File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.12951E-02 0.11234E-07 0.9586 0.00000000E+00 H2O 2 0. 0.55507E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13796E-03 0.9585 0.00000000E+00 SO4-- 4 -2. 0.27694E-04 0.25426E-04 0.8907 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.12673E-04 0.9585 0.00000000E+00 HS- 6 -1. -0.21894E-05 0.48550E-12 0.9585 0.00000000E+00 Al+++ 7 3. 0.25760E-03 0.95583E-21 0.7879 0.00000000E+00 H4SiO4 8 0. 0.82261E-03 0.38296E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.10533E-03 0.11648E-04 0.8906 0.00000000E+00 Mg++ 10 2. 0.62698E-04 0.47465E-07 0.8905 0.00000000E+00 Fe++ 11 2. 0.56328E-04 0.28095E-09 0.8905 0.00000000E+00 K+ 12 1. 0.16773E-04 0.16767E-04 0.9585 0.00000000E+00 Na+ 13 1. 0.25924E-03 0.25908E-03 0.9585 0.00000000E+00 Mn++ 14 2. 0.13697E-05 0.36272E-07 0.8905 0.00000000E+00 HPO4-- 15 -2. 0.46749E-06 0.54587E-08 0.8907 0.00000000E+00 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 100.0000 SLIM = 0.200000E+00 TEMP = 100.0000 SINC = 0.4000E-02 TEMPC = 0.0000 TOTMIX = 0.790000E-01 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 1.0316 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0107 MnO2-2 65 -2. 40.4376 Ca(HSiO3)+ 17 1. 7.6603 HMnO2- 66 -1. 29.1018 Mg(HSiO3)+ 18 1. 7.5653 MnO4- 67 -1. 83.3383 NaHSiO3,aq 19 0. 7.8098 MnO4-2 68 -2. 81.3024 AlO+ 20 1. 6.8891 MnCl+ 69 1. -0.7819 AlOH+2 21 2. 3.1893 MnSO4,aq 70 0. -2.4524 HAlO2,aq 22 0. 10.5878 NaCl,aq 71 0. 0.4861 AlO2- 23 -1. 16.2390 NaOH,aq 72 0. 12.3571 CH4,aq 24 0. 6.0082 O2,aq 73 0. 53.5759 C2H6,aq 25 0. 12.3556 OH- 74 -1. 12.2220 C3H8,aq 26 0. 17.3423 HO2- 75 -1. 50.7897 C4H10,aq 27 0. 22.3397 H2O2,aq 76 0. 40.0297 ethanol,aq 28 0. 15.3114 H3PO2,aq 77 0. 24.3310 CO,aq 29 0. 4.7087 H2PO2- 78 -1. 26.5491 CO2,aq 30 0. -6.3045 HPO3-2 79 -2. 11.9246 CO3-2 31 -2. 10.0340 H3PO3,aq 80 0. 3.5932 CaCO3,aq 32 0. 5.9460 H2PO3- 81 -1. 5.6314 Ca(HCO3)+ 33 1. -1.4013 H3PO4,aq 82 0. -9.8087 CaCl+ 34 1. -0.2023 H2PO4- 83 -1. -7.2438 CaCl2,aq 35 0. 0.4306 PO4-3 84 -3. 12.0588 CaOH+ 36 1. 10.1517 H4P2O7,aq 85 0. -17.7539 CaSO4,aq 37 0. -2.4936 H3P2O7- 86 -1. -15.8646 HCl,aq 38 0. 0.7256 H2P2O7-2 87 -2. -13.3812 HClO,aq 39 0. 32.4377 HP2O7-3 88 -3. -6.6931 ClO- 40 -1. 39.6416 P2O7-4 89 -4. 2.9147 HClO2,aq 41 0. 70.2060 H2S,aq 90 0. -6.4778 Fe+3 42 3. 8.3763 S2-2 91 -2. 1.2336 FeCl+ 43 1. -0.1924 S3-2 92 -2. -8.7963 FeCl2,aq 44 0. 4.3160 S3- 93 -1. -16.3178 FeCl+2 45 2. 6.5223 S4-2 94 -2. -18.6473 FeO,aq 46 0. 16.4029 S5-2 95 -2. -28.3223 FeOH+ 47 1. 7.4795 SO2,aq 96 0. -0.1980 HFeO2- 48 -1. 24.3713 SO3-2 97 -2. 10.2895 FeO+ 49 1. 11.3812 HSO3- 98 -1. 2.5222 FeOH+2 50 2. 9.1115 HSO4- 99 -1. -2.9675 FeO2- 51 -1. 24.0877 HSO5- 100 -1. 38.8657 HFeO2,aq 52 0. 15.9903 S2O3-2 101 -2. -4.5491 H2,aq 53 0. 9.4241 HS2O3- 102 -1. -6.8007 KCl,aq 54 0. 1.7519 H2S2O3,aq 103 0. -7.9944 KHSO4,aq 55 0. -0.4275 S2O4-2 104 -2. 10.5639 KOH,aq 56 0. 12.3606 HS2O4- 105 -1. 7.6762 KSO4- 57 -1. -1.1877 H2S2O4,aq 106 0. 6.6566 MgCO3,aq 58 0. 6.5483 S2O5-2 107 -2. 10.0891 Mg(HCO3)+ 59 1. -1.4098 S2O6-2 108 -2. 11.5737 MgCl+ 60 1. -0.1603 S2O8-2 109 -2. 42.1139 MgOH+ 61 1. 9.4082 S3O6-2 110 -2. 3.8101 Mn+3 62 3. 19.1332 S4O6-2 111 -2. -17.8301 MnO,aq 63 0. 17.9765 S5O6-2 112 -2. -14.1051 MnOH+ 64 1. 8.5115 113 0. 10.3157 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.984 0.0000E+00 osumilite(2) 124 20.895 0.0000E+00 CO2,gas 2 -6.363 0.0000E+00 osumilite-Fe 125 14.657 0.0000E+00 CH4,gas 3 4.809 0.0000E+00 pargasite 126 65.279 0.0000E+00 H2,gas 4 8.287 0.0000E+00 periclase 127 16.149 0.0000E+00 H2S,gas 5 -5.943 0.0000E+00 periclase-Fe 128 11.639 0.0000E+00 S2,gas 6 -7.033 0.0000E+00 perovskite-Al 129 12.395 0.0000E+00 CO,gas 7 3.510 0.0000E+00 perovskite-Ca 130 23.818 0.0000E+00 SO3,gas 8 17.427 0.0000E+00 perovskite-Fe 131 21.158 0.0000E+00 SO2,gas 9 1.136 0.0000E+00 perovskite-Mg 132 23.132 0.0000E+00 HCl,gas 10 5.479 0.0000E+00 phase_A 133 80.267 0.0000E+00 acmite 11 7.737 0.0000E+00 phlogopite-Na 134 29.731 0.0000E+00 akermanite 12 36.495 0.0000E+00 piemontite(ordered) 135 33.876 0.0000E+00 akimotoite 13 16.606 0.0000E+00 prehnite 136 19.466 0.0000E+00 akimotoite-Fe 14 13.083 0.0000E+00 prehnite-Fe 137 22.587 0.0000E+00 albite-high 15 0.750 0.0000E+00 pumpellyite-Fe 138 46.471 0.0000E+00 albite 16 -0.328 0.0000E+00 pumpellyite-Mg 139 49.194 0.0000E+00 almandine 17 24.545 0.0000E+00 px-Mg-tschermaks 140 19.687 0.0000E+00 pyrope 18 37.348 0.0000E+00 px-Ca-tschermaks 141 18.679 0.0000E+00 spessartine 19 24.550 0.0000E+00 pyrite 142 -21.225 0.0000E+00 analcite 20 3.371 0.0000E+00 pyrrhotite 143 -4.244 0.0000E+00 andalusite 21 5.062 0.0000E+00 pyrrhotiteFe0.875 144 -6.001 0.0000E+00 andradite 22 39.088 0.0000E+00 pyroxmangite 145 7.416 0.0000E+00 grossular 23 32.828 0.0000E+00 pyrophyllite 146 -6.098 0.0000E+00 anhydrite 24 -5.280 0.0000E+00 quartz 147 -2.982 0.0000E+00 ankerite 25 -2.093 0.0000E+00 rankinite 148 40.765 0.0000E+00 annite 26 20.209 0.0000E+00 riebeckite 149 20.593 0.0000E+00 phlogopite 27 27.147 0.0000E+00 ringwoodite-Fe 150 15.486 0.0000E+00 biotite-Mn 28 33.034 0.0000E+00 ringwoodite-Mg 151 27.602 0.0000E+00 anorthite 29 12.798 0.0000E+00 rhodochrosite 152 -0.959 0.0000E+00 anthophyllite 30 51.988 0.0000E+00 rhodonite 153 7.462 0.0000E+00 anthophyllite-Fe 31 29.455 0.0000E+00 sanidine 154 -1.221 0.0000E+00 apatite-OH 32 -17.989 0.1537E-06 sapphirine(351) 155 79.204 0.0000E+00 apatite-OH-zs 33 -12.572 0.0000E+00 siderite 156 -2.588 0.0000E+00 apatite-Cl-zs 34 -16.504 0.0000E+00 sillimanite 157 5.321 0.0000E+00 aragonite 35 0.986 0.0000E+00 sodalite 158 50.255 0.0000E+00 brucite 36 12.577 0.0000E+00 spinel 159 20.934 0.0000E+00 calcite 37 0.833 0.0000E+00 spurrite 160 59.566 0.0000E+00 carnegieite-low 38 9.065 0.0000E+00 staurolite-Fe 161 74.138 0.0000E+00 carnegieite-high 39 10.134 0.0000E+00 staurolite-Mg 162 90.336 0.0000E+00 carpholite-Mg 40 8.650 0.0000E+00 staurolite-Mn 163 84.438 0.0000E+00 carpholite-Fe 41 6.783 0.0000E+00 stilbite 164 -7.406 0.2571E-04 celadonite 42 5.401 0.0000E+00 stilpnomelane-Fe 165 13.179 0.0000E+00 celadonite-Fe 43 3.937 0.0000E+00 stilpnomelane-Mg 166 27.596 0.0000E+00 chrysotile 44 23.937 0.0000E+00 stishovite 167 2.721 0.0000E+00 chondrodite 45 56.542 0.0000E+00 sudoite-Fe 168 18.437 0.0000E+00 clinochlore 46 39.193 0.1253E-04 sudoite 169 21.216 0.0000E+00 daphnite 47 29.094 0.7762E-05 sulfur 170 -9.141 0.0000E+00 chlorite-Mn 48 46.985 0.2647E-06 sylvite 171 1.345 0.0000E+00 chlorite-Al-free 49 47.262 0.0000E+00 talc 172 16.553 0.0000E+00 chloritoid-Mg 50 13.261 0.0000E+00 talc-Fe 173 13.516 0.0000E+00 chloritoid-Fe 51 9.239 0.0000E+00 talc-tschermaks 174 19.189 0.0000E+00 chloritoid-Mn 52 11.463 0.0000E+00 tephroite 175 18.113 0.0000E+00 clinohumite 53 97.255 0.0000E+00 tilleyite 176 41.473 0.0000E+00 coesite 54 -2.369 0.0000E+00 titanite-CaSi 177 15.497 0.0000E+00 cordierite-H 55 23.898 0.0000E+00 topaz-H 178 4.668 0.0000E+00 cordierite 56 24.245 0.0000E+00 tridymite 179 -2.615 0.0000E+00 cordierite-Fe 57 20.649 0.0000E+00 tremolite 180 48.003 0.0000E+00 cordierite-Mn 58 25.261 0.0000E+00 ferroactinolite 181 38.596 0.0000E+00 corundum 59 8.433 0.0000E+00 troilite-low 182 -4.394 0.0000E+00 corundum-MgSi 60 18.905 0.0000E+00 tschermakite 183 48.414 0.0000E+00 cristobalite 61 -2.549 0.0000E+00 vesuvianite 184 224.056 0.0000E+00 cummingtonite 62 52.233 0.0000E+00 wadeite-Si 185 20.233 0.0000E+00 cymrite-K 63 1.731 0.0000E+00 wadsleyite-Fe 186 15.711 0.0000E+00 deerite 64 95.982 0.0000E+00 wadsleyite-Mg 187 25.878 0.0000E+00 diaspore 65 2.896 0.0000E+00 wairakite 188 4.058 0.0000E+00 diamond 66 -3.107 0.0000E+00 walstromite 189 11.528 0.0000E+00 diopside 67 16.215 0.0000E+00 wollastonite 190 10.482 0.0000E+00 hedenbergite 68 14.244 0.0000E+00 pseudo-wollastonite 191 11.020 0.0000E+00 dolomite,ordered 69 0.587 0.0000E+00 zoisite 192 22.964 0.0000E+00 eastonite 70 28.605 0.0000E+00 akaganeite 193 7.768 0.0000E+00 enstatite 71 17.301 0.0000E+00 beidellite-Ca 194 -1.560 0.0000E+00 clinoenstatite-HiP 72 18.388 0.0000E+00 beidellite-H 195 -2.241 0.0000E+00 clinoenstatite 73 17.202 0.0000E+00 beidellite-K 196 -1.435 0.0000E+00 protoenstatite 74 17.860 0.0000E+00 beidellite-Mg 197 -1.707 0.0000E+00 epidote 75 24.775 0.0000E+00 beidellite-Na 198 -1.257 0.0000E+00 clinozoisite 76 22.921 0.0000E+00 calcium 199 84.043 0.0000E+00 epidote-Fe 77 29.937 0.0000E+00 chalcedony 200 -2.794 0.0000E+00 fayalite 78 14.079 0.0000E+00 dawsonite 201 1.714 0.0000E+00 ferrosilite 79 11.188 0.0000E+00 montmorillonite-Ca 202 -2.214 0.0000E+00 forsterite 80 21.047 0.0000E+00 montmorillonite-K 203 -2.161 0.0000E+00 gedrite 81 50.725 0.0000E+00 montmorillonite-Mg 204 -2.402 0.0000E+00 gehlenite 82 36.717 0.0000E+00 montmorillonite-Na 205 -1.961 0.0000E+00 gibbsite 83 4.097 0.0000E+00 nontronite-Ca 206 3.280 0.0000E+00 glaucophane 84 23.111 0.0000E+00 nontronite-H 207 2.596 0.0000E+00 glaucophane-Fe 85 17.417 0.0000E+00 nontronite-K 208 3.404 0.0000E+00 graphite 86 -3.549 0.0000E+00 nontronite-Mg 209 3.139 0.0000E+00 greenalite 87 16.194 0.0000E+00 nontronite-Na 210 3.583 0.0000E+00 grunerite 88 31.364 0.0000E+00 sepiolite 211 24.194 0.0000E+00 halite 89 1.582 0.0000E+00 alite 212 58.043 0.0000E+00 hematite 90 12.598 0.8758E-05 belite 213 30.461 0.0000E+00 heulandite 91 -5.707 0.0000E+00 ettringite 214 43.354 0.0000E+00 hercynite 92 17.345 0.0000E+00 gypsum 215 -4.924 0.0000E+00 hollandite 93 25.702 0.0000E+00 hemicarboaluminate 216 71.028 0.0000E+00 iron 94 19.095 0.0000E+00 hydrogarnet 217 60.721 0.0000E+00 jadeite 95 4.251 0.0000E+00 hydrogarnet-Si 218 50.654 0.0000E+00 julgoldite 96 70.573 0.0000E+00 jennite 219 24.386 0.0000E+00 kalsilite 97 7.620 0.0000E+00 monosulfoaluminate 220 53.497 0.0000E+00 kaolinite 98 -1.273 0.1380E-04 monocarboaluminate 221 61.966 0.0000E+00 kyanite 99 4.932 0.0000E+00 portlandite 222 18.282 0.0000E+00 larnite-bredigite 100 30.714 0.0000E+00 stratlingite 223 36.573 0.0000E+00 laumontite 101 2.975 0.0000E+00 tricarboaluminate 224 70.427 0.0000E+00 lawsonite 102 9.678 0.6704E-04 tobermorite 225 9.839 0.0000E+00 leucite 103 4.168 0.0000E+00 C4AH13 226 81.870 0.0000E+00 lime 104 26.009 0.0000E+00 C2AH8 227 45.260 0.0000E+00 lizardite 105 23.287 0.0000E+00 C3A 228 87.049 0.0000E+00 magnesite 106 0.709 0.0000E+00 C4AF 229 117.550 0.0000E+00 magnetite 107 20.133 0.0000E+00 CAH10 230 28.373 0.0000E+00 minnesotaite 108 10.461 0.0000E+00 alabandite 231 -0.962 0.0000E+00 minnesotaite-Mg 109 20.669 0.0000E+00 alunite 232 -10.224 0.0000E+00 magnesioferrite 110 26.257 0.0000E+00 artinite 233 15.139 0.0000E+00 majorite 111 53.314 0.0000E+00 boehmite 234 4.430 0.0000E+00 manganosite 112 14.068 0.0000E+00 dolomite,disordered 235 1.288 0.0000E+00 margarite 113 17.452 0.0000E+00 ferrous-oxide 236 9.824 0.0000E+00 meionite 114 45.158 0.0000E+00 huntite 237 3.850 0.0000E+00 merwinite 115 55.988 0.0000E+00 hydromagnesite 238 20.077 0.0000E+00 microcline 116 -2.432 0.0000E+00 nesquehonite 239 4.735 0.0000E+00 monticellite 117 24.371 0.0000E+00 potassium-oxide 240 69.039 0.0000E+00 mullite-Al 118 363.258 0.0000E+00 silica-amorphous 241 -2.080 0.0000E+00 mullite-Si 119 7.324 0.0000E+00 sodium-oxide 242 55.173 0.0000E+00 muscovite 120 2.679 0.0000E+00 an20ab80 243 2.079 0.0000E+00 paragonite 121 4.337 0.0000E+00 an25ab75 244 2.709 0.0000E+00 nepheline 122 8.378 0.0000E+00 an30ab70 245 3.344 0.0000E+00 osumilite(1) 123 21.978 0.0000E+00 tr.625ac.25prg.125 246 45.308 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 0.0790000 g log = -1.1024 Original solution: 1000.0103000 g Original solution / Rock added: 12658.36 (Water/Rock Ratio), log = 4.1024 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0790000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3036186E-03 Osmotic coef. = 0.9896 True ionic strength = .3367011E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11234E-07 -7.9495 0.10769E-07 -7.9678 0.95862E+00 -0.0184 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13224E-03 -3.8787 0.95848E+00 -0.0184 4 SO4-- 0.25426E-04 -4.5947 0.22647E-04 -4.6450 0.89072E+00 -0.0503 5 HCO3- 0.12673E-04 -4.8971 0.12147E-04 -4.9155 0.95851E+00 -0.0184 6 HS- 0.48550E-12 -12.3138 0.46534E-12 -12.3322 0.95848E+00 -0.0184 7 Al+++ 0.95583E-21 -21.0196 0.75310E-21 -21.1231 0.78790E+00 -0.1035 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.11648E-04 -4.9338 0.10373E-04 -4.9841 0.89056E+00 -0.0503 10 Mg++ 0.47465E-07 -7.3236 0.42266E-07 -7.3740 0.89046E+00 -0.0504 11 Fe++ 0.28095E-09 -9.5514 0.25018E-09 -9.6017 0.89048E+00 -0.0504 12 K+ 0.16767E-04 -4.7756 0.16071E-04 -4.7940 0.95852E+00 -0.0184 13 Na+ 0.25908E-03 -3.5866 0.24832E-03 -3.6050 0.95847E+00 -0.0184 14 Mn++ 0.36272E-07 -7.4404 0.32300E-07 -7.4908 0.89050E+00 -0.0504 15 HPO4-- 0.54587E-08 -8.2629 0.48622E-08 -8.3132 0.89072E+00 -0.0503 16 HSiO3- 0.36198E-04 -4.4413 0.34695E-04 -4.4597 0.95848E+00 -0.0184 17 Ca(HSiO3)+ 0.84122E-08 -8.0751 0.80633E-08 -8.0935 0.95852E+00 -0.0184 18 Mg(HSiO3)+ 0.42658E-10 -10.3700 0.40889E-10 -10.3884 0.95852E+00 -0.0184 19 NaHSiO3,aq 0.13684E-06 -6.8638 0.13684E-06 -6.8638 0.10000E+01 0.0000 20 AlO+ 0.87454E-12 -12.0582 0.83826E-12 -12.0766 0.95852E+00 -0.0184 21 AlOH+2 0.50782E-16 -16.2943 0.45223E-16 -16.3446 0.89052E+00 -0.0504 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.33695E-05 -5.4724 0.32295E-05 -5.4909 0.95843E+00 -0.0184 24 CH4,aq 0.24494E-18 -18.6109 0.24491E-18 -18.6110 0.99991E+00 0.0000 29 CO,aq 0.30066E-17 -17.5219 0.30066E-17 -17.5219 0.10000E+01 0.0000 30 CO2,aq 0.26378E-06 -6.5788 0.26375E-06 -6.5788 0.99991E+00 0.0000 31 CO3-2 0.11709E-06 -6.9315 0.10429E-06 -6.9818 0.89067E+00 -0.0503 32 CaCO3,aq 0.13249E-07 -7.8778 0.13249E-07 -7.8778 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.33122E-08 -8.4799 0.31748E-08 -8.4983 0.95852E+00 -0.0184 34 CaCl+ 0.22803E-08 -8.6420 0.21857E-08 -8.6604 0.95852E+00 -0.0184 35 CaCl2,aq 0.67297E-13 -13.1720 0.67297E-13 -13.1720 0.10000E+01 0.0000 36 CaOH+ 0.70856E-07 -7.1496 0.67917E-07 -7.1680 0.95852E+00 -0.0184 37 CaSO4,aq 0.73194E-07 -7.1355 0.73194E-07 -7.1355 0.10000E+01 0.0000 38 HCl,aq 0.26787E-12 -12.5721 0.26787E-12 -12.5721 0.10000E+01 0.0000 43 FeCl+ 0.53757E-13 -13.2696 0.51527E-13 -13.2880 0.95852E+00 -0.0184 46 FeO,aq 0.85301E-10 -10.0690 0.85301E-10 -10.0690 0.10000E+01 0.0000 47 FeOH+ 0.80349E-09 -9.0950 0.77016E-09 -9.1134 0.95852E+00 -0.0184 48 HFeO2- 0.88886E-10 -10.0512 0.85195E-10 -10.0696 0.95848E+00 -0.0184 49 FeO+ 0.92941E-13 -13.0318 0.89086E-13 -13.0502 0.95852E+00 -0.0184 50 FeOH+2 0.20047E-18 -18.6979 0.17853E-18 -18.7483 0.89052E+00 -0.0504 51 FeO2- 0.15751E-09 -9.8027 0.15097E-09 -9.8211 0.95848E+00 -0.0184 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44264E-09 -9.3540 0.44259E-09 -9.3540 0.99991E+00 0.0000 54 KCl,aq 0.37629E-10 -10.4245 0.37629E-10 -10.4245 0.10000E+01 0.0000 55 KHSO4,aq 0.10489E-16 -16.9793 0.10489E-16 -16.9793 0.10000E+01 0.0000 56 KOH,aq 0.65056E-09 -9.1867 0.65056E-09 -9.1867 0.10000E+01 0.0000 57 KSO4- 0.58503E-08 -8.2328 0.56074E-08 -8.2512 0.95848E+00 -0.0184 58 MgCO3,aq 0.13490E-10 -10.8700 0.13490E-10 -10.8700 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13762E-10 -10.8613 0.13192E-10 -10.8797 0.95852E+00 -0.0184 60 MgCl+ 0.84350E-11 -11.0739 0.80851E-11 -11.0923 0.95852E+00 -0.0184 61 MgOH+ 0.15995E-08 -8.7960 0.15331E-08 -8.8144 0.95852E+00 -0.0184 63 MnO,aq 0.29399E-09 -9.5317 0.29399E-09 -9.5317 0.10000E+01 0.0000 64 MnOH+ 0.96367E-08 -8.0161 0.92370E-08 -8.0345 0.95852E+00 -0.0184 65 MnO2-2 0.98424E-16 -16.0069 0.87664E-16 -16.0572 0.89067E+00 -0.0503 66 HMnO2- 0.21341E-12 -12.6708 0.20455E-12 -12.6892 0.95848E+00 -0.0184 69 MnCl+ 0.26969E-10 -10.5691 0.25851E-10 -10.5875 0.95852E+00 -0.0184 70 MnSO4,aq 0.20731E-09 -9.6834 0.20731E-09 -9.6834 0.10000E+01 0.0000 71 NaCl,aq 0.10722E-07 -7.9697 0.10722E-07 -7.9697 0.10000E+01 0.0000 72 NaOH,aq 0.10132E-07 -7.9943 0.10132E-07 -7.9943 0.10000E+01 0.0000 74 OH- 0.58114E-04 -4.2357 0.55698E-04 -4.2542 0.95843E+00 -0.0184 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.95778E-09 -9.0187 0.91803E-09 -9.0371 0.95850E+00 -0.0184 84 PO4-3 0.49981E-12 -12.3012 0.39429E-12 -12.4042 0.78886E+00 -0.1030 87 H2P2O7-2 0.74057E-19 -19.1304 0.65961E-19 -19.1807 0.89067E+00 -0.0503 88 HP2O7-3 0.15940E-17 -17.7975 0.12559E-17 -17.9010 0.78791E+00 -0.1035 89 P2O7-4 0.43317E-19 -19.3633 0.28770E-19 -19.5411 0.66416E+00 -0.1777 90 H2S,aq 0.15059E-13 -13.8222 0.15057E-13 -13.8223 0.99991E+00 0.0000 97 SO3-2 0.15339E-14 -14.8142 0.13667E-14 -14.8643 0.89099E+00 -0.0501 98 HSO3- 0.89867E-15 -15.0464 0.86135E-15 -15.0648 0.95848E+00 -0.0184 99 HSO4- 0.23609E-09 -9.6269 0.22630E-09 -9.6453 0.95854E+00 -0.0184 Charge balance for all species = 0.7206E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1123432E-07 -.1079313E-03 -.1087824E+00 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999445E+06 0.0000 3 Cl- 0.1379642E-03 0.1379772E-03 0.4891444E+01 4.0892 4 SO4-- 0.2542555E-04 0.2550497E-04 0.2449916E+01 11.2906 5 HCO3- 0.1267284E-04 0.1307029E-04 0.7974696E+00 3.0523 6 HS- 0.4854965E-12 0.6602635E-10 0.2183506E-05 -4.3644 7 Al+++ 0.9558257E-21 0.3385095E-05 0.9133003E-01 2.7803 8 H4SiO4 0.3829605E-03 0.4193036E-03 0.4029936E+02 -3.4168 9 Ca++ 0.1164759E-04 0.1181889E-04 0.4736521E+00 10.9515 10 Mg++ 0.4746509E-07 0.4914291E-07 0.1194698E-02 8.5616 11 Fe++ 0.2809509E-09 0.1619748E-08 0.9045321E-04 6.3339 12 K+ 0.1676666E-04 0.1677320E-04 0.6558302E+00 3.1739 13 Na+ 0.2590833E-03 0.2592410E-03 0.5959578E+01 4.3628 14 Mn++ 0.3627190E-07 0.4643706E-07 0.2551022E-02 8.4448 15 HPO4-- 0.5458726E-08 0.6417013E-08 0.6158654E-03 7.6224 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1295083E-02 -.1079289E-03 -.1187154E-02 0.0000000E+00 2 H2O 0.5550726E+02 0.5550705E+02 0.2117590E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2769383E-04 0.2550440E-04 0.2189425E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2189359E-05 0.6602489E-10 -.2189425E-05 0.0000000E+00 7 Al+++ 0.2575986E-03 0.3385020E-05 0.2542136E-03 0.0000000E+00 8 H4SiO4 0.8226099E-03 0.4192943E-03 0.4033156E-03 0.0000000E+00 9 Ca++ 0.1053323E-03 0.1181863E-04 0.9351370E-04 0.0000000E+00 10 Mg++ 0.6269841E-04 0.4914182E-07 0.6264927E-04 0.0000000E+00 11 Fe++ 0.5632768E-04 0.1619712E-08 0.5632606E-04 0.0000000E+00 12 K+ 0.1677282E-04 0.1677282E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2592352E-03 0.2592352E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1369749E-05 0.4643603E-07 0.1323313E-05 0.0000000E+00 15 HPO4-- 0.4674886E-06 0.6416871E-08 0.4610717E-06 0.0000000E+00 Chg. balance for solid moles: 0.7253E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1537E-06 -6.813 0.7720E-04 -4.112 0.1356 0.2453E-04 clinochlore 0.1253E-04 -4.902 0.6964E-02 -2.157 12.24 0.2649E-02 daphnite 0.7762E-05 -5.110 0.5538E-02 -2.257 9.731 0.1678E-02 chlorite-Mn 0.2647E-06 -6.577 0.1876E-03 -3.727 0.3297 0.5980E-04 hematite 0.8758E-05 -5.058 0.1399E-02 -2.854 2.457 0.2651E-03 kaolinite 0.1380E-04 -4.860 0.3564E-02 -2.448 6.262 0.1371E-02 lawsonite 0.6704E-04 -4.174 0.2107E-01 -1.676 37.01 0.6793E-02 stilbite 0.2571E-04 -4.590 0.1812E-01 -1.742 31.83 0.8450E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3776E+00 0.3776E+00 1.0000 -0.423 chlorite-Mn 0.1287E-01 0.1287E-01 1.0000 -1.890 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.056913 g Volume = 0.021292 cm3 Porosity: 97.9361% V(tot) - V(min): 0.10103E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0790000 g log = -1.1024 Original solution: 1000.0103000 g Original solution / Rock added: 12658.36 (Water/Rock Ratio), log = 4.1024 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2849E-04 1.0073 0.3019E-04 0.2997E-04 CH4,gas 0.3635E-15 1.0129 0.3873E-15 0.3824E-15 H2,gas 0.5767E-06 1.0006 0.6071E-06 0.6067E-06 H2S,gas 0.4192E-12 0.9959 0.4392E-12 0.4410E-12 S2,gas 0.1863E-31 1.0000 0.1960E-31 0.1960E-31 CO,gas 0.4513E-14 1.0000 0.4747E-14 0.4747E-14 SO3,gas 0.9335E-36 1.0000 0.9820E-36 0.9820E-36 SO2,gas 0.2144E-19 1.0000 0.2255E-19 0.2255E-19 HCl,gas 0.4496E-15 1.0000 0.4730E-15 0.4730E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.24265E-10 164 stilbite -7.41 -7.41 0.00 0.000 0.15165E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.88 -6.52 -2.173 0.11133E+05 -4.520 3 CH4,gas 4.81 -12.60 -17.41 -4.353 0.29730E+05 -15.412 4 H2,gas 8.29 0.07 -8.22 -4.695 0.14030E+05 -6.217 5 H2S,gas -5.94 -20.30 -14.36 -7.179 0.24515E+05 -12.357 6 S2,gas -7.03 -40.74 -33.71 -5.186 0.57555E+05 -31.708 7 CO,gas 3.51 -12.81 -16.32 -5.023 0.27872E+05 -14.324 8 SO3,gas 17.43 -20.58 -38.01 -9.502 0.64897E+05 -36.008 9 SO2,gas 1.14 -20.51 -21.65 -5.772 0.36961E+05 -19.647 10 HCl,gas 5.48 -11.85 -17.33 -8.663 0.29582E+05 -15.325 11 acmite 7.74 3.83 -3.91 -0.406 0.66753E+04 15 albite-high 0.75 -3.11 -3.86 -0.297 0.65859E+04 16 albite -0.33 -3.11 -2.78 -0.214 0.47452E+04 19 spessartine 24.55 20.64 -3.91 -0.195 0.66684E+04 20 analcite 3.37 0.31 -3.06 -0.340 0.52270E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -9.63 -4.35 -2.175 0.74264E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.93 -2.92 -0.973 0.49825E+04 36 brucite 12.58 8.56 -4.01 -0.803 0.68555E+04 37 calcite 0.83 -1.93 -2.76 -0.922 0.47211E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23254E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29405E+04 42 celadonite 5.40 0.85 -4.55 -0.268 0.77727E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43642E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.12996E+04 52 chloritoid-Mn 11.46 10.59 -0.87 -0.058 0.14935E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60377E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64760E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82438E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68748E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.31 -3.94 -0.394 0.67300E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 105 lizardite 23.29 18.85 -4.44 -0.370 0.75749E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20512E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -4.30 -1.86 -0.143 0.31838E+04 120 muscovite 2.68 1.26 -1.42 -0.083 0.24162E+04 121 paragonite 4.34 2.45 -1.88 -0.111 0.32160E+04 122 nepheline 8.38 3.73 -4.65 -0.665 0.79429E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50034E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58499E+04 145 pyroxmangite 7.42 5.03 -2.39 -0.478 0.40775E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.44 -3.48 -1.160 0.59420E+04 153 rhodonite 7.46 5.03 -2.43 -0.487 0.41568E+04 154 sanidine -1.22 -4.30 -3.08 -0.237 0.52515E+04 156 siderite -2.59 -6.55 -3.96 -1.321 0.67647E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.48 -1.70 -0.051 0.28981E+04 166 stilpnomelane-Mg 27.60 22.62 -4.98 -0.149 0.84956E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83644E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55022E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77450E+04 175 tephroite 18.11 13.47 -4.64 -0.663 0.79229E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -5.01 -3.58 -0.219 0.61117E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.62 -3.37 -0.206 0.57457E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -5.15 -2.99 -0.183 0.51064E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40718E+04 205 montmorillonite-Na -1.96 -4.76 -2.80 -0.171 0.47786E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.02 -1.38 -0.089 0.23583E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.41 -1.17 -0.075 0.19940E+04 215 gypsum -4.92 -9.63 -4.70 -1.176 0.80331E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59597E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.55 -2.63 -0.202 0.44898E+04 244 an25ab75 2.71 0.09 -2.62 -0.202 0.44738E+04 245 an30ab70 3.34 0.73 -2.62 -0.201 0.44662E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.0790000 g New total amount of reactant added: 0.0830000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0830000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3053543E-03 Osmotic coef. = 0.9896 True ionic strength = .3398611E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10792E-07 -7.9669 0.10345E-07 -7.9853 0.95851E+00 -0.0184 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13222E-03 -3.8787 0.95837E+00 -0.0185 4 SO4-- 0.25431E-04 -4.5946 0.22642E-04 -4.6451 0.89032E+00 -0.0505 5 HCO3- 0.12679E-04 -4.8969 0.12152E-04 -4.9154 0.95840E+00 -0.0185 6 HS- 0.46590E-12 -12.3317 0.44650E-12 -12.3502 0.95837E+00 -0.0185 7 Al+++ 0.84795E-21 -21.0716 0.66743E-21 -21.1756 0.78711E+00 -0.1040 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.10751E-04 -4.9685 0.95706E-05 -5.0191 0.89016E+00 -0.0505 10 Mg++ 0.43813E-07 -7.3584 0.38996E-07 -7.4090 0.89006E+00 -0.0506 11 Fe++ 0.25931E-09 -9.5862 0.23081E-09 -9.6368 0.89009E+00 -0.0506 12 K+ 0.17616E-04 -4.7541 0.16883E-04 -4.7726 0.95841E+00 -0.0184 13 Na+ 0.26410E-03 -3.5782 0.25310E-03 -3.5967 0.95837E+00 -0.0185 14 Mn++ 0.33607E-07 -7.4736 0.29914E-07 -7.5241 0.89010E+00 -0.0506 15 HPO4-- 0.59190E-08 -8.2278 0.52698E-08 -8.2782 0.89033E+00 -0.0505 16 HSiO3- 0.37689E-04 -4.4238 0.36120E-04 -4.4423 0.95837E+00 -0.0185 17 Ca(HSiO3)+ 0.80812E-08 -8.0925 0.77452E-08 -8.1110 0.95841E+00 -0.0184 18 Mg(HSiO3)+ 0.40979E-10 -10.3874 0.39275E-10 -10.4059 0.95841E+00 -0.0184 19 NaHSiO3,aq 0.14520E-06 -6.8380 0.14520E-06 -6.8380 0.10000E+01 0.0000 20 AlO+ 0.84013E-12 -12.0757 0.80519E-12 -12.0941 0.95841E+00 -0.0184 21 AlOH+2 0.46875E-16 -16.3291 0.41725E-16 -16.3796 0.89013E+00 -0.0505 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.35083E-05 -5.4549 0.33621E-05 -5.4734 0.95832E+00 -0.0185 24 CH4,aq 0.23516E-18 -18.6286 0.23514E-18 -18.6287 0.99991E+00 0.0000 29 CO,aq 0.28884E-17 -17.5393 0.28884E-17 -17.5393 0.10000E+01 0.0000 30 CO2,aq 0.25347E-06 -6.5961 0.25344E-06 -6.5961 0.99991E+00 0.0000 31 CO3-2 0.12200E-06 -6.9137 0.10861E-06 -6.9641 0.89028E+00 -0.0505 32 CaCO3,aq 0.12731E-07 -7.8951 0.12731E-07 -7.8951 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.30575E-08 -8.5146 0.29304E-08 -8.5331 0.95841E+00 -0.0184 34 CaCl+ 0.21039E-08 -8.6770 0.20164E-08 -8.6954 0.95841E+00 -0.0184 35 CaCl2,aq 0.62078E-13 -13.2071 0.62078E-13 -13.2071 0.10000E+01 0.0000 36 CaOH+ 0.68068E-07 -7.1671 0.65237E-07 -7.1855 0.95841E+00 -0.0184 37 CaSO4,aq 0.67517E-07 -7.1706 0.67517E-07 -7.1706 0.10000E+01 0.0000 38 HCl,aq 0.25727E-12 -12.5896 0.25727E-12 -12.5896 0.10000E+01 0.0000 43 FeCl+ 0.49594E-13 -13.3046 0.47531E-13 -13.3230 0.95841E+00 -0.0184 46 FeO,aq 0.85292E-10 -10.0691 0.85292E-10 -10.0691 0.10000E+01 0.0000 47 FeOH+ 0.77179E-09 -9.1125 0.73970E-09 -9.1309 0.95841E+00 -0.0184 48 HFeO2- 0.92537E-10 -10.0337 0.88685E-10 -10.0522 0.95837E+00 -0.0185 49 FeO+ 0.89284E-13 -13.0492 0.85571E-13 -13.0677 0.95841E+00 -0.0184 50 FeOH+2 0.18505E-18 -18.7327 0.16472E-18 -18.7833 0.89013E+00 -0.0505 51 FeO2- 0.16399E-09 -9.7852 0.15717E-09 -9.8036 0.95837E+00 -0.0185 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44254E-09 -9.3540 0.44250E-09 -9.3541 0.99991E+00 0.0000 54 KCl,aq 0.39526E-10 -10.4031 0.39526E-10 -10.4031 0.10000E+01 0.0000 55 KHSO4,aq 0.10582E-16 -16.9754 0.10582E-16 -16.9754 0.10000E+01 0.0000 56 KOH,aq 0.71149E-09 -9.1478 0.71149E-09 -9.1478 0.10000E+01 0.0000 57 KSO4- 0.61451E-08 -8.2115 0.58892E-08 -8.2299 0.95837E+00 -0.0185 58 MgCO3,aq 0.12962E-10 -10.8873 0.12962E-10 -10.8873 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12704E-10 -10.8961 0.12176E-10 -10.9145 0.95841E+00 -0.0184 60 MgCl+ 0.77824E-11 -11.1089 0.74588E-11 -11.1273 0.95841E+00 -0.0184 61 MgOH+ 0.15365E-08 -8.8135 0.14726E-08 -8.8319 0.95841E+00 -0.0184 63 MnO,aq 0.29510E-09 -9.5300 0.29510E-09 -9.5300 0.10000E+01 0.0000 64 MnOH+ 0.92923E-08 -8.0319 0.89059E-08 -8.0503 0.95841E+00 -0.0184 65 MnO2-2 0.10712E-15 -15.9701 0.95370E-16 -16.0206 0.89028E+00 -0.0505 66 HMnO2- 0.22304E-12 -12.6516 0.21375E-12 -12.6701 0.95837E+00 -0.0185 69 MnCl+ 0.24977E-10 -10.6025 0.23938E-10 -10.6209 0.95841E+00 -0.0184 70 MnSO4,aq 0.19195E-09 -9.7168 0.19195E-09 -9.7168 0.10000E+01 0.0000 71 NaCl,aq 0.10927E-07 -7.9615 0.10927E-07 -7.9615 0.10000E+01 0.0000 72 NaOH,aq 0.10751E-07 -7.9686 0.10751E-07 -7.9686 0.10000E+01 0.0000 74 OH- 0.60507E-04 -4.2182 0.57986E-04 -4.2367 0.95832E+00 -0.0185 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.99723E-09 -9.0012 0.95574E-09 -9.0197 0.95839E+00 -0.0185 84 PO4-3 0.56452E-12 -12.2483 0.44489E-12 -12.3517 0.78808E+00 -0.1034 87 H2P2O7-2 0.80301E-19 -19.0953 0.71490E-19 -19.1458 0.89028E+00 -0.0505 88 HP2O7-3 0.18004E-17 -17.7446 0.14171E-17 -17.8486 0.78712E+00 -0.1040 89 P2O7-4 0.50975E-19 -19.2926 0.33795E-19 -19.4711 0.66298E+00 -0.1785 90 H2S,aq 0.13879E-13 -13.8576 0.13878E-13 -13.8577 0.99991E+00 0.0000 97 SO3-2 0.15339E-14 -14.8142 0.13661E-14 -14.8645 0.89060E+00 -0.0503 98 HSO3- 0.86293E-15 -15.0640 0.82700E-15 -15.0825 0.95837E+00 -0.0185 99 HSO4- 0.22675E-09 -9.6445 0.21732E-09 -9.6629 0.95844E+00 -0.0184 Charge balance for all species = 0.7205E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1079229E-07 -.1123918E-03 -.1132780E+00 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999442E+06 0.0000 3 Cl- 0.1379642E-03 0.1379773E-03 0.4891446E+01 4.1066 4 SO4-- 0.2543097E-04 0.2550499E-04 0.2449918E+01 11.3255 5 HCO3- 0.1267902E-04 0.1307030E-04 0.7974700E+00 3.0699 6 HS- 0.4658956E-12 0.6517192E-10 0.2155249E-05 -4.3649 7 Al+++ 0.8479524E-21 0.3523886E-05 0.9507460E-01 2.7803 8 H4SiO4 0.3829605E-03 0.4208026E-03 0.4044342E+02 -3.4168 9 Ca++ 0.1075147E-04 0.1091302E-04 0.4373485E+00 10.9515 10 Mg++ 0.4381271E-07 0.4542366E-07 0.1104280E-02 8.5616 11 Fe++ 0.2593086E-09 0.1576534E-08 0.8803993E-04 6.3338 12 K+ 0.1761559E-04 0.1762249E-04 0.6890371E+00 3.2127 13 Na+ 0.2640954E-03 0.2642623E-03 0.6075008E+01 4.3886 14 Mn++ 0.3360711E-07 0.4341167E-07 0.2384821E-02 8.4464 15 HPO4-- 0.5918983E-08 0.6916786E-08 0.6638303E-03 7.6924 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1361317E-02 -.1123892E-03 -.1248928E-02 0.0000000E+00 2 H2O 0.5550721E+02 0.5550701E+02 0.2035843E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2780468E-04 0.2550440E-04 0.2300278E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2300213E-05 0.6517043E-10 -.2300278E-05 0.0000000E+00 7 Al+++ 0.2706416E-03 0.3523806E-05 0.2671177E-03 0.0000000E+00 8 H4SiO4 0.8642610E-03 0.4207929E-03 0.4434680E-03 0.0000000E+00 9 Ca++ 0.1099329E-03 0.1091277E-04 0.9902013E-04 0.0000000E+00 10 Mg++ 0.6587302E-04 0.4542261E-07 0.6582759E-04 0.0000000E+00 11 Fe++ 0.5917971E-04 0.1576498E-08 0.5917814E-04 0.0000000E+00 12 K+ 0.1762208E-04 0.1762208E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2642562E-03 0.2642562E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1439103E-05 0.4341067E-07 0.1395693E-05 0.0000000E+00 15 HPO4-- 0.4911589E-06 0.6916627E-08 0.4842422E-06 0.0000000E+00 Chg. balance for solid moles: -.2075E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0830000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1614E-06 -6.792 0.8108E-04 -4.091 0.1321 0.2576E-04 clinochlore 0.1317E-04 -4.881 0.7318E-02 -2.136 11.92 0.2783E-02 daphnite 0.8155E-05 -5.089 0.5819E-02 -2.235 9.480 0.1763E-02 chlorite-Mn 0.2791E-06 -6.554 0.1979E-03 -3.704 0.3224 0.6307E-04 hematite 0.9201E-05 -5.036 0.1469E-02 -2.833 2.394 0.2785E-03 kaolinite 0.1375E-04 -4.862 0.3549E-02 -2.450 5.781 0.1365E-02 lawsonite 0.6726E-04 -4.172 0.2114E-01 -1.675 34.43 0.6816E-02 stilbite 0.3095E-04 -4.509 0.2181E-01 -1.661 35.53 0.1017E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3776E+00 0.3776E+00 1.0000 -0.423 chlorite-Mn 0.1292E-01 0.1292E-01 1.0000 -1.889 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.061382 g Volume = 0.023269 cm3 Porosity: 97.7479% V(tot) - V(min): 0.10099E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0830000 g log = -1.0809 Original solution: 1000.0103000 g Original solution / Rock added: 12048.32 (Water/Rock Ratio), log = 4.0809 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2738E-04 1.0073 0.2901E-04 0.2880E-04 CH4,gas 0.3490E-15 1.0129 0.3718E-15 0.3671E-15 H2,gas 0.5766E-06 1.0006 0.6069E-06 0.6066E-06 H2S,gas 0.3863E-12 0.9959 0.4047E-12 0.4064E-12 S2,gas 0.1583E-31 1.0000 0.1666E-31 0.1666E-31 CO,gas 0.4336E-14 1.0000 0.4561E-14 0.4561E-14 SO3,gas 0.8611E-36 1.0000 0.9058E-36 0.9058E-36 SO2,gas 0.1977E-19 1.0000 0.2080E-19 0.2080E-19 HCl,gas 0.4318E-15 1.0000 0.4543E-15 0.4543E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 164 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.90 -6.54 -2.179 0.11162E+05 -4.537 3 CH4,gas 4.81 -12.62 -17.43 -4.357 0.29761E+05 -15.430 4 H2,gas 8.29 0.07 -8.22 -4.695 0.14030E+05 -6.217 5 H2S,gas -5.94 -20.34 -14.39 -7.196 0.24575E+05 -12.393 6 S2,gas -7.03 -40.81 -33.78 -5.197 0.57676E+05 -31.778 7 CO,gas 3.51 -12.83 -16.34 -5.028 0.27902E+05 -14.341 8 SO3,gas 17.43 -20.62 -38.04 -9.511 0.64957E+05 -36.043 9 SO2,gas 1.14 -20.55 -21.68 -5.782 0.37021E+05 -19.682 10 HCl,gas 5.48 -11.86 -17.34 -8.671 0.29612E+05 -15.343 11 acmite 7.74 3.85 -3.88 -0.404 0.66313E+04 15 albite-high 0.75 -3.08 -3.83 -0.295 0.65419E+04 16 albite -0.33 -3.08 -2.75 -0.212 0.47012E+04 19 spessartine 24.55 20.65 -3.90 -0.195 0.66601E+04 20 analcite 3.37 0.34 -3.04 -0.337 0.51830E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -9.66 -4.38 -2.192 0.74863E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.95 -2.94 -0.978 0.50120E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68555E+04 37 calcite 0.83 -1.95 -2.78 -0.927 0.47507E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23254E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29406E+04 42 celadonite 5.40 0.89 -4.51 -0.265 0.77063E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43642E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.12996E+04 52 chloritoid-Mn 11.46 10.59 -0.87 -0.058 0.14907E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60377E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64760E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82439E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68750E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.34 -3.92 -0.392 0.66860E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 105 lizardite 23.29 18.85 -4.44 -0.370 0.75749E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20513E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -4.26 -1.83 -0.140 0.31174E+04 120 muscovite 2.68 1.30 -1.38 -0.081 0.23498E+04 121 paragonite 4.34 2.48 -1.86 -0.109 0.31721E+04 122 nepheline 8.38 3.75 -4.63 -0.661 0.78990E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50035E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58499E+04 145 pyroxmangite 7.42 5.03 -2.39 -0.477 0.40748E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.45 -3.50 -1.165 0.59688E+04 153 rhodonite 7.46 5.03 -2.43 -0.487 0.41540E+04 154 sanidine -1.22 -4.26 -3.04 -0.234 0.51851E+04 156 siderite -2.59 -6.57 -3.98 -1.326 0.67943E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.50 -1.68 -0.050 0.28652E+04 166 stilpnomelane-Mg 27.60 22.64 -4.96 -0.148 0.84624E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83646E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55022E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77450E+04 175 tephroite 18.11 13.48 -4.64 -0.662 0.79173E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -5.00 -3.57 -0.218 0.60898E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.61 -3.36 -0.206 0.57312E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -5.14 -2.98 -0.182 0.50845E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40718E+04 205 montmorillonite-Na -1.96 -4.75 -2.79 -0.171 0.47641E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.04 -1.37 -0.088 0.23364E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.42 -1.16 -0.074 0.19795E+04 215 gypsum -4.92 -9.66 -4.74 -1.185 0.80930E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59598E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.53 -2.61 -0.201 0.44546E+04 244 an25ab75 2.71 0.11 -2.60 -0.200 0.44408E+04 245 an30ab70 3.34 0.75 -2.60 -0.200 0.44354E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.0830000 g New total amount of reactant added: 0.0870000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0870000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3072608E-03 Osmotic coef. = 0.9895 True ionic strength = .3432405E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10370E-07 -7.9842 0.99382E-08 -8.0027 0.95840E+00 -0.0185 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13220E-03 -3.8788 0.95825E+00 -0.0185 4 SO4-- 0.25436E-04 -4.5946 0.22635E-04 -4.6452 0.88990E+00 -0.0507 5 HCO3- 0.12685E-04 -4.8967 0.12155E-04 -4.9152 0.95829E+00 -0.0185 6 HS- 0.44720E-12 -12.3495 0.42853E-12 -12.3680 0.95826E+00 -0.0185 7 Al+++ 0.75271E-21 -21.1234 0.59183E-21 -21.2278 0.78627E+00 -0.1044 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.99281E-05 -5.0031 0.88335E-05 -5.0539 0.88974E+00 -0.0507 10 Mg++ 0.40457E-07 -7.3930 0.35992E-07 -7.4438 0.88964E+00 -0.0508 11 Fe++ 0.23943E-09 -9.6208 0.21301E-09 -9.6716 0.88966E+00 -0.0508 12 K+ 0.18465E-04 -4.7337 0.17694E-04 -4.7522 0.95830E+00 -0.0185 13 Na+ 0.26911E-03 -3.5701 0.25787E-03 -3.5886 0.95825E+00 -0.0185 14 Mn++ 0.31135E-07 -7.5068 0.27700E-07 -7.5575 0.88968E+00 -0.0508 15 HPO4-- 0.64159E-08 -8.1927 0.57096E-08 -8.2434 0.88990E+00 -0.0507 16 HSiO3- 0.39234E-04 -4.4063 0.37597E-04 -4.4249 0.95825E+00 -0.0185 17 Ca(HSiO3)+ 0.77647E-08 -8.1099 0.74409E-08 -8.1284 0.95830E+00 -0.0185 18 Mg(HSiO3)+ 0.39374E-10 -10.4048 0.37732E-10 -10.4233 0.95830E+00 -0.0185 19 NaHSiO3,aq 0.15398E-06 -6.8125 0.15398E-06 -6.8125 0.10000E+01 0.0000 20 AlO+ 0.80722E-12 -12.0930 0.77356E-12 -12.1115 0.95830E+00 -0.0185 21 AlOH+2 0.43285E-16 -16.3637 0.38511E-16 -16.4144 0.88970E+00 -0.0508 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.36522E-05 -5.4374 0.34996E-05 -5.4560 0.95821E+00 -0.0185 24 CH4,aq 0.22583E-18 -18.6462 0.22581E-18 -18.6463 0.99990E+00 0.0000 29 CO,aq 0.27753E-17 -17.5567 0.27753E-17 -17.5567 0.10000E+01 0.0000 30 CO2,aq 0.24359E-06 -6.6133 0.24356E-06 -6.6134 0.99990E+00 0.0000 31 CO3-2 0.12709E-06 -6.8959 0.11309E-06 -6.9466 0.88985E+00 -0.0507 32 CaCO3,aq 0.12235E-07 -7.9124 0.12235E-07 -7.9124 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.28233E-08 -8.5492 0.27055E-08 -8.5677 0.95830E+00 -0.0185 34 CaCl+ 0.19419E-08 -8.7118 0.18609E-08 -8.7303 0.95830E+00 -0.0185 35 CaCl2,aq 0.57283E-13 -13.2420 0.57283E-13 -13.2420 0.10000E+01 0.0000 36 CaOH+ 0.65402E-07 -7.1844 0.62675E-07 -7.2029 0.95830E+00 -0.0185 37 CaSO4,aq 0.62300E-07 -7.2055 0.62300E-07 -7.2055 0.10000E+01 0.0000 38 HCl,aq 0.24714E-12 -12.6071 0.24714E-12 -12.6071 0.10000E+01 0.0000 43 FeCl+ 0.45770E-13 -13.3394 0.43861E-13 -13.3579 0.95830E+00 -0.0185 46 FeO,aq 0.85284E-10 -10.0691 0.85284E-10 -10.0691 0.10000E+01 0.0000 47 FeOH+ 0.74150E-09 -9.1299 0.71058E-09 -9.1484 0.95830E+00 -0.0185 48 HFeO2- 0.96324E-10 -10.0163 0.92302E-10 -10.0348 0.95825E+00 -0.0185 49 FeO+ 0.85788E-13 -13.0666 0.82210E-13 -13.0851 0.95830E+00 -0.0185 50 FeOH+2 0.17088E-18 -18.7673 0.15203E-18 -18.8181 0.88970E+00 -0.0508 51 FeO2- 0.17072E-09 -9.7677 0.16359E-09 -9.7862 0.95825E+00 -0.0185 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44246E-09 -9.3541 0.44242E-09 -9.3542 0.99990E+00 0.0000 54 KCl,aq 0.41421E-10 -10.3828 0.41421E-10 -10.3828 0.10000E+01 0.0000 55 KHSO4,aq 0.10652E-16 -16.9726 0.10652E-16 -16.9726 0.10000E+01 0.0000 56 KOH,aq 0.77618E-09 -9.1100 0.77618E-09 -9.1100 0.10000E+01 0.0000 57 KSO4- 0.64394E-08 -8.1912 0.61706E-08 -8.2097 0.95825E+00 -0.0185 58 MgCO3,aq 0.12457E-10 -10.9046 0.12457E-10 -10.9046 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11730E-10 -10.9307 0.11241E-10 -10.9492 0.95830E+00 -0.0185 60 MgCl+ 0.71830E-11 -11.1437 0.68834E-11 -11.1622 0.95830E+00 -0.0185 61 MgOH+ 0.14763E-08 -8.8308 0.14148E-08 -8.8493 0.95830E+00 -0.0185 63 MnO,aq 0.29606E-09 -9.5286 0.29606E-09 -9.5286 0.10000E+01 0.0000 64 MnOH+ 0.89575E-08 -8.0478 0.85840E-08 -8.0663 0.95830E+00 -0.0185 65 MnO2-2 0.11650E-15 -15.9337 0.10367E-15 -15.9844 0.88985E+00 -0.0507 66 HMnO2- 0.23294E-12 -12.6328 0.22322E-12 -12.6513 0.95825E+00 -0.0185 69 MnCl+ 0.23128E-10 -10.6359 0.22164E-10 -10.6544 0.95830E+00 -0.0185 70 MnSO4,aq 0.17769E-09 -9.7503 0.17769E-09 -9.7503 0.10000E+01 0.0000 71 NaCl,aq 0.11132E-07 -7.9534 0.11132E-07 -7.9534 0.10000E+01 0.0000 72 NaOH,aq 0.11402E-07 -7.9430 0.11402E-07 -7.9430 0.10000E+01 0.0000 74 OH- 0.62989E-04 -4.2007 0.60356E-04 -4.2193 0.95821E+00 -0.0185 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.10381E-08 -8.9837 0.99482E-09 -9.0023 0.95828E+00 -0.0185 84 PO4-3 0.63731E-12 -12.1956 0.50172E-12 -12.2995 0.78725E+00 -0.1039 87 H2P2O7-2 0.87043E-19 -19.0603 0.77456E-19 -19.1109 0.88985E+00 -0.0507 88 HP2O7-3 0.20325E-17 -17.6920 0.15981E-17 -17.7964 0.78628E+00 -0.1044 89 P2O7-4 0.59951E-19 -19.2222 0.39671E-19 -19.4015 0.66172E+00 -0.1793 90 H2S,aq 0.12797E-13 -13.8929 0.12796E-13 -13.8929 0.99990E+00 0.0000 97 SO3-2 0.15339E-14 -14.8142 0.13655E-14 -14.8647 0.89018E+00 -0.0505 98 HSO3- 0.82875E-15 -15.0816 0.79415E-15 -15.1001 0.95825E+00 -0.0185 99 HSO4- 0.21781E-09 -9.6619 0.20873E-09 -9.6804 0.95832E+00 -0.0185 Charge balance for all species = 0.7206E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1036959E-07 -.1170154E-03 -.1179381E+00 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999440E+06 0.0000 3 Cl- 0.1379643E-03 0.1379775E-03 0.4891449E+01 4.1239 4 SO4-- 0.2543594E-04 0.2550501E-04 0.2449919E+01 11.3602 5 HCO3- 0.1268455E-04 0.1307031E-04 0.7974704E+00 3.0875 6 HS- 0.4471990E-12 0.6429187E-10 0.2126145E-05 -4.3653 7 Al+++ 0.7527071E-21 0.3667765E-05 0.9895642E-01 2.7803 8 H4SiO4 0.3829605E-03 0.4223567E-03 0.4059278E+02 -3.4168 9 Ca++ 0.9928136E-05 0.1008060E-04 0.4039884E+00 10.9515 10 Mg++ 0.4045712E-07 0.4200419E-07 0.1021150E-02 8.5616 11 Fe++ 0.2394296E-09 0.1536856E-08 0.8582414E-04 6.3338 12 K+ 0.1846452E-04 0.1847178E-04 0.7222441E+00 3.2505 13 Na+ 0.2691071E-03 0.2692836E-03 0.6190439E+01 4.4141 14 Mn++ 0.3113486E-07 0.4058949E-07 0.2229784E-02 8.4479 15 HPO4-- 0.6415925E-08 0.7454698E-08 0.7154556E-03 7.7620 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1427551E-02 -.1170126E-03 -.1310538E-02 0.0000000E+00 2 H2O 0.5550716E+02 0.5550696E+02 0.1953831E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2791554E-04 0.2550441E-04 0.2411131E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2411067E-05 0.6429035E-10 -.2411131E-05 0.0000000E+00 7 Al+++ 0.2836845E-03 0.3667678E-05 0.2800168E-03 0.0000000E+00 8 H4SiO4 0.9059121E-03 0.4223467E-03 0.4835654E-03 0.0000000E+00 9 Ca++ 0.1145335E-03 0.1008036E-04 0.1044531E-03 0.0000000E+00 10 Mg++ 0.6904762E-04 0.4200319E-07 0.6900562E-04 0.0000000E+00 11 Fe++ 0.6203175E-04 0.1536820E-08 0.6203021E-04 0.0000000E+00 12 K+ 0.1847134E-04 0.1847134E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2692772E-03 0.2692772E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1508458E-05 0.4058853E-07 0.1467869E-05 0.0000000E+00 15 HPO4-- 0.5148292E-06 0.7454521E-08 0.5073746E-06 0.0000000E+00 Chg. balance for solid moles: 0.1372E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0870000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1691E-06 -6.772 0.8495E-04 -4.071 0.1290 0.2700E-04 clinochlore 0.1380E-04 -4.860 0.7671E-02 -2.115 11.65 0.2918E-02 daphnite 0.8548E-05 -5.068 0.6099E-02 -2.215 9.264 0.1848E-02 chlorite-Mn 0.2936E-06 -6.532 0.2081E-03 -3.682 0.3161 0.6633E-04 hematite 0.9645E-05 -5.016 0.1540E-02 -2.812 2.339 0.2919E-03 kaolinite 0.1376E-04 -4.861 0.3552E-02 -2.450 5.394 0.1367E-02 lawsonite 0.6743E-04 -4.171 0.2119E-01 -1.674 32.18 0.6833E-02 stilbite 0.3618E-04 -4.442 0.2550E-01 -1.594 38.73 0.1189E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3775E+00 0.3775E+00 1.0000 -0.423 chlorite-Mn 0.1297E-01 0.1297E-01 1.0000 -1.887 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.065841 g Volume = 0.025243 cm3 Porosity: 97.5606% V(tot) - V(min): 0.10096E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0870000 g log = -1.0605 Original solution: 1000.0103000 g Original solution / Rock added: 11494.37 (Water/Rock Ratio), log = 4.0605 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2631E-04 1.0073 0.2788E-04 0.2768E-04 CH4,gas 0.3351E-15 1.0129 0.3571E-15 0.3525E-15 H2,gas 0.5765E-06 1.0006 0.6068E-06 0.6065E-06 H2S,gas 0.3562E-12 0.9959 0.3732E-12 0.3747E-12 S2,gas 0.1347E-31 1.0000 0.1417E-31 0.1417E-31 CO,gas 0.4166E-14 1.0000 0.4382E-14 0.4382E-14 SO3,gas 0.7945E-36 1.0000 0.8358E-36 0.8358E-36 SO2,gas 0.1824E-19 1.0000 0.1919E-19 0.1919E-19 HCl,gas 0.4148E-15 1.0000 0.4364E-15 0.4364E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 164 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.92 -6.55 -2.185 0.11192E+05 -4.555 3 CH4,gas 4.81 -12.64 -17.45 -4.362 0.29791E+05 -15.447 4 H2,gas 8.29 0.07 -8.22 -4.695 0.14030E+05 -6.217 5 H2S,gas -5.94 -20.37 -14.43 -7.214 0.24636E+05 -12.428 6 S2,gas -7.03 -40.88 -33.85 -5.207 0.57796E+05 -31.849 7 CO,gas 3.51 -12.85 -16.36 -5.033 0.27931E+05 -14.358 8 SO3,gas 17.43 -20.65 -38.08 -9.519 0.65017E+05 -36.078 9 SO2,gas 1.14 -20.58 -21.72 -5.791 0.37081E+05 -19.717 10 HCl,gas 5.48 -11.88 -17.36 -8.680 0.29642E+05 -15.360 11 acmite 7.74 3.88 -3.86 -0.401 0.65877E+04 15 albite-high 0.75 -3.06 -3.81 -0.293 0.64983E+04 16 albite -0.33 -3.06 -2.73 -0.210 0.46577E+04 19 spessartine 24.55 20.65 -3.90 -0.195 0.66528E+04 20 analcite 3.37 0.36 -3.01 -0.334 0.51394E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -9.70 -4.42 -2.210 0.75459E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.97 -2.95 -0.984 0.50415E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68555E+04 37 calcite 0.83 -1.97 -2.80 -0.933 0.47802E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23254E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29407E+04 42 celadonite 5.40 0.93 -4.48 -0.263 0.76418E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43642E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.12997E+04 52 chloritoid-Mn 11.46 10.59 -0.87 -0.058 0.14883E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60377E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64761E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82441E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68752E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.36 -3.89 -0.389 0.66425E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.80 -4.97 -0.497 0.84870E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75749E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20513E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -4.22 -1.79 -0.138 0.30529E+04 120 muscovite 2.68 1.34 -1.34 -0.079 0.22852E+04 121 paragonite 4.34 2.50 -1.83 -0.108 0.31285E+04 122 nepheline 8.38 3.78 -4.60 -0.657 0.78554E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50036E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.03 -2.39 -0.477 0.40723E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.47 -3.51 -1.171 0.59958E+04 153 rhodonite 7.46 5.03 -2.43 -0.486 0.41516E+04 154 sanidine -1.22 -4.22 -3.00 -0.231 0.51206E+04 156 siderite -2.59 -6.58 -4.00 -1.332 0.68239E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.52 -1.66 -0.050 0.28333E+04 166 stilpnomelane-Mg 27.60 22.66 -4.94 -0.147 0.84302E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83647E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55022E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77451E+04 175 tephroite 18.11 13.48 -4.63 -0.662 0.79125E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.99 -3.55 -0.218 0.60685E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.61 -3.35 -0.205 0.57168E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -5.13 -2.97 -0.182 0.50633E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40718E+04 205 montmorillonite-Na -1.96 -4.74 -2.78 -0.170 0.47497E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.05 -1.36 -0.087 0.23151E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.43 -1.15 -0.074 0.19651E+04 215 gypsum -4.92 -9.70 -4.77 -1.194 0.81526E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59598E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.51 -2.59 -0.199 0.44197E+04 244 an25ab75 2.71 0.13 -2.58 -0.199 0.44082E+04 245 an30ab70 3.34 0.76 -2.58 -0.198 0.44049E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.0870000 g New total amount of reactant added: 0.0910000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0910000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3093286E-03 Osmotic coef. = 0.9895 True ionic strength = .3468269E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.99665E-08 -8.0015 0.95507E-08 -8.0200 0.95828E+00 -0.0185 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13219E-03 -3.8788 0.95813E+00 -0.0186 4 SO4-- 0.25440E-04 -4.5945 0.22628E-04 -4.6454 0.88946E+00 -0.0509 5 HCO3- 0.12689E-04 -4.8966 0.12159E-04 -4.9151 0.95817E+00 -0.0186 6 HS- 0.42940E-12 -12.3671 0.41143E-12 -12.3857 0.95814E+00 -0.0186 7 Al+++ 0.66879E-21 -21.1747 0.52526E-21 -21.2796 0.78538E+00 -0.1049 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.91735E-05 -5.0375 0.81579E-05 -5.0884 0.88929E+00 -0.0510 10 Mg++ 0.37382E-07 -7.4273 0.33239E-07 -7.4783 0.88919E+00 -0.0510 11 Fe++ 0.22121E-09 -9.6552 0.19671E-09 -9.7062 0.88921E+00 -0.0510 12 K+ 0.19313E-04 -4.7141 0.18506E-04 -4.7327 0.95817E+00 -0.0186 13 Na+ 0.27412E-03 -3.5621 0.26264E-03 -3.5806 0.95813E+00 -0.0186 14 Mn++ 0.28850E-07 -7.5399 0.25654E-07 -7.5908 0.88923E+00 -0.0510 15 HPO4-- 0.69507E-08 -8.1580 0.61823E-08 -8.2088 0.88946E+00 -0.0509 16 HSiO3- 0.40832E-04 -4.3890 0.39122E-04 -4.4076 0.95813E+00 -0.0186 17 Ca(HSiO3)+ 0.74629E-08 -8.1271 0.71508E-08 -8.1456 0.95818E+00 -0.0186 18 Mg(HSiO3)+ 0.37842E-10 -10.4220 0.36260E-10 -10.4406 0.95818E+00 -0.0186 19 NaHSiO3,aq 0.16319E-06 -6.7873 0.16319E-06 -6.7873 0.10000E+01 0.0000 20 AlO+ 0.77584E-12 -12.1102 0.74339E-12 -12.1288 0.95818E+00 -0.0186 21 AlOH+2 0.39995E-16 -16.3980 0.35566E-16 -16.4490 0.88926E+00 -0.0510 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.38009E-05 -5.4201 0.36416E-05 -5.4387 0.95809E+00 -0.0186 24 CH4,aq 0.21695E-18 -18.6636 0.21693E-18 -18.6637 0.99990E+00 0.0000 29 CO,aq 0.26674E-17 -17.5739 0.26674E-17 -17.5739 0.10000E+01 0.0000 30 CO2,aq 0.23415E-06 -6.6305 0.23413E-06 -6.6305 0.99990E+00 0.0000 31 CO3-2 0.13234E-06 -6.8783 0.11771E-06 -6.9292 0.88941E+00 -0.0509 32 CaCO3,aq 0.11761E-07 -7.9296 0.11761E-07 -7.9296 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.26084E-08 -8.5836 0.24993E-08 -8.6022 0.95818E+00 -0.0186 34 CaCl+ 0.17934E-08 -8.7463 0.17184E-08 -8.7649 0.95818E+00 -0.0186 35 CaCl2,aq 0.52889E-13 -13.2766 0.52889E-13 -13.2766 0.10000E+01 0.0000 36 CaOH+ 0.62859E-07 -7.2016 0.60230E-07 -7.2202 0.95818E+00 -0.0186 37 CaSO4,aq 0.57517E-07 -7.2402 0.57517E-07 -7.2402 0.10000E+01 0.0000 38 HCl,aq 0.23747E-12 -12.6244 0.23747E-12 -12.6244 0.10000E+01 0.0000 43 FeCl+ 0.42266E-13 -13.3740 0.40499E-13 -13.3926 0.95818E+00 -0.0186 46 FeO,aq 0.85278E-10 -10.0692 0.85278E-10 -10.0692 0.10000E+01 0.0000 47 FeOH+ 0.71261E-09 -9.1471 0.68281E-09 -9.1657 0.95818E+00 -0.0186 48 HFeO2- 0.10024E-09 -9.9990 0.96040E-10 -10.0175 0.95813E+00 -0.0186 49 FeO+ 0.82452E-13 -13.0838 0.79004E-13 -13.1023 0.95818E+00 -0.0186 50 FeOH+2 0.15789E-18 -18.8016 0.14041E-18 -18.8526 0.88926E+00 -0.0510 51 FeO2- 0.17767E-09 -9.7504 0.17023E-09 -9.7690 0.95813E+00 -0.0186 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44239E-09 -9.3542 0.44235E-09 -9.3542 0.99990E+00 0.0000 54 KCl,aq 0.43314E-10 -10.3634 0.43314E-10 -10.3634 0.10000E+01 0.0000 55 KHSO4,aq 0.10702E-16 -16.9705 0.10702E-16 -16.9705 0.10000E+01 0.0000 56 KOH,aq 0.84471E-09 -9.0733 0.84471E-09 -9.0733 0.10000E+01 0.0000 57 KSO4- 0.67333E-08 -8.1718 0.64514E-08 -8.1903 0.95813E+00 -0.0186 58 MgCO3,aq 0.11974E-10 -10.9218 0.11974E-10 -10.9218 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10837E-10 -10.9651 0.10384E-10 -10.9836 0.95818E+00 -0.0186 60 MgCl+ 0.66336E-11 -11.1783 0.63562E-11 -11.1968 0.95818E+00 -0.0186 61 MgOH+ 0.14189E-08 -8.8480 0.13596E-08 -8.8666 0.95818E+00 -0.0186 63 MnO,aq 0.29690E-09 -9.5274 0.29690E-09 -9.5274 0.10000E+01 0.0000 64 MnOH+ 0.86337E-08 -8.0638 0.82727E-08 -8.0824 0.95818E+00 -0.0186 65 MnO2-2 0.12657E-15 -15.8977 0.11257E-15 -15.9486 0.88941E+00 -0.0509 66 HMnO2- 0.24311E-12 -12.6142 0.23293E-12 -12.6328 0.95813E+00 -0.0186 69 MnCl+ 0.21420E-10 -10.6692 0.20525E-10 -10.6877 0.95818E+00 -0.0186 70 MnSO4,aq 0.16452E-09 -9.7838 0.16452E-09 -9.7838 0.10000E+01 0.0000 71 NaCl,aq 0.11336E-07 -7.9455 0.11336E-07 -7.9455 0.10000E+01 0.0000 72 NaOH,aq 0.12084E-07 -7.9178 0.12084E-07 -7.9178 0.10000E+01 0.0000 74 OH- 0.65553E-04 -4.1834 0.62806E-04 -4.2020 0.95809E+00 -0.0186 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.10804E-08 -8.9664 0.10352E-08 -8.9850 0.95816E+00 -0.0186 84 PO4-3 0.71889E-12 -12.1433 0.56531E-12 -12.2477 0.78637E+00 -0.1044 87 H2P2O7-2 0.94298E-19 -19.0255 0.83869E-19 -19.0764 0.88941E+00 -0.0509 88 HP2O7-3 0.22927E-17 -17.6396 0.18007E-17 -17.7446 0.78539E+00 -0.1049 89 P2O7-4 0.70431E-19 -19.1522 0.46513E-19 -19.3324 0.66040E+00 -0.1802 90 H2S,aq 0.11807E-13 -13.9278 0.11806E-13 -13.9279 0.99990E+00 0.0000 97 SO3-2 0.15339E-14 -14.8142 0.13648E-14 -14.8649 0.88974E+00 -0.0507 98 HSO3- 0.79615E-15 -15.0990 0.76282E-15 -15.1176 0.95813E+00 -0.0186 99 HSO4- 0.20927E-09 -9.6793 0.20052E-09 -9.6978 0.95820E+00 -0.0185 Charge balance for all species = 0.7206E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9966450E-08 -.1217929E-03 -.1227533E+00 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999437E+06 0.0000 3 Cl- 0.1379644E-03 0.1379776E-03 0.4891451E+01 4.1412 4 SO4-- 0.2544047E-04 0.2550503E-04 0.2449920E+01 11.3946 5 HCO3- 0.1268944E-04 0.1307032E-04 0.7974707E+00 3.1049 6 HS- 0.4294049E-12 0.6338740E-10 0.2096233E-05 -4.3657 7 Al+++ 0.6687924E-21 0.3816446E-05 0.1029678E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4239628E-03 0.4074713E+02 -3.4168 9 Ca++ 0.9173516E-05 0.9317517E-05 0.3734070E+00 10.9515 10 Mg++ 0.3738165E-07 0.3886785E-07 0.9449036E-03 8.5616 11 Fe++ 0.2212138E-09 0.1500608E-08 0.8379986E-04 6.3338 12 K+ 0.1931345E-04 0.1932107E-04 0.7554511E+00 3.2873 13 Na+ 0.2741183E-03 0.2743049E-03 0.6305870E+01 4.4393 14 Mn++ 0.2885012E-07 0.3796695E-07 0.2085714E-02 8.4491 15 HPO4-- 0.6950666E-08 0.8031782E-08 0.7708402E-03 7.8311 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1493785E-02 -.1217899E-03 -.1371995E-02 0.0000000E+00 2 H2O 0.5550711E+02 0.5550692E+02 0.1871568E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2802639E-04 0.2550441E-04 0.2521984E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2521920E-05 0.6338585E-10 -.2521984E-05 0.0000000E+00 7 Al+++ 0.2967275E-03 0.3816353E-05 0.2929111E-03 0.0000000E+00 8 H4SiO4 0.9475632E-03 0.4239524E-03 0.5236108E-03 0.0000000E+00 9 Ca++ 0.1191340E-03 0.9317289E-05 0.1098168E-03 0.0000000E+00 10 Mg++ 0.7222222E-04 0.3886690E-07 0.7218336E-04 0.0000000E+00 11 Fe++ 0.6488378E-04 0.1500571E-08 0.6488228E-04 0.0000000E+00 12 K+ 0.1932059E-04 0.1932059E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2742982E-03 0.2742982E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1577812E-05 0.3796602E-07 0.1539846E-05 0.0000000E+00 15 HPO4-- 0.5384995E-06 0.8031585E-08 0.5304679E-06 0.0000000E+00 Chg. balance for solid moles: -.3981E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0910000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1768E-06 -6.752 0.8882E-04 -4.051 0.1264 0.2822E-04 clinochlore 0.1444E-04 -4.841 0.8024E-02 -2.096 11.42 0.3052E-02 daphnite 0.8941E-05 -5.049 0.6380E-02 -2.195 9.076 0.1933E-02 chlorite-Mn 0.3080E-06 -6.511 0.2183E-03 -3.661 0.3106 0.6958E-04 hematite 0.1009E-04 -4.996 0.1611E-02 -2.793 2.292 0.3054E-03 kaolinite 0.1384E-04 -4.859 0.3572E-02 -2.447 5.082 0.1374E-02 lawsonite 0.6753E-04 -4.171 0.2122E-01 -1.673 30.19 0.6843E-02 stilbite 0.4140E-04 -4.383 0.2918E-01 -1.535 41.51 0.1361E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3775E+00 0.3775E+00 1.0000 -0.423 chlorite-Mn 0.1300E-01 0.1300E-01 1.0000 -1.886 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.070292 g Volume = 0.027215 cm3 Porosity: 97.3741% V(tot) - V(min): 0.10092E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0910000 g log = -1.0410 Original solution: 1000.0103000 g Original solution / Rock added: 10989.12 (Water/Rock Ratio), log = 4.0410 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2529E-04 1.0073 0.2680E-04 0.2661E-04 CH4,gas 0.3219E-15 1.0129 0.3430E-15 0.3387E-15 H2,gas 0.5764E-06 1.0006 0.6067E-06 0.6064E-06 H2S,gas 0.3287E-12 0.9959 0.3443E-12 0.3457E-12 S2,gas 0.1147E-31 1.0000 0.1206E-31 0.1206E-31 CO,gas 0.4004E-14 1.0000 0.4212E-14 0.4212E-14 SO3,gas 0.7335E-36 1.0000 0.7716E-36 0.7716E-36 SO2,gas 0.1684E-19 1.0000 0.1771E-19 0.1771E-19 HCl,gas 0.3986E-15 1.0000 0.4193E-15 0.4193E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.60662E-10 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.24265E-10 164 stilbite -7.41 -7.41 0.00 0.000 0.37914E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.94 -6.57 -2.191 0.11221E+05 -4.572 3 CH4,gas 4.81 -12.66 -17.46 -4.366 0.29820E+05 -15.465 4 H2,gas 8.29 0.07 -8.22 -4.695 0.14030E+05 -6.217 5 H2S,gas -5.94 -20.41 -14.46 -7.232 0.24695E+05 -12.463 6 S2,gas -7.03 -40.95 -33.92 -5.218 0.57915E+05 -31.919 7 CO,gas 3.51 -12.87 -16.38 -5.039 0.27961E+05 -14.376 8 SO3,gas 17.43 -20.69 -38.11 -9.528 0.65076E+05 -36.113 9 SO2,gas 1.14 -20.62 -21.75 -5.800 0.37141E+05 -19.752 10 HCl,gas 5.48 -11.90 -17.38 -8.689 0.29672E+05 -15.377 11 acmite 7.74 3.90 -3.83 -0.398 0.65447E+04 15 albite-high 0.75 -3.03 -3.78 -0.291 0.64552E+04 16 albite -0.33 -3.03 -2.70 -0.208 0.46146E+04 19 spessartine 24.55 20.66 -3.89 -0.195 0.66465E+04 20 analcite 3.37 0.39 -2.98 -0.332 0.50963E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -9.73 -4.45 -2.227 0.76051E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -1.98 -2.97 -0.990 0.50708E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68555E+04 37 calcite 0.83 -1.98 -2.82 -0.939 0.48095E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29407E+04 42 celadonite 5.40 0.96 -4.44 -0.261 0.75791E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43642E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.12998E+04 52 chloritoid-Mn 11.46 10.59 -0.87 -0.058 0.14862E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60377E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64762E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82442E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68754E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.39 -3.86 -0.386 0.65994E+04 97 kalsilite 7.62 2.65 -4.97 -0.710 0.84854E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.77 -4.93 -0.493 0.84243E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75749E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20514E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -4.18 -1.75 -0.135 0.29901E+04 120 muscovite 2.68 1.38 -1.30 -0.077 0.22225E+04 121 paragonite 4.34 2.53 -1.81 -0.106 0.30854E+04 122 nepheline 8.38 3.80 -4.58 -0.654 0.78123E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50036E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.03 -2.38 -0.477 0.40702E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.49 -3.53 -1.176 0.60230E+04 153 rhodonite 7.46 5.03 -2.43 -0.486 0.41495E+04 154 sanidine -1.22 -4.18 -2.96 -0.228 0.50579E+04 156 siderite -2.59 -6.60 -4.01 -1.338 0.68532E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.54 -1.64 -0.049 0.28022E+04 166 stilpnomelane-Mg 27.60 22.68 -4.92 -0.147 0.83989E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83648E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55022E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77451E+04 175 tephroite 18.11 13.48 -4.63 -0.662 0.79082E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.98 -3.54 -0.217 0.60478E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.60 -3.34 -0.205 0.57026E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -5.11 -2.95 -0.181 0.50426E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40718E+04 205 montmorillonite-Na -1.96 -4.73 -2.77 -0.170 0.47355E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.06 -1.34 -0.086 0.22944E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.44 -1.14 -0.073 0.19509E+04 215 gypsum -4.92 -9.73 -4.81 -1.202 0.82119E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59599E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.49 -2.57 -0.198 0.43853E+04 244 an25ab75 2.71 0.15 -2.56 -0.197 0.43758E+04 245 an30ab70 3.34 0.78 -2.56 -0.197 0.43748E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.0910000 g New total amount of reactant added: 0.0950000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0950000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3115476E-03 Osmotic coef. = 0.9895 True ionic strength = .3506072E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.95829E-08 -8.0185 0.91819E-08 -8.0371 0.95816E+00 -0.0186 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13217E-03 -3.8789 0.95801E+00 -0.0186 4 SO4-- 0.25445E-04 -4.5944 0.22620E-04 -4.6455 0.88899E+00 -0.0511 5 HCO3- 0.12694E-04 -4.8964 0.12161E-04 -4.9150 0.95804E+00 -0.0186 6 HS- 0.41250E-12 -12.3846 0.39518E-12 -12.4032 0.95801E+00 -0.0186 7 Al+++ 0.59498E-21 -21.2255 0.46673E-21 -21.3309 0.78445E+00 -0.1054 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.84832E-05 -5.0714 0.75401E-05 -5.1226 0.88883E+00 -0.0512 10 Mg++ 0.34568E-07 -7.4613 0.30722E-07 -7.5126 0.88872E+00 -0.0512 11 Fe++ 0.20455E-09 -9.6892 0.18180E-09 -9.7404 0.88875E+00 -0.0512 12 K+ 0.20162E-04 -4.6955 0.19317E-04 -4.7141 0.95805E+00 -0.0186 13 Na+ 0.27913E-03 -3.5542 0.26741E-03 -3.5728 0.95800E+00 -0.0186 14 Mn++ 0.26745E-07 -7.5728 0.23770E-07 -7.6240 0.88877E+00 -0.0512 15 HPO4-- 0.75241E-08 -8.1235 0.66889E-08 -8.1746 0.88899E+00 -0.0511 16 HSiO3- 0.42477E-04 -4.3718 0.40693E-04 -4.3905 0.95801E+00 -0.0186 17 Ca(HSiO3)+ 0.71757E-08 -8.1441 0.68747E-08 -8.1627 0.95805E+00 -0.0186 18 Mg(HSiO3)+ 0.36386E-10 -10.4391 0.34859E-10 -10.4577 0.95805E+00 -0.0186 19 NaHSiO3,aq 0.17283E-06 -6.7624 0.17283E-06 -6.7624 0.10000E+01 0.0000 20 AlO+ 0.74598E-12 -12.1273 0.71469E-12 -12.1459 0.95805E+00 -0.0186 21 AlOH+2 0.36986E-16 -16.4320 0.32873E-16 -16.4832 0.88879E+00 -0.0512 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.39540E-05 -5.4030 0.37878E-05 -5.4216 0.95796E+00 -0.0187 24 CH4,aq 0.20850E-18 -18.6809 0.20848E-18 -18.6809 0.99990E+00 0.0000 29 CO,aq 0.25646E-17 -17.5910 0.25646E-17 -17.5910 0.10000E+01 0.0000 30 CO2,aq 0.22515E-06 -6.6475 0.22513E-06 -6.6476 0.99990E+00 0.0000 31 CO3-2 0.13776E-06 -6.8609 0.12246E-06 -6.9120 0.88894E+00 -0.0511 32 CaCO3,aq 0.11309E-07 -7.9466 0.11309E-07 -7.9466 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.24116E-08 -8.6177 0.23105E-08 -8.6363 0.95805E+00 -0.0186 34 CaCl+ 0.16576E-08 -8.7805 0.15880E-08 -8.7991 0.95805E+00 -0.0186 35 CaCl2,aq 0.48871E-13 -13.3110 0.48871E-13 -13.3110 0.10000E+01 0.0000 36 CaOH+ 0.60440E-07 -7.2187 0.57905E-07 -7.2373 0.95805E+00 -0.0186 37 CaSO4,aq 0.53142E-07 -7.2746 0.53142E-07 -7.2746 0.10000E+01 0.0000 38 HCl,aq 0.22827E-12 -12.6416 0.22827E-12 -12.6416 0.10000E+01 0.0000 43 FeCl+ 0.39063E-13 -13.4082 0.37424E-13 -13.4268 0.95805E+00 -0.0186 46 FeO,aq 0.85272E-10 -10.0692 0.85272E-10 -10.0692 0.10000E+01 0.0000 47 FeOH+ 0.68514E-09 -9.1642 0.65640E-09 -9.1828 0.95805E+00 -0.0186 48 HFeO2- 0.10427E-09 -9.9818 0.99891E-10 -10.0005 0.95801E+00 -0.0186 49 FeO+ 0.79279E-13 -13.1008 0.75954E-13 -13.1195 0.95805E+00 -0.0186 50 FeOH+2 0.14601E-18 -18.8356 0.12977E-18 -18.8868 0.88879E+00 -0.0512 51 FeO2- 0.18483E-09 -9.7332 0.17707E-09 -9.7519 0.95801E+00 -0.0186 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44233E-09 -9.3543 0.44229E-09 -9.3543 0.99990E+00 0.0000 54 KCl,aq 0.45206E-10 -10.3448 0.45206E-10 -10.3448 0.10000E+01 0.0000 55 KHSO4,aq 0.10736E-16 -16.9692 0.10736E-16 -16.9692 0.10000E+01 0.0000 56 KOH,aq 0.91713E-09 -9.0376 0.91713E-09 -9.0376 0.10000E+01 0.0000 57 KSO4- 0.70267E-08 -8.1532 0.67317E-08 -8.1719 0.95801E+00 -0.0186 58 MgCO3,aq 0.11514E-10 -10.9388 0.11514E-10 -10.9388 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10020E-10 -10.9991 0.95996E-11 -11.0177 0.95805E+00 -0.0186 60 MgCl+ 0.61311E-11 -11.2125 0.58740E-11 -11.2311 0.95805E+00 -0.0186 61 MgOH+ 0.13643E-08 -8.8651 0.13071E-08 -8.8837 0.95805E+00 -0.0186 63 MnO,aq 0.29764E-09 -9.5263 0.29764E-09 -9.5263 0.10000E+01 0.0000 64 MnOH+ 0.83220E-08 -8.0798 0.79730E-08 -8.0984 0.95805E+00 -0.0186 65 MnO2-2 0.13735E-15 -15.8622 0.12209E-15 -15.9133 0.88894E+00 -0.0511 66 HMnO2- 0.25354E-12 -12.5960 0.24289E-12 -12.6146 0.95801E+00 -0.0186 69 MnCl+ 0.19847E-10 -10.7023 0.19015E-10 -10.7209 0.95805E+00 -0.0186 70 MnSO4,aq 0.15238E-09 -9.8171 0.15238E-09 -9.8171 0.10000E+01 0.0000 71 NaCl,aq 0.11541E-07 -7.9378 0.11541E-07 -7.9378 0.10000E+01 0.0000 72 NaOH,aq 0.12797E-07 -7.8929 0.12797E-07 -7.8929 0.10000E+01 0.0000 74 OH- 0.68195E-04 -4.1662 0.65328E-04 -4.1849 0.95796E+00 -0.0187 79 HPO3-2 0.10512E-19 -19.9783 0.93444E-20 -20.0294 0.88894E+00 -0.0511 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.11239E-08 -8.9493 0.10768E-08 -8.9679 0.95803E+00 -0.0186 84 PO4-3 0.80998E-12 -12.0915 0.63620E-12 -12.1964 0.78545E+00 -0.1049 87 H2P2O7-2 0.10208E-18 -18.9911 0.90742E-19 -19.0422 0.88894E+00 -0.0511 88 HP2O7-3 0.25833E-17 -17.5878 0.20265E-17 -17.6933 0.78446E+00 -0.1054 89 P2O7-4 0.82619E-19 -19.0829 0.54447E-19 -19.2640 0.65902E+00 -0.1811 90 H2S,aq 0.10903E-13 -13.9624 0.10902E-13 -13.9625 0.99990E+00 0.0000 97 SO3-2 0.15340E-14 -14.8142 0.13641E-14 -14.8651 0.88928E+00 -0.0510 98 HSO3- 0.76513E-15 -15.1163 0.73300E-15 -15.1349 0.95801E+00 -0.0186 99 HSO4- 0.20114E-09 -9.6965 0.19271E-09 -9.7151 0.95808E+00 -0.0186 Charge balance for all species = 0.7206E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9582870E-08 -.1267147E-03 -.1277138E+00 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999434E+06 0.0000 3 Cl- 0.1379644E-03 0.1379777E-03 0.4891453E+01 4.1582 4 SO4-- 0.2544459E-04 0.2550505E-04 0.2449921E+01 11.4286 5 HCO3- 0.1269368E-04 0.1307033E-04 0.7974711E+00 3.1220 6 HS- 0.4125034E-12 0.6245989E-10 0.2065560E-05 -4.3661 7 Al+++ 0.5949773E-21 0.3969626E-05 0.1071006E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4256177E-03 0.4090617E+02 -3.4168 9 Ca++ 0.8483229E-05 0.8619365E-05 0.3454279E+00 10.9515 10 Mg++ 0.3456845E-07 0.3599679E-07 0.8751059E-03 8.5616 11 Fe++ 0.2045541E-09 0.1467656E-08 0.8195967E-04 6.3337 12 K+ 0.2016237E-04 0.2017036E-04 0.7886581E+00 3.3230 13 Na+ 0.2791290E-03 0.2793262E-03 0.6421301E+01 4.4642 14 Mn++ 0.2674534E-07 0.3553750E-07 0.1952252E-02 8.4502 15 HPO4-- 0.7524145E-08 0.8648892E-08 0.8300664E-03 7.8995 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1560019E-02 -.1267115E-03 -.1433307E-02 0.0000000E+00 2 H2O 0.5550706E+02 0.5550688E+02 0.1789070E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2813724E-04 0.2550441E-04 0.2632836E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2632774E-05 0.6245831E-10 -.2632836E-05 0.0000000E+00 7 Al+++ 0.3097705E-03 0.3969526E-05 0.3058009E-03 0.0000000E+00 8 H4SiO4 0.9892144E-03 0.4256070E-03 0.5636074E-03 0.0000000E+00 9 Ca++ 0.1237346E-03 0.8619147E-05 0.1151155E-03 0.0000000E+00 10 Mg++ 0.7539683E-04 0.3599588E-07 0.7536083E-04 0.0000000E+00 11 Fe++ 0.6773582E-04 0.1467619E-08 0.6773435E-04 0.0000000E+00 12 K+ 0.2016985E-04 0.2016985E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2793191E-03 0.2793191E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1647167E-05 0.3553660E-07 0.1611630E-05 0.0000000E+00 15 HPO4-- 0.5621698E-06 0.8648673E-08 0.5535211E-06 0.0000000E+00 Chg. balance for solid moles: -.3515E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0950000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1845E-06 -6.734 0.9268E-04 -4.033 0.1240 0.2945E-04 clinochlore 0.1507E-04 -4.822 0.8378E-02 -2.077 11.21 0.3187E-02 daphnite 0.9334E-05 -5.030 0.6660E-02 -2.177 8.912 0.2018E-02 chlorite-Mn 0.3223E-06 -6.492 0.2285E-03 -3.641 0.3058 0.7282E-04 hematite 0.1053E-04 -4.978 0.1682E-02 -2.774 2.250 0.3188E-03 kaolinite 0.1398E-04 -4.855 0.3609E-02 -2.443 4.829 0.1389E-02 lawsonite 0.6758E-04 -4.170 0.2124E-01 -1.673 28.41 0.6848E-02 stilbite 0.4662E-04 -4.331 0.3285E-01 -1.483 43.96 0.1532E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3775E+00 0.3775E+00 1.0000 -0.423 chlorite-Mn 0.1303E-01 0.1303E-01 1.0000 -1.885 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.074736 g Volume = 0.029185 cm3 Porosity: 97.1884% V(tot) - V(min): 0.10088E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0950000 g log = -1.0223 Original solution: 1000.0103000 g Original solution / Rock added: 10526.42 (Water/Rock Ratio), log = 4.0223 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2432E-04 1.0073 0.2577E-04 0.2558E-04 CH4,gas 0.3094E-15 1.0129 0.3297E-15 0.3255E-15 H2,gas 0.5764E-06 1.0006 0.6066E-06 0.6063E-06 H2S,gas 0.3035E-12 0.9959 0.3180E-12 0.3193E-12 S2,gas 0.9782E-32 1.0000 0.1029E-31 0.1029E-31 CO,gas 0.3849E-14 1.0000 0.4049E-14 0.4049E-14 SO3,gas 0.6777E-36 1.0000 0.7129E-36 0.7129E-36 SO2,gas 0.1555E-19 1.0000 0.1636E-19 0.1636E-19 HCl,gas 0.3832E-15 1.0000 0.4031E-15 0.4031E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.18198E-10 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 164 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.95 -6.59 -2.196 0.11250E+05 -4.589 3 CH4,gas 4.81 -12.67 -17.48 -4.370 0.29850E+05 -15.482 4 H2,gas 8.29 0.07 -8.22 -4.695 0.14030E+05 -6.217 5 H2S,gas -5.94 -20.44 -14.50 -7.249 0.24754E+05 -12.498 6 S2,gas -7.03 -41.02 -33.99 -5.229 0.58033E+05 -31.988 7 CO,gas 3.51 -12.88 -16.39 -5.044 0.27990E+05 -14.393 8 SO3,gas 17.43 -20.72 -38.15 -9.537 0.65135E+05 -36.147 9 SO2,gas 1.14 -20.65 -21.79 -5.810 0.37199E+05 -19.786 10 HCl,gas 5.48 -11.92 -17.39 -8.697 0.29701E+05 -15.395 11 acmite 7.74 3.93 -3.81 -0.396 0.65021E+04 15 albite-high 0.75 -3.01 -3.76 -0.289 0.64127E+04 16 albite -0.33 -3.01 -2.68 -0.206 0.45720E+04 19 spessartine 24.55 20.66 -3.89 -0.194 0.66410E+04 20 analcite 3.37 0.41 -2.96 -0.329 0.50538E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -9.77 -4.49 -2.244 0.76638E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.00 -2.99 -0.996 0.50999E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68555E+04 37 calcite 0.83 -2.00 -2.83 -0.945 0.48386E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29408E+04 42 celadonite 5.40 1.00 -4.40 -0.259 0.75181E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43642E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.12998E+04 52 chloritoid-Mn 11.46 10.59 -0.87 -0.058 0.14844E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60377E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64762E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82443E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68755E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.41 -3.84 -0.384 0.65568E+04 97 kalsilite 7.62 2.69 -4.93 -0.705 0.84244E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.73 -4.90 -0.490 0.83633E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75750E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20514E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -4.15 -1.72 -0.132 0.29291E+04 120 muscovite 2.68 1.41 -1.27 -0.074 0.21615E+04 121 paragonite 4.34 2.55 -1.78 -0.105 0.30429E+04 122 nepheline 8.38 3.83 -4.55 -0.650 0.77698E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50037E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.03 -2.38 -0.477 0.40684E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.50 -3.54 -1.181 0.60502E+04 153 rhodonite 7.46 5.03 -2.43 -0.486 0.41476E+04 154 sanidine -1.22 -4.15 -2.93 -0.225 0.49969E+04 156 siderite -2.59 -6.62 -4.03 -1.344 0.68823E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.56 -1.62 -0.048 0.27720E+04 166 stilpnomelane-Mg 27.60 22.70 -4.90 -0.146 0.83684E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83649E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55023E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77451E+04 175 tephroite 18.11 13.48 -4.63 -0.661 0.79046E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.97 -3.53 -0.216 0.60277E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.59 -3.33 -0.204 0.56885E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -5.10 -2.94 -0.180 0.50224E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40718E+04 205 montmorillonite-Na -1.96 -4.73 -2.77 -0.169 0.47215E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.07 -1.33 -0.085 0.22743E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.45 -1.13 -0.073 0.19368E+04 215 gypsum -4.92 -9.77 -4.84 -1.211 0.82705E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59599E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.47 -2.55 -0.196 0.43512E+04 244 an25ab75 2.71 0.17 -2.54 -0.196 0.43439E+04 245 an30ab70 3.34 0.80 -2.54 -0.196 0.43450E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.0950000 g New total amount of reactant added: 0.0990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.0990000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3139071E-03 Osmotic coef. = 0.9894 True ionic strength = .3545678E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92186E-08 -8.0353 0.88317E-08 -8.0540 0.95803E+00 -0.0186 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13215E-03 -3.8789 0.95787E+00 -0.0187 4 SO4-- 0.25448E-04 -4.5943 0.22611E-04 -4.6457 0.88851E+00 -0.0513 5 HCO3- 0.12697E-04 -4.8963 0.12163E-04 -4.9150 0.95791E+00 -0.0187 6 HS- 0.39648E-12 -12.4018 0.37978E-12 -12.4205 0.95788E+00 -0.0187 7 Al+++ 0.53011E-21 -21.2756 0.41534E-21 -21.3816 0.78349E+00 -0.1060 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.78527E-05 -5.1050 0.69759E-05 -5.1564 0.88834E+00 -0.0514 10 Mg++ 0.31999E-07 -7.4949 0.28423E-07 -7.5463 0.88823E+00 -0.0515 11 Fe++ 0.18934E-09 -9.7228 0.16818E-09 -9.7742 0.88826E+00 -0.0515 12 K+ 0.21011E-04 -4.6775 0.20127E-04 -4.6962 0.95792E+00 -0.0187 13 Na+ 0.28414E-03 -3.5465 0.27217E-03 -3.5652 0.95787E+00 -0.0187 14 Mn++ 0.24811E-07 -7.6054 0.22039E-07 -7.6568 0.88828E+00 -0.0515 15 HPO4-- 0.81371E-08 -8.0895 0.72299E-08 -8.1409 0.88851E+00 -0.0513 16 HSiO3- 0.44168E-04 -4.3549 0.42307E-04 -4.3736 0.95787E+00 -0.0187 17 Ca(HSiO3)+ 0.69029E-08 -8.1610 0.66125E-08 -8.1796 0.95792E+00 -0.0187 18 Mg(HSiO3)+ 0.35002E-10 -10.4559 0.33529E-10 -10.4746 0.95792E+00 -0.0187 19 NaHSiO3,aq 0.18288E-06 -6.7378 0.18288E-06 -6.7378 0.10000E+01 0.0000 20 AlO+ 0.71763E-12 -12.1441 0.68743E-12 -12.1628 0.95792E+00 -0.0187 21 AlOH+2 0.34237E-16 -16.4655 0.30413E-16 -16.5169 0.88830E+00 -0.0514 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.41114E-05 -5.3860 0.39380E-05 -5.4047 0.95783E+00 -0.0187 24 CH4,aq 0.20048E-18 -18.6979 0.20046E-18 -18.6980 0.99990E+00 0.0000 29 CO,aq 0.24668E-17 -17.6079 0.24668E-17 -17.6079 0.10000E+01 0.0000 30 CO2,aq 0.21660E-06 -6.6643 0.21658E-06 -6.6644 0.99990E+00 0.0000 31 CO3-2 0.14332E-06 -6.8437 0.12733E-06 -6.8951 0.88846E+00 -0.0514 32 CaCO3,aq 0.10879E-07 -7.9634 0.10879E-07 -7.9634 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.22318E-08 -8.6513 0.21379E-08 -8.6700 0.95792E+00 -0.0187 34 CaCl+ 0.15335E-08 -8.8143 0.14690E-08 -8.8330 0.95792E+00 -0.0187 35 CaCl2,aq 0.45202E-13 -13.3448 0.45202E-13 -13.3448 0.10000E+01 0.0000 36 CaOH+ 0.58143E-07 -7.2355 0.55696E-07 -7.2542 0.95792E+00 -0.0187 37 CaSO4,aq 0.49146E-07 -7.3085 0.49146E-07 -7.3085 0.10000E+01 0.0000 38 HCl,aq 0.21953E-12 -12.6585 0.21953E-12 -12.6585 0.10000E+01 0.0000 43 FeCl+ 0.36138E-13 -13.4420 0.34617E-13 -13.4607 0.95792E+00 -0.0187 46 FeO,aq 0.85267E-10 -10.0692 0.85267E-10 -10.0692 0.10000E+01 0.0000 47 FeOH+ 0.65906E-09 -9.1811 0.63133E-09 -9.1997 0.95792E+00 -0.0187 48 HFeO2- 0.10841E-09 -9.9649 0.10385E-09 -9.9836 0.95787E+00 -0.0187 49 FeO+ 0.76266E-13 -13.1177 0.73057E-13 -13.1363 0.95792E+00 -0.0187 50 FeOH+2 0.13516E-18 -18.8692 0.12006E-18 -18.9206 0.88830E+00 -0.0514 51 FeO2- 0.19218E-09 -9.7163 0.18409E-09 -9.7350 0.95787E+00 -0.0187 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44228E-09 -9.3543 0.44224E-09 -9.3543 0.99990E+00 0.0000 54 KCl,aq 0.47097E-10 -10.3270 0.47097E-10 -10.3270 0.10000E+01 0.0000 55 KHSO4,aq 0.10755E-16 -16.9684 0.10755E-16 -16.9684 0.10000E+01 0.0000 56 KOH,aq 0.99351E-09 -9.0028 0.99351E-09 -9.0028 0.10000E+01 0.0000 57 KSO4- 0.73197E-08 -8.1355 0.70113E-08 -8.1542 0.95787E+00 -0.0187 58 MgCO3,aq 0.11076E-10 -10.9556 0.11076E-10 -10.9556 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.92727E-11 -11.0328 0.88825E-11 -11.0515 0.95792E+00 -0.0187 60 MgCl+ 0.56723E-11 -11.2462 0.54336E-11 -11.2649 0.95792E+00 -0.0187 61 MgOH+ 0.13124E-08 -8.8819 0.12572E-08 -8.9006 0.95792E+00 -0.0187 63 MnO,aq 0.29828E-09 -9.5254 0.29828E-09 -9.5254 0.10000E+01 0.0000 64 MnOH+ 0.80231E-08 -8.0957 0.76855E-08 -8.1143 0.95792E+00 -0.0187 65 MnO2-2 0.14886E-15 -15.8272 0.13225E-15 -15.8786 0.88846E+00 -0.0514 66 HMnO2- 0.26420E-12 -12.5781 0.25307E-12 -12.5968 0.95787E+00 -0.0187 69 MnCl+ 0.18402E-10 -10.7351 0.17627E-10 -10.7538 0.95792E+00 -0.0187 70 MnSO4,aq 0.14123E-09 -9.8501 0.14123E-09 -9.8501 0.10000E+01 0.0000 71 NaCl,aq 0.11744E-07 -7.9302 0.11744E-07 -7.9302 0.10000E+01 0.0000 72 NaOH,aq 0.13541E-07 -7.8683 0.13541E-07 -7.8683 0.10000E+01 0.0000 74 OH- 0.70909E-04 -4.1493 0.67919E-04 -4.1680 0.95783E+00 -0.0187 79 HPO3-2 0.11367E-19 -19.9444 0.10099E-19 -19.9957 0.88846E+00 -0.0514 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.11687E-08 -8.9323 0.11195E-08 -8.9510 0.95790E+00 -0.0187 84 PO4-3 0.91132E-12 -12.0403 0.71492E-12 -12.1457 0.78449E+00 -0.1054 87 H2P2O7-2 0.11039E-18 -18.9571 0.98081E-19 -19.0084 0.88846E+00 -0.0514 88 HP2O7-3 0.29065E-17 -17.5366 0.22772E-17 -17.6426 0.78350E+00 -0.1060 89 P2O7-4 0.96735E-19 -19.0144 0.63611E-19 -19.1965 0.65758E+00 -0.1821 90 H2S,aq 0.10078E-13 -13.9966 0.10077E-13 -13.9966 0.99990E+00 0.0000 97 SO3-2 0.15340E-14 -14.8142 0.13634E-14 -14.8654 0.88879E+00 -0.0512 98 HSO3- 0.73566E-15 -15.1333 0.70467E-15 -15.1520 0.95787E+00 -0.0187 99 HSO4- 0.19342E-09 -9.7135 0.18529E-09 -9.7322 0.95795E+00 -0.0187 Charge balance for all species = 0.7206E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9218616E-08 -.1317706E-03 -.1328095E+00 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9999431E+06 0.0000 3 Cl- 0.1379644E-03 0.1379778E-03 0.4891456E+01 4.1750 4 SO4-- 0.2544833E-04 0.2550507E-04 0.2449923E+01 11.4622 5 HCO3- 0.1269729E-04 0.1307034E-04 0.7974715E+00 3.1390 6 HS- 0.3964770E-12 0.6151085E-10 0.2034174E-05 -4.3665 7 Al+++ 0.5301138E-21 0.4126987E-05 0.1113461E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4273179E-03 0.4106957E+02 -3.4168 9 Ca++ 0.7852747E-05 0.7981582E-05 0.3198682E+00 10.9515 10 Mg++ 0.3199903E-07 0.3337247E-07 0.8113067E-03 8.5616 11 Fe++ 0.1893403E-09 0.1437848E-08 0.8029508E-04 6.3337 12 K+ 0.2101130E-04 0.2101966E-04 0.8218652E+00 3.3577 13 Na+ 0.2841394E-03 0.2843475E-03 0.6536731E+01 4.4888 14 Mn++ 0.2481123E-07 0.3329246E-07 0.1828920E-02 8.4511 15 HPO4-- 0.8137141E-08 0.9306719E-08 0.8932002E-03 7.9670 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1626253E-02 -.1317671E-03 -.1494486E-02 0.0000000E+00 2 H2O 0.5550701E+02 0.5550684E+02 0.1706355E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2824810E-04 0.2550441E-04 0.2743689E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2743627E-05 0.6150925E-10 -.2743689E-05 0.0000000E+00 7 Al+++ 0.3228134E-03 0.4126879E-05 0.3186865E-03 0.0000000E+00 8 H4SiO4 0.1030866E-02 0.4273068E-03 0.6035587E-03 0.0000000E+00 9 Ca++ 0.1283352E-03 0.7981374E-05 0.1203538E-03 0.0000000E+00 10 Mg++ 0.7857143E-04 0.3337160E-07 0.7853806E-04 0.0000000E+00 11 Fe++ 0.7058785E-04 0.1437811E-08 0.7058641E-04 0.0000000E+00 12 K+ 0.2101911E-04 0.2101911E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2843401E-03 0.2843401E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1716521E-05 0.3329159E-07 0.1683229E-05 0.0000000E+00 15 HPO4-- 0.5858401E-06 0.9306477E-08 0.5765336E-06 0.0000000E+00 Chg. balance for solid moles: 0.1393E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.0990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1922E-06 -6.716 0.9653E-04 -4.015 0.1219 0.3068E-04 clinochlore 0.1571E-04 -4.804 0.8731E-02 -2.059 11.03 0.3321E-02 daphnite 0.9727E-05 -5.012 0.6941E-02 -2.159 8.766 0.2103E-02 chlorite-Mn 0.3366E-06 -6.473 0.2387E-03 -3.622 0.3015 0.7606E-04 hematite 0.1097E-04 -4.960 0.1753E-02 -2.756 2.214 0.3322E-03 kaolinite 0.1418E-04 -4.848 0.3660E-02 -2.436 4.623 0.1408E-02 lawsonite 0.6757E-04 -4.170 0.2123E-01 -1.673 26.82 0.6847E-02 stilbite 0.5182E-04 -4.286 0.3652E-01 -1.437 46.13 0.1703E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3774E+00 0.3774E+00 1.0000 -0.423 chlorite-Mn 0.1306E-01 0.1306E-01 1.0000 -1.884 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.079172 g Volume = 0.031152 cm3 Porosity: 97.0035% V(tot) - V(min): 0.10084E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.0990000 g log = -1.0044 Original solution: 1000.0103000 g Original solution / Rock added: 10101.11 (Water/Rock Ratio), log = 4.0044 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2340E-04 1.0073 0.2479E-04 0.2461E-04 CH4,gas 0.2975E-15 1.0129 0.3170E-15 0.3130E-15 H2,gas 0.5763E-06 1.0006 0.6066E-06 0.6062E-06 H2S,gas 0.2805E-12 0.9959 0.2939E-12 0.2951E-12 S2,gas 0.8360E-32 1.0000 0.8794E-32 0.8794E-32 CO,gas 0.3703E-14 1.0000 0.3895E-14 0.3895E-14 SO3,gas 0.6268E-36 1.0000 0.6593E-36 0.6593E-36 SO2,gas 0.1438E-19 1.0000 0.1513E-19 0.1513E-19 HCl,gas 0.3685E-15 1.0000 0.3876E-15 0.3876E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 164 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.97 -6.61 -2.202 0.11279E+05 -4.606 3 CH4,gas 4.81 -12.69 -17.50 -4.375 0.29879E+05 -15.499 4 H2,gas 8.29 0.07 -8.22 -4.695 0.14031E+05 -6.217 5 H2S,gas -5.94 -20.47 -14.53 -7.266 0.24813E+05 -12.532 6 S2,gas -7.03 -41.09 -34.06 -5.239 0.58149E+05 -32.056 7 CO,gas 3.51 -12.90 -16.41 -5.049 0.28019E+05 -14.409 8 SO3,gas 17.43 -20.75 -38.18 -9.545 0.65193E+05 -36.181 9 SO2,gas 1.14 -20.68 -21.82 -5.819 0.37257E+05 -19.820 10 HCl,gas 5.48 -11.93 -17.41 -8.706 0.29730E+05 -15.412 11 acmite 7.74 3.95 -3.78 -0.393 0.64602E+04 15 albite-high 0.75 -2.98 -3.73 -0.287 0.63708E+04 16 albite -0.33 -2.98 -2.65 -0.204 0.45301E+04 19 spessartine 24.55 20.66 -3.89 -0.194 0.66362E+04 20 analcite 3.37 0.44 -2.94 -0.326 0.50119E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -9.80 -4.52 -2.261 0.77218E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.02 -3.00 -1.001 0.51286E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68555E+04 37 calcite 0.83 -2.02 -2.85 -0.950 0.48673E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29408E+04 42 celadonite 5.40 1.03 -4.37 -0.257 0.74587E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43642E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.12998E+04 52 chloritoid-Mn 11.46 10.59 -0.87 -0.058 0.14828E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60377E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64763E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82444E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68757E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.44 -3.82 -0.382 0.65149E+04 97 kalsilite 7.62 2.72 -4.90 -0.700 0.83651E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.70 -4.86 -0.486 0.83040E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75750E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20515E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -4.11 -1.68 -0.129 0.28698E+04 120 muscovite 2.68 1.45 -1.23 -0.072 0.21022E+04 121 paragonite 4.34 2.58 -1.76 -0.103 0.30010E+04 122 nepheline 8.38 3.85 -4.53 -0.647 0.77278E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50037E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.03 -2.38 -0.476 0.40668E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.52 -3.56 -1.186 0.60774E+04 153 rhodonite 7.46 5.03 -2.43 -0.486 0.41460E+04 154 sanidine -1.22 -4.11 -2.89 -0.222 0.49376E+04 156 siderite -2.59 -6.64 -4.05 -1.349 0.69111E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.57 -1.61 -0.048 0.27426E+04 166 stilpnomelane-Mg 27.60 22.71 -4.88 -0.146 0.83388E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83650E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55023E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77451E+04 175 tephroite 18.11 13.49 -4.63 -0.661 0.79014E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.95 -3.52 -0.215 0.60081E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.58 -3.32 -0.204 0.56747E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -5.09 -2.93 -0.179 0.50029E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40718E+04 205 montmorillonite-Na -1.96 -4.72 -2.76 -0.169 0.47076E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.08 -1.32 -0.085 0.22547E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.46 -1.13 -0.072 0.19230E+04 215 gypsum -4.92 -9.80 -4.88 -1.219 0.83285E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59600E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.45 -2.53 -0.195 0.43177E+04 244 an25ab75 2.71 0.18 -2.53 -0.194 0.43125E+04 245 an30ab70 3.34 0.82 -2.53 -0.194 0.43156E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.0990000 g New total amount of reactant added: 0.1030000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1030000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3163964E-03 Osmotic coef. = 0.9894 True ionic strength = .3586948E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.88733E-08 -8.0519 0.84996E-08 -8.0706 0.95789E+00 -0.0187 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13213E-03 -3.8790 0.95774E+00 -0.0188 4 SO4-- 0.25452E-04 -4.5943 0.22601E-04 -4.6459 0.88800E+00 -0.0516 5 HCO3- 0.12700E-04 -4.8962 0.12164E-04 -4.9149 0.95777E+00 -0.0187 6 HS- 0.38130E-12 -12.4187 0.36519E-12 -12.4375 0.95774E+00 -0.0188 7 Al+++ 0.47315E-21 -21.3250 0.37023E-21 -21.4315 0.78249E+00 -0.1065 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.72775E-05 -5.1380 0.64612E-05 -5.1897 0.88783E+00 -0.0517 10 Mg++ 0.29655E-07 -7.5279 0.26325E-07 -7.5796 0.88773E+00 -0.0517 11 Fe++ 0.17546E-09 -9.7558 0.15577E-09 -9.8075 0.88775E+00 -0.0517 12 K+ 0.21860E-04 -4.6603 0.20937E-04 -4.6791 0.95778E+00 -0.0187 13 Na+ 0.28915E-03 -3.5389 0.27693E-03 -3.5576 0.95774E+00 -0.0188 14 Mn++ 0.23037E-07 -7.6376 0.20452E-07 -7.6893 0.88777E+00 -0.0517 15 HPO4-- 0.87903E-08 -8.0560 0.78058E-08 -8.1076 0.88801E+00 -0.0516 16 HSiO3- 0.45900E-04 -4.3382 0.43960E-04 -4.3569 0.95774E+00 -0.0188 17 Ca(HSiO3)+ 0.66443E-08 -8.1775 0.63639E-08 -8.1963 0.95779E+00 -0.0187 18 Mg(HSiO3)+ 0.33691E-10 -10.4725 0.32269E-10 -10.4912 0.95779E+00 -0.0187 19 NaHSiO3,aq 0.19335E-06 -6.7137 0.19335E-06 -6.7137 0.10000E+01 0.0000 20 AlO+ 0.69074E-12 -12.1607 0.66159E-12 -12.1794 0.95779E+00 -0.0187 21 AlOH+2 0.31729E-16 -16.4985 0.28169E-16 -16.5502 0.88780E+00 -0.0517 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.42726E-05 -5.3693 0.40919E-05 -5.3881 0.95769E+00 -0.0188 24 CH4,aq 0.19288E-18 -18.7147 0.19286E-18 -18.7148 0.99990E+00 0.0000 29 CO,aq 0.23740E-17 -17.6245 0.23740E-17 -17.6245 0.10000E+01 0.0000 30 CO2,aq 0.20847E-06 -6.6809 0.20845E-06 -6.6810 0.99990E+00 0.0000 31 CO3-2 0.14902E-06 -6.8268 0.13232E-06 -6.8784 0.88795E+00 -0.0516 32 CaCO3,aq 0.10471E-07 -7.9800 0.10471E-07 -7.9800 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.20676E-08 -8.6845 0.19803E-08 -8.7033 0.95779E+00 -0.0187 34 CaCl+ 0.14204E-08 -8.8476 0.13604E-08 -8.8663 0.95779E+00 -0.0187 35 CaCl2,aq 0.41855E-13 -13.3783 0.41855E-13 -13.3783 0.10000E+01 0.0000 36 CaOH+ 0.55965E-07 -7.2521 0.53602E-07 -7.2708 0.95779E+00 -0.0187 37 CaSO4,aq 0.45500E-07 -7.3420 0.45500E-07 -7.3420 0.10000E+01 0.0000 38 HCl,aq 0.21125E-12 -12.6752 0.21125E-12 -12.6752 0.10000E+01 0.0000 43 FeCl+ 0.33470E-13 -13.4753 0.32057E-13 -13.4941 0.95779E+00 -0.0187 46 FeO,aq 0.85262E-10 -10.0692 0.85262E-10 -10.0692 0.10000E+01 0.0000 47 FeOH+ 0.63434E-09 -9.1977 0.60756E-09 -9.2164 0.95779E+00 -0.0187 48 HFeO2- 0.11266E-09 -9.9482 0.10790E-09 -9.9670 0.95774E+00 -0.0188 49 FeO+ 0.73409E-13 -13.1343 0.70310E-13 -13.1530 0.95779E+00 -0.0187 50 FeOH+2 0.12526E-18 -18.9022 0.11120E-18 -18.9539 0.88780E+00 -0.0517 51 FeO2- 0.19972E-09 -9.6996 0.19128E-09 -9.7183 0.95774E+00 -0.0188 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44224E-09 -9.3543 0.44219E-09 -9.3544 0.99990E+00 0.0000 54 KCl,aq 0.48986E-10 -10.3099 0.48986E-10 -10.3099 0.10000E+01 0.0000 55 KHSO4,aq 0.10763E-16 -16.9681 0.10763E-16 -16.9681 0.10000E+01 0.0000 56 KOH,aq 0.10739E-08 -8.9690 0.10739E-08 -8.9690 0.10000E+01 0.0000 57 KSO4- 0.76121E-08 -8.1185 0.72904E-08 -8.1372 0.95774E+00 -0.0188 58 MgCO3,aq 0.10661E-10 -10.9722 0.10661E-10 -10.9722 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.85905E-11 -11.0660 0.82279E-11 -11.0847 0.95779E+00 -0.0187 60 MgCl+ 0.52538E-11 -11.2795 0.50320E-11 -11.2983 0.95779E+00 -0.0187 61 MgOH+ 0.12632E-08 -8.8985 0.12099E-08 -8.9172 0.95779E+00 -0.0187 63 MnO,aq 0.29885E-09 -9.5245 0.29885E-09 -9.5245 0.10000E+01 0.0000 64 MnOH+ 0.77372E-08 -8.1114 0.74105E-08 -8.1301 0.95779E+00 -0.0187 65 MnO2-2 0.16111E-15 -15.7929 0.14306E-15 -15.8445 0.88795E+00 -0.0516 66 HMnO2- 0.27508E-12 -12.5605 0.26345E-12 -12.5793 0.95774E+00 -0.0188 69 MnCl+ 0.17076E-10 -10.7676 0.16356E-10 -10.7863 0.95779E+00 -0.0187 70 MnSO4,aq 0.13100E-09 -9.8827 0.13100E-09 -9.8827 0.10000E+01 0.0000 71 NaCl,aq 0.11948E-07 -7.9227 0.11948E-07 -7.9227 0.10000E+01 0.0000 72 NaOH,aq 0.14316E-07 -7.8442 0.14316E-07 -7.8442 0.10000E+01 0.0000 74 OH- 0.73690E-04 -4.1326 0.70572E-04 -4.1514 0.95769E+00 -0.0188 79 HPO3-2 0.12278E-19 -19.9109 0.10902E-19 -19.9625 0.88795E+00 -0.0516 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.12145E-08 -8.9156 0.11632E-08 -8.9343 0.95776E+00 -0.0187 84 PO4-3 0.10236E-11 -11.9899 0.80203E-12 -12.0958 0.78351E+00 -0.1060 87 H2P2O7-2 0.11926E-18 -18.9235 0.10589E-18 -18.9751 0.88795E+00 -0.0516 88 HP2O7-3 0.32648E-17 -17.4861 0.25547E-17 -17.5927 0.78250E+00 -0.1065 89 P2O7-4 0.11302E-18 -18.9469 0.74149E-19 -19.1299 0.65609E+00 -0.1830 90 H2S,aq 0.93270E-14 -14.0303 0.93261E-14 -14.0303 0.99990E+00 0.0000 97 SO3-2 0.15340E-14 -14.8142 0.13627E-14 -14.8656 0.88829E+00 -0.0514 98 HSO3- 0.70773E-15 -15.1501 0.67782E-15 -15.1689 0.95774E+00 -0.0188 99 HSO4- 0.18609E-09 -9.7303 0.17824E-09 -9.7490 0.95781E+00 -0.0187 Charge balance for all species = 0.7206E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8873276E-08 -.1369503E-03 -.1380300E+00 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999428E+06 0.0000 3 Cl- 0.1379644E-03 0.1379779E-03 0.4891458E+01 4.1916 4 SO4-- 0.2545172E-04 0.2550509E-04 0.2449924E+01 11.4953 5 HCO3- 0.1270030E-04 0.1307035E-04 0.7974719E+00 3.1557 6 HS- 0.3813015E-12 0.6054183E-10 0.2002128E-05 -4.3669 7 Al+++ 0.4731457E-21 0.4288211E-05 0.1156959E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4290601E-03 0.4123699E+02 -3.4168 9 Ca++ 0.7277504E-05 0.7399573E-05 0.2965436E+00 10.9515 10 Mg++ 0.2965477E-07 0.3097621E-07 0.7530518E-03 8.5616 11 Fe++ 0.1754615E-09 0.1411020E-08 0.7879684E-04 6.3337 12 K+ 0.2186022E-04 0.2186895E-04 0.8550722E+00 3.3915 13 Na+ 0.2891492E-03 0.2893689E-03 0.6652162E+01 4.5130 14 Mn++ 0.2303734E-07 0.3122169E-07 0.1715162E-02 8.4519 15 HPO4-- 0.8790287E-08 0.1000580E-07 0.9602937E-03 8.0336 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1692487E-02 -.1369466E-03 -.1555540E-02 0.0000000E+00 2 H2O 0.5550696E+02 0.5550680E+02 0.1623440E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2835895E-04 0.2550441E-04 0.2854542E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2854481E-05 0.6054021E-10 -.2854542E-05 0.0000000E+00 7 Al+++ 0.3358564E-03 0.4288096E-05 0.3315683E-03 0.0000000E+00 8 H4SiO4 0.1072517E-02 0.4290486E-03 0.6434680E-03 0.0000000E+00 9 Ca++ 0.1329358E-03 0.7399374E-05 0.1255364E-03 0.0000000E+00 10 Mg++ 0.8174603E-04 0.3097538E-07 0.8171506E-04 0.0000000E+00 11 Fe++ 0.7343989E-04 0.1410982E-08 0.7343847E-04 0.0000000E+00 12 K+ 0.2186837E-04 0.2186837E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2893611E-03 0.2893611E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1785875E-05 0.3122085E-07 0.1754655E-05 0.0000000E+00 15 HPO4-- 0.6095104E-06 0.1000554E-07 0.5995049E-06 0.0000000E+00 Chg. balance for solid moles: 0.2160E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1030000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1998E-06 -6.699 0.1004E-03 -3.998 0.1201 0.3190E-04 clinochlore 0.1634E-04 -4.787 0.9084E-02 -2.042 10.87 0.3455E-02 daphnite 0.1012E-04 -4.995 0.7221E-02 -2.141 8.637 0.2188E-02 chlorite-Mn 0.3509E-06 -6.455 0.2488E-03 -3.604 0.2976 0.7929E-04 hematite 0.1142E-04 -4.942 0.1823E-02 -2.739 2.181 0.3456E-03 kaolinite 0.1443E-04 -4.841 0.3726E-02 -2.429 4.457 0.1434E-02 lawsonite 0.6752E-04 -4.171 0.2122E-01 -1.673 25.38 0.6842E-02 stilbite 0.5702E-04 -4.244 0.4018E-01 -1.396 48.06 0.1874E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3774E+00 0.3774E+00 1.0000 -0.423 chlorite-Mn 0.1309E-01 0.1309E-01 1.0000 -1.883 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.083602 g Volume = 0.033117 cm3 Porosity: 96.8193% V(tot) - V(min): 0.10081E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1030000 g log = -0.9872 Original solution: 1000.0103000 g Original solution / Rock added: 9708.84 (Water/Rock Ratio), log = 3.9872 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2252E-04 1.0073 0.2386E-04 0.2369E-04 CH4,gas 0.2862E-15 1.0129 0.3050E-15 0.3011E-15 H2,gas 0.5762E-06 1.0006 0.6065E-06 0.6062E-06 H2S,gas 0.2596E-12 0.9959 0.2720E-12 0.2731E-12 S2,gas 0.7161E-32 1.0000 0.7533E-32 0.7533E-32 CO,gas 0.3564E-14 1.0000 0.3749E-14 0.3749E-14 SO3,gas 0.5803E-36 1.0000 0.6104E-36 0.6104E-36 SO2,gas 0.1331E-19 1.0000 0.1401E-19 0.1401E-19 HCl,gas 0.3546E-15 1.0000 0.3730E-15 0.3730E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.60662E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.84926E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.24265E-10 164 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -12.99 -6.62 -2.207 0.11307E+05 -4.622 3 CH4,gas 4.81 -12.71 -17.52 -4.379 0.29908E+05 -15.516 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -20.51 -14.57 -7.283 0.24870E+05 -12.565 6 S2,gas -7.03 -41.16 -34.12 -5.250 0.58264E+05 -32.123 7 CO,gas 3.51 -12.92 -16.43 -5.054 0.28047E+05 -14.426 8 SO3,gas 17.43 -20.79 -38.21 -9.554 0.65250E+05 -36.214 9 SO2,gas 1.14 -20.72 -21.85 -5.828 0.37315E+05 -19.854 10 HCl,gas 5.48 -11.95 -17.43 -8.714 0.29758E+05 -15.428 11 acmite 7.74 3.98 -3.76 -0.391 0.64189E+04 15 albite-high 0.75 -2.96 -3.71 -0.285 0.63295E+04 16 albite -0.33 -2.96 -2.63 -0.202 0.44888E+04 19 spessartine 24.55 20.67 -3.88 -0.194 0.66320E+04 20 analcite 3.37 0.46 -2.91 -0.323 0.49706E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -9.84 -4.56 -2.278 0.77789E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.03 -3.02 -1.007 0.51570E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68555E+04 37 calcite 0.83 -2.03 -2.87 -0.956 0.48956E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29409E+04 42 celadonite 5.40 1.07 -4.33 -0.255 0.74011E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43642E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.12999E+04 52 chloritoid-Mn 11.46 10.60 -0.87 -0.058 0.14814E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60377E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64763E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82444E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68758E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.46 -3.79 -0.379 0.64736E+04 97 kalsilite 7.62 2.75 -4.87 -0.695 0.83074E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.66 -4.83 -0.483 0.82463E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75750E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20515E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -4.08 -1.65 -0.127 0.28121E+04 120 muscovite 2.68 1.48 -1.20 -0.070 0.20445E+04 121 paragonite 4.34 2.60 -1.73 -0.102 0.29597E+04 122 nepheline 8.38 3.88 -4.50 -0.643 0.76866E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50038E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.476 0.40654E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.53 -3.58 -1.192 0.61043E+04 153 rhodonite 7.46 5.04 -2.43 -0.485 0.41446E+04 154 sanidine -1.22 -4.08 -2.86 -0.220 0.48799E+04 156 siderite -2.59 -6.65 -4.06 -1.355 0.69395E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.59 -1.59 -0.047 0.27139E+04 166 stilpnomelane-Mg 27.60 22.73 -4.87 -0.145 0.83100E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83651E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55023E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77451E+04 175 tephroite 18.11 13.49 -4.63 -0.661 0.78986E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.94 -3.51 -0.215 0.59891E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.57 -3.32 -0.203 0.56611E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -5.08 -2.92 -0.179 0.49838E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40718E+04 205 montmorillonite-Na -1.96 -4.71 -2.75 -0.168 0.46940E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.09 -1.31 -0.084 0.22356E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.46 -1.12 -0.072 0.19094E+04 215 gypsum -4.92 -9.84 -4.91 -1.228 0.83857E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59600E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.43 -2.51 -0.193 0.42847E+04 244 an25ab75 2.71 0.20 -2.51 -0.193 0.42815E+04 245 an30ab70 3.34 0.83 -2.51 -0.193 0.42868E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1030000 g New total amount of reactant added: 0.1070000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1070000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3190050E-03 Osmotic coef. = 0.9894 True ionic strength = .3629747E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.85463E-08 -8.0682 0.81852E-08 -8.0870 0.95775E+00 -0.0187 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13211E-03 -3.8790 0.95760E+00 -0.0188 4 SO4-- 0.25455E-04 -4.5942 0.22591E-04 -4.6461 0.88749E+00 -0.0518 5 HCO3- 0.12703E-04 -4.8961 0.12165E-04 -4.9149 0.95763E+00 -0.0188 6 HS- 0.36695E-12 -12.4354 0.35139E-12 -12.4542 0.95760E+00 -0.0188 7 Al+++ 0.42311E-21 -21.3735 0.33065E-21 -21.4806 0.78146E+00 -0.1071 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.67530E-05 -5.1705 0.59920E-05 -5.2224 0.88732E+00 -0.0519 10 Mg++ 0.27517E-07 -7.5604 0.24414E-07 -7.6124 0.88721E+00 -0.0520 11 Fe++ 0.16281E-09 -9.7883 0.14445E-09 -9.8403 0.88723E+00 -0.0520 12 K+ 0.22709E-04 -4.6438 0.21747E-04 -4.6626 0.95764E+00 -0.0188 13 Na+ 0.29416E-03 -3.5314 0.28168E-03 -3.5502 0.95759E+00 -0.0188 14 Mn++ 0.21413E-07 -7.6693 0.18998E-07 -7.7213 0.88725E+00 -0.0520 15 HPO4-- 0.94841E-08 -8.0230 0.84170E-08 -8.0748 0.88749E+00 -0.0518 16 HSiO3- 0.47670E-04 -4.3218 0.45648E-04 -4.3406 0.95760E+00 -0.0188 17 Ca(HSiO3)+ 0.63995E-08 -8.1939 0.61284E-08 -8.2126 0.95765E+00 -0.0188 18 Mg(HSiO3)+ 0.32449E-10 -10.4888 0.31075E-10 -10.5076 0.95765E+00 -0.0188 19 NaHSiO3,aq 0.20422E-06 -6.6899 0.20422E-06 -6.6899 0.10000E+01 0.0000 20 AlO+ 0.66529E-12 -12.1770 0.63711E-12 -12.1958 0.95765E+00 -0.0188 21 AlOH+2 0.29442E-16 -16.5310 0.26124E-16 -16.5830 0.88728E+00 -0.0519 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.44374E-05 -5.3529 0.42490E-05 -5.3717 0.95755E+00 -0.0188 24 CH4,aq 0.18569E-18 -18.7312 0.18567E-18 -18.7313 0.99990E+00 0.0000 29 CO,aq 0.22861E-17 -17.6409 0.22861E-17 -17.6409 0.10000E+01 0.0000 30 CO2,aq 0.20077E-06 -6.6973 0.20075E-06 -6.6973 0.99990E+00 0.0000 31 CO3-2 0.15484E-06 -6.8101 0.13741E-06 -6.8620 0.88743E+00 -0.0519 32 CaCO3,aq 0.10084E-07 -7.9964 0.10084E-07 -7.9964 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.19179E-08 -8.7172 0.18366E-08 -8.7360 0.95765E+00 -0.0188 34 CaCl+ 0.13173E-08 -8.8803 0.12615E-08 -8.8991 0.95765E+00 -0.0188 35 CaCl2,aq 0.38804E-13 -13.4111 0.38804E-13 -13.4111 0.10000E+01 0.0000 36 CaOH+ 0.53902E-07 -7.2684 0.51619E-07 -7.2872 0.95765E+00 -0.0188 37 CaSO4,aq 0.42177E-07 -7.3749 0.42177E-07 -7.3749 0.10000E+01 0.0000 38 HCl,aq 0.20341E-12 -12.6916 0.20341E-12 -12.6916 0.10000E+01 0.0000 43 FeCl+ 0.31038E-13 -13.5081 0.29723E-13 -13.5269 0.95765E+00 -0.0188 46 FeO,aq 0.85258E-10 -10.0693 0.85258E-10 -10.0693 0.10000E+01 0.0000 47 FeOH+ 0.61094E-09 -9.2140 0.58506E-09 -9.2328 0.95765E+00 -0.0188 48 HFeO2- 0.11700E-09 -9.9318 0.11204E-09 -9.9506 0.95760E+00 -0.0188 49 FeO+ 0.70704E-13 -13.1506 0.67709E-13 -13.1694 0.95765E+00 -0.0188 50 FeOH+2 0.11623E-18 -18.9347 0.10313E-18 -18.9866 0.88728E+00 -0.0519 51 FeO2- 0.20742E-09 -9.6831 0.19863E-09 -9.7020 0.95760E+00 -0.0188 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44220E-09 -9.3544 0.44215E-09 -9.3544 0.99990E+00 0.0000 54 KCl,aq 0.50873E-10 -10.2935 0.50873E-10 -10.2935 0.10000E+01 0.0000 55 KHSO4,aq 0.10761E-16 -16.9682 0.10761E-16 -16.9682 0.10000E+01 0.0000 56 KOH,aq 0.11583E-08 -8.9362 0.11583E-08 -8.9362 0.10000E+01 0.0000 57 KSO4- 0.79041E-08 -8.1021 0.75689E-08 -8.1210 0.95760E+00 -0.0188 58 MgCO3,aq 0.10267E-10 -10.9886 0.10267E-10 -10.9886 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.79682E-11 -11.0986 0.76307E-11 -11.1174 0.95765E+00 -0.0188 60 MgCl+ 0.48722E-11 -11.3123 0.46659E-11 -11.3311 0.95765E+00 -0.0188 61 MgOH+ 0.12167E-08 -8.9148 0.11652E-08 -8.9336 0.95765E+00 -0.0188 63 MnO,aq 0.29935E-09 -9.5238 0.29935E-09 -9.5238 0.10000E+01 0.0000 64 MnOH+ 0.74644E-08 -8.1270 0.71483E-08 -8.1458 0.95765E+00 -0.0188 65 MnO2-2 0.17412E-15 -15.7592 0.15452E-15 -15.8110 0.88743E+00 -0.0519 66 HMnO2- 0.28616E-12 -12.5434 0.27403E-12 -12.5622 0.95760E+00 -0.0188 69 MnCl+ 0.15863E-10 -10.7996 0.15191E-10 -10.8184 0.95765E+00 -0.0188 70 MnSO4,aq 0.12163E-09 -9.9149 0.12163E-09 -9.9149 0.10000E+01 0.0000 71 NaCl,aq 0.12152E-07 -7.9154 0.12152E-07 -7.9154 0.10000E+01 0.0000 72 NaOH,aq 0.15122E-07 -7.8204 0.15122E-07 -7.8204 0.10000E+01 0.0000 74 OH- 0.76531E-04 -4.1162 0.73283E-04 -4.1350 0.95755E+00 -0.0188 79 HPO3-2 0.13246E-19 -19.8779 0.11755E-19 -19.9298 0.88743E+00 -0.0519 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.12613E-08 -8.8992 0.12079E-08 -8.9180 0.95762E+00 -0.0188 84 PO4-3 0.11477E-11 -11.9402 0.89804E-12 -12.0467 0.78249E+00 -0.1065 87 H2P2O7-2 0.12867E-18 -18.8905 0.11418E-18 -18.9424 0.88743E+00 -0.0519 88 HP2O7-3 0.36604E-17 -17.4365 0.28605E-17 -17.5436 0.78147E+00 -0.1071 89 P2O7-4 0.13171E-18 -18.8804 0.86215E-19 -19.0644 0.65457E+00 -0.1840 90 H2S,aq 0.86426E-14 -14.0634 0.86417E-14 -14.0634 0.99990E+00 0.0000 97 SO3-2 0.15341E-14 -14.8141 0.13619E-14 -14.8658 0.88778E+00 -0.0517 98 HSO3- 0.68127E-15 -15.1667 0.65238E-15 -15.1855 0.95760E+00 -0.0188 99 HSO4- 0.17915E-09 -9.7468 0.17157E-09 -9.7656 0.95767E+00 -0.0188 Charge balance for all species = 0.7207E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8546285E-08 -.1422439E-03 -.1433653E+00 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999425E+06 0.0000 3 Cl- 0.1379644E-03 0.1379780E-03 0.4891460E+01 4.2079 4 SO4-- 0.2545479E-04 0.2550511E-04 0.2449925E+01 11.5279 5 HCO3- 0.1270273E-04 0.1307036E-04 0.7974722E+00 3.1721 6 HS- 0.3669474E-12 0.5955440E-10 0.1969473E-05 -4.3672 7 Al+++ 0.4231141E-21 0.4452983E-05 0.1201415E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4308408E-03 0.4140812E+02 -3.4168 9 Ca++ 0.6753011E-05 0.6868809E-05 0.2752727E+00 10.9515 10 Mg++ 0.2751736E-07 0.2878961E-07 0.6998938E-03 8.5616 11 Fe++ 0.1628087E-09 0.1386996E-08 0.7745523E-04 6.3337 12 K+ 0.2270914E-04 0.2271825E-04 0.8882793E+00 3.4244 13 Na+ 0.2941587E-03 0.2943902E-03 0.6767593E+01 4.5367 14 Mn++ 0.2141261E-07 0.2931418E-07 0.1610372E-02 8.4527 15 HPO4-- 0.9484082E-08 0.1074656E-07 0.1031386E-02 8.0991 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1758721E-02 -.1422399E-03 -.1616481E-02 0.0000000E+00 2 H2O 0.5550691E+02 0.5550675E+02 0.1540340E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2846980E-04 0.2550441E-04 0.2965394E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2965335E-05 0.5955276E-10 -.2965394E-05 0.0000000E+00 7 Al+++ 0.3488994E-03 0.4452860E-05 0.3444465E-03 0.0000000E+00 8 H4SiO4 0.1114168E-02 0.4308289E-03 0.6833389E-03 0.0000000E+00 9 Ca++ 0.1375363E-03 0.6868619E-05 0.1306677E-03 0.0000000E+00 10 Mg++ 0.8492063E-04 0.2878881E-07 0.8489185E-04 0.0000000E+00 11 Fe++ 0.7629192E-04 0.1386958E-08 0.7629053E-04 0.0000000E+00 12 K+ 0.2271762E-04 0.2271762E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2943821E-03 0.2943821E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1855230E-05 0.2931337E-07 0.1825916E-05 0.0000000E+00 15 HPO4-- 0.6331807E-06 0.1074626E-07 0.6224344E-06 0.0000000E+00 Chg. balance for solid moles: 0.9317E-20 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1070000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2075E-06 -6.683 0.1042E-03 -3.982 0.1184 0.3312E-04 clinochlore 0.1698E-04 -4.770 0.9437E-02 -2.025 10.72 0.3590E-02 daphnite 0.1051E-04 -4.978 0.7501E-02 -2.125 8.522 0.2273E-02 chlorite-Mn 0.3652E-06 -6.437 0.2589E-03 -3.587 0.2941 0.8251E-04 hematite 0.1186E-04 -4.926 0.1894E-02 -2.723 2.152 0.3590E-03 kaolinite 0.1474E-04 -4.832 0.3804E-02 -2.420 4.322 0.1464E-02 lawsonite 0.6742E-04 -4.171 0.2119E-01 -1.674 24.07 0.6832E-02 stilbite 0.6221E-04 -4.206 0.4384E-01 -1.358 49.80 0.2045E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3774E+00 0.3774E+00 1.0000 -0.423 chlorite-Mn 0.1311E-01 0.1311E-01 1.0000 -1.882 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.088026 g Volume = 0.035081 cm3 Porosity: 96.6359% V(tot) - V(min): 0.10077E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1070000 g log = -0.9706 Original solution: 1000.0103000 g Original solution / Rock added: 9345.89 (Water/Rock Ratio), log = 3.9706 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2169E-04 1.0073 0.2298E-04 0.2281E-04 CH4,gas 0.2756E-15 1.0129 0.2936E-15 0.2899E-15 H2,gas 0.5762E-06 1.0006 0.6064E-06 0.6061E-06 H2S,gas 0.2406E-12 0.9959 0.2520E-12 0.2531E-12 S2,gas 0.6150E-32 1.0000 0.6470E-32 0.6470E-32 CO,gas 0.3432E-14 1.0000 0.3610E-14 0.3610E-14 SO3,gas 0.5379E-36 1.0000 0.5658E-36 0.5658E-36 SO2,gas 0.1234E-19 1.0000 0.1298E-19 0.1298E-19 HCl,gas 0.3414E-15 1.0000 0.3592E-15 0.3592E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 164 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.00 -6.64 -2.213 0.11335E+05 -4.639 3 CH4,gas 4.81 -12.72 -17.53 -4.383 0.29936E+05 -15.532 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -20.54 -14.60 -7.299 0.24927E+05 -12.599 6 S2,gas -7.03 -41.22 -34.19 -5.260 0.58377E+05 -32.189 7 CO,gas 3.51 -12.93 -16.44 -5.059 0.28075E+05 -14.443 8 SO3,gas 17.43 -20.82 -38.25 -9.562 0.65306E+05 -36.247 9 SO2,gas 1.14 -20.75 -21.89 -5.836 0.37371E+05 -19.887 10 HCl,gas 5.48 -11.97 -17.44 -8.722 0.29786E+05 -15.445 11 acmite 7.74 4.00 -3.74 -0.388 0.63783E+04 15 albite-high 0.75 -2.93 -3.68 -0.283 0.62889E+04 16 albite -0.33 -2.93 -2.61 -0.200 0.44483E+04 19 spessartine 24.55 20.67 -3.88 -0.194 0.66283E+04 20 analcite 3.37 0.48 -2.89 -0.321 0.49300E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -9.87 -4.59 -2.294 0.78352E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.05 -3.04 -1.012 0.51849E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68555E+04 37 calcite 0.83 -2.05 -2.88 -0.961 0.49235E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29409E+04 42 celadonite 5.40 1.10 -4.30 -0.253 0.73450E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43642E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.12999E+04 52 chloritoid-Mn 11.46 10.60 -0.87 -0.058 0.14801E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64763E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82445E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68759E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.48 -3.77 -0.377 0.64331E+04 97 kalsilite 7.62 2.79 -4.83 -0.690 0.82513E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.63 -4.80 -0.480 0.81902E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75750E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20515E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -4.05 -1.61 -0.124 0.27560E+04 120 muscovite 2.68 1.51 -1.16 -0.069 0.19884E+04 121 paragonite 4.34 2.63 -1.71 -0.101 0.29191E+04 122 nepheline 8.38 3.90 -4.48 -0.640 0.76460E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50038E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.476 0.40642E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.55 -3.59 -1.197 0.61310E+04 153 rhodonite 7.46 5.04 -2.43 -0.485 0.41434E+04 154 sanidine -1.22 -4.05 -2.83 -0.217 0.48238E+04 156 siderite -2.59 -6.67 -4.08 -1.360 0.69674E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.61 -1.57 -0.047 0.26860E+04 166 stilpnomelane-Mg 27.60 22.75 -4.85 -0.145 0.82820E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83652E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55023E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77452E+04 175 tephroite 18.11 13.49 -4.62 -0.661 0.78961E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.93 -3.50 -0.214 0.59705E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.56 -3.31 -0.203 0.56477E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -5.07 -2.91 -0.178 0.49653E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40718E+04 205 montmorillonite-Na -1.96 -4.70 -2.74 -0.168 0.46806E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.11 -1.30 -0.083 0.22171E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.47 -1.11 -0.071 0.18960E+04 215 gypsum -4.92 -9.87 -4.94 -1.236 0.84419E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59600E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.41 -2.49 -0.192 0.42522E+04 244 an25ab75 2.71 0.22 -2.49 -0.192 0.42511E+04 245 an30ab70 3.34 0.85 -2.49 -0.192 0.42584E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1070000 g New total amount of reactant added: 0.1110000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7207E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1110000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3217227E-03 Osmotic coef. = 0.9893 True ionic strength = .3673944E-03 Chg. balance for total moles = 0.7207E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.82370E-08 -8.0842 0.78878E-08 -8.1030 0.95761E+00 -0.0188 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13209E-03 -3.8791 0.95745E+00 -0.0189 4 SO4-- 0.25458E-04 -4.5942 0.22580E-04 -4.6463 0.88695E+00 -0.0521 5 HCO3- 0.12705E-04 -4.8960 0.12165E-04 -4.9149 0.95749E+00 -0.0189 6 HS- 0.35338E-12 -12.4518 0.33835E-12 -12.4706 0.95746E+00 -0.0189 7 Al+++ 0.37916E-21 -21.4212 0.29590E-21 -21.5289 0.78041E+00 -0.1077 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.62749E-05 -5.2024 0.55645E-05 -5.2546 0.88678E+00 -0.0522 10 Mg++ 0.25569E-07 -7.5923 0.22671E-07 -7.6445 0.88667E+00 -0.0522 11 Fe++ 0.15128E-09 -9.8202 0.13414E-09 -9.8725 0.88670E+00 -0.0522 12 K+ 0.23558E-04 -4.6279 0.22557E-04 -4.6467 0.95750E+00 -0.0189 13 Na+ 0.29917E-03 -3.5241 0.28644E-03 -3.5430 0.95745E+00 -0.0189 14 Mn++ 0.19926E-07 -7.7006 0.17669E-07 -7.7528 0.88672E+00 -0.0522 15 HPO4-- 0.10219E-07 -7.9906 0.90637E-08 -8.0427 0.88696E+00 -0.0521 16 HSiO3- 0.49475E-04 -4.3056 0.47370E-04 -4.3245 0.95745E+00 -0.0189 17 Ca(HSiO3)+ 0.61679E-08 -8.2099 0.59058E-08 -8.2287 0.95750E+00 -0.0189 18 Mg(HSiO3)+ 0.31274E-10 -10.5048 0.29945E-10 -10.5237 0.95750E+00 -0.0189 19 NaHSiO3,aq 0.21550E-06 -6.6666 0.21550E-06 -6.6666 0.10000E+01 0.0000 20 AlO+ 0.64121E-12 -12.1930 0.61396E-12 -12.2119 0.95750E+00 -0.0189 21 AlOH+2 0.27358E-16 -16.5629 0.24260E-16 -16.6151 0.88674E+00 -0.0522 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.46054E-05 -5.3367 0.44093E-05 -5.3556 0.95741E+00 -0.0189 24 CH4,aq 0.17888E-18 -18.7474 0.17886E-18 -18.7475 0.99990E+00 0.0000 29 CO,aq 0.22029E-17 -17.6570 0.22029E-17 -17.6570 0.10000E+01 0.0000 30 CO2,aq 0.19348E-06 -6.7134 0.19346E-06 -6.7134 0.99990E+00 0.0000 31 CO3-2 0.16077E-06 -6.7938 0.14259E-06 -6.8459 0.88690E+00 -0.0521 32 CaCO3,aq 0.97178E-08 -8.0124 0.97178E-08 -8.0124 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.17813E-08 -8.7493 0.17056E-08 -8.7681 0.95750E+00 -0.0189 34 CaCl+ 0.12233E-08 -8.9125 0.11713E-08 -8.9313 0.95750E+00 -0.0189 35 CaCl2,aq 0.36024E-13 -13.4434 0.36024E-13 -13.4434 0.10000E+01 0.0000 36 CaOH+ 0.51952E-07 -7.2844 0.49744E-07 -7.3033 0.95750E+00 -0.0189 37 CaSO4,aq 0.39148E-07 -7.4073 0.39148E-07 -7.4073 0.10000E+01 0.0000 38 HCl,aq 0.19598E-12 -12.7078 0.19598E-12 -12.7078 0.10000E+01 0.0000 43 FeCl+ 0.28822E-13 -13.5403 0.27597E-13 -13.5591 0.95750E+00 -0.0189 46 FeO,aq 0.85255E-10 -10.0693 0.85255E-10 -10.0693 0.10000E+01 0.0000 47 FeOH+ 0.58880E-09 -9.2300 0.56378E-09 -9.2489 0.95750E+00 -0.0189 48 HFeO2- 0.12142E-09 -9.9157 0.11626E-09 -9.9346 0.95745E+00 -0.0189 49 FeO+ 0.68145E-13 -13.1666 0.65249E-13 -13.1854 0.95750E+00 -0.0189 50 FeOH+2 0.10800E-18 -18.9666 0.95770E-19 -19.0188 0.88674E+00 -0.0522 51 FeO2- 0.21528E-09 -9.6670 0.20612E-09 -9.6859 0.95745E+00 -0.0189 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44216E-09 -9.3544 0.44212E-09 -9.3545 0.99990E+00 0.0000 54 KCl,aq 0.52759E-10 -10.2777 0.52759E-10 -10.2777 0.10000E+01 0.0000 55 KHSO4,aq 0.10751E-16 -16.9686 0.10751E-16 -16.9686 0.10000E+01 0.0000 56 KOH,aq 0.12467E-08 -8.9042 0.12467E-08 -8.9042 0.10000E+01 0.0000 57 KSO4- 0.81956E-08 -8.0864 0.78469E-08 -8.1053 0.95745E+00 -0.0189 58 MgCO3,aq 0.98936E-11 -11.0046 0.98936E-11 -11.0046 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.74007E-11 -11.1307 0.70862E-11 -11.1496 0.95750E+00 -0.0189 60 MgCl+ 0.45245E-11 -11.3444 0.43323E-11 -11.3633 0.95750E+00 -0.0189 61 MgOH+ 0.11726E-08 -8.9308 0.11228E-08 -8.9497 0.95750E+00 -0.0189 63 MnO,aq 0.29978E-09 -9.5232 0.29978E-09 -9.5232 0.10000E+01 0.0000 64 MnOH+ 0.72048E-08 -8.1424 0.68986E-08 -8.1612 0.95750E+00 -0.0189 65 MnO2-2 0.18788E-15 -15.7261 0.16663E-15 -15.7782 0.88690E+00 -0.0521 66 HMnO2- 0.29743E-12 -12.5266 0.28478E-12 -12.5455 0.95745E+00 -0.0189 69 MnCl+ 0.14752E-10 -10.8311 0.14126E-10 -10.8500 0.95750E+00 -0.0189 70 MnSO4,aq 0.11306E-09 -9.9467 0.11306E-09 -9.9467 0.10000E+01 0.0000 71 NaCl,aq 0.12355E-07 -7.9082 0.12355E-07 -7.9082 0.10000E+01 0.0000 72 NaOH,aq 0.15957E-07 -7.7971 0.15957E-07 -7.7971 0.10000E+01 0.0000 74 OH- 0.79429E-04 -4.1000 0.76046E-04 -4.1189 0.95741E+00 -0.0189 79 HPO3-2 0.14271E-19 -19.8455 0.12657E-19 -19.8977 0.88690E+00 -0.0521 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.13091E-08 -8.8830 0.12534E-08 -8.9019 0.95748E+00 -0.0189 84 PO4-3 0.12842E-11 -11.8914 0.10035E-11 -11.9985 0.78144E+00 -0.1071 87 H2P2O7-2 0.13864E-18 -18.8581 0.12296E-18 -18.9102 0.88690E+00 -0.0521 88 HP2O7-3 0.40959E-17 -17.3877 0.31965E-17 -17.4953 0.78042E+00 -0.1077 89 P2O7-4 0.15310E-18 -18.8150 0.99973E-19 -19.0001 0.65300E+00 -0.1851 90 H2S,aq 0.80194E-14 -14.0959 0.80186E-14 -14.0959 0.99990E+00 0.0000 97 SO3-2 0.15341E-14 -14.8141 0.13612E-14 -14.8661 0.88725E+00 -0.0520 98 HSO3- 0.65624E-15 -15.1829 0.62832E-15 -15.2018 0.95745E+00 -0.0189 99 HSO4- 0.17259E-09 -9.7630 0.16526E-09 -9.7818 0.95753E+00 -0.0188 Charge balance for all species = 0.7206E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8236964E-08 -.1476415E-03 -.1488054E+00 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999422E+06 0.0000 3 Cl- 0.1379644E-03 0.1379781E-03 0.4891462E+01 4.2239 4 SO4-- 0.2545756E-04 0.2550514E-04 0.2449926E+01 11.5598 5 HCO3- 0.1270460E-04 0.1307037E-04 0.7974726E+00 3.1881 6 HS- 0.3533813E-12 0.5855009E-10 0.1936260E-05 -4.3676 7 Al+++ 0.3791572E-21 0.4621001E-05 0.1246745E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4326568E-03 0.4158264E+02 -3.4168 9 Ca++ 0.6274926E-05 0.6384915E-05 0.2558803E+00 10.9515 10 Mg++ 0.2556911E-07 0.2679485E-07 0.6513998E-03 8.5616 11 Fe++ 0.1512766E-09 0.1365600E-08 0.7626037E-04 6.3336 12 K+ 0.2355805E-04 0.2356755E-04 0.9214864E+00 3.4563 13 Na+ 0.2991677E-03 0.2994115E-03 0.6883024E+01 4.5601 14 Mn++ 0.1992583E-07 0.2755854E-07 0.1513926E-02 8.4533 15 HPO4-- 0.1021891E-07 0.1152928E-07 0.1106507E-02 8.1634 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1824955E-02 -.1476373E-03 -.1677318E-02 0.0000000E+00 2 H2O 0.5550686E+02 0.5550671E+02 0.1457072E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2858066E-04 0.2550441E-04 0.3076247E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3076188E-05 0.5854843E-10 -.3076247E-05 0.0000000E+00 7 Al+++ 0.3619423E-03 0.4620870E-05 0.3573214E-03 0.0000000E+00 8 H4SiO4 0.1155819E-02 0.4326445E-03 0.7231744E-03 0.0000000E+00 9 Ca++ 0.1421369E-03 0.6384734E-05 0.1357522E-03 0.0000000E+00 10 Mg++ 0.8809524E-04 0.2679409E-07 0.8806844E-04 0.0000000E+00 11 Fe++ 0.7914395E-04 0.1365561E-08 0.7914259E-04 0.0000000E+00 12 K+ 0.2356688E-04 0.2356688E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.2994030E-03 0.2994030E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1924584E-05 0.2755775E-07 0.1897026E-05 0.0000000E+00 15 HPO4-- 0.6568510E-06 0.1152895E-07 0.6453221E-06 0.0000000E+00 Chg. balance for solid moles: -.1038E-19 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1110000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2151E-06 -6.667 0.1081E-03 -3.966 0.1169 0.3434E-04 clinochlore 0.1761E-04 -4.754 0.9790E-02 -2.009 10.59 0.3724E-02 daphnite 0.1091E-04 -4.962 0.7782E-02 -2.109 8.418 0.2358E-02 chlorite-Mn 0.3794E-06 -6.421 0.2690E-03 -3.570 0.2910 0.8572E-04 hematite 0.1230E-04 -4.910 0.1965E-02 -2.707 2.126 0.3725E-03 kaolinite 0.1508E-04 -4.821 0.3894E-02 -2.410 4.213 0.1498E-02 lawsonite 0.6729E-04 -4.172 0.2114E-01 -1.675 22.87 0.6818E-02 stilbite 0.6739E-04 -4.171 0.4749E-01 -1.323 51.37 0.2215E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3774E+00 0.3774E+00 1.0000 -0.423 chlorite-Mn 0.1313E-01 0.1313E-01 1.0000 -1.882 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.092444 g Volume = 0.037042 cm3 Porosity: 96.4532% V(tot) - V(min): 0.10074E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1110000 g log = -0.9547 Original solution: 1000.0103000 g Original solution / Rock added: 9009.10 (Water/Rock Ratio), log = 3.9547 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2090E-04 1.0073 0.2214E-04 0.2198E-04 CH4,gas 0.2655E-15 1.0129 0.2829E-15 0.2792E-15 H2,gas 0.5761E-06 1.0006 0.6064E-06 0.6061E-06 H2S,gas 0.2232E-12 0.9959 0.2339E-12 0.2348E-12 S2,gas 0.5296E-32 1.0000 0.5571E-32 0.5571E-32 CO,gas 0.3307E-14 1.0000 0.3478E-14 0.3478E-14 SO3,gas 0.4993E-36 1.0000 0.5252E-36 0.5252E-36 SO2,gas 0.1145E-19 1.0000 0.1205E-19 0.1205E-19 HCl,gas 0.3290E-15 1.0000 0.3461E-15 0.3461E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.24265E-10 164 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.02 -6.65 -2.218 0.11363E+05 -4.655 3 CH4,gas 4.81 -12.74 -17.55 -4.387 0.29963E+05 -15.548 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -20.57 -14.63 -7.316 0.24982E+05 -12.631 6 S2,gas -7.03 -41.29 -34.25 -5.270 0.58488E+05 -32.254 7 CO,gas 3.51 -12.95 -16.46 -5.064 0.28103E+05 -14.459 8 SO3,gas 17.43 -20.85 -38.28 -9.570 0.65361E+05 -36.280 9 SO2,gas 1.14 -20.78 -21.92 -5.845 0.37426E+05 -19.919 10 HCl,gas 5.48 -11.98 -17.46 -8.730 0.29814E+05 -15.461 11 acmite 7.74 4.03 -3.71 -0.386 0.63385E+04 15 albite-high 0.75 -2.91 -3.66 -0.282 0.62491E+04 16 albite -0.33 -2.91 -2.58 -0.199 0.44084E+04 19 spessartine 24.55 20.67 -3.88 -0.194 0.66250E+04 20 analcite 3.37 0.51 -2.86 -0.318 0.48902E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -9.90 -4.62 -2.311 0.78904E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.07 -3.05 -1.018 0.52123E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.07 -2.90 -0.967 0.49510E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29409E+04 42 celadonite 5.40 1.13 -4.27 -0.251 0.72904E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43642E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13000E+04 52 chloritoid-Mn 11.46 10.60 -0.87 -0.058 0.14790E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64764E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82446E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68760E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.51 -3.74 -0.374 0.63932E+04 97 kalsilite 7.62 2.82 -4.80 -0.686 0.81967E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.60 -4.76 -0.476 0.81357E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75750E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20516E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -4.01 -1.58 -0.122 0.27015E+04 120 muscovite 2.68 1.55 -1.13 -0.067 0.19339E+04 121 paragonite 4.34 2.65 -1.69 -0.099 0.28793E+04 122 nepheline 8.38 3.92 -4.45 -0.636 0.76061E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50038E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.476 0.40631E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.56 -3.61 -1.202 0.61574E+04 153 rhodonite 7.46 5.04 -2.43 -0.485 0.41423E+04 154 sanidine -1.22 -4.01 -2.79 -0.215 0.47692E+04 156 siderite -2.59 -6.68 -4.10 -1.366 0.69949E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.62 -1.56 -0.046 0.26589E+04 166 stilpnomelane-Mg 27.60 22.76 -4.83 -0.144 0.82547E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83652E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55023E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77452E+04 175 tephroite 18.11 13.49 -4.62 -0.660 0.78939E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.92 -3.49 -0.213 0.59525E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.56 -3.30 -0.202 0.56345E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -5.06 -2.90 -0.177 0.49473E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.69 -2.73 -0.167 0.46675E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.12 -1.29 -0.083 0.21991E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.48 -1.10 -0.071 0.18828E+04 215 gypsum -4.92 -9.90 -4.98 -1.244 0.84972E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59601E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.39 -2.47 -0.190 0.42203E+04 244 an25ab75 2.71 0.24 -2.47 -0.190 0.42212E+04 245 an30ab70 3.34 0.87 -2.48 -0.191 0.42305E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1110000 g New total amount of reactant added: 0.1150000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7207E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1150000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3245399E-03 Osmotic coef. = 0.9893 True ionic strength = .3719416E-03 Chg. balance for total moles = 0.7207E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.79446E-08 -8.0999 0.76066E-08 -8.1188 0.95746E+00 -0.0189 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13207E-03 -3.8792 0.95731E+00 -0.0189 4 SO4-- 0.25460E-04 -4.5941 0.22568E-04 -4.6465 0.88641E+00 -0.0524 5 HCO3- 0.12706E-04 -4.8960 0.12164E-04 -4.9149 0.95734E+00 -0.0189 6 HS- 0.34057E-12 -12.4678 0.32603E-12 -12.4867 0.95731E+00 -0.0189 7 Al+++ 0.34051E-21 -21.4679 0.26537E-21 -21.5762 0.77933E+00 -0.1083 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.58391E-05 -5.2337 0.51749E-05 -5.2861 0.88624E+00 -0.0524 10 Mg++ 0.23793E-07 -7.6235 0.21084E-07 -7.6761 0.88613E+00 -0.0525 11 Fe++ 0.14077E-09 -9.8515 0.12474E-09 -9.9040 0.88616E+00 -0.0525 12 K+ 0.24407E-04 -4.6125 0.23366E-04 -4.6314 0.95735E+00 -0.0189 13 Na+ 0.30418E-03 -3.5169 0.29119E-03 -3.5358 0.95730E+00 -0.0190 14 Mn++ 0.18566E-07 -7.7313 0.16453E-07 -7.7838 0.88617E+00 -0.0525 15 HPO4-- 0.10995E-07 -7.9588 0.97462E-08 -8.0112 0.88642E+00 -0.0524 16 HSiO3- 0.51311E-04 -4.2898 0.49121E-04 -4.3087 0.95731E+00 -0.0189 17 Ca(HSiO3)+ 0.59489E-08 -8.2256 0.56952E-08 -8.2445 0.95736E+00 -0.0189 18 Mg(HSiO3)+ 0.30164E-10 -10.5205 0.28878E-10 -10.5394 0.95736E+00 -0.0189 19 NaHSiO3,aq 0.22717E-06 -6.6436 0.22717E-06 -6.6436 0.10000E+01 0.0000 20 AlO+ 0.61845E-12 -12.2087 0.59208E-12 -12.2276 0.95736E+00 -0.0189 21 AlOH+2 0.25458E-16 -16.5942 0.22561E-16 -16.6466 0.88620E+00 -0.0525 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.47764E-05 -5.3209 0.45723E-05 -5.3399 0.95726E+00 -0.0190 24 CH4,aq 0.17245E-18 -18.7633 0.17243E-18 -18.7634 0.99990E+00 0.0000 29 CO,aq 0.21241E-17 -17.6728 0.21241E-17 -17.6728 0.10000E+01 0.0000 30 CO2,aq 0.18657E-06 -6.7292 0.18655E-06 -6.7292 0.99990E+00 0.0000 31 CO3-2 0.16681E-06 -6.7778 0.14785E-06 -6.8302 0.88636E+00 -0.0524 32 CaCO3,aq 0.93710E-08 -8.0282 0.93710E-08 -8.0282 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.16567E-08 -8.7808 0.15861E-08 -8.7997 0.95736E+00 -0.0189 34 CaCl+ 0.11376E-08 -8.9440 0.10891E-08 -8.9629 0.95736E+00 -0.0189 35 CaCl2,aq 0.33492E-13 -13.4751 0.33492E-13 -13.4751 0.10000E+01 0.0000 36 CaOH+ 0.50107E-07 -7.3001 0.47971E-07 -7.3190 0.95736E+00 -0.0189 37 CaSO4,aq 0.36388E-07 -7.4390 0.36388E-07 -7.4390 0.10000E+01 0.0000 38 HCl,aq 0.18897E-12 -12.7236 0.18897E-12 -12.7236 0.10000E+01 0.0000 43 FeCl+ 0.26803E-13 -13.5718 0.25660E-13 -13.5907 0.95736E+00 -0.0189 46 FeO,aq 0.85252E-10 -10.0693 0.85252E-10 -10.0693 0.10000E+01 0.0000 47 FeOH+ 0.56788E-09 -9.2457 0.54366E-09 -9.2647 0.95736E+00 -0.0189 48 HFeO2- 0.12593E-09 -9.8999 0.12055E-09 -9.9188 0.95731E+00 -0.0189 49 FeO+ 0.65726E-13 -13.1823 0.62923E-13 -13.2012 0.95736E+00 -0.0189 50 FeOH+2 0.10050E-18 -18.9978 0.89064E-19 -19.0503 0.88620E+00 -0.0525 51 FeO2- 0.22327E-09 -9.6512 0.21374E-09 -9.6701 0.95731E+00 -0.0189 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44213E-09 -9.3545 0.44209E-09 -9.3545 0.99990E+00 0.0000 54 KCl,aq 0.54643E-10 -10.2625 0.54643E-10 -10.2625 0.10000E+01 0.0000 55 KHSO4,aq 0.10734E-16 -16.9692 0.10734E-16 -16.9692 0.10000E+01 0.0000 56 KOH,aq 0.13391E-08 -8.8732 0.13391E-08 -8.8732 0.10000E+01 0.0000 57 KSO4- 0.84865E-08 -8.0713 0.81242E-08 -8.0902 0.95731E+00 -0.0189 58 MgCO3,aq 0.95404E-11 -11.0204 0.95404E-11 -11.0204 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.68831E-11 -11.1622 0.65896E-11 -11.1811 0.95736E+00 -0.0189 60 MgCl+ 0.42077E-11 -11.3760 0.40283E-11 -11.3949 0.95736E+00 -0.0189 61 MgOH+ 0.11310E-08 -8.9465 0.10828E-08 -8.9655 0.95736E+00 -0.0189 63 MnO,aq 0.30017E-09 -9.5226 0.30017E-09 -9.5226 0.10000E+01 0.0000 64 MnOH+ 0.69580E-08 -8.1575 0.66613E-08 -8.1764 0.95736E+00 -0.0189 65 MnO2-2 0.20241E-15 -15.6938 0.17941E-15 -15.7461 0.88636E+00 -0.0524 66 HMnO2- 0.30887E-12 -12.5102 0.29568E-12 -12.5292 0.95731E+00 -0.0189 69 MnCl+ 0.13737E-10 -10.8621 0.13151E-10 -10.8810 0.95736E+00 -0.0189 70 MnSO4,aq 0.10523E-09 -9.9779 0.10523E-09 -9.9779 0.10000E+01 0.0000 71 NaCl,aq 0.12558E-07 -7.9011 0.12558E-07 -7.9011 0.10000E+01 0.0000 72 NaOH,aq 0.16821E-07 -7.7741 0.16821E-07 -7.7741 0.10000E+01 0.0000 74 OH- 0.82378E-04 -4.0842 0.78857E-04 -4.1032 0.95726E+00 -0.0190 79 HPO3-2 0.15354E-19 -19.8138 0.13609E-19 -19.8662 0.88636E+00 -0.0524 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.13577E-08 -8.8672 0.12997E-08 -8.8861 0.95733E+00 -0.0189 84 PO4-3 0.14339E-11 -11.8435 0.11190E-11 -11.9512 0.78038E+00 -0.1077 87 H2P2O7-2 0.14917E-18 -18.8263 0.13222E-18 -18.8787 0.88636E+00 -0.0524 88 HP2O7-3 0.45734E-17 -17.3398 0.35642E-17 -17.4480 0.77934E+00 -0.1083 89 P2O7-4 0.17745E-18 -18.7509 0.11559E-18 -18.9371 0.65141E+00 -0.1861 90 H2S,aq 0.74520E-14 -14.1277 0.74512E-14 -14.1278 0.99990E+00 0.0000 97 SO3-2 0.15342E-14 -14.8141 0.13604E-14 -14.8663 0.88671E+00 -0.0522 98 HSO3- 0.63258E-15 -15.1989 0.60557E-15 -15.2178 0.95731E+00 -0.0189 99 HSO4- 0.16637E-09 -9.7789 0.15928E-09 -9.7978 0.95738E+00 -0.0189 Charge balance for all species = 0.7207E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7944552E-08 -.1531340E-03 -.1543412E+00 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999419E+06 0.0000 3 Cl- 0.1379644E-03 0.1379782E-03 0.4891465E+01 4.2396 4 SO4-- 0.2546007E-04 0.2550516E-04 0.2449928E+01 11.5911 5 HCO3- 0.1270595E-04 0.1307038E-04 0.7974729E+00 3.2039 6 HS- 0.3405667E-12 0.5753037E-10 0.1902537E-05 -4.3679 7 Al+++ 0.3405079E-21 0.4791975E-05 0.1292874E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4345049E-03 0.4176025E+02 -3.4168 9 Ca++ 0.5839122E-05 0.5943731E-05 0.2381994E+00 10.9515 10 Mg++ 0.2379318E-07 0.2497499E-07 0.6071576E-03 8.5616 11 Fe++ 0.1407655E-09 0.1346655E-08 0.7520238E-04 6.3336 12 K+ 0.2440697E-04 0.2441685E-04 0.9546936E+00 3.4874 13 Na+ 0.3041763E-03 0.3044329E-03 0.6998455E+01 4.5830 14 Mn++ 0.1856589E-07 0.2594335E-07 0.1425195E-02 8.4539 15 HPO4-- 0.1099506E-07 0.1235418E-07 0.1185675E-02 8.2265 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1891189E-02 -.1531295E-03 -.1738060E-02 0.0000000E+00 2 H2O 0.5550681E+02 0.5550667E+02 0.1373651E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2869151E-04 0.2550441E-04 0.3187100E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3187042E-05 0.5752869E-10 -.3187100E-05 0.0000000E+00 7 Al+++ 0.3749853E-03 0.4791835E-05 0.3701935E-03 0.0000000E+00 8 H4SiO4 0.1197470E-02 0.4344923E-03 0.7629778E-03 0.0000000E+00 9 Ca++ 0.1467375E-03 0.5943558E-05 0.1407939E-03 0.0000000E+00 10 Mg++ 0.9126984E-04 0.2497426E-07 0.9124487E-04 0.0000000E+00 11 Fe++ 0.8199599E-04 0.1346616E-08 0.8199464E-04 0.0000000E+00 12 K+ 0.2441614E-04 0.2441614E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3044240E-03 0.3044240E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1993939E-05 0.2594259E-07 0.1967996E-05 0.0000000E+00 15 HPO4-- 0.6805213E-06 0.1235382E-07 0.6681675E-06 0.0000000E+00 Chg. balance for solid moles: -.2687E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1150000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2227E-06 -6.652 0.1119E-03 -3.951 0.1155 0.3555E-04 clinochlore 0.1825E-04 -4.739 0.1014E-01 -1.994 10.47 0.3858E-02 daphnite 0.1130E-04 -4.947 0.8062E-02 -2.094 8.324 0.2443E-02 chlorite-Mn 0.3936E-06 -6.405 0.2791E-03 -3.554 0.2881 0.8893E-04 hematite 0.1275E-04 -4.895 0.2036E-02 -2.691 2.102 0.3859E-03 kaolinite 0.1547E-04 -4.810 0.3995E-02 -2.399 4.124 0.1537E-02 lawsonite 0.6711E-04 -4.173 0.2109E-01 -1.676 21.77 0.6801E-02 stilbite 0.7257E-04 -4.139 0.5114E-01 -1.291 52.80 0.2385E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3774E+00 0.3774E+00 1.0000 -0.423 chlorite-Mn 0.1315E-01 0.1315E-01 1.0000 -1.881 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.096857 g Volume = 0.039002 cm3 Porosity: 96.2713% V(tot) - V(min): 0.10070E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1150000 g log = -0.9393 Original solution: 1000.0103000 g Original solution / Rock added: 8695.74 (Water/Rock Ratio), log = 3.9393 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2015E-04 1.0073 0.2135E-04 0.2120E-04 CH4,gas 0.2559E-15 1.0129 0.2727E-15 0.2692E-15 H2,gas 0.5761E-06 1.0006 0.6064E-06 0.6060E-06 H2S,gas 0.2074E-12 0.9959 0.2173E-12 0.2182E-12 S2,gas 0.4574E-32 1.0000 0.4811E-32 0.4811E-32 CO,gas 0.3188E-14 1.0000 0.3354E-14 0.3354E-14 SO3,gas 0.4641E-36 1.0000 0.4882E-36 0.4882E-36 SO2,gas 0.1064E-19 1.0000 0.1120E-19 0.1120E-19 HCl,gas 0.3172E-15 1.0000 0.3337E-15 0.3337E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 164 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.03 -6.67 -2.224 0.11390E+05 -4.671 3 CH4,gas 4.81 -12.76 -17.56 -4.391 0.29991E+05 -15.564 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -20.61 -14.66 -7.331 0.25037E+05 -12.663 6 S2,gas -7.03 -41.35 -34.32 -5.280 0.58597E+05 -32.318 7 CO,gas 3.51 -12.96 -16.47 -5.069 0.28130E+05 -14.474 8 SO3,gas 17.43 -20.88 -38.31 -9.578 0.65416E+05 -36.311 9 SO2,gas 1.14 -20.81 -21.95 -5.854 0.37480E+05 -19.951 10 HCl,gas 5.48 -12.00 -17.48 -8.738 0.29841E+05 -15.477 11 acmite 7.74 4.05 -3.69 -0.383 0.62994E+04 15 albite-high 0.75 -2.89 -3.64 -0.280 0.62099E+04 16 albite -0.33 -2.89 -2.56 -0.197 0.43693E+04 19 spessartine 24.55 20.67 -3.88 -0.194 0.66221E+04 20 analcite 3.37 0.53 -2.84 -0.316 0.48511E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -9.93 -4.65 -2.326 0.79446E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.08 -3.07 -1.023 0.52393E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.08 -2.92 -0.972 0.49779E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29410E+04 42 celadonite 5.40 1.16 -4.24 -0.249 0.72374E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43642E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13000E+04 52 chloritoid-Mn 11.46 10.60 -0.87 -0.058 0.14781E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64764E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82446E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68760E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.53 -3.72 -0.372 0.63541E+04 97 kalsilite 7.62 2.85 -4.77 -0.681 0.81437E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.57 -4.73 -0.473 0.80826E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75751E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20516E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.98 -1.55 -0.119 0.26484E+04 120 muscovite 2.68 1.58 -1.10 -0.065 0.18808E+04 121 paragonite 4.34 2.67 -1.66 -0.098 0.28401E+04 122 nepheline 8.38 3.95 -4.43 -0.633 0.75670E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50039E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.476 0.40621E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.58 -3.62 -1.207 0.61834E+04 153 rhodonite 7.46 5.04 -2.43 -0.485 0.41414E+04 154 sanidine -1.22 -3.98 -2.76 -0.212 0.47162E+04 156 siderite -2.59 -6.70 -4.11 -1.371 0.70219E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.64 -1.54 -0.046 0.26325E+04 166 stilpnomelane-Mg 27.60 22.78 -4.82 -0.144 0.82282E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83653E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55023E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77452E+04 175 tephroite 18.11 13.49 -4.62 -0.660 0.78920E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.91 -3.48 -0.213 0.59350E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.55 -3.29 -0.202 0.56216E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -5.05 -2.89 -0.177 0.49298E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.69 -2.73 -0.167 0.46546E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.13 -1.28 -0.082 0.21816E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.49 -1.10 -0.070 0.18699E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59601E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.37 -2.45 -0.189 0.41890E+04 244 an25ab75 2.71 0.25 -2.46 -0.189 0.41919E+04 245 an30ab70 3.34 0.88 -2.46 -0.189 0.42031E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1150000 g New total amount of reactant added: 0.1190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1190000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3274474E-03 Osmotic coef. = 0.9892 True ionic strength = .3766044E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.76682E-08 -8.1153 0.73409E-08 -8.1342 0.95732E+00 -0.0189 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13205E-03 -3.8793 0.95716E+00 -0.0190 4 SO4-- 0.25462E-04 -4.5941 0.22556E-04 -4.6467 0.88586E+00 -0.0526 5 HCO3- 0.12707E-04 -4.8960 0.12163E-04 -4.9150 0.95719E+00 -0.0190 6 HS- 0.32847E-12 -12.4835 0.31439E-12 -12.5025 0.95716E+00 -0.0190 7 Al+++ 0.30649E-21 -21.5136 0.23852E-21 -21.6225 0.77823E+00 -0.1089 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.54417E-05 -5.2643 0.48197E-05 -5.3170 0.88568E+00 -0.0527 10 Mg++ 0.22174E-07 -7.6542 0.19637E-07 -7.7069 0.88557E+00 -0.0528 11 Fe++ 0.13118E-09 -9.8821 0.11617E-09 -9.9349 0.88560E+00 -0.0528 12 K+ 0.25256E-04 -4.5976 0.24175E-04 -4.6166 0.95720E+00 -0.0190 13 Na+ 0.30918E-03 -3.5098 0.29594E-03 -3.5288 0.95715E+00 -0.0190 14 Mn++ 0.17322E-07 -7.7614 0.15341E-07 -7.8142 0.88562E+00 -0.0528 15 HPO4-- 0.11813E-07 -7.9276 0.10464E-07 -7.9803 0.88586E+00 -0.0526 16 HSiO3- 0.53177E-04 -4.2743 0.50899E-04 -4.2933 0.95716E+00 -0.0190 17 Ca(HSiO3)+ 0.57420E-08 -8.2409 0.54963E-08 -8.2599 0.95721E+00 -0.0190 18 Mg(HSiO3)+ 0.29115E-10 -10.5359 0.27869E-10 -10.5549 0.95721E+00 -0.0190 19 NaHSiO3,aq 0.23923E-06 -6.6212 0.23923E-06 -6.6212 0.10000E+01 0.0000 20 AlO+ 0.59694E-12 -12.2241 0.57140E-12 -12.2431 0.95721E+00 -0.0190 21 AlOH+2 0.23725E-16 -16.6248 0.21012E-16 -16.6775 0.88564E+00 -0.0527 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.49501E-05 -5.3054 0.47377E-05 -5.3244 0.95711E+00 -0.0190 24 CH4,aq 0.16637E-18 -18.7789 0.16635E-18 -18.7790 0.99990E+00 0.0000 29 CO,aq 0.20496E-17 -17.6883 0.20496E-17 -17.6883 0.10000E+01 0.0000 30 CO2,aq 0.18004E-06 -6.7446 0.18002E-06 -6.7447 0.99990E+00 0.0000 31 CO3-2 0.17294E-06 -6.7621 0.15319E-06 -6.8148 0.88581E+00 -0.0527 32 CaCO3,aq 0.90428E-08 -8.0437 0.90428E-08 -8.0437 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.15431E-08 -8.8116 0.14771E-08 -8.8306 0.95721E+00 -0.0190 34 CaCl+ 0.10595E-08 -8.9749 0.10142E-08 -8.9939 0.95721E+00 -0.0190 35 CaCl2,aq 0.31183E-13 -13.5061 0.31183E-13 -13.5061 0.10000E+01 0.0000 36 CaOH+ 0.48365E-07 -7.3155 0.46295E-07 -7.3345 0.95721E+00 -0.0190 37 CaSO4,aq 0.33872E-07 -7.4702 0.33872E-07 -7.4702 0.10000E+01 0.0000 38 HCl,aq 0.18234E-12 -12.7391 0.18234E-12 -12.7391 0.10000E+01 0.0000 43 FeCl+ 0.24962E-13 -13.6027 0.23894E-13 -13.6217 0.95721E+00 -0.0190 46 FeO,aq 0.85249E-10 -10.0693 0.85249E-10 -10.0693 0.10000E+01 0.0000 47 FeOH+ 0.54811E-09 -9.2611 0.52466E-09 -9.2801 0.95721E+00 -0.0190 48 HFeO2- 0.13050E-09 -9.8844 0.12491E-09 -9.9034 0.95716E+00 -0.0190 49 FeO+ 0.63440E-13 -13.1976 0.60725E-13 -13.2166 0.95721E+00 -0.0190 50 FeOH+2 0.93661E-19 -19.0284 0.82950E-19 -19.0812 0.88564E+00 -0.0527 51 FeO2- 0.23139E-09 -9.6357 0.22147E-09 -9.6547 0.95716E+00 -0.0190 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44210E-09 -9.3545 0.44206E-09 -9.3545 0.99990E+00 0.0000 54 KCl,aq 0.56526E-10 -10.2478 0.56526E-10 -10.2478 0.10000E+01 0.0000 55 KHSO4,aq 0.10712E-16 -16.9701 0.10712E-16 -16.9701 0.10000E+01 0.0000 56 KOH,aq 0.14357E-08 -8.8430 0.14357E-08 -8.8430 0.10000E+01 0.0000 57 KSO4- 0.87770E-08 -8.0567 0.84010E-08 -8.0757 0.95716E+00 -0.0190 58 MgCO3,aq 0.92063E-11 -11.0359 0.92063E-11 -11.0359 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.64111E-11 -11.1931 0.61367E-11 -11.2121 0.95721E+00 -0.0190 60 MgCl+ 0.39188E-11 -11.4068 0.37511E-11 -11.4258 0.95721E+00 -0.0190 61 MgOH+ 0.10917E-08 -8.9619 0.10450E-08 -8.9809 0.95721E+00 -0.0190 63 MnO,aq 0.30051E-09 -9.5221 0.30051E-09 -9.5221 0.10000E+01 0.0000 64 MnOH+ 0.67237E-08 -8.1724 0.64360E-08 -8.1914 0.95721E+00 -0.0190 65 MnO2-2 0.21772E-15 -15.6621 0.19285E-15 -15.7148 0.88581E+00 -0.0527 66 HMnO2- 0.32047E-12 -12.4942 0.30674E-12 -12.5132 0.95716E+00 -0.0190 69 MnCl+ 0.12809E-10 -10.8925 0.12261E-10 -10.9115 0.95721E+00 -0.0190 70 MnSO4,aq 0.98065E-10 -10.0085 0.98065E-10 -10.0085 0.10000E+01 0.0000 71 NaCl,aq 0.12760E-07 -7.8941 0.12760E-07 -7.8941 0.10000E+01 0.0000 72 NaOH,aq 0.17714E-07 -7.7517 0.17714E-07 -7.7517 0.10000E+01 0.0000 74 OH- 0.85373E-04 -4.0687 0.81711E-04 -4.0877 0.95711E+00 -0.0190 79 HPO3-2 0.16495E-19 -19.7827 0.14611E-19 -19.8353 0.88581E+00 -0.0527 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.14070E-08 -8.8517 0.13468E-08 -8.8707 0.95718E+00 -0.0190 84 PO4-3 0.15975E-11 -11.7966 0.12449E-11 -11.9049 0.77930E+00 -0.1083 87 H2P2O7-2 0.16026E-18 -18.7952 0.14196E-18 -18.8478 0.88581E+00 -0.0527 88 HP2O7-3 0.50953E-17 -17.2928 0.39654E-17 -17.4017 0.77824E+00 -0.1089 89 P2O7-4 0.20508E-18 -18.6881 0.13326E-18 -18.8753 0.64979E+00 -0.1872 90 H2S,aq 0.69351E-14 -14.1589 0.69344E-14 -14.1590 0.99990E+00 0.0000 97 SO3-2 0.15342E-14 -14.8141 0.13596E-14 -14.8666 0.88616E+00 -0.0525 98 HSO3- 0.61021E-15 -15.2145 0.58407E-15 -15.2335 0.95716E+00 -0.0190 99 HSO4- 0.16050E-09 -9.7945 0.15364E-09 -9.8135 0.95723E+00 -0.0190 Charge balance for all species = 0.7207E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7668233E-08 -.1587127E-03 -.1599637E+00 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999416E+06 0.0000 3 Cl- 0.1379644E-03 0.1379783E-03 0.4891467E+01 4.2550 4 SO4-- 0.2546233E-04 0.2550518E-04 0.2449929E+01 11.6218 5 HCO3- 0.1270681E-04 0.1307039E-04 0.7974733E+00 3.2193 6 HS- 0.3284656E-12 0.5649665E-10 0.1868351E-05 -4.3683 7 Al+++ 0.3064881E-21 0.4965634E-05 0.1339726E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4363823E-03 0.4194067E+02 -3.4168 9 Ca++ 0.5441722E-05 0.5541347E-05 0.2220735E+00 10.9515 10 Mg++ 0.2217378E-07 0.2331410E-07 0.5667801E-03 8.5616 11 Fe++ 0.1311813E-09 0.1329988E-08 0.7427163E-04 6.3336 12 K+ 0.2525588E-04 0.2526615E-04 0.9879008E+00 3.5176 13 Na+ 0.3091846E-03 0.3094543E-03 0.7113887E+01 4.6054 14 Mn++ 0.1732208E-07 0.2445746E-07 0.1343568E-02 8.4543 15 HPO4-- 0.1181274E-07 0.1322138E-07 0.1268903E-02 8.2882 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1957423E-02 -.1587079E-03 -.1798715E-02 0.0000000E+00 2 H2O 0.5550676E+02 0.5550663E+02 0.1290091E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2880237E-04 0.2550441E-04 0.3297952E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3297896E-05 0.5649495E-10 -.3297952E-05 0.0000000E+00 7 Al+++ 0.3880283E-03 0.4965486E-05 0.3830628E-03 0.0000000E+00 8 H4SiO4 0.1239121E-02 0.4363693E-03 0.8027519E-03 0.0000000E+00 9 Ca++ 0.1513380E-03 0.5541181E-05 0.1457969E-03 0.0000000E+00 10 Mg++ 0.9444444E-04 0.2331340E-07 0.9442113E-04 0.0000000E+00 11 Fe++ 0.8484802E-04 0.1329948E-08 0.8484669E-04 0.0000000E+00 12 K+ 0.2526539E-04 0.2526539E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3094450E-03 0.3094450E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2063293E-05 0.2445673E-07 0.2038836E-05 0.0000000E+00 15 HPO4-- 0.7041916E-06 0.1322099E-07 0.6909706E-06 0.0000000E+00 Chg. balance for solid moles: 0.2808E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2303E-06 -6.638 0.1157E-03 -3.937 0.1143 0.3676E-04 clinochlore 0.1888E-04 -4.724 0.1050E-01 -1.979 10.37 0.3993E-02 daphnite 0.1169E-04 -4.932 0.8343E-02 -2.079 8.239 0.2528E-02 chlorite-Mn 0.4078E-06 -6.390 0.2891E-03 -3.539 0.2855 0.9213E-04 hematite 0.1319E-04 -4.880 0.2107E-02 -2.676 2.080 0.3993E-03 kaolinite 0.1590E-04 -4.799 0.4105E-02 -2.387 4.054 0.1580E-02 lawsonite 0.6690E-04 -4.175 0.2102E-01 -1.677 20.76 0.6780E-02 stilbite 0.7774E-04 -4.109 0.5479E-01 -1.261 54.10 0.2555E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3774E+00 0.3774E+00 1.0000 -0.423 chlorite-Mn 0.1316E-01 0.1316E-01 1.0000 -1.881 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.101265 g Volume = 0.040961 cm3 Porosity: 96.0900% V(tot) - V(min): 0.10066E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1190000 g log = -0.9245 Original solution: 1000.0103000 g Original solution / Rock added: 8403.45 (Water/Rock Ratio), log = 3.9245 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1945E-04 1.0073 0.2061E-04 0.2046E-04 CH4,gas 0.2469E-15 1.0129 0.2631E-15 0.2597E-15 H2,gas 0.5761E-06 1.0006 0.6063E-06 0.6060E-06 H2S,gas 0.1930E-12 0.9959 0.2022E-12 0.2031E-12 S2,gas 0.3962E-32 1.0000 0.4167E-32 0.4167E-32 CO,gas 0.3076E-14 1.0000 0.3236E-14 0.3236E-14 SO3,gas 0.4320E-36 1.0000 0.4544E-36 0.4544E-36 SO2,gas 0.9908E-20 1.0000 0.1042E-19 0.1042E-19 HCl,gas 0.3061E-15 1.0000 0.3220E-15 0.3220E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 164 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.05 -6.69 -2.229 0.11416E+05 -4.686 3 CH4,gas 4.81 -12.77 -17.58 -4.395 0.30017E+05 -15.580 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -20.64 -14.69 -7.347 0.25090E+05 -12.694 6 S2,gas -7.03 -41.41 -34.38 -5.289 0.58703E+05 -32.380 7 CO,gas 3.51 -12.98 -16.49 -5.074 0.28156E+05 -14.490 8 SO3,gas 17.43 -20.92 -38.34 -9.586 0.65469E+05 -36.343 9 SO2,gas 1.14 -20.85 -21.98 -5.862 0.37534E+05 -19.982 10 HCl,gas 5.48 -12.01 -17.49 -8.746 0.29867E+05 -15.492 11 acmite 7.74 4.07 -3.67 -0.381 0.62610E+04 15 albite-high 0.75 -2.86 -3.61 -0.278 0.61716E+04 16 albite -0.33 -2.86 -2.54 -0.195 0.43309E+04 19 spessartine 24.55 20.67 -3.88 -0.194 0.66196E+04 20 analcite 3.37 0.55 -2.82 -0.313 0.48127E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -9.96 -4.68 -2.342 0.79978E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.10 -3.08 -1.028 0.52657E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.10 -2.93 -0.977 0.50044E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29410E+04 42 celadonite 5.40 1.19 -4.21 -0.248 0.71858E+04 43 celadonite-Fe 3.94 -1.04 -4.97 -0.293 0.84910E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13000E+04 52 chloritoid-Mn 11.46 10.60 -0.87 -0.058 0.14772E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64764E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82447E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68761E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.55 -3.70 -0.370 0.63157E+04 97 kalsilite 7.62 2.88 -4.74 -0.677 0.80921E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.54 -4.70 -0.470 0.80310E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75751E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20516E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.95 -1.52 -0.117 0.25968E+04 120 muscovite 2.68 1.61 -1.07 -0.063 0.18292E+04 121 paragonite 4.34 2.70 -1.64 -0.097 0.28018E+04 122 nepheline 8.38 3.97 -4.41 -0.630 0.75287E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50039E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.476 0.40613E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.59 -3.64 -1.212 0.62089E+04 153 rhodonite 7.46 5.04 -2.42 -0.485 0.41405E+04 154 sanidine -1.22 -3.95 -2.73 -0.210 0.46646E+04 156 siderite -2.59 -6.72 -4.13 -1.376 0.70483E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.65 -1.53 -0.046 0.26068E+04 166 stilpnomelane-Mg 27.60 22.79 -4.80 -0.143 0.82025E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83653E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55023E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77452E+04 175 tephroite 18.11 13.49 -4.62 -0.660 0.78903E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.90 -3.47 -0.212 0.59180E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.54 -3.28 -0.201 0.56090E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -5.04 -2.88 -0.176 0.49128E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.68 -2.72 -0.166 0.46419E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.14 -1.27 -0.081 0.21646E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.50 -1.09 -0.070 0.18573E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59601E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.36 -2.44 -0.187 0.41584E+04 244 an25ab75 2.71 0.27 -2.44 -0.188 0.41631E+04 245 an30ab70 3.34 0.90 -2.45 -0.188 0.41762E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1190000 g New total amount of reactant added: 0.1230000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7207E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1230000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3304368E-03 Osmotic coef. = 0.9892 True ionic strength = .3813720E-03 Chg. balance for total moles = 0.7207E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.74072E-08 -8.1303 0.70899E-08 -8.1494 0.95717E+00 -0.0190 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13203E-03 -3.8793 0.95700E+00 -0.0191 4 SO4-- 0.25464E-04 -4.5941 0.22544E-04 -4.6470 0.88530E+00 -0.0529 5 HCO3- 0.12707E-04 -4.8960 0.12161E-04 -4.9150 0.95704E+00 -0.0191 6 HS- 0.31704E-12 -12.4989 0.30341E-12 -12.5180 0.95701E+00 -0.0191 7 Al+++ 0.27650E-21 -21.5583 0.21488E-21 -21.6678 0.77712E+00 -0.1095 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.50791E-05 -5.2942 0.44957E-05 -5.3472 0.88512E+00 -0.0530 10 Mg++ 0.20696E-07 -7.6841 0.18316E-07 -7.7372 0.88501E+00 -0.0531 11 Fe++ 0.12244E-09 -9.9121 0.10836E-09 -9.9651 0.88504E+00 -0.0530 12 K+ 0.26105E-04 -4.5833 0.24984E-04 -4.6023 0.95705E+00 -0.0191 13 Na+ 0.31419E-03 -3.5028 0.30068E-03 -3.5219 0.95700E+00 -0.0191 14 Mn++ 0.16184E-07 -7.7909 0.14324E-07 -7.8439 0.88506E+00 -0.0530 15 HPO4-- 0.12672E-07 -7.8972 0.11219E-07 -7.9501 0.88530E+00 -0.0529 16 HSiO3- 0.55068E-04 -4.2591 0.52701E-04 -4.2782 0.95700E+00 -0.0191 17 Ca(HSiO3)+ 0.55465E-08 -8.2560 0.53083E-08 -8.2750 0.95706E+00 -0.0191 18 Mg(HSiO3)+ 0.28123E-10 -10.5509 0.26916E-10 -10.5700 0.95706E+00 -0.0191 19 NaHSiO3,aq 0.25168E-06 -6.5992 0.25168E-06 -6.5992 0.10000E+01 0.0000 20 AlO+ 0.57662E-12 -12.2391 0.55186E-12 -12.2582 0.95706E+00 -0.0191 21 AlOH+2 0.22144E-16 -16.6547 0.19600E-16 -16.7078 0.88508E+00 -0.0530 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.51261E-05 -5.2902 0.49055E-05 -5.3093 0.95696E+00 -0.0191 24 CH4,aq 0.16063E-18 -18.7942 0.16061E-18 -18.7942 0.99990E+00 0.0000 29 CO,aq 0.19791E-17 -17.7035 0.19791E-17 -17.7035 0.10000E+01 0.0000 30 CO2,aq 0.17386E-06 -6.7598 0.17384E-06 -6.7598 0.99990E+00 0.0000 31 CO3-2 0.17916E-06 -6.7468 0.15860E-06 -6.7997 0.88525E+00 -0.0529 32 CaCO3,aq 0.87325E-08 -8.0589 0.87325E-08 -8.0589 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.14394E-08 -8.8418 0.13776E-08 -8.8609 0.95706E+00 -0.0191 34 CaCl+ 0.98829E-09 -9.0051 0.94585E-09 -9.0242 0.95706E+00 -0.0191 35 CaCl2,aq 0.29077E-13 -13.5364 0.29077E-13 -13.5364 0.10000E+01 0.0000 36 CaOH+ 0.46718E-07 -7.3305 0.44712E-07 -7.3496 0.95706E+00 -0.0191 37 CaSO4,aq 0.31578E-07 -7.5006 0.31578E-07 -7.5006 0.10000E+01 0.0000 38 HCl,aq 0.17608E-12 -12.7543 0.17608E-12 -12.7543 0.10000E+01 0.0000 43 FeCl+ 0.23284E-13 -13.6329 0.22284E-13 -13.6520 0.95706E+00 -0.0191 46 FeO,aq 0.85247E-10 -10.0693 0.85247E-10 -10.0693 0.10000E+01 0.0000 47 FeOH+ 0.52944E-09 -9.2762 0.50670E-09 -9.2952 0.95706E+00 -0.0191 48 HFeO2- 0.13514E-09 -9.8692 0.12933E-09 -9.8883 0.95700E+00 -0.0191 49 FeO+ 0.61280E-13 -13.2127 0.58648E-13 -13.2317 0.95706E+00 -0.0191 50 FeOH+2 0.87420E-19 -19.0584 0.77374E-19 -19.1114 0.88508E+00 -0.0530 51 FeO2- 0.23962E-09 -9.6205 0.22931E-09 -9.6396 0.95700E+00 -0.0191 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44208E-09 -9.3545 0.44203E-09 -9.3545 0.99990E+00 0.0000 54 KCl,aq 0.58407E-10 -10.2335 0.58407E-10 -10.2335 0.10000E+01 0.0000 55 KHSO4,aq 0.10686E-16 -16.9712 0.10686E-16 -16.9712 0.10000E+01 0.0000 56 KOH,aq 0.15362E-08 -8.8135 0.15362E-08 -8.8135 0.10000E+01 0.0000 57 KSO4- 0.90670E-08 -8.0425 0.86772E-08 -8.0616 0.95700E+00 -0.0191 58 MgCO3,aq 0.88903E-11 -11.0511 0.88903E-11 -11.0511 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.59802E-11 -11.2233 0.57234E-11 -11.2423 0.95706E+00 -0.0191 60 MgCl+ 0.36554E-11 -11.4371 0.34984E-11 -11.4561 0.95706E+00 -0.0191 61 MgOH+ 0.10545E-08 -8.9770 0.10092E-08 -8.9960 0.95706E+00 -0.0191 63 MnO,aq 0.30082E-09 -9.5217 0.30082E-09 -9.5217 0.10000E+01 0.0000 64 MnOH+ 0.65013E-08 -8.1870 0.62221E-08 -8.2061 0.95706E+00 -0.0191 65 MnO2-2 0.23379E-15 -15.6312 0.20696E-15 -15.6841 0.88525E+00 -0.0529 66 HMnO2- 0.33220E-12 -12.4786 0.31792E-12 -12.4977 0.95700E+00 -0.0191 69 MnCl+ 0.11960E-10 -10.9223 0.11446E-10 -10.9413 0.95706E+00 -0.0191 70 MnSO4,aq 0.91514E-10 -10.0385 0.91514E-10 -10.0385 0.10000E+01 0.0000 71 NaCl,aq 0.12963E-07 -7.8873 0.12963E-07 -7.8873 0.10000E+01 0.0000 72 NaOH,aq 0.18635E-07 -7.7297 0.18635E-07 -7.7297 0.10000E+01 0.0000 74 OH- 0.88410E-04 -4.0535 0.84604E-04 -4.0726 0.95696E+00 -0.0191 79 HPO3-2 0.17694E-19 -19.7522 0.15663E-19 -19.8051 0.88525E+00 -0.0529 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.14571E-08 -8.8365 0.13945E-08 -8.8556 0.95703E+00 -0.0191 84 PO4-3 0.17758E-11 -11.7506 0.13819E-11 -11.8595 0.77820E+00 -0.1089 87 H2P2O7-2 0.17192E-18 -18.7647 0.15219E-18 -18.8176 0.88525E+00 -0.0529 88 HP2O7-3 0.56640E-17 -17.2469 0.44017E-17 -17.3564 0.77713E+00 -0.1095 89 P2O7-4 0.23630E-18 -18.6265 0.15316E-18 -18.8149 0.64815E+00 -0.1883 90 H2S,aq 0.64639E-14 -14.1895 0.64632E-14 -14.1896 0.99990E+00 0.0000 97 SO3-2 0.15342E-14 -14.8141 0.13587E-14 -14.8669 0.88561E+00 -0.0528 98 HSO3- 0.58908E-15 -15.2298 0.56375E-15 -15.2489 0.95700E+00 -0.0191 99 HSO4- 0.15495E-09 -9.8098 0.14830E-09 -9.8289 0.95708E+00 -0.0191 Charge balance for all species = 0.7187E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7407166E-08 -.1643694E-03 -.1656650E+00 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999413E+06 0.0000 3 Cl- 0.1379644E-03 0.1379784E-03 0.4891469E+01 4.2700 4 SO4-- 0.2546436E-04 0.2550520E-04 0.2449930E+01 11.6517 5 HCO3- 0.1270720E-04 0.1307040E-04 0.7974736E+00 3.2343 6 HS- 0.3170393E-12 0.5545022E-10 0.1833745E-05 -4.3686 7 Al+++ 0.2765025E-21 0.5141726E-05 0.1387235E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4382862E-03 0.4212364E+02 -3.4168 9 Ca++ 0.5079127E-05 0.5174130E-05 0.2073569E+00 10.9515 10 Mg++ 0.2069621E-07 0.2179736E-07 0.5299071E-03 8.5616 11 Fe++ 0.1224372E-09 0.1315433E-08 0.7345880E-04 6.3336 12 K+ 0.2610479E-04 0.2611545E-04 0.1021108E+01 3.5470 13 Na+ 0.3141924E-03 0.3144756E-03 0.7229318E+01 4.6275 14 Mn++ 0.1618421E-07 0.2309018E-07 0.1268455E-02 8.4548 15 HPO4-- 0.1267210E-07 0.1413097E-07 0.1356199E-02 8.3487 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2023657E-02 -.1643643E-03 -.1859293E-02 0.0000000E+00 2 H2O 0.5550671E+02 0.5550659E+02 0.1206405E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2891322E-04 0.2550441E-04 0.3408805E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3408749E-05 0.5544851E-10 -.3408805E-05 0.0000000E+00 7 Al+++ 0.4010712E-03 0.5141568E-05 0.3959297E-03 0.0000000E+00 8 H4SiO4 0.1280772E-02 0.4382728E-03 0.8424995E-03 0.0000000E+00 9 Ca++ 0.1559386E-03 0.5173971E-05 0.1507646E-03 0.0000000E+00 10 Mg++ 0.9761905E-04 0.2179669E-07 0.9759725E-04 0.0000000E+00 11 Fe++ 0.8770006E-04 0.1315393E-08 0.8769874E-04 0.0000000E+00 12 K+ 0.2611465E-04 0.2611465E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3144660E-03 0.3144660E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2132647E-05 0.2308947E-07 0.2109558E-05 0.0000000E+00 15 HPO4-- 0.7278619E-06 0.1413054E-07 0.7137314E-06 0.0000000E+00 Chg. balance for solid moles: 0.1008E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1230000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2379E-06 -6.624 0.1195E-03 -3.923 0.1131 0.3797E-04 clinochlore 0.1952E-04 -4.710 0.1085E-01 -1.965 10.27 0.4127E-02 daphnite 0.1209E-04 -4.918 0.8623E-02 -2.064 8.161 0.2613E-02 chlorite-Mn 0.4219E-06 -6.375 0.2991E-03 -3.524 0.2831 0.9532E-04 hematite 0.1364E-04 -4.865 0.2178E-02 -2.662 2.061 0.4127E-03 kaolinite 0.1636E-04 -4.786 0.4224E-02 -2.374 3.998 0.1625E-02 lawsonite 0.6667E-04 -4.176 0.2095E-01 -1.679 19.83 0.6756E-02 stilbite 0.8291E-04 -4.081 0.5843E-01 -1.233 55.29 0.2725E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3774E+00 0.3774E+00 1.0000 -0.423 chlorite-Mn 0.1317E-01 0.1317E-01 1.0000 -1.880 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.105670 g Volume = 0.042919 cm3 Porosity: 95.9094% V(tot) - V(min): 0.10063E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1230000 g log = -0.9101 Original solution: 1000.0103000 g Original solution / Rock added: 8130.17 (Water/Rock Ratio), log = 3.9101 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1878E-04 1.0073 0.1990E-04 0.1975E-04 CH4,gas 0.2384E-15 1.0129 0.2540E-15 0.2507E-15 H2,gas 0.5760E-06 1.0006 0.6063E-06 0.6059E-06 H2S,gas 0.1799E-12 0.9959 0.1885E-12 0.1893E-12 S2,gas 0.3442E-32 1.0000 0.3621E-32 0.3621E-32 CO,gas 0.2971E-14 1.0000 0.3125E-14 0.3125E-14 SO3,gas 0.4027E-36 1.0000 0.4236E-36 0.4236E-36 SO2,gas 0.9237E-20 1.0000 0.9717E-20 0.9717E-20 HCl,gas 0.2955E-15 1.0000 0.3109E-15 0.3109E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 164 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.06 -6.70 -2.234 0.11442E+05 -4.701 3 CH4,gas 4.81 -12.79 -17.60 -4.399 0.30043E+05 -15.595 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -20.67 -14.72 -7.362 0.25142E+05 -12.725 6 S2,gas -7.03 -41.47 -34.44 -5.299 0.58807E+05 -32.441 7 CO,gas 3.51 -12.99 -16.51 -5.079 0.28182E+05 -14.505 8 SO3,gas 17.43 -20.95 -38.37 -9.593 0.65521E+05 -36.373 9 SO2,gas 1.14 -20.88 -22.01 -5.870 0.37586E+05 -20.012 10 HCl,gas 5.48 -12.03 -17.51 -8.754 0.29893E+05 -15.507 11 acmite 7.74 4.09 -3.64 -0.379 0.62234E+04 15 albite-high 0.75 -2.84 -3.59 -0.276 0.61340E+04 16 albite -0.33 -2.84 -2.51 -0.193 0.42933E+04 19 spessartine 24.55 20.67 -3.88 -0.194 0.66174E+04 20 analcite 3.37 0.57 -2.80 -0.311 0.47751E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -9.99 -4.71 -2.357 0.80498E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.11 -3.10 -1.033 0.52916E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.11 -2.95 -0.982 0.50303E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29410E+04 42 celadonite 5.40 1.22 -4.18 -0.246 0.71356E+04 43 celadonite-Fe 3.94 -1.01 -4.94 -0.291 0.84408E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13000E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.058 0.14765E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64764E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82447E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68762E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.57 -3.68 -0.368 0.62781E+04 97 kalsilite 7.62 2.91 -4.71 -0.673 0.80419E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.51 -4.67 -0.467 0.79808E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75751E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20516E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.92 -1.49 -0.115 0.25466E+04 120 muscovite 2.68 1.64 -1.04 -0.061 0.17790E+04 121 paragonite 4.34 2.72 -1.62 -0.095 0.27642E+04 122 nepheline 8.38 3.99 -4.39 -0.627 0.74911E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50039E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.476 0.40605E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.61 -3.65 -1.217 0.62341E+04 153 rhodonite 7.46 5.04 -2.42 -0.485 0.41398E+04 154 sanidine -1.22 -3.92 -2.70 -0.208 0.46144E+04 156 siderite -2.59 -6.73 -4.14 -1.381 0.70743E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.67 -1.51 -0.045 0.25818E+04 166 stilpnomelane-Mg 27.60 22.81 -4.79 -0.143 0.81774E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83654E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55023E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77452E+04 175 tephroite 18.11 13.49 -4.62 -0.660 0.78888E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.89 -3.46 -0.212 0.59014E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.53 -3.28 -0.201 0.55966E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -5.03 -2.87 -0.176 0.48962E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.67 -2.71 -0.166 0.46295E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.15 -1.26 -0.081 0.21480E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.50 -1.08 -0.069 0.18449E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59601E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.34 -2.42 -0.186 0.41283E+04 244 an25ab75 2.71 0.29 -2.42 -0.186 0.41349E+04 245 an30ab70 3.34 0.91 -2.43 -0.187 0.41499E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1230000 g New total amount of reactant added: 0.1270000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1270000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3335004E-03 Osmotic coef. = 0.9891 True ionic strength = .3862344E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.71605E-08 -8.1451 0.68527E-08 -8.1641 0.95701E+00 -0.0191 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13201E-03 -3.8794 0.95685E+00 -0.0192 4 SO4-- 0.25466E-04 -4.5940 0.22531E-04 -4.6472 0.88473E+00 -0.0532 5 HCO3- 0.12707E-04 -4.8960 0.12159E-04 -4.9151 0.95689E+00 -0.0191 6 HS- 0.30625E-12 -12.5139 0.29304E-12 -12.5331 0.95685E+00 -0.0192 7 Al+++ 0.25003E-21 -21.6020 0.19402E-21 -21.7121 0.77600E+00 -0.1101 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.47480E-05 -5.3235 0.41999E-05 -5.3768 0.88455E+00 -0.0533 10 Mg++ 0.19347E-07 -7.7134 0.17111E-07 -7.7667 0.88444E+00 -0.0533 11 Fe++ 0.11445E-09 -9.9414 0.10123E-09 -9.9947 0.88447E+00 -0.0533 12 K+ 0.26954E-04 -4.5694 0.25792E-04 -4.5885 0.95690E+00 -0.0191 13 Na+ 0.31920E-03 -3.4959 0.30543E-03 -3.5151 0.95685E+00 -0.0192 14 Mn++ 0.15143E-07 -7.8198 0.13394E-07 -7.8731 0.88449E+00 -0.0533 15 HPO4-- 0.13573E-07 -7.8673 0.12009E-07 -7.9205 0.88474E+00 -0.0532 16 HSiO3- 0.56984E-04 -4.2442 0.54525E-04 -4.2634 0.95685E+00 -0.0192 17 Ca(HSiO3)+ 0.53618E-08 -8.2707 0.51308E-08 -8.2898 0.95690E+00 -0.0191 18 Mg(HSiO3)+ 0.27187E-10 -10.5656 0.26015E-10 -10.5848 0.95690E+00 -0.0191 19 NaHSiO3,aq 0.26449E-06 -6.5776 0.26449E-06 -6.5776 0.10000E+01 0.0000 20 AlO+ 0.55742E-12 -12.2538 0.53339E-12 -12.2730 0.95690E+00 -0.0191 21 AlOH+2 0.20701E-16 -16.6840 0.18310E-16 -16.7373 0.88451E+00 -0.0533 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.53044E-05 -5.2754 0.50753E-05 -5.2945 0.95680E+00 -0.0192 24 CH4,aq 0.15520E-18 -18.8091 0.15518E-18 -18.8092 0.99990E+00 0.0000 29 CO,aq 0.19125E-17 -17.7184 0.19125E-17 -17.7184 0.10000E+01 0.0000 30 CO2,aq 0.16802E-06 -6.7747 0.16800E-06 -6.7747 0.99990E+00 0.0000 31 CO3-2 0.18544E-06 -6.7318 0.16406E-06 -6.7850 0.88468E+00 -0.0532 32 CaCO3,aq 0.84389E-08 -8.0737 0.84389E-08 -8.0737 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.13447E-08 -8.8714 0.12868E-08 -8.8905 0.95690E+00 -0.0191 34 CaCl+ 0.92327E-09 -9.0347 0.88348E-09 -9.0538 0.95690E+00 -0.0191 35 CaCl2,aq 0.27156E-13 -13.5661 0.27156E-13 -13.5661 0.10000E+01 0.0000 36 CaOH+ 0.45162E-07 -7.3452 0.43216E-07 -7.3644 0.95690E+00 -0.0191 37 CaSO4,aq 0.29483E-07 -7.5304 0.29483E-07 -7.5304 0.10000E+01 0.0000 38 HCl,aq 0.17016E-12 -12.7691 0.17016E-12 -12.7691 0.10000E+01 0.0000 43 FeCl+ 0.21751E-13 -13.6625 0.20814E-13 -13.6816 0.95690E+00 -0.0191 46 FeO,aq 0.85245E-10 -10.0693 0.85245E-10 -10.0693 0.10000E+01 0.0000 47 FeOH+ 0.51180E-09 -9.2909 0.48974E-09 -9.3100 0.95690E+00 -0.0191 48 HFeO2- 0.13984E-09 -9.8544 0.13380E-09 -9.8735 0.95685E+00 -0.0192 49 FeO+ 0.59239E-13 -13.2274 0.56686E-13 -13.2465 0.95690E+00 -0.0191 50 FeOH+2 0.81721E-19 -19.0877 0.72283E-19 -19.1410 0.88451E+00 -0.0533 51 FeO2- 0.24795E-09 -9.6056 0.23725E-09 -9.6248 0.95685E+00 -0.0192 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44206E-09 -9.3545 0.44201E-09 -9.3546 0.99990E+00 0.0000 54 KCl,aq 0.60287E-10 -10.2198 0.60287E-10 -10.2198 0.10000E+01 0.0000 55 KHSO4,aq 0.10656E-16 -16.9724 0.10656E-16 -16.9724 0.10000E+01 0.0000 56 KOH,aq 0.16408E-08 -8.7849 0.16408E-08 -8.7849 0.10000E+01 0.0000 57 KSO4- 0.93566E-08 -8.0289 0.89528E-08 -8.0480 0.95685E+00 -0.0192 58 MgCO3,aq 0.85914E-11 -11.0659 0.85914E-11 -11.0659 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.55867E-11 -11.2528 0.53460E-11 -11.2720 0.95690E+00 -0.0191 60 MgCl+ 0.34149E-11 -11.4666 0.32677E-11 -11.4858 0.95690E+00 -0.0191 61 MgOH+ 0.10194E-08 -8.9917 0.97545E-09 -9.0108 0.95690E+00 -0.0191 63 MnO,aq 0.30109E-09 -9.5213 0.30109E-09 -9.5213 0.10000E+01 0.0000 64 MnOH+ 0.62905E-08 -8.2013 0.60194E-08 -8.2204 0.95690E+00 -0.0191 65 MnO2-2 0.25064E-15 -15.6009 0.22174E-15 -15.6542 0.88468E+00 -0.0532 66 HMnO2- 0.34406E-12 -12.4634 0.32922E-12 -12.4825 0.95685E+00 -0.0192 69 MnCl+ 0.11183E-10 -10.9514 0.10701E-10 -10.9706 0.95690E+00 -0.0191 70 MnSO4,aq 0.85522E-10 -10.0679 0.85522E-10 -10.0679 0.10000E+01 0.0000 71 NaCl,aq 0.13165E-07 -7.8806 0.13165E-07 -7.8806 0.10000E+01 0.0000 72 NaOH,aq 0.19584E-07 -7.7081 0.19584E-07 -7.7081 0.10000E+01 0.0000 74 OH- 0.91485E-04 -4.0387 0.87533E-04 -4.0578 0.95680E+00 -0.0192 79 HPO3-2 0.18951E-19 -19.7224 0.16766E-19 -19.7756 0.88468E+00 -0.0532 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.15078E-08 -8.8217 0.14427E-08 -8.8408 0.95687E+00 -0.0191 84 PO4-3 0.19694E-11 -11.7057 0.15304E-11 -11.8152 0.77709E+00 -0.1095 87 H2P2O7-2 0.18415E-18 -18.7348 0.16291E-18 -18.7881 0.88468E+00 -0.0532 88 HP2O7-3 0.62818E-17 -17.2019 0.48748E-17 -17.3120 0.77601E+00 -0.1101 89 P2O7-4 0.27145E-18 -18.5663 0.17549E-18 -18.7557 0.64649E+00 -0.1894 90 H2S,aq 0.60340E-14 -14.2194 0.60334E-14 -14.2194 0.99990E+00 0.0000 97 SO3-2 0.15343E-14 -14.8141 0.13579E-14 -14.8671 0.88504E+00 -0.0530 98 HSO3- 0.56911E-15 -15.2448 0.54456E-15 -15.2640 0.95685E+00 -0.0192 99 HSO4- 0.14971E-09 -9.8248 0.14326E-09 -9.8439 0.95693E+00 -0.0191 Charge balance for all species = 0.7191E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7160498E-08 -.1700968E-03 -.1714375E+00 0.0000 2 H2O 0.1000000E+01 0.5550829E+02 0.9999410E+06 0.0000 3 Cl- 0.1379644E-03 0.1379785E-03 0.4891471E+01 4.2847 4 SO4-- 0.2546620E-04 0.2550522E-04 0.2449931E+01 11.6811 5 HCO3- 0.1270715E-04 0.1307041E-04 0.7974740E+00 3.2490 6 HS- 0.3062489E-12 0.5439229E-10 0.1798758E-05 -4.3689 7 Al+++ 0.2500306E-21 0.5320018E-05 0.1435338E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4402142E-03 0.4230892E+02 -3.4168 9 Ca++ 0.4748019E-05 0.4838733E-05 0.1939156E+00 10.9515 10 Mg++ 0.1934697E-07 0.2041113E-07 0.4962068E-03 8.5616 11 Fe++ 0.1144529E-09 0.1302832E-08 0.7275505E-04 6.3336 12 K+ 0.2695370E-04 0.2696476E-04 0.1054315E+01 3.5756 13 Na+ 0.3191998E-03 0.3194970E-03 0.7344749E+01 4.6490 14 Mn++ 0.1514275E-07 0.2183137E-07 0.1199303E-02 8.4552 15 HPO4-- 0.1357322E-07 0.1508297E-07 0.1447565E-02 8.4078 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2089891E-02 -.1700914E-03 -.1919800E-02 0.0000000E+00 2 H2O 0.5550666E+02 0.5550655E+02 0.1122606E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2902407E-04 0.2550442E-04 0.3519657E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3519603E-05 0.5439058E-10 -.3519657E-05 0.0000000E+00 7 Al+++ 0.4141142E-03 0.5319850E-05 0.4087943E-03 0.0000000E+00 8 H4SiO4 0.1322423E-02 0.4402003E-03 0.8822231E-03 0.0000000E+00 9 Ca++ 0.1605392E-03 0.4838581E-05 0.1557006E-03 0.0000000E+00 10 Mg++ 0.1007937E-03 0.2041049E-07 0.1007732E-03 0.0000000E+00 11 Fe++ 0.9055209E-04 0.1302791E-08 0.9055079E-04 0.0000000E+00 12 K+ 0.2696391E-04 0.2696391E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3194869E-03 0.3194869E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2202002E-05 0.2183069E-07 0.2180171E-05 0.0000000E+00 15 HPO4-- 0.7515322E-06 0.1508249E-07 0.7364497E-06 0.0000000E+00 Chg. balance for solid moles: -.2816E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1270000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2455E-06 -6.610 0.1233E-03 -3.909 0.1120 0.3918E-04 clinochlore 0.2015E-04 -4.696 0.1120E-01 -1.951 10.18 0.4261E-02 daphnite 0.1248E-04 -4.904 0.8904E-02 -2.050 8.089 0.2698E-02 chlorite-Mn 0.4360E-06 -6.360 0.3091E-03 -3.510 0.2809 0.9851E-04 hematite 0.1408E-04 -4.851 0.2248E-02 -2.648 2.043 0.4261E-03 kaolinite 0.1685E-04 -4.773 0.4351E-02 -2.361 3.953 0.1674E-02 lawsonite 0.6640E-04 -4.178 0.2087E-01 -1.681 18.96 0.6729E-02 stilbite 0.8807E-04 -4.055 0.6207E-01 -1.207 56.39 0.2895E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1319E-01 0.1319E-01 1.0000 -1.880 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.110070 g Volume = 0.044875 cm3 Porosity: 95.7295% V(tot) - V(min): 0.10059E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1270000 g log = -0.8962 Original solution: 1000.0103000 g Original solution / Rock added: 7874.10 (Water/Rock Ratio), log = 3.8962 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1815E-04 1.0073 0.1923E-04 0.1909E-04 CH4,gas 0.2303E-15 1.0129 0.2454E-15 0.2423E-15 H2,gas 0.5760E-06 1.0006 0.6063E-06 0.6059E-06 H2S,gas 0.1680E-12 0.9959 0.1760E-12 0.1767E-12 S2,gas 0.3000E-32 1.0000 0.3156E-32 0.3156E-32 CO,gas 0.2871E-14 1.0000 0.3020E-14 0.3020E-14 SO3,gas 0.3760E-36 1.0000 0.3955E-36 0.3955E-36 SO2,gas 0.8624E-20 1.0000 0.9072E-20 0.9072E-20 HCl,gas 0.2856E-15 1.0000 0.3004E-15 0.3004E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.48529E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.48529E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.24265E-10 164 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.08 -6.72 -2.239 0.11467E+05 -4.716 3 CH4,gas 4.81 -12.80 -17.61 -4.403 0.30069E+05 -15.610 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -20.70 -14.75 -7.377 0.25193E+05 -12.755 6 S2,gas -7.03 -41.53 -34.50 -5.308 0.58909E+05 -32.501 7 CO,gas 3.51 -13.01 -16.52 -5.083 0.28207E+05 -14.520 8 SO3,gas 17.43 -20.98 -38.40 -9.601 0.65572E+05 -36.403 9 SO2,gas 1.14 -20.91 -22.04 -5.878 0.37637E+05 -20.042 10 HCl,gas 5.48 -12.04 -17.52 -8.761 0.29919E+05 -15.522 11 acmite 7.74 4.11 -3.62 -0.376 0.61866E+04 15 albite-high 0.75 -2.82 -3.57 -0.275 0.60971E+04 16 albite -0.33 -2.82 -2.49 -0.192 0.42565E+04 19 spessartine 24.55 20.68 -3.87 -0.194 0.66154E+04 20 analcite 3.37 0.60 -2.78 -0.308 0.47383E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -10.02 -4.74 -2.372 0.81007E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.13 -3.11 -1.038 0.53170E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.13 -2.96 -0.987 0.50556E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29410E+04 42 celadonite 5.40 1.25 -4.15 -0.244 0.70868E+04 43 celadonite-Fe 3.94 -0.98 -4.91 -0.289 0.83920E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13000E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.058 0.14758E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64765E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82447E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68762E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.60 -3.66 -0.366 0.62413E+04 97 kalsilite 7.62 2.94 -4.68 -0.669 0.79930E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.48 -4.65 -0.465 0.79319E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75751E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20517E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.89 -1.46 -0.113 0.24978E+04 120 muscovite 2.68 1.67 -1.01 -0.060 0.17302E+04 121 paragonite 4.34 2.74 -1.60 -0.094 0.27273E+04 122 nepheline 8.38 4.01 -4.37 -0.624 0.74542E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50039E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.476 0.40599E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.62 -3.67 -1.222 0.62588E+04 153 rhodonite 7.46 5.04 -2.42 -0.485 0.41391E+04 154 sanidine -1.22 -3.89 -2.67 -0.206 0.45655E+04 156 siderite -2.59 -6.75 -4.16 -1.386 0.70996E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.68 -1.50 -0.045 0.25575E+04 166 stilpnomelane-Mg 27.60 22.82 -4.77 -0.143 0.81530E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83654E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55023E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77452E+04 175 tephroite 18.11 13.49 -4.62 -0.660 0.78875E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.88 -3.45 -0.211 0.58853E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.53 -3.27 -0.200 0.55844E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -5.02 -2.86 -0.175 0.48801E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.66 -2.70 -0.166 0.46173E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.16 -1.25 -0.080 0.21319E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.51 -1.07 -0.069 0.18327E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59602E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.32 -2.40 -0.185 0.40988E+04 244 an25ab75 2.71 0.30 -2.41 -0.185 0.41073E+04 245 an30ab70 3.34 0.93 -2.42 -0.186 0.41241E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1270000 g New total amount of reactant added: 0.1310000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1310000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3366309E-03 Osmotic coef. = 0.9891 True ionic strength = .3911824E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.69274E-08 -8.1594 0.66285E-08 -8.1786 0.95686E+00 -0.0192 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13199E-03 -3.8795 0.95669E+00 -0.0192 4 SO4-- 0.25468E-04 -4.5940 0.22518E-04 -4.6475 0.88416E+00 -0.0535 5 HCO3- 0.12707E-04 -4.8960 0.12157E-04 -4.9152 0.95673E+00 -0.0192 6 HS- 0.29606E-12 -12.5286 0.28324E-12 -12.5479 0.95670E+00 -0.0192 7 Al+++ 0.22662E-21 -21.6447 0.17560E-21 -21.7555 0.77487E+00 -0.1108 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.44454E-05 -5.3521 0.39296E-05 -5.4057 0.88398E+00 -0.0536 10 Mg++ 0.18114E-07 -7.7420 0.16010E-07 -7.7956 0.88386E+00 -0.0536 11 Fe++ 0.10716E-09 -9.9700 0.94713E-10 -10.0236 0.88389E+00 -0.0536 12 K+ 0.27803E-04 -4.5559 0.26600E-04 -4.5751 0.95674E+00 -0.0192 13 Na+ 0.32421E-03 -3.4892 0.31017E-03 -3.5084 0.95669E+00 -0.0192 14 Mn++ 0.14189E-07 -7.8481 0.12542E-07 -7.9016 0.88391E+00 -0.0536 15 HPO4-- 0.14516E-07 -7.8381 0.12835E-07 -7.8916 0.88416E+00 -0.0535 16 HSiO3- 0.58920E-04 -4.2297 0.56369E-04 -4.2490 0.95669E+00 -0.0192 17 Ca(HSiO3)+ 0.51873E-08 -8.2851 0.49629E-08 -8.3043 0.95675E+00 -0.0192 18 Mg(HSiO3)+ 0.26302E-10 -10.5800 0.25164E-10 -10.5992 0.95675E+00 -0.0192 19 NaHSiO3,aq 0.27768E-06 -6.5565 0.27768E-06 -6.5565 0.10000E+01 0.0000 20 AlO+ 0.53927E-12 -12.2682 0.51595E-12 -12.2874 0.95675E+00 -0.0192 21 AlOH+2 0.19381E-16 -16.7126 0.17132E-16 -16.7662 0.88394E+00 -0.0536 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.54847E-05 -5.2608 0.52469E-05 -5.2801 0.95664E+00 -0.0192 24 CH4,aq 0.15006E-18 -18.8237 0.15005E-18 -18.8238 0.99990E+00 0.0000 29 CO,aq 0.18495E-17 -17.7329 0.18495E-17 -17.7329 0.10000E+01 0.0000 30 CO2,aq 0.16249E-06 -6.7892 0.16247E-06 -6.7892 0.99990E+00 0.0000 31 CO3-2 0.19180E-06 -6.7171 0.16957E-06 -6.7706 0.88411E+00 -0.0535 32 CaCO3,aq 0.81613E-08 -8.0882 0.81613E-08 -8.0882 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.12581E-08 -8.9003 0.12037E-08 -8.9195 0.95675E+00 -0.0192 34 CaCl+ 0.86386E-09 -9.0636 0.82649E-09 -9.0828 0.95675E+00 -0.0192 35 CaCl2,aq 0.25400E-13 -13.5952 0.25400E-13 -13.5952 0.10000E+01 0.0000 36 CaOH+ 0.43692E-07 -7.3596 0.41802E-07 -7.3788 0.95675E+00 -0.0192 37 CaSO4,aq 0.27570E-07 -7.5596 0.27570E-07 -7.5596 0.10000E+01 0.0000 38 HCl,aq 0.16457E-12 -12.7837 0.16457E-12 -12.7837 0.10000E+01 0.0000 43 FeCl+ 0.20351E-13 -13.6914 0.19471E-13 -13.7106 0.95675E+00 -0.0192 46 FeO,aq 0.85243E-10 -10.0693 0.85243E-10 -10.0693 0.10000E+01 0.0000 47 FeOH+ 0.49512E-09 -9.3053 0.47371E-09 -9.3245 0.95675E+00 -0.0192 48 HFeO2- 0.14458E-09 -9.8399 0.13832E-09 -9.8591 0.95669E+00 -0.0192 49 FeO+ 0.57311E-13 -13.2418 0.54832E-13 -13.2610 0.95675E+00 -0.0192 50 FeOH+2 0.76512E-19 -19.1163 0.67632E-19 -19.1698 0.88394E+00 -0.0536 51 FeO2- 0.25638E-09 -9.5911 0.24528E-09 -9.6103 0.95669E+00 -0.0192 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44204E-09 -9.3545 0.44199E-09 -9.3546 0.99990E+00 0.0000 54 KCl,aq 0.62166E-10 -10.2064 0.62166E-10 -10.2064 0.10000E+01 0.0000 55 KHSO4,aq 0.10624E-16 -16.9737 0.10624E-16 -16.9737 0.10000E+01 0.0000 56 KOH,aq 0.17494E-08 -8.7571 0.17494E-08 -8.7571 0.10000E+01 0.0000 57 KSO4- 0.96456E-08 -8.0157 0.92279E-08 -8.0349 0.95669E+00 -0.0192 58 MgCO3,aq 0.83087E-11 -11.0805 0.83087E-11 -11.0805 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.52270E-11 -11.2817 0.50009E-11 -11.3009 0.95675E+00 -0.0192 60 MgCl+ 0.31951E-11 -11.4955 0.30569E-11 -11.5147 0.95675E+00 -0.0192 61 MgOH+ 0.98619E-09 -9.0060 0.94353E-09 -9.0252 0.95675E+00 -0.0192 63 MnO,aq 0.30133E-09 -9.5210 0.30133E-09 -9.5210 0.10000E+01 0.0000 64 MnOH+ 0.60906E-08 -8.2153 0.58271E-08 -8.2345 0.95675E+00 -0.0192 65 MnO2-2 0.26827E-15 -15.5714 0.23718E-15 -15.6249 0.88411E+00 -0.0535 66 HMnO2- 0.35604E-12 -12.4485 0.34062E-12 -12.4677 0.95669E+00 -0.0192 69 MnCl+ 0.10472E-10 -10.9800 0.10019E-10 -10.9992 0.95675E+00 -0.0192 70 MnSO4,aq 0.80035E-10 -10.0967 0.80035E-10 -10.0967 0.10000E+01 0.0000 71 NaCl,aq 0.13367E-07 -7.8740 0.13367E-07 -7.8740 0.10000E+01 0.0000 72 NaOH,aq 0.20561E-07 -7.6870 0.20561E-07 -7.6870 0.10000E+01 0.0000 74 OH- 0.94594E-04 -4.0241 0.90493E-04 -4.0434 0.95664E+00 -0.0192 79 HPO3-2 0.20267E-19 -19.6932 0.17918E-19 -19.7467 0.88411E+00 -0.0535 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.15590E-08 -8.8072 0.14915E-08 -8.8264 0.95672E+00 -0.0192 84 PO4-3 0.21792E-11 -11.6617 0.16910E-11 -11.7719 0.77596E+00 -0.1102 87 H2P2O7-2 0.19694E-18 -18.7057 0.17411E-18 -18.7592 0.88411E+00 -0.0535 88 HP2O7-3 0.69511E-17 -17.1579 0.53862E-17 -17.2687 0.77488E+00 -0.1108 89 P2O7-4 0.31088E-18 -18.5074 0.20046E-18 -18.6980 0.64482E+00 -0.1906 90 H2S,aq 0.56415E-14 -14.2486 0.56409E-14 -14.2487 0.99990E+00 0.0000 97 SO3-2 0.15343E-14 -14.8141 0.13570E-14 -14.8674 0.88448E+00 -0.0533 98 HSO3- 0.55024E-15 -15.2594 0.52641E-15 -15.2787 0.95669E+00 -0.0192 99 HSO4- 0.14475E-09 -9.8394 0.13849E-09 -9.8586 0.95677E+00 -0.0192 Charge balance for all species = 0.7193E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6927386E-08 -.1758880E-03 -.1772743E+00 0.0000 2 H2O 0.1000000E+01 0.5550830E+02 0.9999407E+06 0.0000 3 Cl- 0.1379643E-03 0.1379786E-03 0.4891473E+01 4.2991 4 SO4-- 0.2546785E-04 0.2550524E-04 0.2449932E+01 11.7097 5 HCO3- 0.1270670E-04 0.1307042E-04 0.7974743E+00 3.2634 6 HS- 0.2960564E-12 0.5332398E-10 0.1763429E-05 -4.3693 7 Al+++ 0.2266193E-21 0.5500298E-05 0.1483977E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4421638E-03 0.4249629E+02 -3.4168 9 Ca++ 0.4445364E-05 0.4532097E-05 0.1816268E+00 10.9515 10 Mg++ 0.1811368E-07 0.1914291E-07 0.4653754E-03 8.5616 11 Fe++ 0.1071551E-09 0.1292033E-08 0.7215201E-04 6.3336 12 K+ 0.2780260E-04 0.2781406E-04 0.1087522E+01 3.6035 13 Na+ 0.3242068E-03 0.3245184E-03 0.7460181E+01 4.6702 14 Mn++ 0.1418884E-07 0.2067160E-07 0.1135591E-02 8.4555 15 HPO4-- 0.1451616E-07 0.1607736E-07 0.1542999E-02 8.4656 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2156126E-02 -.1758823E-03 -.1980243E-02 0.0000000E+00 2 H2O 0.5550661E+02 0.5550650E+02 0.1038705E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2913493E-04 0.2550442E-04 0.3630510E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3630457E-05 0.5332226E-10 -.3630510E-05 0.0000000E+00 7 Al+++ 0.4271572E-03 0.5500120E-05 0.4216570E-03 0.0000000E+00 8 H4SiO4 0.1364075E-02 0.4421495E-03 0.9219250E-03 0.0000000E+00 9 Ca++ 0.1651397E-03 0.4531950E-05 0.1606078E-03 0.0000000E+00 10 Mg++ 0.1039683E-03 0.1914229E-07 0.1039491E-03 0.0000000E+00 11 Fe++ 0.9340413E-04 0.1291992E-08 0.9340283E-04 0.0000000E+00 12 K+ 0.2781316E-04 0.2781316E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3245079E-03 0.3245079E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2271356E-05 0.2067093E-07 0.2250685E-05 0.0000000E+00 15 HPO4-- 0.7752025E-06 0.1607684E-07 0.7591257E-06 0.0000000E+00 Chg. balance for solid moles: -.4172E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1310000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2530E-06 -6.597 0.1271E-03 -3.896 0.1110 0.4039E-04 clinochlore 0.2079E-04 -4.682 0.1156E-01 -1.937 10.10 0.4395E-02 daphnite 0.1287E-04 -4.890 0.9184E-02 -2.037 8.023 0.2783E-02 chlorite-Mn 0.4501E-06 -6.347 0.3191E-03 -3.496 0.2788 0.1017E-03 hematite 0.1452E-04 -4.838 0.2319E-02 -2.635 2.026 0.4396E-03 kaolinite 0.1737E-04 -4.760 0.4485E-02 -2.348 3.918 0.1726E-02 lawsonite 0.6611E-04 -4.180 0.2077E-01 -1.682 18.15 0.6699E-02 stilbite 0.9323E-04 -4.030 0.6570E-01 -1.182 57.40 0.3064E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1320E-01 0.1320E-01 1.0000 -1.880 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.114467 g Volume = 0.046830 cm3 Porosity: 95.5502% V(tot) - V(min): 0.10056E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1310000 g log = -0.8827 Original solution: 1000.0103000 g Original solution / Rock added: 7633.67 (Water/Rock Ratio), log = 3.8827 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1755E-04 1.0073 0.1860E-04 0.1846E-04 CH4,gas 0.2227E-15 1.0129 0.2373E-15 0.2343E-15 H2,gas 0.5760E-06 1.0006 0.6062E-06 0.6059E-06 H2S,gas 0.1570E-12 0.9959 0.1645E-12 0.1652E-12 S2,gas 0.2622E-32 1.0000 0.2759E-32 0.2759E-32 CO,gas 0.2776E-14 1.0000 0.2920E-14 0.2920E-14 SO3,gas 0.3516E-36 1.0000 0.3699E-36 0.3699E-36 SO2,gas 0.8064E-20 1.0000 0.8483E-20 0.8483E-20 HCl,gas 0.2762E-15 1.0000 0.2906E-15 0.2906E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.24265E-10 164 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.09 -6.73 -2.244 0.11492E+05 -4.731 3 CH4,gas 4.81 -12.82 -17.62 -4.406 0.30094E+05 -15.625 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -20.73 -14.78 -7.392 0.25243E+05 -12.784 6 S2,gas -7.03 -41.59 -34.56 -5.317 0.59009E+05 -32.559 7 CO,gas 3.51 -13.02 -16.53 -5.088 0.28232E+05 -14.535 8 SO3,gas 17.43 -21.00 -38.43 -9.608 0.65621E+05 -36.432 9 SO2,gas 1.14 -20.94 -22.07 -5.886 0.37686E+05 -20.071 10 HCl,gas 5.48 -12.06 -17.54 -8.768 0.29944E+05 -15.537 11 acmite 7.74 4.14 -3.60 -0.374 0.61505E+04 15 albite-high 0.75 -2.80 -3.55 -0.273 0.60611E+04 16 albite -0.33 -2.80 -2.47 -0.190 0.42204E+04 19 spessartine 24.55 20.68 -3.87 -0.194 0.66136E+04 20 analcite 3.37 0.62 -2.75 -0.306 0.47022E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -10.05 -4.77 -2.387 0.81504E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.14 -3.13 -1.043 0.53418E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.14 -2.98 -0.992 0.50804E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29410E+04 42 celadonite 5.40 1.28 -4.12 -0.243 0.70392E+04 43 celadonite-Fe 3.94 -0.95 -4.89 -0.287 0.83444E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13001E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.058 0.14752E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64765E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82448E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68763E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.62 -3.63 -0.363 0.62052E+04 97 kalsilite 7.62 2.97 -4.65 -0.665 0.79455E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.45 -4.62 -0.462 0.78844E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75751E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20517E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.87 -1.44 -0.110 0.24502E+04 120 muscovite 2.68 1.69 -0.99 -0.058 0.16826E+04 121 paragonite 4.34 2.76 -1.58 -0.093 0.26913E+04 122 nepheline 8.38 4.03 -4.34 -0.621 0.74181E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50039E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.475 0.40593E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.64 -3.68 -1.227 0.62830E+04 153 rhodonite 7.46 5.04 -2.42 -0.485 0.41385E+04 154 sanidine -1.22 -3.87 -2.65 -0.204 0.45180E+04 156 siderite -2.59 -6.76 -4.17 -1.391 0.71245E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.70 -1.48 -0.044 0.25338E+04 166 stilpnomelane-Mg 27.60 22.84 -4.76 -0.142 0.81292E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83654E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55023E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77452E+04 175 tephroite 18.11 13.49 -4.62 -0.660 0.78863E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.87 -3.44 -0.211 0.58696E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.52 -3.26 -0.200 0.55725E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -5.01 -2.85 -0.174 0.48644E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.66 -2.70 -0.165 0.46054E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.16 -1.24 -0.080 0.21162E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.52 -1.07 -0.068 0.18208E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59602E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.30 -2.38 -0.183 0.40699E+04 244 an25ab75 2.71 0.32 -2.39 -0.184 0.40802E+04 245 an30ab70 3.34 0.94 -2.40 -0.185 0.40989E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1310000 g New total amount of reactant added: 0.1350000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1350000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3398219E-03 Osmotic coef. = 0.9890 True ionic strength = .3962078E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.67070E-08 -8.1735 0.64166E-08 -8.1927 0.95670E+00 -0.0192 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13197E-03 -3.8795 0.95654E+00 -0.0193 4 SO4-- 0.25469E-04 -4.5940 0.22504E-04 -4.6477 0.88358E+00 -0.0538 5 HCO3- 0.12706E-04 -4.8960 0.12154E-04 -4.9153 0.95658E+00 -0.0193 6 HS- 0.28642E-12 -12.5430 0.27398E-12 -12.5623 0.95654E+00 -0.0193 7 Al+++ 0.20588E-21 -21.6864 0.15929E-21 -21.7978 0.77373E+00 -0.1114 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.41684E-05 -5.3800 0.36824E-05 -5.4339 0.88340E+00 -0.0538 10 Mg++ 0.16985E-07 -7.7699 0.15003E-07 -7.8238 0.88328E+00 -0.0539 11 Fe++ 0.10048E-09 -9.9979 0.88753E-10 -10.0518 0.88331E+00 -0.0539 12 K+ 0.28652E-04 -4.5429 0.27408E-04 -4.5621 0.95658E+00 -0.0193 13 Na+ 0.32921E-03 -3.4825 0.31490E-03 -3.5018 0.95653E+00 -0.0193 14 Mn++ 0.13314E-07 -7.8757 0.11761E-07 -7.9296 0.88333E+00 -0.0539 15 HPO4-- 0.15501E-07 -7.8096 0.13696E-07 -7.8634 0.88359E+00 -0.0538 16 HSiO3- 0.60876E-04 -4.2156 0.58230E-04 -4.2349 0.95654E+00 -0.0193 17 Ca(HSiO3)+ 0.50223E-08 -8.2991 0.48043E-08 -8.3184 0.95659E+00 -0.0193 18 Mg(HSiO3)+ 0.25465E-10 -10.5941 0.24359E-10 -10.6133 0.95659E+00 -0.0193 19 NaHSiO3,aq 0.29124E-06 -6.5358 0.29124E-06 -6.5358 0.10000E+01 0.0000 20 AlO+ 0.52212E-12 -12.2822 0.49945E-12 -12.3015 0.95659E+00 -0.0193 21 AlOH+2 0.18174E-16 -16.7406 0.16054E-16 -16.7944 0.88336E+00 -0.0539 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.56668E-05 -5.2467 0.54202E-05 -5.2660 0.95649E+00 -0.0193 24 CH4,aq 0.14521E-18 -18.8380 0.14520E-18 -18.8380 0.99989E+00 0.0000 29 CO,aq 0.17899E-17 -17.7472 0.17899E-17 -17.7472 0.10000E+01 0.0000 30 CO2,aq 0.15726E-06 -6.8034 0.15724E-06 -6.8034 0.99989E+00 0.0000 31 CO3-2 0.19822E-06 -6.7029 0.17513E-06 -6.7566 0.88353E+00 -0.0538 32 CaCO3,aq 0.78985E-08 -8.1025 0.78985E-08 -8.1025 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.11789E-08 -8.9285 0.11277E-08 -8.9478 0.95659E+00 -0.0193 34 CaCl+ 0.80950E-09 -9.0918 0.77436E-09 -9.1111 0.95659E+00 -0.0193 35 CaCl2,aq 0.23794E-13 -13.6235 0.23794E-13 -13.6235 0.10000E+01 0.0000 36 CaOH+ 0.42302E-07 -7.3736 0.40466E-07 -7.3929 0.95659E+00 -0.0193 37 CaSO4,aq 0.25820E-07 -7.5880 0.25820E-07 -7.5880 0.10000E+01 0.0000 38 HCl,aq 0.15928E-12 -12.7978 0.15928E-12 -12.7978 0.10000E+01 0.0000 43 FeCl+ 0.19070E-13 -13.7196 0.18242E-13 -13.7389 0.95659E+00 -0.0193 46 FeO,aq 0.85242E-10 -10.0693 0.85242E-10 -10.0693 0.10000E+01 0.0000 47 FeOH+ 0.47936E-09 -9.3193 0.45855E-09 -9.3386 0.95659E+00 -0.0193 48 HFeO2- 0.14938E-09 -9.8257 0.14289E-09 -9.8450 0.95654E+00 -0.0193 49 FeO+ 0.55488E-13 -13.2558 0.53079E-13 -13.2751 0.95659E+00 -0.0193 50 FeOH+2 0.71745E-19 -19.1442 0.63377E-19 -19.1981 0.88336E+00 -0.0539 51 FeO2- 0.26489E-09 -9.5769 0.25338E-09 -9.5962 0.95654E+00 -0.0193 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44202E-09 -9.3546 0.44198E-09 -9.3546 0.99989E+00 0.0000 54 KCl,aq 0.64043E-10 -10.1935 0.64043E-10 -10.1935 0.10000E+01 0.0000 55 KHSO4,aq 0.10591E-16 -16.9751 0.10591E-16 -16.9751 0.10000E+01 0.0000 56 KOH,aq 0.18621E-08 -8.7300 0.18621E-08 -8.7300 0.10000E+01 0.0000 57 KSO4- 0.99343E-08 -8.0029 0.95025E-08 -8.0222 0.95654E+00 -0.0193 58 MgCO3,aq 0.80412E-11 -11.0947 0.80412E-11 -11.0947 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.48978E-11 -11.3100 0.46852E-11 -11.3293 0.95659E+00 -0.0193 60 MgCl+ 0.29941E-11 -11.5237 0.28641E-11 -11.5430 0.95659E+00 -0.0193 61 MgOH+ 0.95481E-09 -9.0201 0.91337E-09 -9.0394 0.95659E+00 -0.0193 63 MnO,aq 0.30154E-09 -9.5207 0.30154E-09 -9.5207 0.10000E+01 0.0000 64 MnOH+ 0.59010E-08 -8.2291 0.56449E-08 -8.2483 0.95659E+00 -0.0193 65 MnO2-2 0.28667E-15 -15.5426 0.25328E-15 -15.5964 0.88353E+00 -0.0538 66 HMnO2- 0.36812E-12 -12.4340 0.35212E-12 -12.4533 0.95654E+00 -0.0193 69 MnCl+ 0.98198E-11 -11.0079 0.93935E-11 -11.0272 0.95659E+00 -0.0193 70 MnSO4,aq 0.75008E-10 -10.1249 0.75008E-10 -10.1249 0.10000E+01 0.0000 71 NaCl,aq 0.13569E-07 -7.8674 0.13569E-07 -7.8674 0.10000E+01 0.0000 72 NaOH,aq 0.21564E-07 -7.6663 0.21564E-07 -7.6663 0.10000E+01 0.0000 74 OH- 0.97734E-04 -4.0100 0.93482E-04 -4.0293 0.95649E+00 -0.0193 79 HPO3-2 0.21641E-19 -19.6647 0.19120E-19 -19.7185 0.88353E+00 -0.0538 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.16108E-08 -8.7930 0.15408E-08 -8.8123 0.95656E+00 -0.0193 84 PO4-3 0.24058E-11 -11.6187 0.18641E-11 -11.7295 0.77483E+00 -0.1108 87 H2P2O7-2 0.21030E-18 -18.6772 0.18581E-18 -18.7309 0.88353E+00 -0.0538 88 HP2O7-3 0.76741E-17 -17.1150 0.59377E-17 -17.2264 0.77374E+00 -0.1114 89 P2O7-4 0.35496E-18 -18.4498 0.22829E-18 -18.6415 0.64314E+00 -0.1917 90 H2S,aq 0.52826E-14 -14.2772 0.52820E-14 -14.2772 0.99989E+00 0.0000 97 SO3-2 0.15343E-14 -14.8141 0.13562E-14 -14.8677 0.88390E+00 -0.0536 98 HSO3- 0.53240E-15 -15.2738 0.50926E-15 -15.2931 0.95654E+00 -0.0193 99 HSO4- 0.14006E-09 -9.8537 0.13398E-09 -9.8729 0.95661E+00 -0.0193 Charge balance for all species = 0.7197E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6707007E-08 -.1817369E-03 -.1831692E+00 0.0000 2 H2O 0.1000000E+01 0.5550830E+02 0.9999403E+06 0.0000 3 Cl- 0.1379643E-03 0.1379787E-03 0.4891475E+01 4.3132 4 SO4-- 0.2546934E-04 0.2550526E-04 0.2449933E+01 11.7377 5 HCO3- 0.1270586E-04 0.1307043E-04 0.7974747E+00 3.2774 6 HS- 0.2864247E-12 0.5224630E-10 0.1727789E-05 -4.3696 7 Al+++ 0.2058751E-21 0.5682371E-05 0.1533100E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4441331E-03 0.4268554E+02 -3.4168 9 Ca++ 0.4168404E-05 0.4251436E-05 0.1703791E+00 10.9515 10 Mg++ 0.1698511E-07 0.1798132E-07 0.4371365E-03 8.5616 11 Fe++ 0.1004773E-09 0.1282899E-08 0.7164187E-04 6.3336 12 K+ 0.2865151E-04 0.2866337E-04 0.1120730E+01 3.6306 13 Na+ 0.3292134E-03 0.3295398E-03 0.7575612E+01 4.6909 14 Mn++ 0.1331434E-07 0.1960210E-07 0.1076837E-02 8.4558 15 HPO4-- 0.1550094E-07 0.1711411E-07 0.1642499E-02 8.5220 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2222360E-02 -.1817309E-03 -.2040629E-02 0.0000000E+00 2 H2O 0.5550656E+02 0.5550646E+02 0.9547116E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2924578E-04 0.2550442E-04 0.3741362E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3741310E-05 0.5224457E-10 -.3741362E-05 0.0000000E+00 7 Al+++ 0.4402001E-03 0.5682184E-05 0.4345179E-03 0.0000000E+00 8 H4SiO4 0.1405726E-02 0.4441184E-03 0.9616073E-03 0.0000000E+00 9 Ca++ 0.1697403E-03 0.4251295E-05 0.1654890E-03 0.0000000E+00 10 Mg++ 0.1071429E-03 0.1798073E-07 0.1071249E-03 0.0000000E+00 11 Fe++ 0.9625616E-04 0.1282856E-08 0.9625488E-04 0.0000000E+00 12 K+ 0.2866242E-04 0.2866242E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3295289E-03 0.3295289E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2340710E-05 0.1960145E-07 0.2321109E-05 0.0000000E+00 15 HPO4-- 0.7988728E-06 0.1711354E-07 0.7817593E-06 0.0000000E+00 Chg. balance for solid moles: 0.3541E-18 Mass of aqueous solution: 0.100003E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1350000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2606E-06 -6.584 0.1309E-03 -3.883 0.1101 0.4159E-04 clinochlore 0.2142E-04 -4.669 0.1191E-01 -1.924 10.02 0.4530E-02 daphnite 0.1326E-04 -4.877 0.9465E-02 -2.024 7.963 0.2868E-02 chlorite-Mn 0.4642E-06 -6.333 0.3291E-03 -3.483 0.2769 0.1049E-03 hematite 0.1497E-04 -4.825 0.2390E-02 -2.622 2.011 0.4530E-03 kaolinite 0.1792E-04 -4.747 0.4626E-02 -2.335 3.892 0.1780E-02 lawsonite 0.6580E-04 -4.182 0.2068E-01 -1.685 17.40 0.6668E-02 stilbite 0.9839E-04 -4.007 0.6934E-01 -1.159 58.33 0.3234E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1321E-01 0.1321E-01 1.0000 -1.879 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.118861 g Volume = 0.048784 cm3 Porosity: 95.3715% V(tot) - V(min): 0.10052E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1350000 g log = -0.8697 Original solution: 1000.0103000 g Original solution / Rock added: 7407.48 (Water/Rock Ratio), log = 3.8697 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1699E-04 1.0073 0.1800E-04 0.1787E-04 CH4,gas 0.2155E-15 1.0129 0.2296E-15 0.2267E-15 H2,gas 0.5759E-06 1.0006 0.6062E-06 0.6059E-06 H2S,gas 0.1470E-12 0.9959 0.1541E-12 0.1547E-12 S2,gas 0.2299E-32 1.0000 0.2419E-32 0.2419E-32 CO,gas 0.2687E-14 1.0000 0.2826E-14 0.2826E-14 SO3,gas 0.3293E-36 1.0000 0.3464E-36 0.3464E-36 SO2,gas 0.7552E-20 1.0000 0.7944E-20 0.7944E-20 HCl,gas 0.2673E-15 1.0000 0.2812E-15 0.2812E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 164 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.11 -6.74 -2.248 0.11516E+05 -4.745 3 CH4,gas 4.81 -12.83 -17.64 -4.410 0.30118E+05 -15.639 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -20.75 -14.81 -7.406 0.25292E+05 -12.812 6 S2,gas -7.03 -41.65 -34.62 -5.326 0.59107E+05 -32.616 7 CO,gas 3.51 -13.04 -16.55 -5.092 0.28257E+05 -14.549 8 SO3,gas 17.43 -21.03 -38.46 -9.615 0.65670E+05 -36.460 9 SO2,gas 1.14 -20.96 -22.10 -5.893 0.37735E+05 -20.100 10 HCl,gas 5.48 -12.07 -17.55 -8.775 0.29968E+05 -15.551 11 acmite 7.74 4.16 -3.58 -0.372 0.61152E+04 15 albite-high 0.75 -2.78 -3.53 -0.271 0.60257E+04 16 albite -0.33 -2.78 -2.45 -0.189 0.41851E+04 19 spessartine 24.55 20.68 -3.87 -0.194 0.66120E+04 20 analcite 3.37 0.64 -2.73 -0.304 0.46668E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -10.08 -4.80 -2.401 0.81990E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.16 -3.14 -1.048 0.53660E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.16 -2.99 -0.997 0.51047E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29411E+04 42 celadonite 5.40 1.31 -4.10 -0.241 0.69929E+04 43 celadonite-Fe 3.94 -0.92 -4.86 -0.286 0.82982E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13001E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.058 0.14747E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64765E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82448E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68763E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.64 -3.61 -0.361 0.61699E+04 97 kalsilite 7.62 2.99 -4.63 -0.661 0.78992E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.42 -4.59 -0.459 0.78381E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75751E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20517E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.84 -1.41 -0.108 0.24040E+04 120 muscovite 2.68 1.72 -0.96 -0.056 0.16363E+04 121 paragonite 4.34 2.78 -1.56 -0.091 0.26559E+04 122 nepheline 8.38 4.05 -4.32 -0.618 0.73828E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50040E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.475 0.40587E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.65 -3.69 -1.231 0.63067E+04 153 rhodonite 7.46 5.04 -2.42 -0.485 0.41380E+04 154 sanidine -1.22 -3.84 -2.62 -0.201 0.44717E+04 156 siderite -2.59 -6.77 -4.19 -1.396 0.71487E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.71 -1.47 -0.044 0.25107E+04 166 stilpnomelane-Mg 27.60 22.85 -4.75 -0.142 0.81061E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83655E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55023E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77452E+04 175 tephroite 18.11 13.49 -4.62 -0.660 0.78853E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.86 -3.43 -0.210 0.58544E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.51 -3.26 -0.199 0.55608E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -5.00 -2.84 -0.174 0.48491E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.65 -2.69 -0.165 0.45938E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.17 -1.23 -0.079 0.21010E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.52 -1.06 -0.068 0.18091E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59602E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.29 -2.37 -0.182 0.40417E+04 244 an25ab75 2.71 0.34 -2.37 -0.183 0.40537E+04 245 an30ab70 3.34 0.96 -2.39 -0.184 0.40741E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1350000 g New total amount of reactant added: 0.1390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7206E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1390000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3430676E-03 Osmotic coef. = 0.9890 True ionic strength = .4013030E-03 Chg. balance for total moles = 0.7206E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.64986E-08 -8.1872 0.62162E-08 -8.2065 0.95655E+00 -0.0193 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13195E-03 -3.8796 0.95638E+00 -0.0194 4 SO4-- 0.25471E-04 -4.5940 0.22491E-04 -4.6480 0.88300E+00 -0.0540 5 HCO3- 0.12705E-04 -4.8960 0.12151E-04 -4.9154 0.95642E+00 -0.0194 6 HS- 0.27732E-12 -12.5570 0.26522E-12 -12.5764 0.95638E+00 -0.0194 7 Al+++ 0.18746E-21 -21.7271 0.14483E-21 -21.8392 0.77258E+00 -0.1121 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.39146E-05 -5.4073 0.34559E-05 -5.4614 0.88282E+00 -0.0541 10 Mg++ 0.15951E-07 -7.7972 0.14080E-07 -7.8514 0.88270E+00 -0.0542 11 Fe++ 0.94359E-10 -10.0252 0.83293E-10 -10.0794 0.88273E+00 -0.0542 12 K+ 0.29500E-04 -4.5302 0.28215E-04 -4.5495 0.95643E+00 -0.0193 13 Na+ 0.33422E-03 -3.4760 0.31964E-03 -3.4953 0.95637E+00 -0.0194 14 Mn++ 0.12512E-07 -7.9027 0.11045E-07 -7.9568 0.88275E+00 -0.0542 15 HPO4-- 0.16528E-07 -7.7818 0.14594E-07 -7.8358 0.88301E+00 -0.0540 16 HSiO3- 0.62850E-04 -4.2017 0.60108E-04 -4.2211 0.95638E+00 -0.0194 17 Ca(HSiO3)+ 0.48662E-08 -8.3128 0.46542E-08 -8.3322 0.95643E+00 -0.0193 18 Mg(HSiO3)+ 0.24673E-10 -10.6078 0.23598E-10 -10.6271 0.95643E+00 -0.0193 19 NaHSiO3,aq 0.30515E-06 -6.5155 0.30515E-06 -6.5155 0.10000E+01 0.0000 20 AlO+ 0.50589E-12 -12.2959 0.48385E-12 -12.3153 0.95643E+00 -0.0193 21 AlOH+2 0.17067E-16 -16.7678 0.15067E-16 -16.8220 0.88277E+00 -0.0542 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.58505E-05 -5.2328 0.55950E-05 -5.2522 0.95633E+00 -0.0194 24 CH4,aq 0.14062E-18 -18.8520 0.14061E-18 -18.8520 0.99989E+00 0.0000 29 CO,aq 0.17335E-17 -17.7611 0.17335E-17 -17.7611 0.10000E+01 0.0000 30 CO2,aq 0.15231E-06 -6.8173 0.15229E-06 -6.8173 0.99989E+00 0.0000 31 CO3-2 0.20469E-06 -6.6889 0.18073E-06 -6.7430 0.88295E+00 -0.0541 32 CaCO3,aq 0.76498E-08 -8.1163 0.76498E-08 -8.1163 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.11063E-08 -8.9561 0.10581E-08 -8.9755 0.95643E+00 -0.0193 34 CaCl+ 0.75972E-09 -9.1193 0.72662E-09 -9.1387 0.95643E+00 -0.0193 35 CaCl2,aq 0.22323E-13 -13.6512 0.22323E-13 -13.6512 0.10000E+01 0.0000 36 CaOH+ 0.40988E-07 -7.3873 0.39202E-07 -7.4067 0.95643E+00 -0.0193 37 CaSO4,aq 0.24218E-07 -7.6159 0.24218E-07 -7.6159 0.10000E+01 0.0000 38 HCl,aq 0.15428E-12 -12.8117 0.15428E-12 -12.8117 0.10000E+01 0.0000 43 FeCl+ 0.17897E-13 -13.7472 0.17117E-13 -13.7666 0.95643E+00 -0.0193 46 FeO,aq 0.85240E-10 -10.0694 0.85240E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.46446E-09 -9.3331 0.44422E-09 -9.3524 0.95643E+00 -0.0193 48 HFeO2- 0.15422E-09 -9.8119 0.14749E-09 -9.8312 0.95638E+00 -0.0194 49 FeO+ 0.53763E-13 -13.2695 0.51421E-13 -13.2889 0.95643E+00 -0.0193 50 FeOH+2 0.67378E-19 -19.1715 0.59479E-19 -19.2256 0.88277E+00 -0.0542 51 FeO2- 0.27348E-09 -9.5631 0.26155E-09 -9.5825 0.95638E+00 -0.0194 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44201E-09 -9.3546 0.44196E-09 -9.3546 0.99989E+00 0.0000 54 KCl,aq 0.65919E-10 -10.1810 0.65919E-10 -10.1810 0.10000E+01 0.0000 55 KHSO4,aq 0.10556E-16 -16.9765 0.10556E-16 -16.9765 0.10000E+01 0.0000 56 KOH,aq 0.19787E-08 -8.7036 0.19787E-08 -8.7036 0.10000E+01 0.0000 57 KSO4- 0.10222E-07 -7.9904 0.97765E-08 -8.0098 0.95638E+00 -0.0194 58 MgCO3,aq 0.77879E-11 -11.1086 0.77879E-11 -11.1086 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.45962E-11 -11.3376 0.43959E-11 -11.3570 0.95643E+00 -0.0193 60 MgCl+ 0.28099E-11 -11.5513 0.26875E-11 -11.5707 0.95643E+00 -0.0193 61 MgOH+ 0.92514E-09 -9.0338 0.88483E-09 -9.0531 0.95643E+00 -0.0193 63 MnO,aq 0.30173E-09 -9.5204 0.30173E-09 -9.5204 0.10000E+01 0.0000 64 MnOH+ 0.57213E-08 -8.2425 0.54720E-08 -8.2619 0.95643E+00 -0.0193 65 MnO2-2 0.30585E-15 -15.5145 0.27005E-15 -15.5686 0.88295E+00 -0.0541 66 HMnO2- 0.38030E-12 -12.4199 0.36371E-12 -12.4392 0.95638E+00 -0.0194 69 MnCl+ 0.92218E-11 -11.0352 0.88200E-11 -11.0545 0.95643E+00 -0.0193 70 MnSO4,aq 0.70398E-10 -10.1524 0.70398E-10 -10.1524 0.10000E+01 0.0000 71 NaCl,aq 0.13771E-07 -7.8610 0.13771E-07 -7.8610 0.10000E+01 0.0000 72 NaOH,aq 0.22595E-07 -7.6460 0.22595E-07 -7.6460 0.10000E+01 0.0000 74 OH- 0.10090E-03 -3.9961 0.96496E-04 -4.0155 0.95633E+00 -0.0194 79 HPO3-2 0.23073E-19 -19.6369 0.20372E-19 -19.6910 0.88295E+00 -0.0541 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.16630E-08 -8.7791 0.15905E-08 -8.7985 0.95640E+00 -0.0194 84 PO4-3 0.26500E-11 -11.5768 0.20503E-11 -11.6882 0.77370E+00 -0.1114 87 H2P2O7-2 0.22423E-18 -18.6493 0.19798E-18 -18.7034 0.88295E+00 -0.0541 88 HP2O7-3 0.84531E-17 -17.0730 0.65308E-17 -17.1850 0.77259E+00 -0.1121 89 P2O7-4 0.40406E-18 -18.3936 0.25918E-18 -18.5864 0.64145E+00 -0.1928 90 H2S,aq 0.49541E-14 -14.3050 0.49535E-14 -14.3051 0.99989E+00 0.0000 97 SO3-2 0.15343E-14 -14.8141 0.13553E-14 -14.8680 0.88332E+00 -0.0539 98 HSO3- 0.51553E-15 -15.2877 0.49304E-15 -15.3071 0.95638E+00 -0.0194 99 HSO4- 0.13563E-09 -9.8677 0.12972E-09 -9.8870 0.95646E+00 -0.0193 Charge balance for all species = 0.7196E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6498565E-08 -.1876378E-03 -.1891166E+00 0.0000 2 H2O 0.1000000E+01 0.5550830E+02 0.9999400E+06 0.0000 3 Cl- 0.1379642E-03 0.1379789E-03 0.4891477E+01 4.3269 4 SO4-- 0.2547069E-04 0.2550528E-04 0.2449934E+01 11.7650 5 HCO3- 0.1270467E-04 0.1307044E-04 0.7974750E+00 3.2911 6 HS- 0.2773184E-12 0.5116016E-10 0.1691870E-05 -4.3699 7 Al+++ 0.1874571E-21 0.5866064E-05 0.1582659E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4461202E-03 0.4287650E+02 -3.4168 9 Ca++ 0.3914643E-05 0.3994230E-05 0.1600714E+00 10.9515 10 Mg++ 0.1595107E-07 0.1691608E-07 0.4112396E-03 8.5616 11 Fe++ 0.9435901E-10 0.1275297E-08 0.7121734E-04 6.3336 12 K+ 0.2950041E-04 0.2951268E-04 0.1153937E+01 3.6570 13 Na+ 0.3342197E-03 0.3345612E-03 0.7691044E+01 4.7111 14 Mn++ 0.1251179E-07 0.1861481E-07 0.1022601E-02 8.4561 15 HPO4-- 0.1652754E-07 0.1819318E-07 0.1746060E-02 8.5771 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2288594E-02 -.1876315E-03 -.2100962E-02 0.0000000E+00 2 H2O 0.5550651E+02 0.5550642E+02 0.8706355E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2935663E-04 0.2550442E-04 0.3852215E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3852164E-05 0.5115843E-10 -.3852215E-05 0.0000000E+00 7 Al+++ 0.4532431E-03 0.5865866E-05 0.4473772E-03 0.0000000E+00 8 H4SiO4 0.1447377E-02 0.4461051E-03 0.1001272E-02 0.0000000E+00 9 Ca++ 0.1743409E-03 0.3994095E-05 0.1703468E-03 0.0000000E+00 10 Mg++ 0.1103175E-03 0.1691551E-07 0.1103005E-03 0.0000000E+00 11 Fe++ 0.9910819E-04 0.1275254E-08 0.9910692E-04 0.0000000E+00 12 K+ 0.2951168E-04 0.2951168E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3345499E-03 0.3345499E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2410065E-05 0.1861418E-07 0.2391451E-05 0.0000000E+00 15 HPO4-- 0.8225431E-06 0.1819256E-07 0.8043506E-06 0.0000000E+00 Chg. balance for solid moles: -.1567E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2681E-06 -6.572 0.1347E-03 -3.871 0.1093 0.4280E-04 clinochlore 0.2206E-04 -4.656 0.1226E-01 -1.911 9.948 0.4664E-02 daphnite 0.1366E-04 -4.865 0.9745E-02 -2.011 7.907 0.2953E-02 chlorite-Mn 0.4783E-06 -6.320 0.3391E-03 -3.470 0.2751 0.1081E-03 hematite 0.1541E-04 -4.812 0.2461E-02 -2.609 1.997 0.4664E-03 kaolinite 0.1849E-04 -4.733 0.4772E-02 -2.321 3.872 0.1836E-02 lawsonite 0.6547E-04 -4.184 0.2057E-01 -1.687 16.69 0.6634E-02 stilbite 0.1035E-03 -3.985 0.7297E-01 -1.137 59.20 0.3403E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1321E-01 0.1321E-01 1.0000 -1.879 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.123252 g Volume = 0.050737 cm3 Porosity: 95.1935% V(tot) - V(min): 0.10049E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1390000 g log = -0.8570 Original solution: 1000.0103000 g Original solution / Rock added: 7194.32 (Water/Rock Ratio), log = 3.8570 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1645E-04 1.0073 0.1743E-04 0.1731E-04 CH4,gas 0.2087E-15 1.0129 0.2224E-15 0.2195E-15 H2,gas 0.5759E-06 1.0006 0.6062E-06 0.6058E-06 H2S,gas 0.1379E-12 0.9959 0.1445E-12 0.1451E-12 S2,gas 0.2022E-32 1.0000 0.2128E-32 0.2128E-32 CO,gas 0.2602E-14 1.0000 0.2737E-14 0.2737E-14 SO3,gas 0.3089E-36 1.0000 0.3249E-36 0.3249E-36 SO2,gas 0.7083E-20 1.0000 0.7451E-20 0.7451E-20 HCl,gas 0.2590E-15 1.0000 0.2724E-15 0.2724E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.48529E-10 47 daphnite 29.09 29.09 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.24265E-10 164 stilbite -7.41 -7.41 0.00 0.000 0.37914E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.12 -6.76 -2.253 0.11540E+05 -4.759 3 CH4,gas 4.81 -12.84 -17.65 -4.413 0.30142E+05 -15.653 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -20.78 -14.84 -7.420 0.25339E+05 -12.840 6 S2,gas -7.03 -41.70 -34.67 -5.334 0.59202E+05 -32.672 7 CO,gas 3.51 -13.05 -16.56 -5.096 0.28280E+05 -14.563 8 SO3,gas 17.43 -21.06 -38.49 -9.622 0.65718E+05 -36.488 9 SO2,gas 1.14 -20.99 -22.13 -5.901 0.37783E+05 -20.128 10 HCl,gas 5.48 -12.09 -17.56 -8.782 0.29991E+05 -15.565 11 acmite 7.74 4.18 -3.56 -0.370 0.60805E+04 15 albite-high 0.75 -2.76 -3.51 -0.270 0.59911E+04 16 albite -0.33 -2.76 -2.43 -0.187 0.41505E+04 19 spessartine 24.55 20.68 -3.87 -0.194 0.66106E+04 20 analcite 3.37 0.66 -2.71 -0.301 0.46322E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -10.11 -4.83 -2.415 0.82466E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.17 -3.16 -1.052 0.53898E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.17 -3.00 -1.001 0.51284E+04 38 carnegieite-low 9.06 4.07 -4.99 -0.713 0.85203E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29411E+04 42 celadonite 5.40 1.33 -4.07 -0.239 0.69479E+04 43 celadonite-Fe 3.94 -0.90 -4.83 -0.284 0.82531E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13001E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.058 0.14742E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64765E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82448E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68764E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.66 -3.59 -0.359 0.61353E+04 97 kalsilite 7.62 3.02 -4.60 -0.657 0.78542E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.40 -4.56 -0.456 0.77931E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75751E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20517E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.81 -1.38 -0.106 0.23589E+04 120 muscovite 2.68 1.75 -0.93 -0.055 0.15913E+04 121 paragonite 4.34 2.80 -1.54 -0.090 0.26213E+04 122 nepheline 8.38 4.07 -4.30 -0.615 0.73482E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50040E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.475 0.40583E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.67 -3.71 -1.236 0.63300E+04 153 rhodonite 7.46 5.04 -2.42 -0.485 0.41375E+04 154 sanidine -1.22 -3.81 -2.59 -0.199 0.44266E+04 156 siderite -2.59 -6.79 -4.20 -1.400 0.71725E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.72 -1.46 -0.044 0.24883E+04 166 stilpnomelane-Mg 27.60 22.86 -4.73 -0.141 0.80836E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83655E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55023E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77452E+04 175 tephroite 18.11 13.50 -4.62 -0.660 0.78843E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.85 -3.42 -0.209 0.58395E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.51 -3.25 -0.199 0.55494E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -4.99 -2.83 -0.173 0.48343E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.64 -2.68 -0.164 0.45824E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.18 -1.22 -0.078 0.20861E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.53 -1.05 -0.068 0.17977E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59602E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.27 -2.35 -0.181 0.40140E+04 244 an25ab75 2.71 0.35 -2.36 -0.181 0.40278E+04 245 an30ab70 3.34 0.97 -2.37 -0.182 0.40499E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1390000 g New total amount of reactant added: 0.1430000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1430000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3463626E-03 Osmotic coef. = 0.9889 True ionic strength = .4064611E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.63013E-08 -8.2006 0.60265E-08 -8.2199 0.95639E+00 -0.0194 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13192E-03 -3.8797 0.95622E+00 -0.0194 4 SO4-- 0.25472E-04 -4.5939 0.22477E-04 -4.6483 0.88242E+00 -0.0543 5 HCO3- 0.12703E-04 -4.8961 0.12148E-04 -4.9155 0.95626E+00 -0.0194 6 HS- 0.26870E-12 -12.5707 0.25694E-12 -12.5902 0.95622E+00 -0.0194 7 Al+++ 0.17107E-21 -21.7668 0.13197E-21 -21.8795 0.77142E+00 -0.1127 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.36818E-05 -5.4339 0.32482E-05 -5.4884 0.88223E+00 -0.0544 10 Mg++ 0.15002E-07 -7.8238 0.13234E-07 -7.8783 0.88211E+00 -0.0545 11 Fe++ 0.88746E-10 -10.0519 0.78286E-10 -10.1063 0.88214E+00 -0.0545 12 K+ 0.30349E-04 -4.5179 0.29022E-04 -4.5373 0.95627E+00 -0.0194 13 Na+ 0.33923E-03 -3.4695 0.32437E-03 -3.4890 0.95621E+00 -0.0194 14 Mn++ 0.11774E-07 -7.9291 0.10387E-07 -7.9835 0.88216E+00 -0.0545 15 HPO4-- 0.17596E-07 -7.7546 0.15527E-07 -7.8089 0.88242E+00 -0.0543 16 HSiO3- 0.64839E-04 -4.1882 0.62000E-04 -4.2076 0.95622E+00 -0.0194 17 Ca(HSiO3)+ 0.47185E-08 -8.3262 0.45122E-08 -8.3456 0.95627E+00 -0.0194 18 Mg(HSiO3)+ 0.23924E-10 -10.6212 0.22878E-10 -10.6406 0.95627E+00 -0.0194 19 NaHSiO3,aq 0.31941E-06 -6.4956 0.31941E-06 -6.4956 0.10000E+01 0.0000 20 AlO+ 0.49053E-12 -12.3093 0.46908E-12 -12.3287 0.95627E+00 -0.0194 21 AlOH+2 0.16052E-16 -16.7945 0.14161E-16 -16.8489 0.88219E+00 -0.0544 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.60356E-05 -5.2193 0.57711E-05 -5.2387 0.95617E+00 -0.0195 24 CH4,aq 0.13627E-18 -18.8656 0.13626E-18 -18.8656 0.99989E+00 0.0000 29 CO,aq 0.16801E-17 -17.7747 0.16801E-17 -17.7747 0.10000E+01 0.0000 30 CO2,aq 0.14762E-06 -6.8309 0.14760E-06 -6.8309 0.99989E+00 0.0000 31 CO3-2 0.21122E-06 -6.6753 0.18637E-06 -6.7296 0.88236E+00 -0.0544 32 CaCO3,aq 0.74143E-08 -8.1299 0.74143E-08 -8.1299 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10397E-08 -8.9831 0.99422E-09 -9.0025 0.95627E+00 -0.0194 34 CaCl+ 0.71406E-09 -9.1463 0.68284E-09 -9.1657 0.95627E+00 -0.0194 35 CaCl2,aq 0.20975E-13 -13.6783 0.20975E-13 -13.6783 0.10000E+01 0.0000 36 CaOH+ 0.39744E-07 -7.4007 0.38006E-07 -7.4202 0.95627E+00 -0.0194 37 CaSO4,aq 0.22748E-07 -7.6431 0.22748E-07 -7.6431 0.10000E+01 0.0000 38 HCl,aq 0.14954E-12 -12.8252 0.14954E-12 -12.8252 0.10000E+01 0.0000 43 FeCl+ 0.16821E-13 -13.7741 0.16086E-13 -13.7936 0.95627E+00 -0.0194 46 FeO,aq 0.85239E-10 -10.0694 0.85239E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.45035E-09 -9.3464 0.43066E-09 -9.3659 0.95627E+00 -0.0194 48 HFeO2- 0.15910E-09 -9.7983 0.15213E-09 -9.8178 0.95622E+00 -0.0194 49 FeO+ 0.52132E-13 -13.2829 0.49852E-13 -13.3023 0.95627E+00 -0.0194 50 FeOH+2 0.63371E-19 -19.1981 0.55905E-19 -19.2526 0.88219E+00 -0.0544 51 FeO2- 0.28213E-09 -9.5496 0.26978E-09 -9.5690 0.95622E+00 -0.0194 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44200E-09 -9.3546 0.44195E-09 -9.3546 0.99989E+00 0.0000 54 KCl,aq 0.67793E-10 -10.1688 0.67793E-10 -10.1688 0.10000E+01 0.0000 55 KHSO4,aq 0.10520E-16 -16.9780 0.10520E-16 -16.9780 0.10000E+01 0.0000 56 KOH,aq 0.20994E-08 -8.6779 0.20994E-08 -8.6779 0.10000E+01 0.0000 57 KSO4- 0.10510E-07 -7.9784 0.10050E-07 -7.9978 0.95622E+00 -0.0194 58 MgCO3,aq 0.75481E-11 -11.1222 0.75481E-11 -11.1222 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.43194E-11 -11.3646 0.41305E-11 -11.3840 0.95627E+00 -0.0194 60 MgCl+ 0.26410E-11 -11.5782 0.25256E-11 -11.5976 0.95627E+00 -0.0194 61 MgOH+ 0.89706E-09 -9.0472 0.85783E-09 -9.0666 0.95627E+00 -0.0194 63 MnO,aq 0.30191E-09 -9.5201 0.30191E-09 -9.5201 0.10000E+01 0.0000 64 MnOH+ 0.55508E-08 -8.2556 0.53081E-08 -8.2751 0.95627E+00 -0.0194 65 MnO2-2 0.32581E-15 -15.4870 0.28748E-15 -15.5414 0.88236E+00 -0.0544 66 HMnO2- 0.39256E-12 -12.4061 0.37537E-12 -12.4255 0.95622E+00 -0.0194 69 MnCl+ 0.86725E-11 -11.0619 0.82933E-11 -11.0813 0.95627E+00 -0.0194 70 MnSO4,aq 0.66164E-10 -10.1794 0.66164E-10 -10.1794 0.10000E+01 0.0000 71 NaCl,aq 0.13973E-07 -7.8547 0.13973E-07 -7.8547 0.10000E+01 0.0000 72 NaOH,aq 0.23651E-07 -7.6262 0.23651E-07 -7.6262 0.10000E+01 0.0000 74 OH- 0.10410E-03 -3.9826 0.99533E-04 -4.0020 0.95617E+00 -0.0195 79 HPO3-2 0.24564E-19 -19.6097 0.21674E-19 -19.6641 0.88236E+00 -0.0544 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.17156E-08 -8.7656 0.16405E-08 -8.7850 0.95624E+00 -0.0194 84 PO4-3 0.29125E-11 -11.5357 0.22501E-11 -11.6478 0.77256E+00 -0.1121 87 H2P2O7-2 0.23872E-18 -18.6221 0.21064E-18 -18.6765 0.88236E+00 -0.0544 88 HP2O7-3 0.92906E-17 -17.0320 0.71671E-17 -17.1447 0.77143E+00 -0.1127 89 P2O7-4 0.45860E-18 -18.3386 0.29339E-18 -18.5326 0.63975E+00 -0.1940 90 H2S,aq 0.46529E-14 -14.3323 0.46524E-14 -14.3323 0.99989E+00 0.0000 97 SO3-2 0.15344E-14 -14.8141 0.13544E-14 -14.8682 0.88274E+00 -0.0542 98 HSO3- 0.49956E-15 -15.3014 0.47769E-15 -15.3209 0.95622E+00 -0.0194 99 HSO4- 0.13143E-09 -9.8813 0.12568E-09 -9.9007 0.95630E+00 -0.0194 Charge balance for all species = 0.7199E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6301301E-08 -.1935858E-03 -.1951113E+00 0.0000 2 H2O 0.1000000E+01 0.5550830E+02 0.9999397E+06 0.0000 3 Cl- 0.1379642E-03 0.1379790E-03 0.4891479E+01 4.3403 4 SO4-- 0.2547190E-04 0.2550530E-04 0.2449936E+01 11.7916 5 HCO3- 0.1270315E-04 0.1307045E-04 0.7974754E+00 3.3044 6 HS- 0.2687034E-12 0.5006640E-10 0.1655698E-05 -4.3702 7 Al+++ 0.1710703E-21 0.6051218E-05 0.1632613E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4481233E-03 0.4306901E+02 -3.4168 9 Ca++ 0.3681826E-05 0.3758204E-05 0.1506124E+00 10.9515 10 Mg++ 0.1500239E-07 0.1593788E-07 0.3874588E-03 8.5616 11 Fe++ 0.8874594E-10 0.1269108E-08 0.7087170E-04 6.3336 12 K+ 0.3034931E-04 0.3036199E-04 0.1187144E+01 3.6827 13 Na+ 0.3392256E-03 0.3395826E-03 0.7806475E+01 4.7310 14 Mn++ 0.1177442E-07 0.1770236E-07 0.9724749E-03 8.4564 15 HPO4-- 0.1759596E-07 0.1931448E-07 0.1853676E-02 8.6310 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2354828E-02 -.1935791E-03 -.2161249E-02 0.0000000E+00 2 H2O 0.5550646E+02 0.5550638E+02 0.7864848E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2946749E-04 0.2550442E-04 0.3963068E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3963017E-05 0.5006466E-10 -.3963068E-05 0.0000000E+00 7 Al+++ 0.4662861E-03 0.6051008E-05 0.4602350E-03 0.0000000E+00 8 H4SiO4 0.1489028E-02 0.4481078E-03 0.1040920E-02 0.0000000E+00 9 Ca++ 0.1789415E-03 0.3758074E-05 0.1751834E-03 0.0000000E+00 10 Mg++ 0.1134921E-03 0.1593733E-07 0.1134761E-03 0.0000000E+00 11 Fe++ 0.1019602E-03 0.1269064E-08 0.1019590E-03 0.0000000E+00 12 K+ 0.3036093E-04 0.3036093E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3395708E-03 0.3395708E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2479419E-05 0.1770175E-07 0.2461717E-05 0.0000000E+00 15 HPO4-- 0.8462135E-06 0.1931382E-07 0.8268996E-06 0.0000000E+00 Chg. balance for solid moles: 0.1571E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1430000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2756E-06 -6.560 0.1385E-03 -3.859 0.1085 0.4400E-04 clinochlore 0.2270E-04 -4.644 0.1261E-01 -1.899 9.883 0.4798E-02 daphnite 0.1405E-04 -4.852 0.1003E-01 -1.999 7.854 0.3038E-02 chlorite-Mn 0.4923E-06 -6.308 0.3491E-03 -3.457 0.2735 0.1112E-03 hematite 0.1585E-04 -4.800 0.2532E-02 -2.597 1.983 0.4798E-03 kaolinite 0.1907E-04 -4.720 0.4924E-02 -2.308 3.858 0.1895E-02 lawsonite 0.6512E-04 -4.186 0.2046E-01 -1.689 16.03 0.6599E-02 stilbite 0.1087E-03 -3.964 0.7660E-01 -1.116 60.01 0.3573E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1322E-01 0.1322E-01 1.0000 -1.879 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.127641 g Volume = 0.052690 cm3 Porosity: 95.0161% V(tot) - V(min): 0.10045E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1430000 g log = -0.8447 Original solution: 1000.0103000 g Original solution / Rock added: 6993.08 (Water/Rock Ratio), log = 3.8447 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1594E-04 1.0073 0.1690E-04 0.1677E-04 CH4,gas 0.2022E-15 1.0129 0.2155E-15 0.2127E-15 H2,gas 0.5759E-06 1.0006 0.6062E-06 0.6058E-06 H2S,gas 0.1295E-12 0.9959 0.1357E-12 0.1362E-12 S2,gas 0.1784E-32 1.0000 0.1877E-32 0.1877E-32 CO,gas 0.2522E-14 1.0000 0.2653E-14 0.2653E-14 SO3,gas 0.2901E-36 1.0000 0.3052E-36 0.3052E-36 SO2,gas 0.6653E-20 1.0000 0.6998E-20 0.6998E-20 HCl,gas 0.2510E-15 1.0000 0.2641E-15 0.2641E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 164 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.14 -6.77 -2.257 0.11563E+05 -4.772 3 CH4,gas 4.81 -12.86 -17.67 -4.417 0.30165E+05 -15.667 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -20.81 -14.87 -7.434 0.25386E+05 -12.867 6 S2,gas -7.03 -41.76 -34.73 -5.343 0.59295E+05 -32.727 7 CO,gas 3.51 -13.07 -16.58 -5.100 0.28304E+05 -14.576 8 SO3,gas 17.43 -21.09 -38.52 -9.629 0.65764E+05 -36.515 9 SO2,gas 1.14 -21.02 -22.16 -5.908 0.37829E+05 -20.155 10 HCl,gas 5.48 -12.10 -17.58 -8.789 0.30014E+05 -15.578 11 acmite 7.74 4.20 -3.54 -0.368 0.60467E+04 15 albite-high 0.75 -2.74 -3.49 -0.268 0.59572E+04 16 albite -0.33 -2.74 -2.41 -0.185 0.41166E+04 19 spessartine 24.55 20.68 -3.87 -0.194 0.66093E+04 20 analcite 3.37 0.68 -2.69 -0.299 0.45984E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -10.14 -4.86 -2.428 0.82930E+04 26 annite 20.21 15.21 -5.00 -0.278 0.85310E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.18 -3.17 -1.057 0.54130E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.18 -3.02 -1.006 0.51516E+04 38 carnegieite-low 9.06 4.09 -4.97 -0.710 0.84864E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29411E+04 42 celadonite 5.40 1.36 -4.04 -0.238 0.69040E+04 43 celadonite-Fe 3.94 -0.87 -4.81 -0.283 0.82092E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13001E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.058 0.14738E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64765E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82449E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68764E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.68 -3.57 -0.357 0.61014E+04 97 kalsilite 7.62 3.05 -4.57 -0.653 0.78103E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.37 -4.54 -0.454 0.77492E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75751E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20517E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.79 -1.36 -0.104 0.23150E+04 120 muscovite 2.68 1.77 -0.91 -0.053 0.15474E+04 121 paragonite 4.34 2.82 -1.52 -0.089 0.25874E+04 122 nepheline 8.38 4.09 -4.28 -0.612 0.73143E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50040E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.475 0.40578E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.68 -3.72 -1.240 0.63527E+04 153 rhodonite 7.46 5.04 -2.42 -0.485 0.41371E+04 154 sanidine -1.22 -3.79 -2.57 -0.197 0.43828E+04 156 siderite -2.59 -6.80 -4.21 -1.405 0.71957E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.73 -1.44 -0.043 0.24664E+04 166 stilpnomelane-Mg 27.60 22.87 -4.72 -0.141 0.80616E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83655E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 175 tephroite 18.11 13.50 -4.62 -0.660 0.78835E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.85 -3.41 -0.209 0.58250E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.50 -3.24 -0.199 0.55382E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -4.98 -2.82 -0.173 0.48198E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.64 -2.68 -0.164 0.45712E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.19 -1.21 -0.078 0.20716E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.54 -1.05 -0.067 0.17865E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59602E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.26 -2.33 -0.180 0.39869E+04 244 an25ab75 2.71 0.37 -2.34 -0.180 0.40024E+04 245 an30ab70 3.34 0.99 -2.36 -0.181 0.40262E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1430000 g New total amount of reactant added: 0.1470000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1470000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3497023E-03 Osmotic coef. = 0.9889 True ionic strength = .4116761E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.61145E-08 -8.2136 0.58469E-08 -8.2331 0.95623E+00 -0.0194 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13190E-03 -3.8797 0.95606E+00 -0.0195 4 SO4-- 0.25473E-04 -4.5939 0.22463E-04 -4.6485 0.88183E+00 -0.0546 5 HCO3- 0.12701E-04 -4.8962 0.12144E-04 -4.9156 0.95610E+00 -0.0195 6 HS- 0.26055E-12 -12.5841 0.24910E-12 -12.6036 0.95606E+00 -0.0195 7 Al+++ 0.15646E-21 -21.8056 0.12052E-21 -21.9190 0.77027E+00 -0.1134 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.34679E-05 -5.4599 0.30575E-05 -5.5146 0.88164E+00 -0.0547 10 Mg++ 0.14131E-07 -7.8498 0.12457E-07 -7.9046 0.88152E+00 -0.0548 11 Fe++ 0.83589E-10 -10.0779 0.73688E-10 -10.1326 0.88155E+00 -0.0548 12 K+ 0.31198E-04 -4.5059 0.29829E-04 -4.5254 0.95611E+00 -0.0195 13 Na+ 0.34423E-03 -3.4631 0.32910E-03 -3.4827 0.95605E+00 -0.0195 14 Mn++ 0.11096E-07 -7.9548 0.97820E-08 -8.0096 0.88157E+00 -0.0547 15 HPO4-- 0.18706E-07 -7.7280 0.16496E-07 -7.7826 0.88184E+00 -0.0546 16 HSiO3- 0.66842E-04 -4.1750 0.63905E-04 -4.1945 0.95606E+00 -0.0195 17 Ca(HSiO3)+ 0.45786E-08 -8.3393 0.43777E-08 -8.3588 0.95611E+00 -0.0195 18 Mg(HSiO3)+ 0.23215E-10 -10.6342 0.22196E-10 -10.6537 0.95611E+00 -0.0195 19 NaHSiO3,aq 0.33403E-06 -6.4762 0.33403E-06 -6.4762 0.10000E+01 0.0000 20 AlO+ 0.47599E-12 -12.3224 0.45510E-12 -12.3419 0.95611E+00 -0.0195 21 AlOH+2 0.15120E-16 -16.8205 0.13330E-16 -16.8752 0.88160E+00 -0.0547 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.62221E-05 -5.2061 0.59484E-05 -5.2256 0.95601E+00 -0.0195 24 CH4,aq 0.13216E-18 -18.8789 0.13214E-18 -18.8790 0.99989E+00 0.0000 29 CO,aq 0.16294E-17 -17.7880 0.16294E-17 -17.7880 0.10000E+01 0.0000 30 CO2,aq 0.14317E-06 -6.8441 0.14316E-06 -6.8442 0.99989E+00 0.0000 31 CO3-2 0.21778E-06 -6.6620 0.19204E-06 -6.7166 0.88177E+00 -0.0546 32 CaCO3,aq 0.71911E-08 -8.1432 0.71911E-08 -8.1432 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.97848E-09 -9.0094 0.93554E-09 -9.0289 0.95611E+00 -0.0195 34 CaCl+ 0.67213E-09 -9.1725 0.64263E-09 -9.1920 0.95611E+00 -0.0195 35 CaCl2,aq 0.19736E-13 -13.7047 0.19736E-13 -13.7047 0.10000E+01 0.0000 36 CaOH+ 0.38565E-07 -7.4138 0.36873E-07 -7.4333 0.95611E+00 -0.0195 37 CaSO4,aq 0.21399E-07 -7.6696 0.21399E-07 -7.6696 0.10000E+01 0.0000 38 HCl,aq 0.14506E-12 -12.8384 0.14506E-12 -12.8384 0.10000E+01 0.0000 43 FeCl+ 0.15833E-13 -13.8004 0.15138E-13 -13.8199 0.95611E+00 -0.0195 46 FeO,aq 0.85238E-10 -10.0694 0.85238E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.43700E-09 -9.3595 0.41782E-09 -9.3790 0.95611E+00 -0.0195 48 HFeO2- 0.16401E-09 -9.7851 0.15681E-09 -9.8046 0.95606E+00 -0.0195 49 FeO+ 0.50586E-13 -13.2960 0.48366E-13 -13.3155 0.95611E+00 -0.0195 50 FeOH+2 0.59689E-19 -19.2241 0.52622E-19 -19.2788 0.88160E+00 -0.0547 51 FeO2- 0.29085E-09 -9.5363 0.27807E-09 -9.5559 0.95606E+00 -0.0195 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44199E-09 -9.3546 0.44194E-09 -9.3546 0.99989E+00 0.0000 54 KCl,aq 0.69666E-10 -10.1570 0.69666E-10 -10.1570 0.10000E+01 0.0000 55 KHSO4,aq 0.10483E-16 -16.9795 0.10483E-16 -16.9795 0.10000E+01 0.0000 56 KOH,aq 0.22241E-08 -8.6529 0.22241E-08 -8.6529 0.10000E+01 0.0000 57 KSO4- 0.10797E-07 -7.9667 0.10323E-07 -7.9862 0.95606E+00 -0.0195 58 MgCO3,aq 0.73208E-11 -11.1354 0.73208E-11 -11.1354 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.40652E-11 -11.3909 0.38867E-11 -11.4104 0.95611E+00 -0.0195 60 MgCl+ 0.24859E-11 -11.6045 0.23768E-11 -11.6240 0.95611E+00 -0.0195 61 MgOH+ 0.87046E-09 -9.0603 0.83226E-09 -9.0797 0.95611E+00 -0.0195 63 MnO,aq 0.30206E-09 -9.5199 0.30206E-09 -9.5199 0.10000E+01 0.0000 64 MnOH+ 0.53890E-08 -8.2685 0.51525E-08 -8.2880 0.95611E+00 -0.0195 65 MnO2-2 0.34655E-15 -15.4602 0.30558E-15 -15.5149 0.88177E+00 -0.0546 66 HMnO2- 0.40489E-12 -12.3927 0.38710E-12 -12.4122 0.95606E+00 -0.0195 69 MnCl+ 0.81674E-11 -11.0879 0.78090E-11 -11.1074 0.95611E+00 -0.0195 70 MnSO4,aq 0.62272E-10 -10.2057 0.62272E-10 -10.2057 0.10000E+01 0.0000 71 NaCl,aq 0.14174E-07 -7.8485 0.14174E-07 -7.8485 0.10000E+01 0.0000 72 NaOH,aq 0.24733E-07 -7.6067 0.24733E-07 -7.6067 0.10000E+01 0.0000 74 OH- 0.10731E-03 -3.9694 0.10259E-03 -3.9889 0.95601E+00 -0.0195 79 HPO3-2 0.26113E-19 -19.5831 0.23026E-19 -19.6378 0.88177E+00 -0.0546 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.17686E-08 -8.7524 0.16909E-08 -8.7719 0.95608E+00 -0.0195 84 PO4-3 0.31940E-11 -11.4957 0.24639E-11 -11.6084 0.77141E+00 -0.1127 87 H2P2O7-2 0.25378E-18 -18.5955 0.22378E-18 -18.6502 0.88177E+00 -0.0546 88 HP2O7-3 0.10189E-16 -16.9919 0.78481E-17 -17.1052 0.77028E+00 -0.1134 89 P2O7-4 0.51898E-18 -18.2848 0.33114E-18 -18.4800 0.63805E+00 -0.1951 90 H2S,aq 0.43765E-14 -14.3589 0.43760E-14 -14.3589 0.99989E+00 0.0000 97 SO3-2 0.15344E-14 -14.8141 0.13536E-14 -14.8685 0.88216E+00 -0.0545 98 HSO3- 0.48443E-15 -15.3148 0.46315E-15 -15.3343 0.95606E+00 -0.0195 99 HSO4- 0.12745E-09 -9.8946 0.12186E-09 -9.9141 0.95614E+00 -0.0195 Charge balance for all species = 0.7200E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6114492E-08 -.1995761E-03 -.2011488E+00 0.0000 2 H2O 0.1000000E+01 0.5550830E+02 0.9999393E+06 0.0000 3 Cl- 0.1379641E-03 0.1379791E-03 0.4891481E+01 4.3533 4 SO4-- 0.2547299E-04 0.2550532E-04 0.2449937E+01 11.8176 5 HCO3- 0.1270133E-04 0.1307046E-04 0.7974757E+00 3.3174 6 HS- 0.2605478E-12 0.4896575E-10 0.1619299E-05 -4.3706 7 Al+++ 0.1564593E-21 0.6237690E-05 0.1682922E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4501409E-03 0.4326291E+02 -3.4168 9 Ca++ 0.3467927E-05 0.3541311E-05 0.1419202E+00 10.9515 10 Mg++ 0.1413080E-07 0.1503834E-07 0.3655905E-03 8.5616 11 Fe++ 0.8358914E-10 0.1264221E-08 0.7059873E-04 6.3335 12 K+ 0.3119821E-04 0.3121130E-04 0.1220352E+01 3.7077 13 Na+ 0.3442311E-03 0.3446040E-03 0.7921907E+01 4.7504 14 Mn++ 0.1109609E-07 0.1685803E-07 0.9260915E-03 8.4566 15 HPO4-- 0.1870616E-07 0.2047797E-07 0.1965338E-02 8.6835 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2421062E-02 -.1995691E-03 -.2221493E-02 0.0000000E+00 2 H2O 0.5550641E+02 0.5550634E+02 0.7022669E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2957834E-04 0.2550442E-04 0.4073920E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4073871E-05 0.4896402E-10 -.4073920E-05 0.0000000E+00 7 Al+++ 0.4793290E-03 0.6237469E-05 0.4730915E-03 0.0000000E+00 8 H4SiO4 0.1530679E-02 0.4501250E-03 0.1080554E-02 0.0000000E+00 9 Ca++ 0.1835420E-03 0.3541186E-05 0.1800008E-03 0.0000000E+00 10 Mg++ 0.1166667E-03 0.1503781E-07 0.1166516E-03 0.0000000E+00 11 Fe++ 0.1048123E-03 0.1264176E-08 0.1048110E-03 0.0000000E+00 12 K+ 0.3121019E-04 0.3121019E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3445918E-03 0.3445918E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2548774E-05 0.1685743E-07 0.2531916E-05 0.0000000E+00 15 HPO4-- 0.8698838E-06 0.2047724E-07 0.8494065E-06 0.0000000E+00 Chg. balance for solid moles: 0.1050E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1470000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2831E-06 -6.548 0.1422E-03 -3.847 0.1077 0.4519E-04 clinochlore 0.2333E-04 -4.632 0.1297E-01 -1.887 9.822 0.4933E-02 daphnite 0.1444E-04 -4.840 0.1031E-01 -1.987 7.806 0.3123E-02 chlorite-Mn 0.5064E-06 -6.296 0.3590E-03 -3.445 0.2719 0.1144E-03 hematite 0.1630E-04 -4.788 0.2602E-02 -2.585 1.971 0.4933E-03 kaolinite 0.1968E-04 -4.706 0.5081E-02 -2.294 3.848 0.1955E-02 lawsonite 0.6475E-04 -4.189 0.2035E-01 -1.692 15.41 0.6561E-02 stilbite 0.1138E-03 -3.944 0.8022E-01 -1.096 60.76 0.3742E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1323E-01 0.1323E-01 1.0000 -1.878 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.132027 g Volume = 0.054642 cm3 Porosity: 94.8393% V(tot) - V(min): 0.10042E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1470000 g log = -0.8327 Original solution: 1000.0103000 g Original solution / Rock added: 6802.79 (Water/Rock Ratio), log = 3.8327 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1546E-04 1.0073 0.1639E-04 0.1627E-04 CH4,gas 0.1961E-15 1.0129 0.2090E-15 0.2063E-15 H2,gas 0.5759E-06 1.0006 0.6062E-06 0.6058E-06 H2S,gas 0.1218E-12 0.9959 0.1276E-12 0.1282E-12 S2,gas 0.1579E-32 1.0000 0.1661E-32 0.1661E-32 CO,gas 0.2446E-14 1.0000 0.2573E-14 0.2573E-14 SO3,gas 0.2729E-36 1.0000 0.2871E-36 0.2871E-36 SO2,gas 0.6258E-20 1.0000 0.6583E-20 0.6583E-20 HCl,gas 0.2435E-15 1.0000 0.2561E-15 0.2561E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 164 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.15 -6.79 -2.262 0.11586E+05 -4.786 3 CH4,gas 4.81 -12.87 -17.68 -4.420 0.30188E+05 -15.680 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -20.84 -14.89 -7.447 0.25431E+05 -12.894 6 S2,gas -7.03 -41.81 -34.78 -5.351 0.59385E+05 -32.780 7 CO,gas 3.51 -13.08 -16.59 -5.104 0.28326E+05 -14.590 8 SO3,gas 17.43 -21.11 -38.54 -9.635 0.65809E+05 -36.542 9 SO2,gas 1.14 -21.05 -22.18 -5.915 0.37874E+05 -20.182 10 HCl,gas 5.48 -12.11 -17.59 -8.796 0.30037E+05 -15.592 11 acmite 7.74 4.22 -3.52 -0.366 0.60135E+04 15 albite-high 0.75 -2.72 -3.47 -0.267 0.59241E+04 16 albite -0.33 -2.72 -2.39 -0.184 0.40834E+04 19 spessartine 24.55 20.68 -3.87 -0.194 0.66082E+04 20 analcite 3.37 0.70 -2.67 -0.297 0.45652E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -10.16 -4.88 -2.442 0.83383E+04 26 annite 20.21 15.24 -4.97 -0.276 0.84882E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.20 -3.18 -1.061 0.54356E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.20 -3.03 -1.010 0.51743E+04 38 carnegieite-low 9.06 4.11 -4.95 -0.707 0.84532E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29411E+04 42 celadonite 5.40 1.38 -4.02 -0.236 0.68612E+04 43 celadonite-Fe 3.94 -0.85 -4.78 -0.281 0.81665E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13001E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.058 0.14734E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64765E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82449E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68764E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.70 -3.55 -0.355 0.60682E+04 97 kalsilite 7.62 3.07 -4.55 -0.650 0.77675E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.35 -4.51 -0.451 0.77064E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75751E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20517E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.76 -1.33 -0.102 0.22722E+04 120 muscovite 2.68 1.80 -0.88 -0.052 0.15046E+04 121 paragonite 4.34 2.84 -1.50 -0.088 0.25543E+04 122 nepheline 8.38 4.11 -4.26 -0.609 0.72811E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50040E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.475 0.40575E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.69 -3.73 -1.245 0.63750E+04 153 rhodonite 7.46 5.04 -2.42 -0.485 0.41367E+04 154 sanidine -1.22 -3.76 -2.54 -0.196 0.43400E+04 156 siderite -2.59 -6.82 -4.23 -1.409 0.72184E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.75 -1.43 -0.043 0.24450E+04 166 stilpnomelane-Mg 27.60 22.89 -4.71 -0.141 0.80403E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83655E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 175 tephroite 18.11 13.50 -4.62 -0.660 0.78827E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.84 -3.40 -0.208 0.58109E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.49 -3.24 -0.198 0.55273E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -4.98 -2.81 -0.172 0.48057E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.63 -2.67 -0.164 0.45602E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.20 -1.20 -0.077 0.20575E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.54 -1.04 -0.067 0.17756E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59602E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.24 -2.32 -0.178 0.39603E+04 244 an25ab75 2.71 0.38 -2.33 -0.179 0.39775E+04 245 an30ab70 3.34 1.00 -2.34 -0.180 0.40030E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1470000 g New total amount of reactant added: 0.1510000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1510000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3530822E-03 Osmotic coef. = 0.9888 True ionic strength = .4169425E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.59375E-08 -8.2264 0.56766E-08 -8.2459 0.95607E+00 -0.0195 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13188E-03 -3.8798 0.95590E+00 -0.0196 4 SO4-- 0.25474E-04 -4.5939 0.22449E-04 -4.6488 0.88124E+00 -0.0549 5 HCO3- 0.12699E-04 -4.8962 0.12140E-04 -4.9158 0.95594E+00 -0.0196 6 HS- 0.25282E-12 -12.5972 0.24167E-12 -12.6168 0.95590E+00 -0.0196 7 Al+++ 0.14340E-21 -21.8434 0.11029E-21 -21.9575 0.76911E+00 -0.1140 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.32711E-05 -5.4853 0.28820E-05 -5.5403 0.88105E+00 -0.0550 10 Mg++ 0.13329E-07 -7.8752 0.11742E-07 -7.9303 0.88093E+00 -0.0551 11 Fe++ 0.78845E-10 -10.1032 0.69459E-10 -10.1583 0.88096E+00 -0.0550 12 K+ 0.32047E-04 -4.4942 0.30635E-04 -4.5138 0.95595E+00 -0.0196 13 Na+ 0.34924E-03 -3.4569 0.33383E-03 -3.4765 0.95589E+00 -0.0196 14 Mn++ 0.10471E-07 -7.9800 0.92250E-08 -8.0350 0.88098E+00 -0.0550 15 HPO4-- 0.19858E-07 -7.7021 0.17500E-07 -7.7570 0.88125E+00 -0.0549 16 HSiO3- 0.68858E-04 -4.1620 0.65821E-04 -4.1816 0.95590E+00 -0.0196 17 Ca(HSiO3)+ 0.44461E-08 -8.3520 0.42502E-08 -8.3716 0.95595E+00 -0.0196 18 Mg(HSiO3)+ 0.22543E-10 -10.6470 0.21550E-10 -10.6666 0.95595E+00 -0.0196 19 NaHSiO3,aq 0.34899E-06 -6.4572 0.34899E-06 -6.4572 0.10000E+01 0.0000 20 AlO+ 0.46221E-12 -12.3352 0.44185E-12 -12.3547 0.95595E+00 -0.0196 21 AlOH+2 0.14262E-16 -16.8458 0.12565E-16 -16.9008 0.88101E+00 -0.0550 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.64098E-05 -5.1932 0.61268E-05 -5.2128 0.95584E+00 -0.0196 24 CH4,aq 0.12825E-18 -18.8919 0.12824E-18 -18.8920 0.99989E+00 0.0000 29 CO,aq 0.15814E-17 -17.8010 0.15814E-17 -17.8010 0.10000E+01 0.0000 30 CO2,aq 0.13896E-06 -6.8571 0.13894E-06 -6.8572 0.99989E+00 0.0000 31 CO3-2 0.22439E-06 -6.6490 0.19773E-06 -6.7039 0.88119E+00 -0.0549 32 CaCO3,aq 0.69794E-08 -8.1562 0.69794E-08 -8.1562 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.92219E-09 -9.0352 0.88157E-09 -9.0547 0.95595E+00 -0.0196 34 CaCl+ 0.63356E-09 -9.1982 0.60565E-09 -9.2178 0.95595E+00 -0.0196 35 CaCl2,aq 0.18597E-13 -13.7305 0.18597E-13 -13.7305 0.10000E+01 0.0000 36 CaOH+ 0.37449E-07 -7.4266 0.35799E-07 -7.4461 0.95595E+00 -0.0196 37 CaSO4,aq 0.20158E-07 -7.6955 0.20158E-07 -7.6955 0.10000E+01 0.0000 38 HCl,aq 0.14082E-12 -12.8513 0.14082E-12 -12.8513 0.10000E+01 0.0000 43 FeCl+ 0.14924E-13 -13.8261 0.14267E-13 -13.8457 0.95595E+00 -0.0196 46 FeO,aq 0.85237E-10 -10.0694 0.85237E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.42434E-09 -9.3723 0.40565E-09 -9.3918 0.95595E+00 -0.0196 48 HFeO2- 0.16896E-09 -9.7722 0.16151E-09 -9.7918 0.95590E+00 -0.0196 49 FeO+ 0.49122E-13 -13.3087 0.46958E-13 -13.3283 0.95595E+00 -0.0196 50 FeOH+2 0.56302E-19 -19.2495 0.49602E-19 -19.3045 0.88101E+00 -0.0550 51 FeO2- 0.29962E-09 -9.5234 0.28640E-09 -9.5430 0.95590E+00 -0.0196 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44197E-09 -9.3546 0.44193E-09 -9.3547 0.99989E+00 0.0000 54 KCl,aq 0.71537E-10 -10.1455 0.71537E-10 -10.1455 0.10000E+01 0.0000 55 KHSO4,aq 0.10447E-16 -16.9810 0.10447E-16 -16.9810 0.10000E+01 0.0000 56 KOH,aq 0.23527E-08 -8.6284 0.23527E-08 -8.6284 0.10000E+01 0.0000 57 KSO4- 0.11084E-07 -7.9553 0.10595E-07 -7.9749 0.95590E+00 -0.0196 58 MgCO3,aq 0.71053E-11 -11.1484 0.71053E-11 -11.1484 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.38312E-11 -11.4167 0.36625E-11 -11.4362 0.95595E+00 -0.0196 60 MgCl+ 0.23433E-11 -11.6302 0.22401E-11 -11.6497 0.95595E+00 -0.0196 61 MgOH+ 0.84526E-09 -9.0730 0.80803E-09 -9.0926 0.95595E+00 -0.0196 63 MnO,aq 0.30220E-09 -9.5197 0.30220E-09 -9.5197 0.10000E+01 0.0000 64 MnOH+ 0.52354E-08 -8.2810 0.50048E-08 -8.3006 0.95595E+00 -0.0196 65 MnO2-2 0.36806E-15 -15.4341 0.32433E-15 -15.4890 0.88119E+00 -0.0549 66 HMnO2- 0.41730E-12 -12.3796 0.39889E-12 -12.3991 0.95590E+00 -0.0196 69 MnCl+ 0.77023E-11 -11.1134 0.73631E-11 -11.1329 0.95595E+00 -0.0196 70 MnSO4,aq 0.58689E-10 -10.2314 0.58689E-10 -10.2314 0.10000E+01 0.0000 71 NaCl,aq 0.14376E-07 -7.8424 0.14376E-07 -7.8424 0.10000E+01 0.0000 72 NaOH,aq 0.25841E-07 -7.5877 0.25841E-07 -7.5877 0.10000E+01 0.0000 74 OH- 0.11055E-03 -3.9564 0.10567E-03 -3.9761 0.95584E+00 -0.0196 79 HPO3-2 0.27721E-19 -19.5572 0.24427E-19 -19.6121 0.88119E+00 -0.0549 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.18219E-08 -8.7395 0.17416E-08 -8.7590 0.95592E+00 -0.0196 84 PO4-3 0.34952E-11 -11.4565 0.26922E-11 -11.5699 0.77027E+00 -0.1134 87 H2P2O7-2 0.26941E-18 -18.5696 0.23740E-18 -18.6245 0.88119E+00 -0.0549 88 HP2O7-3 0.11150E-16 -16.9527 0.85755E-17 -17.0667 0.76912E+00 -0.1140 89 P2O7-4 0.58565E-18 -18.2324 0.37268E-18 -18.4287 0.63636E+00 -0.1963 90 H2S,aq 0.41224E-14 -14.3849 0.41219E-14 -14.3849 0.99989E+00 0.0000 97 SO3-2 0.15344E-14 -14.8141 0.13527E-14 -14.8688 0.88158E+00 -0.0547 98 HSO3- 0.47010E-15 -15.3278 0.44937E-15 -15.3474 0.95590E+00 -0.0196 99 HSO4- 0.12369E-09 -9.9077 0.11824E-09 -9.9272 0.95598E+00 -0.0196 Charge balance for all species = 0.7202E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5937458E-08 -.2056049E-03 -.2072250E+00 0.0000 2 H2O 0.1000000E+01 0.5550830E+02 0.9999390E+06 0.0000 3 Cl- 0.1379641E-03 0.1379792E-03 0.4891483E+01 4.3661 4 SO4-- 0.2547397E-04 0.2550535E-04 0.2449938E+01 11.8430 5 HCO3- 0.1269922E-04 0.1307047E-04 0.7974760E+00 3.3301 6 HS- 0.2528213E-12 0.4785890E-10 0.1582695E-05 -4.3709 7 Al+++ 0.1434034E-21 0.6425353E-05 0.1733553E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4521717E-03 0.4345807E+02 -3.4168 9 Ca++ 0.3271124E-05 0.3341713E-05 0.1339212E+00 10.9515 10 Mg++ 0.1332887E-07 0.1420995E-07 0.3454516E-03 8.5616 11 Fe++ 0.7884465E-10 0.1260532E-08 0.7039273E-04 6.3335 12 K+ 0.3204710E-04 0.3206061E-04 0.1253559E+01 3.7321 13 Na+ 0.3492362E-03 0.3496254E-03 0.8037339E+01 4.7694 14 Mn++ 0.1047127E-07 0.1607572E-07 0.8831149E-03 8.4568 15 HPO4-- 0.1985810E-07 0.2168354E-07 0.2081041E-02 8.7349 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2487296E-02 -.2055974E-03 -.2281698E-02 0.0000000E+00 2 H2O 0.5550636E+02 0.5550630E+02 0.6179886E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2968919E-04 0.2550442E-04 0.4184773E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4184725E-05 0.4785716E-10 -.4184773E-05 0.0000000E+00 7 Al+++ 0.4923720E-03 0.6425121E-05 0.4859469E-03 0.0000000E+00 8 H4SiO4 0.1572330E-02 0.4521553E-03 0.1120175E-02 0.0000000E+00 9 Ca++ 0.1881426E-03 0.3341592E-05 0.1848010E-03 0.0000000E+00 10 Mg++ 0.1198413E-03 0.1420943E-07 0.1198271E-03 0.0000000E+00 11 Fe++ 0.1076643E-03 0.1260487E-08 0.1076630E-03 0.0000000E+00 12 K+ 0.3205945E-04 0.3205945E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3496128E-03 0.3496128E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2618128E-05 0.1607513E-07 0.2602053E-05 0.0000000E+00 15 HPO4-- 0.8935541E-06 0.2168276E-07 0.8718713E-06 0.0000000E+00 Chg. balance for solid moles: 0.2736E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1510000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2906E-06 -6.537 0.1460E-03 -3.836 0.1070 0.4639E-04 clinochlore 0.2397E-04 -4.620 0.1332E-01 -1.875 9.765 0.5067E-02 daphnite 0.1484E-04 -4.829 0.1059E-01 -1.975 7.761 0.3208E-02 chlorite-Mn 0.5204E-06 -6.284 0.3690E-03 -3.433 0.2705 0.1176E-03 hematite 0.1674E-04 -4.776 0.2673E-02 -2.573 1.960 0.5067E-03 kaolinite 0.2030E-04 -4.692 0.5241E-02 -2.281 3.842 0.2017E-02 lawsonite 0.6437E-04 -4.191 0.2023E-01 -1.694 14.83 0.6523E-02 stilbite 0.1190E-03 -3.925 0.8385E-01 -1.077 61.47 0.3911E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1323E-01 0.1323E-01 1.0000 -1.878 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.136412 g Volume = 0.056593 cm3 Porosity: 94.6630% V(tot) - V(min): 0.10038E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1510000 g log = -0.8210 Original solution: 1000.0103000 g Original solution / Rock added: 6622.58 (Water/Rock Ratio), log = 3.8210 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1501E-04 1.0073 0.1590E-04 0.1579E-04 CH4,gas 0.1903E-15 1.0129 0.2028E-15 0.2002E-15 H2,gas 0.5759E-06 1.0006 0.6061E-06 0.6058E-06 H2S,gas 0.1148E-12 0.9959 0.1202E-12 0.1207E-12 S2,gas 0.1401E-32 1.0000 0.1473E-32 0.1473E-32 CO,gas 0.2374E-14 1.0000 0.2497E-14 0.2497E-14 SO3,gas 0.2571E-36 1.0000 0.2704E-36 0.2704E-36 SO2,gas 0.5895E-20 1.0000 0.6201E-20 0.6201E-20 HCl,gas 0.2364E-15 1.0000 0.2486E-15 0.2486E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.18198E-10 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 164 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.16 -6.80 -2.266 0.11608E+05 -4.798 3 CH4,gas 4.81 -12.88 -17.69 -4.423 0.30210E+05 -15.693 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -20.86 -14.92 -7.460 0.25476E+05 -12.920 6 S2,gas -7.03 -41.86 -34.83 -5.359 0.59474E+05 -32.832 7 CO,gas 3.51 -13.09 -16.60 -5.108 0.28348E+05 -14.603 8 SO3,gas 17.43 -21.14 -38.57 -9.642 0.65854E+05 -36.568 9 SO2,gas 1.14 -21.07 -22.21 -5.922 0.37919E+05 -20.208 10 HCl,gas 5.48 -12.13 -17.60 -8.802 0.30059E+05 -15.604 11 acmite 7.74 4.23 -3.50 -0.364 0.59810E+04 15 albite-high 0.75 -2.70 -3.45 -0.265 0.58916E+04 16 albite -0.33 -2.70 -2.37 -0.182 0.40509E+04 19 spessartine 24.55 20.68 -3.87 -0.193 0.66071E+04 20 analcite 3.37 0.72 -2.65 -0.295 0.45327E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -10.19 -4.91 -2.455 0.83826E+04 26 annite 20.21 15.26 -4.95 -0.275 0.84466E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.21 -3.20 -1.065 0.54578E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.21 -3.04 -1.014 0.51964E+04 38 carnegieite-low 9.06 4.13 -4.93 -0.705 0.84207E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29411E+04 42 celadonite 5.40 1.41 -3.99 -0.235 0.68195E+04 43 celadonite-Fe 3.94 -0.82 -4.76 -0.280 0.81248E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13001E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.058 0.14731E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64765E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82449E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68764E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.72 -3.53 -0.353 0.60357E+04 97 kalsilite 7.62 3.10 -4.52 -0.646 0.77258E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.32 -4.49 -0.449 0.76647E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75751E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20517E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.74 -1.31 -0.100 0.22305E+04 