File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.11943E-03 0.38056E-07 0.9609 0.00000000E+00 H2O 2 0. 0.55508E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13796E-03 0.9608 0.00000000E+00 SO4-- 4 -2. 0.25726E-04 0.25348E-04 0.8994 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.12161E-04 0.9609 0.00000000E+00 HS- 6 -1. -0.22171E-06 0.46630E-08 0.9608 0.00000000E+00 Al+++ 7 3. 0.26086E-04 0.47801E-19 0.8054 0.00000000E+00 H4SiO4 8 0. 0.83302E-04 0.75784E-04 1.0000 0.00000000E+00 Ca++ 9 2. 0.23672E-04 0.23405E-04 0.8993 0.00000000E+00 Mg++ 10 2. 0.63492E-05 0.12031E-05 0.8992 0.00000000E+00 Fe++ 11 2. 0.57041E-05 0.86586E-08 0.8992 0.00000000E+00 K+ 12 1. 0.16985E-05 0.16979E-05 0.9609 0.00000000E+00 Na+ 13 1. 0.17011E-03 0.17010E-03 0.9608 0.00000000E+00 Mn++ 14 2. 0.13871E-06 0.11521E-06 0.8993 0.00000000E+00 HPO4-- 15 -2. 0.47341E-07 0.84837E-08 0.8994 0.00000000E+00 Chg. balance for total moles = 0.1648E-14 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 100.0000 SLIM = 0.200000E-01 TEMP = 100.0000 SINC = 0.4000E-03 TEMPC = 0.0000 TOTMIX = 0.800000E-02 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 1.0032 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0107 MnO2-2 65 -2. 40.4376 Ca(HSiO3)+ 17 1. 7.6603 HMnO2- 66 -1. 29.1018 Mg(HSiO3)+ 18 1. 7.5653 MnO4- 67 -1. 83.3383 NaHSiO3,aq 19 0. 7.8098 MnO4-2 68 -2. 81.3024 AlO+ 20 1. 6.8891 MnCl+ 69 1. -0.7819 AlOH+2 21 2. 3.1893 MnSO4,aq 70 0. -2.4524 HAlO2,aq 22 0. 10.5878 NaCl,aq 71 0. 0.4861 AlO2- 23 -1. 16.2390 NaOH,aq 72 0. 12.3571 CH4,aq 24 0. 6.0082 O2,aq 73 0. 53.5759 C2H6,aq 25 0. 12.3556 OH- 74 -1. 12.2220 C3H8,aq 26 0. 17.3423 HO2- 75 -1. 50.7897 C4H10,aq 27 0. 22.3397 H2O2,aq 76 0. 40.0297 ethanol,aq 28 0. 15.3114 H3PO2,aq 77 0. 24.3310 CO,aq 29 0. 4.7087 H2PO2- 78 -1. 26.5491 CO2,aq 30 0. -6.3045 HPO3-2 79 -2. 11.9246 CO3-2 31 -2. 10.0340 H3PO3,aq 80 0. 3.5932 CaCO3,aq 32 0. 5.9460 H2PO3- 81 -1. 5.6314 Ca(HCO3)+ 33 1. -1.4013 H3PO4,aq 82 0. -9.8087 CaCl+ 34 1. -0.2023 H2PO4- 83 -1. -7.2438 CaCl2,aq 35 0. 0.4306 PO4-3 84 -3. 12.0588 CaOH+ 36 1. 10.1517 H4P2O7,aq 85 0. -17.7539 CaSO4,aq 37 0. -2.4936 H3P2O7- 86 -1. -15.8646 HCl,aq 38 0. 0.7256 H2P2O7-2 87 -2. -13.3812 HClO,aq 39 0. 32.4377 HP2O7-3 88 -3. -6.6931 ClO- 40 -1. 39.6416 P2O7-4 89 -4. 2.9147 HClO2,aq 41 0. 70.2060 H2S,aq 90 0. -6.4778 Fe+3 42 3. 8.3763 S2-2 91 -2. 1.2336 FeCl+ 43 1. -0.1924 S3-2 92 -2. -8.7963 FeCl2,aq 44 0. 4.3160 S3- 93 -1. -16.3178 FeCl+2 45 2. 6.5223 S4-2 94 -2. -18.6473 FeO,aq 46 0. 16.4029 S5-2 95 -2. -28.3223 FeOH+ 47 1. 7.4795 SO2,aq 96 0. -0.1980 HFeO2- 48 -1. 24.3713 SO3-2 97 -2. 10.2895 FeO+ 49 1. 11.3812 HSO3- 98 -1. 2.5222 FeOH+2 50 2. 9.1115 HSO4- 99 -1. -2.9675 FeO2- 51 -1. 24.0877 HSO5- 100 -1. 38.8657 HFeO2,aq 52 0. 15.9903 S2O3-2 101 -2. -4.5491 H2,aq 53 0. 9.4241 HS2O3- 102 -1. -6.8007 KCl,aq 54 0. 1.7519 H2S2O3,aq 103 0. -7.9944 KHSO4,aq 55 0. -0.4275 S2O4-2 104 -2. 10.5639 KOH,aq 56 0. 12.3606 HS2O4- 105 -1. 7.6762 KSO4- 57 -1. -1.1877 H2S2O4,aq 106 0. 6.6566 MgCO3,aq 58 0. 6.5483 S2O5-2 107 -2. 10.0891 Mg(HCO3)+ 59 1. -1.4098 S2O6-2 108 -2. 11.5737 MgCl+ 60 1. -0.1603 S2O8-2 109 -2. 42.1139 MgOH+ 61 1. 9.4082 S3O6-2 110 -2. 3.8101 Mn+3 62 3. 19.1332 S4O6-2 111 -2. -17.8301 MnO,aq 63 0. 17.9765 S5O6-2 112 -2. -14.1051 MnOH+ 64 1. 8.5115 113 0. 10.3157 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.984 0.0000E+00 osumilite(2) 124 20.895 0.0000E+00 CO2,gas 2 -6.363 0.0000E+00 osumilite-Fe 125 14.657 0.0000E+00 CH4,gas 3 4.809 0.0000E+00 pargasite 126 65.279 0.0000E+00 H2,gas 4 8.287 0.0000E+00 periclase 127 16.149 0.0000E+00 H2S,gas 5 -5.943 0.0000E+00 periclase-Fe 128 11.639 0.0000E+00 S2,gas 6 -7.033 0.0000E+00 perovskite-Al 129 12.395 0.0000E+00 CO,gas 7 3.510 0.0000E+00 perovskite-Ca 130 23.818 0.0000E+00 SO3,gas 8 17.427 0.0000E+00 perovskite-Fe 131 21.158 0.0000E+00 SO2,gas 9 1.136 0.0000E+00 perovskite-Mg 132 23.132 0.0000E+00 HCl,gas 10 5.479 0.0000E+00 phase_A 133 80.267 0.0000E+00 acmite 11 7.737 0.0000E+00 phlogopite-Na 134 29.731 0.0000E+00 akermanite 12 36.495 0.0000E+00 piemontite(ordered) 135 33.876 0.0000E+00 akimotoite 13 16.606 0.0000E+00 prehnite 136 19.466 0.0000E+00 akimotoite-Fe 14 13.083 0.0000E+00 prehnite-Fe 137 22.587 0.0000E+00 albite-high 15 0.750 0.0000E+00 pumpellyite-Fe 138 46.471 0.0000E+00 albite 16 -0.328 0.0000E+00 pumpellyite-Mg 139 49.194 0.0000E+00 almandine 17 24.545 0.0000E+00 px-Mg-tschermaks 140 19.687 0.0000E+00 pyrope 18 37.348 0.0000E+00 px-Ca-tschermaks 141 18.679 0.0000E+00 spessartine 19 24.550 0.0000E+00 pyrite 142 -21.225 0.0000E+00 analcite 20 3.371 0.0000E+00 pyrrhotite 143 -4.244 0.0000E+00 andalusite 21 5.062 0.0000E+00 pyrrhotiteFe0.875 144 -6.001 0.0000E+00 andradite 22 39.088 0.0000E+00 pyroxmangite 145 7.416 0.0000E+00 grossular 23 32.828 0.0000E+00 pyrophyllite 146 -6.098 0.0000E+00 anhydrite 24 -5.280 0.0000E+00 quartz 147 -2.982 0.0000E+00 ankerite 25 -2.093 0.0000E+00 rankinite 148 40.765 0.0000E+00 annite 26 20.209 0.0000E+00 riebeckite 149 20.593 0.0000E+00 phlogopite 27 27.147 0.0000E+00 ringwoodite-Fe 150 15.486 0.0000E+00 biotite-Mn 28 33.034 0.0000E+00 ringwoodite-Mg 151 27.602 0.0000E+00 anorthite 29 12.798 0.0000E+00 rhodochrosite 152 -0.959 0.0000E+00 anthophyllite 30 51.988 0.0000E+00 rhodonite 153 7.462 0.0000E+00 anthophyllite-Fe 31 29.455 0.0000E+00 sanidine 154 -1.221 0.0000E+00 apatite-OH 32 -17.989 0.1126E-07 sapphirine(351) 155 79.204 0.0000E+00 apatite-OH-zs 33 -12.572 0.0000E+00 siderite 156 -2.588 0.0000E+00 apatite-Cl-zs 34 -16.504 0.0000E+00 sillimanite 157 5.321 0.0000E+00 aragonite 35 0.986 0.0000E+00 sodalite 158 50.255 0.0000E+00 brucite 36 12.577 0.0000E+00 spinel 159 20.934 0.0000E+00 calcite 37 0.833 0.0000E+00 spurrite 160 59.566 0.0000E+00 carnegieite-low 38 9.065 0.0000E+00 staurolite-Fe 161 74.138 0.0000E+00 carnegieite-high 39 10.134 0.0000E+00 staurolite-Mg 162 90.336 0.0000E+00 carpholite-Mg 40 8.650 0.0000E+00 staurolite-Mn 163 84.438 0.0000E+00 carpholite-Fe 41 6.783 0.0000E+00 stilbite 164 -7.406 0.0000E+00 celadonite 42 5.401 0.0000E+00 stilpnomelane-Fe 165 13.179 0.0000E+00 celadonite-Fe 43 3.937 0.0000E+00 stilpnomelane-Mg 166 27.596 0.0000E+00 chrysotile 44 23.937 0.0000E+00 stishovite 167 2.721 0.0000E+00 chondrodite 45 56.542 0.0000E+00 sudoite-Fe 168 18.437 0.0000E+00 clinochlore 46 39.193 0.1027E-05 sudoite 169 21.216 0.0000E+00 daphnite 47 29.094 0.7733E-06 sulfur 170 -9.141 0.0000E+00 chlorite-Mn 48 46.985 0.2717E-08 sylvite 171 1.345 0.0000E+00 chlorite-Al-free 49 47.262 0.0000E+00 talc 172 16.553 0.0000E+00 chloritoid-Mg 50 13.261 0.0000E+00 talc-Fe 173 13.516 0.0000E+00 chloritoid-Fe 51 9.239 0.0000E+00 talc-tschermaks 174 19.189 0.0000E+00 chloritoid-Mn 52 11.463 0.0000E+00 tephroite 175 18.113 0.0000E+00 clinohumite 53 97.255 0.0000E+00 tilleyite 176 41.473 0.0000E+00 coesite 54 -2.369 0.0000E+00 titanite-CaSi 177 15.497 0.0000E+00 cordierite-H 55 23.898 0.0000E+00 topaz-H 178 4.668 0.0000E+00 cordierite 56 24.245 0.0000E+00 tridymite 179 -2.615 0.0000E+00 cordierite-Fe 57 20.649 0.0000E+00 tremolite 180 48.003 0.0000E+00 cordierite-Mn 58 25.261 0.0000E+00 ferroactinolite 181 38.596 0.0000E+00 corundum 59 8.433 0.0000E+00 troilite-low 182 -4.394 0.0000E+00 corundum-MgSi 60 18.905 0.0000E+00 tschermakite 183 48.414 0.0000E+00 cristobalite 61 -2.549 0.0000E+00 vesuvianite 184 224.056 0.0000E+00 cummingtonite 62 52.233 0.0000E+00 wadeite-Si 185 20.233 0.0000E+00 cymrite-K 63 1.731 0.0000E+00 wadsleyite-Fe 186 15.711 0.0000E+00 deerite 64 95.982 0.0000E+00 wadsleyite-Mg 187 25.878 0.0000E+00 diaspore 65 2.896 0.2117E-04 wairakite 188 4.058 0.0000E+00 diamond 66 -3.107 0.0000E+00 walstromite 189 11.528 0.0000E+00 diopside 67 16.215 0.0000E+00 wollastonite 190 10.482 0.0000E+00 hedenbergite 68 14.244 0.0000E+00 pseudo-wollastonite 191 11.020 0.0000E+00 dolomite,ordered 69 0.587 0.0000E+00 zoisite 192 22.964 0.0000E+00 eastonite 70 28.605 0.0000E+00 akaganeite 193 7.768 0.0000E+00 enstatite 71 17.301 0.0000E+00 beidellite-Ca 194 -1.560 0.0000E+00 clinoenstatite-HiP 72 18.388 0.0000E+00 beidellite-H 195 -2.241 0.0000E+00 clinoenstatite 73 17.202 0.0000E+00 beidellite-K 196 -1.435 0.0000E+00 protoenstatite 74 17.860 0.0000E+00 beidellite-Mg 197 -1.707 0.0000E+00 epidote 75 24.775 0.0000E+00 beidellite-Na 198 -1.257 0.0000E+00 clinozoisite 76 22.921 0.0000E+00 calcium 199 84.043 0.0000E+00 epidote-Fe 77 29.937 0.0000E+00 chalcedony 200 -2.794 0.0000E+00 fayalite 78 14.079 0.0000E+00 dawsonite 201 1.714 0.0000E+00 ferrosilite 79 11.188 0.0000E+00 montmorillonite-Ca 202 -2.214 0.0000E+00 forsterite 80 21.047 0.0000E+00 montmorillonite-K 203 -2.161 0.0000E+00 gedrite 81 50.725 0.0000E+00 montmorillonite-Mg 204 -2.402 0.0000E+00 gehlenite 82 36.717 0.0000E+00 montmorillonite-Na 205 -1.961 0.0000E+00 gibbsite 83 4.097 0.0000E+00 nontronite-Ca 206 3.280 0.0000E+00 glaucophane 84 23.111 0.0000E+00 nontronite-H 207 2.596 0.0000E+00 glaucophane-Fe 85 17.417 0.0000E+00 nontronite-K 208 3.404 0.0000E+00 graphite 86 -3.549 0.0000E+00 nontronite-Mg 209 3.139 0.0000E+00 greenalite 87 16.194 0.0000E+00 nontronite-Na 210 3.583 0.0000E+00 grunerite 88 31.364 0.0000E+00 sepiolite 211 24.194 0.0000E+00 halite 89 1.582 0.0000E+00 alite 212 58.043 0.0000E+00 hematite 90 12.598 0.9106E-06 belite 213 30.461 0.0000E+00 heulandite 91 -5.707 0.0000E+00 ettringite 214 43.354 0.0000E+00 hercynite 92 17.345 0.0000E+00 gypsum 215 -4.924 0.0000E+00 hollandite 93 25.702 0.0000E+00 hemicarboaluminate 216 71.028 0.0000E+00 iron 94 19.095 0.0000E+00 hydrogarnet 217 60.721 0.0000E+00 jadeite 95 4.251 0.0000E+00 hydrogarnet-Si 218 50.654 0.0000E+00 julgoldite 96 70.573 0.0000E+00 jennite 219 24.386 0.0000E+00 kalsilite 97 7.620 0.0000E+00 monosulfoaluminate 220 53.497 0.0000E+00 kaolinite 98 -1.273 0.0000E+00 monocarboaluminate 221 61.966 0.0000E+00 kyanite 99 4.932 0.0000E+00 portlandite 222 18.282 0.0000E+00 larnite-bredigite 100 30.714 0.0000E+00 stratlingite 223 36.573 0.0000E+00 laumontite 101 2.975 0.0000E+00 tricarboaluminate 224 70.427 0.0000E+00 lawsonite 102 9.678 0.0000E+00 tobermorite 225 9.839 0.0000E+00 leucite 103 4.168 0.0000E+00 C4AH13 226 81.870 0.0000E+00 lime 104 26.009 0.0000E+00 C2AH8 227 45.260 0.0000E+00 lizardite 105 23.287 0.0000E+00 C3A 228 87.049 0.0000E+00 magnesite 106 0.709 0.0000E+00 C4AF 229 117.550 0.0000E+00 magnetite 107 20.133 0.0000E+00 CAH10 230 28.373 0.0000E+00 minnesotaite 108 10.461 0.0000E+00 alabandite 231 -0.962 0.0000E+00 minnesotaite-Mg 109 20.669 0.0000E+00 alunite 232 -10.224 0.0000E+00 magnesioferrite 110 26.257 0.0000E+00 artinite 233 15.139 0.0000E+00 majorite 111 53.314 0.0000E+00 boehmite 234 4.430 0.0000E+00 manganosite 112 14.068 0.0000E+00 dolomite,disordered 235 1.288 0.0000E+00 margarite 113 17.452 0.0000E+00 ferrous-oxide 236 9.824 0.0000E+00 meionite 114 45.158 0.0000E+00 huntite 237 3.850 0.0000E+00 merwinite 115 55.988 0.0000E+00 hydromagnesite 238 20.077 0.0000E+00 microcline 116 -2.432 0.0000E+00 nesquehonite 239 4.735 0.0000E+00 monticellite 117 24.371 0.0000E+00 potassium-oxide 240 69.039 0.0000E+00 mullite-Al 118 363.258 0.0000E+00 silica-amorphous 241 -2.080 0.0000E+00 mullite-Si 119 7.324 0.0000E+00 sodium-oxide 242 55.173 0.0000E+00 muscovite 120 2.679 0.0000E+00 an20ab80 243 2.079 0.0000E+00 paragonite 121 4.337 0.0000E+00 an25ab75 244 2.709 0.0000E+00 nepheline 122 8.378 0.0000E+00 an30ab70 245 3.344 0.0000E+00 osumilite(1) 123 21.978 0.0000E+00 tr.625ac.25prg.125 246 45.308 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 0.0080000 g log = -2.0969 Original solution: 1000.0103000 g Original solution / Rock added: 125001.29 (Water/Rock Ratio), log = 5.0969 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0080000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2683099E-03 Osmotic coef. = 0.9902 True ionic strength = .2715025E-03 Chg. balance for total moles = 0.1648E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.38056E-07 -7.4196 0.36570E-07 -7.4369 0.96095E+00 -0.0173 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13256E-03 -3.8776 0.96083E+00 -0.0174 4 SO4-- 0.25348E-04 -4.5961 0.22799E-04 -4.6421 0.89944E+00 -0.0460 5 HCO3- 0.12161E-04 -4.9150 0.11685E-04 -4.9324 0.96086E+00 -0.0173 6 HS- 0.46630E-08 -8.3313 0.44804E-08 -8.3487 0.96083E+00 -0.0174 7 Al+++ 0.47801E-19 -19.3206 0.38499E-19 -19.4146 0.80540E+00 -0.0940 8 H4SiO4 0.75784E-04 -4.1204 0.75784E-04 -4.1204 0.10000E+01 0.0000 9 Ca++ 0.23405E-04 -4.6307 0.21048E-04 -4.6768 0.89931E+00 -0.0461 10 Mg++ 0.12031E-05 -5.9197 0.10819E-05 -5.9658 0.89922E+00 -0.0461 11 Fe++ 0.86586E-08 -8.0626 0.77862E-08 -8.1087 0.89924E+00 -0.0461 12 K+ 0.16979E-05 -5.7701 0.16315E-05 -5.7874 0.96086E+00 -0.0173 13 Na+ 0.17010E-03 -3.7693 0.16344E-03 -3.7867 0.96083E+00 -0.0174 14 Mn++ 0.11521E-06 -6.9385 0.10360E-06 -6.9846 0.89926E+00 -0.0461 15 HPO4-- 0.84837E-08 -8.0714 0.76306E-08 -8.1174 0.89944E+00 -0.0460 16 HSiO3- 0.21043E-05 -5.6769 0.20219E-05 -5.6942 0.96083E+00 -0.0174 17 Ca(HSiO3)+ 0.99232E-09 -9.0033 0.95349E-09 -9.0207 0.96087E+00 -0.0173 18 Mg(HSiO3)+ 0.63479E-10 -10.1974 0.60995E-10 -10.2147 0.96087E+00 -0.0173 19 NaHSiO3,aq 0.52484E-08 -8.2800 0.52484E-08 -8.2800 0.10000E+01 0.0000 20 AlO+ 0.38677E-11 -11.4125 0.37164E-11 -11.4299 0.96087E+00 -0.0173 21 AlOH+2 0.75706E-15 -15.1209 0.68081E-15 -15.1670 0.89928E+00 -0.0461 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.12924E-05 -5.8886 0.12417E-05 -5.9060 0.96080E+00 -0.0174 24 CH4,aq 0.22535E-14 -14.6471 0.22533E-14 -14.6472 0.99992E+00 0.0000 29 CO,aq 0.71546E-16 -16.1454 0.71546E-16 -16.1454 0.10000E+01 0.0000 30 CO2,aq 0.86163E-06 -6.0647 0.86156E-06 -6.0647 0.99992E+00 0.0000 31 CO3-2 0.32848E-07 -7.4835 0.29544E-07 -7.5295 0.89940E+00 -0.0460 32 CaCO3,aq 0.76159E-08 -8.1183 0.76159E-08 -8.1183 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.64495E-08 -8.1905 0.61971E-08 -8.2078 0.96087E+00 -0.0173 34 CaCl+ 0.46270E-08 -8.3347 0.44460E-08 -8.3520 0.96087E+00 -0.0173 35 CaCl2,aq 0.13722E-12 -12.8626 0.13722E-12 -12.8626 0.10000E+01 0.0000 36 CaOH+ 0.42237E-07 -7.3743 0.40584E-07 -7.3916 0.96087E+00 -0.0173 37 CaSO4,aq 0.14951E-06 -6.8253 0.14951E-06 -6.8253 0.10000E+01 0.0000 38 HCl,aq 0.91182E-12 -12.0401 0.91182E-12 -12.0401 0.10000E+01 0.0000 43 FeCl+ 0.16730E-11 -11.7765 0.16076E-11 -11.7938 0.96087E+00 -0.0173 46 FeO,aq 0.23023E-09 -9.6378 0.23023E-09 -9.6378 0.10000E+01 0.0000 47 FeOH+ 0.73461E-08 -8.1339 0.70587E-08 -8.1513 0.96087E+00 -0.0173 48 HFeO2- 0.70478E-10 -10.1519 0.67718E-10 -10.1693 0.96083E+00 -0.0174 49 FeO+ 0.31483E-12 -12.5019 0.30251E-12 -12.5193 0.96087E+00 -0.0173 50 FeOH+2 0.22891E-17 -17.6403 0.20585E-17 -17.6864 0.89928E+00 -0.0461 51 FeO2- 0.46270E-10 -10.3347 0.44458E-10 -10.3520 0.96083E+00 -0.0174 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.32246E-08 -8.4915 0.32243E-08 -8.4916 0.99992E+00 0.0000 54 KCl,aq 0.38293E-11 -11.4169 0.38293E-11 -11.4169 0.10000E+01 0.0000 55 KHSO4,aq 0.36399E-17 -17.4389 0.36399E-17 -17.4389 0.10000E+01 0.0000 56 KOH,aq 0.19449E-10 -10.7111 0.19449E-10 -10.7111 0.10000E+01 0.0000 57 KSO4- 0.59640E-09 -9.2245 0.57304E-09 -9.2418 0.96083E+00 -0.0174 58 MgCO3,aq 0.97820E-10 -10.0096 0.97820E-10 -10.0096 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.33805E-09 -9.4710 0.32483E-09 -9.4883 0.96087E+00 -0.0173 60 MgCl+ 0.21591E-09 -9.6657 0.20746E-09 -9.6831 0.96087E+00 -0.0173 61 MgOH+ 0.12028E-07 -7.9198 0.11557E-07 -7.9372 0.96087E+00 -0.0173 63 MnO,aq 0.81777E-10 -10.0874 0.81777E-10 -10.0874 0.10000E+01 0.0000 64 MnOH+ 0.90801E-08 -8.0419 0.87247E-08 -8.0592 0.96087E+00 -0.0173 65 MnO2-2 0.23513E-17 -17.6287 0.21148E-17 -17.6747 0.89940E+00 -0.0460 66 HMnO2- 0.17439E-13 -13.7585 0.16756E-13 -13.7758 0.96083E+00 -0.0174 69 MnCl+ 0.86500E-10 -10.0630 0.83115E-10 -10.0803 0.96087E+00 -0.0173 70 MnSO4,aq 0.66937E-09 -9.1743 0.66937E-09 -9.1743 0.10000E+01 0.0000 71 NaCl,aq 0.70741E-08 -8.1503 0.70741E-08 -8.1503 0.10000E+01 0.0000 72 NaOH,aq 0.19638E-08 -8.7069 0.19638E-08 -8.7069 0.10000E+01 0.0000 74 OH- 0.17072E-04 -4.7677 0.16403E-04 -4.7851 0.96080E+00 -0.0174 79 HPO3-2 0.86403E-19 -19.0635 0.77710E-19 -19.1095 0.89940E+00 -0.0460 82 H3PO4,aq 0.65697E-13 -13.1825 0.65697E-13 -13.1825 0.10000E+01 0.0000 83 H2PO4- 0.50916E-08 -8.2931 0.48922E-08 -8.3105 0.96085E+00 -0.0173 84 PO4-3 0.22603E-12 -12.6458 0.18222E-12 -12.7394 0.80620E+00 -0.0936 87 H2P2O7-2 0.20827E-17 -17.6814 0.18732E-17 -17.7274 0.89940E+00 -0.0460 88 HP2O7-3 0.13041E-16 -16.8847 0.10503E-16 -16.9787 0.80541E+00 -0.0940 89 P2O7-4 0.10261E-18 -18.9888 0.70856E-19 -19.1496 0.69051E+00 -0.1608 90 H2S,aq 0.49233E-09 -9.3077 0.49229E-09 -9.3078 0.99992E+00 0.0000 91 S2-2 0.15225E-18 -18.8175 0.13693E-18 -18.8635 0.89940E+00 -0.0460 96 SO2,aq 0.41188E-18 -18.3852 0.41188E-18 -18.3852 0.10000E+01 0.0000 97 SO3-2 0.11141E-13 -13.9531 0.10023E-13 -13.9990 0.89966E+00 -0.0459 98 HSO3- 0.22325E-13 -13.6512 0.21450E-13 -13.6686 0.96083E+00 -0.0174 99 HSO4- 0.80508E-09 -9.0942 0.77359E-09 -9.1115 0.96089E+00 -0.0173 101 S2O3-2 0.14707E-15 -15.8325 0.13228E-15 -15.8785 0.89940E+00 -0.0460 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3805572E-07 -.2362226E-04 -.2380938E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999794E+06 0.0000 3 Cl- 0.1379626E-03 0.1379746E-03 0.4891522E+01 3.5593 4 SO4-- 0.2534781E-04 0.2549862E-04 0.2449392E+01 10.2317 5 HCO3- 0.1216106E-04 0.1307004E-04 0.7974824E+00 2.5045 6 HS- 0.4663033E-08 0.5930258E-08 0.1961218E-03 -0.9118 7 Al+++ 0.4780077E-19 0.1312703E-05 0.3541803E-01 2.8961 8 H4SiO4 0.7578389E-04 0.7789451E-04 0.7486722E+01 -4.1204 9 Ca++ 0.2340456E-04 0.2361600E-04 0.9464643E+00 10.1970 10 Mg++ 0.1203141E-05 0.1215884E-05 0.2956002E-01 8.9079 11 Fe++ 0.8658632E-08 0.1655721E-07 0.9246530E-03 6.7651 12 K+ 0.1697899E-05 0.1698519E-05 0.6641425E-01 1.6495 13 Na+ 0.1700992E-03 0.1701135E-03 0.3910802E+01 3.6502 14 Mn++ 0.1152051E-06 0.1251229E-06 0.6873872E-02 7.8891 15 HPO4-- 0.8483688E-08 0.1357557E-07 0.1302945E-02 6.7563 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1194281E-03 -.2362219E-04 -.9580593E-04 0.0000000E+00 2 H2O 0.5550815E+02 0.5550809E+02 0.5498415E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2572618E-04 0.2549854E-04 0.2276375E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2217073E-06 0.5930240E-08 -.2276375E-06 0.0000000E+00 7 Al+++ 0.2608593E-04 0.1312699E-05 0.2477323E-04 0.0000000E+00 8 H4SiO4 0.8330226E-04 0.7789427E-04 0.5407994E-05 0.0000000E+00 9 Ca++ 0.2367220E-04 0.2361593E-04 0.5627515E-07 0.0000000E+00 10 Mg++ 0.6349206E-05 0.1215880E-05 0.5133326E-05 0.0000000E+00 11 Fe++ 0.5704069E-05 0.1655715E-07 0.5687512E-05 0.0000000E+00 12 K+ 0.1698514E-05 0.1698514E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1701129E-03 0.1701129E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1387088E-06 0.1251225E-06 0.1358629E-07 0.0000000E+00 15 HPO4-- 0.4734061E-07 0.1357552E-07 0.3376509E-07 0.0000000E+00 Chg. balance for solid moles: -.3706E-21 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0080000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1126E-07 -7.949 0.5654E-05 -5.248 0.2221 0.1797E-05 clinochlore 0.1027E-05 -5.989 0.5707E-03 -3.244 22.42 0.2171E-03 daphnite 0.7733E-06 -6.112 0.5517E-03 -3.258 21.68 0.1672E-03 chlorite-Mn 0.2717E-08 -8.566 0.1926E-05 -5.715 0.7569E-01 0.6139E-06 diaspore 0.2117E-04 -4.674 0.1270E-02 -2.896 49.89 0.3780E-03 hematite 0.9106E-06 -6.041 0.1454E-03 -3.837 5.713 0.2756E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5695E+00 0.5695E+00 1.0000 -0.244 daphnite 0.4290E+00 0.4290E+00 1.0000 -0.368 chlorite-Mn 0.1507E-02 0.1507E-02 1.0000 -2.822 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.002545 g Volume = 0.000792 cm3 Porosity: 99.9210% V(tot) - V(min): 0.10024E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0080000 g log = -2.0969 Original solution: 1000.0103000 g Original solution / Rock added: 125001.29 (Water/Rock Ratio), log = 5.0969 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.9306E-04 1.0073 0.9862E-04 0.9790E-04 CH4,gas 0.3344E-11 1.0129 0.3563E-11 0.3518E-11 H2,gas 0.4201E-05 1.0006 0.4422E-05 0.4420E-05 H2S,gas 0.1370E-07 0.9959 0.1436E-07 0.1442E-07 S2,gas 0.3753E-24 1.0000 0.3948E-24 0.3948E-24 CO,gas 0.1074E-12 1.0000 0.1130E-12 0.1130E-12 SO3,gas 0.1083E-34 1.0000 0.1140E-34 0.1140E-34 SO2,gas 0.1813E-17 1.0000 0.1907E-17 0.1907E-17 HCl,gas 0.1530E-14 1.0000 0.1610E-14 0.1610E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.37 -6.01 -2.002 0.10255E+05 -4.006 3 CH4,gas 4.81 -8.64 -13.45 -3.362 0.22962E+05 -11.448 4 H2,gas 8.29 0.93 -7.35 -4.202 0.12557E+05 -5.354 5 H2S,gas -5.94 -15.79 -9.84 -4.921 0.16807E+05 -7.843 6 S2,gas -7.03 -33.44 -26.40 -4.062 0.45083E+05 -24.404 7 CO,gas 3.51 -11.44 -14.95 -4.599 0.25522E+05 -12.947 8 SO3,gas 17.43 -19.52 -36.94 -9.236 0.63079E+05 -34.943 9 SO2,gas 1.14 -18.58 -19.72 -5.259 0.33671E+05 -17.720 10 HCl,gas 5.48 -11.31 -16.79 -8.397 0.28674E+05 -14.793 21 andalusite 5.06 1.67 -3.39 -0.339 0.57894E+04 24 anhydrite -5.28 -9.32 -4.04 -2.020 0.68967E+04 35 aragonite 0.99 -2.17 -3.16 -1.053 0.53931E+04 36 brucite 12.58 8.91 -3.67 -0.734 0.62641E+04 37 calcite 0.83 -2.17 -3.01 -1.002 0.51317E+04 40 carpholite-Mg 8.65 6.46 -2.19 -0.146 0.37412E+04 41 carpholite-Fe 6.78 4.32 -2.47 -0.164 0.42114E+04 50 chloritoid-Mg 13.26 10.58 -2.68 -0.179 0.45787E+04 51 chloritoid-Fe 9.24 8.44 -0.80 -0.053 0.13691E+04 52 chloritoid-Mn 11.46 9.56 -1.90 -0.127 0.32482E+04 54 coesite -2.37 -4.12 -1.75 -0.584 0.29899E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.12 -1.57 -0.524 0.26828E+04 75 epidote 24.78 20.12 -4.65 -0.226 0.79424E+04 78 fayalite 14.08 9.41 -4.67 -0.667 0.79725E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.05 -4.14 -0.345 0.70686E+04 92 hercynite 17.34 12.56 -4.79 -0.319 0.81741E+04 98 kaolinite -1.27 -2.45 -1.18 -0.107 0.20072E+04 99 kyanite 4.93 1.67 -3.26 -0.326 0.55662E+04 101 laumontite 2.97 -0.49 -3.47 -0.231 0.59200E+04 102 lawsonite 9.68 7.75 -1.93 -0.129 0.32955E+04 105 lizardite 23.29 18.48 -4.80 -0.400 0.82034E+04 106 magnesite 0.71 -3.46 -4.17 -1.390 0.71212E+04 107 magnetite 20.13 19.36 -0.77 -0.063 0.13149E+04 110 magnesioferrite 26.26 21.51 -4.75 -0.388 0.81134E+04 113 margarite 17.45 13.54 -3.91 -0.156 0.66785E+04 120 muscovite 2.68 -2.02 -4.70 -0.277 0.80298E+04 121 paragonite 4.34 -0.02 -4.36 -0.256 0.74436E+04 128 periclase-Fe 11.64 6.77 -4.87 -1.219 0.83223E+04 142 pyrite -21.23 -25.74 -4.51 -1.062 0.77063E+04 143 pyrrhotite -4.24 -9.02 -4.78 -1.592 0.81564E+04 144 pyrrhotiteFe0.875 -6.00 -9.98 -3.98 -1.464 0.67970E+04 145 pyroxmangite 7.42 3.77 -3.65 -0.729 0.62277E+04 146 pyrophyllite -6.10 -10.69 -4.59 -0.287 0.78398E+04 147 quartz -2.98 -4.12 -1.14 -0.379 0.19438E+04 152 rhodochrosite -0.96 -4.48 -3.52 -1.174 0.60130E+04 153 rhodonite 7.46 3.77 -3.69 -0.739 0.63070E+04 156 siderite -2.59 -5.60 -3.02 -1.005 0.51506E+04 157 sillimanite 5.32 1.67 -3.65 -0.365 0.62316E+04 169 sudoite 21.22 17.04 -4.18 -0.135 0.71325E+04 178 topaz-H 4.67 1.67 -3.00 -0.272 0.51153E+04 179 tridymite -2.61 -4.12 -1.51 -0.502 0.25711E+04 182 troilite-low -4.39 -9.02 -4.63 -1.542 0.78996E+04 188 wairakite 4.06 -0.49 -4.55 -0.268 0.77708E+04 190 wollastonite 10.48 6.08 -4.41 -0.881 0.75219E+04 191 pseudo-wollastonite 11.02 6.08 -4.94 -0.989 0.84405E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.12 -1.33 -0.442 0.22641E+04 202 montmorillonite-Ca -2.21 -7.02 -4.81 -0.297 0.82114E+04 204 montmorillonite-Mg -2.40 -7.24 -4.83 -0.299 0.82542E+04 206 nontronite-Ca 3.28 0.11 -3.17 -0.205 0.54055E+04 207 nontronite-H 2.60 -1.57 -4.16 -0.279 0.71105E+04 208 nontronite-K 3.40 -1.02 -4.43 -0.284 0.75609E+04 209 nontronite-Mg 3.14 -0.10 -3.24 -0.210 0.55289E+04 210 nontronite-Na 3.58 -0.36 -3.95 -0.253 0.67392E+04 215 gypsum -4.92 -9.32 -4.39 -1.099 0.75035E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.77 -3.06 -0.765 0.52234E+04 241 silica-amorphous -2.08 -4.12 -2.04 -0.680 0.34843E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0080000 g New total amount of reactant added: 0.0084000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1648E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0084000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2695527E-03 Osmotic coef. = 0.9902 True ionic strength = .2730362E-03 Chg. balance for total moles = 0.1648E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.36155E-07 -7.4418 0.34741E-07 -7.4592 0.96089E+00 -0.0173 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13255E-03 -3.8776 0.96077E+00 -0.0174 4 SO4-- 0.25347E-04 -4.5961 0.22792E-04 -4.6422 0.89922E+00 -0.0461 5 HCO3- 0.12199E-04 -4.9137 0.11721E-04 -4.9310 0.96080E+00 -0.0174 6 HS- 0.30830E-08 -8.5110 0.29621E-08 -8.5284 0.96078E+00 -0.0174 7 Al+++ 0.41005E-19 -19.3872 0.33008E-19 -19.4814 0.80496E+00 -0.0942 8 H4SiO4 0.79333E-04 -4.1005 0.79333E-04 -4.1005 0.10000E+01 0.0000 9 Ca++ 0.23851E-04 -4.6225 0.21444E-04 -4.6687 0.89909E+00 -0.0462 10 Mg++ 0.10703E-05 -5.9705 0.96218E-06 -6.0167 0.89900E+00 -0.0462 11 Fe++ 0.74703E-08 -8.1267 0.67159E-08 -8.1729 0.89902E+00 -0.0462 12 K+ 0.17828E-05 -5.7489 0.17129E-05 -5.7663 0.96081E+00 -0.0174 13 Na+ 0.17060E-03 -3.7680 0.16391E-03 -3.7854 0.96077E+00 -0.0174 14 Mn++ 0.11798E-06 -6.9282 0.10607E-06 -6.9744 0.89904E+00 -0.0462 15 HPO4-- 0.76820E-08 -8.1145 0.69078E-08 -8.1607 0.89922E+00 -0.0461 16 HSiO3- 0.23190E-05 -5.6347 0.22280E-05 -5.6521 0.96077E+00 -0.0174 17 Ca(HSiO3)+ 0.11141E-08 -8.9531 0.10705E-08 -8.9704 0.96081E+00 -0.0174 18 Mg(HSiO3)+ 0.62213E-10 -10.2061 0.59775E-10 -10.2235 0.96081E+00 -0.0174 19 NaHSiO3,aq 0.58000E-08 -8.2366 0.58000E-08 -8.2366 0.10000E+01 0.0000 20 AlO+ 0.36746E-11 -11.4348 0.35306E-11 -11.4522 0.96081E+00 -0.0174 21 AlOH+2 0.68341E-15 -15.1653 0.61443E-15 -15.2115 0.89906E+00 -0.0462 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.13605E-05 -5.8663 0.13071E-05 -5.8837 0.96074E+00 -0.0174 24 CH4,aq 0.14948E-14 -14.8254 0.14947E-14 -14.8254 0.99992E+00 0.0000 29 CO,aq 0.62275E-16 -16.2057 0.62275E-16 -16.2057 0.10000E+01 0.0000 30 CO2,aq 0.82106E-06 -6.0856 0.82099E-06 -6.0857 0.99992E+00 0.0000 31 CO3-2 0.34692E-07 -7.4598 0.31194E-07 -7.5059 0.89918E+00 -0.0462 32 CaCO3,aq 0.81929E-08 -8.0866 0.81929E-08 -8.0866 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.65916E-08 -8.1810 0.63333E-08 -8.1984 0.96081E+00 -0.0174 34 CaCl+ 0.47142E-08 -8.3266 0.45295E-08 -8.3440 0.96081E+00 -0.0174 35 CaCl2,aq 0.13979E-12 -12.8545 0.13979E-12 -12.8545 0.10000E+01 0.0000 36 CaOH+ 0.45301E-07 -7.3439 0.43525E-07 -7.3613 0.96081E+00 -0.0174 37 CaSO4,aq 0.15229E-06 -6.8173 0.15229E-06 -6.8173 0.10000E+01 0.0000 38 HCl,aq 0.86618E-12 -12.0624 0.86618E-12 -12.0624 0.10000E+01 0.0000 43 FeCl+ 0.14431E-11 -11.8407 0.13865E-11 -11.8581 0.96081E+00 -0.0174 46 FeO,aq 0.22004E-09 -9.6575 0.22004E-09 -9.6575 0.10000E+01 0.0000 47 FeOH+ 0.66703E-08 -8.1759 0.64089E-08 -8.1932 0.96081E+00 -0.0174 48 HFeO2- 0.70908E-10 -10.1493 0.68126E-10 -10.1667 0.96077E+00 -0.0174 49 FeO+ 0.29910E-12 -12.5242 0.28738E-12 -12.5415 0.96081E+00 -0.0174 50 FeOH+2 0.20664E-17 -17.6848 0.18578E-17 -17.7310 0.89906E+00 -0.0462 51 FeO2- 0.48709E-10 -10.3124 0.46798E-10 -10.3298 0.96077E+00 -0.0174 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.29454E-08 -8.5309 0.29451E-08 -8.5309 0.99992E+00 0.0000 54 KCl,aq 0.40202E-11 -11.3957 0.40202E-11 -11.3957 0.10000E+01 0.0000 55 KHSO4,aq 0.36295E-17 -17.4402 0.36295E-17 -17.4402 0.10000E+01 0.0000 56 KOH,aq 0.21495E-10 -10.6677 0.21495E-10 -10.6677 0.10000E+01 0.0000 57 KSO4- 0.62604E-09 -9.2034 0.60149E-09 -9.2208 0.96077E+00 -0.0174 58 MgCO3,aq 0.91856E-10 -10.0369 0.91856E-10 -10.0369 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.30159E-09 -9.5206 0.28977E-09 -9.5379 0.96081E+00 -0.0174 60 MgCl+ 0.19202E-09 -9.7167 0.18450E-09 -9.7340 0.96081E+00 -0.0174 61 MgOH+ 0.11260E-07 -7.9484 0.10819E-07 -7.9658 0.96081E+00 -0.0174 63 MnO,aq 0.92770E-10 -10.0326 0.92770E-10 -10.0326 0.10000E+01 0.0000 64 MnOH+ 0.97861E-08 -8.0094 0.94026E-08 -8.0268 0.96081E+00 -0.0174 65 MnO2-2 0.29563E-17 -17.5293 0.26582E-17 -17.5754 0.89918E+00 -0.0462 66 HMnO2- 0.20825E-13 -13.6814 0.20009E-13 -13.6988 0.96077E+00 -0.0174 69 MnCl+ 0.88560E-10 -10.0528 0.85089E-10 -10.0701 0.96081E+00 -0.0174 70 MnSO4,aq 0.68512E-09 -9.1642 0.68512E-09 -9.1642 0.10000E+01 0.0000 71 NaCl,aq 0.70941E-08 -8.1491 0.70941E-08 -8.1491 0.10000E+01 0.0000 72 NaOH,aq 0.20731E-08 -8.6834 0.20731E-08 -8.6834 0.10000E+01 0.0000 74 OH- 0.17971E-04 -4.7454 0.17266E-04 -4.7628 0.96074E+00 -0.0174 79 HPO3-2 0.71464E-19 -19.1459 0.64259E-19 -19.1921 0.89918E+00 -0.0462 82 H3PO4,aq 0.53675E-13 -13.2702 0.53675E-13 -13.2702 0.10000E+01 0.0000 83 H2PO4- 0.43791E-08 -8.3586 0.42074E-08 -8.3760 0.96079E+00 -0.0174 84 PO4-3 0.21551E-12 -12.6665 0.17365E-12 -12.7603 0.80576E+00 -0.0938 87 H2P2O7-2 0.15408E-17 -17.8122 0.13855E-17 -17.8584 0.89918E+00 -0.0462 88 HP2O7-3 0.10159E-16 -16.9932 0.81776E-17 -17.0874 0.80497E+00 -0.0942 89 P2O7-4 0.84177E-19 -19.0748 0.58069E-19 -19.2361 0.68985E+00 -0.1612 90 H2S,aq 0.30921E-09 -9.5097 0.30919E-09 -9.5098 0.99992E+00 0.0000 91 S2-2 0.72868E-19 -19.1375 0.65521E-19 -19.1836 0.89918E+00 -0.0462 96 SO2,aq 0.33944E-18 -18.4692 0.33944E-18 -18.4692 0.10000E+01 0.0000 97 SO3-2 0.10176E-13 -13.9924 0.91526E-14 -14.0385 0.89944E+00 -0.0460 98 HSO3- 0.19368E-13 -13.7129 0.18608E-13 -13.7303 0.96077E+00 -0.0174 99 HSO4- 0.76466E-09 -9.1165 0.73471E-09 -9.1339 0.96083E+00 -0.0174 101 S2O3-2 0.92366E-16 -16.0345 0.83054E-16 -16.0806 0.89918E+00 -0.0462 Charge balance for all species = 0.1648E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3615506E-07 -.2505783E-04 -.2525631E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999790E+06 0.0000 3 Cl- 0.1379625E-03 0.1379746E-03 0.4891521E+01 3.5815 4 SO4-- 0.2534680E-04 0.2550046E-04 0.2449568E+01 10.2761 5 HCO3- 0.1219911E-04 0.1307004E-04 0.7974822E+00 2.5281 6 HS- 0.3082999E-08 0.4097006E-08 0.1354936E-03 -1.0692 7 Al+++ 0.4100544E-19 0.1380807E-05 0.3725552E-01 2.8961 8 H4SiO4 0.7933312E-04 0.8165906E-04 0.7848543E+01 -4.1005 9 Ca++ 0.2385139E-04 0.2406959E-04 0.9646427E+00 10.2496 10 Mg++ 0.1070268E-05 0.1082176E-05 0.2630937E-01 8.9016 11 Fe++ 0.7470262E-08 0.1468540E-07 0.8201197E-03 6.7454 12 K+ 0.1782794E-05 0.1783445E-05 0.6973495E-01 1.6929 13 Na+ 0.1706006E-03 0.1706156E-03 0.3922344E+01 3.6738 14 Mn++ 0.1179769E-06 0.1286295E-06 0.7066513E-02 7.9439 15 HPO4-- 0.7682007E-08 0.1206140E-07 0.1157619E-02 6.7577 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1260515E-03 -.2505775E-04 -.1009938E-03 0.0000000E+00 2 H2O 0.5550814E+02 0.5550809E+02 0.5779891E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2573726E-04 0.2550037E-04 0.2368896E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2327926E-06 0.4096993E-08 -.2368896E-06 0.0000000E+00 7 Al+++ 0.2739023E-04 0.1380802E-05 0.2600943E-04 0.0000000E+00 8 H4SiO4 0.8746738E-04 0.8165879E-04 0.5808587E-05 0.0000000E+00 9 Ca++ 0.2413226E-04 0.2406951E-04 0.6274381E-07 0.0000000E+00 10 Mg++ 0.6666667E-05 0.1082173E-05 0.5584494E-05 0.0000000E+00 11 Fe++ 0.5989272E-05 0.1468535E-07 0.5974587E-05 0.0000000E+00 12 K+ 0.1783439E-05 0.1783439E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1706150E-03 0.1706150E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1456442E-06 0.1286291E-06 0.1701512E-07 0.0000000E+00 15 HPO4-- 0.4970764E-07 0.1206136E-07 0.3764628E-07 0.0000000E+00 Chg. balance for solid moles: -.6247E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0084000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1255E-07 -7.901 0.6303E-05 -5.200 0.2342 0.2003E-05 clinochlore 0.1117E-05 -5.952 0.6208E-03 -3.207 23.07 0.2361E-03 daphnite 0.8159E-06 -6.088 0.5821E-03 -3.235 21.63 0.1764E-03 chlorite-Mn 0.3403E-08 -8.468 0.2413E-05 -5.618 0.8966E-01 0.7688E-06 diaspore 0.2214E-04 -4.655 0.1328E-02 -2.877 49.35 0.3954E-03 hematite 0.9476E-06 -6.023 0.1513E-03 -3.820 5.623 0.2868E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5769E+00 0.5769E+00 1.0000 -0.239 daphnite 0.4214E+00 0.4214E+00 1.0000 -0.375 chlorite-Mn 0.1758E-02 0.1758E-02 1.0000 -2.755 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.002691 g Volume = 0.000839 cm3 Porosity: 99.9163% V(tot) - V(min): 0.10025E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0084000 g log = -2.0757 Original solution: 1000.0103000 g Original solution / Rock added: 119048.85 (Water/Rock Ratio), log = 5.0757 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.8868E-04 1.0073 0.9398E-04 0.9329E-04 CH4,gas 0.2218E-11 1.0129 0.2364E-11 0.2334E-11 H2,gas 0.3838E-05 1.0006 0.4039E-05 0.4037E-05 H2S,gas 0.8607E-08 0.9959 0.9018E-08 0.9055E-08 S2,gas 0.1774E-24 1.0000 0.1867E-24 0.1867E-24 CO,gas 0.9347E-13 1.0000 0.9833E-13 0.9833E-13 SO3,gas 0.9776E-35 1.0000 0.1028E-34 0.1028E-34 SO2,gas 0.1494E-17 1.0000 0.1572E-17 0.1572E-17 HCl,gas 0.1454E-14 1.0000 0.1529E-14 0.1529E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.39 -6.03 -2.009 0.10291E+05 -4.027 3 CH4,gas 4.81 -8.82 -13.63 -3.407 0.23267E+05 -11.626 4 H2,gas 8.29 0.89 -7.39 -4.225 0.12624E+05 -5.394 5 H2S,gas -5.94 -15.99 -10.04 -5.022 0.17151E+05 -8.045 6 S2,gas -7.03 -33.76 -26.73 -4.112 0.45639E+05 -24.729 7 CO,gas 3.51 -11.50 -15.01 -4.618 0.25625E+05 -13.007 8 SO3,gas 17.43 -19.56 -36.99 -9.247 0.63156E+05 -34.988 9 SO2,gas 1.14 -18.67 -19.80 -5.281 0.33814E+05 -17.804 10 HCl,gas 5.48 -11.34 -16.82 -8.408 0.28712E+05 -14.815 21 andalusite 5.06 1.69 -3.37 -0.337 0.57554E+04 24 anhydrite -5.28 -9.31 -4.03 -2.016 0.68831E+04 29 anorthite 12.80 7.84 -4.96 -0.381 0.84639E+04 35 aragonite 0.99 -2.14 -3.13 -1.042 0.53389E+04 36 brucite 12.58 8.90 -3.68 -0.735 0.62750E+04 37 calcite 0.83 -2.14 -2.97 -0.991 0.50776E+04 40 carpholite-Mg 8.65 6.49 -2.16 -0.144 0.36842E+04 41 carpholite-Fe 6.78 4.34 -2.45 -0.163 0.41771E+04 50 chloritoid-Mg 13.26 10.59 -2.67 -0.178 0.45556E+04 51 chloritoid-Fe 9.24 8.44 -0.80 -0.053 0.13687E+04 52 chloritoid-Mn 11.46 9.64 -1.83 -0.122 0.31207E+04 54 coesite -2.37 -4.10 -1.73 -0.577 0.29560E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.10 -1.55 -0.517 0.26489E+04 75 epidote 24.78 20.29 -4.49 -0.218 0.76607E+04 78 fayalite 14.08 9.39 -4.69 -0.670 0.80058E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.04 -4.16 -0.347 0.71014E+04 92 hercynite 17.34 12.54 -4.81 -0.320 0.82077E+04 98 kaolinite -1.27 -2.41 -1.14 -0.103 0.19393E+04 99 kyanite 4.93 1.69 -3.24 -0.324 0.55322E+04 101 laumontite 2.97 -0.36 -3.33 -0.222 0.56943E+04 102 lawsonite 9.68 7.84 -1.84 -0.123 0.31377E+04 105 lizardite 23.29 18.50 -4.78 -0.399 0.81682E+04 106 magnesite 0.71 -3.49 -4.20 -1.399 0.71678E+04 107 magnetite 20.13 19.34 -0.79 -0.064 0.13485E+04 110 magnesioferrite 26.26 21.50 -4.76 -0.388 0.81243E+04 113 margarite 17.45 13.63 -3.82 -0.153 0.65207E+04 120 muscovite 2.68 -1.92 -4.60 -0.271 0.78538E+04 121 paragonite 4.34 0.06 -4.28 -0.252 0.73016E+04 128 periclase-Fe 11.64 6.75 -4.89 -1.223 0.83559E+04 142 pyrite -21.23 -26.12 -4.90 -1.152 0.83625E+04 143 pyrrhotite -4.24 -9.24 -5.00 -1.666 0.85349E+04 144 pyrrhotiteFe0.875 -6.00 -10.20 -4.20 -1.543 0.71630E+04 145 pyroxmangite 7.42 3.84 -3.57 -0.715 0.61003E+04 146 pyrophyllite -6.10 -10.61 -4.51 -0.282 0.77041E+04 147 quartz -2.98 -4.10 -1.12 -0.373 0.19099E+04 152 rhodochrosite -0.96 -4.45 -3.49 -1.163 0.59553E+04 153 rhodonite 7.46 3.84 -3.62 -0.724 0.61795E+04 156 siderite -2.59 -5.64 -3.06 -1.019 0.52199E+04 157 sillimanite 5.32 1.69 -3.63 -0.363 0.61976E+04 169 sudoite 21.22 17.09 -4.13 -0.133 0.70524E+04 178 topaz-H 4.67 1.69 -2.98 -0.271 0.50813E+04 179 tridymite -2.61 -4.10 -1.49 -0.495 0.25372E+04 182 troilite-low -4.39 -9.24 -4.85 -1.616 0.82781E+04 188 wairakite 4.06 -0.36 -4.42 -0.260 0.75451E+04 190 wollastonite 10.48 6.15 -4.33 -0.867 0.73980E+04 191 pseudo-wollastonite 11.02 6.15 -4.87 -0.974 0.83166E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 200 chalcedony -2.79 -4.10 -1.31 -0.435 0.22302E+04 202 montmorillonite-Ca -2.21 -6.94 -4.72 -0.292 0.80644E+04 204 montmorillonite-Mg -2.40 -7.16 -4.76 -0.294 0.81238E+04 206 nontronite-Ca 3.28 0.20 -3.08 -0.200 0.52661E+04 207 nontronite-H 2.60 -1.50 -4.09 -0.274 0.69860E+04 208 nontronite-K 3.40 -0.94 -4.34 -0.279 0.74119E+04 209 nontronite-Mg 3.14 -0.03 -3.17 -0.205 0.54061E+04 210 nontronite-Na 3.58 -0.28 -3.87 -0.248 0.66013E+04 215 gypsum -4.92 -9.31 -4.39 -1.097 0.74898E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.75 -3.08 -0.770 0.52570E+04 241 silica-amorphous -2.08 -4.10 -2.02 -0.674 0.34504E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0084000 g New total amount of reactant added: 0.0088000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1648E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0088000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2708347E-03 Osmotic coef. = 0.9901 True ionic strength = .2746180E-03 Chg. balance for total moles = 0.1648E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.34397E-07 -7.4635 0.33050E-07 -7.4808 0.96083E+00 -0.0174 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13254E-03 -3.8776 0.96071E+00 -0.0174 4 SO4-- 0.25345E-04 -4.5961 0.22785E-04 -4.6423 0.89899E+00 -0.0462 5 HCO3- 0.12234E-04 -4.9124 0.11754E-04 -4.9298 0.96074E+00 -0.0174 6 HS- 0.21070E-08 -8.6763 0.20242E-08 -8.6937 0.96072E+00 -0.0174 7 Al+++ 0.35325E-19 -19.4519 0.28419E-19 -19.5464 0.80451E+00 -0.0945 8 H4SiO4 0.82882E-04 -4.0815 0.82882E-04 -4.0815 0.10000E+01 0.0000 9 Ca++ 0.24298E-04 -4.6144 0.21841E-04 -4.6607 0.89886E+00 -0.0463 10 Mg++ 0.95361E-06 -6.0206 0.85708E-06 -6.0670 0.89878E+00 -0.0463 11 Fe++ 0.64888E-08 -8.1878 0.58321E-08 -8.2342 0.89880E+00 -0.0463 12 K+ 0.18677E-05 -5.7287 0.17944E-05 -5.7461 0.96075E+00 -0.0174 13 Na+ 0.17110E-03 -3.7667 0.16438E-03 -3.7842 0.96071E+00 -0.0174 14 Mn++ 0.12023E-06 -6.9200 0.10806E-06 -6.9663 0.89881E+00 -0.0463 15 HPO4-- 0.69732E-08 -8.1566 0.62689E-08 -8.2028 0.89900E+00 -0.0462 16 HSiO3- 0.25468E-05 -5.5940 0.24467E-05 -5.6114 0.96071E+00 -0.0174 17 Ca(HSiO3)+ 0.12462E-08 -8.9044 0.11973E-08 -8.9218 0.96075E+00 -0.0174 18 Mg(HSiO3)+ 0.60863E-10 -10.2156 0.58474E-10 -10.2330 0.96075E+00 -0.0174 19 NaHSiO3,aq 0.63878E-08 -8.1946 0.63878E-08 -8.1946 0.10000E+01 0.0000 20 AlO+ 0.34959E-11 -11.4564 0.33587E-11 -11.4738 0.96075E+00 -0.0174 21 AlOH+2 0.61866E-15 -15.2085 0.55607E-15 -15.2549 0.89883E+00 -0.0463 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.14302E-05 -5.8446 0.13739E-05 -5.8620 0.96068E+00 -0.0174 24 CH4,aq 0.10247E-14 -14.9894 0.10246E-14 -14.9894 0.99992E+00 0.0000 29 CO,aq 0.54699E-16 -16.2620 0.54699E-16 -16.2620 0.10000E+01 0.0000 30 CO2,aq 0.78330E-06 -6.1061 0.78323E-06 -6.1061 0.99992E+00 0.0000 31 CO3-2 0.36578E-07 -7.4368 0.32882E-07 -7.4830 0.89895E+00 -0.0463 32 CaCO3,aq 0.87960E-08 -8.0557 0.87960E-08 -8.0557 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.67328E-08 -8.1718 0.64685E-08 -8.1892 0.96075E+00 -0.0174 34 CaCl+ 0.48014E-08 -8.3186 0.46129E-08 -8.3360 0.96075E+00 -0.0174 35 CaCl2,aq 0.14236E-12 -12.8466 0.14236E-12 -12.8466 0.10000E+01 0.0000 36 CaOH+ 0.48502E-07 -7.3142 0.46598E-07 -7.3316 0.96075E+00 -0.0174 37 CaSO4,aq 0.15506E-06 -6.8095 0.15506E-06 -6.8095 0.10000E+01 0.0000 38 HCl,aq 0.82397E-12 -12.0841 0.82397E-12 -12.0841 0.10000E+01 0.0000 43 FeCl+ 0.12531E-11 -11.9020 0.12040E-11 -11.9194 0.96075E+00 -0.0174 46 FeO,aq 0.21114E-09 -9.6754 0.21114E-09 -9.6754 0.10000E+01 0.0000 47 FeOH+ 0.60892E-08 -8.2154 0.58502E-08 -8.2328 0.96075E+00 -0.0174 48 HFeO2- 0.71523E-10 -10.1456 0.68713E-10 -10.1630 0.96071E+00 -0.0174 49 FeO+ 0.28456E-12 -12.5458 0.27340E-12 -12.5632 0.96075E+00 -0.0174 50 FeOH+2 0.18706E-17 -17.7280 0.16814E-17 -17.7743 0.89883E+00 -0.0463 51 FeO2- 0.51204E-10 -10.2907 0.49192E-10 -10.3081 0.96071E+00 -0.0174 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.27118E-08 -8.5667 0.27116E-08 -8.5668 0.99992E+00 0.0000 54 KCl,aq 0.42111E-11 -11.3756 0.42111E-11 -11.3756 0.10000E+01 0.0000 55 KHSO4,aq 0.36159E-17 -17.4418 0.36159E-17 -17.4418 0.10000E+01 0.0000 56 KOH,aq 0.23669E-10 -10.6258 0.23669E-10 -10.6258 0.10000E+01 0.0000 57 KSO4- 0.65565E-09 -9.1833 0.62989E-09 -9.2007 0.96071E+00 -0.0174 58 MgCO3,aq 0.86252E-10 -10.0642 0.86252E-10 -10.0642 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26942E-09 -9.5696 0.25885E-09 -9.5870 0.96075E+00 -0.0174 60 MgCl+ 0.17105E-09 -9.7669 0.16433E-09 -9.7843 0.96075E+00 -0.0174 61 MgOH+ 0.10544E-07 -7.9770 0.10131E-07 -7.9944 0.96075E+00 -0.0174 63 MnO,aq 0.10444E-09 -9.9811 0.10444E-09 -9.9811 0.10000E+01 0.0000 64 MnOH+ 0.10481E-07 -7.9796 0.10070E-07 -7.9970 0.96075E+00 -0.0174 65 MnO2-2 0.36782E-17 -17.4344 0.33065E-17 -17.4806 0.89895E+00 -0.0463 66 HMnO2- 0.24645E-13 -13.6083 0.23677E-13 -13.6257 0.96071E+00 -0.0174 69 MnCl+ 0.90228E-10 -10.0447 0.86687E-10 -10.0620 0.96075E+00 -0.0174 70 MnSO4,aq 0.69781E-09 -9.1563 0.69781E-09 -9.1563 0.10000E+01 0.0000 71 NaCl,aq 0.71141E-08 -8.1479 0.71141E-08 -8.1479 0.10000E+01 0.0000 72 NaOH,aq 0.21855E-08 -8.6605 0.21855E-08 -8.6605 0.10000E+01 0.0000 74 OH- 0.18892E-04 -4.7237 0.18149E-04 -4.7411 0.96068E+00 -0.0174 79 HPO3-2 0.59726E-19 -19.2238 0.53691E-19 -19.2701 0.89895E+00 -0.0463 82 H3PO4,aq 0.44084E-13 -13.3557 0.44084E-13 -13.3557 0.10000E+01 0.0000 83 H2PO4- 0.37809E-08 -8.4224 0.36324E-08 -8.4398 0.96073E+00 -0.0174 84 PO4-3 0.20569E-12 -12.6868 0.16565E-12 -12.7808 0.80531E+00 -0.0940 87 H2P2O7-2 0.11487E-17 -17.9398 0.10327E-17 -17.9860 0.89895E+00 -0.0463 88 HP2O7-3 0.79638E-17 -17.0989 0.64070E-17 -17.1933 0.80451E+00 -0.0945 89 P2O7-4 0.69394E-19 -19.1587 0.47824E-19 -19.3204 0.68916E+00 -0.1617 90 H2S,aq 0.20102E-09 -9.6968 0.20101E-09 -9.6968 0.99992E+00 0.0000 91 S2-2 0.36970E-19 -19.4322 0.33234E-19 -19.4784 0.89895E+00 -0.0463 96 SO2,aq 0.28275E-18 -18.5486 0.28275E-18 -18.5486 0.10000E+01 0.0000 97 SO3-2 0.93683E-14 -14.0283 0.84242E-14 -14.0745 0.89922E+00 -0.0461 98 HSO3- 0.16960E-13 -13.7706 0.16294E-13 -13.7880 0.96071E+00 -0.0174 99 HSO4- 0.72726E-09 -9.1383 0.69873E-09 -9.1557 0.96077E+00 -0.0174 101 S2O3-2 0.60045E-16 -16.2215 0.53977E-16 -16.2678 0.89895E+00 -0.0463 Charge balance for all species = 0.1648E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3439748E-07 -.2653122E-04 -.2674135E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999786E+06 0.0000 3 Cl- 0.1379625E-03 0.1379747E-03 0.4891520E+01 3.6032 4 SO4-- 0.2534511E-04 0.2550160E-04 0.2449677E+01 10.3193 5 HCO3- 0.1223428E-04 0.1307004E-04 0.7974820E+00 2.5510 6 HS- 0.2106978E-08 0.2954090E-08 0.9769577E-04 -1.2129 7 Al+++ 0.3532461E-19 0.1450500E-05 0.3913590E-01 2.8961 8 H4SiO4 0.8288204E-04 0.8543654E-04 0.8211607E+01 -4.0815 9 Ca++ 0.2429840E-04 0.2452353E-04 0.9828349E+00 10.3009 10 Mg++ 0.9536079E-06 0.9647399E-06 0.2345430E-01 8.8947 11 Fe++ 0.6488794E-08 0.1311685E-07 0.7325223E-03 6.7275 12 K+ 0.1867688E-05 0.1868372E-05 0.7305564E-01 1.7347 13 Na+ 0.1711020E-03 0.1711177E-03 0.3933886E+01 3.6967 14 Mn++ 0.1202295E-06 0.1316032E-06 0.7229877E-02 7.9953 15 HPO4-- 0.6973188E-08 0.1075432E-07 0.1032169E-02 6.7588 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1326749E-03 -.2653113E-04 -.1061438E-03 0.0000000E+00 2 H2O 0.5550814E+02 0.5550808E+02 0.6060732E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2574835E-04 0.2550152E-04 0.2468321E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2438780E-06 0.2954080E-08 -.2468321E-06 0.0000000E+00 7 Al+++ 0.2869453E-04 0.1450495E-05 0.2724403E-04 0.0000000E+00 8 H4SiO4 0.9163249E-04 0.8543625E-04 0.6196242E-05 0.0000000E+00 9 Ca++ 0.2459232E-04 0.2452345E-04 0.6886731E-07 0.0000000E+00 10 Mg++ 0.6984127E-05 0.9647366E-06 0.6019390E-05 0.0000000E+00 11 Fe++ 0.6274476E-05 0.1311680E-07 0.6261359E-05 0.0000000E+00 12 K+ 0.1868365E-05 0.1868365E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1711171E-03 0.1711171E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1525796E-06 0.1316028E-06 0.2097686E-07 0.0000000E+00 15 HPO4-- 0.5207467E-07 0.1075429E-07 0.4132039E-07 0.0000000E+00 Chg. balance for solid moles: -.1102E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0088000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1377E-07 -7.861 0.6919E-05 -5.160 0.2440 0.2199E-05 clinochlore 0.1204E-05 -5.919 0.6692E-03 -3.174 23.60 0.2545E-03 daphnite 0.8573E-06 -6.067 0.6117E-03 -3.213 21.58 0.1854E-03 chlorite-Mn 0.4195E-08 -8.377 0.2974E-05 -5.527 0.1049 0.9479E-06 diaspore 0.2311E-04 -4.636 0.1387E-02 -2.858 48.91 0.4128E-03 hematite 0.9873E-06 -6.006 0.1577E-03 -3.802 5.562 0.2989E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5829E+00 0.5829E+00 1.0000 -0.234 daphnite 0.4151E+00 0.4151E+00 1.0000 -0.382 chlorite-Mn 0.2031E-02 0.2031E-02 1.0000 -2.692 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.002835 g Volume = 0.000886 cm3 Porosity: 99.9117% V(tot) - V(min): 0.10026E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0088000 g log = -2.0555 Original solution: 1000.0103000 g Original solution / Rock added: 113637.53 (Water/Rock Ratio), log = 5.0555 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.8460E-04 1.0073 0.8966E-04 0.8900E-04 CH4,gas 0.1521E-11 1.0129 0.1620E-11 0.1600E-11 H2,gas 0.3533E-05 1.0006 0.3719E-05 0.3717E-05 H2S,gas 0.5595E-08 0.9959 0.5862E-08 0.5887E-08 S2,gas 0.8846E-25 1.0000 0.9307E-25 0.9307E-25 CO,gas 0.8210E-13 1.0000 0.8637E-13 0.8637E-13 SO3,gas 0.8845E-35 1.0000 0.9305E-35 0.9305E-35 SO2,gas 0.1244E-17 1.0000 0.1309E-17 0.1309E-17 HCl,gas 0.1383E-14 1.0000 0.1455E-14 0.1455E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.41 -6.05 -2.016 0.10326E+05 -4.047 3 CH4,gas 4.81 -8.98 -13.79 -3.448 0.23547E+05 -11.790 4 H2,gas 8.29 0.86 -7.43 -4.245 0.12686E+05 -5.430 5 H2S,gas -5.94 -16.17 -10.23 -5.116 0.17471E+05 -8.232 6 S2,gas -7.03 -34.06 -27.03 -4.159 0.46155E+05 -25.031 7 CO,gas 3.51 -11.55 -15.06 -4.635 0.25721E+05 -13.064 8 SO3,gas 17.43 -19.60 -37.03 -9.258 0.63230E+05 -35.031 9 SO2,gas 1.14 -18.75 -19.88 -5.302 0.33950E+05 -17.883 10 HCl,gas 5.48 -11.36 -16.84 -8.419 0.28749E+05 -14.837 20 analcite 3.37 -1.57 -4.94 -0.549 0.84365E+04 21 andalusite 5.06 1.71 -3.35 -0.335 0.57230E+04 24 anhydrite -5.28 -9.30 -4.02 -2.012 0.68697E+04 29 anorthite 12.80 7.93 -4.87 -0.374 0.83114E+04 35 aragonite 0.99 -2.11 -3.10 -1.032 0.52862E+04 36 brucite 12.58 8.89 -3.68 -0.736 0.62868E+04 37 calcite 0.83 -2.11 -2.94 -0.981 0.50249E+04 40 carpholite-Mg 8.65 6.52 -2.13 -0.142 0.36311E+04 41 carpholite-Fe 6.78 4.36 -2.43 -0.162 0.41429E+04 50 chloritoid-Mg 13.26 10.61 -2.66 -0.177 0.45349E+04 51 chloritoid-Fe 9.24 8.44 -0.80 -0.053 0.13669E+04 52 chloritoid-Mn 11.46 9.71 -1.76 -0.117 0.30004E+04 54 coesite -2.37 -4.08 -1.71 -0.571 0.29235E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.08 -1.53 -0.511 0.26164E+04 75 epidote 24.78 20.45 -4.33 -0.210 0.73882E+04 78 fayalite 14.08 9.37 -4.71 -0.672 0.80346E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.02 -4.17 -0.348 0.71284E+04 92 hercynite 17.34 12.52 -4.82 -0.322 0.82383E+04 98 kaolinite -1.27 -2.37 -1.10 -0.100 0.18744E+04 99 kyanite 4.93 1.71 -3.22 -0.322 0.54998E+04 101 laumontite 2.97 -0.23 -3.21 -0.214 0.54769E+04 102 lawsonite 9.68 7.93 -1.75 -0.117 0.29853E+04 105 lizardite 23.29 18.52 -4.77 -0.397 0.81386E+04 106 magnesite 0.71 -3.52 -4.23 -1.408 0.72145E+04 107 magnetite 20.13 19.33 -0.81 -0.066 0.13791E+04 110 magnesioferrite 26.26 21.49 -4.76 -0.389 0.81361E+04 113 margarite 17.45 13.72 -3.73 -0.149 0.63682E+04 120 muscovite 2.68 -1.82 -4.50 -0.265 0.76850E+04 121 paragonite 4.34 0.14 -4.20 -0.247 0.71651E+04 128 periclase-Fe 11.64 6.73 -4.91 -1.228 0.83865E+04 144 pyrrhotiteFe0.875 -6.00 -10.39 -4.39 -1.616 0.75015E+04 145 pyroxmangite 7.42 3.91 -3.50 -0.700 0.59800E+04 146 pyrophyllite -6.10 -10.53 -4.44 -0.277 0.75743E+04 147 quartz -2.98 -4.08 -1.10 -0.367 0.18774E+04 152 rhodochrosite -0.96 -4.42 -3.46 -1.152 0.59023E+04 153 rhodonite 7.46 3.91 -3.55 -0.710 0.60592E+04 156 siderite -2.59 -5.68 -3.10 -1.032 0.52855E+04 157 sillimanite 5.32 1.71 -3.61 -0.361 0.61652E+04 169 sudoite 21.22 17.13 -4.09 -0.132 0.69786E+04 178 topaz-H 4.67 1.71 -2.96 -0.269 0.50489E+04 179 tridymite -2.61 -4.08 -1.47 -0.489 0.25047E+04 188 wairakite 4.06 -0.23 -4.29 -0.252 0.73277E+04 190 wollastonite 10.48 6.22 -4.26 -0.852 0.72780E+04 191 pseudo-wollastonite 11.02 6.22 -4.80 -0.960 0.81966E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -6.53 -4.97 -0.308 0.84896E+04 200 chalcedony -2.79 -4.08 -1.29 -0.429 0.21978E+04 202 montmorillonite-Ca -2.21 -6.85 -4.64 -0.287 0.79240E+04 204 montmorillonite-Mg -2.40 -7.09 -4.69 -0.290 0.79999E+04 206 nontronite-Ca 3.28 0.27 -3.01 -0.195 0.51325E+04 207 nontronite-H 2.60 -1.43 -4.02 -0.270 0.68669E+04 208 nontronite-K 3.40 -0.85 -4.26 -0.273 0.72692E+04 209 nontronite-Mg 3.14 0.04 -3.10 -0.201 0.52890E+04 210 nontronite-Na 3.58 -0.21 -3.79 -0.243 0.64693E+04 215 gypsum -4.92 -9.30 -4.38 -1.095 0.74765E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.73 -3.10 -0.774 0.52876E+04 241 silica-amorphous -2.08 -4.08 -2.00 -0.667 0.34179E+04 244 an25ab75 2.71 -2.26 -4.97 -0.382 0.84785E+04 245 an30ab70 3.34 -1.58 -4.92 -0.379 0.84030E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0088000 g New total amount of reactant added: 0.0092000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1648E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0092000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2721517E-03 Osmotic coef. = 0.9901 True ionic strength = .2762428E-03 Chg. balance for total moles = 0.1648E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.32774E-07 -7.4845 0.31489E-07 -7.5018 0.96077E+00 -0.0174 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13253E-03 -3.8777 0.96065E+00 -0.0174 4 SO4-- 0.25343E-04 -4.5961 0.22777E-04 -4.6425 0.89876E+00 -0.0464 5 HCO3- 0.12267E-04 -4.9113 0.11784E-04 -4.9287 0.96068E+00 -0.0174 6 HS- 0.14833E-08 -8.8288 0.14250E-08 -8.8462 0.96065E+00 -0.0174 7 Al+++ 0.30568E-19 -19.5147 0.24578E-19 -19.6095 0.80404E+00 -0.0947 8 H4SiO4 0.86428E-04 -4.0633 0.86428E-04 -4.0633 0.10000E+01 0.0000 9 Ca++ 0.24746E-04 -4.6065 0.22237E-04 -4.6529 0.89863E+00 -0.0464 10 Mg++ 0.85148E-06 -6.0698 0.76510E-06 -6.1163 0.89855E+00 -0.0465 11 Fe++ 0.56732E-08 -8.2462 0.50977E-08 -8.2926 0.89857E+00 -0.0464 12 K+ 0.19526E-05 -5.7094 0.18758E-05 -5.7268 0.96068E+00 -0.0174 13 Na+ 0.17160E-03 -3.7655 0.16485E-03 -3.7829 0.96065E+00 -0.0174 14 Mn++ 0.12195E-06 -6.9138 0.10958E-06 -6.9603 0.89858E+00 -0.0464 15 HPO4-- 0.63460E-08 -8.1975 0.57036E-08 -8.2438 0.89877E+00 -0.0464 16 HSiO3- 0.27877E-05 -5.5548 0.26780E-05 -5.5722 0.96065E+00 -0.0174 17 Ca(HSiO3)+ 0.13888E-08 -8.8573 0.13342E-08 -8.8748 0.96069E+00 -0.0174 18 Mg(HSiO3)+ 0.59469E-10 -10.2257 0.57131E-10 -10.2431 0.96069E+00 -0.0174 19 NaHSiO3,aq 0.70115E-08 -8.1542 0.70115E-08 -8.1542 0.10000E+01 0.0000 20 AlO+ 0.33310E-11 -11.4774 0.32000E-11 -11.4948 0.96069E+00 -0.0174 21 AlOH+2 0.56173E-15 -15.2505 0.50477E-15 -15.2969 0.89860E+00 -0.0464 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.15012E-05 -5.8236 0.14421E-05 -5.8410 0.96062E+00 -0.0175 24 CH4,aq 0.72348E-15 -15.1406 0.72342E-15 -15.1406 0.99992E+00 0.0000 29 CO,aq 0.48446E-16 -16.3147 0.48446E-16 -16.3147 0.10000E+01 0.0000 30 CO2,aq 0.74822E-06 -6.1260 0.74816E-06 -6.1260 0.99992E+00 0.0000 31 CO3-2 0.38501E-07 -7.4145 0.34602E-07 -7.4609 0.89873E+00 -0.0464 32 CaCO3,aq 0.94240E-08 -8.0258 0.94240E-08 -8.0258 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.68731E-08 -8.1628 0.66029E-08 -8.1803 0.96069E+00 -0.0174 34 CaCl+ 0.48885E-08 -8.3108 0.46963E-08 -8.3282 0.96069E+00 -0.0174 35 CaCl2,aq 0.14492E-12 -12.8389 0.14492E-12 -12.8389 0.10000E+01 0.0000 36 CaOH+ 0.51833E-07 -7.2854 0.49796E-07 -7.3028 0.96069E+00 -0.0174 37 CaSO4,aq 0.15782E-06 -6.8019 0.15782E-06 -6.8019 0.10000E+01 0.0000 38 HCl,aq 0.78499E-12 -12.1051 0.78499E-12 -12.1051 0.10000E+01 0.0000 43 FeCl+ 0.10953E-11 -11.9604 0.10523E-11 -11.9779 0.96069E+00 -0.0174 46 FeO,aq 0.20331E-09 -9.6918 0.20331E-09 -9.6918 0.10000E+01 0.0000 47 FeOH+ 0.55867E-08 -8.2528 0.53671E-08 -8.2703 0.96069E+00 -0.0174 48 HFeO2- 0.72291E-10 -10.1409 0.69446E-10 -10.1584 0.96065E+00 -0.0174 49 FeO+ 0.27114E-12 -12.5668 0.26048E-12 -12.5842 0.96069E+00 -0.0174 50 FeOH+2 0.16985E-17 -17.7699 0.15263E-17 -17.8164 0.89860E+00 -0.0464 51 FeO2- 0.53747E-10 -10.2696 0.51632E-10 -10.2871 0.96065E+00 -0.0174 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.25144E-08 -8.5996 0.25142E-08 -8.5996 0.99992E+00 0.0000 54 KCl,aq 0.44020E-11 -11.3564 0.44020E-11 -11.3564 0.10000E+01 0.0000 55 KHSO4,aq 0.36002E-17 -17.4437 0.36002E-17 -17.4437 0.10000E+01 0.0000 56 KOH,aq 0.25970E-10 -10.5855 0.25970E-10 -10.5855 0.10000E+01 0.0000 57 KSO4- 0.68522E-09 -9.1642 0.65826E-09 -9.1816 0.96065E+00 -0.0174 58 MgCO3,aq 0.81022E-10 -10.0914 0.81022E-10 -10.0914 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24114E-09 -9.6177 0.23166E-09 -9.6351 0.96069E+00 -0.0174 60 MgCl+ 0.15269E-09 -9.8162 0.14669E-09 -9.8336 0.96069E+00 -0.0174 61 MgOH+ 0.98802E-08 -8.0052 0.94918E-08 -8.0227 0.96069E+00 -0.0174 63 MnO,aq 0.11667E-09 -9.9330 0.11667E-09 -9.9330 0.10000E+01 0.0000 64 MnOH+ 0.11156E-07 -7.9525 0.10718E-07 -7.9699 0.96069E+00 -0.0174 65 MnO2-2 0.45278E-17 -17.3441 0.40692E-17 -17.3905 0.89873E+00 -0.0464 66 HMnO2- 0.28899E-13 -13.5391 0.27762E-13 -13.5566 0.96065E+00 -0.0174 69 MnCl+ 0.91496E-10 -10.0386 0.87900E-10 -10.0560 0.96069E+00 -0.0174 70 MnSO4,aq 0.70738E-09 -9.1503 0.70738E-09 -9.1503 0.10000E+01 0.0000 71 NaCl,aq 0.71340E-08 -8.1467 0.71340E-08 -8.1467 0.10000E+01 0.0000 72 NaOH,aq 0.23004E-08 -8.6382 0.23004E-08 -8.6382 0.10000E+01 0.0000 74 OH- 0.19830E-04 -4.7027 0.19049E-04 -4.7201 0.96062E+00 -0.0175 79 HPO3-2 0.50398E-19 -19.2976 0.45294E-19 -19.3440 0.89873E+00 -0.0464 82 H3PO4,aq 0.36409E-13 -13.4388 0.36409E-13 -13.4388 0.10000E+01 0.0000 83 H2PO4- 0.32777E-08 -8.4844 0.31487E-08 -8.5019 0.96067E+00 -0.0174 84 PO4-3 0.19654E-12 -12.7066 0.15818E-12 -12.8008 0.80485E+00 -0.0943 87 H2P2O7-2 0.86340E-18 -18.0638 0.77596E-18 -18.1102 0.89873E+00 -0.0464 88 HP2O7-3 0.62845E-17 -17.2017 0.50531E-17 -17.2964 0.80405E+00 -0.0947 89 P2O7-4 0.57503E-19 -19.2403 0.39588E-19 -19.4024 0.68846E+00 -0.1621 90 H2S,aq 0.13483E-09 -9.8702 0.13481E-09 -9.8703 0.99992E+00 0.0000 91 S2-2 0.19764E-19 -19.7041 0.17762E-19 -19.7505 0.89873E+00 -0.0464 96 SO2,aq 0.23790E-18 -18.6236 0.23790E-18 -18.6236 0.10000E+01 0.0000 97 SO3-2 0.86856E-14 -14.0612 0.78083E-14 -14.1074 0.89899E+00 -0.0462 98 HSO3- 0.14978E-13 -13.8245 0.14389E-13 -13.8420 0.96065E+00 -0.0174 99 HSO4- 0.69271E-09 -9.1594 0.66549E-09 -9.1769 0.96071E+00 -0.0174 101 S2O3-2 0.40269E-16 -16.3950 0.36190E-16 -16.4414 0.89873E+00 -0.0464 Charge balance for all species = 0.1648E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3277443E-07 -.2803779E-04 -.2825985E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999782E+06 0.0000 3 Cl- 0.1379624E-03 0.1379747E-03 0.4891519E+01 3.6242 4 SO4-- 0.2534304E-04 0.2550235E-04 0.2449747E+01 10.3612 5 HCO3- 0.1226670E-04 0.1307005E-04 0.7974818E+00 2.5732 6 HS- 0.1483322E-08 0.2214572E-08 0.7323888E-04 -1.3444 7 Al+++ 0.3056820E-19 0.1521516E-05 0.4105197E-01 2.8961 8 H4SiO4 0.8642842E-04 0.8922453E-04 0.8575681E+01 -4.0633 9 Ca++ 0.2474554E-04 0.2497777E-04 0.1001039E+01 10.3508 10 Mg++ 0.8514849E-06 0.8618994E-06 0.2095408E-01 8.8874 11 Fe++ 0.5673175E-08 0.1179407E-07 0.6586505E-03 6.7111 12 K+ 0.1952582E-05 0.1953298E-05 0.7637633E-01 1.7750 13 Na+ 0.1716034E-03 0.1716199E-03 0.3945428E+01 3.7189 14 Mn++ 0.1219507E-06 0.1340226E-06 0.7362790E-02 8.0434 15 HPO4-- 0.6346044E-08 0.9623931E-08 0.9236769E-03 6.7598 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1392983E-03 -.2803769E-04 -.1112607E-03 0.0000000E+00 2 H2O 0.5550813E+02 0.5550807E+02 0.6340925E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2575943E-04 0.2550226E-04 0.2571779E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2549634E-06 0.2214564E-08 -.2571779E-06 0.0000000E+00 7 Al+++ 0.2999882E-04 0.1521511E-05 0.2847731E-04 0.0000000E+00 8 H4SiO4 0.9579760E-04 0.8922422E-04 0.6573387E-05 0.0000000E+00 9 Ca++ 0.2505237E-04 0.2497768E-04 0.7469635E-07 0.0000000E+00 10 Mg++ 0.7301587E-05 0.8618963E-06 0.6439691E-05 0.0000000E+00 11 Fe++ 0.6559679E-05 0.1179403E-07 0.6547885E-05 0.0000000E+00 12 K+ 0.1953291E-05 0.1953291E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1716192E-03 0.1716192E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1595151E-06 0.1340222E-06 0.2549291E-07 0.0000000E+00 15 HPO4-- 0.5444170E-07 0.9623897E-08 0.4481781E-07 0.0000000E+00 Chg. balance for solid moles: 0.2683E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0092000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1494E-07 -7.826 0.7504E-05 -5.125 0.2520 0.2385E-05 clinochlore 0.1288E-05 -5.890 0.7159E-03 -3.145 24.04 0.2723E-03 daphnite 0.8981E-06 -6.047 0.6408E-03 -3.193 21.52 0.1942E-03 chlorite-Mn 0.5099E-08 -8.293 0.3615E-05 -5.442 0.1214 0.1152E-05 diaspore 0.2410E-04 -4.618 0.1445E-02 -2.840 48.55 0.4303E-03 hematite 0.1029E-05 -5.988 0.1643E-03 -3.784 5.517 0.3114E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5878E+00 0.5878E+00 1.0000 -0.231 daphnite 0.4099E+00 0.4099E+00 1.0000 -0.387 chlorite-Mn 0.2327E-02 0.2327E-02 1.0000 -2.633 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.002978 g Volume = 0.000931 cm3 Porosity: 99.9072% V(tot) - V(min): 0.10027E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0092000 g log = -2.0362 Original solution: 1000.0103000 g Original solution / Rock added: 108696.77 (Water/Rock Ratio), log = 5.0362 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.8081E-04 1.0073 0.8564E-04 0.8502E-04 CH4,gas 0.1074E-11 1.0129 0.1144E-11 0.1129E-11 H2,gas 0.3276E-05 1.0006 0.3448E-05 0.3446E-05 H2S,gas 0.3753E-08 0.9959 0.3932E-08 0.3948E-08 S2,gas 0.4629E-25 1.0000 0.4870E-25 0.4870E-25 CO,gas 0.7271E-13 1.0000 0.7650E-13 0.7650E-13 SO3,gas 0.8026E-35 1.0000 0.8443E-35 0.8443E-35 SO2,gas 0.1047E-17 1.0000 0.1101E-17 0.1101E-17 HCl,gas 0.1318E-14 1.0000 0.1386E-14 0.1386E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.43 -6.07 -2.022 0.10360E+05 -4.067 3 CH4,gas 4.81 -9.13 -13.94 -3.485 0.23805E+05 -11.942 4 H2,gas 8.29 0.82 -7.46 -4.264 0.12742E+05 -5.462 5 H2S,gas -5.94 -16.35 -10.41 -5.203 0.17767E+05 -8.405 6 S2,gas -7.03 -34.35 -27.31 -4.202 0.46635E+05 -25.313 7 CO,gas 3.51 -11.61 -15.12 -4.651 0.25811E+05 -13.116 8 SO3,gas 17.43 -19.65 -37.07 -9.268 0.63302E+05 -35.073 9 SO2,gas 1.14 -18.82 -19.96 -5.322 0.34078E+05 -17.958 10 HCl,gas 5.48 -11.38 -16.86 -8.429 0.28785E+05 -14.858 20 analcite 3.37 -1.51 -4.88 -0.542 0.83364E+04 21 andalusite 5.06 1.73 -3.33 -0.333 0.56919E+04 24 anhydrite -5.28 -9.30 -4.02 -2.008 0.68566E+04 29 anorthite 12.80 8.02 -4.78 -0.368 0.81641E+04 35 aragonite 0.99 -2.08 -3.07 -1.022 0.52351E+04 36 brucite 12.58 8.89 -3.69 -0.738 0.62992E+04 37 calcite 0.83 -2.08 -2.91 -0.971 0.49738E+04 40 carpholite-Mg 8.65 6.55 -2.10 -0.140 0.35814E+04 41 carpholite-Fe 6.78 4.38 -2.41 -0.160 0.41087E+04 50 chloritoid-Mg 13.26 10.62 -2.64 -0.176 0.45163E+04 51 chloritoid-Fe 9.24 8.44 -0.80 -0.053 0.13639E+04 52 chloritoid-Mn 11.46 9.77 -1.69 -0.113 0.28872E+04 54 coesite -2.37 -4.06 -1.69 -0.565 0.28924E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.06 -1.51 -0.505 0.25853E+04 75 epidote 24.78 20.60 -4.17 -0.202 0.71248E+04 78 fayalite 14.08 9.36 -4.72 -0.674 0.80595E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.01 -4.19 -0.349 0.71504E+04 92 hercynite 17.34 12.50 -4.84 -0.323 0.82663E+04 98 kaolinite -1.27 -2.33 -1.06 -0.096 0.18123E+04 99 kyanite 4.93 1.73 -3.20 -0.320 0.54687E+04 101 laumontite 2.97 -0.11 -3.08 -0.206 0.52675E+04 102 lawsonite 9.68 8.02 -1.66 -0.111 0.28380E+04 105 lizardite 23.29 18.54 -4.75 -0.396 0.81137E+04 106 magnesite 0.71 -3.54 -4.25 -1.417 0.72609E+04 107 magnetite 20.13 19.31 -0.82 -0.067 0.14071E+04 110 magnesioferrite 26.26 21.49 -4.77 -0.390 0.81485E+04 113 margarite 17.45 13.81 -3.64 -0.146 0.62209E+04 120 muscovite 2.68 -1.73 -4.41 -0.259 0.75230E+04 121 paragonite 4.34 0.22 -4.12 -0.242 0.70339E+04 128 periclase-Fe 11.64 6.71 -4.93 -1.232 0.84145E+04 137 prehnite-Fe 22.59 17.71 -4.88 -0.294 0.83331E+04 144 pyrrhotiteFe0.875 -6.00 -10.58 -4.58 -1.683 0.78153E+04 145 pyroxmangite 7.42 3.98 -3.44 -0.687 0.58668E+04 146 pyrophyllite -6.10 -10.46 -4.36 -0.273 0.74500E+04 147 quartz -2.98 -4.06 -1.08 -0.360 0.18464E+04 152 rhodochrosite -0.96 -4.39 -3.43 -1.143 0.58542E+04 153 rhodonite 7.46 3.98 -3.48 -0.696 0.59460E+04 156 siderite -2.59 -5.72 -3.13 -1.044 0.53475E+04 157 sillimanite 5.32 1.73 -3.59 -0.359 0.61341E+04 164 stilbite -7.41 -12.30 -4.89 -0.233 0.83574E+04 169 sudoite 21.22 17.17 -4.05 -0.131 0.69102E+04 178 topaz-H 4.67 1.73 -2.94 -0.267 0.50178E+04 179 tridymite -2.61 -4.06 -1.45 -0.483 0.24737E+04 188 wairakite 4.06 -0.11 -4.17 -0.245 0.71183E+04 190 wollastonite 10.48 6.29 -4.19 -0.839 0.71618E+04 191 pseudo-wollastonite 11.02 6.29 -4.73 -0.946 0.80804E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -6.46 -4.90 -0.303 0.83615E+04 197 beidellite-Mg -1.71 -6.70 -4.99 -0.309 0.85225E+04 200 chalcedony -2.79 -4.06 -1.27 -0.423 0.21667E+04 202 montmorillonite-Ca -2.21 -6.78 -4.56 -0.282 0.77898E+04 204 montmorillonite-Mg -2.40 -7.02 -4.62 -0.286 0.78817E+04 206 nontronite-Ca 3.28 0.35 -2.93 -0.190 0.50045E+04 207 nontronite-H 2.60 -1.36 -3.95 -0.265 0.67528E+04 208 nontronite-K 3.40 -0.77 -4.18 -0.268 0.71325E+04 209 nontronite-Mg 3.14 0.11 -3.03 -0.197 0.51770E+04 210 nontronite-Na 3.58 -0.13 -3.71 -0.238 0.63428E+04 215 gypsum -4.92 -9.30 -4.37 -1.093 0.74634E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.71 -3.11 -0.778 0.53156E+04 241 silica-amorphous -2.08 -4.06 -1.98 -0.661 0.33869E+04 243 an20ab80 2.08 -2.86 -4.94 -0.380 0.84280E+04 244 an25ab75 2.71 -2.18 -4.89 -0.376 0.83433E+04 245 an30ab70 3.34 -1.50 -4.84 -0.372 0.82669E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0092000 g New total amount of reactant added: 0.0096000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1648E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0096000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2734990E-03 Osmotic coef. = 0.9901 True ionic strength = .2779055E-03 Chg. balance for total moles = 0.1648E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.31277E-07 -7.5048 0.30048E-07 -7.5222 0.96071E+00 -0.0174 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13252E-03 -3.8777 0.96059E+00 -0.0175 4 SO4-- 0.25341E-04 -4.5962 0.22769E-04 -4.6426 0.89853E+00 -0.0465 5 HCO3- 0.12297E-04 -4.9102 0.11812E-04 -4.9277 0.96062E+00 -0.0175 6 HS- 0.10719E-08 -8.9698 0.10297E-08 -8.9873 0.96059E+00 -0.0175 7 Al+++ 0.26577E-19 -19.5755 0.21356E-19 -19.6705 0.80357E+00 -0.0950 8 H4SiO4 0.89971E-04 -4.0459 0.89971E-04 -4.0459 0.10000E+01 0.0000 9 Ca++ 0.25193E-04 -4.5987 0.22633E-04 -4.6453 0.89840E+00 -0.0465 10 Mg++ 0.76224E-06 -6.1179 0.68473E-06 -6.1645 0.89831E+00 -0.0466 11 Fe++ 0.49909E-08 -8.3018 0.44835E-08 -8.3484 0.89833E+00 -0.0466 12 K+ 0.20375E-05 -5.6909 0.19572E-05 -5.7084 0.96062E+00 -0.0174 13 Na+ 0.17210E-03 -3.7642 0.16532E-03 -3.7817 0.96059E+00 -0.0175 14 Mn++ 0.12314E-06 -6.9096 0.11062E-06 -6.9562 0.89835E+00 -0.0466 15 HPO4-- 0.57905E-08 -8.2373 0.52030E-08 -8.2837 0.89853E+00 -0.0465 16 HSiO3- 0.30413E-05 -5.5169 0.29214E-05 -5.5344 0.96059E+00 -0.0175 17 Ca(HSiO3)+ 0.15422E-08 -8.8119 0.14814E-08 -8.8293 0.96063E+00 -0.0174 18 Mg(HSiO3)+ 0.58064E-10 -10.2361 0.55778E-10 -10.2535 0.96063E+00 -0.0174 19 NaHSiO3,aq 0.76707E-08 -8.1152 0.76707E-08 -8.1152 0.10000E+01 0.0000 20 AlO+ 0.31788E-11 -11.4977 0.30536E-11 -11.5152 0.96063E+00 -0.0174 21 AlOH+2 0.51163E-15 -15.2910 0.45963E-15 -15.3376 0.89837E+00 -0.0465 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.15733E-05 -5.8032 0.15112E-05 -5.8207 0.96055E+00 -0.0175 24 CH4,aq 0.52419E-15 -15.2805 0.52415E-15 -15.2805 0.99992E+00 0.0000 29 CO,aq 0.43231E-16 -16.3642 0.43231E-16 -16.3642 0.10000E+01 0.0000 30 CO2,aq 0.71567E-06 -6.1453 0.71561E-06 -6.1453 0.99992E+00 0.0000 31 CO3-2 0.40454E-07 -7.3930 0.36347E-07 -7.4395 0.89849E+00 -0.0465 32 CaCO3,aq 0.10076E-07 -7.9967 0.10076E-07 -7.9967 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.70125E-08 -8.1541 0.67364E-08 -8.1716 0.96063E+00 -0.0174 34 CaCl+ 0.49755E-08 -8.3032 0.47796E-08 -8.3206 0.96063E+00 -0.0174 35 CaCl2,aq 0.14748E-12 -12.8313 0.14748E-12 -12.8313 0.10000E+01 0.0000 36 CaOH+ 0.55290E-07 -7.2574 0.53113E-07 -7.2748 0.96063E+00 -0.0174 37 CaSO4,aq 0.16057E-06 -6.7943 0.16057E-06 -6.7943 0.10000E+01 0.0000 38 HCl,aq 0.74902E-12 -12.1255 0.74902E-12 -12.1255 0.10000E+01 0.0000 43 FeCl+ 0.96336E-12 -12.0162 0.92543E-12 -12.0337 0.96063E+00 -0.0174 46 FeO,aq 0.19637E-09 -9.7069 0.19637E-09 -9.7069 0.10000E+01 0.0000 47 FeOH+ 0.51495E-08 -8.2882 0.49467E-08 -8.3057 0.96063E+00 -0.0174 48 HFeO2- 0.73177E-10 -10.1356 0.70293E-10 -10.1531 0.96059E+00 -0.0175 49 FeO+ 0.25875E-12 -12.5871 0.24856E-12 -12.6046 0.96063E+00 -0.0174 50 FeOH+2 0.15470E-17 -17.8105 0.13898E-17 -17.8571 0.89837E+00 -0.0465 51 FeO2- 0.56328E-10 -10.2493 0.54108E-10 -10.2667 0.96059E+00 -0.0175 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.23458E-08 -8.6297 0.23456E-08 -8.6298 0.99992E+00 0.0000 54 KCl,aq 0.45928E-11 -11.3379 0.45928E-11 -11.3379 0.10000E+01 0.0000 55 KHSO4,aq 0.35834E-17 -17.4457 0.35834E-17 -17.4457 0.10000E+01 0.0000 56 KOH,aq 0.28397E-10 -10.5467 0.28397E-10 -10.5467 0.10000E+01 0.0000 57 KSO4- 0.71476E-09 -9.1458 0.68659E-09 -9.1633 0.96059E+00 -0.0175 58 MgCO3,aq 0.76169E-10 -10.1182 0.76169E-10 -10.1182 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21634E-09 -9.6649 0.20782E-09 -9.6823 0.96063E+00 -0.0174 60 MgCl+ 0.13665E-09 -9.8644 0.13127E-09 -9.8818 0.96063E+00 -0.0174 61 MgOH+ 0.92670E-08 -8.0331 0.89021E-08 -8.0505 0.96063E+00 -0.0174 63 MnO,aq 0.12934E-09 -9.8883 0.12934E-09 -9.8883 0.10000E+01 0.0000 64 MnOH+ 0.11803E-07 -7.9280 0.11338E-07 -7.9455 0.96063E+00 -0.0174 65 MnO2-2 0.55139E-17 -17.2585 0.49542E-17 -17.3050 0.89849E+00 -0.0465 66 HMnO2- 0.33576E-13 -13.4740 0.32253E-13 -13.4914 0.96059E+00 -0.0175 69 MnCl+ 0.92363E-10 -10.0345 0.88727E-10 -10.0519 0.96063E+00 -0.0174 70 MnSO4,aq 0.71383E-09 -9.1464 0.71383E-09 -9.1464 0.10000E+01 0.0000 71 NaCl,aq 0.71539E-08 -8.1455 0.71539E-08 -8.1455 0.10000E+01 0.0000 72 NaOH,aq 0.24176E-08 -8.6166 0.24176E-08 -8.6166 0.10000E+01 0.0000 74 OH- 0.20783E-04 -4.6823 0.19963E-04 -4.6998 0.96055E+00 -0.0175 79 HPO3-2 0.42901E-19 -19.3675 0.38546E-19 -19.4140 0.89849E+00 -0.0465 82 H3PO4,aq 0.30243E-13 -13.5194 0.30243E-13 -13.5194 0.10000E+01 0.0000 83 H2PO4- 0.28533E-08 -8.5447 0.27409E-08 -8.5621 0.96061E+00 -0.0175 84 PO4-3 0.18799E-12 -12.7259 0.15122E-12 -12.8204 0.80439E+00 -0.0945 87 H2P2O7-2 0.65440E-18 -18.1842 0.58797E-18 -18.2306 0.89849E+00 -0.0465 88 HP2O7-3 0.49933E-17 -17.3016 0.40125E-17 -17.3966 0.80358E+00 -0.0950 89 P2O7-4 0.47901E-19 -19.3197 0.32943E-19 -19.4822 0.68774E+00 -0.1626 90 H2S,aq 0.92965E-10 -10.0317 0.92957E-10 -10.0317 0.99992E+00 0.0000 91 S2-2 0.11064E-19 -19.9561 0.99410E-20 -20.0026 0.89849E+00 -0.0465 96 SO2,aq 0.20202E-18 -18.6946 0.20202E-18 -18.6946 0.10000E+01 0.0000 97 SO3-2 0.81023E-14 -14.0914 0.72820E-14 -14.1377 0.89876E+00 -0.0464 98 HSO3- 0.13330E-13 -13.8752 0.12805E-13 -13.8926 0.96059E+00 -0.0175 99 HSO4- 0.66082E-09 -9.1799 0.63481E-09 -9.1974 0.96064E+00 -0.0174 101 S2O3-2 0.27763E-16 -16.5565 0.24945E-16 -16.6030 0.89849E+00 -0.0465 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3127671E-07 -.2957317E-04 -.2980738E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999778E+06 0.0000 3 Cl- 0.1379623E-03 0.1379747E-03 0.4891517E+01 3.6445 4 SO4-- 0.2534074E-04 0.2550285E-04 0.2449794E+01 10.4017 5 HCO3- 0.1229654E-04 0.1307005E-04 0.7974816E+00 2.5945 6 HS- 0.1071894E-08 0.1718797E-08 0.5684289E-04 -1.4651 7 Al+++ 0.2657652E-19 0.1593607E-05 0.4299703E-01 2.8961 8 H4SiO4 0.8997071E-04 0.9302124E-04 0.8940592E+01 -4.0459 9 Ca++ 0.2519278E-04 0.2543225E-04 0.1019253E+01 10.3991 10 Mg++ 0.7622439E-06 0.7719981E-06 0.1876844E-01 8.8799 11 Fe++ 0.4990892E-08 0.1067097E-07 0.5959294E-03 6.6960 12 K+ 0.2037476E-05 0.2038224E-05 0.7969702E-01 1.8138 13 Na+ 0.1721047E-03 0.1721220E-03 0.3956969E+01 3.7405 14 Mn++ 0.1231386E-06 0.1358771E-06 0.7464665E-02 8.0882 15 HPO4-- 0.5790510E-08 0.8644045E-08 0.8296300E-03 6.7606 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1459217E-03 -.2957306E-04 -.1163487E-03 0.0000000E+00 2 H2O 0.5550813E+02 0.5550806E+02 0.6620511E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2577052E-04 0.2550275E-04 0.2677675E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2660487E-06 0.1718790E-08 -.2677675E-06 0.0000000E+00 7 Al+++ 0.3130312E-04 0.1593601E-05 0.2970952E-04 0.0000000E+00 8 H4SiO4 0.9996272E-04 0.9302090E-04 0.6941819E-05 0.0000000E+00 9 Ca++ 0.2551243E-04 0.2543215E-04 0.8027454E-07 0.0000000E+00 10 Mg++ 0.7619048E-05 0.7719952E-06 0.6847052E-05 0.0000000E+00 11 Fe++ 0.6844882E-05 0.1067093E-07 0.6834212E-05 0.0000000E+00 12 K+ 0.2038217E-05 0.2038217E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1721213E-03 0.1721213E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1664505E-06 0.1358766E-06 0.3057392E-07 0.0000000E+00 15 HPO4-- 0.5680874E-07 0.8644013E-08 0.4816472E-07 0.0000000E+00 Chg. balance for solid moles: -.4950E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0096000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1605E-07 -7.794 0.8065E-05 -5.093 0.2586 0.2563E-05 clinochlore 0.1369E-05 -5.863 0.7612E-03 -3.119 24.41 0.2895E-03 daphnite 0.9384E-06 -6.028 0.6696E-03 -3.174 21.47 0.2029E-03 chlorite-Mn 0.6115E-08 -8.214 0.4335E-05 -5.363 0.1390 0.1382E-05 diaspore 0.2508E-04 -4.601 0.1505E-02 -2.823 48.24 0.4479E-03 hematite 0.1071E-05 -5.970 0.1710E-03 -3.767 5.484 0.3242E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5918E+00 0.5918E+00 1.0000 -0.228 daphnite 0.4055E+00 0.4055E+00 1.0000 -0.392 chlorite-Mn 0.2643E-02 0.2643E-02 1.0000 -2.578 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.003119 g Volume = 0.000977 cm3 Porosity: 99.9027% V(tot) - V(min): 0.10029E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0096000 g log = -2.0177 Original solution: 1000.0103000 g Original solution / Rock added: 104167.74 (Water/Rock Ratio), log = 5.0177 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.7730E-04 1.0073 0.8191E-04 0.8132E-04 CH4,gas 0.7778E-12 1.0129 0.8289E-12 0.8183E-12 H2,gas 0.3056E-05 1.0006 0.3217E-05 0.3215E-05 H2S,gas 0.2588E-08 0.9959 0.2711E-08 0.2722E-08 S2,gas 0.2529E-25 1.0000 0.2660E-25 0.2660E-25 CO,gas 0.6489E-13 1.0000 0.6826E-13 0.6826E-13 SO3,gas 0.7306E-35 1.0000 0.7686E-35 0.7686E-35 SO2,gas 0.8891E-18 1.0000 0.9354E-18 0.9354E-18 HCl,gas 0.1257E-14 1.0000 0.1323E-14 0.1323E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.45 -6.09 -2.029 0.10393E+05 -4.087 3 CH4,gas 4.81 -9.27 -14.08 -3.520 0.24044E+05 -12.082 4 H2,gas 8.29 0.79 -7.49 -4.281 0.12793E+05 -5.493 5 H2S,gas -5.94 -16.51 -10.57 -5.283 0.18043E+05 -8.567 6 S2,gas -7.03 -34.61 -27.58 -4.242 0.47084E+05 -25.575 7 CO,gas 3.51 -11.66 -15.17 -4.666 0.25895E+05 -13.166 8 SO3,gas 17.43 -19.69 -37.11 -9.279 0.63372E+05 -35.114 9 SO2,gas 1.14 -18.89 -20.03 -5.341 0.34199E+05 -18.029 10 HCl,gas 5.48 -11.40 -16.88 -8.439 0.28820E+05 -14.879 20 analcite 3.37 -1.46 -4.83 -0.536 0.82400E+04 21 andalusite 5.06 1.75 -3.32 -0.332 0.56621E+04 24 anhydrite -5.28 -9.29 -4.01 -2.004 0.68438E+04 29 anorthite 12.80 8.10 -4.70 -0.361 0.80220E+04 35 aragonite 0.99 -2.05 -3.04 -1.012 0.51855E+04 36 brucite 12.58 8.88 -3.70 -0.739 0.63120E+04 37 calcite 0.83 -2.05 -2.88 -0.961 0.49242E+04 40 carpholite-Mg 8.65 6.58 -2.07 -0.138 0.35346E+04 41 carpholite-Fe 6.78 4.40 -2.39 -0.159 0.40749E+04 50 chloritoid-Mg 13.26 10.63 -2.64 -0.176 0.44993E+04 51 chloritoid-Fe 9.24 8.44 -0.80 -0.053 0.13598E+04 52 chloritoid-Mn 11.46 9.83 -1.63 -0.109 0.27810E+04 54 coesite -2.37 -4.05 -1.68 -0.559 0.28627E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.05 -1.50 -0.499 0.25555E+04 75 epidote 24.78 20.75 -4.02 -0.195 0.68703E+04 78 fayalite 14.08 9.35 -4.73 -0.676 0.80812E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.00 -4.20 -0.350 0.71680E+04 92 hercynite 17.34 12.49 -4.86 -0.324 0.82921E+04 98 kaolinite -1.27 -2.30 -1.03 -0.093 0.17527E+04 99 kyanite 4.93 1.75 -3.19 -0.319 0.54389E+04 101 laumontite 2.97 0.01 -2.97 -0.198 0.50658E+04 102 lawsonite 9.68 8.10 -1.58 -0.105 0.26959E+04 105 lizardite 23.29 18.55 -4.74 -0.395 0.80926E+04 106 magnesite 0.71 -3.57 -4.28 -1.426 0.73067E+04 107 magnetite 20.13 19.29 -0.84 -0.069 0.14329E+04 110 magnesioferrite 26.26 21.48 -4.78 -0.390 0.81613E+04 113 margarite 17.45 13.89 -3.56 -0.142 0.60788E+04 116 microcline -2.43 -7.43 -5.00 -0.384 0.85305E+04 120 muscovite 2.68 -1.64 -4.31 -0.254 0.73674E+04 121 paragonite 4.34 0.29 -4.05 -0.238 0.69077E+04 128 periclase-Fe 11.64 6.70 -4.94 -1.236 0.84403E+04 137 prehnite-Fe 22.59 17.86 -4.73 -0.285 0.80786E+04 144 pyrrhotiteFe0.875 -6.00 -10.75 -4.75 -1.746 0.81071E+04 145 pyroxmangite 7.42 4.04 -3.37 -0.675 0.57605E+04 146 pyrophyllite -6.10 -10.39 -4.29 -0.268 0.73308E+04 147 quartz -2.98 -4.05 -1.06 -0.355 0.18166E+04 152 rhodochrosite -0.96 -4.36 -3.40 -1.134 0.58107E+04 153 rhodonite 7.46 4.04 -3.42 -0.684 0.58398E+04 156 siderite -2.59 -5.75 -3.17 -1.055 0.54062E+04 157 sillimanite 5.32 1.75 -3.58 -0.358 0.61043E+04 164 stilbite -7.41 -12.13 -4.72 -0.225 0.80663E+04 169 sudoite 21.22 17.21 -4.01 -0.129 0.68465E+04 178 topaz-H 4.67 1.75 -2.92 -0.266 0.49880E+04 179 tridymite -2.61 -4.05 -1.43 -0.477 0.24439E+04 188 wairakite 4.06 0.01 -4.05 -0.238 0.69166E+04 190 wollastonite 10.48 6.35 -4.13 -0.826 0.70495E+04 191 pseudo-wollastonite 11.02 6.35 -4.67 -0.933 0.79681E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -6.38 -4.83 -0.298 0.82386E+04 197 beidellite-Mg -1.71 -6.64 -4.93 -0.305 0.84153E+04 200 chalcedony -2.79 -4.05 -1.25 -0.417 0.21369E+04 202 montmorillonite-Ca -2.21 -6.70 -4.49 -0.278 0.76612E+04 204 montmorillonite-Mg -2.40 -6.95 -4.55 -0.281 0.77689E+04 206 nontronite-Ca 3.28 0.42 -2.86 -0.185 0.48815E+04 207 nontronite-H 2.60 -1.30 -3.89 -0.261 0.66435E+04 208 nontronite-K 3.40 -0.70 -4.10 -0.263 0.70013E+04 209 nontronite-Mg 3.14 0.17 -2.97 -0.193 0.50698E+04 210 nontronite-Na 3.58 -0.06 -3.64 -0.234 0.62213E+04 215 gypsum -4.92 -9.29 -4.36 -1.091 0.74506E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.70 -3.13 -0.782 0.53414E+04 241 silica-amorphous -2.08 -4.05 -1.97 -0.655 0.33571E+04 243 an20ab80 2.08 -2.78 -4.86 -0.374 0.82986E+04 244 an25ab75 2.71 -2.10 -4.81 -0.370 0.82131E+04 245 an30ab70 3.34 -1.42 -4.76 -0.367 0.81359E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0096000 g New total amount of reactant added: 0.0100000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0100000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2748726E-03 Osmotic coef. = 0.9901 True ionic strength = .2796013E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.29895E-07 -7.5244 0.28718E-07 -7.5418 0.96064E+00 -0.0174 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13252E-03 -3.8777 0.96052E+00 -0.0175 4 SO4-- 0.25338E-04 -4.5962 0.22761E-04 -4.6428 0.89829E+00 -0.0466 5 HCO3- 0.12324E-04 -4.9092 0.11838E-04 -4.9267 0.96055E+00 -0.0175 6 HS- 0.79246E-09 -9.1010 0.76118E-09 -9.1185 0.96053E+00 -0.0175 7 Al+++ 0.23217E-19 -19.6342 0.18645E-19 -19.7294 0.80309E+00 -0.0952 8 H4SiO4 0.93508E-04 -4.0292 0.93508E-04 -4.0292 0.10000E+01 0.0000 9 Ca++ 0.25640E-04 -4.5911 0.23029E-04 -4.6377 0.89816E+00 -0.0466 10 Mg++ 0.68431E-06 -6.1647 0.61456E-06 -6.2114 0.89808E+00 -0.0467 11 Fe++ 0.44164E-08 -8.3549 0.39663E-08 -8.4016 0.89810E+00 -0.0467 12 K+ 0.21224E-05 -5.6732 0.20387E-05 -5.6907 0.96056E+00 -0.0175 13 Na+ 0.17261E-03 -3.7629 0.16579E-03 -3.7804 0.96052E+00 -0.0175 14 Mn++ 0.12380E-06 -6.9073 0.11119E-06 -6.9539 0.89811E+00 -0.0467 15 HPO4-- 0.52976E-08 -8.2759 0.47588E-08 -8.3225 0.89830E+00 -0.0466 16 HSiO3- 0.33074E-05 -5.4805 0.31768E-05 -5.4980 0.96052E+00 -0.0175 17 Ca(HSiO3)+ 0.17064E-08 -8.7679 0.16391E-08 -8.7854 0.96056E+00 -0.0175 18 Mg(HSiO3)+ 0.56673E-10 -10.2466 0.54438E-10 -10.2641 0.96056E+00 -0.0175 19 NaHSiO3,aq 0.83651E-08 -8.0775 0.83651E-08 -8.0775 0.10000E+01 0.0000 20 AlO+ 0.30383E-11 -11.5174 0.29185E-11 -11.5348 0.96056E+00 -0.0175 21 AlOH+2 0.46748E-15 -15.3302 0.41986E-15 -15.3769 0.89813E+00 -0.0467 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.16462E-05 -5.7835 0.15812E-05 -5.8010 0.96049E+00 -0.0175 24 CH4,aq 0.38849E-15 -15.4106 0.38846E-15 -15.4107 0.99991E+00 0.0000 29 CO,aq 0.38836E-16 -16.4108 0.38836E-16 -16.4108 0.10000E+01 0.0000 30 CO2,aq 0.68549E-06 -6.1640 0.68543E-06 -6.1640 0.99991E+00 0.0000 31 CO3-2 0.42429E-07 -7.3723 0.38112E-07 -7.4189 0.89825E+00 -0.0466 32 CaCO3,aq 0.10749E-07 -7.9686 0.10749E-07 -7.9686 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.71510E-08 -8.1456 0.68690E-08 -8.1631 0.96056E+00 -0.0175 34 CaCl+ 0.50625E-08 -8.2956 0.48629E-08 -8.3131 0.96056E+00 -0.0175 35 CaCl2,aq 0.15004E-12 -12.8238 0.15004E-12 -12.8238 0.10000E+01 0.0000 36 CaOH+ 0.58865E-07 -7.2301 0.56543E-07 -7.2476 0.96056E+00 -0.0175 37 CaSO4,aq 0.16332E-06 -6.7870 0.16332E-06 -6.7870 0.10000E+01 0.0000 38 HCl,aq 0.71583E-12 -12.1452 0.71583E-12 -12.1452 0.10000E+01 0.0000 43 FeCl+ 0.85224E-12 -12.0694 0.81863E-12 -12.0869 0.96056E+00 -0.0175 46 FeO,aq 0.19017E-09 -9.7208 0.19017E-09 -9.7208 0.10000E+01 0.0000 47 FeOH+ 0.47667E-08 -8.3218 0.45787E-08 -8.3393 0.96056E+00 -0.0175 48 HFeO2- 0.74154E-10 -10.1299 0.71227E-10 -10.1474 0.96052E+00 -0.0175 49 FeO+ 0.24732E-12 -12.6067 0.23756E-12 -12.6242 0.96056E+00 -0.0175 50 FeOH+2 0.14135E-17 -17.8497 0.12695E-17 -17.8964 0.89813E+00 -0.0467 51 FeO2- 0.58939E-10 -10.2296 0.56612E-10 -10.2471 0.96052E+00 -0.0175 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.22001E-08 -8.6576 0.21999E-08 -8.6576 0.99991E+00 0.0000 54 KCl,aq 0.47835E-11 -11.3203 0.47835E-11 -11.3203 0.10000E+01 0.0000 55 KHSO4,aq 0.35660E-17 -17.4478 0.35660E-17 -17.4478 0.10000E+01 0.0000 56 KOH,aq 0.30947E-10 -10.5094 0.30947E-10 -10.5094 0.10000E+01 0.0000 57 KSO4- 0.74427E-09 -9.1283 0.71489E-09 -9.1458 0.96052E+00 -0.0175 58 MgCO3,aq 0.71682E-10 -10.1446 0.71682E-10 -10.1446 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19460E-09 -9.7109 0.18693E-09 -9.7283 0.96056E+00 -0.0175 60 MgCl+ 0.12265E-09 -9.9113 0.11781E-09 -9.9288 0.96056E+00 -0.0175 61 MgOH+ 0.87028E-08 -8.0603 0.83596E-08 -8.0778 0.96056E+00 -0.0175 63 MnO,aq 0.14232E-09 -9.8467 0.14232E-09 -9.8467 0.10000E+01 0.0000 64 MnOH+ 0.12413E-07 -7.9061 0.11924E-07 -7.9236 0.96056E+00 -0.0175 65 MnO2-2 0.66436E-17 -17.1776 0.59676E-17 -17.2242 0.89825E+00 -0.0466 66 HMnO2- 0.38658E-13 -13.4128 0.37132E-13 -13.4303 0.96052E+00 -0.0175 69 MnCl+ 0.92836E-10 -10.0323 0.89174E-10 -10.0498 0.96056E+00 -0.0175 70 MnSO4,aq 0.71722E-09 -9.1443 0.71722E-09 -9.1443 0.10000E+01 0.0000 71 NaCl,aq 0.71738E-08 -8.1443 0.71738E-08 -8.1443 0.10000E+01 0.0000 72 NaOH,aq 0.25367E-08 -8.5957 0.25367E-08 -8.5957 0.10000E+01 0.0000 74 OH- 0.21746E-04 -4.6626 0.20887E-04 -4.6801 0.96049E+00 -0.0175 79 HPO3-2 0.36812E-19 -19.4340 0.33066E-19 -19.4806 0.89825E+00 -0.0466 82 H3PO4,aq 0.25268E-13 -13.5974 0.25268E-13 -13.5974 0.10000E+01 0.0000 83 H2PO4- 0.24945E-08 -8.6030 0.23960E-08 -8.6205 0.96054E+00 -0.0175 84 PO4-3 0.18001E-12 -12.7447 0.14471E-12 -12.8395 0.80391E+00 -0.0948 87 H2P2O7-2 0.50021E-18 -18.3008 0.44932E-18 -18.3474 0.89825E+00 -0.0466 88 HP2O7-3 0.39948E-17 -17.3985 0.32082E-17 -17.4937 0.80310E+00 -0.0952 89 P2O7-4 0.40115E-19 -19.3967 0.27559E-19 -19.5597 0.68701E+00 -0.1630 90 H2S,aq 0.65685E-10 -10.1825 0.65679E-10 -10.1826 0.99991E+00 0.0000 96 SO2,aq 0.17302E-18 -18.7619 0.17302E-18 -18.7619 0.10000E+01 0.0000 97 SO3-2 0.75983E-14 -14.1193 0.68273E-14 -14.1658 0.89852E+00 -0.0465 98 HSO3- 0.11946E-13 -13.9228 0.11474E-13 -13.9403 0.96052E+00 -0.0175 99 HSO4- 0.63140E-09 -9.1997 0.60651E-09 -9.2172 0.96058E+00 -0.0175 101 S2O3-2 0.19614E-16 -16.7074 0.17619E-16 -16.7540 0.89825E+00 -0.0466 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2989492E-07 -.3113334E-04 -.3137988E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999774E+06 0.0000 3 Cl- 0.1379623E-03 0.1379747E-03 0.4891516E+01 3.6641 4 SO4-- 0.2533830E-04 0.2550319E-04 0.2449827E+01 10.4409 5 HCO3- 0.1232396E-04 0.1307005E-04 0.7974814E+00 2.6151 6 HS- 0.7924606E-09 0.1375333E-08 0.4548408E-04 -1.5767 7 Al+++ 0.2321671E-19 0.1666544E-05 0.4496492E-01 2.8961 8 H4SiO4 0.9350777E-04 0.9682526E-04 0.9306206E+01 -4.0292 9 Ca++ 0.2564010E-04 0.2588695E-04 0.1037476E+01 10.4460 10 Mg++ 0.6843063E-06 0.6934547E-06 0.1685892E-01 8.8722 11 Fe++ 0.4416365E-08 0.9710904E-08 0.5423136E-03 6.6821 12 K+ 0.2122370E-05 0.2123150E-05 0.8301771E-01 1.8512 13 Na+ 0.1726060E-03 0.1726241E-03 0.3968511E+01 3.7614 14 Mn++ 0.1238012E-06 0.1371669E-06 0.7535519E-02 8.1297 15 HPO4-- 0.5297633E-08 0.7792299E-08 0.7478816E-03 6.7612 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1525452E-03 -.3113321E-04 -.1214119E-03 0.0000000E+00 2 H2O 0.5550812E+02 0.5550806E+02 0.6899559E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2578160E-04 0.2550309E-04 0.2785094E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2771341E-06 0.1375328E-08 -.2785094E-06 0.0000000E+00 7 Al+++ 0.3260742E-04 0.1666537E-05 0.3094088E-04 0.0000000E+00 8 H4SiO4 0.1041278E-03 0.9682488E-04 0.7302945E-05 0.0000000E+00 9 Ca++ 0.2597249E-04 0.2588685E-04 0.8563916E-07 0.0000000E+00 10 Mg++ 0.7936508E-05 0.6934520E-06 0.7243056E-05 0.0000000E+00 11 Fe++ 0.7130086E-05 0.9710866E-08 0.7120375E-05 0.0000000E+00 12 K+ 0.2123142E-05 0.2123142E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1726234E-03 0.1726234E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1733860E-06 0.1371664E-06 0.3621959E-07 0.0000000E+00 15 HPO4-- 0.5917577E-07 0.7792269E-08 0.5138350E-07 0.0000000E+00 Chg. balance for solid moles: 0.5850E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0100000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1713E-07 -7.766 0.8604E-05 -5.065 0.2640 0.2734E-05 clinochlore 0.1449E-05 -5.839 0.8052E-03 -3.094 24.71 0.3063E-03 daphnite 0.9785E-06 -6.009 0.6981E-03 -3.156 21.42 0.2116E-03 chlorite-Mn 0.7244E-08 -8.140 0.5136E-05 -5.289 0.1576 0.1637E-05 diaspore 0.2607E-04 -4.584 0.1564E-02 -2.806 47.99 0.4656E-03 hematite 0.1114E-05 -5.953 0.1779E-03 -3.750 5.459 0.3372E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5951E+00 0.5951E+00 1.0000 -0.225 daphnite 0.4019E+00 0.4019E+00 1.0000 -0.396 chlorite-Mn 0.2976E-02 0.2976E-02 1.0000 -2.526 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.003259 g Volume = 0.001022 cm3 Porosity: 99.8983% V(tot) - V(min): 0.10030E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0100000 g log = -2.0000 Original solution: 1000.0103000 g Original solution / Rock added: 100001.03 (Water/Rock Ratio), log = 5.0000 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.7404E-04 1.0073 0.7846E-04 0.7789E-04 CH4,gas 0.5765E-12 1.0129 0.6143E-12 0.6065E-12 H2,gas 0.2867E-05 1.0006 0.3017E-05 0.3016E-05 H2S,gas 0.1828E-08 0.9959 0.1916E-08 0.1923E-08 S2,gas 0.1435E-25 1.0000 0.1510E-25 0.1510E-25 CO,gas 0.5829E-13 1.0000 0.6132E-13 0.6132E-13 SO3,gas 0.6671E-35 1.0000 0.7018E-35 0.7018E-35 SO2,gas 0.7615E-18 1.0000 0.8011E-18 0.8011E-18 HCl,gas 0.1201E-14 1.0000 0.1264E-14 0.1264E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.47 -6.11 -2.035 0.10425E+05 -4.105 3 CH4,gas 4.81 -9.40 -14.21 -3.553 0.24266E+05 -12.212 4 H2,gas 8.29 0.77 -7.52 -4.297 0.12841E+05 -5.520 5 H2S,gas -5.94 -16.66 -10.72 -5.359 0.18300E+05 -8.718 6 S2,gas -7.03 -34.85 -27.82 -4.280 0.47504E+05 -25.821 7 CO,gas 3.51 -11.70 -15.21 -4.681 0.25975E+05 -13.212 8 SO3,gas 17.43 -19.73 -37.15 -9.288 0.63439E+05 -35.154 9 SO2,gas 1.14 -18.96 -20.10 -5.359 0.34314E+05 -18.096 10 HCl,gas 5.48 -11.42 -16.90 -8.449 0.28853E+05 -14.898 20 analcite 3.37 -1.40 -4.77 -0.530 0.81471E+04 21 andalusite 5.06 1.76 -3.30 -0.330 0.56335E+04 24 anhydrite -5.28 -9.28 -4.00 -2.000 0.68312E+04 29 anorthite 12.80 8.18 -4.62 -0.355 0.78849E+04 35 aragonite 0.99 -2.02 -3.01 -1.003 0.51375E+04 36 brucite 12.58 8.87 -3.70 -0.741 0.63251E+04 37 calcite 0.83 -2.02 -2.86 -0.952 0.48762E+04 40 carpholite-Mg 8.65 6.61 -2.04 -0.136 0.34905E+04 41 carpholite-Fe 6.78 4.42 -2.37 -0.158 0.40415E+04 50 chloritoid-Mg 13.26 10.64 -2.63 -0.175 0.44838E+04 51 chloritoid-Fe 9.24 8.45 -0.79 -0.053 0.13550E+04 52 chloritoid-Mn 11.46 9.89 -1.57 -0.105 0.26815E+04 54 coesite -2.37 -4.03 -1.66 -0.553 0.28341E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.03 -1.48 -0.493 0.25270E+04 67 diopside 16.22 11.26 -4.96 -0.496 0.84615E+04 75 epidote 24.78 20.90 -3.88 -0.188 0.66246E+04 78 fayalite 14.08 9.33 -4.74 -0.678 0.81002E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.99 -4.21 -0.351 0.71822E+04 92 hercynite 17.34 12.47 -4.87 -0.325 0.83158E+04 98 kaolinite -1.27 -2.27 -0.99 -0.090 0.16955E+04 99 kyanite 4.93 1.76 -3.17 -0.317 0.54103E+04 101 laumontite 2.97 0.12 -2.85 -0.190 0.48715E+04 102 lawsonite 9.68 8.18 -1.50 -0.100 0.25587E+04 105 lizardite 23.29 18.56 -4.73 -0.394 0.80746E+04 106 magnesite 0.71 -3.60 -4.31 -1.435 0.73517E+04 107 magnetite 20.13 19.28 -0.85 -0.070 0.14566E+04 110 magnesioferrite 26.26 21.47 -4.79 -0.391 0.81744E+04 113 margarite 17.45 13.97 -3.48 -0.139 0.59417E+04 116 microcline -2.43 -7.34 -4.91 -0.378 0.83809E+04 120 muscovite 2.68 -1.55 -4.23 -0.249 0.72178E+04 121 paragonite 4.34 0.36 -3.97 -0.234 0.67862E+04 128 periclase-Fe 11.64 6.68 -4.96 -1.239 0.84641E+04 136 prehnite 19.47 14.60 -4.87 -0.286 0.83149E+04 137 prehnite-Fe 22.59 18.00 -4.59 -0.276 0.78329E+04 144 pyrrhotiteFe0.875 -6.00 -10.91 -4.91 -1.805 0.83796E+04 145 pyroxmangite 7.42 4.10 -3.32 -0.663 0.56610E+04 146 pyrophyllite -6.10 -10.32 -4.23 -0.264 0.72165E+04 147 quartz -2.98 -4.03 -1.05 -0.349 0.17880E+04 152 rhodochrosite -0.96 -4.34 -3.38 -1.127 0.57718E+04 153 rhodonite 7.46 4.10 -3.36 -0.672 0.57403E+04 156 siderite -2.59 -5.79 -3.20 -1.066 0.54619E+04 157 sillimanite 5.32 1.76 -3.56 -0.356 0.60757E+04 164 stilbite -7.41 -11.97 -4.56 -0.217 0.77862E+04 169 sudoite 21.22 17.24 -3.97 -0.128 0.67869E+04 178 topaz-H 4.67 1.76 -2.90 -0.264 0.49594E+04 179 tridymite -2.61 -4.03 -1.41 -0.472 0.24153E+04 188 wairakite 4.06 0.12 -3.94 -0.232 0.67223E+04 190 wollastonite 10.48 6.42 -4.07 -0.813 0.69409E+04 191 pseudo-wollastonite 11.02 6.42 -4.60 -0.921 0.78595E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -6.32 -4.76 -0.294 0.81205E+04 197 beidellite-Mg -1.71 -6.58 -4.87 -0.301 0.83125E+04 200 chalcedony -2.79 -4.03 -1.23 -0.412 0.21083E+04 202 montmorillonite-Ca -2.21 -6.63 -4.41 -0.273 0.75380E+04 204 montmorillonite-Mg -2.40 -6.89 -4.49 -0.278 0.76610E+04 206 nontronite-Ca 3.28 0.49 -2.79 -0.181 0.47634E+04 207 nontronite-H 2.60 -1.23 -3.83 -0.257 0.65386E+04 208 nontronite-K 3.40 -0.62 -4.03 -0.258 0.68753E+04 209 nontronite-Mg 3.14 0.23 -2.91 -0.189 0.49670E+04 210 nontronite-Na 3.58 0.01 -3.58 -0.229 0.61046E+04 215 gypsum -4.92 -9.28 -4.36 -1.089 0.74380E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.68 -3.14 -0.786 0.53651E+04 241 silica-amorphous -2.08 -4.03 -1.95 -0.650 0.33285E+04 243 an20ab80 2.08 -2.71 -4.79 -0.368 0.81740E+04 244 an25ab75 2.71 -2.03 -4.74 -0.364 0.80877E+04 245 an30ab70 3.34 -1.35 -4.69 -0.361 0.80098E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0100000 g New total amount of reactant added: 0.0104000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0104000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2762684E-03 Osmotic coef. = 0.9901 True ionic strength = .2813258E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.28620E-07 -7.5433 0.27492E-07 -7.5608 0.96058E+00 -0.0175 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13251E-03 -3.8778 0.96046E+00 -0.0175 4 SO4-- 0.25336E-04 -4.5963 0.22753E-04 -4.6430 0.89805E+00 -0.0467 5 HCO3- 0.12349E-04 -4.9084 0.11861E-04 -4.9259 0.96049E+00 -0.0175 6 HS- 0.59766E-09 -9.2235 0.57403E-09 -9.2411 0.96046E+00 -0.0175 7 Al+++ 0.20379E-19 -19.6908 0.16356E-19 -19.7863 0.80261E+00 -0.0955 8 H4SiO4 0.97039E-04 -4.0131 0.97039E-04 -4.0131 0.10000E+01 0.0000 9 Ca++ 0.26087E-04 -4.5836 0.23424E-04 -4.6303 0.89792E+00 -0.0468 10 Mg++ 0.61621E-06 -6.2103 0.55326E-06 -6.2571 0.89783E+00 -0.0468 11 Fe++ 0.39295E-08 -8.4057 0.35281E-08 -8.4525 0.89785E+00 -0.0468 12 K+ 0.22073E-05 -5.6561 0.21201E-05 -5.6737 0.96049E+00 -0.0175 13 Na+ 0.17311E-03 -3.7617 0.16626E-03 -3.7792 0.96046E+00 -0.0175 14 Mn++ 0.12396E-06 -6.9067 0.11130E-06 -6.9535 0.89787E+00 -0.0468 15 HPO4-- 0.48595E-08 -8.3134 0.43641E-08 -8.3601 0.89805E+00 -0.0467 16 HSiO3- 0.35857E-05 -5.4454 0.34439E-05 -5.4630 0.96046E+00 -0.0175 17 Ca(HSiO3)+ 0.18818E-08 -8.7254 0.18074E-08 -8.7429 0.96050E+00 -0.0175 18 Mg(HSiO3)+ 0.55313E-10 -10.2572 0.53128E-10 -10.2747 0.96050E+00 -0.0175 19 NaHSiO3,aq 0.90941E-08 -8.0412 0.90941E-08 -8.0412 0.10000E+01 0.0000 20 AlO+ 0.29087E-11 -11.5363 0.27938E-11 -11.5538 0.96050E+00 -0.0175 21 AlOH+2 0.42851E-15 -15.3680 0.38475E-15 -15.4148 0.89789E+00 -0.0468 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.17198E-05 -5.7645 0.16517E-05 -5.7821 0.96042E+00 -0.0175 24 CH4,aq 0.29366E-15 -15.5322 0.29364E-15 -15.5322 0.99991E+00 0.0000 29 CO,aq 0.35097E-16 -16.4547 0.35097E-16 -16.4547 0.10000E+01 0.0000 30 CO2,aq 0.65751E-06 -6.1821 0.65745E-06 -6.1821 0.99991E+00 0.0000 31 CO3-2 0.44422E-07 -7.3524 0.39892E-07 -7.3991 0.89801E+00 -0.0467 32 CaCO3,aq 0.11445E-07 -7.9414 0.11445E-07 -7.9414 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.72887E-08 -8.1373 0.70008E-08 -8.1549 0.96050E+00 -0.0175 34 CaCl+ 0.51494E-08 -8.2882 0.49460E-08 -8.3057 0.96050E+00 -0.0175 35 CaCl2,aq 0.15260E-12 -12.8165 0.15260E-12 -12.8165 0.10000E+01 0.0000 36 CaOH+ 0.62552E-07 -7.2038 0.60081E-07 -7.2213 0.96050E+00 -0.0175 37 CaSO4,aq 0.16606E-06 -6.7797 0.16606E-06 -6.7797 0.10000E+01 0.0000 38 HCl,aq 0.68520E-12 -12.1642 0.68520E-12 -12.1642 0.10000E+01 0.0000 43 FeCl+ 0.75807E-12 -12.1203 0.72813E-12 -12.1378 0.96050E+00 -0.0175 46 FeO,aq 0.18460E-09 -9.7338 0.18460E-09 -9.7338 0.10000E+01 0.0000 47 FeOH+ 0.44295E-08 -8.3536 0.42546E-08 -8.3711 0.96050E+00 -0.0175 48 HFeO2- 0.75196E-10 -10.1238 0.72223E-10 -10.1413 0.96046E+00 -0.0175 49 FeO+ 0.23677E-12 -12.6257 0.22741E-12 -12.6432 0.96050E+00 -0.0175 50 FeOH+2 0.12957E-17 -17.8875 0.11634E-17 -17.9343 0.89789E+00 -0.0468 51 FeO2- 0.61573E-10 -10.2106 0.59139E-10 -10.2281 0.96046E+00 -0.0175 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.20729E-08 -8.6834 0.20727E-08 -8.6835 0.99991E+00 0.0000 54 KCl,aq 0.49742E-11 -11.3033 0.49742E-11 -11.3033 0.10000E+01 0.0000 55 KHSO4,aq 0.35487E-17 -17.4499 0.35487E-17 -17.4499 0.10000E+01 0.0000 56 KOH,aq 0.33619E-10 -10.4734 0.33619E-10 -10.4734 0.10000E+01 0.0000 57 KSO4- 0.77376E-09 -9.1114 0.74317E-09 -9.1289 0.96046E+00 -0.0175 58 MgCO3,aq 0.67544E-10 -10.1704 0.67544E-10 -10.1704 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.17555E-09 -9.7556 0.16861E-09 -9.7731 0.96050E+00 -0.0175 60 MgCl+ 0.11041E-09 -9.9570 0.10605E-09 -9.9745 0.96050E+00 -0.0175 61 MgOH+ 0.81849E-08 -8.0870 0.78616E-08 -8.1045 0.96050E+00 -0.0175 63 MnO,aq 0.15545E-09 -9.8084 0.15545E-09 -9.8084 0.10000E+01 0.0000 64 MnOH+ 0.12981E-07 -7.8867 0.12468E-07 -7.9042 0.96050E+00 -0.0175 65 MnO2-2 0.79211E-17 -17.1012 0.71132E-17 -17.1479 0.89801E+00 -0.0467 66 HMnO2- 0.44113E-13 -13.3554 0.42369E-13 -13.3730 0.96046E+00 -0.0175 69 MnCl+ 0.92927E-10 -10.0319 0.89256E-10 -10.0494 0.96050E+00 -0.0175 70 MnSO4,aq 0.71766E-09 -9.1441 0.71766E-09 -9.1441 0.10000E+01 0.0000 71 NaCl,aq 0.71936E-08 -8.1431 0.71936E-08 -8.1431 0.10000E+01 0.0000 72 NaOH,aq 0.26574E-08 -8.5755 0.26574E-08 -8.5755 0.10000E+01 0.0000 74 OH- 0.22718E-04 -4.6436 0.21819E-04 -4.6612 0.96042E+00 -0.0175 79 HPO3-2 0.31816E-19 -19.4974 0.28571E-19 -19.5441 0.89801E+00 -0.0467 82 H3PO4,aq 0.21234E-13 -13.6730 0.21234E-13 -13.6730 0.10000E+01 0.0000 83 H2PO4- 0.21900E-08 -8.6596 0.21034E-08 -8.6771 0.96048E+00 -0.0175 84 PO4-3 0.17255E-12 -12.7631 0.13863E-12 -12.8581 0.80343E+00 -0.0951 87 H2P2O7-2 0.38560E-18 -18.4139 0.34628E-18 -18.4606 0.89801E+00 -0.0467 88 HP2O7-3 0.32180E-17 -17.4924 0.25828E-17 -17.5879 0.80261E+00 -0.0955 89 P2O7-4 0.33772E-19 -19.4714 0.23177E-19 -19.6349 0.68628E+00 -0.1635 90 H2S,aq 0.47419E-10 -10.3240 0.47415E-10 -10.3241 0.99991E+00 0.0000 96 SO2,aq 0.14933E-18 -18.8258 0.14933E-18 -18.8258 0.10000E+01 0.0000 97 SO3-2 0.71584E-14 -14.1452 0.64303E-14 -14.1918 0.89828E+00 -0.0466 98 HSO3- 0.10771E-13 -13.9677 0.10345E-13 -13.9853 0.96046E+00 -0.0175 99 HSO4- 0.60424E-09 -9.2188 0.58039E-09 -9.2363 0.96052E+00 -0.0175 101 S2O3-2 0.14159E-16 -16.8490 0.12715E-16 -16.8957 0.89801E+00 -0.0467 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2861976E-07 -.3271462E-04 -.3297367E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999770E+06 0.0000 3 Cl- 0.1379622E-03 0.1379747E-03 0.4891515E+01 3.6830 4 SO4-- 0.2533577E-04 0.2550344E-04 0.2449850E+01 10.4786 5 HCO3- 0.1234915E-04 0.1307005E-04 0.7974812E+00 2.6349 6 HS- 0.5976600E-09 0.1130146E-08 0.3737541E-04 -1.6803 7 Al+++ 0.2037897E-19 0.1740122E-05 0.4695011E-01 2.8961 8 H4SiO4 0.9703875E-04 0.1006354E-03 0.9672411E+01 -4.0131 9 Ca++ 0.2608745E-04 0.2634183E-04 0.1055705E+01 10.4913 10 Mg++ 0.6162132E-06 0.6248069E-06 0.1518998E-01 8.8645 11 Fe++ 0.3929453E-08 0.8884815E-08 0.4961797E-03 6.6691 12 K+ 0.2207265E-05 0.2208077E-05 0.8633840E-01 1.8871 13 Na+ 0.1731073E-03 0.1731262E-03 0.3980053E+01 3.7816 14 Mn++ 0.1239560E-06 0.1379029E-06 0.7575950E-02 8.1681 15 HPO4-- 0.4859512E-08 0.7049684E-08 0.6766073E-03 6.7615 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1591686E-03 -.3271448E-04 -.1264541E-03 0.0000000E+00 2 H2O 0.5550812E+02 0.5550805E+02 0.7178143E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2579269E-04 0.2550334E-04 0.2893496E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2882195E-06 0.1130142E-08 -.2893496E-06 0.0000000E+00 7 Al+++ 0.3391171E-04 0.1740115E-05 0.3217160E-04 0.0000000E+00 8 H4SiO4 0.1082929E-03 0.1006350E-03 0.7657914E-05 0.0000000E+00 9 Ca++ 0.2643254E-04 0.2634172E-04 0.9082190E-07 0.0000000E+00 10 Mg++ 0.8253968E-05 0.6248044E-06 0.7629164E-05 0.0000000E+00 11 Fe++ 0.7415289E-05 0.8884779E-08 0.7406405E-05 0.0000000E+00 12 K+ 0.2208068E-05 0.2208068E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1731255E-03 0.1731255E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1803214E-06 0.1379023E-06 0.4241905E-07 0.0000000E+00 15 HPO4-- 0.6154280E-07 0.7049656E-08 0.5449314E-07 0.0000000E+00 Chg. balance for solid moles: -.1815E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0104000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1816E-07 -7.741 0.9124E-05 -5.040 0.2685 0.2899E-05 clinochlore 0.1526E-05 -5.816 0.8481E-03 -3.072 24.96 0.3226E-03 daphnite 0.1018E-05 -5.992 0.7266E-03 -3.139 21.38 0.2202E-03 chlorite-Mn 0.8484E-08 -8.071 0.6015E-05 -5.221 0.1770 0.1917E-05 diaspore 0.2707E-04 -4.568 0.1624E-02 -2.789 47.78 0.4834E-03 hematite 0.1157E-05 -5.937 0.1848E-03 -3.733 5.439 0.3503E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5977E+00 0.5977E+00 1.0000 -0.223 daphnite 0.3989E+00 0.3989E+00 1.0000 -0.399 chlorite-Mn 0.3324E-02 0.3324E-02 1.0000 -2.478 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.003398 g Volume = 0.001066 cm3 Porosity: 99.8938% V(tot) - V(min): 0.10031E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0104000 g log = -1.9830 Original solution: 1000.0103000 g Original solution / Rock added: 96154.84 (Water/Rock Ratio), log = 4.9830 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.7102E-04 1.0073 0.7526E-04 0.7471E-04 CH4,gas 0.4358E-12 1.0129 0.4644E-12 0.4584E-12 H2,gas 0.2701E-05 1.0006 0.2843E-05 0.2841E-05 H2S,gas 0.1320E-08 0.9959 0.1383E-08 0.1389E-08 S2,gas 0.8425E-26 1.0000 0.8863E-26 0.8863E-26 CO,gas 0.5268E-13 1.0000 0.5542E-13 0.5542E-13 SO3,gas 0.6111E-35 1.0000 0.6429E-35 0.6429E-35 SO2,gas 0.6572E-18 1.0000 0.6914E-18 0.6914E-18 HCl,gas 0.1150E-14 1.0000 0.1210E-14 0.1210E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.49 -6.12 -2.041 0.10456E+05 -4.123 3 CH4,gas 4.81 -9.52 -14.33 -3.583 0.24473E+05 -12.333 4 H2,gas 8.29 0.74 -7.55 -4.312 0.12885E+05 -5.546 5 H2S,gas -5.94 -16.80 -10.86 -5.430 0.18542E+05 -8.859 6 S2,gas -7.03 -35.09 -28.05 -4.316 0.47899E+05 -26.052 7 CO,gas 3.51 -11.75 -15.26 -4.694 0.26050E+05 -13.256 8 SO3,gas 17.43 -19.76 -37.19 -9.298 0.63504E+05 -35.192 9 SO2,gas 1.14 -19.02 -20.16 -5.376 0.34423E+05 -18.160 10 HCl,gas 5.48 -11.44 -16.92 -8.459 0.28886E+05 -14.917 20 analcite 3.37 -1.35 -4.72 -0.524 0.80577E+04 21 andalusite 5.06 1.78 -3.28 -0.328 0.56061E+04 24 anhydrite -5.28 -9.27 -3.99 -1.997 0.68189E+04 29 anorthite 12.80 8.26 -4.54 -0.349 0.77525E+04 35 aragonite 0.99 -2.00 -2.98 -0.994 0.50910E+04 36 brucite 12.58 8.86 -3.71 -0.742 0.63383E+04 37 calcite 0.83 -2.00 -2.83 -0.943 0.48297E+04 40 carpholite-Mg 8.65 6.63 -2.02 -0.135 0.34487E+04 41 carpholite-Fe 6.78 4.44 -2.35 -0.157 0.40086E+04 50 chloritoid-Mg 13.26 10.64 -2.62 -0.175 0.44695E+04 51 chloritoid-Fe 9.24 8.45 -0.79 -0.053 0.13496E+04 52 chloritoid-Mn 11.46 9.95 -1.52 -0.101 0.25885E+04 54 coesite -2.37 -4.01 -1.64 -0.548 0.28066E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.01 -1.46 -0.488 0.24995E+04 67 diopside 16.22 11.33 -4.89 -0.489 0.83423E+04 75 epidote 24.78 21.03 -3.74 -0.181 0.63874E+04 78 fayalite 14.08 9.33 -4.75 -0.679 0.81169E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.98 -4.21 -0.351 0.71934E+04 92 hercynite 17.34 12.46 -4.88 -0.326 0.83379E+04 98 kaolinite -1.27 -2.23 -0.96 -0.087 0.16405E+04 99 kyanite 4.93 1.78 -3.15 -0.315 0.53828E+04 101 laumontite 2.97 0.23 -2.74 -0.183 0.46841E+04 102 lawsonite 9.68 8.26 -1.42 -0.095 0.24264E+04 105 lizardite 23.29 18.57 -4.72 -0.393 0.80592E+04 106 magnesite 0.71 -3.62 -4.33 -1.444 0.73958E+04 107 magnetite 20.13 19.27 -0.87 -0.071 0.14787E+04 110 magnesioferrite 26.26 21.46 -4.80 -0.391 0.81875E+04 113 margarite 17.45 14.05 -3.40 -0.136 0.58093E+04 116 microcline -2.43 -7.26 -4.82 -0.371 0.82371E+04 120 muscovite 2.68 -1.46 -4.14 -0.244 0.70740E+04 121 paragonite 4.34 0.43 -3.91 -0.230 0.66693E+04 128 periclase-Fe 11.64 6.67 -4.97 -1.242 0.84861E+04 136 prehnite 19.47 14.74 -4.73 -0.278 0.80777E+04 137 prehnite-Fe 22.59 18.14 -4.45 -0.268 0.75957E+04 145 pyroxmangite 7.42 4.16 -3.26 -0.652 0.55681E+04 146 pyrophyllite -6.10 -10.26 -4.16 -0.260 0.71065E+04 147 quartz -2.98 -4.01 -1.03 -0.344 0.17605E+04 152 rhodochrosite -0.96 -4.32 -3.36 -1.120 0.57372E+04 153 rhodonite 7.46 4.16 -3.31 -0.661 0.56473E+04 156 siderite -2.59 -5.82 -3.23 -1.077 0.55149E+04 157 sillimanite 5.32 1.78 -3.54 -0.354 0.60482E+04 164 stilbite -7.41 -11.81 -4.40 -0.210 0.75164E+04 169 sudoite 21.22 17.27 -3.94 -0.127 0.67307E+04 178 topaz-H 4.67 1.78 -2.89 -0.263 0.49319E+04 179 tridymite -2.61 -4.01 -1.40 -0.466 0.23878E+04 188 wairakite 4.06 0.23 -3.83 -0.225 0.65350E+04 190 wollastonite 10.48 6.48 -4.00 -0.801 0.68360E+04 191 pseudo-wollastonite 11.02 6.48 -4.54 -0.908 0.77547E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -6.25 -4.69 -0.290 0.80068E+04 197 beidellite-Mg -1.71 -6.52 -4.81 -0.298 0.82138E+04 200 chalcedony -2.79 -4.01 -1.22 -0.406 0.20808E+04 202 montmorillonite-Ca -2.21 -6.56 -4.35 -0.269 0.74196E+04 204 montmorillonite-Mg -2.40 -6.83 -4.43 -0.274 0.75576E+04 206 nontronite-Ca 3.28 0.56 -2.72 -0.177 0.46498E+04 207 nontronite-H 2.60 -1.17 -3.77 -0.253 0.64377E+04 208 nontronite-K 3.40 -0.55 -3.96 -0.254 0.67542E+04 209 nontronite-Mg 3.14 0.29 -2.85 -0.185 0.48683E+04 210 nontronite-Na 3.58 0.07 -3.51 -0.225 0.59923E+04 215 gypsum -4.92 -9.27 -4.35 -1.087 0.74256E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.67 -3.16 -0.789 0.53872E+04 241 silica-amorphous -2.08 -4.01 -1.93 -0.644 0.33010E+04 243 an20ab80 2.08 -2.64 -4.72 -0.363 0.80540E+04 244 an25ab75 2.71 -1.96 -4.67 -0.359 0.79670E+04 245 an30ab70 3.34 -1.28 -4.62 -0.355 0.78882E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0104000 g New total amount of reactant added: 0.0108000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0108000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2776830E-03 Osmotic coef. = 0.9900 True ionic strength = .2830749E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.27442E-07 -7.5616 0.26359E-07 -7.5791 0.96052E+00 -0.0175 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13250E-03 -3.8778 0.96039E+00 -0.0176 4 SO4-- 0.25333E-04 -4.5963 0.22744E-04 -4.6431 0.89781E+00 -0.0468 5 HCO3- 0.12372E-04 -4.9076 0.11883E-04 -4.9251 0.96042E+00 -0.0175 6 HS- 0.45867E-09 -9.3385 0.44051E-09 -9.3560 0.96040E+00 -0.0175 7 Al+++ 0.17973E-19 -19.7454 0.14416E-19 -19.8411 0.80211E+00 -0.0958 8 H4SiO4 0.10056E-03 -3.9976 0.10056E-03 -3.9976 0.10000E+01 0.0000 9 Ca++ 0.26535E-04 -4.5762 0.23820E-04 -4.6231 0.89767E+00 -0.0469 10 Mg++ 0.55665E-06 -6.2544 0.49964E-06 -6.3013 0.89759E+00 -0.0469 11 Fe++ 0.35142E-08 -8.4542 0.31544E-08 -8.5011 0.89761E+00 -0.0469 12 K+ 0.22922E-05 -5.6398 0.22015E-05 -5.6573 0.96043E+00 -0.0175 13 Na+ 0.17361E-03 -3.7604 0.16673E-03 -3.7780 0.96039E+00 -0.0176 14 Mn++ 0.12363E-06 -6.9079 0.11097E-06 -6.9548 0.89762E+00 -0.0469 15 HPO4-- 0.44692E-08 -8.3498 0.40125E-08 -8.3966 0.89781E+00 -0.0468 16 HSiO3- 0.38759E-05 -5.4116 0.37223E-05 -5.4292 0.96039E+00 -0.0176 17 Ca(HSiO3)+ 0.20684E-08 -8.6844 0.19866E-08 -8.7019 0.96043E+00 -0.0175 18 Mg(HSiO3)+ 0.53996E-10 -10.2676 0.51859E-10 -10.2852 0.96043E+00 -0.0175 19 NaHSiO3,aq 0.98572E-08 -8.0062 0.98572E-08 -8.0062 0.10000E+01 0.0000 20 AlO+ 0.27891E-11 -11.5545 0.26787E-11 -11.5721 0.96043E+00 -0.0175 21 AlOH+2 0.39403E-15 -15.4045 0.35370E-15 -15.4514 0.89764E+00 -0.0469 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.17938E-05 -5.7462 0.17227E-05 -5.7638 0.96036E+00 -0.0176 24 CH4,aq 0.22585E-15 -15.6462 0.22583E-15 -15.6462 0.99991E+00 0.0000 29 CO,aq 0.31889E-16 -16.4964 0.31889E-16 -16.4964 0.10000E+01 0.0000 30 CO2,aq 0.63155E-06 -6.1996 0.63149E-06 -6.1996 0.99991E+00 0.0000 31 CO3-2 0.46428E-07 -7.3332 0.41681E-07 -7.3801 0.89777E+00 -0.0468 32 CaCO3,aq 0.12160E-07 -7.9151 0.12160E-07 -7.9151 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.74256E-08 -8.1293 0.71318E-08 -8.1468 0.96043E+00 -0.0175 34 CaCl+ 0.52363E-08 -8.2810 0.50291E-08 -8.2985 0.96043E+00 -0.0175 35 CaCl2,aq 0.15515E-12 -12.8092 0.15515E-12 -12.8092 0.10000E+01 0.0000 36 CaOH+ 0.66346E-07 -7.1782 0.63721E-07 -7.1957 0.96043E+00 -0.0175 37 CaSO4,aq 0.16880E-06 -6.7726 0.16880E-06 -6.7726 0.10000E+01 0.0000 38 HCl,aq 0.65692E-12 -12.1825 0.65692E-12 -12.1825 0.10000E+01 0.0000 43 FeCl+ 0.67778E-12 -12.1689 0.65097E-12 -12.1864 0.96043E+00 -0.0175 46 FeO,aq 0.17954E-09 -9.7458 0.17954E-09 -9.7458 0.10000E+01 0.0000 47 FeOH+ 0.41309E-08 -8.3840 0.39674E-08 -8.4015 0.96043E+00 -0.0175 48 HFeO2- 0.76284E-10 -10.1176 0.73263E-10 -10.1351 0.96039E+00 -0.0176 49 FeO+ 0.22703E-12 -12.6439 0.21804E-12 -12.6615 0.96043E+00 -0.0175 50 FeOH+2 0.11914E-17 -17.9239 0.10695E-17 -17.9708 0.89764E+00 -0.0469 51 FeO2- 0.64224E-10 -10.1923 0.61680E-10 -10.2099 0.96039E+00 -0.0176 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.19608E-08 -8.7076 0.19607E-08 -8.7076 0.99991E+00 0.0000 54 KCl,aq 0.51648E-11 -11.2869 0.51648E-11 -11.2869 0.10000E+01 0.0000 55 KHSO4,aq 0.35317E-17 -17.4520 0.35317E-17 -17.4520 0.10000E+01 0.0000 56 KOH,aq 0.36410E-10 -10.4388 0.36410E-10 -10.4388 0.10000E+01 0.0000 57 KSO4- 0.80322E-09 -9.0952 0.77141E-09 -9.1127 0.96039E+00 -0.0176 58 MgCO3,aq 0.63735E-10 -10.1956 0.63735E-10 -10.1956 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15883E-09 -9.7991 0.15255E-09 -9.8166 0.96043E+00 -0.0175 60 MgCl+ 0.99713E-10 -10.0012 0.95767E-10 -10.0188 0.96043E+00 -0.0175 61 MgOH+ 0.77099E-08 -8.1129 0.74049E-08 -8.1305 0.96043E+00 -0.0175 63 MnO,aq 0.16861E-09 -9.7731 0.16861E-09 -9.7731 0.10000E+01 0.0000 64 MnOH+ 0.13500E-07 -7.8697 0.12966E-07 -7.8872 0.96043E+00 -0.0175 65 MnO2-2 0.93485E-17 -17.0293 0.83928E-17 -17.0761 0.89777E+00 -0.0468 66 HMnO2- 0.49907E-13 -13.3018 0.47930E-13 -13.3194 0.96039E+00 -0.0176 69 MnCl+ 0.92656E-10 -10.0331 0.88990E-10 -10.0507 0.96043E+00 -0.0175 70 MnSO4,aq 0.71530E-09 -9.1455 0.71530E-09 -9.1455 0.10000E+01 0.0000 71 NaCl,aq 0.72135E-08 -8.1419 0.72135E-08 -8.1419 0.10000E+01 0.0000 72 NaOH,aq 0.27795E-08 -8.5560 0.27795E-08 -8.5560 0.10000E+01 0.0000 74 OH- 0.23696E-04 -4.6253 0.22757E-04 -4.6429 0.96036E+00 -0.0176 79 HPO3-2 0.27679E-19 -19.5579 0.24849E-19 -19.6047 0.89777E+00 -0.0468 82 H3PO4,aq 0.17948E-13 -13.7460 0.17948E-13 -13.7460 0.10000E+01 0.0000 83 H2PO4- 0.19307E-08 -8.7143 0.18543E-08 -8.7318 0.96041E+00 -0.0175 84 PO4-3 0.16557E-12 -12.7810 0.13294E-12 -12.8763 0.80294E+00 -0.0953 87 H2P2O7-2 0.29974E-18 -18.5233 0.26910E-18 -18.5701 0.89777E+00 -0.0468 88 HP2O7-3 0.26098E-17 -17.5834 0.20934E-17 -17.6791 0.80212E+00 -0.0958 89 P2O7-4 0.28581E-19 -19.5439 0.19593E-19 -19.7079 0.68553E+00 -0.1640 90 H2S,aq 0.34890E-10 -10.4573 0.34887E-10 -10.4573 0.99991E+00 0.0000 96 SO2,aq 0.12981E-18 -18.8867 0.12981E-18 -18.8867 0.10000E+01 0.0000 97 SO3-2 0.67707E-14 -14.1694 0.60804E-14 -14.2161 0.89804E+00 -0.0467 98 HSO3- 0.97661E-14 -14.0103 0.93793E-14 -14.0278 0.96039E+00 -0.0176 99 HSO4- 0.57917E-09 -9.2372 0.55626E-09 -9.2547 0.96045E+00 -0.0175 101 S2O3-2 0.10416E-16 -16.9823 0.93515E-17 -17.0291 0.89777E+00 -0.0468 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2744222E-07 -.3431378E-04 -.3458548E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999766E+06 0.0000 3 Cl- 0.1379621E-03 0.1379748E-03 0.4891514E+01 3.7013 4 SO4-- 0.2533319E-04 0.2550363E-04 0.2449866E+01 10.5150 5 HCO3- 0.1237227E-04 0.1307005E-04 0.7974810E+00 2.6540 6 HS- 0.4586720E-09 0.9502840E-09 0.3142711E-04 -1.7770 7 Al+++ 0.1797297E-19 0.1814161E-05 0.4894774E-01 2.8961 8 H4SiO4 0.1005630E-03 0.1044508E-03 0.1003912E+02 -3.9976 9 Ca++ 0.2653483E-04 0.2679686E-04 0.1073942E+01 10.5351 10 Mg++ 0.5566494E-06 0.5647357E-06 0.1372956E-01 8.8568 11 Fe++ 0.3514232E-08 0.8169539E-08 0.4562344E-03 6.6571 12 K+ 0.2292158E-05 0.2293003E-05 0.8965908E-01 1.9218 13 Na+ 0.1736085E-03 0.1736284E-03 0.3991595E+01 3.8011 14 Mn++ 0.1236289E-06 0.1381057E-06 0.7587087E-02 8.2034 15 HPO4-- 0.4469218E-08 0.6400100E-08 0.6142620E-03 6.7616 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1657920E-03 -.3431363E-04 -.1314783E-03 0.0000000E+00 2 H2O 0.5550811E+02 0.5550804E+02 0.7456337E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2580377E-04 0.2550352E-04 0.3002551E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2993048E-06 0.9502800E-09 -.3002551E-06 0.0000000E+00 7 Al+++ 0.3521601E-04 0.1814154E-05 0.3340186E-04 0.0000000E+00 8 H4SiO4 0.1124581E-03 0.1044504E-03 0.8007678E-05 0.0000000E+00 9 Ca++ 0.2689260E-04 0.2679675E-04 0.9584959E-07 0.0000000E+00 10 Mg++ 0.8571429E-05 0.5647333E-06 0.8006695E-05 0.0000000E+00 11 Fe++ 0.7700493E-05 0.8169504E-08 0.7692323E-05 0.0000000E+00 12 K+ 0.2292994E-05 0.2292994E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1736276E-03 0.1736276E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1872568E-06 0.1381051E-06 0.4915173E-07 0.0000000E+00 15 HPO4-- 0.6390983E-07 0.6400073E-08 0.5750975E-07 0.0000000E+00 Chg. balance for solid moles: -.7676E-21 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0108000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1917E-07 -7.717 0.9629E-05 -5.016 0.2723 0.3060E-05 clinochlore 0.1601E-05 -5.796 0.8901E-03 -3.051 25.17 0.3386E-03 daphnite 0.1058E-05 -5.975 0.7549E-03 -3.122 21.34 0.2288E-03 chlorite-Mn 0.9830E-08 -8.007 0.6969E-05 -5.157 0.1970 0.2221E-05 diaspore 0.2806E-04 -4.552 0.1684E-02 -2.774 47.60 0.5012E-03 hematite 0.1201E-05 -5.920 0.1918E-03 -3.717 5.423 0.3635E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.5999E+00 0.5999E+00 1.0000 -0.222 daphnite 0.3964E+00 0.3964E+00 1.0000 -0.402 chlorite-Mn 0.3683E-02 0.3683E-02 1.0000 -2.434 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.003537 g Volume = 0.001110 cm3 Porosity: 99.8895% V(tot) - V(min): 0.10032E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0108000 g log = -1.9666 Original solution: 1000.0103000 g Original solution / Rock added: 92593.55 (Water/Rock Ratio), log = 4.9666 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.6821E-04 1.0073 0.7229E-04 0.7176E-04 CH4,gas 0.3351E-12 1.0129 0.3571E-12 0.3526E-12 H2,gas 0.2555E-05 1.0006 0.2689E-05 0.2688E-05 H2S,gas 0.9712E-09 0.9959 0.1017E-08 0.1022E-08 S2,gas 0.5097E-26 1.0000 0.5362E-26 0.5362E-26 CO,gas 0.4786E-13 1.0000 0.5035E-13 0.5035E-13 SO3,gas 0.5616E-35 1.0000 0.5908E-35 0.5908E-35 SO2,gas 0.5713E-18 1.0000 0.6010E-18 0.6010E-18 HCl,gas 0.1103E-14 1.0000 0.1160E-14 0.1160E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.50 -6.14 -2.047 0.10486E+05 -4.141 3 CH4,gas 4.81 -9.64 -14.45 -3.612 0.24668E+05 -12.447 4 H2,gas 8.29 0.72 -7.57 -4.326 0.12926E+05 -5.570 5 H2S,gas -5.94 -16.94 -10.99 -5.496 0.18769E+05 -8.992 6 S2,gas -7.03 -35.30 -28.27 -4.349 0.48271E+05 -26.271 7 CO,gas 3.51 -11.79 -15.30 -4.707 0.26121E+05 -13.298 8 SO3,gas 17.43 -19.80 -37.23 -9.307 0.63567E+05 -35.229 9 SO2,gas 1.14 -19.08 -20.22 -5.392 0.34527E+05 -18.221 10 HCl,gas 5.48 -11.46 -16.94 -8.468 0.28917E+05 -14.936 16 albite -0.33 -5.30 -4.97 -0.382 0.84813E+04 20 analcite 3.37 -1.30 -4.67 -0.519 0.79715E+04 21 andalusite 5.06 1.79 -3.27 -0.327 0.55796E+04 24 anhydrite -5.28 -9.27 -3.99 -1.993 0.68067E+04 29 anorthite 12.80 8.33 -4.47 -0.344 0.76248E+04 35 aragonite 0.99 -1.97 -2.96 -0.985 0.50461E+04 36 brucite 12.58 8.86 -3.72 -0.744 0.63514E+04 37 calcite 0.83 -1.97 -2.80 -0.934 0.47848E+04 40 carpholite-Mg 8.65 6.65 -2.00 -0.133 0.34090E+04 41 carpholite-Fe 6.78 4.45 -2.33 -0.155 0.39763E+04 50 chloritoid-Mg 13.26 10.65 -2.61 -0.174 0.44562E+04 51 chloritoid-Fe 9.24 8.45 -0.79 -0.052 0.13438E+04 52 chloritoid-Mn 11.46 10.00 -1.47 -0.098 0.25018E+04 54 coesite -2.37 -4.00 -1.63 -0.543 0.27801E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -4.00 -1.45 -0.483 0.24730E+04 67 diopside 16.22 11.40 -4.82 -0.482 0.82278E+04 75 epidote 24.78 21.17 -3.61 -0.175 0.61584E+04 78 fayalite 14.08 9.32 -4.76 -0.680 0.81316E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.98 -4.22 -0.352 0.72023E+04 92 hercynite 17.34 12.45 -4.90 -0.326 0.83585E+04 98 kaolinite -1.27 -2.20 -0.93 -0.085 0.15876E+04 99 kyanite 4.93 1.79 -3.14 -0.314 0.53564E+04 101 laumontite 2.97 0.34 -2.64 -0.176 0.45035E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22987E+04 105 lizardite 23.29 18.58 -4.71 -0.393 0.80458E+04 106 magnesite 0.71 -3.65 -4.36 -1.452 0.74389E+04 107 magnetite 20.13 19.25 -0.88 -0.072 0.14993E+04 110 magnesioferrite 26.26 21.45 -4.80 -0.392 0.82007E+04 113 margarite 17.45 14.12 -3.33 -0.133 0.56816E+04 116 microcline -2.43 -7.17 -4.74 -0.365 0.80986E+04 120 muscovite 2.68 -1.38 -4.06 -0.239 0.69355E+04 121 paragonite 4.34 0.50 -3.84 -0.226 0.65566E+04 128 periclase-Fe 11.64 6.66 -4.98 -1.246 0.85067E+04 136 prehnite 19.47 14.87 -4.60 -0.270 0.78487E+04 137 prehnite-Fe 22.59 18.27 -4.31 -0.260 0.73667E+04 145 pyroxmangite 7.42 4.21 -3.21 -0.642 0.54814E+04 146 pyrophyllite -6.10 -10.20 -4.10 -0.256 0.70007E+04 147 quartz -2.98 -4.00 -1.02 -0.339 0.17340E+04 152 rhodochrosite -0.96 -4.30 -3.34 -1.114 0.57068E+04 153 rhodonite 7.46 4.21 -3.26 -0.651 0.55606E+04 156 siderite -2.59 -5.85 -3.26 -1.086 0.55654E+04 157 sillimanite 5.32 1.79 -3.53 -0.353 0.60218E+04 164 stilbite -7.41 -11.66 -4.25 -0.202 0.72564E+04 169 sudoite 21.22 17.31 -3.91 -0.126 0.66777E+04 178 topaz-H 4.67 1.79 -2.87 -0.261 0.49055E+04 179 tridymite -2.61 -4.00 -1.38 -0.461 0.23613E+04 188 wairakite 4.06 0.34 -3.72 -0.219 0.63543E+04 189 walstromite 11.53 6.54 -4.99 -0.998 0.85209E+04 190 wollastonite 10.48 6.54 -3.94 -0.789 0.67348E+04 191 pseudo-wollastonite 11.02 6.54 -4.48 -0.896 0.76534E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -6.18 -4.63 -0.286 0.78974E+04 197 beidellite-Mg -1.71 -6.46 -4.75 -0.294 0.81189E+04 200 chalcedony -2.79 -4.00 -1.20 -0.401 0.20544E+04 202 montmorillonite-Ca -2.21 -6.49 -4.28 -0.265 0.73058E+04 204 montmorillonite-Mg -2.40 -6.77 -4.37 -0.270 0.74583E+04 206 nontronite-Ca 3.28 0.62 -2.66 -0.173 0.45403E+04 207 nontronite-H 2.60 -1.12 -3.71 -0.249 0.63406E+04 208 nontronite-K 3.40 -0.48 -3.89 -0.250 0.66375E+04 209 nontronite-Mg 3.14 0.34 -2.80 -0.181 0.47734E+04 210 nontronite-Na 3.58 0.14 -3.45 -0.221 0.58843E+04 215 gypsum -4.92 -9.27 -4.34 -1.085 0.74135E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.66 -3.17 -0.792 0.54078E+04 241 silica-amorphous -2.08 -4.00 -1.92 -0.639 0.32746E+04 243 an20ab80 2.08 -2.57 -4.65 -0.358 0.79383E+04 244 an25ab75 2.71 -1.89 -4.60 -0.354 0.78505E+04 245 an30ab70 3.34 -1.21 -4.55 -0.350 0.77711E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0108000 g New total amount of reactant added: 0.0112000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0112000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2791133E-03 Osmotic coef. = 0.9900 True ionic strength = .2848451E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.26354E-07 -7.5792 0.25311E-07 -7.5967 0.96045E+00 -0.0175 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13249E-03 -3.8778 0.96033E+00 -0.0176 4 SO4-- 0.25331E-04 -4.5964 0.22736E-04 -4.6433 0.89756E+00 -0.0469 5 HCO3- 0.12393E-04 -4.9068 0.11902E-04 -4.9244 0.96036E+00 -0.0176 6 HS- 0.35744E-09 -9.4468 0.34326E-09 -9.4644 0.96033E+00 -0.0176 7 Al+++ 0.15925E-19 -19.7979 0.12765E-19 -19.8940 0.80162E+00 -0.0960 8 H4SiO4 0.10408E-03 -3.9826 0.10408E-03 -3.9826 0.10000E+01 0.0000 9 Ca++ 0.26982E-04 -4.5689 0.24215E-04 -4.6159 0.89743E+00 -0.0470 10 Mg++ 0.50445E-06 -6.2972 0.45267E-06 -6.3442 0.89734E+00 -0.0470 11 Fe++ 0.31580E-08 -8.5006 0.28339E-08 -8.5476 0.89736E+00 -0.0470 12 K+ 0.23771E-05 -5.6240 0.22828E-05 -5.6415 0.96036E+00 -0.0176 13 Na+ 0.17411E-03 -3.7592 0.16720E-03 -3.7768 0.96033E+00 -0.0176 14 Mn++ 0.12285E-06 -6.9106 0.11025E-06 -6.9576 0.89738E+00 -0.0470 15 HPO4-- 0.41207E-08 -8.3850 0.36986E-08 -8.4320 0.89757E+00 -0.0469 16 HSiO3- 0.41777E-05 -5.3791 0.40119E-05 -5.3966 0.96033E+00 -0.0176 17 Ca(HSiO3)+ 0.22664E-08 -8.6447 0.21766E-08 -8.6622 0.96037E+00 -0.0176 18 Mg(HSiO3)+ 0.52728E-10 -10.2780 0.50638E-10 -10.2955 0.96037E+00 -0.0176 19 NaHSiO3,aq 0.10654E-07 -7.9725 0.10654E-07 -7.9725 0.10000E+01 0.0000 20 AlO+ 0.26784E-11 -11.5721 0.25723E-11 -11.5897 0.96037E+00 -0.0176 21 AlOH+2 0.36344E-15 -15.4396 0.32615E-15 -15.4866 0.89740E+00 -0.0470 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.18682E-05 -5.7286 0.17940E-05 -5.7462 0.96029E+00 -0.0176 24 CH4,aq 0.17635E-15 -15.7536 0.17633E-15 -15.7537 0.99991E+00 0.0000 29 CO,aq 0.29114E-16 -16.5359 0.29114E-16 -16.5359 0.10000E+01 0.0000 30 CO2,aq 0.60746E-06 -6.2165 0.60740E-06 -6.2165 0.99991E+00 0.0000 31 CO3-2 0.48441E-07 -7.3148 0.43477E-07 -7.3617 0.89752E+00 -0.0470 32 CaCO3,aq 0.12894E-07 -7.8896 0.12894E-07 -7.8896 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.75616E-08 -8.1214 0.72619E-08 -8.1389 0.96037E+00 -0.0176 34 CaCl+ 0.53231E-08 -8.2738 0.51122E-08 -8.2914 0.96037E+00 -0.0176 35 CaCl2,aq 0.15770E-12 -12.8022 0.15770E-12 -12.8022 0.10000E+01 0.0000 36 CaOH+ 0.70241E-07 -7.1534 0.67457E-07 -7.1710 0.96037E+00 -0.0176 37 CaSO4,aq 0.17153E-06 -6.7656 0.17153E-06 -6.7656 0.10000E+01 0.0000 38 HCl,aq 0.63078E-12 -12.2001 0.63078E-12 -12.2001 0.10000E+01 0.0000 43 FeCl+ 0.60892E-12 -12.2154 0.58478E-12 -12.2330 0.96037E+00 -0.0176 46 FeO,aq 0.17492E-09 -9.7572 0.17492E-09 -9.7572 0.10000E+01 0.0000 47 FeOH+ 0.38650E-08 -8.4129 0.37118E-08 -8.4304 0.96037E+00 -0.0176 48 HFeO2- 0.77402E-10 -10.1113 0.74331E-10 -10.1288 0.96033E+00 -0.0176 49 FeO+ 0.21802E-12 -12.6615 0.20938E-12 -12.6791 0.96037E+00 -0.0176 50 FeOH+2 0.10989E-17 -17.9590 0.98617E-18 -18.0060 0.89740E+00 -0.0470 51 FeO2- 0.66886E-10 -10.1747 0.64232E-10 -10.1922 0.96033E+00 -0.0176 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.18612E-08 -8.7302 0.18611E-08 -8.7302 0.99991E+00 0.0000 54 KCl,aq 0.53553E-11 -11.2712 0.53553E-11 -11.2712 0.10000E+01 0.0000 55 KHSO4,aq 0.35155E-17 -17.4540 0.35155E-17 -17.4540 0.10000E+01 0.0000 56 KOH,aq 0.39318E-10 -10.4054 0.39318E-10 -10.4054 0.10000E+01 0.0000 57 KSO4- 0.83266E-09 -9.0795 0.79962E-09 -9.0971 0.96033E+00 -0.0176 58 MgCO3,aq 0.60231E-10 -10.2202 0.60231E-10 -10.2202 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14415E-09 -9.8412 0.13843E-09 -9.8588 0.96037E+00 -0.0176 60 MgCl+ 0.90338E-10 -10.0441 0.86757E-10 -10.0617 0.96037E+00 -0.0176 61 MgOH+ 0.72745E-08 -8.1382 0.69862E-08 -8.1558 0.96037E+00 -0.0176 63 MnO,aq 0.18165E-09 -9.7408 0.18165E-09 -9.7408 0.10000E+01 0.0000 64 MnOH+ 0.13968E-07 -7.8549 0.13414E-07 -7.8724 0.96037E+00 -0.0176 65 MnO2-2 0.10925E-16 -16.9616 0.98056E-17 -17.0085 0.89752E+00 -0.0470 66 HMnO2- 0.55996E-13 -13.2518 0.53774E-13 -13.2694 0.96033E+00 -0.0176 69 MnCl+ 0.92049E-10 -10.0360 0.88401E-10 -10.0535 0.96037E+00 -0.0176 70 MnSO4,aq 0.71035E-09 -9.1485 0.71035E-09 -9.1485 0.10000E+01 0.0000 71 NaCl,aq 0.72333E-08 -8.1407 0.72333E-08 -8.1407 0.10000E+01 0.0000 72 NaOH,aq 0.29026E-08 -8.5372 0.29026E-08 -8.5372 0.10000E+01 0.0000 74 OH- 0.24678E-04 -4.6077 0.23698E-04 -4.6253 0.96029E+00 -0.0176 79 HPO3-2 0.24224E-19 -19.6158 0.21742E-19 -19.6627 0.89752E+00 -0.0470 82 H3PO4,aq 0.15255E-13 -13.8166 0.15255E-13 -13.8166 0.10000E+01 0.0000 83 H2PO4- 0.17091E-08 -8.7672 0.16413E-08 -8.7848 0.96035E+00 -0.0176 84 PO4-3 0.15903E-12 -12.7985 0.12761E-12 -12.8941 0.80245E+00 -0.0956 87 H2P2O7-2 0.23491E-18 -18.6291 0.21083E-18 -18.6761 0.89752E+00 -0.0470 88 HP2O7-3 0.21307E-17 -17.6715 0.17080E-17 -17.7675 0.80163E+00 -0.0960 89 P2O7-4 0.24310E-19 -19.6142 0.16647E-19 -19.7787 0.68478E+00 -0.1644 90 H2S,aq 0.26107E-10 -10.5832 0.26105E-10 -10.5833 0.99991E+00 0.0000 96 SO2,aq 0.11358E-18 -18.9447 0.11358E-18 -18.9447 0.10000E+01 0.0000 97 SO3-2 0.64261E-14 -14.1921 0.57694E-14 -14.2389 0.89780E+00 -0.0468 98 HSO3- 0.88990E-14 -14.0507 0.85460E-14 -14.0682 0.96033E+00 -0.0176 99 HSO4- 0.55599E-09 -9.2549 0.53396E-09 -9.2725 0.96038E+00 -0.0176 101 S2O3-2 0.77937E-17 -17.1083 0.69950E-17 -17.1552 0.89752E+00 -0.0470 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2635375E-07 -.3592800E-04 -.3621247E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999762E+06 0.0000 3 Cl- 0.1379620E-03 0.1379748E-03 0.4891512E+01 3.7189 4 SO4-- 0.2533056E-04 0.2550377E-04 0.2449879E+01 10.5501 5 HCO3- 0.1239350E-04 0.1307006E-04 0.7974807E+00 2.6723 6 HS- 0.3574432E-09 0.8150425E-09 0.2695449E-04 -1.8677 7 Al+++ 0.1592461E-19 0.1888506E-05 0.5095361E-01 2.8961 8 H4SiO4 0.1040800E-03 0.1082706E-03 0.1040624E+02 -3.9826 9 Ca++ 0.2698221E-04 0.2725203E-04 0.1092183E+01 10.5774 10 Mg++ 0.5044517E-06 0.5120737E-06 0.1244926E-01 8.8491 11 Fe++ 0.3158041E-08 0.7546526E-08 0.4214416E-03 6.6458 12 K+ 0.2377052E-05 0.2377930E-05 0.9297976E-01 1.9552 13 Na+ 0.1741097E-03 0.1741305E-03 0.4003137E+01 3.8199 14 Mn++ 0.1228526E-06 0.1378043E-06 0.7570525E-02 8.2357 15 HPO4-- 0.4120708E-08 0.5829951E-08 0.5595406E-03 6.7614 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1724154E-03 -.3592785E-04 -.1364875E-03 0.0000000E+00 2 H2O 0.5550811E+02 0.5550803E+02 0.7734209E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2581486E-04 0.2550365E-04 0.3112052E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3103902E-06 0.8150390E-09 -.3112052E-06 0.0000000E+00 7 Al+++ 0.3652031E-04 0.1888498E-05 0.3463181E-04 0.0000000E+00 8 H4SiO4 0.1166232E-03 0.1082701E-03 0.8353028E-05 0.0000000E+00 9 Ca++ 0.2735266E-04 0.2725191E-04 0.1007449E-06 0.0000000E+00 10 Mg++ 0.8888889E-05 0.5120714E-06 0.8376817E-05 0.0000000E+00 11 Fe++ 0.7985696E-05 0.7546493E-08 0.7978150E-05 0.0000000E+00 12 K+ 0.2377919E-05 0.2377919E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1741297E-03 0.1741297E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1941923E-06 0.1378037E-06 0.5638859E-07 0.0000000E+00 15 HPO4-- 0.6627686E-07 0.5829926E-08 0.6044693E-07 0.0000000E+00 Chg. balance for solid moles: -.1083E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0112000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2015E-07 -7.696 0.1012E-04 -4.995 0.2754 0.3216E-05 clinochlore 0.1675E-05 -5.776 0.9312E-03 -3.031 25.34 0.3542E-03 daphnite 0.1098E-05 -5.960 0.7832E-03 -3.106 21.31 0.2373E-03 chlorite-Mn 0.1128E-07 -7.948 0.7996E-05 -5.097 0.2176 0.2548E-05 diaspore 0.2906E-04 -4.537 0.1743E-02 -2.759 47.44 0.5191E-03 hematite 0.1245E-05 -5.905 0.1988E-03 -3.702 5.410 0.3768E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6017E+00 0.6017E+00 1.0000 -0.221 daphnite 0.3942E+00 0.3942E+00 1.0000 -0.404 chlorite-Mn 0.4050E-02 0.4050E-02 1.0000 -2.393 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.003675 g Volume = 0.001154 cm3 Porosity: 99.8851% V(tot) - V(min): 0.10033E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0112000 g log = -1.9508 Original solution: 1000.0103000 g Original solution / Rock added: 89286.63 (Water/Rock Ratio), log = 4.9508 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.6561E-04 1.0073 0.6953E-04 0.6902E-04 CH4,gas 0.2617E-12 1.0129 0.2788E-12 0.2753E-12 H2,gas 0.2425E-05 1.0006 0.2553E-05 0.2551E-05 H2S,gas 0.7267E-09 0.9959 0.7614E-09 0.7645E-09 S2,gas 0.3168E-26 1.0000 0.3332E-26 0.3332E-26 CO,gas 0.4370E-13 1.0000 0.4597E-13 0.4597E-13 SO3,gas 0.5176E-35 1.0000 0.5446E-35 0.5446E-35 SO2,gas 0.4999E-18 1.0000 0.5259E-18 0.5259E-18 HCl,gas 0.1059E-14 1.0000 0.1114E-14 0.1114E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.52 -6.16 -2.053 0.10514E+05 -4.158 3 CH4,gas 4.81 -9.75 -14.55 -3.639 0.24852E+05 -12.555 4 H2,gas 8.29 0.69 -7.59 -4.339 0.12965E+05 -5.593 5 H2S,gas -5.94 -17.06 -11.12 -5.559 0.18984E+05 -9.118 6 S2,gas -7.03 -35.51 -28.48 -4.381 0.48624E+05 -26.477 7 CO,gas 3.51 -11.83 -15.34 -4.719 0.26188E+05 -13.338 8 SO3,gas 17.43 -19.84 -37.26 -9.316 0.63627E+05 -35.264 9 SO2,gas 1.14 -19.14 -20.28 -5.408 0.34626E+05 -18.279 10 HCl,gas 5.48 -11.47 -16.95 -8.477 0.28947E+05 -14.953 16 albite -0.33 -5.23 -4.90 -0.377 0.83726E+04 20 analcite 3.37 -1.25 -4.62 -0.513 0.78883E+04 21 andalusite 5.06 1.81 -3.25 -0.325 0.55541E+04 24 anhydrite -5.28 -9.26 -3.98 -1.990 0.67948E+04 29 anorthite 12.80 8.40 -4.39 -0.338 0.75015E+04 35 aragonite 0.99 -1.94 -2.93 -0.977 0.50026E+04 36 brucite 12.58 8.85 -3.73 -0.745 0.63645E+04 37 calcite 0.83 -1.94 -2.78 -0.926 0.47413E+04 40 carpholite-Mg 8.65 6.68 -1.97 -0.132 0.33711E+04 41 carpholite-Fe 6.78 4.47 -2.31 -0.154 0.39446E+04 50 chloritoid-Mg 13.26 10.66 -2.60 -0.174 0.44438E+04 51 chloritoid-Fe 9.24 8.46 -0.78 -0.052 0.13376E+04 52 chloritoid-Mn 11.46 10.05 -1.42 -0.095 0.24211E+04 54 coesite -2.37 -3.98 -1.61 -0.538 0.27546E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.98 -1.43 -0.478 0.24475E+04 67 diopside 16.22 11.46 -4.75 -0.475 0.81176E+04 68 hedenbergite 14.24 9.26 -4.99 -0.499 0.85143E+04 75 epidote 24.78 21.30 -3.48 -0.169 0.59373E+04 78 fayalite 14.08 9.31 -4.77 -0.681 0.81448E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.97 -4.22 -0.352 0.72093E+04 92 hercynite 17.34 12.44 -4.91 -0.327 0.83779E+04 98 kaolinite -1.27 -2.17 -0.90 -0.082 0.15366E+04 99 kyanite 4.93 1.81 -3.12 -0.312 0.53309E+04 101 laumontite 2.97 0.44 -2.54 -0.169 0.43292E+04 102 lawsonite 9.68 8.40 -1.27 -0.085 0.21754E+04 105 lizardite 23.29 18.58 -4.71 -0.392 0.80341E+04 106 magnesite 0.71 -3.67 -4.38 -1.460 0.74808E+04 107 magnetite 20.13 19.24 -0.89 -0.073 0.15187E+04 110 magnesioferrite 26.26 21.45 -4.81 -0.393 0.82138E+04 113 margarite 17.45 14.20 -3.26 -0.130 0.55583E+04 116 microcline -2.43 -7.10 -4.66 -0.359 0.79651E+04 120 muscovite 2.68 -1.30 -3.98 -0.234 0.68020E+04 121 paragonite 4.34 0.56 -3.78 -0.222 0.64480E+04 128 periclase-Fe 11.64 6.65 -4.99 -1.248 0.85261E+04 136 prehnite 19.47 15.00 -4.47 -0.263 0.76276E+04 137 prehnite-Fe 22.59 18.40 -4.18 -0.252 0.71456E+04 145 pyroxmangite 7.42 4.25 -3.16 -0.633 0.54006E+04 146 pyrophyllite -6.10 -10.14 -4.04 -0.253 0.68987E+04 147 quartz -2.98 -3.98 -1.00 -0.334 0.17086E+04 152 rhodochrosite -0.96 -4.29 -3.33 -1.109 0.56804E+04 153 rhodonite 7.46 4.25 -3.21 -0.642 0.54799E+04 156 siderite -2.59 -5.88 -3.29 -1.096 0.56135E+04 157 sillimanite 5.32 1.81 -3.51 -0.351 0.59963E+04 164 stilbite -7.41 -11.51 -4.10 -0.195 0.70057E+04 169 sudoite 21.22 17.33 -3.88 -0.125 0.66275E+04 178 topaz-H 4.67 1.81 -2.86 -0.260 0.48800E+04 179 tridymite -2.61 -3.98 -1.37 -0.456 0.23358E+04 188 wairakite 4.06 0.44 -3.62 -0.213 0.61800E+04 189 walstromite 11.53 6.59 -4.93 -0.987 0.84231E+04 190 wollastonite 10.48 6.59 -3.89 -0.777 0.66370E+04 191 pseudo-wollastonite 11.02 6.59 -4.43 -0.885 0.75556E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -6.12 -4.56 -0.282 0.77919E+04 197 beidellite-Mg -1.71 -6.41 -4.70 -0.291 0.80275E+04 200 chalcedony -2.79 -3.98 -1.19 -0.396 0.20289E+04 202 montmorillonite-Ca -2.21 -6.43 -4.21 -0.261 0.71962E+04 204 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73628E+04 205 montmorillonite-Na -1.96 -6.91 -4.95 -0.303 0.84565E+04 206 nontronite-Ca 3.28 0.68 -2.60 -0.168 0.44348E+04 207 nontronite-H 2.60 -1.06 -3.66 -0.245 0.62471E+04 208 nontronite-K 3.40 -0.42 -3.82 -0.245 0.65252E+04 209 nontronite-Mg 3.14 0.40 -2.74 -0.178 0.46820E+04 210 nontronite-Na 3.58 0.20 -3.39 -0.217 0.57801E+04 215 gypsum -4.92 -9.26 -4.33 -1.084 0.74016E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.65 -3.18 -0.795 0.54271E+04 241 silica-amorphous -2.08 -3.98 -1.90 -0.634 0.32491E+04 243 an20ab80 2.08 -2.50 -4.58 -0.353 0.78268E+04 244 an25ab75 2.71 -1.82 -4.53 -0.349 0.77382E+04 245 an30ab70 3.34 -1.14 -4.49 -0.345 0.76580E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0112000 g New total amount of reactant added: 0.0116000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0116000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2805567E-03 Osmotic coef. = 0.9900 True ionic strength = .2866335E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.25346E-07 -7.5961 0.24342E-07 -7.6136 0.96038E+00 -0.0176 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13248E-03 -3.8779 0.96026E+00 -0.0176 4 SO4-- 0.25328E-04 -4.5964 0.22727E-04 -4.6435 0.89732E+00 -0.0471 5 HCO3- 0.12413E-04 -4.9061 0.11920E-04 -4.9237 0.96029E+00 -0.0176 6 HS- 0.28236E-09 -9.5492 0.27114E-09 -9.5668 0.96026E+00 -0.0176 7 Al+++ 0.14173E-19 -19.8485 0.11355E-19 -19.9448 0.80112E+00 -0.0963 8 H4SiO4 0.10759E-03 -3.9682 0.10759E-03 -3.9682 0.10000E+01 0.0000 9 Ca++ 0.27430E-04 -4.5618 0.24609E-04 -4.6089 0.89718E+00 -0.0471 10 Mg++ 0.45860E-06 -6.3386 0.41141E-06 -6.3857 0.89709E+00 -0.0472 11 Fe++ 0.28508E-08 -8.5450 0.25575E-08 -8.5922 0.89711E+00 -0.0472 12 K+ 0.24619E-05 -5.6087 0.23642E-05 -5.6263 0.96030E+00 -0.0176 13 Na+ 0.17461E-03 -3.7579 0.16767E-03 -3.7755 0.96026E+00 -0.0176 14 Mn++ 0.12167E-06 -6.9148 0.10915E-06 -6.9620 0.89713E+00 -0.0471 15 HPO4-- 0.38087E-08 -8.4192 0.34176E-08 -8.4663 0.89732E+00 -0.0471 16 HSiO3- 0.44908E-05 -5.3477 0.43123E-05 -5.3653 0.96026E+00 -0.0176 17 Ca(HSiO3)+ 0.24760E-08 -8.6062 0.23777E-08 -8.6238 0.96030E+00 -0.0176 18 Mg(HSiO3)+ 0.51514E-10 -10.2881 0.49469E-10 -10.3057 0.96030E+00 -0.0176 19 NaHSiO3,aq 0.11484E-07 -7.9399 0.11484E-07 -7.9399 0.10000E+01 0.0000 20 AlO+ 0.25760E-11 -11.5890 0.24738E-11 -11.6066 0.96030E+00 -0.0176 21 AlOH+2 0.33623E-15 -15.4734 0.30165E-15 -15.5205 0.89715E+00 -0.0471 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.19427E-05 -5.7116 0.18654E-05 -5.7292 0.96022E+00 -0.0176 24 CH4,aq 0.13955E-15 -15.8553 0.13954E-15 -15.8553 0.99991E+00 0.0000 29 CO,aq 0.26698E-16 -16.5735 0.26698E-16 -16.5735 0.10000E+01 0.0000 30 CO2,aq 0.58507E-06 -6.2328 0.58502E-06 -6.2328 0.99991E+00 0.0000 31 CO3-2 0.50460E-07 -7.2971 0.45276E-07 -7.3441 0.89728E+00 -0.0471 32 CaCO3,aq 0.13646E-07 -7.8650 0.13646E-07 -7.8650 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.76970E-08 -8.1137 0.73914E-08 -8.1313 0.96030E+00 -0.0176 34 CaCl+ 0.54099E-08 -8.2668 0.51951E-08 -8.2844 0.96030E+00 -0.0176 35 CaCl2,aq 0.16025E-12 -12.7952 0.16025E-12 -12.7952 0.10000E+01 0.0000 36 CaOH+ 0.74233E-07 -7.1294 0.71286E-07 -7.1470 0.96030E+00 -0.0176 37 CaSO4,aq 0.17426E-06 -6.7588 0.17426E-06 -6.7588 0.10000E+01 0.0000 38 HCl,aq 0.60658E-12 -12.2171 0.60658E-12 -12.2171 0.10000E+01 0.0000 43 FeCl+ 0.54952E-12 -12.2600 0.52770E-12 -12.2776 0.96030E+00 -0.0176 46 FeO,aq 0.17067E-09 -9.7678 0.17067E-09 -9.7678 0.10000E+01 0.0000 47 FeOH+ 0.36271E-08 -8.4404 0.34831E-08 -8.4580 0.96030E+00 -0.0176 48 HFeO2- 0.78536E-10 -10.1049 0.75415E-10 -10.1225 0.96026E+00 -0.0176 49 FeO+ 0.20969E-12 -12.6784 0.20136E-12 -12.6960 0.96030E+00 -0.0176 50 FeOH+2 0.10167E-17 -17.9928 0.91209E-18 -18.0400 0.89715E+00 -0.0471 51 FeO2- 0.69554E-10 -10.1577 0.66790E-10 -10.1753 0.96026E+00 -0.0176 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.17720E-08 -8.7515 0.17719E-08 -8.7516 0.99991E+00 0.0000 54 KCl,aq 0.55458E-11 -11.2560 0.55458E-11 -11.2560 0.10000E+01 0.0000 55 KHSO4,aq 0.35000E-17 -17.4559 0.35000E-17 -17.4559 0.10000E+01 0.0000 56 KOH,aq 0.42341E-10 -10.3732 0.42341E-10 -10.3732 0.10000E+01 0.0000 57 KSO4- 0.86207E-09 -9.0645 0.82781E-09 -9.0821 0.96026E+00 -0.0176 58 MgCO3,aq 0.57007E-10 -10.2441 0.57007E-10 -10.2441 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13121E-09 -9.8820 0.12601E-09 -9.8996 0.96030E+00 -0.0176 60 MgCl+ 0.82105E-10 -10.0856 0.78845E-10 -10.1032 0.96030E+00 -0.0176 61 MgOH+ 0.68753E-08 -8.1627 0.66023E-08 -8.1803 0.96030E+00 -0.0176 63 MnO,aq 0.19445E-09 -9.7112 0.19445E-09 -9.7112 0.10000E+01 0.0000 64 MnOH+ 0.14380E-07 -7.8422 0.13809E-07 -7.8598 0.96030E+00 -0.0176 65 MnO2-2 0.12648E-16 -16.8980 0.11349E-16 -16.9450 0.89728E+00 -0.0471 66 HMnO2- 0.62333E-13 -13.2053 0.59856E-13 -13.2229 0.96026E+00 -0.0176 69 MnCl+ 0.91134E-10 -10.0403 0.87516E-10 -10.0579 0.96030E+00 -0.0176 70 MnSO4,aq 0.70302E-09 -9.1530 0.70302E-09 -9.1530 0.10000E+01 0.0000 71 NaCl,aq 0.72531E-08 -8.1395 0.72531E-08 -8.1395 0.10000E+01 0.0000 72 NaOH,aq 0.30267E-08 -8.5190 0.30267E-08 -8.5190 0.10000E+01 0.0000 74 OH- 0.25662E-04 -4.5907 0.24642E-04 -4.6083 0.96022E+00 -0.0176 79 HPO3-2 0.21317E-19 -19.6713 0.19127E-19 -19.7184 0.89728E+00 -0.0471 82 H3PO4,aq 0.13038E-13 -13.8848 0.13038E-13 -13.8848 0.10000E+01 0.0000 83 H2PO4- 0.15189E-08 -8.8185 0.14585E-08 -8.8361 0.96028E+00 -0.0176 84 PO4-3 0.15289E-12 -12.8156 0.12261E-12 -12.9115 0.80196E+00 -0.0958 87 H2P2O7-2 0.18556E-18 -18.7315 0.16650E-18 -18.7786 0.89728E+00 -0.0471 88 HP2O7-3 0.17507E-17 -17.7568 0.14025E-17 -17.8531 0.80113E+00 -0.0963 89 P2O7-4 0.20780E-19 -19.6824 0.14214E-19 -19.8473 0.68403E+00 -0.1649 90 H2S,aq 0.19832E-10 -10.7026 0.19830E-10 -10.7027 0.99991E+00 0.0000 96 SO2,aq 0.99973E-19 -19.0001 0.99973E-19 -19.0001 0.10000E+01 0.0000 97 SO3-2 0.61175E-14 -14.2134 0.54908E-14 -14.2604 0.89755E+00 -0.0469 98 HSO3- 0.81456E-14 -14.0891 0.78219E-14 -14.1067 0.96026E+00 -0.0176 99 HSO4- 0.53453E-09 -9.2720 0.51332E-09 -9.2896 0.96032E+00 -0.0176 101 S2O3-2 0.59197E-17 -17.2277 0.53116E-17 -17.2748 0.89728E+00 -0.0471 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2534638E-07 -.3755486E-04 -.3785220E-01 0.0000 2 H2O 0.1000000E+01 0.5550827E+02 0.9999758E+06 0.0000 3 Cl- 0.1379620E-03 0.1379748E-03 0.4891511E+01 3.7358 4 SO4-- 0.2532792E-04 0.2550387E-04 0.2449888E+01 10.5838 5 HCO3- 0.1241299E-04 0.1307006E-04 0.7974805E+00 2.6899 6 HS- 0.2823560E-09 0.7110466E-09 0.2351521E-04 -1.9532 7 Al+++ 0.1417326E-19 0.1963023E-05 0.5296413E-01 2.8961 8 H4SiO4 0.1075894E-03 0.1120942E-03 0.1077373E+02 -3.9682 9 Ca++ 0.2742959E-04 0.2770731E-04 0.1110429E+01 10.6184 10 Mg++ 0.4586046E-06 0.4658018E-06 0.1132432E-01 8.8416 11 Fe++ 0.2850759E-08 0.7000826E-08 0.3909664E-03 6.6351 12 K+ 0.2461946E-05 0.2462856E-05 0.9630044E-01 1.9873 13 Na+ 0.1746108E-03 0.1746326E-03 0.4014679E+01 3.8381 14 Mn++ 0.1216655E-06 0.1370346E-06 0.7528239E-02 8.2653 15 HPO4-- 0.3808730E-08 0.5327771E-08 0.5113427E-03 6.7610 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1790388E-03 -.3755469E-04 -.1414841E-03 0.0000000E+00 2 H2O 0.5550810E+02 0.5550802E+02 0.8011819E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2582595E-04 0.2550376E-04 0.3221866E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3214755E-06 0.7110434E-09 -.3221866E-06 0.0000000E+00 7 Al+++ 0.3782460E-04 0.1963015E-05 0.3586159E-04 0.0000000E+00 8 H4SiO4 0.1207883E-03 0.1120937E-03 0.8694630E-05 0.0000000E+00 9 Ca++ 0.2781271E-04 0.2770719E-04 0.1055269E-06 0.0000000E+00 10 Mg++ 0.9206349E-05 0.4657997E-06 0.8740550E-05 0.0000000E+00 11 Fe++ 0.8270900E-05 0.7000795E-08 0.8263899E-05 0.0000000E+00 12 K+ 0.2462845E-05 0.2462845E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1746318E-03 0.1746318E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2011277E-06 0.1370340E-06 0.6409372E-07 0.0000000E+00 15 HPO4-- 0.6864389E-07 0.5327747E-08 0.6331614E-07 0.0000000E+00 Chg. balance for solid moles: -.2083E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0116000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2111E-07 -7.676 0.1060E-04 -4.975 0.2781 0.3369E-05 clinochlore 0.1748E-05 -5.757 0.9717E-03 -3.012 25.49 0.3696E-03 daphnite 0.1137E-05 -5.944 0.8115E-03 -3.091 21.29 0.2459E-03 chlorite-Mn 0.1282E-07 -7.892 0.9088E-05 -5.042 0.2384 0.2896E-05 diaspore 0.3007E-04 -4.522 0.1804E-02 -2.744 47.31 0.5369E-03 hematite 0.1289E-05 -5.890 0.2058E-03 -3.687 5.399 0.3901E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6032E+00 0.6032E+00 1.0000 -0.220 daphnite 0.3924E+00 0.3924E+00 1.0000 -0.406 chlorite-Mn 0.4423E-02 0.4423E-02 1.0000 -2.354 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.003812 g Volume = 0.001198 cm3 Porosity: 99.8808% V(tot) - V(min): 0.10034E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0116000 g log = -1.9355 Original solution: 1000.0103000 g Original solution / Rock added: 86207.78 (Water/Rock Ratio), log = 4.9355 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.6319E-04 1.0073 0.6697E-04 0.6648E-04 CH4,gas 0.2071E-12 1.0129 0.2207E-12 0.2179E-12 H2,gas 0.2309E-05 1.0006 0.2430E-05 0.2429E-05 H2S,gas 0.5520E-09 0.9959 0.5784E-09 0.5807E-09 S2,gas 0.2016E-26 1.0000 0.2121E-26 0.2121E-26 CO,gas 0.4007E-13 1.0000 0.4216E-13 0.4216E-13 SO3,gas 0.4786E-35 1.0000 0.5035E-35 0.5035E-35 SO2,gas 0.4400E-18 1.0000 0.4629E-18 0.4629E-18 HCl,gas 0.1018E-14 1.0000 0.1071E-14 0.1071E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.54 -6.17 -2.058 0.10542E+05 -4.174 3 CH4,gas 4.81 -9.85 -14.66 -3.664 0.25025E+05 -12.656 4 H2,gas 8.29 0.67 -7.61 -4.351 0.13001E+05 -5.614 5 H2S,gas -5.94 -17.18 -11.24 -5.619 0.19188E+05 -9.238 6 S2,gas -7.03 -35.71 -28.67 -4.411 0.48959E+05 -26.673 7 CO,gas 3.51 -11.86 -15.38 -4.731 0.26253E+05 -13.375 8 SO3,gas 17.43 -19.87 -37.30 -9.325 0.63685E+05 -35.298 9 SO2,gas 1.14 -19.20 -20.33 -5.423 0.34721E+05 -18.335 10 HCl,gas 5.48 -11.49 -16.97 -8.485 0.28976E+05 -14.970 16 albite -0.33 -5.17 -4.84 -0.372 0.82678E+04 20 analcite 3.37 -1.20 -4.57 -0.508 0.78081E+04 21 andalusite 5.06 1.82 -3.24 -0.324 0.55295E+04 24 anhydrite -5.28 -9.25 -3.97 -1.986 0.67831E+04 29 anorthite 12.80 8.47 -4.32 -0.333 0.73824E+04 35 aragonite 0.99 -1.92 -2.91 -0.968 0.49606E+04 36 brucite 12.58 8.84 -3.74 -0.747 0.63775E+04 37 calcite 0.83 -1.92 -2.75 -0.917 0.46992E+04 40 carpholite-Mg 8.65 6.70 -1.95 -0.130 0.33349E+04 41 carpholite-Fe 6.78 4.49 -2.29 -0.153 0.39137E+04 50 chloritoid-Mg 13.26 10.67 -2.60 -0.173 0.44322E+04 51 chloritoid-Fe 9.24 8.46 -0.78 -0.052 0.13312E+04 52 chloritoid-Mn 11.46 10.09 -1.37 -0.092 0.23460E+04 54 coesite -2.37 -3.97 -1.60 -0.533 0.27300E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.97 -1.42 -0.473 0.24229E+04 67 diopside 16.22 11.52 -4.69 -0.469 0.80115E+04 68 hedenbergite 14.24 9.32 -4.93 -0.493 0.84134E+04 75 epidote 24.78 21.42 -3.35 -0.163 0.57237E+04 76 clinozoisite 22.92 18.02 -4.90 -0.223 0.83680E+04 78 fayalite 14.08 9.30 -4.78 -0.682 0.81566E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.97 -4.23 -0.352 0.72148E+04 92 hercynite 17.34 12.43 -4.92 -0.328 0.83961E+04 98 kaolinite -1.27 -2.14 -0.87 -0.079 0.14875E+04 99 kyanite 4.93 1.82 -3.11 -0.311 0.53063E+04 101 laumontite 2.97 0.54 -2.44 -0.162 0.41610E+04 102 lawsonite 9.68 8.47 -1.20 -0.080 0.20563E+04 105 lizardite 23.29 18.59 -4.70 -0.392 0.80238E+04 106 magnesite 0.71 -3.70 -4.41 -1.468 0.75216E+04 107 magnetite 20.13 19.23 -0.90 -0.073 0.15369E+04 110 magnesioferrite 26.26 21.44 -4.82 -0.393 0.82268E+04 113 margarite 17.45 14.27 -3.19 -0.127 0.54392E+04 116 microcline -2.43 -7.02 -4.59 -0.353 0.78364E+04 120 muscovite 2.68 -1.23 -3.91 -0.230 0.66733E+04 121 paragonite 4.34 0.62 -3.71 -0.219 0.63432E+04 136 prehnite 19.47 15.12 -4.34 -0.255 0.74140E+04 137 prehnite-Fe 22.59 18.53 -4.06 -0.244 0.69320E+04 145 pyroxmangite 7.42 4.30 -3.12 -0.624 0.53255E+04 146 pyrophyllite -6.10 -10.08 -3.98 -0.249 0.68004E+04 147 quartz -2.98 -3.97 -0.99 -0.329 0.16840E+04 152 rhodochrosite -0.96 -4.27 -3.31 -1.105 0.56578E+04 153 rhodonite 7.46 4.30 -3.17 -0.633 0.54048E+04 156 siderite -2.59 -5.90 -3.31 -1.105 0.56596E+04 157 sillimanite 5.32 1.82 -3.50 -0.350 0.59717E+04 164 stilbite -7.41 -11.37 -3.96 -0.189 0.67636E+04 165 stilpnomelane-Fe 13.18 8.22 -4.96 -0.148 0.84758E+04 169 sudoite 21.22 17.36 -3.85 -0.124 0.65796E+04 178 topaz-H 4.67 1.82 -2.84 -0.259 0.48554E+04 179 tridymite -2.61 -3.97 -1.35 -0.451 0.23113E+04 188 wairakite 4.06 0.54 -3.52 -0.207 0.60118E+04 189 walstromite 11.53 6.65 -4.88 -0.976 0.83286E+04 190 wollastonite 10.48 6.65 -3.83 -0.766 0.65425E+04 191 pseudo-wollastonite 11.02 6.65 -4.37 -0.874 0.74611E+04 192 zoisite 22.96 18.02 -4.94 -0.225 0.84406E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -6.06 -4.50 -0.279 0.76901E+04 197 beidellite-Mg -1.71 -6.36 -4.65 -0.288 0.79394E+04 200 chalcedony -2.79 -3.97 -1.17 -0.391 0.20043E+04 202 montmorillonite-Ca -2.21 -6.37 -4.15 -0.257 0.70906E+04 204 montmorillonite-Mg -2.40 -6.66 -4.26 -0.263 0.72709E+04 205 montmorillonite-Na -1.96 -6.85 -4.89 -0.300 0.83522E+04 206 nontronite-Ca 3.28 0.74 -2.54 -0.165 0.43331E+04 207 nontronite-H 2.60 -1.01 -3.61 -0.242 0.61568E+04 208 nontronite-K 3.40 -0.35 -3.76 -0.241 0.64168E+04 209 nontronite-Mg 3.14 0.45 -2.69 -0.175 0.45939E+04 210 nontronite-Na 3.58 0.26 -3.33 -0.213 0.56796E+04 215 gypsum -4.92 -9.25 -4.33 -1.082 0.73899E+04 225 tobermorite 9.84 4.88 -4.96 -1.354 0.84727E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.64 -3.19 -0.797 0.54454E+04 241 silica-amorphous -2.08 -3.97 -1.89 -0.629 0.32245E+04 243 an20ab80 2.08 -2.44 -4.52 -0.348 0.77191E+04 244 an25ab75 2.71 -1.76 -4.47 -0.344 0.76299E+04 245 an30ab70 3.34 -1.08 -4.42 -0.340 0.75489E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0116000 g New total amount of reactant added: 0.0120000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0120000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2820110E-03 Osmotic coef. = 0.9900 True ionic strength = .2884374E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.24413E-07 -7.6124 0.23444E-07 -7.6300 0.96032E+00 -0.0176 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13247E-03 -3.8779 0.96019E+00 -0.0176 4 SO4-- 0.25325E-04 -4.5964 0.22718E-04 -4.6436 0.89707E+00 -0.0472 5 HCO3- 0.12431E-04 -4.9055 0.11936E-04 -4.9231 0.96022E+00 -0.0176 6 HS- 0.22575E-09 -9.6464 0.21676E-09 -9.6640 0.96020E+00 -0.0176 7 Al+++ 0.12669E-19 -19.8972 0.10143E-19 -19.9938 0.80062E+00 -0.0966 8 H4SiO4 0.11109E-03 -3.9543 0.11109E-03 -3.9543 0.10000E+01 0.0000 9 Ca++ 0.27877E-04 -4.5548 0.25004E-04 -4.6020 0.89693E+00 -0.0472 10 Mg++ 0.41823E-06 -6.3786 0.37509E-06 -6.4259 0.89684E+00 -0.0473 11 Fe++ 0.25842E-08 -8.5877 0.23177E-08 -8.6349 0.89686E+00 -0.0473 12 K+ 0.25468E-05 -5.5940 0.24455E-05 -5.6116 0.96023E+00 -0.0176 13 Na+ 0.17511E-03 -3.7567 0.16814E-03 -3.7743 0.96019E+00 -0.0176 14 Mn++ 0.12011E-06 -6.9204 0.10772E-06 -6.9677 0.89688E+00 -0.0473 15 HPO4-- 0.35287E-08 -8.4524 0.31655E-08 -8.4996 0.89707E+00 -0.0472 16 HSiO3- 0.48149E-05 -5.3174 0.46233E-05 -5.3351 0.96019E+00 -0.0176 17 Ca(HSiO3)+ 0.26973E-08 -8.5691 0.25900E-08 -8.5867 0.96023E+00 -0.0176 18 Mg(HSiO3)+ 0.50356E-10 -10.2979 0.48354E-10 -10.3156 0.96023E+00 -0.0176 19 NaHSiO3,aq 0.12346E-07 -7.9085 0.12346E-07 -7.9085 0.10000E+01 0.0000 20 AlO+ 0.24812E-11 -11.6053 0.23825E-11 -11.6230 0.96023E+00 -0.0176 21 AlOH+2 0.31196E-15 -15.5059 0.27980E-15 -15.5532 0.89690E+00 -0.0473 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.20173E-05 -5.6952 0.19369E-05 -5.7129 0.96016E+00 -0.0177 24 CH4,aq 0.11176E-15 -15.9517 0.11175E-15 -15.9517 0.99991E+00 0.0000 29 CO,aq 0.24579E-16 -16.6094 0.24579E-16 -16.6094 0.10000E+01 0.0000 30 CO2,aq 0.56426E-06 -6.2485 0.56421E-06 -6.2486 0.99991E+00 0.0000 31 CO3-2 0.52480E-07 -7.2800 0.47076E-07 -7.3272 0.89703E+00 -0.0472 32 CaCO3,aq 0.14416E-07 -7.8411 0.14416E-07 -7.8411 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.78316E-08 -8.1061 0.75202E-08 -8.1238 0.96023E+00 -0.0176 34 CaCl+ 0.54966E-08 -8.2599 0.52780E-08 -8.2775 0.96023E+00 -0.0176 35 CaCl2,aq 0.16279E-12 -12.7884 0.16279E-12 -12.7884 0.10000E+01 0.0000 36 CaOH+ 0.78318E-07 -7.1061 0.75204E-07 -7.1238 0.96023E+00 -0.0176 37 CaSO4,aq 0.17699E-06 -6.7521 0.17699E-06 -6.7521 0.10000E+01 0.0000 38 HCl,aq 0.58416E-12 -12.2335 0.58416E-12 -12.2335 0.10000E+01 0.0000 43 FeCl+ 0.49800E-12 -12.3028 0.47820E-12 -12.3204 0.96023E+00 -0.0176 46 FeO,aq 0.16676E-09 -9.7779 0.16676E-09 -9.7779 0.10000E+01 0.0000 47 FeOH+ 0.34132E-08 -8.4668 0.32775E-08 -8.4845 0.96023E+00 -0.0176 48 HFeO2- 0.79679E-10 -10.0987 0.76507E-10 -10.1163 0.96019E+00 -0.0176 49 FeO+ 0.20196E-12 -12.6947 0.19393E-12 -12.7124 0.96023E+00 -0.0176 50 FeOH+2 0.94327E-18 -18.0254 0.84602E-18 -18.0726 0.89690E+00 -0.0473 51 FeO2- 0.72224E-10 -10.1413 0.69349E-10 -10.1590 0.96019E+00 -0.0176 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.16916E-08 -8.7717 0.16914E-08 -8.7717 0.99991E+00 0.0000 54 KCl,aq 0.57362E-11 -11.2414 0.57362E-11 -11.2414 0.10000E+01 0.0000 55 KHSO4,aq 0.34855E-17 -17.4577 0.34855E-17 -17.4577 0.10000E+01 0.0000 56 KOH,aq 0.45476E-10 -10.3422 0.45476E-10 -10.3422 0.10000E+01 0.0000 57 KSO4- 0.89145E-09 -9.0499 0.85597E-09 -9.0675 0.96019E+00 -0.0176 58 MgCO3,aq 0.54039E-10 -10.2673 0.54039E-10 -10.2673 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11980E-09 -9.9215 0.11504E-09 -9.9392 0.96023E+00 -0.0176 60 MgCl+ 0.74855E-10 -10.1258 0.71879E-10 -10.1434 0.96023E+00 -0.0176 61 MgOH+ 0.65089E-08 -8.1865 0.62501E-08 -8.2041 0.96023E+00 -0.0176 63 MnO,aq 0.20690E-09 -9.6842 0.20690E-09 -9.6842 0.10000E+01 0.0000 64 MnOH+ 0.14737E-07 -7.8316 0.14151E-07 -7.8492 0.96023E+00 -0.0176 65 MnO2-2 0.14513E-16 -16.8382 0.13019E-16 -16.8854 0.89703E+00 -0.0472 66 HMnO2- 0.68870E-13 -13.1620 0.66128E-13 -13.1796 0.96019E+00 -0.0176 69 MnCl+ 0.89944E-10 -10.0460 0.86367E-10 -10.0637 0.96023E+00 -0.0176 70 MnSO4,aq 0.69358E-09 -9.1589 0.69358E-09 -9.1589 0.10000E+01 0.0000 71 NaCl,aq 0.72729E-08 -8.1383 0.72729E-08 -8.1383 0.10000E+01 0.0000 72 NaOH,aq 0.31514E-08 -8.5015 0.31514E-08 -8.5015 0.10000E+01 0.0000 74 OH- 0.26648E-04 -4.5743 0.25586E-04 -4.5920 0.96016E+00 -0.0177 79 HPO3-2 0.18853E-19 -19.7246 0.16912E-19 -19.7718 0.89703E+00 -0.0472 82 H3PO4,aq 0.11201E-13 -13.9507 0.11201E-13 -13.9507 0.10000E+01 0.0000 83 H2PO4- 0.13550E-08 -8.8681 0.13011E-08 -8.8857 0.96021E+00 -0.0176 84 PO4-3 0.14713E-12 -12.8323 0.11792E-12 -12.9284 0.80146E+00 -0.0961 87 H2P2O7-2 0.14770E-18 -18.8306 0.13249E-18 -18.8778 0.89703E+00 -0.0472 88 HP2O7-3 0.14474E-17 -17.8394 0.11588E-17 -17.9360 0.80063E+00 -0.0966 89 P2O7-4 0.17847E-19 -19.7484 0.12194E-19 -19.9138 0.68327E+00 -0.1654 90 H2S,aq 0.15270E-10 -10.8162 0.15268E-10 -10.8162 0.99991E+00 0.0000 96 SO2,aq 0.88487E-19 -19.0531 0.88487E-19 -19.0531 0.10000E+01 0.0000 97 SO3-2 0.58391E-14 -14.2337 0.52395E-14 -14.2807 0.89731E+00 -0.0471 98 HSO3- 0.74865E-14 -14.1257 0.71885E-14 -14.1434 0.96019E+00 -0.0176 99 HSO4- 0.51464E-09 -9.2885 0.49419E-09 -9.3061 0.96025E+00 -0.0176 101 S2O3-2 0.45574E-17 -17.3413 0.40881E-17 -17.3885 0.89703E+00 -0.0472 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2441271E-07 -.3919230E-04 -.3950259E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999754E+06 0.0000 3 Cl- 0.1379619E-03 0.1379748E-03 0.4891510E+01 3.7521 4 SO4-- 0.2532526E-04 0.2550396E-04 0.2449895E+01 10.6163 5 HCO3- 0.1243090E-04 0.1307006E-04 0.7974803E+00 2.7068 6 HS- 0.2257466E-09 0.6294303E-09 0.2081604E-04 -2.0340 7 Al+++ 0.1266928E-19 0.2037601E-05 0.5497629E-01 2.8961 8 H4SiO4 0.1110909E-03 0.1159209E-03 0.1114153E+02 -3.9543 9 Ca++ 0.2787694E-04 0.2816269E-04 0.1128679E+01 10.6579 10 Mg++ 0.4182307E-06 0.4250386E-06 0.1033330E-01 8.8341 11 Fe++ 0.2584241E-08 0.6520318E-08 0.3641319E-03 6.6250 12 K+ 0.2546840E-05 0.2547783E-05 0.9962112E-01 2.0183 13 Na+ 0.1751120E-03 0.1751347E-03 0.4026221E+01 3.8556 14 Mn++ 0.1201099E-06 0.1358378E-06 0.7462487E-02 8.2923 15 HPO4-- 0.3528733E-08 0.4883896E-08 0.4687407E-03 6.7604 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1856622E-03 -.3919212E-04 -.1464701E-03 0.0000000E+00 2 H2O 0.5550810E+02 0.5550802E+02 0.8289220E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2583703E-04 0.2550384E-04 0.3331903E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3325609E-06 0.6294274E-09 -.3331903E-06 0.0000000E+00 7 Al+++ 0.3912890E-04 0.2037592E-05 0.3709131E-04 0.0000000E+00 8 H4SiO4 0.1249534E-03 0.1159204E-03 0.9033035E-05 0.0000000E+00 9 Ca++ 0.2827277E-04 0.2816256E-04 0.1102117E-06 0.0000000E+00 10 Mg++ 0.9523810E-05 0.4250366E-06 0.9098773E-05 0.0000000E+00 11 Fe++ 0.8556103E-05 0.6520287E-08 0.8549583E-05 0.0000000E+00 12 K+ 0.2547771E-05 0.2547771E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1751339E-03 0.1751339E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2080632E-06 0.1358372E-06 0.7222598E-07 0.0000000E+00 15 HPO4-- 0.7101092E-07 0.4883873E-08 0.6612705E-07 0.0000000E+00 Chg. balance for solid moles: -.7306E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0120000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2204E-07 -7.657 0.1107E-04 -4.956 0.2804 0.3518E-05 clinochlore 0.1820E-05 -5.740 0.1011E-02 -2.995 25.61 0.3847E-03 daphnite 0.1177E-05 -5.929 0.8397E-03 -3.076 21.26 0.2544E-03 chlorite-Mn 0.1445E-07 -7.840 0.1024E-04 -4.990 0.2593 0.3264E-05 diaspore 0.3107E-04 -4.508 0.1864E-02 -2.730 47.20 0.5549E-03 hematite 0.1333E-05 -5.875 0.2128E-03 -3.672 5.390 0.4034E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6044E+00 0.6044E+00 1.0000 -0.219 daphnite 0.3908E+00 0.3908E+00 1.0000 -0.408 chlorite-Mn 0.4797E-02 0.4797E-02 1.0000 -2.319 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.003949 g Volume = 0.001241 cm3 Porosity: 99.8765% V(tot) - V(min): 0.10036E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0120000 g log = -1.9208 Original solution: 1000.0103000 g Original solution / Rock added: 83334.19 (Water/Rock Ratio), log = 4.9208 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.6095E-04 1.0073 0.6458E-04 0.6411E-04 CH4,gas 0.1658E-12 1.0129 0.1767E-12 0.1745E-12 H2,gas 0.2204E-05 1.0006 0.2320E-05 0.2319E-05 H2S,gas 0.4250E-09 0.9959 0.4453E-09 0.4471E-09 S2,gas 0.1312E-26 1.0000 0.1380E-26 0.1380E-26 CO,gas 0.3689E-13 1.0000 0.3881E-13 0.3881E-13 SO3,gas 0.4437E-35 1.0000 0.4668E-35 0.4668E-35 SO2,gas 0.3894E-18 1.0000 0.4097E-18 0.4097E-18 HCl,gas 0.9805E-15 1.0000 0.1031E-14 0.1031E-14 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.55 -6.19 -2.063 0.10569E+05 -4.190 3 CH4,gas 4.81 -9.94 -14.75 -3.688 0.25190E+05 -12.753 4 H2,gas 8.29 0.65 -7.63 -4.363 0.13036E+05 -5.635 5 H2S,gas -5.94 -17.29 -11.35 -5.676 0.19382E+05 -9.351 6 S2,gas -7.03 -35.89 -28.86 -4.440 0.49278E+05 -26.860 7 CO,gas 3.51 -11.90 -15.41 -4.742 0.26314E+05 -13.411 8 SO3,gas 17.43 -19.90 -37.33 -9.333 0.63741E+05 -35.331 9 SO2,gas 1.14 -19.25 -20.39 -5.437 0.34811E+05 -18.388 10 HCl,gas 5.48 -11.51 -16.99 -8.493 0.29004E+05 -14.987 16 albite -0.33 -5.11 -4.78 -0.368 0.81666E+04 20 analcite 3.37 -1.16 -4.53 -0.503 0.77307E+04 21 andalusite 5.06 1.84 -3.22 -0.322 0.55058E+04 24 anhydrite -5.28 -9.25 -3.97 -1.983 0.67716E+04 29 anorthite 12.80 8.54 -4.26 -0.327 0.72673E+04 35 aragonite 0.99 -1.90 -2.88 -0.960 0.49199E+04 36 brucite 12.58 8.83 -3.74 -0.749 0.63903E+04 37 calcite 0.83 -1.90 -2.73 -0.909 0.46585E+04 40 carpholite-Mg 8.65 6.72 -1.93 -0.129 0.33002E+04 41 carpholite-Fe 6.78 4.51 -2.27 -0.152 0.38834E+04 50 chloritoid-Mg 13.26 10.67 -2.59 -0.173 0.44212E+04 51 chloritoid-Fe 9.24 8.46 -0.78 -0.052 0.13247E+04 52 chloritoid-Mn 11.46 10.13 -1.33 -0.089 0.22762E+04 54 coesite -2.37 -3.95 -1.58 -0.528 0.27063E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.95 -1.41 -0.468 0.23992E+04 67 diopside 16.22 11.58 -4.63 -0.463 0.79092E+04 68 hedenbergite 14.24 9.37 -4.87 -0.487 0.83156E+04 75 epidote 24.78 21.54 -3.23 -0.157 0.55174E+04 76 clinozoisite 22.92 18.14 -4.78 -0.217 0.81617E+04 77 epidote-Fe 29.94 24.95 -4.99 -0.259 0.85205E+04 78 fayalite 14.08 9.30 -4.78 -0.683 0.81673E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.97 -4.23 -0.352 0.72189E+04 92 hercynite 17.34 12.42 -4.93 -0.328 0.84133E+04 98 kaolinite -1.27 -2.12 -0.84 -0.077 0.14400E+04 99 kyanite 4.93 1.84 -3.09 -0.309 0.52826E+04 101 laumontite 2.97 0.63 -2.34 -0.156 0.39984E+04 102 lawsonite 9.68 8.54 -1.14 -0.076 0.19412E+04 105 lizardite 23.29 18.59 -4.69 -0.391 0.80146E+04 106 magnesite 0.71 -3.72 -4.43 -1.476 0.75612E+04 107 magnetite 20.13 19.22 -0.91 -0.074 0.15541E+04 110 magnesioferrite 26.26 21.43 -4.83 -0.394 0.82395E+04 113 margarite 17.45 14.33 -3.12 -0.125 0.53241E+04 116 microcline -2.43 -6.95 -4.52 -0.347 0.77122E+04 120 muscovite 2.68 -1.16 -3.84 -0.226 0.65491E+04 121 paragonite 4.34 0.68 -3.66 -0.215 0.62420E+04 136 prehnite 19.47 15.25 -4.22 -0.248 0.72076E+04 137 prehnite-Fe 22.59 18.65 -3.94 -0.237 0.67256E+04 145 pyroxmangite 7.42 4.34 -3.08 -0.616 0.52558E+04 146 pyrophyllite -6.10 -10.03 -3.93 -0.245 0.67054E+04 147 quartz -2.98 -3.95 -0.97 -0.324 0.16602E+04 152 rhodochrosite -0.96 -4.26 -3.30 -1.101 0.56386E+04 153 rhodonite 7.46 4.34 -3.12 -0.625 0.53350E+04 156 siderite -2.59 -5.93 -3.34 -1.113 0.57037E+04 157 sillimanite 5.32 1.84 -3.48 -0.348 0.59480E+04 164 stilbite -7.41 -11.23 -3.82 -0.182 0.65298E+04 165 stilpnomelane-Fe 13.18 8.29 -4.89 -0.146 0.83454E+04 169 sudoite 21.22 17.39 -3.83 -0.123 0.65339E+04 178 topaz-H 4.67 1.84 -2.83 -0.257 0.48316E+04 179 tridymite -2.61 -3.95 -1.34 -0.447 0.22875E+04 188 wairakite 4.06 0.63 -3.43 -0.202 0.58492E+04 189 walstromite 11.53 6.70 -4.82 -0.965 0.82373E+04 190 wollastonite 10.48 6.70 -3.78 -0.756 0.64512E+04 191 pseudo-wollastonite 11.02 6.70 -4.32 -0.863 0.73698E+04 192 zoisite 22.96 18.14 -4.82 -0.219 0.82342E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -6.01 -4.45 -0.275 0.75918E+04 197 beidellite-Mg -1.71 -6.31 -4.60 -0.285 0.78543E+04 200 chalcedony -2.79 -3.95 -1.16 -0.387 0.19805E+04 202 montmorillonite-Ca -2.21 -6.31 -4.09 -0.253 0.69887E+04 204 montmorillonite-Mg -2.40 -6.61 -4.21 -0.260 0.71822E+04 205 montmorillonite-Na -1.96 -6.79 -4.83 -0.296 0.82515E+04 206 nontronite-Ca 3.28 0.80 -2.48 -0.161 0.42347E+04 207 nontronite-H 2.60 -0.96 -3.55 -0.238 0.60697E+04 208 nontronite-K 3.40 -0.29 -3.70 -0.237 0.63122E+04 209 nontronite-Mg 3.14 0.50 -2.64 -0.171 0.45089E+04 210 nontronite-Na 3.58 0.31 -3.27 -0.210 0.55826E+04 215 gypsum -4.92 -9.25 -4.32 -1.080 0.73784E+04 225 tobermorite 9.84 4.92 -4.92 -1.341 0.83927E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.62 -3.20 -0.800 0.54626E+04 241 silica-amorphous -2.08 -3.95 -1.87 -0.625 0.32007E+04 243 an20ab80 2.08 -2.38 -4.46 -0.343 0.76152E+04 244 an25ab75 2.71 -1.70 -4.41 -0.339 0.75252E+04 245 an30ab70 3.34 -1.02 -4.36 -0.335 0.74436E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0120000 g New total amount of reactant added: 0.0124000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0124000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2834742E-03 Osmotic coef. = 0.9899 True ionic strength = .2902547E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.23546E-07 -7.6281 0.22610E-07 -7.6457 0.96025E+00 -0.0176 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13246E-03 -3.8779 0.96013E+00 -0.0177 4 SO4-- 0.25323E-04 -4.5965 0.22710E-04 -4.6438 0.89682E+00 -0.0473 5 HCO3- 0.12447E-04 -4.9049 0.11951E-04 -4.9226 0.96016E+00 -0.0177 6 HS- 0.18244E-09 -9.7389 0.17517E-09 -9.7565 0.96013E+00 -0.0177 7 Al+++ 0.11372E-19 -19.9442 0.90990E-20 -20.0410 0.80012E+00 -0.0968 8 H4SiO4 0.11458E-03 -3.9409 0.11458E-03 -3.9409 0.10000E+01 0.0000 9 Ca++ 0.28324E-04 -4.5478 0.25398E-04 -4.5952 0.89668E+00 -0.0474 10 Mg++ 0.38258E-06 -6.4173 0.34301E-06 -6.4647 0.89659E+00 -0.0474 11 Fe++ 0.23519E-08 -8.6286 0.21087E-08 -8.6760 0.89661E+00 -0.0474 12 K+ 0.26317E-05 -5.5798 0.25269E-05 -5.5974 0.96016E+00 -0.0177 13 Na+ 0.17561E-03 -3.7554 0.16861E-03 -3.7731 0.96012E+00 -0.0177 14 Mn++ 0.11823E-06 -6.9273 0.10601E-06 -6.9747 0.89663E+00 -0.0474 15 HPO4-- 0.32768E-08 -8.4846 0.29387E-08 -8.5318 0.89682E+00 -0.0473 16 HSiO3- 0.51499E-05 -5.2882 0.49445E-05 -5.3059 0.96013E+00 -0.0177 17 Ca(HSiO3)+ 0.29304E-08 -8.5331 0.28137E-08 -8.5507 0.96017E+00 -0.0177 18 Mg(HSiO3)+ 0.49254E-10 -10.3076 0.47292E-10 -10.3252 0.96017E+00 -0.0177 19 NaHSiO3,aq 0.13241E-07 -7.8781 0.13241E-07 -7.8781 0.10000E+01 0.0000 20 AlO+ 0.23931E-11 -11.6210 0.22977E-11 -11.6387 0.96017E+00 -0.0177 21 AlOH+2 0.29025E-15 -15.5372 0.26025E-15 -15.5846 0.89665E+00 -0.0474 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.20918E-05 -5.6795 0.20083E-05 -5.6972 0.96009E+00 -0.0177 24 CH4,aq 0.90467E-16 -16.0435 0.90459E-16 -16.0435 0.99991E+00 0.0000 29 CO,aq 0.22710E-16 -16.6438 0.22710E-16 -16.6438 0.10000E+01 0.0000 30 CO2,aq 0.54487E-06 -6.2637 0.54482E-06 -6.2637 0.99991E+00 0.0000 31 CO3-2 0.54499E-07 -7.2636 0.48873E-07 -7.3109 0.89678E+00 -0.0473 32 CaCO3,aq 0.15203E-07 -7.8181 0.15203E-07 -7.8181 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.79656E-08 -8.0988 0.76483E-08 -8.1164 0.96017E+00 -0.0177 34 CaCl+ 0.55832E-08 -8.2531 0.53608E-08 -8.2708 0.96017E+00 -0.0177 35 CaCl2,aq 0.16534E-12 -12.7816 0.16534E-12 -12.7816 0.10000E+01 0.0000 36 CaOH+ 0.82493E-07 -7.0836 0.79207E-07 -7.1012 0.96017E+00 -0.0177 37 CaSO4,aq 0.17971E-06 -6.7454 0.17971E-06 -6.7454 0.10000E+01 0.0000 38 HCl,aq 0.56334E-12 -12.2492 0.56334E-12 -12.2492 0.10000E+01 0.0000 43 FeCl+ 0.45310E-12 -12.3438 0.43505E-12 -12.3615 0.96017E+00 -0.0177 46 FeO,aq 0.16312E-09 -9.7875 0.16312E-09 -9.7875 0.10000E+01 0.0000 47 FeOH+ 0.32203E-08 -8.4921 0.30920E-08 -8.5098 0.96017E+00 -0.0177 48 HFeO2- 0.80821E-10 -10.0925 0.77598E-10 -10.1101 0.96013E+00 -0.0177 49 FeO+ 0.19479E-12 -12.7104 0.18703E-12 -12.7281 0.96017E+00 -0.0177 50 FeOH+2 0.87761E-18 -18.0567 0.78690E-18 -18.1041 0.89665E+00 -0.0474 51 FeO2- 0.74893E-10 -10.1256 0.71907E-10 -10.1432 0.96013E+00 -0.0177 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.16186E-08 -8.7909 0.16185E-08 -8.7909 0.99991E+00 0.0000 54 KCl,aq 0.59266E-11 -11.2272 0.59266E-11 -11.2272 0.10000E+01 0.0000 55 KHSO4,aq 0.34720E-17 -17.4594 0.34720E-17 -17.4594 0.10000E+01 0.0000 56 KOH,aq 0.48721E-10 -10.3123 0.48721E-10 -10.3123 0.10000E+01 0.0000 57 KSO4- 0.92081E-09 -9.0358 0.88410E-09 -9.0535 0.96013E+00 -0.0177 58 MgCO3,aq 0.51305E-10 -10.2898 0.51305E-10 -10.2898 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10970E-09 -9.9598 0.10533E-09 -9.9774 0.96017E+00 -0.0177 60 MgCl+ 0.68455E-10 -10.1646 0.65728E-10 -10.1822 0.96017E+00 -0.0177 61 MgOH+ 0.61723E-08 -8.2096 0.59264E-08 -8.2272 0.96017E+00 -0.0177 63 MnO,aq 0.21890E-09 -9.6597 0.21890E-09 -9.6597 0.10000E+01 0.0000 64 MnOH+ 0.15039E-07 -7.8228 0.14440E-07 -7.8404 0.96017E+00 -0.0177 65 MnO2-2 0.16513E-16 -16.7822 0.14809E-16 -16.8295 0.89678E+00 -0.0473 66 HMnO2- 0.75557E-13 -13.1217 0.72544E-13 -13.1394 0.96013E+00 -0.0177 69 MnCl+ 0.88511E-10 -10.0530 0.84986E-10 -10.0707 0.96017E+00 -0.0177 70 MnSO4,aq 0.68227E-09 -9.1660 0.68227E-09 -9.1660 0.10000E+01 0.0000 71 NaCl,aq 0.72927E-08 -8.1371 0.72927E-08 -8.1371 0.10000E+01 0.0000 72 NaOH,aq 0.32768E-08 -8.4846 0.32768E-08 -8.4846 0.10000E+01 0.0000 74 OH- 0.27632E-04 -4.5586 0.26530E-04 -4.5763 0.96009E+00 -0.0177 79 HPO3-2 0.16752E-19 -19.7759 0.15022E-19 -19.8233 0.89678E+00 -0.0473 82 H3PO4,aq 0.96717E-14 -14.0145 0.96717E-14 -14.0145 0.10000E+01 0.0000 83 H2PO4- 0.12132E-08 -8.9161 0.11649E-08 -8.9337 0.96015E+00 -0.0177 84 PO4-3 0.14171E-12 -12.8486 0.11351E-12 -12.9450 0.80097E+00 -0.0964 87 H2P2O7-2 0.11843E-18 -18.9265 0.10620E-18 -18.9739 0.89678E+00 -0.0473 88 HP2O7-3 0.12038E-17 -17.9195 0.96318E-18 -18.0163 0.80013E+00 -0.0968 89 P2O7-4 0.15398E-19 -19.8125 0.10509E-19 -19.9784 0.68251E+00 -0.1659 90 H2S,aq 0.11901E-10 -10.9244 