File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.13217E-01 0.11998E-08 0.9384 0.00000000E+00 H2O 2 0. 0.55498E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13795E-03 0.9379 0.00000000E+00 SO4-- 4 -2. 0.47647E-04 0.25487E-04 0.8173 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.11922E-04 0.9380 0.00000000E+00 HS- 6 -1. -0.22143E-04 0.52171E-13 0.9379 0.00000000E+00 Al+++ 7 3. 0.26053E-02 0.98133E-24 0.6487 0.00000000E+00 H4SiO4 8 0. 0.83198E-02 0.45880E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.93344E-03 0.71562E-07 0.8168 0.00000000E+00 Mg++ 10 2. 0.63413E-03 0.57252E-09 0.8165 0.00000000E+00 Fe++ 11 2. 0.56969E-03 0.33861E-11 0.8166 0.00000000E+00 K+ 12 1. 0.16964E-03 0.66866E-04 0.9380 0.00000000E+00 Na+ 13 1. 0.11630E-02 0.11559E-02 0.9379 0.00000000E+00 Mn++ 14 2. 0.13854E-04 0.45239E-09 0.8166 0.00000000E+00 HPO4-- 15 -2. 0.47281E-05 0.16418E-05 0.8173 0.00000000E+00 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 100.0000 SLIM = 0.200000E+01 TEMP = 100.0000 SINC = 0.4000E-01 TEMPC = 0.0000 TOTMIX = 0.799000E+00 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 1.3196 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0107 MnO2-2 65 -2. 40.4376 Ca(HSiO3)+ 17 1. 7.6603 HMnO2- 66 -1. 29.1018 Mg(HSiO3)+ 18 1. 7.5653 MnO4- 67 -1. 83.3383 NaHSiO3,aq 19 0. 7.8098 MnO4-2 68 -2. 81.3024 AlO+ 20 1. 6.8891 MnCl+ 69 1. -0.7819 AlOH+2 21 2. 3.1893 MnSO4,aq 70 0. -2.4524 HAlO2,aq 22 0. 10.5878 NaCl,aq 71 0. 0.4861 AlO2- 23 -1. 16.2390 NaOH,aq 72 0. 12.3571 CH4,aq 24 0. 6.0082 O2,aq 73 0. 53.5759 C2H6,aq 25 0. 12.3556 OH- 74 -1. 12.2220 C3H8,aq 26 0. 17.3423 HO2- 75 -1. 50.7897 C4H10,aq 27 0. 22.3397 H2O2,aq 76 0. 40.0297 ethanol,aq 28 0. 15.3114 H3PO2,aq 77 0. 24.3310 CO,aq 29 0. 4.7087 H2PO2- 78 -1. 26.5491 CO2,aq 30 0. -6.3045 HPO3-2 79 -2. 11.9246 CO3-2 31 -2. 10.0340 H3PO3,aq 80 0. 3.5932 CaCO3,aq 32 0. 5.9460 H2PO3- 81 -1. 5.6314 Ca(HCO3)+ 33 1. -1.4013 H3PO4,aq 82 0. -9.8087 CaCl+ 34 1. -0.2023 H2PO4- 83 -1. -7.2438 CaCl2,aq 35 0. 0.4306 PO4-3 84 -3. 12.0588 CaOH+ 36 1. 10.1517 H4P2O7,aq 85 0. -17.7539 CaSO4,aq 37 0. -2.4936 H3P2O7- 86 -1. -15.8646 HCl,aq 38 0. 0.7256 H2P2O7-2 87 -2. -13.3812 HClO,aq 39 0. 32.4377 HP2O7-3 88 -3. -6.6931 ClO- 40 -1. 39.6416 P2O7-4 89 -4. 2.9147 HClO2,aq 41 0. 70.2060 H2S,aq 90 0. -6.4778 Fe+3 42 3. 8.3763 S2-2 91 -2. 1.2336 FeCl+ 43 1. -0.1924 S3-2 92 -2. -8.7963 FeCl2,aq 44 0. 4.3160 S3- 93 -1. -16.3178 FeCl+2 45 2. 6.5223 S4-2 94 -2. -18.6473 FeO,aq 46 0. 16.4029 S5-2 95 -2. -28.3223 FeOH+ 47 1. 7.4795 SO2,aq 96 0. -0.1980 HFeO2- 48 -1. 24.3713 SO3-2 97 -2. 10.2895 FeO+ 49 1. 11.3812 HSO3- 98 -1. 2.5222 FeOH+2 50 2. 9.1115 HSO4- 99 -1. -2.9675 FeO2- 51 -1. 24.0877 HSO5- 100 -1. 38.8657 HFeO2,aq 52 0. 15.9903 S2O3-2 101 -2. -4.5491 H2,aq 53 0. 9.4241 HS2O3- 102 -1. -6.8007 KCl,aq 54 0. 1.7519 H2S2O3,aq 103 0. -7.9944 KHSO4,aq 55 0. -0.4275 S2O4-2 104 -2. 10.5639 KOH,aq 56 0. 12.3606 HS2O4- 105 -1. 7.6762 KSO4- 57 -1. -1.1877 H2S2O4,aq 106 0. 6.6566 MgCO3,aq 58 0. 6.5483 S2O5-2 107 -2. 10.0891 Mg(HCO3)+ 59 1. -1.4098 S2O6-2 108 -2. 11.5737 MgCl+ 60 1. -0.1603 S2O8-2 109 -2. 42.1139 MgOH+ 61 1. 9.4082 S3O6-2 110 -2. 3.8101 Mn+3 62 3. 19.1332 S4O6-2 111 -2. -17.8301 MnO,aq 63 0. 17.9765 S5O6-2 112 -2. -14.1051 MnOH+ 64 1. 8.5115 113 0. 10.3157 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.984 0.0000E+00 osumilite(2) 124 20.895 0.0000E+00 CO2,gas 2 -6.363 0.0000E+00 osumilite-Fe 125 14.657 0.0000E+00 CH4,gas 3 4.809 0.0000E+00 pargasite 126 65.279 0.0000E+00 H2,gas 4 8.287 0.0000E+00 periclase 127 16.149 0.0000E+00 H2S,gas 5 -5.943 0.0000E+00 periclase-Fe 128 11.639 0.0000E+00 S2,gas 6 -7.033 0.0000E+00 perovskite-Al 129 12.395 0.0000E+00 CO,gas 7 3.510 0.0000E+00 perovskite-Ca 130 23.818 0.0000E+00 SO3,gas 8 17.427 0.0000E+00 perovskite-Fe 131 21.158 0.0000E+00 SO2,gas 9 1.136 0.0000E+00 perovskite-Mg 132 23.132 0.0000E+00 HCl,gas 10 5.479 0.0000E+00 phase_A 133 80.267 0.0000E+00 acmite 11 7.737 0.0000E+00 phlogopite-Na 134 29.731 0.0000E+00 akermanite 12 36.495 0.0000E+00 piemontite(ordered) 135 33.876 0.0000E+00 akimotoite 13 16.606 0.0000E+00 prehnite 136 19.466 0.0000E+00 akimotoite-Fe 14 13.083 0.0000E+00 prehnite-Fe 137 22.587 0.0000E+00 albite-high 15 0.750 0.0000E+00 pumpellyite-Fe 138 46.471 0.0000E+00 albite 16 -0.328 0.0000E+00 pumpellyite-Mg 139 49.194 0.0000E+00 almandine 17 24.545 0.0000E+00 px-Mg-tschermaks 140 19.687 0.0000E+00 pyrope 18 37.348 0.0000E+00 px-Ca-tschermaks 141 18.679 0.0000E+00 spessartine 19 24.550 0.0000E+00 pyrite 142 -21.225 0.0000E+00 analcite 20 3.371 0.0000E+00 pyrrhotite 143 -4.244 0.0000E+00 andalusite 21 5.062 0.0000E+00 pyrrhotiteFe0.875 144 -6.001 0.0000E+00 andradite 22 39.088 0.0000E+00 pyroxmangite 145 7.416 0.0000E+00 grossular 23 32.828 0.0000E+00 pyrophyllite 146 -6.098 0.0000E+00 anhydrite 24 -5.280 0.0000E+00 quartz 147 -2.982 0.0000E+00 ankerite 25 -2.093 0.0000E+00 rankinite 148 40.765 0.0000E+00 annite 26 20.209 0.0000E+00 ringwoodite-Fe 149 15.486 0.0000E+00 phlogopite 27 27.147 0.0000E+00 ringwoodite-Mg 150 27.602 0.0000E+00 biotite-Mn 28 33.034 0.0000E+00 rhodochrosite 151 -0.959 0.0000E+00 anorthite 29 12.798 0.0000E+00 rhodonite 152 7.462 0.0000E+00 anthophyllite 30 51.988 0.0000E+00 sanidine 153 -1.221 0.0000E+00 anthophyllite-Fe 31 29.455 0.0000E+00 sapphirine(351) 154 79.204 0.0000E+00 apatite-OH 32 -17.989 0.1019E-05 siderite 155 -2.588 0.0000E+00 apatite-OH-zs 33 -12.572 0.0000E+00 sillimanite 156 5.321 0.0000E+00 apatite-Cl-zs 34 -16.504 0.0000E+00 sodalite 157 50.255 0.0000E+00 aragonite 35 0.986 0.0000E+00 spinel 158 20.934 0.0000E+00 brucite 36 12.577 0.0000E+00 spurrite 159 59.566 0.0000E+00 calcite 37 0.833 0.0000E+00 staurolite-Fe 160 74.138 0.0000E+00 carnegieite-low 38 9.065 0.0000E+00 staurolite-Mg 161 90.336 0.0000E+00 carnegieite-high 39 10.134 0.0000E+00 staurolite-Mn 162 84.438 0.0000E+00 carpholite-Mg 40 8.650 0.0000E+00 stilbite 163 -7.406 0.9283E-03 carpholite-Fe 41 6.783 0.0000E+00 stilpnomelane-Fe 164 13.179 0.0000E+00 celadonite 42 5.401 0.0000E+00 stilpnomelane-Mg 165 27.596 0.0000E+00 celadonite-Fe 43 3.937 0.0000E+00 stishovite 166 2.721 0.0000E+00 chrysotile 44 23.937 0.0000E+00 sudoite-Fe 167 18.437 0.0000E+00 chondrodite 45 56.542 0.0000E+00 sudoite 168 21.216 0.0000E+00 clinochlore 46 39.193 0.1268E-03 sulfur 169 -9.141 0.0000E+00 daphnite 47 29.094 0.7851E-04 sylvite 170 1.345 0.0000E+00 chlorite-Mn 48 46.985 0.2770E-05 talc 171 16.553 0.0000E+00 chlorite-Al-free 49 47.262 0.0000E+00 talc-Fe 172 13.516 0.0000E+00 chloritoid-Mg 50 13.261 0.0000E+00 talc-tschermaks 173 19.189 0.0000E+00 chloritoid-Fe 51 9.239 0.0000E+00 tephroite 174 18.113 0.0000E+00 chloritoid-Mn 52 11.463 0.0000E+00 tilleyite 175 41.473 0.0000E+00 clinohumite 53 97.255 0.0000E+00 titanite-CaSi 176 15.497 0.0000E+00 coesite 54 -2.369 0.0000E+00 topaz-H 177 4.668 0.0000E+00 cordierite-H 55 23.898 0.0000E+00 tridymite 178 -2.615 0.0000E+00 cordierite 56 24.245 0.0000E+00 tremolite 179 48.003 0.0000E+00 cordierite-Fe 57 20.649 0.0000E+00 ferroactinolite 180 38.596 0.0000E+00 cordierite-Mn 58 25.261 0.0000E+00 troilite-low 181 -4.394 0.0000E+00 corundum 59 8.433 0.0000E+00 tschermakite 182 48.414 0.0000E+00 corundum-MgSi 60 18.905 0.0000E+00 vesuvianite 183 224.056 0.0000E+00 cristobalite 61 -2.549 0.0000E+00 wadeite-Si 184 20.233 0.0000E+00 cummingtonite 62 52.233 0.0000E+00 wadsleyite-Fe 185 15.711 0.0000E+00 cymrite-K 63 1.731 0.0000E+00 wadsleyite-Mg 186 25.878 0.0000E+00 deerite 64 95.982 0.0000E+00 wairakite 187 4.058 0.0000E+00 diaspore 65 2.896 0.0000E+00 walstromite 188 11.528 0.0000E+00 diamond 66 -3.107 0.0000E+00 wollastonite 189 10.482 0.0000E+00 diopside 67 16.215 0.0000E+00 pseudo-wollastonite 190 11.020 0.0000E+00 hedenbergite 68 14.244 0.0000E+00 zoisite 191 22.964 0.0000E+00 dolomite,ordered 69 0.587 0.0000E+00 akaganeite 192 7.768 0.0000E+00 eastonite 70 28.605 0.0000E+00 beidellite-Ca 193 -1.560 0.0000E+00 enstatite 71 17.301 0.0000E+00 beidellite-H 194 -2.241 0.0000E+00 clinoenstatite-HiP 72 18.388 0.0000E+00 beidellite-K 195 -1.435 0.0000E+00 clinoenstatite 73 17.202 0.0000E+00 beidellite-Mg 196 -1.707 0.0000E+00 protoenstatite 74 17.860 0.0000E+00 beidellite-Na 197 -1.257 0.0000E+00 epidote 75 24.775 0.0000E+00 calcium 198 84.043 0.0000E+00 clinozoisite 76 22.921 0.0000E+00 chalcedony 199 -2.794 0.0000E+00 epidote-Fe 77 29.937 0.0000E+00 dawsonite 200 1.714 0.0000E+00 fayalite 78 14.079 0.0000E+00 montmorillonite-Ca 201 -2.214 0.0000E+00 ferrosilite 79 11.188 0.0000E+00 montmorillonite-K 202 -2.161 0.0000E+00 forsterite 80 21.047 0.0000E+00 montmorillonite-Mg 203 -2.402 0.0000E+00 gedrite 81 50.725 0.0000E+00 montmorillonite-Na 204 -1.961 0.0000E+00 gehlenite 82 36.717 0.0000E+00 nontronite-Ca 205 3.280 0.0000E+00 gibbsite 83 4.097 0.0000E+00 nontronite-H 206 2.596 0.0000E+00 glaucophane 84 23.111 0.0000E+00 nontronite-K 207 3.404 0.0000E+00 glaucophane-Fe 85 17.417 0.0000E+00 nontronite-Mg 208 3.139 0.0000E+00 graphite 86 -3.549 0.0000E+00 nontronite-Na 209 3.583 0.0000E+00 greenalite 87 16.194 0.0000E+00 sepiolite 210 24.194 0.0000E+00 grunerite 88 31.364 0.0000E+00 alite 211 58.043 0.0000E+00 halite 89 1.582 0.0000E+00 belite 212 30.461 0.0000E+00 hematite 90 12.598 0.8857E-04 ettringite 213 43.354 0.0000E+00 heulandite 91 -5.707 0.0000E+00 gypsum 214 -4.924 0.0000E+00 hercynite 92 17.345 0.0000E+00 hemicarboaluminate 215 71.028 0.0000E+00 hollandite 93 25.702 0.0000E+00 hydrogarnet 216 60.721 0.0000E+00 iron 94 19.095 0.0000E+00 hydrogarnet-Si 217 50.654 0.0000E+00 jadeite 95 4.251 0.0000E+00 jennite 218 24.386 0.0000E+00 julgoldite 96 70.573 0.0000E+00 monosulfoaluminate 219 53.497 0.0000E+00 kalsilite 97 7.620 0.0000E+00 monocarboaluminate 220 61.966 0.0000E+00 kaolinite 98 -1.273 0.0000E+00 portlandite 221 18.282 0.0000E+00 kyanite 99 4.932 0.0000E+00 stratlingite 222 36.573 0.0000E+00 larnite-bredigite 100 30.714 0.0000E+00 tricarboaluminate 223 70.427 0.0000E+00 laumontite 101 2.975 0.0000E+00 tobermorite 224 9.839 0.0000E+00 lawsonite 102 9.678 0.0000E+00 C4AH13 225 81.870 0.0000E+00 leucite 103 4.168 0.0000E+00 C2AH8 226 45.260 0.0000E+00 lime 104 26.009 0.0000E+00 C3A 227 87.049 0.0000E+00 lizardite 105 23.287 0.0000E+00 C4AF 228 117.550 0.0000E+00 magnesite 106 0.709 0.0000E+00 CAH10 229 28.373 0.0000E+00 magnetite 107 20.133 0.0000E+00 alabandite 230 -0.962 0.0000E+00 minnesotaite 108 10.461 0.0000E+00 alunite 231 -10.224 0.0000E+00 minnesotaite-Mg 109 20.669 0.0000E+00 artinite 232 15.139 0.0000E+00 magnesioferrite 110 26.257 0.0000E+00 boehmite 233 4.430 0.0000E+00 majorite 111 53.314 0.0000E+00 dolomite,disordered 234 1.288 0.0000E+00 manganosite 112 14.068 0.0000E+00 ferrous-oxide 235 9.824 0.0000E+00 margarite 113 17.452 0.0000E+00 huntite 236 3.850 0.0000E+00 meionite 114 45.158 0.0000E+00 hydromagnesite 237 20.077 0.0000E+00 merwinite 115 55.988 0.0000E+00 nesquehonite 238 4.735 0.0000E+00 microcline 116 -2.432 0.0000E+00 potassium-oxide 239 69.039 0.0000E+00 monticellite 117 24.371 0.0000E+00 silica-amorphous 240 -2.080 0.0000E+00 mullite-Al 118 363.258 0.0000E+00 sodium-oxide 241 55.173 0.0000E+00 mullite-Si 119 7.324 0.0000E+00 an20ab80 242 2.079 0.0000E+00 muscovite 120 2.679 0.1027E-03 an25ab75 243 2.709 0.0000E+00 paragonite 121 4.337 0.0000E+00 an30ab70 244 3.344 0.0000E+00 nepheline 122 8.378 0.0000E+00 tr.625ac.25prg.125 245 45.308 0.0000E+00 osumilite(1) 123 21.978 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 0.7990000 g log = -0.0975 Original solution: 1000.0103000 g Original solution / Rock added: 1251.58 (Water/Rock Ratio), log = 3.0975 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.7990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .8548490E-03 Osmotic coef. = 0.9830 True ionic strength = .1251229E-02 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11998E-08 -8.9209 0.11258E-08 -8.9485 0.93838E+00 -0.0276 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12938E-03 -3.8881 0.93789E+00 -0.0278 4 SO4-- 0.25487E-04 -4.5937 0.20831E-04 -4.6813 0.81732E+00 -0.0876 5 HCO3- 0.11922E-04 -4.9236 0.11183E-04 -4.9514 0.93801E+00 -0.0278 6 HS- 0.52171E-13 -13.2826 0.48931E-13 -13.3104 0.93790E+00 -0.0278 7 Al+++ 0.98133E-24 -24.0082 0.63664E-24 -24.1961 0.64875E+00 -0.1879 8 H4SiO4 0.45880E-03 -3.3384 0.45880E-03 -3.3384 0.10000E+01 0.0000 9 Ca++ 0.71562E-07 -7.1453 0.58452E-07 -7.2332 0.81680E+00 -0.0879 10 Mg++ 0.57252E-09 -9.2422 0.46745E-09 -9.3303 0.81648E+00 -0.0881 11 Fe++ 0.33861E-11 -11.4703 0.27649E-11 -11.5583 0.81656E+00 -0.0880 12 K+ 0.66866E-04 -4.1748 0.62722E-04 -4.2026 0.93803E+00 -0.0278 13 Na+ 0.11559E-02 -2.9371 0.10841E-02 -2.9649 0.93788E+00 -0.0279 14 Mn++ 0.45239E-09 -9.3445 0.36943E-09 -9.4325 0.81661E+00 -0.0880 15 HPO4-- 0.16418E-05 -5.7847 0.13419E-05 -5.8723 0.81733E+00 -0.0876 16 HSiO3- 0.42393E-03 -3.3727 0.39760E-03 -3.4006 0.93789E+00 -0.0278 17 Ca(HSiO3)+ 0.55510E-09 -9.2556 0.52071E-09 -9.2834 0.93805E+00 -0.0278 18 Mg(HSiO3)+ 0.55247E-11 -11.2577 0.51824E-11 -11.2855 0.93805E+00 -0.0278 19 NaHSiO3,aq 0.68459E-05 -5.1646 0.68459E-05 -5.1646 0.10000E+01 0.0000 20 AlO+ 0.69123E-13 -13.1604 0.64841E-13 -13.1882 0.93805E+00 -0.0278 21 AlOH+2 0.44777E-18 -18.3489 0.36569E-18 -18.4369 0.81668E+00 -0.0879 22 HAlO2,aq 0.11525E-07 -7.9384 0.11525E-07 -7.9384 0.10000E+01 0.0000 23 AlO2- 0.24375E-04 -4.6131 0.22857E-04 -4.6410 0.93774E+00 -0.0279 24 CH4,aq 0.25783E-19 -19.5887 0.25777E-19 -19.5888 0.99973E+00 -0.0001 29 CO,aq 0.29591E-18 -18.5288 0.29591E-18 -18.5288 0.10000E+01 0.0000 30 CO2,aq 0.25391E-07 -7.5953 0.25385E-07 -7.5954 0.99973E+00 -0.0001 31 CO3-2 0.11239E-05 -5.9493 0.91840E-06 -6.0370 0.81716E+00 -0.0877 32 CaCO3,aq 0.65748E-09 -9.1821 0.65748E-09 -9.1821 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.17558E-10 -10.7555 0.16471E-10 -10.7833 0.93805E+00 -0.0278 34 CaCl+ 0.12847E-10 -10.8912 0.12051E-10 -10.9190 0.93805E+00 -0.0278 35 CaCl2,aq 0.36304E-15 -15.4401 0.36304E-15 -15.4401 0.10000E+01 0.0000 36 CaOH+ 0.39027E-08 -8.4086 0.36609E-08 -8.4364 0.93805E+00 -0.0278 37 CaSO4,aq 0.37937E-09 -9.4209 0.37937E-09 -9.4209 0.10000E+01 0.0000 38 HCl,aq 0.27399E-13 -13.5623 0.27399E-13 -13.5623 0.10000E+01 0.0000 43 FeCl+ 0.59397E-15 -15.2262 0.55717E-15 -15.2540 0.93805E+00 -0.0278 46 FeO,aq 0.86260E-10 -10.0642 0.86260E-10 -10.0642 0.10000E+01 0.0000 47 FeOH+ 0.86795E-10 -10.0615 0.81418E-10 -10.0893 0.93805E+00 -0.0278 48 HFeO2- 0.87868E-09 -9.0562 0.82410E-09 -9.0840 0.93789E+00 -0.0278 49 FeO+ 0.99282E-14 -14.0031 0.93131E-14 -14.0309 0.93805E+00 -0.0278 51 FeO2- 0.15397E-08 -8.8126 0.14441E-08 -8.8404 0.93789E+00 -0.0278 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.45272E-09 -9.3442 0.45260E-09 -9.3443 0.99973E+00 -0.0001 54 KCl,aq 0.14369E-09 -9.8426 0.14369E-09 -9.8426 0.10000E+01 0.0000 55 KHSO4,aq 0.39363E-17 -17.4049 0.39363E-17 -17.4049 0.10000E+01 0.0000 56 KOH,aq 0.24287E-07 -7.6146 0.24287E-07 -7.6146 0.10000E+01 0.0000 57 KSO4- 0.21462E-07 -7.6683 0.20129E-07 -7.6962 0.93789E+00 -0.0278 58 MgCO3,aq 0.13139E-11 -11.8815 0.13139E-11 -11.8815 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14319E-12 -12.8441 0.13432E-12 -12.8719 0.93805E+00 -0.0278 60 MgCl+ 0.93268E-13 -13.0303 0.87490E-13 -13.0580 0.93805E+00 -0.0278 61 MgOH+ 0.17291E-09 -9.7622 0.16220E-09 -9.7900 0.93805E+00 -0.0278 63 MnO,aq 0.30767E-09 -9.5119 0.30767E-09 -9.5119 0.10000E+01 0.0000 64 MnOH+ 0.10773E-08 -8.9677 0.10106E-08 -8.9954 0.93805E+00 -0.0278 65 MnO2-2 0.10273E-13 -13.9883 0.83946E-14 -14.0760 0.81716E+00 -0.0877 66 HMnO2- 0.21833E-11 -11.6609 0.20477E-11 -11.6887 0.93789E+00 -0.0278 69 MnCl+ 0.30839E-12 -12.5109 0.28928E-12 -12.5387 0.93805E+00 -0.0278 70 MnSO4,aq 0.21809E-11 -11.6614 0.21809E-11 -11.6614 0.10000E+01 0.0000 71 NaCl,aq 0.45799E-07 -7.3391 0.45799E-07 -7.3391 0.10000E+01 0.0000 72 NaOH,aq 0.42311E-06 -6.3736 0.42311E-06 -6.3736 0.10000E+01 0.0000 74 OH- 0.56816E-03 -3.2455 0.53279E-03 -3.2734 0.93774E+00 -0.0279 79 HPO3-2 0.23475E-17 -17.6294 0.19183E-17 -17.7171 0.81716E+00 -0.0877 82 H3PO4,aq 0.10950E-13 -13.9606 0.10950E-13 -13.9606 0.10000E+01 0.0000 83 H2PO4- 0.28238E-07 -7.5492 0.26487E-07 -7.5770 0.93797E+00 -0.0278 84 PO4-3 0.15976E-08 -8.7965 0.10409E-08 -8.9826 0.65153E+00 -0.1861 87 H2P2O7-2 0.67192E-16 -16.1727 0.54907E-16 -16.2604 0.81716E+00 -0.0877 88 HP2O7-3 0.15414E-13 -13.8121 0.10000E-13 -14.0000 0.64878E+00 -0.1879 89 P2O7-4 0.46530E-14 -14.3323 0.21913E-14 -14.6593 0.47094E+00 -0.3270 90 H2S,aq 0.16556E-15 -15.7810 0.16552E-15 -15.7812 0.99973E+00 -0.0001 97 SO3-2 0.15711E-14 -14.8038 0.12855E-14 -14.8909 0.81820E+00 -0.0871 98 HSO3- 0.90305E-16 -16.0443 0.84697E-16 -16.0721 0.93789E+00 -0.0278 99 HSO4- 0.23196E-10 -10.6346 0.21760E-10 -10.6623 0.93812E+00 -0.0277 Charge balance for all species = 0.4567E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1199771E-08 -.1098003E-02 -.1106584E+01 0.0000 2 H2O 0.1000000E+01 0.5550844E+02 0.9998773E+06 0.0000 3 Cl- 0.1379502E-03 0.1379962E-03 0.4891772E+01 5.0604 4 SO4-- 0.2548667E-04 0.2550864E-04 0.2450097E+01 13.2157 5 HCO3- 0.1192212E-04 0.1307208E-04 0.7975231E+00 3.9971 6 HS- 0.5217058E-13 -.1046662E-09 -.3461093E-05 -4.3619 7 Al+++ 0.9813279E-24 0.2438628E-04 0.6578970E+00 2.6495 8 H4SiO4 0.4588038E-03 0.8895832E-03 0.8549206E+02 -3.3384 9 Ca++ 0.7156184E-07 0.7708688E-07 0.3089106E-02 10.6638 10 Mg++ 0.5725183E-09 0.7525007E-09 0.1829253E-04 8.5668 11 Fe++ 0.3386087E-11 0.2798312E-08 0.1562580E-03 6.3387 12 K+ 0.6686612E-04 0.6691201E-04 0.2616069E+01 4.7459 13 Na+ 0.1155881E-02 0.1163196E-02 0.2673833E+02 5.9836 14 Mn++ 0.4523915E-09 0.1842066E-08 0.1011869E-03 8.4646 15 HPO4-- 0.1641809E-05 0.1671645E-05 0.1604229E+00 12.0248 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1321721E-01 -.1097828E-02 -.1211939E-01 0.0000000E+00 2 H2O 0.5549823E+02 0.5549959E+02 -.1357997E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4764748E-04 0.2550457E-04 0.2214291E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2214301E-04 -.1046495E-09 -.2214291E-04 0.0000000E+00 7 Al+++ 0.2605333E-02 0.2438240E-04 0.2580950E-02 0.0000000E+00 8 H4SiO4 0.8319814E-02 0.8894415E-03 0.7430372E-02 0.0000000E+00 9 Ca++ 0.9334350E-03 0.7707460E-07 0.9333580E-03 0.0000000E+00 10 Mg++ 0.6341270E-03 0.7523808E-09 0.6341262E-03 0.0000000E+00 11 Fe++ 0.5696939E-03 0.2797866E-08 0.5696911E-03 0.0000000E+00 12 K+ 0.1696391E-03 0.6690135E-04 0.1027377E-03 0.0000000E+00 13 Na+ 0.1163011E-02 0.1163011E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1385354E-04 0.1841772E-08 0.1385170E-04 0.0000000E+00 15 HPO4-- 0.4728144E-05 0.1671378E-05 0.3056765E-05 0.0000000E+00 Chg. balance for solid moles: 0.4896E-18 Mass of aqueous solution: 0.999965E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1019E-05 -5.992 0.5118E-03 -3.291 0.6106E-01 0.1626E-03 clinochlore 0.1268E-03 -3.897 0.7049E-01 -1.152 8.410 0.2681E-01 daphnite 0.7851E-04 -4.105 0.5602E-01 -1.252 6.683 0.1697E-01 chlorite-Mn 0.2770E-05 -5.557 0.1964E-02 -2.707 0.2343 0.6259E-03 hematite 0.8857E-04 -4.053 0.1414E-01 -1.849 1.687 0.2681E-02 muscovite 0.1027E-03 -3.988 0.4092E-01 -1.388 4.882 0.1447E-01 stilbite 0.9283E-03 -3.032 0.6542 -0.184 78.04 0.3051 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.838219 g Volume = 0.366843 cm3 Porosity: 72.2004% V(tot) - V(min): 0.95276E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.7990000 g log = -0.0975 Original solution: 1000.0103000 g Original solution / Rock added: 1251.58 (Water/Rock Ratio), log = 3.0975 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2742E-05 1.0073 0.2906E-05 0.2885E-05 CH4,gas 0.3826E-16 1.0129 0.4076E-16 0.4024E-16 H2,gas 0.5898E-06 1.0006 0.6208E-06 0.6204E-06 H2S,gas 0.4608E-14 0.9959 0.4827E-14 0.4847E-14 S2,gas 0.2153E-35 1.0000 0.2265E-35 0.2265E-35 CO,gas 0.4442E-15 1.0000 0.4672E-15 0.4672E-15 SO3,gas 0.9384E-38 1.0000 0.9871E-38 0.9871E-38 SO2,gas 0.2204E-21 1.0000 0.2318E-21 0.2318E-21 HCl,gas 0.4599E-16 1.0000 0.4838E-16 0.4838E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.90 -7.54 -2.512 0.12869E+05 -5.537 3 CH4,gas 4.81 -13.58 -18.39 -4.597 0.31400E+05 -16.390 4 H2,gas 8.29 0.08 -8.21 -4.690 0.14013E+05 -6.207 5 H2S,gas -5.94 -22.26 -16.32 -8.158 0.27860E+05 -14.316 6 S2,gas -7.03 -44.68 -37.64 -5.792 0.64278E+05 -35.645 7 CO,gas 3.51 -13.82 -17.33 -5.332 0.29591E+05 -15.330 8 SO3,gas 17.43 -22.58 -40.01 -10.001 0.68309E+05 -38.006 9 SO2,gas 1.14 -22.50 -23.63 -6.303 0.40356E+05 -21.635 10 HCl,gas 5.48 -12.84 -18.32 -9.158 0.31273E+05 -16.315 11 acmite 7.74 5.61 -2.13 -0.221 0.36399E+04 15 albite-high 0.75 -1.38 -2.13 -0.164 0.36399E+04 16 albite -0.33 -1.38 -1.05 -0.081 0.17992E+04 19 spessartine 24.55 20.68 -3.87 -0.194 0.66120E+04 20 analcite 3.37 1.96 -1.41 -0.157 0.24150E+04 21 andalusite 5.06 1.96 -3.10 -0.310 0.52963E+04 22 andradite 39.09 34.57 -4.51 -0.234 0.77070E+04 26 annite 20.21 16.40 -3.81 -0.212 0.65104E+04 27 phlogopite 27.15 23.08 -4.07 -0.226 0.69425E+04 29 anorthite 12.80 9.29 -3.51 -0.270 0.59961E+04 35 aragonite 0.99 -3.24 -4.22 -1.407 0.72095E+04 36 brucite 12.58 8.57 -4.01 -0.802 0.68467E+04 37 calcite 0.83 -3.24 -4.07 -1.356 0.69482E+04 38 carnegieite-low 9.06 5.29 -3.77 -0.539 0.64370E+04 39 carnegieite-high 10.13 5.29 -4.84 -0.691 0.82638E+04 40 carpholite-Mg 8.65 7.19 -1.46 -0.097 0.24954E+04 41 carpholite-Fe 6.78 4.96 -1.82 -0.121 0.31110E+04 42 celadonite 5.40 2.61 -2.79 -0.164 0.47670E+04 43 celadonite-Fe 3.94 0.38 -3.56 -0.209 0.60723E+04 44 chrysotile 23.94 19.02 -4.91 -0.409 0.83901E+04 50 chloritoid-Mg 13.26 10.53 -2.73 -0.182 0.46681E+04 51 chloritoid-Fe 9.24 8.30 -0.94 -0.063 0.16040E+04 52 chloritoid-Mn 11.46 10.43 -1.04 -0.069 0.17725E+04 54 coesite -2.37 -3.34 -0.97 -0.323 0.16546E+04 59 corundum 8.43 5.30 -3.13 -0.285 0.53521E+04 61 cristobalite -2.55 -3.34 -0.79 -0.263 0.13475E+04 63 cymrite-K 1.73 -2.62 -4.35 -0.363 0.74283E+04 65 diaspore 2.90 2.65 -0.25 -0.041 0.42112E+03 67 diopside 16.22 12.55 -3.66 -0.366 0.62521E+04 68 hedenbergite 14.24 10.33 -3.92 -0.392 0.66909E+04 75 epidote 24.78 22.91 -1.86 -0.090 0.31843E+04 76 clinozoisite 22.92 19.26 -3.66 -0.166 0.62497E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.175 0.57664E+04 78 fayalite 14.08 9.34 -4.74 -0.677 0.80932E+04 83 gibbsite 4.10 2.65 -1.45 -0.207 0.24723E+04 87 greenalite 16.19 12.34 -3.85 -0.321 0.65819E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.96 -2.29 -0.229 0.39180E+04 97 kalsilite 7.62 4.06 -3.56 -0.509 0.60841E+04 98 kaolinite -1.27 -1.38 -0.10 -0.010 0.17876E+03 99 kyanite 4.93 1.96 -2.97 -0.297 0.50731E+04 101 laumontite 2.97 2.61 -0.37 -0.024 0.62371E+03 102 lawsonite 9.68 9.29 -0.39 -0.026 0.66995E+03 103 leucite 4.17 0.72 -3.45 -0.345 0.58890E+04 105 lizardite 23.29 19.02 -4.26 -0.355 0.72804E+04 107 magnetite 20.13 18.94 -1.20 -0.098 0.20429E+04 108 minnesotaite 10.46 5.66 -4.80 -0.282 0.81925E+04 113 margarite 17.45 14.58 -2.87 -0.115 0.48951E+04 116 microcline -2.43 -2.62 -0.19 -0.014 0.32087E+03 121 paragonite 4.34 3.92 -0.42 -0.025 0.71679E+03 122 nepheline 8.38 5.29 -3.08 -0.440 0.52649E+04 136 prehnite 19.47 16.61 -2.85 -0.168 0.48746E+04 137 prehnite-Fe 22.59 20.26 -2.33 -0.140 0.39715E+04 138 pumpellyite-Fe 46.47 42.21 -4.26 -0.095 0.72728E+04 139 pumpellyite-Mg 49.19 44.44 -4.75 -0.106 0.81188E+04 145 pyroxmangite 7.42 5.13 -2.29 -0.458 0.39098E+04 146 pyrophyllite -6.10 -8.05 -1.96 -0.122 0.33408E+04 147 quartz -2.98 -3.34 -0.36 -0.119 0.60850E+03 151 rhodochrosite -0.96 -5.44 -4.48 -1.492 0.76441E+04 152 rhodonite 7.46 5.13 -2.34 -0.467 0.39891E+04 153 sanidine -1.22 -2.62 -1.40 -0.108 0.23886E+04 155 siderite -2.59 -7.56 -4.97 -1.658 0.84922E+04 156 sillimanite 5.32 1.96 -3.36 -0.336 0.57385E+04 164 stilpnomelane-Fe 13.18 12.66 -0.52 -0.016 0.88927E+03 165 stilpnomelane-Mg 27.60 23.80 -3.80 -0.113 0.64841E+04 168 sudoite 21.22 17.72 -3.50 -0.113 0.59760E+04 171 talc 16.55 12.35 -4.21 -0.247 0.71825E+04 174 tephroite 18.11 13.59 -4.52 -0.646 0.77214E+04 177 topaz-H 4.67 1.96 -2.71 -0.246 0.46222E+04 178 tridymite -2.61 -3.34 -0.72 -0.241 0.12358E+04 187 wairakite 4.06 2.61 -1.45 -0.085 0.24745E+04 188 walstromite 11.53 7.33 -4.20 -0.840 0.71755E+04 189 wollastonite 10.48 7.33 -3.16 -0.631 0.53894E+04 190 pseudo-wollastonite 11.02 7.33 -3.69 -0.739 0.63080E+04 191 zoisite 22.96 19.26 -3.70 -0.168 0.63223E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.32 -2.76 -0.171 0.47116E+04 194 beidellite-H -2.24 -6.08 -3.84 -0.245 0.65524E+04 195 beidellite-K -1.44 -4.51 -3.08 -0.188 0.52546E+04 196 beidellite-Mg -1.71 -4.67 -2.96 -0.183 0.50510E+04 197 beidellite-Na -1.26 -4.10 -2.85 -0.174 0.48612E+04 199 chalcedony -2.79 -3.34 -0.54 -0.181 0.92882E+03 201 montmorillonite-Ca -2.21 -4.34 -2.13 -0.132 0.36340E+04 202 montmorillonite-K -2.16 -4.54 -2.37 -0.145 0.40548E+04 203 montmorillonite-Mg -2.40 -4.69 -2.29 -0.141 0.39045E+04 204 montmorillonite-Na -1.96 -4.13 -2.17 -0.133 0.36995E+04 205 nontronite-Ca 3.28 2.98 -0.30 -0.019 0.51226E+03 206 nontronite-H 2.60 1.22 -1.38 -0.092 0.23488E+04 207 nontronite-K 3.40 2.79 -0.62 -0.040 0.10544E+04 208 nontronite-Mg 3.14 2.63 -0.51 -0.033 0.86334E+03 209 nontronite-Na 3.58 3.19 -0.39 -0.025 0.66271E+03 224 tobermorite 9.84 5.54 -4.29 -1.172 0.73326E+04 233 boehmite 4.43 2.65 -1.78 -0.297 0.30396E+04 235 ferrous-oxide 9.82 6.34 -3.49 -0.871 0.59514E+04 240 silica-amorphous -2.08 -3.34 -1.26 -0.420 0.21490E+04 242 an20ab80 2.08 0.75 -1.33 -0.102 0.22670E+04 243 an25ab75 2.71 1.28 -1.42 -0.110 0.24318E+04 244 an30ab70 3.34 1.82 -1.53 -0.117 0.26050E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 0.7990000 g New total amount of reactant added: 0.8390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4566E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.8390000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .8804482E-03 Osmotic coef. = 0.9828 True ionic strength = .1303818E-02 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11568E-08 -8.9368 0.10845E-08 -8.9648 0.93754E+00 -0.0280 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12926E-03 -3.8885 0.93703E+00 -0.0282 4 SO4-- 0.25486E-04 -4.5937 0.20755E-04 -4.6829 0.81436E+00 -0.0892 5 HCO3- 0.11881E-04 -4.9251 0.11135E-04 -4.9533 0.93715E+00 -0.0282 6 HS- 0.51939E-13 -13.2845 0.48669E-13 -13.3127 0.93704E+00 -0.0282 7 Al+++ 0.83767E-24 -24.0769 0.53901E-24 -24.2684 0.64346E+00 -0.1915 8 H4SiO4 0.47217E-03 -3.3259 0.47217E-03 -3.3259 0.10000E+01 0.0000 9 Ca++ 0.60753E-07 -7.2164 0.49442E-07 -7.3059 0.81383E+00 -0.0895 10 Mg++ 0.53558E-09 -9.2712 0.43569E-09 -9.3608 0.81350E+00 -0.0896 11 Fe++ 0.31676E-11 -11.4993 0.25771E-11 -11.5889 0.81358E+00 -0.0896 12 K+ 0.69598E-04 -4.1574 0.65225E-04 -4.1856 0.93718E+00 -0.0282 13 Na+ 0.12053E-02 -2.9189 0.11294E-02 -2.9472 0.93702E+00 -0.0283 14 Mn++ 0.42320E-09 -9.3735 0.34433E-09 -9.4630 0.81364E+00 -0.0896 15 HPO4-- 0.20720E-05 -5.6836 0.16874E-05 -5.7728 0.81437E+00 -0.0892 16 HSiO3- 0.45333E-03 -3.3436 0.42479E-03 -3.3718 0.93703E+00 -0.0282 17 Ca(HSiO3)+ 0.50210E-09 -9.2992 0.47056E-09 -9.3274 0.93719E+00 -0.0282 18 Mg(HSiO3)+ 0.55064E-11 -11.2591 0.51606E-11 -11.2873 0.93719E+00 -0.0282 19 NaHSiO3,aq 0.76196E-05 -5.1181 0.76196E-05 -5.1181 0.10000E+01 0.0000 20 AlO+ 0.63127E-13 -13.1998 0.59162E-13 -13.2280 0.93719E+00 -0.0282 21 AlOH+2 0.39500E-18 -18.4034 0.32141E-18 -18.4929 0.81371E+00 -0.0895 22 HAlO2,aq 0.10917E-07 -7.9619 0.10917E-07 -7.9619 0.10000E+01 0.0000 23 AlO2- 0.23990E-04 -4.6200 0.22476E-04 -4.6483 0.93688E+00 -0.0283 24 CH4,aq 0.25628E-19 -19.5913 0.25621E-19 -19.5914 0.99973E+00 -0.0001 29 CO,aq 0.28635E-18 -18.5431 0.28635E-18 -18.5431 0.10000E+01 0.0000 30 CO2,aq 0.24353E-07 -7.6134 0.24347E-07 -7.6136 0.99973E+00 -0.0001 31 CO3-2 0.11659E-05 -5.9333 0.94929E-06 -6.0226 0.81421E+00 -0.0893 32 CaCO3,aq 0.57484E-09 -9.2405 0.57484E-09 -9.2405 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.14801E-10 -10.8297 0.13872E-10 -10.8579 0.93719E+00 -0.0282 34 CaCl+ 0.10867E-10 -10.9639 0.10184E-10 -10.9921 0.93719E+00 -0.0282 35 CaCl2,aq 0.30651E-15 -15.5136 0.30651E-15 -15.5136 0.10000E+01 0.0000 36 CaOH+ 0.34301E-08 -8.4647 0.32147E-08 -8.4929 0.93719E+00 -0.0282 37 CaSO4,aq 0.31973E-09 -9.4952 0.31973E-09 -9.4952 0.10000E+01 0.0000 38 HCl,aq 0.26369E-13 -13.5789 0.26369E-13 -13.5789 0.10000E+01 0.0000 43 FeCl+ 0.55361E-15 -15.2568 0.51884E-15 -15.2850 0.93719E+00 -0.0282 46 FeO,aq 0.86646E-10 -10.0623 0.86646E-10 -10.0623 0.10000E+01 0.0000 47 FeOH+ 0.84058E-10 -10.0754 0.78779E-10 -10.1036 0.93719E+00 -0.0282 48 HFeO2- 0.91709E-09 -9.0376 0.85934E-09 -9.0658 0.93703E+00 -0.0282 49 FeO+ 0.95724E-14 -14.0190 0.89712E-14 -14.0472 0.93719E+00 -0.0282 51 FeO2- 0.15999E-08 -8.7959 0.14991E-08 -8.8242 0.93703E+00 -0.0282 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.45678E-09 -9.3403 0.45666E-09 -9.3404 0.99973E+00 -0.0001 54 KCl,aq 0.14929E-09 -9.8260 0.14929E-09 -9.8260 0.10000E+01 0.0000 55 KHSO4,aq 0.39287E-17 -17.4057 0.39287E-17 -17.4057 0.10000E+01 0.0000 56 KOH,aq 0.26219E-07 -7.5814 0.26219E-07 -7.5814 0.10000E+01 0.0000 57 KSO4- 0.22258E-07 -7.6525 0.20856E-07 -7.6808 0.93703E+00 -0.0282 58 MgCO3,aq 0.12658E-11 -11.8976 0.12658E-11 -11.8976 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13300E-12 -12.8761 0.12465E-12 -12.9043 0.93719E+00 -0.0282 60 MgCl+ 0.86930E-13 -13.0608 0.81471E-13 -13.0890 0.93719E+00 -0.0282 61 MgOH+ 0.16746E-09 -9.7761 0.15694E-09 -9.8043 0.93719E+00 -0.0282 63 MnO,aq 0.30905E-09 -9.5100 0.30905E-09 -9.5100 0.10000E+01 0.0000 64 MnOH+ 0.10434E-08 -8.9816 0.97783E-09 -9.0097 0.93719E+00 -0.0282 65 MnO2-2 0.11161E-13 -13.9523 0.90874E-14 -14.0416 0.81421E+00 -0.0893 66 HMnO2- 0.22788E-11 -11.6423 0.21353E-11 -11.6705 0.93703E+00 -0.0282 69 MnCl+ 0.28744E-12 -12.5415 0.26938E-12 -12.5696 0.93719E+00 -0.0282 70 MnSO4,aq 0.20254E-11 -11.6935 0.20254E-11 -11.6935 0.10000E+01 0.0000 71 NaCl,aq 0.47669E-07 -7.3218 0.47669E-07 -7.3218 0.10000E+01 0.0000 72 NaOH,aq 0.45759E-06 -6.3395 0.45759E-06 -6.3395 0.10000E+01 0.0000 74 OH- 0.59036E-03 -3.2289 0.55310E-03 -3.2572 0.93688E+00 -0.0283 79 HPO3-2 0.29893E-17 -17.5244 0.24339E-17 -17.6137 0.81421E+00 -0.0893 82 H3PO4,aq 0.12777E-13 -13.8936 0.12777E-13 -13.8936 0.10000E+01 0.0000 83 H2PO4- 0.34237E-07 -7.4655 0.32084E-07 -7.4937 0.93711E+00 -0.0282 84 PO4-3 0.21023E-08 -8.6773 0.13588E-08 -8.8668 0.64633E+00 -0.1895 87 H2P2O7-2 0.98947E-16 -16.0046 0.80563E-16 -16.0939 0.81421E+00 -0.0893 88 HP2O7-3 0.23672E-13 -13.6258 0.15232E-13 -13.8172 0.64349E+00 -0.1915 89 P2O7-4 0.74648E-14 -14.1270 0.34650E-14 -14.4603 0.46418E+00 -0.3333 90 H2S,aq 0.15863E-15 -15.7996 0.15859E-15 -15.7997 0.99973E+00 -0.0001 97 SO3-2 0.15851E-14 -14.7999 0.12923E-14 -14.8886 0.81528E+00 -0.0887 98 HSO3- 0.87530E-16 -16.0578 0.82019E-16 -16.0861 0.93703E+00 -0.0282 99 HSO4- 0.22283E-10 -10.6520 0.20885E-10 -10.6802 0.93727E+00 -0.0281 Charge balance for all species = 0.4567E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1156751E-08 -.1148911E-02 -.1157884E+01 0.0000 2 H2O 0.1000000E+01 0.5550843E+02 0.9998719E+06 0.0000 3 Cl- 0.1379494E-03 0.1379972E-03 0.4891784E+01 5.0762 4 SO4-- 0.2548613E-04 0.2550884E-04 0.2450104E+01 13.2467 5 HCO3- 0.1188133E-04 0.1307218E-04 0.7975250E+00 4.0114 6 HS- 0.5193919E-13 -.1111709E-09 -.3676171E-05 -4.3480 7 Al+++ 0.8376716E-24 0.2400116E-04 0.6475038E+00 2.6259 8 H4SiO4 0.4721719E-03 0.9331233E-03 0.8967594E+02 -3.3259 9 Ca++ 0.6075252E-07 0.6560495E-07 0.2628976E-02 10.6236 10 Mg++ 0.5355761E-09 0.7100234E-09 0.1725986E-04 8.5687 11 Fe++ 0.3167585E-11 0.2894314E-08 0.1616179E-03 6.3407 12 K+ 0.6959779E-04 0.6964642E-04 0.2722963E+01 4.7792 13 Na+ 0.1205298E-02 0.1213423E-02 0.2789275E+02 6.0176 14 Mn++ 0.4232023E-09 0.1780215E-08 0.9778885E-04 8.4665 15 HPO4-- 0.2072033E-05 0.2108372E-05 0.2023333E+00 12.1568 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1387955E-01 -.1148719E-02 -.1273084E-01 0.0000000E+00 2 H2O 0.5549773E+02 0.5549916E+02 -.1425737E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4875602E-04 0.2550458E-04 0.2325144E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2325155E-04 -.1111524E-09 -.2325144E-04 0.0000000E+00 7 Al+++ 0.2735762E-02 0.2399716E-04 0.2711765E-02 0.0000000E+00 8 H4SiO4 0.8736325E-02 0.9329675E-03 0.7803357E-02 0.0000000E+00 9 Ca++ 0.9794407E-03 0.6559400E-07 0.9793752E-03 0.0000000E+00 10 Mg++ 0.6658730E-03 0.7099048E-09 0.6658723E-03 0.0000000E+00 11 Fe++ 0.5982142E-03 0.2893831E-08 0.5982113E-03 0.0000000E+00 12 K+ 0.1781316E-03 0.6963479E-04 0.1084968E-03 0.0000000E+00 13 Na+ 0.1213220E-02 0.1213220E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1454708E-04 0.1779918E-08 0.1454530E-04 0.0000000E+00 15 HPO4-- 0.4964847E-05 0.2108020E-05 0.2856827E-05 0.0000000E+00 Chg. balance for solid moles: 0.2821E-18 Mass of aqueous solution: 0.999962E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.8390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.9523E-06 -6.021 0.4783E-03 -3.320 0.5434E-01 0.1520E-03 clinochlore 0.1332E-03 -3.876 0.7402E-01 -1.131 8.409 0.2816E-01 daphnite 0.8244E-04 -4.084 0.5882E-01 -1.230 6.682 0.1782E-01 chlorite-Mn 0.2909E-05 -5.536 0.2062E-02 -2.686 0.2343 0.6572E-03 hematite 0.9301E-04 -4.031 0.1485E-01 -1.828 1.687 0.2815E-02 muscovite 0.1085E-03 -3.965 0.4322E-01 -1.364 4.909 0.1528E-01 stilbite 0.9746E-03 -3.011 0.6868 -0.163 78.02 0.3203 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.880283 g Volume = 0.385236 cm3 Porosity: 71.1563% V(tot) - V(min): 0.95036E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.8390000 g log = -0.0762 Original solution: 1000.0103000 g Original solution / Rock added: 1191.91 (Water/Rock Ratio), log = 3.0762 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2630E-05 1.0073 0.2787E-05 0.2767E-05 CH4,gas 0.3802E-16 1.0129 0.4052E-16 0.4000E-16 H2,gas 0.5951E-06 1.0006 0.6263E-06 0.6260E-06 H2S,gas 0.4415E-14 0.9959 0.4625E-14 0.4644E-14 S2,gas 0.1942E-35 1.0000 0.2043E-35 0.2043E-35 CO,gas 0.4298E-15 1.0000 0.4522E-15 0.4522E-15 SO3,gas 0.8676E-38 1.0000 0.9126E-38 0.9126E-38 SO2,gas 0.2056E-21 1.0000 0.2162E-21 0.2162E-21 HCl,gas 0.4426E-16 1.0000 0.4656E-16 0.4656E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.92 -7.55 -2.518 0.12900E+05 -5.555 3 CH4,gas 4.81 -13.58 -18.39 -4.598 0.31404E+05 -16.392 4 H2,gas 8.29 0.08 -8.20 -4.688 0.14007E+05 -6.203 5 H2S,gas -5.94 -22.28 -16.33 -8.167 0.27891E+05 -14.335 6 S2,gas -7.03 -44.72 -37.69 -5.798 0.64354E+05 -35.690 7 CO,gas 3.51 -13.83 -17.34 -5.337 0.29616E+05 -15.345 8 SO3,gas 17.43 -22.61 -40.04 -10.010 0.68367E+05 -38.040 9 SO2,gas 1.14 -22.53 -23.67 -6.311 0.40407E+05 -21.665 10 HCl,gas 5.48 -12.85 -18.33 -9.166 0.31301E+05 -16.332 11 acmite 7.74 5.66 -2.07 -0.215 0.35392E+04 15 albite-high 0.75 -1.33 -2.08 -0.160 0.35581E+04 16 albite -0.33 -1.33 -1.01 -0.077 0.17174E+04 19 spessartine 24.55 20.67 -3.88 -0.194 0.66186E+04 20 analcite 3.37 1.99 -1.38 -0.153 0.23545E+04 21 andalusite 5.06 1.93 -3.14 -0.314 0.53554E+04 22 andradite 39.09 34.49 -4.60 -0.239 0.78491E+04 26 annite 20.21 16.45 -3.76 -0.209 0.64200E+04 27 phlogopite 27.15 23.13 -4.01 -0.223 0.68522E+04 29 anorthite 12.80 9.22 -3.57 -0.275 0.61026E+04 35 aragonite 0.99 -3.29 -4.28 -1.427 0.73091E+04 36 brucite 12.58 8.57 -4.01 -0.802 0.68434E+04 37 calcite 0.83 -3.29 -4.13 -1.376 0.70478E+04 38 carnegieite-low 9.06 5.32 -3.75 -0.535 0.63978E+04 39 carnegieite-high 10.13 5.32 -4.82 -0.688 0.82247E+04 40 carpholite-Mg 8.65 7.17 -1.48 -0.099 0.25299E+04 41 carpholite-Fe 6.78 4.94 -1.84 -0.123 0.31455E+04 42 celadonite 5.40 2.67 -2.73 -0.161 0.46619E+04 43 celadonite-Fe 3.94 0.44 -3.49 -0.206 0.59672E+04 44 chrysotile 23.94 19.05 -4.88 -0.407 0.83376E+04 50 chloritoid-Mg 13.26 10.49 -2.77 -0.184 0.47239E+04 51 chloritoid-Fe 9.24 8.27 -0.97 -0.065 0.16598E+04 52 chloritoid-Mn 11.46 10.39 -1.07 -0.071 0.18283E+04 54 coesite -2.37 -3.33 -0.96 -0.319 0.16333E+04 59 corundum 8.43 5.25 -3.18 -0.289 0.54325E+04 61 cristobalite -2.55 -3.33 -0.78 -0.259 0.13262E+04 63 cymrite-K 1.73 -2.57 -4.30 -0.359 0.73479E+04 65 diaspore 2.90 2.63 -0.27 -0.045 0.46133E+03 67 diopside 16.22 12.54 -3.67 -0.367 0.62748E+04 68 hedenbergite 14.24 10.31 -3.93 -0.393 0.67136E+04 75 epidote 24.78 22.82 -1.96 -0.095 0.33381E+04 76 clinozoisite 22.92 19.15 -3.77 -0.172 0.64438E+04 77 epidote-Fe 29.94 26.49 -3.44 -0.179 0.58800E+04 78 fayalite 14.08 9.36 -4.72 -0.675 0.80653E+04 83 gibbsite 4.10 2.63 -1.47 -0.210 0.25125E+04 87 greenalite 16.19 12.37 -3.82 -0.319 0.65294E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.99 -2.26 -0.226 0.38575E+04 97 kalsilite 7.62 4.08 -3.54 -0.506 0.60463E+04 98 kaolinite -1.27 -1.40 -0.13 -0.012 0.21660E+03 99 kyanite 4.93 1.93 -3.01 -0.301 0.51322E+04 101 laumontite 2.97 2.57 -0.40 -0.027 0.68760E+03 102 lawsonite 9.68 9.22 -0.45 -0.030 0.77644E+03 103 leucite 4.17 0.75 -3.41 -0.341 0.58299E+04 105 lizardite 23.29 19.05 -4.23 -0.353 0.72279E+04 107 magnetite 20.13 18.94 -1.19 -0.098 0.20396E+04 108 minnesotaite 10.46 5.72 -4.74 -0.279 0.80974E+04 113 margarite 17.45 14.48 -2.98 -0.119 0.50820E+04 116 microcline -2.43 -2.57 -0.14 -0.011 0.24044E+03 121 paragonite 4.34 3.92 -0.42 -0.025 0.71544E+03 122 nepheline 8.38 5.32 -3.06 -0.437 0.52257E+04 136 prehnite 19.47 16.52 -2.94 -0.173 0.50284E+04 137 prehnite-Fe 22.59 20.19 -2.39 -0.144 0.40851E+04 138 pumpellyite-Fe 46.47 42.01 -4.46 -0.099 0.76174E+04 139 pumpellyite-Mg 49.19 44.24 -4.96 -0.110 0.84634E+04 145 pyroxmangite 7.42 5.14 -2.28 -0.455 0.38852E+04 146 pyrophyllite -6.10 -8.05 -1.95 -0.122 0.33360E+04 147 quartz -2.98 -3.33 -0.34 -0.115 0.58720E+03 151 rhodochrosite -0.96 -5.45 -4.49 -1.498 0.76717E+04 152 rhodonite 7.46 5.14 -2.32 -0.464 0.39644E+04 153 sanidine -1.22 -2.57 -1.35 -0.104 0.23082E+04 155 siderite -2.59 -7.58 -4.99 -1.663 0.85199E+04 156 sillimanite 5.32 1.93 -3.40 -0.340 0.57976E+04 164 stilpnomelane-Fe 13.18 12.74 -0.44 -0.013 0.75440E+03 165 stilpnomelane-Mg 27.60 23.88 -3.72 -0.111 0.63492E+04 168 sudoite 21.22 17.66 -3.55 -0.115 0.60664E+04 171 talc 16.55 12.40 -4.15 -0.244 0.70874E+04 174 tephroite 18.11 13.61 -4.51 -0.644 0.76935E+04 177 topaz-H 4.67 1.93 -2.74 -0.249 0.46813E+04 178 tridymite -2.61 -3.33 -0.71 -0.237 0.12145E+04 187 wairakite 4.06 2.57 -1.49 -0.087 0.25384E+04 188 walstromite 11.53 7.30 -4.23 -0.846 0.72228E+04 189 wollastonite 10.48 7.30 -3.18 -0.637 0.54367E+04 190 pseudo-wollastonite 11.02 7.30 -3.72 -0.744 0.63554E+04 191 zoisite 22.96 19.15 -3.82 -0.173 0.65163E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.33 -2.78 -0.172 0.47384E+04 194 beidellite-H -2.24 -6.09 -3.85 -0.245 0.65680E+04 195 beidellite-K -1.44 -4.51 -3.08 -0.188 0.52514E+04 196 beidellite-Mg -1.71 -4.67 -2.97 -0.184 0.50660E+04 197 beidellite-Na -1.26 -4.10 -2.84 -0.174 0.48575E+04 199 chalcedony -2.79 -3.33 -0.53 -0.177 0.90752E+03 201 montmorillonite-Ca -2.21 -4.34 -2.12 -0.131 0.36262E+04 202 montmorillonite-K -2.16 -4.51 -2.35 -0.144 0.40169E+04 203 montmorillonite-Mg -2.40 -4.68 -2.28 -0.141 0.38848E+04 204 montmorillonite-Na -1.96 -4.10 -2.14 -0.131 0.36612E+04 205 nontronite-Ca 3.28 3.01 -0.27 -0.017 0.45870E+03 206 nontronite-H 2.60 1.26 -1.34 -0.090 0.22840E+04 207 nontronite-K 3.40 2.84 -0.57 -0.036 0.97082E+03 208 nontronite-Mg 3.14 2.67 -0.47 -0.030 0.79790E+03 209 nontronite-Na 3.58 3.24 -0.34 -0.022 0.57865E+03 224 tobermorite 9.84 5.52 -4.32 -1.177 0.73685E+04 233 boehmite 4.43 2.63 -1.80 -0.301 0.30798E+04 235 ferrous-oxide 9.82 6.34 -3.48 -0.871 0.59481E+04 240 silica-amorphous -2.08 -3.33 -1.25 -0.415 0.21277E+04 242 an20ab80 2.08 0.78 -1.30 -0.100 0.22228E+04 243 an25ab75 2.71 1.31 -1.40 -0.108 0.23971E+04 244 an30ab70 3.34 1.83 -1.51 -0.116 0.25797E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 0.8390000 g New total amount of reactant added: 0.8790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4566E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.8790000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .9063627E-03 Osmotic coef. = 0.9825 True ionic strength = .1356516E-02 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11172E-08 -8.9519 0.10466E-08 -8.9802 0.93672E+00 -0.0284 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12915E-03 -3.8889 0.93619E+00 -0.0286 4 SO4-- 0.25486E-04 -4.5937 0.20681E-04 -4.6844 0.81148E+00 -0.0907 5 HCO3- 0.11841E-04 -4.9266 0.11087E-04 -4.9552 0.93632E+00 -0.0286 6 HS- 0.51860E-13 -13.2852 0.48552E-13 -13.3138 0.93620E+00 -0.0286 7 Al+++ 0.72085E-24 -24.1422 0.46013E-24 -24.3371 0.63832E+00 -0.1950 8 H4SiO4 0.48489E-03 -3.3144 0.48489E-03 -3.3144 0.10000E+01 0.0000 9 Ca++ 0.52239E-07 -7.2820 0.42362E-07 -7.3730 0.81093E+00 -0.0910 10 Mg++ 0.50284E-09 -9.2986 0.40760E-09 -9.3898 0.81058E+00 -0.0912 11 Fe++ 0.29740E-11 -11.5267 0.24109E-11 -11.6178 0.81067E+00 -0.0912 12 K+ 0.72409E-04 -4.1402 0.67800E-04 -4.1688 0.93634E+00 -0.0286 13 Na+ 0.12547E-02 -2.9015 0.11746E-02 -2.9301 0.93618E+00 -0.0286 14 Mn++ 0.39734E-09 -9.4008 0.32213E-09 -9.4920 0.81073E+00 -0.0911 15 HPO4-- 0.25655E-05 -5.5908 0.20819E-05 -5.6815 0.81149E+00 -0.0907 16 HSiO3- 0.48286E-03 -3.3162 0.45204E-03 -3.3448 0.93619E+00 -0.0286 17 Ca(HSiO3)+ 0.45821E-09 -9.3389 0.42905E-09 -9.3675 0.93636E+00 -0.0286 18 Mg(HSiO3)+ 0.54868E-11 -11.2607 0.51376E-11 -11.2892 0.93636E+00 -0.0286 19 NaHSiO3,aq 0.84331E-05 -5.0740 0.84331E-05 -5.0740 0.10000E+01 0.0000 20 AlO+ 0.57920E-13 -13.2372 0.54234E-13 -13.2657 0.93636E+00 -0.0286 21 AlOH+2 0.35067E-18 -18.4551 0.28433E-18 -18.5462 0.81080E+00 -0.0911 22 HAlO2,aq 0.10370E-07 -7.9842 0.10370E-07 -7.9842 0.10000E+01 0.0000 23 AlO2- 0.23637E-04 -4.6264 0.22125E-04 -4.6551 0.93603E+00 -0.0287 24 CH4,aq 0.25548E-19 -19.5926 0.25541E-19 -19.5928 0.99972E+00 -0.0001 29 CO,aq 0.27769E-18 -18.5564 0.27769E-18 -18.5564 0.10000E+01 0.0000 30 CO2,aq 0.23401E-07 -7.6308 0.23394E-07 -7.6309 0.99972E+00 -0.0001 31 CO3-2 0.12073E-05 -5.9182 0.97950E-06 -6.0090 0.81132E+00 -0.0908 32 CaCO3,aq 0.50820E-09 -9.2940 0.50820E-09 -9.2940 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.12639E-10 -10.8983 0.11834E-10 -10.9269 0.93636E+00 -0.0286 34 CaCl+ 0.93104E-11 -11.0310 0.87179E-11 -11.0596 0.93636E+00 -0.0286 35 CaCl2,aq 0.26215E-15 -15.5815 0.26215E-15 -15.5815 0.10000E+01 0.0000 36 CaOH+ 0.30482E-08 -8.5160 0.28542E-08 -8.5445 0.93636E+00 -0.0286 37 CaSO4,aq 0.27297E-09 -9.5639 0.27297E-09 -9.5639 0.10000E+01 0.0000 38 HCl,aq 0.25423E-13 -13.5948 0.25423E-13 -13.5948 0.10000E+01 0.0000 43 FeCl+ 0.51791E-15 -15.2857 0.48495E-15 -15.3143 0.93636E+00 -0.0286 46 FeO,aq 0.87045E-10 -10.0603 0.87045E-10 -10.0603 0.10000E+01 0.0000 47 FeOH+ 0.81563E-10 -10.0885 0.76372E-10 -10.1171 0.93636E+00 -0.0286 48 HFeO2- 0.95559E-09 -9.0197 0.89461E-09 -9.0484 0.93619E+00 -0.0286 49 FeO+ 0.92456E-14 -14.0341 0.86572E-14 -14.0626 0.93636E+00 -0.0286 51 FeO2- 0.16594E-08 -8.7801 0.15535E-08 -8.8087 0.93619E+00 -0.0286 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.46100E-09 -9.3363 0.46087E-09 -9.3364 0.99972E+00 -0.0001 54 KCl,aq 0.15504E-09 -9.8096 0.15504E-09 -9.8096 0.10000E+01 0.0000 55 KHSO4,aq 0.39268E-17 -17.4060 0.39268E-17 -17.4060 0.10000E+01 0.0000 56 KOH,aq 0.28242E-07 -7.5491 0.28242E-07 -7.5491 0.10000E+01 0.0000 57 KSO4- 0.23075E-07 -7.6369 0.21602E-07 -7.6655 0.93619E+00 -0.0286 58 MgCO3,aq 0.12219E-11 -11.9130 0.12219E-11 -11.9130 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12400E-12 -12.9066 0.11611E-12 -12.9351 0.93636E+00 -0.0286 60 MgCl+ 0.81324E-13 -13.0898 0.76149E-13 -13.1183 0.93636E+00 -0.0286 61 MgOH+ 0.16248E-09 -9.7892 0.15214E-09 -9.8177 0.93636E+00 -0.0286 63 MnO,aq 0.31048E-09 -9.5080 0.31048E-09 -9.5080 0.10000E+01 0.0000 64 MnOH+ 0.10124E-08 -8.9947 0.94797E-09 -9.0232 0.93636E+00 -0.0286 65 MnO2-2 0.12083E-13 -13.9178 0.98035E-14 -14.0086 0.81132E+00 -0.0908 66 HMnO2- 0.23744E-11 -11.6244 0.22229E-11 -11.6531 0.93619E+00 -0.0286 69 MnCl+ 0.26890E-12 -12.5704 0.25179E-12 -12.5990 0.93636E+00 -0.0286 70 MnSO4,aq 0.18880E-11 -11.7240 0.18880E-11 -11.7240 0.10000E+01 0.0000 71 NaCl,aq 0.49532E-07 -7.3051 0.49532E-07 -7.3051 0.10000E+01 0.0000 72 NaOH,aq 0.49317E-06 -6.3070 0.49317E-06 -6.3070 0.10000E+01 0.0000 74 OH- 0.61232E-03 -3.2130 0.57315E-03 -3.2417 0.93603E+00 -0.0287 79 HPO3-2 0.37354E-17 -17.4277 0.30306E-17 -17.5185 0.81132E+00 -0.0908 82 H3PO4,aq 0.14680E-13 -13.8333 0.14680E-13 -13.8333 0.10000E+01 0.0000 83 H2PO4- 0.40799E-07 -7.3894 0.38199E-07 -7.4179 0.93627E+00 -0.0286 84 PO4-3 0.27091E-08 -8.5672 0.17373E-08 -8.7601 0.64127E+00 -0.1930 87 H2P2O7-2 0.14076E-15 -15.8515 0.11420E-15 -15.9423 0.81132E+00 -0.0908 88 HP2O7-3 0.35053E-13 -13.4553 0.22376E-13 -13.6502 0.63835E+00 -0.1949 89 P2O7-4 0.11525E-13 -13.9383 0.52745E-14 -14.2778 0.45765E+00 -0.3395 90 H2S,aq 0.15271E-15 -15.8161 0.15267E-15 -15.8163 0.99972E+00 -0.0001 97 SO3-2 0.15996E-14 -14.7960 0.12996E-14 -14.8862 0.81242E+00 -0.0902 98 HSO3- 0.85020E-16 -16.0705 0.79595E-16 -16.0991 0.93619E+00 -0.0286 99 HSO4- 0.21445E-10 -10.6687 0.20082E-10 -10.6972 0.93644E+00 -0.0285 Charge balance for all species = 0.4567E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1117248E-08 -.1199872E-02 -.1209236E+01 0.0000 2 H2O 0.1000000E+01 0.5550842E+02 0.9998665E+06 0.0000 3 Cl- 0.1379486E-03 0.1379983E-03 0.4891796E+01 5.0913 4 SO4-- 0.2548555E-04 0.2550904E-04 0.2450110E+01 13.2761 5 HCO3- 0.1184106E-04 0.1307228E-04 0.7975269E+00 4.0251 6 HS- 0.5186025E-13 -.1175541E-09 -.3887226E-05 -4.3336 7 Al+++ 0.7208489E-24 0.2364766E-04 0.6379635E+00 2.6036 8 H4SiO4 0.4848865E-03 0.9761751E-03 0.9381286E+02 -3.3144 9 Ca++ 0.5223902E-07 0.5654856E-07 0.2266049E-02 10.5875 10 Mg++ 0.5028437E-09 0.6722417E-09 0.1634135E-04 8.5707 11 Fe++ 0.2973983E-11 0.2990028E-08 0.1669617E-03 6.3427 12 K+ 0.7240934E-04 0.7246081E-04 0.2832982E+01 4.8115 13 Na+ 0.1254675E-02 0.1263651E-02 0.2904718E+02 6.0501 14 Mn++ 0.3973387E-09 0.1724756E-08 0.9474189E-04 8.4685 15 HPO4-- 0.2565519E-05 0.2609027E-05 0.2503782E+00 12.2789 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1454190E-01 -.1199662E-02 -.1334223E-01 0.0000000E+00 2 H2O 0.5549723E+02 0.5549873E+02 -.1493810E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4986456E-04 0.2550459E-04 0.2435997E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2436009E-04 -.1175335E-09 -.2435997E-04 0.0000000E+00 7 Al+++ 0.2866192E-02 0.2364353E-04 0.2842548E-02 0.0000000E+00 8 H4SiO4 0.9152836E-02 0.9760046E-03 0.8176832E-02 0.0000000E+00 9 Ca++ 0.1025446E-02 0.5653868E-07 0.1025390E-02 0.0000000E+00 10 Mg++ 0.6976190E-03 0.6721243E-09 0.6976184E-03 0.0000000E+00 11 Fe++ 0.6267346E-03 0.2989506E-08 0.6267316E-03 0.0000000E+00 12 K+ 0.1866242E-03 0.7244815E-04 0.1141760E-03 0.0000000E+00 13 Na+ 0.1263430E-02 0.1263430E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1524063E-04 0.1724454E-08 0.1523890E-04 0.0000000E+00 15 HPO4-- 0.5201550E-05 0.2608572E-05 0.2592978E-05 0.0000000E+00 Chg. balance for solid moles: 0.7979E-18 Mass of aqueous solution: 0.999960E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.8790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.8643E-06 -6.063 0.4342E-03 -3.362 0.4707E-01 0.1380E-03 clinochlore 0.1395E-03 -3.855 0.7755E-01 -1.110 8.408 0.2950E-01 daphnite 0.8637E-04 -4.064 0.6163E-01 -1.210 6.681 0.1867E-01 chlorite-Mn 0.3048E-05 -5.516 0.2161E-02 -2.665 0.2343 0.6886E-03 hematite 0.9744E-04 -4.011 0.1556E-01 -1.808 1.687 0.2949E-02 muscovite 0.1142E-03 -3.942 0.4548E-01 -1.342 4.930 0.1608E-01 stilbite 0.1021E-02 -2.991 0.7196 -0.143 78.01 0.3356 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.922378 g Volume = 0.403649 cm3 Porosity: 70.1355% V(tot) - V(min): 0.94795E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.8790000 g log = -0.0560 Original solution: 1000.0103000 g Original solution / Rock added: 1137.67 (Water/Rock Ratio), log = 3.0560 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2527E-05 1.0073 0.2678E-05 0.2658E-05 CH4,gas 0.3791E-16 1.0129 0.4039E-16 0.3987E-16 H2,gas 0.6006E-06 1.0006 0.6321E-06 0.6318E-06 H2S,gas 0.4250E-14 0.9959 0.4453E-14 0.4471E-14 S2,gas 0.1767E-35 1.0000 0.1858E-35 0.1858E-35 CO,gas 0.4168E-15 1.0000 0.4385E-15 0.4385E-15 SO3,gas 0.8050E-38 1.0000 0.8468E-38 0.8468E-38 SO2,gas 0.1925E-21 1.0000 0.2025E-21 0.2025E-21 HCl,gas 0.4267E-16 1.0000 0.4489E-16 0.4489E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.94 -7.57 -2.524 0.12929E+05 -5.572 3 CH4,gas 4.81 -13.58 -18.39 -4.598 0.31407E+05 -16.394 4 H2,gas 8.29 0.09 -8.20 -4.685 0.14000E+05 -6.199 5 H2S,gas -5.94 -22.29 -16.35 -8.176 0.27920E+05 -14.351 6 S2,gas -7.03 -44.76 -37.73 -5.805 0.64424E+05 -35.731 7 CO,gas 3.51 -13.85 -17.36 -5.341 0.29638E+05 -15.358 8 SO3,gas 17.43 -22.64 -40.07 -10.018 0.68422E+05 -38.072 9 SO2,gas 1.14 -22.56 -23.69 -6.318 0.40456E+05 -21.694 10 HCl,gas 5.48 -12.87 -18.35 -9.174 0.31328E+05 -16.348 11 acmite 7.74 5.72 -2.02 -0.210 0.34443E+04 15 albite-high 0.75 -1.29 -2.04 -0.157 0.34815E+04 16 albite -0.33 -1.29 -0.96 -0.074 0.16409E+04 19 spessartine 24.55 20.67 -3.88 -0.194 0.66254E+04 20 analcite 3.37 2.03 -1.35 -0.150 0.22976E+04 21 andalusite 5.06 1.89 -3.17 -0.317 0.54119E+04 22 andradite 39.09 34.42 -4.67 -0.243 0.79753E+04 26 annite 20.21 16.50 -3.71 -0.206 0.63336E+04 27 phlogopite 27.15 23.18 -3.96 -0.220 0.67658E+04 29 anorthite 12.80 9.17 -3.63 -0.279 0.62011E+04 35 aragonite 0.99 -3.35 -4.33 -1.445 0.74005E+04 36 brucite 12.58 8.57 -4.01 -0.801 0.68399E+04 37 calcite 0.83 -3.35 -4.18 -1.394 0.71392E+04 38 carnegieite-low 9.06 5.34 -3.73 -0.532 0.63606E+04 39 carnegieite-high 10.13 5.34 -4.80 -0.685 0.81875E+04 40 carpholite-Mg 8.65 7.15 -1.50 -0.100 0.25632E+04 41 carpholite-Fe 6.78 4.92 -1.86 -0.124 0.31789E+04 42 celadonite 5.40 2.73 -2.67 -0.157 0.45626E+04 43 celadonite-Fe 3.94 0.50 -3.44 -0.202 0.58680E+04 44 chrysotile 23.94 19.08 -4.85 -0.404 0.82879E+04 50 chloritoid-Mg 13.26 10.46 -2.80 -0.187 0.47770E+04 51 chloritoid-Fe 9.24 8.24 -1.00 -0.067 0.17129E+04 52 chloritoid-Mn 11.46 10.36 -1.10 -0.073 0.18814E+04 54 coesite -2.37 -3.31 -0.95 -0.315 0.16136E+04 59 corundum 8.43 5.21 -3.23 -0.293 0.55087E+04 61 cristobalite -2.55 -3.31 -0.77 -0.255 0.13065E+04 63 cymrite-K 1.73 -2.53 -4.26 -0.355 0.72718E+04 65 diaspore 2.90 2.60 -0.29 -0.049 0.49941E+03 67 diopside 16.22 12.53 -3.69 -0.369 0.62938E+04 68 hedenbergite 14.24 10.30 -3.94 -0.394 0.67326E+04 75 epidote 24.78 22.74 -2.04 -0.099 0.34787E+04 76 clinozoisite 22.92 19.04 -3.88 -0.176 0.66224E+04 77 epidote-Fe 29.94 26.43 -3.50 -0.182 0.59825E+04 78 fayalite 14.08 9.37 -4.71 -0.673 0.80388E+04 83 gibbsite 4.10 2.60 -1.49 -0.213 0.25506E+04 87 greenalite 16.19 12.40 -3.79 -0.316 0.64798E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.03 -2.23 -0.223 0.38006E+04 97 kalsilite 7.62 4.10 -3.52 -0.503 0.60095E+04 98 kaolinite -1.27 -1.42 -0.15 -0.013 0.25334E+03 99 kyanite 4.93 1.89 -3.04 -0.304 0.51887E+04 101 laumontite 2.97 2.54 -0.44 -0.029 0.74671E+03 102 lawsonite 9.68 9.17 -0.51 -0.034 0.87496E+03 103 leucite 4.17 0.79 -3.38 -0.338 0.57735E+04 105 lizardite 23.29 19.08 -4.20 -0.350 0.71782E+04 107 magnetite 20.13 18.94 -1.19 -0.097 0.20362E+04 108 minnesotaite 10.46 5.77 -4.69 -0.276 0.80084E+04 113 margarite 17.45 14.37 -3.08 -0.123 0.52567E+04 116 microcline -2.43 -2.53 -0.10 -0.007 0.16428E+03 121 paragonite 4.34 3.92 -0.42 -0.025 0.71504E+03 122 nepheline 8.38 5.34 -3.04 -0.434 0.51886E+04 136 prehnite 19.47 16.44 -3.03 -0.178 0.51690E+04 137 prehnite-Fe 22.59 20.13 -2.45 -0.148 0.41876E+04 138 pumpellyite-Fe 46.47 41.82 -4.65 -0.103 0.79333E+04 145 pyroxmangite 7.42 5.15 -2.26 -0.452 0.38621E+04 146 pyrophyllite -6.10 -8.05 -1.95 -0.122 0.33333E+04 147 quartz -2.98 -3.31 -0.33 -0.111 0.56750E+03 151 rhodochrosite -0.96 -5.47 -4.51 -1.503 0.76979E+04 152 rhodonite 7.46 5.15 -2.31 -0.462 0.39413E+04 153 sanidine -1.22 -2.53 -1.31 -0.101 0.22320E+04 156 sillimanite 5.32 1.89 -3.43 -0.343 0.58541E+04 164 stilpnomelane-Fe 13.18 12.81 -0.37 -0.011 0.62832E+03 165 stilpnomelane-Mg 27.60 23.95 -3.64 -0.109 0.62231E+04 168 sudoite 21.22 17.61 -3.60 -0.116 0.61528E+04 171 talc 16.55 12.45 -4.10 -0.241 0.69984E+04 174 tephroite 18.11 13.62 -4.49 -0.641 0.76669E+04 177 topaz-H 4.67 1.89 -2.77 -0.252 0.47377E+04 178 tridymite -2.61 -3.31 -0.70 -0.233 0.11948E+04 187 wairakite 4.06 2.54 -1.52 -0.089 0.25975E+04 188 walstromite 11.53 7.27 -4.25 -0.851 0.72649E+04 189 wollastonite 10.48 7.27 -3.21 -0.642 0.54788E+04 190 pseudo-wollastonite 11.02 7.27 -3.75 -0.749 0.63974E+04 191 zoisite 22.96 19.04 -3.92 -0.178 0.66950E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.35 -2.79 -0.173 0.47650E+04 194 beidellite-H -2.24 -6.10 -3.86 -0.246 0.65844E+04 195 beidellite-K -1.44 -4.51 -3.07 -0.188 0.52496E+04 196 beidellite-Mg -1.71 -4.68 -2.98 -0.184 0.50819E+04 197 beidellite-Na -1.26 -4.10 -2.84 -0.174 0.48556E+04 199 chalcedony -2.79 -3.31 -0.52 -0.173 0.88781E+03 201 montmorillonite-Ca -2.21 -4.33 -2.12 -0.131 0.36201E+04 202 montmorillonite-K -2.16 -4.49 -2.33 -0.143 0.39824E+04 203 montmorillonite-Mg -2.40 -4.67 -2.27 -0.140 0.38679E+04 204 montmorillonite-Na -1.96 -4.08 -2.12 -0.130 0.36265E+04 205 nontronite-Ca 3.28 3.04 -0.24 -0.016 0.40914E+03 206 nontronite-H 2.60 1.29 -1.30 -0.087 0.22242E+04 207 nontronite-K 3.40 2.88 -0.52 -0.034 0.89288E+03 208 nontronite-Mg 3.14 2.71 -0.43 -0.028 0.73759E+03 209 nontronite-Na 3.58 3.29 -0.29 -0.019 0.50058E+03 224 tobermorite 9.84 5.50 -4.33 -1.183 0.74002E+04 233 boehmite 4.43 2.60 -1.83 -0.304 0.31178E+04 235 ferrous-oxide 9.82 6.34 -3.48 -0.870 0.59447E+04 240 silica-amorphous -2.08 -3.31 -1.23 -0.412 0.21080E+04 242 an20ab80 2.08 0.80 -1.28 -0.098 0.21813E+04 243 an25ab75 2.71 1.32 -1.38 -0.107 0.23643E+04 244 an30ab70 3.34 1.85 -1.50 -0.115 0.25557E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 0.8790000 g New total amount of reactant added: 0.9190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4566E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.9190000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .9325786E-03 Osmotic coef. = 0.9823 True ionic strength = .1409322E-02 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10808E-08 -8.9663 0.10115E-08 -8.9950 0.93592E+00 -0.0288 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12903E-03 -3.8893 0.93537E+00 -0.0290 4 SO4-- 0.25485E-04 -4.5937 0.20609E-04 -4.6859 0.80866E+00 -0.0922 5 HCO3- 0.11801E-04 -4.9281 0.11040E-04 -4.9570 0.93550E+00 -0.0290 6 HS- 0.51916E-13 -13.2847 0.48561E-13 -13.3137 0.93538E+00 -0.0290 7 Al+++ 0.62484E-24 -24.2042 0.39572E-24 -24.4026 0.63331E+00 -0.1984 8 H4SiO4 0.49697E-03 -3.3037 0.49697E-03 -3.3037 0.10000E+01 0.0000 9 Ca++ 0.45439E-07 -7.3426 0.36719E-07 -7.4351 0.80810E+00 -0.0925 10 Mg++ 0.47364E-09 -9.3245 0.38258E-09 -9.4173 0.80774E+00 -0.0927 11 Fe++ 0.28013E-11 -11.5526 0.22629E-11 -11.6453 0.80782E+00 -0.0927 12 K+ 0.75300E-04 -4.1232 0.70445E-04 -4.1521 0.93552E+00 -0.0289 13 Na+ 0.13040E-02 -2.8847 0.12197E-02 -2.9137 0.93536E+00 -0.0290 14 Mn++ 0.37427E-09 -9.4268 0.30237E-09 -9.5195 0.80789E+00 -0.0926 15 HPO4-- 0.31222E-05 -5.5055 0.25249E-05 -5.5978 0.80867E+00 -0.0922 16 HSiO3- 0.51247E-03 -3.2903 0.47935E-03 -3.3193 0.93537E+00 -0.0290 17 Ca(HSiO3)+ 0.42153E-09 -9.3752 0.39436E-09 -9.4041 0.93554E+00 -0.0289 18 Mg(HSiO3)+ 0.54659E-11 -11.2623 0.51136E-11 -11.2913 0.93554E+00 -0.0289 19 NaHSiO3,aq 0.92860E-05 -5.0322 0.92860E-05 -5.0322 0.10000E+01 0.0000 20 AlO+ 0.53367E-13 -13.2727 0.49927E-13 -13.3017 0.93554E+00 -0.0289 21 AlOH+2 0.31312E-18 -18.5043 0.25299E-18 -18.5969 0.80796E+00 -0.0926 22 HAlO2,aq 0.98770E-08 -8.0054 0.98770E-08 -8.0054 0.10000E+01 0.0000 23 AlO2- 0.23313E-04 -4.6324 0.21803E-04 -4.6615 0.93520E+00 -0.0291 24 CH4,aq 0.25534E-19 -19.5929 0.25527E-19 -19.5930 0.99971E+00 -0.0001 29 CO,aq 0.26979E-18 -18.5690 0.26979E-18 -18.5690 0.10000E+01 0.0000 30 CO2,aq 0.22522E-07 -7.6474 0.22516E-07 -7.6475 0.99971E+00 -0.0001 31 CO3-2 0.12481E-05 -5.9037 0.10091E-05 -5.9961 0.80850E+00 -0.0923 32 CaCO3,aq 0.45382E-09 -9.3431 0.45382E-09 -9.3431 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10918E-10 -10.9619 0.10214E-10 -10.9908 0.93554E+00 -0.0289 34 CaCl+ 0.80700E-11 -11.0931 0.75498E-11 -11.1221 0.93554E+00 -0.0289 35 CaCl2,aq 0.22682E-15 -15.6443 0.22682E-15 -15.6443 0.10000E+01 0.0000 36 CaOH+ 0.27360E-08 -8.5629 0.25596E-08 -8.5918 0.93554E+00 -0.0289 37 CaSO4,aq 0.23578E-09 -9.6275 0.23578E-09 -9.6275 0.10000E+01 0.0000 38 HCl,aq 0.24551E-13 -13.6099 0.24551E-13 -13.6099 0.10000E+01 0.0000 43 FeCl+ 0.48611E-15 -15.3133 0.45478E-15 -15.3422 0.93554E+00 -0.0289 46 FeO,aq 0.87456E-10 -10.0582 0.87456E-10 -10.0582 0.10000E+01 0.0000 47 FeOH+ 0.79276E-10 -10.1009 0.74166E-10 -10.1298 0.93554E+00 -0.0289 48 HFeO2- 0.99421E-09 -9.0025 0.92995E-09 -9.0315 0.93537E+00 -0.0290 49 FeO+ 0.89441E-14 -14.0485 0.83676E-14 -14.0774 0.93554E+00 -0.0289 51 FeO2- 0.17183E-08 -8.7649 0.16073E-08 -8.7939 0.93537E+00 -0.0290 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.46538E-09 -9.3322 0.46524E-09 -9.3323 0.99971E+00 -0.0001 54 KCl,aq 0.16095E-09 -9.7933 0.16095E-09 -9.7933 0.10000E+01 0.0000 55 KHSO4,aq 0.39297E-17 -17.4056 0.39297E-17 -17.4056 0.10000E+01 0.0000 56 KOH,aq 0.30360E-07 -7.5177 0.30360E-07 -7.5177 0.10000E+01 0.0000 57 KSO4- 0.23912E-07 -7.6214 0.22367E-07 -7.6504 0.93537E+00 -0.0290 58 MgCO3,aq 0.11815E-11 -11.9276 0.11815E-11 -11.9276 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11600E-12 -12.9355 0.10852E-12 -12.9645 0.93554E+00 -0.0289 60 MgCl+ 0.76332E-13 -13.1173 0.71412E-13 -13.1462 0.93554E+00 -0.0289 61 MgOH+ 0.15793E-09 -9.8015 0.14775E-09 -9.8305 0.93554E+00 -0.0289 63 MnO,aq 0.31195E-09 -9.5059 0.31195E-09 -9.5059 0.10000E+01 0.0000 64 MnOH+ 0.98402E-09 -9.0070 0.92059E-09 -9.0359 0.93554E+00 -0.0289 65 MnO2-2 0.13041E-13 -13.8847 0.10544E-13 -13.9770 0.80850E+00 -0.0923 66 HMnO2- 0.24704E-11 -11.6072 0.23107E-11 -11.6362 0.93537E+00 -0.0290 69 MnCl+ 0.25240E-12 -12.5979 0.23613E-12 -12.6269 0.93554E+00 -0.0289 70 MnSO4,aq 0.17660E-11 -11.7530 0.17660E-11 -11.7530 0.10000E+01 0.0000 71 NaCl,aq 0.51389E-07 -7.2891 0.51389E-07 -7.2891 0.10000E+01 0.0000 72 NaOH,aq 0.52984E-06 -6.2759 0.52984E-06 -6.2759 0.10000E+01 0.0000 74 OH- 0.63408E-03 -3.1979 0.59299E-03 -3.2270 0.93520E+00 -0.0291 79 HPO3-2 0.45891E-17 -17.3383 0.37103E-17 -17.4306 0.80850E+00 -0.0923 82 H3PO4,aq 0.16632E-13 -13.7790 0.16632E-13 -13.7790 0.10000E+01 0.0000 83 H2PO4- 0.47867E-07 -7.3200 0.44777E-07 -7.3489 0.93545E+00 -0.0290 84 PO4-3 0.34255E-08 -8.4653 0.21799E-08 -8.6616 0.63635E+00 -0.1963 87 H2P2O7-2 0.19409E-15 -15.7120 0.15692E-15 -15.8043 0.80850E+00 -0.0923 88 HP2O7-3 0.50225E-13 -13.2991 0.31810E-13 -13.4974 0.63335E+00 -0.1984 89 P2O7-4 0.17189E-13 -13.7648 0.77579E-14 -14.1103 0.45133E+00 -0.3455 90 H2S,aq 0.14763E-15 -15.8308 0.14759E-15 -15.8309 0.99971E+00 -0.0001 97 SO3-2 0.16147E-14 -14.7919 0.13073E-14 -14.8836 0.80964E+00 -0.0917 98 HSO3- 0.82737E-16 -16.0823 0.77389E-16 -16.1113 0.93537E+00 -0.0290 99 HSO4- 0.20673E-10 -10.6846 0.19343E-10 -10.7135 0.93563E+00 -0.0289 Charge balance for all species = 0.4567E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1080800E-08 -.1250875E-02 -.1260631E+01 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9998611E+06 0.0000 3 Cl- 0.1379478E-03 0.1379993E-03 0.4891808E+01 5.1057 4 SO4-- 0.2548495E-04 0.2550924E-04 0.2450117E+01 13.3041 5 HCO3- 0.1180125E-04 0.1307238E-04 0.7975289E+00 4.0380 6 HS- 0.5191595E-13 -.1238297E-09 -.4094723E-05 -4.3187 7 Al+++ 0.6248382E-24 0.2332301E-04 0.6292021E+00 2.5824 8 H4SiO4 0.4969740E-03 0.1018733E-02 0.9790231E+02 -3.3037 9 Ca++ 0.4543857E-07 0.4930465E-07 0.1975756E-02 10.5549 10 Mg++ 0.4736446E-09 0.6384127E-09 0.1551892E-04 8.5728 11 Fe++ 0.2801279E-11 0.3085553E-08 0.1722948E-03 6.3447 12 K+ 0.7530016E-04 0.7535460E-04 0.2946104E+01 4.8429 13 Na+ 0.1304012E-02 0.1313879E-02 0.3020161E+02 6.0813 14 Mn++ 0.3742666E-09 0.1674734E-08 0.9199372E-04 8.4706 15 HPO4-- 0.3122245E-05 0.3173537E-05 0.3045504E+00 12.3923 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1520424E-01 -.1250647E-02 -.1395359E-01 0.0000000E+00 2 H2O 0.5549673E+02 0.5549829E+02 -.1562218E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5097309E-04 0.2550459E-04 0.2546850E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2546862E-04 -.1238071E-09 -.2546850E-04 0.0000000E+00 7 Al+++ 0.2996622E-02 0.2331876E-04 0.2973303E-02 0.0000000E+00 8 H4SiO4 0.9569348E-02 0.1018548E-02 0.8550800E-02 0.0000000E+00 9 Ca++ 0.1071452E-02 0.4929566E-07 0.1071403E-02 0.0000000E+00 10 Mg++ 0.7293651E-03 0.6382964E-09 0.7293644E-03 0.0000000E+00 11 Fe++ 0.6552549E-03 0.3084991E-08 0.6552518E-03 0.0000000E+00 12 K+ 0.1951168E-03 0.7534086E-04 0.1197759E-03 0.0000000E+00 13 Na+ 0.1313640E-02 0.1313640E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1593417E-04 0.1674429E-08 0.1593250E-04 0.0000000E+00 15 HPO4-- 0.5438253E-05 0.3172959E-05 0.2265294E-05 0.0000000E+00 Chg. balance for solid moles: -.6776E-19 Mass of aqueous solution: 0.999957E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.9190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7551E-06 -6.122 0.3793E-03 -3.421 0.3933E-01 0.1205E-03 clinochlore 0.1459E-03 -3.836 0.8108E-01 -1.091 8.406 0.3084E-01 daphnite 0.9030E-04 -4.044 0.6443E-01 -1.191 6.680 0.1952E-01 chlorite-Mn 0.3186E-05 -5.497 0.2259E-02 -2.646 0.2342 0.7199E-03 hematite 0.1019E-03 -3.992 0.1627E-01 -1.789 1.687 0.3084E-02 muscovite 0.1198E-03 -3.922 0.4771E-01 -1.321 4.946 0.1687E-01 stilbite 0.1068E-02 -2.972 0.7524 -0.124 78.01 0.3509 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.964505 g Volume = 0.422082 cm3 Porosity: 69.1370% V(tot) - V(min): 0.94552E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.9190000 g log = -0.0367 Original solution: 1000.0103000 g Original solution / Rock added: 1088.15 (Water/Rock Ratio), log = 3.0367 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2432E-05 1.0073 0.2577E-05 0.2559E-05 CH4,gas 0.3788E-16 1.0129 0.4037E-16 0.3985E-16 H2,gas 0.6063E-06 1.0006 0.6381E-06 0.6378E-06 H2S,gas 0.4109E-14 0.9959 0.4305E-14 0.4322E-14 S2,gas 0.1620E-35 1.0000 0.1704E-35 0.1704E-35 CO,gas 0.4050E-15 1.0000 0.4260E-15 0.4260E-15 SO3,gas 0.7494E-38 1.0000 0.7883E-38 0.7883E-38 SO2,gas 0.1809E-21 1.0000 0.1903E-21 0.1903E-21 HCl,gas 0.4121E-16 1.0000 0.4335E-16 0.4335E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.15165E-10 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.95 -7.59 -2.530 0.12958E+05 -5.589 3 CH4,gas 4.81 -13.58 -18.39 -4.598 0.31407E+05 -16.394 4 H2,gas 8.29 0.09 -8.20 -4.683 0.13993E+05 -6.195 5 H2S,gas -5.94 -22.31 -16.37 -8.183 0.27945E+05 -14.366 6 S2,gas -7.03 -44.80 -37.77 -5.811 0.64489E+05 -35.768 7 CO,gas 3.51 -13.86 -17.37 -5.345 0.29660E+05 -15.371 8 SO3,gas 17.43 -22.68 -40.10 -10.026 0.68475E+05 -38.103 9 SO2,gas 1.14 -22.58 -23.72 -6.325 0.40502E+05 -21.721 10 HCl,gas 5.48 -12.88 -18.36 -9.182 0.31354E+05 -16.363 11 acmite 7.74 5.77 -1.96 -0.204 0.33546E+04 15 albite-high 0.75 -1.25 -2.00 -0.154 0.34097E+04 16 albite -0.33 -1.25 -0.92 -0.071 0.15690E+04 19 spessartine 24.55 20.67 -3.88 -0.194 0.66323E+04 20 analcite 3.37 2.06 -1.31 -0.146 0.22440E+04 21 andalusite 5.06 1.86 -3.20 -0.320 0.54659E+04 22 andradite 39.09 34.35 -4.74 -0.246 0.80872E+04 26 annite 20.21 16.55 -3.66 -0.203 0.62509E+04 27 phlogopite 27.15 23.23 -3.91 -0.217 0.66831E+04 29 anorthite 12.80 9.11 -3.69 -0.283 0.62924E+04 35 aragonite 0.99 -3.40 -4.38 -1.461 0.74844E+04 36 brucite 12.58 8.57 -4.00 -0.801 0.68364E+04 37 calcite 0.83 -3.40 -4.23 -1.410 0.72231E+04 38 carnegieite-low 9.06 5.36 -3.70 -0.529 0.63253E+04 39 carnegieite-high 10.13 5.36 -4.77 -0.682 0.81522E+04 40 carpholite-Mg 8.65 7.13 -1.52 -0.101 0.25955E+04 41 carpholite-Fe 6.78 4.90 -1.88 -0.125 0.32111E+04 42 celadonite 5.40 2.78 -2.62 -0.154 0.44686E+04 43 celadonite-Fe 3.94 0.56 -3.38 -0.199 0.57740E+04 44 chrysotile 23.94 19.11 -4.83 -0.402 0.82409E+04 50 chloritoid-Mg 13.26 10.43 -2.83 -0.188 0.48275E+04 51 chloritoid-Fe 9.24 8.21 -1.03 -0.069 0.17634E+04 52 chloritoid-Mn 11.46 10.33 -1.13 -0.075 0.19319E+04 54 coesite -2.37 -3.30 -0.93 -0.311 0.15953E+04 59 corundum 8.43 5.16 -3.27 -0.297 0.55809E+04 61 cristobalite -2.55 -3.30 -0.75 -0.251 0.12882E+04 63 cymrite-K 1.73 -2.49 -4.22 -0.351 0.71995E+04 65 diaspore 2.90 2.58 -0.31 -0.052 0.53554E+03 67 diopside 16.22 12.52 -3.70 -0.370 0.63093E+04 68 hedenbergite 14.24 10.29 -3.95 -0.395 0.67481E+04 75 epidote 24.78 22.66 -2.11 -0.102 0.36073E+04 76 clinozoisite 22.92 18.95 -3.97 -0.181 0.67872E+04 77 epidote-Fe 29.94 26.38 -3.56 -0.185 0.60750E+04 78 fayalite 14.08 9.39 -4.69 -0.670 0.80135E+04 83 gibbsite 4.10 2.58 -1.51 -0.216 0.25867E+04 87 greenalite 16.19 12.43 -3.77 -0.314 0.64328E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.06 -2.19 -0.219 0.37471E+04 97 kalsilite 7.62 4.12 -3.50 -0.500 0.59738E+04 98 kaolinite -1.27 -1.44 -0.17 -0.015 0.28909E+03 99 kyanite 4.93 1.86 -3.07 -0.307 0.52427E+04 101 laumontite 2.97 2.51 -0.47 -0.031 0.80149E+03 102 lawsonite 9.68 9.11 -0.57 -0.038 0.96626E+03 103 leucite 4.17 0.82 -3.35 -0.335 0.57195E+04 105 lizardite 23.29 19.11 -4.18 -0.348 0.71312E+04 107 magnetite 20.13 18.94 -1.19 -0.097 0.20327E+04 108 minnesotaite 10.46 5.82 -4.64 -0.273 0.79248E+04 113 margarite 17.45 14.28 -3.17 -0.127 0.54203E+04 116 microcline -2.43 -2.49 -0.05 -0.004 0.92023E+02 121 paragonite 4.34 3.92 -0.42 -0.025 0.71547E+03 122 nepheline 8.38 5.36 -3.02 -0.431 0.51533E+04 136 prehnite 19.47 16.36 -3.10 -0.183 0.52976E+04 137 prehnite-Fe 22.59 20.08 -2.51 -0.151 0.42801E+04 138 pumpellyite-Fe 46.47 41.65 -4.82 -0.107 0.82231E+04 145 pyroxmangite 7.42 5.17 -2.25 -0.450 0.38403E+04 146 pyrophyllite -6.10 -8.05 -1.95 -0.122 0.33326E+04 147 quartz -2.98 -3.30 -0.32 -0.107 0.54924E+03 151 rhodochrosite -0.96 -5.48 -4.52 -1.508 0.77228E+04 152 rhodonite 7.46 5.17 -2.30 -0.459 0.39196E+04 153 sanidine -1.22 -2.49 -1.26 -0.097 0.21598E+04 156 sillimanite 5.32 1.86 -3.46 -0.346 0.59081E+04 164 stilpnomelane-Fe 13.18 12.88 -0.30 -0.009 0.51022E+03 165 stilpnomelane-Mg 27.60 24.02 -3.58 -0.107 0.61050E+04 168 sudoite 21.22 17.56 -3.65 -0.118 0.62355E+04 171 talc 16.55 12.50 -4.05 -0.238 0.69149E+04 174 tephroite 18.11 13.64 -4.48 -0.639 0.76417E+04 177 topaz-H 4.67 1.86 -2.81 -0.255 0.47917E+04 178 tridymite -2.61 -3.30 -0.69 -0.230 0.11765E+04 187 wairakite 4.06 2.51 -1.55 -0.091 0.26523E+04 188 walstromite 11.53 7.25 -4.28 -0.855 0.73022E+04 189 wollastonite 10.48 7.25 -3.23 -0.646 0.55161E+04 190 pseudo-wollastonite 11.02 7.25 -3.77 -0.754 0.64347E+04 191 zoisite 22.96 18.95 -4.02 -0.183 0.68597E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.37 -2.81 -0.174 0.47914E+04 194 beidellite-H -2.24 -6.11 -3.87 -0.247 0.66015E+04 195 beidellite-K -1.44 -4.51 -3.07 -0.188 0.52491E+04 196 beidellite-Mg -1.71 -4.69 -2.99 -0.185 0.50985E+04 197 beidellite-Na -1.26 -4.10 -2.84 -0.174 0.48552E+04 199 chalcedony -2.79 -3.30 -0.51 -0.170 0.86955E+03 201 montmorillonite-Ca -2.21 -4.33 -2.12 -0.131 0.36154E+04 202 montmorillonite-K -2.16 -4.47 -2.31 -0.142 0.39508E+04 203 montmorillonite-Mg -2.40 -4.66 -2.26 -0.140 0.38535E+04 204 montmorillonite-Na -1.96 -4.07 -2.11 -0.129 0.35951E+04 205 nontronite-Ca 3.28 3.07 -0.21 -0.014 0.36322E+03 206 nontronite-H 2.60 1.33 -1.27 -0.085 0.21691E+04 207 nontronite-K 3.40 2.92 -0.48 -0.031 0.82010E+03 208 nontronite-Mg 3.14 2.74 -0.40 -0.026 0.68192E+03 209 nontronite-Na 3.58 3.33 -0.25 -0.016 0.42794E+03 224 tobermorite 9.84 5.49 -4.35 -1.187 0.74282E+04 233 boehmite 4.43 2.58 -1.85 -0.308 0.31540E+04 235 ferrous-oxide 9.82 6.34 -3.48 -0.870 0.59412E+04 240 silica-amorphous -2.08 -3.30 -1.22 -0.408 0.20898E+04 242 an20ab80 2.08 0.82 -1.25 -0.097 0.21421E+04 243 an25ab75 2.71 1.34 -1.37 -0.105 0.23333E+04 244 an30ab70 3.34 1.86 -1.48 -0.114 0.25328E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 0.9190000 g New total amount of reactant added: 0.9590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4566E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.9590000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .9590805E-03 Osmotic coef. = 0.9821 True ionic strength = .1462233E-02 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10470E-08 -8.9800 0.97910E-09 -9.0092 0.93513E+00 -0.0291 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12892E-03 -3.8897 0.93456E+00 -0.0294 4 SO4-- 0.25484E-04 -4.5937 0.20538E-04 -4.6874 0.80591E+00 -0.0937 5 HCO3- 0.11762E-04 -4.9295 0.10994E-04 -4.9589 0.93469E+00 -0.0293 6 HS- 0.52090E-13 -13.2832 0.48682E-13 -13.3126 0.93457E+00 -0.0294 7 Al+++ 0.54518E-24 -24.2635 0.34261E-24 -24.4652 0.62844E+00 -0.2017 8 H4SiO4 0.50846E-03 -3.2937 0.50846E-03 -3.2937 0.10000E+01 0.0000 9 Ca++ 0.39935E-07 -7.3986 0.32161E-07 -7.4927 0.80532E+00 -0.0940 10 Mg++ 0.44744E-09 -9.3493 0.36017E-09 -9.4435 0.80495E+00 -0.0942 11 Fe++ 0.26463E-11 -11.5774 0.21304E-11 -11.6715 0.80504E+00 -0.0942 12 K+ 0.78269E-04 -4.1064 0.73159E-04 -4.1357 0.93472E+00 -0.0293 13 Na+ 0.13533E-02 -2.8686 0.12647E-02 -2.8980 0.93455E+00 -0.0294 14 Mn++ 0.35356E-09 -9.4515 0.28465E-09 -9.5457 0.80511E+00 -0.0941 15 HPO4-- 0.37412E-05 -5.4270 0.30151E-05 -5.5207 0.80592E+00 -0.0937 16 HSiO3- 0.54216E-03 -3.2659 0.50668E-03 -3.2953 0.93456E+00 -0.0294 17 Ca(HSiO3)+ 0.39059E-09 -9.4083 0.36510E-09 -9.4376 0.93474E+00 -0.0293 18 Mg(HSiO3)+ 0.54438E-11 -11.2641 0.50885E-11 -11.2934 0.93474E+00 -0.0293 19 NaHSiO3,aq 0.10178E-04 -4.9924 0.10178E-04 -4.9924 0.10000E+01 0.0000 20 AlO+ 0.49360E-13 -13.3066 0.46138E-13 -13.3359 0.93474E+00 -0.0293 21 AlOH+2 0.28105E-18 -18.5512 0.22630E-18 -18.6453 0.80519E+00 -0.0941 22 HAlO2,aq 0.94299E-08 -8.0255 0.94299E-08 -8.0255 0.10000E+01 0.0000 23 AlO2- 0.23015E-04 -4.6380 0.21505E-04 -4.6675 0.93439E+00 -0.0295 24 CH4,aq 0.25578E-19 -19.5921 0.25571E-19 -19.5923 0.99970E+00 -0.0001 29 CO,aq 0.26256E-18 -18.5808 0.26256E-18 -18.5808 0.10000E+01 0.0000 30 CO2,aq 0.21709E-07 -7.6634 0.21702E-07 -7.6635 0.99970E+00 -0.0001 31 CO3-2 0.12885E-05 -5.8899 0.10382E-05 -5.9837 0.80573E+00 -0.0938 32 CaCO3,aq 0.40893E-09 -9.3884 0.40893E-09 -9.3884 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.95309E-11 -11.0209 0.89089E-11 -11.0502 0.93474E+00 -0.0293 34 CaCl+ 0.70681E-11 -11.1507 0.66069E-11 -11.1800 0.93474E+00 -0.0293 35 CaCl2,aq 0.19832E-15 -15.7026 0.19832E-15 -15.7026 0.10000E+01 0.0000 36 CaOH+ 0.24779E-08 -8.6059 0.23162E-08 -8.6352 0.93474E+00 -0.0293 37 CaSO4,aq 0.20580E-09 -9.6865 0.20580E-09 -9.6865 0.10000E+01 0.0000 38 HCl,aq 0.23743E-13 -13.6245 0.23743E-13 -13.6245 0.10000E+01 0.0000 43 FeCl+ 0.45763E-15 -15.3395 0.42776E-15 -15.3688 0.93474E+00 -0.0293 46 FeO,aq 0.87878E-10 -10.0561 0.87878E-10 -10.0561 0.10000E+01 0.0000 47 FeOH+ 0.77171E-10 -10.1125 0.72134E-10 -10.1419 0.93474E+00 -0.0293 48 HFeO2- 0.10330E-08 -8.9859 0.96540E-09 -9.0153 0.93456E+00 -0.0294 49 FeO+ 0.86647E-14 -14.0622 0.80993E-14 -14.0916 0.93474E+00 -0.0293 51 FeO2- 0.17768E-08 -8.7504 0.16605E-08 -8.7798 0.93456E+00 -0.0294 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.46988E-09 -9.3280 0.46974E-09 -9.3281 0.99970E+00 -0.0001 54 KCl,aq 0.16700E-09 -9.7773 0.16700E-09 -9.7773 0.10000E+01 0.0000 55 KHSO4,aq 0.39367E-17 -17.4049 0.39367E-17 -17.4049 0.10000E+01 0.0000 56 KOH,aq 0.32574E-07 -7.4871 0.32574E-07 -7.4871 0.10000E+01 0.0000 57 KSO4- 0.24770E-07 -7.6061 0.23149E-07 -7.6355 0.93456E+00 -0.0294 58 MgCO3,aq 0.11443E-11 -11.9414 0.11443E-11 -11.9414 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10884E-12 -12.9632 0.10174E-12 -12.9925 0.93474E+00 -0.0293 60 MgCl+ 0.71859E-13 -13.1435 0.67170E-13 -13.1728 0.93474E+00 -0.0293 61 MgOH+ 0.15373E-09 -9.8132 0.14370E-09 -9.8425 0.93474E+00 -0.0293 63 MnO,aq 0.31346E-09 -9.5038 0.31346E-09 -9.5038 0.10000E+01 0.0000 64 MnOH+ 0.95789E-09 -9.0187 0.89538E-09 -9.0480 0.93474E+00 -0.0293 65 MnO2-2 0.14035E-13 -13.8528 0.11308E-13 -13.9466 0.80573E+00 -0.0938 66 HMnO2- 0.25668E-11 -11.5906 0.23988E-11 -11.6200 0.93456E+00 -0.0294 69 MnCl+ 0.23761E-12 -12.6241 0.22210E-12 -12.6534 0.93474E+00 -0.0293 70 MnSO4,aq 0.16568E-11 -11.7807 0.16568E-11 -11.7807 0.10000E+01 0.0000 71 NaCl,aq 0.53240E-07 -7.2738 0.53240E-07 -7.2738 0.10000E+01 0.0000 72 NaOH,aq 0.56759E-06 -6.2460 0.56759E-06 -6.2460 0.10000E+01 0.0000 74 OH- 0.65566E-03 -3.1833 0.61264E-03 -3.2128 0.93439E+00 -0.0295 79 HPO3-2 0.55521E-17 -17.2555 0.44735E-17 -17.3494 0.80573E+00 -0.0938 82 H3PO4,aq 0.18608E-13 -13.7303 0.18608E-13 -13.7303 0.10000E+01 0.0000 83 H2PO4- 0.55375E-07 -7.2567 0.51756E-07 -7.2860 0.93465E+00 -0.0294 84 PO4-3 0.42582E-08 -8.3708 0.26893E-08 -8.5704 0.63156E+00 -0.1996 87 H2P2O7-2 0.26019E-15 -15.5847 0.20965E-15 -15.6785 0.80573E+00 -0.0938 88 HP2O7-3 0.69862E-13 -13.1558 0.43907E-13 -13.3575 0.62848E+00 -0.2017 89 P2O7-4 0.24848E-13 -13.6047 0.11063E-13 -13.9561 0.44522E+00 -0.3514 90 H2S,aq 0.14325E-15 -15.8439 0.14321E-15 -15.8440 0.99970E+00 -0.0001 97 SO3-2 0.16302E-14 -14.7878 0.13154E-14 -14.8809 0.80691E+00 -0.0932 98 HSO3- 0.80651E-16 -16.0934 0.75373E-16 -16.1228 0.93456E+00 -0.0294 99 HSO4- 0.19959E-10 -10.6999 0.18658E-10 -10.7291 0.93483E+00 -0.0293 Charge balance for all species = 0.4567E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1047025E-08 -.1301913E-02 -.1312061E+01 0.0000 2 H2O 0.1000000E+01 0.5550840E+02 0.9998558E+06 0.0000 3 Cl- 0.1379470E-03 0.1380004E-03 0.4891820E+01 5.1195 4 SO4-- 0.2548432E-04 0.2550944E-04 0.2450124E+01 13.3309 5 HCO3- 0.1176187E-04 0.1307248E-04 0.7975309E+00 4.0503 6 HS- 0.5209031E-13 -.1300105E-09 -.4299087E-05 -4.3035 7 Al+++ 0.5451797E-24 0.2302469E-04 0.6211509E+00 2.5623 8 H4SiO4 0.5084641E-03 0.1060803E-02 0.1019447E+03 -3.2937 9 Ca++ 0.3993531E-07 0.4343509E-07 0.1740540E-02 10.5257 10 Mg++ 0.4474388E-09 0.6079413E-09 0.1477813E-04 8.5748 11 Fe++ 0.2646280E-11 0.3180965E-08 0.1776216E-03 6.3468 12 K+ 0.7826852E-04 0.7832603E-04 0.3062261E+01 4.8734 13 Na+ 0.1353310E-02 0.1364109E-02 0.3135605E+02 6.1112 14 Mn++ 0.3535593E-09 0.1629379E-08 0.8950187E-04 8.4727 15 HPO4-- 0.3741190E-05 0.3800824E-05 0.3647465E+00 12.4976 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1586658E-01 -.1301666E-02 -.1456491E-01 0.0000000E+00 2 H2O 0.5549623E+02 0.5549786E+02 -.1630957E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5208163E-04 0.2550460E-04 0.2657703E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2657716E-04 -.1299859E-09 -.2657703E-04 0.0000000E+00 7 Al+++ 0.3127051E-02 0.2302032E-04 0.3104031E-02 0.0000000E+00 8 H4SiO4 0.9985859E-02 0.1060601E-02 0.8925258E-02 0.0000000E+00 9 Ca++ 0.1117458E-02 0.4342684E-07 0.1117414E-02 0.0000000E+00 10 Mg++ 0.7611111E-03 0.6078258E-09 0.7611105E-03 0.0000000E+00 11 Fe++ 0.6837752E-03 0.3180361E-08 0.6837721E-03 0.0000000E+00 12 K+ 0.2036093E-03 0.7831116E-04 0.1252982E-03 0.0000000E+00 13 Na+ 0.1363850E-02 0.1363850E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1662771E-04 0.1629069E-08 0.1662608E-04 0.0000000E+00 15 HPO4-- 0.5674956E-05 0.3800102E-05 0.1874854E-05 0.0000000E+00 Chg. balance for solid moles: -.1345E-17 Mass of aqueous solution: 0.999955E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.9590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6250E-06 -6.204 0.3139E-03 -3.503 0.3118E-01 0.9975E-04 clinochlore 0.1522E-03 -3.818 0.8461E-01 -1.073 8.405 0.3218E-01 daphnite 0.9423E-04 -4.026 0.6723E-01 -1.172 6.679 0.2037E-01 chlorite-Mn 0.3325E-05 -5.478 0.2357E-02 -2.628 0.2342 0.7513E-03 hematite 0.1063E-03 -3.973 0.1698E-01 -1.770 1.687 0.3218E-02 muscovite 0.1253E-03 -3.902 0.4991E-01 -1.302 4.958 0.1765E-01 stilbite 0.1114E-02 -2.953 0.7853 -0.105 78.01 0.3663 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.006663 g Volume = 0.440534 cm3 Porosity: 68.1603% V(tot) - V(min): 0.94307E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.9590000 g log = -0.0182 Original solution: 1000.0103000 g Original solution / Rock added: 1042.76 (Water/Rock Ratio), log = 3.0182 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2344E-05 1.0073 0.2484E-05 0.2466E-05 CH4,gas 0.3795E-16 1.0129 0.4044E-16 0.3992E-16 H2,gas 0.6121E-06 1.0006 0.6443E-06 0.6439E-06 H2S,gas 0.3987E-14 0.9959 0.4177E-14 0.4194E-14 S2,gas 0.1496E-35 1.0000 0.1574E-35 0.1574E-35 CO,gas 0.3941E-15 1.0000 0.4146E-15 0.4146E-15 SO3,gas 0.6997E-38 1.0000 0.7361E-38 0.7361E-38 SO2,gas 0.1705E-21 1.0000 0.1794E-21 0.1794E-21 HCl,gas 0.3985E-16 1.0000 0.4192E-16 0.4192E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 120 muscovite 2.68 2.68 0.00 0.000 0.30331E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.97 -7.60 -2.535 0.12985E+05 -5.605 3 CH4,gas 4.81 -13.58 -18.39 -4.598 0.31406E+05 -16.393 4 H2,gas 8.29 0.10 -8.19 -4.681 0.13986E+05 -6.191 5 H2S,gas -5.94 -22.32 -16.38 -8.190 0.27967E+05 -14.379 6 S2,gas -7.03 -44.84 -37.80 -5.816 0.64548E+05 -35.803 7 CO,gas 3.51 -13.87 -17.38 -5.348 0.29680E+05 -15.382 8 SO3,gas 17.43 -22.71 -40.13 -10.033 0.68526E+05 -38.133 9 SO2,gas 1.14 -22.61 -23.75 -6.332 0.40546E+05 -21.746 10 HCl,gas 5.48 -12.90 -18.38 -9.189 0.31379E+05 -16.378 11 acmite 7.74 5.82 -1.91 -0.199 0.32696E+04 15 albite-high 0.75 -1.21 -1.96 -0.151 0.33421E+04 16 albite -0.33 -1.21 -0.88 -0.068 0.15015E+04 19 spessartine 24.55 20.66 -3.89 -0.194 0.66395E+04 20 analcite 3.37 2.09 -1.28 -0.143 0.21935E+04 21 andalusite 5.06 1.83 -3.23 -0.323 0.55176E+04 22 andradite 39.09 34.29 -4.79 -0.249 0.81862E+04 26 annite 20.21 16.59 -3.61 -0.201 0.61715E+04 27 phlogopite 27.15 23.28 -3.87 -0.215 0.66036E+04 29 anorthite 12.80 9.06 -3.73 -0.287 0.63771E+04 35 aragonite 0.99 -3.44 -4.43 -1.476 0.75617E+04 36 brucite 12.58 8.57 -4.00 -0.800 0.68329E+04 37 calcite 0.83 -3.44 -4.28 -1.425 0.73003E+04 38 carnegieite-low 9.06 5.38 -3.68 -0.526 0.62917E+04 39 carnegieite-high 10.13 5.38 -4.75 -0.679 0.81185E+04 40 carpholite-Mg 8.65 7.11 -1.54 -0.103 0.26267E+04 41 carpholite-Fe 6.78 4.88 -1.90 -0.127 0.32424E+04 42 celadonite 5.40 2.84 -2.56 -0.151 0.43794E+04 43 celadonite-Fe 3.94 0.61 -3.33 -0.196 0.56847E+04 44 chrysotile 23.94 19.14 -4.80 -0.400 0.81963E+04 50 chloritoid-Mg 13.26 10.41 -2.86 -0.190 0.48757E+04 51 chloritoid-Fe 9.24 8.18 -1.06 -0.071 0.18116E+04 52 chloritoid-Mn 11.46 10.30 -1.16 -0.077 0.19801E+04 54 coesite -2.37 -3.29 -0.92 -0.308 0.15784E+04 59 corundum 8.43 5.12 -3.31 -0.301 0.56496E+04 61 cristobalite -2.55 -3.29 -0.74 -0.248 0.12713E+04 63 cymrite-K 1.73 -2.45 -4.18 -0.348 0.71308E+04 65 diaspore 2.90 2.56 -0.33 -0.056 0.56989E+03 67 diopside 16.22 12.51 -3.70 -0.370 0.63218E+04 68 hedenbergite 14.24 10.28 -3.96 -0.396 0.67606E+04 75 epidote 24.78 22.59 -2.18 -0.106 0.37251E+04 76 clinozoisite 22.92 18.86 -4.06 -0.185 0.69393E+04 77 epidote-Fe 29.94 26.33 -3.61 -0.187 0.61584E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79894E+04 83 gibbsite 4.10 2.56 -1.54 -0.219 0.26211E+04 87 greenalite 16.19 12.45 -3.74 -0.312 0.63881E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.09 -2.16 -0.216 0.36965E+04 97 kalsilite 7.62 4.14 -3.48 -0.497 0.59390E+04 98 kaolinite -1.27 -1.46 -0.19 -0.017 0.32389E+03 99 kyanite 4.93 1.83 -3.10 -0.310 0.52944E+04 101 laumontite 2.97 2.48 -0.50 -0.033 0.85234E+03 102 lawsonite 9.68 9.06 -0.62 -0.041 0.10510E+04 103 leucite 4.17 0.85 -3.32 -0.332 0.56677E+04 105 lizardite 23.29 19.14 -4.15 -0.346 0.70866E+04 107 magnetite 20.13 18.94 -1.19 -0.097 0.20291E+04 108 minnesotaite 10.46 5.87 -4.60 -0.270 0.78463E+04 113 margarite 17.45 14.19 -3.26 -0.131 0.55737E+04 116 microcline -2.43 -2.45 -0.01 -0.001 0.23323E+02 121 paragonite 4.34 3.92 -0.42 -0.025 0.71663E+03 122 nepheline 8.38 5.38 -3.00 -0.428 0.51196E+04 136 prehnite 19.47 16.29 -3.17 -0.187 0.54153E+04 137 prehnite-Fe 22.59 20.03 -2.56 -0.154 0.43635E+04 138 pumpellyite-Fe 46.47 41.50 -4.97 -0.110 0.84894E+04 145 pyroxmangite 7.42 5.18 -2.24 -0.447 0.38198E+04 146 pyrophyllite -6.10 -8.05 -1.95 -0.122 0.33335E+04 147 quartz -2.98 -3.29 -0.31 -0.104 0.53229E+03 151 rhodochrosite -0.96 -5.50 -4.54 -1.512 0.77465E+04 152 rhodonite 7.46 5.18 -2.28 -0.457 0.38990E+04 153 sanidine -1.22 -2.45 -1.22 -0.094 0.20911E+04 156 sillimanite 5.32 1.83 -3.49 -0.349 0.59598E+04 164 stilpnomelane-Fe 13.18 12.95 -0.23 -0.007 0.39937E+03 165 stilpnomelane-Mg 27.60 24.09 -3.51 -0.105 0.59942E+04 168 sudoite 21.22 17.52 -3.70 -0.119 0.63149E+04 171 talc 16.55 12.55 -4.00 -0.236 0.68363E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76176E+04 177 topaz-H 4.67 1.83 -2.84 -0.258 0.48435E+04 178 tridymite -2.61 -3.29 -0.68 -0.226 0.11596E+04 187 wairakite 4.06 2.48 -1.58 -0.093 0.27032E+04 188 walstromite 11.53 7.23 -4.30 -0.859 0.73352E+04 189 wollastonite 10.48 7.23 -3.25 -0.650 0.55491E+04 190 pseudo-wollastonite 11.02 7.23 -3.79 -0.758 0.64677E+04 191 zoisite 22.96 18.86 -4.11 -0.187 0.70118E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.38 -2.82 -0.175 0.48175E+04 194 beidellite-H -2.24 -6.12 -3.88 -0.247 0.66194E+04 195 beidellite-K -1.44 -4.51 -3.07 -0.188 0.52497E+04 196 beidellite-Mg -1.71 -4.70 -3.00 -0.185 0.51157E+04 197 beidellite-Na -1.26 -4.10 -2.84 -0.174 0.48562E+04 199 chalcedony -2.79 -3.29 -0.50 -0.166 0.85260E+03 201 montmorillonite-Ca -2.21 -4.33 -2.12 -0.131 0.36120E+04 202 montmorillonite-K -2.16 -4.46 -2.30 -0.141 0.39220E+04 203 montmorillonite-Mg -2.40 -4.65 -2.25 -0.139 0.38413E+04 204 montmorillonite-Na -1.96 -4.05 -2.09 -0.128 0.35667E+04 205 nontronite-Ca 3.28 3.09 -0.19 -0.012 0.32059E+03 206 nontronite-H 2.60 1.36 -1.24 -0.083 0.21182E+04 207 nontronite-K 3.40 2.96 -0.44 -0.028 0.75201E+03 208 nontronite-Mg 3.14 2.77 -0.37 -0.024 0.63047E+03 209 nontronite-Na 3.58 3.37 -0.21 -0.014 0.36023E+03 224 tobermorite 9.84 5.47 -4.36 -1.191 0.74529E+04 233 boehmite 4.43 2.56 -1.87 -0.311 0.31883E+04 235 ferrous-oxide 9.82 6.35 -3.48 -0.869 0.59376E+04 240 silica-amorphous -2.08 -3.29 -1.21 -0.405 0.20728E+04 242 an20ab80 2.08 0.85 -1.23 -0.095 0.21050E+04 243 an25ab75 2.71 1.36 -1.35 -0.104 0.23038E+04 244 an30ab70 3.34 1.87 -1.47 -0.113 0.25109E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 0.9590000 g New total amount of reactant added: 0.