120 muscovite 2.68 1.82 -0.86 -0.050 0.14629E+04 121 paragonite 4.34 2.86 -1.48 -0.087 0.25218E+04 122 nepheline 8.38 4.13 -4.25 -0.606 0.72487E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50040E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.475 0.40571E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.70 -3.75 -1.249 0.63968E+04 153 rhodonite 7.46 5.04 -2.42 -0.485 0.41364E+04 154 sanidine -1.22 -3.74 -2.52 -0.194 0.42983E+04 156 siderite -2.59 -6.83 -4.24 -1.413 0.72405E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.76 -1.42 -0.042 0.24242E+04 166 stilpnomelane-Mg 27.60 22.90 -4.70 -0.140 0.80194E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83655E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 175 tephroite 18.11 13.50 -4.62 -0.659 0.78820E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.83 -3.40 -0.208 0.57971E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.49 -3.23 -0.198 0.55166E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -4.97 -2.81 -0.172 0.47919E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.63 -2.66 -0.163 0.45495E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.21 -1.20 -0.077 0.20437E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.55 -1.03 -0.066 0.17649E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59602E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.22 -2.30 -0.177 0.39343E+04 244 an25ab75 2.71 0.39 -2.32 -0.178 0.39531E+04 245 an30ab70 3.34 1.01 -2.33 -0.179 0.39802E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1510000 g New total amount of reactant added: 0.1550000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1550000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3564986E-03 Osmotic coef. = 0.9888 True ionic strength = .4222553E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.57696E-08 -8.2389 0.55152E-08 -8.2584 0.95591E+00 -0.0196 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13186E-03 -3.8799 0.95574E+00 -0.0197 4 SO4-- 0.25475E-04 -4.5939 0.22435E-04 -4.6491 0.88066E+00 -0.0552 5 HCO3- 0.12697E-04 -4.8963 0.12135E-04 -4.9159 0.95578E+00 -0.0196 6 HS- 0.24550E-12 -12.6100 0.23463E-12 -12.6296 0.95574E+00 -0.0197 7 Al+++ 0.13171E-21 -21.8804 0.10115E-21 -21.9950 0.76795E+00 -0.1147 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.30898E-05 -5.5101 0.27204E-05 -5.5654 0.88046E+00 -0.0553 10 Mg++ 0.12590E-07 -7.9000 0.11083E-07 -7.9553 0.88034E+00 -0.0554 11 Fe++ 0.74473E-10 -10.1280 0.65564E-10 -10.1833 0.88037E+00 -0.0553 12 K+ 0.32896E-04 -4.4829 0.31442E-04 -4.5025 0.95579E+00 -0.0196 13 Na+ 0.35424E-03 -3.4507 0.33856E-03 -3.4704 0.95573E+00 -0.0197 14 Mn++ 0.98949E-08 -8.0046 0.87114E-08 -8.0599 0.88039E+00 -0.0553 15 HPO4-- 0.21052E-07 -7.6767 0.18539E-07 -7.7319 0.88066E+00 -0.0552 16 HSiO3- 0.70885E-04 -4.1494 0.67748E-04 -4.1691 0.95574E+00 -0.0197 17 Ca(HSiO3)+ 0.43203E-08 -8.3645 0.41294E-08 -8.3841 0.95579E+00 -0.0196 18 Mg(HSiO3)+ 0.21905E-10 -10.6594 0.20937E-10 -10.6791 0.95579E+00 -0.0196 19 NaHSiO3,aq 0.36429E-06 -6.4386 0.36429E-06 -6.4386 0.10000E+01 0.0000 20 AlO+ 0.44914E-12 -12.3476 0.42929E-12 -12.3673 0.95579E+00 -0.0196 21 AlOH+2 0.13471E-16 -16.8706 0.11860E-16 -16.9259 0.88041E+00 -0.0553 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.65985E-05 -5.1806 0.63061E-05 -5.2002 0.95568E+00 -0.0197 24 CH4,aq 0.12455E-18 -18.9046 0.12454E-18 -18.9047 0.99989E+00 0.0000 29 CO,aq 0.15359E-17 -17.8136 0.15359E-17 -17.8136 0.10000E+01 0.0000 30 CO2,aq 0.13496E-06 -6.8698 0.13494E-06 -6.8699 0.99989E+00 0.0000 31 CO3-2 0.23103E-06 -6.6363 0.20344E-06 -6.6916 0.88060E+00 -0.0552 32 CaCO3,aq 0.67785E-08 -8.1689 0.67785E-08 -8.1689 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.87032E-09 -9.0603 0.83184E-09 -9.0800 0.95579E+00 -0.0196 34 CaCl+ 0.59804E-09 -9.2233 0.57160E-09 -9.2429 0.95579E+00 -0.0196 35 CaCl2,aq 0.17549E-13 -13.7558 0.17549E-13 -13.7558 0.10000E+01 0.0000 36 CaOH+ 0.36390E-07 -7.4390 0.34781E-07 -7.4587 0.95579E+00 -0.0196 37 CaSO4,aq 0.19016E-07 -7.7209 0.19016E-07 -7.7209 0.10000E+01 0.0000 38 HCl,aq 0.13679E-12 -12.8640 0.13679E-12 -12.8640 0.10000E+01 0.0000 43 FeCl+ 0.14088E-13 -13.8512 0.13465E-13 -13.8708 0.95579E+00 -0.0196 46 FeO,aq 0.85236E-10 -10.0694 0.85236E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.41234E-09 -9.3847 0.39411E-09 -9.4044 0.95579E+00 -0.0196 48 HFeO2- 0.17393E-09 -9.7596 0.16623E-09 -9.7793 0.95574E+00 -0.0197 49 FeO+ 0.47733E-13 -13.3212 0.45623E-13 -13.3408 0.95579E+00 -0.0196 50 FeOH+2 0.53181E-19 -19.2742 0.46821E-19 -19.3296 0.88041E+00 -0.0553 51 FeO2- 0.30844E-09 -9.5108 0.29479E-09 -9.5305 0.95574E+00 -0.0197 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44197E-09 -9.3546 0.44192E-09 -9.3547 0.99989E+00 0.0000 54 KCl,aq 0.73408E-10 -10.1343 0.73408E-10 -10.1343 0.10000E+01 0.0000 55 KHSO4,aq 0.10410E-16 -16.9825 0.10410E-16 -16.9825 0.10000E+01 0.0000 56 KOH,aq 0.24853E-08 -8.6046 0.24853E-08 -8.6046 0.10000E+01 0.0000 57 KSO4- 0.11371E-07 -7.9442 0.10867E-07 -7.9639 0.95574E+00 -0.0197 58 MgCO3,aq 0.69008E-11 -11.1611 0.69008E-11 -11.1611 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.36157E-11 -11.4418 0.34559E-11 -11.4614 0.95579E+00 -0.0196 60 MgCl+ 0.22119E-11 -11.6552 0.21141E-11 -11.6749 0.95579E+00 -0.0196 61 MgOH+ 0.82135E-09 -9.0855 0.78504E-09 -9.1051 0.95579E+00 -0.0196 63 MnO,aq 0.30233E-09 -9.5195 0.30233E-09 -9.5195 0.10000E+01 0.0000 64 MnOH+ 0.50895E-08 -8.2933 0.48645E-08 -8.3130 0.95579E+00 -0.0196 65 MnO2-2 0.39034E-15 -15.4086 0.34374E-15 -15.4638 0.88060E+00 -0.0552 66 HMnO2- 0.42977E-12 -12.3668 0.41074E-12 -12.3864 0.95574E+00 -0.0197 69 MnCl+ 0.72735E-11 -11.1383 0.69520E-11 -11.1579 0.95579E+00 -0.0196 70 MnSO4,aq 0.55387E-10 -10.2566 0.55387E-10 -10.2566 0.10000E+01 0.0000 71 NaCl,aq 0.14577E-07 -7.8363 0.14577E-07 -7.8363 0.10000E+01 0.0000 72 NaOH,aq 0.26974E-07 -7.5691 0.26974E-07 -7.5691 0.10000E+01 0.0000 74 OH- 0.11380E-03 -3.9438 0.10876E-03 -3.9635 0.95568E+00 -0.0197 79 HPO3-2 0.29386E-19 -19.5319 0.25878E-19 -19.5871 0.88060E+00 -0.0552 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.18756E-08 -8.7269 0.17926E-08 -8.7465 0.95576E+00 -0.0196 84 PO4-3 0.38169E-11 -11.4183 0.29356E-11 -11.5323 0.76912E+00 -0.1140 87 H2P2O7-2 0.28561E-18 -18.5442 0.25150E-18 -18.5995 0.88060E+00 -0.0552 88 HP2O7-3 0.12176E-16 -16.9145 0.93509E-17 -17.0291 0.76796E+00 -0.1147 89 P2O7-4 0.65905E-18 -18.1811 0.41827E-18 -18.3785 0.63466E+00 -0.1975 90 H2S,aq 0.38884E-14 -14.4102 0.38880E-14 -14.4103 0.99989E+00 0.0000 97 SO3-2 0.15344E-14 -14.8141 0.13518E-14 -14.8691 0.88099E+00 -0.0550 98 HSO3- 0.45651E-15 -15.3405 0.43630E-15 -15.3602 0.95574E+00 -0.0197 99 HSO4- 0.12011E-09 -9.9204 0.11481E-09 -9.9400 0.95582E+00 -0.0196 Charge balance for all species = 0.7200E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5769559E-08 -.2116683E-03 -.2133361E+00 0.0000 2 H2O 0.1000000E+01 0.5550831E+02 0.9999387E+06 0.0000 3 Cl- 0.1379640E-03 0.1379793E-03 0.4891485E+01 4.3785 4 SO4-- 0.2547485E-04 0.2550537E-04 0.2449939E+01 11.8678 5 HCO3- 0.1269684E-04 0.1307048E-04 0.7974763E+00 3.3425 6 HS- 0.2454956E-12 0.4674644E-10 0.1545905E-05 -4.3712 7 Al+++ 0.1317116E-21 0.6614093E-05 0.1784474E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4542144E-03 0.4365437E+02 -3.4168 9 Ca++ 0.3089785E-05 0.3157758E-05 0.1265490E+00 10.9515 10 Mg++ 0.1258996E-07 0.1344594E-07 0.3268782E-03 8.5615 11 Fe++ 0.7447307E-10 0.1257949E-08 0.7024847E-04 6.3335 12 K+ 0.3289599E-04 0.3290992E-04 0.1286766E+01 3.7559 13 Na+ 0.3542410E-03 0.3546469E-03 0.8152771E+01 4.7881 14 Mn++ 0.9894938E-08 0.1534989E-07 0.8432415E-03 8.4570 15 HPO4-- 0.2105172E-07 0.2293114E-07 0.2200775E-02 8.7850 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2553530E-02 -.2116605E-03 -.2341869E-02 0.0000000E+00 2 H2O 0.5550631E+02 0.5550625E+02 0.5336558E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2980005E-04 0.2550442E-04 0.4295625E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4295578E-05 0.4674471E-10 -.4295625E-05 0.0000000E+00 7 Al+++ 0.5054149E-03 0.6613848E-05 0.4988011E-03 0.0000000E+00 8 H4SiO4 0.1613981E-02 0.4541976E-03 0.1159784E-02 0.0000000E+00 9 Ca++ 0.1927432E-03 0.3157641E-05 0.1895855E-03 0.0000000E+00 10 Mg++ 0.1230159E-03 0.1344545E-07 0.1230024E-03 0.0000000E+00 11 Fe++ 0.1105163E-03 0.1257903E-08 0.1105151E-03 0.0000000E+00 12 K+ 0.3290870E-04 0.3290870E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3546338E-03 0.3546338E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2687482E-05 0.1534932E-07 0.2672133E-05 0.0000000E+00 15 HPO4-- 0.9172244E-06 0.2293029E-07 0.8942941E-06 0.0000000E+00 Chg. balance for solid moles: -.1827E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1550000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2981E-06 -6.526 0.1497E-03 -3.825 0.1064 0.4758E-04 clinochlore 0.2460E-04 -4.609 0.1367E-01 -1.864 9.712 0.5201E-02 daphnite 0.1523E-04 -4.817 0.1087E-01 -1.964 7.718 0.3293E-02 chlorite-Mn 0.5344E-06 -6.272 0.3789E-03 -3.421 0.2691 0.1207E-03 hematite 0.1718E-04 -4.765 0.2744E-02 -2.562 1.949 0.5201E-03 kaolinite 0.2094E-04 -4.679 0.5406E-02 -2.267 3.840 0.2080E-02 lawsonite 0.6397E-04 -4.194 0.2010E-01 -1.697 14.28 0.6483E-02 stilbite 0.1241E-03 -3.906 0.8747E-01 -1.058 62.13 0.4080E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1324E-01 0.1324E-01 1.0000 -1.878 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.140794 g Volume = 0.058544 cm3 Porosity: 94.4874% V(tot) - V(min): 0.10035E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1550000 g log = -0.8097 Original solution: 1000.0103000 g Original solution / Rock added: 6451.68 (Water/Rock Ratio), log = 3.8097 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1458E-04 1.0073 0.1545E-04 0.1533E-04 CH4,gas 0.1848E-15 1.0129 0.1969E-15 0.1944E-15 H2,gas 0.5759E-06 1.0006 0.6061E-06 0.6058E-06 H2S,gas 0.1082E-12 0.9959 0.1134E-12 0.1139E-12 S2,gas 0.1246E-32 1.0000 0.1311E-32 0.1311E-32 CO,gas 0.2305E-14 1.0000 0.2425E-14 0.2425E-14 SO3,gas 0.2425E-36 1.0000 0.2551E-36 0.2551E-36 SO2,gas 0.5561E-20 1.0000 0.5850E-20 0.5850E-20 HCl,gas 0.2296E-15 1.0000 0.2415E-15 0.2415E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 164 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.17 -6.81 -2.270 0.11630E+05 -4.811 3 CH4,gas 4.81 -12.90 -17.71 -4.426 0.30232E+05 -15.706 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -20.89 -14.95 -7.473 0.25519E+05 -12.945 6 S2,gas -7.03 -41.92 -34.88 -5.367 0.59561E+05 -32.882 7 CO,gas 3.51 -13.10 -16.62 -5.112 0.28370E+05 -14.615 8 SO3,gas 17.43 -21.17 -38.59 -9.648 0.65897E+05 -36.593 9 SO2,gas 1.14 -21.10 -22.23 -5.929 0.37962E+05 -20.233 10 HCl,gas 5.48 -12.14 -17.62 -8.809 0.30081E+05 -15.617 11 acmite 7.74 4.25 -3.48 -0.362 0.59492E+04 15 albite-high 0.75 -2.68 -3.43 -0.264 0.58598E+04 16 albite -0.33 -2.68 -2.35 -0.181 0.40191E+04 19 spessartine 24.55 20.68 -3.87 -0.193 0.66062E+04 20 analcite 3.37 0.73 -2.64 -0.293 0.45009E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -10.21 -4.93 -2.467 0.84259E+04 26 annite 20.21 15.29 -4.92 -0.274 0.84059E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.22 -3.21 -1.070 0.54794E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.22 -3.06 -1.019 0.52181E+04 38 carnegieite-low 9.06 4.15 -4.91 -0.702 0.83889E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29411E+04 42 celadonite 5.40 1.43 -3.97 -0.234 0.67789E+04 43 celadonite-Fe 3.94 -0.80 -4.73 -0.279 0.80841E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13001E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.058 0.14728E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64765E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82449E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68765E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.73 -3.52 -0.352 0.60039E+04 97 kalsilite 7.62 3.12 -4.50 -0.643 0.76851E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.30 -4.47 -0.447 0.76241E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75751E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20517E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.71 -1.28 -0.099 0.21899E+04 120 muscovite 2.68 1.85 -0.83 -0.049 0.14223E+04 121 paragonite 4.34 2.88 -1.46 -0.086 0.24900E+04 122 nepheline 8.38 4.15 -4.23 -0.604 0.72168E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50040E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.475 0.40568E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.72 -3.76 -1.253 0.64182E+04 153 rhodonite 7.46 5.04 -2.42 -0.484 0.41360E+04 154 sanidine -1.22 -3.71 -2.49 -0.192 0.42576E+04 156 siderite -2.59 -6.84 -4.25 -1.418 0.72622E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.77 -1.41 -0.042 0.24039E+04 166 stilpnomelane-Mg 27.60 22.91 -4.68 -0.140 0.79991E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83656E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 175 tephroite 18.11 13.50 -4.62 -0.659 0.78814E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.82 -3.39 -0.207 0.57837E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.48 -3.22 -0.197 0.55061E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -4.96 -2.80 -0.171 0.47785E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.62 -2.66 -0.163 0.45390E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.21 -1.19 -0.076 0.20303E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.56 -1.03 -0.066 0.17544E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59602E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.21 -2.29 -0.176 0.39089E+04 244 an25ab75 2.71 0.41 -2.30 -0.177 0.39292E+04 245 an30ab70 3.34 1.03 -2.32 -0.178 0.39579E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1550000 g New total amount of reactant added: 0.1590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1590000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3599480E-03 Osmotic coef. = 0.9887 True ionic strength = .4276101E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.56102E-08 -8.2510 0.53620E-08 -8.2707 0.95576E+00 -0.0197 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13184E-03 -3.8800 0.95558E+00 -0.0197 4 SO4-- 0.25476E-04 -4.5939 0.22420E-04 -4.6494 0.88007E+00 -0.0555 5 HCO3- 0.12694E-04 -4.8964 0.12131E-04 -4.9161 0.95562E+00 -0.0197 6 HS- 0.23854E-12 -12.6224 0.22795E-12 -12.6422 0.95558E+00 -0.0197 7 Al+++ 0.12122E-21 -21.9164 0.92950E-22 -22.0318 0.76679E+00 -0.1153 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.29224E-05 -5.5343 0.25714E-05 -5.5898 0.87987E+00 -0.0556 10 Mg++ 0.11908E-07 -7.9242 0.10476E-07 -7.9798 0.87974E+00 -0.0556 11 Fe++ 0.70439E-10 -10.1522 0.61970E-10 -10.2078 0.87977E+00 -0.0556 12 K+ 0.33745E-04 -4.4718 0.32248E-04 -4.4915 0.95563E+00 -0.0197 13 Na+ 0.35925E-03 -3.4446 0.34328E-03 -3.4643 0.95557E+00 -0.0197 14 Mn++ 0.93626E-08 -8.0286 0.82372E-08 -8.0842 0.87980E+00 -0.0556 15 HPO4-- 0.22287E-07 -7.6519 0.19614E-07 -7.7074 0.88007E+00 -0.0555 16 HSiO3- 0.72923E-04 -4.1371 0.69684E-04 -4.1569 0.95558E+00 -0.0197 17 Ca(HSiO3)+ 0.42010E-08 -8.3766 0.40146E-08 -8.3964 0.95563E+00 -0.0197 18 Mg(HSiO3)+ 0.21300E-10 -10.6716 0.20355E-10 -10.6913 0.95563E+00 -0.0197 19 NaHSiO3,aq 0.37993E-06 -6.4203 0.37993E-06 -6.4203 0.10000E+01 0.0000 20 AlO+ 0.43674E-12 -12.3598 0.41736E-12 -12.3795 0.95563E+00 -0.0197 21 AlOH+2 0.12742E-16 -16.8948 0.11210E-16 -16.9504 0.87982E+00 -0.0556 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.67882E-05 -5.1682 0.64863E-05 -5.1880 0.95552E+00 -0.0198 24 CH4,aq 0.12104E-18 -18.9171 0.12102E-18 -18.9171 0.99989E+00 0.0000 29 CO,aq 0.14926E-17 -17.8261 0.14926E-17 -17.8261 0.10000E+01 0.0000 30 CO2,aq 0.13116E-06 -6.8822 0.13114E-06 -6.8823 0.99989E+00 0.0000 31 CO3-2 0.23770E-06 -6.6240 0.20918E-06 -6.6795 0.88001E+00 -0.0555 32 CaCO3,aq 0.65877E-08 -8.1813 0.65877E-08 -8.1813 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.82246E-09 -9.0849 0.78597E-09 -9.1046 0.95563E+00 -0.0197 34 CaCl+ 0.56527E-09 -9.2477 0.54019E-09 -9.2675 0.95563E+00 -0.0197 35 CaCl2,aq 0.16582E-13 -13.7804 0.16582E-13 -13.7804 0.10000E+01 0.0000 36 CaOH+ 0.35385E-07 -7.4512 0.33815E-07 -7.4709 0.95563E+00 -0.0197 37 CaSO4,aq 0.17963E-07 -7.7456 0.17963E-07 -7.7456 0.10000E+01 0.0000 38 HCl,aq 0.13297E-12 -12.8763 0.13297E-12 -12.8763 0.10000E+01 0.0000 43 FeCl+ 0.13315E-13 -13.8756 0.12725E-13 -13.8954 0.95563E+00 -0.0197 46 FeO,aq 0.85235E-10 -10.0694 0.85235E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.40095E-09 -9.3969 0.38316E-09 -9.4166 0.95563E+00 -0.0197 48 HFeO2- 0.17893E-09 -9.7473 0.17098E-09 -9.7671 0.95558E+00 -0.0197 49 FeO+ 0.46414E-13 -13.3333 0.44355E-13 -13.3531 0.95563E+00 -0.0197 50 FeOH+2 0.50300E-19 -19.2984 0.44255E-19 -19.3540 0.87982E+00 -0.0556 51 FeO2- 0.31731E-09 -9.4985 0.30321E-09 -9.5183 0.95558E+00 -0.0197 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44196E-09 -9.3546 0.44191E-09 -9.3547 0.99989E+00 0.0000 54 KCl,aq 0.75277E-10 -10.1233 0.75277E-10 -10.1233 0.10000E+01 0.0000 55 KHSO4,aq 0.10374E-16 -16.9841 0.10374E-16 -16.9841 0.10000E+01 0.0000 56 KOH,aq 0.26218E-08 -8.5814 0.26218E-08 -8.5814 0.10000E+01 0.0000 57 KSO4- 0.11657E-07 -7.9334 0.11139E-07 -7.9532 0.95558E+00 -0.0197 58 MgCO3,aq 0.67065E-11 -11.1735 0.67065E-11 -11.1735 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.34169E-11 -11.4664 0.32653E-11 -11.4861 0.95563E+00 -0.0197 60 MgCl+ 0.20907E-11 -11.6797 0.19979E-11 -11.6994 0.95563E+00 -0.0197 61 MgOH+ 0.79867E-09 -9.0976 0.76323E-09 -9.1173 0.95563E+00 -0.0197 63 MnO,aq 0.30244E-09 -9.5194 0.30244E-09 -9.5194 0.10000E+01 0.0000 64 MnOH+ 0.49508E-08 -8.3053 0.47312E-08 -8.3250 0.95563E+00 -0.0197 65 MnO2-2 0.41341E-15 -15.3836 0.36380E-15 -15.4391 0.88001E+00 -0.0555 66 HMnO2- 0.44229E-12 -12.3543 0.42264E-12 -12.3740 0.95558E+00 -0.0197 69 MnCl+ 0.68776E-11 -11.1626 0.65724E-11 -11.1823 0.95563E+00 -0.0197 70 MnSO4,aq 0.52339E-10 -10.2812 0.52339E-10 -10.2812 0.10000E+01 0.0000 71 NaCl,aq 0.14778E-07 -7.8304 0.14778E-07 -7.8304 0.10000E+01 0.0000 72 NaOH,aq 0.28132E-07 -7.5508 0.28132E-07 -7.5508 0.10000E+01 0.0000 74 OH- 0.11708E-03 -3.9315 0.11187E-03 -3.9513 0.95552E+00 -0.0198 79 HPO3-2 0.31110E-19 -19.5071 0.27377E-19 -19.5626 0.88001E+00 -0.0555 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.19295E-08 -8.7146 0.18439E-08 -8.7343 0.95560E+00 -0.0197 84 PO4-3 0.41597E-11 -11.3809 0.31946E-11 -11.4956 0.76797E+00 -0.1147 87 H2P2O7-2 0.30237E-18 -18.5195 0.26608E-18 -18.5750 0.88001E+00 -0.0555 88 HP2O7-3 0.13270E-16 -16.8771 0.10176E-16 -16.9924 0.76680E+00 -0.1153 89 P2O7-4 0.73965E-18 -18.1310 0.46817E-18 -18.3296 0.63297E+00 -0.1986 90 H2S,aq 0.36727E-14 -14.4350 0.36723E-14 -14.4351 0.99989E+00 0.0000 97 SO3-2 0.15344E-14 -14.8141 0.13509E-14 -14.8694 0.88041E+00 -0.0553 98 HSO3- 0.44361E-15 -15.3530 0.42390E-15 -15.3727 0.95558E+00 -0.0197 99 HSO4- 0.11672E-09 -9.9329 0.11154E-09 -9.9526 0.95566E+00 -0.0197 Charge balance for all species = 0.7202E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5610197E-08 -.2177631E-03 -.2194789E+00 0.0000 2 H2O 0.1000000E+01 0.5550831E+02 0.9999383E+06 0.0000 3 Cl- 0.1379640E-03 0.1379794E-03 0.4891487E+01 4.3907 4 SO4-- 0.2547564E-04 0.2550539E-04 0.2449940E+01 11.8920 5 HCO3- 0.1269421E-04 0.1307049E-04 0.7974767E+00 3.3546 6 HS- 0.2385444E-12 0.4562892E-10 0.1508948E-05 -4.3715 7 Al+++ 0.1212187E-21 0.6803805E-05 0.1835658E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4562678E-03 0.4385171E+02 -3.4168 9 Ca++ 0.2922445E-05 0.2987969E-05 0.1197446E+00 10.9515 10 Mg++ 0.1190809E-07 0.1274027E-07 0.3097228E-03 8.5615 11 Fe++ 0.7043909E-10 0.1256386E-08 0.7016115E-04 6.3335 12 K+ 0.3374488E-04 0.3375924E-04 0.1319974E+01 3.7792 13 Na+ 0.3592455E-03 0.3596683E-03 0.8268203E+01 4.8063 14 Mn++ 0.9362603E-08 0.1467555E-07 0.8061964E-03 8.4571 15 HPO4-- 0.2228699E-07 0.2422067E-07 0.2324535E-02 8.8339 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2619764E-02 -.2177549E-03 -.2402009E-02 0.0000000E+00 2 H2O 0.5550626E+02 0.5550621E+02 0.4492739E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2991090E-04 0.2550442E-04 0.4406478E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4406432E-05 0.4562720E-10 -.4406478E-05 0.0000000E+00 7 Al+++ 0.5184579E-03 0.6803548E-05 0.5116544E-03 0.0000000E+00 8 H4SiO4 0.1655632E-02 0.4562506E-03 0.1199382E-02 0.0000000E+00 9 Ca++ 0.1973437E-03 0.2987856E-05 0.1943559E-03 0.0000000E+00 10 Mg++ 0.1261905E-03 0.1273979E-07 0.1261777E-03 0.0000000E+00 11 Fe++ 0.1133684E-03 0.1256339E-08 0.1133671E-03 0.0000000E+00 12 K+ 0.3375796E-04 0.3375796E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3596547E-03 0.3596547E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2756837E-05 0.1467499E-07 0.2742162E-05 0.0000000E+00 15 HPO4-- 0.9408947E-06 0.2421976E-07 0.9166749E-06 0.0000000E+00 Chg. balance for solid moles: 0.4150E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3056E-06 -6.515 0.1535E-03 -3.814 0.1057 0.4877E-04 clinochlore 0.2524E-04 -4.598 0.1403E-01 -1.853 9.662 0.5335E-02 daphnite 0.1562E-04 -4.806 0.1115E-01 -1.953 7.678 0.3378E-02 chlorite-Mn 0.5484E-06 -6.261 0.3888E-03 -3.410 0.2678 0.1239E-03 hematite 0.1763E-04 -4.754 0.2815E-02 -2.551 1.939 0.5335E-03 kaolinite 0.2159E-04 -4.666 0.5574E-02 -2.254 3.840 0.2145E-02 lawsonite 0.6356E-04 -4.197 0.1997E-01 -1.700 13.76 0.6441E-02 stilbite 0.1293E-03 -3.889 0.9109E-01 -1.041 62.75 0.4249E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6095E+00 0.6095E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1324E-01 0.1324E-01 1.0000 -1.878 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.145175 g Volume = 0.060494 cm3 Porosity: 94.3123% V(tot) - V(min): 0.10031E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1590000 g log = -0.7986 Original solution: 1000.0103000 g Original solution / Rock added: 6289.37 (Water/Rock Ratio), log = 3.7986 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1417E-04 1.0073 0.1501E-04 0.1490E-04 CH4,gas 0.1796E-15 1.0129 0.1914E-15 0.1889E-15 H2,gas 0.5759E-06 1.0006 0.6061E-06 0.6058E-06 H2S,gas 0.1022E-12 0.9959 0.1071E-12 0.1075E-12 S2,gas 0.1112E-32 1.0000 0.1170E-32 0.1170E-32 CO,gas 0.2240E-14 1.0000 0.2357E-14 0.2357E-14 SO3,gas 0.2291E-36 1.0000 0.2410E-36 0.2410E-36 SO2,gas 0.5253E-20 1.0000 0.5526E-20 0.5526E-20 HCl,gas 0.2232E-15 1.0000 0.2348E-15 0.2348E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 164 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.19 -6.82 -2.275 0.11651E+05 -4.824 3 CH4,gas 4.81 -12.91 -17.72 -4.430 0.30253E+05 -15.718 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -20.91 -14.97 -7.485 0.25561E+05 -12.970 6 S2,gas -7.03 -41.96 -34.93 -5.374 0.59645E+05 -32.932 7 CO,gas 3.51 -13.12 -16.63 -5.116 0.28391E+05 -14.628 8 SO3,gas 17.43 -21.19 -38.62 -9.655 0.65939E+05 -36.618 9 SO2,gas 1.14 -21.12 -22.26 -5.935 0.38004E+05 -20.258 10 HCl,gas 5.48 -12.15 -17.63 -8.815 0.30102E+05 -15.629 11 acmite 7.74 4.27 -3.47 -0.360 0.59180E+04 15 albite-high 0.75 -2.66 -3.41 -0.263 0.58286E+04 16 albite -0.33 -2.66 -2.34 -0.180 0.39879E+04 19 spessartine 24.55 20.68 -3.87 -0.193 0.66053E+04 20 analcite 3.37 0.75 -2.62 -0.291 0.44697E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -10.24 -4.96 -2.480 0.84681E+04 26 annite 20.21 15.31 -4.90 -0.272 0.83663E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.24 -3.22 -1.074 0.55006E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.24 -3.07 -1.023 0.52393E+04 38 carnegieite-low 9.06 4.17 -4.89 -0.699 0.83577E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29411E+04 42 celadonite 5.40 1.45 -3.95 -0.232 0.67392E+04 43 celadonite-Fe 3.94 -0.77 -4.71 -0.277 0.80445E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13001E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14725E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64765E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82449E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68765E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.75 -3.50 -0.350 0.59727E+04 97 kalsilite 7.62 3.14 -4.48 -0.640 0.76455E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.27 -4.44 -0.444 0.75844E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75751E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.69 -1.26 -0.097 0.21502E+04 120 muscovite 2.68 1.87 -0.81 -0.048 0.13826E+04 121 paragonite 4.34 2.90 -1.44 -0.085 0.24588E+04 122 nepheline 8.38 4.17 -4.21 -0.601 0.71857E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50040E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.475 0.40565E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.73 -3.77 -1.257 0.64391E+04 153 rhodonite 7.46 5.04 -2.42 -0.484 0.41358E+04 154 sanidine -1.22 -3.69 -2.47 -0.190 0.42180E+04 156 siderite -2.59 -6.85 -4.27 -1.422 0.72834E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.78 -1.40 -0.042 0.23841E+04 166 stilpnomelane-Mg 27.60 22.92 -4.67 -0.139 0.79793E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83656E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 175 tephroite 18.11 13.50 -4.62 -0.659 0.78808E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.81 -3.38 -0.207 0.57706E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.48 -3.22 -0.197 0.54958E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37188E+04 203 montmorillonite-K -2.16 -4.95 -2.79 -0.171 0.47654E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.61 -2.65 -0.162 0.45287E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.22 -1.18 -0.076 0.20172E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.56 -1.02 -0.066 0.17441E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59602E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.20 -2.27 -0.175 0.38840E+04 244 an25ab75 2.71 0.42 -2.29 -0.176 0.39059E+04 245 an30ab70 3.34 1.04 -2.31 -0.177 0.39361E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1590000 g New total amount of reactant added: 0.1630000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1630000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3634273E-03 Osmotic coef. = 0.9887 True ionic strength = .4330030E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.54588E-08 -8.2629 0.52164E-08 -8.2826 0.95560E+00 -0.0197 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13181E-03 -3.8800 0.95541E+00 -0.0198 4 SO4-- 0.25476E-04 -4.5939 0.22406E-04 -4.6496 0.87948E+00 -0.0558 5 HCO3- 0.12691E-04 -4.8965 0.12126E-04 -4.9163 0.95546E+00 -0.0198 6 HS- 0.23194E-12 -12.6346 0.22160E-12 -12.6544 0.95542E+00 -0.0198 7 Al+++ 0.11178E-21 -21.9516 0.85584E-22 -22.0676 0.76564E+00 -0.1160 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.27678E-05 -5.5579 0.24337E-05 -5.6137 0.87928E+00 -0.0559 10 Mg++ 0.11278E-07 -7.9478 0.99150E-08 -8.0037 0.87915E+00 -0.0559 11 Fe++ 0.66711E-10 -10.1758 0.58651E-10 -10.2317 0.87918E+00 -0.0559 12 K+ 0.34594E-04 -4.4610 0.33053E-04 -4.4808 0.95547E+00 -0.0198 13 Na+ 0.36425E-03 -3.4386 0.34801E-03 -3.4584 0.95541E+00 -0.0198 14 Mn++ 0.88702E-08 -8.0521 0.77987E-08 -8.1080 0.87921E+00 -0.0559 15 HPO4-- 0.23564E-07 -7.6278 0.20724E-07 -7.6835 0.87948E+00 -0.0558 16 HSiO3- 0.74971E-04 -4.1251 0.71628E-04 -4.1449 0.95541E+00 -0.0198 17 Ca(HSiO3)+ 0.40877E-08 -8.3885 0.39056E-08 -8.4083 0.95547E+00 -0.0198 18 Mg(HSiO3)+ 0.20726E-10 -10.6835 0.19803E-10 -10.7033 0.95547E+00 -0.0198 19 NaHSiO3,aq 0.39590E-06 -6.4024 0.39590E-06 -6.4024 0.10000E+01 0.0000 20 AlO+ 0.42495E-12 -12.3717 0.40603E-12 -12.3914 0.95547E+00 -0.0198 21 AlOH+2 0.12067E-16 -16.9184 0.10610E-16 -16.9743 0.87923E+00 -0.0559 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.69788E-05 -5.1562 0.66673E-05 -5.1761 0.95536E+00 -0.0198 24 CH4,aq 0.11770E-18 -18.9292 0.11768E-18 -18.9293 0.99989E+00 0.0000 29 CO,aq 0.14515E-17 -17.8382 0.14515E-17 -17.8382 0.10000E+01 0.0000 30 CO2,aq 0.12755E-06 -6.8943 0.12753E-06 -6.8944 0.99989E+00 0.0000 31 CO3-2 0.24440E-06 -6.6119 0.21493E-06 -6.6677 0.87942E+00 -0.0558 32 CaCO3,aq 0.64063E-08 -8.1934 0.64063E-08 -8.1934 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.77824E-09 -9.1089 0.74358E-09 -9.1287 0.95547E+00 -0.0198 34 CaCl+ 0.53499E-09 -9.2717 0.51117E-09 -9.2914 0.95547E+00 -0.0198 35 CaCl2,aq 0.15688E-13 -13.8044 0.15688E-13 -13.8044 0.10000E+01 0.0000 36 CaOH+ 0.34430E-07 -7.4631 0.32897E-07 -7.4828 0.95547E+00 -0.0198 37 CaSO4,aq 0.16990E-07 -7.7698 0.16990E-07 -7.7698 0.10000E+01 0.0000 38 HCl,aq 0.12933E-12 -12.8883 0.12933E-12 -12.8883 0.10000E+01 0.0000 43 FeCl+ 0.12602E-13 -13.8996 0.12041E-13 -13.9193 0.95547E+00 -0.0198 46 FeO,aq 0.85234E-10 -10.0694 0.85234E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.39012E-09 -9.4088 0.37275E-09 -9.4286 0.95547E+00 -0.0198 48 HFeO2- 0.18395E-09 -9.7353 0.17575E-09 -9.7551 0.95541E+00 -0.0198 49 FeO+ 0.45162E-13 -13.3452 0.43151E-13 -13.3650 0.95547E+00 -0.0198 50 FeOH+2 0.47639E-19 -19.3220 0.41885E-19 -19.3779 0.87923E+00 -0.0559 51 FeO2- 0.32622E-09 -9.4865 0.31167E-09 -9.5063 0.95541E+00 -0.0198 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44195E-09 -9.3546 0.44190E-09 -9.3547 0.99989E+00 0.0000 54 KCl,aq 0.77144E-10 -10.1127 0.77144E-10 -10.1127 0.10000E+01 0.0000 55 KHSO4,aq 0.10338E-16 -16.9856 0.10338E-16 -16.9856 0.10000E+01 0.0000 56 KOH,aq 0.27623E-08 -8.5587 0.27623E-08 -8.5587 0.10000E+01 0.0000 57 KSO4- 0.11942E-07 -7.9229 0.11410E-07 -7.9427 0.95541E+00 -0.0198 58 MgCO3,aq 0.65219E-11 -11.1856 0.65219E-11 -11.1856 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.32332E-11 -11.4904 0.30892E-11 -11.5102 0.95547E+00 -0.0198 60 MgCl+ 0.19787E-11 -11.7036 0.18906E-11 -11.7234 0.95547E+00 -0.0198 61 MgOH+ 0.77711E-09 -9.1095 0.74251E-09 -9.1293 0.95547E+00 -0.0198 63 MnO,aq 0.30255E-09 -9.5192 0.30255E-09 -9.5192 0.10000E+01 0.0000 64 MnOH+ 0.48189E-08 -8.3171 0.46043E-08 -8.3368 0.95547E+00 -0.0198 65 MnO2-2 0.43724E-15 -15.3593 0.38452E-15 -15.4151 0.87942E+00 -0.0558 66 HMnO2- 0.45486E-12 -12.3421 0.43458E-12 -12.3619 0.95541E+00 -0.0198 69 MnCl+ 0.65115E-11 -11.1863 0.62216E-11 -11.2061 0.95547E+00 -0.0198 70 MnSO4,aq 0.49521E-10 -10.3052 0.49521E-10 -10.3052 0.10000E+01 0.0000 71 NaCl,aq 0.14978E-07 -7.8245 0.14978E-07 -7.8245 0.10000E+01 0.0000 72 NaOH,aq 0.29315E-07 -7.5329 0.29315E-07 -7.5329 0.10000E+01 0.0000 74 OH- 0.12036E-03 -3.9195 0.11499E-03 -3.9393 0.95536E+00 -0.0198 79 HPO3-2 0.32892E-19 -19.4829 0.28926E-19 -19.5387 0.87942E+00 -0.0558 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.19837E-08 -8.7025 0.18953E-08 -8.7223 0.95544E+00 -0.0198 84 PO4-3 0.45245E-11 -11.3444 0.34695E-11 -11.4597 0.76683E+00 -0.1153 87 H2P2O7-2 0.31969E-18 -18.4953 0.28114E-18 -18.5511 0.87942E+00 -0.0558 88 HP2O7-3 0.14434E-16 -16.8406 0.11051E-16 -16.9566 0.76565E+00 -0.1160 89 P2O7-4 0.82793E-18 -18.0820 0.52265E-18 -18.2818 0.63127E+00 -0.1998 90 H2S,aq 0.34736E-14 -14.4592 0.34732E-14 -14.4593 0.99989E+00 0.0000 97 SO3-2 0.15344E-14 -14.8141 0.13500E-14 -14.8697 0.87982E+00 -0.0556 98 HSO3- 0.43136E-15 -15.3652 0.41213E-15 -15.3850 0.95541E+00 -0.0198 99 HSO4- 0.11350E-09 -9.9450 0.10845E-09 -9.9648 0.95550E+00 -0.0198 Charge balance for all species = 0.7204E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5458812E-08 -.2238864E-03 -.2256503E+00 0.0000 2 H2O 0.1000000E+01 0.5550831E+02 0.9999380E+06 0.0000 3 Cl- 0.1379639E-03 0.1379795E-03 0.4891489E+01 4.4026 4 SO4-- 0.2547636E-04 0.2550541E-04 0.2449941E+01 11.9156 5 HCO3- 0.1269136E-04 0.1307050E-04 0.7974770E+00 3.3663 6 HS- 0.2319428E-12 0.4450682E-10 0.1471840E-05 -4.3718 7 Al+++ 0.1117812E-21 0.6994398E-05 0.1887079E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4583311E-03 0.4405000E+02 -3.4168 9 Ca++ 0.2767794E-05 0.2831021E-05 0.1134547E+00 10.9515 10 Mg++ 0.1127793E-07 0.1208750E-07 0.2938535E-03 8.5615 11 Fe++ 0.6671105E-10 0.1255764E-08 0.7012640E-04 6.3335 12 K+ 0.3459377E-04 0.3460855E-04 0.1353181E+01 3.8018 13 Na+ 0.3642496E-03 0.3646898E-03 0.8383635E+01 4.8242 14 Mn++ 0.8870216E-08 0.1404817E-07 0.7717313E-03 8.4573 15 HPO4-- 0.2356385E-07 0.2555207E-07 0.2452313E-02 8.8817 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2685998E-02 -.2238777E-03 -.2462120E-02 0.0000000E+00 2 H2O 0.5550621E+02 0.5550617E+02 0.3648477E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3002176E-04 0.2550443E-04 0.4517330E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4517286E-05 0.4450511E-10 -.4517330E-05 0.0000000E+00 7 Al+++ 0.5315009E-03 0.6994129E-05 0.5245068E-03 0.0000000E+00 8 H4SiO4 0.1697284E-02 0.4583135E-03 0.1238970E-02 0.0000000E+00 9 Ca++ 0.2019443E-03 0.2830912E-05 0.1991134E-03 0.0000000E+00 10 Mg++ 0.1293651E-03 0.1208704E-07 0.1293530E-03 0.0000000E+00 11 Fe++ 0.1162204E-03 0.1255716E-08 0.1162191E-03 0.0000000E+00 12 K+ 0.3460722E-04 0.3460722E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3646757E-03 0.3646757E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2826191E-05 0.1404763E-07 0.2812144E-05 0.0000000E+00 15 HPO4-- 0.9645650E-06 0.2555109E-07 0.9390139E-06 0.0000000E+00 Chg. balance for solid moles: -.7899E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1630000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3130E-06 -6.504 0.1572E-03 -3.803 0.1051 0.4996E-04 clinochlore 0.2587E-04 -4.587 0.1438E-01 -1.842 9.615 0.5470E-02 daphnite 0.1602E-04 -4.795 0.1143E-01 -1.942 7.641 0.3463E-02 chlorite-Mn 0.5624E-06 -6.250 0.3987E-03 -3.399 0.2666 0.1271E-03 hematite 0.1807E-04 -4.743 0.2886E-02 -2.540 1.930 0.5469E-03 kaolinite 0.2226E-04 -4.653 0.5746E-02 -2.241 3.842 0.2211E-02 lawsonite 0.6315E-04 -4.200 0.1984E-01 -1.702 13.27 0.6399E-02 stilbite 0.1344E-03 -3.872 0.9472E-01 -1.024 63.33 0.4418E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1325E-01 0.1325E-01 1.0000 -1.878 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.149554 g Volume = 0.062443 cm3 Porosity: 94.1379% V(tot) - V(min): 0.10028E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1630000 g log = -0.7878 Original solution: 1000.0103000 g Original solution / Rock added: 6135.03 (Water/Rock Ratio), log = 3.7878 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1378E-04 1.0073 0.1460E-04 0.1449E-04 CH4,gas 0.1747E-15 1.0129 0.1861E-15 0.1837E-15 H2,gas 0.5758E-06 1.0006 0.6061E-06 0.6058E-06 H2S,gas 0.9669E-13 0.9959 0.1013E-12 0.1017E-12 S2,gas 0.9946E-33 1.0000 0.1046E-32 0.1046E-32 CO,gas 0.2179E-14 1.0000 0.2292E-14 0.2292E-14 SO3,gas 0.2167E-36 1.0000 0.2279E-36 0.2279E-36 SO2,gas 0.4968E-20 1.0000 0.5226E-20 0.5226E-20 HCl,gas 0.2171E-15 1.0000 0.2284E-15 0.2284E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 164 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.20 -6.84 -2.279 0.11672E+05 -4.836 3 CH4,gas 4.81 -12.92 -17.73 -4.433 0.30274E+05 -15.730 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -20.94 -14.99 -7.497 0.25603E+05 -12.994 6 S2,gas -7.03 -42.01 -34.98 -5.382 0.59728E+05 -32.980 7 CO,gas 3.51 -13.13 -16.64 -5.120 0.28412E+05 -14.640 8 SO3,gas 17.43 -21.21 -38.64 -9.661 0.65980E+05 -36.642 9 SO2,gas 1.14 -21.15 -22.28 -5.942 0.38046E+05 -20.282 10 HCl,gas 5.48 -12.16 -17.64 -8.821 0.30122E+05 -15.641 11 acmite 7.74 4.29 -3.45 -0.358 0.58875E+04 15 albite-high 0.75 -2.65 -3.40 -0.261 0.57980E+04 16 albite -0.33 -2.65 -2.32 -0.178 0.39574E+04 19 spessartine 24.55 20.68 -3.87 -0.193 0.66046E+04 20 analcite 3.37 0.77 -2.60 -0.289 0.44392E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 24 anhydrite -5.28 -10.26 -4.98 -2.492 0.85094E+04 26 annite 20.21 15.33 -4.88 -0.271 0.83276E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.25 -3.23 -1.078 0.55213E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.25 -3.08 -1.027 0.52600E+04 38 carnegieite-low 9.06 4.19 -4.88 -0.697 0.83272E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29411E+04 42 celadonite 5.40 1.48 -3.92 -0.231 0.67005E+04 43 celadonite-Fe 3.94 -0.75 -4.69 -0.276 0.80058E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13001E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14722E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82449E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68765E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.77 -3.48 -0.348 0.59422E+04 97 kalsilite 7.62 3.17 -4.45 -0.636 0.76068E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.25 -4.42 -0.442 0.75457E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75751E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.67 -1.24 -0.095 0.21115E+04 120 muscovite 2.68 1.89 -0.79 -0.046 0.13439E+04 121 paragonite 4.34 2.91 -1.42 -0.084 0.24282E+04 122 nepheline 8.38 4.19 -4.19 -0.599 0.71551E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50040E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.475 0.40563E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.74 -3.78 -1.261 0.64595E+04 153 rhodonite 7.46 5.04 -2.42 -0.484 0.41355E+04 154 sanidine -1.22 -3.67 -2.45 -0.188 0.41793E+04 156 siderite -2.59 -6.87 -4.28 -1.426 0.73041E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.79 -1.38 -0.041 0.23648E+04 166 stilpnomelane-Mg 27.60 22.93 -4.66 -0.139 0.79599E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83656E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 175 tephroite 18.11 13.50 -4.62 -0.659 0.78803E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.81 -3.37 -0.207 0.57579E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.47 -3.21 -0.197 0.54857E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 203 montmorillonite-K -2.16 -4.94 -2.78 -0.170 0.47526E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.61 -2.65 -0.162 0.45187E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.23 -1.17 -0.075 0.20044E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.57 -1.02 -0.065 0.17340E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.18 -2.26 -0.174 0.38595E+04 244 an25ab75 2.71 0.44 -2.27 -0.175 0.38830E+04 245 an30ab70 3.34 1.05 -2.29 -0.176 0.39147E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1630000 g New total amount of reactant added: 0.1670000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1670000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3669338E-03 Osmotic coef. = 0.9886 True ionic strength = .4384304E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.53149E-08 -8.2745 0.50780E-08 -8.2943 0.95544E+00 -0.0198 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13179E-03 -3.8801 0.95525E+00 -0.0199 4 SO4-- 0.25477E-04 -4.5939 0.22391E-04 -4.6499 0.87889E+00 -0.0561 5 HCO3- 0.12688E-04 -4.8966 0.12121E-04 -4.9165 0.95530E+00 -0.0199 6 HS- 0.22567E-12 -12.6465 0.21557E-12 -12.6664 0.95526E+00 -0.0199 7 Al+++ 0.10327E-21 -21.9860 0.78952E-22 -22.1026 0.76448E+00 -0.1166 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.26247E-05 -5.5809 0.23063E-05 -5.6371 0.87869E+00 -0.0562 10 Mg++ 0.10695E-07 -7.9708 0.93959E-08 -8.0271 0.87856E+00 -0.0562 11 Fe++ 0.63261E-10 -10.1989 0.55580E-10 -10.2551 0.87859E+00 -0.0562 12 K+ 0.35443E-04 -4.4505 0.33859E-04 -4.4703 0.95531E+00 -0.0199 13 Na+ 0.36925E-03 -3.4327 0.35273E-03 -3.4526 0.95525E+00 -0.0199 14 Mn++ 0.84141E-08 -8.0750 0.73928E-08 -8.1312 0.87861E+00 -0.0562 15 HPO4-- 0.24882E-07 -7.6041 0.21869E-07 -7.6602 0.87889E+00 -0.0561 16 HSiO3- 0.77027E-04 -4.1134 0.73580E-04 -4.1332 0.95525E+00 -0.0199 17 Ca(HSiO3)+ 0.39799E-08 -8.4001 0.38020E-08 -8.4200 0.95531E+00 -0.0199 18 Mg(HSiO3)+ 0.20179E-10 -10.6951 0.19277E-10 -10.7150 0.95531E+00 -0.0199 19 NaHSiO3,aq 0.41221E-06 -6.3849 0.41221E-06 -6.3849 0.10000E+01 0.0000 20 AlO+ 0.41375E-12 -12.3833 0.39526E-12 -12.4031 0.95531E+00 -0.0199 21 AlOH+2 0.11443E-16 -16.9414 0.10055E-16 -16.9976 0.87864E+00 -0.0562 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.71702E-05 -5.1445 0.68490E-05 -5.1644 0.95520E+00 -0.0199 24 CH4,aq 0.11452E-18 -18.9411 0.11451E-18 -18.9412 0.99989E+00 0.0000 29 CO,aq 0.14124E-17 -17.8500 0.14124E-17 -17.8500 0.10000E+01 0.0000 30 CO2,aq 0.12411E-06 -6.9062 0.12410E-06 -6.9062 0.99989E+00 0.0000 31 CO3-2 0.25113E-06 -6.6001 0.22070E-06 -6.6562 0.87883E+00 -0.0561 32 CaCO3,aq 0.62338E-08 -8.2052 0.62338E-08 -8.2052 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.73732E-09 -9.1323 0.70437E-09 -9.1522 0.95531E+00 -0.0199 34 CaCl+ 0.50699E-09 -9.2950 0.48433E-09 -9.3149 0.95531E+00 -0.0199 35 CaCl2,aq 0.14862E-13 -13.8279 0.14862E-13 -13.8279 0.10000E+01 0.0000 36 CaOH+ 0.33522E-07 -7.4747 0.32024E-07 -7.4945 0.95531E+00 -0.0199 37 CaSO4,aq 0.16090E-07 -7.7934 0.16090E-07 -7.7934 0.10000E+01 0.0000 38 HCl,aq 0.12588E-12 -12.9000 0.12588E-12 -12.9000 0.10000E+01 0.0000 43 FeCl+ 0.11942E-13 -13.9229 0.11409E-13 -13.9428 0.95531E+00 -0.0199 46 FeO,aq 0.85234E-10 -10.0694 0.85234E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.37983E-09 -9.4204 0.36286E-09 -9.4403 0.95531E+00 -0.0199 48 HFeO2- 0.18899E-09 -9.7236 0.18054E-09 -9.7434 0.95525E+00 -0.0199 49 FeO+ 0.43971E-13 -13.3568 0.42006E-13 -13.3767 0.95531E+00 -0.0199 50 FeOH+2 0.45175E-19 -19.3451 0.39693E-19 -19.4013 0.87864E+00 -0.0562 51 FeO2- 0.33516E-09 -9.4747 0.32017E-09 -9.4946 0.95525E+00 -0.0199 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44194E-09 -9.3546 0.44189E-09 -9.3547 0.99989E+00 0.0000 54 KCl,aq 0.79011E-10 -10.1023 0.79011E-10 -10.1023 0.10000E+01 0.0000 55 KHSO4,aq 0.10302E-16 -16.9871 0.10302E-16 -16.9871 0.10000E+01 0.0000 56 KOH,aq 0.29067E-08 -8.5366 0.29067E-08 -8.5366 0.10000E+01 0.0000 57 KSO4- 0.12227E-07 -7.9127 0.11680E-07 -7.9325 0.95525E+00 -0.0199 58 MgCO3,aq 0.63463E-11 -11.1975 0.63463E-11 -11.1975 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.30632E-11 -11.5138 0.29263E-11 -11.5337 0.95531E+00 -0.0199 60 MgCl+ 0.18751E-11 -11.7270 0.17913E-11 -11.7468 0.95531E+00 -0.0199 61 MgOH+ 0.75663E-09 -9.1211 0.72281E-09 -9.1410 0.95531E+00 -0.0199 63 MnO,aq 0.30264E-09 -9.5191 0.30264E-09 -9.5191 0.10000E+01 0.0000 64 MnOH+ 0.46933E-08 -8.3285 0.44836E-08 -8.3484 0.95531E+00 -0.0199 65 MnO2-2 0.46185E-15 -15.3355 0.40589E-15 -15.3916 0.87883E+00 -0.0561 66 HMnO2- 0.46749E-12 -12.3302 0.44657E-12 -12.3501 0.95525E+00 -0.0199 69 MnCl+ 0.61725E-11 -11.2095 0.58967E-11 -11.2294 0.95531E+00 -0.0199 70 MnSO4,aq 0.46913E-10 -10.3287 0.46913E-10 -10.3287 0.10000E+01 0.0000 71 NaCl,aq 0.15179E-07 -7.8188 0.15179E-07 -7.8188 0.10000E+01 0.0000 72 NaOH,aq 0.30522E-07 -7.5154 0.30522E-07 -7.5154 0.10000E+01 0.0000 74 OH- 0.12366E-03 -3.9078 0.11812E-03 -3.9277 0.95520E+00 -0.0199 79 HPO3-2 0.34732E-19 -19.4593 0.30523E-19 -19.5154 0.87883E+00 -0.0561 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.20381E-08 -8.6908 0.19470E-08 -8.7106 0.95528E+00 -0.0199 84 PO4-3 0.49119E-11 -11.3088 0.37610E-11 -11.4247 0.76569E+00 -0.1159 87 H2P2O7-2 0.33758E-18 -18.4716 0.29667E-18 -18.5277 0.87883E+00 -0.0561 88 HP2O7-3 0.15670E-16 -16.8049 0.11980E-16 -16.9216 0.76449E+00 -0.1166 89 P2O7-4 0.92440E-18 -18.0341 0.58199E-18 -18.2351 0.62959E+00 -0.2009 90 H2S,aq 0.32894E-14 -14.4829 0.32890E-14 -14.4829 0.99989E+00 0.0000 97 SO3-2 0.15344E-14 -14.8141 0.13491E-14 -14.8699 0.87924E+00 -0.0559 98 HSO3- 0.41971E-15 -15.3771 0.40093E-15 -15.3969 0.95525E+00 -0.0199 99 HSO4- 0.11043E-09 -9.9569 0.10550E-09 -9.9767 0.95534E+00 -0.0198 Charge balance for all species = 0.7204E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5314883E-08 -.2300354E-03 -.2318477E+00 0.0000 2 H2O 0.1000000E+01 0.5550831E+02 0.9999377E+06 0.0000 3 Cl- 0.1379638E-03 0.1379796E-03 0.4891491E+01 4.4142 4 SO4-- 0.2547700E-04 0.2550543E-04 0.2449942E+01 11.9387 5 HCO3- 0.1268829E-04 0.1307051E-04 0.7974773E+00 3.3778 6 HS- 0.2256680E-12 0.4338058E-10 0.1434595E-05 -4.3721 7 Al+++ 0.1032749E-21 0.7185790E-05 0.1938715E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4604033E-03 0.4424914E+02 -3.4168 9 Ca++ 0.2624655E-05 0.2685726E-05 0.1076319E+00 10.9515 10 Mg++ 0.1069468E-07 0.1148277E-07 0.2791521E-03 8.5615 11 Fe++ 0.6326061E-10 0.1256012E-08 0.7014021E-04 6.3335 12 K+ 0.3544266E-04 0.3545787E-04 0.1386389E+01 3.8240 13 Na+ 0.3692533E-03 0.3697112E-03 0.8499067E+01 4.8417 14 Mn++ 0.8414135E-08 0.1346367E-07 0.7396219E-03 8.4574 15 HPO4-- 0.2488226E-07 0.2692526E-07 0.2584102E-02 8.9284 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2752232E-02 -.2300264E-03 -.2522206E-02 0.0000000E+00 2 H2O 0.5550616E+02 0.5550613E+02 0.2803815E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3013261E-04 0.2550443E-04 0.4628183E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4628139E-05 0.4337888E-10 -.4628183E-05 0.0000000E+00 7 Al+++ 0.5445438E-03 0.7185508E-05 0.5373583E-03 0.0000000E+00 8 H4SiO4 0.1738935E-02 0.4603852E-03 0.1278550E-02 0.0000000E+00 9 Ca++ 0.2065449E-03 0.2685620E-05 0.2038593E-03 0.0000000E+00 10 Mg++ 0.1325397E-03 0.1148232E-07 0.1325282E-03 0.0000000E+00 11 Fe++ 0.1190724E-03 0.1255963E-08 0.1190712E-03 0.0000000E+00 12 K+ 0.3545648E-04 0.3545648E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3696967E-03 0.3696967E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2895546E-05 0.1346314E-07 0.2882082E-05 0.0000000E+00 15 HPO4-- 0.9882353E-06 0.2692420E-07 0.9613111E-06 0.0000000E+00 Chg. balance for solid moles: -.2363E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1670000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3204E-06 -6.494 0.1610E-03 -3.793 0.1046 0.5115E-04 clinochlore 0.2651E-04 -4.577 0.1473E-01 -1.832 9.571 0.5604E-02 daphnite 0.1641E-04 -4.785 0.1171E-01 -1.932 7.606 0.3548E-02 chlorite-Mn 0.5764E-06 -6.239 0.4087E-03 -3.389 0.2655 0.1302E-03 hematite 0.1851E-04 -4.733 0.2956E-02 -2.529 1.921 0.5604E-03 kaolinite 0.2293E-04 -4.640 0.5920E-02 -2.228 3.846 0.2278E-02 lawsonite 0.6272E-04 -4.203 0.1971E-01 -1.705 12.80 0.6355E-02 stilbite 0.1395E-03 -3.855 0.9834E-01 -1.007 63.88 0.4587E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1325E-01 0.1325E-01 1.0000 -1.878 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.153932 g Volume = 0.064393 cm3 Porosity: 93.9639% V(tot) - V(min): 0.10024E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1670000 g log = -0.7773 Original solution: 1000.0103000 g Original solution / Rock added: 5988.09 (Water/Rock Ratio), log = 3.7773 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1341E-04 1.0073 0.1421E-04 0.1410E-04 CH4,gas 0.1699E-15 1.0129 0.1811E-15 0.1788E-15 H2,gas 0.5758E-06 1.0006 0.6061E-06 0.6058E-06 H2S,gas 0.9156E-13 0.9959 0.9593E-13 0.9632E-13 S2,gas 0.8919E-33 1.0000 0.9382E-33 0.9382E-33 CO,gas 0.2120E-14 1.0000 0.2230E-14 0.2230E-14 SO3,gas 0.2052E-36 1.0000 0.2159E-36 0.2159E-36 SO2,gas 0.4705E-20 1.0000 0.4949E-20 0.4949E-20 HCl,gas 0.2113E-15 1.0000 0.2223E-15 0.2223E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.54595E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 164 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.21 -6.85 -2.283 0.11692E+05 -4.848 3 CH4,gas 4.81 -12.93 -17.74 -4.436 0.30294E+05 -15.742 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -20.96 -15.02 -7.509 0.25643E+05 -13.018 6 S2,gas -7.03 -42.06 -35.03 -5.389 0.59809E+05 -33.028 7 CO,gas 3.51 -13.14 -16.65 -5.124 0.28432E+05 -14.652 8 SO3,gas 17.43 -21.24 -38.67 -9.666 0.66021E+05 -36.666 9 SO2,gas 1.14 -21.17 -22.31 -5.948 0.38086E+05 -20.305 10 HCl,gas 5.48 -12.17 -17.65 -8.827 0.30142E+05 -15.653 11 acmite 7.74 4.31 -3.43 -0.356 0.58575E+04 15 albite-high 0.75 -2.63 -3.38 -0.260 0.57681E+04 16 albite -0.33 -2.63 -2.30 -0.177 0.39275E+04 19 spessartine 24.55 20.68 -3.87 -0.193 0.66039E+04 20 analcite 3.37 0.79 -2.58 -0.287 0.44092E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.35 -4.86 -0.270 0.82898E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.26 -3.25 -1.082 0.55415E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.26 -3.09 -1.031 0.52802E+04 38 carnegieite-low 9.06 4.21 -4.86 -0.694 0.82973E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29411E+04 42 celadonite 5.40 1.50 -3.90 -0.230 0.66627E+04 43 celadonite-Fe 3.94 -0.73 -4.67 -0.275 0.79680E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13001E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14720E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82450E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68765E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.79 -3.46 -0.346 0.59123E+04 97 kalsilite 7.62 3.19 -4.43 -0.633 0.75690E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.23 -4.40 -0.440 0.75079E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75751E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.65 -1.21 -0.093 0.20737E+04 120 muscovite 2.68 1.91 -0.76 -0.045 0.13061E+04 121 paragonite 4.34 2.93 -1.40 -0.083 0.23983E+04 122 nepheline 8.38 4.21 -4.17 -0.596 0.71252E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50040E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.475 