0.11900E-10 -10.9245 0.99991E+00 0.0000 96 SO2,aq 0.78723E-19 -19.1039 0.78723E-19 -19.1039 0.10000E+01 0.0000 97 SO3-2 0.55866E-14 -14.2529 0.50115E-14 -14.3000 0.89706E+00 -0.0472 98 HSO3- 0.69065E-14 -14.1607 0.66311E-14 -14.1784 0.96013E+00 -0.0177 99 HSO4- 0.49618E-09 -9.3044 0.47643E-09 -9.3220 0.96019E+00 -0.0176 101 S2O3-2 0.35516E-17 -17.4496 0.31850E-17 -17.4969 0.89678E+00 -0.0473 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2354601E-07 -.4083857E-04 -.4116188E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999750E+06 0.0000 3 Cl- 0.1379618E-03 0.1379748E-03 0.4891509E+01 3.7678 4 SO4-- 0.2532259E-04 0.2550403E-04 0.2449901E+01 10.6476 5 HCO3- 0.1244736E-04 0.1307006E-04 0.7974801E+00 2.7231 6 HS- 0.1824438E-09 0.5641772E-09 0.1865804E-04 -2.1108 7 Al+++ 0.1137203E-19 0.2112146E-05 0.5698755E-01 2.8961 8 H4SiO4 0.1145843E-03 0.1197504E-03 0.1150959E+02 -3.9409 9 Ca++ 0.2832427E-04 0.2861815E-04 0.1146932E+01 10.6962 10 Mg++ 0.3825761E-06 0.3890271E-06 0.9457807E-02 8.8267 11 Fe++ 0.2351897E-08 0.6095107E-08 0.3403856E-03 6.6154 12 K+ 0.2631734E-05 0.2632709E-05 0.1029418E+00 2.0483 13 Na+ 0.1756131E-03 0.1756369E-03 0.4037763E+01 3.8726 14 Mn++ 0.1182301E-06 0.1342585E-06 0.7375720E-02 8.3167 15 HPO4-- 0.3276779E-08 0.4490179E-08 0.4309529E-03 6.7595 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1922856E-03 -.4083838E-04 -.1514472E-03 0.0000000E+00 2 H2O 0.5550809E+02 0.5550801E+02 0.8566457E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2584812E-04 0.2550391E-04 0.3442104E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3436463E-06 0.5641745E-09 -.3442104E-06 0.0000000E+00 7 Al+++ 0.4043320E-04 0.2112136E-05 0.3832106E-04 0.0000000E+00 8 H4SiO4 0.1291185E-03 0.1197498E-03 0.9368708E-05 0.0000000E+00 9 Ca++ 0.2873283E-04 0.2861802E-04 0.1148130E-06 0.0000000E+00 10 Mg++ 0.9841270E-05 0.3890252E-06 0.9452245E-05 0.0000000E+00 11 Fe++ 0.8841307E-05 0.6095078E-08 0.8835211E-05 0.0000000E+00 12 K+ 0.2632696E-05 0.2632696E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1756360E-03 0.1756360E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2149986E-06 0.1342578E-06 0.8074078E-07 0.0000000E+00 15 HPO4-- 0.7337795E-07 0.4490157E-08 0.6888779E-07 0.0000000E+00 Chg. balance for solid moles: 0.2012E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0124000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2296E-07 -7.639 0.1153E-04 -4.938 0.2823 0.3665E-05 clinochlore 0.1890E-05 -5.723 0.1051E-02 -2.978 25.72 0.3997E-03 daphnite 0.1216E-05 -5.915 0.8678E-03 -3.062 21.24 0.2630E-03 chlorite-Mn 0.1615E-07 -7.792 0.1145E-04 -4.941 0.2802 0.3648E-05 diaspore 0.3208E-04 -4.494 0.1924E-02 -2.716 47.10 0.5728E-03 hematite 0.1377E-05 -5.861 0.2199E-03 -3.658 5.382 0.4168E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6053E+00 0.6053E+00 1.0000 -0.218 daphnite 0.3895E+00 0.3895E+00 1.0000 -0.410 chlorite-Mn 0.5171E-02 0.5171E-02 1.0000 -2.286 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.004086 g Volume = 0.001285 cm3 Porosity: 99.8722% V(tot) - V(min): 0.10037E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0124000 g log = -1.9066 Original solution: 1000.0103000 g Original solution / Rock added: 80645.99 (Water/Rock Ratio), log = 4.9066 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.5885E-04 1.0073 0.6236E-04 0.6191E-04 CH4,gas 0.1342E-12 1.0129 0.1430E-12 0.1412E-12 H2,gas 0.2109E-05 1.0006 0.2220E-05 0.2219E-05 H2S,gas 0.3313E-09 0.9959 0.3471E-09 0.3485E-09 S2,gas 0.8703E-27 1.0000 0.9156E-27 0.9156E-27 CO,gas 0.3409E-13 1.0000 0.3586E-13 0.3586E-13 SO3,gas 0.4126E-35 1.0000 0.4340E-35 0.4340E-35 SO2,gas 0.3465E-18 1.0000 0.3645E-18 0.3645E-18 HCl,gas 0.9455E-15 1.0000 0.9947E-15 0.9947E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.57 -6.21 -2.068 0.10595E+05 -4.205 3 CH4,gas 4.81 -10.04 -14.84 -3.711 0.25347E+05 -12.845 4 H2,gas 8.29 0.63 -7.65 -4.374 0.13068E+05 -5.654 5 H2S,gas -5.94 -17.40 -11.46 -5.730 0.19567E+05 -9.460 6 S2,gas -7.03 -36.07 -29.04 -4.467 0.49582E+05 -27.038 7 CO,gas 3.51 -11.94 -15.45 -4.752 0.26373E+05 -13.445 8 SO3,gas 17.43 -19.94 -37.36 -9.341 0.63795E+05 -35.362 9 SO2,gas 1.14 -19.30 -20.44 -5.450 0.34898E+05 -18.438 10 HCl,gas 5.48 -11.52 -17.00 -8.501 0.29031E+05 -15.002 16 albite -0.33 -5.05 -4.73 -0.364 0.80688E+04 20 analcite 3.37 -1.11 -4.48 -0.498 0.76558E+04 21 andalusite 5.06 1.85 -3.21 -0.321 0.54828E+04 24 anhydrite -5.28 -9.24 -3.96 -1.980 0.67603E+04 29 anorthite 12.80 8.61 -4.19 -0.322 0.71561E+04 35 aragonite 0.99 -1.87 -2.86 -0.953 0.48805E+04 36 brucite 12.58 8.83 -3.75 -0.750 0.64028E+04 37 calcite 0.83 -1.87 -2.71 -0.902 0.46191E+04 40 carpholite-Mg 8.65 6.74 -1.91 -0.128 0.32668E+04 41 carpholite-Fe 6.78 4.53 -2.26 -0.150 0.38538E+04 50 chloritoid-Mg 13.26 10.68 -2.58 -0.172 0.44108E+04 51 chloritoid-Fe 9.24 8.47 -0.77 -0.051 0.13181E+04 52 chloritoid-Mn 11.46 10.17 -1.30 -0.086 0.22115E+04 54 coesite -2.37 -3.94 -1.57 -0.524 0.26833E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.94 -1.39 -0.464 0.23762E+04 67 diopside 16.22 11.64 -4.57 -0.457 0.78105E+04 68 hedenbergite 14.24 9.43 -4.81 -0.481 0.82207E+04 75 epidote 24.78 21.66 -3.11 -0.151 0.53178E+04 76 clinozoisite 22.92 18.26 -4.66 -0.212 0.79622E+04 77 epidote-Fe 29.94 25.06 -4.87 -0.253 0.83210E+04 78 fayalite 14.08 9.29 -4.79 -0.684 0.81771E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.96 -4.23 -0.352 0.72221E+04 92 hercynite 17.34 12.41 -4.94 -0.329 0.84296E+04 98 kaolinite -1.27 -2.09 -0.82 -0.074 0.13940E+04 99 kyanite 4.93 1.85 -3.08 -0.308 0.52596E+04 101 laumontite 2.97 0.72 -2.25 -0.150 0.38413E+04 102 lawsonite 9.68 8.61 -1.07 -0.071 0.18300E+04 105 lizardite 23.29 18.60 -4.69 -0.391 0.80064E+04 106 magnesite 0.71 -3.74 -4.45 -1.484 0.75997E+04 107 magnetite 20.13 19.21 -0.92 -0.075 0.15704E+04 110 magnesioferrite 26.26 21.42 -4.83 -0.395 0.82521E+04 113 margarite 17.45 14.40 -3.05 -0.122 0.52129E+04 116 microcline -2.43 -6.88 -4.45 -0.342 0.75922E+04 120 muscovite 2.68 -1.09 -3.77 -0.221 0.64291E+04 121 paragonite 4.34 0.74 -3.60 -0.212 0.61442E+04 136 prehnite 19.47 15.36 -4.10 -0.241 0.70081E+04 137 prehnite-Fe 22.59 18.76 -3.82 -0.230 0.65261E+04 145 pyroxmangite 7.42 4.38 -3.04 -0.608 0.51910E+04 146 pyrophyllite -6.10 -9.97 -3.87 -0.242 0.66135E+04 147 quartz -2.98 -3.94 -0.96 -0.320 0.16373E+04 152 rhodochrosite -0.96 -4.25 -3.29 -1.098 0.56227E+04 153 rhodonite 7.46 4.38 -3.09 -0.617 0.52702E+04 156 siderite -2.59 -5.95 -3.37 -1.122 0.57460E+04 157 sillimanite 5.32 1.85 -3.47 -0.347 0.59250E+04 164 stilbite -7.41 -11.10 -3.69 -0.176 0.63038E+04 165 stilpnomelane-Fe 13.18 8.37 -4.81 -0.144 0.82179E+04 169 sudoite 21.22 17.42 -3.80 -0.123 0.64902E+04 178 topaz-H 4.67 1.85 -2.82 -0.256 0.48087E+04 179 tridymite -2.61 -3.94 -1.33 -0.442 0.22645E+04 188 wairakite 4.06 0.72 -3.33 -0.196 0.56921E+04 189 walstromite 11.53 6.76 -4.77 -0.955 0.81490E+04 190 wollastonite 10.48 6.76 -3.73 -0.745 0.63629E+04 191 pseudo-wollastonite 11.02 6.76 -4.26 -0.853 0.72815E+04 192 zoisite 22.96 18.26 -4.71 -0.214 0.80347E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.95 -4.39 -0.272 0.74968E+04 197 beidellite-Mg -1.71 -6.26 -4.55 -0.282 0.77721E+04 200 chalcedony -2.79 -3.94 -1.15 -0.382 0.19576E+04 202 montmorillonite-Ca -2.21 -6.25 -4.04 -0.250 0.68902E+04 204 montmorillonite-Mg -2.40 -6.56 -4.16 -0.257 0.70966E+04 205 montmorillonite-Na -1.96 -6.74 -4.78 -0.292 0.81543E+04 206 nontronite-Ca 3.28 0.86 -2.42 -0.157 0.41397E+04 207 nontronite-H 2.60 -0.91 -3.51 -0.235 0.59854E+04 208 nontronite-K 3.40 -0.23 -3.64 -0.233 0.62110E+04 209 nontronite-Mg 3.14 0.55 -2.59 -0.168 0.44267E+04 210 nontronite-Na 3.58 0.37 -3.21 -0.206 0.54888E+04 215 gypsum -4.92 -9.24 -4.31 -1.079 0.73671E+04 225 tobermorite 9.84 4.97 -4.87 -1.329 0.83153E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.62 -3.21 -0.802 0.54789E+04 241 silica-amorphous -2.08 -3.94 -1.86 -0.620 0.31778E+04 243 an20ab80 2.08 -2.32 -4.40 -0.339 0.75147E+04 244 an25ab75 2.71 -1.64 -4.35 -0.334 0.74240E+04 245 an30ab70 3.34 -0.96 -4.30 -0.331 0.73417E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0124000 g New total amount of reactant added: 0.0128000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0128000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2849447E-03 Osmotic coef. = 0.9899 True ionic strength = .2920835E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.22740E-07 -7.6432 0.21835E-07 -7.6609 0.96018E+00 -0.0176 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13245E-03 -3.8779 0.96006E+00 -0.0177 4 SO4-- 0.25320E-04 -4.5965 0.22701E-04 -4.6440 0.89657E+00 -0.0474 5 HCO3- 0.12463E-04 -4.9044 0.11965E-04 -4.9221 0.96009E+00 -0.0177 6 HS- 0.14889E-09 -9.8271 0.14294E-09 -9.8448 0.96006E+00 -0.0177 7 Al+++ 0.10248E-19 -19.9894 0.81946E-20 -20.0865 0.79962E+00 -0.0971 8 H4SiO4 0.11807E-03 -3.9279 0.11807E-03 -3.9279 0.10000E+01 0.0000 9 Ca++ 0.28772E-04 -4.5410 0.25792E-04 -4.5885 0.89643E+00 -0.0475 10 Mg++ 0.35100E-06 -6.4547 0.31461E-06 -6.5022 0.89634E+00 -0.0475 11 Fe++ 0.21484E-08 -8.6679 0.19257E-08 -8.7154 0.89636E+00 -0.0475 12 K+ 0.27166E-05 -5.5660 0.26082E-05 -5.5837 0.96009E+00 -0.0177 13 Na+ 0.17611E-03 -3.7542 0.16908E-03 -3.7719 0.96006E+00 -0.0177 14 Mn++ 0.11607E-06 -6.9353 0.10404E-06 -6.9828 0.89638E+00 -0.0475 15 HPO4-- 0.30495E-08 -8.5158 0.27341E-08 -8.5632 0.89657E+00 -0.0474 16 HSiO3- 0.54953E-05 -5.2600 0.52758E-05 -5.2777 0.96006E+00 -0.0177 17 Ca(HSiO3)+ 0.31754E-08 -8.4982 0.30487E-08 -8.5159 0.96010E+00 -0.0177 18 Mg(HSiO3)+ 0.48206E-10 -10.3169 0.46283E-10 -10.3346 0.96010E+00 -0.0177 19 NaHSiO3,aq 0.14168E-07 -7.8487 0.14168E-07 -7.8487 0.10000E+01 0.0000 20 AlO+ 0.23112E-11 -11.6362 0.22190E-11 -11.6539 0.96010E+00 -0.0177 21 AlOH+2 0.27076E-15 -15.5674 0.24271E-15 -15.6149 0.89640E+00 -0.0475 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.21662E-05 -5.6643 0.20796E-05 -5.6820 0.96002E+00 -0.0177 24 CH4,aq 0.73934E-16 -16.1312 0.73928E-16 -16.1312 0.99991E+00 0.0000 29 CO,aq 0.21053E-16 -16.6767 0.21053E-16 -16.6767 0.10000E+01 0.0000 30 CO2,aq 0.52679E-06 -6.2784 0.52674E-06 -6.2784 0.99991E+00 0.0000 31 CO3-2 0.56514E-07 -7.2478 0.50667E-07 -7.2953 0.89653E+00 -0.0474 32 CaCO3,aq 0.16005E-07 -7.7957 0.16005E-07 -7.7957 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.80990E-08 -8.0916 0.77758E-08 -8.1093 0.96010E+00 -0.0177 34 CaCl+ 0.56698E-08 -8.2464 0.54436E-08 -8.2641 0.96010E+00 -0.0177 35 CaCl2,aq 0.16788E-12 -12.7750 0.16788E-12 -12.7750 0.10000E+01 0.0000 36 CaOH+ 0.86753E-07 -7.0617 0.83291E-07 -7.0794 0.96010E+00 -0.0177 37 CaSO4,aq 0.18243E-06 -6.7389 0.18243E-06 -6.7389 0.10000E+01 0.0000 38 HCl,aq 0.54398E-12 -12.2644 0.54398E-12 -12.2644 0.10000E+01 0.0000 43 FeCl+ 0.41377E-12 -12.3832 0.39726E-12 -12.4009 0.96010E+00 -0.0177 46 FeO,aq 0.15973E-09 -9.7966 0.15973E-09 -9.7966 0.10000E+01 0.0000 47 FeOH+ 0.30454E-08 -8.5164 0.29239E-08 -8.5340 0.96010E+00 -0.0177 48 HFeO2- 0.81957E-10 -10.0864 0.78683E-10 -10.1041 0.96006E+00 -0.0177 49 FeO+ 0.18813E-12 -12.7256 0.18062E-12 -12.7432 0.96010E+00 -0.0177 50 FeOH+2 0.81868E-18 -18.0869 0.73386E-18 -18.1344 0.89640E+00 -0.0475 51 FeO2- 0.77558E-10 -10.1104 0.74460E-10 -10.1281 0.96006E+00 -0.0177 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.15520E-08 -8.8091 0.15519E-08 -8.8091 0.99991E+00 0.0000 54 KCl,aq 0.61169E-11 -11.2135 0.61169E-11 -11.2135 0.10000E+01 0.0000 55 KHSO4,aq 0.34595E-17 -17.4610 0.34595E-17 -17.4610 0.10000E+01 0.0000 56 KOH,aq 0.52075E-10 -10.2834 0.52075E-10 -10.2834 0.10000E+01 0.0000 57 KSO4- 0.95015E-09 -9.0222 0.91220E-09 -9.0399 0.96006E+00 -0.0177 58 MgCO3,aq 0.48784E-10 -10.3117 0.48784E-10 -10.3117 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10074E-09 -9.9968 0.96723E-10 -10.0145 0.96010E+00 -0.0177 60 MgCl+ 0.62786E-10 -10.2021 0.60281E-10 -10.2198 0.96010E+00 -0.0177 61 MgOH+ 0.58627E-08 -8.2319 0.56287E-08 -8.2496 0.96010E+00 -0.0177 63 MnO,aq 0.23038E-09 -9.6376 0.23038E-09 -9.6376 0.10000E+01 0.0000 64 MnOH+ 0.15285E-07 -7.8157 0.14675E-07 -7.8334 0.96010E+00 -0.0177 65 MnO2-2 0.18640E-16 -16.7296 0.16711E-16 -16.7770 0.89653E+00 -0.0474 66 HMnO2- 0.82346E-13 -13.0844 0.79057E-13 -13.1021 0.96006E+00 -0.0177 69 MnCl+ 0.86871E-10 -10.0611 0.83404E-10 -10.0788 0.96010E+00 -0.0177 70 MnSO4,aq 0.66937E-09 -9.1743 0.66937E-09 -9.1743 0.10000E+01 0.0000 71 NaCl,aq 0.73125E-08 -8.1359 0.73125E-08 -8.1359 0.10000E+01 0.0000 72 NaOH,aq 0.34026E-08 -8.4682 0.34026E-08 -8.4682 0.10000E+01 0.0000 74 OH- 0.28616E-04 -4.5434 0.27472E-04 -4.5611 0.96002E+00 -0.0177 79 HPO3-2 0.14948E-19 -19.8254 0.13401E-19 -19.8729 0.89653E+00 -0.0474 82 H3PO4,aq 0.83917E-14 -14.0761 0.83917E-14 -14.0761 0.10000E+01 0.0000 83 H2PO4- 0.10901E-08 -8.9625 0.10466E-08 -8.9802 0.96008E+00 -0.0177 84 PO4-3 0.13661E-12 -12.8645 0.10935E-12 -12.9612 0.80047E+00 -0.0967 87 H2P2O7-2 0.95627E-19 -19.0194 0.85732E-19 -19.0669 0.89653E+00 -0.0474 88 HP2O7-3 0.10069E-17 -17.9970 0.80512E-18 -18.0941 0.79962E+00 -0.0971 89 P2O7-4 0.13343E-19 -19.8747 0.90966E-20 -20.0411 0.68175E+00 -0.1664 90 H2S,aq 0.93782E-11 -11.0279 0.93774E-11 -11.0279 0.99991E+00 0.0000 96 SO2,aq 0.70368E-19 -19.1526 0.70368E-19 -19.1526 0.10000E+01 0.0000 97 SO3-2 0.53562E-14 -14.2711 0.48034E-14 -14.3184 0.89681E+00 -0.0473 98 HSO3- 0.63932E-14 -14.1943 0.61379E-14 -14.2120 0.96006E+00 -0.0177 99 HSO4- 0.47902E-09 -9.3196 0.45991E-09 -9.3373 0.96012E+00 -0.0177 101 S2O3-2 0.27984E-17 -17.5531 0.25089E-17 -17.6005 0.89653E+00 -0.0474 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2274013E-07 -.4249221E-04 -.4282859E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999746E+06 0.0000 3 Cl- 0.1379617E-03 0.1379749E-03 0.4891507E+01 3.7829 4 SO4-- 0.2531991E-04 0.2550409E-04 0.2449905E+01 10.6778 5 HCO3- 0.1246251E-04 0.1307006E-04 0.7974799E+00 2.7388 6 HS- 0.1488856E-09 0.5111155E-09 0.1690321E-04 -2.1840 7 Al+++ 0.1024819E-19 0.2186580E-05 0.5899583E-01 2.8961 8 H4SiO4 0.1180695E-03 0.1235822E-03 0.1187787E+02 -3.9279 9 Ca++ 0.2877156E-04 0.2907369E-04 0.1165188E+01 10.7332 10 Mg++ 0.3509962E-06 0.3571193E-06 0.8682080E-02 8.8195 11 Fe++ 0.2148363E-08 0.5717072E-08 0.3192738E-03 6.6063 12 K+ 0.2716627E-05 0.2717636E-05 0.1062625E+00 2.0772 13 Na+ 0.1761141E-03 0.1761390E-03 0.4049305E+01 3.8889 14 Mn++ 0.1160712E-06 0.1323430E-06 0.7270488E-02 8.3389 15 HPO4-- 0.3049464E-08 0.4139746E-08 0.3973192E-03 6.7585 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1989090E-03 -.4249200E-04 -.1564170E-03 0.0000000E+00 2 H2O 0.5550809E+02 0.5550800E+02 0.8843568E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2585920E-04 0.2550396E-04 0.3552427E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3547316E-06 0.5111130E-09 -.3552427E-06 0.0000000E+00 7 Al+++ 0.4173749E-04 0.2186570E-05 0.3955092E-04 0.0000000E+00 8 H4SiO4 0.1332836E-03 0.1235816E-03 0.9702033E-05 0.0000000E+00 9 Ca++ 0.2919289E-04 0.2907354E-04 0.1193421E-06 0.0000000E+00 10 Mg++ 0.1015873E-04 0.3571176E-06 0.9801613E-05 0.0000000E+00 11 Fe++ 0.9126510E-05 0.5717044E-08 0.9120793E-05 0.0000000E+00 12 K+ 0.2717622E-05 0.2717622E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1761381E-03 0.1761381E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2219340E-06 0.1323424E-06 0.8959168E-07 0.0000000E+00 15 HPO4-- 0.7574498E-07 0.4139725E-08 0.7160526E-07 0.0000000E+00 Chg. balance for solid moles: -.1191E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0128000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2387E-07 -7.622 0.1199E-04 -4.921 0.2840 0.3810E-05 clinochlore 0.1960E-05 -5.708 0.1090E-02 -2.963 25.81 0.4145E-03 daphnite 0.1256E-05 -5.901 0.8960E-03 -3.048 21.22 0.2715E-03 chlorite-Mn 0.1792E-07 -7.747 0.1270E-04 -4.896 0.3009 0.4048E-05 diaspore 0.3308E-04 -4.480 0.1985E-02 -2.702 47.01 0.5908E-03 hematite 0.1421E-05 -5.847 0.2269E-03 -3.644 5.375 0.4301E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6062E+00 0.6062E+00 1.0000 -0.217 daphnite 0.3883E+00 0.3883E+00 1.0000 -0.411 chlorite-Mn 0.5541E-02 0.5541E-02 1.0000 -2.256 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.004222 g Volume = 0.001328 cm3 Porosity: 99.8679% V(tot) - V(min): 0.10038E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0128000 g log = -1.8928 Original solution: 1000.0103000 g Original solution / Rock added: 78125.80 (Water/Rock Ratio), log = 4.8928 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.5690E-04 1.0073 0.6030E-04 0.5986E-04 CH4,gas 0.1097E-12 1.0129 0.1169E-12 0.1154E-12 H2,gas 0.2022E-05 1.0006 0.2129E-05 0.2127E-05 H2S,gas 0.2610E-09 0.9959 0.2735E-09 0.2746E-09 S2,gas 0.5878E-27 1.0000 0.6184E-27 0.6184E-27 CO,gas 0.3160E-13 1.0000 0.3324E-13 0.3324E-13 SO3,gas 0.3846E-35 1.0000 0.4046E-35 0.4046E-35 SO2,gas 0.3097E-18 1.0000 0.3258E-18 0.3258E-18 HCl,gas 0.9130E-15 1.0000 0.9605E-15 0.9605E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.58 -6.22 -2.073 0.10620E+05 -4.220 3 CH4,gas 4.81 -10.12 -14.93 -3.733 0.25496E+05 -12.932 4 H2,gas 8.29 0.61 -7.67 -4.384 0.13100E+05 -5.672 5 H2S,gas -5.94 -17.51 -11.56 -5.782 0.19744E+05 -9.563 6 S2,gas -7.03 -36.24 -29.21 -4.494 0.49873E+05 -27.209 7 CO,gas 3.51 -11.97 -15.48 -4.763 0.26429E+05 -13.478 8 SO3,gas 17.43 -19.97 -37.39 -9.348 0.63847E+05 -35.393 9 SO2,gas 1.14 -19.35 -20.49 -5.463 0.34981E+05 -18.487 10 HCl,gas 5.48 -11.54 -17.02 -8.509 0.29057E+05 -15.017 16 albite -0.33 -5.00 -4.67 -0.359 0.79742E+04 20 analcite 3.37 -1.07 -4.44 -0.493 0.75834E+04 21 andalusite 5.06 1.86 -3.20 -0.320 0.54606E+04 24 anhydrite -5.28 -9.23 -3.95 -1.976 0.67492E+04 29 anorthite 12.80 8.67 -4.13 -0.318 0.70485E+04 35 aragonite 0.99 -1.85 -2.84 -0.945 0.48423E+04 36 brucite 12.58 8.82 -3.76 -0.751 0.64152E+04 37 calcite 0.83 -1.85 -2.68 -0.894 0.45810E+04 40 carpholite-Mg 8.65 6.76 -1.89 -0.126 0.32347E+04 41 carpholite-Fe 6.78 4.54 -2.24 -0.149 0.38250E+04 50 chloritoid-Mg 13.26 10.68 -2.58 -0.172 0.44009E+04 51 chloritoid-Fe 9.24 8.47 -0.77 -0.051 0.13114E+04 52 chloritoid-Mn 11.46 10.20 -1.26 -0.084 0.21514E+04 54 coesite -2.37 -3.93 -1.56 -0.520 0.26611E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.93 -1.38 -0.460 0.23540E+04 67 diopside 16.22 11.70 -4.52 -0.452 0.77153E+04 68 hedenbergite 14.24 9.48 -4.76 -0.476 0.81287E+04 75 epidote 24.78 21.77 -3.00 -0.146 0.51249E+04 76 clinozoisite 22.92 18.37 -4.55 -0.207 0.77692E+04 77 epidote-Fe 29.94 25.18 -4.76 -0.247 0.81281E+04 78 fayalite 14.08 9.28 -4.79 -0.685 0.81860E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.96 -4.23 -0.353 0.72244E+04 92 hercynite 17.34 12.40 -4.95 -0.330 0.84452E+04 98 kaolinite -1.27 -2.06 -0.79 -0.072 0.13496E+04 99 kyanite 4.93 1.86 -3.07 -0.307 0.52374E+04 101 laumontite 2.97 0.81 -2.16 -0.144 0.36892E+04 102 lawsonite 9.68 8.67 -1.01 -0.067 0.17224E+04 105 lizardite 23.29 18.60 -4.68 -0.390 0.79990E+04 106 magnesite 0.71 -3.76 -4.47 -1.491 0.76371E+04 107 magnetite 20.13 19.20 -0.93 -0.076 0.15860E+04 110 magnesioferrite 26.26 21.42 -4.84 -0.395 0.82645E+04 113 margarite 17.45 14.46 -2.99 -0.120 0.51053E+04 116 microcline -2.43 -6.81 -4.38 -0.337 0.74762E+04 120 muscovite 2.68 -1.02 -3.70 -0.217 0.63131E+04 121 paragonite 4.34 0.79 -3.54 -0.208 0.60496E+04 136 prehnite 19.47 15.47 -3.99 -0.235 0.68152E+04 137 prehnite-Fe 22.59 18.88 -3.71 -0.223 0.63332E+04 145 pyroxmangite 7.42 4.41 -3.00 -0.601 0.51309E+04 146 pyrophyllite -6.10 -9.92 -3.82 -0.239 0.65247E+04 147 quartz -2.98 -3.93 -0.95 -0.315 0.16150E+04 152 rhodochrosite -0.96 -4.24 -3.29 -1.095 0.56099E+04 153 rhodonite 7.46 4.41 -3.05 -0.610 0.52101E+04 156 siderite -2.59 -5.98 -3.39 -1.130 0.57866E+04 157 sillimanite 5.32 1.86 -3.46 -0.346 0.59028E+04 164 stilbite -7.41 -10.97 -3.56 -0.170 0.60851E+04 165 stilpnomelane-Fe 13.18 8.44 -4.74 -0.141 0.80934E+04 169 sudoite 21.22 17.44 -3.78 -0.122 0.64482E+04 178 topaz-H 4.67 1.86 -2.80 -0.255 0.47865E+04 179 tridymite -2.61 -3.93 -1.31 -0.438 0.22423E+04 188 wairakite 4.06 0.81 -3.24 -0.191 0.55400E+04 189 walstromite 11.53 6.81 -4.72 -0.945 0.80636E+04 190 wollastonite 10.48 6.81 -3.68 -0.735 0.62775E+04 191 pseudo-wollastonite 11.02 6.81 -4.21 -0.843 0.71961E+04 192 zoisite 22.96 18.37 -4.59 -0.209 0.78417E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.90 -4.34 -0.268 0.74048E+04 197 beidellite-Mg -1.71 -6.21 -4.51 -0.279 0.76926E+04 200 chalcedony -2.79 -3.93 -1.13 -0.378 0.19354E+04 202 montmorillonite-Ca -2.21 -6.19 -3.98 -0.246 0.67950E+04 204 montmorillonite-Mg -2.40 -6.51 -4.11 -0.254 0.70138E+04 205 montmorillonite-Na -1.96 -6.68 -4.72 -0.289 0.80603E+04 206 nontronite-Ca 3.28 0.91 -2.37 -0.154 0.40477E+04 207 nontronite-H 2.60 -0.86 -3.46 -0.232 0.59039E+04 208 nontronite-K 3.40 -0.18 -3.58 -0.230 0.61132E+04 209 nontronite-Mg 3.14 0.59 -2.55 -0.165 0.43472E+04 210 nontronite-Na 3.58 0.42 -3.16 -0.203 0.53980E+04 215 gypsum -4.92 -9.23 -4.31 -1.077 0.73559E+04 225 tobermorite 9.84 5.01 -4.83 -1.317 0.82405E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.61 -3.22 -0.804 0.54945E+04 241 silica-amorphous -2.08 -3.93 -1.85 -0.616 0.31555E+04 243 an20ab80 2.08 -2.26 -4.34 -0.334 0.74175E+04 244 an25ab75 2.71 -1.58 -4.29 -0.330 0.73262E+04 245 an30ab70 3.34 -0.90 -4.24 -0.326 0.72433E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0128000 g New total amount of reactant added: 0.0132000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0132000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2864212E-03 Osmotic coef. = 0.9899 True ionic strength = .2939222E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.21990E-07 -7.6578 0.21113E-07 -7.6755 0.96012E+00 -0.0177 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13244E-03 -3.8780 0.95999E+00 -0.0177 4 SO4-- 0.25317E-04 -4.5966 0.22692E-04 -4.6441 0.89632E+00 -0.0475 5 HCO3- 0.12476E-04 -4.9039 0.11978E-04 -4.9216 0.96002E+00 -0.0177 6 HS- 0.12257E-09 -9.9116 0.11767E-09 -9.9293 0.95999E+00 -0.0177 7 Al+++ 0.92704E-20 -20.0329 0.74081E-20 -20.1303 0.79911E+00 -0.0974 8 H4SiO4 0.12155E-03 -3.9153 0.12155E-03 -3.9153 0.10000E+01 0.0000 9 Ca++ 0.29219E-04 -4.5343 0.26185E-04 -4.5819 0.89618E+00 -0.0476 10 Mg++ 0.32294E-06 -6.4909 0.28938E-06 -6.5385 0.89609E+00 -0.0476 11 Fe++ 0.19692E-08 -8.7057 0.17647E-08 -8.7533 0.89611E+00 -0.0476 12 K+ 0.28015E-05 -5.5526 0.26895E-05 -5.5703 0.96003E+00 -0.0177 13 Na+ 0.17662E-03 -3.7530 0.16955E-03 -3.7707 0.95999E+00 -0.0177 14 Mn++ 0.11368E-06 -6.9443 0.10187E-06 -6.9920 0.89613E+00 -0.0476 15 HPO4-- 0.28438E-08 -8.5461 0.25490E-08 -8.5936 0.89632E+00 -0.0475 16 HSiO3- 0.58511E-05 -5.2328 0.56170E-05 -5.2505 0.95999E+00 -0.0177 17 Ca(HSiO3)+ 0.34326E-08 -8.4644 0.32954E-08 -8.4821 0.96003E+00 -0.0177 18 Mg(HSiO3)+ 0.47211E-10 -10.3260 0.45324E-10 -10.3437 0.96003E+00 -0.0177 19 NaHSiO3,aq 0.15126E-07 -7.8203 0.15126E-07 -7.8203 0.10000E+01 0.0000 20 AlO+ 0.22349E-11 -11.6507 0.21456E-11 -11.6685 0.96003E+00 -0.0177 21 AlOH+2 0.25321E-15 -15.5965 0.22692E-15 -15.6441 0.89614E+00 -0.0476 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.22405E-05 -5.6497 0.21508E-05 -5.6674 0.95995E+00 -0.0177 24 CH4,aq 0.60951E-16 -16.2150 0.60945E-16 -16.2151 0.99991E+00 0.0000 29 CO,aq 0.19577E-16 -16.7083 0.19577E-16 -16.7083 0.10000E+01 0.0000 30 CO2,aq 0.50990E-06 -6.2925 0.50985E-06 -6.2926 0.99991E+00 0.0000 31 CO3-2 0.58525E-07 -7.2327 0.52455E-07 -7.2802 0.89628E+00 -0.0476 32 CaCO3,aq 0.16823E-07 -7.7741 0.16823E-07 -7.7741 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.82318E-08 -8.0845 0.79028E-08 -8.1022 0.96003E+00 -0.0177 34 CaCl+ 0.57563E-08 -8.2399 0.55263E-08 -8.2576 0.96003E+00 -0.0177 35 CaCl2,aq 0.17042E-12 -12.7685 0.17042E-12 -12.7685 0.10000E+01 0.0000 36 CaOH+ 0.91096E-07 -7.0405 0.87455E-07 -7.0582 0.96003E+00 -0.0177 37 CaSO4,aq 0.18514E-06 -6.7325 0.18514E-06 -6.7325 0.10000E+01 0.0000 38 HCl,aq 0.52595E-12 -12.2791 0.52595E-12 -12.2791 0.10000E+01 0.0000 43 FeCl+ 0.37917E-12 -12.4212 0.36401E-12 -12.4389 0.96003E+00 -0.0177 46 FeO,aq 0.15655E-09 -9.8053 0.15655E-09 -9.8053 0.10000E+01 0.0000 47 FeOH+ 0.28864E-08 -8.5396 0.27710E-08 -8.5574 0.96003E+00 -0.0177 48 HFeO2- 0.83082E-10 -10.0805 0.79758E-10 -10.0982 0.95999E+00 -0.0177 49 FeO+ 0.18192E-12 -12.7401 0.17465E-12 -12.7578 0.96003E+00 -0.0177 50 FeOH+2 0.76563E-18 -18.1160 0.68612E-18 -18.1636 0.89614E+00 -0.0476 51 FeO2- 0.80216E-10 -10.0957 0.77007E-10 -10.1135 0.95999E+00 -0.0177 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.14910E-08 -8.8265 0.14908E-08 -8.8266 0.99991E+00 0.0000 54 KCl,aq 0.63072E-11 -11.2002 0.63072E-11 -11.2002 0.10000E+01 0.0000 55 KHSO4,aq 0.34481E-17 -17.4624 0.34481E-17 -17.4624 0.10000E+01 0.0000 56 KOH,aq 0.55536E-10 -10.2554 0.55536E-10 -10.2554 0.10000E+01 0.0000 57 KSO4- 0.97947E-09 -9.0090 0.94028E-09 -9.0267 0.95999E+00 -0.0177 58 MgCO3,aq 0.46456E-10 -10.3330 0.46456E-10 -10.3330 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.92767E-10 -10.0326 0.89060E-10 -10.0503 0.96003E+00 -0.0177 60 MgCl+ 0.57752E-10 -10.2384 0.55443E-10 -10.2562 0.96003E+00 -0.0177 61 MgOH+ 0.55774E-08 -8.2536 0.53545E-08 -8.2713 0.96003E+00 -0.0177 63 MnO,aq 0.24126E-09 -9.6175 0.24126E-09 -9.6175 0.10000E+01 0.0000 64 MnOH+ 0.15479E-07 -7.8103 0.14860E-07 -7.8280 0.96003E+00 -0.0177 65 MnO2-2 0.20885E-16 -16.6802 0.18718E-16 -16.7277 0.89628E+00 -0.0476 66 HMnO2- 0.89192E-13 -13.0497 0.85624E-13 -13.0674 0.95999E+00 -0.0177 69 MnCl+ 0.85056E-10 -10.0703 0.81656E-10 -10.0880 0.96003E+00 -0.0177 70 MnSO4,aq 0.65513E-09 -9.1837 0.65513E-09 -9.1837 0.10000E+01 0.0000 71 NaCl,aq 0.73322E-08 -8.1348 0.73322E-08 -8.1348 0.10000E+01 0.0000 72 NaOH,aq 0.35288E-08 -8.4524 0.35288E-08 -8.4524 0.10000E+01 0.0000 74 OH- 0.29597E-04 -4.5288 0.28411E-04 -4.5465 0.95995E+00 -0.0177 79 HPO3-2 0.13392E-19 -19.8732 0.12003E-19 -19.9207 0.89628E+00 -0.0476 82 H3PO4,aq 0.73147E-14 -14.1358 0.73147E-14 -14.1358 0.10000E+01 0.0000 83 H2PO4- 0.98280E-09 -9.0075 0.94350E-09 -9.0253 0.96001E+00 -0.0177 84 PO4-3 0.13180E-12 -12.8801 0.10544E-12 -12.9770 0.79997E+00 -0.0969 87 H2P2O7-2 0.77733E-19 -19.1094 0.69671E-19 -19.1570 0.89628E+00 -0.0476 88 HP2O7-3 0.84677E-18 -18.0722 0.67667E-18 -18.1696 0.79912E+00 -0.0974 89 P2O7-4 0.11611E-19 -19.9351 0.79068E-20 -20.1020 0.68099E+00 -0.1669 90 H2S,aq 0.74649E-11 -11.1270 0.74642E-11 -11.1270 0.99991E+00 0.0000 96 SO2,aq 0.63178E-19 -19.1994 0.63178E-19 -19.1994 0.10000E+01 0.0000 97 SO3-2 0.51449E-14 -14.2886 0.46127E-14 -14.3360 0.89656E+00 -0.0474 98 HSO3- 0.59367E-14 -14.2265 0.56992E-14 -14.2442 0.95999E+00 -0.0177 99 HSO4- 0.46303E-09 -9.3344 0.44453E-09 -9.3521 0.96005E+00 -0.0177 101 S2O3-2 0.22273E-17 -17.6522 0.19962E-17 -17.6998 0.89628E+00 -0.0476 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2198951E-07 -.4415199E-04 -.4450149E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999742E+06 0.0000 3 Cl- 0.1379616E-03 0.1379749E-03 0.4891506E+01 3.7975 4 SO4-- 0.2531723E-04 0.2550413E-04 0.2449909E+01 10.7068 5 HCO3- 0.1247645E-04 0.1307007E-04 0.7974797E+00 2.7538 6 HS- 0.1225726E-09 0.4672949E-09 0.1545400E-04 -2.2539 7 Al+++ 0.9270399E-20 0.2260840E-05 0.6099938E-01 2.8961 8 H4SiO4 0.1215464E-03 0.1274161E-03 0.1224635E+02 -3.9153 9 Ca++ 0.2921881E-04 0.2952929E-04 0.1183446E+01 10.7690 10 Mg++ 0.3229407E-06 0.3287623E-06 0.7992676E-02 8.8124 11 Fe++ 0.1969247E-08 0.5379502E-08 0.3004218E-03 6.5976 12 K+ 0.2801521E-05 0.2802562E-05 0.1095831E+00 2.1051 13 Na+ 0.1766151E-03 0.1766411E-03 0.4060846E+01 3.9048 14 Mn++ 0.1136780E-06 0.1301382E-06 0.7149362E-02 8.3590 15 HPO4-- 0.2843845E-08 0.3826784E-08 0.3672821E-03 6.7573 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2055324E-03 -.4415177E-04 -.1613806E-03 0.0000000E+00 2 H2O 0.5550808E+02 0.5550799E+02 0.9120585E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2587029E-04 0.2550400E-04 0.3662843E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3658170E-06 0.4672925E-09 -.3662843E-06 0.0000000E+00 7 Al+++ 0.4304179E-04 0.2260828E-05 0.4078096E-04 0.0000000E+00 8 H4SiO4 0.1374487E-03 0.1274154E-03 0.1003333E-04 0.0000000E+00 9 Ca++ 0.2965294E-04 0.2952913E-04 0.1238087E-06 0.0000000E+00 10 Mg++ 0.1047619E-04 0.3287606E-06 0.1014743E-04 0.0000000E+00 11 Fe++ 0.9411713E-05 0.5379475E-08 0.9406334E-05 0.0000000E+00 12 K+ 0.2802548E-05 0.2802548E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1766402E-03 0.1766402E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2288695E-06 0.1301376E-06 0.9873191E-07 0.0000000E+00 15 HPO4-- 0.7811201E-07 0.3826765E-08 0.7428525E-07 0.0000000E+00 Chg. balance for solid moles: -.2851E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0132000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2476E-07 -7.606 0.1244E-04 -4.905 0.2854 0.3952E-05 clinochlore 0.2029E-05 -5.693 0.1128E-02 -2.948 25.89 0.4291E-03 daphnite 0.1295E-05 -5.888 0.9241E-03 -3.034 21.21 0.2800E-03 chlorite-Mn 0.1975E-07 -7.705 0.1400E-04 -4.854 0.3213 0.4461E-05 diaspore 0.3409E-04 -4.467 0.2045E-02 -2.689 46.93 0.6089E-03 hematite 0.1465E-05 -5.834 0.2340E-03 -3.631 5.369 0.4435E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6068E+00 0.6068E+00 1.0000 -0.217 daphnite 0.3873E+00 0.3873E+00 1.0000 -0.412 chlorite-Mn 0.5904E-02 0.5904E-02 1.0000 -2.229 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.004358 g Volume = 0.001371 cm3 Porosity: 99.8636% V(tot) - V(min): 0.10039E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0132000 g log = -1.8794 Original solution: 1000.0103000 g Original solution / Rock added: 75758.36 (Water/Rock Ratio), log = 4.8794 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.5507E-04 1.0073 0.5836E-04 0.5794E-04 CH4,gas 0.9045E-13 1.0129 0.9638E-13 0.9515E-13 H2,gas 0.1943E-05 1.0006 0.2045E-05 0.2044E-05 H2S,gas 0.2078E-09 0.9959 0.2177E-09 0.2186E-09 S2,gas 0.4036E-27 1.0000 0.4246E-27 0.4246E-27 CO,gas 0.2938E-13 1.0000 0.3091E-13 0.3091E-13 SO3,gas 0.3595E-35 1.0000 0.3781E-35 0.3781E-35 SO2,gas 0.2781E-18 1.0000 0.2925E-18 0.2925E-18 HCl,gas 0.8828E-15 1.0000 0.9287E-15 0.9287E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.60 -6.23 -2.078 0.10644E+05 -4.234 3 CH4,gas 4.81 -10.21 -15.02 -3.754 0.25639E+05 -13.016 4 H2,gas 8.29 0.60 -7.69 -4.394 0.13129E+05 -5.689 5 H2S,gas -5.94 -17.60 -11.66 -5.831 0.19913E+05 -9.662 6 S2,gas -7.03 -36.40 -29.37 -4.519 0.50152E+05 -27.372 7 CO,gas 3.51 -12.00 -15.51 -4.772 0.26483E+05 -13.510 8 SO3,gas 17.43 -20.00 -37.42 -9.356 0.63898E+05 -35.422 9 SO2,gas 1.14 -19.40 -20.53 -5.476 0.35061E+05 -18.534 10 HCl,gas 5.48 -11.55 -17.03 -8.516 0.29082E+05 -15.032 16 albite -0.33 -4.94 -4.62 -0.355 0.78827E+04 20 analcite 3.37 -1.03 -4.40 -0.489 0.75134E+04 21 andalusite 5.06 1.88 -3.19 -0.319 0.54391E+04 24 anhydrite -5.28 -9.23 -3.95 -1.973 0.67382E+04 29 anorthite 12.80 8.73 -4.07 -0.313 0.69444E+04 35 aragonite 0.99 -1.83 -2.81 -0.938 0.48054E+04 36 brucite 12.58 8.81 -3.76 -0.753 0.64273E+04 37 calcite 0.83 -1.83 -2.66 -0.887 0.45441E+04 40 carpholite-Mg 8.65 6.77 -1.88 -0.125 0.32038E+04 41 carpholite-Fe 6.78 4.56 -2.22 -0.148 0.37968E+04 50 chloritoid-Mg 13.26 10.69 -2.57 -0.171 0.43915E+04 51 chloritoid-Fe 9.24 8.47 -0.76 -0.051 0.13048E+04 52 chloritoid-Mn 11.46 10.24 -1.23 -0.082 0.20956E+04 54 coesite -2.37 -3.92 -1.55 -0.515 0.26396E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.92 -1.37 -0.455 0.23325E+04 67 diopside 16.22 11.75 -4.46 -0.446 0.76232E+04 68 hedenbergite 14.24 9.54 -4.71 -0.471 0.80394E+04 75 epidote 24.78 21.88 -2.89 -0.140 0.49381E+04 76 clinozoisite 22.92 18.48 -4.44 -0.202 0.75824E+04 77 epidote-Fe 29.94 25.29 -4.65 -0.242 0.79413E+04 78 fayalite 14.08 9.28 -4.80 -0.686 0.81942E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.96 -4.23 -0.353 0.72260E+04 92 hercynite 17.34 12.39 -4.95 -0.330 0.84601E+04 98 kaolinite -1.27 -2.04 -0.77 -0.070 0.13066E+04 99 kyanite 4.93 1.88 -3.05 -0.305 0.52159E+04 101 laumontite 2.97 0.90 -2.07 -0.138 0.35420E+04 102 lawsonite 9.68 8.73 -0.95 -0.063 0.16182E+04 105 lizardite 23.29 18.61 -4.68 -0.390 0.79923E+04 106 magnesite 0.71 -3.78 -4.49 -1.498 0.76734E+04 107 magnetite 20.13 19.20 -0.94 -0.077 0.16009E+04 110 magnesioferrite 26.26 21.41 -4.85 -0.396 0.82766E+04 113 margarite 17.45 14.52 -2.93 -0.117 0.50012E+04 116 microcline -2.43 -6.74 -4.31 -0.332 0.73639E+04 120 muscovite 2.68 -0.95 -3.63 -0.214 0.62008E+04 121 paragonite 4.34 0.85 -3.49 -0.205 0.59580E+04 136 prehnite 19.47 15.58 -3.88 -0.228 0.66284E+04 137 prehnite-Fe 22.59 18.99 -3.60 -0.217 0.61464E+04 145 pyroxmangite 7.42 4.44 -2.97 -0.594 0.50752E+04 146 pyrophyllite -6.10 -9.87 -3.77 -0.236 0.64386E+04 147 quartz -2.98 -3.92 -0.93 -0.311 0.15935E+04 152 rhodochrosite -0.96 -4.24 -3.28 -1.093 0.55998E+04 153 rhodonite 7.46 4.44 -3.02 -0.604 0.51544E+04 156 siderite -2.59 -6.00 -3.41 -1.137 0.58256E+04 157 sillimanite 5.32 1.88 -3.44 -0.344 0.58813E+04 164 stilbite -7.41 -10.85 -3.44 -0.164 0.58734E+04 165 stilpnomelane-Fe 13.18 8.51 -4.67 -0.139 0.79718E+04 169 sudoite 21.22 17.46 -3.75 -0.121 0.64078E+04 178 topaz-H 4.67 1.88 -2.79 -0.254 0.47649E+04 179 tridymite -2.61 -3.92 -1.30 -0.434 0.22208E+04 188 wairakite 4.06 0.90 -3.16 -0.186 0.53928E+04 189 walstromite 11.53 6.85 -4.67 -0.935 0.79810E+04 190 wollastonite 10.48 6.85 -3.63 -0.726 0.61949E+04 191 pseudo-wollastonite 11.02 6.85 -4.17 -0.833 0.71135E+04 192 zoisite 22.96 18.48 -4.48 -0.204 0.76549E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.84 -4.28 -0.265 0.73158E+04 197 beidellite-Mg -1.71 -6.17 -4.46 -0.276 0.76156E+04 200 chalcedony -2.79 -3.92 -1.12 -0.374 0.19138E+04 202 montmorillonite-Ca -2.21 -6.14 -3.93 -0.243 0.67028E+04 204 montmorillonite-Mg -2.40 -6.46 -4.06 -0.251 0.69337E+04 205 montmorillonite-Na -1.96 -6.63 -4.67 -0.286 0.79693E+04 206 nontronite-Ca 3.28 0.96 -2.32 -0.150 0.39587E+04 207 nontronite-H 2.60 -0.82 -3.41 -0.229 0.58249E+04 208 nontronite-K 3.40 -0.12 -3.52 -0.226 0.60185E+04 209 nontronite-Mg 3.14 0.64 -2.50 -0.162 0.42702E+04 210 nontronite-Na 3.58 0.47 -3.11 -0.200 0.53101E+04 215 gypsum -4.92 -9.23 -4.30 -1.075 0.73450E+04 225 tobermorite 9.84 5.06 -4.78 -1.305 0.81680E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.60 -3.23 -0.807 0.55094E+04 241 silica-amorphous -2.08 -3.92 -1.84 -0.612 0.31340E+04 243 an20ab80 2.08 -2.21 -4.29 -0.330 0.73234E+04 244 an25ab75 2.71 -1.53 -4.24 -0.326 0.72315E+04 245 an30ab70 3.34 -0.84 -4.19 -0.322 0.71479E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0132000 g New total amount of reactant added: 0.0136000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0136000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2879027E-03 Osmotic coef. = 0.9899 True ionic strength = .2957695E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.21289E-07 -7.6718 0.20439E-07 -7.6895 0.96005E+00 -0.0177 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13243E-03 -3.8780 0.95992E+00 -0.0178 4 SO4-- 0.25315E-04 -4.5966 0.22684E-04 -4.6443 0.89607E+00 -0.0477 5 HCO3- 0.12489E-04 -4.9035 0.11989E-04 -4.9212 0.95995E+00 -0.0177 6 HS- 0.10172E-09 -9.9926 0.97644E-10 -10.0104 0.95993E+00 -0.0178 7 Al+++ 0.84161E-20 -20.0749 0.67212E-20 -20.1726 0.79861E+00 -0.0977 8 H4SiO4 0.12501E-03 -3.9030 0.12501E-03 -3.9030 0.10000E+01 0.0000 9 Ca++ 0.29666E-04 -4.5277 0.26579E-04 -4.5755 0.89593E+00 -0.0477 10 Mg++ 0.29794E-06 -6.5259 0.26691E-06 -6.5736 0.89584E+00 -0.0478 11 Fe++ 0.18109E-08 -8.7421 0.16223E-08 -8.7899 0.89586E+00 -0.0478 12 K+ 0.28864E-05 -5.5396 0.27708E-05 -5.5574 0.95996E+00 -0.0177 13 Na+ 0.17712E-03 -3.7517 0.17002E-03 -3.7695 0.95992E+00 -0.0178 14 Mn++ 0.11109E-06 -6.9543 0.99526E-07 -7.0021 0.89587E+00 -0.0478 15 HPO4-- 0.26574E-08 -8.5755 0.23812E-08 -8.6232 0.89607E+00 -0.0477 16 HSiO3- 0.62169E-05 -5.2064 0.59678E-05 -5.2242 0.95992E+00 -0.0178 17 Ca(HSiO3)+ 0.37020E-08 -8.4316 0.35538E-08 -8.4493 0.95996E+00 -0.0177 18 Mg(HSiO3)+ 0.46266E-10 -10.3347 0.44414E-10 -10.3525 0.95996E+00 -0.0177 19 NaHSiO3,aq 0.16115E-07 -7.7928 0.16115E-07 -7.7928 0.10000E+01 0.0000 20 AlO+ 0.21637E-11 -11.6648 0.20771E-11 -11.6825 0.95996E+00 -0.0177 21 AlOH+2 0.23737E-15 -15.6246 0.21266E-15 -15.6723 0.89589E+00 -0.0477 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.23145E-05 -5.6355 0.22217E-05 -5.6533 0.95989E+00 -0.0178 24 CH4,aq 0.50646E-16 -16.2955 0.50642E-16 -16.2955 0.99991E+00 0.0000 29 CO,aq 0.18255E-16 -16.7386 0.18255E-16 -16.7386 0.10000E+01 0.0000 30 CO2,aq 0.49410E-06 -6.3062 0.49405E-06 -6.3062 0.99991E+00 0.0000 31 CO3-2 0.60530E-07 -7.2180 0.54236E-07 -7.2657 0.89602E+00 -0.0477 32 CaCO3,aq 0.17655E-07 -7.7531 0.17655E-07 -7.7531 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.83640E-08 -8.0776 0.80291E-08 -8.0953 0.95996E+00 -0.0177 34 CaCl+ 0.58428E-08 -8.2334 0.56089E-08 -8.2511 0.95996E+00 -0.0177 35 CaCl2,aq 0.17295E-12 -12.7621 0.17295E-12 -12.7621 0.10000E+01 0.0000 36 CaOH+ 0.95519E-07 -7.0199 0.91695E-07 -7.0377 0.95996E+00 -0.0177 37 CaSO4,aq 0.18785E-06 -6.7262 0.18785E-06 -6.7262 0.10000E+01 0.0000 38 HCl,aq 0.50913E-12 -12.2932 0.50913E-12 -12.2932 0.10000E+01 0.0000 43 FeCl+ 0.34859E-12 -12.4577 0.33463E-12 -12.4754 0.95996E+00 -0.0177 46 FeO,aq 0.15357E-09 -9.8137 0.15357E-09 -9.8137 0.10000E+01 0.0000 47 FeOH+ 0.27413E-08 -8.5621 0.26315E-08 -8.5798 0.95996E+00 -0.0177 48 HFeO2- 0.84194E-10 -10.0747 0.80820E-10 -10.0925 0.95992E+00 -0.0178 49 FeO+ 0.17612E-12 -12.7542 0.16907E-12 -12.7719 0.95996E+00 -0.0177 50 FeOH+2 0.71774E-18 -18.1440 0.64302E-18 -18.1918 0.89589E+00 -0.0477 51 FeO2- 0.82867E-10 -10.0816 0.79546E-10 -10.0994 0.95992E+00 -0.0178 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.14347E-08 -8.8432 0.14346E-08 -8.8433 0.99991E+00 0.0000 54 KCl,aq 0.64974E-11 -11.1873 0.64974E-11 -11.1873 0.10000E+01 0.0000 55 KHSO4,aq 0.34376E-17 -17.4637 0.34376E-17 -17.4637 0.10000E+01 0.0000 56 KOH,aq 0.59101E-10 -10.2284 0.59101E-10 -10.2284 0.10000E+01 0.0000 57 KSO4- 0.10088E-08 -8.9962 0.96833E-09 -9.0140 0.95992E+00 -0.0178 58 MgCO3,aq 0.44302E-10 -10.3536 0.44302E-10 -10.3536 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.85650E-10 -10.0673 0.82221E-10 -10.0850 0.95996E+00 -0.0177 60 MgCl+ 0.53266E-10 -10.2736 0.51133E-10 -10.2913 0.95996E+00 -0.0177 61 MgOH+ 0.53141E-08 -8.2746 0.51014E-08 -8.2923 0.95996E+00 -0.0177 63 MnO,aq 0.25150E-09 -9.5995 0.25150E-09 -9.5995 0.10000E+01 0.0000 64 MnOH+ 0.15622E-07 -7.8063 0.14997E-07 -7.8240 0.95996E+00 -0.0177 65 MnO2-2 0.23237E-16 -16.6338 0.20821E-16 -16.6815 0.89602E+00 -0.0477 66 HMnO2- 0.96052E-13 -13.0175 0.92203E-13 -13.0353 0.95992E+00 -0.0178 69 MnCl+ 0.83098E-10 -10.0804 0.79771E-10 -10.0982 0.95996E+00 -0.0177 70 MnSO4,aq 0.63980E-09 -9.1940 0.63980E-09 -9.1940 0.10000E+01 0.0000 71 NaCl,aq 0.73520E-08 -8.1336 0.73520E-08 -8.1336 0.10000E+01 0.0000 72 NaOH,aq 0.36552E-08 -8.4371 0.36552E-08 -8.4371 0.10000E+01 0.0000 74 OH- 0.30575E-04 -4.5146 0.29348E-04 -4.5324 0.95989E+00 -0.0178 79 HPO3-2 0.12042E-19 -19.9193 0.10790E-19 -19.9670 0.89602E+00 -0.0477 82 H3PO4,aq 0.64039E-14 -14.1936 0.64039E-14 -14.1936 0.10000E+01 0.0000 83 H2PO4- 0.88886E-09 -9.0512 0.85326E-09 -9.0689 0.95994E+00 -0.0178 84 PO4-3 0.12727E-12 -12.8953 0.10174E-12 -12.9925 0.79947E+00 -0.0972 87 H2P2O7-2 0.63593E-19 -19.1966 0.56981E-19 -19.2443 0.89602E+00 -0.0477 88 HP2O7-3 0.71582E-18 -18.1452 0.57166E-18 -18.2429 0.79862E+00 -0.0977 89 P2O7-4 0.10144E-19 -19.9938 0.69001E-20 -20.1611 0.68023E+00 -0.1673 90 H2S,aq 0.59968E-11 -11.2221 0.59962E-11 -11.2221 0.99991E+00 0.0000 96 SO2,aq 0.56955E-19 -19.2445 0.56955E-19 -19.2445 0.10000E+01 0.0000 97 SO3-2 0.49504E-14 -14.3054 0.44371E-14 -14.3529 0.89631E+00 -0.0475 98 HSO3- 0.55288E-14 -14.2574 0.53072E-14 -14.2751 0.95992E+00 -0.0178 99 HSO4- 0.44811E-09 -9.3486 0.43018E-09 -9.3664 0.95998E+00 -0.0177 101 S2O3-2 0.17890E-17 -17.7474 0.16030E-17 -17.7951 0.89602E+00 -0.0477 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2128915E-07 -.4581688E-04 -.4617953E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999738E+06 0.0000 3 Cl- 0.1379616E-03 0.1379749E-03 0.4891505E+01 3.8115 4 SO4-- 0.2531455E-04 0.2550417E-04 0.2449912E+01 10.7348 5 HCO3- 0.1248929E-04 0.1307007E-04 0.7974795E+00 2.7683 6 HS- 0.1017202E-09 0.4305909E-09 0.1424015E-04 -2.3208 7 Al+++ 0.8416092E-20 0.2334871E-05 0.6299677E-01 2.8961 8 H4SiO4 0.1250149E-03 0.1312517E-03 0.1261500E+02 -3.9030 9 Ca++ 0.2966601E-04 0.2998494E-04 0.1201707E+01 10.8036 10 Mg++ 0.2979406E-06 0.3034842E-06 0.7378128E-02 8.8055 11 Fe++ 0.1810933E-08 0.5076822E-08 0.2835184E-03 6.5892 12 K+ 0.2886414E-05 0.2887489E-05 0.1129038E+00 2.1322 13 Na+ 0.1771161E-03 0.1771432E-03 0.4072388E+01 3.9200 14 Mn++ 0.1110932E-06 0.1276899E-06 0.7014859E-02 8.3770 15 HPO4-- 0.2657378E-08 0.3546373E-08 0.3403690E-03 6.7559 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2121558E-03 -.4581664E-04 -.1663392E-03 0.0000000E+00 2 H2O 0.5550808E+02 0.5550799E+02 0.9397535E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2588137E-04 0.2550404E-04 0.3773329E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3769024E-06 0.4305886E-09 -.3773329E-06 0.0000000E+00 7 Al+++ 0.4434609E-04 0.2334858E-05 0.4201123E-04 0.0000000E+00 8 H4SiO4 0.1416138E-03 0.1312510E-03 0.1036288E-04 0.0000000E+00 9 Ca++ 0.3011300E-04 0.2998478E-04 0.1282211E-06 0.0000000E+00 10 Mg++ 0.1079365E-04 0.3034826E-06 0.1049017E-04 0.0000000E+00 11 Fe++ 0.9696917E-05 0.5076796E-08 0.9691840E-05 0.0000000E+00 12 K+ 0.2887473E-05 0.2887473E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1771423E-03 0.1771423E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2358049E-06 0.1276893E-06 0.1081156E-06 0.0000000E+00 15 HPO4-- 0.8047904E-07 0.3546354E-08 0.7693269E-07 0.0000000E+00 Chg. balance for solid moles: 0.1993E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0136000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2564E-07 -7.591 0.1288E-04 -4.890 0.2867 0.4093E-05 clinochlore 0.2098E-05 -5.678 0.1166E-02 -2.933 25.95 0.4436E-03 daphnite 0.1335E-05 -5.875 0.9523E-03 -3.021 21.19 0.2886E-03 chlorite-Mn 0.2162E-07 -7.665 0.1533E-04 -4.814 0.3412 0.4885E-05 diaspore 0.3510E-04 -4.455 0.2106E-02 -2.677 46.86 0.6269E-03 hematite 0.1509E-05 -5.821 0.2410E-03 -3.618 5.364 0.4569E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6074E+00 0.6074E+00 1.0000 -0.217 daphnite 0.3864E+00 0.3864E+00 1.0000 -0.413 chlorite-Mn 0.6260E-02 0.6260E-02 1.0000 -2.203 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.004493 g Volume = 0.001414 cm3 Porosity: 99.8594% V(tot) - V(min): 0.10040E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0136000 g log = -1.8665 Original solution: 1000.0103000 g Original solution / Rock added: 73530.17 (Water/Rock Ratio), log = 4.8665 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.5337E-04 1.0073 0.5655E-04 0.5614E-04 CH4,gas 0.7515E-13 1.0129 0.8008E-13 0.7906E-13 H2,gas 0.1869E-05 1.0006 0.1968E-05 0.1967E-05 H2S,gas 0.1669E-09 0.9959 0.1749E-09 0.1756E-09 S2,gas 0.2813E-27 1.0000 0.2959E-27 0.2959E-27 CO,gas 0.2740E-13 1.0000 0.2882E-13 0.2882E-13 SO3,gas 0.3367E-35 1.0000 0.3543E-35 0.3543E-35 SO2,gas 0.2507E-18 1.0000 0.2637E-18 0.2637E-18 HCl,gas 0.8545E-15 1.0000 0.8990E-15 0.8990E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.61 -6.25 -2.083 0.10668E+05 -4.248 3 CH4,gas 4.81 -10.29 -15.10 -3.774 0.25777E+05 -13.096 4 H2,gas 8.29 0.58 -7.71 -4.403 0.13158E+05 -5.706 5 H2S,gas -5.94 -17.70 -11.76 -5.879 0.20075E+05 -9.757 6 S2,gas -7.03 -36.56 -29.53 -4.543 0.50420E+05 -27.529 7 CO,gas 3.51 -12.03 -15.54 -4.782 0.26535E+05 -13.540 8 SO3,gas 17.43 -20.02 -37.45 -9.363 0.63946E+05 -35.451 9 SO2,gas 1.14 -19.44 -20.58 -5.488 0.35138E+05 -18.579 10 HCl,gas 5.48 -11.57 -17.05 -8.523 0.29106E+05 -15.046 16 albite -0.33 -4.89 -4.56 -0.351 0.77940E+04 20 analcite 3.37 -0.99 -4.36 -0.485 0.74456E+04 21 andalusite 5.06 1.89 -3.17 -0.317 0.54182E+04 24 anhydrite -5.28 -9.22 -3.94 -1.970 0.67275E+04 29 anorthite 12.80 8.79 -4.01 -0.308 0.68435E+04 35 aragonite 0.99 -1.81 -2.79 -0.931 0.47696E+04 36 brucite 12.58 8.81 -3.77 -0.754 0.64391E+04 37 calcite 0.83 -1.81 -2.64 -0.880 0.45082E+04 40 carpholite-Mg 8.65 6.79 -1.86 -0.124 0.31739E+04 41 carpholite-Fe 6.78 4.58 -2.21 -0.147 0.37693E+04 50 chloritoid-Mg 13.26 10.69 -2.57 -0.171 0.43825E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.12982E+04 52 chloritoid-Mn 11.46 10.27 -1.20 -0.080 0.20439E+04 54 coesite -2.37 -3.90 -1.53 -0.511 0.26187E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.90 -1.35 -0.451 0.23116E+04 67 diopside 16.22 11.80 -4.41 -0.441 0.75342E+04 68 hedenbergite 14.24 9.59 -4.66 -0.466 0.79528E+04 75 epidote 24.78 21.99 -2.79 -0.135 0.47572E+04 76 clinozoisite 22.92 18.59 -4.33 -0.197 0.74015E+04 77 epidote-Fe 29.94 25.39 -4.54 -0.236 0.77603E+04 78 fayalite 14.08 9.28 -4.80 -0.686 0.82019E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.96 -4.23 -0.353 0.72270E+04 92 hercynite 17.34 12.38 -4.96 -0.331 0.84743E+04 98 kaolinite -1.27 -2.01 -0.74 -0.067 0.12648E+04 99 kyanite 4.93 1.89 -3.04 -0.304 0.51950E+04 101 laumontite 2.97 0.98 -1.99 -0.133 0.33994E+04 102 lawsonite 9.68 8.79 -0.89 -0.059 0.15173E+04 105 lizardite 23.29 18.61 -4.68 -0.390 0.79861E+04 106 magnesite 0.71 -3.81 -4.51 -1.505 0.77086E+04 107 magnetite 20.13 19.19 -0.95 -0.077 0.16151E+04 110 magnesioferrite 26.26 21.40 -4.85 -0.396 0.82884E+04 113 margarite 17.45 14.58 -2.87 -0.115 0.49003E+04 116 microcline -2.43 -6.68 -4.25 -0.327 0.72552E+04 120 muscovite 2.68 -0.89 -3.57 -0.210 0.60921E+04 121 paragonite 4.34 0.90 -3.44 -0.202 0.58693E+04 136 prehnite 19.47 15.69 -3.78 -0.222 0.64474E+04 137 prehnite-Fe 22.59 19.09 -3.49 -0.210 0.59654E+04 145 pyroxmangite 7.42 4.47 -2.94 -0.588 0.50235E+04 146 pyrophyllite -6.10 -9.82 -3.72 -0.233 0.63551E+04 147 quartz -2.98 -3.90 -0.92 -0.307 0.15727E+04 152 rhodochrosite -0.96 -4.23 -3.28 -1.092 0.55923E+04 153 rhodonite 7.46 4.47 -2.99 -0.598 0.51027E+04 156 siderite -2.59 -6.02 -3.43 -1.145 0.58632E+04 157 sillimanite 5.32 1.89 -3.43 -0.343 0.58604E+04 164 stilbite -7.41 -10.73 -3.32 -0.158 0.56681E+04 165 stilpnomelane-Fe 13.18 8.58 -4.60 -0.137 0.78530E+04 169 sudoite 21.22 17.49 -3.73 -0.120 0.63689E+04 178 topaz-H 4.67 1.89 -2.78 -0.253 0.47441E+04 179 tridymite -2.61 -3.90 -1.29 -0.429 0.21999E+04 188 wairakite 4.06 0.98 -3.07 -0.181 0.52502E+04 189 walstromite 11.53 6.90 -4.63 -0.925 0.79010E+04 190 wollastonite 10.48 6.90 -3.58 -0.716 0.61149E+04 191 pseudo-wollastonite 11.02 6.90 -4.12 -0.824 0.70335E+04 192 zoisite 22.96 18.59 -4.38 -0.199 0.74740E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.79 -4.23 -0.262 0.72294E+04 197 beidellite-Mg -1.71 -6.12 -4.42 -0.273 0.75410E+04 200 chalcedony -2.79 -3.90 -1.11 -0.370 0.18930E+04 202 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66135E+04 204 montmorillonite-Mg -2.40 -6.42 -4.02 -0.248 0.68561E+04 205 montmorillonite-Na -1.96 -6.58 -4.62 -0.283 0.78811E+04 206 nontronite-Ca 3.28 1.01 -2.27 -0.147 0.38723E+04 207 nontronite-H 2.60 -0.77 -3.37 -0.226 0.57483E+04 208 nontronite-K 3.40 -0.07 -3.47 -0.223 0.59267E+04 209 nontronite-Mg 3.14 0.68 -2.46 -0.159 0.41956E+04 210 nontronite-Na 3.58 0.52 -3.06 -0.196 0.52249E+04 215 gypsum -4.92 -9.22 -4.30 -1.074 0.73342E+04 225 tobermorite 9.84 5.10 -4.74 -1.294 0.80979E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.59 -3.23 -0.809 0.55236E+04 241 silica-amorphous -2.08 -3.90 -1.82 -0.608 0.31132E+04 243 an20ab80 2.08 -2.16 -4.24 -0.326 0.72323E+04 244 an25ab75 2.71 -1.47 -4.18 -0.322 0.71397E+04 245 an30ab70 3.34 -0.79 -4.13 -0.318 0.70556E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0136000 g New total amount of reactant added: 0.0140000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0140000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2893880E-03 Osmotic coef. = 0.9898 True ionic strength = .2976243E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.20635E-07 -7.6854 0.19809E-07 -7.7031 0.95998E+00 -0.0177 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13242E-03 -3.8780 0.95986E+00 -0.0178 4 SO4-- 0.25312E-04 -4.5967 0.22675E-04 -4.6445 0.89582E+00 -0.0478 5 HCO3- 0.12501E-04 -4.9031 0.12000E-04 -4.9208 0.95989E+00 -0.0178 6 HS- 0.85035E-10 -10.0704 0.81622E-10 -10.0882 0.95986E+00 -0.0178 7 Al+++ 0.76666E-20 -20.1154 0.61188E-20 -20.2133 0.79810E+00 -0.0979 8 H4SiO4 0.12848E-03 -3.8912 0.12848E-03 -3.8912 0.10000E+01 0.0000 9 Ca++ 0.30113E-04 -4.5212 0.26972E-04 -4.5691 0.89567E+00 -0.0479 10 Mg++ 0.27560E-06 -6.5597 0.24682E-06 -6.6076 0.89558E+00 -0.0479 11 Fe++ 0.16704E-08 -8.7772 0.14960E-08 -8.8251 0.89561E+00 -0.0479 12 K+ 0.29713E-05 -5.5271 0.28521E-05 -5.5448 0.95989E+00 -0.0178 13 Na+ 0.17762E-03 -3.7505 0.17049E-03 -3.7683 0.95985E+00 -0.0178 14 Mn++ 0.10836E-06 -6.9651 0.97047E-07 -7.0130 0.89562E+00 -0.0479 15 HPO4-- 0.24879E-08 -8.6042 0.22287E-08 -8.6520 0.89582E+00 -0.0478 16 HSiO3- 0.65926E-05 -5.1809 0.63279E-05 -5.1987 0.95986E+00 -0.0178 17 Ca(HSiO3)+ 0.39838E-08 -8.3997 0.38240E-08 -8.4175 0.95990E+00 -0.0178 18 Mg(HSiO3)+ 0.45370E-10 -10.3432 0.43550E-10 -10.3610 0.95990E+00 -0.0178 19 NaHSiO3,aq 0.17134E-07 -7.7661 0.17134E-07 -7.7661 0.10000E+01 0.0000 20 AlO+ 0.20972E-11 -11.6784 0.20131E-11 -11.6961 0.95990E+00 -0.0178 21 AlOH+2 0.22303E-15 -15.6516 0.19976E-15 -15.6995 0.89564E+00 -0.0479 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.23883E-05 -5.6219 0.22923E-05 -5.6397 0.95982E+00 -0.0178 24 CH4,aq 0.42389E-16 -16.3727 0.42385E-16 -16.3728 0.99991E+00 0.0000 29 CO,aq 0.17067E-16 -16.7679 0.17067E-16 -16.7679 0.10000E+01 0.0000 30 CO2,aq 0.47929E-06 -6.3194 0.47925E-06 -6.3194 0.99991E+00 0.0000 31 CO3-2 0.62526E-07 -7.2039 0.56010E-07 -7.2517 0.89577E+00 -0.0478 32 CaCO3,aq 0.18502E-07 -7.7328 0.18502E-07 -7.7328 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.84957E-08 -8.0708 0.81550E-08 -8.0886 0.95990E+00 -0.0178 34 CaCl+ 0.59292E-08 -8.2270 0.56914E-08 -8.2448 0.95990E+00 -0.0178 35 CaCl2,aq 0.17548E-12 -12.7558 0.17548E-12 -12.7558 0.10000E+01 0.0000 36 CaOH+ 0.10002E-06 -6.9999 0.96010E-07 -7.0177 0.95990E+00 -0.0178 37 CaSO4,aq 0.19055E-06 -6.7200 0.19055E-06 -6.7200 0.10000E+01 0.0000 38 HCl,aq 0.49341E-12 -12.3068 0.49341E-12 -12.3068 0.10000E+01 0.0000 43 FeCl+ 0.32145E-12 -12.4929 0.30856E-12 -12.5107 0.95990E+00 -0.0178 46 FeO,aq 0.15077E-09 -9.8217 0.15077E-09 -9.8217 0.10000E+01 0.0000 47 FeOH+ 0.26084E-08 -8.5836 0.25038E-08 -8.6014 0.95990E+00 -0.0178 48 HFeO2- 0.85290E-10 -10.0691 0.81866E-10 -10.0869 0.95986E+00 -0.0178 49 FeO+ 0.17071E-12 -12.7677 0.16386E-12 -12.7855 0.95990E+00 -0.0178 50 FeOH+2 0.67437E-18 -18.1711 0.60400E-18 -18.2190 0.89564E+00 -0.0479 51 FeO2- 0.85508E-10 -10.0680 0.82075E-10 -10.0858 0.95986E+00 -0.0178 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.13828E-08 -8.8592 0.13827E-08 -8.8593 0.99991E+00 0.0000 54 KCl,aq 0.66876E-11 -11.1747 0.66876E-11 -11.1747 0.10000E+01 0.0000 55 KHSO4,aq 0.34281E-17 -17.4649 0.34281E-17 -17.4649 0.10000E+01 0.0000 56 KOH,aq 0.62769E-10 -10.2023 0.62769E-10 -10.2023 0.10000E+01 0.0000 57 KSO4- 0.10380E-08 -8.9838 0.99636E-09 -9.0016 0.95986E+00 -0.0178 58 MgCO3,aq 0.42308E-10 -10.3736 0.42308E-10 -10.3736 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.79279E-10 -10.1008 0.76100E-10 -10.1186 0.95990E+00 -0.0178 60 MgCl+ 0.49257E-10 -10.3075 0.47282E-10 -10.3253 0.95990E+00 -0.0178 61 MgOH+ 0.50708E-08 -8.2949 0.48675E-08 -8.3127 0.95990E+00 -0.0178 63 MnO,aq 0.26108E-09 -9.5832 0.26108E-09 -9.5832 0.10000E+01 0.0000 64 MnOH+ 0.15719E-07 -7.8036 0.15088E-07 -7.8214 0.95990E+00 -0.0178 65 MnO2-2 0.25688E-16 -16.5903 0.23011E-16 -16.6381 0.89577E+00 -0.0478 66 HMnO2- 0.10289E-12 -12.9876 0.98758E-13 -13.0054 0.95986E+00 -0.0178 69 MnCl+ 0.81029E-10 -10.0914 0.77779E-10 -10.1091 0.95990E+00 -0.0178 70 MnSO4,aq 0.62363E-09 -9.2051 0.62363E-09 -9.2051 0.10000E+01 0.0000 71 NaCl,aq 0.73718E-08 -8.1324 0.73718E-08 -8.1324 0.10000E+01 0.0000 72 NaOH,aq 0.37818E-08 -8.4223 0.37818E-08 -8.4223 0.10000E+01 0.0000 74 OH- 0.31549E-04 -4.5010 0.30281E-04 -4.5188 0.95982E+00 -0.0178 79 HPO3-2 0.10865E-19 -19.9640 0.97330E-20 -20.0118 0.89577E+00 -0.0478 82 H3PO4,aq 0.56300E-14 -14.2495 0.56300E-14 -14.2495 0.10000E+01 0.0000 83 H2PO4- 0.80635E-09 -9.0935 0.77399E-09 -9.1113 0.95988E+00 -0.0178 84 PO4-3 0.12298E-12 -12.9102 0.98255E-13 -13.0076 0.79897E+00 -0.0975 87 H2P2O7-2 0.52341E-19 -19.2812 0.46886E-19 -19.3290 0.89577E+00 -0.0478 88 HP2O7-3 0.60811E-18 -18.2160 0.48534E-18 -18.3140 0.79811E+00 -0.0979 90 H2S,aq 0.48583E-11 -11.3135 