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4567E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.9990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .9858521E-03 Osmotic coef. = 0.9818 True ionic strength = .1515243E-02 Chg. balance for total moles = 0.4567E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10156E-08 -8.9933 0.94894E-09 -9.0228 0.93435E+00 -0.0295 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12881E-03 -3.8901 0.93377E+00 -0.0298 4 SO4-- 0.25484E-04 -4.5937 0.20469E-04 -4.6889 0.80321E+00 -0.0952 5 HCO3- 0.11723E-04 -4.9310 0.10948E-04 -4.9607 0.93391E+00 -0.0297 6 HS- 0.52369E-13 -13.2809 0.48901E-13 -13.3107 0.93378E+00 -0.0298 7 Al+++ 0.47852E-24 -24.3201 0.29845E-24 -24.5251 0.62369E+00 -0.2050 8 H4SiO4 0.51939E-03 -3.2845 0.51939E-03 -3.2845 0.10000E+01 0.0000 9 Ca++ 0.35428E-07 -7.4507 0.28435E-07 -7.5462 0.80261E+00 -0.0955 10 Mg++ 0.42379E-09 -9.3728 0.33998E-09 -9.4686 0.80223E+00 -0.0957 11 Fe++ 0.25064E-11 -11.6009 0.20109E-11 -11.6966 0.80232E+00 -0.0957 12 K+ 0.81312E-04 -4.0898 0.75940E-04 -4.1195 0.93393E+00 -0.0297 13 Na+ 0.14026E-02 -2.8531 0.13097E-02 -2.8828 0.93375E+00 -0.0298 14 Mn++ 0.33487E-09 -9.4751 0.26870E-09 -9.5707 0.80239E+00 -0.0956 15 HPO4-- 0.44205E-05 -5.3545 0.35507E-05 -5.4497 0.80322E+00 -0.0952 16 HSiO3- 0.57190E-03 -3.2427 0.53402E-03 -3.2724 0.93377E+00 -0.0298 17 Ca(HSiO3)+ 0.36428E-09 -9.4386 0.34022E-09 -9.4682 0.93395E+00 -0.0297 18 Mg(HSiO3)+ 0.54204E-11 -11.2660 0.50624E-11 -11.2956 0.93395E+00 -0.0297 19 NaHSiO3,aq 0.11108E-04 -4.9544 0.11108E-04 -4.9544 0.10000E+01 0.0000 20 AlO+ 0.45813E-13 -13.3390 0.42787E-13 -13.3687 0.93395E+00 -0.0297 21 AlOH+2 0.25346E-18 -18.5961 0.20339E-18 -18.6917 0.80247E+00 -0.0956 22 HAlO2,aq 0.90228E-08 -8.0447 0.90228E-08 -8.0447 0.10000E+01 0.0000 23 AlO2- 0.22741E-04 -4.6432 0.21231E-04 -4.6730 0.93359E+00 -0.0298 24 CH4,aq 0.25673E-19 -19.5905 0.25665E-19 -19.5907 0.99969E+00 -0.0001 29 CO,aq 0.25591E-18 -18.5919 0.25591E-18 -18.5919 0.10000E+01 0.0000 30 CO2,aq 0.20953E-07 -7.6788 0.20946E-07 -7.6789 0.99969E+00 -0.0001 31 CO3-2 0.13284E-05 -5.8767 0.10667E-05 -5.9719 0.80303E+00 -0.0953 32 CaCO3,aq 0.37149E-09 -9.4300 0.37149E-09 -9.4300 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.83987E-11 -11.0758 0.78440E-11 -11.1055 0.93395E+00 -0.0297 34 CaCl+ 0.62492E-11 -11.2042 0.58364E-11 -11.2339 0.93395E+00 -0.0297 35 CaCl2,aq 0.17504E-15 -15.7569 0.17504E-15 -15.7569 0.10000E+01 0.0000 36 CaOH+ 0.22623E-08 -8.6454 0.21129E-08 -8.6751 0.93395E+00 -0.0297 37 CaSO4,aq 0.18135E-09 -9.7415 0.18135E-09 -9.7415 0.10000E+01 0.0000 38 HCl,aq 0.22991E-13 -13.6384 0.22991E-13 -13.6384 0.10000E+01 0.0000 43 FeCl+ 0.43197E-15 -15.3645 0.40344E-15 -15.3942 0.93395E+00 -0.0297 46 FeO,aq 0.88310E-10 -10.0540 0.88310E-10 -10.0540 0.10000E+01 0.0000 47 FeOH+ 0.75223E-10 -10.1236 0.70255E-10 -10.1533 0.93395E+00 -0.0297 48 HFeO2- 0.10720E-08 -8.9698 0.10010E-08 -8.9996 0.93377E+00 -0.0298 49 FeO+ 0.84048E-14 -14.0755 0.78497E-14 -14.1051 0.93395E+00 -0.0297 51 FeO2- 0.18348E-08 -8.7364 0.17133E-08 -8.7662 0.93377E+00 -0.0298 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.47451E-09 -9.3238 0.47436E-09 -9.3239 0.99969E+00 -0.0001 54 KCl,aq 0.17320E-09 -9.7615 0.17320E-09 -9.7615 0.10000E+01 0.0000 55 KHSO4,aq 0.39471E-17 -17.4037 0.39471E-17 -17.4037 0.10000E+01 0.0000 56 KOH,aq 0.34887E-07 -7.4573 0.34887E-07 -7.4573 0.10000E+01 0.0000 57 KSO4- 0.25646E-07 -7.5910 0.23948E-07 -7.6207 0.93377E+00 -0.0298 58 MgCO3,aq 0.11099E-11 -11.9547 0.11099E-11 -11.9547 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10240E-12 -12.9897 0.95636E-13 -13.0194 0.93395E+00 -0.0297 60 MgCl+ 0.67830E-13 -13.1686 0.63350E-13 -13.1983 0.93395E+00 -0.0297 61 MgOH+ 0.14985E-09 -9.8243 0.13996E-09 -9.8540 0.93395E+00 -0.0297 63 MnO,aq 0.31500E-09 -9.5017 0.31500E-09 -9.5017 0.10000E+01 0.0000 64 MnOH+ 0.93372E-09 -9.0298 0.87205E-09 -9.0595 0.93395E+00 -0.0297 65 MnO2-2 0.15065E-13 -13.8220 0.12098E-13 -13.9173 0.80303E+00 -0.0953 66 HMnO2- 0.26637E-11 -11.5745 0.24873E-11 -11.6043 0.93377E+00 -0.0298 69 MnCl+ 0.22429E-12 -12.6492 0.20947E-12 -12.6789 0.93395E+00 -0.0297 70 MnSO4,aq 0.15587E-11 -11.8072 0.15587E-11 -11.8072 0.10000E+01 0.0000 71 NaCl,aq 0.55083E-07 -7.2590 0.55083E-07 -7.2590 0.10000E+01 0.0000 72 NaOH,aq 0.60644E-06 -6.2172 0.60644E-06 -6.2172 0.10000E+01 0.0000 74 OH- 0.67708E-03 -3.1694 0.63211E-03 -3.1992 0.93359E+00 -0.0298 79 HPO3-2 0.66249E-17 -17.1788 0.53200E-17 -17.2741 0.80303E+00 -0.0953 81 H2PO3- 0.10620E-19 -19.9739 0.99166E-20 -20.0036 0.93377E+00 -0.0298 82 H3PO4,aq 0.20584E-13 -13.6865 0.20584E-13 -13.6865 0.10000E+01 0.0000 83 H2PO4- 0.63256E-07 -7.1989 0.59072E-07 -7.2286 0.93386E+00 -0.0297 84 PO4-3 0.52125E-08 -8.2830 0.32677E-08 -8.4858 0.62690E+00 -0.2028 87 H2P2O7-2 0.34009E-15 -15.4684 0.27311E-15 -15.5637 0.80303E+00 -0.0953 88 HP2O7-3 0.94616E-13 -13.0240 0.59015E-13 -13.2290 0.62373E+00 -0.2050 89 P2O7-4 0.34925E-13 -13.4569 0.15342E-13 -13.8141 0.43930E+00 -0.3572 90 H2S,aq 0.13947E-15 -15.8555 0.13942E-15 -15.8557 0.99969E+00 -0.0001 97 SO3-2 0.16461E-14 -14.7835 0.13239E-14 -14.8781 0.80425E+00 -0.0946 98 HSO3- 0.78736E-16 -16.1038 0.73521E-16 -16.1336 0.93377E+00 -0.0298 99 HSO4- 0.19295E-10 -10.7146 0.18022E-10 -10.7442 0.93404E+00 -0.0296 Charge balance for all species = 0.4568E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1015608E-08 -.1352979E-02 -.1363518E+01 0.0000 2 H2O 0.1000000E+01 0.5550839E+02 0.9998505E+06 0.0000 3 Cl- 0.1379462E-03 0.1380014E-03 0.4891832E+01 5.1327 4 SO4-- 0.2548366E-04 0.2550964E-04 0.2450130E+01 13.3566 5 HCO3- 0.1172288E-04 0.1307258E-04 0.7975329E+00 4.0621 6 HS- 0.5236898E-13 -.1361083E-09 -.4500699E-05 -4.2879 7 Al+++ 0.4785205E-24 0.2275035E-04 0.6137466E+00 2.5432 8 H4SiO4 0.5193881E-03 0.1102394E-02 0.1059412E+03 -3.2845 9 Ca++ 0.3542779E-07 0.3862188E-07 0.1547656E-02 10.4994 10 Mg++ 0.4237907E-09 0.5803459E-09 0.1410726E-04 8.5770 11 Fe++ 0.2506409E-11 0.3276321E-08 0.1829453E-03 6.3489 12 K+ 0.8131175E-04 0.8137245E-04 0.3181349E+01 4.9032 13 Na+ 0.1402569E-02 0.1414339E-02 0.3251049E+02 6.1399 14 Mn++ 0.3348729E-09 0.1588055E-08 0.8723150E-04 8.4748 15 HPO4-- 0.4420544E-05 0.4489013E-05 0.4307865E+00 12.5958 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1652892E-01 -.1352712E-02 -.1517620E-01 0.0000000E+00 2 H2O 0.5549573E+02 0.5549743E+02 -.1700017E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5319017E-04 0.2550461E-04 0.2768556E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2768570E-04 -.1360814E-09 -.2768556E-04 0.0000000E+00 7 Al+++ 0.3257481E-02 0.2274586E-04 0.3234735E-02 0.0000000E+00 8 H4SiO4 0.1040237E-01 0.1102176E-02 0.9300194E-02 0.0000000E+00 9 Ca++ 0.1163464E-02 0.3861425E-07 0.1163425E-02 0.0000000E+00 10 Mg++ 0.7928571E-03 0.5802312E-09 0.7928566E-03 0.0000000E+00 11 Fe++ 0.7122956E-03 0.3275674E-08 0.7122923E-03 0.0000000E+00 12 K+ 0.2121019E-03 0.8135638E-04 0.1307455E-03 0.0000000E+00 13 Na+ 0.1414059E-02 0.1414059E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1732126E-04 0.1587741E-08 0.1731967E-04 0.0000000E+00 15 HPO4-- 0.5911659E-05 0.4488127E-05 0.1423532E-05 0.0000000E+00 Chg. balance for solid moles: 0.8132E-18 Mass of aqueous solution: 0.999952E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4745E-06 -6.324 0.2384E-03 -3.623 0.2273E-01 0.7574E-04 clinochlore 0.1586E-03 -3.800 0.8814E-01 -1.055 8.403 0.3353E-01 daphnite 0.9816E-04 -4.008 0.7004E-01 -1.155 6.678 0.2122E-01 chlorite-Mn 0.3464E-05 -5.460 0.2456E-02 -2.610 0.2341 0.7826E-03 hematite 0.1107E-03 -3.956 0.1769E-01 -1.752 1.686 0.3352E-02 muscovite 0.1307E-03 -3.884 0.5208E-01 -1.283 4.965 0.1841E-01 stilbite 0.1161E-02 -2.935 0.8182 -0.087 78.01 0.3816 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.048852 g Volume = 0.459006 cm3 Porosity: 67.2045% V(tot) - V(min): 0.94059E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.9990000 g log = -0.0004 Original solution: 1000.0103000 g Original solution / Rock added: 1001.01 (Water/Rock Ratio), log = 3.0004 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2263E-05 1.0073 0.2398E-05 0.2380E-05 CH4,gas 0.3809E-16 1.0129 0.4059E-16 0.4007E-16 H2,gas 0.6182E-06 1.0006 0.6506E-06 0.6503E-06 H2S,gas 0.3881E-14 0.9959 0.4066E-14 0.4083E-14 S2,gas 0.1391E-35 1.0000 0.1463E-35 0.1463E-35 CO,gas 0.3841E-15 1.0000 0.4041E-15 0.4041E-15 SO3,gas 0.6551E-38 1.0000 0.6891E-38 0.6891E-38 SO2,gas 0.1612E-21 1.0000 0.1696E-21 0.1696E-21 HCl,gas 0.3859E-16 1.0000 0.4060E-16 0.4060E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.37914E-10 116 microcline -2.43 -2.41 0.02 0.002 -0.42114E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.98 -7.62 -2.540 0.13011E+05 -5.620 3 CH4,gas 4.81 -13.58 -18.39 -4.598 0.31403E+05 -16.392 4 H2,gas 8.29 0.10 -8.19 -4.678 0.13979E+05 -6.187 5 H2S,gas -5.94 -22.33 -16.39 -8.195 0.27987E+05 -14.391 6 S2,gas -7.03 -44.87 -37.83 -5.821 0.64602E+05 -35.835 7 CO,gas 3.51 -13.88 -17.39 -5.352 0.29699E+05 -15.394 8 SO3,gas 17.43 -22.73 -40.16 -10.040 0.68575E+05 -38.162 9 SO2,gas 1.14 -22.63 -23.77 -6.339 0.40588E+05 -21.771 10 HCl,gas 5.48 -12.91 -18.39 -9.196 0.31403E+05 -16.392 11 acmite 7.74 5.87 -1.87 -0.194 0.31890E+04 15 albite-high 0.75 -1.17 -1.92 -0.148 0.32785E+04 16 albite -0.33 -1.17 -0.84 -0.065 0.14378E+04 19 spessartine 24.55 20.66 -3.89 -0.195 0.66467E+04 20 analcite 3.37 2.11 -1.26 -0.140 0.21456E+04 21 andalusite 5.06 1.80 -3.26 -0.326 0.55673E+04 22 andradite 39.09 34.24 -4.85 -0.252 0.82736E+04 26 annite 20.21 16.64 -3.57 -0.198 0.60951E+04 27 phlogopite 27.15 23.32 -3.82 -0.212 0.65273E+04 29 anorthite 12.80 9.02 -3.78 -0.291 0.64559E+04 35 aragonite 0.99 -3.48 -4.47 -1.490 0.76329E+04 36 brucite 12.58 8.58 -4.00 -0.800 0.68292E+04 37 calcite 0.83 -3.48 -4.32 -1.439 0.73715E+04 38 carnegieite-low 9.06 5.40 -3.67 -0.524 0.62596E+04 39 carnegieite-high 10.13 5.40 -4.74 -0.677 0.80864E+04 40 carpholite-Mg 8.65 7.09 -1.56 -0.104 0.26570E+04 41 carpholite-Fe 6.78 4.87 -1.92 -0.128 0.32726E+04 42 celadonite 5.40 2.89 -2.52 -0.148 0.42946E+04 43 celadonite-Fe 3.94 0.66 -3.28 -0.193 0.55999E+04 44 chrysotile 23.94 19.16 -4.78 -0.398 0.81539E+04 50 chloritoid-Mg 13.26 10.38 -2.88 -0.192 0.49217E+04 51 chloritoid-Fe 9.24 8.15 -1.09 -0.073 0.18576E+04 52 chloritoid-Mn 11.46 10.28 -1.19 -0.079 0.20261E+04 54 coesite -2.37 -3.28 -0.92 -0.305 0.15626E+04 59 corundum 8.43 5.09 -3.35 -0.304 0.57151E+04 61 cristobalite -2.55 -3.28 -0.74 -0.245 0.12555E+04 63 cymrite-K 1.73 -2.41 -4.14 -0.345 0.70654E+04 65 diaspore 2.90 2.54 -0.35 -0.059 0.60261E+03 67 diopside 16.22 12.51 -3.71 -0.371 0.63315E+04 68 hedenbergite 14.24 10.28 -3.97 -0.397 0.67704E+04 75 epidote 24.78 22.53 -2.24 -0.109 0.38330E+04 76 clinozoisite 22.92 18.77 -4.15 -0.188 0.70799E+04 77 epidote-Fe 29.94 26.29 -3.65 -0.190 0.62336E+04 78 fayalite 14.08 9.41 -4.67 -0.667 0.79664E+04 83 gibbsite 4.10 2.54 -1.55 -0.222 0.26538E+04 87 greenalite 16.19 12.48 -3.72 -0.310 0.63457E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.11 -2.14 -0.214 0.36486E+04 97 kalsilite 7.62 4.16 -3.46 -0.494 0.59051E+04 98 kaolinite -1.27 -1.48 -0.21 -0.019 0.35780E+03 99 kyanite 4.93 1.80 -3.13 -0.313 0.53441E+04 101 laumontite 2.97 2.45 -0.53 -0.035 0.89963E+03 102 lawsonite 9.68 9.02 -0.66 -0.044 0.11298E+04 103 leucite 4.17 0.88 -3.29 -0.329 0.56180E+04 105 lizardite 23.29 19.16 -4.13 -0.344 0.70442E+04 107 magnetite 20.13 18.95 -1.19 -0.097 0.20255E+04 108 minnesotaite 10.46 5.91 -4.55 -0.268 0.77724E+04 113 margarite 17.45 14.10 -3.35 -0.134 0.57180E+04 121 paragonite 4.34 3.92 -0.42 -0.025 0.71841E+03 122 nepheline 8.38 5.40 -2.98 -0.426 0.50875E+04 136 prehnite 19.47 16.23 -3.23 -0.190 0.55233E+04 137 prehnite-Fe 22.59 19.99 -2.60 -0.156 0.44387E+04 145 pyroxmangite 7.42 5.19 -2.23 -0.445 0.38004E+04 146 pyrophyllite -6.10 -8.05 -1.95 -0.122 0.33359E+04 147 quartz -2.98 -3.28 -0.30 -0.101 0.51653E+03 151 rhodochrosite -0.96 -5.51 -4.55 -1.517 0.77692E+04 152 rhodonite 7.46 5.19 -2.27 -0.454 0.38796E+04 153 sanidine -1.22 -2.41 -1.19 -0.091 0.20256E+04 156 sillimanite 5.32 1.80 -3.52 -0.352 0.60095E+04 164 stilpnomelane-Fe 13.18 13.01 -0.17 -0.005 0.29513E+03 165 stilpnomelane-Mg 27.60 24.15 -3.45 -0.103 0.58899E+04 168 sudoite 21.22 17.47 -3.74 -0.121 0.63913E+04 171 talc 16.55 12.59 -3.96 -0.233 0.67624E+04 174 tephroite 18.11 13.67 -4.45 -0.635 0.75945E+04 177 topaz-H 4.67 1.80 -2.87 -0.261 0.48932E+04 178 tridymite -2.61 -3.28 -0.67 -0.223 0.11438E+04 187 wairakite 4.06 2.45 -1.61 -0.095 0.27504E+04 188 walstromite 11.53 7.21 -4.31 -0.863 0.73643E+04 189 wollastonite 10.48 7.21 -3.27 -0.653 0.55782E+04 190 pseudo-wollastonite 11.02 7.21 -3.80 -0.761 0.64969E+04 191 zoisite 22.96 18.77 -4.19 -0.190 0.71525E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.40 -2.84 -0.175 0.48433E+04 194 beidellite-H -2.24 -6.13 -3.89 -0.248 0.66377E+04 195 beidellite-K -1.44 -4.51 -3.08 -0.188 0.52513E+04 196 beidellite-Mg -1.71 -4.71 -3.01 -0.186 0.51335E+04 197 beidellite-Na -1.26 -4.10 -2.85 -0.174 0.48584E+04 199 chalcedony -2.79 -3.28 -0.49 -0.163 0.83684E+03 201 montmorillonite-Ca -2.21 -4.33 -2.11 -0.131 0.36098E+04 202 montmorillonite-K -2.16 -4.44 -2.28 -0.140 0.38956E+04 203 montmorillonite-Mg -2.40 -4.65 -2.24 -0.139 0.38311E+04 204 montmorillonite-Na -1.96 -4.03 -2.07 -0.127 0.35409E+04 205 nontronite-Ca 3.28 3.12 -0.16 -0.011 0.28095E+03 206 nontronite-H 2.60 1.38 -1.21 -0.081 0.20712E+04 207 nontronite-K 3.40 3.00 -0.40 -0.026 0.68817E+03 208 nontronite-Mg 3.14 2.80 -0.34 -0.022 0.58281E+03 209 nontronite-Na 3.58 3.41 -0.17 -0.011 0.29697E+03 224 tobermorite 9.84 5.46 -4.38 -1.194 0.74745E+04 233 boehmite 4.43 2.54 -1.89 -0.314 0.32210E+04 235 ferrous-oxide 9.82 6.35 -3.48 -0.869 0.59340E+04 240 silica-amorphous -2.08 -3.28 -1.20 -0.402 0.20570E+04 242 an20ab80 2.08 0.87 -1.21 -0.093 0.20698E+04 243 an25ab75 2.71 1.38 -1.33 -0.103 0.22757E+04 244 an30ab70 3.34 1.89 -1.46 -0.112 0.24900E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.9990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .9865388E-03 Osmotic coef. = 0.9818 True ionic strength = .1510955E-02 Chg. balance for total moles = 0.4567E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10141E-08 -8.9939 0.94762E-09 -9.0234 0.93442E+00 -0.0295 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12882E-03 -3.8900 0.93383E+00 -0.0297 4 SO4-- 0.25485E-04 -4.5937 0.20475E-04 -4.6888 0.80343E+00 -0.0951 5 HCO3- 0.11721E-04 -4.9310 0.10948E-04 -4.9607 0.93397E+00 -0.0297 6 HS- 0.50340E-13 -13.2981 0.47009E-13 -13.3278 0.93384E+00 -0.0297 7 Al+++ 0.48996E-24 -24.3098 0.30577E-24 -24.5146 0.62407E+00 -0.2048 8 H4SiO4 0.51374E-03 -3.2893 0.51374E-03 -3.2893 0.10000E+01 0.0000 9 Ca++ 0.36024E-07 -7.4434 0.28921E-07 -7.5388 0.80283E+00 -0.0954 10 Mg++ 0.42048E-09 -9.3763 0.33741E-09 -9.4718 0.80245E+00 -0.0956 11 Fe++ 0.24868E-11 -11.6044 0.19958E-11 -11.6999 0.80254E+00 -0.0955 12 K+ 0.77049E-04 -4.1132 0.71964E-04 -4.1429 0.93400E+00 -0.0297 13 Na+ 0.14027E-02 -2.8530 0.13098E-02 -2.8828 0.93382E+00 -0.0297 14 Mn++ 0.33226E-09 -9.4785 0.26667E-09 -9.5740 0.80261E+00 -0.0955 15 HPO4-- 0.42882E-05 -5.3677 0.34453E-05 -5.4628 0.80344E+00 -0.0950 16 HSiO3- 0.56643E-03 -3.2469 0.52894E-03 -3.2766 0.93383E+00 -0.0297 17 Ca(HSiO3)+ 0.36696E-09 -9.4354 0.34275E-09 -9.4650 0.93402E+00 -0.0296 18 Mg(HSiO3)+ 0.53280E-11 -11.2734 0.49765E-11 -11.3031 0.93402E+00 -0.0296 19 NaHSiO3,aq 0.11004E-04 -4.9585 0.11004E-04 -4.9585 0.10000E+01 0.0000 20 AlO+ 0.47064E-13 -13.3273 0.43958E-13 -13.3570 0.93402E+00 -0.0296 21 AlOH+2 0.25997E-18 -18.5851 0.20867E-18 -18.6805 0.80269E+00 -0.0955 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.23427E-04 -4.6303 0.21873E-04 -4.6601 0.93365E+00 -0.0298 24 CH4,aq 0.24671E-19 -19.6078 0.24663E-19 -19.6079 0.99969E+00 -0.0001 29 CO,aq 0.25310E-18 -18.5967 0.25310E-18 -18.5967 0.10000E+01 0.0000 30 CO2,aq 0.20923E-07 -7.6794 0.20916E-07 -7.6795 0.99969E+00 -0.0001 31 CO3-2 0.13298E-05 -5.8762 0.10681E-05 -5.9714 0.80325E+00 -0.0951 32 CaCO3,aq 0.37835E-09 -9.4221 0.37835E-09 -9.4221 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.85414E-11 -11.0685 0.79778E-11 -11.0981 0.93402E+00 -0.0296 34 CaCl+ 0.63561E-11 -11.1968 0.59367E-11 -11.2265 0.93402E+00 -0.0296 35 CaCl2,aq 0.17806E-15 -15.7494 0.17806E-15 -15.7494 0.10000E+01 0.0000 36 CaOH+ 0.23041E-08 -8.6375 0.21520E-08 -8.6672 0.93402E+00 -0.0296 37 CaSO4,aq 0.18451E-09 -9.7340 0.18451E-09 -9.7340 0.10000E+01 0.0000 38 HCl,aq 0.22961E-13 -13.6390 0.22961E-13 -13.6390 0.10000E+01 0.0000 43 FeCl+ 0.42871E-15 -15.3678 0.40042E-15 -15.3975 0.93402E+00 -0.0296 46 FeO,aq 0.87887E-10 -10.0561 0.87887E-10 -10.0561 0.10000E+01 0.0000 47 FeOH+ 0.74755E-10 -10.1264 0.69822E-10 -10.1560 0.93402E+00 -0.0296 48 HFeO2- 0.10682E-08 -8.9713 0.99756E-09 -9.0011 0.93383E+00 -0.0297 49 FeO+ 0.83926E-14 -14.0761 0.78389E-14 -14.1057 0.93402E+00 -0.0296 51 FeO2- 0.18372E-08 -8.7358 0.17157E-08 -8.7656 0.93383E+00 -0.0297 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.46998E-09 -9.3279 0.46983E-09 -9.3281 0.99969E+00 -0.0001 54 KCl,aq 0.16414E-09 -9.7848 0.16414E-09 -9.7848 0.10000E+01 0.0000 55 KHSO4,aq 0.37365E-17 -17.4275 0.37365E-17 -17.4275 0.10000E+01 0.0000 56 KOH,aq 0.33106E-07 -7.4801 0.33106E-07 -7.4801 0.10000E+01 0.0000 57 KSO4- 0.24310E-07 -7.6142 0.22701E-07 -7.6440 0.93383E+00 -0.0297 58 MgCO3,aq 0.11030E-11 -11.9574 0.11030E-11 -11.9574 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10162E-12 -12.9930 0.94910E-13 -13.0227 0.93402E+00 -0.0296 60 MgCl+ 0.67319E-13 -13.1719 0.62877E-13 -13.2015 0.93402E+00 -0.0296 61 MgOH+ 0.14892E-09 -9.8270 0.13909E-09 -9.8567 0.93402E+00 -0.0296 63 MnO,aq 0.31349E-09 -9.5038 0.31349E-09 -9.5038 0.10000E+01 0.0000 64 MnOH+ 0.92790E-09 -9.0325 0.86668E-09 -9.0621 0.93402E+00 -0.0296 65 MnO2-2 0.15030E-13 -13.8230 0.12073E-13 -13.9182 0.80325E+00 -0.0951 66 HMnO2- 0.26544E-11 -11.5760 0.24788E-11 -11.6058 0.93383E+00 -0.0297 69 MnCl+ 0.22260E-12 -12.6525 0.20791E-12 -12.6821 0.93402E+00 -0.0296 70 MnSO4,aq 0.15474E-11 -11.8104 0.15474E-11 -11.8104 0.10000E+01 0.0000 71 NaCl,aq 0.55095E-07 -7.2589 0.55095E-07 -7.2589 0.10000E+01 0.0000 72 NaOH,aq 0.60736E-06 -6.2166 0.60736E-06 -6.2166 0.10000E+01 0.0000 74 OH- 0.67797E-03 -3.1688 0.63299E-03 -3.1986 0.93365E+00 -0.0298 79 HPO3-2 0.63652E-17 -17.1962 0.51128E-17 -17.2913 0.80325E+00 -0.0951 81 H2PO3- 0.10192E-19 -19.9918 0.95172E-20 -20.0215 0.93383E+00 -0.0297 82 H3PO4,aq 0.19918E-13 -13.7008 0.19918E-13 -13.7008 0.10000E+01 0.0000 83 H2PO4- 0.61290E-07 -7.2126 0.57240E-07 -7.2423 0.93392E+00 -0.0297 84 PO4-3 0.50618E-08 -8.2957 0.31752E-08 -8.4982 0.62727E+00 -0.2025 87 H2P2O7-2 0.31924E-15 -15.4959 0.25643E-15 -15.5910 0.80325E+00 -0.0951 88 HP2O7-3 0.88907E-13 -13.0511 0.55488E-13 -13.2558 0.62411E+00 -0.2047 89 P2O7-4 0.32847E-13 -13.4835 0.14445E-13 -13.8403 0.43977E+00 -0.3568 90 H2S,aq 0.13389E-15 -15.8733 0.13384E-15 -15.8734 0.99969E+00 -0.0001 97 SO3-2 0.16305E-14 -14.7877 0.13117E-14 -14.8822 0.80446E+00 -0.0945 98 HSO3- 0.77895E-16 -16.1085 0.72741E-16 -16.1382 0.93383E+00 -0.0297 99 HSO4- 0.19273E-10 -10.7150 0.18003E-10 -10.7447 0.93411E+00 -0.0296 Charge balance for all species = 0.4562E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1014135E-08 -.1351042E-02 -.1361567E+01 0.0000 2 H2O 0.1000000E+01 0.5550840E+02 0.9998518E+06 0.0000 3 Cl- 0.1379461E-03 0.1380014E-03 0.4891836E+01 5.1333 4 SO4-- 0.2548499E-04 0.2550964E-04 0.2450132E+01 13.3580 5 HCO3- 0.1172148E-04 0.1307258E-04 0.7975335E+00 4.0627 6 HS- 0.5033953E-13 -.1375458E-09 -.4548238E-05 -4.3045 7 Al+++ 0.4899629E-24 0.2343646E-04 0.6322568E+00 2.5555 8 H4SiO4 0.5137408E-03 0.1091170E-02 0.1048627E+03 -3.2893 9 Ca++ 0.3602418E-07 0.3927296E-07 0.1573748E-02 10.5079 10 Mg++ 0.4204802E-09 0.5760008E-09 0.1400165E-04 8.5749 11 Fe++ 0.2486831E-11 0.3274104E-08 0.1828217E-03 6.3468 12 K+ 0.7704943E-04 0.7710701E-04 0.3014590E+01 4.8805 13 Na+ 0.1402672E-02 0.1414338E-02 0.3251052E+02 6.1406 14 Mn++ 0.3322573E-09 0.1578090E-08 0.8668424E-04 8.4727 15 HPO4-- 0.4288224E-05 0.4354576E-05 0.4178857E+00 12.5840 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1652892E-01 -.1350775E-02 -.1517814E-01 0.0000000E+00 2 H2O 0.5549573E+02 0.5549745E+02 -.1725359E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5319017E-04 0.2550461E-04 0.2768556E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2768570E-04 -.1375187E-09 -.2768556E-04 0.0000000E+00 7 Al+++ 0.3257481E-02 0.2343184E-04 0.3234049E-02 0.0000000E+00 8 H4SiO4 0.1040237E-01 0.1090955E-02 0.9311415E-02 0.0000000E+00 9 Ca++ 0.1163464E-02 0.3926522E-07 0.1163424E-02 0.0000000E+00 10 Mg++ 0.7928571E-03 0.5758872E-09 0.7928566E-03 0.0000000E+00 11 Fe++ 0.7122956E-03 0.3273458E-08 0.7122923E-03 0.0000000E+00 12 K+ 0.2121019E-03 0.7709180E-04 0.1350101E-03 0.0000000E+00 13 Na+ 0.1414059E-02 0.1414059E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1732126E-04 0.1577779E-08 0.1731968E-04 0.0000000E+00 15 HPO4-- 0.5911659E-05 0.4353717E-05 0.1557942E-05 0.0000000E+00 Chg. balance for solid moles: 0.2507E-18 Mass of aqueous solution: 0.999951E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5193E-06 -6.285 0.2609E-03 -3.584 0.2485E-01 0.8289E-04 clinochlore 0.1586E-03 -3.800 0.8814E-01 -1.055 8.397 0.3353E-01 daphnite 0.9816E-04 -4.008 0.7004E-01 -1.155 6.673 0.2122E-01 chlorite-Mn 0.3464E-05 -5.460 0.2456E-02 -2.610 0.2340 0.7826E-03 hematite 0.1107E-03 -3.956 0.1769E-01 -1.752 1.685 0.3352E-02 muscovite 0.1285E-03 -3.891 0.5118E-01 -1.291 4.876 0.1810E-01 stilbite 0.1161E-02 -2.935 0.8181 -0.087 77.94 0.3816 microcline 0.6515E-05 -5.186 0.1813E-02 -2.741 0.1728 0.7084E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.049633 g Volume = 0.459331 cm3 Porosity: 67.1813% V(tot) - V(min): 0.94027E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.9990000 g log = -0.0004 Original solution: 1000.0103000 g Original solution / Rock added: 1001.01 (Water/Rock Ratio), log = 3.0004 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2259E-05 1.0073 0.2394E-05 0.2377E-05 CH4,gas 0.3660E-16 1.0129 0.3900E-16 0.3850E-16 H2,gas 0.6123E-06 1.0006 0.6444E-06 0.6441E-06 H2S,gas 0.3726E-14 0.9959 0.3904E-14 0.3920E-14 S2,gas 0.1307E-35 1.0000 0.1374E-35 0.1374E-35 CO,gas 0.3799E-15 1.0000 0.3997E-15 0.3997E-15 SO3,gas 0.6535E-38 1.0000 0.6874E-38 0.6874E-38 SO2,gas 0.1593E-21 1.0000 0.1676E-21 0.1676E-21 HCl,gas 0.3854E-16 1.0000 0.4054E-16 0.4054E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.60662E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.98 -7.62 -2.540 0.13012E+05 -5.621 3 CH4,gas 4.81 -13.60 -18.41 -4.602 0.31433E+05 -16.409 4 H2,gas 8.29 0.10 -8.19 -4.680 0.13986E+05 -6.191 5 H2S,gas -5.94 -22.35 -16.41 -8.204 0.28017E+05 -14.409 6 S2,gas -7.03 -44.89 -37.86 -5.825 0.64648E+05 -35.862 7 CO,gas 3.51 -13.89 -17.40 -5.353 0.29707E+05 -15.398 8 SO3,gas 17.43 -22.74 -40.16 -10.041 0.68577E+05 -38.163 9 SO2,gas 1.14 -22.64 -23.78 -6.340 0.40597E+05 -21.776 10 HCl,gas 5.48 -12.91 -18.39 -9.196 0.31404E+05 -16.392 11 acmite 7.74 5.86 -1.88 -0.195 0.32041E+04 15 albite-high 0.75 -1.17 -1.92 -0.148 0.32806E+04 16 albite -0.33 -1.17 -0.84 -0.065 0.14400E+04 19 spessartine 24.55 20.66 -3.89 -0.194 0.66396E+04 20 analcite 3.37 2.12 -1.25 -0.139 0.21396E+04 21 andalusite 5.06 1.82 -3.24 -0.324 0.55333E+04 22 andradite 39.09 34.25 -4.83 -0.251 0.82540E+04 26 annite 20.21 16.61 -3.60 -0.200 0.61479E+04 27 phlogopite 27.15 23.29 -3.85 -0.214 0.65801E+04 29 anorthite 12.80 9.04 -3.76 -0.289 0.64154E+04 35 aragonite 0.99 -3.48 -4.46 -1.487 0.76193E+04 36 brucite 12.58 8.57 -4.00 -0.800 0.68328E+04 37 calcite 0.83 -3.48 -4.31 -1.436 0.73580E+04 38 carnegieite-low 9.06 5.41 -3.66 -0.523 0.62455E+04 39 carnegieite-high 10.13 5.41 -4.73 -0.675 0.80723E+04 40 carpholite-Mg 8.65 7.11 -1.54 -0.103 0.26346E+04 41 carpholite-Fe 6.78 4.88 -1.90 -0.127 0.32503E+04 42 celadonite 5.40 2.85 -2.55 -0.150 0.43484E+04 43 celadonite-Fe 3.94 0.63 -3.31 -0.195 0.56537E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81808E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.191 0.48913E+04 51 chloritoid-Fe 9.24 8.17 -1.07 -0.071 0.18272E+04 52 chloritoid-Mn 11.46 10.29 -1.17 -0.078 0.19956E+04 54 coesite -2.37 -3.29 -0.92 -0.307 0.15707E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.29 -0.74 -0.247 0.12636E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.50 -3.71 -0.371 0.63367E+04 68 hedenbergite 14.24 10.28 -3.97 -0.397 0.67755E+04 75 epidote 24.78 22.56 -2.22 -0.108 0.37859E+04 76 clinozoisite 22.92 18.81 -4.11 -0.187 0.70118E+04 77 epidote-Fe 29.94 26.30 -3.64 -0.189 0.62076E+04 78 fayalite 14.08 9.40 -4.67 -0.668 0.79816E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63726E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.12 -2.13 -0.213 0.36426E+04 97 kalsilite 7.62 4.15 -3.47 -0.496 0.59310E+04 98 kaolinite -1.27 -1.47 -0.19 -0.018 0.33190E+03 99 kyanite 4.93 1.82 -3.11 -0.311 0.53101E+04 101 laumontite 2.97 2.46 -0.51 -0.034 0.87530E+03 102 lawsonite 9.68 9.04 -0.64 -0.043 0.10893E+04 103 leucite 4.17 0.86 -3.31 -0.331 0.56520E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70711E+04 107 magnetite 20.13 18.94 -1.19 -0.097 0.20290E+04 108 minnesotaite 10.46 5.88 -4.58 -0.269 0.78155E+04 113 margarite 17.45 14.15 -3.30 -0.132 0.56353E+04 121 paragonite 4.34 3.94 -0.40 -0.023 0.67843E+03 122 nepheline 8.38 5.41 -2.97 -0.424 0.50734E+04 136 prehnite 19.47 16.26 -3.21 -0.189 0.54762E+04 137 prehnite-Fe 22.59 20.00 -2.58 -0.155 0.44127E+04 145 pyroxmangite 7.42 5.18 -2.23 -0.447 0.38121E+04 146 pyrophyllite -6.10 -8.05 -1.95 -0.122 0.33262E+04 147 quartz -2.98 -3.29 -0.31 -0.102 0.52463E+03 151 rhodochrosite -0.96 -5.51 -4.55 -1.518 0.77738E+04 152 rhodonite 7.46 5.18 -2.28 -0.456 0.38913E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.82 -3.50 -0.350 0.59755E+04 164 stilpnomelane-Fe 13.18 12.97 -0.21 -0.006 0.35509E+03 165 stilpnomelane-Mg 27.60 24.11 -3.48 -0.104 0.59499E+04 168 sudoite 21.22 17.50 -3.71 -0.120 0.63385E+04 171 talc 16.55 12.57 -3.99 -0.234 0.68055E+04 174 tephroite 18.11 13.66 -4.46 -0.637 0.76098E+04 177 topaz-H 4.67 1.82 -2.85 -0.259 0.48592E+04 178 tridymite -2.61 -3.29 -0.67 -0.225 0.11519E+04 187 wairakite 4.06 2.46 -1.60 -0.094 0.27261E+04 188 walstromite 11.53 7.22 -4.31 -0.862 0.73578E+04 189 wollastonite 10.48 7.22 -3.26 -0.653 0.55717E+04 190 pseudo-wollastonite 11.02 7.22 -3.80 -0.760 0.64903E+04 191 zoisite 22.96 18.81 -4.15 -0.189 0.70843E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.38 -2.82 -0.175 0.48215E+04 194 beidellite-H -2.24 -6.12 -3.88 -0.247 0.66184E+04 195 beidellite-K -1.44 -4.51 -3.07 -0.188 0.52448E+04 196 beidellite-Mg -1.71 -4.70 -3.00 -0.185 0.51148E+04 197 beidellite-Na -1.26 -4.09 -2.83 -0.174 0.48387E+04 199 chalcedony -2.79 -3.29 -0.49 -0.165 0.84495E+03 201 montmorillonite-Ca -2.21 -4.33 -2.11 -0.131 0.36058E+04 202 montmorillonite-K -2.16 -4.45 -2.29 -0.140 0.39069E+04 203 montmorillonite-Mg -2.40 -4.64 -2.24 -0.139 0.38301E+04 204 montmorillonite-Na -1.96 -4.03 -2.07 -0.127 0.35389E+04 205 nontronite-Ca 3.28 3.10 -0.18 -0.011 0.30134E+03 206 nontronite-H 2.60 1.37 -1.23 -0.082 0.20940E+04 207 nontronite-K 3.40 2.98 -0.42 -0.027 0.72379E+03 208 nontronite-Mg 3.14 2.78 -0.36 -0.023 0.60621E+03 209 nontronite-Na 3.58 3.40 -0.19 -0.012 0.31940E+03 224 tobermorite 9.84 5.46 -4.38 -1.194 0.74704E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.35 -3.48 -0.869 0.59375E+04 240 silica-amorphous -2.08 -3.29 -1.21 -0.403 0.20651E+04 242 an20ab80 2.08 0.87 -1.21 -0.093 0.20634E+04 243 an25ab75 2.71 1.38 -1.33 -0.102 0.22672E+04 244 an30ab70 3.34 1.89 -1.45 -0.112 0.24793E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 0.9990000 g New total amount of reactant added: 1.0390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4567E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.0390000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .1014593E-02 Osmotic coef. = 0.9816 True ionic strength = .1557591E-02 Chg. balance for total moles = 0.4567E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.98264E-09 -9.0076 0.91753E-09 -9.0374 0.93375E+00 -0.0298 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12872E-03 -3.8903 0.93314E+00 -0.0301 4 SO4-- 0.25486E-04 -4.5937 0.20417E-04 -4.6900 0.80110E+00 -0.0963 5 HCO3- 0.11681E-04 -4.9325 0.10901E-04 -4.9625 0.93329E+00 -0.0300 6 HS- 0.47684E-13 -13.3216 0.44497E-13 -13.3517 0.93316E+00 -0.0300 7 Al+++ 0.44768E-24 -24.3490 0.27756E-24 -24.5566 0.61999E+00 -0.2076 8 H4SiO4 0.51587E-03 -3.2875 0.51587E-03 -3.2875 0.10000E+01 0.0000 9 Ca++ 0.32907E-07 -7.4827 0.26341E-07 -7.5794 0.80049E+00 -0.0966 10 Mg++ 0.39438E-09 -9.4041 0.31554E-09 -9.5009 0.80010E+00 -0.0969 11 Fe++ 0.23325E-11 -11.6322 0.18664E-11 -11.7290 0.80019E+00 -0.0968 12 K+ 0.73738E-04 -4.1323 0.68821E-04 -4.1623 0.93331E+00 -0.0300 13 Na+ 0.14521E-02 -2.8380 0.13550E-02 -2.8681 0.93313E+00 -0.0301 14 Mn++ 0.31163E-09 -9.5064 0.24939E-09 -9.6031 0.80026E+00 -0.0968 15 HPO4-- 0.48137E-05 -5.3175 0.38563E-05 -5.4138 0.80111E+00 -0.0963 16 HSiO3- 0.58785E-03 -3.2307 0.54855E-03 -3.2608 0.93314E+00 -0.0301 17 Ca(HSiO3)+ 0.34687E-09 -9.4598 0.32375E-09 -9.4898 0.93334E+00 -0.0300 18 Mg(HSiO3)+ 0.51712E-11 -11.2864 0.48264E-11 -11.3164 0.93334E+00 -0.0300 19 NaHSiO3,aq 0.11805E-04 -4.9279 0.11805E-04 -4.9279 0.10000E+01 0.0000 20 AlO+ 0.45603E-13 -13.3410 0.42562E-13 -13.3710 0.93334E+00 -0.0300 21 AlOH+2 0.24443E-18 -18.6118 0.19563E-18 -18.7086 0.80034E+00 -0.0967 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.24213E-04 -4.6159 0.22590E-04 -4.6461 0.93296E+00 -0.0301 24 CH4,aq 0.23320E-19 -19.6323 0.23313E-19 -19.6324 0.99969E+00 -0.0001 29 CO,aq 0.24283E-18 -18.6147 0.24283E-18 -18.6147 0.10000E+01 0.0000 30 CO2,aq 0.20173E-07 -7.6952 0.20167E-07 -7.6954 0.99969E+00 -0.0001 31 CO3-2 0.13716E-05 -5.8628 0.10985E-05 -5.9592 0.80092E+00 -0.0964 32 CaCO3,aq 0.35440E-09 -9.4505 0.35440E-09 -9.4505 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.77523E-11 -11.1106 0.72355E-11 -11.1405 0.93334E+00 -0.0300 34 CaCl+ 0.57890E-11 -11.2374 0.54031E-11 -11.2674 0.93334E+00 -0.0300 35 CaCl2,aq 0.16194E-15 -15.7906 0.16194E-15 -15.7906 0.10000E+01 0.0000 36 CaOH+ 0.21689E-08 -8.6638 0.20243E-08 -8.6937 0.93334E+00 -0.0300 37 CaSO4,aq 0.16757E-09 -9.7758 0.16757E-09 -9.7758 0.10000E+01 0.0000 38 HCl,aq 0.22216E-13 -13.6533 0.22216E-13 -13.6533 0.10000E+01 0.0000 43 FeCl+ 0.40092E-15 -15.3969 0.37419E-15 -15.4269 0.93334E+00 -0.0300 46 FeO,aq 0.87669E-10 -10.0572 0.87669E-10 -10.0572 0.10000E+01 0.0000 47 FeOH+ 0.72254E-10 -10.1411 0.67438E-10 -10.1711 0.93334E+00 -0.0300 48 HFeO2- 0.11014E-08 -8.9581 0.10277E-08 -8.9881 0.93314E+00 -0.0301 49 FeO+ 0.81321E-14 -14.0898 0.75899E-14 -14.1198 0.93334E+00 -0.0300 51 FeO2- 0.18989E-08 -8.7215 0.17719E-08 -8.7516 0.93314E+00 -0.0301 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.46766E-09 -9.3301 0.46751E-09 -9.3302 0.99969E+00 -0.0001 54 KCl,aq 0.15686E-09 -9.8045 0.15686E-09 -9.8045 0.10000E+01 0.0000 55 KHSO4,aq 0.34500E-17 -17.4622 0.34500E-17 -17.4622 0.10000E+01 0.0000 56 KOH,aq 0.32699E-07 -7.4855 0.32699E-07 -7.4855 0.10000E+01 0.0000 57 KSO4- 0.23199E-07 -7.6345 0.21648E-07 -7.6646 0.93314E+00 -0.0301 58 MgCO3,aq 0.10608E-11 -11.9744 0.10608E-11 -11.9744 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.94697E-13 -13.0237 0.88384E-13 -13.0536 0.93334E+00 -0.0300 60 MgCl+ 0.62954E-13 -13.2010 0.58757E-13 -13.2309 0.93334E+00 -0.0300 61 MgOH+ 0.14394E-09 -9.8418 0.13434E-09 -9.8718 0.93334E+00 -0.0300 63 MnO,aq 0.31272E-09 -9.5049 0.31272E-09 -9.5049 0.10000E+01 0.0000 64 MnOH+ 0.89688E-09 -9.0473 0.83709E-09 -9.0772 0.93334E+00 -0.0300 65 MnO2-2 0.16039E-13 -13.7948 0.12846E-13 -13.8912 0.80092E+00 -0.0964 66 HMnO2- 0.27367E-11 -11.5628 0.25538E-11 -11.5928 0.93314E+00 -0.0301 69 MnCl+ 0.20817E-12 -12.6816 0.19429E-12 -12.7116 0.93334E+00 -0.0300 70 MnSO4,aq 0.14430E-11 -11.8407 0.14430E-11 -11.8407 0.10000E+01 0.0000 71 NaCl,aq 0.56951E-07 -7.2445 0.56951E-07 -7.2445 0.10000E+01 0.0000 72 NaOH,aq 0.64889E-06 -6.1878 0.64889E-06 -6.1878 0.10000E+01 0.0000 74 OH- 0.70072E-03 -3.1545 0.65375E-03 -3.1846 0.93296E+00 -0.0301 79 HPO3-2 0.71099E-17 -17.1481 0.56945E-17 -17.2445 0.80092E+00 -0.0964 81 H2PO3- 0.10999E-19 -19.9587 0.10263E-19 -19.9887 0.93314E+00 -0.0301 82 H3PO4,aq 0.20901E-13 -13.6798 0.20901E-13 -13.6798 0.10000E+01 0.0000 83 H2PO4- 0.66472E-07 -7.1774 0.62034E-07 -7.2074 0.93324E+00 -0.0300 84 PO4-3 0.58891E-08 -8.2299 0.36705E-08 -8.4353 0.62326E+00 -0.2053 87 H2P2O7-2 0.37604E-15 -15.4248 0.30118E-15 -15.5212 0.80092E+00 -0.0964 88 HP2O7-3 0.10856E-12 -12.9643 0.67308E-13 -13.1719 0.62003E+00 -0.2076 89 P2O7-4 0.41631E-13 -13.3806 0.18097E-13 -13.7424 0.43471E+00 -0.3618 90 H2S,aq 0.12271E-15 -15.9111 0.12267E-15 -15.9113 0.99969E+00 -0.0001 97 SO3-2 0.16225E-14 -14.7898 0.13015E-14 -14.8856 0.80216E+00 -0.0957 98 HSO3- 0.74891E-16 -16.1256 0.69884E-16 -16.1556 0.93314E+00 -0.0301 99 HSO4- 0.18622E-10 -10.7300 0.17382E-10 -10.7599 0.93343E+00 -0.0299 Charge balance for all species = 0.4651E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9826354E-09 -.1399247E-02 -.1410142E+01 0.0000 2 H2O 0.1000000E+01 0.5550840E+02 0.9998484E+06 0.0000 3 Cl- 0.1379453E-03 0.1380024E-03 0.4891854E+01 5.1470 4 SO4-- 0.2548630E-04 0.2550983E-04 0.2450142E+01 13.3848 5 HCO3- 0.1168056E-04 0.1307267E-04 0.7975365E+00 4.0749 6 HS- 0.4768393E-13 -.1458339E-09 -.4822284E-05 -4.3143 7 Al+++ 0.4476821E-24 0.2422267E-04 0.6534645E+00 2.5555 8 H4SiO4 0.5158658E-03 0.1115524E-02 0.1072027E+03 -3.2875 9 Ca++ 0.3290674E-07 0.3595807E-07 0.1440908E-02 10.4954 10 Mg++ 0.3943805E-09 0.5447102E-09 0.1324098E-04 8.5738 11 Fe++ 0.2332463E-11 0.3365992E-08 0.1879519E-03 6.3458 12 K+ 0.7373841E-04 0.7379446E-04 0.2885072E+01 4.8751 13 Na+ 0.1452058E-02 0.1464568E-02 0.3366501E+02 6.1693 14 Mn++ 0.3116340E-09 0.1525630E-08 0.8380230E-04 8.4716 15 HPO4-- 0.4813704E-05 0.4886065E-05 0.4688883E+00 12.6609 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1719126E-01 -.1398961E-02 -.1579230E-01 0.0000000E+00 2 H2O 0.5549523E+02 0.5549706E+02 -.1832796E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5429870E-04 0.2550462E-04 0.2879409E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2879423E-04 -.1458041E-09 -.2879409E-04 0.0000000E+00 7 Al+++ 0.3387911E-02 0.2421772E-04 0.3363693E-02 0.0000000E+00 8 H4SiO4 0.1081888E-01 0.1115296E-02 0.9703586E-02 0.0000000E+00 9 Ca++ 0.1209469E-02 0.3595073E-07 0.1209433E-02 0.0000000E+00 10 Mg++ 0.8246032E-03 0.5445989E-09 0.8246026E-03 0.0000000E+00 11 Fe++ 0.7408159E-03 0.3365304E-08 0.7408126E-03 0.0000000E+00 12 K+ 0.2205945E-03 0.7377939E-04 0.1468151E-03 0.0000000E+00 13 Na+ 0.1464269E-02 0.1464269E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1801480E-04 0.1525318E-08 0.1801328E-04 0.0000000E+00 15 HPO4-- 0.6148362E-05 0.4885066E-05 0.1263296E-05 0.0000000E+00 Chg. balance for solid moles: -.2178E-17 Mass of aqueous solution: 0.999948E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.0390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4211E-06 -6.376 0.2115E-03 -3.675 0.1935E-01 0.6722E-04 clinochlore 0.1649E-03 -3.783 0.9167E-01 -1.038 8.387 0.3487E-01 daphnite 0.1021E-03 -3.991 0.7284E-01 -1.138 6.664 0.2207E-01 chlorite-Mn 0.3603E-05 -5.443 0.2554E-02 -2.593 0.2337 0.8139E-03 hematite 0.1152E-03 -3.939 0.1839E-01 -1.735 1.683 0.3486E-02 microcline 0.1632E-04 -4.787 0.4542E-02 -2.343 0.4156 0.1774E-02 muscovite 0.1305E-03 -3.884 0.5198E-01 -1.284 4.755 0.1838E-01 stilbite 0.1207E-02 -2.918 0.8508 -0.070 77.84 0.3968 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.093019 g Volume = 0.478305 cm3 Porosity: 66.2119% V(tot) - V(min): 0.93730E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.0390000 g log = 0.0166 Original solution: 1000.0103000 g Original solution / Rock added: 962.47 (Water/Rock Ratio), log = 2.9834 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2179E-05 1.0073 0.2308E-05 0.2292E-05 CH4,gas 0.3460E-16 1.0129 0.3687E-16 0.3640E-16 H2,gas 0.6092E-06 1.0006 0.6412E-06 0.6409E-06 H2S,gas 0.3415E-14 0.9959 0.3578E-14 0.3592E-14 S2,gas 0.1108E-35 1.0000 0.1166E-35 0.1166E-35 CO,gas 0.3645E-15 1.0000 0.3834E-15 0.3834E-15 SO3,gas 0.6109E-38 1.0000 0.6426E-38 0.6426E-38 SO2,gas 0.1482E-21 1.0000 0.1559E-21 0.1559E-21 HCl,gas 0.3729E-16 1.0000 0.3923E-16 0.3923E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.48529E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.54595E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.72794E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.00 -7.64 -2.546 0.13039E+05 -5.637 3 CH4,gas 4.81 -13.62 -18.43 -4.608 0.31474E+05 -16.433 4 H2,gas 8.29 0.09 -8.19 -4.682 0.13989E+05 -6.193 5 H2S,gas -5.94 -22.39 -16.45 -8.223 0.28082E+05 -14.446 6 S2,gas -7.03 -44.97 -37.93 -5.836 0.64770E+05 -35.933 7 CO,gas 3.51 -13.91 -17.42 -5.359 0.29738E+05 -15.416 8 SO3,gas 17.43 -22.76 -40.19 -10.048 0.68627E+05 -38.192 9 SO2,gas 1.14 -22.67 -23.81 -6.349 0.40650E+05 -21.807 10 HCl,gas 5.48 -12.93 -18.41 -9.203 0.31428E+05 -16.406 11 acmite 7.74 5.89 -1.84 -0.192 0.31489E+04 15 albite-high 0.75 -1.14 -1.89 -0.145 0.32224E+04 16 albite -0.33 -1.14 -0.81 -0.062 0.13817E+04 19 spessartine 24.55 20.66 -3.89 -0.194 0.66359E+04 20 analcite 3.37 2.15 -1.22 -0.136 0.20844E+04 21 andalusite 5.06 1.82 -3.24 -0.324 0.55302E+04 22 andradite 39.09 34.22 -4.87 -0.253 0.83091E+04 26 annite 20.21 16.61 -3.60 -0.200 0.61534E+04 27 phlogopite 27.15 23.29 -3.86 -0.214 0.65856E+04 29 anorthite 12.80 9.03 -3.77 -0.290 0.64307E+04 35 aragonite 0.99 -3.50 -4.49 -1.497 0.76678E+04 36 brucite 12.58 8.57 -4.00 -0.801 0.68346E+04 37 calcite 0.83 -3.50 -4.34 -1.446 0.74065E+04 38 carnegieite-low 9.06 5.44 -3.63 -0.518 0.61934E+04 39 carnegieite-high 10.13 5.44 -4.70 -0.671 0.80202E+04 40 carpholite-Mg 8.65 7.11 -1.54 -0.103 0.26304E+04 41 carpholite-Fe 6.78 4.88 -1.90 -0.127 0.32460E+04 42 celadonite 5.40 2.85 -2.55 -0.150 0.43471E+04 43 celadonite-Fe 3.94 0.63 -3.31 -0.195 0.56525E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81802E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.191 0.48900E+04 51 chloritoid-Fe 9.24 8.17 -1.07 -0.071 0.18259E+04 52 chloritoid-Mn 11.46 10.30 -1.17 -0.078 0.19944E+04 54 coesite -2.37 -3.29 -0.92 -0.306 0.15677E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.29 -0.74 -0.246 0.12605E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.49 -3.72 -0.372 0.63538E+04 68 hedenbergite 14.24 10.27 -3.98 -0.398 0.67926E+04 75 epidote 24.78 22.54 -2.24 -0.108 0.38196E+04 76 clinozoisite 22.92 18.79 -4.13 -0.188 0.70455E+04 77 epidote-Fe 29.94 26.28 -3.66 -0.190 0.62413E+04 78 fayalite 14.08 9.40 -4.67 -0.668 0.79822E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63720E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.15 -2.10 -0.210 0.35875E+04 97 kalsilite 7.62 4.14 -3.48 -0.497 0.59371E+04 98 kaolinite -1.27 -1.46 -0.19 -0.017 0.32578E+03 99 kyanite 4.93 1.82 -3.11 -0.311 0.53070E+04 101 laumontite 2.97 2.46 -0.52 -0.035 0.88449E+03 102 lawsonite 9.68 9.03 -0.65 -0.043 0.11046E+04 103 leucite 4.17 0.86 -3.31 -0.331 0.56551E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70705E+04 107 magnetite 20.13 18.94 -1.19 -0.097 0.20309E+04 108 minnesotaite 10.46 5.89 -4.57 -0.269 0.78087E+04 113 margarite 