File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.65938E-02 0.20895E-08 0.9473 0.00000000E+00 H2O 2 0. 0.55503E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13796E-03 0.9470 0.00000000E+00 SO4-- 4 -2. 0.36562E-04 0.25477E-04 0.8491 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.12377E-04 0.9471 0.00000000E+00 HS- 6 -1. -0.11058E-04 0.85659E-13 0.9470 0.00000000E+00 Al+++ 7 3. 0.13010E-02 0.66109E-23 0.7073 0.00000000E+00 H4SiO4 8 0. 0.41547E-02 0.38296E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.47338E-03 0.41281E-06 0.8488 0.00000000E+00 Mg++ 10 2. 0.31667E-03 0.16822E-08 0.8486 0.00000000E+00 Fe++ 11 2. 0.28449E-03 0.99497E-11 0.8486 0.00000000E+00 K+ 12 1. 0.84713E-04 0.81104E-04 0.9471 0.00000000E+00 Na+ 13 1. 0.66091E-03 0.65893E-03 0.9470 0.00000000E+00 Mn++ 14 2. 0.69181E-05 0.13289E-08 0.8487 0.00000000E+00 HPO4-- 15 -2. 0.23611E-05 0.16951E-06 0.8491 0.00000000E+00 Chg. balance for total moles = -.5880E-14 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 100.0000 SLIM = 0.800000E+00 TEMP = 100.0000 SINC = 0.2000E-01 TEMPC = 0.0000 TOTMIX = 0.399000E+00 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 1.1596 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0107 MnO2-2 65 -2. 40.4376 Ca(HSiO3)+ 17 1. 7.6603 HMnO2- 66 -1. 29.1018 Mg(HSiO3)+ 18 1. 7.5653 MnO4- 67 -1. 83.3383 NaHSiO3,aq 19 0. 7.8098 MnO4-2 68 -2. 81.3024 AlO+ 20 1. 6.8891 MnCl+ 69 1. -0.7819 AlOH+2 21 2. 3.1893 MnSO4,aq 70 0. -2.4524 HAlO2,aq 22 0. 10.5878 NaCl,aq 71 0. 0.4861 AlO2- 23 -1. 16.2390 NaOH,aq 72 0. 12.3571 CH4,aq 24 0. 6.0082 O2,aq 73 0. 53.5759 C2H6,aq 25 0. 12.3556 OH- 74 -1. 12.2220 C3H8,aq 26 0. 17.3423 HO2- 75 -1. 50.7897 C4H10,aq 27 0. 22.3397 H2O2,aq 76 0. 40.0297 ethanol,aq 28 0. 15.3114 H3PO2,aq 77 0. 24.3310 CO,aq 29 0. 4.7087 H2PO2- 78 -1. 26.5491 CO2,aq 30 0. -6.3045 HPO3-2 79 -2. 11.9246 CO3-2 31 -2. 10.0340 H3PO3,aq 80 0. 3.5932 CaCO3,aq 32 0. 5.9460 H2PO3- 81 -1. 5.6314 Ca(HCO3)+ 33 1. -1.4013 H3PO4,aq 82 0. -9.8087 CaCl+ 34 1. -0.2023 H2PO4- 83 -1. -7.2438 CaCl2,aq 35 0. 0.4306 PO4-3 84 -3. 12.0588 CaOH+ 36 1. 10.1517 H4P2O7,aq 85 0. -17.7539 CaSO4,aq 37 0. -2.4936 H3P2O7- 86 -1. -15.8646 HCl,aq 38 0. 0.7256 H2P2O7-2 87 -2. -13.3812 HClO,aq 39 0. 32.4377 HP2O7-3 88 -3. -6.6931 ClO- 40 -1. 39.6416 P2O7-4 89 -4. 2.9147 HClO2,aq 41 0. 70.2060 H2S,aq 90 0. -6.4778 Fe+3 42 3. 8.3763 S2-2 91 -2. 1.2336 FeCl+ 43 1. -0.1924 S3-2 92 -2. -8.7963 FeCl2,aq 44 0. 4.3160 S3- 93 -1. -16.3178 FeCl+2 45 2. 6.5223 S4-2 94 -2. -18.6473 FeO,aq 46 0. 16.4029 S5-2 95 -2. -28.3223 FeOH+ 47 1. 7.4795 SO2,aq 96 0. -0.1980 HFeO2- 48 -1. 24.3713 SO3-2 97 -2. 10.2895 FeO+ 49 1. 11.3812 HSO3- 98 -1. 2.5222 FeOH+2 50 2. 9.1115 HSO4- 99 -1. -2.9675 FeO2- 51 -1. 24.0877 HSO5- 100 -1. 38.8657 HFeO2,aq 52 0. 15.9903 S2O3-2 101 -2. -4.5491 H2,aq 53 0. 9.4241 HS2O3- 102 -1. -6.8007 KCl,aq 54 0. 1.7519 H2S2O3,aq 103 0. -7.9944 KHSO4,aq 55 0. -0.4275 S2O4-2 104 -2. 10.5639 KOH,aq 56 0. 12.3606 HS2O4- 105 -1. 7.6762 KSO4- 57 -1. -1.1877 H2S2O4,aq 106 0. 6.6566 MgCO3,aq 58 0. 6.5483 S2O5-2 107 -2. 10.0891 Mg(HCO3)+ 59 1. -1.4098 S2O6-2 108 -2. 11.5737 MgCl+ 60 1. -0.1603 S2O8-2 109 -2. 42.1139 MgOH+ 61 1. 9.4082 S3O6-2 110 -2. 3.8101 Mn+3 62 3. 19.1332 S4O6-2 111 -2. -17.8301 MnO,aq 63 0. 17.9765 S5O6-2 112 -2. -14.1051 MnOH+ 64 1. 8.5115 113 0. 10.3157 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.984 0.0000E+00 osumilite(2) 124 20.895 0.0000E+00 CO2,gas 2 -6.363 0.0000E+00 osumilite-Fe 125 14.657 0.0000E+00 CH4,gas 3 4.809 0.0000E+00 pargasite 126 65.279 0.0000E+00 H2,gas 4 8.287 0.0000E+00 periclase 127 16.149 0.0000E+00 H2S,gas 5 -5.943 0.0000E+00 periclase-Fe 128 11.639 0.0000E+00 S2,gas 6 -7.033 0.0000E+00 perovskite-Al 129 12.395 0.0000E+00 CO,gas 7 3.510 0.0000E+00 perovskite-Ca 130 23.818 0.0000E+00 SO3,gas 8 17.427 0.0000E+00 perovskite-Fe 131 21.158 0.0000E+00 SO2,gas 9 1.136 0.0000E+00 perovskite-Mg 132 23.132 0.0000E+00 HCl,gas 10 5.479 0.0000E+00 phase_A 133 80.267 0.0000E+00 acmite 11 7.737 0.0000E+00 phlogopite-Na 134 29.731 0.0000E+00 akermanite 12 36.495 0.0000E+00 piemontite(ordered) 135 33.876 0.0000E+00 akimotoite 13 16.606 0.0000E+00 prehnite 136 19.466 0.0000E+00 akimotoite-Fe 14 13.083 0.0000E+00 prehnite-Fe 137 22.587 0.0000E+00 albite-high 15 0.750 0.0000E+00 pumpellyite-Fe 138 46.471 0.0000E+00 albite 16 -0.328 0.0000E+00 pumpellyite-Mg 139 49.194 0.0000E+00 almandine 17 24.545 0.0000E+00 px-Mg-tschermaks 140 19.687 0.0000E+00 pyrope 18 37.348 0.0000E+00 px-Ca-tschermaks 141 18.679 0.0000E+00 spessartine 19 24.550 0.0000E+00 pyrite 142 -21.225 0.0000E+00 analcite 20 3.371 0.0000E+00 pyrrhotite 143 -4.244 0.0000E+00 andalusite 21 5.062 0.0000E+00 pyrrhotiteFe0.875 144 -6.001 0.0000E+00 andradite 22 39.088 0.0000E+00 pyroxmangite 145 7.416 0.0000E+00 grossular 23 32.828 0.0000E+00 pyrophyllite 146 -6.098 0.0000E+00 anhydrite 24 -5.280 0.0000E+00 quartz 147 -2.982 0.0000E+00 ankerite 25 -2.093 0.0000E+00 rankinite 148 40.765 0.0000E+00 annite 26 20.209 0.0000E+00 ringwoodite-Fe 149 15.486 0.0000E+00 phlogopite 27 27.147 0.0000E+00 ringwoodite-Mg 150 27.602 0.0000E+00 biotite-Mn 28 33.034 0.0000E+00 rhodochrosite 151 -0.959 0.0000E+00 anorthite 29 12.798 0.0000E+00 rhodonite 152 7.462 0.0000E+00 anthophyllite 30 51.988 0.0000E+00 sanidine 153 -1.221 0.0000E+00 anthophyllite-Fe 31 29.455 0.0000E+00 sapphirine(351) 154 79.204 0.0000E+00 apatite-OH 32 -17.989 0.7288E-06 siderite 155 -2.588 0.0000E+00 apatite-OH-zs 33 -12.572 0.0000E+00 sillimanite 156 5.321 0.0000E+00 apatite-Cl-zs 34 -16.504 0.0000E+00 sodalite 157 50.255 0.0000E+00 aragonite 35 0.986 0.0000E+00 spinel 158 20.934 0.0000E+00 brucite 36 12.577 0.0000E+00 spurrite 159 59.566 0.0000E+00 calcite 37 0.833 0.0000E+00 staurolite-Fe 160 74.138 0.0000E+00 carnegieite-low 38 9.065 0.0000E+00 staurolite-Mg 161 90.336 0.0000E+00 carnegieite-high 39 10.134 0.0000E+00 staurolite-Mn 162 84.438 0.0000E+00 carpholite-Mg 40 8.650 0.0000E+00 stilbite 163 -7.406 0.4368E-03 carpholite-Fe 41 6.783 0.0000E+00 stilpnomelane-Fe 164 13.179 0.0000E+00 celadonite 42 5.401 0.0000E+00 stilpnomelane-Mg 165 27.596 0.0000E+00 celadonite-Fe 43 3.937 0.0000E+00 stishovite 166 2.721 0.0000E+00 chrysotile 44 23.937 0.0000E+00 sudoite-Fe 167 18.437 0.0000E+00 chondrodite 45 56.542 0.0000E+00 sudoite 168 21.216 0.0000E+00 clinochlore 46 39.193 0.6333E-04 sulfur 169 -9.141 0.0000E+00 daphnite 47 29.094 0.3921E-04 sylvite 170 1.345 0.0000E+00 chlorite-Mn 48 46.985 0.1383E-05 talc 171 16.553 0.0000E+00 chlorite-Al-free 49 47.262 0.0000E+00 talc-Fe 172 13.516 0.0000E+00 chloritoid-Mg 50 13.261 0.0000E+00 talc-tschermaks 173 19.189 0.0000E+00 chloritoid-Fe 51 9.239 0.0000E+00 tephroite 174 18.113 0.0000E+00 chloritoid-Mn 52 11.463 0.0000E+00 tilleyite 175 41.473 0.0000E+00 clinohumite 53 97.255 0.0000E+00 titanite-CaSi 176 15.497 0.0000E+00 coesite 54 -2.369 0.0000E+00 topaz-H 177 4.668 0.0000E+00 cordierite-H 55 23.898 0.0000E+00 tridymite 178 -2.615 0.0000E+00 cordierite 56 24.245 0.0000E+00 tremolite 179 48.003 0.0000E+00 cordierite-Fe 57 20.649 0.0000E+00 ferroactinolite 180 38.596 0.0000E+00 cordierite-Mn 58 25.261 0.0000E+00 troilite-low 181 -4.394 0.0000E+00 corundum 59 8.433 0.0000E+00 tschermakite 182 48.414 0.0000E+00 corundum-MgSi 60 18.905 0.0000E+00 vesuvianite 183 224.056 0.0000E+00 cristobalite 61 -2.549 0.0000E+00 wadeite-Si 184 20.233 0.0000E+00 cummingtonite 62 52.233 0.0000E+00 wadsleyite-Fe 185 15.711 0.0000E+00 cymrite-K 63 1.731 0.0000E+00 wadsleyite-Mg 186 25.878 0.0000E+00 deerite 64 95.982 0.0000E+00 wairakite 187 4.058 0.0000E+00 diaspore 65 2.896 0.0000E+00 walstromite 188 11.528 0.0000E+00 diamond 66 -3.107 0.0000E+00 wollastonite 189 10.482 0.0000E+00 diopside 67 16.215 0.0000E+00 pseudo-wollastonite 190 11.020 0.0000E+00 hedenbergite 68 14.244 0.0000E+00 zoisite 191 22.964 0.0000E+00 dolomite,ordered 69 0.587 0.0000E+00 akaganeite 192 7.768 0.0000E+00 eastonite 70 28.605 0.0000E+00 beidellite-Ca 193 -1.560 0.0000E+00 enstatite 71 17.301 0.0000E+00 beidellite-H 194 -2.241 0.0000E+00 clinoenstatite-HiP 72 18.388 0.0000E+00 beidellite-K 195 -1.435 0.0000E+00 clinoenstatite 73 17.202 0.0000E+00 beidellite-Mg 196 -1.707 0.0000E+00 protoenstatite 74 17.860 0.0000E+00 beidellite-Na 197 -1.257 0.0000E+00 epidote 75 24.775 0.0000E+00 calcium 198 84.043 0.0000E+00 clinozoisite 76 22.921 0.0000E+00 chalcedony 199 -2.794 0.0000E+00 epidote-Fe 77 29.937 0.0000E+00 dawsonite 200 1.714 0.0000E+00 fayalite 78 14.079 0.0000E+00 montmorillonite-Ca 201 -2.214 0.0000E+00 ferrosilite 79 11.188 0.0000E+00 montmorillonite-K 202 -2.161 0.0000E+00 forsterite 80 21.047 0.0000E+00 montmorillonite-Mg 203 -2.402 0.0000E+00 gedrite 81 50.725 0.0000E+00 montmorillonite-Na 204 -1.961 0.0000E+00 gehlenite 82 36.717 0.0000E+00 nontronite-Ca 205 3.280 0.0000E+00 gibbsite 83 4.097 0.0000E+00 nontronite-H 206 2.596 0.0000E+00 glaucophane 84 23.111 0.0000E+00 nontronite-K 207 3.404 0.0000E+00 glaucophane-Fe 85 17.417 0.0000E+00 nontronite-Mg 208 3.139 0.0000E+00 graphite 86 -3.549 0.0000E+00 nontronite-Na 209 3.583 0.0000E+00 greenalite 87 16.194 0.0000E+00 sepiolite 210 24.194 0.0000E+00 grunerite 88 31.364 0.0000E+00 alite 211 58.043 0.0000E+00 halite 89 1.582 0.0000E+00 belite 212 30.461 0.0000E+00 hematite 90 12.598 0.4423E-04 ettringite 213 43.354 0.0000E+00 heulandite 91 -5.707 0.0000E+00 gypsum 214 -4.924 0.0000E+00 hercynite 92 17.345 0.0000E+00 hemicarboaluminate 215 71.028 0.0000E+00 hollandite 93 25.702 0.0000E+00 hydrogarnet 216 60.721 0.0000E+00 iron 94 19.095 0.0000E+00 hydrogarnet-Si 217 50.654 0.0000E+00 jadeite 95 4.251 0.0000E+00 jennite 218 24.386 0.0000E+00 julgoldite 96 70.573 0.0000E+00 monosulfoaluminate 219 53.497 0.0000E+00 kalsilite 97 7.620 0.0000E+00 monocarboaluminate 220 61.966 0.0000E+00 kaolinite 98 -1.273 0.6265E-04 portlandite 221 18.282 0.0000E+00 kyanite 99 4.932 0.0000E+00 stratlingite 222 36.573 0.0000E+00 larnite-bredigite 100 30.714 0.0000E+00 tricarboaluminate 223 70.427 0.0000E+00 laumontite 101 2.975 0.0000E+00 tobermorite 224 9.839 0.0000E+00 lawsonite 102 9.678 0.3246E-04 C4AH13 225 81.870 0.0000E+00 leucite 103 4.168 0.0000E+00 C2AH8 226 45.260 0.0000E+00 lime 104 26.009 0.0000E+00 C3A 227 87.049 0.0000E+00 lizardite 105 23.287 0.0000E+00 C4AF 228 117.550 0.0000E+00 magnesite 106 0.709 0.0000E+00 CAH10 229 28.373 0.0000E+00 magnetite 107 20.133 0.0000E+00 alabandite 230 -0.962 0.0000E+00 minnesotaite 108 10.461 0.0000E+00 alunite 231 -10.224 0.0000E+00 minnesotaite-Mg 109 20.669 0.0000E+00 artinite 232 15.139 0.0000E+00 magnesioferrite 110 26.257 0.0000E+00 boehmite 233 4.430 0.0000E+00 majorite 111 53.314 0.0000E+00 dolomite,disordered 234 1.288 0.0000E+00 manganosite 112 14.068 0.0000E+00 ferrous-oxide 235 9.824 0.0000E+00 margarite 113 17.452 0.0000E+00 huntite 236 3.850 0.0000E+00 meionite 114 45.158 0.0000E+00 hydromagnesite 237 20.077 0.0000E+00 merwinite 115 55.988 0.0000E+00 nesquehonite 238 4.735 0.0000E+00 microcline 116 -2.432 0.0000E+00 potassium-oxide 239 69.039 0.0000E+00 monticellite 117 24.371 0.0000E+00 silica-amorphous 240 -2.080 0.0000E+00 mullite-Al 118 363.258 0.0000E+00 sodium-oxide 241 55.173 0.0000E+00 mullite-Si 119 7.324 0.0000E+00 an20ab80 242 2.079 0.0000E+00 muscovite 120 2.679 0.3572E-05 an25ab75 243 2.709 0.0000E+00 paragonite 121 4.337 0.0000E+00 an30ab70 244 3.344 0.0000E+00 nepheline 122 8.378 0.0000E+00 tr.625ac.25prg.125 245 45.308 0.0000E+00 osumilite(1) 123 21.978 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 0.3990000 g log = -0.3990 Original solution: 1000.0103000 g Original solution / Rock added: 2506.29 (Water/Rock Ratio), log = 3.3990 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.3990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .5824025E-03 Osmotic coef. = 0.9858 True ionic strength = .7675960E-03 Chg. balance for total moles = -.5880E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.20895E-08 -8.6800 0.19793E-08 -8.7035 0.94730E+00 -0.0235 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.13065E-03 -3.8839 0.94699E+00 -0.0237 4 SO4-- 0.25477E-04 -4.5938 0.21633E-04 -4.6649 0.84913E+00 -0.0710 5 HCO3- 0.12377E-04 -4.9074 0.11722E-04 -4.9310 0.94707E+00 -0.0236 6 HS- 0.85659E-13 -13.0672 0.81119E-13 -13.0909 0.94700E+00 -0.0237 7 Al+++ 0.66109E-23 -23.1797 0.46756E-23 -23.3302 0.70726E+00 -0.1504 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.41281E-06 -6.3842 0.35040E-06 -6.4554 0.84880E+00 -0.0712 10 Mg++ 0.16822E-08 -8.7741 0.14275E-08 -8.8454 0.84859E+00 -0.0713 11 Fe++ 0.99497E-11 -11.0022 0.84437E-11 -11.0735 0.84864E+00 -0.0713 12 K+ 0.81104E-04 -4.0910 0.76812E-04 -4.1146 0.94708E+00 -0.0236 13 Na+ 0.65893E-03 -3.1812 0.62400E-03 -3.2048 0.94698E+00 -0.0237 14 Mn++ 0.13289E-08 -8.8765 0.11278E-08 -8.9478 0.84867E+00 -0.0713 15 HPO4-- 0.16951E-06 -6.7708 0.14394E-06 -6.8418 0.84914E+00 -0.0710 16 HSiO3- 0.19934E-03 -3.7004 0.18877E-03 -3.7241 0.94699E+00 -0.0237 17 Ca(HSiO3)+ 0.15648E-08 -8.8055 0.14820E-08 -8.8292 0.94709E+00 -0.0236 18 Mg(HSiO3)+ 0.79336E-11 -11.1005 0.75139E-11 -11.1241 0.94709E+00 -0.0236 19 NaHSiO3,aq 0.18708E-05 -5.7280 0.18708E-05 -5.7280 0.10000E+01 0.0000 20 AlO+ 0.16267E-12 -12.7887 0.15407E-12 -12.8123 0.94709E+00 -0.0236 21 AlOH+2 0.17999E-17 -17.7447 0.15276E-17 -17.8160 0.84872E+00 -0.0712 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.18557E-04 -4.7315 0.17571E-04 -4.7552 0.94690E+00 -0.0237 24 CH4,aq 0.43137E-19 -19.3651 0.43129E-19 -19.3652 0.99982E+00 -0.0001 29 CO,aq 0.53229E-18 -18.2739 0.53229E-18 -18.2739 0.10000E+01 0.0000 30 CO2,aq 0.46787E-07 -7.3299 0.46779E-07 -7.3300 0.99982E+00 -0.0001 31 CO3-2 0.64491E-06 -6.1905 0.54755E-06 -6.2616 0.84903E+00 -0.0711 32 CaCO3,aq 0.23498E-08 -8.6290 0.23498E-08 -8.6290 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10927E-09 -9.9615 0.10349E-09 -9.9851 0.94709E+00 -0.0236 34 CaCl+ 0.77022E-10 -10.1134 0.72947E-10 -10.1370 0.94709E+00 -0.0236 35 CaCl2,aq 0.22190E-14 -14.6538 0.22190E-14 -14.6538 0.10000E+01 0.0000 36 CaOH+ 0.13180E-07 -7.8801 0.12483E-07 -7.9037 0.94709E+00 -0.0236 37 CaSO4,aq 0.23618E-08 -8.6267 0.23618E-08 -8.6267 0.10000E+01 0.0000 38 HCl,aq 0.48641E-13 -13.3130 0.48641E-13 -13.3130 0.10000E+01 0.0000 43 FeCl+ 0.18141E-14 -14.7413 0.17181E-14 -14.7649 0.94709E+00 -0.0236 46 FeO,aq 0.85225E-10 -10.0694 0.85225E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.14933E-09 -9.8259 0.14142E-09 -9.8495 0.94709E+00 -0.0236 48 HFeO2- 0.48905E-09 -9.3106 0.46312E-09 -9.3343 0.94699E+00 -0.0237 49 FeO+ 0.17288E-13 -13.7623 0.16373E-13 -13.7859 0.94709E+00 -0.0236 51 FeO2- 0.86737E-09 -9.0618 0.82139E-09 -9.0855 0.94699E+00 -0.0237 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44189E-09 -9.3547 0.44181E-09 -9.3548 0.99982E+00 -0.0001 54 KCl,aq 0.17769E-09 -9.7503 0.17769E-09 -9.7503 0.10000E+01 0.0000 55 KHSO4,aq 0.88016E-17 -17.0554 0.88016E-17 -17.0554 0.10000E+01 0.0000 56 KOH,aq 0.16918E-07 -7.7717 0.16918E-07 -7.7717 0.10000E+01 0.0000 57 KSO4- 0.27034E-07 -7.5681 0.25601E-07 -7.5917 0.94699E+00 -0.0237 58 MgCO3,aq 0.23921E-11 -11.6212 0.23921E-11 -11.6212 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.45396E-12 -12.3430 0.42994E-12 -12.3666 0.94709E+00 -0.0236 60 MgCl+ 0.28486E-12 -12.5454 0.26979E-12 -12.5690 0.94709E+00 -0.0236 61 MgOH+ 0.29747E-09 -9.5266 0.28173E-09 -9.5502 0.94709E+00 -0.0236 63 MnO,aq 0.30387E-09 -9.5173 0.30387E-09 -9.5173 0.10000E+01 0.0000 64 MnOH+ 0.18528E-08 -8.7322 0.17547E-08 -8.7558 0.94709E+00 -0.0236 65 MnO2-2 0.31593E-14 -14.5004 0.26823E-14 -14.5715 0.84903E+00 -0.0711 66 HMnO2- 0.12147E-11 -11.9155 0.11503E-11 -11.9392 0.94699E+00 -0.0237 69 MnCl+ 0.94154E-12 -12.0262 0.89172E-12 -12.0498 0.94709E+00 -0.0236 70 MnSO4,aq 0.69143E-11 -11.1603 0.69143E-11 -11.1603 0.10000E+01 0.0000 71 NaCl,aq 0.26619E-07 -7.5748 0.26619E-07 -7.5748 0.10000E+01 0.0000 72 NaOH,aq 0.13853E-06 -6.8585 0.13853E-06 -6.8585 0.10000E+01 0.0000 74 OH- 0.32004E-03 -3.4948 0.30305E-03 -3.5185 0.94690E+00 -0.0237 79 HPO3-2 0.23658E-18 -18.6260 0.20086E-18 -18.6971 0.84903E+00 -0.0711 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.52743E-08 -8.2778 0.49949E-08 -8.3015 0.94704E+00 -0.0236 84 PO4-3 0.89551E-10 -10.0479 0.63507E-10 -10.1972 0.70917E+00 -0.1493 87 H2P2O7-2 0.22999E-17 -17.6383 0.19527E-17 -17.7094 0.84903E+00 -0.0711 88 HP2O7-3 0.28601E-15 -15.5436 0.20229E-15 -15.6940 0.70728E+00 -0.1504 89 P2O7-4 0.45958E-16 -16.3376 0.25212E-16 -16.5984 0.54860E+00 -0.2607 90 H2S,aq 0.48251E-15 -15.3165 0.48242E-15 -15.3166 0.99982E+00 -0.0001 97 SO3-2 0.15337E-14 -14.8143 0.13032E-14 -14.8850 0.84971E+00 -0.0707 98 HSO3- 0.15941E-15 -15.7975 0.15096E-15 -15.8211 0.94699E+00 -0.0237 99 HSO4- 0.41949E-10 -10.3773 0.39731E-10 -10.4009 0.94714E+00 -0.0236 Charge balance for all species = -.5480E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2089457E-08 -.5962933E-03 -.6009779E+00 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9999174E+06 0.0000 3 Cl- 0.1379590E-03 0.1379858E-03 0.4891605E+01 4.8196 4 SO4-- 0.2547718E-04 0.2550665E-04 0.2450006E+01 12.7421 5 HCO3- 0.1237695E-04 0.1307110E-04 0.7974958E+00 3.7725 6 HS- 0.8565922E-13 -.2329851E-10 -.7704641E-06 -4.3874 7 Al+++ 0.6610920E-23 0.1857211E-04 0.5010616E+00 2.7803 8 H4SiO4 0.3829605E-03 0.5841697E-03 0.5614304E+02 -3.4168 9 Ca++ 0.4128149E-06 0.4324576E-06 0.1733059E-01 10.9515 10 Mg++ 0.1682224E-08 0.1990763E-08 0.4839540E-04 8.5615 11 Fe++ 0.9949668E-11 0.1804405E-08 0.1007622E-03 6.3335 12 K+ 0.8110426E-04 0.8114839E-04 0.3172800E+01 4.5889 13 Na+ 0.6589331E-03 0.6609690E-03 0.1519428E+02 5.4987 14 Mn++ 0.1328851E-08 0.3494558E-08 0.1919681E-03 8.4592 15 HPO4-- 0.1695100E-06 0.1748738E-06 0.1678281E-01 10.5651 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6593808E-02 -.5962429E-03 -.5997565E-02 0.0000000E+00 2 H2O 0.5550325E+02 0.5550372E+02 -.4702199E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3656212E-04 0.2550449E-04 0.1105763E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1105765E-04 -.2329654E-10 -.1105763E-04 0.0000000E+00 7 Al+++ 0.1301036E-02 0.1857054E-04 0.1282465E-02 0.0000000E+00 8 H4SiO4 0.4154700E-02 0.5841204E-03 0.3570580E-02 0.0000000E+00 9 Ca++ 0.4733780E-03 0.4324211E-06 0.4729456E-03 0.0000000E+00 10 Mg++ 0.3166667E-03 0.1990595E-08 0.3166647E-03 0.0000000E+00 11 Fe++ 0.2844904E-03 0.1804253E-08 0.2844886E-03 0.0000000E+00 12 K+ 0.8471338E-04 0.8114154E-04 0.3571839E-05 0.0000000E+00 13 Na+ 0.6609132E-03 0.6609132E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.6918100E-05 0.3494263E-08 0.6914606E-05 0.0000000E+00 15 HPO4-- 0.2361113E-05 0.1748590E-06 0.2186254E-05 0.0000000E+00 Chg. balance for solid moles: -.4235E-19 Mass of aqueous solution: 0.999999E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7288E-06 -6.137 0.3661E-03 -3.436 0.8989E-01 0.1163E-03 clinochlore 0.6333E-04 -4.198 0.3520E-01 -1.453 8.644 0.1339E-01 daphnite 0.3921E-04 -4.407 0.2797E-01 -1.553 6.869 0.8477E-02 chlorite-Mn 0.1383E-05 -5.859 0.9804E-03 -3.009 0.2408 0.3124E-03 hematite 0.4423E-04 -4.354 0.7064E-02 -2.151 1.735 0.1339E-02 kaolinite 0.6265E-04 -4.203 0.1617E-01 -1.791 3.972 0.6223E-02 lawsonite 0.3246E-04 -4.489 0.1020E-01 -1.991 2.505 0.3290E-02 muscovite 0.3572E-05 -5.447 0.1423E-02 -2.847 0.3494 0.5031E-03 stilbite 0.4368E-03 -3.360 0.3078 -0.512 75.60 0.1436 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.407233 g Volume = 0.177237 cm3 Porosity: 84.7157% V(tot) - V(min): 0.98236E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.3990000 g log = -0.3990 Original solution: 1000.0103000 g Original solution / Rock added: 2506.29 (Water/Rock Ratio), log = 3.3990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.5053E-05 1.0073 0.5355E-05 0.5316E-05 CH4,gas 0.6401E-16 1.0129 0.6820E-16 0.6733E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.1343E-13 0.9959 0.1407E-13 0.1413E-13 S2,gas 0.1920E-34 1.0000 0.2019E-34 0.2019E-34 CO,gas 0.7990E-15 1.0000 0.8405E-15 0.8405E-15 SO3,gas 0.3012E-37 1.0000 0.3169E-37 0.3169E-37 SO2,gas 0.6905E-21 1.0000 0.7264E-21 0.7264E-21 HCl,gas 0.8164E-16 1.0000 0.8589E-16 0.8589E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 120 muscovite 2.68 2.68 0.00 0.000 0.30331E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.63 -7.27 -2.424 0.12415E+05 -5.271 3 CH4,gas 4.81 -13.36 -18.17 -4.542 0.31018E+05 -16.166 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.79 -15.85 -7.926 0.27066E+05 -13.852 6 S2,gas -7.03 -43.73 -36.69 -5.645 0.62655E+05 -34.695 7 CO,gas 3.51 -13.57 -17.08 -5.254 0.29156E+05 -15.075 8 SO3,gas 17.43 -22.07 -39.50 -9.875 0.67444E+05 -37.499 9 SO2,gas 1.14 -22.00 -23.14 -6.170 0.39509E+05 -21.139 10 HCl,gas 5.48 -12.59 -18.07 -9.033 0.30847E+05 -16.066 11 acmite 7.74 4.96 -2.77 -0.288 0.47359E+04 15 albite-high 0.75 -1.97 -2.72 -0.209 0.46464E+04 16 albite -0.33 -1.97 -1.64 -0.126 0.28058E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65949E+04 20 analcite 3.37 1.45 -1.93 -0.214 0.32876E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 16.12 -4.09 -0.227 0.69839E+04 27 phlogopite 27.15 22.80 -4.34 -0.241 0.74161E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.68 -3.67 -1.223 0.62650E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.68 -3.52 -1.172 0.60037E+04 38 carnegieite-low 9.06 4.86 -4.20 -0.600 0.71756E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.26 -3.14 -0.185 0.53566E+04 43 celadonite-Fe 3.94 0.04 -3.90 -0.230 0.66620E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14690E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.88 -4.61 -0.384 0.78751E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.45 -2.81 -0.281 0.47906E+04 97 kalsilite 7.62 3.95 -3.67 -0.524 0.62629E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.54 -3.63 -0.363 0.62018E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -2.88 -0.45 -0.035 0.76761E+03 121 paragonite 4.34 3.59 -0.75 -0.044 0.12766E+04 122 nepheline 8.38 4.86 -3.52 -0.502 0.60035E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40530E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.18 -4.22 -1.406 0.72000E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41323E+04 153 sanidine -1.22 -2.88 -1.66 -0.128 0.28354E+04 155 siderite -2.59 -7.30 -4.71 -1.571 0.80479E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.19 -0.99 -0.030 0.16933E+04 165 stilpnomelane-Mg 27.60 23.33 -4.27 -0.127 0.72881E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78738E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.55 -3.11 -0.191 0.53144E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.25 -2.99 -0.183 0.51057E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.68 -2.52 -0.155 0.43092E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.38 -2.42 -0.148 0.41386E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.49 -0.91 -0.059 0.15610E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.79 -0.79 -0.051 0.13540E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.36 -1.72 -0.132 0.29382E+04 243 an25ab75 2.71 0.94 -1.77 -0.136 0.30193E+04 244 an30ab70 3.34 1.52 -1.82 -0.140 0.31086E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.3990000 g New total amount of reactant added: 0.4190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5879E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.4190000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .5967627E-03 Osmotic coef. = 0.9857 True ionic strength = .7894197E-03 Chg. balance for total moles = -.5879E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.20102E-08 -8.6968 0.19034E-08 -8.7205 0.94684E+00 -0.0237 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.13058E-03 -3.8841 0.94652E+00 -0.0239 4 SO4-- 0.25479E-04 -4.5938 0.21592E-04 -4.6657 0.84746E+00 -0.0719 5 HCO3- 0.12354E-04 -4.9082 0.11694E-04 -4.9320 0.94660E+00 -0.0238 6 HS- 0.82253E-13 -13.0848 0.77855E-13 -13.1087 0.94653E+00 -0.0239 7 Al+++ 0.59046E-23 -23.2288 0.41575E-23 -23.3812 0.70412E+00 -0.1524 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.38248E-06 -6.4174 0.32401E-06 -6.4894 0.84712E+00 -0.0721 10 Mg++ 0.15586E-08 -8.8073 0.13200E-08 -8.8794 0.84690E+00 -0.0722 11 Fe++ 0.92186E-11 -11.0353 0.78078E-11 -11.1075 0.84695E+00 -0.0721 12 K+ 0.78029E-04 -4.1077 0.73863E-04 -4.1316 0.94661E+00 -0.0238 13 Na+ 0.68388E-03 -3.1650 0.64730E-03 -3.1889 0.94651E+00 -0.0239 14 Mn++ 0.12313E-08 -8.9096 0.10429E-08 -8.9818 0.84699E+00 -0.0721 15 HPO4-- 0.18368E-06 -6.7359 0.15566E-06 -6.8078 0.84747E+00 -0.0719 16 HSiO3- 0.20740E-03 -3.6832 0.19631E-03 -3.7071 0.94652E+00 -0.0239 17 Ca(HSiO3)+ 0.15054E-08 -8.8223 0.14251E-08 -8.8462 0.94662E+00 -0.0238 18 Mg(HSiO3)+ 0.76328E-11 -11.1173 0.72254E-11 -11.1411 0.94662E+00 -0.0238 19 NaHSiO3,aq 0.20182E-05 -5.6950 0.20182E-05 -5.6950 0.10000E+01 0.0000 20 AlO+ 0.15651E-12 -12.8055 0.14815E-12 -12.8293 0.94662E+00 -0.0238 21 AlOH+2 0.16677E-17 -17.7779 0.14126E-17 -17.8500 0.84704E+00 -0.0721 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.19307E-04 -4.7143 0.18273E-04 -4.7382 0.94642E+00 -0.0239 24 CH4,aq 0.41382E-19 -19.3832 0.41374E-19 -19.3833 0.99981E+00 -0.0001 29 CO,aq 0.51063E-18 -18.2919 0.51063E-18 -18.2919 0.10000E+01 0.0000 30 CO2,aq 0.44884E-07 -7.3479 0.44876E-07 -7.3480 0.99981E+00 -0.0001 31 CO3-2 0.67038E-06 -6.1737 0.56805E-06 -6.2456 0.84736E+00 -0.0719 32 CaCO3,aq 0.22542E-08 -8.6470 0.22542E-08 -8.6470 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10085E-09 -9.9963 0.95469E-10 -10.0201 0.94662E+00 -0.0238 34 CaCl+ 0.71221E-10 -10.1474 0.67419E-10 -10.1712 0.94662E+00 -0.0238 35 CaCl2,aq 0.20498E-14 -14.6883 0.20498E-14 -14.6883 0.10000E+01 0.0000 36 CaOH+ 0.12680E-07 -7.8969 0.12003E-07 -7.9207 0.94662E+00 -0.0238 37 CaSO4,aq 0.21798E-08 -8.6616 0.21798E-08 -8.6616 0.10000E+01 0.0000 38 HCl,aq 0.46750E-13 -13.3302 0.46750E-13 -13.3302 0.10000E+01 0.0000 43 FeCl+ 0.16775E-14 -14.7753 0.15879E-14 -14.7992 0.94662E+00 -0.0238 46 FeO,aq 0.85225E-10 -10.0694 0.85225E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.14366E-09 -9.8427 0.13599E-09 -9.8665 0.94662E+00 -0.0238 48 HFeO2- 0.50883E-09 -9.2934 0.48161E-09 -9.3173 0.94652E+00 -0.0239 49 FeO+ 0.16633E-13 -13.7790 0.15745E-13 -13.8029 0.94662E+00 -0.0238 51 FeO2- 0.90244E-09 -9.0446 0.85418E-09 -9.0684 0.94652E+00 -0.0239 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44189E-09 -9.3547 0.44181E-09 -9.3548 0.99981E+00 -0.0001 54 KCl,aq 0.17078E-09 -9.7676 0.17078E-09 -9.7676 0.10000E+01 0.0000 55 KHSO4,aq 0.81231E-17 -17.0903 0.81231E-17 -17.0903 0.10000E+01 0.0000 56 KOH,aq 0.16918E-07 -7.7717 0.16918E-07 -7.7717 0.10000E+01 0.0000 57 KSO4- 0.25959E-07 -7.5857 0.24571E-07 -7.6096 0.94652E+00 -0.0239 58 MgCO3,aq 0.22948E-11 -11.6393 0.22948E-11 -11.6393 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.41898E-12 -12.3778 0.39661E-12 -12.4016 0.94662E+00 -0.0238 60 MgCl+ 0.26341E-12 -12.5794 0.24935E-12 -12.6032 0.94662E+00 -0.0238 61 MgOH+ 0.28619E-09 -9.5433 0.27092E-09 -9.5672 0.94662E+00 -0.0238 63 MnO,aq 0.30388E-09 -9.5173 0.30388E-09 -9.5173 0.10000E+01 0.0000 64 MnOH+ 0.17826E-08 -8.7489 0.16874E-08 -8.7728 0.94662E+00 -0.0238 65 MnO2-2 0.34235E-14 -14.4655 0.29009E-14 -14.5375 0.84736E+00 -0.0719 66 HMnO2- 0.12639E-11 -11.8983 0.11963E-11 -11.9222 0.94652E+00 -0.0239 69 MnCl+ 0.87067E-12 -12.0601 0.82419E-12 -12.0840 0.94662E+00 -0.0238 70 MnSO4,aq 0.63816E-11 -11.1951 0.63816E-11 -11.1951 0.10000E+01 0.0000 71 NaCl,aq 0.27600E-07 -7.5591 0.27600E-07 -7.5591 0.10000E+01 0.0000 72 NaOH,aq 0.14944E-06 -6.8255 0.14944E-06 -6.8255 0.10000E+01 0.0000 74 OH- 0.33299E-03 -3.4776 0.31515E-03 -3.5015 0.94642E+00 -0.0239 79 HPO3-2 0.25635E-18 -18.5912 0.21722E-18 -18.6631 0.84736E+00 -0.0719 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.54875E-08 -8.2606 0.51943E-08 -8.2845 0.94657E+00 -0.0238 84 PO4-3 0.10115E-09 -9.9950 0.71421E-10 -10.1462 0.70607E+00 -0.1512 87 H2P2O7-2 0.24921E-17 -17.6034 0.21117E-17 -17.6754 0.84736E+00 -0.0719 88 HP2O7-3 0.32309E-15 -15.4907 0.22750E-15 -15.6430 0.70414E+00 -0.1523 89 P2O7-4 0.54173E-16 -16.2662 0.29486E-16 -16.5304 0.54430E+00 -0.2642 90 H2S,aq 0.44532E-15 -15.3513 0.44523E-15 -15.3514 0.99981E+00 -0.0001 97 SO3-2 0.15338E-14 -14.8142 0.13007E-14 -14.8858 0.84805E+00 -0.0716 98 HSO3- 0.15307E-15 -15.8151 0.14488E-15 -15.8390 0.94652E+00 -0.0239 99 HSO4- 0.40281E-10 -10.3949 0.38133E-10 -10.4187 0.94667E+00 -0.0238 Charge balance for all species = -.5881E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2010220E-08 -.6204857E-03 -.6253595E+00 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9999162E+06 0.0000 3 Cl- 0.1379585E-03 0.1379863E-03 0.4891616E+01 4.8364 4 SO4-- 0.2547853E-04 0.2550674E-04 0.2450012E+01 12.7753 5 HCO3- 0.1235353E-04 0.1307115E-04 0.7974976E+00 3.7884 6 HS- 0.8225324E-13 -.2768628E-10 -.9155632E-06 -4.3882 7 Al+++ 0.5904585E-23 0.1932262E-04 0.5213091E+00 2.7803 8 H4SiO4 0.3829605E-03 0.5923785E-03 0.5693189E+02 -3.4168 9 Ca++ 0.3824827E-06 0.4012744E-06 0.1608092E-01 10.9515 10 Mg++ 0.1558630E-08 0.1855434E-08 0.4510551E-04 8.5615 11 Fe++ 0.9218640E-11 0.1852866E-08 0.1034683E-03 6.3335 12 K+ 0.7802913E-04 0.7807218E-04 0.3052520E+01 4.5889 13 Na+ 0.6838833E-03 0.6860785E-03 0.1577147E+02 5.5316 14 Mn++ 0.1231273E-08 0.3326273E-08 0.1827233E-03 8.4592 15 HPO4-- 0.1836767E-06 0.1892654E-06 0.1816396E-01 10.6331 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6924978E-02 -.6204310E-03 -.6304547E-02 0.0000000E+00 2 H2O 0.5550300E+02 0.5550352E+02 -.5259718E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3711639E-04 0.2550450E-04 0.1161189E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1161192E-04 -.2768384E-10 -.1161189E-04 0.0000000E+00 7 Al+++ 0.1366251E-02 0.1932091E-04 0.1346930E-02 0.0000000E+00 8 H4SiO4 0.4362956E-02 0.5923264E-03 0.3770630E-02 0.0000000E+00 9 Ca++ 0.4963808E-03 0.4012391E-06 0.4959796E-03 0.0000000E+00 10 Mg++ 0.3325397E-03 0.1855271E-08 0.3325378E-03 0.0000000E+00 11 Fe++ 0.2987506E-03 0.1852703E-08 0.2987487E-03 0.0000000E+00 12 K+ 0.8895966E-04 0.7806530E-04 0.1089436E-04 0.0000000E+00 13 Na+ 0.6860181E-03 0.6860181E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.7264872E-05 0.3325980E-08 0.7261546E-05 0.0000000E+00 15 HPO4-- 0.2479465E-05 0.1892487E-06 0.2290216E-05 0.0000000E+00 Chg. balance for solid moles: -.7877E-18 Mass of aqueous solution: 0.999996E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.4190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7634E-06 -6.117 0.3835E-03 -3.416 0.8932E-01 0.1219E-03 clinochlore 0.6651E-04 -4.177 0.3697E-01 -1.432 8.610 0.1406E-01 daphnite 0.4117E-04 -4.385 0.2938E-01 -1.532 6.842 0.8902E-02 chlorite-Mn 0.1452E-05 -5.838 0.1030E-02 -2.987 0.2398 0.3281E-03 hematite 0.4645E-04 -4.333 0.7418E-02 -2.130 1.728 0.1406E-02 kaolinite 0.5583E-04 -4.253 0.1441E-01 -1.841 3.357 0.5546E-02 lawsonite 0.2925E-04 -4.534 0.9191E-02 -2.037 2.141 0.2964E-02 muscovite 0.1089E-04 -4.963 0.4339E-02 -2.363 1.011 0.1534E-02 stilbite 0.4629E-03 -3.334 0.3262 -0.486 75.98 0.1522 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.429342 g Volume = 0.187020 cm3 Porosity: 83.9825% V(tot) - V(min): 0.98058E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.4190000 g log = -0.3778 Original solution: 1000.0103000 g Original solution / Rock added: 2386.66 (Water/Rock Ratio), log = 3.3778 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.4848E-05 1.0073 0.5137E-05 0.5099E-05 CH4,gas 0.6140E-16 1.0129 0.6543E-16 0.6459E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.1240E-13 0.9959 0.1299E-13 0.1304E-13 S2,gas 0.1635E-34 1.0000 0.1720E-34 0.1720E-34 CO,gas 0.7665E-15 1.0000 0.8063E-15 0.8063E-15 SO3,gas 0.2780E-37 1.0000 0.2924E-37 0.2924E-37 SO2,gas 0.6373E-21 1.0000 0.6704E-21 0.6704E-21 HCl,gas 0.7847E-16 1.0000 0.8255E-16 0.8255E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.48529E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.48529E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.18198E-10 102 lawsonite 9.68 9.68 0.00 0.000 -0.24265E-10 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.65 -7.29 -2.430 0.12446E+05 -5.289 3 CH4,gas 4.81 -13.38 -18.18 -4.546 0.31049E+05 -16.184 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.83 -15.89 -7.943 0.27126E+05 -13.887 6 S2,gas -7.03 -43.80 -36.76 -5.656 0.62774E+05 -34.764 7 CO,gas 3.51 -13.58 -17.09 -5.260 0.29187E+05 -15.094 8 SO3,gas 17.43 -22.11 -39.53 -9.883 0.67503E+05 -37.534 9 SO2,gas 1.14 -22.04 -23.17 -6.180 0.39568E+05 -21.174 10 HCl,gas 5.48 -12.60 -18.08 -9.042 0.30877E+05 -16.083 11 acmite 7.74 5.00 -2.74 -0.285 0.46797E+04 15 albite-high 0.75 -1.94 -2.69 -0.207 0.45902E+04 16 albite -0.33 -1.94 -1.61 -0.124 0.27496E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65948E+04 20 analcite 3.37 1.48 -1.89 -0.210 0.32313E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 16.12 -4.09 -0.227 0.69839E+04 27 phlogopite 27.15 22.80 -4.34 -0.241 0.74161E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.70 -3.69 -1.229 0.62958E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.70 -3.53 -1.178 0.60345E+04 38 carnegieite-low 9.06 4.90 -4.17 -0.596 0.71194E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.26 -3.14 -0.185 0.53566E+04 43 celadonite-Fe 3.94 0.04 -3.90 -0.230 0.66620E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14690E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.88 -4.61 -0.384 0.78751E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.48 -2.77 -0.277 0.47344E+04 97 kalsilite 7.62 3.95 -3.67 -0.524 0.62629E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.54 -3.63 -0.363 0.62018E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -2.88 -0.45 -0.035 0.76761E+03 121 paragonite 4.34 3.62 -0.71 -0.042 0.12204E+04 122 nepheline 8.38 4.90 -3.48 -0.498 0.59473E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40530E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.19 -4.23 -1.412 0.72308E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41322E+04 153 sanidine -1.22 -2.88 -1.66 -0.128 0.28354E+04 155 siderite -2.59 -7.32 -4.73 -1.577 0.80787E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.19 -0.99 -0.030 0.16933E+04 165 stilpnomelane-Mg 27.60 23.33 -4.27 -0.127 0.72881E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77453E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78738E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.55 -3.11 -0.191 0.53144E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.24 -2.98 -0.182 0.50871E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.68 -2.52 -0.155 0.43092E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.37 -2.41 -0.148 0.41201E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.49 -0.91 -0.059 0.15610E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.80 -0.78 -0.050 0.13354E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.38 -1.69 -0.130 0.28933E+04 243 an25ab75 2.71 0.97 -1.74 -0.134 0.29771E+04 244 an30ab70 3.34 1.55 -1.80 -0.138 0.30693E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.4190000 g New total amount of reactant added: 0.4390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5880E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.4390000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .6112640E-03 Osmotic coef. = 0.9855 True ionic strength = .8114508E-03 Chg. balance for total moles = -.5880E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.19362E-08 -8.7130 0.18324E-08 -8.7370 0.94638E+00 -0.0239 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.13052E-03 -3.8843 0.94605E+00 -0.0241 4 SO4-- 0.25480E-04 -4.5938 0.21551E-04 -4.6665 0.84580E+00 -0.0727 5 HCO3- 0.12330E-04 -4.9090 0.11666E-04 -4.9331 0.94613E+00 -0.0240 6 HS- 0.79075E-13 -13.1020 0.74810E-13 -13.1260 0.94606E+00 -0.0241 7 Al+++ 0.52920E-23 -23.2764 0.37097E-23 -23.4307 0.70101E+00 -0.1543 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.35520E-06 -6.4495 0.30030E-06 -6.5224 0.84545E+00 -0.0729 10 Mg++ 0.14475E-08 -8.8394 0.12234E-08 -8.9124 0.84523E+00 -0.0730 11 Fe++ 0.85611E-11 -11.0675 0.72366E-11 -11.1405 0.84528E+00 -0.0730 12 K+ 0.75158E-04 -4.1240 0.71110E-04 -4.1481 0.94615E+00 -0.0240 13 Na+ 0.70883E-03 -3.1495 0.67058E-03 -3.1735 0.94604E+00 -0.0241 14 Mn++ 0.11435E-08 -8.9418 0.96662E-09 -9.0147 0.84532E+00 -0.0730 15 HPO4-- 0.19856E-06 -6.7021 0.16795E-06 -6.7748 0.84581E+00 -0.0727 16 HSiO3- 0.21553E-03 -3.6665 0.20391E-03 -3.6906 0.94605E+00 -0.0241 17 Ca(HSiO3)+ 0.14500E-08 -8.8386 0.13720E-08 -8.8627 0.94616E+00 -0.0240 18 Mg(HSiO3)+ 0.73519E-11 -11.1336 0.69561E-11 -11.1576 0.94616E+00 -0.0240 19 NaHSiO3,aq 0.21717E-05 -5.6632 0.21717E-05 -5.6632 0.10000E+01 0.0000 20 AlO+ 0.15075E-12 -12.8218 0.14263E-12 -12.8458 0.94616E+00 -0.0240 21 AlOH+2 0.15487E-17 -17.8100 0.13092E-17 -17.8830 0.84537E+00 -0.0730 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.20065E-04 -4.6976 0.18980E-04 -4.7217 0.94595E+00 -0.0241 24 CH4,aq 0.39744E-19 -19.4007 0.39736E-19 -19.4008 0.99981E+00 -0.0001 29 CO,aq 0.49041E-18 -18.3094 0.49041E-18 -18.3094 0.10000E+01 0.0000 30 CO2,aq 0.43107E-07 -7.3655 0.43099E-07 -7.3655 0.99981E+00 -0.0001 31 CO3-2 0.69602E-06 -6.1574 0.58862E-06 -6.2302 0.84570E+00 -0.0728 32 CaCO3,aq 0.21650E-08 -8.6646 0.21650E-08 -8.6646 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.93295E-10 -10.0301 0.88271E-10 -10.0542 0.94616E+00 -0.0240 34 CaCl+ 0.66010E-10 -10.1804 0.62456E-10 -10.2044 0.94616E+00 -0.0240 35 CaCl2,aq 0.18980E-14 -14.7217 0.18980E-14 -14.7217 0.10000E+01 0.0000 36 CaOH+ 0.12214E-07 -7.9132 0.11556E-07 -7.9372 0.94616E+00 -0.0240 37 CaSO4,aq 0.20165E-08 -8.6954 0.20165E-08 -8.6954 0.10000E+01 0.0000 38 HCl,aq 0.44985E-13 -13.3469 0.44985E-13 -13.3469 0.10000E+01 0.0000 43 FeCl+ 0.15548E-14 -14.8083 0.14710E-14 -14.8324 0.94616E+00 -0.0240 46 FeO,aq 0.85225E-10 -10.0694 0.85225E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.13838E-09 -9.8589 0.13093E-09 -9.8830 0.94616E+00 -0.0240 48 HFeO2- 0.52879E-09 -9.2767 0.50026E-09 -9.3008 0.94605E+00 -0.0241 49 FeO+ 0.16021E-13 -13.7953 0.15158E-13 -13.8194 0.94616E+00 -0.0240 51 FeO2- 0.93785E-09 -9.0279 0.88725E-09 -9.0520 0.94605E+00 -0.0241 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44189E-09 -9.3547 0.44181E-09 -9.3548 0.99981E+00 -0.0001 54 KCl,aq 0.16433E-09 -9.7843 0.16433E-09 -9.7843 0.10000E+01 0.0000 55 KHSO4,aq 0.75145E-17 -17.1241 0.75145E-17 -17.1241 0.10000E+01 0.0000 56 KOH,aq 0.16918E-07 -7.7717 0.16918E-07 -7.7717 0.10000E+01 0.0000 57 KSO4- 0.24956E-07 -7.6028 0.23610E-07 -7.6269 0.94605E+00 -0.0241 58 MgCO3,aq 0.22039E-11 -11.6568 0.22039E-11 -11.6568 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.38758E-12 -12.4116 0.36671E-12 -12.4357 0.94616E+00 -0.0240 60 MgCl+ 0.24414E-12 -12.6124 0.23099E-12 -12.6364 0.94616E+00 -0.0240 61 MgOH+ 0.27566E-09 -9.5596 0.26082E-09 -9.5837 0.94616E+00 -0.0240 63 MnO,aq 0.30390E-09 -9.5173 0.30390E-09 -9.5173 0.10000E+01 0.0000 64 MnOH+ 0.17171E-08 -8.7652 0.16246E-08 -8.7893 