0.48579E-11 -11.3136 0.99991E+00 0.0000 96 SO2,aq 0.51542E-19 -19.2878 0.51542E-19 -19.2878 0.10000E+01 0.0000 97 SO3-2 0.47706E-14 -14.3214 0.42748E-14 -14.3691 0.89606E+00 -0.0477 98 HSO3- 0.51627E-14 -14.2871 0.49555E-14 -14.3049 0.95986E+00 -0.0178 99 HSO4- 0.43416E-09 -9.3623 0.41676E-09 -9.3801 0.95992E+00 -0.0178 101 S2O3-2 0.14492E-17 -17.8389 0.12982E-17 -17.8867 0.89577E+00 -0.0478 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2063456E-07 -.4748601E-04 -.4786185E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999734E+06 0.0000 3 Cl- 0.1379615E-03 0.1379749E-03 0.4891503E+01 3.8251 4 SO4-- 0.2531187E-04 0.2550421E-04 0.2449914E+01 10.7618 5 HCO3- 0.1250113E-04 0.1307007E-04 0.7974793E+00 2.7823 6 HS- 0.8503516E-10 0.3994484E-09 0.1321023E-04 -2.3851 7 Al+++ 0.7666630E-20 0.2408630E-05 0.6498685E-01 2.8961 8 H4SiO4 0.1284751E-03 0.1350888E-03 0.1298379E+02 -3.8912 9 Ca++ 0.3011315E-04 0.3044064E-04 0.1219969E+01 10.8372 10 Mg++ 0.2755958E-06 0.2808828E-06 0.6828652E-02 8.7987 11 Fe++ 0.1670429E-08 0.4804375E-08 0.2683033E-03 6.5812 12 K+ 0.2971308E-05 0.2972415E-05 0.1162245E+00 2.1583 13 Na+ 0.1776171E-03 0.1776454E-03 0.4083930E+01 3.9348 14 Mn++ 0.1083575E-06 0.1250421E-06 0.6869391E-02 8.3933 15 HPO4-- 0.2487856E-08 0.3294330E-08 0.3161786E-03 6.7543 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2187792E-03 -.4748575E-04 -.1712935E-03 0.0000000E+00 2 H2O 0.5550807E+02 0.5550798E+02 0.9674440E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2589246E-04 0.2550407E-04 0.3883872E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3879877E-06 0.3994462E-09 -.3883872E-06 0.0000000E+00 7 Al+++ 0.4565038E-04 0.2408617E-05 0.4324177E-04 0.0000000E+00 8 H4SiO4 0.1457790E-03 0.1350881E-03 0.1069089E-04 0.0000000E+00 9 Ca++ 0.3057306E-04 0.3044047E-04 0.1325863E-06 0.0000000E+00 10 Mg++ 0.1111111E-04 0.2808813E-06 0.1083023E-04 0.0000000E+00 11 Fe++ 0.9982120E-05 0.4804349E-08 0.9977316E-05 0.0000000E+00 12 K+ 0.2972399E-05 0.2972399E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1776444E-03 0.1776444E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2427403E-06 0.1250414E-06 0.1176989E-06 0.0000000E+00 15 HPO4-- 0.8284607E-07 0.3294312E-08 0.7955176E-07 0.0000000E+00 Chg. balance for solid moles: -.2279E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0140000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2652E-07 -7.576 0.1332E-04 -4.875 0.2878 0.4233E-05 clinochlore 0.2166E-05 -5.664 0.1204E-02 -2.919 26.01 0.4580E-03 daphnite 0.1374E-05 -5.862 0.9804E-03 -3.009 21.18 0.2971E-03 chlorite-Mn 0.2354E-07 -7.628 0.1669E-04 -4.778 0.3605 0.5318E-05 diaspore 0.3611E-04 -4.442 0.2167E-02 -2.664 46.80 0.6450E-03 hematite 0.1554E-05 -5.809 0.2481E-03 -3.605 5.360 0.4702E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6078E+00 0.6078E+00 1.0000 -0.216 daphnite 0.3856E+00 0.3856E+00 1.0000 -0.414 chlorite-Mn 0.6606E-02 0.6606E-02 1.0000 -2.180 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.004629 g Volume = 0.001457 cm3 Porosity: 99.8552% V(tot) - V(min): 0.10041E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0140000 g log = -1.8539 Original solution: 1000.0103000 g Original solution / Rock added: 71429.31 (Water/Rock Ratio), log = 4.8539 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.5177E-04 1.0073 0.5486E-04 0.5446E-04 CH4,gas 0.6290E-13 1.0129 0.6703E-13 0.6617E-13 H2,gas 0.1802E-05 1.0006 0.1896E-05 0.1895E-05 H2S,gas 0.1352E-09 0.9959 0.1417E-09 0.1423E-09 S2,gas 0.1987E-27 1.0000 0.2091E-27 0.2091E-27 CO,gas 0.2562E-13 1.0000 0.2695E-13 0.2695E-13 SO3,gas 0.3162E-35 1.0000 0.3326E-35 0.3326E-35 SO2,gas 0.2268E-18 1.0000 0.2386E-18 0.2386E-18 HCl,gas 0.8282E-15 1.0000 0.8712E-15 0.8712E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.62 -6.26 -2.087 0.10690E+05 -4.261 3 CH4,gas 4.81 -10.36 -15.17 -3.793 0.25909E+05 -13.174 4 H2,gas 8.29 0.56 -7.72 -4.413 0.13185E+05 -5.722 5 H2S,gas -5.94 -17.79 -11.85 -5.924 0.20231E+05 -9.849 6 S2,gas -7.03 -36.71 -29.68 -4.566 0.50677E+05 -27.680 7 CO,gas 3.51 -12.06 -15.57 -4.791 0.26584E+05 -13.569 8 SO3,gas 17.43 -20.05 -37.48 -9.370 0.63993E+05 -35.478 9 SO2,gas 1.14 -19.49 -20.62 -5.499 0.35212E+05 -18.622 10 HCl,gas 5.48 -11.58 -17.06 -8.530 0.29129E+05 -15.060 16 albite -0.33 -4.84 -4.51 -0.347 0.77080E+04 20 analcite 3.37 -0.95 -4.32 -0.480 0.73798E+04 21 andalusite 5.06 1.90 -3.16 -0.316 0.53980E+04 24 anhydrite -5.28 -9.21 -3.93 -1.967 0.67169E+04 29 anorthite 12.80 8.85 -3.95 -0.304 0.67457E+04 35 aragonite 0.99 -1.79 -2.77 -0.924 0.47348E+04 36 brucite 12.58 8.80 -3.78 -0.756 0.64507E+04 37 calcite 0.83 -1.79 -2.62 -0.873 0.44735E+04 40 carpholite-Mg 8.65 6.81 -1.84 -0.123 0.31450E+04 41 carpholite-Fe 6.78 4.59 -2.19 -0.146 0.37425E+04 50 chloritoid-Mg 13.26 10.70 -2.56 -0.171 0.43738E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.050 0.12916E+04 52 chloritoid-Mn 11.46 10.29 -1.17 -0.078 0.19959E+04 54 coesite -2.37 -3.89 -1.52 -0.507 0.25985E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.89 -1.34 -0.447 0.22914E+04 67 diopside 16.22 11.85 -4.36 -0.436 0.74480E+04 68 hedenbergite 14.24 9.64 -4.61 -0.461 0.78687E+04 75 epidote 24.78 22.09 -2.68 -0.130 0.45818E+04 76 clinozoisite 22.92 18.69 -4.23 -0.192 0.72261E+04 77 epidote-Fe 29.94 25.49 -4.44 -0.231 0.75850E+04 78 fayalite 14.08 9.27 -4.81 -0.687 0.82090E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.96 -4.23 -0.353 0.72275E+04 91 heulandite -5.71 -10.61 -4.90 -0.223 0.83697E+04 92 hercynite 17.34 12.37 -4.97 -0.331 0.84880E+04 98 kaolinite -1.27 -1.99 -0.72 -0.065 0.12243E+04 99 kyanite 4.93 1.90 -3.03 -0.303 0.51747E+04 101 laumontite 2.97 1.06 -1.91 -0.127 0.32611E+04 102 lawsonite 9.68 8.85 -0.83 -0.055 0.14195E+04 105 lizardite 23.29 18.61 -4.67 -0.389 0.79804E+04 106 magnesite 0.71 -3.83 -4.53 -1.512 0.77427E+04 107 magnetite 20.13 19.18 -0.95 -0.078 0.16288E+04 110 magnesioferrite 26.26 21.40 -4.86 -0.397 0.83000E+04 113 margarite 17.45 14.64 -2.81 -0.113 0.48025E+04 116 microcline -2.43 -6.62 -4.19 -0.322 0.71498E+04 120 muscovite 2.68 -0.83 -3.51 -0.206 0.59867E+04 121 paragonite 4.34 0.95 -3.39 -0.199 0.57833E+04 136 prehnite 19.47 15.79 -3.67 -0.216 0.62721E+04 137 prehnite-Fe 22.59 19.20 -3.39 -0.204 0.57901E+04 145 pyroxmangite 7.42 4.50 -2.91 -0.583 0.49755E+04 146 pyrophyllite -6.10 -9.77 -3.67 -0.230 0.62741E+04 147 quartz -2.98 -3.89 -0.91 -0.303 0.15524E+04 152 rhodochrosite -0.96 -4.23 -3.27 -1.091 0.55871E+04 153 rhodonite 7.46 4.50 -2.96 -0.592 0.50547E+04 156 siderite -2.59 -6.04 -3.46 -1.152 0.58994E+04 157 sillimanite 5.32 1.90 -3.42 -0.342 0.58402E+04 164 stilbite -7.41 -10.61 -3.20 -0.153 0.54691E+04 165 stilpnomelane-Fe 13.18 8.65 -4.53 -0.135 0.77371E+04 169 sudoite 21.22 17.51 -3.71 -0.120 0.63314E+04 178 topaz-H 4.67 1.90 -2.77 -0.252 0.47238E+04 179 tridymite -2.61 -3.89 -1.28 -0.426 0.21797E+04 188 wairakite 4.06 1.06 -2.99 -0.176 0.51119E+04 189 walstromite 11.53 6.95 -4.58 -0.916 0.78234E+04 190 wollastonite 10.48 6.95 -3.54 -0.707 0.60373E+04 191 pseudo-wollastonite 11.02 6.95 -4.07 -0.815 0.69559E+04 192 zoisite 22.96 18.69 -4.27 -0.194 0.72986E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.74 -4.18 -0.259 0.71457E+04 197 beidellite-Mg -1.71 -6.08 -4.37 -0.271 0.74686E+04 198 beidellite-Na -1.26 -6.23 -4.98 -0.305 0.84985E+04 200 chalcedony -2.79 -3.89 -1.10 -0.366 0.18727E+04 202 montmorillonite-Ca -2.21 -6.04 -3.82 -0.236 0.65269E+04 203 montmorillonite-K -2.16 -7.11 -4.95 -0.303 0.84545E+04 204 montmorillonite-Mg -2.40 -6.37 -3.97 -0.246 0.67809E+04 205 montmorillonite-Na -1.96 -6.53 -4.57 -0.280 0.77956E+04 206 nontronite-Ca 3.28 1.06 -2.22 -0.144 0.37886E+04 207 nontronite-H 2.60 -0.73 -3.32 -0.223 0.56740E+04 208 nontronite-K 3.40 -0.02 -3.42 -0.219 0.58376E+04 209 nontronite-Mg 3.14 0.72 -2.41 -0.157 0.41232E+04 210 nontronite-Na 3.58 0.57 -3.01 -0.193 0.51423E+04 215 gypsum -4.92 -9.21 -4.29 -1.072 0.73236E+04 225 tobermorite 9.84 5.14 -4.70 -1.283 0.80299E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.58 -3.24 -0.811 0.55373E+04 241 silica-amorphous -2.08 -3.89 -1.81 -0.604 0.30929E+04 243 an20ab80 2.08 -2.10 -4.18 -0.322 0.71439E+04 244 an25ab75 2.71 -1.42 -4.13 -0.318 0.70508E+04 245 an30ab70 3.34 -0.74 -4.08 -0.314 0.69660E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0140000 g New total amount of reactant added: 0.0144000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0144000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2908765E-03 Osmotic coef. = 0.9898 True ionic strength = .2994857E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.20022E-07 -7.6985 0.19219E-07 -7.7163 0.95992E+00 -0.0178 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13241E-03 -3.8781 0.95979E+00 -0.0178 4 SO4-- 0.25309E-04 -4.5967 0.22666E-04 -4.6446 0.89556E+00 -0.0479 5 HCO3- 0.12512E-04 -4.9027 0.12009E-04 -4.9205 0.95982E+00 -0.0178 6 HS- 0.71566E-10 -10.1453 0.68689E-10 -10.1631 0.95979E+00 -0.0178 7 Al+++ 0.70066E-20 -20.1545 0.55884E-20 -20.2527 0.79760E+00 -0.0982 8 H4SiO4 0.13193E-03 -3.8797 0.13193E-03 -3.8797 0.10000E+01 0.0000 9 Ca++ 0.30560E-04 -4.5148 0.27364E-04 -4.5628 0.89542E+00 -0.0480 10 Mg++ 0.25556E-06 -6.5925 0.22882E-06 -6.6405 0.89533E+00 -0.0480 11 Fe++ 0.15452E-08 -8.8110 0.13835E-08 -8.8590 0.89535E+00 -0.0480 12 K+ 0.30562E-05 -5.5148 0.29334E-05 -5.5326 0.95983E+00 -0.0178 13 Na+ 0.17812E-03 -3.7493 0.17096E-03 -3.7671 0.95979E+00 -0.0178 14 Mn++ 0.10551E-06 -6.9767 0.94469E-07 -7.0247 0.89537E+00 -0.0480 15 HPO4-- 0.23334E-08 -8.6320 0.20897E-08 -8.6799 0.89557E+00 -0.0479 16 HSiO3- 0.69779E-05 -5.1563 0.66973E-05 -5.1741 0.95979E+00 -0.0178 17 Ca(HSiO3)+ 0.42780E-08 -8.3688 0.41062E-08 -8.3866 0.95983E+00 -0.0178 18 Mg(HSiO3)+ 0.44519E-10 -10.3515 0.42730E-10 -10.3693 0.95983E+00 -0.0178 19 NaHSiO3,aq 0.18184E-07 -7.7403 0.18184E-07 -7.7403 0.10000E+01 0.0000 20 AlO+ 0.20349E-11 -11.6915 0.19531E-11 -11.7093 0.95983E+00 -0.0178 21 AlOH+2 0.21001E-15 -15.6778 0.18804E-15 -15.7257 0.89539E+00 -0.0480 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.24617E-05 -5.6088 0.23627E-05 -5.6266 0.95975E+00 -0.0178 24 CH4,aq 0.35715E-16 -16.4471 0.35712E-16 -16.4472 0.99991E+00 0.0000 29 CO,aq 0.15994E-16 -16.7960 0.15994E-16 -16.7960 0.10000E+01 0.0000 30 CO2,aq 0.46540E-06 -6.3322 0.46536E-06 -6.3322 0.99991E+00 0.0000 31 CO3-2 0.64515E-07 -7.1903 0.57774E-07 -7.2383 0.89552E+00 -0.0479 32 CaCO3,aq 0.19363E-07 -7.7130 0.19363E-07 -7.7130 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.86270E-08 -8.0641 0.82804E-08 -8.0819 0.95983E+00 -0.0178 34 CaCl+ 0.60155E-08 -8.2207 0.57739E-08 -8.2385 0.95983E+00 -0.0178 35 CaCl2,aq 0.17801E-12 -12.7495 0.17801E-12 -12.7495 0.10000E+01 0.0000 36 CaOH+ 0.10460E-06 -6.9805 0.10040E-06 -6.9983 0.95983E+00 -0.0178 37 CaSO4,aq 0.19325E-06 -6.7139 0.19325E-06 -6.7139 0.10000E+01 0.0000 38 HCl,aq 0.47868E-12 -12.3200 0.47868E-12 -12.3200 0.10000E+01 0.0000 43 FeCl+ 0.29728E-12 -12.5268 0.28534E-12 -12.5446 0.95983E+00 -0.0178 46 FeO,aq 0.14812E-09 -9.8294 0.14812E-09 -9.8294 0.10000E+01 0.0000 47 FeOH+ 0.24864E-08 -8.6044 0.23866E-08 -8.6222 0.95983E+00 -0.0178 48 HFeO2- 0.86367E-10 -10.0637 0.82894E-10 -10.0815 0.95979E+00 -0.0178 49 FeO+ 0.16564E-12 -12.7808 0.15898E-12 -12.7986 0.95983E+00 -0.0178 50 FeOH+2 0.63500E-18 -18.1972 0.56857E-18 -18.2452 0.89539E+00 -0.0480 51 FeO2- 0.88138E-10 -10.0548 0.84593E-10 -10.0727 0.95979E+00 -0.0178 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.13346E-08 -8.8747 0.13345E-08 -8.8747 0.99991E+00 0.0000 54 KCl,aq 0.68776E-11 -11.1626 0.68776E-11 -11.1626 0.10000E+01 0.0000 55 KHSO4,aq 0.34195E-17 -17.4660 0.34195E-17 -17.4660 0.10000E+01 0.0000 56 KOH,aq 0.66539E-10 -10.1769 0.66539E-10 -10.1769 0.10000E+01 0.0000 57 KSO4- 0.10673E-08 -8.9717 0.10244E-08 -8.9895 0.95979E+00 -0.0178 58 MgCO3,aq 0.40458E-10 -10.3930 0.40458E-10 -10.3930 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.73560E-10 -10.1334 0.70606E-10 -10.1512 0.95983E+00 -0.0178 60 MgCl+ 0.45664E-10 -10.3404 0.43830E-10 -10.3582 0.95983E+00 -0.0178 61 MgOH+ 0.48455E-08 -8.3147 0.46509E-08 -8.3325 0.95983E+00 -0.0178 63 MnO,aq 0.26998E-09 -9.5687 0.26998E-09 -9.5687 0.10000E+01 0.0000 64 MnOH+ 0.15772E-07 -7.8021 0.15138E-07 -7.8199 0.95983E+00 -0.0178 65 MnO2-2 0.28227E-16 -16.5493 0.25278E-16 -16.5973 0.89552E+00 -0.0479 66 HMnO2- 0.10967E-12 -12.9599 0.10526E-12 -12.9777 0.95979E+00 -0.0178 69 MnCl+ 0.78876E-10 -10.1031 0.75708E-10 -10.1209 0.95983E+00 -0.0178 70 MnSO4,aq 0.60683E-09 -9.2169 0.60683E-09 -9.2169 0.10000E+01 0.0000 71 NaCl,aq 0.73915E-08 -8.1313 0.73915E-08 -8.1313 0.10000E+01 0.0000 72 NaOH,aq 0.39085E-08 -8.4080 0.39085E-08 -8.4080 0.10000E+01 0.0000 74 OH- 0.32519E-04 -4.4879 0.31210E-04 -4.5057 0.95975E+00 -0.0178 82 H3PO4,aq 0.49693E-14 -14.3037 0.49693E-14 -14.3037 0.10000E+01 0.0000 83 H2PO4- 0.73361E-09 -9.1345 0.70412E-09 -9.1524 0.95981E+00 -0.0178 84 PO4-3 0.11892E-12 -12.9247 0.94955E-13 -13.0225 0.79847E+00 -0.0977 87 H2P2O7-2 0.43330E-19 -19.3632 0.38803E-19 -19.4111 0.89552E+00 -0.0479 88 HP2O7-3 0.51905E-18 -18.2848 0.41400E-18 -18.3830 0.79761E+00 -0.0982 90 H2S,aq 0.39668E-11 -11.4016 0.39664E-11 -11.4016 0.99991E+00 0.0000 96 SO2,aq 0.46810E-19 -19.3297 0.46810E-19 -19.3297 0.10000E+01 0.0000 97 SO3-2 0.46038E-14 -14.3369 0.41242E-14 -14.3847 0.89581E+00 -0.0478 98 HSO3- 0.48329E-14 -14.3158 0.46386E-14 -14.3336 0.95979E+00 -0.0178 99 HSO4- 0.42110E-09 -9.3756 0.40420E-09 -9.3934 0.95985E+00 -0.0178 101 S2O3-2 0.11832E-17 -17.9269 0.10596E-17 -17.9749 0.89552E+00 -0.0479 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2002168E-07 -.4915866E-04 -.4954772E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999730E+06 0.0000 3 Cl- 0.1379614E-03 0.1379750E-03 0.4891502E+01 3.8382 4 SO4-- 0.2530919E-04 0.2550424E-04 0.2449916E+01 10.7879 5 HCO3- 0.1251206E-04 0.1307007E-04 0.7974791E+00 2.7958 6 HS- 0.7156634E-10 0.3727111E-09 0.1232599E-04 -2.4468 7 Al+++ 0.7006552E-20 0.2482083E-05 0.6696864E-01 2.8961 8 H4SiO4 0.1319269E-03 0.1389273E-03 0.1335271E+02 -3.8797 9 Ca++ 0.3056024E-04 0.3089638E-04 0.1238234E+01 10.8697 10 Mg++ 0.2555648E-06 0.2606145E-06 0.6335899E-02 8.7920 11 Fe++ 0.1545244E-08 0.4558247E-08 0.2545580E-03 6.5735 12 K+ 0.3056201E-05 0.3057342E-05 0.1195452E+00 2.1836 13 Na+ 0.1781180E-03 0.1781475E-03 0.4095472E+01 3.9491 14 Mn++ 0.1055084E-06 0.1222358E-06 0.6715221E-02 8.4078 15 HPO4-- 0.2333366E-08 0.3067096E-08 0.2943694E-03 6.7526 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2254026E-03 -.4915838E-04 -.1762442E-03 0.0000000E+00 2 H2O 0.5550807E+02 0.5550797E+02 0.9951321E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2590354E-04 0.2550410E-04 0.3994458E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3990731E-06 0.3727090E-09 -.3994458E-06 0.0000000E+00 7 Al+++ 0.4695468E-04 0.2482069E-05 0.4447261E-04 0.0000000E+00 8 H4SiO4 0.1499441E-03 0.1389265E-03 0.1101756E-04 0.0000000E+00 9 Ca++ 0.3103311E-04 0.3089620E-04 0.1369100E-06 0.0000000E+00 10 Mg++ 0.1142857E-04 0.2606130E-06 0.1116796E-04 0.0000000E+00 11 Fe++ 0.1026732E-04 0.4558222E-08 0.1026277E-04 0.0000000E+00 12 K+ 0.3057325E-05 0.3057325E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1781465E-03 0.1781465E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2496758E-06 0.1222351E-06 0.1274407E-06 0.0000000E+00 15 HPO4-- 0.8521310E-07 0.3067079E-08 0.8214602E-07 0.0000000E+00 Chg. balance for solid moles: 0.2118E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0144000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2738E-07 -7.563 0.1375E-04 -4.862 0.2887 0.4371E-05 clinochlore 0.2234E-05 -5.651 0.1241E-02 -2.906 26.06 0.4722E-03 daphnite 0.1413E-05 -5.850 0.1009E-02 -2.996 21.17 0.3056E-03 chlorite-Mn 0.2549E-07 -7.594 0.1807E-04 -4.743 0.3793 0.5759E-05 diaspore 0.3713E-04 -4.430 0.2227E-02 -2.652 46.75 0.6631E-03 hematite 0.1598E-05 -5.796 0.2552E-03 -3.593 5.356 0.4836E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6082E+00 0.6082E+00 1.0000 -0.216 daphnite 0.3849E+00 0.3849E+00 1.0000 -0.415 chlorite-Mn 0.6940E-02 0.6940E-02 1.0000 -2.159 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.004764 g Volume = 0.001499 cm3 Porosity: 99.8509% V(tot) - V(min): 0.10043E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0144000 g log = -1.8416 Original solution: 1000.0103000 g Original solution / Rock added: 69445.16 (Water/Rock Ratio), log = 4.8416 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.5027E-04 1.0073 0.5327E-04 0.5288E-04 CH4,gas 0.5300E-13 1.0129 0.5647E-13 0.5575E-13 H2,gas 0.1739E-05 1.0006 0.1830E-05 0.1829E-05 H2S,gas 0.1104E-09 0.9959 0.1157E-09 0.1162E-09 S2,gas 0.1422E-27 1.0000 0.1496E-27 0.1496E-27 CO,gas 0.2401E-13 1.0000 0.2525E-13 0.2525E-13 SO3,gas 0.2975E-35 1.0000 0.3130E-35 0.3130E-35 SO2,gas 0.2060E-18 1.0000 0.2167E-18 0.2167E-18 HCl,gas 0.8034E-15 1.0000 0.8452E-15 0.8452E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.64 -6.27 -2.091 0.10712E+05 -4.274 3 CH4,gas 4.81 -10.44 -15.25 -3.812 0.26036E+05 -13.248 4 H2,gas 8.29 0.55 -7.74 -4.421 0.13212E+05 -5.737 5 H2S,gas -5.94 -17.88 -11.94 -5.968 0.20382E+05 -9.937 6 S2,gas -7.03 -36.86 -29.82 -4.588 0.50925E+05 -27.825 7 CO,gas 3.51 -12.09 -15.60 -4.799 0.26633E+05 -13.598 8 SO3,gas 17.43 -20.08 -37.50 -9.376 0.64038E+05 -35.504 9 SO2,gas 1.14 -19.53 -20.66 -5.510 0.35283E+05 -18.664 10 HCl,gas 5.48 -11.59 -17.07 -8.537 0.29152E+05 -15.073 16 albite -0.33 -4.79 -4.47 -0.343 0.76246E+04 20 analcite 3.37 -0.91 -4.28 -0.476 0.73161E+04 21 andalusite 5.06 1.91 -3.15 -0.315 0.53783E+04 24 anhydrite -5.28 -9.21 -3.93 -1.964 0.67064E+04 29 anorthite 12.80 8.90 -3.90 -0.300 0.66508E+04 35 aragonite 0.99 -1.77 -2.75 -0.918 0.47011E+04 36 brucite 12.58 8.79 -3.78 -0.757 0.64621E+04 37 calcite 0.83 -1.77 -2.60 -0.867 0.44398E+04 40 carpholite-Mg 8.65 6.82 -1.83 -0.122 0.31170E+04 41 carpholite-Fe 6.78 4.61 -2.18 -0.145 0.37164E+04 50 chloritoid-Mg 13.26 10.70 -2.56 -0.170 0.43655E+04 51 chloritoid-Fe 9.24 8.49 -0.75 -0.050 0.12851E+04 52 chloritoid-Mn 11.46 10.32 -1.14 -0.076 0.19514E+04 54 coesite -2.37 -3.88 -1.51 -0.503 0.25788E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.88 -1.33 -0.443 0.22717E+04 67 diopside 16.22 11.90 -4.31 -0.431 0.73644E+04 68 hedenbergite 14.24 9.68 -4.56 -0.456 0.77869E+04 75 epidote 24.78 22.19 -2.58 -0.125 0.44117E+04 76 clinozoisite 22.92 18.79 -4.13 -0.188 0.70560E+04 77 epidote-Fe 29.94 25.59 -4.34 -0.226 0.74149E+04 78 fayalite 14.08 9.27 -4.81 -0.687 0.82156E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.96 -4.23 -0.353 0.72277E+04 91 heulandite -5.71 -10.50 -4.79 -0.218 0.81765E+04 92 hercynite 17.34 12.37 -4.98 -0.332 0.85012E+04 98 kaolinite -1.27 -1.97 -0.69 -0.063 0.11850E+04 99 kyanite 4.93 1.91 -3.02 -0.302 0.51551E+04 101 laumontite 2.97 1.14 -1.83 -0.122 0.31269E+04 102 lawsonite 9.68 8.90 -0.78 -0.052 0.13247E+04 105 lizardite 23.29 18.62 -4.67 -0.389 0.79751E+04 106 magnesite 0.71 -3.84 -4.55 -1.518 0.77759E+04 107 magnetite 20.13 19.17 -0.96 -0.079 0.16420E+04 110 magnesioferrite 26.26 21.39 -4.87 -0.397 0.83114E+04 113 margarite 17.45 14.69 -2.76 -0.110 0.47076E+04 116 microcline -2.43 -6.56 -4.13 -0.317 0.70476E+04 120 muscovite 2.68 -0.77 -3.45 -0.203 0.58844E+04 121 paragonite 4.34 1.00 -3.34 -0.196 0.56999E+04 136 prehnite 19.47 15.89 -3.57 -0.210 0.61020E+04 137 prehnite-Fe 22.59 19.30 -3.29 -0.198 0.56200E+04 145 pyroxmangite 7.42 4.53 -2.89 -0.578 0.49310E+04 146 pyrophyllite -6.10 -9.73 -3.63 -0.227 0.61955E+04 147 quartz -2.98 -3.88 -0.90 -0.299 0.15327E+04 152 rhodochrosite -0.96 -4.23 -3.27 -1.090 0.55841E+04 153 rhodonite 7.46 4.53 -2.93 -0.587 0.50102E+04 156 siderite -2.59 -6.06 -3.48 -1.159 0.59344E+04 157 sillimanite 5.32 1.91 -3.41 -0.341 0.58205E+04 164 stilbite -7.41 -10.50 -3.09 -0.147 0.52759E+04 165 stilpnomelane-Fe 13.18 8.71 -4.47 -0.133 0.76240E+04 169 sudoite 21.22 17.53 -3.69 -0.119 0.62951E+04 178 topaz-H 4.67 1.91 -2.76 -0.250 0.47042E+04 179 tridymite -2.61 -3.88 -1.27 -0.422 0.21600E+04 188 wairakite 4.06 1.14 -2.92 -0.171 0.49777E+04 189 walstromite 11.53 6.99 -4.54 -0.908 0.77482E+04 190 wollastonite 10.48 6.99 -3.49 -0.698 0.59621E+04 191 pseudo-wollastonite 11.02 6.99 -4.03 -0.806 0.68807E+04 192 zoisite 22.96 18.79 -4.17 -0.190 0.71286E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.70 -4.14 -0.256 0.70643E+04 197 beidellite-Mg -1.71 -6.04 -4.33 -0.268 0.73983E+04 198 beidellite-Na -1.26 -6.19 -4.93 -0.302 0.84183E+04 200 chalcedony -2.79 -3.88 -1.09 -0.362 0.18531E+04 202 montmorillonite-Ca -2.21 -5.99 -3.77 -0.233 0.64428E+04 203 montmorillonite-K -2.16 -7.06 -4.90 -0.300 0.83653E+04 204 montmorillonite-Mg -2.40 -6.33 -3.93 -0.243 0.67079E+04 205 montmorillonite-Na -1.96 -6.48 -4.52 -0.277 0.77126E+04 206 nontronite-Ca 3.28 1.11 -2.17 -0.141 0.37073E+04 207 nontronite-H 2.60 -0.69 -3.28 -0.220 0.56019E+04 208 nontronite-K 3.40 0.04 -3.37 -0.216 0.57512E+04 209 nontronite-Mg 3.14 0.77 -2.37 -0.154 0.40529E+04 210 nontronite-Na 3.58 0.62 -2.96 -0.190 0.50621E+04 215 gypsum -4.92 -9.21 -4.28 -1.071 0.73132E+04 225 tobermorite 9.84 5.17 -4.66 -1.273 0.79640E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.57 -3.25 -0.813 0.55505E+04 241 silica-amorphous -2.08 -3.88 -1.80 -0.600 0.30733E+04 243 an20ab80 2.08 -2.05 -4.13 -0.318 0.70582E+04 244 an25ab75 2.71 -1.37 -4.08 -0.314 0.69645E+04 245 an30ab70 3.34 -0.68 -4.03 -0.310 0.68792E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0144000 g New total amount of reactant added: 0.0148000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0148000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2923675E-03 Osmotic coef. = 0.9898 True ionic strength = .3013529E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.19447E-07 -7.7111 0.18666E-07 -7.7289 0.95985E+00 -0.0178 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13240E-03 -3.8781 0.95972E+00 -0.0179 4 SO4-- 0.25307E-04 -4.5968 0.22657E-04 -4.6448 0.89531E+00 -0.0480 5 HCO3- 0.12522E-04 -4.9023 0.12018E-04 -4.9202 0.95975E+00 -0.0178 6 HS- 0.60606E-10 -10.2175 0.58165E-10 -10.2353 0.95972E+00 -0.0179 7 Al+++ 0.64230E-20 -20.1923 0.51197E-20 -20.2908 0.79709E+00 -0.0985 8 H4SiO4 0.13537E-03 -3.8685 0.13537E-03 -3.8685 0.10000E+01 0.0000 9 Ca++ 0.31007E-04 -4.5085 0.27757E-04 -4.5566 0.89517E+00 -0.0481 10 Mg++ 0.23756E-06 -6.6242 0.21263E-06 -6.6724 0.89508E+00 -0.0481 11 Fe++ 0.14333E-08 -8.8437 0.12829E-08 -8.8918 0.89510E+00 -0.0481 12 K+ 0.31411E-05 -5.5029 0.30147E-05 -5.5208 0.95976E+00 -0.0178 13 Na+ 0.17862E-03 -3.7481 0.17142E-03 -3.7659 0.95972E+00 -0.0179 14 Mn++ 0.10258E-06 -6.9889 0.91821E-07 -7.0371 0.89512E+00 -0.0481 15 HPO4-- 0.21922E-08 -8.6591 0.19628E-08 -8.7071 0.89532E+00 -0.0480 16 HSiO3- 0.73727E-05 -5.1324 0.70757E-05 -5.1502 0.95972E+00 -0.0179 17 Ca(HSiO3)+ 0.45849E-08 -8.3387 0.44004E-08 -8.3565 0.95976E+00 -0.0178 18 Mg(HSiO3)+ 0.43710E-10 -10.3594 0.41952E-10 -10.3773 0.95976E+00 -0.0178 19 NaHSiO3,aq 0.19265E-07 -7.7152 0.19265E-07 -7.7152 0.10000E+01 0.0000 20 AlO+ 0.19765E-11 -11.7041 0.18969E-11 -11.7219 0.95976E+00 -0.0178 21 AlOH+2 0.19815E-15 -15.7030 0.17737E-15 -15.7511 0.89514E+00 -0.0481 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.25349E-05 -5.5960 0.24327E-05 -5.6139 0.95968E+00 -0.0179 24 CH4,aq 0.30277E-16 -16.5189 0.30274E-16 -16.5189 0.99991E+00 0.0000 29 CO,aq 0.15023E-16 -16.8232 0.15023E-16 -16.8232 0.10000E+01 0.0000 30 CO2,aq 0.45234E-06 -6.3445 0.45230E-06 -6.3446 0.99991E+00 0.0000 31 CO3-2 0.66494E-07 -7.1772 0.59530E-07 -7.2253 0.89527E+00 -0.0480 32 CaCO3,aq 0.20237E-07 -7.6938 0.20237E-07 -7.6938 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.87578E-08 -8.0576 0.84054E-08 -8.0754 0.95976E+00 -0.0178 34 CaCl+ 0.61018E-08 -8.2145 0.58563E-08 -8.2324 0.95976E+00 -0.0178 35 CaCl2,aq 0.18054E-12 -12.7434 0.18054E-12 -12.7434 0.10000E+01 0.0000 36 CaOH+ 0.10925E-06 -6.9616 0.10485E-06 -6.9794 0.95976E+00 -0.0178 37 CaSO4,aq 0.19595E-06 -6.7079 0.19595E-06 -6.7079 0.10000E+01 0.0000 38 HCl,aq 0.46488E-12 -12.3327 0.46488E-12 -12.3327 0.10000E+01 0.0000 43 FeCl+ 0.27566E-12 -12.5596 0.26457E-12 -12.5775 0.95976E+00 -0.0178 46 FeO,aq 0.14561E-09 -9.8368 0.14561E-09 -9.8368 0.10000E+01 0.0000 47 FeOH+ 0.23741E-08 -8.6245 0.22786E-08 -8.6423 0.95976E+00 -0.0178 48 HFeO2- 0.87425E-10 -10.0584 0.83904E-10 -10.0762 0.95972E+00 -0.0179 49 FeO+ 0.16088E-12 -12.7935 0.15441E-12 -12.8113 0.95976E+00 -0.0178 50 FeOH+2 0.59915E-18 -18.2225 0.53632E-18 -18.2706 0.89514E+00 -0.0481 51 FeO2- 0.90755E-10 -10.0421 0.87100E-10 -10.0600 0.95972E+00 -0.0179 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.12897E-08 -8.8895 0.12896E-08 -8.8895 0.99991E+00 0.0000 54 KCl,aq 0.70677E-11 -11.1507 0.70677E-11 -11.1507 0.10000E+01 0.0000 55 KHSO4,aq 0.34118E-17 -17.4670 0.34118E-17 -17.4670 0.10000E+01 0.0000 56 KOH,aq 0.70408E-10 -10.1524 0.70408E-10 -10.1524 0.10000E+01 0.0000 57 KSO4- 0.10965E-08 -8.9600 0.10523E-08 -8.9778 0.95972E+00 -0.0179 58 MgCO3,aq 0.38739E-10 -10.4119 0.38739E-10 -10.4119 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.68413E-10 -10.1649 0.65660E-10 -10.1827 0.95976E+00 -0.0178 60 MgCl+ 0.42434E-10 -10.3723 0.40727E-10 -10.3901 0.95976E+00 -0.0178 61 MgOH+ 0.46365E-08 -8.3338 0.44500E-08 -8.3516 0.95976E+00 -0.0178 63 MnO,aq 0.27820E-09 -9.5557 0.27820E-09 -9.5557 0.10000E+01 0.0000 64 MnOH+ 0.15785E-07 -7.8018 0.15150E-07 -7.8196 0.95976E+00 -0.0178 65 MnO2-2 0.30843E-16 -16.5108 0.27613E-16 -16.5589 0.89527E+00 -0.0480 66 HMnO2- 0.11636E-12 -12.9342 0.11167E-12 -12.9521 0.95972E+00 -0.0179 69 MnCl+ 0.76665E-10 -10.1154 0.73580E-10 -10.1332 0.95976E+00 -0.0178 70 MnSO4,aq 0.58959E-09 -9.2294 0.58959E-09 -9.2294 0.10000E+01 0.0000 71 NaCl,aq 0.74112E-08 -8.1301 0.74112E-08 -8.1301 0.10000E+01 0.0000 72 NaOH,aq 0.40354E-08 -8.3941 0.40354E-08 -8.3941 0.10000E+01 0.0000 74 OH- 0.33485E-04 -4.4751 0.32135E-04 -4.4930 0.95968E+00 -0.0179 82 H3PO4,aq 0.44027E-14 -14.3563 0.44027E-14 -14.3563 0.10000E+01 0.0000 83 H2PO4- 0.66926E-09 -9.1744 0.64232E-09 -9.1922 0.95974E+00 -0.0178 84 PO4-3 0.11508E-12 -12.9390 0.91829E-13 -13.0370 0.79797E+00 -0.0980 87 H2P2O7-2 0.36068E-19 -19.4429 0.32290E-19 -19.4909 0.89527E+00 -0.0480 88 HP2O7-3 0.44501E-18 -18.3516 0.35472E-18 -18.4501 0.79710E+00 -0.0985 90 H2S,aq 0.32624E-11 -11.4865 0.32621E-11 -11.4865 0.99991E+00 0.0000 96 SO2,aq 0.42654E-19 -19.3700 0.42654E-19 -19.3700 0.10000E+01 0.0000 97 SO3-2 0.44487E-14 -14.3518 0.39840E-14 -14.3997 0.89556E+00 -0.0479 98 HSO3- 0.45347E-14 -14.3435 0.43521E-14 -14.3613 0.95972E+00 -0.0179 99 HSO4- 0.40886E-09 -9.3884 0.39241E-09 -9.4063 0.95978E+00 -0.0178 101 S2O3-2 0.97297E-18 -18.0119 0.87107E-18 -18.0599 0.89527E+00 -0.0480 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1944690E-07 -.5083421E-04 -.5123652E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999726E+06 0.0000 3 Cl- 0.1379613E-03 0.1379750E-03 0.4891501E+01 3.8508 4 SO4-- 0.2530651E-04 0.2550427E-04 0.2449918E+01 10.8131 5 HCO3- 0.1252214E-04 0.1307008E-04 0.7974789E+00 2.8088 6 HS- 0.6060554E-10 0.3495075E-09 0.1155862E-04 -2.5064 7 Al+++ 0.6422990E-20 0.2555200E-05 0.6894136E-01 2.8961 8 H4SiO4 0.1353704E-03 0.1427670E-03 0.1372175E+02 -3.8685 9 Ca++ 0.3100727E-04 0.3135215E-04 0.1256499E+01 10.9013 10 Mg++ 0.2375557E-06 0.2423855E-06 0.5892726E-02 8.7855 11 Fe++ 0.1433296E-08 0.4335135E-08 0.2420980E-03 6.5661 12 K+ 0.3141095E-05 0.3142269E-05 0.1228658E+00 2.2082 13 Na+ 0.1786189E-03 0.1786496E-03 0.4107014E+01 3.9630 14 Mn++ 0.1025796E-06 0.1193090E-06 0.6554431E-02 8.4208 15 HPO4-- 0.2192246E-08 0.2861630E-08 0.2746493E-03 6.7508 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2320260E-03 -.5083392E-04 -.1811921E-03 0.0000000E+00 2 H2O 0.5550806E+02 0.5550796E+02 0.1022819E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2591463E-04 0.2550412E-04 0.4105080E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4101585E-06 0.3495055E-09 -.4105080E-06 0.0000000E+00 7 Al+++ 0.4825898E-04 0.2555186E-05 0.4570379E-04 0.0000000E+00 8 H4SiO4 0.1541092E-03 0.1427661E-03 0.1134305E-04 0.0000000E+00 9 Ca++ 0.3149317E-04 0.3135197E-04 0.1411975E-06 0.0000000E+00 10 Mg++ 0.1174603E-04 0.2423841E-06 0.1150365E-04 0.0000000E+00 11 Fe++ 0.1055253E-04 0.4335110E-08 0.1054819E-04 0.0000000E+00 12 K+ 0.3142251E-05 0.3142251E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1786486E-03 0.1786486E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2566112E-06 0.1193083E-06 0.1373029E-06 0.0000000E+00 15 HPO4-- 0.8758013E-07 0.2861613E-08 0.8471852E-07 0.0000000E+00 Chg. balance for solid moles: 0.2557E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0148000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2824E-07 -7.549 0.1419E-04 -4.848 0.2895 0.4508E-05 clinochlore 0.2301E-05 -5.638 0.1279E-02 -2.893 26.10 0.4864E-03 daphnite 0.1453E-05 -5.838 0.1037E-02 -2.984 21.16 0.3141E-03 chlorite-Mn 0.2746E-07 -7.561 0.1947E-04 -4.711 0.3974 0.6204E-05 diaspore 0.3814E-04 -4.419 0.2288E-02 -2.641 46.70 0.6812E-03 hematite 0.1642E-05 -5.785 0.2622E-03 -3.581 5.352 0.4970E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6085E+00 0.6085E+00 1.0000 -0.216 daphnite 0.3842E+00 0.3842E+00 1.0000 -0.415 chlorite-Mn 0.7263E-02 0.7263E-02 1.0000 -2.139 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.004899 g Volume = 0.001542 cm3 Porosity: 99.8467% V(tot) - V(min): 0.10044E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0148000 g log = -1.8297 Original solution: 1000.0103000 g Original solution / Rock added: 67568.26 (Water/Rock Ratio), log = 4.8297 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.4886E-04 1.0073 0.5177E-04 0.5140E-04 CH4,gas 0.4493E-13 1.0129 0.4787E-13 0.4726E-13 H2,gas 0.1680E-05 1.0006 0.1769E-05 0.1768E-05 H2S,gas 0.9081E-10 0.9959 0.9514E-10 0.9553E-10 S2,gas 0.1030E-27 1.0000 0.1084E-27 0.1084E-27 CO,gas 0.2255E-13 1.0000 0.2372E-13 0.2372E-13 SO3,gas 0.2805E-35 1.0000 0.2951E-35 0.2951E-35 SO2,gas 0.1877E-18 1.0000 0.1975E-18 0.1975E-18 HCl,gas 0.7803E-15 1.0000 0.8208E-15 0.8208E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.65 -6.29 -2.095 0.10733E+05 -4.286 3 CH4,gas 4.81 -10.51 -15.32 -3.830 0.26158E+05 -13.320 4 H2,gas 8.29 0.53 -7.75 -4.430 0.13237E+05 -5.752 5 H2S,gas -5.94 -17.96 -12.02 -6.011 0.20527E+05 -10.022 6 S2,gas -7.03 -37.00 -29.97 -4.610 0.51165E+05 -27.965 7 CO,gas 3.51 -12.11 -15.62 -4.808 0.26679E+05 -13.625 8 SO3,gas 17.43 -20.10 -37.53 -9.382 0.64081E+05 -35.530 9 SO2,gas 1.14 -19.57 -20.70 -5.521 0.35352E+05 -18.704 10 HCl,gas 5.48 -11.61 -17.09 -8.543 0.29173E+05 -15.086 16 albite -0.33 -4.75 -4.42 -0.340 0.75435E+04 20 analcite 3.37 -0.88 -4.25 -0.472 0.72542E+04 21 andalusite 5.06 1.92 -3.14 -0.314 0.53592E+04 24 anhydrite -5.28 -9.20 -3.92 -1.961 0.66962E+04 29 anorthite 12.80 8.96 -3.84 -0.295 0.65587E+04 35 aragonite 0.99 -1.75 -2.73 -0.911 0.46683E+04 36 brucite 12.58 8.79 -3.79 -0.758 0.64732E+04 37 calcite 0.83 -1.75 -2.58 -0.860 0.44070E+04 40 carpholite-Mg 8.65 6.84 -1.81 -0.121 0.30899E+04 41 carpholite-Fe 6.78 4.62 -2.16 -0.144 0.36908E+04 50 chloritoid-Mg 13.26 10.71 -2.55 -0.170 0.43575E+04 51 chloritoid-Fe 9.24 8.49 -0.75 -0.050 0.12787E+04 52 chloritoid-Mn 11.46 10.34 -1.12 -0.075 0.19101E+04 54 coesite -2.37 -3.87 -1.50 -0.500 0.25597E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.87 -1.32 -0.440 0.22526E+04 67 diopside 16.22 11.95 -4.27 -0.427 0.72835E+04 68 hedenbergite 14.24 9.73 -4.51 -0.451 0.77075E+04 75 epidote 24.78 22.29 -2.49 -0.121 0.42467E+04 76 clinozoisite 22.92 18.89 -4.04 -0.183 0.68910E+04 77 epidote-Fe 29.94 25.69 -4.25 -0.221 0.72499E+04 78 fayalite 14.08 9.26 -4.82 -0.688 0.82219E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.96 -4.23 -0.353 0.72275E+04 91 heulandite -5.71 -10.39 -4.68 -0.213 0.79889E+04 92 hercynite 17.34 12.36 -4.99 -0.332 0.85139E+04 98 kaolinite -1.27 -1.94 -0.67 -0.061 0.11468E+04 99 kyanite 4.93 1.92 -3.01 -0.301 0.51360E+04 101 laumontite 2.97 1.22 -1.76 -0.117 0.29966E+04 102 lawsonite 9.68 8.96 -0.72 -0.048 0.12326E+04 105 lizardite 23.29 18.62 -4.67 -0.389 0.79702E+04 106 magnesite 0.71 -3.86 -4.57 -1.524 0.78081E+04 107 magnetite 20.13 19.16 -0.97 -0.079 0.16547E+04 110 magnesioferrite 26.26 21.38 -4.87 -0.398 0.83224E+04 113 margarite 17.45 14.75 -2.70 -0.108 0.46155E+04 116 microcline -2.43 -6.50 -4.07 -0.313 0.69483E+04 120 muscovite 2.68 -0.71 -3.39 -0.199 0.57852E+04 121 paragonite 4.34 1.05 -3.29 -0.194 0.56189E+04 136 prehnite 19.47 15.99 -3.48 -0.205 0.59370E+04 137 prehnite-Fe 22.59 19.39 -3.19 -0.192 0.54550E+04 145 pyroxmangite 7.42 4.55 -2.86 -0.573 0.48896E+04 146 pyrophyllite -6.10 -9.68 -3.58 -0.224 0.61191E+04 147 quartz -2.98 -3.87 -0.89 -0.295 0.15136E+04 152 rhodochrosite -0.96 -4.23 -3.27 -1.090 0.55830E+04 153 rhodonite 7.46 4.55 -2.91 -0.582 0.49689E+04 156 siderite -2.59 -6.08 -3.50 -1.165 0.59682E+04 157 sillimanite 5.32 1.92 -3.40 -0.340 0.58014E+04 164 stilbite -7.41 -10.39 -2.98 -0.142 0.50883E+04 165 stilpnomelane-Fe 13.18 8.78 -4.40 -0.131 0.75135E+04 169 sudoite 21.22 17.55 -3.67 -0.118 0.62600E+04 178 topaz-H 4.67 1.92 -2.74 -0.249 0.46851E+04 179 tridymite -2.61 -3.87 -1.25 -0.418 0.21409E+04 188 wairakite 4.06 1.22 -2.84 -0.167 0.48474E+04 189 walstromite 11.53 7.03 -4.50 -0.899 0.76752E+04 190 wollastonite 10.48 7.03 -3.45 -0.690 0.58891E+04 191 pseudo-wollastonite 11.02 7.03 -3.99 -0.797 0.68077E+04 192 zoisite 22.96 18.89 -4.08 -0.185 0.69635E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.65 -4.09 -0.253 0.69853E+04 197 beidellite-Mg -1.71 -6.00 -4.29 -0.266 0.73300E+04 198 beidellite-Na -1.26 -6.14 -4.88 -0.299 0.83403E+04 200 chalcedony -2.79 -3.87 -1.07 -0.358 0.18340E+04 202 montmorillonite-Ca -2.21 -5.94 -3.73 -0.230 0.63612E+04 203 montmorillonite-K -2.16 -7.01 -4.85 -0.297 0.82787E+04 204 montmorillonite-Mg -2.40 -6.29 -3.89 -0.240 0.66369E+04 205 montmorillonite-Na -1.96 -6.43 -4.47 -0.274 0.76321E+04 206 nontronite-Ca 3.28 1.15 -2.12 -0.138 0.36283E+04 207 nontronite-H 2.60 -0.64 -3.24 -0.217 0.55317E+04 208 nontronite-K 3.40 0.08 -3.32 -0.213 0.56673E+04 209 nontronite-Mg 3.14 0.81 -2.33 -0.151 0.39846E+04 210 nontronite-Na 3.58 0.66 -2.92 -0.187 0.49841E+04 215 gypsum -4.92 -9.20 -4.28 -1.069 0.73029E+04 225 tobermorite 9.84 5.21 -4.63 -1.262 0.79000E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.57 -3.26 -0.815 0.55631E+04 241 silica-amorphous -2.08 -3.87 -1.79 -0.596 0.30541E+04 243 an20ab80 2.08 -2.01 -4.08 -0.314 0.69750E+04 244 an25ab75 2.71 -1.32 -4.03 -0.310 0.68807E+04 245 an30ab70 3.34 -0.64 -3.98 -0.306 0.67948E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0148000 g New total amount of reactant added: 0.0152000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0152000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2938604E-03 Osmotic coef. = 0.9898 True ionic strength = .3032252E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.18907E-07 -7.7234 0.18147E-07 -7.7412 0.95978E+00 -0.0178 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13240E-03 -3.8781 0.95965E+00 -0.0179 4 SO4-- 0.25304E-04 -4.5968 0.22649E-04 -4.6450 0.89506E+00 -0.0481 5 HCO3- 0.12531E-04 -4.9020 0.12026E-04 -4.9199 0.95968E+00 -0.0179 6 HS- 0.51619E-10 -10.2872 0.49537E-10 -10.3051 0.95966E+00 -0.0179 7 Al+++ 0.59052E-20 -20.2288 0.47040E-20 -20.3275 0.79659E+00 -0.0988 8 H4SiO4 0.13881E-03 -3.8576 0.13881E-03 -3.8576 0.10000E+01 0.0000 9 Ca++ 0.31454E-04 -4.5023 0.28149E-04 -4.5505 0.89492E+00 -0.0482 10 Mg++ 0.22132E-06 -6.6550 0.19804E-06 -6.7032 0.89483E+00 -0.0483 11 Fe++ 0.13328E-08 -8.8752 0.11927E-08 -8.9235 0.89485E+00 -0.0482 12 K+ 0.32260E-05 -5.4913 0.30959E-05 -5.5092 0.95969E+00 -0.0179 13 Na+ 0.17912E-03 -3.7469 0.17189E-03 -3.7647 0.95965E+00 -0.0179 14 Mn++ 0.99602E-07 -7.0017 0.89130E-07 -7.0500 0.89487E+00 -0.0482 15 HPO4-- 0.20630E-08 -8.6855 0.18466E-08 -8.7336 0.89507E+00 -0.0481 16 HSiO3- 0.77768E-05 -5.1092 0.74630E-05 -5.1271 0.95965E+00 -0.0179 17 Ca(HSiO3)+ 0.49045E-08 -8.3094 0.47068E-08 -8.3273 0.95969E+00 -0.0179 18 Mg(HSiO3)+ 0.42943E-10 -10.3671 0.41212E-10 -10.3850 0.95969E+00 -0.0179 19 NaHSiO3,aq 0.20375E-07 -7.6909 0.20375E-07 -7.6909 0.10000E+01 0.0000 20 AlO+ 0.19216E-11 -11.7163 0.18441E-11 -11.7342 0.95969E+00 -0.0179 21 AlOH+2 0.18733E-15 -15.7274 0.16764E-15 -15.7756 0.89489E+00 -0.0482 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.26076E-05 -5.5838 0.25023E-05 -5.6017 0.95961E+00 -0.0179 24 CH4,aq 0.25813E-16 -16.5882 0.25811E-16 -16.5882 0.99991E+00 0.0000 29 CO,aq 0.14140E-16 -16.8495 0.14140E-16 -16.8495 0.10000E+01 0.0000 30 CO2,aq 0.44005E-06 -6.3565 0.44001E-06 -6.3565 0.99991E+00 0.0000 31 CO3-2 0.68463E-07 -7.1645 0.61276E-07 -7.2127 0.89502E+00 -0.0482 32 CaCO3,aq 0.21125E-07 -7.6752 0.21125E-07 -7.6752 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.88881E-08 -8.0512 0.85299E-08 -8.0691 0.95969E+00 -0.0179 34 CaCl+ 0.61880E-08 -8.2084 0.59386E-08 -8.2263 0.95969E+00 -0.0179 35 CaCl2,aq 0.18307E-12 -12.7374 0.18307E-12 -12.7374 0.10000E+01 0.0000 36 CaOH+ 0.11397E-06 -6.9432 0.10938E-06 -6.9611 0.95969E+00 -0.0179 37 CaSO4,aq 0.19864E-06 -6.7019 0.19864E-06 -6.7019 0.10000E+01 0.0000 38 HCl,aq 0.45191E-12 -12.3450 0.45191E-12 -12.3450 0.10000E+01 0.0000 43 FeCl+ 0.25627E-12 -12.5913 0.24594E-12 -12.6092 0.95969E+00 -0.0179 46 FeO,aq 0.14323E-09 -9.8440 0.14323E-09 -9.8440 0.10000E+01 0.0000 47 FeOH+ 0.22705E-08 -8.6439 0.21790E-08 -8.6618 0.95969E+00 -0.0179 48 HFeO2- 0.88463E-10 -10.0532 0.84894E-10 -10.0711 0.95965E+00 -0.0179 49 FeO+ 0.15642E-12 -12.8057 0.15011E-12 -12.8236 0.95969E+00 -0.0179 50 FeOH+2 0.56642E-18 -18.2469 0.50688E-18 -18.2951 0.89489E+00 -0.0482 51 FeO2- 0.93360E-10 -10.0298 0.89593E-10 -10.0477 0.95965E+00 -0.0179 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.12479E-08 -8.9038 0.12478E-08 -8.9039 0.99991E+00 0.0000 54 KCl,aq 0.72577E-11 -11.1392 0.72577E-11 -11.1392 0.10000E+01 0.0000 55 KHSO4,aq 0.34049E-17 -17.4679 0.34049E-17 -17.4679 0.10000E+01 0.0000 56 KOH,aq 0.74376E-10 -10.1286 0.74376E-10 -10.1286 0.10000E+01 0.0000 57 KSO4- 0.11257E-08 -8.9486 0.10803E-08 -8.9665 0.95965E+00 -0.0179 58 MgCO3,aq 0.37139E-10 -10.4302 0.37139E-10 -10.4302 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.63766E-10 -10.1954 0.61196E-10 -10.2133 0.95969E+00 -0.0179 60 MgCl+ 0.39523E-10 -10.4032 0.37930E-10 -10.4210 0.95969E+00 -0.0179 61 MgOH+ 0.44423E-08 -8.3524 0.42633E-08 -8.3703 0.95969E+00 -0.0179 63 MnO,aq 0.28573E-09 -9.5440 0.28573E-09 -9.5440 0.10000E+01 0.0000 64 MnOH+ 0.15762E-07 -7.8024 0.15127E-07 -7.8203 0.95969E+00 -0.0179 65 MnO2-2 0.33527E-16 -16.4746 0.30008E-16 -16.5228 0.89502E+00 -0.0482 66 HMnO2- 0.12294E-12 -12.9103 0.11798E-12 -12.9282 0.95965E+00 -0.0179 69 MnCl+ 0.74418E-10 -10.1283 0.71419E-10 -10.1462 0.95969E+00 -0.0179 70 MnSO4,aq 0.57209E-09 -9.2425 0.57209E-09 -9.2425 0.10000E+01 0.0000 71 NaCl,aq 0.74310E-08 -8.1290 0.74310E-08 -8.1290 0.10000E+01 0.0000 72 NaOH,aq 0.41623E-08 -8.3807 0.41623E-08 -8.3807 0.10000E+01 0.0000 74 OH- 0.34446E-04 -4.4629 0.33055E-04 -4.4808 0.95961E+00 -0.0179 82 H3PO4,aq 0.39147E-14 -14.4073 0.39147E-14 -14.4073 0.10000E+01 0.0000 83 H2PO4- 0.61216E-09 -9.2131 0.58748E-09 -9.2310 0.95967E+00 -0.0179 84 PO4-3 0.11144E-12 -12.9530 0.88867E-13 -13.0513 0.79747E+00 -0.0983 87 H2P2O7-2 0.30180E-19 -19.5203 0.27012E-19 -19.5685 0.89502E+00 -0.0482 88 HP2O7-3 0.38316E-18 -18.4166 0.30523E-18 -18.5154 0.79660E+00 -0.0988 90 H2S,aq 0.27011E-11 -11.5685 0.27009E-11 -11.5685 0.99991E+00 0.0000 96 SO2,aq 0.38990E-19 -19.4091 0.38990E-19 -19.4091 0.10000E+01 0.0000 97 SO3-2 0.43038E-14 -14.3661 0.38533E-14 -14.4142 0.89531E+00 -0.0480 98 HSO3- 0.42641E-14 -14.3702 0.40921E-14 -14.3881 0.95965E+00 -0.0179 99 HSO4- 0.39735E-09 -9.4008 0.38134E-09 -9.4187 0.95971E+00 -0.0179 101 S2O3-2 0.80549E-18 -18.0939 0.72093E-18 -18.1421 0.89502E+00 -0.0482 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1890695E-07 -.5251217E-04 -.5292773E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999722E+06 0.0000 3 Cl- 0.1379613E-03 0.1379750E-03 0.4891500E+01 3.8631 4 SO4-- 0.2530383E-04 0.2550429E-04 0.2449919E+01 10.8375 5 HCO3- 0.1253145E-04 0.1307008E-04 0.7974787E+00 2.8213 6 HS- 0.5161905E-10 0.3291717E-09 0.1088608E-04 -2.5639 7 Al+++ 0.5905191E-20 0.2627958E-05 0.7090439E-01 2.8961 8 H4SiO4 0.1388056E-03 0.1466077E-03 0.1409089E+02 -3.8576 9 Ca++ 0.3145424E-04 0.3180796E-04 0.1274766E+01 10.9319 10 Mg++ 0.2213186E-06 0.2259443E-06 0.5493015E-02 8.7792 11 Fe++ 0.1332835E-08 0.4132234E-08 0.2307668E-03 6.5589 12 K+ 0.3225988E-05 0.3227195E-05 0.1261865E+00 2.2320 13 Na+ 0.1791198E-03 0.1791518E-03 0.4118555E+01 3.9765 14 Mn++ 0.9960166E-07 0.1162961E-06 0.6388908E-02 8.4324 15 HPO4-- 0.2063047E-08 0.2675326E-08 0.2567684E-03 6.7488 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2386494E-03 -.5251186E-04 -.1861376E-03 0.0000000E+00 2 H2O 0.5550806E+02 0.5550795E+02 0.1050507E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2592571E-04 0.2550414E-04 0.4215730E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4212438E-06 0.3291698E-09 -.4215730E-06 0.0000000E+00 7 Al+++ 0.4956327E-04 0.2627942E-05 0.4693533E-04 0.0000000E+00 8 H4SiO4 0.1582743E-03 0.1466068E-03 0.1166749E-04 0.0000000E+00 9 Ca++ 0.3195323E-04 0.3180778E-04 0.1454531E-06 0.0000000E+00 10 Mg++ 0.1206349E-04 0.2259430E-06 0.1183755E-04 0.0000000E+00 11 Fe++ 0.1083773E-04 0.4132209E-08 0.1083360E-04 0.0000000E+00 12 K+ 0.3227176E-05 0.3227176E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1791507E-03 0.1791507E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2635467E-06 0.1162954E-06 0.1472513E-06 0.0000000E+00 15 HPO4-- 0.8994716E-07 0.2675310E-08 0.8727185E-07 0.0000000E+00 Chg. balance for solid moles: 0.1374E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0152000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2909E-07 -7.536 0.1461E-04 -4.835 0.2903 0.4643E-05 clinochlore 0.2368E-05 -5.626 0.1316E-02 -2.881 26.14 0.5005E-03 daphnite 0.1492E-05 -5.826 0.1065E-02 -2.973 21.15 0.3226E-03 chlorite-Mn 0.2945E-07 -7.531 0.2088E-04 -4.680 0.4147 0.6654E-05 diaspore 0.3916E-04 -4.407 0.2349E-02 -2.629 46.66 0.6993E-03 hematite 0.1686E-05 -5.773 0.2693E-03 -3.570 5.349 0.5104E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6087E+00 0.6087E+00 1.0000 -0.216 daphnite 0.3837E+00 0.3837E+00 1.0000 -0.416 chlorite-Mn 0.7572E-02 0.7572E-02 1.0000 -2.121 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.005034 g Volume = 0.001585 cm3 Porosity: 99.8425% V(tot) - V(min): 0.10045E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0152000 g log = -1.8182 Original solution: 1000.0103000 g Original solution / Rock added: 65790.15 (Water/Rock Ratio), log = 4.8182 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.4753E-04 1.0073 0.5037E-04 0.5000E-04 CH4,gas 0.3830E-13 1.0129 0.4082E-13 0.4030E-13 H2,gas 0.1626E-05 1.0006 0.1711E-05 0.1710E-05 H2S,gas 0.7519E-10 0.9959 0.7877E-10 0.7910E-10 S2,gas 0.7543E-28 1.0000 0.7935E-28 0.7935E-28 CO,gas 0.2122E-13 1.0000 0.2233E-13 0.2233E-13 SO3,gas 0.2650E-35 1.0000 0.2788E-35 0.2788E-35 SO2,gas 0.1716E-18 1.0000 0.1805E-18 0.1805E-18 HCl,gas 0.7585E-15 1.0000 0.7979E-15 0.7979E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.66 -6.30 -2.099 0.10753E+05 -4.298 3 CH4,gas 4.81 -10.58 -15.39 -3.847 0.26277E+05 -13.389 4 H2,gas 8.29 0.52 -7.77 -4.438 0.13261E+05 -5.767 5 H2S,gas -5.94 -18.05 -12.10 -6.052 0.20667E+05 -10.104 6 S2,gas -7.03 -37.13 -30.10 -4.631 0.51396E+05 -28.100 7 CO,gas 3.51 -12.14 -15.65 -4.816 0.26724E+05 -13.651 8 SO3,gas 17.43 -20.13 -37.55 -9.389 0.64124E+05 -35.555 9 SO2,gas 1.14 -19.61 -20.74 -5.532 0.35419E+05 -18.743 10 HCl,gas 5.48 -11.62 -17.10 -8.549 0.29194E+05 -15.098 16 albite -0.33 -4.70 -4.37 -0.336 0.74648E+04 20 analcite 3.37 -0.84 -4.21 -0.468 0.71940E+04 21 andalusite 5.06 1.93 -3.13 -0.313 0.53406E+04 24 anhydrite -5.28 -9.20 -3.92 -1.958 0.66860E+04 29 anorthite 12.80 9.01 -3.79 -0.291 0.64693E+04 35 aragonite 0.99 -1.73 -2.72 -0.905 0.46365E+04 36 brucite 12.58 8.78 -3.80 -0.759 0.64840E+04 37 calcite 0.83 -1.73 -2.56 -0.854 0.43752E+04 40 carpholite-Mg 8.65 6.86 -1.79 -0.120 0.30636E+04 41 carpholite-Fe 6.78 4.64 -2.15 -0.143 0.36659E+04 50 chloritoid-Mg 13.26 10.71 -2.55 -0.170 0.43498E+04 51 chloritoid-Fe 9.24 8.49 -0.75 -0.050 0.12723E+04 52 chloritoid-Mn 11.46 10.37 -1.10 -0.073 0.18717E+04 54 coesite -2.37 -3.86 -1.49 -0.496 0.25411E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.86 -1.31 -0.436 0.22340E+04 67 diopside 16.22 12.00 -4.22 -0.422 0.72049E+04 68 hedenbergite 14.24 9.78 -4.47 -0.447 0.76303E+04 75 epidote 24.78 22.38 -2.39 -0.116 0.40864E+04 76 clinozoisite 22.92 18.98 -3.94 -0.179 0.67307E+04 77 epidote-Fe 29.94 25.78 -4.15 -0.216 0.70896E+04 78 fayalite 14.08 9.26 -4.82 -0.688 0.82278E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.96 -4.23 -0.353 0.72270E+04 91 heulandite -5.71 -10.28 -4.57 -0.208 0.78065E+04 92 hercynite 17.34 12.35 -4.99 -0.333 0.85261E+04 98 kaolinite -1.27 -1.92 -0.65 -0.059 0.11096E+04 99 kyanite 4.93 1.93 -3.00 -0.300 0.51174E+04 101 laumontite 2.97 1.29 -1.68 -0.112 0.28700E+04 102 lawsonite 9.68 9.01 -0.67 -0.045 0.11432E+04 105 lizardite 23.29 18.62 -4.67 -0.389 0.79655E+04 106 magnesite 0.71 -3.88 -4.59 -1.530 0.78394E+04 107 magnetite 20.13 19.16 -0.98 -0.080 0.16669E+04 110 magnesioferrite 26.26 21.38 -4.88 -0.398 0.83333E+04 113 margarite 17.45 14.80 -2.65 -0.106 0.45261E+04 116 microcline -2.43 -6.44 -4.01 -0.309 0.68519E+04 120 muscovite 2.68 -0.65 -3.33 -0.196 0.56888E+04 121 paragonite 4.34 1.09 -3.24 -0.191 0.55402E+04 136 prehnite 19.47 16.08 -3.38 -0.199 0.57767E+04 137 prehnite-Fe 22.59 19.49 -3.10 -0.187 0.52947E+04 138 pumpellyite-Fe 46.47 41.62 -4.85 -0.108 0.82799E+04 145 pyroxmangite 7.42 4.57 -2.84 -0.568 0.48513E+04 146 pyrophyllite -6.10 -9.64 -3.54 -0.221 0.60447E+04 147 quartz -2.98 -3.86 -0.88 -0.292 0.14951E+04 152 rhodochrosite -0.96 -4.23 -3.27 -1.090 0.55836E+04 153 rhodonite 7.46 4.57 -2.89 -0.578 0.49305E+04 156 siderite -2.59 -6.10 -3.51 -1.171 0.60009E+04 157 sillimanite 5.32 1.93 -3.39 -0.339 0.57828E+04 164 stilbite -7.41 -10.28 -2.87 -0.137 0.49060E+04 165 stilpnomelane-Fe 13.18 8.84 -4.34 -0.129 0.74057E+04 169 sudoite 21.22 17.57 -3.65 -0.118 0.62259E+04 178 topaz-H 4.67 1.93 -2.73 -0.248 0.46665E+04 179 tridymite -2.61 -3.86 -1.24 -0.414 0.21223E+04 188 wairakite 4.06 1.29 -2.76 -0.163 0.47208E+04 189 walstromite 11.53 7.07 -4.45 -0.891 0.76044E+04 190 wollastonite 10.48 7.07 -3.41 -0.682 0.58183E+04 191 pseudo-wollastonite 11.02 7.07 -3.95 -0.789 0.67369E+04 192 zoisite 22.96 18.98 -3.98 -0.181 0.68032E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.61 -4.05 -0.250 0.69085E+04 197 beidellite-Mg -1.71 -5.96 -4.25 -0.263 0.72636E+04 198 beidellite-Na -1.26 -6.10 -4.84 -0.296 0.82645E+04 200 chalcedony -2.79 -3.86 -1.06 -0.354 0.18154E+04 202 montmorillonite-Ca -2.21 -5.89 -3.68 -0.228 0.62818E+04 203 montmorillonite-K -2.16 -6.96 -4.80 -0.294 0.81946E+04 204 montmorillonite-Mg -2.40 -6.25 -3.85 -0.238 0.65679E+04 205 montmorillonite-Na -1.96 -6.38 -4.42 -0.271 0.75537E+04 206 nontronite-Ca 3.28 1.20 -2.08 -0.135 0.35514E+04 207 nontronite-H 2.60 -0.60 -3.20 -0.214 0.54635E+04 208 nontronite-K 3.40 0.13 -3.27 -0.210 0.55857E+04 209 nontronite-Mg 3.14 0.84 -2.29 -0.149 0.39182E+04 210 nontronite-Na 3.58 0.71 -2.87 -0.185 0.49083E+04 215 gypsum -4.92 -9.20 -4.27 -1.068 0.72928E+04 225 tobermorite 9.84 5.25 -4.59 -1.252 0.78379E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.56 -3.27 -0.816 0.55754E+04 241 silica-amorphous -2.08 -3.86 -1.78 -0.593 0.30356E+04 243 an20ab80 2.08 -1.96 -4.04 -0.311 0.68941E+04 244 an25ab75 2.71 -1.27 -3.98 -0.306 0.67993E+04 245 an30ab70 3.34 -0.59 -3.93 -0.302 0.67129E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0152000 g New total amount of reactant added: 0.0156000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0156000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2953548E-03 Osmotic coef. = 0.9897 True ionic strength = .3051020E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.18399E-07 -7.7352 0.17658E-07 -7.7531 0.95972E+00 -0.0179 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13239E-03 -3.8782 0.95959E+00 -0.0179 4 SO4-- 0.25301E-04 -4.5969 0.22640E-04 -4.6451 0.89481E+00 -0.0483 5 HCO3- 0.12540E-04 -4.9017 0.12034E-04 -4.9196 0.95962E+00 -0.0179 6 HS- 0.44200E-10 -10.3546 0.42414E-10 -10.3725 0.95959E+00 -0.0179 7 Al+++ 0.54441E-20 -20.2641 0.43340E-20 -20.3631 0.79609E+00 -0.0990 8 H4SiO4 0.14223E-03 -3.8470 0.14223E-03 -3.8470 0.10000E+01 0.0000 9 Ca++ 0.31901E-04 -4.4962 0.28541E-04 -4.5445 0.89467E+00 -0.0483 10 Mg++ 0.20664E-06 -6.6848 0.18485E-06 -6.7332 0.89458E+00 -0.0484 11 Fe++ 0.12424E-08 -8.9057 0.11114E-08 -8.9541 0.89460E+00 -0.0484 12 K+ 0.33109E-05 -5.4801 0.31772E-05 -5.4980 0.95962E+00 -0.0179 13 Na+ 0.17962E-03 -3.7456 0.17236E-03 -3.7636 0.95958E+00 -0.0179 14 Mn++ 0.96601E-07 -7.0150 0.86421E-07 -7.0634 0.89461E+00 -0.0484 15 HPO4-- 0.19445E-08 -8.7112 0.17400E-08 -8.7595 0.89482E+00 -0.0483 16 HSiO3- 0.81900E-05 -5.0867 0.78590E-05 -5.1046 0.95959E+00 -0.0179 17 Ca(HSiO3)+ 0.52370E-08 -8.2809 0.50256E-08 -8.2988 0.95963E+00 -0.0179 18 Mg(HSiO3)+ 0.42213E-10 -10.3746 0.40508E-10 -10.3925 0.95963E+00 -0.0179 19 NaHSiO3,aq 0.21514E-07 -7.6673 0.21514E-07 -7.6673 0.10000E+01 0.0000 20 AlO+ 0.18700E-11 -11.7282 0.17945E-11 -11.7461 0.95963E+00 -0.0179 21 AlOH+2 0.17742E-15 -15.7510 0.15873E-15 -15.7993 0.89463E+00 -0.0484 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.26800E-05 -5.5719 0.25716E-05 -5.5898 0.95955E+00 -0.0179 24 CH4,aq 0.22124E-16 -16.6551 0.22122E-16 -16.6552 0.99991E+00 0.0000 29 CO,aq 0.13336E-16 -16.8750 0.13336E-16 -16.8750 0.10000E+01 0.0000 30 CO2,aq 0.42846E-06 -6.3681 0.42842E-06 -6.3681 0.99991E+00 0.0000 31 CO3-2 0.70421E-07 -7.1523 0.63011E-07 -7.2006 0.89477E+00 -0.0483 32 CaCO3,aq 0.22026E-07 -7.6571 0.22026E-07 -7.6571 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.90181E-08 -8.0449 0.86540E-08 -8.0628 0.95963E+00 -0.0179 34 CaCl+ 0.62742E-08 -8.2024 0.60209E-08 -8.2203 0.95963E+00 -0.0179 35 CaCl2,aq 0.18559E-12 -12.7314 0.18559E-12 -12.7314 0.10000E+01 0.0000 36 CaOH+ 0.11877E-06 -6.9253 0.11397E-06 -6.9432 0.95963E+00 -0.0179 37 CaSO4,aq 0.20133E-06 -6.6961 0.20133E-06 -6.6961 0.10000E+01 0.0000 38 HCl,aq 0.43970E-12 -12.3568 0.43970E-12 -12.3568 0.10000E+01 0.0000 43 FeCl+ 0.23881E-12 -12.6219 0.22917E-12 -12.6398 0.95963E+00 -0.0179 46 FeO,aq 0.14096E-09 -9.8509 0.14096E-09 -9.8509 0.10000E+01 0.0000 47 FeOH+ 0.21745E-08 -8.6626 0.20867E-08 -8.6805 0.95963E+00 -0.0179 48 HFeO2- 0.89481E-10 -10.0483 0.85865E-10 -10.0662 0.95959E+00 -0.0179 49 FeO+ 0.15221E-12 -12.8176 0.14607E-12 -12.8354 0.95963E+00 -0.0179 50 FeOH+2 0.53646E-18 -18.2705 0.47994E-18 -18.3188 0.89463E+00 -0.0484 51 FeO2- 0.95952E-10 -10.0179 0.92074E-10 -10.0359 0.95959E+00 -0.0179 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.12087E-08 -8.9177 0.12086E-08 -8.9177 0.99991E+00 0.0000 54 KCl,aq 0.74476E-11 -11.1280 0.74476E-11 -11.1280 0.10000E+01 0.0000 55 KHSO4,aq 0.33989E-17 -17.4687 0.33989E-17 -17.4687 0.10000E+01 0.0000 56 KOH,aq 0.78441E-10 -10.1055 0.78441E-10 -10.1055 0.10000E+01 0.0000 57 KSO4- 0.11549E-08 -8.9375 0.11082E-08 -8.9554 0.95959E+00 -0.0179 58 MgCO3,aq 0.35647E-10 -10.4480 0.35647E-10 -10.4480 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.59561E-10 -10.2250 0.57156E-10 -10.2429 0.95963E+00 -0.0179 60 MgCl+ 0.36891E-10 -10.4331 0.35401E-10 -10.4510 0.95963E+00 -0.0179 61 MgOH+ 0.42616E-08 -8.3704 0.40896E-08 -8.3883 0.95963E+00 -0.0179 63 MnO,aq 0.29259E-09 -9.5337 0.29259E-09 -9.5337 0.10000E+01 0.0000 64 MnOH+ 0.15707E-07 -7.8039 0.15073E-07 -7.8218 0.95963E+00 -0.0179 65 MnO2-2 0.36270E-16 -16.4404 0.32454E-16 -16.4887 0.89477E+00 -0.0483 66 HMnO2- 0.12939E-12 -12.8881 0.12416E-12 -12.9060 0.95959E+00 -0.0179 69 MnCl+ 0.72156E-10 -10.1417 0.69243E-10 -10.1596 0.95963E+00 -0.0179 70 MnSO4,aq 0.55449E-09 -9.2561 0.55449E-09 -9.2561 0.10000E+01 0.0000 71 NaCl,aq 0.74507E-08 -8.1278 0.74507E-08 -8.1278 0.10000E+01 0.0000 72 NaOH,aq 0.42892E-08 -8.3676 0.42892E-08 -8.3676 0.10000E+01 0.0000 74 OH- 0.35402E-04 -4.4510 0.33970E-04 -4.4689 0.95955E+00 -0.0179 82 H3PO4,aq 0.34927E-14 -14.4568 0.34927E-14 -14.4568 0.10000E+01 0.0000 83 H2PO4- 0.56133E-09 -9.2508 0.53865E-09 -9.2687 0.95961E+00 -0.0179 84 PO4-3 