17.45 14.14 -3.31 -0.132 0.56506E+04 121 paragonite 4.34 3.97 -0.36 -0.021 0.62020E+03 122 nepheline 8.38 5.44 -2.94 -0.420 0.50213E+04 136 prehnite 19.47 16.24 -3.23 -0.190 0.55099E+04 137 prehnite-Fe 22.59 19.98 -2.60 -0.157 0.44464E+04 145 pyroxmangite 7.42 5.18 -2.23 -0.446 0.38108E+04 146 pyrophyllite -6.10 -8.04 -1.94 -0.121 0.33139E+04 147 quartz -2.98 -3.29 -0.31 -0.102 0.52157E+03 151 rhodochrosite -0.96 -5.53 -4.57 -1.523 0.78027E+04 152 rhodonite 7.46 5.18 -2.28 -0.456 0.38901E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.82 -3.50 -0.350 0.59724E+04 164 stilpnomelane-Fe 13.18 12.98 -0.20 -0.006 0.34437E+03 165 stilpnomelane-Mg 27.60 24.12 -3.48 -0.104 0.59392E+04 168 sudoite 21.22 17.51 -3.71 -0.120 0.63330E+04 171 talc 16.55 12.57 -3.98 -0.234 0.67988E+04 174 tephroite 18.11 13.66 -4.46 -0.637 0.76104E+04 177 topaz-H 4.67 1.82 -2.84 -0.259 0.48561E+04 178 tridymite -2.61 -3.29 -0.67 -0.224 0.11489E+04 187 wairakite 4.06 2.46 -1.60 -0.094 0.27353E+04 188 walstromite 11.53 7.21 -4.32 -0.864 0.73762E+04 189 wollastonite 10.48 7.21 -3.27 -0.655 0.55901E+04 190 pseudo-wollastonite 11.02 7.21 -3.81 -0.762 0.65087E+04 191 zoisite 22.96 18.79 -4.17 -0.189 0.71180E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.38 -2.82 -0.174 0.48138E+04 194 beidellite-H -2.24 -6.11 -3.87 -0.247 0.66072E+04 195 beidellite-K -1.44 -4.50 -3.07 -0.188 0.52366E+04 196 beidellite-Mg -1.71 -4.70 -2.99 -0.185 0.51038E+04 197 beidellite-Na -1.26 -4.07 -2.82 -0.173 0.48113E+04 199 chalcedony -2.79 -3.29 -0.49 -0.164 0.84189E+03 201 montmorillonite-Ca -2.21 -4.32 -2.11 -0.130 0.35977E+04 202 montmorillonite-K -2.16 -4.44 -2.28 -0.140 0.38983E+04 203 montmorillonite-Mg -2.40 -4.64 -2.24 -0.138 0.38188E+04 204 montmorillonite-Na -1.96 -4.02 -2.06 -0.126 0.35111E+04 205 nontronite-Ca 3.28 3.11 -0.17 -0.011 0.29364E+03 206 nontronite-H 2.60 1.38 -1.22 -0.082 0.20828E+04 207 nontronite-K 3.40 2.98 -0.42 -0.027 0.71559E+03 208 nontronite-Mg 3.14 2.79 -0.35 -0.023 0.59528E+03 209 nontronite-Na 3.58 3.41 -0.17 -0.011 0.29199E+03 224 tobermorite 9.84 5.46 -4.38 -1.196 0.74852E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.35 -3.48 -0.870 0.59394E+04 240 silica-amorphous -2.08 -3.29 -1.21 -0.403 0.20621E+04 242 an20ab80 2.08 0.90 -1.18 -0.091 0.20199E+04 243 an25ab75 2.71 1.40 -1.30 -0.100 0.22274E+04 244 an30ab70 3.34 1.91 -1.43 -0.110 0.24432E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.0390000 g New total amount of reactant added: 1.0790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4567E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.0790000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5549E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .1042859E-02 Osmotic coef. = 0.9814 True ionic strength = .1604477E-02 Chg. balance for total moles = 0.4567E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.95312E-09 -9.0209 0.88934E-09 -9.0509 0.93309E+00 -0.0301 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12863E-03 -3.8907 0.93247E+00 -0.0304 4 SO4-- 0.25488E-04 -4.5937 0.20360E-04 -4.6912 0.79881E+00 -0.0976 5 HCO3- 0.11640E-04 -4.9341 0.10855E-04 -4.9644 0.93261E+00 -0.0303 6 HS- 0.45231E-13 -13.3446 0.42177E-13 -13.3749 0.93248E+00 -0.0304 7 Al+++ 0.41033E-24 -24.3869 0.25276E-24 -24.5973 0.61598E+00 -0.2104 8 H4SiO4 0.51797E-03 -3.2857 0.51797E-03 -3.2857 0.10000E+01 0.0000 9 Ca++ 0.30136E-07 -7.5209 0.24054E-07 -7.6188 0.79818E+00 -0.0979 10 Mg++ 0.37069E-09 -9.4310 0.29573E-09 -9.5291 0.79778E+00 -0.0981 11 Fe++ 0.21924E-11 -11.6591 0.17492E-11 -11.7572 0.79787E+00 -0.0981 12 K+ 0.70658E-04 -4.1508 0.65898E-04 -4.1811 0.93264E+00 -0.0303 13 Na+ 0.15014E-02 -2.8235 0.14000E-02 -2.8539 0.93245E+00 -0.0304 14 Mn++ 0.29292E-09 -9.5333 0.23373E-09 -9.6313 0.79795E+00 -0.0980 15 HPO4-- 0.53879E-05 -5.2686 0.43040E-05 -5.3661 0.79882E+00 -0.0975 16 HSiO3- 0.60940E-03 -3.2151 0.56824E-03 -3.2455 0.93247E+00 -0.0304 17 Ca(HSiO3)+ 0.32835E-09 -9.4837 0.30624E-09 -9.5139 0.93266E+00 -0.0303 18 Mg(HSiO3)+ 0.50241E-11 -11.2989 0.46857E-11 -11.3292 0.93266E+00 -0.0303 19 NaHSiO3,aq 0.12635E-04 -4.8984 0.12635E-04 -4.8984 0.10000E+01 0.0000 20 AlO+ 0.44233E-13 -13.3542 0.41255E-13 -13.3845 0.93266E+00 -0.0303 21 AlOH+2 0.23031E-18 -18.6377 0.18379E-18 -18.7357 0.79803E+00 -0.0980 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.24999E-04 -4.6021 0.23306E-04 -4.6325 0.93228E+00 -0.0305 24 CH4,aq 0.22074E-19 -19.6561 0.22067E-19 -19.6563 0.99968E+00 -0.0001 29 CO,aq 0.23323E-18 -18.6322 0.23323E-18 -18.6322 0.10000E+01 0.0000 30 CO2,aq 0.19471E-07 -7.7106 0.19465E-07 -7.7107 0.99968E+00 -0.0001 31 CO3-2 0.14132E-05 -5.8498 0.11286E-05 -5.9475 0.79862E+00 -0.0977 32 CaCO3,aq 0.33248E-09 -9.4782 0.33248E-09 -9.4782 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.70543E-11 -11.1515 0.65793E-11 -11.1818 0.93266E+00 -0.0303 34 CaCl+ 0.52862E-11 -11.2769 0.49302E-11 -11.3071 0.93266E+00 -0.0303 35 CaCl2,aq 0.14766E-15 -15.8307 0.14766E-15 -15.8307 0.10000E+01 0.0000 36 CaOH+ 0.20448E-08 -8.6893 0.19071E-08 -8.7196 0.93266E+00 -0.0303 37 CaSO4,aq 0.15259E-09 -9.8165 0.15259E-09 -9.8165 0.10000E+01 0.0000 38 HCl,aq 0.21517E-13 -13.6672 0.21517E-13 -13.6672 0.10000E+01 0.0000 43 FeCl+ 0.37574E-15 -15.4251 0.35044E-15 -15.4554 0.93266E+00 -0.0303 46 FeO,aq 0.87456E-10 -10.0582 0.87456E-10 -10.0582 0.10000E+01 0.0000 47 FeOH+ 0.69914E-10 -10.1554 0.65207E-10 -10.1857 0.93266E+00 -0.0303 48 HFeO2- 0.11343E-08 -8.9453 0.10577E-08 -8.9756 0.93247E+00 -0.0304 49 FeO+ 0.78879E-14 -14.1030 0.73568E-14 -14.1333 0.93266E+00 -0.0303 51 FeO2- 0.19605E-08 -8.7076 0.18281E-08 -8.7380 0.93247E+00 -0.0304 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.46539E-09 -9.3322 0.46524E-09 -9.3323 0.99968E+00 -0.0001 54 KCl,aq 0.15009E-09 -9.8237 0.15009E-09 -9.8237 0.10000E+01 0.0000 55 KHSO4,aq 0.31930E-17 -17.4958 0.31930E-17 -17.4958 0.10000E+01 0.0000 56 KOH,aq 0.32303E-07 -7.4908 0.32303E-07 -7.4908 0.10000E+01 0.0000 57 KSO4- 0.22167E-07 -7.6543 0.20670E-07 -7.6847 0.93247E+00 -0.0304 58 MgCO3,aq 0.10214E-11 -11.9908 0.10214E-11 -11.9908 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.88441E-13 -13.0533 0.82486E-13 -13.0836 0.93266E+00 -0.0303 60 MgCl+ 0.59001E-13 -13.2291 0.55028E-13 -13.2594 0.93266E+00 -0.0303 61 MgOH+ 0.13928E-09 -9.8561 0.12990E-09 -9.8864 0.93266E+00 -0.0303 63 MnO,aq 0.31196E-09 -9.5059 0.31196E-09 -9.5059 0.10000E+01 0.0000 64 MnOH+ 0.86784E-09 -9.0616 0.80940E-09 -9.0918 0.93266E+00 -0.0303 65 MnO2-2 0.17080E-13 -13.7675 0.13640E-13 -13.8652 0.79862E+00 -0.0977 66 HMnO2- 0.28187E-11 -11.5500 0.26283E-11 -11.5803 0.93247E+00 -0.0304 69 MnCl+ 0.19509E-12 -12.7098 0.18196E-12 -12.7400 0.93266E+00 -0.0303 70 MnSO4,aq 0.13486E-11 -11.8701 0.13486E-11 -11.8701 0.10000E+01 0.0000 71 NaCl,aq 0.58801E-07 -7.2306 0.58801E-07 -7.2306 0.10000E+01 0.0000 72 NaOH,aq 0.69171E-06 -6.1601 0.69171E-06 -6.1601 0.10000E+01 0.0000 74 OH- 0.72346E-03 -3.1406 0.67447E-03 -3.1710 0.93228E+00 -0.0305 79 HPO3-2 0.79193E-17 -17.1013 0.63245E-17 -17.1990 0.79862E+00 -0.0977 81 H2PO3- 0.11849E-19 -19.9263 0.11049E-19 -19.9567 0.93247E+00 -0.0304 82 H3PO4,aq 0.21916E-13 -13.6592 0.21916E-13 -13.6592 0.10000E+01 0.0000 83 H2PO4- 0.71960E-07 -7.1429 0.67107E-07 -7.1732 0.93256E+00 -0.0303 84 PO4-3 0.68242E-08 -8.1659 0.42264E-08 -8.3740 0.61932E+00 -0.2081 87 H2P2O7-2 0.44133E-15 -15.3552 0.35246E-15 -15.4529 0.79862E+00 -0.0977 88 HP2O7-3 0.13192E-12 -12.8797 0.81265E-13 -13.0901 0.61602E+00 -0.2104 89 P2O7-4 0.52454E-13 -13.2802 0.22542E-13 -13.6470 0.42976E+00 -0.3668 90 H2S,aq 0.11274E-15 -15.9479 0.11270E-15 -15.9481 0.99968E+00 -0.0001 97 SO3-2 0.16146E-14 -14.7919 0.12915E-14 -14.8889 0.79990E+00 -0.0970 98 HSO3- 0.72086E-16 -16.1421 0.67218E-16 -16.1725 0.93247E+00 -0.0304 99 HSO4- 0.18012E-10 -10.7444 0.16801E-10 -10.7747 0.93276E+00 -0.0302 Charge balance for all species = 0.4648E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9531210E-09 -.1447585E-02 -.1458851E+01 0.0000 2 H2O 0.1000000E+01 0.5550840E+02 0.9998450E+06 0.0000 3 Cl- 0.1379444E-03 0.1380034E-03 0.4891872E+01 5.1603 4 SO4-- 0.2548753E-04 0.2551002E-04 0.2450152E+01 13.4106 5 HCO3- 0.1163980E-04 0.1307276E-04 0.7975394E+00 4.0866 6 HS- 0.4523145E-13 -.1541054E-09 -.5095782E-05 -4.3240 7 Al+++ 0.4103283E-24 0.2500843E-04 0.6746599E+00 2.5555 8 H4SiO4 0.5179664E-03 0.1139999E-02 0.1095544E+03 -3.2857 9 Ca++ 0.3013571E-07 0.3300628E-07 0.1322620E-02 10.4830 10 Mg++ 0.3706915E-09 0.5161628E-09 0.1254700E-04 8.5728 11 Fe++ 0.2192354E-11 0.3457874E-08 0.1930819E-03 6.3447 12 K+ 0.7065788E-04 0.7071250E-04 0.2764570E+01 4.8698 13 Na+ 0.1501414E-02 0.1514799E-02 0.3481951E+02 6.1971 14 Mn++ 0.2929152E-09 0.1477085E-08 0.8113549E-04 8.4706 15 HPO4-- 0.5387868E-05 0.5466653E-05 0.5246023E+00 12.7357 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1785360E-01 -.1447278E-02 -.1640632E-01 0.0000000E+00 2 H2O 0.5549472E+02 0.5549666E+02 -.1939434E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5540724E-04 0.2550462E-04 0.2990261E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2990277E-04 -.1540728E-09 -.2990261E-04 0.0000000E+00 7 Al+++ 0.3518340E-02 0.2500314E-04 0.3493337E-02 0.0000000E+00 8 H4SiO4 0.1123539E-01 0.1139758E-02 0.1009563E-01 0.0000000E+00 9 Ca++ 0.1255475E-02 0.3299931E-07 0.1255442E-02 0.0000000E+00 10 Mg++ 0.8563492E-03 0.5160536E-09 0.8563487E-03 0.0000000E+00 11 Fe++ 0.7693363E-03 0.3457143E-08 0.7693328E-03 0.0000000E+00 12 K+ 0.2290870E-03 0.7069754E-04 0.1583895E-03 0.0000000E+00 13 Na+ 0.1514479E-02 0.1514479E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1870835E-04 0.1476773E-08 0.1870687E-04 0.0000000E+00 15 HPO4-- 0.6385065E-05 0.5465497E-05 0.9195683E-06 0.0000000E+00 Chg. balance for solid moles: -.3399E-17 Mass of aqueous solution: 0.999944E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.0790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3065E-06 -6.514 0.1540E-03 -3.813 0.1355E-01 0.4893E-04 clinochlore 0.1713E-03 -3.766 0.9520E-01 -1.021 8.377 0.3621E-01 daphnite 0.1060E-03 -3.975 0.7565E-01 -1.121 6.657 0.2292E-01 chlorite-Mn 0.3741E-05 -5.427 0.2653E-02 -2.576 0.2334 0.8453E-03 hematite 0.1196E-03 -3.922 0.1910E-01 -1.719 1.681 0.3621E-02 microcline 0.2586E-04 -4.587 0.7197E-02 -2.143 0.6334 0.2812E-02 muscovite 0.1325E-03 -3.878 0.5279E-01 -1.277 4.645 0.1867E-01 stilbite 0.1254E-02 -2.902 0.8837 -0.054 77.76 0.4122 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.136394 g Volume = 0.497279 cm3 Porosity: 65.2641% V(tot) - V(min): 0.93432E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.0790000 g log = 0.0330 Original solution: 1000.0103000 g Original solution / Rock added: 926.79 (Water/Rock Ratio), log = 2.9670 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2103E-05 1.0073 0.2228E-05 0.2212E-05 CH4,gas 0.3275E-16 1.0129 0.3490E-16 0.3445E-16 H2,gas 0.6063E-06 1.0006 0.6381E-06 0.6378E-06 H2S,gas 0.3138E-14 0.9959 0.3287E-14 0.3301E-14 S2,gas 0.9448E-36 1.0000 0.9939E-36 0.9939E-36 CO,gas 0.3501E-15 1.0000 0.3683E-15 0.3683E-15 SO3,gas 0.5723E-38 1.0000 0.6020E-38 0.6020E-38 SO2,gas 0.1382E-21 1.0000 0.1453E-21 0.1453E-21 HCl,gas 0.3612E-16 1.0000 0.3799E-16 0.3799E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.48529E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.02 -7.65 -2.551 0.13066E+05 -5.652 3 CH4,gas 4.81 -13.65 -18.46 -4.614 0.31515E+05 -16.457 4 H2,gas 8.29 0.09 -8.20 -4.683 0.13993E+05 -6.195 5 H2S,gas -5.94 -22.43 -16.48 -8.242 0.28145E+05 -14.483 6 S2,gas -7.03 -45.04 -38.00 -5.847 0.64889E+05 -36.003 7 CO,gas 3.51 -13.92 -17.43 -5.364 0.29768E+05 -15.434 8 SO3,gas 17.43 -22.79 -40.22 -10.055 0.68675E+05 -38.220 9 SO2,gas 1.14 -22.70 -23.84 -6.357 0.40702E+05 -21.838 10 HCl,gas 5.48 -12.94 -18.42 -9.210 0.31452E+05 -16.420 11 acmite 7.74 5.92 -1.81 -0.188 0.30955E+04 15 albite-high 0.75 -1.10 -1.85 -0.143 0.31660E+04 16 albite -0.33 -1.10 -0.78 -0.060 0.13253E+04 19 spessartine 24.55 20.67 -3.88 -0.194 0.66323E+04 20 analcite 3.37 2.18 -1.19 -0.132 0.20310E+04 21 andalusite 5.06 1.83 -3.24 -0.324 0.55272E+04 22 andradite 39.09 34.19 -4.90 -0.254 0.83634E+04 26 annite 20.21 16.60 -3.61 -0.200 0.61589E+04 27 phlogopite 27.15 23.29 -3.86 -0.214 0.65910E+04 29 anorthite 12.80 9.02 -3.78 -0.290 0.64458E+04 35 aragonite 0.99 -3.53 -4.52 -1.506 0.77151E+04 36 brucite 12.58 8.57 -4.00 -0.801 0.68365E+04 37 calcite 0.83 -3.53 -4.37 -1.455 0.74538E+04 38 carnegieite-low 9.06 5.47 -3.60 -0.514 0.61430E+04 39 carnegieite-high 10.13 5.47 -4.67 -0.667 0.79698E+04 40 carpholite-Mg 8.65 7.11 -1.54 -0.103 0.26261E+04 41 carpholite-Fe 6.78 4.88 -1.90 -0.127 0.32418E+04 42 celadonite 5.40 2.86 -2.55 -0.150 0.43459E+04 43 celadonite-Fe 3.94 0.63 -3.31 -0.195 0.56513E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81796E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.191 0.48888E+04 51 chloritoid-Fe 9.24 8.17 -1.07 -0.071 0.18247E+04 52 chloritoid-Mn 11.46 10.30 -1.17 -0.078 0.19932E+04 54 coesite -2.37 -3.29 -0.92 -0.305 0.15646E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.29 -0.74 -0.245 0.12575E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.48 -3.73 -0.373 0.63707E+04 68 hedenbergite 14.24 10.26 -3.99 -0.399 0.68095E+04 75 epidote 24.78 22.52 -2.26 -0.109 0.38528E+04 76 clinozoisite 22.92 18.78 -4.15 -0.188 0.70786E+04 77 epidote-Fe 29.94 26.26 -3.67 -0.191 0.62744E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79828E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63714E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.18 -2.07 -0.207 0.35340E+04 97 kalsilite 7.62 4.14 -3.48 -0.497 0.59431E+04 98 kaolinite -1.27 -1.46 -0.19 -0.017 0.31975E+03 99 kyanite 4.93 1.83 -3.11 -0.311 0.53040E+04 101 laumontite 2.97 2.45 -0.52 -0.035 0.89353E+03 102 lawsonite 9.68 9.02 -0.66 -0.044 0.11197E+04 103 leucite 4.17 0.85 -3.31 -0.331 0.56581E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70699E+04 107 magnetite 20.13 18.94 -1.19 -0.097 0.20327E+04 108 minnesotaite 10.46 5.89 -4.57 -0.269 0.78021E+04 113 margarite 17.45 14.13 -3.32 -0.133 0.56657E+04 121 paragonite 4.34 4.01 -0.33 -0.019 0.56377E+03 122 nepheline 8.38 5.47 -2.91 -0.416 0.49709E+04 136 prehnite 19.47 16.22 -3.25 -0.191 0.55431E+04 137 prehnite-Fe 22.59 19.96 -2.62 -0.158 0.44795E+04 145 pyroxmangite 7.42 5.18 -2.23 -0.446 0.38096E+04 146 pyrophyllite -6.10 -8.03 -1.93 -0.121 0.33019E+04 147 quartz -2.98 -3.29 -0.30 -0.101 0.51856E+03 151 rhodochrosite -0.96 -5.54 -4.59 -1.529 0.78308E+04 152 rhodonite 7.46 5.18 -2.28 -0.456 0.38889E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.83 -3.50 -0.350 0.59694E+04 164 stilpnomelane-Fe 13.18 12.98 -0.20 -0.006 0.33383E+03 165 stilpnomelane-Mg 27.60 24.12 -3.47 -0.104 0.59286E+04 168 sudoite 21.22 17.51 -3.71 -0.120 0.63275E+04 171 talc 16.55 12.58 -3.98 -0.234 0.67921E+04 174 tephroite 18.11 13.66 -4.46 -0.637 0.76110E+04 177 topaz-H 4.67 1.83 -2.84 -0.258 0.48531E+04 178 tridymite -2.61 -3.29 -0.67 -0.224 0.11459E+04 187 wairakite 4.06 2.45 -1.61 -0.095 0.27443E+04 188 walstromite 11.53 7.20 -4.33 -0.866 0.73943E+04 189 wollastonite 10.48 7.20 -3.28 -0.657 0.56081E+04 190 pseudo-wollastonite 11.02 7.20 -3.82 -0.764 0.65268E+04 191 zoisite 22.96 18.78 -4.19 -0.190 0.71512E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.37 -2.81 -0.174 0.48063E+04 194 beidellite-H -2.24 -6.10 -3.86 -0.247 0.65961E+04 195 beidellite-K -1.44 -4.50 -3.06 -0.188 0.52285E+04 196 beidellite-Mg -1.71 -4.69 -2.98 -0.185 0.50931E+04 197 beidellite-Na -1.26 -4.06 -2.80 -0.172 0.47846E+04 199 chalcedony -2.79 -3.29 -0.49 -0.164 0.83887E+03 201 montmorillonite-Ca -2.21 -4.32 -2.10 -0.130 0.35898E+04 202 montmorillonite-K -2.16 -4.44 -2.28 -0.140 0.38898E+04 203 montmorillonite-Mg -2.40 -4.63 -2.23 -0.138 0.38076E+04 204 montmorillonite-Na -1.96 -4.00 -2.04 -0.125 0.34840E+04 205 nontronite-Ca 3.28 3.11 -0.17 -0.011 0.28606E+03 206 nontronite-H 2.60 1.38 -1.21 -0.081 0.20717E+04 207 nontronite-K 3.40 2.99 -0.41 -0.027 0.70751E+03 208 nontronite-Mg 3.14 2.80 -0.34 -0.022 0.58451E+03 209 nontronite-Na 3.58 3.43 -0.16 -0.010 0.26529E+03 224 tobermorite 9.84 5.45 -4.39 -1.198 0.74998E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.34 -3.48 -0.870 0.59412E+04 240 silica-amorphous -2.08 -3.29 -1.21 -0.402 0.20591E+04 242 an20ab80 2.08 0.92 -1.16 -0.089 0.19778E+04 243 an25ab75 2.71 1.43 -1.28 -0.099 0.21888E+04 244 an30ab70 3.34 1.93 -1.41 -0.108 0.24082E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.0790000 g New total amount of reactant added: 1.1190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4567E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.1190000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1071333E-02 Osmotic coef. = 0.9811 True ionic strength = .1651601E-02 Chg. balance for total moles = 0.4567E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92540E-09 -9.0337 0.86287E-09 -9.0641 0.93243E+00 -0.0304 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12854E-03 -3.8910 0.93180E+00 -0.0307 4 SO4-- 0.25489E-04 -4.5937 0.20303E-04 -4.6924 0.79655E+00 -0.0988 5 HCO3- 0.11599E-04 -4.9356 0.10810E-04 -4.9662 0.93195E+00 -0.0306 6 HS- 0.42970E-13 -13.3668 0.40040E-13 -13.3975 0.93181E+00 -0.0307 7 Al+++ 0.37718E-24 -24.4235 0.23085E-24 -24.6367 0.61204E+00 -0.2132 8 H4SiO4 0.52002E-03 -3.2840 0.52002E-03 -3.2840 0.10000E+01 0.0000 9 Ca++ 0.27672E-07 -7.5580 0.22024E-07 -7.6571 0.79590E+00 -0.0991 10 Mg++ 0.34912E-09 -9.4570 0.27773E-09 -9.5564 0.79549E+00 -0.0994 11 Fe++ 0.20648E-11 -11.6851 0.16427E-11 -11.7844 0.79559E+00 -0.0993 12 K+ 0.67794E-04 -4.1688 0.63182E-04 -4.1994 0.93198E+00 -0.0306 13 Na+ 0.15507E-02 -2.8095 0.14450E-02 -2.8401 0.93178E+00 -0.0307 14 Mn++ 0.27587E-09 -9.5593 0.21950E-09 -9.6586 0.79566E+00 -0.0993 15 HPO4-- 0.60110E-05 -5.2211 0.47881E-05 -5.3198 0.79656E+00 -0.0988 16 HSiO3- 0.63104E-03 -3.1999 0.58800E-03 -3.2306 0.93180E+00 -0.0307 17 Ca(HSiO3)+ 0.31132E-09 -9.5068 0.29015E-09 -9.5374 0.93200E+00 -0.0306 18 Mg(HSiO3)+ 0.48857E-11 -11.3111 0.45535E-11 -11.3417 0.93200E+00 -0.0306 19 NaHSiO3,aq 0.13494E-04 -4.8699 0.13494E-04 -4.8699 0.10000E+01 0.0000 20 AlO+ 0.42947E-13 -13.3671 0.40027E-13 -13.3976 0.93200E+00 -0.0306 21 AlOH+2 0.21742E-18 -18.6627 0.17301E-18 -18.7619 0.79575E+00 -0.0992 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.25785E-04 -4.5886 0.24021E-04 -4.6194 0.93161E+00 -0.0308 24 CH4,aq 0.20926E-19 -19.6793 0.20919E-19 -19.6795 0.99967E+00 -0.0001 29 CO,aq 0.22427E-18 -18.6492 0.22427E-18 -18.6492 0.10000E+01 0.0000 30 CO2,aq 0.18812E-07 -7.7256 0.18806E-07 -7.7257 0.99967E+00 -0.0001 31 CO3-2 0.14545E-05 -5.8373 0.11583E-05 -5.9362 0.79636E+00 -0.0989 32 CaCO3,aq 0.31245E-09 -9.5052 0.31245E-09 -9.5052 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.64366E-11 -11.1913 0.59989E-11 -11.2219 0.93200E+00 -0.0306 34 CaCl+ 0.48402E-11 -11.3151 0.45110E-11 -11.3457 0.93200E+00 -0.0306 35 CaCl2,aq 0.13500E-15 -15.8697 0.13500E-15 -15.8697 0.10000E+01 0.0000 36 CaOH+ 0.19311E-08 -8.7142 0.17998E-08 -8.7448 0.93200E+00 -0.0306 37 CaSO4,aq 0.13932E-09 -9.8560 0.13932E-09 -9.8560 0.10000E+01 0.0000 38 HCl,aq 0.20862E-13 -13.6806 0.20862E-13 -13.6806 0.10000E+01 0.0000 43 FeCl+ 0.35286E-15 -15.4524 0.32887E-15 -15.4830 0.93200E+00 -0.0306 46 FeO,aq 0.87248E-10 -10.0592 0.87248E-10 -10.0592 0.10000E+01 0.0000 47 FeOH+ 0.67721E-10 -10.1693 0.63116E-10 -10.1999 0.93200E+00 -0.0306 48 HFeO2- 0.11672E-08 -8.9329 0.10876E-08 -8.9635 0.93180E+00 -0.0307 49 FeO+ 0.76586E-14 -14.1159 0.71378E-14 -14.1464 0.93200E+00 -0.0306 51 FeO2- 0.20221E-08 -8.6942 0.18842E-08 -8.7249 0.93180E+00 -0.0307 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.46319E-09 -9.3342 0.46303E-09 -9.3344 0.99967E+00 -0.0001 54 KCl,aq 0.14380E-09 -9.8422 0.14380E-09 -9.8422 0.10000E+01 0.0000 55 KHSO4,aq 0.29620E-17 -17.5284 0.29620E-17 -17.5284 0.10000E+01 0.0000 56 KOH,aq 0.31922E-07 -7.4959 0.31922E-07 -7.4959 0.10000E+01 0.0000 57 KSO4- 0.21210E-07 -7.6735 0.19763E-07 -7.7041 0.93180E+00 -0.0307 58 MgCO3,aq 0.98452E-12 -12.0068 0.98452E-12 -12.0068 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.82767E-13 -13.0821 0.77139E-13 -13.1127 0.93200E+00 -0.0306 60 MgCl+ 0.55408E-13 -13.2564 0.51640E-13 -13.2870 0.93200E+00 -0.0306 61 MgOH+ 0.13491E-09 -9.8700 0.12573E-09 -9.9005 0.93200E+00 -0.0306 63 MnO,aq 0.31122E-09 -9.5069 0.31122E-09 -9.5069 0.10000E+01 0.0000 64 MnOH+ 0.84061E-09 -9.0754 0.78345E-09 -9.1060 0.93200E+00 -0.0306 65 MnO2-2 0.18152E-13 -13.7411 0.14456E-13 -13.8400 0.79636E+00 -0.0989 66 HMnO2- 0.29003E-11 -11.5376 0.27025E-11 -11.5682 0.93180E+00 -0.0307 69 MnCl+ 0.18322E-12 -12.7370 0.17076E-12 -12.7676 0.93200E+00 -0.0306 70 MnSO4,aq 0.12630E-11 -11.8986 0.12630E-11 -11.8986 0.10000E+01 0.0000 71 NaCl,aq 0.60645E-07 -7.2172 0.60645E-07 -7.2172 0.10000E+01 0.0000 72 NaOH,aq 0.73583E-06 -6.1332 0.73583E-06 -6.1332 0.10000E+01 0.0000 74 OH- 0.74620E-03 -3.1271 0.69516E-03 -3.1579 0.93161E+00 -0.0308 79 HPO3-2 0.87934E-17 -17.0558 0.70027E-17 -17.1547 0.79636E+00 -0.0989 81 H2PO3- 0.12738E-19 -19.8949 0.11869E-19 -19.9256 0.93180E+00 -0.0307 82 H3PO4,aq 0.22951E-13 -13.6392 0.22951E-13 -13.6392 0.10000E+01 0.0000 83 H2PO4- 0.77728E-07 -7.1094 0.72434E-07 -7.1401 0.93190E+00 -0.0306 84 PO4-3 0.78740E-08 -8.1038 0.48461E-08 -8.3146 0.61545E+00 -0.2108 87 H2P2O7-2 0.51564E-15 -15.2877 0.41064E-15 -15.3865 0.79636E+00 -0.0989 88 HP2O7-3 0.15943E-12 -12.7974 0.97584E-13 -13.0106 0.61208E+00 -0.2132 89 P2O7-4 0.65659E-13 -13.1827 0.27900E-13 -13.5544 0.42492E+00 -0.3717 90 H2S,aq 0.10384E-15 -15.9836 0.10381E-15 -15.9838 0.99967E+00 -0.0001 97 SO3-2 0.16070E-14 -14.7940 0.12818E-14 -14.8922 0.79766E+00 -0.0982 98 HSO3- 0.69465E-16 -16.1582 0.64727E-16 -16.1889 0.93180E+00 -0.0307 99 HSO4- 0.17439E-10 -10.7585 0.16255E-10 -10.7890 0.93210E+00 -0.0305 Charge balance for all species = 0.4646E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9253983E-09 -.1496041E-02 -.1507680E+01 0.0000 2 H2O 0.1000000E+01 0.5550840E+02 0.9998415E+06 0.0000 3 Cl- 0.1379436E-03 0.1380044E-03 0.4891890E+01 5.1731 4 SO4-- 0.2548868E-04 0.2551021E-04 0.2450162E+01 13.4357 5 HCO3- 0.1159921E-04 0.1307286E-04 0.7975424E+00 4.0979 6 HS- 0.4297023E-13 -.1623576E-09 -.5368636E-05 -4.3334 7 Al+++ 0.3771788E-24 0.2579402E-04 0.6958506E+00 2.5555 8 H4SiO4 0.5200204E-03 0.1164552E-02 0.1119135E+03 -3.2840 9 Ca++ 0.2767216E-07 0.3037766E-07 0.1217282E-02 10.4710 10 Mg++ 0.3491248E-09 0.4900414E-09 0.1191199E-04 8.5717 11 Fe++ 0.2064796E-11 0.3549807E-08 0.1982146E-03 6.3437 12 K+ 0.6779388E-04 0.6784716E-04 0.2652538E+01 4.8646 13 Na+ 0.1550740E-02 0.1565031E-02 0.3597402E+02 6.2239 14 Mn++ 0.2758733E-09 0.1432064E-08 0.7866224E-04 8.4695 15 HPO4-- 0.6010999E-05 0.6096601E-05 0.5850526E+00 12.8083 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1851594E-01 -.1495714E-02 -.1702022E-01 0.0000000E+00 2 H2O 0.5549422E+02 0.5549627E+02 -.2045362E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5651577E-04 0.2550463E-04 0.3101114E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3101130E-04 -.1623221E-09 -.3101114E-04 0.0000000E+00 7 Al+++ 0.3648770E-02 0.2578838E-04 0.3622981E-02 0.0000000E+00 8 H4SiO4 0.1165190E-01 0.1164297E-02 0.1048761E-01 0.0000000E+00 9 Ca++ 0.1301481E-02 0.3037102E-07 0.1301450E-02 0.0000000E+00 10 Mg++ 0.8880952E-03 0.4899342E-09 0.8880947E-03 0.0000000E+00 11 Fe++ 0.7978566E-03 0.3549031E-08 0.7978531E-03 0.0000000E+00 12 K+ 0.2375796E-03 0.6783232E-04 0.1697473E-03 0.0000000E+00 13 Na+ 0.1564689E-02 0.1564689E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1940189E-04 0.1431751E-08 0.1940046E-04 0.0000000E+00 15 HPO4-- 0.6621768E-05 0.6095268E-05 0.5265001E-06 0.0000000E+00 Chg. balance for solid moles: -.3153E-17 Mass of aqueous solution: 0.999940E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.1190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1755E-06 -6.756 0.8816E-04 -4.055 0.7472E-02 0.2801E-04 clinochlore 0.1776E-03 -3.751 0.9873E-01 -1.006 8.368 0.3755E-01 daphnite 0.1100E-03 -3.959 0.7845E-01 -1.105 6.650 0.2377E-01 chlorite-Mn 0.3880E-05 -5.411 0.2751E-02 -2.561 0.2332 0.8766E-03 hematite 0.1240E-03 -3.906 0.1981E-01 -1.703 1.679 0.3755E-02 microcline 0.3515E-04 -4.454 0.9785E-02 -2.009 0.8294 0.3822E-02 muscovite 0.1346E-03 -3.871 0.5361E-01 -1.271 4.544 0.1896E-01 stilbite 0.1301E-02 -2.886 0.9165 -0.038 77.69 0.4275 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.179761 g Volume = 0.516255 cm3 Porosity: 64.3372% V(tot) - V(min): 0.93135E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.1190000 g log = 0.0488 Original solution: 1000.0103000 g Original solution / Rock added: 893.66 (Water/Rock Ratio), log = 2.9512 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2032E-05 1.0073 0.2153E-05 0.2137E-05 CH4,gas 0.3105E-16 1.0129 0.3308E-16 0.3266E-16 H2,gas 0.6034E-06 1.0006 0.6351E-06 0.6347E-06 H2S,gas 0.2890E-14 0.9959 0.3028E-14 0.3040E-14 S2,gas 0.8092E-36 1.0000 0.8512E-36 0.8512E-36 CO,gas 0.3366E-15 1.0000 0.3541E-15 0.3541E-15 SO3,gas 0.5372E-38 1.0000 0.5651E-38 0.5651E-38 SO2,gas 0.1291E-21 1.0000 0.1358E-21 0.1358E-21 HCl,gas 0.3502E-16 1.0000 0.3684E-16 0.3684E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.03 -7.67 -2.556 0.13091E+05 -5.667 3 CH4,gas 4.81 -13.67 -18.48 -4.620 0.31555E+05 -16.480 4 H2,gas 8.29 0.09 -8.20 -4.684 0.13996E+05 -6.197 5 H2S,gas -5.94 -22.46 -16.52 -8.259 0.28206E+05 -14.519 6 S2,gas -7.03 -45.10 -38.07 -5.857 0.65003E+05 -36.070 7 CO,gas 3.51 -13.94 -17.45 -5.369 0.29797E+05 -15.451 8 SO3,gas 17.43 -22.82 -40.25 -10.062 0.68722E+05 -38.248 9 SO2,gas 1.14 -22.73 -23.87 -6.365 0.40753E+05 -21.867 10 HCl,gas 5.48 -12.96 -18.43 -9.217 0.31475E+05 -16.434 11 acmite 7.74 5.95 -1.78 -0.185 0.30438E+04 15 albite-high 0.75 -1.07 -1.82 -0.140 0.31113E+04 16 albite -0.33 -1.07 -0.74 -0.057 0.12707E+04 19 spessartine 24.55 20.67 -3.88 -0.194 0.66288E+04 20 analcite 3.37 2.21 -1.16 -0.129 0.19793E+04 21 andalusite 5.06 1.83 -3.24 -0.324 0.55243E+04 22 andradite 39.09 34.16 -4.93 -0.256 0.84162E+04 26 annite 20.21 16.60 -3.61 -0.201 0.61641E+04 27 phlogopite 27.15 23.28 -3.86 -0.215 0.65963E+04 29 anorthite 12.80 9.01 -3.78 -0.291 0.64605E+04 35 aragonite 0.99 -3.56 -4.55 -1.515 0.77612E+04 36 brucite 12.58 8.57 -4.00 -0.801 0.68382E+04 37 calcite 0.83 -3.56 -4.39 -1.464 0.74999E+04 38 carnegieite-low 9.06 5.50 -3.57 -0.510 0.60942E+04 39 carnegieite-high 10.13 5.50 -4.64 -0.663 0.79211E+04 40 carpholite-Mg 8.65 7.11 -1.54 -0.102 0.26220E+04 41 carpholite-Fe 6.78 4.89 -1.90 -0.126 0.32377E+04 42 celadonite 5.40 2.86 -2.54 -0.150 0.43448E+04 43 celadonite-Fe 3.94 0.63 -3.31 -0.195 0.56501E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81790E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.191 0.48876E+04 51 chloritoid-Fe 9.24 8.17 -1.07 -0.071 0.18236E+04 52 chloritoid-Mn 11.46 10.30 -1.17 -0.078 0.19920E+04 54 coesite -2.37 -3.28 -0.91 -0.305 0.15617E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.28 -0.73 -0.245 0.12546E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.47 -3.74 -0.374 0.63871E+04 68 hedenbergite 14.24 10.25 -4.00 -0.400 0.68259E+04 75 epidote 24.78 22.50 -2.28 -0.110 0.38850E+04 76 clinozoisite 22.92 18.76 -4.16 -0.189 0.71109E+04 77 epidote-Fe 29.94 26.24 -3.69 -0.192 0.63067E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79834E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63708E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.21 -2.04 -0.204 0.34823E+04 97 kalsilite 7.62 4.14 -3.48 -0.498 0.59490E+04 98 kaolinite -1.27 -1.46 -0.18 -0.017 0.31388E+03 99 kyanite 4.93 1.83 -3.10 -0.310 0.53011E+04 101 laumontite 2.97 2.45 -0.53 -0.035 0.90233E+03 102 lawsonite 9.68 9.01 -0.66 -0.044 0.11343E+04 103 leucite 4.17 0.85 -3.32 -0.332 0.56610E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70693E+04 107 magnetite 20.13 18.94 -1.19 -0.097 0.20344E+04 108 minnesotaite 10.46 5.90 -4.57 -0.269 0.77957E+04 113 margarite 17.45 14.13 -3.33 -0.133 0.56804E+04 121 paragonite 4.34 4.04 -0.30 -0.018 0.50913E+03 122 nepheline 8.38 5.50 -2.88 -0.412 0.49221E+04 136 prehnite 19.47 16.20 -3.27 -0.192 0.55753E+04 137 prehnite-Fe 22.59 19.94 -2.64 -0.159 0.45118E+04 145 pyroxmangite 7.42 5.19 -2.23 -0.446 0.38085E+04 146 pyrophyllite -6.10 -8.02 -1.93 -0.120 0.32901E+04 147 quartz -2.98 -3.28 -0.30 -0.101 0.51562E+03 151 rhodochrosite -0.96 -5.56 -4.60 -1.534 0.78580E+04 152 rhodonite 7.46 5.19 -2.28 -0.455 0.38877E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.83 -3.49 -0.349 0.59665E+04 164 stilpnomelane-Fe 13.18 12.99 -0.19 -0.006 0.32355E+03 165 stilpnomelane-Mg 27.60 24.13 -3.47 -0.103 0.59184E+04 168 sudoite 21.22 17.51 -3.70 -0.119 0.63222E+04 171 talc 16.55 12.58 -3.97 -0.234 0.67857E+04 174 tephroite 18.11 13.66 -4.46 -0.637 0.76115E+04 177 topaz-H 4.67 1.83 -2.84 -0.258 0.48502E+04 178 tridymite -2.61 -3.28 -0.67 -0.223 0.11429E+04 187 wairakite 4.06 2.45 -1.61 -0.095 0.27531E+04 188 walstromite 11.53 7.19 -4.34 -0.868 0.74119E+04 189 wollastonite 10.48 7.19 -3.29 -0.659 0.56258E+04 190 pseudo-wollastonite 11.02 7.19 -3.83 -0.767 0.65444E+04 191 zoisite 22.96 18.76 -4.21 -0.191 0.71834E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.37 -2.81 -0.174 0.47989E+04 194 beidellite-H -2.24 -6.10 -3.86 -0.246 0.65854E+04 195 beidellite-K -1.44 -4.49 -3.06 -0.187 0.52207E+04 196 beidellite-Mg -1.71 -4.68 -2.98 -0.184 0.50826E+04 197 beidellite-Na -1.26 -4.04 -2.79 -0.171 0.47587E+04 199 chalcedony -2.79 -3.28 -0.49 -0.163 0.83594E+03 201 montmorillonite-Ca -2.21 -4.31 -2.10 -0.130 0.35820E+04 202 montmorillonite-K -2.16 -4.43 -2.27 -0.139 0.38815E+04 203 montmorillonite-Mg -2.40 -4.63 -2.22 -0.138 0.37968E+04 204 montmorillonite-Na -1.96 -3.99 -2.03 -0.124 0.34577E+04 205 nontronite-Ca 3.28 3.12 -0.16 -0.011 0.27868E+03 206 nontronite-H 2.60 1.39 -1.21 -0.081 0.20609E+04 207 nontronite-K 3.40 2.99 -0.41 -0.026 0.69965E+03 208 nontronite-Mg 3.14 2.80 -0.34 -0.022 0.57403E+03 209 nontronite-Na 3.58 3.44 -0.14 -0.009 0.23939E+03 224 tobermorite 9.84 5.44 -4.40 -1.201 0.75140E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.34 -3.48 -0.870 0.59429E+04 240 silica-amorphous -2.08 -3.28 -1.20 -0.401 0.20561E+04 242 an20ab80 2.08 0.94 -1.13 -0.087 0.19370E+04 243 an25ab75 2.71 1.45 -1.26 -0.097 0.21515E+04 244 an30ab70 3.34 1.95 -1.39 -0.107 0.23743E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.1190000 g New total amount of reactant added: 1.1590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4568E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.1590000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1100007E-02 Osmotic coef. = 0.9809 True ionic strength = .1698948E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.89930E-09 -9.0461 0.83796E-09 -9.0768 0.93179E+00 -0.0307 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12844E-03 -3.8913 0.93114E+00 -0.0310 4 SO4-- 0.25490E-04 -4.5936 0.20247E-04 -4.6936 0.79432E+00 -0.1000 5 HCO3- 0.11559E-04 -4.9371 0.10765E-04 -4.9680 0.93129E+00 -0.0309 6 HS- 0.40888E-13 -13.3884 0.38073E-13 -13.4194 0.93115E+00 -0.0310 7 Al+++ 0.34764E-24 -24.4589 0.21142E-24 -24.6748 0.60817E+00 -0.2160 8 H4SiO4 0.52201E-03 -3.2823 0.52201E-03 -3.2823 0.10000E+01 0.0000 9 Ca++ 0.25481E-07 -7.5938 0.20223E-07 -7.6942 0.79366E+00 -0.1004 10 Mg++ 0.32943E-09 -9.4822 0.26132E-09 -9.5828 0.79324E+00 -0.1006 11 Fe++ 0.19483E-11 -11.7103 0.15457E-11 -11.8109 0.79334E+00 -0.1005 12 K+ 0.65132E-04 -4.1862 0.60659E-04 -4.2171 0.93132E+00 -0.0309 13 Na+ 0.16000E-02 -2.7959 0.14898E-02 -2.8269 0.93112E+00 -0.0310 14 Mn++ 0.26031E-09 -9.5845 0.20654E-09 -9.6850 0.79342E+00 -0.1005 15 HPO4-- 0.66828E-05 -5.1750 0.53084E-05 -5.2750 0.79434E+00 -0.1000 16 HSiO3- 0.65275E-03 -3.1853 0.60780E-03 -3.2162 0.93114E+00 -0.0310 17 Ca(HSiO3)+ 0.29569E-09 -9.5292 0.27539E-09 -9.5600 0.93134E+00 -0.0309 18 Mg(HSiO3)+ 0.47552E-11 -11.3228 0.44288E-11 -11.3537 0.93134E+00 -0.0309 19 NaHSiO3,aq 0.14382E-04 -4.8422 0.14382E-04 -4.8422 0.10000E+01 0.0000 20 AlO+ 0.41737E-13 -13.3795 0.38871E-13 -13.4104 0.93134E+00 -0.0309 21 AlOH+2 0.20563E-18 -18.6869 0.16317E-18 -18.7874 0.79350E+00 -0.1005 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.26570E-04 -4.5756 0.24735E-04 -4.6067 0.93094E+00 -0.0311 24 CH4,aq 0.19869E-19 -19.7018 0.19862E-19 -19.7020 0.99966E+00 -0.0001 29 CO,aq 0.21589E-18 -18.6658 0.21589E-18 -18.6658 0.10000E+01 0.0000 30 CO2,aq 0.18193E-07 -7.7401 0.18187E-07 -7.7402 0.99966E+00 -0.0001 31 CO3-2 0.14957E-05 -5.8252 0.11878E-05 -5.9253 0.79413E+00 -0.1001 32 CaCO3,aq 0.29419E-09 -9.5314 0.29419E-09 -9.5314 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.58895E-11 -11.2299 0.54852E-11 -11.2608 0.93134E+00 -0.0309 34 CaCl+ 0.44442E-11 -11.3522 0.41391E-11 -11.3831 0.93134E+00 -0.0309 35 CaCl2,aq 0.12379E-15 -15.9073 0.12379E-15 -15.9073 0.10000E+01 0.0000 36 CaOH+ 0.18272E-08 -8.7382 0.17017E-08 -8.7691 0.93134E+00 -0.0309 37 CaSO4,aq 0.12758E-09 -9.8942 0.12758E-09 -9.8942 0.10000E+01 0.0000 38 HCl,aq 0.20245E-13 -13.6937 0.20245E-13 -13.6937 0.10000E+01 0.0000 43 FeCl+ 0.33201E-15 -15.4788 0.30922E-15 -15.5097 0.93134E+00 -0.0309 46 FeO,aq 0.87049E-10 -10.0602 0.87049E-10 -10.0602 0.10000E+01 0.0000 47 FeOH+ 0.65661E-10 -10.1827 0.61153E-10 -10.2136 0.93134E+00 -0.0309 48 HFeO2- 0.12000E-08 -8.9208 0.11174E-08 -8.9518 0.93114E+00 -0.0310 49 FeO+ 0.74427E-14 -14.1283 0.69317E-14 -14.1592 0.93134E+00 -0.0309 51 FeO2- 0.20837E-08 -8.6812 0.19402E-08 -8.7122 0.93114E+00 -0.0310 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.46107E-09 -9.3362 0.46092E-09 -9.3364 0.99966E+00 -0.0001 54 KCl,aq 0.13796E-09 -9.8603 0.13796E-09 -9.8603 0.10000E+01 0.0000 55 KHSO4,aq 0.27540E-17 -17.5600 0.27540E-17 -17.5600 0.10000E+01 0.0000 56 KOH,aq 0.31558E-07 -7.5009 0.31558E-07 -7.5009 0.10000E+01 0.0000 57 KSO4- 0.20321E-07 -7.6921 0.18922E-07 -7.7230 0.93114E+00 -0.0310 58 MgCO3,aq 0.94991E-12 -12.0223 0.94991E-12 -12.0223 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.77606E-13 -13.1101 0.72278E-13 -13.1410 0.93134E+00 -0.0309 60 MgCl+ 0.52134E-13 -13.2829 0.48555E-13 -13.3138 0.93134E+00 -0.0309 61 MgOH+ 0.13080E-09 -9.8834 0.12182E-09 -9.9143 0.93134E+00 -0.0309 63 MnO,aq 0.31051E-09 -9.5079 0.31051E-09 -9.5079 0.10000E+01 0.0000 64 MnOH+ 0.81505E-09 -9.0888 0.75909E-09 -9.1197 0.93134E+00 -0.0309 65 MnO2-2 0.19258E-13 -13.7154 0.15293E-13 -13.8155 0.79413E+00 -0.1001 66 HMnO2- 0.29819E-11 -11.5255 0.27765E-11 -11.5565 0.93114E+00 -0.0310 69 MnCl+ 0.17239E-12 -12.7635 0.16056E-12 -12.7944 0.93134E+00 -0.0309 70 MnSO4,aq 0.11851E-11 -11.9262 0.11851E-11 -11.9262 0.10000E+01 0.0000 71 NaCl,aq 0.62484E-07 -7.2042 0.62484E-07 -7.2042 0.10000E+01 0.0000 72 NaOH,aq 0.78124E-06 -6.1072 0.78124E-06 -6.1072 0.10000E+01 0.0000 74 OH- 0.76893E-03 -3.1141 0.71583E-03 -3.1452 0.93094E+00 -0.0311 79 HPO3-2 0.97316E-17 -17.0118 0.77281E-17 -17.1119 0.79413E+00 -0.1001 81 H2PO3- 0.13661E-19 -19.8645 0.12721E-19 -19.8955 0.93114E+00 -0.0310 82 H3PO4,aq 0.23997E-13 -13.6198 0.23997E-13 -13.6198 0.10000E+01 0.0000 83 H2PO4- 0.83745E-07 -7.0770 0.77986E-07 -7.1080 0.93124E+00 -0.0309 84 PO4-3 0.90450E-08 -8.0436 0.55324E-08 -8.2571 0.61165E+00 -0.2135 87 H2P2O7-2 0.59940E-15 -15.2223 0.47600E-15 -15.3224 0.79413E+00 -0.1001 88 HP2O7-3 0.19151E-12 -12.7178 0.11648E-12 -12.9337 0.60821E+00 -0.2159 89 P2O7-4 0.81611E-13 -13.0882 0.34292E-13 -13.4648 0.42019E+00 -0.3766 90 H2S,aq 0.95888E-16 -16.0182 0.95855E-16 -16.0184 0.99966E+00 -0.0001 97 SO3-2 0.15996E-14 -14.7960 0.12724E-14 -14.8954 0.79546E+00 -0.0994 98 HSO3- 0.67013E-16 -16.1738 0.62399E-16 -16.2048 0.93114E+00 -0.0310 99 HSO4- 0.16901E-10 -10.7721 0.15742E-10 -10.8029 0.93144E+00 -0.0308 Charge balance for all species = 0.4645E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8992993E-09 -.1544603E-02 -.1556615E+01 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9998381E+06 0.0000 3 Cl- 0.1379427E-03 0.1380053E-03 0.4891908E+01 5.1855 4 SO4-- 0.2548976E-04 0.2551040E-04 0.2450172E+01 13.4599 5 HCO3- 0.1155878E-04 0.1307295E-04 0.7975453E+00 4.1088 6 HS- 0.4088765E-13 -.1705885E-09 -.5640787E-05 -4.3426 7 Al+++ 0.3476379E-24 0.2657970E-04 0.7170437E+00 2.5555 8 H4SiO4 0.5220100E-03 0.1189141E-02 0.1142762E+03 -3.2823 9 Ca++ 0.2548064E-07 0.2803561E-07 0.1123429E-02 10.4594 10 Mg++ 0.3294335E-09 0.4660733E-09 0.1132933E-04 8.5707 11 Fe++ 0.1948332E-11 0.3641841E-08 0.2033529E-03 6.3427 12 K+ 0.6513230E-04 0.6518432E-04 0.2548423E+01 4.8597 13 Na+ 0.1600038E-02 0.1615263E-02 0.3712854E+02 6.2499 14 Mn++ 0.2603132E-09 0.1390224E-08 0.7636371E-04 8.4686 15 HPO4-- 0.6682845E-05 0.6775635E-05 0.6502130E+00 12.8785 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1917828E-01 -.1544255E-02 -.1763402E-01 0.0000000E+00 2 H2O 0.5549372E+02 0.5549587E+02 -.2150662E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5762431E-04 0.2550464E-04 0.3211967E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3211984E-04 -.1705500E-09 -.3211967E-04 0.0000000E+00 7 Al+++ 0.3779200E-02 0.2657370E-04 0.3752626E-02 0.0000000E+00 8 H4SiO4 0.1206842E-01 0.1188873E-02 0.1087954E-01 0.0000000E+00 9 Ca++ 0.1347486E-02 0.2802928E-07 0.1347458E-02 0.0000000E+00 10 Mg++ 0.9198413E-03 0.4659681E-09 0.9198408E-03 0.0000000E+00 11 Fe++ 0.8263770E-03 0.3641019E-08 0.8263733E-03 0.0000000E+00 12 K+ 0.2460722E-03 0.6516960E-04 0.1809026E-03 0.0000000E+00 13 Na+ 0.1614898E-02 0.1614898E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2009543E-04 0.1389910E-08 0.2009404E-04 0.0000000E+00 15 HPO4-- 0.6858471E-05 0.6774105E-05 0.8436602E-07 0.0000000E+00 Chg. balance for solid moles: -.1407E-17 Mass of aqueous solution: 0.999937E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.1590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2812E-07 -7.551 0.1413E-04 -4.850 0.1155E-02 0.4489E-05 clinochlore 0.1840E-03 -3.735 0.1023 -0.990 8.360 0.3890E-01 daphnite 0.1139E-03 -3.944 0.8126E-01 -1.090 6.643 0.2462E-01 chlorite-Mn 0.4019E-05 -5.396 0.2849E-02 -2.545 0.2329 0.9080E-03 hematite 0.1285E-03 -3.891 0.2052E-01 -1.688 1.678 0.3889E-02 microcline 0.4423E-04 -4.354 0.1231E-01 -1.910 1.006 0.4809E-02 muscovite 0.1367E-03 -3.864 0.5444E-01 -1.264 4.451 0.1925E-01 stilbite 0.1347E-02 -2.871 0.9495 -0.023 77.63 0.4429 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.223124 g Volume = 0.535234 cm3 Porosity: 63.4303% V(tot) - V(min): 0.92837E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.1590000 g log = 0.0641 Original solution: 1000.0103000 g Original solution / Rock added: 862.82 (Water/Rock Ratio), log = 2.9359 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1965E-05 1.0073 0.2082E-05 0.2067E-05 CH4,gas 0.2948E-16 1.0129 0.3141E-16 0.3101E-16 H2,gas 0.6006E-06 1.0006 0.6322E-06 0.6318E-06 H2S,gas 0.2669E-14 0.9959 0.2796E-14 0.2807E-14 S2,gas 0.6963E-36 1.0000 0.7325E-36 0.7325E-36 CO,gas 0.3241E-15 1.0000 0.3409E-15 0.3409E-15 SO3,gas 0.5053E-38 1.0000 0.5315E-38 0.5315E-38 SO2,gas 0.1208E-21 1.0000 0.1271E-21 0.1271E-21 HCl,gas 0.3398E-16 1.0000 0.3575E-16 0.3575E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.04 -7.68 -2.561 0.13116E+05 -5.682 3 CH4,gas 4.81 -13.69 -18.50 -4.626 0.31593E+05 -16.503 4 H2,gas 8.29 0.09 -8.20 -4.685 0.14000E+05 -6.199 5 H2S,gas -5.94 -22.50 -16.55 -8.277 0.28265E+05 -14.554 6 S2,gas -7.03 -45.17 -38.14 -5.867 0.65115E+05 -36.135 7 CO,gas 3.51 -13.96 -17.47 -5.375 0.29825E+05 -15.467 8 SO3,gas 17.43 -22.85 -40.27 -10.069 0.68768E+05 -38.274 9 SO2,gas 1.14 -22.76 -23.90 -6.372 0.40801E+05 -21.896 10 HCl,gas 5.48 -12.97 -18.45 -9.223 0.31497E+05 -16.447 11 acmite 7.74 5.98 -1.75 -0.182 0.29937E+04 15 albite-high 0.75 -1.04 -1.79 -0.138 0.30584E+04 16 albite -0.33 -1.04 -0.71 -0.055 0.12178E+04 19 spessartine 24.55 20.67 -3.88 -0.194 0.66253E+04 20 analcite 3.37 2.24 -1.13 -0.126 0.19292E+04 21 andalusite 5.06 1.83 -3.23 -0.323 0.55215E+04 22 andradite 39.09 34.13 -4.96 -0.258 0.84672E+04 26 annite 20.21 16.60 -3.61 -0.201 0.61692E+04 27 phlogopite 27.15 23.28 -3.87 -0.215 0.66014E+04 29 anorthite 12.80 9.01 -3.79 -0.292 0.64746E+04 35 aragonite 0.99 -3.59 -4.57 -1.524 0.78059E+04 36 brucite 12.58 8.57 -4.01 -0.801 0.68399E+04 37 calcite 0.83 -3.59 -4.42 -1.473 0.75446E+04 38 carnegieite-low 9.06 5.52 -3.54 -0.506 0.60470E+04 39 carnegieite-high 10.13 5.52 -4.61 -0.659 0.78738E+04 40 carpholite-Mg 8.65 7.12 -1.53 -0.102 0.26181E+04 41 carpholite-Fe 6.78 4.89 -1.89 -0.126 0.32337E+04 42 celadonite 5.40 2.86 -2.54 -0.150 0.43436E+04 43 celadonite-Fe 3.94 0.63 -3.31 -0.195 0.56490E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81784E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.191 0.48865E+04 51 chloritoid-Fe 9.24 8.17 -1.07 -0.071 0.18224E+04 52 chloritoid-Mn 11.46 10.30 -1.17 -0.078 0.19909E+04 54 coesite -2.37 -3.28 -0.91 -0.304 0.15589E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.28 -0.73 -0.244 0.12518E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.47 -3.75 -0.375 0.64030E+04 68 hedenbergite 14.24 10.24 -4.01 -0.401 0.68418E+04 75 epidote 24.78 22.48 -2.29 -0.111 0.39162E+04 76 clinozoisite 22.92 18.74 -4.18 -0.190 0.71421E+04 77 epidote-Fe 29.94 26.22 -3.71 -0.193 0.63378E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79840E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63702E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.24 -2.01 -0.201 0.34323E+04 97 kalsilite 7.62 4.13 -3.49 -0.498 0.59547E+04 98 kaolinite -1.27 -1.45 -0.18 -0.016 0.30822E+03 99 kyanite 4.93 1.83 -3.10 -0.310 0.52982E+04 101 laumontite 2.97 2.44 -0.53 -0.036 0.91083E+03 102 lawsonite 9.68 9.01 -0.67 -0.045 0.11485E+04 103 leucite 4.17 0.85 -3.32 -0.332 0.56639E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70687E+04 107 magnetite 20.13 18.94 -1.19 -0.097 0.20361E+04 108 minnesotaite 10.46 5.90 -4.56 -0.268 0.77894E+04 113 margarite 17.45 14.12 -3.34 -0.133 0.56945E+04 121 paragonite 4.34 4.07 -0.27 -0.016 0.45622E+03 122 nepheline 8.38 5.52 -2.86 -0.408 0.48749E+04 136 prehnite 19.47 16.18 -3.28 -0.193 0.56065E+04 137 prehnite-Fe 22.59 19.93 -2.66 -0.160 0.45429E+04 145 pyroxmangite 7.42 5.19 -2.23 -0.446 0.38073E+04 146 pyrophyllite -6.10 -8.02 -1.92 -0.120 0.32788E+04 147 quartz -2.98 -3.28 -0.30 -0.100 0.51279E+03 151 rhodochrosite -0.96 -5.58 -4.62 -1.539 0.78846E+04 152 rhodonite 7.46 5.19 -2.28 -0.455 0.38866E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.83 -3.49 -0.349 0.59636E+04 164 stilpnomelane-Fe 13.18 13.00 -0.18 -0.005 0.31364E+03 165 stilpnomelane-Mg 27.60 24.14 -3.46 -0.103 0.59085E+04 168 sudoite 21.22 17.52 -3.70 -0.119 0.63171E+04 171 talc 16.55 12.58 -3.97 -0.234 0.67795E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76121E+04 177 topaz-H 4.67 1.83 -2.84 -0.258 0.48473E+04 178 tridymite -2.61 -3.28 -0.67 -0.223 0.11401E+04 187 wairakite 4.06 2.44 -1.62 -0.095 0.27616E+04 188 walstromite 11.53 7.18 -4.35 -0.870 0.74289E+04 189 wollastonite 10.48 7.18 -3.30 -0.661 0.56427E+04 190 pseudo-wollastonite 11.02 7.18 -3.84 -0.769 0.65614E+04 191 zoisite 22.96 18.74 -4.23 -0.192 0.72146E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.37 -2.81 -0.174 0.47918E+04 194 beidellite-H -2.24 -6.09 -3.85 -0.246 0.65750E+04 195 beidellite-K -1.44 -4.49 -3.05 -0.187 0.52131E+04 196 beidellite-Mg -1.71 -4.68 -2.97 -0.184 0.50725E+04 197 beidellite-Na -1.26 -4.03 -2.77 -0.170 0.47337E+04 199 chalcedony -2.79 -3.28 -0.49 -0.163 0.83311E+03 201 montmorillonite-Ca -2.21 -4.31 -2.09 -0.130 0.35745E+04 202 montmorillonite-K -2.16 -4.43 -2.27 -0.139 0.38736E+04 203 montmorillonite-Mg -2.40 -4.62 -2.22 -0.137 0.37863E+04 204 montmorillonite-Na -1.96 -3.97 -2.01 -0.123 0.34323E+04 205 nontronite-Ca 3.28 3.12 -0.16 -0.010 0.27156E+03 206 nontronite-H 2.60 1.39 -1.20 -0.080 0.20505E+04 207 nontronite-K 3.40 3.00 -0.41 -0.026 0.69206E+03 208 nontronite-Mg 3.14 2.81 -0.33 -0.021 0.56392E+03 209 nontronite-Na 3.58 3.46 -0.13 -0.008 0.21434E+03 224 tobermorite 9.84 5.43 -4.41 -1.203 0.75276E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.34 -3.48 -0.870 0.59446E+04 240 silica-amorphous -2.08 -3.28 -1.20 -0.401 0.20533E+04 242 an20ab80 2.08 0.97 -1.11 -0.085 0.18975E+04 243 an25ab75 2.71 1.47 -1.24 -0.095 0.21154E+04 244 an30ab70 3.34 1.97 -1.37 -0.105 0.23416E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.1590000 g New total amount of reactant added: 1.