0.94616E+00 -0.0240 65 MnO2-2 0.37011E-14 -14.4317 0.31300E-14 -14.5045 0.84570E+00 -0.0728 66 HMnO2- 0.13135E-11 -11.8816 0.12427E-11 -11.9056 0.94605E+00 -0.0241 69 MnCl+ 0.80700E-12 -12.0931 0.76355E-12 -12.1172 0.94616E+00 -0.0240 70 MnSO4,aq 0.59037E-11 -11.2289 0.59037E-11 -11.2289 0.10000E+01 0.0000 71 NaCl,aq 0.28578E-07 -7.5440 0.28578E-07 -7.5440 0.10000E+01 0.0000 72 NaOH,aq 0.16080E-06 -6.7937 0.16080E-06 -6.7937 0.10000E+01 0.0000 74 OH- 0.34605E-03 -3.4609 0.32735E-03 -3.4850 0.94595E+00 -0.0241 79 HPO3-2 0.27712E-18 -18.5573 0.23436E-18 -18.6301 0.84570E+00 -0.0728 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.57028E-08 -8.2439 0.53955E-08 -8.2680 0.94610E+00 -0.0241 84 PO4-3 0.11386E-09 -9.9436 0.80042E-10 -10.0967 0.70301E+00 -0.1530 87 H2P2O7-2 0.26941E-17 -17.5696 0.22784E-17 -17.6424 0.84570E+00 -0.0728 88 HP2O7-3 0.36369E-15 -15.4393 0.25496E-15 -15.5935 0.70103E+00 -0.1543 89 P2O7-4 0.63558E-16 -16.1968 0.34325E-16 -16.4644 0.54005E+00 -0.2676 90 H2S,aq 0.41195E-15 -15.3852 0.41187E-15 -15.3852 0.99981E+00 -0.0001 97 SO3-2 0.15338E-14 -14.8142 0.12982E-14 -14.8866 0.84641E+00 -0.0724 98 HSO3- 0.14716E-15 -15.8322 0.13922E-15 -15.8563 0.94605E+00 -0.0241 99 HSO4- 0.38724E-10 -10.4120 0.36641E-10 -10.4360 0.94621E+00 -0.0240 Charge balance for all species = -.5880E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1936232E-08 -.6449077E-03 -.6499725E+00 0.0000 2 H2O 0.1000000E+01 0.5550842E+02 0.9999149E+06 0.0000 3 Cl- 0.1379580E-03 0.1379868E-03 0.4891627E+01 4.8526 4 SO4-- 0.2547979E-04 0.2550684E-04 0.2450017E+01 12.8074 5 HCO3- 0.1232981E-04 0.1307120E-04 0.7974994E+00 3.8039 6 HS- 0.7907498E-13 -.3211450E-10 -.1062000E-05 -4.3891 7 Al+++ 0.5292003E-23 0.2008010E-04 0.5417446E+00 2.7803 8 H4SiO4 0.3829605E-03 0.6006684E-03 0.5772852E+02 -3.4168 9 Ca++ 0.3551998E-06 0.3732041E-06 0.1495599E-01 10.9515 10 Mg++ 0.1447460E-08 0.1733310E-08 0.4213662E-04 8.5615 11 Fe++ 0.8561102E-11 0.1902286E-08 0.1062278E-03 6.3335 12 K+ 0.7515767E-04 0.7519971E-04 0.2940206E+01 4.5889 13 Na+ 0.7088271E-03 0.7111882E-03 0.1634867E+02 5.5634 14 Mn++ 0.1143495E-08 0.3172484E-08 0.1742750E-03 8.4592 15 HPO4-- 0.1985631E-06 0.2043798E-06 0.1961448E-01 10.6991 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7256148E-02 -.6448486E-03 -.6611300E-02 0.0000000E+00 2 H2O 0.5550275E+02 0.5550333E+02 -.5813498E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3767066E-04 0.2550450E-04 0.1216615E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1216619E-04 -.3211156E-10 -.1216615E-04 0.0000000E+00 7 Al+++ 0.1431466E-02 0.2007825E-04 0.1411387E-02 0.0000000E+00 8 H4SiO4 0.4571212E-02 0.6006133E-03 0.3970598E-02 0.0000000E+00 9 Ca++ 0.5193837E-03 0.3731699E-06 0.5190105E-03 0.0000000E+00 10 Mg++ 0.3484127E-03 0.1733151E-08 0.3484110E-03 0.0000000E+00 11 Fe++ 0.3130108E-03 0.1902111E-08 0.3130089E-03 0.0000000E+00 12 K+ 0.9320594E-04 0.7519281E-04 0.1801313E-04 0.0000000E+00 13 Na+ 0.7111230E-03 0.7111230E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.7611644E-05 0.3172193E-08 0.7608471E-05 0.0000000E+00 15 HPO4-- 0.2597816E-05 0.2043611E-06 0.2393455E-05 0.0000000E+00 Chg. balance for solid moles: -.8436E-18 Mass of aqueous solution: 0.999994E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.4390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7978E-06 -6.098 0.4008E-03 -3.397 0.8877E-01 0.1273E-03 clinochlore 0.6968E-04 -4.157 0.3873E-01 -1.412 8.580 0.1473E-01 daphnite 0.4314E-04 -4.365 0.3078E-01 -1.512 6.818 0.9327E-02 chlorite-Mn 0.1522E-05 -5.818 0.1079E-02 -2.967 0.2390 0.3438E-03 hematite 0.4866E-04 -4.313 0.7772E-02 -2.109 1.722 0.1473E-02 kaolinite 0.4931E-04 -4.307 0.1273E-01 -1.895 2.820 0.4898E-02 lawsonite 0.2605E-04 -4.584 0.8185E-02 -2.087 1.813 0.2639E-02 muscovite 0.1801E-04 -4.744 0.7175E-02 -2.144 1.589 0.2537E-02 stilbite 0.4890E-03 -3.311 0.3446 -0.463 76.33 0.1607 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.451441 g Volume = 0.196801 cm3 Porosity: 83.2595% V(tot) - V(min): 0.97880E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.4390000 g log = -0.3575 Original solution: 1000.0103000 g Original solution / Rock added: 2277.93 (Water/Rock Ratio), log = 3.3575 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.4656E-05 1.0073 0.4933E-05 0.4898E-05 CH4,gas 0.5897E-16 1.0129 0.6284E-16 0.6204E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.1147E-13 0.9959 0.1201E-13 0.1206E-13 S2,gas 0.1399E-34 1.0000 0.1472E-34 0.1472E-34 CO,gas 0.7361E-15 1.0000 0.7744E-15 0.7744E-15 SO3,gas 0.2572E-37 1.0000 0.2705E-37 0.2705E-37 SO2,gas 0.5895E-21 1.0000 0.6202E-21 0.6202E-21 HCl,gas 0.7551E-16 1.0000 0.7943E-16 0.7943E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.67 -7.31 -2.436 0.12476E+05 -5.307 3 CH4,gas 4.81 -13.39 -18.20 -4.550 0.31079E+05 -16.202 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.86 -15.92 -7.960 0.27184E+05 -13.920 6 S2,gas -7.03 -43.86 -36.83 -5.666 0.62890E+05 -34.832 7 CO,gas 3.51 -13.60 -17.11 -5.265 0.29217E+05 -15.111 8 SO3,gas 17.43 -22.14 -39.57 -9.892 0.67561E+05 -37.568 9 SO2,gas 1.14 -22.07 -23.21 -6.189 0.39626E+05 -21.208 10 HCl,gas 5.48 -12.62 -18.10 -9.050 0.30905E+05 -16.100 11 acmite 7.74 5.03 -2.71 -0.281 0.46253E+04 15 albite-high 0.75 -1.91 -2.66 -0.204 0.45359E+04 16 albite -0.33 -1.91 -1.58 -0.121 0.26952E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65947E+04 20 analcite 3.37 1.51 -1.86 -0.207 0.31770E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 16.12 -4.09 -0.227 0.69839E+04 27 phlogopite 27.15 22.80 -4.34 -0.241 0.74161E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.72 -3.70 -1.235 0.63258E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.72 -3.55 -1.184 0.60645E+04 38 carnegieite-low 9.06 4.93 -4.14 -0.591 0.70650E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.26 -3.14 -0.185 0.53566E+04 43 celadonite-Fe 3.94 0.04 -3.90 -0.230 0.66620E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14689E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.88 -4.61 -0.384 0.78751E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.51 -2.74 -0.274 0.46800E+04 97 kalsilite 7.62 3.95 -3.67 -0.524 0.62629E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.54 -3.63 -0.363 0.62018E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -2.88 -0.45 -0.035 0.76761E+03 121 paragonite 4.34 3.65 -0.68 -0.040 0.11661E+04 122 nepheline 8.38 4.93 -3.45 -0.493 0.58929E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58500E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40530E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.21 -4.25 -1.417 0.72607E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41322E+04 153 sanidine -1.22 -2.88 -1.66 -0.128 0.28354E+04 155 siderite -2.59 -7.34 -4.75 -1.583 0.81086E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.19 -0.99 -0.030 0.16933E+04 165 stilpnomelane-Mg 27.60 23.33 -4.27 -0.127 0.72881E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77454E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78737E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.55 -3.11 -0.191 0.53144E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.23 -2.97 -0.182 0.50692E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.68 -2.52 -0.155 0.43092E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.36 -2.40 -0.147 0.41021E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.49 -0.91 -0.059 0.15610E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.81 -0.77 -0.050 0.13175E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.41 -1.67 -0.128 0.28498E+04 243 an25ab75 2.71 0.99 -1.72 -0.132 0.29363E+04 244 an30ab70 3.34 1.57 -1.78 -0.137 0.30312E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.4390000 g New total amount of reactant added: 0.4590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5878E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.4590000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .6258941E-03 Osmotic coef. = 0.9853 True ionic strength = .8336707E-03 Chg. balance for total moles = -.5878E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.18670E-08 -8.7288 0.17661E-08 -8.7530 0.94593E+00 -0.0241 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.13045E-03 -3.8846 0.94559E+00 -0.0243 4 SO4-- 0.25481E-04 -4.5938 0.21510E-04 -4.6674 0.84416E+00 -0.0736 5 HCO3- 0.12306E-04 -4.9099 0.11637E-04 -4.9342 0.94567E+00 -0.0243 6 HS- 0.76105E-13 -13.1186 0.71965E-13 -13.1429 0.94560E+00 -0.0243 7 Al+++ 0.47588E-23 -23.3225 0.33213E-23 -23.4787 0.69793E+00 -0.1562 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.33060E-06 -6.4807 0.27896E-06 -6.5545 0.84380E+00 -0.0738 10 Mg++ 0.13472E-08 -8.8706 0.11365E-08 -8.9444 0.84357E+00 -0.0739 11 Fe++ 0.79682E-11 -11.0986 0.67222E-11 -11.1725 0.84363E+00 -0.0738 12 K+ 0.72473E-04 -4.1398 0.68536E-04 -4.1641 0.94568E+00 -0.0243 13 Na+ 0.73376E-03 -3.1344 0.69383E-03 -3.1587 0.94558E+00 -0.0243 14 Mn++ 0.10643E-08 -8.9729 0.89794E-09 -9.0468 0.84367E+00 -0.0738 15 HPO4-- 0.21417E-06 -6.6692 0.18080E-06 -6.7428 0.84417E+00 -0.0736 16 HSiO3- 0.22374E-03 -3.6503 0.21156E-03 -3.6746 0.94559E+00 -0.0243 17 Ca(HSiO3)+ 0.13982E-08 -8.8544 0.13223E-08 -8.8787 0.94569E+00 -0.0242 18 Mg(HSiO3)+ 0.70893E-11 -11.1494 0.67043E-11 -11.1736 0.94569E+00 -0.0242 19 NaHSiO3,aq 0.23314E-05 -5.6324 0.23314E-05 -5.6324 0.10000E+01 0.0000 20 AlO+ 0.14536E-12 -12.8376 0.13747E-12 -12.8618 0.94569E+00 -0.0242 21 AlOH+2 0.14414E-17 -17.8412 0.12162E-17 -17.9150 0.84372E+00 -0.0738 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.20828E-04 -4.6813 0.19693E-04 -4.7057 0.94549E+00 -0.0243 24 CH4,aq 0.38212E-19 -19.4178 0.38204E-19 -19.4179 0.99981E+00 -0.0001 29 CO,aq 0.47151E-18 -18.3265 0.47151E-18 -18.3265 0.10000E+01 0.0000 30 CO2,aq 0.41446E-07 -7.3825 0.41438E-07 -7.3826 0.99981E+00 -0.0001 31 CO3-2 0.72180E-06 -6.1416 0.60924E-06 -6.2152 0.84405E+00 -0.0736 32 CaCO3,aq 0.20815E-08 -8.6816 0.20815E-08 -8.6816 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.86494E-10 -10.0630 0.81797E-10 -10.0873 0.94569E+00 -0.0242 34 CaCl+ 0.61318E-10 -10.2124 0.57988E-10 -10.2367 0.94569E+00 -0.0242 35 CaCl2,aq 0.17613E-14 -14.7542 0.17613E-14 -14.7542 0.10000E+01 0.0000 36 CaOH+ 0.11777E-07 -7.9290 0.11138E-07 -7.9532 0.94569E+00 -0.0242 37 CaSO4,aq 0.18696E-08 -8.7283 0.18696E-08 -8.7283 0.10000E+01 0.0000 38 HCl,aq 0.43335E-13 -13.3632 0.43335E-13 -13.3632 0.10000E+01 0.0000 43 FeCl+ 0.14442E-14 -14.8404 0.13658E-14 -14.8646 0.94569E+00 -0.0242 46 FeO,aq 0.85225E-10 -10.0694 0.85225E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.13343E-09 -9.8747 0.12619E-09 -9.8990 0.94569E+00 -0.0242 48 HFeO2- 0.54892E-09 -9.2605 0.51905E-09 -9.2848 0.94559E+00 -0.0243 49 FeO+ 0.15448E-13 -13.8111 0.14609E-13 -13.8354 0.94569E+00 -0.0242 51 FeO2- 0.97355E-09 -9.0116 0.92057E-09 -9.0359 0.94559E+00 -0.0243 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44189E-09 -9.3547 0.44181E-09 -9.3548 0.99981E+00 -0.0001 54 KCl,aq 0.15831E-09 -9.8005 0.15831E-09 -9.8005 0.10000E+01 0.0000 55 KHSO4,aq 0.69671E-17 -17.1569 0.69671E-17 -17.1569 0.10000E+01 0.0000 56 KOH,aq 0.16918E-07 -7.7717 0.16918E-07 -7.7717 0.10000E+01 0.0000 57 KSO4- 0.24019E-07 -7.6194 0.22712E-07 -7.6437 0.94559E+00 -0.0243 58 MgCO3,aq 0.21190E-11 -11.6739 0.21190E-11 -11.6739 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.35933E-12 -12.4445 0.33982E-12 -12.4688 0.94569E+00 -0.0242 60 MgCl+ 0.22678E-12 -12.6444 0.21446E-12 -12.6686 0.94569E+00 -0.0242 61 MgOH+ 0.26581E-09 -9.5754 0.25138E-09 -9.5997 0.94569E+00 -0.0242 63 MnO,aq 0.30391E-09 -9.5173 0.30391E-09 -9.5173 0.10000E+01 0.0000 64 MnOH+ 0.16558E-08 -8.7810 0.15659E-08 -8.8052 0.94569E+00 -0.0242 65 MnO2-2 0.39922E-14 -14.3988 0.33697E-14 -14.4724 0.84405E+00 -0.0736 66 HMnO2- 0.13636E-11 -11.8653 0.12894E-11 -11.8896 0.94559E+00 -0.0243 69 MnCl+ 0.74966E-12 -12.1251 0.70895E-12 -12.1494 0.94569E+00 -0.0242 70 MnSO4,aq 0.54738E-11 -11.2617 0.54738E-11 -11.2617 0.10000E+01 0.0000 71 NaCl,aq 0.29554E-07 -7.5294 0.29554E-07 -7.5294 0.10000E+01 0.0000 72 NaOH,aq 0.17263E-06 -6.7629 0.17263E-06 -6.7629 0.10000E+01 0.0000 74 OH- 0.35922E-03 -3.4446 0.33964E-03 -3.4690 0.94549E+00 -0.0243 79 HPO3-2 0.29891E-18 -18.5245 0.25230E-18 -18.5981 0.84405E+00 -0.0736 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.59199E-08 -8.2277 0.55981E-08 -8.2520 0.94564E+00 -0.0243 84 PO4-3 0.12772E-09 -9.8937 0.89403E-10 -10.0486 0.69997E+00 -0.1549 87 H2P2O7-2 0.29059E-17 -17.5367 0.24527E-17 -17.6104 0.84405E+00 -0.0736 88 HP2O7-3 0.40801E-15 -15.3893 0.28477E-15 -15.5455 0.69795E+00 -0.1562 89 P2O7-4 0.74233E-16 -16.1294 0.39779E-16 -16.4003 0.53587E+00 -0.2709 90 H2S,aq 0.38194E-15 -15.4180 0.38187E-15 -15.4181 0.99981E+00 -0.0001 97 SO3-2 0.15338E-14 -14.8142 0.12958E-14 -14.8875 0.84478E+00 -0.0733 98 HSO3- 0.14163E-15 -15.8488 0.13392E-15 -15.8731 0.94559E+00 -0.0243 99 HSO4- 0.37270E-10 -10.4286 0.35248E-10 -10.4529 0.94575E+00 -0.0242 Charge balance for all species = -.5729E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1867048E-08 -.6695396E-03 -.6747969E+00 0.0000 2 H2O 0.1000000E+01 0.5550843E+02 0.9999136E+06 0.0000 3 Cl- 0.1379576E-03 0.1379873E-03 0.4891638E+01 4.8684 4 SO4-- 0.2548097E-04 0.2550694E-04 0.2450023E+01 12.8386 5 HCO3- 0.1230583E-04 0.1307125E-04 0.7975012E+00 3.8188 6 HS- 0.7610509E-13 -.3657958E-10 -.1209654E-05 -4.3899 7 Al+++ 0.4758782E-23 0.2084393E-04 0.5623513E+00 2.7803 8 H4SiO4 0.3829605E-03 0.6090325E-03 0.5853230E+02 -3.4168 9 Ca++ 0.3305975E-06 0.3478719E-06 0.1394079E-01 10.9515 10 Mg++ 0.1347213E-08 0.1622822E-08 0.3945060E-04 8.5615 11 Fe++ 0.7968170E-11 0.1952577E-08 0.1090360E-03 6.3335 12 K+ 0.7247265E-04 0.7251375E-04 0.2835185E+01 4.5889 13 Na+ 0.7337645E-03 0.7362980E-03 0.1692587E+02 5.5942 14 Mn++ 0.1064335E-08 0.3031613E-08 0.1665362E-03 8.4592 15 HPO4-- 0.2141739E-06 0.2202216E-06 0.2113480E-01 10.7632 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7587319E-02 -.6694758E-03 -.6917843E-02 0.0000000E+00 2 H2O 0.5550250E+02 0.5550313E+02 -.6363851E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3822492E-04 0.2550451E-04 0.1272042E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1272045E-04 -.3657610E-10 -.1272042E-04 0.0000000E+00 7 Al+++ 0.1496680E-02 0.2084194E-04 0.1475838E-02 0.0000000E+00 8 H4SiO4 0.4779467E-02 0.6089745E-03 0.4170493E-02 0.0000000E+00 9 Ca++ 0.5423865E-03 0.3478387E-06 0.5420387E-03 0.0000000E+00 10 Mg++ 0.3642857E-03 0.1622667E-08 0.3642841E-03 0.0000000E+00 11 Fe++ 0.3272709E-03 0.1952391E-08 0.3272690E-03 0.0000000E+00 12 K+ 0.9745223E-04 0.7250683E-04 0.2494539E-04 0.0000000E+00 13 Na+ 0.7362278E-03 0.7362278E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.7958416E-05 0.3031324E-08 0.7955384E-05 0.0000000E+00 15 HPO4-- 0.2716168E-05 0.2202006E-06 0.2495967E-05 0.0000000E+00 Chg. balance for solid moles: 0.1838E-18 Mass of aqueous solution: 0.999992E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.4590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.8320E-06 -6.080 0.4179E-03 -3.379 0.8826E-01 0.1328E-03 clinochlore 0.7286E-04 -4.138 0.4050E-01 -1.393 8.552 0.1540E-01 daphnite 0.4510E-04 -4.346 0.3218E-01 -1.492 6.796 0.9752E-02 chlorite-Mn 0.1591E-05 -5.798 0.1128E-02 -2.948 0.2382 0.3595E-03 hematite 0.5088E-04 -4.293 0.8126E-02 -2.090 1.716 0.1540E-02 kaolinite 0.4307E-04 -4.366 0.1112E-01 -1.954 2.348 0.4278E-02 lawsonite 0.2286E-04 -4.641 0.7183E-02 -2.144 1.517 0.2316E-02 muscovite 0.2495E-04 -4.603 0.9936E-02 -2.003 2.098 0.3513E-02 stilbite 0.5150E-03 -3.288 0.3629 -0.440 76.65 0.1693 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.473532 g Volume = 0.206580 cm3 Porosity: 82.5465% V(tot) - V(min): 0.97702E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.4590000 g log = -0.3382 Original solution: 1000.0103000 g Original solution / Rock added: 2178.67 (Water/Rock Ratio), log = 3.3382 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.4476E-05 1.0073 0.4743E-05 0.4709E-05 CH4,gas 0.5670E-16 1.0129 0.6042E-16 0.5964E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.1063E-13 0.9959 0.1114E-13 0.1118E-13 S2,gas 0.1203E-34 1.0000 0.1265E-34 0.1265E-34 CO,gas 0.7078E-15 1.0000 0.7445E-15 0.7445E-15 SO3,gas 0.2384E-37 1.0000 0.2508E-37 0.2508E-37 SO2,gas 0.5466E-21 1.0000 0.5750E-21 0.5750E-21 HCl,gas 0.7274E-16 1.0000 0.7652E-16 0.7652E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.69 -7.32 -2.441 0.12505E+05 -5.324 3 CH4,gas 4.81 -13.41 -18.22 -4.555 0.31108E+05 -16.219 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.90 -15.95 -7.977 0.27240E+05 -13.953 6 S2,gas -7.03 -43.93 -36.90 -5.677 0.63002E+05 -34.898 7 CO,gas 3.51 -13.62 -17.13 -5.270 0.29246E+05 -15.128 8 SO3,gas 17.43 -22.17 -39.60 -9.900 0.67617E+05 -37.601 9 SO2,gas 1.14 -22.10 -23.24 -6.197 0.39682E+05 -21.240 10 HCl,gas 5.48 -12.64 -18.12 -9.058 0.30933E+05 -16.116 11 acmite 7.74 5.06 -2.68 -0.278 0.45727E+04 15 albite-high 0.75 -1.88 -2.63 -0.202 0.44832E+04 16 albite -0.33 -1.88 -1.55 -0.119 0.26426E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65946E+04 20 analcite 3.37 1.54 -1.83 -0.203 0.31244E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 16.12 -4.09 -0.227 0.69839E+04 27 phlogopite 27.15 22.80 -4.34 -0.241 0.74161E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.74 -3.72 -1.241 0.63549E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.74 -3.57 -1.190 0.60936E+04 38 carnegieite-low 9.06 4.96 -4.11 -0.587 0.70124E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.26 -3.14 -0.185 0.53566E+04 43 celadonite-Fe 3.94 0.04 -3.90 -0.230 0.66620E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14689E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.88 -4.61 -0.384 0.78751E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.54 -2.71 -0.271 0.46274E+04 97 kalsilite 7.62 3.95 -3.67 -0.524 0.62629E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.54 -3.63 -0.363 0.62018E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -2.88 -0.45 -0.035 0.76761E+03 121 paragonite 4.34 3.68 -0.65 -0.038 0.11134E+04 122 nepheline 8.38 4.96 -3.42 -0.489 0.58403E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58501E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40529E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.23 -4.27 -1.423 0.72898E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41322E+04 153 sanidine -1.22 -2.88 -1.66 -0.128 0.28354E+04 155 siderite -2.59 -7.35 -4.77 -1.589 0.81378E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.19 -0.99 -0.030 0.16933E+04 165 stilpnomelane-Mg 27.60 23.33 -4.27 -0.127 0.72881E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77454E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78737E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.55 -3.11 -0.191 0.53144E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.22 -2.96 -0.181 0.50518E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.68 -2.52 -0.155 0.43092E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.35 -2.39 -0.146 0.40848E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.49 -0.91 -0.059 0.15610E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.82 -0.76 -0.049 0.13001E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.43 -1.64 -0.126 0.28077E+04 243 an25ab75 2.71 1.01 -1.70 -0.131 0.28969E+04 244 an30ab70 3.34 1.59 -1.75 -0.135 0.29944E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.4590000 g New total amount of reactant added: 0.4790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5880E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.4790000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .6406422E-03 Osmotic coef. = 0.9852 True ionic strength = .8560631E-03 Chg. balance for total moles = -.5880E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.18023E-08 -8.7442 0.17040E-08 -8.7685 0.94547E+00 -0.0244 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.13039E-03 -3.8848 0.94513E+00 -0.0245 4 SO4-- 0.25482E-04 -4.5938 0.21469E-04 -4.6682 0.84253E+00 -0.0744 5 HCO3- 0.12282E-04 -4.9107 0.11609E-04 -4.9352 0.94521E+00 -0.0245 6 HS- 0.73326E-13 -13.1347 0.69303E-13 -13.1592 0.94513E+00 -0.0245 7 Al+++ 0.42930E-23 -23.3672 0.29831E-23 -23.5253 0.69489E+00 -0.1581 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.30836E-06 -6.5109 0.25969E-06 -6.5856 0.84216E+00 -0.0746 10 Mg++ 0.12566E-08 -8.9008 0.10580E-08 -8.9755 0.84193E+00 -0.0747 11 Fe++ 0.74322E-11 -11.1289 0.62578E-11 -11.2036 0.84198E+00 -0.0747 12 K+ 0.69958E-04 -4.1552 0.66126E-04 -4.1796 0.94522E+00 -0.0245 13 Na+ 0.75870E-03 -3.1199 0.71706E-03 -3.1444 0.94512E+00 -0.0245 14 Mn++ 0.99277E-09 -9.0032 0.83594E-09 -9.0778 0.84203E+00 -0.0747 15 HPO4-- 0.23051E-06 -6.6373 0.19422E-06 -6.7117 0.84254E+00 -0.0744 16 HSiO3- 0.23201E-03 -3.6345 0.21927E-03 -3.6590 0.94513E+00 -0.0245 17 Ca(HSiO3)+ 0.13497E-08 -8.8698 0.12758E-08 -8.8942 0.94524E+00 -0.0245 18 Mg(HSiO3)+ 0.68433E-11 -11.1647 0.64686E-11 -11.1892 0.94524E+00 -0.0245 19 NaHSiO3,aq 0.24972E-05 -5.6025 0.24972E-05 -5.6025 0.10000E+01 0.0000 20 AlO+ 0.14032E-12 -12.8529 0.13263E-12 -12.8773 0.94524E+00 -0.0245 21 AlOH+2 0.13445E-17 -17.8714 0.11322E-17 -17.9461 0.84208E+00 -0.0746 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.21598E-04 -4.6656 0.20411E-04 -4.6901 0.94502E+00 -0.0246 24 CH4,aq 0.36778E-19 -19.4344 0.36770E-19 -19.4345 0.99980E+00 -0.0001 29 CO,aq 0.45382E-18 -18.3431 0.45382E-18 -18.3431 0.10000E+01 0.0000 30 CO2,aq 0.39890E-07 -7.3991 0.39883E-07 -7.3992 0.99980E+00 -0.0001 31 CO3-2 0.74772E-06 -6.1263 0.62989E-06 -6.2007 0.84242E+00 -0.0745 32 CaCO3,aq 0.20034E-08 -8.6982 0.20034E-08 -8.6982 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.80360E-10 -10.0950 0.75959E-10 -10.1194 0.94524E+00 -0.0245 34 CaCl+ 0.57081E-10 -10.2435 0.53955E-10 -10.2680 0.94524E+00 -0.0245 35 CaCl2,aq 0.16380E-14 -14.7857 0.16380E-14 -14.7857 0.10000E+01 0.0000 36 CaOH+ 0.11369E-07 -7.9443 0.10746E-07 -7.9687 0.94524E+00 -0.0245 37 CaSO4,aq 0.17371E-08 -8.7602 0.17371E-08 -8.7602 0.10000E+01 0.0000 38 HCl,aq 0.41791E-13 -13.3789 0.41791E-13 -13.3789 0.10000E+01 0.0000 43 FeCl+ 0.13444E-14 -14.8715 0.12708E-14 -14.8959 0.94524E+00 -0.0245 46 FeO,aq 0.85225E-10 -10.0694 0.85225E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.12880E-09 -9.8901 0.12175E-09 -9.9145 0.94524E+00 -0.0245 48 HFeO2- 0.56920E-09 -9.2447 0.53796E-09 -9.2692 0.94513E+00 -0.0245 49 FeO+ 0.14912E-13 -13.8265 0.14096E-13 -13.8509 0.94524E+00 -0.0245 51 FeO2- 0.10095E-08 -8.9959 0.95412E-09 -9.0204 0.94513E+00 -0.0245 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44189E-09 -9.3547 0.44180E-09 -9.3548 0.99980E+00 -0.0001 54 KCl,aq 0.15267E-09 -9.8163 0.15267E-09 -9.8163 0.10000E+01 0.0000 55 KHSO4,aq 0.64736E-17 -17.1889 0.64736E-17 -17.1889 0.10000E+01 0.0000 56 KOH,aq 0.16918E-07 -7.7717 0.16918E-07 -7.7717 0.10000E+01 0.0000 57 KSO4- 0.23142E-07 -7.6356 0.21872E-07 -7.6601 0.94513E+00 -0.0245 58 MgCO3,aq 0.20395E-11 -11.6905 0.20395E-11 -11.6905 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.33385E-12 -12.4765 0.31556E-12 -12.5009 0.94524E+00 -0.0245 60 MgCl+ 0.21111E-12 -12.6755 0.19955E-12 -12.6999 0.94524E+00 -0.0245 61 MgOH+ 0.25659E-09 -9.5908 0.24254E-09 -9.6152 0.94524E+00 -0.0245 63 MnO,aq 0.30392E-09 -9.5172 0.30392E-09 -9.5172 0.10000E+01 0.0000 64 MnOH+ 0.15984E-08 -8.7963 0.15109E-08 -8.8208 0.94524E+00 -0.0245 65 MnO2-2 0.42969E-14 -14.3668 0.36198E-14 -14.4413 0.84242E+00 -0.0745 66 HMnO2- 0.14140E-11 -11.8496 0.13364E-11 -11.8741 0.94513E+00 -0.0245 69 MnCl+ 0.69788E-12 -12.1562 0.65967E-12 -12.1807 0.94524E+00 -0.0245 70 MnSO4,aq 0.50862E-11 -11.2936 0.50862E-11 -11.2936 0.10000E+01 0.0000 71 NaCl,aq 0.30528E-07 -7.5153 0.30528E-07 -7.5153 0.10000E+01 0.0000 72 NaOH,aq 0.18491E-06 -6.7330 0.18491E-06 -6.7330 0.10000E+01 0.0000 74 OH- 0.37250E-03 -3.4289 0.35202E-03 -3.4534 0.94502E+00 -0.0246 79 HPO3-2 0.32172E-18 -18.4925 0.27102E-18 -18.5670 0.84242E+00 -0.0745 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.61386E-08 -8.2119 0.58021E-08 -8.2364 0.94518E+00 -0.0245 84 PO4-3 0.14281E-09 -9.8452 0.99537E-10 -10.0020 0.69697E+00 -0.1568 87 H2P2O7-2 0.31276E-17 -17.5048 0.26347E-17 -17.5793 0.84242E+00 -0.0745 88 HP2O7-3 0.45625E-15 -15.3408 0.31706E-15 -15.4989 0.69491E+00 -0.1581 89 P2O7-4 0.86324E-16 -16.0639 0.45902E-16 -16.3382 0.53175E+00 -0.2743 90 H2S,aq 0.35488E-15 -15.4499 0.35481E-15 -15.4500 0.99980E+00 -0.0001 97 SO3-2 0.15339E-14 -14.8142 0.12933E-14 -14.8883 0.84316E+00 -0.0741 98 HSO3- 0.13646E-15 -15.8650 0.12897E-15 -15.8895 0.94513E+00 -0.0245 99 HSO4- 0.35909E-10 -10.4448 0.33945E-10 -10.4692 0.94529E+00 -0.0244 Charge balance for all species = -.5740E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1802265E-08 -.6943634E-03 -.6998146E+00 0.0000 2 H2O 0.1000000E+01 0.5550843E+02 0.9999124E+06 0.0000 3 Cl- 0.1379571E-03 0.1379878E-03 0.4891649E+01 4.8838 4 SO4-- 0.2548207E-04 0.2550704E-04 0.2450029E+01 12.8689 5 HCO3- 0.1228160E-04 0.1307129E-04 0.7975030E+00 3.8333 6 HS- 0.7332605E-13 -.4107825E-10 -.1358419E-05 -4.3907 7 Al+++ 0.4292977E-23 0.2161355E-04 0.5831143E+00 2.7803 8 H4SiO4 0.3829605E-03 0.6174650E-03 0.5934263E+02 -3.4168 9 Ca++ 0.3083571E-06 0.3249535E-06 0.1302233E-01 10.9515 10 Mg++ 0.1256590E-08 0.1522610E-08 0.3701442E-04 8.5615 11 Fe++ 0.7432160E-11 0.2003662E-08 0.1118886E-03 6.3335 12 K+ 0.6995845E-04 0.6999867E-04 0.2736845E+01 4.5889 13 Na+ 0.7586954E-03 0.7614081E-03 0.1750307E+02 5.6241 14 Mn++ 0.9927678E-09 0.2902273E-08 0.1594309E-03 8.4592 15 HPO4-- 0.2305132E-06 0.2367946E-06 0.2272529E-01 10.8253 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7918489E-02 -.6942947E-03 -.7224194E-02 0.0000000E+00 2 H2O 0.5550225E+02 0.5550294E+02 -.6911059E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3877919E-04 0.2550451E-04 0.1327468E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1327472E-04 -.4107418E-10 -.1327468E-04 0.0000000E+00 7 Al+++ 0.1561895E-02 0.2161141E-04 0.1540284E-02 0.0000000E+00 8 H4SiO4 0.4987723E-02 0.6174039E-03 0.4370319E-02 0.0000000E+00 9 Ca++ 0.5653894E-03 0.3249213E-06 0.5650645E-03 0.0000000E+00 10 Mg++ 0.3801587E-03 0.1522460E-08 0.3801572E-03 0.0000000E+00 11 Fe++ 0.3415311E-03 0.2003464E-08 0.3415291E-03 0.0000000E+00 12 K+ 0.1016985E-03 0.6999174E-04 0.3170678E-04 0.0000000E+00 13 Na+ 0.7613327E-03 0.7613327E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.8305187E-05 0.2901986E-08 0.8302285E-05 0.0000000E+00 15 HPO4-- 0.2834519E-05 0.2367711E-06 0.2597748E-05 0.0000000E+00 Chg. balance for solid moles: -.2770E-18 Mass of aqueous solution: 0.999990E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.4790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.8659E-06 -6.063 0.4350E-03 -3.362 0.8776E-01 0.1382E-03 clinochlore 0.7603E-04 -4.119 0.4226E-01 -1.374 8.527 0.1607E-01 daphnite 0.4707E-04 -4.327 0.3358E-01 -1.474 6.776 0.1018E-01 chlorite-Mn 0.1660E-05 -5.780 0.1177E-02 -2.929 0.2375 0.3751E-03 hematite 0.5310E-04 -4.275 0.8480E-02 -2.072 1.711 0.1607E-02 kaolinite 0.3709E-04 -4.431 0.9575E-02 -2.019 1.932 0.3684E-02 lawsonite 0.1968E-04 -4.706 0.6184E-02 -2.209 1.248 0.1994E-02 muscovite 0.3171E-04 -4.499 0.1263E-01 -1.899 2.548 0.4466E-02 stilbite 0.5411E-03 -3.267 0.3813 -0.419 76.93 0.1778 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.495615 g Volume = 0.216358 cm3 Porosity: 81.8431% V(tot) - V(min): 0.97524E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.4790000 g log = -0.3197 Original solution: 1000.0103000 g Original solution / Rock added: 2087.70 (Water/Rock Ratio), log = 3.3197 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.4308E-05 1.0073 0.4565E-05 0.4532E-05 CH4,gas 0.5457E-16 1.0129 0.5815E-16 0.5741E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.9878E-14 0.9959 0.1035E-13 0.1039E-13 S2,gas 0.1038E-34 1.0000 0.1092E-34 0.1092E-34 CO,gas 0.6812E-15 1.0000 0.7166E-15 0.7166E-15 SO3,gas 0.2215E-37 1.0000 0.2331E-37 0.2331E-37 SO2,gas 0.5079E-21 1.0000 0.5342E-21 0.5342E-21 HCl,gas 0.7015E-16 1.0000 0.7379E-16 0.7379E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 120 muscovite 2.68 2.68 0.00 0.000 0.30331E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.70 -7.34 -2.447 0.12534E+05 -5.341 3 CH4,gas 4.81 -13.43 -18.24 -4.559 0.31137E+05 -16.235 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.93 -15.99 -7.993 0.27294E+05 -13.985 6 S2,gas -7.03 -43.99 -36.96 -5.686 0.63111E+05 -34.962 7 CO,gas 3.51 -13.63 -17.14 -5.275 0.29274E+05 -15.145 8 SO3,gas 17.43 -22.21 -39.63 -9.908 0.67671E+05 -37.633 9 SO2,gas 1.14 -22.14 -23.27 -6.206 0.39737E+05 -21.272 10 HCl,gas 5.48 -12.65 -18.13 -9.066 0.30960E+05 -16.132 11 acmite 7.74 5.09 -2.65 -0.275 0.45217E+04 15 albite-high 0.75 -1.85 -2.60 -0.200 0.44323E+04 16 albite -0.33 -1.85 -1.52 -0.117 0.25916E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65945E+04 20 analcite 3.37 1.57 -1.80 -0.200 0.30734E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 16.12 -4.09 -0.227 0.69839E+04 27 phlogopite 27.15 22.80 -4.34 -0.241 0.74161E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.75 -3.74 -1.246 0.63833E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.75 -3.59 -1.195 0.61220E+04 38 carnegieite-low 9.06 4.99 -4.08 -0.582 0.69614E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.26 -3.14 -0.185 0.53566E+04 43 celadonite-Fe 3.94 0.04 -3.90 -0.230 0.66620E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14689E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.88 -4.61 -0.384 0.78751E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.57 -2.68 -0.268 0.45764E+04 97 kalsilite 7.62 3.95 -3.67 -0.524 0.62629E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.54 -3.63 -0.363 0.62018E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -2.88 -0.45 -0.035 0.76761E+03 121 paragonite 4.34 3.71 -0.62 -0.037 0.10625E+04 122 nepheline 8.38 4.99 -3.39 -0.484 0.57894E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58501E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40529E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.24 -4.29 -1.429 0.73182E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41322E+04 153 sanidine -1.22 -2.88 -1.66 -0.128 0.28354E+04 155 siderite -2.59 -7.37 -4.78 -1.594 0.81662E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.19 -0.99 -0.030 0.16933E+04 165 stilpnomelane-Mg 27.60 23.33 -4.27 -0.127 0.72881E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77454E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78736E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.55 -3.11 -0.191 0.53144E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.21 -2.95 -0.181 0.50350E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.68 -2.52 -0.155 0.43092E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.34 -2.38 -0.146 0.40680E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.49 -0.91 -0.059 0.15610E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.83 -0.75 -0.048 0.12833E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.46 -1.62 -0.125 0.27669E+04 243 an25ab75 2.71 1.03 -1.67 -0.129 0.28586E+04 244 an30ab70 3.34 1.61 -1.73 -0.133 0.29587E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.4790000 g New total amount of reactant added: 0.4990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5880E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.4990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .6554983E-03 Osmotic coef. = 0.9850 True ionic strength = .8786128E-03 Chg. balance for total moles = -.5880E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.17415E-08 -8.7591 0.16458E-08 -8.7836 0.94502E+00 -0.0246 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.13032E-03 -3.8850 0.94467E+00 -0.0247 4 SO4-- 0.25483E-04 -4.5937 0.21429E-04 -4.6690 0.84091E+00 -0.0752 5 HCO3- 0.12257E-04 -4.9116 0.11580E-04 -4.9363 0.94475E+00 -0.0247 6 HS- 0.70722E-13 -13.1504 0.66809E-13 -13.1752 0.94468E+00 -0.0247 7 Al+++ 0.38846E-23 -23.4106 0.26877E-23 -23.5706 0.69188E+00 -0.1600 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.28820E-06 -6.5403 0.24224E-06 -6.6157 0.84054E+00 -0.0754 10 Mg++ 0.11745E-08 -8.9302 0.98690E-09 -9.0057 0.84030E+00 -0.0756 11 Fe++ 0.69464E-11 -11.1582 0.58375E-11 -11.2338 0.84036E+00 -0.0755 12 K+ 0.67601E-04 -4.1700 0.63867E-04 -4.1947 0.94477E+00 -0.0247 13 Na+ 0.78362E-03 -3.1059 0.74025E-03 -3.1306 0.94466E+00 -0.0247 14 Mn++ 0.92791E-09 -9.0325 0.77981E-09 -9.1080 0.84040E+00 -0.0755 15 HPO4-- 0.24758E-06 -6.6063 0.20820E-06 -6.6815 0.84092E+00 -0.0752 16 HSiO3- 0.24033E-03 -3.6192 0.22703E-03 -3.6439 0.94467E+00 -0.0247 17 Ca(HSiO3)+ 0.13042E-08 -8.8846 0.12322E-08 -8.9093 0.94478E+00 -0.0247 18 Mg(HSiO3)+ 0.66127E-11 -11.1796 0.62476E-11 -11.2043 0.94478E+00 -0.0247 19 NaHSiO3,aq 0.26692E-05 -5.5736 0.26692E-05 -5.5736 0.10000E+01 0.0000 20 AlO+ 0.13559E-12 -12.8678 0.12810E-12 -12.8924 0.94478E+00 -0.0247 21 AlOH+2 0.12566E-17 -17.9008 0.10561E-17 -17.9763 0.84045E+00 -0.0755 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.22373E-04 -4.6503 0.21133E-04 -4.6750 0.94456E+00 -0.0248 24 CH4,aq 0.35433E-19 -19.4506 0.35426E-19 -19.4507 0.99980E+00 -0.0001 29 CO,aq 0.43723E-18 -18.3593 0.43723E-18 -18.3593 0.10000E+01 0.0000 30 CO2,aq 0.38433E-07 -7.4153 0.38425E-07 -7.4154 0.99980E+00 -0.0001 31 CO3-2 0.77374E-06 -6.1114 0.65056E-06 -6.1867 0.84080E+00 -0.0753 32 CaCO3,aq 0.19302E-08 -8.7144 0.19302E-08 -8.7144 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.74814E-10 -10.1260 0.70683E-10 -10.1507 0.94478E+00 -0.0247 34 CaCl+ 0.53247E-10 -10.2737 0.50307E-10 -10.2984 0.94478E+00 -0.0247 35 CaCl2,aq 0.15265E-14 -14.8163 0.15265E-14 -14.8163 0.10000E+01 0.0000 36 CaOH+ 0.10986E-07 -7.9592 0.10379E-07 -7.9838 0.94478E+00 -0.0247 37 CaSO4,aq 0.16174E-08 -8.7912 0.16174E-08 -8.7912 0.10000E+01 0.0000 38 HCl,aq 0.40344E-13 -13.3942 0.40344E-13 -13.3942 0.10000E+01 0.0000 43 FeCl+ 0.12541E-14 -14.9017 0.11849E-14 -14.9263 0.94478E+00 -0.0247 46 FeO,aq 0.85225E-10 -10.0694 0.85225E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.12446E-09 -9.9050 0.11759E-09 -9.9296 0.94478E+00 -0.0247 48 HFeO2- 0.58962E-09 -9.2294 0.55699E-09 -9.2542 0.94467E+00 -0.0247 49 FeO+ 0.14410E-13 -13.8413 0.13614E-13 -13.8660 0.94478E+00 -0.0247 51 FeO2- 0.10457E-08 -8.9806 0.98787E-09 -9.0053 0.94467E+00 -0.0247 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44189E-09 -9.3547 0.44180E-09 -9.3548 0.99980E+00 -0.0001 54 KCl,aq 0.14738E-09 -9.8316 0.14738E-09 -9.8316 0.10000E+01 0.0000 55 KHSO4,aq 0.60274E-17 -17.2199 0.60274E-17 -17.2199 0.10000E+01 0.0000 56 KOH,aq 0.16918E-07 -7.7717 0.16918E-07 -7.7717 0.10000E+01 0.0000 57 KSO4- 0.22321E-07 -7.6513 0.21085E-07 -7.6760 0.94467E+00 -0.0247 58 MgCO3,aq 0.19649E-11 -11.7067 0.19649E-11 -11.7067 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.31080E-12 -12.5075 0.29364E-12 -12.5322 0.94478E+00 -0.0247 60 MgCl+ 0.19693E-12 -12.7057 0.18606E-12 -12.7304 0.94478E+00 -0.0247 61 MgOH+ 0.24795E-09 -9.6056 0.23425E-09 -9.6303 0.94478E+00 -0.0247 63 MnO,aq 0.30392E-09 -9.5172 0.30392E-09 -9.5172 0.10000E+01 0.0000 64 MnOH+ 0.15446E-08 -8.8112 0.14593E-08 -8.8359 0.94478E+00 -0.0247 65 MnO2-2 0.46153E-14 -14.3358 0.38806E-14 -14.4111 0.84080E+00 -0.0753 66 HMnO2- 0.14648E-11 -11.8342 0.13837E-11 -11.8590 0.94467E+00 -0.0247 69 MnCl+ 0.65103E-12 -12.1864 0.61508E-12 -12.2111 0.94478E+00 -0.0247 70 MnSO4,aq 0.47358E-11 -11.3246 0.47358E-11 -11.3246 0.10000E+01 0.0000 71 NaCl,aq 0.31501E-07 -7.5017 0.31501E-07 -7.5017 0.10000E+01 0.0000 72 NaOH,aq 0.19764E-06 -6.7041 0.19764E-06 -6.7041 0.10000E+01 0.0000 74 OH- 0.38586E-03 -3.4136 0.36447E-03 -3.4383 0.94456E+00 -0.0248 79 HPO3-2 0.34554E-18 -18.4615 0.29053E-18 -18.5368 0.84080E+00 -0.0753 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.63588E-08 -8.1966 0.60073E-08 -8.2213 0.94472E+00 -0.0247 84 PO4-3 0.15919E-09 -9.7981 0.11048E-09 -9.9567 0.69401E+00 -0.1586 87 H2P2O7-2 0.33592E-17 -17.4738 0.28244E-17 -17.5491 0.84080E+00 -0.0753 88 HP2O7-3 0.50861E-15 -15.2936 0.35191E-15 -15.4536 0.69190E+00 -0.1600 89 P2O7-4 0.99965E-16 -16.0002 0.52750E-16 -16.2778 0.52768E+00 -0.2776 90 H2S,aq 0.33043E-15 -15.4809 0.33036E-15 -15.4810 0.99980E+00 -0.0001 97 SO3-2 0.15339E-14 -14.8142 0.12909E-14 -14.8891 0.84156E+00 -0.0749 98 HSO3- 0.13161E-15 -15.8807 0.12433E-15 -15.9054 0.94467E+00 -0.0247 99 HSO4- 0.34634E-10 -10.4605 0.32723E-10 -10.4851 0.94483E+00 -0.0246 Charge balance for all species = -.5743E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1741518E-08 -.7193627E-03 -.7250091E+00 0.0000 2 H2O 0.1000000E+01 0.5550844E+02 0.9999111E+06 0.0000 3 Cl- 0.1379566E-03 0.1379883E-03 0.4891660E+01 4.8987 4 SO4-- 0.2548311E-04 0.2550713E-04 0.2450035E+01 12.8983 5 HCO3- 0.1225716E-04 0.1307134E-04 0.7975048E+00 3.8473 6 HS- 0.7072196E-13 -.4560756E-10 -.1508197E-05 -4.3915 7 Al+++ 0.3884641E-23 0.2238845E-04 0.6040196E+00 2.7803 8 H4SiO4 0.3829605E-03 0.6259603E-03 0.6015901E+02 -3.4168 9 Ca++ 0.2882026E-06 0.3041680E-06 0.1218935E-01 10.9515 10 Mg++ 0.1174466E-08 0.1431497E-08 0.3479941E-04 8.5615 11 Fe++ 0.6946419E-11 0.2055473E-08 0.1147816E-03 6.3335 12 K+ 0.6760090E-04 0.6764028E-04 0.2644632E+01 4.5889 13 Na+ 0.7836199E-03 0.7865183E-03 0.1808027E+02 5.6530 14 Mn++ 0.9279082E-09 0.2783253E-08 0.1528925E-03 8.4593 15 HPO4-- 0.2475844E-06 0.2541024E-06 0.2438630E-01 10.8857 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8249659E-02 -.7192889E-03 -.7530370E-02 0.0000000E+00 2 H2O 0.5550200E+02 0.5550274E+02 -.7455381E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3933346E-04 0.2550452E-04 0.1382895E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1382899E-04 -.4560288E-10 -.1382895E-04 0.0000000E+00 7 Al+++ 0.1627110E-02 0.2238616E-04 0.1604724E-02 0.0000000E+00 8 H4SiO4 0.5195979E-02 0.6258961E-03 0.4570083E-02 0.0000000E+00 9 Ca++ 0.5883922E-03 0.3041368E-06 0.5880881E-03 0.0000000E+00 10 Mg++ 0.3960317E-03 0.1431350E-08 0.3960303E-03 0.0000000E+00 11 Fe++ 0.3557913E-03 0.2055262E-08 0.3557892E-03 0.0000000E+00 12 K+ 0.1059448E-03 0.6763334E-04 0.3831146E-04 0.0000000E+00 13 Na+ 0.7864376E-03 0.7864376E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.8651959E-05 0.2782967E-08 0.8649176E-05 0.0000000E+00 15 HPO4-- 0.2952871E-05 0.2540763E-06 0.2698794E-05 0.0000000E+00 Chg. balance for solid moles: -.2101E-18 Mass of aqueous solution: 0.999987E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.4990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.8996E-06 -6.046 0.4519E-03 -3.345 0.8729E-01 0.1436E-03 clinochlore 0.7921E-04 -4.101 0.4403E-01 -1.356 8.504 0.1675E-01 daphnite 0.4903E-04 -4.310 0.3498E-01 -1.456 6.758 0.1060E-01 chlorite-Mn 0.1730E-05 -5.762 0.1226E-02 -2.911 0.2369 0.3908E-03 hematite 0.5532E-04 -4.257 0.8834E-02 -2.054 1.706 0.1674E-02 kaolinite 0.3134E-04 -4.504 0.8090E-02 -2.092 1.563 0.3113E-02 lawsonite 0.1651E-04 -4.782 0.5189E-02 -2.285 1.002 0.1673E-02 muscovite 0.3831E-04 -4.417 0.1526E-01 -1.816 2.948 0.5396E-02 stilbite 0.5671E-03 -3.246 0.3996 -0.398 77.19 0.1864 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.517692 g Volume = 0.226133 cm3 Porosity: 81.1493% V(tot) - V(min): 0.97347E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.4990000 g log = -0.3019 Original solution: 1000.0103000 g Original solution / Rock added: 2004.03 (Water/Rock Ratio), log = 3.3019 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.4151E-05 1.0073 0.4398E-05 0.4366E-05 CH4,gas 0.5258E-16 1.0129 0.5602E-16 0.5531E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.9197E-14 0.9959 0.9635E-14 0.9675E-14 S2,gas 0.9002E-35 1.0000 0.9470E-35 0.9470E-35 CO,gas 0.6563E-15 1.0000 0.6904E-15 0.6904E-15 SO3,gas 0.2063E-37 1.0000 0.2170E-37 0.2170E-37 SO2,gas 0.4729E-21 1.0000 0.4974E-21 0.4974E-21 HCl,gas 0.6772E-16 1.0000 0.7123E-16 0.7123E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.72794E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.84926E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.18198E-10 102 lawsonite 9.68 9.68 0.00 0.000 -0.24265E-10 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.72 -7.36 -2.452 0.12561E+05 -5.357 3 CH4,gas 4.81 -13.44 -18.25 -4.563 0.31164E+05 -16.252 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.96 -16.02 -8.008 0.27347E+05 -14.016 6 S2,gas -7.03 -44.06 -37.02 -5.696 0.63217E+05 -35.024 7 CO,gas 3.51 -13.65 -17.16 -5.280 0.29302E+05 -15.161 8 SO3,gas 17.43 -22.24 -39.66 -9.916 0.67724E+05 -37.664 9 SO2,gas 1.14 -22.17 -23.30 -6.214 0.39790E+05 -21.303 10 HCl,gas 5.48 -12.67 -18.15 -9.074 0.30986E+05 -16.147 11 acmite 7.74 5.12 -2.62 -0.272 0.44723E+04 15 albite-high 0.75 -1.82 -2.57 -0.197 0.43829E+04 16 albite -0.33 -1.82 -1.49 -0.115 0.25422E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65945E+04 20 analcite 3.37 1.60 -1.77 -0.197 0.30240E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 16.12 -4.09 -0.227 0.69839E+04 27 phlogopite 27.15 22.80 -4.34 -0.241 0.74161E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.77 -3.75 -1.252 0.64109E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.77 -3.60 -1.201 0.61496E+04 38 carnegieite-low 9.06 5.02 -4.05 -0.578 0.69120E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.26 -3.14 -0.185 0.53566E+04 43 celadonite-Fe 3.94 0.04 -3.90 -0.230 0.66620E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14689E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.88 -4.61 -0.384 0.78751E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68767E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.60 -2.65 -0.265 0.45270E+04 97 kalsilite 7.62 3.95 -3.67 -0.524 0.62629E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.54 -3.63 -0.363 0.62018E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -2.88 -0.45 -0.035 0.76761E+03 121 paragonite 4.34 3.74 -0.59 -0.035 0.10131E+04 122 nepheline 8.38 5.02 -3.36 -0.480 0.57400E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58501E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40529E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.26 -4.30 -1.434 0.73458E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41321E+04 153 sanidine -1.22 -2.88 -1.66 -0.128 0.28354E+04 155 siderite -2.59 -7.39 -4.80 -1.600 0.81938E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.19 -0.99 -0.030 0.16933E+04 165 stilpnomelane-Mg 27.60 23.33 -4.27 -0.127 0.72881E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77454E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78736E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.55 -3.11 -0.191 0.53144E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.20 -2.94 -0.180 0.50187E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.68 -2.52 -0.155 0.43092E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.33 -2.37 -0.145 0.40517E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.49 -0.91 -0.059 0.15610E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.84 -0.74 -0.048 0.12670E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.48 -1.60 -0.123 0.27274E+04 243 an25ab75 2.71 1.06 -1.65 -0.127 0.28216E+04 244 an30ab70 3.34 1.63 -1.71 -0.132 0.29241E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.4990000 g New total amount of reactant added: 0.5190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5878E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.5190000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .6704534E-03 Osmotic coef. = 0.9848 True ionic strength = .9013063E-03 Chg. balance for total moles = -.5878E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.16845E-08 -8.7735 0.15911E-08 -8.7983 0.94458E+00 -0.0248 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.13026E-03 -3.8852 0.94421E+00 -0.0249 4 SO4-- 0.25484E-04 -4.5937 0.21389E-04 -4.6698 0.83931E+00 -0.0761 5 HCO3- 0.12233E-04 -4.9125 0.11551E-04 -4.9374 0.94430E+00 -0.0249 6 HS- 0.68278E-13 -13.1657 0.64470E-13 -13.1906 0.94422E+00 -0.0249 7 Al+++ 0.35255E-23 -23.4528 0.24287E-23 -23.6146 0.68891E+00 -0.1618 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.26989E-06 -6.5688 0.22642E-06 -6.6451 0.83893E+00 -0.0763 10 Mg++ 0.10999E-08 -8.9587 0.92244E-09 -9.0351 0.83869E+00 -0.0764 11 Fe++ 0.65052E-11 -11.1867 0.54562E-11 -11.2631 0.83874E+00 -0.0764 12 K+ 0.65387E-04 -4.1845 0.61746E-04 -4.2094 0.94432E+00 -0.0249 13 Na+ 0.80854E-03 -3.0923 0.76343E-03 -3.1172 0.94421E+00 -0.0249 14 Mn++ 0.86899E-09 -9.0610 0.72890E-09 -9.1373 0.83879E+00 -0.0763 15 HPO4-- 0.26539E-06 -6.5761 0.22275E-06 -6.6522 0.83932E+00 -0.0761 16 HSiO3- 0.24870E-03 -3.6043 0.23483E-03 -3.6292 0.94421E+00 -0.0249 17 Ca(HSiO3)+ 0.12615E-08 -8.8991 0.11913E-08 -8.9240 0.94433E+00 -0.0249 18 Mg(HSiO3)+ 0.63962E-11 -11.1941 0.60401E-11 -11.2190 0.94433E+00 -0.0249 19 NaHSiO3,aq 0.28473E-05 -5.5456 0.28473E-05 -5.5456 0.10000E+01 0.0000 20 AlO+ 0.13115E-12 -12.8822 0.12385E-12 -12.9071 0.94433E+00 -0.0249 21 AlOH+2 0.11768E-17 -17.9293 0.98713E-18 -18.0056 0.83884E+00 -0.0763 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.23153E-04 -4.6354 0.21858E-04 -4.6604 0.94410E+00 -0.0250 24 CH4,aq 0.34172E-19 -19.4663 0.34164E-19 -19.4664 0.99979E+00 -0.0001 29 CO,aq 0.42166E-18 -18.3750 0.42166E-18 -18.3750 0.10000E+01 0.0000 30 CO2,aq 0.37064E-07 -7.4310 0.37056E-07 -7.4311 0.99979E+00 -0.0001 31 CO3-2 0.79985E-06 -6.0970 0.67124E-06 -6.1731 0.83920E+00 -0.0761 32 CaCO3,aq 0.18614E-08 -8.7302 0.18614E-08 -8.7302 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.69787E-10 -10.1562 0.65902E-10 -10.1811 0.94433E+00 -0.0249 34 CaCl+ 0.49769E-10 -10.3030 0.46998E-10 -10.3279 0.94433E+00 -0.0249 35 CaCl2,aq 0.14254E-14 -14.8461 0.14254E-14 -14.8461 0.10000E+01 0.0000 36 CaOH+ 0.10626E-07 -7.9736 0.10034E-07 -7.9985 0.94433E+00 -0.0249 37 CaSO4,aq 0.15090E-08 -8.8213 0.15090E-08 -8.8213 0.10000E+01 0.0000 38 HCl,aq 0.38985E-13 -13.4091 0.38985E-13 -13.4091 0.10000E+01 0.0000 43 FeCl+ 0.11722E-14 -14.9310 0.11070E-14 -14.9559 0.94433E+00 -0.0249 46 FeO,aq 0.85225E-10 -10.0694 0.85225E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.12039E-09 -9.9194 0.11368E-09 -9.9443 0.94433E+00 -0.0249 48 HFeO2- 0.61016E-09 -9.2146 0.57612E-09 -9.2395 0.94421E+00 -0.0249 49 FeO+ 0.13938E-13 -13.8558 0.13162E-13 -13.8807 0.94433E+00 -0.0249 51 FeO2- 0.10822E-08 -8.9657 0.10218E-08 -8.9906 0.94421E+00 -0.0249 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44190E-09 -9.3547 0.44180E-09 -9.3548 0.99979E+00 -0.0001 54 KCl,aq 0.14241E-09 -9.8464 0.14241E-09 -9.8464 0.10000E+01 0.0000 55 KHSO4,aq 0.56232E-17 -17.2500 0.56232E-17 -17.2500 0.10000E+01 0.0000 56 KOH,aq 0.16918E-07 -7.7717 0.16918E-07 -7.7717 0.10000E+01 0.0000 57 KSO4- 0.21549E-07 -7.6666 0.20347E-07 -7.6915 0.94421E+00 -0.0249 58 MgCO3,aq 0.18949E-11 -11.7224 0.18949E-11 -11.7224 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28992E-12 -12.5377 0.27378E-12 -12.5626 0.94433E+00 -0.0249 60 MgCl+ 0.18407E-12 -12.7350 0.17382E-12 -12.7599 0.94433E+00 -0.0249 61 MgOH+ 0.23983E-09 -9.6201 0.22647E-09 -9.6450 0.94433E+00 -0.0249 63 MnO,aq 0.30393E-09 -9.5172 0.30393E-09 -9.5172 0.10000E+01 0.0000 64 MnOH+ 0.14940E-08 -8.8256 0.14108E-08 -8.8505 0.94433E+00 -0.0249 65 MnO2-2 0.49474E-14 -14.3056 0.41518E-14 -14.3818 0.83920E+00 -0.0761 66 HMnO2- 0.15158E-11 -11.8193 0.14313E-11 -11.8443 0.94421E+00 -0.0249 69 MnCl+ 0.60851E-12 -12.2157 0.57464E-12 -12.2406 0.94433E+00 -0.0249 70 MnSO4,aq 0.44184E-11 -11.3547 0.44184E-11 -11.3547 0.10000E+01 0.0000 71 NaCl,aq 0.32471E-07 -7.4885 0.32471E-07 -7.4885 0.10000E+01 0.0000 72 NaOH,aq 0.21083E-06 -6.6761 0.21083E-06 -6.6761 0.10000E+01 0.0000 74 OH- 0.39931E-03 -3.3987 0.37699E-03 -3.4237 0.94410E+00 -0.0250 79 HPO3-2 0.37040E-18 -18.4313 0.31084E-18 -18.5075 0.83920E+00 -0.0761 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.65804E-08 -8.1817 0.62137E-08 -8.2067 0.94427E+00 -0.0249 84 PO4-3 0.17691E-09 -9.7522 0.12226E-09 -9.9127 0.69108E+00 -0.1605 87 H2P2O7-2 0.36008E-17 -17.4436 0.30218E-17 -17.5197 0.83920E+00 -0.0761 88 HP2O7-3 0.56527E-15 -15.2477 0.38943E-15 -15.4096 0.68893E+00 -0.1618 89 P2O7-4 0.11530E-15 -15.9382 0.60380E-16 -16.2191 0.52368E+00 -0.2809 90 H2S,aq 0.30827E-15 -15.5111 0.30821E-15 -15.5112 0.99979E+00 -0.0001 97 SO3-2 0.15339E-14 -14.8142 0.12885E-14 -14.8899 0.83998E+00 -0.0757 98 HSO3- 0.12706E-15 -15.8960 0.11998E-15 -15.9209 0.94421E+00 -0.0249 99 HSO4- 0.33437E-10 -10.4758 0.31578E-10 -10.5006 0.94438E+00 -0.0249 Charge balance for all species = -.5744E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1684477E-08 -.7445229E-03 -.7503657E+00 0.0000 2 H2O 0.1000000E+01 0.5550844E+02 0.9999098E+06 0.0000 3 Cl- 0.1379562E-03 0.1379888E-03 0.4891671E+01 4.9131 4 SO4-- 0.2548409E-04 0.2550723E-04 0.2450041E+01 12.9268 5 HCO3- 0.1223254E-04 0.1307139E-04 0.7975066E+00 3.8609 6 HS- 0.6827842E-13 -.5016485E-10 -.1658900E-05 -4.3923 7 Al+++ 0.3525467E-23 0.2316818E-04 0.6250551E+00 2.7803 8 H4SiO4 0.3829605E-03 0.6345135E-03 0.6098094E+02 -3.4168 9 Ca++ 0.2698944E-06 0.2852717E-06 0.1143207E-01 10.9515 10 Mg++ 0.1099865E-08 0.1348456E-08 0.3278065E-04 8.5615 11 Fe++ 0.6505177E-11 0.2107944E-08 0.1177116E-03 6.3335 12 K+ 0.6538715E-04 0.6542576E-04 0.2558044E+01 4.5889 13 Na+ 0.8085381E-03 0.8116287E-03 0.1865747E+02 5.6811 14 Mn++ 0.8689869E-09 0.2673485E-08 0.1468625E-03 8.4593 15 HPO4-- 0.2653908E-06 0.2721481E-06 0.2611811E-01 10.9444 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8580829E-02 -.7444437E-03 -.7836386E-02 0.0000000E+00 2 H2O 0.5550174E+02 0.5550254E+02 -.7997047E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3988773E-04 0.2550452E-04 0.1438321E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1438326E-04 -.5015952E-10 -.1438321E-04 0.0000000E+00 7 Al+++ 0.1692325E-02 0.2316572E-04 0.1669159E-02 0.0000000E+00 8 H4SiO4 0.5404234E-02 0.6344461E-03 0.4769788E-02 0.0000000E+00 9 Ca++ 0.6113951E-03 0.2852414E-06 0.6111099E-03 0.0000000E+00 10 Mg++ 0.4119048E-03 0.1348312E-08 0.4119034E-03 0.0000000E+00 11 Fe++ 0.3700515E-03 0.2107720E-08 0.3700494E-03 0.0000000E+00 12 K+ 0.1101911E-03 0.6541881E-04 0.4477228E-04 0.0000000E+00 13 Na+ 0.8115424E-03 0.8115424E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.8998731E-05 0.2673201E-08 0.8996058E-05 0.0000000E+00 15 HPO4-- 0.3071222E-05 0.2721192E-06 0.2799103E-05 0.0000000E+00 Chg. balance for solid moles: 0.3244E-18 Mass of aqueous solution: 0.999985E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.5190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.9330E-06 -6.030 0.4687E-03 -3.329 0.8683E-01 0.1489E-03 clinochlore 0.8238E-04 -4.084 0.4579E-01 -1.339 8.483 0.1742E-01 daphnite 0.5100E-04 -4.292 0.3639E-01 -1.439 6.741 0.1103E-01 chlorite-Mn 0.1799E-05 -5.745 0.1276E-02 -2.894 0.2363 0.4065E-03 hematite 0.5753E-04 -4.240 0.9188E-02 -2.037 1.702 0.1741E-02 kaolinite 0.2580E-04 -4.588 0.6660E-02 -2.176 1.234 0.2563E-02 lawsonite 0.1335E-04 -4.874 0.4196E-02 -2.377 0.7775 0.1353E-02 muscovite 0.4477E-04 -4.349 0.1783E-01 -1.749 3.304 0.6306E-02 stilbite 0.5931E-03 -3.227 0.4180 -0.379 77.43 0.1949 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.539761 g Volume = 0.235908 cm3 Porosity: 80.4648% V(tot) - V(min): 0.97169E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.5190000 g log = -0.2848 Original solution: 1000.0103000 g Original solution / Rock added: 1926.80 (Water/Rock Ratio), log = 3.2848 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.4003E-05 1.0073 0.4242E-05 0.4211E-05 CH4,gas 0.5070E-16 1.0129 0.5403E-16 0.5334E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.8580E-14 0.9959 0.8989E-14 0.9026E-14 S2,gas 0.7835E-35 1.0000 0.8242E-35 0.8242E-35 CO,gas 0.6329E-15 1.0000 0.6658E-15 0.6658E-15 SO3,gas 0.1924E-37 1.0000 0.2024E-37 0.2024E-37 SO2,gas 0.4412E-21 1.0000 0.4641E-21 0.4641E-21 HCl,gas 0.6544E-16 1.0000 0.6884E-16 0.6884E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.74 -7.37 -2.457 0.12588E+05 -5.372 3 CH4,gas 4.81 -13.46 -18.27 -4.567 0.31191E+05 -16.267 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -21.99 -16.05 -8.023 0.27399E+05 -14.046 6 S2,gas -7.03 -44.12 -37.08 -5.705 0.63320E+05 -35.084 7 CO,gas 3.51 -13.67 -17.18 -5.285 0.29329E+05 -15.177 8 SO3,gas 17.43 -22.27 -39.69 -9.923 0.67776E+05 -37.694 9 SO2,gas 1.14 -22.20 -23.33 -6.222 0.39841E+05 -21.333 10 HCl,gas 5.48 -12.68 -18.16 -9.081 0.31011E+05 -16.162 11 acmite 7.74 5.15 -2.59 -0.269 0.44244E+04 15 albite-high 0.75 -1.79 -2.54 -0.195 0.43350E+04 16 albite -0.33 -1.79 -1.46 -0.112 0.24943E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65944E+04 20 analcite 3.37 1.63 -1.74 -0.194 0.29761E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 16.12 -4.09 -0.227 0.69840E+04 27 phlogopite 27.15 22.80 -4.34 -0.241 0.74161E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.78 -3.77 -1.257 0.64378E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.78 -3.62 -1.206 0.61765E+04 38 carnegieite-low 9.06 5.04 -4.02 -0.574 0.68641E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.26 -3.14 -0.185 0.53566E+04 43 celadonite-Fe 3.94 0.04 -3.90 -0.230 0.66620E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14688E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.88 -4.61 -0.384 0.78751E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68768E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.63 -2.62 -0.262 0.44791E+04 97 kalsilite 7.62 3.95 -3.67 -0.524 0.62629E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.54 -3.63 -0.363 0.62018E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -2.88 -0.45 -0.035 0.76761E+03 121 paragonite 4.34 3.77 -0.57 -0.033 0.96519E+03 122 nepheline 8.38 5.04 -3.33 -0.476 0.56921E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58501E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40529E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.28 -4.32 -1.439 0.73727E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41321E+04 153 sanidine -1.22 -2.88 -1.66 -0.128 0.28354E+04 155 siderite -2.59 -7.40 -4.81 -1.605 0.82207E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.19 -0.99 -0.030 0.16933E+04 165 stilpnomelane-Mg 27.60 23.33 -4.27 -0.127 0.72881E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77454E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78735E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.55 -3.11 -0.191 0.53144E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.19 -2.93 -0.179 0.50029E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.68 -2.52 -0.155 0.43092E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.32 -2.36 -0.145 0.40359E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.49 -0.91 -0.059 0.15610E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.85 -0.73 -0.047 0.12512E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.50 -1.57 -0.121 0.26891E+04 243 an25ab75 2.71 1.08 -1.63 -0.125 0.27857E+04 244 an30ab70 3.34 1.65 -1.69 -0.130 0.28906E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.5190000 g New total amount of reactant added: 0.5390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5877E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.5390000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .6854993E-03 Osmotic coef. = 0.9847 True ionic strength = .9241313E-03 Chg. balance for total moles = -.5877E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.16308E-08 -8.7876 0.15397E-08 -8.8126 0.94413E+00 -0.0250 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.13020E-03 -3.8854 0.94376E+00 -0.0251 4 SO4-- 0.25485E-04 -4.5937 0.21350E-04 -4.6706 0.83773E+00 -0.0769 5 HCO3- 0.12208E-04 -4.9134 0.11522E-04 -4.9385 0.94385E+00 -0.0251 6 HS- 0.65982E-13 -13.1806 0.62272E-13 -13.2057 0.94377E+00 -0.0251 7 Al+++ 0.32085E-23 -23.4937 0.22009E-23 -23.6574 0.68597E+00 -0.1637 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.25322E-06 -6.5965 0.21203E-06 -6.6736 0.83734E+00 -0.0771 10 Mg++ 0.10319E-08 -8.9863 0.86382E-09 -9.0636 0.83709E+00 -0.0772 11 Fe++ 0.61034E-11 -11.2144 0.51095E-11 -11.2916 0.83715E+00 -0.0772 12 K+ 0.63306E-04 -4.1986 0.59752E-04 -4.2236 0.94387E+00 -0.0251 13 Na+ 0.83345E-03 -3.0791 0.78657E-03 -3.1043 0.94375E+00 -0.0251 14 Mn++ 0.81534E-09 -9.0887 0.68259E-09 -9.1658 0.83719E+00 -0.0772 15 HPO4-- 0.28394E-06 -6.5468 0.23786E-06 -6.6237 0.83774E+00 -0.0769 16 HSiO3- 0.25713E-03 -3.5899 0.24267E-03 -3.6150 0.94376E+00 -0.0251 17 Ca(HSiO3)+ 0.12214E-08 -8.9132 0.11528E-08 -8.9382 0.94388E+00 -0.0251 18 Mg(HSiO3)+ 0.61925E-11 -11.2081 0.58450E-11 -11.2332 0.94388E+00 -0.0251 19 NaHSiO3,aq 0.30316E-05 -5.5183 0.30316E-05 -5.5183 0.10000E+01 0.0000 20 AlO+ 0.12697E-12 -12.8963 0.11985E-12 -12.9214 0.94388E+00 -0.0251 21 AlOH+2 0.11041E-17 -17.9570 0.92440E-18 -18.0341 0.83724E+00 -0.0771 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.23937E-04 -4.6209 0.22588E-04 -4.6461 0.94365E+00 -0.0252 24 CH4,aq 0.32985E-19 -19.4817 0.32978E-19 -19.4818 0.99979E+00 -0.0001 29 CO,aq 0.40702E-18 -18.3904 0.40702E-18 -18.3904 0.10000E+01 0.0000 30 CO2,aq 0.35778E-07 -7.4464 0.35770E-07 -7.4465 0.99979E+00 -0.0001 31 CO3-2 0.82604E-06 -6.0830 0.69190E-06 -6.1600 0.83761E+00 -0.0770 32 CaCO3,aq 0.17968E-08 -8.7455 0.17968E-08 -8.7455 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.65220E-10 -10.1856 0.61559E-10 -10.2107 0.94388E+00 -0.0251 34 CaCl+ 0.46606E-10 -10.3316 0.43990E-10 -10.3566 0.94388E+00 -0.0251 35 CaCl2,aq 0.13336E-14 -14.8750 0.13336E-14 -14.8750 0.10000E+01 0.0000 36 CaOH+ 0.10288E-07 -7.9877 0.97102E-08 -8.0128 0.94388E+00 -0.0251 37 CaSO4,aq 0.14105E-08 -8.8506 0.14105E-08 -8.8506 0.10000E+01 0.0000 38 HCl,aq 0.37708E-13 -13.4236 0.37708E-13 -13.4236 0.10000E+01 0.0000 43 FeCl+ 0.10977E-14 -14.9595 0.10361E-14 -14.9846 0.94388E+00 -0.0251 46 FeO,aq 0.85225E-10 -10.0694 0.85225E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.11655E-09 -9.9335 0.11001E-09 -9.9586 0.94388E+00 -0.0251 48 HFeO2- 0.63083E-09 -9.2001 0.59535E-09 -9.2252 0.94376E+00 -0.0251 49 FeO+ 0.13494E-13 -13.8699 0.12737E-13 -13.8949 0.94388E+00 -0.0251 51 FeO2- 0.11188E-08 -8.9512 0.10559E-08 -8.9764 0.94376E+00 -0.0251 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44190E-09 -9.3547 0.44180E-09 -9.3548 0.99979E+00 -0.0001 54 KCl,aq 0.13775E-09 -9.8609 0.13775E-09 -9.8609 0.10000E+01 0.0000 55 KHSO4,aq 0.52562E-17 -17.2793 0.52562E-17 -17.2793 0.10000E+01 0.0000 56 KOH,aq 0.16918E-07 -7.7717 0.16918E-07 -7.7717 0.10000E+01 0.0000 57 KSO4- 0.20825E-07 -7.6814 0.19654E-07 -7.7066 0.94376E+00 -0.0251 58 MgCO3,aq 0.18292E-11 -11.7377 0.18292E-11 -11.7377 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27095E-12 -12.5671 0.25574E-12 -12.5922 0.94388E+00 -0.0251 60 MgCl+ 0.17237E-12 -12.7635 0.16270E-12 -12.7886 0.94388E+00 -0.0251 61 MgOH+ 0.23219E-09 -9.6342 0.21916E-09 -9.6592 0.94388E+00 -0.0251 63 MnO,aq 0.30394E-09 -9.5172 0.30394E-09 -9.5172 0.10000E+01 0.0000 64 MnOH+ 0.14465E-08 -8.8397 0.13653E-08 -8.8648 0.94388E+00 -0.0251 65 MnO2-2 0.52932E-14 -14.2763 0.44337E-14 -14.3532 0.83761E+00 -0.0770 66 HMnO2- 0.15672E-11 -11.8049 0.14791E-11 -11.8300 0.94376E+00 -0.0251 69 MnCl+ 0.56985E-12 -12.2442 0.53787E-12 -12.2693 0.94388E+00 -0.0251 70 MnSO4,aq 0.41300E-11 -11.3840 0.41300E-11 -11.3840 0.10000E+01 0.0000 71 NaCl,aq 0.33439E-07 -7.4757 0.33439E-07 -7.4757 0.10000E+01 0.0000 72 NaOH,aq 0.22447E-06 -6.6488 0.22447E-06 -6.6488 0.10000E+01 0.0000 74 OH- 0.41283E-03 -3.3842 0.38957E-03 -3.4094 0.94365E+00 -0.0252 79 HPO3-2 0.39628E-18 -18.4020 0.33193E-18 -18.4790 0.83761E+00 -0.0770 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.68033E-08 -8.1673 0.64210E-08 -8.1924 0.94382E+00 -0.0251 84 PO4-3 0.19604E-09 -9.7077 0.13491E-09 -9.8699 0.68819E+00 -0.1623 87 H2P2O7-2 0.38524E-17 -17.4143 0.32268E-17 -17.4912 0.83761E+00 -0.0770 88 HP2O7-3 0.62644E-15 -15.2031 0.42973E-15 -15.3668 0.68600E+00 -0.1637 89 P2O7-4 0.13247E-15 -15.8779 0.68853E-16 -16.1621 0.51974E+00 -0.2842 90 H2S,aq 0.28815E-15 -15.5404 0.28809E-15 -15.5405 0.99979E+00 -0.0001 97 SO3-2 0.15340E-14 -14.8142 0.12861E-14 -14.8907 0.83841E+00 -0.0765 98 HSO3- 0.12279E-15 -15.9108 0.11589E-15 -15.9360 0.94376E+00 -0.0251 99 HSO4- 0.32313E-10 -10.4906 0.30501E-10 -10.5157 0.94394E+00 -0.0251 Charge balance for all species = -.5748E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1630842E-08 -.7698306E-03 -.7758709E+00 0.0000 2 H2O 0.1000000E+01 0.5550845E+02 0.9999084E+06 0.0000 3 Cl- 0.1379557E-03 0.1379894E-03 0.4891682E+01 4.9272 4 SO4-- 0.2548500E-04 0.2550733E-04 0.2450047E+01 12.9545 5 HCO3- 0.1220775E-04 0.1307144E-04 0.7975084E+00 3.8741 6 HS- 0.6598239E-13 -.5474770E-10 -.1810448E-05 -4.3932 7 Al+++ 0.3208495E-23 0.2395232E-04 0.6462093E+00 2.7803 8 H4SiO4 0.3829605E-03 0.6431202E-03 0.6180800E+02 -3.4168 9 Ca++ 0.2532245E-06 0.2680526E-06 0.1074201E-01 10.9515 10 Mg++ 0.1031939E-08 0.1272595E-08 0.3093646E-04 8.5615 11 Fe++ 0.6103419E-11 0.2161021E-08 0.1206753E-03 6.3335 12 K+ 0.6330557E-04 0.6334345E-04 0.2476626E+01 4.5889 13 Na+ 0.8334499E-03 0.8367393E-03 0.1923468E+02 5.7083 14 Mn++ 0.8153352E-09 0.2572033E-08 0.1412892E-03 8.4593 15 HPO4-- 0.2839353E-06 0.2909346E-06 0.2792102E-01 11.0014 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8912000E-02 -.7697459E-03 -.8142254E-02 0.0000000E+00 2 H2O 0.5550149E+02 0.5550235E+02 -.8536271E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4044200E-04 0.2550452E-04 0.1493747E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1493753E-04 -.5474168E-10 -.1493747E-04 0.0000000E+00 7 Al+++ 0.1757540E-02 0.2394968E-04 0.1733590E-02 0.0000000E+00 8 H4SiO4 0.5612490E-02 0.6430494E-03 0.4969441E-02 0.0000000E+00 9 Ca++ 0.6343980E-03 0.2680231E-06 0.6341299E-03 0.0000000E+00 10 Mg++ 0.4277778E-03 0.1272455E-08 0.4277765E-03 0.0000000E+00 11 Fe++ 0.3843116E-03 0.2160783E-08 0.3843095E-03 0.0000000E+00 12 K+ 0.1144374E-03 0.6333649E-04 0.5110088E-04 0.0000000E+00 13 Na+ 0.8366473E-03 0.8366473E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.9345503E-05 0.2571751E-08 0.9342931E-05 0.0000000E+00 15 HPO4-- 0.3189574E-05 0.2909026E-06 0.2898671E-05 0.0000000E+00 Chg. balance for solid moles: -.9190E-18 Mass of aqueous solution: 0.999983E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.5390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.9662E-06 -6.015 0.4854E-03 -3.314 0.8639E-01 0.1542E-03 clinochlore 0.8556E-04 -4.068 0.4755E-01 -1.323 8.464 0.1809E-01 daphnite 0.5296E-04 -4.276 0.3779E-01 -1.423 6.726 0.1145E-01 chlorite-Mn 0.1869E-05 -5.728 0.1325E-02 -2.878 0.2358 0.4222E-03 hematite 0.5975E-04 -4.224 0.9542E-02 -2.020 1.698 0.1809E-02 kaolinite 0.2046E-04 -4.689 0.5282E-02 -2.277 0.9401 0.2032E-02 lawsonite 0.1021E-04 -4.991 0.3207E-02 -2.494 0.5708 0.1034E-02 muscovite 0.5110E-04 -4.292 0.2035E-01 -1.691 3.623 0.7197E-02 stilbite 0.6191E-03 -3.208 0.4363 -0.360 77.66 0.2035 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.561825 g Volume = 0.245680 cm3 Porosity: 79.7894% V(tot) - V(min): 0.96992E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.5390000 g log = -0.2684 Original solution: 1000.0103000 g Original solution / Rock added: 1855.31 (Water/Rock Ratio), log = 3.2684 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3864E-05 1.0073 0.4095E-05 0.4065E-05 CH4,gas 0.4894E-16 1.0129 0.5215E-16 0.5149E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.8020E-14 0.9959 0.8402E-14 0.8437E-14 S2,gas 0.6846E-35 1.0000 0.7201E-35 0.7201E-35 CO,gas 0.6110E-15 1.0000 0.6427E-15 0.6427E-15 SO3,gas 0.1799E-37 1.0000 0.1892E-37 0.1892E-37 SO2,gas 0.4124E-21 1.0000 0.4338E-21 0.4338E-21 HCl,gas 0.6329E-16 1.0000 0.6658E-16 0.6658E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.75 -7.39 -2.463 0.12614E+05 -5.388 3 CH4,gas 4.81 -13.47 -18.28 -4.571 0.31217E+05 -16.283 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -22.02 -16.08 -8.038 0.27449E+05 -14.076 6 S2,gas -7.03 -44.18 -37.14 -5.714 0.63420E+05 -35.143 7 CO,gas 3.51 -13.68 -17.19 -5.290 0.29355E+05 -15.192 8 SO3,gas 17.43 -22.30 -39.72 -9.931 0.67826E+05 -37.723 9 SO2,gas 1.14 -22.23 -23.36 -6.230 0.39891E+05 -21.363 10 HCl,gas 5.48 -12.70 -18.18 -9.088 0.31036E+05 -16.177 11 acmite 7.74 5.17 -2.56 -0.266 0.43779E+04 15 albite-high 0.75 -1.76 -2.51 -0.193 0.42885E+04 16 albite -0.33 -1.76 -1.43 -0.110 0.24478E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65944E+04 20 analcite 3.37 1.65 -1.72 -0.191 0.29296E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 16.12 -4.09 -0.227 0.69840E+04 27 phlogopite 27.15 22.80 -4.34 -0.241 0.74161E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.80 -3.79 -1.262 0.64640E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.80 -3.63 -1.211 0.62027E+04 38 carnegieite-low 9.06 5.07 -3.99 -0.570 0.68177E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.26 -3.14 -0.185 0.53566E+04 43 celadonite-Fe 3.94 0.04 -3.90 -0.230 0.66620E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14688E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.88 -4.61 -0.384 0.78751E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68768E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.65 -2.60 -0.260 0.44326E+04 97 kalsilite 7.62 3.95 -3.67 -0.524 0.62629E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.54 -3.63 -0.363 0.62018E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -2.88 -0.45 -0.035 0.76761E+03 121 paragonite 4.34 3.80 -0.54 -0.032 0.91870E+03 122 nepheline 8.38 5.07 -3.31 -0.472 0.56456E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58501E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40529E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.29 -4.33 -1.444 0.73988E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41321E+04 153 sanidine -1.22 -2.88 -1.66 -0.128 0.28354E+04 155 siderite -2.59 -7.42 -4.83 -1.610 0.82469E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.19 -0.99 -0.030 0.16933E+04 165 stilpnomelane-Mg 27.60 23.33 -4.27 -0.127 0.72881E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77454E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78735E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.55 -3.11 -0.191 0.53144E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.18 -2.92 -0.179 0.49876E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.68 -2.52 -0.155 0.43092E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.32 -2.35 -0.144 0.40205E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.49 -0.91 -0.059 0.15610E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.86 -0.72 -0.046 0.12359E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.53 -1.55 -0.119 0.26519E+04 243 an25ab75 2.71 1.10 -1.61 -0.124 0.27508E+04 244 an30ab70 3.34 1.67 -1.67 -0.129 0.28581E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.5390000 g New total amount of reactant added: 0.5590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5876E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.5590000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .7006289E-03 Osmotic coef. = 0.9845 True ionic strength = .9470768E-03 Chg. balance for total moles = -.5876E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15803E-08 -8.8012 0.14914E-08 -8.8264 0.94370E+00 -0.0252 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.13014E-03 -3.8856 0.94332E+00 -0.0253 4 SO4-- 0.25486E-04 -4.5937 0.21310E-04 -4.6714 0.83616E+00 -0.0777 5 HCO3- 0.12183E-04 -4.9143 0.11493E-04 -4.9396 0.94341E+00 -0.0253 6 HS- 0.63822E-13 -13.1950 0.60205E-13 -13.2204 0.94332E+00 -0.0253 7 Al+++ 0.29279E-23 -23.5334 0.20000E-23 -23.6990 0.68308E+00 -0.1655 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.23801E-06 -6.6234 0.19892E-06 -6.7013 0.83576E+00 -0.0779 10 Mg++ 0.96995E-09 -9.0133 0.81040E-09 -9.0913 0.83551E+00 -0.0781 11 Fe++ 0.57368E-11 -11.2413 0.47935E-11 -11.3194 0.83557E+00 -0.0780 12 K+ 0.61346E-04 -4.2122 0.57875E-04 -4.2375 0.94342E+00 -0.0253 13 Na+ 0.85836E-03 -3.0663 0.80969E-03 -3.0917 0.94331E+00 -0.0253 14 Mn++ 0.76637E-09 -9.1156 0.64039E-09 -9.1936 0.83561E+00 -0.0780 15 HPO4-- 0.30322E-06 -6.5182 0.25354E-06 -6.5959 0.83617E+00 -0.0777 16 HSiO3- 0.26559E-03 -3.5758 0.25054E-03 -3.6011 0.94332E+00 -0.0253 17 Ca(HSiO3)+ 0.11836E-08 -8.9268 0.11166E-08 -8.9521 0.94344E+00 -0.0253 18 Mg(HSiO3)+ 0.60008E-11 -11.2218 0.56614E-11 -11.2471 0.94344E+00 -0.0253 19 NaHSiO3,aq 0.32219E-05 -5.4919 0.32219E-05 -5.4919 0.10000E+01 0.0000 20 AlO+ 0.12304E-12 -12.9099 0.11608E-12 -12.9352 0.94344E+00 -0.0253 21 AlOH+2 0.10378E-17 -17.9839 0.86723E-18 -18.0619 0.83567E+00 -0.0780 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.24725E-04 -4.6069 0.23321E-04 -4.6323 0.94320E+00 -0.0254 24 CH4,aq 0.31869E-19 -19.4966 0.31862E-19 -19.4967 0.99978E+00 -0.0001 29 CO,aq 0.39324E-18 -18.4053 0.39324E-18 -18.4053 0.10000E+01 0.0000 30 CO2,aq 0.34567E-07 -7.4613 0.34559E-07 -7.4614 0.99978E+00 -0.0001 31 CO3-2 0.85229E-06 -6.0694 0.71255E-06 -6.1472 0.83604E+00 -0.0778 32 CaCO3,aq 0.17360E-08 -8.7605 0.17360E-08 -8.7605 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.61061E-10 -10.2142 0.57607E-10 -10.2395 0.94344E+00 -0.0253 34 CaCl+ 0.43723E-10 -10.3593 0.41250E-10 -10.3846 0.94344E+00 -0.0253 35 CaCl2,aq 0.12499E-14 -14.9031 0.12499E-14 -14.9031 0.10000E+01 0.0000 36 CaOH+ 0.99690E-08 -8.0013 0.94051E-08 -8.0266 0.94344E+00 -0.0253 37 CaSO4,aq 0.13208E-08 -8.8792 0.13208E-08 -8.8792 0.10000E+01 0.0000 38 HCl,aq 0.36506E-13 -13.4376 0.36506E-13 -13.4376 0.10000E+01 0.0000 43 FeCl+ 0.10298E-14 -14.9872 0.97157E-15 -15.0125 0.94344E+00 -0.0253 46 FeO,aq 0.85225E-10 -10.0694 0.85225E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.11295E-09 -9.9471 0.10656E-09 -9.9724 0.94344E+00 -0.0253 48 HFeO2- 0.65160E-09 -9.1860 0.61466E-09 -9.2114 0.94332E+00 -0.0253 49 FeO+ 0.13076E-13 -13.8835 0.12337E-13 -13.9088 0.94344E+00 -0.0253 51 FeO2- 0.11557E-08 -8.9372 0.10902E-08 -8.9625 0.94332E+00 -0.0253 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44190E-09 -9.3547 0.44180E-09 -9.3548 0.99978E+00 -0.0001 54 KCl,aq 0.13336E-09 -9.8750 0.13336E-09 -9.8750 0.10000E+01 0.0000 55 KHSO4,aq 0.49220E-17 -17.3079 0.49220E-17 -17.3079 0.10000E+01 0.0000 56 KOH,aq 0.16918E-07 -7.7717 0.16918E-07 -7.7717 0.10000E+01 0.0000 57 KSO4- 0.20143E-07 -7.6959 0.19001E-07 -7.7212 0.94332E+00 -0.0253 58 MgCO3,aq 0.17672E-11 -11.7527 0.17672E-11 -11.7527 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.25367E-12 -12.5957 0.23932E-12 -12.6210 0.94344E+00 -0.0253 60 MgCl+ 0.16171E-12 -12.7913 0.15256E-12 -12.8166 0.94344E+00 -0.0253 61 MgOH+ 0.22500E-09 -9.6478 0.21228E-09 -9.6731 0.94344E+00 -0.0253 63 MnO,aq 0.30394E-09 -9.5172 0.30394E-09 -9.5172 0.10000E+01 0.0000 64 MnOH+ 0.14017E-08 -8.8533 0.13224E-08 -8.8786 0.94344E+00 -0.0253 65 MnO2-2 0.56529E-14 -14.2477 0.47260E-14 -14.3255 0.83604E+00 -0.0778 66 HMnO2- 0.16188E-11 -11.7908 0.15271E-11 -11.8161 0.94332E+00 -0.0253 69 MnCl+ 0.53462E-12 -12.2720 0.50438E-12 -12.2972 0.94344E+00 -0.0253 70 MnSO4,aq 0.38676E-11 -11.4126 0.38676E-11 -11.4126 0.10000E+01 0.0000 71 NaCl,aq 0.34406E-07 -7.4634 0.34406E-07 -7.4634 0.10000E+01 0.0000 72 NaOH,aq 0.23856E-06 -6.6224 0.23856E-06 -6.6224 0.10000E+01 0.0000 74 OH- 0.42643E-03 -3.3702 0.40221E-03 -3.3956 0.94320E+00 -0.0254 79 HPO3-2 0.42320E-18 -18.3735 0.35381E-18 -18.4512 0.83604E+00 -0.0778 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.70272E-08 -8.1532 0.66293E-08 -8.1785 0.94337E+00 -0.0253 84 PO4-3 0.21664E-09 -9.6643 0.14847E-09 -9.8284 0.68533E+00 -0.1641 87 H2P2O7-2 0.41141E-17 -17.3857 0.34396E-17 -17.4635 0.83604E+00 -0.0778 88 HP2O7-3 0.69232E-15 -15.1597 0.47292E-15 -15.3252 0.68310E+00 -0.1655 89 P2O7-4 0.15165E-15 -15.8192 0.78230E-16 -16.1066 0.51587E+00 -0.2875 90 H2S,aq 0.26983E-15 -15.5689 0.26977E-15 -15.5690 0.99978E+00 -0.0001 97 SO3-2 0.15340E-14 -14.8142 0.12837E-14 -14.8915 0.83686E+00 -0.0773 98 HSO3- 0.11877E-15 -15.9253 0.11204E-15 -15.9506 0.94332E+00 -0.0253 99 HSO4- 0.31255E-10 -10.5051 0.29489E-10 -10.5303 0.94350E+00 -0.0253 Charge balance for all species = -.5756E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1580340E-08 -.7952738E-03 -.8015126E+00 0.0000 2 H2O 0.1000000E+01 0.5550846E+02 0.9999071E+06 0.0000 3 Cl- 0.1379553E-03 0.1379899E-03 0.4891693E+01 4.9408 4 SO4-- 0.2548587E-04 0.2550743E-04 0.2450053E+01 12.9814 5 HCO3- 0.1218283E-04 0.1307149E-04 0.7975101E+00 3.8869 6 HS- 0.6382205E-13 -.5935393E-10 -.1962768E-05 -4.3940 7 Al+++ 0.2927874E-23 0.2474048E-04 0.6674723E+00 2.7803 8 H4SiO4 0.3829605E-03 0.6517761E-03 0.6263981E+02 -3.4168 9 Ca++ 0.2380119E-06 0.2523260E-06 0.1011177E-01 10.9515 10 Mg++ 0.9699514E-09 0.1203137E-08 0.2924790E-04 8.5615 11 Fe++ 0.5736780E-11 0.2214651E-08 0.1236699E-03 6.3335 12 K+ 0.6134563E-04 0.6138282E-04 0.2399965E+01 4.5889 13 Na+ 0.8583553E-03 0.8618501E-03 0.1981189E+02 5.7347 14 Mn++ 0.7663711E-09 0.2478072E-08 0.1361275E-03 8.4593 15 HPO4-- 0.3032205E-06 0.3104644E-06 0.2979525E-01 11.0569 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9243170E-02 -.7951834E-03 -.8447987E-02 0.0000000E+00 2 H2O 0.5550124E+02 0.5550215E+02 -.9073241E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4099627E-04 0.2550453E-04 0.1549174E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1549180E-04 -.5934719E-10 -.1549174E-04 0.0000000E+00 7 Al+++ 0.1822755E-02 0.2473767E-04 0.1798017E-02 0.0000000E+00 8 H4SiO4 0.5820746E-02 0.6517021E-03 0.5169044E-02 0.0000000E+00 9 Ca++ 0.6574008E-03 0.2522974E-06 0.6571485E-03 0.0000000E+00 10 Mg++ 0.4436508E-03 0.1203000E-08 0.4436496E-03 0.0000000E+00 11 Fe++ 0.3985718E-03 0.2214399E-08 0.3985696E-03 0.0000000E+00 12 K+ 0.1186837E-03 0.6137585E-04 0.5730780E-04 0.0000000E+00 13 Na+ 0.8617522E-03 0.8617522E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.9692275E-05 0.2477791E-08 0.9689797E-05 0.0000000E+00 15 HPO4-- 0.3307925E-05 0.3104291E-06 0.2997496E-05 0.0000000E+00 Chg. balance for solid moles: 0.1426E-17 Mass of aqueous solution: 0.999981E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.5590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.9992E-06 -6.000 0.5019E-03 -3.299 0.8596E-01 0.1595E-03 clinochlore 0.8873E-04 -4.052 0.4932E-01 -1.307 8.447 0.1876E-01 daphnite 0.5493E-04 -4.260 0.3919E-01 -1.407 6.712 0.1188E-01 chlorite-Mn 0.1938E-05 -5.713 0.1374E-02 -2.862 0.2353 0.4378E-03 hematite 0.6197E-04 -4.208 0.9896E-02 -2.005 1.695 0.1876E-02 kaolinite 0.1530E-04 -4.815 0.3950E-02 -2.403 0.6764 0.1520E-02 lawsonite 0.7066E-05 -5.151 0.2221E-02 -2.654 0.3803 0.7161E-03 muscovite 0.5731E-04 -4.242 0.2283E-01 -1.642 3.909 0.8072E-02 stilbite 0.6451E-03 -3.190 0.4546 -0.342 77.86 0.2120 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.583883 g Volume = 0.255452 cm3 Porosity: 79.1229% V(tot) - V(min): 0.96815E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.5590000 g log = -0.2526 Original solution: 1000.0103000 g Original solution / Rock added: 1788.93 (Water/Rock Ratio), log = 3.2526 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3733E-05 1.0073 0.3956E-05 0.3927E-05 CH4,gas 0.4729E-16 1.0129 0.5039E-16 0.4974E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.7510E-14 0.9959 0.7868E-14 0.7900E-14 S2,gas 0.6003E-35 1.0000 0.6315E-35 0.6315E-35 CO,gas 0.5903E-15 1.0000 0.6209E-15 0.6209E-15 SO3,gas 0.1684E-37 1.0000 0.1772E-37 0.1772E-37 SO2,gas 0.3861E-21 1.0000 0.4062E-21 0.4062E-21 HCl,gas 0.6128E-16 1.0000 0.6446E-16 0.6446E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.72794E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.24265E-10 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.77 -7.40 -2.468 0.12640E+05 -5.403 3 CH4,gas 4.81 -13.49 -18.30 -4.574 0.31243E+05 -16.298 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -22.05 -16.10 -8.052 0.27497E+05 -14.104 6 S2,gas -7.03 -44.23 -37.20 -5.723 0.63517E+05 -35.200 7 CO,gas 3.51 -13.70 -17.21 -5.294 0.29380E+05 -15.207 8 SO3,gas 17.43 -22.32 -39.75 -9.938 0.67875E+05 -37.752 9 SO2,gas 1.14 -22.25 -23.39 -6.238 0.39940E+05 -21.391 10 HCl,gas 5.48 -12.71 -18.19 -9.095 0.31060E+05 -16.191 11 acmite 7.74 5.20 -2.54 -0.264 0.43328E+04 15 albite-high 0.75 -1.74 -2.49 -0.191 0.42433E+04 16 albite -0.33 -1.74 -1.41 -0.108 0.24027E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65943E+04 20 analcite 3.37 1.68 -1.69 -0.188 0.28845E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 16.12 -4.09 -0.227 0.69840E+04 27 phlogopite 27.15 22.80 -4.34 -0.241 0.74161E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.81 -3.80 -1.267 0.64896E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.81 -3.65 -1.216 0.62282E+04 38 carnegieite-low 9.06 5.10 -3.97 -0.567 0.67725E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.26 -3.14 -0.185 0.53566E+04 43 celadonite-Fe 3.94 0.04 -3.90 -0.230 0.66620E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14688E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.88 -4.61 -0.384 0.78751E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68768E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.68 -2.57 -0.257 0.43875E+04 97 kalsilite 7.62 3.95 -3.67 -0.524 0.62629E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.54 -3.63 -0.363 0.62018E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -2.88 -0.45 -0.035 0.76761E+03 121 paragonite 4.34 3.83 -0.51 -0.030 0.87355E+03 122 nepheline 8.38 5.10 -3.28 -0.469 0.56004E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58501E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40529E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.31 -4.35 -1.449 0.74244E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41321E+04 153 sanidine -1.22 -2.88 -1.66 -0.128 0.28354E+04 155 siderite -2.59 -7.43 -4.84 -1.615 0.82724E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.19 -0.99 -0.030 0.16933E+04 165 stilpnomelane-Mg 27.60 23.33 -4.27 -0.127 0.72881E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77454E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78735E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.55 -3.11 -0.191 0.53144E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.17 -2.91 -0.178 0.49727E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.68 -2.52 -0.155 0.43092E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.31 -2.35 -0.144 0.40056E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.49 -0.91 -0.059 0.15610E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.87 -0.72 -0.046 0.12210E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.55 -1.53 -0.118 0.26158E+04 243 an25ab75 2.71 1.12 -1.59 -0.122 0.27169E+04 244 an30ab70 3.34 1.69 -1.66 -0.127 0.28265E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.5590000 g New total amount of reactant added: 0.5790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5874E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.5790000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .7158354E-03 Osmotic coef. = 0.9844 True ionic strength = .9701327E-03 Chg. balance for total moles = -.5874E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15327E-08 -8.8145 0.14458E-08 -8.8399 0.94326E+00 -0.0254 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.13007E-03 -3.8858 0.94287E+00 -0.0255 4 SO4-- 0.25487E-04 -4.5937 0.21271E-04 -4.6722 0.83461E+00 -0.0785 5 HCO3- 0.12158E-04 -4.9151 0.11464E-04 -4.9406 0.94297E+00 -0.0255 6 HS- 0.61787E-13 -13.2091 0.58258E-13 -13.2346 0.94288E+00 -0.0255 7 Al+++ 0.26787E-23 -23.5721 0.18221E-23 -23.7394 0.68021E+00 -0.1674 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.22410E-06 -6.6496 0.18694E-06 -6.7283 0.83420E+00 -0.0787 10 Mg++ 0.91326E-09 -9.0394 0.76160E-09 -9.1183 0.83394E+00 -0.0789 11 Fe++ 0.54015E-11 -11.2675 0.45048E-11 -11.3463 0.83400E+00 -0.0788 12 K+ 0.59498E-04 -4.2255 0.56105E-04 -4.2510 0.94298E+00 -0.0255 13 Na+ 0.88325E-03 -3.0539 0.83279E-03 -3.0795 0.94286E+00 -0.0256 14 Mn++ 0.72159E-09 -9.1417 0.60184E-09 -9.2205 0.83405E+00 -0.0788 15 HPO4-- 0.32325E-06 -6.4905 0.26979E-06 -6.5690 0.83462E+00 -0.0785 16 HSiO3- 0.27410E-03 -3.5621 0.25844E-03 -3.5876 0.94287E+00 -0.0255 17 Ca(HSiO3)+ 0.11479E-08 -8.9401 0.10825E-08 -8.9656 0.94300E+00 -0.0255 18 Mg(HSiO3)+ 0.58200E-11 -11.2351 0.54883E-11 -11.2606 0.94300E+00 -0.0255 19 NaHSiO3,aq 0.34183E-05 -5.4662 0.34183E-05 -5.4662 0.10000E+01 0.0000 20 AlO+ 0.11934E-12 -12.9232 0.11253E-12 -12.9487 0.94300E+00 -0.0255 21 AlOH+2 0.97711E-18 -18.0101 0.81501E-18 -18.0888 0.83410E+00 -0.0788 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.25517E-04 -4.5932 0.24056E-04 -4.6188 0.94276E+00 -0.0256 24 CH4,aq 0.30817E-19 -19.5112 0.30810E-19 -19.5113 0.99978E+00 -0.0001 29 CO,aq 0.38026E-18 -18.4199 0.38026E-18 -18.4199 0.10000E+01 0.0000 30 CO2,aq 0.33425E-07 -7.4759 0.33418E-07 -7.4760 0.99978E+00 -0.0001 31 CO3-2 0.87859E-06 -6.0562 0.73317E-06 -6.1348 0.83449E+00 -0.0786 32 CaCO3,aq 0.16787E-08 -8.7750 0.16787E-08 -8.7750 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.57266E-10 -10.2421 0.54002E-10 -10.2676 0.94300E+00 -0.0255 34 CaCl+ 0.41090E-10 -10.3863 0.38748E-10 -10.4118 0.94300E+00 -0.0255 35 CaCl2,aq 0.11735E-14 -14.9305 0.11735E-14 -14.9305 0.10000E+01 0.0000 36 CaOH+ 0.96687E-08 -8.0146 0.91176E-08 -8.0401 0.94300E+00 -0.0255 37 CaSO4,aq 0.12390E-08 -8.9069 0.12390E-08 -8.9069 0.10000E+01 0.0000 38 HCl,aq 0.35373E-13 -13.4513 0.35373E-13 -13.4513 0.10000E+01 0.0000 43 FeCl+ 0.96781E-15 -15.0142 0.91264E-15 -15.0397 0.94300E+00 -0.0255 46 FeO,aq 0.85225E-10 -10.0694 0.85225E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.10954E-09 -9.9604 0.10330E-09 -9.9859 0.94300E+00 -0.0255 48 HFeO2- 0.67246E-09 -9.1723 0.63405E-09 -9.1979 0.94287E+00 -0.0255 49 FeO+ 0.12682E-13 -13.8968 0.11960E-13 -13.9223 0.94300E+00 -0.0255 51 FeO2- 0.11927E-08 -8.9235 0.11245E-08 -8.9490 0.94287E+00 -0.0255 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44190E-09 -9.3547 0.44180E-09 -9.3548 0.99978E+00 -0.0001 54 KCl,aq 0.12922E-09 -9.8887 0.12922E-09 -9.8887 0.10000E+01 0.0000 55 KHSO4,aq 0.46172E-17 -17.3356 0.46172E-17 -17.3356 0.10000E+01 0.0000 56 KOH,aq 0.16918E-07 -7.7717 0.16918E-07 -7.7717 0.10000E+01 0.0000 57 KSO4- 0.19501E-07 -7.7100 0.18387E-07 -7.7355 0.94287E+00 -0.0255 58 MgCO3,aq 0.17089E-11 -11.7673 0.17089E-11 -11.7673 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23790E-12 -12.6236 0.22434E-12 -12.6491 0.94300E+00 -0.0255 60 MgCl+ 0.15197E-12 -12.8182 0.14331E-12 -12.8437 0.94300E+00 -0.0255 61 MgOH+ 0.21822E-09 -9.6611 0.20578E-09 -9.6866 0.94300E+00 -0.0255 63 MnO,aq 0.30395E-09 -9.5172 0.30395E-09 -9.5172 0.10000E+01 0.0000 64 MnOH+ 0.13595E-08 -8.8666 0.12820E-08 -8.8921 0.94300E+00 -0.0255 65 MnO2-2 0.60264E-14 -14.2199 0.50289E-14 -14.2985 0.83449E+00 -0.0786 66 HMnO2- 0.16707E-11 -11.7771 0.15753E-11 -11.8026 0.94287E+00 -0.0255 69 MnCl+ 0.50243E-12 -12.2989 0.47379E-12 -12.3244 0.94300E+00 -0.0255 70 MnSO4,aq 0.36281E-11 -11.4403 0.36281E-11 -11.4403 0.10000E+01 0.0000 71 NaCl,aq 0.35371E-07 -7.4514 0.35371E-07 -7.4514 0.10000E+01 0.0000 72 NaOH,aq 0.25311E-06 -6.5967 0.25311E-06 -6.5967 0.10000E+01 0.0000 74 OH- 0.44008E-03 -3.3565 0.41489E-03 -3.3821 0.94276E+00 -0.0256 79 HPO3-2 0.45115E-18 -18.3457 0.37648E-18 -18.4243 0.83449E+00 -0.0786 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.72523E-08 -8.1395 0.68384E-08 -8.1650 0.94293E+00 -0.0255 84 PO4-3 0.23878E-09 -9.6220 0.16297E-09 -9.7879 0.68251E+00 -0.1659 87 H2P2O7-2 0.43859E-17 -17.3579 0.36600E-17 -17.4365 0.83449E+00 -0.0786 88 HP2O7-3 0.76311E-15 -15.1174 0.51909E-15 -15.2848 0.68024E+00 -0.1673 89 P2O7-4 0.17298E-15 -15.7620 0.88576E-16 -16.0527 0.51205E+00 -0.2907 90 H2S,aq 0.25312E-15 -15.5967 0.25306E-15 -15.5968 0.99978E+00 -0.0001 97 SO3-2 0.15340E-14 -14.8142 0.12814E-14 -14.8923 0.83532E+00 -0.0781 98 HSO3- 0.11498E-15 -15.9394 0.10842E-15 -15.9649 0.94287E+00 -0.0255 99 HSO4- 0.30258E-10 -10.5192 0.28535E-10 -10.5446 0.94306E+00 -0.0255 Charge balance for all species = -.5772E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1532726E-08 -.8208415E-03 -.8272797E+00 0.0000 2 H2O 0.1000000E+01 0.5550846E+02 0.9999058E+06 0.0000 3 Cl- 0.1379548E-03 0.1379904E-03 0.4891703E+01 4.9541 4 SO4-- 0.2548669E-04 0.2550753E-04 0.2450059E+01 13.0076 5 HCO3- 0.1215778E-04 0.1307153E-04 0.7975119E+00 3.8993 6 HS- 0.6178670E-13 -.6398157E-10 -.2115796E-05 -4.3947 7 Al+++ 0.2678669E-23 0.2553234E-04 0.6888348E+00 2.7803 8 H4SiO4 0.3829605E-03 0.6604778E-03 0.6347600E+02 -3.4168 9 Ca++ 0.2240983E-06 0.2379310E-06 0.9534885E-02 10.9515 10 Mg++ 0.9132568E-09 0.1139400E-08 0.2769844E-04 8.5615 11 Fe++ 0.5401451E-11 0.2268788E-08 0.1266928E-03 6.3335 12 K+ 0.5949776E-04 0.5953430E-04 0.2327687E+01 4.5889 13 Na+ 0.8832543E-03 0.8869611E-03 0.2038910E+02 5.7604 14 Mn++ 0.7215863E-09 0.2390873E-08 0.1313372E-03 8.4593 15 HPO4-- 0.3232488E-06 0.3307398E-06 0.3174104E-01 11.1108 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9574340E-02 -.8207452E-03 -.8753595E-02 0.0000000E+00 2 H2O 0.5550099E+02 0.5550195E+02 -.9608133E-03 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4155053E-04 0.2550453E-04 0.1604600E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1604606E-04 -.6397407E-10 -.1604600E-04 0.0000000E+00 7 Al+++ 0.1887969E-02 0.2552935E-04 0.1862440E-02 0.0000000E+00 8 H4SiO4 0.6029001E-02 0.6604003E-03 0.5368601E-02 0.0000000E+00 9 Ca++ 0.6804037E-03 0.2379031E-06 0.6801658E-03 0.0000000E+00 10 Mg++ 0.4595238E-03 0.1139266E-08 0.4595227E-03 0.0000000E+00 11 Fe++ 0.4128320E-03 0.2268522E-08 0.4128297E-03 0.0000000E+00 12 K+ 0.1229299E-03 0.5952732E-04 0.6340262E-04 0.0000000E+00 13 Na+ 0.8868571E-03 0.8868571E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1003905E-04 0.2390592E-08 0.1003666E-04 0.0000000E+00 15 HPO4-- 0.3426277E-05 0.3307011E-06 0.3095576E-05 0.0000000E+00 Chg. balance for solid moles: -.1028E-17 Mass of aqueous solution: 0.999979E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.5790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1032E-05 -5.986 0.5183E-03 -3.285 0.8554E-01 0.1647E-03 clinochlore 0.9190E-04 -4.037 0.5108E-01 -1.292 8.430 0.1943E-01 daphnite 0.5689E-04 -4.245 0.4059E-01 -1.392 6.699 0.1230E-01 chlorite-Mn 0.2007E-05 -5.697 0.1423E-02 -2.847 0.2349 0.4535E-03 hematite 0.6418E-04 -4.193 0.1025E-01 -1.989 1.692 0.1943E-02 kaolinite 0.1031E-04 -4.987 0.2660E-02 -2.575 0.4391 0.1024E-02 lawsonite 0.3935E-05 -5.405 0.1237E-02 -2.908 0.2041 0.3988E-03 muscovite 0.6340E-04 -4.198 0.2525E-01 -1.598 4.168 0.8930E-02 stilbite 0.6711E-03 -3.173 0.4729 -0.325 78.05 0.2206 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.605937 g Volume = 0.265222 cm3 Porosity: 78.4652% V(tot) - V(min): 0.96638E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.5790000 g log = -0.2373 Original solution: 1000.0103000 g Original solution / Rock added: 1727.13 (Water/Rock Ratio), log = 3.2373 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3610E-05 1.0073 0.3825E-05 0.3797E-05 CH4,gas 0.4573E-16 1.0129 0.4872E-16 0.4810E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.7045E-14 0.9959 0.7381E-14 0.7411E-14 S2,gas 0.5282E-35 1.0000 0.5557E-35 0.5557E-35 CO,gas 0.5708E-15 1.0000 0.6004E-15 0.6004E-15 SO3,gas 0.1580E-37 1.0000 0.1662E-37 0.1662E-37 SO2,gas 0.3622E-21 1.0000 0.3810E-21 0.3810E-21 HCl,gas 0.5937E-16 1.0000 0.6246E-16 0.6246E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 -0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.78 -7.42 -2.472 0.12665E+05 -5.417 3 CH4,gas 4.81 -13.50 -18.31 -4.578 0.31268E+05 -16.312 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -22.07 -16.13 -8.066 0.27545E+05 -14.132 6 S2,gas -7.03 -44.29 -37.26 -5.732 0.63612E+05 -35.255 7 CO,gas 3.51 -13.71 -17.22 -5.299 0.29405E+05 -15.222 8 SO3,gas 17.43 -22.35 -39.78 -9.945 0.67922E+05 -37.779 9 SO2,gas 1.14 -22.28 -23.42 -6.245 0.39987E+05 -21.419 10 HCl,gas 5.48 -12.73 -18.20 -9.102 0.31084E+05 -16.204 11 acmite 7.74 5.23 -2.51 -0.261 0.42889E+04 15 albite-high 0.75 -1.71 -2.46 -0.189 0.41995E+04 16 albite -0.33 -1.71 -1.38 -0.106 0.23588E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65943E+04 20 analcite 3.37 1.71 -1.66 -0.185 0.28406E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 16.12 -4.09 -0.227 0.69840E+04 27 phlogopite 27.15 22.80 -4.34 -0.241 0.74161E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.83 -3.82 -1.272 0.65145E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.83 -3.66 -1.221 0.62531E+04 38 carnegieite-low 9.06 5.12 -3.94 -0.563 0.67286E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.26 -3.14 -0.185 0.53566E+04 43 celadonite-Fe 3.94 0.04 -3.90 -0.230 0.66620E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14688E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.88 -4.61 -0.384 0.78751E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68768E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.71 -2.54 -0.254 0.43436E+04 97 kalsilite 7.62 3.95 -3.67 -0.524 0.62629E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.54 -3.63 -0.363 0.62018E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -2.88 -0.45 -0.035 0.76761E+03 121 paragonite 4.34 3.85 -0.49 -0.029 0.82966E+03 122 nepheline 8.38 5.12 -3.25 -0.465 0.55565E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58501E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40528E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.32 -4.36 -1.454 0.74492E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41321E+04 153 sanidine -1.22 -2.88 -1.66 -0.128 0.28354E+04 155 siderite -2.59 -7.45 -4.86 -1.620 0.82973E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.19 -0.99 -0.030 0.16933E+04 165 stilpnomelane-Mg 27.60 23.33 -4.27 -0.127 0.72881E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77454E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78735E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.55 -3.11 -0.191 0.53144E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.16 -2.90 -0.178 0.49582E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.68 -2.52 -0.155 0.43092E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.30 -2.34 -0.143 0.39911E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.49 -0.91 -0.059 0.15610E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.88 -0.71 -0.045 0.12065E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.57 -1.51 -0.116 0.25807E+04 243 an25ab75 2.71 1.14 -1.57 -0.121 0.26840E+04 244 an30ab70 3.34 1.71 -1.64 -0.126 0.27957E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.5790000 g New total amount of reactant added: 0.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5874E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.5990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .7311128E-03 Osmotic coef. = 0.9842 True ionic strength = .9932899E-03 Chg. balance for total moles = -.5874E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14878E-08 -8.8275 0.14027E-08 -8.8530 0.94283E+00 -0.0256 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.13001E-03 -3.8860 0.94243E+00 -0.0257 4 SO4-- 0.25487E-04 -4.5937 0.21233E-04 -4.6730 0.83307E+00 -0.0793 5 HCO3- 0.12133E-04 -4.9160 0.11435E-04 -4.9418 0.94253E+00 -0.0257 6 HS- 0.59867E-13 -13.2228 0.56421E-13 -13.2486 0.94244E+00 -0.0257 7 Al+++ 0.24567E-23 -23.6096 0.16641E-23 -23.7788 0.67739E+00 -0.1692 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.21135E-06 -6.6750 0.17598E-06 -6.7545 0.83266E+00 -0.0795 10 Mg++ 0.86129E-09 -9.0648 0.71693E-09 -9.1445 0.83239E+00 -0.0797 11 Fe++ 0.50941E-11 -11.2929 0.42406E-11 -11.3726 0.83245E+00 -0.0796 12 K+ 0.57753E-04 -4.2384 0.54435E-04 -4.2641 0.94255E+00 -0.0257 13 Na+ 0.90815E-03 -3.0418 0.85586E-03 -3.0676 0.94243E+00 -0.0258 14 Mn++ 0.68054E-09 -9.1671 0.56655E-09 -9.2468 0.83250E+00 -0.0796 15 HPO4-- 0.34402E-06 -6.4634 0.28660E-06 -6.5427 0.83308E+00 -0.0793 16 HSiO3- 0.28264E-03 -3.5488 0.26637E-03 -3.5745 0.94243E+00 -0.0257 17 Ca(HSiO3)+ 0.11143E-08 -8.9530 0.10502E-08 -8.9787 0.94256E+00 -0.0257 18 Mg(HSiO3)+ 0.56494E-11 -11.2480 0.53249E-11 -11.2737 0.94256E+00 -0.0257 19 NaHSiO3,aq 0.36208E-05 -5.4412 0.36208E-05 -5.4412 0.10000E+01 0.0000 20 AlO+ 0.11584E-12 -12.9362 0.10918E-12 -12.9618 0.94256E+00 -0.0257 21 AlOH+2 0.92151E-18 -18.0355 0.76721E-18 -18.1151 0.83256E+00 -0.0796 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.26312E-04 -4.5798 0.24794E-04 -4.6057 0.94231E+00 -0.0258 24 CH4,aq 0.29824E-19 -19.5254 0.29817E-19 -19.5255 0.99977E+00 -0.0001 29 CO,aq 0.36800E-18 -18.4341 0.36800E-18 -18.4341 0.10000E+01 0.0000 30 CO2,aq 0.32348E-07 -7.4901 0.32341E-07 -7.4902 0.99977E+00 -0.0001 31 CO3-2 0.90492E-06 -6.0434 0.75375E-06 -6.1228 0.83295E+00 -0.0794 32 CaCO3,aq 0.16246E-08 -8.7893 0.16246E-08 -8.7893 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53796E-10 -10.2693 0.50706E-10 -10.2949 0.94256E+00 -0.0257 34 CaCl+ 0.38680E-10 -10.4125 0.36458E-10 -10.4382 0.94256E+00 -0.0257 35 CaCl2,aq 0.11037E-14 -14.9572 0.11037E-14 -14.9572 0.10000E+01 0.0000 36 CaOH+ 0.93852E-08 -8.0276 0.88462E-08 -8.0532 0.94256E+00 -0.0257 37 CaSO4,aq 0.11642E-08 -8.9340 0.11642E-08 -8.9340 0.10000E+01 0.0000 38 HCl,aq 0.34304E-13 -13.4647 0.34304E-13 -13.4647 0.10000E+01 0.0000 43 FeCl+ 0.91104E-15 -15.0405 0.85871E-15 -15.0662 0.94256E+00 -0.0257 46 FeO,aq 0.85225E-10 -10.0694 0.85225E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.10633E-09 -9.9733 0.10022E-09 -9.9990 0.94256E+00 -0.0257 48 HFeO2- 0.69342E-09 -9.1590 0.65350E-09 -9.1848 0.94243E+00 -0.0257 49 FeO+ 0.12311E-13 -13.9097 0.11604E-13 -13.9354 0.94256E+00 -0.0257 51 FeO2- 0.12298E-08 -8.9102 0.11590E-08 -8.9359 0.94243E+00 -0.0257 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44190E-09 -9.3547 0.44180E-09 -9.3548 0.99977E+00 -0.0001 54 KCl,aq 0.12531E-09 -9.9020 0.12531E-09 -9.9020 0.10000E+01 0.0000 55 KHSO4,aq 0.43385E-17 -17.3627 0.43385E-17 -17.3627 0.10000E+01 0.0000 56 KOH,aq 0.16918E-07 -7.7717 0.16918E-07 -7.7717 0.10000E+01 0.0000 57 KSO4- 0.18895E-07 -7.7237 0.17807E-07 -7.7494 0.94243E+00 -0.0257 58 MgCO3,aq 0.16538E-11 -11.7815 0.16538E-11 -11.7815 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22349E-12 -12.6507 0.21065E-12 -12.6764 0.94256E+00 -0.0257 60 MgCl+ 0.14306E-12 -12.8445 0.13484E-12 -12.8702 0.94256E+00 -0.0257 61 MgOH+ 0.21183E-09 -9.6740 0.19966E-09 -9.6997 0.94256E+00 -0.0257 63 MnO,aq 0.30395E-09 -9.5172 0.30395E-09 -9.5172 0.10000E+01 0.0000 64 MnOH+ 0.13197E-08 -8.8795 0.12439E-08 -8.9052 0.94256E+00 -0.0257 65 MnO2-2 0.64138E-14 -14.1929 0.53424E-14 -14.2723 0.83295E+00 -0.0794 66 HMnO2- 0.17228E-11 -11.7638 0.16236E-11 -11.7895 0.94243E+00 -0.0257 69 MnCl+ 0.47297E-12 -12.3252 0.44580E-12 -12.3509 0.94256E+00 -0.0257 70 MnSO4,aq 0.34092E-11 -11.4674 0.34092E-11 -11.4674 0.10000E+01 0.0000 71 NaCl,aq 0.36333E-07 -7.4397 0.36333E-07 -7.4397 0.10000E+01 0.0000 72 NaOH,aq 0.26810E-06 -6.5717 0.26810E-06 -6.5717 0.10000E+01 0.0000 74 OH- 0.45380E-03 -3.3431 0.42762E-03 -3.3689 0.94231E+00 -0.0258 79 HPO3-2 0.48014E-18 -18.3186 0.39994E-18 -18.3980 0.83295E+00 -0.0794 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.74783E-08 -8.1262 0.70482E-08 -8.1519 0.94250E+00 -0.0257 84 PO4-3 0.26251E-09 -9.5809 0.17843E-09 -9.7485 0.67972E+00 -0.1677 87 H2P2O7-2 0.46677E-17 -17.3309 0.38880E-17 -17.4103 0.83295E+00 -0.0794 88 HP2O7-3 0.83901E-15 -15.0762 0.56836E-15 -15.2454 0.67741E+00 -0.1691 89 P2O7-4 0.19665E-15 -15.7063 0.99957E-16 -16.0002 0.50829E+00 -0.2939 90 H2S,aq 0.23784E-15 -15.6237 0.23779E-15 -15.6238 0.99977E+00 -0.0001 97 SO3-2 0.15340E-14 -14.8142 0.12791E-14 -14.8931 0.83380E+00 -0.0789 98 HSO3- 0.11141E-15 -15.9531 0.10500E-15 -15.9788 0.94243E+00 -0.0257 99 HSO4- 0.29318E-10 -10.5329 0.27635E-10 -10.5585 0.94262E+00 -0.0257 Charge balance for all species = -.5772E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1487777E-08 -.8465240E-03 -.8531623E+00 0.0000 2 H2O 0.1000000E+01 0.5550847E+02 0.9999044E+06 0.0000 3 Cl- 0.1379544E-03 0.1379909E-03 0.4891714E+01 4.9670 4 SO4-- 0.2548746E-04 0.2550762E-04 0.2450065E+01 13.0331 5 HCO3- 0.1213263E-04 0.1307158E-04 0.7975137E+00 3.9113 6 HS- 0.5986661E-13 -.6862882E-10 -.2269472E-05 -4.3955 7 Al+++ 0.2456704E-23 0.2632758E-04 0.7102885E+00 2.7803 8 H4SiO4 0.3829605E-03 0.6692219E-03 0.6431627E+02 -3.4168 9 Ca++ 0.2113457E-06 0.2247265E-06 0.9005712E-02 10.9515 10 Mg++ 0.8612927E-09 0.1080788E-08 0.2627357E-04 8.5615 11 Fe++ 0.5094101E-11 0.2323390E-08 0.1297417E-03 6.3335 12 K+ 0.5775328E-04 0.5778922E-04 0.2259454E+01 4.5889 13 Na+ 0.9081470E-03 0.9120723E-03 0.2096632E+02 5.7854 14 Mn++ 0.6805368E-09 0.2309790E-08 0.1268829E-03 8.4593 15 HPO4-- 0.3440223E-06 0.3517630E-06 0.3375858E-01 11.1633 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9905511E-02 -.8464215E-03 -.9059089E-02 0.0000000E+00 2 H2O 0.5550074E+02 0.5550176E+02 -.1014110E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4210480E-04 0.2550454E-04 0.1660026E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1660033E-04 -.6862052E-10 -.1660026E-04 0.0000000E+00 7 Al+++ 0.1953184E-02 0.2632440E-04 0.1926860E-02 0.0000000E+00 8 H4SiO4 0.6237257E-02 0.6691409E-03 0.5568116E-02 0.0000000E+00 9 Ca++ 0.7034065E-03 0.2246993E-06 0.7031818E-03 0.0000000E+00 10 Mg++ 0.4753968E-03 0.1080658E-08 0.4753957E-03 0.0000000E+00 11 Fe++ 0.4270921E-03 0.2323109E-08 0.4270898E-03 0.0000000E+00 12 K+ 0.1271762E-03 0.5778223E-04 0.6939399E-04 0.0000000E+00 13 Na+ 0.9119619E-03 0.9119619E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1038582E-04 0.2309511E-08 0.1038351E-04 0.0000000E+00 15 HPO4-- 0.3544628E-05 0.3517205E-06 0.3192908E-05 0.0000000E+00 Chg. balance for solid moles: 0.2058E-17 Mass of aqueous solution: 0.999976E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1064E-05 -5.973 0.5346E-03 -3.272 0.8513E-01 0.1699E-03 clinochlore 0.9508E-04 -4.022 0.5285E-01 -1.277 8.415 0.2010E-01 daphnite 0.5886E-04 -4.230 0.4200E-01 -1.377 6.687 0.1273E-01 chlorite-Mn 0.2077E-05 -5.683 0.1472E-02 -2.832 0.2345 0.4692E-03 hematite 0.6640E-04 -4.178 0.1060E-01 -1.975 1.689 0.2010E-02 kaolinite 0.5465E-05 -5.262 0.1411E-02 -2.851 0.2247 0.5429E-03 lawsonite 0.8117E-06 -6.091 0.2551E-03 -3.593 0.4062E-01 0.8226E-04 muscovite 0.6939E-04 -4.159 0.2764E-01 -1.558 4.401 0.9774E-02 stilbite 0.6970E-03 -3.157 0.4912 -0.309 78.22 0.2291 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.627985 g Volume = 0.274991 cm3 Porosity: 77.8161% V(tot) - V(min): 0.96461E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.5990000 g log = -0.2226 Original solution: 1000.0103000 g Original solution / Rock added: 1669.47 (Water/Rock Ratio), log = 3.2226 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3494E-05 1.0073 0.3702E-05 0.3675E-05 CH4,gas 0.4425E-16 1.0129 0.4715E-16 0.4655E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.6620E-14 0.9959 0.6935E-14 0.6964E-14 S2,gas 0.4664E-35 1.0000 0.4906E-35 0.4906E-35 CO,gas 0.5524E-15 1.0000 0.5811E-15 0.5811E-15 SO3,gas 0.1485E-37 1.0000 0.1562E-37 0.1562E-37 SO2,gas 0.3404E-21 1.0000 0.3580E-21 0.3580E-21 HCl,gas 0.5758E-16 1.0000 0.6057E-16 0.6057E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 0.15165E-10 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.24265E-10 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.79 -7.43 -2.477 0.12689E+05 -5.432 3 CH4,gas 4.81 -13.52 -18.33 -4.582 0.31292E+05 -16.327 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -22.10 -16.16 -8.079 0.27591E+05 -14.159 6 S2,gas -7.03 -44.34 -37.31 -5.740 0.63705E+05 -35.309 7 CO,gas 3.51 -13.73 -17.24 -5.303 0.29430E+05 -15.236 8 SO3,gas 17.43 -22.38 -39.81 -9.952 0.67968E+05 -37.806 9 SO2,gas 1.14 -22.31 -23.45 -6.252 0.40034E+05 -21.446 10 HCl,gas 5.48 -12.74 -18.22 -9.109 0.31106E+05 -16.218 11 acmite 7.74 5.25 -2.49 -0.258 0.42462E+04 15 albite-high 0.75 -1.68 -2.43 -0.187 0.41568E+04 16 albite -0.33 -1.68 -1.36 -0.104 0.23161E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65943E+04 20 analcite 3.37 1.73 -1.64 -0.182 0.27979E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 16.12 -4.09 -0.227 0.69840E+04 27 phlogopite 27.15 22.80 -4.34 -0.241 0.74161E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.84 -3.83 -1.276 0.65387E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.84 -3.68 -1.225 0.62774E+04 38 carnegieite-low 9.06 5.15 -3.92 -0.559 0.66859E+04 39 carnegieite-high 10.13 5.15 -4.99 -0.712 0.85128E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.26 -3.14 -0.185 0.53566E+04 43 celadonite-Fe 3.94 0.04 -3.90 -0.230 0.66620E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14688E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.88 -4.61 -0.384 0.78751E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68768E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.73 -2.52 -0.252 0.43009E+04 97 kalsilite 7.62 3.95 -3.67 -0.524 0.62629E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.54 -3.63 -0.363 0.62018E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -2.88 -0.45 -0.035 0.76761E+03 121 paragonite 4.34 3.88 -0.46 -0.027 0.78699E+03 122 nepheline 8.38 5.15 -3.23 -0.461 0.55139E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58501E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40528E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.34 -4.38 -1.459 0.74735E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41321E+04 153 sanidine -1.22 -2.88 -1.66 -0.128 0.28354E+04 155 siderite -2.59 -7.46 -4.87 -1.625 0.83216E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.19 -0.99 -0.030 0.16933E+04 165 stilpnomelane-Mg 27.60 23.33 -4.27 -0.127 0.72881E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77454E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78734E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.55 -3.11 -0.191 0.53144E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.15 -2.90 -0.177 0.49441E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.68 -2.52 -0.155 0.43092E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.29 -2.33 -0.143 0.39770E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.49 -0.91 -0.059 0.15610E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.88 -0.70 -0.045 0.11924E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.59 -1.49 -0.115 0.25465E+04 243 an25ab75 2.71 1.16 -1.55 -0.119 0.26520E+04 244 an30ab70 3.34 1.72 -1.62 -0.125 0.27659E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.5990000 g New total amount of reactant added: 0.6190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5872E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.6190000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .7464557E-03 Osmotic coef. = 0.9841 True ionic strength = .1016540E-02 Chg. balance for total moles = -.5872E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14453E-08 -8.8400 0.13620E-08 -8.8658 0.94241E+00 -0.0258 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12995E-03 -3.8862 0.94200E+00 -0.0259 4 SO4-- 0.25488E-04 -4.5937 0.21195E-04 -4.6738 0.83156E+00 -0.0801 5 HCO3- 0.12107E-04 -4.9169 0.11406E-04 -4.9429 0.94210E+00 -0.0259 6 HS- 0.58053E-13 -13.2362 0.54686E-13 -13.2621 0.94201E+00 -0.0259 7 Al+++ 0.22584E-23 -23.6462 0.15235E-23 -23.8171 0.67460E+00 -0.1710 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.19963E-06 -6.6998 0.16592E-06 -6.7801 0.83113E+00 -0.0803 10 Mg++ 0.81357E-09 -9.0896 0.67596E-09 -9.1701 0.83086E+00 -0.0805 11 Fe++ 0.48118E-11 -11.3177 0.39982E-11 -11.3981 0.83092E+00 -0.0804 12 K+ 0.56104E-04 -4.2510 0.52857E-04 -4.2769 0.94211E+00 -0.0259 13 Na+ 0.93303E-03 -3.0301 0.87891E-03 -3.0561 0.94199E+00 -0.0260 14 Mn++ 0.64283E-09 -9.1919 0.53417E-09 -9.2723 0.83097E+00 -0.0804 15 HPO4-- 0.36554E-06 -6.4371 0.30397E-06 -6.5172 0.83156E+00 -0.0801 16 HSiO3- 0.29121E-03 -3.5358 0.27432E-03 -3.5617 0.94200E+00 -0.0259 17 Ca(HSiO3)+ 0.10824E-08 -8.9656 0.10198E-08 -8.9915 0.94213E+00 -0.0259 18 Mg(HSiO3)+ 0.54881E-11 -11.2606 0.51705E-11 -11.2865 0.94213E+00 -0.0259 19 NaHSiO3,aq 0.38293E-05 -5.4169 0.38293E-05 -5.4169 0.10000E+01 0.0000 20 AlO+ 0.11253E-12 -12.9487 0.10602E-12 -12.9746 0.94213E+00 -0.0259 21 AlOH+2 0.87044E-18 -18.0603 0.72336E-18 -18.1406 0.83103E+00 -0.0804 22 HAlO2,aq 0.15576E-07 -7.8075 0.15576E-07 -7.8075 0.10000E+01 0.0000 23 AlO2- 0.27110E-04 -4.5669 0.25535E-04 -4.5929 0.94188E+00 -0.0260 24 CH4,aq 0.28885E-19 -19.5393 0.28879E-19 -19.5394 0.99977E+00 -0.0001 29 CO,aq 0.35642E-18 -18.4480 0.35642E-18 -18.4480 0.10000E+01 0.0000 30 CO2,aq 0.31331E-07 -7.5040 0.31324E-07 -7.5041 0.99977E+00 -0.0001 31 CO3-2 0.93128E-06 -6.0309 0.77429E-06 -6.1111 0.83143E+00 -0.0802 32 CaCO3,aq 0.15735E-08 -8.8031 0.15735E-08 -8.8031 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.50616E-10 -10.2957 0.47686E-10 -10.3216 0.94213E+00 -0.0259 34 CaCl+ 0.36469E-10 -10.4381 0.34358E-10 -10.4640 0.94213E+00 -0.0259 35 CaCl2,aq 0.10396E-14 -14.9831 0.10396E-14 -14.9831 0.10000E+01 0.0000 36 CaOH+ 0.91173E-08 -8.0401 0.85896E-08 -8.0660 0.94213E+00 -0.0259 37 CaSO4,aq 0.10957E-08 -8.9603 0.10957E-08 -8.9603 0.10000E+01 0.0000 38 HCl,aq 0.33293E-13 -13.4776 0.33293E-13 -13.4776 0.10000E+01 0.0000 43 FeCl+ 0.85896E-15 -15.0660 0.80925E-15 -15.0919 0.94213E+00 -0.0259 46 FeO,aq 0.85225E-10 -10.0694 0.85225E-10 -10.0694 0.10000E+01 0.0000 47 FeOH+ 0.10330E-09 -9.9859 0.97318E-10 -10.0118 0.94213E+00 -0.0259 48 HFeO2- 0.71445E-09 -9.1460 0.67302E-09 -9.1720 0.94200E+00 -0.0259 49 FeO+ 0.11959E-13 -13.9223 0.11267E-13 -13.9482 0.94213E+00 -0.0259 51 FeO2- 0.12671E-08 -8.8972 0.11937E-08 -8.9231 0.94200E+00 -0.0259 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44191E-09 -9.3547 0.44180E-09 -9.3548 0.99977E+00 -0.0001 54 KCl,aq 0.12162E-09 -9.9150 0.12162E-09 -9.9150 0.10000E+01 0.0000 55 KHSO4,aq 0.40832E-17 -17.3890 0.40832E-17 -17.3890 0.10000E+01 0.0000 56 KOH,aq 0.16918E-07 -7.7717 0.16918E-07 -7.7717 0.10000E+01 0.0000 57 KSO4- 0.18322E-07 -7.7370 0.17260E-07 -7.7630 0.94200E+00 -0.0259 58 MgCO3,aq 0.16018E-11 -11.7954 0.16018E-11 -11.7954 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21028E-12 -12.6772 0.19811E-12 -12.7031 0.94213E+00 -0.0259 60 MgCl+ 0.13488E-12 -12.8701 0.12707E-12 -12.8959 0.94213E+00 -0.0259 61 MgOH+ 0.20578E-09 -9.6866 0.19387E-09 -9.7125 0.94213E+00 -0.0259 63 MnO,aq 0.30396E-09 -9.5172 0.30396E-09 -9.5172 0.10000E+01 0.0000 64 MnOH+ 0.12820E-08 -8.8921 0.12078E-08 -8.9180 0.94213E+00 -0.0259 65 MnO2-2 0.68151E-14 -14.1665 0.56663E-14 -14.2467 0.83143E+00 -0.0802 66 HMnO2- 0.17751E-11 -11.7508 0.16721E-11 -11.7767 0.94200E+00 -0.0259 69 MnCl+ 0.44594E-12 -12.3507 0.42013E-12 -12.3766 0.94213E+00 -0.0259 70 MnSO4,aq 0.32086E-11 -11.4937 0.32086E-11 -11.4937 0.10000E+01 0.0000 71 NaCl,aq 0.37295E-07 -7.4284 0.37295E-07 -7.4284 0.10000E+01 0.0000 72 NaOH,aq 0.28354E-06 -6.5474 0.28354E-06 -6.5474 0.10000E+01 0.0000 74 OH- 0.46757E-03 -3.3302 0.44039E-03 -3.3562 0.94188E+00 -0.0260 79 HPO3-2 0.51018E-18 -18.2923 0.42418E-18 -18.3725 0.83143E+00 -0.0802 82 H3PO4,aq 0.36305E-14 -14.4400 0.36305E-14 -14.4400 0.10000E+01 0.0000 83 H2PO4- 0.77051E-08 -8.1132 0.72587E-08 -8.1391 0.94206E+00 -0.0259 84 PO4-3 0.28790E-09 -9.5408 0.19490E-09 -9.7102 0.67698E+00 -0.1694 87 H2P2O7-2 0.49598E-17 -17.3045 0.41237E-17 -17.3847 0.83143E+00 -0.0802 88 HP2O7-3 0.92024E-15 -15.0361 0.62081E-15 -15.2070 0.67462E+00 -0.1709 89 P2O7-4 0.22284E-15 -15.6520 0.11244E-15 -15.9491 0.50460E+00 -0.2971 90 H2S,aq 0.22385E-15 -15.6500 0.22380E-15 -15.6501 0.99977E+00 -0.0001 97 SO3-2 0.15340E-14 -14.8142 0.12768E-14 -14.8939 0.83229E+00 -0.0797 98 HSO3- 0.10804E-15 -15.9664 0.10177E-15 -15.9924 0.94200E+00 -0.0259 99 HSO4- 0.28429E-10 -10.5462 0.26786E-10 -10.5721 0.94219E+00 -0.0259 Charge balance for all species = -.5781E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1445289E-08 -.8723121E-03 -.8791514E+00 0.0000 2 H2O 0.1000000E+01 0.5550848E+02 0.9999031E+06 0.0000 3 Cl- 0.1379539E-03 0.1379914E-03 0.4891725E+01 4.9796 4 SO4-- 0.2548820E-04 0.2550772E-04 0.2450071E+01 13.0578 5 HCO3- 0.1210739E-04 0.1307163E-04 0.7975154E+00 3.9230 6 HS- 0.5805296E-13 -.7329407E-10 -.2423742E-05 -4.3963 7 Al+++ 0.2258433E-23 0.2712593E-04 0.7318259E+00 2.7803 8 H4SiO4 0.3829605E-03 0.6780052E-03 0.6516031E+02 -3.4168 9 Ca++ 0.1996329E-06 0.2125889E-06 0.8519297E-02 10.9515 10 Mg++ 0.8135654E-09 0.1026778E-08 0.2496057E-04 8.5615 11 Fe++ 0.4811810E-11 0.2378420E-08 0.1328145E-03 6.3335 12 K+ 0.5610434E-04 0.5613970E-04 0.2194958E+01 4.5889 13 Na+ 0.9330335E-03 0.9371836E-03 0.2154354E+02 5.8098 14 Mn++ 0.6428329E-09 0.2234254E-08 0.1227333E-03 8.4593 15 HPO4-- 0.3655429E-06 0.3735359E-06 0.3584806E-01 11.2144 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1023668E-01 -.8722034E-03 -.9364478E-02 0.0000000E+00 2 H2O 0.5550049E+02 0.5550156E+02 -.1067229E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4265907E-04 0.2550454E-04 0.1715453E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1715460E-04 -.7328493E-10 -.1715453E-04 0.0000000E+00 7 Al+++ 0.2018399E-02 0.2712254E-04 0.1991277E-02 0.0000000E+00 8 H4SiO4 0.6445513E-02 0.6779207E-03 0.5767592E-02 0.0000000E+00 9 Ca++ 0.7264094E-03 0.2125624E-06 0.7261968E-03 0.0000000E+00 10 Mg++ 0.4912698E-03 0.1026650E-08 0.4912688E-03 0.0000000E+00 11 Fe++ 0.4413523E-03 0.2378124E-08 0.4413499E-03 0.0000000E+00 12 K+ 0.1314225E-03 0.5613271E-04 0.7528980E-04 0.0000000E+00 13 Na+ 0.9370668E-03 0.9370668E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1073259E-04 0.2233976E-08 0.1073036E-04 0.0000000E+00 15 HPO4-- 0.3662980E-05 0.3734894E-06 0.3289491E-05 0.0000000E+00 Chg. balance for solid moles: -.2114E-17 Mass of aqueous solution: 0.999974E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.6190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1096E-05 -5.960 0.5508E-03 -3.259 0.8473E-01 0.1750E-03 clinochlore 0.9825E-04 -4.008 0.5461E-01 -1.263 8.402 0.2077E-01 daphnite 0.6082E-04 -4.216 0.4340E-01 -1.363 6.676 0.1315E-01 chlorite-Mn 0.2146E-05 -5.668 0.1522E-02 -2.818 0.2341 0.4849E-03 hematite 0.6862E-04 -4.164 0.1096E-01 -1.960 1.686 0.2077E-02 kaolinite 0.7667E-06 -6.115 0.1979E-03 -3.704 0.3045E-01 0.7615E-04 lawsonite -.2304E-05 1.000 -.7241E-03 1.000 -.1114 -.2335E-03 muscovite 0.7529E-04 -4.123 0.2999E-01 -1.523 4.613 0.1060E-01 stilbite 0.7230E-03 -3.141 0.5095 -0.293 78.39 0.2377 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.650029 g Volume = 0.284759 cm3 Porosity: 77.1754% V(tot) - V(min): 0.96284E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.6190000 g log = -0.2083 Original solution: 1000.0103000 g Original solution / Rock added: 1615.53 (Water/Rock Ratio), log = 3.2083 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3384E-05 1.0073 0.3586E-05 0.3559E-05 CH4,gas 0.4286E-16 1.0129 0.4567E-16 0.4509E-16 H2,gas 0.5757E-06 1.0006 0.6060E-06 0.6056E-06 H2S,gas 0.6230E-14 0.9959 0.6527E-14 0.6554E-14 S2,gas 0.4131E-35 1.0000 0.4346E-35 0.4346E-35 CO,gas 0.5350E-15 1.0000 0.5628E-15 0.5628E-15 SO3,gas 0.1397E-37 1.0000 0.1470E-37 0.1470E-37 SO2,gas 0.3203E-21 1.0000 0.3370E-21 0.3370E-21 HCl,gas 0.5588E-16 1.0000 0.5879E-16 0.5879E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.18198E-10 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.81 -7.45 -2.482 0.12713E+05 -5.445 3 CH4,gas 4.81 -13.53 -18.34 -4.585 0.31316E+05 -16.340 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14031E+05 -6.218 5 H2S,gas -5.94 -22.13 -16.19 -8.093 0.27636E+05 -14.185 6 S2,gas -7.03 -44.39 -37.36 -5.748 0.63794E+05 -35.362 7 CO,gas 3.51 -13.74 -17.25 -5.308 0.29453E+05 -15.250 8 SO3,gas 17.43 -22.41 -39.83 -9.958 0.68013E+05 -37.833 9 SO2,gas 1.14 -22.34 -23.47 -6.259 0.40078E+05 -21.472 10 HCl,gas 5.48 -12.75 -18.23 -9.115 0.31128E+05 -16.231 11 acmite 7.74 5.27 -2.46 -0.256 0.42047E+04 15 albite-high 0.75 -1.66 -2.41 -0.185 0.41153E+04 16 albite -0.33 -1.66 -1.33 -0.102 0.22746E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65942E+04 20 analcite 3.37 1.76 -1.61 -0.179 0.27564E+04 21 andalusite 5.06 2.14 -2.92 -0.292 0.49835E+04 22 andradite 39.09 35.20 -3.89 -0.202 0.66354E+04 23 grossular 32.83 28.16 -4.66 -0.233 0.79630E+04 26 annite 20.21 16.12 -4.09 -0.227 0.69840E+04 27 phlogopite 27.15 22.80 -4.34 -0.241 0.74161E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.86 -3.84 -1.281 0.65624E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68556E+04 37 calcite 0.83 -2.86 -3.69 -1.230 0.63011E+04 38 carnegieite-low 9.06 5.17 -3.89 -0.556 0.66444E+04 39 carnegieite-high 10.13 5.17 -4.96 -0.709 0.84713E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23255E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29412E+04 42 celadonite 5.40 2.26 -3.14 -0.185 0.53566E+04 43 celadonite-Fe 3.94 0.04 -3.90 -0.230 0.66620E+04 50 chloritoid-Mg 13.26 10.71 -2.56 -0.170 0.43643E+04 51 chloritoid-Fe 9.24 8.48 -0.76 -0.051 0.13002E+04 52 chloritoid-Mn 11.46 10.60 -0.86 -0.057 0.14688E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 5.56 -2.87 -0.261 0.49054E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.88 -4.61 -0.384 0.78751E+04 65 diaspore 2.90 2.78 -0.12 -0.019 0.19775E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60378E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64766E+04 75 epidote 24.78 23.51 -1.26 -0.061 0.21571E+04 76 clinozoisite 22.92 19.99 -2.93 -0.133 0.49992E+04 77 epidote-Fe 29.94 27.03 -2.91 -0.151 0.49626E+04 78 fayalite 14.08 9.25 -4.83 -0.690 0.82451E+04 83 gibbsite 4.10 2.78 -1.32 -0.188 0.22489E+04 87 greenalite 16.19 12.17 -4.03 -0.336 0.68768E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.76 -2.49 -0.249 0.42594E+04 97 kalsilite 7.62 3.95 -3.67 -0.524 0.62629E+04 99 kyanite 4.93 2.14 -2.79 -0.279 0.47603E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 103 leucite 4.17 0.54 -3.63 -0.363 0.62018E+04 105 lizardite 23.29 18.85 -4.44 -0.370 0.75752E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20518E+04 113 margarite 17.45 15.24 -2.21 -0.089 0.37784E+04 116 microcline -2.43 -2.88 -0.45 -0.035 0.76761E+03 121 paragonite 4.34 3.90 -0.44 -0.026 0.74546E+03 122 nepheline 8.38 5.17 -3.20 -0.458 0.54723E+04 136 prehnite 19.47 17.21 -2.25 -0.133 0.38474E+04 137 prehnite-Fe 22.59 20.73 -1.86 -0.112 0.31677E+04 138 pumpellyite-Fe 46.47 43.54 -2.93 -0.065 0.50041E+04 139 pumpellyite-Mg 49.19 45.77 -3.43 -0.076 0.58501E+04 145 pyroxmangite 7.42 5.04 -2.37 -0.475 0.40528E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34300E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 151 rhodochrosite -0.96 -5.35 -4.39 -1.464 0.74972E+04 152 rhodonite 7.46 5.04 -2.42 -0.484 0.41321E+04 153 sanidine -1.22 -2.88 -1.66 -0.128 0.28354E+04 155 siderite -2.59 -7.48 -4.89 -1.629 0.83453E+04 156 sillimanite 5.32 2.14 -3.18 -0.318 0.54257E+04 164 stilpnomelane-Fe 13.18 12.19 -0.99 -0.030 0.16933E+04 165 stilpnomelane-Mg 27.60 23.33 -4.27 -0.127 0.72881E+04 167 sudoite-Fe 18.44 13.54 -4.90 -0.158 0.83657E+04 168 sudoite 21.22 17.99 -3.22 -0.104 0.55024E+04 171 talc 16.55 12.02 -4.54 -0.267 0.77454E+04 174 tephroite 18.11 13.50 -4.61 -0.659 0.78734E+04 177 topaz-H 4.67 2.14 -2.52 -0.229 0.43094E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 7.53 -3.99 -0.799 0.68183E+04 189 wollastonite 10.48 7.53 -2.95 -0.589 0.50322E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.697 0.59508E+04 191 zoisite 22.96 19.99 -2.97 -0.135 0.50717E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.70 -0.167 0.46018E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65237E+04 195 beidellite-K -1.44 -4.55 -3.11 -0.191 0.53144E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50238E+04 197 beidellite-Na -1.26 -4.14 -2.89 -0.177 0.49304E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37189E+04 202 montmorillonite-K -2.16 -4.68 -2.52 -0.155 0.43092E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -4.28 -2.32 -0.142 0.39633E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.98 -1.62 -0.109 0.27669E+04 207 nontronite-K 3.40 2.49 -0.91 -0.059 0.15610E+04 208 nontronite-Mg 3.14 2.39 -0.75 -0.049 0.12828E+04 209 nontronite-Na 3.58 2.89 -0.69 -0.044 0.11787E+04 224 tobermorite 9.84 5.71 -4.13 -1.128 0.70574E+04 233 boehmite 4.43 2.78 -1.65 -0.275 0.28162E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59603E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 0.61 -1.47 -0.113 0.25133E+04 243 an25ab75 2.71 1.17 -1.53 -0.118 0.26209E+04 244 an30ab70 3.34 1.74 -1.60 -0.123 0.27368E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.6190000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .7438638E-03 Osmotic coef. = 0.9841 True ionic strength = .1016827E-02 Chg. balance for total moles = -.5872E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14537E-08 -8.8375 0.13700E-08 -8.8633 0.94240E+00 -0.0258 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12995E-03 -3.8862 0.94199E+00 -0.0260 4 SO4-- 0.25488E-04 -4.5937 0.21194E-04 -4.6738 0.83154E+00 -0.0801 5 HCO3- 0.12112E-04 -4.9168 0.11411E-04 -4.9427 0.94209E+00 -0.0259 6 HS- 0.56761E-13 -13.2460 0.53469E-13 -13.2719 0.94200E+00 -0.0259 7 Al+++ 