File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.31813E-03 0.14321E-07 0.9590 0.00000000E+00 H2O 2 0. 0.55508E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13796E-03 0.9589 0.00000000E+00 SO4-- 4 -2. 0.26059E-04 0.25272E-04 0.8921 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.12601E-04 0.9589 0.00000000E+00 HS- 6 -1. -0.55427E-06 0.10509E-10 0.9589 0.00000000E+00 Al+++ 7 3. 0.65215E-04 0.25790E-20 0.7906 0.00000000E+00 H4SiO4 8 0. 0.20826E-03 0.17941E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.37474E-04 0.36813E-04 0.8919 0.00000000E+00 Mg++ 10 2. 0.15873E-04 0.10922E-06 0.8918 0.00000000E+00 Fe++ 11 2. 0.14260E-04 0.65031E-09 0.8919 0.00000000E+00 K+ 12 1. 0.42463E-05 0.42447E-05 0.9589 0.00000000E+00 Na+ 13 1. 0.18518E-03 0.18513E-03 0.9588 0.00000000E+00 Mn++ 14 2. 0.34677E-06 0.66574E-07 0.8919 0.00000000E+00 HPO4-- 15 -2. 0.11835E-06 0.11045E-08 0.8921 0.00000000E+00 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 100.0000 SLIM = 0.400000E-01 TEMP = 100.0000 SINC = 0.1000E-02 TEMPC = 0.0000 TOTMIX = 0.200000E-01 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 1.0080 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0107 MnO2-2 65 -2. 40.4376 Ca(HSiO3)+ 17 1. 7.6603 HMnO2- 66 -1. 29.1018 Mg(HSiO3)+ 18 1. 7.5653 MnO4- 67 -1. 83.3383 NaHSiO3,aq 19 0. 7.8098 MnO4-2 68 -2. 81.3024 AlO+ 20 1. 6.8891 MnCl+ 69 1. -0.7819 AlOH+2 21 2. 3.1893 MnSO4,aq 70 0. -2.4524 HAlO2,aq 22 0. 10.5878 NaCl,aq 71 0. 0.4861 AlO2- 23 -1. 16.2390 NaOH,aq 72 0. 12.3571 CH4,aq 24 0. 6.0082 O2,aq 73 0. 53.5759 C2H6,aq 25 0. 12.3556 OH- 74 -1. 12.2220 C3H8,aq 26 0. 17.3423 HO2- 75 -1. 50.7897 C4H10,aq 27 0. 22.3397 H2O2,aq 76 0. 40.0297 ethanol,aq 28 0. 15.3114 H3PO2,aq 77 0. 24.3310 CO,aq 29 0. 4.7087 H2PO2- 78 -1. 26.5491 CO2,aq 30 0. -6.3045 HPO3-2 79 -2. 11.9246 CO3-2 31 -2. 10.0340 H3PO3,aq 80 0. 3.5932 CaCO3,aq 32 0. 5.9460 H2PO3- 81 -1. 5.6314 Ca(HCO3)+ 33 1. -1.4013 H3PO4,aq 82 0. -9.8087 CaCl+ 34 1. -0.2023 H2PO4- 83 -1. -7.2438 CaCl2,aq 35 0. 0.4306 PO4-3 84 -3. 12.0588 CaOH+ 36 1. 10.1517 H4P2O7,aq 85 0. -17.7539 CaSO4,aq 37 0. -2.4936 H3P2O7- 86 -1. -15.8646 HCl,aq 38 0. 0.7256 H2P2O7-2 87 -2. -13.3812 HClO,aq 39 0. 32.4377 HP2O7-3 88 -3. -6.6931 ClO- 40 -1. 39.6416 P2O7-4 89 -4. 2.9147 HClO2,aq 41 0. 70.2060 H2S,aq 90 0. -6.4778 Fe+3 42 3. 8.3763 S2-2 91 -2. 1.2336 FeCl+ 43 1. -0.1924 S3-2 92 -2. -8.7963 FeCl2,aq 44 0. 4.3160 S3- 93 -1. -16.3178 FeCl+2 45 2. 6.5223 S4-2 94 -2. -18.6473 FeO,aq 46 0. 16.4029 S5-2 95 -2. -28.3223 FeOH+ 47 1. 7.4795 SO2,aq 96 0. -0.1980 HFeO2- 48 -1. 24.3713 SO3-2 97 -2. 10.2895 FeO+ 49 1. 11.3812 HSO3- 98 -1. 2.5222 FeOH+2 50 2. 9.1115 HSO4- 99 -1. -2.9675 FeO2- 51 -1. 24.0877 HSO5- 100 -1. 38.8657 HFeO2,aq 52 0. 15.9903 S2O3-2 101 -2. -4.5491 H2,aq 53 0. 9.4241 HS2O3- 102 -1. -6.8007 KCl,aq 54 0. 1.7519 H2S2O3,aq 103 0. -7.9944 KHSO4,aq 55 0. -0.4275 S2O4-2 104 -2. 10.5639 KOH,aq 56 0. 12.3606 HS2O4- 105 -1. 7.6762 KSO4- 57 -1. -1.1877 H2S2O4,aq 106 0. 6.6566 MgCO3,aq 58 0. 6.5483 S2O5-2 107 -2. 10.0891 Mg(HCO3)+ 59 1. -1.4098 S2O6-2 108 -2. 11.5737 MgCl+ 60 1. -0.1603 S2O8-2 109 -2. 42.1139 MgOH+ 61 1. 9.4082 S3O6-2 110 -2. 3.8101 Mn+3 62 3. 19.1332 S4O6-2 111 -2. -17.8301 MnO,aq 63 0. 17.9765 S5O6-2 112 -2. -14.1051 MnOH+ 64 1. 8.5115 113 0. 10.3157 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.984 0.0000E+00 osumilite(2) 124 20.895 0.0000E+00 CO2,gas 2 -6.363 0.0000E+00 osumilite-Fe 125 14.657 0.0000E+00 CH4,gas 3 4.809 0.0000E+00 pargasite 126 65.279 0.0000E+00 H2,gas 4 8.287 0.0000E+00 periclase 127 16.149 0.0000E+00 H2S,gas 5 -5.943 0.0000E+00 periclase-Fe 128 11.639 0.0000E+00 S2,gas 6 -7.033 0.0000E+00 perovskite-Al 129 12.395 0.0000E+00 CO,gas 7 3.510 0.0000E+00 perovskite-Ca 130 23.818 0.0000E+00 SO3,gas 8 17.427 0.0000E+00 perovskite-Fe 131 21.158 0.0000E+00 SO2,gas 9 1.136 0.0000E+00 perovskite-Mg 132 23.132 0.0000E+00 HCl,gas 10 5.479 0.0000E+00 phase_A 133 80.267 0.0000E+00 acmite 11 7.737 0.0000E+00 phlogopite-Na 134 29.731 0.0000E+00 akermanite 12 36.495 0.0000E+00 piemontite(ordered) 135 33.876 0.0000E+00 akimotoite 13 16.606 0.0000E+00 prehnite 136 19.466 0.0000E+00 akimotoite-Fe 14 13.083 0.0000E+00 prehnite-Fe 137 22.587 0.0000E+00 albite-high 15 0.750 0.0000E+00 pumpellyite-Fe 138 46.471 0.0000E+00 albite 16 -0.328 0.0000E+00 pumpellyite-Mg 139 49.194 0.0000E+00 almandine 17 24.545 0.0000E+00 px-Mg-tschermaks 140 19.687 0.0000E+00 pyrope 18 37.348 0.0000E+00 px-Ca-tschermaks 141 18.679 0.0000E+00 spessartine 19 24.550 0.0000E+00 pyrite 142 -21.225 0.0000E+00 analcite 20 3.371 0.0000E+00 pyrrhotite 143 -4.244 0.0000E+00 andalusite 21 5.062 0.0000E+00 pyrrhotiteFe0.875 144 -6.001 0.0000E+00 andradite 22 39.088 0.0000E+00 pyroxmangite 145 7.416 0.0000E+00 grossular 23 32.828 0.0000E+00 pyrophyllite 146 -6.098 0.0000E+00 anhydrite 24 -5.280 0.0000E+00 quartz 147 -2.982 0.0000E+00 ankerite 25 -2.093 0.0000E+00 rankinite 148 40.765 0.0000E+00 annite 26 20.209 0.0000E+00 riebeckite 149 20.593 0.0000E+00 phlogopite 27 27.147 0.0000E+00 ringwoodite-Fe 150 15.486 0.0000E+00 biotite-Mn 28 33.034 0.0000E+00 ringwoodite-Mg 151 27.602 0.0000E+00 anorthite 29 12.798 0.0000E+00 rhodochrosite 152 -0.959 0.0000E+00 anthophyllite 30 51.988 0.0000E+00 rhodonite 153 7.462 0.0000E+00 anthophyllite-Fe 31 29.455 0.0000E+00 sanidine 154 -1.221 0.0000E+00 apatite-OH 32 -17.989 0.3900E-07 sapphirine(351) 155 79.204 0.0000E+00 apatite-OH-zs 33 -12.572 0.0000E+00 siderite 156 -2.588 0.0000E+00 apatite-Cl-zs 34 -16.504 0.0000E+00 sillimanite 157 5.321 0.0000E+00 aragonite 35 0.986 0.0000E+00 sodalite 158 50.255 0.0000E+00 brucite 36 12.577 0.0000E+00 spinel 159 20.934 0.0000E+00 calcite 37 0.833 0.0000E+00 spurrite 160 59.566 0.0000E+00 carnegieite-low 38 9.065 0.0000E+00 staurolite-Fe 161 74.138 0.0000E+00 carnegieite-high 39 10.134 0.0000E+00 staurolite-Mg 162 90.336 0.0000E+00 carpholite-Mg 40 8.650 0.0000E+00 staurolite-Mn 163 84.438 0.0000E+00 carpholite-Fe 41 6.783 0.0000E+00 stilbite 164 -7.406 0.0000E+00 celadonite 42 5.401 0.0000E+00 stilpnomelane-Fe 165 13.179 0.0000E+00 celadonite-Fe 43 3.937 0.0000E+00 stilpnomelane-Mg 166 27.596 0.0000E+00 chrysotile 44 23.937 0.0000E+00 stishovite 167 2.721 0.0000E+00 chondrodite 45 56.542 0.0000E+00 sudoite-Fe 168 18.437 0.0000E+00 clinochlore 46 39.193 0.3152E-05 sudoite 169 21.216 0.0000E+00 daphnite 47 29.094 0.1964E-05 sulfur 170 -9.141 0.0000E+00 chlorite-Mn 48 46.985 0.5311E-07 sylvite 171 1.345 0.0000E+00 chlorite-Al-free 49 47.262 0.0000E+00 talc 172 16.553 0.0000E+00 chloritoid-Mg 50 13.261 0.0000E+00 talc-Fe 173 13.516 0.0000E+00 chloritoid-Fe 51 9.239 0.0000E+00 talc-tschermaks 174 19.189 0.0000E+00 chloritoid-Mn 52 11.463 0.0000E+00 tephroite 175 18.113 0.0000E+00 clinohumite 53 97.255 0.0000E+00 tilleyite 176 41.473 0.0000E+00 coesite 54 -2.369 0.0000E+00 titanite-CaSi 177 15.497 0.0000E+00 cordierite-H 55 23.898 0.0000E+00 topaz-H 178 4.668 0.0000E+00 cordierite 56 24.245 0.0000E+00 tridymite 179 -2.615 0.0000E+00 cordierite-Fe 57 20.649 0.0000E+00 tremolite 180 48.003 0.0000E+00 cordierite-Mn 58 25.261 0.0000E+00 ferroactinolite 181 38.596 0.0000E+00 corundum 59 8.433 0.0000E+00 troilite-low 182 -4.394 0.0000E+00 corundum-MgSi 60 18.905 0.0000E+00 tschermakite 183 48.414 0.0000E+00 cristobalite 61 -2.549 0.0000E+00 vesuvianite 184 224.056 0.0000E+00 cummingtonite 62 52.233 0.0000E+00 wadeite-Si 185 20.233 0.0000E+00 cymrite-K 63 1.731 0.0000E+00 wadsleyite-Fe 186 15.711 0.0000E+00 deerite 64 95.982 0.0000E+00 wadsleyite-Mg 187 25.878 0.0000E+00 diaspore 65 2.896 0.5141E-04 wairakite 188 4.058 0.0000E+00 diamond 66 -3.107 0.0000E+00 walstromite 189 11.528 0.0000E+00 diopside 67 16.215 0.0000E+00 wollastonite 190 10.482 0.0000E+00 hedenbergite 68 14.244 0.0000E+00 pseudo-wollastonite 191 11.020 0.0000E+00 dolomite,ordered 69 0.587 0.0000E+00 zoisite 192 22.964 0.0000E+00 eastonite 70 28.605 0.0000E+00 akaganeite 193 7.768 0.0000E+00 enstatite 71 17.301 0.0000E+00 beidellite-Ca 194 -1.560 0.0000E+00 clinoenstatite-HiP 72 18.388 0.0000E+00 beidellite-H 195 -2.241 0.0000E+00 clinoenstatite 73 17.202 0.0000E+00 beidellite-K 196 -1.435 0.0000E+00 protoenstatite 74 17.860 0.0000E+00 beidellite-Mg 197 -1.707 0.0000E+00 epidote 75 24.775 0.0000E+00 beidellite-Na 198 -1.257 0.0000E+00 clinozoisite 76 22.921 0.0000E+00 calcium 199 84.043 0.0000E+00 epidote-Fe 77 29.937 0.0000E+00 chalcedony 200 -2.794 0.0000E+00 fayalite 78 14.079 0.0000E+00 dawsonite 201 1.714 0.0000E+00 ferrosilite 79 11.188 0.0000E+00 montmorillonite-Ca 202 -2.214 0.0000E+00 forsterite 80 21.047 0.0000E+00 montmorillonite-K 203 -2.161 0.0000E+00 gedrite 81 50.725 0.0000E+00 montmorillonite-Mg 204 -2.402 0.0000E+00 gehlenite 82 36.717 0.0000E+00 montmorillonite-Na 205 -1.961 0.0000E+00 gibbsite 83 4.097 0.0000E+00 nontronite-Ca 206 3.280 0.0000E+00 glaucophane 84 23.111 0.0000E+00 nontronite-H 207 2.596 0.0000E+00 glaucophane-Fe 85 17.417 0.0000E+00 nontronite-K 208 3.404 0.0000E+00 graphite 86 -3.549 0.0000E+00 nontronite-Mg 209 3.139 0.0000E+00 greenalite 87 16.194 0.0000E+00 nontronite-Na 210 3.583 0.0000E+00 grunerite 88 31.364 0.0000E+00 sepiolite 211 24.194 0.0000E+00 halite 89 1.582 0.0000E+00 alite 212 58.043 0.0000E+00 hematite 90 12.598 0.2218E-05 belite 213 30.461 0.0000E+00 heulandite 91 -5.707 0.0000E+00 ettringite 214 43.354 0.0000E+00 hercynite 92 17.345 0.0000E+00 gypsum 215 -4.924 0.0000E+00 hollandite 93 25.702 0.0000E+00 hemicarboaluminate 216 71.028 0.0000E+00 iron 94 19.095 0.0000E+00 hydrogarnet 217 60.721 0.0000E+00 jadeite 95 4.251 0.0000E+00 hydrogarnet-Si 218 50.654 0.0000E+00 julgoldite 96 70.573 0.0000E+00 jennite 219 24.386 0.0000E+00 kalsilite 97 7.620 0.0000E+00 monosulfoaluminate 220 53.497 0.0000E+00 kaolinite 98 -1.273 0.0000E+00 monocarboaluminate 221 61.966 0.0000E+00 kyanite 99 4.932 0.0000E+00 portlandite 222 18.282 0.0000E+00 larnite-bredigite 100 30.714 0.0000E+00 stratlingite 223 36.573 0.0000E+00 laumontite 101 2.975 0.0000E+00 tricarboaluminate 224 70.427 0.0000E+00 lawsonite 102 9.678 0.0000E+00 tobermorite 225 9.839 0.0000E+00 leucite 103 4.168 0.0000E+00 C4AH13 226 81.870 0.0000E+00 lime 104 26.009 0.0000E+00 C2AH8 227 45.260 0.0000E+00 lizardite 105 23.287 0.0000E+00 C3A 228 87.049 0.0000E+00 magnesite 106 0.709 0.0000E+00 C4AF 229 117.550 0.0000E+00 magnetite 107 20.133 0.0000E+00 CAH10 230 28.373 0.0000E+00 minnesotaite 108 10.461 0.0000E+00 alabandite 231 -0.962 0.0000E+00 minnesotaite-Mg 109 20.669 0.0000E+00 alunite 232 -10.224 0.0000E+00 magnesioferrite 110 26.257 0.0000E+00 artinite 233 15.139 0.0000E+00 majorite 111 53.314 0.0000E+00 boehmite 234 4.430 0.0000E+00 manganosite 112 14.068 0.0000E+00 dolomite,disordered 235 1.288 0.0000E+00 margarite 113 17.452 0.0000E+00 ferrous-oxide 236 9.824 0.0000E+00 meionite 114 45.158 0.0000E+00 huntite 237 3.850 0.0000E+00 merwinite 115 55.988 0.0000E+00 hydromagnesite 238 20.077 0.0000E+00 microcline 116 -2.432 0.0000E+00 nesquehonite 239 4.735 0.0000E+00 monticellite 117 24.371 0.0000E+00 potassium-oxide 240 69.039 0.0000E+00 mullite-Al 118 363.258 0.0000E+00 silica-amorphous 241 -2.080 0.0000E+00 mullite-Si 119 7.324 0.0000E+00 sodium-oxide 242 55.173 0.0000E+00 muscovite 120 2.679 0.0000E+00 an20ab80 243 2.079 0.0000E+00 paragonite 121 4.337 0.0000E+00 an25ab75 244 2.709 0.0000E+00 nepheline 122 8.378 0.0000E+00 an30ab70 245 3.344 0.0000E+00 osumilite(1) 123 21.978 0.0000E+00 tr.625ac.25prg.125 246 45.308 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 0.0200000 g log = -1.6990 Original solution: 1000.0103000 g Original solution / Rock added: 50000.51 (Water/Rock Ratio), log = 4.6990 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0200000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3118062E-03 Osmotic coef. = 0.9895 True ionic strength = .3259400E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14321E-07 -7.8440 0.13733E-07 -7.8622 0.95899E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13228E-03 -3.8785 0.95885E+00 -0.0182 4 SO4-- 0.25272E-04 -4.5974 0.22545E-04 -4.6470 0.89209E+00 -0.0496 5 HCO3- 0.12601E-04 -4.8996 0.12083E-04 -4.9178 0.95888E+00 -0.0182 6 HS- 0.10509E-10 -10.9784 0.10077E-10 -10.9967 0.95885E+00 -0.0182 7 Al+++ 0.25790E-20 -20.5886 0.20390E-20 -20.6906 0.79064E+00 -0.1020 8 H4SiO4 0.17941E-03 -3.7462 0.17941E-03 -3.7462 0.10000E+01 0.0000 9 Ca++ 0.36813E-04 -4.4340 0.32835E-04 -4.4837 0.89194E+00 -0.0497 10 Mg++ 0.10922E-06 -6.9617 0.97404E-07 -7.0114 0.89184E+00 -0.0497 11 Fe++ 0.65031E-09 -9.1869 0.57999E-09 -9.2366 0.89186E+00 -0.0497 12 K+ 0.42447E-05 -5.3722 0.40702E-05 -5.3904 0.95889E+00 -0.0182 13 Na+ 0.18513E-03 -3.7325 0.17751E-03 -3.7508 0.95885E+00 -0.0183 14 Mn++ 0.66574E-07 -7.1767 0.59376E-07 -7.2264 0.89188E+00 -0.0497 15 HPO4-- 0.11045E-08 -8.9568 0.98529E-09 -9.0064 0.89209E+00 -0.0496 16 HSiO3- 0.13293E-04 -4.8764 0.12746E-04 -4.8946 0.95885E+00 -0.0182 17 Ca(HSiO3)+ 0.97786E-08 -8.0097 0.93767E-08 -8.0280 0.95889E+00 -0.0182 18 Mg(HSiO3)+ 0.36101E-10 -10.4425 0.34617E-10 -10.4607 0.95889E+00 -0.0182 19 NaHSiO3,aq 0.35934E-07 -7.4445 0.35934E-07 -7.4445 0.10000E+01 0.0000 20 AlO+ 0.14555E-11 -11.8370 0.13957E-11 -11.8552 0.95889E+00 -0.0182 21 AlOH+2 0.10765E-15 -15.9680 0.96016E-16 -16.0177 0.89190E+00 -0.0497 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.34485E-05 -5.4624 0.33064E-05 -5.4806 0.95881E+00 -0.0183 24 CH4,aq 0.53001E-17 -17.2757 0.52996E-17 -17.2758 0.99990E+00 0.0000 29 CO,aq 0.77508E-17 -17.1107 0.77508E-17 -17.1107 0.10000E+01 0.0000 30 CO2,aq 0.33460E-06 -6.4755 0.33457E-06 -6.4755 0.99990E+00 0.0000 31 CO3-2 0.91193E-07 -7.0400 0.81348E-07 -7.0897 0.89204E+00 -0.0496 32 CaCO3,aq 0.32714E-07 -7.4853 0.32714E-07 -7.4853 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10425E-07 -7.9819 0.99967E-08 -8.0001 0.95889E+00 -0.0182 34 CaCl+ 0.72180E-08 -8.1416 0.69213E-08 -8.1598 0.95889E+00 -0.0182 35 CaCl2,aq 0.21318E-12 -12.6713 0.21318E-12 -12.6713 0.10000E+01 0.0000 36 CaOH+ 0.17581E-06 -6.7550 0.16859E-06 -6.7732 0.95889E+00 -0.0182 37 CaSO4,aq 0.23064E-06 -6.6371 0.23064E-06 -6.6371 0.10000E+01 0.0000 38 HCl,aq 0.34172E-12 -12.4663 0.34172E-12 -12.4663 0.10000E+01 0.0000 43 FeCl+ 0.12462E-12 -12.9044 0.11950E-12 -12.9226 0.95889E+00 -0.0182 46 FeO,aq 0.12160E-09 -9.9151 0.12160E-09 -9.9151 0.10000E+01 0.0000 47 FeOH+ 0.14601E-08 -8.8356 0.14001E-08 -8.8538 0.95889E+00 -0.0182 48 HFeO2- 0.99328E-10 -10.0029 0.95240E-10 -10.0212 0.95885E+00 -0.0182 49 FeO+ 0.11847E-12 -12.9264 0.11360E-12 -12.9446 0.95889E+00 -0.0182 50 FeOH+2 0.32550E-18 -18.4874 0.29032E-18 -18.5371 0.89190E+00 -0.0497 51 FeO2- 0.12346E-09 -9.9085 0.11838E-09 -9.9267 0.95885E+00 -0.0182 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.89957E-09 -9.0460 0.89948E-09 -9.0460 0.99990E+00 0.0000 54 KCl,aq 0.95335E-11 -11.0207 0.95335E-11 -11.0207 0.10000E+01 0.0000 55 KHSO4,aq 0.33723E-17 -17.4721 0.33723E-17 -17.4721 0.10000E+01 0.0000 56 KOH,aq 0.12920E-09 -9.8887 0.12920E-09 -9.8887 0.10000E+01 0.0000 57 KSO4- 0.14744E-08 -8.8314 0.14137E-08 -8.8496 0.95885E+00 -0.0182 58 MgCO3,aq 0.24250E-10 -10.6153 0.24250E-10 -10.6153 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.31537E-10 -10.5012 0.30240E-10 -10.5194 0.95889E+00 -0.0182 60 MgCl+ 0.19438E-10 -10.7113 0.18639E-10 -10.7296 0.95889E+00 -0.0182 61 MgOH+ 0.28894E-08 -8.5392 0.27706E-08 -8.5574 0.95889E+00 -0.0182 63 MnO,aq 0.33233E-09 -9.4784 0.33233E-09 -9.4784 0.10000E+01 0.0000 64 MnOH+ 0.13886E-07 -7.8574 0.13315E-07 -7.8756 0.95889E+00 -0.0182 65 MnO2-2 0.68312E-16 -16.1655 0.60938E-16 -16.2151 0.89204E+00 -0.0496 66 HMnO2- 0.18910E-12 -12.7233 0.18132E-12 -12.7416 0.95885E+00 -0.0182 69 MnCl+ 0.49575E-10 -10.3047 0.47537E-10 -10.3230 0.95889E+00 -0.0182 70 MnSO4,aq 0.37937E-09 -9.4209 0.37937E-09 -9.4209 0.10000E+01 0.0000 71 NaCl,aq 0.76673E-08 -8.1154 0.76673E-08 -8.1154 0.10000E+01 0.0000 72 NaOH,aq 0.56795E-08 -8.2457 0.56795E-08 -8.2457 0.10000E+01 0.0000 74 OH- 0.45553E-04 -4.3415 0.43677E-04 -4.3597 0.95881E+00 -0.0183 82 H3PO4,aq 0.11964E-14 -14.9221 0.11964E-14 -14.9221 0.10000E+01 0.0000 83 H2PO4- 0.24741E-09 -9.6066 0.23723E-09 -9.6248 0.95887E+00 -0.0182 84 PO4-3 0.79152E-13 -13.1015 0.62655E-13 -13.2030 0.79157E+00 -0.1015 88 HP2O7-3 0.83181E-19 -19.0800 0.65767E-19 -19.1820 0.79064E+00 -0.1020 90 H2S,aq 0.41585E-12 -12.3811 0.41581E-12 -12.3811 0.99990E+00 0.0000 96 SO2,aq 0.16024E-19 -19.7952 0.16024E-19 -19.7952 0.10000E+01 0.0000 97 SO3-2 0.30985E-14 -14.5088 0.27650E-14 -14.5583 0.89236E+00 -0.0495 98 HSO3- 0.23176E-14 -14.6350 0.22222E-14 -14.6532 0.95885E+00 -0.0182 99 HSO4- 0.29959E-09 -9.5235 0.28728E-09 -9.5417 0.95892E+00 -0.0182 101 S2O3-2 0.12385E-18 -18.9071 0.11048E-18 -18.9567 0.89204E+00 -0.0496 Charge balance for all species = 0.2080E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1432072E-07 -.7272342E-04 -.7329857E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999674E+06 0.0000 3 Cl- 0.1379603E-03 0.1379752E-03 0.4891484E+01 3.9837 4 SO4-- 0.2527186E-04 0.2550447E-04 0.2449924E+01 11.0775 5 HCO3- 0.1260111E-04 0.1307010E-04 0.7974762E+00 2.9444 6 HS- 0.1050941E-10 0.1949363E-09 0.6446732E-05 -3.1344 7 Al+++ 0.2578966E-20 0.3468798E-05 0.9359046E-01 2.8961 8 H4SiO4 0.1794096E-03 0.1927483E-03 0.1852550E+02 -3.7462 9 Ca++ 0.3681261E-04 0.3727920E-04 0.1494029E+01 11.2408 10 Mg++ 0.1092166E-06 0.1122173E-06 0.2728143E-02 8.7130 11 Fe++ 0.6503146E-09 0.2658543E-08 0.1484670E-03 6.4879 12 K+ 0.4244704E-05 0.4246317E-05 0.1660343E+00 2.4718 13 Na+ 0.1851280E-03 0.1851773E-03 0.4257057E+01 4.1114 14 Mn++ 0.6657446E-07 0.8122204E-07 0.4462038E-02 8.4981 15 HPO4-- 0.1104468E-08 0.1351957E-08 0.1297554E-03 6.7180 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3181303E-03 -.7272286E-04 -.2454074E-03 0.0000000E+00 2 H2O 0.5550800E+02 0.5550786E+02 0.1383061E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2605874E-04 0.2550428E-04 0.5544631E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5542682E-06 0.1949348E-09 -.5544631E-06 0.0000000E+00 7 Al+++ 0.6521483E-04 0.3468771E-05 0.6174606E-04 0.0000000E+00 8 H4SiO4 0.2082557E-03 0.1927468E-03 0.1550890E-04 0.0000000E+00 9 Ca++ 0.3747391E-04 0.3727891E-04 0.1949993E-06 0.0000000E+00 10 Mg++ 0.1587302E-04 0.1122165E-06 0.1576080E-04 0.0000000E+00 11 Fe++ 0.1426017E-04 0.2658522E-08 0.1425751E-04 0.0000000E+00 12 K+ 0.4246285E-05 0.4246285E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1851759E-03 0.1851759E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3467719E-06 0.8122142E-07 0.2655505E-06 0.0000000E+00 15 HPO4-- 0.1183515E-06 0.1351946E-08 0.1169996E-06 0.0000000E+00 Chg. balance for solid moles: -.3992E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0200000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3900E-07 -7.409 0.1959E-04 -4.708 0.2946 0.6225E-05 clinochlore 0.3152E-05 -5.501 0.1752E-02 -2.756 26.35 0.6664E-03 daphnite 0.1964E-05 -5.707 0.1402E-02 -2.853 21.08 0.4247E-03 chlorite-Mn 0.5311E-07 -7.275 0.3765E-04 -4.424 0.5663 0.1200E-04 diaspore 0.5141E-04 -4.289 0.3084E-02 -2.511 46.38 0.9181E-03 hematite 0.2218E-05 -5.654 0.3542E-03 -3.451 5.327 0.6713E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3800E+00 0.3800E+00 1.0000 -0.420 chlorite-Mn 0.1027E-01 0.1027E-01 1.0000 -1.988 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.006649 g Volume = 0.002095 cm3 Porosity: 99.7922% V(tot) - V(min): 0.10059E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0200000 g log = -1.6990 Original solution: 1000.0103000 g Original solution / Rock added: 50000.51 (Water/Rock Ratio), log = 4.6990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3614E-04 1.0073 0.3830E-04 0.3802E-04 CH4,gas 0.7865E-14 1.0129 0.8381E-14 0.8274E-14 H2,gas 0.1172E-05 1.0006 0.1234E-05 0.1233E-05 H2S,gas 0.1158E-10 0.9959 0.1213E-10 0.1218E-10 S2,gas 0.3440E-29 1.0000 0.3619E-29 0.3619E-29 CO,gas 0.1163E-13 1.0000 0.1224E-13 0.1224E-13 SO3,gas 0.1511E-35 1.0000 0.1590E-35 0.1590E-35 SO2,gas 0.7053E-19 1.0000 0.7419E-19 0.7419E-19 HCl,gas 0.5736E-15 1.0000 0.6034E-15 0.6034E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.78 -6.42 -2.139 0.10957E+05 -4.417 3 CH4,gas 4.81 -11.27 -16.08 -4.019 0.27451E+05 -14.077 4 H2,gas 8.29 0.38 -7.91 -4.519 0.13504E+05 -5.909 5 H2S,gas -5.94 -18.86 -12.92 -6.458 0.22054E+05 -10.916 6 S2,gas -7.03 -38.47 -31.44 -4.837 0.53685E+05 -29.441 7 CO,gas 3.51 -12.40 -15.91 -4.896 0.27170E+05 -13.912 8 SO3,gas 17.43 -20.37 -37.80 -9.450 0.64540E+05 -35.799 9 SO2,gas 1.14 -19.99 -21.13 -5.635 0.36078E+05 -19.130 10 HCl,gas 5.48 -11.74 -17.22 -8.610 0.29402E+05 -15.219 11 acmite 7.74 2.92 -4.82 -0.501 0.82291E+04 15 albite-high 0.75 -4.23 -4.98 -0.383 0.85042E+04 16 albite -0.33 -4.23 -3.90 -0.300 0.66635E+04 19 spessartine 24.55 20.05 -4.50 -0.225 0.76871E+04 20 analcite 3.37 -0.48 -3.86 -0.428 0.65830E+04 21 andalusite 5.06 2.05 -3.02 -0.302 0.51503E+04 22 andradite 39.09 35.08 -4.01 -0.208 0.68406E+04 23 grossular 32.83 28.28 -4.55 -0.228 0.77727E+04 24 anhydrite -5.28 -9.13 -3.85 -1.925 0.65753E+04 29 anorthite 12.80 9.54 -3.26 -0.251 0.55613E+04 35 aragonite 0.99 -1.54 -2.53 -0.842 0.43122E+04 36 brucite 12.58 8.71 -3.86 -0.773 0.65970E+04 37 calcite 0.83 -1.54 -2.37 -0.791 0.40509E+04 40 carpholite-Mg 8.65 7.01 -1.64 -0.109 0.27960E+04 41 carpholite-Fe 6.78 4.79 -2.00 -0.133 0.34067E+04 50 chloritoid-Mg 13.26 10.76 -2.50 -0.167 0.42724E+04 51 chloritoid-Fe 9.24 8.53 -0.70 -0.047 0.12034E+04 52 chloritoid-Mn 11.46 10.54 -0.92 -0.061 0.15694E+04 54 coesite -2.37 -3.75 -1.38 -0.459 0.23509E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.75 -1.20 -0.399 0.20437E+04 67 diopside 16.22 12.46 -3.75 -0.375 0.64098E+04 68 hedenbergite 14.24 10.24 -4.01 -0.401 0.68437E+04 75 epidote 24.78 23.33 -1.44 -0.070 0.24607E+04 76 clinozoisite 22.92 19.93 -2.99 -0.136 0.51050E+04 77 epidote-Fe 29.94 26.74 -3.20 -0.166 0.54639E+04 78 fayalite 14.08 9.23 -4.85 -0.693 0.82802E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.97 -4.22 -0.352 0.72105E+04 91 heulandite -5.71 -9.19 -3.48 -0.158 0.59471E+04 95 jadeite 4.25 -0.48 -4.74 -0.474 0.80860E+04 98 kaolinite -1.27 -1.70 -0.43 -0.039 0.72907E+03 99 kyanite 4.93 2.05 -2.89 -0.289 0.49271E+04 101 laumontite 2.97 2.05 -0.93 -0.062 0.15815E+04 102 lawsonite 9.68 9.54 -0.14 -0.009 0.23517E+03 105 lizardite 23.29 18.65 -4.64 -0.387 0.79238E+04 106 magnesite 0.71 -4.07 -4.78 -1.592 0.81555E+04 107 magnetite 20.13 19.09 -1.05 -0.085 0.17882E+04 110 magnesioferrite 26.26 21.31 -4.95 -0.404 0.84462E+04 113 margarite 17.45 15.33 -2.12 -0.085 0.36181E+04 116 microcline -2.43 -5.87 -3.44 -0.265 0.58716E+04 120 muscovite 2.68 -0.08 -2.76 -0.162 0.47084E+04 121 paragonite 4.34 1.56 -2.78 -0.163 0.47389E+04 136 prehnite 19.47 17.04 -2.43 -0.143 0.41510E+04 137 prehnite-Fe 22.59 20.44 -2.15 -0.129 0.36690E+04 138 pumpellyite-Fe 46.47 43.45 -3.02 -0.067 0.51499E+04 139 pumpellyite-Mg 49.19 45.68 -3.51 -0.078 0.60008E+04 145 pyroxmangite 7.42 4.75 -2.66 -0.533 0.45489E+04 146 pyrophyllite -6.10 -9.19 -3.09 -0.193 0.52836E+04 147 quartz -2.98 -3.75 -0.76 -0.255 0.13048E+04 152 rhodochrosite -0.96 -4.28 -3.32 -1.108 0.56747E+04 153 rhodonite 7.46 4.75 -2.71 -0.542 0.46282E+04 154 sanidine -1.22 -5.87 -4.65 -0.358 0.79393E+04 156 siderite -2.59 -6.29 -3.70 -1.235 0.63254E+04 157 sillimanite 5.32 2.05 -3.28 -0.328 0.55925E+04 164 stilbite -7.41 -9.19 -1.78 -0.085 0.30466E+04 165 stilpnomelane-Fe 13.18 9.50 -3.68 -0.110 0.62855E+04 169 sudoite 21.22 17.77 -3.44 -0.111 0.58810E+04 175 tephroite 18.11 13.25 -4.86 -0.695 0.83033E+04 178 topaz-H 4.67 2.05 -2.62 -0.238 0.44762E+04 179 tridymite -2.61 -3.75 -1.13 -0.377 0.19321E+04 188 wairakite 4.06 2.05 -2.01 -0.118 0.34323E+04 189 walstromite 11.53 7.49 -4.03 -0.807 0.68867E+04 190 wollastonite 10.48 7.49 -2.99 -0.597 0.51006E+04 191 pseudo-wollastonite 11.02 7.49 -3.53 -0.705 0.60192E+04 192 zoisite 22.96 19.93 -3.03 -0.138 0.51775E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.15 -3.59 -0.222 0.61232E+04 195 beidellite-H -2.24 -7.00 -4.76 -0.304 0.81265E+04 196 beidellite-K -1.44 -6.18 -4.75 -0.291 0.81101E+04 197 beidellite-Mg -1.71 -5.56 -3.86 -0.239 0.65839E+04 198 beidellite-Na -1.26 -5.64 -4.39 -0.269 0.74902E+04 200 chalcedony -2.79 -3.75 -0.95 -0.317 0.16251E+04 202 montmorillonite-Ca -2.21 -5.42 -3.20 -0.198 0.54709E+04 203 montmorillonite-K -2.16 -6.46 -4.30 -0.263 0.73356E+04 204 montmorillonite-Mg -2.40 -5.84 -3.43 -0.212 0.58627E+04 205 montmorillonite-Na -1.96 -5.92 -3.96 -0.242 0.67538E+04 206 nontronite-Ca 3.28 1.66 -1.62 -0.105 0.27661E+04 207 nontronite-H 2.60 -0.20 -2.79 -0.187 0.47652E+04 208 nontronite-K 3.40 0.62 -2.78 -0.179 0.47522E+04 209 nontronite-Mg 3.14 1.24 -1.90 -0.123 0.32385E+04 210 nontronite-Na 3.58 1.16 -2.42 -0.155 0.41340E+04 215 gypsum -4.92 -9.13 -4.21 -1.052 0.71820E+04 225 tobermorite 9.84 5.62 -4.22 -1.152 0.72083E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.49 -3.34 -0.834 0.56967E+04 241 silica-amorphous -2.08 -3.75 -1.67 -0.555 0.28453E+04 243 an20ab80 2.08 -1.48 -3.56 -0.274 0.60715E+04 244 an25ab75 2.71 -0.79 -3.50 -0.269 0.59714E+04 245 an30ab70 3.34 -0.10 -3.44 -0.265 0.58796E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0200000 g New total amount of reactant added: 0.0210000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0210000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3155348E-03 Osmotic coef. = 0.9894 True ionic strength = .3307066E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13663E-07 -7.8645 0.13100E-07 -7.8827 0.95883E+00 -0.0183 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13226E-03 -3.8786 0.95869E+00 -0.0183 4 SO4-- 0.25265E-04 -4.5975 0.22524E-04 -4.6474 0.89148E+00 -0.0499 5 HCO3- 0.12609E-04 -4.8993 0.12088E-04 -4.9176 0.95872E+00 -0.0183 6 HS- 0.79925E-11 -11.0973 0.76623E-11 -11.1156 0.95869E+00 -0.0183 7 Al+++ 0.22419E-20 -20.6494 0.17698E-20 -20.7521 0.78942E+00 -0.1027 8 H4SiO4 0.18773E-03 -3.7265 0.18773E-03 -3.7265 0.10000E+01 0.0000 9 Ca++ 0.37928E-04 -4.4210 0.33806E-04 -4.4710 0.89133E+00 -0.0500 10 Mg++ 0.96781E-07 -7.0142 0.86254E-07 -7.0642 0.89123E+00 -0.0500 11 Fe++ 0.57566E-09 -9.2398 0.51306E-09 -9.2898 0.89125E+00 -0.0500 12 K+ 0.44569E-05 -5.3510 0.42730E-05 -5.3693 0.95873E+00 -0.0183 13 Na+ 0.18638E-03 -3.7296 0.17868E-03 -3.7479 0.95868E+00 -0.0183 14 Mn++ 0.61071E-07 -7.2142 0.54431E-07 -7.2642 0.89127E+00 -0.0500 15 HPO4-- 0.98859E-09 -9.0050 0.88131E-09 -9.0549 0.89149E+00 -0.0499 16 HSiO3- 0.14584E-04 -4.8361 0.13982E-04 -4.8544 0.95869E+00 -0.0183 17 Ca(HSiO3)+ 0.11046E-07 -7.9568 0.10590E-07 -7.9751 0.95873E+00 -0.0183 18 Mg(HSiO3)+ 0.35075E-10 -10.4550 0.33627E-10 -10.4733 0.95873E+00 -0.0183 19 NaHSiO3,aq 0.39678E-07 -7.4014 0.39678E-07 -7.4014 0.10000E+01 0.0000 20 AlO+ 0.13886E-11 -11.8574 0.13313E-11 -11.8757 0.95873E+00 -0.0183 21 AlOH+2 0.98023E-16 -16.0087 0.87367E-16 -16.0587 0.89129E+00 -0.0500 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.36157E-05 -5.4418 0.34662E-05 -5.4601 0.95864E+00 -0.0183 24 CH4,aq 0.40357E-17 -17.3941 0.40353E-17 -17.3941 0.99990E+00 0.0000 29 CO,aq 0.69908E-17 -17.1555 0.69908E-17 -17.1555 0.10000E+01 0.0000 30 CO2,aq 0.31932E-06 -6.4958 0.31929E-06 -6.4958 0.99990E+00 0.0000 31 CO3-2 0.95709E-07 -7.0190 0.85318E-07 -7.0690 0.89144E+00 -0.0499 32 CaCO3,aq 0.35325E-07 -7.4519 0.35325E-07 -7.4519 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10740E-07 -7.9690 0.10297E-07 -7.9873 0.95873E+00 -0.0183 34 CaCl+ 0.74315E-08 -8.1289 0.71248E-08 -8.1472 0.95873E+00 -0.0183 35 CaCl2,aq 0.21941E-12 -12.6587 0.21941E-12 -12.6587 0.10000E+01 0.0000 36 CaOH+ 0.18979E-06 -6.7217 0.18196E-06 -6.7400 0.95873E+00 -0.0183 37 CaSO4,aq 0.23724E-06 -6.6248 0.23724E-06 -6.6248 0.10000E+01 0.0000 38 HCl,aq 0.32591E-12 -12.4869 0.32591E-12 -12.4869 0.10000E+01 0.0000 43 FeCl+ 0.11024E-12 -12.9577 0.10569E-12 -12.9760 0.95873E+00 -0.0183 46 FeO,aq 0.11822E-09 -9.9273 0.11822E-09 -9.9273 0.10000E+01 0.0000 47 FeOH+ 0.13543E-08 -8.8683 0.12984E-08 -8.8866 0.95873E+00 -0.0183 48 HFeO2- 0.10125E-09 -9.9946 0.97064E-10 -10.0129 0.95869E+00 -0.0183 49 FeO+ 0.11303E-12 -12.9468 0.10837E-12 -12.9651 0.95873E+00 -0.0183 50 FeOH+2 0.29639E-18 -18.5281 0.26417E-18 -18.5781 0.89129E+00 -0.0500 51 FeO2- 0.12945E-09 -9.8879 0.12411E-09 -9.9062 0.95869E+00 -0.0183 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.85019E-09 -9.0705 0.85011E-09 -9.0705 0.99990E+00 0.0000 54 KCl,aq 0.10007E-10 -10.9997 0.10007E-10 -10.9997 0.10000E+01 0.0000 55 KHSO4,aq 0.33739E-17 -17.4719 0.33739E-17 -17.4719 0.10000E+01 0.0000 56 KOH,aq 0.14219E-09 -9.8471 0.14219E-09 -9.8471 0.10000E+01 0.0000 57 KSO4- 0.15466E-08 -8.8106 0.14827E-08 -8.8289 0.95869E+00 -0.0183 58 MgCO3,aq 0.22522E-10 -10.6474 0.22522E-10 -10.6474 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27944E-10 -10.5537 0.26791E-10 -10.5720 0.95873E+00 -0.0183 60 MgCl+ 0.17213E-10 -10.7641 0.16503E-10 -10.7824 0.95873E+00 -0.0183 61 MgOH+ 0.26828E-08 -8.5714 0.25721E-08 -8.5897 0.95873E+00 -0.0183 63 MnO,aq 0.33481E-09 -9.4752 0.33481E-09 -9.4752 0.10000E+01 0.0000 64 MnOH+ 0.13347E-07 -7.8746 0.12796E-07 -7.8929 0.95873E+00 -0.0183 65 MnO2-2 0.75687E-16 -16.1210 0.67470E-16 -16.1709 0.89144E+00 -0.0499 66 HMnO2- 0.19975E-12 -12.6995 0.19150E-12 -12.7178 0.95869E+00 -0.0183 69 MnCl+ 0.45446E-10 -10.3425 0.43571E-10 -10.3608 0.95873E+00 -0.0183 70 MnSO4,aq 0.34744E-09 -9.4591 0.34744E-09 -9.4591 0.10000E+01 0.0000 71 NaCl,aq 0.77165E-08 -8.1126 0.77165E-08 -8.1126 0.10000E+01 0.0000 72 NaOH,aq 0.59932E-08 -8.2223 0.59932E-08 -8.2223 0.10000E+01 0.0000 74 OH- 0.47763E-04 -4.3209 0.45788E-04 -4.3392 0.95864E+00 -0.0183 82 H3PO4,aq 0.97373E-15 -15.0116 0.97373E-15 -15.0116 0.10000E+01 0.0000 83 H2PO4- 0.21113E-09 -9.6754 0.20242E-09 -9.6938 0.95871E+00 -0.0183 84 PO4-3 0.74334E-13 -13.1288 0.58751E-13 -13.2310 0.79037E+00 -0.1022 88 HP2O7-3 0.63581E-19 -19.1967 0.50193E-19 -19.2994 0.78943E+00 -0.1027 90 H2S,aq 0.30162E-12 -12.5205 0.30159E-12 -12.5206 0.99990E+00 0.0000 96 SO2,aq 0.13767E-19 -19.8611 0.13767E-19 -19.8611 0.10000E+01 0.0000 97 SO3-2 0.29277E-14 -14.5335 0.26107E-14 -14.5832 0.89175E+00 -0.0498 98 HSO3- 0.20878E-14 -14.6803 0.20015E-14 -14.6986 0.95869E+00 -0.0183 99 HSO4- 0.28556E-09 -9.5443 0.27378E-09 -9.5626 0.95875E+00 -0.0183 101 S2O3-2 0.89808E-19 -19.0467 0.80058E-19 -19.0966 0.89144E+00 -0.0499 Charge balance for all species = 0.2080E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1366284E-07 -.7693543E-04 -.7754380E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999664E+06 0.0000 3 Cl- 0.1379601E-03 0.1379753E-03 0.4891481E+01 4.0041 4 SO4-- 0.2526524E-04 0.2550450E-04 0.2449924E+01 11.1181 5 HCO3- 0.1260896E-04 0.1307011E-04 0.7974756E+00 2.9651 6 HS- 0.7992453E-11 0.1792137E-09 0.5926764E-05 -3.2329 7 Al+++ 0.2241925E-20 0.3636083E-05 0.9810382E-01 2.8961 8 H4SiO4 0.1877333E-03 0.2023684E-03 0.1945009E+02 -3.7265 9 Ca++ 0.3792767E-04 0.3841925E-04 0.1539717E+01 11.2944 10 Mg++ 0.9678110E-07 0.9956663E-07 0.2420586E-02 8.7012 11 Fe++ 0.5756623E-09 0.2482551E-08 0.1386386E-03 6.4756 12 K+ 0.4456936E-05 0.4458635E-05 0.1743359E+00 2.5134 13 Na+ 0.1863792E-03 0.1864326E-03 0.4285911E+01 4.1348 14 Mn++ 0.6107149E-07 0.7514647E-07 0.4128264E-02 8.5013 15 HPO4-- 0.9885886E-09 0.1199797E-08 0.1151516E-03 6.7106 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3346888E-03 -.7693480E-04 -.2577540E-03 0.0000000E+00 2 H2O 0.5550799E+02 0.5550784E+02 0.1452451E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2608645E-04 0.2550429E-04 0.5821608E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5819816E-06 0.1792122E-09 -.5821608E-06 0.0000000E+00 7 Al+++ 0.6847557E-04 0.3636054E-05 0.6483952E-04 0.0000000E+00 8 H4SiO4 0.2186684E-03 0.2023668E-03 0.1630169E-04 0.0000000E+00 9 Ca++ 0.3862406E-04 0.3841894E-04 0.2051155E-06 0.0000000E+00 10 Mg++ 0.1666667E-04 0.9956582E-07 0.1656710E-04 0.0000000E+00 11 Fe++ 0.1497318E-04 0.2482531E-08 0.1497070E-04 0.0000000E+00 12 K+ 0.4458599E-05 0.4458599E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1864311E-03 0.1864311E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3641105E-06 0.7514586E-07 0.2889647E-06 0.0000000E+00 15 HPO4-- 0.1242691E-06 0.1199788E-08 0.1230693E-06 0.0000000E+00 Chg. balance for solid moles: -.1302E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0210000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4102E-07 -7.387 0.2061E-04 -4.686 0.2950 0.6548E-05 clinochlore 0.3313E-05 -5.480 0.1842E-02 -2.735 26.37 0.7005E-03 daphnite 0.2063E-05 -5.686 0.1472E-02 -2.832 21.07 0.4460E-03 chlorite-Mn 0.5779E-07 -7.238 0.4097E-04 -4.387 0.5866 0.1306E-04 diaspore 0.5397E-04 -4.268 0.3238E-02 -2.490 46.36 0.9639E-03 hematite 0.2329E-05 -5.633 0.3719E-03 -3.430 5.324 0.7049E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6098E+00 0.6098E+00 1.0000 -0.215 daphnite 0.3796E+00 0.3796E+00 1.0000 -0.421 chlorite-Mn 0.1064E-01 0.1064E-01 1.0000 -1.973 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.006985 g Volume = 0.002201 cm3 Porosity: 99.7818% V(tot) - V(min): 0.10062E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0210000 g log = -1.6778 Original solution: 1000.0103000 g Original solution / Rock added: 47619.54 (Water/Rock Ratio), log = 4.6778 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3449E-04 1.0073 0.3655E-04 0.3628E-04 CH4,gas 0.5989E-14 1.0129 0.6381E-14 0.6300E-14 H2,gas 0.1108E-05 1.0006 0.1166E-05 0.1165E-05 H2S,gas 0.8396E-11 0.9959 0.8796E-11 0.8832E-11 S2,gas 0.2026E-29 1.0000 0.2132E-29 0.2132E-29 CO,gas 0.1049E-13 1.0000 0.1104E-13 0.1104E-13 SO3,gas 0.1374E-35 1.0000 0.1445E-35 0.1445E-35 SO2,gas 0.6059E-19 1.0000 0.6374E-19 0.6374E-19 HCl,gas 0.5470E-15 1.0000 0.5755E-15 0.5755E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.80 -6.44 -2.146 0.10991E+05 -4.437 3 CH4,gas 4.81 -11.39 -16.20 -4.049 0.27653E+05 -14.195 4 H2,gas 8.29 0.35 -7.93 -4.533 0.13546E+05 -5.933 5 H2S,gas -5.94 -19.00 -13.06 -6.528 0.22292E+05 -11.056 6 S2,gas -7.03 -38.70 -31.67 -4.873 0.54078E+05 -29.671 7 CO,gas 3.51 -12.45 -15.96 -4.910 0.27246E+05 -13.957 8 SO3,gas 17.43 -20.41 -37.84 -9.460 0.64611E+05 -35.840 9 SO2,gas 1.14 -20.06 -21.20 -5.652 0.36191E+05 -19.196 10 HCl,gas 5.48 -11.76 -17.24 -8.620 0.29437E+05 -15.240 11 acmite 7.74 2.98 -4.76 -0.494 0.81220E+04 15 albite-high 0.75 -4.15 -4.90 -0.377 0.83634E+04 16 albite -0.33 -4.15 -3.82 -0.294 0.65228E+04 19 spessartine 24.55 20.12 -4.43 -0.222 0.75696E+04 20 analcite 3.37 -0.42 -3.79 -0.421 0.64759E+04 21 andalusite 5.06 2.07 -3.00 -0.300 0.51167E+04 22 andradite 39.09 35.30 -3.79 -0.197 0.64648E+04 23 grossular 32.83 28.50 -4.33 -0.217 0.73969E+04 24 anhydrite -5.28 -9.12 -3.84 -1.919 0.65543E+04 29 anorthite 12.80 9.63 -3.16 -0.243 0.54024E+04 35 aragonite 0.99 -1.51 -2.49 -0.831 0.42553E+04 36 brucite 12.58 8.70 -3.88 -0.775 0.66171E+04 37 calcite 0.83 -1.51 -2.34 -0.780 0.39939E+04 40 carpholite-Mg 8.65 7.04 -1.61 -0.107 0.27489E+04 41 carpholite-Fe 6.78 4.81 -1.97 -0.131 0.33603E+04 50 chloritoid-Mg 13.26 10.77 -2.49 -0.166 0.42590E+04 51 chloritoid-Fe 9.24 8.54 -0.70 -0.046 0.11907E+04 52 chloritoid-Mn 11.46 10.57 -0.90 -0.060 0.15302E+04 54 coesite -2.37 -3.73 -1.36 -0.452 0.23172E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.73 -1.18 -0.392 0.20101E+04 67 diopside 16.22 12.54 -3.67 -0.367 0.62711E+04 68 hedenbergite 14.24 10.32 -3.93 -0.393 0.67058E+04 75 epidote 24.78 23.50 -1.27 -0.062 0.21766E+04 76 clinozoisite 22.92 20.10 -2.82 -0.128 0.48209E+04 77 epidote-Fe 29.94 26.90 -3.03 -0.158 0.51798E+04 78 fayalite 14.08 9.22 -4.85 -0.693 0.82884E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.97 -4.22 -0.352 0.72061E+04 91 heulandite -5.71 -9.00 -3.29 -0.150 0.56201E+04 95 jadeite 4.25 -0.42 -4.67 -0.467 0.79789E+04 98 kaolinite -1.27 -1.66 -0.39 -0.035 0.66181E+03 99 kyanite 4.93 2.07 -2.87 -0.287 0.48935E+04 101 laumontite 2.97 2.18 -0.79 -0.053 0.13553E+04 102 lawsonite 9.68 9.63 -0.04 -0.003 0.76292E+02 105 lizardite 23.29 18.65 -4.64 -0.386 0.79170E+04 106 magnesite 0.71 -4.10 -4.81 -1.603 0.82103E+04 107 magnetite 20.13 19.07 -1.06 -0.086 0.18092E+04 110 magnesioferrite 26.26 21.30 -4.96 -0.405 0.84664E+04 113 margarite 17.45 15.43 -2.03 -0.081 0.34592E+04 116 microcline -2.43 -5.77 -3.34 -0.257 0.56996E+04 120 muscovite 2.68 0.02 -2.66 -0.156 0.45365E+04 121 paragonite 4.34 1.64 -2.69 -0.158 0.45981E+04 136 prehnite 19.47 17.20 -2.26 -0.133 0.38668E+04 137 prehnite-Fe 22.59 20.60 -1.98 -0.119 0.33849E+04 138 pumpellyite-Fe 46.47 43.78 -2.70 -0.060 0.46025E+04 139 pumpellyite-Mg 49.19 46.00 -3.19 -0.071 0.54526E+04 145 pyroxmangite 7.42 4.77 -2.64 -0.528 0.45098E+04 146 pyrophyllite -6.10 -9.11 -3.02 -0.188 0.51491E+04 147 quartz -2.98 -3.73 -0.74 -0.248 0.12711E+04 152 rhodochrosite -0.96 -4.30 -3.34 -1.114 0.57039E+04 153 rhodonite 7.46 4.77 -2.69 -0.538 0.45890E+04 154 sanidine -1.22 -5.77 -4.55 -0.350 0.77674E+04 156 siderite -2.59 -6.32 -3.74 -1.246 0.63810E+04 157 sillimanite 5.32 2.07 -3.26 -0.326 0.55589E+04 164 stilbite -7.41 -9.00 -1.59 -0.076 0.27196E+04 165 stilpnomelane-Fe 13.18 9.62 -3.56 -0.106 0.60856E+04 169 sudoite 21.22 17.81 -3.41 -0.110 0.58204E+04 175 tephroite 18.11 13.28 -4.84 -0.691 0.82587E+04 178 topaz-H 4.67 2.07 -2.60 -0.237 0.44426E+04 179 tridymite -2.61 -3.73 -1.11 -0.371 0.18984E+04 188 wairakite 4.06 2.18 -1.88 -0.110 0.32062E+04 189 walstromite 11.53 7.57 -3.96 -0.792 0.67614E+04 190 wollastonite 10.48 7.57 -2.91 -0.583 0.49753E+04 191 pseudo-wollastonite 