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4568E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.1990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1128875E-02 Osmotic coef. = 0.9807 True ionic strength = .1746503E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.87468E-09 -9.0582 0.81446E-09 -9.0891 0.93115E+00 -0.0310 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12835E-03 -3.8916 0.93048E+00 -0.0313 4 SO4-- 0.25491E-04 -4.5936 0.20192E-04 -4.6948 0.79212E+00 -0.1012 5 HCO3- 0.11518E-04 -4.9386 0.10720E-04 -4.9698 0.93064E+00 -0.0312 6 HS- 0.38971E-13 -13.4093 0.36262E-13 -13.4405 0.93050E+00 -0.0313 7 Al+++ 0.32121E-24 -24.4932 0.19413E-24 -24.7119 0.60437E+00 -0.2187 8 H4SiO4 0.52392E-03 -3.2807 0.52392E-03 -3.2807 0.10000E+01 0.0000 9 Ca++ 0.23529E-07 -7.6284 0.18622E-07 -7.7300 0.79145E+00 -0.1016 10 Mg++ 0.31141E-09 -9.5067 0.24633E-09 -9.6085 0.79102E+00 -0.1018 11 Fe++ 0.18417E-11 -11.7348 0.14570E-11 -11.8365 0.79112E+00 -0.1018 12 K+ 0.62659E-04 -4.2030 0.58315E-04 -4.2342 0.93067E+00 -0.0312 13 Na+ 0.16493E-02 -2.7827 0.15346E-02 -2.8140 0.93047E+00 -0.0313 14 Mn++ 0.24607E-09 -9.6089 0.19469E-09 -9.7107 0.79120E+00 -0.1017 15 HPO4-- 0.74027E-05 -5.1306 0.58639E-05 -5.2318 0.79214E+00 -0.1012 16 HSiO3- 0.67452E-03 -3.1710 0.62763E-03 -3.2023 0.93048E+00 -0.0313 17 Ca(HSiO3)+ 0.28136E-09 -9.5507 0.26186E-09 -9.5819 0.93069E+00 -0.0312 18 Mg(HSiO3)+ 0.46319E-11 -11.3342 0.43108E-11 -11.3654 0.93069E+00 -0.0312 19 NaHSiO3,aq 0.15297E-04 -4.8154 0.15297E-04 -4.8154 0.10000E+01 0.0000 20 AlO+ 0.40594E-13 -13.3915 0.37781E-13 -13.4227 0.93069E+00 -0.0312 21 AlOH+2 0.19480E-18 -18.7104 0.15414E-18 -18.8121 0.79129E+00 -0.1017 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.27356E-04 -4.5629 0.25449E-04 -4.5943 0.93028E+00 -0.0314 24 CH4,aq 0.18897E-19 -19.7236 0.18890E-19 -19.7238 0.99965E+00 -0.0002 29 CO,aq 0.20805E-18 -18.6818 0.20805E-18 -18.6818 0.10000E+01 0.0000 30 CO2,aq 0.17609E-07 -7.7543 0.17603E-07 -7.7544 0.99965E+00 -0.0002 31 CO3-2 0.15367E-05 -5.8134 0.12169E-05 -5.9147 0.79192E+00 -0.1013 32 CaCO3,aq 0.27755E-09 -9.5567 0.27755E-09 -9.5567 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.54044E-11 -11.2673 0.50298E-11 -11.2984 0.93069E+00 -0.0312 34 CaCl+ 0.40924E-11 -11.3880 0.38087E-11 -11.4192 0.93069E+00 -0.0312 35 CaCl2,aq 0.11382E-15 -15.9438 0.11382E-15 -15.9438 0.10000E+01 0.0000 36 CaOH+ 0.17323E-08 -8.7614 0.16122E-08 -8.7926 0.93069E+00 -0.0312 37 CaSO4,aq 0.11716E-09 -9.9312 0.11716E-09 -9.9312 0.10000E+01 0.0000 38 HCl,aq 0.19663E-13 -13.7063 0.19663E-13 -13.7063 0.10000E+01 0.0000 43 FeCl+ 0.31296E-15 -15.5045 0.29127E-15 -15.5357 0.93069E+00 -0.0312 46 FeO,aq 0.86858E-10 -10.0612 0.86858E-10 -10.0612 0.10000E+01 0.0000 47 FeOH+ 0.63724E-10 -10.1957 0.59308E-10 -10.2269 0.93069E+00 -0.0312 48 HFeO2- 0.12328E-08 -8.9091 0.11471E-08 -8.9404 0.93048E+00 -0.0313 49 FeO+ 0.72390E-14 -14.1403 0.67373E-14 -14.1715 0.93069E+00 -0.0312 51 FeO2- 0.21453E-08 -8.6685 0.19962E-08 -8.6998 0.93048E+00 -0.0313 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.45906E-09 -9.3381 0.45890E-09 -9.3383 0.99965E+00 -0.0002 54 KCl,aq 0.13253E-09 -9.8777 0.13253E-09 -9.8777 0.10000E+01 0.0000 55 KHSO4,aq 0.25663E-17 -17.5907 0.25663E-17 -17.5907 0.10000E+01 0.0000 56 KOH,aq 0.31214E-07 -7.5057 0.31214E-07 -7.5057 0.10000E+01 0.0000 57 KSO4- 0.19496E-07 -7.7101 0.18141E-07 -7.7413 0.93048E+00 -0.0313 58 MgCO3,aq 0.91739E-12 -12.0374 0.91739E-12 -12.0374 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.72899E-13 -13.1373 0.67846E-13 -13.1685 0.93069E+00 -0.0312 60 MgCl+ 0.49143E-13 -13.3085 0.45737E-13 -13.3397 0.93069E+00 -0.0312 61 MgOH+ 0.12695E-09 -9.8964 0.11815E-09 -9.9276 0.93069E+00 -0.0312 63 MnO,aq 0.30983E-09 -9.5089 0.30983E-09 -9.5089 0.10000E+01 0.0000 64 MnOH+ 0.79101E-09 -9.1018 0.73619E-09 -9.1330 0.93069E+00 -0.0312 65 MnO2-2 0.20397E-13 -13.6904 0.16153E-13 -13.7917 0.79192E+00 -0.1013 66 HMnO2- 0.30633E-11 -11.5138 0.28504E-11 -11.5451 0.93048E+00 -0.0313 69 MnCl+ 0.16250E-12 -12.7891 0.15124E-12 -12.8203 0.93069E+00 -0.0312 70 MnSO4,aq 0.11141E-11 -11.9531 0.11141E-11 -11.9531 0.10000E+01 0.0000 71 NaCl,aq 0.64317E-07 -7.1917 0.64317E-07 -7.1917 0.10000E+01 0.0000 72 NaOH,aq 0.82795E-06 -6.0820 0.82795E-06 -6.0820 0.10000E+01 0.0000 74 OH- 0.79168E-03 -3.1015 0.73649E-03 -3.1328 0.93028E+00 -0.0314 79 HPO3-2 0.10733E-16 -16.9693 0.84995E-17 -17.0706 0.79192E+00 -0.1013 81 H2PO3- 0.14614E-19 -19.8352 0.13598E-19 -19.8665 0.93048E+00 -0.0313 82 H3PO4,aq 0.25042E-13 -13.6013 0.25042E-13 -13.6013 0.10000E+01 0.0000 83 H2PO4- 0.89977E-07 -7.0459 0.83732E-07 -7.0771 0.93059E+00 -0.0312 84 PO4-3 0.10343E-07 -7.9854 0.62877E-08 -8.2015 0.60792E+00 -0.2162 87 H2P2O7-2 0.69289E-15 -15.1593 0.54871E-15 -15.2607 0.79192E+00 -0.1013 88 HP2O7-3 0.22857E-12 -12.6410 0.13815E-12 -12.8597 0.60441E+00 -0.2187 89 P2O7-4 0.10069E-12 -12.9970 0.41845E-13 -13.3784 0.41556E+00 -0.3814 90 H2S,aq 0.88768E-16 -16.0517 0.88737E-16 -16.0519 0.99965E+00 -0.0002 97 SO3-2 0.15926E-14 -14.7979 0.12634E-14 -14.8985 0.79329E+00 -0.1006 98 HSO3- 0.64718E-16 -16.1890 0.60219E-16 -16.2203 0.93048E+00 -0.0313 99 HSO4- 0.16393E-10 -10.7853 0.15259E-10 -10.8165 0.93080E+00 -0.0311 Charge balance for all species = 0.4643E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8746769E-09 -.1593260E-02 -.1605644E+01 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9998346E+06 0.0000 3 Cl- 0.1379419E-03 0.1380063E-03 0.4891926E+01 5.1975 4 SO4-- 0.2549078E-04 0.2551059E-04 0.2450182E+01 13.4834 5 HCO3- 0.1151849E-04 0.1307305E-04 0.7975482E+00 4.1193 6 HS- 0.3897078E-13 -.1787974E-09 -.5912207E-05 -4.3514 7 Al+++ 0.3212108E-24 0.2736572E-04 0.7382455E+00 2.5555 8 H4SiO4 0.5239212E-03 0.1213735E-02 0.1166393E+03 -3.2807 9 Ca++ 0.2352909E-07 0.2594695E-07 0.1039729E-02 10.4483 10 Mg++ 0.3114057E-09 0.4440235E-09 0.1079331E-04 8.5698 11 Fe++ 0.1841706E-11 0.3734021E-08 0.2084993E-03 6.3417 12 K+ 0.6265907E-04 0.6270992E-04 0.2451676E+01 4.8549 13 Na+ 0.1649306E-02 0.1665496E-02 0.3828307E+02 6.2751 14 Mn++ 0.2460676E-09 0.1351262E-08 0.7422332E-04 8.4676 15 HPO4-- 0.7402675E-05 0.7502996E-05 0.7200106E+00 12.9465 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1984062E-01 -.1592889E-02 -.1824773E-01 0.0000000E+00 2 H2O 0.5549322E+02 0.5549548E+02 -.2255410E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5873285E-04 0.2550465E-04 0.3322820E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3322838E-04 -.1787558E-09 -.3322820E-04 0.0000000E+00 7 Al+++ 0.3909629E-02 0.2735934E-04 0.3882270E-02 0.0000000E+00 8 H4SiO4 0.1248493E-01 0.1213452E-02 0.1127147E-01 0.0000000E+00 9 Ca++ 0.1393492E-02 0.2594090E-07 0.1393466E-02 0.0000000E+00 10 Mg++ 0.9515873E-03 0.4439200E-09 0.9515869E-03 0.0000000E+00 11 Fe++ 0.8548973E-03 0.3733151E-08 0.8548936E-03 0.0000000E+00 12 K+ 0.2545648E-03 0.6269531E-04 0.1918695E-03 0.0000000E+00 13 Na+ 0.1665108E-02 0.1665108E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2078898E-04 0.1350947E-08 0.2078763E-04 0.0000000E+00 15 HPO4-- 0.7095174E-05 0.7501248E-05 -.4060740E-06 0.0000000E+00 Chg. balance for solid moles: -.5905E-17 Mass of aqueous solution: 0.999933E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH -.1354E-06 1.000 -.6799E-04 1.000 -.5369E-02 -.2161E-04 clinochlore 0.1903E-03 -3.721 0.1058 -0.976 8.353 0.4024E-01 daphnite 0.1178E-03 -3.929 0.8406E-01 -1.075 6.637 0.2547E-01 chlorite-Mn 0.4158E-05 -5.381 0.2948E-02 -2.531 0.2327 0.9393E-03 hematite 0.1329E-03 -3.876 0.2123E-01 -1.673 1.676 0.4023E-02 microcline 0.5310E-04 -4.275 0.1478E-01 -1.830 1.167 0.5773E-02 muscovite 0.1388E-03 -3.858 0.5527E-01 -1.257 4.364 0.1954E-01 stilbite 0.1394E-02 -2.856 0.9825 -0.008 77.58 0.4582 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.266484 g Volume = 0.554216 cm3 Porosity: 62.5428% V(tot) - V(min): 0.92538E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.1990000 g log = 0.0788 Original solution: 1000.0103000 g Original solution / Rock added: 834.04 (Water/Rock Ratio), log = 2.9212 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1902E-05 1.0073 0.2015E-05 0.2000E-05 CH4,gas 0.2804E-16 1.0129 0.2987E-16 0.2949E-16 H2,gas 0.5980E-06 1.0006 0.6294E-06 0.6291E-06 H2S,gas 0.2470E-14 0.9959 0.2588E-14 0.2599E-14 S2,gas 0.6020E-36 1.0000 0.6333E-36 0.6333E-36 CO,gas 0.3123E-15 1.0000 0.3285E-15 0.3285E-15 SO3,gas 0.4760E-38 1.0000 0.5007E-38 0.5007E-38 SO2,gas 0.1133E-21 1.0000 0.1192E-21 0.1192E-21 HCl,gas 0.3301E-16 1.0000 0.3472E-16 0.3472E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.06 -7.70 -2.565 0.13140E+05 -5.696 3 CH4,gas 4.81 -13.72 -18.52 -4.631 0.31630E+05 -16.525 4 H2,gas 8.29 0.09 -8.20 -4.686 0.14003E+05 -6.201 5 H2S,gas -5.94 -22.53 -16.59 -8.294 0.28322E+05 -14.587 6 S2,gas -7.03 -45.23 -38.20 -5.877 0.65223E+05 -36.198 7 CO,gas 3.51 -13.97 -17.48 -5.380 0.29853E+05 -15.483 8 SO3,gas 17.43 -22.87 -40.30 -10.075 0.68812E+05 -38.300 9 SO2,gas 1.14 -22.79 -23.92 -6.380 0.40849E+05 -21.924 10 HCl,gas 5.48 -12.98 -18.46 -9.230 0.31519E+05 -16.459 11 acmite 7.74 6.01 -1.72 -0.179 0.29452E+04 15 albite-high 0.75 -1.01 -1.76 -0.135 0.30072E+04 16 albite -0.33 -1.01 -0.68 -0.053 0.11666E+04 19 spessartine 24.55 20.67 -3.88 -0.194 0.66221E+04 20 analcite 3.37 2.27 -1.10 -0.122 0.18807E+04 21 andalusite 5.06 1.83 -3.23 -0.323 0.55188E+04 22 andradite 39.09 34.10 -4.99 -0.259 0.85159E+04 26 annite 20.21 16.59 -3.62 -0.201 0.61741E+04 27 phlogopite 27.15 23.28 -3.87 -0.215 0.66063E+04 29 anorthite 12.80 9.00 -3.80 -0.292 0.64882E+04 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 35 aragonite 0.99 -3.61 -4.60 -1.532 0.78491E+04 36 brucite 12.58 8.57 -4.01 -0.801 0.68415E+04 37 calcite 0.83 -3.61 -4.44 -1.481 0.75877E+04 38 carnegieite-low 9.06 5.55 -3.51 -0.502 0.60012E+04 39 carnegieite-high 10.13 5.55 -4.58 -0.655 0.78280E+04 40 carpholite-Mg 8.65 7.12 -1.53 -0.102 0.26143E+04 41 carpholite-Fe 6.78 4.89 -1.89 -0.126 0.32299E+04 42 celadonite 5.40 2.86 -2.54 -0.150 0.43425E+04 43 celadonite-Fe 3.94 0.63 -3.31 -0.195 0.56479E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81779E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.191 0.48854E+04 51 chloritoid-Fe 9.24 8.17 -1.07 -0.071 0.18213E+04 52 chloritoid-Mn 11.46 10.30 -1.17 -0.078 0.19898E+04 54 coesite -2.37 -3.28 -0.91 -0.304 0.15562E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.28 -0.73 -0.244 0.12491E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.46 -3.76 -0.376 0.64182E+04 68 hedenbergite 14.24 10.23 -4.02 -0.402 0.68570E+04 75 epidote 24.78 22.46 -2.31 -0.112 0.39460E+04 76 clinozoisite 22.92 18.72 -4.20 -0.191 0.71719E+04 77 epidote-Fe 29.94 26.21 -3.73 -0.194 0.63676E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79845E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63697E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.27 -1.98 -0.198 0.33838E+04 97 kalsilite 7.62 4.13 -3.49 -0.499 0.59601E+04 98 kaolinite -1.27 -1.45 -0.18 -0.016 0.30280E+03 99 kyanite 4.93 1.83 -3.10 -0.310 0.52955E+04 101 laumontite 2.97 2.44 -0.54 -0.036 0.91896E+03 102 lawsonite 9.68 9.00 -0.68 -0.045 0.11620E+04 103 leucite 4.17 0.85 -3.32 -0.332 0.56666E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70682E+04 107 magnetite 20.13 18.94 -1.19 -0.097 0.20378E+04 108 minnesotaite 10.46 5.90 -4.56 -0.268 0.77835E+04 113 margarite 17.45 14.11 -3.34 -0.134 0.57081E+04 121 paragonite 4.34 4.10 -0.24 -0.014 0.40503E+03 122 nepheline 8.38 5.55 -2.83 -0.404 0.48291E+04 136 prehnite 19.47 16.17 -3.30 -0.194 0.56363E+04 137 prehnite-Fe 22.59 19.91 -2.68 -0.161 0.45727E+04 145 pyroxmangite 7.42 5.19 -2.23 -0.446 0.38062E+04 146 pyrophyllite -6.10 -8.01 -1.91 -0.120 0.32680E+04 147 quartz -2.98 -3.28 -0.30 -0.100 0.51008E+03 151 rhodochrosite -0.96 -5.59 -4.63 -1.544 0.79104E+04 152 rhodonite 7.46 5.19 -2.28 -0.455 0.38855E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.83 -3.49 -0.349 0.59609E+04 164 stilpnomelane-Fe 13.18 13.00 -0.18 -0.005 0.30416E+03 165 stilpnomelane-Mg 27.60 24.14 -3.45 -0.103 0.58990E+04 168 sudoite 21.22 17.52 -3.70 -0.119 0.63123E+04 171 talc 16.55 12.59 -3.97 -0.233 0.67735E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76126E+04 177 topaz-H 4.67 1.83 -2.84 -0.258 0.48446E+04 178 tridymite -2.61 -3.28 -0.67 -0.222 0.11374E+04 187 wairakite 4.06 2.44 -1.62 -0.095 0.27698E+04 188 walstromite 11.53 7.17 -4.36 -0.872 0.74451E+04 189 wollastonite 10.48 7.17 -3.31 -0.663 0.56590E+04 190 pseudo-wollastonite 11.02 7.17 -3.85 -0.770 0.65776E+04 191 zoisite 22.96 18.72 -4.24 -0.193 0.72444E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.36 -2.80 -0.173 0.47849E+04 194 beidellite-H -2.24 -6.09 -3.84 -0.245 0.65650E+04 195 beidellite-K -1.44 -4.48 -3.05 -0.187 0.52058E+04 196 beidellite-Mg -1.71 -4.67 -2.97 -0.183 0.50628E+04 197 beidellite-Na -1.26 -4.02 -2.76 -0.169 0.47095E+04 199 chalcedony -2.79 -3.28 -0.49 -0.162 0.83040E+03 201 montmorillonite-Ca -2.21 -4.30 -2.09 -0.129 0.35673E+04 202 montmorillonite-K -2.16 -4.43 -2.26 -0.139 0.38660E+04 203 montmorillonite-Mg -2.40 -4.61 -2.21 -0.137 0.37762E+04 204 montmorillonite-Na -1.96 -3.96 -2.00 -0.122 0.34078E+04 205 nontronite-Ca 3.28 3.12 -0.16 -0.010 0.26474E+03 206 nontronite-H 2.60 1.40 -1.20 -0.080 0.20406E+04 207 nontronite-K 3.40 3.00 -0.40 -0.026 0.68480E+03 208 nontronite-Mg 3.14 2.81 -0.32 -0.021 0.55424E+03 209 nontronite-Na 3.58 3.47 -0.11 -0.007 0.19019E+03 224 tobermorite 9.84 5.42 -4.42 -1.205 0.75407E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.34 -3.48 -0.871 0.59463E+04 240 silica-amorphous -2.08 -3.28 -1.20 -0.400 0.20506E+04 242 an20ab80 2.08 0.99 -1.09 -0.084 0.18593E+04 243 an25ab75 2.71 1.49 -1.22 -0.094 0.20804E+04 244 an30ab70 3.34 1.99 -1.35 -0.104 0.23098E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.1990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1127626E-02 Osmotic coef. = 0.9807 True ionic strength = .1745527E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.87583E-09 -9.0576 0.81554E-09 -9.0886 0.93116E+00 -0.0310 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12835E-03 -3.8916 0.93050E+00 -0.0313 4 SO4-- 0.25491E-04 -4.5936 0.20193E-04 -4.6948 0.79217E+00 -0.1012 5 HCO3- 0.11520E-04 -4.9385 0.10721E-04 -4.9697 0.93065E+00 -0.0312 6 HS- 0.38407E-13 -13.4156 0.35738E-13 -13.4469 0.93051E+00 -0.0313 7 Al+++ 0.32245E-24 -24.4915 0.19491E-24 -24.7102 0.60445E+00 -0.2186 8 H4SiO4 0.52567E-03 -3.2793 0.52567E-03 -3.2793 0.10000E+01 0.0000 9 Ca++ 0.23048E-07 -7.6374 0.18242E-07 -7.7389 0.79149E+00 -0.1016 10 Mg++ 0.31159E-09 -9.5064 0.24649E-09 -9.6082 0.79106E+00 -0.1018 11 Fe++ 0.18428E-11 -11.7345 0.14580E-11 -11.8363 0.79116E+00 -0.1017 12 K+ 0.62119E-04 -4.2068 0.57813E-04 -4.2380 0.93068E+00 -0.0312 13 Na+ 0.16493E-02 -2.7827 0.15346E-02 -2.8140 0.93048E+00 -0.0313 14 Mn++ 0.24622E-09 -9.6087 0.19482E-09 -9.7104 0.79124E+00 -0.1017 15 HPO4-- 0.70018E-05 -5.1548 0.55467E-05 -5.2560 0.79218E+00 -0.1012 16 HSiO3- 0.67585E-03 -3.1701 0.62888E-03 -3.2014 0.93050E+00 -0.0313 17 Ca(HSiO3)+ 0.27617E-09 -9.5588 0.25703E-09 -9.5900 0.93071E+00 -0.0312 18 Mg(HSiO3)+ 0.46441E-11 -11.3331 0.43223E-11 -11.3643 0.93071E+00 -0.0312 19 NaHSiO3,aq 0.15328E-04 -4.8145 0.15328E-04 -4.8145 0.10000E+01 0.0000 20 AlO+ 0.40648E-13 -13.3910 0.37831E-13 -13.4221 0.93071E+00 -0.0312 21 AlOH+2 0.19531E-18 -18.7093 0.15455E-18 -18.8109 0.79133E+00 -0.1016 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.27320E-04 -4.5635 0.25415E-04 -4.5949 0.93030E+00 -0.0314 24 CH4,aq 0.18626E-19 -19.7299 0.18619E-19 -19.7300 0.99965E+00 -0.0002 29 CO,aq 0.20753E-18 -18.6829 0.20753E-18 -18.6829 0.10000E+01 0.0000 30 CO2,aq 0.17635E-07 -7.7536 0.17629E-07 -7.7538 0.99965E+00 -0.0002 31 CO3-2 0.15348E-05 -5.8139 0.12155E-05 -5.9152 0.79197E+00 -0.1013 32 CaCO3,aq 0.27157E-09 -9.5661 0.27157E-09 -9.5661 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.52950E-11 -11.2761 0.49281E-11 -11.3073 0.93071E+00 -0.0312 34 CaCl+ 0.40089E-11 -11.3970 0.37311E-11 -11.4282 0.93071E+00 -0.0312 35 CaCl2,aq 0.11151E-15 -15.9527 0.11151E-15 -15.9527 0.10000E+01 0.0000 36 CaOH+ 0.16947E-08 -8.7709 0.15772E-08 -8.8021 0.93071E+00 -0.0312 37 CaSO4,aq 0.11477E-09 -9.9402 0.11477E-09 -9.9402 0.10000E+01 0.0000 38 HCl,aq 0.19690E-13 -13.7058 0.19690E-13 -13.7058 0.10000E+01 0.0000 43 FeCl+ 0.31317E-15 -15.5042 0.29147E-15 -15.5354 0.93071E+00 -0.0312 46 FeO,aq 0.86685E-10 -10.0621 0.86685E-10 -10.0621 0.10000E+01 0.0000 47 FeOH+ 0.63681E-10 -10.1960 0.59268E-10 -10.2272 0.93071E+00 -0.0312 48 HFeO2- 0.12287E-08 -8.9106 0.11433E-08 -8.9418 0.93050E+00 -0.0313 49 FeO+ 0.72485E-14 -14.1398 0.67462E-14 -14.1709 0.93071E+00 -0.0312 51 FeO2- 0.21425E-08 -8.6691 0.19935E-08 -8.7004 0.93050E+00 -0.0313 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.45723E-09 -9.3399 0.45707E-09 -9.3400 0.99965E+00 -0.0002 54 KCl,aq 0.13139E-09 -9.8814 0.13139E-09 -9.8814 0.10000E+01 0.0000 55 KHSO4,aq 0.25477E-17 -17.5938 0.25477E-17 -17.5938 0.10000E+01 0.0000 56 KOH,aq 0.30904E-07 -7.5100 0.30904E-07 -7.5100 0.10000E+01 0.0000 57 KSO4- 0.19329E-07 -7.7138 0.17986E-07 -7.7451 0.93050E+00 -0.0313 58 MgCO3,aq 0.91694E-12 -12.0377 0.91694E-12 -12.0377 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.72958E-13 -13.1369 0.67903E-13 -13.1681 0.93071E+00 -0.0312 60 MgCl+ 0.49175E-13 -13.3083 0.45768E-13 -13.3394 0.93071E+00 -0.0312 61 MgOH+ 0.12686E-09 -9.8967 0.11807E-09 -9.9279 0.93071E+00 -0.0312 63 MnO,aq 0.30921E-09 -9.5097 0.30921E-09 -9.5097 0.10000E+01 0.0000 64 MnOH+ 0.79047E-09 -9.1021 0.73570E-09 -9.1333 0.93071E+00 -0.0312 65 MnO2-2 0.20301E-13 -13.6925 0.16078E-13 -13.7938 0.79197E+00 -0.1013 66 HMnO2- 0.30531E-11 -11.5153 0.28409E-11 -11.5465 0.93050E+00 -0.0313 69 MnCl+ 0.16261E-12 -12.7889 0.15134E-12 -12.8200 0.93071E+00 -0.0312 70 MnSO4,aq 0.11149E-11 -11.9528 0.11149E-11 -11.9528 0.10000E+01 0.0000 71 NaCl,aq 0.64317E-07 -7.1917 0.64317E-07 -7.1917 0.10000E+01 0.0000 72 NaOH,aq 0.82685E-06 -6.0826 0.82685E-06 -6.0826 0.10000E+01 0.0000 74 OH- 0.79062E-03 -3.1020 0.73551E-03 -3.1334 0.93030E+00 -0.0314 79 HPO3-2 0.10111E-16 -16.9952 0.80077E-17 -17.0965 0.79197E+00 -0.1013 81 H2PO3- 0.13786E-19 -19.8605 0.12828E-19 -19.8918 0.93050E+00 -0.0313 82 H3PO4,aq 0.23751E-13 -13.6243 0.23751E-13 -13.6243 0.10000E+01 0.0000 83 H2PO4- 0.85222E-07 -7.0694 0.79307E-07 -7.1007 0.93060E+00 -0.0312 84 PO4-3 0.97693E-08 -8.0101 0.59397E-08 -8.2262 0.60799E+00 -0.2161 87 H2P2O7-2 0.62157E-15 -15.2065 0.49226E-15 -15.3078 0.79197E+00 -0.1013 88 HP2O7-3 0.20475E-12 -12.6888 0.12377E-12 -12.9074 0.60449E+00 -0.2186 89 P2O7-4 0.90075E-13 -13.0454 0.37440E-13 -13.4267 0.41566E+00 -0.3813 90 H2S,aq 0.87601E-16 -16.0575 0.87570E-16 -16.0576 0.99965E+00 -0.0002 97 SO3-2 0.15863E-14 -14.7996 0.12585E-14 -14.9002 0.79334E+00 -0.1005 98 HSO3- 0.64549E-16 -16.1901 0.60062E-16 -16.2214 0.93050E+00 -0.0313 99 HSO4- 0.16416E-10 -10.7847 0.15280E-10 -10.8159 0.93081E+00 -0.0311 Charge balance for all species = 0.4569E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8758272E-09 -.1593420E-02 -.1605805E+01 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9998344E+06 0.0000 3 Cl- 0.1379419E-03 0.1380063E-03 0.4891925E+01 5.1970 4 SO4-- 0.2549095E-04 0.2551059E-04 0.2450181E+01 13.4823 5 HCO3- 0.1152033E-04 0.1307305E-04 0.7975481E+00 4.1188 6 HS- 0.3840677E-13 -.1788952E-09 -.5915439E-05 -4.3583 7 Al+++ 0.3224520E-24 0.2732902E-04 0.7372553E+00 2.5555 8 H4SiO4 0.5256657E-03 0.1216848E-02 0.1169384E+03 -3.2793 9 Ca++ 0.2304777E-07 0.2541426E-07 0.1018383E-02 10.4382 10 Mg++ 0.3115941E-09 0.4441374E-09 0.1079607E-04 8.5689 11 Fe++ 0.1842820E-11 0.3726822E-08 0.2080972E-03 6.3409 12 K+ 0.6211890E-04 0.6216927E-04 0.2430539E+01 4.8506 13 Na+ 0.1649277E-02 0.1665496E-02 0.3828306E+02 6.2746 14 Mn++ 0.2462164E-09 0.1350246E-08 0.7416751E-04 8.4667 15 HPO4-- 0.7001836E-05 0.7096828E-05 0.6810332E+00 12.9211 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1984062E-01 -.1593049E-02 -.1824757E-01 0.0000000E+00 2 H2O 0.5549322E+02 0.5549547E+02 -.2253711E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5873285E-04 0.2550465E-04 0.3322820E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3322838E-04 -.1788535E-09 -.3322820E-04 0.0000000E+00 7 Al+++ 0.3909629E-02 0.2732265E-04 0.3882307E-02 0.0000000E+00 8 H4SiO4 0.1248493E-01 0.1216565E-02 0.1126836E-01 0.0000000E+00 9 Ca++ 0.1393492E-02 0.2540834E-07 0.1393467E-02 0.0000000E+00 10 Mg++ 0.9515873E-03 0.4440339E-09 0.9515869E-03 0.0000000E+00 11 Fe++ 0.8548973E-03 0.3725954E-08 0.8548936E-03 0.0000000E+00 12 K+ 0.2545648E-03 0.6215479E-04 0.1924100E-03 0.0000000E+00 13 Na+ 0.1665108E-02 0.1665108E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2078898E-04 0.1349932E-08 0.2078763E-04 0.0000000E+00 15 HPO4-- 0.7095174E-05 0.7095174E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.5109E-17 Mass of aqueous solution: 0.999933E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.1903E-03 -3.721 0.1058 -0.976 8.354 0.4024E-01 daphnite 0.1178E-03 -3.929 0.8406E-01 -1.075 6.638 0.2547E-01 chlorite-Mn 0.4158E-05 -5.381 0.2948E-02 -2.531 0.2328 0.9393E-03 hematite 0.1329E-03 -3.876 0.2123E-01 -1.673 1.676 0.4023E-02 microcline 0.5322E-04 -4.274 0.1481E-01 -1.829 1.170 0.5786E-02 muscovite 0.1392E-03 -3.856 0.5544E-01 -1.256 4.378 0.1960E-01 stilbite 0.1393E-02 -2.856 0.9820 -0.008 77.55 0.4580 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.266277 g Volume = 0.554088 cm3 Porosity: 62.5515% V(tot) - V(min): 0.92551E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.1990000 g log = 0.0788 Original solution: 1000.0103000 g Original solution / Rock added: 834.04 (Water/Rock Ratio), log = 2.9212 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1904E-05 1.0073 0.2018E-05 0.2003E-05 CH4,gas 0.2763E-16 1.0129 0.2944E-16 0.2907E-16 H2,gas 0.5956E-06 1.0006 0.6269E-06 0.6266E-06 H2S,gas 0.2438E-14 0.9959 0.2554E-14 0.2565E-14 S2,gas 0.5910E-36 1.0000 0.6217E-36 0.6217E-36 CO,gas 0.3115E-15 1.0000 0.3277E-15 0.3277E-15 SO3,gas 0.4773E-38 1.0000 0.5021E-38 0.5021E-38 SO2,gas 0.1132E-21 1.0000 0.1191E-21 0.1191E-21 HCl,gas 0.3305E-16 1.0000 0.3477E-16 0.3477E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 120 muscovite 2.68 2.68 0.00 0.000 0.30331E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.06 -7.70 -2.565 0.13139E+05 -5.695 3 CH4,gas 4.81 -13.72 -18.53 -4.633 0.31641E+05 -16.531 4 H2,gas 8.29 0.08 -8.20 -4.687 0.14006E+05 -6.203 5 H2S,gas -5.94 -22.54 -16.59 -8.296 0.28332E+05 -14.593 6 S2,gas -7.03 -45.24 -38.21 -5.878 0.65236E+05 -36.206 7 CO,gas 3.51 -13.97 -17.48 -5.380 0.29854E+05 -15.485 8 SO3,gas 17.43 -22.87 -40.30 -10.075 0.68810E+05 -38.299 9 SO2,gas 1.14 -22.79 -23.92 -6.380 0.40850E+05 -21.924 10 HCl,gas 5.48 -12.98 -18.46 -9.229 0.31518E+05 -16.459 11 acmite 7.74 6.01 -1.72 -0.179 0.29413E+04 15 albite-high 0.75 -1.01 -1.76 -0.135 0.30008E+04 16 albite -0.33 -1.01 -0.68 -0.052 0.11602E+04 19 spessartine 24.55 20.67 -3.88 -0.194 0.66191E+04 20 analcite 3.37 2.27 -1.10 -0.122 0.18768E+04 21 andalusite 5.06 1.83 -3.23 -0.323 0.55163E+04 26 annite 20.21 16.59 -3.62 -0.201 0.61785E+04 27 phlogopite 27.15 23.27 -3.87 -0.215 0.66107E+04 29 anorthite 12.80 8.99 -3.81 -0.293 0.65005E+04 32 apatite-OH -17.99 -18.11 -0.12 -0.009 0.20408E+03 35 aragonite 0.99 -3.62 -4.61 -1.535 0.78652E+04 36 brucite 12.58 8.57 -4.01 -0.802 0.68430E+04 37 calcite 0.83 -3.62 -4.45 -1.484 0.76039E+04 38 carnegieite-low 9.06 5.55 -3.51 -0.502 0.59997E+04 39 carnegieite-high 10.13 5.55 -4.58 -0.655 0.78266E+04 40 carpholite-Mg 8.65 7.12 -1.53 -0.102 0.26108E+04 41 carpholite-Fe 6.78 4.89 -1.89 -0.126 0.32265E+04 42 celadonite 5.40 2.86 -2.54 -0.150 0.43416E+04 43 celadonite-Fe 3.94 0.63 -3.31 -0.195 0.56469E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81774E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.191 0.48844E+04 51 chloritoid-Fe 9.24 8.17 -1.07 -0.071 0.18204E+04 52 chloritoid-Mn 11.46 10.30 -1.16 -0.078 0.19888E+04 54 coesite -2.37 -3.28 -0.91 -0.303 0.15537E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.28 -0.73 -0.243 0.12466E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.45 -3.77 -0.377 0.64320E+04 68 hedenbergite 14.24 10.22 -4.02 -0.402 0.68708E+04 75 epidote 24.78 22.45 -2.33 -0.113 0.39731E+04 76 clinozoisite 22.92 18.70 -4.22 -0.192 0.71990E+04 77 epidote-Fe 29.94 26.19 -3.75 -0.195 0.63948E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79850E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63692E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.27 -1.98 -0.198 0.33798E+04 97 kalsilite 7.62 4.13 -3.49 -0.499 0.59650E+04 98 kaolinite -1.27 -1.45 -0.17 -0.016 0.29787E+03 99 kyanite 4.93 1.83 -3.10 -0.310 0.52931E+04 101 laumontite 2.97 2.43 -0.54 -0.036 0.92635E+03 102 lawsonite 9.68 8.99 -0.69 -0.046 0.11744E+04 103 leucite 4.17 0.85 -3.32 -0.332 0.56691E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70677E+04 107 magnetite 20.13 18.94 -1.19 -0.097 0.20392E+04 108 minnesotaite 10.46 5.91 -4.56 -0.268 0.77780E+04 113 margarite 17.45 14.10 -3.35 -0.134 0.57204E+04 121 paragonite 4.34 4.10 -0.23 -0.014 0.39862E+03 122 nepheline 8.38 5.55 -2.83 -0.404 0.48276E+04 136 prehnite 19.47 16.15 -3.32 -0.195 0.56634E+04 137 prehnite-Fe 22.59 19.89 -2.69 -0.162 0.45999E+04 145 pyroxmangite 7.42 5.19 -2.23 -0.446 0.38052E+04 146 pyrophyllite -6.10 -8.01 -1.91 -0.119 0.32581E+04 147 quartz -2.98 -3.28 -0.30 -0.099 0.50762E+03 151 rhodochrosite -0.96 -5.59 -4.63 -1.544 0.79108E+04 152 rhodonite 7.46 5.19 -2.27 -0.455 0.38845E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.83 -3.49 -0.349 0.59585E+04 164 stilpnomelane-Fe 13.18 13.01 -0.17 -0.005 0.29553E+03 165 stilpnomelane-Mg 27.60 24.15 -3.45 -0.103 0.58903E+04 168 sudoite 21.22 17.52 -3.69 -0.119 0.63078E+04 171 talc 16.55 12.59 -3.96 -0.233 0.67681E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76131E+04 177 topaz-H 4.67 1.83 -2.84 -0.258 0.48422E+04 178 tridymite -2.61 -3.28 -0.66 -0.222 0.11349E+04 187 wairakite 4.06 2.43 -1.63 -0.096 0.27772E+04 188 walstromite 11.53 7.16 -4.37 -0.874 0.74599E+04 189 wollastonite 10.48 7.16 -3.32 -0.665 0.56738E+04 190 pseudo-wollastonite 11.02 7.16 -3.86 -0.772 0.65924E+04 191 zoisite 22.96 18.70 -4.26 -0.194 0.72715E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.36 -2.80 -0.173 0.47787E+04 194 beidellite-H -2.24 -6.08 -3.84 -0.245 0.65560E+04 195 beidellite-K -1.44 -4.48 -3.04 -0.186 0.51992E+04 196 beidellite-Mg -1.71 -4.67 -2.96 -0.183 0.50540E+04 197 beidellite-Na -1.26 -4.01 -2.75 -0.169 0.47008E+04 199 chalcedony -2.79 -3.28 -0.48 -0.162 0.82793E+03 201 montmorillonite-Ca -2.21 -4.30 -2.09 -0.129 0.35608E+04 202 montmorillonite-K -2.16 -4.42 -2.26 -0.138 0.38590E+04 203 montmorillonite-Mg -2.40 -4.61 -2.21 -0.136 0.37671E+04 204 montmorillonite-Na -1.96 -3.95 -1.99 -0.122 0.33988E+04 205 nontronite-Ca 3.28 3.13 -0.15 -0.010 0.25854E+03 206 nontronite-H 2.60 1.41 -1.19 -0.080 0.20316E+04 207 nontronite-K 3.40 3.01 -0.40 -0.025 0.67819E+03 208 nontronite-Mg 3.14 2.82 -0.32 -0.021 0.54544E+03 209 nontronite-Na 3.58 3.48 -0.11 -0.007 0.18147E+03 224 tobermorite 9.84 5.42 -4.42 -1.207 0.75526E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.34 -3.48 -0.871 0.59477E+04 240 silica-amorphous -2.08 -3.28 -1.20 -0.400 0.20481E+04 242 an20ab80 2.08 0.99 -1.09 -0.084 0.18566E+04 243 an25ab75 2.71 1.49 -1.22 -0.094 0.20786E+04 244 an30ab70 3.34 1.99 -1.35 -0.104 0.23090E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.1990000 g New total amount of reactant added: 1.2390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4568E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.2390000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9998E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1155041E-02 Osmotic coef. = 0.9805 True ionic strength = .1792031E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.85401E-09 -9.0685 0.79470E-09 -9.0998 0.93055E+00 -0.0313 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12827E-03 -3.8919 0.92987E+00 -0.0316 4 SO4-- 0.25492E-04 -4.5936 0.20140E-04 -4.6959 0.79006E+00 -0.1023 5 HCO3- 0.11483E-04 -4.9400 0.10679E-04 -4.9715 0.93003E+00 -0.0315 6 HS- 0.35965E-13 -13.4441 0.33443E-13 -13.4757 0.92988E+00 -0.0316 7 Al+++ 0.30017E-24 -24.5226 0.18034E-24 -24.7439 0.60081E+00 -0.2213 8 H4SiO4 0.52983E-03 -3.2759 0.52983E-03 -3.2759 0.10000E+01 0.0000 9 Ca++ 0.20765E-07 -7.6827 0.16391E-07 -7.7854 0.78936E+00 -0.1027 10 Mg++ 0.29527E-09 -9.5298 0.23295E-09 -9.6327 0.78893E+00 -0.1030 11 Fe++ 0.17463E-11 -11.7579 0.13779E-11 -11.8608 0.78903E+00 -0.1029 12 K+ 0.59155E-04 -4.2280 0.55018E-04 -4.2595 0.93006E+00 -0.0315 13 Na+ 0.16985E-02 -2.7699 0.15793E-02 -2.8015 0.92985E+00 -0.0316 14 Mn++ 0.23332E-09 -9.6321 0.18411E-09 -9.7349 0.78911E+00 -0.1029 15 HPO4-- 0.72376E-05 -5.1404 0.57182E-05 -5.2427 0.79007E+00 -0.1023 16 HSiO3- 0.69955E-03 -3.1552 0.65048E-03 -3.1868 0.92987E+00 -0.0316 17 Ca(HSiO3)+ 0.25685E-09 -9.5903 0.23889E-09 -9.6218 0.93008E+00 -0.0315 18 Mg(HSiO3)+ 0.45428E-11 -11.3427 0.42252E-11 -11.3742 0.93008E+00 -0.0315 19 NaHSiO3,aq 0.16316E-04 -4.7874 0.16316E-04 -4.7874 0.10000E+01 0.0000 20 AlO+ 0.39636E-13 -13.4019 0.36864E-13 -13.4334 0.93008E+00 -0.0315 21 AlOH+2 0.18595E-18 -18.7306 0.14675E-18 -18.8334 0.78920E+00 -0.1028 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.28055E-04 -4.5520 0.26082E-04 -4.5837 0.92966E+00 -0.0317 24 CH4,aq 0.17407E-19 -19.7593 0.17401E-19 -19.7594 0.99964E+00 -0.0002 29 CO,aq 0.19953E-18 -18.7000 0.19953E-18 -18.7000 0.10000E+01 0.0000 30 CO2,aq 0.17117E-07 -7.7666 0.17111E-07 -7.7667 0.99964E+00 -0.0002 31 CO3-2 0.15731E-05 -5.8033 0.12425E-05 -5.9057 0.78985E+00 -0.1025 32 CaCO3,aq 0.24943E-09 -9.6030 0.24943E-09 -9.6030 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.47422E-11 -11.3240 0.44106E-11 -11.3555 0.93008E+00 -0.0315 34 CaCl+ 0.36021E-11 -11.4435 0.33502E-11 -11.4749 0.93008E+00 -0.0315 35 CaCl2,aq 0.10005E-15 -15.9998 0.10005E-15 -15.9998 0.10000E+01 0.0000 36 CaOH+ 0.15637E-08 -8.8058 0.14544E-08 -8.8373 0.93008E+00 -0.0315 37 CaSO4,aq 0.10286E-09 -9.9878 0.10286E-09 -9.9878 0.10000E+01 0.0000 38 HCl,aq 0.19173E-13 -13.7173 0.19173E-13 -13.7173 0.10000E+01 0.0000 43 FeCl+ 0.29596E-15 -15.5288 0.27527E-15 -15.5602 0.93008E+00 -0.0315 46 FeO,aq 0.86276E-10 -10.0641 0.86276E-10 -10.0641 0.10000E+01 0.0000 47 FeOH+ 0.61802E-10 -10.2090 0.57481E-10 -10.2405 0.93008E+00 -0.0315 48 HFeO2- 0.12558E-08 -8.9011 0.11677E-08 -8.9327 0.92987E+00 -0.0316 49 FeO+ 0.70680E-14 -14.1507 0.65738E-14 -14.1822 0.93008E+00 -0.0315 51 FeO2- 0.22001E-08 -8.6576 0.20458E-08 -8.6891 0.92987E+00 -0.0316 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.45293E-09 -9.3440 0.45277E-09 -9.3441 0.99964E+00 -0.0002 54 KCl,aq 0.12495E-09 -9.9032 0.12495E-09 -9.9032 0.10000E+01 0.0000 55 KHSO4,aq 0.23564E-17 -17.6277 0.23564E-17 -17.6277 0.10000E+01 0.0000 56 KOH,aq 0.30181E-07 -7.5203 0.30181E-07 -7.5203 0.10000E+01 0.0000 57 KSO4- 0.18359E-07 -7.7361 0.17071E-07 -7.7677 0.92987E+00 -0.0316 58 MgCO3,aq 0.88579E-12 -12.0527 0.88579E-12 -12.0527 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.68725E-13 -13.1629 0.63920E-13 -13.1944 0.93008E+00 -0.0315 60 MgCl+ 0.46473E-13 -13.3328 0.43224E-13 -13.3643 0.93008E+00 -0.0315 61 MgOH+ 0.12312E-09 -9.9097 0.11451E-09 -9.9412 0.93008E+00 -0.0315 63 MnO,aq 0.30775E-09 -9.5118 0.30775E-09 -9.5118 0.10000E+01 0.0000 64 MnOH+ 0.76715E-09 -9.1151 0.71351E-09 -9.1466 0.93008E+00 -0.0315 65 MnO2-2 0.21336E-13 -13.6709 0.16853E-13 -13.7733 0.78985E+00 -0.1025 66 HMnO2- 0.31205E-11 -11.5058 0.29017E-11 -11.5373 0.92987E+00 -0.0316 69 MnCl+ 0.15367E-12 -12.8134 0.14293E-12 -12.8449 0.93008E+00 -0.0315 70 MnSO4,aq 0.10509E-11 -11.9784 0.10509E-11 -11.9784 0.10000E+01 0.0000 71 NaCl,aq 0.66146E-07 -7.1795 0.66146E-07 -7.1795 0.10000E+01 0.0000 72 NaOH,aq 0.87325E-06 -6.0589 0.87325E-06 -6.0589 0.10000E+01 0.0000 74 OH- 0.81191E-03 -3.0905 0.75480E-03 -3.1222 0.92966E+00 -0.0317 79 HPO3-2 0.10353E-16 -16.9849 0.81775E-17 -17.0874 0.78985E+00 -0.1025 81 H2PO3- 0.13728E-19 -19.8624 0.12765E-19 -19.8940 0.92987E+00 -0.0316 82 H3PO4,aq 0.23249E-13 -13.6336 0.23249E-13 -13.6336 0.10000E+01 0.0000 83 H2PO4- 0.85669E-07 -7.0672 0.79670E-07 -7.0987 0.92997E+00 -0.0315 84 PO4-3 0.10397E-07 -7.9831 0.62839E-08 -8.2018 0.60442E+00 -0.2187 87 H2P2O7-2 0.62894E-15 -15.2014 0.49677E-15 -15.3038 0.78985E+00 -0.1025 88 HP2O7-3 0.21333E-12 -12.6709 0.12818E-12 -12.8922 0.60085E+00 -0.2212 89 P2O7-4 0.96756E-13 -13.0143 0.39791E-13 -13.4002 0.41125E+00 -0.3859 90 H2S,aq 0.79881E-16 -16.0976 0.79852E-16 -16.0977 0.99964E+00 -0.0002 97 SO3-2 0.15714E-14 -14.8037 0.12433E-14 -14.9054 0.79125E+00 -0.1017 98 HSO3- 0.62185E-16 -16.2063 0.57824E-16 -16.2379 0.92987E+00 -0.0316 99 HSO4- 0.15965E-10 -10.7968 0.14851E-10 -10.8283 0.93019E+00 -0.0314 Charge balance for all species = 0.4601E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8540071E-09 -.1642416E-02 -.1655175E+01 0.0000 2 H2O 0.1000000E+01 0.5550840E+02 0.9998306E+06 0.0000 3 Cl- 0.1379410E-03 0.1380073E-03 0.4891942E+01 5.2079 4 SO4-- 0.2549212E-04 0.2551078E-04 0.2450190E+01 13.5037 5 HCO3- 0.1148271E-04 0.1307314E-04 0.7975508E+00 4.1283 6 HS- 0.3596461E-13 -.1871833E-09 -.6189473E-05 -4.3759 7 Al+++ 0.3001653E-24 0.2806465E-04 0.7570976E+00 2.5555 8 H4SiO4 0.5298286E-03 0.1245691E-02 0.1197097E+03 -3.2759 9 Ca++ 0.2076494E-07 0.2294611E-07 0.9194781E-03 10.4142 10 Mg++ 0.2952716E-09 0.4239323E-09 0.1030489E-04 8.5669 11 Fe++ 0.1746281E-11 0.3809234E-08 0.2126981E-03 6.3388 12 K+ 0.5915549E-04 0.5920416E-04 0.2314608E+01 4.8403 13 Na+ 0.1698474E-02 0.1715730E-02 0.3943758E+02 6.2983 14 Mn++ 0.2333182E-09 0.1312564E-08 0.7209739E-04 8.4647 15 HPO4-- 0.7237572E-05 0.7333638E-05 0.7037557E+00 12.9569 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2050296E-01 -.1642021E-02 -.1886094E-01 0.0000000E+00 2 H2O 0.5549272E+02 0.5549507E+02 -.2355419E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5984138E-04 0.2550466E-04 0.3433673E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3433691E-04 -.1871383E-09 -.3433673E-04 0.0000000E+00 7 Al+++ 0.4040059E-02 0.2805791E-04 0.4012001E-02 0.0000000E+00 8 H4SiO4 0.1290144E-01 0.1245391E-02 0.1165605E-01 0.0000000E+00 9 Ca++ 0.1439498E-02 0.2294060E-07 0.1439475E-02 0.0000000E+00 10 Mg++ 0.9833333E-03 0.4238305E-09 0.9833329E-03 0.0000000E+00 11 Fe++ 0.8834176E-03 0.3808319E-08 0.8834138E-03 0.0000000E+00 12 K+ 0.2630573E-03 0.5918994E-04 0.2038674E-03 0.0000000E+00 13 Na+ 0.1715318E-02 0.1715318E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2148252E-04 0.1312249E-08 0.2148121E-04 0.0000000E+00 15 HPO4-- 0.7331877E-05 0.7331877E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2792E-17 Mass of aqueous solution: 0.999930E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.2390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.1967E-03 -3.706 0.1093 -0.961 8.349 0.4158E-01 daphnite 0.1217E-03 -3.915 0.8687E-01 -1.061 6.634 0.2632E-01 chlorite-Mn 0.4296E-05 -5.367 0.3046E-02 -2.516 0.2326 0.9707E-03 hematite 0.1373E-03 -3.862 0.2193E-01 -1.659 1.675 0.4157E-02 microcline 0.6198E-04 -4.208 0.1725E-01 -1.763 1.318 0.6739E-02 muscovite 0.1419E-03 -3.848 0.5651E-01 -1.248 4.316 0.1998E-01 stilbite 0.1439E-02 -2.842 1.014 0.006 77.48 0.4731 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.309352 g Volume = 0.572900 cm3 Porosity: 61.6943% V(tot) - V(min): 0.92270E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.2390000 g log = 0.0931 Original solution: 1000.0103000 g Original solution / Rock added: 807.11 (Water/Rock Ratio), log = 2.9069 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1848E-05 1.0073 0.1959E-05 0.1944E-05 CH4,gas 0.2582E-16 1.0129 0.2752E-16 0.2717E-16 H2,gas 0.5900E-06 1.0006 0.6210E-06 0.6207E-06 H2S,gas 0.2223E-14 0.9959 0.2329E-14 0.2338E-14 S2,gas 0.5008E-36 1.0000 0.5268E-36 0.5268E-36 CO,gas 0.2995E-15 1.0000 0.3151E-15 0.3151E-15 SO3,gas 0.4520E-38 1.0000 0.4755E-38 0.4755E-38 SO2,gas 0.1062E-21 1.0000 0.1117E-21 0.1117E-21 HCl,gas 0.3218E-16 1.0000 0.3385E-16 0.3385E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.72794E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.07 -7.71 -2.569 0.13161E+05 -5.708 3 CH4,gas 4.81 -13.75 -18.56 -4.640 0.31691E+05 -16.560 4 H2,gas 8.29 0.08 -8.21 -4.690 0.14013E+05 -6.207 5 H2S,gas -5.94 -22.58 -16.63 -8.316 0.28400E+05 -14.633 6 S2,gas -7.03 -45.31 -38.28 -5.889 0.65359E+05 -36.278 7 CO,gas 3.51 -13.99 -17.50 -5.385 0.29884E+05 -15.502 8 SO3,gas 17.43 -22.90 -40.32 -10.081 0.68850E+05 -38.323 9 SO2,gas 1.14 -22.82 -23.95 -6.387 0.40897E+05 -21.952 10 HCl,gas 5.48 -12.99 -18.47 -9.235 0.31538E+05 -16.470 11 acmite 7.74 6.05 -1.69 -0.176 0.28891E+04 15 albite-high 0.75 -0.97 -1.72 -0.133 0.29428E+04 16 albite -0.33 -0.97 -0.65 -0.050 0.11021E+04 19 spessartine 24.55 20.68 -3.87 -0.194 0.66121E+04 20 analcite 3.37 2.30 -1.07 -0.119 0.18246E+04 21 andalusite 5.06 1.84 -3.23 -0.323 0.55104E+04 26 annite 20.21 16.58 -3.62 -0.201 0.61891E+04 27 phlogopite 27.15 23.27 -3.88 -0.215 0.66213E+04 29 anorthite 12.80 8.97 -3.82 -0.294 0.65297E+04 32 apatite-OH -17.99 -18.26 -0.27 -0.021 0.45627E+03 35 aragonite 0.99 -3.66 -4.64 -1.548 0.79283E+04 36 brucite 12.58 8.57 -4.01 -0.802 0.68465E+04 37 calcite 0.83 -3.66 -4.49 -1.497 0.76669E+04 38 carnegieite-low 9.06 5.58 -3.49 -0.498 0.59534E+04 39 carnegieite-high 10.13 5.58 -4.56 -0.651 0.77802E+04 40 carpholite-Mg 8.65 7.13 -1.52 -0.102 0.26026E+04 41 carpholite-Fe 6.78 4.90 -1.88 -0.126 0.32183E+04 42 celadonite 5.40 2.86 -2.54 -0.149 0.43392E+04 43 celadonite-Fe 3.94 0.63 -3.31 -0.194 0.56445E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81762E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.191 0.48821E+04 51 chloritoid-Fe 9.24 8.17 -1.06 -0.071 0.18180E+04 52 chloritoid-Mn 11.46 10.30 -1.16 -0.078 0.19865E+04 54 coesite -2.37 -3.28 -0.91 -0.302 0.15478E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.28 -0.73 -0.242 0.12407E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.43 -3.79 -0.379 0.64647E+04 68 hedenbergite 14.24 10.20 -4.04 -0.404 0.69035E+04 75 epidote 24.78 22.41 -2.36 -0.115 0.40375E+04 76 clinozoisite 22.92 18.67 -4.25 -0.193 0.72633E+04 77 epidote-Fe 29.94 26.15 -3.78 -0.197 0.64591E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79862E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63680E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.30 -1.95 -0.195 0.33276E+04 97 kalsilite 7.62 4.12 -3.50 -0.500 0.59767E+04 98 kaolinite -1.27 -1.44 -0.17 -0.015 0.28617E+03 99 kyanite 4.93 1.84 -3.10 -0.310 0.52872E+04 101 laumontite 2.97 2.42 -0.55 -0.037 0.94390E+03 102 lawsonite 9.68 8.97 -0.70 -0.047 0.12036E+04 103 leucite 4.17 0.84 -3.32 -0.332 0.56749E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70665E+04 107 magnetite 20.13 18.94 -1.20 -0.098 0.20428E+04 108 minnesotaite 10.46 5.91 -4.55 -0.268 0.77652E+04 113 margarite 17.45 14.08 -3.37 -0.135 0.57496E+04 121 paragonite 4.34 4.14 -0.20 -0.012 0.34058E+03 122 nepheline 8.38 5.58 -2.80 -0.400 0.47813E+04 136 prehnite 19.47 16.11 -3.35 -0.197 0.57278E+04 137 prehnite-Fe 22.59 19.86 -2.73 -0.164 0.46642E+04 145 pyroxmangite 7.42 5.19 -2.23 -0.445 0.38029E+04 146 pyrophyllite -6.10 -7.99 -1.89 -0.118 0.32347E+04 147 quartz -2.98 -3.28 -0.29 -0.098 0.50177E+03 151 rhodochrosite -0.96 -5.61 -4.65 -1.549 0.79364E+04 152 rhodonite 7.46 5.19 -2.27 -0.455 0.38821E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.84 -3.49 -0.349 0.59526E+04 164 stilpnomelane-Fe 13.18 13.02 -0.16 -0.005 0.27506E+03 165 stilpnomelane-Mg 27.60 24.16 -3.44 -0.103 0.58699E+04 168 sudoite 21.22 17.53 -3.69 -0.119 0.62973E+04 171 talc 16.55 12.60 -3.96 -0.233 0.67552E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76143E+04 177 topaz-H 4.67 1.84 -2.83 -0.257 0.48363E+04 178 tridymite -2.61 -3.28 -0.66 -0.220 0.11291E+04 187 wairakite 4.06 2.42 -1.64 -0.096 0.27947E+04 188 walstromite 11.53 7.14 -4.39 -0.878 0.74950E+04 189 wollastonite 10.48 7.14 -3.34 -0.669 0.57089E+04 190 pseudo-wollastonite 11.02 7.14 -3.88 -0.776 0.66275E+04 191 zoisite 22.96 18.67 -4.30 -0.195 0.73359E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.35 -2.79 -0.173 0.47640E+04 194 beidellite-H -2.24 -6.07 -3.83 -0.244 0.65345E+04 195 beidellite-K -1.44 -4.47 -3.04 -0.186 0.51835E+04 196 beidellite-Mg -1.71 -4.65 -2.95 -0.182 0.50331E+04 197 beidellite-Na -1.26 -3.99 -2.73 -0.167 0.46660E+04 199 chalcedony -2.79 -3.28 -0.48 -0.160 0.82208E+03 201 montmorillonite-Ca -2.21 -4.29 -2.08 -0.128 0.35453E+04 202 montmorillonite-K -2.16 -4.41 -2.25 -0.138 0.38426E+04 203 montmorillonite-Mg -2.40 -4.60 -2.19 -0.136 0.37455E+04 204 montmorillonite-Na -1.96 -3.93 -1.97 -0.121 0.33632E+04 205 nontronite-Ca 3.28 3.14 -0.14 -0.009 0.24383E+03 206 nontronite-H 2.60 1.42 -1.18 -0.079 0.20101E+04 207 nontronite-K 3.40 3.02 -0.39 -0.025 0.66251E+03 208 nontronite-Mg 3.14 2.83 -0.31 -0.020 0.52455E+03 209 nontronite-Na 3.58 3.50 -0.09 -0.006 0.14664E+03 224 tobermorite 9.84 5.40 -4.44 -1.211 0.75809E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.34 -3.49 -0.871 0.59512E+04 240 silica-amorphous -2.08 -3.28 -1.20 -0.399 0.20423E+04 242 an20ab80 2.08 1.02 -1.06 -0.082 0.18160E+04 243 an25ab75 2.71 1.51 -1.20 -0.092 0.20424E+04 244 an30ab70 3.34 2.01 -1.33 -0.103 0.22771E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.2390000 g New total amount of reactant added: 1.2790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4568E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.2790000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9998E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1182508E-02 Osmotic coef. = 0.9802 True ionic strength = .1838658E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.83347E-09 -9.0791 0.77508E-09 -9.1107 0.92994E+00 -0.0315 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12818E-03 -3.8922 0.92924E+00 -0.0319 4 SO4-- 0.25493E-04 -4.5936 0.20088E-04 -4.6971 0.78798E+00 -0.1035 5 HCO3- 0.11446E-04 -4.9414 0.10638E-04 -4.9732 0.92941E+00 -0.0318 6 HS- 0.33678E-13 -13.4727 0.31296E-13 -13.5045 0.92926E+00 -0.0319 7 Al+++ 0.28015E-24 -24.5526 0.16731E-24 -24.7765 0.59723E+00 -0.2239 8 H4SiO4 0.53412E-03 -3.2724 0.53412E-03 -3.2724 0.10000E+01 0.0000 9 Ca++ 0.18717E-07 -7.7278 0.14735E-07 -7.8317 0.78727E+00 -0.1039 10 Mg++ 0.28027E-09 -9.5524 0.22052E-09 -9.6566 0.78682E+00 -0.1041 11 Fe++ 0.16575E-11 -11.7805 0.13044E-11 -11.8846 0.78693E+00 -0.1041 12 K+ 0.56352E-04 -4.2491 0.52376E-04 -4.2809 0.92944E+00 -0.0318 13 Na+ 0.17476E-02 -2.7575 0.16240E-02 -2.7894 0.92923E+00 -0.0319 14 Mn++ 0.22146E-09 -9.6547 0.17429E-09 -9.7587 0.78701E+00 -0.1040 15 HPO4-- 0.74733E-05 -5.1265 0.58889E-05 -5.2300 0.78799E+00 -0.1035 16 HSiO3- 0.72355E-03 -3.1405 0.67235E-03 -3.1724 0.92924E+00 -0.0319 17 Ca(HSiO3)+ 0.23882E-09 -9.6219 0.22197E-09 -9.6537 0.92947E+00 -0.0318 18 Mg(HSiO3)+ 0.44479E-11 -11.3518 0.41342E-11 -11.3836 0.92947E+00 -0.0318 19 NaHSiO3,aq 0.17342E-04 -4.7609 0.17342E-04 -4.7609 0.10000E+01 0.0000 20 AlO+ 0.38683E-13 -13.4125 0.35955E-13 -13.4442 0.92947E+00 -0.0318 21 AlOH+2 0.17736E-18 -18.7511 0.13960E-18 -18.8551 0.78710E+00 -0.1040 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.28785E-04 -4.5408 0.26742E-04 -4.5728 0.92903E+00 -0.0320 24 CH4,aq 0.16268E-19 -19.7887 0.16262E-19 -19.7888 0.99963E+00 -0.0002 29 CO,aq 0.19198E-18 -18.7167 0.19198E-18 -18.7167 0.10000E+01 0.0000 30 CO2,aq 0.16630E-07 -7.7791 0.16624E-07 -7.7793 0.99963E+00 -0.0002 31 CO3-2 0.16108E-05 -5.7929 0.12690E-05 -5.8966 0.78777E+00 -0.1036 32 CaCO3,aq 0.22901E-09 -9.6402 0.22901E-09 -9.6402 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.42492E-11 -11.3717 0.39495E-11 -11.4035 0.92947E+00 -0.0318 34 CaCl+ 0.32381E-11 -11.4897 0.30097E-11 -11.5215 0.92947E+00 -0.0318 35 CaCl2,aq 0.89824E-16 -16.0466 0.89824E-16 -16.0466 0.10000E+01 0.0000 36 CaOH+ 0.14422E-08 -8.8410 0.13405E-08 -8.8727 0.92947E+00 -0.0318 37 CaSO4,aq 0.92226E-10 -10.0351 0.92226E-10 -10.0351 0.10000E+01 0.0000 38 HCl,aq 0.18687E-13 -13.7284 0.18687E-13 -13.7284 0.10000E+01 0.0000 43 FeCl+ 0.28017E-15 -15.5526 0.26040E-15 -15.5844 0.92947E+00 -0.0318 46 FeO,aq 0.85859E-10 -10.0662 0.85859E-10 -10.0662 0.10000E+01 0.0000 47 FeOH+ 0.60025E-10 -10.2217 0.55791E-10 -10.2534 0.92947E+00 -0.0318 48 HFeO2- 0.12822E-08 -8.8920 0.11915E-08 -8.9239 0.92924E+00 -0.0319 49 FeO+ 0.68981E-14 -14.1613 0.64116E-14 -14.1930 0.92947E+00 -0.0318 51 FeO2- 0.22573E-08 -8.6464 0.20976E-08 -8.6783 0.92924E+00 -0.0319 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44856E-09 -9.3482 0.44840E-09 -9.3483 0.99963E+00 -0.0002 54 KCl,aq 0.11887E-09 -9.9249 0.11887E-09 -9.9249 0.10000E+01 0.0000 55 KHSO4,aq 0.21822E-17 -17.6611 0.21822E-17 -17.6611 0.10000E+01 0.0000 56 KOH,aq 0.29459E-07 -7.5308 0.29459E-07 -7.5308 0.10000E+01 0.0000 57 KSO4- 0.17444E-07 -7.7584 0.16209E-07 -7.7902 0.92924E+00 -0.0319 58 MgCO3,aq 0.85640E-12 -12.0673 0.85640E-12 -12.0673 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.64847E-13 -13.1881 0.60273E-13 -13.2199 0.92947E+00 -0.0318 60 MgCl+ 0.43993E-13 -13.3566 0.40890E-13 -13.3884 0.92947E+00 -0.0318 61 MgOH+ 0.11958E-09 -9.9224 0.11114E-09 -9.9541 0.92947E+00 -0.0318 63 MnO,aq 0.30626E-09 -9.5139 0.30626E-09 -9.5139 0.10000E+01 0.0000 64 MnOH+ 0.74509E-09 -9.1278 0.69254E-09 -9.1596 0.92947E+00 -0.0318 65 MnO2-2 0.22381E-13 -13.6501 0.17631E-13 -13.7537 0.78777E+00 -0.1036 66 HMnO2- 0.31862E-11 -11.4967 0.29607E-11 -11.5286 0.92924E+00 -0.0319 69 MnCl+ 0.14547E-12 -12.8372 0.13521E-12 -12.8690 0.92947E+00 -0.0318 70 MnSO4,aq 0.99224E-12 -12.0034 0.99224E-12 -12.0034 0.10000E+01 0.0000 71 NaCl,aq 0.67969E-07 -7.1677 0.67969E-07 -7.1677 0.10000E+01 0.0000 72 NaOH,aq 0.92065E-06 -6.0359 0.92065E-06 -6.0359 0.10000E+01 0.0000 74 OH- 0.83301E-03 -3.0793 0.77390E-03 -3.1113 0.92903E+00 -0.0320 79 HPO3-2 0.10587E-16 -16.9752 0.83404E-17 -17.0788 0.78777E+00 -0.1036 81 H2PO3- 0.13665E-19 -19.8644 0.12698E-19 -19.8963 0.92924E+00 -0.0319 82 H3PO4,aq 0.22776E-13 -13.6425 0.22776E-13 -13.6425 0.10000E+01 0.0000 83 H2PO4- 0.86106E-07 -7.0650 0.80023E-07 -7.0968 0.92935E+00 -0.0318 84 PO4-3 0.11042E-07 -7.9570 0.66352E-08 -8.1781 0.60091E+00 -0.2212 87 H2P2O7-2 0.63620E-15 -15.1964 0.50118E-15 -15.3000 0.78777E+00 -0.1036 88 HP2O7-3 0.22199E-12 -12.6537 0.13259E-12 -12.8775 0.59727E+00 -0.2238 89 P2O7-4 0.10371E-12 -12.9842 0.42202E-13 -13.3747 0.40694E+00 -0.3905 90 H2S,aq 0.72908E-16 -16.1372 0.72881E-16 -16.1374 0.99963E+00 -0.0002 97 SO3-2 0.15562E-14 -14.8079 0.12282E-14 -14.9107 0.78919E+00 -0.1028 98 HSO3- 0.59950E-16 -16.2222 0.55708E-16 -16.2541 0.92924E+00 -0.0319 99 HSO4- 0.15541E-10 -10.8085 0.14447E-10 -10.8402 0.92957E+00 -0.0317 Charge balance for all species = 0.4600E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8334716E-09 -.1691554E-02 -.1704688E+01 0.0000 2 H2O 0.1000000E+01 0.5550840E+02 0.9998267E+06 0.0000 3 Cl- 0.1379402E-03 0.1380083E-03 0.4891958E+01 5.2185 4 SO4-- 0.2549323E-04 0.2551097E-04 0.2450199E+01 13.5242 5 HCO3- 0.1144554E-04 0.1307323E-04 0.7975535E+00 4.1375 6 HS- 0.3367827E-13 -.1954249E-09 -.6461969E-05 -4.3939 7 Al+++ 0.2801522E-24 0.2879401E-04 0.7767706E+00 2.5555 8 H4SiO4 0.5341250E-03 0.1275014E-02 0.1225272E+03 -3.2724 9 Ca++ 0.1871655E-07 0.2072632E-07 0.8305252E-03 10.3897 10 Mg++ 0.2802662E-09 0.4052564E-09 0.9850883E-05 8.5648 11 Fe++ 0.1657531E-11 0.3890549E-08 0.2172377E-03 6.3367 12 K+ 0.5635176E-04 0.5639878E-04 0.2204922E+01 4.8298 13 Na+ 0.1747634E-02 0.1765964E-02 0.4059211E+02 6.3212 14 Mn++ 0.2214608E-09 0.1277165E-08 0.7015272E-04 8.4626 15 HPO4-- 0.7473304E-05 0.7570453E-05 0.7264782E+00 12.9913 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2116530E-01 -.1691135E-02 -.1947417E-01 0.0000000E+00 2 H2O 0.5549222E+02 0.5549467E+02 -.2456154E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6094992E-04 0.2550467E-04 0.3544525E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3544545E-04 -.1953766E-09 -.3544525E-04 0.0000000E+00 7 Al+++ 0.4170489E-02 0.2878689E-04 0.4141702E-02 0.0000000E+00 8 H4SiO4 0.1331795E-01 0.1274699E-02 0.1204325E-01 0.0000000E+00 9 Ca++ 0.1485504E-02 0.2072120E-07 0.1485483E-02 0.0000000E+00 10 Mg++ 0.1015079E-02 0.4051562E-09 0.1015079E-02 0.0000000E+00 11 Fe++ 0.9119380E-03 0.3889587E-08 0.9119341E-03 0.0000000E+00 12 K+ 0.2715499E-03 0.5638483E-04 0.2151651E-03 0.0000000E+00 13 Na+ 0.1765528E-02 0.1765528E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2217606E-04 0.1276849E-08 0.2217479E-04 0.0000000E+00 15 HPO4-- 0.7568580E-05 0.7568580E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1626E-17 Mass of aqueous solution: 0.999926E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.2790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2030E-03 -3.692 0.1128 -0.948 8.344 0.4292E-01 daphnite 0.1257E-03 -3.901 0.8967E-01 -1.047 6.630 0.2717E-01 chlorite-Mn 0.4435E-05 -5.353 0.3144E-02 -2.502 0.2325 0.1002E-02 hematite 0.1418E-03 -3.848 0.2264E-01 -1.645 1.674 0.4292E-02 microcline 0.7050E-04 -4.152 0.1962E-01 -1.707 1.451 0.7666E-02 muscovite 0.1447E-03 -3.840 0.5762E-01 -1.239 4.261 0.2037E-01 stilbite 0.1485E-02 -2.828 1.047 0.020 77.41 0.4883 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.352392 g Volume = 0.591698 cm3 Porosity: 60.8562% V(tot) - V(min): 0.91990E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.2790000 g log = 0.1069 Original solution: 1000.0103000 g Original solution / Rock added: 781.87 (Water/Rock Ratio), log = 2.8931 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1796E-05 1.0073 0.1903E-05 0.1889E-05 CH4,gas 0.2414E-16 1.0129 0.2572E-16 0.2539E-16 H2,gas 0.5843E-06 1.0006 0.6150E-06 0.6147E-06 H2S,gas 0.2029E-14 0.9959 0.2126E-14 0.2134E-14 S2,gas 0.4253E-36 1.0000 0.4474E-36 0.4474E-36 CO,gas 0.2882E-15 1.0000 0.3031E-15 0.3031E-15 SO3,gas 0.4289E-38 1.0000 0.4512E-38 0.4512E-38 SO2,gas 0.9979E-22 1.0000 0.1050E-21 0.1050E-21 HCl,gas 0.3137E-16 1.0000 0.3300E-16 0.3300E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.08 -7.72 -2.574 0.13183E+05 -5.721 3 CH4,gas 4.81 -13.78 -18.59 -4.647 0.31742E+05 -16.590 4 H2,gas 8.29 0.08 -8.21 -4.692 0.14020E+05 -6.211 5 H2S,gas -5.94 -22.62 -16.67 -8.336 0.28468E+05 -14.673 6 S2,gas -7.03 -45.38 -38.35 -5.900 0.65480E+05 -36.349 7 CO,gas 3.51 -14.01 -17.52 -5.390 0.29912E+05 -15.518 8 SO3,gas 17.43 -22.92 -40.35 -10.086 0.68889E+05 -38.346 9 SO2,gas 1.14 -22.84 -23.98 -6.394 0.40943E+05 -21.979 10 HCl,gas 5.48 -13.00 -18.48 -9.241 0.31557E+05 -16.482 11 acmite 7.74 6.08 -1.66 -0.173 0.28379E+04 15 albite-high 0.75 -0.94 -1.69 -0.130 0.28856E+04 16 albite -0.33 -0.94 -0.61 -0.047 0.10450E+04 19 spessartine 24.55 20.68 -3.87 -0.193 0.66049E+04 20 analcite 3.37 2.33 -1.04 -0.115 0.17734E+04 21 andalusite 5.06 1.84 -3.22 -0.322 0.55044E+04 26 annite 20.21 16.58 -3.63 -0.202 0.61999E+04 27 phlogopite 27.15 23.26 -3.88 -0.216 0.66320E+04 29 anorthite 12.80 8.96 -3.84 -0.296 0.65597E+04 32 apatite-OH -17.99 -18.41 -0.42 -0.032 0.71163E+03 35 aragonite 0.99 -3.69 -4.68 -1.560 0.79916E+04 36 brucite 12.58 8.56 -4.01 -0.802 0.68501E+04 37 calcite 0.83 -3.69 -4.53 -1.509 0.77303E+04 38 carnegieite-low 9.06 5.60 -3.46 -0.494 0.59082E+04 39 carnegieite-high 10.13 5.60 -4.53 -0.647 0.77350E+04 40 carpholite-Mg 8.65 7.13 -1.52 -0.101 0.25942E+04 41 carpholite-Fe 6.78 4.90 -1.88 -0.125 0.32099E+04 42 celadonite 5.40 2.86 -2.54 -0.149 0.43368E+04 43 celadonite-Fe 3.94 0.63 -3.30 -0.194 0.56422E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81750E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.191 0.48797E+04 51 chloritoid-Fe 9.24 8.18 -1.06 -0.071 0.18156E+04 52 chloritoid-Mn 11.46 10.30 -1.16 -0.077 0.19841E+04 54 coesite -2.37 -3.27 -0.90 -0.301 0.15419E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.27 -0.72 -0.241 0.12347E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.41 -3.81 -0.381 0.64983E+04 68 hedenbergite 14.24 10.18 -4.06 -0.406 0.69371E+04 75 epidote 24.78 22.37 -2.40 -0.117 0.41033E+04 76 clinozoisite 22.92 18.63 -4.29 -0.195 0.73292E+04 77 epidote-Fe 29.94 26.12 -3.82 -0.199 0.65250E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79874E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.47 -3.73 -0.311 0.63668E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.33 -1.92 -0.192 0.32765E+04 97 kalsilite 7.62 4.11 -3.51 -0.501 0.59887E+04 98 kaolinite -1.27 -1.43 -0.16 -0.015 0.27419E+03 99 kyanite 4.93 1.84 -3.09 -0.309 0.52812E+04 101 laumontite 2.97 2.41 -0.56 -0.038 0.96187E+03 102 lawsonite 9.68 8.96 -0.72 -0.048 0.12336E+04 103 leucite 4.17 0.84 -3.33 -0.333 0.56809E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70653E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20463E+04 108 minnesotaite 10.46 5.92 -4.54 -0.267 0.77520E+04 113 margarite 17.45 14.07 -3.38 -0.135 0.57796E+04 121 paragonite 4.34 4.17 -0.17 -0.010 0.28342E+03 122 nepheline 8.38 5.60 -2.77 -0.396 0.47361E+04 134 phlogopite-Na 29.73 24.75 -4.98 -0.277 0.84989E+04 136 prehnite 19.47 16.07 -3.39 -0.200 0.57936E+04 137 prehnite-Fe 22.59 19.82 -2.77 -0.167 0.47301E+04 145 pyroxmangite 7.42 5.19 -2.23 -0.445 0.38005E+04 146 pyrophyllite -6.10 -7.98 -1.88 -0.118 0.32108E+04 147 quartz -2.98 -3.27 -0.29 -0.097 0.49578E+03 151 rhodochrosite -0.96 -5.62 -4.66 -1.554 0.79614E+04 152 rhodonite 7.46 5.19 -2.27 -0.454 0.38797E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.84 -3.48 -0.348 0.59466E+04 164 stilpnomelane-Fe 13.18 13.03 -0.15 -0.004 0.25410E+03 165 stilpnomelane-Mg 27.60 24.17 -3.43 -0.102 0.58489E+04 168 sudoite 21.22 17.53 -3.68 -0.119 0.62865E+04 171 talc 16.55 12.60 -3.95 -0.232 0.67420E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76155E+04 177 topaz-H 4.67 1.84 -2.83 -0.257 0.48303E+04 178 tridymite -2.61 -3.27 -0.66 -0.219 0.11231E+04 187 wairakite 4.06 2.41 -1.65 -0.097 0.28127E+04 188 walstromite 11.53 7.12 -4.41 -0.882 0.75309E+04 189 wollastonite 10.48 7.12 -3.36 -0.673 0.57448E+04 190 pseudo-wollastonite 11.02 7.12 -3.90 -0.781 0.66634E+04 191 zoisite 22.96 18.63 -4.33 -0.197 0.74017E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.34 -2.78 -0.172 0.47490E+04 194 beidellite-H -2.24 -6.06 -3.81 -0.243 0.65125E+04 195 beidellite-K -1.44 -4.46 -3.03 -0.185 0.51675E+04 196 beidellite-Mg -1.71 -4.64 -2.94 -0.182 0.50117E+04 197 beidellite-Na -1.26 -3.97 -2.71 -0.166 0.46310E+04 199 chalcedony -2.79 -3.27 -0.48 -0.159 0.81609E+03 201 montmorillonite-Ca -2.21 -4.28 -2.07 -0.128 0.35295E+04 202 montmorillonite-K -2.16 -4.40 -2.24 -0.137 0.38257E+04 203 montmorillonite-Mg -2.40 -4.58 -2.18 -0.135 0.37233E+04 204 montmorillonite-Na -1.96 -3.91 -1.95 -0.119 0.33274E+04 205 nontronite-Ca 3.28 3.15 -0.13 -0.009 0.22877E+03 206 nontronite-H 2.60 1.43 -1.16 -0.078 0.19881E+04 207 nontronite-K 3.40 3.03 -0.38 -0.024 0.64646E+03 208 nontronite-Mg 3.14 2.84 -0.29 -0.019 0.50317E+03 209 nontronite-Na 3.58 3.52 -0.07 -0.004 0.11172E+03 224 tobermorite 9.84 5.38 -4.46 -1.216 0.76098E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.34 -3.49 -0.872 0.59548E+04 240 silica-amorphous -2.08 -3.27 -1.19 -0.398 0.20363E+04 242 an20ab80 2.08 1.04 -1.04 -0.080 0.17763E+04 243 an25ab75 2.71 1.53 -1.18 -0.090 0.20070E+04 244 an30ab70 3.34 2.03 -1.32 -0.101 0.22461E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.2790000 g New total amount of reactant added: 1.3190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4568E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.3190000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1210023E-02 Osmotic coef. = 0.9800 True ionic strength = .1885400E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.81411E-09 -9.0893 0.75659E-09 -9.1211 0.92935E+00 -0.0318 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12809E-03 -3.8925 0.92863E+00 -0.0322 4 SO4-- 0.25494E-04 -4.5936 0.20037E-04 -4.6982 0.78593E+00 -0.1046 5 HCO3- 0.11409E-04 -4.9428 0.10597E-04 -4.9748 0.92880E+00 -0.0321 6 HS- 0.31541E-13 -13.5011 0.29290E-13 -13.5333 0.92865E+00 -0.0321 7 Al+++ 0.26212E-24 -24.5815 0.15562E-24 -24.8079 0.59371E+00 -0.2264 8 H4SiO4 0.53854E-03 -3.2688 0.53854E-03 -3.2688 0.10000E+01 0.0000 9 Ca++ 0.16880E-07 -7.7726 0.13254E-07 -7.8777 0.78520E+00 -0.1050 10 Mg++ 0.26644E-09 -9.5744 0.20909E-09 -9.6797 0.78475E+00 -0.1053 11 Fe++ 0.15758E-11 -11.8025 0.12367E-11 -11.9077 0.78485E+00 -0.1052 12 K+ 0.53700E-04 -4.2700 0.49879E-04 -4.3021 0.92883E+00 -0.0321 13 Na+ 0.17968E-02 -2.7455 0.16685E-02 -2.7777 0.92861E+00 -0.0322 14 Mn++ 0.21054E-09 -9.6767 0.16526E-09 -9.7818 0.78494E+00 -0.1052 15 HPO4-- 0.77090E-05 -5.1130 0.60588E-05 -5.2176 0.78594E+00 -0.1046 16 HSiO3- 0.74785E-03 -3.1262 0.69448E-03 -3.1583 0.92863E+00 -0.0322 17 Ca(HSiO3)+ 0.22203E-09 -9.6536 0.20623E-09 -9.6856 0.92886E+00 -0.0321 18 Mg(HSiO3)+ 0.43590E-11 -11.3606 0.40489E-11 -11.3927 0.92886E+00 -0.0321 19 NaHSiO3,aq 0.18404E-04 -4.7351 0.18404E-04 -4.7351 0.10000E+01 0.0000 20 AlO+ 0.37785E-13 -13.4227 0.35097E-13 -13.4547 0.92886E+00 -0.0321 21 AlOH+2 0.16944E-18 -18.7710 0.13302E-18 -18.8761 0.78503E+00 -0.1051 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.29508E-04 -4.5301 0.27396E-04 -4.5623 0.92842E+00 -0.0323 24 CH4,aq 0.15206E-19 -19.8180 0.15200E-19 -19.8182 0.99963E+00 -0.0002 29 CO,aq 0.18484E-18 -18.7332 0.18484E-18 -18.7332 0.10000E+01 0.0000 30 CO2,aq 0.16170E-07 -7.7913 0.16164E-07 -7.7914 0.99963E+00 -0.0002 31 CO3-2 0.16481E-05 -5.7830 0.12950E-05 -5.8877 0.78571E+00 -0.1047 32 CaCO3,aq 0.21021E-09 -9.6774 0.21021E-09 -9.6774 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.38099E-11 -11.4191 0.35388E-11 -11.4511 0.92886E+00 -0.0321 34 CaCl+ 0.29126E-11 -11.5357 0.27054E-11 -11.5678 0.92886E+00 -0.0321 35 CaCl2,aq 0.80688E-16 -16.0932 0.80688E-16 -16.0932 0.10000E+01 0.0000 36 CaOH+ 0.13298E-08 -8.8762 0.12352E-08 -8.9082 0.92886E+00 -0.0321 37 CaSO4,aq 0.82744E-10 -10.0823 0.82744E-10 -10.0823 0.10000E+01 0.0000 38 HCl,aq 0.18229E-13 -13.7392 0.18229E-13 -13.7392 0.10000E+01 0.0000 43 FeCl+ 0.26564E-15 -15.5757 0.24674E-15 -15.6078 0.92886E+00 -0.0321 46 FeO,aq 0.85436E-10 -10.0684 0.85436E-10 -10.0684 0.10000E+01 0.0000 47 FeOH+ 0.58342E-10 -10.2340 0.54192E-10 -10.2661 0.92886E+00 -0.0321 48 HFeO2- 0.13079E-08 -8.8834 0.12146E-08 -8.9156 0.92863E+00 -0.0322 49 FeO+ 0.67380E-14 -14.1715 0.62586E-14 -14.2035 0.92886E+00 -0.0321 51 FeO2- 0.23140E-08 -8.6356 0.21489E-08 -8.6678 0.92863E+00 -0.0322 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44416E-09 -9.3525 0.44399E-09 -9.3526 0.99963E+00 -0.0002 54 KCl,aq 0.11313E-09 -9.9464 0.11313E-09 -9.9464 0.10000E+01 0.0000 55 KHSO4,aq 0.20234E-17 -17.6939 0.20234E-17 -17.6939 0.10000E+01 0.0000 56 KOH,aq 0.28740E-07 -7.5415 0.28740E-07 -7.5415 0.10000E+01 0.0000 57 KSO4- 0.16581E-07 -7.7804 0.15397E-07 -7.8126 0.92863E+00 -0.0322 58 MgCO3,aq 0.82864E-12 -12.0816 0.82864E-12 -12.0816 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.61288E-13 -13.2126 0.56928E-13 -13.2447 0.92886E+00 -0.0321 60 MgCl+ 0.41712E-13 -13.3797 0.38744E-13 -13.4118 0.92886E+00 -0.0321 61 MgOH+ 0.11623E-09 -9.9347 0.10796E-09 -9.9668 0.92886E+00 -0.0321 63 MnO,aq 0.30476E-09 -9.5160 0.30476E-09 -9.5160 0.10000E+01 0.0000 64 MnOH+ 0.72421E-09 -9.1401 0.67269E-09 -9.1722 0.92886E+00 -0.0321 65 MnO2-2 0.23433E-13 -13.6302 0.18412E-13 -13.7349 0.78571E+00 -0.1047 66 HMnO2- 0.32501E-11 -11.4881 0.30182E-11 -11.5203 0.92863E+00 -0.0322 69 MnCl+ 0.13793E-12 -12.8603 0.12812E-12 -12.8924 0.92886E+00 -0.0321 70 MnSO4,aq 0.93840E-12 -12.0276 0.93840E-12 -12.0276 0.10000E+01 0.0000 71 NaCl,aq 0.69787E-07 -7.1562 0.69787E-07 -7.1562 0.10000E+01 0.0000 72 NaOH,aq 0.96902E-06 -6.0137 0.96902E-06 -6.0137 0.10000E+01 0.0000 74 OH- 0.85394E-03 -3.0686 0.79281E-03 -3.1008 0.92842E+00 -0.0323 79 HPO3-2 0.10814E-16 -16.9660 0.84967E-17 -17.0708 0.78571E+00 -0.1047 81 H2PO3- 0.13598E-19 -19.8665 0.12628E-19 -19.8987 0.92863E+00 -0.0322 82 H3PO4,aq 0.22329E-13 -13.6511 0.22329E-13 -13.6511 0.10000E+01 0.0000 83 H2PO4- 0.86534E-07 -7.0628 0.80368E-07 -7.0949 0.92874E+00 -0.0321 84 PO4-3 0.11706E-07 -7.9316 0.69935E-08 -8.1553 0.59746E+00 -0.2237 87 H2P2O7-2 0.64338E-15 -15.1915 0.50551E-15 -15.2963 0.78571E+00 -0.1047 88 HP2O7-3 0.23074E-12 -12.6369 0.13701E-12 -12.8633 0.59376E+00 -0.2264 89 P2O7-4 0.11093E-12 -12.9550 0.44673E-13 -13.3500 0.40272E+00 -0.3950 90 H2S,aq 0.66608E-16 -16.1765 0.66583E-16 -16.1766 0.99963E+00 -0.0002 97 SO3-2 0.15409E-14 -14.8122 0.12130E-14 -14.9161 0.78717E+00 -0.1039 98 HSO3- 0.57834E-16 -16.2378 0.53707E-16 -16.2700 0.92863E+00 -0.0322 99 HSO4- 0.15141E-10 -10.8198 0.14066E-10 -10.8518 0.92897E+00 -0.0320 Charge balance for all species = 0.4598E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8141120E-09 -.1740826E-02 -.1754337E+01 0.0000 2 H2O 0.1000000E+01 0.5550840E+02 0.9998228E+06 0.0000 3 Cl- 0.1379394E-03 0.1380093E-03 0.4891975E+01 5.2287 4 SO4-- 0.2549428E-04 0.2551117E-04 0.2450208E+01 13.5441 5 HCO3- 0.1140882E-04 0.1307333E-04 0.7975561E+00 4.1463 6 HS- 0.3154074E-13 -.2036156E-09 -.6732781E-05 -4.4121 7 Al+++ 0.2621194E-24 0.2951714E-04 0.7962752E+00 2.5555 8 H4SiO4 0.5385411E-03 0.1304798E-02 0.1253889E+03 -3.2688 9 Ca++ 0.1687963E-07 0.1873117E-07 0.7505746E-03 10.3646 10 Mg++ 0.2664403E-09 0.3879563E-09 0.9430318E-05 8.5626 11 Fe++ 0.1575758E-11 0.3970784E-08 0.2217170E-03 6.3346 12 K+ 0.5370050E-04 0.5374593E-04 0.2101200E+01 4.8191 13 Na+ 0.1796757E-02 0.1816200E-02 0.4174665E+02 6.3435 14 Mn++ 0.2105353E-09 0.1243853E-08 0.6832263E-04 8.4604 15 HPO4-- 0.7709030E-05 0.7807270E-05 0.7492009E+00 13.0247 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2182764E-01 -.1740383E-02 -.2008726E-01 0.0000000E+00 2 H2O 0.5549172E+02 0.5549427E+02 -.2555960E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6205846E-04 0.2550467E-04 0.3655378E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3655399E-04 -.2035638E-09 -.3655378E-04 0.0000000E+00 7 Al+++ 0.4300918E-02 0.2950963E-04 0.4271409E-02 0.0000000E+00 8 H4SiO4 0.1373446E-01 0.1304466E-02 0.1242999E-01 0.0000000E+00 9 Ca++ 0.1531509E-02 0.1872641E-07 0.1531490E-02 0.0000000E+00 10 Mg++ 0.1046825E-02 0.3878576E-09 0.1046825E-02 0.0000000E+00 11 Fe++ 0.9404583E-03 0.3969774E-08 0.9404544E-03 0.0000000E+00 12 K+ 0.2800425E-03 0.5373225E-04 0.2263102E-03 0.0000000E+00 13 Na+ 0.1815737E-02 0.1815737E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2286961E-04 0.1243536E-08 0.2286836E-04 0.0000000E+00 15 HPO4-- 0.7805284E-05 0.7805284E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1091E-17 Mass of aqueous solution: 0.999923E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.3190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2094E-03 -3.679 0.1164 -0.934 8.340 0.4426E-01 daphnite 0.1296E-03 -3.887 0.9247E-01 -1.034 6.627 0.2802E-01 chlorite-Mn 0.4574E-05 -5.340 0.3243E-02 -2.489 0.2324 0.1033E-02 hematite 0.1462E-03 -3.835 0.2335E-01 -1.632 1.673 0.4426E-02 microcline 0.7880E-04 -4.104 0.2193E-01 -1.659 1.572 0.8567E-02 muscovite 0.1475E-03 -3.831 0.5876E-01 -1.231 4.211 0.2078E-01 stilbite 0.1531E-02 -2.815 1.079 0.033 77.35 0.5034 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.395399 g Volume = 0.610482 cm3 Porosity: 60.0365% V(tot) - V(min): 0.91712E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.3190000 g log = 0.1202 Original solution: 1000.0103000 g Original solution / Rock added: 758.16 (Water/Rock Ratio), log = 2.8798 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1746E-05 1.0073 0.1850E-05 0.1837E-05 CH4,gas 0.2256E-16 1.0129 0.2404E-16 0.2373E-16 H2,gas 0.5786E-06 1.0006 0.6090E-06 0.6086E-06 H2S,gas 0.1854E-14 0.9959 0.1942E-14 0.1950E-14 S2,gas 0.3621E-36 1.0000 0.3809E-36 0.3809E-36 CO,gas 0.2775E-15 1.0000 0.2919E-15 0.2919E-15 SO3,gas 0.4076E-38 1.0000 0.4288E-38 0.4288E-38 SO2,gas 0.9390E-22 1.0000 0.9878E-22 0.9878E-22 HCl,gas 0.3060E-16 1.0000 0.3219E-16 0.3219E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.10 -7.73 -2.578 0.13203E+05 -5.733 3 CH4,gas 4.81 -13.81 -18.62 -4.655 0.31792E+05 -16.619 4 H2,gas 8.29 0.07 -8.22 -4.695 0.14028E+05 -6.215 5 H2S,gas -5.94 -22.65 -16.71 -8.356 0.28535E+05 -14.712 6 S2,gas -7.03 -45.45 -38.42 -5.911 0.65600E+05 -36.419 7 CO,gas 3.51 -14.02 -17.53 -5.395 0.29940E+05 -15.535 8 SO3,gas 17.43 -22.94 -40.37 -10.092 0.68927E+05 -38.368 9 SO2,gas 1.14 -22.87 -24.01 -6.401 0.40988E+05 -22.005 10 HCl,gas 5.48 -13.01 -18.49 -9.246 0.31575E+05 -16.492 11 acmite 7.74 6.10 -1.63 -0.170 0.27878E+04 15 albite-high 0.75 -0.91 -1.66 -0.127 0.28293E+04 16 albite -0.33 -0.91 -0.58 -0.045 0.98867E+03 19 spessartine 24.55 20.69 -3.86 -0.193 0.65976E+04 20 analcite 3.37 2.36 -1.01 -0.112 0.17233E+04 21 andalusite 5.06 1.84 -3.22 -0.322 0.54983E+04 26 annite 20.21 16.57 -3.64 -0.202 0.62108E+04 27 phlogopite 27.15 23.26 -3.89 -0.216 0.66430E+04 29 anorthite 12.80 8.94 -3.86 -0.297 0.65902E+04 32 apatite-OH -17.99 -18.56 -0.57 -0.044 0.96948E+03 35 aragonite 0.99 -3.73 -4.72 -1.573 0.80551E+04 36 brucite 12.58 8.56 -4.01 -0.803 0.68538E+04 37 calcite 0.83 -3.73 -4.56 -1.522 0.77938E+04 38 carnegieite-low 9.06 5.63 -3.43 -0.491 0.58641E+04 39 carnegieite-high 10.13 5.63 -4.50 -0.643 0.76910E+04 40 carpholite-Mg 8.65 7.14 -1.51 -0.101 0.25857E+04 41 carpholite-Fe 6.78 4.91 -1.87 -0.125 0.32014E+04 42 celadonite 5.40 2.86 -2.54 -0.149 0.43344E+04 43 celadonite-Fe 3.94 0.63 -3.30 -0.194 0.56397E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81738E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.190 0.48773E+04 51 chloritoid-Fe 9.24 8.18 -1.06 -0.071 0.18132E+04 52 chloritoid-Mn 11.46 10.30 -1.16 -0.077 0.19816E+04 54 coesite -2.37 -3.27 -0.90 -0.300 0.15358E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.27 -0.72 -0.240 0.12286E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.39 -3.83 -0.383 0.65325E+04 68 hedenbergite 14.24 10.16 -4.08 -0.408 0.69713E+04 75 epidote 24.78 22.33 -2.44 -0.118 0.41705E+04 76 clinozoisite 22.92 18.59 -4.33 -0.197 0.73964E+04 77 epidote-Fe 29.94 26.08 -3.86 -0.201 0.65921E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79886E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.47 -3.73 -0.311 0.63656E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.36 -1.89 -0.189 0.32263E+04 97 kalsilite 7.62 4.11 -3.51 -0.502 0.60009E+04 98 kaolinite -1.27 -1.43 -0.15 -0.014 0.26198E+03 99 kyanite 4.93 1.84 -3.09 -0.309 0.52751E+04 101 laumontite 2.97 2.40 -0.57 -0.038 0.98019E+03 102 lawsonite 9.68 8.94 -0.74 -0.049 0.12641E+04 103 leucite 4.17 0.84 -3.33 -0.333 0.56870E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70641E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20500E+04 108 minnesotaite 10.46 5.93 -4.53 -0.267 0.77386E+04 113 margarite 17.45 14.05 -3.40 -0.136 0.58101E+04 121 paragonite 4.34 4.20 -0.13 -0.008 0.22713E+03 122 nepheline 8.38 5.63 -2.75 -0.393 0.46920E+04 134 phlogopite-Na 29.73 24.78 -4.95 -0.275 0.84536E+04 136 prehnite 19.47 16.03 -3.43 -0.202 0.58608E+04 137 prehnite-Fe 22.59 19.78 -2.81 -0.169 0.47972E+04 145 pyroxmangite 7.42 5.19 -2.22 -0.445 0.37981E+04 146 pyrophyllite -6.10 -7.96 -1.87 -0.117 0.31863E+04 147 quartz -2.98 -3.27 -0.29 -0.096 0.48967E+03 151 rhodochrosite -0.96 -5.64 -4.68 -1.559 0.79859E+04 152 rhodonite 7.46 5.19 -2.27 -0.454 0.38773E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.84 -3.48 -0.348 0.59405E+04 164 stilpnomelane-Fe 13.18 13.04 -0.14 -0.004 0.23273E+03 165 stilpnomelane-Mg 27.60 24.18 -3.41 -0.102 0.58275E+04 168 sudoite 21.22 17.54 -3.68 -0.119 0.62755E+04 171 talc 16.55 12.61 -3.94 -0.232 0.67286E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76167E+04 177 topaz-H 4.67 1.84 -2.83 -0.257 0.48242E+04 178 tridymite -2.61 -3.27 -0.65 -0.218 0.11170E+04 187 wairakite 4.06 2.40 -1.66 -0.098 0.28310E+04 188 walstromite 11.53 7.10 -4.43 -0.886 0.75676E+04 189 wollastonite 10.48 7.10 -3.39 -0.677 0.57815E+04 190 pseudo-wollastonite 11.02 7.10 -3.92 -0.785 0.67001E+04 191 zoisite 22.96 18.59 -4.37 -0.199 0.74689E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.33 -2.77 -0.171 0.47336E+04 194 beidellite-H -2.24 -6.04 -3.80 -0.243 0.64901E+04 195 beidellite-K -1.44 -4.45 -3.02 -0.185 0.51511E+04 196 beidellite-Mg -1.71 -4.63 -2.92 -0.181 0.49899E+04 197 beidellite-Na -1.26 -3.95 -2.69 -0.165 0.45961E+04 199 chalcedony -2.79 -3.27 -0.47 -0.158 0.80999E+03 201 montmorillonite-Ca -2.21 -4.27 -2.06 -0.127 0.35133E+04 202 montmorillonite-K -2.16 -4.39 -2.23 -0.137 0.38086E+04 203 montmorillonite-Mg -2.40 -4.57 -2.17 -0.134 0.37007E+04 204 montmorillonite-Na -1.96 -3.89 -1.93 -0.118 0.32917E+04 205 nontronite-Ca 3.28 3.15 -0.12 -0.008 0.21341E+03 206 nontronite-H 2.60 1.44 -1.15 -0.077 0.19657E+04 207 nontronite-K 3.40 3.03 -0.37 -0.024 0.63010E+03 208 nontronite-Mg 3.14 2.86 -0.28 -0.018 0.48136E+03 209 nontronite-Na 3.58 3.54 -0.04 -0.003 0.76785E+02 224 tobermorite 9.84 5.36 -4.47 -1.221 0.76393E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.872 0.59585E+04 240 silica-amorphous -2.08 -3.27 -1.19 -0.396 0.20302E+04 242 an20ab80 2.08 1.06 -1.02 -0.078 0.17374E+04 243 an25ab75 2.71 1.55 -1.16 -0.089 0.19724E+04 244 an30ab70 3.34 2.05 -1.30 -0.100 0.22159E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.3190000 g New total amount of reactant added: 1.3590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4569E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.3590000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1237585E-02 Osmotic coef. = 0.9798 True ionic strength = .1932250E-02 Chg. balance for total moles = 0.4569E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.79583E-09 -9.0992 0.73913E-09 -9.1313 0.92876E+00 -0.0321 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12801E-03 -3.8928 0.92802E+00 -0.0324 4 SO4-- 0.25495E-04 -4.5935 0.19986E-04 -4.6993 0.78390E+00 -0.1057 5 HCO3- 0.11373E-04 -4.9441 0.10556E-04 -4.9765 0.92820E+00 -0.0324 6 HS- 0.29545E-13 -13.5295 0.27419E-13 -13.5620 0.92804E+00 -0.0324 7 Al+++ 0.24582E-24 -24.6094 0.14510E-24 -24.8383 0.59026E+00 -0.2290 8 H4SiO4 0.54306E-03 -3.2651 0.54306E-03 -3.2651 0.10000E+01 0.0000 9 Ca++ 0.15233E-07 -7.8172 0.11930E-07 -7.9234 0.78317E+00 -0.1061 10 Mg++ 0.25367E-09 -9.5957 0.19855E-09 -9.7021 0.78270E+00 -0.1064 11 Fe++ 0.15002E-11 -11.8238 0.11744E-11 -11.9302 0.78281E+00 -0.1063 12 K+ 0.51195E-04 -4.2908 0.47520E-04 -4.3231 0.92823E+00 -0.0323 13 Na+ 0.18458E-02 -2.7338 0.17130E-02 -2.7663 0.92801E+00 -0.0324 14 Mn++ 0.20045E-09 -9.6980 0.15693E-09 -9.8043 0.78289E+00 -0.1063 15 HPO4-- 0.79447E-05 -5.0999 0.62280E-05 -5.2056 0.78392E+00 -0.1057 16 HSiO3- 0.77245E-03 -3.1121 0.71685E-03 -3.1446 0.92802E+00 -0.0324 17 Ca(HSiO3)+ 0.20642E-09 -9.6852 0.19161E-09 -9.7176 0.92826E+00 -0.0323 18 Mg(HSiO3)+ 0.42755E-11 -11.3690 0.39687E-11 -11.4013 0.92826E+00 -0.0323 19 NaHSiO3,aq 0.19503E-04 -4.7099 0.19503E-04 -4.7099 0.10000E+01 0.0000 20 AlO+ 0.36937E-13 -13.4325 0.34287E-13 -13.4649 0.92826E+00 -0.0323 21 AlOH+2 0.16213E-18 -18.7901 0.12695E-18 -18.8964 0.78299E+00 -0.1062 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.30225E-04 -4.5196 0.28043E-04 -4.5522 0.92780E+00 -0.0325 24 CH4,aq 0.14216E-19 -19.8472 0.14210E-19 -19.8474 0.99962E+00 -0.0002 29 CO,aq 0.17809E-18 -18.7494 0.17809E-18 -18.7494 0.10000E+01 0.0000 30 CO2,aq 0.15737E-07 -7.8031 0.15731E-07 -7.8032 0.99962E+00 -0.0002 31 CO3-2 0.16849E-05 -5.7734 0.13205E-05 -5.8793 0.78369E+00 -0.1059 32 CaCO3,aq 0.19294E-09 -9.7146 0.19294E-09 -9.7146 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.34184E-11 -11.4662 0.31731E-11 -11.4985 0.92826E+00 -0.0323 34 CaCl+ 0.26216E-11 -11.5814 0.24335E-11 -11.6138 0.92826E+00 -0.0323 35 CaCl2,aq 0.72532E-16 -16.1395 0.72532E-16 -16.1395 0.10000E+01 0.0000 36 CaOH+ 0.12261E-08 -8.9115 0.11381E-08 -8.9438 0.92826E+00 -0.0323 37 CaSO4,aq 0.74290E-10 -10.1291 0.74290E-10 -10.1291 0.10000E+01 0.0000 38 HCl,aq 0.17797E-13 -13.7497 0.17797E-13 -13.7497 0.10000E+01 0.0000 43 FeCl+ 0.25225E-15 -15.5982 0.23415E-15 -15.6305 0.92826E+00 -0.0323 46 FeO,aq 0.85008E-10 -10.0705 0.85008E-10 -10.0705 0.10000E+01 0.0000 47 FeOH+ 0.56747E-10 -10.2461 0.52676E-10 -10.2784 0.92826E+00 -0.0323 48 HFeO2- 0.13330E-08 -8.8752 0.12371E-08 -8.9076 0.92802E+00 -0.0324 49 FeO+ 0.65868E-14 -14.1813 0.61142E-14 -14.2137 0.92826E+00 -0.0323 51 FeO2- 0.23702E-08 -8.6252 0.21996E-08 -8.6577 0.92802E+00 -0.0324 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.43973E-09 -9.3568 0.43956E-09 -9.3570 0.99962E+00 -0.0002 54 KCl,aq 0.10771E-09 -9.9677 0.10771E-09 -9.9677 0.10000E+01 0.0000 55 KHSO4,aq 0.18785E-17 -17.7262 0.18785E-17 -17.7262 0.10000E+01 0.0000 56 KOH,aq 0.28028E-07 -7.5524 0.28028E-07 -7.5524 0.10000E+01 0.0000 57 KSO4- 0.15767E-07 -7.8023 0.14632E-07 -7.8347 0.92802E+00 -0.0324 58 MgCO3,aq 0.80238E-12 -12.0956 0.80238E-12 -12.0956 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.58014E-13 -13.2365 0.53852E-13 -13.2688 0.92826E+00 -0.0323 60 MgCl+ 0.39609E-13 -13.4022 0.36768E-13 -13.4345 0.92826E+00 -0.0323 61 MgOH+ 0.11305E-09 -9.9467 0.10494E-09 -9.9791 0.92826E+00 -0.0323 63 MnO,aq 0.30323E-09 -9.5182 0.30323E-09 -9.5182 0.10000E+01 0.0000 64 MnOH+ 0.70442E-09 -9.1522 0.65388E-09 -9.1845 0.92826E+00 -0.0323 65 MnO2-2 0.24494E-13 -13.6109 0.19196E-13 -13.7168 0.78369E+00 -0.1059 66 HMnO2- 0.33124E-11 -11.4799 0.30740E-11 -11.5123 0.92802E+00 -0.0324 69 MnCl+ 0.13098E-12 -12.8828 0.12158E-12 -12.9151 0.92826E+00 -0.0323 70 MnSO4,aq 0.88885E-12 -12.0512 0.88885E-12 -12.0512 0.10000E+01 0.0000 71 NaCl,aq 0.71599E-07 -7.1451 0.71599E-07 -7.1451 0.10000E+01 0.0000 72 NaOH,aq 0.10183E-05 -5.9921 0.10183E-05 -5.9921 0.10000E+01 0.0000 74 OH- 0.87469E-03 -3.0581 0.81154E-03 -3.0907 0.92780E+00 -0.0325 79 HPO3-2 0.11033E-16 -16.9573 0.86468E-17 -17.0631 0.78369E+00 -0.1059 81 H2PO3- 0.13528E-19 -19.8688 0.12554E-19 -19.9012 0.92802E+00 -0.0324 82 H3PO4,aq 0.21905E-13 -13.6595 0.21905E-13 -13.6595 0.10000E+01 0.0000 83 H2PO4- 0.86955E-07 -7.0607 0.80706E-07 -7.0931 0.92814E+00 -0.0324 84 PO4-3 0.12387E-07 -7.9070 0.73587E-08 -8.1332 0.59407E+00 -0.2262 87 H2P2O7-2 0.65048E-15 -15.1868 0.50977E-15 -15.2926 0.78369E+00 -0.1059 88 HP2O7-3 0.23958E-12 -12.6206 0.14142E-12 -12.8495 0.59030E+00 -0.2289 89 P2O7-4 0.11842E-12 -12.9266 0.47203E-13 -13.3260 0.39860E+00 -0.3995 90 H2S,aq 0.60914E-16 -16.2153 0.60891E-16 -16.2155 0.99962E+00 -0.0002 97 SO3-2 0.15255E-14 -14.8166 0.11978E-14 -14.9216 0.78517E+00 -0.1050 98 HSO3- 0.55830E-16 -16.2531 0.51812E-16 -16.2856 0.92802E+00 -0.0324 99 HSO4- 0.14764E-10 -10.8308 0.13707E-10 -10.8631 0.92837E+00 -0.0323 Charge balance for all species = 0.4598E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7958307E-09 -.1790227E-02 -.1804114E+01 0.0000 2 H2O 0.1000000E+01 0.5550839E+02 0.9998189E+06 0.0000 3 Cl- 0.1379386E-03 0.1380103E-03 0.4891991E+01 5.2385 4 SO4-- 0.2549529E-04 0.2551136E-04 0.2450217E+01 13.5633 5 HCO3- 0.1137254E-04 0.1307342E-04 0.7975588E+00 4.1548 6 HS- 0.2954470E-13 -.2117518E-09 -.7001784E-05 -4.4307 7 Al+++ 0.2458184E-24 0.3023408E-04 0.8156127E+00 2.5555 8 H4SiO4 0.5430641E-03 0.1335020E-02 0.1282927E+03 -3.2651 9 Ca++ 0.1523302E-07 0.1693879E-07 0.6787496E-03 10.3392 10 Mg++ 0.2536735E-09 0.3718971E-09 0.9039922E-05 8.5604 11 Fe++ 0.1500249E-11 0.4049961E-08 0.2261371E-03 6.3324 12 K+ 0.5119455E-04 0.5123845E-04 0.2003162E+01 4.8082 13 Na+ 0.1845843E-02 0.1866435E-02 0.4290119E+02 6.3650 14 Mn++ 0.2004467E-09 0.1212451E-08 0.6659752E-04 8.4583 15 HPO4-- 0.7944749E-05 0.8044092E-05 0.7719237E+00 13.0569 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2248998E-01 -.1789758E-02 -.2070022E-01 0.0000000E+00 2 H2O 0.5549121E+02 0.5549387E+02 -.2654880E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6316699E-04 0.2550468E-04 0.3766231E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3766252E-04 -.2116964E-09 -.3766231E-04 0.0000000E+00 7 Al+++ 0.4431348E-02 0.3022617E-04 0.4401122E-02 0.0000000E+00 8 H4SiO4 0.1415097E-01 0.1334671E-02 0.1281630E-01 0.0000000E+00 9 Ca++ 0.1577515E-02 0.1693436E-07 0.1577498E-02 0.0000000E+00 10 Mg++ 0.1078571E-02 0.3717998E-09 0.1078571E-02 0.0000000E+00 11 Fe++ 0.9689787E-03 0.4048901E-08 0.9689746E-03 0.0000000E+00 12 K+ 0.2885350E-03 0.5122504E-04 0.2373100E-03 0.0000000E+00 13 Na+ 0.1865947E-02 0.1865947E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2356315E-04 0.1212133E-08 0.2356194E-04 0.0000000E+00 15 HPO4-- 0.8041987E-05 0.8041987E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1355E-17 Mass of aqueous solution: 0.999920E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.3590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2157E-03 -3.666 0.1199 -0.921 8.336 0.4561E-01 daphnite 0.1335E-03 -3.874 0.9528E-01 -1.021 6.624 0.2887E-01 chlorite-Mn 0.4712E-05 -5.327 0.3341E-02 -2.476 0.2323 0.1065E-02 hematite 0.1506E-03 -3.822 0.2406E-01 -1.619 1.673 0.4560E-02 microcline 0.8686E-04 -4.061 0.2418E-01 -1.617 1.681 0.9444E-02 muscovite 0.1504E-03 -3.823 0.5992E-01 -1.222 4.166 0.2119E-01 stilbite 0.1577E-02 -2.802 1.112 0.046 77.29 0.5185 