0.22579E-23 -23.6463 0.15231E-23 -23.8173 0.67456E+00 -0.1710 8 H4SiO4 0.38979E-03 -3.4092 0.38979E-03 -3.4092 0.10000E+01 0.0000 9 Ca++ 0.18488E-06 -6.7331 0.15365E-06 -6.8135 0.83111E+00 -0.0803 10 Mg++ 0.82018E-09 -9.0861 0.68143E-09 -9.1666 0.83084E+00 -0.0805 11 Fe++ 0.48509E-11 -11.3142 0.40306E-11 -11.3946 0.83090E+00 -0.0804 12 K+ 0.56431E-04 -4.2485 0.53164E-04 -4.2744 0.94211E+00 -0.0259 13 Na+ 0.93299E-03 -3.0301 0.87886E-03 -3.0561 0.94198E+00 -0.0260 14 Mn++ 0.64806E-09 -9.1884 0.53850E-09 -9.2688 0.83095E+00 -0.0804 15 HPO4-- 0.41871E-06 -6.3781 0.34818E-06 -6.4582 0.83155E+00 -0.0801 16 HSiO3- 0.29470E-03 -3.5306 0.27760E-03 -3.5566 0.94199E+00 -0.0260 17 Ca(HSiO3)+ 0.10144E-08 -8.9938 0.95567E-09 -9.0197 0.94212E+00 -0.0259 18 Mg(HSiO3)+ 0.55987E-11 -11.2519 0.52747E-11 -11.2778 0.94212E+00 -0.0259 19 NaHSiO3,aq 0.38749E-05 -5.4117 0.38749E-05 -5.4117 0.10000E+01 0.0000 20 AlO+ 0.11120E-12 -12.9539 0.10477E-12 -12.9798 0.94212E+00 -0.0259 21 AlOH+2 0.86519E-18 -18.0629 0.71898E-18 -18.1433 0.83101E+00 -0.0804 22 HAlO2,aq 0.15303E-07 -7.8152 0.15303E-07 -7.8152 0.10000E+01 0.0000 23 AlO2- 0.26481E-04 -4.5771 0.24942E-04 -4.6031 0.94187E+00 -0.0260 24 CH4,aq 0.28254E-19 -19.5489 0.28248E-19 -19.5490 0.99977E+00 -0.0001 29 CO,aq 0.35612E-18 -18.4484 0.35612E-18 -18.4484 0.10000E+01 0.0000 30 CO2,aq 0.31526E-07 -7.5013 0.31519E-07 -7.5014 0.99977E+00 -0.0001 31 CO3-2 0.92628E-06 -6.0333 0.77012E-06 -6.1134 0.83141E+00 -0.0802 32 CaCO3,aq 0.14493E-08 -8.8389 0.14493E-08 -8.8389 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.46892E-10 -10.3289 0.44178E-10 -10.3548 0.94212E+00 -0.0259 34 CaCl+ 0.33772E-10 -10.4714 0.31818E-10 -10.4973 0.94212E+00 -0.0259 35 CaCl2,aq 0.96272E-15 -15.0165 0.96272E-15 -15.0165 0.10000E+01 0.0000 36 CaOH+ 0.83943E-08 -8.0760 0.79085E-08 -8.1019 0.94212E+00 -0.0259 37 CaSO4,aq 0.10147E-08 -8.9937 0.10147E-08 -8.9937 0.10000E+01 0.0000 38 HCl,aq 0.33487E-13 -13.4751 0.33487E-13 -13.4751 0.10000E+01 0.0000 43 FeCl+ 0.86592E-15 -15.0625 0.81581E-15 -15.0884 0.94212E+00 -0.0259 46 FeO,aq 0.84924E-10 -10.0710 0.84924E-10 -10.0710 0.10000E+01 0.0000 47 FeOH+ 0.10353E-09 -9.9849 0.97539E-10 -10.0108 0.94212E+00 -0.0259 48 HFeO2- 0.70782E-09 -9.1501 0.66676E-09 -9.1760 0.94199E+00 -0.0260 49 FeO+ 0.12029E-13 -13.9198 0.11333E-13 -13.9457 0.94212E+00 -0.0259 51 FeO2- 0.12598E-08 -8.8997 0.11867E-08 -8.9256 0.94199E+00 -0.0260 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.43879E-09 -9.3577 0.43869E-09 -9.3578 0.99977E+00 -0.0001 54 KCl,aq 0.12233E-09 -9.9125 0.12233E-09 -9.9125 0.10000E+01 0.0000 55 KHSO4,aq 0.41308E-17 -17.3840 0.41308E-17 -17.3840 0.10000E+01 0.0000 56 KOH,aq 0.16918E-07 -7.7717 0.16918E-07 -7.7717 0.10000E+01 0.0000 57 KSO4- 0.18429E-07 -7.7345 0.17360E-07 -7.7605 0.94199E+00 -0.0260 58 MgCO3,aq 0.16061E-11 -11.7942 0.16061E-11 -11.7942 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21207E-12 -12.6735 0.19979E-12 -12.6994 0.94212E+00 -0.0259 60 MgCl+ 0.13597E-12 -12.8666 0.12810E-12 -12.8924 0.94212E+00 -0.0259 61 MgOH+ 0.20625E-09 -9.6856 0.19431E-09 -9.7115 0.94212E+00 -0.0259 63 MnO,aq 0.30289E-09 -9.5187 0.30289E-09 -9.5187 0.10000E+01 0.0000 64 MnOH+ 0.12849E-08 -8.8911 0.12106E-08 -8.9170 0.94212E+00 -0.0259 65 MnO2-2 0.67128E-14 -14.1731 0.55811E-14 -14.2533 0.83141E+00 -0.0802 66 HMnO2- 0.17586E-11 -11.7548 0.16566E-11 -11.7808 0.94199E+00 -0.0260 69 MnCl+ 0.44955E-12 -12.3472 0.42353E-12 -12.3731 0.94212E+00 -0.0259 70 MnSO4,aq 0.32345E-11 -11.4902 0.32345E-11 -11.4902 0.10000E+01 0.0000 71 NaCl,aq 0.37292E-07 -7.4284 0.37292E-07 -7.4284 0.10000E+01 0.0000 72 NaOH,aq 0.28189E-06 -6.5499 0.28189E-06 -6.5499 0.10000E+01 0.0000 74 OH- 0.46487E-03 -3.3327 0.43784E-03 -3.3587 0.94187E+00 -0.0260 79 HPO3-2 0.58027E-18 -18.2364 0.48244E-18 -18.3166 0.83141E+00 -0.0802 82 H3PO4,aq 0.42070E-14 -14.3760 0.42070E-14 -14.3760 0.10000E+01 0.0000 83 H2PO4- 0.88770E-08 -8.0517 0.83627E-08 -8.0777 0.94206E+00 -0.0259 84 PO4-3 0.32787E-09 -9.4843 0.22195E-09 -9.6537 0.67694E+00 -0.1694 87 H2P2O7-2 0.65833E-17 -17.1816 0.54734E-17 -17.2617 0.83141E+00 -0.0802 88 HP2O7-3 0.12144E-14 -14.9156 0.81924E-15 -15.0866 0.67459E+00 -0.1710 89 P2O7-4 0.29239E-15 -15.5340 0.14752E-15 -15.8311 0.50455E+00 -0.2971 90 H2S,aq 0.22014E-15 -15.6573 0.22009E-15 -15.6574 0.99977E+00 -0.0001 97 SO3-2 0.15232E-14 -14.8172 0.12677E-14 -14.8970 0.83227E+00 -0.0797 98 HSO3- 0.10790E-15 -15.9670 0.10164E-15 -15.9929 0.94199E+00 -0.0260 99 HSO4- 0.28594E-10 -10.5437 0.26941E-10 -10.5696 0.94219E+00 -0.0259 Charge balance for all species = -.5877E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1453710E-08 -.8706104E-03 -.8774355E+00 0.0000 2 H2O 0.1000000E+01 0.5550847E+02 0.9999021E+06 0.0000 3 Cl- 0.1379539E-03 0.1379914E-03 0.4891721E+01 4.9771 4 SO4-- 0.2548818E-04 0.2550772E-04 0.2450069E+01 13.0528 5 HCO3- 0.1211232E-04 0.1307163E-04 0.7975148E+00 3.9206 6 HS- 0.5676075E-13 -.7315852E-10 -.2419257E-05 -4.4086 7 Al+++ 0.2257928E-23 0.2649641E-04 0.7148417E+00 2.7726 8 H4SiO4 0.3897937E-03 0.6883665E-03 0.6615603E+02 -3.4092 9 Ca++ 0.1848753E-06 0.1968286E-06 0.7887709E-02 10.9131 10 Mg++ 0.8201765E-09 0.1033975E-08 0.2513550E-04 8.5600 11 Fe++ 0.4850911E-11 0.2364429E-08 0.1320331E-03 6.3319 12 K+ 0.5643123E-04 0.5646670E-04 0.2207741E+01 4.5889 13 Na+ 0.9329896E-03 0.9371837E-03 0.2154352E+02 5.8072 14 Mn++ 0.6480562E-09 0.2241333E-08 0.1231221E-03 8.4578 15 HPO4-- 0.4187107E-06 0.4279157E-06 0.4106682E-01 11.2684 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1023668E-01 -.8705018E-03 -.9366179E-02 0.0000000E+00 2 H2O 0.5550049E+02 0.5550155E+02 -.1055347E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4265907E-04 0.2550454E-04 0.1715453E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1715460E-04 -.7314939E-10 -.1715453E-04 0.0000000E+00 7 Al+++ 0.2018399E-02 0.2649311E-04 0.1991906E-02 0.0000000E+00 8 H4SiO4 0.6445513E-02 0.6882806E-03 0.5757232E-02 0.0000000E+00 9 Ca++ 0.7264094E-03 0.1968040E-06 0.7262126E-03 0.0000000E+00 10 Mg++ 0.4912698E-03 0.1033846E-08 0.4912688E-03 0.0000000E+00 11 Fe++ 0.4413523E-03 0.2364134E-08 0.4413500E-03 0.0000000E+00 12 K+ 0.1314225E-03 0.5645966E-04 0.7496285E-04 0.0000000E+00 13 Na+ 0.9370668E-03 0.9370668E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1073259E-04 0.2241053E-08 0.1073035E-04 0.0000000E+00 15 HPO4-- 0.3662980E-05 0.4278623E-06 0.3235118E-05 0.0000000E+00 Chg. balance for solid moles: 0.3846E-18 Mass of aqueous solution: 0.999975E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.6190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1078E-05 -5.967 0.5417E-03 -3.266 0.8343E-01 0.1721E-03 clinochlore 0.9825E-04 -4.008 0.5461E-01 -1.263 8.412 0.2077E-01 daphnite 0.6082E-04 -4.216 0.4340E-01 -1.363 6.684 0.1315E-01 chlorite-Mn 0.2146E-05 -5.668 0.1521E-02 -2.818 0.2343 0.4849E-03 hematite 0.6862E-04 -4.164 0.1096E-01 -1.960 1.688 0.2077E-02 kaolinite 0.1465E-05 -5.834 0.3783E-03 -3.422 0.5827E-01 0.1456E-03 muscovite 0.7496E-04 -4.125 0.2986E-01 -1.525 4.599 0.1056E-01 stilbite 0.7208E-03 -3.142 0.5080 -0.294 78.24 0.2369 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.649245 g Volume = 0.284291 cm3 Porosity: 77.2130% V(tot) - V(min): 0.96331E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.6190000 g log = -0.2083 Original solution: 1000.0103000 g Original solution / Rock added: 1615.53 (Water/Rock Ratio), log = 3.2083 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3405E-05 1.0073 0.3608E-05 0.3582E-05 CH4,gas 0.4192E-16 1.0129 0.4467E-16 0.4410E-16 H2,gas 0.5717E-06 1.0006 0.6017E-06 0.6014E-06 H2S,gas 0.6127E-14 0.9959 0.6419E-14 0.6445E-14 S2,gas 0.4052E-35 1.0000 0.4263E-35 0.4263E-35 CO,gas 0.5345E-15 1.0000 0.5623E-15 0.5623E-15 SO3,gas 0.1414E-37 1.0000 0.1487E-37 0.1487E-37 SO2,gas 0.3218E-21 1.0000 0.3385E-21 0.3385E-21 HCl,gas 0.5621E-16 1.0000 0.5913E-16 0.5913E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.81 -7.44 -2.481 0.12708E+05 -5.443 3 CH4,gas 4.81 -13.54 -18.35 -4.587 0.31332E+05 -16.350 4 H2,gas 8.29 0.07 -8.22 -4.697 0.14036E+05 -6.221 5 H2S,gas -5.94 -22.14 -16.19 -8.096 0.27648E+05 -14.193 6 S2,gas -7.03 -44.40 -37.37 -5.749 0.63809E+05 -35.370 7 CO,gas 3.51 -13.74 -17.25 -5.308 0.29454E+05 -15.250 8 SO3,gas 17.43 -22.40 -39.83 -9.957 0.68005E+05 -37.828 9 SO2,gas 1.14 -22.33 -23.47 -6.259 0.40075E+05 -21.470 10 HCl,gas 5.48 -12.75 -18.23 -9.114 0.31124E+05 -16.228 11 acmite 7.74 5.29 -2.45 -0.255 0.41828E+04 15 albite-high 0.75 -1.65 -2.40 -0.184 0.40934E+04 16 albite -0.33 -1.65 -1.32 -0.101 0.22527E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65890E+04 20 analcite 3.37 1.76 -1.61 -0.179 0.27476E+04 21 andalusite 5.06 2.14 -2.93 -0.293 0.49967E+04 22 andradite 39.09 35.11 -3.98 -0.207 0.67928E+04 23 grossular 32.83 28.06 -4.77 -0.239 0.81466E+04 26 annite 20.21 16.13 -4.08 -0.227 0.69656E+04 27 phlogopite 27.15 22.81 -4.33 -0.241 0.73978E+04 29 anorthite 12.80 9.64 -3.16 -0.243 0.53917E+04 35 aragonite 0.99 -2.89 -3.88 -1.293 0.66234E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68582E+04 37 calcite 0.83 -2.89 -3.73 -1.242 0.63621E+04 38 carnegieite-low 9.06 5.17 -3.89 -0.556 0.66488E+04 39 carnegieite-high 10.13 5.17 -4.96 -0.709 0.84756E+04 40 carpholite-Mg 8.65 7.29 -1.36 -0.091 0.23282E+04 41 carpholite-Fe 6.78 5.06 -1.72 -0.115 0.29438E+04 42 celadonite 5.40 2.28 -3.12 -0.183 0.53199E+04 43 celadonite-Fe 3.94 0.06 -3.88 -0.228 0.66252E+04 50 chloritoid-Mg 13.26 10.70 -2.57 -0.171 0.43800E+04 51 chloritoid-Fe 9.24 8.47 -0.77 -0.051 0.13160E+04 52 chloritoid-Mn 11.46 10.59 -0.87 -0.058 0.14845E+04 54 coesite -2.37 -3.41 -1.04 -0.347 0.17755E+04 59 corundum 8.43 5.55 -2.89 -0.263 0.49316E+04 61 cristobalite -2.55 -3.41 -0.86 -0.287 0.14683E+04 63 cymrite-K 1.73 -2.87 -4.60 -0.383 0.78489E+04 65 diaspore 2.90 2.77 -0.12 -0.021 0.21086E+03 67 diopside 16.22 12.65 -3.56 -0.356 0.60798E+04 68 hedenbergite 14.24 10.43 -3.82 -0.382 0.65186E+04 75 epidote 24.78 23.44 -1.33 -0.065 0.22752E+04 76 clinozoisite 22.92 19.92 -3.00 -0.137 0.51303E+04 77 epidote-Fe 29.94 26.97 -2.97 -0.154 0.50675E+04 78 fayalite 14.08 9.25 -4.82 -0.689 0.82372E+04 83 gibbsite 4.10 2.77 -1.32 -0.189 0.22620E+04 87 greenalite 16.19 12.18 -4.02 -0.335 0.68584E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.76 -2.49 -0.249 0.42506E+04 97 kalsilite 7.62 3.95 -3.67 -0.524 0.62629E+04 99 kyanite 4.93 2.14 -2.80 -0.280 0.47734E+04 101 laumontite 2.97 2.82 -0.15 -0.010 0.26108E+03 102 lawsonite 9.68 9.64 -0.04 -0.003 0.65574E+02 103 leucite 4.17 0.54 -3.62 -0.362 0.61887E+04 105 lizardite 23.29 18.86 -4.43 -0.369 0.75569E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20545E+04 113 margarite 17.45 15.19 -2.27 -0.091 0.38702E+04 116 microcline -2.43 -2.87 -0.43 -0.033 0.74138E+03 121 paragonite 4.34 3.90 -0.44 -0.026 0.74981E+03 122 nepheline 8.38 5.17 -3.21 -0.458 0.54767E+04 136 prehnite 19.47 17.14 -2.32 -0.137 0.39655E+04 137 prehnite-Fe 22.59 20.67 -1.92 -0.115 0.32726E+04 138 pumpellyite-Fe 46.47 43.39 -3.08 -0.068 0.52559E+04 139 pumpellyite-Mg 49.19 45.62 -3.57 -0.079 0.61019E+04 145 pyroxmangite 7.42 5.05 -2.37 -0.473 0.40423E+04 146 pyrophyllite -6.10 -8.09 -1.99 -0.125 0.34038E+04 147 quartz -2.98 -3.41 -0.43 -0.142 0.72938E+03 151 rhodochrosite -0.96 -5.35 -4.39 -1.463 0.74952E+04 152 rhodonite 7.46 5.05 -2.41 -0.483 0.41216E+04 153 sanidine -1.22 -2.87 -1.65 -0.127 0.28091E+04 155 siderite -2.59 -7.47 -4.89 -1.629 0.83433E+04 156 sillimanite 5.32 2.14 -3.19 -0.319 0.54388E+04 164 stilpnomelane-Fe 13.18 12.23 -0.95 -0.028 0.16277E+04 165 stilpnomelane-Mg 27.60 23.37 -4.23 -0.126 0.72225E+04 167 sudoite-Fe 18.44 13.53 -4.91 -0.158 0.83841E+04 168 sudoite 21.22 17.98 -3.23 -0.104 0.55208E+04 171 talc 16.55 12.04 -4.51 -0.265 0.77008E+04 174 tephroite 18.11 13.51 -4.61 -0.658 0.78655E+04 177 topaz-H 4.67 2.14 -2.53 -0.230 0.43225E+04 178 tridymite -2.61 -3.41 -0.79 -0.265 0.13567E+04 187 wairakite 4.06 2.82 -1.24 -0.073 0.21119E+04 188 walstromite 11.53 7.50 -4.02 -0.805 0.68707E+04 189 wollastonite 10.48 7.50 -2.98 -0.596 0.50846E+04 190 pseudo-wollastonite 11.02 7.50 -3.52 -0.703 0.60033E+04 191 zoisite 22.96 19.92 -3.05 -0.139 0.52029E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.69 -0.166 0.45951E+04 194 beidellite-H -2.24 -6.05 -3.81 -0.243 0.65061E+04 195 beidellite-K -1.44 -4.54 -3.10 -0.190 0.52968E+04 196 beidellite-Mg -1.71 -4.64 -2.93 -0.181 0.50067E+04 197 beidellite-Na -1.26 -4.14 -2.88 -0.176 0.49143E+04 199 chalcedony -2.79 -3.41 -0.61 -0.205 0.10497E+04 201 montmorillonite-Ca -2.21 -4.38 -2.17 -0.134 0.37000E+04 202 montmorillonite-K -2.16 -4.67 -2.51 -0.153 0.42795E+04 203 montmorillonite-Mg -2.40 -4.77 -2.37 -0.146 0.40426E+04 204 montmorillonite-Na -1.96 -4.27 -2.30 -0.141 0.39351E+04 205 nontronite-Ca 3.28 2.80 -0.48 -0.031 0.81626E+03 206 nontronite-H 2.60 1.00 -1.59 -0.107 0.27231E+04 207 nontronite-K 3.40 2.52 -0.89 -0.057 0.15172E+04 208 nontronite-Mg 3.14 2.41 -0.73 -0.047 0.12395E+04 209 nontronite-Na 3.58 2.92 -0.67 -0.043 0.11363E+04 224 tobermorite 9.84 5.68 -4.16 -1.134 0.70989E+04 233 boehmite 4.43 2.77 -1.66 -0.276 0.28293E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59630E+04 240 silica-amorphous -2.08 -3.41 -1.33 -0.443 0.22699E+04 242 an20ab80 2.08 0.61 -1.47 -0.113 0.25089E+04 243 an25ab75 2.71 1.17 -1.53 -0.118 0.26209E+04 244 an30ab70 3.34 1.74 -1.61 -0.123 0.27412E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.6190000 g New total amount of reactant added: 0.6390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5871E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.6390000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .7558330E-03 Osmotic coef. = 0.9840 True ionic strength = .1040551E-02 Chg. balance for total moles = -.5871E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14242E-08 -8.8464 0.13416E-08 -8.8724 0.94197E+00 -0.0260 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12989E-03 -3.8864 0.94156E+00 -0.0262 4 SO4-- 0.25489E-04 -4.5937 0.21156E-04 -4.6746 0.83001E+00 -0.0809 5 HCO3- 0.12094E-04 -4.9174 0.11388E-04 -4.9435 0.94165E+00 -0.0261 6 HS- 0.53509E-13 -13.2716 0.50383E-13 -13.2977 0.94157E+00 -0.0261 7 Al+++ 0.20810E-23 -23.6817 0.13980E-23 -23.8545 0.67176E+00 -0.1728 8 H4SiO4 0.39884E-03 -3.3992 0.39884E-03 -3.3992 0.10000E+01 0.0000 9 Ca++ 0.15837E-06 -6.8003 0.13138E-06 -6.8815 0.82957E+00 -0.0811 10 Mg++ 0.78441E-09 -9.1055 0.65050E-09 -9.1868 0.82930E+00 -0.0813 11 Fe++ 0.46393E-11 -11.3335 0.38477E-11 -11.4148 0.82936E+00 -0.0813 12 K+ 0.55288E-04 -4.2574 0.52063E-04 -4.2835 0.94167E+00 -0.0261 13 Na+ 0.95781E-03 -3.0187 0.90182E-03 -3.0449 0.94155E+00 -0.0262 14 Mn++ 0.61980E-09 -9.2078 0.51407E-09 -9.2890 0.82941E+00 -0.0812 15 HPO4-- 0.52957E-06 -6.2761 0.43955E-06 -6.3570 0.83002E+00 -0.0809 16 HSiO3- 0.30806E-03 -3.5114 0.29005E-03 -3.5375 0.94156E+00 -0.0262 17 Ca(HSiO3)+ 0.90669E-09 -9.0425 0.85382E-09 -9.0686 0.94169E+00 -0.0261 18 Mg(HSiO3)+ 0.55869E-11 -11.2528 0.52611E-11 -11.2789 0.94169E+00 -0.0261 19 NaHSiO3,aq 0.41545E-05 -5.3815 0.41545E-05 -5.3815 0.10000E+01 0.0000 20 AlO+ 0.10648E-12 -12.9727 0.10027E-12 -12.9988 0.94169E+00 -0.0261 21 AlOH+2 0.81240E-18 -18.0902 0.67386E-18 -18.1714 0.82947E+00 -0.0812 22 HAlO2,aq 0.14956E-07 -7.8252 0.14956E-07 -7.8252 0.10000E+01 0.0000 23 AlO2- 0.26440E-04 -4.5777 0.24892E-04 -4.6039 0.94143E+00 -0.0262 24 CH4,aq 0.26619E-19 -19.5748 0.26613E-19 -19.5749 0.99977E+00 -0.0001 29 CO,aq 0.34487E-18 -18.4624 0.34487E-18 -18.4624 0.10000E+01 0.0000 30 CO2,aq 0.30812E-07 -7.5113 0.30804E-07 -7.5114 0.99977E+00 -0.0001 31 CO3-2 0.94574E-06 -6.0242 0.78485E-06 -6.1052 0.82988E+00 -0.0810 32 CaCO3,aq 0.12629E-08 -8.8986 0.12629E-08 -8.8986 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40035E-10 -10.3976 0.37700E-10 -10.4237 0.94169E+00 -0.0261 34 CaCl+ 0.28878E-10 -10.5394 0.27194E-10 -10.5655 0.94169E+00 -0.0261 35 CaCl2,aq 0.82243E-15 -15.0849 0.82243E-15 -15.0849 0.10000E+01 0.0000 36 CaOH+ 0.73329E-08 -8.1347 0.69053E-08 -8.1608 0.94169E+00 -0.0261 37 CaSO4,aq 0.86604E-09 -9.0625 0.86604E-09 -9.0625 0.10000E+01 0.0000 38 HCl,aq 0.32778E-13 -13.4844 0.32778E-13 -13.4844 0.10000E+01 0.0000 43 FeCl+ 0.82661E-15 -15.0827 0.77841E-15 -15.1088 0.94169E+00 -0.0261 46 FeO,aq 0.84535E-10 -10.0730 0.84535E-10 -10.0730 0.10000E+01 0.0000 47 FeOH+ 0.10097E-09 -9.9958 0.95081E-10 -10.0219 0.94169E+00 -0.0261 48 HFeO2- 0.71981E-09 -9.1428 0.67775E-09 -9.1689 0.94156E+00 -0.0262 49 FeO+ 0.11785E-13 -13.9287 0.11098E-13 -13.9548 0.94169E+00 -0.0261 51 FeO2- 0.12871E-08 -8.8904 0.12118E-08 -8.9166 0.94156E+00 -0.0262 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.43478E-09 -9.3617 0.43468E-09 -9.3618 0.99977E+00 -0.0001 54 KCl,aq 0.11974E-09 -9.9218 0.11974E-09 -9.9218 0.10000E+01 0.0000 55 KHSO4,aq 0.39543E-17 -17.4029 0.39543E-17 -17.4029 0.10000E+01 0.0000 56 KOH,aq 0.16918E-07 -7.7717 0.16918E-07 -7.7717 0.10000E+01 0.0000 57 KSO4- 0.18023E-07 -7.7442 0.16969E-07 -7.7703 0.94156E+00 -0.0262 58 MgCO3,aq 0.15625E-11 -11.8062 0.15625E-11 -11.8062 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20213E-12 -12.6944 0.19034E-12 -12.7205 0.94169E+00 -0.0261 60 MgCl+ 0.12980E-12 -12.8867 0.12223E-12 -12.9128 0.94169E+00 -0.0261 61 MgOH+ 0.20114E-09 -9.6965 0.18941E-09 -9.7226 0.94169E+00 -0.0261 63 MnO,aq 0.30150E-09 -9.5207 0.30150E-09 -9.5207 0.10000E+01 0.0000 64 MnOH+ 0.12532E-08 -8.9020 0.11801E-08 -8.9281 0.94169E+00 -0.0261 65 MnO2-2 0.69807E-14 -14.1561 0.57931E-14 -14.2371 0.82988E+00 -0.0810 66 HMnO2- 0.17884E-11 -11.7475 0.16839E-11 -11.7737 0.94156E+00 -0.0262 69 MnCl+ 0.42915E-12 -12.3674 0.40412E-12 -12.3935 0.94169E+00 -0.0261 70 MnSO4,aq 0.30822E-11 -11.5111 0.30822E-11 -11.5111 0.10000E+01 0.0000 71 NaCl,aq 0.38249E-07 -7.4174 0.38249E-07 -7.4174 0.10000E+01 0.0000 72 NaOH,aq 0.29537E-06 -6.5296 0.29537E-06 -6.5296 0.10000E+01 0.0000 74 OH- 0.47492E-03 -3.3234 0.44710E-03 -3.3496 0.94143E+00 -0.0262 79 HPO3-2 0.72720E-18 -18.1383 0.60349E-18 -18.2193 0.82988E+00 -0.0810 82 H3PO4,aq 0.50933E-14 -14.2930 0.50933E-14 -14.2930 0.10000E+01 0.0000 83 H2PO4- 0.10980E-07 -7.9594 0.10339E-07 -7.9855 0.94162E+00 -0.0261 84 PO4-3 0.42440E-09 -9.3722 0.28613E-09 -9.5434 0.67418E+00 -0.1712 87 H2P2O7-2 0.10080E-16 -16.9965 0.83656E-17 -17.0775 0.82988E+00 -0.0810 88 HP2O7-3 0.19033E-14 -14.7205 0.12786E-14 -14.8933 0.67179E+00 -0.1728 89 P2O7-4 0.46943E-15 -15.3284 0.23512E-15 -15.6287 0.50086E+00 -0.3003 90 H2S,aq 0.20314E-15 -15.6922 0.20309E-15 -15.6923 0.99977E+00 -0.0001 97 SO3-2 0.15093E-14 -14.8212 0.12539E-14 -14.9017 0.83076E+00 -0.0805 98 HSO3- 0.10456E-15 -15.9807 0.98445E-16 -16.0068 0.94156E+00 -0.0262 99 HSO4- 0.27964E-10 -10.5534 0.26335E-10 -10.5795 0.94175E+00 -0.0261 Charge balance for all species = -.5875E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1424246E-08 -.8941717E-03 -.9011792E+00 0.0000 2 H2O 0.1000000E+01 0.5550847E+02 0.9998994E+06 0.0000 3 Cl- 0.1379535E-03 0.1379919E-03 0.4891727E+01 4.9860 4 SO4-- 0.2548883E-04 0.2550783E-04 0.2450072E+01 13.0702 5 HCO3- 0.1209383E-04 0.1307168E-04 0.7975157E+00 3.9288 6 HS- 0.5350936E-13 -.7756929E-10 -.2565109E-05 -4.4253 7 Al+++ 0.2081044E-23 0.2645526E-04 0.7137297E+00 2.7626 8 H4SiO4 0.3988396E-03 0.7110523E-03 0.6833609E+02 -3.3992 9 Ca++ 0.1583741E-06 0.1688116E-06 0.6764939E-02 10.8633 10 Mg++ 0.7844050E-09 0.9930284E-09 0.2414004E-04 8.5580 11 Fe++ 0.4639334E-11 0.2400511E-08 0.1340476E-03 6.3300 12 K+ 0.5528787E-04 0.5532293E-04 0.2163016E+01 4.5889 13 Na+ 0.9578073E-03 0.9622953E-03 0.2212071E+02 5.8275 14 Mn++ 0.6197972E-09 0.2179765E-08 0.1197397E-03 8.4558 15 HPO4-- 0.5295694E-06 0.5409735E-06 0.5191678E-01 11.3878 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1056785E-01 -.8940568E-03 -.9673795E-02 0.0000000E+00 2 H2O 0.5550024E+02 0.5550133E+02 -.1092410E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4321334E-04 0.2550455E-04 0.1770879E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1770887E-04 -.7755932E-10 -.1770879E-04 0.0000000E+00 7 Al+++ 0.2083614E-02 0.2645186E-04 0.2057162E-02 0.0000000E+00 8 H4SiO4 0.6653768E-02 0.7109610E-03 0.5942807E-02 0.0000000E+00 9 Ca++ 0.7494122E-03 0.1687899E-06 0.7492434E-03 0.0000000E+00 10 Mg++ 0.5071429E-03 0.9929008E-09 0.5071419E-03 0.0000000E+00 11 Fe++ 0.4556125E-03 0.2400203E-08 0.4556101E-03 0.0000000E+00 12 K+ 0.1356688E-03 0.5531582E-04 0.8035297E-04 0.0000000E+00 13 Na+ 0.9621717E-03 0.9621717E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1107936E-04 0.2179485E-08 0.1107718E-04 0.0000000E+00 15 HPO4-- 0.3781331E-05 0.5409040E-06 0.3240427E-05 0.0000000E+00 Chg. balance for solid moles: -.7276E-18 Mass of aqueous solution: 0.999974E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.6390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1080E-05 -5.967 0.5426E-03 -3.266 0.8095E-01 0.1724E-03 clinochlore 0.1014E-03 -3.994 0.5638E-01 -1.249 8.412 0.2144E-01 daphnite 0.6279E-04 -4.202 0.4480E-01 -1.349 6.684 0.1358E-01 chlorite-Mn 0.2215E-05 -5.655 0.1571E-02 -2.804 0.2343 0.5005E-03 hematite 0.7084E-04 -4.150 0.1131E-01 -1.946 1.688 0.2144E-02 kaolinite -.2223E-05 1.000 -.5739E-03 1.000 -.8562E-01 -.2208E-03 muscovite 0.8035E-04 -4.095 0.3201E-01 -1.495 4.775 0.1132E-01 stilbite 0.7438E-03 -3.129 0.5242 -0.281 78.21 0.2445 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 kaolinite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.670235 g Volume = 0.293430 cm3 Porosity: 76.6303% V(tot) - V(min): 0.96217E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.6390000 g log = -0.1945 Original solution: 1000.0103000 g Original solution / Rock added: 1564.96 (Water/Rock Ratio), log = 3.1945 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3328E-05 1.0073 0.3526E-05 0.3500E-05 CH4,gas 0.3950E-16 1.0129 0.4208E-16 0.4155E-16 H2,gas 0.5664E-06 1.0006 0.5962E-06 0.5959E-06 H2S,gas 0.5654E-14 0.9959 0.5923E-14 0.5947E-14 S2,gas 0.3514E-35 1.0000 0.3697E-35 0.3697E-35 CO,gas 0.5177E-15 1.0000 0.5445E-15 0.5445E-15 SO3,gas 0.1353E-37 1.0000 0.1424E-37 0.1424E-37 SO2,gas 0.3052E-21 1.0000 0.3211E-21 0.3211E-21 HCl,gas 0.5502E-16 1.0000 0.5788E-16 0.5788E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.82 -7.45 -2.484 0.12725E+05 -5.453 3 CH4,gas 4.81 -13.57 -18.38 -4.594 0.31376E+05 -16.376 4 H2,gas 8.29 0.06 -8.22 -4.700 0.14043E+05 -6.225 5 H2S,gas -5.94 -22.17 -16.23 -8.114 0.27708E+05 -14.227 6 S2,gas -7.03 -44.46 -37.43 -5.759 0.63914E+05 -35.432 7 CO,gas 3.51 -13.75 -17.26 -5.312 0.29478E+05 -15.264 8 SO3,gas 17.43 -22.42 -39.85 -9.962 0.68037E+05 -37.847 9 SO2,gas 1.14 -22.36 -23.49 -6.265 0.40114E+05 -21.493 10 HCl,gas 5.48 -12.76 -18.24 -9.119 0.31140E+05 -16.237 11 acmite 7.74 5.33 -2.41 -0.250 0.41141E+04 15 albite-high 0.75 -1.61 -2.36 -0.181 0.40247E+04 16 albite -0.33 -1.61 -1.28 -0.098 0.21841E+04 19 spessartine 24.55 20.69 -3.85 -0.193 0.65822E+04 20 analcite 3.37 1.79 -1.58 -0.175 0.26959E+04 21 andalusite 5.06 2.13 -2.94 -0.294 0.50137E+04 22 andradite 39.09 34.99 -4.10 -0.213 0.69970E+04 23 grossular 32.83 27.92 -4.91 -0.246 0.83848E+04 26 annite 20.21 16.14 -4.07 -0.226 0.69418E+04 27 phlogopite 27.15 22.83 -4.32 -0.240 0.73740E+04 29 anorthite 12.80 9.59 -3.21 -0.247 0.54768E+04 35 aragonite 0.99 -2.95 -3.94 -1.313 0.67255E+04 36 brucite 12.58 8.56 -4.02 -0.804 0.68616E+04 37 calcite 0.83 -2.95 -3.79 -1.262 0.64641E+04 38 carnegieite-low 9.06 5.19 -3.87 -0.553 0.66141E+04 39 carnegieite-high 10.13 5.19 -4.94 -0.706 0.84410E+04 40 carpholite-Mg 8.65 7.28 -1.37 -0.091 0.23316E+04 41 carpholite-Fe 6.78 5.06 -1.73 -0.115 0.29472E+04 42 celadonite 5.40 2.31 -3.09 -0.182 0.52723E+04 43 celadonite-Fe 3.94 0.08 -3.85 -0.227 0.65776E+04 50 chloritoid-Mg 13.26 10.68 -2.58 -0.172 0.44005E+04 51 chloritoid-Fe 9.24 8.46 -0.78 -0.052 0.13364E+04 52 chloritoid-Mn 11.46 10.58 -0.88 -0.059 0.15049E+04 54 coesite -2.37 -3.40 -1.03 -0.343 0.17584E+04 59 corundum 8.43 5.53 -2.91 -0.264 0.49656E+04 61 cristobalite -2.55 -3.40 -0.85 -0.283 0.14513E+04 63 cymrite-K 1.73 -2.85 -4.58 -0.381 0.78148E+04 65 diaspore 2.90 2.76 -0.13 -0.022 0.22788E+03 67 diopside 16.22 12.62 -3.59 -0.359 0.61342E+04 68 hedenbergite 14.24 10.39 -3.85 -0.385 0.65730E+04 75 epidote 24.78 23.35 -1.42 -0.069 0.24283E+04 76 clinozoisite 22.92 19.82 -3.10 -0.141 0.53005E+04 77 epidote-Fe 29.94 26.89 -3.05 -0.158 0.52036E+04 78 fayalite 14.08 9.26 -4.82 -0.688 0.82270E+04 83 gibbsite 4.10 2.76 -1.33 -0.191 0.22791E+04 87 greenalite 16.19 12.19 -4.00 -0.334 0.68346E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.79 -2.46 -0.246 0.41990E+04 97 kalsilite 7.62 3.95 -3.67 -0.524 0.62629E+04 98 kaolinite -1.27 -1.27 0.00 0.000 0.60662E-11 99 kyanite 4.93 2.13 -2.81 -0.281 0.47905E+04 101 laumontite 2.97 2.79 -0.18 -0.012 0.31212E+03 102 lawsonite 9.68 9.59 -0.09 -0.006 0.15064E+03 103 leucite 4.17 0.55 -3.61 -0.361 0.61717E+04 105 lizardite 23.29 18.88 -4.41 -0.368 0.75330E+04 107 magnetite 20.13 18.93 -1.21 -0.098 0.20579E+04 113 margarite 17.45 15.12 -2.34 -0.093 0.39893E+04 116 microcline -2.43 -2.85 -0.41 -0.032 0.70736E+03 121 paragonite 4.34 3.92 -0.42 -0.025 0.71516E+03 122 nepheline 8.38 5.19 -3.19 -0.455 0.54420E+04 136 prehnite 19.47 17.05 -2.41 -0.142 0.41186E+04 137 prehnite-Fe 22.59 20.59 -2.00 -0.120 0.34087E+04 138 pumpellyite-Fe 46.47 43.20 -3.27 -0.073 0.55826E+04 139 pumpellyite-Mg 49.19 45.43 -3.76 -0.084 0.64285E+04 145 pyroxmangite 7.42 5.06 -2.36 -0.472 0.40287E+04 146 pyrophyllite -6.10 -8.07 -1.97 -0.123 0.33697E+04 147 quartz -2.98 -3.40 -0.42 -0.139 0.71236E+03 151 rhodochrosite -0.96 -5.36 -4.40 -1.467 0.75156E+04 152 rhodonite 7.46 5.06 -2.41 -0.481 0.41079E+04 153 sanidine -1.22 -2.85 -1.63 -0.125 0.27751E+04 155 siderite -2.59 -7.49 -4.90 -1.633 0.83637E+04 156 sillimanite 5.32 2.13 -3.20 -0.320 0.54559E+04 164 stilpnomelane-Fe 13.18 12.28 -0.90 -0.027 0.15427E+04 165 stilpnomelane-Mg 27.60 23.42 -4.18 -0.125 0.71375E+04 167 sudoite-Fe 18.44 13.51 -4.92 -0.159 0.84079E+04 168 sudoite 21.22 17.97 -3.25 -0.105 0.55446E+04 171 talc 16.55 12.08 -4.48 -0.263 0.76429E+04 174 tephroite 18.11 13.51 -4.60 -0.657 0.78553E+04 177 topaz-H 4.67 2.13 -2.54 -0.231 0.43395E+04 178 tridymite -2.61 -3.40 -0.78 -0.262 0.13397E+04 187 wairakite 4.06 2.79 -1.27 -0.075 0.21629E+04 188 walstromite 11.53 7.46 -4.06 -0.813 0.69388E+04 189 wollastonite 10.48 7.46 -3.02 -0.604 0.51527E+04 190 pseudo-wollastonite 11.02 7.46 -3.56 -0.711 0.60713E+04 191 zoisite 22.96 19.82 -3.15 -0.143 0.53730E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.69 -0.166 0.45863E+04 194 beidellite-H -2.24 -6.04 -3.80 -0.242 0.64833E+04 195 beidellite-K -1.44 -4.52 -3.09 -0.189 0.52740E+04 196 beidellite-Mg -1.71 -4.63 -2.92 -0.181 0.49844E+04 197 beidellite-Na -1.26 -4.12 -2.86 -0.175 0.48800E+04 199 chalcedony -2.79 -3.40 -0.60 -0.202 0.10327E+04 201 montmorillonite-Ca -2.21 -4.37 -2.15 -0.133 0.36755E+04 202 montmorillonite-K -2.16 -4.64 -2.48 -0.152 0.42409E+04 203 montmorillonite-Mg -2.40 -4.75 -2.35 -0.145 0.40047E+04 204 montmorillonite-Na -1.96 -4.24 -2.28 -0.139 0.38851E+04 205 nontronite-Ca 3.28 2.83 -0.45 -0.029 0.77348E+03 206 nontronite-H 2.60 1.03 -1.56 -0.105 0.26663E+04 207 nontronite-K 3.40 2.55 -0.86 -0.055 0.14603E+04 208 nontronite-Mg 3.14 2.45 -0.69 -0.045 0.11832E+04 209 nontronite-Na 3.58 2.96 -0.63 -0.040 0.10681E+04 224 tobermorite 9.84 5.65 -4.19 -1.143 0.71527E+04 233 boehmite 4.43 2.76 -1.67 -0.278 0.28463E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.874 0.59664E+04 240 silica-amorphous -2.08 -3.40 -1.32 -0.440 0.22529E+04 242 an20ab80 2.08 0.63 -1.45 -0.111 0.24710E+04 243 an25ab75 2.71 1.19 -1.52 -0.117 0.25906E+04 244 an30ab70 3.34 1.75 -1.59 -0.122 0.27186E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.6390000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .7558319E-03 Osmotic coef. = 0.9840 True ionic strength = .1041947E-02 Chg. balance for total moles = -.5871E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14208E-08 -8.8475 0.13384E-08 -8.8734 0.94195E+00 -0.0260 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12989E-03 -3.8864 0.94153E+00 -0.0262 4 SO4-- 0.25488E-04 -4.5937 0.21153E-04 -4.6746 0.82992E+00 -0.0810 5 HCO3- 0.12092E-04 -4.9175 0.11386E-04 -4.9436 0.94163E+00 -0.0261 6 HS- 0.55059E-13 -13.2592 0.51840E-13 -13.2853 0.94154E+00 -0.0262 7 Al+++ 0.20498E-23 -23.6883 0.13766E-23 -23.8612 0.67160E+00 -0.1729 8 H4SiO4 0.39842E-03 -3.3997 0.39842E-03 -3.3997 0.10000E+01 0.0000 9 Ca++ 0.16139E-06 -6.7921 0.13387E-06 -6.8733 0.82948E+00 -0.0812 10 Mg++ 0.78374E-09 -9.1058 0.64988E-09 -9.1872 0.82921E+00 -0.0813 11 Fe++ 0.46354E-11 -11.3339 0.38440E-11 -11.4152 0.82927E+00 -0.0813 12 K+ 0.56697E-04 -4.2464 0.53388E-04 -4.2726 0.94165E+00 -0.0261 13 Na+ 0.95780E-03 -3.0187 0.90179E-03 -3.0449 0.94152E+00 -0.0262 14 Mn++ 0.61927E-09 -9.2081 0.51358E-09 -9.2894 0.82932E+00 -0.0813 15 HPO4-- 0.51166E-06 -6.2910 0.42464E-06 -6.3720 0.82993E+00 -0.0810 16 HSiO3- 0.30849E-03 -3.5108 0.29045E-03 -3.5369 0.94153E+00 -0.0262 17 Ca(HSiO3)+ 0.92516E-09 -9.0338 0.87119E-09 -9.0599 0.94166E+00 -0.0261 18 Mg(HSiO3)+ 0.55894E-11 -11.2526 0.52633E-11 -11.2787 0.94166E+00 -0.0261 19 NaHSiO3,aq 0.41600E-05 -5.3809 0.41600E-05 -5.3809 0.10000E+01 0.0000 20 AlO+ 0.10536E-12 -12.9773 0.99216E-13 -13.0034 0.94166E+00 -0.0261 21 AlOH+2 0.80202E-18 -18.0958 0.66518E-18 -18.1771 0.82938E+00 -0.0812 22 HAlO2,aq 0.14835E-07 -7.8287 0.14835E-07 -7.8287 0.10000E+01 0.0000 23 AlO2- 0.26290E-04 -4.5802 0.24750E-04 -4.6064 0.94141E+00 -0.0262 24 CH4,aq 0.27387E-19 -19.5625 0.27380E-19 -19.5626 0.99977E+00 -0.0001 29 CO,aq 0.34664E-18 -18.4601 0.34664E-18 -18.4601 0.10000E+01 0.0000 30 CO2,aq 0.30731E-07 -7.5124 0.30724E-07 -7.5125 0.99977E+00 -0.0001 31 CO3-2 0.94793E-06 -6.0232 0.78659E-06 -6.1043 0.82979E+00 -0.0810 32 CaCO3,aq 0.12897E-08 -8.8895 0.12897E-08 -8.8895 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40786E-10 -10.3895 0.38407E-10 -10.4156 0.94166E+00 -0.0261 34 CaCl+ 0.29425E-10 -10.5313 0.27708E-10 -10.5574 0.94166E+00 -0.0261 35 CaCl2,aq 0.83796E-15 -15.0768 0.83796E-15 -15.0768 0.10000E+01 0.0000 36 CaOH+ 0.74901E-08 -8.1255 0.70532E-08 -8.1516 0.94166E+00 -0.0261 37 CaSO4,aq 0.88233E-09 -9.0544 0.88233E-09 -9.0544 0.10000E+01 0.0000 38 HCl,aq 0.32698E-13 -13.4855 0.32698E-13 -13.4855 0.10000E+01 0.0000 43 FeCl+ 0.82583E-15 -15.0831 0.77765E-15 -15.1092 0.94166E+00 -0.0261 46 FeO,aq 0.84864E-10 -10.0713 0.84864E-10 -10.0713 0.10000E+01 0.0000 47 FeOH+ 0.10112E-09 -9.9952 0.95220E-10 -10.0213 0.94166E+00 -0.0261 48 HFeO2- 0.72438E-09 -9.1400 0.68203E-09 -9.1662 0.94153E+00 -0.0262 49 FeO+ 0.11757E-13 -13.9297 0.11071E-13 -13.9558 0.94166E+00 -0.0261 51 FeO2- 0.12902E-08 -8.8893 0.12148E-08 -8.9155 0.94153E+00 -0.0262 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.43817E-09 -9.3584 0.43807E-09 -9.3585 0.99977E+00 -0.0001 54 KCl,aq 0.12278E-09 -9.9109 0.12278E-09 -9.9109 0.10000E+01 0.0000 55 KHSO4,aq 0.40446E-17 -17.3931 0.40446E-17 -17.3931 0.10000E+01 0.0000 56 KOH,aq 0.17390E-07 -7.7597 0.17390E-07 -7.7597 0.10000E+01 0.0000 57 KSO4- 0.18479E-07 -7.7333 0.17399E-07 -7.7595 0.94153E+00 -0.0262 58 MgCO3,aq 0.15645E-11 -11.8056 0.15645E-11 -11.8056 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20190E-12 -12.6949 0.19012E-12 -12.7210 0.94166E+00 -0.0261 60 MgCl+ 0.12968E-12 -12.8871 0.12211E-12 -12.9132 0.94166E+00 -0.0261 61 MgOH+ 0.20144E-09 -9.6958 0.18969E-09 -9.7220 0.94166E+00 -0.0261 63 MnO,aq 0.30267E-09 -9.5190 0.30267E-09 -9.5190 0.10000E+01 0.0000 64 MnOH+ 0.12550E-08 -8.9013 0.11818E-08 -8.9275 0.94166E+00 -0.0261 65 MnO2-2 0.70426E-14 -14.1523 0.58439E-14 -14.2333 0.82979E+00 -0.0810 66 HMnO2- 0.17998E-11 -11.7448 0.16946E-11 -11.7709 0.94153E+00 -0.0262 69 MnCl+ 0.42874E-12 -12.3678 0.40373E-12 -12.3939 0.94166E+00 -0.0261 70 MnSO4,aq 0.30788E-11 -11.5116 0.30788E-11 -11.5116 0.10000E+01 0.0000 71 NaCl,aq 0.38246E-07 -7.4174 0.38246E-07 -7.4174 0.10000E+01 0.0000 72 NaOH,aq 0.29607E-06 -6.5286 0.29607E-06 -6.5286 0.10000E+01 0.0000 74 OH- 0.47608E-03 -3.3223 0.44819E-03 -3.3485 0.94141E+00 -0.0262 79 HPO3-2 0.70809E-18 -18.1499 0.58756E-18 -18.2309 0.82979E+00 -0.0810 82 H3PO4,aq 0.48969E-14 -14.3101 0.48969E-14 -14.3101 0.10000E+01 0.0000 83 H2PO4- 0.10582E-07 -7.9754 0.99639E-08 -8.0016 0.94159E+00 -0.0261 84 PO4-3 0.41110E-09 -9.3861 0.27709E-09 -9.5574 0.67402E+00 -0.1713 87 H2P2O7-2 0.93639E-17 -17.0285 0.77701E-17 -17.1096 0.82979E+00 -0.0810 88 HP2O7-3 0.17725E-14 -14.7514 0.11905E-14 -14.9243 0.67162E+00 -0.1729 89 P2O7-4 0.43832E-15 -15.3582 0.21944E-15 -15.6587 0.50064E+00 -0.3005 90 H2S,aq 0.20851E-15 -15.6809 0.20846E-15 -15.6810 0.99977E+00 -0.0001 97 SO3-2 0.15211E-14 -14.8179 0.12635E-14 -14.8984 0.83067E+00 -0.0806 98 HSO3- 0.10511E-15 -15.9784 0.98961E-16 -16.0045 0.94153E+00 -0.0262 99 HSO4- 0.27894E-10 -10.5545 0.26268E-10 -10.5806 0.94173E+00 -0.0261 Charge balance for all species = -.5872E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1420845E-08 -.8951740E-03 -.9021893E+00 0.0000 2 H2O 0.1000000E+01 0.5550847E+02 0.9998993E+06 0.0000 3 Cl- 0.1379535E-03 0.1379919E-03 0.4891727E+01 4.9870 4 SO4-- 0.2548836E-04 0.2550783E-04 0.2450072E+01 13.0722 5 HCO3- 0.1209168E-04 0.1307168E-04 0.7975157E+00 3.9298 6 HS- 0.5505883E-13 -.7711414E-10 -.2550058E-05 -4.4119 7 Al+++ 0.2049764E-23 0.2630510E-04 0.7096784E+00 2.7591 8 H4SiO4 0.3984221E-03 0.7110710E-03 0.6833788E+02 -3.3997 9 Ca++ 0.1613921E-06 0.1720497E-06 0.6894701E-02 10.8735 10 Mg++ 0.7837437E-09 0.9926716E-09 0.2413136E-04 8.5597 11 Fe++ 0.4635422E-11 0.2408706E-08 0.1345052E-03 6.3316 12 K+ 0.5669651E-04 0.5673250E-04 0.2218127E+01 4.6009 13 Na+ 0.9578011E-03 0.9622954E-03 0.2212071E+02 5.8285 14 Mn++ 0.6192744E-09 0.2182294E-08 0.1198786E-03 8.4575 15 HPO4-- 0.5116634E-06 0.5226565E-06 0.5015891E-01 11.3749 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1056785E-01 -.8950589E-03 -.9672792E-02 0.0000000E+00 2 H2O 0.5550024E+02 0.5550133E+02 -.1090080E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4321334E-04 0.2550455E-04 0.1770879E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1770887E-04 -.7710422E-10 -.1770879E-04 0.0000000E+00 7 Al+++ 0.2083614E-02 0.2630172E-04 0.2057312E-02 0.0000000E+00 8 H4SiO4 0.6653768E-02 0.7109796E-03 0.5942789E-02 0.0000000E+00 9 Ca++ 0.7494122E-03 0.1720276E-06 0.7492402E-03 0.0000000E+00 10 Mg++ 0.5071429E-03 0.9925440E-09 0.5071419E-03 0.0000000E+00 11 Fe++ 0.4556125E-03 0.2408396E-08 0.4556101E-03 0.0000000E+00 12 K+ 0.1356688E-03 0.5672521E-04 0.7894358E-04 0.0000000E+00 13 Na+ 0.9621717E-03 0.9621717E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1107936E-04 0.2182013E-08 0.1107718E-04 0.0000000E+00 15 HPO4-- 0.3781331E-05 0.5225893E-06 0.3258742E-05 0.0000000E+00 Chg. balance for solid moles: -.1183E-17 Mass of aqueous solution: 0.999974E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.6390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1086E-05 -5.964 0.5456E-03 -3.263 0.8141E-01 0.1734E-03 clinochlore 0.1014E-03 -3.994 0.5638E-01 -1.249 8.412 0.2144E-01 daphnite 0.6279E-04 -4.202 0.4480E-01 -1.349 6.684 0.1358E-01 chlorite-Mn 0.2215E-05 -5.655 0.1571E-02 -2.804 0.2344 0.5005E-03 hematite 0.7084E-04 -4.150 0.1131E-01 -1.946 1.688 0.2144E-02 muscovite 0.7894E-04 -4.103 0.3144E-01 -1.502 4.692 0.1112E-01 stilbite 0.7438E-03 -3.129 0.5242 -0.281 78.21 0.2445 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.670227 g Volume = 0.293442 cm3 Porosity: 76.6293% V(tot) - V(min): 0.96216E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.6390000 g log = -0.1945 Original solution: 1000.0103000 g Original solution / Rock added: 1564.96 (Water/Rock Ratio), log = 3.1945 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3319E-05 1.0073 0.3517E-05 0.3491E-05 CH4,gas 0.4064E-16 1.0129 0.4330E-16 0.4275E-16 H2,gas 0.5709E-06 1.0006 0.6008E-06 0.6005E-06 H2S,gas 0.5803E-14 0.9959 0.6080E-14 0.6105E-14 S2,gas 0.3646E-35 1.0000 0.3835E-35 0.3835E-35 CO,gas 0.5203E-15 1.0000 0.5474E-15 0.5474E-15 SO3,gas 0.1347E-37 1.0000 0.1417E-37 0.1417E-37 SO2,gas 0.3061E-21 1.0000 0.3220E-21 0.3220E-21 HCl,gas 0.5488E-16 1.0000 0.5774E-16 0.5774E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 120 muscovite 2.68 2.68 0.00 0.000 0.30331E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.82 -7.45 -2.485 0.12727E+05 -5.454 3 CH4,gas 4.81 -13.55 -18.36 -4.591 0.31355E+05 -16.364 4 H2,gas 8.29 0.07 -8.22 -4.698 0.14038E+05 -6.221 5 H2S,gas -5.94 -22.16 -16.22 -8.108 0.27689E+05 -14.216 6 S2,gas -7.03 -44.45 -37.42 -5.756 0.63887E+05 -35.416 7 CO,gas 3.51 -13.75 -17.26 -5.311 0.29474E+05 -15.262 8 SO3,gas 17.43 -22.42 -39.85 -9.962 0.68041E+05 -37.849 9 SO2,gas 1.14 -22.36 -23.49 -6.265 0.40112E+05 -21.492 10 HCl,gas 5.48 -12.76 -18.24 -9.119 0.31142E+05 -16.239 11 acmite 7.74 5.33 -2.41 -0.250 0.41139E+04 15 albite-high 0.75 -1.61 -2.36 -0.182 0.40313E+04 16 albite -0.33 -1.61 -1.28 -0.099 0.21907E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65879E+04 20 analcite 3.37 1.79 -1.58 -0.176 0.27018E+04 21 andalusite 5.06 2.12 -2.94 -0.294 0.50265E+04 22 andradite 39.09 35.02 -4.07 -0.211 0.69468E+04 23 grossular 32.83 27.94 -4.89 -0.244 0.83467E+04 26 annite 20.21 16.16 -4.05 -0.225 0.69211E+04 27 phlogopite 27.15 22.84 -4.31 -0.239 0.73533E+04 29 anorthite 12.80 9.59 -3.21 -0.247 0.54729E+04 35 aragonite 0.99 -2.94 -3.93 -1.310 0.67099E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68588E+04 37 calcite 0.83 -2.94 -3.78 -1.259 0.64486E+04 38 carnegieite-low 9.06 5.19 -3.88 -0.554 0.66192E+04 39 carnegieite-high 10.13 5.19 -4.95 -0.707 0.84460E+04 40 carpholite-Mg 8.65 7.28 -1.37 -0.091 0.23423E+04 41 carpholite-Fe 6.78 5.05 -1.73 -0.115 0.29580E+04 42 celadonite 5.40 2.32 -3.08 -0.181 0.52581E+04 43 celadonite-Fe 3.94 0.09 -3.84 -0.226 0.65634E+04 50 chloritoid-Mg 13.26 10.68 -2.58 -0.172 0.44104E+04 51 chloritoid-Fe 9.24 8.45 -0.79 -0.053 0.13463E+04 52 chloritoid-Mn 11.46 10.58 -0.89 -0.059 0.15149E+04 54 coesite -2.37 -3.40 -1.03 -0.343 0.17592E+04 59 corundum 8.43 5.52 -2.92 -0.265 0.49777E+04 61 cristobalite -2.55 -3.40 -0.85 -0.283 0.14521E+04 63 cymrite-K 1.73 -2.84 -4.57 -0.381 0.78028E+04 65 diaspore 2.90 2.76 -0.14 -0.023 0.23391E+03 67 diopside 16.22 12.63 -3.58 -0.358 0.61154E+04 68 hedenbergite 14.24 10.41 -3.84 -0.384 0.65542E+04 75 epidote 24.78 23.37 -1.41 -0.068 0.24077E+04 76 clinozoisite 22.92 19.83 -3.10 -0.141 0.52859E+04 77 epidote-Fe 29.94 26.90 -3.03 -0.158 0.51770E+04 78 fayalite 14.08 9.26 -4.82 -0.688 0.82220E+04 83 gibbsite 4.10 2.76 -1.34 -0.191 0.22851E+04 87 greenalite 16.19 12.20 -4.00 -0.333 0.68275E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.79 -2.46 -0.246 0.42048E+04 97 kalsilite 7.62 3.96 -3.66 -0.523 0.62493E+04 98 kaolinite -1.27 -1.28 -0.01 -0.001 0.13619E+02 99 kyanite 4.93 2.12 -2.81 -0.281 0.48033E+04 101 laumontite 2.97 2.79 -0.18 -0.012 0.30979E+03 102 lawsonite 9.68 9.59 -0.09 -0.006 0.14675E+03 103 leucite 4.17 0.56 -3.61 -0.361 0.61588E+04 105 