0.40560E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.75 -3.79 -1.265 0.64795E+04 153 rhodonite 7.46 5.04 -2.42 -0.484 0.41353E+04 154 sanidine -1.22 -3.65 -2.43 -0.187 0.41415E+04 156 siderite -2.59 -6.88 -4.29 -1.430 0.73243E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.81 -1.37 -0.041 0.23460E+04 166 stilpnomelane-Mg 27.60 22.95 -4.65 -0.139 0.79410E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83656E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 175 tephroite 18.11 13.50 -4.61 -0.659 0.78798E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.80 -3.36 -0.206 0.57454E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.46 -3.21 -0.196 0.54758E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 203 montmorillonite-K -2.16 -4.94 -2.78 -0.170 0.47402E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.60 -2.64 -0.162 0.45088E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.24 -1.17 -0.075 0.19920E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.57 -1.01 -0.065 0.17241E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.17 -2.25 -0.173 0.38356E+04 244 an25ab75 2.71 0.45 -2.26 -0.174 0.38605E+04 245 an30ab70 3.34 1.06 -2.28 -0.175 0.38938E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1670000 g New total amount of reactant added: 0.1710000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1710000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3704651E-03 Osmotic coef. = 0.9886 True ionic strength = .4438891E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.51779E-08 -8.2858 0.49464E-08 -8.3057 0.95528E+00 -0.0199 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13177E-03 -3.8802 0.95509E+00 -0.0200 4 SO4-- 0.25478E-04 -4.5938 0.22377E-04 -4.6502 0.87830E+00 -0.0564 5 HCO3- 0.12685E-04 -4.8967 0.12116E-04 -4.9166 0.95514E+00 -0.0199 6 HS- 0.21970E-12 -12.6582 0.20983E-12 -12.6781 0.95510E+00 -0.0200 7 Al+++ 0.95592E-22 -22.0196 0.72968E-22 -22.1369 0.76333E+00 -0.1173 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.24920E-05 -5.6035 0.21882E-05 -5.6599 0.87810E+00 -0.0565 10 Mg++ 0.10154E-07 -7.9934 0.89150E-08 -8.0499 0.87797E+00 -0.0565 11 Fe++ 0.60062E-10 -10.2214 0.52735E-10 -10.2779 0.87800E+00 -0.0565 12 K+ 0.36292E-04 -4.4402 0.34664E-04 -4.4601 0.95515E+00 -0.0199 13 Na+ 0.37426E-03 -3.4268 0.35745E-03 -3.4468 0.95509E+00 -0.0200 14 Mn++ 0.79911E-08 -8.0974 0.70164E-08 -8.1539 0.87802E+00 -0.0565 15 HPO4-- 0.26242E-07 -7.5810 0.23049E-07 -7.6374 0.87831E+00 -0.0564 16 HSiO3- 0.79090E-04 -4.1019 0.75539E-04 -4.1218 0.95509E+00 -0.0200 17 Ca(HSiO3)+ 0.38773E-08 -8.4115 0.37035E-08 -8.4314 0.95515E+00 -0.0199 18 Mg(HSiO3)+ 0.19659E-10 -10.7064 0.18778E-10 -10.7264 0.95515E+00 -0.0199 19 NaHSiO3,aq 0.42884E-06 -6.3677 0.42884E-06 -6.3677 0.10000E+01 0.0000 20 AlO+ 0.40309E-12 -12.3946 0.38501E-12 -12.4145 0.95515E+00 -0.0199 21 AlOH+2 0.10865E-16 -16.9640 0.95399E-17 -17.0205 0.87805E+00 -0.0565 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.73623E-05 -5.1330 0.70313E-05 -5.1530 0.95504E+00 -0.0200 24 CH4,aq 0.11150E-18 -18.9527 0.11148E-18 -18.9528 0.99989E+00 0.0000 29 CO,aq 0.13752E-17 -17.8616 0.13752E-17 -17.8616 0.10000E+01 0.0000 30 CO2,aq 0.12084E-06 -6.9178 0.12083E-06 -6.9178 0.99989E+00 0.0000 31 CO3-2 0.25787E-06 -6.5886 0.22648E-06 -6.6450 0.87824E+00 -0.0564 32 CaCO3,aq 0.60696E-08 -8.2168 0.60696E-08 -8.2168 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.69939E-09 -9.1553 0.66803E-09 -9.1752 0.95515E+00 -0.0199 34 CaCl+ 0.48103E-09 -9.3178 0.45946E-09 -9.3378 0.95515E+00 -0.0199 35 CaCl2,aq 0.14096E-13 -13.8509 0.14096E-13 -13.8509 0.10000E+01 0.0000 36 CaOH+ 0.32659E-07 -7.4860 0.31194E-07 -7.5059 0.95515E+00 -0.0199 37 CaSO4,aq 0.15257E-07 -7.8165 0.15257E-07 -7.8165 0.10000E+01 0.0000 38 HCl,aq 0.12260E-12 -12.9115 0.12260E-12 -12.9115 0.10000E+01 0.0000 43 FeCl+ 0.11331E-13 -13.9457 0.10823E-13 -13.9657 0.95515E+00 -0.0199 46 FeO,aq 0.85233E-10 -10.0694 0.85233E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.37004E-09 -9.4317 0.35345E-09 -9.4517 0.95515E+00 -0.0199 48 HFeO2- 0.19406E-09 -9.7121 0.18534E-09 -9.7320 0.95509E+00 -0.0200 49 FeO+ 0.42838E-13 -13.3682 0.40917E-13 -13.3881 0.95515E+00 -0.0199 50 FeOH+2 0.42891E-19 -19.3676 0.37661E-19 -19.4241 0.87805E+00 -0.0565 51 FeO2- 0.34414E-09 -9.4633 0.32869E-09 -9.4832 0.95509E+00 -0.0200 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44194E-09 -9.3546 0.44189E-09 -9.3547 0.99989E+00 0.0000 54 KCl,aq 0.80876E-10 -10.0922 0.80876E-10 -10.0922 0.10000E+01 0.0000 55 KHSO4,aq 0.10267E-16 -16.9886 0.10267E-16 -16.9886 0.10000E+01 0.0000 56 KOH,aq 0.30551E-08 -8.5150 0.30551E-08 -8.5150 0.10000E+01 0.0000 57 KSO4- 0.12512E-07 -7.9027 0.11950E-07 -7.9226 0.95509E+00 -0.0200 58 MgCO3,aq 0.61791E-11 -11.2091 0.61791E-11 -11.2091 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.29056E-11 -11.5368 0.27753E-11 -11.5567 0.95515E+00 -0.0199 60 MgCl+ 0.17791E-11 -11.7498 0.16993E-11 -11.7697 0.95515E+00 -0.0199 61 MgOH+ 0.73713E-09 -9.1325 0.70407E-09 -9.1524 0.95515E+00 -0.0199 63 MnO,aq 0.30273E-09 -9.5189 0.30273E-09 -9.5189 0.10000E+01 0.0000 64 MnOH+ 0.45737E-08 -8.3397 0.43686E-08 -8.3597 0.95515E+00 -0.0199 65 MnO2-2 0.48723E-15 -15.3123 0.42791E-15 -15.3686 0.87824E+00 -0.0564 66 HMnO2- 0.48015E-12 -12.3186 0.45859E-12 -12.3386 0.95509E+00 -0.0200 69 MnCl+ 0.58582E-11 -11.2322 0.55955E-11 -11.2522 0.95515E+00 -0.0199 70 MnSO4,aq 0.44496E-10 -10.3517 0.44496E-10 -10.3517 0.10000E+01 0.0000 71 NaCl,aq 0.15379E-07 -7.8131 0.15379E-07 -7.8131 0.10000E+01 0.0000 72 NaOH,aq 0.31754E-07 -7.4982 0.31754E-07 -7.4982 0.10000E+01 0.0000 74 OH- 0.12698E-03 -3.8963 0.12127E-03 -3.9163 0.95504E+00 -0.0200 79 HPO3-2 0.36629E-19 -19.4362 0.32169E-19 -19.4926 0.87824E+00 -0.0564 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.20927E-08 -8.6793 0.19988E-08 -8.6992 0.95512E+00 -0.0199 84 PO4-3 0.53226E-11 -11.2739 0.40694E-11 -11.3905 0.76455E+00 -0.1166 87 H2P2O7-2 0.35603E-18 -18.4485 0.31268E-18 -18.5049 0.87824E+00 -0.0564 88 HP2O7-3 0.16981E-16 -16.7700 0.12962E-16 -16.8873 0.76334E+00 -0.1173 89 P2O7-4 0.10296E-17 -17.9873 0.64648E-18 -18.1894 0.62791E+00 -0.2021 90 H2S,aq 0.31188E-14 -14.5060 0.31185E-14 -14.5061 0.99989E+00 0.0000 97 SO3-2 0.15344E-14 -14.8141 0.13482E-14 -14.8702 0.87866E+00 -0.0562 98 HSO3- 0.40862E-15 -15.3887 0.39027E-15 -15.4086 0.95509E+00 -0.0200 99 HSO4- 0.10752E-09 -9.9685 0.10270E-09 -9.9884 0.95518E+00 -0.0199 Charge balance for all species = 0.7204E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5177929E-08 -.2362080E-03 -.2380688E+00 0.0000 2 H2O 0.1000000E+01 0.5550831E+02 0.9999373E+06 0.0000 3 Cl- 0.1379638E-03 0.1379797E-03 0.4891493E+01 4.4255 4 SO4-- 0.2547757E-04 0.2550545E-04 0.2449943E+01 11.9612 5 HCO3- 0.1268503E-04 0.1307052E-04 0.7974777E+00 3.3891 6 HS- 0.2196987E-12 0.4225058E-10 0.1397225E-05 -4.3724 7 Al+++ 0.9559179E-22 0.7377907E-05 0.1990547E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4624836E-03 0.4444906E+02 -3.4168 9 Ca++ 0.2491977E-05 0.2551020E-05 0.1022335E+00 10.9515 10 Mg++ 0.1015406E-07 0.1092171E-07 0.2655123E-03 8.5615 11 Fe++ 0.6006239E-10 0.1257064E-08 0.7019893E-04 6.3335 12 K+ 0.3629154E-04 0.3630719E-04 0.1419596E+01 3.8456 13 Na+ 0.3742567E-03 0.3747327E-03 0.8614499E+01 4.8589 14 Mn++ 0.7991090E-08 0.1291837E-07 0.7096658E-03 8.4575 15 HPO4-- 0.2624215E-07 0.2834018E-07 0.2719894E-02 8.9741 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2818466E-02 -.2361985E-03 -.2582268E-02 0.0000000E+00 2 H2O 0.5550611E+02 0.5550609E+02 0.1958793E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3024346E-04 0.2550443E-04 0.4739035E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4738993E-05 0.4224889E-10 -.4739035E-05 0.0000000E+00 7 Al+++ 0.5575868E-03 0.7377611E-05 0.5502092E-03 0.0000000E+00 8 H4SiO4 0.1780586E-02 0.4624651E-03 0.1318121E-02 0.0000000E+00 9 Ca++ 0.2111455E-03 0.2550918E-05 0.2085945E-03 0.0000000E+00 10 Mg++ 0.1357143E-03 0.1092127E-07 0.1357034E-03 0.0000000E+00 11 Fe++ 0.1219245E-03 0.1257014E-08 0.1219232E-03 0.0000000E+00 12 K+ 0.3630573E-04 0.3630573E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3747177E-03 0.3747177E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2964900E-05 0.1291785E-07 0.2951982E-05 0.0000000E+00 15 HPO4-- 0.1011906E-05 0.2833904E-07 0.9835666E-06 0.0000000E+00 Chg. balance for solid moles: -.4252E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1710000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3279E-06 -6.484 0.1647E-03 -3.783 0.1040 0.5233E-04 clinochlore 0.2714E-04 -4.566 0.1509E-01 -1.821 9.529 0.5738E-02 daphnite 0.1680E-04 -4.775 0.1199E-01 -1.921 7.573 0.3633E-02 chlorite-Mn 0.5904E-06 -6.229 0.4186E-03 -3.378 0.2644 0.1334E-03 hematite 0.1896E-04 -4.722 0.3027E-02 -2.519 1.912 0.5738E-03 kaolinite 0.2362E-04 -4.627 0.6097E-02 -2.215 3.851 0.2346E-02 lawsonite 0.6228E-04 -4.206 0.1957E-01 -1.708 12.36 0.6311E-02 stilbite 0.1447E-03 -3.840 0.1020 -0.992 64.40 0.4755E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1326E-01 0.1326E-01 1.0000 -1.878 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.158308 g Volume = 0.066341 cm3 Porosity: 93.7906% V(tot) - V(min): 0.10021E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1710000 g log = -0.7670 Original solution: 1000.0103000 g Original solution / Rock added: 5848.01 (Water/Rock Ratio), log = 3.7670 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1305E-04 1.0073 0.1383E-04 0.1373E-04 CH4,gas 0.1655E-15 1.0129 0.1763E-15 0.1741E-15 H2,gas 0.5758E-06 1.0006 0.6061E-06 0.6057E-06 H2S,gas 0.8682E-13 0.9959 0.9095E-13 0.9133E-13 S2,gas 0.8018E-33 1.0000 0.8435E-33 0.8435E-33 CO,gas 0.2064E-14 1.0000 0.2171E-14 0.2171E-14 SO3,gas 0.1946E-36 1.0000 0.2047E-36 0.2047E-36 SO2,gas 0.4461E-20 1.0000 0.4693E-20 0.4693E-20 HCl,gas 0.2058E-15 1.0000 0.2165E-15 0.2165E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 164 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.22 -6.86 -2.286 0.11712E+05 -4.859 3 CH4,gas 4.81 -12.94 -17.75 -4.438 0.30314E+05 -15.754 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -20.98 -15.04 -7.521 0.25682E+05 -13.041 6 S2,gas -7.03 -42.11 -35.07 -5.396 0.59888E+05 -33.074 7 CO,gas 3.51 -13.15 -16.66 -5.127 0.28452E+05 -14.663 8 SO3,gas 17.43 -21.26 -38.69 -9.672 0.66060E+05 -36.689 9 SO2,gas 1.14 -21.19 -22.33 -5.954 0.38125E+05 -20.329 10 HCl,gas 5.48 -12.19 -17.66 -8.832 0.30162E+05 -15.665 11 acmite 7.74 4.32 -3.41 -0.355 0.58282E+04 15 albite-high 0.75 -2.61 -3.36 -0.259 0.57388E+04 16 albite -0.33 -2.61 -2.28 -0.176 0.38981E+04 19 spessartine 24.55 20.68 -3.87 -0.193 0.66032E+04 20 analcite 3.37 0.81 -2.57 -0.285 0.43799E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.38 -4.83 -0.269 0.82529E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.27 -3.26 -1.086 0.55613E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.27 -3.10 -1.035 0.53000E+04 38 carnegieite-low 9.06 4.22 -4.84 -0.692 0.82679E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29411E+04 42 celadonite 5.40 1.52 -3.88 -0.228 0.66258E+04 43 celadonite-Fe 3.94 -0.71 -4.64 -0.273 0.79311E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13001E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14718E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82450E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68765E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.81 -3.45 -0.345 0.58829E+04 97 kalsilite 7.62 3.21 -4.41 -0.630 0.75321E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.21 -4.38 -0.438 0.74710E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.62 -1.19 -0.092 0.20368E+04 120 muscovite 2.68 1.94 -0.74 -0.044 0.12692E+04 121 paragonite 4.34 2.95 -1.39 -0.082 0.23690E+04 122 nepheline 8.38 4.22 -4.16 -0.594 0.70959E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50040E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.475 0.40558E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.76 -3.81 -1.269 0.64991E+04 153 rhodonite 7.46 5.04 -2.42 -0.484 0.41351E+04 154 sanidine -1.22 -3.62 -2.40 -0.185 0.41046E+04 156 siderite -2.59 -6.89 -4.30 -1.434 0.73441E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.82 -1.36 -0.041 0.23275E+04 166 stilpnomelane-Mg 27.60 22.96 -4.64 -0.139 0.79226E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83656E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 175 tephroite 18.11 13.50 -4.61 -0.659 0.78794E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.79 -3.36 -0.206 0.57332E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.46 -3.20 -0.196 0.54662E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 203 montmorillonite-K -2.16 -4.93 -2.77 -0.170 0.47280E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.60 -2.63 -0.161 0.44991E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.24 -1.16 -0.074 0.19798E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.58 -1.00 -0.064 0.17145E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.15 -2.23 -0.172 0.38121E+04 244 an25ab75 2.71 0.46 -2.25 -0.173 0.38385E+04 245 an30ab70 3.34 1.08 -2.27 -0.174 0.38733E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1710000 g New total amount of reactant added: 0.1750000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1750000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3740187E-03 Osmotic coef. = 0.9885 True ionic strength = .4493763E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.50475E-08 -8.2969 0.48210E-08 -8.3169 0.95512E+00 -0.0199 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13175E-03 -3.8803 0.95493E+00 -0.0200 4 SO4-- 0.25478E-04 -4.5938 0.22363E-04 -4.6505 0.87772E+00 -0.0566 5 HCO3- 0.12682E-04 -4.8968 0.12111E-04 -4.9168 0.95498E+00 -0.0200 6 HS- 0.21402E-12 -12.6696 0.20437E-12 -12.6896 0.95494E+00 -0.0200 7 Al+++ 0.88638E-22 -22.0524 0.67558E-22 -22.1703 0.76218E+00 -0.1179 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.23688E-05 -5.6255 0.20787E-05 -5.6822 0.87751E+00 -0.0567 10 Mg++ 0.96522E-08 -8.0154 0.84687E-08 -8.0722 0.87738E+00 -0.0568 11 Fe++ 0.57094E-10 -10.2434 0.50095E-10 -10.3002 0.87741E+00 -0.0568 12 K+ 0.37140E-04 -4.4302 0.35469E-04 -4.4502 0.95499E+00 -0.0200 13 Na+ 0.37926E-03 -3.4211 0.36217E-03 -3.4411 0.95493E+00 -0.0200 14 Mn++ 0.75981E-08 -8.1193 0.66669E-08 -8.1761 0.87743E+00 -0.0568 15 HPO4-- 0.27643E-07 -7.5584 0.24263E-07 -7.6151 0.87772E+00 -0.0566 16 HSiO3- 0.81161E-04 -4.0907 0.77503E-04 -4.1107 0.95493E+00 -0.0200 17 Ca(HSiO3)+ 0.37797E-08 -8.4225 0.36096E-08 -8.4425 0.95499E+00 -0.0200 18 Mg(HSiO3)+ 0.19164E-10 -10.7175 0.18301E-10 -10.7375 0.95499E+00 -0.0200 19 NaHSiO3,aq 0.44581E-06 -6.3509 0.44581E-06 -6.3509 0.10000E+01 0.0000 20 AlO+ 0.39294E-12 -12.4057 0.37525E-12 -12.4257 0.95499E+00 -0.0200 21 AlOH+2 0.10328E-16 -16.9860 0.90623E-17 -17.0428 0.87746E+00 -0.0568 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.75551E-05 -5.1218 0.72142E-05 -5.1418 0.95488E+00 -0.0201 24 CH4,aq 0.10862E-18 -18.9641 0.10860E-18 -18.9642 0.99988E+00 -0.0001 29 CO,aq 0.13397E-17 -17.8730 0.13397E-17 -17.8730 0.10000E+01 0.0000 30 CO2,aq 0.11773E-06 -6.9291 0.11772E-06 -6.9292 0.99988E+00 -0.0001 31 CO3-2 0.26464E-06 -6.5773 0.23226E-06 -6.6340 0.87766E+00 -0.0567 32 CaCO3,aq 0.59131E-08 -8.2282 0.59131E-08 -8.2282 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.66420E-09 -9.1777 0.63431E-09 -9.1977 0.95499E+00 -0.0200 34 CaCl+ 0.45695E-09 -9.3401 0.43639E-09 -9.3601 0.95499E+00 -0.0200 35 CaCl2,aq 0.13386E-13 -13.8733 0.13386E-13 -13.8733 0.10000E+01 0.0000 36 CaOH+ 0.31836E-07 -7.4971 0.30403E-07 -7.5171 0.95499E+00 -0.0200 37 CaSO4,aq 0.14483E-07 -7.8391 0.14483E-07 -7.8391 0.10000E+01 0.0000 38 HCl,aq 0.11947E-12 -12.9227 0.11947E-12 -12.9227 0.10000E+01 0.0000 43 FeCl+ 0.10764E-13 -13.9680 0.10279E-13 -13.9880 0.95499E+00 -0.0200 46 FeO,aq 0.85232E-10 -10.0694 0.85232E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.36072E-09 -9.4428 0.34449E-09 -9.4628 0.95499E+00 -0.0200 48 HFeO2- 0.19914E-09 -9.7009 0.19016E-09 -9.7209 0.95493E+00 -0.0200 49 FeO+ 0.41759E-13 -13.3792 0.39880E-13 -13.3992 0.95499E+00 -0.0200 50 FeOH+2 0.40772E-19 -19.3896 0.35776E-19 -19.4464 0.87746E+00 -0.0568 51 FeO2- 0.35315E-09 -9.4520 0.33724E-09 -9.4721 0.95493E+00 -0.0200 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44193E-09 -9.3546 0.44188E-09 -9.3547 0.99988E+00 -0.0001 54 KCl,aq 0.82740E-10 -10.0823 0.82740E-10 -10.0823 0.10000E+01 0.0000 55 KHSO4,aq 0.10232E-16 -16.9900 0.10232E-16 -16.9900 0.10000E+01 0.0000 56 KOH,aq 0.32073E-08 -8.4939 0.32073E-08 -8.4939 0.10000E+01 0.0000 57 KSO4- 0.12797E-07 -7.8929 0.12220E-07 -7.9129 0.95493E+00 -0.0200 58 MgCO3,aq 0.60198E-11 -11.2204 0.60198E-11 -11.2204 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27594E-11 -11.5592 0.26352E-11 -11.5792 0.95499E+00 -0.0200 60 MgCl+ 0.16901E-11 -11.7721 0.16140E-11 -11.7921 0.95499E+00 -0.0200 61 MgOH+ 0.71856E-09 -9.1435 0.68622E-09 -9.1635 0.95499E+00 -0.0200 63 MnO,aq 0.30281E-09 -9.5188 0.30281E-09 -9.5188 0.10000E+01 0.0000 64 MnOH+ 0.44597E-08 -8.3507 0.42590E-08 -8.3707 0.95499E+00 -0.0200 65 MnO2-2 0.51339E-15 -15.2896 0.45058E-15 -15.3462 0.87766E+00 -0.0567 66 HMnO2- 0.49285E-12 -12.3073 0.47064E-12 -12.3273 0.95493E+00 -0.0200 69 MnCl+ 0.55664E-11 -11.2544 0.53159E-11 -11.2744 0.95499E+00 -0.0200 70 MnSO4,aq 0.42252E-10 -10.3742 0.42252E-10 -10.3742 0.10000E+01 0.0000 71 NaCl,aq 0.15580E-07 -7.8074 0.15580E-07 -7.8074 0.10000E+01 0.0000 72 NaOH,aq 0.33010E-07 -7.4814 0.33010E-07 -7.4814 0.10000E+01 0.0000 74 OH- 0.13030E-03 -3.8850 0.12442E-03 -3.9051 0.95488E+00 -0.0201 79 HPO3-2 0.38585E-19 -19.4136 0.33864E-19 -19.4703 0.87766E+00 -0.0567 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.21475E-08 -8.6681 0.20508E-08 -8.6881 0.95496E+00 -0.0200 84 PO4-3 0.57574E-11 -11.2398 0.43953E-11 -11.3570 0.76341E+00 -0.1172 87 H2P2O7-2 0.37504E-18 -18.4259 0.32916E-18 -18.4826 0.87766E+00 -0.0567 88 HP2O7-3 0.18368E-16 -16.7359 0.14000E-16 -16.8539 0.76219E+00 -0.1179 89 P2O7-4 0.11440E-17 -17.9416 0.71642E-18 -18.1448 0.62624E+00 -0.2033 90 H2S,aq 0.29606E-14 -14.5286 0.29603E-14 -14.5287 0.99988E+00 -0.0001 97 SO3-2 0.15344E-14 -14.8141 0.13473E-14 -14.8705 0.87807E+00 -0.0565 98 HSO3- 0.39807E-15 -15.4000 0.38013E-15 -15.4201 0.95493E+00 -0.0200 99 HSO4- 0.10474E-09 -9.9799 0.10003E-09 -9.9999 0.95502E+00 -0.0200 Charge balance for all species = 0.7204E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5047498E-08 -.2424018E-03 -.2443113E+00 0.0000 2 H2O 0.1000000E+01 0.5550831E+02 0.9999370E+06 0.0000 3 Cl- 0.1379637E-03 0.1379798E-03 0.4891495E+01 4.4366 4 SO4-- 0.2547809E-04 0.2550547E-04 0.2449945E+01 11.9833 5 HCO3- 0.1268158E-04 0.1307053E-04 0.7974780E+00 3.4000 6 HS- 0.2140152E-12 0.4111718E-10 0.1359743E-05 -4.3727 7 Al+++ 0.8863784E-22 0.7570681E-05 0.2042557E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4645713E-03 0.4464969E+02 -3.4168 9 Ca++ 0.2368816E-05 0.2425949E-05 0.9722117E-01 10.9515 10 Mg++ 0.9652217E-08 0.1040041E-07 0.2528391E-03 8.5615 11 Fe++ 0.5709362E-10 0.1258860E-08 0.7029922E-04 6.3335 12 K+ 0.3714042E-04 0.3715651E-04 0.1452804E+01 3.8667 13 Na+ 0.3792598E-03 0.3797542E-03 0.8729931E+01 4.8758 14 Mn++ 0.7598139E-08 0.1240894E-07 0.6816801E-03 8.4577 15 HPO4-- 0.2764350E-07 0.2979675E-07 0.2859685E-02 9.0187 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2884700E-02 -.2423919E-03 -.2642308E-02 0.0000000E+00 2 H2O 0.5550606E+02 0.5550605E+02 0.1113444E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3035432E-04 0.2550443E-04 0.4849888E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4849847E-05 0.4111550E-10 -.4849888E-05 0.0000000E+00 7 Al+++ 0.5706298E-03 0.7570372E-05 0.5630594E-03 0.0000000E+00 8 H4SiO4 0.1822237E-02 0.4645523E-03 0.1357685E-02 0.0000000E+00 9 Ca++ 0.2157460E-03 0.2425850E-05 0.2133202E-03 0.0000000E+00 10 Mg++ 0.1388889E-03 0.1039999E-07 0.1388785E-03 0.0000000E+00 11 Fe++ 0.1247765E-03 0.1258809E-08 0.1247752E-03 0.0000000E+00 12 K+ 0.3715499E-04 0.3715499E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3797386E-03 0.3797386E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3034254E-05 0.1240843E-07 0.3021846E-05 0.0000000E+00 15 HPO4-- 0.1035576E-05 0.2979553E-07 0.1005780E-05 0.0000000E+00 Chg. balance for solid moles: 0.1546E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1750000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3353E-06 -6.475 0.1684E-03 -3.774 0.1035 0.5351E-04 clinochlore 0.2778E-04 -4.556 0.1544E-01 -1.811 9.490 0.5872E-02 daphnite 0.1720E-04 -4.765 0.1227E-01 -1.911 7.542 0.3718E-02 chlorite-Mn 0.6044E-06 -6.219 0.4285E-03 -3.368 0.2634 0.1365E-03 hematite 0.1940E-04 -4.712 0.3098E-02 -2.509 1.904 0.5872E-03 kaolinite 0.2431E-04 -4.614 0.6276E-02 -2.202 3.858 0.2415E-02 lawsonite 0.6183E-04 -4.209 0.1943E-01 -1.712 11.94 0.6266E-02 stilbite 0.1498E-03 -3.824 0.1056 -0.976 64.90 0.4924E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1326E-01 0.1326E-01 1.0000 -1.877 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.162683 g Volume = 0.068290 cm3 Porosity: 93.6178% V(tot) - V(min): 0.10017E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1750000 g log = -0.7570 Original solution: 1000.0103000 g Original solution / Rock added: 5714.34 (Water/Rock Ratio), log = 3.7570 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1272E-04 1.0073 0.1347E-04 0.1338E-04 CH4,gas 0.1612E-15 1.0129 0.1717E-15 0.1696E-15 H2,gas 0.5758E-06 1.0006 0.6061E-06 0.6057E-06 H2S,gas 0.8241E-13 0.9959 0.8634E-13 0.8669E-13 S2,gas 0.7226E-33 1.0000 0.7601E-33 0.7601E-33 CO,gas 0.2011E-14 1.0000 0.2115E-14 0.2115E-14 SO3,gas 0.1847E-36 1.0000 0.1943E-36 0.1943E-36 SO2,gas 0.4235E-20 1.0000 0.4455E-20 0.4455E-20 HCl,gas 0.2005E-15 1.0000 0.2109E-15 0.2109E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 164 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.23 -6.87 -2.290 0.11731E+05 -4.870 3 CH4,gas 4.81 -12.96 -17.77 -4.441 0.30333E+05 -15.765 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -21.01 -15.06 -7.532 0.25721E+05 -13.064 6 S2,gas -7.03 -42.15 -35.12 -5.403 0.59965E+05 -33.119 7 CO,gas 3.51 -13.16 -16.67 -5.131 0.28471E+05 -14.675 8 SO3,gas 17.43 -21.28 -38.71 -9.678 0.66099E+05 -36.712 9 SO2,gas 1.14 -21.21 -22.35 -5.960 0.38164E+05 -20.351 10 HCl,gas 5.48 -12.20 -17.68 -8.838 0.30181E+05 -15.676 11 acmite 7.74 4.34 -3.40 -0.353 0.57994E+04 15 albite-high 0.75 -2.59 -3.34 -0.257 0.57100E+04 16 albite -0.33 -2.59 -2.27 -0.174 0.38694E+04 19 spessartine 24.55 20.68 -3.87 -0.193 0.66027E+04 20 analcite 3.37 0.82 -2.55 -0.283 0.43511E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.40 -4.81 -0.267 0.82169E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.28 -3.27 -1.089 0.55807E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.28 -3.12 -1.038 0.53194E+04 38 carnegieite-low 9.06 4.24 -4.83 -0.689 0.82392E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29411E+04 42 celadonite 5.40 1.54 -3.86 -0.227 0.65897E+04 43 celadonite-Fe 3.94 -0.69 -4.62 -0.272 0.78950E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13001E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14716E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82450E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68766E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.82 -3.43 -0.343 0.58542E+04 97 kalsilite 7.62 3.23 -4.39 -0.627 0.74960E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.19 -4.35 -0.435 0.74349E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.60 -1.17 -0.090 0.20007E+04 120 muscovite 2.68 1.96 -0.72 -0.042 0.12331E+04 121 paragonite 4.34 2.97 -1.37 -0.081 0.23402E+04 122 nepheline 8.38 4.24 -4.14 -0.591 0.70671E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50040E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.475 0.40556E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.78 -3.82 -1.273 0.65183E+04 153 rhodonite 7.46 5.04 -2.42 -0.484 0.41349E+04 154 sanidine -1.22 -3.60 -2.38 -0.183 0.40685E+04 156 siderite -2.59 -6.90 -4.31 -1.438 0.73635E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.83 -1.35 -0.040 0.23095E+04 166 stilpnomelane-Mg 27.60 22.97 -4.63 -0.138 0.79046E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83656E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 175 tephroite 18.11 13.50 -4.61 -0.659 0.78790E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.79 -3.35 -0.205 0.57213E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.45 -3.20 -0.196 0.54567E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 203 montmorillonite-K -2.16 -4.92 -2.76 -0.169 0.47161E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.59 -2.63 -0.161 0.44896E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.25 -1.15 -0.074 0.19679E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.58 -1.00 -0.064 0.17050E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.14 -2.22 -0.171 0.37891E+04 244 an25ab75 2.71 0.47 -2.24 -0.172 0.38169E+04 245 an30ab70 3.34 1.09 -2.26 -0.174 0.38531E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1750000 g New total amount of reactant added: 0.1790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1790000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3775929E-03 Osmotic coef. = 0.9885 True ionic strength = .4548894E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.49232E-08 -8.3078 0.47015E-08 -8.3278 0.95496E+00 -0.0200 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13172E-03 -3.8803 0.95477E+00 -0.0201 4 SO4-- 0.25479E-04 -4.5938 0.22348E-04 -4.6508 0.87713E+00 -0.0569 5 HCO3- 0.12678E-04 -4.8970 0.12105E-04 -4.9170 0.95482E+00 -0.0201 6 HS- 0.20860E-12 -12.6807 0.19917E-12 -12.7008 0.95478E+00 -0.0201 7 Al+++ 0.82331E-22 -22.0844 0.62657E-22 -22.2030 0.76103E+00 -0.1186 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.22543E-05 -5.6470 0.19769E-05 -5.7040 0.87692E+00 -0.0570 10 Mg++ 0.91857E-08 -8.0369 0.80539E-08 -8.0940 0.87679E+00 -0.0571 11 Fe++ 0.54334E-10 -10.2649 0.47641E-10 -10.3220 0.87682E+00 -0.0571 12 K+ 0.37989E-04 -4.4203 0.36273E-04 -4.4404 0.95483E+00 -0.0201 13 Na+ 0.38426E-03 -3.4154 0.36688E-03 -3.4355 0.95477E+00 -0.0201 14 Mn++ 0.72326E-08 -8.1407 0.63419E-08 -8.1978 0.87685E+00 -0.0571 15 HPO4-- 0.29086E-07 -7.5363 0.25513E-07 -7.5932 0.87714E+00 -0.0569 16 HSiO3- 0.83238E-04 -4.0797 0.79474E-04 -4.0998 0.95477E+00 -0.0201 17 Ca(HSiO3)+ 0.36866E-08 -8.4334 0.35201E-08 -8.4534 0.95483E+00 -0.0201 18 Mg(HSiO3)+ 0.18692E-10 -10.7283 0.17848E-10 -10.7484 0.95483E+00 -0.0201 19 NaHSiO3,aq 0.46309E-06 -6.3343 0.46309E-06 -6.3343 0.10000E+01 0.0000 20 AlO+ 0.38326E-12 -12.4165 0.36595E-12 -12.4366 0.95483E+00 -0.0201 21 AlOH+2 0.98287E-17 -17.0075 0.86186E-17 -17.0646 0.87688E+00 -0.0571 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.77485E-05 -5.1108 0.73976E-05 -5.1309 0.95471E+00 -0.0201 24 CH4,aq 0.10587E-18 -18.9752 0.10586E-18 -18.9753 0.99988E+00 -0.0001 29 CO,aq 0.13059E-17 -17.8841 0.13059E-17 -17.8841 0.10000E+01 0.0000 30 CO2,aq 0.11476E-06 -6.9402 0.11475E-06 -6.9403 0.99988E+00 -0.0001 31 CO3-2 0.27143E-06 -6.5663 0.23806E-06 -6.6233 0.87707E+00 -0.0570 32 CaCO3,aq 0.57639E-08 -8.2393 0.57639E-08 -8.2393 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.63150E-09 -9.1996 0.60297E-09 -9.2197 0.95483E+00 -0.0201 34 CaCl+ 0.43458E-09 -9.3619 0.41495E-09 -9.3820 0.95483E+00 -0.0201 35 CaCl2,aq 0.12726E-13 -13.8953 0.12726E-13 -13.8953 0.10000E+01 0.0000 36 CaOH+ 0.31052E-07 -7.5079 0.29649E-07 -7.5280 0.95483E+00 -0.0201 37 CaSO4,aq 0.13765E-07 -7.8612 0.13765E-07 -7.8612 0.10000E+01 0.0000 38 HCl,aq 0.11649E-12 -12.9337 0.11649E-12 -12.9337 0.10000E+01 0.0000 43 FeCl+ 0.10236E-13 -13.9898 0.97741E-14 -14.0099 0.95483E+00 -0.0201 46 FeO,aq 0.85232E-10 -10.0694 0.85232E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.35184E-09 -9.4537 0.33594E-09 -9.4737 0.95483E+00 -0.0201 48 HFeO2- 0.20423E-09 -9.6899 0.19499E-09 -9.7100 0.95477E+00 -0.0201 49 FeO+ 0.40731E-13 -13.3901 0.38891E-13 -13.4102 0.95483E+00 -0.0201 50 FeOH+2 0.38801E-19 -19.4112 0.34024E-19 -19.4682 0.87688E+00 -0.0571 51 FeO2- 0.36219E-09 -9.4411 0.34581E-09 -9.4612 0.95477E+00 -0.0201 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44193E-09 -9.3546 0.44188E-09 -9.3547 0.99988E+00 -0.0001 54 KCl,aq 0.84602E-10 -10.0726 0.84602E-10 -10.0726 0.10000E+01 0.0000 55 KHSO4,aq 0.10199E-16 -16.9915 0.10199E-16 -16.9915 0.10000E+01 0.0000 56 KOH,aq 0.33635E-08 -8.4732 0.33635E-08 -8.4732 0.10000E+01 0.0000 57 KSO4- 0.13081E-07 -7.8834 0.12489E-07 -7.9035 0.95477E+00 -0.0201 58 MgCO3,aq 0.58679E-11 -11.2315 0.58679E-11 -11.2315 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26235E-11 -11.5811 0.25050E-11 -11.6012 0.95483E+00 -0.0201 60 MgCl+ 0.16073E-11 -11.7939 0.15347E-11 -11.8140 0.95483E+00 -0.0201 61 MgOH+ 0.70086E-09 -9.1544 0.66921E-09 -9.1744 0.95483E+00 -0.0201 63 MnO,aq 0.30288E-09 -9.5187 0.30288E-09 -9.5187 0.10000E+01 0.0000 64 MnOH+ 0.43509E-08 -8.3614 0.41544E-08 -8.3815 0.95483E+00 -0.0201 65 MnO2-2 0.54031E-15 -15.2674 0.47389E-15 -15.3243 0.87707E+00 -0.0570 66 HMnO2- 0.50558E-12 -12.2962 0.48272E-12 -12.3163 0.95477E+00 -0.0201 69 MnCl+ 0.52951E-11 -11.2761 0.50559E-11 -11.2962 0.95483E+00 -0.0201 70 MnSO4,aq 0.40166E-10 -10.3961 0.40166E-10 -10.3961 0.10000E+01 0.0000 71 NaCl,aq 0.15780E-07 -7.8019 0.15780E-07 -7.8019 0.10000E+01 0.0000 72 NaOH,aq 0.34290E-07 -7.4648 0.34290E-07 -7.4648 0.10000E+01 0.0000 74 OH- 0.13364E-03 -3.8741 0.12759E-03 -3.8942 0.95471E+00 -0.0201 79 HPO3-2 0.40598E-19 -19.3915 0.35608E-19 -19.4485 0.87707E+00 -0.0570 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.22025E-08 -8.6571 0.21029E-08 -8.6772 0.95480E+00 -0.0201 84 PO4-3 0.62170E-11 -11.2064 0.47391E-11 -11.3243 0.76228E+00 -0.1179 87 H2P2O7-2 0.39461E-18 -18.4038 0.34610E-18 -18.4608 0.87707E+00 -0.0570 88 HP2O7-3 0.19835E-16 -16.7026 0.15095E-16 -16.8212 0.76105E+00 -0.1186 89 P2O7-4 0.12682E-17 -17.8968 0.79209E-18 -18.1012 0.62457E+00 -0.2044 90 H2S,aq 0.28137E-14 -14.5507 0.28134E-14 -14.5508 0.99988E+00 -0.0001 97 SO3-2 0.15344E-14 -14.8141 0.13465E-14 -14.8708 0.87749E+00 -0.0568 98 HSO3- 0.38801E-15 -15.4112 0.37046E-15 -15.4313 0.95477E+00 -0.0201 99 HSO4- 0.10210E-09 -9.9910 0.97489E-10 -10.0110 0.95486E+00 -0.0201 Charge balance for all species = 0.7204E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4923176E-08 -.2486151E-03 -.2505735E+00 0.0000 2 H2O 0.1000000E+01 0.5550832E+02 0.9999366E+06 0.0000 3 Cl- 0.1379636E-03 0.1379799E-03 0.4891497E+01 4.4474 4 SO4-- 0.2547854E-04 0.2550549E-04 0.2449946E+01 12.0048 5 HCO3- 0.1267795E-04 0.1307054E-04 0.7974783E+00 3.4107 6 HS- 0.2085990E-12 0.3998069E-10 0.1322159E-05 -4.3730 7 Al+++ 0.8233113E-22 0.7764054E-05 0.2094728E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4666658E-03 0.4485097E+02 -3.4168 9 Ca++ 0.2254324E-05 0.2309658E-05 0.9256070E-01 10.9515 10 Mg++ 0.9185700E-08 0.9915353E-08 0.2410470E-03 8.5615 11 Fe++ 0.5433386E-10 0.1261346E-08 0.7043802E-04 6.3335 12 K+ 0.3798930E-04 0.3800583E-04 0.1486011E+01 3.8874 13 Na+ 0.3842625E-03 0.3847756E-03 0.8845363E+01 4.8923 14 Mn++ 0.7232638E-08 0.1193237E-07 0.6554997E-03 8.4578 15 HPO4-- 0.2908624E-07 0.3129492E-07 0.3003468E-02 9.0623 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2950934E-02 -.2486047E-03 -.2702330E-02 0.0000000E+00 2 H2O 0.5550601E+02 0.5550600E+02 0.2678001E-05 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3046517E-04 0.2550443E-04 0.4960740E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4960700E-05 0.3997903E-10 -.4960740E-05 0.0000000E+00 7 Al+++ 0.5836727E-03 0.7763731E-05 0.5759090E-03 0.0000000E+00 8 H4SiO4 0.1863888E-02 0.4666463E-03 0.1397242E-02 0.0000000E+00 9 Ca++ 0.2203466E-03 0.2309562E-05 0.2180370E-03 0.0000000E+00 10 Mg++ 0.1420635E-03 0.9914940E-08 0.1420536E-03 0.0000000E+00 11 Fe++ 0.1276285E-03 0.1261294E-08 0.1276273E-03 0.0000000E+00 12 K+ 0.3800425E-04 0.3800425E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3847596E-03 0.3847596E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3103609E-05 0.1193187E-07 0.3091677E-05 0.0000000E+00 15 HPO4-- 0.1059246E-05 0.3129361E-07 0.1027953E-05 0.0000000E+00 Chg. balance for solid moles: 0.5751E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3427E-06 -6.465 0.1721E-03 -3.764 0.1030 0.5469E-04 clinochlore 0.2841E-04 -4.547 0.1579E-01 -1.802 9.453 0.6007E-02 daphnite 0.1759E-04 -4.755 0.1255E-01 -1.901 7.512 0.3803E-02 chlorite-Mn 0.6183E-06 -6.209 0.4384E-03 -3.358 0.2624 0.1397E-03 hematite 0.1984E-04 -4.702 0.3169E-02 -2.499 1.897 0.6006E-03 kaolinite 0.2501E-04 -4.602 0.6457E-02 -2.190 3.865 0.2485E-02 lawsonite 0.6138E-04 -4.212 0.1929E-01 -1.715 11.55 0.6220E-02 stilbite 0.1549E-03 -3.810 0.1092 -0.962 65.36 0.5093E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1326E-01 0.1326E-01 1.0000 -1.877 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.167058 g Volume = 0.070238 cm3 Porosity: 93.4455% V(tot) - V(min): 0.10014E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1790000 g log = -0.7471 Original solution: 1000.0103000 g Original solution / Rock added: 5586.65 (Water/Rock Ratio), log = 3.7472 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1240E-04 1.0073 0.1313E-04 0.1304E-04 CH4,gas 0.1571E-15 1.0129 0.1674E-15 0.1653E-15 H2,gas 0.5758E-06 1.0006 0.6061E-06 0.6057E-06 H2S,gas 0.7832E-13 0.9959 0.8205E-13 0.8239E-13 S2,gas 0.6526E-33 1.0000 0.6865E-33 0.6865E-33 CO,gas 0.1960E-14 1.0000 0.2062E-14 0.2062E-14 SO3,gas 0.1756E-36 1.0000 0.1847E-36 0.1847E-36 SO2,gas 0.4025E-20 1.0000 0.4234E-20 0.4234E-20 HCl,gas 0.1955E-15 1.0000 0.2057E-15 0.2057E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.21232E-10 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 164 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.24 -6.88 -2.294 0.11750E+05 -4.882 3 CH4,gas 4.81 -12.97 -17.78 -4.444 0.30352E+05 -15.776 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -21.03 -15.09 -7.543 0.25759E+05 -13.086 6 S2,gas -7.03 -42.20 -35.16 -5.410 0.60040E+05 -33.163 7 CO,gas 3.51 -13.18 -16.69 -5.134 0.28490E+05 -14.686 8 SO3,gas 17.43 -21.31 -38.73 -9.683 0.66137E+05 -36.734 9 SO2,gas 1.14 -21.24 -22.37 -5.966 0.38202E+05 -20.373 10 HCl,gas 5.48 -12.21 -17.69 -8.843 0.30200E+05 -15.687 11 acmite 7.74 4.36 -3.38 -0.351 0.57712E+04 15 albite-high 0.75 -2.58 -3.33 -0.256 0.56818E+04 16 albite -0.33 -2.58 -2.25 -0.173 0.38411E+04 19 spessartine 24.55 20.68 -3.87 -0.193 0.66021E+04 20 analcite 3.37 0.84 -2.53 -0.281 0.43229E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.42 -4.79 -0.266 0.81817E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.29 -3.28 -1.093 0.55997E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.29 -3.13 -1.042 0.53383E+04 38 carnegieite-low 9.06 4.26 -4.81 -0.687 0.82109E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29411E+04 42 celadonite 5.40 1.56 -3.84 -0.226 0.65545E+04 43 celadonite-Fe 3.94 -0.67 -4.60 -0.271 0.78598E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14714E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82450E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68766E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.84 -3.41 -0.341 0.58259E+04 97 kalsilite 7.62 3.25 -4.37 -0.624 0.74608E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.17 -4.33 -0.433 0.73997E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.58 -1.15 -0.089 0.19655E+04 120 muscovite 2.68 1.98 -0.70 -0.041 0.11979E+04 121 paragonite 4.34 2.98 -1.35 -0.080 0.23120E+04 122 nepheline 8.38 4.26 -4.12 -0.589 0.70389E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50040E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.475 0.40555E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.79 -3.83 -1.276 0.65371E+04 153 rhodonite 7.46 5.04 -2.42 -0.484 0.41347E+04 154 sanidine -1.22 -3.58 -2.36 -0.182 0.40332E+04 156 siderite -2.59 -6.91 -4.32 -1.441 0.73824E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.84 -1.34 -0.040 0.22919E+04 166 stilpnomelane-Mg 27.60 22.98 -4.62 -0.138 0.78869E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83656E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 175 tephroite 18.11 13.50 -4.61 -0.659 0.78787E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.78 -3.34 -0.205 0.57097E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.45 -3.19 -0.195 0.54474E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 203 montmorillonite-K -2.16 -4.92 -2.76 -0.169 0.47044E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.58 -2.62 -0.161 0.44803E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.26 -1.15 -0.074 0.19563E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.59 -0.99 -0.064 0.16957E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.13 -2.21 -0.170 0.37665E+04 244 an25ab75 2.71 0.49 -2.22 -0.171 0.37958E+04 245 an30ab70 3.34 1.10 -2.25 -0.173 0.38334E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1790000 g New total amount of reactant added: 0.1830000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1830000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3811857E-03 Osmotic coef. = 0.9884 True ionic strength = .4604261E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.48046E-08 -8.3183 0.45874E-08 -8.3384 0.95481E+00 -0.0201 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13170E-03 -3.8804 0.95461E+00 -0.0202 4 SO4-- 0.25479E-04 -4.5938 0.22334E-04 -4.6510 0.87655E+00 -0.0572 5 HCO3- 0.12674E-04 -4.8971 0.12100E-04 -4.9172 0.95466E+00 -0.0202 6 HS- 0.20343E-12 -12.6916 0.19420E-12 -12.7117 0.95462E+00 -0.0202 7 Al+++ 0.76600E-22 -22.1158 0.58208E-22 -22.2350 0.75989E+00 -0.1192 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.21477E-05 -5.6680 0.18821E-05 -5.7253 0.87634E+00 -0.0573 10 Mg++ 0.87514E-08 -8.0579 0.76680E-08 -8.1153 0.87621E+00 -0.0574 11 Fe++ 0.51765E-10 -10.2860 0.45358E-10 -10.3433 0.87624E+00 -0.0574 12 K+ 0.38838E-04 -4.4107 0.37078E-04 -4.4309 0.95467E+00 -0.0201 13 Na+ 0.38926E-03 -3.4098 0.37160E-03 -3.4299 0.95461E+00 -0.0202 14 Mn++ 0.68922E-08 -8.1616 0.60394E-08 -8.2190 0.87626E+00 -0.0574 15 HPO4-- 0.30570E-07 -7.5147 0.26797E-07 -7.5719 0.87655E+00 -0.0572 16 HSiO3- 0.85322E-04 -4.0689 0.81449E-04 -4.0891 0.95461E+00 -0.0202 17 Ca(HSiO3)+ 0.35978E-08 -8.4440 0.34347E-08 -8.4641 0.95467E+00 -0.0201 18 Mg(HSiO3)+ 0.18242E-10 -10.7389 0.17415E-10 -10.7591 0.95467E+00 -0.0201 19 NaHSiO3,aq 0.48070E-06 -6.3181 0.48070E-06 -6.3181 0.10000E+01 0.0000 20 AlO+ 0.37403E-12 -12.4271 0.35707E-12 -12.4472 0.95467E+00 -0.0201 21 AlOH+2 0.93640E-17 -17.0285 0.82056E-17 -17.0859 0.87629E+00 -0.0574 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.79424E-05 -5.1000 0.75814E-05 -5.1202 0.95455E+00 -0.0202 24 CH4,aq 0.10325E-18 -18.9861 0.10324E-18 -18.9862 0.99988E+00 -0.0001 29 CO,aq 0.12736E-17 -17.8950 0.12736E-17 -17.8950 0.10000E+01 0.0000 30 CO2,aq 0.11192E-06 -6.9511 0.11191E-06 -6.9511 0.99988E+00 -0.0001 31 CO3-2 0.27823E-06 -6.5556 0.24387E-06 -6.6129 0.87649E+00 -0.0573 32 CaCO3,aq 0.56215E-08 -8.2501 0.56215E-08 -8.2501 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.60106E-09 -9.2211 0.57381E-09 -9.2412 0.95467E+00 -0.0201 34 CaCl+ 0.41375E-09 -9.3833 0.39500E-09 -9.4034 0.95467E+00 -0.0201 35 CaCl2,aq 0.12113E-13 -13.9168 0.12113E-13 -13.9168 0.10000E+01 0.0000 36 CaOH+ 0.30304E-07 -7.5185 0.28930E-07 -7.5386 0.95467E+00 -0.0201 37 CaSO4,aq 0.13097E-07 -7.8828 0.13097E-07 -7.8828 0.10000E+01 0.0000 38 HCl,aq 0.11364E-12 -12.9445 0.11364E-12 -12.9445 0.10000E+01 0.0000 43 FeCl+ 0.97459E-14 -14.0112 0.93042E-14 -14.0313 0.95467E+00 -0.0201 46 FeO,aq 0.85231E-10 -10.0694 0.85231E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.34336E-09 -9.4643 0.32779E-09 -9.4844 0.95467E+00 -0.0201 48 HFeO2- 0.20934E-09 -9.6791 0.19984E-09 -9.6993 0.95461E+00 -0.0202 49 FeO+ 0.39750E-13 -13.4007 0.37948E-13 -13.4208 0.95467E+00 -0.0201 50 FeOH+2 0.36967E-19 -19.4322 0.32393E-19 -19.4895 0.87629E+00 -0.0574 51 FeO2- 0.37126E-09 -9.4303 0.35441E-09 -9.4505 0.95461E+00 -0.0202 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44192E-09 -9.3547 0.44187E-09 -9.3547 0.99988E+00 -0.0001 54 KCl,aq 0.86464E-10 -10.0632 0.86464E-10 -10.0632 0.10000E+01 0.0000 55 KHSO4,aq 0.10165E-16 -16.9929 0.10165E-16 -16.9929 0.10000E+01 0.0000 56 KOH,aq 0.35235E-08 -8.4530 0.35235E-08 -8.4530 0.10000E+01 0.0000 57 KSO4- 0.13364E-07 -7.8741 0.12758E-07 -7.8942 0.95461E+00 -0.0202 58 MgCO3,aq 0.57229E-11 -11.2424 0.57229E-11 -11.2424 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24971E-11 -11.6026 0.23839E-11 -11.6227 0.95467E+00 -0.0201 60 MgCl+ 0.15303E-11 -11.8152 0.14609E-11 -11.8354 0.95467E+00 -0.0201 61 MgOH+ 0.68398E-09 -9.1650 0.65298E-09 -9.1851 0.95467E+00 -0.0201 63 MnO,aq 0.30295E-09 -9.5186 0.30295E-09 -9.5186 0.10000E+01 0.0000 64 MnOH+ 0.42470E-08 -8.3719 0.40545E-08 -8.3921 0.95467E+00 -0.0201 65 MnO2-2 0.56800E-15 -15.2456 0.49785E-15 -15.3029 0.87649E+00 -0.0573 66 HMnO2- 0.51835E-12 -12.2854 0.49482E-12 -12.3055 0.95461E+00 -0.0202 69 MnCl+ 0.50425E-11 -11.2974 0.48139E-11 -11.3175 0.95467E+00 -0.0201 70 MnSO4,aq 0.38225E-10 -10.4176 0.38225E-10 -10.4176 0.10000E+01 0.0000 71 NaCl,aq 0.15980E-07 -7.7964 0.15980E-07 -7.7964 0.10000E+01 0.0000 72 NaOH,aq 0.35593E-07 -7.4486 0.35593E-07 -7.4486 0.10000E+01 0.0000 74 OH- 0.13698E-03 -3.8633 0.13076E-03 -3.8835 0.95455E+00 -0.0202 79 HPO3-2 0.42669E-19 -19.3699 0.37399E-19 -19.4271 0.87649E+00 -0.0573 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.22576E-08 -8.6464 0.21552E-08 -8.6665 0.95464E+00 -0.0202 84 PO4-3 0.67021E-11 -11.1738 0.51013E-11 -11.2923 0.76115E+00 -0.1185 87 H2P2O7-2 0.41475E-18 -18.3822 0.36352E-18 -18.4395 0.87649E+00 -0.0573 88 HP2O7-3 0.21383E-16 -16.6699 0.16249E-16 -16.7892 0.75991E+00 -0.1192 89 P2O7-4 0.14028E-17 -17.8530 0.87382E-18 -18.0586 0.62291E+00 -0.2056 90 H2S,aq 0.26770E-14 -14.5723 0.26767E-14 -14.5724 0.99988E+00 -0.0001 97 SO3-2 0.15344E-14 -14.8141 0.13456E-14 -14.8711 0.87692E+00 -0.0570 98 HSO3- 0.37841E-15 -15.4220 0.36124E-15 -15.4422 0.95461E+00 -0.0202 99 HSO4- 0.99573E-10 -10.0019 0.95063E-10 -10.0220 0.95470E+00 -0.0201 Charge balance for all species = 0.7204E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4804575E-08 -.2548460E-03 -.2568534E+00 0.0000 2 H2O 0.1000000E+01 0.5550832E+02 0.9999363E+06 0.0000 3 Cl- 0.1379635E-03 0.1379800E-03 0.4891499E+01 4.4580 4 SO4-- 0.2547895E-04 0.2550551E-04 0.2449947E+01 12.0258 5 HCO3- 0.1267417E-04 0.1307055E-04 0.7974786E+00 3.4212 6 HS- 0.2034332E-12 0.3884139E-10 0.1284482E-05 -4.3733 7 Al+++ 0.7660011E-22 0.7957972E-05 0.2147046E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4687664E-03 0.4505285E+02 -3.4168 9 Ca++ 0.2147742E-05 0.2201377E-05 0.8822124E-01 10.9515 10 Mg++ 0.8751411E-08 0.9463381E-08 0.2300593E-03 8.5615 11 Fe++ 0.5176478E-10 0.1264472E-08 0.7061256E-04 6.3335 12 K+ 0.3883818E-04 0.3885515E-04 0.1519219E+01 3.9075 13 Na+ 0.3892649E-03 0.3897971E-03 0.8960796E+01 4.9085 14 Mn++ 0.6892204E-08 0.1148595E-07 0.6309754E-03 8.4579 15 HPO4-- 0.3057035E-07 0.3283463E-07 0.3151237E-02 9.1049 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3017168E-02 -.2548352E-03 -.2762333E-02 0.0000000E+00 2 H2O 0.5550596E+02 0.5550596E+02 -.5781113E-05 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3057602E-04 0.2550443E-04 0.5071593E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5071554E-05 0.3883974E-10 -.5071593E-05 0.0000000E+00 7 Al+++ 0.5967157E-03 0.7957635E-05 0.5887581E-03 0.0000000E+00 8 H4SiO4 0.1905539E-02 0.4687465E-03 0.1436793E-02 0.0000000E+00 9 Ca++ 0.2249472E-03 0.2201283E-05 0.2227459E-03 0.0000000E+00 10 Mg++ 0.1452381E-03 0.9462980E-08 0.1452286E-03 0.0000000E+00 11 Fe++ 0.1304806E-03 0.1264419E-08 0.1304793E-03 0.0000000E+00 12 K+ 0.3885350E-04 0.3885350E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3897806E-03 0.3897806E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3172963E-05 0.1148546E-07 0.3161478E-05 0.0000000E+00 15 HPO4-- 0.1082917E-05 0.3283324E-07 0.1050083E-05 0.0000000E+00 Chg. balance for solid moles: 0.5976E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1830000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3500E-06 -6.456 0.1758E-03 -3.755 0.1026 0.5587E-04 clinochlore 0.2905E-04 -4.537 0.1614E-01 -1.792 9.417 0.6141E-02 daphnite 0.1798E-04 -4.745 0.1283E-01 -1.892 7.484 0.3888E-02 chlorite-Mn 0.6323E-06 -6.199 0.4483E-03 -3.348 0.2615 0.1429E-03 hematite 0.2029E-04 -4.693 0.3240E-02 -2.489 1.890 0.6141E-03 kaolinite 0.2572E-04 -4.590 0.6641E-02 -2.178 3.874 0.2555E-02 lawsonite 0.6092E-04 -4.215 0.1914E-01 -1.718 11.17 0.6173E-02 stilbite 0.1601E-03 -3.796 0.1128 -0.948 65.80 0.5262E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1327E-01 0.1327E-01 1.0000 -1.877 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.171431 g Volume = 0.072186 cm3 Porosity: 93.2738% V(tot) - V(min): 0.10010E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1830000 g log = -0.7375 Original solution: 1000.0103000 g Original solution / Rock added: 5464.54 (Water/Rock Ratio), log = 3.7376 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1209E-04 1.0073 0.1281E-04 0.1272E-04 CH4,gas 0.1532E-15 1.0129 0.1633E-15 0.1612E-15 H2,gas 0.5758E-06 1.0006 0.6061E-06 0.6057E-06 H2S,gas 0.7452E-13 0.9959 0.7807E-13 0.7839E-13 S2,gas 0.5908E-33 1.0000 0.6215E-33 0.6215E-33 CO,gas 0.1912E-14 1.0000 0.2011E-14 0.2011E-14 SO3,gas 0.1670E-36 1.0000 0.1757E-36 0.1757E-36 SO2,gas 0.3830E-20 1.0000 0.4029E-20 0.4029E-20 HCl,gas 0.1908E-15 1.0000 0.2007E-15 0.2007E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 164 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.26 -6.89 -2.297 0.11769E+05 -4.892 3 CH4,gas 4.81 -12.98 -17.79 -4.447 0.30371E+05 -15.787 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -21.05 -15.11 -7.554 0.25796E+05 -13.108 6 S2,gas -7.03 -42.24 -35.21 -5.416 0.60114E+05 -33.207 7 CO,gas 3.51 -13.19 -16.70 -5.137 0.28509E+05 -14.697 8 SO3,gas 17.43 -21.33 -38.76 -9.689 0.66173E+05 -36.755 9 SO2,gas 1.14 -21.26 -22.39 -5.972 0.38239E+05 -20.395 10 HCl,gas 5.48 -12.22 -17.70 -8.849 0.30218E+05 -15.698 11 acmite 7.74 4.37 -3.36 -0.349 0.57436E+04 15 albite-high 0.75 -2.56 -3.31 -0.255 0.56541E+04 16 albite -0.33 -2.56 -2.23 -0.172 0.38135E+04 19 spessartine 24.55 20.68 -3.87 -0.193 0.66016E+04 20 analcite 3.37 0.86 -2.52 -0.280 0.42952E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.44 -4.77 -0.265 0.81472E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.30 -3.29 -1.097 0.56182E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.30 -3.14 -1.046 0.53569E+04 38 carnegieite-low 9.06 4.27 -4.79 -0.685 0.81833E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29411E+04 42 celadonite 5.40 1.58 -3.82 -0.225 0.65200E+04 43 celadonite-Fe 3.94 -0.65 -4.58 -0.270 0.78253E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14712E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82450E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68766E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.86 -3.40 -0.340 0.57983E+04 97 kalsilite 7.62 3.27 -4.35 -0.621 0.74263E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.15 -4.31 -0.431 0.73652E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.56 -1.13 -0.087 0.19310E+04 120 muscovite 2.68 2.00 -0.68 -0.040 0.11634E+04 121 paragonite 4.34 3.00 -1.34 -0.079 0.22843E+04 122 nepheline 8.38 4.27 -4.11 -0.587 0.70112E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.38 -0.475 0.40553E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.80 -3.84 -1.280 0.65555E+04 153 rhodonite 7.46 5.04 -2.42 -0.484 0.41345E+04 154 sanidine -1.22 -3.56 -2.34 -0.180 0.39988E+04 156 siderite -2.59 -6.92 -4.33 -1.445 0.74010E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.85 -1.33 -0.040 0.22747E+04 166 stilpnomelane-Mg 27.60 22.99 -4.61 -0.138 0.78697E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83656E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 175 tephroite 18.11 13.50 -4.61 -0.659 0.78783E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.77 -3.34 -0.204 0.56983E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.44 -3.18 -0.195 0.54382E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 203 montmorillonite-K -2.16 -4.91 -2.75 -0.168 0.46931E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.58 -2.62 -0.160 0.44712E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.26 -1.14 -0.073 0.19449E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.60 -0.99 -0.063 0.16865E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.11 -2.19 -0.169 0.37444E+04 244 an25ab75 2.71 0.50 -2.21 -0.170 0.37750E+04 245 an30ab70 3.34 1.11 -2.23 -0.172 0.38140E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1830000 