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.438375 g Volume = 0.629252 cm3 Porosity: 59.2348% V(tot) - V(min): 0.91435E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.3590000 g log = 0.1332 Original solution: 1000.0103000 g Original solution / Rock added: 735.84 (Water/Rock Ratio), log = 2.8668 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1699E-05 1.0073 0.1801E-05 0.1788E-05 CH4,gas 0.2109E-16 1.0129 0.2247E-16 0.2219E-16 H2,gas 0.5728E-06 1.0006 0.6029E-06 0.6025E-06 H2S,gas 0.1695E-14 0.9959 0.1776E-14 0.1783E-14 S2,gas 0.3090E-36 1.0000 0.3250E-36 0.3250E-36 CO,gas 0.2673E-15 1.0000 0.2812E-15 0.2812E-15 SO3,gas 0.3880E-38 1.0000 0.4082E-38 0.4082E-38 SO2,gas 0.8850E-22 1.0000 0.9310E-22 0.9310E-22 HCl,gas 0.2987E-16 1.0000 0.3142E-16 0.3142E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.54595E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.15165E-10 116 microcline -2.43 -2.43 0.00 0.000 0.18957E-10 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.11 -7.74 -2.582 0.13224E+05 -5.745 3 CH4,gas 4.81 -13.84 -18.65 -4.662 0.31842E+05 -16.648 4 H2,gas 8.29 0.07 -8.22 -4.697 0.14035E+05 -6.220 5 H2S,gas -5.94 -22.69 -16.75 -8.375 0.28601E+05 -14.751 6 S2,gas -7.03 -45.52 -38.49 -5.921 0.65717E+05 -36.488 7 CO,gas 3.51 -14.04 -17.55 -5.400 0.29968E+05 -15.551 8 SO3,gas 17.43 -22.96 -40.39 -10.097 0.68963E+05 -38.389 9 SO2,gas 1.14 -22.89 -24.03 -6.408 0.41032E+05 -22.031 10 HCl,gas 5.48 -13.02 -18.50 -9.251 0.31593E+05 -16.503 11 acmite 7.74 6.13 -1.60 -0.167 0.27385E+04 15 albite-high 0.75 -0.87 -1.62 -0.125 0.27739E+04 16 albite -0.33 -0.87 -0.55 -0.042 0.93325E+03 19 spessartine 24.55 20.69 -3.86 -0.193 0.65901E+04 20 analcite 3.37 2.39 -0.98 -0.109 0.16740E+04 21 andalusite 5.06 1.85 -3.22 -0.322 0.54921E+04 26 annite 20.21 16.57 -3.64 -0.202 0.62220E+04 27 phlogopite 27.15 23.25 -3.90 -0.217 0.66542E+04 29 anorthite 12.80 8.92 -3.88 -0.298 0.66212E+04 32 apatite-OH -17.99 -18.71 -0.72 -0.055 0.12292E+04 35 aragonite 0.99 -3.77 -4.75 -1.585 0.81187E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68575E+04 37 calcite 0.83 -3.77 -4.60 -1.534 0.78574E+04 38 carnegieite-low 9.06 5.66 -3.41 -0.487 0.58211E+04 39 carnegieite-high 10.13 5.66 -4.48 -0.640 0.76479E+04 40 carpholite-Mg 8.65 7.14 -1.51 -0.101 0.25770E+04 41 carpholite-Fe 6.78 4.91 -1.87 -0.125 0.31927E+04 42 celadonite 5.40 2.86 -2.54 -0.149 0.43319E+04 43 celadonite-Fe 3.94 0.64 -3.30 -0.194 0.56372E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81726E+04 50 chloritoid-Mg 13.26 10.41 -2.85 -0.190 0.48748E+04 51 chloritoid-Fe 9.24 8.18 -1.06 -0.071 0.18107E+04 52 chloritoid-Mn 11.46 10.30 -1.16 -0.077 0.19791E+04 54 coesite -2.37 -3.27 -0.90 -0.299 0.15296E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.27 -0.72 -0.239 0.12224E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.37 -3.85 -0.385 0.65672E+04 68 hedenbergite 14.24 10.14 -4.10 -0.410 0.70060E+04 75 epidote 24.78 22.29 -2.48 -0.120 0.42387E+04 76 clinozoisite 22.92 18.55 -4.37 -0.199 0.74646E+04 77 epidote-Fe 29.94 26.04 -3.90 -0.203 0.66604E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79899E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.47 -3.73 -0.311 0.63644E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.39 -1.86 -0.186 0.31771E+04 97 kalsilite 7.62 4.10 -3.52 -0.503 0.60133E+04 98 kaolinite -1.27 -1.42 -0.15 -0.013 0.24958E+03 99 kyanite 4.93 1.85 -3.09 -0.309 0.52689E+04 101 laumontite 2.97 2.39 -0.58 -0.039 0.99879E+03 102 lawsonite 9.68 8.92 -0.76 -0.051 0.12951E+04 103 leucite 4.17 0.83 -3.33 -0.333 0.56932E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70629E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20537E+04 108 minnesotaite 10.46 5.94 -4.52 -0.266 0.77249E+04 113 margarite 17.45 14.03 -3.42 -0.137 0.58411E+04 121 paragonite 4.34 4.24 -0.10 -0.006 0.17171E+03 122 nepheline 8.38 5.66 -2.72 -0.389 0.46490E+04 134 phlogopite-Na 29.73 24.81 -4.93 -0.274 0.84093E+04 136 prehnite 19.47 15.99 -3.47 -0.204 0.59290E+04 137 prehnite-Fe 22.59 19.74 -2.85 -0.171 0.48655E+04 145 pyroxmangite 7.42 5.19 -2.22 -0.445 0.37956E+04 146 pyrophyllite -6.10 -7.95 -1.85 -0.116 0.31615E+04 147 quartz -2.98 -3.27 -0.28 -0.094 0.48347E+03 151 rhodochrosite -0.96 -5.65 -4.69 -1.564 0.80097E+04 152 rhodonite 7.46 5.19 -2.27 -0.454 0.38748E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.85 -3.48 -0.348 0.59343E+04 164 stilpnomelane-Fe 13.18 13.06 -0.12 -0.004 0.21102E+03 165 stilpnomelane-Mg 27.60 24.20 -3.40 -0.102 0.58058E+04 168 sudoite 21.22 17.55 -3.67 -0.118 0.62644E+04 171 talc 16.55 12.62 -3.93 -0.231 0.67150E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76179E+04 177 topaz-H 4.67 1.85 -2.82 -0.257 0.48180E+04 178 tridymite -2.61 -3.27 -0.65 -0.217 0.11108E+04 187 wairakite 4.06 2.39 -1.67 -0.098 0.28496E+04 188 walstromite 11.53 7.07 -4.45 -0.891 0.76048E+04 189 wollastonite 10.48 7.07 -3.41 -0.682 0.58187E+04 190 pseudo-wollastonite 11.02 7.07 -3.95 -0.789 0.67373E+04 191 zoisite 22.96 18.55 -4.41 -0.201 0.75371E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.32 -2.76 -0.171 0.47180E+04 194 beidellite-H -2.24 -6.03 -3.79 -0.242 0.64674E+04 195 beidellite-K -1.44 -4.44 -3.01 -0.184 0.51345E+04 196 beidellite-Mg -1.71 -4.62 -2.91 -0.180 0.49678E+04 197 beidellite-Na -1.26 -3.93 -2.67 -0.164 0.45612E+04 199 chalcedony -2.79 -3.27 -0.47 -0.157 0.80379E+03 201 montmorillonite-Ca -2.21 -4.26 -2.05 -0.127 0.34969E+04 202 montmorillonite-K -2.16 -4.38 -2.22 -0.136 0.37911E+04 203 montmorillonite-Mg -2.40 -4.56 -2.15 -0.133 0.36777E+04 204 montmorillonite-Na -1.96 -3.87 -1.91 -0.117 0.32560E+04 205 nontronite-Ca 3.28 3.16 -0.12 -0.008 0.19781E+03 206 nontronite-H 2.60 1.46 -1.14 -0.076 0.19429E+04 207 nontronite-K 3.40 3.04 -0.36 -0.023 0.61348E+03 208 nontronite-Mg 3.14 2.87 -0.27 -0.017 0.45922E+03 209 nontronite-Na 3.58 3.56 -0.02 -0.002 0.41875E+02 224 tobermorite 9.84 5.35 -4.49 -1.226 0.76693E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59622E+04 240 silica-amorphous -2.08 -3.27 -1.19 -0.395 0.20240E+04 242 an20ab80 2.08 1.08 -1.00 -0.077 0.16992E+04 243 an25ab75 2.71 1.57 -1.14 -0.087 0.19386E+04 244 an30ab70 3.34 2.06 -1.28 -0.098 0.21864E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.3590000 g New total amount of reactant added: 1.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4569E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.3990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1265189E-02 Osmotic coef. = 0.9796 True ionic strength = .1979201E-02 Chg. balance for total moles = 0.4569E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.77854E-09 -9.1087 0.72262E-09 -9.1411 0.92817E+00 -0.0324 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12793E-03 -3.8930 0.92742E+00 -0.0327 4 SO4-- 0.25496E-04 -4.5935 0.19936E-04 -4.7004 0.78191E+00 -0.1068 5 HCO3- 0.11337E-04 -4.9455 0.10516E-04 -4.9782 0.92760E+00 -0.0326 6 HS- 0.27683E-13 -13.5578 0.25674E-13 -13.5905 0.92744E+00 -0.0327 7 Al+++ 0.23104E-24 -24.6363 0.13559E-24 -24.8678 0.58687E+00 -0.2315 8 H4SiO4 0.54768E-03 -3.2615 0.54768E-03 -3.2615 0.10000E+01 0.0000 9 Ca++ 0.13757E-07 -7.8615 0.10747E-07 -7.9687 0.78116E+00 -0.1073 10 Mg++ 0.24186E-09 -9.6164 0.18882E-09 -9.7240 0.78068E+00 -0.1075 11 Fe++ 0.14304E-11 -11.8445 0.11168E-11 -11.9520 0.78080E+00 -0.1075 12 K+ 0.48827E-04 -4.3113 0.45293E-04 -4.3440 0.92764E+00 -0.0326 13 Na+ 0.18949E-02 -2.7224 0.17573E-02 -2.7551 0.92741E+00 -0.0327 14 Mn++ 0.19111E-09 -9.7187 0.14924E-09 -9.8261 0.78088E+00 -0.1074 15 HPO4-- 0.81805E-05 -5.0872 0.63965E-05 -5.1941 0.78193E+00 -0.1068 16 HSiO3- 0.79734E-03 -3.0984 0.73947E-03 -3.1311 0.92742E+00 -0.0327 17 Ca(HSiO3)+ 0.19194E-09 -9.7168 0.17805E-09 -9.7495 0.92766E+00 -0.0326 18 Mg(HSiO3)+ 0.41968E-11 -11.3771 0.38932E-11 -11.4097 0.92766E+00 -0.0326 19 NaHSiO3,aq 0.20639E-04 -4.6853 0.20639E-04 -4.6853 0.10000E+01 0.0000 20 AlO+ 0.36135E-13 -13.4421 0.33521E-13 -13.4747 0.92766E+00 -0.0326 21 AlOH+2 0.15537E-18 -18.8086 0.12134E-18 -18.9160 0.78098E+00 -0.1074 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.30936E-04 -4.5095 0.28683E-04 -4.5424 0.92720E+00 -0.0328 24 CH4,aq 0.13294E-19 -19.8763 0.13289E-19 -19.8765 0.99961E+00 -0.0002 29 CO,aq 0.17170E-18 -18.7652 0.17170E-18 -18.7652 0.10000E+01 0.0000 30 CO2,aq 0.15327E-07 -7.8145 0.15321E-07 -7.8147 0.99961E+00 -0.0002 31 CO3-2 0.17213E-05 -5.7641 0.13455E-05 -5.8711 0.78169E+00 -0.1070 32 CaCO3,aq 0.17710E-09 -9.7518 0.17710E-09 -9.7518 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.30696E-11 -11.5129 0.28476E-11 -11.5455 0.92766E+00 -0.0326 34 CaCl+ 0.23615E-11 -11.6268 0.21907E-11 -11.6594 0.92766E+00 -0.0326 35 CaCl2,aq 0.65253E-16 -16.1854 0.65253E-16 -16.1854 0.10000E+01 0.0000 36 CaOH+ 0.11304E-08 -8.9468 0.10487E-08 -8.9794 0.92766E+00 -0.0326 37 CaSO4,aq 0.66753E-10 -10.1755 0.66753E-10 -10.1755 0.10000E+01 0.0000 38 HCl,aq 0.17388E-13 -13.7597 0.17388E-13 -13.7597 0.10000E+01 0.0000 43 FeCl+ 0.23988E-15 -15.6200 0.22253E-15 -15.6526 0.92766E+00 -0.0326 46 FeO,aq 0.84577E-10 -10.0727 0.84577E-10 -10.0727 0.10000E+01 0.0000 47 FeOH+ 0.55234E-10 -10.2578 0.51238E-10 -10.2904 0.92766E+00 -0.0326 48 HFeO2- 0.13574E-08 -8.8673 0.12589E-08 -8.9000 0.92742E+00 -0.0327 49 FeO+ 0.64437E-14 -14.1909 0.59776E-14 -14.2235 0.92766E+00 -0.0326 51 FeO2- 0.24260E-08 -8.6151 0.22499E-08 -8.6478 0.92742E+00 -0.0327 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.43528E-09 -9.3612 0.43511E-09 -9.3614 0.99961E+00 -0.0002 54 KCl,aq 0.10260E-09 -9.9889 0.10260E-09 -9.9889 0.10000E+01 0.0000 55 KHSO4,aq 0.17461E-17 -17.7579 0.17461E-17 -17.7579 0.10000E+01 0.0000 56 KOH,aq 0.27325E-07 -7.5634 0.27325E-07 -7.5634 0.10000E+01 0.0000 57 KSO4- 0.15000E-07 -7.8239 0.13911E-07 -7.8566 0.92742E+00 -0.0327 58 MgCO3,aq 0.77752E-12 -12.1093 0.77752E-12 -12.1093 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.54996E-13 -13.2597 0.51018E-13 -13.2923 0.92766E+00 -0.0326 60 MgCl+ 0.37667E-13 -13.4240 0.34942E-13 -13.4566 0.92766E+00 -0.0326 61 MgOH+ 0.11003E-09 -9.9585 0.10207E-09 -9.9911 0.92766E+00 -0.0326 63 MnO,aq 0.30170E-09 -9.5204 0.30170E-09 -9.5204 0.10000E+01 0.0000 64 MnOH+ 0.68563E-09 -9.1639 0.63603E-09 -9.1965 0.92766E+00 -0.0326 65 MnO2-2 0.25561E-13 -13.5924 0.19981E-13 -13.6994 0.78169E+00 -0.1070 66 HMnO2- 0.33731E-11 -11.4720 0.31283E-11 -11.5047 0.92742E+00 -0.0327 69 MnCl+ 0.12456E-12 -12.9046 0.11554E-12 -12.9372 0.92766E+00 -0.0326 70 MnSO4,aq 0.84316E-12 -12.0741 0.84316E-12 -12.0741 0.10000E+01 0.0000 71 NaCl,aq 0.73406E-07 -7.1343 0.73406E-07 -7.1343 0.10000E+01 0.0000 72 NaOH,aq 0.10686E-05 -5.9712 0.10686E-05 -5.9712 0.10000E+01 0.0000 74 OH- 0.89526E-03 -3.0481 0.83008E-03 -3.0809 0.92720E+00 -0.0328 79 HPO3-2 0.11246E-16 -16.9490 0.87909E-17 -17.0560 0.78169E+00 -0.1070 81 H2PO3- 0.13455E-19 -19.8711 0.12478E-19 -19.9038 0.92742E+00 -0.0327 82 H3PO4,aq 0.21504E-13 -13.6675 0.21504E-13 -13.6675 0.10000E+01 0.0000 83 H2PO4- 0.87368E-07 -7.0586 0.81037E-07 -7.0913 0.92754E+00 -0.0327 84 PO4-3 0.13086E-07 -7.8832 0.77304E-08 -8.1118 0.59073E+00 -0.2286 87 H2P2O7-2 0.65751E-15 -15.1821 0.51397E-15 -15.2891 0.78169E+00 -0.1070 88 HP2O7-3 0.24850E-12 -12.6047 0.14585E-12 -12.8361 0.58691E+00 -0.2314 89 P2O7-4 0.12619E-12 -12.8990 0.49791E-13 -13.3028 0.39456E+00 -0.4039 90 H2S,aq 0.55764E-16 -16.2536 0.55742E-16 -16.2538 0.99961E+00 -0.0002 97 SO3-2 0.15101E-14 -14.8210 0.11827E-14 -14.9271 0.78320E+00 -0.1061 98 HSO3- 0.53931E-16 -16.2682 0.50017E-16 -16.3009 0.92742E+00 -0.0327 99 HSO4- 0.14407E-10 -10.8414 0.13367E-10 -10.8740 0.92778E+00 -0.0326 Charge balance for all species = 0.4597E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7785403E-09 -.1839749E-02 -.1854012E+01 0.0000 2 H2O 0.1000000E+01 0.5550839E+02 0.9998149E+06 0.0000 3 Cl- 0.1379378E-03 0.1380113E-03 0.4892007E+01 5.2481 4 SO4-- 0.2549625E-04 0.2551155E-04 0.2450226E+01 13.5818 5 HCO3- 0.1133670E-04 0.1307352E-04 0.7975614E+00 4.1629 6 HS- 0.2768268E-13 -.2198302E-09 -.7268875E-05 -4.4494 7 Al+++ 0.2310373E-24 0.3094490E-04 0.8347849E+00 2.5555 8 H4SiO4 0.5476816E-03 0.1365658E-02 0.1312365E+03 -3.2615 9 Ca++ 0.1375742E-07 0.1532907E-07 0.6142445E-03 10.3135 10 Mg++ 0.2418605E-09 0.3569605E-09 0.8676814E-05 8.5582 11 Fe++ 0.1430382E-11 0.4128105E-08 0.2304995E-03 6.3302 12 K+ 0.4882683E-04 0.4886926E-04 0.1910531E+01 4.7971 13 Na+ 0.1894891E-02 0.1916672E-02 0.4405574E+02 6.3859 14 Mn++ 0.1911118E-09 0.1182804E-08 0.6496882E-04 8.4561 15 HPO4-- 0.8180461E-05 0.8280916E-05 0.7946467E+00 13.0881 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2315232E-01 -.1839254E-02 -.2131307E-01 0.0000000E+00 2 H2O 0.5549071E+02 0.5549347E+02 -.2752957E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6427553E-04 0.2550469E-04 0.3877084E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3877106E-04 -.2197711E-09 -.3877084E-04 0.0000000E+00 7 Al+++ 0.4561778E-02 0.3093658E-04 0.4530841E-02 0.0000000E+00 8 H4SiO4 0.1456748E-01 0.1365291E-02 0.1320219E-01 0.0000000E+00 9 Ca++ 0.1623521E-02 0.1532495E-07 0.1623505E-02 0.0000000E+00 10 Mg++ 0.1110317E-02 0.3568645E-09 0.1110317E-02 0.0000000E+00 11 Fe++ 0.9974990E-03 0.4126995E-08 0.9974949E-03 0.0000000E+00 12 K+ 0.2970276E-03 0.4885612E-04 0.2481715E-03 0.0000000E+00 13 Na+ 0.1916157E-02 0.1916157E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2425670E-04 0.1182486E-08 0.2425551E-04 0.0000000E+00 15 HPO4-- 0.8278690E-05 0.8278690E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2643E-17 Mass of aqueous solution: 0.999917E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2221E-03 -3.654 0.1234 -0.909 8.332 0.4695E-01 daphnite 0.1375E-03 -3.862 0.9808E-01 -1.008 6.621 0.2972E-01 chlorite-Mn 0.4851E-05 -5.314 0.3439E-02 -2.464 0.2322 0.1096E-02 hematite 0.1551E-03 -3.809 0.2477E-01 -1.606 1.672 0.4694E-02 microcline 0.9472E-04 -4.024 0.2636E-01 -1.579 1.780 0.1030E-01 muscovite 0.1534E-03 -3.814 0.6112E-01 -1.214 4.126 0.2161E-01 stilbite 0.1624E-02 -2.790 1.144 0.058 77.24 0.5336 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.481321 g Volume = 0.648010 cm3 Porosity: 58.4503% V(tot) - V(min): 0.91159E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.3990000 g log = 0.1458 Original solution: 1000.0103000 g Original solution / Rock added: 714.80 (Water/Rock Ratio), log = 2.8542 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1655E-05 1.0073 0.1754E-05 0.1741E-05 CH4,gas 0.1972E-16 1.0129 0.2102E-16 0.2075E-16 H2,gas 0.5670E-06 1.0006 0.5968E-06 0.5965E-06 H2S,gas 0.1552E-14 0.9959 0.1626E-14 0.1632E-14 S2,gas 0.2642E-36 1.0000 0.2780E-36 0.2780E-36 CO,gas 0.2577E-15 1.0000 0.2711E-15 0.2711E-15 SO3,gas 0.3700E-38 1.0000 0.3892E-38 0.3892E-38 SO2,gas 0.8353E-22 1.0000 0.8786E-22 0.8786E-22 HCl,gas 0.2919E-16 1.0000 0.3070E-16 0.3070E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.12 -7.76 -2.585 0.13243E+05 -5.756 3 CH4,gas 4.81 -13.87 -18.68 -4.669 0.31891E+05 -16.677 4 H2,gas 8.29 0.06 -8.22 -4.700 0.14043E+05 -6.224 5 H2S,gas -5.94 -22.73 -16.79 -8.394 0.28667E+05 -14.789 6 S2,gas -7.03 -45.59 -38.56 -5.932 0.65833E+05 -36.556 7 CO,gas 3.51 -14.06 -17.57 -5.405 0.29995E+05 -15.567 8 SO3,gas 17.43 -22.98 -40.41 -10.102 0.68999E+05 -38.410 9 SO2,gas 1.14 -22.92 -24.06 -6.415 0.41075E+05 -22.056 10 HCl,gas 5.48 -13.03 -18.51 -9.256 0.31610E+05 -16.513 11 acmite 7.74 6.16 -1.58 -0.164 0.26903E+04 15 albite-high 0.75 -0.84 -1.59 -0.123 0.27193E+04 16 albite -0.33 -0.84 -0.51 -0.040 0.87869E+03 19 spessartine 24.55 20.69 -3.86 -0.193 0.65826E+04 20 analcite 3.37 2.42 -0.95 -0.106 0.16258E+04 21 andalusite 5.06 1.85 -3.21 -0.321 0.54859E+04 26 annite 20.21 16.56 -3.65 -0.203 0.62333E+04 27 phlogopite 27.15 23.24 -3.90 -0.217 0.66655E+04 29 anorthite 12.80 8.90 -3.90 -0.300 0.66526E+04 32 apatite-OH -17.99 -18.86 -0.87 -0.067 0.14900E+04 35 aragonite 0.99 -3.81 -4.79 -1.597 0.81822E+04 36 brucite 12.58 8.56 -4.02 -0.804 0.68613E+04 37 calcite 0.83 -3.81 -4.64 -1.546 0.79209E+04 38 carnegieite-low 9.06 5.68 -3.38 -0.484 0.57791E+04 39 carnegieite-high 10.13 5.68 -4.45 -0.636 0.76059E+04 40 carpholite-Mg 8.65 7.15 -1.50 -0.100 0.25682E+04 41 carpholite-Fe 6.78 4.92 -1.86 -0.124 0.31839E+04 42 celadonite 5.40 2.86 -2.54 -0.149 0.43294E+04 43 celadonite-Fe 3.94 0.64 -3.30 -0.194 0.56347E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81713E+04 50 chloritoid-Mg 13.26 10.41 -2.85 -0.190 0.48723E+04 51 chloritoid-Fe 9.24 8.18 -1.06 -0.071 0.18082E+04 52 chloritoid-Mn 11.46 10.31 -1.16 -0.077 0.19766E+04 54 coesite -2.37 -3.26 -0.89 -0.297 0.15233E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.26 -0.71 -0.237 0.12162E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.35 -3.87 -0.387 0.66023E+04 68 hedenbergite 14.24 10.12 -4.12 -0.412 0.70412E+04 75 epidote 24.78 22.25 -2.52 -0.122 0.43078E+04 76 clinozoisite 22.92 18.51 -4.41 -0.201 0.75337E+04 77 epidote-Fe 29.94 26.00 -3.94 -0.205 0.67294E+04 78 fayalite 14.08 9.40 -4.68 -0.669 0.79911E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.47 -3.73 -0.311 0.63631E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.42 -1.83 -0.183 0.31288E+04 97 kalsilite 7.62 4.09 -3.53 -0.504 0.60259E+04 98 kaolinite -1.27 -1.41 -0.14 -0.013 0.23702E+03 99 kyanite 4.93 1.85 -3.08 -0.308 0.52626E+04 101 laumontite 2.97 2.38 -0.60 -0.040 0.10176E+04 102 lawsonite 9.68 8.90 -0.78 -0.052 0.13265E+04 103 leucite 4.17 0.83 -3.34 -0.334 0.56995E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70616E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20575E+04 108 minnesotaite 10.46 5.94 -4.52 -0.266 0.77111E+04 113 margarite 17.45 14.01 -3.44 -0.138 0.58725E+04 121 paragonite 4.34 4.27 -0.07 -0.004 0.11716E+03 122 nepheline 8.38 5.68 -2.70 -0.385 0.46070E+04 134 phlogopite-Na 29.73 24.83 -4.90 -0.272 0.83661E+04 136 prehnite 19.47 15.95 -3.51 -0.207 0.59981E+04 137 prehnite-Fe 22.59 19.70 -2.89 -0.174 0.49345E+04 145 pyroxmangite 7.42 5.19 -2.22 -0.444 0.37931E+04 146 pyrophyllite -6.10 -7.93 -1.84 -0.115 0.31364E+04 147 quartz -2.98 -3.26 -0.28 -0.093 0.47719E+03 151 rhodochrosite -0.96 -5.66 -4.70 -1.568 0.80331E+04 152 rhodonite 7.46 5.19 -2.27 -0.454 0.38723E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.85 -3.47 -0.347 0.59280E+04 164 stilpnomelane-Fe 13.18 13.07 -0.11 -0.003 0.18904E+03 165 stilpnomelane-Mg 27.60 24.21 -3.39 -0.101 0.57839E+04 168 sudoite 21.22 17.55 -3.66 -0.118 0.62531E+04 171 talc 16.55 12.63 -3.92 -0.231 0.67011E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76192E+04 177 topaz-H 4.67 1.85 -2.82 -0.256 0.48117E+04 178 tridymite -2.61 -3.26 -0.65 -0.216 0.11045E+04 187 wairakite 4.06 2.38 -1.68 -0.099 0.28684E+04 188 walstromite 11.53 7.05 -4.48 -0.895 0.76425E+04 189 wollastonite 10.48 7.05 -3.43 -0.686 0.58563E+04 190 pseudo-wollastonite 11.02 7.05 -3.97 -0.794 0.67750E+04 191 zoisite 22.96 18.51 -4.45 -0.202 0.76062E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.31 -2.75 -0.170 0.47022E+04 194 beidellite-H -2.24 -6.02 -3.77 -0.241 0.64443E+04 195 beidellite-K -1.44 -4.43 -3.00 -0.184 0.51177E+04 196 beidellite-Mg -1.71 -4.60 -2.90 -0.179 0.49454E+04 197 beidellite-Na -1.26 -3.91 -2.65 -0.162 0.45264E+04 199 chalcedony -2.79 -3.26 -0.47 -0.156 0.79751E+03 201 montmorillonite-Ca -2.21 -4.25 -2.04 -0.126 0.34803E+04 202 montmorillonite-K -2.16 -4.37 -2.21 -0.135 0.37735E+04 203 montmorillonite-Mg -2.40 -4.54 -2.14 -0.132 0.36544E+04 204 montmorillonite-Na -1.96 -3.85 -1.89 -0.115 0.32203E+04 205 nontronite-Ca 3.28 3.17 -0.11 -0.007 0.18202E+03 206 nontronite-H 2.60 1.47 -1.12 -0.075 0.19199E+04 207 nontronite-K 3.40 3.05 -0.35 -0.022 0.59665E+03 208 nontronite-Mg 3.14 2.88 -0.26 -0.017 0.43680E+03 209 nontronite-Na 3.58 3.58 0.00 0.000 0.70443E+01 224 tobermorite 9.84 5.33 -4.51 -1.230 0.76996E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.874 0.59660E+04 240 silica-amorphous -2.08 -3.26 -1.18 -0.394 0.20177E+04 242 an20ab80 2.08 1.11 -0.97 -0.075 0.16619E+04 243 an25ab75 2.71 1.59 -1.12 -0.086 0.19056E+04 244 an30ab70 3.34 2.08 -1.26 -0.097 0.21576E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.3990000 g New total amount of reactant added: 1.4390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4569E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.4390000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1292832E-02 Osmotic coef. = 0.9794 True ionic strength = .2026245E-02 Chg. balance for total moles = 0.4569E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.76216E-09 -9.1180 0.70698E-09 -9.1506 0.92760E+00 -0.0326 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12784E-03 -3.8933 0.92683E+00 -0.0330 4 SO4-- 0.25497E-04 -4.5935 0.19886E-04 -4.7014 0.77994E+00 -0.1079 5 HCO3- 0.11301E-04 -4.9469 0.10476E-04 -4.9798 0.92701E+00 -0.0329 6 HS- 0.25947E-13 -13.5859 0.24049E-13 -13.6189 0.92685E+00 -0.0330 7 Al+++ 0.21759E-24 -24.6624 0.12697E-24 -24.8963 0.58353E+00 -0.2339 8 H4SiO4 0.55238E-03 -3.2578 0.55238E-03 -3.2578 0.10000E+01 0.0000 9 Ca++ 0.12435E-07 -7.9053 0.96892E-08 -8.0137 0.77918E+00 -0.1084 10 Mg++ 0.23091E-09 -9.6366 0.17981E-09 -9.7452 0.77869E+00 -0.1086 11 Fe++ 0.13656E-11 -11.8647 0.10635E-11 -11.9732 0.77881E+00 -0.1086 12 K+ 0.46590E-04 -4.3317 0.43191E-04 -4.3646 0.92705E+00 -0.0329 13 Na+ 0.19439E-02 -2.7113 0.18016E-02 -2.7443 0.92681E+00 -0.0330 14 Mn++ 0.18246E-09 -9.7388 0.14211E-09 -9.8474 0.77890E+00 -0.1085 15 HPO4-- 0.84162E-05 -5.0749 0.65643E-05 -5.1828 0.77996E+00 -0.1079 16 HSiO3- 0.82250E-03 -3.0849 0.76232E-03 -3.1179 0.92683E+00 -0.0330 17 Ca(HSiO3)+ 0.17851E-09 -9.7483 0.16549E-09 -9.7812 0.92707E+00 -0.0329 18 Mg(HSiO3)+ 0.41226E-11 -11.3848 0.38220E-11 -11.4177 0.92707E+00 -0.0329 19 NaHSiO3,aq 0.21813E-04 -4.6613 0.21813E-04 -4.6613 0.10000E+01 0.0000 20 AlO+ 0.35375E-13 -13.4513 0.32795E-13 -13.4842 0.92707E+00 -0.0329 21 AlOH+2 0.14910E-18 -18.8265 0.11615E-18 -18.9350 0.77900E+00 -0.1085 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.31640E-04 -4.4998 0.29318E-04 -4.5329 0.92660E+00 -0.0331 24 CH4,aq 0.12437E-19 -19.9053 0.12432E-19 -19.9055 0.99960E+00 -0.0002 29 CO,aq 0.16564E-18 -18.7808 0.16564E-18 -18.7808 0.10000E+01 0.0000 30 CO2,aq 0.14939E-07 -7.8257 0.14933E-07 -7.8258 0.99960E+00 -0.0002 31 CO3-2 0.17572E-05 -5.7552 0.13701E-05 -5.8632 0.77972E+00 -0.1081 32 CaCO3,aq 0.16259E-09 -9.7889 0.16259E-09 -9.7889 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.27589E-11 -11.5593 0.25577E-11 -11.5921 0.92707E+00 -0.0329 34 CaCl+ 0.21291E-11 -11.6718 0.19739E-11 -11.7047 0.92707E+00 -0.0329 35 CaCl2,aq 0.58756E-16 -16.2309 0.58756E-16 -16.2309 0.10000E+01 0.0000 36 CaOH+ 0.10424E-08 -8.9820 0.96639E-09 -9.0148 0.92707E+00 -0.0329 37 CaSO4,aq 0.60036E-10 -10.2216 0.60036E-10 -10.2216 0.10000E+01 0.0000 38 HCl,aq 0.17001E-13 -13.7695 0.17001E-13 -13.7695 0.10000E+01 0.0000 43 FeCl+ 0.22843E-15 -15.6412 0.21177E-15 -15.6741 0.92707E+00 -0.0329 46 FeO,aq 0.84145E-10 -10.0750 0.84145E-10 -10.0750 0.10000E+01 0.0000 47 FeOH+ 0.53796E-10 -10.2692 0.49873E-10 -10.3021 0.92707E+00 -0.0329 48 HFeO2- 0.13812E-08 -8.8597 0.12802E-08 -8.8927 0.92683E+00 -0.0330 49 FeO+ 0.63083E-14 -14.2001 0.58482E-14 -14.2330 0.92707E+00 -0.0329 51 FeO2- 0.24812E-08 -8.6053 0.22997E-08 -8.6383 0.92683E+00 -0.0330 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.43085E-09 -9.3657 0.43067E-09 -9.3659 0.99960E+00 -0.0002 54 KCl,aq 0.97772E-10 -10.0098 0.97772E-10 -10.0098 0.10000E+01 0.0000 55 KHSO4,aq 0.16250E-17 -17.7892 0.16250E-17 -17.7892 0.10000E+01 0.0000 56 KOH,aq 0.26633E-07 -7.5746 0.26633E-07 -7.5746 0.10000E+01 0.0000 57 KSO4- 0.14278E-07 -7.8453 0.13233E-07 -7.8783 0.92683E+00 -0.0330 58 MgCO3,aq 0.75396E-12 -12.1227 0.75396E-12 -12.1227 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.52208E-13 -13.2823 0.48401E-13 -13.3151 0.92707E+00 -0.0329 60 MgCl+ 0.35869E-13 -13.4453 0.33253E-13 -13.4782 0.92707E+00 -0.0329 61 MgOH+ 0.10717E-09 -9.9699 0.99353E-10 -10.0028 0.92707E+00 -0.0329 63 MnO,aq 0.30015E-09 -9.5227 0.30015E-09 -9.5227 0.10000E+01 0.0000 64 MnOH+ 0.66778E-09 -9.1754 0.61908E-09 -9.2083 0.92707E+00 -0.0329 65 MnO2-2 0.26636E-13 -13.5745 0.20768E-13 -13.6826 0.77972E+00 -0.1081 66 HMnO2- 0.34323E-11 -11.4644 0.31812E-11 -11.4974 0.92683E+00 -0.0330 69 MnCl+ 0.11861E-12 -12.9259 0.10996E-12 -12.9588 0.92707E+00 -0.0329 70 MnSO4,aq 0.80094E-12 -12.0964 0.80094E-12 -12.0964 0.10000E+01 0.0000 71 NaCl,aq 0.75208E-07 -7.1237 0.75208E-07 -7.1237 0.10000E+01 0.0000 72 NaOH,aq 0.11198E-05 -5.9509 0.11198E-05 -5.9509 0.10000E+01 0.0000 74 OH- 0.91566E-03 -3.0383 0.84845E-03 -3.0714 0.92660E+00 -0.0331 79 HPO3-2 0.11452E-16 -16.9411 0.89294E-17 -17.0492 0.77972E+00 -0.1081 81 H2PO3- 0.13380E-19 -19.8736 0.12401E-19 -19.9066 0.92683E+00 -0.0330 82 H3PO4,aq 0.21123E-13 -13.6753 0.21123E-13 -13.6753 0.10000E+01 0.0000 83 H2PO4- 0.87775E-07 -7.0566 0.81363E-07 -7.0896 0.92695E+00 -0.0329 84 PO4-3 0.13803E-07 -7.8600 0.81087E-08 -8.0911 0.58746E+00 -0.2310 87 H2P2O7-2 0.66448E-15 -15.1775 0.51810E-15 -15.2856 0.77972E+00 -0.1081 88 HP2O7-3 0.25750E-12 -12.5892 0.15027E-12 -12.8231 0.58357E+00 -0.2339 89 P2O7-4 0.13424E-12 -12.8721 0.52437E-13 -13.2804 0.39061E+00 -0.4083 90 H2S,aq 0.51105E-16 -16.2915 0.51084E-16 -16.2917 0.99960E+00 -0.0002 97 SO3-2 0.14947E-14 -14.8254 0.11678E-14 -14.9326 0.78126E+00 -0.1072 98 HSO3- 0.52129E-16 -16.2829 0.48315E-16 -16.3159 0.92683E+00 -0.0330 99 HSO4- 0.14069E-10 -10.8517 0.13045E-10 -10.8846 0.92719E+00 -0.0328 Charge balance for all species = 0.4598E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7621624E-09 -.1889385E-02 -.1904026E+01 0.0000 2 H2O 0.1000000E+01 0.5550839E+02 0.9998108E+06 0.0000 3 Cl- 0.1379370E-03 0.1380123E-03 0.4892023E+01 5.2573 4 SO4-- 0.2549716E-04 0.2551174E-04 0.2450235E+01 13.5997 5 HCO3- 0.1130130E-04 0.1307361E-04 0.7975640E+00 4.1708 6 HS- 0.2594714E-13 -.2278481E-09 -.7533966E-05 -4.4683 7 Al+++ 0.2175949E-24 0.3164968E-04 0.8537940E+00 2.5555 8 H4SiO4 0.5523821E-03 0.1396693E-02 0.1342182E+03 -3.2578 9 Ca++ 0.1243520E-07 0.1388363E-07 0.5563229E-03 10.2875 10 Mg++ 0.2309084E-09 0.3430417E-09 0.8338451E-05 8.5560 11 Fe++ 0.1365606E-11 0.4205242E-08 0.2348057E-03 6.3279 12 K+ 0.4659037E-04 0.4663138E-04 0.1823035E+01 4.7860 13 Na+ 0.1943901E-02 0.1966910E-02 0.4521029E+02 6.4063 14 Mn++ 0.1824572E-09 0.1154772E-08 0.6342887E-04 8.4538 15 HPO4-- 0.8416166E-05 0.8517744E-05 0.8173697E+00 13.1184 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2381466E-01 -.1888863E-02 -.2192580E-01 0.0000000E+00 2 H2O 0.5549021E+02 0.5549306E+02 -.2850233E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6538407E-04 0.2550470E-04 0.3987937E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3987960E-04 -.2277852E-09 -.3987937E-04 0.0000000E+00 7 Al+++ 0.4692207E-02 0.3164094E-04 0.4660566E-02 0.0000000E+00 8 H4SiO4 0.1498399E-01 0.1396307E-02 0.1358769E-01 0.0000000E+00 9 Ca++ 0.1669526E-02 0.1387980E-07 0.1669512E-02 0.0000000E+00 10 Mg++ 0.1142063E-02 0.3429470E-09 0.1142063E-02 0.0000000E+00 11 Fe++ 0.1026019E-02 0.4204081E-08 0.1026015E-02 0.0000000E+00 12 K+ 0.3055202E-03 0.4661851E-04 0.2589017E-03 0.0000000E+00 13 Na+ 0.1966367E-02 0.1966367E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2495024E-04 0.1154453E-08 0.2494909E-04 0.0000000E+00 15 HPO4-- 0.8515393E-05 0.8515393E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4987E-17 Mass of aqueous solution: 0.999913E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.4390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2284E-03 -3.641 0.1270 -0.896 8.329 0.4829E-01 daphnite 0.1414E-03 -3.850 0.1009 -0.996 6.619 0.3057E-01 chlorite-Mn 0.4990E-05 -5.302 0.3538E-02 -2.451 0.2321 0.1127E-02 hematite 0.1595E-03 -3.797 0.2547E-01 -1.594 1.671 0.4828E-02 microcline 0.1024E-03 -3.990 0.2850E-01 -1.545 1.870 0.1113E-01 muscovite 0.1565E-03 -3.805 0.6234E-01 -1.205 4.090 0.2205E-01 stilbite 0.1670E-02 -2.777 1.177 0.071 77.19 0.5488 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.524238 g Volume = 0.666755 cm3 Porosity: 57.6825% V(tot) - V(min): 0.90885E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.4390000 g log = 0.1581 Original solution: 1000.0103000 g Original solution / Rock added: 694.93 (Water/Rock Ratio), log = 2.8419 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1613E-05 1.0073 0.1709E-05 0.1697E-05 CH4,gas 0.1845E-16 1.0129 0.1966E-16 0.1941E-16 H2,gas 0.5612E-06 1.0006 0.5907E-06 0.5904E-06 H2S,gas 0.1422E-14 0.9959 0.1490E-14 0.1496E-14 S2,gas 0.2265E-36 1.0000 0.2383E-36 0.2383E-36 CO,gas 0.2486E-15 1.0000 0.2616E-15 0.2616E-15 SO3,gas 0.3532E-38 1.0000 0.3716E-38 0.3716E-38 SO2,gas 0.7894E-22 1.0000 0.8304E-22 0.8304E-22 HCl,gas 0.2854E-16 1.0000 0.3002E-16 0.3002E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 120 muscovite 2.68 2.68 0.00 0.000 0.30331E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 209 nontronite-Na 3.58 3.60 0.02 0.001 -0.27660E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.13 -7.77 -2.589 0.13262E+05 -5.767 3 CH4,gas 4.81 -13.90 -18.71 -4.677 0.31941E+05 -16.706 4 H2,gas 8.29 0.06 -8.23 -4.702 0.14050E+05 -6.229 5 H2S,gas -5.94 -22.77 -16.83 -8.413 0.28731E+05 -14.827 6 S2,gas -7.03 -45.66 -38.62 -5.942 0.65948E+05 -36.623 7 CO,gas 3.51 -14.07 -17.58 -5.410 0.30022E+05 -15.582 8 SO3,gas 17.43 -23.00 -40.43 -10.107 0.69033E+05 -38.430 9 SO2,gas 1.14 -22.94 -24.08 -6.422 0.41117E+05 -22.081 10 HCl,gas 5.48 -13.04 -18.52 -9.261 0.31627E+05 -16.523 11 acmite 7.74 6.19 -1.55 -0.161 0.26429E+04 15 albite-high 0.75 -0.81 -1.56 -0.120 0.26656E+04 16 albite -0.33 -0.81 -0.48 -0.037 0.82499E+03 19 spessartine 24.55 20.70 -3.85 -0.193 0.65750E+04 20 analcite 3.37 2.45 -0.92 -0.103 0.15784E+04 21 andalusite 5.06 1.85 -3.21 -0.321 0.54795E+04 26 annite 20.21 16.55 -3.66 -0.203 0.62447E+04 27 phlogopite 27.15 23.24 -3.91 -0.217 0.66769E+04 29 anorthite 12.80 8.88 -3.91 -0.301 0.66843E+04 32 apatite-OH -17.99 -19.01 -1.03 -0.079 0.17516E+04 35 aragonite 0.99 -3.84 -4.83 -1.610 0.82456E+04 36 brucite 12.58 8.56 -4.02 -0.804 0.68651E+04 37 calcite 0.83 -3.84 -4.68 -1.559 0.79843E+04 38 carnegieite-low 9.06 5.70 -3.36 -0.480 0.57381E+04 39 carnegieite-high 10.13 5.70 -4.43 -0.633 0.75649E+04 40 carpholite-Mg 8.65 7.15 -1.50 -0.100 0.25594E+04 41 carpholite-Fe 6.78 4.92 -1.86 -0.124 0.31750E+04 42 celadonite 5.40 2.87 -2.53 -0.149 0.43268E+04 43 celadonite-Fe 3.94 0.64 -3.30 -0.194 0.56322E+04 44 chrysotile 23.94 19.15 -4.78 -0.399 0.81700E+04 50 chloritoid-Mg 13.26 10.41 -2.85 -0.190 0.48697E+04 51 chloritoid-Fe 9.24 8.18 -1.06 -0.070 0.18057E+04 52 chloritoid-Mn 11.46 10.31 -1.16 -0.077 0.19741E+04 54 coesite -2.37 -3.26 -0.89 -0.296 0.15169E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.26 -0.71 -0.236 0.12098E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.33 -3.89 -0.389 0.66378E+04 68 hedenbergite 14.24 10.10 -4.14 -0.414 0.70766E+04 75 epidote 24.78 22.21 -2.56 -0.124 0.43775E+04 76 clinozoisite 22.92 18.47 -4.45 -0.202 0.76034E+04 77 epidote-Fe 29.94 25.95 -3.98 -0.207 0.67991E+04 78 fayalite 14.08 9.40 -4.68 -0.669 0.79924E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.47 -3.73 -0.310 0.63619E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.45 -1.80 -0.180 0.30814E+04 97 kalsilite 7.62 4.08 -3.54 -0.505 0.60385E+04 98 kaolinite -1.27 -1.40 -0.13 -0.012 0.22434E+03 99 kyanite 4.93 1.85 -3.08 -0.308 0.52563E+04 101 laumontite 2.97 2.37 -0.61 -0.040 0.10366E+04 102 lawsonite 9.68 8.88 -0.80 -0.053 0.13582E+04 103 leucite 4.17 0.83 -3.34 -0.334 0.57058E+04 105 lizardite 23.29 19.15 -4.13 -0.345 0.70603E+04 107 magnetite 20.13 18.93 -1.21 -0.099 0.20613E+04 108 minnesotaite 10.46 5.95 -4.51 -0.265 0.76972E+04 113 margarite 17.45 13.99 -3.46 -0.138 0.59042E+04 121 paragonite 4.34 4.30 -0.04 -0.002 0.63457E+02 122 nepheline 8.38 5.70 -2.67 -0.382 0.45660E+04 134 phlogopite-Na 29.73 24.86 -4.87 -0.271 0.83238E+04 136 prehnite 19.47 15.91 -3.55 -0.209 0.60678E+04 137 prehnite-Fe 22.59 19.66 -2.93 -0.176 0.50042E+04 145 pyroxmangite 7.42 5.20 -2.22 -0.444 0.37905E+04 146 pyrophyllite -6.10 -7.92 -1.82 -0.114 0.31111E+04 147 quartz -2.98 -3.26 -0.28 -0.092 0.47086E+03 151 rhodochrosite -0.96 -5.68 -4.72 -1.573 0.80559E+04 152 rhodonite 7.46 5.20 -2.27 -0.453 0.38698E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.85 -3.47 -0.347 0.59217E+04 164 stilpnomelane-Fe 13.18 13.08 -0.10 -0.003 0.16686E+03 165 stilpnomelane-Mg 27.60 24.22 -3.37 -0.101 0.57617E+04 168 sudoite 21.22 17.56 -3.66 -0.118 0.62417E+04 171 talc 16.55 12.64 -3.92 -0.230 0.66872E+04 174 tephroite 18.11 13.65 -4.46 -0.638 0.76205E+04 177 topaz-H 4.67 1.85 -2.81 -0.256 0.48054E+04 178 tridymite -2.61 -3.26 -0.64 -0.214 0.10981E+04 187 wairakite 4.06 2.37 -1.69 -0.099 0.28875E+04 188 walstromite 11.53 7.03 -4.50 -0.900 0.76805E+04 189 wollastonite 10.48 7.03 -3.45 -0.690 0.58944E+04 190 pseudo-wollastonite 11.02 7.03 -3.99 -0.798 0.68130E+04 191 zoisite 22.96 18.47 -4.50 -0.204 0.76759E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.30 -2.74 -0.170 0.46863E+04 194 beidellite-H -2.24 -6.00 -3.76 -0.240 0.64211E+04 195 beidellite-K -1.44 -4.42 -2.99 -0.183 0.51007E+04 196 beidellite-Mg -1.71 -4.59 -2.88 -0.178 0.49227E+04 197 beidellite-Na -1.26 -3.89 -2.63 -0.161 0.44917E+04 199 chalcedony -2.79 -3.26 -0.46 -0.154 0.79117E+03 201 montmorillonite-Ca -2.21 -4.24 -2.03 -0.125 0.34635E+04 202 montmorillonite-K -2.16 -4.36 -2.20 -0.135 0.37556E+04 203 montmorillonite-Mg -2.40 -4.53 -2.13 -0.132 0.36310E+04 204 montmorillonite-Na -1.96 -3.83 -1.87 -0.114 0.31848E+04 205 nontronite-Ca 3.28 3.18 -0.10 -0.006 0.16609E+03 206 nontronite-H 2.60 1.48 -1.11 -0.074 0.18966E+04 207 nontronite-K 3.40 3.06 -0.34 -0.022 0.57967E+03 208 nontronite-Mg 3.14 2.90 -0.24 -0.016 0.41417E+03 224 tobermorite 9.84 5.31 -4.53 -1.235 0.77302E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.33 -3.50 -0.874 0.59698E+04 240 silica-amorphous -2.08 -3.26 -1.18 -0.393 0.20114E+04 242 an20ab80 2.08 1.13 -0.95 -0.073 0.16252E+04 243 an25ab75 2.71 1.61 -1.10 -0.084 0.18732E+04 244 an30ab70 3.34 2.10 -1.25 -0.096 0.21295E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.4390000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1293527E-02 Osmotic coef. = 0.9794 True ionic strength = .2026358E-02 Chg. balance for total moles = 0.4569E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.75840E-09 -9.1201 0.70349E-09 -9.1527 0.92759E+00 -0.0326 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12784E-03 -3.8933 0.92683E+00 -0.0330 4 SO4-- 0.25497E-04 -4.5935 0.19886E-04 -4.7015 0.77994E+00 -0.1079 5 HCO3- 0.11294E-04 -4.9472 0.10470E-04 -4.9801 0.92701E+00 -0.0329 6 HS- 0.27160E-13 -13.5661 0.25174E-13 -13.5991 0.92685E+00 -0.0330 7 Al+++ 0.21439E-24 -24.6688 0.12510E-24 -24.9027 0.58352E+00 -0.2339 8 H4SiO4 0.54658E-03 -3.2623 0.54658E-03 -3.2623 0.10000E+01 0.0000 9 Ca++ 0.13257E-07 -7.8776 0.10330E-07 -7.9859 0.77917E+00 -0.1084 10 Mg++ 0.23009E-09 -9.6381 0.17917E-09 -9.7467 0.77869E+00 -0.1086 11 Fe++ 0.13608E-11 -11.8662 0.10598E-11 -11.9748 0.77880E+00 -0.1086 12 K+ 0.47852E-04 -4.3201 0.44361E-04 -4.3530 0.92705E+00 -0.0329 13 Na+ 0.19427E-02 -2.7116 0.18006E-02 -2.7446 0.92681E+00 -0.0330 14 Mn++ 0.18181E-09 -9.7404 0.14161E-09 -9.8489 0.77889E+00 -0.1085 15 HPO4-- 0.84165E-05 -5.0749 0.65645E-05 -5.1828 0.77995E+00 -0.1079 16 HSiO3- 0.81790E-03 -3.0873 0.75805E-03 -3.1203 0.92683E+00 -0.0330 17 Ca(HSiO3)+ 0.18924E-09 -9.7230 0.17544E-09 -9.7559 0.92707E+00 -0.0329 18 Mg(HSiO3)+ 0.40850E-11 -11.3888 0.37871E-11 -11.4217 0.92707E+00 -0.0329 19 NaHSiO3,aq 0.21678E-04 -4.6640 0.21678E-04 -4.6640 0.10000E+01 0.0000 20 AlO+ 0.35201E-13 -13.4534 0.32634E-13 -13.4863 0.92707E+00 -0.0329 21 AlOH+2 0.14763E-18 -18.8308 0.11500E-18 -18.9393 0.77899E+00 -0.1085 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.31797E-04 -4.4976 0.29463E-04 -4.5307 0.92660E+00 -0.0331 24 CH4,aq 0.13010E-19 -19.8857 0.13005E-19 -19.8859 0.99960E+00 -0.0002 29 CO,aq 0.16682E-18 -18.7778 0.16682E-18 -18.7778 0.10000E+01 0.0000 30 CO2,aq 0.14856E-07 -7.8281 0.14850E-07 -7.8283 0.99960E+00 -0.0002 31 CO3-2 0.17648E-05 -5.7533 0.13760E-05 -5.8614 0.77971E+00 -0.1081 32 CaCO3,aq 0.17408E-09 -9.7592 0.17408E-09 -9.7592 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.29393E-11 -11.5318 0.27249E-11 -11.5646 0.92707E+00 -0.0329 34 CaCl+ 0.22698E-11 -11.6440 0.21043E-11 -11.6769 0.92707E+00 -0.0329 35 CaCl2,aq 0.62639E-16 -16.2032 0.62639E-16 -16.2032 0.10000E+01 0.0000 36 CaOH+ 0.11168E-08 -8.9520 0.10354E-08 -8.9849 0.92707E+00 -0.0329 37 CaSO4,aq 0.64002E-10 -10.1938 0.64002E-10 -10.1938 0.10000E+01 0.0000 38 HCl,aq 0.16917E-13 -13.7717 0.16917E-13 -13.7717 0.10000E+01 0.0000 43 FeCl+ 0.22762E-15 -15.6428 0.21102E-15 -15.6757 0.92707E+00 -0.0329 46 FeO,aq 0.84679E-10 -10.0722 0.84679E-10 -10.0722 0.10000E+01 0.0000 47 FeOH+ 0.53871E-10 -10.2686 0.49942E-10 -10.3015 0.92707E+00 -0.0329 48 HFeO2- 0.13969E-08 -8.8548 0.12947E-08 -8.8878 0.92683E+00 -0.0330 49 FeO+ 0.62771E-14 -14.2022 0.58194E-14 -14.2351 0.92707E+00 -0.0329 51 FeO2- 0.24935E-08 -8.6032 0.23111E-08 -8.6362 0.92683E+00 -0.0330 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.43634E-09 -9.3602 0.43616E-09 -9.3604 0.99960E+00 -0.0002 54 KCl,aq 0.10042E-09 -9.9982 0.10042E-09 -9.9982 0.10000E+01 0.0000 55 KHSO4,aq 0.16607E-17 -17.7797 0.16607E-17 -17.7797 0.10000E+01 0.0000 56 KOH,aq 0.27490E-07 -7.5608 0.27490E-07 -7.5608 0.10000E+01 0.0000 57 KSO4- 0.14664E-07 -7.8338 0.13591E-07 -7.8668 0.92683E+00 -0.0330 58 MgCO3,aq 0.75450E-12 -12.1223 0.75450E-12 -12.1223 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.51989E-13 -13.2841 0.48197E-13 -13.3170 0.92707E+00 -0.0329 60 MgCl+ 0.35742E-13 -13.4468 0.33135E-13 -13.4797 0.92707E+00 -0.0329 61 MgOH+ 0.10732E-09 -9.9693 0.99491E-10 -10.0022 0.92707E+00 -0.0329 63 MnO,aq 0.30206E-09 -9.5199 0.30206E-09 -9.5199 0.10000E+01 0.0000 64 MnOH+ 0.66871E-09 -9.1748 0.61994E-09 -9.2076 0.92707E+00 -0.0329 65 MnO2-2 0.27071E-13 -13.5675 0.21108E-13 -13.6756 0.77971E+00 -0.1081 66 HMnO2- 0.34713E-11 -11.4595 0.32173E-11 -11.4925 0.92683E+00 -0.0330 69 MnCl+ 0.11819E-12 -12.9274 0.10957E-12 -12.9603 0.92707E+00 -0.0329 70 MnSO4,aq 0.79808E-12 -12.0980 0.79808E-12 -12.0980 0.10000E+01 0.0000 71 NaCl,aq 0.75163E-07 -7.1240 0.75163E-07 -7.1240 0.10000E+01 0.0000 72 NaOH,aq 0.11246E-05 -5.9490 0.11246E-05 -5.9490 0.10000E+01 0.0000 74 OH- 0.92020E-03 -3.0361 0.85266E-03 -3.0692 0.92660E+00 -0.0331 79 HPO3-2 0.11599E-16 -16.9356 0.90435E-17 -17.0437 0.77971E+00 -0.1081 81 H2PO3- 0.13484E-19 -19.8702 0.12497E-19 -19.9032 0.92683E+00 -0.0330 82 H3PO4,aq 0.20915E-13 -13.6795 0.20915E-13 -13.6795 0.10000E+01 0.0000 83 H2PO4- 0.87345E-07 -7.0588 0.80964E-07 -7.0917 0.92695E+00 -0.0329 84 PO4-3 0.13872E-07 -7.8579 0.81492E-08 -8.0889 0.58745E+00 -0.2310 87 H2P2O7-2 0.65799E-15 -15.1818 0.51304E-15 -15.2898 0.77971E+00 -0.1081 88 HP2O7-3 0.25626E-12 -12.5913 0.14954E-12 -12.8252 0.58357E+00 -0.2339 89 P2O7-4 0.13426E-12 -12.8721 0.52441E-13 -13.2803 0.39061E+00 -0.4083 90 H2S,aq 0.53230E-16 -16.2738 0.53209E-16 -16.2740 0.99960E+00 -0.0002 97 SO3-2 0.15137E-14 -14.8199 0.11826E-14 -14.9272 0.78126E+00 -0.1072 98 HSO3- 0.52532E-16 -16.2796 0.48688E-16 -16.3126 0.92683E+00 -0.0330 99 HSO4- 0.14000E-10 -10.8539 0.12980E-10 -10.8867 0.92719E+00 -0.0328 Charge balance for all species = 0.4570E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7584041E-09 -.1889831E-02 -.1904477E+01 0.0000 2 H2O 0.1000000E+01 0.5550840E+02 0.9998118E+06 0.0000 3 Cl- 0.1379370E-03 0.1380123E-03 0.4892026E+01 5.2594 4 SO4-- 0.2549677E-04 0.2551174E-04 0.2450236E+01 13.6040 5 HCO3- 0.1129382E-04 0.1307361E-04 0.7975645E+00 4.1727 6 HS- 0.2716036E-13 -.2280118E-09 -.7539385E-05 -4.4463 7 Al+++ 0.2143938E-24 0.3180656E-04 0.8580269E+00 2.5555 8 H4SiO4 0.5465826E-03 0.1386158E-02 0.1332060E+03 -3.2623 9 Ca++ 0.1325706E-07 0.1480639E-07 0.5932986E-03 10.3196 10 Mg++ 0.2300900E-09 0.3423349E-09 0.8321276E-05 8.5587 11 Fe++ 0.1360766E-11 0.4233816E-08 0.2364013E-03 6.3307 12 K+ 0.4785207E-04 0.4789432E-04 0.1872411E+01 4.7997 13 Na+ 0.1942743E-02 0.1965621E-02 0.4518071E+02 6.4081 14 Mn++ 0.1818105E-09 0.1156997E-08 0.6355111E-04 8.4566 15 HPO4-- 0.8416525E-05 0.8517743E-05 0.8173703E+00 13.1227 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2381466E-01 -.1889310E-02 -.2192535E-01 0.0000000E+00 2 H2O 0.5549021E+02 0.5549308E+02 -.2867712E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6538407E-04 0.2550470E-04 