11.02 7.57 -3.45 -0.690 0.58939E+04 192 zoisite 22.96 20.10 -2.87 -0.130 0.48934E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.06 -3.50 -0.217 0.59846E+04 195 beidellite-H -2.24 -6.93 -4.69 -0.299 0.80031E+04 196 beidellite-K -1.44 -6.10 -4.66 -0.286 0.79632E+04 197 beidellite-Mg -1.71 -5.49 -3.79 -0.234 0.64639E+04 198 beidellite-Na -1.26 -5.56 -4.31 -0.264 0.73536E+04 200 chalcedony -2.79 -3.73 -0.93 -0.311 0.15915E+04 202 montmorillonite-Ca -2.21 -5.33 -3.12 -0.193 0.53279E+04 203 montmorillonite-K -2.16 -6.37 -4.21 -0.258 0.71843E+04 204 montmorillonite-Mg -2.40 -5.76 -3.36 -0.208 0.57382E+04 205 montmorillonite-Na -1.96 -5.83 -3.87 -0.237 0.66128E+04 206 nontronite-Ca 3.28 1.74 -1.54 -0.100 0.26275E+04 207 nontronite-H 2.60 -0.12 -2.72 -0.182 0.46418E+04 208 nontronite-K 3.40 0.71 -2.70 -0.173 0.46053E+04 209 nontronite-Mg 3.14 1.31 -1.83 -0.118 0.31184E+04 210 nontronite-Na 3.58 1.24 -2.34 -0.150 0.39974E+04 215 gypsum -4.92 -9.12 -4.19 -1.048 0.71611E+04 225 tobermorite 9.84 5.68 -4.16 -1.134 0.70983E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.48 -3.35 -0.837 0.57177E+04 241 silica-amorphous -2.08 -3.73 -1.65 -0.549 0.28117E+04 243 an20ab80 2.08 -1.39 -3.47 -0.267 0.59271E+04 244 an25ab75 2.71 -0.70 -3.41 -0.262 0.58261E+04 245 an30ab70 3.34 -0.01 -3.36 -0.258 0.57334E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0210000 g New total amount of reactant added: 0.0220000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0220000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3192566E-03 Osmotic coef. = 0.9894 True ionic strength = .3354799E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13073E-07 -7.8836 0.12532E-07 -7.9020 0.95866E+00 -0.0183 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13224E-03 -3.8786 0.95852E+00 -0.0184 4 SO4-- 0.25259E-04 -4.5976 0.22502E-04 -4.6478 0.89088E+00 -0.0502 5 HCO3- 0.12615E-04 -4.8991 0.12092E-04 -4.9175 0.95856E+00 -0.0184 6 HS- 0.61691E-11 -11.2098 0.59132E-11 -11.2282 0.95853E+00 -0.0184 7 Al+++ 0.19657E-20 -20.7065 0.15494E-20 -20.8098 0.78821E+00 -0.1034 8 H4SiO4 0.19601E-03 -3.7077 0.19601E-03 -3.7077 0.10000E+01 0.0000 9 Ca++ 0.39042E-04 -4.4085 0.34776E-04 -4.4587 0.89072E+00 -0.0503 10 Mg++ 0.86364E-07 -7.0637 0.76918E-07 -7.1140 0.89062E+00 -0.0503 11 Fe++ 0.51327E-09 -9.2897 0.45714E-09 -9.3400 0.89064E+00 -0.0503 12 K+ 0.46692E-05 -5.3308 0.44757E-05 -5.3491 0.95856E+00 -0.0184 13 Na+ 0.18763E-03 -3.7267 0.17985E-03 -3.7451 0.95852E+00 -0.0184 14 Mn++ 0.56092E-07 -7.2511 0.49959E-07 -7.3014 0.89066E+00 -0.0503 15 HPO4-- 0.88954E-09 -9.0508 0.79247E-09 -9.1010 0.89088E+00 -0.0502 16 HSiO3- 0.15921E-04 -4.7980 0.15260E-04 -4.8164 0.95852E+00 -0.0184 17 Ca(HSiO3)+ 0.12404E-07 -7.9064 0.11890E-07 -7.9248 0.95857E+00 -0.0184 18 Mg(HSiO3)+ 0.34144E-10 -10.4667 0.32729E-10 -10.4851 0.95857E+00 -0.0184 19 NaHSiO3,aq 0.43590E-07 -7.3606 0.43590E-07 -7.3606 0.10000E+01 0.0000 20 AlO+ 0.13286E-11 -11.8766 0.12736E-11 -11.8950 0.95857E+00 -0.0184 21 AlOH+2 0.89766E-16 -16.0469 0.79953E-16 -16.0972 0.89068E+00 -0.0503 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.37803E-05 -5.4225 0.36233E-05 -5.4409 0.95848E+00 -0.0184 24 CH4,aq 0.31184E-17 -17.5061 0.31181E-17 -17.5061 0.99990E+00 0.0000 29 CO,aq 0.63416E-17 -17.1978 0.63416E-17 -17.1978 0.10000E+01 0.0000 30 CO2,aq 0.30557E-06 -6.5149 0.30554E-06 -6.5149 0.99990E+00 0.0000 31 CO3-2 0.10015E-06 -6.9994 0.89216E-07 -7.0496 0.89083E+00 -0.0502 32 CaCO3,aq 0.37999E-07 -7.4202 0.37999E-07 -7.4202 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.11054E-07 -7.9565 0.10596E-07 -7.9749 0.95857E+00 -0.0184 34 CaCl+ 0.76447E-08 -8.1166 0.73279E-08 -8.1350 0.95857E+00 -0.0184 35 CaCl2,aq 0.22562E-12 -12.6466 0.22562E-12 -12.6466 0.10000E+01 0.0000 36 CaOH+ 0.20413E-06 -6.6901 0.19567E-06 -6.7085 0.95857E+00 -0.0184 37 CaSO4,aq 0.24382E-06 -6.6129 0.24382E-06 -6.6129 0.10000E+01 0.0000 38 HCl,aq 0.31172E-12 -12.5062 0.31172E-12 -12.5062 0.10000E+01 0.0000 43 FeCl+ 0.98223E-13 -13.0078 0.94153E-13 -13.0262 0.95857E+00 -0.0184 46 FeO,aq 0.11510E-09 -9.9389 0.11510E-09 -9.9389 0.10000E+01 0.0000 47 FeOH+ 0.12616E-08 -8.8991 0.12093E-08 -8.9175 0.95857E+00 -0.0184 48 HFeO2- 0.10306E-09 -9.9869 0.98789E-10 -10.0053 0.95852E+00 -0.0184 49 FeO+ 0.10815E-12 -12.9660 0.10367E-12 -12.9844 0.95857E+00 -0.0184 50 FeOH+2 0.27142E-18 -18.5664 0.24175E-18 -18.6166 0.89068E+00 -0.0503 51 FeO2- 0.13535E-09 -9.8686 0.12973E-09 -9.8870 0.95852E+00 -0.0184 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.80593E-09 -9.0937 0.80585E-09 -9.0937 0.99990E+00 0.0000 54 KCl,aq 0.10480E-10 -10.9797 0.10480E-10 -10.9797 0.10000E+01 0.0000 55 KHSO4,aq 0.33775E-17 -17.4714 0.33775E-17 -17.4714 0.10000E+01 0.0000 56 KOH,aq 0.15569E-09 -9.8077 0.15569E-09 -9.8077 0.10000E+01 0.0000 57 KSO4- 0.16188E-08 -8.7908 0.15516E-08 -8.8092 0.95852E+00 -0.0184 58 MgCO3,aq 0.21001E-10 -10.6778 0.21001E-10 -10.6778 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24932E-10 -10.6032 0.23899E-10 -10.6216 0.95857E+00 -0.0184 60 MgCl+ 0.15350E-10 -10.8139 0.14714E-10 -10.8323 0.95857E+00 -0.0184 61 MgOH+ 0.25013E-08 -8.6018 0.23976E-08 -8.6202 0.95857E+00 -0.0184 63 MnO,aq 0.33580E-09 -9.4739 0.33580E-09 -9.4739 0.10000E+01 0.0000 64 MnOH+ 0.12808E-07 -7.8925 0.12277E-07 -7.9109 0.95857E+00 -0.0184 65 MnO2-2 0.83004E-16 -16.0809 0.73943E-16 -16.1311 0.89083E+00 -0.0502 66 HMnO2- 0.20946E-12 -12.6789 0.20077E-12 -12.6973 0.95852E+00 -0.0184 69 MnCl+ 0.41712E-10 -10.3797 0.39984E-10 -10.3981 0.95857E+00 -0.0184 70 MnSO4,aq 0.31860E-09 -9.4968 0.31860E-09 -9.4968 0.10000E+01 0.0000 71 NaCl,aq 0.77656E-08 -8.1098 0.77656E-08 -8.1098 0.10000E+01 0.0000 72 NaOH,aq 0.63059E-08 -8.2003 0.63059E-08 -8.2003 0.10000E+01 0.0000 74 OH- 0.49937E-04 -4.3016 0.47864E-04 -4.3200 0.95848E+00 -0.0184 82 H3PO4,aq 0.80128E-15 -15.0962 0.80128E-15 -15.0962 0.10000E+01 0.0000 83 H2PO4- 0.18165E-09 -9.7408 0.17412E-09 -9.7592 0.95854E+00 -0.0184 84 PO4-3 0.69977E-13 -13.1550 0.55224E-13 -13.2579 0.78917E+00 -0.1028 88 HP2O7-3 0.49254E-19 -19.3076 0.38823E-19 -19.4109 0.78822E+00 -0.1034 90 H2S,aq 0.22268E-12 -12.6523 0.22265E-12 -12.6524 0.99990E+00 0.0000 96 SO2,aq 0.11932E-19 -19.9233 0.11932E-19 -19.9233 0.10000E+01 0.0000 97 SO3-2 0.27745E-14 -14.5568 0.24725E-14 -14.6069 0.89115E+00 -0.0500 98 HSO3- 0.18918E-14 -14.7231 0.18133E-14 -14.7415 0.95852E+00 -0.0184 99 HSO4- 0.27296E-09 -9.5639 0.26166E-09 -9.5823 0.95859E+00 -0.0184 101 S2O3-2 0.66285E-19 -19.1786 0.59049E-19 -19.2288 0.89083E+00 -0.0502 Charge balance for all species = 0.2080E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1307250E-07 -.8114450E-04 -.8178608E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999654E+06 0.0000 3 Cl- 0.1379599E-03 0.1379753E-03 0.4891478E+01 4.0233 4 SO4-- 0.2525865E-04 0.2550452E-04 0.2449924E+01 11.1562 5 HCO3- 0.1261529E-04 0.1307011E-04 0.7974751E+00 2.9845 6 HS- 0.6169075E-11 0.1655110E-09 0.5473599E-05 -3.3262 7 Al+++ 0.1965711E-20 0.3800649E-05 0.1025438E+00 2.8961 8 H4SiO4 0.1960134E-03 0.2119901E-03 0.2037484E+02 -3.7077 9 Ca++ 0.3904229E-04 0.3955934E-04 0.1585407E+01 11.3452 10 Mg++ 0.8636408E-07 0.8896077E-07 0.2162743E-02 8.6900 11 Fe++ 0.5132682E-09 0.2332040E-08 0.1302331E-03 6.4640 12 K+ 0.4669168E-05 0.4670952E-05 0.1826375E+00 2.5528 13 Na+ 0.1876303E-03 0.1876879E-03 0.4314765E+01 4.1569 14 Mn++ 0.5609183E-07 0.6959612E-07 0.3823345E-02 8.5026 15 HPO4-- 0.8895363E-09 0.1071254E-08 0.1028145E-03 6.7029 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3512473E-03 -.8114381E-04 -.2701035E-03 0.0000000E+00 2 H2O 0.5550797E+02 0.5550782E+02 0.1521886E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2611416E-04 0.2550430E-04 0.6098605E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6096950E-06 0.1655096E-09 -.6098605E-06 0.0000000E+00 7 Al+++ 0.7173632E-04 0.3800617E-05 0.6793570E-04 0.0000000E+00 8 H4SiO4 0.2290812E-03 0.2119883E-03 0.1709291E-04 0.0000000E+00 9 Ca++ 0.3977420E-04 0.3955901E-04 0.2151924E-06 0.0000000E+00 10 Mg++ 0.1746032E-04 0.8896002E-07 0.1737136E-04 0.0000000E+00 11 Fe++ 0.1568619E-04 0.2332020E-08 0.1568386E-04 0.0000000E+00 12 K+ 0.4670913E-05 0.4670913E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1876864E-03 0.1876864E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3814491E-06 0.6959553E-07 0.3118536E-06 0.0000000E+00 15 HPO4-- 0.1301867E-06 0.1071245E-08 0.1291154E-06 0.0000000E+00 Chg. balance for solid moles: -.1271E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0220000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4304E-07 -7.366 0.2162E-04 -4.665 0.2953 0.6870E-05 clinochlore 0.3474E-05 -5.459 0.1931E-02 -2.714 26.38 0.7345E-03 daphnite 0.2161E-05 -5.665 0.1542E-02 -2.812 21.06 0.4672E-03 chlorite-Mn 0.6237E-07 -7.205 0.4422E-04 -4.354 0.6041 0.1409E-04 diaspore 0.5654E-04 -4.248 0.3392E-02 -2.470 46.34 0.1010E-02 hematite 0.2439E-05 -5.613 0.3896E-03 -3.409 5.322 0.7384E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6098E+00 0.6098E+00 1.0000 -0.215 daphnite 0.3793E+00 0.3793E+00 1.0000 -0.421 chlorite-Mn 0.1095E-01 0.1095E-01 1.0000 -1.961 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.007320 g Volume = 0.002306 cm3 Porosity: 99.7714% V(tot) - V(min): 0.10065E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0220000 g log = -1.6576 Original solution: 1000.0103000 g Original solution / Rock added: 45455.01 (Water/Rock Ratio), log = 4.6576 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3301E-04 1.0073 0.3497E-04 0.3472E-04 CH4,gas 0.4628E-14 1.0129 0.4931E-14 0.4868E-14 H2,gas 0.1050E-05 1.0006 0.1105E-05 0.1105E-05 H2S,gas 0.6198E-11 0.9959 0.6494E-11 0.6520E-11 S2,gas 0.1229E-29 1.0000 0.1293E-29 0.1293E-29 CO,gas 0.9519E-14 1.0000 0.1001E-13 0.1001E-13 SO3,gas 0.1256E-35 1.0000 0.1321E-35 0.1321E-35 SO2,gas 0.5252E-19 1.0000 0.5524E-19 0.5524E-19 HCl,gas 0.5232E-15 1.0000 0.5504E-15 0.5504E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 102 lawsonite 9.68 9.72 0.04 0.003 -0.74449E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.82 -6.46 -2.152 0.11024E+05 -4.456 3 CH4,gas 4.81 -11.50 -16.31 -4.077 0.27844E+05 -14.307 4 H2,gas 8.29 0.33 -7.96 -4.547 0.13586E+05 -5.957 5 H2S,gas -5.94 -19.13 -13.19 -6.594 0.22517E+05 -11.187 6 S2,gas -7.03 -38.92 -31.89 -4.906 0.54449E+05 -29.888 7 CO,gas 3.51 -12.49 -16.00 -4.923 0.27319E+05 -13.999 8 SO3,gas 17.43 -20.45 -37.88 -9.470 0.64677E+05 -35.879 9 SO2,gas 1.14 -20.12 -21.26 -5.669 0.36297E+05 -19.258 10 HCl,gas 5.48 -11.78 -17.26 -8.630 0.29470E+05 -15.259 11 acmite 7.74 3.04 -4.70 -0.488 0.80202E+04 15 albite-high 0.75 -4.07 -4.82 -0.371 0.82297E+04 16 albite -0.33 -4.07 -3.74 -0.288 0.63890E+04 19 spessartine 24.55 20.18 -4.37 -0.219 0.74671E+04 20 analcite 3.37 -0.36 -3.73 -0.415 0.63742E+04 21 andalusite 5.06 2.08 -2.98 -0.298 0.50847E+04 22 andradite 39.09 35.51 -3.58 -0.186 0.61086E+04 23 grossular 32.83 28.70 -4.12 -0.206 0.70407E+04 24 anhydrite -5.28 -9.11 -3.83 -1.913 0.65341E+04 29 anorthite 12.80 9.72 -3.08 -0.237 0.52517E+04 35 aragonite 0.99 -1.47 -2.46 -0.820 0.42012E+04 36 brucite 12.58 8.69 -3.89 -0.777 0.66363E+04 37 calcite 0.83 -1.47 -2.31 -0.769 0.39398E+04 40 carpholite-Mg 8.65 7.07 -1.58 -0.106 0.27040E+04 41 carpholite-Fe 6.78 4.84 -1.94 -0.129 0.33162E+04 50 chloritoid-Mg 13.26 10.77 -2.49 -0.166 0.42461E+04 51 chloritoid-Fe 9.24 8.55 -0.69 -0.046 0.11785E+04 52 chloritoid-Mn 11.46 10.59 -0.88 -0.058 0.14961E+04 54 coesite -2.37 -3.71 -1.34 -0.446 0.22852E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.71 -1.16 -0.386 0.19781E+04 67 diopside 16.22 12.62 -3.60 -0.360 0.61396E+04 68 hedenbergite 14.24 10.39 -3.85 -0.385 0.65748E+04 75 epidote 24.78 23.66 -1.12 -0.054 0.19071E+04 76 clinozoisite 22.92 20.26 -2.67 -0.121 0.45514E+04 77 epidote-Fe 29.94 27.06 -2.88 -0.149 0.49103E+04 78 fayalite 14.08 9.22 -4.86 -0.694 0.82961E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.98 -4.22 -0.351 0.72015E+04 91 heulandite -5.71 -8.82 -3.11 -0.141 0.53093E+04 95 jadeite 4.25 -0.36 -4.61 -0.461 0.78772E+04 98 kaolinite -1.27 -1.62 -0.35 -0.032 0.59780E+03 99 kyanite 4.93 2.08 -2.85 -0.285 0.48615E+04 101 laumontite 2.97 2.31 -0.67 -0.045 0.11406E+04 105 lizardite 23.29 18.65 -4.63 -0.386 0.79106E+04 106 magnesite 0.71 -4.13 -4.84 -1.613 0.82621E+04 107 magnetite 20.13 19.06 -1.07 -0.087 0.18290E+04 110 magnesioferrite 26.26 21.29 -4.97 -0.406 0.84856E+04 113 margarite 17.45 15.51 -1.94 -0.078 0.33085E+04 116 microcline -2.43 -5.67 -3.24 -0.249 0.55364E+04 120 muscovite 2.68 0.12 -2.56 -0.151 0.43732E+04 121 paragonite 4.34 1.72 -2.61 -0.154 0.44644E+04 136 prehnite 19.47 17.36 -2.11 -0.124 0.35974E+04 137 prehnite-Fe 22.59 20.76 -1.82 -0.110 0.31154E+04 138 pumpellyite-Fe 46.47 44.08 -2.39 -0.053 0.40834E+04 139 pumpellyite-Mg 49.19 46.31 -2.89 -0.064 0.49329E+04 145 pyroxmangite 7.42 4.79 -2.62 -0.524 0.44756E+04 146 pyrophyllite -6.10 -9.04 -2.94 -0.184 0.50211E+04 147 quartz -2.98 -3.71 -0.73 -0.242 0.12391E+04 152 rhodochrosite -0.96 -4.32 -3.36 -1.119 0.57343E+04 153 rhodonite 7.46 4.79 -2.67 -0.534 0.45548E+04 154 sanidine -1.22 -5.67 -4.45 -0.343 0.76041E+04 156 siderite -2.59 -6.36 -3.77 -1.256 0.64334E+04 157 sillimanite 5.32 2.08 -3.24 -0.324 0.55269E+04 164 stilbite -7.41 -8.82 -1.41 -0.067 0.24088E+04 165 stilpnomelane-Fe 13.18 9.73 -3.45 -0.103 0.58950E+04 169 sudoite 21.22 17.84 -3.38 -0.109 0.57628E+04 175 tephroite 18.11 13.30 -4.82 -0.688 0.82223E+04 178 topaz-H 4.67 2.08 -2.58 -0.235 0.44106E+04 179 tridymite -2.61 -3.71 -1.09 -0.364 0.18664E+04 188 wairakite 4.06 2.31 -1.75 -0.103 0.29914E+04 189 walstromite 11.53 7.64 -3.89 -0.778 0.66427E+04 190 wollastonite 10.48 7.64 -2.84 -0.569 0.48566E+04 191 pseudo-wollastonite 11.02 7.64 -3.38 -0.676 0.57752E+04 192 zoisite 22.96 20.26 -2.71 -0.123 0.46239E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.99 -3.43 -0.212 0.58529E+04 195 beidellite-H -2.24 -6.86 -4.62 -0.295 0.78857E+04 196 beidellite-K -1.44 -6.02 -4.58 -0.281 0.78236E+04 197 beidellite-Mg -1.71 -5.43 -3.72 -0.230 0.63496E+04 198 beidellite-Na -1.26 -5.49 -4.23 -0.259 0.72237E+04 200 chalcedony -2.79 -3.71 -0.91 -0.304 0.15595E+04 202 montmorillonite-Ca -2.21 -5.25 -3.04 -0.188 0.51919E+04 203 montmorillonite-K -2.16 -6.28 -4.12 -0.252 0.70404E+04 204 montmorillonite-Mg -2.40 -5.69 -3.29 -0.204 0.56197E+04 205 montmorillonite-Na -1.96 -5.75 -3.79 -0.232 0.64787E+04 206 nontronite-Ca 3.28 1.82 -1.46 -0.095 0.24958E+04 207 nontronite-H 2.60 -0.05 -2.65 -0.178 0.45243E+04 208 nontronite-K 3.40 0.79 -2.62 -0.168 0.44657E+04 209 nontronite-Mg 3.14 1.38 -1.76 -0.114 0.30041E+04 210 nontronite-Na 3.58 1.32 -2.27 -0.145 0.38675E+04 215 gypsum -4.92 -9.11 -4.18 -1.046 0.71408E+04 225 tobermorite 9.84 5.74 -4.10 -1.118 0.69941E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.46 -3.36 -0.840 0.57375E+04 241 silica-amorphous -2.08 -3.71 -1.63 -0.543 0.27797E+04 243 an20ab80 2.08 -1.31 -3.39 -0.261 0.57900E+04 244 an25ab75 2.71 -0.62 -3.33 -0.256 0.56881E+04 245 an30ab70 3.34 0.07 -3.28 -0.252 0.55946E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0220000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3166426E-03 Osmotic coef. = 0.9894 True ionic strength = .3323386E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13452E-07 -7.8712 0.12897E-07 -7.8895 0.95877E+00 -0.0183 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13225E-03 -3.8786 0.95863E+00 -0.0183 4 SO4-- 0.25265E-04 -4.5975 0.22518E-04 -4.6475 0.89127E+00 -0.0500 5 HCO3- 0.12612E-04 -4.8992 0.12090E-04 -4.9176 0.95866E+00 -0.0183 6 HS- 0.66180E-11 -11.1793 0.63442E-11 -11.1976 0.95863E+00 -0.0183 7 Al+++ 0.21405E-20 -20.6695 0.16889E-20 -20.7724 0.78900E+00 -0.1029 8 H4SiO4 0.19445E-03 -3.7112 0.19445E-03 -3.7112 0.10000E+01 0.0000 9 Ca++ 0.37989E-04 -4.4203 0.33853E-04 -4.4704 0.89112E+00 -0.0501 10 Mg++ 0.91871E-07 -7.0368 0.81859E-07 -7.0869 0.89102E+00 -0.0501 11 Fe++ 0.54617E-09 -9.2627 0.48666E-09 -9.3128 0.89104E+00 -0.0501 12 K+ 0.46692E-05 -5.3308 0.44762E-05 -5.3491 0.95867E+00 -0.0183 13 Na+ 0.18763E-03 -3.7267 0.17987E-03 -3.7450 0.95863E+00 -0.0184 14 Mn++ 0.59059E-07 -7.2287 0.52625E-07 -7.2788 0.89106E+00 -0.0501 15 HPO4-- 0.96623E-09 -9.0149 0.86118E-09 -9.0649 0.89128E+00 -0.0500 16 HSiO3- 0.15345E-04 -4.8140 0.14710E-04 -4.8324 0.95863E+00 -0.0183 17 Ca(HSiO3)+ 0.11638E-07 -7.9341 0.11157E-07 -7.9525 0.95867E+00 -0.0183 18 Mg(HSiO3)+ 0.35023E-10 -10.4557 0.33575E-10 -10.4740 0.95867E+00 -0.0183 19 NaHSiO3,aq 0.42022E-07 -7.3765 0.42022E-07 -7.3765 0.10000E+01 0.0000 20 AlO+ 0.13672E-11 -11.8642 0.13107E-11 -11.8825 0.95867E+00 -0.0183 21 AlOH+2 0.95032E-16 -16.0221 0.84682E-16 -16.0722 0.89108E+00 -0.0501 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.36728E-05 -5.4350 0.35207E-05 -5.4534 0.95859E+00 -0.0184 24 CH4,aq 0.33428E-17 -17.4759 0.33425E-17 -17.4759 0.99990E+00 0.0000 29 CO,aq 0.65924E-17 -17.1810 0.65924E-17 -17.1810 0.10000E+01 0.0000 30 CO2,aq 0.31443E-06 -6.5025 0.31439E-06 -6.5025 0.99990E+00 0.0000 31 CO3-2 0.97252E-07 -7.0121 0.86674E-07 -7.0621 0.89123E+00 -0.0500 32 CaCO3,aq 0.35936E-07 -7.4445 0.35936E-07 -7.4445 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10757E-07 -7.9683 0.10313E-07 -7.9866 0.95867E+00 -0.0183 34 CaCl+ 0.74417E-08 -8.1283 0.71342E-08 -8.1467 0.95867E+00 -0.0183 35 CaCl2,aq 0.21968E-12 -12.6582 0.21968E-12 -12.6582 0.10000E+01 0.0000 36 CaOH+ 0.19306E-06 -6.7143 0.18508E-06 -6.7326 0.95867E+00 -0.0183 37 CaSO4,aq 0.23751E-06 -6.6243 0.23751E-06 -6.6243 0.10000E+01 0.0000 38 HCl,aq 0.32084E-12 -12.4937 0.32084E-12 -12.4937 0.10000E+01 0.0000 43 FeCl+ 0.10457E-12 -12.9806 0.10024E-12 -12.9989 0.95867E+00 -0.0183 46 FeO,aq 0.11569E-09 -9.9367 0.11569E-09 -9.9367 0.10000E+01 0.0000 47 FeOH+ 0.13049E-08 -8.8844 0.12509E-08 -8.9028 0.95867E+00 -0.0183 48 HFeO2- 0.10065E-09 -9.9972 0.96483E-10 -10.0155 0.95863E+00 -0.0183 49 FeO+ 0.11129E-12 -12.9536 0.10669E-12 -12.9719 0.95867E+00 -0.0183 50 FeOH+2 0.28735E-18 -18.5416 0.25605E-18 -18.5917 0.89108E+00 -0.0501 51 FeO2- 0.13150E-09 -9.8811 0.12606E-09 -9.8994 0.95863E+00 -0.0183 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.81422E-09 -9.0893 0.81414E-09 -9.0893 0.99990E+00 0.0000 54 KCl,aq 0.10482E-10 -10.9796 0.10482E-10 -10.9796 0.10000E+01 0.0000 55 KHSO4,aq 0.34787E-17 -17.4586 0.34787E-17 -17.4586 0.10000E+01 0.0000 56 KOH,aq 0.15130E-09 -9.8202 0.15130E-09 -9.8202 0.10000E+01 0.0000 57 KSO4- 0.16199E-08 -8.7905 0.15529E-08 -8.8089 0.95863E+00 -0.0183 58 MgCO3,aq 0.21714E-10 -10.6633 0.21714E-10 -10.6633 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26526E-10 -10.5763 0.25430E-10 -10.5947 0.95867E+00 -0.0183 60 MgCl+ 0.16336E-10 -10.7869 0.15661E-10 -10.8052 0.95867E+00 -0.0183 61 MgOH+ 0.25863E-08 -8.5873 0.24794E-08 -8.6057 0.95867E+00 -0.0183 63 MnO,aq 0.33397E-09 -9.4763 0.33397E-09 -9.4763 0.10000E+01 0.0000 64 MnOH+ 0.13108E-07 -7.8825 0.12566E-07 -7.9008 0.95867E+00 -0.0183 65 MnO2-2 0.77908E-16 -16.1084 0.69433E-16 -16.1584 0.89123E+00 -0.0500 66 HMnO2- 0.20240E-12 -12.6938 0.19402E-12 -12.7121 0.95863E+00 -0.0183 69 MnCl+ 0.43938E-10 -10.3572 0.42123E-10 -10.3755 0.95867E+00 -0.0183 70 MnSO4,aq 0.33583E-09 -9.4739 0.33583E-09 -9.4739 0.10000E+01 0.0000 71 NaCl,aq 0.77674E-08 -8.1097 0.77674E-08 -8.1097 0.10000E+01 0.0000 72 NaOH,aq 0.61280E-08 -8.2127 0.61280E-08 -8.2127 0.10000E+01 0.0000 74 OH- 0.48517E-04 -4.3141 0.46508E-04 -4.3325 0.95859E+00 -0.0184 82 H3PO4,aq 0.92225E-15 -15.0352 0.92225E-15 -15.0352 0.10000E+01 0.0000 83 H2PO4- 0.20313E-09 -9.6922 0.19473E-09 -9.7106 0.95865E+00 -0.0183 84 PO4-3 0.73817E-13 -13.1318 0.58313E-13 -13.2342 0.78996E+00 -0.1024 88 HP2O7-3 0.59801E-19 -19.2233 0.47184E-19 -19.3262 0.78901E+00 -0.1029 90 H2S,aq 0.24587E-12 -12.6093 0.24584E-12 -12.6093 0.99990E+00 0.0000 96 SO2,aq 0.12777E-19 -19.8936 0.12777E-19 -19.8936 0.10000E+01 0.0000 97 SO3-2 0.28038E-14 -14.5523 0.24997E-14 -14.6021 0.89155E+00 -0.0499 98 HSO3- 0.19681E-14 -14.7059 0.18867E-14 -14.7243 0.95863E+00 -0.0183 99 HSO4- 0.28108E-09 -9.5512 0.26947E-09 -9.5695 0.95870E+00 -0.0183 101 S2O3-2 0.73207E-19 -19.1354 0.65244E-19 -19.1855 0.89123E+00 -0.0500 Charge balance for all species = 0.2084E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1345203E-07 -.7869138E-04 -.7931359E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999656E+06 0.0000 3 Cl- 0.1379601E-03 0.1379753E-03 0.4891479E+01 4.0109 4 SO4-- 0.2526493E-04 0.2550452E-04 0.2449924E+01 11.1315 5 HCO3- 0.1261169E-04 0.1307011E-04 0.7974753E+00 2.9719 6 HS- 0.6617957E-11 0.1685356E-09 0.5573627E-05 -3.3081 7 Al+++ 0.2140494E-20 0.3693175E-05 0.9964412E-01 2.8961 8 H4SiO4 0.1944485E-03 0.2098468E-03 0.2016884E+02 -3.7112 9 Ca++ 0.3798880E-04 0.3848514E-04 0.1542357E+01 11.3086 10 Mg++ 0.9187094E-07 0.9455682E-07 0.2298790E-02 8.6921 11 Fe++ 0.5461672E-09 0.2402558E-08 0.1341712E-03 6.4662 12 K+ 0.4669171E-05 0.4670952E-05 0.1826376E+00 2.5404 13 Na+ 0.1876320E-03 0.1876879E-03 0.4314766E+01 4.1445 14 Mn++ 0.5905900E-07 0.7288092E-07 0.4003800E-02 8.5002 15 HPO4-- 0.9662336E-09 0.1169436E-08 0.1122376E-03 6.7141 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3512473E-03 -.7869072E-04 -.2725566E-03 0.0000000E+00 2 H2O 0.5550797E+02 0.5550782E+02 0.1502512E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2611416E-04 0.2550430E-04 0.6098635E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6096950E-06 0.1685342E-09 -.6098635E-06 0.0000000E+00 7 Al+++ 0.7173632E-04 0.3693144E-05 0.6804317E-04 0.0000000E+00 8 H4SiO4 0.2290812E-03 0.2098450E-03 0.1923623E-04 0.0000000E+00 9 Ca++ 0.3977420E-04 0.3848482E-04 0.1289383E-05 0.0000000E+00 10 Mg++ 0.1746032E-04 0.9455602E-07 0.1736576E-04 0.0000000E+00 11 Fe++ 0.1568619E-04 0.2402538E-08 0.1568379E-04 0.0000000E+00 12 K+ 0.4670913E-05 0.4670913E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1876864E-03 0.1876864E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3814491E-06 0.7288031E-07 0.3085688E-06 0.0000000E+00 15 HPO4-- 0.1301867E-06 0.1169426E-08 0.1290173E-06 0.0000000E+00 Chg. balance for solid moles: 0.3081E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0220000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4301E-07 -7.366 0.2160E-04 -4.665 0.2867 0.6865E-05 clinochlore 0.3473E-05 -5.459 0.1930E-02 -2.714 25.62 0.7343E-03 daphnite 0.2161E-05 -5.665 0.1542E-02 -2.812 20.46 0.4672E-03 chlorite-Mn 0.6171E-07 -7.210 0.4375E-04 -4.359 0.5807 0.1394E-04 diaspore 0.5450E-04 -4.264 0.3270E-02 -2.486 43.40 0.9734E-03 hematite 0.2439E-05 -5.613 0.3896E-03 -3.409 5.171 0.7384E-04 lawsonite 0.1074E-05 -5.969 0.3376E-03 -3.472 4.481 0.1089E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6098E+00 0.6098E+00 1.0000 -0.215 daphnite 0.3794E+00 0.3794E+00 1.0000 -0.421 chlorite-Mn 0.1083E-01 0.1083E-01 1.0000 -1.965 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.007535 g Volume = 0.002378 cm3 Porosity: 99.7642% V(tot) - V(min): 0.10064E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0220000 g log = -1.6576 Original solution: 1000.0103000 g Original solution / Rock added: 45455.01 (Water/Rock Ratio), log = 4.6576 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3396E-04 1.0073 0.3599E-04 0.3573E-04 CH4,gas 0.4961E-14 1.0129 0.5286E-14 0.5218E-14 H2,gas 0.1061E-05 1.0006 0.1117E-05 0.1116E-05 H2S,gas 0.6844E-11 0.9959 0.7170E-11 0.7200E-11 S2,gas 0.1468E-29 1.0000 0.1544E-29 0.1544E-29 CO,gas 0.9895E-14 1.0000 0.1041E-13 0.1041E-13 SO3,gas 0.1331E-35 1.0000 0.1400E-35 0.1400E-35 SO2,gas 0.5623E-19 1.0000 0.5915E-19 0.5915E-19 HCl,gas 0.5385E-15 1.0000 0.5665E-15 0.5665E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.81 -6.44 -2.148 0.11003E+05 -4.444 3 CH4,gas 4.81 -11.47 -16.28 -4.069 0.27792E+05 -14.277 4 H2,gas 8.29 0.33 -7.95 -4.544 0.13578E+05 -5.952 5 H2S,gas -5.94 -19.09 -13.14 -6.572 0.22444E+05 -11.144 6 S2,gas -7.03 -38.84 -31.81 -4.894 0.54317E+05 -29.811 7 CO,gas 3.51 -12.47 -15.98 -4.918 0.27290E+05 -13.983 8 SO3,gas 17.43 -20.43 -37.85 -9.463 0.64634E+05 -35.854 9 SO2,gas 1.14 -20.09 -21.23 -5.661 0.36246E+05 -19.228 10 HCl,gas 5.48 -11.77 -17.25 -8.623 0.29448E+05 -15.247 11 acmite 7.74 3.02 -4.72 -0.490 0.80533E+04 15 albite-high 0.75 -4.09 -4.84 -0.373 0.82687E+04 16 albite -0.33 -4.09 -3.76 -0.290 0.64281E+04 19 spessartine 24.55 20.16 -4.39 -0.220 0.74971E+04 20 analcite 3.37 -0.38 -3.75 -0.417 0.64073E+04 21 andalusite 5.06 2.08 -2.98 -0.298 0.50906E+04 22 andradite 39.09 35.39 -3.70 -0.192 0.63141E+04 23 grossular 32.83 28.58 -4.24 -0.212 0.72462E+04 24 anhydrite -5.28 -9.12 -3.84 -1.919 0.65535E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.50 -2.48 -0.828 0.42425E+04 36 brucite 12.58 8.69 -3.88 -0.777 0.66327E+04 37 calcite 0.83 -1.50 -2.33 -0.777 0.39812E+04 40 carpholite-Mg 8.65 7.06 -1.59 -0.106 0.27124E+04 41 carpholite-Fe 6.78 4.84 -1.95 -0.130 0.33242E+04 50 chloritoid-Mg 13.26 10.77 -2.49 -0.166 0.42485E+04 51 chloritoid-Fe 9.24 8.55 -0.69 -0.046 0.11807E+04 52 chloritoid-Mn 11.46 10.58 -0.88 -0.059 0.15061E+04 54 coesite -2.37 -3.71 -1.34 -0.447 0.22912E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.71 -1.16 -0.387 0.19841E+04 67 diopside 16.22 12.58 -3.64 -0.364 0.62104E+04 68 hedenbergite 14.24 10.35 -3.89 -0.389 0.66455E+04 75 epidote 24.78 23.57 -1.20 -0.058 0.20500E+04 76 clinozoisite 22.92 20.17 -2.75 -0.125 0.46943E+04 77 epidote-Fe 29.94 26.98 -2.96 -0.154 0.50532E+04 78 fayalite 14.08 9.22 -4.86 -0.694 0.82944E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.98 -4.22 -0.351 0.72020E+04 91 heulandite -5.71 -8.88 -3.17 -0.144 0.54135E+04 95 jadeite 4.25 -0.38 -4.63 -0.463 0.79103E+04 98 kaolinite -1.27 -1.63 -0.36 -0.032 0.60969E+03 99 kyanite 4.93 2.08 -2.85 -0.285 0.48674E+04 101 laumontite 2.97 2.26 -0.72 -0.048 0.12269E+04 105 lizardite 23.29 18.65 -4.63 -0.386 0.79118E+04 106 magnesite 0.71 -4.11 -4.82 -1.608 0.82374E+04 107 magnetite 20.13 19.06 -1.07 -0.087 0.18252E+04 110 magnesioferrite 26.26 21.29 -4.97 -0.406 0.84820E+04 113 margarite 17.45 15.47 -1.98 -0.079 0.33829E+04 116 microcline -2.43 -5.70 -3.27 -0.251 0.55754E+04 120 muscovite 2.68 0.10 -2.58 -0.152 0.44123E+04 121 paragonite 4.34 1.70 -2.64 -0.155 0.45034E+04 136 prehnite 19.47 17.28 -2.19 -0.129 0.37403E+04 137 prehnite-Fe 22.59 20.68 -1.91 -0.115 0.32583E+04 138 pumpellyite-Fe 46.47 43.91 -2.56 -0.057 0.43655E+04 139 pumpellyite-Mg 49.19 46.14 -3.05 -0.068 0.52152E+04 145 pyroxmangite 7.42 4.79 -2.63 -0.525 0.44856E+04 146 pyrophyllite -6.10 -9.05 -2.95 -0.185 0.50449E+04 147 quartz -2.98 -3.71 -0.73 -0.243 0.12451E+04 152 rhodochrosite -0.96 -4.31 -3.35 -1.116 0.57172E+04 153 rhodonite 7.46 4.79 -2.67 -0.535 0.45648E+04 154 sanidine -1.22 -5.70 -4.48 -0.344 0.76432E+04 156 siderite -2.59 -6.34 -3.75 -1.251 0.64084E+04 157 sillimanite 5.32 2.08 -3.24 -0.324 0.55328E+04 164 stilbite -7.41 -8.88 -1.47 -0.070 0.25130E+04 165 stilpnomelane-Fe 13.18 9.70 -3.48 -0.104 0.59342E+04 169 sudoite 21.22 17.83 -3.38 -0.109 0.57735E+04 175 tephroite 18.11 13.29 -4.82 -0.689 0.82364E+04 178 topaz-H 4.67 2.08 -2.59 -0.235 0.44165E+04 179 tridymite -2.61 -3.71 -1.10 -0.366 0.18724E+04 188 wairakite 4.06 2.26 -1.80 -0.106 0.30777E+04 189 walstromite 11.53 7.60 -3.93 -0.786 0.67112E+04 190 wollastonite 10.48 7.60 -2.88 -0.577 0.49251E+04 191 pseudo-wollastonite 11.02 7.60 -3.42 -0.684 0.58437E+04 192 zoisite 22.96 20.17 -2.79 -0.127 0.47669E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -5.01 -3.45 -0.213 0.58850E+04 195 beidellite-H -2.24 -6.87 -4.63 -0.296 0.79075E+04 196 beidellite-K -1.44 -6.03 -4.60 -0.282 0.78524E+04 197 beidellite-Mg -1.71 -5.44 -3.73 -0.231 0.63708E+04 198 beidellite-Na -1.26 -5.50 -4.25 -0.260 0.72525E+04 200 chalcedony -2.79 -3.71 -0.92 -0.306 0.15654E+04 202 montmorillonite-Ca -2.21 -5.27 -3.06 -0.189 0.52248E+04 203 montmorillonite-K -2.16 -6.30 -4.14 -0.254 0.70700E+04 204 montmorillonite-Mg -2.40 -5.71 -3.30 -0.204 0.56417E+04 205 montmorillonite-Na -1.96 -5.77 -3.81 -0.233 0.65083E+04 206 nontronite-Ca 3.28 1.80 -1.48 -0.096 0.25279E+04 207 nontronite-H 2.60 -0.07 -2.66 -0.178 0.45461E+04 208 nontronite-K 3.40 0.77 -2.63 -0.169 0.44945E+04 209 nontronite-Mg 3.14 1.37 -1.77 -0.115 0.30253E+04 210 nontronite-Na 3.58 1.30 -2.28 -0.146 0.38963E+04 215 gypsum -4.92 -9.12 -4.19 -1.048 0.71603E+04 225 tobermorite 9.84 5.71 -4.13 -1.127 0.70521E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.47 -3.36 -0.839 0.57337E+04 241 silica-amorphous -2.08 -3.71 -1.63 -0.544 0.27856E+04 243 an20ab80 2.08 -1.34 -3.42 -0.263 0.58361E+04 244 an25ab75 2.71 -0.65 -3.36 -0.258 0.57360E+04 245 an30ab70 3.34 0.04 -3.31 -0.254 0.56442E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0220000 g New total amount of reactant added: 0.0230000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0230000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3151793E-03 Osmotic coef. = 0.9894 True ionic strength = .3308820E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13632E-07 -7.8654 0.13071E-07 -7.8837 0.95882E+00 -0.0183 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13226E-03 -3.8786 0.95868E+00 -0.0183 4 SO4-- 0.25271E-04 -4.5974 0.22528E-04 -4.6473 0.89146E+00 -0.0499 5 HCO3- 0.12610E-04 -4.8993 0.12090E-04 -4.9176 0.95871E+00 -0.0183 6 HS- 0.59071E-11 -11.2286 0.56630E-11 -11.2470 0.95868E+00 -0.0183 7 Al+++ 0.22269E-20 -20.6523 0.17578E-20 -20.7550 0.78937E+00 -0.1027 8 H4SiO4 0.19962E-03 -3.6998 0.19962E-03 -3.6998 0.10000E+01 0.0000 9 Ca++ 0.37013E-04 -4.4316 0.32990E-04 -4.4816 0.89130E+00 -0.0500 10 Mg++ 0.92861E-07 -7.0322 0.82758E-07 -7.0822 0.89120E+00 -0.0500 11 Fe++ 0.55197E-09 -9.2581 0.49193E-09 -9.3081 0.89123E+00 -0.0500 12 K+ 0.48814E-05 -5.3115 0.46799E-05 -5.3298 0.95872E+00 -0.0183 13 Na+ 0.18889E-03 -3.7238 0.18108E-03 -3.7421 0.95868E+00 -0.0183 14 Mn++ 0.60095E-07 -7.2212 0.53560E-07 -7.2712 0.89125E+00 -0.0500 15 HPO4-- 0.10266E-08 -8.9886 0.91517E-09 -9.0385 0.89146E+00 -0.0499 16 HSiO3- 0.15543E-04 -4.8085 0.14901E-04 -4.8268 0.95868E+00 -0.0183 17 Ca(HSiO3)+ 0.11488E-07 -7.9398 0.11014E-07 -7.9581 0.95872E+00 -0.0183 18 Mg(HSiO3)+ 0.35865E-10 -10.4453 0.34385E-10 -10.4636 0.95872E+00 -0.0183 19 NaHSiO3,aq 0.42855E-07 -7.3680 0.42855E-07 -7.3680 0.10000E+01 0.0000 20 AlO+ 0.13855E-11 -11.8584 0.13283E-11 -11.8767 0.95872E+00 -0.0183 21 AlOH+2 0.97583E-16 -16.0106 0.86972E-16 -16.0606 0.89127E+00 -0.0500 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.36240E-05 -5.4408 0.34741E-05 -5.4592 0.95864E+00 -0.0183 24 CH4,aq 0.29824E-17 -17.5254 0.29822E-17 -17.5255 0.99990E+00 0.0000 29 CO,aq 0.64713E-17 -17.1890 0.64713E-17 -17.1890 0.10000E+01 0.0000 30 CO2,aq 0.31863E-06 -6.4967 0.31860E-06 -6.4967 0.99990E+00 0.0000 31 CO3-2 0.95939E-07 -7.0180 0.85521E-07 -7.0679 0.89141E+00 -0.0499 32 CaCO3,aq 0.34555E-07 -7.4615 0.34555E-07 -7.4615 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10482E-07 -7.9795 0.10050E-07 -7.9978 0.95872E+00 -0.0183 34 CaCl+ 0.72522E-08 -8.1395 0.69528E-08 -8.1578 0.95872E+00 -0.0183 35 CaCl2,aq 0.21411E-12 -12.6694 0.21411E-12 -12.6694 0.10000E+01 0.0000 36 CaOH+ 0.18564E-06 -6.7313 0.17797E-06 -6.7496 0.95872E+00 -0.0183 37 CaSO4,aq 0.23156E-06 -6.6353 0.23156E-06 -6.6353 0.10000E+01 0.0000 38 HCl,aq 0.32517E-12 -12.4879 0.32517E-12 -12.4879 0.10000E+01 0.0000 43 FeCl+ 0.10570E-12 -12.9759 0.10134E-12 -12.9942 0.95872E+00 -0.0183 46 FeO,aq 0.11386E-09 -9.9436 0.11386E-09 -9.9436 0.10000E+01 0.0000 47 FeOH+ 0.13014E-08 -8.8856 0.12477E-08 -8.9039 0.95872E+00 -0.0183 48 HFeO2- 0.97739E-10 -10.0099 0.93700E-10 -10.0283 0.95868E+00 -0.0183 49 FeO+ 0.11278E-12 -12.9478 0.10812E-12 -12.9661 0.95872E+00 -0.0183 50 FeOH+2 0.29506E-18 -18.5301 0.26297E-18 -18.5801 0.89127E+00 -0.0500 51 FeO2- 0.12975E-09 -9.8869 0.12439E-09 -9.9052 0.95868E+00 -0.0183 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.78870E-09 -9.1031 0.78863E-09 -9.1031 0.99990E+00 0.0000 54 KCl,aq 0.10960E-10 -10.9602 0.10960E-10 -10.9602 0.10000E+01 0.0000 55 KHSO4,aq 0.36875E-17 -17.4333 0.36875E-17 -17.4333 0.10000E+01 0.0000 56 KOH,aq 0.15609E-09 -9.8066 0.15609E-09 -9.8066 0.10000E+01 0.0000 57 KSO4- 0.16943E-08 -8.7710 0.16243E-08 -8.7893 0.95868E+00 -0.0183 58 MgCO3,aq 0.21660E-10 -10.6643 0.21660E-10 -10.6643 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26815E-10 -10.5716 0.25708E-10 -10.5899 0.95872E+00 -0.0183 60 MgCl+ 0.16516E-10 -10.7821 0.15834E-10 -10.8004 0.95872E+00 -0.0183 61 MgOH+ 0.25799E-08 -8.5884 0.24734E-08 -8.6067 0.95872E+00 -0.0183 63 MnO,aq 0.33095E-09 -9.4802 0.33095E-09 -9.4802 0.10000E+01 0.0000 64 MnOH+ 0.13163E-07 -7.8806 0.12620E-07 -7.8989 0.95872E+00 -0.0183 65 MnO2-2 0.75154E-16 -16.1241 0.66993E-16 -16.1740 0.89141E+00 -0.0499 66 HMnO2- 0.19790E-12 -12.7036 0.18972E-12 -12.7219 0.95868E+00 -0.0183 69 MnCl+ 0.44718E-10 -10.3495 0.42873E-10 -10.3678 0.95872E+00 -0.0183 70 MnSO4,aq 0.34195E-09 -9.4660 0.34195E-09 -9.4660 0.10000E+01 0.0000 71 NaCl,aq 0.78202E-08 -8.1068 0.78202E-08 -8.1068 0.10000E+01 0.0000 72 NaOH,aq 0.60875E-08 -8.2156 0.60875E-08 -8.2156 0.10000E+01 0.0000 74 OH- 0.47872E-04 -4.3199 0.45892E-04 -4.3383 0.95864E+00 -0.0183 82 H3PO4,aq 0.10066E-14 -14.9972 0.10066E-14 -14.9972 0.10000E+01 0.0000 83 H2PO4- 0.21875E-09 -9.6601 0.20972E-09 -9.6784 0.95870E+00 -0.0183 84 PO4-3 0.77369E-13 -13.1114 0.61146E-13 -13.2136 0.79032E+00 -0.1022 88 HP2O7-3 0.68408E-19 -19.1649 0.54000E-19 -19.2676 0.78938E+00 -0.1027 90 H2S,aq 0.22242E-12 -12.6528 0.22240E-12 -12.6529 0.99990E+00 0.0000 96 SO2,aq 0.12717E-19 -19.8956 0.12717E-19 -19.8956 0.10000E+01 0.0000 97 SO3-2 0.27165E-14 -14.5660 0.24224E-14 -14.6158 0.89173E+00 -0.0498 98 HSO3- 0.19328E-14 -14.7138 0.18529E-14 -14.7321 0.95868E+00 -0.0183 99 HSO4- 0.28497E-09 -9.5452 0.27321E-09 -9.5635 0.95875E+00 -0.0183 101 S2O3-2 0.66240E-19 -19.1789 0.59047E-19 -19.2288 0.89141E+00 -0.0499 Charge balance for all species = 0.2012E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1363205E-07 -.7803477E-04 -.7865175E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999651E+06 0.0000 3 Cl- 0.1379602E-03 0.1379754E-03 0.4891478E+01 4.0051 4 SO4-- 0.2527080E-04 0.2550453E-04 0.2449924E+01 11.1201 5 HCO3- 0.1261045E-04 0.1307011E-04 0.7974751E+00 2.9661 6 HS- 0.5907067E-11 0.1616401E-09 0.5345583E-05 -3.3633 7 Al+++ 0.2226886E-20 0.3644296E-05 0.9832530E-01 2.8961 8 H4SiO4 0.1996198E-03 0.2152171E-03 0.2068499E+02 -3.6998 9 Ca++ 0.3701339E-04 0.3749437E-04 0.1502649E+01 11.2858 10 Mg++ 0.9286136E-07 0.9554212E-07 0.2322742E-02 8.6852 11 Fe++ 0.5519657E-09 0.2398449E-08 0.1339417E-03 6.4593 12 K+ 0.4881408E-05 0.4883270E-05 0.1909392E+00 2.5539 13 Na+ 0.1888865E-03 0.1889432E-03 0.4343622E+01 4.1416 14 Mn++ 0.6009509E-07 0.7397608E-07 0.4063963E-02 8.4962 15 HPO4-- 0.1026590E-08 0.1245418E-08 0.1195300E-03 6.7289 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3678059E-03 -.7803410E-04 -.2897718E-03 0.0000000E+00 2 H2O 0.5550796E+02 0.5550781E+02 0.1533518E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2614188E-04 0.2550431E-04 0.6375700E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6374084E-06 0.1616387E-09 -.6375700E-06 0.0000000E+00 7 Al+++ 0.7499706E-04 0.3644265E-05 0.7135279E-04 0.0000000E+00 8 H4SiO4 0.2394940E-03 0.2152153E-03 0.2427875E-04 0.0000000E+00 9 Ca++ 0.4092434E-04 0.3749405E-04 0.3430295E-05 0.0000000E+00 10 Mg++ 0.1825397E-04 0.9554129E-07 0.1815843E-04 0.0000000E+00 11 Fe++ 0.1639920E-04 0.2398429E-08 0.1639680E-04 0.0000000E+00 12 K+ 0.4883227E-05 0.4883227E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1889416E-03 0.1889416E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3987877E-06 0.7397544E-07 0.3248123E-06 0.0000000E+00 15 HPO4-- 0.1361043E-06 0.1245407E-08 0.1348589E-06 0.0000000E+00 Chg. balance for solid moles: -.2128E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0230000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4495E-07 -7.347 0.2258E-04 -4.646 0.2722 0.7175E-05 clinochlore 0.3632E-05 -5.440 0.2019E-02 -2.695 24.33 0.7678E-03 daphnite 0.2259E-05 -5.646 0.1612E-02 -2.793 19.43 0.4885E-03 chlorite-Mn 0.6496E-07 -7.187 0.4606E-04 -4.337 0.5552 0.1468E-04 diaspore 0.5303E-04 -4.275 0.3181E-02 -2.497 38.35 0.9471E-03 hematite 0.2550E-05 -5.593 0.4073E-03 -3.390 4.910 0.7719E-04 lawsonite 0.3206E-05 -5.494 0.1007E-02 -2.997 12.14 0.3248E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6098E+00 0.6098E+00 1.0000 -0.215 daphnite 0.3793E+00 0.3793E+00 1.0000 -0.421 chlorite-Mn 0.1091E-01 0.1091E-01 1.0000 -1.962 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.008295 g Volume = 0.002627 cm3 Porosity: 99.7397% V(tot) - V(min): 0.10066E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0230000 g log = -1.6383 Original solution: 1000.0103000 g Original solution / Rock added: 43478.71 (Water/Rock Ratio), log = 4.6383 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3442E-04 1.0073 0.3647E-04 0.3620E-04 CH4,gas 0.4426E-14 1.0129 0.4716E-14 0.4656E-14 H2,gas 0.1028E-05 1.0006 0.1082E-05 0.1081E-05 H2S,gas 0.6191E-11 0.9959 0.6486E-11 0.6513E-11 S2,gas 0.1280E-29 1.0000 0.1347E-29 0.1347E-29 CO,gas 0.9713E-14 1.0000 0.1022E-13 0.1022E-13 SO3,gas 0.1368E-35 1.0000 0.1439E-35 0.1439E-35 SO2,gas 0.5597E-19 1.0000 0.5888E-19 0.5888E-19 HCl,gas 0.5458E-15 1.0000 0.5742E-15 0.5742E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.80 -6.44 -2.146 0.10993E+05 -4.438 3 CH4,gas 4.81 -11.52 -16.33 -4.082 0.27877E+05 -14.326 4 H2,gas 8.29 0.32 -7.97 -4.552 0.13602E+05 -5.966 5 H2S,gas -5.94 -19.13 -13.19 -6.594 0.22518E+05 -11.188 