File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.32821E-02 0.43806E-08 0.9542 0.00000000E+00 H2O 2 0. 0.55506E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13796E-03 0.9540 0.00000000E+00 SO4-- 4 -2. 0.31019E-04 0.25480E-04 0.8742 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.12658E-04 0.9540 0.00000000E+00 HS- 6 -1. -0.55150E-05 0.18498E-12 0.9540 0.00000000E+00 Al+++ 7 3. 0.64889E-03 0.58291E-22 0.7554 0.00000000E+00 H4SiO4 8 0. 0.20721E-02 0.38296E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.24335E-03 0.17878E-05 0.8740 0.00000000E+00 Mg++ 10 2. 0.15794E-03 0.72848E-08 0.8739 0.00000000E+00 Fe++ 11 2. 0.14189E-03 0.43089E-10 0.8739 0.00000000E+00 K+ 12 1. 0.42251E-04 0.42234E-04 0.9540 0.00000000E+00 Na+ 13 1. 0.40986E-03 0.40927E-03 0.9540 0.00000000E+00 Mn++ 14 2. 0.34504E-05 0.57413E-08 0.8739 0.00000000E+00 HPO4-- 15 -2. 0.11776E-05 0.36920E-07 0.8742 0.00000000E+00 Chg. balance for total moles = 0.1074E-13 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 100.0000 SLIM = 0.400000E+00 TEMP = 100.0000 SINC = 0.1000E-01 TEMPC = 0.0000 TOTMIX = 0.199000E+00 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 1.0796 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0107 MnO2-2 65 -2. 40.4376 Ca(HSiO3)+ 17 1. 7.6603 HMnO2- 66 -1. 29.1018 Mg(HSiO3)+ 18 1. 7.5653 MnO4- 67 -1. 83.3383 NaHSiO3,aq 19 0. 7.8098 MnO4-2 68 -2. 81.3024 AlO+ 20 1. 6.8891 MnCl+ 69 1. -0.7819 AlOH+2 21 2. 3.1893 MnSO4,aq 70 0. -2.4524 HAlO2,aq 22 0. 10.5878 NaCl,aq 71 0. 0.4861 AlO2- 23 -1. 16.2390 NaOH,aq 72 0. 12.3571 CH4,aq 24 0. 6.0082 O2,aq 73 0. 53.5759 C2H6,aq 25 0. 12.3556 OH- 74 -1. 12.2220 C3H8,aq 26 0. 17.3423 HO2- 75 -1. 50.7897 C4H10,aq 27 0. 22.3397 H2O2,aq 76 0. 40.0297 ethanol,aq 28 0. 15.3114 H3PO2,aq 77 0. 24.3310 CO,aq 29 0. 4.7087 H2PO2- 78 -1. 26.5491 CO2,aq 30 0. -6.3045 HPO3-2 79 -2. 11.9246 CO3-2 31 -2. 10.0340 H3PO3,aq 80 0. 3.5932 CaCO3,aq 32 0. 5.9460 H2PO3- 81 -1. 5.6314 Ca(HCO3)+ 33 1. -1.4013 H3PO4,aq 82 0. -9.8087 CaCl+ 34 1. -0.2023 H2PO4- 83 -1. -7.2438 CaCl2,aq 35 0. 0.4306 PO4-3 84 -3. 12.0588 CaOH+ 36 1. 10.1517 H4P2O7,aq 85 0. -17.7539 CaSO4,aq 37 0. -2.4936 H3P2O7- 86 -1. -15.8646 HCl,aq 38 0. 0.7256 H2P2O7-2 87 -2. -13.3812 HClO,aq 39 0. 32.4377 HP2O7-3 88 -3. -6.6931 ClO- 40 -1. 39.6416 P2O7-4 89 -4. 2.9147 HClO2,aq 41 0. 70.2060 H2S,aq 90 0. -6.4778 Fe+3 42 3. 8.3763 S2-2 91 -2. 1.2336 FeCl+ 43 1. -0.1924 S3-2 92 -2. -8.7963 FeCl2,aq 44 0. 4.3160 S3- 93 -1. -16.3178 FeCl+2 45 2. 6.5223 S4-2 94 -2. -18.6473 FeO,aq 46 0. 16.4029 S5-2 95 -2. -28.3223 FeOH+ 47 1. 7.4795 SO2,aq 96 0. -0.1980 HFeO2- 48 -1. 24.3713 SO3-2 97 -2. 10.2895 FeO+ 49 1. 11.3812 HSO3- 98 -1. 2.5222 FeOH+2 50 2. 9.1115 HSO4- 99 -1. -2.9675 FeO2- 51 -1. 24.0877 HSO5- 100 -1. 38.8657 HFeO2,aq 52 0. 15.9903 S2O3-2 101 -2. -4.5491 H2,aq 53 0. 9.4241 HS2O3- 102 -1. -6.8007 KCl,aq 54 0. 1.7519 H2S2O3,aq 103 0. -7.9944 KHSO4,aq 55 0. -0.4275 S2O4-2 104 -2. 10.5639 KOH,aq 56 0. 12.3606 HS2O4- 105 -1. 7.6762 KSO4- 57 -1. -1.1877 H2S2O4,aq 106 0. 6.6566 MgCO3,aq 58 0. 6.5483 S2O5-2 107 -2. 10.0891 Mg(HCO3)+ 59 1. -1.4098 S2O6-2 108 -2. 11.5737 MgCl+ 60 1. -0.1603 S2O8-2 109 -2. 42.1139 MgOH+ 61 1. 9.4082 S3O6-2 110 -2. 3.8101 Mn+3 62 3. 19.1332 S4O6-2 111 -2. -17.8301 MnO,aq 63 0. 17.9765 S5O6-2 112 -2. -14.1051 MnOH+ 64 1. 8.5115 113 0. 10.3157 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.984 0.0000E+00 osumilite(2) 124 20.895 0.0000E+00 CO2,gas 2 -6.363 0.0000E+00 osumilite-Fe 125 14.657 0.0000E+00 CH4,gas 3 4.809 0.0000E+00 pargasite 126 65.279 0.0000E+00 H2,gas 4 8.287 0.0000E+00 periclase 127 16.149 0.0000E+00 H2S,gas 5 -5.943 0.0000E+00 periclase-Fe 128 11.639 0.0000E+00 S2,gas 6 -7.033 0.0000E+00 perovskite-Al 129 12.395 0.0000E+00 CO,gas 7 3.510 0.0000E+00 perovskite-Ca 130 23.818 0.0000E+00 SO3,gas 8 17.427 0.0000E+00 perovskite-Fe 131 21.158 0.0000E+00 SO2,gas 9 1.136 0.0000E+00 perovskite-Mg 132 23.132 0.0000E+00 HCl,gas 10 5.479 0.0000E+00 phase_A 133 80.267 0.0000E+00 acmite 11 7.737 0.0000E+00 phlogopite-Na 134 29.731 0.0000E+00 akermanite 12 36.495 0.0000E+00 piemontite(ordered) 135 33.876 0.0000E+00 akimotoite 13 16.606 0.0000E+00 prehnite 136 19.466 0.0000E+00 akimotoite-Fe 14 13.083 0.0000E+00 prehnite-Fe 137 22.587 0.0000E+00 albite-high 15 0.750 0.0000E+00 pumpellyite-Fe 138 46.471 0.0000E+00 albite 16 -0.328 0.0000E+00 pumpellyite-Mg 139 49.194 0.0000E+00 almandine 17 24.545 0.0000E+00 px-Mg-tschermaks 140 19.687 0.0000E+00 pyrope 18 37.348 0.0000E+00 px-Ca-tschermaks 141 18.679 0.0000E+00 spessartine 19 24.550 0.0000E+00 pyrite 142 -21.225 0.0000E+00 analcite 20 3.371 0.0000E+00 pyrrhotite 143 -4.244 0.0000E+00 andalusite 21 5.062 0.0000E+00 pyrrhotiteFe0.875 144 -6.001 0.0000E+00 andradite 22 39.088 0.0000E+00 pyroxmangite 145 7.416 0.0000E+00 grossular 23 32.828 0.0000E+00 pyrophyllite 146 -6.098 0.0000E+00 anhydrite 24 -5.280 0.0000E+00 quartz 147 -2.982 0.0000E+00 ankerite 25 -2.093 0.0000E+00 rankinite 148 40.765 0.0000E+00 annite 26 20.209 0.0000E+00 ringwoodite-Fe 149 15.486 0.0000E+00 phlogopite 27 27.147 0.0000E+00 ringwoodite-Mg 150 27.602 0.0000E+00 biotite-Mn 28 33.034 0.0000E+00 rhodochrosite 151 -0.959 0.0000E+00 anorthite 29 12.798 0.0000E+00 rhodonite 152 7.462 0.0000E+00 anthophyllite 30 51.988 0.0000E+00 sanidine 153 -1.221 0.0000E+00 anthophyllite-Fe 31 29.455 0.0000E+00 sapphirine(351) 154 79.204 0.0000E+00 apatite-OH 32 -17.989 0.3794E-06 siderite 155 -2.588 0.0000E+00 apatite-OH-zs 33 -12.572 0.0000E+00 sillimanite 156 5.321 0.0000E+00 apatite-Cl-zs 34 -16.504 0.0000E+00 sodalite 157 50.255 0.0000E+00 aragonite 35 0.986 0.0000E+00 spinel 158 20.934 0.0000E+00 brucite 36 12.577 0.0000E+00 spurrite 159 59.566 0.0000E+00 calcite 37 0.833 0.0000E+00 staurolite-Fe 160 74.138 0.0000E+00 carnegieite-low 38 9.065 0.0000E+00 staurolite-Mg 161 90.336 0.0000E+00 carnegieite-high 39 10.134 0.0000E+00 staurolite-Mn 162 84.438 0.0000E+00 carpholite-Mg 40 8.650 0.0000E+00 stilbite 163 -7.406 0.1806E-03 carpholite-Fe 41 6.783 0.0000E+00 stilpnomelane-Fe 164 13.179 0.0000E+00 celadonite 42 5.401 0.0000E+00 stilpnomelane-Mg 165 27.596 0.0000E+00 celadonite-Fe 43 3.937 0.0000E+00 stishovite 166 2.721 0.0000E+00 chrysotile 44 23.937 0.0000E+00 sudoite-Fe 167 18.437 0.0000E+00 chondrodite 45 56.542 0.0000E+00 sudoite 168 21.216 0.0000E+00 clinochlore 46 39.193 0.3159E-04 sulfur 169 -9.141 0.0000E+00 daphnite 47 29.094 0.1955E-04 sylvite 170 1.345 0.0000E+00 chlorite-Mn 48 46.985 0.6881E-06 talc 171 16.553 0.0000E+00 chlorite-Al-free 49 47.262 0.0000E+00 talc-Fe 172 13.516 0.0000E+00 chloritoid-Mg 50 13.261 0.0000E+00 talc-tschermaks 173 19.189 0.0000E+00 chloritoid-Fe 51 9.239 0.0000E+00 tephroite 174 18.113 0.0000E+00 chloritoid-Mn 52 11.463 0.0000E+00 tilleyite 175 41.473 0.0000E+00 clinohumite 53 97.255 0.0000E+00 titanite-CaSi 176 15.497 0.0000E+00 coesite 54 -2.369 0.0000E+00 topaz-H 177 4.668 0.0000E+00 cordierite-H 55 23.898 0.0000E+00 tridymite 178 -2.615 0.0000E+00 cordierite 56 24.245 0.0000E+00 tremolite 179 48.003 0.0000E+00 cordierite-Fe 57 20.649 0.0000E+00 ferroactinolite 180 38.596 0.0000E+00 cordierite-Mn 58 25.261 0.0000E+00 troilite-low 181 -4.394 0.0000E+00 corundum 59 8.433 0.0000E+00 tschermakite 182 48.414 0.0000E+00 corundum-MgSi 60 18.905 0.0000E+00 vesuvianite 183 224.056 0.0000E+00 cristobalite 61 -2.549 0.0000E+00 wadeite-Si 184 20.233 0.0000E+00 cummingtonite 62 52.233 0.0000E+00 wadsleyite-Fe 185 15.711 0.0000E+00 cymrite-K 63 1.731 0.0000E+00 wadsleyite-Mg 186 25.878 0.0000E+00 deerite 64 95.982 0.0000E+00 wairakite 187 4.058 0.0000E+00 diaspore 65 2.896 0.0000E+00 walstromite 188 11.528 0.0000E+00 diamond 66 -3.107 0.0000E+00 wollastonite 189 10.482 0.0000E+00 diopside 67 16.215 0.0000E+00 pseudo-wollastonite 190 11.020 0.0000E+00 hedenbergite 68 14.244 0.0000E+00 zoisite 191 22.964 0.0000E+00 dolomite,ordered 69 0.587 0.0000E+00 akaganeite 192 7.768 0.0000E+00 eastonite 70 28.605 0.0000E+00 beidellite-Ca 193 -1.560 0.0000E+00 enstatite 71 17.301 0.0000E+00 beidellite-H 194 -2.241 0.0000E+00 clinoenstatite-HiP 72 18.388 0.0000E+00 beidellite-K 195 -1.435 0.0000E+00 clinoenstatite 73 17.202 0.0000E+00 beidellite-Mg 196 -1.707 0.0000E+00 protoenstatite 74 17.860 0.0000E+00 beidellite-Na 197 -1.257 0.0000E+00 epidote 75 24.775 0.0000E+00 calcium 198 84.043 0.0000E+00 clinozoisite 76 22.921 0.0000E+00 chalcedony 199 -2.794 0.0000E+00 epidote-Fe 77 29.937 0.0000E+00 dawsonite 200 1.714 0.0000E+00 fayalite 78 14.079 0.0000E+00 montmorillonite-Ca 201 -2.214 0.0000E+00 ferrosilite 79 11.188 0.0000E+00 montmorillonite-K 202 -2.161 0.0000E+00 forsterite 80 21.047 0.0000E+00 montmorillonite-Mg 203 -2.402 0.0000E+00 gedrite 81 50.725 0.0000E+00 montmorillonite-Na 204 -1.961 0.0000E+00 gehlenite 82 36.717 0.0000E+00 nontronite-Ca 205 3.280 0.0000E+00 gibbsite 83 4.097 0.0000E+00 nontronite-H 206 2.596 0.0000E+00 glaucophane 84 23.111 0.0000E+00 nontronite-K 207 3.404 0.0000E+00 glaucophane-Fe 85 17.417 0.0000E+00 nontronite-Mg 208 3.139 0.0000E+00 graphite 86 -3.549 0.0000E+00 nontronite-Na 209 3.583 0.0000E+00 greenalite 87 16.194 0.0000E+00 sepiolite 210 24.194 0.0000E+00 grunerite 88 31.364 0.0000E+00 alite 211 58.043 0.0000E+00 halite 89 1.582 0.0000E+00 belite 212 30.461 0.0000E+00 hematite 90 12.598 0.2206E-04 ettringite 213 43.354 0.0000E+00 heulandite 91 -5.707 0.0000E+00 gypsum 214 -4.924 0.0000E+00 hercynite 92 17.345 0.0000E+00 hemicarboaluminate 215 71.028 0.0000E+00 hollandite 93 25.702 0.0000E+00 hydrogarnet 216 60.721 0.0000E+00 iron 94 19.095 0.0000E+00 hydrogarnet-Si 217 50.654 0.0000E+00 jadeite 95 4.251 0.0000E+00 jennite 218 24.386 0.0000E+00 julgoldite 96 70.573 0.0000E+00 monosulfoaluminate 219 53.497 0.0000E+00 kalsilite 97 7.620 0.0000E+00 monocarboaluminate 220 61.966 0.0000E+00 kaolinite 98 -1.273 0.2863E-04 portlandite 221 18.282 0.0000E+00 kyanite 99 4.932 0.0000E+00 stratlingite 222 36.573 0.0000E+00 larnite-bredigite 100 30.714 0.0000E+00 tricarboaluminate 223 70.427 0.0000E+00 laumontite 101 2.975 0.0000E+00 tobermorite 224 9.839 0.0000E+00 lawsonite 102 9.678 0.5902E-04 C4AH13 225 81.870 0.0000E+00 leucite 103 4.168 0.0000E+00 C2AH8 226 45.260 0.0000E+00 lime 104 26.009 0.0000E+00 C3A 227 87.049 0.0000E+00 lizardite 105 23.287 0.0000E+00 C4AF 228 117.550 0.0000E+00 magnesite 106 0.709 0.0000E+00 CAH10 229 28.373 0.0000E+00 magnetite 107 20.133 0.0000E+00 alabandite 230 -0.962 0.0000E+00 minnesotaite 108 10.461 0.0000E+00 alunite 231 -10.224 0.0000E+00 minnesotaite-Mg 109 20.669 0.0000E+00 artinite 232 15.139 0.0000E+00 magnesioferrite 110 26.257 0.0000E+00 boehmite 233 4.430 0.0000E+00 majorite 111 53.314 0.0000E+00 dolomite,disordered 234 1.288 0.0000E+00 manganosite 112 14.068 0.0000E+00 ferrous-oxide 235 9.824 0.0000E+00 margarite 113 17.452 0.0000E+00 huntite 236 3.850 0.0000E+00 meionite 114 45.158 0.0000E+00 hydromagnesite 237 20.077 0.0000E+00 merwinite 115 55.988 0.0000E+00 nesquehonite 238 4.735 0.0000E+00 microcline 116 -2.432 0.0000E+00 potassium-oxide 239 69.039 0.0000E+00 monticellite 117 24.371 0.0000E+00 silica-amorphous 240 -2.080 0.0000E+00 mullite-Al 118 363.258 0.0000E+00 sodium-oxide 241 55.173 0.0000E+00 mullite-Si 119 7.324 0.0000E+00 an20ab80 242 2.079 0.0000E+00 muscovite 120 2.679 0.0000E+00 an25ab75 243 2.709 0.0000E+00 paragonite 121 4.337 0.0000E+00 an30ab70 244 3.344 0.0000E+00 nepheline 122 8.378 0.0000E+00 tr.625ac.25prg.125 245 45.308 0.0000E+00 osumilite(1) 123 21.978 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 0.1990000 g log = -0.7011 Original solution: 1000.0103000 g Original solution / Rock added: 5025.18 (Water/Rock Ratio), log = 3.7012 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.1990000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .3957141E-03 Osmotic coef. = 0.9882 True ionic strength = .4827710E-03 Chg. balance for total moles = 0.1074E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.43806E-08 -8.3585 0.41799E-08 -8.3788 0.95418E+00 -0.0204 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13161E-03 -3.8807 0.95398E+00 -0.0205 4 SO4-- 0.25480E-04 -4.5938 0.22276E-04 -4.6522 0.87424E+00 -0.0584 5 HCO3- 0.12658E-04 -4.8976 0.12076E-04 -4.9181 0.95403E+00 -0.0204 6 HS- 0.18498E-12 -12.7329 0.17646E-12 -12.7533 0.95398E+00 -0.0205 7 Al+++ 0.58291E-22 -22.2344 0.44032E-22 -22.3562 0.75538E+00 -0.1218 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.17878E-05 -5.7477 0.15626E-05 -5.8062 0.87402E+00 -0.0585 10 Mg++ 0.72848E-08 -8.1376 0.63661E-08 -8.1961 0.87388E+00 -0.0585 11 Fe++ 0.43089E-10 -10.3656 0.37656E-10 -10.4242 0.87391E+00 -0.0585 12 K+ 0.42234E-04 -4.3743 0.40292E-04 -4.3948 0.95403E+00 -0.0204 13 Na+ 0.40927E-03 -3.3880 0.39043E-03 -3.4085 0.95397E+00 -0.0205 14 Mn++ 0.57413E-08 -8.2410 0.50176E-08 -8.2995 0.87394E+00 -0.0585 15 HPO4-- 0.36920E-07 -7.4327 0.32277E-07 -7.4911 0.87424E+00 -0.0584 16 HSiO3- 0.93703E-04 -4.0282 0.89391E-04 -4.0487 0.95398E+00 -0.0205 17 Ca(HSiO3)+ 0.32803E-08 -8.4841 0.31296E-08 -8.5045 0.95404E+00 -0.0204 18 Mg(HSiO3)+ 0.16632E-10 -10.7791 0.15868E-10 -10.7995 0.95404E+00 -0.0204 19 NaHSiO3,aq 0.55431E-06 -6.2562 0.55431E-06 -6.2562 0.10000E+01 0.0000 20 AlO+ 0.34102E-12 -12.4672 0.32535E-12 -12.4876 0.95404E+00 -0.0204 21 AlOH+2 0.77948E-17 -17.1082 0.68124E-17 -17.1667 0.87397E+00 -0.0585 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.87226E-05 -5.0594 0.83207E-05 -5.0798 0.95392E+00 -0.0205 24 CH4,aq 0.93880E-19 -19.0274 0.93869E-19 -19.0275 0.99988E+00 -0.0001 29 CO,aq 0.11581E-17 -17.9362 0.11581E-17 -17.9362 0.10000E+01 0.0000 30 CO2,aq 0.10178E-06 -6.9923 0.10177E-06 -6.9924 0.99988E+00 -0.0001 31 CO3-2 0.30556E-06 -6.5149 0.26712E-06 -6.5733 0.87417E+00 -0.0584 32 CaCO3,aq 0.51120E-08 -8.2914 0.51120E-08 -8.2914 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.49835E-09 -9.3025 0.47545E-09 -9.3229 0.95404E+00 -0.0204 34 CaCl+ 0.34350E-09 -9.4641 0.32771E-09 -9.4845 0.95404E+00 -0.0204 35 CaCl2,aq 0.10043E-13 -13.9982 0.10043E-13 -13.9982 0.10000E+01 0.0000 36 CaOH+ 0.27630E-07 -7.5586 0.26360E-07 -7.5791 0.95404E+00 -0.0204 37 CaSO4,aq 0.10845E-07 -7.9648 0.10845E-07 -7.9648 0.10000E+01 0.0000 38 HCl,aq 0.10348E-12 -12.9852 0.10348E-12 -12.9852 0.10000E+01 0.0000 43 FeCl+ 0.80910E-14 -14.0920 0.77192E-14 -14.1124 0.95404E+00 -0.0204 46 FeO,aq 0.85230E-10 -10.0694 0.85230E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.31306E-09 -9.5044 0.29867E-09 -9.5248 0.95404E+00 -0.0204 48 HFeO2- 0.22990E-09 -9.6385 0.21932E-09 -9.6589 0.95398E+00 -0.0205 49 FeO+ 0.36242E-13 -13.4408 0.34577E-13 -13.4612 0.95404E+00 -0.0204 50 FeOH+2 0.30772E-19 -19.5118 0.26893E-19 -19.5704 0.87397E+00 -0.0585 51 FeO2- 0.40773E-09 -9.3896 0.38896E-09 -9.4101 0.95398E+00 -0.0205 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44191E-09 -9.3547 0.44185E-09 -9.3547 0.99988E+00 -0.0001 54 KCl,aq 0.93898E-10 -10.0273 0.93898E-10 -10.0273 0.10000E+01 0.0000 55 KHSO4,aq 0.10039E-16 -16.9983 0.10039E-16 -16.9983 0.10000E+01 0.0000 56 KOH,aq 0.42024E-08 -8.3765 0.42024E-08 -8.3765 0.10000E+01 0.0000 57 KSO4- 0.14495E-07 -7.8388 0.13828E-07 -7.8592 0.95398E+00 -0.0205 58 MgCO3,aq 0.52042E-11 -11.2836 0.52042E-11 -11.2836 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20704E-11 -11.6839 0.19752E-11 -11.7044 0.95404E+00 -0.0204 60 MgCl+ 0.12704E-11 -11.8960 0.12121E-11 -11.9165 0.95404E+00 -0.0204 61 MgOH+ 0.62362E-09 -9.2051 0.59496E-09 -9.2255 0.95404E+00 -0.0204 63 MnO,aq 0.30317E-09 -9.5183 0.30317E-09 -9.5183 0.10000E+01 0.0000 64 MnOH+ 0.38750E-08 -8.4117 0.36970E-08 -8.4322 0.95404E+00 -0.0204 65 MnO2-2 0.68647E-15 -15.1634 0.60010E-15 -15.2218 0.87417E+00 -0.0584 66 HMnO2- 0.56968E-12 -12.2444 0.54346E-12 -12.2648 0.95398E+00 -0.0205 69 MnCl+ 0.41893E-11 -11.3779 0.39968E-11 -11.3983 0.95404E+00 -0.0204 70 MnSO4,aq 0.31676E-10 -10.4993 0.31676E-10 -10.4993 0.10000E+01 0.0000 71 NaCl,aq 0.16779E-07 -7.7752 0.16779E-07 -7.7752 0.10000E+01 0.0000 72 NaOH,aq 0.41044E-07 -7.3867 0.41044E-07 -7.3867 0.10000E+01 0.0000 74 OH- 0.15044E-03 -3.8226 0.14351E-03 -3.8431 0.95392E+00 -0.0205 79 HPO3-2 0.51530E-19 -19.2879 0.45046E-19 -19.3463 0.87417E+00 -0.0584 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.24793E-08 -8.6057 0.23653E-08 -8.6261 0.95401E+00 -0.0204 84 PO4-3 0.89121E-11 -11.0500 0.67437E-11 -11.1711 0.75669E+00 -0.1211 87 H2P2O7-2 0.50089E-18 -18.3003 0.43787E-18 -18.3587 0.87417E+00 -0.0584 88 HP2O7-3 0.28436E-16 -16.5461 0.21480E-16 -16.6680 0.75539E+00 -0.1218 89 P2O7-4 0.20568E-17 -17.6868 0.12678E-17 -17.8970 0.61637E+00 -0.2102 90 H2S,aq 0.22164E-14 -14.6543 0.22162E-14 -14.6544 0.99988E+00 -0.0001 97 SO3-2 0.15344E-14 -14.8141 0.13420E-14 -14.8722 0.87462E+00 -0.0582 98 HSO3- 0.34412E-15 -15.4633 0.32828E-15 -15.4838 0.95398E+00 -0.0205 99 HSO4- 0.90552E-10 -10.0431 0.86393E-10 -10.0635 0.95407E+00 -0.0204 Charge balance for all species = 0.1074E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4380606E-08 -.2799185E-03 -.2821229E+00 0.0000 2 H2O 0.1000000E+01 0.5550832E+02 0.9999349E+06 0.0000 3 Cl- 0.1379632E-03 0.1379805E-03 0.4891507E+01 4.4981 4 SO4-- 0.2548017E-04 0.2550560E-04 0.2449951E+01 12.1055 5 HCO3- 0.1265763E-04 0.1307060E-04 0.7974799E+00 3.4607 6 HS- 0.1849768E-12 0.3426075E-10 0.1132999E-05 -4.3745 7 Al+++ 0.5829096E-22 0.8738202E-05 0.2357546E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4772211E-03 0.4586535E+02 -3.4168 9 Ca++ 0.1787814E-05 0.1835523E-05 0.7355938E-01 10.9515 10 Mg++ 0.7284831E-08 0.7933631E-08 0.1928701E-03 8.5615 11 Fe++ 0.4308928E-10 0.1282517E-08 0.7162015E-04 6.3335 12 K+ 0.4223366E-04 0.4225246E-04 0.1652049E+01 3.9841 13 Na+ 0.4092710E-03 0.4098832E-03 0.9422527E+01 4.9704 14 Mn++ 0.5741320E-08 0.9955966E-08 0.5469257E-03 8.4582 15 HPO4-- 0.3691968E-07 0.3940793E-07 0.3782090E-02 9.2666 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3282105E-02 -.2799057E-03 -.3002199E-02 0.0000000E+00 2 H2O 0.5550576E+02 0.5550580E+02 -.3963966E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3101944E-04 0.2550444E-04 0.5515003E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5514968E-05 0.3425918E-10 -.5515003E-05 0.0000000E+00 7 Al+++ 0.6488876E-03 0.8737804E-05 0.6401498E-03 0.0000000E+00 8 H4SiO4 0.2072144E-02 0.4771994E-03 0.1594944E-02 0.0000000E+00 9 Ca++ 0.2433494E-03 0.1835440E-05 0.2415140E-03 0.0000000E+00 10 Mg++ 0.1579365E-03 0.7933270E-08 0.1579286E-03 0.0000000E+00 11 Fe++ 0.1418887E-03 0.1282459E-08 0.1418874E-03 0.0000000E+00 12 K+ 0.4225053E-04 0.4225053E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.4098645E-03 0.4098645E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3450381E-05 0.9955512E-08 0.3440425E-05 0.0000000E+00 15 HPO4-- 0.1177598E-05 0.3940613E-07 0.1138192E-05 0.0000000E+00 Chg. balance for solid moles: -.3147E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3794E-06 -6.421 0.1906E-03 -3.720 0.1009 0.6056E-04 clinochlore 0.3159E-04 -4.501 0.1756E-01 -1.756 9.293 0.6678E-02 daphnite 0.1955E-04 -4.709 0.1395E-01 -1.855 7.385 0.4228E-02 chlorite-Mn 0.6881E-06 -6.162 0.4878E-03 -3.312 0.2582 0.1555E-03 hematite 0.2206E-04 -4.656 0.3523E-02 -2.453 1.865 0.6677E-03 kaolinite 0.2863E-04 -4.543 0.7391E-02 -2.131 3.912 0.2844E-02 lawsonite 0.5902E-04 -4.229 0.1855E-01 -1.732 9.818 0.5981E-02 stilbite 0.1806E-03 -3.743 0.1273 -0.895 67.37 0.5936E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1328E-01 0.1328E-01 1.0000 -1.877 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.188916 g Volume = 0.079974 cm3 Porosity: 92.5922% V(tot) - V(min): 0.99963E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.1990000 g log = -0.7011 Original solution: 1000.0103000 g Original solution / Rock added: 5025.18 (Water/Rock Ratio), log = 3.7012 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1099E-04 1.0073 0.1165E-04 0.1156E-04 CH4,gas 0.1393E-15 1.0129 0.1484E-15 0.1465E-15 H2,gas 0.5758E-06 1.0006 0.6060E-06 0.6057E-06 H2S,gas 0.6170E-13 0.9959 0.6464E-13 0.6490E-13 S2,gas 0.4050E-33 1.0000 0.4261E-33 0.4261E-33 CO,gas 0.1738E-14 1.0000 0.1829E-14 0.1829E-14 SO3,gas 0.1383E-36 1.0000 0.1455E-36 0.1455E-36 SO2,gas 0.3171E-20 1.0000 0.3336E-20 0.3336E-20 HCl,gas 0.1737E-15 1.0000 0.1827E-15 0.1827E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.30 -6.93 -2.311 0.11839E+05 -4.934 3 CH4,gas 4.81 -13.02 -17.83 -4.457 0.30442E+05 -15.828 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.13 -15.19 -7.595 0.25936E+05 -13.190 6 S2,gas -7.03 -42.40 -35.37 -5.442 0.60394E+05 -33.371 7 CO,gas 3.51 -13.23 -16.74 -5.150 0.28579E+05 -14.738 8 SO3,gas 17.43 -21.41 -38.84 -9.709 0.66313E+05 -36.837 9 SO2,gas 1.14 -21.34 -22.48 -5.994 0.38379E+05 -20.477 10 HCl,gas 5.48 -12.26 -17.74 -8.869 0.30288E+05 -15.738 11 acmite 7.74 4.44 -3.30 -0.343 0.56379E+04 15 albite-high 0.75 -2.50 -3.25 -0.250 0.55485E+04 16 albite -0.33 -2.50 -2.17 -0.167 0.37078E+04 19 spessartine 24.55 20.68 -3.87 -0.193 0.66000E+04 20 analcite 3.37 0.92 -2.45 -0.273 0.41896E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.51 -4.70 -0.261 0.80166E+04 27 phlogopite 27.15 22.20 -4.95 -0.275 0.84489E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.35 -3.33 -1.111 0.56887E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.35 -3.18 -1.060 0.54273E+04 38 carnegieite-low 9.06 4.33 -4.73 -0.676 0.80776E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 1.66 -3.74 -0.220 0.63894E+04 43 celadonite-Fe 3.94 -0.57 -4.51 -0.265 0.76947E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14707E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82450E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68766E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.92 -3.33 -0.333 0.56926E+04 97 kalsilite 7.62 3.35 -4.27 -0.610 0.72956E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.07 -4.24 -0.424 0.72346E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.49 -1.05 -0.081 0.18004E+04 120 muscovite 2.68 2.07 -0.60 -0.036 0.10328E+04 121 paragonite 4.34 3.06 -1.28 -0.075 0.21787E+04 122 nepheline 8.38 4.33 -4.04 -0.578 0.69055E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40548E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -4.84 -3.88 -1.293 0.66254E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41340E+04 153 sanidine -1.22 -3.49 -2.27 -0.174 0.38681E+04 155 siderite -2.59 -6.96 -4.38 -1.459 0.74715E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 11.89 -1.29 -0.039 0.22095E+04 165 stilpnomelane-Mg 27.60 23.03 -4.57 -0.136 0.78044E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78773E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.75 -3.31 -0.203 0.56552E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.42 -3.16 -0.194 0.54034E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.88 -2.72 -0.167 0.46500E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.56 -2.60 -0.159 0.44363E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.29 -1.11 -0.071 0.19018E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.62 -0.97 -0.062 0.16517E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 -0.06 -2.14 -0.165 0.36599E+04 243 an25ab75 2.71 0.54 -2.16 -0.166 0.36958E+04 244 an30ab70 3.34 1.15 -2.19 -0.168 0.37400E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.1990000 g New total amount of reactant added: 0.2090000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1074E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.2090000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .4048975E-03 Osmotic coef. = 0.9881 True ionic strength = .4968660E-03 Chg. balance for total moles = 0.1074E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.41507E-08 -8.3819 0.39589E-08 -8.4024 0.95379E+00 -0.0205 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13156E-03 -3.8809 0.95359E+00 -0.0206 4 SO4-- 0.25481E-04 -4.5938 0.22240E-04 -4.6529 0.87281E+00 -0.0591 5 HCO3- 0.12646E-04 -4.8980 0.12060E-04 -4.9187 0.95363E+00 -0.0206 6 HS- 0.17498E-12 -12.7570 0.16686E-12 -12.7777 0.95359E+00 -0.0206 7 Al+++ 0.49710E-22 -22.3036 0.37412E-22 -22.4270 0.75260E+00 -0.1234 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.16064E-05 -5.7941 0.14018E-05 -5.8533 0.87259E+00 -0.0592 10 Mg++ 0.65458E-08 -8.1840 0.57108E-08 -8.2433 0.87244E+00 -0.0593 11 Fe++ 0.38717E-10 -10.4121 0.33780E-10 -10.4713 0.87248E+00 -0.0592 12 K+ 0.44356E-04 -4.3530 0.42300E-04 -4.3737 0.95364E+00 -0.0206 13 Na+ 0.42177E-03 -3.3749 0.40219E-03 -3.3956 0.95358E+00 -0.0206 14 Mn++ 0.51606E-08 -8.2873 0.45027E-08 -8.3465 0.87250E+00 -0.0592 15 HPO4-- 0.41223E-07 -7.3849 0.35980E-07 -7.4439 0.87282E+00 -0.0591 16 HSiO3- 0.98973E-04 -4.0045 0.94379E-04 -4.0251 0.95359E+00 -0.0206 17 Ca(HSiO3)+ 0.31082E-08 -8.5075 0.29641E-08 -8.5281 0.95365E+00 -0.0206 18 Mg(HSiO3)+ 0.15759E-10 -10.8025 0.15029E-10 -10.8231 0.95365E+00 -0.0206 19 NaHSiO3,aq 0.60288E-06 -6.2198 0.60288E-06 -6.2198 0.10000E+01 0.0000 20 AlO+ 0.32313E-12 -12.4906 0.30815E-12 -12.5112 0.95365E+00 -0.0206 21 AlOH+2 0.70040E-17 -17.1547 0.61112E-17 -17.2139 0.87253E+00 -0.0592 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.92132E-05 -5.0356 0.87850E-05 -5.0563 0.95352E+00 -0.0207 24 CH4,aq 0.88796E-19 -19.0516 0.88785E-19 -19.0517 0.99987E+00 -0.0001 29 CO,aq 0.10955E-17 -17.9604 0.10955E-17 -17.9604 0.10000E+01 0.0000 30 CO2,aq 0.96275E-07 -7.0165 0.96263E-07 -7.0165 0.99987E+00 -0.0001 31 CO3-2 0.32272E-06 -6.4912 0.28166E-06 -6.5503 0.87275E+00 -0.0591 32 CaCO3,aq 0.48355E-08 -8.3156 0.48355E-08 -8.3156 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44666E-09 -9.3500 0.42596E-09 -9.3706 0.95365E+00 -0.0206 34 CaCl+ 0.30814E-09 -9.5112 0.29386E-09 -9.5319 0.95365E+00 -0.0206 35 CaCl2,aq 0.90015E-14 -14.0457 0.90015E-14 -14.0457 0.10000E+01 0.0000 36 CaOH+ 0.26180E-07 -7.5820 0.24967E-07 -7.6026 0.95365E+00 -0.0206 37 CaSO4,aq 0.97134E-08 -8.0126 0.97134E-08 -8.0126 0.10000E+01 0.0000 38 HCl,aq 0.97968E-13 -13.0089 0.97968E-13 -13.0089 0.10000E+01 0.0000 43 FeCl+ 0.72582E-14 -14.1392 0.69217E-14 -14.1598 0.95365E+00 -0.0206 46 FeO,aq 0.85229E-10 -10.0694 0.85229E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.29663E-09 -9.5278 0.28288E-09 -9.5484 0.95365E+00 -0.0206 48 HFeO2- 0.24283E-09 -9.6147 0.23156E-09 -9.6353 0.95359E+00 -0.0206 49 FeO+ 0.34340E-13 -13.4642 0.32749E-13 -13.4848 0.95365E+00 -0.0206 50 FeOH+2 0.27650E-19 -19.5583 0.24125E-19 -19.6175 0.87253E+00 -0.0592 51 FeO2- 0.43066E-09 -9.3659 0.41067E-09 -9.3865 0.95359E+00 -0.0206 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44190E-09 -9.3547 0.44185E-09 -9.3547 0.99987E+00 -0.0001 54 KCl,aq 0.98535E-10 -10.0064 0.98535E-10 -10.0064 0.10000E+01 0.0000 55 KHSO4,aq 0.99662E-17 -17.0015 0.99662E-17 -17.0015 0.10000E+01 0.0000 56 KOH,aq 0.46579E-08 -8.3318 0.46579E-08 -8.3318 0.10000E+01 0.0000 57 KSO4- 0.15199E-07 -7.8182 0.14493E-07 -7.8388 0.95359E+00 -0.0206 58 MgCO3,aq 0.49227E-11 -11.3078 0.49227E-11 -11.3078 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18556E-11 -11.7315 0.17696E-11 -11.7521 0.95365E+00 -0.0206 60 MgCl+ 0.11397E-11 -11.9432 0.10869E-11 -11.9638 0.95365E+00 -0.0206 61 MgOH+ 0.59090E-09 -9.2285 0.56351E-09 -9.2491 0.95365E+00 -0.0206 63 MnO,aq 0.30327E-09 -9.5182 0.30327E-09 -9.5182 0.10000E+01 0.0000 64 MnOH+ 0.36730E-08 -8.4350 0.35027E-08 -8.4556 0.95365E+00 -0.0206 65 MnO2-2 0.76675E-15 -15.1153 0.66918E-15 -15.1745 0.87275E+00 -0.0591 66 HMnO2- 0.60193E-12 -12.2205 0.57399E-12 -12.2411 0.95359E+00 -0.0206 69 MnCl+ 0.37594E-11 -11.4249 0.35852E-11 -11.4455 0.95365E+00 -0.0206 70 MnSO4,aq 0.28380E-10 -10.5470 0.28380E-10 -10.5470 0.10000E+01 0.0000 71 NaCl,aq 0.17277E-07 -7.7625 0.17277E-07 -7.7625 0.10000E+01 0.0000 72 NaOH,aq 0.44640E-07 -7.3503 0.44640E-07 -7.3503 0.10000E+01 0.0000 74 OH- 0.15890E-03 -3.7989 0.15151E-03 -3.8195 0.95352E+00 -0.0207 79 HPO3-2 0.57535E-19 -19.2401 0.50214E-19 -19.2992 0.87275E+00 -0.0591 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.26188E-08 -8.5819 0.24973E-08 -8.6025 0.95362E+00 -0.0206 84 PO4-3 0.10527E-10 -10.9777 0.79369E-11 -11.1003 0.75394E+00 -0.1227 87 H2P2O7-2 0.55927E-18 -18.2524 0.48810E-18 -18.3115 0.87275E+00 -0.0591 88 HP2O7-3 0.33592E-16 -16.4738 0.25281E-16 -16.5972 0.75261E+00 -0.1234 89 P2O7-4 0.25726E-17 -17.5896 0.15754E-17 -17.8026 0.61237E+00 -0.2130 90 H2S,aq 0.19850E-14 -14.7022 0.19847E-14 -14.7023 0.99987E+00 -0.0001 97 SO3-2 0.15344E-14 -14.8141 0.13399E-14 -14.8729 0.87321E+00 -0.0589 98 HSO3- 0.32553E-15 -15.4874 0.31042E-15 -15.5080 0.95359E+00 -0.0206 99 HSO4- 0.85662E-10 -10.0672 0.81695E-10 -10.0878 0.95368E+00 -0.0206 Charge balance for all species = 0.1074E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4150730E-08 -.2956861E-03 -.2980145E+00 0.0000 2 H2O 0.1000000E+01 0.5550833E+02 0.9999340E+06 0.0000 3 Cl- 0.1379630E-03 0.1379807E-03 0.4891512E+01 4.5215 4 SO4-- 0.2548066E-04 0.2550565E-04 0.2449954E+01 12.1520 5 HCO3- 0.1264633E-04 0.1307062E-04 0.7974807E+00 3.4838 6 HS- 0.1749767E-12 0.3138264E-10 0.1037819E-05 -4.3752 7 Al+++ 0.4971001E-22 0.9228817E-05 0.2489911E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4825398E-03 0.4637648E+02 -3.4168 9 Ca++ 0.1606432E-05 0.1651024E-05 0.6616544E-01 10.9515 10 Mg++ 0.6545768E-08 0.7160344E-08 0.1740709E-03 8.5615 11 Fe++ 0.3871749E-10 0.1297574E-08 0.7246088E-04 6.3335 12 K+ 0.4435583E-04 0.4437578E-04 0.1735069E+01 4.0288 13 Na+ 0.4217722E-03 0.4224370E-03 0.9711109E+01 5.0069 14 Mn++ 0.5160640E-08 0.9169638E-08 0.5037288E-03 8.4583 15 HPO4-- 0.4122286E-07 0.4385217E-07 0.4208613E-02 9.3609 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3447690E-02 -.2956721E-03 -.3152018E-02 0.0000000E+00 2 H2O 0.5550563E+02 0.5550569E+02 -.6081538E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3129657E-04 0.2550444E-04 0.5792134E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5792102E-05 0.3138115E-10 -.5792134E-05 0.0000000E+00 7 Al+++ 0.6814950E-03 0.9228378E-05 0.6722666E-03 0.0000000E+00 8 H4SiO4 0.2176272E-02 0.4825168E-03 0.1693755E-02 0.0000000E+00 9 Ca++ 0.2548509E-03 0.1650946E-05 0.2531999E-03 0.0000000E+00 10 Mg++ 0.1658730E-03 0.7160003E-08 0.1658659E-03 0.0000000E+00 11 Fe++ 0.1490188E-03 0.1297512E-08 0.1490175E-03 0.0000000E+00 12 K+ 0.4437367E-04 0.4437367E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.4224169E-03 0.4224169E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3623767E-05 0.9169203E-08 0.3614597E-05 0.0000000E+00 15 HPO4-- 0.1236774E-05 0.4385008E-07 0.1192923E-05 0.0000000E+00 Chg. balance for solid moles: -.2372E-19 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.2090000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3976E-06 -6.401 0.1997E-03 -3.700 0.9995E-01 0.6347E-04 clinochlore 0.3317E-04 -4.479 0.1844E-01 -1.734 9.227 0.7014E-02 daphnite 0.2054E-04 -4.687 0.1465E-01 -1.834 7.332 0.4440E-02 chlorite-Mn 0.7229E-06 -6.141 0.5125E-03 -3.290 0.2565 0.1633E-03 hematite 0.2317E-04 -4.635 0.3700E-02 -2.432 1.852 0.7013E-03 kaolinite 0.3049E-04 -4.516 0.7871E-02 -2.104 3.939 0.3029E-02 lawsonite 0.5780E-04 -4.238 0.1816E-01 -1.741 9.089 0.5857E-02 stilbite 0.1934E-03 -3.714 0.1363 -0.866 68.21 0.6357E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1328E-01 0.1328E-01 1.0000 -1.877 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.199839 g Volume = 0.084841 cm3 Porosity: 92.1705% V(tot) - V(min): 0.99876E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2090000 g log = -0.6799 Original solution: 1000.0103000 g Original solution / Rock added: 4784.74 (Water/Rock Ratio), log = 3.6799 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1040E-04 1.0073 0.1102E-04 0.1094E-04 CH4,gas 0.1318E-15 1.0129 0.1404E-15 0.1386E-15 H2,gas 0.5758E-06 1.0006 0.6060E-06 0.6057E-06 H2S,gas 0.5525E-13 0.9959 0.5789E-13 0.5812E-13 S2,gas 0.3248E-33 1.0000 0.3417E-33 0.3417E-33 CO,gas 0.1644E-14 1.0000 0.1730E-14 0.1730E-14 SO3,gas 0.1239E-36 1.0000 0.1303E-36 0.1303E-36 SO2,gas 0.2840E-20 1.0000 0.2988E-20 0.2988E-20 HCl,gas 0.1644E-15 1.0000 0.1730E-15 0.1730E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.32 -6.96 -2.319 0.11880E+05 -4.958 3 CH4,gas 4.81 -13.04 -17.85 -4.463 0.30483E+05 -15.853 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.18 -15.24 -7.619 0.26017E+05 -13.237 6 S2,gas -7.03 -42.50 -35.47 -5.456 0.60558E+05 -33.466 7 CO,gas 3.51 -13.25 -16.76 -5.158 0.28621E+05 -14.762 8 SO3,gas 17.43 -21.46 -38.89 -9.721 0.66395E+05 -36.885 9 SO2,gas 1.14 -21.39 -22.52 -6.007 0.38460E+05 -20.525 10 HCl,gas 5.48 -12.28 -17.76 -8.881 0.30328E+05 -15.762 11 acmite 7.74 4.47 -3.27 -0.339 0.55756E+04 15 albite-high 0.75 -2.46 -3.21 -0.247 0.54862E+04 16 albite -0.33 -2.46 -2.14 -0.164 0.36455E+04 19 spessartine 24.55 20.68 -3.86 -0.193 0.65993E+04 20 analcite 3.37 0.95 -2.42 -0.269 0.41273E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.56 -4.65 -0.258 0.79403E+04 27 phlogopite 27.15 22.24 -4.90 -0.272 0.83725E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.37 -3.36 -1.119 0.57299E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.37 -3.20 -1.068 0.54686E+04 38 carnegieite-low 9.06 4.37 -4.69 -0.671 0.80153E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 1.70 -3.70 -0.217 0.63131E+04 43 celadonite-Fe 3.94 -0.52 -4.46 -0.262 0.76184E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14705E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82450E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68766E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.95 -3.30 -0.330 0.56303E+04 97 kalsilite 7.62 3.39 -4.23 -0.604 0.72193E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 -0.02 -4.19 -0.419 0.71582E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.44 -1.01 -0.078 