E-01 1.2398 13 Na+ 0.1658351E-03 0.1658454E-03 0.3812694E+01 3.4699 14 Mn++ 0.7522449E-07 0.7975769E-07 0.4381660E-02 7.3657 15 HPO4-- 0.1442057E-07 0.2722090E-07 0.2612595E-02 6.6484 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6312917E-04 -.1475383E-04 -.4837534E-04 0.0000000E+00 2 H2O 0.5550819E+02 0.5550816E+02 0.3144202E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2563195E-04 0.2522784E-04 0.4041070E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1274817E-06 0.2766253E-06 -.4041070E-06 0.0000000E+00 7 Al+++ 0.1499941E-04 0.8948314E-06 0.1410458E-04 0.0000000E+00 8 H4SiO4 0.4789880E-04 0.4789880E-04 0.0000000E+00 0.0000000E+00 9 Ca++ 0.1976172E-04 0.1976172E-04 0.0000000E+00 0.0000000E+00 10 Mg++ 0.3650794E-05 0.3650794E-05 0.0000000E+00 0.0000000E+00 11 Fe++ 0.3279840E-05 0.4698382E-07 0.3232856E-05 0.0000000E+00 12 K+ 0.9766454E-06 0.9766454E-06 0.0000000E+00 0.0000000E+00 13 Na+ 0.1658451E-03 0.1658451E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.7975754E-07 0.7975754E-07 0.0000000E+00 0.0000000E+00 15 HPO4-- 0.2722085E-07 0.2722085E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.3388E-20 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0046000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) diaspore 0.1410E-04 -4.851 0.8461E-03 -3.073 76.62 0.2519E-03 hematite 0.1616E-05 -5.791 0.2581E-03 -3.588 23.38 0.4893E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.001104 g Volume = 0.000301 cm3 Porosity: 99.9700% V(tot) - V(min): 0.10015E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0046000 g log = -2.3372 Original solution: 1000.0103000 g Original solution / Rock added: 217393.54 (Water/Rock Ratio), log = 5.3372 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1335E-03 1.0073 0.1414E-03 0.1404E-03 CH4,gas 0.1668E-09 1.0129 0.1778E-09 0.1755E-09 H2,gas 0.1020E-04 1.0006 0.1074E-04 0.1073E-04 H2S,gas 0.1032E-05 0.9959 0.1081E-05 0.1086E-05 S2,gas 0.3608E-21 1.0000 0.3796E-21 0.3796E-21 CO,gas 0.3740E-12 1.0000 0.3935E-12 0.3935E-12 SO3,gas 0.2345E-34 1.0000 0.2467E-34 0.2467E-34 SO2,gas 0.9529E-17 1.0000 0.1002E-16 0.1002E-16 HCl,gas 0.2262E-14 1.0000 0.2379E-14 0.2379E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 0.00000E+00 46 clinochlore 39.19 38.05 -1.14 -0.036 0.19487E+04 47 daphnite 29.09 27.60 -1.50 -0.047 0.25553E+04 48 chlorite-Mn 46.99 29.64 -17.35 -0.542 0.29621E+05 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.21 -5.85 -1.950 0.99877E+04 -3.849 3 CH4,gas 4.81 -6.94 -11.75 -2.938 0.20063E+05 -9.750 4 H2,gas 8.29 1.32 -6.97 -3.982 0.11899E+05 -4.969 5 H2S,gas -5.94 -13.91 -7.97 -3.983 0.13602E+05 -5.966 6 S2,gas -7.03 -30.45 -23.42 -3.603 0.39990E+05 -21.421 7 CO,gas 3.51 -10.89 -14.41 -4.432 0.24596E+05 -12.405 8 SO3,gas 17.43 -19.18 -36.61 -9.152 0.62507E+05 -34.608 9 SO2,gas 1.14 -17.86 -19.00 -5.066 0.32440E+05 -16.999 10 HCl,gas 5.48 -11.14 -16.62 -8.312 0.28384E+05 -14.624 21 andalusite 5.06 1.46 -3.60 -0.360 0.61434E+04 24 anhydrite -5.28 -9.40 -4.12 -2.060 0.70332E+04 32 apatite-OH -17.99 -18.36 -0.37 -0.028 0.62608E+03 35 aragonite 0.99 -2.43 -3.42 -1.139 0.58348E+04 36 brucite 12.58 9.05 -3.53 -0.706 0.60240E+04 37 calcite 0.83 -2.43 -3.26 -1.088 0.55735E+04 40 carpholite-Mg 8.65 6.19 -2.47 -0.164 0.42092E+04 41 carpholite-Fe 6.78 4.09 -2.69 -0.179 0.45905E+04 50 chloritoid-Mg 13.26 10.51 -2.75 -0.183 0.46926E+04 51 chloritoid-Fe 9.24 8.42 -0.82 -0.054 0.13942E+04 52 chloritoid-Mn 11.46 8.83 -2.63 -0.176 0.44959E+04 54 coesite -2.37 -4.33 -1.96 -0.653 0.33440E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.33 -1.78 -0.593 0.30369E+04 78 fayalite 14.08 9.59 -4.49 -0.642 0.76686E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.22 -3.98 -0.331 0.67897E+04 92 hercynite 17.34 12.75 -4.59 -0.306 0.78451E+04 98 kaolinite -1.27 -2.86 -1.59 -0.145 0.27153E+04 99 kyanite 4.93 1.46 -3.47 -0.347 0.59202E+04 101 laumontite 2.97 -1.74 -4.71 -0.314 0.80454E+04 102 lawsonite 9.68 6.92 -2.76 -0.184 0.47128E+04 105 lizardite 23.29 18.49 -4.80 -0.400 0.81911E+04 106 magnesite 0.71 -3.16 -3.87 -1.291 0.66136E+04 107 magnetite 20.13 19.56 -0.58 -0.047 0.98589E+03 110 magnesioferrite 26.26 21.65 -4.61 -0.376 0.78733E+04 113 margarite 17.45 12.71 -4.74 -0.190 0.80957E+04 128 periclase-Fe 11.64 6.96 -4.68 -1.170 0.79933E+04 142 pyrite -21.23 -22.18 -0.95 -0.224 0.16260E+04 143 pyrrhotite -4.24 -6.95 -2.71 -0.902 0.46228E+04 144 pyrrhotiteFe0.875 -6.00 -7.98 -1.98 -0.729 0.33861E+04 145 pyroxmangite 7.42 3.04 -4.38 -0.876 0.74755E+04 147 quartz -2.98 -4.33 -1.35 -0.449 0.22979E+04 152 rhodochrosite -0.96 -4.85 -3.89 -1.296 0.66393E+04 153 rhodonite 7.46 3.04 -4.42 -0.885 0.75547E+04 156 siderite -2.59 -5.25 -2.67 -0.889 0.45542E+04 157 sillimanite 5.32 1.46 -3.86 -0.386 0.65856E+04 169 sudoite 21.22 16.70 -4.52 -0.146 0.77144E+04 178 topaz-H 4.67 1.46 -3.20 -0.291 0.54693E+04 179 tridymite -2.61 -4.33 -1.71 -0.571 0.29252E+04 182 troilite-low -4.39 -6.95 -2.56 -0.852 0.43660E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.33 -1.53 -0.511 0.26182E+04 206 nontronite-Ca 3.28 -0.72 -4.00 -0.259 0.68219E+04 207 nontronite-H 2.60 -2.33 -4.93 -0.330 0.84099E+04 209 nontronite-Mg 3.14 -0.84 -3.98 -0.258 0.67887E+04 210 nontronite-Na 3.58 -1.18 -4.77 -0.306 0.81402E+04 215 gypsum -4.92 -9.40 -4.47 -1.119 0.76400E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.96 -2.87 -0.717 0.48944E+04 241 silica-amorphous -2.08 -4.33 -2.25 -0.749 0.38384E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0046000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2600865E-03 Osmotic coef. = 0.9903 True ionic strength = .2613567E-03 Chg. balance for total moles = 0.9762E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.58314E-07 -7.2342 0.56059E-07 -7.2514 0.96134E+00 -0.0171 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13261E-03 -3.8774 0.96122E+00 -0.0172 4 SO4-- 0.25134E-04 -4.5997 0.22643E-04 -4.6451 0.90090E+00 -0.0453 5 HCO3- 0.11761E-04 -4.9296 0.11305E-04 -4.9467 0.96125E+00 -0.0172 6 HS- 0.21002E-06 -6.6777 0.20188E-06 -6.6949 0.96123E+00 -0.0172 7 Al+++ 0.17156E-18 -18.7656 0.13868E-18 -18.8580 0.80835E+00 -0.0924 8 H4SiO4 0.46751E-04 -4.3302 0.46751E-04 -4.3302 0.10000E+01 0.0000 9 Ca++ 0.19601E-04 -4.7077 0.17656E-04 -4.7531 0.90077E+00 -0.0454 10 Mg++ 0.33734E-05 -5.4719 0.30384E-05 -5.5174 0.90069E+00 -0.0454 11 Fe++ 0.31024E-07 -7.5083 0.27944E-07 -7.5537 0.90071E+00 -0.0454 12 K+ 0.97630E-06 -6.0104 0.93847E-06 -6.0276 0.96126E+00 -0.0172 13 Na+ 0.16584E-03 -3.7803 0.15940E-03 -3.7975 0.96122E+00 -0.0172 14 Mn++ 0.75215E-07 -7.1237 0.67748E-07 -7.1691 0.90072E+00 -0.0454 15 HPO4-- 0.14169E-07 -7.8487 0.12765E-07 -7.8940 0.90090E+00 -0.0453 16 HSiO3- 0.84649E-06 -6.0724 0.81367E-06 -6.0896 0.96122E+00 -0.0172 17 Ca(HSiO3)+ 0.33484E-09 -9.4752 0.32187E-09 -9.4923 0.96126E+00 -0.0172 18 Mg(HSiO3)+ 0.71714E-10 -10.1444 0.68936E-10 -10.1616 0.96126E+00 -0.0172 19 NaHSiO3,aq 0.20600E-08 -8.6861 0.20600E-08 -8.6861 0.10000E+01 0.0000 20 AlO+ 0.59266E-11 -11.2272 0.56970E-11 -11.2444 0.96126E+00 -0.0172 21 AlOH+2 0.17761E-14 -14.7505 0.15998E-14 -14.7959 0.90074E+00 -0.0454 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.84271E-06 -6.0743 0.81001E-06 -6.0915 0.96119E+00 -0.0172 24 CH4,aq 0.98914E-13 -13.0047 0.98906E-13 -13.0048 0.99992E+00 0.0000 29 CO,aq 0.24750E-15 -15.6064 0.24750E-15 -15.6064 0.10000E+01 0.0000 30 CO2,aq 0.12779E-05 -5.8935 0.12778E-05 -5.8935 0.99992E+00 0.0000 31 CO3-2 0.20698E-07 -7.6841 0.18646E-07 -7.7294 0.90086E+00 -0.0453 32 CaCO3,aq 0.40320E-08 -8.3945 0.40320E-08 -8.3945 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.52321E-08 -8.2813 0.50294E-08 -8.2985 0.96126E+00 -0.0172 34 CaCl+ 0.38813E-08 -8.4110 0.37310E-08 -8.4282 0.96126E+00 -0.0172 35 CaCl2,aq 0.11520E-12 -12.9385 0.11520E-12 -12.9385 0.10000E+01 0.0000 36 CaOH+ 0.23103E-07 -7.6363 0.22208E-07 -7.6535 0.96126E+00 -0.0172 37 CaSO4,aq 0.12456E-06 -6.9046 0.12456E-06 -6.9046 0.10000E+01 0.0000 38 HCl,aq 0.13983E-11 -11.8544 0.13983E-11 -11.8544 0.10000E+01 0.0000 43 FeCl+ 0.60043E-11 -11.2215 0.57717E-11 -11.2387 0.96126E+00 -0.0172 44 FeCl2,aq 0.23739E-19 -19.6245 0.23739E-19 -19.6245 0.10000E+01 0.0000 46 FeO,aq 0.35162E-09 -9.4539 0.35162E-09 -9.4539 0.10000E+01 0.0000 47 FeOH+ 0.17191E-07 -7.7647 0.16525E-07 -7.7818 0.96126E+00 -0.0172 48 HFeO2- 0.70187E-10 -10.1537 0.67465E-10 -10.1709 0.96122E+00 -0.0172 49 FeO+ 0.48242E-12 -12.3166 0.46373E-12 -12.3337 0.96126E+00 -0.0172 50 FeOH+2 0.53704E-17 -17.2700 0.48374E-17 -17.3154 0.90074E+00 -0.0454 51 FeO2- 0.30172E-10 -10.5204 0.29002E-10 -10.5376 0.96122E+00 -0.0172 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.75210E-08 -8.1237 0.75204E-08 -8.1238 0.99992E+00 0.0000 54 KCl,aq 0.22036E-11 -11.6569 0.22036E-11 -11.6569 0.10000E+01 0.0000 55 KHSO4,aq 0.31877E-17 -17.4965 0.31877E-17 -17.4965 0.10000E+01 0.0000 56 KOH,aq 0.72981E-11 -11.1368 0.72981E-11 -11.1368 0.10000E+01 0.0000 57 KSO4- 0.34059E-09 -9.4678 0.32738E-09 -9.4849 0.96122E+00 -0.0172 58 MgCO3,aq 0.17339E-09 -9.7610 0.17339E-09 -9.7610 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.91817E-09 -9.0371 0.88260E-09 -9.0542 0.96126E+00 -0.0172 60 MgCl+ 0.60638E-09 -9.2173 0.58289E-09 -9.2344 0.96126E+00 -0.0172 61 MgOH+ 0.22026E-07 -7.6571 0.21173E-07 -7.6742 0.96126E+00 -0.0172 63 MnO,aq 0.22757E-10 -10.6429 0.22757E-10 -10.6429 0.10000E+01 0.0000 64 MnOH+ 0.38719E-08 -8.4121 0.37219E-08 -8.4292 0.96126E+00 -0.0172 65 MnO2-2 0.27800E-18 -18.5560 0.25044E-18 -18.6013 0.90086E+00 -0.0453 66 HMnO2- 0.31645E-14 -14.4997 0.30418E-14 -14.5169 0.96122E+00 -0.0172 69 MnCl+ 0.56567E-10 -10.2474 0.54375E-10 -10.2646 0.96126E+00 -0.0172 70 MnSO4,aq 0.43475E-09 -9.3618 0.43475E-09 -9.3618 0.10000E+01 0.0000 71 NaCl,aq 0.69025E-08 -8.1610 0.69025E-08 -8.1610 0.10000E+01 0.0000 72 NaOH,aq 0.12495E-08 -8.9033 0.12495E-08 -8.9033 0.10000E+01 0.0000 74 OH- 0.11132E-04 -4.9534 0.10700E-04 -4.9706 0.96119E+00 -0.0172 79 HPO3-2 0.33658E-18 -18.4729 0.30321E-18 -18.5183 0.90086E+00 -0.0453 81 H2PO3- 0.34736E-19 -19.4592 0.33389E-19 -19.4764 0.96122E+00 -0.0172 82 H3PO4,aq 0.25826E-12 -12.5879 0.25826E-12 -12.5879 0.10000E+01 0.0000 83 H2PO4- 0.13051E-07 -7.8843 0.12546E-07 -7.9015 0.96124E+00 -0.0172 84 PO4-3 0.24577E-12 -12.6095 0.19885E-12 -12.7015 0.80912E+00 -0.0920 87 H2P2O7-2 0.13674E-16 -16.8641 0.12318E-16 -16.9095 0.90086E+00 -0.0453 88 HP2O7-3 0.55740E-16 -16.2538 0.45058E-16 -16.3462 0.80836E+00 -0.0924 89 P2O7-4 0.28530E-18 -18.5447 0.19829E-18 -18.7027 0.69500E+00 -0.1580 90 H2S,aq 0.34006E-07 -7.4684 0.34003E-07 -7.4685 0.99992E+00 0.0000 91 S2-2 0.13231E-15 -15.8784 0.11919E-15 -15.9238 0.90086E+00 -0.0453 96 SO2,aq 0.22421E-17 -17.6493 0.22421E-17 -17.6493 0.10000E+01 0.0000 97 SO3-2 0.25766E-13 -13.5889 0.23218E-13 -13.6342 0.90111E+00 -0.0452 98 HSO3- 0.79244E-13 -13.1010 0.76172E-13 -13.1182 0.96122E+00 -0.0172 99 HSO4- 0.12252E-08 -8.9118 0.11778E-08 -8.9289 0.96128E+00 -0.0172 101 S2O3-2 0.10073E-13 -13.9969 0.90741E-14 -14.0422 0.90086E+00 -0.0453 102 HS2O3- 0.94448E-19 -19.0248 0.90786E-19 -19.0420 0.96122E+00 -0.0172 Charge balance for all species = 0.9746E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5831374E-07 -.1412408E-04 -.1423601E-01 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9999826E+06 0.0000 3 Cl- 0.1379630E-03 0.1379744E-03 0.4891532E+01 3.3739 4 SO4-- 0.2513393E-04 0.2525864E-04 0.2426348E+01 9.8576 5 HCO3- 0.1176107E-04 0.1307002E-04 0.7974839E+00 2.3046 6 HS- 0.2100227E-06 0.2458797E-06 0.8131608E-02 0.5564 7 Al+++ 0.1715637E-18 0.8630561E-06 0.2328619E-01 2.8961 8 H4SiO4 0.4675124E-04 0.4760020E-04 0.4575042E+01 -4.3302 9 Ca++ 0.1960061E-04 0.1976175E-04 0.7919993E+00 9.7496 10 Mg++ 0.3373421E-05 0.3397217E-05 0.8259186E-01 8.9854 11 Fe++ 0.3102397E-07 0.4887732E-07 0.2729609E-02 6.9490 12 K+ 0.9762971E-06 0.9766472E-06 0.3818827E-01 1.2238 13 Na+ 0.1658352E-03 0.1658454E-03 0.3812694E+01 3.4539 14 Mn++ 0.7521540E-07 0.7960141E-07 0.4373075E-02 7.3336 15 HPO4-- 0.1416894E-07 0.2722090E-07 0.2612595E-02 6.6087 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6312917E-04 -.1412406E-04 -.4900511E-04 0.0000000E+00 2 H2O 0.5550819E+02 0.5550816E+02 0.3145873E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2563195E-04 0.2525859E-04 0.3733609E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1274817E-06 0.2458792E-06 -.3733609E-06 0.0000000E+00 7 Al+++ 0.1499941E-04 0.8630546E-06 0.1413636E-04 0.0000000E+00 8 H4SiO4 0.4789880E-04 0.4760011E-04 0.2986885E-06 0.0000000E+00 9 Ca++ 0.1976172E-04 0.1976172E-04 0.0000000E+00 0.0000000E+00 10 Mg++ 0.3650794E-05 0.3397211E-05 0.2535829E-06 0.0000000E+00 11 Fe++ 0.3279840E-05 0.4887723E-07 0.3230962E-05 0.0000000E+00 12 K+ 0.9766454E-06 0.9766454E-06 0.0000000E+00 0.0000000E+00 13 Na+ 0.1658451E-03 0.1658451E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.7975754E-07 0.7960126E-07 0.1562796E-09 0.0000000E+00 15 HPO4-- 0.2722085E-07 0.2722085E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2172E-20 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0046000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) diaspore 0.1394E-04 -4.856 0.8361E-03 -3.078 73.49 0.2489E-03 hematite 0.1493E-05 -5.826 0.2385E-03 -3.623 20.96 0.4521E-04 clinochlore 0.5072E-07 -7.295 0.2819E-04 -4.550 2.478 0.1072E-04 daphnite 0.4881E-07 -7.311 0.3483E-04 -4.458 3.062 0.1055E-04 chlorite-Mn 0.3126E-10 -10.505 0.2216E-07 -7.654 0.1948E-02 0.7062E-08 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5094E+00 0.5094E+00 1.0000 -0.293 daphnite 0.4903E+00 0.4903E+00 1.0000 -0.310 chlorite-Mn 0.3139E-03 0.3139E-03 1.0000 -3.503 Solid products produced: Mass = 0.001138 g Volume = 0.000315 cm3 Porosity: 99.9685% V(tot) - V(min): 0.10015E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0046000 g log = -2.3372 Original solution: 1000.0103000 g Original solution / Rock added: 217393.54 (Water/Rock Ratio), log = 5.3372 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1380E-03 1.0073 0.1463E-03 0.1452E-03 CH4,gas 0.1468E-09 1.0129 0.1564E-09 0.1544E-09 H2,gas 0.9799E-05 1.0006 0.1031E-04 0.1031E-04 H2S,gas 0.9465E-06 0.9959 0.9917E-06 0.9958E-06 S2,gas 0.3291E-21 1.0000 0.3462E-21 0.3462E-21 CO,gas 0.3715E-12 1.0000 0.3908E-12 0.3908E-12 SO3,gas 0.2529E-34 1.0000 0.2660E-34 0.2660E-34 SO2,gas 0.9867E-17 1.0000 0.1038E-16 0.1038E-16 HCl,gas 0.2347E-14 1.0000 0.2469E-14 0.2469E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.20 -5.83 -1.945 0.99629E+04 -3.835 3 CH4,gas 4.81 -7.00 -11.81 -2.951 0.20158E+05 -9.806 4 H2,gas 8.29 1.30 -6.99 -3.992 0.11929E+05 -4.987 5 H2S,gas -5.94 -13.95 -8.00 -4.002 0.13666E+05 -6.004 6 S2,gas -7.03 -30.49 -23.46 -3.609 0.40058E+05 -21.461 7 CO,gas 3.51 -10.90 -14.41 -4.433 0.24601E+05 -12.408 8 SO3,gas 17.43 -19.15 -36.58 -9.144 0.62451E+05 -34.575 9 SO2,gas 1.14 -17.85 -18.98 -5.062 0.32414E+05 -16.984 10 HCl,gas 5.48 -11.13 -16.61 -8.304 0.28357E+05 -14.607 21 andalusite 5.06 1.46 -3.60 -0.360 0.61476E+04 24 anhydrite -5.28 -9.40 -4.12 -2.059 0.70321E+04 32 apatite-OH -17.99 -18.44 -0.45 -0.035 0.77410E+03 35 aragonite 0.99 -2.45 -3.43 -1.145 0.58647E+04 36 brucite 12.58 8.99 -3.59 -0.718 0.61320E+04 37 calcite 0.83 -2.45 -3.28 -1.094 0.56033E+04 40 carpholite-Mg 8.65 6.12 -2.53 -0.169 0.43255E+04 41 carpholite-Fe 6.78 4.08 -2.70 -0.180 0.46138E+04 50 chloritoid-Mg 13.26 10.45 -2.81 -0.188 0.48047E+04 51 chloritoid-Fe 9.24 8.41 -0.83 -0.055 0.14133E+04 52 chloritoid-Mn 11.46 8.80 -2.67 -0.178 0.45549E+04 54 coesite -2.37 -4.33 -1.96 -0.654 0.33481E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.33 -1.78 -0.594 0.30410E+04 78 fayalite 14.08 9.57 -4.51 -0.644 0.77027E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.19 -4.01 -0.334 0.68429E+04 92 hercynite 17.34 12.74 -4.60 -0.307 0.78601E+04 98 kaolinite -1.27 -2.87 -1.60 -0.145 0.27236E+04 99 kyanite 4.93 1.46 -3.47 -0.347 0.59244E+04 101 laumontite 2.97 -1.78 -4.75 -0.317 0.81166E+04 102 lawsonite 9.68 6.88 -2.80 -0.186 0.47758E+04 105 lizardite 23.29 18.30 -4.99 -0.416 0.85233E+04 106 magnesite 0.71 -3.21 -3.92 -1.307 0.66967E+04 107 magnetite 20.13 19.55 -0.59 -0.048 0.10009E+04 110 magnesioferrite 26.26 21.58 -4.67 -0.382 0.79812E+04 113 margarite 17.45 12.67 -4.78 -0.191 0.81588E+04 128 periclase-Fe 11.64 6.95 -4.69 -1.173 0.80083E+04 142 pyrite -21.23 -22.24 -1.02 -0.240 0.17392E+04 143 pyrrhotite -4.24 -7.00 -2.75 -0.918 0.47019E+04 144 pyrrhotiteFe0.875 -6.00 -8.03 -2.03 -0.745 0.34596E+04 145 pyroxmangite 7.42 3.00 -4.41 -0.883 0.75345E+04 147 quartz -2.98 -4.33 -1.35 -0.449 0.23020E+04 152 rhodochrosite -0.96 -4.86 -3.91 -1.302 0.66693E+04 153 rhodonite 7.46 3.00 -4.46 -0.892 0.76137E+04 156 siderite -2.59 -5.25 -2.66 -0.887 0.45443E+04 157 sillimanite 5.32 1.46 -3.86 -0.386 0.65898E+04 169 sudoite 21.22 16.56 -4.65 -0.150 0.79427E+04 178 topaz-H 4.67 1.46 -3.21 -0.291 0.54735E+04 179 tridymite -2.61 -4.33 -1.72 -0.572 0.29293E+04 182 troilite-low -4.39 -7.00 -2.60 -0.868 0.44451E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.33 -1.54 -0.512 0.26223E+04 206 nontronite-Ca 3.28 -0.73 -4.01 -0.260 0.68461E+04 207 nontronite-H 2.60 -2.34 -4.93 -0.331 0.84251E+04 209 nontronite-Mg 3.14 -0.86 -4.00 -0.259 0.68217E+04 210 nontronite-Na 3.58 -1.20 -4.78 -0.307 0.81644E+04 215 gypsum -4.92 -9.40 -4.47 -1.118 0.76389E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.95 -2.88 -0.719 0.49094E+04 241 silica-amorphous -2.08 -4.33 -2.25 -0.750 0.38425E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0046000 g New total amount of reactant added: 0.0048000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.9762E-15 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0048000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2604034E-03 Osmotic coef. = 0.9903 True ionic strength = .2617458E-03 Chg. balance for total moles = 0.9762E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.57211E-07 -7.2425 0.54998E-07 -7.2597 0.96132E+00 -0.0171 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13261E-03 -3.8774 0.96121E+00 -0.0172 4 SO4-- 0.25165E-04 -4.5992 0.22669E-04 -4.6446 0.90084E+00 -0.0454 5 HCO3- 0.11782E-04 -4.9288 0.11326E-04 -4.9459 0.96124E+00 -0.0172 6 HS- 0.18274E-06 -6.7382 0.17565E-06 -6.7553 0.96121E+00 -0.0172 7 Al+++ 0.16203E-18 -18.7904 0.13095E-18 -18.8829 0.80824E+00 -0.0925 8 H4SiO4 0.48352E-04 -4.3156 0.48352E-04 -4.3156 0.10000E+01 0.0000 9 Ca++ 0.19828E-04 -4.7027 0.17859E-04 -4.7481 0.90071E+00 -0.0454 10 Mg++ 0.31665E-05 -5.4994 0.28518E-05 -5.5449 0.90063E+00 -0.0455 11 Fe++ 0.29413E-07 -7.5315 0.26491E-07 -7.5769 0.90065E+00 -0.0454 12 K+ 0.10187E-05 -5.9919 0.97926E-06 -6.0091 0.96124E+00 -0.0172 13 Na+ 0.16609E-03 -3.7797 0.15964E-03 -3.7969 0.96121E+00 -0.0172 14 Mn++ 0.78165E-07 -7.1070 0.70401E-07 -7.1524 0.90067E+00 -0.0454 15 HPO4-- 0.14921E-07 -7.8262 0.13441E-07 -7.8716 0.90084E+00 -0.0454 16 HSiO3- 0.89239E-06 -6.0494 0.85777E-06 -6.0666 0.96121E+00 -0.0172 17 Ca(HSiO3)+ 0.35707E-09 -9.4472 0.34323E-09 -9.4644 0.96124E+00 -0.0172 18 Mg(HSiO3)+ 0.70959E-10 -10.1490 0.68209E-10 -10.1662 0.96124E+00 -0.0172 19 NaHSiO3,aq 0.21749E-08 -8.6626 0.21749E-08 -8.6626 0.10000E+01 0.0000 20 AlO+ 0.58145E-11 -11.2355 0.55891E-11 -11.2527 0.96124E+00 -0.0172 21 AlOH+2 0.17096E-14 -14.7671 0.15398E-14 -14.8125 0.90068E+00 -0.0454 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.85899E-06 -6.0660 0.82564E-06 -6.0832 0.96117E+00 -0.0172 24 CH4,aq 0.86119E-13 -13.0649 0.86112E-13 -13.0649 0.99992E+00 0.0000 29 CO,aq 0.23599E-15 -15.6271 0.23599E-15 -15.6271 0.10000E+01 0.0000 30 CO2,aq 0.12560E-05 -5.9010 0.12559E-05 -5.9011 0.99992E+00 0.0000 31 CO3-2 0.21137E-07 -7.6750 0.19040E-07 -7.7203 0.90080E+00 -0.0454 32 CaCO3,aq 0.41648E-08 -8.3804 0.41648E-08 -8.3804 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53021E-08 -8.2756 0.50966E-08 -8.2927 0.96124E+00 -0.0172 34 CaCl+ 0.39261E-08 -8.4060 0.37740E-08 -8.4232 0.96124E+00 -0.0172 35 CaCl2,aq 0.11653E-12 -12.9336 0.11653E-12 -12.9336 0.10000E+01 0.0000 36 CaOH+ 0.23821E-07 -7.6230 0.22898E-07 -7.6402 0.96124E+00 -0.0172 37 CaSO4,aq 0.12614E-06 -6.8991 0.12614E-06 -6.8991 0.10000E+01 0.0000 38 HCl,aq 0.13719E-11 -11.8627 0.13719E-11 -11.8627 0.10000E+01 0.0000 43 FeCl+ 0.56922E-11 -11.2447 0.54716E-11 -11.2619 0.96124E+00 -0.0172 44 FeCl2,aq 0.22504E-19 -19.6477 0.22504E-19 -19.6477 0.10000E+01 0.0000 46 FeO,aq 0.34633E-09 -9.4605 0.34633E-09 -9.4605 0.10000E+01 0.0000 47 FeOH+ 0.16613E-07 -7.7796 0.15969E-07 -7.7967 0.96124E+00 -0.0172 48 HFeO2- 0.70466E-10 -10.1520 0.67733E-10 -10.1692 0.96121E+00 -0.0172 49 FeO+ 0.47329E-12 -12.3249 0.45495E-12 -12.3420 0.96124E+00 -0.0172 50 FeOH+2 0.51693E-17 -17.2866 0.46559E-17 -17.3320 0.90068E+00 -0.0454 51 FeO2- 0.30754E-10 -10.5121 0.29561E-10 -10.5293 0.96121E+00 -0.0172 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.72965E-08 -8.1369 0.72959E-08 -8.1369 0.99992E+00 0.0000 54 KCl,aq 0.22994E-11 -11.6384 0.22994E-11 -11.6384 0.10000E+01 0.0000 55 KHSO4,aq 0.32671E-17 -17.4858 0.32671E-17 -17.4858 0.10000E+01 0.0000 56 KOH,aq 0.77622E-11 -11.1100 0.77622E-11 -11.1100 0.10000E+01 0.0000 57 KSO4- 0.35581E-09 -9.4488 0.34201E-09 -9.4660 0.96121E+00 -0.0172 58 MgCO3,aq 0.16618E-09 -9.7794 0.16618E-09 -9.7794 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.86335E-09 -9.0638 0.82989E-09 -9.0810 0.96124E+00 -0.0172 60 MgCl+ 0.56914E-09 -9.2448 0.54708E-09 -9.2619 0.96124E+00 -0.0172 61 MgOH+ 0.21073E-07 -7.6763 0.20256E-07 -7.6934 0.96124E+00 -0.0172 63 MnO,aq 0.24570E-10 -10.6096 0.24570E-10 -10.6096 0.10000E+01 0.0000 64 MnOH+ 0.41012E-08 -8.3871 0.39423E-08 -8.4043 0.96124E+00 -0.0172 65 MnO2-2 0.31186E-18 -18.5060 0.28092E-18 -18.5514 0.90080E+00 -0.0454 66 HMnO2- 0.34825E-14 -14.4581 0.33474E-14 -14.4753 0.96121E+00 -0.0172 69 MnCl+ 0.58782E-10 -10.2308 0.56503E-10 -10.2479 0.96124E+00 -0.0172 70 MnSO4,aq 0.45229E-09 -9.3446 0.45229E-09 -9.3446 0.10000E+01 0.0000 71 NaCl,aq 0.69127E-08 -8.1604 0.69127E-08 -8.1604 0.10000E+01 0.0000 72 NaOH,aq 0.12755E-08 -8.8943 0.12755E-08 -8.8943 0.10000E+01 0.0000 74 OH- 0.11347E-04 -4.9451 0.10907E-04 -4.9623 0.96117E+00 -0.0172 79 HPO3-2 0.34386E-18 -18.4636 0.30975E-18 -18.5090 0.90080E+00 -0.0454 81 H2PO3- 0.34814E-19 -19.4583 0.33463E-19 -19.4754 0.96121E+00 -0.0172 82 H3PO4,aq 0.26174E-12 -12.5821 0.26174E-12 -12.5821 0.10000E+01 0.0000 83 H2PO4- 0.13483E-07 -7.8702 0.12960E-07 -7.8874 0.96123E+00 -0.0172 84 PO4-3 0.26382E-12 -12.5787 0.21343E-12 -12.6707 0.80901E+00 -0.0920 87 H2P2O7-2 0.14594E-16 -16.8358 0.13146E-16 -16.8812 0.90080E+00 -0.0454 88 HP2O7-3 0.60643E-16 -16.2172 0.49014E-16 -16.3097 0.80824E+00 -0.0925 89 P2O7-4 0.31642E-18 -18.4997 0.21986E-18 -18.6579 0.69483E+00 -0.1581 90 H2S,aq 0.29028E-07 -7.5372 0.29025E-07 -7.5372 0.99992E+00 0.0000 91 S2-2 0.10325E-15 -15.9861 0.93007E-16 -16.0315 0.90080E+00 -0.0454 96 SO2,aq 0.20960E-17 -17.6786 0.20960E-17 -17.6786 0.10000E+01 0.0000 97 SO3-2 0.25028E-13 -13.6016 0.22551E-13 -13.6468 0.90106E+00 -0.0452 98 HSO3- 0.75512E-13 -13.1220 0.72583E-13 -13.1392 0.96121E+00 -0.0172 99 HSO4- 0.12034E-08 -8.9196 0.11568E-08 -8.9367 0.96126E+00 -0.0172 101 S2O3-2 0.86087E-14 -14.0651 0.77547E-14 -14.1104 0.90080E+00 -0.0454 102 HS2O3- 0.79188E-19 -19.1013 0.76116E-19 -19.1185 0.96121E+00 -0.0172 Charge balance for all species = 0.9782E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5721063E-07 -.1447777E-04 -.1459250E-01 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9999824E+06 0.0000 3 Cl- 0.1379630E-03 0.1379744E-03 0.4891531E+01 3.3822 4 SO4-- 0.2516459E-04 0.2529096E-04 0.2429452E+01 9.8747 5 HCO3- 0.1178242E-04 0.1307002E-04 0.7974839E+00 2.3137 6 HS- 0.1827393E-06 0.2135618E-06 0.7062807E-02 0.5043 7 Al+++ 0.1620258E-18 0.8793319E-06 0.2372532E-01 2.8961 8 H4SiO4 0.4835216E-04 0.4924715E-04 0.4733336E+01 -4.3156 9 Ca++ 0.1982807E-04 0.1999178E-04 0.8012182E+00 9.7712 10 Mg++ 0.3166456E-05 0.3189198E-05 0.7753458E-01 8.9744 11 Fe++ 0.2941322E-07 0.4668299E-07 0.2607064E-02 6.9424 12 K+ 0.1018744E-05 0.1019110E-05 0.3984863E-01 1.2506 13 Na+ 0.1660861E-03 0.1660965E-03 0.3818465E+01 3.4628 14 Mn++ 0.7816527E-07 0.8280215E-07 0.4548914E-02 7.3669 15 HPO4-- 0.1492075E-07 0.2840442E-07 0.2726185E-02 6.6477 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6644087E-04 -.1447775E-04 -.5196313E-04 0.0000000E+00 2 H2O 0.5550819E+02 0.5550816E+02 0.3280668E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2563749E-04 0.2529091E-04 0.3465858E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1330244E-06 0.2135614E-06 -.3465858E-06 0.0000000E+00 7 Al+++ 0.1565156E-04 0.8793302E-06 0.1477223E-04 0.0000000E+00 8 H4SiO4 0.4998136E-04 0.4924706E-04 0.7342959E-06 0.0000000E+00 9 Ca++ 0.1999174E-04 0.1999174E-04 0.0000000E+00 0.0000000E+00 10 Mg++ 0.3809524E-05 0.3189193E-05 0.6203313E-06 0.0000000E+00 11 Fe++ 0.3422441E-05 0.4668290E-07 0.3375758E-05 0.0000000E+00 12 K+ 0.1019108E-05 0.1019108E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1660962E-03 0.1660962E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.8322526E-07 0.8280200E-07 0.4232629E-09 0.0000000E+00 15 HPO4-- 0.2840437E-07 0.2840437E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.2679E-20 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0048000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.1241E-06 -6.906 0.6896E-04 -4.161 5.591 0.2623E-04 daphnite 0.1206E-06 -6.919 0.8606E-04 -4.065 6.978 0.2608E-04 chlorite-Mn 0.8465E-10 -10.072 0.6002E-07 -7.222 0.4866E-02 0.1913E-07 diaspore 0.1428E-04 -4.845 0.8568E-03 -3.067 69.47 0.2551E-03 hematite 0.1386E-05 -5.858 0.2214E-03 -3.655 17.95 0.4196E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.5069E+00 0.5069E+00 1.0000 -0.295 daphnite 0.4928E+00 0.4928E+00 1.0000 -0.307 chlorite-Mn 0.3459E-03 0.3459E-03 1.0000 -3.461 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.001233 g Volume = 0.000349 cm3 Porosity: 99.9651% V(tot) - V(min): 0.10016E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0048000 g log = -2.3188 Original solution: 1000.0103000 g Original solution / Rock added: 208335.48 (Water/Rock Ratio), log = 5.3188 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1356E-03 1.0073 0.1438E-03 0.1427E-03 CH4,gas 0.1278E-09 1.0129 0.1362E-09 0.1344E-09 H2,gas 0.9506E-05 1.0006 0.1001E-04 0.1000E-04 H2S,gas 0.8079E-06 0.9959 0.8465E-06 0.8500E-06 S2,gas 0.2548E-21 1.0000 0.2680E-21 0.2680E-21 CO,gas 0.3542E-12 1.0000 0.3726E-12 0.3726E-12 SO3,gas 0.2437E-34 1.0000 0.2563E-34 0.2563E-34 SO2,gas 0.9224E-17 1.0000 0.9704E-17 0.9704E-17 HCl,gas 0.2302E-14 1.0000 0.2422E-14 0.2422E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.60662E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.21 -5.84 -1.947 0.99757E+04 -3.842 3 CH4,gas 4.81 -7.06 -11.87 -2.966 0.20261E+05 -9.866 4 H2,gas 8.29 1.29 -7.00 -4.000 0.11952E+05 -5.000 5 H2S,gas -5.94 -14.02 -8.07 -4.036 0.13783E+05 -6.072 6 S2,gas -7.03 -30.60 -23.57 -3.626 0.40248E+05 -21.572 7 CO,gas 3.51 -10.92 -14.43 -4.440 0.24637E+05 -12.429 8 SO3,gas 17.43 -19.16 -36.59 -9.148 0.62478E+05 -34.591 9 SO2,gas 1.14 -17.88 -19.01 -5.070 0.32464E+05 -17.013 10 HCl,gas 5.48 -11.14 -16.62 -8.308 0.28371E+05 -14.616 21 andalusite 5.06 1.48 -3.59 -0.359 0.61226E+04 24 anhydrite -5.28 -9.39 -4.11 -2.056 0.70227E+04 32 apatite-OH -17.99 -18.32 -0.33 -0.025 0.55998E+03 35 aragonite 0.99 -2.43 -3.42 -1.140 0.58406E+04 36 brucite 12.58 8.97 -3.60 -0.720 0.61506E+04 37 calcite 0.83 -2.43 -3.27 -1.089 0.55793E+04 40 carpholite-Mg 8.65 6.14 -2.51 -0.168 0.42942E+04 41 carpholite-Fe 6.78 4.10 -2.68 -0.179 0.45751E+04 50 chloritoid-Mg 13.26 10.45 -2.81 -0.187 0.47984E+04 51 chloritoid-Fe 9.24 8.42 -0.82 -0.055 0.13996E+04 52 chloritoid-Mn 11.46 8.84 -2.62 -0.175 0.44731E+04 54 coesite -2.37 -4.32 -1.95 -0.649 0.33231E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.32 -1.77 -0.589 0.30160E+04 78 fayalite 14.08 9.57 -4.51 -0.644 0.77002E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.20 -4.00 -0.333 0.68267E+04 92 hercynite 17.34 12.73 -4.61 -0.307 0.78713E+04 98 kaolinite -1.27 -2.84 -1.57 -0.142 0.26736E+04 99 kyanite 4.93 1.48 -3.46 -0.346 0.58994E+04 101 laumontite 2.97 -1.70 -4.67 -0.312 0.79799E+04 102 lawsonite 9.68 6.93 -2.75 -0.183 0.46890E+04 105 lizardite 23.29 18.29 -5.00 -0.416 0.85293E+04 106 magnesite 0.71 -3.23 -3.94 -1.313 0.67282E+04 107 magnetite 20.13 19.54 -0.59 -0.048 0.10121E+04 110 magnesioferrite 26.26 21.57 -4.69 -0.382 0.79999E+04 113 margarite 17.45 12.72 -4.73 -0.189 0.80720E+04 128 periclase-Fe 11.64 6.94 -4.70 -1.174 0.80195E+04 142 pyrite -21.23 -22.37 -1.15 -0.270 0.19627E+04 143 pyrrhotite -4.24 -7.07 -2.83 -0.943 0.48305E+04 144 pyrrhotiteFe0.875 -6.00 -8.10 -2.10 -0.772 0.35840E+04 145 pyroxmangite 7.42 3.05 -4.36 -0.873 0.74527E+04 147 quartz -2.98 -4.32 -1.33 -0.445 0.22771E+04 152 rhodochrosite -0.96 -4.84 -3.88 -1.293 0.66253E+04 153 rhodonite 7.46 3.05 -4.41 -0.882 0.75319E+04 156 siderite -2.59 -5.26 -2.68 -0.892 0.45684E+04 157 sillimanite 5.32 1.48 -3.84 -0.384 0.65648E+04 169 sudoite 21.22 16.59 -4.63 -0.149 0.79051E+04 178 topaz-H 4.67 1.48 -3.19 -0.290 0.54485E+04 179 tridymite -2.61 -4.32 -1.70 -0.567 0.29044E+04 182 troilite-low -4.39 -7.07 -2.68 -0.893 0.45737E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.32 -1.52 -0.507 0.25974E+04 206 nontronite-Ca 3.28 -0.67 -3.95 -0.256 0.67484E+04 207 nontronite-H 2.60 -2.28 -4.88 -0.327 0.83335E+04 209 nontronite-Mg 3.14 -0.80 -3.94 -0.256 0.67331E+04 210 nontronite-Na 3.58 -1.14 -4.72 -0.303 0.80677E+04 215 gypsum -4.92 -9.39 -4.47 -1.117 0.76295E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.94 -2.88 -0.720 0.49206E+04 241 silica-amorphous -2.08 -4.32 -2.24 -0.745 0.38176E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0048000 g New total amount of reactant added: 0.0050000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.9763E-15 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0050000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2607507E-03 Osmotic coef. = 0.9903 True ionic strength = .2621712E-03 