6 S2,gas -7.03 -38.90 -31.87 -4.903 0.54418E+05 -29.871 7 CO,gas 3.51 -12.48 -15.99 -4.920 0.27304E+05 -13.991 8 SO3,gas 17.43 -20.41 -37.84 -9.460 0.64614E+05 -35.842 9 SO2,gas 1.14 -20.09 -21.23 -5.661 0.36250E+05 -19.230 10 HCl,gas 5.48 -11.76 -17.24 -8.620 0.29438E+05 -15.241 11 acmite 7.74 3.04 -4.70 -0.488 0.80193E+04 15 albite-high 0.75 -4.06 -4.81 -0.370 0.82153E+04 16 albite -0.33 -4.06 -3.73 -0.287 0.63746E+04 19 spessartine 24.55 20.18 -4.37 -0.218 0.74589E+04 20 analcite 3.37 -0.36 -3.73 -0.415 0.63733E+04 21 andalusite 5.06 2.09 -2.97 -0.297 0.50712E+04 22 andradite 39.09 35.36 -3.73 -0.194 0.63725E+04 23 grossular 32.83 28.55 -4.28 -0.214 0.73046E+04 24 anhydrite -5.28 -9.13 -3.85 -1.925 0.65723E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.52 -2.50 -0.834 0.42716E+04 36 brucite 12.58 8.69 -3.89 -0.778 0.66444E+04 37 calcite 0.83 -1.52 -2.35 -0.783 0.40103E+04 40 carpholite-Mg 8.65 7.08 -1.57 -0.105 0.26851E+04 41 carpholite-Fe 6.78 4.85 -1.93 -0.129 0.32971E+04 50 chloritoid-Mg 13.26 10.78 -2.48 -0.166 0.42408E+04 51 chloritoid-Fe 9.24 8.55 -0.69 -0.046 0.11730E+04 52 chloritoid-Mn 11.46 10.59 -0.87 -0.058 0.14933E+04 54 coesite -2.37 -3.70 -1.33 -0.443 0.22717E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.70 -1.15 -0.384 0.19646E+04 67 diopside 16.22 12.57 -3.64 -0.364 0.62221E+04 68 hedenbergite 14.24 10.35 -3.90 -0.390 0.66573E+04 75 epidote 24.78 23.56 -1.21 -0.059 0.20695E+04 76 clinozoisite 22.92 20.16 -2.76 -0.125 0.47138E+04 77 epidote-Fe 29.94 26.97 -2.97 -0.154 0.50727E+04 78 fayalite 14.08 9.22 -4.86 -0.694 0.82986E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.98 -4.22 -0.351 0.71985E+04 91 heulandite -5.71 -8.82 -3.11 -0.142 0.53162E+04 95 jadeite 4.25 -0.36 -4.61 -0.461 0.78763E+04 98 kaolinite -1.27 -1.61 -0.33 -0.030 0.57076E+03 99 kyanite 4.93 2.09 -2.84 -0.284 0.48480E+04 101 laumontite 2.97 2.28 -0.70 -0.046 0.11880E+04 105 lizardite 23.29 18.66 -4.63 -0.386 0.79079E+04 106 magnesite 0.71 -4.12 -4.83 -1.608 0.82392E+04 107 magnetite 20.13 19.06 -1.08 -0.088 0.18370E+04 110 magnesioferrite 26.26 21.28 -4.97 -0.406 0.84937E+04 113 margarite 17.45 15.47 -1.98 -0.079 0.33829E+04 116 microcline -2.43 -5.65 -3.22 -0.248 0.54939E+04 120 muscovite 2.68 0.14 -2.54 -0.149 0.43308E+04 121 paragonite 4.34 1.73 -2.61 -0.153 0.44500E+04 136 prehnite 19.47 17.26 -2.20 -0.130 0.37598E+04 137 prehnite-Fe 22.59 20.67 -1.92 -0.115 0.32778E+04 138 pumpellyite-Fe 46.47 43.88 -2.59 -0.057 0.44163E+04 139 pumpellyite-Mg 49.19 46.11 -3.08 -0.069 0.52659E+04 145 pyroxmangite 7.42 4.80 -2.62 -0.524 0.44729E+04 146 pyrophyllite -6.10 -9.01 -2.91 -0.182 0.49670E+04 147 quartz -2.98 -3.70 -0.72 -0.239 0.12256E+04 152 rhodochrosite -0.96 -4.31 -3.35 -1.116 0.57141E+04 153 rhodonite 7.46 4.80 -2.67 -0.533 0.45521E+04 154 sanidine -1.22 -5.65 -4.43 -0.341 0.75617E+04 156 siderite -2.59 -6.34 -3.75 -1.251 0.64104E+04 157 sillimanite 5.32 2.09 -3.23 -0.323 0.55134E+04 164 stilbite -7.41 -8.82 -1.41 -0.067 0.24157E+04 165 stilpnomelane-Fe 13.18 9.77 -3.41 -0.102 0.58260E+04 169 sudoite 21.22 17.86 -3.36 -0.108 0.57384E+04 175 tephroite 18.11 13.29 -4.82 -0.689 0.82304E+04 178 topaz-H 4.67 2.09 -2.58 -0.234 0.43970E+04 179 tridymite -2.61 -3.70 -1.09 -0.362 0.18529E+04 188 wairakite 4.06 2.28 -1.78 -0.105 0.30388E+04 189 walstromite 11.53 7.59 -3.94 -0.788 0.67306E+04 190 wollastonite 10.48 7.59 -2.90 -0.579 0.49445E+04 191 pseudo-wollastonite 11.02 7.59 -3.43 -0.687 0.58632E+04 192 zoisite 22.96 20.16 -2.80 -0.127 0.47863E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.97 -3.41 -0.211 0.58200E+04 195 beidellite-H -2.24 -6.83 -4.59 -0.293 0.78360E+04 196 beidellite-K -1.44 -5.99 -4.55 -0.279 0.77733E+04 197 beidellite-Mg -1.71 -5.40 -3.69 -0.228 0.63013E+04 198 beidellite-Na -1.26 -5.46 -4.21 -0.258 0.71827E+04 200 chalcedony -2.79 -3.70 -0.91 -0.302 0.15459E+04 202 montmorillonite-Ca -2.21 -5.23 -3.02 -0.187 0.51573E+04 203 montmorillonite-K -2.16 -6.25 -4.09 -0.251 0.69884E+04 204 montmorillonite-Mg -2.40 -5.66 -3.26 -0.202 0.55696E+04 205 montmorillonite-Na -1.96 -5.73 -3.77 -0.231 0.64359E+04 206 nontronite-Ca 3.28 1.84 -1.44 -0.094 0.24629E+04 207 nontronite-H 2.60 -0.02 -2.62 -0.176 0.44747E+04 208 nontronite-K 3.40 0.82 -2.59 -0.166 0.44154E+04 209 nontronite-Mg 3.14 1.41 -1.73 -0.112 0.29558E+04 210 nontronite-Na 3.58 1.34 -2.24 -0.144 0.38265E+04 215 gypsum -4.92 -9.13 -4.20 -1.051 0.71791E+04 225 tobermorite 9.84 5.70 -4.14 -1.129 0.70651E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.46 -3.36 -0.841 0.57455E+04 241 silica-amorphous -2.08 -3.70 -1.62 -0.540 0.27661E+04 243 an20ab80 2.08 -1.31 -3.39 -0.261 0.57933E+04 244 an25ab75 2.71 -0.63 -3.34 -0.257 0.56959E+04 245 an30ab70 3.34 0.06 -3.28 -0.253 0.56068E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0230000 g New total amount of reactant added: 0.0240000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0240000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3137696E-03 Osmotic coef. = 0.9894 True ionic strength = .3294867E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13807E-07 -7.8599 0.13239E-07 -7.8781 0.95887E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13227E-03 -3.8786 0.95873E+00 -0.0183 4 SO4-- 0.25277E-04 -4.5973 0.22538E-04 -4.6471 0.89164E+00 -0.0498 5 HCO3- 0.12609E-04 -4.8993 0.12089E-04 -4.9176 0.95876E+00 -0.0183 6 HS- 0.52823E-11 -11.2772 0.50643E-11 -11.2955 0.95873E+00 -0.0183 7 Al+++ 0.23130E-20 -20.6358 0.18266E-20 -20.7384 0.78973E+00 -0.1025 8 H4SiO4 0.20483E-03 -3.6886 0.20483E-03 -3.6886 0.10000E+01 0.0000 9 Ca++ 0.36058E-04 -4.4430 0.32145E-04 -4.4929 0.89148E+00 -0.0499 10 Mg++ 0.93787E-07 -7.0279 0.83600E-07 -7.0778 0.89138E+00 -0.0499 11 Fe++ 0.55738E-09 -9.2538 0.49685E-09 -9.3038 0.89141E+00 -0.0499 12 K+ 0.50936E-05 -5.2930 0.48836E-05 -5.3113 0.95877E+00 -0.0183 13 Na+ 0.19014E-03 -3.7209 0.18229E-03 -3.7392 0.95872E+00 -0.0183 14 Mn++ 0.61075E-07 -7.2141 0.54444E-07 -7.2641 0.89142E+00 -0.0499 15 HPO4-- 0.10902E-08 -8.9625 0.97204E-09 -9.0123 0.89164E+00 -0.0498 16 HSiO3- 0.15745E-04 -4.8029 0.15095E-04 -4.8212 0.95873E+00 -0.0183 17 Ca(HSiO3)+ 0.11339E-07 -7.9454 0.10872E-07 -7.9637 0.95877E+00 -0.0183 18 Mg(HSiO3)+ 0.36701E-10 -10.4353 0.35188E-10 -10.4536 0.95877E+00 -0.0183 19 NaHSiO3,aq 0.43704E-07 -7.3595 0.43704E-07 -7.3595 0.10000E+01 0.0000 20 AlO+ 0.14033E-11 -11.8529 0.13454E-11 -11.8711 0.95877E+00 -0.0183 21 AlOH+2 0.10009E-15 -15.9996 0.89226E-16 -16.0495 0.89145E+00 -0.0499 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.35777E-05 -5.4464 0.34299E-05 -5.4647 0.95869E+00 -0.0183 24 CH4,aq 0.26658E-17 -17.5742 0.26656E-17 -17.5742 0.99990E+00 0.0000 29 CO,aq 0.63527E-17 -17.1970 0.63527E-17 -17.1970 0.10000E+01 0.0000 30 CO2,aq 0.32272E-06 -6.4912 0.32269E-06 -6.4912 0.99990E+00 0.0000 31 CO3-2 0.94696E-07 -7.0237 0.84430E-07 -7.0735 0.89159E+00 -0.0498 32 CaCO3,aq 0.33240E-07 -7.4783 0.33240E-07 -7.4783 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10213E-07 -7.9908 0.97919E-08 -8.0091 0.95877E+00 -0.0183 34 CaCl+ 0.70665E-08 -8.1508 0.67751E-08 -8.1691 0.95877E+00 -0.0183 35 CaCl2,aq 0.20865E-12 -12.6806 0.20865E-12 -12.6806 0.10000E+01 0.0000 36 CaOH+ 0.17857E-06 -6.7482 0.17121E-06 -6.7665 0.95877E+00 -0.0183 37 CaSO4,aq 0.22573E-06 -6.6464 0.22573E-06 -6.6464 0.10000E+01 0.0000 38 HCl,aq 0.32937E-12 -12.4823 0.32937E-12 -12.4823 0.10000E+01 0.0000 43 FeCl+ 0.10676E-12 -12.9716 0.10236E-12 -12.9899 0.95877E+00 -0.0183 46 FeO,aq 0.11210E-09 -9.9504 0.11210E-09 -9.9504 0.10000E+01 0.0000 47 FeOH+ 0.12977E-08 -8.8868 0.12442E-08 -8.9051 0.95877E+00 -0.0183 48 HFeO2- 0.94996E-10 -10.0223 0.91075E-10 -10.0406 0.95873E+00 -0.0183 49 FeO+ 0.11422E-12 -12.9422 0.10951E-12 -12.9605 0.95877E+00 -0.0183 50 FeOH+2 0.30264E-18 -18.5191 0.26979E-18 -18.5690 0.89145E+00 -0.0499 51 FeO2- 0.12809E-09 -9.8925 0.12281E-09 -9.9108 0.95873E+00 -0.0183 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.76444E-09 -9.1167 0.76437E-09 -9.1167 0.99990E+00 0.0000 54 KCl,aq 0.11437E-10 -10.9417 0.11437E-10 -10.9417 0.10000E+01 0.0000 55 KHSO4,aq 0.38993E-17 -17.4090 0.38993E-17 -17.4090 0.10000E+01 0.0000 56 KOH,aq 0.16081E-09 -9.7937 0.16081E-09 -9.7937 0.10000E+01 0.0000 57 KSO4- 0.17687E-08 -8.7523 0.16957E-08 -8.7707 0.95873E+00 -0.0183 58 MgCO3,aq 0.21601E-10 -10.6655 0.21601E-10 -10.6655 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27085E-10 -10.5673 0.25968E-10 -10.5856 0.95877E+00 -0.0183 60 MgCl+ 0.16684E-10 -10.7777 0.15996E-10 -10.7960 0.95877E+00 -0.0183 61 MgOH+ 0.25729E-08 -8.5896 0.24668E-08 -8.6079 0.95877E+00 -0.0183 63 MnO,aq 0.32791E-09 -9.4842 0.32791E-09 -9.4842 0.10000E+01 0.0000 64 MnOH+ 0.13210E-07 -7.8791 0.12665E-07 -7.8974 0.95877E+00 -0.0183 65 MnO2-2 0.72569E-16 -16.1392 0.64702E-16 -16.1891 0.89159E+00 -0.0498 66 HMnO2- 0.19358E-12 -12.7131 0.18559E-12 -12.7314 0.95873E+00 -0.0183 69 MnCl+ 0.45457E-10 -10.3424 0.43583E-10 -10.3607 0.95877E+00 -0.0183 70 MnSO4,aq 0.34774E-09 -9.4587 0.34774E-09 -9.4587 0.10000E+01 0.0000 71 NaCl,aq 0.78729E-08 -8.1039 0.78729E-08 -8.1039 0.10000E+01 0.0000 72 NaOH,aq 0.60504E-08 -8.2182 0.60504E-08 -8.2182 0.10000E+01 0.0000 74 OH- 0.47261E-04 -4.3255 0.45308E-04 -4.3438 0.95869E+00 -0.0183 82 H3PO4,aq 0.10968E-14 -14.9599 0.10968E-14 -14.9599 0.10000E+01 0.0000 83 H2PO4- 0.23532E-09 -9.6283 0.22562E-09 -9.6466 0.95875E+00 -0.0183 84 PO4-3 0.81096E-13 -13.0910 0.64121E-13 -13.1930 0.79067E+00 -0.1020 88 HP2O7-3 0.78133E-19 -19.1072 0.61705E-19 -19.2097 0.78974E+00 -0.1025 90 H2S,aq 0.20146E-12 -12.6958 0.20144E-12 -12.6958 0.99990E+00 0.0000 96 SO2,aq 0.12650E-19 -19.8979 0.12650E-19 -19.8979 0.10000E+01 0.0000 97 SO3-2 0.26336E-14 -14.5795 0.23489E-14 -14.6291 0.89191E+00 -0.0497 98 HSO3- 0.18982E-14 -14.7217 0.18198E-14 -14.7400 0.95873E+00 -0.0183 99 HSO4- 0.28875E-09 -9.5395 0.27685E-09 -9.5578 0.95879E+00 -0.0183 101 S2O3-2 0.60013E-19 -19.2218 0.53507E-19 -19.2716 0.89159E+00 -0.0498 Charge balance for all species = 0.2012E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1380688E-07 -.7742780E-04 -.7803994E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999646E+06 0.0000 3 Cl- 0.1379604E-03 0.1379754E-03 0.4891477E+01 3.9996 4 SO4-- 0.2527656E-04 0.2550454E-04 0.2449924E+01 11.1092 5 HCO3- 0.1260920E-04 0.1307012E-04 0.7974749E+00 2.9605 6 HS- 0.5282270E-11 0.1551363E-09 0.5130495E-05 -3.4173 7 Al+++ 0.2312972E-20 0.3598052E-05 0.9707755E-01 2.8961 8 H4SiO4 0.2048293E-03 0.2206294E-03 0.2120517E+02 -3.6886 9 Ca++ 0.3605844E-04 0.3652461E-04 0.1463784E+01 11.2634 10 Mg++ 0.9378686E-07 0.9646182E-07 0.2345100E-02 8.6785 11 Fe++ 0.5573821E-09 0.2393966E-08 0.1336913E-03 6.4525 12 K+ 0.5093646E-05 0.5095587E-05 0.1992409E+00 2.5669 13 Na+ 0.1901409E-03 0.1901985E-03 0.4372478E+01 4.1389 14 Mn++ 0.6107512E-07 0.7500620E-07 0.4120551E-02 8.4922 15 HPO4-- 0.1090168E-08 0.1325574E-08 0.1272229E-03 6.7440 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3843644E-03 -.7742711E-04 -.3069373E-03 0.0000000E+00 2 H2O 0.5550795E+02 0.5550779E+02 0.1564892E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2616959E-04 0.2550431E-04 0.6652769E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6651218E-06 0.1551349E-09 -.6652769E-06 0.0000000E+00 7 Al+++ 0.7825780E-04 0.3598020E-05 0.7465978E-04 0.0000000E+00 8 H4SiO4 0.2499068E-03 0.2206274E-03 0.2927934E-04 0.0000000E+00 9 Ca++ 0.4207448E-04 0.3652428E-04 0.5550203E-05 0.0000000E+00 10 Mg++ 0.1904762E-04 0.9646096E-07 0.1895116E-04 0.0000000E+00 11 Fe++ 0.1711221E-04 0.2393944E-08 0.1710981E-04 0.0000000E+00 12 K+ 0.5095541E-05 0.5095541E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1901968E-03 0.1901968E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.4161263E-06 0.7500553E-07 0.3411208E-06 0.0000000E+00 15 HPO4-- 0.1420218E-06 0.1325562E-08 0.1406963E-06 0.0000000E+00 Chg. balance for solid moles: -.1149E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0240000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4690E-07 -7.329 0.2356E-04 -4.628 0.2603 0.7486E-05 clinochlore 0.3790E-05 -5.421 0.2107E-02 -2.676 23.28 0.8013E-03 daphnite 0.2358E-05 -5.628 0.1682E-02 -2.774 18.58 0.5097E-03 chlorite-Mn 0.6822E-07 -7.166 0.4837E-04 -4.315 0.5344 0.1541E-04 diaspore 0.5160E-04 -4.287 0.3095E-02 -2.509 34.20 0.9215E-03 hematite 0.2661E-05 -5.575 0.4250E-03 -3.372 4.695 0.8055E-04 lawsonite 0.5316E-05 -5.274 0.1670E-02 -2.777 18.45 0.5387E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6098E+00 0.6098E+00 1.0000 -0.215 daphnite 0.3793E+00 0.3793E+00 1.0000 -0.421 chlorite-Mn 0.1098E-01 0.1098E-01 1.0000 -1.960 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.009051 g Volume = 0.002875 cm3 Porosity: 99.7153% V(tot) - V(min): 0.10067E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0240000 g log = -1.6198 Original solution: 1000.0103000 g Original solution / Rock added: 41667.10 (Water/Rock Ratio), log = 4.6198 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3486E-04 1.0073 0.3694E-04 0.3667E-04 CH4,gas 0.3956E-14 1.0129 0.4215E-14 0.4162E-14 H2,gas 0.9960E-06 1.0006 0.1048E-05 0.1048E-05 H2S,gas 0.5608E-11 0.9959 0.5875E-11 0.5899E-11 S2,gas 0.1118E-29 1.0000 0.1176E-29 0.1176E-29 CO,gas 0.9535E-14 1.0000 0.1003E-13 0.1003E-13 SO3,gas 0.1404E-35 1.0000 0.1477E-35 0.1477E-35 SO2,gas 0.5568E-19 1.0000 0.5857E-19 0.5857E-19 HCl,gas 0.5528E-15 1.0000 0.5816E-15 0.5816E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.80 -6.43 -2.144 0.10983E+05 -4.433 3 CH4,gas 4.81 -11.57 -16.38 -4.094 0.27960E+05 -14.375 4 H2,gas 8.29 0.31 -7.98 -4.560 0.13625E+05 -5.979 5 H2S,gas -5.94 -19.17 -13.23 -6.615 0.22592E+05 -11.231 6 S2,gas -7.03 -38.96 -31.93 -4.912 0.54519E+05 -29.929 7 CO,gas 3.51 -12.49 -16.00 -4.923 0.27317E+05 -13.999 8 SO3,gas 17.43 -20.40 -37.83 -9.458 0.64595E+05 -35.831 9 SO2,gas 1.14 -20.10 -21.23 -5.662 0.36254E+05 -19.232 10 HCl,gas 5.48 -11.76 -17.24 -8.618 0.29429E+05 -15.235 11 acmite 7.74 3.06 -4.68 -0.486 0.79857E+04 15 albite-high 0.75 -4.03 -4.78 -0.368 0.81625E+04 16 albite -0.33 -4.03 -3.70 -0.285 0.63218E+04 19 spessartine 24.55 20.20 -4.35 -0.217 0.74221E+04 20 analcite 3.37 -0.34 -3.71 -0.413 0.63396E+04 21 andalusite 5.06 2.10 -2.96 -0.296 0.50521E+04 22 andradite 39.09 35.32 -3.77 -0.196 0.64298E+04 23 grossular 32.83 28.52 -4.31 -0.216 0.73619E+04 24 anhydrite -5.28 -9.14 -3.86 -1.930 0.65912E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.53 -2.52 -0.840 0.43004E+04 36 brucite 12.58 8.68 -3.90 -0.780 0.66559E+04 37 calcite 0.83 -1.53 -2.37 -0.789 0.40390E+04 40 carpholite-Mg 8.65 7.09 -1.56 -0.104 0.26584E+04 41 carpholite-Fe 6.78 4.87 -1.92 -0.128 0.32705E+04 50 chloritoid-Mg 13.26 10.78 -2.48 -0.165 0.42331E+04 51 chloritoid-Fe 9.24 8.56 -0.68 -0.046 0.11655E+04 52 chloritoid-Mn 11.46 10.60 -0.87 -0.058 0.14811E+04 54 coesite -2.37 -3.69 -1.32 -0.440 0.22526E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.69 -1.14 -0.380 0.19455E+04 67 diopside 16.22 12.56 -3.65 -0.365 0.62336E+04 68 hedenbergite 14.24 10.34 -3.91 -0.391 0.66689E+04 75 epidote 24.78 23.55 -1.22 -0.059 0.20886E+04 76 clinozoisite 22.92 20.15 -2.77 -0.126 0.47329E+04 77 epidote-Fe 29.94 26.95 -2.98 -0.155 0.50918E+04 78 fayalite 14.08 9.22 -4.86 -0.695 0.83026E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.98 -4.21 -0.351 0.71950E+04 91 heulandite -5.71 -8.76 -3.06 -0.139 0.52207E+04 95 jadeite 4.25 -0.34 -4.59 -0.459 0.78426E+04 98 kaolinite -1.27 -1.59 -0.31 -0.028 0.53256E+03 99 kyanite 4.93 2.10 -2.83 -0.283 0.48289E+04 101 laumontite 2.97 2.30 -0.67 -0.045 0.11498E+04 105 lizardite 23.29 18.66 -4.63 -0.386 0.79041E+04 106 magnesite 0.71 -4.12 -4.83 -1.609 0.82412E+04 107 magnetite 20.13 19.05 -1.08 -0.088 0.18486E+04 110 magnesioferrite 26.26 21.28 -4.98 -0.407 0.85052E+04 113 margarite 17.45 15.47 -1.98 -0.079 0.33829E+04 116 microcline -2.43 -5.60 -3.17 -0.244 0.54145E+04 120 muscovite 2.68 0.19 -2.49 -0.146 0.42514E+04 121 paragonite 4.34 1.76 -2.58 -0.151 0.43972E+04 136 prehnite 19.47 17.25 -2.21 -0.130 0.37789E+04 137 prehnite-Fe 22.59 20.66 -1.93 -0.116 0.32969E+04 138 pumpellyite-Fe 46.47 43.85 -2.62 -0.058 0.44660E+04 139 pumpellyite-Mg 49.19 46.08 -3.11 -0.069 0.53155E+04 145 pyroxmangite 7.42 4.80 -2.61 -0.522 0.44606E+04 146 pyrophyllite -6.10 -8.96 -2.86 -0.179 0.48906E+04 147 quartz -2.98 -3.69 -0.71 -0.236 0.12065E+04 152 rhodochrosite -0.96 -4.30 -3.34 -1.115 0.57114E+04 153 rhodonite 7.46 4.80 -2.66 -0.532 0.45398E+04 154 sanidine -1.22 -5.60 -4.38 -0.337 0.74822E+04 156 siderite -2.59 -6.34 -3.76 -1.252 0.64125E+04 157 sillimanite 5.32 2.10 -3.22 -0.322 0.54943E+04 164 stilbite -7.41 -8.76 -1.36 -0.065 0.23201E+04 165 stilpnomelane-Fe 13.18 9.83 -3.35 -0.100 0.57200E+04 169 sudoite 21.22 17.88 -3.34 -0.108 0.57041E+04 175 tephroite 18.11 13.30 -4.82 -0.688 0.82249E+04 178 topaz-H 4.67 2.10 -2.56 -0.233 0.43779E+04 179 tridymite -2.61 -3.69 -1.07 -0.358 0.18338E+04 188 wairakite 4.06 2.30 -1.76 -0.103 0.30006E+04 189 walstromite 11.53 7.57 -3.95 -0.791 0.67498E+04 190 wollastonite 10.48 7.57 -2.91 -0.581 0.49636E+04 191 pseudo-wollastonite 11.02 7.57 -3.45 -0.689 0.58823E+04 192 zoisite 22.96 20.15 -2.81 -0.128 0.48055E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.93 -3.37 -0.209 0.57562E+04 195 beidellite-H -2.24 -6.79 -4.55 -0.290 0.77659E+04 196 beidellite-K -1.44 -5.94 -4.51 -0.276 0.76959E+04 197 beidellite-Mg -1.71 -5.36 -3.65 -0.226 0.62331E+04 198 beidellite-Na -1.26 -5.42 -4.17 -0.255 0.71141E+04 200 chalcedony -2.79 -3.69 -0.89 -0.298 0.15268E+04 202 montmorillonite-Ca -2.21 -5.20 -2.98 -0.184 0.50909E+04 203 montmorillonite-K -2.16 -6.21 -4.05 -0.248 0.69085E+04 204 montmorillonite-Mg -2.40 -5.62 -3.22 -0.199 0.54989E+04 205 montmorillonite-Na -1.96 -5.69 -3.73 -0.228 0.63648E+04 206 nontronite-Ca 3.28 1.87 -1.41 -0.091 0.23991E+04 207 nontronite-H 2.60 0.02 -2.58 -0.173 0.44046E+04 208 nontronite-K 3.40 0.86 -2.54 -0.163 0.43380E+04 209 nontronite-Mg 3.14 1.45 -1.69 -0.110 0.28876E+04 210 nontronite-Na 3.58 1.38 -2.20 -0.141 0.37579E+04 215 gypsum -4.92 -9.14 -4.22 -1.054 0.71980E+04 225 tobermorite 9.84 5.69 -4.15 -1.131 0.70778E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.45 -3.37 -0.843 0.57571E+04 241 silica-amorphous -2.08 -3.69 -1.61 -0.536 0.27470E+04 243 an20ab80 2.08 -1.29 -3.37 -0.259 0.57511E+04 244 an25ab75 2.71 -0.60 -3.31 -0.255 0.56563E+04 245 an30ab70 3.34 0.08 -3.26 -0.251 0.55699E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0240000 g New total amount of reactant added: 0.0250000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0250000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3124116E-03 Osmotic coef. = 0.9895 True ionic strength = .3281506E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13976E-07 -7.8546 0.13402E-07 -7.8728 0.95891E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13227E-03 -3.8785 0.95877E+00 -0.0183 4 SO4-- 0.25282E-04 -4.5972 0.22547E-04 -4.6469 0.89181E+00 -0.0497 5 HCO3- 0.12608E-04 -4.8994 0.12089E-04 -4.9176 0.95881E+00 -0.0183 6 HS- 0.47320E-11 -11.3250 0.45369E-11 -11.3432 0.95878E+00 -0.0183 7 Al+++ 0.23985E-20 -20.6201 0.18950E-20 -20.7224 0.79007E+00 -0.1023 8 H4SiO4 0.21008E-03 -3.6776 0.21008E-03 -3.6776 0.10000E+01 0.0000 9 Ca++ 0.35123E-04 -4.4544 0.31318E-04 -4.5042 0.89165E+00 -0.0498 10 Mg++ 0.94646E-07 -7.0239 0.84382E-07 -7.0738 0.89155E+00 -0.0499 11 Fe++ 0.56241E-09 -9.2499 0.50143E-09 -9.2998 0.89158E+00 -0.0498 12 K+ 0.53059E-05 -5.2752 0.50873E-05 -5.2935 0.95881E+00 -0.0183 13 Na+ 0.19140E-03 -3.7181 0.18350E-03 -3.7364 0.95877E+00 -0.0183 14 Mn++ 0.61999E-07 -7.2076 0.55278E-07 -7.2574 0.89160E+00 -0.0498 15 HPO4-- 0.11571E-08 -8.9366 0.10319E-08 -8.9863 0.89181E+00 -0.0497 16 HSiO3- 0.15951E-04 -4.7972 0.15293E-04 -4.8155 0.95877E+00 -0.0183 17 Ca(HSiO3)+ 0.11192E-07 -7.9511 0.10731E-07 -7.9694 0.95882E+00 -0.0183 18 Mg(HSiO3)+ 0.37529E-10 -10.4256 0.35984E-10 -10.4439 0.95882E+00 -0.0183 19 NaHSiO3,aq 0.44573E-07 -7.3509 0.44573E-07 -7.3509 0.10000E+01 0.0000 20 AlO+ 0.14205E-11 -11.8476 0.13620E-11 -11.8658 0.95882E+00 -0.0183 21 AlOH+2 0.10255E-15 -15.9890 0.91439E-16 -16.0389 0.89162E+00 -0.0498 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.35340E-05 -5.4517 0.33882E-05 -5.4700 0.95873E+00 -0.0183 24 CH4,aq 0.23871E-17 -17.6221 0.23869E-17 -17.6222 0.99990E+00 0.0000 29 CO,aq 0.62365E-17 -17.2051 0.62365E-17 -17.2051 0.10000E+01 0.0000 30 CO2,aq 0.32668E-06 -6.4859 0.32665E-06 -6.4859 0.99990E+00 0.0000 31 CO3-2 0.93520E-07 -7.0291 0.83398E-07 -7.0788 0.89176E+00 -0.0498 32 CaCO3,aq 0.31989E-07 -7.4950 0.31989E-07 -7.4950 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.99490E-08 -8.0022 0.95393E-08 -8.0205 0.95882E+00 -0.0183 34 CaCl+ 0.68845E-08 -8.1621 0.66010E-08 -8.1804 0.95882E+00 -0.0183 35 CaCl2,aq 0.20330E-12 -12.6919 0.20330E-12 -12.6919 0.10000E+01 0.0000 36 CaOH+ 0.17185E-06 -6.7649 0.16477E-06 -6.7831 0.95882E+00 -0.0183 37 CaSO4,aq 0.22001E-06 -6.6576 0.22001E-06 -6.6576 0.10000E+01 0.0000 38 HCl,aq 0.33345E-12 -12.4770 0.33345E-12 -12.4770 0.10000E+01 0.0000 43 FeCl+ 0.10774E-12 -12.9676 0.10330E-12 -12.9859 0.95882E+00 -0.0183 46 FeO,aq 0.11039E-09 -9.9571 0.11039E-09 -9.9571 0.10000E+01 0.0000 47 FeOH+ 0.12937E-08 -8.8882 0.12404E-08 -8.9064 0.95882E+00 -0.0183 48 HFeO2- 0.92408E-10 -10.0343 0.88598E-10 -10.0526 0.95877E+00 -0.0183 49 FeO+ 0.11563E-12 -12.9369 0.11086E-12 -12.9552 0.95882E+00 -0.0183 50 FeOH+2 0.31009E-18 -18.5085 0.27648E-18 -18.5583 0.89162E+00 -0.0498 51 FeO2- 0.12653E-09 -9.8978 0.12131E-09 -9.9161 0.95877E+00 -0.0183 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.74136E-09 -9.1300 0.74129E-09 -9.1300 0.99990E+00 0.0000 54 KCl,aq 0.11915E-10 -10.9239 0.11915E-10 -10.9239 0.10000E+01 0.0000 55 KHSO4,aq 0.41137E-17 -17.3858 0.41137E-17 -17.3858 0.10000E+01 0.0000 56 KOH,aq 0.16548E-09 -9.7812 0.16548E-09 -9.7812 0.10000E+01 0.0000 57 KSO4- 0.18432E-08 -8.7344 0.17672E-08 -8.7527 0.95877E+00 -0.0183 58 MgCO3,aq 0.21537E-10 -10.6668 0.21537E-10 -10.6668 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27335E-10 -10.5633 0.26210E-10 -10.5815 0.95882E+00 -0.0183 60 MgCl+ 0.16840E-10 -10.7737 0.16146E-10 -10.7919 0.95882E+00 -0.0183 61 MgOH+ 0.25652E-08 -8.5909 0.24596E-08 -8.6091 0.95882E+00 -0.0183 63 MnO,aq 0.32488E-09 -9.4883 0.32488E-09 -9.4883 0.10000E+01 0.0000 64 MnOH+ 0.13248E-07 -7.8778 0.12703E-07 -7.8961 0.95882E+00 -0.0183 65 MnO2-2 0.70145E-16 -16.1540 0.62553E-16 -16.2038 0.89176E+00 -0.0498 66 HMnO2- 0.18945E-12 -12.7225 0.18164E-12 -12.7408 0.95877E+00 -0.0183 69 MnCl+ 0.46154E-10 -10.3358 0.44253E-10 -10.3541 0.95882E+00 -0.0183 70 MnSO4,aq 0.35322E-09 -9.4520 0.35322E-09 -9.4520 0.10000E+01 0.0000 71 NaCl,aq 0.79256E-08 -8.1010 0.79256E-08 -8.1010 0.10000E+01 0.0000 72 NaOH,aq 0.60165E-08 -8.2207 0.60165E-08 -8.2207 0.10000E+01 0.0000 74 OH- 0.46683E-04 -4.3308 0.44757E-04 -4.3491 0.95873E+00 -0.0183 82 H3PO4,aq 0.11933E-14 -14.9233 0.11933E-14 -14.9233 0.10000E+01 0.0000 83 H2PO4- 0.25289E-09 -9.5971 0.24247E-09 -9.6153 0.95879E+00 -0.0183 84 PO4-3 0.85010E-13 -13.0705 0.67244E-13 -13.1723 0.79101E+00 -0.1018 88 HP2O7-3 0.89108E-19 -19.0501 0.70402E-19 -19.1524 0.79008E+00 -0.1023 90 H2S,aq 0.18271E-12 -12.7382 0.18269E-12 -12.7383 0.99990E+00 0.0000 96 SO2,aq 0.12578E-19 -19.9004 0.12578E-19 -19.9004 0.10000E+01 0.0000 97 SO3-2 0.25546E-14 -14.5927 0.22789E-14 -14.6423 0.89208E+00 -0.0496 98 HSO3- 0.18642E-14 -14.7295 0.17874E-14 -14.7478 0.95877E+00 -0.0183 99 HSO4- 0.29241E-09 -9.5340 0.28038E-09 -9.5523 0.95884E+00 -0.0183 101 S2O3-2 0.54438E-19 -19.2641 0.48546E-19 -19.3138 0.89176E+00 -0.0498 Charge balance for all species = 0.2013E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1397635E-07 -.7686874E-04 -.7747641E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999641E+06 0.0000 3 Cl- 0.1379606E-03 0.1379754E-03 0.4891475E+01 3.9943 4 SO4-- 0.2528220E-04 0.2550456E-04 0.2449924E+01 11.0987 5 HCO3- 0.1260793E-04 0.1307012E-04 0.7974747E+00 2.9552 6 HS- 0.4731988E-11 0.1489929E-09 0.4927323E-05 -3.4704 7 Al+++ 0.2398499E-20 0.3554333E-05 0.9589793E-01 2.8961 8 H4SiO4 0.2100754E-03 0.2260822E-03 0.2172924E+02 -3.6776 9 Ca++ 0.3512327E-04 0.3557514E-04 0.1425732E+01 11.2414 10 Mg++ 0.9464588E-07 0.9731434E-07 0.2365825E-02 8.6719 11 Fe++ 0.5624066E-09 0.2389080E-08 0.1334184E-03 6.4459 12 K+ 0.5305884E-05 0.5307904E-05 0.2075425E+00 2.5793 13 Na+ 0.1913953E-03 0.1914539E-03 0.4401334E+01 4.1365 14 Mn++ 0.6199917E-07 0.7597193E-07 0.4173602E-02 8.4882 15 HPO4-- 0.1157134E-08 0.1410113E-08 0.1353366E-03 6.7593 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4009229E-03 -.7686803E-04 -.3240549E-03 0.0000000E+00 2 H2O 0.5550794E+02 0.5550778E+02 0.1596622E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2619731E-04 0.2550432E-04 0.6929842E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6928352E-06 0.1489915E-09 -.6929842E-06 0.0000000E+00 7 Al+++ 0.8151854E-04 0.3554300E-05 0.7796424E-04 0.0000000E+00 8 H4SiO4 0.2603196E-03 0.2260801E-03 0.3423943E-04 0.0000000E+00 9 Ca++ 0.4322463E-04 0.3557481E-04 0.7649812E-05 0.0000000E+00 10 Mg++ 0.1984127E-04 0.9731344E-07 0.1974396E-04 0.0000000E+00 11 Fe++ 0.1782521E-04 0.2389058E-08 0.1782283E-04 0.0000000E+00 12 K+ 0.5307856E-05 0.5307856E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1914521E-03 0.1914521E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.4334649E-06 0.7597123E-07 0.3574937E-06 0.0000000E+00 15 HPO4-- 0.1479394E-06 0.1410100E-08 0.1465293E-06 0.0000000E+00 Chg. balance for solid moles: -.6448E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0250000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4884E-07 -7.311 0.2453E-04 -4.610 0.2503 0.7796E-05 clinochlore 0.3949E-05 -5.404 0.2195E-02 -2.659 22.39 0.8349E-03 daphnite 0.2456E-05 -5.610 0.1752E-02 -2.756 17.87 0.5310E-03 chlorite-Mn 0.7150E-07 -7.146 0.5069E-04 -4.295 0.5171 0.1615E-04 diaspore 0.5020E-04 -4.299 0.3012E-02 -2.521 30.72 0.8966E-03 hematite 0.2772E-05 -5.557 0.4427E-03 -3.354 4.515 0.8390E-04 lawsonite 0.7406E-05 -5.130 0.2327E-02 -2.633 23.74 0.7504E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6098E+00 0.6098E+00 1.0000 -0.215 daphnite 0.3792E+00 0.3792E+00 1.0000 -0.421 chlorite-Mn 0.1104E-01 0.1104E-01 1.0000 -1.957 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.009804 g Volume = 0.003121 cm3 Porosity: 99.6910% V(tot) - V(min): 0.10069E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0250000 g log = -1.6021 Original solution: 1000.0103000 g Original solution / Rock added: 40000.41 (Water/Rock Ratio), log = 4.6021 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3529E-04 1.0073 0.3739E-04 0.3712E-04 CH4,gas 0.3542E-14 1.0129 0.3775E-14 0.3726E-14 H2,gas 0.9660E-06 1.0006 0.1017E-05 0.1016E-05 H2S,gas 0.5086E-11 0.9959 0.5328E-11 0.5350E-11 S2,gas 0.9778E-30 1.0000 0.1029E-29 0.1029E-29 CO,gas 0.9361E-14 1.0000 0.9847E-14 0.9847E-14 SO3,gas 0.1439E-35 1.0000 0.1514E-35 0.1514E-35 SO2,gas 0.5536E-19 1.0000 0.5823E-19 0.5823E-19 HCl,gas 0.5597E-15 1.0000 0.5888E-15 0.5888E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.79 -6.43 -2.142 0.10974E+05 -4.427 3 CH4,gas 4.81 -11.61 -16.42 -4.106 0.28042E+05 -14.423 4 H2,gas 8.29 0.29 -7.99 -4.567 0.13647E+05 -5.993 5 H2S,gas -5.94 -19.22 -13.27 -6.637 0.22664E+05 -11.273 6 S2,gas -7.03 -39.02 -31.99 -4.921 0.54618E+05 -29.988 7 CO,gas 3.51 -12.50 -16.01 -4.925 0.27331E+05 -14.007 8 SO3,gas 17.43 -20.39 -37.82 -9.455 0.64576E+05 -35.820 9 SO2,gas 1.14 -20.10 -21.23 -5.663 0.36258E+05 -19.235 10 HCl,gas 5.48 -11.75 -17.23 -8.615 0.29420E+05 -15.230 11 acmite 7.74 3.08 -4.66 -0.484 0.79523E+04 15 albite-high 0.75 -4.00 -4.75 -0.365 0.81104E+04 16 albite -0.33 -4.00 -3.67 -0.282 0.62698E+04 19 spessartine 24.55 20.22 -4.33 -0.216 0.73865E+04 20 analcite 3.37 -0.32 -3.69 -0.410 0.63063E+04 21 andalusite 5.06 2.11 -2.95 -0.295 0.50333E+04 22 andradite 39.09 35.29 -3.80 -0.197 0.64861E+04 23 grossular 32.83 28.48 -4.34 -0.217 0.74182E+04 24 anhydrite -5.28 -9.15 -3.87 -1.936 0.66103E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.55 -2.54 -0.845 0.43288E+04 36 brucite 12.58 8.67 -3.90 -0.781 0.66672E+04 37 calcite 0.83 -1.55 -2.38 -0.794 0.40675E+04 40 carpholite-Mg 8.65 7.11 -1.54 -0.103 0.26321E+04 41 carpholite-Fe 6.78 4.88 -1.90 -0.127 0.32444E+04 50 chloritoid-Mg 13.26 10.79 -2.47 -0.165 0.42256E+04 51 chloritoid-Fe 9.24 8.56 -0.68 -0.045 0.11581E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14692E+04 54 coesite -2.37 -3.68 -1.31 -0.436 0.22338E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.68 -1.13 -0.376 0.19267E+04 67 diopside 16.22 12.56 -3.66 -0.366 0.62449E+04 68 hedenbergite 14.24 10.33 -3.91 -0.391 0.66802E+04 75 epidote 24.78 23.54 -1.23 -0.060 0.21074E+04 76 clinozoisite 22.92 20.14 -2.78 -0.126 0.47517E+04 77 epidote-Fe 29.94 26.94 -2.99 -0.155 0.51106E+04 78 fayalite 14.08 9.21 -4.86 -0.695 0.83066E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.98 -4.21 -0.351 0.71916E+04 91 heulandite -5.71 -8.71 -3.00 -0.136 0.51269E+04 95 jadeite 4.25 -0.32 -4.57 -0.457 0.78093E+04 98 kaolinite -1.27 -1.56 -0.29 -0.026 0.49505E+03 99 kyanite 4.93 2.11 -2.82 -0.282 0.48101E+04 101 laumontite 2.97 2.32 -0.65 -0.043 0.11123E+04 105 lizardite 23.29 18.66 -4.63 -0.386 0.79004E+04 106 magnesite 0.71 -4.12 -4.83 -1.609 0.82434E+04 107 magnetite 20.13 19.04 -1.09 -0.089 0.18600E+04 110 magnesioferrite 26.26 21.27 -4.99 -0.407 0.85164E+04 113 margarite 17.45 15.47 -1.98 -0.079 0.33829E+04 116 microcline -2.43 -5.56 -3.13 -0.240 0.53370E+04 120 muscovite 2.68 0.23 -2.44 -0.144 0.41739E+04 121 paragonite 4.34 1.79 -2.54 -0.150 0.43451E+04 136 prehnite 19.47 17.24 -2.22 -0.131 0.37976E+04 137 prehnite-Fe 22.59 20.64 -1.94 -0.117 0.33157E+04 138 pumpellyite-Fe 46.47 43.83 -2.64 -0.059 0.45149E+04 139 pumpellyite-Mg 49.19 46.05 -3.14 -0.070 0.53643E+04 145 pyroxmangite 7.42 4.81 -2.61 -0.521 0.44487E+04 146 pyrophyllite -6.10 -8.92 -2.82 -0.176 0.48156E+04 147 quartz -2.98 -3.68 -0.70 -0.232 0.11878E+04 152 rhodochrosite -0.96 -4.30 -3.34 -1.115 0.57093E+04 153 rhodonite 7.46 4.81 -2.65 -0.530 0.45280E+04 154 sanidine -1.22 -5.56 -4.34 -0.334 0.74048E+04 156 siderite -2.59 -6.34 -3.76 -1.252 0.64148E+04 157 sillimanite 5.32 2.11 -3.21 -0.321 0.54755E+04 164 stilbite -7.41 -8.71 -1.30 -0.062 0.22264E+04 165 stilpnomelane-Fe 13.18 9.89 -3.29 -0.098 0.56162E+04 168 sudoite-Fe 18.44 13.44 -4.99 -0.161 0.85268E+04 169 sudoite 21.22 17.90 -3.32 -0.107 0.56703E+04 175 tephroite 18.11 13.30 -4.81 -0.688 0.82200E+04 178 topaz-H 4.67 2.11 -2.55 -0.232 0.43592E+04 179 tridymite -2.61 -3.68 -1.06 -0.354 0.18151E+04 188 wairakite 4.06 2.32 -1.74 -0.102 0.29631E+04 189 walstromite 11.53 7.56 -3.96 -0.793 0.67685E+04 190 wollastonite 10.48 7.56 -2.92 -0.584 0.49824E+04 191 pseudo-wollastonite 11.02 7.56 -3.46 -0.691 0.59010E+04 192 zoisite 22.96 20.14 -2.83 -0.128 0.48242E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.89 -3.33 -0.206 0.56935E+04 195 beidellite-H -2.24 -6.75 -4.51 -0.288 0.76971E+04 196 beidellite-K -1.44 -5.90 -4.46 -0.273 0.76201E+04 197 beidellite-Mg -1.71 -5.32 -3.61 -0.223 0.61661E+04 198 beidellite-Na -1.26 -5.38 -4.13 -0.253 0.70466E+04 200 chalcedony -2.79 -3.68 -0.88 -0.294 0.15081E+04 202 montmorillonite-Ca -2.21 -5.16 -2.94 -0.182 0.50258E+04 203 montmorillonite-K -2.16 -6.16 -4.00 -0.245 0.68301E+04 204 montmorillonite-Mg -2.40 -5.58 -3.18 -0.197 0.54294E+04 205 montmorillonite-Na -1.96 -5.65 -3.69 -0.226 0.62948E+04 206 nontronite-Ca 3.28 1.91 -1.37 -0.089 0.23365E+04 207 nontronite-H 2.60 0.06 -2.54 -0.170 0.43358E+04 208 nontronite-K 3.40 0.91 -2.50 -0.160 0.42622E+04 209 nontronite-Mg 3.14 1.49 -1.65 -0.107 0.28206E+04 210 nontronite-Na 3.58 1.42 -2.16 -0.139 0.36904E+04 215 gypsum -4.92 -9.15 -4.23 -1.057 0.72170E+04 225 tobermorite 9.84 5.69 -4.15 -1.133 0.70903E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.45 -3.38 -0.845 0.57684E+04 241 silica-amorphous -2.08 -3.68 -1.60 -0.533 0.27283E+04 243 an20ab80 2.08 -1.26 -3.34 -0.257 0.57094E+04 244 an25ab75 2.71 -0.58 -3.29 -0.253 0.56172E+04 245 an30ab70 3.34 0.10 -3.24 -0.249 0.55334E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0250000 g New total amount of reactant added: 0.0260000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0260000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3111035E-03 Osmotic coef. = 0.9895 True ionic strength = .3268719E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14140E-07 -7.8495 0.13560E-07 -7.8677 0.95896E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13228E-03 -3.8785 0.95882E+00 -0.0183 4 SO4-- 0.25288E-04 -4.5971 0.22556E-04 -4.6467 0.89197E+00 -0.0496 5 HCO3- 0.12607E-04 -4.8994 0.12088E-04 -4.9176 0.95885E+00 -0.0182 6 HS- 0.42463E-11 -11.3720 0.40715E-11 -11.3902 0.95882E+00 -0.0183 7 Al+++ 0.24832E-20 -20.6050 0.19627E-20 -20.7071 0.79040E+00 -0.1022 8 H4SiO4 0.21536E-03 -3.6668 0.21536E-03 -3.6668 0.10000E+01 0.0000 9 Ca++ 0.34207E-04 -4.4659 0.30507E-04 -4.5156 0.89182E+00 -0.0497 10 Mg++ 0.95437E-07 -7.0203 0.85103E-07 -7.0701 0.89172E+00 -0.0498 11 Fe++ 0.56703E-09 -9.2464 0.50564E-09 -9.2962 0.89174E+00 -0.0498 12 K+ 0.55181E-05 -5.2582 0.52911E-05 -5.2765 0.95886E+00 -0.0182 13 Na+ 0.19265E-03 -3.7152 0.18472E-03 -3.7335 0.95881E+00 -0.0183 14 Mn++ 0.62867E-07 -7.2016 0.56062E-07 -7.2513 0.89176E+00 -0.0498 15 HPO4-- 0.12277E-08 -8.9109 0.10950E-08 -8.9606 0.89197E+00 -0.0496 16 HSiO3- 0.16161E-04 -4.7915 0.15495E-04 -4.8098 0.95882E+00 -0.0183 17 Ca(HSiO3)+ 0.11046E-07 -7.9568 0.10591E-07 -7.9751 0.95886E+00 -0.0182 18 Mg(HSiO3)+ 0.38348E-10 -10.4163 0.36770E-10 -10.4345 0.95886E+00 -0.0182 19 NaHSiO3,aq 0.45459E-07 -7.3424 0.45459E-07 -7.3424 0.10000E+01 0.0000 20 AlO+ 0.14371E-11 -11.8425 0.13780E-11 -11.8607 0.95886E+00 -0.0182 21 AlOH+2 0.10496E-15 -15.9790 0.93605E-16 -16.0287 0.89178E+00 -0.0497 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.34927E-05 -5.4568 0.33487E-05 -5.4751 0.95878E+00 -0.0183 24 CH4,aq 0.21413E-17 -17.6693 0.21411E-17 -17.6694 0.99990E+00 0.0000 29 CO,aq 0.61226E-17 -17.2131 0.61226E-17 -17.2131 0.10000E+01 0.0000 30 CO2,aq 0.33051E-06 -6.4808 0.33048E-06 -6.4809 0.99990E+00 0.0000 31 CO3-2 0.92410E-07 -7.0343 0.82422E-07 -7.0840 0.89192E+00 -0.0497 32 CaCO3,aq 0.30796E-07 -7.5115 0.30796E-07 -7.5115 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.96903E-08 -8.0137 0.92917E-08 -8.0319 0.95886E+00 -0.0182 34 CaCl+ 0.67062E-08 -8.1735 0.64303E-08 -8.1918 0.95886E+00 -0.0182 35 CaCl2,aq 0.19805E-12 -12.7032 0.19805E-12 -12.7032 0.10000E+01 0.0000 36 CaOH+ 0.16544E-06 -6.7814 0.15864E-06 -6.7996 0.95886E+00 -0.0182 37 CaSO4,aq 0.21440E-06 -6.6688 0.21440E-06 -6.6688 0.10000E+01 0.0000 38 HCl,aq 0.33739E-12 -12.4719 0.33739E-12 -12.4719 0.10000E+01 0.0000 43 FeCl+ 0.10865E-12 -12.9640 0.10418E-12 -12.9822 0.95886E+00 -0.0182 46 FeO,aq 0.10875E-09 -9.9636 0.10875E-09 -9.9636 0.10000E+01 0.0000 47 FeOH+ 0.12893E-08 -8.8897 0.12362E-08 -8.9079 0.95886E+00 -0.0182 48 HFeO2- 0.89965E-10 -10.0459 0.86260E-10 -10.0642 0.95882E+00 -0.0183 49 FeO+ 0.11698E-12 -12.9319 0.11217E-12 -12.9501 0.95886E+00 -0.0182 50 FeOH+2 0.31738E-18 -18.4984 0.28303E-18 -18.5482 0.89178E+00 -0.0497 51 FeO2- 0.12505E-09 -9.9029 0.11990E-09 -9.9212 0.95882E+00 -0.0183 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.71939E-09 -9.1430 0.71932E-09 -9.1431 0.99990E+00 0.0000 54 KCl,aq 0.12393E-10 -10.9068 0.12393E-10 -10.9068 0.10000E+01 0.0000 55 KHSO4,aq 0.43306E-17 -17.3635 0.43306E-17 -17.3635 0.10000E+01 0.0000 56 KOH,aq 0.17011E-09 -9.7693 0.17011E-09 -9.7693 0.10000E+01 0.0000 57 KSO4- 0.19177E-08 -8.7172 0.18387E-08 -8.7355 0.95882E+00 -0.0183 58 MgCO3,aq 0.21467E-10 -10.6682 0.21467E-10 -10.6682 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27566E-10 -10.5596 0.26432E-10 -10.5779 0.95886E+00 -0.0182 60 MgCl+ 0.16984E-10 -10.7700 0.16285E-10 -10.7882 0.95886E+00 -0.0182 61 MgOH+ 0.25569E-08 -8.5923 0.24517E-08 -8.6105 0.95886E+00 -0.0182 63 MnO,aq 0.32186E-09 -9.4923 0.32186E-09 -9.4923 0.10000E+01 0.0000 64 MnOH+ 0.13279E-07 -7.8768 0.12733E-07 -7.8951 0.95886E+00 -0.0182 65 MnO2-2 0.67873E-16 -16.1683 0.60538E-16 -16.2180 0.89192E+00 -0.0497 66 HMnO2- 0.18549E-12 -12.7317 0.17786E-12 -12.7499 0.95882E+00 -0.0183 69 MnCl+ 0.46808E-10 -10.3297 0.44883E-10 -10.3479 0.95886E+00 -0.0182 70 MnSO4,aq 0.35837E-09 -9.4457 0.35837E-09 -9.4457 0.10000E+01 0.0000 71 NaCl,aq 0.79783E-08 -8.0981 0.79783E-08 -8.0981 0.10000E+01 0.0000 72 NaOH,aq 0.59857E-08 -8.2229 0.59857E-08 -8.2229 0.10000E+01 0.0000 74 OH- 0.46138E-04 -4.3359 0.44236E-04 -4.3542 0.95878E+00 -0.0183 82 H3PO4,aq 0.12963E-14 -14.8873 0.12963E-14 -14.8873 0.10000E+01 0.0000 83 H2PO4- 0.27150E-09 -9.5662 0.26033E-09 -9.5845 0.95884E+00 -0.0183 84 PO4-3 0.89121E-13 -13.0500 0.70525E-13 -13.1517 0.79134E+00 -0.1016 88 HP2O7-3 0.10148E-18 -18.9936 0.80208E-19 -19.0958 0.79040E+00 -0.1022 90 H2S,aq 0.16590E-12 -12.7802 0.16588E-12 -12.7802 0.99990E+00 0.0000 96 SO2,aq 0.12499E-19 -19.9031 0.12499E-19 -19.9031 0.10000E+01 0.0000 97 SO3-2 0.24795E-14 -14.6056 0.22123E-14 -14.6552 0.89224E+00 -0.0495 98 HSO3- 0.18309E-14 -14.7373 0.17555E-14 -14.7556 0.95882E+00 -0.0183 99 HSO4- 0.29596E-09 -9.5288 0.28379E-09 -9.5470 0.95888E+00 -0.0182 101 S2O3-2 0.49440E-19 -19.3059 0.44096E-19 -19.3556 0.89192E+00 -0.0497 Charge balance for all species = 0.2013E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1414030E-07 -.7635596E-04 -.7695954E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999635E+06 