lizardite 23.29 18.88 -4.41 -0.367 0.75260E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20550E+04 113 margarite 17.45 15.11 -2.34 -0.094 0.39975E+04 116 microcline -2.43 -2.84 -0.41 -0.031 0.69529E+03 121 paragonite 4.34 3.91 -0.43 -0.025 0.73382E+03 122 nepheline 8.38 5.19 -3.19 -0.456 0.54471E+04 136 prehnite 19.47 17.07 -2.40 -0.141 0.40980E+04 137 prehnite-Fe 22.59 20.61 -1.98 -0.119 0.33821E+04 138 pumpellyite-Fe 46.47 43.22 -3.25 -0.072 0.55445E+04 139 pumpellyite-Mg 49.19 45.45 -3.74 -0.083 0.63904E+04 145 pyroxmangite 7.42 5.06 -2.36 -0.472 0.40266E+04 146 pyrophyllite -6.10 -8.08 -1.98 -0.124 0.33849E+04 147 quartz -2.98 -3.40 -0.42 -0.139 0.71314E+03 151 rhodochrosite -0.96 -5.36 -4.40 -1.467 0.75147E+04 152 rhodonite 7.46 5.06 -2.40 -0.481 0.41058E+04 153 sanidine -1.22 -2.84 -1.62 -0.124 0.27630E+04 155 siderite -2.59 -7.49 -4.90 -1.633 0.83628E+04 156 sillimanite 5.32 2.12 -3.20 -0.320 0.54687E+04 164 stilpnomelane-Fe 13.18 12.28 -0.90 -0.027 0.15363E+04 165 stilpnomelane-Mg 27.60 23.42 -4.18 -0.125 0.71311E+04 167 sudoite-Fe 18.44 13.50 -4.94 -0.159 0.84286E+04 168 sudoite 21.22 17.96 -3.26 -0.105 0.55653E+04 171 talc 16.55 12.08 -4.47 -0.263 0.76374E+04 174 tephroite 18.11 13.52 -4.60 -0.657 0.78503E+04 177 topaz-H 4.67 2.12 -2.55 -0.232 0.43524E+04 178 tridymite -2.61 -3.40 -0.79 -0.262 0.13404E+04 187 wairakite 4.06 2.79 -1.27 -0.074 0.21606E+04 188 walstromite 11.53 7.47 -4.05 -0.811 0.69221E+04 189 wollastonite 10.48 7.47 -3.01 -0.602 0.51360E+04 190 pseudo-wollastonite 11.02 7.47 -3.55 -0.709 0.60546E+04 191 zoisite 22.96 19.83 -3.14 -0.143 0.53584E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.25 -2.69 -0.167 0.46003E+04 194 beidellite-H -2.24 -6.05 -3.81 -0.243 0.65002E+04 195 beidellite-K -1.44 -4.53 -3.09 -0.190 0.52842E+04 196 beidellite-Mg -1.71 -4.64 -2.93 -0.181 0.50008E+04 197 beidellite-Na -1.26 -4.12 -2.87 -0.176 0.48964E+04 199 chalcedony -2.79 -3.40 -0.61 -0.202 0.10335E+04 201 montmorillonite-Ca -2.21 -4.37 -2.16 -0.134 0.36848E+04 202 montmorillonite-K -2.16 -4.65 -2.49 -0.152 0.42464E+04 203 montmorillonite-Mg -2.40 -4.75 -2.35 -0.146 0.40164E+04 204 montmorillonite-Na -1.96 -4.24 -2.28 -0.140 0.38968E+04 205 nontronite-Ca 3.28 2.83 -0.45 -0.029 0.77543E+03 206 nontronite-H 2.60 1.03 -1.56 -0.105 0.26711E+04 207 nontronite-K 3.40 2.55 -0.85 -0.055 0.14584E+04 208 nontronite-Mg 3.14 2.44 -0.70 -0.045 0.11876E+04 209 nontronite-Na 3.58 2.95 -0.63 -0.040 0.10723E+04 224 tobermorite 9.84 5.66 -4.18 -1.141 0.71389E+04 233 boehmite 4.43 2.76 -1.67 -0.278 0.28523E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59635E+04 240 silica-amorphous -2.08 -3.40 -1.32 -0.440 0.22537E+04 242 an20ab80 2.08 0.63 -1.45 -0.112 0.24755E+04 243 an25ab75 2.71 1.19 -1.52 -0.117 0.25946E+04 244 an30ab70 3.34 1.75 -1.59 -0.123 0.27221E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.6390000 g New total amount of reactant added: 0.6590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5870E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.6590000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9999E+00 Activity = 1.0000 Stoichiometric ionic strength = .7679006E-03 Osmotic coef. = 0.9838 True ionic strength = .1068017E-02 Chg. balance for total moles = -.5870E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13877E-08 -8.8577 0.13065E-08 -8.8839 0.94148E+00 -0.0262 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12982E-03 -3.8867 0.94106E+00 -0.0264 4 SO4-- 0.25488E-04 -4.5937 0.21111E-04 -4.6755 0.82827E+00 -0.0818 5 HCO3- 0.12070E-04 -4.9183 0.11360E-04 -4.9446 0.94116E+00 -0.0263 6 HS- 0.54492E-13 -13.2637 0.51280E-13 -13.2900 0.94107E+00 -0.0264 7 Al+++ 0.18491E-23 -23.7330 0.12363E-23 -23.9079 0.66858E+00 -0.1748 8 H4SiO4 0.40659E-03 -3.3908 0.40659E-03 -3.3908 0.10000E+01 0.0000 9 Ca++ 0.14345E-06 -6.8433 0.11875E-06 -6.9254 0.82782E+00 -0.0821 10 Mg++ 0.74978E-09 -9.1251 0.62047E-09 -9.2073 0.82754E+00 -0.0822 11 Fe++ 0.44346E-11 -11.3531 0.36701E-11 -11.4353 0.82760E+00 -0.0822 12 K+ 0.57907E-04 -4.2373 0.54501E-04 -4.2636 0.94118E+00 -0.0263 13 Na+ 0.98260E-03 -3.0076 0.92467E-03 -3.0340 0.94105E+00 -0.0264 14 Mn++ 0.59245E-09 -9.2274 0.49034E-09 -9.3095 0.82766E+00 -0.0822 15 HPO4-- 0.60623E-06 -6.2174 0.50213E-06 -6.2992 0.82828E+00 -0.0818 16 HSiO3- 0.32266E-03 -3.4913 0.30364E-03 -3.5176 0.94106E+00 -0.0264 17 Ca(HSiO3)+ 0.85835E-09 -9.0663 0.80787E-09 -9.0927 0.94119E+00 -0.0263 18 Mg(HSiO3)+ 0.55815E-11 -11.2532 0.52533E-11 -11.2796 0.94119E+00 -0.0263 19 NaHSiO3,aq 0.44592E-05 -5.3507 0.44592E-05 -5.3507 0.10000E+01 0.0000 20 AlO+ 0.99345E-13 -13.0029 0.93502E-13 -13.0292 0.94119E+00 -0.0263 21 AlOH+2 0.73931E-18 -18.1312 0.61194E-18 -18.2133 0.82772E+00 -0.0821 22 HAlO2,aq 0.14322E-07 -7.8440 0.14322E-07 -7.8440 0.10000E+01 0.0000 23 AlO2- 0.26013E-04 -4.5848 0.24477E-04 -4.6112 0.94093E+00 -0.0264 24 CH4,aq 0.27083E-19 -19.5673 0.27076E-19 -19.5674 0.99976E+00 -0.0001 29 CO,aq 0.33890E-18 -18.4699 0.33890E-18 -18.4699 0.10000E+01 0.0000 30 CO2,aq 0.29930E-07 -7.5239 0.29923E-07 -7.5240 0.99976E+00 -0.0001 31 CO3-2 0.97076E-06 -6.0129 0.80392E-06 -6.0948 0.82813E+00 -0.0819 32 CaCO3,aq 0.11692E-08 -8.9321 0.11692E-08 -8.9321 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.36114E-10 -10.4423 0.33990E-10 -10.4686 0.94119E+00 -0.0263 34 CaCl+ 0.26101E-10 -10.5833 0.24566E-10 -10.6097 0.94119E+00 -0.0263 35 CaCl2,aq 0.74256E-15 -15.1293 0.74256E-15 -15.1293 0.10000E+01 0.0000 36 CaOH+ 0.68097E-08 -8.1669 0.64092E-08 -8.1932 0.94119E+00 -0.0263 37 CaSO4,aq 0.78111E-09 -9.1073 0.78111E-09 -9.1073 0.10000E+01 0.0000 38 HCl,aq 0.31903E-13 -13.4962 0.31903E-13 -13.4962 0.10000E+01 0.0000 43 FeCl+ 0.78845E-15 -15.1032 0.74208E-15 -15.1295 0.94119E+00 -0.0263 46 FeO,aq 0.85026E-10 -10.0704 0.85026E-10 -10.0704 0.10000E+01 0.0000 47 FeOH+ 0.98949E-10 -10.0046 0.93129E-10 -10.0309 0.94119E+00 -0.0263 48 HFeO2- 0.74385E-09 -9.1285 0.70000E-09 -9.1549 0.94106E+00 -0.0264 49 FeO+ 0.11483E-13 -13.9400 0.10807E-13 -13.9663 0.94119E+00 -0.0263 51 FeO2- 0.13224E-08 -8.8786 0.12444E-08 -8.9050 0.94106E+00 -0.0264 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.43985E-09 -9.3567 0.43974E-09 -9.3568 0.99976E+00 -0.0001 54 KCl,aq 0.12528E-09 -9.9021 0.12528E-09 -9.9021 0.10000E+01 0.0000 55 KHSO4,aq 0.40225E-17 -17.3955 0.40225E-17 -17.3955 0.10000E+01 0.0000 56 KOH,aq 0.18186E-07 -7.7403 0.18186E-07 -7.7403 0.10000E+01 0.0000 57 KSO4- 0.18836E-07 -7.7250 0.17726E-07 -7.7514 0.94106E+00 -0.0264 58 MgCO3,aq 0.15266E-11 -11.8163 0.15266E-11 -11.8163 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19242E-12 -12.7158 0.18110E-12 -12.7421 0.94119E+00 -0.0263 60 MgCl+ 0.12381E-12 -12.9073 0.11653E-12 -12.9336 0.94119E+00 -0.0263 61 MgOH+ 0.19712E-09 -9.7053 0.18553E-09 -9.7316 0.94119E+00 -0.0263 63 MnO,aq 0.30326E-09 -9.5182 0.30326E-09 -9.5182 0.10000E+01 0.0000 64 MnOH+ 0.12281E-08 -8.9108 0.11559E-08 -8.9371 0.94119E+00 -0.0263 65 MnO2-2 0.74195E-14 -14.1296 0.61443E-14 -14.2115 0.82813E+00 -0.0819 66 HMnO2- 0.18482E-11 -11.7333 0.17392E-11 -11.7596 0.94106E+00 -0.0264 69 MnCl+ 0.40934E-12 -12.3879 0.38527E-12 -12.4142 0.94119E+00 -0.0263 70 MnSO4,aq 0.29337E-11 -11.5326 0.29337E-11 -11.5326 0.10000E+01 0.0000 71 NaCl,aq 0.39197E-07 -7.4067 0.39197E-07 -7.4067 0.10000E+01 0.0000 72 NaOH,aq 0.31099E-06 -6.5072 0.31099E-06 -6.5072 0.10000E+01 0.0000 74 OH- 0.48795E-03 -3.3116 0.45912E-03 -3.3381 0.94093E+00 -0.0264 79 HPO3-2 0.84217E-18 -18.0746 0.69743E-18 -18.1565 0.82813E+00 -0.0819 82 H3PO4,aq 0.55178E-14 -14.2582 0.55178E-14 -14.2582 0.10000E+01 0.0000 83 H2PO4- 0.12221E-07 -7.9129 0.11501E-07 -7.9392 0.94112E+00 -0.0264 84 PO4-3 0.50018E-09 -9.3009 0.33565E-09 -9.4741 0.67105E+00 -0.1732 87 H2P2O7-2 0.12502E-16 -16.9030 0.10353E-16 -16.9849 0.82813E+00 -0.0819 88 HP2O7-3 0.24303E-14 -14.6143 0.16249E-14 -14.7892 0.66860E+00 -0.1748 89 P2O7-4 0.61777E-15 -15.2092 0.30683E-15 -15.5131 0.49667E+00 -0.3039 90 H2S,aq 0.20134E-15 -15.6961 0.20130E-15 -15.6962 0.99976E+00 -0.0001 97 SO3-2 0.15268E-14 -14.8162 0.12658E-14 -14.8976 0.82904E+00 -0.0814 98 HSO3- 0.10284E-15 -15.9878 0.96779E-16 -16.0142 0.94106E+00 -0.0264 99 HSO4- 0.27189E-10 -10.5656 0.25591E-10 -10.5919 0.94126E+00 -0.0263 Charge balance for all species = -.5876E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1387685E-08 -.9204343E-03 -.9276451E+00 0.0000 2 H2O 0.1000000E+01 0.5550846E+02 0.9998965E+06 0.0000 3 Cl- 0.1379531E-03 0.1379925E-03 0.4891732E+01 4.9972 4 SO4-- 0.2548820E-04 0.2550793E-04 0.2450075E+01 13.0923 5 HCO3- 0.1206983E-04 0.1307173E-04 0.7975166E+00 3.9393 6 HS- 0.5449186E-13 -.8071453E-10 -.2669111E-05 -4.4062 7 Al+++ 0.1849103E-23 0.2602767E-04 0.7021918E+00 2.7438 8 H4SiO4 0.4065895E-03 0.7337060E-03 0.7051303E+02 -3.3908 9 Ca++ 0.1434507E-06 0.1531313E-06 0.6136551E-02 10.8424 10 Mg++ 0.7497837E-09 0.9543260E-09 0.2319914E-04 8.5605 11 Fe++ 0.4434558E-11 0.2458114E-08 0.1372639E-03 6.3325 12 K+ 0.5790735E-04 0.5794450E-04 0.2265508E+01 4.6203 13 Na+ 0.9825979E-03 0.9874073E-03 0.2269791E+02 5.8499 14 Mn++ 0.5924452E-09 0.2129000E-08 0.1169507E-03 8.4583 15 HPO4-- 0.6062349E-06 0.6189561E-06 0.5940054E-01 11.4686 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1089902E-01 -.9203124E-03 -.9978709E-02 0.0000000E+00 2 H2O 0.5549999E+02 0.5550111E+02 -.1123338E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4376761E-04 0.2550455E-04 0.1826306E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1826314E-04 -.8070384E-10 -.1826306E-04 0.0000000E+00 7 Al+++ 0.2148829E-02 0.2602422E-04 0.2122804E-02 0.0000000E+00 8 H4SiO4 0.6862024E-02 0.7336088E-03 0.6128415E-02 0.0000000E+00 9 Ca++ 0.7724151E-03 0.1531110E-06 0.7722620E-03 0.0000000E+00 10 Mg++ 0.5230159E-03 0.9541996E-09 0.5230149E-03 0.0000000E+00 11 Fe++ 0.4698727E-03 0.2457788E-08 0.4698702E-03 0.0000000E+00 12 K+ 0.1399151E-03 0.5793683E-04 0.8197825E-04 0.0000000E+00 13 Na+ 0.9872766E-03 0.9872766E-03 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1142613E-04 0.2128718E-08 0.1142401E-04 0.0000000E+00 15 HPO4-- 0.3899683E-05 0.6188741E-06 0.3280809E-05 0.0000000E+00 Chg. balance for solid moles: 0.3676E-18 Mass of aqueous solution: 0.999973E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.6590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1094E-05 -5.961 0.5493E-03 -3.260 0.7948E-01 0.1746E-03 clinochlore 0.1046E-03 -3.980 0.5814E-01 -1.236 8.412 0.2212E-01 daphnite 0.6475E-04 -4.189 0.4620E-01 -1.335 6.684 0.1400E-01 chlorite-Mn 0.2285E-05 -5.641 0.1620E-02 -2.791 0.2344 0.5162E-03 hematite 0.7305E-04 -4.136 0.1167E-01 -1.933 1.688 0.2211E-02 muscovite 0.8198E-04 -4.086 0.3265E-01 -1.486 4.724 0.1155E-01 stilbite 0.7668E-03 -3.115 0.5404 -0.267 78.18 0.2520 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.691207 g Volume = 0.302605 cm3 Porosity: 76.0522% V(tot) - V(min): 0.96100E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.6590000 g log = -0.1811 Original solution: 1000.0103000 g Original solution / Rock added: 1517.47 (Water/Rock Ratio), log = 3.1811 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3232E-05 1.0073 0.3425E-05 0.3400E-05 CH4,gas 0.4018E-16 1.0129 0.4282E-16 0.4227E-16 H2,gas 0.5730E-06 1.0006 0.6031E-06 0.6028E-06 H2S,gas 0.5604E-14 0.9959 0.5871E-14 0.5895E-14 S2,gas 0.3374E-35 1.0000 0.3549E-35 0.3549E-35 CO,gas 0.5087E-15 1.0000 0.5351E-15 0.5351E-15 SO3,gas 0.1281E-37 1.0000 0.1347E-37 0.1347E-37 SO2,gas 0.2922E-21 1.0000 0.3074E-21 0.3074E-21 HCl,gas 0.5355E-16 1.0000 0.5633E-16 0.5633E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.83 -7.47 -2.488 0.12747E+05 -5.465 3 CH4,gas 4.81 -13.56 -18.37 -4.592 0.31364E+05 -16.368 4 H2,gas 8.29 0.07 -8.22 -4.697 0.14035E+05 -6.220 5 H2S,gas -5.94 -22.17 -16.23 -8.116 0.27714E+05 -14.231 6 S2,gas -7.03 -44.48 -37.45 -5.762 0.63945E+05 -35.450 7 CO,gas 3.51 -13.76 -17.27 -5.314 0.29491E+05 -15.272 8 SO3,gas 17.43 -22.44 -39.87 -9.968 0.68078E+05 -37.871 9 SO2,gas 1.14 -22.38 -23.51 -6.270 0.40147E+05 -21.512 10 HCl,gas 5.48 -12.77 -18.25 -9.125 0.31160E+05 -16.249 11 acmite 7.74 5.37 -2.37 -0.246 0.40474E+04 15 albite-high 0.75 -1.58 -2.33 -0.179 0.39758E+04 16 albite -0.33 -1.58 -1.25 -0.096 0.21352E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65907E+04 20 analcite 3.37 1.81 -1.56 -0.173 0.26613E+04 21 andalusite 5.06 2.10 -2.97 -0.297 0.50637E+04 22 andradite 39.09 34.95 -4.14 -0.215 0.70610E+04 23 grossular 32.83 27.84 -4.99 -0.249 0.85131E+04 26 annite 20.21 16.19 -4.02 -0.223 0.68646E+04 27 phlogopite 27.15 22.87 -4.27 -0.237 0.72968E+04 29 anorthite 12.80 9.55 -3.25 -0.250 0.55481E+04 35 aragonite 0.99 -2.99 -3.97 -1.324 0.67826E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68573E+04 37 calcite 0.83 -2.99 -3.82 -1.273 0.65213E+04 38 carnegieite-low 9.06 5.20 -3.86 -0.552 0.65938E+04 39 carnegieite-high 10.13 5.20 -4.93 -0.705 0.84206E+04 40 carpholite-Mg 8.65 7.27 -1.38 -0.092 0.23630E+04 41 carpholite-Fe 6.78 5.04 -1.74 -0.116 0.29787E+04 42 celadonite 5.40 2.36 -3.04 -0.179 0.51894E+04 43 celadonite-Fe 3.94 0.13 -3.80 -0.224 0.64948E+04 50 chloritoid-Mg 13.26 10.66 -2.60 -0.174 0.44462E+04 51 chloritoid-Fe 9.24 8.43 -0.81 -0.054 0.13821E+04 52 chloritoid-Mn 11.46 10.56 -0.91 -0.061 0.15506E+04 54 coesite -2.37 -3.39 -1.02 -0.340 0.17442E+04 59 corundum 8.43 5.49 -2.95 -0.268 0.50299E+04 61 cristobalite -2.55 -3.39 -0.84 -0.281 0.14371E+04 63 cymrite-K 1.73 -2.81 -4.54 -0.378 0.77505E+04 65 diaspore 2.90 2.74 -0.15 -0.025 0.26002E+03 67 diopside 16.22 12.62 -3.59 -0.359 0.61370E+04 68 hedenbergite 14.24 10.39 -3.85 -0.385 0.65758E+04 75 epidote 24.78 23.30 -1.48 -0.072 0.25210E+04 76 clinozoisite 22.92 19.74 -3.18 -0.144 0.54253E+04 77 epidote-Fe 29.94 26.85 -3.08 -0.160 0.52642E+04 78 fayalite 14.08 9.27 -4.80 -0.686 0.82042E+04 83 gibbsite 4.10 2.74 -1.35 -0.193 0.23112E+04 87 greenalite 16.19 12.22 -3.98 -0.332 0.67932E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.81 -2.44 -0.244 0.41644E+04 97 kalsilite 7.62 3.97 -3.65 -0.521 0.62271E+04 98 kaolinite -1.27 -1.29 -0.02 -0.002 0.35737E+02 99 kyanite 4.93 2.10 -2.83 -0.283 0.48405E+04 101 laumontite 2.97 2.77 -0.21 -0.014 0.35493E+03 102 lawsonite 9.68 9.55 -0.13 -0.009 0.22199E+03 103 leucite 4.17 0.58 -3.59 -0.359 0.61217E+04 105 lizardite 23.29 18.90 -4.39 -0.366 0.74916E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20536E+04 113 margarite 17.45 15.04 -2.42 -0.097 0.41249E+04 116 microcline -2.43 -2.81 -0.38 -0.029 0.64308E+03 121 paragonite 4.34 3.91 -0.43 -0.025 0.73054E+03 122 nepheline 8.38 5.20 -3.18 -0.454 0.54217E+04 136 prehnite 19.47 17.00 -2.47 -0.145 0.42113E+04 137 prehnite-Fe 22.59 20.55 -2.03 -0.122 0.34693E+04 138 pumpellyite-Fe 46.47 43.08 -3.39 -0.075 0.57958E+04 139 pumpellyite-Mg 49.19 45.30 -3.89 -0.086 0.66417E+04 145 pyroxmangite 7.42 5.07 -2.35 -0.470 0.40101E+04 146 pyrophyllite -6.10 -8.08 -1.98 -0.124 0.33769E+04 147 quartz -2.98 -3.39 -0.41 -0.136 0.69809E+03 151 rhodochrosite -0.96 -5.37 -4.41 -1.471 0.75329E+04 152 rhodonite 7.46 5.07 -2.39 -0.479 0.40894E+04 153 sanidine -1.22 -2.81 -1.59 -0.122 0.27108E+04 155 siderite -2.59 -7.50 -4.91 -1.636 0.83810E+04 156 sillimanite 5.32 2.10 -3.22 -0.322 0.55059E+04 164 stilpnomelane-Fe 13.18 12.33 -0.85 -0.025 0.14445E+04 165 stilpnomelane-Mg 27.60 23.47 -4.12 -0.123 0.70393E+04 167 sudoite-Fe 18.44 13.47 -4.97 -0.160 0.84851E+04 168 sudoite 21.22 17.92 -3.29 -0.106 0.56218E+04 171 talc 16.55 12.12 -4.44 -0.261 0.75730E+04 174 tephroite 18.11 13.53 -4.59 -0.655 0.78324E+04 177 topaz-H 4.67 2.10 -2.57 -0.234 0.43895E+04 178 tridymite -2.61 -3.39 -0.78 -0.259 0.13254E+04 187 wairakite 4.06 2.77 -1.29 -0.076 0.22057E+04 188 walstromite 11.53 7.45 -4.08 -0.815 0.69601E+04 189 wollastonite 10.48 7.45 -3.03 -0.606 0.51740E+04 190 pseudo-wollastonite 11.02 7.45 -3.57 -0.714 0.60927E+04 191 zoisite 22.96 19.74 -3.22 -0.146 0.54978E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.26 -2.70 -0.167 0.46147E+04 194 beidellite-H -2.24 -6.05 -3.81 -0.243 0.65058E+04 195 beidellite-K -1.44 -4.53 -3.09 -0.189 0.52788E+04 196 beidellite-Mg -1.71 -4.64 -2.93 -0.181 0.50062E+04 197 beidellite-Na -1.26 -4.12 -2.86 -0.175 0.48899E+04 199 chalcedony -2.79 -3.39 -0.60 -0.199 0.10184E+04 201 montmorillonite-Ca -2.21 -4.37 -2.15 -0.133 0.36766E+04 202 montmorillonite-K -2.16 -4.63 -2.47 -0.151 0.42184E+04 203 montmorillonite-Mg -2.40 -4.74 -2.34 -0.145 0.39991E+04 204 montmorillonite-Na -1.96 -4.23 -2.27 -0.139 0.38677E+04 205 nontronite-Ca 3.28 2.85 -0.43 -0.028 0.73759E+03 206 nontronite-H 2.60 1.06 -1.54 -0.103 0.26245E+04 207 nontronite-K 3.40 2.58 -0.82 -0.053 0.14009E+04 208 nontronite-Mg 3.14 2.47 -0.67 -0.043 0.11407E+04 209 nontronite-Na 3.58 2.99 -0.59 -0.038 0.10137E+04 224 tobermorite 9.84 5.64 -4.20 -1.145 0.71681E+04 233 boehmite 4.43 2.74 -1.69 -0.281 0.28784E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59621E+04 240 silica-amorphous -2.08 -3.39 -1.31 -0.437 0.22386E+04 242 an20ab80 2.08 0.65 -1.43 -0.110 0.24461E+04 243 an25ab75 2.71 1.20 -1.51 -0.116 0.25718E+04 244 an30ab70 3.34 1.76 -1.58 -0.122 0.27058E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.6590000 g New total amount of reactant added: 0.6790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5867E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.6790000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .7800598E-03 Osmotic coef. = 0.9837 True ionic strength = .1094112E-02 Chg. balance for total moles = -.5867E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13564E-08 -8.8676 0.12764E-08 -8.8940 0.94102E+00 -0.0264 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12976E-03 -3.8869 0.94059E+00 -0.0266 4 SO4-- 0.25488E-04 -4.5937 0.21069E-04 -4.6763 0.82664E+00 -0.0827 5 HCO3- 0.12048E-04 -4.9191 0.11334E-04 -4.9456 0.94069E+00 -0.0266 6 HS- 0.53991E-13 -13.2677 0.50784E-13 -13.2943 0.94060E+00 -0.0266 7 Al+++ 0.16740E-23 -23.7762 0.11143E-23 -23.9530 0.66561E+00 -0.1768 8 H4SiO4 0.41458E-03 -3.3824 0.41458E-03 -3.3824 0.10000E+01 0.0000 9 Ca++ 0.12816E-06 -6.8923 0.10588E-06 -6.9752 0.82618E+00 -0.0829 10 Mg++ 0.71848E-09 -9.1436 0.59339E-09 -9.2267 0.82589E+00 -0.0831 11 Fe++ 0.42494E-11 -11.3717 0.35098E-11 -11.4547 0.82596E+00 -0.0830 12 K+ 0.59134E-04 -4.2282 0.55628E-04 -4.2547 0.94071E+00 -0.0265 13 Na+ 0.10074E-02 -2.9968 0.94752E-03 -3.0234 0.94058E+00 -0.0266 14 Mn++ 0.56771E-09 -9.2459 0.46894E-09 -9.3289 0.82601E+00 -0.0830 15 HPO4-- 0.71291E-06 -6.1470 0.58932E-06 -6.2296 0.82665E+00 -0.0827 16 HSiO3- 0.33692E-03 -3.4725 0.31690E-03 -3.4991 0.94059E+00 -0.0266 17 Ca(HSiO3)+ 0.79916E-09 -9.0974 0.75179E-09 -9.1239 0.94073E+00 -0.0265 18 Mg(HSiO3)+ 0.55737E-11 -11.2539 0.52433E-11 -11.2804 0.94073E+00 -0.0265 19 NaHSiO3,aq 0.47690E-05 -5.3216 0.47690E-05 -5.3216 0.10000E+01 0.0000 20 AlO+ 0.93855E-13 -13.0275 0.88292E-13 -13.0541 0.94073E+00 -0.0265 21 AlOH+2 0.68340E-18 -18.1653 0.56454E-18 -18.2483 0.82608E+00 -0.0830 22 HAlO2,aq 0.13842E-07 -7.8588 0.13842E-07 -7.8588 0.10000E+01 0.0000 23 AlO2- 0.25748E-04 -4.5893 0.24215E-04 -4.6159 0.94046E+00 -0.0267 24 CH4,aq 0.26812E-19 -19.5717 0.26806E-19 -19.5718 0.99976E+00 -0.0001 29 CO,aq 0.33162E-18 -18.4794 0.33162E-18 -18.4794 0.10000E+01 0.0000 30 CO2,aq 0.29174E-07 -7.5350 0.29167E-07 -7.5351 0.99976E+00 -0.0001 31 CO3-2 0.99332E-06 -6.0029 0.82098E-06 -6.0857 0.82650E+00 -0.0828 32 CaCO3,aq 0.10647E-08 -8.9728 0.10647E-08 -8.9728 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.32143E-10 -10.4929 0.30237E-10 -10.5195 0.94073E+00 -0.0265 34 CaCl+ 0.23272E-10 -10.6332 0.21893E-10 -10.6597 0.94073E+00 -0.0265 35 CaCl2,aq 0.66143E-15 -15.1795 0.66143E-15 -15.1795 0.10000E+01 0.0000 36 CaOH+ 0.62179E-08 -8.2064 0.58493E-08 -8.2329 0.94073E+00 -0.0265 37 CaSO4,aq 0.69509E-09 -9.1580 0.69509E-09 -9.1580 0.10000E+01 0.0000 38 HCl,aq 0.31153E-13 -13.5065 0.31153E-13 -13.5065 0.10000E+01 0.0000 43 FeCl+ 0.75402E-15 -15.1226 0.70933E-15 -15.1492 0.94073E+00 -0.0265 46 FeO,aq 0.85191E-10 -10.0696 0.85191E-10 -10.0696 0.10000E+01 0.0000 47 FeOH+ 0.96906E-10 -10.0136 0.91162E-10 -10.0402 0.94073E+00 -0.0265 48 HFeO2- 0.76324E-09 -9.1173 0.71789E-09 -9.1439 0.94059E+00 -0.0266 49 FeO+ 0.11224E-13 -13.9499 0.10559E-13 -13.9764 0.94073E+00 -0.0265 51 FeO2- 0.13542E-08 -8.8683 0.12737E-08 -8.8949 0.94059E+00 -0.0266 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44156E-09 -9.3550 0.44145E-09 -9.3551 0.99976E+00 -0.0001 54 KCl,aq 0.12781E-09 -9.8934 0.12781E-09 -9.8934 0.10000E+01 0.0000 55 KHSO4,aq 0.40032E-17 -17.3976 0.40032E-17 -17.3976 0.10000E+01 0.0000 56 KOH,aq 0.18999E-07 -7.7213 0.18999E-07 -7.7213 0.10000E+01 0.0000 57 KSO4- 0.19198E-07 -7.7168 0.18057E-07 -7.7434 0.94059E+00 -0.0266 58 MgCO3,aq 0.14909E-11 -11.8265 0.14909E-11 -11.8265 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18369E-12 -12.7359 0.17280E-12 -12.7625 0.94073E+00 -0.0265 60 MgCl+ 0.11840E-12 -12.9266 0.11138E-12 -12.9532 0.94073E+00 -0.0265 61 MgOH+ 0.19305E-09 -9.7143 0.18161E-09 -9.7409 0.94073E+00 -0.0265 63 MnO,aq 0.30385E-09 -9.5173 0.30385E-09 -9.5173 0.10000E+01 0.0000 64 MnOH+ 0.12028E-08 -8.9198 0.11315E-08 -8.9464 0.94073E+00 -0.0265 65 MnO2-2 0.78038E-14 -14.1077 0.64499E-14 -14.1904 0.82650E+00 -0.0828 66 HMnO2- 0.18964E-11 -11.7221 0.17837E-11 -11.7487 0.94059E+00 -0.0266 69 MnCl+ 0.39147E-12 -12.4073 0.36827E-12 -12.4338 0.94073E+00 -0.0265 70 MnSO4,aq 0.28001E-11 -11.5528 0.28001E-11 -11.5528 0.10000E+01 0.0000 71 NaCl,aq 0.40145E-07 -7.3964 0.40145E-07 -7.3964 0.10000E+01 0.0000 72 NaOH,aq 0.32619E-06 -6.4865 0.32619E-06 -6.4865 0.10000E+01 0.0000 74 OH- 0.49970E-03 -3.3013 0.46994E-03 -3.3280 0.94046E+00 -0.0267 79 HPO3-2 0.99422E-18 -18.0025 0.82172E-18 -18.0853 0.82650E+00 -0.0828 82 H3PO4,aq 0.61812E-14 -14.2089 0.61812E-14 -14.2089 0.10000E+01 0.0000 83 H2PO4- 0.14020E-07 -7.8533 0.13188E-07 -7.8798 0.94065E+00 -0.0266 84 PO4-3 0.60350E-09 -9.2193 0.40321E-09 -9.3945 0.66812E+00 -0.1751 87 H2P2O7-2 0.16469E-16 -16.7833 0.13612E-16 -16.8661 0.82650E+00 -0.0828 88 HP2O7-3 0.32852E-14 -14.4834 0.21867E-14 -14.6602 0.66563E+00 -0.1768 89 P2O7-4 0.85767E-15 -15.0667 0.42264E-15 -15.3740 0.49278E+00 -0.3073 90 H2S,aq 0.19481E-15 -15.7104 0.19476E-15 -15.7105 0.99976E+00 -0.0001 97 SO3-2 0.15327E-14 -14.8145 0.12682E-14 -14.8968 0.82742E+00 -0.0823 98 HSO3- 0.10072E-15 -15.9969 0.94732E-16 -16.0235 0.94059E+00 -0.0266 99 HSO4- 0.26523E-10 -10.5764 0.24953E-10 -10.6029 0.94079E+00 -0.0265 Charge balance for all species = -.5870E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1356400E-08 -.9457264E-03 -.9531327E+00 0.0000 2 H2O 0.1000000E+01 0.5550846E+02 0.9998938E+06 0.0000 3 Cl- 0.1379527E-03 0.1379930E-03 0.4891738E+01 5.0071 4 SO4-- 0.2548802E-04 0.2550803E-04 0.2450078E+01 13.1117 5 HCO3- 0.1204819E-04 0.1307178E-04 0.7975175E+00 3.9484 6 HS- 0.5399118E-13 -.8426589E-10 -.2786541E-05 -4.4003 7 Al+++ 0.1674038E-23 0.2576188E-04 0.6950193E+00 2.7290 8 H4SiO4 0.4145783E-03 0.7562644E-03 0.7268082E+02 -3.3824 9 Ca++ 0.1281590E-06 0.1369913E-06 0.5489744E-02 10.8128 10 Mg++ 0.7184782E-09 0.9188949E-09 0.2233777E-04 8.5614 11 Fe++ 0.4249396E-11 0.2507274E-08 0.1400086E-03 6.3333 12 K+ 0.5913385E-04 0.5917218E-04 0.2313501E+01 4.6393 13 Na+ 0.1007384E-02 0.1012519E-02 0.2327511E+02 5.8706 14 Mn++ 0.5677126E-09 0.2079424E-08 0.1142271E-03 8.4591 15 HPO4-- 0.7129063E-06 0.7275296E-06 0.6982004E-01 11.5584 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1123019E-01 -.9455975E-03 -.1028459E-01 0.0000000E+00 2 H2O 0.5549974E+02 0.5550090E+02 -.1156654E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4432187E-04 0.2550455E-04 0.1881732E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1881740E-04 -.8425441E-10 -.1881732E-04 0.0000000E+00 7 Al+++ 0.2214044E-02 0.2575837E-04 0.2188285E-02 0.0000000E+00 8 H4SiO4 0.7070280E-02 0.7561613E-03 0.6314118E-02 0.0000000E+00 9 Ca++ 0.7954179E-03 0.1369726E-06 0.7952809E-03 0.0000000E+00 10 Mg++ 0.5388889E-03 0.9187697E-09 0.5388880E-03 0.0000000E+00 11 Fe++ 0.4841328E-03 0.2506932E-08 0.4841303E-03 0.0000000E+00 12 K+ 0.1441614E-03 0.5916411E-04 0.8499725E-04 0.0000000E+00 13 Na+ 0.1012381E-02 0.1012381E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1177291E-04 0.2079140E-08 0.1177083E-04 0.0000000E+00 15 HPO4-- 0.4018035E-05 0.7274304E-06 0.3290604E-05 0.0000000E+00 Chg. balance for solid moles: -.8098E-18 Mass of aqueous solution: 0.999972E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.6790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1097E-05 -5.960 0.5510E-03 -3.259 0.7736E-01 0.1751E-03 clinochlore 0.1078E-03 -3.967 0.5991E-01 -1.223 8.412 0.2279E-01 daphnite 0.6672E-04 -4.176 0.4760E-01 -1.322 6.684 0.1443E-01 chlorite-Mn 0.2354E-05 -5.628 0.1669E-02 -2.778 0.2344 0.5319E-03 hematite 0.7527E-04 -4.123 0.1202E-01 -1.920 1.688 0.2278E-02 muscovite 0.8500E-04 -4.071 0.3386E-01 -1.470 4.754 0.1197E-01 stilbite 0.7898E-03 -3.102 0.5566 -0.254 78.15 0.2596 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.712191 g Volume = 0.311770 cm3 Porosity: 75.4820% V(tot) - V(min): 0.95983E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.6790000 g log = -0.1681 Original solution: 1000.0103000 g Original solution / Rock added: 1472.77 (Water/Rock Ratio), log = 3.1681 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3151E-05 1.0073 0.3339E-05 0.3314E-05 CH4,gas 0.3978E-16 1.0129 0.4239E-16 0.4185E-16 H2,gas 0.5753E-06 1.0006 0.6055E-06 0.6051E-06 H2S,gas 0.5422E-14 0.9959 0.5680E-14 0.5704E-14 S2,gas 0.3134E-35 1.0000 0.3296E-35 0.3296E-35 CO,gas 0.4978E-15 1.0000 0.5236E-15 0.5236E-15 SO3,gas 0.1220E-37 1.0000 0.1283E-37 0.1283E-37 SO2,gas 0.2794E-21 1.0000 0.2939E-21 0.2939E-21 HCl,gas 0.5229E-16 1.0000 0.5501E-16 0.5501E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.72794E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.60662E-10 90 hematite 12.60 12.60 0.00 0.000 0.15165E-10 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.84 -7.48 -2.492 0.12766E+05 -5.476 3 CH4,gas 4.81 -13.56 -18.37 -4.593 0.31371E+05 -16.373 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14032E+05 -6.218 5 H2S,gas -5.94 -22.19 -16.25 -8.123 0.27739E+05 -14.246 6 S2,gas -7.03 -44.51 -37.48 -5.766 0.63999E+05 -35.482 7 CO,gas 3.51 -13.77 -17.28 -5.317 0.29507E+05 -15.281 8 SO3,gas 17.43 -22.46 -39.89 -9.973 0.68114E+05 -37.892 9 SO2,gas 1.14 -22.40 -23.53 -6.275 0.40180E+05 -21.532 10 HCl,gas 5.48 -12.78 -18.26 -9.130 0.31178E+05 -16.260 11 acmite 7.74 5.40 -2.33 -0.242 0.39831E+04 15 albite-high 0.75 -1.55 -2.30 -0.177 0.39224E+04 16 albite -0.33 -1.55 -1.22 -0.094 0.20817E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65936E+04 20 analcite 3.37 1.83 -1.54 -0.171 0.26223E+04 21 andalusite 5.06 2.08 -2.99 -0.299 0.50997E+04 22 andradite 39.09 34.89 -4.20 -0.218 0.71693E+04 26 annite 20.21 16.22 -3.99 -0.222 0.68098E+04 27 phlogopite 27.15 22.91 -4.24 -0.236 0.72420E+04 29 anorthite 12.80 9.51 -3.29 -0.253 0.56203E+04 35 aragonite 0.99 -3.03 -4.01 -1.338 0.68521E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68559E+04 37 calcite 0.83 -3.03 -3.86 -1.287 0.65908E+04 38 carnegieite-low 9.06 5.22 -3.85 -0.550 0.65692E+04 39 carnegieite-high 10.13 5.22 -4.92 -0.702 0.83961E+04 40 carpholite-Mg 8.65 7.25 -1.40 -0.093 0.23832E+04 41 carpholite-Fe 6.78 5.03 -1.76 -0.117 0.29989E+04 42 celadonite 5.40 2.40 -3.00 -0.176 0.51231E+04 43 celadonite-Fe 3.94 0.17 -3.76 -0.221 0.64284E+04 50 chloritoid-Mg 13.26 10.64 -2.62 -0.175 0.44808E+04 51 chloritoid-Fe 9.24 8.41 -0.83 -0.055 0.14167E+04 52 chloritoid-Mn 11.46 10.53 -0.93 -0.062 0.15852E+04 54 coesite -2.37 -3.38 -1.01 -0.338 0.17297E+04 59 corundum 8.43 5.46 -2.98 -0.270 0.50804E+04 61 cristobalite -2.55 -3.38 -0.83 -0.278 0.14226E+04 63 cymrite-K 1.73 -2.78 -4.51 -0.376 0.77001E+04 65 diaspore 2.90 2.73 -0.17 -0.028 0.28526E+03 67 diopside 16.22 12.61 -3.61 -0.361 0.61572E+04 68 hedenbergite 14.24 10.38 -3.86 -0.386 0.65960E+04 75 epidote 24.78 23.24 -1.54 -0.075 0.26292E+04 76 clinozoisite 22.92 19.67 -3.26 -0.148 0.55588E+04 77 epidote-Fe 29.94 26.81 -3.13 -0.163 0.53471E+04 78 fayalite 14.08 9.28 -4.79 -0.685 0.81869E+04 83 gibbsite 4.10 2.73 -1.37 -0.195 0.23364E+04 87 greenalite 16.19 12.24 -3.96 -0.330 0.67600E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.83 -2.42 -0.242 0.41254E+04 97 kalsilite 7.62 3.99 -3.63 -0.519 0.62055E+04 98 kaolinite -1.27 -1.31 -0.03 -0.003 0.57368E+02 99 kyanite 4.93 2.08 -2.86 -0.286 0.48765E+04 101 laumontite 2.97 2.74 -0.23 -0.016 0.39822E+03 102 lawsonite 9.68 9.51 -0.17 -0.011 0.29413E+03 103 leucite 4.17 0.60 -3.56 -0.356 0.60856E+04 105 lizardite 23.29 18.92 -4.37 -0.364 0.74584E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20521E+04 108 minnesotaite 10.46 5.47 -4.99 -0.294 0.85209E+04 113 margarite 17.45 14.96 -2.49 -0.100 0.42476E+04 116 microcline -2.43 -2.78 -0.35 -0.027 0.59259E+03 121 paragonite 4.34 3.91 -0.43 -0.025 0.72761E+03 122 nepheline 8.38 5.22 -3.16 -0.452 0.53971E+04 136 prehnite 19.47 16.94 -2.53 -0.149 0.43195E+04 137 prehnite-Fe 22.59 20.51 -2.08 -0.125 0.35522E+04 138 pumpellyite-Fe 46.47 42.94 -3.54 -0.079 0.60361E+04 139 pumpellyite-Mg 49.19 45.16 -4.03 -0.090 0.68820E+04 145 pyroxmangite 7.42 5.08 -2.34 -0.468 0.39943E+04 146 pyrophyllite -6.10 -8.07 -1.97 -0.123 0.33697E+04 147 quartz -2.98 -3.38 -0.40 -0.133 0.68366E+03 151 rhodochrosite -0.96 -5.38 -4.42 -1.474 0.75504E+04 152 rhodonite 7.46 5.08 -2.39 -0.477 0.40735E+04 153 sanidine -1.22 -2.78 -1.56 -0.120 0.26603E+04 155 siderite -2.59 -7.51 -4.92 -1.640 0.83985E+04 156 sillimanite 5.32 2.08 -3.25 -0.325 0.55419E+04 164 stilpnomelane-Fe 13.18 12.39 -0.79 -0.024 0.13561E+04 165 stilpnomelane-Mg 27.60 23.53 -4.07 -0.122 0.69509E+04 168 sudoite 21.22 17.89 -3.32 -0.107 0.56766E+04 171 talc 16.55 12.15 -4.40 -0.259 0.75109E+04 174 tephroite 18.11 13.54 -4.58 -0.654 0.78151E+04 177 topaz-H 4.67 2.08 -2.59 -0.236 0.44256E+04 178 tridymite -2.61 -3.38 -0.77 -0.256 0.13110E+04 187 wairakite 4.06 2.74 -1.32 -0.077 0.22490E+04 188 walstromite 11.53 7.43 -4.10 -0.819 0.69962E+04 189 wollastonite 10.48 7.43 -3.05 -0.610 0.52101E+04 190 pseudo-wollastonite 11.02 7.43 -3.59 -0.718 0.61287E+04 191 zoisite 22.96 19.67 -3.30 -0.150 0.56313E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.27 -2.71 -0.168 0.46289E+04 194 beidellite-H -2.24 -6.05 -3.81 -0.243 0.65117E+04 195 beidellite-K -1.44 -4.52 -3.09 -0.189 0.52740E+04 196 beidellite-Mg -1.71 -4.64 -2.94 -0.182 0.50118E+04 197 beidellite-Na -1.26 -4.12 -2.86 -0.175 0.48841E+04 199 chalcedony -2.79 -3.38 -0.59 -0.196 0.10040E+04 201 montmorillonite-Ca -2.21 -4.36 -2.15 -0.133 0.36689E+04 202 montmorillonite-K -2.16 -4.62 -2.45 -0.150 0.41917E+04 203 montmorillonite-Mg -2.40 -4.73 -2.33 -0.144 0.39829E+04 204 montmorillonite-Na -1.96 -4.21 -2.25 -0.138 0.38400E+04 205 nontronite-Ca 3.28 2.87 -0.41 -0.027 0.70130E+03 206 nontronite-H 2.60 1.08 -1.51 -0.101 0.25799E+04 207 nontronite-K 3.40 2.62 -0.79 -0.051 0.13455E+04 208 nontronite-Mg 3.14 2.50 -0.64 -0.042 0.10959E+04 209 nontronite-Na 3.58 3.02 -0.56 -0.036 0.95739E+03 224 tobermorite 9.84 5.62 -4.21 -1.150 0.71958E+04 233 boehmite 4.43 2.73 -1.70 -0.283 0.29037E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59606E+04 240 silica-amorphous -2.08 -3.38 -1.30 -0.434 0.22242E+04 242 an20ab80 2.08 0.66 -1.42 -0.109 0.24178E+04 243 an25ab75 2.71 1.22 -1.49 -0.115 0.25498E+04 244 an30ab70 3.34 1.77 -1.58 -0.121 0.26900E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.6790000 g New total amount of reactant added: 0.6990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5867E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.6990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .7923082E-03 Osmotic coef. = 0.9836 True ionic strength = .1120233E-02 Chg. balance for total moles = -.5867E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13268E-08 -8.8772 0.12480E-08 -8.9038 0.94057E+00 -0.0266 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12969E-03 -3.8871 0.94012E+00 -0.0268 4 SO4-- 0.25488E-04 -4.5937 0.21028E-04 -4.6772 0.82503E+00 -0.0835 5 HCO3- 0.12027E-04 -4.9199 0.11308E-04 -4.9466 0.94023E+00 -0.0268 6 HS- 0.53553E-13 -13.2712 0.50347E-13 -13.2980 0.94013E+00 -0.0268 7 Al+++ 0.15206E-23 -23.8180 0.10077E-23 -23.9967 0.66269E+00 -0.1787 8 H4SiO4 0.42239E-03 -3.3743 0.42239E-03 -3.3743 0.10000E+01 0.0000 9 Ca++ 0.11505E-06 -6.9391 0.94870E-07 -7.0229 0.82457E+00 -0.0838 10 Mg++ 0.68954E-09 -9.1614 0.56836E-09 -9.2454 0.82427E+00 -0.0839 11 Fe++ 0.40782E-11 -11.3895 0.33618E-11 -11.4734 0.82434E+00 -0.0839 12 K+ 0.60377E-04 -4.2191 0.56769E-04 -4.2459 0.94025E+00 -0.0268 13 Na+ 0.10322E-02 -2.9863 0.97035E-03 -3.0131 0.94011E+00 -0.0268 14 Mn++ 0.54485E-09 -9.2637 0.44917E-09 -9.3476 0.82439E+00 -0.0839 15 HPO4-- 0.83238E-06 -6.0797 0.68675E-06 -6.1632 0.82504E+00 -0.0835 16 HSiO3- 0.35126E-03 -3.4544 0.33023E-03 -3.4812 0.94012E+00 -0.0268 17 Ca(HSiO3)+ 0.74652E-09 -9.1270 0.70193E-09 -9.1537 0.94027E+00 -0.0267 18 Mg(HSiO3)+ 0.55659E-11 -11.2545 0.52335E-11 -11.2812 0.94027E+00 -0.0267 19 NaHSiO3,aq 0.50893E-05 -5.2933 0.50893E-05 -5.2933 0.10000E+01 0.0000 20 AlO+ 0.88834E-13 -13.0514 0.83527E-13 -13.0782 0.94027E+00 -0.0267 21 AlOH+2 0.63335E-18 -18.1984 0.52217E-18 -18.2822 0.82446E+00 -0.0838 22 HAlO2,aq 0.13394E-07 -7.8731 0.13394E-07 -7.8731 0.10000E+01 0.0000 23 AlO2- 0.25494E-04 -4.5936 0.23964E-04 -4.6204 0.93999E+00 -0.0269 24 CH4,aq 0.26573E-19 -19.5756 0.26567E-19 -19.5757 0.99975E+00 -0.0001 29 CO,aq 0.32478E-18 -18.4884 0.32478E-18 -18.4884 0.10000E+01 0.0000 30 CO2,aq 0.28459E-07 -7.5458 0.28452E-07 -7.5459 0.99975E+00 -0.0001 31 CO3-2 0.10156E-05 -5.9933 0.83778E-06 -6.0769 0.82489E+00 -0.0836 32 CaCO3,aq 0.97345E-09 -9.0117 0.97345E-09 -9.0117 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.28748E-10 -10.5414 0.27031E-10 -10.5681 0.94027E+00 -0.0267 34 CaCl+ 0.20852E-10 -10.6809 0.19606E-10 -10.7076 0.94027E+00 -0.0267 35 CaCl2,aq 0.59205E-15 -15.2276 0.59205E-15 -15.2276 0.10000E+01 0.0000 36 CaOH+ 0.57009E-08 -8.2441 0.53604E-08 -8.2708 0.94027E+00 -0.0267 37 CaSO4,aq 0.62158E-09 -9.2065 0.62158E-09 -9.2065 0.10000E+01 0.0000 38 HCl,aq 0.30444E-13 -13.5165 0.30444E-13 -13.5165 0.10000E+01 0.0000 43 FeCl+ 0.72222E-15 -15.1413 0.67908E-15 -15.1681 0.94027E+00 -0.0267 46 FeO,aq 0.85360E-10 -10.0687 0.85360E-10 -10.0687 0.10000E+01 0.0000 47 FeOH+ 0.94982E-10 -10.0224 0.89308E-10 -10.0491 0.94027E+00 -0.0267 48 HFeO2- 0.78256E-09 -9.1065 0.73571E-09 -9.1333 0.94012E+00 -0.0268 49 FeO+ 0.10979E-13 -13.9594 0.10323E-13 -13.9862 0.94027E+00 -0.0267 51 FeO2- 0.13857E-08 -8.8583 0.13028E-08 -8.8851 0.94012E+00 -0.0268 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44332E-09 -9.3533 0.44321E-09 -9.3534 0.99975E+00 -0.0001 54 KCl,aq 0.13037E-09 -9.8848 0.13037E-09 -9.8848 0.10000E+01 0.0000 55 KHSO4,aq 0.39866E-17 -17.3994 0.39866E-17 -17.3994 0.10000E+01 0.0000 56 KOH,aq 0.19831E-07 -7.7027 0.19831E-07 -7.7027 0.10000E+01 0.0000 57 KSO4- 0.19563E-07 -7.7086 0.18392E-07 -7.7354 0.94012E+00 -0.0268 58 MgCO3,aq 0.14573E-11 -11.8365 0.14573E-11 -11.8365 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.17563E-12 -12.7554 0.16514E-12 -12.7822 0.94027E+00 -0.0267 60 MgCl+ 0.11341E-12 -12.9454 0.10663E-12 -12.9721 0.94027E+00 -0.0267 61 MgOH+ 0.18922E-09 -9.7230 0.17791E-09 -9.7498 0.94027E+00 -0.0267 63 MnO,aq 0.30445E-09 -9.5165 0.30445E-09 -9.5165 0.10000E+01 0.0000 64 MnOH+ 0.11789E-08 -8.9285 0.11085E-08 -8.9553 0.94027E+00 -0.0267 65 MnO2-2 0.81957E-14 -14.0864 0.67606E-14 -14.1700 0.82489E+00 -0.0836 66 HMnO2- 0.19444E-11 -11.7112 0.18280E-11 -11.7380 0.94012E+00 -0.0268 69 MnCl+ 0.37496E-12 -12.4260 0.35257E-12 -12.4528 0.94027E+00 -0.0267 70 MnSO4,aq 0.26768E-11 -11.5724 0.26768E-11 -11.5724 0.10000E+01 0.0000 71 NaCl,aq 0.41092E-07 -7.3862 0.41092E-07 -7.3862 0.10000E+01 0.0000 72 NaOH,aq 0.34166E-06 -6.4664 0.34166E-06 -6.4664 0.10000E+01 0.0000 74 OH- 0.51134E-03 -3.2913 0.48065E-03 -3.3182 0.93999E+00 -0.0269 79 HPO3-2 0.11654E-17 -17.9335 0.96137E-18 -18.0171 0.82489E+00 -0.0836 82 H3PO4,aq 0.68857E-14 -14.1621 0.68857E-14 -14.1621 0.10000E+01 0.0000 83 H2PO4- 0.15981E-07 -7.7964 0.15026E-07 -7.8232 0.94019E+00 -0.0268 84 PO4-3 0.72240E-09 -9.1412 0.48058E-09 -9.3182 0.66525E+00 -0.1770 87 H2P2O7-2 0.21421E-16 -16.6692 0.17670E-16 -16.7528 0.82489E+00 -0.0836 88 HP2O7-3 0.43810E-14 -14.3584 0.29033E-14 -14.5371 0.66271E+00 -0.1787 89 P2O7-4 0.11738E-14 -14.9304 0.57393E-15 -15.2411 0.48896E+00 -0.3107 90 H2S,aq 0.18883E-15 -15.7239 0.18878E-15 -15.7240 0.99975E+00 -0.0001 97 SO3-2 0.15388E-14 -14.8128 0.12708E-14 -14.8959 0.82583E+00 -0.0831 98 HSO3- 0.98718E-16 -16.0056 0.92807E-16 -16.0324 0.94012E+00 -0.0268 99 HSO4- 0.25894E-10 -10.5868 0.24349E-10 -10.6135 0.94033E+00 -0.0267 Charge balance for all species = -.5866E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1326819E-08 -.9710475E-03 -.9786495E+00 0.0000 2 H2O 0.1000000E+01 0.5550846E+02 0.9998910E+06 0.0000 3 Cl- 0.1379523E-03 0.1379935E-03 0.4891744E+01 5.0167 4 SO4-- 0.2548783E-04 0.2550813E-04 0.2450081E+01 13.1304 5 HCO3- 0.1202674E-04 0.1307183E-04 0.7975184E+00 3.9572 6 HS- 0.5355273E-13 -.8777041E-10 -.2902422E-05 -4.3942 7 Al+++ 0.1520588E-23 0.2550727E-04 0.6881484E+00 2.7147 8 H4SiO4 0.4223889E-03 0.7787374E-03 0.7484039E+02 -3.3743 9 Ca++ 0.1150547E-06 0.1231468E-06 0.4934932E-02 10.7847 10 Mg++ 0.6895354E-09 0.8860632E-09 0.2153959E-04 8.5622 11 Fe++ 0.4078208E-11 0.2556210E-08 0.1427409E-03 6.3342 12 K+ 0.6037695E-04 0.6041648E-04 0.2362144E+01 4.6579 13 Na+ 0.1032160E-02 0.1037632E-02 0.2385231E+02 5.8907 14 Mn++ 0.5448461E-09 0.2033191E-08 0.1116871E-03 8.4600 15 HPO4-- 0.8323799E-06 0.8490838E-06 0.8148521E-01 11.6444 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1156136E-01 -.9709115E-03 -.1059045E-01 0.0000000E+00 2 H2O 0.5549949E+02 0.5550068E+02 -.1190032E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4487614E-04 0.2550456E-04 0.1937159E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1937167E-04 -.8775811E-10 -.1937159E-04 0.0000000E+00 7 Al+++ 0.2279258E-02 0.2550370E-04 0.2253755E-02 0.0000000E+00 8 H4SiO4 0.7278535E-02 0.7786283E-03 0.6499907E-02 0.0000000E+00 9 Ca++ 0.8184208E-03 0.1231296E-06 0.8182976E-03 0.0000000E+00 10 Mg++ 0.5547619E-03 0.8859390E-09 0.5547610E-03 0.0000000E+00 11 Fe++ 0.4983930E-03 0.2555852E-08 0.4983905E-03 0.0000000E+00 12 K+ 0.1484076E-03 0.6040801E-04 0.8799963E-04 0.0000000E+00 13 Na+ 0.1037486E-02 0.1037486E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1211968E-04 0.2032906E-08 0.1211765E-04 0.0000000E+00 15 HPO4-- 0.4136386E-05 0.8489648E-06 0.3287421E-05 0.0000000E+00 Chg. balance for solid moles: -.9148E-19 Mass of aqueous solution: 0.999970E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.6990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1096E-05 -5.960 0.5504E-03 -3.259 0.7508E-01 0.1749E-03 clinochlore 0.1110E-03 -3.955 0.6167E-01 -1.210 8.411 0.2346E-01 daphnite 0.6868E-04 -4.163 0.4901E-01 -1.310 6.684 