g New total amount of reactant added: 0.1870000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1870000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3847957E-03 Osmotic coef. = 0.9884 True ionic strength = .4659844E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.46913E-08 -8.3287 0.44786E-08 -8.3489 0.95465E+00 -0.0202 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13168E-03 -3.8805 0.95445E+00 -0.0202 4 SO4-- 0.25479E-04 -4.5938 0.22319E-04 -4.6513 0.87597E+00 -0.0575 5 HCO3- 0.12670E-04 -4.8972 0.12094E-04 -4.9174 0.95450E+00 -0.0202 6 HS- 0.19850E-12 -12.7022 0.18946E-12 -12.7225 0.95446E+00 -0.0202 7 Al+++ 0.71382E-22 -22.1464 0.54162E-22 -22.2663 0.75876E+00 -0.1199 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.20484E-05 -5.6886 0.17939E-05 -5.7462 0.87576E+00 -0.0576 10 Mg++ 0.83466E-08 -8.0785 0.73084E-08 -8.1362 0.87562E+00 -0.0577 11 Fe++ 0.49370E-10 -10.3065 0.43231E-10 -10.3642 0.87565E+00 -0.0577 12 K+ 0.39687E-04 -4.4014 0.37882E-04 -4.4216 0.95451E+00 -0.0202 13 Na+ 0.39427E-03 -3.4042 0.37631E-03 -3.4245 0.95445E+00 -0.0202 14 Mn++ 0.65747E-08 -8.1821 0.57573E-08 -8.2398 0.87568E+00 -0.0577 15 HPO4-- 0.32096E-07 -7.4936 0.28115E-07 -7.5511 0.87597E+00 -0.0575 16 HSiO3- 0.87410E-04 -4.0584 0.83429E-04 -4.0787 0.95445E+00 -0.0202 17 Ca(HSiO3)+ 0.35130E-08 -8.4543 0.33532E-08 -8.4745 0.95451E+00 -0.0202 18 Mg(HSiO3)+ 0.17812E-10 -10.7493 0.17002E-10 -10.7695 0.95451E+00 -0.0202 19 NaHSiO3,aq 0.49863E-06 -6.3022 0.49863E-06 -6.3022 0.10000E+01 0.0000 20 AlO+ 0.36521E-12 -12.4375 0.34860E-12 -12.4577 0.95451E+00 -0.0202 21 AlOH+2 0.89308E-17 -17.0491 0.78208E-17 -17.1067 0.87571E+00 -0.0576 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.81368E-05 -5.0895 0.77657E-05 -5.1098 0.95439E+00 -0.0203 24 CH4,aq 0.10075E-18 -18.9968 0.10074E-18 -18.9968 0.99988E+00 -0.0001 29 CO,aq 0.12428E-17 -17.9056 0.12428E-17 -17.9056 0.10000E+01 0.0000 30 CO2,aq 0.10922E-06 -6.9617 0.10920E-06 -6.9618 0.99988E+00 -0.0001 31 CO3-2 0.28505E-06 -6.5451 0.24967E-06 -6.6026 0.87591E+00 -0.0575 32 CaCO3,aq 0.54855E-08 -8.2608 0.54855E-08 -8.2608 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.57269E-09 -9.2421 0.54664E-09 -9.2623 0.95451E+00 -0.0202 34 CaCl+ 0.39435E-09 -9.4041 0.37641E-09 -9.4243 0.95451E+00 -0.0202 35 CaCl2,aq 0.11541E-13 -13.9378 0.11541E-13 -13.9378 0.10000E+01 0.0000 36 CaOH+ 0.29590E-07 -7.5289 0.28244E-07 -7.5491 0.95451E+00 -0.0202 37 CaSO4,aq 0.12475E-07 -7.9040 0.12475E-07 -7.9040 0.10000E+01 0.0000 38 HCl,aq 0.11093E-12 -12.9550 0.11093E-12 -12.9550 0.10000E+01 0.0000 43 FeCl+ 0.92888E-14 -14.0320 0.88663E-14 -14.0523 0.95451E+00 -0.0202 46 FeO,aq 0.85231E-10 -10.0694 0.85231E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.33526E-09 -9.4746 0.32001E-09 -9.4948 0.95451E+00 -0.0202 48 HFeO2- 0.21446E-09 -9.6686 0.20470E-09 -9.6889 0.95445E+00 -0.0202 49 FeO+ 0.38813E-13 -13.4110 0.37047E-13 -13.4312 0.95451E+00 -0.0202 50 FeOH+2 0.35256E-19 -19.4528 0.30874E-19 -19.5104 0.87571E+00 -0.0576 51 FeO2- 0.38034E-09 -9.4198 0.36302E-09 -9.4401 0.95445E+00 -0.0202 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44192E-09 -9.3547 0.44187E-09 -9.3547 0.99988E+00 -0.0001 54 KCl,aq 0.88324E-10 -10.0539 0.88324E-10 -10.0539 0.10000E+01 0.0000 55 KHSO4,aq 0.10133E-16 -16.9943 0.10133E-16 -16.9943 0.10000E+01 0.0000 56 KOH,aq 0.36874E-08 -8.4333 0.36874E-08 -8.4333 0.10000E+01 0.0000 57 KSO4- 0.13647E-07 -7.8649 0.13026E-07 -7.8852 0.95445E+00 -0.0202 58 MgCO3,aq 0.55844E-11 -11.2530 0.55844E-11 -11.2530 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23792E-11 -11.6236 0.22710E-11 -11.6438 0.95451E+00 -0.0202 60 MgCl+ 0.14585E-11 -11.8361 0.13922E-11 -11.8563 0.95451E+00 -0.0202 61 MgOH+ 0.66786E-09 -9.1753 0.63748E-09 -9.1955 0.95451E+00 -0.0202 63 MnO,aq 0.30301E-09 -9.5185 0.30301E-09 -9.5185 0.10000E+01 0.0000 64 MnOH+ 0.41478E-08 -8.3822 0.39591E-08 -8.4024 0.95451E+00 -0.0202 65 MnO2-2 0.59647E-15 -15.2244 0.52245E-15 -15.2820 0.87591E+00 -0.0575 66 HMnO2- 0.53114E-12 -12.2748 0.50695E-12 -12.2950 0.95445E+00 -0.0202 69 MnCl+ 0.48070E-11 -11.3181 0.45883E-11 -11.3383 0.95451E+00 -0.0202 70 MnSO4,aq 0.36417E-10 -10.4387 0.36417E-10 -10.4387 0.10000E+01 0.0000 71 NaCl,aq 0.16180E-07 -7.7910 0.16180E-07 -7.7910 0.10000E+01 0.0000 72 NaOH,aq 0.36921E-07 -7.4327 0.36921E-07 -7.4327 0.10000E+01 0.0000 74 OH- 0.14033E-03 -3.8528 0.13393E-03 -3.8731 0.95439E+00 -0.0203 79 HPO3-2 0.44798E-19 -19.3487 0.39239E-19 -19.4063 0.87591E+00 -0.0575 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.23128E-08 -8.6359 0.22076E-08 -8.6561 0.95448E+00 -0.0202 84 PO4-3 0.72134E-11 -11.1419 0.54824E-11 -11.2610 0.76003E+00 -0.1192 87 H2P2O7-2 0.43544E-18 -18.3611 0.38141E-18 -18.4186 0.87591E+00 -0.0575 88 HP2O7-3 0.23015E-16 -16.6380 0.17463E-16 -16.7579 0.75877E+00 -0.1199 89 P2O7-4 0.15483E-17 -17.8101 0.96193E-18 -18.0169 0.62127E+00 -0.2067 90 H2S,aq 0.25497E-14 -14.5935 0.25494E-14 -14.5936 0.99988E+00 -0.0001 97 SO3-2 0.15344E-14 -14.8141 0.13447E-14 -14.8714 0.87634E+00 -0.0573 98 HSO3- 0.36925E-15 -15.4327 0.35243E-15 -15.4529 0.95445E+00 -0.0202 99 HSO4- 0.97163E-10 -10.0125 0.92747E-10 -10.0327 0.95454E+00 -0.0202 Charge balance for all species = 0.7205E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4691337E-08 -.2610932E-03 -.2631497E+00 0.0000 2 H2O 0.1000000E+01 0.5550832E+02 0.9999359E+06 0.0000 3 Cl- 0.1379635E-03 0.1379801E-03 0.4891501E+01 4.4684 4 SO4-- 0.2547932E-04 0.2550553E-04 0.2449948E+01 12.0464 5 HCO3- 0.1267024E-04 0.1307056E-04 0.7974790E+00 3.4314 6 HS- 0.1985022E-12 0.3769952E-10 0.1246720E-05 -4.3736 7 Al+++ 0.7138220E-22 0.8152387E-05 0.2199498E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4708727E-03 0.4525526E+02 -3.4168 9 Ca++ 0.2048384E-05 0.2100415E-05 0.8417510E-01 10.9515 10 Mg++ 0.8346565E-08 0.9041656E-08 0.2198069E-03 8.5615 11 Fe++ 0.4936990E-10 0.1268192E-08 0.7082027E-04 6.3335 12 K+ 0.3968705E-04 0.3970448E-04 0.1552426E+01 3.9273 13 Na+ 0.3942669E-03 0.3948186E-03 0.9076228E+01 4.9244 14 Mn++ 0.6574696E-08 0.1106722E-07 0.6079724E-03 8.4579 15 HPO4-- 0.3209579E-07 0.3441583E-07 0.3302989E-02 9.1467 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3083402E-02 -.2610819E-03 -.2822320E-02 0.0000000E+00 2 H2O 0.5550591E+02 0.5550592E+02 -.1424265E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3068688E-04 0.2550443E-04 0.5182445E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5182407E-05 0.3769789E-10 -.5182445E-05 0.0000000E+00 7 Al+++ 0.6097587E-03 0.8152035E-05 0.6016066E-03 0.0000000E+00 8 H4SiO4 0.1947190E-02 0.4708524E-03 0.1476338E-02 0.0000000E+00 9 Ca++ 0.2295477E-03 0.2100324E-05 0.2274474E-03 0.0000000E+00 10 Mg++ 0.1484127E-03 0.9041266E-08 0.1484037E-03 0.0000000E+00 11 Fe++ 0.1333326E-03 0.1268138E-08 0.1333313E-03 0.0000000E+00 12 K+ 0.3970276E-04 0.3970276E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3948016E-03 0.3948016E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3242317E-05 0.1106674E-07 0.3231251E-05 0.0000000E+00 15 HPO4-- 0.1106587E-05 0.3441434E-07 0.1072172E-05 0.0000000E+00 Chg. balance for solid moles: 0.4150E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1870000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3574E-06 -6.447 0.1795E-03 -3.746 0.1021 0.5705E-04 clinochlore 0.2968E-04 -4.528 0.1650E-01 -1.783 9.384 0.6275E-02 daphnite 0.1837E-04 -4.736 0.1311E-01 -1.882 7.457 0.3973E-02 chlorite-Mn 0.6463E-06 -6.190 0.4582E-03 -3.339 0.2606 0.1460E-03 hematite 0.2073E-04 -4.683 0.3311E-02 -2.480 1.883 0.6275E-03 kaolinite 0.2644E-04 -4.578 0.6826E-02 -2.166 3.883 0.2626E-02 lawsonite 0.6045E-04 -4.219 0.1900E-01 -1.721 10.81 0.6126E-02 stilbite 0.1652E-03 -3.782 0.1164 -0.934 66.22 0.5430E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1327E-01 0.1327E-01 1.0000 -1.877 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.175803 g Volume = 0.074133 cm3 Porosity: 93.1026% V(tot) - V(min): 0.10007E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1870000 g log = -0.7282 Original solution: 1000.0103000 g Original solution / Rock added: 5347.65 (Water/Rock Ratio), log = 3.7282 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1180E-04 1.0073 0.1250E-04 0.1241E-04 CH4,gas 0.1495E-15 1.0129 0.1593E-15 0.1573E-15 H2,gas 0.5758E-06 1.0006 0.6061E-06 0.6057E-06 H2S,gas 0.7097E-13 0.9959 0.7436E-13 0.7466E-13 S2,gas 0.5360E-33 1.0000 0.5638E-33 0.5638E-33 CO,gas 0.1865E-14 1.0000 0.1962E-14 0.1962E-14 SO3,gas 0.1591E-36 1.0000 0.1674E-36 0.1674E-36 SO2,gas 0.3648E-20 1.0000 0.3837E-20 0.3837E-20 HCl,gas 0.1862E-15 1.0000 0.1959E-15 0.1959E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 164 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.27 -6.90 -2.301 0.11787E+05 -4.903 3 CH4,gas 4.81 -12.99 -17.80 -4.449 0.30389E+05 -15.798 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -21.07 -15.13 -7.564 0.25832E+05 -13.129 6 S2,gas -7.03 -42.28 -35.25 -5.423 0.60187E+05 -33.249 7 CO,gas 3.51 -13.20 -16.71 -5.141 0.28527E+05 -14.707 8 SO3,gas 17.43 -21.35 -38.78 -9.694 0.66210E+05 -36.776 9 SO2,gas 1.14 -21.28 -22.42 -5.978 0.38275E+05 -20.416 10 HCl,gas 5.48 -12.23 -17.71 -8.854 0.30236E+05 -15.708 11 acmite 7.74 4.39 -3.35 -0.348 0.57164E+04 15 albite-high 0.75 -2.55 -3.30 -0.253 0.56270E+04 16 albite -0.33 -2.55 -2.22 -0.171 0.37863E+04 19 spessartine 24.55 20.68 -3.87 -0.193 0.66012E+04 20 analcite 3.37 0.87 -2.50 -0.278 0.42681E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.46 -4.75 -0.264 0.81135E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.31 -3.30 -1.100 0.56364E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.31 -3.15 -1.049 0.53750E+04 38 carnegieite-low 9.06 4.29 -4.78 -0.682 0.81561E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29411E+04 42 celadonite 5.40 1.60 -3.80 -0.223 0.64863E+04 43 celadonite-Fe 3.94 -0.63 -4.56 -0.268 0.77916E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14711E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82450E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68766E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.87 -3.38 -0.338 0.57711E+04 97 kalsilite 7.62 3.29 -4.33 -0.619 0.73926E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.13 -4.29 -0.429 0.73315E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.54 -1.11 -0.085 0.18973E+04 120 muscovite 2.68 2.02 -0.66 -0.039 0.11297E+04 121 paragonite 4.34 3.01 -1.32 -0.078 0.22572E+04 122 nepheline 8.38 4.29 -4.09 -0.584 0.69841E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40551E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.81 -3.85 -1.283 0.65735E+04 153 rhodonite 7.46 5.04 -2.42 -0.484 0.41344E+04 154 sanidine -1.22 -3.54 -2.32 -0.179 0.39651E+04 156 siderite -2.59 -6.93 -4.35 -1.448 0.74192E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.86 -1.32 -0.039 0.22579E+04 166 stilpnomelane-Mg 27.60 23.00 -4.60 -0.137 0.78529E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83656E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 175 tephroite 18.11 13.50 -4.61 -0.659 0.78781E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.77 -3.33 -0.204 0.56872E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.44 -3.18 -0.195 0.54293E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 203 montmorillonite-K -2.16 -4.90 -2.74 -0.168 0.46819E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.57 -2.61 -0.160 0.44622E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.27 -1.13 -0.073 0.19338E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.60 -0.98 -0.063 0.16776E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.10 -2.18 -0.168 0.37227E+04 244 an25ab75 2.71 0.51 -2.20 -0.169 0.37547E+04 245 an30ab70 3.34 1.12 -2.22 -0.171 0.37950E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1870000 g New total amount of reactant added: 0.1910000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1910000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3884212E-03 Osmotic coef. = 0.9883 True ionic strength = .4715624E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.45831E-08 -8.3388 0.43746E-08 -8.3591 0.95449E+00 -0.0202 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13166E-03 -3.8806 0.95429E+00 -0.0203 4 SO4-- 0.25480E-04 -4.5938 0.22305E-04 -4.6516 0.87539E+00 -0.0578 5 HCO3- 0.12666E-04 -4.8974 0.12088E-04 -4.9177 0.95434E+00 -0.0203 6 HS- 0.19379E-12 -12.7127 0.18493E-12 -12.7330 0.95430E+00 -0.0203 7 Al+++ 0.66623E-22 -22.1764 0.50475E-22 -22.2969 0.75763E+00 -0.1205 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.19556E-05 -5.7087 0.17115E-05 -5.7666 0.87517E+00 -0.0579 10 Mg++ 0.79687E-08 -8.0986 0.69729E-08 -8.1566 0.87504E+00 -0.0580 11 Fe++ 0.47134E-10 -10.3267 0.41246E-10 -10.3846 0.87507E+00 -0.0580 12 K+ 0.40536E-04 -4.3922 0.38685E-04 -4.4125 0.95435E+00 -0.0203 13 Na+ 0.39927E-03 -3.3987 0.38102E-03 -3.4191 0.95429E+00 -0.0203 14 Mn++ 0.62782E-08 -8.2022 0.54940E-08 -8.2601 0.87510E+00 -0.0579 15 HPO4-- 0.33663E-07 -7.4729 0.29468E-07 -7.5306 0.87539E+00 -0.0578 16 HSiO3- 0.89503E-04 -4.0482 0.85413E-04 -4.0685 0.95429E+00 -0.0203 17 Ca(HSiO3)+ 0.34320E-08 -8.4645 0.32753E-08 -8.4847 0.95436E+00 -0.0203 18 Mg(HSiO3)+ 0.17401E-10 -10.7594 0.16607E-10 -10.7797 0.95436E+00 -0.0203 19 NaHSiO3,aq 0.51687E-06 -6.2866 0.51687E-06 -6.2866 0.10000E+01 0.0000 20 AlO+ 0.35679E-12 -12.4476 0.34050E-12 -12.4679 0.95436E+00 -0.0203 21 AlOH+2 0.85265E-17 -17.0692 0.74617E-17 -17.1272 0.87512E+00 -0.0579 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.83317E-05 -5.0793 0.79504E-05 -5.0996 0.95423E+00 -0.0203 24 CH4,aq 0.98358E-19 -19.0072 0.98346E-19 -19.0072 0.99988E+00 -0.0001 29 CO,aq 0.12133E-17 -17.9160 0.12133E-17 -17.9160 0.10000E+01 0.0000 30 CO2,aq 0.10663E-06 -6.9721 0.10661E-06 -6.9722 0.99988E+00 -0.0001 31 CO3-2 0.29187E-06 -6.5348 0.25549E-06 -6.5926 0.87533E+00 -0.0578 32 CaCO3,aq 0.53555E-08 -8.2712 0.53555E-08 -8.2712 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.54622E-09 -9.2626 0.52129E-09 -9.2829 0.95436E+00 -0.0203 34 CaCl+ 0.37624E-09 -9.4245 0.35907E-09 -9.4448 0.95436E+00 -0.0203 35 CaCl2,aq 0.11007E-13 -13.9583 0.11007E-13 -13.9583 0.10000E+01 0.0000 36 CaOH+ 0.28907E-07 -7.5390 0.27588E-07 -7.5593 0.95436E+00 -0.0203 37 CaSO4,aq 0.11894E-07 -7.9247 0.11894E-07 -7.9247 0.10000E+01 0.0000 38 HCl,aq 0.10833E-12 -12.9652 0.10833E-12 -12.9652 0.10000E+01 0.0000 43 FeCl+ 0.88623E-14 -14.0525 0.84578E-14 -14.0727 0.95436E+00 -0.0203 46 FeO,aq 0.85231E-10 -10.0694 0.85231E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.32753E-09 -9.4847 0.31258E-09 -9.5050 0.95436E+00 -0.0203 48 HFeO2- 0.21960E-09 -9.6584 0.20956E-09 -9.6787 0.95429E+00 -0.0203 49 FeO+ 0.37918E-13 -13.4212 0.36187E-13 -13.4414 0.95436E+00 -0.0203 50 FeOH+2 0.33660E-19 -19.4729 0.29457E-19 -19.5308 0.87512E+00 -0.0579 51 FeO2- 0.38945E-09 -9.4095 0.37165E-09 -9.4299 0.95429E+00 -0.0203 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44192E-09 -9.3547 0.44186E-09 -9.3547 0.99988E+00 -0.0001 54 KCl,aq 0.90183E-10 -10.0449 0.90183E-10 -10.0449 0.10000E+01 0.0000 55 KHSO4,aq 0.10101E-16 -16.9956 0.10101E-16 -16.9956 0.10000E+01 0.0000 56 KOH,aq 0.38552E-08 -8.4140 0.38552E-08 -8.4140 0.10000E+01 0.0000 57 KSO4- 0.13930E-07 -7.8560 0.13294E-07 -7.8764 0.95429E+00 -0.0203 58 MgCO3,aq 0.54520E-11 -11.2634 0.54520E-11 -11.2634 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22693E-11 -11.6441 0.21657E-11 -11.6644 0.95436E+00 -0.0203 60 MgCl+ 0.13915E-11 -11.8565 0.13280E-11 -11.8768 0.95436E+00 -0.0203 61 MgOH+ 0.65245E-09 -9.1855 0.62267E-09 -9.2057 0.95436E+00 -0.0203 63 MnO,aq 0.30307E-09 -9.5185 0.30307E-09 -9.5185 0.10000E+01 0.0000 64 MnOH+ 0.40528E-08 -8.3922 0.38679E-08 -8.4125 0.95436E+00 -0.0203 65 MnO2-2 0.62570E-15 -15.2036 0.54769E-15 -15.2615 0.87533E+00 -0.0578 66 HMnO2- 0.54397E-12 -12.2644 0.51910E-12 -12.2847 0.95429E+00 -0.0203 69 MnCl+ 0.45871E-11 -11.3385 0.43778E-11 -11.3587 0.95436E+00 -0.0203 70 MnSO4,aq 0.34729E-10 -10.4593 0.34729E-10 -10.4593 0.10000E+01 0.0000 71 NaCl,aq 0.16380E-07 -7.7857 0.16380E-07 -7.7857 0.10000E+01 0.0000 72 NaOH,aq 0.38272E-07 -7.4171 0.38272E-07 -7.4171 0.10000E+01 0.0000 74 OH- 0.14370E-03 -3.8426 0.13712E-03 -3.8629 0.95423E+00 -0.0203 79 HPO3-2 0.46984E-19 -19.3280 0.41127E-19 -19.3859 0.87533E+00 -0.0578 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.23682E-08 -8.6256 0.22600E-08 -8.6459 0.95432E+00 -0.0203 84 PO4-3 0.77517E-11 -11.1106 0.58828E-11 -11.2304 0.75891E+00 -0.1198 87 H2P2O7-2 0.45670E-18 -18.3404 0.39976E-18 -18.3982 0.87533E+00 -0.0578 88 HP2O7-3 0.24733E-16 -16.6067 0.18738E-16 -16.7273 0.75764E+00 -0.1205 89 P2O7-4 0.17054E-17 -17.7682 0.10567E-17 -17.9760 0.61963E+00 -0.2079 90 H2S,aq 0.24310E-14 -14.6142 0.24307E-14 -14.6143 0.99988E+00 -0.0001 97 SO3-2 0.15344E-14 -14.8141 0.13438E-14 -14.8717 0.87576E+00 -0.0576 98 HSO3- 0.36050E-15 -15.4431 0.34402E-15 -15.4634 0.95429E+00 -0.0203 99 HSO4- 0.94861E-10 -10.0229 0.90534E-10 -10.0432 0.95439E+00 -0.0203 Charge balance for all species = 0.7206E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4583131E-08 -.2673551E-03 -.2694608E+00 0.0000 2 H2O 0.1000000E+01 0.5550832E+02 0.9999356E+06 0.0000 3 Cl- 0.1379634E-03 0.1379802E-03 0.4891503E+01 4.4785 4 SO4-- 0.2547964E-04 0.2550556E-04 0.2449949E+01 12.0665 5 HCO3- 0.1266616E-04 0.1307057E-04 0.7974793E+00 3.4414 6 HS- 0.1937913E-12 0.3655533E-10 0.1208881E-05 -4.3739 7 Al+++ 0.6662252E-22 0.8347256E-05 0.2252072E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4729842E-03 0.4545818E+02 -3.4168 9 Ca++ 0.1955638E-05 0.2006149E-05 0.8039735E-01 10.9515 10 Mg++ 0.7968654E-08 0.8647622E-08 0.2102276E-03 8.5615 11 Fe++ 0.4713437E-10 0.1272465E-08 0.7105883E-04 6.3335 12 K+ 0.4053593E-04 0.4055380E-04 0.1585634E+01 3.9466 13 Na+ 0.3992686E-03 0.3998401E-03 0.9191661E+01 4.9400 14 Mn++ 0.6278180E-08 0.1067395E-07 0.5863684E-03 8.4580 15 HPO4-- 0.3366251E-07 0.3603848E-07 0.3458717E-02 9.1875 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3149636E-02 -.2673434E-03 -.2882293E-02 0.0000000E+00 2 H2O 0.5550586E+02 0.5550588E+02 -.2270639E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3079773E-04 0.2550443E-04 0.5293298E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5293261E-05 0.3655372E-10 -.5293298E-05 0.0000000E+00 7 Al+++ 0.6228016E-03 0.8346889E-05 0.6144548E-03 0.0000000E+00 8 H4SiO4 0.1988842E-02 0.4729634E-03 0.1515878E-02 0.0000000E+00 9 Ca++ 0.2341483E-03 0.2006061E-05 0.2321422E-03 0.0000000E+00 10 Mg++ 0.1515873E-03 0.8647242E-08 0.1515787E-03 0.0000000E+00 11 Fe++ 0.1361846E-03 0.1272409E-08 0.1361834E-03 0.0000000E+00 12 K+ 0.4055202E-04 0.4055202E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.3998225E-03 0.3998225E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3311672E-05 0.1067348E-07 0.3300998E-05 0.0000000E+00 15 HPO4-- 0.1130257E-05 0.3603689E-07 0.1094220E-05 0.0000000E+00 Chg. balance for solid moles: 0.3901E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1910000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3647E-06 -6.438 0.1832E-03 -3.737 0.1017 0.5822E-04 clinochlore 0.3032E-04 -4.518 0.1685E-01 -1.773 9.352 0.6409E-02 daphnite 0.1877E-04 -4.727 0.1339E-01 -1.873 7.432 0.4058E-02 chlorite-Mn 0.6602E-06 -6.180 0.4681E-03 -3.330 0.2598 0.1492E-03 hematite 0.2117E-04 -4.674 0.3381E-02 -2.471 1.877 0.6409E-03 kaolinite 0.2717E-04 -4.566 0.7013E-02 -2.154 3.892 0.2698E-02 lawsonite 0.5998E-04 -4.222 0.1885E-01 -1.725 10.46 0.6078E-02 stilbite 0.1703E-03 -3.769 0.1200 -0.921 66.62 0.5599E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1327E-01 0.1327E-01 1.0000 -1.877 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.180175 g Volume = 0.076081 cm3 Porosity: 92.9319% V(tot) - V(min): 0.10003E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1910000 g log = -0.7190 Original solution: 1000.0103000 g Original solution / Rock added: 5235.66 (Water/Rock Ratio), log = 3.7190 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1152E-04 1.0073 0.1220E-04 0.1212E-04 CH4,gas 0.1460E-15 1.0129 0.1555E-15 0.1535E-15 H2,gas 0.5758E-06 1.0006 0.6060E-06 0.6057E-06 H2S,gas 0.6767E-13 0.9959 0.7089E-13 0.7118E-13 S2,gas 0.4872E-33 1.0000 0.5125E-33 0.5125E-33 CO,gas 0.1821E-14 1.0000 0.1916E-14 0.1916E-14 SO3,gas 0.1517E-36 1.0000 0.1596E-36 0.1596E-36 SO2,gas 0.3478E-20 1.0000 0.3659E-20 0.3659E-20 HCl,gas 0.1818E-15 1.0000 0.1913E-15 0.1913E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 164 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.28 -6.91 -2.304 0.11805E+05 -4.913 3 CH4,gas 4.81 -13.00 -17.81 -4.452 0.30407E+05 -15.808 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -21.09 -15.15 -7.575 0.25867E+05 -13.149 6 S2,gas -7.03 -42.32 -35.29 -5.429 0.60257E+05 -33.290 7 CO,gas 3.51 -13.21 -16.72 -5.144 0.28545E+05 -14.718 8 SO3,gas 17.43 -21.37 -38.80 -9.699 0.66245E+05 -36.797 9 SO2,gas 1.14 -21.30 -22.44 -5.983 0.38310E+05 -20.437 10 HCl,gas 5.48 -12.24 -17.72 -8.859 0.30254E+05 -15.718 11 acmite 7.74 4.41 -3.33 -0.346 0.56898E+04 15 albite-high 0.75 -2.53 -3.28 -0.252 0.56003E+04 16 albite -0.33 -2.53 -2.20 -0.169 0.37597E+04 19 spessartine 24.55 20.68 -3.87 -0.193 0.66008E+04 20 analcite 3.37 0.89 -2.48 -0.276 0.42414E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.48 -4.73 -0.263 0.80805E+04 27 phlogopite 27.15 22.16 -4.99 -0.277 0.85128E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.33 -3.31 -1.104 0.56542E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.33 -3.16 -1.053 0.53928E+04 38 carnegieite-low 9.06 4.30 -4.76 -0.680 0.81295E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 1.62 -3.78 -0.222 0.64533E+04 43 celadonite-Fe 3.94 -0.61 -4.54 -0.267 0.77586E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14710E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82450E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68766E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.89 -3.36 -0.336 0.57445E+04 97 kalsilite 7.62 3.31 -4.31 -0.616 0.73596E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.11 -4.27 -0.427 0.72985E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.52 -1.09 -0.084 0.18643E+04 120 muscovite 2.68 2.04 -0.64 -0.038 0.10967E+04 121 paragonite 4.34 3.03 -1.31 -0.077 0.22305E+04 122 nepheline 8.38 4.30 -4.07 -0.582 0.69574E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40550E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.82 -3.86 -1.287 0.65911E+04 153 rhodonite 7.46 5.04 -2.42 -0.484 0.41342E+04 154 sanidine -1.22 -3.52 -2.30 -0.177 0.39321E+04 156 siderite -2.59 -6.94 -4.36 -1.452 0.74370E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.87 -1.31 -0.039 0.22414E+04 166 stilpnomelane-Mg 27.60 23.01 -4.59 -0.137 0.78364E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83656E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 175 tephroite 18.11 13.50 -4.61 -0.659 0.78778E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.76 -3.32 -0.204 0.56763E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.43 -3.17 -0.194 0.54205E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 203 montmorillonite-K -2.16 -4.90 -2.74 -0.168 0.46711E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.57 -2.61 -0.160 0.44534E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.28 -1.13 -0.072 0.19229E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.61 -0.98 -0.063 0.16688E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.09 -2.17 -0.167 0.37013E+04 244 an25ab75 2.71 0.52 -2.19 -0.168 0.37347E+04 245 an30ab70 3.34 1.13 -2.21 -0.170 0.37763E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1910000 g New total amount of reactant added: 0.1950000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1950000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3920611E-03 Osmotic coef. = 0.9883 True ionic strength = .4771584E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.44796E-08 -8.3488 0.42751E-08 -8.3691 0.95434E+00 -0.0203 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13164E-03 -3.8806 0.95414E+00 -0.0204 4 SO4-- 0.25480E-04 -4.5938 0.22290E-04 -4.6519 0.87481E+00 -0.0581 5 HCO3- 0.12662E-04 -4.8975 0.12082E-04 -4.9179 0.95418E+00 -0.0204 6 HS- 0.18929E-12 -12.7229 0.18061E-12 -12.7433 0.95414E+00 -0.0204 7 Al+++ 0.62273E-22 -22.2057 0.47109E-22 -22.3269 0.75650E+00 -0.1212 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.18689E-05 -5.7284 0.16346E-05 -5.7866 0.87460E+00 -0.0582 10 Mg++ 0.76154E-08 -8.1183 0.66594E-08 -8.1766 0.87446E+00 -0.0583 11 Fe++ 0.45045E-10 -10.3464 0.39391E-10 -10.4046 0.87449E+00 -0.0582 12 K+ 0.41385E-04 -4.3832 0.39489E-04 -4.4035 0.95419E+00 -0.0204 13 Na+ 0.40427E-03 -3.3933 0.38573E-03 -3.4137 0.95413E+00 -0.0204 14 Mn++ 0.60009E-08 -8.2218 0.52479E-08 -8.2800 0.87452E+00 -0.0582 15 HPO4-- 0.35270E-07 -7.4526 0.30855E-07 -7.5107 0.87482E+00 -0.0581 16 HSiO3- 0.91601E-04 -4.0381 0.87400E-04 -4.0585 0.95414E+00 -0.0204 17 Ca(HSiO3)+ 0.33545E-08 -8.4744 0.32008E-08 -8.4947 0.95420E+00 -0.0204 18 Mg(HSiO3)+ 0.17008E-10 -10.7693 0.16229E-10 -10.7897 0.95420E+00 -0.0204 19 NaHSiO3,aq 0.53544E-06 -6.2713 0.53544E-06 -6.2713 0.10000E+01 0.0000 20 AlO+ 0.34873E-12 -12.4575 0.33276E-12 -12.4779 0.95420E+00 -0.0204 21 AlOH+2 0.81485E-17 -17.0889 0.71262E-17 -17.1471 0.87454E+00 -0.0582 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.85270E-05 -5.0692 0.81354E-05 -5.0896 0.95408E+00 -0.0204 24 CH4,aq 0.96070E-19 -19.0174 0.96059E-19 -19.0175 0.99988E+00 -0.0001 29 CO,aq 0.11851E-17 -17.9262 0.11851E-17 -17.9262 0.10000E+01 0.0000 30 CO2,aq 0.10415E-06 -6.9823 0.10414E-06 -6.9824 0.99988E+00 -0.0001 31 CO3-2 0.29871E-06 -6.5247 0.26130E-06 -6.5829 0.87475E+00 -0.0581 32 CaCO3,aq 0.52311E-08 -8.2814 0.52311E-08 -8.2814 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.52149E-09 -9.2828 0.49761E-09 -9.3031 0.95420E+00 -0.0204 34 CaCl+ 0.35933E-09 -9.4445 0.34287E-09 -9.4649 0.95420E+00 -0.0204 35 CaCl2,aq 0.10509E-13 -13.9784 0.10509E-13 -13.9784 0.10000E+01 0.0000 36 CaOH+ 0.28255E-07 -7.5489 0.26960E-07 -7.5693 0.95420E+00 -0.0204 37 CaSO4,aq 0.11352E-07 -7.9449 0.11352E-07 -7.9449 0.10000E+01 0.0000 38 HCl,aq 0.10585E-12 -12.9753 0.10585E-12 -12.9753 0.10000E+01 0.0000 43 FeCl+ 0.84638E-14 -14.0724 0.80762E-14 -14.0928 0.95420E+00 -0.0204 46 FeO,aq 0.85230E-10 -10.0694 0.85230E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.32013E-09 -9.4947 0.30547E-09 -9.5150 0.95420E+00 -0.0204 48 HFeO2- 0.22475E-09 -9.6483 0.21444E-09 -9.6687 0.95414E+00 -0.0204 49 FeO+ 0.37062E-13 -13.4311 0.35364E-13 -13.4514 0.95420E+00 -0.0204 50 FeOH+2 0.32168E-19 -19.4926 0.28132E-19 -19.5508 0.87454E+00 -0.0582 51 FeO2- 0.39858E-09 -9.3995 0.38030E-09 -9.4199 0.95414E+00 -0.0204 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44191E-09 -9.3547 0.44186E-09 -9.3547 0.99988E+00 -0.0001 54 KCl,aq 0.92041E-10 -10.0360 0.92041E-10 -10.0360 0.10000E+01 0.0000 55 KHSO4,aq 0.10070E-16 -16.9970 0.10070E-16 -16.9970 0.10000E+01 0.0000 56 KOH,aq 0.40269E-08 -8.3950 0.40269E-08 -8.3950 0.10000E+01 0.0000 57 KSO4- 0.14213E-07 -7.8473 0.13561E-07 -7.8677 0.95414E+00 -0.0204 58 MgCO3,aq 0.53254E-11 -11.2736 0.53254E-11 -11.2736 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21665E-11 -11.6642 0.20673E-11 -11.6846 0.95420E+00 -0.0204 60 MgCl+ 0.13290E-11 -11.8765 0.12681E-11 -11.8968 0.95420E+00 -0.0204 61 MgOH+ 0.63772E-09 -9.1954 0.60851E-09 -9.2157 0.95420E+00 -0.0204 63 MnO,aq 0.30312E-09 -9.5184 0.30312E-09 -9.5184 0.10000E+01 0.0000 64 MnOH+ 0.39620E-08 -8.4021 0.37806E-08 -8.4224 0.95420E+00 -0.0204 65 MnO2-2 0.65570E-15 -15.1833 0.57357E-15 -15.2414 0.87475E+00 -0.0581 66 HMnO2- 0.55681E-12 -12.2543 0.53127E-12 -12.2747 0.95414E+00 -0.0204 69 MnCl+ 0.43816E-11 -11.3584 0.41810E-11 -11.3787 0.95420E+00 -0.0204 70 MnSO4,aq 0.33151E-10 -10.4795 0.33151E-10 -10.4795 0.10000E+01 0.0000 71 NaCl,aq 0.16579E-07 -7.7804 0.16579E-07 -7.7804 0.10000E+01 0.0000 72 NaOH,aq 0.39646E-07 -7.4018 0.39646E-07 -7.4018 0.10000E+01 0.0000 74 OH- 0.14706E-03 -3.8325 0.14031E-03 -3.8529 0.95408E+00 -0.0204 79 HPO3-2 0.49228E-19 -19.3078 0.43062E-19 -19.3659 0.87475E+00 -0.0581 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.24237E-08 -8.6155 0.23126E-08 -8.6359 0.95417E+00 -0.0204 84 PO4-3 0.83177E-11 -11.0800 0.63031E-11 -11.2004 0.75779E+00 -0.1204 87 H2P2O7-2 0.47852E-18 -18.3201 0.41858E-18 -18.3782 0.87475E+00 -0.0581 88 HP2O7-3 0.26539E-16 -16.5761 0.20077E-16 -16.6973 0.75651E+00 -0.1212 89 P2O7-4 0.18747E-17 -17.7271 0.11586E-17 -17.9361 0.61800E+00 -0.2090 90 H2S,aq 0.23201E-14 -14.6345 0.23198E-14 -14.6345 0.99988E+00 -0.0001 97 SO3-2 0.15344E-14 -14.8141 0.13429E-14 -14.8720 0.87519E+00 -0.0579 98 HSO3- 0.35213E-15 -15.4533 0.33598E-15 -15.4737 0.95414E+00 -0.0204 99 HSO4- 0.92659E-10 -10.0331 0.88418E-10 -10.0535 0.95423E+00 -0.0203 Charge balance for all species = 0.7204E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4479649E-08 -.2736306E-03 -.2757856E+00 0.0000 2 H2O 0.1000000E+01 0.5550832E+02 0.9999352E+06 0.0000 3 Cl- 0.1379633E-03 0.1379804E-03 0.4891505E+01 4.4884 4 SO4-- 0.2547992E-04 0.2550558E-04 0.2449950E+01 12.0862 5 HCO3- 0.1266196E-04 0.1307059E-04 0.7974796E+00 3.4512 6 HS- 0.1892870E-12 0.3540901E-10 0.1170972E-05 -4.3742 7 Al+++ 0.6227290E-22 0.8542539E-05 0.2304758E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4751004E-03 0.4566155E+02 -3.4168 9 Ca++ 0.1868948E-05 0.1918021E-05 0.7686553E-01 10.9515 10 Mg++ 0.7615422E-08 0.8278973E-08 0.2012656E-03 8.5615 11 Fe++ 0.4504485E-10 0.1277252E-08 0.7132611E-04 6.3335 12 K+ 0.4138480E-04 0.4140313E-04 0.1618842E+01 3.9655 13 Na+ 0.4042700E-03 0.4048616E-03 0.9307094E+01 4.9553 14 Mn++ 0.6000913E-08 0.1030414E-07 0.5660530E-03 8.4581 15 HPO4-- 0.3527048E-07 0.3770252E-07 0.3618419E-02 9.2274 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3215871E-02 -.2736184E-03 -.2942252E-02 0.0000000E+00 2 H2O 0.5550581E+02 0.5550584E+02 -.3117211E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3090858E-04 0.2550443E-04 0.5404150E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5404115E-05 0.3540742E-10 -.5404150E-05 0.0000000E+00 7 Al+++ 0.6358446E-03 0.8542157E-05 0.6273025E-03 0.0000000E+00 8 H4SiO4 0.2030493E-02 0.4750792E-03 0.1555413E-02 0.0000000E+00 9 Ca++ 0.2387489E-03 0.1917935E-05 0.2368309E-03 0.0000000E+00 10 Mg++ 0.1547619E-03 0.8278603E-08 0.1547536E-03 0.0000000E+00 11 Fe++ 0.1390367E-03 0.1277194E-08 0.1390354E-03 0.0000000E+00 12 K+ 0.4140127E-04 0.4140127E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.4048435E-03 0.4048435E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3381026E-05 0.1030368E-07 0.3370723E-05 0.0000000E+00 15 HPO4-- 0.1153927E-05 0.3770083E-07 0.1116227E-05 0.0000000E+00 Chg. balance for solid moles: 0.6903E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1950000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3721E-06 -6.429 0.1869E-03 -3.728 0.1013 0.5939E-04 clinochlore 0.3095E-04 -4.509 0.1720E-01 -1.764 9.322 0.6544E-02 daphnite 0.1916E-04 -4.718 0.1367E-01 -1.864 7.408 0.4143E-02 chlorite-Mn 0.6741E-06 -6.171 0.4779E-03 -3.321 0.2590 0.1523E-03 hematite 0.2162E-04 -4.665 0.3452E-02 -2.462 1.871 0.6543E-03 kaolinite 0.2790E-04 -4.554 0.7201E-02 -2.143 3.902 0.2771E-02 lawsonite 0.5951E-04 -4.225 0.1870E-01 -1.728 10.13 0.6030E-02 stilbite 0.1755E-03 -3.756 0.1237 -0.908 67.00 0.5767E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1327E-01 0.1327E-01 1.0000 -1.877 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.184546 g Volume = 0.078028 cm3 Porosity: 92.7618% V(tot) - V(min): 0.99997E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1950000 g log = -0.7100 Original solution: 1000.0103000 g Original solution / Rock added: 5128.26 (Water/Rock Ratio), log = 3.7100 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1125E-04 1.0073 0.1192E-04 0.1183E-04 CH4,gas 0.1426E-15 1.0129 0.1519E-15 0.1500E-15 H2,gas 0.5758E-06 1.0006 0.6060E-06 0.6057E-06 H2S,gas 0.6458E-13 0.9959 0.6766E-13 0.6794E-13 S2,gas 0.4438E-33 1.0000 0.4668E-33 0.4668E-33 CO,gas 0.1779E-14 1.0000 0.1871E-14 0.1871E-14 SO3,gas 0.1448E-36 1.0000 0.1523E-36 0.1523E-36 SO2,gas 0.3319E-20 1.0000 0.3492E-20 0.3492E-20 HCl,gas 0.1777E-15 1.0000 0.1869E-15 0.1869E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.66728E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.48529E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 164 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.29 -6.92 -2.308 0.11822E+05 -4.924 3 CH4,gas 4.81 -13.01 -17.82 -4.455 0.30424E+05 -15.818 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.217 5 H2S,gas -5.94 -21.11 -15.17 -7.585 0.25902E+05 -13.170 6 S2,gas -7.03 -42.36 -35.33 -5.436 0.60326E+05 -33.331 7 CO,gas 3.51 -13.22 -16.73 -5.147 0.28562E+05 -14.728 8 SO3,gas 17.43 -21.39 -38.82 -9.704 0.66279E+05 -36.817 9 SO2,gas 1.14 -21.32 -22.46 -5.989 0.38345E+05 -20.457 10 HCl,gas 5.48 -12.25 -17.73 -8.864 0.30271E+05 -15.728 11 acmite 7.74 4.42 -3.32 -0.345 0.56636E+04 15 albite-high 0.75 -2.51 -3.26 -0.251 0.55742E+04 16 albite -0.33 -2.51 -2.19 -0.168 0.37335E+04 19 spessartine 24.55 20.68 -3.87 -0.193 0.66004E+04 20 analcite 3.37 0.90 -2.47 -0.274 0.42153E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.50 -4.71 -0.262 0.80482E+04 27 phlogopite 27.15 22.18 -4.97 -0.276 0.84805E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.34 -3.32 -1.107 0.56716E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.34 -3.17 -1.056 0.54103E+04 38 carnegieite-low 9.06 4.32 -4.75 -0.678 0.81033E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 1.64 -3.76 -0.221 0.64210E+04 43 celadonite-Fe 3.94 -0.59 -4.53 -0.266 0.77263E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14708E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82450E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68766E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.90 -3.35 -0.335 0.57183E+04 97 kalsilite 7.62 3.33 -4.29 -0.613 0.73273E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.09 -4.26 -0.426 0.72662E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.50 -1.07 -0.083 0.18320E+04 120 muscovite 2.68 2.06 -0.62 -0.037 0.10644E+04 121 paragonite 4.34 3.05 -1.29 -0.076 0.22044E+04 122 nepheline 8.38 4.32 -4.06 -0.580 0.69312E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40549E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.83 -3.87 -1.290 0.66084E+04 153 rhodonite 7.46 5.04 -2.42 -0.484 0.41341E+04 154 sanidine -1.22 -3.50 -2.28 -0.176 0.38998E+04 156 siderite -2.59 -6.95 -4.37 -1.455 0.74544E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.88 -1.30 -0.039 0.22253E+04 166 stilpnomelane-Mg 27.60 23.02 -4.58 -0.137 0.78202E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 175 tephroite 18.11 13.50 -4.61 -0.659 0.78775E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.75 -3.32 -0.203 0.56656E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.43 -3.17 -0.194 0.54118E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 203 montmorillonite-K -2.16 -4.89 -2.73 -0.167 0.46604E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.56 -2.60 -0.159 0.44448E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.28 -1.12 -0.072 0.19122E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.61 -0.97 -0.062 0.16601E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.08 -2.16 -0.166 0.36804E+04 244 an25ab75 2.71 0.53 -2.18 -0.167 0.37150E+04 245 an30ab70 3.34 1.14 -2.20 -0.169 0.37580E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1950000 g New total amount of reactant added: 0.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7205E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1990000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3957141E-03 Osmotic coef. = 0.9882 True ionic strength = .4827710E-03 Chg. balance for total moles = 0.7205E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.43806E-08 -8.3585 0.41799E-08 -8.3788 0.95418E+00 -0.0204 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13161E-03 -3.8807 0.95398E+00 -0.0205 4 SO4-- 0.25480E-04 -4.5938 0.22276E-04 -4.6522 0.87424E+00 -0.0584 5 HCO3- 0.12658E-04 -4.8976 0.12076E-04 -4.9181 0.95403E+00 -0.0204 6 HS- 0.18498E-12 -12.7329 0.17646E-12 -12.7533 0.95398E+00 -0.0205 7 Al+++ 0.58291E-22 -22.2344 0.44032E-22 -22.3562 0.75538E+00 -0.1218 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.17878E-05 -5.7477 0.15626E-05 -5.8062 0.87402E+00 -0.0585 10 Mg++ 0.72848E-08 -8.1376 0.63661E-08 -8.1961 0.87388E+00 -0.0585 11 Fe++ 0.43089E-10 -10.3656 0.37656E-10 -10.4242 0.87391E+00 -0.0585 12 K+ 0.42234E-04 -4.3743 0.40292E-04 -4.3948 0.95403E+00 -0.0204 13 Na+ 0.40927E-03 -3.3880 0.39043E-03 -3.4085 0.95397E+00 -0.0205 14 Mn++ 0.57413E-08 -8.2410 0.50176E-08 -8.2995 0.87394E+00 -0.0585 15 HPO4-- 0.36920E-07 -7.4327 0.32277E-07 -7.4911 0.87424E+00 -0.0584 16 HSiO3- 0.93703E-04 -4.0282 0.89391E-04 -4.0487 0.95398E+00 -0.0205 17 Ca(HSiO3)+ 0.32803E-08 -8.4841 0.31296E-08 -8.5045 0.95404E+00 -0.0204 18 Mg(HSiO3)+ 0.16632E-10 -10.7791 0.15868E-10 -10.7995 0.95404E+00 -0.0204 19 NaHSiO3,aq 0.55431E-06 -6.2562 0.55431E-06 -6.2562 0.10000E+01 0.0000 20 AlO+ 0.34102E-12 -12.4672 0.32535E-12 -12.4876 0.95404E+00 -0.0204 21 AlOH+2 0.77948E-17 -17.1082 0.68124E-17 -17.1667 0.87397E+00 -0.0585 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.87226E-05 -5.0594 0.83207E-05 -5.0798 0.95392E+00 -0.0205 24 CH4,aq 0.93880E-19 -19.0274 0.93869E-19 -19.0275 0.99988E+00 -0.0001 29 CO,aq 0.11581E-17 -17.9362 0.11581E-17 -17.9362 0.10000E+01 0.0000 30 CO2,aq 0.10178E-06 -6.9923 0.10177E-06 -6.9924 0.99988E+00 -0.0001 31 CO3-2 0.30556E-06 -6.5149 0.26712E-06 -6.5733 0.87417E+00 -0.0584 32 CaCO3,aq 0.51120E-08 -8.2914 0.51120E-08 -8.2914 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.49835E-09 -9.3025 0.47545E-09 -9.3229 0.95404E+00 -0.0204 34 CaCl+ 0.34350E-09 -9.4641 0.32771E-09 -9.4845 0.95404E+00 -0.0204 35 CaCl2,aq 0.10043E-13 -13.9982 0.10043E-13 -13.9982 0.10000E+01 0.0000 36 CaOH+ 0.27630E-07 -7.5586 0.26360E-07 -7.5791 0.95404E+00 -0.0204 37 CaSO4,aq 0.10845E-07 -7.9648 0.10845E-07 -7.9648 0.10000E+01 0.0000 38 HCl,aq 0.10348E-12 -12.9852 0.10348E-12 -12.9852 0.10000E+01 0.0000 43 FeCl+ 0.80910E-14 -14.0920 0.77192E-14 -14.1124 0.95404E+00 -0.0204 46 FeO,aq 0.85230E-10 -10.0694 0.85230E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.31306E-09 -9.5044 0.29867E-09 -9.5248 0.95404E+00 -0.0204 48 HFeO2- 0.22990E-09 -9.6385 0.21932E-09 -9.6589 0.95398E+00 -0.0205 49 FeO+ 0.36242E-13 -13.4408 0.34577E-13 -13.4612 0.95404E+00 -0.0204 50 FeOH+2 0.30772E-19 -19.5118 0.26893E-19 -19.5704 0.87397E+00 -0.0585 51 FeO2- 0.40773E-09 -9.3896 0.38896E-09 -9.4101 0.95398E+00 -0.0205 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44191E-09 -9.3547 0.44185E-09 -9.3547 0.99988E+00 -0.0001 54 KCl,aq 0.93898E-10 -10.0273 0.93898E-10 -10.0273 0.10000E+01 0.0000 55 KHSO4,aq 0.10039E-16 -16.9983 0.10039E-16 -16.9983 0.10000E+01 0.0000 56 KOH,aq 0.42024E-08 -8.3765 0.42024E-08 -8.3765 0.10000E+01 0.0000 57 KSO4- 0.14495E-07 -7.8388 0.13828E-07 -7.8592 0.95398E+00 -0.0205 58 MgCO3,aq 0.52042E-11 -11.2836 0.52042E-11 -11.2836 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20704E-11 -11.6839 0.19752E-11 -11.7044 0.95404E+00 -0.0204 60 MgCl+ 0.12704E-11 -11.8960 0.12121E-11 -11.9165 0.95404E+00 -0.0204 61 MgOH+ 0.62362E-09 -9.2051 0.59496E-09 -9.2255 0.95404E+00 -0.0204 63 MnO,aq 0.30317E-09 -9.5183 0.30317E-09 -9.5183 0.10000E+01 0.0000 64 MnOH+ 0.38750E-08 -8.4117 0.36970E-08 -8.4322 0.95404E+00 -0.0204 65 MnO2-2 0.68647E-15 -15.1634 0.60010E-15 -15.2218 0.87417E+00 -0.0584 66 HMnO2- 0.56968E-12 -12.2444 0.54346E-12 -12.2648 0.95398E+00 -0.0205 69 MnCl+ 0.41893E-11 -11.3779 0.39968E-11 -11.3983 0.95404E+00 -0.0204 70 MnSO4,aq 0.31676E-10 -10.4993 0.31676E-10 -10.4993 0.10000E+01 0.0000 71 NaCl,aq 0.16779E-07 -7.7752 0.16779E-07 -7.7752 0.10000E+01 0.0000 72 NaOH,aq 0.41044E-07 -7.3867 0.41044E-07 -7.3867 0.10000E+01 0.0000 74 OH- 0.15044E-03 -3.8226 0.14351E-03 -3.8431 0.95392E+00 -0.0205 79 HPO3-2 0.51530E-19 -19.2879 0.45046E-19 -19.3463 0.87417E+00 -0.0584 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.24793E-08 -8.6057 0.23653E-08 -8.6261 0.95401E+00 -0.0204 84 PO4-3 0.89121E-11 -11.0500 0.67437E-11 -11.1711 0.75669E+00 -0.1211 87 H2P2O7-2 0.50089E-18 -18.3003 0.43787E-18 -18.3587 0.87417E+00 -0.0584 88 HP2O7-3 0.28436E-16 -16.5461 0.21480E-16 -16.6680 0.75539E+00 -0.1218 89 P2O7-4 0.20568E-17 -17.6868 0.12678E-17 -17.8970 0.61637E+00 -0.2102 90 H2S,aq 0.22164E-14 -14.6543 0.22162E-14 -14.6544 0.99988E+00 -0.0001 97 SO3-2 0.15344E-14 -14.8141 0.13420E-14 -14.8722 0.87462E+00 -0.0582 98 HSO3- 0.34412E-15 -15.4633 0.32828E-15 -15.4838 0.95398E+00 -0.0205 99 HSO4- 0.90552E-10 -10.0431 0.86393E-10 -10.0635 0.95407E+00 -0.0204 Charge balance for all species = 0.7204E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4380606E-08 -.2799185E-03 -.2821229E+00 0.0000 2 H2O 0.1000000E+01 0.5550832E+02 0.9999349E+06 0.0000 3 Cl- 0.1379632E-03 0.1379805E-03 0.4891507E+01 4.4981 4 SO4-- 0.2548017E-04 0.2550560E-04 0.2449951E+01 12.1055 5 HCO3- 0.1265763E-04 0.1307060E-04 0.7974799E+00 3.4607 6 HS- 0.1849768E-12 0.3426075E-10 0.1132999E-05 -4.3745 7 Al+++ 0.5829096E-22 0.8738202E-05 0.2357546E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4772211E-03 0.4586535E+02 -3.4168 9 Ca++ 0.1787814E-05 0.1835523E-05 0.7355938E-01 10.9515 10 Mg++ 0.7284831E-08 0.7933631E-08 0.1928701E-03 8.5615 11 Fe++ 0.4308928E-10 0.1282517E-08 0.7162015E-04 6.3335 12 K+ 0.4223366E-04 0.4225246E-04 0.1652049E+01 3.9841 13 Na+ 0.4092710E-03 0.4098832E-03 0.9422527E+01 4.9704 14 Mn++ 0.5741320E-08 0.9955966E-08 0.5469257E-03 8.4582 15 HPO4-- 0.3691968E-07 0.3940793E-07 0.3782090E-02 9.2666 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3282105E-02 -.2799057E-03 -.3002199E-02 0.0000000E+00 2 H2O 0.5550576E+02 0.5550580E+02 -.3963966E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3101944E-04 0.2550444E-04 0.5515003E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5514968E-05 0.3425919E-10 -.5515003E-05 0.0000000E+00 7 Al+++ 0.6488876E-03 0.8737804E-05 0.6401498E-03 0.0000000E+00 8 H4SiO4 0.2072144E-02 0.4771994E-03 0.1594944E-02 0.0000000E+00 9 Ca++ 0.2433494E-03 0.1835440E-05 0.2415140E-03 0.0000000E+00 10 Mg++ 0.1579365E-03 0.7933270E-08 0.1579286E-03 0.0000000E+00 11 Fe++ 0.1418887E-03 0.1282459E-08 0.1418874E-03 0.0000000E+00 12 K+ 0.4225053E-04 0.4225053E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.4098645E-03 0.4098645E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3450381E-05 0.9955512E-08 0.3440425E-05 0.0000000E+00 15 HPO4-- 0.1177598E-05 0.3940613E-07 0.1138192E-05 0.0000000E+00 Chg. balance for solid moles: 0.5743E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3794E-06 -6.421 0.1906E-03 -3.720 0.1009 0.6056E-04 clinochlore 0.3159E-04 -4.501 0.1756E-01 -1.756 9.293 0.6678E-02 daphnite 0.1955E-04 -4.709 0.1395E-01 -1.855 7.385 0.4228E-02 chlorite-Mn 0.6881E-06 -6.162 0.4878E-03 -3.312 0.2582 0.1555E-03 hematite 0.2206E-04 -4.656 0.3523E-02 -2.453 1.865 0.6677E-03 kaolinite 0.2863E-04 -4.543 0.7391E-02 -2.131 3.912 0.2844E-02 lawsonite 0.5902E-04 -4.229 0.1855E-01 -1.732 9.818 0.5981E-02 stilbite 0.1806E-03 -3.743 0.1273 -0.895 67.37 0.5936E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1328E-01 0.1328E-01 1.0000 -1.877 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.188916 g Volume = 0.079974 cm3 Porosity: 92.5922% V(tot) - V(min): 0.99963E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1990000 g log = -0.7011 Original solution: 1000.0103000 g Original solution / Rock added: 5025.18 (Water/Rock Ratio), log = 3.7012 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1099E-04 1.0073 0.1165E-04 0.1156E-04 CH4,gas 0.1393E-15 1.0129 0.1484E-15 0.1465E-15 H2,gas 0.5758E-06 1.0006 0.6060E-06 0.6057E-06 H2S,gas 0.6170E-13 0.9959 0.6464E-13 0.6490E-13 S2,gas 0.4050E-33 1.0000 0.4261E-33 0.4261E-33 CO,gas 0.1738E-14 1.0000 0.1829E-14 0.1829E-14 SO3,gas 0.1383E-36 1.0000 0.1455E-36 0.1455E-36 SO2,gas 0.3171E-20 1.0000 0.3336E-20 0.3336E-20 HCl,gas 0.1737E-15 1.0000 0.1827E-15 0.1827E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 164 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.30 -6.93 -2.311 0.11839E+05 -4.934 3 CH4,gas 4.81 -13.02 -17.83 -4.457 0.30442E+05 -15.828 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.13 -15.19 -7.595 0.25936E+05 -13.190 6 S2,gas -7.03 -42.40 -35.37 -5.442 0.60394E+05 -33.371 7 CO,gas 3.51 -13.23 -16.74 -5.150 0.28579E+05 -14.738 8 SO3,gas 17.43 -21.41 -38.84 -9.709 0.66313E+05 -36.837 9 SO2,gas 1.14 -21.34 -22.48 -5.994 0.38379E+05 -20.477 10 HCl,gas 5.48 -12.26 -17.74 -8.869 0.30288E+05 -15.738 11 acmite 7.74 4.44 -3.30 -0.343 0.56379E+04 15 albite-high 0.75 -2.50 -3.25 -0.250 0.55485E+04 16 albite -0.33 -2.50 -2.17 -0.167 0.37078E+04 19 spessartine 24.55 20.68 -3.87 -0.193 0.66000E+04 20 analcite 3.37 0.92 -2.45 -0.273 0.41896E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.51 -4.70 -0.261 0.80166E+04 27 phlogopite 27.15 22.20 -4.95 -0.275 0.84489E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.35 -3.33 -1.111 0.56887E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.35 -3.18 -1.060 0.54273E+04 38 carnegieite-low 9.06 4.33 -4.73 -0.676 0.80776E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 1.66 -3.74 -0.220 0.63894E+04 43 celadonite-Fe 3.94 -0.57 -4.51 -0.265 0.76947E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14707E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82450E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68766E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.92 -3.33 -0.333 0.56926E+04 97 kalsilite 7.62 3.35 -4.27 -0.610 0.72956E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.07 -4.24 -0.424 0.72346E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.49 -1.05 -0.081 0.18004E+04 120 muscovite 2.68 2.07 -0.60 -0.036 0.10328E+04 121 paragonite 4.34 3.06 -1.28 -0.075 0.21787E+04 122 nepheline 8.38 4.33 -4.04 -0.578 0.69055E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40548E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodochrosite -0.96 -4.84 -3.88 -1.293 0.66254E+04 153 rhodonite 7.46 5.04 -2.42 -0.484 0.41340E+04 154 sanidine -1.22 -3.49 -2.27 -0.174 0.38681E+04 156 siderite -2.59 -6.96 -4.38 -1.459 0.74715E+04 157 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 165 stilpnomelane-Fe 13.18 11.89 -1.29 -0.039 0.22095E+04 166 stilpnomelane-Mg 27.60 23.03 -4.57 -0.136 0.78044E+04 168 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 169 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 172 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 175 tephroite 18.11 13.50 -4.61 -0.659 0.78773E+04 178 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 179 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 188 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 189 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 190 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 191 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 192 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 193 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 194 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 195 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 196 beidellite-K -1.44 -4.75 -3.31 -0.203 0.56552E+04 197 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 198 beidellite-Na -1.26 -4.42 -3.16 -0.194 0.54034E+04 200 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 202 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 203 montmorillonite-K -2.16 -4.88 -2.72 -0.167 0.46500E+04 204 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 205 montmorillonite-Na -1.96 -4.56 -2.60 -0.159 0.44363E+04 206 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 207 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 208 nontronite-K 3.40 2.29 -1.11 -0.071 0.19018E+04 209 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 210 nontronite-Na 3.58 2.62 -0.97 -0.062 0.16517E+04 225 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 234 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 236 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 241 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 243 an20ab80 2.08 -0.06 -2.14 -0.165 0.36599E+04 244 an25ab75 2.71 0.54 -2.16 -0.166 0.36958E+04 245 an30ab70 3.34 1.15 -2.19 -0.168 0.37400E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0040000 g Current total amount of reactant added: 0.1990000 g New total amount of reactant added: 0.2030000 g Mixing fraction reached given limit of 0.2000E+00 TOTMIX = 0.2030E+00 Execution stopped.