0.0000 3 Cl- 0.1379607E-03 0.1379755E-03 0.4891474E+01 3.9892 4 SO4-- 0.2528774E-04 0.2550457E-04 0.2449924E+01 11.0887 5 HCO3- 0.1260667E-04 0.1307012E-04 0.7974745E+00 2.9501 6 HS- 0.4246345E-11 0.1431815E-09 0.4735134E-05 -3.5225 7 Al+++ 0.2483214E-20 0.3513037E-05 0.9478369E-01 2.8961 8 H4SiO4 0.2153567E-03 0.2315742E-03 0.2225707E+02 -3.6668 9 Ca++ 0.3420724E-04 0.3464532E-04 0.1388467E+01 11.2199 10 Mg++ 0.9543701E-07 0.9809828E-07 0.2384882E-02 8.6654 11 Fe++ 0.5670305E-09 0.2383769E-08 0.1331217E-03 6.4393 12 K+ 0.5518122E-05 0.5520222E-05 0.2158442E+00 2.5913 13 Na+ 0.1926497E-03 0.1927092E-03 0.4430190E+01 4.1342 14 Mn++ 0.6286725E-07 0.7687376E-07 0.4223143E-02 8.4842 15 HPO4-- 0.1227662E-08 0.1499256E-08 0.1438921E-03 6.7749 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4174814E-03 -.7635523E-04 -.3411262E-03 0.0000000E+00 2 H2O 0.5550792E+02 0.5550776E+02 0.1628696E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2622502E-04 0.2550433E-04 0.7206918E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7205486E-06 0.1431802E-09 -.7206918E-06 0.0000000E+00 7 Al+++ 0.8477928E-04 0.3513004E-05 0.8126628E-04 0.0000000E+00 8 H4SiO4 0.2707324E-03 0.2315720E-03 0.3916033E-04 0.0000000E+00 9 Ca++ 0.4437477E-04 0.3464499E-04 0.9729776E-05 0.0000000E+00 10 Mg++ 0.2063492E-04 0.9809735E-07 0.2053682E-04 0.0000000E+00 11 Fe++ 0.1853822E-04 0.2383746E-08 0.1853584E-04 0.0000000E+00 12 K+ 0.5520170E-05 0.5520170E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1927073E-03 0.1927073E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.4508035E-06 0.7687304E-07 0.3739305E-06 0.0000000E+00 15 HPO4-- 0.1538570E-06 0.1499242E-08 0.1523577E-06 0.0000000E+00 Chg. balance for solid moles: -.4833E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0260000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5079E-07 -7.294 0.2551E-04 -4.593 0.2418 0.8106E-05 clinochlore 0.4107E-05 -5.386 0.2283E-02 -2.641 21.64 0.8684E-03 daphnite 0.2554E-05 -5.593 0.1822E-02 -2.739 17.27 0.5522E-03 chlorite-Mn 0.7479E-07 -7.126 0.5302E-04 -4.276 0.5025 0.1690E-04 diaspore 0.4884E-04 -4.311 0.2930E-02 -2.533 27.77 0.8723E-03 hematite 0.2883E-05 -5.540 0.4604E-03 -3.337 4.363 0.8726E-04 lawsonite 0.9476E-05 -5.023 0.2978E-02 -2.526 28.22 0.9602E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3792E+00 0.3792E+00 1.0000 -0.421 chlorite-Mn 0.1110E-01 0.1110E-01 1.0000 -1.955 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.010552 g Volume = 0.003365 cm3 Porosity: 99.6669% V(tot) - V(min): 0.10070E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0260000 g log = -1.5850 Original solution: 1000.0103000 g Original solution / Rock added: 38461.93 (Water/Rock Ratio), log = 4.5850 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3570E-04 1.0073 0.3783E-04 0.3755E-04 CH4,gas 0.3177E-14 1.0129 0.3386E-14 0.3343E-14 H2,gas 0.9373E-06 1.0006 0.9866E-06 0.9861E-06 H2S,gas 0.4618E-11 0.9959 0.4838E-11 0.4858E-11 S2,gas 0.8561E-30 1.0000 0.9006E-30 0.9006E-30 CO,gas 0.9190E-14 1.0000 0.9668E-14 0.9668E-14 SO3,gas 0.1474E-35 1.0000 0.1551E-35 0.1551E-35 SO2,gas 0.5501E-19 1.0000 0.5787E-19 0.5787E-19 HCl,gas 0.5663E-15 1.0000 0.5957E-15 0.5957E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.79 -6.42 -2.141 0.10966E+05 -4.422 3 CH4,gas 4.81 -11.66 -16.47 -4.118 0.28123E+05 -14.470 4 H2,gas 8.29 0.28 -8.01 -4.575 0.13670E+05 -6.006 5 H2S,gas -5.94 -19.26 -13.32 -6.658 0.22736E+05 -11.315 6 S2,gas -7.03 -39.08 -32.05 -4.930 0.54717E+05 -30.045 7 CO,gas 3.51 -12.50 -16.01 -4.928 0.27345E+05 -14.015 8 SO3,gas 17.43 -20.38 -37.81 -9.452 0.64559E+05 -35.810 9 SO2,gas 1.14 -20.10 -21.24 -5.663 0.36263E+05 -19.238 10 HCl,gas 5.48 -11.75 -17.22 -8.612 0.29411E+05 -15.225 11 acmite 7.74 3.10 -4.64 -0.482 0.79193E+04 15 albite-high 0.75 -3.97 -4.72 -0.363 0.80590E+04 16 albite -0.33 -3.97 -3.64 -0.280 0.62183E+04 19 spessartine 24.55 20.24 -4.31 -0.215 0.73520E+04 20 analcite 3.37 -0.30 -3.67 -0.408 0.62732E+04 21 andalusite 5.06 2.13 -2.94 -0.294 0.50149E+04 22 andradite 39.09 35.26 -3.83 -0.199 0.65413E+04 23 grossular 32.83 28.45 -4.38 -0.219 0.74734E+04 24 anhydrite -5.28 -9.16 -3.88 -1.941 0.66294E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.57 -2.55 -0.851 0.43570E+04 36 brucite 12.58 8.67 -3.91 -0.782 0.66782E+04 37 calcite 0.83 -1.57 -2.40 -0.800 0.40957E+04 40 carpholite-Mg 8.65 7.12 -1.53 -0.102 0.26064E+04 41 carpholite-Fe 6.78 4.90 -1.89 -0.126 0.32187E+04 50 chloritoid-Mg 13.26 10.79 -2.47 -0.165 0.42183E+04 51 chloritoid-Fe 9.24 8.56 -0.67 -0.045 0.11508E+04 52 chloritoid-Mn 11.46 10.61 -0.85 -0.057 0.14577E+04 54 coesite -2.37 -3.67 -1.30 -0.432 0.22154E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.67 -1.12 -0.373 0.19083E+04 67 diopside 16.22 12.55 -3.66 -0.366 0.62559E+04 68 hedenbergite 14.24 10.33 -3.92 -0.392 0.66914E+04 75 epidote 24.78 23.53 -1.24 -0.060 0.21258E+04 76 clinozoisite 22.92 20.13 -2.79 -0.127 0.47701E+04 77 epidote-Fe 29.94 26.93 -3.00 -0.156 0.51290E+04 78 fayalite 14.08 9.21 -4.87 -0.695 0.83105E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.98 -4.21 -0.351 0.71883E+04 91 heulandite -5.71 -8.66 -2.95 -0.134 0.50348E+04 95 jadeite 4.25 -0.30 -4.55 -0.455 0.77763E+04 98 kaolinite -1.27 -1.54 -0.27 -0.024 0.45822E+03 99 kyanite 4.93 2.13 -2.81 -0.281 0.47917E+04 101 laumontite 2.97 2.34 -0.63 -0.042 0.10755E+04 105 lizardite 23.29 18.66 -4.62 -0.385 0.78967E+04 106 magnesite 0.71 -4.12 -4.83 -1.610 0.82458E+04 107 magnetite 20.13 19.04 -1.10 -0.089 0.18711E+04 110 magnesioferrite 26.26 21.26 -4.99 -0.408 0.85275E+04 113 margarite 17.45 15.47 -1.98 -0.079 0.33829E+04 116 microcline -2.43 -5.51 -3.08 -0.237 0.52613E+04 120 muscovite 2.68 0.28 -2.40 -0.141 0.40982E+04 121 paragonite 4.34 1.82 -2.51 -0.148 0.42937E+04 136 prehnite 19.47 17.23 -2.23 -0.131 0.38161E+04 137 prehnite-Fe 22.59 20.63 -1.95 -0.117 0.33341E+04 138 pumpellyite-Fe 46.47 43.80 -2.67 -0.059 0.45629E+04 139 pumpellyite-Mg 49.19 46.02 -3.17 -0.070 0.54122E+04 145 pyroxmangite 7.42 4.82 -2.60 -0.520 0.44372E+04 146 pyrophyllite -6.10 -8.88 -2.78 -0.174 0.47419E+04 147 quartz -2.98 -3.67 -0.68 -0.228 0.11694E+04 152 rhodochrosite -0.96 -4.30 -3.34 -1.114 0.57076E+04 153 rhodonite 7.46 4.82 -2.65 -0.529 0.45165E+04 154 sanidine -1.22 -5.51 -4.29 -0.330 0.73291E+04 156 siderite -2.59 -6.35 -3.76 -1.253 0.64174E+04 157 sillimanite 5.32 2.13 -3.20 -0.320 0.54571E+04 164 stilbite -7.41 -8.66 -1.25 -0.060 0.21343E+04 165 stilpnomelane-Fe 13.18 9.95 -3.23 -0.096 0.55145E+04 168 sudoite-Fe 18.44 13.46 -4.97 -0.160 0.84939E+04 169 sudoite 21.22 17.91 -3.30 -0.106 0.56372E+04 175 tephroite 18.11 13.30 -4.81 -0.687 0.82154E+04 178 topaz-H 4.67 2.13 -2.54 -0.231 0.43408E+04 179 tridymite -2.61 -3.67 -1.05 -0.351 0.17966E+04 188 wairakite 4.06 2.34 -1.71 -0.101 0.29263E+04 189 walstromite 11.53 7.55 -3.97 -0.795 0.67869E+04 190 wollastonite 10.48 7.55 -2.93 -0.586 0.50008E+04 191 pseudo-wollastonite 11.02 7.55 -3.47 -0.693 0.59194E+04 192 zoisite 22.96 20.13 -2.84 -0.129 0.48426E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.86 -3.30 -0.204 0.56320E+04 195 beidellite-H -2.24 -6.71 -4.47 -0.285 0.76295E+04 196 beidellite-K -1.44 -5.85 -4.42 -0.271 0.75458E+04 197 beidellite-Mg -1.71 -5.28 -3.57 -0.221 0.61003E+04 198 beidellite-Na -1.26 -5.35 -4.09 -0.250 0.69803E+04 200 chalcedony -2.79 -3.67 -0.87 -0.291 0.14897E+04 202 montmorillonite-Ca -2.21 -5.12 -2.91 -0.180 0.49619E+04 203 montmorillonite-K -2.16 -6.12 -3.96 -0.242 0.67534E+04 204 montmorillonite-Mg -2.40 -5.54 -3.14 -0.194 0.53613E+04 205 montmorillonite-Na -1.96 -5.61 -3.65 -0.223 0.62261E+04 206 nontronite-Ca 3.28 1.95 -1.33 -0.086 0.22750E+04 207 nontronite-H 2.60 0.10 -2.50 -0.168 0.42682E+04 208 nontronite-K 3.40 0.95 -2.45 -0.157 0.41879E+04 209 nontronite-Mg 3.14 1.53 -1.61 -0.105 0.27549E+04 210 nontronite-Na 3.58 1.46 -2.12 -0.136 0.36241E+04 215 gypsum -4.92 -9.16 -4.24 -1.059 0.72362E+04 225 tobermorite 9.84 5.68 -4.16 -1.135 0.71026E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.44 -3.38 -0.846 0.57796E+04 241 silica-amorphous -2.08 -3.67 -1.59 -0.529 0.27099E+04 243 an20ab80 2.08 -1.24 -3.32 -0.255 0.56683E+04 244 an25ab75 2.71 -0.56 -3.27 -0.251 0.55787E+04 245 an30ab70 3.34 0.12 -3.22 -0.248 0.54974E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0260000 g New total amount of reactant added: 0.0270000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0270000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3098437E-03 Osmotic coef. = 0.9895 True ionic strength = .3256487E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14299E-07 -7.8447 0.13712E-07 -7.8629 0.95900E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13229E-03 -3.8785 0.95886E+00 -0.0182 4 SO4-- 0.25293E-04 -4.5970 0.22565E-04 -4.6466 0.89213E+00 -0.0496 5 HCO3- 0.12605E-04 -4.8994 0.12087E-04 -4.9177 0.95889E+00 -0.0182 6 HS- 0.38169E-11 -11.4183 0.36599E-11 -11.4365 0.95886E+00 -0.0182 7 Al+++ 0.25669E-20 -20.5906 0.20296E-20 -20.6926 0.79071E+00 -0.1020 8 H4SiO4 0.22067E-03 -3.6563 0.22067E-03 -3.6563 0.10000E+01 0.0000 9 Ca++ 0.33310E-04 -4.4774 0.29711E-04 -4.5271 0.89197E+00 -0.0496 10 Mg++ 0.96159E-07 -7.0170 0.85762E-07 -7.0667 0.89188E+00 -0.0497 11 Fe++ 0.57125E-09 -9.2432 0.50949E-09 -9.2929 0.89190E+00 -0.0497 12 K+ 0.57304E-05 -5.2418 0.54948E-05 -5.2600 0.95890E+00 -0.0182 13 Na+ 0.19390E-03 -3.7124 0.18593E-03 -3.7307 0.95886E+00 -0.0182 14 Mn++ 0.63679E-07 -7.1960 0.56797E-07 -7.2457 0.89192E+00 -0.0497 15 HPO4-- 0.13019E-08 -8.8854 0.11615E-08 -8.9350 0.89213E+00 -0.0496 16 HSiO3- 0.16375E-04 -4.7858 0.15701E-04 -4.8041 0.95886E+00 -0.0182 17 Ca(HSiO3)+ 0.10900E-07 -7.9626 0.10452E-07 -7.9808 0.95890E+00 -0.0182 18 Mg(HSiO3)+ 0.39157E-10 -10.4072 0.37548E-10 -10.4254 0.95890E+00 -0.0182 19 NaHSiO3,aq 0.46366E-07 -7.3338 0.46366E-07 -7.3338 0.10000E+01 0.0000 20 AlO+ 0.14532E-11 -11.8377 0.13935E-11 -11.8559 0.95890E+00 -0.0182 21 AlOH+2 0.10732E-15 -15.9693 0.95721E-16 -16.0190 0.89194E+00 -0.0497 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.34537E-05 -5.4617 0.33115E-05 -5.4800 0.95882E+00 -0.0183 24 CH4,aq 0.19239E-17 -17.7158 0.19237E-17 -17.7159 0.99990E+00 0.0000 29 CO,aq 0.60108E-17 -17.2211 0.60108E-17 -17.2211 0.10000E+01 0.0000 30 CO2,aq 0.33421E-06 -6.4760 0.33417E-06 -6.4760 0.99990E+00 0.0000 31 CO3-2 0.91362E-07 -7.0392 0.81502E-07 -7.0888 0.89208E+00 -0.0496 32 CaCO3,aq 0.29658E-07 -7.5279 0.29658E-07 -7.5279 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.94368E-08 -8.0252 0.90490E-08 -8.0434 0.95890E+00 -0.0182 34 CaCl+ 0.65314E-08 -8.1850 0.62630E-08 -8.2032 0.95890E+00 -0.0182 35 CaCl2,aq 0.19291E-12 -12.7147 0.19291E-12 -12.7147 0.10000E+01 0.0000 36 CaOH+ 0.15933E-06 -6.7977 0.15279E-06 -6.8159 0.95890E+00 -0.0182 37 CaSO4,aq 0.20889E-06 -6.6801 0.20889E-06 -6.6801 0.10000E+01 0.0000 38 HCl,aq 0.34120E-12 -12.4670 0.34120E-12 -12.4670 0.10000E+01 0.0000 43 FeCl+ 0.10947E-12 -12.9607 0.10497E-12 -12.9789 0.95890E+00 -0.0182 46 FeO,aq 0.10715E-09 -9.9700 0.10715E-09 -9.9700 0.10000E+01 0.0000 47 FeOH+ 0.12846E-08 -8.8912 0.12318E-08 -8.9095 0.95890E+00 -0.0182 48 HFeO2- 0.87657E-10 -10.0572 0.84051E-10 -10.0755 0.95886E+00 -0.0182 49 FeO+ 0.11829E-12 -12.9270 0.11343E-12 -12.9453 0.95890E+00 -0.0182 50 FeOH+2 0.32449E-18 -18.4888 0.28943E-18 -18.5385 0.89194E+00 -0.0497 51 FeO2- 0.12365E-09 -9.9078 0.11857E-09 -9.9260 0.95886E+00 -0.0182 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.69845E-09 -9.1559 0.69839E-09 -9.1559 0.99990E+00 0.0000 54 KCl,aq 0.12871E-10 -10.8904 0.12871E-10 -10.8904 0.10000E+01 0.0000 55 KHSO4,aq 0.45496E-17 -17.3420 0.45496E-17 -17.3420 0.10000E+01 0.0000 56 KOH,aq 0.17469E-09 -9.7577 0.17469E-09 -9.7577 0.10000E+01 0.0000 57 KSO4- 0.19922E-08 -8.7007 0.19102E-08 -8.7189 0.95886E+00 -0.0182 58 MgCO3,aq 0.21392E-10 -10.6698 0.21392E-10 -10.6698 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27777E-10 -10.5563 0.26635E-10 -10.5745 0.95890E+00 -0.0182 60 MgCl+ 0.17115E-10 -10.7666 0.16412E-10 -10.7848 0.95890E+00 -0.0182 61 MgOH+ 0.25480E-08 -8.5938 0.24432E-08 -8.6120 0.95890E+00 -0.0182 63 MnO,aq 0.31887E-09 -9.4964 0.31887E-09 -9.4964 0.10000E+01 0.0000 64 MnOH+ 0.13303E-07 -7.8760 0.12756E-07 -7.8943 0.95890E+00 -0.0182 65 MnO2-2 0.65744E-16 -16.1821 0.58649E-16 -16.2317 0.89208E+00 -0.0496 66 HMnO2- 0.18172E-12 -12.7406 0.17424E-12 -12.7588 0.95886E+00 -0.0182 69 MnCl+ 0.47422E-10 -10.3240 0.45473E-10 -10.3422 0.95890E+00 -0.0182 70 MnSO4,aq 0.36321E-09 -9.4398 0.36321E-09 -9.4398 0.10000E+01 0.0000 71 NaCl,aq 0.80310E-08 -8.0952 0.80310E-08 -8.0952 0.10000E+01 0.0000 72 NaOH,aq 0.59579E-08 -8.2249 0.59579E-08 -8.2249 0.10000E+01 0.0000 74 OH- 0.45623E-04 -4.3408 0.43744E-04 -4.3591 0.95882E+00 -0.0183 82 H3PO4,aq 0.14060E-14 -14.8520 0.14060E-14 -14.8520 0.10000E+01 0.0000 83 H2PO4- 0.29120E-09 -9.5358 0.27923E-09 -9.5540 0.95888E+00 -0.0182 84 PO4-3 0.93443E-13 -13.0295 0.73974E-13 -13.1309 0.79165E+00 -0.1015 88 HP2O7-3 0.11541E-18 -18.9378 0.91253E-19 -19.0398 0.79072E+00 -0.1020 90 H2S,aq 0.15080E-12 -12.8216 0.15079E-12 -12.8216 0.99990E+00 0.0000 96 SO2,aq 0.12415E-19 -19.9061 0.12415E-19 -19.9061 0.10000E+01 0.0000 97 SO3-2 0.24078E-14 -14.6184 0.21487E-14 -14.6678 0.89239E+00 -0.0494 98 HSO3- 0.17983E-14 -14.7451 0.17243E-14 -14.7634 0.95886E+00 -0.0182 99 HSO4- 0.29939E-09 -9.5238 0.28709E-09 -9.5420 0.95892E+00 -0.0182 101 S2O3-2 0.44951E-19 -19.3473 0.40100E-19 -19.3969 0.89208E+00 -0.0496 Charge balance for all species = 0.2014E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1429860E-07 -.7588795E-04 -.7648779E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999630E+06 0.0000 3 Cl- 0.1379609E-03 0.1379755E-03 0.4891473E+01 3.9844 4 SO4-- 0.2529317E-04 0.2550458E-04 0.2449924E+01 11.0792 5 HCO3- 0.1260542E-04 0.1307013E-04 0.7974743E+00 2.9452 6 HS- 0.3816897E-11 0.1376769E-09 0.4553088E-05 -3.5736 7 Al+++ 0.2566865E-20 0.3474067E-05 0.9373223E-01 2.8961 8 H4SiO4 0.2206718E-03 0.2371042E-03 0.2278856E+02 -3.6563 9 Ca++ 0.3330979E-04 0.3373454E-04 0.1351965E+01 11.1987 10 Mg++ 0.9615902E-07 0.9881241E-07 0.2402242E-02 8.6591 11 Fe++ 0.5712463E-09 0.2378010E-08 0.1328000E-03 6.4329 12 K+ 0.5730360E-05 0.5732540E-05 0.2241458E+00 2.6028 13 Na+ 0.1939041E-03 0.1939645E-03 0.4459046E+01 4.1322 14 Mn++ 0.6367929E-07 0.7771206E-07 0.4269194E-02 8.4801 15 HPO4-- 0.1301938E-08 0.1593237E-08 0.1529119E-03 6.7908 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4340399E-03 -.7588721E-04 -.3581527E-03 0.0000000E+00 2 H2O 0.5550791E+02 0.5550775E+02 0.1661105E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2625273E-04 0.2550433E-04 0.7483997E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7482620E-06 0.1376755E-09 -.7483997E-06 0.0000000E+00 7 Al+++ 0.8804002E-04 0.3474033E-05 0.8456599E-04 0.0000000E+00 8 H4SiO4 0.2811451E-03 0.2371019E-03 0.4404324E-04 0.0000000E+00 9 Ca++ 0.4552491E-04 0.3373421E-04 0.1179070E-04 0.0000000E+00 10 Mg++ 0.2142857E-04 0.9881145E-07 0.2132976E-04 0.0000000E+00 11 Fe++ 0.1925123E-04 0.2377987E-08 0.1924885E-04 0.0000000E+00 12 K+ 0.5732484E-05 0.5732484E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1939626E-03 0.1939626E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.4681421E-06 0.7771130E-07 0.3904308E-06 0.0000000E+00 15 HPO4-- 0.1597746E-06 0.1593222E-08 0.1581813E-06 0.0000000E+00 Chg. balance for solid moles: 0.5336E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0270000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5273E-07 -7.278 0.2649E-04 -4.577 0.2345 0.8416E-05 clinochlore 0.4266E-05 -5.370 0.2371E-02 -2.625 20.99 0.9019E-03 daphnite 0.2652E-05 -5.576 0.1892E-02 -2.723 16.75 0.5735E-03 chlorite-Mn 0.7809E-07 -7.107 0.5536E-04 -4.257 0.4901 0.1764E-04 diaspore 0.4752E-04 -4.323 0.2851E-02 -2.545 25.24 0.8487E-03 hematite 0.2994E-05 -5.524 0.4781E-03 -3.321 4.232 0.9061E-04 lawsonite 0.1153E-04 -4.938 0.3622E-02 -2.441 32.07 0.1168E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3791E+00 0.3791E+00 1.0000 -0.421 chlorite-Mn 0.1116E-01 0.1116E-01 1.0000 -1.952 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.011296 g Volume = 0.003609 cm3 Porosity: 99.6430% V(tot) - V(min): 0.10072E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0270000 g log = -1.5686 Original solution: 1000.0103000 g Original solution / Rock added: 37037.42 (Water/Rock Ratio), log = 4.5686 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3610E-04 1.0073 0.3825E-04 0.3797E-04 CH4,gas 0.2855E-14 1.0129 0.3042E-14 0.3003E-14 H2,gas 0.9101E-06 1.0006 0.9579E-06 0.9574E-06 H2S,gas 0.4198E-11 0.9959 0.4398E-11 0.4416E-11 S2,gas 0.7505E-30 1.0000 0.7895E-30 0.7895E-30 CO,gas 0.9022E-14 1.0000 0.9491E-14 0.9491E-14 SO3,gas 0.1508E-35 1.0000 0.1586E-35 0.1586E-35 SO2,gas 0.5464E-19 1.0000 0.5748E-19 0.5748E-19 HCl,gas 0.5727E-15 1.0000 0.6025E-15 0.6025E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 0.15165E-10 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.78 -6.42 -2.139 0.10957E+05 -4.417 3 CH4,gas 4.81 -11.71 -16.52 -4.129 0.28202E+05 -14.517 4 H2,gas 8.29 0.27 -8.02 -4.582 0.13692E+05 -6.019 5 H2S,gas -5.94 -19.30 -13.36 -6.678 0.22806E+05 -11.357 6 S2,gas -7.03 -39.14 -32.10 -4.939 0.54814E+05 -30.103 7 CO,gas 3.51 -12.51 -16.02 -4.930 0.27358E+05 -14.023 8 SO3,gas 17.43 -20.37 -37.80 -9.450 0.64542E+05 -35.800 9 SO2,gas 1.14 -20.10 -21.24 -5.664 0.36268E+05 -19.240 10 HCl,gas 5.48 -11.74 -17.22 -8.610 0.29403E+05 -15.220 11 acmite 7.74 3.12 -4.62 -0.480 0.78866E+04 15 albite-high 0.75 -3.94 -4.69 -0.361 0.80082E+04 16 albite -0.33 -3.94 -3.61 -0.278 0.61675E+04 19 spessartine 24.55 20.26 -4.29 -0.214 0.73185E+04 20 analcite 3.37 -0.28 -3.65 -0.406 0.62405E+04 21 andalusite 5.06 2.14 -2.93 -0.293 0.49968E+04 22 andradite 39.09 35.22 -3.86 -0.201 0.65956E+04 23 grossular 32.83 28.42 -4.41 -0.220 0.75277E+04 24 anhydrite -5.28 -9.17 -3.89 -1.947 0.66487E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.58 -2.57 -0.856 0.43849E+04 36 brucite 12.58 8.66 -3.92 -0.784 0.66891E+04 37 calcite 0.83 -1.58 -2.42 -0.805 0.41236E+04 40 carpholite-Mg 8.65 7.14 -1.51 -0.101 0.25811E+04 41 carpholite-Fe 6.78 4.91 -1.87 -0.125 0.31935E+04 50 chloritoid-Mg 13.26 10.79 -2.47 -0.164 0.42110E+04 51 chloritoid-Fe 9.24 8.57 -0.67 -0.045 0.11437E+04 52 chloritoid-Mn 11.46 10.62 -0.85 -0.056 0.14465E+04 54 coesite -2.37 -3.66 -1.29 -0.429 0.21974E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.66 -1.11 -0.369 0.18902E+04 67 diopside 16.22 12.55 -3.67 -0.367 0.62668E+04 68 hedenbergite 14.24 10.32 -3.93 -0.393 0.67023E+04 75 epidote 24.78 23.52 -1.26 -0.061 0.21439E+04 76 clinozoisite 22.92 20.12 -2.80 -0.127 0.47882E+04 77 epidote-Fe 29.94 26.92 -3.01 -0.157 0.51470E+04 78 fayalite 14.08 9.21 -4.87 -0.696 0.83143E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.99 -4.21 -0.351 0.71850E+04 91 heulandite -5.71 -8.60 -2.90 -0.132 0.49444E+04 95 jadeite 4.25 -0.28 -4.54 -0.454 0.77435E+04 98 kaolinite -1.27 -1.52 -0.25 -0.022 0.42206E+03 99 kyanite 4.93 2.14 -2.80 -0.280 0.47736E+04 101 laumontite 2.97 2.37 -0.61 -0.041 0.10393E+04 105 lizardite 23.29 18.66 -4.62 -0.385 0.78931E+04 106 magnesite 0.71 -4.12 -4.83 -1.610 0.82484E+04 107 magnetite 20.13 19.03 -1.10 -0.090 0.18821E+04 113 margarite 17.45 15.47 -1.98 -0.079 0.33829E+04 116 microcline -2.43 -5.47 -3.04 -0.234 0.51874E+04 120 muscovite 2.68 0.32 -2.36 -0.139 0.40242E+04 121 paragonite 4.34 1.85 -2.48 -0.146 0.42429E+04 136 prehnite 19.47 17.22 -2.25 -0.132 0.38341E+04 137 prehnite-Fe 22.59 20.62 -1.96 -0.118 0.33521E+04 138 pumpellyite-Fe 46.47 43.77 -2.70 -0.060 0.46100E+04 139 pumpellyite-Mg 49.19 46.00 -3.20 -0.071 0.54592E+04 145 pyroxmangite 7.42 4.82 -2.59 -0.518 0.44261E+04 146 pyrophyllite -6.10 -8.83 -2.73 -0.171 0.46696E+04 147 quartz -2.98 -3.66 -0.67 -0.225 0.11513E+04 152 rhodochrosite -0.96 -4.30 -3.34 -1.114 0.57062E+04 153 rhodonite 7.46 4.82 -2.64 -0.528 0.45053E+04 154 sanidine -1.22 -5.47 -4.25 -0.327 0.72551E+04 156 siderite -2.59 -6.35 -3.76 -1.253 0.64201E+04 157 sillimanite 5.32 2.14 -3.19 -0.319 0.54390E+04 164 stilbite -7.41 -8.60 -1.20 -0.057 0.20439E+04 165 stilpnomelane-Fe 13.18 10.01 -3.17 -0.095 0.54147E+04 168 sudoite-Fe 18.44 13.48 -4.96 -0.160 0.84615E+04 169 sudoite 21.22 17.93 -3.28 -0.106 0.56047E+04 175 tephroite 18.11 13.30 -4.81 -0.687 0.82112E+04 178 topaz-H 4.67 2.14 -2.53 -0.230 0.43227E+04 179 tridymite -2.61 -3.66 -1.04 -0.347 0.17786E+04 188 wairakite 4.06 2.37 -1.69 -0.100 0.28901E+04 189 walstromite 11.53 7.54 -3.99 -0.797 0.68050E+04 190 wollastonite 10.48 7.54 -2.94 -0.588 0.50189E+04 191 pseudo-wollastonite 11.02 7.54 -3.48 -0.695 0.59375E+04 192 zoisite 22.96 20.12 -2.85 -0.129 0.48607E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.82 -3.26 -0.202 0.55717E+04 195 beidellite-H -2.24 -6.67 -4.43 -0.283 0.75632E+04 196 beidellite-K -1.44 -5.81 -4.38 -0.268 0.74729E+04 197 beidellite-Mg -1.71 -5.24 -3.53 -0.219 0.60358E+04 198 beidellite-Na -1.26 -5.31 -4.05 -0.248 0.69151E+04 200 chalcedony -2.79 -3.66 -0.86 -0.287 0.14716E+04 202 montmorillonite-Ca -2.21 -5.08 -2.87 -0.177 0.48991E+04 203 montmorillonite-K -2.16 -6.07 -3.91 -0.240 0.66782E+04 204 montmorillonite-Mg -2.40 -5.50 -3.10 -0.192 0.52943E+04 205 montmorillonite-Na -1.96 -5.57 -3.61 -0.221 0.61585E+04 206 nontronite-Ca 3.28 1.98 -1.30 -0.084 0.22146E+04 207 nontronite-H 2.60 0.13 -2.46 -0.165 0.42018E+04 208 nontronite-K 3.40 0.99 -2.41 -0.155 0.41150E+04 209 nontronite-Mg 3.14 1.56 -1.58 -0.102 0.26903E+04 210 nontronite-Na 3.58 1.50 -2.08 -0.134 0.35589E+04 215 gypsum -4.92 -9.17 -4.25 -1.062 0.72555E+04 225 tobermorite 9.84 5.67 -4.17 -1.137 0.71146E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.43 -3.39 -0.848 0.57906E+04 241 silica-amorphous -2.08 -3.66 -1.58 -0.525 0.26918E+04 243 an20ab80 2.08 -1.22 -3.30 -0.254 0.56276E+04 244 an25ab75 2.71 -0.54 -3.24 -0.250 0.55406E+04 245 an30ab70 3.34 0.15 -3.20 -0.246 0.54618E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0270000 g New total amount of reactant added: 0.0280000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0280000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3086307E-03 Osmotic coef. = 0.9895 True ionic strength = .3244794E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14451E-07 -7.8401 0.13859E-07 -7.8583 0.95904E+00 -0.0182 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13229E-03 -3.8785 0.95890E+00 -0.0182 4 SO4-- 0.25298E-04 -4.5969 0.22573E-04 -4.6464 0.89228E+00 -0.0495 5 HCO3- 0.12604E-04 -4.8995 0.12087E-04 -4.9177 0.95893E+00 -0.0182 6 HS- 0.34364E-11 -11.4639 0.32952E-11 -11.4821 0.95890E+00 -0.0182 7 Al+++ 0.26492E-20 -20.5769 0.20955E-20 -20.6787 0.79101E+00 -0.1018 8 H4SiO4 0.22602E-03 -3.6459 0.22602E-03 -3.6459 0.10000E+01 0.0000 9 Ca++ 0.32430E-04 -4.4890 0.28932E-04 -4.5386 0.89212E+00 -0.0496 10 Mg++ 0.96811E-07 -7.0141 0.86358E-07 -7.0637 0.89203E+00 -0.0496 11 Fe++ 0.57505E-09 -9.2403 0.51297E-09 -9.2899 0.89205E+00 -0.0496 12 K+ 0.59426E-05 -5.2260 0.56986E-05 -5.2442 0.95894E+00 -0.0182 13 Na+ 0.19516E-03 -3.7096 0.18714E-03 -3.7278 0.95890E+00 -0.0182 14 Mn++ 0.64435E-07 -7.1909 0.57481E-07 -7.2405 0.89207E+00 -0.0496 15 HPO4-- 0.13802E-08 -8.8601 0.12315E-08 -8.9096 0.89228E+00 -0.0495 16 HSiO3- 0.16593E-04 -4.7801 0.15911E-04 -4.7983 0.95890E+00 -0.0182 17 Ca(HSiO3)+ 0.10756E-07 -7.9684 0.10314E-07 -7.9866 0.95894E+00 -0.0182 18 Mg(HSiO3)+ 0.39955E-10 -10.3984 0.38314E-10 -10.4166 0.95894E+00 -0.0182 19 NaHSiO3,aq 0.47292E-07 -7.3252 0.47292E-07 -7.3252 0.10000E+01 0.0000 20 AlO+ 0.14687E-11 -11.8331 0.14084E-11 -11.8513 0.95894E+00 -0.0182 21 AlOH+2 0.10961E-15 -15.9602 0.97782E-16 -16.0097 0.89209E+00 -0.0496 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.34170E-05 -5.4664 0.32764E-05 -5.4846 0.95886E+00 -0.0182 24 CH4,aq 0.17315E-17 -17.7616 0.17313E-17 -17.7616 0.99990E+00 0.0000 29 CO,aq 0.59012E-17 -17.2291 0.59012E-17 -17.2291 0.10000E+01 0.0000 30 CO2,aq 0.33776E-06 -6.4714 0.33773E-06 -6.4714 0.99990E+00 0.0000 31 CO3-2 0.90373E-07 -7.0440 0.80634E-07 -7.0935 0.89223E+00 -0.0495 32 CaCO3,aq 0.28572E-07 -7.5441 0.28572E-07 -7.5441 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.91883E-08 -8.0368 0.88111E-08 -8.0550 0.95894E+00 -0.0182 34 CaCl+ 0.63601E-08 -8.1965 0.60990E-08 -8.2147 0.95894E+00 -0.0182 35 CaCl2,aq 0.18786E-12 -12.7262 0.18786E-12 -12.7262 0.10000E+01 0.0000 36 CaOH+ 0.15350E-06 -6.8139 0.14720E-06 -6.8321 0.95894E+00 -0.0182 37 CaSO4,aq 0.20349E-06 -6.6915 0.20349E-06 -6.6915 0.10000E+01 0.0000 38 HCl,aq 0.34486E-12 -12.4624 0.34486E-12 -12.4624 0.10000E+01 0.0000 43 FeCl+ 0.11022E-12 -12.9577 0.10569E-12 -12.9759 0.95894E+00 -0.0182 46 FeO,aq 0.10561E-09 -9.9763 0.10561E-09 -9.9763 0.10000E+01 0.0000 47 FeOH+ 0.12796E-08 -8.8929 0.12271E-08 -8.9111 0.95894E+00 -0.0182 48 HFeO2- 0.85476E-10 -10.0682 0.81963E-10 -10.0864 0.95890E+00 -0.0182 49 FeO+ 0.11955E-12 -12.9224 0.11464E-12 -12.9406 0.95894E+00 -0.0182 50 FeOH+2 0.33142E-18 -18.4796 0.29566E-18 -18.5292 0.89209E+00 -0.0496 51 FeO2- 0.12234E-09 -9.9124 0.11731E-09 -9.9307 0.95890E+00 -0.0182 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.67849E-09 -9.1685 0.67842E-09 -9.1685 0.99990E+00 0.0000 54 KCl,aq 0.13348E-10 -10.8746 0.13348E-10 -10.8746 0.10000E+01 0.0000 55 KHSO4,aq 0.47707E-17 -17.3214 0.47707E-17 -17.3214 0.10000E+01 0.0000 56 KOH,aq 0.17925E-09 -9.7465 0.17925E-09 -9.7465 0.10000E+01 0.0000 57 KSO4- 0.20668E-08 -8.6847 0.19818E-08 -8.7029 0.95890E+00 -0.0182 58 MgCO3,aq 0.21311E-10 -10.6714 0.21311E-10 -10.6714 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27967E-10 -10.5534 0.26819E-10 -10.5716 0.95894E+00 -0.0182 60 MgCl+ 0.17234E-10 -10.7636 0.16527E-10 -10.7818 0.95894E+00 -0.0182 61 MgOH+ 0.25384E-08 -8.5954 0.24342E-08 -8.6137 0.95894E+00 -0.0182 63 MnO,aq 0.31591E-09 -9.5004 0.31591E-09 -9.5004 0.10000E+01 0.0000 64 MnOH+ 0.13320E-07 -7.8755 0.12773E-07 -7.8937 0.95894E+00 -0.0182 65 MnO2-2 0.63750E-16 -16.1955 0.56880E-16 -16.2450 0.89223E+00 -0.0495 66 HMnO2- 0.17812E-12 -12.7493 0.17080E-12 -12.7675 0.95890E+00 -0.0182 69 MnCl+ 0.47993E-10 -10.3188 0.46022E-10 -10.3370 0.95894E+00 -0.0182 70 MnSO4,aq 0.36772E-09 -9.4345 0.36772E-09 -9.4345 0.10000E+01 0.0000 71 NaCl,aq 0.80836E-08 -8.0924 0.80836E-08 -8.0924 0.10000E+01 0.0000 72 NaOH,aq 0.59332E-08 -8.2267 0.59332E-08 -8.2267 0.10000E+01 0.0000 74 OH- 0.45138E-04 -4.3455 0.43281E-04 -4.3637 0.95886E+00 -0.0182 82 H3PO4,aq 0.15228E-14 -14.8173 0.15228E-14 -14.8173 0.10000E+01 0.0000 83 H2PO4- 0.31204E-09 -9.5058 0.29923E-09 -9.5240 0.95892E+00 -0.0182 84 PO4-3 0.97987E-13 -13.0088 0.77600E-13 -13.1101 0.79194E+00 -0.1013 88 HP2O7-3 0.13107E-18 -18.8825 0.10368E-18 -18.9843 0.79102E+00 -0.1018 90 H2S,aq 0.13723E-12 -12.8626 0.13721E-12 -12.8626 0.99990E+00 0.0000 96 SO2,aq 0.12324E-19 -19.9092 0.12324E-19 -19.9092 0.10000E+01 0.0000 97 SO3-2 0.23395E-14 -14.6309 0.20881E-14 -14.6803 0.89254E+00 -0.0494 98 HSO3- 0.17662E-14 -14.7530 0.16936E-14 -14.7712 0.95890E+00 -0.0182 99 HSO4- 0.30270E-09 -9.5190 0.29028E-09 -9.5372 0.95896E+00 -0.0182 101 S2O3-2 0.40913E-19 -19.3881 0.36504E-19 -19.4377 0.89223E+00 -0.0495 Charge balance for all species = 0.2015E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1445109E-07 -.7546331E-04 -.7605976E-01 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999625E+06 0.0000 3 Cl- 0.1379610E-03 0.1379756E-03 0.4891472E+01 3.9798 4 SO4-- 0.2529850E-04 0.2550459E-04 0.2449924E+01 11.0701 5 HCO3- 0.1260418E-04 0.1307013E-04 0.7974741E+00 2.9406 6 HS- 0.3436409E-11 0.1324560E-09 0.4380426E-05 -3.6239 7 Al+++ 0.2649199E-20 0.3437334E-05 0.9274109E-01 2.8961 8 H4SiO4 0.2260195E-03 0.2426710E-03 0.2332359E+02 -3.6459 9 Ca++ 0.3243036E-04 0.3284222E-04 0.1316203E+01 11.1779 10 Mg++ 0.9681084E-07 0.9945567E-07 0.2417879E-02 8.6528 11 Fe++ 0.5750476E-09 0.2371786E-08 0.1324524E-03 6.4266 12 K+ 0.5942598E-05 0.5944858E-05 0.2324475E+00 2.6140 13 Na+ 0.1951585E-03 0.1952198E-03 0.4487902E+01 4.1304 14 Mn++ 0.6443519E-07 0.7848708E-07 0.4311768E-02 8.4760 15 HPO4-- 0.1380160E-08 0.1692304E-08 0.1624198E-03 6.8070 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4505984E-03 -.7546256E-04 -.3751359E-03 0.0000000E+00 2 H2O 0.5550790E+02 0.5550773E+02 0.1693839E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2628045E-04 0.2550434E-04 0.7761079E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7759754E-06 0.1324546E-09 -.7761079E-06 0.0000000E+00 7 Al+++ 0.9130077E-04 0.3437299E-05 0.8786347E-04 0.0000000E+00 8 H4SiO4 0.2915579E-03 0.2426686E-03 0.4888932E-04 0.0000000E+00 9 Ca++ 0.4667505E-04 0.3284189E-04 0.1383316E-04 0.0000000E+00 10 Mg++ 0.2222222E-04 0.9945468E-07 0.2212277E-04 0.0000000E+00 11 Fe++ 0.1996424E-04 0.2371762E-08 0.1996187E-04 0.0000000E+00 12 K+ 0.5944798E-05 0.5944798E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1952178E-03 0.1952178E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.4854807E-06 0.7848629E-07 0.4069944E-06 0.0000000E+00 15 HPO4-- 0.1656921E-06 0.1692287E-08 0.1639999E-06 0.0000000E+00 Chg. balance for solid moles: -.2149E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0280000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5467E-07 -7.262 0.2746E-04 -4.561 0.2281 0.8726E-05 clinochlore 0.4425E-05 -5.354 0.2459E-02 -2.609 20.43 0.9355E-03 daphnite 0.2751E-05 -5.561 0.1963E-02 -2.707 16.30 0.5947E-03 chlorite-Mn 0.8140E-07 -7.089 0.5771E-04 -4.239 0.4794 0.1839E-04 diaspore 0.4623E-04 -4.335 0.2773E-02 -2.557 23.04 0.8257E-03 hematite 0.3104E-05 -5.508 0.4958E-03 -3.305 4.119 0.9397E-04 lawsonite 0.1356E-04 -4.868 0.4261E-02 -2.370 35.40 0.1374E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3791E+00 0.3791E+00 1.0000 -0.421 chlorite-Mn 0.1122E-01 0.1122E-01 1.0000 -1.950 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.012037 g Volume = 0.003851 cm3 Porosity: 99.6192% V(tot) - V(min): 0.10073E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0280000 g log = -1.5528 Original solution: 1000.0103000 g Original solution / Rock added: 35714.65 (Water/Rock Ratio), log = 4.5528 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3648E-04 1.0073 0.3866E-04 0.3838E-04 CH4,gas 0.2569E-14 1.0129 0.2738E-14 0.2703E-14 H2,gas 0.8840E-06 1.0006 0.9305E-06 0.9300E-06 H2S,gas 0.3820E-11 0.9959 0.4002E-11 0.4018E-11 S2,gas 0.6586E-30 1.0000 0.6928E-30 0.6928E-30 CO,gas 0.8858E-14 1.0000 0.9318E-14 0.9318E-14 SO3,gas 0.1541E-35 1.0000 0.1621E-35 0.1621E-35 SO2,gas 0.5424E-19 1.0000 0.5706E-19 0.5706E-19 HCl,gas 0.5788E-15 1.0000 0.6089E-15 0.6089E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.78 -6.41 -2.138 0.10950E+05 -4.413 3 CH4,gas 4.81 -11.75 -16.56 -4.141 0.28280E+05 -14.563 4 H2,gas 8.29 0.26 -8.03 -4.589 0.13713E+05 -6.031 5 H2S,gas -5.94 -19.34 -13.40 -6.699 0.22876E+05 -11.398 6 S2,gas -7.03 -39.19 -32.16 -4.948 0.54911E+05 -30.159 7 CO,gas 3.51 -12.52 -16.03 -4.933 0.27372E+05 -14.031 8 SO3,gas 17.43 -20.36 -37.79 -9.448 0.64526E+05 -35.790 9 SO2,gas 1.14 -20.11 -21.24 -5.665 0.36273E+05 -19.244 10 HCl,gas 5.48 -11.74 -17.22 -8.608 0.29395E+05 -15.215 11 acmite 7.74 3.14 -4.60 -0.478 0.78542E+04 15 albite-high 0.75 -3.91 -4.66 -0.359 0.79580E+04 16 albite -0.33 -3.91 -3.58 -0.276 0.61173E+04 19 spessartine 24.55 20.28 -4.27 -0.213 0.72860E+04 20 analcite 3.37 -0.27 -3.64 -0.404 0.62081E+04 21 andalusite 5.06 2.15 -2.92 -0.292 0.49791E+04 22 andradite 39.09 35.19 -3.89 -0.202 0.66489E+04 23 grossular 32.83 28.39 -4.44 -0.222 0.75810E+04 24 anhydrite -5.28 -9.19 -3.91 -1.953 0.66682E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.60 -2.58 -0.861 0.44126E+04 36 brucite 12.58 8.65 -3.92 -0.785 0.66997E+04 37 calcite 0.83 -1.60 -2.43 -0.810 0.41513E+04 40 carpholite-Mg 8.65 7.15 -1.50 -0.100 0.25562E+04 41 carpholite-Fe 6.78 4.93 -1.86 -0.124 0.31687E+04 50 chloritoid-Mg 13.26 10.80 -2.46 -0.164 0.42039E+04 51 chloritoid-Fe 9.24 8.57 -0.67 -0.044 0.11367E+04 52 chloritoid-Mn 11.46 10.62 -0.84 -0.056 0.14357E+04 54 coesite -2.37 -3.65 -1.28 -0.426 0.21796E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.65 -1.10 -0.366 0.18725E+04 67 diopside 16.22 12.54 -3.68 -0.368 0.62774E+04 68 hedenbergite 14.24 10.31 -3.93 -0.393 0.67131E+04 75 epidote 24.78 23.51 -1.27 -0.061 0.21616E+04 76 clinozoisite 22.92 20.11 -2.81 -0.128 0.48059E+04 77 epidote-Fe 29.94 26.91 -3.02 -0.157 0.51648E+04 78 fayalite 14.08 9.21 -4.87 -0.696 0.83181E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.99 -4.21 -0.351 0.71817E+04 91 heulandite -5.71 -8.55 -2.84 -0.129 0.48557E+04 95 jadeite 4.25 -0.27 -4.52 -0.452 0.77111E+04 98 kaolinite -1.27 -1.50 -0.23 -0.021 0.38655E+03 99 kyanite 4.93 2.15 -2.79 -0.279 0.47559E+04 101 laumontite 2.97 2.39 -0.59 -0.039 0.10038E+04 105 lizardite 23.29 18.67 -4.62 -0.385 0.78896E+04 106 magnesite 0.71 -4.12 -4.83 -1.611 0.82512E+04 107 magnetite 20.13 19.02 -1.11 -0.090 0.18928E+04 113 margarite 17.45 15.47 -1.98 -0.079 0.33829E+04 116 microcline -2.43 -5.43 -3.00 -0.230 0.51150E+04 120 muscovite 2.68 0.36 -2.31 -0.136 0.39519E+04 121 paragonite 4.34 1.88 -2.46 -0.144 0.41927E+04 122 nepheline 8.38 3.38 -5.00 -0.714 0.85330E+04 136 prehnite 19.47 17.21 -2.26 -0.133 0.38519E+04 137 prehnite-Fe 22.59 20.61 -1.97 -0.119 0.33699E+04 138 pumpellyite-Fe 46.47 43.74 -2.73 -0.061 0.46563E+04 139 pumpellyite-Mg 49.19 45.97 -3.22 -0.072 0.55054E+04 145 pyroxmangite 7.42 4.83 -2.59 -0.517 0.44152E+04 146 pyrophyllite -6.10 -8.79 -2.69 -0.168 0.45986E+04 147 quartz -2.98 -3.65 -0.66 -0.221 0.11335E+04 152 rhodochrosite -0.96 -4.30 -3.34 -1.114 0.57053E+04 153 rhodonite 7.46 4.83 -2.63 -0.526 0.44945E+04 154 sanidine -1.22 -5.43 -4.21 -0.324 0.71827E+04 156 siderite -2.59 -6.35 -3.76 -1.254 0.64230E+04 157 sillimanite 5.32 2.15 -3.18 -0.318 0.54213E+04 164 stilbite -7.41 -8.55 -1.15 -0.055 0.19551E+04 165 stilpnomelane-Fe 13.18 10.07 -3.11 -0.093 0.53169E+04 168 sudoite-Fe 18.44 13.50 -4.94 -0.159 0.84298E+04 169 sudoite 21.22 17.95 -3.26 -0.105 0.55727E+04 175 tephroite 18.11 13.31 -4.81 -0.687 0.82072E+04 178 topaz-H 4.67 2.15 -2.52 -0.229 0.43049E+04 179 tridymite -2.61 -3.65 -1.03 -0.344 0.17608E+04 188 wairakite 4.06 2.39 -1.67 -0.098 0.28546E+04 189 walstromite 11.53 7.53 -4.00 -0.799 0.68228E+04 190 wollastonite 10.48 7.53 -2.95 -0.590 0.50366E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.698 0.59553E+04 192 zoisite 22.96 20.11 -2.86 -0.130 0.48785E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.79 -3.23 -0.200 0.55124E+04 195 beidellite-H -2.24 -6.63 -4.39 -0.280 0.74980E+04 196 beidellite-K -1.44 -5.77 -4.33 -0.265 0.74015E+04 197 beidellite-Mg -1.71 -5.20 -3.50 -0.216 0.59724E+04 198 beidellite-Na -1.26 -5.27 -4.01 -0.246 0.68509E+04 200 chalcedony -2.79 -3.65 -0.85 -0.284 0.14538E+04 202 montmorillonite-Ca -2.21 -5.05 -2.83 -0.175 0.48375E+04 203 montmorillonite-K -2.16 -6.03 -3.87 -0.237 0.66043E+04 204 montmorillonite-Mg -2.40 -5.46 -3.06 -0.189 0.52286E+04 205 montmorillonite-Na -1.96 -5.53 -3.57 -0.218 0.60920E+04 206 nontronite-Ca 3.28 2.02 -1.26 -0.082 0.21553E+04 207 nontronite-H 2.60 0.17 -2.42 -0.162 0.41367E+04 208 nontronite-K 3.40 1.04 -2.37 -0.152 0.40435E+04 209 nontronite-Mg 3.14 1.60 -1.54 -0.100 0.26269E+04 210 nontronite-Na 3.58 1.54 -2.05 -0.131 0.34947E+04 215 gypsum -4.92 -9.19 -4.26 -1.065 0.72749E+04 225 tobermorite 9.84 5.67 -4.17 -1.139 0.71264E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.43 -3.40 -0.849 0.58013E+04 241 silica-amorphous -2.08 -3.65 -1.57 -0.522 0.26740E+04 243 an20ab80 2.08 -1.19 -3.27 -0.252 0.55875E+04 244 an25ab75 2.71 -0.51 -3.22 -0.248 0.55029E+04 245 an30ab70 3.34 0.17 -3.18 -0.244 0.54267E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0280000 g New total amount of reactant added: 0.0290000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0290000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3074629E-03 Osmotic coef. = 0.9895 True ionic strength = .3233625E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14598E-07 -7.8357 0.14000E-07 -7.8539 0.95908E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13230E-03 -3.8785 0.95894E+00 -0.0182 4 SO4-- 0.25304E-04 -4.5968 0.22582E-04 -4.6462 0.89242E+00 -0.0494 5 HCO3- 0.12603E-04 -4.8995 0.12086E-04 -4.9177 0.95897E+00 -0.0182 6 HS- 0.30987E-11 -11.5088 0.29714E-11 -11.5270 0.95894E+00 -0.0182 7 Al+++ 0.27300E-20 -20.5638 0.21602E-20 -20.6655 0.79130E+00 -0.1017 8 H4SiO4 0.23140E-03 -3.6356 0.23140E-03 -3.6356 0.10000E+01 0.0000 9 Ca++ 0.31568E-04 -4.5007 0.28168E-04 -4.5503 0.89227E+00 -0.0495 10 Mg++ 0.97392E-07 -7.0115 0.86890E-07 -7.0610 0.89217E+00 -0.0496 11 Fe++ 0.57843E-09 -9.2378 0.51607E-09 -9.2873 0.89219E+00 -0.0495 12 K+ 0.61548E-05 -5.2108 0.59024E-05 -5.2290 0.95898E+00 -0.0182 13 Na+ 0.19641E-03 -3.7068 0.18835E-03 -3.7250 0.95894E+00 -0.0182 14 Mn++ 0.65135E-07 -7.1862 0.58114E-07 -7.2357 0.89221E+00 -0.0495 15 HPO4-- 0.14625E-08 -8.8349 0.13052E-08 -8.8843 0.89242E+00 -0.0494 16 HSiO3- 0.16816E-04 -4.7743 0.16126E-04 -4.7925 0.95894E+00 -0.0182 17 Ca(HSiO3)+ 0.10612E-07 -7.9742 0.10177E-07 -7.9924 0.95898E+00 -0.0182 18 Mg(HSiO3)+ 0.40741E-10 -10.3900 0.39070E-10 -10.4082 0.95898E+00 -0.0182 19 NaHSiO3,aq 0.48239E-07 -7.3166 0.48239E-07 -7.3166 0.10000E+01 0.0000 20 AlO+ 0.14836E-11 -11.8287 0.14228E-11 -11.8469 0.95898E+00 -0.0182 21 AlOH+2 0.11184E-15 -15.9514 0.99783E-16 -16.0009 0.89223E+00 -0.0495 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.33824E-05 -5.4708 0.32434E-05 -5.4890 0.95890E+00 -0.0182 24 CH4,aq 0.15607E-17 -17.8067 0.15605E-17 -17.8067 0.99990E+00 0.0000 29 CO,aq 0.57936E-17 -17.2371 0.57936E-17 -17.2371 0.10000E+01 0.0000 30 CO2,aq 0.34119E-06 -6.4670 0.34115E-06 -6.4671 0.99990E+00 0.0000 31 CO3-2 0.89443E-07 -7.0485 0.79817E-07 -7.0979 0.89238E+00 -0.0495 32 CaCO3,aq 0.27536E-07 -7.5601 0.27536E-07 -7.5601 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.89447E-08 -8.0484 0.85778E-08 -8.0666 0.95898E+00 -0.0182 34 CaCl+ 0.61921E-08 -8.2082 0.59381E-08 -8.2264 0.95898E+00 -0.0182 35 CaCl2,aq 0.18291E-12 -12.7378 0.18291E-12 -12.7378 0.10000E+01 0.0000 36 CaOH+ 0.14793E-06 -6.8299 0.14187E-06 -6.8481 0.95898E+00 -0.0182 37 CaSO4,aq 0.19818E-06 -6.7029 0.19818E-06 -6.7029 0.10000E+01 0.0000 38 HCl,aq 0.34839E-12 -12.4579 0.34839E-12 -12.4579 0.10000E+01 0.0000 43 FeCl+ 0.11089E-12 -12.9551 0.10634E-12 -12.9733 0.95898E+00 -0.0182 46 FeO,aq 0.10412E-09 -9.9825 0.10412E-09 -9.9825 0.10000E+01 0.0000 47 FeOH+ 0.12743E-08 -8.8947 0.12220E-08 -8.9129 0.95898E+00 -0.0182 48 HFeO2- 0.83415E-10 -10.0788 0.79990E-10 -10.0970 0.95894E+00 -0.0182 49 FeO+ 0.12077E-12 -12.9181 0.11581E-12 -12.9362 0.95898E+00 -0.0182 50 FeOH+2 0.33815E-18 -18.4709 0.30171E-18 -18.5204 0.89223E+00 -0.0495 51 FeO2- 0.12110E-09 -9.9169 0.11613E-09 -9.9351 0.95894E+00 -0.0182 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.65944E-09 -9.1808 0.65938E-09 -9.1809 0.99990E+00 0.0000 54 KCl,aq 0.13826E-10 -10.8593 0.13826E-10 -10.8593 0.10000E+01 0.0000 55 KHSO4,aq 0.49934E-17 -17.3016 0.49934E-17 -17.3016 0.10000E+01 0.0000 56 KOH,aq 0.18379E-09 -9.7357 0.18379E-09 -9.7357 0.10000E+01 0.0000 57 KSO4- 0.21414E-08 -8.6693 0.20534E-08 -8.6875 0.95894E+00 -0.0182 58 MgCO3,aq 0.21225E-10 -10.6732 0.21225E-10 -10.6732 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28137E-10 -10.5507 0.26983E-10 -10.5689 0.95898E+00 -0.0182 60 MgCl+ 0.17340E-10 -10.7609 0.16629E-10 -10.7791 0.95898E+00 -0.0182 61 MgOH+ 0.25282E-08 -8.5972 0.24245E-08 -8.6154 0.95898E+00 -0.0182 63 MnO,aq 0.31298E-09 -9.5045 0.31298E-09 -9.5045 0.10000E+01 0.0000 64 MnOH+ 0.13331E-07 -7.8752 0.12784E-07 -7.8933 0.95898E+00 -0.0182 65 MnO2-2 0.61883E-16 -16.2084 0.55223E-16 -16.2579 0.89238E+00 -0.0495 66 HMnO2- 0.17468E-12 -12.7578 0.16751E-12 -12.7760 0.95894E+00 -0.0182 69 MnCl+ 0.48522E-10 -10.3141 0.46531E-10 -10.3323 0.95898E+00 -0.0182 70 MnSO4,aq 0.37191E-09 -9.4296 0.37191E-09 -9.4296 0.10000E+01 0.0000 71 NaCl,aq 0.81362E-08 -8.0896 0.81362E-08 -8.0896 0.10000E+01 0.0000 72 NaOH,aq 0.59114E-08 -8.2283 0.59114E-08 -8.2283 0.10000E+01 0.0000 74 OH- 0.44681E-04 -4.3499 0.42845E-04 -4.3681 0.95890E+00 -0.0182 82 H3PO4,aq 0.16470E-14 -14.7833 0.16470E-14 -14.7833 0.10000E+01 0.0000 83 H2PO4- 0.33408E-09 -9.4762 0.32037E-09 -9.4944 0.95896E+00 -0.0182 84 PO4-3 0.10277E-12 -12.9881 0.81416E-13 -13.0893 0.79223E+00 -0.1012 88 HP2O7-3 0.14868E-18 -18.8278 0.11765E-18 -18.9294 0.79131E+00 -0.1017 90 H2S,aq 0.12500E-12 -12.9031 0.12499E-12 -12.9031 0.99990E+00 0.0000 96 SO2,aq 0.12228E-19 -19.9127 0.12228E-19 -19.9127 0.10000E+01 0.0000 97 SO3-2 0.22743E-14 -14.6432 0.20302E-14 -14.6925 0.89269E+00 -0.0493 98 HSO3- 0.17346E-14 -14.7608 0.16634E-14 -14.7790 0.95894E+00 -0.0182 99 HSO4- 0.30588E-09 -9.5144 0.29334E-09 -9.5326 0.95900E+00 -0.0182 101 S2O3-2 0.37277E-19 -19.4286 0.33265E-19 -19.4780 0.89238E+00 -0.0495 Charge balance for all species = 0.2015E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1459767E-07 -.7508074E-04 -.7567412E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999619E+06 0.0000 3 Cl- 0.1379612E-03 0.1379756E-03 0.4891471E+01 3.9754 4 SO4-- 0.2530373E-04 0.2550460E-04 0.2449924E+01 11.0615 5 HCO3- 0.1260298E-04 0.1307013E-04 0.7974739E+00 2.9361 6 HS- 0.3098667E-11 0.1274981E-09 0.4216462E-05 -3.6732 7 Al+++ 0.2729968E-20 0.3402751E-05 0.9180798E-01 2.8961 8 H4SiO4 0.2313983E-03 0.2482737E-03 0.2386205E+02 -3.6356 9 Ca++ 0.3156845E-04 0.3196785E-04 0.1281161E+01 11.1575 10 Mg++ 0.9739159E-07 0.1000272E-06 0.2431772E-02 8.6467 11 Fe++ 0.5784289E-09 0.2365080E-08 0.1320778E-03 6.4204 12 K+ 0.6154837E-05 0.6157176E-05 0.2407491E+00 2.6249 13 Na+ 0.1964128E-03 0.1964751E-03 0.4516758E+01 4.1288 14 Mn++ 0.6513484E-07 0.7919903E-07 0.4350878E-02 8.4720 15 HPO4-- 0.1462538E-08 0.1796720E-08 0.1724411E-03 6.8234 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4671569E-03 -.7507997E-04 -.3920770E-03 0.0000000E+00 2 H2O 0.5550789E+02 0.5550771E+02 0.1726889E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2630816E-04 0.2550434E-04 0.8038164E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8036889E-06 0.1274968E-09 -.8038164E-06 0.0000000E+00 7 Al+++ 0.9456151E-04 0.3402716E-05 0.9115879E-04 0.0000000E+00 8 H4SiO4 0.3019707E-03 0.2482711E-03 0.5369959E-04 0.0000000E+00 9 Ca++ 0.4782520E-04 0.3196753E-04 0.1585767E-04 0.0000000E+00 10 Mg++ 0.2301587E-04 0.1000262E-06 0.2291585E-04 0.0000000E+00 11 Fe++ 0.2067725E-04 0.2365056E-08 0.2067488E-04 0.0000000E+00 12 K+ 0.6157113E-05 0.6157113E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1964731E-03 0.1964731E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.5028193E-06 0.7919821E-07 0.4236211E-06 0.0000000E+00 15 HPO4-- 0.1716097E-06 0.1796701E-08 0.1698130E-06 0.0000000E+00 Chg. balance for solid moles: 0.1488E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0290000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5660E-07 -7.247 0.2843E-04 -4.546 0.2226 0.9035E-05 clinochlore 0.4583E-05 -5.339 0.2547E-02 -2.594 19.94 0.9690E-03 daphnite 0.2849E-05 -5.545 0.2033E-02 -2.692 15.91 0.6160E-03 chlorite-Mn 0.8472E-07 -7.072 0.6007E-04 -4.221 0.4702 0.1914E-04 diaspore 0.4498E-04 -4.347 0.2698E-02 -2.569 21.12 0.8032E-03 hematite 0.3215E-05 -5.493 0.5135E-03 -3.289 4.020 0.9732E-04 lawsonite 0.1557E-04 -4.808 0.4894E-02 -2.310 38.31 0.1578E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3790E+00 0.3790E+00 1.0000 -0.421 chlorite-Mn 0.1127E-01 0.1127E-01 1.0000 -1.948 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.012774 g Volume = 0.004092 cm3 Porosity: 99.5955% V(tot) - V(min): 0.10075E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0290000 g log = -1.5376 Original solution: 1000.0103000 g Original solution / Rock added: 34483.11 (Water/Rock Ratio), log = 4.5376 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3685E-04 1.0073 0.3905E-04 0.3877E-04 CH4,gas 0.2316E-14 1.0129 0.2468E-14 0.2436E-14 H2,gas 0.8592E-06 1.0006 0.9044E-06 0.9039E-06 H2S,gas 0.3480E-11 0.9959 0.3645E-11 0.3660E-11 S2,gas 0.5785E-30 1.0000 0.6086E-30 0.6086E-30 CO,gas 0.8696E-14 1.0000 0.9148E-14 0.9148E-14 SO3,gas 0.1573E-35 1.0000 0.1655E-35 0.1655E-35 SO2,gas 0.5382E-19 1.0000 0.5661E-19 0.5661E-19 HCl,gas 0.5848E-15 1.0000 0.6152E-15 0.6152E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.77 -6.41 -2.136 0.10942E+05 -4.408 3 CH4,gas 4.81 -11.80 -16.61 -4.152 0.28357E+05 -14.608 4 H2,gas 8.29 0.24 -8.04 -4.596 0.13734E+05 -6.044 5 H2S,gas -5.94 -19.38 -13.44 -6.719 0.22945E+05 -11.438 6 S2,gas -7.03 -39.25 -32.22 -4.956 0.55007E+05 -30.216 7 CO,gas 3.51 -12.53 -16.04 -4.935 0.27386E+05 -14.039 8 SO3,gas 17.43 -20.35 -37.78 -9.445 0.64510E+05 -35.781 9 SO2,gas 1.14 -20.11 -21.25 -5.666 0.36279E+05 -19.247 10 HCl,gas 5.48 -11.73 -17.21 -8.606 0.29387E+05 -15.211 11 acmite 7.74 3.16 -4.58 -0.476 0.78220E+04 15 albite-high 0.75 -3.88 -4.63 -0.356 0.79084E+04 16 albite -0.33 -3.88 -3.55 -0.273 0.60678E+04 19 spessartine 24.55 20.30 -4.25 -0.212 0.72544E+04 20 analcite 3.37 -0.25 -3.62 -0.402 0.61759E+04 21 andalusite 5.06 2.16 -2.91 -0.291 0.49616E+04 22 andradite 39.09 35.16 -3.92 -0.204 0.67012E+04 23 grossular 32.83 28.36 -4.47 -0.224 0.76333E+04 24 anhydrite -5.28 -9.20 -3.92 -1.958 0.66877E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.61 -2.60 -0.867 0.44400E+04 36 brucite 12.58 8.65 -3.93 -0.786 0.67102E+04 37 calcite 0.83 -1.61 -2.45 -0.816 0.41787E+04 40 carpholite-Mg 8.65 7.17 -1.48 -0.099 0.25318E+04 41 carpholite-Fe 6.78 4.94 -1.84 -0.123 0.31444E+04 50 chloritoid-Mg 13.26 10.80 -2.46 -0.164 0.41970E+04 51 chloritoid-Fe 9.24 8.58 -0.66 -0.044 0.11298E+04 52 chloritoid-Mn 11.46 10.63 -0.83 -0.056 0.14252E+04 54 coesite -2.37 -3.64 -1.27 -0.422 0.21622E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.64 -1.09 -0.362 0.18550E+04 67 diopside 16.22 12.53 -3.68 -0.368 0.62879E+04 68 hedenbergite 14.24 10.31 -3.94 -0.394 0.67237E+04 75 epidote 24.78 23.50 -1.28 -0.062 0.21791E+04 76 clinozoisite 22.92 20.10 -2.82 -0.128 0.48234E+04 77 epidote-Fe 29.94 26.90 -3.04 -0.158 0.51822E+04 78 fayalite 14.08 9.21 -4.87 -0.696 0.83217E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.99 -4.20 -0.350 0.71785E+04 91 heulandite -5.71 -8.50 -2.79 -0.127 0.47685E+04 95 jadeite 4.25 -0.25 -4.50 -0.450 0.76790E+04 98 kaolinite -1.27 -1.48 -0.21 -0.019 0.35167E+03 99 kyanite 4.93 2.16 -2.78 -0.278 0.47384E+04 101 laumontite 2.97 2.41 -0.57 -0.038 0.96890E+03 105 lizardite 23.29 18.67 -4.62 -0.385 0.78861E+04 106 magnesite 0.71 -4.12 -4.83 -1.611 0.82542E+04 107 magnetite 20.13 19.02 -1.11 -0.091 0.19034E+04 113 margarite 17.45 15.47 -1.98 -0.079 0.33829E+04 116 microcline -2.43 -5.39 -2.95 -0.227 0.50441E+04 120 muscovite 2.68 0.41 -2.27 -0.134 0.38810E+04 121 paragonite 4.34 1.91 -2.43 -0.143 0.41431E+04 122 nepheline 8.38 3.39 -4.99 -0.713 0.85183E+04 136 prehnite 19.47 17.20 -2.27 -0.133 0.38693E+04 137 prehnite-Fe 22.59 20.60 -1.98 -0.119 0.33873E+04 138 pumpellyite-Fe 46.47 43.72 -2.75 -0.061 0.47017E+04 139 pumpellyite-Mg 49.19 45.94 -3.25 -0.072 0.55507E+04 145 pyroxmangite 7.42 4.84 -2.58 -0.516 0.44047E+04 146 pyrophyllite -6.10 -8.75 -2.65 -0.166 0.45288E+04 147 quartz -2.98 -3.64 -0.65 -0.218 0.11161E+04 152 rhodochrosite -0.96 -4.30 -3.34 -1.114 0.57047E+04 153 rhodonite 7.46 4.84 -2.63 -0.525 0.44839E+04 154 sanidine -1.22 -5.39 -4.17 -0.320 0.71119E+04 156 siderite -2.59 -6.35 -3.76 -1.254 0.64260E+04 157 sillimanite 5.32 2.16 -3.16 -0.316 0.54038E+04 164 stilbite -7.41 -8.50 -1.09 -0.052 0.18679E+04 165 stilpnomelane-Fe 13.18 10.12 -3.06 -0.091 0.52209E+04 168 sudoite-Fe 18.44 13.52 -4.92 -0.159 0.83986E+04 169 sudoite 21.22 17.97 -3.25 -0.105 0.55414E+04 175 tephroite 18.11 13.31 -4.80 -0.686 0.82036E+04 178 topaz-H 4.67 2.16 -2.51 -0.228 0.42875E+04 179 tridymite -2.61 -3.64 -1.02 -0.340 0.17434E+04 188 wairakite 4.06 2.41 -1.65 -0.097 0.28197E+04 189 walstromite 11.53 7.52 -4.01 -0.801 0.68402E+04 190 wollastonite 10.48 7.52 -2.96 -0.592 0.50541E+04 191 pseudo-wollastonite 11.02 7.52 -3.50 -0.700 0.59727E+04 192 zoisite 22.96 20.10 -2.87 -0.130 0.48959E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.75 -3.19 -0.198 0.54541E+04 195 beidellite-H -2.24 -6.59 -4.35 -0.278 0.74340E+04 196 beidellite-K -1.44 -5.73 -4.29 -0.263 0.73313E+04 197 beidellite-Mg -1.71 -5.17 -3.46 -0.214 0.59101E+04 198 beidellite-Na -1.26 -5.23 -3.98 -0.243 0.67878E+04 200 chalcedony -2.79 -3.64 -0.84 -0.280 0.14364E+04 202 montmorillonite-Ca -2.21 -5.01 -2.80 -0.173 0.47769E+04 203 montmorillonite-K -2.16 -5.99 -3.83 -0.234 0.65319E+04 204 montmorillonite-Mg -2.40 -5.43 -3.02 -0.187 0.51640E+04 205 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60266E+04 206 nontronite-Ca 3.28 2.05 -1.23 -0.080 0.20970E+04 207 nontronite-H 2.60 0.21 -2.39 -0.160 0.40727E+04 208 nontronite-K 3.40 1.08 -2.33 -0.149 0.39734E+04 209 nontronite-Mg 3.14 1.64 -1.50 -0.097 0.25647E+04 210 nontronite-Na 3.58 1.57 -2.01 -0.129 0.34316E+04 215 gypsum -4.92 -9.20 -4.27 -1.068 0.72945E+04 225 tobermorite 9.84 5.66 -4.18 -1.141 0.71380E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.42 -3.40 -0.851 0.58119E+04 241 silica-amorphous -2.08 -3.64 -1.56 -0.519 0.26566E+04 243 an20ab80 2.08 -1.17 -3.25 -0.250 0.55478E+04 244 an25ab75 2.71 -0.49 -3.20 -0.246 0.54657E+04 245 an30ab70 3.34 0.19 -3.16 -0.243 0.53920E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0290000 g New total amount of reactant added: 0.0300000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0300000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3063392E-03 Osmotic coef. = 0.9896 True ionic strength = .3222966E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14738E-07 -7.8316 0.14136E-07 -7.8497 0.95911E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13230E-03 -3.8784 0.95898E+00 -0.0182 4 SO4-- 0.25309E-04 -4.5967 0.22590E-04 -4.6461 0.89256E+00 -0.0494 5 HCO3- 0.12602E-04 -4.8996 0.12085E-04 -4.9177 0.95901E+00 -0.0182 6 HS- 0.27983E-11 -11.5531 0.26835E-11 -11.5713 0.95898E+00 -0.0182 7 Al+++ 0.28089E-20 -20.5515 0.22235E-20 -20.6530 0.79157E+00 -0.1015 8 H4SiO4 0.23681E-03 -3.6256 0.23681E-03 -3.6256 0.10000E+01 0.0000 9 Ca++ 0.30724E-04 -4.5125 0.27418E-04 -4.5620 0.89241E+00 -0.0494 10 Mg++ 0.97901E-07 -7.0092 0.87358E-07 -7.0587 0.89231E+00 -0.0495 11 Fe++ 0.58139E-09 -9.2355 0.51879E-09 -9.2850 0.89233E+00 -0.0495 12 K+ 0.63671E-05 -5.1961 0.61061E-05 -5.2142 0.95901E+00 -0.0182 13 Na+ 0.19767E-03 -3.7041 0.18956E-03 -3.7223 0.95897E+00 -0.0182 14 Mn++ 0.65778E-07 -7.1819 0.58697E-07 -7.2314 0.89235E+00 -0.0495 15 HPO4-- 0.15493E-08 -8.8099 0.13828E-08 -8.8592 0.89256E+00 -0.0494 16 HSiO3- 0.17044E-04 -4.7684 0.16345E-04 -4.7866 0.95898E+00 -0.0182 17 Ca(HSiO3)+ 0.10470E-07 -7.9801 0.10041E-07 -7.9982 0.95902E+00 -0.0182 18 Mg(HSiO3)+ 0.41515E-10 -10.3818 0.39814E-10 -10.4000 0.95902E+00 -0.0182 19 NaHSiO3,aq 0.49208E-07 -7.3080 0.49208E-07 -7.3080 0.10000E+01 0.0000 20 AlO+ 0.14979E-11 -11.8245 0.14365E-11 -11.8427 0.95902E+00 -0.0182 21 AlOH+2 0.11399E-15 -15.9431 0.10172E-15 -15.9926 0.89237E+00 -0.0495 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.33499E-05 -5.4750 0.32123E-05 -5.4932 0.95893E+00 -0.0182 24 CH4,aq 0.14089E-17 -17.8511 0.14088E-17 -17.8512 0.99990E+00 0.0000 29 CO,aq 0.56880E-17 -17.2450 0.56880E-17 -17.2450 0.10000E+01 0.0000 30 CO2,aq 0.34446E-06 -6.4629 0.34443E-06 -6.4629 0.99990E+00 0.0000 31 CO3-2 0.88568E-07 -7.0527 0.79048E-07 -7.1021 0.89251E+00 -0.0494 32 CaCO3,aq 0.26545E-07 -7.5760 0.26545E-07 -7.5760 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.87059E-08 -8.0602 0.83491E-08 -8.0784 0.95902E+00 -0.0182 34 CaCl+ 0.60273E-08 -8.2199 0.57803E-08 -8.2381 0.95902E+00 -0.0182 35 CaCl2,aq 0.17806E-12 -12.7494 0.17806E-12 -12.7494 0.10000E+01 0.0000 36 CaOH+ 0.14261E-06 -6.8458 0.13677E-06 -6.8640 0.95902E+00 -0.0182 37 CaSO4,aq 0.19298E-06 -6.7145 0.19298E-06 -6.7145 0.10000E+01 0.0000 38 HCl,aq 0.35177E-12 -12.4537 0.35177E-12 -12.4537 0.10000E+01 0.0000 43 FeCl+ 0.11147E-12 -12.9528 0.10690E-12 -12.9710 0.95902E+00 -0.0182 46 FeO,aq 0.10267E-09 -9.9886 0.10267E-09 -9.9886 0.10000E+01 0.0000 47 FeOH+ 0.12687E-08 -8.8966 0.12167E-08 -8.9148 0.95902E+00 -0.0182 48 HFeO2- 0.81466E-10 -10.0890 0.78123E-10 -10.1072 0.95898E+00 -0.0182 49 FeO+ 0.12193E-12 -12.9139 0.11693E-12 -12.9321 0.95902E+00 -0.0182 50 FeOH+2 0.34467E-18 -18.4626 0.30757E-18 -18.5121 0.89237E+00 -0.0495 51 FeO2- 0.11994E-09 -9.9211 0.11502E-09 -9.9392 0.95898E+00 -0.0182 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.64125E-09 -9.1930 0.64119E-09 -9.1930 0.99990E+00 0.0000 54 KCl,aq 0.14304E-10 -10.8445 0.14304E-10 -10.8445 0.10000E+01 0.0000 55 KHSO4,aq 0.52176E-17 -17.2825 0.52176E-17 -17.2825 0.10000E+01 0.0000 56 KOH,aq 0.18831E-09 -9.7251 0.18831E-09 -9.7251 0.10000E+01 0.0000 57 KSO4- 0.22160E-08 -8.6544 0.21251E-08 -8.6726 0.95898E+00 -0.0182 58 MgCO3,aq 0.21134E-10 -10.6750 0.21134E-10 -10.6750 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28285E-10 -10.5484 0.27126E-10 -10.5666 0.95902E+00 -0.0182 60 MgCl+ 0.17434E-10 -10.7586 0.16719E-10 -10.7768 0.95902E+00 -0.0182 61 MgOH+ 0.25173E-08 -8.5991 0.24142E-08 -8.6172 0.95902E+00 -0.0182 63 MnO,aq 0.31010E-09 -9.5085 0.31010E-09 -9.5085 0.10000E+01 0.0000 64 MnOH+ 0.13335E-07 -7.8750 0.12788E-07 -7.8932 0.95902E+00 -0.0182 65 MnO2-2 0.60135E-16 -16.2209 0.53671E-16 -16.2703 0.89251E+00 -0.0494 66 HMnO2- 0.17141E-12 -12.7660 0.16438E-12 -12.7842 0.95898E+00 -0.0182 69 MnCl+ 0.49008E-10 -10.3097 0.47000E-10 -10.3279 0.95902E+00 -0.0182 70 MnSO4,aq 0.37577E-09 -9.4251 0.37577E-09 -9.4251 0.10000E+01 0.0000 71 NaCl,aq 0.81888E-08 -8.0868 0.81888E-08 -8.0868 0.10000E+01 0.0000 72 NaOH,aq 0.58924E-08 -8.2297 0.58924E-08 -8.2297 0.10000E+01 0.0000 74 OH- 0.44252E-04 -4.3541 0.42434E-04 -4.3723 0.95893E+00 -0.0182 82 H3PO4,aq 0.17789E-14 -14.7499 0.17789E-14 -14.7499 0.10000E+01 0.0000 83 H2PO4- 0.35736E-09 -9.4469 0.34270E-09 -9.4651 0.95900E+00 -0.0182 84 PO4-3 0.10780E-12 -12.9674 0.85433E-13 -13.0684 0.79250E+00 -0.1010 87 H2P2O7-2 0.10299E-19 -19.9872 0.91919E-20 -20.0366 0.89251E+00 -0.0494 88 HP2O7-3 0.16845E-18 -18.7735 0.13334E-18 -18.8750 0.79158E+00 -0.1015 90 H2S,aq 0.11398E-12 -12.9432 0.11397E-12 -12.9432 0.99990E+00 0.0000 96 SO2,aq 0.12126E-19 -19.9163 0.12126E-19 -19.9163 0.10000E+01 0.0000 97 SO3-2 0.22120E-14 -14.6552 0.19749E-14 -14.7045 0.89282E+00 -0.0492 98 HSO3- 0.17036E-14 -14.7686 0.16337E-14 -14.7868 0.95898E+00 -0.0182 99 HSO4- 0.30894E-09 -9.5101 0.29628E-09 -9.5283 0.95904E+00 -0.0182 101 S2O3-2 0.33998E-19 -19.4686 0.30343E-19 -19.5179 0.89251E+00 -0.0494 Charge balance for all species = 0.2016E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1473822E-07 -.7473903E-04 -.7532967E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999614E+06 0.0000 3 Cl- 0.1379613E-03 0.1379756E-03 0.4891469E+01 3.9713 4 SO4-- 0.2530886E-04 0.2550462E-04 0.2449924E+01 11.0533 5 HCO3- 0.1260181E-04 0.1307014E-04 0.7974737E+00 2.9319 6 HS- 0.2798321E-11 0.1227843E-09 0.4060573E-05 -3.7216 7 Al+++ 0.2808926E-20 0.3370239E-05 0.9093073E-01 2.8961 8 H4SiO4 0.2368073E-03 0.2539111E-03 0.2440387E+02 -3.6256 9 Ca++ 0.3072361E-04 0.3111095E-04 0.1246819E+01 11.1374 10 Mg++ 0.9790054E-07 0.1005262E-06 0.2443904E-02 8.6407 11 Fe++ 0.5813858E-09 0.2357879E-08 0.1316756E-03 6.4144 12 K+ 0.6367075E-05 0.6369494E-05 0.2490507E+00 2.6355 13 Na+ 0.1976671E-03 0.1977304E-03 0.4545614E+01 4.1274 14 Mn++ 0.6577811E-07 0.7984808E-07 0.4386532E-02 8.4680 15 HPO4-- 0.1549295E-08 0.1906761E-08 0.1830023E-03 6.8401 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4837155E-03 -.7473824E-04 -.4089772E-03 0.0000000E+00 2 H2O 0.5550787E+02 0.5550770E+02 0.1760248E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2633587E-04 0.2550435E-04 0.8315251E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8314023E-06 0.1227830E-09 -.8315251E-06 0.0000000E+00 7 Al+++ 0.9782225E-04 0.3370203E-05 0.9445205E-04 0.0000000E+00 8 H4SiO4 0.3123835E-03 0.2539084E-03 0.5847504E-04 0.0000000E+00 9 Ca++ 0.4897534E-04 0.3111062E-04 0.1786472E-04 0.0000000E+00 10 Mg++ 0.2380952E-04 0.1005252E-06 0.2370900E-04 0.0000000E+00 11 Fe++ 0.2139026E-04 0.2357854E-08 0.2138790E-04 0.0000000E+00 12 K+ 0.6369427E-05 0.6369427E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1977283E-03 0.1977283E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.5201579E-06 0.7984724E-07 0.4403106E-06 0.0000000E+00 15 HPO4-- 0.1775273E-06 0.1906741E-08 0.1756206E-06 0.0000000E+00 Chg. balance for solid moles: -.8730E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0300000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5854E-07 -7.233 0.2941E-04 -4.532 0.2177 0.9344E-05 clinochlore 0.4742E-05 -5.324 0.2636E-02 -2.579 19.51 0.1003E-02 daphnite 0.2947E-05 -5.531 0.2103E-02 -2.677 15.57 0.6372E-03 chlorite-Mn 0.8806E-07 -7.055 0.6243E-04 -4.205 0.4622 0.1990E-04 diaspore 0.4375E-04 -4.359 0.2625E-02 -2.581 19.43 0.7814E-03 hematite 0.3326E-05 -5.478 0.5312E-03 -3.275 3.932 0.1007E-03 lawsonite 0.1757E-04 -4.755 0.5522E-02 -2.258 40.88 0.1781E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3790E+00 0.3790E+00 1.0000 -0.421 chlorite-Mn 0.1132E-01 0.1132E-01 1.0000 -1.946 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.013508 g Volume = 0.004332 cm3 Porosity: 99.5720% V(tot) - V(min): 0.10077E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0300000 g log = -1.5229 Original solution: 1000.0103000 g Original solution / Rock added: 33333.68 (Water/Rock Ratio), log = 4.5229 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3721E-04 1.0073 0.3943E-04 0.3914E-04 CH4,gas 0.2091E-14 1.0129 0.2228E-14 0.2199E-14 H2,gas 0.8355E-06 1.0006 0.8794E-06 0.8789E-06 H2S,gas 0.3173E-11 0.9959 0.3324E-11 0.3338E-11 S2,gas 0.5087E-30 1.0000 0.5351E-30 0.5351E-30 CO,gas 0.8538E-14 1.0000 0.8981E-14 0.8981E-14 SO3,gas 0.1604E-35 1.0000 0.1687E-35 0.1687E-35 SO2,gas 0.5337E-19 1.0000 0.5614E-19 0.5614E-19 HCl,gas 0.5904E-15 1.0000 0.6211E-15 0.6211E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.77 -6.40 -2.135 0.10935E+05 -4.404 3 CH4,gas 4.81 -11.84 -16.65 -4.163 0.28433E+05 -14.652 4 H2,gas 8.29 0.23 -8.06 -4.603 0.13755E+05 -6.056 5 H2S,gas -5.94 -19.42 -13.48 -6.739 0.23014E+05 -11.478 6 S2,gas -7.03 -39.30 -32.27 -4.965 0.55103E+05 -30.272 7 CO,gas 3.51 -12.54 -16.05 -4.937 0.27399E+05 -14.047 8 SO3,gas 17.43 -20.35 -37.77 -9.443 0.64496E+05 -35.773 9 SO2,gas 1.14 -20.11 -21.25 -5.667 0.36285E+05 -19.251 10 HCl,gas 5.48 -11.73 -17.21 -8.603 0.29380E+05 -15.207 11 acmite 7.74 3.18 -4.56 -0.474 0.77901E+04 15 albite-high 0.75 -3.85 -4.60 -0.354 0.78594E+04 16 albite -0.33 -3.85 -3.52 -0.271 0.60187E+04 19 spessartine 24.55 20.32 -4.23 -0.212 0.72236E+04 20 analcite 3.37 -0.23 -3.60 -0.400 0.61441E+04 21 andalusite 5.06 2.17 -2.90 -0.290 0.49445E+04 22 andradite 39.09 35.13 -3.95 -0.205 0.67526E+04 23 grossular 32.83 28.33 -4.50 -0.225 0.76847E+04 24 anhydrite -5.28 -9.21 -3.93 -1.964 0.67075E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.63 -2.62 -0.872 0.44672E+04 36 brucite 12.58 8.64 -3.94 -0.787 0.67205E+04 37 calcite 0.83 -1.63 -2.46 -0.821 0.42058E+04 40 carpholite-Mg 8.65 7.18 -1.47 -0.098 0.25078E+04 41 carpholite-Fe 6.78 4.96 -1.83 -0.122 0.31205E+04 50 chloritoid-Mg 13.26 10.81 -2.45 -0.164 0.41901E+04 51 chloritoid-Fe 9.24 8.58 -0.66 -0.044 0.11231E+04 52 chloritoid-Mn 11.46 10.63 -0.83 -0.055 0.14149E+04 54 coesite -2.37 -3.63 -1.26 -0.419 0.21450E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.63 -1.08 -0.359 0.18379E+04 67 diopside 16.22 12.53 -3.69 -0.369 0.62982E+04 68 hedenbergite 14.24 10.30 -3.94 -0.394 0.67340E+04 75 epidote 24.78 23.49 -1.29 -0.062 0.21962E+04 76 clinozoisite 22.92 20.09 -2.83 -0.129 0.48405E+04 77 epidote-Fe 29.94 26.89 -3.05 -0.158 0.51994E+04 78 fayalite 14.08 9.20 -4.88 -0.697 0.83254E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.99 -4.20 -0.350 0.71754E+04 91 heulandite -5.71 -8.45 -2.74 -0.125 0.46828E+04 95 jadeite 4.25 -0.23 -4.48 -0.448 0.76471E+04 98 kaolinite -1.27 -1.46 -0.19 -0.017 0.31740E+03 99 kyanite 4.93 2.17 -2.77 -0.277 0.47213E+04 101 laumontite 2.97 2.43 -0.55 -0.036 0.93463E+03 105 lizardite 23.29 18.67 -4.62 -0.385 0.78827E+04 106 magnesite 0.71 -4.13 -4.84 -1.612 0.82574E+04 107 magnetite 20.13 19.01 -1.12 -0.091 0.19137E+04 113 margarite 17.45 15.47 -1.98 -0.079 0.33829E+04 116 microcline -2.43 -5.35 -2.91 -0.224 0.49747E+04 120 muscovite 2.68 0.45 -2.23 -0.131 0.38116E+04 121 paragonite 4.34 1.94 -2.40 -0.141 0.40941E+04 122 nepheline 8.38 3.40 -4.98 -0.711 0.85036E+04 136 prehnite 19.47 17.19 -2.28 -0.134 0.38865E+04 137 prehnite-Fe 22.59 20.59 -1.99 -0.120 0.34045E+04 138 pumpellyite-Fe 46.47 43.69 -2.78 -0.062 0.47464E+04 139 pumpellyite-Mg 49.19 45.92 -3.28 -0.073 0.55953E+04 145 pyroxmangite 7.42 4.84 -2.57 -0.515 0.43944E+04 146 pyrophyllite -6.10 -8.71 -2.61 -0.163 0.44603E+04 147 quartz -2.98 -3.63 -0.64 -0.215 0.10989E+04 152 rhodochrosite -0.96 -4.30 -3.34 -1.114 0.57045E+04 153 rhodonite 7.46 4.84 -2.62 -0.524 0.44737E+04 154 sanidine -1.22 -5.35 -4.12 -0.317 0.70424E+04 156 siderite -2.59 -6.35 -3.77 -1.255 0.64293E+04 157 sillimanite 5.32 2.17 -3.15 -0.315 0.53867E+04 164 stilbite -7.41 -8.45 -1.04 -0.050 0.17823E+04 165 stilpnomelane-Fe 13.18 10.18 -3.00 -0.090 0.51266E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83679E+04 169 sudoite 21.22 17.99 -3.23 -0.104 0.55105E+04 175 tephroite 18.11 13.31 -4.80 -0.686 0.82002E+04 178 topaz-H 4.67 2.17 -2.50 -0.227 0.42704E+04 179 tridymite -2.61 -3.63 -1.01 -0.337 0.17262E+04 188 wairakite 4.06 2.43 -1.63 -0.096 0.27855E+04 189 walstromite 11.53 7.51 -4.02 -0.803 0.68573E+04 190 wollastonite 10.48 7.51 -2.97 -0.594 0.50712E+04 191 pseudo-wollastonite 11.02 7.51 -3.51 -0.702 0.59898E+04 192 zoisite 22.96 20.09 -2.88 -0.131 0.49130E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.72 -3.16 -0.196 0.53969E+04 195 beidellite-H -2.24 -6.56 -4.32 -0.275 0.73711E+04 196 beidellite-K -1.44 -5.69 -4.25 -0.260 0.72625E+04 197 beidellite-Mg -1.71 -5.13 -3.43 -0.212 0.58489E+04 198 beidellite-Na -1.26 -5.20 -3.94 -0.241 0.67257E+04 200 chalcedony -2.79 -3.63 -0.83 -0.277 0.14193E+04 202 montmorillonite-Ca -2.21 -4.98 -2.76 -0.171 0.47175E+04 203 montmorillonite-K -2.16 -5.94 -3.78 -0.232 0.64608E+04 204 montmorillonite-Mg -2.40 -5.39 -2.99 -0.185 0.51006E+04 205 montmorillonite-Na -1.96 -5.45 -3.49 -0.214 0.59622E+04 206 nontronite-Ca 3.28 2.09 -1.19 -0.077 0.20398E+04 207 nontronite-H 2.60 0.25 -2.35 -0.157 0.40098E+04 208 nontronite-K 3.40 1.12 -2.29 -0.147 0.39046E+04 209 nontronite-Mg 3.14 1.67 -1.47 -0.095 0.25035E+04 210 nontronite-Na 3.58 1.61 -1.97 -0.127 0.33695E+04 215 gypsum -4.92 -9.21 -4.28 -1.071 0.73142E+04 225 tobermorite 9.84 5.65 -4.19 -1.142 0.71494E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.41 -3.41 -0.852 0.58222E+04 241 silica-amorphous -2.08 -3.63 -1.55 -0.515 0.26395E+04 243 an20ab80 2.08 -1.15 -3.23 -0.248 0.55086E+04 244 an25ab75 2.71 -0.47 -3.18 -0.245 0.54290E+04 245 an30ab70 3.34 0.21 -3.14 -0.241 0.53577E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0300000 g New total amount of reactant added: 0.0310000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0310000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3052582E-03 Osmotic coef. = 0.9896 True ionic strength = .3212804E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14873E-07 -7.8276 0.14265E-07 -7.8457 0.95915E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13231E-03 -3.8784 0.95901E+00 -0.0182 4 SO4-- 0.25314E-04 -4.5966 0.22597E-04 -4.6459 0.89269E+00 -0.0493 5 HCO3- 0.12601E-04 -4.8996 0.12085E-04 -4.9178 0.95904E+00 -0.0182 6 HS- 0.25308E-11 -11.5967 0.24270E-11 -11.6149 0.95901E+00 -0.0182 7 Al+++ 0.28858E-20 -20.5397 0.22851E-20 -20.6411 0.79183E+00 -0.1014 8 H4SiO4 0.24225E-03 -3.6157 0.24225E-03 -3.6157 0.10000E+01 0.0000 9 Ca++ 0.29895E-04 -4.5244 0.26683E-04 -4.5738 0.89254E+00 -0.0494 10 Mg++ 0.98337E-07 -7.0073 0.87760E-07 -7.0567 0.89244E+00 -0.0494 11 Fe++ 0.58391E-09 -9.2337 0.52112E-09 -9.2831 0.89246E+00 -0.0494 12 K+ 0.65793E-05 -5.1818 0.63099E-05 -5.2000 0.95905E+00 -0.0182 13 Na+ 0.19892E-03 -3.7013 0.19077E-03 -3.7195 0.95901E+00 -0.0182 14 Mn++ 0.66365E-07 -7.1781 0.59229E-07 -7.2275 0.89248E+00 -0.0494 15 HPO4-- 0.16407E-08 -8.7850 0.14646E-08 -8.8343 0.89269E+00 -0.0493 16 HSiO3- 0.17277E-04 -4.7625 0.16569E-04 -4.7807 0.95901E+00 -0.0182 17 Ca(HSiO3)+ 0.10328E-07 -7.9860 0.99052E-08 -8.0041 0.95905E+00 -0.0182 18 Mg(HSiO3)+ 0.42275E-10 -10.3739 0.40544E-10 -10.3921 0.95905E+00 -0.0182 19 NaHSiO3,aq 0.50200E-07 -7.2993 0.50200E-07 -7.2993 0.10000E+01 0.0000 20 AlO+ 0.15116E-11 -11.8206 0.14497E-11 -11.8387 0.95905E+00 -0.0182 21 AlOH+2 0.11607E-15 -15.9353 0.10359E-15 -15.9847 0.89250E+00 -0.0494 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.33194E-05 -5.4789 0.31832E-05 -5.4971 0.95897E+00 -0.0182 24 CH4,aq 0.12737E-17 -17.8949 0.12736E-17 -17.8950 0.99991E+00 0.0000 29 CO,aq 0.55841E-17 -17.2530 0.55841E-17 -17.2530 0.10000E+01 0.0000 30 CO2,aq 0.34760E-06 -6.4589 0.34757E-06 -6.4590 0.99991E+00 0.0000 31 CO3-2 0.87747E-07 -7.0568 0.78327E-07 -7.1061 0.89264E+00 -0.0493 32 CaCO3,aq 0.25597E-07 -7.5918 0.25597E-07 -7.5918 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.84717E-08 -8.0720 0.81248E-08 -8.0902 0.95905E+00 -0.0182 34 CaCl+ 0.58657E-08 -8.2317 0.56255E-08 -8.2498 0.95905E+00 -0.0182 35 CaCl2,aq 0.17330E-12 -12.7612 0.17330E-12 -12.7612 0.10000E+01 0.0000 36 CaOH+ 0.13753E-06 -6.8616 0.13189E-06 -6.8798 0.95905E+00 -0.0182 37 CaSO4,aq 0.18787E-06 -6.7261 0.18787E-06 -6.7261 0.10000E+01 0.0000 38 HCl,aq 0.35501E-12 -12.4498 0.35501E-12 -12.4498 0.10000E+01 0.0000 43 FeCl+ 0.11197E-12 -12.9509 0.10739E-12 -12.9690 0.95905E+00 -0.0182 46 FeO,aq 0.10127E-09 -9.9945 0.10127E-09 -9.9945 0.10000E+01 0.0000 47 FeOH+ 0.12628E-08 -8.8987 0.12111E-08 -8.9168 0.95905E+00 -0.0182 48 HFeO2- 0.79622E-10 -10.0990 0.76358E-10 -10.1171 0.95901E+00 -0.0182 49 FeO+ 0.12304E-12 -12.9100 0.11800E-12 -12.9281 0.95905E+00 -0.0182 50 FeOH+2 0.35096E-18 -18.4547 0.31323E-18 -18.5041 0.89250E+00 -0.0494 51 FeO2- 0.11884E-09 -9.9250 0.11397E-09 -9.9432 0.95901E+00 -0.0182 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.62387E-09 -9.2049 0.62381E-09 -9.2049 0.99991E+00 0.0000 54 KCl,aq 0.14782E-10 -10.8303 0.14782E-10 -10.8303 0.10000E+01 0.0000 55 KHSO4,aq 0.54430E-17 -17.2642 0.54430E-17 -17.2642 0.10000E+01 0.0000 56 KOH,aq 0.19283E-09 -9.7148 0.19283E-09 -9.7148 0.10000E+01 0.0000 57 KSO4- 0.22906E-08 -8.6400 0.21968E-08 -8.6582 0.95901E+00 -0.0182 58 MgCO3,aq 0.21037E-10 -10.6770 0.21037E-10 -10.6770 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28413E-10 -10.5465 0.27250E-10 -10.5646 0.95905E+00 -0.0182 60 MgCl+ 0.17514E-10 -10.7566 0.16797E-10 -10.7748 0.95905E+00 -0.0182 61 MgOH+ 0.25059E-08 -8.6010 0.24033E-08 -8.6192 0.95905E+00 -0.0182 63 MnO,aq 0.30726E-09 -9.5125 0.30726E-09 -9.5125 0.10000E+01 0.0000 64 MnOH+ 0.13333E-07 -7.8751 0.12787E-07 -7.8932 0.95905E+00 -0.0182 65 MnO2-2 0.58499E-16 -16.2328 0.52219E-16 -16.2822 0.89264E+00 -0.0493 66 HMnO2- 0.16829E-12 -12.7739 0.16139E-12 -12.7921 0.95901E+00 -0.0182 69 MnCl+ 0.49453E-10 -10.3058 0.47428E-10 -10.3240 0.95905E+00 -0.0182 70 MnSO4,aq 0.37931E-09 -9.4210 0.37931E-09 -9.4210 0.10000E+01 0.0000 71 NaCl,aq 0.82414E-08 -8.0840 0.82414E-08 -8.0840 0.10000E+01 0.0000 72 NaOH,aq 0.58762E-08 -8.2309 0.58762E-08 -8.2309 0.10000E+01 0.0000 74 OH- 0.43848E-04 -4.3580 0.42049E-04 -4.3762 0.95897E+00 -0.0182 82 H3PO4,aq 0.19187E-14 -14.7170 0.19187E-14 -14.7170 0.10000E+01 0.0000 83 H2PO4- 0.38194E-09 -9.4180 0.36629E-09 -9.4362 0.95903E+00 -0.0182 84 PO4-3 0.11310E-12 -12.9465 0.89664E-13 -13.0474 0.79276E+00 -0.1009 87 H2P2O7-2 0.11764E-19 -19.9295 0.10501E-19 -19.9788 0.89264E+00 -0.0493 88 HP2O7-3 0.19062E-18 -18.7198 0.15094E-18 -18.8212 0.79184E+00 -0.1014 90 H2S,aq 0.10403E-12 -12.9828 0.10402E-12 -12.9829 0.99991E+00 0.0000 96 SO2,aq 0.12018E-19 -19.9202 0.12018E-19 -19.9202 0.10000E+01 0.0000 97 SO3-2 0.21525E-14 -14.6671 0.19220E-14 -14.7162 0.89295E+00 -0.0492 98 HSO3- 0.16731E-14 -14.7765 0.16045E-14 -14.7946 0.95901E+00 -0.0182 99 HSO4- 0.31186E-09 -9.5060 0.29910E-09 -9.5242 0.95908E+00 -0.0181 101 S2O3-2 0.31036E-19 -19.5081 0.27704E-19 -19.5575 0.89264E+00 -0.0493 Charge balance for all species = 0.2016E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1487262E-07 -.7443705E-04 -.7502527E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999608E+06 0.0000 3 Cl- 0.1379615E-03 0.1379757E-03 0.4891468E+01 3.9673 4 SO4-- 0.2531389E-04 0.2550463E-04 0.2449923E+01 11.0455 5 HCO3- 0.1260068E-04 0.1307014E-04 0.7974735E+00 2.9280 6 HS- 0.2530757E-11 0.1182976E-09 0.3912191E-05 -3.7692 7 Al+++ 0.2885834E-20 0.3339722E-05 0.9010733E-01 2.8961 8 H4SiO4 0.2422453E-03 0.2595825E-03 0.2494894E+02 -3.6157 9 Ca++ 0.2989541E-04 0.3027106E-04 0.1213158E+01 11.1177 10 Mg++ 0.9833716E-07 0.1009523E-06 0.2454260E-02 8.6348 11 Fe++ 0.5839149E-09 0.2350170E-08 0.1312450E-03 6.4084 12 K+ 0.6579314E-05 0.6581812E-05 0.2573524E+00 2.6457 13 Na+ 0.1989214E-03 0.1989857E-03 0.4574470E+01 4.1262 14 Mn++ 0.6636491E-07 0.8043440E-07 0.4418739E-02 8.4640 15 HPO4-- 0.1640670E-08 0.2022724E-08 0.1941318E-03 6.8572 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5002740E-03 -.7443625E-04 -.4258377E-03 0.0000000E+00 2 H2O 0.5550786E+02 0.5550768E+02 0.1793907E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2636359E-04 0.2550435E-04 0.8592340E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8591157E-06 0.1182963E-09 -.8592340E-06 0.0000000E+00 7 Al+++ 0.1010830E-03 0.3339686E-05 0.9774330E-04 0.0000000E+00 8 H4SiO4 0.3227963E-03 0.2595797E-03 0.6321655E-04 0.0000000E+00 9 Ca++ 0.5012548E-04 0.3027074E-04 0.1985475E-04 0.0000000E+00 10 Mg++ 0.2460317E-04 0.1009512E-06 0.2450222E-04 0.0000000E+00 11 Fe++ 0.2210327E-04 0.2350145E-08 0.2210092E-04 0.0000000E+00 12 K+ 0.6581741E-05 0.6581741E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.1989836E-03 0.1989836E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.5374965E-06 0.8043353E-07 0.4570629E-06 0.0000000E+00 15 HPO4-- 0.1834449E-06 0.2022703E-08 0.1814222E-06 0.0000000E+00 Chg. balance for solid moles: 0.9709E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0310000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6047E-07 -7.218 0.3038E-04 -4.517 0.2133 0.9653E-05 clinochlore 0.4900E-05 -5.310 0.2724E-02 -2.565 19.13 0.1036E-02 daphnite 0.3045E-05 -5.516 0.2173E-02 -2.663 15.26 0.6585E-03 chlorite-Mn 0.9141E-07 -7.039 0.6481E-04 -4.188 0.4552 0.2065E-04 diaspore 0.4256E-04 -4.371 0.2553E-02 -2.593 17.93 0.7602E-03 hematite 0.3437E-05 -5.464 0.5489E-03 -3.261 3.855 0.1040E-03 lawsonite 0.1955E-04 -4.709 0.6144E-02 -2.212 43.15 0.1981E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3789E+00 0.3789E+00 1.0000 -0.421 chlorite-Mn 0.1137E-01 0.1137E-01 1.0000 -1.944 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.014238 g Volume = 0.004570 cm3 Porosity: 99.5486% V(tot) - V(min): 0.10078E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0310000 g log = -1.5086 Original solution: 1000.0103000 g Original solution / Rock added: 32258.40 (Water/Rock Ratio), log = 4.5086 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3754E-04 1.0073 0.3979E-04 0.3950E-04 CH4,gas 0.1890E-14 1.0129 0.2014E-14 0.1988E-14 H2,gas 0.8129E-06 1.0006 0.8556E-06 0.8551E-06 H2S,gas 0.2896E-11 0.9959 0.3034E-11 0.3046E-11 S2,gas 0.4477E-30 1.0000 0.4709E-30 0.4709E-30 CO,gas 0.8382E-14 1.0000 0.8817E-14 0.8817E-14 SO3,gas 0.1634E-35 1.0000 0.1719E-35 0.1719E-35 SO2,gas 0.5289E-19 1.0000 0.5564E-19 0.5564E-19 HCl,gas 0.5959E-15 1.0000 0.6268E-15 0.6268E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.76 -6.40 -2.133 0.10928E+05 -4.400 3 CH4,gas 4.81 -11.89 -16.70 -4.174 0.28508E+05 -14.696 4 H2,gas 8.29 0.22 -8.07 -4.610 0.13775E+05 -6.068 5 H2S,gas -5.94 -19.46 -13.52 -6.759 0.23082E+05 -11.518 6 S2,gas -7.03 -39.36 -32.33 -4.973 0.55198E+05 -30.327 7 CO,gas 3.51 -12.54 -16.05 -4.940 0.27413E+05 -14.055 8 SO3,gas 17.43 -20.34 -37.76 -9.441 0.64482E+05 -35.765 9 SO2,gas 1.14 -20.12 -21.25 -5.668 0.36292E+05 -19.255 10 HCl,gas 5.48 -11.72 -17.20 -8.601 0.29373E+05 -15.203 11 acmite 7.74 3.19 -4.54 -0.472 0.77585E+04 15 albite-high 0.75 -3.82 -4.57 -0.352 0.78109E+04 16 albite -0.33 -3.82 -3.50 -0.269 0.59703E+04 19 spessartine 24.55 20.34 -4.21 -0.211 0.71935E+04 20 analcite 3.37 -0.21 -3.58 -0.398 0.61124E+04 21 andalusite 5.06 2.18 -2.89 -0.289 0.49277E+04 22 andradite 39.09 35.10 -3.98 -0.207 0.68031E+04 23 grossular 32.83 28.30 -4.53 -0.227 0.77352E+04 24 anhydrite -5.28 -9.22 -3.94 -1.970 0.67274E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.65 -2.63 -0.877 0.44941E+04 36 brucite 12.58 8.63 -3.94 -0.788 0.67306E+04 37 calcite 0.83 -1.65 -2.48 -0.826 0.42328E+04 40 carpholite-Mg 8.65 7.20 -1.45 -0.097 0.24843E+04 41 carpholite-Fe 6.78 4.97 -1.81 -0.121 0.30970E+04 50 chloritoid-Mg 13.26 10.81 -2.45 -0.163 0.41834E+04 51 chloritoid-Fe 9.24 8.58 -0.65 -0.044 0.11164E+04 52 chloritoid-Mn 11.46 10.64 -0.82 -0.055 0.14049E+04 54 coesite -2.37 -3.62 -1.25 -0.415 0.21282E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.62 -1.07 -0.356 0.18211E+04 67 diopside 16.22 12.52 -3.69 -0.369 0.63083E+04 68 hedenbergite 14.24 10.29 -3.95 -0.395 0.67442E+04 75 epidote 24.78 23.48 -1.30 -0.063 0.22130E+04 76 clinozoisite 22.92 20.08 -2.84 -0.129 0.48573E+04 77 epidote-Fe 29.94 26.88 -3.05 -0.159 0.52162E+04 78 fayalite 14.08 9.20 -4.88 -0.697 0.83289E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 11.99 -4.20 -0.350 0.71723E+04 91 heulandite -5.71 -8.40 -2.69 -0.122 0.45986E+04 95 jadeite 4.25 -0.21 -4.46 -0.446 0.76155E+04 98 kaolinite -1.27 -1.44 -0.17 -0.015 0.28373E+03 99 kyanite 4.93 2.18 -2.76 -0.276 0.47044E+04 101 laumontite 2.97 2.45 -0.53 -0.035 0.90096E+03 105 lizardite 23.29 18.67 -4.61 -0.385 0.78794E+04 106 magnesite 0.71 -4.13 -4.84 -1.613 0.82608E+04 107 magnetite 20.13 19.01 -1.13 -0.092 0.19239E+04 113 margarite 17.45 15.47 -1.98 -0.079 0.33829E+04 116 microcline -2.43 -5.31 -2.87 -0.221 0.49066E+04 120 muscovite 2.68 0.49 -2.19 -0.129 0.37435E+04 121 paragonite 4.34 1.97 -2.37 -0.139 0.40456E+04 122 nepheline 8.38 3.41 -4.97 -0.710 0.84888E+04 136 prehnite 19.47 17.18 -2.29 -0.134 0.39033E+04 137 prehnite-Fe 22.59 20.58 -2.00 -0.121 0.34213E+04 138 pumpellyite-Fe 46.47 43.67 -2.81 -0.062 0.47902E+04 139 pumpellyite-Mg 49.19 45.89 -3.30 -0.073 0.56391E+04 145 pyroxmangite 7.42 4.85 -2.57 -0.514 0.43844E+04 146 pyrophyllite -6.10 -8.67 -2.57 -0.161 0.43929E+04 147 quartz -2.98 -3.62 -0.63 -0.211 0.10821E+04 152 rhodochrosite -0.96 -4.30 -3.34 -1.114 0.57046E+04 153 rhodonite 7.46 4.85 -2.61 -0.523 0.44637E+04 154 sanidine -1.22 -5.31 -4.08 -0.314 0.69743E+04 156 siderite -2.59 -6.36 -3.77 -1.256 0.64328E+04 157 sillimanite 5.32 2.18 -3.14 -0.314 0.53698E+04 164 stilbite -7.41 -8.40 -0.99 -0.047 0.16981E+04 165 stilpnomelane-Fe 13.18 10.23 -2.95 -0.088 