0.10798E-12 -12.9667 0.86055E-13 -13.0652 0.79697E+00 -0.0986 87 H2P2O7-2 0.25379E-19 -19.5955 0.22708E-19 -19.6438 0.89477E+00 -0.0483 88 HP2O7-3 0.33125E-18 -18.4798 0.26371E-18 -18.5789 0.79610E+00 -0.0990 90 H2S,aq 0.22504E-11 -11.6477 0.22502E-11 -11.6478 0.99991E+00 0.0000 96 SO2,aq 0.35745E-19 -19.4468 0.35745E-19 -19.4468 0.10000E+01 0.0000 97 SO3-2 0.41683E-14 -14.3800 0.37309E-14 -14.4282 0.89506E+00 -0.0481 98 HSO3- 0.40178E-14 -14.3960 0.38554E-14 -14.4139 0.95959E+00 -0.0179 99 HSO4- 0.38653E-09 -9.4128 0.37093E-09 -9.4307 0.95965E+00 -0.0179 101 S2O3-2 0.67103E-18 -18.1733 0.60041E-18 -18.2215 0.89477E+00 -0.0483 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1839890E-07 -.5419208E-04 -.5462091E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999718E+06 0.0000 3 Cl- 0.1379612E-03 0.1379750E-03 0.4891498E+01 3.8749 4 SO4-- 0.2530115E-04 0.2550431E-04 0.2449920E+01 10.8610 5 HCO3- 0.1254006E-04 0.1307008E-04 0.7974785E+00 2.8335 6 HS- 0.4420035E-10 0.3111890E-09 0.1029137E-04 -2.6194 7 Al+++ 0.5444137E-20 0.2700337E-05 0.7285720E-01 2.8961 8 H4SiO4 0.1422326E-03 0.1504493E-03 0.1446011E+02 -3.8470 9 Ca++ 0.3190115E-04 0.3226380E-04 0.1293034E+01 10.9616 10 Mg++ 0.2066389E-06 0.2110748E-06 0.5131514E-02 8.7730 11 Fe++ 0.1242384E-08 0.3947153E-08 0.2204308E-03 6.5520 12 K+ 0.3310881E-05 0.3312122E-05 0.1295072E+00 2.2551 13 Na+ 0.1796206E-03 0.1796539E-03 0.4130097E+01 3.9895 14 Mn++ 0.9660110E-07 0.1132276E-06 0.6220332E-02 8.4427 15 HPO4-- 0.1944505E-08 0.2505945E-08 0.2405117E-03 6.7467 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2452728E-03 -.5419175E-04 -.1910811E-03 0.0000000E+00 2 H2O 0.5550805E+02 0.5550795E+02 0.1078196E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2593680E-04 0.2550416E-04 0.4326404E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4323292E-06 0.3111871E-09 -.4326404E-06 0.0000000E+00 7 Al+++ 0.5086757E-04 0.2700320E-05 0.4816725E-04 0.0000000E+00 8 H4SiO4 0.1624394E-03 0.1504484E-03 0.1199100E-04 0.0000000E+00 9 Ca++ 0.3241329E-04 0.3226360E-04 0.1496804E-06 0.0000000E+00 10 Mg++ 0.1238095E-04 0.2110735E-06 0.1216988E-04 0.0000000E+00 11 Fe++ 0.1112293E-04 0.3947129E-08 0.1111899E-04 0.0000000E+00 12 K+ 0.3312102E-05 0.3312102E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1796528E-03 0.1796528E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2704821E-06 0.1132269E-06 0.1572552E-06 0.0000000E+00 15 HPO4-- 0.9231420E-07 0.2505930E-08 0.8980827E-07 0.0000000E+00 Chg. balance for solid moles: 0.1609E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0156000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2994E-07 -7.524 0.1504E-04 -4.823 0.2909 0.4778E-05 clinochlore 0.2434E-05 -5.614 0.1353E-02 -2.869 26.17 0.5146E-03 daphnite 0.1532E-05 -5.815 0.1093E-02 -2.961 21.14 0.3311E-03 chlorite-Mn 0.3145E-07 -7.502 0.2230E-04 -4.652 0.4313 0.7106E-05 diaspore 0.4017E-04 -4.396 0.2410E-02 -2.618 46.62 0.7175E-03 hematite 0.1731E-05 -5.762 0.2764E-03 -3.559 5.346 0.5238E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6090E+00 0.6090E+00 1.0000 -0.215 daphnite 0.3832E+00 0.3832E+00 1.0000 -0.417 chlorite-Mn 0.7869E-02 0.7869E-02 1.0000 -2.104 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.005169 g Volume = 0.001627 cm3 Porosity: 99.8383% V(tot) - V(min): 0.10046E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0156000 g log = -1.8069 Original solution: 1000.0103000 g Original solution / Rock added: 64103.22 (Water/Rock Ratio), log = 4.8069 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.4628E-04 1.0073 0.4904E-04 0.4868E-04 CH4,gas 0.3283E-13 1.0129 0.3498E-13 0.3454E-13 H2,gas 0.1575E-05 1.0006 0.1658E-05 0.1657E-05 H2S,gas 0.6264E-10 0.9959 0.6563E-10 0.6590E-10 S2,gas 0.5581E-28 1.0000 0.5871E-28 0.5871E-28 CO,gas 0.2002E-13 1.0000 0.2106E-13 0.2106E-13 SO3,gas 0.2509E-35 1.0000 0.2639E-35 0.2639E-35 SO2,gas 0.1573E-18 1.0000 0.1655E-18 0.1655E-18 HCl,gas 0.7380E-15 1.0000 0.7764E-15 0.7764E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.83410E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.67 -6.31 -2.103 0.10773E+05 -4.309 3 CH4,gas 4.81 -10.65 -15.46 -3.864 0.26391E+05 -13.456 4 H2,gas 8.29 0.51 -7.78 -4.446 0.13285E+05 -5.780 5 H2S,gas -5.94 -18.13 -12.18 -6.091 0.20802E+05 -10.183 6 S2,gas -7.03 -37.26 -30.23 -4.651 0.51619E+05 -28.231 7 CO,gas 3.51 -12.17 -15.68 -4.824 0.26767E+05 -13.677 8 SO3,gas 17.43 -20.15 -37.58 -9.395 0.64164E+05 -35.579 9 SO2,gas 1.14 -19.64 -20.78 -5.542 0.35483E+05 -18.781 10 HCl,gas 5.48 -11.63 -17.11 -8.555 0.29215E+05 -15.110 16 albite -0.33 -4.66 -4.33 -0.333 0.73883E+04 19 spessartine 24.55 19.58 -4.97 -0.249 0.84869E+04 20 analcite 3.37 -0.81 -4.18 -0.464 0.71356E+04 21 andalusite 5.06 1.95 -3.12 -0.312 0.53225E+04 24 anhydrite -5.28 -9.19 -3.91 -1.955 0.66761E+04 29 anorthite 12.80 9.06 -3.74 -0.288 0.63824E+04 35 aragonite 0.99 -1.71 -2.70 -0.899 0.46055E+04 36 brucite 12.58 8.77 -3.80 -0.761 0.64946E+04 37 calcite 0.83 -1.71 -2.54 -0.848 0.43442E+04 40 carpholite-Mg 8.65 6.87 -1.78 -0.119 0.30380E+04 41 carpholite-Fe 6.78 4.65 -2.13 -0.142 0.36415E+04 50 chloritoid-Mg 13.26 10.72 -2.54 -0.170 0.43423E+04 51 chloritoid-Fe 9.24 8.50 -0.74 -0.049 0.12661E+04 52 chloritoid-Mn 11.46 10.39 -1.08 -0.072 0.18360E+04 54 coesite -2.37 -3.85 -1.48 -0.493 0.25230E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.85 -1.30 -0.433 0.22159E+04 67 diopside 16.22 12.04 -4.17 -0.417 0.71285E+04 68 hedenbergite 14.24 9.82 -4.42 -0.442 0.75552E+04 75 epidote 24.78 22.47 -2.30 -0.112 0.39306E+04 76 clinozoisite 22.92 19.07 -3.85 -0.175 0.65749E+04 77 epidote-Fe 29.94 25.88 -4.06 -0.211 0.69338E+04 78 fayalite 14.08 9.26 -4.82 -0.689 0.82333E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.96 -4.23 -0.353 0.72263E+04 91 heulandite -5.71 -10.18 -4.47 -0.203 0.76292E+04 98 kaolinite -1.27 -1.90 -0.63 -0.057 0.10735E+04 99 kyanite 4.93 1.95 -2.99 -0.299 0.50993E+04 101 laumontite 2.97 1.37 -1.61 -0.107 0.27469E+04 102 lawsonite 9.68 9.06 -0.62 -0.041 0.10562E+04 105 lizardite 23.29 18.62 -4.66 -0.389 0.79612E+04 106 magnesite 0.71 -3.90 -4.61 -1.536 0.78698E+04 107 magnetite 20.13 19.15 -0.98 -0.080 0.16787E+04 110 magnesioferrite 26.26 21.37 -4.89 -0.399 0.83439E+04 113 margarite 17.45 14.85 -2.60 -0.104 0.44392E+04 116 microcline -2.43 -6.39 -3.96 -0.304 0.67582E+04 120 muscovite 2.68 -0.60 -3.28 -0.193 0.55951E+04 121 paragonite 4.34 1.14 -3.20 -0.188 0.54637E+04 136 prehnite 19.47 16.17 -3.29 -0.194 0.56209E+04 137 prehnite-Fe 22.59 19.58 -3.01 -0.181 0.51389E+04 138 pumpellyite-Fe 46.47 41.80 -4.67 -0.104 0.79802E+04 145 pyroxmangite 7.42 4.60 -2.82 -0.564 0.48156E+04 146 pyrophyllite -6.10 -9.60 -3.50 -0.219 0.59724E+04 147 quartz -2.98 -3.85 -0.87 -0.288 0.14770E+04 152 rhodochrosite -0.96 -4.23 -3.27 -1.090 0.55858E+04 153 rhodonite 7.46 4.60 -2.87 -0.573 0.48948E+04 156 siderite -2.59 -6.12 -3.53 -1.178 0.60325E+04 157 sillimanite 5.32 1.95 -3.38 -0.338 0.57647E+04 164 stilbite -7.41 -10.18 -2.77 -0.132 0.47286E+04 165 stilpnomelane-Fe 13.18 8.90 -4.28 -0.128 0.73004E+04 169 sudoite 21.22 17.59 -3.63 -0.117 0.61928E+04 178 topaz-H 4.67 1.95 -2.72 -0.247 0.46484E+04 179 tridymite -2.61 -3.85 -1.23 -0.411 0.21043E+04 188 wairakite 4.06 1.37 -2.69 -0.158 0.45977E+04 189 walstromite 11.53 7.11 -4.41 -0.883 0.75355E+04 190 wollastonite 10.48 7.11 -3.37 -0.673 0.57494E+04 191 pseudo-wollastonite 11.02 7.11 -3.91 -0.781 0.66681E+04 192 zoisite 22.96 19.07 -3.89 -0.177 0.66475E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.56 -4.00 -0.248 0.68338E+04 197 beidellite-Mg -1.71 -5.92 -4.22 -0.261 0.71990E+04 198 beidellite-Na -1.26 -6.05 -4.80 -0.294 0.81908E+04 200 chalcedony -2.79 -3.85 -1.05 -0.351 0.17973E+04 202 montmorillonite-Ca -2.21 -5.85 -3.63 -0.225 0.62046E+04 203 montmorillonite-K -2.16 -6.91 -4.75 -0.291 0.81127E+04 204 montmorillonite-Mg -2.40 -6.21 -3.81 -0.236 0.65009E+04 205 montmorillonite-Na -1.96 -6.34 -4.38 -0.268 0.74775E+04 206 nontronite-Ca 3.28 1.24 -2.04 -0.132 0.34767E+04 207 nontronite-H 2.60 -0.57 -3.16 -0.212 0.53972E+04 208 nontronite-K 3.40 0.18 -3.22 -0.207 0.55063E+04 209 nontronite-Mg 3.14 0.88 -2.26 -0.146 0.38536E+04 210 nontronite-Na 3.58 0.75 -2.83 -0.182 0.48346E+04 215 gypsum -4.92 -9.19 -4.27 -1.066 0.72828E+04 225 tobermorite 9.84 5.28 -4.55 -1.243 0.77775E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.55 -3.27 -0.818 0.55872E+04 241 silica-amorphous -2.08 -3.85 -1.77 -0.589 0.30175E+04 243 an20ab80 2.08 -1.91 -3.99 -0.307 0.68155E+04 244 an25ab75 2.71 -1.23 -3.94 -0.303 0.67202E+04 245 an30ab70 3.34 -0.54 -3.88 -0.299 0.66333E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0156000 g New total amount of reactant added: 0.0160000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0160000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2968502E-03 Osmotic coef. = 0.9897 True ionic strength = .3069828E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.17920E-07 -7.7467 0.17197E-07 -7.7645 0.95965E+00 -0.0179 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13238E-03 -3.8782 0.95952E+00 -0.0179 4 SO4-- 0.25298E-04 -4.5969 0.22631E-04 -4.6453 0.89456E+00 -0.0484 5 HCO3- 0.12548E-04 -4.9014 0.12040E-04 -4.9194 0.95955E+00 -0.0179 6 HS- 0.38037E-10 -10.4198 0.36497E-10 -10.4377 0.95952E+00 -0.0179 7 Al+++ 0.50322E-20 -20.2982 0.40036E-20 -20.3976 0.79559E+00 -0.0993 8 H4SiO4 0.14565E-03 -3.8367 0.14565E-03 -3.8367 0.10000E+01 0.0000 9 Ca++ 0.32348E-04 -4.4902 0.28933E-04 -4.5386 0.89442E+00 -0.0485 10 Mg++ 0.19333E-06 -6.7137 0.17290E-06 -6.7622 0.89433E+00 -0.0485 11 Fe++ 0.11607E-08 -8.9353 0.10381E-08 -8.9838 0.89435E+00 -0.0485 12 K+ 0.33958E-05 -5.4691 0.32584E-05 -5.4870 0.95956E+00 -0.0179 13 Na+ 0.18012E-03 -3.7444 0.17283E-03 -3.7624 0.95952E+00 -0.0179 14 Mn++ 0.93601E-07 -7.0287 0.83713E-07 -7.0772 0.89436E+00 -0.0485 15 HPO4-- 0.18355E-08 -8.7362 0.16420E-08 -8.7846 0.89457E+00 -0.0484 16 HSiO3- 0.86121E-05 -5.0649 0.82635E-05 -5.0828 0.95952E+00 -0.0179 17 Ca(HSiO3)+ 0.55825E-08 -8.2532 0.53567E-08 -8.2711 0.95956E+00 -0.0179 18 Mg(HSiO3)+ 0.41518E-10 -10.3818 0.39839E-10 -10.3997 0.95956E+00 -0.0179 19 NaHSiO3,aq 0.22683E-07 -7.6443 0.22683E-07 -7.6443 0.10000E+01 0.0000 20 AlO+ 0.18213E-11 -11.7396 0.17476E-11 -11.7575 0.95956E+00 -0.0179 21 AlOH+2 0.16833E-15 -15.7738 0.15055E-15 -15.8223 0.89438E+00 -0.0485 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.27520E-05 -5.5604 0.26405E-05 -5.5783 0.95948E+00 -0.0180 24 CH4,aq 0.19055E-16 -16.7200 0.19054E-16 -16.7200 0.99991E+00 0.0000 29 CO,aq 0.12600E-16 -16.8996 0.12600E-16 -16.8996 0.10000E+01 0.0000 30 CO2,aq 0.41751E-06 -6.3793 0.41747E-06 -6.3794 0.99991E+00 0.0000 31 CO3-2 0.72369E-07 -7.1404 0.64735E-07 -7.1889 0.89452E+00 -0.0484 32 CaCO3,aq 0.22939E-07 -7.6394 0.22939E-07 -7.6394 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.91476E-08 -8.0387 0.87777E-08 -8.0566 0.95956E+00 -0.0179 34 CaCl+ 0.63603E-08 -8.1965 0.61031E-08 -8.2145 0.95956E+00 -0.0179 35 CaCl2,aq 0.18811E-12 -12.7256 0.18811E-12 -12.7256 0.10000E+01 0.0000 36 CaOH+ 0.12363E-06 -6.9079 0.11863E-06 -6.9258 0.95956E+00 -0.0179 37 CaSO4,aq 0.20401E-06 -6.6903 0.20401E-06 -6.6903 0.10000E+01 0.0000 38 HCl,aq 0.42820E-12 -12.3684 0.42820E-12 -12.3684 0.10000E+01 0.0000 43 FeCl+ 0.22304E-12 -12.6516 0.21402E-12 -12.6695 0.95956E+00 -0.0179 46 FeO,aq 0.13880E-09 -9.8576 0.13880E-09 -9.8576 0.10000E+01 0.0000 47 FeOH+ 0.20855E-08 -8.6808 0.20012E-08 -8.6987 0.95956E+00 -0.0179 48 HFeO2- 0.90477E-10 -10.0435 0.86815E-10 -10.0614 0.95952E+00 -0.0179 49 FeO+ 0.14825E-12 -12.8290 0.14226E-12 -12.8469 0.95956E+00 -0.0179 50 FeOH+2 0.50898E-18 -18.2933 0.45522E-18 -18.3418 0.89438E+00 -0.0485 51 FeO2- 0.98529E-10 -10.0064 0.94540E-10 -10.0244 0.95952E+00 -0.0179 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.11720E-08 -8.9311 0.11719E-08 -8.9311 0.99991E+00 0.0000 54 KCl,aq 0.76375E-11 -11.1170 0.76375E-11 -11.1170 0.10000E+01 0.0000 55 KHSO4,aq 0.33935E-17 -17.4694 0.33935E-17 -17.4694 0.10000E+01 0.0000 56 KOH,aq 0.82602E-10 -10.0830 0.82602E-10 -10.0830 0.10000E+01 0.0000 57 KSO4- 0.11840E-08 -8.9266 0.11361E-08 -8.9446 0.95952E+00 -0.0179 58 MgCO3,aq 0.34255E-10 -10.4653 0.34255E-10 -10.4653 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.55745E-10 -10.2538 0.53491E-10 -10.2717 0.95956E+00 -0.0179 60 MgCl+ 0.34505E-10 -10.4621 0.33110E-10 -10.4800 0.95956E+00 -0.0179 61 MgOH+ 0.40931E-08 -8.3879 0.39276E-08 -8.4059 0.95956E+00 -0.0179 63 MnO,aq 0.29881E-09 -9.5246 0.29881E-09 -9.5246 0.10000E+01 0.0000 64 MnOH+ 0.15624E-07 -7.8062 0.14992E-07 -7.8241 0.95956E+00 -0.0179 65 MnO2-2 0.39064E-16 -16.4082 0.34943E-16 -16.4566 0.89452E+00 -0.0484 66 HMnO2- 0.13569E-12 -12.8675 0.13020E-12 -12.8854 0.95952E+00 -0.0179 69 MnCl+ 0.69895E-10 -10.1556 0.67069E-10 -10.1735 0.95956E+00 -0.0179 70 MnSO4,aq 0.53691E-09 -9.2701 0.53691E-09 -9.2701 0.10000E+01 0.0000 71 NaCl,aq 0.74704E-08 -8.1267 0.74704E-08 -8.1267 0.10000E+01 0.0000 72 NaOH,aq 0.44160E-08 -8.3550 0.44160E-08 -8.3550 0.10000E+01 0.0000 74 OH- 0.36353E-04 -4.4395 0.34880E-04 -4.4574 0.95948E+00 -0.0180 82 H3PO4,aq 0.31263E-14 -14.5050 0.31263E-14 -14.5050 0.10000E+01 0.0000 83 H2PO4- 0.51593E-09 -9.2874 0.49506E-09 -9.3053 0.95954E+00 -0.0179 84 PO4-3 0.10469E-12 -12.9801 0.83384E-13 -13.0789 0.79648E+00 -0.0988 87 H2P2O7-2 0.21443E-19 -19.6687 0.19181E-19 -19.7171 0.89452E+00 -0.0484 88 HP2O7-3 0.28748E-18 -18.5414 0.22871E-18 -18.6407 0.79560E+00 -0.0993 90 H2S,aq 0.18860E-11 -11.7245 0.18858E-11 -11.7245 0.99991E+00 0.0000 96 SO2,aq 0.32861E-19 -19.4833 0.32861E-19 -19.4833 0.10000E+01 0.0000 97 SO3-2 0.40412E-14 -14.3935 0.36162E-14 -14.4418 0.89481E+00 -0.0483 98 HSO3- 0.37928E-14 -14.4210 0.36393E-14 -14.4390 0.95952E+00 -0.0179 99 HSO4- 0.37632E-09 -9.4244 0.36111E-09 -9.4424 0.95958E+00 -0.0179 101 S2O3-2 0.56229E-18 -18.2500 0.50298E-18 -18.2985 0.89452E+00 -0.0484 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1792014E-07 -.5587357E-04 -.5631569E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999714E+06 0.0000 3 Cl- 0.1379611E-03 0.1379750E-03 0.4891497E+01 3.8864 4 SO4-- 0.2529848E-04 0.2550433E-04 0.2449921E+01 10.8838 5 HCO3- 0.1254802E-04 0.1307008E-04 0.7974782E+00 2.8452 6 HS- 0.3803664E-10 0.2951568E-09 0.9761163E-05 -2.6732 7 Al+++ 0.5032235E-20 0.2772322E-05 0.7479939E-01 2.8961 8 H4SiO4 0.1456514E-03 0.1542918E-03 0.1482942E+02 -3.8367 9 Ca++ 0.3234799E-04 0.3271966E-04 0.1311303E+01 10.9905 10 Mg++ 0.1933318E-06 0.1975910E-06 0.4803702E-02 8.7669 11 Fe++ 0.1160688E-08 0.3777844E-08 0.2109756E-03 6.5453 12 K+ 0.3395774E-05 0.3397049E-05 0.1328278E+00 2.2776 13 Na+ 0.1801214E-03 0.1801560E-03 0.4141639E+01 4.0022 14 Mn++ 0.9360095E-07 0.1101304E-06 0.6050181E-02 8.4519 15 HPO4-- 0.1835514E-08 0.2351555E-08 0.2256938E-03 6.7445 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2518962E-03 -.5587323E-04 -.1960230E-03 0.0000000E+00 2 H2O 0.5550805E+02 0.5550794E+02 0.1105887E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2594788E-04 0.2550417E-04 0.4437097E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4434145E-06 0.2951550E-09 -.4437097E-06 0.0000000E+00 7 Al+++ 0.5217187E-04 0.2772305E-05 0.4939956E-04 0.0000000E+00 8 H4SiO4 0.1666045E-03 0.1542909E-03 0.1231368E-04 0.0000000E+00 9 Ca++ 0.3287334E-04 0.3271946E-04 0.1538828E-06 0.0000000E+00 10 Mg++ 0.1269841E-04 0.1975898E-06 0.1250082E-04 0.0000000E+00 11 Fe++ 0.1140814E-04 0.3777821E-08 0.1140436E-04 0.0000000E+00 12 K+ 0.3397028E-05 0.3397028E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1801549E-03 0.1801549E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2774175E-06 0.1101297E-06 0.1672878E-06 0.0000000E+00 15 HPO4-- 0.9468123E-07 0.2351540E-08 0.9232969E-07 0.0000000E+00 Chg. balance for solid moles: -.3970E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0160000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3078E-07 -7.512 0.1546E-04 -4.811 0.2915 0.4913E-05 clinochlore 0.2500E-05 -5.602 0.1390E-02 -2.857 26.20 0.5286E-03 daphnite 0.1571E-05 -5.804 0.1121E-02 -2.950 21.13 0.3397E-03 chlorite-Mn 0.3346E-07 -7.476 0.2372E-04 -4.625 0.4472 0.7559E-05 diaspore 0.4119E-04 -4.385 0.2471E-02 -2.607 46.59 0.7356E-03 hematite 0.1775E-05 -5.751 0.2834E-03 -3.548 5.344 0.5372E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6091E+00 0.6091E+00 1.0000 -0.215 daphnite 0.3827E+00 0.3827E+00 1.0000 -0.417 chlorite-Mn 0.8151E-02 0.8151E-02 1.0000 -2.089 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.005304 g Volume = 0.001670 cm3 Porosity: 99.8341% V(tot) - V(min): 0.10047E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0160000 g log = -1.7959 Original solution: 1000.0103000 g Original solution / Rock added: 62500.64 (Water/Rock Ratio), log = 4.7959 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.4510E-04 1.0073 0.4779E-04 0.4744E-04 CH4,gas 0.2828E-13 1.0129 0.3013E-13 0.2975E-13 H2,gas 0.1527E-05 1.0006 0.1607E-05 0.1606E-05 H2S,gas 0.5250E-10 0.9959 0.5500E-10 0.5523E-10 S2,gas 0.4169E-28 1.0000 0.4386E-28 0.4386E-28 CO,gas 0.1891E-13 1.0000 0.1990E-13 0.1990E-13 SO3,gas 0.2379E-35 1.0000 0.2502E-35 0.2502E-35 SO2,gas 0.1446E-18 1.0000 0.1521E-18 0.1521E-18 HCl,gas 0.7187E-15 1.0000 0.7561E-15 0.7561E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.68 -6.32 -2.107 0.10792E+05 -4.321 3 CH4,gas 4.81 -10.71 -15.52 -3.880 0.26502E+05 -13.521 4 H2,gas 8.29 0.49 -7.79 -4.454 0.13308E+05 -5.794 5 H2S,gas -5.94 -18.20 -12.26 -6.130 0.20933E+05 -10.260 6 S2,gas -7.03 -37.39 -30.36 -4.670 0.51835E+05 -28.358 7 CO,gas 3.51 -12.19 -15.70 -4.831 0.26809E+05 -13.701 8 SO3,gas 17.43 -20.17 -37.60 -9.400 0.64204E+05 -35.602 9 SO2,gas 1.14 -19.68 -20.82 -5.551 0.35546E+05 -18.818 10 HCl,gas 5.48 -11.64 -17.12 -8.561 0.29234E+05 -15.121 16 albite -0.33 -4.61 -4.28 -0.329 0.73139E+04 19 spessartine 24.55 19.64 -4.91 -0.246 0.83873E+04 20 analcite 3.37 -0.78 -4.15 -0.461 0.70788E+04 21 andalusite 5.06 1.96 -3.11 -0.311 0.53049E+04 24 anhydrite -5.28 -9.18 -3.90 -1.952 0.66662E+04 29 anorthite 12.80 9.11 -3.69 -0.284 0.62978E+04 35 aragonite 0.99 -1.69 -2.68 -0.893 0.45754E+04 36 brucite 12.58 8.77 -3.81 -0.762 0.65050E+04 37 calcite 0.83 -1.69 -2.53 -0.842 0.43141E+04 40 carpholite-Mg 8.65 6.89 -1.76 -0.118 0.30131E+04 41 carpholite-Fe 6.78 4.66 -2.12 -0.141 0.36177E+04 50 chloritoid-Mg 13.26 10.72 -2.54 -0.169 0.43350E+04 51 chloritoid-Fe 9.24 8.50 -0.74 -0.049 0.12599E+04 52 chloritoid-Mn 11.46 10.41 -1.06 -0.070 0.18028E+04 54 coesite -2.37 -3.84 -1.47 -0.489 0.25054E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.84 -1.29 -0.429 0.21983E+04 67 diopside 16.22 12.08 -4.13 -0.413 0.70544E+04 68 hedenbergite 14.24 9.86 -4.38 -0.438 0.74821E+04 75 epidote 24.78 22.56 -2.21 -0.107 0.37792E+04 76 clinozoisite 22.92 19.16 -3.76 -0.171 0.64235E+04 77 epidote-Fe 29.94 25.96 -3.97 -0.206 0.67824E+04 78 fayalite 14.08 9.25 -4.83 -0.689 0.82386E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.96 -4.23 -0.353 0.72254E+04 91 heulandite -5.71 -10.07 -4.37 -0.199 0.74566E+04 98 kaolinite -1.27 -1.88 -0.61 -0.055 0.10382E+04 99 kyanite 4.93 1.96 -2.98 -0.298 0.50817E+04 101 laumontite 2.97 1.44 -1.54 -0.103 0.26272E+04 102 lawsonite 9.68 9.11 -0.57 -0.038 0.97170E+03 105 lizardite 23.29 18.63 -4.66 -0.388 0.79570E+04 106 magnesite 0.71 -3.92 -4.63 -1.542 0.78993E+04 107 magnetite 20.13 19.14 -0.99 -0.081 0.16901E+04 110 magnesioferrite 26.26 21.36 -4.89 -0.399 0.83543E+04 113 margarite 17.45 14.90 -2.55 -0.102 0.43546E+04 116 microcline -2.43 -6.34 -3.90 -0.300 0.66670E+04 120 muscovite 2.68 -0.54 -3.22 -0.190 0.55039E+04 121 paragonite 4.34 1.18 -3.16 -0.186 0.53892E+04 136 prehnite 19.47 16.26 -3.20 -0.188 0.54695E+04 137 prehnite-Fe 22.59 19.67 -2.92 -0.176 0.49875E+04 138 pumpellyite-Fe 46.47 41.97 -4.50 -0.100 0.76887E+04 145 pyroxmangite 7.42 4.62 -2.80 -0.560 0.47823E+04 146 pyrophyllite -6.10 -9.55 -3.46 -0.216 0.59019E+04 147 quartz -2.98 -3.84 -0.85 -0.285 0.14594E+04 152 rhodochrosite -0.96 -4.23 -3.27 -1.091 0.55894E+04 153 rhodonite 7.46 4.62 -2.85 -0.569 0.48616E+04 156 siderite -2.59 -6.14 -3.55 -1.184 0.60631E+04 157 sillimanite 5.32 1.96 -3.37 -0.337 0.57471E+04 164 stilbite -7.41 -10.07 -2.67 -0.127 0.45560E+04 165 stilpnomelane-Fe 13.18 8.96 -4.22 -0.126 0.71975E+04 169 sudoite 21.22 17.61 -3.61 -0.116 0.61607E+04 178 topaz-H 4.67 1.96 -2.71 -0.247 0.46308E+04 179 tridymite -2.61 -3.84 -1.22 -0.407 0.20866E+04 188 wairakite 4.06 1.44 -2.62 -0.154 0.44780E+04 189 walstromite 11.53 7.15 -4.37 -0.875 0.74686E+04 190 wollastonite 10.48 7.15 -3.33 -0.666 0.56825E+04 191 pseudo-wollastonite 11.02 7.15 -3.87 -0.773 0.66011E+04 192 zoisite 22.96 19.16 -3.80 -0.173 0.64960E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.52 -3.96 -0.245 0.67610E+04 197 beidellite-Mg -1.71 -5.89 -4.18 -0.259 0.71361E+04 198 beidellite-Na -1.26 -6.01 -4.76 -0.291 0.81190E+04 200 chalcedony -2.79 -3.84 -1.04 -0.347 0.17797E+04 202 montmorillonite-Ca -2.21 -5.80 -3.59 -0.222 0.61294E+04 203 montmorillonite-K -2.16 -6.87 -4.70 -0.288 0.80330E+04 204 montmorillonite-Mg -2.40 -6.17 -3.77 -0.233 0.64355E+04 205 montmorillonite-Na -1.96 -6.30 -4.34 -0.266 0.74034E+04 206 nontronite-Ca 3.28 1.29 -1.99 -0.129 0.34039E+04 207 nontronite-H 2.60 -0.53 -3.12 -0.209 0.53325E+04 208 nontronite-K 3.40 0.22 -3.18 -0.204 0.54290E+04 209 nontronite-Mg 3.14 0.92 -2.22 -0.144 0.37906E+04 210 nontronite-Na 3.58 0.79 -2.79 -0.179 0.47628E+04 215 gypsum -4.92 -9.18 -4.26 -1.065 0.72730E+04 225 tobermorite 9.84 5.32 -4.52 -1.233 0.77188E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.55 -3.28 -0.820 0.55986E+04 241 silica-amorphous -2.08 -3.84 -1.76 -0.586 0.29999E+04 243 an20ab80 2.08 -1.87 -3.95 -0.304 0.67390E+04 244 an25ab75 2.71 -1.18 -3.89 -0.299 0.66432E+04 245 an30ab70 3.34 -0.50 -3.84 -0.295 0.65558E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0160000 g New total amount of reactant added: 0.0164000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0164000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2983463E-03 Osmotic coef. = 0.9897 True ionic strength = .3088672E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.17468E-07 -7.7577 0.16762E-07 -7.7757 0.95958E+00 -0.0179 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13237E-03 -3.8782 0.95945E+00 -0.0180 4 SO4-- 0.25296E-04 -4.5970 0.22622E-04 -4.6455 0.89431E+00 -0.0485 5 HCO3- 0.12555E-04 -4.9012 0.12047E-04 -4.9191 0.95948E+00 -0.0180 6 HS- 0.32885E-10 -10.4830 0.31552E-10 -10.5010 0.95945E+00 -0.0180 7 Al+++ 0.46631E-20 -20.3313 0.37075E-20 -20.4309 0.79509E+00 -0.0996 8 H4SiO4 0.14906E-03 -3.8266 0.14906E-03 -3.8266 0.10000E+01 0.0000 9 Ca++ 0.32795E-04 -4.4842 0.29324E-04 -4.5328 0.89417E+00 -0.0486 10 Mg++ 0.18124E-06 -6.7418 0.16204E-06 -6.7904 0.89407E+00 -0.0486 11 Fe++ 0.10867E-08 -8.9639 0.97160E-09 -9.0125 0.89410E+00 -0.0486 12 K+ 0.34807E-05 -5.4583 0.33397E-05 -5.4763 0.95949E+00 -0.0180 13 Na+ 0.18062E-03 -3.7432 0.17330E-03 -3.7612 0.95945E+00 -0.0180 14 Mn++ 0.90621E-07 -7.0428 0.81025E-07 -7.0914 0.89411E+00 -0.0486 15 HPO4-- 0.17351E-08 -8.7607 0.15517E-08 -8.8092 0.89432E+00 -0.0485 16 HSiO3- 0.90430E-05 -5.0437 0.86763E-05 -5.0617 0.95945E+00 -0.0180 17 Ca(HSiO3)+ 0.59411E-08 -8.2261 0.57004E-08 -8.2441 0.95949E+00 -0.0180 18 Mg(HSiO3)+ 0.40857E-10 -10.3887 0.39202E-10 -10.4067 0.95949E+00 -0.0180 19 NaHSiO3,aq 0.23881E-07 -7.6220 0.23881E-07 -7.6220 0.10000E+01 0.0000 20 AlO+ 0.17754E-11 -11.7507 0.17035E-11 -11.7687 0.95949E+00 -0.0180 21 AlOH+2 0.15997E-15 -15.7960 0.14304E-15 -15.8445 0.89413E+00 -0.0486 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.28236E-05 -5.5492 0.27090E-05 -5.5672 0.95941E+00 -0.0180 24 CH4,aq 0.16488E-16 -16.7828 0.16487E-16 -16.7829 0.99991E+00 0.0000 29 CO,aq 0.11926E-16 -16.9235 0.11926E-16 -16.9235 0.10000E+01 0.0000 30 CO2,aq 0.40717E-06 -6.3902 0.40713E-06 -6.3903 0.99991E+00 0.0000 31 CO3-2 0.74305E-07 -7.1290 0.66449E-07 -7.1775 0.89427E+00 -0.0485 32 CaCO3,aq 0.23865E-07 -7.6222 0.23865E-07 -7.6222 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.92768E-08 -8.0326 0.89010E-08 -8.0506 0.95949E+00 -0.0180 34 CaCl+ 0.64463E-08 -8.1907 0.61852E-08 -8.2086 0.95949E+00 -0.0180 35 CaCl2,aq 0.19063E-12 -12.7198 0.19063E-12 -12.7198 0.10000E+01 0.0000 36 CaOH+ 0.12856E-06 -6.8909 0.12336E-06 -6.9088 0.95949E+00 -0.0180 37 CaSO4,aq 0.20669E-06 -6.6847 0.20669E-06 -6.6847 0.10000E+01 0.0000 38 HCl,aq 0.41734E-12 -12.3795 0.41734E-12 -12.3795 0.10000E+01 0.0000 43 FeCl+ 0.20876E-12 -12.6803 0.20031E-12 -12.6983 0.95949E+00 -0.0180 46 FeO,aq 0.13674E-09 -9.8641 0.13674E-09 -9.8641 0.10000E+01 0.0000 47 FeOH+ 0.20028E-08 -8.6984 0.19216E-08 -8.7163 0.95949E+00 -0.0180 48 HFeO2- 0.91453E-10 -10.0388 0.87745E-10 -10.0568 0.95945E+00 -0.0180 49 FeO+ 0.14451E-12 -12.8401 0.13866E-12 -12.8580 0.95949E+00 -0.0180 50 FeOH+2 0.48371E-18 -18.3154 0.43250E-18 -18.3640 0.89413E+00 -0.0486 51 FeO2- 0.10109E-09 -9.9953 0.96992E-10 -10.0133 0.95945E+00 -0.0180 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.11375E-08 -8.9441 0.11374E-08 -8.9441 0.99991E+00 0.0000 54 KCl,aq 0.78273E-11 -11.1064 0.78273E-11 -11.1064 0.10000E+01 0.0000 55 KHSO4,aq 0.33889E-17 -17.4699 0.33889E-17 -17.4699 0.10000E+01 0.0000 56 KOH,aq 0.86857E-10 -10.0612 0.86857E-10 -10.0612 0.10000E+01 0.0000 57 KSO4- 0.12132E-08 -8.9161 0.11640E-08 -8.9341 0.95945E+00 -0.0180 58 MgCO3,aq 0.32953E-10 -10.4821 0.32953E-10 -10.4821 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.52274E-10 -10.2817 0.50156E-10 -10.2997 0.95949E+00 -0.0180 60 MgCl+ 0.32338E-10 -10.4903 0.31028E-10 -10.5082 0.95949E+00 -0.0180 61 MgOH+ 0.39358E-08 -8.4050 0.37764E-08 -8.4229 0.95949E+00 -0.0180 63 MnO,aq 0.30442E-09 -9.5165 0.30442E-09 -9.5165 0.10000E+01 0.0000 64 MnOH+ 0.15515E-07 -7.8092 0.14887E-07 -7.8272 0.95949E+00 -0.0180 65 MnO2-2 0.41899E-16 -16.3778 0.37469E-16 -16.4263 0.89427E+00 -0.0485 66 HMnO2- 0.14183E-12 -12.8482 0.13608E-12 -12.8662 0.95945E+00 -0.0180 69 MnCl+ 0.67651E-10 -10.1697 0.64911E-10 -10.1877 0.95949E+00 -0.0180 70 MnSO4,aq 0.51947E-09 -9.2844 0.51947E-09 -9.2844 0.10000E+01 0.0000 71 NaCl,aq 0.74901E-08 -8.1255 0.74901E-08 -8.1255 0.10000E+01 0.0000 72 NaOH,aq 0.45428E-08 -8.3427 0.45428E-08 -8.3427 0.10000E+01 0.0000 74 OH- 0.37299E-04 -4.4283 0.35785E-04 -4.4463 0.95941E+00 -0.0180 82 H3PO4,aq 0.28069E-14 -14.5518 0.28069E-14 -14.5518 0.10000E+01 0.0000 83 H2PO4- 0.47528E-09 -9.3231 0.45602E-09 -9.3410 0.95947E+00 -0.0180 84 PO4-3 0.10157E-12 -12.9933 0.80845E-13 -13.0923 0.79598E+00 -0.0991 87 H2P2O7-2 0.18200E-19 -19.7399 0.16275E-19 -19.7885 0.89427E+00 -0.0485 88 HP2O7-3 0.25041E-18 -18.6014 0.19910E-18 -18.7009 0.79509E+00 -0.0996 90 H2S,aq 0.15892E-11 -11.7988 0.15890E-11 -11.7989 0.99991E+00 0.0000 96 SO2,aq 0.30289E-19 -19.5187 0.30289E-19 -19.5187 0.10000E+01 0.0000 97 SO3-2 0.39218E-14 -14.4065 0.35083E-14 -14.4549 0.89457E+00 -0.0484 98 HSO3- 0.35869E-14 -14.4453 0.34415E-14 -14.4633 0.95945E+00 -0.0180 99 HSO4- 0.36669E-09 -9.4357 0.35185E-09 -9.4536 0.95951E+00 -0.0179 101 S2O3-2 0.47376E-18 -18.3244 0.42367E-18 -18.3730 0.89427E+00 -0.0485 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1746830E-07 -.5755634E-04 -.5801175E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999710E+06 0.0000 3 Cl- 0.1379610E-03 0.1379751E-03 0.4891496E+01 3.8974 4 SO4-- 0.2529580E-04 0.2550435E-04 0.2449922E+01 10.9059 5 HCO3- 0.1255538E-04 0.1307008E-04 0.7974780E+00 2.8565 6 HS- 0.3288507E-10 0.2807569E-09 0.9284939E-05 -2.7253 7 Al+++ 0.4663064E-20 0.2843901E-05 0.7673062E-01 2.8961 8 H4SiO4 0.1490622E-03 0.1581350E-03 0.1519880E+02 -3.8266 9 Ca++ 0.3279476E-04 0.3317555E-04 0.1329573E+01 11.0186 10 Mg++ 0.1812382E-06 0.1853324E-06 0.4505678E-02 8.7610 11 Fe++ 0.1086681E-08 0.3622546E-08 0.2023028E-03 6.5388 12 K+ 0.3480668E-05 0.3481975E-05 0.1361485E+00 2.2994 13 Na+ 0.1806222E-03 0.1806581E-03 0.4153181E+01 4.0145 14 Mn++ 0.9062079E-07 0.1070278E-06 0.5879733E-02 8.4600 15 HPO4-- 0.1735101E-08 0.2210485E-08 0.2121544E-03 6.7421 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2585197E-03 -.5755597E-04 -.2009637E-03 0.0000000E+00 2 H2O 0.5550804E+02 0.5550793E+02 0.1133582E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2595897E-04 0.2550419E-04 0.4547807E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4544999E-06 0.2807552E-09 -.4547807E-06 0.0000000E+00 7 Al+++ 0.5347616E-04 0.2843883E-05 0.5063228E-04 0.0000000E+00 8 H4SiO4 0.1707696E-03 0.1581340E-03 0.1263560E-04 0.0000000E+00 9 Ca++ 0.3333340E-04 0.3317534E-04 0.1580630E-06 0.0000000E+00 10 Mg++ 0.1301587E-04 0.1853312E-06 0.1283054E-04 0.0000000E+00 11 Fe++ 0.1169334E-04 0.3622523E-08 0.1168972E-04 0.0000000E+00 12 K+ 0.3481953E-05 0.3481953E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1806570E-03 0.1806570E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2843530E-06 0.1070271E-06 0.1773258E-06 0.0000000E+00 15 HPO4-- 0.9704826E-07 0.2210471E-08 0.9483779E-07 0.0000000E+00 Chg. balance for solid moles: 0.5135E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0164000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3161E-07 -7.500 0.1588E-04 -4.799 0.2920 0.5046E-05 clinochlore 0.2566E-05 -5.591 0.1426E-02 -2.846 26.22 0.5425E-03 daphnite 0.1610E-05 -5.793 0.1149E-02 -2.940 21.12 0.3482E-03 chlorite-Mn 0.3547E-07 -7.450 0.2514E-04 -4.600 0.4623 0.8013E-05 diaspore 0.4221E-04 -4.375 0.2532E-02 -2.597 46.56 0.7538E-03 hematite 0.1819E-05 -5.740 0.2905E-03 -3.537 5.341 0.5506E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6093E+00 0.6093E+00 1.0000 -0.215 daphnite 0.3823E+00 0.3823E+00 1.0000 -0.418 chlorite-Mn 0.8420E-02 0.8420E-02 1.0000 -2.075 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.005439 g Volume = 0.001713 cm3 Porosity: 99.8299% V(tot) - V(min): 0.10048E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0164000 g log = -1.7852 Original solution: 1000.0103000 g Original solution / Rock added: 60976.24 (Water/Rock Ratio), log = 4.7852 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.4398E-04 1.0073 0.4660E-04 0.4626E-04 CH4,gas 0.2447E-13 1.0129 0.2607E-13 0.2574E-13 H2,gas 0.1482E-05 1.0006 0.1560E-05 0.1559E-05 H2S,gas 0.4424E-10 0.9959 0.4635E-10 0.4654E-10 S2,gas 0.3143E-28 1.0000 0.3306E-28 0.3306E-28 CO,gas 0.1790E-13 1.0000 0.1883E-13 0.1883E-13 SO3,gas 0.2259E-35 1.0000 0.2376E-35 0.2376E-35 SO2,gas 0.1333E-18 1.0000 0.1402E-18 0.1402E-18 HCl,gas 0.7005E-15 1.0000 0.7369E-15 0.7369E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 0.98575E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.69 -6.33 -2.111 0.10811E+05 -4.332 3 CH4,gas 4.81 -10.77 -15.58 -3.896 0.26609E+05 -13.584 4 H2,gas 8.29 0.48 -7.81 -4.461 0.13330E+05 -5.807 5 H2S,gas -5.94 -18.28 -12.33 -6.167 0.21060E+05 -10.334 6 S2,gas -7.03 -37.51 -30.48 -4.689 0.52045E+05 -28.481 7 CO,gas 3.51 -12.21 -15.73 -4.838 0.26850E+05 -13.725 8 SO3,gas 17.43 -20.20 -37.62 -9.406 0.64242E+05 -35.624 9 SO2,gas 1.14 -19.72 -20.85 -5.561 0.35606E+05 -18.853 10 HCl,gas 5.48 -11.65 -17.13 -8.566 0.29253E+05 -15.133 16 albite -0.33 -4.57 -4.24 -0.326 0.72414E+04 19 spessartine 24.55 19.69 -4.86 -0.243 0.82945E+04 20 analcite 3.37 -0.74 -4.11 -0.457 0.70234E+04 21 andalusite 5.06 1.97 -3.10 -0.310 0.52877E+04 22 andradite 39.09 34.17 -4.91 -0.255 0.83911E+04 24 anhydrite -5.28 -9.18 -3.90 -1.949 0.66566E+04 29 anorthite 12.80 9.16 -3.64 -0.280 0.62156E+04 35 aragonite 0.99 -1.68 -2.66 -0.887 0.45461E+04 36 brucite 12.58 8.76 -3.82 -0.763 0.65151E+04 37 calcite 0.83 -1.68 -2.51 -0.836 0.42848E+04 40 carpholite-Mg 8.65 6.90 -1.75 -0.117 0.29889E+04 41 carpholite-Fe 6.78 4.68 -2.11 -0.140 0.35945E+04 50 chloritoid-Mg 13.26 10.73 -2.53 -0.169 0.43280E+04 51 chloritoid-Fe 9.24 8.50 -0.73 -0.049 0.12538E+04 52 chloritoid-Mn 11.46 10.43 -1.04 -0.069 0.17719E+04 54 coesite -2.37 -3.83 -1.46 -0.486 0.24883E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.83 -1.28 -0.426 0.21812E+04 67 diopside 16.22 12.13 -4.09 -0.409 0.69822E+04 68 hedenbergite 14.24 9.90 -4.34 -0.434 0.74110E+04 75 epidote 24.78 22.65 -2.13 -0.103 0.36318E+04 76 clinozoisite 22.92 19.25 -3.68 -0.167 0.62761E+04 77 epidote-Fe 29.94 26.05 -3.89 -0.202 0.66350E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82436E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.96 -4.23 -0.353 0.72243E+04 91 heulandite -5.71 -9.98 -4.27 -0.194 0.72885E+04 95 jadeite 4.25 -0.74 -4.99 -0.499 0.85265E+04 98 kaolinite -1.27 -1.86 -0.59 -0.053 0.10039E+04 99 kyanite 4.93 1.97 -2.97 -0.297 0.50645E+04 101 laumontite 2.97 1.50 -1.47 -0.098 0.25106E+04 102 lawsonite 9.68 9.16 -0.52 -0.035 0.88943E+03 105 lizardite 23.29 18.63 -4.66 -0.388 0.79531E+04 106 magnesite 0.71 -3.93 -4.64 -1.548 0.79280E+04 107 magnetite 20.13 19.14 -1.00 -0.081 0.17012E+04 110 magnesioferrite 26.26 21.36 -4.90 -0.400 0.83644E+04 113 margarite 17.45 14.95 -2.50 -0.100 0.42724E+04 116 microcline -2.43 -6.28 -3.85 -0.296 0.65783E+04 120 muscovite 2.68 -0.49 -3.17 -0.187 0.54152E+04 121 paragonite 4.34 1.22 -3.11 -0.183 0.53167E+04 136 prehnite 19.47 16.35 -3.12 -0.183 0.53221E+04 137 prehnite-Fe 22.59 19.75 -2.83 -0.171 0.48401E+04 138 pumpellyite-Fe 46.47 42.13 -4.34 -0.096 0.74051E+04 139 pumpellyite-Mg 49.19 44.36 -4.84 -0.108 0.82611E+04 145 pyroxmangite 7.42 4.63 -2.78 -0.557 0.47514E+04 146 pyrophyllite -6.10 -9.51 -3.42 -0.214 0.58333E+04 147 quartz -2.98 -3.83 -0.84 -0.282 0.14422E+04 152 rhodochrosite -0.96 -4.23 -3.28 -1.092 0.55942E+04 153 rhodonite 7.46 4.63 -2.83 -0.566 0.48306E+04 156 siderite -2.59 -6.16 -3.57 -1.189 0.60928E+04 157 sillimanite 5.32 1.97 -3.36 -0.336 0.57299E+04 164 stilbite -7.41 -9.98 -2.57 -0.122 0.43879E+04 165 stilpnomelane-Fe 13.18 9.02 -4.16 -0.124 0.70970E+04 169 sudoite 21.22 17.63 -3.59 -0.116 0.61295E+04 178 topaz-H 4.67 1.97 -2.70 -0.246 0.46136E+04 179 tridymite -2.61 -3.83 -1.21 -0.404 0.20695E+04 188 wairakite 4.06 1.50 -2.55 -0.150 0.43614E+04 189 walstromite 11.53 7.19 -4.34 -0.867 0.74035E+04 190 wollastonite 10.48 7.19 -3.29 -0.658 0.56174E+04 191 pseudo-wollastonite 11.02 7.19 -3.83 -0.766 0.65360E+04 192 zoisite 22.96 19.25 -3.72 -0.169 0.63486E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.48 -3.92 -0.242 0.66901E+04 197 beidellite-Mg -1.71 -5.85 -4.14 -0.256 0.70748E+04 198 beidellite-Na -1.26 -5.97 -4.71 -0.289 0.80491E+04 200 chalcedony -2.79 -3.83 -1.03 -0.344 0.17625E+04 202 montmorillonite-Ca -2.21 -5.76 -3.55 -0.219 0.60562E+04 203 montmorillonite-K -2.16 -6.82 -4.66 -0.285 0.79554E+04 204 montmorillonite-Mg -2.40 -6.13 -3.73 -0.231 0.63719E+04 205 montmorillonite-Na -1.96 -6.25 -4.29 -0.263 0.73311E+04 206 nontronite-Ca 3.28 1.33 -1.95 -0.127 0.33330E+04 207 nontronite-H 2.60 -0.49 -3.09 -0.207 0.52695E+04 208 nontronite-K 3.40 0.27 -3.14 -0.201 0.53537E+04 209 nontronite-Mg 3.14 0.96 -2.18 -0.142 0.37293E+04 210 nontronite-Na 3.58 0.83 -2.75 -0.176 0.46929E+04 215 gypsum -4.92 -9.18 -4.25 -1.063 0.72633E+04 225 tobermorite 9.84 5.35 -4.49 -1.224 0.76617E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.54 -3.29 -0.821 0.56097E+04 241 silica-amorphous -2.08 -3.83 -1.75 -0.582 0.29827E+04 243 an20ab80 2.08 -1.82 -3.90 -0.300 0.66646E+04 244 an25ab75 2.71 -1.14 -3.85 -0.296 0.65683E+04 245 an30ab70 3.34 -0.45 -3.80 -0.292 0.64804E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0164000 g New total amount of reactant added: 0.0168000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0168000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2998429E-03 Osmotic coef. = 0.9897 True ionic strength = .3107548E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.17041E-07 -7.7685 0.16351E-07 -7.7864 0.95952E+00 -0.0179 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13236E-03 -3.8783 0.95938E+00 -0.0180 4 SO4-- 0.25293E-04 -4.5970 0.22614E-04 -4.6456 0.89406E+00 -0.0486 5 HCO3- 0.12562E-04 -4.9009 0.12052E-04 -4.9189 0.95942E+00 -0.0180 6 HS- 0.28555E-10 -10.5443 0.27396E-10 -10.5623 0.95939E+00 -0.0180 7 Al+++ 0.43312E-20 -20.3634 0.34415E-20 -20.4633 0.79459E+00 -0.0999 8 H4SiO4 0.15246E-03 -3.8168 0.15246E-03 -3.8168 0.10000E+01 0.0000 9 Ca++ 0.33241E-04 -4.4783 0.29715E-04 -4.5270 0.89392E+00 -0.0487 10 Mg++ 0.17022E-06 -6.7690 0.15215E-06 -6.8177 0.89382E+00 -0.0487 11 Fe++ 0.10194E-08 -8.9916 0.91123E-09 -9.0404 0.89385E+00 -0.0487 12 K+ 0.35656E-05 -5.4479 0.34209E-05 -5.4659 0.95942E+00 -0.0180 13 Na+ 0.18112E-03 -3.7420 0.17377E-03 -3.7600 0.95938E+00 -0.0180 14 Mn++ 0.87677E-07 -7.0571 0.78371E-07 -7.1058 0.89386E+00 -0.0487 15 HPO4-- 0.16424E-08 -8.7845 0.14684E-08 -8.8331 0.89407E+00 -0.0486 16 HSiO3- 0.94826E-05 -5.0231 0.90974E-05 -5.0411 0.95938E+00 -0.0180 17 Ca(HSiO3)+ 0.63130E-08 -8.1998 0.60568E-08 -8.2178 0.95943E+00 -0.0180 18 Mg(HSiO3)+ 0.40227E-10 -10.3955 0.38595E-10 -10.4135 0.95943E+00 -0.0180 19 NaHSiO3,aq 0.25107E-07 -7.6002 0.25107E-07 -7.6002 0.10000E+01 0.0000 20 AlO+ 0.17320E-11 -11.7615 0.16617E-11 -11.7794 0.95943E+00 -0.0180 21 AlOH+2 0.15227E-15 -15.8174 0.13611E-15 -15.8661 0.89388E+00 -0.0487 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.28947E-05 -5.5384 0.27770E-05 -5.5564 0.95934E+00 -0.0180 24 CH4,aq 0.14329E-16 -16.8438 0.14327E-16 -16.8438 0.99991E+00 0.0000 29 CO,aq 0.11307E-16 -16.9467 0.11307E-16 -16.9467 0.10000E+01 0.0000 30 CO2,aq 0.39737E-06 -6.4008 0.39734E-06 -6.4008 0.99991E+00 0.0000 31 CO3-2 0.76229E-07 -7.1179 0.68151E-07 -7.1665 0.89402E+00 -0.0487 32 CaCO3,aq 0.24803E-07 -7.6055 0.24803E-07 -7.6055 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.94056E-08 -8.0266 0.90240E-08 -8.0446 0.95943E+00 -0.0180 34 CaCl+ 0.65323E-08 -8.1849 0.62672E-08 -8.2029 0.95943E+00 -0.0180 35 CaCl2,aq 0.19314E-12 -12.7141 0.19314E-12 -12.7141 0.10000E+01 0.0000 36 CaOH+ 0.13356E-06 -6.8743 0.12814E-06 -6.8923 0.95943E+00 -0.0180 37 CaSO4,aq 0.20937E-06 -6.6791 0.20937E-06 -6.6791 0.10000E+01 0.0000 38 HCl,aq 0.40708E-12 -12.3903 0.40708E-12 -12.3903 0.10000E+01 0.0000 43 FeCl+ 0.19579E-12 -12.7082 0.18785E-12 -12.7262 0.95943E+00 -0.0180 46 FeO,aq 0.13477E-09 -9.8704 0.13477E-09 -9.8704 0.10000E+01 0.0000 47 FeOH+ 0.19257E-08 -8.7154 0.18475E-08 -8.7334 0.95943E+00 -0.0180 48 HFeO2- 0.92408E-10 -10.0343 0.88655E-10 -10.0523 0.95938E+00 -0.0180 49 FeO+ 0.14098E-12 -12.8508 0.13526E-12 -12.8688 0.95943E+00 -0.0180 50 FeOH+2 0.46041E-18 -18.3369 0.41155E-18 -18.3856 0.89388E+00 -0.0487 51 FeO2- 0.10364E-09 -9.9845 0.99430E-10 -10.0025 0.95938E+00 -0.0180 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.11050E-08 -8.9567 0.11049E-08 -8.9567 0.99991E+00 0.0000 54 KCl,aq 0.80171E-11 -11.0960 0.80171E-11 -11.0960 0.10000E+01 0.0000 55 KHSO4,aq 0.33849E-17 -17.4705 0.33849E-17 -17.4705 0.10000E+01 0.0000 56 KOH,aq 0.91205E-10 -10.0400 0.91205E-10 -10.0400 0.10000E+01 0.0000 57 KSO4- 0.12423E-08 -8.9058 0.11918E-08 -8.9238 0.95938E+00 -0.0180 58 MgCO3,aq 0.31733E-10 -10.4985 0.31733E-10 -10.4985 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.49109E-10 -10.3088 0.47116E-10 -10.3268 0.95943E+00 -0.0180 60 MgCl+ 0.30363E-10 -10.5177 0.29131E-10 -10.5356 0.95943E+00 -0.0180 61 MgOH+ 0.37886E-08 -8.4215 0.36349E-08 -8.4395 0.95943E+00 -0.0180 63 MnO,aq 0.30943E-09 -9.5094 0.30943E-09 -9.5094 0.10000E+01 0.0000 64 MnOH+ 0.15385E-07 -7.8129 0.14761E-07 -7.8309 0.95943E+00 -0.0180 65 MnO2-2 0.44769E-16 -16.3490 0.40025E-16 -16.3977 0.89402E+00 -0.0487 66 HMnO2- 0.14780E-12 -12.8303 0.14180E-12 -12.8483 0.95938E+00 -0.0180 69 MnCl+ 0.65435E-10 -10.1842 0.62780E-10 -10.2022 0.95943E+00 -0.0180 70 MnSO4,aq 0.50226E-09 -9.2991 0.50226E-09 -9.2991 0.10000E+01 0.0000 71 NaCl,aq 0.75098E-08 -8.1244 0.75098E-08 -8.1244 0.10000E+01 0.0000 72 NaOH,aq 0.46696E-08 -8.3307 0.46696E-08 -8.3307 0.10000E+01 0.0000 74 OH- 0.38239E-04 -4.4175 0.36684E-04 -4.4355 0.95934E+00 -0.0180 82 H3PO4,aq 0.25276E-14 -14.5973 0.25276E-14 -14.5973 0.10000E+01 0.0000 83 H2PO4- 0.43877E-09 -9.3578 0.42096E-09 -9.3758 0.95940E+00 -0.0180 84 PO4-3 0.98591E-13 -13.0062 0.78427E-13 -13.1055 0.79549E+00 -0.0994 87 H2P2O7-2 0.15513E-19 -19.8093 0.13869E-19 -19.8580 0.89402E+00 -0.0487 88 HP2O7-3 0.21888E-18 -18.6598 0.17392E-18 -18.7596 0.79460E+00 -0.0999 90 H2S,aq 0.13460E-11 -11.8709 0.13459E-11 -11.8710 0.99991E+00 0.0000 96 SO2,aq 0.27988E-19 -19.5530 0.27988E-19 -19.5530 0.10000E+01 0.0000 97 SO3-2 0.38092E-14 -14.4192 0.34067E-14 -14.4677 0.89432E+00 -0.0485 98 HSO3- 0.33979E-14 -14.4688 0.32599E-14 -14.4868 0.95938E+00 -0.0180 99 HSO4- 0.35759E-09 -9.4466 0.34309E-09 -9.4646 0.95945E+00 -0.0180 101 S2O3-2 0.40123E-18 -18.3966 0.35871E-18 -18.4453 0.89402E+00 -0.0487 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1704124E-07 -.5924010E-04 -.5970881E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999706E+06 0.0000 3 Cl- 0.1379609E-03 0.1379751E-03 0.4891494E+01 3.9082 4 SO4-- 0.2529313E-04 0.2550437E-04 0.2449922E+01 10.9273 5 HCO3- 0.1256219E-04 0.1307009E-04 0.7974778E+00 2.8675 6 HS- 0.2855545E-10 0.2677354E-09 0.8854299E-05 -2.7759 7 Al+++ 0.4331178E-20 0.2915064E-05 0.7865062E-01 2.8961 8 H4SiO4 0.1524649E-03 0.1619789E-03 0.1556824E+02 -3.8168 9 Ca++ 0.3324147E-04 0.3363145E-04 0.1347844E+01 11.0459 10 Mg++ 0.1702201E-06 0.1741602E-06 0.4234065E-02 8.7552 11 Fe++ 0.1019450E-08 0.3479736E-08 0.1943274E-03 6.5325 12 K+ 0.3565561E-05 0.3566902E-05 0.1394691E+00 2.3206 13 Na+ 0.1811230E-03 0.1811603E-03 0.4164723E+01 4.0264 14 Mn++ 0.8767701E-07 0.1039396E-06 0.5710077E-02 8.4670 15 HPO4-- 0.1642414E-08 0.2081286E-08 0.1997542E-03 6.7397 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2651431E-03 -.5923972E-04 -.2059033E-03 0.0000000E+00 2 H2O 0.5550804E+02 0.5550792E+02 0.1161280E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2597006E-04 0.2550420E-04 0.4658530E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4655853E-06 0.2677337E-09 -.4658530E-06 0.0000000E+00 7 Al+++ 0.5478046E-04 0.2915045E-05 0.5186541E-04 0.0000000E+00 8 H4SiO4 0.1749348E-03 0.1619779E-03 0.1295686E-04 0.0000000E+00 9 Ca++ 0.3379346E-04 0.3363123E-04 0.1622234E-06 0.0000000E+00 10 Mg++ 0.1333333E-04 0.1741590E-06 0.1315917E-04 0.0000000E+00 11 Fe++ 0.1197854E-04 0.3479713E-08 0.1197506E-04 0.0000000E+00 12 K+ 0.3566879E-05 0.3566879E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1811591E-03 0.1811591E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2912884E-06 0.1039390E-06 0.1873495E-06 0.0000000E+00 15 HPO4-- 0.9941529E-07 0.2081272E-08 0.9733401E-07 0.0000000E+00 Chg. balance for solid moles: 0.1588E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0168000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3244E-07 -7.489 0.1630E-04 -4.788 0.2924 0.5179E-05 clinochlore 0.2632E-05 -5.580 0.1463E-02 -2.835 26.25 0.5564E-03 daphnite 0.1650E-05 -5.783 0.1177E-02 -2.929 21.12 0.3567E-03 chlorite-Mn 0.3747E-07 -7.426 0.2657E-04 -4.576 0.4766 0.8466E-05 diaspore 0.4323E-04 -4.364 0.2593E-02 -2.586 46.53 0.7720E-03 hematite 0.1863E-05 -5.730 0.2976E-03 -3.526 5.339 0.5640E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3820E+00 0.3820E+00 1.0000 -0.418 chlorite-Mn 0.8676E-02 0.8676E-02 1.0000 -2.062 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.005574 g Volume = 0.001755 cm3 Porosity: 99.8257% V(tot) - V(min): 0.10050E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0168000 g log = -1.7747 Original solution: 1000.0103000 g Original solution / Rock added: 59524.42 (Water/Rock Ratio), log = 4.7747 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.4292E-04 1.0073 0.4548E-04 0.4515E-04 CH4,gas 0.2126E-13 1.0129 0.2266E-13 0.2237E-13 H2,gas 0.1440E-05 1.0006 0.1515E-05 0.1515E-05 H2S,gas 0.3747E-10 0.9959 0.3925E-10 0.3942E-10 S2,gas 0.2389E-28 1.0000 0.2513E-28 0.2513E-28 CO,gas 0.1697E-13 1.0000 0.1785E-13 0.1785E-13 SO3,gas 0.2149E-35 1.0000 0.2260E-35 0.2260E-35 SO2,gas 0.1232E-18 1.0000 0.1296E-18 0.1296E-18 HCl,gas 0.6833E-15 1.0000 0.7188E-15 0.7188E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.71 -6.34 -2.114 0.10829E+05 -4.342 3 CH4,gas 4.81 -10.84 -15.64 -3.911 0.26713E+05 -13.645 4 H2,gas 8.29 0.47 -7.82 -4.468 0.13352E+05 -5.819 5 H2S,gas -5.94 -18.35 -12.41 -6.203 0.21183E+05 -10.406 6 S2,gas -7.03 -37.63 -30.60 -4.708 0.52248E+05 -28.600 7 CO,gas 3.51 -12.24 -15.75 -4.846 0.26890E+05 -13.748 8 SO3,gas 17.43 -20.22 -37.65 -9.411 0.64279E+05 -35.646 9 SO2,gas 1.14 -19.75 -20.89 -5.570 0.35665E+05 -18.887 10 HCl,gas 5.48 -11.66 -17.14 -8.572 0.29272E+05 -15.143 16 albite -0.33 -4.53 -4.20 -0.323 0.71708E+04 19 spessartine 24.55 19.74 -4.81 -0.240 0.82079E+04 20 analcite 3.37 -0.71 -4.08 -0.454 0.69696E+04 21 andalusite 5.06 1.98 -3.09 -0.309 0.52710E+04 22 andradite 39.09 34.28 -4.80 -0.250 0.82010E+04 24 anhydrite -5.28 -9.17 -3.89 -1.946 0.66470E+04 29 anorthite 12.80 9.20 -3.59 -0.276 0.61354E+04 35 aragonite 0.99 -1.66 -2.65 -0.882 0.45175E+04 36 brucite 12.58 8.76 -3.82 -0.764 0.65250E+04 37 calcite 0.83 -1.66 -2.49 -0.831 0.42562E+04 40 carpholite-Mg 8.65 6.91 -1.74 -0.116 0.29654E+04 41 carpholite-Fe 6.78 4.69 -2.09 -0.139 0.35718E+04 50 chloritoid-Mg 13.26 10.73 -2.53 -0.169 0.43212E+04 51 chloritoid-Fe 9.24 8.51 -0.73 -0.049 0.12478E+04 52 chloritoid-Mn 11.46 10.44 -1.02 -0.068 0.17430E+04 54 coesite -2.37 -3.82 -1.45 -0.482 0.24715E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.82 -1.27 -0.423 0.21644E+04 67 diopside 16.22 12.17 -4.05 -0.405 0.69120E+04 68 hedenbergite 14.24 9.94 -4.30 -0.430 0.73416E+04 75 epidote 24.78 22.73 -2.04 -0.099 0.34883E+04 76 clinozoisite 22.92 19.33 -3.59 -0.163 0.61326E+04 77 epidote-Fe 29.94 26.13 -3.80 -0.197 0.64915E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82484E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.96 -4.23 -0.353 0.72231E+04 91 heulandite -5.71 -9.88 -4.17 -0.190 0.71247E+04 95 jadeite 4.25 -0.71 -4.96 -0.496 0.84726E+04 98 kaolinite -1.27 -1.84 -0.57 -0.052 0.97043E+03 99 kyanite 4.93 1.98 -2.96 -0.296 0.50478E+04 101 laumontite 2.97 1.57 -1.40 -0.094 0.23970E+04 102 lawsonite 9.68 9.20 -0.47 -0.032 0.80932E+03 105 lizardite 23.29 18.63 -4.66 -0.388 0.79493E+04 106 magnesite 0.71 -3.95 -4.66 -1.553 0.79560E+04 107 magnetite 20.13 19.13 -1.00 -0.082 0.17120E+04 110 magnesioferrite 26.26 21.35 -4.90 -0.400 0.83743E+04 113 margarite 17.45 15.00 -2.46 -0.098 0.41922E+04 116 microcline -2.43 -6.23 -3.80 -0.292 0.64919E+04 120 muscovite 2.68 -0.44 -3.12 -0.184 0.53287E+04 121 paragonite 4.34 1.26 -3.07 -0.181 0.52461E+04 136 prehnite 19.47 16.43 -3.03 -0.178 0.51786E+04 137 prehnite-Fe 22.59 19.84 -2.75 -0.165 0.46966E+04 138 pumpellyite-Fe 46.47 42.30 -4.18 -0.093 0.71288E+04 139 pumpellyite-Mg 49.19 44.52 -4.68 -0.104 0.79840E+04 145 pyroxmangite 7.42 4.65 -2.77 -0.553 0.47226E+04 146 pyrophyllite -6.10 -9.48 -3.38 -0.211 0.57663E+04 147 quartz -2.98 -3.82 -0.83 -0.278 0.14255E+04 152 rhodochrosite -0.96 -4.24 -3.28 -1.093 0.56002E+04 153 rhodonite 7.46 4.65 -2.81 -0.562 0.48018E+04 156 siderite -2.59 -6.17 -3.59 -1.195 0.61216E+04 157 sillimanite 5.32 1.98 -3.35 -0.335 0.57132E+04 164 stilbite -7.41 -9.88 -2.47 -0.118 0.42241E+04 165 stilpnomelane-Fe 13.18 9.08 -4.10 -0.122 0.69988E+04 169 sudoite 21.22 17.64 -3.57 -0.115 0.60991E+04 175 tephroite 18.11 13.12 -5.00 -0.714 0.85299E+04 178 topaz-H 4.67 1.98 -2.69 -0.245 0.45969E+04 179 tridymite -2.61 -3.82 -1.20 -0.401 0.20527E+04 188 wairakite 4.06 1.57 -2.49 -0.146 0.42478E+04 189 walstromite 11.53 7.23 -4.30 -0.860 0.73401E+04 190 wollastonite 10.48 7.23 -3.25 -0.651 0.55540E+04 191 pseudo-wollastonite 11.02 7.23 -3.79 -0.758 0.64726E+04 192 zoisite 22.96 19.33 -3.63 -0.165 0.62052E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.44 -3.88 -0.240 0.66210E+04 197 beidellite-Mg -1.71 -5.82 -4.11 -0.254 0.70150E+04 198 beidellite-Na -1.26 -5.93 -4.67 -0.286 0.79810E+04 200 chalcedony -2.79 -3.82 -1.02 -0.341 0.17458E+04 202 montmorillonite-Ca -2.21 -5.72 -3.51 -0.217 0.59848E+04 203 montmorillonite-K -2.16 -6.78 -4.61 -0.283 0.78798E+04 204 montmorillonite-Mg -2.40 -6.10 -3.70 -0.229 0.63098E+04 205 montmorillonite-Na -1.96 -6.21 -4.25 -0.260 0.72607E+04 206 nontronite-Ca 3.28 1.37 -1.91 -0.124 0.32639E+04 207 nontronite-H 2.60 -0.45 -3.05 -0.204 0.52081E+04 208 nontronite-K 3.40 0.31 -3.09 -0.198 0.52803E+04 209 nontronite-Mg 3.14 0.99 -2.15 -0.139 0.36695E+04 210 nontronite-Na 3.58 0.87 -2.71 -0.174 0.46248E+04 215 gypsum -4.92 -9.17 -4.25 -1.062 0.72538E+04 225 tobermorite 9.84 5.38 -4.45 -1.215 0.76061E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.53 -3.29 -0.823 0.56205E+04 241 silica-amorphous -2.08 -3.82 -1.74 -0.579 0.29660E+04 243 an20ab80 2.08 -1.78 -3.86 -0.297 0.65921E+04 244 an25ab75 2.71 -1.09 -3.80 -0.293 0.64953E+04 245 an30ab70 3.34 -0.41 -3.75 -0.289 0.64069E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0168000 g New total amount of reactant added: 0.0172000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0172000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3013396E-03 Osmotic coef. = 0.9896 True ionic strength = .3126454E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.16637E-07 -7.7789 0.15962E-07 -7.7969 0.95945E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13235E-03 -3.8783 0.95932E+00 -0.0180 4 SO4-- 0.25290E-04 -4.5970 0.22605E-04 -4.6458 0.89382E+00 -0.0488 5 HCO3- 0.12568E-04 -4.9007 0.12058E-04 -4.9187 0.95935E+00 -0.0180 6 HS- 0.24898E-10 -10.6038 0.23885E-10 -10.6219 0.95932E+00 -0.0180 7 Al+++ 0.40319E-20 -20.3945 0.32017E-20 -20.4946 0.79409E+00 -0.1001 8 H4SiO4 0.15586E-03 -3.8073 0.15586E-03 -3.8073 0.10000E+01 0.0000 9 Ca++ 0.33688E-04 -4.4725 0.30106E-04 -4.5213 0.89367E+00 -0.0488 10 Mg++ 0.16016E-06 -6.7955 0.14311E-06 -6.8443 0.89357E+00 -0.0489 11 Fe++ 0.95821E-09 -9.0185 0.85625E-09 -9.0674 0.89360E+00 -0.0489 12 K+ 0.36505E-05 -5.4377 0.35021E-05 -5.4557 0.95935E+00 -0.0180 13 Na+ 0.18162E-03 -3.7408 0.17423E-03 -3.7589 0.95931E+00 -0.0180 14 Mn++ 0.84783E-07 -7.0717 0.75763E-07 -7.1205 0.89361E+00 -0.0489 15 HPO4-- 0.15567E-08 -8.8078 0.13914E-08 -8.8565 0.89382E+00 -0.0488 16 HSiO3- 0.99306E-05 -5.0030 0.95266E-05 -5.0211 0.95932E+00 -0.0180 17 Ca(HSiO3)+ 0.66982E-08 -8.1740 0.64260E-08 -8.1921 0.95936E+00 -0.0180 18 Mg(HSiO3)+ 0.39626E-10 -10.4020 0.38016E-10 -10.4200 0.95936E+00 -0.0180 19 NaHSiO3,aq 0.26363E-07 -7.5790 0.26363E-07 -7.5790 0.10000E+01 0.0000 20 AlO+ 0.16909E-11 -11.7719 0.16222E-11 -11.7899 0.95936E+00 -0.0180 21 AlOH+2 0.14515E-15 -15.8382 0.12971E-15 -15.8870 0.89363E+00 -0.0488 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.29655E-05 -5.5279 0.28447E-05 -5.5460 0.95928E+00 -0.0181 24 CH4,aq 0.12503E-16 -16.9030 0.12501E-16 -16.9030 0.99991E+00 0.0000 29 CO,aq 0.10736E-16 -16.9692 0.10736E-16 -16.9692 0.10000E+01 0.0000 30 CO2,aq 0.38809E-06 -6.4111 0.38805E-06 -6.4111 0.99991E+00 0.0000 31 CO3-2 0.78142E-07 -7.1071 0.69841E-07 -7.1559 0.89377E+00 -0.0488 32 CaCO3,aq 0.25752E-07 -7.5892 0.25752E-07 -7.5892 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.95341E-08 -8.0207 0.91466E-08 -8.0387 0.95936E+00 -0.0180 34 CaCl+ 0.66182E-08 -8.1793 0.63492E-08 -8.1973 0.95936E+00 -0.0180 35 CaCl2,aq 0.19565E-12 -12.7085 0.19565E-12 -12.7085 0.10000E+01 0.0000 36 CaOH+ 0.13862E-06 -6.8582 0.13299E-06 -6.8762 0.95936E+00 -0.0180 37 CaSO4,aq 0.21204E-06 -6.6736 0.21204E-06 -6.6736 0.10000E+01 0.0000 38 HCl,aq 0.39737E-12 -12.4008 0.39737E-12 -12.4008 0.10000E+01 0.0000 43 FeCl+ 0.18398E-12 -12.7352 0.17650E-12 -12.7532 0.95936E+00 -0.0180 46 FeO,aq 0.13289E-09 -9.8765 0.13289E-09 -9.8765 0.10000E+01 0.0000 47 FeOH+ 0.18537E-08 -8.7320 0.17784E-08 -8.7500 0.95936E+00 -0.0180 48 HFeO2- 0.93342E-10 -10.0299 0.89545E-10 -10.0480 0.95932E+00 -0.0180 49 FeO+ 0.13764E-12 -12.8613 0.13204E-12 -12.8793 0.95936E+00 -0.0180 50 FeOH+2 0.43889E-18 -18.3576 0.39221E-18 -18.4065 0.89363E+00 -0.0488 51 FeO2- 0.10617E-09 -9.9740 0.10185E-09 -9.9920 0.95932E+00 -0.0180 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.10743E-08 -8.9689 0.10742E-08 -8.9689 0.99991E+00 0.0000 54 KCl,aq 0.82068E-11 -11.0858 0.82068E-11 -11.0858 0.10000E+01 0.0000 55 KHSO4,aq 0.33815E-17 -17.4709 0.33815E-17 -17.4709 0.10000E+01 0.0000 56 KOH,aq 0.95645E-10 -10.0193 0.95645E-10 -10.0193 0.10000E+01 0.0000 57 KSO4- 0.12714E-08 -8.8957 0.12196E-08 -8.9138 0.95932E+00 -0.0180 58 MgCO3,aq 0.30590E-10 -10.5144 0.30590E-10 -10.5144 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.46216E-10 -10.3352 0.44338E-10 -10.3532 0.95936E+00 -0.0180 60 MgCl+ 0.28561E-10 -10.5442 0.27400E-10 -10.5623 0.95936E+00 -0.0180 61 MgOH+ 0.36508E-08 -8.4376 