0.17241E+04 120 muscovite 2.68 2.12 -0.56 -0.033 0.95644E+03 121 paragonite 4.34 3.10 -1.24 -0.073 0.21164E+04 122 nepheline 8.38 4.37 -4.01 -0.573 0.68433E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40545E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -4.86 -3.90 -1.301 0.66664E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41337E+04 153 sanidine -1.22 -3.44 -2.22 -0.171 0.37918E+04 155 siderite -2.59 -6.99 -4.40 -1.467 0.75127E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 11.91 -1.27 -0.038 0.21713E+04 165 stilpnomelane-Mg 27.60 23.05 -4.55 -0.136 0.77663E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78768E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.73 -3.30 -0.202 0.56300E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.41 -3.15 -0.193 0.53828E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.87 -2.71 -0.166 0.46248E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.55 -2.59 -0.158 0.44157E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.30 -1.10 -0.071 0.18766E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.63 -0.96 -0.061 0.16311E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 -0.04 -2.11 -0.163 0.36100E+04 243 an25ab75 2.71 0.57 -2.14 -0.164 0.36491E+04 244 an30ab70 3.34 1.18 -2.16 -0.167 0.36964E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.2090000 g New total amount of reactant added: 0.2190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1074E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.2190000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.1000E+01 Moles total = 0.5551E+02 kg total = 0.1000E+01 Activity = 1.0000 Stoichiometric ionic strength = .4141426E-03 Osmotic coef. = 0.9879 True ionic strength = .5110380E-03 Chg. balance for total moles = 0.1074E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.39434E-08 -8.4041 0.37596E-08 -8.4249 0.95341E+00 -0.0207 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13151E-03 -3.8811 0.95320E+00 -0.0208 4 SO4-- 0.25481E-04 -4.5938 0.22204E-04 -4.6536 0.87140E+00 -0.0598 5 HCO3- 0.12634E-04 -4.8984 0.12044E-04 -4.9192 0.95325E+00 -0.0208 6 HS- 0.16596E-12 -12.7800 0.15819E-12 -12.8008 0.95320E+00 -0.0208 7 Al+++ 0.42730E-22 -22.3693 0.32041E-22 -22.4943 0.74986E+00 -0.1250 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.14511E-05 -5.8383 0.12642E-05 -5.8982 0.87117E+00 -0.0599 10 Mg++ 0.59129E-08 -8.2282 0.51503E-08 -8.2882 0.87103E+00 -0.0600 11 Fe++ 0.34974E-10 -10.4563 0.30464E-10 -10.5162 0.87106E+00 -0.0600 12 K+ 0.46478E-04 -4.3328 0.44305E-04 -4.3535 0.95326E+00 -0.0208 13 Na+ 0.43427E-03 -3.3622 0.41394E-03 -3.3831 0.95319E+00 -0.0208 14 Mn++ 0.46630E-08 -8.3313 0.40619E-08 -8.3913 0.87109E+00 -0.0599 15 HPO4-- 0.45783E-07 -7.3393 0.39896E-07 -7.3991 0.87141E+00 -0.0598 16 HSiO3- 0.10426E-03 -3.9819 0.99383E-04 -4.0027 0.95320E+00 -0.0208 17 Ca(HSiO3)+ 0.29529E-08 -8.5297 0.28149E-08 -8.5505 0.95326E+00 -0.0208 18 Mg(HSiO3)+ 0.14972E-10 -10.8247 0.14272E-10 -10.8455 0.95326E+00 -0.0208 19 NaHSiO3,aq 0.65338E-06 -6.1848 0.65338E-06 -6.1848 0.10000E+01 0.0000 20 AlO+ 0.30699E-12 -12.5129 0.29264E-12 -12.5337 0.95326E+00 -0.0208 21 AlOH+2 0.63268E-17 -17.1988 0.55114E-17 -17.2587 0.87112E+00 -0.0599 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.97056E-05 -5.0130 0.92507E-05 -5.0338 0.95313E+00 -0.0208 24 CH4,aq 0.84208E-19 -19.0746 0.84197E-19 -19.0747 0.99987E+00 -0.0001 29 CO,aq 0.10389E-17 -17.9834 0.10389E-17 -17.9834 0.10000E+01 0.0000 30 CO2,aq 0.91305E-07 -7.0395 0.91294E-07 -7.0396 0.99987E+00 -0.0001 31 CO3-2 0.33992E-06 -6.4686 0.29619E-06 -6.5284 0.87134E+00 -0.0598 32 CaCO3,aq 0.45859E-08 -8.3386 0.45859E-08 -8.3386 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40244E-09 -9.3953 0.38363E-09 -9.4161 0.95326E+00 -0.0208 34 CaCl+ 0.27790E-09 -9.5561 0.26491E-09 -9.5769 0.95326E+00 -0.0208 35 CaCl2,aq 0.81114E-14 -14.0909 0.81114E-14 -14.0909 0.10000E+01 0.0000 36 CaOH+ 0.24872E-07 -7.6043 0.23710E-07 -7.6251 0.95326E+00 -0.0208 37 CaSO4,aq 0.87459E-08 -8.0582 0.87459E-08 -8.0582 0.10000E+01 0.0000 38 HCl,aq 0.92998E-13 -13.0315 0.92998E-13 -13.0315 0.10000E+01 0.0000 43 FeCl+ 0.65457E-14 -14.1840 0.62398E-14 -14.2048 0.95326E+00 -0.0208 46 FeO,aq 0.85229E-10 -10.0694 0.85229E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.28181E-09 -9.5501 0.26864E-09 -9.5708 0.95326E+00 -0.0208 48 HFeO2- 0.25580E-09 -9.5921 0.24383E-09 -9.6129 0.95320E+00 -0.0208 49 FeO+ 0.32625E-13 -13.4865 0.31100E-13 -13.5072 0.95326E+00 -0.0208 50 FeOH+2 0.24976E-19 -19.6025 0.21757E-19 -19.6624 0.87112E+00 -0.0599 51 FeO2- 0.45367E-09 -9.3433 0.43244E-09 -9.3641 0.95320E+00 -0.0208 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44190E-09 -9.3547 0.44184E-09 -9.3547 0.99987E+00 -0.0001 54 KCl,aq 0.10317E-09 -9.9865 0.10317E-09 -9.9865 0.10000E+01 0.0000 55 KHSO4,aq 0.98974E-17 -17.0045 0.98974E-17 -17.0045 0.10000E+01 0.0000 56 KOH,aq 0.51374E-08 -8.2893 0.51374E-08 -8.2893 0.10000E+01 0.0000 57 KSO4- 0.15901E-07 -7.7986 0.15156E-07 -7.8194 0.95320E+00 -0.0208 58 MgCO3,aq 0.46685E-11 -11.3308 0.46685E-11 -11.3308 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16719E-11 -11.7768 0.15938E-11 -11.7976 0.95326E+00 -0.0208 60 MgCl+ 0.10278E-11 -11.9881 0.97977E-12 -12.0089 0.95326E+00 -0.0208 61 MgOH+ 0.56138E-09 -9.2507 0.53514E-09 -9.2715 0.95326E+00 -0.0208 63 MnO,aq 0.30336E-09 -9.5180 0.30336E-09 -9.5180 0.10000E+01 0.0000 64 MnOH+ 0.34905E-08 -8.4571 0.33274E-08 -8.4779 0.95326E+00 -0.0208 65 MnO2-2 0.85182E-15 -15.0697 0.74222E-15 -15.1295 0.87134E+00 -0.0598 66 HMnO2- 0.63428E-12 -12.1977 0.60459E-12 -12.2185 0.95320E+00 -0.0208 69 MnCl+ 0.33914E-11 -11.4696 0.32329E-11 -11.4904 0.95326E+00 -0.0208 70 MnSO4,aq 0.25560E-10 -10.5924 0.25560E-10 -10.5924 0.10000E+01 0.0000 71 NaCl,aq 0.17775E-07 -7.7502 0.17775E-07 -7.7502 0.10000E+01 0.0000 72 NaOH,aq 0.48380E-07 -7.3153 0.48380E-07 -7.3153 0.10000E+01 0.0000 74 OH- 0.16739E-03 -3.7763 0.15955E-03 -3.7971 0.95313E+00 -0.0208 79 HPO3-2 0.63899E-19 -19.1945 0.55678E-19 -19.2543 0.87134E+00 -0.0598 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.27587E-08 -8.5593 0.26297E-08 -8.5801 0.95323E+00 -0.0208 84 PO4-3 0.12336E-10 -10.9088 0.92673E-11 -11.0330 0.75123E+00 -0.1242 87 H2P2O7-2 0.62115E-18 -18.2068 0.54123E-18 -18.2666 0.87134E+00 -0.0598 88 HP2O7-3 0.39365E-16 -16.4049 0.29519E-16 -16.5299 0.74987E+00 -0.1250 89 P2O7-4 0.31836E-17 -17.4971 0.19370E-17 -17.7129 0.60842E+00 -0.2158 90 H2S,aq 0.17872E-14 -14.7478 0.17870E-14 -14.7479 0.99987E+00 -0.0001 97 SO3-2 0.15344E-14 -14.8141 0.13377E-14 -14.8736 0.87181E+00 -0.0596 98 HSO3- 0.30877E-15 -15.5104 0.29432E-15 -15.5312 0.95320E+00 -0.0208 99 HSO4- 0.81252E-10 -10.0902 0.77458E-10 -10.1109 0.95330E+00 -0.0208 Charge balance for all species = 0.1074E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3943353E-08 -.3115119E-03 -.3139645E+00 0.0000 2 H2O 0.1000000E+01 0.5550833E+02 0.9999331E+06 0.0000 3 Cl- 0.1379628E-03 0.1379810E-03 0.4891517E+01 4.5438 4 SO4-- 0.2548098E-04 0.2550570E-04 0.2449957E+01 12.1961 5 HCO3- 0.1263442E-04 0.1307065E-04 0.7974815E+00 3.5056 6 HS- 0.1659600E-12 0.2849559E-10 0.9423440E-06 -4.3760 7 Al+++ 0.4272966E-22 0.9721193E-05 0.2622750E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4878793E-03 0.4688961E+02 -3.4168 9 Ca++ 0.1451113E-05 0.1492950E-05 0.5983051E-01 10.9515 10 Mg++ 0.5912900E-08 0.6496618E-08 0.1579353E-03 8.5615 11 Fe++ 0.3497393E-10 0.1314996E-08 0.7343373E-04 6.3335 12 K+ 0.4647797E-04 0.4649911E-04 0.1818088E+01 4.0713 13 Na+ 0.4342713E-03 0.4349909E-03 0.9999692E+01 5.0418 14 Mn++ 0.4663036E-08 0.8486481E-08 0.4661995E-03 8.4584 15 HPO4-- 0.4578317E-07 0.4855424E-07 0.4659879E-02 9.4506 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3613275E-02 -.3114965E-03 -.3301778E-02 0.0000000E+00 2 H2O 0.5550550E+02 0.5550559E+02 -.8199926E-04 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3157371E-04 0.2550444E-04 0.6069265E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6069237E-05 0.2849418E-10 -.6069265E-05 0.0000000E+00 7 Al+++ 0.7141024E-03 0.9720712E-05 0.7043817E-03 0.0000000E+00 8 H4SiO4 0.2280399E-02 0.4878551E-03 0.1792544E-02 0.0000000E+00 9 Ca++ 0.2663523E-03 0.1492877E-05 0.2648594E-03 0.0000000E+00 10 Mg++ 0.1738095E-03 0.6496296E-08 0.1738030E-03 0.0000000E+00 11 Fe++ 0.1561489E-03 0.1314931E-08 0.1561476E-03 0.0000000E+00 12 K+ 0.4649682E-04 0.4649682E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.4349694E-03 0.4349694E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3797153E-05 0.8486061E-08 0.3788666E-05 0.0000000E+00 15 HPO4-- 0.1295949E-05 0.4855184E-07 0.1247397E-05 0.0000000E+00 Chg. balance for solid moles: 0.2304E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.2190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4158E-06 -6.381 0.2089E-03 -3.680 0.9910E-01 0.6637E-04 clinochlore 0.3476E-04 -4.459 0.1932E-01 -1.714 9.167 0.7349E-02 daphnite 0.2152E-04 -4.667 0.1535E-01 -1.814 7.285 0.4653E-02 chlorite-Mn 0.7577E-06 -6.120 0.5372E-03 -3.270 0.2549 0.1712E-03 hematite 0.2428E-04 -4.615 0.3877E-02 -2.411 1.840 0.7348E-03 kaolinite 0.3237E-04 -4.490 0.8358E-02 -2.078 3.965 0.3216E-02 lawsonite 0.5656E-04 -4.248 0.1777E-01 -1.750 8.432 0.5731E-02 stilbite 0.2062E-03 -3.686 0.1453 -0.838 68.96 0.6778E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1328E-01 0.1328E-01 1.0000 -1.877 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.210758 g Volume = 0.089706 cm3 Porosity: 91.7519% V(tot) - V(min): 0.99789E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2190000 g log = -0.6596 Original solution: 1000.0103000 g Original solution / Rock added: 4566.26 (Water/Rock Ratio), log = 3.6596 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.9862E-05 1.0073 0.1045E-04 0.1037E-04 CH4,gas 0.1250E-15 1.0129 0.1331E-15 0.1314E-15 H2,gas 0.5758E-06 1.0006 0.6060E-06 0.6057E-06 H2S,gas 0.4975E-13 0.9959 0.5212E-13 0.5233E-13 S2,gas 0.2633E-33 1.0000 0.2770E-33 0.2770E-33 CO,gas 0.1559E-14 1.0000 0.1640E-14 0.1640E-14 SO3,gas 0.1115E-36 1.0000 0.1173E-36 0.1173E-36 SO2,gas 0.2557E-20 1.0000 0.2690E-20 0.2690E-20 HCl,gas 0.1561E-15 1.0000 0.1642E-15 0.1642E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.34 -6.98 -2.327 0.11920E+05 -4.981 3 CH4,gas 4.81 -13.07 -17.88 -4.469 0.30522E+05 -15.876 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.23 -15.28 -7.642 0.26095E+05 -13.283 6 S2,gas -7.03 -42.59 -35.56 -5.470 0.60713E+05 -33.557 7 CO,gas 3.51 -13.27 -16.79 -5.165 0.28660E+05 -14.785 8 SO3,gas 17.43 -21.50 -38.93 -9.733 0.66473E+05 -36.931 9 SO2,gas 1.14 -21.43 -22.57 -6.019 0.38538E+05 -20.570 10 HCl,gas 5.48 -12.31 -17.78 -8.892 0.30367E+05 -15.785 11 acmite 7.74 4.51 -3.23 -0.336 0.55160E+04 15 albite-high 0.75 -2.43 -3.18 -0.244 0.54265E+04 16 albite -0.33 -2.43 -2.10 -0.162 0.35859E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65986E+04 20 analcite 3.37 0.99 -2.38 -0.265 0.40676E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.60 -4.61 -0.256 0.78676E+04 27 phlogopite 27.15 22.29 -4.86 -0.270 0.82999E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.39 -3.38 -1.126 0.57692E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.39 -3.23 -1.075 0.55079E+04 38 carnegieite-low 9.06 4.41 -4.66 -0.666 0.79557E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 1.75 -3.65 -0.215 0.62404E+04 43 celadonite-Fe 3.94 -0.48 -4.42 -0.260 0.75457E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14702E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82450E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 0.99 -3.26 -0.326 0.55707E+04 97 kalsilite 7.62 3.43 -4.19 -0.598 0.71467E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.02 -4.15 -0.415 0.70856E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.40 -0.97 -0.074 0.16514E+04 120 muscovite 2.68 2.16 -0.52 -0.030 0.88378E+03 121 paragonite 4.34 3.13 -1.20 -0.071 0.20567E+04 122 nepheline 8.38 4.41 -3.97 -0.568 0.67836E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40543E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -4.89 -3.93 -1.309 0.67054E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41335E+04 153 sanidine -1.22 -3.40 -2.18 -0.168 0.37191E+04 155 siderite -2.59 -7.01 -4.42 -1.474 0.75520E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 11.93 -1.25 -0.037 0.21350E+04 165 stilpnomelane-Mg 27.60 23.07 -4.53 -0.135 0.77299E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78763E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.72 -3.28 -0.201 0.56060E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.40 -3.14 -0.192 0.53631E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.86 -2.69 -0.165 0.46008E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.54 -2.57 -0.158 0.43961E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.32 -1.09 -0.070 0.18526E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.64 -0.94 -0.061 0.16114E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 -0.01 -2.09 -0.160 0.35623E+04 243 an25ab75 2.71 0.60 -2.11 -0.162 0.36043E+04 244 an30ab70 3.34 1.20 -2.14 -0.165 0.36547E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.2190000 g New total amount of reactant added: 0.2290000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1074E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.2290000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.9999E+00 Moles total = 0.5551E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .4234384E-03 Osmotic coef. = 0.9878 True ionic strength = .5252730E-03 Chg. balance for total moles = 0.1074E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.37554E-08 -8.4253 0.35791E-08 -8.4462 0.95303E+00 -0.0209 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13145E-03 -3.8812 0.95281E+00 -0.0210 4 SO4-- 0.25481E-04 -4.5938 0.22169E-04 -4.6543 0.87001E+00 -0.0605 5 HCO3- 0.12622E-04 -4.8989 0.12027E-04 -4.9198 0.95286E+00 -0.0210 6 HS- 0.15779E-12 -12.8019 0.15035E-12 -12.8229 0.95282E+00 -0.0210 7 Al+++ 0.36997E-22 -22.4318 0.27643E-22 -22.5584 0.74716E+00 -0.1266 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.13172E-05 -5.8804 0.11457E-05 -5.9409 0.86977E+00 -0.0606 10 Mg++ 0.53672E-08 -8.2703 0.46674E-08 -8.3309 0.86962E+00 -0.0607 11 Fe++ 0.31746E-10 -10.4983 0.27608E-10 -10.5590 0.86966E+00 -0.0607 12 K+ 0.48600E-04 -4.3134 0.46310E-04 -4.3343 0.95287E+00 -0.0210 13 Na+ 0.44677E-03 -3.3499 0.42568E-03 -3.3709 0.95281E+00 -0.0210 14 Mn++ 0.42337E-08 -8.3733 0.36820E-08 -8.4339 0.86969E+00 -0.0606 15 HPO4-- 0.50600E-07 -7.2958 0.44023E-07 -7.3563 0.87002E+00 -0.0605 16 HSiO3- 0.10957E-03 -3.9603 0.10440E-03 -3.9813 0.95281E+00 -0.0210 17 Ca(HSiO3)+ 0.28122E-08 -8.5510 0.26797E-08 -8.5719 0.95288E+00 -0.0210 18 Mg(HSiO3)+ 0.14259E-10 -10.8459 0.13587E-10 -10.8669 0.95288E+00 -0.0210 19 NaHSiO3,aq 0.70582E-06 -6.1513 0.70582E-06 -6.1513 0.10000E+01 0.0000 20 AlO+ 0.29236E-12 -12.5341 0.27858E-12 -12.5550 0.95288E+00 -0.0210 21 AlOH+2 0.57429E-17 -17.2409 0.49947E-17 -17.3015 0.86972E+00 -0.0606 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.10199E-04 -4.9914 0.97175E-05 -5.0124 0.95275E+00 -0.0210 24 CH4,aq 0.80049E-19 -19.0966 0.80038E-19 -19.0967 0.99987E+00 -0.0001 29 CO,aq 0.98762E-18 -18.0054 0.98762E-18 -18.0054 0.10000E+01 0.0000 30 CO2,aq 0.86800E-07 -7.0615 0.86788E-07 -7.0615 0.99987E+00 -0.0001 31 CO3-2 0.35715E-06 -6.4471 0.31070E-06 -6.5077 0.86994E+00 -0.0605 32 CaCO3,aq 0.43596E-08 -8.3606 0.43596E-08 -8.3606 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.36435E-09 -9.4385 0.34719E-09 -9.4594 0.95288E+00 -0.0210 34 CaCl+ 0.25184E-09 -9.5989 0.23998E-09 -9.6198 0.95288E+00 -0.0210 35 CaCl2,aq 0.73450E-14 -14.1340 0.73450E-14 -14.1340 0.10000E+01 0.0000 36 CaOH+ 0.23687E-07 -7.6255 0.22571E-07 -7.6464 0.95288E+00 -0.0210 37 CaSO4,aq 0.79134E-08 -8.1016 0.79134E-08 -8.1016 0.10000E+01 0.0000 38 HCl,aq 0.88495E-13 -13.0531 0.88495E-13 -13.0531 0.10000E+01 0.0000 43 FeCl+ 0.59320E-14 -14.2268 0.56525E-14 -14.2478 0.95288E+00 -0.0210 46 FeO,aq 0.85228E-10 -10.0694 0.85228E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.26838E-09 -9.5713 0.25573E-09 -9.5922 0.95288E+00 -0.0210 48 HFeO2- 0.26882E-09 -9.5705 0.25613E-09 -9.5915 0.95281E+00 -0.0210 49 FeO+ 0.31070E-13 -13.5077 0.29606E-13 -13.5286 0.95288E+00 -0.0210 50 FeOH+2 0.22671E-19 -19.6445 0.19718E-19 -19.7051 0.86972E+00 -0.0606 51 FeO2- 0.47675E-09 -9.3217 0.45426E-09 -9.3427 0.95281E+00 -0.0210 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44189E-09 -9.3547 0.44184E-09 -9.3547 0.99987E+00 -0.0001 54 KCl,aq 0.10779E-09 -9.9674 0.10779E-09 -9.9674 0.10000E+01 0.0000 55 KHSO4,aq 0.98326E-17 -17.0073 0.98326E-17 -17.0073 0.10000E+01 0.0000 56 KOH,aq 0.56408E-08 -8.2487 0.56408E-08 -8.2487 0.10000E+01 0.0000 57 KSO4- 0.16600E-07 -7.7799 0.15817E-07 -7.8009 0.95281E+00 -0.0210 58 MgCO3,aq 0.44381E-11 -11.3528 0.44381E-11 -11.3528 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15137E-11 -11.8200 0.14424E-11 -11.8409 0.95288E+00 -0.0210 60 MgCl+ 0.93144E-12 -12.0308 0.88756E-12 -12.0518 0.95288E+00 -0.0210 61 MgOH+ 0.53463E-09 -9.2719 0.50944E-09 -9.2929 0.95288E+00 -0.0210 63 MnO,aq 0.30343E-09 -9.5179 0.30343E-09 -9.5179 0.10000E+01 0.0000 64 MnOH+ 0.33250E-08 -8.4782 0.31683E-08 -8.4992 0.95288E+00 -0.0210 65 MnO2-2 0.94168E-15 -15.0261 0.81920E-15 -15.0866 0.86994E+00 -0.0605 66 HMnO2- 0.66671E-12 -12.1761 0.63525E-12 -12.1971 0.95281E+00 -0.0210 69 MnCl+ 0.30742E-11 -11.5123 0.29293E-11 -11.5332 0.95288E+00 -0.0210 70 MnSO4,aq 0.23133E-10 -10.6358 0.23133E-10 -10.6358 0.10000E+01 0.0000 71 NaCl,aq 0.18271E-07 -7.7382 0.18271E-07 -7.7382 0.10000E+01 0.0000 72 NaOH,aq 0.52262E-07 -7.2818 0.52262E-07 -7.2818 0.10000E+01 0.0000 74 OH- 0.17591E-03 -3.7547 0.16760E-03 -3.7757 0.95275E+00 -0.0210 79 HPO3-2 0.70622E-19 -19.1511 0.61437E-19 -19.2116 0.86994E+00 -0.0605 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.28991E-08 -8.5377 0.27624E-08 -8.5587 0.95285E+00 -0.0210 84 PO4-3 0.14350E-10 -10.8431 0.10742E-10 -10.9689 0.74856E+00 -0.1258 87 H2P2O7-2 0.68650E-18 -18.1634 0.59722E-18 -18.2239 0.86994E+00 -0.0605 88 HP2O7-3 0.45794E-16 -16.3392 0.34216E-16 -16.4658 0.74717E+00 -0.1266 89 P2O7-4 0.39012E-17 -17.4088 0.23585E-17 -17.6274 0.60455E+00 -0.2186 90 H2S,aq 0.16170E-14 -14.7913 0.16168E-14 -14.7913 0.99987E+00 -0.0001 97 SO3-2 0.15344E-14 -14.8141 0.13355E-14 -14.8743 0.87042E+00 -0.0603 98 HSO3- 0.29359E-15 -15.5323 0.27973E-15 -15.5533 0.95281E+00 -0.0210 99 HSO4- 0.77258E-10 -10.1121 0.73620E-10 -10.1330 0.95292E+00 -0.0209 Charge balance for all species = 0.1074E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3755446E-08 -.3273852E-03 -.3299625E+00 0.0000 2 H2O 0.1000000E+01 0.5550834E+02 0.9999323E+06 0.0000 3 Cl- 0.1379626E-03 0.1379813E-03 0.4891522E+01 4.5650 4 SO4-- 0.2548117E-04 0.2550576E-04 0.2449959E+01 12.2382 5 HCO3- 0.1262199E-04 0.1307067E-04 0.7974823E+00 3.5264 6 HS- 0.1577939E-12 0.2560132E-10 0.8466300E-06 -4.3767 7 Al+++ 0.3699712E-22 0.1021500E-04 0.2755975E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4932361E-03 0.4740440E+02 -3.4168 9 Ca++ 0.1317181E-05 0.1356570E-05 0.5436496E-01 10.9515 10 Mg++ 0.5367179E-08 0.5922950E-08 0.1439891E-03 8.5615 11 Fe++ 0.3174591E-10 0.1334431E-08 0.7451895E-04 6.3335 12 K+ 0.4860011E-04 0.4862246E-04 0.1901108E+01 4.1119 13 Na+ 0.4467684E-03 0.4475448E-03 0.1028828E+02 5.0753 14 Mn++ 0.4233694E-08 0.7888990E-08 0.4333763E-03 8.4585 15 HPO4-- 0.5060036E-07 0.5351379E-07 0.5135856E-02 9.5361 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3778860E-02 -.3273683E-03 -.3451492E-02 0.0000000E+00 2 H2O 0.5550538E+02 0.5550548E+02 -.1031896E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3185084E-04 0.2550444E-04 0.6346396E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6346371E-05 0.2560000E-10 -.6346396E-05 0.0000000E+00 7 Al+++ 0.7467098E-03 0.1021447E-04 0.7364954E-03 0.0000000E+00 8 H4SiO4 0.2384527E-02 0.4932107E-03 0.1891317E-02 0.0000000E+00 9 Ca++ 0.2778537E-03 0.1356500E-05 0.2764972E-03 0.0000000E+00 10 Mg++ 0.1817460E-03 0.5922645E-08 0.1817401E-03 0.0000000E+00 11 Fe++ 0.1632790E-03 0.1334362E-08 0.1632776E-03 0.0000000E+00 12 K+ 0.4861996E-04 0.4861996E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.4475218E-03 0.4475218E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.3970538E-05 0.7888584E-08 0.3962650E-05 0.0000000E+00 15 HPO4-- 0.1355125E-05 0.5351104E-07 0.1301614E-05 0.0000000E+00 Chg. balance for solid moles: 0.2245E-18 Mass of aqueous solution: 0.100002E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.2290000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4339E-06 -6.363 0.2179E-03 -3.662 0.9832E-01 0.6925E-04 clinochlore 0.3635E-04 -4.440 0.2020E-01 -1.695 9.114 0.7685E-02 daphnite 0.2250E-04 -4.648 0.1605E-01 -1.794 7.243 0.4865E-02 chlorite-Mn 0.7925E-06 -6.101 0.5619E-03 -3.250 0.2535 0.1791E-03 hematite 0.2539E-04 -4.595 0.4054E-02 -2.392 1.829 0.7684E-03 kaolinite 0.3428E-04 -4.465 0.8849E-02 -2.053 3.992 0.3405E-02 lawsonite 0.5529E-04 -4.257 0.1737E-01 -1.760 7.838 0.5603E-02 stilbite 0.2190E-03 -3.659 0.1544 -0.811 69.63 0.7200E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1329E-01 0.1329E-01 1.0000 -1.877 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.221675 g Volume = 0.094570 cm3 Porosity: 91.3365% V(tot) - V(min): 0.99703E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2290000 g log = -0.6402 Original solution: 1000.0103000 g Original solution / Rock added: 4366.86 (Water/Rock Ratio), log = 3.6402 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.9375E-05 1.0073 0.9934E-05 0.9862E-05 CH4,gas 0.1188E-15 1.0129 0.1266E-15 0.1250E-15 H2,gas 0.5758E-06 1.0006 0.6060E-06 0.6057E-06 H2S,gas 0.4501E-13 0.9959 0.4715E-13 0.4735E-13 S2,gas 0.2156E-33 1.0000 0.2268E-33 0.2268E-33 CO,gas 0.1482E-14 1.0000 0.1559E-14 0.1559E-14 SO3,gas 0.1009E-36 1.0000 0.1062E-36 0.1062E-36 SO2,gas 0.2314E-20 1.0000 0.2434E-20 0.2434E-20 HCl,gas 0.1485E-15 1.0000 0.1563E-15 0.1563E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.37 -7.00 -2.334 0.11957E+05 -5.003 3 CH4,gas 4.81 -13.09 -17.90 -4.474 0.30560E+05 -15.898 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.27 -15.33 -7.663 0.26170E+05 -13.326 6 S2,gas -7.03 -42.68 -35.64 -5.484 0.60862E+05 -33.644 7 CO,gas 3.51 -13.30 -16.81 -5.171 0.28698E+05 -14.807 8 SO3,gas 17.43 -21.55 -38.97 -9.744 0.66547E+05 -36.974 9 SO2,gas 1.14 -21.48 -22.61 -6.030 0.38612E+05 -20.614 10 HCl,gas 5.48 -12.33 -17.81 -8.903 0.30404E+05 -15.806 11 acmite 7.74 4.54 -3.20 -0.332 0.54587E+04 15 albite-high 0.75 -2.39 -3.14 -0.242 0.53693E+04 16 albite -0.33 -2.39 -2.07 -0.159 0.35286E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65981E+04 20 analcite 3.37 1.02 -2.35 -0.261 0.40104E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.64 -4.57 -0.254 0.77983E+04 27 phlogopite 27.15 22.33 -4.82 -0.268 0.82306E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.41 -3.40 -1.134 0.58067E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.41 -3.25 -1.083 0.55454E+04 38 carnegieite-low 9.06 4.44 -4.63 -0.661 0.78984E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 1.79 -3.61 -0.213 0.61711E+04 43 celadonite-Fe 3.94 -0.44 -4.38 -0.258 0.74764E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14701E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82450E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.02 -3.23 -0.323 0.55134E+04 97 kalsilite 7.62 3.48 -4.14 -0.592 0.70773E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.06 -4.11 -0.411 0.70163E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.36 -0.93 -0.071 0.15821E+04 120 muscovite 2.68 2.20 -0.48 -0.028 0.81447E+03 121 paragonite 4.34 3.17 -1.17 -0.069 0.19995E+04 122 nepheline 8.38 4.44 -3.94 -0.563 0.67264E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40541E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -4.91 -3.95 -1.316 0.67428E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41333E+04 153 sanidine -1.22 -3.36 -2.14 -0.164 0.36498E+04 155 siderite -2.59 -7.03 -4.44 -1.482 0.75896E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 11.95 -1.23 -0.037 0.21004E+04 165 stilpnomelane-Mg 27.60 23.09 -4.51 -0.135 0.76953E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78760E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.70 -3.27 -0.200 0.55831E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.39 -3.13 -0.192 0.53442E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.84 -2.68 -0.164 0.45779E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.52 -2.56 -0.157 0.43772E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.33 -1.07 -0.069 0.18297E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.65 -0.93 -0.060 0.15925E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.02 -2.06 -0.158 0.35165E+04 243 an25ab75 2.71 0.62 -2.09 -0.160 0.35614E+04 244 an30ab70 3.34 1.23 -2.12 -0.163 0.36146E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.2290000 g New total amount of reactant added: 0.2390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1074E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.2390000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.9999E+00 Moles total = 0.5551E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .4327763E-03 Osmotic coef. = 0.9877 True ionic strength = .5395597E-03 Chg. balance for total moles = 0.1074E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.35845E-08 -8.4456 0.34148E-08 -8.4666 0.95266E+00 -0.0211 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13140E-03 -3.8814 0.95243E+00 -0.0212 4 SO4-- 0.25481E-04 -4.5938 0.22134E-04 -4.6549 0.86864E+00 -0.0612 5 HCO3- 0.12609E-04 -4.8993 0.12010E-04 -4.9205 0.95249E+00 -0.0211 6 HS- 0.15037E-12 -12.8228 0.14322E-12 -12.8440 0.95244E+00 -0.0212 7 Al+++ 0.32248E-22 -22.4915 0.24008E-22 -22.6196 0.74449E+00 -0.1281 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.12009E-05 -5.9205 0.10429E-05 -5.9818 0.86839E+00 -0.0613 10 Mg++ 0.48935E-08 -8.3104 0.42488E-08 -8.3717 0.86824E+00 -0.0614 11 Fe++ 0.28944E-10 -10.5384 0.25132E-10 -10.5998 0.86828E+00 -0.0613 12 K+ 0.50722E-04 -4.2948 0.48313E-04 -4.3159 0.95250E+00 -0.0211 13 Na+ 0.45926E-03 -3.3379 0.43742E-03 -3.3591 0.95243E+00 -0.0212 14 Mn++ 0.38609E-08 -8.4133 0.33524E-08 -8.4746 0.86830E+00 -0.0613 15 HPO4-- 0.55674E-07 -7.2543 0.48361E-07 -7.3155 0.86864E+00 -0.0612 16 HSiO3- 0.11488E-03 -3.9397 0.10942E-03 -3.9609 0.95243E+00 -0.0212 17 Ca(HSiO3)+ 0.26842E-08 -8.5712 0.25567E-08 -8.5923 0.95250E+00 -0.0211 18 Mg(HSiO3)+ 0.13609E-10 -10.8662 0.12963E-10 -10.8873 0.95250E+00 -0.0211 19 NaHSiO3,aq 0.76016E-06 -6.1191 0.76016E-06 -6.1191 0.10000E+01 0.0000 20 AlO+ 0.27905E-12 -12.5543 0.26580E-12 -12.5755 0.95250E+00 -0.0211 21 AlOH+2 0.52361E-17 -17.2810 0.45467E-17 -17.3423 0.86834E+00 -0.0613 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.10694E-04 -4.9708 0.10185E-04 -4.9920 0.95237E+00 -0.0212 24 CH4,aq 0.76264E-19 -19.1177 0.76253E-19 -19.1177 0.99987E+00 -0.0001 29 CO,aq 0.94094E-18 -18.0264 0.94094E-18 -18.0264 0.10000E+01 0.0000 30 CO2,aq 0.82698E-07 -7.0825 0.82687E-07 -7.0826 0.99987E+00 -0.0001 31 CO3-2 0.37440E-06 -6.4267 0.32519E-06 -6.4879 0.86856E+00 -0.0612 32 CaCO3,aq 0.41536E-08 -8.3816 0.41536E-08 -8.3816 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.33133E-09 -9.4797 0.31560E-09 -9.5009 0.95250E+00 -0.0211 34 CaCl+ 0.22925E-09 -9.6397 0.21837E-09 -9.6608 0.95250E+00 -0.0211 35 CaCl2,aq 0.66808E-14 -14.1752 0.66808E-14 -14.1752 0.10000E+01 0.0000 36 CaOH+ 0.22609E-07 -7.6457 0.21535E-07 -7.6669 0.95250E+00 -0.0211 37 CaSO4,aq 0.71922E-08 -8.1431 0.71922E-08 -8.1431 0.10000E+01 0.0000 38 HCl,aq 0.84399E-13 -13.0737 0.84399E-13 -13.0737 0.10000E+01 0.0000 43 FeCl+ 0.53998E-14 -14.2676 0.51434E-14 -14.2888 0.95250E+00 -0.0211 46 FeO,aq 0.85228E-10 -10.0694 0.85228E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.25616E-09 -9.5915 0.24399E-09 -9.6126 0.95250E+00 -0.0211 48 HFeO2- 0.28186E-09 -9.5500 0.26845E-09 -9.5711 0.95243E+00 -0.0212 49 FeO+ 0.29656E-13 -13.5279 0.28247E-13 -13.5490 0.95250E+00 -0.0211 50 FeOH+2 0.20671E-19 -19.6846 0.17949E-19 -19.7460 0.86834E+00 -0.0613 51 FeO2- 0.49989E-09 -9.3011 0.47611E-09 -9.3223 0.95243E+00 -0.0212 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44189E-09 -9.3547 0.44183E-09 -9.3547 0.99987E+00 -0.0001 54 KCl,aq 0.11241E-09 -9.9492 0.11241E-09 -9.9492 0.10000E+01 0.0000 55 KHSO4,aq 0.97716E-17 -17.0100 0.97716E-17 -17.0100 0.10000E+01 0.0000 56 KOH,aq 0.61679E-08 -8.2099 0.61679E-08 -8.2099 0.10000E+01 0.0000 57 KSO4- 0.17298E-07 -7.7620 0.16475E-07 -7.7832 0.95243E+00 -0.0212 58 MgCO3,aq 0.42284E-11 -11.3738 0.42284E-11 -11.3738 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13765E-11 -11.8612 0.13111E-11 -11.8824 0.95250E+00 -0.0211 60 MgCl+ 0.84789E-12 -12.0717 0.80762E-12 -12.0928 0.95250E+00 -0.0211 61 MgOH+ 0.51029E-09 -9.2922 0.48605E-09 -9.3133 0.95250E+00 -0.0211 63 MnO,aq 0.30349E-09 -9.5179 0.30349E-09 -9.5179 0.10000E+01 0.0000 64 MnOH+ 0.31743E-08 -8.4984 0.30235E-08 -8.5195 0.95250E+00 -0.0211 65 MnO2-2 0.10363E-14 -14.9845 0.90011E-15 -15.0457 0.86856E+00 -0.0612 66 HMnO2- 0.69921E-12 -12.1554 0.66595E-12 -12.1766 0.95243E+00 -0.0212 69 MnCl+ 0.27990E-11 -11.5530 0.26661E-11 -11.5741 0.95250E+00 -0.0211 70 MnSO4,aq 0.21029E-10 -10.6772 0.21029E-10 -10.6772 0.10000E+01 0.0000 71 NaCl,aq 0.18767E-07 -7.7266 0.18767E-07 -7.7266 0.10000E+01 0.0000 72 NaOH,aq 0.56286E-07 -7.2496 0.56286E-07 -7.2496 0.10000E+01 0.0000 74 OH- 0.18444E-03 -3.7341 0.17566E-03 -3.7553 0.95237E+00 -0.0212 79 HPO3-2 0.77703E-19 -19.1096 0.67490E-19 -19.1708 0.86856E+00 -0.0612 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.30398E-08 -8.5172 0.28953E-08 -8.5383 0.95247E+00 -0.0211 84 PO4-3 0.16581E-10 -10.7804 0.12368E-10 -10.9077 0.74593E+00 -0.1273 87 H2P2O7-2 0.75534E-18 -18.1219 0.65606E-18 -18.1831 0.86856E+00 -0.0612 88 HP2O7-3 0.52916E-16 -16.2764 0.39396E-16 -16.4045 0.74451E+00 -0.1281 89 P2O7-4 0.47377E-17 -17.3244 0.28461E-17 -17.5457 0.60074E+00 -0.2213 90 H2S,aq 0.14696E-14 -14.8328 0.14694E-14 -14.8329 0.99987E+00 -0.0001 97 SO3-2 0.15343E-14 -14.8141 0.13334E-14 -14.8750 0.86906E+00 -0.0610 98 HSO3- 0.27978E-15 -15.5532 0.26647E-15 -15.5744 0.95243E+00 -0.0212 99 HSO4- 0.73624E-10 -10.1330 0.70130E-10 -10.1541 0.95254E+00 -0.0211 Charge balance for all species = 0.1074E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3584473E-08 -.3432977E-03 -.3460000E+00 0.0000 2 H2O 0.1000000E+01 0.5550834E+02 0.9999314E+06 0.0000 3 Cl- 0.1379624E-03 0.1379815E-03 0.4891527E+01 4.5852 4 SO4-- 0.2548125E-04 0.2550581E-04 0.2449962E+01 12.2783 5 HCO3- 0.1260911E-04 0.1307070E-04 0.7974831E+00 3.5462 6 HS- 0.1503675E-12 0.2270117E-10 0.7507219E-06 -4.3774 7 Al+++ 0.3224770E-22 0.1070998E-04 0.2889516E+00 2.7803 8 H4SiO4 0.3829605E-03 0.4986074E-03 0.4792059E+02 -3.4168 9 Ca++ 0.1200942E-05 0.1238141E-05 0.4961885E-01 10.9515 10 Mg++ 0.4893548E-08 0.5423900E-08 0.1318569E-03 8.5615 11 Fe++ 0.2894433E-10 0.1355588E-08 0.7570037E-04 6.3335 12 K+ 0.5072223E-04 0.5074581E-04 0.1984128E+01 4.1507 13 Na+ 0.4592636E-03 0.4600988E-03 0.1057686E+02 5.1075 14 Mn++ 0.3860877E-08 0.7363177E-08 0.4044907E-03 8.4586 15 HPO4-- 0.5567424E-07 0.5873058E-07 0.5636519E-02 9.6178 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3944445E-02 -.3432794E-03 -.3601166E-02 0.0000000E+00 2 H2O 0.5550525E+02 0.5550538E+02 -.1243850E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3212797E-04 0.2550445E-04 0.6623527E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6623505E-05 0.2269996E-10 -.6623527E-05 0.0000000E+00 7 Al+++ 0.7793172E-03 0.1070941E-04 0.7686078E-03 0.0000000E+00 8 H4SiO4 0.2488655E-02 0.4985808E-03 0.1990074E-02 0.0000000E+00 9 Ca++ 0.2893552E-03 0.1238075E-05 0.2881171E-03 0.0000000E+00 10 Mg++ 0.1896825E-03 0.5423611E-08 0.1896771E-03 0.0000000E+00 11 Fe++ 0.1704091E-03 0.1355516E-08 0.1704077E-03 0.0000000E+00 12 K+ 0.5074310E-04 0.5074310E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.4600742E-03 0.4600742E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.4143924E-05 0.7362784E-08 0.4136562E-05 0.0000000E+00 15 HPO4-- 0.1414301E-05 0.5872745E-07 0.1355573E-05 0.0000000E+00 Chg. balance for solid moles: 0.2495E-18 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.2390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4519E-06 -6.345 0.2270E-03 -3.644 0.9759E-01 0.7212E-04 clinochlore 0.3794E-04 -4.421 0.2109E-01 -1.676 9.066 0.8020E-02 daphnite 0.2348E-04 -4.629 0.1676E-01 -1.776 7.204 0.5078E-02 chlorite-Mn 0.8273E-06 -6.082 0.5865E-03 -3.232 0.2522 0.1869E-03 hematite 0.2649E-04 -4.577 0.4231E-02 -2.374 1.819 0.8020E-03 kaolinite 0.3620E-04 -4.441 0.9345E-02 -2.029 4.018 0.3596E-02 lawsonite 0.5401E-04 -4.267 0.1697E-01 -1.770 7.298 0.5473E-02 stilbite 0.2318E-03 -3.635 0.1634 -0.787 70.25 0.7621E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1329E-01 0.1329E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.232590 g Volume = 0.099434 cm3 Porosity: 90.9243% V(tot) - V(min): 0.99617E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2390000 g log = -0.6216 Original solution: 1000.0103000 g Original solution / Rock added: 4184.14 (Water/Rock Ratio), log = 3.6216 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.8932E-05 1.0073 0.9465E-05 0.9396E-05 CH4,gas 0.1132E-15 1.0129 0.1206E-15 0.1190E-15 H2,gas 0.5758E-06 1.0006 0.6060E-06 0.6057E-06 H2S,gas 0.4091E-13 0.9959 0.4286E-13 0.4303E-13 S2,gas 0.1781E-33 1.0000 0.1873E-33 0.1873E-33 CO,gas 0.1412E-14 1.0000 0.1486E-14 0.1486E-14 SO3,gas 0.9173E-37 1.0000 