0.50341E+04 168 sudoite-Fe 18.44 13.55 -4.88 -0.158 0.83378E+04 169 sudoite 21.22 18.01 -3.21 -0.104 0.54802E+04 175 tephroite 18.11 13.31 -4.80 -0.686 0.81970E+04 178 topaz-H 4.67 2.18 -2.49 -0.226 0.42535E+04 179 tridymite -2.61 -3.62 -1.00 -0.334 0.17094E+04 188 wairakite 4.06 2.45 -1.61 -0.095 0.27518E+04 189 walstromite 11.53 7.50 -4.03 -0.805 0.68742E+04 190 wollastonite 10.48 7.50 -2.98 -0.596 0.50881E+04 191 pseudo-wollastonite 11.02 7.50 -3.52 -0.704 0.60067E+04 192 zoisite 22.96 20.08 -2.89 -0.131 0.49299E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.69 -3.13 -0.193 0.53406E+04 195 beidellite-H -2.24 -6.52 -4.28 -0.273 0.73093E+04 196 beidellite-K -1.44 -5.65 -4.21 -0.258 0.71949E+04 197 beidellite-Mg -1.71 -5.10 -3.39 -0.210 0.57888E+04 198 beidellite-Na -1.26 -5.16 -3.90 -0.239 0.66646E+04 200 chalcedony -2.79 -3.62 -0.82 -0.274 0.14024E+04 202 montmorillonite-Ca -2.21 -4.94 -2.73 -0.169 0.46590E+04 203 montmorillonite-K -2.16 -5.90 -3.74 -0.229 0.63910E+04 204 montmorillonite-Mg -2.40 -5.35 -2.95 -0.183 0.50382E+04 205 montmorillonite-Na -1.96 -5.42 -3.45 -0.212 0.58989E+04 206 nontronite-Ca 3.28 2.12 -1.16 -0.075 0.19836E+04 207 nontronite-H 2.60 0.28 -2.31 -0.155 0.39480E+04 208 nontronite-K 3.40 1.16 -2.25 -0.144 0.38370E+04 209 nontronite-Mg 3.14 1.71 -1.43 -0.093 0.24433E+04 210 nontronite-Na 3.58 1.65 -1.94 -0.124 0.33084E+04 215 gypsum -4.92 -9.22 -4.30 -1.074 0.73341E+04 225 tobermorite 9.84 5.65 -4.19 -1.144 0.71607E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.41 -3.42 -0.854 0.58324E+04 241 silica-amorphous -2.08 -3.62 -1.54 -0.512 0.26226E+04 243 an20ab80 2.08 -1.12 -3.20 -0.246 0.54698E+04 244 an25ab75 2.71 -0.45 -3.16 -0.243 0.53926E+04 245 an30ab70 3.34 0.23 -3.12 -0.240 0.53238E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0310000 g New total amount of reactant added: 0.0320000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0320000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3042188E-03 Osmotic coef. = 0.9896 True ionic strength = .3203127E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15001E-07 -7.8239 0.14388E-07 -7.8420 0.95918E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13231E-03 -3.8784 0.95904E+00 -0.0182 4 SO4-- 0.25319E-04 -4.5966 0.22605E-04 -4.6458 0.89281E+00 -0.0492 5 HCO3- 0.12600E-04 -4.8996 0.12084E-04 -4.9178 0.95908E+00 -0.0181 6 HS- 0.22920E-11 -11.6398 0.21981E-11 -11.6579 0.95905E+00 -0.0182 7 Al+++ 0.29605E-20 -20.5286 0.23449E-20 -20.6299 0.79208E+00 -0.1012 8 H4SiO4 0.24771E-03 -3.6061 0.24771E-03 -3.6061 0.10000E+01 0.0000 9 Ca++ 0.29083E-04 -4.5364 0.25962E-04 -4.5857 0.89266E+00 -0.0493 10 Mg++ 0.98701E-07 -7.0057 0.88097E-07 -7.0550 0.89257E+00 -0.0494 11 Fe++ 0.58601E-09 -9.2321 0.52307E-09 -9.2814 0.89259E+00 -0.0493 12 K+ 0.67916E-05 -5.1680 0.65137E-05 -5.1862 0.95908E+00 -0.0181 13 Na+ 0.20018E-03 -3.6986 0.19198E-03 -3.7168 0.95904E+00 -0.0182 14 Mn++ 0.66895E-07 -7.1746 0.59711E-07 -7.2239 0.89261E+00 -0.0493 15 HPO4-- 0.17369E-08 -8.7602 0.15507E-08 -8.8095 0.89282E+00 -0.0492 16 HSiO3- 0.17514E-04 -4.7566 0.16797E-04 -4.7748 0.95904E+00 -0.0182 17 Ca(HSiO3)+ 0.10187E-07 -7.9919 0.97705E-08 -8.0101 0.95909E+00 -0.0181 18 Mg(HSiO3)+ 0.43022E-10 -10.3663 0.41262E-10 -10.3845 0.95909E+00 -0.0181 19 NaHSiO3,aq 0.51215E-07 -7.2906 0.51215E-07 -7.2906 0.10000E+01 0.0000 20 AlO+ 0.15246E-11 -11.8168 0.14622E-11 -11.8350 0.95909E+00 -0.0181 21 AlOH+2 0.11807E-15 -15.9279 0.10539E-15 -15.9772 0.89263E+00 -0.0493 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.32908E-05 -5.4827 0.31559E-05 -5.5009 0.95900E+00 -0.0182 24 CH4,aq 0.11531E-17 -17.9381 0.11530E-17 -17.9382 0.99991E+00 0.0000 29 CO,aq 0.54821E-17 -17.2611 0.54821E-17 -17.2611 0.10000E+01 0.0000 30 CO2,aq 0.35059E-06 -6.4552 0.35056E-06 -6.4552 0.99991E+00 0.0000 31 CO3-2 0.86978E-07 -7.0606 0.77651E-07 -7.1099 0.89277E+00 -0.0493 32 CaCO3,aq 0.24691E-07 -7.6075 0.24691E-07 -7.6075 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.82420E-08 -8.0840 0.79048E-08 -8.1021 0.95909E+00 -0.0181 34 CaCl+ 0.57072E-08 -8.2436 0.54737E-08 -8.2617 0.95909E+00 -0.0181 35 CaCl2,aq 0.16863E-12 -12.7731 0.16863E-12 -12.7731 0.10000E+01 0.0000 36 CaOH+ 0.13266E-06 -6.8773 0.12723E-06 -6.8954 0.95909E+00 -0.0181 37 CaSO4,aq 0.18285E-06 -6.7379 0.18285E-06 -6.7379 0.10000E+01 0.0000 38 HCl,aq 0.35809E-12 -12.4460 0.35809E-12 -12.4460 0.10000E+01 0.0000 43 FeCl+ 0.11239E-12 -12.9493 0.10779E-12 -12.9674 0.95909E+00 -0.0181 46 FeO,aq 0.99911E-10 -10.0004 0.99911E-10 -10.0004 0.10000E+01 0.0000 47 FeOH+ 0.12566E-08 -8.9008 0.12052E-08 -8.9189 0.95909E+00 -0.0181 48 HFeO2- 0.77877E-10 -10.1086 0.74688E-10 -10.1267 0.95904E+00 -0.0182 49 FeO+ 0.12410E-12 -12.9062 0.11902E-12 -12.9244 0.95909E+00 -0.0181 50 FeOH+2 0.35701E-18 -18.4473 0.31867E-18 -18.4967 0.89263E+00 -0.0493 51 FeO2- 0.11782E-09 -9.9288 0.11299E-09 -9.9469 0.95904E+00 -0.0182 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.60724E-09 -9.2166 0.60719E-09 -9.2167 0.99991E+00 0.0000 54 KCl,aq 0.15260E-10 -10.8164 0.15260E-10 -10.8164 0.10000E+01 0.0000 55 KHSO4,aq 0.56693E-17 -17.2465 0.56693E-17 -17.2465 0.10000E+01 0.0000 56 KOH,aq 0.19735E-09 -9.7048 0.19735E-09 -9.7048 0.10000E+01 0.0000 57 KSO4- 0.23653E-08 -8.6261 0.22685E-08 -8.6443 0.95904E+00 -0.0182 58 MgCO3,aq 0.20936E-10 -10.6791 0.20936E-10 -10.6791 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28520E-10 -10.5449 0.27353E-10 -10.5630 0.95909E+00 -0.0181 60 MgCl+ 0.17581E-10 -10.7549 0.16862E-10 -10.7731 0.95909E+00 -0.0181 61 MgOH+ 0.24939E-08 -8.6031 0.23918E-08 -8.6213 0.95909E+00 -0.0181 63 MnO,aq 0.30447E-09 -9.5165 0.30447E-09 -9.5165 0.10000E+01 0.0000 64 MnOH+ 0.13326E-07 -7.8753 0.12781E-07 -7.8934 0.95909E+00 -0.0181 65 MnO2-2 0.56969E-16 -16.2444 0.50861E-16 -16.2936 0.89277E+00 -0.0493 66 HMnO2- 0.16533E-12 -12.7817 0.15855E-12 -12.7998 0.95904E+00 -0.0182 69 MnCl+ 0.49855E-10 -10.3023 0.47816E-10 -10.3204 0.95909E+00 -0.0181 70 MnSO4,aq 0.38253E-09 -9.4173 0.38253E-09 -9.4173 0.10000E+01 0.0000 71 NaCl,aq 0.82940E-08 -8.0812 0.82940E-08 -8.0812 0.10000E+01 0.0000 72 NaOH,aq 0.58628E-08 -8.2319 0.58628E-08 -8.2319 0.10000E+01 0.0000 74 OH- 0.43471E-04 -4.3618 0.41689E-04 -4.3800 0.95900E+00 -0.0182 82 H3PO4,aq 0.20669E-14 -14.6847 0.20669E-14 -14.6847 0.10000E+01 0.0000 83 H2PO4- 0.40789E-09 -9.3895 0.39119E-09 -9.4076 0.95907E+00 -0.0182 84 PO4-3 0.11869E-12 -12.9256 0.94123E-13 -13.0263 0.79301E+00 -0.1007 87 H2P2O7-2 0.13415E-19 -19.8724 0.11977E-19 -19.9217 0.89277E+00 -0.0493 88 HP2O7-3 0.21549E-18 -18.6666 0.17069E-18 -18.7678 0.79209E+00 -0.1012 90 H2S,aq 0.95036E-13 -13.0221 0.95027E-13 -13.0222 0.99991E+00 0.0000 96 SO2,aq 0.11905E-19 -19.9243 0.11905E-19 -19.9243 0.10000E+01 0.0000 97 SO3-2 0.20955E-14 -14.6787 0.18715E-14 -14.7278 0.89308E+00 -0.0491 98 HSO3- 0.16431E-14 -14.7843 0.15758E-14 -14.8025 0.95904E+00 -0.0182 99 HSO4- 0.31465E-09 -9.5022 0.30179E-09 -9.5203 0.95911E+00 -0.0181 101 S2O3-2 0.28357E-19 -19.5473 0.25317E-19 -19.5966 0.89277E+00 -0.0493 Charge balance for all species = 0.2017E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1500079E-07 -.7417379E-04 -.7475988E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999603E+06 0.0000 3 Cl- 0.1379616E-03 0.1379757E-03 0.4891467E+01 3.9636 4 SO4-- 0.2531883E-04 0.2550464E-04 0.2449923E+01 11.0382 5 HCO3- 0.1259960E-04 0.1307015E-04 0.7974733E+00 2.9242 6 HS- 0.2291987E-11 0.1140223E-09 0.3770801E-05 -3.8160 7 Al+++ 0.2960459E-20 0.3311131E-05 0.8933587E-01 2.8961 8 H4SiO4 0.2477113E-03 0.2652871E-03 0.2549720E+02 -3.6061 9 Ca++ 0.2908345E-04 0.2944779E-04 0.1180163E+01 11.0983 10 Mg++ 0.9870106E-07 0.1013050E-06 0.2462833E-02 8.6289 11 Fe++ 0.5860140E-09 0.2341945E-08 0.1307856E-03 6.4025 12 K+ 0.6791553E-05 0.6794131E-05 0.2656540E+00 2.6558 13 Na+ 0.2001756E-03 0.2002410E-03 0.4603326E+01 4.1252 14 Mn++ 0.6689520E-07 0.8095816E-07 0.4447510E-02 8.4600 15 HPO4-- 0.1736914E-08 0.2144922E-08 0.2058596E-03 6.8745 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5168325E-03 -.7417296E-04 -.4426595E-03 0.0000000E+00 2 H2O 0.5550785E+02 0.5550767E+02 0.1827861E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2639130E-04 0.2550436E-04 0.8869431E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8868291E-06 0.1140210E-09 -.8869431E-06 0.0000000E+00 7 Al+++ 0.1043437E-03 0.3311094E-05 0.1010326E-03 0.0000000E+00 8 H4SiO4 0.3332091E-03 0.2652841E-03 0.6792495E-04 0.0000000E+00 9 Ca++ 0.5127562E-04 0.2944746E-04 0.2182817E-04 0.0000000E+00 10 Mg++ 0.2539683E-04 0.1013039E-06 0.2529552E-04 0.0000000E+00 11 Fe++ 0.2281627E-04 0.2341919E-08 0.2281393E-04 0.0000000E+00 12 K+ 0.6794055E-05 0.6794055E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2002388E-03 0.2002388E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.5548351E-06 0.8095726E-07 0.4738778E-06 0.0000000E+00 15 HPO4-- 0.1893625E-06 0.2144898E-08 0.1872176E-06 0.0000000E+00 Chg. balance for solid moles: 0.2763E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0320000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6241E-07 -7.205 0.3135E-04 -4.504 0.2095 0.9961E-05 clinochlore 0.5059E-05 -5.296 0.2812E-02 -2.551 18.79 0.1070E-02 daphnite 0.3144E-05 -5.503 0.2243E-02 -2.649 14.99 0.6797E-03 chlorite-Mn 0.9478E-07 -7.023 0.6719E-04 -4.173 0.4490 0.2141E-04 diaspore 0.4141E-04 -4.383 0.2484E-02 -2.605 16.60 0.7395E-03 hematite 0.3548E-05 -5.450 0.5666E-03 -3.247 3.786 0.1074E-03 lawsonite 0.2152E-04 -4.667 0.6761E-02 -2.170 45.18 0.2180E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3789E+00 0.3789E+00 1.0000 -0.422 chlorite-Mn 0.1142E-01 0.1142E-01 1.0000 -1.942 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.014965 g Volume = 0.004808 cm3 Porosity: 99.5253% V(tot) - V(min): 0.10080E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0320000 g log = -1.4949 Original solution: 1000.0103000 g Original solution / Rock added: 31250.32 (Water/Rock Ratio), log = 4.4949 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3787E-04 1.0073 0.4013E-04 0.3984E-04 CH4,gas 0.1711E-14 1.0129 0.1823E-14 0.1800E-14 H2,gas 0.7912E-06 1.0006 0.8328E-06 0.8323E-06 H2S,gas 0.2645E-11 0.9959 0.2772E-11 0.2783E-11 S2,gas 0.3943E-30 1.0000 0.4148E-30 0.4148E-30 CO,gas 0.8229E-14 1.0000 0.8656E-14 0.8656E-14 SO3,gas 0.1663E-35 1.0000 0.1750E-35 0.1750E-35 SO2,gas 0.5240E-19 1.0000 0.5512E-19 0.5512E-19 HCl,gas 0.6010E-15 1.0000 0.6323E-15 0.6323E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.76 -6.40 -2.132 0.10922E+05 -4.397 3 CH4,gas 4.81 -11.93 -16.74 -4.185 0.28582E+05 -14.739 4 H2,gas 8.29 0.21 -8.08 -4.617 0.13795E+05 -6.079 5 H2S,gas -5.94 -19.50 -13.56 -6.779 0.23149E+05 -11.557 6 S2,gas -7.03 -39.41 -32.38 -4.982 0.55292E+05 -30.382 7 CO,gas 3.51 -12.55 -16.06 -4.942 0.27427E+05 -14.063 8 SO3,gas 17.43 -20.33 -37.76 -9.439 0.64469E+05 -35.757 9 SO2,gas 1.14 -20.12 -21.26 -5.669 0.36299E+05 -19.259 10 HCl,gas 5.48 -11.72 -17.20 -8.600 0.29367E+05 -15.199 11 acmite 7.74 3.21 -4.53 -0.470 0.77271E+04 15 albite-high 0.75 -3.80 -4.55 -0.350 0.77630E+04 16 albite -0.33 -3.80 -3.47 -0.267 0.59223E+04 19 spessartine 24.55 20.35 -4.20 -0.210 0.71642E+04 20 analcite 3.37 -0.19 -3.56 -0.396 0.60810E+04 21 andalusite 5.06 2.19 -2.88 -0.288 0.49111E+04 22 andradite 39.09 35.07 -4.01 -0.208 0.68527E+04 23 grossular 32.83 28.27 -4.56 -0.228 0.77848E+04 24 anhydrite -5.28 -9.23 -3.95 -1.976 0.67474E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.66 -2.65 -0.883 0.45209E+04 36 brucite 12.58 8.63 -3.95 -0.790 0.67405E+04 37 calcite 0.83 -1.66 -2.49 -0.832 0.42595E+04 40 carpholite-Mg 8.65 7.21 -1.44 -0.096 0.24611E+04 41 carpholite-Fe 6.78 4.98 -1.80 -0.120 0.30739E+04 50 chloritoid-Mg 13.26 10.82 -2.45 -0.163 0.41768E+04 51 chloritoid-Fe 9.24 8.59 -0.65 -0.043 0.11099E+04 52 chloritoid-Mn 11.46 10.65 -0.82 -0.054 0.13951E+04 54 coesite -2.37 -3.61 -1.24 -0.412 0.21116E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.61 -1.06 -0.352 0.18045E+04 67 diopside 16.22 12.52 -3.70 -0.370 0.63182E+04 68 hedenbergite 14.24 10.29 -3.96 -0.396 0.67542E+04 75 epidote 24.78 23.47 -1.31 -0.063 0.22296E+04 76 clinozoisite 22.92 20.07 -2.85 -0.130 0.48739E+04 77 epidote-Fe 29.94 26.87 -3.06 -0.159 0.52328E+04 78 fayalite 14.08 9.20 -4.88 -0.697 0.83324E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.00 -4.20 -0.350 0.71692E+04 91 heulandite -5.71 -8.35 -2.64 -0.120 0.45159E+04 95 jadeite 4.25 -0.19 -4.44 -0.444 0.75841E+04 98 kaolinite -1.27 -1.42 -0.15 -0.013 0.25064E+03 99 kyanite 4.93 2.19 -2.75 -0.275 0.46879E+04 101 laumontite 2.97 2.47 -0.51 -0.034 0.86787E+03 105 lizardite 23.29 18.67 -4.61 -0.384 0.78761E+04 106 magnesite 0.71 -4.13 -4.84 -1.613 0.82644E+04 107 magnetite 20.13 19.00 -1.13 -0.092 0.19339E+04 113 margarite 17.45 15.47 -1.98 -0.079 0.33829E+04 116 microcline -2.43 -5.27 -2.83 -0.218 0.48398E+04 120 muscovite 2.68 0.53 -2.15 -0.127 0.36767E+04 121 paragonite 4.34 2.00 -2.34 -0.138 0.39977E+04 122 nepheline 8.38 3.42 -4.96 -0.709 0.84739E+04 136 prehnite 19.47 17.17 -2.30 -0.135 0.39199E+04 137 prehnite-Fe 22.59 20.57 -2.01 -0.121 0.34379E+04 138 pumpellyite-Fe 46.47 43.64 -2.83 -0.063 0.48333E+04 139 pumpellyite-Mg 49.19 45.87 -3.33 -0.074 0.56821E+04 145 pyroxmangite 7.42 4.85 -2.56 -0.512 0.43746E+04 146 pyrophyllite -6.10 -8.63 -2.53 -0.158 0.43268E+04 147 quartz -2.98 -3.61 -0.62 -0.208 0.10656E+04 152 rhodochrosite -0.96 -4.30 -3.34 -1.114 0.57050E+04 153 rhodonite 7.46 4.85 -2.61 -0.522 0.44539E+04 154 sanidine -1.22 -5.27 -4.05 -0.311 0.69075E+04 156 siderite -2.59 -6.36 -3.77 -1.257 0.64364E+04 157 sillimanite 5.32 2.19 -3.14 -0.314 0.53533E+04 164 stilbite -7.41 -8.35 -0.95 -0.045 0.16153E+04 165 stilpnomelane-Fe 13.18 10.28 -2.90 -0.086 0.49432E+04 168 sudoite-Fe 18.44 13.57 -4.87 -0.157 0.83082E+04 169 sudoite 21.22 18.02 -3.19 -0.103 0.54505E+04 175 tephroite 18.11 13.31 -4.80 -0.686 0.81940E+04 178 topaz-H 4.67 2.19 -2.48 -0.226 0.42370E+04 179 tridymite -2.61 -3.61 -0.99 -0.330 0.16929E+04 188 wairakite 4.06 2.47 -1.59 -0.094 0.27187E+04 189 walstromite 11.53 7.49 -4.04 -0.807 0.68907E+04 190 wollastonite 10.48 7.49 -2.99 -0.598 0.51046E+04 191 pseudo-wollastonite 11.02 7.49 -3.53 -0.706 0.60232E+04 192 zoisite 22.96 20.07 -2.90 -0.132 0.49464E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.66 -3.10 -0.191 0.52854E+04 195 beidellite-H -2.24 -6.49 -4.25 -0.271 0.72486E+04 196 beidellite-K -1.44 -5.61 -4.17 -0.256 0.71285E+04 197 beidellite-Mg -1.71 -5.06 -3.36 -0.208 0.57297E+04 198 beidellite-Na -1.26 -5.13 -3.87 -0.237 0.66045E+04 200 chalcedony -2.79 -3.61 -0.81 -0.271 0.13859E+04 202 montmorillonite-Ca -2.21 -4.91 -2.69 -0.167 0.46016E+04 203 montmorillonite-K -2.16 -5.86 -3.70 -0.227 0.63224E+04 204 montmorillonite-Mg -2.40 -5.32 -2.91 -0.180 0.49769E+04 205 montmorillonite-Na -1.96 -5.38 -3.42 -0.209 0.58366E+04 206 nontronite-Ca 3.28 2.15 -1.13 -0.073 0.19283E+04 207 nontronite-H 2.60 0.32 -2.28 -0.153 0.38873E+04 208 nontronite-K 3.40 1.20 -2.21 -0.142 0.37706E+04 209 nontronite-Mg 3.14 1.74 -1.40 -0.091 0.23843E+04 210 nontronite-Na 3.58 1.68 -1.90 -0.122 0.32483E+04 215 gypsum -4.92 -9.23 -4.31 -1.077 0.73542E+04 225 tobermorite 9.84 5.64 -4.20 -1.146 0.71717E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.40 -3.42 -0.855 0.58424E+04 241 silica-amorphous -2.08 -3.61 -1.53 -0.509 0.26061E+04 243 an20ab80 2.08 -1.10 -3.18 -0.245 0.54315E+04 244 an25ab75 2.71 -0.43 -3.14 -0.241 0.53567E+04 245 an30ab70 3.34 0.25 -3.10 -0.238 0.52902E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0320000 g New total amount of reactant added: 0.0330000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0330000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3032200E-03 Osmotic coef. = 0.9896 True ionic strength = .3193924E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15123E-07 -7.8204 0.14506E-07 -7.8385 0.95921E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13232E-03 -3.8784 0.95908E+00 -0.0181 4 SO4-- 0.25324E-04 -4.5965 0.22612E-04 -4.6457 0.89293E+00 -0.0492 5 HCO3- 0.12599E-04 -4.8997 0.12083E-04 -4.9178 0.95911E+00 -0.0181 6 HS- 0.20786E-11 -11.6822 0.19935E-11 -11.7004 0.95908E+00 -0.0181 7 Al+++ 0.30326E-20 -20.5182 0.24028E-20 -20.6193 0.79232E+00 -0.1011 8 H4SiO4 0.25320E-03 -3.5965 0.25320E-03 -3.5965 0.10000E+01 0.0000 9 Ca++ 0.28287E-04 -4.5484 0.25254E-04 -4.5977 0.89278E+00 -0.0493 10 Mg++ 0.98992E-07 -7.0044 0.88369E-07 -7.0537 0.89269E+00 -0.0493 11 Fe++ 0.58768E-09 -9.2309 0.52463E-09 -9.2801 0.89271E+00 -0.0493 12 K+ 0.70038E-05 -5.1547 0.67174E-05 -5.1728 0.95912E+00 -0.0181 13 Na+ 0.20143E-03 -3.6959 0.19319E-03 -3.7140 0.95907E+00 -0.0181 14 Mn++ 0.67369E-07 -7.1715 0.60142E-07 -7.2208 0.89273E+00 -0.0493 15 HPO4-- 0.18383E-08 -8.7356 0.16415E-08 -8.7848 0.89294E+00 -0.0492 16 HSiO3- 0.17757E-04 -4.7506 0.17031E-04 -4.7688 0.95908E+00 -0.0181 17 Ca(HSiO3)+ 0.10047E-07 -7.9980 0.96365E-08 -8.0161 0.95912E+00 -0.0181 18 Mg(HSiO3)+ 0.43753E-10 -10.3590 0.41964E-10 -10.3771 0.95912E+00 -0.0181 19 NaHSiO3,aq 0.52254E-07 -7.2819 0.52254E-07 -7.2819 0.10000E+01 0.0000 20 AlO+ 0.15370E-11 -11.8133 0.14742E-11 -11.8315 0.95912E+00 -0.0181 21 AlOH+2 0.11999E-15 -15.9209 0.10712E-15 -15.9701 0.89275E+00 -0.0493 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.32641E-05 -5.4862 0.31304E-05 -5.5044 0.95904E+00 -0.0182 24 CH4,aq 0.10454E-17 -17.9807 0.10453E-17 -17.9808 0.99991E+00 0.0000 29 CO,aq 0.53818E-17 -17.2691 0.53818E-17 -17.2691 0.10000E+01 0.0000 30 CO2,aq 0.35343E-06 -6.4517 0.35340E-06 -6.4517 0.99991E+00 0.0000 31 CO3-2 0.86258E-07 -7.0642 0.77019E-07 -7.1134 0.89289E+00 -0.0492 32 CaCO3,aq 0.23823E-07 -7.6230 0.23823E-07 -7.6230 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.80169E-08 -8.0960 0.76891E-08 -8.1141 0.95912E+00 -0.0181 34 CaCl+ 0.55517E-08 -8.2556 0.53248E-08 -8.2737 0.95912E+00 -0.0181 35 CaCl2,aq 0.16405E-12 -12.7850 0.16405E-12 -12.7850 0.10000E+01 0.0000 36 CaOH+ 0.12799E-06 -6.8928 0.12276E-06 -6.9109 0.95912E+00 -0.0181 37 CaSO4,aq 0.17793E-06 -6.7498 0.17793E-06 -6.7498 0.10000E+01 0.0000 38 HCl,aq 0.36102E-12 -12.4425 0.36102E-12 -12.4425 0.10000E+01 0.0000 43 FeCl+ 0.11273E-12 -12.9480 0.10812E-12 -12.9661 0.95912E+00 -0.0181 46 FeO,aq 0.98594E-10 -10.0061 0.98594E-10 -10.0061 0.10000E+01 0.0000 47 FeOH+ 0.12501E-08 -8.9030 0.11990E-08 -8.9212 0.95912E+00 -0.0181 48 HFeO2- 0.76226E-10 -10.1179 0.73107E-10 -10.1360 0.95908E+00 -0.0181 49 FeO+ 0.12511E-12 -12.9027 0.11999E-12 -12.9208 0.95912E+00 -0.0181 50 FeOH+2 0.36281E-18 -18.4403 0.32389E-18 -18.4896 0.89275E+00 -0.0493 51 FeO2- 0.11686E-09 -9.9323 0.11208E-09 -9.9505 0.95908E+00 -0.0181 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.59134E-09 -9.2282 0.59128E-09 -9.2282 0.99991E+00 0.0000 54 KCl,aq 0.15738E-10 -10.8031 0.15738E-10 -10.8031 0.10000E+01 0.0000 55 KHSO4,aq 0.58962E-17 -17.2294 0.58962E-17 -17.2294 0.10000E+01 0.0000 56 KOH,aq 0.20188E-09 -9.6949 0.20188E-09 -9.6949 0.10000E+01 0.0000 57 KSO4- 0.24400E-08 -8.6126 0.23402E-08 -8.6307 0.95908E+00 -0.0181 58 MgCO3,aq 0.20830E-10 -10.6813 0.20830E-10 -10.6813 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28606E-10 -10.5435 0.27436E-10 -10.5617 0.95912E+00 -0.0181 60 MgCl+ 0.17636E-10 -10.7536 0.16915E-10 -10.7717 0.95912E+00 -0.0181 61 MgOH+ 0.24812E-08 -8.6053 0.23798E-08 -8.6235 0.95912E+00 -0.0181 63 MnO,aq 0.30172E-09 -9.5204 0.30172E-09 -9.5204 0.10000E+01 0.0000 64 MnOH+ 0.13313E-07 -7.8757 0.12769E-07 -7.8938 0.95912E+00 -0.0181 65 MnO2-2 0.55539E-16 -16.2554 0.49590E-16 -16.3046 0.89289E+00 -0.0492 66 HMnO2- 0.16250E-12 -12.7891 0.15585E-12 -12.8073 0.95908E+00 -0.0181 69 MnCl+ 0.50215E-10 -10.2992 0.48162E-10 -10.3173 0.95912E+00 -0.0181 70 MnSO4,aq 0.38541E-09 -9.4141 0.38541E-09 -9.4141 0.10000E+01 0.0000 71 NaCl,aq 0.83465E-08 -8.0785 0.83465E-08 -8.0785 0.10000E+01 0.0000 72 NaOH,aq 0.58520E-08 -8.2327 0.58520E-08 -8.2327 0.10000E+01 0.0000 74 OH- 0.43118E-04 -4.3653 0.41351E-04 -4.3835 0.95904E+00 -0.0182 82 H3PO4,aq 0.22237E-14 -14.6529 0.22237E-14 -14.6529 0.10000E+01 0.0000 83 H2PO4- 0.43526E-09 -9.3613 0.41746E-09 -9.3794 0.95910E+00 -0.0181 84 PO4-3 0.12458E-12 -12.9045 0.98824E-13 -13.0051 0.79324E+00 -0.1006 87 H2P2O7-2 0.15275E-19 -19.8160 0.13639E-19 -19.8652 0.89289E+00 -0.0492 88 HP2O7-3 0.24334E-18 -18.6138 0.19280E-18 -18.7149 0.79233E+00 -0.1011 90 H2S,aq 0.86892E-13 -13.0610 0.86884E-13 -13.0611 0.99991E+00 0.0000 96 SO2,aq 0.11787E-19 -19.9286 0.11787E-19 -19.9286 0.10000E+01 0.0000 97 SO3-2 0.20410E-14 -14.6902 0.18230E-14 -14.7392 0.89319E+00 -0.0491 98 HSO3- 0.16136E-14 -14.7922 0.15476E-14 -14.8103 0.95908E+00 -0.0181 99 HSO4- 0.31731E-09 -9.4985 0.30435E-09 -9.5166 0.95914E+00 -0.0181 101 S2O3-2 0.25932E-19 -19.5862 0.23155E-19 -19.6354 0.89289E+00 -0.0492 Charge balance for all species = 0.2017E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1512264E-07 -.7394827E-04 -.7453255E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999597E+06 0.0000 3 Cl- 0.1379618E-03 0.1379757E-03 0.4891465E+01 3.9601 4 SO4-- 0.2532369E-04 0.2550465E-04 0.2449923E+01 11.0313 5 HCO3- 0.1259857E-04 0.1307015E-04 0.7974731E+00 2.9206 6 HS- 0.2078556E-11 0.1099440E-09 0.3635929E-05 -3.8619 7 Al+++ 0.3032575E-20 0.3284398E-05 0.8861456E-01 2.8961 8 H4SiO4 0.2532043E-03 0.2710239E-03 0.2604857E+02 -3.5965 9 Ca++ 0.2828738E-04 0.2864074E-04 0.1147819E+01 11.0793 10 Mg++ 0.9899203E-07 0.1015841E-06 0.2469617E-02 8.6232 11 Fe++ 0.5876817E-09 0.2333196E-08 0.1302970E-03 6.3968 12 K+ 0.7003791E-05 0.7006449E-05 0.2739556E+00 2.6657 13 Na+ 0.2014299E-03 0.2014963E-03 0.4632182E+01 4.1244 14 Mn++ 0.6736895E-07 0.8141955E-07 0.4472855E-02 8.4561 15 HPO4-- 0.1838298E-08 0.2273684E-08 0.2182175E-03 6.8922 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5333910E-03 -.7394743E-04 -.4594436E-03 0.0000000E+00 2 H2O 0.5550784E+02 0.5550765E+02 0.1862102E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2641901E-04 0.2550436E-04 0.9146524E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9145425E-06 0.1099428E-09 -.9146524E-06 0.0000000E+00 7 Al+++ 0.1076045E-03 0.3284361E-05 0.1043201E-03 0.0000000E+00 8 H4SiO4 0.3436218E-03 0.2710209E-03 0.7260098E-04 0.0000000E+00 9 Ca++ 0.5242577E-04 0.2864041E-04 0.2378535E-04 0.0000000E+00 10 Mg++ 0.2619048E-04 0.1015829E-06 0.2608889E-04 0.0000000E+00 11 Fe++ 0.2352928E-04 0.2333170E-08 0.2352695E-04 0.0000000E+00 12 K+ 0.7006369E-05 0.7006369E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2014940E-03 0.2014940E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.5721737E-06 0.8141863E-07 0.4907550E-06 0.0000000E+00 15 HPO4-- 0.1952800E-06 0.2273659E-08 0.1930064E-06 0.0000000E+00 Chg. balance for solid moles: -.5400E-20 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0330000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6434E-07 -7.192 0.3232E-04 -4.491 0.2060 0.1027E-04 clinochlore 0.5218E-05 -5.283 0.2900E-02 -2.538 18.49 0.1103E-02 daphnite 0.3242E-05 -5.489 0.2313E-02 -2.636 14.74 0.7010E-03 chlorite-Mn 0.9815E-07 -7.008 0.6959E-04 -4.157 0.4435 0.2218E-04 diaspore 0.4028E-04 -4.395 0.2416E-02 -2.617 15.40 0.7193E-03 hematite 0.3659E-05 -5.437 0.5843E-03 -3.233 3.724 0.1107E-03 lawsonite 0.2346E-04 -4.630 0.7373E-02 -2.132 47.00 0.2378E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3788E+00 0.3788E+00 1.0000 -0.422 chlorite-Mn 0.1147E-01 0.1147E-01 1.0000 -1.940 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.015689 g Volume = 0.005044 cm3 Porosity: 99.5021% V(tot) - V(min): 0.10082E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0330000 g log = -1.4815 Original solution: 1000.0103000 g Original solution / Rock added: 30303.34 (Water/Rock Ratio), log = 4.4815 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3817E-04 1.0073 0.4045E-04 0.4016E-04 CH4,gas 0.1551E-14 1.0129 0.1653E-14 0.1632E-14 H2,gas 0.7705E-06 1.0006 0.8110E-06 0.8105E-06 H2S,gas 0.2419E-11 0.9959 0.2534E-11 0.2544E-11 S2,gas 0.3476E-30 1.0000 0.3657E-30 0.3657E-30 CO,gas 0.8078E-14 1.0000 0.8498E-14 0.8498E-14 SO3,gas 0.1691E-35 1.0000 0.1779E-35 0.1779E-35 SO2,gas 0.5188E-19 1.0000 0.5457E-19 0.5457E-19 HCl,gas 0.6060E-15 1.0000 0.6375E-15 0.6375E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.76 -6.39 -2.131 0.10916E+05 -4.393 3 CH4,gas 4.81 -11.97 -16.78 -4.195 0.28654E+05 -14.782 4 H2,gas 8.29 0.20 -8.09 -4.623 0.13815E+05 -6.091 5 H2S,gas -5.94 -19.54 -13.60 -6.798 0.23215E+05 -11.596 6 S2,gas -7.03 -39.47 -32.44 -4.990 0.55385E+05 -30.437 7 CO,gas 3.51 -12.56 -16.07 -4.945 0.27440E+05 -14.071 8 SO3,gas 17.43 -20.32 -37.75 -9.437 0.64457E+05 -35.750 9 SO2,gas 1.14 -20.13 -21.26 -5.670 0.36306E+05 -19.263 10 HCl,gas 5.48 -11.72 -17.20 -8.598 0.29361E+05 -15.196 11 acmite 7.74 3.23 -4.51 -0.468 0.76959E+04 15 albite-high 0.75 -3.77 -4.52 -0.348 0.77156E+04 16 albite -0.33 -3.77 -3.44 -0.265 0.58749E+04 19 spessartine 24.55 20.37 -4.18 -0.209 0.71356E+04 20 analcite 3.37 -0.17 -3.54 -0.394 0.60499E+04 21 andalusite 5.06 2.20 -2.87 -0.287 0.48949E+04 22 andradite 39.09 35.05 -4.04 -0.210 0.69015E+04 23 grossular 32.83 28.24 -4.59 -0.229 0.78336E+04 24 anhydrite -5.28 -9.24 -3.96 -1.982 0.67677E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.68 -2.66 -0.888 0.45474E+04 36 brucite 12.58 8.62 -3.95 -0.791 0.67503E+04 37 calcite 0.83 -1.68 -2.51 -0.837 0.42861E+04 40 carpholite-Mg 8.65 7.22 -1.43 -0.095 0.24383E+04 41 carpholite-Fe 6.78 5.00 -1.79 -0.119 0.30513E+04 50 chloritoid-Mg 13.26 10.82 -2.44 -0.163 0.41703E+04 51 chloritoid-Fe 9.24 8.59 -0.65 -0.043 0.11035E+04 52 chloritoid-Mn 11.46 10.65 -0.81 -0.054 0.13856E+04 54 coesite -2.37 -3.60 -1.23 -0.409 0.20954E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.60 -1.05 -0.349 0.17883E+04 67 diopside 16.22 12.51 -3.71 -0.371 0.63280E+04 68 hedenbergite 14.24 10.28 -3.96 -0.396 0.67641E+04 75 epidote 24.78 23.46 -1.32 -0.064 0.22458E+04 76 clinozoisite 22.92 20.06 -2.86 -0.130 0.48901E+04 77 epidote-Fe 29.94 26.86 -3.07 -0.160 0.52490E+04 78 fayalite 14.08 9.20 -4.88 -0.697 0.83358E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.00 -4.20 -0.350 0.71662E+04 91 heulandite -5.71 -8.30 -2.60 -0.118 0.44346E+04 95 jadeite 4.25 -0.17 -4.42 -0.442 0.75529E+04 98 kaolinite -1.27 -1.40 -0.13 -0.012 0.21811E+03 99 kyanite 4.93 2.20 -2.74 -0.274 0.46716E+04 101 laumontite 2.97 2.49 -0.49 -0.033 0.83534E+03 105 lizardite 23.29 18.68 -4.61 -0.384 0.78729E+04 106 magnesite 0.71 -4.13 -4.84 -1.614 0.82682E+04 107 magnetite 20.13 18.99 -1.14 -0.093 0.19438E+04 113 margarite 17.45 15.47 -1.98 -0.079 0.33829E+04 116 microcline -2.43 -5.23 -2.80 -0.215 0.47742E+04 120 muscovite 2.68 0.56 -2.11 -0.124 0.36111E+04 121 paragonite 4.34 2.02 -2.31 -0.136 0.39503E+04 122 nepheline 8.38 3.42 -4.95 -0.708 0.84590E+04 136 prehnite 19.47 17.16 -2.31 -0.136 0.39361E+04 137 prehnite-Fe 22.59 20.56 -2.02 -0.122 0.34541E+04 138 pumpellyite-Fe 46.47 43.62 -2.86 -0.063 0.48757E+04 139 pumpellyite-Mg 49.19 45.84 -3.35 -0.075 0.57244E+04 145 pyroxmangite 7.42 4.86 -2.56 -0.511 0.43651E+04 146 pyrophyllite -6.10 -8.59 -2.50 -0.156 0.42617E+04 147 quartz -2.98 -3.60 -0.61 -0.205 0.10493E+04 152 rhodochrosite -0.96 -4.30 -3.34 -1.114 0.57058E+04 153 rhodonite 7.46 4.86 -2.60 -0.521 0.44443E+04 154 sanidine -1.22 -5.23 -4.01 -0.308 0.68419E+04 156 siderite -2.59 -6.36 -3.77 -1.257 0.64403E+04 157 sillimanite 5.32 2.20 -3.13 -0.313 0.53370E+04 164 stilbite -7.41 -8.30 -0.90 -0.043 0.15340E+04 165 stilpnomelane-Fe 13.18 10.34 -2.84 -0.085 0.48539E+04 168 sudoite-Fe 18.44 13.59 -4.85 -0.156 0.82791E+04 169 sudoite 21.22 18.04 -3.17 -0.102 0.54212E+04 175 tephroite 18.11 13.32 -4.80 -0.685 0.81912E+04 178 topaz-H 4.67 2.20 -2.47 -0.225 0.42207E+04 179 tridymite -2.61 -3.60 -0.98 -0.327 0.16766E+04 188 wairakite 4.06 2.49 -1.57 -0.093 0.26862E+04 189 walstromite 11.53 7.48 -4.05 -0.809 0.69070E+04 190 wollastonite 10.48 7.48 -3.00 -0.600 0.51209E+04 191 pseudo-wollastonite 11.02 7.48 -3.54 -0.707 0.60395E+04 192 zoisite 22.96 20.06 -2.91 -0.132 0.49627E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.62 -3.06 -0.190 0.52311E+04 195 beidellite-H -2.24 -6.45 -4.21 -0.269 0.71889E+04 196 beidellite-K -1.44 -5.57 -4.14 -0.253 0.70633E+04 197 beidellite-Mg -1.71 -5.03 -3.32 -0.205 0.56716E+04 198 beidellite-Na -1.26 -5.09 -3.83 -0.235 0.65452E+04 200 chalcedony -2.79 -3.60 -0.80 -0.267 0.13696E+04 202 montmorillonite-Ca -2.21 -4.88 -2.66 -0.165 0.45451E+04 203 montmorillonite-K -2.16 -5.82 -3.66 -0.224 0.62551E+04 204 montmorillonite-Mg -2.40 -5.28 -2.88 -0.178 0.49167E+04 205 montmorillonite-Na -1.96 -5.34 -3.38 -0.207 0.57752E+04 206 nontronite-Ca 3.28 2.18 -1.10 -0.071 0.18740E+04 207 nontronite-H 2.60 0.35 -2.24 -0.150 0.38276E+04 208 nontronite-K 3.40 1.23 -2.17 -0.139 0.37054E+04 209 nontronite-Mg 3.14 1.78 -1.36 -0.088 0.23262E+04 210 nontronite-Na 3.58 1.72 -1.87 -0.120 0.31890E+04 215 gypsum -4.92 -9.24 -4.32 -1.080 0.73744E+04 225 tobermorite 9.84 5.63 -4.21 -1.148 0.71825E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.40 -3.43 -0.857 0.58523E+04 241 silica-amorphous -2.08 -3.60 -1.52 -0.506 0.25898E+04 243 an20ab80 2.08 -1.08 -3.16 -0.243 0.53935E+04 244 an25ab75 2.71 -0.41 -3.12 -0.240 0.53211E+04 245 an30ab70 3.34 0.27 -3.08 -0.237 0.52570E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0330000 g New total amount of reactant added: 0.0340000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0340000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3022608E-03 Osmotic coef. = 0.9896 True ionic strength = .3185185E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15238E-07 -7.8171 0.14617E-07 -7.8351 0.95924E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13232E-03 -3.8784 0.95911E+00 -0.0181 4 SO4-- 0.25328E-04 -4.5964 0.22619E-04 -4.6455 0.89305E+00 -0.0491 5 HCO3- 0.12598E-04 -4.8997 0.12083E-04 -4.9178 0.95914E+00 -0.0181 6 HS- 0.18875E-11 -11.7241 0.18103E-11 -11.7423 0.95911E+00 -0.0181 7 Al+++ 0.31020E-20 -20.5084 0.24585E-20 -20.6093 0.79255E+00 -0.1010 8 H4SiO4 0.25872E-03 -3.5872 0.25872E-03 -3.5872 0.10000E+01 0.0000 9 Ca++ 0.27507E-04 -4.5606 0.24561E-04 -4.6098 0.89290E+00 -0.0492 10 Mg++ 0.99210E-07 -7.0034 0.88575E-07 -7.0527 0.89280E+00 -0.0492 11 Fe++ 0.58892E-09 -9.2299 0.52580E-09 -9.2792 0.89282E+00 -0.0492 12 K+ 0.72160E-05 -5.1417 0.69212E-05 -5.1598 0.95915E+00 -0.0181 13 Na+ 0.20268E-03 -3.6932 0.19440E-03 -3.7113 0.95910E+00 -0.0181 14 Mn++ 0.67786E-07 -7.1689 0.60522E-07 -7.2181 0.89284E+00 -0.0492 15 HPO4-- 0.19451E-08 -8.7111 0.17371E-08 -8.7602 0.89305E+00 -0.0491 16 HSiO3- 0.18006E-04 -4.7446 0.17269E-04 -4.7627 0.95911E+00 -0.0181 17 Ca(HSiO3)+ 0.99079E-08 -8.0040 0.95032E-08 -8.0221 0.95915E+00 -0.0181 18 Mg(HSiO3)+ 0.44468E-10 -10.3519 0.42652E-10 -10.3701 0.95915E+00 -0.0181 19 NaHSiO3,aq 0.53319E-07 -7.2731 0.53319E-07 -7.2731 0.10000E+01 0.0000 20 AlO+ 0.15487E-11 -11.8100 0.14855E-11 -11.8281 0.95915E+00 -0.0181 21 AlOH+2 0.12182E-15 -15.9143 0.10877E-15 -15.9635 0.89286E+00 -0.0492 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.32391E-05 -5.4896 0.31065E-05 -5.5077 0.95907E+00 -0.0182 24 CH4,aq 0.94899E-18 -18.0227 0.94890E-18 -18.0228 0.99991E+00 0.0000 29 CO,aq 0.52832E-17 -17.2771 0.52832E-17 -17.2771 0.10000E+01 0.0000 30 CO2,aq 0.35613E-06 -6.4484 0.35609E-06 -6.4484 0.99991E+00 0.0000 31 CO3-2 0.85587E-07 -7.0676 0.76430E-07 -7.1167 0.89300E+00 -0.0491 32 CaCO3,aq 0.22991E-07 -7.6384 0.22991E-07 -7.6384 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.77961E-08 -8.1081 0.74776E-08 -8.1262 0.95915E+00 -0.0181 34 CaCl+ 0.53992E-08 -8.2677 0.51787E-08 -8.2858 0.95915E+00 -0.0181 35 CaCl2,aq 0.15955E-12 -12.7971 0.15955E-12 -12.7971 0.10000E+01 0.0000 36 CaOH+ 0.12353E-06 -6.9082 0.11848E-06 -6.9263 0.95915E+00 -0.0181 37 CaSO4,aq 0.17310E-06 -6.7617 0.17310E-06 -6.7617 0.10000E+01 0.0000 38 HCl,aq 0.36380E-12 -12.4391 0.36380E-12 -12.4391 0.10000E+01 0.0000 43 FeCl+ 0.11298E-12 -12.9470 0.10836E-12 -12.9651 0.95915E+00 -0.0181 46 FeO,aq 0.97316E-10 -10.0118 0.97316E-10 -10.0118 0.10000E+01 0.0000 47 FeOH+ 0.12433E-08 -8.9054 0.11926E-08 -8.9235 0.95915E+00 -0.0181 48 HFeO2- 0.74664E-10 -10.1269 0.71611E-10 -10.1450 0.95911E+00 -0.0181 49 FeO+ 0.12606E-12 -12.8994 0.12091E-12 -12.9175 0.95915E+00 -0.0181 50 FeOH+2 0.36834E-18 -18.4337 0.32888E-18 -18.4830 0.89286E+00 -0.0492 51 FeO2- 0.11597E-09 -9.9357 0.11123E-09 -9.9538 0.95911E+00 -0.0181 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.57611E-09 -9.2395 0.57606E-09 -9.2395 0.99991E+00 0.0000 54 KCl,aq 0.16216E-10 -10.7901 0.16216E-10 -10.7901 0.10000E+01 0.0000 55 KHSO4,aq 0.61236E-17 -17.2130 0.61236E-17 -17.2130 0.10000E+01 0.0000 56 KOH,aq 0.20642E-09 -9.6852 0.20642E-09 -9.6852 0.10000E+01 0.0000 57 KSO4- 0.25148E-08 -8.5995 0.24119E-08 -8.6176 0.95911E+00 -0.0181 58 MgCO3,aq 0.20718E-10 -10.6836 0.20718E-10 -10.6836 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28670E-10 -10.5426 0.27499E-10 -10.5607 0.95915E+00 -0.0181 60 MgCl+ 0.17677E-10 -10.7526 0.16955E-10 -10.7707 0.95915E+00 -0.0181 61 MgOH+ 0.24680E-08 -8.6077 0.23672E-08 -8.6258 0.95915E+00 -0.0181 63 MnO,aq 0.29903E-09 -9.5243 0.29903E-09 -9.5243 0.10000E+01 0.0000 64 MnOH+ 0.13295E-07 -7.8763 0.12752E-07 -7.8944 0.95915E+00 -0.0181 65 MnO2-2 0.54201E-16 -16.2660 0.48402E-16 -16.3151 0.89300E+00 -0.0491 66 HMnO2- 0.15982E-12 -12.7964 0.15329E-12 -12.8145 0.95911E+00 -0.0181 69 MnCl+ 0.50533E-10 -10.2964 0.48468E-10 -10.3145 0.95915E+00 -0.0181 70 MnSO4,aq 0.38797E-09 -9.4112 0.38797E-09 -9.4112 0.10000E+01 0.0000 71 NaCl,aq 0.83990E-08 -8.0758 0.83990E-08 -8.0758 0.10000E+01 0.0000 72 NaOH,aq 0.58438E-08 -8.2333 0.58438E-08 -8.2333 0.10000E+01 0.0000 74 OH- 0.42788E-04 -4.3687 0.41037E-04 -4.3868 0.95907E+00 -0.0182 82 H3PO4,aq 0.23894E-14 -14.6217 0.23894E-14 -14.6217 0.10000E+01 0.0000 83 H2PO4- 0.46412E-09 -9.3334 0.44515E-09 -9.3515 0.95913E+00 -0.0181 84 PO4-3 0.13080E-12 -12.8834 0.10378E-12 -12.9839 0.79347E+00 -0.1005 87 H2P2O7-2 0.17367E-19 -19.7603 0.15509E-19 -19.8094 0.89300E+00 -0.0491 88 HP2O7-3 0.27451E-18 -18.5614 0.21757E-18 -18.6624 0.79256E+00 -0.1010 90 H2S,aq 0.79511E-13 -13.0996 0.79504E-13 -13.0996 0.99991E+00 0.0000 96 SO2,aq 0.11664E-19 -19.9332 0.11664E-19 -19.9332 0.10000E+01 0.0000 97 SO3-2 0.19888E-14 -14.7014 0.17766E-14 -14.7504 0.89331E+00 -0.0490 98 HSO3- 0.15846E-14 -14.8001 0.15198E-14 -14.8182 0.95911E+00 -0.0181 99 HSO4- 0.31984E-09 -9.4951 0.30678E-09 -9.5132 0.95917E+00 -0.0181 101 S2O3-2 0.23734E-19 -19.6246 0.21194E-19 -19.6738 0.89300E+00 -0.0491 Charge balance for all species = 0.2018E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1523809E-07 -.7375965E-04 -.7434239E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999592E+06 0.0000 3 Cl- 0.1379619E-03 0.1379758E-03 0.4891464E+01 3.9568 4 SO4-- 0.2532845E-04 0.2550466E-04 0.2449923E+01 11.0248 5 HCO3- 0.1259760E-04 0.1307015E-04 0.7974729E+00 2.9173 6 HS- 0.1887465E-11 0.1060499E-09 0.3507145E-05 -3.9071 7 Al+++ 0.3101966E-20 0.3259462E-05 0.8794174E-01 2.8961 8 H4SiO4 0.2587235E-03 0.2767925E-03 0.2660298E+02 -3.5872 9 Ca++ 0.2750686E-04 0.2784958E-04 0.1116112E+01 11.0605 10 Mg++ 0.9921003E-07 0.1017896E-06 0.2474611E-02 8.6176 11 Fe++ 0.5889179E-09 0.2323919E-08 0.1297788E-03 6.3911 12 K+ 0.7216030E-05 0.7218768E-05 0.2822572E+00 2.6753 13 Na+ 0.2026841E-03 0.2027516E-03 0.4661037E+01 4.1238 14 Mn++ 0.6778622E-07 0.8181882E-07 0.4494786E-02 8.4522 15 HPO4-- 0.1945107E-08 0.2409364E-08 0.2312393E-03 6.9101 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5499495E-03 -.7375879E-04 -.4761907E-03 0.0000000E+00 2 H2O 0.5550782E+02 0.5550763E+02 0.1896625E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2644673E-04 0.2550436E-04 0.9423620E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9422559E-06 0.1060487E-09 -.9423620E-06 0.0000000E+00 7 Al+++ 0.1108652E-03 0.3259424E-05 0.1076058E-03 0.0000000E+00 8 H4SiO4 0.3540346E-03 0.2767893E-03 0.7724534E-04 0.0000000E+00 9 Ca++ 0.5357591E-04 0.2784926E-04 0.2572665E-04 0.0000000E+00 10 Mg++ 0.2698413E-04 0.1017884E-06 0.2688234E-04 0.0000000E+00 11 Fe++ 0.2424229E-04 0.2323891E-08 0.2423997E-04 0.0000000E+00 12 K+ 0.7218684E-05 0.7218684E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2027493E-03 0.2027493E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.5895123E-06 0.8181787E-07 0.5076944E-06 0.0000000E+00 15 HPO4-- 0.2011976E-06 0.2409336E-08 0.1987883E-06 0.0000000E+00 Chg. balance for solid moles: -.1466E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0340000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6626E-07 -7.179 0.3329E-04 -4.478 0.2028 0.1058E-04 clinochlore 0.5376E-05 -5.270 0.2988E-02 -2.525 18.21 0.1137E-02 daphnite 0.3340E-05 -5.476 0.2383E-02 -2.623 14.52 0.7222E-03 chlorite-Mn 0.1015E-06 -6.993 0.7199E-04 -4.143 0.4387 0.2294E-04 diaspore 0.3918E-04 -4.407 0.2350E-02 -2.629 14.32 0.6997E-03 hematite 0.3769E-05 -5.424 0.6020E-03 -3.220 3.668 0.1141E-03 lawsonite 0.2540E-04 -4.595 0.7980E-02 -2.098 48.63 0.2573E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3788E+00 0.3788E+00 1.0000 -0.422 chlorite-Mn 0.1151E-01 0.1151E-01 1.0000 -1.939 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.016409 g Volume = 0.005280 cm3 Porosity: 99.4791% V(tot) - V(min): 0.10083E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0340000 g log = -1.4685 Original solution: 1000.0103000 g Original solution / Rock added: 29412.07 (Water/Rock Ratio), log = 4.4685 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3847E-04 1.0073 0.4076E-04 