0.1485E-01 chlorite-Mn 0.2424E-05 -5.616 0.1718E-02 -2.765 0.2344 0.5475E-03 hematite 0.7749E-04 -4.111 0.1237E-01 -1.907 1.688 0.2345E-02 muscovite 0.8800E-04 -4.056 0.3505E-01 -1.455 4.781 0.1239E-01 stilbite 0.8128E-03 -3.090 0.5728 -0.242 78.13 0.2672 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.733181 g Volume = 0.320939 cm3 Porosity: 74.9188% V(tot) - V(min): 0.95866E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.6990000 g log = -0.1555 Original solution: 1000.0103000 g Original solution / Rock added: 1430.63 (Water/Rock Ratio), log = 3.1555 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3074E-05 1.0073 0.3257E-05 0.3233E-05 CH4,gas 0.3943E-16 1.0129 0.4201E-16 0.4148E-16 H2,gas 0.5776E-06 1.0006 0.6079E-06 0.6076E-06 H2S,gas 0.5256E-14 0.9959 0.5506E-14 0.5528E-14 S2,gas 0.2921E-35 1.0000 0.3073E-35 0.3073E-35 CO,gas 0.4875E-15 1.0000 0.5128E-15 0.5128E-15 SO3,gas 0.1164E-37 1.0000 0.1224E-37 0.1224E-37 SO2,gas 0.2677E-21 1.0000 0.2816E-21 0.2816E-21 HCl,gas 0.5110E-16 1.0000 0.5375E-16 0.5375E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.85 -7.49 -2.496 0.12784E+05 -5.487 3 CH4,gas 4.81 -13.57 -18.38 -4.594 0.31378E+05 -16.377 4 H2,gas 8.29 0.07 -8.22 -4.695 0.14029E+05 -6.216 5 H2S,gas -5.94 -22.20 -16.26 -8.130 0.27762E+05 -14.259 6 S2,gas -7.03 -44.55 -37.51 -5.771 0.64052E+05 -35.512 7 CO,gas 3.51 -13.78 -17.29 -5.320 0.29522E+05 -15.290 8 SO3,gas 17.43 -22.48 -39.91 -9.978 0.68149E+05 -37.912 9 SO2,gas 1.14 -22.41 -23.55 -6.280 0.40212E+05 -21.550 10 HCl,gas 5.48 -12.79 -18.27 -9.135 0.31195E+05 -16.270 11 acmite 7.74 5.44 -2.30 -0.239 0.39211E+04 15 albite-high 0.75 -1.52 -2.27 -0.174 0.38709E+04 16 albite -0.33 -1.52 -1.19 -0.091 0.20303E+04 19 spessartine 24.55 20.69 -3.86 -0.193 0.65965E+04 20 analcite 3.37 1.86 -1.51 -0.168 0.25847E+04 21 andalusite 5.06 2.06 -3.01 -0.301 0.51348E+04 22 andradite 39.09 34.83 -4.26 -0.221 0.72718E+04 26 annite 20.21 16.25 -3.96 -0.220 0.67565E+04 27 phlogopite 27.15 22.94 -4.21 -0.234 0.71887E+04 29 anorthite 12.80 9.47 -3.33 -0.256 0.56895E+04 35 aragonite 0.99 -3.07 -4.05 -1.351 0.69185E+04 36 brucite 12.58 8.56 -4.01 -0.803 0.68544E+04 37 calcite 0.83 -3.07 -3.90 -1.300 0.66572E+04 38 carnegieite-low 9.06 5.23 -3.83 -0.548 0.65454E+04 39 carnegieite-high 10.13 5.23 -4.90 -0.700 0.83723E+04 40 carpholite-Mg 8.65 7.24 -1.41 -0.094 0.24029E+04 41 carpholite-Fe 6.78 5.02 -1.77 -0.118 0.30186E+04 42 celadonite 5.40 2.44 -2.96 -0.174 0.50589E+04 43 celadonite-Fe 3.94 0.21 -3.73 -0.219 0.63642E+04 44 chrysotile 23.94 18.94 -5.00 -0.417 0.85361E+04 50 chloritoid-Mg 13.26 10.62 -2.64 -0.176 0.45143E+04 51 chloritoid-Fe 9.24 8.39 -0.85 -0.057 0.14503E+04 52 chloritoid-Mn 11.46 10.52 -0.95 -0.063 0.16188E+04 54 coesite -2.37 -3.37 -1.00 -0.335 0.17159E+04 59 corundum 8.43 5.43 -3.00 -0.273 0.51292E+04 61 cristobalite -2.55 -3.37 -0.83 -0.275 0.14088E+04 63 cymrite-K 1.73 -2.75 -4.48 -0.373 0.76512E+04 65 diaspore 2.90 2.71 -0.18 -0.030 0.30969E+03 67 diopside 16.22 12.60 -3.62 -0.362 0.61761E+04 68 hedenbergite 14.24 10.37 -3.87 -0.387 0.66149E+04 75 epidote 24.78 23.17 -1.60 -0.078 0.27326E+04 76 clinozoisite 22.92 19.59 -3.33 -0.151 0.56866E+04 77 epidote-Fe 29.94 26.76 -3.18 -0.165 0.54261E+04 78 fayalite 14.08 9.29 -4.78 -0.684 0.81701E+04 83 gibbsite 4.10 2.71 -1.38 -0.198 0.23609E+04 87 greenalite 16.19 12.25 -3.94 -0.328 0.67279E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.86 -2.39 -0.239 0.40878E+04 97 kalsilite 7.62 4.00 -3.62 -0.517 0.61843E+04 98 kaolinite -1.27 -1.32 -0.05 -0.004 0.78549E+02 99 kyanite 4.93 2.06 -2.88 -0.288 0.49115E+04 101 laumontite 2.97 2.72 -0.26 -0.017 0.43974E+03 102 lawsonite 9.68 9.47 -0.21 -0.014 0.36334E+03 103 leucite 4.17 0.62 -3.54 -0.354 0.60506E+04 105 lizardite 23.29 18.94 -4.35 -0.362 0.74264E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20507E+04 108 minnesotaite 10.46 5.51 -4.96 -0.291 0.84611E+04 113 margarite 17.45 14.89 -2.56 -0.102 0.43656E+04 116 microcline -2.43 -2.75 -0.32 -0.024 0.54373E+03 121 paragonite 4.34 3.91 -0.42 -0.025 0.72503E+03 122 nepheline 8.38 5.23 -3.15 -0.450 0.53734E+04 136 prehnite 19.47 16.88 -2.59 -0.152 0.44229E+04 137 prehnite-Fe 22.59 20.46 -2.13 -0.128 0.36312E+04 138 pumpellyite-Fe 46.47 42.80 -3.67 -0.082 0.62658E+04 139 pumpellyite-Mg 49.19 45.03 -4.17 -0.093 0.71117E+04 145 pyroxmangite 7.42 5.09 -2.33 -0.466 0.39789E+04 146 pyrophyllite -6.10 -8.07 -1.97 -0.123 0.33632E+04 147 quartz -2.98 -3.37 -0.39 -0.131 0.66982E+03 151 rhodochrosite -0.96 -5.39 -4.43 -1.477 0.75673E+04 152 rhodonite 7.46 5.09 -2.38 -0.475 0.40582E+04 153 sanidine -1.22 -2.75 -1.53 -0.118 0.26115E+04 155 siderite -2.59 -7.52 -4.93 -1.643 0.84154E+04 156 sillimanite 5.32 2.06 -3.27 -0.327 0.55769E+04 164 stilpnomelane-Fe 13.18 12.43 -0.74 -0.022 0.12710E+04 165 stilpnomelane-Mg 27.60 23.58 -4.02 -0.120 0.68659E+04 168 sudoite 21.22 17.86 -3.36 -0.108 0.57298E+04 171 talc 16.55 12.19 -4.36 -0.257 0.74512E+04 174 tephroite 18.11 13.55 -4.57 -0.652 0.77983E+04 177 topaz-H 4.67 2.06 -2.61 -0.237 0.44606E+04 178 tridymite -2.61 -3.37 -0.76 -0.253 0.12971E+04 187 wairakite 4.06 2.72 -1.34 -0.079 0.22906E+04 188 walstromite 11.53 7.41 -4.12 -0.823 0.70304E+04 189 wollastonite 10.48 7.41 -3.07 -0.614 0.52443E+04 190 pseudo-wollastonite 11.02 7.41 -3.61 -0.722 0.61629E+04 191 zoisite 22.96 19.59 -3.37 -0.153 0.57591E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.28 -2.72 -0.168 0.46430E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65178E+04 195 beidellite-K -1.44 -4.52 -3.09 -0.189 0.52696E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50177E+04 197 beidellite-Na -1.26 -4.11 -2.86 -0.175 0.48789E+04 199 chalcedony -2.79 -3.37 -0.58 -0.193 0.99014E+03 201 montmorillonite-Ca -2.21 -4.36 -2.14 -0.133 0.36617E+04 202 montmorillonite-K -2.16 -4.60 -2.44 -0.149 0.41662E+04 203 montmorillonite-Mg -2.40 -4.73 -2.32 -0.144 0.39676E+04 204 montmorillonite-Na -1.96 -4.19 -2.23 -0.137 0.38136E+04 205 nontronite-Ca 3.28 2.89 -0.39 -0.025 0.66649E+03 206 nontronite-H 2.60 1.11 -1.49 -0.100 0.25371E+04 207 nontronite-K 3.40 2.65 -0.76 -0.049 0.12923E+04 208 nontronite-Mg 3.14 2.52 -0.62 -0.040 0.10529E+04 209 nontronite-Na 3.58 3.05 -0.53 -0.034 0.90332E+03 224 tobermorite 9.84 5.61 -4.23 -1.154 0.72220E+04 233 boehmite 4.43 2.71 -1.71 -0.286 0.29281E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59592E+04 240 silica-amorphous -2.08 -3.37 -1.29 -0.432 0.22103E+04 242 an20ab80 2.08 0.68 -1.40 -0.108 0.23905E+04 243 an25ab75 2.71 1.23 -1.48 -0.114 0.25285E+04 244 an30ab70 3.34 1.78 -1.57 -0.121 0.26748E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.6990000 g New total amount of reactant added: 0.7190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5865E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.7190000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .8046447E-03 Osmotic coef. = 0.9835 True ionic strength = .1146379E-02 Chg. balance for total moles = -.5865E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12988E-08 -8.8865 0.12210E-08 -8.9133 0.94012E+00 -0.0268 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12963E-03 -3.8873 0.93967E+00 -0.0270 4 SO4-- 0.25488E-04 -4.5937 0.20988E-04 -4.6780 0.82345E+00 -0.0844 5 HCO3- 0.12005E-04 -4.9206 0.11282E-04 -4.9476 0.93978E+00 -0.0270 6 HS- 0.53173E-13 -13.2743 0.49965E-13 -13.3013 0.93968E+00 -0.0270 7 Al+++ 0.13855E-23 -23.8584 0.91416E-24 -24.0390 0.65981E+00 -0.1806 8 H4SiO4 0.43002E-03 -3.3665 0.43002E-03 -3.3665 0.10000E+01 0.0000 9 Ca++ 0.10377E-06 -6.9839 0.85397E-07 -7.0686 0.82297E+00 -0.0846 10 Mg++ 0.66270E-09 -9.1787 0.54519E-09 -9.2635 0.82267E+00 -0.0848 11 Fe++ 0.39195E-11 -11.4068 0.32247E-11 -11.4915 0.82274E+00 -0.0847 12 K+ 0.61637E-04 -4.2102 0.57927E-04 -4.2371 0.93980E+00 -0.0270 13 Na+ 0.10569E-02 -2.9760 0.99315E-03 -3.0030 0.93966E+00 -0.0270 14 Mn++ 0.52365E-09 -9.2810 0.43086E-09 -9.3657 0.82280E+00 -0.0847 15 HPO4-- 0.96530E-06 -6.0153 0.79488E-06 -6.0997 0.82346E+00 -0.0844 16 HSiO3- 0.36567E-03 -3.4369 0.34361E-03 -3.4639 0.93967E+00 -0.0270 17 Ca(HSiO3)+ 0.69955E-09 -9.1552 0.65745E-09 -9.1821 0.93981E+00 -0.0270 18 Mg(HSiO3)+ 0.55581E-11 -11.2551 0.52235E-11 -11.2820 0.93981E+00 -0.0270 19 NaHSiO3,aq 0.54200E-05 -5.2660 0.54200E-05 -5.2660 0.10000E+01 0.0000 20 AlO+ 0.84227E-13 -13.0745 0.79157E-13 -13.1015 0.93981E+00 -0.0270 21 AlOH+2 0.58840E-18 -18.2303 0.48417E-18 -18.3150 0.82286E+00 -0.0847 22 HAlO2,aq 0.12973E-07 -7.8870 0.12973E-07 -7.8870 0.10000E+01 0.0000 23 AlO2- 0.25250E-04 -4.5977 0.23724E-04 -4.6248 0.93953E+00 -0.0271 24 CH4,aq 0.26363E-19 -19.5790 0.26357E-19 -19.5791 0.99975E+00 -0.0001 29 CO,aq 0.31834E-18 -18.4971 0.31834E-18 -18.4971 0.10000E+01 0.0000 30 CO2,aq 0.27782E-07 -7.5562 0.27775E-07 -7.5563 0.99975E+00 -0.0001 31 CO3-2 0.10377E-05 -5.9839 0.85434E-06 -6.0684 0.82331E+00 -0.0844 32 CaCO3,aq 0.89357E-09 -9.0489 0.89357E-09 -9.0489 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.25832E-10 -10.5878 0.24277E-10 -10.6148 0.93981E+00 -0.0270 34 CaCl+ 0.18770E-10 -10.7265 0.17640E-10 -10.7535 0.93981E+00 -0.0270 35 CaCl2,aq 0.53241E-15 -15.2738 0.53241E-15 -15.2738 0.10000E+01 0.0000 36 CaOH+ 0.52474E-08 -8.2801 0.49316E-08 -8.3070 0.93981E+00 -0.0270 37 CaSO4,aq 0.55844E-09 -9.2530 0.55844E-09 -9.2530 0.10000E+01 0.0000 38 HCl,aq 0.29772E-13 -13.5262 0.29772E-13 -13.5262 0.10000E+01 0.0000 43 FeCl+ 0.69277E-15 -15.1594 0.65107E-15 -15.1864 0.93981E+00 -0.0270 46 FeO,aq 0.85533E-10 -10.0679 0.85533E-10 -10.0679 0.10000E+01 0.0000 47 FeOH+ 0.93164E-10 -10.0308 0.87556E-10 -10.0577 0.93981E+00 -0.0270 48 HFeO2- 0.80184E-09 -9.0959 0.75346E-09 -9.1229 0.93967E+00 -0.0270 49 FeO+ 0.10747E-13 -13.9687 0.10100E-13 -13.9957 0.93981E+00 -0.0270 51 FeO2- 0.14170E-08 -8.8486 0.13315E-08 -8.8757 0.93967E+00 -0.0270 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44511E-09 -9.3515 0.44500E-09 -9.3516 0.99975E+00 -0.0001 54 KCl,aq 0.13296E-09 -9.8763 0.13296E-09 -9.8763 0.10000E+01 0.0000 55 KHSO4,aq 0.39724E-17 -17.4010 0.39724E-17 -17.4010 0.10000E+01 0.0000 56 KOH,aq 0.20682E-07 -7.6844 0.20682E-07 -7.6844 0.10000E+01 0.0000 57 KSO4- 0.19933E-07 -7.7004 0.18730E-07 -7.7275 0.93967E+00 -0.0270 58 MgCO3,aq 0.14255E-11 -11.8460 0.14255E-11 -11.8460 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16817E-12 -12.7743 0.15805E-12 -12.8012 0.93981E+00 -0.0270 60 MgCl+ 0.10878E-12 -12.9634 0.10223E-12 -12.9904 0.93981E+00 -0.0270 61 MgOH+ 0.18559E-09 -9.7314 0.17442E-09 -9.7584 0.93981E+00 -0.0270 63 MnO,aq 0.30507E-09 -9.5156 0.30507E-09 -9.5156 0.10000E+01 0.0000 64 MnOH+ 0.11563E-08 -8.9369 0.10867E-08 -8.9639 0.93981E+00 -0.0270 65 MnO2-2 0.85953E-14 -14.0657 0.70766E-14 -14.1502 0.82331E+00 -0.0844 66 HMnO2- 0.19923E-11 -11.7006 0.18721E-11 -11.7277 0.93967E+00 -0.0270 69 MnCl+ 0.35967E-12 -12.4441 0.33803E-12 -12.4710 0.93981E+00 -0.0270 70 MnSO4,aq 0.25627E-11 -11.5913 0.25627E-11 -11.5913 0.10000E+01 0.0000 71 NaCl,aq 0.42037E-07 -7.3764 0.42037E-07 -7.3764 0.10000E+01 0.0000 72 NaOH,aq 0.35740E-06 -6.4468 0.35740E-06 -6.4468 0.10000E+01 0.0000 74 OH- 0.52287E-03 -3.2816 0.49126E-03 -3.3087 0.93953E+00 -0.0271 79 HPO3-2 0.13570E-17 -17.8674 0.11172E-17 -17.9519 0.82331E+00 -0.0844 82 H3PO4,aq 0.76295E-14 -14.1175 0.76295E-14 -14.1175 0.10000E+01 0.0000 83 H2PO4- 0.18107E-07 -7.7421 0.17016E-07 -7.7691 0.93974E+00 -0.0270 84 PO4-3 0.85825E-09 -9.0664 0.56852E-09 -9.2453 0.66242E+00 -0.1789 87 H2P2O7-2 0.27525E-16 -16.5603 0.22661E-16 -16.6447 0.82331E+00 -0.0844 88 HP2O7-3 0.57675E-14 -14.2390 0.38056E-14 -14.4196 0.65984E+00 -0.1806 89 P2O7-4 0.15846E-14 -14.8001 0.76890E-15 -15.1141 0.48522E+00 -0.3141 90 H2S,aq 0.18335E-15 -15.7367 0.18330E-15 -15.7368 0.99975E+00 -0.0001 97 SO3-2 0.15449E-14 -14.8111 0.12734E-14 -14.8950 0.82427E+00 -0.0839 98 HSO3- 0.96837E-16 -16.0140 0.90995E-16 -16.0410 0.93967E+00 -0.0270 99 HSO4- 0.25299E-10 -10.5969 0.23778E-10 -10.6238 0.93988E+00 -0.0269 Charge balance for all species = -.5865E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1298792E-08 -.9963950E-03 -.1004193E+01 0.0000 2 H2O 0.1000000E+01 0.5550845E+02 0.9998883E+06 0.0000 3 Cl- 0.1379519E-03 0.1379940E-03 0.4891749E+01 5.0260 4 SO4-- 0.2548762E-04 0.2550823E-04 0.2450084E+01 13.1485 5 HCO3- 0.1200548E-04 0.1307188E-04 0.7975194E+00 3.9657 6 HS- 0.5317273E-13 -.9123028E-10 -.3016826E-05 -4.3881 7 Al+++ 0.1385493E-23 0.2526337E-04 0.6815665E+00 2.7009 8 H4SiO4 0.4300220E-03 0.8011173E-03 0.7699100E+02 -3.3665 9 Ca++ 0.1037668E-06 0.1112104E-06 0.4456584E-02 10.7580 10 Mg++ 0.6627035E-09 0.8555582E-09 0.2079798E-04 8.5631 11 Fe++ 0.3919505E-11 0.2604946E-08 0.1454619E-03 6.3350 12 K+ 0.6163748E-04 0.6167823E-04 0.2411469E+01 4.6762 13 Na+ 0.1056925E-02 0.1062744E-02 0.2442951E+02 5.9103 14 Mn++ 0.5236470E-09 0.1989975E-08 0.1093129E-03 8.4609 15 HPO4-- 0.9652991E-06 0.9842646E-06 0.9445804E-01 11.7269 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1189253E-01 -.9962516E-03 -.1089628E-01 0.0000000E+00 2 H2O 0.5549924E+02 0.5550046E+02 -.1223476E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4543041E-04 0.2550456E-04 0.1992585E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1992594E-04 -.9121714E-10 -.1992585E-04 0.0000000E+00 7 Al+++ 0.2344473E-02 0.2525974E-04 0.2319213E-02 0.0000000E+00 8 H4SiO4 0.7486791E-02 0.8010020E-03 0.6685789E-02 0.0000000E+00 9 Ca++ 0.8414236E-03 0.1111943E-06 0.8413124E-03 0.0000000E+00 10 Mg++ 0.5706349E-03 0.8554350E-09 0.5706341E-03 0.0000000E+00 11 Fe++ 0.5126532E-03 0.2604571E-08 0.5126506E-03 0.0000000E+00 12 K+ 0.1526539E-03 0.6166935E-04 0.9098458E-04 0.0000000E+00 13 Na+ 0.1062591E-02 0.1062591E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1246645E-04 0.1989689E-08 0.1246446E-04 0.0000000E+00 15 HPO4-- 0.4254738E-05 0.9841229E-06 0.3270615E-05 0.0000000E+00 Chg. balance for solid moles: 0.8030E-18 Mass of aqueous solution: 0.999969E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.7190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1090E-05 -5.962 0.5476E-03 -3.262 0.7261E-01 0.1740E-03 clinochlore 0.1141E-03 -3.943 0.6344E-01 -1.198 8.411 0.2413E-01 daphnite 0.7065E-04 -4.151 0.5041E-01 -1.297 6.684 0.1528E-01 chlorite-Mn 0.2493E-05 -5.603 0.1767E-02 -2.753 0.2343 0.5632E-03 hematite 0.7970E-04 -4.099 0.1273E-01 -1.895 1.688 0.2413E-02 muscovite 0.9098E-04 -4.041 0.3624E-01 -1.441 4.805 0.1281E-01 stilbite 0.8359E-03 -3.078 0.5890 -0.230 78.10 0.2747 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.754176 g Volume = 0.330111 cm3 Porosity: 74.3623% V(tot) - V(min): 0.95749E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.7190000 g log = -0.1433 Original solution: 1000.0103000 g Original solution / Rock added: 1390.83 (Water/Rock Ratio), log = 3.1433 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3000E-05 1.0073 0.3179E-05 0.3156E-05 CH4,gas 0.3912E-16 1.0129 0.4168E-16 0.4115E-16 H2,gas 0.5799E-06 1.0006 0.6104E-06 0.6100E-06 H2S,gas 0.5103E-14 0.9959 0.5346E-14 0.5368E-14 S2,gas 0.2732E-35 1.0000 0.2874E-35 0.2874E-35 CO,gas 0.4778E-15 1.0000 0.5027E-15 0.5027E-15 SO3,gas 0.1112E-37 1.0000 0.1170E-37 0.1170E-37 SO2,gas 0.2568E-21 1.0000 0.2701E-21 0.2701E-21 HCl,gas 0.4997E-16 1.0000 0.5257E-16 0.5257E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.86 -7.50 -2.499 0.12802E+05 -5.498 3 CH4,gas 4.81 -13.57 -18.38 -4.595 0.31383E+05 -16.380 4 H2,gas 8.29 0.07 -8.21 -4.694 0.14026E+05 -6.214 5 H2S,gas -5.94 -22.21 -16.27 -8.136 0.27784E+05 -14.272 6 S2,gas -7.03 -44.57 -37.54 -5.776 0.64101E+05 -35.542 7 CO,gas 3.51 -13.79 -17.30 -5.323 0.29537E+05 -15.299 8 SO3,gas 17.43 -22.50 -39.93 -9.983 0.68183E+05 -37.932 9 SO2,gas 1.14 -22.43 -23.57 -6.285 0.40243E+05 -21.568 10 HCl,gas 5.48 -12.80 -18.28 -9.140 0.31211E+05 -16.279 11 acmite 7.74 5.48 -2.26 -0.235 0.38611E+04 15 albite-high 0.75 -1.49 -2.24 -0.172 0.38214E+04 16 albite -0.33 -1.49 -1.16 -0.089 0.19807E+04 19 spessartine 24.55 20.68 -3.87 -0.193 0.65995E+04 20 analcite 3.37 1.88 -1.49 -0.166 0.25484E+04 21 andalusite 5.06 2.04 -3.03 -0.303 0.51688E+04 22 andradite 39.09 34.77 -4.32 -0.224 0.73689E+04 26 annite 20.21 16.28 -3.93 -0.218 0.67047E+04 27 phlogopite 27.15 22.97 -4.18 -0.232 0.71369E+04 29 anorthite 12.80 9.43 -3.37 -0.259 0.57559E+04 35 aragonite 0.99 -3.10 -4.09 -1.363 0.69820E+04 36 brucite 12.58 8.56 -4.01 -0.803 0.68529E+04 37 calcite 0.83 -3.10 -3.94 -1.312 0.67207E+04 38 carnegieite-low 9.06 5.24 -3.82 -0.546 0.65224E+04 39 carnegieite-high 10.13 5.24 -4.89 -0.699 0.83493E+04 40 carpholite-Mg 8.65 7.23 -1.42 -0.095 0.24222E+04 41 carpholite-Fe 6.78 5.00 -1.78 -0.119 0.30378E+04 42 celadonite 5.40 2.47 -2.93 -0.172 0.49968E+04 43 celadonite-Fe 3.94 0.25 -3.69 -0.217 0.63021E+04 44 chrysotile 23.94 18.96 -4.98 -0.415 0.85050E+04 50 chloritoid-Mg 13.26 10.60 -2.66 -0.178 0.45469E+04 51 chloritoid-Fe 9.24 8.37 -0.87 -0.058 0.14828E+04 52 chloritoid-Mn 11.46 10.50 -0.97 -0.064 0.16513E+04 54 coesite -2.37 -3.37 -1.00 -0.332 0.17026E+04 59 corundum 8.43 5.40 -3.03 -0.276 0.51766E+04 61 cristobalite -2.55 -3.37 -0.82 -0.272 0.13955E+04 63 cymrite-K 1.73 -2.72 -4.45 -0.371 0.76039E+04 65 diaspore 2.90 2.70 -0.20 -0.033 0.33335E+03 67 diopside 16.22 12.59 -3.63 -0.363 0.61937E+04 68 hedenbergite 14.24 10.36 -3.88 -0.388 0.66325E+04 75 epidote 24.78 23.12 -1.66 -0.080 0.28314E+04 76 clinozoisite 22.92 19.52 -3.40 -0.155 0.58090E+04 77 epidote-Fe 29.94 26.71 -3.22 -0.167 0.55012E+04 78 fayalite 14.08 9.30 -4.78 -0.682 0.81538E+04 83 gibbsite 4.10 2.70 -1.40 -0.200 0.23845E+04 87 greenalite 16.19 12.27 -3.92 -0.327 0.66968E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.88 -2.37 -0.237 0.40515E+04 97 kalsilite 7.62 4.01 -3.61 -0.516 0.61636E+04 98 kaolinite -1.27 -1.33 -0.06 -0.005 0.99315E+02 99 kyanite 4.93 2.04 -2.90 -0.290 0.49456E+04 101 laumontite 2.97 2.69 -0.28 -0.019 0.47958E+03 102 lawsonite 9.68 9.43 -0.25 -0.017 0.42974E+03 103 leucite 4.17 0.64 -3.52 -0.352 0.60165E+04 105 lizardite 23.29 18.96 -4.33 -0.361 0.73953E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20492E+04 108 minnesotaite 10.46 5.54 -4.92 -0.290 0.84035E+04 113 margarite 17.45 14.83 -2.62 -0.105 0.44794E+04 116 microcline -2.43 -2.72 -0.29 -0.022 0.49640E+03 121 paragonite 4.34 3.91 -0.42 -0.025 0.72277E+03 122 nepheline 8.38 5.24 -3.13 -0.448 0.53503E+04 136 prehnite 19.47 16.82 -2.65 -0.156 0.45216E+04 137 prehnite-Fe 22.59 20.42 -2.17 -0.131 0.37063E+04 138 pumpellyite-Fe 46.47 42.67 -3.80 -0.084 0.64855E+04 139 pumpellyite-Mg 49.19 44.90 -4.29 -0.095 0.73314E+04 145 pyroxmangite 7.42 5.09 -2.32 -0.464 0.39642E+04 146 pyrophyllite -6.10 -8.06 -1.97 -0.123 0.33574E+04 147 quartz -2.98 -3.37 -0.38 -0.128 0.65654E+03 151 rhodochrosite -0.96 -5.40 -4.44 -1.480 0.75837E+04 152 rhodonite 7.46 5.09 -2.37 -0.474 0.40434E+04 153 sanidine -1.22 -2.72 -1.50 -0.116 0.25642E+04 155 siderite -2.59 -7.53 -4.94 -1.646 0.84318E+04 156 sillimanite 5.32 2.04 -3.29 -0.329 0.56110E+04 164 stilpnomelane-Fe 13.18 12.48 -0.70 -0.021 0.11891E+04 165 stilpnomelane-Mg 27.60 23.62 -3.97 -0.119 0.67839E+04 168 sudoite 21.22 17.83 -3.39 -0.109 0.57817E+04 171 talc 16.55 12.22 -4.33 -0.255 0.73935E+04 174 tephroite 18.11 13.56 -4.56 -0.651 0.77820E+04 177 topaz-H 4.67 2.04 -2.63 -0.239 0.44947E+04 178 tridymite -2.61 -3.37 -0.75 -0.251 0.12838E+04 187 wairakite 4.06 2.69 -1.36 -0.080 0.23304E+04 188 walstromite 11.53 7.39 -4.14 -0.827 0.70628E+04 189 wollastonite 10.48 7.39 -3.09 -0.618 0.52767E+04 190 pseudo-wollastonite 11.02 7.39 -3.63 -0.726 0.61953E+04 191 zoisite 22.96 19.52 -3.44 -0.157 0.58816E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.29 -2.73 -0.169 0.46569E+04 194 beidellite-H -2.24 -6.06 -3.82 -0.244 0.65242E+04 195 beidellite-K -1.44 -4.52 -3.08 -0.189 0.52657E+04 196 beidellite-Mg -1.71 -4.65 -2.94 -0.182 0.50239E+04 197 beidellite-Na -1.26 -4.11 -2.85 -0.175 0.48743E+04 199 chalcedony -2.79 -3.37 -0.57 -0.191 0.97686E+03 201 montmorillonite-Ca -2.21 -4.35 -2.14 -0.132 0.36552E+04 202 montmorillonite-K -2.16 -4.59 -2.43 -0.149 0.41418E+04 203 montmorillonite-Mg -2.40 -4.72 -2.32 -0.143 0.39532E+04 204 montmorillonite-Na -1.96 -4.18 -2.22 -0.136 0.37885E+04 205 nontronite-Ca 3.28 2.91 -0.37 -0.024 0.63309E+03 206 nontronite-H 2.60 1.13 -1.46 -0.098 0.24962E+04 207 nontronite-K 3.40 2.68 -0.73 -0.047 0.12411E+04 208 nontronite-Mg 3.14 2.55 -0.59 -0.038 0.10117E+04 209 nontronite-Na 3.58 3.08 -0.50 -0.032 0.85136E+03 224 tobermorite 9.84 5.59 -4.24 -1.158 0.72467E+04 233 boehmite 4.43 2.70 -1.73 -0.288 0.29518E+04 235 ferrous-oxide 9.82 6.34 -3.49 -0.872 0.59577E+04 240 silica-amorphous -2.08 -3.37 -1.29 -0.429 0.21971E+04 242 an20ab80 2.08 0.69 -1.38 -0.107 0.23641E+04 243 an25ab75 2.71 1.24 -1.47 -0.113 0.25079E+04 244 an30ab70 3.34 1.79 -1.56 -0.120 0.26600E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.7190000 g New total amount of reactant added: 0.7390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5864E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.7390000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9999E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .8170682E-03 Osmotic coef. = 0.9834 True ionic strength = .1172551E-02 Chg. balance for total moles = -.5864E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12722E-08 -8.8954 0.11954E-08 -8.9225 0.93968E+00 -0.0270 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12957E-03 -3.8875 0.93922E+00 -0.0272 4 SO4-- 0.25487E-04 -4.5937 0.20948E-04 -4.6789 0.82188E+00 -0.0852 5 HCO3- 0.11984E-04 -4.9214 0.11257E-04 -4.9486 0.93933E+00 -0.0272 6 HS- 0.52848E-13 -13.2770 0.49636E-13 -13.3042 0.93923E+00 -0.0272 7 Al+++ 0.12661E-23 -23.8975 0.83178E-24 -24.0800 0.65698E+00 -0.1824 8 H4SiO4 0.43748E-03 -3.3590 0.43748E-03 -3.3590 0.10000E+01 0.0000 9 Ca++ 0.93996E-07 -7.0269 0.77208E-07 -7.1123 0.82140E+00 -0.0854 10 Mg++ 0.63776E-09 -9.1953 0.52366E-09 -9.2809 0.82109E+00 -0.0856 11 Fe++ 0.37720E-11 -11.4234 0.30974E-11 -11.5090 0.82117E+00 -0.0856 12 K+ 0.62916E-04 -4.2012 0.59100E-04 -4.2284 0.93935E+00 -0.0272 13 Na+ 0.10817E-02 -2.9659 0.10159E-02 -2.9931 0.93921E+00 -0.0272 14 Mn++ 0.50394E-09 -9.2976 0.41385E-09 -9.3832 0.82122E+00 -0.0855 15 HPO4-- 0.11122E-05 -5.9538 0.91414E-06 -6.0390 0.82189E+00 -0.0852 16 HSiO3- 0.38016E-03 -3.4200 0.35705E-03 -3.4473 0.93922E+00 -0.0272 17 Ca(HSiO3)+ 0.65752E-09 -9.1821 0.61765E-09 -9.2093 0.93936E+00 -0.0272 18 Mg(HSiO3)+ 0.55501E-11 -11.2557 0.52135E-11 -11.2829 0.93936E+00 -0.0272 19 NaHSiO3,aq 0.57611E-05 -5.2395 0.57611E-05 -5.2395 0.10000E+01 0.0000 20 AlO+ 0.79989E-13 -13.0970 0.75139E-13 -13.1241 0.93936E+00 -0.0272 21 AlOH+2 0.54788E-18 -18.2613 0.44996E-18 -18.3468 0.82129E+00 -0.0855 22 HAlO2,aq 0.12578E-07 -7.9004 0.12578E-07 -7.9004 0.10000E+01 0.0000 23 AlO2- 0.25017E-04 -4.6018 0.23493E-04 -4.6291 0.93908E+00 -0.0273 24 CH4,aq 0.26181E-19 -19.5820 0.26174E-19 -19.5821 0.99975E+00 -0.0001 29 CO,aq 0.31226E-18 -18.5055 0.31226E-18 -18.5055 0.10000E+01 0.0000 30 CO2,aq 0.27140E-07 -7.5664 0.27133E-07 -7.5665 0.99975E+00 -0.0001 31 CO3-2 0.10595E-05 -5.9749 0.87067E-06 -6.0601 0.82174E+00 -0.0853 32 CaCO3,aq 0.82332E-09 -9.0844 0.82332E-09 -9.0844 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.23314E-10 -10.6324 0.21900E-10 -10.6596 0.93936E+00 -0.0272 34 CaCl+ 0.16970E-10 -10.7703 0.15941E-10 -10.7975 0.93936E+00 -0.0272 35 CaCl2,aq 0.48089E-15 -15.3180 0.48089E-15 -15.3180 0.10000E+01 0.0000 36 CaOH+ 0.48480E-08 -8.3144 0.45541E-08 -8.3416 0.93936E+00 -0.0272 37 CaSO4,aq 0.50392E-09 -9.2976 0.50392E-09 -9.2976 0.10000E+01 0.0000 38 HCl,aq 0.29134E-13 -13.5356 0.29134E-13 -13.5356 0.10000E+01 0.0000 43 FeCl+ 0.66541E-15 -15.1769 0.62507E-15 -15.2041 0.93936E+00 -0.0272 46 FeO,aq 0.85709E-10 -10.0670 0.85709E-10 -10.0670 0.10000E+01 0.0000 47 FeOH+ 0.91444E-10 -10.0388 0.85899E-10 -10.0660 0.93936E+00 -0.0272 48 HFeO2- 0.82107E-09 -9.0856 0.77116E-09 -9.1129 0.93922E+00 -0.0272 49 FeO+ 0.10527E-13 -13.9777 0.98889E-14 -14.0049 0.93936E+00 -0.0272 51 FeO2- 0.14480E-08 -8.8392 0.13600E-08 -8.8665 0.93922E+00 -0.0272 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44695E-09 -9.3497 0.44683E-09 -9.3499 0.99975E+00 -0.0001 54 KCl,aq 0.13559E-09 -9.8678 0.13559E-09 -9.8678 0.10000E+01 0.0000 55 KHSO4,aq 0.39604E-17 -17.4023 0.39604E-17 -17.4023 0.10000E+01 0.0000 56 KOH,aq 0.21552E-07 -7.6665 0.21552E-07 -7.6665 0.10000E+01 0.0000 57 KSO4- 0.20308E-07 -7.6923 0.19073E-07 -7.7196 0.93922E+00 -0.0272 58 MgCO3,aq 0.13954E-11 -11.8553 0.13954E-11 -11.8553 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16125E-12 -12.7925 0.15147E-12 -12.8197 0.93936E+00 -0.0272 60 MgCl+ 0.10449E-12 -12.9809 0.98151E-13 -13.0081 0.93936E+00 -0.0272 61 MgOH+ 0.18217E-09 -9.7395 0.17112E-09 -9.7667 0.93936E+00 -0.0272 63 MnO,aq 0.30570E-09 -9.5147 0.30570E-09 -9.5147 0.10000E+01 0.0000 64 MnOH+ 0.11350E-08 -8.9450 0.10662E-08 -8.9722 0.93936E+00 -0.0272 65 MnO2-2 0.90027E-14 -14.0456 0.73979E-14 -14.1309 0.82174E+00 -0.0853 66 HMnO2- 0.20401E-11 -11.6903 0.19161E-11 -11.7176 0.93922E+00 -0.0272 69 MnCl+ 0.34548E-12 -12.4616 0.32453E-12 -12.4887 0.93936E+00 -0.0272 70 MnSO4,aq 0.24569E-11 -11.6096 0.24569E-11 -11.6096 0.10000E+01 0.0000 71 NaCl,aq 0.42980E-07 -7.3667 0.42980E-07 -7.3667 0.10000E+01 0.0000 72 NaOH,aq 0.37342E-06 -6.4278 0.37342E-06 -6.4278 0.10000E+01 0.0000 74 OH- 0.53432E-03 -3.2722 0.50177E-03 -3.2995 0.93908E+00 -0.0273 79 HPO3-2 0.15700E-17 -17.8041 0.12902E-17 -17.8894 0.82174E+00 -0.0853 82 H3PO4,aq 0.84105E-14 -14.0752 0.84105E-14 -14.0752 0.10000E+01 0.0000 83 H2PO4- 0.20398E-07 -7.6904 0.19159E-07 -7.7176 0.93929E+00 -0.0272 84 PO4-3 0.10124E-08 -8.9947 0.66781E-09 -9.1753 0.65963E+00 -0.1807 87 H2P2O7-2 0.34961E-16 -16.4564 0.28729E-16 -16.5417 0.82174E+00 -0.0853 88 HP2O7-3 0.75004E-14 -14.1249 0.49278E-14 -14.3073 0.65701E+00 -0.1824 89 P2O7-4 0.21118E-14 -14.6753 0.10169E-14 -14.9927 0.48155E+00 -0.3174 90 H2S,aq 0.17833E-15 -15.7488 0.17828E-15 -15.7489 0.99975E+00 -0.0001 97 SO3-2 0.15513E-14 -14.8093 0.12763E-14 -14.8941 0.82272E+00 -0.0847 98 HSO3- 0.95064E-16 -16.0220 0.89286E-16 -16.0492 0.93922E+00 -0.0272 99 HSO4- 0.24733E-10 -10.6067 0.23235E-10 -10.6339 0.93943E+00 -0.0271 Charge balance for all species = -.5864E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1272185E-08 -.1021766E-02 -.1029760E+01 0.0000 2 H2O 0.1000000E+01 0.5550845E+02 0.9998855E+06 0.0000 3 Cl- 0.1379514E-03 0.1379946E-03 0.4891755E+01 5.0350 4 SO4-- 0.2548740E-04 0.2550834E-04 0.2450088E+01 13.1661 5 HCO3- 0.1198440E-04 0.1307193E-04 0.7975203E+00 3.9739 6 HS- 0.5284769E-13 -.9464767E-10 -.3129825E-05 -4.3817 7 Al+++ 0.1266066E-23 0.2502975E-04 0.6752619E+00 2.6874 8 H4SiO4 0.4374784E-03 0.8233973E-03 0.7913199E+02 -3.3590 9 Ca++ 0.9399554E-07 0.1008686E-06 0.4042144E-02 10.7326 10 Mg++ 0.6377642E-09 0.8271433E-09 0.2010718E-04 8.5640 11 Fe++ 0.3771996E-11 0.2653503E-08 0.1481730E-03 6.3359 12 K+ 0.6291613E-04 0.6295813E-04 0.2461503E+01 4.6941 13 Na+ 0.1081679E-02 0.1087857E-02 0.2500671E+02 5.9293 14 Mn++ 0.5039428E-09 0.1949492E-08 0.1070888E-03 8.4618 15 HPO4-- 0.1112239E-05 0.1133649E-05 0.1087939E+00 11.8060 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1222370E-01 -.1021615E-02 -.1120209E-01 0.0000000E+00 2 H2O 0.5549899E+02 0.5550024E+02 -.1256992E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4598468E-04 0.2550456E-04 0.2048011E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2048021E-04 -.9463368E-10 -.2048011E-04 0.0000000E+00 7 Al+++ 0.2409688E-02 0.2502605E-04 0.2384662E-02 0.0000000E+00 8 H4SiO4 0.7695047E-02 0.8232756E-03 0.6871771E-02 0.0000000E+00 9 Ca++ 0.8644265E-03 0.1008537E-06 0.8643256E-03 0.0000000E+00 10 Mg++ 0.5865079E-03 0.8270210E-09 0.5865071E-03 0.0000000E+00 11 Fe++ 0.5269134E-03 0.2653111E-08 0.5269107E-03 0.0000000E+00 12 K+ 0.1569002E-03 0.6294882E-04 0.9395139E-04 0.0000000E+00 13 Na+ 0.1087696E-02 0.1087696E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1281322E-04 0.1949203E-08 0.1281127E-04 0.0000000E+00 15 HPO4-- 0.4373089E-05 0.1133482E-05 0.3239607E-05 0.0000000E+00 Chg. balance for solid moles: 0.3608E-18 Mass of aqueous solution: 0.999968E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.7390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1080E-05 -5.967 0.5424E-03 -3.266 0.6998E-01 0.1724E-03 clinochlore 0.1173E-03 -3.931 0.6520E-01 -1.186 8.411 0.2480E-01 daphnite 0.7261E-04 -4.139 0.5181E-01 -1.286 6.684 0.1570E-01 chlorite-Mn 0.2562E-05 -5.591 0.1817E-02 -2.741 0.2343 0.5789E-03 hematite 0.8192E-04 -4.087 0.1308E-01 -1.883 1.688 0.2480E-02 muscovite 0.9395E-04 -4.027 0.3742E-01 -1.427 4.828 0.1323E-01 stilbite 0.8589E-03 -3.066 0.6053 -0.218 78.09 0.2823 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.775176 g Volume = 0.339288 cm3 Porosity: 73.8123% V(tot) - V(min): 0.95631E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.7390000 g log = -0.1314 Original solution: 1000.0103000 g Original solution / Rock added: 1353.19 (Water/Rock Ratio), log = 3.1314 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2931E-05 1.0073 0.3106E-05 0.3083E-05 CH4,gas 0.3885E-16 1.0129 0.4139E-16 0.4086E-16 H2,gas 0.5823E-06 1.0006 0.6129E-06 0.6125E-06 H2S,gas 0.4963E-14 0.9959 0.5200E-14 0.5221E-14 S2,gas 0.2563E-35 1.0000 0.2696E-35 0.2696E-35 CO,gas 0.4687E-15 1.0000 0.4931E-15 0.4931E-15 SO3,gas 0.1064E-37 1.0000 0.1119E-37 0.1119E-37 SO2,gas 0.2467E-21 1.0000 0.2595E-21 0.2595E-21 HCl,gas 0.4890E-16 1.0000 0.5144E-16 0.5144E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 120 muscovite 2.68 2.68 0.00 0.000 0.30331E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.87 -7.51 -2.503 0.12819E+05 -5.508 3 CH4,gas 4.81 -13.57 -18.38 -4.596 0.31389E+05 -16.383 4 H2,gas 8.29 0.07 -8.21 -4.693 0.14023E+05 -6.213 5 H2S,gas -5.94 -22.23 -16.28 -8.142 0.27805E+05 -14.284 6 S2,gas -7.03 -44.60 -37.57 -5.780 0.64148E+05 -35.569 7 CO,gas 3.51 -13.80 -17.31 -5.325 0.29551E+05 -15.307 8 SO3,gas 17.43 -22.52 -39.95 -9.988 0.68215E+05 -37.951 9 SO2,gas 1.14 -22.45 -23.59 -6.290 0.40272E+05 -21.586 10 HCl,gas 5.48 -12.81 -18.29 -9.144 0.31227E+05 -16.289 11 acmite 7.74 5.51 -2.23 -0.231 0.38031E+04 15 albite-high 0.75 -1.46 -2.21 -0.170 0.37735E+04 16 albite -0.33 -1.46 -1.13 -0.087 0.19329E+04 19 spessartine 24.55 20.68 -3.87 -0.193 0.66025E+04 20 analcite 3.37 1.90 -1.47 -0.164 0.25134E+04 21 andalusite 5.06 2.02 -3.05 -0.305 0.52019E+04 22 andradite 39.09 34.72 -4.37 -0.227 0.74607E+04 26 annite 20.21 16.31 -3.90 -0.217 0.66543E+04 27 phlogopite 27.15 23.00 -4.15 -0.231 0.70865E+04 29 anorthite 12.80 9.39 -3.41 -0.262 0.58196E+04 35 aragonite 0.99 -3.14 -4.12 -1.375 0.70427E+04 36 brucite 12.58 8.56 -4.01 -0.803 0.68514E+04 37 calcite 0.83 -3.14 -3.97 -1.324 0.67814E+04 38 carnegieite-low 9.06 5.26 -3.81 -0.544 0.65001E+04 39 carnegieite-high 10.13 5.26 -4.88 -0.697 0.83269E+04 40 carpholite-Mg 8.65 7.22 -1.43 -0.095 0.24410E+04 41 carpholite-Fe 6.78 4.99 -1.79 -0.119 0.30567E+04 42 celadonite 5.40 2.51 -2.89 -0.170 0.49367E+04 43 celadonite-Fe 3.94 0.28 -3.66 -0.215 0.62420E+04 44 chrysotile 23.94 18.97 -4.96 -0.414 0.84749E+04 50 chloritoid-Mg 13.26 10.58 -2.68 -0.179 0.45785E+04 51 chloritoid-Fe 9.24 8.35 -0.89 -0.059 0.15144E+04 52 chloritoid-Mn 11.46 10.48 -0.99 -0.066 0.16829E+04 54 coesite -2.37 -3.36 -0.99 -0.330 0.16899E+04 59 corundum 8.43 5.37 -3.06 -0.278 0.52224E+04 61 cristobalite -2.55 -3.36 -0.81 -0.270 0.13828E+04 63 cymrite-K 1.73 -2.70 -4.43 -0.369 0.75580E+04 65 diaspore 2.90 2.69 -0.21 -0.035 0.35629E+03 67 diopside 16.22 12.58 -3.64 -0.364 0.62100E+04 68 hedenbergite 14.24 10.35 -3.89 -0.389 0.66488E+04 75 epidote 24.78 23.06 -1.71 -0.083 0.29257E+04 76 clinozoisite 22.92 19.45 -3.47 -0.158 0.59263E+04 77 epidote-Fe 29.94 26.67 -3.26 -0.170 0.55726E+04 78 fayalite 14.08 9.31 -4.77 -0.681 0.81380E+04 83 gibbsite 4.10 2.69 -1.41 -0.201 0.24075E+04 87 greenalite 16.19 12.29 -3.90 -0.325 0.66668E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.90 -2.35 -0.235 0.40164E+04 97 kalsilite 7.62 4.02 -3.60 -0.514 0.61432E+04 98 kaolinite -1.27 -1.34 -0.07 -0.006 0.11969E+03 99 kyanite 4.93 2.02 -2.92 -0.292 0.49787E+04 101 laumontite 2.97 2.67 -0.30 -0.020 0.51782E+03 102 lawsonite 9.68 9.39 -0.29 -0.019 0.49348E+03 103 leucite 4.17 0.66 -3.50 -0.350 0.59834E+04 105 lizardite 23.29 18.97 -4.31 -0.359 0.73652E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20476E+04 108 minnesotaite 10.46 5.57 -4.89 -0.288 0.83479E+04 113 margarite 17.45 14.76 -2.69 -0.108 0.45890E+04 116 microcline -2.43 -2.70 -0.26 -0.020 0.45053E+03 121 paragonite 4.34 3.91 -0.42 -0.025 0.72083E+03 122 nepheline 8.38 5.26 -3.12 -0.446 0.53280E+04 136 prehnite 19.47 16.76 -2.70 -0.159 0.46160E+04 137 prehnite-Fe 22.59 20.37 -2.21 -0.133 0.37777E+04 138 pumpellyite-Fe 46.47 42.55 -3.92 -0.087 0.66956E+04 139 pumpellyite-Mg 49.19 44.78 -4.42 -0.098 0.75415E+04 145 pyroxmangite 7.42 5.10 -2.31 -0.463 0.39499E+04 146 pyrophyllite -6.10 -8.06 -1.96 -0.123 0.33523E+04 147 quartz -2.98 -3.36 -0.38 -0.126 0.64379E+03 151 rhodochrosite -0.96 -5.41 -4.45 -1.484 0.75995E+04 152 rhodonite 7.46 5.10 -2.36 -0.472 0.40291E+04 153 sanidine -1.22 -2.70 -1.47 -0.113 0.25183E+04 155 siderite -2.59 -7.54 -4.95 -1.649 0.84476E+04 156 sillimanite 5.32 2.02 -3.31 -0.331 0.56441E+04 164 stilpnomelane-Fe 13.18 12.53 -0.65 -0.019 0.11100E+04 165 stilpnomelane-Mg 27.60 23.67 -3.93 -0.117 0.67049E+04 168 sudoite 21.22 17.80 -3.42 -0.110 0.58321E+04 171 talc 16.55 12.26 -4.30 -0.253 0.73380E+04 174 tephroite 18.11 13.56 -4.55 -0.650 0.77662E+04 177 topaz-H 4.67 2.02 -2.65 -0.241 0.45278E+04 178 tridymite -2.61 -3.36 -0.74 -0.248 0.12711E+04 187 wairakite 4.06 2.67 -1.39 -0.082 0.23686E+04 188 walstromite 11.53 7.37 -4.15 -0.831 0.70934E+04 189 wollastonite 10.48 7.37 -3.11 -0.622 0.53073E+04 190 pseudo-wollastonite 11.02 7.37 -3.65 -0.729 0.62259E+04 191 zoisite 22.96 19.45 -3.51 -0.160 0.59988E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.30 -2.74 -0.169 0.46707E+04 194 beidellite-H -2.24 -6.07 -3.82 -0.244 0.65309E+04 195 beidellite-K -1.44 -4.52 -3.08 -0.189 0.52623E+04 196 beidellite-Mg -1.71 -4.65 -2.95 -0.182 0.50303E+04 197 beidellite-Na -1.26 -4.11 -2.85 -0.175 0.48702E+04 199 chalcedony -2.79 -3.36 -0.56 -0.188 0.96411E+03 201 montmorillonite-Ca -2.21 -4.35 -2.14 -0.132 0.36491E+04 202 montmorillonite-K -2.16 -4.57 -2.41 -0.148 0.41185E+04 203 montmorillonite-Mg -2.40 -4.71 -2.31 -0.143 0.39398E+04 204 montmorillonite-Na -1.96 -4.17 -2.20 -0.135 0.37646E+04 205 nontronite-Ca 3.28 2.93 -0.35 -0.023 0.60102E+03 206 nontronite-H 2.60 1.16 -1.44 -0.096 0.24570E+04 207 nontronite-K 3.40 2.71 -0.70 -0.045 0.11918E+04 208 nontronite-Mg 3.14 2.57 -0.57 -0.037 0.97226E+03 209 nontronite-Na 3.58 3.11 -0.47 -0.030 0.80142E+03 224 tobermorite 9.84 5.58 -4.26 -1.162 0.72701E+04 233 boehmite 4.43 2.69 -1.74 -0.290 0.29747E+04 235 ferrous-oxide 9.82 6.34 -3.49 -0.872 0.59561E+04 240 silica-amorphous -2.08 -3.36 -1.28 -0.426 0.21843E+04 242 an20ab80 2.08 0.71 -1.37 -0.105 0.23386E+04 243 an25ab75 2.71 1.25 -1.46 -0.112 0.24880E+04 244 an30ab70 3.34 1.79 -1.55 -0.119 0.26456E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.7390000 g New total amount of reactant added: 0.7590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5863E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.7590000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .8295776E-03 Osmotic coef. = 0.9833 True ionic strength = .1198750E-02 Chg. balance for total moles = -.5863E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12469E-08 -8.9042 0.11711E-08 -8.9314 0.93924E+00 -0.0272 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12950E-03 -3.8877 0.93877E+00 -0.0274 4 SO4-- 0.25487E-04 -4.5937 0.20908E-04 -4.6797 0.82034E+00 -0.0860 5 HCO3- 0.11963E-04 -4.9221 0.11232E-04 -4.9495 0.93888E+00 -0.0274 6 HS- 0.52574E-13 -13.2792 0.49356E-13 -13.3067 0.93878E+00 -0.0274 7 Al+++ 0.11601E-23 -23.9355 0.75892E-24 -24.1198 0.65420E+00 -0.1843 8 H4SiO4 0.44476E-03 -3.3519 0.44476E-03 -3.3519 0.10000E+01 0.0000 9 Ca++ 0.85498E-07 -7.0680 0.70095E-07 -7.1543 0.81985E+00 -0.0863 10 Mg++ 0.61453E-09 -9.2115 0.50363E-09 -9.2979 0.81954E+00 -0.0864 11 Fe++ 0.36346E-11 -11.4395 0.29789E-11 -11.5259 0.81961E+00 -0.0864 12 K+ 0.64213E-04 -4.1924 0.60290E-04 -4.2198 0.93890E+00 -0.0274 13 Na+ 0.11064E-02 -2.9561 0.10387E-02 -2.9835 0.93876E+00 -0.0274 14 Mn++ 0.48558E-09 -9.3137 0.39802E-09 -9.4001 0.81967E+00 -0.0864 15 HPO4-- 0.12737E-05 -5.8949 0.10449E-05 -5.9809 0.82035E+00 -0.0860 16 HSiO3- 0.39470E-03 -3.4037 0.37053E-03 -3.4312 0.93877E+00 -0.0274 17 Ca(HSiO3)+ 0.61977E-09 -9.2078 0.58192E-09 -9.2351 0.93892E+00 -0.0274 18 Mg(HSiO3)+ 0.55419E-11 -11.2563 0.52034E-11 -11.2837 0.93892E+00 -0.0274 19 NaHSiO3,aq 0.61125E-05 -5.2138 0.61125E-05 -5.2138 0.10000E+01 0.0000 20 AlO+ 0.76081E-13 -13.1187 0.71434E-13 -13.1461 0.93892E+00 -0.0274 21 AlOH+2 0.51123E-18 -18.2914 0.41908E-18 -18.3777 0.81973E+00 -0.0863 22 HAlO2,aq 0.12206E-07 -7.9134 0.12206E-07 -7.9134 0.10000E+01 0.0000 23 AlO2- 0.24794E-04 -4.6057 0.23272E-04 -4.6332 0.93863E+00 -0.0275 24 CH4,aq 0.26025E-19 -19.5846 0.26018E-19 -19.5847 0.99974E+00 -0.0001 29 CO,aq 0.30651E-18 -18.5136 0.30651E-18 -18.5136 0.10000E+01 0.0000 30 CO2,aq 0.26529E-07 -7.5763 0.26522E-07 -7.5764 0.99974E+00 -0.0001 31 CO3-2 0.10812E-05 -5.9661 0.88678E-06 -6.0522 0.82020E+00 -0.0861 32 CaCO3,aq 0.76130E-09 -9.1184 0.76130E-09 -9.1184 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.21129E-10 -10.6751 0.19838E-10 -10.7025 0.93892E+00 -0.0274 34 CaCl+ 0.15406E-10 -10.8123 0.14465E-10 -10.8397 0.93892E+00 -0.0274 35 CaCl2,aq 0.43617E-15 -15.3603 0.43617E-15 -15.3603 0.10000E+01 0.0000 36 CaOH+ 0.44949E-08 -8.3473 0.42204E-08 -8.3746 0.93892E+00 -0.0274 37 CaSO4,aq 0.45664E-09 -9.3404 0.45664E-09 -9.3404 0.10000E+01 0.0000 38 HCl,aq 0.28528E-13 -13.5447 0.28528E-13 -13.5447 0.10000E+01 0.0000 43 FeCl+ 0.63995E-15 -15.1939 0.60086E-15 -15.2212 0.93892E+00 -0.0274 46 FeO,aq 0.85889E-10 -10.0661 0.85889E-10 -10.0661 0.10000E+01 0.0000 47 FeOH+ 0.89814E-10 -10.0467 0.84328E-10 -10.0740 0.93892E+00 -0.0274 48 HFeO2- 0.84029E-09 -9.0756 0.78883E-09 -9.1030 0.93877E+00 -0.0274 49 FeO+ 0.10318E-13 -13.9864 0.96877E-14 -14.0138 0.93892E+00 -0.0274 51 FeO2- 0.14788E-08 -8.8301 0.13883E-08 -8.8575 0.93877E+00 -0.0274 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44883E-09 -9.3479 0.44871E-09 -9.3480 0.99974E+00 -0.0001 54 KCl,aq 0.13825E-09 -9.8593 0.13825E-09 -9.8593 0.10000E+01 0.0000 55 KHSO4,aq 0.39505E-17 -17.4034 0.39505E-17 -17.4034 0.10000E+01 0.0000 56 KOH,aq 0.22443E-07 -7.6489 0.22443E-07 -7.6489 0.10000E+01 0.0000 57 KSO4- 0.20687E-07 -7.6843 0.19421E-07 -7.7117 0.93877E+00 -0.0274 58 MgCO3,aq 0.13668E-11 -11.8643 0.13668E-11 -11.8643 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15480E-12 -12.8102 0.14535E-12 -12.8376 0.93892E+00 -0.0274 60 MgCl+ 0.10049E-12 -12.9979 0.94350E-13 -13.0253 0.93892E+00 -0.0274 61 MgOH+ 0.17892E-09 -9.7473 0.16799E-09 -9.7747 