0.9649E-37 0.9649E-37 SO2,gas 0.2103E-20 1.0000 0.2212E-20 0.2212E-20 HCl,gas 0.1417E-15 1.0000 0.1490E-15 0.1490E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.18198E-10 102 lawsonite 9.68 9.68 0.00 0.000 0.36397E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.37914E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.39 -7.02 -2.341 0.11993E+05 -5.024 3 CH4,gas 4.81 -13.11 -17.92 -4.480 0.30596E+05 -15.919 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.31 -15.37 -7.684 0.26240E+05 -13.368 6 S2,gas -7.03 -42.76 -35.73 -5.497 0.61004E+05 -33.727 7 CO,gas 3.51 -13.32 -16.83 -5.178 0.28733E+05 -14.828 8 SO3,gas 17.43 -21.59 -39.02 -9.754 0.66618E+05 -37.016 9 SO2,gas 1.14 -21.52 -22.66 -6.041 0.38683E+05 -20.655 10 HCl,gas 5.48 -12.35 -17.83 -8.913 0.30439E+05 -15.827 11 acmite 7.74 4.57 -3.16 -0.329 0.54037E+04 15 albite-high 0.75 -2.36 -3.11 -0.239 0.53143E+04 16 albite -0.33 -2.36 -2.03 -0.156 0.34736E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65976E+04 20 analcite 3.37 1.05 -2.32 -0.257 0.39554E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.68 -4.53 -0.252 0.77321E+04 27 phlogopite 27.15 22.37 -4.78 -0.266 0.81643E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.44 -3.42 -1.141 0.58426E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.44 -3.27 -1.090 0.55813E+04 38 carnegieite-low 9.06 4.47 -4.59 -0.656 0.78434E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 1.83 -3.58 -0.210 0.61049E+04 43 celadonite-Fe 3.94 -0.40 -4.34 -0.255 0.74102E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14699E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.05 -3.20 -0.320 0.54584E+04 97 kalsilite 7.62 3.51 -4.11 -0.587 0.70111E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.10 -4.07 -0.407 0.69500E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.32 -0.89 -0.068 0.15158E+04 120 muscovite 2.68 2.24 -0.44 -0.026 0.74823E+03 121 paragonite 4.34 3.20 -1.14 -0.067 0.19445E+04 122 nepheline 8.38 4.47 -3.91 -0.558 0.66714E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40540E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -4.93 -3.97 -1.323 0.67785E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41332E+04 153 sanidine -1.22 -3.32 -2.10 -0.161 0.35836E+04 155 siderite -2.59 -7.05 -4.47 -1.489 0.76255E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 11.97 -1.21 -0.036 0.20673E+04 165 stilpnomelane-Mg 27.60 23.11 -4.49 -0.134 0.76622E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78757E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.69 -3.26 -0.199 0.55613E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.38 -3.12 -0.191 0.53261E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.83 -2.67 -0.163 0.45561E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.51 -2.55 -0.156 0.43590E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.34 -1.06 -0.068 0.18079E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.66 -0.92 -0.059 0.15744E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.05 -2.03 -0.156 0.34725E+04 243 an25ab75 2.71 0.65 -2.06 -0.159 0.35201E+04 244 an30ab70 3.34 1.25 -2.09 -0.161 0.35761E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.2390000 g New total amount of reactant added: 0.2490000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1074E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.2490000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.9999E+00 Moles total = 0.5551E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .4421492E-03 Osmotic coef. = 0.9876 True ionic strength = .5538894E-03 Chg. balance for total moles = 0.1074E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.34283E-08 -8.4649 0.32647E-08 -8.4862 0.95229E+00 -0.0212 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13135E-03 -3.8816 0.95206E+00 -0.0213 4 SO4-- 0.25481E-04 -4.5938 0.22099E-04 -4.6556 0.86728E+00 -0.0618 5 HCO3- 0.12596E-04 -4.8998 0.11993E-04 -4.9211 0.95211E+00 -0.0213 6 HS- 0.14359E-12 -12.8429 0.13670E-12 -12.8642 0.95206E+00 -0.0213 7 Al+++ 0.28281E-22 -22.5485 0.20980E-22 -22.6782 0.74187E+00 -0.1297 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.10994E-05 -5.9588 0.95325E-06 -6.0208 0.86703E+00 -0.0620 10 Mg++ 0.44800E-08 -8.3487 0.38836E-08 -8.4108 0.86687E+00 -0.0620 11 Fe++ 0.26498E-10 -10.5768 0.22972E-10 -10.6388 0.86691E+00 -0.0620 12 K+ 0.52844E-04 -4.2770 0.50314E-04 -4.2983 0.95212E+00 -0.0213 13 Na+ 0.47176E-03 -3.3263 0.44914E-03 -3.3476 0.95205E+00 -0.0213 14 Mn++ 0.35352E-08 -8.4516 0.30648E-08 -8.5136 0.86694E+00 -0.0620 15 HPO4-- 0.61005E-07 -7.2146 0.52908E-07 -7.2765 0.86728E+00 -0.0618 16 HSiO3- 0.12021E-03 -3.9201 0.11445E-03 -3.9414 0.95206E+00 -0.0213 17 Ca(HSiO3)+ 0.25673E-08 -8.5905 0.24444E-08 -8.6118 0.95213E+00 -0.0213 18 Mg(HSiO3)+ 0.13017E-10 -10.8855 0.12393E-10 -10.9068 0.95213E+00 -0.0213 19 NaHSiO3,aq 0.81640E-06 -6.0881 0.81640E-06 -6.0881 0.10000E+01 0.0000 20 AlO+ 0.26689E-12 -12.5737 0.25412E-12 -12.5950 0.95213E+00 -0.0213 21 AlOH+2 0.47936E-17 -17.3193 0.41559E-17 -17.3813 0.86697E+00 -0.0620 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.11190E-04 -4.9512 0.10653E-04 -4.9725 0.95199E+00 -0.0214 24 CH4,aq 0.72805E-19 -19.1378 0.72795E-19 -19.1379 0.99986E+00 -0.0001 29 CO,aq 0.89829E-18 -18.0466 0.89829E-18 -18.0466 0.10000E+01 0.0000 30 CO2,aq 0.78951E-07 -7.1026 0.78940E-07 -7.1027 0.99986E+00 -0.0001 31 CO3-2 0.39165E-06 -6.4071 0.33964E-06 -6.4690 0.86721E+00 -0.0619 32 CaCO3,aq 0.39653E-08 -8.4017 0.39653E-08 -8.4017 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.30254E-09 -9.5192 0.28805E-09 -9.5405 0.95213E+00 -0.0213 34 CaCl+ 0.20955E-09 -9.6787 0.19952E-09 -9.7000 0.95213E+00 -0.0213 35 CaCl2,aq 0.61018E-14 -14.2145 0.61018E-14 -14.2145 0.10000E+01 0.0000 36 CaOH+ 0.21624E-07 -7.6651 0.20589E-07 -7.6864 0.95213E+00 -0.0213 37 CaSO4,aq 0.65638E-08 -8.1828 0.65638E-08 -8.1828 0.10000E+01 0.0000 38 HCl,aq 0.80659E-13 -13.0933 0.80659E-13 -13.0933 0.10000E+01 0.0000 43 FeCl+ 0.49357E-14 -14.3067 0.46994E-14 -14.3280 0.95213E+00 -0.0213 46 FeO,aq 0.85227E-10 -10.0694 0.85227E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.24500E-09 -9.6108 0.23327E-09 -9.6321 0.95213E+00 -0.0213 48 HFeO2- 0.29493E-09 -9.5303 0.28079E-09 -9.5516 0.95206E+00 -0.0213 49 FeO+ 0.28364E-13 -13.5472 0.27006E-13 -13.5685 0.95213E+00 -0.0213 50 FeOH+2 0.18924E-19 -19.7230 0.16406E-19 -19.7850 0.86697E+00 -0.0620 51 FeO2- 0.52307E-09 -9.2814 0.49799E-09 -9.3028 0.95206E+00 -0.0213 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44189E-09 -9.3547 0.44183E-09 -9.3547 0.99986E+00 -0.0001 54 KCl,aq 0.11702E-09 -9.9318 0.11702E-09 -9.9318 0.10000E+01 0.0000 55 KHSO4,aq 0.97140E-17 -17.0126 0.97140E-17 -17.0126 0.10000E+01 0.0000 56 KOH,aq 0.67186E-08 -8.1727 0.67186E-08 -8.1727 0.10000E+01 0.0000 57 KSO4- 0.17993E-07 -7.7449 0.17131E-07 -7.7662 0.95206E+00 -0.0213 58 MgCO3,aq 0.40368E-11 -11.3940 0.40368E-11 -11.3940 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12569E-11 -11.9007 0.11967E-11 -11.9220 0.95213E+00 -0.0213 60 MgCl+ 0.77501E-12 -12.1107 0.73791E-12 -12.1320 0.95213E+00 -0.0213 61 MgOH+ 0.48806E-09 -9.3115 0.46470E-09 -9.3328 0.95213E+00 -0.0213 63 MnO,aq 0.30355E-09 -9.5178 0.30355E-09 -9.5178 0.10000E+01 0.0000 64 MnOH+ 0.30365E-08 -8.5176 0.28912E-08 -8.5389 0.95213E+00 -0.0213 65 MnO2-2 0.11357E-14 -14.9447 0.98492E-15 -15.0066 0.86721E+00 -0.0619 66 HMnO2- 0.73176E-12 -12.1356 0.69667E-12 -12.1570 0.95206E+00 -0.0213 69 MnCl+ 0.25589E-11 -11.5920 0.24364E-11 -11.6133 0.95213E+00 -0.0213 70 MnSO4,aq 0.19195E-10 -10.7168 0.19195E-10 -10.7168 0.10000E+01 0.0000 71 NaCl,aq 0.19263E-07 -7.7153 0.19263E-07 -7.7153 0.10000E+01 0.0000 72 NaOH,aq 0.60450E-07 -7.2186 0.60450E-07 -7.2186 0.10000E+01 0.0000 74 OH- 0.19300E-03 -3.7144 0.18373E-03 -3.7358 0.95199E+00 -0.0214 79 HPO3-2 0.85142E-19 -19.0699 0.73835E-19 -19.1317 0.86721E+00 -0.0619 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.31807E-08 -8.4975 0.30283E-08 -8.5188 0.95209E+00 -0.0213 84 PO4-3 0.19040E-10 -10.7203 0.14153E-10 -10.8492 0.74333E+00 -0.1288 87 H2P2O7-2 0.82766E-18 -18.0821 0.71775E-18 -18.1440 0.86721E+00 -0.0619 88 HP2O7-3 0.60766E-16 -16.2163 0.45081E-16 -16.3460 0.74188E+00 -0.1297 89 P2O7-4 0.57062E-17 -17.2437 0.34065E-17 -17.4677 0.59699E+00 -0.2240 90 H2S,aq 0.13411E-14 -14.8725 0.13409E-14 -14.8726 0.99986E+00 -0.0001 97 SO3-2 0.15343E-14 -14.8141 0.13313E-14 -14.8757 0.86771E+00 -0.0616 98 HSO3- 0.26717E-15 -15.5732 0.25436E-15 -15.5946 0.95206E+00 -0.0213 99 HSO4- 0.70307E-10 -10.1530 0.66944E-10 -10.1743 0.95217E+00 -0.0213 Charge balance for all species = 0.1074E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3428303E-08 -.3592429E-03 -.3620703E+00 0.0000 2 H2O 0.1000000E+01 0.5550834E+02 0.9999305E+06 0.0000 3 Cl- 0.1379622E-03 0.1379818E-03 0.4891532E+01 4.6046 4 SO4-- 0.2548123E-04 0.2550586E-04 0.2449965E+01 12.3167 5 HCO3- 0.1259585E-04 0.1307072E-04 0.7974839E+00 3.5651 6 HS- 0.1435875E-12 0.1979622E-10 0.6546556E-06 -4.3781 7 Al+++ 0.2828060E-22 0.1120592E-04 0.3023316E+00 2.7803 8 H4SiO4 0.3829605E-03 0.5039909E-03 0.4843794E+02 -3.4168 9 Ca++ 0.1099449E-05 0.1134681E-05 0.4547260E-01 10.9515 10 Mg++ 0.4480001E-08 0.4987145E-08 0.1212391E-03 8.5615 11 Fe++ 0.2649819E-10 0.1378229E-08 0.7696467E-04 6.3335 12 K+ 0.5284434E-04 0.5286917E-04 0.2067148E+01 4.1878 13 Na+ 0.4717567E-03 0.4726528E-03 0.1086544E+02 5.1385 14 Mn++ 0.3535216E-08 0.6897772E-08 0.3789236E-03 8.4587 15 HPO4-- 0.6100467E-07 0.6420443E-07 0.6161852E-02 9.6958 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4110030E-02 -.3592231E-03 -.3750807E-02 0.0000000E+00 2 H2O 0.5550513E+02 0.5550527E+02 -.1455844E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3240511E-04 0.2550445E-04 0.6900659E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6900639E-05 0.1979513E-10 -.6900659E-05 0.0000000E+00 7 Al+++ 0.8119247E-03 0.1120530E-04 0.8007194E-03 0.0000000E+00 8 H4SiO4 0.2592783E-02 0.5039630E-03 0.2088820E-02 0.0000000E+00 9 Ca++ 0.3008566E-03 0.1134618E-05 0.2997220E-03 0.0000000E+00 10 Mg++ 0.1976190E-03 0.4986870E-08 0.1976141E-03 0.0000000E+00 11 Fe++ 0.1775391E-03 0.1378153E-08 0.1775378E-03 0.0000000E+00 12 K+ 0.5286624E-04 0.5286624E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.4726267E-03 0.4726267E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.4317310E-05 0.6897390E-08 0.4310413E-05 0.0000000E+00 15 HPO4-- 0.1473477E-05 0.6420088E-07 0.1409276E-05 0.0000000E+00 Chg. balance for solid moles: -.2791E-18 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.2490000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4698E-06 -6.328 0.2360E-03 -3.627 0.9691E-01 0.7498E-04 clinochlore 0.3952E-04 -4.403 0.2197E-01 -1.658 9.022 0.8356E-02 daphnite 0.2447E-04 -4.611 0.1746E-01 -1.758 7.169 0.5290E-02 chlorite-Mn 0.8621E-06 -6.064 0.6112E-03 -3.214 0.2510 0.1948E-03 hematite 0.2760E-04 -4.559 0.4408E-02 -2.356 1.810 0.8355E-03 kaolinite 0.3814E-04 -4.419 0.9845E-02 -2.007 4.043 0.3788E-02 lawsonite 0.5272E-04 -4.278 0.1657E-01 -1.781 6.804 0.5343E-02 stilbite 0.2446E-03 -3.611 0.1724 -0.763 70.80 0.8041E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1329E-01 0.1329E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.243503 g Volume = 0.104297 cm3 Porosity: 90.5150% V(tot) - V(min): 0.99530E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2490000 g log = -0.6038 Original solution: 1000.0103000 g Original solution / Rock added: 4016.11 (Water/Rock Ratio), log = 3.6038 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.8527E-05 1.0073 0.9036E-05 0.8970E-05 CH4,gas 0.1080E-15 1.0129 0.1151E-15 0.1136E-15 H2,gas 0.5758E-06 1.0006 0.6060E-06 0.6057E-06 H2S,gas 0.3733E-13 0.9959 0.3911E-13 0.3927E-13 S2,gas 0.1483E-33 1.0000 0.1560E-33 0.1560E-33 CO,gas 0.1348E-14 1.0000 0.1418E-14 0.1418E-14 SO3,gas 0.8371E-37 1.0000 0.8806E-37 0.8806E-37 SO2,gas 0.1919E-20 1.0000 0.2019E-20 0.2019E-20 HCl,gas 0.1354E-15 1.0000 0.1424E-15 0.1424E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.18198E-10 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.41 -7.04 -2.348 0.12027E+05 -5.044 3 CH4,gas 4.81 -13.13 -17.94 -4.485 0.30630E+05 -15.939 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.35 -15.41 -7.704 0.26308E+05 -13.408 6 S2,gas -7.03 -42.84 -35.81 -5.509 0.61139E+05 -33.807 7 CO,gas 3.51 -13.34 -16.85 -5.184 0.28768E+05 -14.848 8 SO3,gas 17.43 -21.63 -39.06 -9.764 0.66686E+05 -37.055 9 SO2,gas 1.14 -21.56 -22.69 -6.052 0.38751E+05 -20.695 10 HCl,gas 5.48 -12.37 -17.85 -8.923 0.30472E+05 -15.846 11 acmite 7.74 4.60 -3.13 -0.326 0.53508E+04 15 albite-high 0.75 -2.33 -3.08 -0.237 0.52614E+04 16 albite -0.33 -2.33 -2.00 -0.154 0.34207E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65973E+04 20 analcite 3.37 1.09 -2.29 -0.254 0.39025E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.72 -4.49 -0.250 0.76687E+04 27 phlogopite 27.15 22.40 -4.74 -0.264 0.81009E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.46 -3.44 -1.147 0.58770E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.46 -3.29 -1.096 0.56157E+04 38 carnegieite-low 9.06 4.50 -4.56 -0.652 0.77905E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 1.86 -3.54 -0.208 0.60414E+04 43 celadonite-Fe 3.94 -0.37 -4.30 -0.253 0.73468E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14698E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.09 -3.17 -0.317 0.54055E+04 97 kalsilite 7.62 3.55 -4.07 -0.581 0.69477E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.13 -4.03 -0.403 0.68866E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.28 -0.85 -0.065 0.14524E+04 120 muscovite 2.68 2.28 -0.40 -0.024 0.68480E+03 121 paragonite 4.34 3.23 -1.11 -0.065 0.18916E+04 122 nepheline 8.38 4.50 -3.88 -0.554 0.66184E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40538E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -4.95 -3.99 -1.330 0.68128E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41331E+04 153 sanidine -1.22 -3.28 -2.06 -0.159 0.35202E+04 155 siderite -2.59 -7.07 -4.49 -1.495 0.76598E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 11.99 -1.19 -0.036 0.20356E+04 165 stilpnomelane-Mg 27.60 23.13 -4.47 -0.133 0.76305E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78754E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.68 -3.24 -0.199 0.55404E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.37 -3.11 -0.190 0.53086E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.82 -2.66 -0.163 0.45351E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.50 -2.54 -0.156 0.43416E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.36 -1.05 -0.067 0.17869E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.67 -0.91 -0.059 0.15569E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.07 -2.01 -0.155 0.34302E+04 243 an25ab75 2.71 0.67 -2.04 -0.157 0.34804E+04 244 an30ab70 3.34 1.27 -2.07 -0.159 0.35391E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.2490000 g New total amount of reactant added: 0.2590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1074E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.2590000 Water: Moles liquid = 0.5551E+02 kg liquid = 0.9999E+00 Moles total = 0.5551E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .4515515E-03 Osmotic coef. = 0.9874 True ionic strength = .5682547E-03 Chg. balance for total moles = 0.1074E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.32851E-08 -8.4834 0.31272E-08 -8.5048 0.95192E+00 -0.0214 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13130E-03 -3.8817 0.95169E+00 -0.0215 4 SO4-- 0.25481E-04 -4.5938 0.22065E-04 -4.6563 0.86594E+00 -0.0625 5 HCO3- 0.12582E-04 -4.9002 0.11975E-04 -4.9217 0.95174E+00 -0.0215 6 HS- 0.13738E-12 -12.8621 0.13074E-12 -12.8836 0.95169E+00 -0.0215 7 Al+++ 0.24942E-22 -22.6031 0.18439E-22 -22.7343 0.73928E+00 -0.1312 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.10103E-05 -5.9955 0.87463E-06 -6.0582 0.86568E+00 -0.0626 10 Mg++ 0.41169E-08 -8.3854 0.35633E-08 -8.4482 0.86552E+00 -0.0627 11 Fe++ 0.24350E-10 -10.6135 0.21077E-10 -10.6762 0.86556E+00 -0.0627 12 K+ 0.54966E-04 -4.2599 0.52314E-04 -4.2814 0.95175E+00 -0.0215 13 Na+ 0.48425E-03 -3.3149 0.46085E-03 -3.3364 0.95168E+00 -0.0215 14 Mn++ 0.32492E-08 -8.4882 0.28124E-08 -8.5509 0.86559E+00 -0.0627 15 HPO4-- 0.66592E-07 -7.1766 0.57665E-07 -7.2391 0.86594E+00 -0.0625 16 HSiO3- 0.12555E-03 -3.9012 0.11948E-03 -3.9227 0.95169E+00 -0.0215 17 Ca(HSiO3)+ 0.24601E-08 -8.6091 0.23414E-08 -8.6305 0.95176E+00 -0.0215 18 Mg(HSiO3)+ 0.12473E-10 -10.9040 0.11871E-10 -10.9255 0.95176E+00 -0.0215 19 NaHSiO3,aq 0.87453E-06 -6.0582 0.87453E-06 -6.0582 0.10000E+01 0.0000 20 AlO+ 0.25575E-12 -12.5922 0.24341E-12 -12.6137 0.95176E+00 -0.0215 21 AlOH+2 0.44051E-17 -17.3560 0.38131E-17 -17.4187 0.86562E+00 -0.0627 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.11687E-04 -4.9323 0.11122E-04 -4.9538 0.95162E+00 -0.0215 24 CH4,aq 0.69634E-19 -19.1572 0.69624E-19 -19.1572 0.99986E+00 -0.0001 29 CO,aq 0.85918E-18 -18.0659 0.85918E-18 -18.0659 0.10000E+01 0.0000 30 CO2,aq 0.75514E-07 -7.1220 0.75503E-07 -7.1220 0.99986E+00 -0.0001 31 CO3-2 0.40891E-06 -6.3884 0.35406E-06 -6.4509 0.86586E+00 -0.0626 32 CaCO3,aq 0.37927E-08 -8.4211 0.37927E-08 -8.4211 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.27728E-09 -9.5571 0.26391E-09 -9.5785 0.95176E+00 -0.0215 34 CaCl+ 0.19226E-09 -9.7161 0.18299E-09 -9.7376 0.95176E+00 -0.0215 35 CaCl2,aq 0.55941E-14 -14.2523 0.55941E-14 -14.2523 0.10000E+01 0.0000 36 CaOH+ 0.20721E-07 -7.6836 0.19721E-07 -7.7051 0.95176E+00 -0.0215 37 CaSO4,aq 0.60131E-08 -8.2209 0.60131E-08 -8.2209 0.10000E+01 0.0000 38 HCl,aq 0.77231E-13 -13.1122 0.77231E-13 -13.1122 0.10000E+01 0.0000 43 FeCl+ 0.45286E-14 -14.3440 0.43101E-14 -14.3655 0.95176E+00 -0.0215 46 FeO,aq 0.85227E-10 -10.0694 0.85227E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.23477E-09 -9.6294 0.22344E-09 -9.6508 0.95176E+00 -0.0215 48 HFeO2- 0.30802E-09 -9.5114 0.29314E-09 -9.5329 0.95169E+00 -0.0215 49 FeO+ 0.27180E-13 -13.5658 0.25869E-13 -13.5872 0.95176E+00 -0.0215 50 FeOH+2 0.17390E-19 -19.7597 0.15053E-19 -19.8224 0.86562E+00 -0.0627 51 FeO2- 0.54629E-09 -9.2626 0.51990E-09 -9.2841 0.95169E+00 -0.0215 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44189E-09 -9.3547 0.44182E-09 -9.3547 0.99986E+00 -0.0001 54 KCl,aq 0.12162E-09 -9.9150 0.12162E-09 -9.9150 0.10000E+01 0.0000 55 KHSO4,aq 0.96597E-17 -17.0150 0.96597E-17 -17.0150 0.10000E+01 0.0000 56 KOH,aq 0.72929E-08 -8.1371 0.72929E-08 -8.1371 0.10000E+01 0.0000 57 KSO4- 0.18687E-07 -7.7285 0.17784E-07 -7.7500 0.95169E+00 -0.0215 58 MgCO3,aq 0.38610E-11 -11.4133 0.38610E-11 -11.4133 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11519E-11 -11.9386 0.10964E-11 -11.9600 0.95176E+00 -0.0215 60 MgCl+ 0.71109E-12 -12.1481 0.67678E-12 -12.1695 0.95176E+00 -0.0215 61 MgOH+ 0.46768E-09 -9.3301 0.44512E-09 -9.3515 0.95176E+00 -0.0215 63 MnO,aq 0.30359E-09 -9.5177 0.30359E-09 -9.5177 0.10000E+01 0.0000 64 MnOH+ 0.29102E-08 -8.5361 0.27698E-08 -8.5576 0.95176E+00 -0.0215 65 MnO2-2 0.12399E-14 -14.9066 0.10736E-14 -14.9691 0.86586E+00 -0.0626 66 HMnO2- 0.76435E-12 -12.1167 0.72742E-12 -12.1382 0.95169E+00 -0.0215 69 MnCl+ 0.23482E-11 -11.6293 0.22349E-11 -11.6507 0.95176E+00 -0.0215 70 MnSO4,aq 0.17587E-10 -10.7548 0.17587E-10 -10.7548 0.10000E+01 0.0000 71 NaCl,aq 0.19757E-07 -7.7043 0.19757E-07 -7.7043 0.10000E+01 0.0000 72 NaOH,aq 0.64755E-07 -7.1887 0.64755E-07 -7.1887 0.10000E+01 0.0000 74 OH- 0.20157E-03 -3.6956 0.19181E-03 -3.7171 0.95162E+00 -0.0215 79 HPO3-2 0.92939E-19 -19.0318 0.80472E-19 -19.0944 0.86586E+00 -0.0626 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.33219E-08 -8.4786 0.31615E-08 -8.5001 0.95172E+00 -0.0215 84 PO4-3 0.21739E-10 -10.6628 0.16104E-10 -10.7931 0.74078E+00 -0.1303 87 H2P2O7-2 0.90346E-18 -18.0441 0.78228E-18 -18.1066 0.86586E+00 -0.0626 88 HP2O7-3 0.69383E-16 -16.1587 0.51295E-16 -16.2899 0.73929E+00 -0.1312 89 P2O7-4 0.68203E-17 -17.1662 0.40465E-17 -17.3929 0.59331E+00 -0.2267 90 H2S,aq 0.12286E-14 -14.9106 0.12284E-14 -14.9107 0.99986E+00 -0.0001 97 SO3-2 0.15343E-14 -14.8141 0.13293E-14 -14.8764 0.86638E+00 -0.0623 98 HSO3- 0.25562E-15 -15.5924 0.24327E-15 -15.6139 0.95169E+00 -0.0215 99 HSO4- 0.67267E-10 -10.1722 0.64024E-10 -10.1937 0.95180E+00 -0.0215 Charge balance for all species = 0.1074E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3285137E-08 -.3752154E-03 -.3781681E+00 0.0000 2 H2O 0.1000000E+01 0.5550835E+02 0.9999296E+06 0.0000 3 Cl- 0.1379620E-03 0.1379821E-03 0.4891537E+01 4.6231 4 SO4-- 0.2548115E-04 0.2550591E-04 0.2449968E+01 12.3534 5 HCO3- 0.1258225E-04 0.1307075E-04 0.7974847E+00 3.5831 6 HS- 0.1373752E-12 0.1688735E-10 0.5584594E-06 -4.3788 7 Al+++ 0.2494183E-22 0.1170265E-04 0.3157330E+00 2.7803 8 H4SiO4 0.3829605E-03 0.5093848E-03 0.4895630E+02 -3.4168 9 Ca++ 0.1010334E-05 0.1043790E-05 0.4183009E-01 10.9515 10 Mg++ 0.4116893E-08 0.4602769E-08 0.1118947E-03 8.5615 11 Fe++ 0.2435040E-10 0.1402157E-08 0.7830079E-04 6.3335 12 K+ 0.5496643E-04 0.5499253E-04 0.2150168E+01 4.2235 13 Na+ 0.4842478E-03 0.4852069E-03 0.1115403E+02 5.1684 14 Mn++ 0.3249169E-08 0.6483628E-08 0.3561727E-03 8.4588 15 HPO4-- 0.6659161E-07 0.6993525E-07 0.6711846E-02 9.7706 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4275615E-02 -.3751939E-03 -.3900422E-02 0.0000000E+00 2 H2O 0.5550500E+02 0.5550517E+02 -.1667869E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3268224E-04 0.2550445E-04 0.7177790E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7177773E-05 0.1688638E-10 -.7177790E-05 0.0000000E+00 7 Al+++ 0.8445321E-03 0.1170198E-04 0.8328301E-03 0.0000000E+00 8 H4SiO4 0.2696911E-02 0.5093556E-03 0.2187555E-02 0.0000000E+00 9 Ca++ 0.3123580E-03 0.1043730E-05 0.3113143E-03 0.0000000E+00 10 Mg++ 0.2055556E-03 0.4602506E-08 0.2055510E-03 0.0000000E+00 11 Fe++ 0.1846692E-03 0.1402077E-08 0.1846678E-03 0.0000000E+00 12 K+ 0.5498938E-04 0.5498938E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.4851791E-03 0.4851791E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.4490696E-05 0.6483257E-08 0.4484213E-05 0.0000000E+00 15 HPO4-- 0.1532652E-05 0.6993125E-07 0.1462721E-05 0.0000000E+00 Chg. balance for solid moles: 0.3740E-18 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.2590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4876E-06 -6.312 0.2449E-03 -3.611 0.9627E-01 0.7783E-04 clinochlore 0.4111E-04 -4.386 0.2285E-01 -1.641 8.982 0.8692E-02 daphnite 0.2545E-04 -4.594 0.1816E-01 -1.741 7.137 0.5502E-02 chlorite-Mn 0.8968E-06 -6.047 0.6358E-03 -3.197 0.2499 0.2026E-03 hematite 0.2871E-04 -4.542 0.4585E-02 -2.339 1.802 0.8691E-03 kaolinite 0.4008E-04 -4.397 0.1035E-01 -1.985 4.067 0.3981E-02 lawsonite 0.5142E-04 -4.289 0.1616E-01 -1.792 6.351 0.5211E-02 stilbite 0.2575E-03 -3.589 0.1814 -0.741 71.31 0.8462E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1330E-01 0.1330E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.254414 g Volume = 0.109159 cm3 Porosity: 90.1088% V(tot) - V(min): 0.99444E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2590000 g log = -0.5867 Original solution: 1000.0103000 g Original solution / Rock added: 3861.04 (Water/Rock Ratio), log = 3.5867 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.8156E-05 1.0073 0.8643E-05 0.8580E-05 CH4,gas 0.1033E-15 1.0129 0.1101E-15 0.1087E-15 H2,gas 0.5758E-06 1.0006 0.6060E-06 0.6057E-06 H2S,gas 0.3420E-13 0.9959 0.3583E-13 0.3597E-13 S2,gas 0.1245E-33 1.0000 0.1309E-33 0.1309E-33 CO,gas 0.1290E-14 1.0000 0.1357E-14 0.1357E-14 SO3,gas 0.7669E-37 1.0000 0.8067E-37 0.8067E-37 SO2,gas 0.1758E-20 1.0000 0.1849E-20 0.1849E-20 HCl,gas 0.1296E-15 1.0000 0.1364E-15 0.1364E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.43 -7.06 -2.354 0.12060E+05 -5.063 3 CH4,gas 4.81 -13.15 -17.96 -4.490 0.30663E+05 -15.958 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.39 -15.45 -7.723 0.26373E+05 -13.446 6 S2,gas -7.03 -42.92 -35.88 -5.520 0.61269E+05 -33.883 7 CO,gas 3.51 -13.36 -16.87 -5.190 0.28801E+05 -14.868 8 SO3,gas 17.43 -21.67 -39.09 -9.773 0.66751E+05 -37.093 9 SO2,gas 1.14 -21.60 -22.73 -6.062 0.38816E+05 -20.733 10 HCl,gas 5.48 -12.39 -17.87 -8.933 0.30505E+05 -15.865 11 acmite 7.74 4.63 -3.10 -0.322 0.52998E+04 15 albite-high 0.75 -2.30 -3.05 -0.235 0.52103E+04 16 albite -0.33 -2.30 -1.97 -0.152 0.33697E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65969E+04 20 analcite 3.37 1.11 -2.26 -0.251 0.38515E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.75 -4.46 -0.248 0.76079E+04 27 phlogopite 27.15 22.44 -4.71 -0.262 0.80401E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.48 -3.46 -1.154 0.59100E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.48 -3.31 -1.103 0.56487E+04 38 carnegieite-low 9.06 4.53 -4.53 -0.648 0.77395E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 1.90 -3.50 -0.206 0.59806E+04 43 celadonite-Fe 3.94 -0.33 -4.27 -0.251 0.72859E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14697E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -3.25 -4.98 -0.415 0.84991E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.11 -3.14 -0.314 0.53545E+04 97 kalsilite 7.62 3.59 -4.03 -0.576 0.68869E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.17 -4.00 -0.400 0.68258E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.25 -0.82 -0.063 0.13916E+04 120 muscovite 2.68 2.31 -0.37 -0.021 0.62398E+03 121 paragonite 4.34 3.26 -1.08 -0.063 0.18405E+04 122 nepheline 8.38 4.53 -3.85 -0.549 0.65674E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40537E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -4.97 -4.01 -1.336 0.68457E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41330E+04 153 sanidine -1.22 -3.25 -2.03 -0.156 0.34593E+04 155 siderite -2.59 -7.09 -4.51 -1.502 0.76929E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.00 -1.17 -0.035 0.20052E+04 165 stilpnomelane-Mg 27.60 23.15 -4.45 -0.133 0.76001E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78752E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.67 -3.23 -0.198 0.55203E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.36 -3.10 -0.190 0.52918E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.81 -2.64 -0.162 0.45151E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.49 -2.53 -0.155 0.43247E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.37 -1.03 -0.066 0.17669E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.68 -0.90 -0.058 0.15401E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.09 -1.99 -0.153 0.33894E+04 243 an25ab75 2.71 0.69 -2.02 -0.155 0.34422E+04 244 an30ab70 3.34 1.29 -2.05 -0.158 0.35034E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.2590000 g New total amount of reactant added: 0.2690000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1074E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.2690000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .4609788E-03 Osmotic coef. = 0.9873 True ionic strength = .5826500E-03 Chg. balance for total moles = 0.1074E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.31534E-08 -8.5012 0.30007E-08 -8.5228 0.95156E+00 -0.0216 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13125E-03 -3.8819 0.95132E+00 -0.0217 4 SO4-- 0.25481E-04 -4.5938 0.22031E-04 -4.6570 0.86462E+00 -0.0632 5 HCO3- 0.12568E-04 -4.9007 0.11957E-04 -4.9224 0.95138E+00 -0.0216 6 HS- 0.13166E-12 -12.8805 0.12525E-12 -12.9022 0.95132E+00 -0.0217 7 Al+++ 0.22112E-22 -22.6554 0.16291E-22 -22.7881 0.73673E+00 -0.1327 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.93168E-06 -6.0307 0.80530E-06 -6.0940 0.86435E+00 -0.0633 10 Mg++ 0.37964E-08 -8.4206 0.32808E-08 -8.4840 0.86419E+00 -0.0634 11 Fe++ 0.22455E-10 -10.6487 0.19406E-10 -10.7121 0.86423E+00 -0.0634 12 K+ 0.57089E-04 -4.2435 0.54313E-04 -4.2651 0.95139E+00 -0.0216 13 Na+ 0.49674E-03 -3.3039 0.47255E-03 -3.3255 0.95131E+00 -0.0217 14 Mn++ 0.29966E-08 -8.5234 0.25899E-08 -8.5867 0.86426E+00 -0.0634 15 HPO4-- 0.72435E-07 -7.1401 0.62629E-07 -7.2032 0.86462E+00 -0.0632 16 HSiO3- 0.13089E-03 -3.8831 0.12452E-03 -3.9048 0.95132E+00 -0.0217 17 Ca(HSiO3)+ 0.23615E-08 -8.6268 0.22467E-08 -8.6485 0.95140E+00 -0.0216 18 Mg(HSiO3)+ 0.11973E-10 -10.9218 0.11391E-10 -10.9434 0.95140E+00 -0.0216 19 NaHSiO3,aq 0.93455E-06 -6.0294 0.93455E-06 -6.0294 0.10000E+01 0.0000 20 AlO+ 0.24550E-12 -12.6100 0.23357E-12 -12.6316 0.95140E+00 -0.0216 21 AlOH+2 0.40621E-17 -17.3912 0.35109E-17 -17.4546 0.86429E+00 -0.0633 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.12184E-04 -4.9142 0.11590E-04 -4.9359 0.95125E+00 -0.0217 24 CH4,aq 0.66716E-19 -19.1758 0.66707E-19 -19.1758 0.99986E+00 -0.0001 29 CO,aq 0.82319E-18 -18.0845 0.82319E-18 -18.0845 0.10000E+01 0.0000 30 CO2,aq 0.72352E-07 -7.1406 0.72341E-07 -7.1406 0.99986E+00 -0.0001 31 CO3-2 0.42616E-06 -6.3704 0.36844E-06 -6.4336 0.86454E+00 -0.0632 32 CaCO3,aq 0.36339E-08 -8.4396 0.36339E-08 -8.4396 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.25502E-09 -9.5934 0.24263E-09 -9.6151 0.95140E+00 -0.0216 34 CaCl+ 0.17702E-09 -9.7520 0.16842E-09 -9.7736 0.95140E+00 -0.0216 35 CaCl2,aq 0.51467E-14 -14.2885 0.51467E-14 -14.2885 0.10000E+01 0.0000 36 CaOH+ 0.19890E-07 -7.7014 0.18924E-07 -7.7230 0.95140E+00 -0.0216 37 CaSO4,aq 0.55280E-08 -8.2574 0.55280E-08 -8.2574 0.10000E+01 0.0000 38 HCl,aq 0.74078E-13 -13.1303 0.74078E-13 -13.1303 0.10000E+01 0.0000 43 FeCl+ 0.41696E-14 -14.3799 0.39669E-14 -14.4015 0.95140E+00 -0.0216 46 FeO,aq 0.85227E-10 -10.0694 0.85227E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.22536E-09 -9.6471 0.21440E-09 -9.6688 0.95140E+00 -0.0216 48 HFeO2- 0.32113E-09 -9.4933 0.30550E-09 -9.5150 0.95132E+00 -0.0217 49 FeO+ 0.26090E-13 -13.5835 0.24822E-13 -13.6052 0.95140E+00 -0.0216 50 FeOH+2 0.16036E-19 -19.7949 0.13860E-19 -19.8582 0.86429E+00 -0.0633 51 FeO2- 0.56954E-09 -9.2445 0.54181E-09 -9.2662 0.95132E+00 -0.0217 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44189E-09 -9.3547 0.44182E-09 -9.3548 0.99986E+00 -0.0001 54 KCl,aq 0.12622E-09 -9.8989 0.12622E-09 -9.8989 0.10000E+01 0.0000 55 KHSO4,aq 0.96084E-17 -17.0174 0.96084E-17 -17.0174 0.10000E+01 0.0000 56 KOH,aq 0.78908E-08 -8.1029 0.78908E-08 -8.1029 0.10000E+01 0.0000 57 KSO4- 0.19379E-07 -7.7127 0.18435E-07 -7.7344 0.95132E+00 -0.0217 58 MgCO3,aq 0.36993E-11 -11.4319 0.36993E-11 -11.4319 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10595E-11 -11.9749 0.10080E-11 -11.9966 0.95140E+00 -0.0216 60 MgCl+ 0.65472E-12 -12.1839 0.62290E-12 -12.2056 0.95140E+00 -0.0216 61 MgOH+ 0.44893E-09 -9.3478 0.42711E-09 -9.3695 0.95140E+00 -0.0216 63 MnO,aq 0.30363E-09 -9.5177 0.30363E-09 -9.5177 0.10000E+01 0.0000 64 MnOH+ 0.27939E-08 -8.5538 0.26581E-08 -8.5754 0.95140E+00 -0.0216 65 MnO2-2 0.13489E-14 -14.8700 0.11662E-14 -14.9332 0.86454E+00 -0.0632 66 HMnO2- 0.79699E-12 -12.0985 0.75819E-12 -12.1202 0.95132E+00 -0.0217 69 MnCl+ 0.21623E-11 -11.6651 0.20572E-11 -11.6867 0.95140E+00 -0.0216 70 MnSO4,aq 0.16170E-10 -10.7913 0.16170E-10 -10.7913 0.10000E+01 0.0000 71 NaCl,aq 0.20251E-07 -7.6935 0.20251E-07 -7.6935 0.10000E+01 0.0000 72 NaOH,aq 0.69198E-07 -7.1599 0.69198E-07 -7.1599 0.10000E+01 0.0000 74 OH- 0.21014E-03 -3.6775 0.19990E-03 -3.6992 0.95125E+00 -0.0217 79 HPO3-2 0.10109E-18 -18.9953 0.87400E-19 -19.0585 0.86454E+00 -0.0632 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.34633E-08 -8.4605 0.32948E-08 -8.4822 0.95136E+00 -0.0217 84 PO4-3 0.24690E-10 -10.6075 0.18227E-10 -10.7393 0.73826E+00 -0.1318 87 H2P2O7-2 0.98275E-18 -18.0076 0.84962E-18 -18.0708 0.86454E+00 -0.0632 88 HP2O7-3 0.78805E-16 -16.1034 0.58059E-16 -16.2361 0.73675E+00 -0.1327 89 P2O7-4 0.80944E-17 -17.0918 0.47733E-17 -17.3212 0.58970E+00 -0.2294 90 H2S,aq 0.11294E-14 -14.9471 0.11293E-14 -14.9472 0.99986E+00 -0.0001 97 SO3-2 0.15342E-14 -14.8141 0.13272E-14 -14.8771 0.86507E+00 -0.0629 98 HSO3- 0.24499E-15 -15.6108 0.23307E-15 -15.6325 0.95132E+00 -0.0217 99 HSO4- 0.64471E-10 -10.1906 0.61340E-10 -10.2123 0.95143E+00 -0.0216 Charge balance for all species = 0.1075E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3153449E-08 -.3912108E-03 -.3942891E+00 0.0000 2 H2O 0.1000000E+01 0.5550835E+02 0.9999287E+06 0.0000 3 Cl- 0.1379618E-03 0.1379824E-03 0.4891541E+01 4.6409 4 SO4-- 0.2548099E-04 0.2550597E-04 0.2449970E+01 12.3886 5 HCO3- 0.1256836E-04 0.1307077E-04 0.7974855E+00 3.6004 6 HS- 0.1316637E-12 0.1397525E-10 0.4621567E-06 -4.3794 7 Al+++ 0.2211211E-22 0.1220005E-04 0.3291522E+00 2.7803 8 H4SiO4 0.3829605E-03 0.5147877E-03 0.4947552E+02 -3.4168 9 Ca++ 0.9316800E-06 0.9635257E-06 0.3861345E-01 10.9515 10 Mg++ 0.3796409E-08 0.4262729E-08 0.1036281E-03 8.5615 11 Fe++ 0.2245475E-10 0.1427205E-08 0.7969949E-04 6.3335 12 K+ 0.5708851E-04 0.5711591E-04 0.2233188E+01 4.2577 13 Na+ 0.4967370E-03 0.4977610E-03 0.1144261E+02 5.1972 14 Mn++ 0.2996620E-08 0.6113266E-08 0.3358268E-03 8.4588 15 HPO4-- 0.7243502E-07 0.7592298E-07 0.7286495E-02 9.8423 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4441201E-02 -.3911876E-03 -.4050013E-02 0.0000000E+00 2 H2O 0.5550488E+02 0.5550507E+02 -.1879919E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3295938E-04 0.2550446E-04 0.7454921E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7454907E-05 0.1397442E-10 -.7454921E-05 0.0000000E+00 7 Al+++ 0.8771395E-03 0.1219933E-04 0.8649402E-03 0.0000000E+00 8 H4SiO4 0.2801039E-02 0.5147572E-03 0.2286281E-02 0.0000000E+00 9 Ca++ 0.3238594E-03 0.9634687E-06 0.3228960E-03 0.0000000E+00 10 Mg++ 0.2134921E-03 0.4262477E-08 0.2134878E-03 0.0000000E+00 11 Fe++ 0.1917993E-03 0.1427121E-08 0.1917979E-03 0.0000000E+00 12 