0.4046E-04 CH4,gas 0.1408E-14 1.0129 0.1501E-14 0.1481E-14 H2,gas 0.7507E-06 1.0006 0.7901E-06 0.7897E-06 H2S,gas 0.2213E-11 0.9959 0.2319E-11 0.2328E-11 S2,gas 0.3067E-30 1.0000 0.3226E-30 0.3226E-30 CO,gas 0.7930E-14 1.0000 0.8342E-14 0.8342E-14 SO3,gas 0.1718E-35 1.0000 0.1807E-35 0.1807E-35 SO2,gas 0.5134E-19 1.0000 0.5400E-19 0.5400E-19 HCl,gas 0.6106E-15 1.0000 0.6424E-15 0.6424E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.75 -6.39 -2.130 0.10910E+05 -4.390 3 CH4,gas 4.81 -12.01 -16.82 -4.206 0.28726E+05 -14.824 4 H2,gas 8.29 0.18 -8.10 -4.630 0.13834E+05 -6.102 5 H2S,gas -5.94 -19.58 -13.63 -6.817 0.23281E+05 -11.635 6 S2,gas -7.03 -39.52 -32.49 -4.999 0.55478E+05 -30.491 7 CO,gas 3.51 -12.57 -16.08 -4.947 0.27454E+05 -14.079 8 SO3,gas 17.43 -20.32 -37.74 -9.436 0.64445E+05 -35.743 9 SO2,gas 1.14 -20.13 -21.27 -5.671 0.36314E+05 -19.268 10 HCl,gas 5.48 -11.71 -17.19 -8.596 0.29355E+05 -15.192 11 acmite 7.74 3.25 -4.49 -0.466 0.76650E+04 15 albite-high 0.75 -3.74 -4.49 -0.345 0.76686E+04 16 albite -0.33 -3.74 -3.41 -0.263 0.58280E+04 19 spessartine 24.55 20.39 -4.16 -0.208 0.71076E+04 20 analcite 3.37 -0.15 -3.53 -0.392 0.60189E+04 21 andalusite 5.06 2.21 -2.86 -0.286 0.48789E+04 22 andradite 39.09 35.02 -4.07 -0.211 0.69495E+04 23 grossular 32.83 28.21 -4.62 -0.231 0.78816E+04 24 anhydrite -5.28 -9.26 -3.98 -1.988 0.67881E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.69 -2.68 -0.893 0.45738E+04 36 brucite 12.58 8.62 -3.96 -0.792 0.67599E+04 37 calcite 0.83 -1.69 -2.53 -0.842 0.43124E+04 40 carpholite-Mg 8.65 7.24 -1.41 -0.094 0.24160E+04 41 carpholite-Fe 6.78 5.01 -1.77 -0.118 0.30290E+04 50 chloritoid-Mg 13.26 10.82 -2.44 -0.163 0.41639E+04 51 chloritoid-Fe 9.24 8.60 -0.64 -0.043 0.10971E+04 52 chloritoid-Mn 11.46 10.66 -0.81 -0.054 0.13762E+04 54 coesite -2.37 -3.59 -1.22 -0.406 0.20794E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.59 -1.04 -0.346 0.17723E+04 67 diopside 16.22 12.50 -3.71 -0.371 0.63376E+04 68 hedenbergite 14.24 10.28 -3.97 -0.397 0.67737E+04 75 epidote 24.78 23.45 -1.32 -0.064 0.22618E+04 76 clinozoisite 22.92 20.05 -2.87 -0.131 0.49061E+04 77 epidote-Fe 29.94 26.85 -3.08 -0.160 0.52650E+04 78 fayalite 14.08 9.20 -4.88 -0.698 0.83392E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.00 -4.20 -0.350 0.71632E+04 91 heulandite -5.71 -8.26 -2.55 -0.116 0.43546E+04 95 jadeite 4.25 -0.15 -4.41 -0.441 0.75220E+04 98 kaolinite -1.27 -1.38 -0.11 -0.010 0.18613E+03 99 kyanite 4.93 2.21 -2.73 -0.273 0.46556E+04 101 laumontite 2.97 2.50 -0.47 -0.031 0.80336E+03 105 lizardite 23.29 18.68 -4.61 -0.384 0.78697E+04 106 magnesite 0.71 -4.14 -4.84 -1.615 0.82722E+04 107 magnetite 20.13 18.99 -1.14 -0.093 0.19535E+04 113 margarite 17.45 15.47 -1.98 -0.079 0.33829E+04 116 microcline -2.43 -5.19 -2.76 -0.212 0.47097E+04 120 muscovite 2.68 0.60 -2.08 -0.122 0.35466E+04 121 paragonite 4.34 2.05 -2.29 -0.134 0.39033E+04 122 nepheline 8.38 3.43 -4.95 -0.706 0.84441E+04 136 prehnite 19.47 17.15 -2.31 -0.136 0.39521E+04 137 prehnite-Fe 22.59 20.55 -2.03 -0.122 0.34701E+04 138 pumpellyite-Fe 46.47 43.59 -2.88 -0.064 0.49173E+04 139 pumpellyite-Mg 49.19 45.82 -3.38 -0.075 0.57660E+04 145 pyroxmangite 7.42 4.87 -2.55 -0.510 0.43558E+04 146 pyrophyllite -6.10 -8.56 -2.46 -0.154 0.41977E+04 147 quartz -2.98 -3.59 -0.61 -0.202 0.10333E+04 152 rhodochrosite -0.96 -4.30 -3.34 -1.114 0.57068E+04 153 rhodonite 7.46 4.87 -2.60 -0.519 0.44350E+04 154 sanidine -1.22 -5.19 -3.97 -0.305 0.67774E+04 156 siderite -2.59 -6.36 -3.77 -1.258 0.64443E+04 157 sillimanite 5.32 2.21 -3.12 -0.312 0.53210E+04 164 stilbite -7.41 -8.26 -0.85 -0.041 0.14541E+04 165 stilpnomelane-Fe 13.18 10.39 -2.79 -0.083 0.47661E+04 168 sudoite-Fe 18.44 13.61 -4.83 -0.156 0.82504E+04 169 sudoite 21.22 18.06 -3.16 -0.102 0.53924E+04 175 tephroite 18.11 13.32 -4.80 -0.685 0.81885E+04 178 topaz-H 4.67 2.21 -2.46 -0.224 0.42047E+04 179 tridymite -2.61 -3.59 -0.97 -0.324 0.16606E+04 188 wairakite 4.06 2.50 -1.55 -0.091 0.26542E+04 189 walstromite 11.53 7.47 -4.05 -0.811 0.69230E+04 190 wollastonite 10.48 7.47 -3.01 -0.602 0.51369E+04 191 pseudo-wollastonite 11.02 7.47 -3.55 -0.709 0.60555E+04 192 zoisite 22.96 20.05 -2.92 -0.133 0.49787E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.59 -3.03 -0.188 0.51776E+04 195 beidellite-H -2.24 -6.42 -4.18 -0.266 0.71302E+04 196 beidellite-K -1.44 -5.53 -4.10 -0.251 0.69991E+04 197 beidellite-Mg -1.71 -5.00 -3.29 -0.203 0.56145E+04 198 beidellite-Na -1.26 -5.06 -3.80 -0.233 0.64869E+04 200 chalcedony -2.79 -3.59 -0.79 -0.264 0.13536E+04 202 montmorillonite-Ca -2.21 -4.84 -2.63 -0.163 0.44896E+04 203 montmorillonite-K -2.16 -5.79 -3.62 -0.222 0.61888E+04 204 montmorillonite-Mg -2.40 -5.25 -2.84 -0.176 0.48575E+04 205 montmorillonite-Na -1.96 -5.31 -3.35 -0.205 0.57147E+04 206 nontronite-Ca 3.28 2.21 -1.07 -0.069 0.18206E+04 207 nontronite-H 2.60 0.39 -2.21 -0.148 0.37689E+04 208 nontronite-K 3.40 1.27 -2.13 -0.137 0.36412E+04 209 nontronite-Mg 3.14 1.81 -1.33 -0.086 0.22691E+04 210 nontronite-Na 3.58 1.75 -1.83 -0.118 0.31307E+04 215 gypsum -4.92 -9.26 -4.33 -1.083 0.73949E+04 225 tobermorite 9.84 5.63 -4.21 -1.149 0.71932E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.39 -3.43 -0.858 0.58620E+04 241 silica-amorphous -2.08 -3.59 -1.51 -0.502 0.25738E+04 243 an20ab80 2.08 -1.06 -3.14 -0.241 0.53560E+04 244 an25ab75 2.71 -0.39 -3.10 -0.238 0.52859E+04 245 an30ab70 3.34 0.28 -3.06 -0.235 0.52242E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0340000 g New total amount of reactant added: 0.0350000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0350000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3013403E-03 Osmotic coef. = 0.9896 True ionic strength = .3176901E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15347E-07 -7.8140 0.14722E-07 -7.8320 0.95927E+00 -0.0181 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13232E-03 -3.8784 0.95914E+00 -0.0181 4 SO4-- 0.25333E-04 -4.5963 0.22626E-04 -4.6454 0.89315E+00 -0.0491 5 HCO3- 0.12597E-04 -4.8997 0.12082E-04 -4.9178 0.95917E+00 -0.0181 6 HS- 0.17161E-11 -11.7655 0.16460E-11 -11.7836 0.95914E+00 -0.0181 7 Al+++ 0.31684E-20 -20.4992 0.25118E-20 -20.6000 0.79277E+00 -0.1009 8 H4SiO4 0.26427E-03 -3.5780 0.26427E-03 -3.5780 0.10000E+01 0.0000 9 Ca++ 0.26742E-04 -4.5728 0.23880E-04 -4.6220 0.89300E+00 -0.0491 10 Mg++ 0.99355E-07 -7.0028 0.88715E-07 -7.0520 0.89291E+00 -0.0492 11 Fe++ 0.58972E-09 -9.2294 0.52658E-09 -9.2785 0.89293E+00 -0.0492 12 K+ 0.74283E-05 -5.1291 0.71250E-05 -5.1472 0.95917E+00 -0.0181 13 Na+ 0.20394E-03 -3.6905 0.19560E-03 -3.7086 0.95913E+00 -0.0181 14 Mn++ 0.68147E-07 -7.1666 0.60852E-07 -7.2157 0.89295E+00 -0.0492 15 HPO4-- 0.20576E-08 -8.6866 0.18378E-08 -8.7357 0.89316E+00 -0.0491 16 HSiO3- 0.18260E-04 -4.7385 0.17514E-04 -4.7566 0.95914E+00 -0.0181 17 Ca(HSiO3)+ 0.97694E-08 -8.0101 0.93706E-08 -8.0282 0.95918E+00 -0.0181 18 Mg(HSiO3)+ 0.45168E-10 -10.3452 0.43324E-10 -10.3633 0.95918E+00 -0.0181 19 NaHSiO3,aq 0.54409E-07 -7.2643 0.54409E-07 -7.2643 0.10000E+01 0.0000 20 AlO+ 0.15598E-11 -11.8069 0.14961E-11 -11.8250 0.95918E+00 -0.0181 21 AlOH+2 0.12356E-15 -15.9081 0.11034E-15 -15.9573 0.89297E+00 -0.0492 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.32159E-05 -5.4927 0.30844E-05 -5.5108 0.95910E+00 -0.0181 24 CH4,aq 0.86256E-18 -18.0642 0.86248E-18 -18.0643 0.99991E+00 0.0000 29 CO,aq 0.51862E-17 -17.2852 0.51862E-17 -17.2852 0.10000E+01 0.0000 30 CO2,aq 0.35867E-06 -6.4453 0.35863E-06 -6.4453 0.99991E+00 0.0000 31 CO3-2 0.84963E-07 -7.0708 0.75882E-07 -7.1199 0.89311E+00 -0.0491 32 CaCO3,aq 0.22194E-07 -7.6538 0.22194E-07 -7.6538 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.75795E-08 -8.1204 0.72701E-08 -8.1385 0.95918E+00 -0.0181 34 CaCl+ 0.52497E-08 -8.2799 0.50354E-08 -8.2980 0.95918E+00 -0.0181 35 CaCl2,aq 0.15514E-12 -12.8093 0.15514E-12 -12.8093 0.10000E+01 0.0000 36 CaOH+ 0.11925E-06 -6.9236 0.11438E-06 -6.9417 0.95918E+00 -0.0181 37 CaSO4,aq 0.16835E-06 -6.7738 0.16835E-06 -6.7738 0.10000E+01 0.0000 38 HCl,aq 0.36643E-12 -12.4360 0.36643E-12 -12.4360 0.10000E+01 0.0000 43 FeCl+ 0.11315E-12 -12.9464 0.10853E-12 -12.9645 0.95918E+00 -0.0181 46 FeO,aq 0.96076E-10 -10.0174 0.96076E-10 -10.0174 0.10000E+01 0.0000 47 FeOH+ 0.12363E-08 -8.9079 0.11858E-08 -8.9260 0.95918E+00 -0.0181 48 HFeO2- 0.73184E-10 -10.1356 0.70194E-10 -10.1537 0.95914E+00 -0.0181 49 FeO+ 0.12697E-12 -12.8963 0.12178E-12 -12.9144 0.95918E+00 -0.0181 50 FeOH+2 0.37361E-18 -18.4276 0.33362E-18 -18.4767 0.89297E+00 -0.0492 51 FeO2- 0.11514E-09 -9.9388 0.11043E-09 -9.9569 0.95914E+00 -0.0181 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.56152E-09 -9.2506 0.56147E-09 -9.2507 0.99991E+00 0.0000 54 KCl,aq 0.16694E-10 -10.7774 0.16694E-10 -10.7774 0.10000E+01 0.0000 55 KHSO4,aq 0.63511E-17 -17.1972 0.63511E-17 -17.1972 0.10000E+01 0.0000 56 KOH,aq 0.21099E-09 -9.6757 0.21099E-09 -9.6757 0.10000E+01 0.0000 57 KSO4- 0.25895E-08 -8.5868 0.24837E-08 -8.6049 0.95914E+00 -0.0181 58 MgCO3,aq 0.20602E-10 -10.6861 0.20602E-10 -10.6861 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28713E-10 -10.5419 0.27541E-10 -10.5600 0.95918E+00 -0.0181 60 MgCl+ 0.17705E-10 -10.7519 0.16982E-10 -10.7700 0.95918E+00 -0.0181 61 MgOH+ 0.24542E-08 -8.6101 0.23540E-08 -8.6282 0.95918E+00 -0.0181 63 MnO,aq 0.29638E-09 -9.5281 0.29638E-09 -9.5281 0.10000E+01 0.0000 64 MnOH+ 0.13272E-07 -7.8771 0.12730E-07 -7.8952 0.95918E+00 -0.0181 65 MnO2-2 0.52952E-16 -16.2761 0.47292E-16 -16.3252 0.89311E+00 -0.0491 66 HMnO2- 0.15727E-12 -12.8033 0.15085E-12 -12.8215 0.95914E+00 -0.0181 69 MnCl+ 0.50808E-10 -10.2941 0.48734E-10 -10.3122 0.95918E+00 -0.0181 70 MnSO4,aq 0.39020E-09 -9.4087 0.39020E-09 -9.4087 0.10000E+01 0.0000 71 NaCl,aq 0.84515E-08 -8.0731 0.84515E-08 -8.0731 0.10000E+01 0.0000 72 NaOH,aq 0.58382E-08 -8.2337 0.58382E-08 -8.2337 0.10000E+01 0.0000 74 OH- 0.42482E-04 -4.3718 0.40744E-04 -4.3899 0.95910E+00 -0.0181 82 H3PO4,aq 0.25644E-14 -14.5910 0.25644E-14 -14.5910 0.10000E+01 0.0000 83 H2PO4- 0.49455E-09 -9.3058 0.47435E-09 -9.3239 0.95916E+00 -0.0181 84 PO4-3 0.13736E-12 -12.8621 0.10902E-12 -12.9625 0.79368E+00 -0.1004 87 H2P2O7-2 0.19718E-19 -19.7051 0.17610E-19 -19.7542 0.89311E+00 -0.0491 88 HP2O7-3 0.30940E-18 -18.5095 0.24528E-18 -18.6103 0.79277E+00 -0.1009 90 H2S,aq 0.72814E-13 -13.1378 0.72807E-13 -13.1378 0.99991E+00 0.0000 96 SO2,aq 0.11536E-19 -19.9379 0.11536E-19 -19.9379 0.10000E+01 0.0000 97 SO3-2 0.19388E-14 -14.7125 0.17322E-14 -14.7614 0.89341E+00 -0.0489 98 HSO3- 0.15560E-14 -14.8080 0.14924E-14 -14.8261 0.95914E+00 -0.0181 99 HSO4- 0.32222E-09 -9.4918 0.30908E-09 -9.5099 0.95920E+00 -0.0181 101 S2O3-2 0.21739E-19 -19.6628 0.19415E-19 -19.7119 0.89311E+00 -0.0491 Charge balance for all species = 0.2019E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1534708E-07 -.7360710E-04 -.7418859E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999586E+06 0.0000 3 Cl- 0.1379620E-03 0.1379758E-03 0.4891463E+01 3.9537 4 SO4-- 0.2533312E-04 0.2550467E-04 0.2449922E+01 11.0187 5 HCO3- 0.1259670E-04 0.1307016E-04 0.7974726E+00 2.9142 6 HS- 0.1716105E-11 0.1023278E-09 0.3384051E-05 -3.9515 7 Al+++ 0.3168426E-20 0.3236266E-05 0.8731584E-01 2.8961 8 H4SiO4 0.2642680E-03 0.2825921E-03 0.2716038E+02 -3.5780 9 Ca++ 0.2674161E-04 0.2707400E-04 0.1085029E+01 11.0421 10 Mg++ 0.9935519E-07 0.1019216E-06 0.2477819E-02 8.6121 11 Fe++ 0.5897232E-09 0.2314109E-08 0.1292309E-03 6.3855 12 K+ 0.7428269E-05 0.7431087E-05 0.2905588E+00 2.6848 13 Na+ 0.2039383E-03 0.2040070E-03 0.4689893E+01 4.1234 14 Mn++ 0.6814711E-07 0.8215625E-07 0.4513321E-02 8.4483 15 HPO4-- 0.2057645E-08 0.2552333E-08 0.2449606E-03 6.9284 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5665080E-03 -.7360622E-04 -.4929018E-03 0.0000000E+00 2 H2O 0.5550781E+02 0.5550762E+02 0.1931425E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2647444E-04 0.2550437E-04 0.9700716E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9699693E-06 0.1023266E-09 -.9700716E-06 0.0000000E+00 7 Al+++ 0.1141260E-03 0.3236227E-05 0.1108897E-03 0.0000000E+00 8 H4SiO4 0.3644474E-03 0.2825887E-03 0.8185865E-04 0.0000000E+00 9 Ca++ 0.5472605E-04 0.2707368E-04 0.2765238E-04 0.0000000E+00 10 Mg++ 0.2777778E-04 0.1019204E-06 0.2767586E-04 0.0000000E+00 11 Fe++ 0.2495530E-04 0.2314081E-08 0.2495299E-04 0.0000000E+00 12 K+ 0.7430998E-05 0.7430998E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2040045E-03 0.2040045E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6068509E-06 0.8215527E-07 0.5246956E-06 0.0000000E+00 15 HPO4-- 0.2071152E-06 0.2552303E-08 0.2045629E-06 0.0000000E+00 Chg. balance for solid moles: -.1442E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0350000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6819E-07 -7.166 0.3425E-04 -4.465 0.2000 0.1088E-04 clinochlore 0.5535E-05 -5.257 0.3077E-02 -2.512 17.96 0.1170E-02 daphnite 0.3438E-05 -5.464 0.2453E-02 -2.610 14.32 0.7435E-03 chlorite-Mn 0.1049E-06 -6.979 0.7440E-04 -4.128 0.4344 0.2371E-04 diaspore 0.3811E-04 -4.419 0.2286E-02 -2.641 13.35 0.6806E-03 hematite 0.3880E-05 -5.411 0.6197E-03 -3.208 3.618 0.1175E-03 lawsonite 0.2731E-04 -4.564 0.8582E-02 -2.066 50.11 0.2768E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3787E+00 0.3787E+00 1.0000 -0.422 chlorite-Mn 0.1156E-01 0.1156E-01 1.0000 -1.937 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.017127 g Volume = 0.005514 cm3 Porosity: 99.4562% V(tot) - V(min): 0.10085E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0350000 g log = -1.4559 Original solution: 1000.0103000 g Original solution / Rock added: 28571.72 (Water/Rock Ratio), log = 4.4559 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3874E-04 1.0073 0.4105E-04 0.4075E-04 CH4,gas 0.1280E-14 1.0129 0.1364E-14 0.1347E-14 H2,gas 0.7316E-06 1.0006 0.7701E-06 0.7697E-06 H2S,gas 0.2027E-11 0.9959 0.2123E-11 0.2132E-11 S2,gas 0.2707E-30 1.0000 0.2848E-30 0.2848E-30 CO,gas 0.7784E-14 1.0000 0.8189E-14 0.8189E-14 SO3,gas 0.1743E-35 1.0000 0.1833E-35 0.1833E-35 SO2,gas 0.5077E-19 1.0000 0.5341E-19 0.5341E-19 HCl,gas 0.6150E-15 1.0000 0.6470E-15 0.6470E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.75 -6.39 -2.129 0.10905E+05 -4.387 3 CH4,gas 4.81 -12.06 -16.87 -4.216 0.28797E+05 -14.865 4 H2,gas 8.29 0.17 -8.11 -4.636 0.13854E+05 -6.113 5 H2S,gas -5.94 -19.62 -13.67 -6.836 0.23346E+05 -11.673 6 S2,gas -7.03 -39.58 -32.55 -5.007 0.55571E+05 -30.545 7 CO,gas 3.51 -12.58 -16.09 -4.950 0.27468E+05 -14.087 8 SO3,gas 17.43 -20.31 -37.74 -9.434 0.64434E+05 -35.737 9 SO2,gas 1.14 -20.14 -21.27 -5.673 0.36322E+05 -19.272 10 HCl,gas 5.48 -11.71 -17.19 -8.595 0.29350E+05 -15.189 11 acmite 7.74 3.27 -4.47 -0.465 0.76343E+04 15 albite-high 0.75 -3.71 -4.46 -0.343 0.76222E+04 16 albite -0.33 -3.71 -3.39 -0.260 0.57815E+04 19 spessartine 24.55 20.40 -4.15 -0.207 0.70801E+04 20 analcite 3.37 -0.14 -3.51 -0.390 0.59882E+04 21 andalusite 5.06 2.21 -2.85 -0.285 0.48631E+04 22 andradite 39.09 34.99 -4.10 -0.213 0.69967E+04 23 grossular 32.83 28.18 -4.64 -0.232 0.79288E+04 24 anhydrite -5.28 -9.27 -3.99 -1.994 0.68087E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.71 -2.69 -0.898 0.45999E+04 36 brucite 12.58 8.61 -3.96 -0.793 0.67693E+04 37 calcite 0.83 -1.71 -2.54 -0.847 0.43386E+04 40 carpholite-Mg 8.65 7.25 -1.40 -0.093 0.23940E+04 41 carpholite-Fe 6.78 5.02 -1.76 -0.117 0.30070E+04 50 chloritoid-Mg 13.26 10.83 -2.43 -0.162 0.41576E+04 51 chloritoid-Fe 9.24 8.60 -0.64 -0.043 0.10909E+04 52 chloritoid-Mn 11.46 10.66 -0.80 -0.053 0.13671E+04 54 coesite -2.37 -3.58 -1.21 -0.403 0.20637E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.58 -1.03 -0.343 0.17565E+04 67 diopside 16.22 12.50 -3.72 -0.372 0.63470E+04 68 hedenbergite 14.24 10.27 -3.97 -0.397 0.67833E+04 75 epidote 24.78 23.44 -1.33 -0.065 0.22775E+04 76 clinozoisite 22.92 20.04 -2.88 -0.131 0.49218E+04 77 epidote-Fe 29.94 26.84 -3.09 -0.161 0.52807E+04 78 fayalite 14.08 9.19 -4.89 -0.698 0.83424E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.00 -4.19 -0.349 0.71603E+04 91 heulandite -5.71 -8.21 -2.50 -0.114 0.42760E+04 95 jadeite 4.25 -0.14 -4.39 -0.439 0.74912E+04 98 kaolinite -1.27 -1.36 -0.09 -0.008 0.15468E+03 99 kyanite 4.93 2.21 -2.72 -0.272 0.46399E+04 101 laumontite 2.97 2.52 -0.45 -0.030 0.77191E+03 105 lizardite 23.29 18.68 -4.61 -0.384 0.78666E+04 106 magnesite 0.71 -4.14 -4.85 -1.616 0.82763E+04 107 magnetite 20.13 18.98 -1.15 -0.094 0.19630E+04 113 margarite 17.45 15.47 -1.98 -0.079 0.33829E+04 116 microcline -2.43 -5.15 -2.72 -0.209 0.46463E+04 120 muscovite 2.68 0.64 -2.04 -0.120 0.34832E+04 121 paragonite 4.34 2.08 -2.26 -0.133 0.38569E+04 122 nepheline 8.38 3.44 -4.94 -0.705 0.84291E+04 136 prehnite 19.47 17.14 -2.32 -0.137 0.39678E+04 137 prehnite-Fe 22.59 20.55 -2.04 -0.123 0.34858E+04 138 pumpellyite-Fe 46.47 43.57 -2.90 -0.065 0.49583E+04 139 pumpellyite-Mg 49.19 45.79 -3.40 -0.076 0.58068E+04 145 pyroxmangite 7.42 4.87 -2.55 -0.509 0.43466E+04 146 pyrophyllite -6.10 -8.52 -2.42 -0.151 0.41348E+04 147 quartz -2.98 -3.58 -0.60 -0.199 0.10176E+04 152 rhodochrosite -0.96 -4.30 -3.34 -1.114 0.57081E+04 153 rhodonite 7.46 4.87 -2.59 -0.518 0.44259E+04 154 sanidine -1.22 -5.15 -3.93 -0.302 0.67141E+04 156 siderite -2.59 -6.36 -3.78 -1.259 0.64486E+04 157 sillimanite 5.32 2.21 -3.11 -0.311 0.53053E+04 164 stilbite -7.41 -8.21 -0.81 -0.038 0.13754E+04 165 stilpnomelane-Fe 13.18 10.44 -2.74 -0.082 0.46797E+04 168 sudoite-Fe 18.44 13.62 -4.82 -0.155 0.82223E+04 169 sudoite 21.22 18.07 -3.14 -0.101 0.53641E+04 175 tephroite 18.11 13.32 -4.79 -0.685 0.81859E+04 178 topaz-H 4.67 2.21 -2.45 -0.223 0.41890E+04 179 tridymite -2.61 -3.58 -0.96 -0.321 0.16449E+04 188 wairakite 4.06 2.52 -1.54 -0.090 0.26227E+04 189 walstromite 11.53 7.46 -4.06 -0.813 0.69387E+04 190 wollastonite 10.48 7.46 -3.02 -0.604 0.51526E+04 191 pseudo-wollastonite 11.02 7.46 -3.56 -0.711 0.60712E+04 192 zoisite 22.96 20.04 -2.93 -0.133 0.49944E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.56 -3.00 -0.186 0.51251E+04 195 beidellite-H -2.24 -6.38 -4.14 -0.264 0.70725E+04 196 beidellite-K -1.44 -5.50 -4.06 -0.249 0.69361E+04 197 beidellite-Mg -1.71 -4.96 -3.26 -0.201 0.55584E+04 198 beidellite-Na -1.26 -5.02 -3.77 -0.231 0.64294E+04 200 chalcedony -2.79 -3.58 -0.78 -0.261 0.13379E+04 202 montmorillonite-Ca -2.21 -4.81 -2.60 -0.161 0.44350E+04 203 montmorillonite-K -2.16 -5.75 -3.59 -0.220 0.61237E+04 204 montmorillonite-Mg -2.40 -5.21 -2.81 -0.174 0.47993E+04 205 montmorillonite-Na -1.96 -5.27 -3.31 -0.203 0.56552E+04 206 nontronite-Ca 3.28 2.24 -1.04 -0.067 0.17680E+04 207 nontronite-H 2.60 0.42 -2.17 -0.146 0.37112E+04 208 nontronite-K 3.40 1.31 -2.10 -0.135 0.35782E+04 209 nontronite-Mg 3.14 1.84 -1.30 -0.084 0.22129E+04 210 nontronite-Na 3.58 1.78 -1.80 -0.116 0.30732E+04 215 gypsum -4.92 -9.27 -4.34 -1.086 0.74155E+04 225 tobermorite 9.84 5.62 -4.22 -1.151 0.72036E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.39 -3.44 -0.860 0.58715E+04 241 silica-amorphous -2.08 -3.58 -1.50 -0.499 0.25581E+04 243 an20ab80 2.08 -1.04 -3.12 -0.240 0.53188E+04 244 an25ab75 2.71 -0.37 -3.08 -0.237 0.52511E+04 245 an30ab70 3.34 0.30 -3.04 -0.234 0.51916E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0350000 g New total amount of reactant added: 0.0360000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0360000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3004577E-03 Osmotic coef. = 0.9897 True ionic strength = .3169064E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15450E-07 -7.8111 0.14821E-07 -7.8291 0.95930E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13233E-03 -3.8783 0.95916E+00 -0.0181 4 SO4-- 0.25338E-04 -4.5962 0.22633E-04 -4.6453 0.89326E+00 -0.0490 5 HCO3- 0.12596E-04 -4.8998 0.12082E-04 -4.9179 0.95920E+00 -0.0181 6 HS- 0.15622E-11 -11.8063 0.14984E-11 -11.8244 0.95917E+00 -0.0181 7 Al+++ 0.32318E-20 -20.4906 0.25627E-20 -20.5913 0.79297E+00 -0.1007 8 H4SiO4 0.26984E-03 -3.5689 0.26984E-03 -3.5689 0.10000E+01 0.0000 9 Ca++ 0.25991E-04 -4.5852 0.23213E-04 -4.6343 0.89311E+00 -0.0491 10 Mg++ 0.99428E-07 -7.0025 0.88790E-07 -7.0516 0.89301E+00 -0.0491 11 Fe++ 0.59010E-09 -9.2291 0.52698E-09 -9.2782 0.89303E+00 -0.0491 12 K+ 0.76405E-05 -5.1169 0.73288E-05 -5.1350 0.95920E+00 -0.0181 13 Na+ 0.20519E-03 -3.6878 0.19681E-03 -3.7059 0.95916E+00 -0.0181 14 Mn++ 0.68452E-07 -7.1646 0.61131E-07 -7.2137 0.89305E+00 -0.0491 15 HPO4-- 0.21762E-08 -8.6623 0.19439E-08 -8.7113 0.89326E+00 -0.0490 16 HSiO3- 0.18520E-04 -4.7324 0.17764E-04 -4.7505 0.95916E+00 -0.0181 17 Ca(HSiO3)+ 0.96317E-08 -8.0163 0.92388E-08 -8.0344 0.95921E+00 -0.0181 18 Mg(HSiO3)+ 0.45850E-10 -10.3387 0.43979E-10 -10.3568 0.95921E+00 -0.0181 19 NaHSiO3,aq 0.55527E-07 -7.2555 0.55527E-07 -7.2555 0.10000E+01 0.0000 20 AlO+ 0.15702E-11 -11.8040 0.15062E-11 -11.8221 0.95921E+00 -0.0181 21 AlOH+2 0.12521E-15 -15.9024 0.11182E-15 -15.9515 0.89307E+00 -0.0491 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.31944E-05 -5.4956 0.30638E-05 -5.5137 0.95912E+00 -0.0181 24 CH4,aq 0.78496E-18 -18.1052 0.78489E-18 -18.1052 0.99991E+00 0.0000 29 CO,aq 0.50907E-17 -17.2932 0.50907E-17 -17.2932 0.10000E+01 0.0000 30 CO2,aq 0.36106E-06 -6.4424 0.36103E-06 -6.4425 0.99991E+00 0.0000 31 CO3-2 0.84385E-07 -7.0737 0.75373E-07 -7.1228 0.89321E+00 -0.0490 32 CaCO3,aq 0.21429E-07 -7.6690 0.21429E-07 -7.6690 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.73672E-08 -8.1327 0.70667E-08 -8.1508 0.95921E+00 -0.0181 34 CaCl+ 0.51030E-08 -8.2922 0.48948E-08 -8.3103 0.95921E+00 -0.0181 35 CaCl2,aq 0.15081E-12 -12.8216 0.15081E-12 -12.8216 0.10000E+01 0.0000 36 CaOH+ 0.11514E-06 -6.9388 0.11044E-06 -6.9569 0.95921E+00 -0.0181 37 CaSO4,aq 0.16370E-06 -6.7860 0.16370E-06 -6.7860 0.10000E+01 0.0000 38 HCl,aq 0.36890E-12 -12.4331 0.36890E-12 -12.4331 0.10000E+01 0.0000 43 FeCl+ 0.11323E-12 -12.9460 0.10861E-12 -12.9641 0.95921E+00 -0.0181 46 FeO,aq 0.94872E-10 -10.0229 0.94872E-10 -10.0229 0.10000E+01 0.0000 47 FeOH+ 0.12289E-08 -8.9105 0.11788E-08 -8.9286 0.95921E+00 -0.0181 48 HFeO2- 0.71784E-10 -10.1440 0.68852E-10 -10.1621 0.95916E+00 -0.0181 49 FeO+ 0.12781E-12 -12.8934 0.12260E-12 -12.9115 0.95921E+00 -0.0181 50 FeOH+2 0.37859E-18 -18.4218 0.33811E-18 -18.4709 0.89307E+00 -0.0491 51 FeO2- 0.11437E-09 -9.9417 0.10970E-09 -9.9598 0.95916E+00 -0.0181 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.54753E-09 -9.2616 0.54748E-09 -9.2616 0.99991E+00 0.0000 54 KCl,aq 0.17172E-10 -10.7652 0.17172E-10 -10.7652 0.10000E+01 0.0000 55 KHSO4,aq 0.65785E-17 -17.1819 0.65785E-17 -17.1819 0.10000E+01 0.0000 56 KOH,aq 0.21557E-09 -9.6664 0.21557E-09 -9.6664 0.10000E+01 0.0000 57 KSO4- 0.26643E-08 -8.5744 0.25555E-08 -8.5925 0.95916E+00 -0.0181 58 MgCO3,aq 0.20482E-10 -10.6886 0.20482E-10 -10.6886 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28736E-10 -10.5416 0.27564E-10 -10.5597 0.95921E+00 -0.0181 60 MgCl+ 0.17720E-10 -10.7515 0.16997E-10 -10.7696 0.95921E+00 -0.0181 61 MgOH+ 0.24399E-08 -8.6126 0.23403E-08 -8.6307 0.95921E+00 -0.0181 63 MnO,aq 0.29379E-09 -9.5320 0.29379E-09 -9.5320 0.10000E+01 0.0000 64 MnOH+ 0.13243E-07 -7.8780 0.12703E-07 -7.8961 0.95921E+00 -0.0181 65 MnO2-2 0.51786E-16 -16.2858 0.46256E-16 -16.3348 0.89321E+00 -0.0490 66 HMnO2- 0.15486E-12 -12.8101 0.14853E-12 -12.8282 0.95916E+00 -0.0181 69 MnCl+ 0.51041E-10 -10.2921 0.48959E-10 -10.3102 0.95921E+00 -0.0181 70 MnSO4,aq 0.39211E-09 -9.4066 0.39211E-09 -9.4066 0.10000E+01 0.0000 71 NaCl,aq 0.85040E-08 -8.0704 0.85040E-08 -8.0704 0.10000E+01 0.0000 72 NaOH,aq 0.58351E-08 -8.2339 0.58351E-08 -8.2339 0.10000E+01 0.0000 74 OH- 0.42198E-04 -4.3747 0.40473E-04 -4.3928 0.95912E+00 -0.0181 82 H3PO4,aq 0.27490E-14 -14.5608 0.27490E-14 -14.5608 0.10000E+01 0.0000 83 H2PO4- 0.52660E-09 -9.2785 0.50511E-09 -9.2966 0.95918E+00 -0.0181 84 PO4-3 0.14429E-12 -12.8408 0.11455E-12 -12.9410 0.79388E+00 -0.1002 87 H2P2O7-2 0.22355E-19 -19.6506 0.19968E-19 -19.6997 0.89321E+00 -0.0490 88 HP2O7-3 0.34840E-18 -18.4579 0.27627E-18 -18.5587 0.79298E+00 -0.1007 90 H2S,aq 0.66730E-13 -13.1757 0.66724E-13 -13.1757 0.99991E+00 0.0000 96 SO2,aq 0.11403E-19 -19.9430 0.11403E-19 -19.9430 0.10000E+01 0.0000 97 SO3-2 0.18909E-14 -14.7233 0.16895E-14 -14.7722 0.89352E+00 -0.0489 98 HSO3- 0.15278E-14 -14.8159 0.14654E-14 -14.8340 0.95916E+00 -0.0181 99 HSO4- 0.32447E-09 -9.4888 0.31124E-09 -9.5069 0.95923E+00 -0.0181 101 S2O3-2 0.19926E-19 -19.7006 0.17798E-19 -19.7496 0.89321E+00 -0.0490 Charge balance for all species = 0.2020E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1544955E-07 -.7348989E-04 -.7407042E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999580E+06 0.0000 3 Cl- 0.1379622E-03 0.1379759E-03 0.4891461E+01 3.9508 4 SO4-- 0.2533770E-04 0.2550468E-04 0.2449922E+01 11.0130 5 HCO3- 0.1259587E-04 0.1307016E-04 0.7974724E+00 2.9113 6 HS- 0.1562204E-11 0.9876684E-10 0.3266285E-05 -3.9952 7 Al+++ 0.3231758E-20 0.3214754E-05 0.8673538E-01 2.8961 8 H4SiO4 0.2698370E-03 0.2884222E-03 0.2772070E+02 -3.5689 9 Ca++ 0.2599134E-04 0.2631371E-04 0.1054558E+01 11.0240 10 Mg++ 0.9942781E-07 0.1019805E-06 0.2479249E-02 8.6066 11 Fe++ 0.5900994E-09 0.2303765E-08 0.1286532E-03 6.3801 12 K+ 0.7640508E-05 0.7643405E-05 0.2988604E+00 2.6942 13 Na+ 0.2051924E-03 0.2052623E-03 0.4718749E+01 4.1232 14 Mn++ 0.6845181E-07 0.8243218E-07 0.4528477E-02 8.4445 15 HPO4-- 0.2176236E-08 0.2702987E-08 0.2594195E-03 6.9469 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5830666E-03 -.7348900E-04 -.5095776E-03 0.0000000E+00 2 H2O 0.5550780E+02 0.5550760E+02 0.1966498E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2650215E-04 0.2550437E-04 0.9977815E-06 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9976827E-06 0.9876563E-10 -.9977815E-06 0.0000000E+00 7 Al+++ 0.1173867E-03 0.3214714E-05 0.1141720E-03 0.0000000E+00 8 H4SiO4 0.3748602E-03 0.2884187E-03 0.8644150E-04 0.0000000E+00 9 Ca++ 0.5587620E-04 0.2631339E-04 0.2956281E-04 0.0000000E+00 10 Mg++ 0.2857143E-04 0.1019792E-06 0.2846945E-04 0.0000000E+00 11 Fe++ 0.2566831E-04 0.2303737E-08 0.2566601E-04 0.0000000E+00 12 K+ 0.7643312E-05 0.7643312E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2052598E-03 0.2052598E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6241895E-06 0.8243117E-07 0.5417583E-06 0.0000000E+00 15 HPO4-- 0.2130328E-06 0.2702954E-08 0.2103298E-06 0.0000000E+00 Chg. balance for solid moles: -.3277E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0360000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7011E-07 -7.154 0.3522E-04 -4.453 0.1974 0.1119E-04 clinochlore 0.5694E-05 -5.245 0.3165E-02 -2.500 17.74 0.1204E-02 daphnite 0.3537E-05 -5.451 0.2524E-02 -2.598 14.14 0.7647E-03 chlorite-Mn 0.1084E-06 -6.965 0.7682E-04 -4.115 0.4306 0.2448E-04 diaspore 0.3707E-04 -4.431 0.2224E-02 -2.653 12.46 0.6620E-03 hematite 0.3991E-05 -5.399 0.6374E-03 -3.196 3.573 0.1208E-03 lawsonite 0.2921E-04 -4.534 0.9180E-02 -2.037 51.45 0.2960E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3787E+00 0.3787E+00 1.0000 -0.422 chlorite-Mn 0.1160E-01 0.1160E-01 1.0000 -1.935 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.017841 g Volume = 0.005747 cm3 Porosity: 99.4334% V(tot) - V(min): 0.10087E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0360000 g log = -1.4437 Original solution: 1000.0103000 g Original solution / Rock added: 27778.06 (Water/Rock Ratio), log = 4.4437 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3900E-04 1.0073 0.4133E-04 0.4103E-04 CH4,gas 0.1165E-14 1.0129 0.1241E-14 0.1225E-14 H2,gas 0.7134E-06 1.0006 0.7509E-06 0.7505E-06 H2S,gas 0.1857E-11 0.9959 0.1946E-11 0.1954E-11 S2,gas 0.2391E-30 1.0000 0.2516E-30 0.2516E-30 CO,gas 0.7641E-14 1.0000 0.8038E-14 0.8038E-14 SO3,gas 0.1767E-35 1.0000 0.1859E-35 0.1859E-35 SO2,gas 0.5019E-19 1.0000 0.5280E-19 0.5280E-19 HCl,gas 0.6192E-15 1.0000 0.6514E-15 0.6514E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.83410E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.75 -6.38 -2.128 0.10900E+05 -4.384 3 CH4,gas 4.81 -12.10 -16.91 -4.227 0.28867E+05 -14.906 4 H2,gas 8.29 0.16 -8.12 -4.643 0.13872E+05 -6.124 5 H2S,gas -5.94 -19.65 -13.71 -6.855 0.23411E+05 -11.711 6 S2,gas -7.03 -39.63 -32.60 -5.015 0.55663E+05 -30.599 7 CO,gas 3.51 -12.58 -16.09 -4.952 0.27482E+05 -14.095 8 SO3,gas 17.43 -20.30 -37.73 -9.433 0.64424E+05 -35.731 9 SO2,gas 1.14 -20.14 -21.28 -5.674 0.36331E+05 -19.277 10 HCl,gas 5.48 -11.71 -17.19 -8.593 0.29345E+05 -15.186 11 acmite 7.74 3.28 -4.45 -0.463 0.76037E+04 15 albite-high 0.75 -3.69 -4.44 -0.341 0.75762E+04 16 albite -0.33 -3.69 -3.36 -0.258 0.57355E+04 19 spessartine 24.55 20.42 -4.13 -0.207 0.70533E+04 20 analcite 3.37 -0.12 -3.49 -0.388 0.59576E+04 21 andalusite 5.06 2.22 -2.84 -0.284 0.48477E+04 22 andradite 39.09 34.96 -4.12 -0.214 0.70431E+04 23 grossular 32.83 28.16 -4.67 -0.234 0.79752E+04 24 anhydrite -5.28 -9.28 -4.00 -2.000 0.68295E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.72 -2.71 -0.903 0.46259E+04 36 brucite 12.58 8.61 -3.97 -0.794 0.67786E+04 37 calcite 0.83 -1.72 -2.56 -0.852 0.43646E+04 40 carpholite-Mg 8.65 7.26 -1.39 -0.093 0.23723E+04 41 carpholite-Fe 6.78 5.03 -1.75 -0.117 0.29854E+04 50 chloritoid-Mg 13.26 10.83 -2.43 -0.162 0.41514E+04 51 chloritoid-Fe 9.24 8.60 -0.64 -0.042 0.10848E+04 52 chloritoid-Mn 11.46 10.67 -0.80 -0.053 0.13581E+04 54 coesite -2.37 -3.57 -1.20 -0.400 0.20482E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.57 -1.02 -0.340 0.17411E+04 67 diopside 16.22 12.49 -3.72 -0.372 0.63563E+04 68 hedenbergite 14.24 10.27 -3.98 -0.398 0.67926E+04 75 epidote 24.78 23.43 -1.34 -0.065 0.22930E+04 76 clinozoisite 22.92 20.03 -2.89 -0.131 0.49373E+04 77 epidote-Fe 29.94 26.83 -3.10 -0.161 0.52962E+04 78 fayalite 14.08 9.19 -4.89 -0.698 0.83457E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.00 -4.19 -0.349 0.71575E+04 91 heulandite -5.71 -8.17 -2.46 -0.112 0.41987E+04 95 jadeite 4.25 -0.12 -4.37 -0.437 0.74607E+04 98 kaolinite -1.27 -1.35 -0.07 -0.007 0.12375E+03 99 kyanite 4.93 2.22 -2.71 -0.271 0.46245E+04 101 laumontite 2.97 2.54 -0.43 -0.029 0.74099E+03 105 lizardite 23.29 18.68 -4.61 -0.384 0.78635E+04 106 magnesite 0.71 -4.14 -4.85 -1.617 0.82807E+04 107 magnetite 20.13 18.98 -1.16 -0.094 0.19723E+04 113 margarite 17.45 15.47 -1.98 -0.079 0.33829E+04 116 microcline -2.43 -5.12 -2.68 -0.207 0.45840E+04 120 muscovite 2.68 0.68 -2.00 -0.118 0.34209E+04 121 paragonite 4.34 2.10 -2.23 -0.131 0.38109E+04 122 nepheline 8.38 3.45 -4.93 -0.704 0.84140E+04 136 prehnite 19.47 17.13 -2.33 -0.137 0.39833E+04 137 prehnite-Fe 22.59 20.54 -2.05 -0.123 0.35013E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.49986E+04 139 pumpellyite-Mg 49.19 45.77 -3.42 -0.076 0.58471E+04 145 pyroxmangite 7.42 4.88 -2.54 -0.508 0.43377E+04 146 pyrophyllite -6.10 -8.48 -2.39 -0.149 0.40730E+04 147 quartz -2.98 -3.57 -0.59 -0.196 0.10021E+04 152 rhodochrosite -0.96 -4.30 -3.34 -1.115 0.57097E+04 153 rhodonite 7.46 4.88 -2.59 -0.517 0.44169E+04 154 sanidine -1.22 -5.12 -3.90 -0.300 0.66517E+04 156 siderite -2.59 -6.37 -3.78 -1.260 0.64530E+04 157 sillimanite 5.32 2.22 -3.10 -0.310 0.52899E+04 164 stilbite -7.41 -8.17 -0.76 -0.036 0.12981E+04 165 stilpnomelane-Fe 13.18 10.49 -2.69 -0.080 0.45948E+04 168 sudoite-Fe 18.44 13.64 -4.80 -0.155 0.81946E+04 169 sudoite 21.22 18.09 -3.13 -0.101 0.53363E+04 175 tephroite 18.11 13.32 -4.79 -0.685 0.81835E+04 178 topaz-H 4.67 2.22 -2.44 -0.222 0.41735E+04 179 tridymite -2.61 -3.57 -0.95 -0.318 0.16294E+04 188 wairakite 4.06 2.54 -1.52 -0.089 0.25918E+04 189 walstromite 11.53 7.46 -4.07 -0.815 0.69542E+04 190 wollastonite 10.48 7.46 -3.03 -0.605 0.51680E+04 191 pseudo-wollastonite 11.02 7.46 -3.56 -0.713 0.60867E+04 192 zoisite 22.96 20.03 -2.93 -0.133 0.50099E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.53 -2.97 -0.184 0.50735E+04 195 beidellite-H -2.24 -6.35 -4.11 -0.262 0.70158E+04 196 beidellite-K -1.44 -5.46 -4.03 -0.247 0.68741E+04 197 beidellite-Mg -1.71 -4.93 -3.22 -0.199 0.55032E+04 198 beidellite-Na -1.26 -4.99 -3.73 -0.229 0.63728E+04 200 chalcedony -2.79 -3.57 -0.77 -0.258 0.13224E+04 202 montmorillonite-Ca -2.21 -4.78 -2.57 -0.159 0.43813E+04 203 montmorillonite-K -2.16 -5.71 -3.55 -0.217 0.60596E+04 204 montmorillonite-Mg -2.40 -5.18 -2.78 -0.172 0.47420E+04 205 montmorillonite-Na -1.96 -5.24 -3.28 -0.201 0.55965E+04 206 nontronite-Ca 3.28 2.27 -1.01 -0.065 0.17164E+04 207 nontronite-H 2.60 0.46 -2.14 -0.143 0.36544E+04 208 nontronite-K 3.40 1.34 -2.06 -0.132 0.35162E+04 209 nontronite-Mg 3.14 1.88 -1.26 -0.082 0.21577E+04 210 nontronite-Na 3.58 1.82 -1.77 -0.113 0.30166E+04 215 gypsum -4.92 -9.28 -4.36 -1.089 0.74363E+04 225 tobermorite 9.84 5.61 -4.22 -1.153 0.72139E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.38 -3.44 -0.861 0.58808E+04 241 silica-amorphous -2.08 -3.57 -1.49 -0.496 0.25426E+04 243 an20ab80 2.08 -1.01 -3.09 -0.238 0.52820E+04 244 an25ab75 2.71 -0.35 -3.06 -0.235 0.52166E+04 245 an30ab70 3.34 0.32 -3.02 -0.232 0.51594E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0360000 g New total amount of reactant added: 0.0370000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0370000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2996123E-03 Osmotic coef. = 0.9897 True ionic strength = .3161666E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15545E-07 -7.8084 0.14913E-07 -7.8264 0.95932E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13233E-03 -3.8783 0.95919E+00 -0.0181 4 SO4-- 0.25342E-04 -4.5962 0.22640E-04 -4.6451 0.89335E+00 -0.0490 5 HCO3- 0.12595E-04 -4.8998 0.12082E-04 -4.9179 0.95922E+00 -0.0181 6 HS- 0.14238E-11 -11.8466 0.13657E-11 -11.8647 0.95919E+00 -0.0181 7 Al+++ 0.32918E-20 -20.4826 0.26109E-20 -20.5832 0.79316E+00 -0.1006 8 H4SiO4 0.27543E-03 -3.5600 0.27543E-03 -3.5600 0.10000E+01 0.0000 9 Ca++ 0.25256E-04 -4.5976 0.22559E-04 -4.6467 0.89320E+00 -0.0491 10 Mg++ 0.99428E-07 -7.0025 0.88800E-07 -7.0516 0.89311E+00 -0.0491 11 Fe++ 0.59005E-09 -9.2291 0.52699E-09 -9.2782 0.89313E+00 -0.0491 12 K+ 0.78527E-05 -5.1050 0.75326E-05 -5.1231 0.95923E+00 -0.0181 13 Na+ 0.20645E-03 -3.6852 0.19802E-03 -3.7033 0.95919E+00 -0.0181 14 Mn++ 0.68701E-07 -7.1630 0.61360E-07 -7.2121 0.89315E+00 -0.0491 15 HPO4-- 0.23012E-08 -8.6380 0.20558E-08 -8.6870 0.89336E+00 -0.0490 16 HSiO3- 0.18786E-04 -4.7262 0.18020E-04 -4.7443 0.95919E+00 -0.0181 17 Ca(HSiO3)+ 0.94947E-08 -8.0225 0.91076E-08 -8.0406 0.95923E+00 -0.0181 18 Mg(HSiO3)+ 0.46514E-10 -10.3324 0.44618E-10 -10.3505 0.95923E+00 -0.0181 19 NaHSiO3,aq 0.56672E-07 -7.2466 0.56672E-07 -7.2466 0.10000E+01 0.0000 20 AlO+ 0.15800E-11 -11.8014 0.15155E-11 -11.8194 0.95923E+00 -0.0181 21 AlOH+2 0.12676E-15 -15.8970 0.11322E-15 -15.9461 0.89317E+00 -0.0491 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.31745E-05 -5.4983 0.30449E-05 -5.5164 0.95915E+00 -0.0181 24 CH4,aq 0.71520E-18 -18.1456 0.71513E-18 -18.1456 0.99991E+00 0.0000 29 CO,aq 0.49967E-17 -17.3013 0.49967E-17 -17.3013 0.10000E+01 0.0000 30 CO2,aq 0.36330E-06 -6.4397 0.36327E-06 -6.4398 0.99991E+00 0.0000 31 CO3-2 0.83850E-07 -7.0765 0.74904E-07 -7.1255 0.89331E+00 -0.0490 32 CaCO3,aq 0.20695E-07 -7.6841 0.20695E-07 -7.6841 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.71591E-08 -8.1451 0.68672E-08 -8.1632 0.95923E+00 -0.0181 34 CaCl+ 0.49591E-08 -8.3046 0.47569E-08 -8.3227 0.95923E+00 -0.0181 35 CaCl2,aq 0.14657E-12 -12.8340 0.14657E-12 -12.8340 0.10000E+01 0.0000 36 CaOH+ 0.11120E-06 -6.9539 0.10666E-06 -6.9720 0.95923E+00 -0.0181 37 CaSO4,aq 0.15913E-06 -6.7983 0.15913E-06 -6.7983 0.10000E+01 0.0000 38 HCl,aq 0.37121E-12 -12.4304 0.37121E-12 -12.4304 0.10000E+01 0.0000 43 FeCl+ 0.11323E-12 -12.9460 0.10862E-12 -12.9641 0.95923E+00 -0.0181 46 FeO,aq 0.93702E-10 -10.0283 0.93702E-10 -10.0283 0.10000E+01 0.0000 47 FeOH+ 0.12213E-08 -8.9132 0.11715E-08 -8.9312 0.95923E+00 -0.0181 48 HFeO2- 0.70457E-10 -10.1521 0.67582E-10 -10.1702 0.95919E+00 -0.0181 49 FeO+ 0.12861E-12 -12.8907 0.12336E-12 -12.9088 0.95923E+00 -0.0181 50 FeOH+2 0.38329E-18 -18.4165 0.34234E-18 -18.4655 0.89317E+00 -0.0491 51 FeO2- 0.11366E-09 -9.9444 0.10902E-09 -9.9625 0.95919E+00 -0.0181 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.53411E-09 -9.2724 0.53406E-09 -9.2724 0.99991E+00 0.0000 54 KCl,aq 0.17650E-10 -10.7533 0.17650E-10 -10.7533 0.10000E+01 0.0000 55 KHSO4,aq 0.68055E-17 -17.1671 0.68055E-17 -17.1671 0.10000E+01 0.0000 56 KOH,aq 0.22020E-09 -9.6572 0.22020E-09 -9.6572 0.10000E+01 0.0000 57 KSO4- 0.27391E-08 -8.5624 0.26273E-08 -8.5805 0.95919E+00 -0.0181 58 MgCO3,aq 0.20356E-10 -10.6913 0.20356E-10 -10.6913 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28737E-10 -10.5416 0.27566E-10 -10.5596 0.95923E+00 -0.0181 60 MgCl+ 0.17722E-10 -10.7515 0.16999E-10 -10.7696 0.95923E+00 -0.0181 61 MgOH+ 0.24250E-08 -8.6153 0.23261E-08 -8.6334 0.95923E+00 -0.0181 63 MnO,aq 0.29125E-09 -9.5357 0.29125E-09 -9.5357 0.10000E+01 0.0000 64 MnOH+ 0.13210E-07 -7.8791 0.12672E-07 -7.8972 0.95923E+00 -0.0181 65 MnO2-2 0.50698E-16 -16.2950 0.45289E-16 -16.3440 0.89331E+00 -0.0490 66 HMnO2- 0.15256E-12 -12.8166 0.14633E-12 -12.8347 0.95919E+00 -0.0181 69 MnCl+ 0.51232E-10 -10.2905 0.49143E-10 -10.3085 0.95923E+00 -0.0181 70 MnSO4,aq 0.39369E-09 -9.4048 0.39369E-09 -9.4048 0.10000E+01 0.0000 71 NaCl,aq 0.85564E-08 -8.0677 0.85564E-08 -8.0677 0.10000E+01 0.0000 72 NaOH,aq 0.58346E-08 -8.2340 0.58346E-08 -8.2340 0.10000E+01 0.0000 74 OH- 0.41935E-04 -4.3774 0.40222E-04 -4.3955 0.95915E+00 -0.0181 82 H3PO4,aq 0.29435E-14 -14.5311 