0.93892E+00 -0.0274 63 MnO,aq 0.30635E-09 -9.5138 0.30635E-09 -9.5138 0.10000E+01 0.0000 64 MnOH+ 0.11148E-08 -8.9528 0.10467E-08 -8.9802 0.93892E+00 -0.0274 65 MnO2-2 0.94180E-14 -14.0260 0.77246E-14 -14.1121 0.82020E+00 -0.0861 66 HMnO2- 0.20879E-11 -11.6803 0.19600E-11 -11.7077 0.93877E+00 -0.0274 69 MnCl+ 0.33226E-12 -12.4785 0.31196E-12 -12.5059 0.93892E+00 -0.0274 70 MnSO4,aq 0.23584E-11 -11.6274 0.23584E-11 -11.6274 0.10000E+01 0.0000 71 NaCl,aq 0.43921E-07 -7.3573 0.43921E-07 -7.3573 0.10000E+01 0.0000 72 NaOH,aq 0.38971E-06 -6.4093 0.38971E-06 -6.4093 0.10000E+01 0.0000 74 OH- 0.54568E-03 -3.2631 0.51219E-03 -3.2906 0.93863E+00 -0.0275 79 HPO3-2 0.18055E-17 -17.7434 0.14809E-17 -17.8295 0.82020E+00 -0.0861 82 H3PO4,aq 0.92262E-14 -14.0350 0.92262E-14 -14.0350 0.10000E+01 0.0000 83 H2PO4- 0.22851E-07 -7.6411 0.21454E-07 -7.6685 0.93884E+00 -0.0274 84 PO4-3 0.11861E-08 -8.9259 0.77917E-09 -9.1084 0.65689E+00 -0.1825 87 H2P2O7-2 0.43919E-16 -16.3573 0.36022E-16 -16.4434 0.82020E+00 -0.0861 88 HP2O7-3 0.96407E-14 -14.0159 0.63072E-14 -14.2002 0.65422E+00 -0.1843 89 P2O7-4 0.27798E-14 -14.5560 0.13286E-14 -14.8766 0.47795E+00 -0.3206 90 H2S,aq 0.17371E-15 -15.7602 0.17367E-15 -15.7603 0.99974E+00 -0.0001 97 SO3-2 0.15577E-14 -14.8075 0.12792E-14 -14.8931 0.82119E+00 -0.0856 98 HSO3- 0.93390E-16 -16.0297 0.87671E-16 -16.0571 0.93877E+00 -0.0274 99 HSO4- 0.24196E-10 -10.6163 0.22720E-10 -10.6436 0.93899E+00 -0.0273 Charge balance for all species = -.5872E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1246881E-08 -.1047160E-02 -.1055349E+01 0.0000 2 H2O 0.1000000E+01 0.5550845E+02 0.9998828E+06 0.0000 3 Cl- 0.1379510E-03 0.1379951E-03 0.4891761E+01 5.0437 4 SO4-- 0.2548717E-04 0.2550844E-04 0.2450091E+01 13.1831 5 HCO3- 0.1196348E-04 0.1307198E-04 0.7975212E+00 3.9819 6 HS- 0.5257432E-13 -.9802473E-10 -.3241490E-05 -4.3753 7 Al+++ 0.1160083E-23 0.2480597E-04 0.6692229E+00 2.6744 8 H4SiO4 0.4447597E-03 0.8455714E-03 0.8126280E+02 -3.3519 9 Ca++ 0.8549768E-07 0.9186688E-07 0.3681404E-02 10.7085 10 Mg++ 0.6145274E-09 0.8006122E-09 0.1946218E-04 8.5649 11 Fe++ 0.3634558E-11 0.2701904E-08 0.1508753E-03 6.3369 12 K+ 0.6421350E-04 0.6425676E-04 0.2512270E+01 4.7116 13 Na+ 0.1106424E-02 0.1112970E-02 0.2558392E+02 5.9479 14 Mn++ 0.4855835E-09 0.1911489E-08 0.1050009E-03 8.4627 15 HPO4-- 0.1273702E-05 0.1297740E-05 0.1245410E+00 11.8819 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1255487E-01 -.1047001E-02 -.1150787E-01 0.0000000E+00 2 H2O 0.5549874E+02 0.5550003E+02 -.1290582E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4653895E-04 0.2550457E-04 0.2103438E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2103448E-04 -.9800987E-10 -.2103438E-04 0.0000000E+00 7 Al+++ 0.2474903E-02 0.2480220E-04 0.2450101E-02 0.0000000E+00 8 H4SiO4 0.7903302E-02 0.8454432E-03 0.7057859E-02 0.0000000E+00 9 Ca++ 0.8874293E-03 0.9185294E-07 0.8873375E-03 0.0000000E+00 10 Mg++ 0.6023810E-03 0.8004908E-09 0.6023802E-03 0.0000000E+00 11 Fe++ 0.5411735E-03 0.2701494E-08 0.5411708E-03 0.0000000E+00 12 K+ 0.1611465E-03 0.6424702E-04 0.9689948E-04 0.0000000E+00 13 Na+ 0.1112801E-02 0.1112801E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1315999E-04 0.1911199E-08 0.1315808E-04 0.0000000E+00 15 HPO4-- 0.4491441E-05 0.1297543E-05 0.3193898E-05 0.0000000E+00 Chg. balance for solid moles: 0.9250E-18 Mass of aqueous solution: 0.999967E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.7590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1065E-05 -5.973 0.5348E-03 -3.272 0.6717E-01 0.1699E-03 clinochlore 0.1205E-03 -3.919 0.6696E-01 -1.174 8.411 0.2547E-01 daphnite 0.7458E-04 -4.127 0.5321E-01 -1.274 6.684 0.1613E-01 chlorite-Mn 0.2632E-05 -5.580 0.1866E-02 -2.729 0.2343 0.5946E-03 hematite 0.8414E-04 -4.075 0.1344E-01 -1.872 1.688 0.2547E-02 muscovite 0.9690E-04 -4.014 0.3860E-01 -1.413 4.848 0.1365E-01 stilbite 0.8820E-03 -3.055 0.6216 -0.207 78.07 0.2899 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.796184 g Volume = 0.348468 cm3 Porosity: 73.2688% V(tot) - V(min): 0.95513E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.7590000 g log = -0.1198 Original solution: 1000.0103000 g Original solution / Rock added: 1317.54 (Water/Rock Ratio), log = 3.1198 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2865E-05 1.0073 0.3036E-05 0.3014E-05 CH4,gas 0.3861E-16 1.0129 0.4114E-16 0.4062E-16 H2,gas 0.5847E-06 1.0006 0.6154E-06 0.6151E-06 H2S,gas 0.4835E-14 0.9959 0.5065E-14 0.5086E-14 S2,gas 0.2412E-35 1.0000 0.2537E-35 0.2537E-35 CO,gas 0.4601E-15 1.0000 0.4840E-15 0.4840E-15 SO3,gas 0.1019E-37 1.0000 0.1072E-37 0.1072E-37 SO2,gas 0.2373E-21 1.0000 0.2496E-21 0.2496E-21 HCl,gas 0.4788E-16 1.0000 0.5037E-16 0.5037E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.88 -7.52 -2.506 0.12836E+05 -5.518 3 CH4,gas 4.81 -13.58 -18.39 -4.596 0.31393E+05 -16.386 4 H2,gas 8.29 0.08 -8.21 -4.692 0.14020E+05 -6.211 5 H2S,gas -5.94 -22.24 -16.30 -8.148 0.27824E+05 -14.295 6 S2,gas -7.03 -44.63 -37.60 -5.784 0.64194E+05 -35.596 7 CO,gas 3.51 -13.80 -17.32 -5.328 0.29565E+05 -15.315 8 SO3,gas 17.43 -22.54 -39.97 -9.992 0.68247E+05 -37.970 9 SO2,gas 1.14 -22.47 -23.60 -6.294 0.40301E+05 -21.603 10 HCl,gas 5.48 -12.82 -18.30 -9.149 0.31243E+05 -16.298 11 acmite 7.74 5.54 -2.19 -0.228 0.37470E+04 15 albite-high 0.75 -1.43 -2.18 -0.168 0.37274E+04 16 albite -0.33 -1.43 -1.10 -0.085 0.18868E+04 19 spessartine 24.55 20.68 -3.87 -0.193 0.66056E+04 20 analcite 3.37 1.92 -1.45 -0.161 0.24795E+04 21 andalusite 5.06 2.00 -3.07 -0.307 0.52342E+04 22 andradite 39.09 34.67 -4.42 -0.230 0.75475E+04 26 annite 20.21 16.34 -3.87 -0.215 0.66051E+04 27 phlogopite 27.15 23.03 -4.12 -0.229 0.70373E+04 29 anorthite 12.80 9.35 -3.44 -0.265 0.58808E+04 35 aragonite 0.99 -3.17 -4.16 -1.386 0.71008E+04 36 brucite 12.58 8.56 -4.01 -0.802 0.68499E+04 37 calcite 0.83 -3.17 -4.01 -1.335 0.68395E+04 38 carnegieite-low 9.06 5.27 -3.79 -0.542 0.64784E+04 39 carnegieite-high 10.13 5.27 -4.86 -0.695 0.83053E+04 40 carpholite-Mg 8.65 7.21 -1.44 -0.096 0.24595E+04 41 carpholite-Fe 6.78 4.98 -1.80 -0.120 0.30752E+04 42 celadonite 5.40 2.54 -2.86 -0.168 0.48784E+04 43 celadonite-Fe 3.94 0.32 -3.62 -0.213 0.61837E+04 44 chrysotile 23.94 18.99 -4.95 -0.412 0.84458E+04 50 chloritoid-Mg 13.26 10.56 -2.70 -0.180 0.46092E+04 51 chloritoid-Fe 9.24 8.33 -0.90 -0.060 0.15451E+04 52 chloritoid-Mn 11.46 10.46 -1.00 -0.067 0.17136E+04 54 coesite -2.37 -3.35 -0.98 -0.328 0.16776E+04 59 corundum 8.43 5.35 -3.08 -0.280 0.52669E+04 61 cristobalite -2.55 -3.35 -0.80 -0.268 0.13705E+04 63 cymrite-K 1.73 -2.67 -4.40 -0.367 0.75135E+04 65 diaspore 2.90 2.67 -0.22 -0.037 0.37854E+03 67 diopside 16.22 12.57 -3.65 -0.365 0.62252E+04 68 hedenbergite 14.24 10.34 -3.90 -0.390 0.66640E+04 75 epidote 24.78 23.01 -1.77 -0.086 0.30159E+04 76 clinozoisite 22.92 19.38 -3.54 -0.161 0.60387E+04 77 epidote-Fe 29.94 26.63 -3.30 -0.172 0.56405E+04 78 fayalite 14.08 9.32 -4.76 -0.680 0.81227E+04 83 gibbsite 4.10 2.67 -1.42 -0.203 0.24297E+04 87 greenalite 16.19 12.31 -3.89 -0.324 0.66376E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.92 -2.33 -0.233 0.39825E+04 97 kalsilite 7.62 4.03 -3.59 -0.512 0.61232E+04 98 kaolinite -1.27 -1.35 -0.08 -0.007 0.13971E+03 99 kyanite 4.93 2.00 -2.93 -0.293 0.50110E+04 101 laumontite 2.97 2.65 -0.32 -0.022 0.55455E+03 102 lawsonite 9.68 9.35 -0.32 -0.022 0.55468E+03 103 leucite 4.17 0.68 -3.49 -0.349 0.59511E+04 105 lizardite 23.29 18.99 -4.30 -0.358 0.73361E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20461E+04 108 minnesotaite 10.46 5.60 -4.86 -0.286 0.82943E+04 113 margarite 17.45 14.70 -2.75 -0.110 0.46947E+04 116 microcline -2.43 -2.67 -0.24 -0.018 0.40603E+03 121 paragonite 4.34 3.92 -0.42 -0.025 0.71920E+03 122 nepheline 8.38 5.27 -3.11 -0.444 0.53064E+04 136 prehnite 19.47 16.71 -2.76 -0.162 0.47061E+04 137 prehnite-Fe 22.59 20.33 -2.25 -0.135 0.38456E+04 138 pumpellyite-Fe 46.47 42.43 -4.04 -0.090 0.68966E+04 139 pumpellyite-Mg 49.19 44.66 -4.53 -0.101 0.77425E+04 145 pyroxmangite 7.42 5.11 -2.31 -0.461 0.39361E+04 146 pyrophyllite -6.10 -8.06 -1.96 -0.123 0.33478E+04 147 quartz -2.98 -3.35 -0.37 -0.123 0.63155E+03 151 rhodochrosite -0.96 -5.42 -4.46 -1.487 0.76148E+04 152 rhodonite 7.46 5.11 -2.35 -0.470 0.40153E+04 153 sanidine -1.22 -2.67 -1.45 -0.111 0.24738E+04 155 siderite -2.59 -7.54 -4.96 -1.652 0.84629E+04 156 sillimanite 5.32 2.00 -3.32 -0.332 0.56764E+04 164 stilpnomelane-Fe 13.18 12.57 -0.61 -0.018 0.10338E+04 165 stilpnomelane-Mg 27.60 23.71 -3.88 -0.116 0.66286E+04 168 sudoite 21.22 17.77 -3.44 -0.111 0.58813E+04 171 talc 16.55 12.29 -4.27 -0.251 0.72843E+04 174 tephroite 18.11 13.57 -4.54 -0.648 0.77509E+04 177 topaz-H 4.67 2.00 -2.67 -0.243 0.45601E+04 178 tridymite -2.61 -3.35 -0.74 -0.246 0.12588E+04 187 wairakite 4.06 2.65 -1.41 -0.083 0.24054E+04 188 walstromite 11.53 7.36 -4.17 -0.834 0.71223E+04 189 wollastonite 10.48 7.36 -3.13 -0.625 0.53362E+04 190 pseudo-wollastonite 11.02 7.36 -3.66 -0.733 0.62548E+04 191 zoisite 22.96 19.38 -3.58 -0.163 0.61112E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.30 -2.74 -0.170 0.46844E+04 194 beidellite-H -2.24 -6.07 -3.83 -0.244 0.65378E+04 195 beidellite-K -1.44 -4.52 -3.08 -0.189 0.52593E+04 196 beidellite-Mg -1.71 -4.66 -2.95 -0.182 0.50370E+04 197 beidellite-Na -1.26 -4.11 -2.85 -0.175 0.48667E+04 199 chalcedony -2.79 -3.35 -0.56 -0.186 0.95187E+03 201 montmorillonite-Ca -2.21 -4.35 -2.13 -0.132 0.36436E+04 202 montmorillonite-K -2.16 -4.56 -2.40 -0.147 0.40963E+04 203 montmorillonite-Mg -2.40 -4.70 -2.30 -0.142 0.39272E+04 204 montmorillonite-Na -1.96 -4.15 -2.19 -0.134 0.37418E+04 205 nontronite-Ca 3.28 2.95 -0.33 -0.022 0.57024E+03 206 nontronite-H 2.60 1.18 -1.42 -0.095 0.24194E+04 207 nontronite-K 3.40 2.73 -0.67 -0.043 0.11443E+04 208 nontronite-Mg 3.14 2.59 -0.55 -0.036 0.93442E+03 209 nontronite-Na 3.58 3.14 -0.44 -0.028 0.75339E+03 224 tobermorite 9.84 5.57 -4.27 -1.165 0.72921E+04 233 boehmite 4.43 2.67 -1.76 -0.293 0.29970E+04 235 ferrous-oxide 9.82 6.34 -3.49 -0.872 0.59546E+04 240 silica-amorphous -2.08 -3.35 -1.27 -0.424 0.21721E+04 242 an20ab80 2.08 0.72 -1.36 -0.104 0.23140E+04 243 an25ab75 2.71 1.26 -1.45 -0.111 0.24687E+04 244 an30ab70 3.34 1.80 -1.54 -0.119 0.26317E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.7590000 g New total amount of reactant added: 0.7790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5861E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.7790000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .8421716E-03 Osmotic coef. = 0.9831 True ionic strength = .1224976E-02 Chg. balance for total moles = -.5861E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12228E-08 -8.9127 0.11480E-08 -8.9401 0.93881E+00 -0.0274 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12944E-03 -3.8879 0.93833E+00 -0.0276 4 SO4-- 0.25487E-04 -4.5937 0.20869E-04 -4.6805 0.81882E+00 -0.0868 5 HCO3- 0.11943E-04 -4.9229 0.11208E-04 -4.9505 0.93844E+00 -0.0276 6 HS- 0.52350E-13 -13.2811 0.49122E-13 -13.3087 0.93834E+00 -0.0276 7 Al+++ 0.10657E-23 -23.9724 0.69425E-24 -24.1585 0.65145E+00 -0.1861 8 H4SiO4 0.45187E-03 -3.3450 0.45187E-03 -3.3450 0.10000E+01 0.0000 9 Ca++ 0.78074E-07 -7.1075 0.63889E-07 -7.1946 0.81832E+00 -0.0871 10 Mg++ 0.59283E-09 -9.2271 0.48493E-09 -9.3143 0.81800E+00 -0.0872 11 Fe++ 0.35062E-11 -11.4552 0.28683E-11 -11.5424 0.81807E+00 -0.0872 12 K+ 0.65530E-04 -4.1836 0.61498E-04 -4.2111 0.93846E+00 -0.0276 13 Na+ 0.11312E-02 -2.9465 0.10614E-02 -2.9741 0.93832E+00 -0.0277 14 Mn++ 0.46844E-09 -9.3293 0.38324E-09 -9.4165 0.81813E+00 -0.0872 15 HPO4-- 0.14501E-05 -5.8386 0.11874E-05 -5.9254 0.81883E+00 -0.0868 16 HSiO3- 0.40929E-03 -3.3880 0.38405E-03 -3.4156 0.93833E+00 -0.0276 17 Ca(HSiO3)+ 0.58579E-09 -9.2323 0.54975E-09 -9.2598 0.93848E+00 -0.0276 18 Mg(HSiO3)+ 0.55334E-11 -11.2570 0.51930E-11 -11.2846 0.93848E+00 -0.0276 19 NaHSiO3,aq 0.64741E-05 -5.1888 0.64741E-05 -5.1888 0.10000E+01 0.0000 20 AlO+ 0.72469E-13 -13.1398 0.68011E-13 -13.1674 0.93848E+00 -0.0276 21 AlOH+2 0.47800E-18 -18.3206 0.39110E-18 -18.4077 0.81820E+00 -0.0871 22 HAlO2,aq 0.11856E-07 -7.9261 0.11856E-07 -7.9261 0.10000E+01 0.0000 23 AlO2- 0.24580E-04 -4.6094 0.23060E-04 -4.6371 0.93818E+00 -0.0277 24 CH4,aq 0.25893E-19 -19.5868 0.25886E-19 -19.5869 0.99974E+00 -0.0001 29 CO,aq 0.30107E-18 -18.5213 0.30107E-18 -18.5213 0.10000E+01 0.0000 30 CO2,aq 0.25947E-07 -7.5859 0.25940E-07 -7.5860 0.99974E+00 -0.0001 31 CO3-2 0.11026E-05 -5.9576 0.90269E-06 -6.0445 0.81867E+00 -0.0869 32 CaCO3,aq 0.70635E-09 -9.1510 0.70635E-09 -9.1510 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.19225E-10 -10.7161 0.18042E-10 -10.7437 0.93848E+00 -0.0276 34 CaCl+ 0.14042E-10 -10.8526 0.13178E-10 -10.8801 0.93848E+00 -0.0276 35 CaCl2,aq 0.39718E-15 -15.4010 0.39718E-15 -15.4010 0.10000E+01 0.0000 36 CaOH+ 0.41816E-08 -8.3787 0.39244E-08 -8.4062 0.93848E+00 -0.0276 37 CaSO4,aq 0.41543E-09 -9.3815 0.41543E-09 -9.3815 0.10000E+01 0.0000 38 HCl,aq 0.27950E-13 -13.5536 0.27950E-13 -13.5536 0.10000E+01 0.0000 43 FeCl+ 0.61619E-15 -15.2103 0.57828E-15 -15.2379 0.93848E+00 -0.0276 46 FeO,aq 0.86073E-10 -10.0651 0.86073E-10 -10.0651 0.10000E+01 0.0000 47 FeOH+ 0.88267E-10 -10.0542 0.82837E-10 -10.0818 0.93848E+00 -0.0276 48 HFeO2- 0.85948E-09 -9.0658 0.80648E-09 -9.0934 0.93833E+00 -0.0276 49 FeO+ 0.10119E-13 -13.9949 0.94960E-14 -14.0225 0.93848E+00 -0.0276 51 FeO2- 0.15094E-08 -8.8212 0.14163E-08 -8.8489 0.93833E+00 -0.0276 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.45075E-09 -9.3461 0.45064E-09 -9.3462 0.99974E+00 -0.0001 54 KCl,aq 0.14095E-09 -9.8509 0.14095E-09 -9.8509 0.10000E+01 0.0000 55 KHSO4,aq 0.39425E-17 -17.4042 0.39425E-17 -17.4042 0.10000E+01 0.0000 56 KOH,aq 0.23354E-07 -7.6316 0.23354E-07 -7.6316 0.10000E+01 0.0000 57 KSO4- 0.21072E-07 -7.6763 0.19773E-07 -7.7039 0.93833E+00 -0.0276 58 MgCO3,aq 0.13397E-11 -11.8730 0.13397E-11 -11.8730 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14880E-12 -12.8274 0.13965E-12 -12.8550 0.93848E+00 -0.0276 60 MgCl+ 0.96757E-13 -13.0143 0.90805E-13 -13.0419 0.93848E+00 -0.0276 61 MgOH+ 0.17584E-09 -9.7549 0.16502E-09 -9.7825 0.93848E+00 -0.0276 63 MnO,aq 0.30700E-09 -9.5129 0.30700E-09 -9.5129 0.10000E+01 0.0000 64 MnOH+ 0.10956E-08 -8.9604 0.10282E-08 -8.9879 0.93848E+00 -0.0276 65 MnO2-2 0.98413E-14 -14.0069 0.80568E-14 -14.0938 0.81867E+00 -0.0869 66 HMnO2- 0.21356E-11 -11.6705 0.20039E-11 -11.6981 0.93833E+00 -0.0276 69 MnCl+ 0.31992E-12 -12.4950 0.30024E-12 -12.5225 0.93848E+00 -0.0276 70 MnSO4,aq 0.22666E-11 -11.6446 0.22666E-11 -11.6446 0.10000E+01 0.0000 71 NaCl,aq 0.44861E-07 -7.3481 0.44861E-07 -7.3481 0.10000E+01 0.0000 72 NaOH,aq 0.40627E-06 -6.3912 0.40627E-06 -6.3912 0.10000E+01 0.0000 74 OH- 0.55696E-03 -3.2542 0.52253E-03 -3.2819 0.93818E+00 -0.0277 79 HPO3-2 0.20644E-17 -17.6852 0.16901E-17 -17.7721 0.81867E+00 -0.0869 82 H3PO4,aq 0.10074E-13 -13.9968 0.10074E-13 -13.9968 0.10000E+01 0.0000 83 H2PO4- 0.25466E-07 -7.5940 0.23897E-07 -7.6216 0.93840E+00 -0.0276 84 PO4-3 0.13808E-08 -8.8599 0.90332E-09 -9.0442 0.65419E+00 -0.1843 87 H2P2O7-2 0.54596E-16 -16.2628 0.44696E-16 -16.3497 0.81867E+00 -0.0869 88 HP2O7-3 0.12255E-13 -13.9117 0.79838E-14 -14.0978 0.65148E+00 -0.1861 89 P2O7-4 0.36166E-14 -14.4417 0.17157E-14 -14.7655 0.47441E+00 -0.3238 90 H2S,aq 0.16947E-15 -15.7709 0.16943E-15 -15.7710 0.99974E+00 -0.0001 97 SO3-2 0.15644E-14 -14.8057 0.12823E-14 -14.8920 0.81968E+00 -0.0864 98 HSO3- 0.91806E-16 -16.0371 0.86144E-16 -16.0648 0.93833E+00 -0.0276 99 HSO4- 0.23684E-10 -10.6255 0.22229E-10 -10.6531 0.93856E+00 -0.0275 Charge balance for all species = -.5860E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1222774E-08 -.1072572E-02 -.1080958E+01 0.0000 2 H2O 0.1000000E+01 0.5550844E+02 0.9998800E+06 0.0000 3 Cl- 0.1379506E-03 0.1379956E-03 0.4891766E+01 5.0522 4 SO4-- 0.2548692E-04 0.2550854E-04 0.2450094E+01 13.1997 5 HCO3- 0.1194273E-04 0.1307203E-04 0.7975222E+00 3.9896 6 HS- 0.5234958E-13 -.1013636E-09 -.3351890E-05 -4.3687 7 Al+++ 0.1065689E-23 0.2459161E-04 0.6634382E+00 2.6617 8 H4SiO4 0.4518674E-03 0.8676348E-03 0.8338296E+02 -3.3450 9 Ca++ 0.7807428E-07 0.8399676E-07 0.3366014E-02 10.6856 10 Mg++ 0.5928273E-09 0.7757842E-09 0.1885858E-04 8.5658 11 Fe++ 0.3506208E-11 0.2750167E-08 0.1535700E-03 6.3378 12 K+ 0.6553004E-04 0.6557461E-04 0.2563787E+01 4.7289 13 Na+ 0.1131158E-02 0.1138083E-02 0.2616112E+02 5.9659 14 Mn++ 0.4684381E-09 0.1875746E-08 0.1030372E-03 8.4636 15 HPO4-- 0.1450111E-05 0.1476958E-05 0.1417398E+00 11.9547 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1288604E-01 -.1072406E-02 -.1181364E-01 0.0000000E+00 2 H2O 0.5549849E+02 0.5549981E+02 -.1324250E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4709322E-04 0.2550457E-04 0.2158864E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2158875E-04 -.1013478E-09 -.2158864E-04 0.0000000E+00 7 Al+++ 0.2540118E-02 0.2458779E-04 0.2515530E-02 0.0000000E+00 8 H4SiO4 0.8111558E-02 0.8674999E-03 0.7244058E-02 0.0000000E+00 9 Ca++ 0.9104322E-03 0.8398370E-07 0.9103482E-03 0.0000000E+00 10 Mg++ 0.6182540E-03 0.7756636E-09 0.6182532E-03 0.0000000E+00 11 Fe++ 0.5554337E-03 0.2749740E-08 0.5554309E-03 0.0000000E+00 12 K+ 0.1653928E-03 0.6556441E-04 0.9982837E-04 0.0000000E+00 13 Na+ 0.1137906E-02 0.1137906E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1350677E-04 0.1875454E-08 0.1350489E-04 0.0000000E+00 15 HPO4-- 0.4609792E-05 0.1476728E-05 0.3133064E-05 0.0000000E+00 Chg. balance for solid moles: -.5912E-18 Mass of aqueous solution: 0.999966E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.7790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1044E-05 -5.981 0.5246E-03 -3.280 0.6420E-01 0.1667E-03 clinochlore 0.1237E-03 -3.908 0.6873E-01 -1.163 8.410 0.2614E-01 daphnite 0.7654E-04 -4.116 0.5462E-01 -1.263 6.683 0.1655E-01 chlorite-Mn 0.2701E-05 -5.568 0.1915E-02 -2.718 0.2343 0.6102E-03 hematite 0.8635E-04 -4.064 0.1379E-01 -1.860 1.688 0.2614E-02 muscovite 0.9983E-04 -4.001 0.3976E-01 -1.401 4.866 0.1406E-01 stilbite 0.9051E-03 -3.043 0.6379 -0.195 78.05 0.2975 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.817198 g Volume = 0.357653 cm3 Porosity: 72.7315% V(tot) - V(min): 0.95395E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.7790000 g log = -0.1085 Original solution: 1000.0103000 g Original solution / Rock added: 1283.71 (Water/Rock Ratio), log = 3.1085 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2802E-05 1.0073 0.2969E-05 0.2948E-05 CH4,gas 0.3842E-16 1.0129 0.4094E-16 0.4041E-16 H2,gas 0.5872E-06 1.0006 0.6181E-06 0.6177E-06 H2S,gas 0.4717E-14 0.9959 0.4941E-14 0.4962E-14 S2,gas 0.2276E-35 1.0000 0.2394E-35 0.2394E-35 CO,gas 0.4519E-15 1.0000 0.4754E-15 0.4754E-15 SO3,gas 0.9774E-38 1.0000 0.1028E-37 0.1028E-37 SO2,gas 0.2285E-21 1.0000 0.2404E-21 0.2404E-21 HCl,gas 0.4692E-16 1.0000 0.4935E-16 0.4935E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 120 muscovite 2.68 2.68 0.00 0.000 0.30331E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.89 -7.53 -2.509 0.12853E+05 -5.527 3 CH4,gas 4.81 -13.58 -18.39 -4.597 0.31397E+05 -16.388 4 H2,gas 8.29 0.08 -8.21 -4.691 0.14017E+05 -6.209 5 H2S,gas -5.94 -22.25 -16.31 -8.153 0.27842E+05 -14.306 6 S2,gas -7.03 -44.65 -37.62 -5.788 0.64237E+05 -35.621 7 CO,gas 3.51 -13.81 -17.32 -5.330 0.29578E+05 -15.323 8 SO3,gas 17.43 -22.56 -39.99 -9.997 0.68278E+05 -37.988 9 SO2,gas 1.14 -22.48 -23.62 -6.298 0.40329E+05 -21.619 10 HCl,gas 5.48 -12.83 -18.31 -9.153 0.31258E+05 -16.307 11 acmite 7.74 5.57 -2.16 -0.225 0.36926E+04 15 albite-high 0.75 -1.41 -2.16 -0.166 0.36829E+04 16 albite -0.33 -1.41 -1.08 -0.083 0.18422E+04 19 spessartine 24.55 20.68 -3.87 -0.194 0.66088E+04 20 analcite 3.37 1.94 -1.43 -0.159 0.24467E+04 21 andalusite 5.06 1.98 -3.08 -0.308 0.52656E+04 22 andradite 39.09 34.62 -4.47 -0.232 0.76296E+04 26 annite 20.21 16.37 -3.84 -0.213 0.65572E+04 27 phlogopite 27.15 23.05 -4.09 -0.227 0.69893E+04 29 anorthite 12.80 9.32 -3.48 -0.268 0.59396E+04 35 aragonite 0.99 -3.20 -4.19 -1.397 0.71564E+04 36 brucite 12.58 8.57 -4.01 -0.802 0.68483E+04 37 calcite 0.83 -3.20 -4.04 -1.346 0.68950E+04 38 carnegieite-low 9.06 5.28 -3.78 -0.540 0.64574E+04 39 carnegieite-high 10.13 5.28 -4.85 -0.693 0.82843E+04 40 carpholite-Mg 8.65 7.20 -1.45 -0.097 0.24776E+04 41 carpholite-Fe 6.78 4.97 -1.81 -0.121 0.30933E+04 42 celadonite 5.40 2.58 -2.82 -0.166 0.48218E+04 43 celadonite-Fe 3.94 0.35 -3.59 -0.211 0.61272E+04 44 chrysotile 23.94 19.01 -4.93 -0.411 0.84175E+04 50 chloritoid-Mg 13.26 10.54 -2.72 -0.181 0.46391E+04 51 chloritoid-Fe 9.24 8.32 -0.92 -0.061 0.15750E+04 52 chloritoid-Mn 11.46 10.44 -1.02 -0.068 0.17435E+04 54 coesite -2.37 -3.34 -0.98 -0.325 0.16659E+04 59 corundum 8.43 5.32 -3.11 -0.283 0.53101E+04 61 cristobalite -2.55 -3.34 -0.80 -0.265 0.13588E+04 63 cymrite-K 1.73 -2.64 -4.38 -0.365 0.74703E+04 65 diaspore 2.90 2.66 -0.23 -0.039 0.40014E+03 67 diopside 16.22 12.56 -3.65 -0.365 0.62392E+04 68 hedenbergite 14.24 10.33 -3.91 -0.391 0.66780E+04 75 epidote 24.78 22.96 -1.82 -0.088 0.31020E+04 76 clinozoisite 22.92 19.32 -3.60 -0.164 0.61464E+04 77 epidote-Fe 29.94 26.60 -3.34 -0.174 0.57050E+04 78 fayalite 14.08 9.33 -4.75 -0.678 0.81077E+04 83 gibbsite 4.10 2.66 -1.44 -0.205 0.24513E+04 87 greenalite 16.19 12.32 -3.87 -0.323 0.66093E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.94 -2.31 -0.231 0.39497E+04 97 kalsilite 7.62 4.05 -3.57 -0.511 0.61035E+04 98 kaolinite -1.27 -1.37 -0.09 -0.008 0.15939E+03 99 kyanite 4.93 1.98 -2.95 -0.295 0.50424E+04 101 laumontite 2.97 2.63 -0.35 -0.023 0.58982E+03 102 lawsonite 9.68 9.32 -0.36 -0.024 0.61347E+03 103 leucite 4.17 0.70 -3.47 -0.347 0.59197E+04 105 lizardite 23.29 19.01 -4.28 -0.357 0.73078E+04 107 magnetite 20.13 18.94 -1.20 -0.098 0.20445E+04 108 minnesotaite 10.46 5.63 -4.83 -0.284 0.82425E+04 113 margarite 17.45 14.64 -2.81 -0.112 0.47967E+04 116 microcline -2.43 -2.64 -0.21 -0.016 0.36283E+03 121 paragonite 4.34 3.92 -0.42 -0.025 0.71785E+03 122 nepheline 8.38 5.28 -3.10 -0.442 0.52853E+04 136 prehnite 19.47 16.66 -2.81 -0.165 0.47923E+04 137 prehnite-Fe 22.59 20.30 -2.29 -0.138 0.39101E+04 138 pumpellyite-Fe 46.47 42.32 -4.15 -0.092 0.70889E+04 139 pumpellyite-Mg 49.19 44.55 -4.65 -0.103 0.79348E+04 145 pyroxmangite 7.42 5.12 -2.30 -0.459 0.39227E+04 146 pyrophyllite -6.10 -8.06 -1.96 -0.122 0.33440E+04 147 quartz -2.98 -3.34 -0.36 -0.121 0.61980E+03 151 rhodochrosite -0.96 -5.43 -4.47 -1.489 0.76297E+04 152 rhodonite 7.46 5.12 -2.34 -0.469 0.40020E+04 153 sanidine -1.22 -2.64 -1.42 -0.109 0.24306E+04 155 siderite -2.59 -7.55 -4.97 -1.655 0.84778E+04 156 sillimanite 5.32 1.98 -3.34 -0.334 0.57078E+04 164 stilpnomelane-Fe 13.18 12.62 -0.56 -0.017 0.96028E+03 165 stilpnomelane-Mg 27.60 23.76 -3.84 -0.115 0.65551E+04 168 sudoite 21.22 17.74 -3.47 -0.112 0.59292E+04 171 talc 16.55 12.32 -4.24 -0.249 0.72326E+04 174 tephroite 18.11 13.58 -4.53 -0.647 0.77359E+04 177 topaz-H 4.67 1.98 -2.69 -0.244 0.45915E+04 178 tridymite -2.61 -3.34 -0.73 -0.243 0.12471E+04 187 wairakite 4.06 2.63 -1.43 -0.084 0.24406E+04 188 walstromite 11.53 7.34 -4.19 -0.837 0.71497E+04 189 wollastonite 10.48 7.34 -3.14 -0.628 0.53636E+04 190 pseudo-wollastonite 11.02 7.34 -3.68 -0.736 0.62822E+04 191 zoisite 22.96 19.32 -3.64 -0.166 0.62190E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.31 -2.75 -0.170 0.46980E+04 194 beidellite-H -2.24 -6.07 -3.83 -0.245 0.65450E+04 195 beidellite-K -1.44 -4.51 -3.08 -0.189 0.52568E+04 196 beidellite-Mg -1.71 -4.66 -2.95 -0.183 0.50439E+04 197 beidellite-Na -1.26 -4.11 -2.85 -0.174 0.48637E+04 199 chalcedony -2.79 -3.34 -0.55 -0.184 0.94011E+03 201 montmorillonite-Ca -2.21 -4.35 -2.13 -0.132 0.36386E+04 202 montmorillonite-K -2.16 -4.55 -2.39 -0.146 0.40750E+04 203 montmorillonite-Mg -2.40 -4.69 -2.29 -0.142 0.39155E+04 204 montmorillonite-Na -1.96 -4.14 -2.18 -0.133 0.37201E+04 205 nontronite-Ca 3.28 2.96 -0.32 -0.021 0.54067E+03 206 nontronite-H 2.60 1.20 -1.40 -0.094 0.23834E+04 207 nontronite-K 3.40 2.76 -0.64 -0.041 0.10986E+04 208 nontronite-Mg 3.14 2.61 -0.53 -0.034 0.89814E+03 209 nontronite-Na 3.58 3.17 -0.41 -0.027 0.70718E+03 224 tobermorite 9.84 5.56 -4.28 -1.169 0.73129E+04 233 boehmite 4.43 2.66 -1.77 -0.295 0.30186E+04 235 ferrous-oxide 9.82 6.34 -3.49 -0.872 0.59530E+04 240 silica-amorphous -2.08 -3.34 -1.27 -0.422 0.21603E+04 242 an20ab80 2.08 0.74 -1.34 -0.103 0.22901E+04 243 an25ab75 2.71 1.27 -1.43 -0.110 0.24500E+04 244 an30ab70 3.34 1.81 -1.53 -0.118 0.26182E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.7790000 g New total amount of reactant added: 0.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.5860E-14 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.7990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .8548490E-03 Osmotic coef. = 0.9830 True ionic strength = .1251229E-02 Chg. balance for total moles = -.5860E-14 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11998E-08 -8.9209 0.11258E-08 -8.9485 0.93838E+00 -0.0276 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12938E-03 -3.8881 0.93789E+00 -0.0278 4 SO4-- 0.25487E-04 -4.5937 0.20831E-04 -4.6813 0.81732E+00 -0.0876 5 HCO3- 0.11922E-04 -4.9236 0.11183E-04 -4.9514 0.93801E+00 -0.0278 6 HS- 0.52171E-13 -13.2826 0.48931E-13 -13.3104 0.93790E+00 -0.0278 7 Al+++ 0.98133E-24 -24.0082 0.63664E-24 -24.1961 0.64875E+00 -0.1879 8 H4SiO4 0.45880E-03 -3.3384 0.45880E-03 -3.3384 0.10000E+01 0.0000 9 Ca++ 0.71562E-07 -7.1453 0.58452E-07 -7.2332 0.81680E+00 -0.0879 10 Mg++ 0.57252E-09 -9.2422 0.46745E-09 -9.3303 0.81648E+00 -0.0881 11 Fe++ 0.33861E-11 -11.4703 0.27649E-11 -11.5583 0.81656E+00 -0.0880 12 K+ 0.66866E-04 -4.1748 0.62722E-04 -4.2026 0.93803E+00 -0.0278 13 Na+ 0.11559E-02 -2.9371 0.10841E-02 -2.9649 0.93788E+00 -0.0279 14 Mn++ 0.45239E-09 -9.3445 0.36943E-09 -9.4325 0.81661E+00 -0.0880 15 HPO4-- 0.16418E-05 -5.7847 0.13419E-05 -5.8723 0.81733E+00 -0.0876 16 HSiO3- 0.42393E-03 -3.3727 0.39760E-03 -3.4006 0.93789E+00 -0.0278 17 Ca(HSiO3)+ 0.55510E-09 -9.2556 0.52071E-09 -9.2834 0.93805E+00 -0.0278 18 Mg(HSiO3)+ 0.55247E-11 -11.2577 0.51824E-11 -11.2855 0.93805E+00 -0.0278 19 NaHSiO3,aq 0.68459E-05 -5.1646 0.68459E-05 -5.1646 0.10000E+01 0.0000 20 AlO+ 0.69123E-13 -13.1604 0.64841E-13 -13.1882 0.93805E+00 -0.0278 21 AlOH+2 0.44777E-18 -18.3489 0.36569E-18 -18.4369 0.81668E+00 -0.0879 22 HAlO2,aq 0.11525E-07 -7.9384 0.11525E-07 -7.9384 0.10000E+01 0.0000 23 AlO2- 0.24375E-04 -4.6131 0.22857E-04 -4.6410 0.93774E+00 -0.0279 24 CH4,aq 0.25783E-19 -19.5887 0.25777E-19 -19.5888 0.99973E+00 -0.0001 29 CO,aq 0.29591E-18 -18.5288 0.29591E-18 -18.5288 0.10000E+01 0.0000 30 CO2,aq 0.25391E-07 -7.5953 0.25385E-07 -7.5954 0.99973E+00 -0.0001 31 CO3-2 0.11239E-05 -5.9493 0.91840E-06 -6.0370 0.81716E+00 -0.0877 32 CaCO3,aq 0.65748E-09 -9.1821 0.65748E-09 -9.1821 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.17558E-10 -10.7555 0.16471E-10 -10.7833 0.93805E+00 -0.0278 34 CaCl+ 0.12847E-10 -10.8912 0.12051E-10 -10.9190 0.93805E+00 -0.0278 35 CaCl2,aq 0.36304E-15 -15.4401 0.36304E-15 -15.4401 0.10000E+01 0.0000 36 CaOH+ 0.39027E-08 -8.4086 0.36609E-08 -8.4364 0.93805E+00 -0.0278 37 CaSO4,aq 0.37937E-09 -9.4209 0.37937E-09 -9.4209 0.10000E+01 0.0000 38 HCl,aq 0.27399E-13 -13.5623 0.27399E-13 -13.5623 0.10000E+01 0.0000 43 FeCl+ 0.59397E-15 -15.2262 0.55717E-15 -15.2540 0.93805E+00 -0.0278 46 FeO,aq 0.86260E-10 -10.0642 0.86260E-10 -10.0642 0.10000E+01 0.0000 47 FeOH+ 0.86795E-10 -10.0615 0.81418E-10 -10.0893 0.93805E+00 -0.0278 48 HFeO2- 0.87868E-09 -9.0562 0.82410E-09 -9.0840 0.93789E+00 -0.0278 49 FeO+ 0.99282E-14 -14.0031 0.93131E-14 -14.0309 0.93805E+00 -0.0278 51 FeO2- 0.15397E-08 -8.8126 0.14441E-08 -8.8404 0.93789E+00 -0.0278 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.45272E-09 -9.3442 0.45260E-09 -9.3443 0.99973E+00 -0.0001 54 KCl,aq 0.14369E-09 -9.8426 0.14369E-09 -9.8426 0.10000E+01 0.0000 55 KHSO4,aq 0.39363E-17 -17.4049 0.39363E-17 -17.4049 0.10000E+01 0.0000 56 KOH,aq 0.24287E-07 -7.6146 0.24287E-07 -7.6146 0.10000E+01 0.0000 57 KSO4- 0.21462E-07 -7.6683 0.20129E-07 -7.6962 0.93789E+00 -0.0278 58 MgCO3,aq 0.13139E-11 -11.8815 0.13139E-11 -11.8815 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14319E-12 -12.8441 0.13432E-12 -12.8719 0.93805E+00 -0.0278 60 MgCl+ 0.93268E-13 -13.0303 0.87490E-13 -13.0580 0.93805E+00 -0.0278 61 MgOH+ 0.17291E-09 -9.7622 0.16220E-09 -9.7900 0.93805E+00 -0.0278 63 MnO,aq 0.30767E-09 -9.5119 0.30767E-09 -9.5119 0.10000E+01 0.0000 64 MnOH+ 0.10773E-08 -8.9677 0.10106E-08 -8.9954 0.93805E+00 -0.0278 65 MnO2-2 0.10273E-13 -13.9883 0.83946E-14 -14.0760 0.81716E+00 -0.0877 66 HMnO2- 0.21833E-11 -11.6609 0.20477E-11 -11.6887 0.93789E+00 -0.0278 69 MnCl+ 0.30839E-12 -12.5109 0.28928E-12 -12.5387 0.93805E+00 -0.0278 70 MnSO4,aq 0.21809E-11 -11.6614 0.21809E-11 -11.6614 0.10000E+01 0.0000 71 NaCl,aq 0.45799E-07 -7.3391 0.45799E-07 -7.3391 0.10000E+01 0.0000 72 NaOH,aq 0.42311E-06 -6.3736 0.42311E-06 -6.3736 0.10000E+01 0.0000 74 OH- 0.56816E-03 -3.2455 0.53279E-03 -3.2734 0.93774E+00 -0.0279 79 HPO3-2 0.23475E-17 -17.6294 0.19183E-17 -17.7171 0.81716E+00 -0.0877 82 H3PO4,aq 0.10950E-13 -13.9606 0.10950E-13 -13.9606 0.10000E+01 0.0000 83 H2PO4- 0.28238E-07 -7.5492 0.26487E-07 -7.5770 0.93797E+00 -0.0278 84 PO4-3 0.15976E-08 -8.7965 0.10409E-08 -8.9826 0.65153E+00 -0.1861 87 H2P2O7-2 0.67192E-16 -16.1727 0.54907E-16 -16.2604 0.81716E+00 -0.0877 88 HP2O7-3 0.15414E-13 -13.8121 0.10000E-13 -14.0000 0.64878E+00 -0.1879 89 P2O7-4 0.46530E-14 -14.3323 0.21913E-14 -14.6593 0.47094E+00 -0.3270 90 H2S,aq 0.16556E-15 -15.7810 0.16552E-15 -15.7812 0.99973E+00 -0.0001 97 SO3-2 0.15711E-14 -14.8038 0.12855E-14 -14.8909 0.81820E+00 -0.0871 98 HSO3- 0.90305E-16 -16.0443 0.84697E-16 -16.0721 0.93789E+00 -0.0278 99 HSO4- 0.23196E-10 -10.6346 0.21760E-10 -10.6623 0.93812E+00 -0.0277 Charge balance for all species = -.5856E-14 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1199771E-08 -.1098003E-02 -.1106584E+01 0.0000 2 H2O 0.1000000E+01 0.5550844E+02 0.9998773E+06 0.0000 3 Cl- 0.1379502E-03 0.1379962E-03 0.4891772E+01 5.0604 4 SO4-- 0.2548667E-04 0.2550864E-04 0.2450097E+01 13.2157 5 HCO3- 0.1192212E-04 0.1307208E-04 0.7975231E+00 3.9971 6 HS- 0.5217058E-13 -.1046662E-09 -.3461093E-05 -4.3619 7 Al+++ 0.9813279E-24 0.2438628E-04 0.6578970E+00 2.6495 8 H4SiO4 0.4588038E-03 0.8895832E-03 0.8549206E+02 -3.3384 9 Ca++ 0.7156184E-07 0.7708688E-07 0.3089106E-02 10.6638 10 Mg++ 0.5725183E-09 0.7525007E-09 0.1829253E-04 8.5668 11 Fe++ 0.3386087E-11 0.2798312E-08 0.1562580E-03 6.3387 12 K+ 0.6686612E-04 0.6691201E-04 0.2616069E+01 4.7459 13 Na+ 0.1155881E-02 0.1163196E-02 0.2673833E+02 5.9836 14 Mn++ 0.4523915E-09 0.1842066E-08 0.1011869E-03 8.4646 15 HPO4-- 0.1641809E-05 0.1671645E-05 0.1604229E+00 12.0248 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1321721E-01 -.1097828E-02 -.1211939E-01 0.0000000E+00 2 H2O 0.5549823E+02 0.5549959E+02 -.1357997E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4764748E-04 0.2550457E-04 0.2214291E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2214301E-04 -.1046496E-09 -.2214291E-04 0.0000000E+00 7 Al+++ 0.2605333E-02 0.2438240E-04 0.2580950E-02 0.0000000E+00 8 H4SiO4 0.8319814E-02 0.8894415E-03 0.7430372E-02 0.0000000E+00 9 Ca++ 0.9334350E-03 0.7707460E-07 0.9333580E-03 0.0000000E+00 10 Mg++ 0.6341270E-03 0.7523808E-09 0.6341262E-03 0.0000000E+00 11 Fe++ 0.5696939E-03 0.2797866E-08 0.5696911E-03 0.0000000E+00 12 K+ 0.1696391E-03 0.6690135E-04 0.1027377E-03 0.0000000E+00 13 Na+ 0.1163011E-02 0.1163011E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1385354E-04 0.1841772E-08 0.1385170E-04 0.0000000E+00 15 HPO4-- 0.4728144E-05 0.1671378E-05 0.3056765E-05 0.0000000E+00 Chg. balance for solid moles: -.8640E-18 Mass of aqueous solution: 0.999965E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1019E-05 -5.992 0.5118E-03 -3.291 0.6106E-01 0.1626E-03 clinochlore 0.1268E-03 -3.897 0.7049E-01 -1.152 8.410 0.2681E-01 daphnite 0.7851E-04 -4.105 0.5602E-01 -1.252 6.683 0.1697E-01 chlorite-Mn 0.2770E-05 -5.557 0.1964E-02 -2.707 0.2343 0.6259E-03 hematite 0.8857E-04 -4.053 0.1414E-01 -1.849 1.687 0.2681E-02 muscovite 0.1027E-03 -3.988 0.4092E-01 -1.388 4.882 0.1447E-01 stilbite 0.9283E-03 -3.032 0.6542 -0.184 78.04 0.3051 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.838219 g Volume = 0.366843 cm3 Porosity: 72.2004% V(tot) - V(min): 0.95276E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.7990000 g log = -0.0975 Original solution: 1000.0103000 g Original solution / Rock added: 1251.58 (Water/Rock Ratio), log = 3.0975 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2742E-05 1.0073 0.2906E-05 0.2885E-05 CH4,gas 0.3826E-16 1.0129 0.4076E-16 0.4024E-16 H2,gas 0.5898E-06 1.0006 0.6208E-06 0.6204E-06 H2S,gas 0.4608E-14 0.9959 0.4827E-14 0.4847E-14 S2,gas 0.2153E-35 1.0000 0.2265E-35 0.2265E-35 CO,gas 0.4442E-15 1.0000 0.4672E-15 0.4672E-15 SO3,gas 0.9384E-38 1.0000 0.9871E-38 0.9871E-38 SO2,gas 0.2204E-21 1.0000 0.2318E-21 0.2318E-21 HCl,gas 0.4599E-16 1.0000 0.4838E-16 0.4838E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 120 muscovite 2.68 2.68 0.00 0.000 0.30331E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.90 -7.54 -2.512 0.12869E+05 -5.537 3 CH4,gas 4.81 -13.58 -18.39 -4.597 0.31400E+05 -16.390 4 H2,gas 8.29 0.08 -8.21 -4.690 0.14013E+05 -6.207 5 H2S,gas -5.94 -22.26 -16.32 -8.158 0.27860E+05 -14.316 6 S2,gas -7.03 -44.68 -37.64 -5.792 0.64278E+05 -35.645 7 CO,gas 3.51 -13.82 -17.33 -5.332 0.29591E+05 -15.330 8 SO3,gas 17.43 -22.58 -40.01 -10.001 0.68309E+05 -38.006 9 SO2,gas 1.14 -22.50 -23.63 -6.303 0.40356E+05 -21.635 10 HCl,gas 5.48 -12.84 -18.32 -9.158 0.31273E+05 -16.315 11 acmite 7.74 5.61 -2.13 -0.221 0.36399E+04 15 albite-high 0.75 -1.38 -2.13 -0.164 0.36399E+04 16 albite -0.33 -1.38 -1.05 -0.081 0.17992E+04 19 spessartine 24.55 20.68 -3.87 -0.194 0.66120E+04 20 analcite 3.37 1.96 -1.41 -0.157 0.24150E+04 21 andalusite 5.06 1.96 -3.10 -0.310 0.52963E+04 22 andradite 39.09 34.57 -4.51 -0.234 0.77070E+04 26 annite 20.21 16.40 -3.81 -0.212 0.65104E+04 27 phlogopite 27.15 23.08 -4.07 -0.226 0.69425E+04 29 anorthite 12.80 9.29 -3.51 -0.270 0.59961E+04 35 aragonite 0.99 -3.24 -4.22 -1.407 0.72095E+04 36 brucite 12.58 8.57 -4.01 -0.802 0.68467E+04 37 calcite 0.83 -3.24 -4.07 -1.356 0.69482E+04 38 carnegieite-low 9.06 5.29 -3.77 -0.539 0.64370E+04 39 carnegieite-high 10.13 5.29 -4.84 -0.691 0.82638E+04 40 carpholite-Mg 8.65 7.19 -1.46 -0.097 0.24954E+04 41 carpholite-Fe 6.78 4.96 -1.82 -0.121 0.31110E+04 42 celadonite 5.40 2.61 -2.79 -0.164 0.47670E+04 43 celadonite-Fe 3.94 0.38 -3.56 -0.209 0.60723E+04 44 chrysotile 23.94 19.02 -4.91 -0.409 0.83901E+04 50 chloritoid-Mg 13.26 10.53 -2.73 -0.182 0.46681E+04 51 chloritoid-Fe 9.24 8.30 -0.94 -0.063 0.16040E+04 52 chloritoid-Mn 11.46 10.43 -1.04 -0.069 0.17725E+04 54 coesite -2.37 -3.34 -0.97 -0.323 0.16546E+04 59 corundum 8.43 5.30 -3.13 -0.285 0.53521E+04 61 cristobalite -2.55 -3.34 -0.79 -0.263 0.13475E+04 63 cymrite-K 1.73 -2.62 -4.35 -0.363 0.74283E+04 65 diaspore 2.90 2.65 -0.25 -0.041 0.42112E+03 67 diopside 16.22 12.55 -3.66 -0.366 0.62521E+04 68 hedenbergite 14.24 10.33 -3.92 -0.392 0.66909E+04 75 epidote 24.78 22.91 -1.86 -0.090 0.31843E+04 76 clinozoisite 22.92 19.26 -3.66 -0.166 0.62497E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.175 0.57664E+04 78 fayalite 14.08 9.34 -4.74 -0.677 0.80932E+04 83 gibbsite 4.10 2.65 -1.45 -0.207 0.24723E+04 87 greenalite 16.19 12.34 -3.85 -0.321 0.65819E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.96 -2.29 -0.229 0.39180E+04 97 kalsilite 7.62 4.06 -3.56 -0.509 0.60841E+04 98 kaolinite -1.27 -1.38 -0.10 -0.010 0.17876E+03 99 kyanite 4.93 1.96 -2.97 -0.297 0.50731E+04 101 laumontite 2.97 2.61 -0.37 -0.024 0.62371E+03 102 lawsonite 9.68 9.29 -0.39 -0.026 0.66995E+03 103 leucite 4.17 0.72 -3.45 -0.345 0.58890E+04 105 lizardite 23.29 19.02 -4.26 -0.355 0.72804E+04 107 magnetite 20.13 18.94 -1.20 -0.098 0.20429E+04 108 minnesotaite 10.46 5.66 -4.80 -0.282 0.81925E+04 113 margarite 17.45 14.58 -2.87 -0.115 0.48951E+04 116 microcline -2.43 -2.62 -0.19 -0.014 0.32087E+03 121 paragonite 4.34 3.92 -0.42 -0.025 0.71679E+03 122 nepheline 8.38 5.29 -3.08 -0.440 0.52649E+04 136 prehnite 19.47 16.61 -2.85 -0.168 0.48746E+04 137 prehnite-Fe 22.59 20.26 -2.33 -0.140 0.39715E+04 138 pumpellyite-Fe 46.47 42.21 -4.26 -0.095 0.72728E+04 139 pumpellyite-Mg 49.19 44.44 -4.75 -0.106 0.81188E+04 145 pyroxmangite 7.42 5.13 -2.29 -0.458 0.39098E+04 146 pyrophyllite -6.10 -8.05 -1.96 -0.122 0.33408E+04 147 quartz -2.98 -3.34 -0.36 -0.119 0.60850E+03 151 rhodochrosite -0.96 -5.44 -4.48 -1.492 0.76441E+04 152 rhodonite 7.46 5.13 -2.34 -0.467 0.39891E+04 153 sanidine -1.22 -2.62 -1.40 -0.108 0.23886E+04 155 siderite -2.59 -7.56 -4.97 -1.658 0.84922E+04 156 sillimanite 5.32 1.96 -3.36 -0.336 0.57385E+04 164 stilpnomelane-Fe 13.18 12.66 -0.52 -0.016 0.88927E+03 165 stilpnomelane-Mg 27.60 23.80 -3.80 -0.113 0.64841E+04 168 sudoite 21.22 17.72 -3.50 -0.113 0.59760E+04 171 talc 16.55 12.35 -4.21 -0.247 0.71825E+04 174 tephroite 18.11 13.59 -4.52 -0.646 0.77214E+04 177 topaz-H 4.67 1.96 -2.71 -0.246 0.46222E+04 178 tridymite -2.61 -3.34 -0.72 -0.241 0.12358E+04 187 wairakite 4.06 2.61 -1.45 -0.085 0.24745E+04 188 walstromite 11.53 7.33 -4.20 -0.840 0.71755E+04 189 wollastonite 10.48 7.33 -3.16 -0.631 0.53894E+04 190 pseudo-wollastonite 11.02 7.33 -3.69 -0.739 0.63080E+04 191 zoisite 22.96 19.26 -3.70 -0.168 0.63223E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.32 -2.76 -0.171 0.47116E+04 194 beidellite-H -2.24 -6.08 -3.84 -0.245 0.65524E+04 195 beidellite-K -1.44 -4.51 -3.08 -0.188 0.52546E+04 196 beidellite-Mg -1.71 -4.67 -2.96 -0.183 0.50510E+04 197 beidellite-Na -1.26 -4.10 -2.85 -0.174 0.48612E+04 199 chalcedony -2.79 -3.34 -0.54 -0.181 0.92882E+03 201 montmorillonite-Ca -2.21 -4.34 -2.13 -0.132 0.36340E+04 202 montmorillonite-K -2.16 -4.54 -2.37 -0.145 0.40548E+04 203 montmorillonite-Mg -2.40 -4.69 -2.29 -0.141 0.39045E+04 204 montmorillonite-Na -1.96 -4.13 -2.17 -0.133 0.36995E+04 205 nontronite-Ca 3.28 2.98 -0.30 -0.019 0.51226E+03 206 nontronite-H 2.60 1.22 -1.38 -0.092 0.23488E+04 207 nontronite-K 3.40 2.79 -0.62 -0.040 0.10544E+04 208 nontronite-Mg 3.14 2.63 -0.51 -0.033 0.86334E+03 209 nontronite-Na 3.58 3.19 -0.39 -0.025 0.66271E+03 224 tobermorite 9.84 5.54 -4.29 -1.172 0.73326E+04 233 boehmite 4.43 2.65 -1.78 -0.297 0.30396E+04 235 ferrous-oxide 9.82 6.34 -3.49 -0.871 0.59514E+04 240 silica-amorphous -2.08 -3.34 -1.26 -0.420 0.21490E+04 242 an20ab80 2.08 0.75 -1.33 -0.102 0.22670E+04 243 an25ab75 2.71 1.28 -1.42 -0.110 0.24318E+04 244 an30ab70 3.34 1.82 -1.53 -0.117 0.26050E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0200000 g Current total amount of reactant added: 0.7990000 g New total amount of reactant added: 0.8190000 g Mixing fraction reached given limit of 0.8000E+00 TOTMIX = 0.8190E+00 Execution stopped.