0.35024E-08 -8.4556 0.95936E+00 -0.0180 63 MnO,aq 0.31389E-09 -9.5032 0.31389E-09 -9.5032 0.10000E+01 0.0000 64 MnOH+ 0.15237E-07 -7.8171 0.14618E-07 -7.8351 0.95936E+00 -0.0180 65 MnO2-2 0.47667E-16 -16.3218 0.42604E-16 -16.3706 0.89377E+00 -0.0488 66 HMnO2- 0.15359E-12 -12.8136 0.14734E-12 -12.8317 0.95932E+00 -0.0180 69 MnCl+ 0.63258E-10 -10.1989 0.60687E-10 -10.2169 0.95936E+00 -0.0180 70 MnSO4,aq 0.48536E-09 -9.3139 0.48536E-09 -9.3139 0.10000E+01 0.0000 71 NaCl,aq 0.75295E-08 -8.1232 0.75295E-08 -8.1232 0.10000E+01 0.0000 72 NaOH,aq 0.47963E-08 -8.3191 0.47963E-08 -8.3191 0.10000E+01 0.0000 74 OH- 0.39173E-04 -4.4070 0.37578E-04 -4.4251 0.95928E+00 -0.0181 82 H3PO4,aq 0.22824E-14 -14.6416 0.22824E-14 -14.6416 0.10000E+01 0.0000 83 H2PO4- 0.40590E-09 -9.3916 0.38939E-09 -9.4096 0.95934E+00 -0.0180 84 PO4-3 0.95755E-13 -13.0188 0.76125E-13 -13.1185 0.79499E+00 -0.0996 87 H2P2O7-2 0.13277E-19 -19.8769 0.11867E-19 -19.9257 0.89377E+00 -0.0488 88 HP2O7-3 0.19197E-18 -18.7168 0.15244E-18 -18.8169 0.79410E+00 -0.1001 90 H2S,aq 0.11456E-11 -11.9410 0.11455E-11 -11.9410 0.99991E+00 0.0000 96 SO2,aq 0.25921E-19 -19.5863 0.25921E-19 -19.5863 0.10000E+01 0.0000 97 SO3-2 0.37030E-14 -14.4314 0.33108E-14 -14.4801 0.89407E+00 -0.0486 98 HSO3- 0.32239E-14 -14.4916 0.30927E-14 -14.5097 0.95932E+00 -0.0180 99 HSO4- 0.34898E-09 -9.4572 0.33480E-09 -9.4752 0.95938E+00 -0.0180 101 S2O3-2 0.34145E-18 -18.4667 0.30518E-18 -18.5154 0.89377E+00 -0.0488 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1663705E-07 -.6092462E-04 -.6140663E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999702E+06 0.0000 3 Cl- 0.1379608E-03 0.1379751E-03 0.4891493E+01 3.9186 4 SO4-- 0.2529047E-04 0.2550438E-04 0.2449923E+01 10.9480 5 HCO3- 0.1256849E-04 0.1307009E-04 0.7974776E+00 2.8782 6 HS- 0.2489765E-10 0.2558875E-09 0.8462474E-05 -2.8250 7 Al+++ 0.4031937E-20 0.2985804E-05 0.8055920E-01 2.8961 8 H4SiO4 0.1558598E-03 0.1658235E-03 0.1593774E+02 -3.8073 9 Ca++ 0.3368810E-04 0.3408737E-04 0.1366115E+01 11.0725 10 Mg++ 0.1601581E-06 0.1639539E-06 0.3985934E-02 8.7495 11 Fe++ 0.9582081E-09 0.3348093E-08 0.1869757E-03 6.5264 12 K+ 0.3650454E-05 0.3651829E-05 0.1427898E+00 2.3412 13 Na+ 0.1816237E-03 0.1816624E-03 0.4176264E+01 4.0380 14 Mn++ 0.8478306E-07 0.1008826E-06 0.5542129E-02 8.4733 15 HPO4-- 0.1556700E-08 0.1962694E-08 0.1883721E-03 6.7373 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2717665E-03 -.6092422E-04 -.2108422E-03 0.0000000E+00 2 H2O 0.5550803E+02 0.5550792E+02 0.1188983E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2598114E-04 0.2550421E-04 0.4769265E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4766706E-06 0.2558858E-09 -.4769265E-06 0.0000000E+00 7 Al+++ 0.5608476E-04 0.2985784E-05 0.5309897E-04 0.0000000E+00 8 H4SiO4 0.1790999E-03 0.1658224E-03 0.1327750E-04 0.0000000E+00 9 Ca++ 0.3425351E-04 0.3408715E-04 0.1663661E-06 0.0000000E+00 10 Mg++ 0.1365079E-04 0.1639528E-06 0.1348684E-04 0.0000000E+00 11 Fe++ 0.1226375E-04 0.3348070E-08 0.1226040E-04 0.0000000E+00 12 K+ 0.3651805E-05 0.3651805E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1816612E-03 0.1816612E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2982239E-06 0.1008819E-06 0.1973420E-06 0.0000000E+00 15 HPO4-- 0.1017823E-06 0.1962681E-08 0.9981964E-07 0.0000000E+00 Chg. balance for solid moles: -.6300E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0172000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3327E-07 -7.478 0.1671E-04 -4.777 0.2928 0.5311E-05 clinochlore 0.2697E-05 -5.569 0.1499E-02 -2.824 26.27 0.5703E-03 daphnite 0.1689E-05 -5.772 0.1205E-02 -2.919 21.11 0.3652E-03 chlorite-Mn 0.3947E-07 -7.404 0.2798E-04 -4.553 0.4902 0.8917E-05 diaspore 0.4425E-04 -4.354 0.2654E-02 -2.576 46.50 0.7902E-03 hematite 0.1908E-05 -5.719 0.3047E-03 -3.516 5.337 0.5774E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3816E+00 0.3816E+00 1.0000 -0.418 chlorite-Mn 0.8918E-02 0.8918E-02 1.0000 -2.050 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.005708 g Volume = 0.001798 cm3 Porosity: 99.8215% V(tot) - V(min): 0.10051E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0172000 g log = -1.7645 Original solution: 1000.0103000 g Original solution / Rock added: 58140.13 (Water/Rock Ratio), log = 4.7645 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.4192E-04 1.0073 0.4442E-04 0.4410E-04 CH4,gas 0.1855E-13 1.0129 0.1977E-13 0.1952E-13 H2,gas 0.1400E-05 1.0006 0.1473E-05 0.1472E-05 H2S,gas 0.3189E-10 0.9959 0.3341E-10 0.3355E-10 S2,gas 0.1831E-28 1.0000 0.1926E-28 0.1926E-28 CO,gas 0.1611E-13 1.0000 0.1695E-13 0.1695E-13 SO3,gas 0.2047E-35 1.0000 0.2153E-35 0.2153E-35 SO2,gas 0.1141E-18 1.0000 0.1200E-18 0.1200E-18 HCl,gas 0.6670E-15 1.0000 0.7016E-15 0.7016E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.72 -6.35 -2.117 0.10847E+05 -4.352 3 CH4,gas 4.81 -10.89 -15.70 -3.926 0.26814E+05 -13.704 4 H2,gas 8.29 0.46 -7.83 -4.475 0.13372E+05 -5.832 5 H2S,gas -5.94 -18.42 -12.48 -6.238 0.21303E+05 -10.476 6 S2,gas -7.03 -37.75 -30.72 -4.725 0.52446E+05 -28.715 7 CO,gas 3.51 -12.26 -15.77 -4.853 0.26928E+05 -13.771 8 SO3,gas 17.43 -20.24 -37.67 -9.417 0.64315E+05 -35.667 9 SO2,gas 1.14 -19.78 -20.92 -5.579 0.35722E+05 -18.921 10 HCl,gas 5.48 -11.68 -17.15 -8.577 0.29290E+05 -15.154 16 albite -0.33 -4.49 -4.16 -0.320 0.71019E+04 19 spessartine 24.55 19.79 -4.76 -0.238 0.81271E+04 20 analcite 3.37 -0.68 -4.05 -0.450 0.69171E+04 21 andalusite 5.06 1.98 -3.08 -0.308 0.52547E+04 22 andradite 39.09 34.39 -4.69 -0.244 0.80158E+04 24 anhydrite -5.28 -9.17 -3.89 -1.944 0.66376E+04 29 anorthite 12.80 9.25 -3.55 -0.273 0.60574E+04 35 aragonite 0.99 -1.64 -2.63 -0.876 0.44896E+04 36 brucite 12.58 8.75 -3.83 -0.765 0.65347E+04 37 calcite 0.83 -1.64 -2.48 -0.825 0.42283E+04 40 carpholite-Mg 8.65 6.93 -1.72 -0.115 0.29424E+04 41 carpholite-Fe 6.78 4.70 -2.08 -0.139 0.35496E+04 50 chloritoid-Mg 13.26 10.73 -2.53 -0.168 0.43145E+04 51 chloritoid-Fe 9.24 8.51 -0.73 -0.048 0.12419E+04 52 chloritoid-Mn 11.46 10.46 -1.01 -0.067 0.17161E+04 54 coesite -2.37 -3.81 -1.44 -0.479 0.24552E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.81 -1.26 -0.419 0.21481E+04 67 diopside 16.22 12.21 -4.01 -0.401 0.68437E+04 68 hedenbergite 14.24 9.98 -4.26 -0.426 0.72740E+04 75 epidote 24.78 22.81 -1.96 -0.095 0.33485E+04 76 clinozoisite 22.92 19.41 -3.51 -0.160 0.59928E+04 77 epidote-Fe 29.94 26.22 -3.72 -0.193 0.63517E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82529E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.96 -4.23 -0.352 0.72218E+04 91 heulandite -5.71 -9.79 -4.08 -0.185 0.69650E+04 95 jadeite 4.25 -0.68 -4.93 -0.493 0.84201E+04 98 kaolinite -1.27 -1.82 -0.55 -0.050 0.93777E+03 99 kyanite 4.93 1.98 -2.95 -0.295 0.50315E+04 101 laumontite 2.97 1.64 -1.34 -0.089 0.22863E+04 102 lawsonite 9.68 9.25 -0.43 -0.029 0.73126E+03 105 lizardite 23.29 18.63 -4.65 -0.388 0.79457E+04 106 magnesite 0.71 -3.97 -4.68 -1.558 0.79832E+04 107 magnetite 20.13 19.12 -1.01 -0.082 0.17224E+04 110 magnesioferrite 26.26 21.35 -4.91 -0.401 0.83840E+04 113 margarite 17.45 15.04 -2.41 -0.096 0.41142E+04 116 microcline -2.43 -6.18 -3.75 -0.289 0.64076E+04 120 muscovite 2.68 -0.39 -3.07 -0.181 0.52445E+04 121 paragonite 4.34 1.30 -3.03 -0.178 0.51773E+04 136 prehnite 19.47 16.52 -2.95 -0.174 0.50388E+04 137 prehnite-Fe 22.59 19.92 -2.67 -0.161 0.45568E+04 138 pumpellyite-Fe 46.47 42.45 -4.02 -0.089 0.68597E+04 139 pumpellyite-Mg 49.19 44.68 -4.52 -0.100 0.77142E+04 145 pyroxmangite 7.42 4.67 -2.75 -0.550 0.46956E+04 146 pyrophyllite -6.10 -9.44 -3.34 -0.209 0.57010E+04 147 quartz -2.98 -3.81 -0.83 -0.275 0.14091E+04 152 rhodochrosite -0.96 -4.24 -3.28 -1.095 0.56071E+04 153 rhodonite 7.46 4.67 -2.80 -0.559 0.47748E+04 154 sanidine -1.22 -6.18 -4.96 -0.382 0.84754E+04 156 siderite -2.59 -6.19 -3.60 -1.201 0.61496E+04 157 sillimanite 5.32 1.98 -3.34 -0.334 0.56969E+04 164 stilbite -7.41 -9.79 -2.38 -0.113 0.40644E+04 165 stilpnomelane-Fe 13.18 9.14 -4.04 -0.121 0.69027E+04 169 sudoite 21.22 17.66 -3.55 -0.115 0.60695E+04 175 tephroite 18.11 13.14 -4.97 -0.711 0.84924E+04 178 topaz-H 4.67 1.98 -2.68 -0.244 0.45805E+04 179 tridymite -2.61 -3.81 -1.19 -0.398 0.20364E+04 188 wairakite 4.06 1.64 -2.42 -0.143 0.41371E+04 189 walstromite 11.53 7.27 -4.26 -0.853 0.72784E+04 190 wollastonite 10.48 7.27 -3.22 -0.643 0.54923E+04 191 pseudo-wollastonite 11.02 7.27 -3.75 -0.751 0.64109E+04 192 zoisite 22.96 19.41 -3.55 -0.161 0.60654E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.40 -3.84 -0.237 0.65535E+04 195 beidellite-H -2.24 -7.22 -4.98 -0.318 0.85095E+04 197 beidellite-Mg -1.71 -5.78 -4.07 -0.252 0.69566E+04 198 beidellite-Na -1.26 -5.89 -4.64 -0.284 0.79145E+04 200 chalcedony -2.79 -3.81 -1.01 -0.338 0.17294E+04 202 montmorillonite-Ca -2.21 -5.68 -3.46 -0.214 0.59152E+04 203 montmorillonite-K -2.16 -6.73 -4.57 -0.280 0.78060E+04 204 montmorillonite-Mg -2.40 -6.06 -3.66 -0.226 0.62493E+04 205 montmorillonite-Na -1.96 -6.17 -4.21 -0.258 0.71920E+04 206 nontronite-Ca 3.28 1.41 -1.87 -0.121 0.31965E+04 207 nontronite-H 2.60 -0.42 -3.02 -0.202 0.51482E+04 208 nontronite-K 3.40 0.35 -3.05 -0.196 0.52087E+04 209 nontronite-Mg 3.14 1.02 -2.11 -0.137 0.36112E+04 210 nontronite-Na 3.58 0.91 -2.67 -0.171 0.45583E+04 215 gypsum -4.92 -9.17 -4.24 -1.061 0.72444E+04 225 tobermorite 9.84 5.42 -4.42 -1.207 0.75520E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.53 -3.30 -0.824 0.56309E+04 241 silica-amorphous -2.08 -3.81 -1.73 -0.576 0.29496E+04 243 an20ab80 2.08 -1.74 -3.82 -0.294 0.65214E+04 244 an25ab75 2.71 -1.05 -3.76 -0.289 0.64242E+04 245 an30ab70 3.34 -0.37 -3.71 -0.285 0.63353E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0172000 g New total amount of reactant added: 0.0176000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0176000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3028362E-03 Osmotic coef. = 0.9896 True ionic strength = .3145385E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.16254E-07 -7.7890 0.15594E-07 -7.8070 0.95938E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13234E-03 -3.8783 0.95925E+00 -0.0181 4 SO4-- 0.25288E-04 -4.5971 0.22596E-04 -4.6460 0.89357E+00 -0.0489 5 HCO3- 0.12574E-04 -4.9005 0.12062E-04 -4.9186 0.95928E+00 -0.0181 6 HS- 0.21792E-10 -10.6617 0.20904E-10 -10.6798 0.95925E+00 -0.0181 7 Al+++ 0.37614E-20 -20.4247 0.29850E-20 -20.5251 0.79359E+00 -0.1004 8 H4SiO4 0.15925E-03 -3.7979 0.15925E-03 -3.7979 0.10000E+01 0.0000 9 Ca++ 0.34135E-04 -4.4668 0.30497E-04 -4.5157 0.89342E+00 -0.0489 10 Mg++ 0.15095E-06 -6.8212 0.13485E-06 -6.8702 0.89332E+00 -0.0490 11 Fe++ 0.90228E-09 -9.0447 0.80605E-09 -9.0936 0.89335E+00 -0.0490 12 K+ 0.37353E-05 -5.4277 0.35833E-05 -5.4457 0.95929E+00 -0.0181 13 Na+ 0.18212E-03 -3.7396 0.17470E-03 -3.7577 0.95925E+00 -0.0181 14 Mn++ 0.81950E-07 -7.0865 0.73211E-07 -7.1354 0.89336E+00 -0.0490 15 HPO4-- 0.14773E-08 -8.8305 0.13201E-08 -8.8794 0.89357E+00 -0.0489 16 HSiO3- 0.10387E-04 -4.9835 0.99637E-05 -5.0016 0.95925E+00 -0.0181 17 Ca(HSiO3)+ 0.70969E-08 -8.1489 0.68080E-08 -8.1670 0.95929E+00 -0.0180 18 Mg(HSiO3)+ 0.39053E-10 -10.4083 0.37463E-10 -10.4264 0.95929E+00 -0.0180 19 NaHSiO3,aq 0.27646E-07 -7.5584 0.27646E-07 -7.5584 0.10000E+01 0.0000 20 AlO+ 0.16520E-11 -11.7820 0.15847E-11 -11.8000 0.95929E+00 -0.0180 21 AlOH+2 0.13856E-15 -15.8583 0.12379E-15 -15.9073 0.89338E+00 -0.0490 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.30358E-05 -5.5177 0.29119E-05 -5.5358 0.95921E+00 -0.0181 24 CH4,aq 0.10951E-16 -16.9605 0.10950E-16 -16.9606 0.99991E+00 0.0000 29 CO,aq 0.10208E-16 -16.9910 0.10208E-16 -16.9910 0.10000E+01 0.0000 30 CO2,aq 0.37928E-06 -6.4210 0.37924E-06 -6.4211 0.99991E+00 0.0000 31 CO3-2 0.80043E-07 -7.0967 0.71520E-07 -7.1456 0.89352E+00 -0.0489 32 CaCO3,aq 0.26714E-07 -7.5733 0.26714E-07 -7.5733 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.96623E-08 -8.0149 0.92690E-08 -8.0330 0.95929E+00 -0.0180 34 CaCl+ 0.67040E-08 -8.1737 0.64311E-08 -8.1917 0.95929E+00 -0.0180 35 CaCl2,aq 0.19816E-12 -12.7030 0.19816E-12 -12.7030 0.10000E+01 0.0000 36 CaOH+ 0.14375E-06 -6.8424 0.13790E-06 -6.8604 0.95929E+00 -0.0180 37 CaSO4,aq 0.21471E-06 -6.6681 0.21471E-06 -6.6681 0.10000E+01 0.0000 38 HCl,aq 0.38817E-12 -12.4110 0.38817E-12 -12.4110 0.10000E+01 0.0000 43 FeCl+ 0.17319E-12 -12.7615 0.16614E-12 -12.7795 0.95929E+00 -0.0180 46 FeO,aq 0.13108E-09 -9.8825 0.13108E-09 -9.8825 0.10000E+01 0.0000 47 FeOH+ 0.17864E-08 -8.7480 0.17137E-08 -8.7661 0.95929E+00 -0.0180 48 HFeO2- 0.94256E-10 -10.0257 0.90415E-10 -10.0438 0.95925E+00 -0.0181 49 FeO+ 0.13447E-12 -12.8714 0.12899E-12 -12.8894 0.95929E+00 -0.0180 50 FeOH+2 0.41897E-18 -18.3778 0.37430E-18 -18.4268 0.89338E+00 -0.0490 51 FeO2- 0.10869E-09 -9.9638 0.10426E-09 -9.9819 0.95925E+00 -0.0181 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.10452E-08 -8.9808 0.10451E-08 -8.9808 0.99991E+00 0.0000 54 KCl,aq 0.83965E-11 -11.0759 0.83965E-11 -11.0759 0.10000E+01 0.0000 55 KHSO4,aq 0.33787E-17 -17.4712 0.33787E-17 -17.4712 0.10000E+01 0.0000 56 KOH,aq 0.10018E-09 -9.9992 0.10018E-09 -9.9992 0.10000E+01 0.0000 57 KSO4- 0.13004E-08 -8.8859 0.12474E-08 -8.9040 0.95925E+00 -0.0181 58 MgCO3,aq 0.29515E-10 -10.5300 0.29515E-10 -10.5300 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.43566E-10 -10.3608 0.41793E-10 -10.3789 0.95929E+00 -0.0180 60 MgCl+ 0.26911E-10 -10.5701 0.25815E-10 -10.5881 0.95929E+00 -0.0180 61 MgOH+ 0.35214E-08 -8.4533 0.33781E-08 -8.4713 0.95929E+00 -0.0180 63 MnO,aq 0.31782E-09 -9.4978 0.31782E-09 -9.4978 0.10000E+01 0.0000 64 MnOH+ 0.15073E-07 -7.8218 0.14459E-07 -7.8399 0.95929E+00 -0.0180 65 MnO2-2 0.50588E-16 -16.2960 0.45201E-16 -16.3448 0.89352E+00 -0.0489 66 HMnO2- 0.15920E-12 -12.7980 0.15272E-12 -12.8161 0.95925E+00 -0.0181 69 MnCl+ 0.61126E-10 -10.2138 0.58638E-10 -10.2318 0.95929E+00 -0.0180 70 MnSO4,aq 0.46883E-09 -9.3290 0.46883E-09 -9.3290 0.10000E+01 0.0000 71 NaCl,aq 0.75492E-08 -8.1221 0.75492E-08 -8.1221 0.10000E+01 0.0000 72 NaOH,aq 0.49228E-08 -8.3078 0.49228E-08 -8.3078 0.10000E+01 0.0000 74 OH- 0.40102E-04 -4.3968 0.38466E-04 -4.4149 0.95921E+00 -0.0181 82 H3PO4,aq 0.20666E-14 -14.6848 0.20666E-14 -14.6848 0.10000E+01 0.0000 83 H2PO4- 0.37622E-09 -9.4246 0.36089E-09 -9.4426 0.95927E+00 -0.0181 84 PO4-3 0.93050E-13 -13.0313 0.73929E-13 -13.1312 0.79450E+00 -0.0999 87 H2P2O7-2 0.11408E-19 -19.9428 0.10194E-19 -19.9917 0.89352E+00 -0.0489 88 HP2O7-3 0.16890E-18 -18.7724 0.13404E-18 -18.8728 0.79360E+00 -0.1004 90 H2S,aq 0.97951E-12 -12.0090 0.97942E-12 -12.0090 0.99991E+00 0.0000 96 SO2,aq 0.24060E-19 -19.6187 0.24060E-19 -19.6187 0.10000E+01 0.0000 97 SO3-2 0.36026E-14 -14.4434 0.32201E-14 -14.4921 0.89383E+00 -0.0487 98 HSO3- 0.30634E-14 -14.5138 0.29386E-14 -14.5319 0.95925E+00 -0.0181 99 HSO4- 0.34081E-09 -9.4675 0.32694E-09 -9.4855 0.95931E+00 -0.0180 101 S2O3-2 0.29191E-18 -18.5347 0.26083E-18 -18.5836 0.89352E+00 -0.0489 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1625399E-07 -.6260971E-04 -.6310502E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999698E+06 0.0000 3 Cl- 0.1379608E-03 0.1379751E-03 0.4891492E+01 3.9287 4 SO4-- 0.2528780E-04 0.2550440E-04 0.2449923E+01 10.9681 5 HCO3- 0.1257432E-04 0.1307009E-04 0.7974774E+00 2.8885 6 HS- 0.2179230E-10 0.2450470E-09 0.8103961E-05 -2.8727 7 Al+++ 0.3761375E-20 0.3056115E-05 0.8245620E-01 2.8961 8 H4SiO4 0.1592468E-03 0.1696685E-03 0.1630729E+02 -3.7979 9 Ca++ 0.3413467E-04 0.3454331E-04 0.1384387E+01 11.0983 10 Mg++ 0.1509482E-06 0.1546087E-06 0.3758739E-02 8.7439 11 Fe++ 0.9022807E-09 0.3226467E-08 0.1801834E-03 6.5205 12 K+ 0.3735347E-05 0.3736756E-05 0.1461104E+00 2.3613 13 Na+ 0.1821244E-03 0.1821645E-03 0.4187806E+01 4.0493 14 Mn++ 0.8194980E-07 0.9787037E-07 0.5376648E-02 8.4787 15 HPO4-- 0.1477294E-08 0.1853606E-08 0.1779022E-03 6.7347 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2783899E-03 -.6260928E-04 -.2157806E-03 0.0000000E+00 2 H2O 0.5550803E+02 0.5550791E+02 0.1216691E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2599223E-04 0.2550422E-04 0.4880010E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4877560E-06 0.2450453E-09 -.4880010E-06 0.0000000E+00 7 Al+++ 0.5738905E-04 0.3056094E-05 0.5433296E-04 0.0000000E+00 8 H4SiO4 0.1832650E-03 0.1696674E-03 0.1359759E-04 0.0000000E+00 9 Ca++ 0.3471357E-04 0.3454308E-04 0.1704929E-06 0.0000000E+00 10 Mg++ 0.1396825E-04 0.1546076E-06 0.1381365E-04 0.0000000E+00 11 Fe++ 0.1254895E-04 0.3226445E-08 0.1254572E-04 0.0000000E+00 12 K+ 0.3736730E-05 0.3736730E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1821633E-03 0.1821633E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3051593E-06 0.9786970E-07 0.2072896E-06 0.0000000E+00 15 HPO4-- 0.1041493E-06 0.1853594E-08 0.1022958E-06 0.0000000E+00 Chg. balance for solid moles: 0.9238E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0176000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3410E-07 -7.467 0.1713E-04 -4.766 0.2932 0.5443E-05 clinochlore 0.2763E-05 -5.559 0.1536E-02 -2.814 26.28 0.5841E-03 daphnite 0.1728E-05 -5.762 0.1233E-02 -2.909 21.11 0.3737E-03 chlorite-Mn 0.4146E-07 -7.382 0.2939E-04 -4.532 0.5031 0.9367E-05 diaspore 0.4527E-04 -4.344 0.2716E-02 -2.566 46.48 0.8085E-03 hematite 0.1952E-05 -5.710 0.3117E-03 -3.506 5.335 0.5909E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3813E+00 0.3813E+00 1.0000 -0.419 chlorite-Mn 0.9147E-02 0.9147E-02 1.0000 -2.039 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.005843 g Volume = 0.001840 cm3 Porosity: 99.8173% V(tot) - V(min): 0.10052E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0176000 g log = -1.7545 Original solution: 1000.0103000 g Original solution / Rock added: 56818.77 (Water/Rock Ratio), log = 4.7545 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.4097E-04 1.0073 0.4341E-04 0.4310E-04 CH4,gas 0.1625E-13 1.0129 0.1732E-13 0.1710E-13 H2,gas 0.1362E-05 1.0006 0.1433E-05 0.1433E-05 H2S,gas 0.2727E-10 0.9959 0.2857E-10 0.2868E-10 S2,gas 0.1414E-28 1.0000 0.1487E-28 0.1487E-28 CO,gas 0.1532E-13 1.0000 0.1612E-13 0.1612E-13 SO3,gas 0.1953E-35 1.0000 0.2054E-35 0.2054E-35 SO2,gas 0.1059E-18 1.0000 0.1114E-18 0.1114E-18 HCl,gas 0.6515E-15 1.0000 0.6854E-15 0.6854E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.73 -6.36 -2.121 0.10864E+05 -4.362 3 CH4,gas 4.81 -10.95 -15.76 -3.940 0.26912E+05 -13.762 4 H2,gas 8.29 0.44 -7.84 -4.482 0.13393E+05 -5.844 5 H2S,gas -5.94 -18.49 -12.54 -6.272 0.21419E+05 -10.544 6 S2,gas -7.03 -37.86 -30.83 -4.743 0.52637E+05 -28.828 7 CO,gas 3.51 -12.28 -15.79 -4.859 0.26966E+05 -13.793 8 SO3,gas 17.43 -20.26 -37.69 -9.422 0.64350E+05 -35.687 9 SO2,gas 1.14 -19.82 -20.95 -5.588 0.35777E+05 -18.953 10 HCl,gas 5.48 -11.69 -17.16 -8.582 0.29307E+05 -15.164 11 acmite 7.74 2.75 -4.99 -0.518 0.85119E+04 16 albite -0.33 -4.45 -4.12 -0.317 0.70348E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80516E+04 20 analcite 3.37 -0.65 -4.02 -0.447 0.68659E+04 21 andalusite 5.06 1.99 -3.07 -0.307 0.52387E+04 22 andradite 39.09 34.50 -4.59 -0.238 0.78354E+04 24 anhydrite -5.28 -9.16 -3.88 -1.941 0.66283E+04 29 anorthite 12.80 9.29 -3.50 -0.269 0.59813E+04 35 aragonite 0.99 -1.63 -2.61 -0.871 0.44625E+04 36 brucite 12.58 8.74 -3.83 -0.767 0.65442E+04 37 calcite 0.83 -1.63 -2.46 -0.820 0.42011E+04 40 carpholite-Mg 8.65 6.94 -1.71 -0.114 0.29200E+04 41 carpholite-Fe 6.78 4.72 -2.07 -0.138 0.35278E+04 50 chloritoid-Mg 13.26 10.74 -2.52 -0.168 0.43081E+04 51 chloritoid-Fe 9.24 8.51 -0.72 -0.048 0.12362E+04 52 chloritoid-Mn 11.46 10.47 -0.99 -0.066 0.16909E+04 54 coesite -2.37 -3.80 -1.43 -0.476 0.24393E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.80 -1.25 -0.416 0.21321E+04 67 diopside 16.22 12.25 -3.97 -0.397 0.67770E+04 68 hedenbergite 14.24 10.02 -4.22 -0.422 0.72080E+04 75 epidote 24.78 22.89 -1.88 -0.091 0.32123E+04 76 clinozoisite 22.92 19.49 -3.43 -0.156 0.58566E+04 77 epidote-Fe 29.94 26.30 -3.64 -0.189 0.62155E+04 78 fayalite 14.08 9.24 -4.84 -0.691 0.82573E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.97 -4.23 -0.352 0.72204E+04 91 heulandite -5.71 -9.69 -3.99 -0.181 0.68092E+04 95 jadeite 4.25 -0.65 -4.90 -0.490 0.83689E+04 98 kaolinite -1.27 -1.80 -0.53 -0.048 0.90588E+03 99 kyanite 4.93 1.99 -2.94 -0.294 0.50155E+04 101 laumontite 2.97 1.70 -1.28 -0.085 0.21783E+04 102 lawsonite 9.68 9.29 -0.38 -0.026 0.65517E+03 105 lizardite 23.29 18.64 -4.65 -0.388 0.79423E+04 106 magnesite 0.71 -3.98 -4.69 -1.564 0.80097E+04 107 magnetite 20.13 19.12 -1.01 -0.083 0.17326E+04 110 magnesioferrite 26.26 21.34 -4.92 -0.401 0.83935E+04 113 margarite 17.45 15.09 -2.36 -0.095 0.40381E+04 116 microcline -2.43 -6.14 -3.70 -0.285 0.63255E+04 120 muscovite 2.68 -0.34 -3.02 -0.178 0.51624E+04 121 paragonite 4.34 1.34 -2.99 -0.176 0.51101E+04 136 prehnite 19.47 16.60 -2.87 -0.169 0.49026E+04 137 prehnite-Fe 22.59 20.00 -2.59 -0.156 0.44206E+04 138 pumpellyite-Fe 46.47 42.61 -3.86 -0.086 0.65974E+04 139 pumpellyite-Mg 49.19 44.83 -4.36 -0.097 0.74512E+04 145 pyroxmangite 7.42 4.68 -2.74 -0.547 0.46704E+04 146 pyrophyllite -6.10 -9.40 -3.30 -0.206 0.56372E+04 147 quartz -2.98 -3.80 -0.82 -0.272 0.13932E+04 152 rhodochrosite -0.96 -4.25 -3.29 -1.096 0.56149E+04 153 rhodonite 7.46 4.68 -2.78 -0.556 0.47497E+04 154 sanidine -1.22 -6.14 -4.92 -0.378 0.83932E+04 156 siderite -2.59 -6.21 -3.62 -1.206 0.61768E+04 157 sillimanite 5.32 1.99 -3.33 -0.333 0.56809E+04 164 stilbite -7.41 -9.69 -2.29 -0.109 0.39086E+04 165 stilpnomelane-Fe 13.18 9.19 -3.99 -0.119 0.68088E+04 169 sudoite 21.22 17.68 -3.54 -0.114 0.60406E+04 175 tephroite 18.11 13.16 -4.95 -0.708 0.84579E+04 178 topaz-H 4.67 1.99 -2.67 -0.243 0.45646E+04 179 tridymite -2.61 -3.80 -1.18 -0.394 0.20205E+04 188 wairakite 4.06 1.70 -2.36 -0.139 0.40291E+04 189 walstromite 11.53 7.30 -4.23 -0.845 0.72183E+04 190 wollastonite 10.48 7.30 -3.18 -0.636 0.54322E+04 191 pseudo-wollastonite 11.02 7.30 -3.72 -0.744 0.63508E+04 192 zoisite 22.96 19.49 -3.47 -0.158 0.59291E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.36 -3.80 -0.235 0.64877E+04 195 beidellite-H -2.24 -7.19 -4.95 -0.316 0.84510E+04 196 beidellite-K -1.44 -6.41 -4.98 -0.305 0.84968E+04 197 beidellite-Mg -1.71 -5.75 -4.04 -0.250 0.68997E+04 198 beidellite-Na -1.26 -5.85 -4.60 -0.282 0.78496E+04 200 chalcedony -2.79 -3.80 -1.00 -0.335 0.17135E+04 202 montmorillonite-Ca -2.21 -5.64 -3.42 -0.212 0.58472E+04 203 montmorillonite-K -2.16 -6.69 -4.53 -0.277 0.77341E+04 204 montmorillonite-Mg -2.40 -6.03 -3.63 -0.224 0.61902E+04 205 montmorillonite-Na -1.96 -6.13 -4.17 -0.256 0.71250E+04 206 nontronite-Ca 3.28 1.45 -1.83 -0.119 0.31307E+04 207 nontronite-H 2.60 -0.39 -2.98 -0.200 0.50896E+04 208 nontronite-K 3.40 0.39 -3.01 -0.193 0.51389E+04 209 nontronite-Mg 3.14 1.06 -2.08 -0.135 0.35542E+04 210 nontronite-Na 3.58 0.95 -2.63 -0.169 0.44934E+04 215 gypsum -4.92 -9.16 -4.24 -1.059 0.72351E+04 225 tobermorite 9.84 5.45 -4.39 -1.198 0.74992E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.52 -3.30 -0.826 0.56411E+04 241 silica-amorphous -2.08 -3.80 -1.72 -0.573 0.29337E+04 243 an20ab80 2.08 -1.70 -3.78 -0.291 0.64525E+04 244 an25ab75 2.71 -1.01 -3.72 -0.286 0.63548E+04 245 an30ab70 3.34 -0.33 -3.67 -0.282 0.62655E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0176000 g New total amount of reactant added: 0.0180000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0180000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3043327E-03 Osmotic coef. = 0.9896 True ionic strength = .3164340E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15890E-07 -7.7989 0.15244E-07 -7.8169 0.95932E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13233E-03 -3.8783 0.95918E+00 -0.0181 4 SO4-- 0.25285E-04 -4.5971 0.22588E-04 -4.6461 0.89332E+00 -0.0490 5 HCO3- 0.12580E-04 -4.9003 0.12067E-04 -4.9184 0.95921E+00 -0.0181 6 HS- 0.19144E-10 -10.7180 0.18362E-10 -10.7361 0.95919E+00 -0.0181 7 Al+++ 0.35161E-20 -20.4539 0.27886E-20 -20.5546 0.79310E+00 -0.1007 8 H4SiO4 0.16263E-03 -3.7888 0.16263E-03 -3.7888 0.10000E+01 0.0000 9 Ca++ 0.34581E-04 -4.4612 0.30887E-04 -4.5102 0.89317E+00 -0.0491 10 Mg++ 0.14250E-06 -6.8462 0.12726E-06 -6.8953 0.89308E+00 -0.0491 11 Fe++ 0.85108E-09 -9.0700 0.76010E-09 -9.1191 0.89310E+00 -0.0491 12 K+ 0.38202E-05 -5.4179 0.36645E-05 -5.4360 0.95922E+00 -0.0181 13 Na+ 0.18263E-03 -3.7384 0.17517E-03 -3.7565 0.95918E+00 -0.0181 14 Mn++ 0.79186E-07 -7.1014 0.70722E-07 -7.1504 0.89311E+00 -0.0491 15 HPO4-- 0.14036E-08 -8.8528 0.12539E-08 -8.9017 0.89332E+00 -0.0490 16 HSiO3- 0.10852E-04 -4.9645 0.10409E-04 -4.9826 0.95918E+00 -0.0181 17 Ca(HSiO3)+ 0.75092E-08 -8.1244 0.72030E-08 -8.1425 0.95923E+00 -0.0181 18 Mg(HSiO3)+ 0.38506E-10 -10.4145 0.36936E-10 -10.4326 0.95923E+00 -0.0181 19 NaHSiO3,aq 0.28958E-07 -7.5382 0.28958E-07 -7.5382 0.10000E+01 0.0000 20 AlO+ 0.16150E-11 -11.7918 0.15492E-11 -11.8099 0.95923E+00 -0.0181 21 AlOH+2 0.13245E-15 -15.8779 0.11830E-15 -15.9270 0.89313E+00 -0.0491 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.31057E-05 -5.5078 0.29788E-05 -5.5260 0.95914E+00 -0.0181 24 CH4,aq 0.96266E-17 -17.0165 0.96256E-17 -17.0166 0.99991E+00 0.0000 29 CO,aq 0.97206E-17 -17.0123 0.97206E-17 -17.0123 0.10000E+01 0.0000 30 CO2,aq 0.37090E-06 -6.4307 0.37087E-06 -6.4308 0.99991E+00 0.0000 31 CO3-2 0.81932E-07 -7.0865 0.73188E-07 -7.1356 0.89328E+00 -0.0490 32 CaCO3,aq 0.27686E-07 -7.5577 0.27686E-07 -7.5577 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.97901E-08 -8.0092 0.93910E-08 -8.0273 0.95923E+00 -0.0181 34 CaCl+ 0.67898E-08 -8.1681 0.65130E-08 -8.1862 0.95923E+00 -0.0181 35 CaCl2,aq 0.20067E-12 -12.6975 0.20067E-12 -12.6975 0.10000E+01 0.0000 36 CaOH+ 0.14894E-06 -6.8270 0.14287E-06 -6.8451 0.95923E+00 -0.0181 37 CaSO4,aq 0.21738E-06 -6.6628 0.21738E-06 -6.6628 0.10000E+01 0.0000 38 HCl,aq 0.37944E-12 -12.4209 0.37944E-12 -12.4209 0.10000E+01 0.0000 43 FeCl+ 0.16332E-12 -12.7870 0.15666E-12 -12.8050 0.95923E+00 -0.0181 46 FeO,aq 0.12935E-09 -9.8882 0.12935E-09 -9.8882 0.10000E+01 0.0000 47 FeOH+ 0.17233E-08 -8.7636 0.16531E-08 -8.7817 0.95923E+00 -0.0181 48 HFeO2- 0.95149E-10 -10.0216 0.91265E-10 -10.0397 0.95918E+00 -0.0181 49 FeO+ 0.13146E-12 -12.8812 0.12610E-12 -12.8993 0.95923E+00 -0.0181 50 FeOH+2 0.40050E-18 -18.3974 0.35770E-18 -18.4465 0.89313E+00 -0.0491 51 FeO2- 0.11119E-09 -9.9539 0.10665E-09 -9.9720 0.95918E+00 -0.0181 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.10178E-08 -8.9924 0.10177E-08 -8.9924 0.99991E+00 0.0000 54 KCl,aq 0.85862E-11 -11.0662 0.85862E-11 -11.0662 0.10000E+01 0.0000 55 KHSO4,aq 0.33765E-17 -17.4715 0.33765E-17 -17.4715 0.10000E+01 0.0000 56 KOH,aq 0.10480E-09 -9.9797 0.10480E-09 -9.9797 0.10000E+01 0.0000 57 KSO4- 0.13295E-08 -8.8763 0.12752E-08 -8.8944 0.95918E+00 -0.0181 58 MgCO3,aq 0.28505E-10 -10.5451 0.28505E-10 -10.5451 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.41134E-10 -10.3858 0.39457E-10 -10.4039 0.95923E+00 -0.0181 60 MgCl+ 0.25397E-10 -10.5952 0.24362E-10 -10.6133 0.95923E+00 -0.0181 61 MgOH+ 0.33999E-08 -8.4685 0.32613E-08 -8.4866 0.95923E+00 -0.0181 63 MnO,aq 0.32127E-09 -9.4931 0.32127E-09 -9.4931 0.10000E+01 0.0000 64 MnOH+ 0.14895E-07 -7.8270 0.14288E-07 -7.8450 0.95923E+00 -0.0181 65 MnO2-2 0.53525E-16 -16.2714 0.47812E-16 -16.3205 0.89328E+00 -0.0490 66 HMnO2- 0.16463E-12 -12.7835 0.15791E-12 -12.8016 0.95918E+00 -0.0181 69 MnCl+ 0.59048E-10 -10.2288 0.56641E-10 -10.2469 0.95923E+00 -0.0181 70 MnSO4,aq 0.45272E-09 -9.3442 0.45272E-09 -9.3442 0.10000E+01 0.0000 71 NaCl,aq 0.75689E-08 -8.1210 0.75689E-08 -8.1210 0.10000E+01 0.0000 72 NaOH,aq 0.50493E-08 -8.2968 0.50493E-08 -8.2968 0.10000E+01 0.0000 74 OH- 0.41025E-04 -4.3870 0.39349E-04 -4.4051 0.95914E+00 -0.0181 82 H3PO4,aq 0.18759E-14 -14.7268 0.18759E-14 -14.7268 0.10000E+01 0.0000 83 H2PO4- 0.34936E-09 -9.4567 0.33511E-09 -9.4748 0.95920E+00 -0.0181 84 PO4-3 0.90469E-13 -13.0435 0.71833E-13 -13.1437 0.79401E+00 -0.1002 88 HP2O7-3 0.14906E-18 -18.8266 0.11822E-18 -18.9273 0.79310E+00 -0.1007 90 H2S,aq 0.84111E-12 -12.0751 0.84103E-12 -12.0752 0.99991E+00 0.0000 96 SO2,aq 0.22380E-19 -19.6501 0.22380E-19 -19.6501 0.10000E+01 0.0000 97 SO3-2 0.35075E-14 -14.4550 0.31342E-14 -14.5039 0.89358E+00 -0.0489 98 HSO3- 0.29150E-14 -14.5354 0.27961E-14 -14.5535 0.95918E+00 -0.0181 99 HSO4- 0.33306E-09 -9.4775 0.31949E-09 -9.4955 0.95925E+00 -0.0181 101 S2O3-2 0.25064E-18 -18.6009 0.22389E-18 -18.6500 0.89328E+00 -0.0490 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1589049E-07 -.6429517E-04 -.6480379E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999694E+06 0.0000 3 Cl- 0.1379607E-03 0.1379751E-03 0.4891491E+01 3.9386 4 SO4-- 0.2528514E-04 0.2550441E-04 0.2449924E+01 10.9877 5 HCO3- 0.1257971E-04 0.1307009E-04 0.7974772E+00 2.8985 6 HS- 0.1914382E-10 0.2350773E-09 0.7774251E-05 -2.9192 7 Al+++ 0.3516089E-20 0.3125992E-05 0.8434149E-01 2.8961 8 H4SiO4 0.1626261E-03 0.1735141E-03 0.1667690E+02 -3.7888 9 Ca++ 0.3458117E-04 0.3499927E-04 0.1402660E+01 11.1236 10 Mg++ 0.1424997E-06 0.1460331E-06 0.3550254E-02 8.7385 11 Fe++ 0.8510819E-09 0.3113854E-08 0.1738944E-03 6.5147 12 K+ 0.3820240E-05 0.3821683E-05 0.1494311E+00 2.3809 13 Na+ 0.1826251E-03 0.1826667E-03 0.4199348E+01 4.0604 14 Mn++ 0.7918575E-07 0.9491427E-07 0.5214249E-02 8.4834 15 HPO4-- 0.1403605E-08 0.1753058E-08 0.1682519E-03 6.7321 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2850133E-03 -.6429472E-04 -.2207186E-03 0.0000000E+00 2 H2O 0.5550802E+02 0.5550790E+02 0.1244404E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2600331E-04 0.2550423E-04 0.4990764E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4988414E-06 0.2350757E-09 -.4990764E-06 0.0000000E+00 7 Al+++ 0.5869335E-04 0.3125970E-05 0.5556738E-04 0.0000000E+00 8 H4SiO4 0.1874301E-03 0.1735129E-03 0.1391718E-04 0.0000000E+00 9 Ca++ 0.3517363E-04 0.3499902E-04 0.1746056E-06 0.0000000E+00 10 Mg++ 0.1428571E-04 0.1460321E-06 0.1413968E-04 0.0000000E+00 11 Fe++ 0.1283415E-04 0.3113833E-08 0.1283104E-04 0.0000000E+00 12 K+ 0.3821656E-05 0.3821656E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1826654E-03 0.1826654E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3120947E-06 0.9491361E-07 0.2171811E-06 0.0000000E+00 15 HPO4-- 0.1065164E-06 0.1753046E-08 0.1047633E-06 0.0000000E+00 Chg. balance for solid moles: -.1938E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0180000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3492E-07 -7.457 0.1754E-04 -4.756 0.2935 0.5574E-05 clinochlore 0.2828E-05 -5.549 0.1572E-02 -2.804 26.30 0.5979E-03 daphnite 0.1768E-05 -5.753 0.1261E-02 -2.899 21.10 0.3822E-03 chlorite-Mn 0.4344E-07 -7.362 0.3079E-04 -4.512 0.5152 0.9814E-05 diaspore 0.4629E-04 -4.335 0.2777E-02 -2.556 46.46 0.8267E-03 hematite 0.1996E-05 -5.700 0.3188E-03 -3.496 5.334 0.6043E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6096E+00 0.6096E+00 1.0000 -0.215 daphnite 0.3810E+00 0.3810E+00 1.0000 -0.419 chlorite-Mn 0.9363E-02 0.9363E-02 1.0000 -2.029 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.005977 g Volume = 0.001883 cm3 Porosity: 99.8131% V(tot) - V(min): 0.10053E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0180000 g log = -1.7447 Original solution: 1000.0103000 g Original solution / Rock added: 55556.13 (Water/Rock Ratio), log = 4.7447 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.4006E-04 1.0073 0.4245E-04 0.4214E-04 CH4,gas 0.1429E-13 1.0129 0.1522E-13 0.1503E-13 H2,gas 0.1326E-05 1.0006 0.1396E-05 0.1395E-05 H2S,gas 0.2341E-10 0.9959 0.2453E-10 0.2463E-10 S2,gas 0.1100E-28 1.0000 0.1157E-28 0.1157E-28 CO,gas 0.1459E-13 1.0000 0.1535E-13 0.1535E-13 SO3,gas 0.1865E-35 1.0000 0.1962E-35 0.1962E-35 SO2,gas 0.9850E-19 1.0000 0.1036E-18 0.1036E-18 HCl,gas 0.6369E-15 1.0000 0.6700E-15 0.6700E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.74 -6.37 -2.124 0.10880E+05 -4.372 3 CH4,gas 4.81 -11.01 -15.82 -3.954 0.27008E+05 -13.818 4 H2,gas 8.29 0.43 -7.86 -4.489 0.13412E+05 -5.855 5 H2S,gas -5.94 -18.55 -12.61 -6.305 0.21532E+05 -10.610 6 S2,gas -7.03 -37.97 -30.94 -4.760 0.52824E+05 -28.937 7 CO,gas 3.51 -12.30 -15.81 -4.866 0.27002E+05 -13.814 8 SO3,gas 17.43 -20.28 -37.71 -9.427 0.64384E+05 -35.707 9 SO2,gas 1.14 -19.85 -20.98 -5.596 0.35831E+05 -18.985 10 HCl,gas 5.48 -11.70 -17.17 -8.587 0.29324E+05 -15.174 11 acmite 7.74 2.78 -4.96 -0.515 0.84620E+04 16 albite -0.33 -4.41 -4.08 -0.314 0.69693E+04 19 spessartine 24.55 19.88 -4.67 -0.234 0.79809E+04 20 analcite 3.37 -0.62 -3.99 -0.444 0.68159E+04 21 andalusite 5.06 2.00 -3.06 -0.306 0.52232E+04 22 andradite 39.09 34.60 -4.49 -0.233 0.76594E+04 24 anhydrite -5.28 -9.16 -3.88 -1.938 0.66192E+04 29 anorthite 12.80 9.34 -3.46 -0.266 0.59071E+04 35 aragonite 0.99 -1.61 -2.60 -0.866 0.44359E+04 36 brucite 12.58 8.74 -3.84 -0.768 0.65534E+04 37 calcite 0.83 -1.61 -2.44 -0.815 0.41746E+04 40 carpholite-Mg 8.65 6.95 -1.70 -0.113 0.28981E+04 41 carpholite-Fe 6.78 4.73 -2.05 -0.137 0.35066E+04 50 chloritoid-Mg 13.26 10.74 -2.52 -0.168 0.43018E+04 51 chloritoid-Fe 9.24 8.52 -0.72 -0.048 0.12305E+04 52 chloritoid-Mn 11.46 10.49 -0.98 -0.065 0.16673E+04 54 coesite -2.37 -3.79 -1.42 -0.473 0.24237E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.79 -1.24 -0.413 0.21166E+04 67 diopside 16.22 12.28 -3.93 -0.393 0.67121E+04 68 hedenbergite 14.24 10.06 -4.18 -0.418 0.71437E+04 75 epidote 24.78 22.97 -1.80 -0.087 0.30794E+04 76 clinozoisite 22.92 19.57 -3.35 -0.152 0.57237E+04 77 epidote-Fe 29.94 26.37 -3.56 -0.185 0.60826E+04 78 fayalite 14.08 9.24 -4.84 -0.691 0.82615E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.97 -4.23 -0.352 0.72189E+04 91 heulandite -5.71 -9.61 -3.90 -0.177 0.66571E+04 95 jadeite 4.25 -0.62 -4.87 -0.487 0.83189E+04 98 kaolinite -1.27 -1.79 -0.51 -0.047 0.87474E+03 99 kyanite 4.93 2.00 -2.93 -0.293 0.49999E+04 101 laumontite 2.97 1.76 -1.21 -0.081 0.20729E+04 102 lawsonite 9.68 9.34 -0.34 -0.023 0.58095E+03 105 lizardite 23.29 18.64 -4.65 -0.387 0.79389E+04 106 magnesite 0.71 -4.00 -4.71 -1.569 0.80356E+04 107 magnetite 20.13 19.11 -1.02 -0.083 0.17425E+04 110 magnesioferrite 26.26 21.34 -4.92 -0.402 0.84027E+04 113 margarite 17.45 15.13 -2.32 -0.093 0.39639E+04 116 microcline -2.43 -6.09 -3.66 -0.281 0.62453E+04 120 muscovite 2.68 -0.30 -2.98 -0.175 0.50822E+04 121 paragonite 4.34 1.38 -2.95 -0.174 0.50446E+04 136 prehnite 19.47 16.67 -2.79 -0.164 0.47697E+04 137 prehnite-Fe 22.59 20.08 -2.51 -0.151 0.42877E+04 138 pumpellyite-Fe 46.47 42.76 -3.71 -0.083 0.63415E+04 139 pumpellyite-Mg 49.19 44.98 -4.21 -0.094 0.71947E+04 145 pyroxmangite 7.42 4.69 -2.72 -0.544 0.46469E+04 146 pyrophyllite -6.10 -9.36 -3.27 -0.204 0.55750E+04 147 quartz -2.98 -3.79 -0.81 -0.269 0.13776E+04 152 rhodochrosite -0.96 -4.25 -3.29 -1.098 0.56234E+04 153 rhodonite 7.46 4.69 -2.77 -0.554 0.47261E+04 154 sanidine -1.22 -6.09 -4.87 -0.375 0.83131E+04 156 siderite -2.59 -6.22 -3.63 -1.211 0.62032E+04 157 sillimanite 5.32 2.00 -3.32 -0.332 0.56654E+04 164 stilbite -7.41 -9.61 -2.20 -0.105 0.37565E+04 165 stilpnomelane-Fe 13.18 9.25 -3.93 -0.117 0.67169E+04 169 sudoite 21.22 17.69 -3.52 -0.114 0.60124E+04 175 tephroite 18.11 13.18 -4.93 -0.705 0.84264E+04 178 topaz-H 4.67 2.00 -2.66 -0.242 0.45490E+04 179 tridymite -2.61 -3.79 -1.17 -0.391 0.20049E+04 188 wairakite 4.06 1.76 -2.30 -0.135 0.39237E+04 189 walstromite 11.53 7.33 -4.19 -0.839 0.71596E+04 190 wollastonite 10.48 7.33 -3.15 -0.629 0.53735E+04 191 pseudo-wollastonite 11.02 7.33 -3.69 -0.737 0.62921E+04 192 zoisite 22.96 19.57 -3.39 -0.154 0.57963E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.32 -3.76 -0.233 0.64235E+04 195 beidellite-H -2.24 -7.16 -4.92 -0.314 0.83938E+04 196 beidellite-K -1.44 -6.37 -4.94 -0.302 0.84286E+04 197 beidellite-Mg -1.71 -5.72 -4.01 -0.248 0.68441E+04 198 beidellite-Na -1.26 -5.82 -4.56 -0.279 0.77862E+04 200 chalcedony -2.79 -3.79 -0.99 -0.331 0.16979E+04 202 montmorillonite-Ca -2.21 -5.60 -3.39 -0.209 0.57809E+04 203 montmorillonite-K -2.16 -6.65 -4.49 -0.275 0.76638E+04 204 montmorillonite-Mg -2.40 -5.99 -3.59 -0.222 0.61325E+04 205 montmorillonite-Na -1.96 -6.10 -4.13 -0.253 0.70596E+04 206 nontronite-Ca 3.28 1.48 -1.80 -0.117 0.30664E+04 207 nontronite-H 2.60 -0.35 -2.95 -0.198 0.50325E+04 208 nontronite-K 3.40 0.43 -2.97 -0.191 0.50707E+04 209 nontronite-Mg 3.14 1.09 -2.05 -0.133 0.34986E+04 210 nontronite-Na 3.58 0.99 -2.59 -0.167 0.44300E+04 215 gypsum -4.92 -9.16 -4.23 -1.058 0.72260E+04 225 tobermorite 9.84 5.48 -4.36 -1.190 0.74478E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.51 -3.31 -0.827 0.56510E+04 241 silica-amorphous -2.08 -3.79 -1.71 -0.570 0.29181E+04 243 an20ab80 2.08 -1.66 -3.74 -0.288 0.63852E+04 244 an25ab75 2.71 -0.97 -3.68 -0.283 0.62871E+04 245 an30ab70 3.34 -0.29 -3.63 -0.279 0.61973E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0180000 g New total amount of reactant added: 0.0184000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0184000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3058287E-03 Osmotic coef. = 0.9896 True ionic strength = .3183317E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15545E-07 -7.8084 0.14912E-07 -7.8265 0.95925E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13232E-03 -3.8784 0.95912E+00 -0.0181 4 SO4-- 0.25282E-04 -4.5972 0.22579E-04 -4.6463 0.89307E+00 -0.0491 5 HCO3- 0.12585E-04 -4.9002 0.12071E-04 -4.9183 0.95915E+00 -0.0181 6 HS- 0.16875E-10 -10.7728 0.16185E-10 -10.7909 0.95912E+00 -0.0181 7 Al+++ 0.32931E-20 -20.4824 0.26101E-20 -20.5833 0.79260E+00 -0.1009 8 H4SiO4 0.16600E-03 -3.7799 0.16600E-03 -3.7799 0.10000E+01 0.0000 9 Ca++ 0.35028E-04 -4.4556 0.31277E-04 -4.5048 0.89292E+00 -0.0492 10 Mg++ 0.13473E-06 -6.8705 0.12029E-06 -6.9198 0.89283E+00 -0.0492 11 Fe++ 0.80410E-09 -9.0947 0.71794E-09 -9.1439 0.89285E+00 -0.0492 12 K+ 0.39051E-05 -5.4084 0.37456E-05 -5.4265 0.95915E+00 -0.0181 13 Na+ 0.18313E-03 -3.7373 0.17564E-03 -3.7554 0.95911E+00 -0.0181 14 Mn++ 0.76497E-07 -7.1164 0.68302E-07 -7.1656 0.89287E+00 -0.0492 15 HPO4-- 0.13351E-08 -8.8745 0.11924E-08 -8.9236 0.89308E+00 -0.0491 16 HSiO3- 0.11324E-04 -4.9460 0.10861E-04 -4.9641 0.95912E+00 -0.0181 17 Ca(HSiO3)+ 0.79353E-08 -8.1004 0.76112E-08 -8.1185 0.95916E+00 -0.0181 18 Mg(HSiO3)+ 0.37982E-10 -10.4204 0.36431E-10 -10.4385 0.95916E+00 -0.0181 19 NaHSiO3,aq 0.30298E-07 -7.5186 0.30298E-07 -7.5186 0.10000E+01 0.0000 20 AlO+ 0.15799E-11 -11.8014 0.15154E-11 -11.8195 0.95916E+00 -0.0181 21 AlOH+2 0.12678E-15 -15.8970 0.11320E-15 -15.9462 0.89289E+00 -0.0492 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.31751E-05 -5.4982 0.30452E-05 -5.5164 0.95908E+00 -0.0181 24 CH4,aq 0.84912E-17 -17.0710 0.84904E-17 -17.0711 0.99991E+00 0.0000 29 CO,aq 0.92681E-17 -17.0330 0.92681E-17 -17.0330 0.10000E+01 0.0000 30 CO2,aq 0.36294E-06 -6.4402 0.36290E-06 -6.4402 0.99991E+00 0.0000 31 CO3-2 0.83809E-07 -7.0767 0.74843E-07 -7.1258 0.89303E+00 -0.0491 32 CaCO3,aq 0.28670E-07 -7.5426 0.28670E-07 -7.5426 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.99177E-08 -8.0036 0.95127E-08 -8.0217 0.95916E+00 -0.0181 34 CaCl+ 0.68756E-08 -8.1627 0.65948E-08 -8.1808 0.95916E+00 -0.0181 35 CaCl2,aq 0.20318E-12 -12.6921 0.20318E-12 -12.6921 0.10000E+01 0.0000 36 CaOH+ 0.15420E-06 -6.8119 0.14790E-06 -6.8300 0.95916E+00 -0.0181 37 CaSO4,aq 0.22004E-06 -6.6575 0.22004E-06 -6.6575 0.10000E+01 0.0000 38 HCl,aq 0.37114E-12 -12.4305 0.37114E-12 -12.4305 0.10000E+01 0.0000 43 FeCl+ 0.15426E-12 -12.8117 0.14796E-12 -12.8299 0.95916E+00 -0.0181 46 FeO,aq 0.12768E-09 -9.8939 0.12768E-09 -9.8939 0.10000E+01 0.0000 47 FeOH+ 0.16641E-08 -8.7788 0.15962E-08 -8.7969 0.95916E+00 -0.0181 48 HFeO2- 0.96023E-10 -10.0176 0.92097E-10 -10.0358 0.95912E+00 -0.0181 49 FeO+ 0.12860E-12 -12.8907 0.12335E-12 -12.9089 0.95916E+00 -0.0181 50 FeOH+2 0.38333E-18 -18.4164 0.34227E-18 -18.4656 0.89289E+00 -0.0492 51 FeO2- 0.11368E-09 -9.9443 0.10903E-09 -9.9625 0.95912E+00 -0.0181 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.99169E-09 -9.0036 0.99160E-09 -9.0037 0.99991E+00 0.0000 54 KCl,aq 0.87757E-11 -11.0567 0.87757E-11 -11.0567 0.10000E+01 0.0000 55 KHSO4,aq 0.33747E-17 -17.4718 0.33747E-17 -17.4718 0.10000E+01 0.0000 56 KOH,aq 0.10950E-09 -9.9606 0.10950E-09 -9.9606 0.10000E+01 0.0000 57 KSO4- 0.13585E-08 -8.8669 0.13030E-08 -8.8851 0.95912E+00 -0.0181 58 MgCO3,aq 0.27554E-10 -10.5598 0.27554E-10 -10.5598 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.38897E-10 -10.4101 0.37308E-10 -10.4282 0.95916E+00 -0.0181 60 MgCl+ 0.24006E-10 -10.6197 0.23026E-10 -10.6378 0.95916E+00 -0.0181 61 MgOH+ 0.32855E-08 -8.4834 0.31514E-08 -8.5015 0.95916E+00 -0.0181 63 MnO,aq 0.32426E-09 -9.4891 0.32426E-09 -9.4891 0.10000E+01 0.0000 64 MnOH+ 0.14707E-07 -7.8325 0.14107E-07 -7.8506 0.95916E+00 -0.0181 65 MnO2-2 0.56474E-16 -16.2482 0.50433E-16 -16.2973 0.89303E+00 -0.0491 66 HMnO2- 0.16988E-12 -12.7698 0.16294E-12 -12.7880 0.95912E+00 -0.0181 69 MnCl+ 0.57028E-10 -10.2439 0.54699E-10 -10.2620 0.95916E+00 -0.0181 70 MnSO4,aq 0.43706E-09 -9.3595 0.43706E-09 -9.3595 0.10000E+01 0.0000 71 NaCl,aq 0.75886E-08 -8.1198 0.75886E-08 -8.1198 0.10000E+01 0.0000 72 NaOH,aq 0.51756E-08 -8.2860 0.51756E-08 -8.2860 0.10000E+01 0.0000 74 OH- 0.41942E-04 -4.3773 0.40226E-04 -4.3955 0.95908E+00 -0.0181 82 H3PO4,aq 0.17069E-14 -14.7678 0.17069E-14 -14.7678 0.10000E+01 0.0000 83 H2PO4- 0.32500E-09 -9.4881 0.31172E-09 -9.5062 0.95914E+00 -0.0181 84 PO4-3 0.88002E-13 -13.0555 0.69831E-13 -13.1560 0.79352E+00 -0.1004 88 HP2O7-3 0.13194E-18 -18.8796 0.10458E-18 -18.9806 0.79261E+00 -0.1009 90 H2S,aq 0.72522E-12 -12.1395 0.72515E-12 -12.1396 0.99991E+00 0.0000 96 SO2,aq 0.20858E-19 -19.6807 0.20858E-19 -19.6807 0.10000E+01 0.0000 97 SO3-2 0.34173E-14 -14.4663 0.30528E-14 -14.5153 0.89333E+00 -0.0490 98 HSO3- 0.27776E-14 -14.5563 0.26640E-14 -14.5745 0.95912E+00 -0.0181 99 HSO4- 0.32570E-09 -9.4872 0.31240E-09 -9.5053 0.95918E+00 -0.0181 101 S2O3-2 0.21608E-18 -18.6654 0.19297E-18 -18.7145 0.89303E+00 -0.0491 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1554511E-07 -.6598086E-04 -.6650279E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999690E+06 0.0000 3 Cl- 0.1379606E-03 0.1379752E-03 0.4891489E+01 3.9481 4 SO4-- 0.2528248E-04 0.2550443E-04 0.2449924E+01 11.0067 5 HCO3- 0.1258469E-04 0.1307009E-04 0.7974770E+00 2.9082 6 HS- 0.1687519E-10 0.2258658E-09 0.7469615E-05 -2.9644 7 Al+++ 0.3293148E-20 0.3195432E-05 0.8621501E-01 2.8961 8 H4SiO4 0.1659977E-03 0.1773602E-03 0.1704654E+02 -3.7799 9 Ca++ 0.3502760E-04 0.3545523E-04 0.1420933E+01 11.1482 10 Mg++ 0.1347333E-06 0.1381473E-06 0.3358537E-02 8.7332 11 Fe++ 0.8041031E-09 0.3009373E-08 0.1680595E-03 6.5090 12 K+ 0.3905133E-05 0.3906610E-05 0.1527517E+00 2.4000 13 Na+ 0.1831257E-03 0.1831688E-03 0.4210890E+01 4.0711 14 Mn++ 0.7649738E-07 0.9202318E-07 0.5055421E-02 8.4874 15 HPO4-- 0.1335110E-08 0.1660200E-08 0.1593396E-03 6.7294 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2916367E-03 -.6598039E-04 -.2256563E-03 0.0000000E+00 2 H2O 0.5550802E+02 0.5550789E+02 0.1272123E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2601440E-04 0.2550424E-04 0.5101526E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5099267E-06 0.2258642E-09 -.5101526E-06 0.0000000E+00 7 Al+++ 0.5999765E-04 0.3195409E-05 0.5680224E-04 0.0000000E+00 8 H4SiO4 0.1915952E-03 0.1773589E-03 0.1423630E-04 0.0000000E+00 9 Ca++ 0.3563368E-04 0.3545498E-04 0.1787054E-06 0.0000000E+00 10 Mg++ 0.1460317E-04 0.1381463E-06 0.1446503E-04 0.0000000E+00 11 Fe++ 0.1311936E-04 0.3009351E-08 0.1311635E-04 0.0000000E+00 12 K+ 0.3906582E-05 0.3906582E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1831675E-03 0.1831675E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3190302E-06 0.9202252E-07 0.2270076E-06 0.0000000E+00 15 HPO4-- 0.1088834E-06 0.1660188E-08 0.1072232E-06 0.0000000E+00 Chg. balance for solid moles: -.2454E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0184000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3574E-07 -7.447 0.1795E-04 -4.746 0.2938 0.5705E-05 clinochlore 0.2893E-05 -5.539 0.1608E-02 -2.794 26.31 0.6116E-03 daphnite 0.1807E-05 -5.743 0.1289E-02 -2.890 21.10 0.3907E-03 chlorite-Mn 0.4540E-07 -7.343 0.3219E-04 -4.492 0.5267 0.1026E-04 diaspore 0.4731E-04 -4.325 0.2838E-02 -2.547 46.44 0.8450E-03 hematite 0.2041E-05 -5.690 0.3259E-03 -3.487 5.332 0.6177E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6096E+00 0.6096E+00 1.0000 -0.215 daphnite 0.3808E+00 0.3808E+00 1.0000 -0.419 chlorite-Mn 0.9567E-02 0.9567E-02 1.0000 -2.019 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.006112 g Volume = 0.001925 cm3 Porosity: 99.8089% V(tot) - V(min): 0.10054E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0184000 g log = -1.7352 Original solution: 1000.0103000 g Original solution / Rock added: 54348.39 (Water/Rock Ratio), log = 4.7352 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3920E-04 1.0073 0.4154E-04 0.4124E-04 CH4,gas 0.1260E-13 1.0129 0.1343E-13 0.1326E-13 H2,gas 0.1292E-05 1.0006 0.1360E-05 0.1359E-05 H2S,gas 0.2019E-10 0.9959 0.2115E-10 0.2124E-10 S2,gas 0.8610E-29 1.0000 0.9057E-29 0.9057E-29 CO,gas 0.1391E-13 1.0000 0.1463E-13 0.1463E-13 SO3,gas 0.1784E-35 1.0000 0.1877E-35 0.1877E-35 SO2,gas 0.9180E-19 1.0000 0.9657E-19 0.9657E-19 HCl,gas 0.6229E-15 1.0000 0.6553E-15 0.6553E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.74 -6.38 -2.127 0.10896E+05 -4.382 3 CH4,gas 4.81 -11.06 -15.87 -3.968 0.27101E+05 -13.872 4 H2,gas 8.29 0.42 -7.87 -4.495 0.13432E+05 -5.866 5 H2S,gas -5.94 -18.62 -12.67 -6.337 0.21642E+05 -10.675 6 S2,gas -7.03 -38.08 -31.04 -4.776 0.53005E+05 -29.043 7 CO,gas 3.51 -12.32 -15.83 -4.872 0.27037E+05 -13.835 8 SO3,gas 17.43 -20.30 -37.73 -9.432 0.64417E+05 -35.727 9 SO2,gas 1.14 -19.88 -21.02 -5.604 0.35883E+05 -19.015 10 HCl,gas 5.48 -11.70 -17.18 -8.592 0.29340E+05 -15.184 11 acmite 7.74 2.81 -4.93 -0.512 0.84132E+04 16 albite -0.33 -4.37 -4.04 -0.311 0.69053E+04 19 spessartine 24.55 19.91 -4.64 -0.232 0.79146E+04 20 analcite 3.37 -0.59 -3.96 -0.440 0.67671E+04 21 andalusite 5.06 2.01 -3.05 -0.305 0.52080E+04 22 andradite 39.09 34.70 -4.39 -0.228 0.74878E+04 23 grossular 32.83 27.90 -4.93 -0.247 0.84199E+04 24 anhydrite -5.28 -9.15 -3.87 -1.936 0.66102E+04 29 anorthite 12.80 9.38 -3.42 -0.263 0.58346E+04 35 aragonite 0.99 -1.60 -2.58 -0.861 0.44101E+04 36 brucite 12.58 8.73 -3.84 -0.769 0.65625E+04 37 calcite 0.83 -1.60 -2.43 -0.810 0.41487E+04 40 carpholite-Mg 8.65 6.97 -1.68 -0.112 0.28768E+04 41 carpholite-Fe 6.78 4.74 -2.04 -0.136 0.34858E+04 50 chloritoid-Mg 13.26 10.75 -2.52 -0.168 0.42956E+04 51 chloritoid-Fe 9.24 8.52 -0.72 -0.048 0.12249E+04 52 chloritoid-Mn 11.46 10.50 -0.96 -0.064 0.16452E+04 54 coesite -2.37 -3.78 -1.41 -0.470 0.24085E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.78 -1.23 -0.410 0.21014E+04 67 diopside 16.22 12.32 -3.89 -0.389 0.66487E+04 68 hedenbergite 14.24 10.10 -4.15 -0.415 0.70809E+04 75 epidote 24.78 23.05 -1.73 -0.084 0.29498E+04 76 clinozoisite 22.92 19.64 -3.28 -0.149 0.55941E+04 77 epidote-Fe 29.94 26.45 -3.49 -0.181 0.59530E+04 78 fayalite 14.08 9.24 -4.84 -0.692 0.82655E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.97 -4.23 -0.352 0.72173E+04 91 heulandite -5.71 -9.52 -3.81 -0.173 0.65086E+04 95 jadeite 4.25 -0.59 -4.84 -0.484 0.82702E+04 98 kaolinite -1.27 -1.77 -0.49 -0.045 0.84430E+03 99 kyanite 4.93 2.01 -2.92 -0.292 0.49847E+04 101 laumontite 2.97 1.82 -1.15 -0.077 0.19701E+04 102 lawsonite 9.68 9.38 -0.30 -0.020 0.50852E+03 105 lizardite 23.29 18.64 -4.65 -0.387 0.79357E+04 106 magnesite 0.71 -4.01 -4.72 -1.574 0.80607E+04 107 magnetite 20.13 19.11 -1.03 -0.084 0.17521E+04 110 magnesioferrite 26.26 21.33 -4.93 -0.402 0.84118E+04 113 margarite 17.45 15.17 -2.28 -0.091 0.38914E+04 116 microcline -2.43 -6.04 -3.61 -0.278 0.61671E+04 120 muscovite 2.68 -0.25 -2.93 -0.172 0.50040E+04 121 paragonite 4.34 1.42 -2.92 -0.172 0.49806E+04 136 prehnite 19.47 16.75 -2.72 -0.160 0.46401E+04 137 prehnite-Fe 22.59 20.15 -2.44 -0.146 0.41581E+04 138 pumpellyite-Fe 46.47 42.90 -3.57 -0.079 0.60919E+04 139 pumpellyite-Mg 49.19 45.13 -4.07 -0.090 0.69445E+04 145 pyroxmangite 7.42 4.71 -2.71 -0.542 0.46248E+04 146 pyrophyllite -6.10 -9.33 -3.23 -0.202 0.55141E+04 147 quartz -2.98 -3.78 -0.80 -0.266 0.13624E+04 152 rhodochrosite -0.96 -4.26 -3.30 -1.100 0.56327E+04 153 rhodonite 7.46 4.71 -2.75 -0.551 0.47040E+04 154 sanidine -1.22 -6.04 -4.82 -0.371 0.82348E+04 156 siderite -2.59 -6.24 -3.65 -1.216 0.62289E+04 157 sillimanite 5.32 2.01 -3.31 -0.331 0.56501E+04 164 stilbite -7.41 -9.52 -2.11 -0.101 0.36080E+04 165 stilpnomelane-Fe 13.18 9.30 -3.88 -0.116 0.66270E+04 169 sudoite 21.22 17.71 -3.51 -0.113 0.59849E+04 175 tephroite 18.11 13.19 -4.92 -0.703 0.83974E+04 178 topaz-H 4.67 2.01 -2.66 -0.241 0.45338E+04 179 tridymite -2.61 -3.78 -1.17 -0.388 0.19897E+04 188 wairakite 4.06 1.82 -2.24 -0.132 0.38209E+04 189 walstromite 11.53 7.37 -4.16 -0.832 0.71024E+04 190 wollastonite 10.48 7.37 -3.11 -0.623 0.53163E+04 191 pseudo-wollastonite 11.02 7.37 -3.65 -0.730 0.62349E+04 192 zoisite 22.96 19.64 -3.32 -0.151 0.56666E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.28 -3.73 -0.230 0.63607E+04 195 beidellite-H -2.24 -7.12 -4.88 -0.312 0.83380E+04 196 beidellite-K -1.44 -6.33 -4.90 -0.300 0.83620E+04 197 beidellite-Mg -1.71 -5.68 -3.98 -0.246 0.67897E+04 198 beidellite-Na -1.26 -5.78 -4.52 -0.277 0.77244E+04 200 chalcedony -2.79 -3.78 -0.99 -0.328 0.16827E+04 202 montmorillonite-Ca -2.21 -5.56 -3.35 -0.207 0.57161E+04 203 montmorillonite-K -2.16 -6.61 -4.45 -0.272 0.75952E+04 204 montmorillonite-Mg -2.40 -5.96 -3.56 -0.220 0.60762E+04 205 montmorillonite-Na -1.96 -6.06 -4.10 -0.251 0.69957E+04 206 nontronite-Ca 3.28 1.52 -1.76 -0.114 0.30036E+04 207 nontronite-H 2.60 -0.32 -2.91 -0.195 0.49767E+04 208 nontronite-K 3.40 0.47 -2.93 -0.188 0.50041E+04 209 nontronite-Mg 3.14 1.12 -2.02 -0.131 0.34443E+04 210 nontronite-Na 3.58 1.02 -2.56 -0.164 0.43681E+04 215 gypsum -4.92 -9.15 -4.23 -1.057 0.72169E+04 225 tobermorite 9.84 5.51 -4.33 -1.182 0.73976E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.51 -3.32 -0.829 0.56606E+04 241 silica-amorphous -2.08 -3.78 -1.70 -0.567 0.29029E+04 243 an20ab80 2.08 -1.62 -3.70 -0.285 0.63195E+04 244 an25ab75 2.71 -0.93 -3.64 -0.280 0.62210E+04 245 an30ab70 3.34 -0.25 -3.59 -0.276 0.61308E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0184000 g New total amount of reactant added: 0.0188000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0188000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3073242E-03 Osmotic coef. = 0.9895 True ionic strength = .3202312E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15217E-07 -7.8177 0.14596E-07 -7.8358 0.95919E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13231E-03 -3.8784 0.95905E+00 -0.0182 4 SO4-- 0.25280E-04 -4.5972 0.22570E-04 -4.6465 0.89283E+00 -0.0492 5 HCO3- 0.12589E-04 -4.9000 0.12074E-04 -4.9181 0.95908E+00 -0.0181 6 HS- 0.14924E-10 -10.8261 0.14313E-10 -10.8443 0.95905E+00 -0.0182 7 Al+++ 0.30900E-20 -20.5100 0.24476E-20 -20.6113 0.79211E+00 -0.1012 8 H4SiO4 0.16936E-03 -3.7712 0.16936E-03 -3.7712 0.10000E+01 0.0000 9 Ca++ 0.35474E-04 -4.4501 0.31667E-04 -4.4994 0.89267E+00 -0.0493 10 Mg++ 0.12758E-06 -6.8942 0.11387E-06 -6.9436 0.89258E+00 -0.0494 11 Fe++ 0.76090E-09 -9.1187 0.67918E-09 -9.1680 0.89260E+00 -0.0493 12 K+ 0.39900E-05 -5.3990 0.38268E-05 -5.4172 0.95909E+00 -0.0181 13 Na+ 0.18363E-03 -3.7361 0.17611E-03 -3.7542 0.95905E+00 -0.0182 14 Mn++ 0.73889E-07 -7.1314 0.65955E-07 -7.1808 0.89262E+00 -0.0493 15 HPO4-- 0.12713E-08 -8.8957 0.11351E-08 -8.9450 0.89283E+00 -0.0492 16 HSiO3- 0.11805E-04 -4.9279 0.11321E-04 -4.9461 0.95905E+00 -0.0182 17 Ca(HSiO3)+ 0.83751E-08 -8.0770 0.80325E-08 -8.0951 0.95909E+00 -0.0181 18 Mg(HSiO3)+ 0.37481E-10 -10.4262 0.35948E-10 -10.4443 0.95909E+00 -0.0181 19 NaHSiO3,aq 0.31666E-07 -7.4994 0.31666E-07 -7.4994 0.10000E+01 0.0000 20 AlO+ 0.15465E-11 -11.8106 0.14833E-11 -11.8288 0.95909E+00 -0.0181 21 AlOH+2 0.12149E-15 -15.9155 0.10845E-15 -15.9648 0.89264E+00 -0.0493 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.32441E-05 -5.4889 0.31111E-05 -5.5071 0.95901E+00 -0.0182 24 CH4,aq 0.75139E-17 -17.1241 0.75132E-17 -17.1242 0.99990E+00 0.0000 29 CO,aq 0.88478E-17 -17.0532 0.88478E-17 -17.0532 0.10000E+01 0.0000 30 CO2,aq 0.35535E-06 -6.4493 0.35531E-06 -6.4494 0.99990E+00 0.0000 31 CO3-2 0.85673E-07 -7.0672 0.76487E-07 -7.1164 0.89278E+00 -0.0493 32 CaCO3,aq 0.29665E-07 -7.5278 0.29665E-07 -7.5278 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10045E-07 -7.9981 0.96341E-08 -8.0162 0.95909E+00 -0.0181 34 CaCl+ 0.69613E-08 -8.1573 0.66765E-08 -8.1755 0.95909E+00 -0.0181 35 CaCl2,aq 0.20568E-12 -12.6868 0.20568E-12 -12.6868 0.10000E+01 0.0000 36 CaOH+ 0.15951E-06 -6.7972 0.15299E-06 -6.8153 0.95909E+00 -0.0181 37 CaSO4,aq 0.22269E-06 -6.6523 0.22269E-06 -6.6523 0.10000E+01 0.0000 38 HCl,aq 0.36324E-12 -12.4398 0.36324E-12 -12.4398 0.10000E+01 0.0000 43 FeCl+ 0.14593E-12 -12.8358 0.13996E-12 -12.8540 0.95909E+00 -0.0181 46 FeO,aq 0.12608E-09 -9.8994 0.12608E-09 -9.8994 0.10000E+01 0.0000 47 FeOH+ 0.16085E-08 -8.7936 0.15427E-08 -8.8117 0.95909E+00 -0.0181 48 HFeO2- 0.96877E-10 -10.0138 0.92910E-10 -10.0319 0.95905E+00 -0.0182 49 FeO+ 0.12589E-12 -12.9000 0.12074E-12 -12.9182 0.95909E+00 -0.0181 50 FeOH+2 0.36735E-18 -18.4349 0.32791E-18 -18.4842 0.89264E+00 -0.0493 51 FeO2- 0.11615E-09 -9.9350 0.11139E-09 -9.9531 0.95905E+00 -0.0182 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.96693E-09 -9.0146 0.96684E-09 -9.0146 0.99990E+00 0.0000 54 KCl,aq 0.89653E-11 -11.0474 0.89653E-11 -11.0474 0.10000E+01 0.0000 55 KHSO4,aq 0.33735E-17 -17.4719 0.33735E-17 -17.4719 0.10000E+01 0.0000 56 KOH,aq 0.11430E-09 -9.9420 0.11430E-09 -9.9420 0.10000E+01 0.0000 57 KSO4- 0.13875E-08 -8.8578 0.13307E-08 -8.8759 0.95905E+00 -0.0182 58 MgCO3,aq 0.26656E-10 -10.5742 0.26656E-10 -10.5742 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.36835E-10 -10.4337 0.35328E-10 -10.4519 0.95909E+00 -0.0181 60 MgCl+ 0.22725E-10 -10.6435 0.21796E-10 -10.6616 0.95909E+00 -0.0181 61 MgOH+ 0.31778E-08 -8.4979 0.30478E-08 -8.5160 0.95909E+00 -0.0181 63 MnO,aq 0.32683E-09 -9.4857 0.32683E-09 -9.4857 0.10000E+01 0.0000 64 MnOH+ 0.14511E-07 -7.8383 0.13917E-07 -7.8565 0.95909E+00 -0.0181 65 MnO2-2 0.59431E-16 -16.2260 0.53058E-16 -16.2752 0.89278E+00 -0.0493 66 HMnO2- 0.17495E-12 -12.7571 0.16779E-12 -12.7752 0.95905E+00 -0.0182 69 MnCl+ 0.55068E-10 -10.2591 0.52815E-10 -10.2772 0.95909E+00 -0.0181 70 MnSO4,aq 0.42188E-09 -9.3748 0.42188E-09 -9.3748 0.10000E+01 0.0000 71 NaCl,aq 0.76083E-08 -8.1187 0.76083E-08 -8.1187 0.10000E+01 0.0000 72 NaOH,aq 0.53018E-08 -8.2756 0.53018E-08 -8.2756 0.10000E+01 0.0000 74 OH- 0.42854E-04 -4.3680 0.41097E-04 -4.3862 0.95901E+00 -0.0182 82 H3PO4,aq 0.15567E-14 -14.8078 0.15567E-14 -14.8078 0.10000E+01 0.0000 83 H2PO4- 0.30285E-09 -9.5188 0.29046E-09 -9.5369 0.95907E+00 -0.0181 84 PO4-3 0.85643E-13 -13.0673 0.67917E-13 -13.1680 0.79303E+00 -0.1007 88 HP2O7-3 0.11711E-18 -18.9314 0.92764E-19 -19.0326 0.79212E+00 -0.1012 90 H2S,aq 0.62772E-12 -12.2022 0.62766E-12 -12.2023 0.99990E+00 0.0000 96 SO2,aq 0.19477E-19 -19.7105 0.19477E-19 -19.7105 0.10000E+01 0.0000 97 SO3-2 0.33316E-14 -14.4773 0.29754E-14 -14.5265 0.89309E+00 -0.0491 98 HSO3- 0.26500E-14 -14.5768 0.25415E-14 -14.5949 0.95905E+00 -0.0182 99 HSO4- 0.31869E-09 -9.4966 0.30566E-09 -9.5148 0.95911E+00 -0.0181 101 S2O3-2 0.18701E-18 -18.7281 0.16696E-18 -18.7774 0.89278E+00 -0.0493 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1521658E-07 -.6766664E-04 -.6820188E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999686E+06 0.0000 3 Cl- 0.1379605E-03 0.1379752E-03 0.4891488E+01 3.9574 4 SO4-- 0.2527982E-04 0.2550444E-04 0.2449924E+01 11.0251 5 HCO3- 0.1258930E-04 0.1307009E-04 0.7974768E+00 2.9176 6 HS- 0.1492394E-10 0.2173188E-09 0.7186952E-05 -3.0085 7 Al+++ 0.3090020E-20 0.3264433E-05 0.8807668E-01 2.8961 8 H4SiO4 0.1693618E-03 0.1812066E-03 0.1741623E+02 -3.7712 9 Ca++ 0.3547396E-04 0.3591121E-04 0.1439206E+01 11.1722 10 Mg++ 0.1275794E-06 0.1308809E-06 0.3181881E-02 8.7280 11 Fe++ 0.7609013E-09 0.2912247E-08 0.1626354E-03 6.5035 12 K+ 0.3990026E-05 0.3991536E-05 0.1560724E+00 2.4186 13 Na+ 0.1836263E-03 0.1836709E-03 0.4222432E+01 4.0816 14 Mn++ 0.7388945E-07 0.8920397E-07 0.4900542E-02 8.4908 15 HPO4-- 0.1271344E-08 0.1574284E-08 0.1510937E-03 6.7266 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2982601E-03 -.6766615E-04 -.2305939E-03 0.0000000E+00 2 H2O 0.5550801E+02 0.5550788E+02 0.1299848E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2602548E-04 0.2550425E-04 0.5212294E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5210121E-06 0.2173172E-09 -.5212294E-06 0.0000000E+00 7 Al+++ 0.6130194E-04 0.3264410E-05 0.5803753E-04 0.0000000E+00 8 H4SiO4 0.1957603E-03 0.1812053E-03 0.1455500E-04 0.0000000E+00 9 Ca++ 0.3609374E-04 0.3591095E-04 0.1827936E-06 0.0000000E+00 10 Mg++ 0.1492063E-04 0.1308799E-06 0.1478975E-04 0.0000000E+00 11 Fe++ 0.1340456E-04 0.2912226E-08 0.1340165E-04 0.0000000E+00 12 K+ 0.3991507E-05 0.3991507E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1836696E-03 0.1836696E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3259656E-06 0.8920333E-07 0.2367623E-06 0.0000000E+00 15 HPO4-- 0.1112504E-06 0.1574273E-08 0.1096762E-06 0.0000000E+00 Chg. balance for solid moles: 0.1085E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0188000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3656E-07 -7.437 0.1836E-04 -4.736 0.2940 0.5835E-05 clinochlore 0.2958E-05 -5.529 0.1644E-02 -2.784 26.32 0.6254E-03 daphnite 0.1846E-05 -5.734 0.1317E-02 -2.880 21.09 0.3992E-03 chlorite-Mn 0.4735E-07 -7.325 0.3357E-04 -4.474 0.5375 0.1070E-04 diaspore 0.4833E-04 -4.316 0.2900E-02 -2.538 46.42 0.8632E-03 hematite 0.2085E-05 -5.681 0.3330E-03 -3.478 5.331 0.6311E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3806E+00 0.3806E+00 1.0000 -0.420 chlorite-Mn 0.9760E-02 0.9760E-02 1.0000 -2.011 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.006246 g Volume = 0.001967 cm3 Porosity: 99.8047% V(tot) - V(min): 0.10056E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0188000 g log = -1.7258 Original solution: 1000.0103000 g Original solution / Rock added: 53192.04 (Water/Rock Ratio), log = 4.7258 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3838E-04 1.0073 0.4067E-04 0.4038E-04 CH4,gas 0.1115E-13 1.0129 0.1188E-13 0.1173E-13 H2,gas 0.1260E-05 1.0006 0.1326E-05 0.1325E-05 H2S,gas 0.1747E-10 0.9959 0.1831E-10 0.1838E-10 S2,gas 0.6785E-29 1.0000 0.7138E-29 0.7138E-29 CO,gas 0.1328E-13 1.0000 0.1397E-13 0.1397E-13 SO3,gas 0.1709E-35 1.0000 0.1798E-35 0.1798E-35 SO2,gas 0.8572E-19 1.0000 0.9018E-19 0.9018E-19 HCl,gas 0.6097E-15 1.0000 0.6414E-15 0.6414E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.75 -6.39 -2.130 0.10912E+05 -4.391 3 CH4,gas 4.81 -11.12 -15.93 -3.981 0.27192E+05 -13.925 4 H2,gas 8.29 0.41 -7.88 -4.501 0.13450E+05 -5.877 5 H2S,gas -5.94 -18.68 -12.74 -6.369 0.21749E+05 -10.737 6 S2,gas -7.03 -38.18 -31.15 -4.792 0.53182E+05 -29.146 7 CO,gas 3.51 -12.34 -15.85 -4.878 0.27072E+05 -13.855 8 SO3,gas 17.43 -20.32 -37.75 -9.436 0.64449E+05 -35.745 9 SO2,gas 1.14 -19.91 -21.04 -5.612 0.35934E+05 -19.045 10 HCl,gas 5.48 -11.71 -17.19 -8.596 0.29356E+05 -15.193 11 acmite 7.74 2.84 -4.90 -0.509 0.83656E+04 16 albite -0.33 -4.34 -4.01 -0.308 0.68428E+04 19 spessartine 24.55 19.95 -4.60 -0.230 0.78524E+04 20 analcite 3.37 -0.56 -3.94 -0.437 0.67195E+04 21 andalusite 5.06 2.02 -3.04 -0.304 0.51931E+04 22 andradite 39.09 34.80 -4.29 -0.223 0.73202E+04 23 grossular 32.83 28.00 -4.83 -0.242 0.82523E+04 24 anhydrite -5.28 -9.15 -3.87 -1.933 0.66013E+04 29 anorthite 12.80 9.42 -3.38 -0.260 0.57639E+04 35 aragonite 0.99 -1.58 -2.57 -0.856 0.43848E+04 36 brucite 12.58 8.73 -3.85 -0.770 0.65714E+04 37 calcite 0.83 -1.58 -2.41 -0.805 0.41234E+04 40 carpholite-Mg 8.65 6.98 -1.67 -0.112 0.28559E+04 41 carpholite-Fe 6.78 4.75 -2.03 -0.135 0.34654E+04 50 chloritoid-Mg 13.26 10.75 -2.51 -0.167 0.42896E+04 51 chloritoid-Fe 9.24 8.52 -0.71 -0.048 0.12194E+04 52 chloritoid-Mn 11.46 10.51 -0.95 -0.063 0.16245E+04 54 coesite -2.37 -3.77 -1.40 -0.467 0.23936E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.77 -1.22 -0.407 0.20865E+04 67 diopside 16.22 12.36 -3.86 -0.386 0.65869E+04 68 hedenbergite 14.24 10.13 -4.11 -0.411 0.70195E+04 75 epidote 24.78 23.12 -1.65 -0.080 0.28232E+04 76 clinozoisite 22.92 19.72 -3.20 -0.146 0.54675E+04 77 epidote-Fe 29.94 26.52 -3.41 -0.177 0.58264E+04 78 fayalite 14.08 9.24 -4.84 -0.692 0.82694E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.97 -4.23 -0.352 0.72157E+04 91 heulandite -5.71 -9.43 -3.73 -0.169 0.63635E+04 95 jadeite 4.25 -0.56 -4.82 -0.482 0.82226E+04 98 kaolinite -1.27 -1.75 -0.48 -0.043 0.81455E+03 99 kyanite 4.93 2.02 -2.91 -0.291 0.49699E+04 101 laumontite 2.97 1.88 -1.09 -0.073 0.18696E+04 102 lawsonite 9.68 9.42 -0.26 -0.017 0.43780E+03 105 lizardite 23.29 18.64 -4.65 -0.387 0.79326E+04 106 magnesite 0.71 -4.03 -4.74 -1.578 0.80853E+04 107 magnetite 20.13 19.10 -1.03 -0.084 0.17615E+04 110 magnesioferrite 26.26 21.33 -4.93 -0.403 0.84207E+04 113 margarite 17.45 15.21 -2.24 -0.090 0.38207E+04 116 microcline -2.43 -6.00 -3.57 -0.274 0.60907E+04 120 muscovite 2.68 -0.21 -2.89 -0.170 0.49275E+04 121 paragonite 4.34 1.46 -2.88 -0.169 0.49181E+04 136 prehnite 19.47 16.82 -2.64 -0.155 0.45135E+04 137 prehnite-Fe 22.59 20.23 -2.36 -0.142 0.40315E+04 138 pumpellyite-Fe 46.47 43.05 -3.43 -0.076 0.58481E+04 139 pumpellyite-Mg 49.19 45.27 -3.92 -0.087 0.67002E+04 145 pyroxmangite 7.42 4.72 -2.70 -0.539 0.46040E+04 146 pyrophyllite -6.10 -9.29 -3.19 -0.200 0.54546E+04 147 quartz -2.98 -3.77 -0.79 -0.263 0.13475E+04 152 rhodochrosite -0.96 -4.26 -3.30 -1.102 0.56425E+04 153 rhodonite 7.46 4.72 -2.74 -0.549 0.46833E+04 154 sanidine -1.22 -6.00 -4.78 -0.368 0.81584E+04 156 siderite -2.59 -6.25 -3.66 -1.221 0.62540E+04 157 sillimanite 5.32 2.02 -3.30 -0.330 0.56353E+04 164 stilbite -7.41 -9.43 -2.03 -0.097 0.34629E+04 165 stilpnomelane-Fe 13.18 9.35 -3.83 -0.114 0.65389E+04 169 sudoite 21.22 17.73 -3.49 -0.113 0.59581E+04 175 tephroite 18.11 13.21 -4.90 -0.700 0.83708E+04 178 topaz-H 4.67 2.02 -2.65 -0.241 0.45189E+04 179 tridymite -2.61 -3.77 -1.16 -0.386 0.19748E+04 188 wairakite 4.06 1.88 -2.18 -0.128 0.37204E+04 189 walstromite 11.53 7.40 -4.13 -0.825 0.70466E+04 190 wollastonite 10.48 7.40 -3.08 -0.616 0.52604E+04 191 pseudo-wollastonite 11.02 7.40 -3.62 -0.724 0.61791E+04 192 zoisite 22.96 19.72 -3.24 -0.147 0.55401E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.25 -3.69 -0.228 0.62993E+04 195 beidellite-H -2.24 -7.09 -4.85 -0.310 0.82834E+04 196 beidellite-K -1.44 -6.29 -4.86 -0.298 0.82969E+04 197 beidellite-Mg -1.71 -5.65 -3.95 -0.244 0.67366E+04 198 beidellite-Na -1.26 -5.75 -4.49 -0.275 0.76639E+04 200 chalcedony -2.79 -3.77 -0.98 -0.326 0.16678E+04 202 montmorillonite-Ca -2.21 -5.52 -3.31 -0.205 0.56528E+04 203 montmorillonite-K -2.16 -6.57 -4.41 -0.270 0.75281E+04 204 montmorillonite-Mg -2.40 -5.93 -3.53 -0.218 0.60210E+04 205 montmorillonite-Na -1.96 -6.02 -4.06 -0.249 0.69332E+04 206 nontronite-Ca 3.28 1.56 -1.72 -0.112 0.29423E+04 207 nontronite-H 2.60 -0.29 -2.88 -0.193 0.49221E+04 208 nontronite-K 3.40 0.51 -2.89 -0.186 0.49390E+04 209 nontronite-Mg 3.14 1.15 -1.99 -0.129 0.33911E+04 210 nontronite-Na 3.58 1.06 -2.52 -0.162 0.43077E+04 215 gypsum -4.92 -9.15 -4.22 -1.055 0.72080E+04 225 tobermorite 9.84 5.54 -4.30 -1.174 0.73486E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.50 -3.32 -0.830 0.56700E+04 241 silica-amorphous -2.08 -3.77 -1.69 -0.564 0.28880E+04 243 an20ab80 2.08 -1.58 -3.66 -0.282 0.62554E+04 244 an25ab75 2.71 -0.90 -3.61 -0.277 0.61565E+04 245 an30ab70 3.34 -0.21 -3.55 -0.273 0.60659E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0188000 g New total amount of reactant added: 0.0192000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0192000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3088190E-03 Osmotic coef. = 0.9895 True ionic strength = .3221326E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14904E-07 -7.8267 0.14294E-07 -7.8448 0.95912E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13230E-03 -3.8784 0.95898E+00 -0.0182 4 SO4-- 0.25277E-04 -4.5973 0.22562E-04 -4.6466 0.89258E+00 -0.0494 5 HCO3- 0.12594E-04 -4.8999 0.12077E-04 -4.9180 0.95902E+00 -0.0182 6 HS- 0.13239E-10 -10.8781 0.12696E-10 -10.8963 0.95899E+00 -0.0182 7 Al+++ 0.29045E-20 -20.5369 0.22993E-20 -20.6384 0.79161E+00 -0.1015 8 H4SiO4 0.17272E-03 -3.7627 0.17272E-03 -3.7627 0.10000E+01 0.0000 9 Ca++ 0.35920E-04 -4.4447 0.32056E-04 -4.4941 0.89243E+00 -0.0494 10 Mg++ 0.12098E-06 -6.9173 0.10795E-06 -6.9668 0.89233E+00 -0.0495 11 Fe++ 0.72109E-09 -9.1420 0.64347E-09 -9.1915 0.89235E+00 -0.0495 12 K+ 0.40749E-05 -5.3899 0.39079E-05 -5.4081 0.95902E+00 -0.0182 13 Na+ 0.18413E-03 -3.7349 0.17657E-03 -3.7531 0.95898E+00 -0.0182 14 Mn++ 0.71365E-07 -7.1465 0.63684E-07 -7.1960 0.89237E+00 -0.0495 15 HPO4-- 0.12119E-08 -8.9165 0.10817E-08 -8.9659 0.89258E+00 -0.0494 16 HSiO3- 0.12293E-04 -4.9103 0.11789E-04 -4.9285 0.95898E+00 -0.0182 17 Ca(HSiO3)+ 0.88289E-08 -8.0541 0.84671E-08 -8.0723 0.95903E+00 -0.0182 18 Mg(HSiO3)+ 0.37002E-10 -10.4318 0.35486E-10 -10.4499 0.95903E+00 -0.0182 19 NaHSiO3,aq 0.33061E-07 -7.4807 0.33061E-07 -7.4807 0.10000E+01 0.0000 20 AlO+ 0.15147E-11 -11.8197 0.14527E-11 -11.8378 0.95903E+00 -0.0182 21 AlOH+2 0.11656E-15 -15.9334 0.10402E-15 -15.9829 0.89239E+00 -0.0494 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.33127E-05 -5.4798 0.31766E-05 -5.4980 0.95894E+00 -0.0182 24 CH4,aq 0.66696E-17 -17.1759 0.66689E-17 -17.1759 0.99990E+00 0.0000 29 CO,aq 0.84565E-17 -17.0728 0.84565E-17 -17.0728 0.10000E+01 0.0000 30 CO2,aq 0.34811E-06 -6.4583 0.34808E-06 -6.4583 0.99990E+00 0.0000 31 CO3-2 0.87525E-07 -7.0579 0.78119E-07 -7.1072 0.89254E+00 -0.0494 32 CaCO3,aq 0.30671E-07 -7.5133 0.30671E-07 -7.5133 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10172E-07 -7.9926 0.97552E-08 -8.0108 0.95903E+00 -0.0182 34 CaCl+ 0.70469E-08 -8.1520 0.67581E-08 -8.1702 0.95903E+00 -0.0182 35 CaCl2,aq 0.20818E-12 -12.6816 0.20818E-12 -12.6816 0.10000E+01 0.0000 36 CaOH+ 0.16489E-06 -6.7828 0.15813E-06 -6.8010 0.95903E+00 -0.0182 37 CaSO4,aq 0.22535E-06 -6.6471 0.22535E-06 -6.6471 0.10000E+01 0.0000 38 HCl,aq 0.35572E-12 -12.4489 0.35572E-12 -12.4489 0.10000E+01 0.0000 43 FeCl+ 0.13826E-12 -12.8593 0.13259E-12 -12.8775 0.95903E+00 -0.0182 46 FeO,aq 0.12453E-09 -9.9047 0.12453E-09 -9.9047 0.10000E+01 0.0000 47 FeOH+ 0.15561E-08 -8.8080 0.14924E-08 -8.8261 0.95903E+00 -0.0182 48 HFeO2- 0.97712E-10 -10.0101 0.93704E-10 -10.0282 0.95898E+00 -0.0182 49 FeO+ 0.12330E-12 -12.9090 0.11825E-12 -12.9272 0.95903E+00 -0.0182 50 FeOH+2 0.35245E-18 -18.4529 0.31452E-18 -18.5023 0.89239E+00 -0.0494 51 FeO2- 0.11860E-09 -9.9259 0.11374E-09 -9.9441 0.95898E+00 -0.0182 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.94338E-09 -9.0253 0.94329E-09 -9.0254 0.99990E+00 0.0000 54 KCl,aq 0.91547E-11 -11.0384 0.91547E-11 -11.0384 0.10000E+01 0.0000 55 KHSO4,aq 0.33726E-17 -17.4720 0.33726E-17 -17.4720 0.10000E+01 0.0000 56 KOH,aq 0.11918E-09 -9.9238 0.11918E-09 -9.9238 0.10000E+01 0.0000 57 KSO4- 0.14165E-08 -8.8488 0.13584E-08 -8.8670 0.95898E+00 -0.0182 58 MgCO3,aq 0.25809E-10 -10.5882 0.25809E-10 -10.5882 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.34931E-10 -10.4568 0.33499E-10 -10.4750 0.95903E+00 -0.0182 60 MgCl+ 0.21543E-10 -10.6667 0.20661E-10 -10.6849 0.95903E+00 -0.0182 61 MgOH+ 0.30762E-08 -8.5120 0.29502E-08 -8.5302 0.95903E+00 -0.0182 63 MnO,aq 0.32901E-09 -9.4828 0.32901E-09 -9.4828 0.10000E+01 0.0000 64 MnOH+ 0.14307E-07 -7.8444 0.13721E-07 -7.8626 0.95903E+00 -0.0182 65 MnO2-2 0.62391E-16 -16.2049 0.55686E-16 -16.2543 0.89254E+00 -0.0494 66 HMnO2- 0.17984E-12 -12.7451 0.17246E-12 -12.7633 0.95898E+00 -0.0182 69 MnCl+ 0.53172E-10 -10.2743 0.50993E-10 -10.2925 0.95903E+00 -0.0182 70 MnSO4,aq 0.40720E-09 -9.3902 0.40720E-09 -9.3902 0.10000E+01 0.0000 71 NaCl,aq 0.76280E-08 -8.1176 0.76280E-08 -8.1176 0.10000E+01 0.0000 72 NaOH,aq 0.54278E-08 -8.2654 0.54278E-08 -8.2654 0.10000E+01 0.0000 74 OH- 0.43760E-04 -4.3589 0.41963E-04 -4.3771 0.95894E+00 -0.0182 82 H3PO4,aq 0.14230E-14 -14.8468 0.14230E-14 -14.8468 0.10000E+01 0.0000 83 H2PO4- 0.28268E-09 -9.5487 0.27109E-09 -9.5669 0.95900E+00 -0.0182 84 PO4-3 0.83386E-13 -13.0789 0.66087E-13 -13.1799 0.79254E+00 -0.1010 88 HP2O7-3 0.10422E-18 -18.9820 0.82507E-19 -19.0835 0.79162E+00 -0.1015 90 H2S,aq 0.54533E-12 -12.2633 0.54528E-12 -12.2634 0.99990E+00 0.0000 96 SO2,aq 0.18220E-19 -19.7395 0.18220E-19 -19.7395 0.10000E+01 0.0000 97 SO3-2 0.32501E-14 -14.4881 0.29019E-14 -14.5373 0.89284E+00 -0.0492 98 HSO3- 0.25313E-14 -14.5967 0.24275E-14 -14.6148 0.95898E+00 -0.0182 99 HSO4- 0.31202E-09 -9.5058 0.29924E-09 -9.5240 0.95905E+00 -0.0182 101 S2O3-2 0.16245E-18 -18.7893 0.14499E-18 -18.8387 0.89254E+00 -0.0494 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1490370E-07 -.6935240E-04 -.6990094E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999682E+06 0.0000 3 Cl- 0.1379604E-03 0.1379752E-03 0.4891487E+01 3.9664 4 SO4-- 0.2527716E-04 0.2550445E-04 0.2449924E+01 11.0430 5 HCO3- 0.1259356E-04 0.1307010E-04 0.7974766E+00 2.9268 6 HS- 0.1323917E-10 0.2093574E-09 0.6923659E-05 -3.0515 7 Al+++ 0.2904512E-20 0.3332995E-05 0.8992648E-01 2.8961 8 H4SiO4 0.1727184E-03 0.1850535E-03 0.1778595E+02 -3.7627 9 Ca++ 0.3592024E-04 0.3636720E-04 0.1457480E+01 11.1956 10 Mg++ 0.1209769E-06 0.1241723E-06 0.3018787E-02 8.7229 11 Fe++ 0.7210890E-09 0.2821793E-08 0.1575839E-03 6.4982 12 K+ 0.4074919E-05 0.4076463E-05 0.1593930E+00 2.4368 13 Na+ 0.1841269E-03 0.1841730E-03 0.4233973E+01 4.0918 14 Mn++ 0.7136518E-07 0.8646182E-07 0.4749896E-02 8.4937 15 HPO4-- 0.1211889E-08 0.1494651E-08 0.1434508E-03 6.7238 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3048835E-03 -.6935189E-04 -.2355316E-03 0.0000000E+00 2 H2O 0.5550801E+02 0.5550788E+02 0.1327579E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2603657E-04 0.2550426E-04 0.5323068E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5320975E-06 0.2093559E-09 -.5323068E-06 0.0000000E+00 7 Al+++ 0.6260624E-04 0.3332970E-05 0.5927327E-04 0.0000000E+00 8 H4SiO4 0.1999254E-03 0.1850521E-03 0.1487331E-04 0.0000000E+00 9 Ca++ 0.3655380E-04 0.3636693E-04 0.1868714E-06 0.0000000E+00 10 Mg++ 0.1523810E-04 0.1241714E-06 0.1511392E-04 0.0000000E+00 11 Fe++ 0.1368976E-04 0.2821772E-08 0.1368694E-04 0.0000000E+00 12 K+ 0.4076433E-05 0.4076433E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1841717E-03 0.1841717E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3329010E-06 0.8646118E-07 0.2464399E-06 0.0000000E+00 15 HPO4-- 0.1136175E-06 0.1494640E-08 0.1121228E-06 0.0000000E+00 Chg. balance for solid moles: -.2507E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0192000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3737E-07 -7.427 0.1877E-04 -4.726 0.2942 0.5966E-05 clinochlore 0.3023E-05 -5.520 0.1680E-02 -2.775 26.33 0.6391E-03 daphnite 0.1886E-05 -5.725 0.1345E-02 -2.871 21.09 0.4077E-03 chlorite-Mn 0.4929E-07 -7.307 0.3494E-04 -4.457 0.5477 0.1114E-04 diaspore 0.4936E-04 -4.307 0.2961E-02 -2.529 46.41 0.8815E-03 hematite 0.2129E-05 -5.672 0.3400E-03 -3.468 5.329 0.6445E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3804E+00 0.3804E+00 1.0000 -0.420 chlorite-Mn 0.9942E-02 0.9942E-02 1.0000 -2.003 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.006380 g Volume = 0.002010 cm3 Porosity: 99.8005% V(tot) - V(min): 0.10057E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0192000 g log = -1.7167 Original solution: 1000.0103000 g Original solution / Rock added: 52083.87 (Water/Rock Ratio), log = 4.7167 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3760E-04 1.0073 0.3984E-04 0.3955E-04 CH4,gas 0.9897E-14 1.0129 0.1055E-13 0.1041E-13 H2,gas 0.1229E-05 1.0006 0.1294E-05 0.1293E-05 H2S,gas 0.1518E-10 0.9959 0.1590E-10 0.1597E-10 S2,gas 0.5380E-29 1.0000 0.5659E-29 0.5659E-29 CO,gas 0.1269E-13 1.0000 0.1335E-13 0.1335E-13 SO3,gas 0.1638E-35 1.0000 0.1723E-35 0.1723E-35 SO2,gas 0.8019E-19 1.0000 0.8436E-19 0.8436E-19 HCl,gas 0.5971E-15 1.0000 0.6281E-15 0.6281E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.76 -6.40 -2.133 0.10927E+05 -4.400 3 CH4,gas 4.81 -11.17 -15.98 -3.994 0.27280E+05 -13.977 4 H2,gas 8.29 0.40 -7.89 -4.508 0.13469E+05 -5.888 5 H2S,gas -5.94 -18.74 -12.80 -6.399 0.21853E+05 -10.799 6 S2,gas -7.03 -38.28 -31.25 -4.807 0.53354E+05 -29.247 7 CO,gas 3.51 -12.36 -15.87 -4.884 0.27105E+05 -13.874 8 SO3,gas 17.43 -20.34 -37.76 -9.441 0.64480E+05 -35.764 9 SO2,gas 1.14 -19.94 -21.07 -5.620 0.35983E+05 -19.074 10 HCl,gas 5.48 -11.72 -17.20 -8.601 0.29372E+05 -15.202 11 acmite 7.74 2.87 -4.87 -0.506 0.83191E+04 16 albite -0.33 -4.30 -3.97 -0.306 0.67817E+04 19 spessartine 24.55 19.99 -4.56 -0.228 0.77939E+04 20 analcite 3.37 -0.54 -3.91 -0.434 0.66730E+04 21 andalusite 5.06 2.03 -3.03 -0.303 0.51785E+04 22 andradite 39.09 34.90 -4.19 -0.218 0.71566E+04 23 grossular 32.83 28.09 -4.74 -0.237 0.80887E+04 24 anhydrite -5.28 -9.14 -3.86 -1.930 0.65925E+04 29 anorthite 12.80 9.46 -3.34 -0.257 0.56948E+04 35 aragonite 0.99 -1.57 -2.55 -0.851 0.43600E+04 36 brucite 12.58 8.72 -3.85 -0.771 0.65801E+04 37 calcite 0.83 -1.57 -2.40 -0.800 0.40987E+04 40 carpholite-Mg 8.65 6.99 -1.66 -0.111 0.28355E+04 41 carpholite-Fe 6.78 4.77 -2.02 -0.135 0.34454E+04 50 chloritoid-Mg 13.26 10.75 -2.51 -0.167 0.42838E+04 51 chloritoid-Fe 9.24 8.53 -0.71 -0.047 0.12139E+04 52 chloritoid-Mn 11.46 10.52 -0.94 -0.063 0.16050E+04 54 coesite -2.37 -3.76 -1.39 -0.464 0.23790E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.76 -1.21 -0.404 0.20719E+04 67 diopside 16.22 12.39 -3.82 -0.382 0.65265E+04 68 hedenbergite 14.24 10.17 -4.08 -0.408 0.69596E+04 75 epidote 24.78 23.19 -1.58 -0.077 0.26996E+04 76 clinozoisite 22.92 19.79 -3.13 -0.142 0.53439E+04 77 epidote-Fe 29.94 26.60 -3.34 -0.174 0.57028E+04 78 fayalite 14.08 9.23 -4.85 -0.692 0.82731E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.97 -4.22 -0.352 0.72140E+04 91 heulandite -5.71 -9.35 -3.64 -0.166 0.62216E+04 95 jadeite 4.25 -0.54 -4.79 -0.479 0.81760E+04 98 kaolinite -1.27 -1.73 -0.46 -0.042 0.78544E+03 99 kyanite 4.93 2.03 -2.90 -0.290 0.49553E+04 101 laumontite 2.97 1.94 -1.04 -0.069 0.17714E+04 102 lawsonite 9.68 9.46 -0.22 -0.014 0.36871E+03 105 lizardite 23.29 18.64 -4.64 -0.387 0.79296E+04 106 magnesite 0.71 -4.04 -4.75 -1.583 0.81092E+04 107 magnetite 20.13 19.10 -1.04 -0.085 0.17706E+04 110 magnesioferrite 26.26 21.32 -4.94 -0.403 0.84294E+04 113 margarite 17.45 15.25 -2.20 -0.088 0.37516E+04 116 microcline -2.43 -5.96 -3.52 -0.271 0.60160E+04 120 muscovite 2.68 -0.16 -2.84 -0.167 0.48529E+04 121 paragonite 4.34 1.49 -2.84 -0.167 0.48571E+04 136 prehnite 19.47 16.90 -2.57 -0.151 0.43899E+04 137 prehnite-Fe 22.59 20.30 -2.29 -0.138 0.39079E+04 138 pumpellyite-Fe 46.47 43.18 -3.29 -0.073 0.56100E+04 139 pumpellyite-Mg 49.19 45.41 -3.78 -0.084 0.64617E+04 145 pyroxmangite 7.42 4.73 -2.68 -0.537 0.45846E+04 146 pyrophyllite -6.10 -9.26 -3.16 -0.198 0.53964E+04 147 quartz -2.98 -3.76 -0.78 -0.260 0.13330E+04 152 rhodochrosite -0.96 -4.27 -3.31 -1.104 0.56528E+04 153 rhodonite 7.46 4.73 -2.73 -0.546 0.46638E+04 154 sanidine -1.22 -5.96 -4.73 -0.364 0.80837E+04 156 siderite -2.59 -6.26 -3.68 -1.226 0.62784E+04 157 sillimanite 5.32 2.03 -3.29 -0.329 0.56207E+04 164 stilbite -7.41 -9.35 -1.95 -0.093 0.33211E+04 165 stilpnomelane-Fe 13.18 9.40 -3.78 -0.113 0.64527E+04 169 sudoite 21.22 17.74 -3.47 -0.112 0.59318E+04 175 tephroite 18.11 13.22 -4.89 -0.698 0.83464E+04 178 topaz-H 4.67 2.03 -2.64 -0.240 0.45044E+04 179 tridymite -2.61 -3.76 -1.15 -0.383 0.19603E+04 188 wairakite 4.06 1.94 -2.12 -0.125 0.36222E+04 189 walstromite 11.53 7.43 -4.09 -0.819 0.69920E+04 190 wollastonite 10.48 7.43 -3.05 -0.610 0.52059E+04 191 pseudo-wollastonite 11.02 7.43 -3.59 -0.717 0.61245E+04 192 zoisite 22.96 19.79 -3.17 -0.144 0.54164E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.21 -3.65 -0.226 0.62393E+04 195 beidellite-H -2.24 -7.06 -4.82 -0.308 0.82300E+04 196 beidellite-K -1.44 -6.26 -4.82 -0.295 0.82333E+04 197 beidellite-Mg -1.71 -5.62 -3.91 -0.242 0.66846E+04 198 beidellite-Na -1.26 -5.71 -4.45 -0.273 0.76047E+04 200 chalcedony -2.79 -3.76 -0.97 -0.323 0.16533E+04 202 montmorillonite-Ca -2.21 -5.49 -3.27 -0.203 0.55908E+04 203 montmorillonite-K -2.16 -6.53 -4.37 -0.268 0.74625E+04 204 montmorillonite-Mg -2.40 -5.90 -3.49 -0.216 0.59671E+04 205 montmorillonite-Na -1.96 -5.99 -4.02 -0.246 0.68721E+04 206 nontronite-Ca 3.28 1.59 -1.69 -0.110 0.28823E+04 207 nontronite-H 2.60 -0.26 -2.85 -0.191 0.48686E+04 208 nontronite-K 3.40 0.55 -2.86 -0.183 0.48754E+04 209 nontronite-Mg 3.14 1.18 -1.96 -0.127 0.33392E+04 210 nontronite-Na 3.58 1.09 -2.49 -0.160 0.42485E+04 215 gypsum -4.92 -9.14 -4.22 -1.054 0.71992E+04 225 tobermorite 9.84 5.56 -4.28 -1.167 0.73007E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.50 -3.33 -0.832 0.56791E+04 241 silica-amorphous -2.08 -3.76 -1.68 -0.561 0.28735E+04 243 an20ab80 2.08 -1.55 -3.63 -0.279 0.61927E+04 244 an25ab75 2.71 -0.86 -3.57 -0.275 0.60934E+04 245 an30ab70 3.34 -0.17 -3.52 -0.270 0.60024E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0192000 g New total amount of reactant added: 0.0196000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0196000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3103130E-03 Osmotic coef. = 0.9895 True ionic strength = .3240355E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14605E-07 -7.8355 0.14007E-07 -7.8536 0.95905E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13229E-03 -3.8785 0.95892E+00 -0.0182 4 SO4-- 0.25275E-04 -4.5973 0.22553E-04 -4.6468 0.89234E+00 -0.0495 5 HCO3- 0.12597E-04 -4.8997 0.12080E-04 -4.9179 0.95895E+00 -0.0182 6 HS- 0.11779E-10 -10.9289 0.11295E-10 -10.9471 0.95892E+00 -0.0182 7 Al+++ 0.27347E-20 -20.5631 0.21635E-20 -20.6648 0.79112E+00 -0.1018 8 H4SiO4 0.17607E-03 -3.7543 0.17607E-03 -3.7543 0.10000E+01 0.0000 9 Ca++ 0.36366E-04 -4.4393 0.32446E-04 -4.4888 0.89218E+00 -0.0495 10 Mg++ 0.11487E-06 -6.9398 0.10248E-06 -6.9894 0.89209E+00 -0.0496 11 Fe++ 0.68433E-09 -9.1647 0.61049E-09 -9.2143 0.89211E+00 -0.0496 12 K+ 0.41598E-05 -5.3809 0.39891E-05 -5.3991 0.95896E+00 -0.0182 13 Na+ 0.18463E-03 -3.7337 0.17704E-03 -3.7519 0.95891E+00 -0.0182 14 Mn++ 0.68927E-07 -7.1616 0.61491E-07 -7.2112 0.89213E+00 -0.0496 15 HPO4-- 0.11564E-08 -8.9369 0.10319E-08 -8.9864 0.89234E+00 -0.0495 16 HSiO3- 0.12789E-04 -4.8932 0.12264E-04 -4.9114 0.95892E+00 -0.0182 17 Ca(HSiO3)+ 0.92967E-08 -8.0317 0.89152E-08 -8.0499 0.95896E+00 -0.0182 18 Mg(HSiO3)+ 0.36542E-10 -10.4372 0.35042E-10 -10.4554 0.95896E+00 -0.0182 19 NaHSiO3,aq 0.34484E-07 -7.4624 0.34484E-07 -7.4624 0.10000E+01 0.0000 20 AlO+ 0.14844E-11 -11.8284 0.14235E-11 -11.8466 0.95896E+00 -0.0182 21 AlOH+2 0.11196E-15 -15.9509 0.99885E-16 -16.0005 0.89215E+00 -0.0496 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.33808E-05 -5.4710 0.32417E-05 -5.4892 0.95888E+00 -0.0182 24 CH4,aq 0.59373E-17 -17.2264 0.59367E-17 -17.2265 0.99990E+00 0.0000 29 CO,aq 0.80916E-17 -17.0920 0.80916E-17 -17.0920 0.10000E+01 0.0000 30 CO2,aq 0.34120E-06 -6.4670 0.34117E-06 -6.4670 0.99990E+00 0.0000 31 CO3-2 0.89365E-07 -7.0488 0.79740E-07 -7.0983 0.89229E+00 -0.0495 32 CaCO3,aq 0.31687E-07 -7.4991 0.31687E-07 -7.4991 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10299E-07 -7.9872 0.98761E-08 -8.0054 0.95896E+00 -0.0182 34 CaCl+ 0.71325E-08 -8.1468 0.68397E-08 -8.1650 0.95896E+00 -0.0182 35 CaCl2,aq 0.21068E-12 -12.6764 0.21068E-12 -12.6764 0.10000E+01 0.0000 36 CaOH+ 0.17032E-06 -6.7687 0.16333E-06 -6.7869 0.95896E+00 -0.0182 37 CaSO4,aq 0.22800E-06 -6.6421 0.22800E-06 -6.6421 0.10000E+01 0.0000 38 HCl,aq 0.34856E-12 -12.4577 0.34856E-12 -12.4577 0.10000E+01 0.0000 43 FeCl+ 0.13117E-12 -12.8822 0.12579E-12 -12.9004 0.95896E+00 -0.0182 46 FeO,aq 0.12304E-09 -9.9099 0.12304E-09 -9.9099 0.10000E+01 0.0000 47 FeOH+ 0.15067E-08 -8.8220 0.14449E-08 -8.8402 0.95896E+00 -0.0182 48 HFeO2- 0.98529E-10 -10.0064 0.94481E-10 -10.0247 0.95892E+00 -0.0182 49 FeO+ 0.12083E-12 -12.9178 0.11587E-12 -12.9360 0.95896E+00 -0.0182 50 FeOH+2 0.33853E-18 -18.4704 0.30202E-18 -18.5200 0.89215E+00 -0.0496 51 FeO2- 0.12104E-09 -9.9171 0.11607E-09 -9.9353 0.95892E+00 -0.0182 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.92095E-09 -9.0358 0.92087E-09 -9.0358 0.99990E+00 0.0000 54 KCl,aq 0.93441E-11 -11.0295 0.93441E-11 -11.0295 0.10000E+01 0.0000 55 KHSO4,aq 0.33723E-17 -17.4721 0.33723E-17 -17.4721 0.10000E+01 0.0000 56 KOH,aq 0.12415E-09 -9.9061 0.12415E-09 -9.9061 0.10000E+01 0.0000 57 KSO4- 0.14455E-08 -8.8400 0.13861E-08 -8.8582 0.95892E+00 -0.0182 58 MgCO3,aq 0.25008E-10 -10.6019 0.25008E-10 -10.6019 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.33169E-10 -10.4793 0.31808E-10 -10.4975 0.95896E+00 -0.0182 60 MgCl+ 0.20451E-10 -10.6893 0.19611E-10 -10.7075 0.95896E+00 -0.0182 61 MgOH+ 0.29802E-08 -8.5258 0.28579E-08 -8.5440 0.95896E+00 -0.0182 63 MnO,aq 0.33084E-09 -9.4804 0.33084E-09 -9.4804 0.10000E+01 0.0000 64 MnOH+ 0.14098E-07 -7.8508 0.13520E-07 -7.8690 0.95896E+00 -0.0182 65 MnO2-2 0.65353E-16 -16.1847 0.58314E-16 -16.2342 0.89229E+00 -0.0495 66 HMnO2- 0.18456E-12 -12.7339 0.17697E-12 -12.7521 0.95892E+00 -0.0182 69 MnCl+ 0.51341E-10 -10.2895 0.49234E-10 -10.3077 0.95896E+00 -0.0182 70 MnSO4,aq 0.39303E-09 -9.4056 0.39303E-09 -9.4056 0.10000E+01 0.0000 71 NaCl,aq 0.76476E-08 -8.1165 0.76476E-08 -8.1165 0.10000E+01 0.0000 72 NaOH,aq 0.55537E-08 -8.2554 0.55537E-08 -8.2554 0.10000E+01 0.0000 74 OH- 0.44659E-04 -4.3501 0.42823E-04 -4.3683 0.95888E+00 -0.0182 82 H3PO4,aq 0.13034E-14 -14.8849 0.13034E-14 -14.8849 0.10000E+01 0.0000 83 H2PO4- 0.26426E-09 -9.5780 0.25341E-09 -9.5962 0.95894E+00 -0.0182 84 PO4-3 0.81224E-13 -13.0903 0.64334E-13 -13.1916 0.79206E+00 -0.1012 88 HP2O7-3 0.92996E-19 -19.0315 0.73572E-19 -19.1333 0.79113E+00 -0.1018 90 H2S,aq 0.47542E-12 -12.3229 0.47537E-12 -12.3230 0.99990E+00 0.0000 96 SO2,aq 0.17073E-19 -19.7677 0.17073E-19 -19.7677 0.10000E+01 0.0000 97 SO3-2 0.31725E-14 -14.4986 0.28318E-14 -14.5479 0.89260E+00 -0.0493 98 HSO3- 0.24208E-14 -14.6160 0.23213E-14 -14.6343 0.95892E+00 -0.0182 99 HSO4- 0.30566E-09 -9.5148 0.29312E-09 -9.5329 0.95898E+00 -0.0182 101 S2O3-2 0.14161E-18 -18.8489 0.12636E-18 -18.8984 0.89229E+00 -0.0495 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1460541E-07 -.7103802E-04 -.7159987E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999678E+06 0.0000 3 Cl- 0.1379604E-03 0.1379752E-03 0.4891486E+01 3.9752 4 SO4-- 0.2527451E-04 0.2550446E-04 0.2449924E+01 11.0605 5 HCO3- 0.1259749E-04 0.1307010E-04 0.7974764E+00 2.9357 6 HS- 0.1177912E-10 0.2019154E-09 0.6677541E-05 -3.0935 7 Al+++ 0.2734716E-20 0.3401116E-05 0.9176440E-01 2.8961 8 H4SiO4 0.1760677E-03 0.1889007E-03 0.1815571E+02 -3.7543 9 Ca++ 0.3636646E-04 0.3682319E-04 0.1475755E+01 11.2184 10 Mg++ 0.1148718E-06 0.1179672E-06 0.2867930E-02 8.7179 11 Fe++ 0.6843265E-09 0.2737404E-08 0.1528711E-03 6.4930 12 K+ 0.4159811E-05 0.4161390E-05 0.1627137E+00 2.4545 13 Na+ 0.1846275E-03 0.1846752E-03 0.4245515E+01 4.1017 14 Mn++ 0.6892654E-07 0.8380037E-07 0.4603684E-02 8.4961 15 HPO4-- 0.1156375E-08 0.1420715E-08 0.1363546E-03 6.7209 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3115069E-03 -.7103749E-04 -.2404694E-03 0.0000000E+00 2 H2O 0.5550800E+02 0.5550787E+02 0.1355317E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2604765E-04 0.2550427E-04 0.5433847E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5431828E-06 0.2019139E-09 -.5433847E-06 0.0000000E+00 7 Al+++ 0.6391054E-04 0.3401091E-05 0.6050945E-04 0.0000000E+00 8 H4SiO4 0.2040905E-03 0.1888993E-03 0.1519127E-04 0.0000000E+00 9 Ca++ 0.3701386E-04 0.3682292E-04 0.1909397E-06 0.0000000E+00 10 Mg++ 0.1555556E-04 0.1179663E-06 0.1543759E-04 0.0000000E+00 11 Fe++ 0.1397497E-04 0.2737384E-08 0.1397223E-04 0.0000000E+00 12 K+ 0.4161359E-05 0.4161359E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1846738E-03 0.1846738E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3398365E-06 0.8379974E-07 0.2560367E-06 0.0000000E+00 15 HPO4-- 0.1159845E-06 0.1420704E-08 0.1145638E-06 0.0000000E+00 Chg. balance for solid moles: 0.1281E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0196000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3819E-07 -7.418 0.1918E-04 -4.717 0.2945 0.6096E-05 clinochlore 0.3088E-05 -5.510 0.1716E-02 -2.765 26.34 0.6528E-03 daphnite 0.1925E-05 -5.716 0.1374E-02 -2.862 21.08 0.4162E-03 chlorite-Mn 0.5121E-07 -7.291 0.3630E-04 -4.440 0.5573 0.1157E-04 diaspore 0.5038E-04 -4.298 0.3022E-02 -2.520 46.39 0.8998E-03 hematite 0.2174E-05 -5.663 0.3471E-03 -3.460 5.328 0.6579E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3802E+00 0.3802E+00 1.0000 -0.420 chlorite-Mn 0.1011E-01 0.1011E-01 1.0000 -1.995 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.006515 g Volume = 0.002052 cm3 Porosity: 99.7964% V(tot) - V(min): 0.10058E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0196000 g log = -1.7077 Original solution: 1000.0103000 g Original solution / Rock added: 51020.93 (Water/Rock Ratio), log = 4.7077 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3685E-04 1.0073 0.3905E-04 0.3877E-04 CH4,gas 0.8811E-14 1.0129 0.9388E-14 0.9268E-14 H2,gas 0.1200E-05 1.0006 0.1263E-05 0.1262E-05 H2S,gas 0.1323E-10 0.9959 0.1386E-10 0.1392E-10 S2,gas 0.4290E-29 1.0000 0.4513E-29 0.4513E-29 CO,gas 0.1215E-13 1.0000 0.1278E-13 0.1278E-13 SO3,gas 0.1573E-35 1.0000 0.1654E-35 0.1654E-35 SO2,gas 0.7514E-19 1.0000 0.7905E-19 0.7905E-19 HCl,gas 0.5850E-15 1.0000 0.6154E-15 0.6154E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.77 -6.41 -2.136 0.10942E+05 -4.408 3 CH4,gas 4.81 -11.22 -16.03 -4.007 0.27366E+05 -14.027 4 H2,gas 8.29 0.39 -7.90 -4.513 0.13487E+05 -5.899 5 H2S,gas -5.94 -18.80 -12.86 -6.429 0.21955E+05 -10.858 6 S2,gas -7.03 -38.38 -31.35 -4.822 0.53522E+05 -29.346 7 CO,gas 3.51 -12.38 -15.89 -4.890 0.27138E+05 -13.894 8 SO3,gas 17.43 -20.35 -37.78 -9.445 0.64511E+05 -35.781 9 SO2,gas 1.14 -19.97 -21.10 -5.627 0.36031E+05 -19.102 10 HCl,gas 5.48 -11.73 -17.21 -8.605 0.29387E+05 -15.211 11 acmite 7.74 2.89 -4.85 -0.503 0.82736E+04 16 albite -0.33 -4.27 -3.94 -0.303 0.67220E+04 19 spessartine 24.55 20.02 -4.53 -0.227 0.77389E+04 20 analcite 3.37 -0.51 -3.88 -0.431 0.66275E+04 21 andalusite 5.06 2.04 -3.02 -0.302 0.51643E+04 22 andradite 39.09 34.99 -4.10 -0.213 0.69968E+04 23 grossular 32.83 28.18 -4.64 -0.232 0.79289E+04 24 anhydrite -5.28 -9.14 -3.86 -1.928 0.65838E+04 29 anorthite 12.80 9.50 -3.30 -0.254 0.56273E+04 35 aragonite 0.99 -1.55 -2.54 -0.846 0.43359E+04 36 brucite 12.58 8.72 -3.86 -0.772 0.65886E+04 37 calcite 0.83 -1.55 -2.39 -0.795 0.40745E+04 40 carpholite-Mg 8.65 7.00 -1.65 -0.110 0.28155E+04 41 carpholite-Fe 6.78 4.78 -2.01 -0.134 0.34258E+04 50 chloritoid-Mg 13.26 10.76 -2.51 -0.167 0.42780E+04 51 chloritoid-Fe 9.24 8.53 -0.71 -0.047 0.12086E+04 52 chloritoid-Mn 11.46 10.53 -0.93 -0.062 0.15867E+04 54 coesite -2.37 -3.75 -1.38 -0.462 0.23648E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.75 -1.21 -0.402 0.20577E+04 67 diopside 16.22 12.43 -3.79 -0.379 0.64675E+04 68 hedenbergite 14.24 10.20 -4.04 -0.404 0.69010E+04 75 epidote 24.78 23.26 -1.51 -0.073 0.25788E+04 76 clinozoisite 22.92 19.86 -3.06 -0.139 0.52231E+04 77 epidote-Fe 29.94 26.67 -3.27 -0.170 0.55820E+04 78 fayalite 14.08 9.23 -4.85 -0.692 0.82767E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.97 -4.22 -0.352 0.72123E+04 91 heulandite -5.71 -9.27 -3.56 -0.162 0.60829E+04 95 jadeite 4.25 -0.51 -4.76 -0.476 0.81305E+04 98 kaolinite -1.27 -1.72 -0.44 -0.040 0.75696E+03 99 kyanite 4.93 2.04 -2.89 -0.289 0.49411E+04 101 laumontite 2.97 1.99 -0.98 -0.065 0.16754E+04 102 lawsonite 9.68 9.50 -0.18 -0.012 0.30119E+03 105 lizardite 23.29 18.65 -4.64 -0.387 0.79267E+04 106 magnesite 0.71 -4.05 -4.76 -1.588 0.81326E+04 107 magnetite 20.13 19.09 -1.04 -0.085 0.17795E+04 110 magnesioferrite 26.26 21.32 -4.94 -0.403 0.84379E+04 113 margarite 17.45 15.29 -2.16 -0.086 0.36841E+04 116 microcline -2.43 -5.91 -3.48 -0.268 0.59430E+04 120 muscovite 2.68 -0.12 -2.80 -0.165 0.47799E+04 121 paragonite 4.34 1.53 -2.81 -0.165 0.47973E+04 136 prehnite 19.47 16.97 -2.50 -0.147 0.42691E+04 137 prehnite-Fe 22.59 20.37 -2.22 -0.133 0.37871E+04 138 pumpellyite-Fe 46.47 43.32 -3.15 -0.070 0.53773E+04 139 pumpellyite-Mg 49.19 45.55 -3.65 -0.081 0.62286E+04 145 pyroxmangite 7.42 4.74 -2.67 -0.535 0.45662E+04 146 pyrophyllite -6.10 -9.23 -3.13 -0.195 0.53394E+04 147 quartz -2.98 -3.75 -0.77 -0.257 0.13187E+04 152 rhodochrosite -0.96 -4.28 -3.32 -1.106 0.56636E+04 153 rhodonite 7.46 4.74 -2.72 -0.544 0.46454E+04 154 sanidine -1.22 -5.91 -4.69 -0.361 0.80107E+04 156 siderite -2.59 -6.28 -3.69 -1.230 0.63022E+04 157 sillimanite 5.32 2.04 -3.28 -0.328 0.56065E+04 164 stilbite -7.41 -9.27 -1.86 -0.089 0.31823E+04 165 stilpnomelane-Fe 13.18 9.45 -3.73 -0.111 0.63683E+04 169 sudoite 21.22 17.76 -3.46 -0.112 0.59061E+04 175 tephroite 18.11 13.24 -4.88 -0.696 0.83240E+04 178 topaz-H 4.67 2.04 -2.63 -0.239 0.44901E+04 179 tridymite -2.61 -3.75 -1.14 -0.380 0.19460E+04 188 wairakite 4.06 1.99 -2.07 -0.121 0.35262E+04 189 walstromite 11.53 7.46 -4.06 -0.813 0.69387E+04 190 wollastonite 10.48 7.46 -3.02 -0.604 0.51526E+04 191 pseudo-wollastonite 11.02 7.46 -3.56 -0.711 0.60713E+04 192 zoisite 22.96 19.86 -3.10 -0.141 0.52956E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.18 -3.62 -0.224 0.61806E+04 195 beidellite-H -2.24 -7.03 -4.79 -0.306 0.81777E+04 196 beidellite-K -1.44 -6.22 -4.79 -0.293 0.81710E+04 197 beidellite-Mg -1.71 -5.59 -3.89 -0.240 0.66337E+04 198 beidellite-Na -1.26 -5.68 -4.42 -0.271 0.75468E+04 200 chalcedony -2.79 -3.75 -0.96 -0.320 0.16390E+04 202 montmorillonite-Ca -2.21 -5.45 -3.24 -0.200 0.55302E+04 203 montmorillonite-K -2.16 -6.49 -4.33 -0.265 0.73984E+04 204 montmorillonite-Mg -2.40 -5.87 -3.46 -0.214 0.59144E+04 205 montmorillonite-Na -1.96 -5.95 -3.99 -0.244 0.68123E+04 206 nontronite-Ca 3.28 1.63 -1.65 -0.107 0.28235E+04 207 nontronite-H 2.60 -0.23 -2.82 -0.189 0.48164E+04 208 nontronite-K 3.40 0.58 -2.82 -0.181 0.48131E+04 209 nontronite-Mg 3.14 1.21 -1.93 -0.125 0.32883E+04 210 nontronite-Na 3.58 1.13 -2.45 -0.158 0.41906E+04 215 gypsum -4.92 -9.14 -4.21 -1.053 0.71906E+04 225 tobermorite 9.84 5.59 -4.25 -1.159 0.72540E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.49 -3.33 -0.833 0.56880E+04 241 silica-amorphous -2.08 -3.75 -1.67 -0.558 0.28592E+04 243 an20ab80 2.08 -1.51 -3.59 -0.276 0.61314E+04 244 an25ab75 2.71 -0.82 -3.53 -0.272 0.60317E+04 245 an30ab70 3.34 -0.14 -3.48 -0.268 0.59403E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0196000 g New total amount of reactant added: 0.0200000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1649E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0200000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3118062E-03 Osmotic coef. = 0.9895 True ionic strength = .3259400E-03 Chg. balance for total moles = 0.1649E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14321E-07 -7.8440 0.13733E-07 -7.8622 0.95899E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13228E-03 -3.8785 0.95885E+00 -0.0182 4 SO4-- 0.25272E-04 -4.5974 0.22545E-04 -4.6470 0.89209E+00 -0.0496 5 HCO3- 0.12601E-04 -4.8996 0.12083E-04 -4.9178 0.95888E+00 -0.0182 6 HS- 0.10509E-10 -10.9784 0.10077E-10 -10.9967 0.95885E+00 -0.0182 7 Al+++ 0.25790E-20 -20.5886 0.20390E-20 -20.6906 0.79064E+00 -0.1020 8 H4SiO4 0.17941E-03 -3.7462 0.17941E-03 -3.7462 0.10000E+01 0.0000 9 Ca++ 0.36813E-04 -4.4340 0.32835E-04 -4.4837 0.89194E+00 -0.0497 10 Mg++ 0.10922E-06 -6.9617 0.97404E-07 -7.0114 0.89184E+00 -0.0497 11 Fe++ 0.65031E-09 -9.1869 0.57999E-09 -9.2366 0.89186E+00 -0.0497 12 K+ 0.42447E-05 -5.3722 0.40702E-05 -5.3904 0.95889E+00 -0.0182 13 Na+ 0.18513E-03 -3.7325 0.17751E-03 -3.7508 0.95885E+00 -0.0183 14 Mn++ 0.66574E-07 -7.1767 0.59376E-07 -7.2264 0.89188E+00 -0.0497 15 HPO4-- 0.11045E-08 -8.9568 0.98529E-09 -9.0064 0.89209E+00 -0.0496 16 HSiO3- 0.13293E-04 -4.8764 0.12746E-04 -4.8946 0.95885E+00 -0.0182 17 Ca(HSiO3)+ 0.97786E-08 -8.0097 0.93767E-08 -8.0280 0.95889E+00 -0.0182 18 Mg(HSiO3)+ 0.36101E-10 -10.4425 0.34617E-10 -10.4607 0.95889E+00 -0.0182 19 NaHSiO3,aq 0.35934E-07 -7.4445 0.35934E-07 -7.4445 0.10000E+01 0.0000 20 AlO+ 0.14555E-11 -11.8370 0.13957E-11 -11.8552 0.95889E+00 -0.0182 21 AlOH+2 0.10765E-15 -15.9680 0.96016E-16 -16.0177 0.89190E+00 -0.0497 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.34485E-05 -5.4624 0.33064E-05 -5.4806 0.95881E+00 -0.0183 24 CH4,aq 0.53001E-17 -17.2757 0.52996E-17 -17.2758 0.99990E+00 0.0000 29 CO,aq 0.77508E-17 -17.1107 0.77508E-17 -17.1107 0.10000E+01 0.0000 30 CO2,aq 0.33460E-06 -6.4755 0.33457E-06 -6.4755 0.99990E+00 0.0000 31 CO3-2 0.91193E-07 -7.0400 0.81348E-07 -7.0897 0.89204E+00 -0.0496 32 CaCO3,aq 0.32714E-07 -7.4853 0.32714E-07 -7.4853 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10425E-07 -7.9819 0.99967E-08 -8.0001 0.95889E+00 -0.0182 34 CaCl+ 0.72180E-08 -8.1416 0.69213E-08 -8.1598 0.95889E+00 -0.0182 35 CaCl2,aq 0.21318E-12 -12.6713 0.21318E-12 -12.6713 0.10000E+01 0.0000 36 CaOH+ 0.17581E-06 -6.7550 0.16859E-06 -6.7732 0.95889E+00 -0.0182 37 CaSO4,aq 0.23064E-06 -6.6371 0.23064E-06 -6.6371 0.10000E+01 0.0000 38 HCl,aq 0.34172E-12 -12.4663 0.34172E-12 -12.4663 0.10000E+01 0.0000 43 FeCl+ 0.12462E-12 -12.9044 0.11950E-12 -12.9226 0.95889E+00 -0.0182 46 FeO,aq 0.12160E-09 -9.9151 0.12160E-09 -9.9151 0.10000E+01 0.0000 47 FeOH+ 0.14601E-08 -8.8356 0.14001E-08 -8.8538 0.95889E+00 -0.0182 48 HFeO2- 0.99328E-10 -10.0029 0.95240E-10 -10.0212 0.95885E+00 -0.0182 49 FeO+ 0.11847E-12 -12.9264 0.11360E-12 -12.9446 0.95889E+00 -0.0182 50 FeOH+2 0.32550E-18 -18.4874 0.29032E-18 -18.5371 0.89190E+00 -0.0497 51 FeO2- 0.12346E-09 -9.9085 0.11838E-09 -9.9267 0.95885E+00 -0.0182 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.89957E-09 -9.0460 0.89948E-09 -9.0460 0.99990E+00 0.0000 54 KCl,aq 0.95335E-11 -11.0207 0.95335E-11 -11.0207 0.10000E+01 0.0000 55 KHSO4,aq 0.33723E-17 -17.4721 0.33723E-17 -17.4721 0.10000E+01 0.0000 56 KOH,aq 0.12920E-09 -9.8887 0.12920E-09 -9.8887 0.10000E+01 0.0000 57 KSO4- 0.14744E-08 -8.8314 0.14137E-08 -8.8496 0.95885E+00 -0.0182 58 MgCO3,aq 0.24250E-10 -10.6153 0.24250E-10 -10.6153 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.31537E-10 -10.5012 0.30240E-10 -10.5194 0.95889E+00 -0.0182 60 MgCl+ 0.19438E-10 -10.7113 0.18639E-10 -10.7296 0.95889E+00 -0.0182 61 MgOH+ 0.28894E-08 -8.5392 0.27706E-08 -8.5574 0.95889E+00 -0.0182 63 MnO,aq 0.33233E-09 -9.4784 0.33233E-09 -9.4784 0.10000E+01 0.0000 64 MnOH+ 0.13886E-07 -7.8574 0.13315E-07 -7.8756 0.95889E+00 -0.0182 65 MnO2-2 0.68312E-16 -16.1655 0.60938E-16 -16.2151 0.89204E+00 -0.0496 66 HMnO2- 0.18910E-12 -12.7233 0.18132E-12 -12.7416 0.95885E+00 -0.0182 69 MnCl+ 0.49575E-10 -10.3047 0.47537E-10 -10.3230 0.95889E+00 -0.0182 70 MnSO4,aq 0.37937E-09 -9.4209 0.37937E-09 -9.4209 0.10000E+01 0.0000 71 NaCl,aq 0.76673E-08 -8.1154 0.76673E-08 -8.1154 0.10000E+01 0.0000 72 NaOH,aq 0.56795E-08 -8.2457 0.56795E-08 -8.2457 0.10000E+01 0.0000 74 OH- 0.45553E-04 -4.3415 0.43677E-04 -4.3597 0.95881E+00 -0.0183 82 H3PO4,aq 0.11964E-14 -14.9221 0.11964E-14 -14.9221 0.10000E+01 0.0000 83 H2PO4- 0.24741E-09 -9.6066 0.23723E-09 -9.6248 0.95887E+00 -0.0182 84 PO4-3 0.79152E-13 -13.1015 0.62655E-13 -13.2030 0.79157E+00 -0.1015 88 HP2O7-3 0.83181E-19 -19.0800 0.65767E-19 -19.1820 0.79064E+00 -0.1020 90 H2S,aq 0.41585E-12 -12.3811 0.41581E-12 -12.3811 0.99990E+00 0.0000 96 SO2,aq 0.16024E-19 -19.7952 0.16024E-19 -19.7952 0.10000E+01 0.0000 97 SO3-2 0.30985E-14 -14.5088 0.27650E-14 -14.5583 0.89236E+00 -0.0495 98 HSO3- 0.23176E-14 -14.6350 0.22222E-14 -14.6532 0.95885E+00 -0.0182 99 HSO4- 0.29959E-09 -9.5235 0.28728E-09 -9.5417 0.95892E+00 -0.0182 101 S2O3-2 0.12385E-18 -18.9071 0.11048E-18 -18.9567 0.89204E+00 -0.0496 Charge balance for all species = 0.1649E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1432072E-07 -.7272342E-04 -.7329857E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999674E+06 0.0000 3 Cl- 0.1379603E-03 0.1379752E-03 0.4891484E+01 3.9837 4 SO4-- 0.2527186E-04 0.2550447E-04 0.2449924E+01 11.0775 5 HCO3- 0.1260111E-04 0.1307010E-04 0.7974762E+00 2.9444 6 HS- 0.1050941E-10 0.1949363E-09 0.6446732E-05 -3.1344 7 Al+++ 0.2578966E-20 0.3468798E-05 0.9359046E-01 2.8961 8 H4SiO4 0.1794096E-03 0.1927483E-03 0.1852550E+02 -3.7462 9 Ca++ 0.3681261E-04 0.3727920E-04 0.1494029E+01 11.2408 10 Mg++ 0.1092166E-06 0.1122173E-06 0.2728143E-02 8.7130 11 Fe++ 0.6503146E-09 0.2658543E-08 0.1484670E-03 6.4879 12 K+ 0.4244704E-05 0.4246317E-05 0.1660343E+00 2.4718 13 Na+ 0.1851280E-03 0.1851773E-03 0.4257057E+01 4.1114 14 Mn++ 0.6657446E-07 0.8122204E-07 0.4462038E-02 8.4981 15 HPO4-- 0.1104468E-08 0.1351957E-08 0.1297554E-03 6.7180 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3181303E-03 -.7272286E-04 -.2454074E-03 0.0000000E+00 2 H2O 0.5550800E+02 0.5550786E+02 0.1383061E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2605874E-04 0.2550428E-04 0.5544631E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5542682E-06 0.1949348E-09 -.5544631E-06 0.0000000E+00 7 Al+++ 0.6521483E-04 0.3468771E-05 0.6174606E-04 0.0000000E+00 8 H4SiO4 0.2082557E-03 0.1927468E-03 0.1550890E-04 0.0000000E+00 9 Ca++ 0.3747391E-04 0.3727891E-04 0.1949993E-06 0.0000000E+00 10 Mg++ 0.1587302E-04 0.1122165E-06 0.1576080E-04 0.0000000E+00 11 Fe++ 0.1426017E-04 0.2658522E-08 0.1425751E-04 0.0000000E+00 12 K+ 0.4246285E-05 0.4246285E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1851759E-03 0.1851759E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3467719E-06 0.8122142E-07 0.2655505E-06 0.0000000E+00 15 HPO4-- 0.1183515E-06 0.1351946E-08 0.1169996E-06 0.0000000E+00 Chg. balance for solid moles: 0.1879E-20 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0200000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3900E-07 -7.409 0.1959E-04 -4.708 0.2946 0.6225E-05 clinochlore 0.3152E-05 -5.501 0.1752E-02 -2.756 26.35 0.6664E-03 daphnite 0.1964E-05 -5.707 0.1402E-02 -2.853 21.08 0.4247E-03 chlorite-Mn 0.5311E-07 -7.275 0.3765E-04 -4.424 0.5663 0.1200E-04 diaspore 0.5141E-04 -4.289 0.3084E-02 -2.511 46.38 0.9181E-03 hematite 0.2218E-05 -5.654 0.3542E-03 -3.451 5.327 0.6713E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3800E+00 0.3800E+00 1.0000 -0.420 chlorite-Mn 0.1027E-01 0.1027E-01 1.0000 -1.988 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.006649 g Volume = 0.002095 cm3 Porosity: 99.7922% V(tot) - V(min): 0.10059E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0200000 g log = -1.6990 Original solution: 1000.0103000 g Original solution / Rock added: 50000.52 (Water/Rock Ratio), log = 4.6990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3614E-04 1.0073 0.3830E-04 0.3802E-04 CH4,gas 0.7865E-14 1.0129 0.8381E-14 0.8274E-14 H2,gas 0.1172E-05 1.0006 0.1234E-05 0.1233E-05 H2S,gas 0.1158E-10 0.9959 0.1213E-10 0.1218E-10 S2,gas 0.3440E-29 1.0000 0.3619E-29 0.3619E-29 CO,gas 0.1163E-13 1.0000 0.1224E-13 0.1224E-13 SO3,gas 0.1511E-35 1.0000 0.1590E-35 0.1590E-35 SO2,gas 0.7053E-19 1.0000 0.7419E-19 0.7419E-19 HCl,gas 0.5736E-15 1.0000 0.6034E-15 0.6034E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.78 -6.42 -2.139 0.10957E+05 -4.417 3 CH4,gas 4.81 -11.27 -16.08 -4.019 0.27451E+05 -14.077 4 H2,gas 8.29 0.38 -7.91 -4.519 0.13504E+05 -5.909 5 H2S,gas -5.94 -18.86 -12.92 -6.458 0.22054E+05 -10.916 6 S2,gas -7.03 -38.47 -31.44 -4.837 0.53685E+05 -29.441 7 CO,gas 3.51 -12.40 -15.91 -4.896 0.27170E+05 -13.912 8 SO3,gas 17.43 -20.37 -37.80 -9.450 0.64540E+05 -35.799 9 SO2,gas 1.14 -19.99 -21.13 -5.635 0.36078E+05 -19.130 10 HCl,gas 5.48 -11.74 -17.22 -8.610 0.29402E+05 -15.219 11 acmite 7.74 2.92 -4.82 -0.501 0.82291E+04 15 albite-high 0.75 -4.23 -4.98 -0.383 0.85042E+04 16 albite -0.33 -4.23 -3.90 -0.300 0.66635E+04 19 spessartine 24.55 20.05 -4.50 -0.225 0.76871E+04 20 analcite 3.37 -0.48 -3.86 -0.428 0.65830E+04 21 andalusite 5.06 2.05 -3.02 -0.302 0.51503E+04 22 andradite 39.09 35.08 -4.01 -0.208 0.68406E+04 23 grossular 32.83 28.28 -4.55 -0.228 0.77727E+04 24 anhydrite -5.28 -9.13 -3.85 -1.925 0.65753E+04 29 anorthite 12.80 9.54 -3.26 -0.251 0.55613E+04 35 aragonite 0.99 -1.54 -2.53 -0.842 0.43122E+04 36 brucite 12.58 8.71 -3.86 -0.773 0.65970E+04 37 calcite 0.83 -1.54 -2.37 -0.791 0.40509E+04 40 carpholite-Mg 8.65 7.01 -1.64 -0.109 0.27960E+04 41 carpholite-Fe 6.78 4.79 -2.00 -0.133 0.34067E+04 50 chloritoid-Mg 13.26 10.76 -2.50 -0.167 0.42724E+04 51 chloritoid-Fe 9.24 8.53 -0.70 -0.047 0.12034E+04 52 chloritoid-Mn 11.46 10.54 -0.92 -0.061 0.15694E+04 54 coesite -2.37 -3.75 -1.38 -0.459 0.23509E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.75 -1.20 -0.399 0.20437E+04 67 diopside 16.22 12.46 -3.75 -0.375 0.64098E+04 68 hedenbergite 14.24 10.24 -4.01 -0.401 0.68437E+04 75 epidote 24.78 23.33 -1.44 -0.070 0.24607E+04 76 clinozoisite 22.92 19.93 -2.99 -0.136 0.51050E+04 77 epidote-Fe 29.94 26.74 -3.20 -0.166 0.54639E+04 78 fayalite 14.08 9.23 -4.85 -0.693 0.82802E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.97 -4.22 -0.352 0.72105E+04 91 heulandite -5.71 -9.19 -3.48 -0.158 0.59471E+04 95 jadeite 4.25 -0.48 -4.74 -0.474 0.80860E+04 98 kaolinite -1.27 -1.70 -0.43 -0.039 0.72907E+03 99 kyanite 4.93 2.05 -2.89 -0.289 0.49271E+04 101 laumontite 2.97 2.05 -0.93 -0.062 0.15815E+04 102 lawsonite 9.68 9.54 -0.14 -0.009 0.23517E+03 105 lizardite 23.29 18.65 -4.64 -0.387 0.79238E+04 106 magnesite 0.71 -4.07 -4.78 -1.592 0.81555E+04 107 magnetite 20.13 19.09 -1.05 -0.085 0.17882E+04 110 magnesioferrite 26.26 21.31 -4.95 -0.404 0.84462E+04 113 margarite 17.45 15.33 -2.12 -0.085 0.36181E+04 116 microcline -2.43 -5.87 -3.44 -0.265 0.58716E+04 120 muscovite 2.68 -0.08 -2.76 -0.162 0.47084E+04 121 paragonite 4.34 1.56 -2.78 -0.163 0.47389E+04 136 prehnite 19.47 17.04 -2.43 -0.143 0.41510E+04 137 prehnite-Fe 22.59 20.44 -2.15 -0.129 0.36690E+04 138 pumpellyite-Fe 46.47 43.45 -3.02 -0.067 0.51499E+04 139 pumpellyite-Mg 49.19 45.68 -3.51 -0.078 0.60008E+04 145 pyroxmangite 7.42 4.75 -2.66 -0.533 0.45489E+04 146 pyrophyllite -6.10 -9.19 -3.09 -0.193 0.52836E+04 147 quartz -2.98 -3.75 -0.76 -0.255 0.13048E+04 152 rhodochrosite -0.96 -4.28 -3.32 -1.108 0.56747E+04 153 rhodonite 7.46 4.75 -2.71 -0.542 0.46282E+04 154 sanidine -1.22 -5.87 -4.65 -0.358 0.79393E+04 156 siderite -2.59 -6.29 -3.70 -1.235 0.63254E+04 157 sillimanite 5.32 2.05 -3.28 -0.328 0.55925E+04 164 stilbite -7.41 -9.19 -1.78 -0.085 0.30466E+04 165 stilpnomelane-Fe 13.18 9.50 -3.68 -0.110 0.62855E+04 169 sudoite 21.22 17.77 -3.44 -0.111 0.58810E+04 175 tephroite 18.11 13.25 -4.86 -0.695 0.83033E+04 178 topaz-H 4.67 2.05 -2.62 -0.238 0.44762E+04 179 tridymite -2.61 -3.75 -1.13 -0.377 0.19321E+04 188 wairakite 4.06 2.05 -2.01 -0.118 0.34323E+04 189 walstromite 11.53 7.49 -4.03 -0.807 0.68867E+04 190 wollastonite 10.48 7.49 -2.99 -0.597 0.51006E+04 191 pseudo-wollastonite 11.02 7.49 -3.53 -0.705 0.60192E+04 192 zoisite 22.96 19.93 -3.03 -0.138 0.51775E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.15 -3.59 -0.222 0.61232E+04 195 beidellite-H -2.24 -7.00 -4.76 -0.304 0.81265E+04 196 beidellite-K -1.44 -6.18 -4.75 -0.291 0.81101E+04 197 beidellite-Mg -1.71 -5.56 -3.86 -0.239 0.65839E+04 198 beidellite-Na -1.26 -5.64 -4.39 -0.269 0.74902E+04 200 chalcedony -2.79 -3.75 -0.95 -0.317 0.16251E+04 202 montmorillonite-Ca -2.21 -5.42 -3.20 -0.198 0.54709E+04 203 montmorillonite-K -2.16 -6.46 -4.30 -0.263 0.73356E+04 204 montmorillonite-Mg -2.40 -5.84 -3.43 -0.212 0.58627E+04 205 montmorillonite-Na -1.96 -5.92 -3.96 -0.242 0.67538E+04 206 nontronite-Ca 3.28 1.66 -1.62 -0.105 0.27661E+04 207 nontronite-H 2.60 -0.20 -2.79 -0.187 0.47652E+04 208 nontronite-K 3.40 0.62 -2.78 -0.179 0.47522E+04 209 nontronite-Mg 3.14 1.24 -1.90 -0.123 0.32385E+04 210 nontronite-Na 3.58 1.16 -2.42 -0.155 0.41340E+04 215 gypsum -4.92 -9.13 -4.21 -1.052 0.71820E+04 225 tobermorite 9.84 5.62 -4.22 -1.152 0.72083E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.49 -3.34 -0.834 0.56967E+04 241 silica-amorphous -2.08 -3.75 -1.67 -0.555 0.28453E+04 243 an20ab80 2.08 -1.48 -3.56 -0.274 0.60715E+04 244 an25ab75 2.71 -0.79 -3.50 -0.269 0.59714E+04 245 an30ab70 3.34 -0.10 -3.44 -0.265 0.58796E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0004000 g Current total amount of reactant added: 0.0200000 g New total amount of reactant added: 0.0204000 g Mixing fraction reached given limit of 0.2000E-01 TOTMIX = 0.2040E-01 Execution stopped.