0.29435E-14 -14.5311 0.10000E+01 0.0000 83 H2PO4- 0.56036E-09 -9.2515 0.53751E-09 -9.2696 0.95921E+00 -0.0181 84 PO4-3 0.15161E-12 -12.8193 0.12039E-12 -12.9194 0.79408E+00 -0.1001 87 H2P2O7-2 0.25312E-19 -19.5967 0.22612E-19 -19.6457 0.89331E+00 -0.0490 88 HP2O7-3 0.39198E-18 -18.4067 0.31091E-18 -18.5074 0.79317E+00 -0.1006 90 H2S,aq 0.61198E-13 -13.2133 0.61193E-13 -13.2133 0.99991E+00 0.0000 96 SO2,aq 0.11266E-19 -19.9482 0.11266E-19 -19.9482 0.10000E+01 0.0000 97 SO3-2 0.18449E-14 -14.7340 0.16486E-14 -14.7829 0.89361E+00 -0.0489 98 HSO3- 0.15000E-14 -14.8239 0.14388E-14 -14.8420 0.95919E+00 -0.0181 99 HSO4- 0.32658E-09 -9.4860 0.31327E-09 -9.5041 0.95925E+00 -0.0181 101 S2O3-2 0.18277E-19 -19.7381 0.16327E-19 -19.7871 0.89331E+00 -0.0490 Charge balance for all species = 0.2020E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1554546E-07 -.7340737E-04 -.7398720E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999575E+06 0.0000 3 Cl- 0.1379623E-03 0.1379759E-03 0.4891460E+01 3.9481 4 SO4-- 0.2534220E-04 0.2550469E-04 0.2449922E+01 11.0077 5 HCO3- 0.1259511E-04 0.1307016E-04 0.7974722E+00 2.9086 6 HS- 0.1423778E-11 0.9535683E-10 0.3153512E-05 -4.0382 7 Al+++ 0.3291780E-20 0.3194875E-05 0.8619900E-01 2.8961 8 H4SiO4 0.2754298E-03 0.2942823E-03 0.2828390E+02 -3.5600 9 Ca++ 0.2525581E-04 0.2556844E-04 0.1024690E+01 11.0062 10 Mg++ 0.9942834E-07 0.1019666E-06 0.2478911E-02 8.6013 11 Fe++ 0.5900492E-09 0.2292889E-08 0.1280458E-03 6.3747 12 K+ 0.7852747E-05 0.7855724E-05 0.3071620E+00 2.7034 13 Na+ 0.2064465E-03 0.2065176E-03 0.4747604E+01 4.1231 14 Mn++ 0.6870059E-07 0.8264703E-07 0.4540277E-02 8.4407 15 HPO4-- 0.2301224E-08 0.2861743E-08 0.2746560E-03 6.9658 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5996251E-03 -.7340645E-04 -.5262186E-03 0.0000000E+00 2 H2O 0.5550779E+02 0.5550759E+02 0.2001839E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2652987E-04 0.2550437E-04 0.1025491E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1025396E-05 0.9535564E-10 -.1025491E-05 0.0000000E+00 7 Al+++ 0.1206474E-03 0.3194835E-05 0.1174526E-03 0.0000000E+00 8 H4SiO4 0.3852730E-03 0.2942786E-03 0.9099439E-04 0.0000000E+00 9 Ca++ 0.5702634E-04 0.2556812E-04 0.3145822E-04 0.0000000E+00 10 Mg++ 0.2936508E-04 0.1019654E-06 0.2926311E-04 0.0000000E+00 11 Fe++ 0.2638132E-04 0.2292861E-08 0.2637903E-04 0.0000000E+00 12 K+ 0.7855626E-05 0.7855626E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2065150E-03 0.2065150E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6415281E-06 0.8264600E-07 0.5588820E-06 0.0000000E+00 15 HPO4-- 0.2189503E-06 0.2861707E-08 0.2160886E-06 0.0000000E+00 Chg. balance for solid moles: 0.3187E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0370000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7203E-07 -7.142 0.3618E-04 -4.442 0.1950 0.1150E-04 clinochlore 0.5853E-05 -5.233 0.3253E-02 -2.488 17.53 0.1237E-02 daphnite 0.3635E-05 -5.439 0.2594E-02 -2.586 13.98 0.7859E-03 chlorite-Mn 0.1118E-06 -6.952 0.7925E-04 -4.101 0.4271 0.2525E-04 diaspore 0.3606E-04 -4.443 0.2163E-02 -2.665 11.66 0.6440E-03 hematite 0.4102E-05 -5.387 0.6551E-03 -3.184 3.531 0.1242E-03 lawsonite 0.3110E-04 -4.507 0.9772E-02 -2.010 52.67 0.3151E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3787E+00 0.3787E+00 1.0000 -0.422 chlorite-Mn 0.1164E-01 0.1164E-01 1.0000 -1.934 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.018553 g Volume = 0.005980 cm3 Porosity: 99.4108% V(tot) - V(min): 0.10088E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0370000 g log = -1.4318 Original solution: 1000.0103000 g Original solution / Rock added: 27027.31 (Water/Rock Ratio), log = 4.4318 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3924E-04 1.0073 0.4158E-04 0.4128E-04 CH4,gas 0.1061E-14 1.0129 0.1131E-14 0.1116E-14 H2,gas 0.6959E-06 1.0006 0.7325E-06 0.7321E-06 H2S,gas 0.1704E-11 0.9959 0.1785E-11 0.1792E-11 S2,gas 0.2114E-30 1.0000 0.2223E-30 0.2223E-30 CO,gas 0.7500E-14 1.0000 0.7890E-14 0.7890E-14 SO3,gas 0.1789E-35 1.0000 0.1882E-35 0.1882E-35 SO2,gas 0.4958E-19 1.0000 0.5216E-19 0.5216E-19 HCl,gas 0.6231E-15 1.0000 0.6554E-15 0.6554E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.74 -6.38 -2.127 0.10896E+05 -4.381 3 CH4,gas 4.81 -12.14 -16.95 -4.237 0.28936E+05 -14.947 4 H2,gas 8.29 0.15 -8.14 -4.649 0.13891E+05 -6.135 5 H2S,gas -5.94 -19.69 -13.75 -6.874 0.23475E+05 -11.748 6 S2,gas -7.03 -39.69 -32.65 -5.024 0.55754E+05 -30.653 7 CO,gas 3.51 -12.59 -16.10 -4.955 0.27495E+05 -14.103 8 SO3,gas 17.43 -20.30 -37.73 -9.431 0.64415E+05 -35.725 9 SO2,gas 1.14 -20.15 -21.28 -5.675 0.36340E+05 -19.283 10 HCl,gas 5.48 -11.70 -17.18 -8.592 0.29340E+05 -15.183 11 acmite 7.74 3.30 -4.44 -0.461 0.75734E+04 15 albite-high 0.75 -3.66 -4.41 -0.339 0.75306E+04 16 albite -0.33 -3.66 -3.33 -0.256 0.56899E+04 19 spessartine 24.55 20.43 -4.12 -0.206 0.70270E+04 20 analcite 3.37 -0.10 -3.47 -0.386 0.59273E+04 21 andalusite 5.06 2.23 -2.83 -0.283 0.48325E+04 22 andradite 39.09 34.94 -4.15 -0.216 0.70887E+04 23 grossular 32.83 28.13 -4.70 -0.235 0.80208E+04 24 anhydrite -5.28 -9.29 -4.01 -2.006 0.68505E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.74 -2.72 -0.908 0.46518E+04 36 brucite 12.58 8.60 -3.98 -0.795 0.67878E+04 37 calcite 0.83 -1.74 -2.57 -0.857 0.43904E+04 40 carpholite-Mg 8.65 7.27 -1.38 -0.092 0.23510E+04 41 carpholite-Fe 6.78 5.05 -1.74 -0.116 0.29642E+04 50 chloritoid-Mg 13.26 10.83 -2.43 -0.162 0.41454E+04 51 chloritoid-Fe 9.24 8.61 -0.63 -0.042 0.10788E+04 52 chloritoid-Mn 11.46 10.67 -0.79 -0.053 0.13494E+04 54 coesite -2.37 -3.56 -1.19 -0.397 0.20330E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.56 -1.01 -0.337 0.17259E+04 67 diopside 16.22 12.49 -3.73 -0.373 0.63655E+04 68 hedenbergite 14.24 10.26 -3.98 -0.398 0.68018E+04 75 epidote 24.78 23.42 -1.35 -0.066 0.23082E+04 76 clinozoisite 22.92 20.02 -2.90 -0.132 0.49525E+04 77 epidote-Fe 29.94 26.83 -3.11 -0.162 0.53114E+04 78 fayalite 14.08 9.19 -4.89 -0.699 0.83489E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.00 -4.19 -0.349 0.71546E+04 91 heulandite -5.71 -8.12 -2.41 -0.110 0.41226E+04 95 jadeite 4.25 -0.10 -4.35 -0.435 0.74303E+04 98 kaolinite -1.27 -1.33 -0.05 -0.005 0.93328E+02 99 kyanite 4.93 2.23 -2.70 -0.270 0.46092E+04 101 laumontite 2.97 2.56 -0.42 -0.028 0.71056E+03 105 lizardite 23.29 18.68 -4.60 -0.384 0.78605E+04 106 magnesite 0.71 -4.14 -4.85 -1.617 0.82852E+04 107 magnetite 20.13 18.97 -1.16 -0.095 0.19815E+04 113 margarite 17.45 15.47 -1.98 -0.079 0.33829E+04 116 microcline -2.43 -5.08 -2.65 -0.204 0.45226E+04 120 muscovite 2.68 0.71 -1.97 -0.116 0.33595E+04 121 paragonite 4.34 2.13 -2.21 -0.130 0.37653E+04 122 nepheline 8.38 3.46 -4.92 -0.703 0.83989E+04 136 prehnite 19.47 17.12 -2.34 -0.138 0.39985E+04 137 prehnite-Fe 22.59 20.53 -2.06 -0.124 0.35165E+04 138 pumpellyite-Fe 46.47 43.52 -2.95 -0.066 0.50382E+04 139 pumpellyite-Mg 49.19 45.75 -3.45 -0.077 0.58866E+04 145 pyroxmangite 7.42 4.88 -2.54 -0.507 0.43289E+04 146 pyrophyllite -6.10 -8.45 -2.35 -0.147 0.40121E+04 147 quartz -2.98 -3.56 -0.58 -0.193 0.98690E+03 152 rhodochrosite -0.96 -4.30 -3.35 -1.115 0.57115E+04 153 rhodonite 7.46 4.88 -2.58 -0.516 0.44081E+04 154 sanidine -1.22 -5.08 -3.86 -0.297 0.65903E+04 156 siderite -2.59 -6.37 -3.78 -1.261 0.64576E+04 157 sillimanite 5.32 2.23 -3.09 -0.309 0.52746E+04 164 stilbite -7.41 -8.12 -0.72 -0.034 0.12221E+04 165 stilpnomelane-Fe 13.18 10.54 -2.64 -0.079 0.45113E+04 168 sudoite-Fe 18.44 13.65 -4.78 -0.154 0.81674E+04 169 sudoite 21.22 18.11 -3.11 -0.100 0.53089E+04 172 talc 16.55 11.56 -4.99 -0.293 0.85194E+04 175 tephroite 18.11 13.32 -4.79 -0.684 0.81812E+04 178 topaz-H 4.67 2.23 -2.44 -0.221 0.41583E+04 179 tridymite -2.61 -3.56 -0.95 -0.315 0.16142E+04 188 wairakite 4.06 2.56 -1.50 -0.088 0.25614E+04 189 walstromite 11.53 7.45 -4.08 -0.816 0.69694E+04 190 wollastonite 10.48 7.45 -3.04 -0.607 0.51833E+04 191 pseudo-wollastonite 11.02 7.45 -3.57 -0.715 0.61019E+04 192 zoisite 22.96 20.02 -2.94 -0.134 0.50251E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.50 -2.94 -0.182 0.50227E+04 195 beidellite-H -2.24 -6.32 -4.08 -0.260 0.69599E+04 196 beidellite-K -1.44 -5.43 -3.99 -0.244 0.68130E+04 197 beidellite-Mg -1.71 -4.90 -3.19 -0.197 0.54488E+04 198 beidellite-Na -1.26 -4.96 -3.70 -0.227 0.63170E+04 200 chalcedony -2.79 -3.56 -0.77 -0.255 0.13072E+04 202 montmorillonite-Ca -2.21 -4.75 -2.54 -0.157 0.43285E+04 203 montmorillonite-K -2.16 -5.67 -3.51 -0.215 0.59966E+04 204 montmorillonite-Mg -2.40 -5.15 -2.74 -0.170 0.46857E+04 205 montmorillonite-Na -1.96 -5.20 -3.24 -0.199 0.55387E+04 206 nontronite-Ca 3.28 2.30 -0.98 -0.063 0.16656E+04 207 nontronite-H 2.60 0.49 -2.11 -0.141 0.35986E+04 208 nontronite-K 3.40 1.38 -2.02 -0.130 0.34551E+04 209 nontronite-Mg 3.14 1.91 -1.23 -0.080 0.21034E+04 210 nontronite-Na 3.58 1.85 -1.73 -0.111 0.29608E+04 215 gypsum -4.92 -9.29 -4.37 -1.092 0.74573E+04 225 tobermorite 9.84 5.61 -4.23 -1.154 0.72241E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.37 -3.45 -0.862 0.58900E+04 241 silica-amorphous -2.08 -3.56 -1.48 -0.493 0.25274E+04 243 an20ab80 2.08 -0.99 -3.07 -0.236 0.52456E+04 244 an25ab75 2.71 -0.33 -3.04 -0.233 0.51824E+04 245 an30ab70 3.34 0.34 -3.00 -0.231 0.51275E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0370000 g New total amount of reactant added: 0.0380000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0380000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2988034E-03 Osmotic coef. = 0.9897 True ionic strength = .3154700E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15635E-07 -7.8059 0.14999E-07 -7.8239 0.95935E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13234E-03 -3.8783 0.95921E+00 -0.0181 4 SO4-- 0.25347E-04 -4.5961 0.22646E-04 -4.6450 0.89344E+00 -0.0489 5 HCO3- 0.12594E-04 -4.8998 0.12081E-04 -4.9179 0.95925E+00 -0.0181 6 HS- 0.12991E-11 -11.8864 0.12461E-11 -11.9044 0.95922E+00 -0.0181 7 Al+++ 0.33483E-20 -20.4752 0.26564E-20 -20.5757 0.79335E+00 -0.1005 8 H4SiO4 0.28105E-03 -3.5512 0.28105E-03 -3.5512 0.10000E+01 0.0000 9 Ca++ 0.24535E-04 -4.6102 0.21917E-04 -4.6592 0.89329E+00 -0.0490 10 Mg++ 0.99357E-07 -7.0028 0.88746E-07 -7.0519 0.89320E+00 -0.0491 11 Fe++ 0.58958E-09 -9.2295 0.52662E-09 -9.2785 0.89322E+00 -0.0490 12 K+ 0.80650E-05 -5.0934 0.77364E-05 -5.1115 0.95925E+00 -0.0181 13 Na+ 0.20770E-03 -3.6826 0.19923E-03 -3.7006 0.95921E+00 -0.0181 14 Mn++ 0.68894E-07 -7.1618 0.61539E-07 -7.2109 0.89324E+00 -0.0490 15 HPO4-- 0.24330E-08 -8.6139 0.21737E-08 -8.6628 0.89345E+00 -0.0489 16 HSiO3- 0.19059E-04 -4.7199 0.18281E-04 -4.7380 0.95921E+00 -0.0181 17 Ca(HSiO3)+ 0.93584E-08 -8.0288 0.89771E-08 -8.0469 0.95926E+00 -0.0181 18 Mg(HSiO3)+ 0.47160E-10 -10.3264 0.45239E-10 -10.3445 0.95926E+00 -0.0181 19 NaHSiO3,aq 0.57847E-07 -7.2377 0.57847E-07 -7.2377 0.10000E+01 0.0000 20 AlO+ 0.15890E-11 -11.7989 0.15243E-11 -11.8169 0.95926E+00 -0.0181 21 AlOH+2 0.12822E-15 -15.8921 0.11453E-15 -15.9411 0.89326E+00 -0.0490 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.31562E-05 -5.5008 0.30274E-05 -5.5189 0.95917E+00 -0.0181 24 CH4,aq 0.65238E-18 -18.1855 0.65232E-18 -18.1855 0.99991E+00 0.0000 29 CO,aq 0.49042E-17 -17.3094 0.49042E-17 -17.3094 0.10000E+01 0.0000 30 CO2,aq 0.36538E-06 -6.4372 0.36535E-06 -6.4373 0.99991E+00 0.0000 31 CO3-2 0.83358E-07 -7.0791 0.74472E-07 -7.1280 0.89340E+00 -0.0490 32 CaCO3,aq 0.19990E-07 -7.6992 0.19990E-07 -7.6992 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.69550E-08 -8.1577 0.66717E-08 -8.1758 0.95926E+00 -0.0181 34 CaCl+ 0.48180E-08 -8.3171 0.46217E-08 -8.3352 0.95926E+00 -0.0181 35 CaCl2,aq 0.14241E-12 -12.8465 0.14241E-12 -12.8465 0.10000E+01 0.0000 36 CaOH+ 0.10741E-06 -6.9690 0.10303E-06 -6.9870 0.95926E+00 -0.0181 37 CaSO4,aq 0.15464E-06 -6.8107 0.15464E-06 -6.8107 0.10000E+01 0.0000 38 HCl,aq 0.37336E-12 -12.4279 0.37336E-12 -12.4279 0.10000E+01 0.0000 43 FeCl+ 0.11315E-12 -12.9463 0.10854E-12 -12.9644 0.95926E+00 -0.0181 46 FeO,aq 0.92565E-10 -10.0336 0.92565E-10 -10.0336 0.10000E+01 0.0000 47 FeOH+ 0.12134E-08 -8.9160 0.11640E-08 -8.9341 0.95926E+00 -0.0181 48 HFeO2- 0.69201E-10 -10.1599 0.66379E-10 -10.1780 0.95921E+00 -0.0181 49 FeO+ 0.12935E-12 -12.8882 0.12408E-12 -12.9063 0.95926E+00 -0.0181 50 FeOH+2 0.38768E-18 -18.4115 0.34630E-18 -18.4605 0.89326E+00 -0.0490 51 FeO2- 0.11300E-09 -9.9469 0.10839E-09 -9.9650 0.95921E+00 -0.0181 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.52123E-09 -9.2830 0.52118E-09 -9.2830 0.99991E+00 0.0000 54 KCl,aq 0.18128E-10 -10.7417 0.18128E-10 -10.7417 0.10000E+01 0.0000 55 KHSO4,aq 0.70319E-17 -17.1529 0.70319E-17 -17.1529 0.10000E+01 0.0000 56 KOH,aq 0.22486E-09 -9.6481 0.22486E-09 -9.6481 0.10000E+01 0.0000 57 KSO4- 0.28139E-08 -8.5507 0.26991E-08 -8.5688 0.95921E+00 -0.0181 58 MgCO3,aq 0.20227E-10 -10.6941 0.20227E-10 -10.6941 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28718E-10 -10.5418 0.27548E-10 -10.5599 0.95926E+00 -0.0181 60 MgCl+ 0.17711E-10 -10.7518 0.16989E-10 -10.7698 0.95926E+00 -0.0181 61 MgOH+ 0.24095E-08 -8.6181 0.23113E-08 -8.6361 0.95926E+00 -0.0181 63 MnO,aq 0.28875E-09 -9.5395 0.28875E-09 -9.5395 0.10000E+01 0.0000 64 MnOH+ 0.13172E-07 -7.8803 0.12636E-07 -7.8984 0.95926E+00 -0.0181 65 MnO2-2 0.49684E-16 -16.3038 0.44388E-16 -16.3527 0.89340E+00 -0.0490 66 HMnO2- 0.15038E-12 -12.8228 0.14425E-12 -12.8409 0.95921E+00 -0.0181 69 MnCl+ 0.51381E-10 -10.2892 0.49288E-10 -10.3073 0.95926E+00 -0.0181 70 MnSO4,aq 0.39495E-09 -9.4035 0.39495E-09 -9.4035 0.10000E+01 0.0000 71 NaCl,aq 0.86089E-08 -8.0651 0.86089E-08 -8.0651 0.10000E+01 0.0000 72 NaOH,aq 0.58365E-08 -8.2338 0.58365E-08 -8.2338 0.10000E+01 0.0000 74 OH- 0.41693E-04 -4.3799 0.39991E-04 -4.3980 0.95917E+00 -0.0181 82 H3PO4,aq 0.31484E-14 -14.5019 0.31484E-14 -14.5019 0.10000E+01 0.0000 83 H2PO4- 0.59591E-09 -9.2248 0.57162E-09 -9.2429 0.95923E+00 -0.0181 84 PO4-3 0.15935E-12 -12.7977 0.12656E-12 -12.8977 0.79426E+00 -0.1000 87 H2P2O7-2 0.28624E-19 -19.5433 0.25573E-19 -19.5922 0.89340E+00 -0.0490 88 HP2O7-3 0.44067E-18 -18.3559 0.34961E-18 -18.4564 0.79335E+00 -0.1005 90 H2S,aq 0.56162E-13 -13.2506 0.56157E-13 -13.2506 0.99991E+00 0.0000 96 SO2,aq 0.11125E-19 -19.9537 0.11125E-19 -19.9537 0.10000E+01 0.0000 97 SO3-2 0.18007E-14 -14.7446 0.16093E-14 -14.7934 0.89370E+00 -0.0488 98 HSO3- 0.14726E-14 -14.8319 0.14126E-14 -14.8500 0.95921E+00 -0.0181 99 HSO4- 0.32854E-09 -9.4834 0.31516E-09 -9.5015 0.95928E+00 -0.0181 101 S2O3-2 0.16776E-19 -19.7753 0.14988E-19 -19.8243 0.89340E+00 -0.0490 Charge balance for all species = 0.2021E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1563476E-07 -.7335890E-04 -.7393831E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999569E+06 0.0000 3 Cl- 0.1379624E-03 0.1379759E-03 0.4891459E+01 3.9456 4 SO4-- 0.2534661E-04 0.2550470E-04 0.2449921E+01 11.0029 5 HCO3- 0.1259443E-04 0.1307017E-04 0.7974720E+00 2.9060 6 HS- 0.1299092E-11 0.9208847E-10 0.3045424E-05 -4.0805 7 Al+++ 0.3348324E-20 0.3176582E-05 0.8570540E-01 2.8961 8 H4SiO4 0.2810457E-03 0.3001718E-03 0.2884994E+02 -3.5512 9 Ca++ 0.2453480E-04 0.2483797E-04 0.9954150E+00 10.9886 10 Mg++ 0.9935742E-07 0.1018808E-06 0.2476822E-02 8.5960 11 Fe++ 0.5895765E-09 0.2281483E-08 0.1274087E-03 6.3694 12 K+ 0.8064987E-05 0.8068044E-05 0.3154636E+00 2.7125 13 Na+ 0.2077006E-03 0.2077729E-03 0.4776460E+01 4.1233 14 Mn++ 0.6889379E-07 0.8280131E-07 0.4548750E-02 8.4370 15 HPO4-- 0.2432974E-08 0.3029046E-08 0.2907128E-03 6.9851 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6161836E-03 -.7335796E-04 -.5428256E-03 0.0000000E+00 2 H2O 0.5550777E+02 0.5550757E+02 0.2037444E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2655758E-04 0.2550438E-04 0.1053202E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1053110E-05 0.9208729E-10 -.1053202E-05 0.0000000E+00 7 Al+++ 0.1239082E-03 0.3176541E-05 0.1207316E-03 0.0000000E+00 8 H4SiO4 0.3956858E-03 0.3001679E-03 0.9551780E-04 0.0000000E+00 9 Ca++ 0.5817648E-04 0.2483765E-04 0.3333883E-04 0.0000000E+00 10 Mg++ 0.3015873E-04 0.1018794E-06 0.3005685E-04 0.0000000E+00 11 Fe++ 0.2709433E-04 0.2281454E-08 0.2709205E-04 0.0000000E+00 12 K+ 0.8067941E-05 0.8067941E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2077703E-03 0.2077703E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6588666E-06 0.8280025E-07 0.5760664E-06 0.0000000E+00 15 HPO4-- 0.2248679E-06 0.3029008E-08 0.2218389E-06 0.0000000E+00 Chg. balance for solid moles: -.2070E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0380000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7395E-07 -7.131 0.3714E-04 -4.430 0.1929 0.1180E-04 clinochlore 0.6011E-05 -5.221 0.3341E-02 -2.476 17.35 0.1271E-02 daphnite 0.3733E-05 -5.428 0.2664E-02 -2.575 13.83 0.8072E-03 chlorite-Mn 0.1152E-06 -6.938 0.8168E-04 -4.088 0.4241 0.2603E-04 diaspore 0.3507E-04 -4.455 0.2104E-02 -2.677 10.92 0.6264E-03 hematite 0.4213E-05 -5.375 0.6728E-03 -3.172 3.493 0.1275E-03 lawsonite 0.3297E-04 -4.482 0.1036E-01 -1.985 53.79 0.3341E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3786E+00 0.3786E+00 1.0000 -0.422 chlorite-Mn 0.1169E-01 0.1169E-01 1.0000 -1.932 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.019261 g Volume = 0.006211 cm3 Porosity: 99.3882% V(tot) - V(min): 0.10090E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0380000 g log = -1.4202 Original solution: 1000.0103000 g Original solution / Rock added: 26316.06 (Water/Rock Ratio), log = 4.4202 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3947E-04 1.0073 0.4182E-04 0.4152E-04 CH4,gas 0.9681E-15 1.0129 0.1032E-14 0.1018E-14 H2,gas 0.6791E-06 1.0006 0.7148E-06 0.7144E-06 H2S,gas 0.1563E-11 0.9959 0.1638E-11 0.1645E-11 S2,gas 0.1869E-30 1.0000 0.1966E-30 0.1966E-30 CO,gas 0.7361E-14 1.0000 0.7744E-14 0.7744E-14 SO3,gas 0.1811E-35 1.0000 0.1905E-35 0.1905E-35 SO2,gas 0.4896E-19 1.0000 0.5151E-19 0.5151E-19 HCl,gas 0.6267E-15 1.0000 0.6592E-15 0.6592E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 65 diaspore 2.90 2.90 0.00 0.000 -0.22748E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.74 -6.38 -2.126 0.10891E+05 -4.379 3 CH4,gas 4.81 -12.18 -16.99 -4.247 0.29004E+05 -14.987 4 H2,gas 8.29 0.14 -8.15 -4.655 0.13909E+05 -6.146 5 H2S,gas -5.94 -19.73 -13.79 -6.893 0.23539E+05 -11.786 6 S2,gas -7.03 -39.74 -32.71 -5.032 0.55845E+05 -30.706 7 CO,gas 3.51 -12.60 -16.11 -4.957 0.27509E+05 -14.111 8 SO3,gas 17.43 -20.29 -37.72 -9.430 0.64406E+05 -35.720 9 SO2,gas 1.14 -20.15 -21.29 -5.677 0.36349E+05 -19.288 10 HCl,gas 5.48 -11.70 -17.18 -8.590 0.29336E+05 -15.181 11 acmite 7.74 3.32 -4.42 -0.459 0.75432E+04 15 albite-high 0.75 -3.63 -4.38 -0.337 0.74854E+04 16 albite -0.33 -3.63 -3.31 -0.254 0.56448E+04 19 spessartine 24.55 20.45 -4.10 -0.205 0.70012E+04 20 analcite 3.37 -0.08 -3.45 -0.384 0.58971E+04 21 andalusite 5.06 2.24 -2.82 -0.282 0.48175E+04 22 andradite 39.09 34.91 -4.18 -0.217 0.71336E+04 23 grossular 32.83 28.10 -4.72 -0.236 0.80657E+04 24 anhydrite -5.28 -9.30 -4.02 -2.012 0.68717E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.75 -2.74 -0.913 0.46775E+04 36 brucite 12.58 8.60 -3.98 -0.796 0.67967E+04 37 calcite 0.83 -1.75 -2.59 -0.862 0.44161E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23301E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29433E+04 50 chloritoid-Mg 13.26 10.84 -2.42 -0.162 0.41394E+04 51 chloritoid-Fe 9.24 8.61 -0.63 -0.042 0.10729E+04 52 chloritoid-Mn 11.46 10.68 -0.79 -0.052 0.13408E+04 54 coesite -2.37 -3.55 -1.18 -0.394 0.20180E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.55 -1.00 -0.334 0.17109E+04 67 diopside 16.22 12.48 -3.73 -0.373 0.63744E+04 68 hedenbergite 14.24 10.26 -3.99 -0.399 0.68109E+04 75 epidote 24.78 23.41 -1.36 -0.066 0.23232E+04 76 clinozoisite 22.92 20.01 -2.91 -0.132 0.49675E+04 77 epidote-Fe 29.94 26.82 -3.12 -0.162 0.53264E+04 78 fayalite 14.08 9.19 -4.89 -0.699 0.83520E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.01 -4.19 -0.349 0.71518E+04 91 heulandite -5.71 -8.08 -2.37 -0.108 0.40478E+04 95 jadeite 4.25 -0.08 -4.33 -0.433 0.74001E+04 98 kaolinite -1.27 -1.31 -0.04 -0.003 0.63393E+02 99 kyanite 4.93 2.24 -2.69 -0.269 0.45943E+04 101 laumontite 2.97 2.58 -0.40 -0.027 0.68062E+03 105 lizardite 23.29 18.69 -4.60 -0.383 0.78575E+04 106 magnesite 0.71 -4.15 -4.86 -1.618 0.82900E+04 107 magnetite 20.13 18.97 -1.17 -0.095 0.19906E+04 113 margarite 17.45 15.47 -1.98 -0.079 0.33829E+04 116 microcline -2.43 -5.05 -2.61 -0.201 0.44622E+04 120 muscovite 2.68 0.75 -1.93 -0.114 0.32991E+04 121 paragonite 4.34 2.16 -2.18 -0.128 0.37201E+04 122 nepheline 8.38 3.47 -4.91 -0.701 0.83836E+04 136 prehnite 19.47 17.12 -2.35 -0.138 0.40135E+04 137 prehnite-Fe 22.59 20.52 -2.07 -0.124 0.35315E+04 138 pumpellyite-Fe 46.47 43.50 -2.97 -0.066 0.50772E+04 139 pumpellyite-Mg 49.19 45.72 -3.47 -0.077 0.59255E+04 145 pyroxmangite 7.42 4.89 -2.53 -0.506 0.43203E+04 146 pyrophyllite -6.10 -8.41 -2.31 -0.145 0.39523E+04 147 quartz -2.98 -3.55 -0.57 -0.190 0.97194E+03 152 rhodochrosite -0.96 -4.30 -3.35 -1.115 0.57137E+04 153 rhodonite 7.46 4.89 -2.58 -0.515 0.43996E+04 154 sanidine -1.22 -5.05 -3.82 -0.294 0.65299E+04 156 siderite -2.59 -6.37 -3.78 -1.262 0.64624E+04 157 sillimanite 5.32 2.24 -3.08 -0.308 0.52597E+04 164 stilbite -7.41 -8.08 -0.67 -0.032 0.11472E+04 165 stilpnomelane-Fe 13.18 10.59 -2.59 -0.077 0.44290E+04 168 sudoite-Fe 18.44 13.67 -4.77 -0.154 0.81406E+04 169 sudoite 21.22 18.12 -3.09 -0.100 0.52820E+04 172 talc 16.55 11.58 -4.97 -0.292 0.84865E+04 175 tephroite 18.11 13.32 -4.79 -0.684 0.81790E+04 178 topaz-H 4.67 2.24 -2.43 -0.221 0.41434E+04 179 tridymite -2.61 -3.55 -0.94 -0.312 0.15992E+04 188 wairakite 4.06 2.58 -1.48 -0.087 0.25314E+04 189 walstromite 11.53 7.44 -4.09 -0.818 0.69843E+04 190 wollastonite 10.48 7.44 -3.04 -0.609 0.51982E+04 191 pseudo-wollastonite 11.02 7.44 -3.58 -0.716 0.61168E+04 192 zoisite 22.96 20.01 -2.95 -0.134 0.50400E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.47 -2.91 -0.180 0.49727E+04 195 beidellite-H -2.24 -6.29 -4.04 -0.258 0.69050E+04 196 beidellite-K -1.44 -5.39 -3.95 -0.242 0.67530E+04 197 beidellite-Mg -1.71 -4.87 -3.16 -0.195 0.53954E+04 198 beidellite-Na -1.26 -4.92 -3.67 -0.225 0.62620E+04 200 chalcedony -2.79 -3.55 -0.76 -0.252 0.12923E+04 202 montmorillonite-Ca -2.21 -4.72 -2.50 -0.155 0.42765E+04 203 montmorillonite-K -2.16 -5.64 -3.48 -0.213 0.59346E+04 204 montmorillonite-Mg -2.40 -5.11 -2.71 -0.168 0.46303E+04 205 montmorillonite-Na -1.96 -5.17 -3.21 -0.197 0.54817E+04 206 nontronite-Ca 3.28 2.33 -0.95 -0.061 0.16156E+04 207 nontronite-H 2.60 0.52 -2.08 -0.139 0.35437E+04 208 nontronite-K 3.40 1.42 -1.99 -0.128 0.33951E+04 209 nontronite-Mg 3.14 1.94 -1.20 -0.078 0.20499E+04 210 nontronite-Na 3.58 1.88 -1.70 -0.109 0.29058E+04 215 gypsum -4.92 -9.30 -4.38 -1.095 0.74785E+04 225 tobermorite 9.84 5.60 -4.24 -1.156 0.72340E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.37 -3.45 -0.864 0.58991E+04 241 silica-amorphous -2.08 -3.55 -1.47 -0.490 0.25124E+04 243 an20ab80 2.08 -0.97 -3.05 -0.235 0.52094E+04 244 an25ab75 2.71 -0.31 -3.02 -0.232 0.51485E+04 245 an30ab70 3.34 0.36 -2.98 -0.230 0.50959E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0380000 g New total amount of reactant added: 0.0390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2080E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0390000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .2980303E-03 Osmotic coef. = 0.9897 True ionic strength = .3148161E-03 Chg. balance for total moles = 0.2080E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15717E-07 -7.8036 0.15079E-07 -7.8216 0.95937E+00 -0.0180 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13234E-03 -3.8783 0.95924E+00 -0.0181 4 SO4-- 0.25351E-04 -4.5960 0.22652E-04 -4.6449 0.89353E+00 -0.0489 5 HCO3- 0.12594E-04 -4.8998 0.12081E-04 -4.9179 0.95927E+00 -0.0181 6 HS- 0.11866E-11 -11.9257 0.11383E-11 -11.9438 0.95924E+00 -0.0181 7 Al+++ 0.34012E-20 -20.4684 0.26989E-20 -20.5688 0.79352E+00 -0.1004 8 H4SiO4 0.28668E-03 -3.5426 0.28668E-03 -3.5426 0.10000E+01 0.0000 9 Ca++ 0.23828E-04 -4.6229 0.21288E-04 -4.6719 0.89338E+00 -0.0490 10 Mg++ 0.99216E-07 -7.0034 0.88628E-07 -7.0524 0.89329E+00 -0.0490 11 Fe++ 0.58869E-09 -9.2301 0.52588E-09 -9.2791 0.89331E+00 -0.0490 12 K+ 0.82772E-05 -5.0821 0.79401E-05 -5.1002 0.95928E+00 -0.0181 13 Na+ 0.20895E-03 -3.6799 0.20044E-03 -3.6980 0.95923E+00 -0.0181 14 Mn++ 0.69032E-07 -7.1610 0.61668E-07 -7.2099 0.89332E+00 -0.0490 15 HPO4-- 0.25719E-08 -8.5898 0.22980E-08 -8.6386 0.89353E+00 -0.0489 16 HSiO3- 0.19338E-04 -4.7136 0.18550E-04 -4.7317 0.95924E+00 -0.0181 17 Ca(HSiO3)+ 0.92229E-08 -8.0351 0.88473E-08 -8.0532 0.95928E+00 -0.0181 18 Mg(HSiO3)+ 0.47787E-10 -10.3207 0.45841E-10 -10.3387 0.95928E+00 -0.0181 19 NaHSiO3,aq 0.59051E-07 -7.2288 0.59051E-07 -7.2288 0.10000E+01 0.0000 20 AlO+ 0.15974E-11 -11.7966 0.15324E-11 -11.8146 0.95928E+00 -0.0181 21 AlOH+2 0.12957E-15 -15.8875 0.11575E-15 -15.9365 0.89334E+00 -0.0490 22 HAlO2,aq 0.20336E-07 -7.6917 0.20336E-07 -7.6917 0.10000E+01 0.0000 23 AlO2- 0.31395E-05 -5.5031 0.30114E-05 -5.5212 0.95920E+00 -0.0181 24 CH4,aq 0.59575E-18 -18.2249 0.59569E-18 -18.2250 0.99991E+00 0.0000 29 CO,aq 0.48131E-17 -17.3176 0.48131E-17 -17.3176 0.10000E+01 0.0000 30 CO2,aq 0.36732E-06 -6.4350 0.36728E-06 -6.4350 0.99991E+00 0.0000 31 CO3-2 0.82908E-07 -7.0814 0.74077E-07 -7.1303 0.89348E+00 -0.0489 32 CaCO3,aq 0.19313E-07 -7.7141 0.19313E-07 -7.7141 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.67550E-08 -8.1704 0.64800E-08 -8.1884 0.95928E+00 -0.0181 34 CaCl+ 0.46797E-08 -8.3298 0.44891E-08 -8.3478 0.95928E+00 -0.0181 35 CaCl2,aq 0.13832E-12 -12.8591 0.13832E-12 -12.8591 0.10000E+01 0.0000 36 CaOH+ 0.10377E-06 -6.9839 0.99546E-07 -7.0020 0.95928E+00 -0.0181 37 CaSO4,aq 0.15024E-06 -6.8232 0.15024E-06 -6.8232 0.10000E+01 0.0000 38 HCl,aq 0.37535E-12 -12.4256 0.37535E-12 -12.4256 0.10000E+01 0.0000 43 FeCl+ 0.11299E-12 -12.9469 0.10839E-12 -12.9650 0.95928E+00 -0.0181 46 FeO,aq 0.91460E-10 -10.0388 0.91460E-10 -10.0388 0.10000E+01 0.0000 47 FeOH+ 0.12053E-08 -8.9189 0.11562E-08 -8.9370 0.95928E+00 -0.0181 48 HFeO2- 0.68012E-10 -10.1674 0.65240E-10 -10.1855 0.95924E+00 -0.0181 49 FeO+ 0.13003E-12 -12.8860 0.12473E-12 -12.9040 0.95928E+00 -0.0181 50 FeOH+2 0.39177E-18 -18.4070 0.34999E-18 -18.4559 0.89334E+00 -0.0490 51 FeO2- 0.11240E-09 -9.9492 0.10782E-09 -9.9673 0.95924E+00 -0.0181 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.50886E-09 -9.2934 0.50881E-09 -9.2934 0.99991E+00 0.0000 54 KCl,aq 0.18606E-10 -10.7304 0.18606E-10 -10.7304 0.10000E+01 0.0000 55 KHSO4,aq 0.72574E-17 -17.1392 0.72574E-17 -17.1392 0.10000E+01 0.0000 56 KOH,aq 0.22956E-09 -9.6391 0.22956E-09 -9.6391 0.10000E+01 0.0000 57 KSO4- 0.28887E-08 -8.5393 0.27710E-08 -8.5574 0.95924E+00 -0.0181 58 MgCO3,aq 0.20092E-10 -10.6970 0.20092E-10 -10.6970 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28679E-10 -10.5424 0.27511E-10 -10.5605 0.95928E+00 -0.0181 60 MgCl+ 0.17687E-10 -10.7523 0.16967E-10 -10.7704 0.95928E+00 -0.0181 61 MgOH+ 0.23935E-08 -8.6210 0.22961E-08 -8.6390 0.95928E+00 -0.0181 63 MnO,aq 0.28631E-09 -9.5432 0.28631E-09 -9.5432 0.10000E+01 0.0000 64 MnOH+ 0.13130E-07 -7.8817 0.12595E-07 -7.8998 0.95928E+00 -0.0181 65 MnO2-2 0.48740E-16 -16.3121 0.43548E-16 -16.3610 0.89348E+00 -0.0489 66 HMnO2- 0.14832E-12 -12.8288 0.14227E-12 -12.8469 0.95924E+00 -0.0181 69 MnCl+ 0.51489E-10 -10.2883 0.49393E-10 -10.3063 0.95928E+00 -0.0181 70 MnSO4,aq 0.39588E-09 -9.4024 0.39588E-09 -9.4024 0.10000E+01 0.0000 71 NaCl,aq 0.86613E-08 -8.0624 0.86613E-08 -8.0624 0.10000E+01 0.0000 72 NaOH,aq 0.58408E-08 -8.2335 0.58408E-08 -8.2335 0.10000E+01 0.0000 74 OH- 0.41472E-04 -4.3822 0.39780E-04 -4.4003 0.95920E+00 -0.0181 82 H3PO4,aq 0.33639E-14 -14.4732 0.33639E-14 -14.4732 0.10000E+01 0.0000 83 H2PO4- 0.63332E-09 -9.1984 0.60752E-09 -9.2164 0.95926E+00 -0.0181 84 PO4-3 0.16754E-12 -12.7759 0.13309E-12 -12.8758 0.79443E+00 -0.0999 87 H2P2O7-2 0.32330E-19 -19.4904 0.28886E-19 -19.5393 0.89348E+00 -0.0489 88 HP2O7-3 0.49502E-18 -18.3054 0.39281E-18 -18.4058 0.79352E+00 -0.1004 90 H2S,aq 0.51574E-13 -13.2876 0.51569E-13 -13.2876 0.99991E+00 0.0000 96 SO2,aq 0.10979E-19 -19.9594 0.10979E-19 -19.9594 0.10000E+01 0.0000 97 SO3-2 0.17582E-14 -14.7549 0.15715E-14 -14.8037 0.89379E+00 -0.0488 98 HSO3- 0.14457E-14 -14.8399 0.13867E-14 -14.8580 0.95924E+00 -0.0181 99 HSO4- 0.33037E-09 -9.4810 0.31692E-09 -9.4990 0.95930E+00 -0.0180 101 S2O3-2 0.15408E-19 -19.8122 0.13767E-19 -19.8612 0.89348E+00 -0.0489 Charge balance for all species = 0.2022E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1571744E-07 -.7334394E-04 -.7392319E-01 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999563E+06 0.0000 3 Cl- 0.1379626E-03 0.1379760E-03 0.4891457E+01 3.9433 4 SO4-- 0.2535094E-04 0.2550471E-04 0.2449921E+01 10.9984 5 HCO3- 0.1259383E-04 0.1307017E-04 0.7974717E+00 2.9037 6 HS- 0.1186625E-11 0.8895315E-10 0.2941735E-05 -4.1221 7 Al+++ 0.3401232E-20 0.3159829E-05 0.8525336E-01 2.8961 8 H4SiO4 0.2866841E-03 0.3060904E-03 0.2941876E+02 -3.5426 9 Ca++ 0.2382810E-04 0.2412208E-04 0.9667242E+00 10.9714 10 Mg++ 0.9921585E-07 0.1017236E-06 0.2473001E-02 8.5908 11 Fe++ 0.5886858E-09 0.2269551E-08 0.1267423E-03 6.3641 12 K+ 0.8277226E-05 0.8280363E-05 0.3237652E+00 2.7215 13 Na+ 0.2089547E-03 0.2090282E-03 0.4805316E+01 4.1236 14 Mn++ 0.6903186E-07 0.8289557E-07 0.4553926E-02 8.4333 15 HPO4-- 0.2571873E-08 0.3205366E-08 0.3076349E-03 7.0046 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6327421E-03 -.7334298E-04 -.5593991E-03 0.0000000E+00 2 H2O 0.5550776E+02 0.5550755E+02 0.2073310E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2658529E-04 0.2550438E-04 0.1080912E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1080823E-05 0.8895199E-10 -.1080912E-05 0.0000000E+00 7 Al+++ 0.1271689E-03 0.3159788E-05 0.1240091E-03 0.0000000E+00 8 H4SiO4 0.4060985E-03 0.3060864E-03 0.1000122E-03 0.0000000E+00 9 Ca++ 0.5932662E-04 0.2412177E-04 0.3520486E-04 0.0000000E+00 10 Mg++ 0.3095238E-04 0.1017223E-06 0.3085066E-04 0.0000000E+00 11 Fe++ 0.2780734E-04 0.2269521E-08 0.2780507E-04 0.0000000E+00 12 K+ 0.8280255E-05 0.8280255E-05 0.0000000E+00 0.0000000E+00 13 Na+ 0.2090255E-03 0.2090255E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6762052E-06 0.8289449E-07 0.5933108E-06 0.0000000E+00 15 HPO4-- 0.2307855E-06 0.3205325E-08 0.2275802E-06 0.0000000E+00 Chg. balance for solid moles: 0.2393E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7586E-07 -7.120 0.3811E-04 -4.419 0.1909 0.1211E-04 clinochlore 0.6170E-05 -5.210 0.3430E-02 -2.465 17.18 0.1305E-02 daphnite 0.3832E-05 -5.417 0.2734E-02 -2.563 13.69 0.8284E-03 chlorite-Mn 0.1187E-06 -6.926 0.8413E-04 -4.075 0.4213 0.2681E-04 diaspore 0.3412E-04 -4.467 0.2047E-02 -2.689 10.25 0.6093E-03 hematite 0.4324E-05 -5.364 0.6905E-03 -3.161 3.458 0.1309E-03 lawsonite 0.3483E-04 -4.458 0.1094E-01 -1.961 54.81 0.3529E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6097E+00 0.6097E+00 1.0000 -0.215 daphnite 0.3786E+00 0.3786E+00 1.0000 -0.422 chlorite-Mn 0.1173E-01 0.1173E-01 1.0000 -1.931 diaspore 0.1000E+01 0.1000E+01 1.0000 0.000 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.019966 g Volume = 0.006441 cm3 Porosity: 99.3658% V(tot) - V(min): 0.10092E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0390000 g log = -1.4089 Original solution: 1000.0103000 g Original solution / Rock added: 25641.29 (Water/Rock Ratio), log = 4.4089 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3967E-04 1.0073 0.4204E-04 0.4174E-04 CH4,gas 0.8840E-15 1.0129 0.9420E-15 0.9300E-15 H2,gas 0.6630E-06 1.0006 0.6979E-06 0.6975E-06 H2S,gas 0.1436E-11 0.9959 0.1504E-11 0.1510E-11 S2,gas 0.1654E-30 1.0000 0.1740E-30 0.1740E-30 CO,gas 0.7224E-14 1.0000 0.7600E-14 0.7600E-14 SO3,gas 0.1830E-35 1.0000 0.1925E-35 0.1925E-35 SO2,gas 0.4832E-19 1.0000 0.5083E-19 0.5083E-19 HCl,gas 0.6300E-15 1.0000 0.6628E-15 0.6628E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 65 diaspore 2.90 2.90 0.00 0.000 0.37914E-11 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.74 -6.38 -2.125 0.10887E+05 -4.376 3 CH4,gas 4.81 -12.22 -17.03 -4.256 0.29071E+05 -15.026 4 H2,gas 8.29 0.13 -8.16 -4.661 0.13927E+05 -6.156 5 H2S,gas -5.94 -19.77 -13.82 -6.911 0.23602E+05 -11.823 6 S2,gas -7.03 -39.79 -32.76 -5.040 0.55936E+05 -30.760 7 CO,gas 3.51 -12.61 -16.12 -4.960 0.27523E+05 -14.119 8 SO3,gas 17.43 -20.29 -37.72 -9.429 0.64398E+05 -35.715 9 SO2,gas 1.14 -20.16 -21.29 -5.678 0.36359E+05 -19.294 10 HCl,gas 5.48 -11.70 -17.18 -8.589 0.29332E+05 -15.179 11 acmite 7.74 3.34 -4.40 -0.457 0.75132E+04 15 albite-high 0.75 -3.61 -4.36 -0.335 0.74407E+04 16 albite -0.33 -3.61 -3.28 -0.252 0.56001E+04 19 spessartine 24.55 20.46 -4.09 -0.204 0.69759E+04 20 analcite 3.37 -0.07 -3.44 -0.382 0.58671E+04 21 andalusite 5.06 2.25 -2.81 -0.281 0.48028E+04 22 andradite 39.09 34.88 -4.20 -0.218 0.71778E+04 23 grossular 32.83 28.08 -4.75 -0.237 0.81099E+04 24 anhydrite -5.28 -9.32 -4.04 -2.019 0.68931E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.77 -2.75 -0.918 0.47030E+04 36 brucite 12.58 8.59 -3.99 -0.797 0.68056E+04 37 calcite 0.83 -1.77 -2.60 -0.867 0.44417E+04 40 carpholite-Mg 8.65 7.30 -1.35 -0.090 0.23095E+04 41 carpholite-Fe 6.78 5.07 -1.71 -0.114 0.29228E+04 50 chloritoid-Mg 13.26 10.84 -2.42 -0.161 0.41335E+04 51 chloritoid-Fe 9.24 8.61 -0.62 -0.042 0.10671E+04 52 chloritoid-Mn 11.46 10.68 -0.78 -0.052 0.13324E+04 54 coesite -2.37 -3.54 -1.17 -0.391 0.20033E+04 59 corundum 8.43 5.79 -2.64 -0.240 0.45099E+04 61 cristobalite -2.55 -3.54 -0.99 -0.331 0.16962E+04 67 diopside 16.22 12.48 -3.74 -0.374 0.63833E+04 68 hedenbergite 14.24 10.25 -3.99 -0.399 0.68198E+04 75 epidote 24.78 23.41 -1.37 -0.066 0.23379E+04 76 clinozoisite 22.92 20.00 -2.92 -0.133 0.49822E+04 77 epidote-Fe 29.94 26.81 -3.13 -0.162 0.53411E+04 78 fayalite 14.08 9.19 -4.89 -0.699 0.83551E+04 83 gibbsite 4.10 2.90 -1.20 -0.172 0.20512E+04 87 greenalite 16.19 12.01 -4.19 -0.349 0.71491E+04 91 heulandite -5.71 -8.03 -2.33 -0.106 0.39741E+04 95 jadeite 4.25 -0.07 -4.32 -0.432 0.73701E+04 98 kaolinite -1.27 -1.29 -0.02 -0.002 0.33933E+02 99 kyanite 4.93 2.25 -2.68 -0.268 0.45795E+04 101 laumontite 2.97 2.59 -0.38 -0.025 0.65117E+03 105 lizardite 23.29 18.69 -4.60 -0.383 0.78546E+04 106 magnesite 0.71 -4.15 -4.86 -1.619 0.82949E+04 107 magnetite 20.13 18.96 -1.17 -0.096 0.19995E+04 113 margarite 17.45 15.47 -1.98 -0.079 0.33829E+04 116 microcline -2.43 -5.01 -2.58 -0.198 0.44026E+04 120 muscovite 2.68 0.78 -1.90 -0.112 0.32395E+04 121 paragonite 4.34 2.18 -2.15 -0.127 0.36754E+04 122 nepheline 8.38 3.48 -4.90 -0.700 0.83684E+04 136 prehnite 19.47 17.11 -2.36 -0.139 0.40282E+04 137 prehnite-Fe 22.59 20.51 -2.08 -0.125 0.35462E+04 138 pumpellyite-Fe 46.47 43.47 -3.00 -0.067 0.51156E+04 139 pumpellyite-Mg 49.19 45.70 -3.49 -0.078 0.59638E+04 145 pyroxmangite 7.42 4.89 -2.53 -0.505 0.43119E+04 146 pyrophyllite -6.10 -8.38 -2.28 -0.143 0.38933E+04 147 quartz -2.98 -3.54 -0.56 -0.187 0.95721E+03 152 rhodochrosite -0.96 -4.31 -3.35 -1.116 0.57161E+04 153 rhodonite 7.46 4.89 -2.57 -0.514 0.43911E+04 154 sanidine -1.22 -5.01 -3.79 -0.291 0.64704E+04 156 siderite -2.59 -6.38 -3.79 -1.263 0.64674E+04 157 sillimanite 5.32 2.25 -3.07 -0.307 0.52450E+04 164 stilbite -7.41 -8.03 -0.63 -0.030 0.10736E+04 165 stilpnomelane-Fe 13.18 10.63 -2.55 -0.076 0.43480E+04 168 sudoite-Fe 18.44 13.68 -4.75 -0.153 0.81142E+04 169 sudoite 21.22 18.14 -3.08 -0.099 0.52555E+04 172 talc 16.55 11.60 -4.95 -0.291 0.84541E+04 175 tephroite 18.11 13.32 -4.79 -0.684 0.81768E+04 178 topaz-H 4.67 2.25 -2.42 -0.220 0.41286E+04 179 tridymite -2.61 -3.54 -0.93 -0.309 0.15845E+04 188 wairakite 4.06 2.59 -1.47 -0.086 0.25020E+04 189 walstromite 11.53 7.43 -4.10 -0.820 0.69991E+04 190 wollastonite 10.48 7.43 -3.05 -0.611 0.52130E+04 191 pseudo-wollastonite 11.02 7.43 -3.59 -0.718 0.61316E+04 192 zoisite 22.96 20.00 -2.96 -0.135 0.50548E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.44 -2.88 -0.178 0.49235E+04 195 beidellite-H -2.24 -6.25 -4.01 -0.256 0.68510E+04 196 beidellite-K -1.44 -5.36 -3.92 -0.240 0.66939E+04 197 beidellite-Mg -1.71 -4.84 -3.13 -0.194 0.53428E+04 198 beidellite-Na -1.26 -4.89 -3.64 -0.223 0.62077E+04 200 chalcedony -2.79 -3.54 -0.75 -0.249 0.12775E+04 202 montmorillonite-Ca -2.21 -4.69 -2.47 -0.153 0.42254E+04 203 montmorillonite-K -2.16 -5.60 -3.44 -0.211 0.58735E+04 204 montmorillonite-Mg -2.40 -5.08 -2.68 -0.166 0.45757E+04 205 montmorillonite-Na -1.96 -5.14 -3.18 -0.195 0.54255E+04 206 nontronite-Ca 3.28 2.36 -0.92 -0.060 0.15664E+04 207 nontronite-H 2.60 0.55 -2.04 -0.137 0.34896E+04 208 nontronite-K 3.40 1.45 -1.95 -0.125 0.33360E+04 209 nontronite-Mg 3.14 1.97 -1.17 -0.076 0.19973E+04 210 nontronite-Na 3.58 1.91 -1.67 -0.107 0.28515E+04 215 gypsum -4.92 -9.32 -4.39 -1.098 0.74999E+04 225 tobermorite 9.84 5.60 -4.24 -1.158 0.72438E+04 234 boehmite 4.43 2.90 -1.53 -0.256 0.26184E+04 236 ferrous-oxide 9.82 6.36 -3.46 -0.865 0.59080E+04 241 silica-amorphous -2.08 -3.54 -1.46 -0.488 0.24977E+04 243 an20ab80 2.08 -0.95 -3.03 -0.233 0.51737E+04 244 an25ab75 2.71 -0.29 -3.00 -0.230 0.51150E+04 245 an30ab70 3.34 0.38 -2.97 -0.228 0.50646E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0010000 g Current total amount of reactant added: 0.0390000 g New total amount of reactant added: 0.0400000 g Mixing fraction reached given limit of 0.4000E-01 TOTMIX = 0.4000E-01 Execution stopped.