K+ 0.5711253E-04 0.5711253E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.4977315E-03 0.4977315E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.4664082E-05 0.6112904E-08 0.4657969E-05 0.0000000E+00 15 HPO4-- 0.1591828E-05 0.7591849E-07 0.1515910E-05 0.0000000E+00 Chg. balance for solid moles: -.1174E-17 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.2690000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5053E-06 -6.296 0.2538E-03 -3.595 0.9567E-01 0.8066E-04 clinochlore 0.4270E-04 -4.370 0.2373E-01 -1.625 8.945 0.9027E-02 daphnite 0.2643E-04 -4.578 0.1886E-01 -1.724 7.108 0.5715E-02 chlorite-Mn 0.9316E-06 -6.031 0.6605E-03 -3.180 0.2489 0.2105E-03 hematite 0.2982E-04 -4.525 0.4762E-02 -2.322 1.795 0.9026E-03 kaolinite 0.4204E-04 -4.376 0.1085E-01 -1.964 4.090 0.4176E-02 lawsonite 0.5011E-04 -4.300 0.1575E-01 -1.803 5.935 0.5078E-02 stilbite 0.2703E-03 -3.568 0.1905 -0.720 71.78 0.8883E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1330E-01 0.1330E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.265324 g Volume = 0.114022 cm3 Porosity: 89.7055% V(tot) - V(min): 0.99358E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2690000 g log = -0.5702 Original solution: 1000.0103000 g Original solution / Rock added: 3717.51 (Water/Rock Ratio), log = 3.5703 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.7815E-05 1.0073 0.8281E-05 0.8221E-05 CH4,gas 0.9900E-16 1.0129 0.1055E-15 0.1041E-15 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6057E-06 H2S,gas 0.3144E-13 0.9959 0.3294E-13 0.3307E-13 S2,gas 0.1052E-33 1.0000 0.1106E-33 0.1106E-33 CO,gas 0.1236E-14 1.0000 0.1300E-14 0.1300E-14 SO3,gas 0.7050E-37 1.0000 0.7416E-37 0.7416E-37 SO2,gas 0.1616E-20 1.0000 0.1700E-20 0.1700E-20 HCl,gas 0.1243E-15 1.0000 0.1308E-15 0.1308E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.45 -7.08 -2.361 0.12092E+05 -5.082 3 CH4,gas 4.81 -13.17 -17.98 -4.494 0.30695E+05 -15.977 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.42 -15.48 -7.741 0.26436E+05 -13.482 6 S2,gas -7.03 -42.99 -35.96 -5.532 0.61394E+05 -33.956 7 CO,gas 3.51 -13.38 -16.89 -5.196 0.28833E+05 -14.886 8 SO3,gas 17.43 -21.70 -39.13 -9.782 0.66813E+05 -37.130 9 SO2,gas 1.14 -21.63 -22.77 -6.072 0.38878E+05 -20.770 10 HCl,gas 5.48 -12.40 -17.88 -8.942 0.30535E+05 -15.883 11 acmite 7.74 4.66 -3.08 -0.319 0.52506E+04 15 albite-high 0.75 -2.27 -3.02 -0.233 0.51611E+04 16 albite -0.33 -2.27 -1.94 -0.150 0.33205E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65966E+04 20 analcite 3.37 1.14 -2.23 -0.247 0.38022E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.79 -4.42 -0.246 0.75495E+04 27 phlogopite 27.15 22.47 -4.67 -0.260 0.79817E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.49 -3.48 -1.160 0.59418E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.49 -3.33 -1.109 0.56804E+04 38 carnegieite-low 9.06 4.56 -4.50 -0.643 0.76903E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 1.93 -3.47 -0.204 0.59222E+04 43 celadonite-Fe 3.94 -0.30 -4.23 -0.249 0.72275E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14696E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -3.21 -4.94 -0.412 0.84406E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.14 -3.11 -0.311 0.53053E+04 97 kalsilite 7.62 3.62 -4.00 -0.571 0.68284E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.20 -3.96 -0.396 0.67673E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.21 -0.78 -0.060 0.13332E+04 120 muscovite 2.68 2.35 -0.33 -0.019 0.56556E+03 121 paragonite 4.34 3.29 -1.05 -0.062 0.17913E+04 122 nepheline 8.38 4.56 -3.82 -0.545 0.65182E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40536E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -4.99 -4.03 -1.343 0.68773E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41329E+04 153 sanidine -1.22 -3.21 -1.99 -0.153 0.34009E+04 155 siderite -2.59 -7.11 -4.52 -1.508 0.77246E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.02 -1.16 -0.035 0.19760E+04 165 stilpnomelane-Mg 27.60 23.16 -4.43 -0.132 0.75708E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78750E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.66 -3.22 -0.197 0.55010E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.35 -3.09 -0.189 0.52755E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.79 -2.63 -0.161 0.44958E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.48 -2.52 -0.155 0.43085E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.38 -1.02 -0.066 0.17476E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.69 -0.89 -0.057 0.15238E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.12 -1.96 -0.151 0.33500E+04 243 an25ab75 2.71 0.71 -1.99 -0.153 0.34053E+04 244 an30ab70 3.34 1.31 -2.03 -0.156 0.34689E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.2690000 g New total amount of reactant added: 0.2790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1074E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.2790000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .4704274E-03 Osmotic coef. = 0.9872 True ionic strength = .5970705E-03 Chg. balance for total moles = 0.1074E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.30319E-08 -8.5183 0.28840E-08 -8.5400 0.95120E+00 -0.0217 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13120E-03 -3.8821 0.95096E+00 -0.0218 4 SO4-- 0.25481E-04 -4.5938 0.21998E-04 -4.6576 0.86331E+00 -0.0638 5 HCO3- 0.12554E-04 -4.9012 0.11939E-04 -4.9230 0.95102E+00 -0.0218 6 HS- 0.12640E-12 -12.8983 0.12020E-12 -12.9201 0.95096E+00 -0.0218 7 Al+++ 0.19698E-22 -22.7056 0.14463E-22 -22.8397 0.73422E+00 -0.1342 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.86192E-06 -6.0645 0.74388E-06 -6.1285 0.86304E+00 -0.0640 10 Mg++ 0.35122E-08 -8.4544 0.30306E-08 -8.5185 0.86287E+00 -0.0641 11 Fe++ 0.20774E-10 -10.6825 0.17926E-10 -10.7465 0.86291E+00 -0.0640 12 K+ 0.59211E-04 -4.2276 0.56311E-04 -4.2494 0.95103E+00 -0.0218 13 Na+ 0.50922E-03 -3.2931 0.48425E-03 -3.3149 0.95095E+00 -0.0218 14 Mn++ 0.27726E-08 -8.5571 0.23926E-08 -8.6211 0.86295E+00 -0.0640 15 HPO4-- 0.78535E-07 -7.1049 0.67800E-07 -7.1688 0.86332E+00 -0.0638 16 HSiO3- 0.13624E-03 -3.8657 0.12956E-03 -3.8875 0.95096E+00 -0.0218 17 Ca(HSiO3)+ 0.22705E-08 -8.6439 0.21593E-08 -8.6657 0.95103E+00 -0.0218 18 Mg(HSiO3)+ 0.11512E-10 -10.9389 0.10948E-10 -10.9607 0.95103E+00 -0.0218 19 NaHSiO3,aq 0.99643E-06 -6.0016 0.99643E-06 -6.0016 0.10000E+01 0.0000 20 AlO+ 0.23604E-12 -12.6270 0.22448E-12 -12.6488 0.95103E+00 -0.0218 21 AlOH+2 0.37580E-17 -17.4250 0.32431E-17 -17.4890 0.86298E+00 -0.0640 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.12682E-04 -4.8968 0.12059E-04 -4.9187 0.95088E+00 -0.0219 24 CH4,aq 0.64024E-19 -19.1937 0.64015E-19 -19.1937 0.99985E+00 -0.0001 29 CO,aq 0.78998E-18 -18.1024 0.78998E-18 -18.1024 0.10000E+01 0.0000 30 CO2,aq 0.69433E-07 -7.1584 0.69423E-07 -7.1585 0.99985E+00 -0.0001 31 CO3-2 0.44341E-06 -6.3532 0.38277E-06 -6.4171 0.86323E+00 -0.0639 32 CaCO3,aq 0.34873E-08 -8.4575 0.34873E-08 -8.4575 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.23531E-09 -9.6284 0.22378E-09 -9.6502 0.95103E+00 -0.0218 34 CaCl+ 0.16352E-09 -9.7864 0.15551E-09 -9.8082 0.95103E+00 -0.0218 35 CaCl2,aq 0.47505E-14 -14.3233 0.47505E-14 -14.3233 0.10000E+01 0.0000 36 CaOH+ 0.19124E-07 -7.7184 0.18188E-07 -7.7402 0.95103E+00 -0.0218 37 CaSO4,aq 0.50985E-08 -8.2926 0.50985E-08 -8.2926 0.10000E+01 0.0000 38 HCl,aq 0.71169E-13 -13.1477 0.71169E-13 -13.1477 0.10000E+01 0.0000 43 FeCl+ 0.38515E-14 -14.4144 0.36629E-14 -14.4362 0.95103E+00 -0.0218 46 FeO,aq 0.85227E-10 -10.0694 0.85227E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.21667E-09 -9.6642 0.20606E-09 -9.6860 0.95103E+00 -0.0218 48 HFeO2- 0.33425E-09 -9.4759 0.31786E-09 -9.4978 0.95096E+00 -0.0218 49 FeO+ 0.25085E-13 -13.6006 0.23857E-13 -13.6224 0.95103E+00 -0.0218 50 FeOH+2 0.14836E-19 -19.8287 0.12803E-19 -19.8927 0.86298E+00 -0.0640 51 FeO2- 0.59281E-09 -9.2271 0.56374E-09 -9.2489 0.95096E+00 -0.0218 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44188E-09 -9.3547 0.44182E-09 -9.3548 0.99985E+00 -0.0001 54 KCl,aq 0.13081E-09 -9.8834 0.13081E-09 -9.8834 0.10000E+01 0.0000 55 KHSO4,aq 0.95597E-17 -17.0196 0.95597E-17 -17.0196 0.10000E+01 0.0000 56 KOH,aq 0.85120E-08 -8.0700 0.85120E-08 -8.0700 0.10000E+01 0.0000 57 KSO4- 0.20068E-07 -7.6975 0.19084E-07 -7.7193 0.95096E+00 -0.0218 58 MgCO3,aq 0.35501E-11 -11.4498 0.35501E-11 -11.4498 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.97755E-12 -12.0099 0.92969E-12 -12.0317 0.95103E+00 -0.0218 60 MgCl+ 0.60478E-12 -12.2184 0.57516E-12 -12.2402 0.95103E+00 -0.0218 61 MgOH+ 0.43164E-09 -9.3649 0.41050E-09 -9.3867 0.95103E+00 -0.0218 63 MnO,aq 0.30367E-09 -9.5176 0.30367E-09 -9.5176 0.10000E+01 0.0000 64 MnOH+ 0.26865E-08 -8.5708 0.25550E-08 -8.5926 0.95103E+00 -0.0218 65 MnO2-2 0.14627E-14 -14.8348 0.12626E-14 -14.8987 0.86323E+00 -0.0639 66 HMnO2- 0.82965E-12 -12.0811 0.78896E-12 -12.1029 0.95096E+00 -0.0218 69 MnCl+ 0.19976E-11 -11.6995 0.18998E-11 -11.7213 0.95103E+00 -0.0218 70 MnSO4,aq 0.14916E-10 -10.8264 0.14916E-10 -10.8264 0.10000E+01 0.0000 71 NaCl,aq 0.20745E-07 -7.6831 0.20745E-07 -7.6831 0.10000E+01 0.0000 72 NaOH,aq 0.73780E-07 -7.1321 0.73780E-07 -7.1321 0.10000E+01 0.0000 74 OH- 0.21873E-03 -3.6601 0.20799E-03 -3.6820 0.95088E+00 -0.0219 79 HPO3-2 0.10961E-18 -18.9602 0.94616E-19 -19.0240 0.86323E+00 -0.0639 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.36048E-08 -8.4431 0.34281E-08 -8.4649 0.95099E+00 -0.0218 84 PO4-3 0.27904E-10 -10.5543 0.20531E-10 -10.6876 0.73578E+00 -0.1333 87 H2P2O7-2 0.10655E-17 -17.9724 0.91978E-18 -18.0363 0.86323E+00 -0.0639 88 HP2O7-3 0.89068E-16 -16.0503 0.65397E-16 -16.1844 0.73424E+00 -0.1342 89 P2O7-4 0.95439E-17 -17.0203 0.55941E-17 -17.2523 0.58614E+00 -0.2320 90 H2S,aq 0.10417E-14 -14.9823 0.10415E-14 -14.9823 0.99985E+00 -0.0001 97 SO3-2 0.15342E-14 -14.8141 0.13252E-14 -14.8777 0.86377E+00 -0.0636 98 HSO3- 0.23519E-15 -15.6286 0.22366E-15 -15.6504 0.95096E+00 -0.0218 99 HSO4- 0.61893E-10 -10.2084 0.58865E-10 -10.2301 0.95107E+00 -0.0218 Charge balance for all species = 0.1074E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3031934E-08 -.4072256E-03 -.4104295E+00 0.0000 2 H2O 0.1000000E+01 0.5550836E+02 0.9999278E+06 0.0000 3 Cl- 0.1379616E-03 0.1379826E-03 0.4891546E+01 4.6579 4 SO4-- 0.2548079E-04 0.2550602E-04 0.2449973E+01 12.4224 5 HCO3- 0.1255423E-04 0.1307080E-04 0.7974863E+00 3.6170 6 HS- 0.1263962E-12 0.1106048E-10 0.3657660E-06 -4.3801 7 Al+++ 0.1969816E-22 0.1269799E-04 0.3425863E+00 2.7803 8 H4SiO4 0.3829605E-03 0.5201984E-03 0.4999548E+02 -3.4168 9 Ca++ 0.8619227E-06 0.8923019E-06 0.3575910E-01 10.9515 10 Mg++ 0.3512175E-08 0.3960455E-08 0.9627965E-04 8.5615 11 Fe++ 0.2077352E-10 0.1453236E-08 0.8115302E-04 6.3335 12 K+ 0.5921058E-04 0.5923929E-04 0.2316208E+01 4.2906 13 Na+ 0.5092242E-03 0.5103152E-03 0.1173120E+02 5.2251 14 Mn++ 0.2772576E-08 0.5780525E-08 0.3175477E-03 8.4589 15 HPO4-- 0.7853493E-07 0.8216763E-07 0.7885800E-02 9.9112 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4606786E-02 -.4072007E-03 -.4199585E-02 0.0000000E+00 2 H2O 0.5550475E+02 0.5550496E+02 -.2091987E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3323651E-04 0.2550446E-04 0.7732052E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7732041E-05 0.1105981E-10 -.7732052E-05 0.0000000E+00 7 Al+++ 0.9097469E-03 0.1269722E-04 0.8970497E-03 0.0000000E+00 8 H4SiO4 0.2905166E-02 0.5201666E-03 0.2385000E-02 0.0000000E+00 9 Ca++ 0.3353609E-03 0.8922473E-06 0.3344686E-03 0.0000000E+00 10 Mg++ 0.2214286E-03 0.3960212E-08 0.2214246E-03 0.0000000E+00 11 Fe++ 0.1989294E-03 0.1453147E-08 0.1989279E-03 0.0000000E+00 12 K+ 0.5923567E-04 0.5923567E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.5102840E-03 0.5102840E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.4837468E-05 0.5780171E-08 0.4831688E-05 0.0000000E+00 15 HPO4-- 0.1651004E-05 0.8216260E-07 0.1568841E-05 0.0000000E+00 Chg. balance for solid moles: -.2473E-18 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.2790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5229E-06 -6.282 0.2627E-03 -3.581 0.9510E-01 0.8347E-04 clinochlore 0.4428E-04 -4.354 0.2461E-01 -1.609 8.911 0.9363E-02 daphnite 0.2741E-04 -4.562 0.1956E-01 -1.709 7.081 0.5927E-02 chlorite-Mn 0.9663E-06 -6.015 0.6851E-03 -3.164 0.2480 0.2183E-03 hematite 0.3093E-04 -4.510 0.4939E-02 -2.306 1.788 0.9362E-03 kaolinite 0.4401E-04 -4.356 0.1136E-01 -1.945 4.113 0.4371E-02 lawsonite 0.4880E-04 -4.312 0.1533E-01 -1.814 5.551 0.4945E-02 stilbite 0.2831E-03 -3.548 0.1995 -0.700 72.21 0.9304E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1330E-01 0.1330E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.276233 g Volume = 0.118883 cm3 Porosity: 89.3052% V(tot) - V(min): 0.99272E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2790000 g log = -0.5544 Original solution: 1000.0103000 g Original solution / Rock added: 3584.27 (Water/Rock Ratio), log = 3.5544 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.7499E-05 1.0073 0.7947E-05 0.7889E-05 CH4,gas 0.9501E-16 1.0129 0.1012E-15 0.9994E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6057E-06 H2S,gas 0.2900E-13 0.9959 0.3038E-13 0.3050E-13 S2,gas 0.8947E-34 1.0000 0.9412E-34 0.9412E-34 CO,gas 0.1186E-14 1.0000 0.1247E-14 0.1247E-14 SO3,gas 0.6502E-37 1.0000 0.6840E-37 0.6840E-37 SO2,gas 0.1491E-20 1.0000 0.1568E-20 0.1568E-20 HCl,gas 0.1195E-15 1.0000 0.1257E-15 0.1257E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.48529E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.46 -7.10 -2.367 0.12123E+05 -5.100 3 CH4,gas 4.81 -13.19 -17.99 -4.499 0.30725E+05 -15.995 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.46 -15.52 -7.759 0.26496E+05 -13.517 6 S2,gas -7.03 -43.06 -36.03 -5.543 0.61514E+05 -34.026 7 CO,gas 3.51 -13.39 -16.90 -5.201 0.28863E+05 -14.904 8 SO3,gas 17.43 -21.74 -39.16 -9.791 0.66873E+05 -37.165 9 SO2,gas 1.14 -21.67 -22.80 -6.081 0.38938E+05 -20.805 10 HCl,gas 5.48 -12.42 -17.90 -8.950 0.30565E+05 -15.901 11 acmite 7.74 4.69 -3.05 -0.317 0.52030E+04 15 albite-high 0.75 -2.25 -2.99 -0.230 0.51136E+04 16 albite -0.33 -2.25 -1.92 -0.147 0.32729E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65964E+04 20 analcite 3.37 1.17 -2.20 -0.244 0.37547E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.82 -4.39 -0.244 0.74933E+04 27 phlogopite 27.15 22.50 -4.64 -0.258 0.79255E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.51 -3.50 -1.166 0.59723E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.51 -3.34 -1.115 0.57110E+04 38 carnegieite-low 9.06 4.59 -4.48 -0.639 0.76427E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 1.97 -3.44 -0.202 0.58660E+04 43 celadonite-Fe 3.94 -0.26 -4.20 -0.247 0.71713E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14695E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -3.18 -4.91 -0.409 0.83844E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.17 -3.08 -0.308 0.52577E+04 97 kalsilite 7.62 3.65 -3.97 -0.567 0.67722E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.24 -3.93 -0.393 0.67111E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.18 -0.75 -0.058 0.12770E+04 120 muscovite 2.68 2.38 -0.30 -0.018 0.50935E+03 121 paragonite 4.34 3.32 -1.02 -0.060 0.17438E+04 122 nepheline 8.38 4.59 -3.79 -0.541 0.64707E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40535E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.00 -4.05 -1.349 0.69078E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41328E+04 153 sanidine -1.22 -3.18 -1.96 -0.151 0.33447E+04 155 siderite -2.59 -7.13 -4.54 -1.514 0.77551E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.04 -1.14 -0.034 0.19479E+04 165 stilpnomelane-Mg 27.60 23.18 -4.42 -0.132 0.75427E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78748E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.65 -3.21 -0.197 0.54825E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.34 -3.08 -0.189 0.52598E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.78 -2.62 -0.161 0.44772E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.47 -2.51 -0.154 0.42928E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.39 -1.01 -0.065 0.17290E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.70 -0.88 -0.057 0.15081E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.14 -1.94 -0.149 0.33120E+04 243 an25ab75 2.71 0.74 -1.97 -0.152 0.33696E+04 244 an30ab70 3.34 1.33 -2.01 -0.155 0.34356E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.2790000 g New total amount of reactant added: 0.2890000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1074E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.2890000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .4798941E-03 Osmotic coef. = 0.9871 True ionic strength = .6115123E-03 Chg. balance for total moles = 0.1074E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.29195E-08 -8.5347 0.27760E-08 -8.5566 0.95085E+00 -0.0219 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13115E-03 -3.8822 0.95060E+00 -0.0220 4 SO4-- 0.25481E-04 -4.5938 0.21965E-04 -4.6583 0.86202E+00 -0.0645 5 HCO3- 0.12540E-04 -4.9017 0.11921E-04 -4.9237 0.95066E+00 -0.0220 6 HS- 0.12152E-12 -12.9153 0.11552E-12 -12.9373 0.95060E+00 -0.0220 7 Al+++ 0.17626E-22 -22.7538 0.12898E-22 -22.8895 0.73175E+00 -0.1356 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.79978E-06 -6.0970 0.68921E-06 -6.1617 0.86175E+00 -0.0646 10 Mg++ 0.32590E-08 -8.4869 0.28078E-08 -8.5516 0.86158E+00 -0.0647 11 Fe++ 0.19276E-10 -10.7150 0.16608E-10 -10.7797 0.86162E+00 -0.0647 12 K+ 0.61333E-04 -4.2123 0.58307E-04 -4.2343 0.95067E+00 -0.0220 13 Na+ 0.52171E-03 -3.2826 0.49593E-03 -3.3046 0.95059E+00 -0.0220 14 Mn++ 0.25729E-08 -8.5896 0.22170E-08 -8.6542 0.86165E+00 -0.0647 15 HPO4-- 0.84891E-07 -7.0711 0.73179E-07 -7.1356 0.86203E+00 -0.0645 16 HSiO3- 0.14159E-03 -3.8490 0.13460E-03 -3.8710 0.95060E+00 -0.0220 17 Ca(HSiO3)+ 0.21863E-08 -8.6603 0.20784E-08 -8.6823 0.95068E+00 -0.0220 18 Mg(HSiO3)+ 0.11085E-10 -10.9553 0.10538E-10 -10.9772 0.95068E+00 -0.0220 19 NaHSiO3,aq 0.10602E-05 -5.9746 0.10602E-05 -5.9746 0.10000E+01 0.0000 20 AlO+ 0.22728E-12 -12.6434 0.21607E-12 -12.6654 0.95068E+00 -0.0220 21 AlOH+2 0.34870E-17 -17.4575 0.30047E-17 -17.5222 0.86169E+00 -0.0647 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.13181E-04 -4.8801 0.12529E-04 -4.9021 0.95052E+00 -0.0220 24 CH4,aq 0.61532E-19 -19.2109 0.61523E-19 -19.2110 0.99985E+00 -0.0001 29 CO,aq 0.75924E-18 -18.1196 0.75924E-18 -18.1196 0.10000E+01 0.0000 30 CO2,aq 0.66732E-07 -7.1757 0.66722E-07 -7.1757 0.99985E+00 -0.0001 31 CO3-2 0.46065E-06 -6.3366 0.39706E-06 -6.4011 0.86194E+00 -0.0645 32 CaCO3,aq 0.33516E-08 -8.4747 0.33516E-08 -8.4747 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.21776E-09 -9.6620 0.20702E-09 -9.6840 0.95068E+00 -0.0220 34 CaCl+ 0.15150E-09 -9.8196 0.14403E-09 -9.8415 0.95068E+00 -0.0220 35 CaCl2,aq 0.43980E-14 -14.3567 0.43980E-14 -14.3567 0.10000E+01 0.0000 36 CaOH+ 0.18415E-07 -7.7348 0.17507E-07 -7.7568 0.95068E+00 -0.0220 37 CaSO4,aq 0.47167E-08 -8.3264 0.47167E-08 -8.3264 0.10000E+01 0.0000 38 HCl,aq 0.68478E-13 -13.1644 0.68478E-13 -13.1644 0.10000E+01 0.0000 43 FeCl+ 0.35684E-14 -14.4475 0.33924E-14 -14.4695 0.95068E+00 -0.0220 46 FeO,aq 0.85226E-10 -10.0694 0.85226E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.20864E-09 -9.6806 0.19835E-09 -9.7026 0.95068E+00 -0.0220 48 HFeO2- 0.34739E-09 -9.4592 0.33022E-09 -9.4812 0.95060E+00 -0.0220 49 FeO+ 0.24155E-13 -13.6170 0.22963E-13 -13.6390 0.95068E+00 -0.0220 50 FeOH+2 0.13766E-19 -19.8612 0.11862E-19 -19.9258 0.86169E+00 -0.0647 51 FeO2- 0.61611E-09 -9.2103 0.58567E-09 -9.2323 0.95060E+00 -0.0220 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44188E-09 -9.3547 0.44182E-09 -9.3548 0.99985E+00 -0.0001 54 KCl,aq 0.13540E-09 -9.8684 0.13540E-09 -9.8684 0.10000E+01 0.0000 55 KHSO4,aq 0.95136E-17 -17.0217 0.95136E-17 -17.0217 0.10000E+01 0.0000 56 KOH,aq 0.91567E-08 -8.0383 0.91567E-08 -8.0383 0.10000E+01 0.0000 57 KSO4- 0.20756E-07 -7.6828 0.19731E-07 -7.7049 0.95060E+00 -0.0220 58 MgCO3,aq 0.34120E-11 -11.4670 0.34120E-11 -11.4670 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.90467E-12 -12.0435 0.86005E-12 -12.0655 0.95068E+00 -0.0220 60 MgCl+ 0.56033E-12 -12.2516 0.53269E-12 -12.2735 0.95068E+00 -0.0220 61 MgOH+ 0.41563E-09 -9.3813 0.39513E-09 -9.4033 0.95068E+00 -0.0220 63 MnO,aq 0.30370E-09 -9.5176 0.30370E-09 -9.5176 0.10000E+01 0.0000 64 MnOH+ 0.25872E-08 -8.5872 0.24596E-08 -8.6091 0.95068E+00 -0.0220 65 MnO2-2 0.15812E-14 -14.8010 0.13629E-14 -14.8655 0.86194E+00 -0.0645 66 HMnO2- 0.86234E-12 -12.0643 0.81974E-12 -12.0863 0.95060E+00 -0.0220 69 MnCl+ 0.18510E-11 -11.7326 0.17597E-11 -11.7546 0.95068E+00 -0.0220 70 MnSO4,aq 0.13800E-10 -10.8601 0.13800E-10 -10.8601 0.10000E+01 0.0000 71 NaCl,aq 0.21237E-07 -7.6729 0.21237E-07 -7.6729 0.10000E+01 0.0000 72 NaOH,aq 0.78501E-07 -7.1051 0.78501E-07 -7.1051 0.10000E+01 0.0000 74 OH- 0.22733E-03 -3.6433 0.21608E-03 -3.6654 0.95052E+00 -0.0220 79 HPO3-2 0.11848E-18 -18.9264 0.10212E-18 -18.9909 0.86194E+00 -0.0645 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.37464E-08 -8.4264 0.35615E-08 -8.4484 0.95064E+00 -0.0220 84 PO4-3 0.31393E-10 -10.5032 0.23022E-10 -10.6379 0.73334E+00 -0.1347 87 H2P2O7-2 0.11517E-17 -17.9386 0.99274E-18 -18.0032 0.86194E+00 -0.0645 88 HP2O7-3 0.10021E-15 -15.9991 0.73331E-16 -16.1347 0.73176E+00 -0.1356 89 P2O7-4 0.11185E-16 -16.9514 0.65168E-17 -17.1860 0.58265E+00 -0.2346 90 H2S,aq 0.96366E-15 -15.0161 0.96352E-15 -15.0161 0.99985E+00 -0.0001 97 SO3-2 0.15341E-14 -14.8141 0.13232E-14 -14.8784 0.86249E+00 -0.0642 98 HSO3- 0.22613E-15 -15.6456 0.21496E-15 -15.6676 0.95060E+00 -0.0220 99 HSO4- 0.59508E-10 -10.2254 0.56575E-10 -10.2474 0.95072E+00 -0.0219 Charge balance for all species = 0.1075E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2919476E-08 -.4232570E-03 -.4265866E+00 0.0000 2 H2O 0.1000000E+01 0.5550836E+02 0.9999270E+06 0.0000 3 Cl- 0.1379614E-03 0.1379829E-03 0.4891551E+01 4.6743 4 SO4-- 0.2548053E-04 0.2550607E-04 0.2449976E+01 12.4549 5 HCO3- 0.1253987E-04 0.1307082E-04 0.7974871E+00 3.6329 6 HS- 0.1215236E-12 0.8143523E-11 0.2693030E-06 -4.3808 7 Al+++ 0.1762639E-22 0.1319640E-04 0.3560326E+00 2.7803 8 H4SiO4 0.3829605E-03 0.5256158E-03 0.5051610E+02 -3.4168 9 Ca++ 0.7997760E-06 0.8288147E-06 0.3321482E-01 10.9515 10 Mg++ 0.3258951E-08 0.3690540E-08 0.8971787E-04 8.5615 11 Fe++ 0.1927573E-10 0.1480130E-08 0.8265480E-04 6.3335 12 K+ 0.6133264E-04 0.6136268E-04 0.2399229E+01 4.3223 13 Na+ 0.5217095E-03 0.5228694E-03 0.1201979E+02 5.2520 14 Mn++ 0.2572928E-08 0.5480296E-08 0.3010546E-03 8.4589 15 HPO4-- 0.8489138E-07 0.8866922E-07 0.8509763E-02 9.9776 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4772371E-02 -.4232303E-03 -.4349141E-02 0.0000000E+00 2 H2O 0.5550463E+02 0.5550486E+02 -.2304070E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3351365E-04 0.2550446E-04 0.8009183E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8009175E-05 0.8143009E-11 -.8009183E-05 0.0000000E+00 7 Al+++ 0.9423543E-03 0.1319556E-04 0.9291588E-03 0.0000000E+00 8 H4SiO4 0.3009294E-02 0.5255826E-03 0.2483712E-02 0.0000000E+00 9 Ca++ 0.3468623E-03 0.8287624E-06 0.3460335E-03 0.0000000E+00 10 Mg++ 0.2293651E-03 0.3690307E-08 0.2293614E-03 0.0000000E+00 11 Fe++ 0.2060595E-03 0.1480037E-08 0.2060580E-03 0.0000000E+00 12 K+ 0.6135881E-04 0.6135881E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.5228364E-03 0.5228364E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.5010854E-05 0.5479950E-08 0.5005374E-05 0.0000000E+00 15 HPO4-- 0.1710180E-05 0.8866362E-07 0.1621516E-05 0.0000000E+00 Chg. balance for solid moles: 0.8318E-18 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.2890000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5405E-06 -6.267 0.2715E-03 -3.566 0.9456E-01 0.8627E-04 clinochlore 0.4587E-04 -4.338 0.2550E-01 -1.594 8.880 0.9698E-02 daphnite 0.2840E-04 -4.547 0.2026E-01 -1.693 7.056 0.6140E-02 chlorite-Mn 0.1001E-05 -6.000 0.7097E-03 -3.149 0.2472 0.2262E-03 hematite 0.3204E-04 -4.494 0.5116E-02 -2.291 1.782 0.9697E-03 kaolinite 0.4598E-04 -4.337 0.1187E-01 -1.926 4.134 0.4567E-02 lawsonite 0.4747E-04 -4.324 0.1492E-01 -1.826 5.196 0.4811E-02 stilbite 0.2959E-03 -3.529 0.2085 -0.681 72.61 0.9725E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1330E-01 0.1330E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.287140 g Volume = 0.123745 cm3 Porosity: 88.9078% V(tot) - V(min): 0.99186E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2890000 g log = -0.5391 Original solution: 1000.0103000 g Original solution / Rock added: 3460.24 (Water/Rock Ratio), log = 3.5391 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.7208E-05 1.0073 0.7638E-05 0.7582E-05 CH4,gas 0.9131E-16 1.0129 0.9729E-16 0.9605E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.2682E-13 0.9959 0.2810E-13 0.2822E-13 S2,gas 0.7657E-34 1.0000 0.8055E-34 0.8055E-34 CO,gas 0.1140E-14 1.0000 0.1199E-14 0.1199E-14 SO3,gas 0.6016E-37 1.0000 0.6328E-37 0.6328E-37 SO2,gas 0.1379E-20 1.0000 0.1451E-20 0.1451E-20 HCl,gas 0.1149E-15 1.0000 0.1209E-15 0.1209E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.15165E-10 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.48 -7.12 -2.372 0.12152E+05 -5.117 3 CH4,gas 4.81 -13.20 -18.01 -4.503 0.30755E+05 -16.012 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.49 -15.55 -7.776 0.26553E+05 -13.551 6 S2,gas -7.03 -43.13 -36.09 -5.553 0.61629E+05 -34.094 7 CO,gas 3.51 -13.41 -16.92 -5.207 0.28893E+05 -14.921 8 SO3,gas 17.43 -21.77 -39.20 -9.800 0.66931E+05 -37.199 9 SO2,gas 1.14 -21.70 -22.84 -6.090 0.38996E+05 -20.838 10 HCl,gas 5.48 -12.44 -17.92 -8.959 0.30594E+05 -15.918 11 acmite 7.74 4.72 -3.02 -0.314 0.51570E+04 15 albite-high 0.75 -2.22 -2.97 -0.228 0.50676E+04 16 albite -0.33 -2.22 -1.89 -0.145 0.32269E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65962E+04 20 analcite 3.37 1.20 -2.17 -0.241 0.37087E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.85 -4.36 -0.242 0.74391E+04 27 phlogopite 27.15 22.54 -4.61 -0.256 0.78713E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.53 -3.51 -1.172 0.60017E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.53 -3.36 -1.121 0.57404E+04 38 carnegieite-low 9.06 4.62 -4.45 -0.636 0.75967E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.00 -3.40 -0.200 0.58118E+04 43 celadonite-Fe 3.94 -0.23 -4.17 -0.245 0.71172E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14694E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -3.15 -4.88 -0.407 0.83303E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.20 -3.05 -0.305 0.52117E+04 97 kalsilite 7.62 3.69 -3.93 -0.562 0.67181E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.27 -3.90 -0.390 0.66570E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.15 -0.72 -0.055 0.12228E+04 120 muscovite 2.68 2.41 -0.27 -0.016 0.45522E+03 121 paragonite 4.34 3.34 -0.99 -0.058 0.16978E+04 122 nepheline 8.38 4.62 -3.76 -0.538 0.64247E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40535E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.02 -4.06 -1.354 0.69371E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41327E+04 153 sanidine -1.22 -3.15 -1.93 -0.148 0.32906E+04 155 siderite -2.59 -7.15 -4.56 -1.520 0.77845E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.05 -1.12 -0.034 0.19208E+04 165 stilpnomelane-Mg 27.60 23.19 -4.40 -0.131 0.75157E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78747E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.64 -3.20 -0.196 0.54646E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.33 -3.07 -0.188 0.52447E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.77 -2.61 -0.160 0.44594E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.47 -2.51 -0.153 0.42776E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.40 -1.00 -0.064 0.17112E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.71 -0.87 -0.056 0.14930E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.16 -1.92 -0.148 0.32752E+04 243 an25ab75 2.71 0.76 -1.95 -0.150 0.33351E+04 244 an30ab70 3.34 1.35 -1.99 -0.153 0.34034E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.2890000 g New total amount of reactant added: 0.2990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1075E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.2990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .4893766E-03 Osmotic coef. = 0.9869 True ionic strength = .6259722E-03 Chg. balance for total moles = 0.1075E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.28151E-08 -8.5505 0.26758E-08 -8.5726 0.95050E+00 -0.0220 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13110E-03 -3.8824 0.95024E+00 -0.0222 4 SO4-- 0.25480E-04 -4.5938 0.21932E-04 -4.6589 0.86075E+00 -0.0651 5 HCO3- 0.12525E-04 -4.9022 0.11903E-04 -4.9243 0.95031E+00 -0.0221 6 HS- 0.11700E-12 -12.9318 0.11118E-12 -12.9540 0.95025E+00 -0.0222 7 Al+++ 0.15838E-22 -22.8003 0.11551E-22 -22.9374 0.72931E+00 -0.1371 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.74418E-06 -6.1283 0.64034E-06 -6.1936 0.86047E+00 -0.0653 10 Mg++ 0.30324E-08 -8.5182 0.26088E-08 -8.5836 0.86029E+00 -0.0654 11 Fe++ 0.17936E-10 -10.7463 0.15431E-10 -10.8116 0.86034E+00 -0.0653 12 K+ 0.63455E-04 -4.1975 0.60302E-04 -4.2197 0.95032E+00 -0.0221 13 Na+ 0.53419E-03 -3.2723 0.50761E-03 -3.2945 0.95024E+00 -0.0222 14 Mn++ 0.23943E-08 -8.6208 0.20600E-08 -8.6861 0.86037E+00 -0.0653 15 HPO4-- 0.91504E-07 -7.0386 0.78763E-07 -7.1037 0.86076E+00 -0.0651 16 HSiO3- 0.14695E-03 -3.8328 0.13964E-03 -3.8550 0.95024E+00 -0.0222 17 Ca(HSiO3)+ 0.21081E-08 -8.6761 0.20034E-08 -8.6982 0.95033E+00 -0.0221 18 Mg(HSiO3)+ 0.10689E-10 -10.9711 0.10158E-10 -10.9932 0.95033E+00 -0.0221 19 NaHSiO3,aq 0.11258E-05 -5.9485 0.11258E-05 -5.9485 0.10000E+01 0.0000 20 AlO+ 0.21916E-12 -12.6592 0.20827E-12 -12.6814 0.95033E+00 -0.0221 21 AlOH+2 0.32446E-17 -17.4888 0.27917E-17 -17.5541 0.86041E+00 -0.0653 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.13680E-04 -4.8639 0.12998E-04 -4.8861 0.95017E+00 -0.0222 24 CH4,aq 0.59219E-19 -19.2275 0.59210E-19 -19.2276 0.99985E+00 -0.0001 29 CO,aq 0.73071E-18 -18.1363 0.73071E-18 -18.1363 0.10000E+01 0.0000 30 CO2,aq 0.64224E-07 -7.1923 0.64215E-07 -7.1924 0.99985E+00 -0.0001 31 CO3-2 0.47788E-06 -6.3207 0.41130E-06 -6.3858 0.86067E+00 -0.0652 32 CaCO3,aq 0.32257E-08 -8.4914 0.32257E-08 -8.4914 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.20209E-09 -9.6945 0.19205E-09 -9.7166 0.95033E+00 -0.0221 34 CaCl+ 0.14076E-09 -9.8515 0.13377E-09 -9.8736 0.95033E+00 -0.0221 35 CaCl2,aq 0.40832E-14 -14.3890 0.40832E-14 -14.3890 0.10000E+01 0.0000 36 CaOH+ 0.17757E-07 -7.7506 0.16875E-07 -7.7728 0.95033E+00 -0.0221 37 CaSO4,aq 0.43758E-08 -8.3589 0.43758E-08 -8.3589 0.10000E+01 0.0000 38 HCl,aq 0.65982E-13 -13.1806 0.65982E-13 -13.1806 0.10000E+01 0.0000 43 FeCl+ 0.33154E-14 -14.4795 0.31507E-14 -14.5016 0.95033E+00 -0.0221 46 FeO,aq 0.85226E-10 -10.0694 0.85226E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.20118E-09 -9.6964 0.19119E-09 -9.7185 0.95033E+00 -0.0221 48 HFeO2- 0.36053E-09 -9.4431 0.34259E-09 -9.4652 0.95024E+00 -0.0222 49 FeO+ 0.23291E-13 -13.6328 0.22134E-13 -13.6549 0.95033E+00 -0.0221 50 FeOH+2 0.12809E-19 -19.8925 0.11021E-19 -19.9578 0.86041E+00 -0.0653 51 FeO2- 0.63942E-09 -9.1942 0.60761E-09 -9.2164 0.95024E+00 -0.0222 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44188E-09 -9.3547 0.44182E-09 -9.3548 0.99985E+00 -0.0001 54 KCl,aq 0.13998E-09 -9.8539 0.13998E-09 -9.8539 0.10000E+01 0.0000 55 KHSO4,aq 0.94698E-17 -17.0237 0.94698E-17 -17.0237 0.10000E+01 0.0000 56 KOH,aq 0.98247E-08 -8.0077 0.98247E-08 -8.0077 0.10000E+01 0.0000 57 KSO4- 0.21443E-07 -7.6687 0.20376E-07 -7.6909 0.95024E+00 -0.0222 58 MgCO3,aq 0.32838E-11 -11.4836 0.32838E-11 -11.4836 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.83955E-12 -12.0760 0.79785E-12 -12.0981 0.95033E+00 -0.0221 60 MgCl+ 0.52060E-12 -12.2835 0.49474E-12 -12.3056 0.95033E+00 -0.0221 61 MgOH+ 0.40077E-09 -9.3971 0.38086E-09 -9.4192 0.95033E+00 -0.0221 63 MnO,aq 0.30372E-09 -9.5175 0.30372E-09 -9.5175 0.10000E+01 0.0000 64 MnOH+ 0.24949E-08 -8.6029 0.23710E-08 -8.6251 0.95033E+00 -0.0221 65 MnO2-2 0.17046E-14 -14.7684 0.14671E-14 -14.8336 0.86067E+00 -0.0652 66 HMnO2- 0.89504E-12 -12.0482 0.85051E-12 -12.0703 0.95024E+00 -0.0222 69 MnCl+ 0.17199E-11 -11.7645 0.16344E-11 -11.7866 0.95033E+00 -0.0221 70 MnSO4,aq 0.12804E-10 -10.8927 0.12804E-10 -10.8927 0.10000E+01 0.0000 71 NaCl,aq 0.21729E-07 -7.6630 0.21729E-07 -7.6630 0.10000E+01 0.0000 72 NaOH,aq 0.83358E-07 -7.0791 0.83358E-07 -7.0791 0.10000E+01 0.0000 74 OH- 0.23593E-03 -3.6272 0.22417E-03 -3.6494 0.95017E+00 -0.0222 79 HPO3-2 0.12771E-18 -18.8938 0.10991E-18 -18.9589 0.86067E+00 -0.0652 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.38882E-08 -8.4103 0.36949E-08 -8.4324 0.95028E+00 -0.0221 84 PO4-3 0.35169E-10 -10.4538 0.25706E-10 -10.5900 0.73093E+00 -0.1361 87 H2P2O7-2 0.12415E-17 -17.9061 0.10685E-17 -17.9712 0.86067E+00 -0.0652 88 HP2O7-3 0.11227E-15 -15.9497 0.81883E-16 -16.0868 0.72933E+00 -0.1371 89 P2O7-4 0.13034E-16 -16.8849 0.75493E-17 -17.1221 0.57922E+00 -0.2372 90 H2S,aq 0.89399E-15 -15.0487 0.89386E-15 -15.0487 0.99985E+00 -0.0001 97 SO3-2 0.15341E-14 -14.8141 0.13212E-14 -14.8790 0.86123E+00 -0.0649 98 HSO3- 0.21772E-15 -15.6621 0.20689E-15 -15.6843 0.95024E+00 -0.0222 99 HSO4- 0.57296E-10 -10.2419 0.54452E-10 -10.2640 0.95037E+00 -0.0221 Charge balance for all species = 