Chg. balance for total moles = 0.9763E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.56049E-07 -7.2514 0.53880E-07 -7.2686 0.96130E+00 -0.0171 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13261E-03 -3.8774 0.96119E+00 -0.0172 4 SO4-- 0.25194E-04 -4.5987 0.22694E-04 -4.6441 0.90078E+00 -0.0454 5 HCO3- 0.11805E-04 -4.9279 0.11347E-04 -4.9451 0.96122E+00 -0.0172 6 HS- 0.15641E-06 -6.8057 0.15034E-06 -6.8229 0.96119E+00 -0.0172 7 Al+++ 0.15237E-18 -18.8171 0.12313E-18 -18.9096 0.80811E+00 -0.0925 8 H4SiO4 0.49964E-04 -4.3013 0.49964E-04 -4.3013 0.10000E+01 0.0000 9 Ca++ 0.20055E-04 -4.6978 0.18063E-04 -4.7432 0.90065E+00 -0.0454 10 Mg++ 0.29721E-05 -5.5269 0.26766E-05 -5.5724 0.90057E+00 -0.0455 11 Fe++ 0.27755E-07 -7.5567 0.24996E-07 -7.6021 0.90059E+00 -0.0455 12 K+ 0.10612E-05 -5.9742 0.10200E-05 -5.9914 0.96122E+00 -0.0172 13 Na+ 0.16634E-03 -3.7790 0.15988E-03 -3.7962 0.96119E+00 -0.0172 14 Mn++ 0.81060E-07 -7.0912 0.73003E-07 -7.1367 0.90061E+00 -0.0455 15 HPO4-- 0.15694E-07 -7.8043 0.14137E-07 -7.8496 0.90078E+00 -0.0454 16 HSiO3- 0.94128E-06 -6.0263 0.90475E-06 -6.0435 0.96119E+00 -0.0172 17 Ca(HSiO3)+ 0.38093E-09 -9.4192 0.36616E-09 -9.4363 0.96123E+00 -0.0172 18 Mg(HSiO3)+ 0.70249E-10 -10.1534 0.67526E-10 -10.1705 0.96123E+00 -0.0172 19 NaHSiO3,aq 0.22974E-08 -8.6388 0.22974E-08 -8.6388 0.10000E+01 0.0000 20 AlO+ 0.56964E-11 -11.2444 0.54755E-11 -11.2616 0.96123E+00 -0.0172 21 AlOH+2 0.16409E-14 -14.7849 0.14779E-14 -14.8304 0.90062E+00 -0.0455 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.87683E-06 -6.0571 0.84277E-06 -6.0743 0.96116E+00 -0.0172 24 CH4,aq 0.73766E-13 -13.1321 0.73760E-13 -13.1322 0.99992E+00 0.0000 29 CO,aq 0.22388E-15 -15.6500 0.22388E-15 -15.6500 0.10000E+01 0.0000 30 CO2,aq 0.12328E-05 -5.9091 0.12327E-05 -5.9092 0.99992E+00 0.0000 31 CO3-2 0.21618E-07 -7.6652 0.19472E-07 -7.7106 0.90074E+00 -0.0454 32 CaCO3,aq 0.43078E-08 -8.3657 0.43078E-08 -8.3657 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53728E-08 -8.2698 0.51645E-08 -8.2870 0.96123E+00 -0.0172 34 CaCl+ 0.39709E-08 -8.4011 0.38169E-08 -8.4183 0.96123E+00 -0.0172 35 CaCl2,aq 0.11785E-12 -12.9287 0.11785E-12 -12.9287 0.10000E+01 0.0000 36 CaOH+ 0.24593E-07 -7.6092 0.23639E-07 -7.6264 0.96123E+00 -0.0172 37 CaSO4,aq 0.12772E-06 -6.8937 0.12772E-06 -6.8937 0.10000E+01 0.0000 38 HCl,aq 0.13439E-11 -11.8716 0.13439E-11 -11.8716 0.10000E+01 0.0000 43 FeCl+ 0.53709E-11 -11.2700 0.51626E-11 -11.2871 0.96123E+00 -0.0172 44 FeCl2,aq 0.21233E-19 -19.6730 0.21233E-19 -19.6730 0.10000E+01 0.0000 46 FeO,aq 0.34049E-09 -9.4679 0.34049E-09 -9.4679 0.10000E+01 0.0000 47 FeOH+ 0.16000E-07 -7.7959 0.15380E-07 -7.8130 0.96123E+00 -0.0172 48 HFeO2- 0.70716E-10 -10.1505 0.67971E-10 -10.1677 0.96119E+00 -0.0172 49 FeO+ 0.46368E-12 -12.3338 0.44570E-12 -12.3510 0.96123E+00 -0.0172 50 FeOH+2 0.49616E-17 -17.3044 0.44686E-17 -17.3498 0.90062E+00 -0.0455 51 FeO2- 0.31393E-10 -10.5032 0.30175E-10 -10.5204 0.96119E+00 -0.0172 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.70523E-08 -8.1517 0.70517E-08 -8.1517 0.99992E+00 0.0000 54 KCl,aq 0.23951E-11 -11.6207 0.23951E-11 -11.6207 0.10000E+01 0.0000 55 KHSO4,aq 0.33376E-17 -17.4766 0.33376E-17 -17.4766 0.10000E+01 0.0000 56 KOH,aq 0.82533E-11 -11.0834 0.82533E-11 -11.0834 0.10000E+01 0.0000 57 KSO4- 0.37104E-09 -9.4306 0.35664E-09 -9.4478 0.96119E+00 -0.0172 58 MgCO3,aq 0.15951E-09 -9.7972 0.15951E-09 -9.7972 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.81187E-09 -9.0905 0.78039E-09 -9.1077 0.96123E+00 -0.0172 60 MgCl+ 0.53418E-09 -9.2723 0.51347E-09 -9.2895 0.96123E+00 -0.0172 61 MgOH+ 0.20189E-07 -7.6949 0.19406E-07 -7.7121 0.96123E+00 -0.0172 63 MnO,aq 0.26547E-10 -10.5760 0.26547E-10 -10.5760 0.10000E+01 0.0000 64 MnOH+ 0.43412E-08 -8.3624 0.41729E-08 -8.3796 0.96123E+00 -0.0172 65 MnO2-2 0.35110E-18 -18.4546 0.31625E-18 -18.5000 0.90074E+00 -0.0454 66 HMnO2- 0.38408E-14 -14.4156 0.36918E-14 -14.4328 0.96119E+00 -0.0172 69 MnCl+ 0.60955E-10 -10.2150 0.58591E-10 -10.2322 0.96123E+00 -0.0172 70 MnSO4,aq 0.46953E-09 -9.3283 0.46953E-09 -9.3283 0.10000E+01 0.0000 71 NaCl,aq 0.69229E-08 -8.1597 0.69229E-08 -8.1597 0.10000E+01 0.0000 72 NaOH,aq 0.13039E-08 -8.8848 0.13039E-08 -8.8848 0.10000E+01 0.0000 74 OH- 0.11583E-04 -4.9362 0.11133E-04 -4.9534 0.96116E+00 -0.0172 79 HPO3-2 0.34958E-18 -18.4565 0.31488E-18 -18.5019 0.90074E+00 -0.0454 81 H2PO3- 0.34671E-19 -19.4600 0.33326E-19 -19.4772 0.96119E+00 -0.0172 82 H3PO4,aq 0.26422E-12 -12.5780 0.26422E-12 -12.5780 0.10000E+01 0.0000 83 H2PO4- 0.13893E-07 -7.8572 0.13354E-07 -7.8744 0.96121E+00 -0.0172 84 PO4-3 0.28328E-12 -12.5478 0.22914E-12 -12.6399 0.80889E+00 -0.0921 87 H2P2O7-2 0.15495E-16 -16.8098 0.13957E-16 -16.8552 0.90074E+00 -0.0454 88 HP2O7-3 0.65731E-16 -16.1822 0.53118E-16 -16.2748 0.80812E+00 -0.0925 89 P2O7-4 0.35013E-18 -18.4558 0.24321E-18 -18.6140 0.69464E+00 -0.1582 90 H2S,aq 0.24339E-07 -7.6137 0.24337E-07 -7.6137 0.99992E+00 0.0000 91 S2-2 0.78259E-16 -16.1065 0.70491E-16 -16.1519 0.90074E+00 -0.0454 96 SO2,aq 0.19464E-17 -17.7108 0.19464E-17 -17.7108 0.10000E+01 0.0000 97 SO3-2 0.24218E-13 -13.6159 0.21820E-13 -13.6611 0.90100E+00 -0.0453 98 HSO3- 0.71581E-13 -13.1452 0.68803E-13 -13.1624 0.96119E+00 -0.0172 99 HSO4- 0.11803E-08 -8.9280 0.11345E-08 -8.9452 0.96124E+00 -0.0172 101 S2O3-2 0.72267E-14 -14.1411 0.65094E-14 -14.1865 0.90074E+00 -0.0454 102 HS2O3- 0.65121E-19 -19.1863 0.62594E-19 -19.2035 0.96119E+00 -0.0172 Charge balance for all species = 0.9763E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5604852E-07 -.1486260E-04 -.1498037E-01 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9999822E+06 0.0000 3 Cl- 0.1379630E-03 0.1379744E-03 0.4891531E+01 3.3911 4 SO4-- 0.2519403E-04 0.2532204E-04 0.2432437E+01 9.8931 5 HCO3- 0.1180499E-04 0.1307003E-04 0.7974838E+00 2.3235 6 HS- 0.1564060E-06 0.1824790E-06 0.6034849E-02 0.4456 7 Al+++ 0.1523672E-18 0.8971722E-06 0.2420667E-01 2.8961 8 H4SiO4 0.4996357E-04 0.5090760E-04 0.4892927E+01 -4.3013 9 Ca++ 0.2005546E-04 0.2022181E-04 0.8104370E+00 9.7939 10 Mg++ 0.2972145E-05 0.2993910E-05 0.7278680E-01 8.9647 11 Fe++ 0.2775489E-07 0.4440722E-07 0.2479971E-02 6.9350 12 K+ 0.1061192E-05 0.1061573E-05 0.4150898E-01 1.2772 13 Na+ 0.1663370E-03 0.1663475E-03 0.3824236E+01 3.4724 14 Mn++ 0.8106042E-07 0.8595863E-07 0.4722321E-02 7.4005 15 HPO4-- 0.1569428E-07 0.2958794E-07 0.2839776E-02 6.6875 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6975258E-04 -.1486257E-04 -.5489001E-04 0.0000000E+00 2 H2O 0.5550819E+02 0.5550815E+02 0.3415238E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2564304E-04 0.2532199E-04 0.3210456E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385670E-06 0.1824786E-06 -.3210456E-06 0.0000000E+00 7 Al+++ 0.1630371E-04 0.8971705E-06 0.1540654E-04 0.0000000E+00 8 H4SiO4 0.5206391E-04 0.5090750E-04 0.1156413E-05 0.0000000E+00 9 Ca++ 0.2022177E-04 0.2022177E-04 0.0000000E+00 0.0000000E+00 10 Mg++ 0.3968254E-05 0.2993905E-05 0.9743494E-06 0.0000000E+00 11 Fe++ 0.3565043E-05 0.4440713E-07 0.3520636E-05 0.0000000E+00 12 K+ 0.1061571E-05 0.1061571E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1663472E-03 0.1663472E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.8669298E-07 0.8595847E-07 0.7345133E-09 0.0000000E+00 15 HPO4-- 0.2958788E-07 0.2958788E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.9471E-21 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0050000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.1949E-06 -6.710 0.1083E-03 -3.965 8.160 0.4120E-04 daphnite 0.1905E-06 -6.720 0.1359E-03 -3.867 10.24 0.4118E-04 chlorite-Mn 0.1469E-09 -9.833 0.1041E-06 -6.982 0.7846E-02 0.3319E-07 diaspore 0.1464E-04 -4.835 0.8780E-03 -3.057 66.14 0.2614E-03 hematite 0.1284E-05 -5.891 0.2051E-03 -3.688 15.45 0.3887E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.5055E+00 0.5055E+00 1.0000 -0.296 daphnite 0.4941E+00 0.4941E+00 1.0000 -0.306 chlorite-Mn 0.3811E-03 0.3811E-03 1.0000 -3.419 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.001327 g Volume = 0.000383 cm3 Porosity: 99.9618% V(tot) - V(min): 0.10016E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0050000 g log = -2.3010 Original solution: 1000.0103000 g Original solution / Rock added: 200002.06 (Water/Rock Ratio), log = 5.3010 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1331E-03 1.0073 0.1411E-03 0.1401E-03 CH4,gas 0.1095E-09 1.0129 0.1166E-09 0.1152E-09 H2,gas 0.9188E-05 1.0006 0.9672E-05 0.9667E-05 H2S,gas 0.6774E-06 0.9959 0.7098E-06 0.7127E-06 S2,gas 0.1917E-21 1.0000 0.2017E-21 0.2017E-21 CO,gas 0.3360E-12 1.0000 0.3535E-12 0.3535E-12 SO3,gas 0.2341E-34 1.0000 0.2463E-34 0.2463E-34 SO2,gas 0.8566E-17 1.0000 0.9012E-17 0.9012E-17 HCl,gas 0.2256E-14 1.0000 0.2373E-14 0.2373E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.21 -5.85 -1.950 0.99895E+04 -3.850 3 CH4,gas 4.81 -7.12 -11.93 -2.983 0.20376E+05 -9.933 4 H2,gas 8.29 1.27 -7.01 -4.008 0.11977E+05 -5.014 5 H2S,gas -5.94 -14.09 -8.15 -4.074 0.13914E+05 -6.149 6 S2,gas -7.03 -30.73 -23.70 -3.645 0.40459E+05 -21.695 7 CO,gas 3.51 -10.94 -14.45 -4.447 0.24676E+05 -12.452 8 SO3,gas 17.43 -19.18 -36.61 -9.152 0.62508E+05 -34.609 9 SO2,gas 1.14 -17.91 -19.05 -5.079 0.32519E+05 -17.045 10 HCl,gas 5.48 -11.15 -16.62 -8.312 0.28386E+05 -14.625 21 andalusite 5.06 1.49 -3.57 -0.357 0.60983E+04 24 anhydrite -5.28 -9.39 -4.11 -2.054 0.70135E+04 32 apatite-OH -17.99 -18.19 -0.20 -0.016 0.34474E+03 35 aragonite 0.99 -2.42 -3.41 -1.135 0.58156E+04 36 brucite 12.58 8.96 -3.61 -0.722 0.61672E+04 37 calcite 0.83 -2.42 -3.25 -1.084 0.55543E+04 40 carpholite-Mg 8.65 6.15 -2.50 -0.166 0.42621E+04 41 carpholite-Fe 6.78 4.12 -2.66 -0.177 0.45391E+04 50 chloritoid-Mg 13.26 10.46 -2.81 -0.187 0.47906E+04 51 chloritoid-Fe 9.24 8.43 -0.81 -0.054 0.13879E+04 52 chloritoid-Mn 11.46 8.89 -2.57 -0.171 0.43914E+04 54 coesite -2.37 -4.30 -1.93 -0.644 0.32988E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.30 -1.75 -0.584 0.29917E+04 78 fayalite 14.08 9.57 -4.51 -0.644 0.77012E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.20 -3.99 -0.333 0.68160E+04 92 hercynite 17.34 12.73 -4.62 -0.308 0.78839E+04 98 kaolinite -1.27 -2.81 -1.54 -0.140 0.26250E+04 99 kyanite 4.93 1.49 -3.44 -0.344 0.58751E+04 101 laumontite 2.97 -1.62 -4.59 -0.306 0.78438E+04 102 lawsonite 9.68 6.98 -2.69 -0.180 0.46016E+04 105 lizardite 23.29 18.29 -5.00 -0.416 0.85304E+04 106 magnesite 0.71 -3.25 -3.96 -1.319 0.67586E+04 107 magnetite 20.13 19.53 -0.60 -0.049 0.10247E+04 110 magnesioferrite 26.26 21.56 -4.69 -0.383 0.80164E+04 113 margarite 17.45 12.78 -4.68 -0.187 0.79845E+04 128 periclase-Fe 11.64 6.94 -4.70 -1.176 0.80322E+04 142 pyrite -21.23 -22.52 -1.30 -0.305 0.22113E+04 143 pyrrhotite -4.24 -7.16 -2.91 -0.971 0.49737E+04 144 pyrrhotiteFe0.875 -6.00 -8.18 -2.18 -0.802 0.37226E+04 145 pyroxmangite 7.42 3.10 -4.32 -0.863 0.73710E+04 147 quartz -2.98 -4.30 -1.32 -0.440 0.22528E+04 152 rhodochrosite -0.96 -4.81 -3.85 -1.285 0.65817E+04 153 rhodonite 7.46 3.10 -4.36 -0.873 0.74502E+04 156 siderite -2.59 -5.28 -2.69 -0.897 0.45948E+04 157 sillimanite 5.32 1.49 -3.83 -0.383 0.65405E+04 169 sudoite 21.22 16.61 -4.61 -0.149 0.78653E+04 178 topaz-H 4.67 1.49 -3.18 -0.289 0.54242E+04 179 tridymite -2.61 -4.30 -1.69 -0.562 0.28800E+04 182 troilite-low -4.39 -7.16 -2.76 -0.921 0.47169E+04 190 wollastonite 10.48 5.49 -4.99 -0.998 0.85190E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.30 -1.51 -0.502 0.25731E+04 206 nontronite-Ca 3.28 -0.62 -3.90 -0.253 0.66528E+04 207 nontronite-H 2.60 -2.23 -4.83 -0.324 0.82443E+04 209 nontronite-Mg 3.14 -0.75 -3.89 -0.253 0.66466E+04 210 nontronite-Na 3.58 -1.09 -4.67 -0.300 0.79731E+04 215 gypsum -4.92 -9.39 -4.46 -1.116 0.76203E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.94 -2.89 -0.722 0.49332E+04 241 silica-amorphous -2.08 -4.30 -2.22 -0.741 0.37933E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0050000 g New total amount of reactant added: 0.0052000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.9763E-15 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0052000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2611271E-03 Osmotic coef. = 0.9903 True ionic strength = .2626317E-03 Chg. balance for total moles = 0.9763E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.54836E-07 -7.2609 0.52713E-07 -7.2781 0.96129E+00 -0.0171 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13261E-03 -3.8774 0.96117E+00 -0.0172 4 SO4-- 0.25222E-04 -4.5982 0.22717E-04 -4.6436 0.90071E+00 -0.0454 5 HCO3- 0.11829E-04 -4.9271 0.11370E-04 -4.9443 0.96120E+00 -0.0172 6 HS- 0.13156E-06 -6.8809 0.12645E-06 -6.8981 0.96118E+00 -0.0172 7 Al+++ 0.14271E-18 -18.8456 0.11530E-18 -18.9382 0.80797E+00 -0.0926 8 H4SiO4 0.51588E-04 -4.2875 0.51588E-04 -4.2875 0.10000E+01 0.0000 9 Ca++ 0.20283E-04 -4.6929 0.18266E-04 -4.7383 0.90058E+00 -0.0455 10 Mg++ 0.27903E-05 -5.5544 0.25126E-05 -5.5999 0.90050E+00 -0.0455 11 Fe++ 0.26068E-07 -7.5839 0.23475E-07 -7.6294 0.90052E+00 -0.0455 12 K+ 0.11036E-05 -5.9572 0.10608E-05 -5.9744 0.96121E+00 -0.0172 13 Na+ 0.16659E-03 -3.7784 0.16012E-03 -3.7956 0.96117E+00 -0.0172 14 Mn++ 0.83897E-07 -7.0763 0.75552E-07 -7.1218 0.90054E+00 -0.0455 15 HPO4-- 0.16490E-07 -7.7828 0.14853E-07 -7.8282 0.90071E+00 -0.0454 16 HSiO3- 0.99341E-06 -6.0029 0.95484E-06 -6.0201 0.96117E+00 -0.0172 17 Ca(HSiO3)+ 0.40655E-09 -9.3909 0.39078E-09 -9.4081 0.96121E+00 -0.0172 18 Mg(HSiO3)+ 0.69597E-10 -10.1574 0.66898E-10 -10.1746 0.96121E+00 -0.0172 19 NaHSiO3,aq 0.24282E-08 -8.6147 0.24282E-08 -8.6147 0.10000E+01 0.0000 20 AlO+ 0.55732E-11 -11.2539 0.53570E-11 -11.2711 0.96121E+00 -0.0172 21 AlOH+2 0.15708E-14 -14.8039 0.14146E-14 -14.8494 0.90056E+00 -0.0455 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.89625E-06 -6.0476 0.86142E-06 -6.0648 0.96114E+00 -0.0172 24 CH4,aq 0.62107E-13 -13.2069 0.62102E-13 -13.2069 0.99992E+00 0.0000 29 CO,aq 0.21127E-15 -15.6752 0.21127E-15 -15.6752 0.10000E+01 0.0000 30 CO2,aq 0.12085E-05 -5.9178 0.12084E-05 -5.9178 0.99992E+00 0.0000 31 CO3-2 0.22142E-07 -7.6548 0.19942E-07 -7.7002 0.90067E+00 -0.0454 32 CaCO3,aq 0.44615E-08 -8.3505 0.44615E-08 -8.3505 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.54442E-08 -8.2641 0.52330E-08 -8.2813 0.96121E+00 -0.0172 34 CaCl+ 0.40156E-08 -8.3963 0.38598E-08 -8.4134 0.96121E+00 -0.0172 35 CaCl2,aq 0.11917E-12 -12.9238 0.11917E-12 -12.9238 0.10000E+01 0.0000 36 CaOH+ 0.25420E-07 -7.5948 0.24434E-07 -7.6120 0.96121E+00 -0.0172 37 CaSO4,aq 0.12929E-06 -6.8884 0.12929E-06 -6.8884 0.10000E+01 0.0000 38 HCl,aq 0.13148E-11 -11.8811 0.13148E-11 -11.8811 0.10000E+01 0.0000 43 FeCl+ 0.50440E-11 -11.2972 0.48483E-11 -11.3144 0.96121E+00 -0.0172 44 FeCl2,aq 0.19940E-19 -19.7003 0.19940E-19 -19.7003 0.10000E+01 0.0000 46 FeO,aq 0.33407E-09 -9.4762 0.33407E-09 -9.4762 0.10000E+01 0.0000 47 FeOH+ 0.15359E-07 -7.8136 0.14764E-07 -7.8308 0.96121E+00 -0.0172 48 HFeO2- 0.70920E-10 -10.1492 0.68167E-10 -10.1664 0.96117E+00 -0.0172 49 FeO+ 0.45365E-12 -12.3433 0.43605E-12 -12.3605 0.96121E+00 -0.0172 50 FeOH+2 0.47495E-17 -17.3234 0.42772E-17 -17.3688 0.90056E+00 -0.0455 51 FeO2- 0.32088E-10 -10.4937 0.30843E-10 -10.5108 0.96117E+00 -0.0172 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.67891E-08 -8.1682 0.67886E-08 -8.1682 0.99992E+00 0.0000 54 KCl,aq 0.24908E-11 -11.6037 0.24908E-11 -11.6037 0.10000E+01 0.0000 55 KHSO4,aq 0.33994E-17 -17.4686 0.33994E-17 -17.4686 0.10000E+01 0.0000 56 KOH,aq 0.87732E-11 -11.0568 0.87732E-11 -11.0568 0.10000E+01 0.0000 57 KSO4- 0.38628E-09 -9.4131 0.37128E-09 -9.4303 0.96117E+00 -0.0172 58 MgCO3,aq 0.15335E-09 -9.8143 0.15335E-09 -9.8143 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.76365E-09 -9.1171 0.73403E-09 -9.1343 0.96121E+00 -0.0172 60 MgCl+ 0.50145E-09 -9.2998 0.48200E-09 -9.3170 0.96121E+00 -0.0172 61 MgOH+ 0.19372E-07 -7.7128 0.18621E-07 -7.7300 0.96121E+00 -0.0172 63 MnO,aq 0.28703E-10 -10.5421 0.28703E-10 -10.5421 0.10000E+01 0.0000 64 MnOH+ 0.45922E-08 -8.3380 0.44141E-08 -8.3552 0.96121E+00 -0.0172 65 MnO2-2 0.39663E-18 -18.4016 0.35723E-18 -18.4470 0.90067E+00 -0.0454 66 HMnO2- 0.42448E-14 -14.3721 0.40800E-14 -14.3893 0.96117E+00 -0.0172 69 MnCl+ 0.63083E-10 -10.2001 0.60636E-10 -10.2173 0.96121E+00 -0.0172 70 MnSO4,aq 0.48642E-09 -9.3130 0.48642E-09 -9.3130 0.10000E+01 0.0000 71 NaCl,aq 0.69331E-08 -8.1591 0.69331E-08 -8.1591 0.10000E+01 0.0000 72 NaOH,aq 0.13347E-08 -8.8746 0.13347E-08 -8.8746 0.10000E+01 0.0000 74 OH- 0.11839E-04 -4.9267 0.11379E-04 -4.9439 0.96114E+00 -0.0172 79 HPO3-2 0.35360E-18 -18.4515 0.31847E-18 -18.4969 0.90067E+00 -0.0454 81 H2PO3- 0.34309E-19 -19.4646 0.32977E-19 -19.4818 0.96117E+00 -0.0172 82 H3PO4,aq 0.26570E-12 -12.5756 0.26570E-12 -12.5756 0.10000E+01 0.0000 83 H2PO4- 0.14281E-07 -7.8452 0.13727E-07 -7.8624 0.96119E+00 -0.0172 84 PO4-3 0.30426E-12 -12.5168 0.24607E-12 -12.6089 0.80875E+00 -0.0922 87 H2P2O7-2 0.16373E-16 -16.7859 0.14747E-16 -16.8313 0.90067E+00 -0.0454 88 HP2O7-3 0.70997E-16 -16.1488 0.57364E-16 -16.2414 0.80798E+00 -0.0926 89 P2O7-4 0.38659E-18 -18.4127 0.26846E-18 -18.5711 0.69443E+00 -0.1584 90 H2S,aq 0.20029E-07 -7.6983 0.20028E-07 -7.6984 0.99992E+00 0.0000 91 S2-2 0.57520E-16 -16.2402 0.51807E-16 -16.2856 0.90067E+00 -0.0454 96 SO2,aq 0.17954E-17 -17.7458 0.17954E-17 -17.7458 0.10000E+01 0.0000 97 SO3-2 0.23340E-13 -13.6319 0.21028E-13 -13.6772 0.90093E+00 -0.0453 98 HSO3- 0.67488E-13 -13.1708 0.64867E-13 -13.1880 0.96117E+00 -0.0172 99 HSO4- 0.11559E-08 -8.9371 0.11111E-08 -8.9542 0.96123E+00 -0.0172 101 S2O3-2 0.59536E-14 -14.2252 0.53622E-14 -14.2707 0.90067E+00 -0.0454 102 HS2O3- 0.52484E-19 -19.2800 0.50447E-19 -19.2972 0.96117E+00 -0.0172 Charge balance for all species = 0.9763E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5483615E-07 -.1527879E-04 -.1539986E-01 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9999820E+06 0.0000 3 Cl- 0.1379629E-03 0.1379745E-03 0.4891530E+01 3.4006 4 SO4-- 0.2522161E-04 0.2535126E-04 0.2435244E+01 9.9125 5 HCO3- 0.1182859E-04 0.1307003E-04 0.7974837E+00 2.3338 6 HS- 0.1315620E-06 0.1532593E-06 0.5068511E-02 0.3800 7 Al+++ 0.1427080E-18 0.9165913E-06 0.2473061E-01 2.8961 8 H4SiO4 0.5158811E-04 0.5258442E-04 0.5054092E+01 -4.2875 9 Ca++ 0.2028280E-04 0.2045184E-04 0.8196559E+00 9.8178 10 Mg++ 0.2790253E-05 0.2811113E-05 0.6834268E-01 8.9563 11 Fe++ 0.2606771E-07 0.4207321E-07 0.2349625E-02 6.9268 12 K+ 0.1103639E-05 0.1104036E-05 0.4316933E-01 1.3037 13 Na+ 0.1665879E-03 0.1665986E-03 0.3830007E+01 3.4825 14 Mn++ 0.8389681E-07 0.8906727E-07 0.4893099E-02 7.4344 15 HPO4-- 0.1649010E-07 0.3077146E-07 0.2953367E-02 6.7280 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7306428E-04 -.1527876E-04 -.5778552E-04 0.0000000E+00 2 H2O 0.5550819E+02 0.5550815E+02 0.3549892E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2564858E-04 0.2535121E-04 0.2973687E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1441097E-06 0.1532590E-06 -.2973687E-06 0.0000000E+00 7 Al+++ 0.1695586E-04 0.9165895E-06 0.1603927E-04 0.0000000E+00 8 H4SiO4 0.5414647E-04 0.5258432E-04 0.1562155E-05 0.0000000E+00 9 Ca++ 0.2045180E-04 0.2045180E-04 0.0000000E+00 0.0000000E+00 10 Mg++ 0.4126984E-05 0.2811107E-05 0.1315877E-05 0.0000000E+00 11 Fe++ 0.3707645E-05 0.4207313E-07 0.3665572E-05 0.0000000E+00 12 K+ 0.1104034E-05 0.1104034E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1665983E-03 0.1665983E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.9016070E-07 0.8906709E-07 0.1093612E-08 0.0000000E+00 15 HPO4-- 0.3077140E-07 0.3077140E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2504E-20 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0052000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2632E-06 -6.580 0.1463E-03 -3.835 10.30 0.5564E-04 daphnite 0.2573E-06 -6.590 0.1836E-03 -3.736 12.93 0.5564E-04 chlorite-Mn 0.2187E-09 -9.660 0.1551E-06 -6.809 0.1092E-01 0.4942E-07 diaspore 0.1500E-04 -4.824 0.8997E-03 -3.046 63.37 0.2679E-03 hematite 0.1189E-05 -5.925 0.1900E-03 -3.721 13.38 0.3600E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.5054E+00 0.5054E+00 1.0000 -0.296 daphnite 0.4942E+00 0.4942E+00 1.0000 -0.306 chlorite-Mn 0.4200E-03 0.4200E-03 1.0000 -3.377 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.001420 g Volume = 0.000415 cm3 Porosity: 99.9586% V(tot) - V(min): 0.10017E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0052000 g log = -2.2840 Original solution: 1000.0103000 g Original solution / Rock added: 192309.67 (Water/Rock Ratio), log = 5.2840 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1305E-03 1.0073 0.1383E-03 0.1373E-03 CH4,gas 0.9216E-10 1.0129 0.9821E-10 0.9695E-10 H2,gas 0.8845E-05 1.0006 0.9311E-05 0.9306E-05 H2S,gas 0.5575E-06 0.9959 0.5841E-06 0.5865E-06 S2,gas 0.1401E-21 1.0000 0.1474E-21 0.1474E-21 CO,gas 0.3171E-12 1.0000 0.3336E-12 0.3336E-12 SO3,gas 0.2243E-34 1.0000 0.2360E-34 0.2360E-34 SO2,gas 0.7901E-17 1.0000 0.8312E-17 0.8312E-17 HCl,gas 0.2207E-14 1.0000 0.2322E-14 0.2322E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.22 -5.86 -1.953 0.10004E+05 -3.859 3 CH4,gas 4.81 -7.20 -12.01 -3.002 0.20503E+05 -10.008 4 H2,gas 8.29 1.26 -7.03 -4.018 0.12005E+05 -5.031 5 H2S,gas -5.94 -14.18 -8.23 -4.117 0.14058E+05 -6.233 6 S2,gas -7.03 -30.86 -23.83 -3.666 0.40692E+05 -21.831 7 CO,gas 3.51 -10.97 -14.48 -4.454 0.24719E+05 -12.477 8 SO3,gas 17.43 -19.20 -36.63 -9.157 0.62540E+05 -34.627 9 SO2,gas 1.14 -17.94 -19.08 -5.088 0.32579E+05 -17.080 10 HCl,gas 5.48 -11.16 -16.63 -8.317 0.28402E+05 -14.634 21 andalusite 5.06 1.50 -3.56 -0.356 0.60746E+04 24 anhydrite -5.28 -9.38 -4.10 -2.051 0.70045E+04 32 apatite-OH -17.99 -18.06 -0.08 -0.006 0.12843E+03 35 aragonite 0.99 -2.40 -3.39 -1.130 0.57896E+04 36 brucite 12.58 8.96 -3.62 -0.724 0.61816E+04 37 calcite 0.83 -2.40 -3.24 -1.079 0.55283E+04 40 carpholite-Mg 8.65 6.17 -2.48 -0.165 0.42291E+04 41 carpholite-Fe 6.78 4.14 -2.64 -0.176 0.45058E+04 50 chloritoid-Mg 13.26 10.46 -2.80 -0.187 0.47813E+04 51 chloritoid-Fe 9.24 8.43 -0.81 -0.054 0.13782E+04 52 chloritoid-Mn 11.46 8.94 -2.52 -0.168 0.43098E+04 54 coesite -2.37 -4.29 -1.92 -0.639 0.32751E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.29 -1.74 -0.579 0.29680E+04 78 fayalite 14.08 9.57 -4.51 -0.645 0.77056E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.21 -3.99 -0.332 0.68108E+04 92 hercynite 17.34 12.72 -4.63 -0.308 0.78980E+04 98 kaolinite -1.27 -2.78 -1.51 -0.137 0.25776E+04 99 kyanite 4.93 1.50 -3.43 -0.343 0.58514E+04 101 laumontite 2.97 -1.54 -4.51 -0.301 0.77081E+04 102 lawsonite 9.68 7.04 -2.64 -0.176 0.45133E+04 105 lizardite 23.29 18.29 -4.99 -0.416 0.85262E+04 106 magnesite 0.71 -3.27 -3.98 -1.325 0.67878E+04 107 magnetite 20.13 19.52 -0.61 -0.050 0.10388E+04 110 magnesioferrite 26.26 21.55 -4.70 -0.384 0.80309E+04 113 margarite 17.45 12.83 -4.62 -0.185 0.78963E+04 128 periclase-Fe 11.64 6.93 -4.71 -1.178 0.80463E+04 142 pyrite -21.23 -22.68 -1.46 -0.343 0.24863E+04 143 pyrrhotite -4.24 -7.25 -3.01 -1.002 0.51324E+04 144 pyrrhotiteFe0.875 -6.00 -8.27 -2.27 -0.835 0.38759E+04 145 pyroxmangite 7.42 3.15 -4.27 -0.854 0.72893E+04 147 quartz -2.98 -4.29 -1.31 -0.435 0.22290E+04 152 rhodochrosite -0.96 -4.79 -3.83 -1.276 0.65386E+04 153 rhodonite 7.46 3.15 -4.32 -0.863 0.73686E+04 156 siderite -2.59 -5.30 -2.71 -0.903 0.46237E+04 157 sillimanite 5.32 1.50 -3.82 -0.382 0.65168E+04 169 sudoite 21.22 16.63 -4.58 -0.148 0.78230E+04 178 topaz-H 4.67 1.50 -3.16 -0.288 0.54004E+04 179 tridymite -2.61 -4.29 -1.67 -0.558 0.28563E+04 182 troilite-low -4.39 -7.25 -2.86 -0.952 0.48756E+04 190 wollastonite 10.48 5.53 -4.95 -0.990 0.84545E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.29 -1.49 -0.498 0.25493E+04 206 nontronite-Ca 3.28 -0.56 -3.84 -0.249 0.65590E+04 207 nontronite-H 2.60 -2.18 -4.78 -0.320 0.81572E+04 209 nontronite-Mg 3.14 -0.70 -3.84 -0.249 0.65620E+04 210 nontronite-Na 3.58 -1.03 -4.62 -0.296 0.78803E+04 215 gypsum -4.92 -9.38 -4.46 -1.114 0.76112E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.93 -2.90 -0.724 0.49473E+04 241 silica-amorphous -2.08 -4.29 -2.21 -0.736 0.37695E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0052000 g New total amount of reactant added: 0.0054000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.9763E-15 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0054000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2615309E-03 Osmotic coef. = 0.9903 True ionic strength = .2631257E-03 Chg. balance for total moles = 0.9763E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.53583E-07 -7.2710 0.51508E-07 -7.2881 0.96127E+00 -0.0172 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13260E-03 -3.8774 0.96115E+00 -0.0172 4 SO4-- 0.25247E-04 -4.5978 0.22738E-04 -4.6432 0.90064E+00 -0.0454 5 HCO3- 0.11853E-04 -4.9262 0.11393E-04 -4.9434 0.96118E+00 -0.0172 6 HS- 0.10871E-06 -6.9638 0.10448E-06 -6.9810 0.96116E+00 -0.0172 7 Al+++ 0.13316E-18 -18.8756 0.10757E-18 -18.9683 0.80783E+00 -0.0927 8 H4SiO4 0.53228E-04 -4.2739 0.53228E-04 -4.2739 0.10000E+01 0.0000 9 Ca++ 0.20510E-04 -4.6880 0.18470E-04 -4.7335 0.90051E+00 -0.0455 10 Mg++ 0.26204E-05 -5.5816 0.23595E-05 -5.6272 0.90043E+00 -0.0455 11 Fe++ 0.24372E-07 -7.6131 0.21946E-07 -7.6586 0.90045E+00 -0.0455 12 K+ 0.11461E-05 -5.9408 0.11016E-05 -5.9580 0.96119E+00 -0.0172 13 Na+ 0.16684E-03 -3.7777 0.16036E-03 -3.7949 0.96115E+00 -0.0172 14 Mn++ 0.86671E-07 -7.0621 0.78044E-07 -7.1077 0.90047E+00 -0.0455 15 HPO4-- 0.17308E-07 -7.7617 0.15589E-07 -7.8072 0.90064E+00 -0.0454 16 HSiO3- 0.10490E-05 -5.9792 0.10083E-05 -5.9964 0.96115E+00 -0.0172 17 Ca(HSiO3)+ 0.43408E-09 -9.3624 0.41723E-09 -9.3796 0.96119E+00 -0.0172 18 Mg(HSiO3)+ 0.69013E-10 -10.1611 0.66335E-10 -10.1783 0.96119E+00 -0.0172 19 NaHSiO3,aq 0.25679E-08 -8.5904 0.25679E-08 -8.5904 0.10000E+01 0.0000 20 AlO+ 0.54458E-11 -11.2639 0.52345E-11 -11.2811 0.96119E+00 -0.0172 21 AlOH+2 0.14999E-14 -14.8239 0.13506E-14 -14.8695 0.90048E+00 -0.0455 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.91724E-06 -6.0375 0.88158E-06 -6.0547 0.96112E+00 -0.0172 24 CH4,aq 0.51374E-13 -13.2893 0.51370E-13 -13.2893 0.99992E+00 0.0000 29 CO,aq 0.19833E-15 -15.7026 0.19833E-15 -15.7026 0.10000E+01 0.0000 30 CO2,aq 0.11833E-05 -5.9269 0.11832E-05 -5.9270 0.99992E+00 0.0000 31 CO3-2 0.22708E-07 -7.6438 0.20451E-07 -7.6893 0.90060E+00 -0.0455 32 CaCO3,aq 0.46262E-08 -8.3348 0.46262E-08 -8.3348 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.55161E-08 -8.2584 0.53020E-08 -8.2756 0.96119E+00 -0.0172 34 CaCl+ 0.40603E-08 -8.3914 0.39027E-08 -8.4086 0.96119E+00 -0.0172 35 CaCl2,aq 0.12050E-12 -12.9190 0.12050E-12 -12.9190 0.10000E+01 0.0000 36 CaOH+ 0.26305E-07 -7.5800 0.25284E-07 -7.5971 0.96119E+00 -0.0172 37 CaSO4,aq 0.13085E-06 -6.8832 0.13085E-06 -6.8832 0.10000E+01 0.0000 38 HCl,aq 0.12847E-11 -11.8912 0.12847E-11 -11.8912 0.10000E+01 0.0000 43 FeCl+ 0.47155E-11 -11.3265 0.45325E-11 -11.3437 0.96119E+00 -0.0172 44 FeCl2,aq 0.18641E-19 -19.7295 0.18641E-19 -19.7295 0.10000E+01 0.0000 46 FeO,aq 0.32710E-09 -9.4853 0.32710E-09 -9.4853 0.10000E+01 0.0000 47 FeOH+ 0.14695E-07 -7.8328 0.14125E-07 -7.8500 0.96119E+00 -0.0172 48 HFeO2- 0.71067E-10 -10.1483 0.68307E-10 -10.1655 0.96115E+00 -0.0172 49 FeO+ 0.44328E-12 -12.3533 0.42608E-12 -12.3705 0.96119E+00 -0.0172 50 FeOH+2 0.45351E-17 -17.3434 0.40838E-17 -17.3889 0.90048E+00 -0.0455 51 FeO2- 0.32840E-10 -10.4836 0.31564E-10 -10.5008 0.96115E+00 -0.0172 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.65088E-08 -8.1865 0.65083E-08 -8.1865 0.99992E+00 0.0000 54 KCl,aq 0.25865E-11 -11.5873 0.25865E-11 -11.5873 0.10000E+01 0.0000 55 KHSO4,aq 0.34525E-17 -17.4619 0.34525E-17 -17.4619 0.10000E+01 0.0000 56 KOH,aq 0.93236E-11 -11.0304 0.93236E-11 -11.0304 0.10000E+01 0.0000 57 KSO4- 0.40150E-09 -9.3963 0.38591E-09 -9.4135 0.96115E+00 -0.0172 58 MgCO3,aq 0.14768E-09 -9.8307 0.14768E-09 -9.8307 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.71859E-09 -9.1435 0.69070E-09 -9.1607 0.96119E+00 -0.0172 60 MgCl+ 0.47089E-09 -9.3271 0.45261E-09 -9.3443 0.96119E+00 -0.0172 61 MgOH+ 0.18617E-07 -7.7301 0.17895E-07 -7.7473 0.96119E+00 -0.0172 63 MnO,aq 0.31053E-10 -10.5079 0.31053E-10 -10.5079 0.10000E+01 0.0000 64 MnOH+ 0.48548E-08 -8.3138 0.46664E-08 -8.3310 0.96119E+00 -0.0172 65 MnO2-2 0.44947E-18 -18.3473 0.40479E-18 -18.3928 0.90060E+00 -0.0455 66 HMnO2- 0.46999E-14 -14.3279 0.45174E-14 -14.3451 0.96115E+00 -0.0172 69 MnCl+ 0.65163E-10 -10.1860 0.62634E-10 -10.2032 0.96119E+00 -0.0172 70 MnSO4,aq 0.50292E-09 -9.2985 0.50292E-09 -9.2985 0.10000E+01 0.0000 71 NaCl,aq 0.69432E-08 -8.1584 0.69432E-08 -8.1584 0.10000E+01 0.0000 72 NaOH,aq 0.13680E-08 -8.8639 0.13680E-08 -8.8639 0.10000E+01 0.0000 74 OH- 0.12117E-04 -4.9166 0.11646E-04 -4.9338 0.96112E+00 -0.0172 79 HPO3-2 0.35582E-18 -18.4488 0.32045E-18 -18.4942 0.90060E+00 -0.0455 81 H2PO3- 0.33733E-19 -19.4719 0.32423E-19 -19.4891 0.96115E+00 -0.0172 82 H3PO4,aq 0.26626E-12 -12.5747 0.26626E-12 -12.5747 0.10000E+01 0.0000 83 H2PO4- 0.14646E-07 -7.8343 0.14077E-07 -7.8515 0.96117E+00 -0.0172 84 PO4-3 0.32687E-12 -12.4856 0.26431E-12 -12.5779 0.80861E+00 -0.0923 87 H2P2O7-2 0.17221E-16 -16.7639 0.15510E-16 -16.8094 0.90060E+00 -0.0455 88 HP2O7-3 0.76431E-16 -16.1167 0.61744E-16 -16.2094 0.80784E+00 -0.0927 89 P2O7-4 0.42599E-18 -18.3706 0.29572E-18 -18.5291 0.69421E+00 -0.1585 90 H2S,aq 0.16171E-07 -7.7913 0.16170E-07 -7.7913 0.99992E+00 0.0000 91 S2-2 0.40962E-16 -16.3876 0.36891E-16 -16.4331 0.90060E+00 -0.0455 96 SO2,aq 0.16450E-17 -17.7838 0.16450E-17 -17.7838 0.10000E+01 0.0000 97 SO3-2 0.22399E-13 -13.6498 0.20178E-13 -13.6951 0.90086E+00 -0.0453 98 HSO3- 0.63281E-13 -13.1987 0.60823E-13 -13.2159 0.96115E+00 -0.0172 99 HSO4- 0.11306E-08 -8.9467 0.10867E-08 -8.9639 0.96121E+00 -0.0172 101 S2O3-2 0.48114E-14 -14.3177 0.43332E-14 -14.3632 0.90060E+00 -0.0455 102 HS2O3- 0.41443E-19 -19.3825 0.39833E-19 -19.3998 0.96115E+00 -0.0172 Charge balance for all species = 0.9763E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5358327E-07 -.1572622E-04 -.1585083E-01 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9999819E+06 0.0000 3 Cl- 0.1379629E-03 0.1379745E-03 0.4891530E+01 3.4107 4 SO4-- 0.2524676E-04 0.2537805E-04 0.2437817E+01 9.9330 5 HCO3- 0.1185306E-04 0.1307003E-04 0.7974836E+00 2.3448 6 HS- 0.1087050E-06 0.1264736E-06 0.4182668E-02 0.3072 7 Al+++ 0.1331642E-18 0.9375837E-06 0.2529701E-01 2.8961 8 H4SiO4 0.5322808E-04 0.5428015E-04 0.5217074E+01 -4.2739 9 Ca++ 0.2051008E-04 0.2068187E-04 0.8288748E+00 9.8427 10 Mg++ 0.2620415E-05 0.2640439E-05 0.6419331E-01 8.9491 11 Fe++ 0.2437192E-07 0.3970702E-07 0.2217482E-02 6.9176 12 K+ 0.1146086E-05 0.1146499E-05 0.4482969E-01 1.3302 13 Na+ 0.1668388E-03 0.1668497E-03 0.3835779E+01 3.4932 14 Mn++ 0.8667053E-07 0.9212447E-07 0.5061053E-02 7.4686 15 HPO4-- 0.1730849E-07 0.3195498E-07 0.3066958E-02 6.7691 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7637598E-04 -.1572619E-04 -.6064979E-04 0.0000000E+00 2 H2O 0.5550818E+02 0.5550815E+02 0.3684918E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2565412E-04 0.2537800E-04 0.2761257E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1496524E-06 0.1264733E-06 -.2761257E-06 0.0000000E+00 7 Al+++ 0.1760800E-04 0.9375817E-06 0.1667042E-04 0.0000000E+00 8 H4SiO4 0.5622903E-04 0.5428004E-04 0.1948991E-05 0.0000000E+00 9 Ca++ 0.2068183E-04 0.2068183E-04 0.0000000E+00 0.0000000E+00 10 Mg++ 0.4285714E-05 0.2640433E-05 0.1645281E-05 0.0000000E+00 11 Fe++ 0.3850246E-05 0.3970693E-07 0.3810539E-05 0.0000000E+00 12 K+ 0.1146497E-05 0.1146497E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1668493E-03 0.1668493E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.9362842E-07 0.9212428E-07 0.1504138E-08 0.0000000E+00 15 HPO4-- 0.3195491E-07 0.3195491E-07 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.5499E-20 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0054000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.3291E-06 -6.483 0.1829E-03 -3.738 12.11 0.6957E-04 daphnite 0.3203E-06 -6.494 0.2285E-03 -3.641 15.13 0.6926E-04 chlorite-Mn 0.3008E-09 -9.522 0.2133E-06 -6.671 0.1412E-01 0.6797E-07 diaspore 0.1537E-04 -4.813 0.9221E-03 -3.035 61.06 0.2745E-03 hematite 0.1105E-05 -5.957 0.1764E-03 -3.754 11.68 0.3343E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.5065E+00 0.5065E+00 1.0000 -0.295 daphnite 0.4930E+00 0.4930E+00 1.0000 -0.307 chlorite-Mn 0.4631E-03 0.4631E-03 1.0000 -3.334 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.001510 g Volume = 0.000447 cm3 Porosity: 99.9554% V(tot) - V(min): 0.10017E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0054000 g log = -2.2676 Original solution: 1000.0103000 g Original solution / Rock added: 185187.09 (Water/Rock Ratio), log = 5.2676 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1278E-03 1.0073 0.1354E-03 0.1344E-03 CH4,gas 0.7623E-10 1.0129 0.8123E-10 0.8020E-10 H2,gas 0.8480E-05 1.0006 0.8927E-05 0.8922E-05 H2S,gas 0.4501E-06 0.9959 0.4716E-06 0.4735E-06 S2,gas 0.9936E-22 1.0000 0.1045E-21 0.1045E-21 CO,gas 0.2977E-12 1.0000 0.3132E-12 0.3132E-12 SO3,gas 0.2144E-34 1.0000 0.2255E-34 0.2255E-34 SO2,gas 0.7239E-17 1.0000 0.7616E-17 0.7616E-17 HCl,gas 0.2156E-14 1.0000 0.2268E-14 0.2268E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.60662E-11 32 apatite-OH -17.99 -17.94 0.05 0.004 -0.88780E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.23 -5.87 -1.956 0.10020E+05 -3.868 3 CH4,gas 4.81 -7.28 -12.09 -3.023 0.20644E+05 -10.090 4 H2,gas 8.29 1.24 -7.05 -4.028 0.12037E+05 -5.049 5 H2S,gas -5.94 -14.27 -8.33 -4.163 0.14217E+05 -6.326 6 S2,gas -7.03 -31.01 -23.98 -3.689 0.40946E+05 -21.981 7 CO,gas 3.51 -10.99 -14.50 -4.463 0.24766E+05 -12.504 8 SO3,gas 17.43 -19.22 -36.65 -9.162 0.62573E+05 -34.647 9 SO2,gas 1.14 -17.98 -19.12 -5.098 0.32644E+05 -17.118 10 HCl,gas 5.48 -11.17 -16.64 -8.322 0.28420E+05 -14.644 21 andalusite 5.06 1.52 -3.54 -0.354 0.60514E+04 24 anhydrite -5.28 -9.38 -4.10 -2.049 0.69956E+04 35 aragonite 0.99 -2.39 -3.38 -1.125 0.57627E+04 36 brucite 12.58 8.95 -3.63 -0.726 0.61939E+04 37 calcite 0.83 -2.39 -3.22 -1.074 0.55014E+04 40 carpholite-Mg 8.65 6.19 -2.46 -0.164 0.41950E+04 41 carpholite-Fe 6.78 4.16 -2.62 -0.175 0.44750E+04 50 chloritoid-Mg 13.26 10.47 -2.79 -0.186 0.47704E+04 51 chloritoid-Fe 9.24 8.44 -0.80 -0.054 0.13707E+04 52 chloritoid-Mn 11.46 8.99 -2.48 -0.165 0.42282E+04 54 coesite -2.37 -4.27 -1.90 -0.635 0.32519E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.27 -1.72 -0.575 0.29448E+04 78 fayalite 14.08 9.56 -4.52 -0.645 0.77137E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.21 -3.99 -0.332 0.68113E+04 92 hercynite 17.34 12.71 -4.63 -0.309 0.79137E+04 98 kaolinite -1.27 -2.76 -1.48 -0.135 0.25312E+04 99 kyanite 4.93 1.52 -3.41 -0.341 0.58282E+04 101 laumontite 2.97 -1.46 -4.44 -0.296 0.75728E+04 102 lawsonite 9.68 7.09 -2.59 -0.173 0.44244E+04 105 lizardite 23.29 18.30 -4.99 -0.416 0.85167E+04 106 magnesite 0.71 -3.28 -3.99 -1.331 0.68158E+04 107 magnetite 20.13 19.52 -0.62 -0.050 0.10545E+04 110 magnesioferrite 26.26 21.55 -4.71 -0.385 0.80432E+04 113 margarite 17.45 12.88 -4.57 -0.183 0.78073E+04 121 paragonite 4.34 -0.64 -4.98 -0.293 0.84976E+04 128 periclase-Fe 11.64 6.92 -4.72 -1.180 0.80619E+04 142 pyrite -21.23 -22.86 -1.63 -0.384 0.27880E+04 143 pyrrhotite -4.24 -7.35 -3.11 -1.036 0.53067E+04 144 pyrrhotiteFe0.875 -6.00 -8.37 -2.37 -0.871 0.40444E+04 145 pyroxmangite 7.42 3.19 -4.22 -0.844 0.72078E+04 147 quartz -2.98 -4.27 -1.29 -0.431 0.22058E+04 152 rhodochrosite -0.96 -4.76 -3.80 -1.268 0.64958E+04 153 rhodonite 7.46 3.19 -4.27 -0.854 0.72870E+04 156 siderite -2.59 -5.31 -2.73 -0.909 0.46549E+04 157 sillimanite 5.32 1.52 -3.80 -0.380 0.64936E+04 169 sudoite 21.22 16.66 -4.56 -0.147 0.77780E+04 178 topaz-H 4.67 1.52 -3.15 -0.286 0.53772E+04 179 tridymite -2.61 -4.27 -1.66 -0.553 0.28331E+04 182 troilite-low -4.39 -7.35 -2.96 -0.986 0.50499E+04 190 wollastonite 10.48 5.57 -4.91 -0.983 0.83888E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.27 -1.48 -0.493 0.25261E+04 206 nontronite-Ca 3.28 -0.51 -3.79 -0.246 0.64668E+04 207 nontronite-H 2.60 -2.13 -4.73 -0.317 0.80720E+04 209 nontronite-Mg 3.14 -0.66 -3.79 -0.246 0.64788E+04 210 nontronite-Na 3.58 -0.98 -4.56 -0.293 0.77891E+04 215 gypsum -4.92 -9.38 -4.45 -1.113 0.76023E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.92 -2.91 -0.727 0.49630E+04 241 silica-amorphous -2.08 -4.27 -2.19 -0.731 0.37463E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0054000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2615247E-03 Osmotic coef. = 0.9903 True ionic strength = .2631200E-03 Chg. balance for total moles = 0.9763E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.53588E-07 -7.2709 0.51513E-07 -7.2881 0.96127E+00 -0.0172 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13260E-03 -3.8774 0.96116E+00 -0.0172 4 SO4-- 0.25247E-04 -4.5978 0.22738E-04 -4.6432 0.90064E+00 -0.0454 5 HCO3- 0.11853E-04 -4.9262 0.11393E-04 -4.9434 0.96118E+00 -0.0172 6 HS- 0.10873E-06 -6.9636 0.10451E-06 -6.9808 0.96116E+00 -0.0172 7 Al+++ 0.13320E-18 -18.8755 0.10760E-18 -18.9682 0.80783E+00 -0.0927 8 H4SiO4 0.53229E-04 -4.2739 0.53229E-04 -4.2739 0.10000E+01 0.0000 9 Ca++ 0.20508E-04 -4.6881 0.18468E-04 -4.7336 0.90051E+00 -0.0455 10 Mg++ 0.26208E-05 -5.5816 0.23599E-05 -5.6271 0.90043E+00 -0.0455 11 Fe++ 0.24377E-07 -7.6130 0.21950E-07 -7.6586 0.90045E+00 -0.0455 12 K+ 0.11461E-05 -5.9408 0.11016E-05 -5.9580 0.96119E+00 -0.0172 13 Na+ 0.16684E-03 -3.7777 0.16036E-03 -3.7949 0.96115E+00 -0.0172 14 Mn++ 0.86671E-07 -7.0621 0.78045E-07 -7.1077 0.90047E+00 -0.0455 15 HPO4-- 0.16636E-07 -7.7789 0.14983E-07 -7.8244 0.90064E+00 -0.0454 16 HSiO3- 0.10489E-05 -5.9793 0.10082E-05 -5.9965 0.96116E+00 -0.0172 17 Ca(HSiO3)+ 0.43400E-09 -9.3625 0.41716E-09 -9.3797 0.96119E+00 -0.0172 18 Mg(HSiO3)+ 0.69018E-10 -10.1610 0.66339E-10 -10.1782 0.96119E+00 -0.0172 19 NaHSiO3,aq 0.25677E-08 -8.5905 0.25677E-08 -8.5905 0.10000E+01 0.0000 20 AlO+ 0.54463E-11 -11.2639 0.52350E-11 -11.2811 0.96119E+00 -0.0172 21 AlOH+2 0.15002E-14 -14.8239 0.13509E-14 -14.8694 0.90048E+00 -0.0455 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.91716E-06 -6.0376 0.88150E-06 -6.0548 0.96112E+00 -0.0172 24 CH4,aq 0.51388E-13 -13.2891 0.51383E-13 -13.2892 0.99992E+00 0.0000 29 CO,aq 0.19835E-15 -15.7026 0.19835E-15 -15.7026 0.10000E+01 0.0000 30 CO2,aq 0.11834E-05 -5.9269 0.11833E-05 -5.9269 0.99992E+00 0.0000 31 CO3-2 0.22706E-07 -7.6439 0.20449E-07 -7.6893 0.90060E+00 -0.0455 32 CaCO3,aq 0.46253E-08 -8.3349 0.46253E-08 -8.3349 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.55155E-08 -8.2584 0.53015E-08 -8.2756 0.96119E+00 -0.0172 34 CaCl+ 0.40599E-08 -8.3915 0.39023E-08 -8.4087 0.96119E+00 -0.0172 35 CaCl2,aq 0.12048E-12 -12.9191 0.12048E-12 -12.9191 0.10000E+01 0.0000 36 CaOH+ 0.26300E-07 -7.5800 0.25280E-07 -7.5972 0.96119E+00 -0.0172 37 CaSO4,aq 0.13084E-06 -6.8833 0.13084E-06 -6.8833 0.10000E+01 0.0000 38 HCl,aq 0.12848E-11 -11.8911 0.12848E-11 -11.8911 0.10000E+01 0.0000 43 FeCl+ 0.47165E-11 -11.3264 0.45334E-11 -11.3436 0.96119E+00 -0.0172 44 FeCl2,aq 0.18644E-19 -19.7295 0.18644E-19 -19.7295 0.10000E+01 0.0000 46 FeO,aq 0.32711E-09 -9.4853 0.32711E-09 -9.4853 0.10000E+01 0.0000 47 FeOH+ 0.14697E-07 -7.8328 0.14127E-07 -7.8500 0.96119E+00 -0.0172 48 HFeO2- 0.71063E-10 -10.1484 0.68302E-10 -10.1656 0.96116E+00 -0.0172 49 FeO+ 0.44332E-12 -12.3533 0.42612E-12 -12.3705 0.96119E+00 -0.0172 50 FeOH+2 0.45359E-17 -17.3433 0.40845E-17 -17.3889 0.90048E+00 -0.0455 51 FeO2- 0.32837E-10 -10.4836 0.31562E-10 -10.5008 0.96116E+00 -0.0172 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.65091E-08 -8.1865 0.65086E-08 -8.1865 0.99992E+00 0.0000 54 KCl,aq 0.25865E-11 -11.5873 0.25865E-11 -11.5873 0.10000E+01 0.0000 55 KHSO4,aq 0.34528E-17 -17.4618 0.34528E-17 -17.4618 0.10000E+01 0.0000 56 KOH,aq 0.93228E-11 -11.0305 0.93228E-11 -11.0305 0.10000E+01 0.0000 57 KSO4- 0.40150E-09 -9.3963 0.38591E-09 -9.4135 0.96116E+00 -0.0172 58 MgCO3,aq 0.14769E-09 -9.8307 0.14769E-09 -9.8307 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.71869E-09 -9.1435 0.69080E-09 -9.1606 0.96119E+00 -0.0172 60 MgCl+ 0.47096E-09 -9.3270 0.45268E-09 -9.3442 0.96119E+00 -0.0172 61 MgOH+ 0.18619E-07 -7.7301 0.17896E-07 -7.7472 0.96119E+00 -0.0172 63 MnO,aq 0.31048E-10 -10.5080 0.31048E-10 -10.5080 0.10000E+01 0.0000 64 MnOH+ 0.48544E-08 -8.3139 0.46660E-08 -8.3311 0.96119E+00 -0.0172 65 MnO2-2 0.44931E-18 -18.3475 0.40465E-18 -18.3929 0.90060E+00 -0.0455 66 HMnO2- 0.46987E-14 -14.3280 0.45162E-14 -14.3452 0.96116E+00 -0.0172 69 MnCl+ 0.65164E-10 -10.1860 0.62635E-10 -10.2032 0.96119E+00 -0.0172 70 MnSO4,aq 0.50292E-09 -9.2985 0.50292E-09 -9.2985 0.10000E+01 0.0000 71 NaCl,aq 0.69432E-08 -8.1584 0.69432E-08 -8.1584 0.10000E+01 0.0000 72 NaOH,aq 0.13679E-08 -8.8640 0.13679E-08 -8.8640 0.10000E+01 0.0000 74 OH- 0.12115E-04 -4.9167 0.11644E-04 -4.9339 0.96112E+00 -0.0172 79 HPO3-2 0.34202E-18 -18.4660 0.30802E-18 -18.5114 0.90060E+00 -0.0455 81 H2PO3- 0.32427E-19 -19.4891 0.31168E-19 -19.5063 0.96116E+00 -0.0172 82 H3PO4,aq 0.25596E-12 -12.5918 0.25596E-12 -12.5918 0.10000E+01 0.0000 83 H2PO4- 0.14078E-07 -7.8515 0.13532E-07 -7.8687 0.96117E+00 -0.0172 84 PO4-3 0.31414E-12 -12.5029 0.25402E-12 -12.5951 0.80861E+00 -0.0923 87 H2P2O7-2 0.15912E-16 -16.7983 0.14331E-16 -16.8437 0.90060E+00 -0.0455 88 HP2O7-3 0.70615E-16 -16.1511 0.57045E-16 -16.2438 0.80784E+00 -0.0927 89 P2O7-4 0.39353E-18 -18.4050 0.27320E-18 -18.5635 0.69422E+00 -0.1585 90 H2S,aq 0.16177E-07 -7.7911 0.16175E-07 -7.7911 0.99992E+00 0.0000 91 S2-2 0.40983E-16 -16.3874 0.36909E-16 -16.4329 0.90060E+00 -0.0455 96 SO2,aq 0.16453E-17 -17.7837 0.16453E-17 -17.7837 0.10000E+01 0.0000 97 SO3-2 0.22400E-13 -13.6498 0.20179E-13 -13.6951 0.90086E+00 -0.0453 98 HSO3- 0.63290E-13 -13.1987 0.60831E-13 -13.2159 0.96116E+00 -0.0172 99 HSO4- 0.11307E-08 -8.9467 0.10868E-08 -8.9638 0.96121E+00 -0.0172 101 S2O3-2 0.48132E-14 -14.3176 0.43348E-14 -14.3630 0.90060E+00 -0.0455 102 HS2O3- 0.41462E-19 -19.3823 0.39852E-19 -19.3996 0.96116E+00 -0.0172 Charge balance for all species = 0.9763E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5358814E-07 -.1572515E-04 -.1584975E-01 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9999819E+06 0.0000 3 Cl- 0.1379629E-03 0.1379745E-03 0.4891530E+01 3.4106 4 SO4-- 0.2524674E-04 0.2537801E-04 0.2437813E+01 9.9329 5 HCO3- 0.1185296E-04 0.1307003E-04 0.7974836E+00 2.3447 6 HS- 0.1087346E-06 0.1265091E-06 0.4183842E-02 0.3072 7 Al+++ 0.1332003E-18 0.9374999E-06 0.2529475E-01 2.8961 8 H4SiO4 0.5322857E-04 0.5428056E-04 0.5217113E+01 -4.2739 9 Ca++ 0.2050803E-04 0.2067981E-04 0.8287919E+00 9.8426 10 Mg++ 0.2620804E-05 0.2640829E-05 0.6420279E-01 8.9491 11 Fe++ 0.2437689E-07 0.3971365E-07 0.2217853E-02 6.9176 12 K+ 0.1146086E-05 0.1146499E-05 0.4482969E-01 1.3301 13 Na+ 0.1668388E-03 0.1668497E-03 0.3835779E+01 3.4932 14 Mn++ 0.8667148E-07 0.9212504E-07 0.5061084E-02 7.4685 15 HPO4-- 0.1663610E-07 0.3071490E-07 0.2947938E-02 6.7518 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7637598E-04 -.1572512E-04 -.6065087E-04 0.0000000E+00 2 H2O 0.5550818E+02 0.5550815E+02 0.3684977E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2565412E-04 0.2537796E-04 0.2761613E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1496524E-06 0.1265088E-06 -.2761613E-06 0.0000000E+00 7 Al+++ 0.1760800E-04 0.9374980E-06 0.1667051E-04 0.0000000E+00 8 H4SiO4 0.5622903E-04 0.5428045E-04 0.1948582E-05 0.0000000E+00 9 Ca++ 0.2068183E-04 0.2067976E-04 0.2066793E-08 0.0000000E+00 10 Mg++ 0.4285714E-05 0.2640823E-05 0.1644891E-05 0.0000000E+00 11 Fe++ 0.3850246E-05 0.3971357E-07 0.3810533E-05 0.0000000E+00 12 K+ 0.1146497E-05 0.1146497E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1668493E-03 0.1668493E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.9362842E-07 0.9212484E-07 0.1503575E-08 0.0000000E+00 15 HPO4-- 0.3195491E-07 0.3071484E-07 0.1240076E-08 0.0000000E+00 Chg. balance for solid moles: 0.1157E-20 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0054000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.3290E-06 -6.483 0.1829E-03 -3.738 12.11 0.6955E-04 daphnite 0.3202E-06 -6.495 0.2285E-03 -3.641 15.13 0.6924E-04 chlorite-Mn 0.3007E-09 -9.522 0.2132E-06 -6.671 0.1412E-01 0.6794E-07 diaspore 0.1537E-04 -4.813 0.9221E-03 -3.035 61.06 0.2745E-03 hematite 0.1105E-05 -5.957 0.1764E-03 -3.753 11.68 0.3344E-04 apatite-OH 0.4134E-09 -9.384 0.2076E-06 -6.683 0.1375E-01 0.6598E-07 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.5065E+00 0.5065E+00 1.0000 -0.295 daphnite 0.4930E+00 0.4930E+00 1.0000 -0.307 chlorite-Mn 0.4630E-03 0.4630E-03 1.0000 -3.334 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.001510 g Volume = 0.000447 cm3 Porosity: 99.9554% V(tot) - V(min): 0.10017E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0054000 g log = -2.2676 Original solution: 1000.0103000 g Original solution / Rock added: 185187.09 (Water/Rock Ratio), log = 5.2676 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1278E-03 1.0073 0.1354E-03 0.1345E-03 CH4,gas 0.7625E-10 1.0129 0.8126E-10 0.8022E-10 H2,gas 0.8480E-05 1.0006 0.8927E-05 0.8922E-05 H2S,gas 0.4503E-06 0.9959 0.4718E-06 0.4737E-06 S2,gas 0.9943E-22 1.0000 0.1046E-21 0.1046E-21 CO,gas 0.2977E-12 1.0000 0.3132E-12 0.3132E-12 SO3,gas 0.2144E-34 1.0000 0.2256E-34 0.2256E-34 SO2,gas 0.7241E-17 1.0000 0.7618E-17 0.7618E-17 HCl,gas 0.2156E-14 1.0000 0.2269E-14 0.2269E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.23 -5.87 -1.956 0.10020E+05 -3.868 3 CH4,gas 4.81 -7.28 -12.09 -3.023 0.20644E+05 -10.090 4 H2,gas 8.29 1.24 -7.05 -4.028 0.12036E+05 -5.049 5 H2S,gas -5.94 -14.27 -8.33 -4.163 0.14217E+05 -6.326 6 S2,gas -7.03 -31.01 -23.98 -3.689 0.40946E+05 -21.980 7 CO,gas 3.51 -10.99 -14.50 -4.463 0.24765E+05 -12.504 8 SO3,gas 17.43 -19.22 -36.65 -9.162 0.62573E+05 -34.647 9 SO2,gas 1.14 -17.98 -19.12 -5.098 0.32644E+05 -17.118 10 HCl,gas 5.48 -11.17 -16.64 -8.322 0.28420E+05 -14.644 21 andalusite 5.06 1.52 -3.54 -0.354 0.60514E+04 24 anhydrite -5.28 -9.38 -4.10 -2.049 0.69957E+04 35 aragonite 0.99 -2.39 -3.38 -1.125 0.57629E+04 36 brucite 12.58 8.95 -3.63 -0.726 0.61939E+04 37 calcite 0.83 -2.39 -3.22 -1.074 0.55015E+04 40 carpholite-Mg 8.65 6.19 -2.46 -0.164 0.41950E+04 41 carpholite-Fe 6.78 4.16 -2.62 -0.175 0.44750E+04 50 chloritoid-Mg 13.26 10.47 -2.79 -0.186 0.47704E+04 51 chloritoid-Fe 9.24 8.44 -0.80 -0.054 0.13707E+04 52 chloritoid-Mn 11.46 8.99 -2.48 -0.165 0.42283E+04 54 coesite -2.37 -4.27 -1.90 -0.635 0.32519E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.27 -1.72 -0.575 0.29448E+04 78 fayalite 14.08 9.56 -4.52 -0.645 0.77137E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.21 -3.99 -0.332 0.68112E+04 92 hercynite 17.34 12.71 -4.63 -0.309 0.79137E+04 98 kaolinite -1.27 -2.76 -1.48 -0.135 0.25311E+04 99 kyanite 4.93 1.52 -3.41 -0.341 0.58281E+04 101 laumontite 2.97 -1.46 -4.44 -0.296 0.75730E+04 102 lawsonite 9.68 7.09 -2.59 -0.173 0.44246E+04 105 lizardite 23.29 18.30 -4.99 -0.416 0.85168E+04 106 magnesite 0.71 -3.28 -3.99 -1.331 0.68157E+04 107 magnetite 20.13 19.52 -0.62 -0.050 0.10545E+04 110 magnesioferrite 26.26 21.55 -4.71 -0.385 0.80432E+04 113 margarite 17.45 12.88 -4.57 -0.183 0.78075E+04 121 paragonite 4.34 -0.64 -4.98 -0.293 0.84977E+04 128 periclase-Fe 11.64 6.92 -4.72 -1.180 0.80619E+04 142 pyrite -21.23 -22.86 -1.63 -0.384 0.27875E+04 143 pyrrhotite -4.24 -7.35 -3.11 -1.036 0.53064E+04 144 pyrrhotiteFe0.875 -6.00 -8.37 -2.37 -0.871 0.40441E+04 145 pyroxmangite 7.42 3.19 -4.22 -0.844 0.72079E+04 147 quartz -2.98 -4.27 -1.29 -0.431 0.22058E+04 152 rhodochrosite -0.96 -4.76 -3.80 -1.268 0.64959E+04 153 rhodonite 7.46 3.19 -4.27 -0.854 0.72871E+04 156 siderite -2.59 -5.31 -2.73 -0.909 0.46549E+04 157 sillimanite 5.32 1.52 -3.80 -0.380 0.64936E+04 169 sudoite 21.22 16.66 -4.56 -0.147 0.77780E+04 178 topaz-H 4.67 1.52 -3.15 -0.286 0.53772E+04 179 tridymite -2.61 -4.27 -1.66 -0.553 0.28331E+04 182 troilite-low -4.39 -7.35 -2.96 -0.986 0.50496E+04 190 wollastonite 10.48 5.57 -4.91 -0.983 0.83890E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.27 -1.48 -0.493 0.25261E+04 206 nontronite-Ca 3.28 -0.51 -3.79 -0.246 0.64668E+04 207 nontronite-H 2.60 -2.13 -4.73 -0.317 0.80720E+04 209 nontronite-Mg 3.14 -0.66 -3.79 -0.246 0.64788E+04 210 nontronite-Na 3.58 -0.98 -4.56 -0.293 0.77891E+04 215 gypsum -4.92 -9.38 -4.45 -1.113 0.76024E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.92 -2.91 -0.727 0.49630E+04 241 silica-amorphous -2.08 -4.27 -2.19 -0.731 0.37463E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0054000 g New total amount of reactant added: 0.0056000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.9763E-15 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0056000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2619390E-03 Osmotic coef. = 0.9903 True ionic strength = .2636317E-03 Chg. balance for total moles = 0.9763E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.52317E-07 -7.2814 0.50290E-07 -7.2985 0.96125E+00 -0.0172 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13260E-03 -3.8775 0.96114E+00 -0.0172 4 SO4-- 0.25269E-04 -4.5974 0.22756E-04 -4.6429 0.90057E+00 -0.0455 5 HCO3- 0.11878E-04 -4.9253 0.11417E-04 -4.9425 0.96116E+00 -0.0172 6 HS- 0.88331E-07 -7.0539 0.84898E-07 -7.0711 0.96114E+00 -0.0172 7 Al+++ 0.12396E-18 -18.9067 0.10012E-18 -18.9995 0.80768E+00 -0.0928 8 H4SiO4 0.54887E-04 -4.2605 0.54887E-04 -4.2605 0.10000E+01 0.0000 9 Ca++ 0.20730E-04 -4.6834 0.18666E-04 -4.7289 0.90044E+00 -0.0455 10 Mg++ 0.24634E-05 -5.6085 0.22179E-05 -5.6541 0.90036E+00 -0.0456 11 Fe++ 0.22705E-07 -7.6439 0.20443E-07 -7.6895 0.90038E+00 -0.0456 12 K+ 0.11885E-05 -5.9250 0.11424E-05 -5.9422 0.96117E+00 -0.0172 13 Na+ 0.16709E-03 -3.7771 0.16060E-03 -3.7943 0.96113E+00 -0.0172 14 Mn++ 0.89381E-07 -7.0488 0.80478E-07 -7.0943 0.90039E+00 -0.0456 15 HPO4-- 0.15828E-07 -7.8006 0.14254E-07 -7.8461 0.90057E+00 -0.0455 16 HSiO3- 0.11079E-05 -5.9555 0.10649E-05 -5.9727 0.96114E+00 -0.0172 17 Ca(HSiO3)+ 0.46334E-09 -9.3341 0.44535E-09 -9.3513 0.96117E+00 -0.0172 18 Mg(HSiO3)+ 0.68515E-10 -10.1642 0.65855E-10 -10.1814 0.96117E+00 -0.0172 19 NaHSiO3,aq 0.27161E-08 -8.5661 0.27161E-08 -8.5661 0.10000E+01 0.0000 20 AlO+ 0.53171E-11 -11.2743 0.51107E-11 -11.2915 0.96117E+00 -0.0172 21 AlOH+2 0.14299E-14 -14.8447 0.12875E-14 -14.8903 0.90041E+00 -0.0456 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.93948E-06 -6.0271 0.90294E-06 -6.0443 0.96110E+00 -0.0172 24 CH4,aq 0.41798E-13 -13.3788 0.41794E-13 -13.3789 0.99992E+00 0.0000 29 CO,aq 0.18529E-15 -15.7321 0.18529E-15 -15.7321 0.10000E+01 0.0000 30 CO2,aq 0.11577E-05 -5.9364 0.11576E-05 -5.9365 0.99992E+00 0.0000 31 CO3-2 0.23308E-07 -7.6325 0.20990E-07 -7.6780 0.90053E+00 -0.0455 32 CaCO3,aq 0.47987E-08 -8.3189 0.47987E-08 -8.3189 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.55866E-08 -8.2529 0.53696E-08 -8.2701 0.96117E+00 -0.0172 34 CaCl+ 0.41035E-08 -8.3868 0.39442E-08 -8.4040 0.96117E+00 -0.0172 35 CaCl2,aq 0.12177E-12 -12.9144 0.12177E-12 -12.9144 0.10000E+01 0.0000 36 CaOH+ 0.27230E-07 -7.5650 0.26173E-07 -7.5821 0.96117E+00 -0.0172 37 CaSO4,aq 0.13235E-06 -6.8783 0.13235E-06 -6.8783 0.10000E+01 0.0000 38 HCl,aq 0.12543E-11 -11.9016 0.12543E-11 -11.9016 0.10000E+01 0.0000 43 FeCl+ 0.43926E-11 -11.3573 0.42221E-11 -11.3745 0.96117E+00 -0.0172 44 FeCl2,aq 0.17364E-19 -19.7604 0.17364E-19 -19.7604 0.10000E+01 0.0000 46 FeO,aq 0.31965E-09 -9.4953 0.31965E-09 -9.4953 0.10000E+01 0.0000 47 FeOH+ 0.14021E-07 -7.8532 0.13477E-07 -7.8704 0.96117E+00 -0.0172 48 HFeO2- 0.71132E-10 -10.1479 0.68367E-10 -10.1652 0.96114E+00 -0.0172 49 FeO+ 0.43281E-12 -12.3637 0.41600E-12 -12.3809 0.96117E+00 -0.0172 50 FeOH+2 0.43235E-17 -17.3642 0.38929E-17 -17.4097 0.90041E+00 -0.0456 51 FeO2- 0.33636E-10 -10.4732 0.32329E-10 -10.4904 0.96114E+00 -0.0172 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.62155E-08 -8.2065 0.62150E-08 -8.2066 0.99992E+00 0.0000 54 KCl,aq 0.26822E-11 -11.5715 0.26822E-11 -11.5715 0.10000E+01 0.0000 55 KHSO4,aq 0.34984E-17 -17.4561 0.34984E-17 -17.4561 0.10000E+01 0.0000 56 KOH,aq 0.99030E-11 -11.0042 0.99030E-11 -11.0042 0.10000E+01 0.0000 57 KSO4- 0.41671E-09 -9.3802 0.40051E-09 -9.3974 0.96114E+00 -0.0172 58 MgCO3,aq 0.14247E-09 -9.8463 0.14247E-09 -9.8463 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.67689E-09 -9.1695 0.65060E-09 -9.1867 0.96117E+00 -0.0172 60 MgCl+ 0.44263E-09 -9.3540 0.42545E-09 -9.3712 0.96117E+00 -0.0172 61 MgOH+ 0.17925E-07 -7.7465 0.17229E-07 -7.7637 0.96117E+00 -0.0172 63 MnO,aq 0.33592E-10 -10.4738 0.33592E-10 -10.4738 0.10000E+01 0.0000 64 MnOH+ 0.51276E-08 -8.2901 0.49285E-08 -8.3073 0.96117E+00 -0.0172 65 MnO2-2 0.51010E-18 -18.2923 0.45936E-18 -18.3378 0.90053E+00 -0.0455 66 HMnO2- 0.52075E-14 -14.2834 0.50051E-14 -14.3006 0.96114E+00 -0.0172 69 MnCl+ 0.67196E-10 -10.1727 0.64587E-10 -10.1899 0.96117E+00 -0.0172 70 MnSO4,aq 0.51902E-09 -9.2848 0.51902E-09 -9.2848 0.10000E+01 0.0000 71 NaCl,aq 0.69534E-08 -8.1578 0.69534E-08 -8.1578 0.10000E+01 0.0000 72 NaOH,aq 0.14032E-08 -8.8529 0.14032E-08 -8.8529 0.10000E+01 0.0000 74 OH- 0.12410E-04 -4.9062 0.11928E-04 -4.9234 0.96110E+00 -0.0172 79 HPO3-2 0.31073E-18 -18.5076 0.27982E-18 -18.5531 0.90053E+00 -0.0455 81 H2PO3- 0.28760E-19 -19.5412 0.27642E-19 -19.5584 0.96114E+00 -0.0172 82 H3PO4,aq 0.23209E-12 -12.6343 0.23209E-12 -12.6343 0.10000E+01 0.0000 83 H2PO4- 0.13076E-07 -7.8835 0.12568E-07 -7.9007 0.96115E+00 -0.0172 84 PO4-3 0.30618E-12 -12.5140 0.24754E-12 -12.6064 0.80846E+00 -0.0923 87 H2P2O7-2 0.13727E-16 -16.8624 0.12362E-16 -16.9079 0.90053E+00 -0.0455 88 HP2O7-3 0.62406E-16 -16.2048 0.50405E-16 -16.2975 0.80769E+00 -0.0928 89 P2O7-4 0.35629E-18 -18.4482 0.24726E-18 -18.6068 0.69399E+00 -0.1586 90 H2S,aq 0.12829E-07 -7.8918 0.12828E-07 -7.8918 0.99992E+00 0.0000 91 S2-2 0.28324E-16 -16.5478 0.25507E-16 -16.5933 0.90053E+00 -0.0455 96 SO2,aq 0.14986E-17 -17.8243 0.14986E-17 -17.8243 0.10000E+01 0.0000 97 SO3-2 0.21408E-13 -13.6694 0.19284E-13 -13.7148 0.90078E+00 -0.0454 98 HSO3- 0.59049E-13 -13.2288 0.56754E-13 -13.2460 0.96114E+00 -0.0172 99 HSO4- 0.11047E-08 -8.9567 0.10619E-08 -8.9739 0.96119E+00 -0.0172 101 S2O3-2 0.38205E-14 -14.4179 0.34404E-14 -14.4634 0.90053E+00 -0.0455 102 HS2O3- 0.32127E-19 -19.4931 0.30879E-19 -19.5103 0.96114E+00 -0.0172 Charge balance for all species = 0.9763E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5231695E-07 -.1620041E-04 -.1632878E-01 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9999817E+06 0.0000 3 Cl- 0.1379629E-03 0.1379745E-03 0.4891529E+01 3.4211 4 SO4-- 0.2526897E-04 0.2540184E-04 0.2440102E+01 9.9541 5 HCO3- 0.1187785E-04 0.1307003E-04 0.7974835E+00 2.3561 6 HS- 0.8833108E-07 0.1026844E-06 0.3395922E-02 0.2274 7 Al+++ 0.1239596E-18 0.9598235E-06 0.2589706E-01 2.8961 8 H4SiO4 0.5488680E-04 0.5599796E-04 0.5382179E+01 -4.2605 9 Ca++ 0.2073031E-04 0.2090485E-04 0.8378108E+00 9.8681 10 Mg++ 0.2463378E-05 0.2482633E-05 0.6035680E-01 8.9430 11 Fe++ 0.2270503E-07 0.3735891E-07 0.2086349E-02 6.9076 12 K+ 0.1188533E-05 0.1188962E-05 0.4649004E-01 1.3563 13 Na+ 0.1670897E-03 0.1671007E-03 0.3841550E+01 3.5043 14 Mn++ 0.8938138E-07 0.9512882E-07 0.5226102E-02 7.5027 15 HPO4-- 0.1582816E-07 0.2890440E-07 0.2774170E-02 6.7510 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7968769E-04 -.1620038E-04 -.6348731E-04 0.0000000E+00 2 H2O 0.5550818E+02 0.5550814E+02 0.3820760E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2565967E-04 0.2540179E-04 0.2578792E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1551951E-06 0.1026841E-06 -.2578792E-06 0.0000000E+00 7 Al+++ 0.1826015E-04 0.9598214E-06 0.1730033E-04 0.0000000E+00 8 H4SiO4 0.5831158E-04 0.5599784E-04 0.2313744E-05 0.0000000E+00 9 Ca++ 0.2091186E-04 0.2090480E-04 0.7056821E-08 0.0000000E+00 10 Mg++ 0.4444444E-05 0.2482628E-05 0.1961817E-05 0.0000000E+00 11 Fe++ 0.3992848E-05 0.3735883E-07 0.3955489E-05 0.0000000E+00 12 K+ 0.1188960E-05 0.1188960E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1671004E-03 0.1671004E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.9709614E-07 0.9512861E-07 0.1967526E-08 0.0000000E+00 15 HPO4-- 0.3313843E-07 0.2890434E-07 0.4234092E-08 0.0000000E+00 Chg. balance for solid moles: -.3130E-20 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0056000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1411E-08 -8.850 0.7090E-06 -6.149 0.4433E-01 0.2253E-06 clinochlore 0.3924E-06 -6.406 0.2181E-03 -3.661 13.64 0.8295E-04 daphnite 0.3785E-06 -6.422 0.2701E-03 -3.569 16.89 0.8184E-04 chlorite-Mn 0.3935E-09 -9.405 0.2790E-06 -6.554 0.1745E-01 0.8890E-07 diaspore 0.1576E-04 -4.803 0.9453E-03 -3.024 59.11 0.2814E-03 hematite 0.1032E-05 -5.987 0.1647E-03 -3.783 10.30 0.3122E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5087E+00 0.5087E+00 1.0000 -0.294 daphnite 0.4908E+00 0.4908E+00 1.0000 -0.309 chlorite-Mn 0.5102E-03 0.5102E-03 1.0000 -3.292 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.001599 g Volume = 0.000478 cm3 Porosity: 99.9523% V(tot) - V(min): 0.10018E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0056000 g log = -2.2518 Original solution: 1000.0103000 g Original solution / Rock added: 178573.27 (Water/Rock Ratio), log = 5.2518 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1250E-03 1.0073 0.1325E-03 0.1315E-03 CH4,gas 0.6202E-10 1.0129 0.6609E-10 0.6525E-10 H2,gas 0.8098E-05 1.0006 0.8524E-05 0.8520E-05 H2S,gas 0.3571E-06 0.9959 0.3741E-06 0.3757E-06 S2,gas 0.6858E-22 1.0000 0.7215E-22 0.7215E-22 CO,gas 0.2781E-12 1.0000 0.2926E-12 0.2926E-12 SO3,gas 0.2045E-34 1.0000 0.2152E-34 0.2152E-34 SO2,gas 0.6595E-17 1.0000 0.6938E-17 0.6938E-17 HCl,gas 0.2105E-14 1.0000 0.2215E-14 0.2215E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.24 -5.88 -1.959 0.10036E+05 -3.878 3 CH4,gas 4.81 -7.37 -12.18 -3.045 0.20797E+05 -10.180 4 H2,gas 8.29 1.22 -7.07 -4.040 0.12071E+05 -5.069 5 H2S,gas -5.94 -14.37 -8.43 -4.213 0.14389E+05 -6.427 6 S2,gas -7.03 -31.17 -24.14 -3.714 0.41221E+05 -22.142 7 CO,gas 3.51 -11.02 -14.53 -4.472 0.24816E+05 -12.534 8 SO3,gas 17.43 -19.24 -36.67 -9.167 0.62608E+05 -34.667 9 SO2,gas 1.14 -18.02 -19.16 -5.109 0.32713E+05 -17.159 10 HCl,gas 5.48 -11.18 -16.65 -8.327 0.28437E+05 -14.655 21 andalusite 5.06 1.53 -3.53 -0.353 0.60286E+04 24 anhydrite -5.28 -9.37 -4.09 -2.046 0.69871E+04 35 aragonite 0.99 -2.37 -3.36 -1.120 0.57356E+04 36 brucite 12.58 8.94 -3.63 -0.727 0.62043E+04 37 calcite 0.83 -2.37 -3.21 -1.069 0.54742E+04 40 carpholite-Mg 8.65 6.21 -2.44 -0.162 0.41599E+04 41 carpholite-Fe 6.78 4.18 -2.60 -0.174 0.44466E+04 50 chloritoid-Mg 13.26 10.47 -2.79 -0.186 0.47580E+04 51 chloritoid-Fe 9.24 8.44 -0.80 -0.053 0.13650E+04 52 chloritoid-Mn 11.46 9.03 -2.43 -0.162 0.41472E+04 54 coesite -2.37 -4.26 -1.89 -0.630 0.32291E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.26 -1.71 -0.570 0.29220E+04 78 fayalite 14.08 9.55 -4.52 -0.646 0.77251E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.20 -3.99 -0.333 0.68171E+04 92 hercynite 17.34 12.70 -4.64 -0.310 0.79308E+04 98 kaolinite -1.27 -2.73 -1.46 -0.132 0.24856E+04 99 kyanite 4.93 1.53 -3.40 -0.340 0.58054E+04 101 laumontite 2.97 -1.38 -4.36 -0.290 0.74384E+04 102 lawsonite 9.68 7.14 -2.54 -0.169 0.43355E+04 105 lizardite 23.29 18.31 -4.98 -0.415 0.85024E+04 106 magnesite 0.71 -3.30 -4.01 -1.336 0.68424E+04 107 magnetite 20.13 19.51 -0.63 -0.051 0.10716E+04 110 magnesioferrite 26.26 21.54 -4.72 -0.385 0.80536E+04 113 margarite 17.45 12.93 -4.52 -0.181 0.77185E+04 121 paragonite 4.34 -0.59 -4.93 -0.290 0.84105E+04 128 periclase-Fe 11.64 6.91 -4.73 -1.183 0.80790E+04 142 pyrite -21.23 -23.05 -1.82 -0.429 0.31142E+04 143 pyrrhotite -4.24 -7.46 -3.22 -1.073 0.54954E+04 144 pyrrhotiteFe0.875 -6.00 -8.48 -2.48 -0.910 0.42268E+04 145 pyroxmangite 7.42 3.24 -4.17 -0.835 0.71267E+04 147 quartz -2.98 -4.26 -1.28 -0.426 0.21831E+04 152 rhodochrosite -0.96 -4.74 -3.78 -1.260 0.64538E+04 153 rhodonite 7.46 3.24 -4.22 -0.844 0.72060E+04 156 siderite -2.59 -5.33 -2.75 -0.915 0.46883E+04 157 sillimanite 5.32 1.53 -3.79 -0.379 0.64708E+04 169 sudoite 21.22 16.69 -4.53 -0.146 0.77305E+04 178 topaz-H 4.67 1.53 -3.14 -0.285 0.53545E+04 179 tridymite -2.61 -4.26 -1.65 -0.549 0.28104E+04 182 troilite-low -4.39 -7.46 -3.07 -1.023 0.52386E+04 190 wollastonite 10.48 5.61 -4.87 -0.975 0.83226E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.26 -1.47 -0.489 0.25034E+04 206 nontronite-Ca 3.28 -0.45 -3.73 -0.242 0.63761E+04 207 nontronite-H 2.60 -2.08 -4.68 -0.314 0.79885E+04 209 nontronite-Mg 3.14 -0.61 -3.75 -0.243 0.63970E+04 210 nontronite-Na 3.58 -0.93 -4.51 -0.289 0.76994E+04 215 gypsum -4.92 -9.37 -4.45 -1.112 0.75939E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.91 -2.92 -0.729 0.49801E+04 241 silica-amorphous -2.08 -4.26 -2.18 -0.727 0.37236E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0056000 g New total amount of reactant added: 0.0058000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.9763E-15 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0058000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2623772E-03 Osmotic coef. = 0.9903 True ionic strength = .2641727E-03 Chg. balance for total moles = 0.9763E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.51027E-07 -7.2922 0.49048E-07 -7.3094 0.96123E+00 -0.0172 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13260E-03 -3.8775 0.96111E+00 -0.0172 4 SO4-- 0.25288E-04 -4.5971 0.22772E-04 -4.6426 0.90049E+00 -0.0455 5 HCO3- 0.11903E-04 -4.9243 0.11441E-04 -4.9415 0.96114E+00 -0.0172 6 HS- 0.70578E-07 -7.1513 0.67833E-07 -7.1686 0.96112E+00 -0.0172 7 Al+++ 0.11503E-18 -18.9392 0.92887E-19 -19.0320 0.80752E+00 -0.0928 8 H4SiO4 0.56563E-04 -4.2475 0.56563E-04 -4.2475 0.10000E+01 0.0000 9 Ca++ 0.20953E-04 -4.6788 0.18865E-04 -4.7243 0.90036E+00 -0.0456 10 Mg++ 0.23167E-05 -5.6351 0.20857E-05 -5.6807 0.90028E+00 -0.0456 11 Fe++ 0.21066E-07 -7.6764 0.18966E-07 -7.7220 0.90030E+00 -0.0456 12 K+ 0.12310E-05 -5.9097 0.11832E-05 -5.9270 0.96115E+00 -0.0172 13 Na+ 0.16734E-03 -3.7764 0.16083E-03 -3.7936 0.96111E+00 -0.0172 14 Mn++ 0.92022E-07 -7.0361 0.82848E-07 -7.0817 0.90031E+00 -0.0456 15 HPO4-- 0.15043E-07 -7.8227 0.13546E-07 -7.8682 0.90049E+00 -0.0455 16 HSiO3- 0.11707E-05 -5.9316 0.11251E-05 -5.9488 0.96111E+00 -0.0172 17 Ca(HSiO3)+ 0.49479E-09 -9.3056 0.47557E-09 -9.3228 0.96115E+00 -0.0172 18 Mg(HSiO3)+ 0.68080E-10 -10.1670 0.65435E-10 -10.1842 0.96115E+00 -0.0172 19 NaHSiO3,aq 0.28741E-08 -8.5415 0.28741E-08 -8.5415 0.10000E+01 0.0000 20 AlO+ 0.51860E-11 -11.2852 0.49845E-11 -11.3024 0.96115E+00 -0.0172 21 AlOH+2 0.13603E-14 -14.8664 0.12247E-14 -14.9120 0.90033E+00 -0.0456 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.96328E-06 -6.0162 0.92579E-06 -6.0335 0.96108E+00 -0.0172 24 CH4,aq 0.33444E-13 -13.4757 0.33441E-13 -13.4757 0.99992E+00 0.0000 29 CO,aq 0.17226E-15 -15.7638 0.17226E-15 -15.7638 0.10000E+01 0.0000 30 CO2,aq 0.11315E-05 -5.9464 0.11314E-05 -5.9464 0.99992E+00 0.0000 31 CO3-2 0.23951E-07 -7.6207 0.21566E-07 -7.6662 0.90045E+00 -0.0455 32 CaCO3,aq 0.49829E-08 -8.3025 0.49829E-08 -8.3025 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.56580E-08 -8.2473 0.54382E-08 -8.2645 0.96115E+00 -0.0172 34 CaCl+ 0.41472E-08 -8.3822 0.39860E-08 -8.3995 0.96115E+00 -0.0172 35 CaCl2,aq 0.12306E-12 -12.9099 0.12306E-12 -12.9099 0.10000E+01 0.0000 36 CaOH+ 0.28217E-07 -7.5495 0.27121E-07 -7.5667 0.96115E+00 -0.0172 37 CaSO4,aq 0.13385E-06 -6.8734 0.13385E-06 -6.8734 0.10000E+01 0.0000 38 HCl,aq 0.12233E-11 -11.9125 0.12233E-11 -11.9125 0.10000E+01 0.0000 43 FeCl+ 0.40752E-11 -11.3898 0.39169E-11 -11.4071 0.96115E+00 -0.0172 44 FeCl2,aq 0.16108E-19 -19.7930 0.16108E-19 -19.7930 0.10000E+01 0.0000 46 FeO,aq 0.31175E-09 -9.5062 0.31175E-09 -9.5062 0.10000E+01 0.0000 47 FeOH+ 0.13338E-07 -7.8749 0.12819E-07 -7.8921 0.96115E+00 -0.0172 48 HFeO2- 0.71132E-10 -10.1479 0.68366E-10 -10.1652 0.96111E+00 -0.0172 49 FeO+ 0.42213E-12 -12.3746 0.40573E-12 -12.3918 0.96115E+00 -0.0172 50 FeOH+2 0.41130E-17 -17.3858 0.37031E-17 -17.4314 0.90033E+00 -0.0456 51 FeO2- 0.34488E-10 -10.4623 0.33147E-10 -10.4796 0.96111E+00 -0.0172 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.59123E-08 -8.2282 0.59118E-08 -8.2283 0.99992E+00 0.0000 54 KCl,aq 0.27779E-11 -11.5563 0.27779E-11 -11.5563 0.10000E+01 0.0000 55 KHSO4,aq 0.35362E-17 -17.4515 0.35362E-17 -17.4515 0.10000E+01 0.0000 56 KOH,aq 0.10516E-10 -10.9781 0.10516E-10 -10.9781 0.10000E+01 0.0000 57 KSO4- 0.43188E-09 -9.3646 0.41508E-09 -9.3819 0.96111E+00 -0.0172 58 MgCO3,aq 0.13766E-09 -9.8612 0.13766E-09 -9.8612 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.63789E-09 -9.1953 0.61311E-09 -9.2125 0.96115E+00 -0.0172 60 MgCl+ 0.41624E-09 -9.3807 0.40007E-09 -9.3979 0.96115E+00 -0.0172 61 MgOH+ 0.17283E-07 -7.7624 0.16612E-07 -7.7796 0.96115E+00 -0.0172 63 MnO,aq 0.36354E-10 -10.4394 0.36354E-10 -10.4394 0.10000E+01 0.0000 64 MnOH+ 0.54123E-08 -8.2666 0.52021E-08 -8.2838 0.96115E+00 -0.0172 65 MnO2-2 0.58038E-18 -18.2363 0.52261E-18 -18.2818 0.90045E+00 -0.0455 66 HMnO2- 0.57784E-14 -14.2382 0.55537E-14 -14.2554 0.96111E+00 -0.0172 69 MnCl+ 0.69175E-10 -10.1601 0.66487E-10 -10.1773 0.96115E+00 -0.0172 70 MnSO4,aq 0.53466E-09 -9.2719 0.53466E-09 -9.2719 0.10000E+01 0.0000 71 NaCl,aq 0.69635E-08 -8.1572 0.69635E-08 -8.1572 0.10000E+01 0.0000 72 NaOH,aq 0.14409E-08 -8.8414 0.14409E-08 -8.8414 0.10000E+01 0.0000 74 OH- 0.12725E-04 -4.8954 0.12229E-04 -4.9126 0.96108E+00 -0.0172 79 HPO3-2 0.28091E-18 -18.5514 0.25294E-18 -18.5970 0.90045E+00 -0.0455 81 H2PO3- 0.25356E-19 -19.5959 0.24370E-19 -19.6131 0.96111E+00 -0.0172 82 H3PO4,aq 0.20980E-12 -12.6782 0.20980E-12 -12.6782 0.10000E+01 0.0000 83 H2PO4- 0.12120E-07 -7.9165 0.11649E-07 -7.9337 0.96113E+00 -0.0172 84 PO4-3 0.29839E-12 -12.5252 0.24119E-12 -12.6176 0.80830E+00 -0.0924 87 H2P2O7-2 0.11794E-16 -16.9284 0.10620E-16 -16.9739 0.90045E+00 -0.0455 88 HP2O7-3 0.54979E-16 -16.2598 0.44397E-16 -16.3526 0.80753E+00 -0.0928 89 P2O7-4 0.32188E-18 -18.4923 0.22330E-18 -18.6511 0.69375E+00 -0.1588 90 H2S,aq 0.99973E-08 -8.0001 0.99965E-08 -8.0002 0.99992E+00 0.0000 91 S2-2 0.19011E-16 -16.7210 0.17118E-16 -16.7665 0.90045E+00 -0.0455 96 SO2,aq 0.13569E-17 -17.8675 0.13569E-17 -17.8675 0.10000E+01 0.0000 97 SO3-2 0.20379E-13 -13.6908 0.18356E-13 -13.7362 0.90071E+00 -0.0454 98 HSO3- 0.54819E-13 -13.2611 0.52687E-13 -13.2783 0.96111E+00 -0.0172 99 HSO4- 0.10782E-08 -8.9673 0.10363E-08 -8.9845 0.96117E+00 -0.0172 101 S2O3-2 0.29794E-14 -14.5259 0.26828E-14 -14.5714 0.90045E+00 -0.0455 102 HS2O3- 0.24435E-19 -19.6120 0.23485E-19 -19.6292 0.96111E+00 -0.0172 Charge balance for all species = 0.9763E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5102666E-07 -.1670494E-04 -.1683730E-01 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9999815E+06 0.0000 3 Cl- 0.1379629E-03 0.1379745E-03 0.4891529E+01 3.4319 4 SO4-- 0.2528806E-04 0.2542250E-04 0.2442086E+01 9.9761 5 HCO3- 0.1190319E-04 0.1307003E-04 0.7974834E+00 2.3678 6 HS- 0.7057752E-07 0.8202314E-07 0.2712625E-02 0.1408 7 Al+++ 0.1150274E-18 0.9836218E-06 0.2653915E-01 2.8961 8 H4SiO4 0.5656292E-04 0.5773703E-04 0.5549326E+01 -4.2475 9 Ca++ 0.2095265E-04 0.2113000E-04 0.8468343E+00 9.8944 10 Mg++ 0.2316720E-05 0.2335263E-05 0.5677398E-01 8.9380 11 Fe++ 0.2106634E-07 0.3502928E-07 0.1956248E-02 6.8967 12 K+ 0.1230980E-05 0.1231425E-05 0.4815040E-01 1.3824 13 Na+ 0.1673405E-03 0.1673518E-03 0.3847321E+01 3.5158 14 Mn++ 0.9202160E-07 0.9807413E-07 0.5387908E-02 7.5370 15 HPO4-- 0.1504306E-07 0.2716316E-07 0.2607050E-02 6.7506 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8299939E-04 -.1670491E-04 -.6629448E-04 0.0000000E+00 2 H2O 0.5550818E+02 0.5550814E+02 0.3957333E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2566521E-04 0.2542245E-04 0.2427607E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1607378E-06 0.8202296E-07 -.2427607E-06 0.0000000E+00 7 Al+++ 0.1891230E-04 0.9836196E-06 0.1792868E-04 0.0000000E+00 8 H4SiO4 0.6039414E-04 0.5773690E-04 0.2657245E-05 0.0000000E+00 9 Ca++ 0.2114189E-04 0.2112996E-04 0.1193140E-07 0.0000000E+00 10 Mg++ 0.4603175E-05 0.2335258E-05 0.2267917E-05 0.0000000E+00 11 Fe++ 0.4135450E-05 0.3502920E-07 0.4100421E-05 0.0000000E+00 12 K+ 0.1231423E-05 0.1231423E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1673514E-03 0.1673514E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1005639E-06 0.9807391E-07 0.2489943E-08 0.0000000E+00 15 HPO4-- 0.3432194E-07 0.2716310E-07 0.7158842E-08 0.0000000E+00 Chg. balance for solid moles: -.6245E-20 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0058000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2386E-08 -8.622 0.1199E-05 -5.921 0.7110E-01 0.3809E-06 clinochlore 0.4536E-06 -6.343 0.2521E-03 -3.598 14.95 0.9590E-04 daphnite 0.4317E-06 -6.365 0.3080E-03 -3.511 18.27 0.9333E-04 chlorite-Mn 0.4980E-09 -9.303 0.3531E-06 -6.452 0.2094E-01 0.1125E-06 diaspore 0.1616E-04 -4.792 0.9693E-03 -3.014 57.49 0.2886E-03 hematite 0.9710E-06 -6.013 0.1551E-03 -3.809 9.198 0.2939E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5121E+00 0.5121E+00 1.0000 -0.291 daphnite 0.4873E+00 0.4873E+00 1.0000 -0.312 chlorite-Mn 0.5622E-03 0.5622E-03 1.0000 -3.250 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.001686 g Volume = 0.000508 cm3 Porosity: 99.9493% V(tot) - V(min): 0.10018E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0058000 g log = -2.2366 Original solution: 1000.0103000 g Original solution / Rock added: 172415.57 (Water/Rock Ratio), log = 5.2366 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1222E-03 1.0073 0.1295E-03 0.1286E-03 CH4,gas 0.4962E-10 1.0129 0.5288E-10 0.5221E-10 H2,gas 0.7703E-05 1.0006 0.8109E-05 0.8104E-05 H2S,gas 0.2783E-06 0.9959 0.2916E-06 0.2927E-06 S2,gas 0.4603E-22 1.0000 0.4842E-22 0.4842E-22 CO,gas 0.2585E-12 1.0000 0.2720E-12 0.2720E-12 SO3,gas 0.1947E-34 1.0000 0.2048E-34 0.2048E-34 SO2,gas 0.5971E-17 1.0000 0.6282E-17 0.6282E-17 HCl,gas 0.2053E-14 1.0000 0.2160E-14 0.2160E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.25 -5.89 -1.963 0.10053E+05 -3.888 3 CH4,gas 4.81 -7.47 -12.28 -3.069 0.20962E+05 -10.277 4 H2,gas 8.29 1.20 -7.09 -4.052 0.12108E+05 -5.091 5 H2S,gas -5.94 -14.48 -8.54 -4.268 0.14574E+05 -6.535 6 S2,gas -7.03 -31.35 -24.31 -3.741 0.41517E+05 -22.315 7 CO,gas 3.51 -11.06 -14.57 -4.482 0.24870E+05 -12.565 8 SO3,gas 17.43 -19.26 -36.69 -9.172 0.62645E+05 -34.689 9 SO2,gas 1.14 -18.07 -19.20 -5.121 0.32787E+05 -17.202 10 HCl,gas 5.48 -11.19 -16.67 -8.333 0.28456E+05 -14.666 21 andalusite 5.06 1.54 -3.52 -0.352 0.60063E+04 24 anhydrite -5.28 -9.37 -4.09 -2.044 0.69788E+04 35 aragonite 0.99 -2.36 -3.34 -1.114 0.57076E+04 36 brucite 12.58 8.94 -3.64 -0.728 0.62128E+04 37 calcite 0.83 -2.36 -3.19 -1.063 0.54463E+04 40 carpholite-Mg 8.65 6.24 -2.42 -0.161 0.41238E+04 41 carpholite-Fe 6.78 4.19 -2.59 -0.173 0.44205E+04 50 chloritoid-Mg 13.26 10.48 -2.78 -0.185 0.47443E+04 51 chloritoid-Fe 9.24 8.44 -0.80 -0.053 0.13613E+04 52 chloritoid-Mn 11.46 9.08 -2.38 -0.159 0.40663E+04 54 coesite -2.37 -4.25 -1.88 -0.626 0.32068E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.25 -1.70 -0.566 0.28997E+04 78 fayalite 14.08 9.55 -4.53 -0.648 0.77399E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.20 -4.00 -0.333 0.68281E+04 92 hercynite 17.34 12.69 -4.66 -0.310 0.79493E+04 98 kaolinite -1.27 -2.70 -1.43 -0.130 0.24410E+04 99 kyanite 4.93 1.54 -3.39 -0.339 0.57831E+04 101 laumontite 2.97 -1.30 -4.28 -0.285 0.73043E+04 102 lawsonite 9.68 7.19 -2.49 -0.166 0.42460E+04 105 lizardite 23.29 18.32 -4.97 -0.414 0.84833E+04 106 magnesite 0.71 -3.31 -4.02 -1.341 0.68678E+04 107 magnetite 20.13 19.49 -0.64 -0.052 0.10901E+04 110 magnesioferrite 26.26 21.54 -4.72 -0.385 0.80621E+04 113 margarite 17.45 12.98 -4.47 -0.179 0.76289E+04 121 paragonite 4.34 -0.54 -4.88 -0.287 0.83240E+04 128 periclase-Fe 11.64 6.90 -4.74 -1.186 0.80975E+04 142 pyrite -21.23 -23.25 -2.03 -0.478 0.34656E+04 143 pyrrhotite -4.24 -7.58 -3.34 -1.113 0.56989E+04 144 pyrrhotiteFe0.875 -6.00 -8.59 -2.59 -0.953 0.44234E+04 145 pyroxmangite 7.42 3.29 -4.13 -0.825 0.70458E+04 147 quartz -2.98 -4.25 -1.27 -0.422 0.21608E+04 152 rhodochrosite -0.96 -4.71 -3.76 -1.252 0.64122E+04 153 rhodonite 7.46 3.29 -4.17 -0.835 0.71251E+04 156 siderite -2.59 -5.35 -2.77 -0.922 0.47238E+04 157 sillimanite 5.32 1.54 -3.78 -0.378 0.64485E+04 169 sudoite 21.22 16.72 -4.50 -0.145 0.76806E+04 178 topaz-H 4.67 1.54 -3.12 -0.284 0.53322E+04 179 tridymite -2.61 -4.25 -1.63 -0.544 0.27880E+04 182 troilite-low -4.39 -7.58 -3.19 -1.062 0.54421E+04 190 wollastonite 10.48 5.65 -4.83 -0.967 0.82554E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.25 -1.45 -0.484 0.24811E+04 206 nontronite-Ca 3.28 -0.40 -3.68 -0.239 0.62868E+04 207 nontronite-H 2.60 -2.03 -4.63 -0.310 0.79067E+04 208 nontronite-K 3.40 -1.58 -4.98 -0.320 0.85075E+04 209 nontronite-Mg 3.14 -0.56 -3.70 -0.240 0.63166E+04 210 nontronite-Na 3.58 -0.87 -4.46 -0.286 0.76111E+04 215 gypsum -4.92 -9.37 -4.44 -1.111 0.75855E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.90 -2.93 -0.732 0.49986E+04 241 silica-amorphous -2.08 -4.25 -2.17 -0.723 0.37013E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0058000 g New total amount of reactant added: 0.0060000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.9763E-15 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0060000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2628372E-03 Osmotic coef. = 0.9903 True ionic strength = .2647408E-03 Chg. balance for total moles = 0.9763E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.49729E-07 -7.3034 0.47800E-07 -7.3206 0.96121E+00 -0.0172 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13260E-03 -3.8775 0.96109E+00 -0.0172 4 SO4-- 0.25304E-04 -4.5968 0.22784E-04 -4.6424 0.90041E+00 -0.0456 5 HCO3- 0.11929E-04 -4.9234 0.11465E-04 -4.9406 0.96112E+00 -0.0172 6 HS- 0.55581E-07 -7.2551 0.53419E-07 -7.2723 0.96109E+00 -0.0172 7 Al+++ 0.10649E-18 -18.9727 0.85973E-19 -19.0656 0.80736E+00 -0.0929 8 H4SiO4 0.58257E-04 -4.2347 0.58257E-04 -4.2347 0.10000E+01 0.0000 9 Ca++ 0.21175E-04 -4.6742 0.19063E-04 -4.7198 0.90028E+00 -0.0456 10 Mg++ 0.21800E-05 -5.6615 0.19625E-05 -5.7072 0.90020E+00 -0.0457 11 Fe++ 0.19482E-07 -7.7104 0.17538E-07 -7.7560 0.90022E+00 -0.0457 12 K+ 0.12734E-05 -5.8950 0.12239E-05 -5.9122 0.96112E+00 -0.0172 13 Na+ 0.16759E-03 -3.7757 0.16107E-03 -3.7930 0.96109E+00 -0.0172 14 Mn++ 0.94588E-07 -7.0242 0.85151E-07 -7.0698 0.90023E+00 -0.0456 15 HPO4-- 0.14285E-07 -7.8451 0.12862E-07 -7.8907 0.90041E+00 -0.0456 16 HSiO3- 0.12373E-05 -5.9075 0.11891E-05 -5.9248 0.96109E+00 -0.0172 17 Ca(HSiO3)+ 0.52844E-09 -9.2770 0.50790E-09 -9.2942 0.96113E+00 -0.0172 18 Mg(HSiO3)+ 0.67701E-10 -10.1694 0.65070E-10 -10.1866 0.96113E+00 -0.0172 19 NaHSiO3,aq 0.30420E-08 -8.5168 0.30420E-08 -8.5168 0.10000E+01 0.0000 20 AlO+ 0.50541E-11 -11.2964 0.48576E-11 -11.3136 0.96113E+00 -0.0172 21 AlOH+2 0.12920E-14 -14.8887 0.11631E-14 -14.9344 0.90025E+00 -0.0456 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.98847E-06 -6.0050 0.94997E-06 -6.0223 0.96106E+00 -0.0173 24 CH4,aq 0.26379E-13 -13.5787 0.26377E-13 -13.5788 0.99992E+00 0.0000 29 CO,aq 0.15949E-15 -15.7973 0.15949E-15 -15.7973 0.10000E+01 0.0000 30 CO2,aq 0.11050E-05 -5.9566 0.11049E-05 -5.9567 0.99992E+00 0.0000 31 CO3-2 0.24631E-07 -7.6085 0.22177E-07 -7.6541 0.90037E+00 -0.0456 32 CaCO3,aq 0.51779E-08 -8.2858 0.51779E-08 -8.2858 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.57298E-08 -8.2419 0.55071E-08 -8.2591 0.96113E+00 -0.0172 34 CaCl+ 0.41908E-08 -8.3777 0.40279E-08 -8.3949 0.96113E+00 -0.0172 35 CaCl2,aq 0.12435E-12 -12.9053 0.12435E-12 -12.9053 0.10000E+01 0.0000 36 CaOH+ 0.29259E-07 -7.5337 0.28122E-07 -7.5510 0.96113E+00 -0.0172 37 CaSO4,aq 0.13533E-06 -6.8686 0.13533E-06 -6.8686 0.10000E+01 0.0000 38 HCl,aq 0.11922E-11 -11.9237 0.11922E-11 -11.9237 0.10000E+01 0.0000 43 FeCl+ 0.37684E-11 -11.4238 0.36219E-11 -11.4411 0.96113E+00 -0.0172 44 FeCl2,aq 0.14895E-19 -19.8270 0.14895E-19 -19.8270 0.10000E+01 0.0000 46 FeO,aq 0.30354E-09 -9.5178 0.30354E-09 -9.5178 0.10000E+01 0.0000 47 FeOH+ 0.12656E-07 -7.8977 0.12164E-07 -7.9149 0.96113E+00 -0.0172 48 HFeO2- 0.71068E-10 -10.1483 0.68303E-10 -10.1656 0.96109E+00 -0.0172 49 FeO+ 0.41140E-12 -12.3857 0.39540E-12 -12.4030 0.96113E+00 -0.0172 50 FeOH+2 0.39066E-17 -17.4082 0.35170E-17 -17.4538 0.90025E+00 -0.0456 51 FeO2- 0.35390E-10 -10.4511 0.34013E-10 -10.4684 0.96109E+00 -0.0172 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.56048E-08 -8.2514 0.56044E-08 -8.2515 0.99992E+00 0.0000 54 KCl,aq 0.28735E-11 -11.5416 0.28735E-11 -11.5416 0.10000E+01 0.0000 55 KHSO4,aq 0.35668E-17 -17.4477 0.35668E-17 -17.4477 0.10000E+01 0.0000 56 KOH,aq 0.11163E-10 -10.9522 0.11163E-10 -10.9522 0.10000E+01 0.0000 57 KSO4- 0.44701E-09 -9.3497 0.42962E-09 -9.3669 0.96109E+00 -0.0172 58 MgCO3,aq 0.13319E-09 -9.8755 0.13319E-09 -9.8755 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.60149E-09 -9.2208 0.57811E-09 -9.2380 0.96113E+00 -0.0172 60 MgCl+ 0.39165E-09 -9.4071 0.37643E-09 -9.4243 0.96113E+00 -0.0172 61 MgOH+ 0.16687E-07 -7.7776 0.16038E-07 -7.7948 0.96113E+00 -0.0172 63 MnO,aq 0.39342E-10 -10.4051 0.39342E-10 -10.4051 0.10000E+01 0.0000 64 MnOH+ 0.57082E-08 -8.2435 0.54863E-08 -8.2607 0.96113E+00 -0.0172 65 MnO2-2 0.66139E-18 -18.1795 0.59550E-18 -18.2251 0.90037E+00 -0.0456 66 HMnO2- 0.64168E-14 -14.1927 0.61672E-14 -14.2099 0.96109E+00 -0.0172 69 MnCl+ 0.71098E-10 -10.1481 0.68334E-10 -10.1654 0.96113E+00 -0.0172 70 MnSO4,aq 0.54982E-09 -9.2598 0.54982E-09 -9.2598 0.10000E+01 0.0000 71 NaCl,aq 0.69736E-08 -8.1565 0.69736E-08 -8.1565 0.10000E+01 0.0000 72 NaOH,aq 0.14807E-08 -8.8295 0.14807E-08 -8.8295 0.10000E+01 0.0000 74 OH- 0.13057E-04 -4.8841 0.12549E-04 -4.9014 0.96106E+00 -0.0173 79 HPO3-2 0.25287E-18 -18.5971 0.22768E-18 -18.6427 0.90037E+00 -0.0456 81 H2PO3- 0.22243E-19 -19.6528 0.21378E-19 -19.6700 0.96109E+00 -0.0172 82 H3PO4,aq 0.18919E-12 -12.7231 0.18919E-12 -12.7231 0.10000E+01 0.0000 83 H2PO4- 0.11215E-07 -7.9502 0.10779E-07 -7.9674 0.96111E+00 -0.0172 84 PO4-3 0.29078E-12 -12.5364 0.23499E-12 -12.6289 0.80814E+00 -0.0925 87 H2P2O7-2 0.10099E-16 -16.9957 0.90927E-17 -17.0413 0.90037E+00 -0.0456 88 HP2O7-3 0.48313E-16 -16.3159 0.39006E-16 -16.4089 0.80736E+00 -0.0929 89 P2O7-4 0.29029E-18 -18.5372 0.20132E-18 -18.6961 0.69349E+00 -0.1590 90 H2S,aq 0.76725E-08 -8.1151 0.76719E-08 -8.1151 0.99992E+00 0.0000 91 S2-2 0.12438E-16 -16.9053 0.11199E-16 -16.9508 0.90037E+00 -0.0456 96 SO2,aq 0.12223E-17 -17.9128 0.12223E-17 -17.9128 0.10000E+01 0.0000 97 SO3-2 0.19331E-13 -13.7137 0.17410E-13 -13.7592 0.90063E+00 -0.0455 98 HSO3- 0.50673E-13 -13.2952 0.48702E-13 -13.3125 0.96109E+00 -0.0172 99 HSO4- 0.10513E-08 -8.9783 0.10105E-08 -8.9955 0.96115E+00 -0.0172 101 S2O3-2 0.22880E-14 -14.6405 0.20600E-14 -14.6861 0.90037E+00 -0.0456 102 HS2O3- 0.18285E-19 -19.7379 0.17574E-19 -19.7551 0.96109E+00 -0.0172 Charge balance for all species = 0.9763E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4972883E-07 -.1723706E-04 -.1737363E-01 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9999813E+06 0.0000 3 Cl- 0.1379629E-03 0.1379745E-03 0.4891528E+01 3.4431 4 SO4-- 0.2530390E-04 0.2543990E-04 0.2443757E+01 9.9988 5 HCO3- 0.1192875E-04 0.1307003E-04 0.7974833E+00 2.3799 6 HS- 0.5558123E-07 0.6462505E-07 0.2137244E-02 0.0483 7 Al+++ 0.1064865E-18 0.1008807E-05 0.2721866E-01 2.8961 8 H4SiO4 0.5825688E-04 0.5949777E-04 0.5718557E+01 -4.2347 9 Ca++ 0.2117507E-04 0.2135529E-04 0.8558630E+00 9.9214 10 Mg++ 0.2180048E-05 0.2197929E-05 0.5343515E-01 8.9340 11 Fe++ 0.1948201E-07 0.3275550E-07 0.1829266E-02 6.8851 12 K+ 0.1273427E-05 0.1273888E-05 0.4981075E-01 1.4083 13 Na+ 0.1675914E-03 0.1676029E-03 0.3853092E+01 3.5276 14 Mn++ 0.9458839E-07 0.1009569E-06 0.5546277E-02 7.5713 15 HPO4-- 0.1428458E-07 0.2549983E-07 0.2447408E-02 6.7505 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8631109E-04 -.1723702E-04 -.6907408E-04 0.0000000E+00 2 H2O 0.5550817E+02 0.5550813E+02 0.4094791E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2567075E-04 0.2543985E-04 0.2309054E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1662805E-06 0.6462490E-07 -.2309054E-06 0.0000000E+00 7 Al+++ 0.1956445E-04 0.1008804E-05 0.1855565E-04 0.0000000E+00 8 H4SiO4 0.6247670E-04 0.5949763E-04 0.2979066E-05 0.0000000E+00 9 Ca++ 0.2137192E-04 0.2135524E-04 0.1667614E-07 0.0000000E+00 10 Mg++ 0.4761905E-05 0.2197924E-05 0.2563981E-05 0.0000000E+00 11 Fe++ 0.4278052E-05 0.3275542E-07 0.4245296E-05 0.0000000E+00 12 K+ 0.1273885E-05 0.1273885E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1676025E-03 0.1676025E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1040316E-06 0.1009567E-06 0.3074914E-08 0.0000000E+00 15 HPO4-- 0.3550546E-07 0.2549977E-07 0.1000569E-07 0.0000000E+00 Chg. balance for solid moles: -.2528E-20 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0060000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3335E-08 -8.477 0.1675E-05 -5.776 0.9461E-01 0.5324E-06 clinochlore 0.5128E-06 -6.290 0.2850E-03 -3.545 16.10 0.1084E-03 daphnite 0.4796E-06 -6.319 0.3422E-03 -3.466 19.32 0.1037E-03 chlorite-Mn 0.6150E-09 -9.211 0.4360E-06 -6.361 0.2462E-01 0.1389E-06 diaspore 0.1657E-04 -4.781 0.9940E-03 -3.003 56.13 0.2959E-03 hematite 0.9236E-06 -6.035 0.1475E-03 -3.831 8.329 0.2796E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5164E+00 0.5164E+00 1.0000 -0.287 daphnite 0.4830E+00 0.4830E+00 1.0000 -0.316 chlorite-Mn 0.6193E-03 0.6193E-03 1.0000 -3.208 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.001771 g Volume = 0.000537 cm3 Porosity: 99.9465% V(tot) - V(min): 0.10019E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0060000 g log = -2.2218 Original solution: 1000.0103000 g Original solution / Rock added: 166668.38 (Water/Rock Ratio), log = 5.2219 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1193E-03 1.0073 0.1265E-03 0.1256E-03 CH4,gas 0.3914E-10 1.0129 0.4171E-10 0.4118E-10 H2,gas 0.7302E-05 1.0006 0.7687E-05 0.7682E-05 H2S,gas 0.2136E-06 0.9959 0.2238E-06 0.2247E-06 S2,gas 0.3017E-22 1.0000 0.3174E-22 0.3174E-22 CO,gas 0.2394E-12 1.0000 0.2518E-12 0.2518E-12 SO3,gas 0.1850E-34 1.0000 0.1946E-34 0.1946E-34 SO2,gas 0.5379E-17 1.0000 0.5659E-17 0.5659E-17 HCl,gas 0.2001E-14 1.0000 0.2105E-14 0.2105E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.26 -5.90 -1.966 0.10071E+05 -3.898 3 CH4,gas 4.81 -7.57 -12.38 -3.095 0.21138E+05 -10.380 4 H2,gas 8.29 1.17 -7.11 -4.065 0.12147E+05 -5.114 5 H2S,gas -5.94 -14.59 -8.65 -4.325 0.14770E+05 -6.650 6 S2,gas -7.03 -31.53 -24.50 -3.769 0.41830E+05 -22.498 7 CO,gas 3.51 -11.09 -14.60 -4.492 0.24927E+05 -12.599 8 SO3,gas 17.43 -19.28 -36.71 -9.178 0.62683E+05 -34.711 9 SO2,gas 1.14 -18.11 -19.25 -5.133 0.32864E+05 -17.247 10 HCl,gas 5.48 -11.20 -16.68 -8.338 0.28475E+05 -14.677 21 andalusite 5.06 1.56 -3.50 -0.350 0.59844E+04 24 anhydrite -5.28 -9.36 -4.08 -2.041 0.69706E+04 35 aragonite 0.99 -2.34 -3.33 -1.109 0.56792E+04 36 brucite 12.58 8.93 -3.64 -0.729 0.62197E+04 37 calcite 0.83 -2.34 -3.17 -1.058 0.54178E+04 40 carpholite-Mg 8.65 6.26 -2.39 -0.160 0.40869E+04 41 carpholite-Fe 6.78 4.21 -2.57 -0.172 0.43965E+04 50 chloritoid-Mg 13.26 10.49 -2.77 -0.185 0.47293E+04 51 chloritoid-Fe 9.24 8.44 -0.80 -0.053 0.13592E+04 52 chloritoid-Mn 11.46 9.13 -2.33 -0.156 0.39858E+04 54 coesite -2.37 -4.23 -1.87 -0.622 0.31850E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.23 -1.69 -0.562 0.28778E+04 78 fayalite 14.08 9.54 -4.54 -0.649 0.77576E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.19 -4.01 -0.334 0.68437E+04 92 hercynite 17.34 12.68 -4.67 -0.311 0.79691E+04 98 kaolinite -1.27 -2.68 -1.40 -0.128 0.23973E+04 99 kyanite 4.93 1.56 -3.37 -0.337 0.57612E+04 101 laumontite 2.97 -1.23 -4.20 -0.280 0.71707E+04 102 lawsonite 9.68 7.24 -2.43 -0.162 0.41562E+04 105 lizardite 23.29 18.33 -4.95 -0.413 0.84603E+04 106 magnesite 0.71 -3.33 -4.04 -1.346 0.68923E+04 107 magnetite 20.13 19.48 -0.65 -0.053 0.11099E+04 110 magnesioferrite 26.26 21.53 -4.73 -0.386 0.80690E+04 113 margarite 17.45 13.04 -4.42 -0.177 0.75392E+04 121 paragonite 4.34 -0.49 -4.82 -0.284 0.82381E+04 128 periclase-Fe 11.64 6.89 -4.75 -1.189 0.81173E+04 142 pyrite -21.23 -23.47 -2.25 -0.529 0.38383E+04 143 pyrrhotite -4.24 -7.71 -3.46 -1.155 0.59150E+04 144 pyrrhotiteFe0.875 -6.00 -8.71 -2.71 -0.998 0.46320E+04 145 pyroxmangite 7.42 3.34 -4.08 -0.816 0.69654E+04 147 quartz -2.98 -4.23 -1.25 -0.418 0.21389E+04 152 rhodochrosite -0.96 -4.69 -3.73 -1.244 0.63711E+04 153 rhodonite 7.46 3.34 -4.13 -0.825 0.70446E+04 156 siderite -2.59 -5.38 -2.79 -0.929 0.47611E+04 157 sillimanite 5.32 1.56 -3.76 -0.376 0.64266E+04 169 sudoite 21.22 16.75 -4.47 -0.144 0.76288E+04 178 topaz-H 4.67 1.56 -3.11 -0.283 0.53103E+04 179 tridymite -2.61 -4.23 -1.62 -0.540 0.27662E+04 182 troilite-low -4.39 -7.71 -3.31 -1.105 0.56582E+04 190 wollastonite 10.48 5.69 -4.80 -0.959 0.81875E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.23 -1.44 -0.480 0.24592E+04 206 nontronite-Ca 3.28 -0.35 -3.63 -0.236 0.61989E+04 207 nontronite-H 2.60 -1.99 -4.58 -0.307 0.78263E+04 208 nontronite-K 3.40 -1.52 -4.93 -0.316 0.84126E+04 209 nontronite-Mg 3.14 -0.51 -3.65 -0.237 0.62374E+04 210 nontronite-Na 3.58 -0.82 -4.41 -0.283 0.75241E+04 215 gypsum -4.92 -9.36 -4.44 -1.109 0.75774E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.89 -2.94 -0.735 0.50184E+04 241 silica-amorphous -2.08 -4.23 -2.15 -0.718 0.36794E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0060000 g New total amount of reactant added: 0.0062000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.9763E-15 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0062000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2633170E-03 Osmotic coef. = 0.9902 True ionic strength = .2653336E-03 Chg. balance for total moles = 0.9763E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.48435E-07 -7.3148 0.46555E-07 -7.3320 0.96118E+00 -0.0172 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13259E-03 -3.8775 0.96107E+00 -0.0172 4 SO4-- 0.25317E-04 -4.5966 0.22793E-04 -4.6422 0.90032E+00 -0.0456 5 HCO3- 0.11954E-04 -4.9225 0.11489E-04 -4.9397 0.96110E+00 -0.0172 6 HS- 0.43273E-07 -7.3638 0.41588E-07 -7.3810 0.96107E+00 -0.0172 7 Al+++ 0.98401E-19 -19.0070 0.79428E-19 -19.1000 0.80718E+00 -0.0930 8 H4SiO4 0.59968E-04 -4.2221 0.59968E-04 -4.2221 0.10000E+01 0.0000 9 Ca++ 0.21398E-04 -4.6696 0.19262E-04 -4.7153 0.90019E+00 -0.0457 10 Mg++ 0.20525E-05 -5.6877 0.18475E-05 -5.7334 0.90011E+00 -0.0457 11 Fe++ 0.17971E-07 -7.7454 0.16176E-07 -7.7911 0.90013E+00 -0.0457 12 K+ 0.13159E-05 -5.8808 0.12647E-05 -5.8980 0.96110E+00 -0.0172 13 Na+ 0.16784E-03 -3.7751 0.16131E-03 -3.7923 0.96107E+00 -0.0172 14 Mn++ 0.97078E-07 -7.0129 0.87384E-07 -7.0586 0.90015E+00 -0.0457 15 HPO4-- 0.13556E-07 -7.8679 0.12205E-07 -7.9135 0.90032E+00 -0.0456 16 HSiO3- 0.13077E-05 -5.8835 0.12568E-05 -5.9007 0.96107E+00 -0.0172 17 Ca(HSiO3)+ 0.56433E-09 -9.2485 0.54238E-09 -9.2657 0.96111E+00 -0.0172 18 Mg(HSiO3)+ 0.67362E-10 -10.1716 0.64742E-10 -10.1888 0.96111E+00 -0.0172 19 NaHSiO3,aq 0.32198E-08 -8.4922 0.32198E-08 -8.4922 0.10000E+01 0.0000 20 AlO+ 0.49226E-11 -11.3078 0.47311E-11 -11.3250 0.96111E+00 -0.0172 21 AlOH+2 0.12257E-14 -14.9116 0.11033E-14 -14.9573 0.90016E+00 -0.0457 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.10149E-05 -5.9936 0.97538E-06 -6.0108 0.96103E+00 -0.0173 24 CH4,aq 0.20572E-13 -13.6867 0.20570E-13 -13.6868 0.99992E+00 0.0000 29 CO,aq 0.14717E-15 -15.8322 0.14717E-15 -15.8322 0.10000E+01 0.0000 30 CO2,aq 0.10785E-05 -5.9672 0.10784E-05 -5.9672 0.99992E+00 0.0000 31 CO3-2 0.25346E-07 -7.5961 0.22818E-07 -7.6417 0.90028E+00 -0.0456 32 CaCO3,aq 0.53831E-08 -8.2690 0.53831E-08 -8.2690 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.58019E-08 -8.2364 0.55762E-08 -8.2537 0.96111E+00 -0.0172 34 CaCl+ 0.42344E-08 -8.3732 0.40697E-08 -8.3904 0.96111E+00 -0.0172 35 CaCl2,aq 0.12564E-12 -12.9009 0.12564E-12 -12.9009 0.10000E+01 0.0000 36 CaOH+ 0.30355E-07 -7.5178 0.29175E-07 -7.5350 0.96111E+00 -0.0172 37 CaSO4,aq 0.13679E-06 -6.8639 0.13679E-06 -6.8639 0.10000E+01 0.0000 38 HCl,aq 0.11611E-11 -11.9351 0.11611E-11 -11.9351 0.10000E+01 0.0000 43 FeCl+ 0.34758E-11 -11.4589 0.33406E-11 -11.4762 0.96111E+00 -0.0172 44 FeCl2,aq 0.13737E-19 -19.8621 0.13737E-19 -19.8621 0.10000E+01 0.0000 46 FeO,aq 0.29514E-09 -9.5300 0.29514E-09 -9.5300 0.10000E+01 0.0000 47 FeOH+ 0.11986E-07 -7.9213 0.11519E-07 -7.9386 0.96111E+00 -0.0172 48 HFeO2- 0.70953E-10 -10.1490 0.68190E-10 -10.1663 0.96107E+00 -0.0172 49 FeO+ 0.40069E-12 -12.3972 0.38511E-12 -12.4144 0.96111E+00 -0.0172 50 FeOH+2 0.37061E-17 -17.4311 0.33361E-17 -17.4768 0.90016E+00 -0.0457 51 FeO2- 0.36337E-10 -10.4396 0.34923E-10 -10.4569 0.96107E+00 -0.0172 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.52991E-08 -8.2758 0.52987E-08 -8.2758 0.99992E+00 0.0000 54 KCl,aq 0.29692E-11 -11.5274 0.29692E-11 -11.5274 0.10000E+01 0.0000 55 KHSO4,aq 0.35911E-17 -17.4448 0.35911E-17 -17.4448 0.10000E+01 0.0000 56 KOH,aq 0.11843E-10 -10.9265 0.11843E-10 -10.9265 0.10000E+01 0.0000 57 KSO4- 0.46210E-09 -9.3353 0.44411E-09 -9.3525 0.96107E+00 -0.0172 58 MgCO3,aq 0.12902E-09 -9.8894 0.12902E-09 -9.8894 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.56746E-09 -9.2461 0.54539E-09 -9.2633 0.96111E+00 -0.0172 60 MgCl+ 0.36870E-09 -9.4333 0.35436E-09 -9.4506 0.96111E+00 -0.0172 61 MgOH+ 0.16130E-07 -7.7924 0.15502E-07 -7.8096 0.96111E+00 -0.0172 63 MnO,aq 0.42562E-10 -10.3710 0.42562E-10 -10.3710 0.10000E+01 0.0000 64 MnOH+ 0.60147E-08 -8.2208 0.57808E-08 -8.2380 0.96111E+00 -0.0172 65 MnO2-2 0.75438E-18 -18.1224 0.67915E-18 -18.1680 0.90028E+00 -0.0456 66 HMnO2- 0.71278E-14 -14.1470 0.68503E-14 -14.1643 0.96107E+00 -0.0172 69 MnCl+ 0.72962E-10 -10.1369 0.70124E-10 -10.1541 0.96111E+00 -0.0172 70 MnSO4,aq 0.56447E-09 -9.2484 0.56447E-09 -9.2484 0.10000E+01 0.0000 71 NaCl,aq 0.69837E-08 -8.1559 