0.1074E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2815111E-08 -.4393025E-03 -.4427579E+00 0.0000 2 H2O 0.1000000E+01 0.5550837E+02 0.9999261E+06 0.0000 3 Cl- 0.1379611E-03 0.1379832E-03 0.4891556E+01 4.6901 4 SO4-- 0.2548024E-04 0.2550612E-04 0.2449978E+01 12.4862 5 HCO3- 0.1252531E-04 0.1307085E-04 0.7974878E+00 3.6482 6 HS- 0.1170040E-12 0.5224750E-11 0.1727802E-06 -4.3814 7 Al+++ 0.1583823E-22 0.1369518E-04 0.3694893E+00 2.7803 8 H4SiO4 0.3829605E-03 0.5310392E-03 0.5103728E+02 -3.4168 9 Ca++ 0.7441763E-06 0.7719853E-06 0.3093734E-01 10.9515 10 Mg++ 0.3032404E-08 0.3448506E-08 0.8383390E-04 8.5615 11 Fe++ 0.1793572E-10 0.1507789E-08 0.8419926E-04 6.3335 12 K+ 0.6345468E-04 0.6348608E-04 0.2482250E+01 4.3529 13 Na+ 0.5341928E-03 0.5354237E-03 0.1230838E+02 5.2781 14 Mn++ 0.2394274E-08 0.5208316E-08 0.2861134E-03 8.4590 15 HPO4-- 0.9150444E-07 0.9542781E-07 0.9158390E-02 10.0414 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4937956E-02 -.4392739E-03 -.4498682E-02 0.0000000E+00 2 H2O 0.5550450E+02 0.5550475E+02 -.2516162E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3379078E-04 0.2550446E-04 0.8286314E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8286309E-05 0.5224410E-11 -.8286314E-05 0.0000000E+00 7 Al+++ 0.9749617E-03 0.1369429E-04 0.9612675E-03 0.0000000E+00 8 H4SiO4 0.3113422E-02 0.5310047E-03 0.2582417E-02 0.0000000E+00 9 Ca++ 0.3583637E-03 0.7719351E-06 0.3575918E-03 0.0000000E+00 10 Mg++ 0.2373016E-03 0.3448282E-08 0.2372981E-03 0.0000000E+00 11 Fe++ 0.2131896E-03 0.1507691E-08 0.2131881E-03 0.0000000E+00 12 K+ 0.6348195E-04 0.6348195E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.5353888E-03 0.5353888E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.5184240E-05 0.5207977E-08 0.5179032E-05 0.0000000E+00 15 HPO4-- 0.1769355E-05 0.9542161E-07 0.1673934E-05 0.0000000E+00 Chg. balance for solid moles: 0.2270E-18 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.2990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5580E-06 -6.253 0.2803E-03 -3.552 0.9404E-01 0.8906E-04 clinochlore 0.4746E-04 -4.324 0.2638E-01 -1.579 8.851 0.1003E-01 daphnite 0.2938E-04 -4.532 0.2096E-01 -1.679 7.033 0.6352E-02 chlorite-Mn 0.1036E-05 -5.985 0.7344E-03 -3.134 0.2464 0.2340E-03 hematite 0.3315E-04 -4.480 0.5293E-02 -2.276 1.776 0.1003E-02 kaolinite 0.4796E-04 -4.319 0.1238E-01 -1.907 4.154 0.4764E-02 lawsonite 0.4615E-04 -4.336 0.1450E-01 -1.839 4.865 0.4676E-02 stilbite 0.3087E-03 -3.511 0.2175 -0.663 72.98 0.1015 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1330E-01 0.1330E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.298047 g Volume = 0.128606 cm3 Porosity: 88.5133% V(tot) - V(min): 0.99099E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.2990000 g log = -0.5243 Original solution: 1000.0103000 g Original solution / Rock added: 3344.52 (Water/Rock Ratio), log = 3.5243 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.6937E-05 1.0073 0.7351E-05 0.7297E-05 CH4,gas 0.8787E-16 1.0129 0.9363E-16 0.9244E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.2488E-13 0.9959 0.2607E-13 0.2618E-13 S2,gas 0.6590E-34 1.0000 0.6932E-34 0.6932E-34 CO,gas 0.1097E-14 1.0000 0.1154E-14 0.1154E-14 SO3,gas 0.5581E-37 1.0000 0.5871E-37 0.5871E-37 SO2,gas 0.1279E-20 1.0000 0.1346E-20 0.1346E-20 HCl,gas 0.1108E-15 1.0000 0.1165E-15 0.1165E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.48529E-10 47 daphnite 29.09 29.09 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.24265E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.37914E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.50 -7.13 -2.378 0.12181E+05 -5.134 3 CH4,gas 4.81 -13.22 -18.03 -4.507 0.30783E+05 -16.029 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.53 -15.58 -7.792 0.26609E+05 -13.584 6 S2,gas -7.03 -43.19 -36.16 -5.563 0.61741E+05 -34.159 7 CO,gas 3.51 -13.43 -16.94 -5.212 0.28921E+05 -14.938 8 SO3,gas 17.43 -21.80 -39.23 -9.808 0.66986E+05 -37.231 9 SO2,gas 1.14 -21.73 -22.87 -6.099 0.39052E+05 -20.871 10 HCl,gas 5.48 -12.45 -17.93 -8.967 0.30621E+05 -15.934 11 acmite 7.74 4.74 -2.99 -0.311 0.51125E+04 15 albite-high 0.75 -2.19 -2.94 -0.226 0.50231E+04 16 albite -0.33 -2.19 -1.86 -0.143 0.31824E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65960E+04 20 analcite 3.37 1.22 -2.15 -0.238 0.36642E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.88 -4.33 -0.240 0.73869E+04 27 phlogopite 27.15 22.57 -4.58 -0.254 0.78191E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.55 -3.53 -1.177 0.60301E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.55 -3.38 -1.126 0.57688E+04 38 carnegieite-low 9.06 4.64 -4.42 -0.632 0.75522E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.03 -3.37 -0.198 0.57596E+04 43 celadonite-Fe 3.94 -0.20 -4.14 -0.243 0.70650E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14694E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -3.12 -4.85 -0.404 0.82781E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.22 -3.03 -0.303 0.51672E+04 97 kalsilite 7.62 3.72 -3.90 -0.558 0.66659E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.30 -3.87 -0.387 0.66048E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.12 -0.69 -0.053 0.11706E+04 120 muscovite 2.68 2.44 -0.24 -0.014 0.40300E+03 121 paragonite 4.34 3.37 -0.97 -0.057 0.16533E+04 122 nepheline 8.38 4.64 -3.74 -0.534 0.63802E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40534E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.04 -4.08 -1.360 0.69655E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41326E+04 153 sanidine -1.22 -3.12 -1.90 -0.146 0.32384E+04 155 siderite -2.59 -7.16 -4.58 -1.525 0.78130E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.07 -1.11 -0.033 0.18947E+04 165 stilpnomelane-Mg 27.60 23.21 -4.39 -0.131 0.74896E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78746E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.63 -3.19 -0.195 0.54474E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.32 -3.06 -0.188 0.52300E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.76 -2.60 -0.159 0.44421E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.46 -2.50 -0.153 0.42629E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.41 -0.99 -0.064 0.16940E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.72 -0.87 -0.056 0.14783E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.18 -1.90 -0.146 0.32396E+04 243 an25ab75 2.71 0.78 -1.93 -0.149 0.33017E+04 244 an30ab70 3.34 1.37 -1.98 -0.152 0.33723E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.2990000 g New total amount of reactant added: 0.3090000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1075E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.3090000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .4988727E-03 Osmotic coef. = 0.9868 True ionic strength = .6404476E-03 Chg. balance for total moles = 0.1075E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.27180E-08 -8.5657 0.25825E-08 -8.5880 0.95016E+00 -0.0222 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13105E-03 -3.8826 0.94989E+00 -0.0223 4 SO4-- 0.25480E-04 -4.5938 0.21900E-04 -4.6596 0.85949E+00 -0.0658 5 HCO3- 0.12511E-04 -4.9027 0.11885E-04 -4.9250 0.94996E+00 -0.0223 6 HS- 0.11280E-12 -12.9477 0.10715E-12 -12.9700 0.94990E+00 -0.0223 7 Al+++ 0.14287E-22 -22.8451 0.10385E-22 -22.9836 0.72691E+00 -0.1385 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.69424E-06 -6.1585 0.59650E-06 -6.2244 0.85921E+00 -0.0659 10 Mg++ 0.28289E-08 -8.5484 0.24301E-08 -8.6144 0.85903E+00 -0.0660 11 Fe++ 0.16732E-10 -10.7764 0.14374E-10 -10.8424 0.85907E+00 -0.0660 12 K+ 0.65577E-04 -4.1833 0.62296E-04 -4.2055 0.94997E+00 -0.0223 13 Na+ 0.54667E-03 -3.2623 0.51928E-03 -3.2846 0.94989E+00 -0.0223 14 Mn++ 0.22338E-08 -8.6510 0.19191E-08 -8.7169 0.85910E+00 -0.0660 15 HPO4-- 0.98374E-07 -7.0071 0.84553E-07 -7.0729 0.85950E+00 -0.0658 16 HSiO3- 0.15231E-03 -3.8173 0.14468E-03 -3.8396 0.94989E+00 -0.0223 17 Ca(HSiO3)+ 0.20354E-08 -8.6913 0.19336E-08 -8.7136 0.94998E+00 -0.0223 18 Mg(HSiO3)+ 0.10320E-10 -10.9863 0.98037E-11 -11.0086 0.94998E+00 -0.0223 19 NaHSiO3,aq 0.11932E-05 -5.9233 0.11932E-05 -5.9233 0.10000E+01 0.0000 20 AlO+ 0.21160E-12 -12.6745 0.20102E-12 -12.6968 0.94998E+00 -0.0223 21 AlOH+2 0.30269E-17 -17.5190 0.26005E-17 -17.5849 0.85914E+00 -0.0659 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.14179E-04 -4.8484 0.13467E-04 -4.8707 0.94981E+00 -0.0224 24 CH4,aq 0.57067E-19 -19.2436 0.57058E-19 -19.2437 0.99985E+00 -0.0001 29 CO,aq 0.70416E-18 -18.1523 0.70416E-18 -18.1523 0.10000E+01 0.0000 30 CO2,aq 0.61891E-07 -7.2084 0.61882E-07 -7.2084 0.99985E+00 -0.0001 31 CO3-2 0.49509E-06 -6.3053 0.42549E-06 -6.3711 0.85941E+00 -0.0658 32 CaCO3,aq 0.31085E-08 -8.5075 0.31085E-08 -8.5075 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.18803E-09 -9.7258 0.17862E-09 -9.7481 0.94998E+00 -0.0223 34 CaCl+ 0.13112E-09 -9.8823 0.12456E-09 -9.9046 0.94998E+00 -0.0223 35 CaCl2,aq 0.38008E-14 -14.4201 0.38008E-14 -14.4201 0.10000E+01 0.0000 36 CaOH+ 0.17144E-07 -7.7659 0.16287E-07 -7.7882 0.94998E+00 -0.0223 37 CaSO4,aq 0.40702E-08 -8.3904 0.40702E-08 -8.3904 0.10000E+01 0.0000 38 HCl,aq 0.63659E-13 -13.1961 0.63659E-13 -13.1961 0.10000E+01 0.0000 43 FeCl+ 0.30884E-14 -14.5103 0.29339E-14 -14.5326 0.94998E+00 -0.0223 46 FeO,aq 0.85226E-10 -10.0694 0.85226E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.19424E-09 -9.7117 0.18452E-09 -9.7339 0.94998E+00 -0.0223 48 HFeO2- 0.37368E-09 -9.4275 0.35496E-09 -9.4498 0.94989E+00 -0.0223 49 FeO+ 0.22488E-13 -13.6480 0.21363E-13 -13.6703 0.94998E+00 -0.0223 50 FeOH+2 0.11949E-19 -19.9227 0.10266E-19 -19.9886 0.85914E+00 -0.0659 51 FeO2- 0.66275E-09 -9.1787 0.62954E-09 -9.2010 0.94989E+00 -0.0223 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44188E-09 -9.3547 0.44181E-09 -9.3548 0.99985E+00 -0.0001 54 KCl,aq 0.14455E-09 -9.8400 0.14455E-09 -9.8400 0.10000E+01 0.0000 55 KHSO4,aq 0.94282E-17 -17.0256 0.94282E-17 -17.0256 0.10000E+01 0.0000 56 KOH,aq 0.10516E-07 -7.9782 0.10516E-07 -7.9782 0.10000E+01 0.0000 57 KSO4- 0.22127E-07 -7.6551 0.21018E-07 -7.6774 0.94989E+00 -0.0223 58 MgCO3,aq 0.31644E-11 -11.4997 0.31644E-11 -11.4997 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.78115E-12 -12.1073 0.74207E-12 -12.1296 0.94998E+00 -0.0223 60 MgCl+ 0.48495E-12 -12.3143 0.46069E-12 -12.3366 0.94998E+00 -0.0223 61 MgOH+ 0.38695E-09 -9.4123 0.36759E-09 -9.4346 0.94998E+00 -0.0223 63 MnO,aq 0.30375E-09 -9.5175 0.30375E-09 -9.5175 0.10000E+01 0.0000 64 MnOH+ 0.24090E-08 -8.6182 0.22885E-08 -8.6404 0.94998E+00 -0.0223 65 MnO2-2 0.18327E-14 -14.7369 0.15750E-14 -14.8027 0.85941E+00 -0.0658 66 HMnO2- 0.92777E-12 -12.0326 0.88128E-12 -12.0549 0.94989E+00 -0.0223 69 MnCl+ 0.16022E-11 -11.7953 0.15221E-11 -11.8176 0.94998E+00 -0.0223 70 MnSO4,aq 0.11910E-10 -10.9241 0.11910E-10 -10.9241 0.10000E+01 0.0000 71 NaCl,aq 0.22220E-07 -7.6533 0.22220E-07 -7.6533 0.10000E+01 0.0000 72 NaOH,aq 0.88353E-07 -7.0538 0.88353E-07 -7.0538 0.10000E+01 0.0000 74 OH- 0.24454E-03 -3.6117 0.23227E-03 -3.6340 0.94981E+00 -0.0224 79 HPO3-2 0.13729E-18 -18.8623 0.11799E-18 -18.9281 0.85941E+00 -0.0658 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.40301E-08 -8.3947 0.38283E-08 -8.4170 0.94993E+00 -0.0223 84 PO4-3 0.39245E-10 -10.4062 0.28592E-10 -10.5438 0.72856E+00 -0.1375 87 H2P2O7-2 0.13347E-17 -17.8746 0.11470E-17 -17.9404 0.85941E+00 -0.0658 88 HP2O7-3 0.12529E-15 -15.9021 0.91075E-16 -16.0406 0.72692E+00 -0.1385 89 P2O7-4 0.15108E-16 -16.8208 0.87000E-17 -17.0605 0.57585E+00 -0.2397 90 H2S,aq 0.83154E-15 -15.0801 0.83142E-15 -15.0802 0.99985E+00 -0.0001 97 SO3-2 0.15341E-14 -14.8142 0.13193E-14 -14.8797 0.85999E+00 -0.0655 98 HSO3- 0.20990E-15 -15.6780 0.19939E-15 -15.7003 0.94989E+00 -0.0223 99 HSO4- 0.55238E-10 -10.2578 0.52477E-10 -10.2800 0.95002E+00 -0.0223 Charge balance for all species = 0.1074E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2718006E-08 -.4553601E-03 -.4589414E+00 0.0000 2 H2O 0.1000000E+01 0.5550837E+02 0.9999252E+06 0.0000 3 Cl- 0.1379609E-03 0.1379834E-03 0.4891561E+01 4.7054 4 SO4-- 0.2547991E-04 0.2550618E-04 0.2449981E+01 12.5163 5 HCO3- 0.1251059E-04 0.1307088E-04 0.7974886E+00 3.6629 6 HS- 0.1128009E-12 0.2304485E-11 0.7620822E-07 -4.3821 7 Al+++ 0.1428671E-22 0.1419429E-04 0.3829546E+00 2.7803 8 H4SiO4 0.3829605E-03 0.5364679E-03 0.5155897E+02 -3.4168 9 Ca++ 0.6942379E-06 0.7209152E-06 0.2889068E-01 10.9515 10 Mg++ 0.2828923E-08 0.3230621E-08 0.7853699E-04 8.5615 11 Fe++ 0.1673216E-10 0.1536126E-08 0.8578163E-04 6.3335 12 K+ 0.6557670E-04 0.6560949E-04 0.2565271E+01 4.3824 13 Na+ 0.5466742E-03 0.5479780E-03 0.1259696E+02 5.3034 14 Mn++ 0.2233782E-08 0.4961005E-08 0.2725273E-03 8.4590 15 HPO4-- 0.9837420E-07 0.1024435E-06 0.9831690E-02 10.1030 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5103541E-02 -.4553296E-03 -.4648212E-02 0.0000000E+00 2 H2O 0.5550438E+02 0.5550465E+02 -.2728262E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3406791E-04 0.2550447E-04 0.8563446E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8563443E-05 0.2304330E-11 -.8563446E-05 0.0000000E+00 7 Al+++ 0.1007569E-02 0.1419334E-04 0.9933758E-03 0.0000000E+00 8 H4SiO4 0.3217550E-02 0.5364319E-03 0.2681118E-02 0.0000000E+00 9 Ca++ 0.3698651E-03 0.7208669E-06 0.3691443E-03 0.0000000E+00 10 Mg++ 0.2452381E-03 0.3230405E-08 0.2452349E-03 0.0000000E+00 11 Fe++ 0.2203197E-03 0.1536023E-08 0.2203181E-03 0.0000000E+00 12 K+ 0.6560510E-04 0.6560510E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.5479413E-03 0.5479413E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.5357626E-05 0.4960673E-08 0.5352665E-05 0.0000000E+00 15 HPO4-- 0.1828531E-05 0.1024366E-06 0.1726095E-05 0.0000000E+00 Chg. balance for solid moles: -.7505E-18 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.3090000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5754E-06 -6.240 0.2890E-03 -3.539 0.9355E-01 0.9184E-04 clinochlore 0.4905E-04 -4.309 0.2726E-01 -1.564 8.824 0.1037E-01 daphnite 0.3036E-04 -4.518 0.2166E-01 -1.664 7.012 0.6565E-02 chlorite-Mn 0.1071E-05 -5.970 0.7590E-03 -3.120 0.2457 0.2419E-03 hematite 0.3425E-04 -4.465 0.5470E-02 -2.262 1.771 0.1037E-02 kaolinite 0.4994E-04 -4.302 0.1289E-01 -1.890 4.173 0.4961E-02 lawsonite 0.4481E-04 -4.349 0.1408E-01 -1.851 4.558 0.4541E-02 stilbite 0.3215E-03 -3.493 0.2265 -0.645 73.32 0.1057 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1330E-01 0.1330E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.308953 g Volume = 0.133466 cm3 Porosity: 88.1215% V(tot) - V(min): 0.99013E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.3090000 g log = -0.5100 Original solution: 1000.0103000 g Original solution / Rock added: 3236.28 (Water/Rock Ratio), log = 3.5100 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.6685E-05 1.0073 0.7083E-05 0.7032E-05 CH4,gas 0.8468E-16 1.0129 0.9023E-16 0.8908E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.2315E-13 0.9959 0.2425E-13 0.2435E-13 S2,gas 0.5701E-34 1.0000 0.5998E-34 0.5998E-34 CO,gas 0.1057E-14 1.0000 0.1112E-14 0.1112E-14 SO3,gas 0.5191E-37 1.0000 0.5461E-37 0.5461E-37 SO2,gas 0.1190E-20 1.0000 0.1252E-20 0.1252E-20 HCl,gas 0.1069E-15 1.0000 0.1124E-15 0.1124E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.18198E-10 102 lawsonite 9.68 9.68 0.00 0.000 -0.24265E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.51 -7.15 -2.383 0.12208E+05 -5.150 3 CH4,gas 4.81 -13.24 -18.04 -4.511 0.30811E+05 -16.045 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.56 -15.62 -7.808 0.26663E+05 -13.615 6 S2,gas -7.03 -43.25 -36.22 -5.573 0.61848E+05 -34.222 7 CO,gas 3.51 -13.44 -16.95 -5.217 0.28948E+05 -14.954 8 SO3,gas 17.43 -21.84 -39.26 -9.816 0.67040E+05 -37.263 9 SO2,gas 1.14 -21.77 -22.90 -6.107 0.39105E+05 -20.902 10 HCl,gas 5.48 -12.47 -17.95 -8.975 0.30648E+05 -15.949 11 acmite 7.74 4.77 -2.97 -0.308 0.50694E+04 15 albite-high 0.75 -2.17 -2.92 -0.224 0.49799E+04 16 albite -0.33 -2.17 -1.84 -0.141 0.31393E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65958E+04 20 analcite 3.37 1.25 -2.12 -0.236 0.36210E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.91 -4.30 -0.239 0.73365E+04 27 phlogopite 27.15 22.60 -4.55 -0.253 0.77687E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.56 -3.55 -1.183 0.60576E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.56 -3.39 -1.132 0.57962E+04 38 carnegieite-low 9.06 4.67 -4.40 -0.628 0.75091E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.06 -3.34 -0.197 0.57092E+04 43 celadonite-Fe 3.94 -0.17 -4.11 -0.242 0.70145E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14693E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -3.09 -4.82 -0.402 0.82277E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.25 -3.00 -0.300 0.51241E+04 97 kalsilite 7.62 3.75 -3.87 -0.553 0.66155E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.33 -3.84 -0.384 0.65544E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.09 -0.66 -0.050 0.11202E+04 120 muscovite 2.68 2.47 -0.21 -0.012 0.35258E+03 121 paragonite 4.34 3.39 -0.94 -0.055 0.16101E+04 122 nepheline 8.38 4.67 -3.71 -0.530 0.63370E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40533E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.05 -4.10 -1.365 0.69929E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41326E+04 153 sanidine -1.22 -3.09 -1.87 -0.144 0.31879E+04 155 siderite -2.59 -7.18 -4.59 -1.531 0.78404E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.08 -1.09 -0.033 0.18695E+04 165 stilpnomelane-Mg 27.60 23.22 -4.37 -0.130 0.74644E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78744E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.62 -3.18 -0.195 0.54307E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.31 -3.05 -0.187 0.52157E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.75 -2.59 -0.159 0.44255E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.45 -2.49 -0.152 0.42487E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.42 -0.98 -0.063 0.16773E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.73 -0.86 -0.055 0.14640E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.20 -1.88 -0.144 0.32050E+04 243 an25ab75 2.71 0.79 -1.91 -0.147 0.32694E+04 244 an30ab70 3.34 1.39 -1.96 -0.151 0.33421E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.3090000 g New total amount of reactant added: 0.3190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1075E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.3190000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .5083806E-03 Osmotic coef. = 0.9867 True ionic strength = .6549361E-03 Chg. balance for total moles = 0.1075E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.26274E-08 -8.5805 0.24956E-08 -8.6028 0.94982E+00 -0.0224 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13100E-03 -3.8827 0.94955E+00 -0.0225 4 SO4-- 0.25480E-04 -4.5938 0.21868E-04 -4.6602 0.85825E+00 -0.0664 5 HCO3- 0.12496E-04 -4.9032 0.11866E-04 -4.9257 0.94961E+00 -0.0225 6 HS- 0.10888E-12 -12.9630 0.10339E-12 -12.9855 0.94955E+00 -0.0225 7 Al+++ 0.12934E-22 -22.8883 0.93711E-23 -23.0282 0.72454E+00 -0.1399 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.64922E-06 -6.1876 0.55701E-06 -6.2541 0.85796E+00 -0.0665 10 Mg++ 0.26455E-08 -8.5775 0.22692E-08 -8.6441 0.85778E+00 -0.0666 11 Fe++ 0.15647E-10 -10.8056 0.13423E-10 -10.8722 0.85782E+00 -0.0666 12 K+ 0.67699E-04 -4.1694 0.64288E-04 -4.1919 0.94962E+00 -0.0224 13 Na+ 0.55915E-03 -3.2525 0.53094E-03 -3.2750 0.94954E+00 -0.0225 14 Mn++ 0.20891E-08 -8.6800 0.17921E-08 -8.7466 0.85786E+00 -0.0666 15 HPO4-- 0.10550E-06 -6.9767 0.90547E-07 -7.0431 0.85826E+00 -0.0664 16 HSiO3- 0.15768E-03 -3.8022 0.14972E-03 -3.8247 0.94955E+00 -0.0225 17 Ca(HSiO3)+ 0.19676E-08 -8.7061 0.18685E-08 -8.7285 0.94963E+00 -0.0224 18 Mg(HSiO3)+ 0.99760E-11 -11.0010 0.94736E-11 -11.0235 0.94963E+00 -0.0224 19 NaHSiO3,aq 0.12625E-05 -5.8988 0.12625E-05 -5.8988 0.10000E+01 0.0000 20 AlO+ 0.20455E-12 -12.6892 0.19425E-12 -12.7116 0.94963E+00 -0.0224 21 AlOH+2 0.28306E-17 -17.5481 0.24284E-17 -17.6147 0.85790E+00 -0.0666 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.14678E-04 -4.8333 0.13936E-04 -4.8559 0.94947E+00 -0.0225 24 CH4,aq 0.55059E-19 -19.2592 0.55051E-19 -19.2592 0.99984E+00 -0.0001 29 CO,aq 0.67939E-18 -18.1679 0.67939E-18 -18.1679 0.10000E+01 0.0000 30 CO2,aq 0.59715E-07 -7.2239 0.59705E-07 -7.2240 0.99984E+00 -0.0001 31 CO3-2 0.51229E-06 -6.2905 0.43963E-06 -6.3569 0.85817E+00 -0.0664 32 CaCO3,aq 0.29991E-08 -8.5230 0.29991E-08 -8.5230 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.17537E-09 -9.7560 0.16654E-09 -9.7785 0.94963E+00 -0.0224 34 CaCl+ 0.12244E-09 -9.9121 0.11627E-09 -9.9345 0.94963E+00 -0.0224 35 CaCl2,aq 0.35465E-14 -14.4502 0.35465E-14 -14.4502 0.10000E+01 0.0000 36 CaOH+ 0.16573E-07 -7.7806 0.15738E-07 -7.8030 0.94963E+00 -0.0224 37 CaSO4,aq 0.37952E-08 -8.4208 0.37952E-08 -8.4208 0.10000E+01 0.0000 38 HCl,aq 0.61493E-13 -13.2112 0.61493E-13 -13.2112 0.10000E+01 0.0000 43 FeCl+ 0.28839E-14 -14.5400 0.27387E-14 -14.5625 0.94963E+00 -0.0224 46 FeO,aq 0.85226E-10 -10.0694 0.85226E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.18777E-09 -9.7264 0.17831E-09 -9.7488 0.94963E+00 -0.0224 48 HFeO2- 0.38684E-09 -9.4125 0.36733E-09 -9.4349 0.94955E+00 -0.0225 49 FeO+ 0.21739E-13 -13.6628 0.20644E-13 -13.6852 0.94963E+00 -0.0224 50 FeOH+2 0.11174E-19 -19.9518 0.95865E-20 -20.0183 0.85790E+00 -0.0666 51 FeO2- 0.68609E-09 -9.1636 0.65148E-09 -9.1861 0.94955E+00 -0.0225 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44188E-09 -9.3547 0.44181E-09 -9.3548 0.99984E+00 -0.0001 54 KCl,aq 0.14912E-09 -9.8265 0.14912E-09 -9.8265 0.10000E+01 0.0000 55 KHSO4,aq 0.93884E-17 -17.0274 0.93884E-17 -17.0274 0.10000E+01 0.0000 56 KOH,aq 0.11230E-07 -7.9496 0.11230E-07 -7.9496 0.10000E+01 0.0000 57 KSO4- 0.22810E-07 -7.6419 0.21659E-07 -7.6644 0.94955E+00 -0.0225 58 MgCO3,aq 0.30532E-11 -11.5153 0.30532E-11 -11.5153 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.72856E-12 -12.1375 0.69187E-12 -12.1600 0.94963E+00 -0.0224 60 MgCl+ 0.45284E-12 -12.3441 0.43003E-12 -12.3665 0.94963E+00 -0.0224 61 MgOH+ 0.37405E-09 -9.4271 0.35522E-09 -9.4495 0.94963E+00 -0.0224 63 MnO,aq 0.30377E-09 -9.5175 0.30377E-09 -9.5175 0.10000E+01 0.0000 64 MnOH+ 0.23289E-08 -8.6328 0.22116E-08 -8.6553 0.94963E+00 -0.0224 65 MnO2-2 0.19656E-14 -14.7065 0.16868E-14 -14.7729 0.85817E+00 -0.0664 66 HMnO2- 0.96051E-12 -12.0175 0.91205E-12 -12.0400 0.94955E+00 -0.0225 69 MnCl+ 0.14962E-11 -11.8250 0.14209E-11 -11.8474 0.94963E+00 -0.0224 70 MnSO4,aq 0.11107E-10 -10.9544 0.11107E-10 -10.9544 0.10000E+01 0.0000 71 NaCl,aq 0.22711E-07 -7.6438 0.22711E-07 -7.6438 0.10000E+01 0.0000 72 NaOH,aq 0.93485E-07 -7.0293 0.93485E-07 -7.0293 0.10000E+01 0.0000 74 OH- 0.25315E-03 -3.5966 0.24036E-03 -3.6191 0.94947E+00 -0.0225 79 HPO3-2 0.14724E-18 -18.8320 0.12636E-18 -18.8984 0.85817E+00 -0.0664 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.41720E-08 -8.3797 0.39617E-08 -8.4021 0.94959E+00 -0.0225 84 PO4-3 0.43632E-10 -10.3602 0.31686E-10 -10.4991 0.72622E+00 -0.1389 87 H2P2O7-2 0.14314E-17 -17.8442 0.12284E-17 -17.9107 0.85817E+00 -0.0664 88 HP2O7-3 0.13930E-15 -15.8561 0.10093E-15 -15.9960 0.72456E+00 -0.1399 89 P2O7-4 0.17426E-16 -16.7588 0.99773E-17 -17.0010 0.57254E+00 -0.2422 90 H2S,aq 0.77536E-15 -15.1105 0.77523E-15 -15.1106 0.99984E+00 -0.0001 97 SO3-2 0.15340E-14 -14.8142 0.13173E-14 -14.8803 0.85875E+00 -0.0661 98 HSO3- 0.20261E-15 -15.6933 0.19239E-15 -15.7158 0.94955E+00 -0.0225 99 HSO4- 0.53320E-10 -10.2731 0.50636E-10 -10.2955 0.94967E+00 -0.0224 Charge balance for all species = 0.1075E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2627437E-08 -.4714282E-03 -.4751353E+00 0.0000 2 H2O 0.1000000E+01 0.5550837E+02 0.9999243E+06 0.0000 3 Cl- 0.1379607E-03 0.1379837E-03 0.4891566E+01 4.7201 4 SO4-- 0.2547956E-04 0.2550623E-04 0.2449984E+01 12.5455 5 HCO3- 0.1249572E-04 0.1307090E-04 0.7974894E+00 3.6771 6 HS- 0.1088827E-12 -.6170069E-12 -.2040411E-07 -4.3827 7 Al+++ 0.1293385E-22 0.1469367E-04 0.3964271E+00 2.7803 8 H4SiO4 0.3829605E-03 0.5419013E-03 0.5208112E+02 -3.4168 9 Ca++ 0.6492189E-06 0.6748516E-06 0.2704465E-01 10.9515 10 Mg++ 0.2645488E-08 0.3033753E-08 0.7375103E-04 8.5615 11 Fe++ 0.1564717E-10 0.1565069E-08 0.8739779E-04 6.3335 12 K+ 0.6769872E-04 0.6773291E-04 0.2648292E+01 4.4110 13 Na+ 0.5591536E-03 0.5605324E-03 0.1288555E+02 5.3279 14 Mn++ 0.2089077E-08 0.4735338E-08 0.2601303E-03 8.4590 15 HPO4-- 0.1055008E-06 0.1097164E-06 0.1052967E-01 10.1625 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5269126E-02 -.4713956E-03 -.4797731E-02 0.0000000E+00 2 H2O 0.5550425E+02 0.5550455E+02 -.2940366E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3434505E-04 0.2550447E-04 0.8840577E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8840577E-05 -.6169644E-12 -.8840577E-05 0.0000000E+00 7 Al+++ 0.1040177E-02 0.1469265E-04 0.1025484E-02 0.0000000E+00 8 H4SiO4 0.3321678E-02 0.5418639E-03 0.2779814E-02 0.0000000E+00 9 Ca++ 0.3813666E-03 0.6748051E-06 0.3806918E-03 0.0000000E+00 10 Mg++ 0.2531746E-03 0.3033544E-08 0.2531716E-03 0.0000000E+00 11 Fe++ 0.2274497E-03 0.1564961E-08 0.2274482E-03 0.0000000E+00 12 K+ 0.6772824E-04 0.6772824E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.5604937E-03 0.5604937E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.5531012E-05 0.4735012E-08 0.5526277E-05 0.0000000E+00 15 HPO4-- 0.1887707E-05 0.1097088E-06 0.1777998E-05 0.0000000E+00 Chg. balance for solid moles: -.7683E-18 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.3190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5927E-06 -6.227 0.2977E-03 -3.526 0.9307E-01 0.9460E-04 clinochlore 0.5063E-04 -4.296 0.2814E-01 -1.551 8.799 0.1071E-01 daphnite 0.3134E-04 -4.504 0.2236E-01 -1.650 6.992 0.6777E-02 chlorite-Mn 0.1105E-05 -5.957 0.7836E-03 -3.106 0.2450 0.2497E-03 hematite 0.3536E-04 -4.451 0.5647E-02 -2.248 1.766 0.1070E-02 kaolinite 0.5193E-04 -4.285 0.1341E-01 -1.873 4.191 0.5158E-02 lawsonite 0.4348E-04 -4.362 0.1366E-01 -1.864 4.272 0.4406E-02 stilbite 0.3342E-03 -3.476 0.2356 -0.628 73.64 0.1099 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1330E-01 0.1330E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.319859 g Volume = 0.138327 cm3 Porosity: 87.7326% V(tot) - V(min): 0.98927E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.3190000 g log = -0.4962 Original solution: 1000.0103000 g Original solution / Rock added: 3134.83 (Water/Rock Ratio), log = 3.4962 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.6450E-05 1.0073 0.6834E-05 0.6785E-05 CH4,gas 0.8170E-16 1.0129 0.8706E-16 0.8595E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.2158E-13 0.9959 0.2261E-13 0.2270E-13 S2,gas 0.4957E-34 1.0000 0.5214E-34 0.5214E-34 CO,gas 0.1020E-14 1.0000 0.1073E-14 0.1073E-14 SO3,gas 0.4840E-37 1.0000 0.5092E-37 0.5092E-37 SO2,gas 0.1110E-20 1.0000 0.1167E-20 0.1167E-20 HCl,gas 0.1032E-15 1.0000 0.1086E-15 0.1086E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.53 -7.17 -2.388 0.12235E+05 -5.165 3 CH4,gas 4.81 -13.25 -18.06 -4.515 0.30837E+05 -16.060 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.59 -15.65 -7.823 0.26715E+05 -13.646 6 S2,gas -7.03 -43.32 -36.28 -5.582 0.61952E+05 -34.283 7 CO,gas 3.51 -13.46 -16.97 -5.221 0.28975E+05 -14.969 8 SO3,gas 17.43 -21.87 -39.29 -9.823 0.67092E+05 -37.293 9 SO2,gas 1.14 -21.80 -22.93 -6.115 0.39157E+05 -20.933 10 HCl,gas 5.48 -12.49 -17.96 -8.982 0.30673E+05 -15.964 11 acmite 7.74 4.79 -2.94 -0.306 0.50275E+04 15 albite-high 0.75 -2.14 -2.89 -0.222 0.49381E+04 16 albite -0.33 -2.14 -1.81 -0.140 0.30974E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65956E+04 20 analcite 3.37 1.27 -2.10 -0.233 0.35792E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.94 -4.27 -0.237 0.72878E+04 27 phlogopite 27.15 22.63 -4.52 -0.251 0.77200E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.58 -3.56 -1.188 0.60841E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.58 -3.41 -1.137 0.58228E+04 38 carnegieite-low 9.06 4.69 -4.37 -0.625 0.74672E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.09 -3.32 -0.195 0.56605E+04 43 celadonite-Fe 3.94 -0.14 -4.08 -0.240 0.69658E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14692E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -3.06 -4.79 -0.399 0.81789E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.27 -2.98 -0.298 0.50822E+04 97 kalsilite 7.62 3.77 -3.85 -0.549 0.65667E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.36 -3.81 -0.381 0.65056E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.06 -0.63 -0.048 0.10715E+04 120 muscovite 2.68 2.50 -0.18 -0.010 0.30384E+03 121 paragonite 4.34 3.42 -0.92 -0.054 0.15683E+04 122 nepheline 8.38 4.69 -3.69 -0.527 0.62951E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40533E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.07 -4.11 -1.370 0.70194E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41325E+04 153 sanidine -1.22 -3.06 -1.84 -0.141 0.31392E+04 155 siderite -2.59 -7.20 -4.61 -1.536 0.78669E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.10 -1.08 -0.032 0.18452E+04 165 stilpnomelane-Mg 27.60 23.24 -4.36 -0.130 0.74400E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78743E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.61 -3.17 -0.194 0.54146E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.30 -3.05 -0.187 0.52019E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.74 -2.58 -0.158 0.44094E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.44 -2.48 -0.152 0.42349E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.43 -0.97 -0.062 0.16612E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.73 -0.85 -0.055 0.14502E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.22 -1.86 -0.143 0.31715E+04 243 an25ab75 2.71 0.81 -1.90 -0.146 0.32380E+04 244 an30ab70 3.34 1.40 -1.94 -0.149 0.33128E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.3190000 g New total amount of reactant added: 0.3290000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1075E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.3290000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .5178988E-03 Osmotic coef. = 0.9866 True ionic strength = .6694360E-03 Chg. balance for total moles = 0.1075E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.25428E-08 -8.5947 0.24143E-08 -8.6172 0.94948E+00 -0.0225 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13095E-03 -3.8829 0.94921E+00 -0.0226 4 SO4-- 0.25479E-04 -4.5938 0.21836E-04 -4.6608 0.85703E+00 -0.0670 5 HCO3- 0.12481E-04 -4.9038 0.11848E-04 -4.9264 0.94927E+00 -0.0226 6 HS- 0.10522E-12 -12.9779 0.99878E-13 -13.0005 0.94921E+00 -0.0226 7 Al+++ 0.11749E-22 -22.9300 0.84850E-23 -23.0713 0.72221E+00 -0.1413 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.60849E-06 -6.2157 0.52132E-06 -6.2829 0.85673E+00 -0.0672 10 Mg++ 0.24796E-08 -8.6056 0.21238E-08 -8.6729 0.85655E+00 -0.0672 11 Fe++ 0.14666E-10 -10.8337 0.12562E-10 -10.9009 0.85659E+00 -0.0672 12 K+ 0.69821E-04 -4.1560 0.66280E-04 -4.1786 0.94928E+00 -0.0226 13 Na+ 0.57163E-03 -3.2429 0.54259E-03 -3.2655 0.94920E+00 -0.0226 14 Mn++ 0.19582E-08 -8.7082 0.16774E-08 -8.7754 0.85662E+00 -0.0672 15 HPO4-- 0.11288E-06 -6.9474 0.96746E-07 -7.0144 0.85703E+00 -0.0670 16 HSiO3- 0.16304E-03 -3.7877 0.15476E-03 -3.8103 0.94921E+00 -0.0226 17 Ca(HSiO3)+ 0.19042E-08 -8.7203 0.18076E-08 -8.7429 0.94929E+00 -0.0226 18 Mg(HSiO3)+ 0.96546E-11 -11.0153 0.91651E-11 -11.0379 0.94929E+00 -0.0226 19 NaHSiO3,aq 0.13337E-05 -5.8749 0.13337E-05 -5.8749 0.10000E+01 0.0000 20 AlO+ 0.19796E-12 -12.7034 0.18792E-12 -12.7260 0.94929E+00 -0.0226 21 AlOH+2 0.26531E-17 -17.5763 0.22728E-17 -17.6434 0.85666E+00 -0.0672 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.15178E-04 -4.8188 0.14405E-04 -4.8415 0.94912E+00 -0.0227 24 CH4,aq 0.53183E-19 -19.2742 0.53174E-19 -19.2743 0.99984E+00 -0.0001 29 CO,aq 0.65624E-18 -18.1829 0.65624E-18 -18.1829 0.10000E+01 0.0000 30 CO2,aq 0.57680E-07 -7.2390 0.57671E-07 -7.2390 0.99984E+00 -0.0001 31 CO3-2 0.52947E-06 -6.2762 0.45372E-06 -6.3432 0.85694E+00 -0.0670 32 CaCO3,aq 0.28970E-08 -8.5381 0.28970E-08 -8.5381 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.16394E-09 -9.7853 0.15563E-09 -9.8079 0.94929E+00 -0.0226 34 CaCl+ 0.11460E-09 -9.9408 0.10878E-09 -9.9634 0.94929E+00 -0.0226 35 CaCl2,aq 0.33169E-14 -14.4793 0.33169E-14 -14.4793 0.10000E+01 0.0000 36 CaOH+ 0.16039E-07 -7.7948 0.15226E-07 -7.8174 0.94929E+00 -0.0226 37 CaSO4,aq 0.35469E-08 -8.4502 0.35469E-08 -8.4502 0.10000E+01 0.0000 38 HCl,aq 0.59469E-13 -13.2257 0.59469E-13 -13.2257 0.10000E+01 0.0000 43 FeCl+ 0.26991E-14 -14.5688 0.25623E-14 -14.5914 0.94929E+00 -0.0226 46 FeO,aq 0.85226E-10 -10.0694 0.85226E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.18172E-09 -9.7406 0.17250E-09 -9.7632 0.94929E+00 -0.0226 48 HFeO2- 0.40001E-09 -9.3979 0.37969E-09 -9.4206 0.94921E+00 -0.0226 49 FeO+ 0.21038E-13 -13.6770 0.19972E-13 -13.6996 0.94929E+00 -0.0226 50 FeOH+2 0.10474E-19 -19.9799 0.89723E-20 -20.0471 0.85666E+00 -0.0672 51 FeO2- 0.70944E-09 -9.1491 0.67341E-09 -9.1717 0.94921E+00 -0.0226 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44188E-09 -9.3547 0.44181E-09 -9.3548 0.99984E+00 -0.0001 54 KCl,aq 0.15368E-09 -9.8134 0.15368E-09 -9.8134 0.10000E+01 0.0000 55 KHSO4,aq 0.93505E-17 -17.0292 0.93505E-17 -17.0292 0.10000E+01 0.0000 56 KOH,aq 0.11968E-07 -7.9220 0.11968E-07 -7.9220 0.10000E+01 0.0000 57 KSO4- 0.23491E-07 -7.6291 0.22298E-07 -7.6517 0.94921E+00 -0.0226 58 MgCO3,aq 0.29491E-11 -11.5303 0.29491E-11 -11.5303 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.68106E-12 -12.1668 0.64653E-12 -12.1894 0.94929E+00 -0.0226 60 MgCl+ 0.42383E-12 -12.3728 0.40234E-12 -12.3954 0.94929E+00 -0.0226 61 MgOH+ 0.36200E-09 -9.4413 0.34365E-09 -9.4639 0.94929E+00 -0.0226 63 MnO,aq 0.30378E-09 -9.5174 0.30378E-09 -9.5174 0.10000E+01 0.0000 64 MnOH+ 0.22540E-08 -8.6470 0.21397E-08 -8.6696 0.94929E+00 -0.0226 65 MnO2-2 0.21033E-14 -14.6771 0.18024E-14 -14.7442 0.85694E+00 -0.0670 66 HMnO2- 0.99326E-12 -12.0029 0.94281E-12 -12.0256 0.94921E+00 -0.0226 69 MnCl+ 0.14005E-11 -11.8537 0.13294E-11 -11.8763 0.94929E+00 -0.0226 70 MnSO4,aq 0.10381E-10 -10.9838 0.10381E-10 -10.9838 0.10000E+01 0.0000 71 NaCl,aq 0.23201E-07 -7.6345 0.23201E-07 -7.6345 0.10000E+01 0.0000 72 NaOH,aq 0.98752E-07 -7.0055 0.98752E-07 -7.0055 0.10000E+01 0.0000 74 OH- 0.26177E-03 -3.5821 0.24845E-03 -3.6048 0.94912E+00 -0.0227 79 HPO3-2 0.15755E-18 -18.8026 0.13501E-18 -18.8696 0.85694E+00 -0.0670 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.43140E-08 -8.3651 0.40950E-08 -8.3877 0.94925E+00 -0.0226 84 PO4-3 0.48341E-10 -10.3157 0.34995E-10 -10.4560 0.72392E+00 -0.1403 87 H2P2O7-2 0.15316E-17 -17.8149 0.13124E-17 -17.8819 0.85694E+00 -0.0670 88 HP2O7-3 0.15434E-15 -15.8115 0.11147E-15 -15.9528 0.72222E+00 -0.1413 89 P2O7-4 0.20008E-16 -16.6988 0.11390E-16 -16.9435 0.56928E+00 -0.2447 90 H2S,aq 0.72462E-15 -15.1399 0.72451E-15 -15.1400 0.99984E+00 -0.0001 97 SO3-2 0.15340E-14 -14.8142 0.13154E-14 -14.8809 0.85754E+00 -0.0667 98 HSO3- 0.19580E-15 -15.7082 0.18586E-15 -15.7308 0.94921E+00 -0.0226 99 HSO4- 0.51527E-10 -10.2880 0.48917E-10 -10.3105 0.94934E+00 -0.0226 Charge balance for all species = 0.1074E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2542772E-08 -.4875053E-03 -.4913384E+00 0.0000 2 H2O 0.1000000E+01 0.5550838E+02 0.9999234E+06 0.0000 3 Cl- 0.1379605E-03 0.1379840E-03 0.4891570E+01 4.7343 4 SO4-- 0.2547918E-04 0.2550628E-04 0.2449986E+01 12.5736 5 HCO3- 0.1248072E-04 0.1307093E-04 0.7974902E+00 3.6908 6 HS- 0.1052217E-12 -.3539501E-11 -.1170494E-06 -4.3833 7 Al+++ 0.1174877E-22 0.1519326E-04 0.4099056E+00 2.7803 8 H4SiO4 0.3829605E-03 0.5473389E-03 0.5260367E+02 -3.4168 9 Ca++ 0.6084947E-06 0.6331602E-06 0.2537385E-01 10.9515 10 Mg++ 0.2479551E-08 0.2855263E-08 0.6941183E-04 8.5615 11 Fe++ 0.1466569E-10 0.1594553E-08 0.8904420E-04 6.3335 12 K+ 0.6982072E-04 0.6985633E-04 0.2731313E+01 4.4386 13 Na+ 0.5716312E-03 0.5730868E-03 0.1317414E+02 5.3517 14 Mn++ 0.1958157E-08 0.4528748E-08 0.2487813E-03 8.4591 15 HPO4-- 0.1128843E-06 0.1172466E-06 0.1125235E-01 10.2200 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5434712E-02 -.4874707E-03 -.4947241E-02 0.0000000E+00 2 H2O 0.5550413E+02 0.5550444E+02 -.3152471E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3462218E-04 0.2550447E-04 0.9117708E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9117712E-05 -.3539250E-11 -.9117708E-05 0.0000000E+00 7 Al+++ 0.1072784E-02 0.1519219E-04 0.1057592E-02 0.0000000E+00 8 H4SiO4 0.3425806E-02 0.5473001E-03 0.2878505E-02 0.0000000E+00 9 Ca++ 0.3928680E-03 0.6331153E-06 0.3922349E-03 0.0000000E+00 10 Mg++ 0.2611111E-03 0.2855060E-08 0.2611083E-03 0.0000000E+00 11 Fe++ 0.2345798E-03 0.1594440E-08 0.2345782E-03 0.0000000E+00 12 K+ 0.6985138E-04 0.6985138E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.5730462E-03 0.5730462E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.5704398E-05 0.4528427E-08 0.5699870E-05 0.0000000E+00 15 HPO4-- 0.1946883E-05 0.1172383E-06 0.1829644E-05 0.0000000E+00 Chg. balance for solid moles: 0.4163E-18 Mass of aqueous solution: 0.100001E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.3290000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6099E-06 -6.215 0.3064E-03 -3.514 0.9262E-01 0.9735E-04 clinochlore 0.5222E-04 -4.282 0.2903E-01 -1.537 8.776 0.1104E-01 daphnite 0.3233E-04 -4.490 0.2307E-01 -1.637 6.974 0.6990E-02 chlorite-Mn 0.1140E-05 -5.943 0.8082E-03 -3.092 0.2443 0.2576E-03 hematite 0.3647E-04 -4.438 0.5824E-02 -2.235 1.761 0.1104E-02 kaolinite 0.5392E-04 -4.268 0.1392E-01 -1.856 4.209 0.5356E-02 lawsonite 0.4214E-04 -4.375 0.1324E-01 -1.878 4.004 0.4270E-02 stilbite 0.3470E-03 -3.460 0.2446 -0.612 73.94 0.1141 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1330E-01 0.1330E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.330763 g Volume = 0.143187 cm3 Porosity: 87.3465% V(tot) - V(min): 0.98841E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.3290000 g log = -0.4828 Original solution: 1000.0103000 g Original solution / Rock added: 3039.54 (Water/Rock Ratio), log = 3.4828 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.6230E-05 1.0073 0.6601E-05 0.6553E-05 CH4,gas 0.7892E-16 1.0129 0.8409E-16 0.8302E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.2017E-13 0.9959 0.2113E-13 0.2122E-13 S2,gas 0.4329E-34 1.0000 0.4554E-34 0.4554E-34 CO,gas 0.9850E-15 1.0000 0.1036E-14 0.1036E-14 SO3,gas 0.4524E-37 1.0000 0.4758E-37 0.4758E-37 SO2,gas 0.1037E-20 1.0000 0.1091E-20 0.1091E-20 HCl,gas 0.9982E-16 1.0000 0.1050E-15 0.1050E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.54 -7.18 -2.393 0.12260E+05 -5.180 3 CH4,gas 4.81 -13.27 -18.08 -4.519 0.30863E+05 -16.075 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.62 -15.68 -7.838 0.26765E+05 -13.675 6 S2,gas -7.03 -43.37 -36.34 -5.591 0.62052E+05 -34.342 7 CO,gas 3.51 -13.47 -16.98 -5.226 0.29001E+05 -14.985 8 SO3,gas 17.43 -21.90 -39.32 -9.831 0.67142E+05 -37.323 9 SO2,gas 1.14 -21.83 -22.96 -6.123 0.39207E+05 -20.962 10 HCl,gas 5.48 -12.50 -17.98 -8.989 0.30698E+05 -15.979 11 acmite 7.74 4.82 -2.92 -0.303 0.49868E+04 15 albite-high 0.75 -2.12 -2.87 -0.221 0.48974E+04 16 albite -0.33 -2.12 -1.79 -0.138 0.30568E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65955E+04 20 analcite 3.37 1.30 -2.07 -0.230 0.35385E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 15.97 -4.24 -0.236 0.72406E+04 27 phlogopite 27.15 22.65 -4.49 -0.250 0.76728E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.59 -3.58 -1.193 0.61098E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.59 -3.43 -1.142 0.58485E+04 38 carnegieite-low 9.06 4.72 -4.35 -0.621 0.74266E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.11 -3.29 -0.193 0.56133E+04 43 celadonite-Fe 3.94 -0.12 -4.05 -0.238 0.69186E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14692E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -3.03 -4.76 -0.397 0.81317E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.30 -2.95 -0.295 0.50416E+04 97 kalsilite 7.62 3.80 -3.82 -0.545 0.65195E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.39 -3.78 -0.378 0.64585E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.03 -0.60 -0.046 0.10243E+04 120 muscovite 2.68 2.53 -0.15 -0.009 0.25667E+03 121 paragonite 4.34 3.44 -0.89 -0.053 0.15276E+04 122 nepheline 8.38 4.72 -3.66 -0.523 0.62545E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40532E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.08 -4.13 -1.375 0.70450E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41325E+04 153 sanidine -1.22 -3.03 -1.81 -0.139 0.30920E+04 155 siderite -2.59 -7.21 -4.62 -1.541 0.78927E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.11 -1.07 -0.032 0.18216E+04 165 stilpnomelane-Mg 27.60 23.25 -4.34 -0.130 0.74164E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78743E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.60 -3.16 -0.194 0.53991E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.30 -3.04 -0.186 0.51885E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.73 -2.57 -0.158 0.43939E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.43 -2.47 -0.151 0.42215E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.44 -0.96 -0.062 0.16457E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.74 -0.84 -0.054 0.14368E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.24 -1.84 -0.141 0.31390E+04 243 an25ab75 2.71 0.83 -1.88 -0.144 0.32075E+04 244 an30ab70 3.34 1.42 -1.92 -0.148 0.32843E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.3290000 g New total amount of reactant added: 0.3390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1075E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.3390000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .5274262E-03 Osmotic coef. = 0.9865 True ionic strength = .6839455E-03 Chg. balance for total moles = 0.1075E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.24635E-08 -8.6085 0.23382E-08 -8.6311 0.94915E+00 -0.0227 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13091E-03 -3.8830 0.94887E+00 -0.0228 4 SO4-- 0.25479E-04 -4.5938 0.21805E-04 -4.6614 0.85582E+00 -0.0676 5 HCO3- 0.12466E-04 -4.9043 0.11829E-04 -4.9271 0.94893E+00 -0.0228 6 HS- 0.10179E-12 -12.9923 0.96589E-13 -13.0151 0.94887E+00 -0.0228 7 Al+++ 0.10706E-22 -22.9704 0.77074E-23 -23.1131 0.71991E+00 -0.1427 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.57154E-06 -6.2430 0.48896E-06 -6.3107 0.85552E+00 -0.0678 10 Mg++ 0.23290E-08 -8.6328 0.19920E-08 -8.7007 0.85533E+00 -0.0679 11 Fe++ 0.13775E-10 -10.8609 0.11783E-10 -10.9288 0.85537E+00 -0.0678 12 K+ 0.71943E-04 -4.1430 0.68270E-04 -4.1658 0.94895E+00 -0.0228 13 Na+ 0.58411E-03 -3.2335 0.55424E-03 -3.2563 0.94886E+00 -0.0228 14 Mn++ 0.18393E-08 -8.7353 0.15734E-08 -8.8032 0.85541E+00 -0.0678 15 HPO4-- 0.12052E-06 -6.9189 0.10315E-06 -6.9865 0.85582E+00 -0.0676 16 HSiO3- 0.16841E-03 -3.7736 0.15980E-03 -3.7964 0.94887E+00 -0.0228 17 Ca(HSiO3)+ 0.18448E-08 -8.7340 0.17506E-08 -8.7568 0.94896E+00 -0.0228 18 Mg(HSiO3)+ 0.93535E-11 -11.0290 0.88761E-11 -11.0518 0.94896E+00 -0.0228 19 NaHSiO3,aq 0.14067E-05 -5.8518 0.14067E-05 -5.8518 0.10000E+01 0.0000 20 AlO+ 0.19179E-12 -12.7172 0.18200E-12 -12.7399 0.94896E+00 -0.0228 21 AlOH+2 0.24919E-17 -17.6035 0.21317E-17 -17.6713 0.85545E+00 -0.0678 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.15677E-04 -4.8047 0.14875E-04 -4.8276 0.94878E+00 -0.0228 24 CH4,aq 0.51425E-19 -19.2888 0.51417E-19 -19.2889 0.99984E+00 -0.0001 29 CO,aq 0.63455E-18 -18.1975 0.63455E-18 -18.1975 0.10000E+01 0.0000 30 CO2,aq 0.55774E-07 -7.2536 0.55765E-07 -7.2536 0.99984E+00 -0.0001 31 CO3-2 0.54662E-06 -6.2623 0.46776E-06 -6.3300 0.85573E+00 -0.0677 32 CaCO3,aq 0.28012E-08 -8.5527 0.28012E-08 -8.5527 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.15358E-09 -9.8137 0.14574E-09 -9.8364 0.94896E+00 -0.0228 34 CaCl+ 0.10748E-09 -9.9687 0.10200E-09 -9.9914 0.94896E+00 -0.0228 35 CaCl2,aq 0.31088E-14 -14.5074 0.31088E-14 -14.5074 0.10000E+01 0.0000 36 CaOH+ 0.15539E-07 -7.8086 0.14746E-07 -7.8313 0.94896E+00 -0.0228 37 CaSO4,aq 0.33220E-08 -8.4786 0.33220E-08 -8.4786 0.10000E+01 0.0000 38 HCl,aq 0.57573E-13 -13.2398 0.57573E-13 -13.2398 0.10000E+01 0.0000 43 FeCl+ 0.25316E-14 -14.5966 0.24023E-14 -14.6194 0.94896E+00 -0.0228 46 FeO,aq 0.85226E-10 -10.0694 0.85226E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.17605E-09 -9.7544 0.16706E-09 -9.7771 0.94896E+00 -0.0228 48 HFeO2- 0.41318E-09 -9.3839 0.39205E-09 -9.4067 0.94887E+00 -0.0228 49 FeO+ 0.20382E-13 -13.6908 0.19342E-13 -13.7135 0.94896E+00 -0.0228 51 FeO2- 0.73280E-09 -9.1350 0.69533E-09 -9.1578 0.94887E+00 -0.0228 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44188E-09 -9.3547 0.44181E-09 -9.3548 0.99984E+00 -0.0001 54 KCl,aq 0.15824E-09 -9.8007 0.15824E-09 -9.8007 0.10000E+01 0.0000 55 KHSO4,aq 0.93143E-17 -17.0309 0.93143E-17 -17.0309 0.10000E+01 0.0000 56 KOH,aq 0.12729E-07 -7.8952 0.12729E-07 -7.8952 0.10000E+01 0.0000 57 KSO4- 0.24170E-07 -7.6167 0.22935E-07 -7.6395 0.94887E+00 -0.0228 58 MgCO3,aq 0.28517E-11 -11.5449 0.28517E-11 -11.5449 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.63802E-12 -12.1952 0.60545E-12 -12.2179 0.94896E+00 -0.0228 60 MgCl+ 0.39752E-12 -12.4006 0.37723E-12 -12.4234 0.94896E+00 -0.0228 61 MgOH+ 0.35071E-09 -9.4550 0.33281E-09 -9.4778 0.94896E+00 -0.0228 63 MnO,aq 0.30380E-09 -9.5174 0.30380E-09 -9.5174 0.10000E+01 0.0000 64 MnOH+ 0.21838E-08 -8.6608 0.20724E-08 -8.6835 0.94896E+00 -0.0228 65 MnO2-2 0.22458E-14 -14.6486 0.19218E-14 -14.7163 0.85573E+00 -0.0677 66 HMnO2- 0.10260E-11 -11.9888 0.97356E-12 -12.0116 0.94887E+00 -0.0228 69 MnCl+ 0.13136E-11 -11.8815 0.12465E-11 -11.9043 0.94896E+00 -0.0228 70 MnSO4,aq 0.97229E-11 -11.0122 0.97229E-11 -11.0122 0.10000E+01 0.0000 71 NaCl,aq 0.23690E-07 -7.6254 0.23690E-07 -7.6254 0.10000E+01 0.0000 72 NaOH,aq 0.10416E-06 -6.9823 0.10416E-06 -6.9823 0.10000E+01 0.0000 74 OH- 0.27039E-03 -3.5680 0.25654E-03 -3.5908 0.94878E+00 -0.0228 79 HPO3-2 0.16821E-18 -18.7742 0.14394E-18 -18.8418 0.85573E+00 -0.0677 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.44560E-08 -8.3511 0.42284E-08 -8.3738 0.94891E+00 -0.0228 84 PO4-3 0.53386E-10 -10.2726 0.38526E-10 -10.4142 0.72165E+00 -0.1417 87 H2P2O7-2 0.16352E-17 -17.7864 0.13993E-17 -17.8541 0.85573E+00 -0.0677 88 HP2O7-3 0.17046E-15 -15.7684 0.12272E-15 -15.9111 0.71992E+00 -0.1427 89 P2O7-4 0.22873E-16 -16.6407 0.12948E-16 -16.8878 0.56607E+00 -0.2471 90 H2S,aq 0.67867E-15 -15.1683 0.67856E-15 -15.1684 0.99984E+00 -0.0001 97 SO3-2 0.15339E-14 -14.8142 0.13136E-14 -14.8815 0.85634E+00 -0.0674 98 HSO3- 0.18943E-15 -15.7226 0.17974E-15 -15.7454 0.94887E+00 -0.0228 99 HSO4- 0.49849E-10 -10.3023 0.47307E-10 -10.3251 0.94900E+00 -0.0227 Charge balance for all species = 0.1075E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2463455E-08 -.5035902E-03 -.5075493E+00 0.0000 2 H2O 0.1000000E+01 0.5550838E+02 0.9999225E+06 0.0000 3 Cl- 0.1379603E-03 0.1379842E-03 0.4891575E+01 4.7481 4 SO4-- 0.2547878E-04 0.2550634E-04 0.2449989E+01 12.6008 5 HCO3- 0.1246560E-04 0.1307095E-04 0.7974910E+00 3.7041 6 HS- 0.1017937E-12 -.6462810E-11 -.2137214E-06 -4.3839 7 Al+++ 0.1070615E-22 0.1569305E-04 0.4233892E+00 2.7803 8 H4SiO4 0.3829605E-03 0.5527804E-03 0.5312658E+02 -3.4168 9 Ca++ 0.5715359E-06 0.5953037E-06 0.2385673E-01 10.9515 10 Mg++ 0.2328958E-08 0.2692910E-08 0.6546496E-04 8.5615 11 Fe++ 0.1377495E-10 0.1624525E-08 0.9071778E-04 6.3335 12 K+ 0.7194271E-04 0.7197977E-04 0.2814334E+01 4.4653 13 Na+ 0.5841068E-03 0.5856413E-03 0.1346273E+02 5.3748 14 Mn++ 0.1839327E-08 0.4339040E-08 0.2383597E-03 8.4591 15 HPO4-- 0.1205248E-06 0.1250342E-06 0.1199973E-01 10.2757 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5600297E-02 -.5035535E-03 -.5096743E-02 0.0000000E+00 2 H2O 0.5550400E+02 0.5550434E+02 -.3364577E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3489932E-04 0.2550448E-04 0.9394839E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9394846E-05 -.6462339E-11 -.9394839E-05 0.0000000E+00 7 Al+++ 0.1105391E-02 0.1569191E-04 0.1089699E-02 0.0000000E+00 8 H4SiO4 0.3529933E-02 0.5527401E-03 0.2977193E-02 0.0000000E+00 9 Ca++ 0.4043694E-03 0.5952603E-06 0.4037742E-03 0.0000000E+00 10 Mg++ 0.2690476E-03 0.2692714E-08 0.2690449E-03 0.0000000E+00 11 Fe++ 0.2417099E-03 0.1624406E-08 0.2417083E-03 0.0000000E+00 12 K+ 0.7197452E-04 0.7197452E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.5855986E-03 0.5855986E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.5877784E-05 0.4338724E-08 0.5873445E-05 0.0000000E+00 15 HPO4-- 0.2006058E-05 0.1250251E-06 0.1881033E-05 0.0000000E+00 Chg. balance for solid moles: 0.1880E-18 Mass of aqueous solution: 0.100000E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.3390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6270E-06 -6.203 0.3150E-03 -3.502 0.9218E-01 0.1001E-03 clinochlore 0.5381E-04 -4.269 0.2991E-01 -1.524 8.754 0.1138E-01 daphnite 0.3331E-04 -4.477 0.2377E-01 -1.624 6.956 0.7202E-02 chlorite-Mn 0.1175E-05 -5.930 0.8328E-03 -3.079 0.2438 0.2654E-03 hematite 0.3758E-04 -4.425 0.6001E-02 -2.222 1.757 0.1137E-02 kaolinite 0.5592E-04 -4.252 0.1444E-01 -1.841 4.225 0.5554E-02 lawsonite 0.4080E-04 -4.389 0.1282E-01 -1.892 3.752 0.4134E-02 stilbite 0.3598E-03 -3.444 0.2536 -0.596 74.22 0.1183 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1330E-01 0.1330E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.341668 g Volume = 0.148047 cm3 Porosity: 86.9631% V(tot) - V(min): 0.98755E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.3390000 g log = -0.4698 Original solution: 1000.0103000 g Original solution / Rock added: 2949.88 (Water/Rock Ratio), log = 3.4698 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.6024E-05 1.0073 0.6383E-05 0.6337E-05 CH4,gas 0.7631E-16 1.0129 0.8131E-16 0.8027E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.1889E-13 0.9959 0.1979E-13 0.1987E-13 S2,gas 0.3798E-34 1.0000 0.3995E-34 0.3995E-34 CO,gas 0.9525E-15 1.0000 0.1002E-14 0.1002E-14 SO3,gas 0.4237E-37 1.0000 0.4457E-37 0.4457E-37 SO2,gas 0.9712E-21 1.0000 0.1022E-20 0.1022E-20 HCl,gas 0.9664E-16 1.0000 0.1017E-15 0.1017E-15 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.56 -7.19 -2.398 0.12285E+05 -5.195 3 CH4,gas 4.81 -13.28 -18.09 -4.522 0.30888E+05 -16.090 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.65 -15.70 -7.852 0.26813E+05 -13.704 6 S2,gas -7.03 -43.43 -36.40 -5.600 0.62149E+05 -34.398 7 CO,gas 3.51 -13.49 -17.00 -5.231 0.29026E+05 -14.999 8 SO3,gas 17.43 -21.92 -39.35 -9.838 0.67191E+05 -37.351 9 SO2,gas 1.14 -21.85 -22.99 -6.131 0.39256E+05 -20.991 10 HCl,gas 5.48 -12.51 -17.99 -8.996 0.30722E+05 -15.993 11 acmite 7.74 4.84 -2.90 -0.301 0.49473E+04 15 albite-high 0.75 -2.10 -2.85 -0.219 0.48579E+04 16 albite -0.33 -2.10 -1.77 -0.136 0.30172E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65954E+04 20 analcite 3.37 1.32 -2.05 -0.228 0.34990E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 16.00 -4.21 -0.234 0.71949E+04 27 phlogopite 27.15 22.68 -4.47 -0.248 0.76271E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.61 -3.59 -1.198 0.61347E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.61 -3.44 -1.147 0.58734E+04 38 carnegieite-low 9.06 4.74 -4.33 -0.618 0.73871E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.14 -3.26 -0.192 0.55676E+04 43 celadonite-Fe 3.94 -0.09 -4.03 -0.237 0.68729E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14692E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -3.00 -4.74 -0.395 0.80861E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.32 -2.93 -0.293 0.50020E+04 97 kalsilite 7.62 3.83 -3.79 -0.542 0.64738E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.41 -3.76 -0.376 0.64128E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -3.00 -0.57 -0.044 0.97858E+03 120 muscovite 2.68 2.56 -0.12 -0.007 0.21097E+03 121 paragonite 4.34 3.47 -0.87 -0.051 0.14881E+04 122 nepheline 8.38 4.74 -3.64 -0.520 0.62150E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40532E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.10 -4.14 -1.380 0.70699E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41324E+04 153 sanidine -1.22 -3.00 -1.78 -0.137 0.30463E+04 155 siderite -2.59 -7.22 -4.64 -1.546 0.79176E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.13 -1.05 -0.031 0.17987E+04 165 stilpnomelane-Mg 27.60 23.27 -4.33 -0.129 0.73936E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78742E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.59 -3.15 -0.193 0.53840E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.29 -3.03 -0.186 0.51755E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.73 -2.56 -0.157 0.43788E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.43 -2.46 -0.151 0.42084E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.45 -0.95 -0.061 0.16306E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.75 -0.83 -0.054 0.14238E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.26 -1.82 -0.140 0.31074E+04 243 an25ab75 2.71 0.85 -1.86 -0.143 0.31779E+04 244 an30ab70 3.34 1.44 -1.91 -0.147 0.32567E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.3390000 g New total amount of reactant added: 0.3490000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1075E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.3490000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .5369617E-03 Osmotic coef. = 0.9864 True ionic strength = .6984635E-03 Chg. balance for total moles = 0.1075E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.23890E-08 -8.6218 0.22667E-08 -8.6446 0.94882E+00 -0.0228 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13086E-03 -3.8832 0.94853E+00 -0.0229 4 SO4-- 0.25478E-04 -4.5938 0.21774E-04 -4.6621 0.85462E+00 -0.0682 5 HCO3- 0.12450E-04 -4.9048 0.11810E-04 -4.9277 0.94860E+00 -0.0229 6 HS- 0.98577E-13 -13.0062 0.93505E-13 -13.0292 0.94854E+00 -0.0229 7 Al+++ 0.97851E-23 -23.0094 0.70222E-23 -23.1535 0.71764E+00 -0.1441 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.53789E-06 -6.2693 0.45953E-06 -6.3377 0.85432E+00 -0.0684 10 Mg++ 0.21919E-08 -8.6592 0.18721E-08 -8.7277 0.85412E+00 -0.0685 11 Fe++ 0.12964E-10 -10.8873 0.11074E-10 -10.9557 0.85417E+00 -0.0685 12 K+ 0.74065E-04 -4.1304 0.70259E-04 -4.1533 0.94861E+00 -0.0229 13 Na+ 0.59658E-03 -3.2243 0.56587E-03 -3.2473 0.94853E+00 -0.0230 14 Mn++ 0.17311E-08 -8.7617 0.14787E-08 -8.8301 0.85420E+00 -0.0684 15 HPO4-- 0.12842E-06 -6.8914 0.10975E-06 -6.9596 0.85463E+00 -0.0682 16 HSiO3- 0.17378E-03 -3.7600 0.16484E-03 -3.7829 0.94853E+00 -0.0229 17 Ca(HSiO3)+ 0.17891E-08 -8.7474 0.16971E-08 -8.7703 0.94862E+00 -0.0229 18 Mg(HSiO3)+ 0.90708E-11 -11.0424 0.86048E-11 -11.0653 0.94862E+00 -0.0229 19 NaHSiO3,aq 0.14815E-05 -5.8293 0.14815E-05 -5.8293 0.10000E+01 0.0000 20 AlO+ 0.18599E-12 -12.7305 0.17644E-12 -12.7534 0.94862E+00 -0.0229 21 AlOH+2 0.23452E-17 -17.6298 0.20034E-17 -17.6982 0.85424E+00 -0.0684 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.16177E-04 -4.7911 0.15343E-04 -4.8141 0.94845E+00 -0.0230 24 CH4,aq 0.49775E-19 -19.3030 0.49766E-19 -19.3031 0.99983E+00 -0.0001 29 CO,aq 0.61419E-18 -18.2117 0.61419E-18 -18.2117 0.10000E+01 0.0000 30 CO2,aq 0.53985E-07 -7.2677 0.53976E-07 -7.2678 0.99983E+00 -0.0001 31 CO3-2 0.56375E-06 -6.2489 0.48175E-06 -6.3172 0.85453E+00 -0.0683 32 CaCO3,aq 0.27113E-08 -8.5668 0.27113E-08 -8.5668 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.14416E-09 -9.8412 0.13675E-09 -9.8641 0.94862E+00 -0.0229 34 CaCl+ 0.10101E-09 -9.9956 0.95823E-10 -10.0185 0.94862E+00 -0.0229 35 CaCl2,aq 0.29196E-14 -14.5347 0.29196E-14 -14.5347 0.10000E+01 0.0000 36 CaOH+ 0.15069E-07 -7.8219 0.14295E-07 -7.8448 0.94862E+00 -0.0229 37 CaSO4,aq 0.31176E-08 -8.5062 0.31176E-08 -8.5062 0.10000E+01 0.0000 38 HCl,aq 0.55794E-13 -13.2534 0.55794E-13 -13.2534 0.10000E+01 0.0000 43 FeCl+ 0.23792E-14 -14.6236 0.22570E-14 -14.6465 0.94862E+00 -0.0229 46 FeO,aq 0.85226E-10 -10.0694 0.85226E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.17073E-09 -9.7677 0.16196E-09 -9.7906 0.94862E+00 -0.0229 48 HFeO2- 0.42635E-09 -9.3702 0.40441E-09 -9.3932 0.94853E+00 -0.0229 49 FeO+ 0.19766E-13 -13.7041 0.18751E-13 -13.7270 0.94862E+00 -0.0229 51 FeO2- 0.75617E-09 -9.1214 0.71725E-09 -9.1443 0.94853E+00 -0.0229 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44188E-09 -9.3547 0.44181E-09 -9.3548 0.99983E+00 -0.0001 54 KCl,aq 0.16279E-09 -9.7884 0.16279E-09 -9.7884 0.10000E+01 0.0000 55 KHSO4,aq 0.92796E-17 -17.0325 0.92796E-17 -17.0325 0.10000E+01 0.0000 56 KOH,aq 0.13512E-07 -7.8693 0.13512E-07 -7.8693 0.10000E+01 0.0000 57 KSO4- 0.24848E-07 -7.6047 0.23569E-07 -7.6277 0.94853E+00 -0.0229 58 MgCO3,aq 0.27602E-11 -11.5591 0.27602E-11 -11.5591 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.59888E-12 -12.2227 0.56812E-12 -12.2456 0.94862E+00 -0.0229 60 MgCl+ 0.37359E-12 -12.4276 0.35440E-12 -12.4505 0.94862E+00 -0.0229 61 MgOH+ 0.34011E-09 -9.4684 0.32264E-09 -9.4913 0.94862E+00 -0.0229 63 MnO,aq 0.30382E-09 -9.5174 0.30382E-09 -9.5174 0.10000E+01 0.0000 64 MnOH+ 0.21180E-08 -8.6741 0.20091E-08 -8.6970 0.94862E+00 -0.0229 65 MnO2-2 0.23931E-14 -14.6210 0.20449E-14 -14.6893 0.85453E+00 -0.0683 66 HMnO2- 0.10588E-11 -11.9752 0.10043E-11 -11.9981 0.94853E+00 -0.0229 69 MnCl+ 0.12346E-11 -11.9085 0.11712E-11 -11.9314 0.94862E+00 -0.0229 70 MnSO4,aq 0.91252E-11 -11.0398 0.91252E-11 -11.0398 0.10000E+01 0.0000 71 NaCl,aq 0.24179E-07 -7.6166 0.24179E-07 -7.6166 0.10000E+01 0.0000 72 NaOH,aq 0.10969E-06 -6.9598 0.10969E-06 -6.9598 0.10000E+01 0.0000 74 OH- 0.27901E-03 -3.5544 0.26463E-03 -3.5774 0.94845E+00 -0.0230 79 HPO3-2 0.17923E-18 -18.7466 0.15316E-18 -18.8149 0.85453E+00 -0.0683 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.45981E-08 -8.3374 0.43617E-08 -8.3603 0.94858E+00 -0.0229 84 PO4-3 0.58778E-10 -10.2308 0.42285E-10 -10.3738 0.71941E+00 -0.1430 87 H2P2O7-2 0.17424E-17 -17.7589 0.14889E-17 -17.8271 0.85453E+00 -0.0683 88 HP2O7-3 0.18768E-15 -15.7266 0.13469E-15 -15.8707 0.71765E+00 -0.1441 89 P2O7-4 0.26041E-16 -16.5843 0.14659E-16 -16.8339 0.56292E+00 -0.2496 90 H2S,aq 0.63692E-15 -15.1959 0.63682E-15 -15.1960 0.99983E+00 -0.0001 97 SO3-2 0.15339E-14 -14.8142 0.13117E-14 -14.8822 0.85516E+00 -0.0680 98 HSO3- 0.18344E-15 -15.7365 0.17400E-15 -15.7594 0.94853E+00 -0.0229 99 HSO4- 0.48274E-10 -10.3163 0.45796E-10 -10.3392 0.94867E+00 -0.0229 Charge balance for all species = 0.1075E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2389000E-08 -.5196819E-03 -.5237670E+00 0.0000 2 H2O 0.1000000E+01 0.5550839E+02 0.9999216E+06 0.0000 3 Cl- 0.1379601E-03 0.1379845E-03 0.4891580E+01 4.7614 4 SO4-- 0.2547836E-04 0.2550639E-04 0.2449992E+01 12.6271 5 HCO3- 0.1245038E-04 0.1307098E-04 0.7974918E+00 3.7169 6 HS- 0.9857736E-13 -.9386772E-11 -.3104149E-06 -4.3846 7 Al+++ 0.9785137E-23 0.1619299E-04 0.4368769E+00 2.7803 8 H4SiO4 0.3829605E-03 0.5582253E-03 0.5364983E+02 -3.4168 9 Ca++ 0.5378920E-06 0.5608244E-06 0.2247495E-01 10.9515 10 Mg++ 0.2191871E-08 0.2544788E-08 0.6186402E-04 8.5615 11 Fe++ 0.1296411E-10 0.1654934E-08 0.9241584E-04 6.3335 12 K+ 0.7406469E-04 0.7410321E-04 0.2897356E+01 4.4913 13 Na+ 0.5965804E-03 0.5981958E-03 0.1375132E+02 5.3973 14 Mn++ 0.1731143E-08 0.4164335E-08 0.2287622E-03 8.4591 15 HPO4-- 0.1284226E-06 0.1330795E-06 0.1277183E-01 10.3296 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5765882E-02 -.5196431E-03 -.5246239E-02 0.0000000E+00 2 H2O 0.5550388E+02 0.5550423E+02 -.3576681E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3517645E-04 0.2550448E-04 0.9671970E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9671980E-05 -.9386070E-11 -.9671970E-05 0.0000000E+00 7 Al+++ 0.1137999E-02 0.1619178E-04 0.1121807E-02 0.0000000E+00 8 H4SiO4 0.3634061E-02 0.5581835E-03 0.3075878E-02 0.0000000E+00 9 Ca++ 0.4158708E-03 0.5607824E-06 0.4153101E-03 0.0000000E+00 10 Mg++ 0.2769841E-03 0.2544598E-08 0.2769816E-03 0.0000000E+00 11 Fe++ 0.2488400E-03 0.1654810E-08 0.2488383E-03 0.0000000E+00 12 K+ 0.7409766E-04 0.7409766E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.5981510E-03 0.5981510E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6051170E-05 0.4164023E-08 0.6047006E-05 0.0000000E+00 15 HPO4-- 0.2065234E-05 0.1330695E-06 0.1932165E-05 0.0000000E+00 Chg. balance for solid moles: 0.9571E-18 Mass of aqueous solution: 0.100000E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.3490000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6441E-06 -6.191 0.3235E-03 -3.490 0.9176E-01 0.1028E-03 clinochlore 0.5540E-04 -4.257 0.3079E-01 -1.512 8.733 0.1171E-01 daphnite 0.3429E-04 -4.465 0.2447E-01 -1.611 6.940 0.7415E-02 chlorite-Mn 0.1209E-05 -5.917 0.8574E-03 -3.067 0.2432 0.2732E-03 hematite 0.3869E-04 -4.412 0.6178E-02 -2.209 1.752 0.1171E-02 kaolinite 0.5792E-04 -4.237 0.1495E-01 -1.825 4.241 0.5753E-02 lawsonite 0.3946E-04 -4.404 0.1240E-01 -1.907 3.517 0.3998E-02 stilbite 0.3726E-03 -3.429 0.2626 -0.581 74.48 0.1225 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.352571 g Volume = 0.152907 cm3 Porosity: 86.5824% V(tot) - V(min): 0.98669E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.3490000 g log = -0.4572 Original solution: 1000.0103000 g Original solution / Rock added: 2865.36 (Water/Rock Ratio), log = 3.4572 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.5831E-05 1.0073 0.6179E-05 0.6134E-05 CH4,gas 0.7386E-16 1.0129 0.7870E-16 0.7770E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.1773E-13 0.9959 0.1857E-13 0.1865E-13 S2,gas 0.3345E-34 1.0000 0.3519E-34 0.3519E-34 CO,gas 0.9219E-15 1.0000 0.9698E-15 0.9698E-15 SO3,gas 0.3976E-37 1.0000 0.4183E-37 0.4183E-37 SO2,gas 0.9115E-21 1.0000 0.9588E-21 0.9588E-21 HCl,gas 0.9365E-16 1.0000 0.9852E-16 0.9852E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.57 -7.21 -2.403 0.12309E+05 -5.209 3 CH4,gas 4.81 -13.29 -18.10 -4.526 0.30912E+05 -16.104 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.67 -15.73 -7.866 0.26860E+05 -13.731 6 S2,gas -7.03 -43.49 -36.45 -5.608 0.62244E+05 -34.454 7 CO,gas 3.51 -13.50 -17.01 -5.235 0.29050E+05 -15.013 8 SO3,gas 17.43 -21.95 -39.38 -9.845 0.67238E+05 -37.379 9 SO2,gas 1.14 -21.88 -23.02 -6.138 0.39303E+05 -21.018 10 HCl,gas 5.48 -12.53 -18.01 -9.003 0.30746E+05 -16.006 11 acmite 7.74 4.86 -2.87 -0.299 0.49089E+04 15 albite-high 0.75 -2.07 -2.82 -0.217 0.48195E+04 16 albite -0.33 -2.07 -1.74 -0.134 0.29788E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65953E+04 20 analcite 3.37 1.34 -2.03 -0.225 0.34606E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 16.02 -4.19 -0.233 0.71506E+04 27 phlogopite 27.15 22.71 -4.44 -0.247 0.75828E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.62 -3.61 -1.202 0.61589E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.62 -3.45 -1.151 0.58976E+04 38 carnegieite-low 9.06 4.76 -4.30 -0.615 0.73486E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.17 -3.23 -0.190 0.55233E+04 43 celadonite-Fe 3.94 -0.06 -4.00 -0.235 0.68286E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14691E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.98 -4.71 -0.392 0.80417E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.34 -2.91 -0.291 0.49636E+04 97 kalsilite 7.62 3.85 -3.77 -0.538 0.64295E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.44 -3.73 -0.373 0.63685E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -2.98 -0.55 -0.042 0.93427E+03 120 muscovite 2.68 2.58 -0.10 -0.006 0.16666E+03 121 paragonite 4.34 3.49 -0.85 -0.050 0.14497E+04 122 nepheline 8.38 4.76 -3.62 -0.517 0.61766E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40532E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.11 -4.15 -1.385 0.70940E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41324E+04 153 sanidine -1.22 -2.98 -1.76 -0.135 0.30020E+04 155 siderite -2.59 -7.24 -4.65 -1.550 0.79418E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.14 -1.04 -0.031 0.17766E+04 165 stilpnomelane-Mg 27.60 23.28 -4.32 -0.129 0.73714E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78741E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.58 -3.14 -0.193 0.53694E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.28 -3.02 -0.185 0.51628E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.72 -2.56 -0.157 0.43642E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.42 -2.46 -0.150 0.41957E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.46 -0.95 -0.061 0.16160E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.76 -0.83 -0.053 0.14111E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.28 -1.80 -0.139 0.30767E+04 243 an25ab75 2.71 0.86 -1.84 -0.142 0.31490E+04 244 an30ab70 3.34 1.45 -1.89 -0.146 0.32298E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.3490000 g New total amount of reactant added: 0.3590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1075E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.3590000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .5465043E-03 Osmotic coef. = 0.9862 True ionic strength = .7129886E-03 Chg. balance for total moles = 0.1075E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.23190E-08 -8.6347 0.21995E-08 -8.6577 0.94849E+00 -0.0230 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13081E-03 -3.8833 0.94820E+00 -0.0231 4 SO4-- 0.25478E-04 -4.5938 0.21744E-04 -4.6627 0.85344E+00 -0.0688 5 HCO3- 0.12435E-04 -4.9054 0.11792E-04 -4.9284 0.94827E+00 -0.0231 6 HS- 0.95554E-13 -13.0198 0.90605E-13 -13.0428 0.94821E+00 -0.0231 7 Al+++ 0.89684E-23 -23.0473 0.64160E-23 -23.1927 0.71540E+00 -0.1455 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.50718E-06 -6.2948 0.43269E-06 -6.3638 0.85313E+00 -0.0690 10 Mg++ 0.20667E-08 -8.6847 0.17628E-08 -8.7538 0.85293E+00 -0.0691 11 Fe++ 0.12224E-10 -10.9128 0.10427E-10 -10.9819 0.85298E+00 -0.0691 12 K+ 0.76187E-04 -4.1181 0.72247E-04 -4.1412 0.94828E+00 -0.0231 13 Na+ 0.60905E-03 -3.2153 0.57750E-03 -3.2384 0.94820E+00 -0.0231 14 Mn++ 0.16324E-08 -8.7872 0.13924E-08 -8.8562 0.85302E+00 -0.0690 15 HPO4-- 0.13658E-06 -6.8646 0.11656E-06 -6.9334 0.85345E+00 -0.0688 16 HSiO3- 0.17915E-03 -3.7468 0.16987E-03 -3.7699 0.94820E+00 -0.0231 17 Ca(HSiO3)+ 0.17366E-08 -8.7603 0.16468E-08 -8.7833 0.94829E+00 -0.0231 18 Mg(HSiO3)+ 0.88050E-11 -11.0553 0.83497E-11 -11.0783 0.94829E+00 -0.0231 19 NaHSiO3,aq 0.15581E-05 -5.8074 0.15581E-05 -5.8074 0.10000E+01 0.0000 20 AlO+ 0.18054E-12 -12.7434 0.17121E-12 -12.7665 0.94829E+00 -0.0231 21 AlOH+2 0.22113E-17 -17.6553 0.18864E-17 -17.7244 0.85306E+00 -0.0690 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.16677E-04 -4.7779 0.15812E-04 -4.8010 0.94811E+00 -0.0231 24 CH4,aq 0.48223E-19 -19.3167 0.48215E-19 -19.3168 0.99983E+00 -0.0001 29 CO,aq 0.59504E-18 -18.2255 0.59504E-18 -18.2255 0.10000E+01 0.0000 30 CO2,aq 0.52302E-07 -7.2815 0.52293E-07 -7.2816 0.99983E+00 -0.0001 31 CO3-2 0.58086E-06 -6.2359 0.49568E-06 -6.3048 0.85335E+00 -0.0689 32 CaCO3,aq 0.26268E-08 -8.5806 0.26268E-08 -8.5806 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.13557E-09 -9.8678 0.12856E-09 -9.8909 0.94829E+00 -0.0231 34 CaCl+ 0.95112E-10 -10.0218 0.90194E-10 -10.0448 0.94829E+00 -0.0231 35 CaCl2,aq 0.27472E-14 -14.5611 0.27472E-14 -14.5611 0.10000E+01 0.0000 36 CaOH+ 0.14627E-07 -7.8348 0.13871E-07 -7.8579 0.94829E+00 -0.0231 37 CaSO4,aq 0.29314E-08 -8.5329 0.29314E-08 -8.5329 0.10000E+01 0.0000 38 HCl,aq 0.54121E-13 -13.2666 0.54121E-13 -13.2666 0.10000E+01 0.0000 43 FeCl+ 0.22402E-14 -14.6497 0.21244E-14 -14.6728 0.94829E+00 -0.0231 46 FeO,aq 0.85226E-10 -10.0694 0.85226E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.16573E-09 -9.7806 0.15716E-09 -9.8037 0.94829E+00 -0.0231 48 HFeO2- 0.43953E-09 -9.3570 0.41676E-09 -9.3801 0.94820E+00 -0.0231 49 FeO+ 0.19187E-13 -13.7170 0.18195E-13 -13.7401 0.94829E+00 -0.0231 51 FeO2- 0.77954E-09 -9.1082 0.73916E-09 -9.1313 0.94820E+00 -0.0231 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44188E-09 -9.3547 0.44181E-09 -9.3548 0.99983E+00 -0.0001 54 KCl,aq 0.16734E-09 -9.7764 0.16734E-09 -9.7764 0.10000E+01 0.0000 55 KHSO4,aq 0.92463E-17 -17.0340 0.92463E-17 -17.0340 0.10000E+01 0.0000 56 KOH,aq 0.14319E-07 -7.8441 0.14319E-07 -7.8441 0.10000E+01 0.0000 57 KSO4- 0.25524E-07 -7.5930 0.24202E-07 -7.6161 0.94820E+00 -0.0231 58 MgCO3,aq 0.26741E-11 -11.5728 0.26741E-11 -11.5728 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.56321E-12 -12.2493 0.53409E-12 -12.2724 0.94829E+00 -0.0231 60 MgCl+ 0.35177E-12 -12.4537 0.33358E-12 -12.4768 0.94829E+00 -0.0231 61 MgOH+ 0.33015E-09 -9.4813 0.31308E-09 -9.5044 0.94829E+00 -0.0231 63 MnO,aq 0.30383E-09 -9.5174 0.30383E-09 -9.5174 0.10000E+01 0.0000 64 MnOH+ 0.20560E-08 -8.6870 0.19497E-08 -8.7100 0.94829E+00 -0.0231 65 MnO2-2 0.25451E-14 -14.5943 0.21719E-14 -14.6632 0.85335E+00 -0.0689 66 HMnO2- 0.10916E-11 -11.9619 0.10350E-11 -11.9850 0.94820E+00 -0.0231 69 MnCl+ 0.11625E-11 -11.9346 0.11024E-11 -11.9577 0.94829E+00 -0.0231 70 MnSO4,aq 0.85806E-11 -11.0665 0.85806E-11 -11.0665 0.10000E+01 0.0000 71 NaCl,aq 0.24667E-07 -7.6079 0.24667E-07 -7.6079 0.10000E+01 0.0000 72 NaOH,aq 0.11537E-06 -6.9379 0.11537E-06 -6.9379 0.10000E+01 0.0000 74 OH- 0.28763E-03 -3.5412 0.27271E-03 -3.5643 0.94811E+00 -0.0231 79 HPO3-2 0.19061E-18 -18.7198 0.16266E-18 -18.7887 0.85335E+00 -0.0689 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.47402E-08 -8.3242 0.44949E-08 -8.3473 0.94825E+00 -0.0231 84 PO4-3 0.64529E-10 -10.1902 0.46280E-10 -10.3346 0.71720E+00 -0.1444 87 H2P2O7-2 0.18530E-17 -17.7321 0.15813E-17 -17.8010 0.85335E+00 -0.0689 88 HP2O7-3 0.20606E-15 -15.6860 0.14742E-15 -15.8315 0.71542E+00 -0.1454 89 P2O7-4 0.29535E-16 -16.5297 0.16534E-16 -16.7816 0.55982E+00 -0.2520 90 H2S,aq 0.59888E-15 -15.2227 0.59878E-15 -15.2227 0.99983E+00 -0.0001 97 SO3-2 0.15338E-14 -14.8142 0.13099E-14 -14.8828 0.85398E+00 -0.0686 98 HSO3- 0.17782E-15 -15.7500 0.16861E-15 -15.7731 0.94820E+00 -0.0231 99 HSO4- 0.46794E-10 -10.3298 0.44376E-10 -10.3528 0.94834E+00 -0.0230 Charge balance for all species = 0.1074E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2318974E-08 -.5357796E-03 -.5399908E+00 0.0000 2 H2O 0.1000000E+01 0.5550839E+02 0.9999207E+06 0.0000 3 Cl- 0.1379598E-03 0.1379848E-03 0.4891585E+01 4.7743 4 SO4-- 0.2547792E-04 0.2550644E-04 0.2449994E+01 12.6527 5 HCO3- 0.1243507E-04 0.1307100E-04 0.7974926E+00 3.7293 6 HS- 0.9555394E-13 -.1231125E-10 -.4071253E-06 -4.3852 7 Al+++ 0.8968419E-23 0.1669306E-04 0.4503680E+00 2.7803 8 H4SiO4 0.3829605E-03 0.5636734E-03 0.5417338E+02 -3.4168 9 Ca++ 0.5071779E-06 0.5293309E-06 0.2121284E-01 10.9515 10 Mg++ 0.2066722E-08 0.2409261E-08 0.5856929E-04 8.5615 11 Fe++ 0.1222388E-10 0.1685740E-08 0.9413604E-04 6.3335 12 K+ 0.7618665E-04 0.7622666E-04 0.2980378E+01 4.5165 13 Na+ 0.6090522E-03 0.6107504E-03 0.1403991E+02 5.4192 14 Mn++ 0.1632369E-08 0.4003008E-08 0.2198998E-03 8.4591 15 HPO4-- 0.1365777E-06 0.1413825E-06 0.1356867E-01 10.3819 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5931467E-02 -.5357385E-03 -.5395729E-02 0.0000000E+00 2 H2O 0.5550375E+02 0.5550413E+02 -.3788783E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3545358E-04 0.2550448E-04 0.9949101E-05 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9949114E-05 -.1231031E-10 -.9949101E-05 0.0000000E+00 7 Al+++ 0.1170606E-02 0.1669178E-04 0.1153914E-02 0.0000000E+00 8 H4SiO4 0.3738189E-02 0.5636301E-03 0.3174559E-02 0.0000000E+00 9 Ca++ 0.4273723E-03 0.5292903E-06 0.4268430E-03 0.0000000E+00 10 Mg++ 0.2849206E-03 0.2409076E-08 0.2849182E-03 0.0000000E+00 11 Fe++ 0.2559701E-03 0.1685611E-08 0.2559684E-03 0.0000000E+00 12 K+ 0.7622081E-04 0.7622081E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.6107035E-03 0.6107035E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6224556E-05 0.4002701E-08 0.6220553E-05 0.0000000E+00 15 HPO4-- 0.2124410E-05 0.1413716E-06 0.1983038E-05 0.0000000E+00 Chg. balance for solid moles: 0.1309E-17 Mass of aqueous solution: 0.100000E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.3590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6610E-06 -6.180 0.3320E-03 -3.479 0.9135E-01 0.1055E-03 clinochlore 0.5698E-04 -4.244 0.3167E-01 -1.499 8.714 0.1205E-01 daphnite 0.3528E-04 -4.453 0.2517E-01 -1.599 6.925 0.7627E-02 chlorite-Mn 0.1244E-05 -5.905 0.8820E-03 -3.055 0.2427 0.2811E-03 hematite 0.3980E-04 -4.400 0.6355E-02 -2.197 1.749 0.1205E-02 kaolinite 0.5992E-04 -4.222 0.1547E-01 -1.811 4.256 0.5952E-02 lawsonite 0.3811E-04 -4.419 0.1198E-01 -1.922 3.295 0.3862E-02 stilbite 0.3854E-03 -3.414 0.2716 -0.566 74.73 0.1267 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.363475 g Volume = 0.157767 cm3 Porosity: 86.2043% V(tot) - V(min): 0.98583E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.3590000 g log = -0.4449 Original solution: 1000.0103000 g Original solution / Rock added: 2785.54 (Water/Rock Ratio), log = 3.4449 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.5649E-05 1.0073 0.5986E-05 0.5942E-05 CH4,gas 0.7156E-16 1.0129 0.7625E-16 0.7527E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.1667E-13 0.9959 0.1746E-13 0.1754E-13 S2,gas 0.2957E-34 1.0000 0.3111E-34 0.3111E-34 CO,gas 0.8932E-15 1.0000 0.9396E-15 0.9396E-15 SO3,gas 0.3739E-37 1.0000 0.3933E-37 0.3933E-37 SO2,gas 0.8570E-21 1.0000 0.9016E-21 0.9016E-21 HCl,gas 0.9084E-16 1.0000 0.9556E-16 0.9556E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.18198E-10 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.59 -7.22 -2.408 0.12333E+05 -5.223 3 CH4,gas 4.81 -13.31 -18.12 -4.529 0.30936E+05 -16.118 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.70 -15.76 -7.879 0.26906E+05 -13.758 6 S2,gas -7.03 -43.54 -36.51 -5.616 0.62335E+05 -34.507 7 CO,gas 3.51 -13.52 -17.03 -5.239 0.29073E+05 -15.027 8 SO3,gas 17.43 -21.98 -39.41 -9.851 0.67283E+05 -37.405 9 SO2,gas 1.14 -21.91 -23.05 -6.145 0.39349E+05 -21.045 10 HCl,gas 5.48 -12.54 -18.02 -9.010 0.30768E+05 -16.020 11 acmite 7.74 4.88 -2.85 -0.296 0.48715E+04 15 albite-high 0.75 -2.05 -2.80 -0.215 0.47821E+04 16 albite -0.33 -2.05 -1.72 -0.133 0.29414E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65952E+04 20 analcite 3.37 1.37 -2.00 -0.223 0.34232E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 16.05 -4.16 -0.231 0.71076E+04 27 phlogopite 27.15 22.73 -4.42 -0.245 0.75398E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.63 -3.62 -1.207 0.61824E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.63 -3.47 -1.156 0.59211E+04 38 carnegieite-low 9.06 4.78 -4.28 -0.612 0.73112E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.19 -3.21 -0.189 0.54803E+04 43 celadonite-Fe 3.94 -0.04 -3.97 -0.234 0.67856E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14691E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.95 -4.68 -0.390 0.79987E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.37 -2.89 -0.289 0.49262E+04 97 kalsilite 7.62 3.88 -3.74 -0.534 0.63865E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.46 -3.70 -0.370 0.63254E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -2.95 -0.52 -0.040 0.89127E+03 120 muscovite 2.68 2.61 -0.07 -0.004 0.12366E+03 121 paragonite 4.34 3.51 -0.83 -0.049 0.14123E+04 122 nepheline 8.38 4.78 -3.60 -0.514 0.61392E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40531E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.13 -4.17 -1.389 0.71175E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41324E+04 153 sanidine -1.22 -2.95 -1.73 -0.133 0.29590E+04 155 siderite -2.59 -7.25 -4.66 -1.555 0.79652E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.15 -1.03 -0.031 0.17551E+04 165 stilpnomelane-Mg 27.60 23.29 -4.30 -0.128 0.73499E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78740E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.57 -3.14 -0.192 0.53552E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.27 -3.02 -0.185 0.51504E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.71 -2.55 -0.156 0.43500E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.41 -2.45 -0.150 0.41834E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.47 -0.94 -0.060 0.16018E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.76 -0.82 -0.053 0.13987E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.29 -1.78 -0.137 0.30468E+04 243 an25ab75 2.71 0.88 -1.83 -0.141 0.31210E+04 244 an30ab70 3.34 1.47 -1.88 -0.144 0.32036E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.3590000 g New total amount of reactant added: 0.3690000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1075E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.3690000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .5560532E-03 Osmotic coef. = 0.9861 True ionic strength = .7275199E-03 Chg. balance for total moles = 0.1075E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.22530E-08 -8.6472 0.21362E-08 -8.6704 0.94817E+00 -0.0231 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13077E-03 -3.8835 0.94787E+00 -0.0232 4 SO4-- 0.25477E-04 -4.5938 0.21714E-04 -4.6633 0.85228E+00 -0.0694 5 HCO3- 0.12420E-04 -4.9059 0.11773E-04 -4.9291 0.94795E+00 -0.0232 6 HS- 0.92707E-13 -13.0329 0.87875E-13 -13.0561 0.94788E+00 -0.0232 7 Al+++ 0.82416E-23 -23.0840 0.58778E-23 -23.2308 0.71319E+00 -0.1468 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.47906E-06 -6.3196 0.40814E-06 -6.3892 0.85196E+00 -0.0696 10 Mg++ 0.19522E-08 -8.7095 0.16628E-08 -8.7792 0.85176E+00 -0.0697 11 Fe++ 0.11546E-10 -10.9376 0.98352E-11 -11.0072 0.85180E+00 -0.0697 12 K+ 0.78309E-04 -4.1062 0.74233E-04 -4.1294 0.94796E+00 -0.0232 13 Na+ 0.62152E-03 -3.2065 0.58912E-03 -3.2298 0.94787E+00 -0.0233 14 Mn++ 0.15419E-08 -8.8119 0.13135E-08 -8.8816 0.85184E+00 -0.0696 15 HPO4-- 0.14499E-06 -6.8387 0.12357E-06 -6.9081 0.85228E+00 -0.0694 16 HSiO3- 0.18453E-03 -3.7339 0.17491E-03 -3.7572 0.94787E+00 -0.0232 17 Ca(HSiO3)+ 0.16872E-08 -8.7728 0.15994E-08 -8.7960 0.94797E+00 -0.0232 18 Mg(HSiO3)+ 0.85545E-11 -11.0678 0.81094E-11 -11.0910 0.94797E+00 -0.0232 19 NaHSiO3,aq 0.16366E-05 -5.7861 0.16366E-05 -5.7861 0.10000E+01 0.0000 20 AlO+ 0.17540E-12 -12.7560 0.16628E-12 -12.7792 0.94797E+00 -0.0232 21 AlOH+2 0.20887E-17 -17.6801 0.17794E-17 -17.7497 0.85188E+00 -0.0696 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.17178E-04 -4.7650 0.16281E-04 -4.7883 0.94779E+00 -0.0233 24 CH4,aq 0.46761E-19 -19.3301 0.46753E-19 -19.3302 0.99983E+00 -0.0001 29 CO,aq 0.57700E-18 -18.2388 0.57700E-18 -18.2388 0.10000E+01 0.0000 30 CO2,aq 0.50717E-07 -7.2948 0.50708E-07 -7.2949 0.99983E+00 -0.0001 31 CO3-2 0.59795E-06 -6.2233 0.50956E-06 -6.2928 0.85218E+00 -0.0695 32 CaCO3,aq 0.25472E-08 -8.5939 0.25472E-08 -8.5939 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.12772E-09 -9.8937 0.12107E-09 -9.9169 0.94797E+00 -0.0232 34 CaCl+ 0.89716E-10 -10.0471 0.85048E-10 -10.0703 0.94797E+00 -0.0232 35 CaCl2,aq 0.25895E-14 -14.5868 0.25895E-14 -14.5868 0.10000E+01 0.0000 36 CaOH+ 0.14211E-07 -7.8474 0.13472E-07 -7.8706 0.94797E+00 -0.0232 37 CaSO4,aq 0.27613E-08 -8.5589 0.27613E-08 -8.5589 0.10000E+01 0.0000 38 HCl,aq 0.52545E-13 -13.2795 0.52545E-13 -13.2795 0.10000E+01 0.0000 43 FeCl+ 0.21131E-14 -14.6751 0.20032E-14 -14.6983 0.94797E+00 -0.0232 46 FeO,aq 0.85225E-10 -10.0694 0.85225E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.16101E-09 -9.7931 0.15263E-09 -9.8163 0.94797E+00 -0.0232 48 HFeO2- 0.45271E-09 -9.3442 0.42911E-09 -9.3674 0.94787E+00 -0.0232 49 FeO+ 0.18641E-13 -13.7295 0.17671E-13 -13.7527 0.94797E+00 -0.0232 51 FeO2- 0.80292E-09 -9.0953 0.76107E-09 -9.1186 0.94787E+00 -0.0232 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44189E-09 -9.3547 0.44181E-09 -9.3548 0.99983E+00 -0.0001 54 KCl,aq 0.17188E-09 -9.7648 0.17188E-09 -9.7648 0.10000E+01 0.0000 55 KHSO4,aq 0.92144E-17 -17.0355 0.92144E-17 -17.0355 0.10000E+01 0.0000 56 KOH,aq 0.15149E-07 -7.8196 0.15149E-07 -7.8196 0.10000E+01 0.0000 57 KSO4- 0.26199E-07 -7.5817 0.24833E-07 -7.6050 0.94787E+00 -0.0232 58 MgCO3,aq 0.25930E-11 -11.5862 0.25930E-11 -11.5862 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.53060E-12 -12.2752 0.50299E-12 -12.2984 0.94797E+00 -0.0232 60 MgCl+ 0.33181E-12 -12.4791 0.31455E-12 -12.5023 0.94797E+00 -0.0232 61 MgOH+ 0.32075E-09 -9.4938 0.30406E-09 -9.5170 0.94797E+00 -0.0232 63 MnO,aq 0.30384E-09 -9.5174 0.30384E-09 -9.5174 0.10000E+01 0.0000 64 MnOH+ 0.19976E-08 -8.6995 0.18936E-08 -8.7227 0.94797E+00 -0.0232 65 MnO2-2 0.27020E-14 -14.5683 0.23026E-14 -14.6378 0.85218E+00 -0.0695 66 HMnO2- 0.11243E-11 -11.9491 0.10657E-11 -11.9723 0.94787E+00 -0.0232 69 MnCl+ 0.10966E-11 -11.9599 0.10396E-11 -11.9832 0.94797E+00 -0.0232 70 MnSO4,aq 0.80829E-11 -11.0924 0.80829E-11 -11.0924 0.10000E+01 0.0000 71 NaCl,aq 0.25155E-07 -7.5994 0.25155E-07 -7.5994 0.10000E+01 0.0000 72 NaOH,aq 0.12118E-06 -6.9166 0.12118E-06 -6.9166 0.10000E+01 0.0000 74 OH- 0.29626E-03 -3.5283 0.28079E-03 -3.5516 0.94779E+00 -0.0233 79 HPO3-2 0.20235E-18 -18.6939 0.17244E-18 -18.7634 0.85218E+00 -0.0695 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.48824E-08 -8.3114 0.46281E-08 -8.3346 0.94792E+00 -0.0232 84 PO4-3 0.70652E-10 -10.1509 0.50518E-10 -10.2966 0.71502E+00 -0.1457 87 H2P2O7-2 0.19672E-17 -17.7062 0.16764E-17 -17.7756 0.85218E+00 -0.0695 88 HP2O7-3 0.22562E-15 -15.6466 0.16091E-15 -15.7934 0.71321E+00 -0.1468 89 P2O7-4 0.33376E-16 -16.4766 0.18583E-16 -16.7309 0.55677E+00 -0.2543 90 H2S,aq 0.56412E-15 -15.2486 0.56402E-15 -15.2487 0.99983E+00 -0.0001 97 SO3-2 0.15338E-14 -14.8142 0.13081E-14 -14.8834 0.85283E+00 -0.0691 98 HSO3- 0.17252E-15 -15.7632 0.16353E-15 -15.7864 0.94787E+00 -0.0232 99 HSO4- 0.45400E-10 -10.3429 0.43040E-10 -10.3661 0.94802E+00 -0.0232 Charge balance for all species = 0.1075E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2252997E-08 -.5518825E-03 -.5562197E+00 0.0000 2 H2O 0.1000000E+01 0.5550839E+02 0.9999198E+06 0.0000 3 Cl- 0.1379596E-03 0.1379850E-03 0.4891590E+01 4.7869 4 SO4-- 0.2547746E-04 0.2550649E-04 0.2449997E+01 12.6774 5 HCO3- 0.1241968E-04 0.1307103E-04 0.7974933E+00 3.7412 6 HS- 0.9270674E-13 -.1523613E-10 -.5038487E-06 -4.3858 7 Al+++ 0.8241570E-23 0.1719323E-04 0.4638618E+00 2.7803 8 H4SiO4 0.3829605E-03 0.5691244E-03 0.5469722E+02 -3.4168 9 Ca++ 0.4790623E-06 0.5004869E-06 0.2005690E-01 10.9515 10 Mg++ 0.1952160E-08 0.2284924E-08 0.5554660E-04 8.5615 11 Fe++ 0.1154628E-10 0.1716906E-08 0.9587631E-04 6.3335 12 K+ 0.7830860E-04 0.7835012E-04 0.3063399E+01 4.5410 13 Na+ 0.6215221E-03 0.6233050E-03 0.1432850E+02 5.4406 14 Mn++ 0.1541944E-08 0.3853657E-08 0.2116952E-03 8.4591 15 HPO4-- 0.1449903E-06 0.1499434E-06 0.1439026E-01 10.4326 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6097052E-02 -.5518391E-03 -.5545213E-02 0.0000000E+00 2 H2O 0.5550362E+02 0.5550402E+02 -.4000880E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3573072E-04 0.2550449E-04 0.1022623E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1022625E-04 -.1523493E-10 -.1022623E-04 0.0000000E+00 7 Al+++ 0.1203214E-02 0.1719188E-04 0.1186022E-02 0.0000000E+00 8 H4SiO4 0.3842317E-02 0.5690796E-03 0.3273237E-02 0.0000000E+00 9 Ca++ 0.4388737E-03 0.5004475E-06 0.4383733E-03 0.0000000E+00 10 Mg++ 0.2928571E-03 0.2284744E-08 0.2928549E-03 0.0000000E+00 11 Fe++ 0.2631002E-03 0.1716771E-08 0.2630985E-03 0.0000000E+00 12 K+ 0.7834395E-04 0.7834395E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.6232559E-03 0.6232559E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6397942E-05 0.3853354E-08 0.6394089E-05 0.0000000E+00 15 HPO4-- 0.2183586E-05 0.1499316E-06 0.2033654E-05 0.0000000E+00 Chg. balance for solid moles: -.6387E-18 Mass of aqueous solution: 0.100000E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.3690000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6779E-06 -6.169 0.3405E-03 -3.468 0.9096E-01 0.1082E-03 clinochlore 0.5857E-04 -4.232 0.3256E-01 -1.487 8.696 0.1238E-01 daphnite 0.3626E-04 -4.441 0.2587E-01 -1.587 6.910 0.7839E-02 chlorite-Mn 0.1279E-05 -5.893 0.9066E-03 -3.043 0.2422 0.2889E-03 hematite 0.4090E-04 -4.388 0.6533E-02 -2.185 1.745 0.1238E-02 kaolinite 0.6192E-04 -4.208 0.1599E-01 -1.796 4.270 0.6151E-02 lawsonite 0.3676E-04 -4.435 0.1155E-01 -1.937 3.086 0.3725E-02 stilbite 0.3982E-03 -3.400 0.2806 -0.552 74.96 0.1309 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.374377 g Volume = 0.162627 cm3 Porosity: 85.8290% V(tot) - V(min): 0.98497E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.3690000 g log = -0.4330 Original solution: 1000.0103000 g Original solution / Rock added: 2710.06 (Water/Rock Ratio), log = 3.4330 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.5478E-05 1.0073 0.5804E-05 0.5762E-05 CH4,gas 0.6939E-16 1.0129 0.7393E-16 0.7299E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.1570E-13 0.9959 0.1645E-13 0.1652E-13 S2,gas 0.2624E-34 1.0000 0.2760E-34 0.2760E-34 CO,gas 0.8661E-15 1.0000 0.9111E-15 0.9111E-15 SO3,gas 0.3522E-37 1.0000 0.3705E-37 0.3705E-37 SO2,gas 0.8073E-21 1.0000 0.8492E-21 0.8492E-21 HCl,gas 0.8820E-16 1.0000 0.9278E-16 0.9278E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.60662E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.00000E+00 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.60 -7.24 -2.412 0.12356E+05 -5.236 3 CH4,gas 4.81 -13.32 -18.13 -4.533 0.30958E+05 -16.131 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.73 -15.78 -7.892 0.26950E+05 -13.784 6 S2,gas -7.03 -43.59 -36.56 -5.624 0.62424E+05 -34.559 7 CO,gas 3.51 -13.53 -17.04 -5.243 0.29096E+05 -15.040 8 SO3,gas 17.43 -22.00 -39.43 -9.858 0.67328E+05 -37.431 9 SO2,gas 1.14 -21.93 -23.07 -6.152 0.39393E+05 -21.071 10 HCl,gas 5.48 -12.55 -18.03 -9.016 0.30790E+05 -16.033 11 acmite 7.74 4.91 -2.83 -0.294 0.48351E+04 15 albite-high 0.75 -2.03 -2.78 -0.214 0.47457E+04 16 albite -0.33 -2.03 -1.70 -0.131 0.29050E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65951E+04 20 analcite 3.37 1.39 -1.98 -0.220 0.33868E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 16.07 -4.14 -0.230 0.70658E+04 27 phlogopite 27.15 22.76 -4.39 -0.244 0.74980E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.65 -3.63 -1.211 0.62052E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.65 -3.48 -1.160 0.59439E+04 38 carnegieite-low 9.06 4.80 -4.26 -0.609 0.72748E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.22 -3.19 -0.187 0.54385E+04 43 celadonite-Fe 3.94 -0.01 -3.95 -0.232 0.67438E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14691E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.93 -4.66 -0.388 0.79570E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.39 -2.86 -0.286 0.48898E+04 97 kalsilite 7.62 3.90 -3.72 -0.531 0.63448E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.49 -3.68 -0.368 0.62837E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -2.93 -0.50 -0.038 0.84950E+03 120 muscovite 2.68 2.63 -0.05 -0.003 0.81884E+02 121 paragonite 4.34 3.53 -0.81 -0.047 0.13759E+04 122 nepheline 8.38 4.80 -3.57 -0.511 0.61027E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40531E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.14 -4.18 -1.394 0.71403E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41323E+04 153 sanidine -1.22 -2.93 -1.71 -0.131 0.29172E+04 155 siderite -2.59 -7.27 -4.68 -1.559 0.79881E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.16 -1.02 -0.030 0.17342E+04 165 stilpnomelane-Mg 27.60 23.30 -4.29 -0.128 0.73290E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78740E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.56 -3.13 -0.192 0.53414E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.27 -3.01 -0.184 0.51384E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.70 -2.54 -0.156 0.43362E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.40 -2.44 -0.150 0.41714E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.47 -0.93 -0.060 0.15880E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.77 -0.81 -0.052 0.13867E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.31 -1.77 -0.136 0.30176E+04 243 an25ab75 2.71 0.90 -1.81 -0.139 0.30937E+04 244 an30ab70 3.34 1.48 -1.86 -0.143 0.31781E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.3690000 g New total amount of reactant added: 0.3790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1075E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.3790000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .5656079E-03 Osmotic coef. = 0.9860 True ionic strength = .7420565E-03 Chg. balance for total moles = 0.1075E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.21907E-08 -8.6594 0.20765E-08 -8.6827 0.94785E+00 -0.0233 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13072E-03 -3.8836 0.94755E+00 -0.0234 4 SO4-- 0.25477E-04 -4.5939 0.21684E-04 -4.6639 0.85112E+00 -0.0700 5 HCO3- 0.12404E-04 -4.9064 0.11755E-04 -4.9298 0.94762E+00 -0.0234 6 HS- 0.90021E-13 -13.0457 0.85300E-13 -13.0691 0.94756E+00 -0.0234 7 Al+++ 0.75925E-23 -23.1196 0.53984E-23 -23.2677 0.71101E+00 -0.1481 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.45326E-06 -6.3437 0.38563E-06 -6.4138 0.85080E+00 -0.0702 10 Mg++ 0.18470E-08 -8.7335 0.15711E-08 -8.8038 0.85059E+00 -0.0703 11 Fe++ 0.10924E-10 -10.9616 0.92928E-11 -11.0319 0.85064E+00 -0.0703 12 K+ 0.80431E-04 -4.0946 0.76219E-04 -4.1179 0.94764E+00 -0.0234 13 Na+ 0.63399E-03 -3.1979 0.60073E-03 -3.2213 0.94754E+00 -0.0234 14 Mn++ 0.14590E-08 -8.8360 0.12411E-08 -8.9062 0.85068E+00 -0.0702 15 HPO4-- 0.15366E-06 -6.8134 0.13079E-06 -6.8834 0.85113E+00 -0.0700 16 HSiO3- 0.18990E-03 -3.7215 0.17994E-03 -3.7449 0.94755E+00 -0.0234 17 Ca(HSiO3)+ 0.16406E-08 -8.7850 0.15547E-08 -8.8083 0.94765E+00 -0.0234 18 Mg(HSiO3)+ 0.83181E-11 -11.0800 0.78826E-11 -11.1033 0.94765E+00 -0.0234 19 NaHSiO3,aq 0.17168E-05 -5.7653 0.17168E-05 -5.7653 0.10000E+01 0.0000 20 AlO+ 0.17056E-12 -12.7681 0.16163E-12 -12.7915 0.94765E+00 -0.0234 21 AlOH+2 0.19762E-17 -17.7042 0.16812E-17 -17.7744 0.85072E+00 -0.0702 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.17678E-04 -4.7526 0.16749E-04 -4.7760 0.94746E+00 -0.0234 24 CH4,aq 0.45381E-19 -19.3431 0.45373E-19 -19.3432 0.99982E+00 -0.0001 29 CO,aq 0.55998E-18 -18.2518 0.55998E-18 -18.2518 0.10000E+01 0.0000 30 CO2,aq 0.49220E-07 -7.3079 0.49212E-07 -7.3079 0.99982E+00 -0.0001 31 CO3-2 0.61501E-06 -6.2111 0.52339E-06 -6.2812 0.85103E+00 -0.0701 32 CaCO3,aq 0.24720E-08 -8.6069 0.24720E-08 -8.6069 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.12053E-09 -9.9189 0.11422E-09 -9.9423 0.94765E+00 -0.0234 34 CaCl+ 0.84768E-10 -10.0718 0.80330E-10 -10.0951 0.94765E+00 -0.0234 35 CaCl2,aq 0.24450E-14 -14.6117 0.24450E-14 -14.6117 0.10000E+01 0.0000 36 CaOH+ 0.13819E-07 -7.8595 0.13095E-07 -7.8829 0.94765E+00 -0.0234 37 CaSO4,aq 0.26054E-08 -8.5841 0.26054E-08 -8.5841 0.10000E+01 0.0000 38 HCl,aq 0.51058E-13 -13.2919 0.51058E-13 -13.2919 0.10000E+01 0.0000 43 FeCl+ 0.19966E-14 -14.6997 0.18920E-14 -14.7231 0.94765E+00 -0.0234 46 FeO,aq 0.85225E-10 -10.0694 0.85225E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.15656E-09 -9.8053 0.14837E-09 -9.8287 0.94765E+00 -0.0234 48 HFeO2- 0.46589E-09 -9.3317 0.44146E-09 -9.3551 0.94755E+00 -0.0234 49 FeO+ 0.18126E-13 -13.7417 0.17177E-13 -13.7651 0.94765E+00 -0.0234 51 FeO2- 0.82630E-09 -9.0829 0.78296E-09 -9.1063 0.94755E+00 -0.0234 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44189E-09 -9.3547 0.44181E-09 -9.3548 0.99982E+00 -0.0001 54 KCl,aq 0.17642E-09 -9.7535 0.17642E-09 -9.7535 0.10000E+01 0.0000 55 KHSO4,aq 0.91836E-17 -17.0370 0.91836E-17 -17.0370 0.10000E+01 0.0000 56 KOH,aq 0.16002E-07 -7.7958 0.16002E-07 -7.7958 0.10000E+01 0.0000 57 KSO4- 0.26872E-07 -7.5707 0.25463E-07 -7.5941 0.94755E+00 -0.0234 58 MgCO3,aq 0.25165E-11 -11.5992 0.25165E-11 -11.5992 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.50071E-12 -12.3004 0.47450E-12 -12.3238 0.94765E+00 -0.0234 60 MgCl+ 0.31351E-12 -12.5037 0.29710E-12 -12.5271 0.94765E+00 -0.0234 61 MgOH+ 0.31189E-09 -9.5060 0.29556E-09 -9.5294 0.94765E+00 -0.0234 63 MnO,aq 0.30385E-09 -9.5173 0.30385E-09 -9.5173 0.10000E+01 0.0000 64 MnOH+ 0.19424E-08 -8.7117 0.18407E-08 -8.7350 0.94765E+00 -0.0234 65 MnO2-2 0.28637E-14 -14.5431 0.24371E-14 -14.6131 0.85103E+00 -0.0701 66 HMnO2- 0.11571E-11 -11.9366 0.10964E-11 -11.9600 0.94755E+00 -0.0234 69 MnCl+ 0.10362E-11 -11.9846 0.98192E-12 -12.0079 0.94765E+00 -0.0234 70 MnSO4,aq 0.76269E-11 -11.1176 0.76269E-11 -11.1176 0.10000E+01 0.0000 71 NaCl,aq 0.25642E-07 -7.5910 0.25642E-07 -7.5910 0.10000E+01 0.0000 72 NaOH,aq 0.12712E-06 -6.8958 0.12712E-06 -6.8958 0.10000E+01 0.0000 74 OH- 0.30489E-03 -3.5159 0.28887E-03 -3.5393 0.94746E+00 -0.0234 79 HPO3-2 0.21445E-18 -18.6687 0.18251E-18 -18.7387 0.85103E+00 -0.0701 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.50246E-08 -8.2989 0.47613E-08 -8.3223 0.94760E+00 -0.0234 84 PO4-3 0.77159E-10 -10.1126 0.55005E-10 -10.2596 0.71287E+00 -0.1470 87 H2P2O7-2 0.20848E-17 -17.6809 0.17742E-17 -17.7510 0.85103E+00 -0.0701 88 HP2O7-3 0.24641E-15 -15.6083 0.17521E-15 -15.7565 0.71103E+00 -0.1481 89 P2O7-4 0.37589E-16 -16.4249 0.20815E-16 -16.6816 0.55376E+00 -0.2567 90 H2S,aq 0.53228E-15 -15.2739 0.53218E-15 -15.2739 0.99982E+00 -0.0001 97 SO3-2 0.15337E-14 -14.8143 0.13063E-14 -14.8840 0.85168E+00 -0.0697 98 HSO3- 0.16752E-15 -15.7759 0.15874E-15 -15.7993 0.94755E+00 -0.0234 99 HSO4- 0.44084E-10 -10.3557 0.41779E-10 -10.3790 0.94769E+00 -0.0233 Charge balance for all species = 0.1075E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2190728E-08 -.5679900E-03 -.5724532E+00 0.0000 2 H2O 0.1000000E+01 0.5550840E+02 0.9999189E+06 0.0000 3 Cl- 0.1379594E-03 0.1379853E-03 0.4891594E+01 4.7990 4 SO4-- 0.2547700E-04 0.2550655E-04 0.2450000E+01 12.7015 5 HCO3- 0.1240423E-04 0.1307105E-04 0.7974941E+00 3.7529 6 HS- 0.9002092E-13 -.1816131E-10 -.6005819E-06 -4.3864 7 Al+++ 0.7592493E-23 0.1769349E-04 0.4773579E+00 2.7803 8 H4SiO4 0.3829605E-03 0.5745782E-03 0.5522131E+02 -3.4168 9 Ca++ 0.4532597E-06 0.4740017E-06 0.1899549E-01 10.9515 10 Mg++ 0.1847023E-08 0.2170562E-08 0.5276640E-04 8.5615 11 Fe++ 0.1092442E-10 0.1748398E-08 0.9763483E-04 6.3335 12 K+ 0.8043053E-04 0.8047358E-04 0.3146422E+01 4.5647 13 Na+ 0.6339901E-03 0.6358596E-03 0.1461709E+02 5.4614 14 Mn++ 0.1458950E-08 0.3715060E-08 0.2040813E-03 8.4591 15 HPO4-- 0.1536606E-06 0.1587624E-06 0.1523661E-01 10.4819 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6262637E-02 -.5679442E-03 -.5694693E-02 0.0000000E+00 2 H2O 0.5550350E+02 0.5550392E+02 -.4212972E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3600785E-04 0.2550449E-04 0.1050336E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1050338E-04 -.1815985E-10 -.1050336E-04 0.0000000E+00 7 Al+++ 0.1235821E-02 0.1769206E-04 0.1218129E-02 0.0000000E+00 8 H4SiO4 0.3946445E-02 0.5745318E-03 0.3371913E-02 0.0000000E+00 9 Ca++ 0.4503751E-03 0.4739635E-06 0.4499012E-03 0.0000000E+00 10 Mg++ 0.3007937E-03 0.2170387E-08 0.3007915E-03 0.0000000E+00 11 Fe++ 0.2702303E-03 0.1748257E-08 0.2702285E-03 0.0000000E+00 12 K+ 0.8046709E-04 0.8046709E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.6358083E-03 0.6358083E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6571328E-05 0.3714760E-08 0.6567613E-05 0.0000000E+00 15 HPO4-- 0.2242762E-05 0.1587495E-06 0.2084012E-05 0.0000000E+00 Chg. balance for solid moles: -.1228E-18 Mass of aqueous solution: 0.100000E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.3790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6947E-06 -6.158 0.3489E-03 -3.457 0.9057E-01 0.1109E-03 clinochlore 0.6016E-04 -4.221 0.3344E-01 -1.476 8.679 0.1272E-01 daphnite 0.3724E-04 -4.429 0.2657E-01 -1.576 6.897 0.8052E-02 chlorite-Mn 0.1314E-05 -5.882 0.9312E-03 -3.031 0.2417 0.2968E-03 hematite 0.4201E-04 -4.377 0.6710E-02 -2.173 1.741 0.1272E-02 kaolinite 0.6392E-04 -4.194 0.1650E-01 -1.782 4.283 0.6350E-02 lawsonite 0.3541E-04 -4.451 0.1113E-01 -1.954 2.888 0.3589E-02 stilbite 0.4110E-03 -3.386 0.2897 -0.538 75.18 0.1351 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.385280 g Volume = 0.167486 cm3 Porosity: 85.4562% V(tot) - V(min): 0.98411E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.3790000 g log = -0.4214 Original solution: 1000.0103000 g Original solution / Rock added: 2638.55 (Water/Rock Ratio), log = 3.4214 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.5316E-05 1.0073 0.5633E-05 0.5592E-05 CH4,gas 0.6734E-16 1.0129 0.7175E-16 0.7084E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.1482E-13 0.9959 0.1552E-13 0.1559E-13 S2,gas 0.2336E-34 1.0000 0.2457E-34 0.2457E-34 CO,gas 0.8406E-15 1.0000 0.8842E-15 0.8842E-15 SO3,gas 0.3323E-37 1.0000 0.3495E-37 0.3495E-37 SO2,gas 0.7617E-21 1.0000 0.8013E-21 0.8013E-21 HCl,gas 0.8570E-16 1.0000 0.9015E-16 0.9015E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.61 -7.25 -2.416 0.12378E+05 -5.249 3 CH4,gas 4.81 -13.33 -18.14 -4.536 0.30981E+05 -16.144 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.75 -15.81 -7.905 0.26994E+05 -13.809 6 S2,gas -7.03 -43.64 -36.61 -5.632 0.62510E+05 -34.610 7 CO,gas 3.51 -13.54 -17.05 -5.247 0.29118E+05 -15.053 8 SO3,gas 17.43 -22.03 -39.46 -9.864 0.67371E+05 -37.456 9 SO2,gas 1.14 -21.96 -23.10 -6.159 0.39436E+05 -21.096 10 HCl,gas 5.48 -12.57 -18.05 -9.023 0.30811E+05 -16.045 11 acmite 7.74 4.93 -2.81 -0.292 0.47996E+04 15 albite-high 0.75 -2.01 -2.76 -0.212 0.47101E+04 16 albite -0.33 -2.01 -1.68 -0.129 0.28695E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65950E+04 20 analcite 3.37 1.41 -1.96 -0.218 0.33513E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 16.09 -4.11 -0.229 0.70252E+04 27 phlogopite 27.15 22.78 -4.37 -0.243 0.74574E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.66 -3.65 -1.216 0.62274E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.66 -3.49 -1.165 0.59661E+04 38 carnegieite-low 9.06 4.82 -4.24 -0.606 0.72393E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.24 -3.16 -0.186 0.53979E+04 43 celadonite-Fe 3.94 0.01 -3.93 -0.231 0.67032E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14690E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.91 -4.64 -0.386 0.79164E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.41 -2.84 -0.284 0.48543E+04 97 kalsilite 7.62 3.93 -3.69 -0.527 0.63041E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.51 -3.66 -0.366 0.62431E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -2.91 -0.47 -0.036 0.80889E+03 120 muscovite 2.68 2.66 -0.02 -0.001 0.41277E+02 121 paragonite 4.34 3.55 -0.78 -0.046 0.13403E+04 122 nepheline 8.38 4.82 -3.55 -0.508 0.60672E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40531E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.15 -4.19 -1.398 0.71625E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41323E+04 153 sanidine -1.22 -2.91 -1.68 -0.130 0.28766E+04 155 siderite -2.59 -7.28 -4.69 -1.564 0.80103E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.18 -1.00 -0.030 0.17139E+04 165 stilpnomelane-Mg 27.60 23.32 -4.28 -0.128 0.73087E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78739E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.56 -3.12 -0.191 0.53280E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.26 -3.00 -0.184 0.51267E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.69 -2.53 -0.155 0.43228E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.40 -2.44 -0.149 0.41597E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.48 -0.92 -0.059 0.15746E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.78 -0.81 -0.052 0.13750E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.33 -1.75 -0.135 0.29892E+04 243 an25ab75 2.71 0.91 -1.80 -0.138 0.30670E+04 244 an30ab70 3.34 1.50 -1.85 -0.142 0.31532E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.3790000 g New total amount of reactant added: 0.3890000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1075E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.3890000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .5751676E-03 Osmotic coef. = 0.9859 True ionic strength = .7565977E-03 Chg. balance for total moles = 0.1075E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.21319E-08 -8.6712 0.20200E-08 -8.6946 0.94754E+00 -0.0234 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.13068E-03 -3.8838 0.94723E+00 -0.0235 4 SO4-- 0.25477E-04 -4.5939 0.21655E-04 -4.6644 0.84999E+00 -0.0706 5 HCO3- 0.12389E-04 -4.9070 0.11736E-04 -4.9305 0.94730E+00 -0.0235 6 HS- 0.87483E-13 -13.0581 0.82867E-13 -13.0816 0.94724E+00 -0.0235 7 Al+++ 0.70110E-23 -23.1542 0.49699E-23 -23.3037 0.70886E+00 -0.1494 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.42952E-06 -6.3670 0.36495E-06 -6.4378 0.84965E+00 -0.0708 10 Mg++ 0.17503E-08 -8.7569 0.14868E-08 -8.8278 0.84945E+00 -0.0709 11 Fe++ 0.10352E-10 -10.9850 0.87943E-11 -11.0558 0.84950E+00 -0.0708 12 K+ 0.82552E-04 -4.0833 0.78203E-04 -4.1068 0.94732E+00 -0.0235 13 Na+ 0.64646E-03 -3.1895 0.61234E-03 -3.2130 0.94722E+00 -0.0235 14 Mn++ 0.13826E-08 -8.8593 0.11746E-08 -8.9301 0.84953E+00 -0.0708 15 HPO4-- 0.16259E-06 -6.7889 0.13820E-06 -6.8595 0.84999E+00 -0.0706 16 HSiO3- 0.19527E-03 -3.7094 0.18497E-03 -3.7329 0.94723E+00 -0.0235 17 Ca(HSiO3)+ 0.15965E-08 -8.7968 0.15124E-08 -8.8203 0.94733E+00 -0.0235 18 Mg(HSiO3)+ 0.80946E-11 -11.0918 0.76683E-11 -11.1153 0.94733E+00 -0.0235 19 NaHSiO3,aq 0.17989E-05 -5.7450 0.17989E-05 -5.7450 0.10000E+01 0.0000 20 AlO+ 0.16597E-12 -12.7800 0.15723E-12 -12.8035 0.94733E+00 -0.0235 21 AlOH+2 0.18728E-17 -17.7275 0.15911E-17 -17.7983 0.84958E+00 -0.0708 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.18178E-04 -4.7404 0.17217E-04 -4.7640 0.94714E+00 -0.0236 24 CH4,aq 0.44077E-19 -19.3558 0.44069E-19 -19.3559 0.99982E+00 -0.0001 29 CO,aq 0.54388E-18 -18.2645 0.54388E-18 -18.2645 0.10000E+01 0.0000 30 CO2,aq 0.47806E-07 -7.3205 0.47798E-07 -7.3206 0.99982E+00 -0.0001 31 CO3-2 0.63205E-06 -6.1993 0.53717E-06 -6.2699 0.84989E+00 -0.0706 32 CaCO3,aq 0.24010E-08 -8.6196 0.24010E-08 -8.6196 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.11392E-09 -9.9434 0.10792E-09 -9.9669 0.94733E+00 -0.0235 34 CaCl+ 0.80220E-10 -10.0957 0.75995E-10 -10.1192 0.94733E+00 -0.0235 35 CaCl2,aq 0.23123E-14 -14.6360 0.23123E-14 -14.6360 0.10000E+01 0.0000 36 CaOH+ 0.13447E-07 -7.8714 0.12739E-07 -7.8949 0.94733E+00 -0.0235 37 CaSO4,aq 0.24623E-08 -8.6087 0.24623E-08 -8.6087 0.10000E+01 0.0000 38 HCl,aq 0.49653E-13 -13.3041 0.49653E-13 -13.3041 0.10000E+01 0.0000 43 FeCl+ 0.18895E-14 -14.7237 0.17899E-14 -14.7472 0.94733E+00 -0.0235 46 FeO,aq 0.85225E-10 -10.0694 0.85225E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.15236E-09 -9.8171 0.14433E-09 -9.8406 0.94733E+00 -0.0235 48 HFeO2- 0.47908E-09 -9.3196 0.45380E-09 -9.3431 0.94723E+00 -0.0235 49 FeO+ 0.17639E-13 -13.7535 0.16710E-13 -13.7770 0.94733E+00 -0.0235 51 FeO2- 0.84969E-09 -9.0707 0.80485E-09 -9.0943 0.94723E+00 -0.0235 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44189E-09 -9.3547 0.44181E-09 -9.3548 0.99982E+00 -0.0001 54 KCl,aq 0.18095E-09 -9.7424 0.18095E-09 -9.7424 0.10000E+01 0.0000 55 KHSO4,aq 0.91541E-17 -17.0384 0.91541E-17 -17.0384 0.10000E+01 0.0000 56 KOH,aq 0.16877E-07 -7.7727 0.16877E-07 -7.7727 0.10000E+01 0.0000 57 KSO4- 0.27544E-07 -7.5600 0.26090E-07 -7.5835 0.94723E+00 -0.0235 58 MgCO3,aq 0.24442E-11 -11.6119 0.24442E-11 -11.6119 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.47326E-12 -12.3249 0.44833E-12 -12.3484 0.94733E+00 -0.0235 60 MgCl+ 0.29669E-12 -12.5277 0.28106E-12 -12.5512 0.94733E+00 -0.0235 61 MgOH+ 0.30351E-09 -9.5178 0.28752E-09 -9.5413 0.94733E+00 -0.0235 63 MnO,aq 0.30386E-09 -9.5173 0.30386E-09 -9.5173 0.10000E+01 0.0000 64 MnOH+ 0.18903E-08 -8.7235 0.17907E-08 -8.7470 0.94733E+00 -0.0235 65 MnO2-2 0.30302E-14 -14.5185 0.25753E-14 -14.5892 0.84989E+00 -0.0706 66 HMnO2- 0.11899E-11 -11.9245 0.11271E-11 -11.9480 0.94723E+00 -0.0235 69 MnCl+ 0.98061E-12 -12.0085 0.92896E-12 -12.0320 0.94733E+00 -0.0235 70 MnSO4,aq 0.72082E-11 -11.1422 0.72082E-11 -11.1422 0.10000E+01 0.0000 71 NaCl,aq 0.26129E-07 -7.5829 0.26129E-07 -7.5829 0.10000E+01 0.0000 72 NaOH,aq 0.13320E-06 -6.8755 0.13320E-06 -6.8755 0.10000E+01 0.0000 74 OH- 0.31352E-03 -3.5037 0.29694E-03 -3.5273 0.94714E+00 -0.0236 79 HPO3-2 0.22692E-18 -18.6441 0.19285E-18 -18.7148 0.84989E+00 -0.0706 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.51667E-08 -8.2868 0.48943E-08 -8.3103 0.94728E+00 -0.0235 84 PO4-3 0.84062E-10 -10.0754 0.59747E-10 -10.2237 0.71075E+00 -0.1483 87 H2P2O7-2 0.22059E-17 -17.6564 0.18748E-17 -17.7270 0.84989E+00 -0.0706 88 HP2O7-3 0.26847E-15 -15.5711 0.19031E-15 -15.7205 0.70888E+00 -0.1494 89 P2O7-4 0.42197E-16 -16.3747 0.23242E-16 -16.6337 0.55081E+00 -0.2590 90 H2S,aq 0.50304E-15 -15.2984 0.50295E-15 -15.2985 0.99982E+00 -0.0001 97 SO3-2 0.15337E-14 -14.8143 0.13045E-14 -14.8846 0.85056E+00 -0.0703 98 HSO3- 0.16280E-15 -15.7883 0.15421E-15 -15.8119 0.94723E+00 -0.0235 99 HSO4- 0.42842E-10 -10.3681 0.40587E-10 -10.3916 0.94738E+00 -0.0235 Charge balance for all species = 0.1075E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2131865E-08 -.5841014E-03 -.5886906E+00 0.0000 2 H2O 0.1000000E+01 0.5550840E+02 0.9999180E+06 0.0000 3 Cl- 0.1379592E-03 0.1379856E-03 0.4891599E+01 4.8108 4 SO4-- 0.2547652E-04 0.2550660E-04 0.2450003E+01 12.7248 5 HCO3- 0.1238871E-04 0.1307108E-04 0.7974949E+00 3.7642 6 HS- 0.8748327E-13 -.2108670E-10 -.6973219E-06 -4.3870 7 Al+++ 0.7010997E-23 0.1819381E-04 0.4908558E+00 2.7803 8 H4SiO4 0.3829605E-03 0.5800344E-03 0.5574564E+02 -3.4168 9 Ca++ 0.4295224E-06 0.4496238E-06 0.1801854E-01 10.9515 10 Mg++ 0.1750302E-08 0.2065121E-08 0.5020309E-04 8.5615 11 Fe++ 0.1035233E-10 0.1780188E-08 0.9940998E-04 6.3335 12 K+ 0.8255246E-04 0.8259706E-04 0.3229444E+01 4.5879 13 Na+ 0.6464561E-03 0.6484144E-03 0.1490569E+02 5.4816 14 Mn++ 0.1382594E-08 0.3586150E-08 0.1969997E-03 8.4592 15 HPO4-- 0.1625887E-06 0.1678396E-06 0.1610774E-01 10.5298 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6428222E-02 -.5840532E-03 -.5844169E-02 0.0000000E+00 2 H2O 0.5550337E+02 0.5550382E+02 -.4425058E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3628499E-04 0.2550449E-04 0.1078049E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1078052E-04 -.2108496E-10 -.1078049E-04 0.0000000E+00 7 Al+++ 0.1268428E-02 0.1819231E-04 0.1250236E-02 0.0000000E+00 8 H4SiO4 0.4050573E-02 0.5799865E-03 0.3470586E-02 0.0000000E+00 9 Ca++ 0.4618766E-03 0.4495867E-06 0.4614270E-03 0.0000000E+00 10 Mg++ 0.3087302E-03 0.2064951E-08 0.3087281E-03 0.0000000E+00 11 Fe++ 0.2773603E-03 0.1780041E-08 0.2773586E-03 0.0000000E+00 12 K+ 0.8259023E-04 0.8259023E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.6483608E-03 0.6483608E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6744714E-05 0.3585854E-08 0.6741128E-05 0.0000000E+00 15 HPO4-- 0.2301937E-05 0.1678257E-06 0.2134112E-05 0.0000000E+00 Chg. balance for solid moles: -.1660E-18 Mass of aqueous solution: 0.100000E+04 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.3890000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7114E-06 -6.148 0.3573E-03 -3.447 0.9019E-01 0.1135E-03 clinochlore 0.6175E-04 -4.209 0.3432E-01 -1.464 8.663 0.1305E-01 daphnite 0.3822E-04 -4.418 0.2727E-01 -1.564 6.884 0.8264E-02 chlorite-Mn 0.1348E-05 -5.870 0.9559E-03 -3.020 0.2413 0.3046E-03 hematite 0.4312E-04 -4.365 0.6887E-02 -2.162 1.738 0.1305E-02 kaolinite 0.6593E-04 -4.181 0.1702E-01 -1.769 4.296 0.6549E-02 lawsonite 0.3406E-04 -4.468 0.1070E-01 -1.970 2.702 0.3452E-02 stilbite 0.4238E-03 -3.373 0.2987 -0.525 75.39 0.1393 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.396182 g Volume = 0.172346 cm3 Porosity: 85.0860% V(tot) - V(min): 0.98325E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.3890000 g log = -0.4101 Original solution: 1000.0103000 g Original solution / Rock added: 2570.72 (Water/Rock Ratio), log = 3.4101 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.5163E-05 1.0073 0.5471E-05 0.5432E-05 CH4,gas 0.6540E-16 1.0129 0.6969E-16 0.6880E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.1400E-13 0.9959 0.1467E-13 0.1473E-13 S2,gas 0.2086E-34 1.0000 0.2195E-34 0.2195E-34 CO,gas 0.8164E-15 1.0000 0.8588E-15 0.8588E-15 SO3,gas 0.3140E-37 1.0000 0.3303E-37 0.3303E-37 SO2,gas 0.7199E-21 1.0000 0.7573E-21 0.7573E-21 HCl,gas 0.8334E-16 1.0000 0.8767E-16 0.8767E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.63 -7.26 -2.421 0.12400E+05 -5.262 3 CH4,gas 4.81 -13.35 -18.16 -4.539 0.31002E+05 -16.157 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.78 -15.83 -7.917 0.27035E+05 -13.834 6 S2,gas -7.03 -43.69 -36.66 -5.640 0.62594E+05 -34.659 7 CO,gas 3.51 -13.56 -17.07 -5.251 0.29140E+05 -15.066 8 SO3,gas 17.43 -22.05 -39.48 -9.870 0.67413E+05 -37.481 9 SO2,gas 1.14 -21.98 -23.12 -6.166 0.39478E+05 -21.121 10 HCl,gas 5.48 -12.58 -18.06 -9.029 0.30832E+05 -16.057 11 acmite 7.74 4.95 -2.79 -0.290 0.47649E+04 15 albite-high 0.75 -1.99 -2.74 -0.211 0.46755E+04 16 albite -0.33 -1.99 -1.66 -0.128 0.28349E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65949E+04 20 analcite 3.37 1.43 -1.94 -0.216 0.33166E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 16.12 -4.09 -0.227 0.69857E+04 27 phlogopite 27.15 22.80 -4.34 -0.241 0.74179E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.67 -3.66 -1.220 0.62491E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.67 -3.51 -1.169 0.59877E+04 38 carnegieite-low 9.06 4.85 -4.22 -0.603 0.72047E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.26 -3.14 -0.185 0.53584E+04 43 celadonite-Fe 3.94 0.03 -3.90 -0.230 0.66637E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14690E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.88 -4.61 -0.384 0.78769E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.43 -2.82 -0.282 0.48197E+04 97 kalsilite 7.62 3.95 -3.67 -0.524 0.62646E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.53 -3.63 -0.363 0.62036E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -2.88 -0.45 -0.035 0.76939E+03 120 muscovite 2.68 2.68 0.00 0.000 0.17733E+01 121 paragonite 4.34 3.57 -0.76 -0.045 0.13057E+04 122 nepheline 8.38 4.85 -3.53 -0.505 0.60326E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40531E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.17 -4.21 -1.402 0.71841E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41323E+04 153 sanidine -1.22 -2.88 -1.66 -0.128 0.28371E+04 155 siderite -2.59 -7.29 -4.70 -1.568 0.80319E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.19 -0.99 -0.030 0.16942E+04 165 stilpnomelane-Mg 27.60 23.33 -4.27 -0.127 0.72890E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78739E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.55 -3.11 -0.191 0.53150E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.25 -3.00 -0.183 0.51153E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.69 -2.52 -0.155 0.43097E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.39 -2.43 -0.149 0.41482E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.49 -0.91 -0.059 0.15615E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.78 -0.80 -0.051 0.13636E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.34 -1.73 -0.133 0.29615E+04 243 an25ab75 2.71 0.93 -1.78 -0.137 0.30411E+04 244 an30ab70 3.34 1.51 -1.83 -0.141 0.31290E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.3890000 g New total amount of reactant added: 0.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.1075E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.3990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .5847319E-03 Osmotic coef. = 0.9858 True ionic strength = .7711429E-03 Chg. balance for total moles = 0.1075E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.20761E-08 -8.6827 0.19666E-08 -8.7063 0.94723E+00 -0.0235 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.13064E-03 -3.8839 0.94691E+00 -0.0237 4 SO4-- 0.25476E-04 -4.5939 0.21626E-04 -4.6650 0.84886E+00 -0.0712 5 HCO3- 0.12373E-04 -4.9075 0.11717E-04 -4.9312 0.94699E+00 -0.0237 6 HS- 0.85082E-13 -13.0702 0.80566E-13 -13.0938 0.94692E+00 -0.0237 7 Al+++ 0.64885E-23 -23.1879 0.45857E-23 -23.3386 0.70674E+00 -0.1507 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.40764E-06 -6.3897 0.34589E-06 -6.4611 0.84852E+00 -0.0713 10 Mg++ 0.16611E-08 -8.7796 0.14091E-08 -8.8510 0.84831E+00 -0.0714 11 Fe++ 0.98248E-11 -11.0077 0.83350E-11 -11.0791 0.84836E+00 -0.0714 12 K+ 0.84674E-04 -4.0722 0.80187E-04 -4.0959 0.94700E+00 -0.0236 13 Na+ 0.65892E-03 -3.1812 0.62394E-03 -3.2049 0.94691E+00 -0.0237 14 Mn++ 0.13122E-08 -8.8820 0.11133E-08 -8.9534 0.84840E+00 -0.0714 15 HPO4-- 0.17177E-06 -6.7650 0.14581E-06 -6.8362 0.84887E+00 -0.0712 16 HSiO3- 0.20065E-03 -3.6976 0.19000E-03 -3.7213 0.94691E+00 -0.0237 17 Ca(HSiO3)+ 0.15548E-08 -8.8083 0.14724E-08 -8.8320 0.94701E+00 -0.0236 18 Mg(HSiO3)+ 0.78831E-11 -11.1033 0.74654E-11 -11.1269 0.94701E+00 -0.0236 19 NaHSiO3,aq 0.18828E-05 -5.7252 0.18828E-05 -5.7252 0.10000E+01 0.0000 20 AlO+ 0.16164E-12 -12.7915 0.15307E-12 -12.8151 0.94701E+00 -0.0236 21 AlOH+2 0.17773E-17 -17.7502 0.15080E-17 -17.8216 0.84844E+00 -0.0714 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.18679E-04 -4.7287 0.17685E-04 -4.7524 0.94682E+00 -0.0237 24 CH4,aq 0.42842E-19 -19.3681 0.42834E-19 -19.3682 0.99982E+00 -0.0001 29 CO,aq 0.52865E-18 -18.2768 0.52865E-18 -18.2768 0.10000E+01 0.0000 30 CO2,aq 0.46467E-07 -7.3329 0.46459E-07 -7.3329 0.99982E+00 -0.0001 31 CO3-2 0.64906E-06 -6.1877 0.55089E-06 -6.2589 0.84876E+00 -0.0712 32 CaCO3,aq 0.23337E-08 -8.6319 0.23337E-08 -8.6319 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10783E-09 -9.9672 0.10212E-09 -9.9909 0.94701E+00 -0.0236 34 CaCl+ 0.76031E-10 -10.1190 0.72002E-10 -10.1427 0.94701E+00 -0.0236 35 CaCl2,aq 0.21901E-14 -14.6595 0.21901E-14 -14.6595 0.10000E+01 0.0000 36 CaOH+ 0.13096E-07 -7.8829 0.12402E-07 -7.9065 0.94701E+00 -0.0236 37 CaSO4,aq 0.23306E-08 -8.6325 0.23306E-08 -8.6325 0.10000E+01 0.0000 38 HCl,aq 0.48323E-13 -13.3158 0.48323E-13 -13.3158 0.10000E+01 0.0000 43 FeCl+ 0.17908E-14 -14.7470 0.16959E-14 -14.7706 0.94701E+00 -0.0236 46 FeO,aq 0.85225E-10 -10.0694 0.85225E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.14837E-09 -9.8286 0.14051E-09 -9.8523 0.94701E+00 -0.0236 48 HFeO2- 0.49227E-09 -9.3078 0.46613E-09 -9.3315 0.94691E+00 -0.0237 49 FeO+ 0.17178E-13 -13.7650 0.16268E-13 -13.7887 0.94701E+00 -0.0236 51 FeO2- 0.87307E-09 -9.0589 0.82672E-09 -9.0826 0.94691E+00 -0.0237 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44189E-09 -9.3547 0.44181E-09 -9.3548 0.99982E+00 -0.0001 54 KCl,aq 0.18548E-09 -9.7317 0.18548E-09 -9.7317 0.10000E+01 0.0000 55 KHSO4,aq 0.91256E-17 -17.0397 0.91256E-17 -17.0397 0.10000E+01 0.0000 56 KOH,aq 0.17776E-07 -7.7502 0.17776E-07 -7.7502 0.10000E+01 0.0000 57 KSO4- 0.28214E-07 -7.5495 0.26716E-07 -7.5732 0.94691E+00 -0.0237 58 MgCO3,aq 0.23758E-11 -11.6242 0.23758E-11 -11.6242 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.44798E-12 -12.3487 0.42424E-12 -12.3724 0.94701E+00 -0.0236 60 MgCl+ 0.28120E-12 -12.5510 0.26630E-12 -12.5746 0.94701E+00 -0.0236 61 MgOH+ 0.29558E-09 -9.5293 0.27992E-09 -9.5530 0.94701E+00 -0.0236 63 MnO,aq 0.30387E-09 -9.5173 0.30387E-09 -9.5173 0.10000E+01 0.0000 64 MnOH+ 0.18410E-08 -8.7350 0.17434E-08 -8.7586 0.94701E+00 -0.0236 65 MnO2-2 0.32015E-14 -14.4946 0.27173E-14 -14.5659 0.84876E+00 -0.0712 66 HMnO2- 0.12227E-11 -11.9127 0.11578E-11 -11.9364 0.94691E+00 -0.0237 69 MnCl+ 0.92943E-12 -12.0318 0.88018E-12 -12.0554 0.94701E+00 -0.0236 70 MnSO4,aq 0.68228E-11 -11.1660 0.68228E-11 -11.1660 0.10000E+01 0.0000 71 NaCl,aq 0.26614E-07 -7.5749 0.26614E-07 -7.5749 0.10000E+01 0.0000 72 NaOH,aq 0.13941E-06 -6.8557 0.13941E-06 -6.8557 0.10000E+01 0.0000 74 OH- 0.32215E-03 -3.4919 0.30502E-03 -3.5157 0.94682E+00 -0.0237 79 HPO3-2 0.23974E-18 -18.6203 0.20348E-18 -18.6915 0.84876E+00 -0.0712 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.53089E-08 -8.2750 0.50274E-08 -8.2987 0.94696E+00 -0.0237 84 PO4-3 0.91373E-10 -10.0392 0.64753E-10 -10.1887 0.70866E+00 -0.1496 87 H2P2O7-2 0.23306E-17 -17.6325 0.19781E-17 -17.7038 0.84876E+00 -0.0712 88 HP2O7-3 0.29183E-15 -15.5349 0.20626E-15 -15.6856 0.70676E+00 -0.1507 89 P2O7-4 0.47224E-16 -16.3258 0.25874E-16 -16.5871 0.54789E+00 -0.2613 90 H2S,aq 0.47613E-15 -15.3223 0.47604E-15 -15.3224 0.99982E+00 -0.0001 97 SO3-2 0.15336E-14 -14.8143 0.13027E-14 -14.8851 0.84944E+00 -0.0709 98 HSO3- 0.15833E-15 -15.8004 0.14993E-15 -15.8241 0.94691E+00 -0.0237 99 HSO4- 0.41666E-10 -10.3802 0.39460E-10 -10.4038 0.94706E+00 -0.0236 Charge balance for all species = 0.1075E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2076136E-08 -.6002164E-03 -.6049316E+00 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9999172E+06 0.0000 3 Cl- 0.1379590E-03 0.1379859E-03 0.4891604E+01 4.8224 4 SO4-- 0.2547603E-04 0.2550665E-04 0.2450005E+01 12.7475 5 HCO3- 0.1237314E-04 0.1307111E-04 0.7974957E+00 3.7751 6 HS- 0.8508195E-13 -.2401224E-10 -.7940664E-06 -4.3876 7 Al+++ 0.6488456E-23 0.1869418E-04 0.5043550E+00 2.7803 8 H4SiO4 0.3829605E-03 0.5854930E-03 0.5627020E+02 -3.4168 9 Ca++ 0.4076351E-06 0.4271341E-06 0.1711725E-01 10.9515 10 Mg++ 0.1661118E-08 0.1967684E-08 0.4783434E-04 8.5615 11 Fe++ 0.9824832E-11 0.1812251E-08 0.1012003E-03 6.3335 12 K+ 0.8467437E-04 0.8472054E-04 0.3312466E+01 4.6104 13 Na+ 0.6589203E-03 0.6609691E-03 0.1519428E+02 5.5014 14 Mn++ 0.1312183E-08 0.3465994E-08 0.1903989E-03 8.4592 15 HPO4-- 0.1717748E-06 0.1771752E-06 0.1700368E-01 10.5764 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6593808E-02 -.6001656E-03 -.5993642E-02 0.0000000E+00 2 H2O 0.5550325E+02 0.5550371E+02 -.4637137E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3656212E-04 0.2550449E-04 0.1105763E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1105765E-04 -.2401020E-10 -.1105763E-04 0.0000000E+00 7 Al+++ 0.1301036E-02 0.1869260E-04 0.1282343E-02 0.0000000E+00 8 H4SiO4 0.4154700E-02 0.5854435E-03 0.3569257E-02 0.0000000E+00 9 Ca++ 0.4733780E-03 0.4270979E-06 0.4729509E-03 0.0000000E+00 10 Mg++ 0.3166667E-03 0.1967518E-08 0.3166647E-03 0.0000000E+00 11 Fe++ 0.2844904E-03 0.1812098E-08 0.2844886E-03 0.0000000E+00 12 K+ 0.8471338E-04 0.8471338E-04 0.0000000E+00 0.0000000E+00 13 Na+ 0.6609132E-03 0.6609132E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6918100E-05 0.3465701E-08 0.6914634E-05 0.0000000E+00 15 HPO4-- 0.2361113E-05 0.1771602E-06 0.2183953E-05 0.0000000E+00 Chg. balance for solid moles: 0.3058E-18 Mass of aqueous solution: 0.999999E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7280E-06 -6.138 0.3657E-03 -3.437 0.8983E-01 0.1162E-03 clinochlore 0.6333E-04 -4.198 0.3520E-01 -1.453 8.647 0.1339E-01 daphnite 0.3921E-04 -4.407 0.2797E-01 -1.553 6.872 0.8477E-02 chlorite-Mn 0.1383E-05 -5.859 0.9805E-03 -3.009 0.2408 0.3124E-03 hematite 0.4423E-04 -4.354 0.7064E-02 -2.151 1.735 0.1339E-02 kaolinite 0.6794E-04 -4.168 0.1754E-01 -1.756 4.308 0.6748E-02 lawsonite 0.3271E-04 -4.485 0.1028E-01 -1.988 2.525 0.3315E-02 stilbite 0.4366E-03 -3.360 0.3077 -0.512 75.58 0.1435 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.407084 g Volume = 0.177205 cm3 Porosity: 84.7184% V(tot) - V(min): 0.98240E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.3990000 g log = -0.3990 Original solution: 1000.0103000 g Original solution / Rock added: 2506.29 (Water/Rock Ratio), log = 3.3990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.5019E-05 1.0073 0.5318E-05 0.5279E-05 CH4,gas 0.6357E-16 1.0129 0.6774E-16 0.6687E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.1325E-13 0.9959 0.1388E-13 0.1394E-13 S2,gas 0.1869E-34 1.0000 0.1966E-34 0.1966E-34 CO,gas 0.7935E-15 1.0000 0.8347E-15 0.8347E-15 SO3,gas 0.2972E-37 1.0000 0.3127E-37 0.3127E-37 SO2,gas 0.6814E-21 1.0000 0.7168E-21 0.7168E-21 HCl,gas 0.8111E-16 1.0000 0.8532E-16 0.8532E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 120 muscovite 2.68 2.70 0.02 0.001 -0.36686E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.64 -7.27 -2.425 0.12421E+05 -5.274 3 CH4,gas 4.81 -13.36 -18.17 -4.542 0.31023E+05 -16.169 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.80 -15.86 -7.929 0.27076E+05 -13.857 6 S2,gas -7.03 -43.74 -36.71 -5.647 0.62675E+05 -34.706 7 CO,gas 3.51 -13.57 -17.08 -5.255 0.29161E+05 -15.078 8 SO3,gas 17.43 -22.08 -39.50 -9.876 0.67454E+05 -37.505 9 SO2,gas 1.14 -22.01 -23.14 -6.172 0.39519E+05 -21.145 10 HCl,gas 5.48 -12.59 -18.07 -9.034 0.30852E+05 -16.069 11 acmite 7.74 4.97 -2.77 -0.288 0.47311E+04 15 albite-high 0.75 -1.97 -2.72 -0.209 0.46417E+04 16 albite -0.33 -1.97 -1.64 -0.126 0.28011E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65949E+04 20 analcite 3.37 1.45 -1.92 -0.214 0.32828E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 16.14 -4.07 -0.226 0.69473E+04 27 phlogopite 27.15 22.82 -4.32 -0.240 0.73795E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.69 -3.67 -1.224 0.62701E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.69 -3.52 -1.173 0.60088E+04 38 carnegieite-low 9.06 4.86 -4.20 -0.600 0.71709E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.28 -3.12 -0.183 0.53199E+04 43 celadonite-Fe 3.94 0.06 -3.88 -0.228 0.66253E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14690E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.86 -4.59 -0.383 0.78384E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.45 -2.80 -0.280 0.47859E+04 97 kalsilite 7.62 3.97 -3.65 -0.521 0.62262E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.56 -3.61 -0.361 0.61651E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -2.86 -0.43 -0.033 0.73093E+03 121 paragonite 4.34 3.59 -0.74 -0.044 0.12719E+04 122 nepheline 8.38 4.86 -3.51 -0.502 0.59988E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40530E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.18 -4.22 -1.407 0.72051E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41323E+04 153 sanidine -1.22 -2.86 -1.64 -0.126 0.27987E+04 155 siderite -2.59 -7.30 -4.72 -1.572 0.80530E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.20 -0.98 -0.029 0.16749E+04 165 stilpnomelane-Mg 27.60 23.34 -4.26 -0.127 0.72698E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78738E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.54 -3.11 -0.190 0.53023E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.25 -2.99 -0.183 0.51041E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.68 -2.52 -0.154 0.42970E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.38 -2.42 -0.148 0.41371E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.50 -0.91 -0.058 0.15489E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.79 -0.79 -0.051 0.13524E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.36 -1.72 -0.132 0.29345E+04 243 an25ab75 2.71 0.94 -1.77 -0.136 0.30157E+04 244 an30ab70 3.34 1.53 -1.82 -0.140 0.31053E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.3990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .5824025E-03 Osmotic coef. = 0.9858 True ionic strength = .7675960E-03 Chg. balance for total moles = 0.1075E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.20895E-08 -8.6800 0.19793E-08 -8.7035 0.94730E+00 -0.0235 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.13065E-03 -3.8839 0.94699E+00 -0.0237 4 SO4-- 0.25477E-04 -4.5938 0.21633E-04 -4.6649 0.84913E+00 -0.0710 5 HCO3- 0.12377E-04 -4.9074 0.11722E-04 -4.9310 0.94707E+00 -0.0236 6 HS- 0.85659E-13 -13.0672 0.81119E-13 -13.0909 0.94700E+00 -0.0237 7 Al+++ 0.66109E-23 -23.1797 0.46756E-23 -23.3302 0.70726E+00 -0.1504 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.41281E-06 -6.3842 0.35040E-06 -6.4554 0.84880E+00 -0.0712 10 Mg++ 0.16822E-08 -8.7741 0.14275E-08 -8.8454 0.84859E+00 -0.0713 11 Fe++ 0.99497E-11 -11.0022 0.84437E-11 -11.0735 0.84864E+00 -0.0713 12 K+ 0.81104E-04 -4.0910 0.76812E-04 -4.1146 0.94708E+00 -0.0236 13 Na+ 0.65893E-03 -3.1812 0.62400E-03 -3.2048 0.94698E+00 -0.0237 14 Mn++ 0.13289E-08 -8.8765 0.11278E-08 -8.9478 0.84867E+00 -0.0713 15 HPO4-- 0.16951E-06 -6.7708 0.14394E-06 -6.8418 0.84914E+00 -0.0710 16 HSiO3- 0.19934E-03 -3.7004 0.18877E-03 -3.7241 0.94699E+00 -0.0237 17 Ca(HSiO3)+ 0.15648E-08 -8.8055 0.14820E-08 -8.8292 0.94709E+00 -0.0236 18 Mg(HSiO3)+ 0.79336E-11 -11.1005 0.75139E-11 -11.1241 0.94709E+00 -0.0236 19 NaHSiO3,aq 0.18708E-05 -5.7280 0.18708E-05 -5.7280 0.10000E+01 0.0000 20 AlO+ 0.16267E-12 -12.7887 0.15407E-12 -12.8123 0.94709E+00 -0.0236 21 AlOH+2 0.17999E-17 -17.7447 0.15276E-17 -17.8160 0.84872E+00 -0.0712 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.18557E-04 -4.7315 0.17571E-04 -4.7552 0.94690E+00 -0.0237 24 CH4,aq 0.43137E-19 -19.3651 0.43129E-19 -19.3652 0.99982E+00 -0.0001 29 CO,aq 0.53229E-18 -18.2739 0.53229E-18 -18.2739 0.10000E+01 0.0000 30 CO2,aq 0.46787E-07 -7.3299 0.46779E-07 -7.3300 0.99982E+00 -0.0001 31 CO3-2 0.64491E-06 -6.1905 0.54755E-06 -6.2616 0.84903E+00 -0.0711 32 CaCO3,aq 0.23498E-08 -8.6290 0.23498E-08 -8.6290 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10927E-09 -9.9615 0.10349E-09 -9.9851 0.94709E+00 -0.0236 34 CaCl+ 0.77022E-10 -10.1134 0.72947E-10 -10.1370 0.94709E+00 -0.0236 35 CaCl2,aq 0.22190E-14 -14.6538 0.22190E-14 -14.6538 0.10000E+01 0.0000 36 CaOH+ 0.13180E-07 -7.8801 0.12483E-07 -7.9037 0.94709E+00 -0.0236 37 CaSO4,aq 0.23618E-08 -8.6267 0.23618E-08 -8.6267 0.10000E+01 0.0000 38 HCl,aq 0.48641E-13 -13.3130 0.48641E-13 -13.3130 0.10000E+01 0.0000 43 FeCl+ 0.18141E-14 -14.7413 0.17181E-14 -14.7649 0.94709E+00 -0.0236 46 FeO,aq 0.85225E-10 -10.0694 0.85225E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.14933E-09 -9.8259 0.14142E-09 -9.8495 0.94709E+00 -0.0236 48 HFeO2- 0.48905E-09 -9.3106 0.46312E-09 -9.3343 0.94699E+00 -0.0237 49 FeO+ 0.17288E-13 -13.7623 0.16373E-13 -13.7859 0.94709E+00 -0.0236 51 FeO2- 0.86737E-09 -9.0618 0.82139E-09 -9.0855 0.94699E+00 -0.0237 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44189E-09 -9.3547 0.44181E-09 -9.3548 0.99982E+00 -0.0001 54 KCl,aq 0.17769E-09 -9.7503 0.17769E-09 -9.7503 0.10000E+01 0.0000 55 KHSO4,aq 0.88016E-17 -17.0554 0.88016E-17 -17.0554 0.10000E+01 0.0000 56 KOH,aq 0.16918E-07 -7.7717 0.16918E-07 -7.7717 0.10000E+01 0.0000 57 KSO4- 0.27034E-07 -7.5681 0.25601E-07 -7.5917 0.94699E+00 -0.0237 58 MgCO3,aq 0.23921E-11 -11.6212 0.23921E-11 -11.6212 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.45396E-12 -12.3430 0.42994E-12 -12.3666 0.94709E+00 -0.0236 60 MgCl+ 0.28486E-12 -12.5454 0.26979E-12 -12.5690 0.94709E+00 -0.0236 61 MgOH+ 0.29747E-09 -9.5266 0.28173E-09 -9.5502 0.94709E+00 -0.0236 63 MnO,aq 0.30387E-09 -9.5173 0.30387E-09 -9.5173 0.10000E+01 0.0000 64 MnOH+ 0.18528E-08 -8.7322 0.17547E-08 -8.7558 0.94709E+00 -0.0236 65 MnO2-2 0.31593E-14 -14.5004 0.26823E-14 -14.5715 0.84903E+00 -0.0711 66 HMnO2- 0.12147E-11 -11.9155 0.11503E-11 -11.9392 0.94699E+00 -0.0237 69 MnCl+ 0.94154E-12 -12.0262 0.89172E-12 -12.0498 0.94709E+00 -0.0236 70 MnSO4,aq 0.69143E-11 -11.1603 0.69143E-11 -11.1603 0.10000E+01 0.0000 71 NaCl,aq 0.26619E-07 -7.5748 0.26619E-07 -7.5748 0.10000E+01 0.0000 72 NaOH,aq 0.13853E-06 -6.8585 0.13853E-06 -6.8585 0.10000E+01 0.0000 74 OH- 0.32004E-03 -3.4948 0.30305E-03 -3.5185 0.94690E+00 -0.0237 79 HPO3-2 0.23658E-18 -18.6260 0.20086E-18 -18.6971 0.84903E+00 -0.0711 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.52743E-08 -8.2778 0.49949E-08 -8.3015 0.94704E+00 -0.0236 84 PO4-3 0.89551E-10 -10.0479 0.63507E-10 -10.1972 0.70917E+00 -0.1493 87 H2P2O7-2 0.22999E-17 -17.6383 0.19527E-17 -17.7094 0.84903E+00 -0.0711 88 HP2O7-3 0.28601E-15 -15.5436 0.20229E-15 -15.6940 0.70728E+00 -0.1504 89 P2O7-4 0.45958E-16 -16.3376 0.25212E-16 -16.5984 0.54860E+00 -0.2607 90 H2S,aq 0.48251E-15 -15.3165 0.48242E-15 -15.3166 0.99982E+00 -0.0001 97 SO3-2 0.15337E-14 -14.8143 0.13032E-14 -14.8850 0.84971E+00 -0.0707 98 HSO3- 0.15941E-15 -15.7975 0.15096E-15 -15.8211 0.94699E+00 -0.0237 99 HSO4- 0.41949E-10 -10.3773 0.39731E-10 -10.4009 0.94714E+00 -0.0236 Charge balance for all species = 0.1071E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2089457E-08 -.5962933E-03 -.6009779E+00 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9999174E+06 0.0000 3 Cl- 0.1379590E-03 0.1379858E-03 0.4891605E+01 4.8196 4 SO4-- 0.2547718E-04 0.2550665E-04 0.2450006E+01 12.7421 5 HCO3- 0.1237695E-04 0.1307110E-04 0.7974958E+00 3.7725 6 HS- 0.8565922E-13 -.2329850E-10 -.7704640E-06 -4.3874 7 Al+++ 0.6610920E-23 0.1857211E-04 0.5010616E+00 2.7803 8 H4SiO4 0.3829605E-03 0.5841697E-03 0.5614304E+02 -3.4168 9 Ca++ 0.4128149E-06 0.4324576E-06 0.1733059E-01 10.9515 10 Mg++ 0.1682224E-08 0.1990763E-08 0.4839540E-04 8.5615 11 Fe++ 0.9949668E-11 0.1804405E-08 0.1007622E-03 6.3335 12 K+ 0.8110426E-04 0.8114839E-04 0.3172800E+01 4.5889 13 Na+ 0.6589331E-03 0.6609690E-03 0.1519428E+02 5.4987 14 Mn++ 0.1328851E-08 0.3494558E-08 0.1919681E-03 8.4592 15 HPO4-- 0.1695100E-06 0.1748738E-06 0.1678281E-01 10.5651 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6593808E-02 -.5962429E-03 -.5997565E-02 0.0000000E+00 2 H2O 0.5550325E+02 0.5550372E+02 -.4702199E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3656212E-04 0.2550449E-04 0.1105763E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1105765E-04 -.2329654E-10 -.1105763E-04 0.0000000E+00 7 Al+++ 0.1301036E-02 0.1857054E-04 0.1282465E-02 0.0000000E+00 8 H4SiO4 0.4154700E-02 0.5841204E-03 0.3570580E-02 0.0000000E+00 9 Ca++ 0.4733780E-03 0.4324211E-06 0.4729456E-03 0.0000000E+00 10 Mg++ 0.3166667E-03 0.1990595E-08 0.3166647E-03 0.0000000E+00 11 Fe++ 0.2844904E-03 0.1804253E-08 0.2844886E-03 0.0000000E+00 12 K+ 0.8471338E-04 0.8114154E-04 0.3571839E-05 0.0000000E+00 13 Na+ 0.6609132E-03 0.6609132E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6918100E-05 0.3494263E-08 0.6914606E-05 0.0000000E+00 15 HPO4-- 0.2361113E-05 0.1748590E-06 0.2186254E-05 0.0000000E+00 Chg. balance for solid moles: -.3354E-18 Mass of aqueous solution: 0.999999E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7288E-06 -6.137 0.3661E-03 -3.436 0.8989E-01 0.1163E-03 clinochlore 0.6333E-04 -4.198 0.3520E-01 -1.453 8.644 0.1339E-01 daphnite 0.3921E-04 -4.407 0.2797E-01 -1.553 6.869 0.8477E-02 chlorite-Mn 0.1383E-05 -5.859 0.9804E-03 -3.009 0.2408 0.3124E-03 hematite 0.4423E-04 -4.354 0.7064E-02 -2.151 1.735 0.1339E-02 kaolinite 0.6265E-04 -4.203 0.1617E-01 -1.791 3.972 0.6223E-02 lawsonite 0.3246E-04 -4.489 0.1020E-01 -1.991 2.505 0.3290E-02 stilbite 0.4368E-03 -3.360 0.3078 -0.512 75.60 0.1436 muscovite 0.3572E-05 -5.447 0.1423E-02 -2.847 0.3494 0.5031E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.407233 g Volume = 0.177237 cm3 Porosity: 84.7157% V(tot) - V(min): 0.98236E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.3990000 g log = -0.3990 Original solution: 1000.0103000 g Original solution / Rock added: 2506.29 (Water/Rock Ratio), log = 3.3990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.5053E-05 1.0073 0.5355E-05 0.5316E-05 CH4,gas 0.6401E-16 1.0129 0.6820E-16 0.6733E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.1343E-13 0.9959 0.1407E-13 0.1413E-13 S2,gas 0.1920E-34 1.0000 0.2019E-34 0.2019E-34 CO,gas 0.7990E-15 1.0000 0.8405E-15 0.8405E-15 SO3,gas 0.3012E-37 1.0000 0.3169E-37 0.3169E-37 SO2,gas 0.6905E-21 1.0000 0.7264E-21 0.7264E-21 HCl,gas 0.8164E-16 1.0000 0.8589E-16 0.8589E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.63 -7.27 -2.424 0.12415E+05 -5.271 3 CH4,gas 4.81 -13.36 -18.17 -4.542 0.31018E+05 -16.166 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.79 -15.85 -7.926 0.27066E+05 -13.852 6 S2,gas -7.03 -43.73 -36.69 -5.645 0.62655E+05 -34.695 7 CO,gas 3.51 -13.57 -17.08 -5.254 0.29156E+05 -15.075 8 SO3,gas 17.43 -22.07 -39.50 -9.875 0.67444E+05 -37.499 9 SO2,gas 1.14 -22.00 -23.14 -6.170 0.39509E+05 -21.139 10 HCl,gas 5.48 -12.59 -18.07 -9.033 0.30847E+05 -16.066 11 acmite 7.74 4.96 -2.77 -0.288 0.47359E+04 15 albite-high 0.75 -1.97 -2.72 -0.209 0.46464E+04 16 albite -0.33 -1.97 -1.64 -0.126 0.28058E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65949E+04 20 analcite 3.37 1.45 -1.93 -0.214 0.32876E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 16.12 -4.09 -0.227 0.69839E+04 27 phlogopite 27.15 22.80 -4.34 -0.241 0.74161E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.68 -3.67 -1.223 0.62650E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.68 -3.52 -1.172 0.60037E+04 38 carnegieite-low 9.06 4.86 -4.20 -0.600 0.71756E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.26 -3.14 -0.185 0.53566E+04 43 celadonite-Fe 3.94 0.04 -3.90 -0.230 0.66620E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14690E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.88 -4.61 -0.384 0.78751E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.45 -2.81 -0.281 0.47906E+04 97 kalsilite 7.62 3.95 -3.67 -0.524 0.62629E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.54 -3.63 -0.363 0.62018E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -2.88 -0.45 -0.035 0.76761E+03 121 paragonite 4.34 3.59 -0.75 -0.044 0.12766E+04 122 nepheline 8.38 4.86 -3.52 -0.502 0.60035E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40530E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.18 -4.22 -1.406 0.72000E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41323E+04 153 sanidine -1.22 -2.88 -1.66 -0.128 0.28354E+04 155 siderite -2.59 -7.30 -4.71 -1.571 0.80479E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.19 -0.99 -0.030 0.16933E+04 165 stilpnomelane-Mg 27.60 23.33 -4.27 -0.127 0.72881E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78738E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.55 -3.11 -0.191 0.53144E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.25 -2.99 -0.183 0.51057E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.68 -2.52 -0.155 0.43092E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.38 -2.42 -0.148 0.41386E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.49 -0.91 -0.059 0.15610E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.79 -0.79 -0.051 0.13540E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.36 -1.72 -0.132 0.29382E+04 243 an25ab75 2.71 0.94 -1.77 -0.136 0.30193E+04 244 an30ab70 3.34 1.52 -1.82 -0.140 0.31086E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0100000 g Current total amount of reactant added: 0.3990000 g New total amount of reactant added: 0.4090000 g Mixing fraction reached given limit of 0.4000E+00 TOTMIX = 0.4090E+00 Execution stopped.