0.69837E-08 -8.1559 0.10000E+01 0.0000 72 NaOH,aq 0.15225E-08 -8.8174 0.15225E-08 -8.8174 0.10000E+01 0.0000 74 OH- 0.13407E-04 -4.8727 0.12885E-04 -4.8899 0.96103E+00 -0.0173 79 HPO3-2 0.22688E-18 -18.6442 0.20426E-18 -18.6898 0.90028E+00 -0.0456 81 H2PO3- 0.19436E-19 -19.7114 0.18679E-19 -19.7286 0.96107E+00 -0.0172 82 H3PO4,aq 0.17029E-12 -12.7688 0.17029E-12 -12.7688 0.10000E+01 0.0000 83 H2PO4- 0.10365E-07 -7.9844 0.99614E-08 -8.0017 0.96109E+00 -0.0172 84 PO4-3 0.28336E-12 -12.5477 0.22895E-12 -12.6403 0.80797E+00 -0.0926 87 H2P2O7-2 0.86264E-17 -17.0642 0.77662E-17 -17.1098 0.90028E+00 -0.0456 88 HP2O7-3 0.42378E-16 -16.3729 0.34207E-16 -16.4659 0.80719E+00 -0.0930 89 P2O7-4 0.26148E-18 -18.5826 0.18127E-18 -18.7417 0.69323E+00 -0.1591 90 H2S,aq 0.58177E-08 -8.2353 0.58172E-08 -8.2353 0.99992E+00 0.0000 91 S2-2 0.79743E-17 -17.0983 0.71791E-17 -17.1439 0.90028E+00 -0.0456 96 SO2,aq 0.10967E-17 -17.9599 0.10967E-17 -17.9599 0.10000E+01 0.0000 97 SO3-2 0.18286E-13 -13.7379 0.16467E-13 -13.7834 0.90054E+00 -0.0455 98 HSO3- 0.46682E-13 -13.3309 0.44864E-13 -13.3481 0.96107E+00 -0.0172 99 HSO4- 0.10244E-08 -8.9895 0.98457E-09 -9.0068 0.96112E+00 -0.0172 101 S2O3-2 0.17358E-14 -14.7605 0.15627E-14 -14.8061 0.90028E+00 -0.0456 102 HS2O3- 0.13510E-19 -19.8694 0.12984E-19 -19.8866 0.96107E+00 -0.0172 Charge balance for all species = 0.9764E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4843469E-07 -.1779463E-04 -.1793562E-01 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9999811E+06 0.0000 3 Cl- 0.1379628E-03 0.1379745E-03 0.4891528E+01 3.4546 4 SO4-- 0.2531660E-04 0.2545415E-04 0.2445125E+01 10.0219 5 HCO3- 0.1195430E-04 0.1307003E-04 0.7974832E+00 2.3923 6 HS- 0.4327271E-07 0.5038517E-07 0.1666310E-02 -0.0490 7 Al+++ 0.9840143E-19 0.1035266E-05 0.2793255E-01 2.8961 8 H4SiO4 0.5996765E-04 0.6127919E-04 0.5889774E+01 -4.2221 9 Ca++ 0.2139758E-04 0.2158072E-04 0.8648973E+00 9.9488 10 Mg++ 0.2052499E-05 0.2069762E-05 0.5031919E-01 8.9307 11 Fe++ 0.1797096E-07 0.3056633E-07 0.1707009E-02 6.8730 12 K+ 0.1315874E-05 0.1316351E-05 0.5147110E-01 1.4340 13 Na+ 0.1678422E-03 0.1678539E-03 0.3858863E+01 3.5397 14 Mn++ 0.9707781E-07 0.1037725E-06 0.5700959E-02 7.6055 15 HPO4-- 0.1355591E-07 0.2392111E-07 0.2295886E-02 6.7506 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8962280E-04 -.1779459E-04 -.7182820E-04 0.0000000E+00 2 H2O 0.5550817E+02 0.5550813E+02 0.4233140E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2567629E-04 0.2545408E-04 0.2222082E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1718231E-06 0.5038505E-07 -.2222082E-06 0.0000000E+00 7 Al+++ 0.2021660E-04 0.1035263E-05 0.1918133E-04 0.0000000E+00 8 H4SiO4 0.6455925E-04 0.6127904E-04 0.3280216E-05 0.0000000E+00 9 Ca++ 0.2160194E-04 0.2158066E-04 0.2127986E-07 0.0000000E+00 10 Mg++ 0.4920635E-05 0.2069757E-05 0.2850878E-05 0.0000000E+00 11 Fe++ 0.4420653E-05 0.3056626E-07 0.4390087E-05 0.0000000E+00 12 K+ 0.1316348E-05 0.1316348E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1678535E-03 0.1678535E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1074993E-06 0.1037723E-06 0.3727022E-08 0.0000000E+00 15 HPO4-- 0.3668898E-07 0.2392106E-07 0.1276792E-07 0.0000000E+00 Chg. balance for solid moles: 0.5383E-20 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0062000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4256E-08 -8.371 0.2138E-05 -5.670 0.1153 0.6793E-06 clinochlore 0.5702E-06 -6.244 0.3169E-03 -3.499 17.10 0.1205E-03 daphnite 0.5225E-06 -6.282 0.3728E-03 -3.429 20.11 0.1130E-03 chlorite-Mn 0.7454E-09 -9.128 0.5285E-06 -6.277 0.2851E-01 0.1684E-06 diaspore 0.1699E-04 -4.770 0.1020E-02 -2.992 54.99 0.3035E-03 hematite 0.8888E-06 -6.051 0.1419E-03 -3.848 7.657 0.2690E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5215E+00 0.5215E+00 1.0000 -0.283 daphnite 0.4779E+00 0.4779E+00 1.0000 -0.321 chlorite-Mn 0.6817E-03 0.6817E-03 1.0000 -3.166 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.001854 g Volume = 0.000565 cm3 Porosity: 99.9437% V(tot) - V(min): 0.10019E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0062000 g log = -2.2076 Original solution: 1000.0103000 g Original solution / Rock added: 161291.98 (Water/Rock Ratio), log = 5.2076 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1165E-03 1.0073 0.1234E-03 0.1225E-03 CH4,gas 0.3053E-10 1.0129 0.3253E-10 0.3211E-10 H2,gas 0.6904E-05 1.0006 0.7268E-05 0.7263E-05 H2S,gas 0.1619E-06 0.9959 0.1697E-06 0.1704E-06 S2,gas 0.1940E-22 1.0000 0.2041E-22 0.2041E-22 CO,gas 0.2209E-12 1.0000 0.2324E-12 0.2324E-12 SO3,gas 0.1755E-34 1.0000 0.1847E-34 0.1847E-34 SO2,gas 0.4826E-17 1.0000 0.5077E-17 0.5077E-17 HCl,gas 0.1949E-14 1.0000 0.2050E-14 0.2050E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.27 -5.91 -1.970 0.10089E+05 -3.909 3 CH4,gas 4.81 -7.68 -12.49 -3.122 0.21322E+05 -10.488 4 H2,gas 8.29 1.15 -7.14 -4.079 0.12189E+05 -5.139 5 H2S,gas -5.94 -14.71 -8.77 -4.385 0.14975E+05 -6.770 6 S2,gas -7.03 -31.72 -24.69 -3.798 0.42158E+05 -22.690 7 CO,gas 3.51 -11.12 -14.63 -4.503 0.24987E+05 -12.634 8 SO3,gas 17.43 -19.31 -36.73 -9.183 0.62722E+05 -34.734 9 SO2,gas 1.14 -18.16 -19.29 -5.145 0.32945E+05 -17.294 10 HCl,gas 5.48 -11.21 -16.69 -8.344 0.28495E+05 -14.688 21 andalusite 5.06 1.57 -3.49 -0.349 0.59630E+04 24 anhydrite -5.28 -9.36 -4.08 -2.039 0.69626E+04 35 aragonite 0.99 -2.32 -3.31 -1.103 0.56504E+04 36 brucite 12.58 8.93 -3.65 -0.729 0.62253E+04 37 calcite 0.83 -2.32 -3.16 -1.052 0.53890E+04 40 carpholite-Mg 8.65 6.28 -2.37 -0.158 0.40496E+04 41 carpholite-Fe 6.78 4.22 -2.56 -0.171 0.43744E+04 50 chloritoid-Mg 13.26 10.50 -2.76 -0.184 0.47135E+04 51 chloritoid-Fe 9.24 8.44 -0.80 -0.053 0.13585E+04 52 chloritoid-Mn 11.46 9.18 -2.29 -0.153 0.39060E+04 54 coesite -2.37 -4.22 -1.85 -0.618 0.31635E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.22 -1.67 -0.558 0.28564E+04 78 fayalite 14.08 9.52 -4.56 -0.651 0.77778E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.17 -4.02 -0.335 0.68632E+04 92 hercynite 17.34 12.67 -4.68 -0.312 0.79899E+04 98 kaolinite -1.27 -2.65 -1.38 -0.125 0.23543E+04 99 kyanite 4.93 1.57 -3.36 -0.336 0.57397E+04 101 laumontite 2.97 -1.15 -4.12 -0.275 0.70381E+04 102 lawsonite 9.68 7.30 -2.38 -0.159 0.40665E+04 105 lizardite 23.29 18.35 -4.94 -0.412 0.84343E+04 106 magnesite 0.71 -3.34 -4.05 -1.350 0.69159E+04 107 magnetite 20.13 19.47 -0.66 -0.054 0.11307E+04 110 magnesioferrite 26.26 21.53 -4.73 -0.386 0.80746E+04 113 margarite 17.45 13.09 -4.36 -0.175 0.74494E+04 121 paragonite 4.34 -0.44 -4.77 -0.281 0.81530E+04 128 periclase-Fe 11.64 6.87 -4.77 -1.192 0.81381E+04 142 pyrite -21.23 -23.70 -2.48 -0.583 0.42279E+04 143 pyrrhotite -4.24 -7.84 -3.60 -1.199 0.61410E+04 144 pyrrhotiteFe0.875 -6.00 -8.84 -2.84 -1.045 0.48503E+04 145 pyroxmangite 7.42 3.38 -4.03 -0.807 0.68856E+04 146 pyrophyllite -6.10 -11.10 -5.00 -0.312 0.85342E+04 147 quartz -2.98 -4.22 -1.24 -0.413 0.21174E+04 152 rhodochrosite -0.96 -4.67 -3.71 -1.236 0.63308E+04 153 rhodonite 7.46 3.38 -4.08 -0.816 0.69648E+04 156 siderite -2.59 -5.40 -2.81 -0.937 0.47999E+04 157 sillimanite 5.32 1.57 -3.75 -0.375 0.64052E+04 169 sudoite 21.22 16.78 -4.44 -0.143 0.75757E+04 178 topaz-H 4.67 1.57 -3.10 -0.282 0.52888E+04 179 tridymite -2.61 -4.22 -1.61 -0.536 0.27447E+04 182 troilite-low -4.39 -7.84 -3.45 -1.149 0.58842E+04 190 wollastonite 10.48 5.73 -4.76 -0.951 0.81192E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.22 -1.43 -0.476 0.24377E+04 206 nontronite-Ca 3.28 -0.30 -3.58 -0.232 0.61125E+04 207 nontronite-H 2.60 -1.94 -4.54 -0.304 0.77476E+04 208 nontronite-K 3.40 -1.47 -4.87 -0.313 0.83193E+04 209 nontronite-Mg 3.14 -0.47 -3.61 -0.234 0.61596E+04 210 nontronite-Na 3.58 -0.77 -4.36 -0.280 0.74385E+04 215 gypsum -4.92 -9.36 -4.43 -1.108 0.75694E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.87 -2.95 -0.738 0.50392E+04 241 silica-amorphous -2.08 -4.22 -2.14 -0.714 0.36579E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0062000 g New total amount of reactant added: 0.0064000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.9763E-15 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0064000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2638148E-03 Osmotic coef. = 0.9902 True ionic strength = .2659487E-03 Chg. balance for total moles = 0.9763E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.47154E-07 -7.3265 0.45323E-07 -7.3437 0.96116E+00 -0.0172 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13259E-03 -3.8775 0.96105E+00 -0.0173 4 SO4-- 0.25326E-04 -4.5964 0.22800E-04 -4.6421 0.90023E+00 -0.0456 5 HCO3- 0.11980E-04 -4.9216 0.11513E-04 -4.9388 0.96107E+00 -0.0172 6 HS- 0.33430E-07 -7.4759 0.32127E-07 -7.4931 0.96105E+00 -0.0173 7 Al+++ 0.90816E-19 -19.0418 0.73289E-19 -19.1350 0.80701E+00 -0.0931 8 H4SiO4 0.61693E-04 -4.2098 0.61693E-04 -4.2098 0.10000E+01 0.0000 9 Ca++ 0.21620E-04 -4.6651 0.19460E-04 -4.7108 0.90010E+00 -0.0457 10 Mg++ 0.19332E-05 -5.7137 0.17399E-05 -5.7595 0.90002E+00 -0.0457 11 Fe++ 0.16548E-07 -7.7812 0.14894E-07 -7.8270 0.90004E+00 -0.0457 12 K+ 0.13583E-05 -5.8670 0.13055E-05 -5.8842 0.96108E+00 -0.0172 13 Na+ 0.16809E-03 -3.7745 0.16154E-03 -3.7917 0.96104E+00 -0.0173 14 Mn++ 0.99486E-07 -7.0022 0.89543E-07 -7.0480 0.90006E+00 -0.0457 15 HPO4-- 0.12860E-07 -7.8908 0.11577E-07 -7.9364 0.90023E+00 -0.0456 16 HSiO3- 0.13819E-05 -5.8595 0.13281E-05 -5.8768 0.96105E+00 -0.0173 17 Ca(HSiO3)+ 0.60251E-09 -9.2200 0.57906E-09 -9.2373 0.96108E+00 -0.0172 18 Mg(HSiO3)+ 0.67042E-10 -10.1737 0.64433E-10 -10.1909 0.96108E+00 -0.0172 19 NaHSiO3,aq 0.34075E-08 -8.4676 0.34075E-08 -8.4676 0.10000E+01 0.0000 20 AlO+ 0.47924E-11 -11.3194 0.46059E-11 -11.3367 0.96108E+00 -0.0172 21 AlOH+2 0.11618E-14 -14.9349 0.10457E-14 -14.9806 0.90007E+00 -0.0457 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.10425E-05 -5.9819 0.10019E-05 -5.9992 0.96101E+00 -0.0173 24 CH4,aq 0.15921E-13 -13.7980 0.15920E-13 -13.7981 0.99992E+00 0.0000 29 CO,aq 0.13550E-15 -15.8681 0.13550E-15 -15.8681 0.10000E+01 0.0000 30 CO2,aq 0.10522E-05 -5.9779 0.10521E-05 -5.9779 0.99992E+00 0.0000 31 CO3-2 0.26091E-07 -7.5835 0.23487E-07 -7.6292 0.90019E+00 -0.0457 32 CaCO3,aq 0.55981E-08 -8.2520 0.55981E-08 -8.2520 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.58741E-08 -8.2311 0.56455E-08 -8.2483 0.96108E+00 -0.0172 34 CaCl+ 0.42781E-08 -8.3688 0.41116E-08 -8.3860 0.96108E+00 -0.0172 35 CaCl2,aq 0.12693E-12 -12.8964 0.12693E-12 -12.8964 0.10000E+01 0.0000 36 CaOH+ 0.31502E-07 -7.5017 0.30276E-07 -7.5189 0.96108E+00 -0.0172 37 CaSO4,aq 0.13824E-06 -6.8594 0.13824E-06 -6.8594 0.10000E+01 0.0000 38 HCl,aq 0.11303E-11 -11.9468 0.11303E-11 -11.9468 0.10000E+01 0.0000 43 FeCl+ 0.32003E-11 -11.4948 0.30758E-11 -11.5120 0.96108E+00 -0.0172 44 FeCl2,aq 0.12648E-19 -19.8980 0.12648E-19 -19.8980 0.10000E+01 0.0000 46 FeO,aq 0.28672E-09 -9.5425 0.28672E-09 -9.5425 0.10000E+01 0.0000 47 FeOH+ 0.11336E-07 -7.9455 0.10895E-07 -7.9628 0.96108E+00 -0.0172 48 HFeO2- 0.70803E-10 -10.1499 0.68045E-10 -10.1672 0.96105E+00 -0.0173 49 FeO+ 0.39010E-12 -12.4088 0.37492E-12 -12.4261 0.96108E+00 -0.0172 50 FeOH+2 0.35130E-17 -17.4543 0.31619E-17 -17.5000 0.90007E+00 -0.0457 51 FeO2- 0.37326E-10 -10.4280 0.35872E-10 -10.4452 0.96105E+00 -0.0173 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.50010E-08 -8.3009 0.50006E-08 -8.3010 0.99992E+00 0.0000 54 KCl,aq 0.30648E-11 -11.5136 0.30648E-11 -11.5136 0.10000E+01 0.0000 55 KHSO4,aq 0.36098E-17 -17.4425 0.36098E-17 -17.4425 0.10000E+01 0.0000 56 KOH,aq 0.12557E-10 -10.9011 0.12557E-10 -10.9011 0.10000E+01 0.0000 57 KSO4- 0.47714E-09 -9.3214 0.45855E-09 -9.3386 0.96105E+00 -0.0173 58 MgCO3,aq 0.12507E-09 -9.9029 0.12507E-09 -9.9029 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.53556E-09 -9.2712 0.51472E-09 -9.2884 0.96108E+00 -0.0172 60 MgCl+ 0.34724E-09 -9.4594 0.33372E-09 -9.4766 0.96108E+00 -0.0172 61 MgOH+ 0.15604E-07 -7.8068 0.14997E-07 -7.8240 0.96108E+00 -0.0172 63 MnO,aq 0.46016E-10 -10.3371 0.46016E-10 -10.3371 0.10000E+01 0.0000 64 MnOH+ 0.63309E-08 -8.1985 0.60846E-08 -8.2158 0.96108E+00 -0.0172 65 MnO2-2 0.86062E-18 -18.0652 0.77472E-18 -18.1109 0.90019E+00 -0.0457 66 HMnO2- 0.79159E-14 -14.1015 0.76076E-14 -14.1188 0.96105E+00 -0.0173 69 MnCl+ 0.74764E-10 -10.1263 0.71854E-10 -10.1435 0.96108E+00 -0.0172 70 MnSO4,aq 0.57858E-09 -9.2376 0.57858E-09 -9.2376 0.10000E+01 0.0000 71 NaCl,aq 0.69938E-08 -8.1553 0.69938E-08 -8.1553 0.10000E+01 0.0000 72 NaOH,aq 0.15662E-08 -8.8052 0.15662E-08 -8.8052 0.10000E+01 0.0000 74 OH- 0.13772E-04 -4.8610 0.13235E-04 -4.8783 0.96101E+00 -0.0173 79 HPO3-2 0.20312E-18 -18.6922 0.18285E-18 -18.7379 0.90019E+00 -0.0457 81 H2PO3- 0.16939E-19 -19.7711 0.16279E-19 -19.7884 0.96105E+00 -0.0173 82 H3PO4,aq 0.15310E-12 -12.8150 0.15310E-12 -12.8150 0.10000E+01 0.0000 83 H2PO4- 0.95714E-08 -8.0190 0.91988E-08 -8.0363 0.96106E+00 -0.0172 84 PO4-3 0.27614E-12 -12.5589 0.22307E-12 -12.6516 0.80779E+00 -0.0927 87 H2P2O7-2 0.73568E-17 -17.1333 0.66226E-17 -17.1790 0.90019E+00 -0.0457 88 HP2O7-3 0.37127E-16 -16.4303 0.29962E-16 -16.5234 0.80701E+00 -0.0931 89 P2O7-4 0.23535E-18 -18.6283 0.16309E-18 -18.7876 0.69296E+00 -0.1593 90 H2S,aq 0.43753E-08 -8.3590 0.43750E-08 -8.3590 0.99992E+00 0.0000 91 S2-2 0.50430E-17 -17.2973 0.45397E-17 -17.3430 0.90019E+00 -0.0457 96 SO2,aq 0.98122E-18 -18.0082 0.98122E-18 -18.0082 0.10000E+01 0.0000 97 SO3-2 0.17264E-13 -13.7629 0.15545E-13 -13.8084 0.90045E+00 -0.0455 98 HSO3- 0.42904E-13 -13.3675 0.41232E-13 -13.3848 0.96105E+00 -0.0173 99 HSO4- 0.99761E-09 -9.0010 0.95880E-09 -9.0183 0.96110E+00 -0.0172 101 S2O3-2 0.13059E-14 -14.8841 0.11756E-14 -14.9297 0.90019E+00 -0.0457 Charge balance for all species = 0.9764E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4715436E-07 -.1837531E-04 -.1852090E-01 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9999809E+06 0.0000 3 Cl- 0.1379628E-03 0.1379745E-03 0.4891527E+01 3.4662 4 SO4-- 0.2532643E-04 0.2546551E-04 0.2446216E+01 10.0453 5 HCO3- 0.1197964E-04 0.1307003E-04 0.7974832E+00 2.4049 6 HS- 0.3342955E-07 0.3902501E-07 0.1290613E-02 -0.1494 7 Al+++ 0.9081591E-19 0.1062874E-05 0.2867745E-01 2.8961 8 H4SiO4 0.6169343E-04 0.6307942E-04 0.6062800E+01 -4.2098 9 Ca++ 0.2162019E-04 0.2180629E-04 0.8739376E+00 9.9765 10 Mg++ 0.1933206E-05 0.1949885E-05 0.4740480E-01 8.9279 11 Fe++ 0.1654824E-07 0.2848597E-07 0.1590829E-02 6.8604 12 K+ 0.1358322E-05 0.1358814E-05 0.5313145E-01 1.4594 13 Na+ 0.1680930E-03 0.1681050E-03 0.3864634E+01 3.5520 14 Mn++ 0.9948553E-07 0.1065158E-06 0.5851667E-02 7.6394 15 HPO4-- 0.1285951E-07 0.2243138E-07 0.2152905E-02 6.7509 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9293450E-04 -.1837527E-04 -.7455923E-04 0.0000000E+00 2 H2O 0.5550817E+02 0.5550813E+02 0.4372305E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2568184E-04 0.2546545E-04 0.2163907E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1773658E-06 0.3902491E-07 -.2163907E-06 0.0000000E+00 7 Al+++ 0.2086875E-04 0.1062872E-05 0.1980587E-04 0.0000000E+00 8 H4SiO4 0.6664181E-04 0.6307926E-04 0.3562548E-05 0.0000000E+00 9 Ca++ 0.2183197E-04 0.2180624E-04 0.2573528E-07 0.0000000E+00 10 Mg++ 0.5079365E-05 0.1949880E-05 0.3129485E-05 0.0000000E+00 11 Fe++ 0.4563255E-05 0.2848590E-07 0.4534769E-05 0.0000000E+00 12 K+ 0.1358811E-05 0.1358811E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1681046E-03 0.1681046E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1109670E-06 0.1065156E-06 0.4451444E-08 0.0000000E+00 15 HPO4-- 0.3787249E-07 0.2243133E-07 0.1544117E-07 0.0000000E+00 Chg. balance for solid moles: -.1145E-19 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0064000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5147E-08 -8.288 0.2585E-05 -5.587 0.1336 0.8216E-06 clinochlore 0.6259E-06 -6.203 0.3479E-03 -3.459 17.98 0.1323E-03 daphnite 0.5607E-06 -6.251 0.4001E-03 -3.398 20.68 0.1212E-03 chlorite-Mn 0.8903E-09 -9.050 0.6312E-06 -6.200 0.3262E-01 0.2011E-06 diaspore 0.1743E-04 -4.759 0.1046E-02 -2.981 54.04 0.3113E-03 hematite 0.8656E-06 -6.063 0.1382E-03 -3.859 7.143 0.2620E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5271E+00 0.5271E+00 1.0000 -0.278 daphnite 0.4722E+00 0.4722E+00 1.0000 -0.326 chlorite-Mn 0.7497E-03 0.7497E-03 1.0000 -3.125 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.001935 g Volume = 0.000592 cm3 Porosity: 99.9409% V(tot) - V(min): 0.10020E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0064000 g log = -2.1938 Original solution: 1000.0103000 g Original solution / Rock added: 156251.61 (Water/Rock Ratio), log = 5.1938 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1136E-03 1.0073 0.1204E-03 0.1196E-03 CH4,gas 0.2362E-10 1.0129 0.2517E-10 0.2485E-10 H2,gas 0.6516E-05 1.0006 0.6859E-05 0.6855E-05 H2S,gas 0.1218E-06 0.9959 0.1276E-06 0.1281E-06 S2,gas 0.1232E-22 1.0000 0.1296E-22 0.1296E-22 CO,gas 0.2034E-12 1.0000 0.2140E-12 0.2140E-12 SO3,gas 0.1664E-34 1.0000 0.1751E-34 0.1751E-34 SO2,gas 0.4318E-17 1.0000 0.4543E-17 0.4543E-17 HCl,gas 0.1897E-14 1.0000 0.1996E-14 0.1996E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.83410E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.28 -5.92 -1.973 0.10107E+05 -3.919 3 CH4,gas 4.81 -7.79 -12.60 -3.150 0.21513E+05 -10.599 4 H2,gas 8.29 1.12 -7.16 -4.094 0.12232E+05 -5.164 5 H2S,gas -5.94 -14.84 -8.89 -4.447 0.15187E+05 -6.894 6 S2,gas -7.03 -31.92 -24.89 -3.829 0.42494E+05 -22.887 7 CO,gas 3.51 -11.16 -14.67 -4.514 0.25048E+05 -12.670 8 SO3,gas 17.43 -19.33 -36.76 -9.189 0.62761E+05 -34.757 9 SO2,gas 1.14 -18.21 -19.34 -5.158 0.33027E+05 -17.343 10 HCl,gas 5.48 -11.22 -16.70 -8.350 0.28515E+05 -14.700 21 andalusite 5.06 1.58 -3.48 -0.348 0.59419E+04 24 anhydrite -5.28 -9.35 -4.07 -2.037 0.69548E+04 35 aragonite 0.99 -2.31 -3.29 -1.097 0.56213E+04 36 brucite 12.58 8.93 -3.65 -0.730 0.62301E+04 37 calcite 0.83 -2.31 -3.14 -1.046 0.53600E+04 40 carpholite-Mg 8.65 6.30 -2.35 -0.157 0.40123E+04 41 carpholite-Fe 6.78 4.23 -2.55 -0.170 0.43538E+04 50 chloritoid-Mg 13.26 10.51 -2.75 -0.183 0.46971E+04 51 chloritoid-Fe 9.24 8.44 -0.80 -0.053 0.13589E+04 52 chloritoid-Mn 11.46 9.22 -2.24 -0.149 0.38271E+04 54 coesite -2.37 -4.21 -1.84 -0.613 0.31425E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.21 -1.66 -0.554 0.28353E+04 78 fayalite 14.08 9.51 -4.57 -0.653 0.77997E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.16 -4.03 -0.336 0.68855E+04 92 hercynite 17.34 12.65 -4.69 -0.313 0.80114E+04 98 kaolinite -1.27 -2.63 -1.35 -0.123 0.23123E+04 99 kyanite 4.93 1.58 -3.35 -0.335 0.57187E+04 101 laumontite 2.97 -1.07 -4.04 -0.270 0.69065E+04 102 lawsonite 9.68 7.35 -2.33 -0.155 0.39770E+04 105 lizardite 23.29 18.36 -4.92 -0.410 0.84063E+04 106 magnesite 0.71 -3.35 -4.06 -1.355 0.69390E+04 107 magnetite 20.13 19.46 -0.67 -0.055 0.11522E+04 110 magnesioferrite 26.26 21.53 -4.73 -0.386 0.80793E+04 113 margarite 17.45 13.14 -4.31 -0.172 0.73600E+04 121 paragonite 4.34 -0.39 -4.73 -0.278 0.80690E+04 128 periclase-Fe 11.64 6.86 -4.78 -1.195 0.81596E+04 142 pyrite -21.23 -23.94 -2.71 -0.638 0.46290E+04 143 pyrrhotite -4.24 -7.98 -3.73 -1.244 0.63738E+04 144 pyrrhotiteFe0.875 -6.00 -8.97 -2.97 -1.093 0.50750E+04 145 pyroxmangite 7.42 3.43 -3.99 -0.797 0.68067E+04 146 pyrophyllite -6.10 -11.05 -4.95 -0.309 0.84500E+04 147 quartz -2.98 -4.21 -1.23 -0.409 0.20964E+04 152 rhodochrosite -0.96 -4.64 -3.68 -1.228 0.62913E+04 153 rhodonite 7.46 3.43 -4.03 -0.807 0.68859E+04 156 siderite -2.59 -5.42 -2.83 -0.945 0.48397E+04 157 sillimanite 5.32 1.58 -3.74 -0.374 0.63841E+04 169 sudoite 21.22 16.81 -4.41 -0.142 0.75220E+04 178 topaz-H 4.67 1.58 -3.09 -0.280 0.52678E+04 179 tridymite -2.61 -4.21 -1.60 -0.532 0.27237E+04 182 troilite-low -4.39 -7.98 -3.58 -1.194 0.61170E+04 190 wollastonite 10.48 5.77 -4.72 -0.943 0.80508E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.21 -1.42 -0.472 0.24167E+04 206 nontronite-Ca 3.28 -0.25 -3.53 -0.229 0.60274E+04 207 nontronite-H 2.60 -1.90 -4.49 -0.301 0.76704E+04 208 nontronite-K 3.40 -1.41 -4.82 -0.309 0.82278E+04 209 nontronite-Mg 3.14 -0.42 -3.56 -0.231 0.60831E+04 210 nontronite-Na 3.58 -0.72 -4.31 -0.276 0.73544E+04 215 gypsum -4.92 -9.35 -4.43 -1.107 0.75616E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.86 -2.96 -0.741 0.50607E+04 241 silica-amorphous -2.08 -4.21 -2.13 -0.710 0.36369E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0064000 g New total amount of reactant added: 0.0066000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.9764E-15 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0066000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2643290E-03 Osmotic coef. = 0.9902 True ionic strength = .2665843E-03 Chg. balance for total moles = 0.9764E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.45896E-07 -7.3382 0.44113E-07 -7.3554 0.96114E+00 -0.0172 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13259E-03 -3.8775 0.96102E+00 -0.0173 4 SO4-- 0.25334E-04 -4.5963 0.22804E-04 -4.6420 0.90014E+00 -0.0457 5 HCO3- 0.12005E-04 -4.9207 0.11537E-04 -4.9379 0.96105E+00 -0.0173 6 HS- 0.25727E-07 -7.5896 0.24724E-07 -7.6069 0.96102E+00 -0.0173 7 Al+++ 0.83752E-19 -19.0770 0.67573E-19 -19.1702 0.80682E+00 -0.0932 8 H4SiO4 0.63432E-04 -4.1977 0.63432E-04 -4.1977 0.10000E+01 0.0000 9 Ca++ 0.21843E-04 -4.6607 0.19659E-04 -4.7064 0.90001E+00 -0.0458 10 Mg++ 0.18214E-05 -5.7396 0.16391E-05 -5.7854 0.89993E+00 -0.0458 11 Fe++ 0.15224E-07 -7.8175 0.13701E-07 -7.8633 0.89995E+00 -0.0458 12 K+ 0.14008E-05 -5.8536 0.13462E-05 -5.8709 0.96105E+00 -0.0173 13 Na+ 0.16834E-03 -3.7738 0.16178E-03 -3.7911 0.96102E+00 -0.0173 14 Mn++ 0.10181E-06 -6.9922 0.91623E-07 -7.0380 0.89996E+00 -0.0458 15 HPO4-- 0.12197E-07 -7.9137 0.10979E-07 -7.9594 0.90014E+00 -0.0457 16 HSiO3- 0.14599E-05 -5.8357 0.14030E-05 -5.8530 0.96102E+00 -0.0173 17 Ca(HSiO3)+ 0.64299E-09 -9.1918 0.61795E-09 -9.2090 0.96106E+00 -0.0173 18 Mg(HSiO3)+ 0.66720E-10 -10.1757 0.64121E-10 -10.1930 0.96106E+00 -0.0173 19 NaHSiO3,aq 0.36049E-08 -8.4431 0.36049E-08 -8.4431 0.10000E+01 0.0000 20 AlO+ 0.46646E-11 -11.3312 0.44829E-11 -11.3484 0.96106E+00 -0.0173 21 AlOH+2 0.11007E-14 -14.9583 0.99062E-15 -15.0041 0.89998E+00 -0.0458 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.10712E-05 -5.9701 0.10294E-05 -5.9874 0.96099E+00 -0.0173 24 CH4,aq 0.12275E-13 -13.9110 0.12274E-13 -13.9110 0.99992E+00 0.0000 29 CO,aq 0.12461E-15 -15.9044 0.12461E-15 -15.9044 0.10000E+01 0.0000 30 CO2,aq 0.10262E-05 -5.9888 0.10261E-05 -5.9888 0.99992E+00 0.0000 31 CO3-2 0.26865E-07 -7.5708 0.24181E-07 -7.6165 0.90010E+00 -0.0457 32 CaCO3,aq 0.58223E-08 -8.2349 0.58223E-08 -8.2349 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.59464E-08 -8.2257 0.57148E-08 -8.2430 0.96106E+00 -0.0173 34 CaCl+ 0.43217E-08 -8.3643 0.41534E-08 -8.3816 0.96106E+00 -0.0173 35 CaCl2,aq 0.12822E-12 -12.8921 0.12822E-12 -12.8921 0.10000E+01 0.0000 36 CaOH+ 0.32698E-07 -7.4855 0.31424E-07 -7.5027 0.96106E+00 -0.0173 37 CaSO4,aq 0.13968E-06 -6.8549 0.13968E-06 -6.8549 0.10000E+01 0.0000 38 HCl,aq 0.11001E-11 -11.9586 0.11001E-11 -11.9586 0.10000E+01 0.0000 43 FeCl+ 0.29439E-11 -11.5311 0.28292E-11 -11.5483 0.96106E+00 -0.0173 44 FeCl2,aq 0.11634E-19 -19.9343 0.11634E-19 -19.9343 0.10000E+01 0.0000 46 FeO,aq 0.27842E-09 -9.5553 0.27842E-09 -9.5553 0.10000E+01 0.0000 47 FeOH+ 0.10714E-07 -7.9701 0.10297E-07 -7.9873 0.96106E+00 -0.0173 48 HFeO2- 0.70641E-10 -10.1509 0.67888E-10 -10.1682 0.96102E+00 -0.0173 49 FeO+ 0.37969E-12 -12.4206 0.36490E-12 -12.4378 0.96106E+00 -0.0173 50 FeOH+2 0.33282E-17 -17.4778 0.29953E-17 -17.5236 0.89998E+00 -0.0458 51 FeO2- 0.38351E-10 -10.4162 0.36856E-10 -10.4335 0.96102E+00 -0.0173 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.47156E-08 -8.3265 0.47152E-08 -8.3265 0.99992E+00 0.0000 54 KCl,aq 0.31604E-11 -11.5003 0.31604E-11 -11.5003 0.10000E+01 0.0000 55 KHSO4,aq 0.36238E-17 -17.4408 0.36238E-17 -17.4408 0.10000E+01 0.0000 56 KOH,aq 0.13304E-10 -10.8760 0.13304E-10 -10.8760 0.10000E+01 0.0000 57 KSO4- 0.49214E-09 -9.3079 0.47296E-09 -9.3252 0.96102E+00 -0.0173 58 MgCO3,aq 0.12130E-09 -9.9161 0.12130E-09 -9.9161 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.50557E-09 -9.2962 0.48588E-09 -9.3135 0.96106E+00 -0.0173 60 MgCl+ 0.32712E-09 -9.4853 0.31438E-09 -9.5025 0.96106E+00 -0.0173 61 MgOH+ 0.15103E-07 -7.8209 0.14515E-07 -7.8382 0.96106E+00 -0.0173 63 MnO,aq 0.49704E-10 -10.3036 0.49704E-10 -10.3036 0.10000E+01 0.0000 64 MnOH+ 0.66559E-08 -8.1768 0.63967E-08 -8.1940 0.96106E+00 -0.0173 65 MnO2-2 0.98140E-18 -18.0082 0.88336E-18 -18.0539 0.90010E+00 -0.0457 66 HMnO2- 0.87852E-14 -14.0562 0.84427E-14 -14.0735 0.96102E+00 -0.0173 69 MnCl+ 0.76501E-10 -10.1163 0.73521E-10 -10.1336 0.96106E+00 -0.0173 70 MnSO4,aq 0.59213E-09 -9.2276 0.59213E-09 -9.2276 0.10000E+01 0.0000 71 NaCl,aq 0.70039E-08 -8.1547 0.70039E-08 -8.1547 0.10000E+01 0.0000 72 NaOH,aq 0.16115E-08 -8.7928 0.16115E-08 -8.7928 0.10000E+01 0.0000 74 OH- 0.14150E-04 -4.8492 0.13598E-04 -4.8665 0.96099E+00 -0.0173 79 HPO3-2 0.18166E-18 -18.7407 0.16351E-18 -18.7864 0.90010E+00 -0.0457 81 H2PO3- 0.14743E-19 -19.8314 0.14169E-19 -19.8487 0.96102E+00 -0.0173 82 H3PO4,aq 0.13754E-12 -12.8616 0.13754E-12 -12.8616 0.10000E+01 0.0000 83 H2PO4- 0.88352E-08 -8.0538 0.84909E-08 -8.0710 0.96104E+00 -0.0173 84 PO4-3 0.26913E-12 -12.5700 0.21735E-12 -12.6628 0.80761E+00 -0.0928 87 H2P2O7-2 0.62689E-17 -17.2028 0.56426E-17 -17.2485 0.90010E+00 -0.0457 88 HP2O7-3 0.32509E-16 -16.4880 0.26229E-16 -16.5812 0.80683E+00 -0.0932 89 P2O7-4 0.21177E-18 -18.6741 0.14669E-18 -18.8336 0.69268E+00 -0.1595 90 H2S,aq 0.32772E-08 -8.4845 0.32769E-08 -8.4845 0.99992E+00 0.0000 91 S2-2 0.31677E-17 -17.4993 0.28513E-17 -17.5450 0.90010E+00 -0.0457 96 SO2,aq 0.87663E-18 -18.0572 0.87663E-18 -18.0572 0.10000E+01 0.0000 97 SO3-2 0.16284E-13 -13.7883 0.14661E-13 -13.8338 0.90036E+00 -0.0456 98 HSO3- 0.39383E-13 -13.4047 0.37848E-13 -13.4220 0.96102E+00 -0.0173 99 HSO4- 0.97118E-09 -9.0127 0.93337E-09 -9.0299 0.96107E+00 -0.0172 101 S2O3-2 0.97844E-15 -15.0095 0.88070E-15 -15.0552 0.90010E+00 -0.0457 Charge balance for all species = 0.9764E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4589631E-07 -.1897672E-04 -.1912706E-01 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9999808E+06 0.0000 3 Cl- 0.1379628E-03 0.1379745E-03 0.4891527E+01 3.4779 4 SO4-- 0.2533380E-04 0.2547438E-04 0.2447068E+01 10.0689 5 HCO3- 0.1200459E-04 0.1307003E-04 0.7974831E+00 2.4175 6 HS- 0.2572686E-07 0.3015269E-07 0.9971925E-03 -0.2514 7 Al+++ 0.8375218E-19 0.1091505E-05 0.2944995E-01 2.8961 8 H4SiO4 0.6343192E-04 0.6489611E-04 0.6237408E+01 -4.1977 9 Ca++ 0.2184291E-04 0.2203202E-04 0.8829840E+00 10.0044 10 Mg++ 0.1821362E-05 0.1837486E-05 0.4467219E-01 8.9255 11 Fe++ 0.1522389E-07 0.2653202E-07 0.1481708E-02 6.8476 12 K+ 0.1400769E-05 0.1401277E-05 0.5479180E-01 1.4846 13 Na+ 0.1683438E-03 0.1683560E-03 0.3870405E+01 3.5644 14 Mn++ 0.1018068E-06 0.1091811E-06 0.5998087E-02 7.6729 15 HPO4-- 0.1219693E-07 0.2103252E-07 0.2018646E-02 6.7514 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9624620E-04 -.1897667E-04 -.7726953E-04 0.0000000E+00 2 H2O 0.5550817E+02 0.5550812E+02 0.4512156E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2568738E-04 0.2547432E-04 0.2130611E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1829085E-06 0.3015261E-07 -.2130611E-06 0.0000000E+00 7 Al+++ 0.2152089E-04 0.1091503E-05 0.2042939E-04 0.0000000E+00 8 H4SiO4 0.6872437E-04 0.6489595E-04 0.3828422E-05 0.0000000E+00 9 Ca++ 0.2206200E-04 0.2203196E-04 0.3003923E-07 0.0000000E+00 10 Mg++ 0.5238095E-05 0.1837481E-05 0.3400614E-05 0.0000000E+00 11 Fe++ 0.4705857E-05 0.2653196E-07 0.4679325E-05 0.0000000E+00 12 K+ 0.1401274E-05 0.1401274E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1683556E-03 0.1683556E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1144347E-06 0.1091808E-06 0.5253931E-08 0.0000000E+00 15 HPO4-- 0.3905601E-07 0.2103247E-07 0.1802354E-07 0.0000000E+00 Chg. balance for solid moles: 0.1687E-19 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0066000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6008E-08 -8.221 0.3018E-05 -5.520 0.1498 0.9590E-06 clinochlore 0.6801E-06 -6.167 0.3780E-03 -3.422 18.76 0.1438E-03 daphnite 0.5950E-06 -6.226 0.4245E-03 -3.372 21.07 0.1286E-03 chlorite-Mn 0.1051E-08 -8.978 0.7450E-06 -6.128 0.3697E-01 0.2374E-06 diaspore 0.1788E-04 -4.748 0.1072E-02 -2.970 53.23 0.3193E-03 hematite 0.8522E-06 -6.069 0.1361E-03 -3.866 6.755 0.2580E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5330E+00 0.5330E+00 1.0000 -0.273 daphnite 0.4662E+00 0.4662E+00 1.0000 -0.331 chlorite-Mn 0.8234E-03 0.8234E-03 1.0000 -3.084 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.002015 g Volume = 0.000619 cm3 Porosity: 99.9383% V(tot) - V(min): 0.10020E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0066000 g log = -2.1805 Original solution: 1000.0103000 g Original solution / Rock added: 151516.71 (Water/Rock Ratio), log = 5.1805 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1108E-03 1.0073 0.1175E-03 0.1166E-03 CH4,gas 0.1821E-10 1.0129 0.1941E-10 0.1916E-10 H2,gas 0.6144E-05 1.0006 0.6467E-05 0.6464E-05 H2S,gas 0.9122E-07 0.9959 0.9557E-07 0.9597E-07 S2,gas 0.7775E-23 1.0000 0.8180E-23 0.8180E-23 CO,gas 0.1870E-12 1.0000 0.1968E-12 0.1968E-12 SO3,gas 0.1577E-34 1.0000 0.1659E-34 0.1659E-34 SO2,gas 0.3858E-17 1.0000 0.4059E-17 0.4059E-17 HCl,gas 0.1846E-14 1.0000 0.1942E-14 0.1942E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 0.60662E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.29 -5.93 -1.977 0.10126E+05 -3.930 3 CH4,gas 4.81 -7.90 -12.71 -3.178 0.21705E+05 -10.712 4 H2,gas 8.29 1.10 -7.19 -4.108 0.12275E+05 -5.189 5 H2S,gas -5.94 -14.96 -9.02 -4.510 0.15401E+05 -7.020 6 S2,gas -7.03 -32.12 -25.09 -3.860 0.42836E+05 -23.087 7 CO,gas 3.51 -11.20 -14.71 -4.525 0.25110E+05 -12.706 8 SO3,gas 17.43 -19.35 -36.78 -9.195 0.62801E+05 -34.780 9 SO2,gas 1.14 -18.26 -19.39 -5.171 0.33111E+05 -17.392 10 HCl,gas 5.48 -11.23 -16.71 -8.356 0.28535E+05 -14.712 21 andalusite 5.06 1.59 -3.47 -0.347 0.59213E+04 24 anhydrite -5.28 -9.35 -4.07 -2.034 0.69472E+04 35 aragonite 0.99 -2.29 -3.28 -1.092 0.55922E+04 36 brucite 12.58 8.93 -3.65 -0.730 0.62342E+04 37 calcite 0.83 -2.29 -3.12 -1.041 0.53309E+04 40 carpholite-Mg 8.65 6.32 -2.33 -0.155 0.39752E+04 41 carpholite-Fe 6.78 4.24 -2.54 -0.169 0.43344E+04 50 chloritoid-Mg 13.26 10.52 -2.74 -0.183 0.46806E+04 51 chloritoid-Fe 9.24 8.44 -0.80 -0.053 0.13601E+04 52 chloritoid-Mn 11.46 9.27 -2.20 -0.146 0.37493E+04 54 coesite -2.37 -4.20 -1.83 -0.609 0.31218E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.20 -1.65 -0.549 0.28147E+04 78 fayalite 14.08 9.50 -4.58 -0.654 0.78226E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.15 -4.05 -0.337 0.69097E+04 92 hercynite 17.34 12.64 -4.70 -0.314 0.80332E+04 98 kaolinite -1.27 -2.60 -1.33 -0.121 0.22710E+04 99 kyanite 4.93 1.59 -3.34 -0.334 0.56981E+04 101 laumontite 2.97 -0.99 -3.97 -0.265 0.67764E+04 102 lawsonite 9.68 7.40 -2.28 -0.152 0.38882E+04 105 lizardite 23.29 18.38 -4.91 -0.409 0.83775E+04 106 magnesite 0.71 -3.37 -4.08 -1.359 0.69617E+04 107 magnetite 20.13 19.45 -0.69 -0.056 0.11740E+04 110 magnesioferrite 26.26 21.52 -4.73 -0.386 0.80835E+04 113 margarite 17.45 13.19 -4.26 -0.170 0.72711E+04 121 paragonite 4.34 -0.34 -4.68 -0.275 0.79860E+04 128 periclase-Fe 11.64 6.85 -4.79 -1.198 0.81814E+04 142 pyrite -21.23 -24.17 -2.95 -0.694 0.50359E+04 143 pyrrhotite -4.24 -8.11 -3.87 -1.290 0.66099E+04 144 pyrrhotiteFe0.875 -6.00 -9.11 -3.11 -1.142 0.53030E+04 145 pyroxmangite 7.42 3.48 -3.94 -0.788 0.67289E+04 146 pyrophyllite -6.10 -11.00 -4.90 -0.306 0.83676E+04 147 quartz -2.98 -4.20 -1.22 -0.405 0.20758E+04 152 rhodochrosite -0.96 -4.62 -3.66 -1.221 0.62526E+04 153 rhodonite 7.46 3.48 -3.99 -0.797 0.68081E+04 156 siderite -2.59 -5.45 -2.86 -0.953 0.48801E+04 157 sillimanite 5.32 1.59 -3.73 -0.373 0.63635E+04 169 sudoite 21.22 16.84 -4.37 -0.141 0.74684E+04 178 topaz-H 4.67 1.59 -3.07 -0.279 0.52472E+04 179 tridymite -2.61 -4.20 -1.58 -0.528 0.27031E+04 182 troilite-low -4.39 -8.11 -3.72 -1.240 0.63530E+04 190 wollastonite 10.48 5.81 -4.68 -0.935 0.79826E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.20 -1.40 -0.468 0.23961E+04 206 nontronite-Ca 3.28 -0.20 -3.48 -0.226 0.59439E+04 207 nontronite-H 2.60 -1.85 -4.45 -0.298 0.75947E+04 208 nontronite-K 3.40 -1.36 -4.77 -0.306 0.81380E+04 209 nontronite-Mg 3.14 -0.38 -3.52 -0.228 0.60082E+04 210 nontronite-Na 3.58 -0.68 -4.26 -0.273 0.72717E+04 215 gypsum -4.92 -9.35 -4.42 -1.106 0.75539E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.85 -2.98 -0.744 0.50825E+04 241 silica-amorphous -2.08 -4.20 -2.12 -0.706 0.36163E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0066000 g New total amount of reactant added: 0.0068000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.9764E-15 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0068000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2648583E-03 Osmotic coef. = 0.9902 True ionic strength = .2672387E-03 Chg. balance for total moles = 0.9764E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.44667E-07 -7.3500 0.42930E-07 -7.3672 0.96111E+00 -0.0172 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13258E-03 -3.8775 0.96100E+00 -0.0173 4 SO4-- 0.25339E-04 -4.5962 0.22806E-04 -4.6419 0.90005E+00 -0.0457 5 HCO3- 0.12029E-04 -4.9198 0.11560E-04 -4.9370 0.96102E+00 -0.0173 6 HS- 0.19797E-07 -7.7034 0.19025E-07 -7.7207 0.96100E+00 -0.0173 7 Al+++ 0.77213E-19 -19.1123 0.62283E-19 -19.2056 0.80663E+00 -0.0933 8 H4SiO4 0.65181E-04 -4.1859 0.65181E-04 -4.1859 0.10000E+01 0.0000 9 Ca++ 0.22066E-04 -4.6563 0.19857E-04 -4.7021 0.89992E+00 -0.0458 10 Mg++ 0.17163E-05 -5.7654 0.15444E-05 -5.8113 0.89984E+00 -0.0458 11 Fe++ 0.14003E-07 -7.8538 0.12600E-07 -7.8996 0.89986E+00 -0.0458 12 K+ 0.14432E-05 -5.8407 0.13870E-05 -5.8579 0.96103E+00 -0.0173 13 Na+ 0.16859E-03 -3.7732 0.16202E-03 -3.7904 0.96099E+00 -0.0173 14 Mn++ 0.10404E-06 -6.9828 0.93620E-07 -7.0286 0.89987E+00 -0.0458 15 HPO4-- 0.11569E-07 -7.9367 0.10413E-07 -7.9824 0.90005E+00 -0.0457 16 HSiO3- 0.15415E-05 -5.8121 0.14814E-05 -5.8293 0.96100E+00 -0.0173 17 Ca(HSiO3)+ 0.68579E-09 -9.1638 0.65907E-09 -9.1811 0.96103E+00 -0.0173 18 Mg(HSiO3)+ 0.66378E-10 -10.1780 0.63791E-10 -10.1952 0.96103E+00 -0.0173 19 NaHSiO3,aq 0.38119E-08 -8.4189 0.38119E-08 -8.4189 0.10000E+01 0.0000 20 AlO+ 0.45397E-11 -11.3430 0.43627E-11 -11.3602 0.96103E+00 -0.0173 21 AlOH+2 0.10426E-14 -14.9819 0.93822E-15 -15.0277 0.89989E+00 -0.0458 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.11007E-05 -5.9583 0.10577E-05 -5.9756 0.96096E+00 -0.0173 24 CH4,aq 0.94634E-14 -14.0240 0.94627E-14 -14.0240 0.99992E+00 0.0000 29 CO,aq 0.11458E-15 -15.9409 0.11458E-15 -15.9409 0.10000E+01 0.0000 30 CO2,aq 0.10007E-05 -5.9997 0.10006E-05 -5.9997 0.99992E+00 0.0000 31 CO3-2 0.27664E-07 -7.5581 0.24898E-07 -7.6038 0.90001E+00 -0.0458 32 CaCO3,aq 0.60552E-08 -8.2179 0.60552E-08 -8.2179 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.60186E-08 -8.2205 0.57841E-08 -8.2378 0.96103E+00 -0.0173 34 CaCl+ 0.43653E-08 -8.3600 0.41952E-08 -8.3772 0.96103E+00 -0.0173 35 CaCl2,aq 0.12951E-12 -12.8877 0.12951E-12 -12.8877 0.10000E+01 0.0000 36 CaOH+ 0.33938E-07 -7.4693 0.32616E-07 -7.4866 0.96103E+00 -0.0173 37 CaSO4,aq 0.14111E-06 -6.8505 0.14111E-06 -6.8505 0.10000E+01 0.0000 38 HCl,aq 0.10706E-11 -11.9704 0.10706E-11 -11.9704 0.10000E+01 0.0000 43 FeCl+ 0.27075E-11 -11.5674 0.26020E-11 -11.5847 0.96103E+00 -0.0173 44 FeCl2,aq 0.10699E-19 -19.9707 0.10699E-19 -19.9707 0.10000E+01 0.0000 46 FeO,aq 0.27036E-09 -9.5681 0.27036E-09 -9.5681 0.10000E+01 0.0000 47 FeOH+ 0.10125E-07 -7.9946 0.97306E-08 -8.0119 0.96103E+00 -0.0173 48 HFeO2- 0.70488E-10 -10.1519 0.67739E-10 -10.1692 0.96100E+00 -0.0173 49 FeO+ 0.36952E-12 -12.4324 0.35512E-12 -12.4496 0.96103E+00 -0.0173 50 FeOH+2 0.31525E-17 -17.5014 0.28369E-17 -17.5472 0.89989E+00 -0.0458 51 FeO2- 0.39408E-10 -10.4044 0.37871E-10 -10.4217 0.96100E+00 -0.0173 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44466E-08 -8.3520 0.44462E-08 -8.3520 0.99992E+00 0.0000 54 KCl,aq 0.32560E-11 -11.4873 0.32560E-11 -11.4873 0.10000E+01 0.0000 55 KHSO4,aq 0.36338E-17 -17.4396 0.36338E-17 -17.4396 0.10000E+01 0.0000 56 KOH,aq 0.14085E-10 -10.8513 0.14085E-10 -10.8513 0.10000E+01 0.0000 57 KSO4- 0.50711E-09 -9.2949 0.48733E-09 -9.3122 0.96100E+00 -0.0173 58 MgCO3,aq 0.11768E-09 -9.9293 0.11768E-09 -9.9293 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.47732E-09 -9.3212 0.45872E-09 -9.3385 0.96103E+00 -0.0173 60 MgCl+ 0.30821E-09 -9.5112 0.29620E-09 -9.5284 0.96103E+00 -0.0173 61 MgOH+ 0.14623E-07 -7.8350 0.14053E-07 -7.8522 0.96103E+00 -0.0173 63 MnO,aq 0.53624E-10 -10.2706 0.53624E-10 -10.2706 0.10000E+01 0.0000 64 MnOH+ 0.69885E-08 -8.1556 0.67162E-08 -8.1729 0.96103E+00 -0.0173 65 MnO2-2 0.11181E-17 -17.9515 0.10063E-17 -17.9973 0.90001E+00 -0.0458 66 HMnO2- 0.97394E-14 -14.0115 0.93595E-14 -14.0287 0.96100E+00 -0.0173 69 MnCl+ 0.78168E-10 -10.1070 0.75122E-10 -10.1242 0.96103E+00 -0.0173 70 MnSO4,aq 0.60510E-09 -9.2182 0.60510E-09 -9.2182 0.10000E+01 0.0000 71 NaCl,aq 0.70140E-08 -8.1540 0.70140E-08 -8.1540 0.10000E+01 0.0000 72 NaOH,aq 0.16583E-08 -8.7803 0.16583E-08 -8.7803 0.10000E+01 0.0000 74 OH- 0.14540E-04 -4.8374 0.13972E-04 -4.8547 0.96096E+00 -0.0173 79 HPO3-2 0.16248E-18 -18.7892 0.14623E-18 -18.8350 0.90001E+00 -0.0458 81 H2PO3- 0.12832E-19 -19.8917 0.12331E-19 -19.9090 0.96100E+00 -0.0173 82 H3PO4,aq 0.12354E-12 -12.9082 0.12354E-12 -12.9082 0.10000E+01 0.0000 83 H2PO4- 0.81549E-08 -8.0886 0.78370E-08 -8.1059 0.96101E+00 -0.0173 84 PO4-3 0.26234E-12 -12.5811 0.21182E-12 -12.6740 0.80742E+00 -0.0929 87 H2P2O7-2 0.53409E-17 -17.2724 0.48069E-17 -17.3181 0.90001E+00 -0.0458 88 HP2O7-3 0.28464E-16 -16.5457 0.22960E-16 -16.6390 0.80664E+00 -0.0933 89 P2O7-4 0.19056E-18 -18.7200 0.13194E-18 -18.8796 0.69239E+00 -0.1597 90 H2S,aq 0.24541E-08 -8.6101 0.24539E-08 -8.6101 0.99992E+00 0.0000 91 S2-2 0.19893E-17 -17.7013 0.17904E-17 -17.7471 0.90001E+00 -0.0458 96 SO2,aq 0.78298E-18 -18.1063 0.78298E-18 -18.1063 0.10000E+01 0.0000 97 SO3-2 0.15358E-13 -13.8137 0.13826E-13 -13.8593 0.90027E+00 -0.0456 98 HSO3- 0.36146E-13 -13.4419 0.34736E-13 -13.4592 0.96100E+00 -0.0173 99 HSO4- 0.94526E-09 -9.0244 0.90845E-09 -9.0417 0.96105E+00 -0.0173 101 S2O3-2 0.73286E-15 -15.1350 0.65958E-15 -15.1807 0.90001E+00 -0.0458 Charge balance for all species = 0.9764E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4466703E-07 -.1959668E-04 -.1975193E-01 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9999806E+06 0.0000 3 Cl- 0.1379628E-03 0.1379745E-03 0.4891526E+01 3.4897 4 SO4-- 0.2533912E-04 0.2548120E-04 0.2447723E+01 10.0925 5 HCO3- 0.1202903E-04 0.1307003E-04 0.7974830E+00 2.4302 6 HS- 0.1979694E-07 0.2333233E-07 0.7716334E-03 -0.3534 7 Al+++ 0.7721340E-19 0.1121042E-05 0.3024688E-01 2.8961 8 H4SiO4 0.6518070E-04 0.6672675E-04 0.6413356E+01 -4.1859 9 Ca++ 0.2206573E-04 0.2225790E-04 0.8920364E+00 10.0324 10 Mg++ 0.1716273E-05 0.1731865E-05 0.4210437E-01 8.9232 11 Fe++ 0.1400270E-07 0.2471468E-07 0.1380217E-02 6.8349 12 K+ 0.1443216E-05 0.1443741E-05 0.5645216E-01 1.5093 13 Na+ 0.1685946E-03 0.1686071E-03 0.3876176E+01 3.5768 14 Mn++ 0.1040367E-06 0.1117621E-06 0.6139877E-02 7.7058 15 HPO4-- 0.1156883E-07 0.1972412E-07 0.1893068E-02 6.7520 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9955790E-04 -.1959663E-04 -.7996128E-04 0.0000000E+00 2 H2O 0.5550816E+02 0.5550812E+02 0.4652535E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2569292E-04 0.2548114E-04 0.2117834E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1884512E-06 0.2333227E-07 -.2117834E-06 0.0000000E+00 7 Al+++ 0.2217304E-04 0.1121039E-05 0.2105200E-04 0.0000000E+00 8 H4SiO4 0.7080692E-04 0.6672658E-04 0.4080349E-05 0.0000000E+00 9 Ca++ 0.2229203E-04 0.2225784E-04 0.3419242E-07 0.0000000E+00 10 Mg++ 0.5396825E-05 0.1731861E-05 0.3664965E-05 0.0000000E+00 11 Fe++ 0.4848458E-05 0.2471462E-07 0.4823744E-05 0.0000000E+00 12 K+ 0.1443737E-05 0.1443737E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1686067E-03 0.1686067E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1179025E-06 0.1117618E-06 0.6140678E-08 0.0000000E+00 15 HPO4-- 0.4023952E-07 0.1972407E-07 0.2051545E-07 0.0000000E+00 Chg. balance for solid moles: 0.2311E-19 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0068000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6838E-08 -8.165 0.3435E-05 -5.464 0.1641 0.1092E-05 clinochlore 0.7330E-06 -6.135 0.4074E-03 -3.390 19.46 0.1550E-03 daphnite 0.6259E-06 -6.203 0.4466E-03 -3.350 21.33 0.1353E-03 chlorite-Mn 0.1228E-08 -8.911 0.8707E-06 -6.060 0.4159E-01 0.2775E-06 diaspore 0.1833E-04 -4.737 0.1100E-02 -2.959 52.53 0.3274E-03 hematite 0.8471E-06 -6.072 0.1353E-03 -3.869 6.463 0.2564E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5389E+00 0.5389E+00 1.0000 -0.268 daphnite 0.4602E+00 0.4602E+00 1.0000 -0.337 chlorite-Mn 0.9030E-03 0.9030E-03 1.0000 -3.044 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.002093 g Volume = 0.000645 cm3 Porosity: 99.9357% V(tot) - V(min): 0.10021E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0068000 g log = -2.1675 Original solution: 1000.0103000 g Original solution / Rock added: 147060.34 (Water/Rock Ratio), log = 5.1675 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1081E-03 1.0073 0.1145E-03 0.1137E-03 CH4,gas 0.1404E-10 1.0129 0.1496E-10 0.1477E-10 H2,gas 0.5793E-05 1.0006 0.6098E-05 0.6095E-05 H2S,gas 0.6831E-07 0.9959 0.7157E-07 0.7186E-07 S2,gas 0.4904E-23 1.0000 0.5159E-23 0.5159E-23 CO,gas 0.1720E-12 1.0000 0.1809E-12 0.1809E-12 SO3,gas 0.1494E-34 1.0000 0.1571E-34 0.1571E-34 SO2,gas 0.3446E-17 1.0000 0.3625E-17 0.3625E-17 HCl,gas 0.1797E-14 1.0000 0.1890E-14 0.1890E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.30 -5.94 -1.980 0.10144E+05 -3.941 3 CH4,gas 4.81 -8.02 -12.82 -3.206 0.21898E+05 -10.825 4 H2,gas 8.29 1.07 -7.21 -4.123 0.12319E+05 -5.215 5 H2S,gas -5.94 -15.09 -9.15 -4.573 0.15615E+05 -7.145 6 S2,gas -7.03 -32.32 -25.29 -3.890 0.43178E+05 -23.287 7 CO,gas 3.51 -11.23 -14.74 -4.536 0.25172E+05 -12.742 8 SO3,gas 17.43 -19.38 -36.80 -9.201 0.62841E+05 -34.804 9 SO2,gas 1.14 -18.30 -19.44 -5.184 0.33194E+05 -17.441 10 HCl,gas 5.48 -11.24 -16.72 -8.362 0.28555E+05 -14.723 21 andalusite 5.06 1.61 -3.46 -0.346 0.59012E+04 24 anhydrite -5.28 -9.34 -4.06 -2.032 0.69396E+04 35 aragonite 0.99 -2.27 -3.26 -1.086 0.55631E+04 36 brucite 12.58 8.92 -3.65 -0.731 0.62380E+04 37 calcite 0.83 -2.27 -3.11 -1.035 0.53018E+04 40 carpholite-Mg 8.65 6.34 -2.31 -0.154 0.39387E+04 41 carpholite-Fe 6.78 4.26 -2.53 -0.169 0.43158E+04 50 chloritoid-Mg 13.26 10.53 -2.73 -0.182 0.46643E+04 51 chloritoid-Fe 9.24 8.44 -0.80 -0.053 0.13617E+04 52 chloritoid-Mn 11.46 9.31 -2.15 -0.143 0.36729E+04 54 coesite -2.37 -4.19 -1.82 -0.606 0.31017E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.19 -1.64 -0.546 0.27946E+04 78 fayalite 14.08 9.48 -4.60 -0.656 0.78460E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.13 -4.06 -0.338 0.69347E+04 92 hercynite 17.34 12.63 -4.72 -0.314 0.80549E+04 98 kaolinite -1.27 -2.58 -1.31 -0.119 0.22307E+04 99 kyanite 4.93 1.61 -3.33 -0.333 0.56779E+04 101 laumontite 2.97 -0.92 -3.89 -0.260 0.66480E+04 102 lawsonite 9.68 7.45 -2.23 -0.148 0.38001E+04 105 lizardite 23.29 18.40 -4.89 -0.407 0.83487E+04 106 magnesite 0.71 -3.38 -4.09 -1.363 0.69842E+04 107 magnetite 20.13 19.43 -0.70 -0.057 0.11957E+04 110 magnesioferrite 26.26 21.52 -4.74 -0.387 0.80873E+04 113 margarite 17.45 13.24 -4.21 -0.168 0.71830E+04 121 paragonite 4.34 -0.29 -4.63 -0.272 0.79042E+04 128 periclase-Fe 11.64 6.83 -4.80 -1.201 0.82032E+04 142 pyrite -21.23 -24.41 -3.19 -0.750 0.54430E+04 143 pyrrhotite -4.24 -8.25 -4.01 -1.336 0.68461E+04 144 pyrrhotiteFe0.875 -6.00 -9.24 -3.24 -1.191 0.55311E+04 145 pyroxmangite 7.42 3.52 -3.90 -0.779 0.66524E+04 146 pyrophyllite -6.10 -10.95 -4.85 -0.303 0.82869E+04 147 quartz -2.98 -4.19 -1.20 -0.401 0.20556E+04 152 rhodochrosite -0.96 -4.60 -3.64 -1.213 0.62150E+04 153 rhodonite 7.46 3.52 -3.94 -0.788 0.67317E+04 156 siderite -2.59 -5.47 -2.88 -0.961 0.49205E+04 157 sillimanite 5.32 1.61 -3.72 -0.372 0.63433E+04 169 sudoite 21.22 16.87 -4.34 -0.140 0.74156E+04 178 topaz-H 4.67 1.61 -3.06 -0.278 0.52270E+04 179 tridymite -2.61 -4.19 -1.57 -0.524 0.26829E+04 182 troilite-low -4.39 -8.25 -3.86 -1.286 0.65893E+04 188 wairakite 4.06 -0.92 -4.98 -0.293 0.84988E+04 190 wollastonite 10.48 5.85 -4.64 -0.927 0.79146E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.19 -1.39 -0.464 0.23759E+04 206 nontronite-Ca 3.28 -0.15 -3.43 -0.223 0.58620E+04 207 nontronite-H 2.60 -1.81 -4.40 -0.295 0.75207E+04 208 nontronite-K 3.40 -1.31 -4.71 -0.303 0.80501E+04 209 nontronite-Mg 3.14 -0.34 -3.48 -0.225 0.59348E+04 210 nontronite-Na 3.58 -0.63 -4.21 -0.270 0.71907E+04 215 gypsum -4.92 -9.34 -4.42 -1.105 0.75464E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.83 -2.99 -0.747 0.51042E+04 241 silica-amorphous -2.08 -4.19 -2.11 -0.702 0.35961E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0068000 g New total amount of reactant added: 0.0070000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.9764E-15 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0070000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2654018E-03 Osmotic coef. = 0.9902 True ionic strength = .2679105E-03 Chg. balance for total moles = 0.9764E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.43471E-07 -7.3618 0.41779E-07 -7.3790 0.96108E+00 -0.0172 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13258E-03 -3.8775 0.96097E+00 -0.0173 4 SO4-- 0.25343E-04 -4.5961 0.22807E-04 -4.6419 0.89995E+00 -0.0458 5 HCO3- 0.12053E-04 -4.9189 0.11583E-04 -4.9362 0.96100E+00 -0.0173 6 HS- 0.15281E-07 -7.8159 0.14684E-07 -7.8332 0.96097E+00 -0.0173 7 Al+++ 0.71188E-19 -19.1476 0.57408E-19 -19.2410 0.80644E+00 -0.0934 8 H4SiO4 0.66937E-04 -4.1743 0.66937E-04 -4.1743 0.10000E+01 0.0000 9 Ca++ 0.22289E-04 -4.6519 0.20056E-04 -4.6978 0.89982E+00 -0.0458 10 Mg++ 0.16174E-05 -5.7912 0.14552E-05 -5.8371 0.89974E+00 -0.0459 11 Fe++ 0.12885E-07 -7.8899 0.11593E-07 -7.9358 0.89976E+00 -0.0459 12 K+ 0.14857E-05 -5.8281 0.14277E-05 -5.8454 0.96100E+00 -0.0173 13 Na+ 0.16885E-03 -3.7725 0.16225E-03 -3.7898 0.96097E+00 -0.0173 14 Mn++ 0.10617E-06 -6.9740 0.95529E-07 -7.0199 0.89977E+00 -0.0459 15 HPO4-- 0.10975E-07 -7.9596 0.98770E-08 -8.0054 0.89995E+00 -0.0458 16 HSiO3- 0.16267E-05 -5.7887 0.15632E-05 -5.8060 0.96097E+00 -0.0173 17 Ca(HSiO3)+ 0.73092E-09 -9.1361 0.70242E-09 -9.1534 0.96101E+00 -0.0173 18 Mg(HSiO3)+ 0.66003E-10 -10.1804 0.63429E-10 -10.1977 0.96101E+00 -0.0173 19 NaHSiO3,aq 0.40283E-08 -8.3949 0.40283E-08 -8.3949 0.10000E+01 0.0000 20 AlO+ 0.44181E-11 -11.3548 0.42458E-11 -11.3720 0.96101E+00 -0.0173 21 AlOH+2 0.98757E-15 -15.0054 0.88861E-15 -15.0513 0.89979E+00 -0.0459 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.11310E-05 -5.9465 0.10869E-05 -5.9638 0.96094E+00 -0.0173 24 CH4,aq 0.73183E-14 -14.1356 0.73176E-14 -14.1356 0.99992E+00 0.0000 29 CO,aq 0.10544E-15 -15.9770 0.10544E-15 -15.9770 0.10000E+01 0.0000 30 CO2,aq 0.97576E-06 -6.0107 0.97568E-06 -6.0107 0.99992E+00 0.0000 31 CO3-2 0.28484E-07 -7.5454 0.25633E-07 -7.5912 0.89991E+00 -0.0458 32 CaCO3,aq 0.62964E-08 -8.2009 0.62964E-08 -8.2009 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.60908E-08 -8.2153 0.58533E-08 -8.2326 0.96101E+00 -0.0173 34 CaCl+ 0.44089E-08 -8.3557 0.42370E-08 -8.3729 0.96101E+00 -0.0173 35 CaCl2,aq 0.13079E-12 -12.8834 0.13079E-12 -12.8834 0.10000E+01 0.0000 36 CaOH+ 0.35222E-07 -7.4532 0.33849E-07 -7.4705 0.96101E+00 -0.0173 37 CaSO4,aq 0.14252E-06 -6.8461 0.14252E-06 -6.8461 0.10000E+01 0.0000 38 HCl,aq 0.10419E-11 -11.9822 0.10419E-11 -11.9822 0.10000E+01 0.0000 43 FeCl+ 0.24910E-11 -11.6036 0.23939E-11 -11.6209 0.96101E+00 -0.0173 46 FeO,aq 0.26264E-09 -9.5806 0.26264E-09 -9.5806 0.10000E+01 0.0000 47 FeOH+ 0.95726E-08 -8.0190 0.91993E-08 -8.0362 0.96101E+00 -0.0173 48 HFeO2- 0.70362E-10 -10.1527 0.67616E-10 -10.1699 0.96097E+00 -0.0173 49 FeO+ 0.35963E-12 -12.4441 0.34560E-12 -12.4614 0.96101E+00 -0.0173 50 FeOH+2 0.29861E-17 -17.5249 0.26868E-17 -17.5708 0.89979E+00 -0.0459 51 FeO2- 0.40495E-10 -10.3926 0.38914E-10 -10.4099 0.96097E+00 -0.0173 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.41962E-08 -8.3771 0.41958E-08 -8.3772 0.99992E+00 0.0000 54 KCl,aq 0.33516E-11 -11.4748 0.33516E-11 -11.4748 0.10000E+01 0.0000 55 KHSO4,aq 0.36405E-17 -17.4388 0.36405E-17 -17.4388 0.10000E+01 0.0000 56 KOH,aq 0.14898E-10 -10.8269 0.14898E-10 -10.8269 0.10000E+01 0.0000 57 KSO4- 0.52205E-09 -9.2823 0.50167E-09 -9.2996 0.96097E+00 -0.0173 58 MgCO3,aq 0.11416E-09 -9.9425 0.11416E-09 -9.9425 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.45066E-09 -9.3462 0.43309E-09 -9.3634 0.96101E+00 -0.0173 60 MgCl+ 0.29042E-09 -9.5370 0.27909E-09 -9.5543 0.96101E+00 -0.0173 61 MgOH+ 0.14159E-07 -7.8490 0.13607E-07 -7.8663 0.96101E+00 -0.0173 63 MnO,aq 0.57773E-10 -10.2383 0.57773E-10 -10.2383 0.10000E+01 0.0000 64 MnOH+ 0.73276E-08 -8.1350 0.70419E-08 -8.1523 0.96101E+00 -0.0173 65 MnO2-2 0.12719E-17 -17.8955 0.11446E-17 -17.9413 0.89991E+00 -0.0458 66 HMnO2- 0.10782E-13 -13.9673 0.10361E-13 -13.9846 0.96097E+00 -0.0173 69 MnCl+ 0.79762E-10 -10.0982 0.76652E-10 -10.1155 0.96101E+00 -0.0173 70 MnSO4,aq 0.61746E-09 -9.2094 0.61746E-09 -9.2094 0.10000E+01 0.0000 71 NaCl,aq 0.70240E-08 -8.1534 0.70240E-08 -8.1534 0.10000E+01 0.0000 72 NaOH,aq 0.17065E-08 -8.7679 0.17065E-08 -8.7679 0.10000E+01 0.0000 74 OH- 0.14941E-04 -4.8256 0.14357E-04 -4.8429 0.96094E+00 -0.0173 79 HPO3-2 0.14546E-18 -18.8373 0.13090E-18 -18.8831 0.89991E+00 -0.0458 81 H2PO3- 0.11179E-19 -19.9516 0.10743E-19 -19.9689 0.96097E+00 -0.0173 82 H3PO4,aq 0.11099E-12 -12.9547 0.11099E-12 -12.9547 0.10000E+01 0.0000 83 H2PO4- 0.75284E-08 -8.1233 0.72347E-08 -8.1406 0.96099E+00 -0.0173 84 PO4-3 0.25576E-12 -12.5922 0.20646E-12 -12.6852 0.80723E+00 -0.0930 87 H2P2O7-2 0.45521E-17 -17.3418 0.40965E-17 -17.3876 0.89991E+00 -0.0458 88 HP2O7-3 0.24931E-16 -16.6033 0.20106E-16 -16.6967 0.80644E+00 -0.0934 89 P2O7-4 0.17154E-18 -18.7656 0.11872E-18 -18.9255 0.69209E+00 -0.1598 90 H2S,aq 0.18434E-08 -8.7344 0.18433E-08 -8.7344 0.99992E+00 0.0000 91 S2-2 0.12560E-17 -17.9010 0.11303E-17 -17.9468 0.89991E+00 -0.0458 96 SO2,aq 0.69984E-18 -18.1550 0.69984E-18 -18.1550 0.10000E+01 0.0000 97 SO3-2 0.14495E-13 -13.8388 0.13048E-13 -13.8845 0.90017E+00 -0.0457 98 HSO3- 0.33198E-13 -13.4789 0.31902E-13 -13.4962 0.96097E+00 -0.0173 99 HSO4- 0.91999E-09 -9.0362 0.88413E-09 -9.0535 0.96102E+00 -0.0173 101 S2O3-2 0.55058E-15 -15.2592 0.49547E-15 -15.3050 0.89991E+00 -0.0458 Charge balance for all species = 0.9768E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4347112E-07 -.2023332E-04 -.2039361E-01 0.0000 2 H2O 0.1000000E+01 0.5550826E+02 0.9999804E+06 0.0000 3 Cl- 0.1379627E-03 0.1379746E-03 0.4891525E+01 3.5015 4 SO4-- 0.2534283E-04 0.2548640E-04 0.2448221E+01 10.1161 5 HCO3- 0.1205284E-04 0.1307004E-04 0.7974829E+00 2.4428 6 HS- 0.1528052E-07 0.1814248E-07 0.5999976E-03 -0.4541 7 Al+++ 0.7118753E-19 0.1151384E-05 0.3106552E-01 2.8961 8 H4SiO4 0.6693748E-04 0.6856897E-04 0.6590418E+01 -4.1743 9 Ca++ 0.2228865E-04 0.2248392E-04 0.9010947E+00 10.0603 10 Mg++ 0.1617376E-05 0.1632456E-05 0.3968757E-01 8.9210 11 Fe++ 0.1288476E-07 0.2303718E-07 0.1286535E-02 6.8223 12 K+ 0.1485663E-05 0.1486204E-05 0.5811251E-01 1.5337 13 Na+ 0.1688454E-03 0.1688582E-03 0.3881947E+01 3.5892 14 Mn++ 0.1061697E-06 0.1142523E-06 0.6276685E-02 7.7382 15 HPO4-- 0.1097508E-07 0.1850386E-07 0.1775951E-02 6.7527 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1028696E-03 -.2023326E-04 -.8263634E-04 0.0000000E+00 2 H2O 0.5550816E+02 0.5550811E+02 0.4793281E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2569846E-04 0.2548633E-04 0.2121363E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1939939E-06 0.1814243E-07 -.2121363E-06 0.0000000E+00 7 Al+++ 0.2282519E-04 0.1151381E-05 0.2167381E-04 0.0000000E+00 8 H4SiO4 0.7288948E-04 0.6856879E-04 0.4320693E-05 0.0000000E+00 9 Ca++ 0.2252206E-04 0.2248386E-04 0.3819871E-07 0.0000000E+00 10 Mg++ 0.5555556E-05 0.1632452E-05 0.3923104E-05 0.0000000E+00 11 Fe++ 0.4991060E-05 0.2303712E-07 0.4968023E-05 0.0000000E+00 12 K+ 0.1486200E-05 0.1486200E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1688577E-03 0.1688577E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1213702E-06 0.1142520E-06 0.7118132E-08 0.0000000E+00 15 HPO4-- 0.4142304E-07 0.1850381E-07 0.2291922E-07 0.0000000E+00 Chg. balance for solid moles: -.9992E-20 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0070000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7640E-08 -8.117 0.3838E-05 -5.416 0.1768 0.1219E-05 clinochlore 0.7846E-06 -6.105 0.4361E-03 -3.360 20.09 0.1659E-03 daphnite 0.6542E-06 -6.184 0.4668E-03 -3.331 21.50 0.1414E-03 chlorite-Mn 0.1424E-08 -8.847 0.1009E-05 -5.996 0.4650E-01 0.3216E-06 diaspore 0.1879E-04 -4.726 0.1127E-02 -2.948 51.94 0.3356E-03 hematite 0.8485E-06 -6.071 0.1355E-03 -3.868 6.243 0.2568E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5448E+00 0.5448E+00 1.0000 -0.264 daphnite 0.4542E+00 0.4542E+00 1.0000 -0.343 chlorite-Mn 0.9885E-03 0.9885E-03 1.0000 -3.005 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.002171 g Volume = 0.000670 cm3 Porosity: 99.9332% V(tot) - V(min): 0.10021E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0070000 g log = -2.1549 Original solution: 1000.0103000 g Original solution / Rock added: 142858.61 (Water/Rock Ratio), log = 5.1549 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1054E-03 1.0073 0.1117E-03 0.1109E-03 CH4,gas 0.1086E-10 1.0129 0.1157E-10 0.1142E-10 H2,gas 0.5467E-05 1.0006 0.5755E-05 0.5752E-05 H2S,gas 0.5131E-07 0.9959 0.5376E-07 0.5398E-07 S2,gas 0.3107E-23 1.0000 0.3269E-23 0.3269E-23 CO,gas 0.1582E-12 1.0000 0.1665E-12 0.1665E-12 SO3,gas 0.1415E-34 1.0000 0.1488E-34 0.1488E-34 SO2,gas 0.3080E-17 1.0000 0.3240E-17 0.3240E-17 HCl,gas 0.1749E-14 1.0000 0.1840E-14 0.1840E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.32 -5.95 -1.984 0.10163E+05 -3.952 3 CH4,gas 4.81 -8.13 -12.94 -3.234 0.22089E+05 -10.937 4 H2,gas 8.29 1.05 -7.24 -4.137 0.12362E+05 -5.240 5 H2S,gas -5.94 -15.21 -9.27 -4.635 0.15827E+05 -7.270 6 S2,gas -7.03 -32.52 -25.49 -3.921 0.43516E+05 -23.486 7 CO,gas 3.51 -11.27 -14.78 -4.547 0.25234E+05 -12.779 8 SO3,gas 17.43 -19.40 -36.83 -9.207 0.62882E+05 -34.827 9 SO2,gas 1.14 -18.35 -19.49 -5.197 0.33278E+05 -17.489 10 HCl,gas 5.48 -11.26 -16.74 -8.368 0.28575E+05 -14.735 21 andalusite 5.06 1.62 -3.44 -0.344 0.58814E+04 24 anhydrite -5.28 -9.34 -4.06 -2.030 0.69322E+04 35 aragonite 0.99 -2.25 -3.24 -1.080 0.55341E+04 36 brucite 12.58 8.92 -3.66 -0.731 0.62418E+04 37 calcite 0.83 -2.25 -3.09 -1.029 0.52728E+04 40 carpholite-Mg 8.65 6.36 -2.29 -0.152 0.39030E+04 41 carpholite-Fe 6.78 4.27 -2.52 -0.168 0.42979E+04 50 chloritoid-Mg 13.26 10.54 -2.72 -0.181 0.46484E+04 51 chloritoid-Fe 9.24 8.44 -0.80 -0.053 0.13635E+04 52 chloritoid-Mn 11.46 9.36 -2.11 -0.140 0.35979E+04 54 coesite -2.37 -4.17 -1.80 -0.602 0.30820E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.17 -1.63 -0.542 0.27748E+04 78 fayalite 14.08 9.47 -4.61 -0.658 0.78693E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.12 -4.08 -0.340 0.69597E+04 92 hercynite 17.34 12.61 -4.73 -0.315 0.80764E+04 98 kaolinite -1.27 -2.56 -1.28 -0.117 0.21913E+04 99 kyanite 4.93 1.62 -3.31 -0.331 0.56582E+04 101 laumontite 2.97 -0.84 -3.82 -0.255 0.65215E+04 102 lawsonite 9.68 7.50 -2.17 -0.145 0.37130E+04 105 lizardite 23.29 18.41 -4.87 -0.406 0.83206E+04 106 magnesite 0.71 -3.39 -4.10 -1.368 0.70067E+04 107 magnetite 20.13 19.42 -0.71 -0.058 0.12172E+04 110 magnesioferrite 26.26 21.52 -4.74 -0.387 0.80911E+04 113 margarite 17.45 13.30 -4.16 -0.166 0.70959E+04 120 muscovite 2.68 -2.30 -4.98 -0.293 0.85036E+04 121 paragonite 4.34 -0.25 -4.58 -0.270 0.78238E+04 128 periclase-Fe 11.64 6.82 -4.82 -1.204 0.82247E+04 142 pyrite -21.23 -24.65 -3.42 -0.806 0.58459E+04 143 pyrrhotite -4.24 -8.39 -4.15 -1.382 0.70798E+04 144 pyrrhotiteFe0.875 -6.00 -9.37 -3.37 -1.240 0.57568E+04 145 pyroxmangite 7.42 3.56 -3.85 -0.770 0.65774E+04 146 pyrophyllite -6.10 -10.91 -4.81 -0.300 0.82080E+04 147 quartz -2.98 -4.17 -1.19 -0.397 0.20359E+04 152 rhodochrosite -0.96 -4.58 -3.62 -1.206 0.61785E+04 153 rhodonite 7.46 3.56 -3.90 -0.780 0.66567E+04 156 siderite -2.59 -5.49 -2.91 -0.968 0.49607E+04 157 sillimanite 5.32 1.62 -3.70 -0.370 0.63236E+04 169 sudoite 21.22 16.90 -4.31 -0.139 0.73640E+04 178 topaz-H 4.67 1.62 -3.05 -0.277 0.52073E+04 179 tridymite -2.61 -4.17 -1.56 -0.520 0.26632E+04 182 troilite-low -4.39 -8.39 -4.00 -1.332 0.68230E+04 188 wairakite 4.06 -0.84 -4.90 -0.288 0.83723E+04 190 wollastonite 10.48 5.89 -4.60 -0.919 0.78473E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.17 -1.38 -0.460 0.23562E+04 206 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57818E+04 207 nontronite-H 2.60 -1.77 -4.36 -0.292 0.74483E+04 208 nontronite-K 3.40 -1.26 -4.66 -0.299 0.79639E+04 209 nontronite-Mg 3.14 -0.29 -3.43 -0.223 0.58630E+04 210 nontronite-Na 3.58 -0.58 -4.16 -0.267 0.71113E+04 215 gypsum -4.92 -9.34 -4.42 -1.104 0.75390E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.82 -3.00 -0.750 0.51257E+04 241 silica-amorphous -2.08 -4.17 -2.09 -0.698 0.35764E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0070000 g New total amount of reactant added: 0.0072000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.9764E-15 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0072000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2659588E-03 Osmotic coef. = 0.9902 True ionic strength = .2685988E-03 Chg. balance for total moles = 0.9764E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.42311E-07 -7.3735 0.40664E-07 -7.3908 0.96106E+00 -0.0173 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13257E-03 -3.8775 0.96094E+00 -0.0173 4 SO4-- 0.25345E-04 -4.5961 0.22807E-04 -4.6419 0.89985E+00 -0.0458 5 HCO3- 0.12076E-04 -4.9181 0.11605E-04 -4.9354 0.96097E+00 -0.0173 6 HS- 0.11860E-07 -7.9259 0.11396E-07 -7.9432 0.96095E+00 -0.0173 7 Al+++ 0.65652E-19 -19.1828 0.52931E-19 -19.2763 0.80624E+00 -0.0935 8 H4SiO4 0.68700E-04 -4.1630 0.68700E-04 -4.1630 0.10000E+01 0.0000 9 Ca++ 0.22512E-04 -4.6476 0.20254E-04 -4.6935 0.89972E+00 -0.0459 10 Mg++ 0.15242E-05 -5.8169 0.13713E-05 -5.8629 0.89964E+00 -0.0459 11 Fe++ 0.11867E-07 -7.9257 0.10676E-07 -7.9716 0.89966E+00 -0.0459 12 K+ 0.15281E-05 -5.8158 0.14685E-05 -5.8331 0.96098E+00 -0.0173 13 Na+ 0.16910E-03 -3.7719 0.16249E-03 -3.7892 0.96094E+00 -0.0173 14 Mn++ 0.10820E-06 -6.9658 0.97345E-07 -7.0117 0.89967E+00 -0.0459 15 HPO4-- 0.10415E-07 -7.9823 0.93719E-08 -8.0282 0.89985E+00 -0.0458 16 HSiO3- 0.17154E-05 -5.7656 0.16484E-05 -5.7829 0.96094E+00 -0.0173 17 Ca(HSiO3)+ 0.77840E-09 -9.1088 0.74803E-09 -9.1261 0.96098E+00 -0.0173 18 Mg(HSiO3)+ 0.65586E-10 -10.1832 0.63026E-10 -10.2005 0.96098E+00 -0.0173 19 NaHSiO3,aq 0.42540E-08 -8.3712 0.42540E-08 -8.3712 0.10000E+01 0.0000 20 AlO+ 0.43003E-11 -11.3665 0.41325E-11 -11.3838 0.96098E+00 -0.0173 21 AlOH+2 0.93563E-15 -15.0289 0.84178E-15 -15.0748 0.89969E+00 -0.0459 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.11621E-05 -5.9348 0.11167E-05 -5.9521 0.96091E+00 -0.0173 24 CH4,aq 0.56905E-14 -14.2448 0.56900E-14 -14.2449 0.99992E+00 0.0000 29 CO,aq 0.97158E-16 -16.0125 0.97158E-16 -16.0125 0.10000E+01 0.0000 30 CO2,aq 0.95150E-06 -6.0216 0.95142E-06 -6.0216 0.99992E+00 0.0000 31 CO3-2 0.29324E-07 -7.5328 0.26386E-07 -7.5786 0.89981E+00 -0.0458 32 CaCO3,aq 0.65455E-08 -8.1841 0.65455E-08 -8.1841 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.61629E-08 -8.2102 0.59224E-08 -8.2275 0.96098E+00 -0.0173 34 CaCl+ 0.44526E-08 -8.3514 0.42788E-08 -8.3687 0.96098E+00 -0.0173 35 CaCl2,aq 0.13208E-12 -12.8792 0.13208E-12 -12.8792 0.10000E+01 0.0000 36 CaOH+ 0.36548E-07 -7.4371 0.35122E-07 -7.4544 0.96098E+00 -0.0173 37 CaSO4,aq 0.14393E-06 -6.8419 0.14393E-06 -6.8419 0.10000E+01 0.0000 38 HCl,aq 0.10140E-11 -11.9940 0.10140E-11 -11.9940 0.10000E+01 0.0000 43 FeCl+ 0.22939E-11 -11.6394 0.22044E-11 -11.6567 0.96098E+00 -0.0173 46 FeO,aq 0.25531E-09 -9.5929 0.25531E-09 -9.5929 0.10000E+01 0.0000 47 FeOH+ 0.90573E-08 -8.0430 0.87038E-08 -8.0603 0.96098E+00 -0.0173 48 HFeO2- 0.70278E-10 -10.1532 0.67533E-10 -10.1705 0.96094E+00 -0.0173 49 FeO+ 0.35003E-12 -12.4559 0.33638E-12 -12.4732 0.96098E+00 -0.0173 50 FeOH+2 0.28290E-17 -17.5484 0.25453E-17 -17.5943 0.89969E+00 -0.0459 51 FeO2- 0.41607E-10 -10.3808 0.39982E-10 -10.3981 0.96094E+00 -0.0173 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.39653E-08 -8.4017 0.39649E-08 -8.4018 0.99992E+00 0.0000 54 KCl,aq 0.34471E-11 -11.4625 0.34471E-11 -11.4625 0.10000E+01 0.0000 55 KHSO4,aq 0.36444E-17 -17.4384 0.36444E-17 -17.4384 0.10000E+01 0.0000 56 KOH,aq 0.15743E-10 -10.8029 0.15743E-10 -10.8029 0.10000E+01 0.0000 57 KSO4- 0.53696E-09 -9.2701 0.51598E-09 -9.2874 0.96094E+00 -0.0173 58 MgCO3,aq 0.11073E-09 -9.9557 0.11073E-09 -9.9557 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.42547E-09 -9.3711 0.40887E-09 -9.3884 0.96098E+00 -0.0173 60 MgCl+ 0.27366E-09 -9.5628 0.26298E-09 -9.5801 0.96098E+00 -0.0173 61 MgOH+ 0.13708E-07 -7.8630 0.13173E-07 -7.8803 0.96098E+00 -0.0173 63 MnO,aq 0.62146E-10 -10.2066 0.62146E-10 -10.2066 0.10000E+01 0.0000 64 MnOH+ 0.76720E-08 -8.1151 0.73727E-08 -8.1324 0.96098E+00 -0.0173 65 MnO2-2 0.14445E-17 -17.8403 0.12998E-17 -17.8861 0.89981E+00 -0.0458 66 HMnO2- 0.11917E-13 -13.9238 0.11451E-13 -13.9411 0.96094E+00 -0.0173 69 MnCl+ 0.81279E-10 -10.0900 0.78107E-10 -10.1073 0.96098E+00 -0.0173 70 MnSO4,aq 0.62920E-09 -9.2012 0.62920E-09 -9.2012 0.10000E+01 0.0000 71 NaCl,aq 0.70341E-08 -8.1528 0.70341E-08 -8.1528 0.10000E+01 0.0000 72 NaOH,aq 0.17559E-08 -8.7555 0.17559E-08 -8.7555 0.10000E+01 0.0000 74 OH- 0.15351E-04 -4.8139 0.14751E-04 -4.8312 0.96091E+00 -0.0173 79 HPO3-2 0.13044E-18 -18.8846 0.11737E-18 -18.9304 0.89981E+00 -0.0458 82 H3PO4,aq 0.99768E-13 -13.0010 0.99768E-13 -13.0010 0.10000E+01 0.0000 83 H2PO4- 0.69528E-08 -8.1578 0.66814E-08 -8.1751 0.96096E+00 -0.0173 84 PO4-3 0.24940E-12 -12.6031 0.20127E-12 -12.6962 0.80703E+00 -0.0931 87 H2P2O7-2 0.38828E-17 -17.4109 0.34938E-17 -17.4567 0.89981E+00 -0.0458 88 HP2O7-3 0.21852E-16 -16.6605 0.17618E-16 -16.7540 0.80624E+00 -0.0935 89 P2O7-4 0.15451E-18 -18.8111 0.10689E-18 -18.9711 0.69179E+00 -0.1600 90 H2S,aq 0.13925E-08 -8.8562 0.13924E-08 -8.8562 0.99992E+00 0.0000 91 S2-2 0.80065E-18 -18.0966 0.72043E-18 -18.1424 0.89981E+00 -0.0458 96 SO2,aq 0.62647E-18 -18.2031 0.62647E-18 -18.2031 0.10000E+01 0.0000 97 SO3-2 0.13699E-13 -13.8633 0.12330E-13 -13.9090 0.90007E+00 -0.0457 98 HSO3- 0.30534E-13 -13.5152 0.29341E-13 -13.5325 0.96094E+00 -0.0173 99 HSO4- 0.89544E-09 -9.0480 0.86051E-09 -9.0652 0.96100E+00 -0.0173 101 S2O3-2 0.41593E-15 -15.3810 0.37426E-15 -15.4268 0.89981E+00 -0.0458 Charge balance for all species = 0.9768E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4231147E-07 -.2088511E-04 -.2105056E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999802E+06 0.0000 3 Cl- 0.1379627E-03 0.1379746E-03 0.4891525E+01 3.5133 4 SO4-- 0.2534530E-04 0.2549033E-04 0.2448598E+01 10.1397 5 HCO3- 0.1207597E-04 0.1307004E-04 0.7974828E+00 2.4554 6 HS- 0.1185953E-07 0.1421267E-07 0.4700331E-03 -0.5524 7 Al+++ 0.6565196E-19 0.1182447E-05 0.3190361E-01 2.8961 8 H4SiO4 0.6870027E-04 0.7042073E-04 0.6768396E+01 -4.1630 9 Ca++ 0.2251167E-04 0.2271009E-04 0.9101586E+00 10.0881 10 Mg++ 0.1524232E-05 0.1538815E-05 0.3741101E-01 8.9187 11 Fe++ 0.1186656E-07 0.2149714E-07 0.1200529E-02 6.8100 12 K+ 0.1528111E-05 0.1528667E-05 0.5977286E-01 1.5577 13 Na+ 0.1690962E-03 0.1691092E-03 0.3887718E+01 3.6016 14 Mn++ 0.1082008E-06 0.1166454E-06 0.6408152E-02 7.7699 15 HPO4-- 0.1041491E-07 0.1736809E-07 0.1666942E-02 6.7534 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1061813E-03 -.2088506E-04 -.8529626E-04 0.0000000E+00 2 H2O 0.5550816E+02 0.5550811E+02 0.4934253E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2570401E-04 0.2549026E-04 0.2137492E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1995365E-06 0.1421263E-07 -.2137492E-06 0.0000000E+00 7 Al+++ 0.2347734E-04 0.1182443E-05 0.2229490E-04 0.0000000E+00 8 H4SiO4 0.7497204E-04 0.7042053E-04 0.4551503E-05 0.0000000E+00 9 Ca++ 0.2275209E-04 0.2271002E-04 0.4206419E-07 0.0000000E+00 10 Mg++ 0.5714286E-05 0.1538811E-05 0.4175475E-05 0.0000000E+00 11 Fe++ 0.5133662E-05 0.2149708E-07 0.5112165E-05 0.0000000E+00 12 K+ 0.1528662E-05 0.1528662E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1691088E-03 0.1691088E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1248379E-06 0.1166451E-06 0.8192789E-08 0.0000000E+00 15 HPO4-- 0.4260655E-07 0.1736804E-07 0.2523851E-07 0.0000000E+00 Chg. balance for solid moles: -.1513E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0072000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.8413E-08 -8.075 0.4226E-05 -5.374 0.1881 0.1343E-05 clinochlore 0.8351E-06 -6.078 0.4642E-03 -3.333 20.66 0.1766E-03 daphnite 0.6804E-06 -6.167 0.4855E-03 -3.314 21.61 0.1471E-03 chlorite-Mn 0.1639E-08 -8.786 0.1162E-05 -5.935 0.5170E-01 0.3702E-06 diaspore 0.1926E-04 -4.715 0.1155E-02 -2.937 51.42 0.3440E-03 hematite 0.8550E-06 -6.068 0.1365E-03 -3.865 6.077 0.2588E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5504E+00 0.5504E+00 1.0000 -0.259 daphnite 0.4485E+00 0.4485E+00 1.0000 -0.348 chlorite-Mn 0.1080E-02 0.1080E-02 1.0000 -2.967 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.002247 g Volume = 0.000695 cm3 Porosity: 99.9307% V(tot) - V(min): 0.10022E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0072000 g log = -2.1427 Original solution: 1000.0103000 g Original solution / Rock added: 138890.32 (Water/Rock Ratio), log = 5.1427 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1028E-03 1.0073 0.1089E-03 0.1081E-03 CH4,gas 0.8444E-11 1.0129 0.8998E-11 0.8883E-11 H2,gas 0.5166E-05 1.0006 0.5438E-05 0.5435E-05 H2S,gas 0.3876E-07 0.9959 0.4061E-07 0.4078E-07 S2,gas 0.1985E-23 1.0000 0.2089E-23 0.2089E-23 CO,gas 0.1458E-12 1.0000 0.1534E-12 0.1534E-12 SO3,gas 0.1340E-34 1.0000 0.1410E-34 0.1410E-34 SO2,gas 0.2757E-17 1.0000 0.2901E-17 0.2901E-17 HCl,gas 0.1702E-14 1.0000 0.1790E-14 0.1790E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.33 -5.96 -1.988 0.10182E+05 -3.963 3 CH4,gas 4.81 -8.24 -13.05 -3.261 0.22275E+05 -11.046 4 H2,gas 8.29 1.02 -7.26 -4.151 0.12404E+05 -5.265 5 H2S,gas -5.94 -15.33 -9.39 -4.696 0.16036E+05 -7.391 6 S2,gas -7.03 -32.71 -25.68 -3.951 0.43848E+05 -23.680 7 CO,gas 3.51 -11.30 -14.81 -4.558 0.25295E+05 -12.814 8 SO3,gas 17.43 -19.42 -36.85 -9.213 0.62922E+05 -34.851 9 SO2,gas 1.14 -18.40 -19.54 -5.210 0.33360E+05 -17.538 10 HCl,gas 5.48 -11.27 -16.75 -8.374 0.28595E+05 -14.747 21 andalusite 5.06 1.63 -3.43 -0.343 0.58622E+04 24 anhydrite -5.28 -9.34 -4.06 -2.028 0.69249E+04 35 aragonite 0.99 -2.24 -3.22 -1.075 0.55054E+04 36 brucite 12.58 8.92 -3.66 -0.732 0.62458E+04 37 calcite 0.83 -2.24 -3.07 -1.024 0.52440E+04 40 carpholite-Mg 8.65 6.38 -2.27 -0.151 0.38684E+04 41 carpholite-Fe 6.78 4.28 -2.51 -0.167 0.42803E+04 50 chloritoid-Mg 13.26 10.55 -2.71 -0.181 0.46331E+04 51 chloritoid-Fe 9.24 8.44 -0.80 -0.053 0.13652E+04 52 chloritoid-Mn 11.46 9.40 -2.06 -0.138 0.35245E+04 54 coesite -2.37 -4.16 -1.79 -0.598 0.30627E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.16 -1.61 -0.538 0.27556E+04 75 epidote 24.78 19.78 -5.00 -0.242 0.85325E+04 78 fayalite 14.08 9.46 -4.62 -0.660 0.78920E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.10 -4.09 -0.341 0.69841E+04 92 hercynite 17.34 12.60 -4.74 -0.316 0.80974E+04 98 kaolinite -1.27 -2.53 -1.26 -0.115 0.21527E+04 99 kyanite 4.93 1.63 -3.30 -0.330 0.56389E+04 101 laumontite 2.97 -0.77 -3.75 -0.250 0.63969E+04 102 lawsonite 9.68 7.55 -2.12 -0.142 0.36270E+04 105 lizardite 23.29 18.43 -4.86 -0.405 0.82939E+04 106 magnesite 0.71 -3.41 -4.12 -1.372 0.70293E+04 107 magnetite 20.13 19.41 -0.73 -0.059 0.12382E+04 110 magnesioferrite 26.26 21.52 -4.74 -0.387 0.80950E+04 113 margarite 17.45 13.35 -4.11 -0.164 0.70099E+04 120 muscovite 2.68 -2.24 -4.92 -0.290 0.84049E+04 121 paragonite 4.34 -0.20 -4.54 -0.267 0.77449E+04 128 periclase-Fe 11.64 6.81 -4.83 -1.207 0.82456E+04 142 pyrite -21.23 -24.88 -3.66 -0.860 0.62410E+04 143 pyrrhotite -4.24 -8.52 -4.28 -1.427 0.73088E+04 144 pyrrhotiteFe0.875 -6.00 -9.50 -3.50 -1.288 0.59780E+04 145 pyroxmangite 7.42 3.61 -3.81 -0.762 0.65041E+04 146 pyrophyllite -6.10 -10.86 -4.76 -0.298 0.81309E+04 147 quartz -2.98 -4.16 -1.18 -0.394 0.20166E+04 152 rhodochrosite -0.96 -4.56 -3.60 -1.199 0.61430E+04 153 rhodonite 7.46 3.61 -3.86 -0.771 0.65833E+04 156 siderite -2.59 -5.52 -2.93 -0.976 0.50003E+04 157 sillimanite 5.32 1.63 -3.69 -0.369 0.63043E+04 169 sudoite 21.22 16.93 -4.28 -0.138 0.73140E+04 178 topaz-H 4.67 1.63 -3.04 -0.276 0.51880E+04 179 tridymite -2.61 -4.16 -1.55 -0.516 0.26439E+04 182 troilite-low -4.39 -8.52 -4.13 -1.377 0.70520E+04 188 wairakite 4.06 -0.77 -4.83 -0.284 0.82477E+04 190 wollastonite 10.48 5.93 -4.56 -0.911 0.77805E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.16 -1.37 -0.456 0.23369E+04 202 montmorillonite-Ca -2.21 -7.21 -4.99 -0.309 0.85271E+04 204 montmorillonite-Mg -2.40 -7.40 -5.00 -0.309 0.85362E+04 206 nontronite-Ca 3.28 -0.06 -3.34 -0.217 0.57032E+04 207 nontronite-H 2.60 -1.73 -4.32 -0.290 0.73776E+04 208 nontronite-K 3.40 -1.21 -4.61 -0.296 0.78797E+04 209 nontronite-Mg 3.14 -0.25 -3.39 -0.220 0.57929E+04 210 nontronite-Na 3.58 -0.54 -4.12 -0.264 0.70336E+04 215 gypsum -4.92 -9.34 -4.41 -1.103 0.75317E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.81 -3.01 -0.754 0.51467E+04 241 silica-amorphous -2.08 -4.16 -2.08 -0.694 0.35571E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0072000 g New total amount of reactant added: 0.0074000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.9764E-15 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0074000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2665285E-03 Osmotic coef. = 0.9902 True ionic strength = .2693028E-03 Chg. balance for total moles = 0.9764E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.41190E-07 -7.3852 0.39585E-07 -7.4025 0.96103E+00 -0.0173 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13257E-03 -3.8776 0.96092E+00 -0.0173 4 SO4-- 0.25347E-04 -4.5961 0.22806E-04 -4.6420 0.89975E+00 -0.0459 5 HCO3- 0.12098E-04 -4.9173 0.11626E-04 -4.9346 0.96094E+00 -0.0173 6 HS- 0.92710E-08 -8.0329 0.89087E-08 -8.0502 0.96092E+00 -0.0173 7 Al+++ 0.60578E-19 -19.2177 0.48828E-19 -19.3113 0.80603E+00 -0.0936 8 H4SiO4 0.70467E-04 -4.1520 0.70467E-04 -4.1520 0.10000E+01 0.0000 9 Ca++ 0.22735E-04 -4.6433 0.20453E-04 -4.6892 0.89962E+00 -0.0459 10 Mg++ 0.14365E-05 -5.8427 0.12922E-05 -5.8887 0.89954E+00 -0.0460 11 Fe++ 0.10942E-07 -7.9609 0.98432E-08 -8.0069 0.89956E+00 -0.0460 12 K+ 0.15706E-05 -5.8039 0.15092E-05 -5.8212 0.96095E+00 -0.0173 13 Na+ 0.16935E-03 -3.7712 0.16273E-03 -3.7885 0.96091E+00 -0.0173 14 Mn++ 0.11012E-06 -6.9581 0.99065E-07 -7.0041 0.89957E+00 -0.0460 15 HPO4-- 0.98872E-08 -8.0049 0.88960E-08 -8.0508 0.89975E+00 -0.0459 16 HSiO3- 0.18075E-05 -5.7429 0.17369E-05 -5.7602 0.96092E+00 -0.0173 17 Ca(HSiO3)+ 0.82825E-09 -9.0818 0.79591E-09 -9.0991 0.96095E+00 -0.0173 18 Mg(HSiO3)+ 0.65123E-10 -10.1863 0.62580E-10 -10.2036 0.96095E+00 -0.0173 19 NaHSiO3,aq 0.44889E-08 -8.3479 0.44889E-08 -8.3479 0.10000E+01 0.0000 20 AlO+ 0.41862E-11 -11.3782 0.40228E-11 -11.3955 0.96095E+00 -0.0173 21 AlOH+2 0.88673E-15 -15.0522 0.79770E-15 -15.0982 0.89959E+00 -0.0460 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.11938E-05 -5.9231 0.11471E-05 -5.9404 0.96088E+00 -0.0173 24 CH4,aq 0.44567E-14 -14.3510 0.44563E-14 -14.3510 0.99992E+00 0.0000 29 CO,aq 0.89697E-16 -16.0472 0.89697E-16 -16.0472 0.10000E+01 0.0000 30 CO2,aq 0.92794E-06 -6.0325 0.92786E-06 -6.0325 0.99992E+00 0.0000 31 CO3-2 0.30182E-07 -7.5203 0.27155E-07 -7.5661 0.89971E+00 -0.0459 32 CaCO3,aq 0.68022E-08 -8.1673 0.68022E-08 -8.1673 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.62348E-08 -8.2052 0.59913E-08 -8.2225 0.96095E+00 -0.0173 34 CaCl+ 0.44962E-08 -8.3472 0.43206E-08 -8.3645 0.96095E+00 -0.0173 35 CaCl2,aq 0.13337E-12 -12.8750 0.13337E-12 -12.8750 0.10000E+01 0.0000 36 CaOH+ 0.37913E-07 -7.4212 0.36433E-07 -7.4385 0.96095E+00 -0.0173 37 CaSO4,aq 0.14533E-06 -6.8376 0.14533E-06 -6.8376 0.10000E+01 0.0000 38 HCl,aq 0.98709E-12 -12.0056 0.98709E-12 -12.0056 0.10000E+01 0.0000 43 FeCl+ 0.21150E-11 -11.6747 0.20324E-11 -11.6920 0.96095E+00 -0.0173 46 FeO,aq 0.24841E-09 -9.6048 0.24841E-09 -9.6048 0.10000E+01 0.0000 47 FeOH+ 0.85787E-08 -8.0666 0.82437E-08 -8.0839 0.96095E+00 -0.0173 48 HFeO2- 0.70243E-10 -10.1534 0.67498E-10 -10.1707 0.96092E+00 -0.0173 49 FeO+ 0.34075E-12 -12.4676 0.32745E-12 -12.4849 0.96095E+00 -0.0173 50 FeOH+2 0.26812E-17 -17.5717 0.24120E-17 -17.6176 0.89959E+00 -0.0460 51 FeO2- 0.42742E-10 -10.3691 0.41072E-10 -10.3865 0.96092E+00 -0.0173 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.37537E-08 -8.4255 0.37534E-08 -8.4256 0.99992E+00 0.0000 54 KCl,aq 0.35427E-11 -11.4507 0.35427E-11 -11.4507 0.10000E+01 0.0000 55 KHSO4,aq 0.36459E-17 -17.4382 0.36459E-17 -17.4382 0.10000E+01 0.0000 56 KOH,aq 0.16621E-10 -10.7793 0.16621E-10 -10.7793 0.10000E+01 0.0000 57 KSO4- 0.55184E-09 -9.2582 0.53027E-09 -9.2755 0.96092E+00 -0.0173 58 MgCO3,aq 0.10739E-09 -9.9690 0.10739E-09 -9.9690 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.40168E-09 -9.3961 0.38600E-09 -9.4134 0.96095E+00 -0.0173 60 MgCl+ 0.25788E-09 -9.5886 0.24781E-09 -9.6059 0.96095E+00 -0.0173 61 MgOH+ 0.13270E-07 -7.8771 0.12752E-07 -7.8944 0.96095E+00 -0.0173 63 MnO,aq 0.66740E-10 -10.1756 0.66740E-10 -10.1756 0.10000E+01 0.0000 64 MnOH+ 0.80206E-08 -8.0958 0.77074E-08 -8.1131 0.96095E+00 -0.0173 65 MnO2-2 0.16372E-17 -17.7859 0.14730E-17 -17.8318 0.89971E+00 -0.0459 66 HMnO2- 0.13147E-13 -13.8812 0.12633E-13 -13.8985 0.96092E+00 -0.0173 69 MnCl+ 0.82715E-10 -10.0824 0.79485E-10 -10.0997 0.96095E+00 -0.0173 70 MnSO4,aq 0.64028E-09 -9.1936 0.64028E-09 -9.1936 0.10000E+01 0.0000 71 NaCl,aq 0.70441E-08 -8.1522 0.70441E-08 -8.1522 0.10000E+01 0.0000 72 NaOH,aq 0.18064E-08 -8.7432 0.18064E-08 -8.7432 0.10000E+01 0.0000 74 OH- 0.15770E-04 -4.8022 0.15153E-04 -4.8195 0.96088E+00 -0.0173 79 HPO3-2 0.11722E-18 -18.9310 0.10546E-18 -18.9769 0.89971E+00 -0.0459 82 H3PO4,aq 0.89742E-13 -13.0470 0.89742E-13 -13.0470 0.10000E+01 0.0000 83 H2PO4- 0.64248E-08 -8.1921 0.61738E-08 -8.2094 0.96093E+00 -0.0173 84 PO4-3 0.24325E-12 -12.6139 0.19626E-12 -12.7072 0.80683E+00 -0.0932 87 H2P2O7-2 0.33157E-17 -17.4794 0.29831E-17 -17.5253 0.89971E+00 -0.0459 88 HP2O7-3 0.19172E-16 -16.7173 0.15453E-16 -16.8110 0.80604E+00 -0.0936 89 P2O7-4 0.13928E-18 -18.8561 0.96306E-19 -19.0163 0.69148E+00 -0.1602 90 H2S,aq 0.10596E-08 -8.9748 0.10596E-08 -8.9749 0.99992E+00 0.0000 91 S2-2 0.51689E-18 -18.2866 0.46505E-18 -18.3325 0.89971E+00 -0.0459 96 SO2,aq 0.56196E-18 -18.2503 0.56196E-18 -18.2503 0.10000E+01 0.0000 97 SO3-2 0.12969E-13 -13.8871 0.11671E-13 -13.9329 0.89997E+00 -0.0458 98 HSO3- 0.28137E-13 -13.5507 0.27037E-13 -13.5680 0.96092E+00 -0.0173 99 HSO4- 0.87165E-09 -9.0597 0.83763E-09 -9.0769 0.96097E+00 -0.0173 101 S2O3-2 0.31653E-15 -15.4996 0.28479E-15 -15.5455 0.89971E+00 -0.0459 Charge balance for all species = 0.9768E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4118972E-07 -.2155083E-04 -.2172155E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999800E+06 0.0000 3 Cl- 0.1379627E-03 0.1379746E-03 0.4891524E+01 3.5249 4 SO4-- 0.2534682E-04 0.2549330E-04 0.2448883E+01 10.1630 5 HCO3- 0.1209837E-04 0.1307004E-04 0.7974827E+00 2.4679 6 HS- 0.9271020E-08 0.1123828E-07 0.3716658E-03 -0.6477 7 Al+++ 0.6057776E-19 0.1214162E-05 0.3275932E-01 2.8961 8 H4SiO4 0.7046746E-04 0.7228034E-04 0.6947129E+01 -4.1520 9 Ca++ 0.2273478E-04 0.2293639E-04 0.9192278E+00 10.1157 10 Mg++ 0.1436495E-05 0.1450597E-05 0.3526629E-01 8.9163 11 Fe++ 0.1094221E-07 0.2008823E-07 0.1121847E-02 6.7981 12 K+ 0.1570558E-05 0.1571130E-05 0.6143321E-01 1.5812 13 Na+ 0.1693469E-03 0.1693603E-03 0.3893489E+01 3.6139 14 Mn++ 0.1101246E-06 0.1189349E-06 0.6533929E-02 7.8009 15 HPO4-- 0.9887166E-08 0.1631231E-07 0.1565611E-02 6.7541 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1094930E-03 -.2155077E-04 -.8794225E-04 0.0000000E+00 2 H2O 0.5550816E+02 0.5550811E+02 0.5075333E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2570955E-04 0.2549323E-04 0.2163175E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2050792E-06 0.1123825E-07 -.2163175E-06 0.0000000E+00 7 Al+++ 0.2412949E-04 0.1214159E-05 0.2291533E-04 0.0000000E+00 8 H4SiO4 0.7705459E-04 0.7228014E-04 0.4774458E-05 0.0000000E+00 9 Ca++ 0.2298212E-04 0.2293632E-04 0.4579634E-07 0.0000000E+00 10 Mg++ 0.5873016E-05 0.1450593E-05 0.4422423E-05 0.0000000E+00 11 Fe++ 0.5276264E-05 0.2008818E-07 0.5256175E-05 0.0000000E+00 12 K+ 0.1571125E-05 0.1571125E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1693598E-03 0.1693598E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1283056E-06 0.1189346E-06 0.9371019E-08 0.0000000E+00 15 HPO4-- 0.4379007E-07 0.1631226E-07 0.2747781E-07 0.0000000E+00 Chg. balance for solid moles: 0.1628E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0074000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.9159E-08 -8.038 0.4601E-05 -5.337 0.1981 0.1462E-05 clinochlore 0.8845E-06 -6.053 0.4916E-03 -3.308 21.17 0.1870E-03 daphnite 0.7051E-06 -6.152 0.5031E-03 -3.298 21.66 0.1525E-03 chlorite-Mn 0.1874E-08 -8.727 0.1329E-05 -5.877 0.5721E-01 0.4234E-06 diaspore 0.1973E-04 -4.705 0.1184E-02 -2.927 50.97 0.3524E-03 hematite 0.8653E-06 -6.063 0.1382E-03 -3.860 5.950 0.2619E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5558E+00 0.5558E+00 1.0000 -0.255 daphnite 0.4431E+00 0.4431E+00 1.0000 -0.354 chlorite-Mn 0.1178E-02 0.1178E-02 1.0000 -2.929 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.002323 g Volume = 0.000720 cm3 Porosity: 99.9282% V(tot) - V(min): 0.10022E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0074000 g log = -2.1308 Original solution: 1000.0103000 g Original solution / Rock added: 135136.53 (Water/Rock Ratio), log = 5.1308 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1002E-03 1.0073 0.1062E-03 0.1054E-03 CH4,gas 0.6613E-11 1.0129 0.7047E-11 0.6957E-11 H2,gas 0.4891E-05 1.0006 0.5148E-05 0.5145E-05 H2S,gas 0.2949E-07 0.9959 0.3090E-07 0.3103E-07 S2,gas 0.1283E-23 1.0000 0.1350E-23 0.1350E-23 CO,gas 0.1346E-12 1.0000 0.1416E-12 0.1416E-12 SO3,gas 0.1270E-34 1.0000 0.1336E-34 0.1336E-34 SO2,gas 0.2473E-17 1.0000 0.2602E-17 0.2602E-17 HCl,gas 0.1657E-14 1.0000 0.1743E-14 0.1743E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.34 -5.97 -1.991 0.10200E+05 -3.974 3 CH4,gas 4.81 -8.34 -13.15 -3.288 0.22457E+05 -11.152 4 H2,gas 8.29 1.00 -7.29 -4.165 0.12445E+05 -5.288 5 H2S,gas -5.94 -15.45 -9.51 -4.755 0.16238E+05 -7.510 6 S2,gas -7.03 -32.90 -25.87 -3.980 0.44172E+05 -23.870 7 CO,gas 3.51 -11.34 -14.85 -4.569 0.25354E+05 -12.849 8 SO3,gas 17.43 -19.45 -36.87 -9.219 0.62962E+05 -34.874 9 SO2,gas 1.14 -18.45 -19.58 -5.223 0.33440E+05 -17.585 10 HCl,gas 5.48 -11.28 -16.76 -8.379 0.28615E+05 -14.759 21 andalusite 5.06 1.64 -3.42 -0.342 0.58433E+04 24 anhydrite -5.28 -9.33 -4.05 -2.026 0.69178E+04 35 aragonite 0.99 -2.22 -3.21 -1.069 0.54768E+04 36 brucite 12.58 8.92 -3.66 -0.732 0.62499E+04 37 calcite 0.83 -2.22 -3.05 -1.018 0.52155E+04 40 carpholite-Mg 8.65 6.40 -2.25 -0.150 0.38349E+04 41 carpholite-Fe 6.78 4.29 -2.50 -0.166 0.42630E+04 50 chloritoid-Mg 13.26 10.56 -2.70 -0.180 0.46184E+04 51 chloritoid-Fe 9.24 8.44 -0.80 -0.053 0.13667E+04 52 chloritoid-Mn 11.46 9.44 -2.02 -0.135 0.34528E+04 54 coesite -2.37 -4.15 -1.78 -0.594 0.30438E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.15 -1.60 -0.534 0.27367E+04 75 epidote 24.78 19.87 -4.91 -0.238 0.83817E+04 78 fayalite 14.08 9.44 -4.63 -0.662 0.79138E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.09 -4.10 -0.342 0.70074E+04 92 hercynite 17.34 12.59 -4.75 -0.317 0.81178E+04 98 kaolinite -1.27 -2.51 -1.24 -0.113 0.21151E+04 99 kyanite 4.93 1.64 -3.29 -0.329 0.56201E+04 101 laumontite 2.97 -0.70 -3.67 -0.245 0.62745E+04 102 lawsonite 9.68 7.60 -2.07 -0.138 0.35422E+04 105 lizardite 23.29 18.44 -4.84 -0.404 0.82687E+04 106 magnesite 0.71 -3.42 -4.13 -1.377 0.70520E+04 107 magnetite 20.13 19.40 -0.74 -0.060 0.12586E+04 110 magnesioferrite 26.26 21.51 -4.74 -0.387 0.80992E+04 113 margarite 17.45 13.40 -4.06 -0.162 0.69251E+04 120 muscovite 2.68 -2.19 -4.87 -0.286 0.83081E+04 121 paragonite 4.34 -0.15 -4.49 -0.264 0.76673E+04 128 periclase-Fe 11.64 6.80 -4.84 -1.210 0.82660E+04 142 pyrite -21.23 -25.11 -3.88 -0.913 0.66258E+04 143 pyrrhotite -4.24 -8.65 -4.41 -1.470 0.75317E+04 144 pyrrhotiteFe0.875 -6.00 -9.63 -3.63 -1.334 0.61933E+04 145 pyroxmangite 7.42 3.65 -3.77 -0.753 0.64324E+04 146 pyrophyllite -6.10 -10.82 -4.72 -0.295 0.80556E+04 147 quartz -2.98 -4.15 -1.17 -0.390 0.19978E+04 152 rhodochrosite -0.96 -4.54 -3.58 -1.193 0.61087E+04 153 rhodonite 7.46 3.65 -3.81 -0.763 0.65116E+04 156 siderite -2.59 -5.54 -2.95 -0.984 0.50393E+04 157 sillimanite 5.32 1.64 -3.68 -0.368 0.62855E+04 169 sudoite 21.22 16.96 -4.26 -0.137 0.72658E+04 178 topaz-H 4.67 1.64 -3.03 -0.275 0.51692E+04 179 tridymite -2.61 -4.15 -1.54 -0.512 0.26251E+04 182 troilite-low -4.39 -8.65 -4.26 -1.420 0.72749E+04 188 wairakite 4.06 -0.70 -4.76 -0.280 0.81253E+04 190 wollastonite 10.48 5.96 -4.52 -0.904 0.77146E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.15 -1.36 -0.453 0.23181E+04 202 montmorillonite-Ca -2.21 -7.16 -4.95 -0.306 0.84453E+04 204 montmorillonite-Mg -2.40 -7.36 -4.96 -0.307 0.84629E+04 206 nontronite-Ca 3.28 -0.02 -3.30 -0.214 0.56263E+04 207 nontronite-H 2.60 -1.68 -4.28 -0.287 0.73085E+04 208 nontronite-K 3.40 -1.16 -4.57 -0.293 0.77973E+04 209 nontronite-Mg 3.14 -0.21 -3.35 -0.217 0.57245E+04 210 nontronite-Na 3.58 -0.49 -4.07 -0.262 0.69576E+04 215 gypsum -4.92 -9.33 -4.41 -1.102 0.75245E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.80 -3.03 -0.757 0.51670E+04 241 silica-amorphous -2.08 -4.15 -2.07 -0.691 0.35383E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0074000 g New total amount of reactant added: 0.0076000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.9765E-15 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0076000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2671106E-03 Osmotic coef. = 0.9902 True ionic strength = .2700218E-03 Chg. balance for total moles = 0.9765E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.40107E-07 -7.3968 0.38543E-07 -7.4141 0.96100E+00 -0.0173 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13257E-03 -3.8776 0.96089E+00 -0.0173 4 SO4-- 0.25348E-04 -4.5961 0.22804E-04 -4.6420 0.89965E+00 -0.0459 5 HCO3- 0.12120E-04 -4.9165 0.11646E-04 -4.9338 0.96092E+00 -0.0173 6 HS- 0.73077E-08 -8.1362 0.70219E-08 -8.1535 0.96089E+00 -0.0173 7 Al+++ 0.55933E-19 -19.2523 0.45072E-19 -19.3461 0.80582E+00 -0.0938 8 H4SiO4 0.72238E-04 -4.1412 0.72238E-04 -4.1412 0.10000E+01 0.0000 9 Ca++ 0.22958E-04 -4.6391 0.20651E-04 -4.6851 0.89952E+00 -0.0460 10 Mg++ 0.13539E-05 -5.8684 0.12177E-05 -5.9144 0.89944E+00 -0.0460 11 Fe++ 0.10105E-07 -7.9955 0.90886E-08 -8.0415 0.89946E+00 -0.0460 12 K+ 0.16130E-05 -5.7924 0.15500E-05 -5.8097 0.96092E+00 -0.0173 13 Na+ 0.16960E-03 -3.7706 0.16296E-03 -3.7879 0.96089E+00 -0.0173 14 Mn++ 0.11194E-06 -6.9510 0.10068E-06 -6.9970 0.89947E+00 -0.0460 15 HPO4-- 0.93904E-08 -8.0273 0.84481E-08 -8.0732 0.89965E+00 -0.0459 16 HSiO3- 0.19031E-05 -5.7205 0.18286E-05 -5.7379 0.96089E+00 -0.0173 17 Ca(HSiO3)+ 0.88050E-09 -9.0553 0.84609E-09 -9.0726 0.96093E+00 -0.0173 18 Mg(HSiO3)+ 0.64616E-10 -10.1897 0.62091E-10 -10.2070 0.96093E+00 -0.0173 19 NaHSiO3,aq 0.47330E-08 -8.3249 0.47330E-08 -8.3249 0.10000E+01 0.0000 20 AlO+ 0.40762E-11 -11.3897 0.39169E-11 -11.4071 0.96093E+00 -0.0173 21 AlOH+2 0.84076E-15 -15.0753 0.75625E-15 -15.1213 0.89949E+00 -0.0460 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.12261E-05 -5.9115 0.11781E-05 -5.9288 0.96085E+00 -0.0173 24 CH4,aq 0.35193E-14 -14.4535 0.35190E-14 -14.4536 0.99992E+00 0.0000 29 CO,aq 0.82989E-16 -16.0810 0.82989E-16 -16.0810 0.10000E+01 0.0000 30 CO2,aq 0.90510E-06 -6.0433 0.90503E-06 -6.0433 0.99992E+00 0.0000 31 CO3-2 0.31056E-07 -7.5079 0.27938E-07 -7.5538 0.89961E+00 -0.0459 32 CaCO3,aq 0.70663E-08 -8.1508 0.70663E-08 -8.1508 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.63066E-08 -8.2002 0.60601E-08 -8.2175 0.96093E+00 -0.0173 34 CaCl+ 0.45398E-08 -8.3430 0.43624E-08 -8.3603 0.96093E+00 -0.0173 35 CaCl2,aq 0.13465E-12 -12.8708 0.13465E-12 -12.8708 0.10000E+01 0.0000 36 CaOH+ 0.39317E-07 -7.4054 0.37781E-07 -7.4227 0.96093E+00 -0.0173 37 CaSO4,aq 0.14673E-06 -6.8335 0.14673E-06 -6.8335 0.10000E+01 0.0000 38 HCl,aq 0.96107E-12 -12.0172 0.96107E-12 -12.0172 0.10000E+01 0.0000 43 FeCl+ 0.19529E-11 -11.7093 0.18766E-11 -11.7266 0.96093E+00 -0.0173 46 FeO,aq 0.24193E-09 -9.6163 0.24193E-09 -9.6163 0.10000E+01 0.0000 47 FeOH+ 0.81354E-08 -8.0896 0.78176E-08 -8.1069 0.96093E+00 -0.0173 48 HFeO2- 0.70264E-10 -10.1533 0.67516E-10 -10.1706 0.96089E+00 -0.0173 49 FeO+ 0.33179E-12 -12.4791 0.31883E-12 -12.4964 0.96093E+00 -0.0173 50 FeOH+2 0.25422E-17 -17.5948 0.22866E-17 -17.6408 0.89949E+00 -0.0460 51 FeO2- 0.43899E-10 -10.3575 0.42182E-10 -10.3749 0.96089E+00 -0.0173 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.35606E-08 -8.4485 0.35603E-08 -8.4485 0.99992E+00 0.0000 54 KCl,aq 0.36382E-11 -11.4391 0.36382E-11 -11.4391 0.10000E+01 0.0000 55 KHSO4,aq 0.36455E-17 -17.4382 0.36455E-17 -17.4382 0.10000E+01 0.0000 56 KOH,aq 0.17531E-10 -10.7562 0.17531E-10 -10.7562 0.10000E+01 0.0000 57 KSO4- 0.56671E-09 -9.2466 0.54455E-09 -9.2640 0.96089E+00 -0.0173 58 MgCO3,aq 0.10412E-09 -9.9825 0.10412E-09 -9.9825 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.37922E-09 -9.4211 0.36440E-09 -9.4384 0.96093E+00 -0.0173 60 MgCl+ 0.24302E-09 -9.6144 0.23353E-09 -9.6317 0.96093E+00 -0.0173 61 MgOH+ 0.12844E-07 -7.8913 0.12342E-07 -7.9086 0.96093E+00 -0.0173 63 MnO,aq 0.71547E-10 -10.1454 0.71547E-10 -10.1454 0.10000E+01 0.0000 64 MnOH+ 0.83723E-08 -8.0772 0.80451E-08 -8.0945 0.96093E+00 -0.0173 65 MnO2-2 0.18515E-17 -17.7325 0.16656E-17 -17.7784 0.89961E+00 -0.0459 66 HMnO2- 0.14475E-13 -13.8394 0.13909E-13 -13.8567 0.96089E+00 -0.0173 69 MnCl+ 0.84066E-10 -10.0754 0.80781E-10 -10.0927 0.96093E+00 -0.0173 70 MnSO4,aq 0.65068E-09 -9.1866 0.65068E-09 -9.1866 0.10000E+01 0.0000 71 NaCl,aq 0.70541E-08 -8.1516 0.70541E-08 -8.1516 0.10000E+01 0.0000 72 NaOH,aq 0.18579E-08 -8.7310 0.18579E-08 -8.7310 0.10000E+01 0.0000 74 OH- 0.16197E-04 -4.7906 0.15563E-04 -4.8079 0.96085E+00 -0.0173 79 HPO3-2 0.10560E-18 -18.9763 0.95003E-19 -19.0223 0.89961E+00 -0.0459 82 H3PO4,aq 0.80796E-13 -13.0926 0.80796E-13 -13.0926 0.10000E+01 0.0000 83 H2PO4- 0.59409E-08 -8.2261 0.57086E-08 -8.2435 0.96091E+00 -0.0173 84 PO4-3 0.23731E-12 -12.6247 0.19142E-12 -12.7180 0.80662E+00 -0.0933 87 H2P2O7-2 0.28352E-17 -17.5474 0.25505E-17 -17.5934 0.89961E+00 -0.0459 88 HP2O7-3 0.16839E-16 -16.7737 0.13569E-16 -16.8674 0.80583E+00 -0.0938 89 P2O7-4 0.12566E-18 -18.9008 0.86853E-19 -19.0612 0.69116E+00 -0.1604 90 H2S,aq 0.81323E-09 -9.0898 0.81316E-09 -9.0898 0.99992E+00 0.0000 91 S2-2 0.33858E-18 -18.4703 0.30459E-18 -18.5163 0.89961E+00 -0.0459 96 SO2,aq 0.50532E-18 -18.2964 0.50532E-18 -18.2964 0.10000E+01 0.0000 97 SO3-2 0.12302E-13 -13.9100 0.11070E-13 -13.9558 0.89987E+00 -0.0458 98 HSO3- 0.25986E-13 -13.5853 0.24970E-13 -13.6026 0.96089E+00 -0.0173 99 HSO4- 0.84866E-09 -9.0713 0.81552E-09 -9.0886 0.96094E+00 -0.0173 101 S2O3-2 0.24293E-15 -15.6145 0.21854E-15 -15.6605 0.89961E+00 -0.0459 Charge balance for all species = 0.9768E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4010655E-07 -.2222947E-04 -.2240556E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999798E+06 0.0000 3 Cl- 0.1379627E-03 0.1379746E-03 0.4891524E+01 3.5365 4 SO4-- 0.2534763E-04 0.2549556E-04 0.2449100E+01 10.1861 5 HCO3- 0.1212002E-04 0.1307004E-04 0.7974826E+00 2.4802 6 HS- 0.7307710E-08 0.8980148E-08 0.2969860E-03 -0.7395 7 Al+++ 0.5593291E-19 0.1246474E-05 0.3363113E-01 2.8961 8 H4SiO4 0.7223775E-04 0.7414649E-04 0.7126489E+01 -4.1412 9 Ca++ 0.2295797E-04 0.2316281E-04 0.9283021E+00 10.1431 10 Mg++ 0.1353889E-05 0.1367525E-05 0.3324665E-01 8.9137 11 Fe++ 0.1010452E-07 0.1880182E-07 0.1050006E-02 6.7866 12 K+ 0.1613005E-05 0.1613593E-05 0.6309355E-01 1.6044 13 Na+ 0.1695977E-03 0.1696114E-03 0.3899260E+01 3.6262 14 Mn++ 0.1119362E-06 0.1211148E-06 0.6653681E-02 7.8311 15 HPO4-- 0.9390425E-08 0.1533162E-07 0.1471487E-02 6.7549 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1128047E-03 -.2222940E-04 -.9057531E-04 0.0000000E+00 2 H2O 0.5550815E+02 0.5550810E+02 0.5216428E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2571509E-04 0.2549549E-04 0.2196020E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2106219E-06 0.8980121E-08 -.2196020E-06 0.0000000E+00 7 Al+++ 0.2478164E-04 0.1246470E-05 0.2353517E-04 0.0000000E+00 8 H4SiO4 0.7913715E-04 0.7414627E-04 0.4990879E-05 0.0000000E+00 9 Ca++ 0.2321214E-04 0.2316274E-04 0.4940334E-07 0.0000000E+00 10 Mg++ 0.6031746E-05 0.1367521E-05 0.4664225E-05 0.0000000E+00 11 Fe++ 0.5418865E-05 0.1880177E-07 0.5400064E-05 0.0000000E+00 12 K+ 0.1613588E-05 0.1613588E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1696109E-03 0.1696109E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1317733E-06 0.1211144E-06 0.1065893E-07 0.0000000E+00 15 HPO4-- 0.4497358E-07 0.1533158E-07 0.2964201E-07 0.0000000E+00 Chg. balance for solid moles: -.1445E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0076000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.9881E-08 -8.005 0.4963E-05 -5.304 0.2070 0.1577E-05 clinochlore 0.9328E-06 -6.030 0.5185E-03 -3.285 21.63 0.1972E-03 daphnite 0.7286E-06 -6.137 0.5199E-03 -3.284 21.69 0.1575E-03 chlorite-Mn 0.2132E-08 -8.671 0.1511E-05 -5.821 0.6304E-01 0.4816E-06 diaspore 0.2021E-04 -4.694 0.1212E-02 -2.916 50.57 0.3609E-03 hematite 0.8784E-06 -6.056 0.1403E-03 -3.853 5.851 0.2659E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5607E+00 0.5607E+00 1.0000 -0.251 daphnite 0.4380E+00 0.4380E+00 1.0000 -0.359 chlorite-Mn 0.1281E-02 0.1281E-02 1.0000 -2.892 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.002397 g Volume = 0.000744 cm3 Porosity: 99.9258% V(tot) - V(min): 0.10023E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0076000 g log = -2.1192 Original solution: 1000.0103000 g Original solution / Rock added: 131580.30 (Water/Rock Ratio), log = 5.1192 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.9776E-04 1.0073 0.1036E-03 0.1028E-03 CH4,gas 0.5222E-11 1.0129 0.5565E-11 0.5494E-11 H2,gas 0.4639E-05 1.0006 0.4883E-05 0.4881E-05 H2S,gas 0.2264E-07 0.9959 0.2372E-07 0.2381E-07 S2,gas 0.8398E-24 1.0000 0.8835E-24 0.8835E-24 CO,gas 0.1246E-12 1.0000 0.1310E-12 0.1310E-12 SO3,gas 0.1204E-34 1.0000 0.1266E-34 0.1266E-34 SO2,gas 0.2224E-17 1.0000 0.2340E-17 0.2340E-17 HCl,gas 0.1613E-14 1.0000 0.1697E-14 0.1697E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.35 -5.98 -1.995 0.10219E+05 -3.985 3 CH4,gas 4.81 -8.45 -13.25 -3.314 0.22632E+05 -11.255 4 H2,gas 8.29 0.98 -7.31 -4.178 0.12484E+05 -5.311 5 H2S,gas -5.94 -15.57 -9.62 -4.812 0.16434E+05 -7.625 6 S2,gas -7.03 -33.09 -26.05 -4.008 0.44486E+05 -24.054 7 CO,gas 3.51 -11.37 -14.88 -4.579 0.25412E+05 -12.883 8 SO3,gas 17.43 -19.47 -36.90 -9.224 0.63001E+05 -34.897 9 SO2,gas 1.14 -18.49 -19.63 -5.235 0.33519E+05 -17.631 10 HCl,gas 5.48 -11.29 -16.77 -8.385 0.28635E+05 -14.770 21 andalusite 5.06 1.65 -3.41 -0.341 0.58249E+04 24 anhydrite -5.28 -9.33 -4.05 -2.024 0.69107E+04 35 aragonite 0.99 -2.20 -3.19 -1.064 0.54486E+04 36 brucite 12.58 8.91 -3.66 -0.733 0.62543E+04 37 calcite 0.83 -2.20 -3.04 -1.013 0.51873E+04 40 carpholite-Mg 8.65 6.42 -2.23 -0.148 0.38025E+04 41 carpholite-Fe 6.78 4.30 -2.49 -0.166 0.42457E+04 50 chloritoid-Mg 13.26 10.56 -2.70 -0.180 0.46044E+04 51 chloritoid-Fe 9.24 8.44 -0.80 -0.053 0.13679E+04 52 chloritoid-Mn 11.46 9.48 -1.98 -0.132 0.33828E+04 54 coesite -2.37 -4.14 -1.77 -0.591 0.30254E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.14 -1.59 -0.531 0.27183E+04 75 epidote 24.78 19.95 -4.82 -0.234 0.82331E+04 78 fayalite 14.08 9.43 -4.65 -0.664 0.79346E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.08 -4.12 -0.343 0.70294E+04 92 hercynite 17.34 12.58 -4.77 -0.318 0.81373E+04 98 kaolinite -1.27 -2.49 -1.22 -0.111 0.20783E+04 99 kyanite 4.93 1.65 -3.28 -0.328 0.56017E+04 101 laumontite 2.97 -0.63 -3.60 -0.240 0.61542E+04 102 lawsonite 9.68 7.65 -2.03 -0.135 0.34587E+04 105 lizardite 23.29 18.46 -4.83 -0.402 0.82452E+04 106 magnesite 0.71 -3.43 -4.14 -1.381 0.70749E+04 107 magnetite 20.13 19.38 -0.75 -0.061 0.12781E+04 110 magnesioferrite 26.26 21.51 -4.75 -0.387 0.81036E+04 113 margarite 17.45 13.44 -4.01 -0.160 0.68416E+04 120 muscovite 2.68 -2.13 -4.81 -0.283 0.82134E+04 121 paragonite 4.34 -0.11 -4.45 -0.262 0.75913E+04 128 periclase-Fe 11.64 6.79 -4.85 -1.213 0.82856E+04 142 pyrite -21.23 -25.32 -4.10 -0.964 0.69987E+04 143 pyrrhotite -4.24 -8.78 -4.54 -1.512 0.77475E+04 144 pyrrhotiteFe0.875 -6.00 -9.75 -3.75 -1.379 0.64018E+04 145 pyroxmangite 7.42 3.69 -3.73 -0.745 0.63624E+04 146 pyrophyllite -6.10 -10.77 -4.67 -0.292 0.79820E+04 147 quartz -2.98 -4.14 -1.16 -0.386 0.19794E+04 152 rhodochrosite -0.96 -4.52 -3.56 -1.186 0.60756E+04 153 rhodonite 7.46 3.69 -3.77 -0.755 0.64416E+04 156 siderite -2.59 -5.56 -2.97 -0.991 0.50773E+04 157 sillimanite 5.32 1.65 -3.67 -0.367 0.62671E+04 169 sudoite 21.22 16.99 -4.23 -0.136 0.72195E+04 178 topaz-H 4.67 1.65 -3.02 -0.274 0.51508E+04 179 tridymite -2.61 -4.14 -1.53 -0.509 0.26067E+04 182 troilite-low -4.39 -8.78 -4.39 -1.462 0.74907E+04 188 wairakite 4.06 -0.63 -4.69 -0.276 0.80050E+04 190 wollastonite 10.48 6.00 -4.48 -0.896 0.76495E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.14 -1.35 -0.449 0.22997E+04 202 montmorillonite-Ca -2.21 -7.11 -4.90 -0.303 0.83655E+04 204 montmorillonite-Mg -2.40 -7.32 -4.91 -0.304 0.83915E+04 206 nontronite-Ca 3.28 0.03 -3.25 -0.211 0.55511E+04 207 nontronite-H 2.60 -1.65 -4.24 -0.284 0.72410E+04 208 nontronite-K 3.40 -1.12 -4.52 -0.290 0.77167E+04 209 nontronite-Mg 3.14 -0.17 -3.31 -0.215 0.56577E+04 210 nontronite-Na 3.58 -0.45 -4.03 -0.259 0.68832E+04 215 gypsum -4.92 -9.33 -4.40 -1.101 0.75174E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.79 -3.04 -0.759 0.51866E+04 241 silica-amorphous -2.08 -4.14 -2.06 -0.687 0.35199E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0076000 g New total amount of reactant added: 0.0078000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.9764E-15 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0078000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2677046E-03 Osmotic coef. = 0.9902 True ionic strength = .2707552E-03 Chg. balance for total moles = 0.9764E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.39062E-07 -7.4082 0.37538E-07 -7.4255 0.96098E+00 -0.0173 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13256E-03 -3.8776 0.96086E+00 -0.0173 4 SO4-- 0.25348E-04 -4.5961 0.22802E-04 -4.6420 0.89954E+00 -0.0460 5 HCO3- 0.12141E-04 -4.9157 0.11666E-04 -4.9331 0.96089E+00 -0.0173 6 HS- 0.58112E-08 -8.2357 0.55838E-08 -8.2531 0.96086E+00 -0.0173 7 Al+++ 0.51685E-19 -19.2866 0.41638E-19 -19.3805 0.80561E+00 -0.0939 8 H4SiO4 0.74010E-04 -4.1307 0.74010E-04 -4.1307 0.10000E+01 0.0000 9 Ca++ 0.23181E-04 -4.6349 0.20849E-04 -4.6809 0.89941E+00 -0.0460 10 Mg++ 0.12762E-05 -5.8941 0.11477E-05 -5.9402 0.89933E+00 -0.0461 11 Fe++ 0.93459E-08 -8.0294 0.84052E-08 -8.0755 0.89935E+00 -0.0461 12 K+ 0.16555E-05 -5.7811 0.15907E-05 -5.7984 0.96089E+00 -0.0173 13 Na+ 0.16985E-03 -3.7699 0.16320E-03 -3.7873 0.96086E+00 -0.0173 14 Mn++ 0.11363E-06 -6.9445 0.10220E-06 -6.9906 0.89937E+00 -0.0461 15 HPO4-- 0.89231E-08 -8.0495 0.80268E-08 -8.0955 0.89955E+00 -0.0460 16 HSiO3- 0.20020E-05 -5.6985 0.19236E-05 -5.7159 0.96086E+00 -0.0173 17 Ca(HSiO3)+ 0.93518E-09 -9.0291 0.89861E-09 -9.0464 0.96090E+00 -0.0173 18 Mg(HSiO3)+ 0.64066E-10 -10.1934 0.61561E-10 -10.2107 0.96090E+00 -0.0173 19 NaHSiO3,aq 0.49861E-08 -8.3022 0.49861E-08 -8.3022 0.10000E+01 0.0000 20 AlO+ 0.39700E-11 -11.4012 0.38148E-11 -11.4185 0.96090E+00 -0.0173 21 AlOH+2 0.79758E-15 -15.0982 0.71733E-15 -15.1443 0.89938E+00 -0.0461 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.12590E-05 -5.9000 0.12097E-05 -5.9173 0.96083E+00 -0.0174 24 CH4,aq 0.28036E-14 -14.5523 0.28033E-14 -14.5523 0.99992E+00 0.0000 29 CO,aq 0.76963E-16 -16.1137 0.76963E-16 -16.1137 0.10000E+01 0.0000 30 CO2,aq 0.88300E-06 -6.0540 0.88293E-06 -6.0541 0.99992E+00 0.0000 31 CO3-2 0.31945E-07 -7.4956 0.28735E-07 -7.5416 0.89950E+00 -0.0460 32 CaCO3,aq 0.73376E-08 -8.1344 0.73376E-08 -8.1344 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.63781E-08 -8.1953 0.61287E-08 -8.2126 0.96090E+00 -0.0173 34 CaCl+ 0.45834E-08 -8.3388 0.44042E-08 -8.3561 0.96090E+00 -0.0173 35 CaCl2,aq 0.13594E-12 -12.8667 0.13594E-12 -12.8667 0.10000E+01 0.0000 36 CaOH+ 0.40759E-07 -7.3898 0.39165E-07 -7.4071 0.96090E+00 -0.0173 37 CaSO4,aq 0.14812E-06 -6.8294 0.14812E-06 -6.8294 0.10000E+01 0.0000 38 HCl,aq 0.93599E-12 -12.0287 0.93599E-12 -12.0287 0.10000E+01 0.0000 43 FeCl+ 0.18060E-11 -11.7433 0.17354E-11 -11.7606 0.96090E+00 -0.0173 46 FeO,aq 0.23588E-09 -9.6273 0.23588E-09 -9.6273 0.10000E+01 0.0000 47 FeOH+ 0.77254E-08 -8.1121 0.74233E-08 -8.1294 0.96090E+00 -0.0173 48 HFeO2- 0.70343E-10 -10.1528 0.67590E-10 -10.1701 0.96086E+00 -0.0173 49 FeO+ 0.32315E-12 -12.4906 0.31052E-12 -12.5079 0.96090E+00 -0.0173 50 FeOH+2 0.24116E-17 -17.6177 0.21690E-17 -17.6637 0.89938E+00 -0.0461 51 FeO2- 0.45076E-10 -10.3461 0.43312E-10 -10.3634 0.96086E+00 -0.0173 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.33847E-08 -8.4705 0.33845E-08 -8.4705 0.99992E+00 0.0000 54 KCl,aq 0.37338E-11 -11.4279 0.37338E-11 -11.4279 0.10000E+01 0.0000 55 KHSO4,aq 0.36434E-17 -17.4385 0.36434E-17 -17.4385 0.10000E+01 0.0000 56 KOH,aq 0.18474E-10 -10.7334 0.18474E-10 -10.7334 0.10000E+01 0.0000 57 KSO4- 0.58156E-09 -9.2354 0.55880E-09 -9.2527 0.96086E+00 -0.0173 58 MgCO3,aq 0.10093E-09 -9.9960 0.10093E-09 -9.9960 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.35802E-09 -9.4461 0.34402E-09 -9.4634 0.96090E+00 -0.0173 60 MgCl+ 0.22905E-09 -9.6401 0.22009E-09 -9.6574 0.96090E+00 -0.0173 61 MgOH+ 0.12430E-07 -7.9055 0.11944E-07 -7.9229 0.96090E+00 -0.0173 63 MnO,aq 0.76562E-10 -10.1160 0.76562E-10 -10.1160 0.10000E+01 0.0000 64 MnOH+ 0.87258E-08 -8.0592 0.83846E-08 -8.0765 0.96090E+00 -0.0173 65 MnO2-2 0.20890E-17 -17.6801 0.18791E-17 -17.7261 0.89950E+00 -0.0460 66 HMnO2- 0.15905E-13 -13.7985 0.15283E-13 -13.8158 0.96086E+00 -0.0173 69 MnCl+ 0.85329E-10 -10.0689 0.81992E-10 -10.0862 0.96090E+00 -0.0173 70 MnSO4,aq 0.66039E-09 -9.1802 0.66039E-09 -9.1802 0.10000E+01 0.0000 71 NaCl,aq 0.70641E-08 -8.1509 0.70641E-08 -8.1509 0.10000E+01 0.0000 72 NaOH,aq 0.19104E-08 -8.7189 0.19104E-08 -8.7189 0.10000E+01 0.0000 74 OH- 0.16631E-04 -4.7791 0.15980E-04 -4.7964 0.96083E+00 -0.0174 79 HPO3-2 0.95392E-19 -19.0205 0.85806E-19 -19.0665 0.89950E+00 -0.0460 82 H3PO4,aq 0.72815E-13 -13.1378 0.72815E-13 -13.1378 0.10000E+01 0.0000 83 H2PO4- 0.54976E-08 -8.2598 0.52825E-08 -8.2772 0.96088E+00 -0.0173 84 PO4-3 0.23157E-12 -12.6353 0.18674E-12 -12.7288 0.80641E+00 -0.0934 87 H2P2O7-2 0.24280E-17 -17.6148 0.21840E-17 -17.6608 0.89950E+00 -0.0460 88 HP2O7-3 0.14809E-16 -16.8295 0.11930E-16 -16.9234 0.80562E+00 -0.0939 89 P2O7-4 0.11349E-18 -18.9450 0.78405E-19 -19.1057 0.69084E+00 -0.1606 90 H2S,aq 0.62982E-09 -9.2008 0.62977E-09 -9.2008 0.99992E+00 0.0000 91 S2-2 0.22525E-18 -18.6473 0.20261E-18 -18.6933 0.89950E+00 -0.0460 96 SO2,aq 0.45559E-18 -18.3414 0.45559E-18 -18.3414 0.10000E+01 0.0000 97 SO3-2 0.11694E-13 -13.9320 0.10522E-13 -13.9779 0.89977E+00 -0.0459 98 HSO3- 0.24056E-13 -13.6188 0.23115E-13 -13.6361 0.96086E+00 -0.0173 99 HSO4- 0.82647E-09 -9.0828 0.79417E-09 -9.1001 0.96091E+00 -0.0173 101 S2O3-2 0.18814E-15 -15.7255 0.16924E-15 -15.7715 0.89950E+00 -0.0460 Charge balance for all species = 0.9768E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3906201E-07 -.2292019E-04 -.2310175E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999796E+06 0.0000 3 Cl- 0.1379626E-03 0.1379746E-03 0.4891523E+01 3.5480 4 SO4-- 0.2534791E-04 0.2549729E-04 0.2449265E+01 10.2090 5 HCO3- 0.1214092E-04 0.1307004E-04 0.7974825E+00 2.4925 6 HS- 0.5811249E-08 0.7256156E-08 0.2399711E-03 -0.8275 7 Al+++ 0.5168463E-19 0.1279335E-05 0.3451774E-01 2.8961 8 H4SiO4 0.7401015E-04 0.7601814E-04 0.7306379E+01 -4.1307 9 Ca++ 0.2318123E-04 0.2338935E-04 0.9373810E+00 10.1702 10 Mg++ 0.1276177E-05 0.1289359E-05 0.3134632E-01 8.9109 11 Fe++ 0.9345859E-08 0.1762814E-07 0.9844608E-03 6.7756 12 K+ 0.1655452E-05 0.1656056E-05 0.6475390E-01 1.6271 13 Na+ 0.1698485E-03 0.1698624E-03 0.3905031E+01 3.6383 14 Mn++ 0.1136311E-06 0.1231792E-06 0.6767092E-02 7.8605 15 HPO4-- 0.8923133E-08 0.1442102E-07 0.1384089E-02 6.7556 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1161164E-03 -.2292012E-04 -.9319630E-04 0.0000000E+00 2 H2O 0.5550815E+02 0.5550810E+02 0.5357471E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2572063E-04 0.2549721E-04 0.2234207E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2161646E-06 0.7256134E-08 -.2234207E-06 0.0000000E+00 7 Al+++ 0.2543378E-04 0.1279331E-05 0.2415445E-04 0.0000000E+00 8 H4SiO4 0.8121971E-04 0.7601791E-04 0.5201794E-05 0.0000000E+00 9 Ca++ 0.2344217E-04 0.2338928E-04 0.5289354E-07 0.0000000E+00 10 Mg++ 0.6190476E-05 0.1289355E-05 0.4901121E-05 0.0000000E+00 11 Fe++ 0.5561467E-05 0.1762809E-07 0.5543839E-05 0.0000000E+00 12 K+ 0.1656051E-05 0.1656051E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1698619E-03 0.1698619E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1352410E-06 0.1231788E-06 0.1206225E-07 0.0000000E+00 15 HPO4-- 0.4615710E-07 0.1442097E-07 0.3173612E-07 0.0000000E+00 Chg. balance for solid moles: 0.5678E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0078000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1058E-07 -7.976 0.5314E-05 -5.275 0.2150 0.1689E-05 clinochlore 0.9802E-06 -6.009 0.5448E-03 -3.264 22.04 0.2072E-03 daphnite 0.7513E-06 -6.124 0.5361E-03 -3.271 21.69 0.1624E-03 chlorite-Mn 0.2412E-08 -8.618 0.1710E-05 -5.767 0.6920E-01 0.5450E-06 diaspore 0.2069E-04 -4.684 0.1241E-02 -2.906 50.21 0.3695E-03 hematite 0.8937E-06 -6.049 0.1427E-03 -3.846 5.774 0.2705E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5653E+00 0.5653E+00 1.0000 -0.248 daphnite 0.4333E+00 0.4333E+00 1.0000 -0.363 chlorite-Mn 0.1391E-02 0.1391E-02 1.0000 -2.857 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.002472 g Volume = 0.000768 cm3 Porosity: 99.9234% V(tot) - V(min): 0.10024E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0078000 g log = -2.1079 Original solution: 1000.0103000 g Original solution / Rock added: 128206.45 (Water/Rock Ratio), log = 5.1079 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.9537E-04 1.0073 0.1011E-03 0.1003E-03 CH4,gas 0.4160E-11 1.0129 0.4433E-11 0.4377E-11 H2,gas 0.4410E-05 1.0006 0.4642E-05 0.4639E-05 H2S,gas 0.1753E-07 0.9959 0.1837E-07 0.1844E-07 S2,gas 0.5574E-24 1.0000 0.5864E-24 0.5864E-24 CO,gas 0.1155E-12 1.0000 0.1215E-12 0.1215E-12 SO3,gas 0.1142E-34 1.0000 0.1201E-34 0.1201E-34 SO2,gas 0.2005E-17 1.0000 0.2109E-17 0.2109E-17 HCl,gas 0.1571E-14 1.0000 0.1653E-14 0.1653E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.36 -6.00 -1.998 0.10237E+05 -3.995 3 CH4,gas 4.81 -8.54 -13.35 -3.338 0.22800E+05 -11.353 4 H2,gas 8.29 0.95 -7.33 -4.190 0.12521E+05 -5.333 5 H2S,gas -5.94 -15.68 -9.74 -4.868 0.16624E+05 -7.736 6 S2,gas -7.03 -33.26 -26.23 -4.036 0.44790E+05 -24.232 7 CO,gas 3.51 -11.40 -14.92 -4.589 0.25468E+05 -12.915 8 SO3,gas 17.43 -19.49 -36.92 -9.230 0.63041E+05 -34.920 9 SO2,gas 1.14 -18.54 -19.68 -5.247 0.33596E+05 -17.676 10 HCl,gas 5.48 -11.30 -16.78 -8.391 0.28654E+05 -14.782 21 andalusite 5.06 1.66 -3.40 -0.340 0.58070E+04 24 anhydrite -5.28 -9.32 -4.04 -2.022 0.69036E+04 35 aragonite 0.99 -2.19 -3.17 -1.058 0.54207E+04 36 brucite 12.58 8.91 -3.67 -0.733 0.62591E+04 37 calcite 0.83 -2.19 -3.02 -1.007 0.51593E+04 40 carpholite-Mg 8.65 6.44 -2.21 -0.147 0.37713E+04 41 carpholite-Fe 6.78 4.31 -2.48 -0.165 0.42286E+04 50 chloritoid-Mg 13.26 10.57 -2.69 -0.179 0.45912E+04 51 chloritoid-Fe 9.24 8.44 -0.80 -0.053 0.13687E+04 52 chloritoid-Mn 11.46 9.52 -1.94 -0.129 0.33146E+04 54 coesite -2.37 -4.13 -1.76 -0.587 0.30075E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.13 -1.58 -0.527 0.27004E+04 75 epidote 24.78 20.04 -4.74 -0.230 0.80866E+04 78 fayalite 14.08 9.42 -4.66 -0.665 0.79542E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.07 -4.13 -0.344 0.70498E+04 92 hercynite 17.34 12.57 -4.78 -0.318 0.81561E+04 98 kaolinite -1.27 -2.47 -1.20 -0.109 0.20423E+04 99 kyanite 4.93 1.66 -3.27 -0.327 0.55837E+04 101 laumontite 2.97 -0.56 -3.54 -0.236 0.60360E+04 102 lawsonite 9.68 7.70 -1.98 -0.132 0.33764E+04 105 lizardite 23.29 18.47 -4.82 -0.401 0.82234E+04 106 magnesite 0.71 -3.45 -4.16 -1.386 0.70980E+04 107 magnetite 20.13 19.37 -0.76 -0.062 0.12969E+04 110 magnesioferrite 26.26 21.51 -4.75 -0.388 0.81084E+04 113 margarite 17.45 13.49 -3.96 -0.158 0.67594E+04 120 muscovite 2.68 -2.08 -4.76 -0.280 0.81206E+04 121 paragonite 4.34 -0.07 -4.40 -0.259 0.75167E+04 128 periclase-Fe 11.64 6.78 -4.86 -1.216 0.83043E+04 142 pyrite -21.23 -25.54 -4.31 -1.014 0.73590E+04 143 pyrrhotite -4.24 -8.90 -4.66 -1.553 0.79558E+04 144 pyrrhotiteFe0.875 -6.00 -9.87 -3.87 -1.422 0.66031E+04 145 pyroxmangite 7.42 3.73 -3.69 -0.737 0.62942E+04 146 pyrophyllite -6.10 -10.73 -4.63 -0.290 0.79101E+04 147 quartz -2.98 -4.13 -1.15 -0.383 0.19614E+04 152 rhodochrosite -0.96 -4.50 -3.54 -1.180 0.60437E+04 153 rhodonite 7.46 3.73 -3.73 -0.747 0.63734E+04 156 siderite -2.59 -5.58 -3.00 -0.998 0.51144E+04 157 sillimanite 5.32 1.66 -3.66 -0.366 0.62491E+04 169 sudoite 21.22 17.01 -4.20 -0.136 0.71751E+04 178 topaz-H 4.67 1.66 -3.01 -0.273 0.51328E+04 179 tridymite -2.61 -4.13 -1.52 -0.505 0.25887E+04 182 troilite-low -4.39 -8.90 -4.51 -1.503 0.76990E+04 188 wairakite 4.06 -0.56 -4.62 -0.272 0.78868E+04 190 wollastonite 10.48 6.04 -4.44 -0.888 0.75852E+04 191 pseudo-wollastonite 11.02 6.04 -4.98 -0.996 0.85038E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.13 -1.34 -0.445 0.22817E+04 202 montmorillonite-Ca -2.21 -7.07 -4.85 -0.300 0.82875E+04 204 montmorillonite-Mg -2.40 -7.28 -4.87 -0.302 0.83220E+04 206 nontronite-Ca 3.28 0.07 -3.21 -0.208 0.54775E+04 207 nontronite-H 2.60 -1.61 -4.20 -0.282 0.71750E+04 208 nontronite-K 3.40 -1.07 -4.47 -0.287 0.76379E+04 209 nontronite-Mg 3.14 -0.14 -3.28 -0.212 0.55925E+04 210 nontronite-Na 3.58 -0.41 -3.99 -0.256 0.68104E+04 215 gypsum -4.92 -9.32 -4.40 -1.100 0.75104E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.78 -3.05 -0.762 0.52054E+04 241 silica-amorphous -2.08 -4.13 -2.05 -0.684 0.35019E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0078000 g New total amount of reactant added: 0.0080000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.9765E-15 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0080000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2683099E-03 Osmotic coef. = 0.9902 True ionic strength = .2715025E-03 Chg. balance for total moles = 0.9765E-15 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.38056E-07 -7.4196 0.36570E-07 -7.4369 0.96095E+00 -0.0173 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13256E-03 -3.8776 0.96083E+00 -0.0174 4 SO4-- 0.25348E-04 -4.5961 0.22799E-04 -4.6421 0.89944E+00 -0.0460 5 HCO3- 0.12161E-04 -4.9150 0.11685E-04 -4.9324 0.96086E+00 -0.0173 6 HS- 0.46630E-08 -8.3313 0.44804E-08 -8.3487 0.96083E+00 -0.0174 7 Al+++ 0.47801E-19 -19.3206 0.38499E-19 -19.4146 0.80540E+00 -0.0940 8 H4SiO4 0.75784E-04 -4.1204 0.75784E-04 -4.1204 0.10000E+01 0.0000 9 Ca++ 0.23405E-04 -4.6307 0.21048E-04 -4.6768 0.89931E+00 -0.0461 10 Mg++ 0.12031E-05 -5.9197 0.10819E-05 -5.9658 0.89922E+00 -0.0461 11 Fe++ 0.86586E-08 -8.0626 0.77862E-08 -8.1087 0.89924E+00 -0.0461 12 K+ 0.16979E-05 -5.7701 0.16315E-05 -5.7874 0.96086E+00 -0.0173 13 Na+ 0.17010E-03 -3.7693 0.16344E-03 -3.7867 0.96083E+00 -0.0174 14 Mn++ 0.11521E-06 -6.9385 0.10360E-06 -6.9846 0.89926E+00 -0.0461 15 HPO4-- 0.84837E-08 -8.0714 0.76306E-08 -8.1174 0.89944E+00 -0.0460 16 HSiO3- 0.21043E-05 -5.6769 0.20219E-05 -5.6942 0.96083E+00 -0.0174 17 Ca(HSiO3)+ 0.99232E-09 -9.0033 0.95349E-09 -9.0207 0.96087E+00 -0.0173 18 Mg(HSiO3)+ 0.63479E-10 -10.1974 0.60995E-10 -10.2147 0.96087E+00 -0.0173 19 NaHSiO3,aq 0.52484E-08 -8.2800 0.52484E-08 -8.2800 0.10000E+01 0.0000 20 AlO+ 0.38677E-11 -11.4125 0.37164E-11 -11.4299 0.96087E+00 -0.0173 21 AlOH+2 0.75706E-15 -15.1209 0.68081E-15 -15.1670 0.89928E+00 -0.0461 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.12924E-05 -5.8886 0.12417E-05 -5.9060 0.96080E+00 -0.0174 24 CH4,aq 0.22535E-14 -14.6471 0.22533E-14 -14.6472 0.99992E+00 0.0000 29 CO,aq 0.71546E-16 -16.1454 0.71546E-16 -16.1454 0.10000E+01 0.0000 30 CO2,aq 0.86163E-06 -6.0647 0.86156E-06 -6.0647 0.99992E+00 0.0000 31 CO3-2 0.32848E-07 -7.4835 0.29544E-07 -7.5295 0.89940E+00 -0.0460 32 CaCO3,aq 0.76159E-08 -8.1183 0.76159E-08 -8.1183 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.64495E-08 -8.1905 0.61971E-08 -8.2078 0.96087E+00 -0.0173 34 CaCl+ 0.46270E-08 -8.3347 0.44460E-08 -8.3520 0.96087E+00 -0.0173 35 CaCl2,aq 0.13722E-12 -12.8626 0.13722E-12 -12.8626 0.10000E+01 0.0000 36 CaOH+ 0.42237E-07 -7.3743 0.40584E-07 -7.3916 0.96087E+00 -0.0173 37 CaSO4,aq 0.14951E-06 -6.8253 0.14951E-06 -6.8253 0.10000E+01 0.0000 38 HCl,aq 0.91182E-12 -12.0401 0.91182E-12 -12.0401 0.10000E+01 0.0000 43 FeCl+ 0.16730E-11 -11.7765 0.16076E-11 -11.7938 0.96087E+00 -0.0173 46 FeO,aq 0.23023E-09 -9.6378 0.23023E-09 -9.6378 0.10000E+01 0.0000 47 FeOH+ 0.73461E-08 -8.1339 0.70587E-08 -8.1513 0.96087E+00 -0.0173 48 HFeO2- 0.70478E-10 -10.1519 0.67718E-10 -10.1693 0.96083E+00 -0.0174 49 FeO+ 0.31483E-12 -12.5019 0.30251E-12 -12.5193 0.96087E+00 -0.0173 50 FeOH+2 0.22891E-17 -17.6403 0.20585E-17 -17.6864 0.89928E+00 -0.0461 51 FeO2- 0.46270E-10 -10.3347 0.44458E-10 -10.3520 0.96083E+00 -0.0174 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.32246E-08 -8.4915 0.32243E-08 -8.4916 0.99992E+00 0.0000 54 KCl,aq 0.38293E-11 -11.4169 0.38293E-11 -11.4169 0.10000E+01 0.0000 55 KHSO4,aq 0.36399E-17 -17.4389 0.36399E-17 -17.4389 0.10000E+01 0.0000 56 KOH,aq 0.19449E-10 -10.7111 0.19449E-10 -10.7111 0.10000E+01 0.0000 57 KSO4- 0.59640E-09 -9.2245 0.57304E-09 -9.2418 0.96083E+00 -0.0174 58 MgCO3,aq 0.97820E-10 -10.0096 0.97820E-10 -10.0096 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.33805E-09 -9.4710 0.32483E-09 -9.4883 0.96087E+00 -0.0173 60 MgCl+ 0.21591E-09 -9.6657 0.20746E-09 -9.6831 0.96087E+00 -0.0173 61 MgOH+ 0.12028E-07 -7.9198 0.11557E-07 -7.9372 0.96087E+00 -0.0173 63 MnO,aq 0.81777E-10 -10.0874 0.81777E-10 -10.0874 0.10000E+01 0.0000 64 MnOH+ 0.90801E-08 -8.0419 0.87247E-08 -8.0592 0.96087E+00 -0.0173 65 MnO2-2 0.23513E-17 -17.6287 0.21148E-17 -17.6747 0.89940E+00 -0.0460 66 HMnO2- 0.17439E-13 -13.7585 0.16756E-13 -13.7758 0.96083E+00 -0.0174 69 MnCl+ 0.86500E-10 -10.0630 0.83115E-10 -10.0803 0.96087E+00 -0.0173 70 MnSO4,aq 0.66937E-09 -9.1743 0.66937E-09 -9.1743 0.10000E+01 0.0000 71 NaCl,aq 0.70741E-08 -8.1503 0.70741E-08 -8.1503 0.10000E+01 0.0000 72 NaOH,aq 0.19638E-08 -8.7069 0.19638E-08 -8.7069 0.10000E+01 0.0000 74 OH- 0.17072E-04 -4.7677 0.16403E-04 -4.7851 0.96080E+00 -0.0174 79 HPO3-2 0.86403E-19 -19.0635 0.77710E-19 -19.1095 0.89940E+00 -0.0460 82 H3PO4,aq 0.65697E-13 -13.1825 0.65697E-13 -13.1825 0.10000E+01 0.0000 83 H2PO4- 0.50916E-08 -8.2931 0.48922E-08 -8.3105 0.96085E+00 -0.0173 84 PO4-3 0.22603E-12 -12.6458 0.18222E-12 -12.7394 0.80620E+00 -0.0936 87 H2P2O7-2 0.20827E-17 -17.6814 0.18732E-17 -17.7274 0.89940E+00 -0.0460 88 HP2O7-3 0.13041E-16 -16.8847 0.10503E-16 -16.9787 0.80541E+00 -0.0940 89 P2O7-4 0.10261E-18 -18.9888 0.70856E-19 -19.1496 0.69051E+00 -0.1608 90 H2S,aq 0.49233E-09 -9.3077 0.49229E-09 -9.3078 0.99992E+00 0.0000 91 S2-2 0.15225E-18 -18.8175 0.13693E-18 -18.8635 0.89940E+00 -0.0460 96 SO2,aq 0.41188E-18 -18.3852 0.41188E-18 -18.3852 0.10000E+01 0.0000 97 SO3-2 0.11141E-13 -13.9531 0.10023E-13 -13.9990 0.89966E+00 -0.0459 98 HSO3- 0.22325E-13 -13.6512 0.21450E-13 -13.6686 0.96083E+00 -0.0174 99 HSO4- 0.80508E-09 -9.0942 0.77359E-09 -9.1115 0.96089E+00 -0.0173 101 S2O3-2 0.14707E-15 -15.8325 0.13228E-15 -15.8785 0.89940E+00 -0.0460 Charge balance for all species = 0.9768E-15 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3805572E-07 -.2362226E-04 -.2380938E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999794E+06 0.0000 3 Cl- 0.1379626E-03 0.1379746E-03 0.4891522E+01 3.5593 4 SO4-- 0.2534781E-04 0.2549862E-04 0.2449392E+01 10.2317 5 HCO3- 0.1216106E-04 0.1307004E-04 0.7974824E+00 2.5045 6 HS- 0.4663033E-08 0.5930258E-08 0.1961218E-03 -0.9118 7 Al+++ 0.4780077E-19 0.1312703E-05 0.3541803E-01 2.8961 8 H4SiO4 0.7578389E-04 0.7789451E-04 0.7486722E+01 -4.1204 9 Ca++ 0.2340456E-04 0.2361600E-04 0.9464643E+00 10.1970 10 Mg++ 0.1203141E-05 0.1215884E-05 0.2956002E-01 8.9079 11 Fe++ 0.8658632E-08 0.1655721E-07 0.9246530E-03 6.7651 12 K+ 0.1697899E-05 0.1698519E-05 0.6641425E-01 1.6495 13 Na+ 0.1700992E-03 0.1701135E-03 0.3910802E+01 3.6502 14 Mn++ 0.1152051E-06 0.1251229E-06 0.6873872E-02 7.8891 15 HPO4-- 0.8483688E-08 0.1357557E-07 0.1302945E-02 6.7563 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1194281E-03 -.2362219E-04 -.9580593E-04 0.0000000E+00 2 H2O 0.5550815E+02 0.5550809E+02 0.5498415E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2572618E-04 0.2549854E-04 0.2276375E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2217073E-06 0.5930240E-08 -.2276375E-06 0.0000000E+00 7 Al+++ 0.2608593E-04 0.1312699E-05 0.2477323E-04 0.0000000E+00 8 H4SiO4 0.8330226E-04 0.7789427E-04 0.5407994E-05 0.0000000E+00 9 Ca++ 0.2367220E-04 0.2361593E-04 0.5627515E-07 0.0000000E+00 10 Mg++ 0.6349206E-05 0.1215880E-05 0.5133326E-05 0.0000000E+00 11 Fe++ 0.5704069E-05 0.1655715E-07 0.5687512E-05 0.0000000E+00 12 K+ 0.1698514E-05 0.1698514E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1701129E-03 0.1701129E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1387088E-06 0.1251225E-06 0.1358629E-07 0.0000000E+00 15 HPO4-- 0.4734061E-07 0.1357552E-07 0.3376509E-07 0.0000000E+00 Chg. balance for solid moles: -.5175E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0080000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1126E-07 -7.949 0.5654E-05 -5.248 0.2221 0.1797E-05 clinochlore 0.1027E-05 -5.989 0.5707E-03 -3.244 22.42 0.2171E-03 daphnite 0.7733E-06 -6.112 0.5517E-03 -3.258 21.68 0.1672E-03 chlorite-Mn 0.2717E-08 -8.566 0.1926E-05 -5.715 0.7569E-01 0.6139E-06 diaspore 0.2117E-04 -4.674 0.1270E-02 -2.896 49.89 0.3780E-03 hematite 0.9106E-06 -6.041 0.1454E-03 -3.837 5.713 0.2756E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5695E+00 0.5695E+00 1.0000 -0.244 daphnite 0.4290E+00 0.4290E+00 1.0000 -0.368 chlorite-Mn 0.1507E-02 0.1507E-02 1.0000 -2.822 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.002545 g Volume = 0.000792 cm3 Porosity: 99.9210% V(tot) - V(min): 0.10024E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0080000 g log = -2.0969 Original solution: 1000.0103000 g Original solution / Rock added: 125001.29 (Water/Rock Ratio), log = 5.0969 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.9306E-04 1.0073 0.9862E-04 0.9790E-04 CH4,gas 0.3344E-11 1.0129 0.3563E-11 0.3518E-11 H2,gas 0.4201E-05 1.0006 0.4422E-05 0.4420E-05 H2S,gas 0.1370E-07 0.9959 0.1436E-07 0.1442E-07 S2,gas 0.3753E-24 1.0000 0.3948E-24 0.3948E-24 CO,gas 0.1074E-12 1.0000 0.1130E-12 0.1130E-12 SO3,gas 0.1083E-34 1.0000 0.1140E-34 0.1140E-34 SO2,gas 0.1813E-17 1.0000 0.1907E-17 0.1907E-17 HCl,gas 0.1530E-14 1.0000 0.1610E-14 0.1610E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.37 -6.01 -2.002 0.10255E+05 -4.006 3 CH4,gas 4.81 -8.64 -13.45 -3.362 0.22962E+05 -11.448 4 H2,gas 8.29 0.93 -7.35 -4.202 0.12557E+05 -5.354 5 H2S,gas -5.94 -15.79 -9.84 -4.921 0.16807E+05 -7.843 6 S2,gas -7.03 -33.44 -26.40 -4.062 0.45083E+05 -24.404 7 CO,gas 3.51 -11.44 -14.95 -4.599 0.25522E+05 -12.947 8 SO3,gas 17.43 -19.52 -36.94 -9.236 0.63079E+05 -34.943 9 SO2,gas 1.14 -18.58 -19.72 -5.259 0.33671E+05 -17.720 10 HCl,gas 5.48 -11.31 -16.79 -8.397 0.28674E+05 -14.793 21 andalusite 5.06 1.67 -3.39 -0.339 0.57894E+04 24 anhydrite -5.28 -9.32 -4.04 -2.020 0.68967E+04 35 aragonite 0.99 -2.17 -3.16 -1.053 0.53931E+04 36 brucite 12.58 8.91 -3.67 -0.734 0.62641E+04 37 calcite 0.83 -2.17 -3.01 -1.002 0.51317E+04 40 carpholite-Mg 8.65 6.46 -2.19 -0.146 0.37412E+04 41 carpholite-Fe 6.78 4.32 -2.47 -0.164 0.42114E+04 50 chloritoid-Mg 13.26 10.58 -2.68 -0.179 0.45787E+04 51 chloritoid-Fe 9.24 8.44 -0.80 -0.053 0.13691E+04 52 chloritoid-Mn 11.46 9.56 -1.90 -0.127 0.32482E+04 54 coesite -2.37 -4.12 -1.75 -0.584 0.29899E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.12 -1.57 -0.524 0.26828E+04 75 epidote 24.78 20.12 -4.65 -0.226 0.79424E+04 78 fayalite 14.08 9.41 -4.67 -0.667 0.79725E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.05 -4.14 -0.345 0.70686E+04 92 hercynite 17.34 12.56 -4.79 -0.319 0.81741E+04 98 kaolinite -1.27 -2.45 -1.18 -0.107 0.20072E+04 99 kyanite 4.93 1.67 -3.26 -0.326 0.55662E+04 101 laumontite 2.97 -0.49 -3.47 -0.231 0.59200E+04 102 lawsonite 9.68 7.75 -1.93 -0.129 0.32955E+04 105 lizardite 23.29 18.48 -4.80 -0.400 0.82034E+04 106 magnesite 0.71 -3.46 -4.17 -1.390 0.71212E+04 107 magnetite 20.13 19.36 -0.77 -0.063 0.13149E+04 110 magnesioferrite 26.26 21.51 -4.75 -0.388 0.81134E+04 113 margarite 17.45 13.54 -3.91 -0.156 0.66785E+04 120 muscovite 2.68 -2.02 -4.70 -0.277 0.80298E+04 121 paragonite 4.34 -0.02 -4.36 -0.256 0.74436E+04 128 periclase-Fe 11.64 6.77 -4.87 -1.219 0.83223E+04 142 pyrite -21.23 -25.74 -4.51 -1.062 0.77063E+04 143 pyrrhotite -4.24 -9.02 -4.78 -1.592 0.81564E+04 144 pyrrhotiteFe0.875 -6.00 -9.98 -3.98 -1.464 0.67970E+04 145 pyroxmangite 7.42 3.77 -3.65 -0.729 0.62277E+04 146 pyrophyllite -6.10 -10.69 -4.59 -0.287 0.78398E+04 147 quartz -2.98 -4.12 -1.14 -0.379 0.19438E+04 152 rhodochrosite -0.96 -4.48 -3.52 -1.174 0.60130E+04 153 rhodonite 7.46 3.77 -3.69 -0.739 0.63070E+04 156 siderite -2.59 -5.60 -3.02 -1.005 0.51506E+04 157 sillimanite 5.32 1.67 -3.65 -0.365 0.62316E+04 169 sudoite 21.22 17.04 -4.18 -0.135 0.71325E+04 178 topaz-H 4.67 1.67 -3.00 -0.272 0.51153E+04 179 tridymite -2.61 -4.12 -1.51 -0.502 0.25711E+04 182 troilite-low -4.39 -9.02 -4.63 -1.542 0.78996E+04 188 wairakite 4.06 -0.49 -4.55 -0.268 0.77708E+04 190 wollastonite 10.48 6.08 -4.41 -0.881 0.75219E+04 191 pseudo-wollastonite 11.02 6.08 -4.94 -0.989 0.84405E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.12 -1.33 -0.442 0.22641E+04 202 montmorillonite-Ca -2.21 -7.02 -4.81 -0.297 0.82114E+04 204 montmorillonite-Mg -2.40 -7.24 -4.83 -0.299 0.82542E+04 206 nontronite-Ca 3.28 0.11 -3.17 -0.205 0.54055E+04 207 nontronite-H 2.60 -1.57 -4.16 -0.279 0.71105E+04 208 nontronite-K 3.40 -1.02 -4.43 -0.284 0.75609E+04 209 nontronite-Mg 3.14 -0.10 -3.24 -0.210 0.55289E+04 210 nontronite-Na 3.58 -0.36 -3.95 -0.253 0.67392E+04 215 gypsum -4.92 -9.32 -4.39 -1.099 0.75035E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.77 -3.06 -0.765 0.52234E+04 241 silica-amorphous -2.08 -4.12 -2.04 -0.680 0.34843E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0002000 g Current total amount of reactant added: 0.0080000 g New total amount of reactant added: 0.0082000 g Mixing fraction reached given limit of 0.8000E-02 TOTMIX = 0.8200E-02 Execution stopped.