0.3987937E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3987960E-04 -.2279489E-09 -.3987937E-04 0.0000000E+00 7 Al+++ 0.4692207E-02 0.3179779E-04 0.4660409E-02 0.0000000E+00 8 H4SiO4 0.1498399E-01 0.1385776E-02 0.1359822E-01 0.0000000E+00 9 Ca++ 0.1669526E-02 0.1480230E-07 0.1669512E-02 0.0000000E+00 10 Mg++ 0.1142063E-02 0.3422404E-09 0.1142063E-02 0.0000000E+00 11 Fe++ 0.1026019E-02 0.4232648E-08 0.1026015E-02 0.0000000E+00 12 K+ 0.3055202E-03 0.4788111E-04 0.2576391E-03 0.0000000E+00 13 Na+ 0.1966367E-02 0.1965078E-02 0.1288135E-05 0.0000000E+00 14 Mn++ 0.2495024E-04 0.1156678E-08 0.2494908E-04 0.0000000E+00 15 HPO4-- 0.8515393E-05 0.8515393E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.3429E-17 Mass of aqueous solution: 0.999913E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.4390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2284E-03 -3.641 0.1270 -0.896 8.326 0.4829E-01 daphnite 0.1414E-03 -3.850 0.1009 -0.996 6.616 0.3057E-01 chlorite-Mn 0.4990E-05 -5.302 0.3538E-02 -2.451 0.2320 0.1127E-02 hematite 0.1556E-03 -3.808 0.2485E-01 -1.605 1.630 0.4710E-02 microcline 0.1012E-03 -3.995 0.2817E-01 -1.550 1.847 0.1100E-01 muscovite 0.1564E-03 -3.806 0.6231E-01 -1.205 4.086 0.2203E-01 stilbite 0.1670E-02 -2.777 1.177 0.071 77.15 0.5488 nontronite-Na 0.3903E-05 -5.409 0.1660E-02 -2.780 0.1089 0.5157E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.524912 g Volume = 0.667012 cm3 Porosity: 57.6662% V(tot) - V(min): 0.90859E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.4390000 g log = 0.1581 Original solution: 1000.0103000 g Original solution / Rock added: 694.93 (Water/Rock Ratio), log = 2.8419 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1604E-05 1.0073 0.1700E-05 0.1687E-05 CH4,gas 0.1930E-16 1.0129 0.2057E-16 0.2030E-16 H2,gas 0.5684E-06 1.0006 0.5982E-06 0.5979E-06 H2S,gas 0.1481E-14 0.9959 0.1552E-14 0.1558E-14 S2,gas 0.2396E-36 1.0000 0.2520E-36 0.2520E-36 CO,gas 0.2504E-15 1.0000 0.2634E-15 0.2634E-15 SO3,gas 0.3498E-38 1.0000 0.3679E-38 0.3679E-38 SO2,gas 0.7916E-22 1.0000 0.8327E-22 0.8327E-22 HCl,gas 0.2840E-16 1.0000 0.2987E-16 0.2987E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 0.30331E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.13 -7.77 -2.590 0.13266E+05 -5.770 3 CH4,gas 4.81 -13.88 -18.69 -4.672 0.31907E+05 -16.687 4 H2,gas 8.29 0.06 -8.22 -4.699 0.14041E+05 -6.223 5 H2S,gas -5.94 -22.75 -16.81 -8.405 0.28701E+05 -14.809 6 S2,gas -7.03 -45.63 -38.60 -5.938 0.65906E+05 -36.599 7 CO,gas 3.51 -14.07 -17.58 -5.409 0.30016E+05 -15.579 8 SO3,gas 17.43 -23.01 -40.43 -10.109 0.69040E+05 -38.434 9 SO2,gas 1.14 -22.94 -24.08 -6.421 0.41115E+05 -22.080 10 HCl,gas 5.48 -13.05 -18.52 -9.262 0.31631E+05 -16.525 11 acmite 7.74 6.18 -1.56 -0.162 0.26553E+04 15 albite-high 0.75 -0.82 -1.57 -0.121 0.26859E+04 16 albite -0.33 -0.82 -0.50 -0.038 0.84525E+03 19 spessartine 24.55 20.69 -3.86 -0.193 0.65844E+04 20 analcite 3.37 2.44 -0.93 -0.104 0.15908E+04 21 andalusite 5.06 1.85 -3.21 -0.321 0.54874E+04 26 annite 20.21 16.56 -3.65 -0.203 0.62306E+04 27 phlogopite 27.15 23.24 -3.90 -0.217 0.66628E+04 29 anorthite 12.80 8.91 -3.89 -0.299 0.66452E+04 32 apatite-OH -17.99 -18.87 -0.88 -0.068 0.14996E+04 35 aragonite 0.99 -3.81 -4.80 -1.600 0.81950E+04 36 brucite 12.58 8.56 -4.02 -0.804 0.68604E+04 37 calcite 0.83 -3.81 -4.65 -1.549 0.79336E+04 38 carnegieite-low 9.06 5.70 -3.36 -0.480 0.57427E+04 39 carnegieite-high 10.13 5.70 -4.43 -0.633 0.75695E+04 40 carpholite-Mg 8.65 7.15 -1.51 -0.100 0.25703E+04 41 carpholite-Fe 6.78 4.92 -1.87 -0.124 0.31860E+04 42 celadonite 5.40 2.86 -2.54 -0.149 0.43300E+04 43 celadonite-Fe 3.94 0.64 -3.30 -0.194 0.56353E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81716E+04 50 chloritoid-Mg 13.26 10.41 -2.85 -0.190 0.48729E+04 51 chloritoid-Fe 9.24 8.18 -1.06 -0.071 0.18088E+04 52 chloritoid-Mn 11.46 10.31 -1.16 -0.077 0.19772E+04 54 coesite -2.37 -3.26 -0.89 -0.298 0.15248E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.26 -0.71 -0.238 0.12177E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.35 -3.86 -0.386 0.65940E+04 68 hedenbergite 14.24 10.13 -4.12 -0.412 0.70328E+04 75 epidote 24.78 22.26 -2.51 -0.122 0.42914E+04 76 clinozoisite 22.92 18.52 -4.40 -0.200 0.75173E+04 77 epidote-Fe 29.94 26.01 -3.93 -0.204 0.67130E+04 78 fayalite 14.08 9.40 -4.68 -0.669 0.79908E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.47 -3.73 -0.311 0.63634E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.44 -1.81 -0.181 0.30939E+04 97 kalsilite 7.62 4.09 -3.53 -0.504 0.60229E+04 98 kaolinite -1.27 -1.41 -0.14 -0.013 0.24000E+03 99 kyanite 4.93 1.85 -3.08 -0.308 0.52641E+04 101 laumontite 2.97 2.38 -0.59 -0.040 0.10132E+04 102 lawsonite 9.68 8.91 -0.77 -0.052 0.13190E+04 103 leucite 4.17 0.83 -3.34 -0.334 0.56980E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70619E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20566E+04 108 minnesotaite 10.46 5.94 -4.52 -0.266 0.77144E+04 113 margarite 17.45 14.02 -3.43 -0.137 0.58651E+04 121 paragonite 4.34 4.29 -0.05 -0.003 0.83713E+02 122 nepheline 8.38 5.70 -2.68 -0.382 0.45706E+04 134 phlogopite-Na 29.73 24.85 -4.88 -0.271 0.83300E+04 136 prehnite 19.47 15.96 -3.50 -0.206 0.59817E+04 137 prehnite-Fe 22.59 19.71 -2.88 -0.173 0.49181E+04 145 pyroxmangite 7.42 5.19 -2.22 -0.444 0.37937E+04 146 pyrophyllite -6.10 -7.94 -1.84 -0.115 0.31424E+04 147 quartz -2.98 -3.26 -0.28 -0.093 0.47868E+03 151 rhodochrosite -0.96 -5.68 -4.72 -1.573 0.80553E+04 152 rhodonite 7.46 5.19 -2.27 -0.454 0.38729E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.85 -3.47 -0.347 0.59295E+04 164 stilpnomelane-Fe 13.18 13.07 -0.11 -0.003 0.19426E+03 165 stilpnomelane-Mg 27.60 24.21 -3.39 -0.101 0.57891E+04 168 sudoite 21.22 17.55 -3.66 -0.118 0.62558E+04 171 talc 16.55 12.63 -3.93 -0.231 0.67044E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76189E+04 177 topaz-H 4.67 1.85 -2.82 -0.256 0.48132E+04 178 tridymite -2.61 -3.26 -0.65 -0.216 0.11060E+04 187 wairakite 4.06 2.38 -1.68 -0.099 0.28640E+04 188 walstromite 11.53 7.06 -4.47 -0.894 0.76335E+04 189 wollastonite 10.48 7.06 -3.42 -0.685 0.58474E+04 190 pseudo-wollastonite 11.02 7.06 -3.96 -0.793 0.67660E+04 191 zoisite 22.96 18.52 -4.45 -0.202 0.75898E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.32 -2.76 -0.170 0.47060E+04 194 beidellite-H -2.24 -6.02 -3.78 -0.241 0.64498E+04 195 beidellite-K -1.44 -4.43 -3.00 -0.184 0.51217E+04 196 beidellite-Mg -1.71 -4.61 -2.90 -0.179 0.49507E+04 197 beidellite-Na -1.26 -3.90 -2.65 -0.162 0.45193E+04 199 chalcedony -2.79 -3.26 -0.47 -0.156 0.79900E+03 201 montmorillonite-Ca -2.21 -4.25 -2.04 -0.126 0.34842E+04 202 montmorillonite-K -2.16 -4.37 -2.21 -0.135 0.37777E+04 203 montmorillonite-Mg -2.40 -4.55 -2.14 -0.133 0.36600E+04 204 montmorillonite-Na -1.96 -3.84 -1.88 -0.115 0.32135E+04 205 nontronite-Ca 3.28 3.17 -0.11 -0.007 0.18577E+03 206 nontronite-H 2.60 1.47 -1.13 -0.076 0.19254E+04 207 nontronite-K 3.40 3.05 -0.35 -0.023 0.60064E+03 208 nontronite-Mg 3.14 2.88 -0.26 -0.017 0.44211E+03 224 tobermorite 9.84 5.33 -4.51 -1.229 0.76924E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59651E+04 240 silica-amorphous -2.08 -3.26 -1.18 -0.394 0.20192E+04 242 an20ab80 2.08 1.12 -0.96 -0.074 0.16336E+04 243 an25ab75 2.71 1.61 -1.10 -0.085 0.18786E+04 244 an30ab70 3.34 2.10 -1.25 -0.096 0.21320E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.4390000 g New total amount of reactant added: 1.4790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4569E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.4790000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1322063E-02 Osmotic coef. = 0.9792 True ionic strength = .2073555E-02 Chg. balance for total moles = 0.4569E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.73840E-09 -9.1317 0.68451E-09 -9.1646 0.92702E+00 -0.0329 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12776E-03 -3.8936 0.92624E+00 -0.0333 4 SO4-- 0.25497E-04 -4.5935 0.19837E-04 -4.7025 0.77800E+00 -0.1090 5 HCO3- 0.11249E-04 -4.9489 0.10422E-04 -4.9821 0.92643E+00 -0.0332 6 HS- 0.26965E-13 -13.5692 0.24976E-13 -13.6025 0.92626E+00 -0.0333 7 Al+++ 0.19862E-24 -24.7020 0.11525E-24 -24.9384 0.58023E+00 -0.2364 8 H4SiO4 0.54409E-03 -3.2643 0.54409E-03 -3.2643 0.10000E+01 0.0000 9 Ca++ 0.12993E-07 -7.8863 0.10098E-07 -7.9958 0.77722E+00 -0.1095 10 Mg++ 0.21899E-09 -9.6596 0.17010E-09 -9.7693 0.77672E+00 -0.1097 11 Fe++ 0.12951E-11 -11.8877 0.10061E-11 -11.9974 0.77684E+00 -0.1097 12 K+ 0.47234E-04 -4.3257 0.43761E-04 -4.3589 0.92646E+00 -0.0332 13 Na+ 0.19903E-02 -2.7011 0.18434E-02 -2.7344 0.92623E+00 -0.0333 14 Mn++ 0.17304E-09 -9.7618 0.13444E-09 -9.8715 0.77693E+00 -0.1096 15 HPO4-- 0.86527E-05 -5.0629 0.67319E-05 -5.1719 0.77801E+00 -0.1090 16 HSiO3- 0.83727E-03 -3.0771 0.77551E-03 -3.1104 0.92624E+00 -0.0333 17 Ca(HSiO3)+ 0.18938E-09 -9.7227 0.17546E-09 -9.7558 0.92649E+00 -0.0332 18 Mg(HSiO3)+ 0.39700E-11 -11.4012 0.36782E-11 -11.4344 0.92649E+00 -0.0332 19 NaHSiO3,aq 0.22706E-04 -4.6439 0.22706E-04 -4.6439 0.10000E+01 0.0000 20 AlO+ 0.34272E-13 -13.4651 0.31753E-13 -13.4982 0.92649E+00 -0.0332 21 AlOH+2 0.14012E-18 -18.8535 0.10888E-18 -18.9630 0.77703E+00 -0.1096 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.32700E-04 -4.4855 0.30280E-04 -4.5188 0.92601E+00 -0.0334 24 CH4,aq 0.12881E-19 -19.8900 0.12876E-19 -19.8902 0.99959E+00 -0.0002 29 CO,aq 0.16246E-18 -18.7892 0.16246E-18 -18.7892 0.10000E+01 0.0000 30 CO2,aq 0.14389E-07 -7.8420 0.14383E-07 -7.8422 0.99959E+00 -0.0002 31 CO3-2 0.18099E-05 -5.7423 0.14077E-05 -5.8515 0.77777E+00 -0.1092 32 CaCO3,aq 0.17410E-09 -9.7592 0.17410E-09 -9.7592 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.28621E-11 -11.5433 0.26517E-11 -11.5765 0.92649E+00 -0.0332 34 CaCl+ 0.22189E-11 -11.6539 0.20558E-11 -11.6870 0.92649E+00 -0.0332 35 CaCl2,aq 0.61157E-16 -16.2136 0.61157E-16 -16.2136 0.10000E+01 0.0000 36 CaOH+ 0.11227E-08 -8.9497 0.10402E-08 -8.9829 0.92649E+00 -0.0332 37 CaSO4,aq 0.62412E-10 -10.2047 0.62412E-10 -10.2047 0.10000E+01 0.0000 38 HCl,aq 0.16450E-13 -13.7838 0.16450E-13 -13.7838 0.10000E+01 0.0000 43 FeCl+ 0.21609E-15 -15.6654 0.20021E-15 -15.6985 0.92649E+00 -0.0332 46 FeO,aq 0.84912E-10 -10.0710 0.84912E-10 -10.0710 0.10000E+01 0.0000 47 FeOH+ 0.52595E-10 -10.2791 0.48728E-10 -10.3122 0.92649E+00 -0.0332 48 HFeO2- 0.14405E-08 -8.8415 0.13343E-08 -8.8748 0.92624E+00 -0.0333 49 FeO+ 0.61116E-14 -14.2138 0.56624E-14 -14.2470 0.92649E+00 -0.0332 51 FeO2- 0.25643E-08 -8.5910 0.23751E-08 -8.6243 0.92624E+00 -0.0333 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.43874E-09 -9.3578 0.43856E-09 -9.3580 0.99959E+00 -0.0002 54 KCl,aq 0.98997E-10 -10.0044 0.98997E-10 -10.0044 0.10000E+01 0.0000 55 KHSO4,aq 0.15901E-17 -17.7986 0.15901E-17 -17.7986 0.10000E+01 0.0000 56 KOH,aq 0.27870E-07 -7.5549 0.27870E-07 -7.5549 0.10000E+01 0.0000 57 KSO4- 0.14439E-07 -7.8405 0.13374E-07 -7.8737 0.92624E+00 -0.0333 58 MgCO3,aq 0.73280E-12 -12.1350 0.73280E-12 -12.1350 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.49162E-13 -13.3084 0.45548E-13 -13.3415 0.92649E+00 -0.0332 60 MgCl+ 0.33932E-13 -13.4694 0.31438E-13 -13.5025 0.92649E+00 -0.0332 61 MgOH+ 0.10477E-09 -9.9797 0.97073E-10 -10.0129 0.92649E+00 -0.0332 63 MnO,aq 0.30289E-09 -9.5187 0.30289E-09 -9.5187 0.10000E+01 0.0000 64 MnOH+ 0.65287E-09 -9.1852 0.60488E-09 -9.2183 0.92649E+00 -0.0332 65 MnO2-2 0.28744E-13 -13.5415 0.22356E-13 -13.6506 0.77777E+00 -0.1092 66 HMnO2- 0.35796E-11 -11.4462 0.33156E-11 -11.4794 0.92624E+00 -0.0333 69 MnCl+ 0.11220E-12 -12.9500 0.10396E-12 -12.9831 0.92649E+00 -0.0332 70 MnSO4,aq 0.75580E-12 -12.1216 0.75580E-12 -12.1216 0.10000E+01 0.0000 71 NaCl,aq 0.76904E-07 -7.1140 0.76904E-07 -7.1140 0.10000E+01 0.0000 72 NaOH,aq 0.11834E-05 -5.9269 0.11834E-05 -5.9269 0.10000E+01 0.0000 74 OH- 0.94632E-03 -3.0240 0.87630E-03 -3.0573 0.92601E+00 -0.0334 79 HPO3-2 0.11990E-16 -16.9212 0.93252E-17 -17.0303 0.77777E+00 -0.1092 81 H2PO3- 0.13537E-19 -19.8685 0.12539E-19 -19.9017 0.92624E+00 -0.0333 82 H3PO4,aq 0.20307E-13 -13.6924 0.20307E-13 -13.6924 0.10000E+01 0.0000 83 H2PO4- 0.87210E-07 -7.0594 0.80788E-07 -7.0927 0.92637E+00 -0.0332 84 PO4-3 0.14701E-07 -7.8327 0.85887E-08 -8.0661 0.58423E+00 -0.2334 87 H2P2O7-2 0.65677E-15 -15.1826 0.51082E-15 -15.2917 0.77777E+00 -0.1092 88 HP2O7-3 0.26370E-12 -12.5789 0.15302E-12 -12.8152 0.58028E+00 -0.2364 89 P2O7-4 0.14260E-12 -12.8459 0.55149E-13 -13.2585 0.38674E+00 -0.4126 90 H2S,aq 0.51389E-16 -16.2891 0.51368E-16 -16.2893 0.99959E+00 -0.0002 97 SO3-2 0.15221E-14 -14.8176 0.11862E-14 -14.9258 0.77934E+00 -0.1083 98 HSO3- 0.51301E-16 -16.2899 0.47518E-16 -16.3231 0.92624E+00 -0.0333 99 HSO4- 0.13597E-10 -10.8666 0.12599E-10 -10.8997 0.92661E+00 -0.0331 Charge balance for all species = 0.4604E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7383958E-09 -.1940065E-02 -.1955095E+01 0.0000 2 H2O 0.1000000E+01 0.5550840E+02 0.9998090E+06 0.0000 3 Cl- 0.1379362E-03 0.1380132E-03 0.4892046E+01 5.2710 4 SO4-- 0.2549717E-04 0.2551192E-04 0.2450247E+01 13.6267 5 HCO3- 0.1124922E-04 0.1307370E-04 0.7975677E+00 4.1826 6 HS- 0.2696467E-13 -.2362558E-09 -.7811954E-05 -4.4379 7 Al+++ 0.1986229E-24 0.3270910E-04 0.8823716E+00 2.5555 8 H4SiO4 0.5440872E-03 0.1404061E-02 0.1349261E+03 -3.2643 9 Ca++ 0.1299251E-07 0.1454622E-07 0.5828718E-03 10.3335 10 Mg++ 0.2189933E-09 0.3285541E-09 0.7986278E-05 8.5599 11 Fe++ 0.1295135E-11 0.4347062E-08 0.2427239E-03 6.3319 12 K+ 0.4723421E-04 0.4727662E-04 0.1848256E+01 4.8057 13 Na+ 0.1990274E-02 0.2014240E-02 0.4629811E+02 6.4302 14 Mn++ 0.1730416E-09 0.1133278E-08 0.6224811E-04 8.4578 15 HPO4-- 0.8652661E-05 0.8754573E-05 0.8400942E+00 13.1574 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2447700E-01 -.1939516E-02 -.2253749E-01 0.0000000E+00 2 H2O 0.5548971E+02 0.5549270E+02 -.2986743E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6649260E-04 0.2550471E-04 0.4098790E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4098813E-04 -.2361889E-09 -.4098790E-04 0.0000000E+00 7 Al+++ 0.4822637E-02 0.3269985E-04 0.4789937E-02 0.0000000E+00 8 H4SiO4 0.1540051E-01 0.1403664E-02 0.1399684E-01 0.0000000E+00 9 Ca++ 0.1715532E-02 0.1454211E-07 0.1715518E-02 0.0000000E+00 10 Mg++ 0.1173810E-02 0.3284612E-09 0.1173809E-02 0.0000000E+00 11 Fe++ 0.1054540E-02 0.4345832E-08 0.1054535E-02 0.0000000E+00 12 K+ 0.3140127E-03 0.4726324E-04 0.2667495E-03 0.0000000E+00 13 Na+ 0.2016576E-02 0.2013670E-02 0.2906217E-05 0.0000000E+00 14 Mn++ 0.2564378E-04 0.1132958E-08 0.2564265E-04 0.0000000E+00 15 HPO4-- 0.8752096E-05 0.8752096E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.7928E-18 Mass of aqueous solution: 0.999909E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.4790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2348E-03 -3.629 0.1305 -0.884 8.318 0.4963E-01 daphnite 0.1453E-03 -3.838 0.1037 -0.984 6.610 0.3142E-01 chlorite-Mn 0.5129E-05 -5.290 0.3636E-02 -2.439 0.2318 0.1159E-02 hematite 0.1551E-03 -3.809 0.2478E-01 -1.606 1.579 0.4696E-02 microcline 0.1073E-03 -3.969 0.2988E-01 -1.525 1.905 0.1167E-01 muscovite 0.1594E-03 -3.797 0.6349E-01 -1.197 4.048 0.2245E-01 stilbite 0.1716E-02 -2.766 1.209 0.082 77.07 0.5639 nontronite-Na 0.8807E-05 -5.055 0.3745E-02 -2.427 0.2387 0.1163E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.568668 g Volume = 0.686077 cm3 Porosity: 56.8939% V(tot) - V(min): 0.90552E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.4790000 g log = 0.1700 Original solution: 1000.0103000 g Original solution / Rock added: 676.14 (Water/Rock Ratio), log = 2.8300 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1554E-05 1.0073 0.1646E-05 0.1634E-05 CH4,gas 0.1911E-16 1.0129 0.2036E-16 0.2010E-16 H2,gas 0.5715E-06 1.0006 0.6015E-06 0.6012E-06 H2S,gas 0.1430E-14 0.9959 0.1498E-14 0.1504E-14 S2,gas 0.2209E-36 1.0000 0.2323E-36 0.2323E-36 CO,gas 0.2439E-15 1.0000 0.2565E-15 0.2565E-15 SO3,gas 0.3303E-38 1.0000 0.3475E-38 0.3475E-38 SO2,gas 0.7517E-22 1.0000 0.7907E-22 0.7907E-22 HCl,gas 0.2761E-16 1.0000 0.2905E-16 0.2905E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 0.21990E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.15 -7.78 -2.594 0.13290E+05 -5.783 3 CH4,gas 4.81 -13.88 -18.69 -4.673 0.31915E+05 -16.691 4 H2,gas 8.29 0.07 -8.22 -4.698 0.14037E+05 -6.221 5 H2S,gas -5.94 -22.77 -16.82 -8.412 0.28727E+05 -14.824 6 S2,gas -7.03 -45.67 -38.63 -5.944 0.65966E+05 -36.634 7 CO,gas 3.51 -14.08 -17.59 -5.413 0.30036E+05 -15.591 8 SO3,gas 17.43 -23.03 -40.46 -10.115 0.69083E+05 -38.459 9 SO2,gas 1.14 -22.97 -24.10 -6.427 0.41153E+05 -22.102 10 HCl,gas 5.48 -13.06 -18.54 -9.268 0.31651E+05 -16.537 11 acmite 7.74 6.20 -1.54 -0.160 0.26244E+04 15 albite-high 0.75 -0.81 -1.56 -0.120 0.26583E+04 16 albite -0.33 -0.81 -0.48 -0.037 0.81769E+03 19 spessartine 24.55 20.69 -3.86 -0.193 0.65884E+04 20 analcite 3.37 2.46 -0.91 -0.102 0.15599E+04 21 andalusite 5.06 1.85 -3.22 -0.322 0.54907E+04 26 annite 20.21 16.56 -3.65 -0.203 0.62245E+04 27 phlogopite 27.15 23.25 -3.90 -0.217 0.66567E+04 29 anorthite 12.80 8.92 -3.88 -0.299 0.66282E+04 32 apatite-OH -17.99 -18.84 -0.85 -0.065 0.14465E+04 35 aragonite 0.99 -3.81 -4.80 -1.600 0.81949E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68583E+04 37 calcite 0.83 -3.81 -4.65 -1.549 0.79336E+04 38 carnegieite-low 9.06 5.72 -3.34 -0.478 0.57083E+04 39 carnegieite-high 10.13 5.72 -4.41 -0.630 0.75352E+04 40 carpholite-Mg 8.65 7.14 -1.51 -0.101 0.25751E+04 41 carpholite-Fe 6.78 4.91 -1.87 -0.125 0.31907E+04 42 celadonite 5.40 2.86 -2.54 -0.149 0.43313E+04 43 celadonite-Fe 3.94 0.64 -3.30 -0.194 0.56367E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81723E+04 50 chloritoid-Mg 13.26 10.41 -2.85 -0.190 0.48742E+04 51 chloritoid-Fe 9.24 8.18 -1.06 -0.071 0.18101E+04 52 chloritoid-Mn 11.46 10.30 -1.16 -0.077 0.19786E+04 54 coesite -2.37 -3.26 -0.89 -0.298 0.15282E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.26 -0.72 -0.238 0.12210E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.36 -3.85 -0.385 0.65750E+04 68 hedenbergite 14.24 10.14 -4.11 -0.411 0.70138E+04 75 epidote 24.78 22.28 -2.49 -0.121 0.42541E+04 76 clinozoisite 22.92 18.54 -4.38 -0.199 0.74799E+04 77 epidote-Fe 29.94 26.03 -3.91 -0.203 0.66757E+04 78 fayalite 14.08 9.40 -4.68 -0.669 0.79901E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.47 -3.73 -0.311 0.63641E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.46 -1.79 -0.179 0.30629E+04 97 kalsilite 7.62 4.10 -3.52 -0.503 0.60161E+04 98 kaolinite -1.27 -1.42 -0.14 -0.013 0.24678E+03 99 kyanite 4.93 1.85 -3.08 -0.308 0.52675E+04 101 laumontite 2.97 2.39 -0.59 -0.039 0.10030E+04 102 lawsonite 9.68 8.92 -0.76 -0.051 0.13021E+04 103 leucite 4.17 0.83 -3.34 -0.334 0.56946E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70626E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20546E+04 108 minnesotaite 10.46 5.94 -4.52 -0.266 0.77219E+04 113 margarite 17.45 14.03 -3.43 -0.137 0.58481E+04 121 paragonite 4.34 4.30 -0.03 -0.002 0.56156E+02 122 nepheline 8.38 5.72 -2.66 -0.380 0.45363E+04 134 phlogopite-Na 29.73 24.87 -4.86 -0.270 0.82963E+04 136 prehnite 19.47 15.98 -3.48 -0.205 0.59444E+04 137 prehnite-Fe 22.59 19.73 -2.86 -0.172 0.48808E+04 145 pyroxmangite 7.42 5.19 -2.22 -0.445 0.37950E+04 146 pyrophyllite -6.10 -7.95 -1.85 -0.116 0.31559E+04 147 quartz -2.98 -3.26 -0.28 -0.094 0.48208E+03 151 rhodochrosite -0.96 -5.69 -4.73 -1.577 0.80770E+04 152 rhodonite 7.46 5.19 -2.27 -0.454 0.38742E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.85 -3.47 -0.347 0.59329E+04 164 stilpnomelane-Fe 13.18 13.06 -0.12 -0.004 0.20613E+03 165 stilpnomelane-Mg 27.60 24.20 -3.40 -0.101 0.58010E+04 168 sudoite 21.22 17.55 -3.67 -0.118 0.62619E+04 171 talc 16.55 12.62 -3.93 -0.231 0.67119E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76182E+04 177 topaz-H 4.67 1.85 -2.82 -0.256 0.48166E+04 178 tridymite -2.61 -3.26 -0.65 -0.217 0.11094E+04 187 wairakite 4.06 2.39 -1.67 -0.098 0.28538E+04 188 walstromite 11.53 7.07 -4.46 -0.892 0.76132E+04 189 wollastonite 10.48 7.07 -3.41 -0.683 0.58270E+04 190 pseudo-wollastonite 11.02 7.07 -3.95 -0.790 0.67457E+04 191 zoisite 22.96 18.54 -4.42 -0.201 0.75525E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.32 -2.76 -0.171 0.47145E+04 194 beidellite-H -2.24 -6.03 -3.78 -0.242 0.64622E+04 195 beidellite-K -1.44 -4.44 -3.00 -0.184 0.51308E+04 196 beidellite-Mg -1.71 -4.61 -2.91 -0.180 0.49628E+04 197 beidellite-Na -1.26 -3.90 -2.65 -0.162 0.45193E+04 199 chalcedony -2.79 -3.26 -0.47 -0.157 0.80239E+03 201 montmorillonite-Ca -2.21 -4.26 -2.05 -0.127 0.34932E+04 202 montmorillonite-K -2.16 -4.38 -2.22 -0.136 0.37872E+04 203 montmorillonite-Mg -2.40 -4.55 -2.15 -0.133 0.36725E+04 204 montmorillonite-Na -1.96 -3.84 -1.88 -0.115 0.32139E+04 205 nontronite-Ca 3.28 3.17 -0.11 -0.007 0.19430E+03 206 nontronite-H 2.60 1.46 -1.13 -0.076 0.19378E+04 207 nontronite-K 3.40 3.05 -0.36 -0.023 0.60974E+03 208 nontronite-Mg 3.14 2.87 -0.27 -0.017 0.45423E+03 224 tobermorite 9.84 5.34 -4.50 -1.227 0.76760E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59631E+04 240 silica-amorphous -2.08 -3.26 -1.18 -0.395 0.20226E+04 242 an20ab80 2.08 1.14 -0.94 -0.072 0.16082E+04 243 an25ab75 2.71 1.62 -1.09 -0.084 0.18537E+04 244 an30ab70 3.34 2.11 -1.23 -0.095 0.21076E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.4790000 g New total amount of reactant added: 1.5190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4570E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.5190000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1350618E-02 Osmotic coef. = 0.9790 True ionic strength = .2120751E-02 Chg. balance for total moles = 0.4570E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.71942E-09 -9.1430 0.66651E-09 -9.1762 0.92646E+00 -0.0332 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12768E-03 -3.8939 0.92567E+00 -0.0335 4 SO4-- 0.25498E-04 -4.5935 0.19788E-04 -4.7036 0.77609E+00 -0.1101 5 HCO3- 0.11205E-04 -4.9506 0.10374E-04 -4.9841 0.92586E+00 -0.0335 6 HS- 0.26775E-13 -13.5723 0.24785E-13 -13.6058 0.92569E+00 -0.0335 7 Al+++ 0.18439E-24 -24.7343 0.10639E-24 -24.9731 0.57701E+00 -0.2388 8 H4SiO4 0.54167E-03 -3.2663 0.54167E-03 -3.2663 0.10000E+01 0.0000 9 Ca++ 0.12740E-07 -7.8948 0.98776E-08 -8.0054 0.77529E+00 -0.1105 10 Mg++ 0.20870E-09 -9.6805 0.16170E-09 -9.7913 0.77479E+00 -0.1108 11 Fe++ 0.12343E-11 -11.9086 0.95645E-12 -12.0193 0.77491E+00 -0.1108 12 K+ 0.46641E-04 -4.3312 0.43184E-04 -4.3647 0.92589E+00 -0.0334 13 Na+ 0.20378E-02 -2.6908 0.18863E-02 -2.7244 0.92565E+00 -0.0336 14 Mn++ 0.16491E-09 -9.7828 0.12781E-09 -9.8935 0.77500E+00 -0.1107 15 HPO4-- 0.88888E-05 -5.0512 0.68986E-05 -5.1612 0.77610E+00 -0.1101 16 HSiO3- 0.85659E-03 -3.0672 0.79291E-03 -3.1008 0.92567E+00 -0.0335 17 Ca(HSiO3)+ 0.18952E-09 -9.7223 0.17548E-09 -9.7558 0.92592E+00 -0.0334 18 Mg(HSiO3)+ 0.38611E-11 -11.4133 0.35751E-11 -11.4467 0.92592E+00 -0.0334 19 NaHSiO3,aq 0.23755E-04 -4.6243 0.23755E-04 -4.6243 0.10000E+01 0.0000 20 AlO+ 0.33392E-13 -13.4764 0.30918E-13 -13.5098 0.92592E+00 -0.0334 21 AlOH+2 0.13318E-18 -18.8756 0.10323E-18 -18.9862 0.77510E+00 -0.1106 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.33604E-04 -4.4736 0.31098E-04 -4.5073 0.92543E+00 -0.0337 24 CH4,aq 0.12756E-19 -19.8943 0.12750E-19 -19.8945 0.99958E+00 -0.0002 29 CO,aq 0.15831E-18 -18.8005 0.15831E-18 -18.8005 0.10000E+01 0.0000 30 CO2,aq 0.13947E-07 -7.8555 0.13941E-07 -7.8557 0.99958E+00 -0.0002 31 CO3-2 0.18549E-05 -5.7317 0.14391E-05 -5.8419 0.77585E+00 -0.1102 32 CaCO3,aq 0.17410E-09 -9.7592 0.17410E-09 -9.7592 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.27885E-11 -11.5546 0.25819E-11 -11.5881 0.92592E+00 -0.0334 34 CaCl+ 0.21705E-11 -11.6634 0.20097E-11 -11.6969 0.92592E+00 -0.0334 35 CaCl2,aq 0.59746E-16 -16.2237 0.59746E-16 -16.2237 0.10000E+01 0.0000 36 CaOH+ 0.11286E-08 -8.9475 0.10450E-08 -8.9809 0.92592E+00 -0.0334 37 CaSO4,aq 0.60901E-10 -10.2154 0.60901E-10 -10.2154 0.10000E+01 0.0000 38 HCl,aq 0.16007E-13 -13.7957 0.16007E-13 -13.7957 0.10000E+01 0.0000 43 FeCl+ 0.20542E-15 -15.6873 0.19021E-15 -15.7208 0.92592E+00 -0.0334 46 FeO,aq 0.85140E-10 -10.0699 0.85140E-10 -10.0699 0.10000E+01 0.0000 47 FeOH+ 0.51381E-10 -10.2892 0.47574E-10 -10.3226 0.92592E+00 -0.0334 48 HFeO2- 0.14843E-08 -8.8285 0.13740E-08 -8.8620 0.92567E+00 -0.0335 49 FeO+ 0.59546E-14 -14.2251 0.55135E-14 -14.2586 0.92592E+00 -0.0334 51 FeO2- 0.26352E-08 -8.5792 0.24393E-08 -8.6127 0.92567E+00 -0.0335 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44110E-09 -9.3555 0.44092E-09 -9.3556 0.99958E+00 -0.0002 54 KCl,aq 0.97631E-10 -10.0104 0.97631E-10 -10.0104 0.10000E+01 0.0000 55 KHSO4,aq 0.15241E-17 -17.8170 0.15241E-17 -17.8170 0.10000E+01 0.0000 56 KOH,aq 0.28246E-07 -7.5490 0.28246E-07 -7.5490 0.10000E+01 0.0000 57 KSO4- 0.14223E-07 -7.8470 0.13165E-07 -7.8806 0.92567E+00 -0.0335 58 MgCO3,aq 0.71217E-12 -12.1474 0.71217E-12 -12.1474 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.46550E-13 -13.3321 0.43102E-13 -13.3655 0.92592E+00 -0.0334 60 MgCl+ 0.32257E-13 -13.4914 0.29867E-13 -13.5248 0.92592E+00 -0.0334 61 MgOH+ 0.10236E-09 -9.9899 0.94774E-10 -10.0233 0.92592E+00 -0.0334 63 MnO,aq 0.30370E-09 -9.5175 0.30370E-09 -9.5175 0.10000E+01 0.0000 64 MnOH+ 0.63780E-09 -9.1953 0.59055E-09 -9.2287 0.92592E+00 -0.0334 65 MnO2-2 0.30474E-13 -13.5161 0.23643E-13 -13.6263 0.77585E+00 -0.1102 66 HMnO2- 0.36884E-11 -11.4332 0.34142E-11 -11.4667 0.92567E+00 -0.0335 69 MnCl+ 0.10667E-12 -12.9720 0.98763E-13 -13.0054 0.92592E+00 -0.0334 70 MnSO4,aq 0.71674E-12 -12.1446 0.71674E-12 -12.1446 0.10000E+01 0.0000 71 NaCl,aq 0.78641E-07 -7.1043 0.78641E-07 -7.1043 0.10000E+01 0.0000 72 NaOH,aq 0.12436E-05 -5.9053 0.12436E-05 -5.9053 0.10000E+01 0.0000 74 OH- 0.97248E-03 -3.0121 0.89996E-03 -3.0458 0.92543E+00 -0.0337 79 HPO3-2 0.12383E-16 -16.9072 0.96074E-17 -17.0174 0.77585E+00 -0.1102 81 H2PO3- 0.13589E-19 -19.8668 0.12578E-19 -19.9004 0.92567E+00 -0.0335 82 H3PO4,aq 0.19730E-13 -13.7049 0.19730E-13 -13.7049 0.10000E+01 0.0000 83 H2PO4- 0.87074E-07 -7.0601 0.80612E-07 -7.0936 0.92579E+00 -0.0335 84 PO4-3 0.15556E-07 -7.8081 0.90391E-08 -8.0439 0.58106E+00 -0.2358 87 H2P2O7-2 0.65552E-15 -15.1834 0.50859E-15 -15.2936 0.77585E+00 -0.1102 88 HP2O7-3 0.27115E-12 -12.5668 0.15647E-12 -12.8056 0.57706E+00 -0.2388 89 P2O7-4 0.15123E-12 -12.8204 0.57914E-13 -13.2372 0.38295E+00 -0.4169 90 H2S,aq 0.49655E-16 -16.3040 0.49634E-16 -16.3042 0.99958E+00 -0.0002 97 SO3-2 0.15302E-14 -14.8153 0.11897E-14 -14.9246 0.77745E+00 -0.1093 98 HSO3- 0.50129E-16 -16.2999 0.46403E-16 -16.3335 0.92567E+00 -0.0335 99 HSO4- 0.13215E-10 -10.8789 0.12238E-10 -10.9123 0.92604E+00 -0.0334 Charge balance for all species = 0.4604E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7194151E-09 -.1990326E-02 -.2005739E+01 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9998062E+06 0.0000 3 Cl- 0.1379355E-03 0.1380142E-03 0.4892066E+01 5.2823 4 SO4-- 0.2549757E-04 0.2551211E-04 0.2450258E+01 13.6488 5 HCO3- 0.1120479E-04 0.1307379E-04 0.7975710E+00 4.1921 6 HS- 0.2677507E-13 -.2445284E-09 -.8085470E-05 -4.4296 7 Al+++ 0.1843871E-24 0.3361337E-04 0.9067628E+00 2.5555 8 H4SiO4 0.5416654E-03 0.1422007E-02 0.1366502E+03 -3.2663 9 Ca++ 0.1274049E-07 0.1429856E-07 0.5729464E-03 10.3470 10 Mg++ 0.2087038E-09 0.3157124E-09 0.7674106E-05 8.5611 11 Fe++ 0.1234279E-11 0.4460707E-08 0.2490686E-03 6.3330 12 K+ 0.4664066E-04 0.4668323E-04 0.1825053E+01 4.8115 13 Na+ 0.2037781E-02 0.2062857E-02 0.4741545E+02 6.4518 14 Mn++ 0.1649105E-09 0.1110957E-08 0.6102189E-04 8.4589 15 HPO4-- 0.8888775E-05 0.8991406E-05 0.8628184E+00 13.1911 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2513934E-01 -.1989749E-02 -.2314960E-01 0.0000000E+00 2 H2O 0.5548921E+02 0.5549231E+02 -.3105684E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6760114E-04 0.2550471E-04 0.4209642E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4209667E-04 -.2444575E-09 -.4209642E-04 0.0000000E+00 7 Al+++ 0.4953067E-02 0.3360362E-04 0.4919463E-02 0.0000000E+00 8 H4SiO4 0.1581702E-01 0.1421595E-02 0.1439542E-01 0.0000000E+00 9 Ca++ 0.1761538E-02 0.1429442E-07 0.1761523E-02 0.0000000E+00 10 Mg++ 0.1205556E-02 0.3156208E-09 0.1205555E-02 0.0000000E+00 11 Fe++ 0.1083060E-02 0.4459413E-08 0.1083056E-02 0.0000000E+00 12 K+ 0.3225053E-03 0.4666969E-04 0.2758356E-03 0.0000000E+00 13 Na+ 0.2066786E-02 0.2062259E-02 0.4527031E-05 0.0000000E+00 14 Mn++ 0.2633733E-04 0.1110635E-08 0.2633622E-04 0.0000000E+00 15 HPO4-- 0.8988799E-05 0.8988799E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.7115E-18 Mass of aqueous solution: 0.999904E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.5190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2411E-03 -3.618 0.1340 -0.873 8.312 0.5098E-01 daphnite 0.1493E-03 -3.826 0.1065 -0.973 6.605 0.3227E-01 chlorite-Mn 0.5267E-05 -5.278 0.3734E-02 -2.428 0.2316 0.1190E-02 hematite 0.1547E-03 -3.811 0.2470E-01 -1.607 1.532 0.4682E-02 microcline 0.1134E-03 -3.945 0.3158E-01 -1.501 1.958 0.1233E-01 muscovite 0.1624E-03 -3.789 0.6468E-01 -1.189 4.011 0.2287E-01 stilbite 0.1762E-02 -2.754 1.241 0.094 76.99 0.5790 nontronite-Na 0.1372E-04 -4.863 0.5834E-02 -2.234 0.3618 0.1812E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.612421 g Volume = 0.705141 cm3 Porosity: 56.1371% V(tot) - V(min): 0.90246E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.5190000 g log = 0.1816 Original solution: 1000.0103000 g Original solution / Rock added: 658.33 (Water/Rock Ratio), log = 2.8184 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1506E-05 1.0073 0.1596E-05 0.1584E-05 CH4,gas 0.1892E-16 1.0129 0.2016E-16 0.1991E-16 H2,gas 0.5746E-06 1.0006 0.6048E-06 0.6044E-06 H2S,gas 0.1382E-14 0.9959 0.1448E-14 0.1454E-14 S2,gas 0.2040E-36 1.0000 0.2146E-36 0.2146E-36 CO,gas 0.2376E-15 1.0000 0.2500E-15 0.2500E-15 SO3,gas 0.3124E-38 1.0000 0.3286E-38 0.3286E-38 SO2,gas 0.7147E-22 1.0000 0.7519E-22 0.7519E-22 HCl,gas 0.2687E-16 1.0000 0.2826E-16 0.2826E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 120 muscovite 2.68 2.68 0.00 0.000 0.30331E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.34880E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.16 -7.80 -2.599 0.13313E+05 -5.797 3 CH4,gas 4.81 -13.89 -18.70 -4.674 0.31922E+05 -16.695 4 H2,gas 8.29 0.07 -8.22 -4.696 0.14033E+05 -6.218 5 H2S,gas -5.94 -22.78 -16.84 -8.420 0.28753E+05 -14.839 6 S2,gas -7.03 -45.70 -38.67 -5.949 0.66025E+05 -36.668 7 CO,gas 3.51 -14.09 -17.60 -5.416 0.30055E+05 -15.602 8 SO3,gas 17.43 -23.06 -40.48 -10.121 0.69124E+05 -38.483 9 SO2,gas 1.14 -22.99 -24.12 -6.433 0.41191E+05 -22.124 10 HCl,gas 5.48 -13.07 -18.55 -9.274 0.31672E+05 -16.549 11 acmite 7.74 6.22 -1.52 -0.158 0.25942E+04 15 albite-high 0.75 -0.79 -1.54 -0.119 0.26315E+04 16 albite -0.33 -0.79 -0.46 -0.036 0.79082E+03 19 spessartine 24.55 20.69 -3.86 -0.193 0.65924E+04 20 analcite 3.37 2.47 -0.90 -0.100 0.15297E+04 21 andalusite 5.06 1.84 -3.22 -0.322 0.54941E+04 26 annite 20.21 16.57 -3.64 -0.202 0.62186E+04 27 phlogopite 27.15 23.25 -3.90 -0.216 0.66508E+04 29 anorthite 12.80 8.93 -3.87 -0.298 0.66117E+04 32 apatite-OH -17.99 -18.81 -0.82 -0.063 0.13949E+04 35 aragonite 0.99 -3.81 -4.80 -1.600 0.81949E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68564E+04 37 calcite 0.83 -3.81 -4.65 -1.549 0.79336E+04 38 carnegieite-low 9.06 5.74 -3.32 -0.475 0.56748E+04 39 carnegieite-high 10.13 5.74 -4.39 -0.628 0.75017E+04 40 carpholite-Mg 8.65 7.14 -1.51 -0.101 0.25797E+04 41 carpholite-Fe 6.78 4.91 -1.87 -0.125 0.31953E+04 42 celadonite 5.40 2.86 -2.54 -0.149 0.43327E+04 43 celadonite-Fe 3.94 0.63 -3.30 -0.194 0.56380E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81730E+04 50 chloritoid-Mg 13.26 10.41 -2.86 -0.190 0.48756E+04 51 chloritoid-Fe 9.24 8.18 -1.06 -0.071 0.18115E+04 52 chloritoid-Mn 11.46 10.30 -1.16 -0.077 0.19799E+04 54 coesite -2.37 -3.27 -0.90 -0.299 0.15315E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.27 -0.72 -0.239 0.12244E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.38 -3.84 -0.384 0.65565E+04 68 hedenbergite 14.24 10.15 -4.10 -0.410 0.69953E+04 75 epidote 24.78 22.31 -2.47 -0.120 0.42177E+04 76 clinozoisite 22.92 18.56 -4.36 -0.198 0.74436E+04 77 epidote-Fe 29.94 26.05 -3.89 -0.202 0.66393E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79895E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.47 -3.73 -0.311 0.63648E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.47 -1.78 -0.178 0.30327E+04 97 kalsilite 7.62 4.10 -3.52 -0.503 0.60095E+04 98 kaolinite -1.27 -1.42 -0.15 -0.013 0.25340E+03 99 kyanite 4.93 1.84 -3.09 -0.309 0.52708E+04 101 laumontite 2.97 2.39 -0.58 -0.039 0.99305E+03 102 lawsonite 9.68 8.93 -0.75 -0.050 0.12855E+04 103 leucite 4.17 0.83 -3.33 -0.333 0.56913E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70632E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20526E+04 108 minnesotaite 10.46 5.93 -4.53 -0.266 0.77291E+04 113 margarite 17.45 14.04 -3.42 -0.137 0.58316E+04 121 paragonite 4.34 4.32 -0.02 -0.001 0.29290E+02 122 nepheline 8.38 5.74 -2.64 -0.377 0.45028E+04 134 phlogopite-Na 29.73 24.89 -4.84 -0.269 0.82635E+04 136 prehnite 19.47 16.01 -3.46 -0.204 0.59080E+04 137 prehnite-Fe 22.59 19.75 -2.84 -0.171 0.48444E+04 145 pyroxmangite 7.42 5.19 -2.22 -0.445 0.37963E+04 146 pyrophyllite -6.10 -7.95 -1.86 -0.116 0.31692E+04 147 quartz -2.98 -3.27 -0.28 -0.095 0.48538E+03 151 rhodochrosite -0.96 -5.70 -4.74 -1.581 0.80982E+04 152 rhodonite 7.46 5.19 -2.27 -0.454 0.38756E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.84 -3.48 -0.348 0.59362E+04 164 stilpnomelane-Fe 13.18 13.05 -0.13 -0.004 0.21771E+03 165 stilpnomelane-Mg 27.60 24.19 -3.40 -0.102 0.58125E+04 168 sudoite 21.22 17.55 -3.67 -0.118 0.62678E+04 171 talc 16.55 12.62 -3.94 -0.231 0.67192E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76175E+04 177 topaz-H 4.67 1.84 -2.82 -0.257 0.48199E+04 178 tridymite -2.61 -3.27 -0.65 -0.217 0.11127E+04 187 wairakite 4.06 2.39 -1.67 -0.098 0.28439E+04 188 walstromite 11.53 7.08 -4.45 -0.889 0.75933E+04 189 wollastonite 10.48 7.08 -3.40 -0.680 0.58072E+04 190 pseudo-wollastonite 11.02 7.08 -3.94 -0.788 0.67258E+04 191 zoisite 22.96 18.56 -4.40 -0.200 0.75161E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.33 -2.77 -0.171 0.47228E+04 194 beidellite-H -2.24 -6.03 -3.79 -0.242 0.64744E+04 195 beidellite-K -1.44 -4.45 -3.01 -0.184 0.51396E+04 196 beidellite-Mg -1.71 -4.62 -2.91 -0.180 0.49746E+04 197 beidellite-Na -1.26 -3.90 -2.65 -0.162 0.45193E+04 199 chalcedony -2.79 -3.27 -0.47 -0.157 0.80570E+03 201 montmorillonite-Ca -2.21 -4.26 -2.05 -0.127 0.35019E+04 202 montmorillonite-K -2.16 -4.38 -2.22 -0.136 0.37965E+04 203 montmorillonite-Mg -2.40 -4.56 -2.16 -0.134 0.36848E+04 204 montmorillonite-Na -1.96 -3.84 -1.88 -0.115 0.32144E+04 205 nontronite-Ca 3.28 3.16 -0.12 -0.008 0.20262E+03 206 nontronite-H 2.60 1.45 -1.14 -0.077 0.19500E+04 207 nontronite-K 3.40 3.04 -0.36 -0.023 0.61860E+03 208 nontronite-Mg 3.14 2.87 -0.27 -0.018 0.46605E+03 224 tobermorite 9.84 5.35 -4.49 -1.224 0.76600E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59611E+04 240 silica-amorphous -2.08 -3.27 -1.19 -0.395 0.20259E+04 242 an20ab80 2.08 1.15 -0.93 -0.071 0.15834E+04 243 an25ab75 2.71 1.64 -1.07 -0.082 0.18294E+04 244 an30ab70 3.34 2.12 -1.22 -0.094 0.20838E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.5190000 g New total amount of reactant added: 1.5590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4570E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.5590000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1379191E-02 Osmotic coef. = 0.9788 True ionic strength = .2167946E-02 Chg. balance for total moles = 0.4570E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.70139E-09 -9.1540 0.64942E-09 -9.1875 0.92591E+00 -0.0334 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12760E-03 -3.8941 0.92510E+00 -0.0338 4 SO4-- 0.25498E-04 -4.5935 0.19741E-04 -4.7046 0.77420E+00 -0.1111 5 HCO3- 0.11161E-04 -4.9523 0.10327E-04 -4.9860 0.92529E+00 -0.0337 6 HS- 0.26591E-13 -13.5753 0.24600E-13 -13.6091 0.92511E+00 -0.0338 7 Al+++ 0.17150E-24 -24.7657 0.98416E-25 -25.0069 0.57384E+00 -0.2412 8 H4SiO4 0.53931E-03 -3.2682 0.53931E-03 -3.2682 0.10000E+01 0.0000 9 Ca++ 0.12500E-07 -7.9031 0.96675E-08 -8.0147 0.77339E+00 -0.1116 10 Mg++ 0.19914E-09 -9.7008 0.15391E-09 -9.8127 0.77288E+00 -0.1119 11 Fe++ 0.11777E-11 -11.9289 0.91040E-12 -12.0408 0.77300E+00 -0.1118 12 K+ 0.46070E-04 -4.3366 0.42630E-04 -4.3703 0.92532E+00 -0.0337 13 Na+ 0.20853E-02 -2.6808 0.19290E-02 -2.7147 0.92508E+00 -0.0338 14 Mn++ 0.15736E-09 -9.8031 0.12165E-09 -9.9149 0.77309E+00 -0.1118 15 HPO4-- 0.91249E-05 -5.0398 0.70646E-05 -5.1509 0.77422E+00 -0.1111 16 HSiO3- 0.87586E-03 -3.0576 0.81025E-03 -3.0914 0.92510E+00 -0.0338 17 Ca(HSiO3)+ 0.18966E-09 -9.7220 0.17550E-09 -9.7557 0.92535E+00 -0.0337 18 Mg(HSiO3)+ 0.37579E-11 -11.4251 0.34774E-11 -11.4588 0.92535E+00 -0.0337 19 NaHSiO3,aq 0.24824E-04 -4.6051 0.24824E-04 -4.6051 0.10000E+01 0.0000 20 AlO+ 0.32555E-13 -13.4874 0.30125E-13 -13.5211 0.92535E+00 -0.0337 21 AlOH+2 0.12675E-18 -18.8971 0.98003E-19 -19.0088 0.77320E+00 -0.1117 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.34510E-04 -4.4621 0.31917E-04 -4.4960 0.92485E+00 -0.0339 24 CH4,aq 0.12633E-19 -19.8985 0.12628E-19 -19.8987 0.99957E+00 -0.0002 29 CO,aq 0.15435E-18 -18.8115 0.15435E-18 -18.8115 0.10000E+01 0.0000 30 CO2,aq 0.13527E-07 -7.8688 0.13521E-07 -7.8690 0.99957E+00 -0.0002 31 CO3-2 0.18996E-05 -5.7213 0.14702E-05 -5.8326 0.77396E+00 -0.1113 32 CaCO3,aq 0.17408E-09 -9.7592 0.17408E-09 -9.7592 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.27184E-11 -11.5657 0.25155E-11 -11.5994 0.92535E+00 -0.0337 34 CaCl+ 0.21243E-11 -11.6728 0.19657E-11 -11.7065 0.92535E+00 -0.0337 35 CaCl2,aq 0.58403E-16 -16.2336 0.58403E-16 -16.2336 0.10000E+01 0.0000 36 CaOH+ 0.11344E-08 -8.9452 0.10497E-08 -8.9789 0.92535E+00 -0.0337 37 CaSO4,aq 0.59462E-10 -10.2258 0.59462E-10 -10.2258 0.10000E+01 0.0000 38 HCl,aq 0.15587E-13 -13.8072 0.15587E-13 -13.8072 0.10000E+01 0.0000 43 FeCl+ 0.19553E-15 -15.7088 0.18093E-15 -15.7425 0.92535E+00 -0.0337 46 FeO,aq 0.85362E-10 -10.0687 0.85362E-10 -10.0687 0.10000E+01 0.0000 47 FeOH+ 0.50224E-10 -10.2991 0.46475E-10 -10.3328 0.92535E+00 -0.0337 48 HFeO2- 0.15283E-08 -8.8158 0.14138E-08 -8.8496 0.92510E+00 -0.0338 49 FeO+ 0.58054E-14 -14.2362 0.53721E-14 -14.2699 0.92535E+00 -0.0337 51 FeO2- 0.27062E-08 -8.5676 0.25035E-08 -8.6015 0.92510E+00 -0.0338 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44342E-09 -9.3532 0.44323E-09 -9.3534 0.99957E+00 -0.0002 54 KCl,aq 0.96317E-10 -10.0163 0.96317E-10 -10.0163 0.10000E+01 0.0000 55 KHSO4,aq 0.14624E-17 -17.8349 0.14624E-17 -17.8349 0.10000E+01 0.0000 56 KOH,aq 0.28617E-07 -7.5434 0.28617E-07 -7.5434 0.10000E+01 0.0000 57 KSO4- 0.14015E-07 -7.8534 0.12965E-07 -7.8872 0.92510E+00 -0.0338 58 MgCO3,aq 0.69255E-12 -12.1595 0.69255E-12 -12.1595 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.44134E-13 -13.3552 0.40839E-13 -13.3889 0.92535E+00 -0.0337 60 MgCl+ 0.30703E-13 -13.5128 0.28411E-13 -13.5465 0.92535E+00 -0.0337 61 MgOH+ 0.10005E-09 -9.9998 0.92585E-10 -10.0335 0.92535E+00 -0.0337 63 MnO,aq 0.30450E-09 -9.5164 0.30450E-09 -9.5164 0.10000E+01 0.0000 64 MnOH+ 0.62345E-09 -9.2052 0.57691E-09 -9.2389 0.92535E+00 -0.0337 65 MnO2-2 0.32262E-13 -13.4913 0.24969E-13 -13.6026 0.77396E+00 -0.1113 66 HMnO2- 0.37977E-11 -11.4205 0.35133E-11 -11.4543 0.92510E+00 -0.0338 69 MnCl+ 0.10153E-12 -12.9934 0.93950E-13 -13.0271 0.92535E+00 -0.0337 70 MnSO4,aq 0.68058E-12 -12.1671 0.68058E-12 -12.1671 0.10000E+01 0.0000 71 NaCl,aq 0.80374E-07 -7.0949 0.80374E-07 -7.0949 0.10000E+01 0.0000 72 NaOH,aq 0.13052E-05 -5.8843 0.13052E-05 -5.8843 0.10000E+01 0.0000 74 OH- 0.99870E-03 -3.0006 0.92365E-03 -3.0345 0.92485E+00 -0.0339 79 HPO3-2 0.12779E-16 -16.8935 0.98902E-17 -17.0048 0.77396E+00 -0.1113 81 H2PO3- 0.13638E-19 -19.8652 0.12617E-19 -19.8991 0.92510E+00 -0.0338 82 H3PO4,aq 0.19182E-13 -13.7171 0.19182E-13 -13.7171 0.10000E+01 0.0000 83 H2PO4- 0.86936E-07 -7.0608 0.80435E-07 -7.0946 0.92522E+00 -0.0338 84 PO4-3 0.16438E-07 -7.7842 0.95003E-08 -8.0223 0.57796E+00 -0.2381 87 H2P2O7-2 0.65425E-15 -15.1843 0.50636E-15 -15.2955 0.77396E+00 -0.1113 88 HP2O7-3 0.27860E-12 -12.5550 0.15988E-12 -12.7962 0.57389E+00 -0.2412 89 P2O7-4 0.16015E-12 -12.7955 0.60736E-13 -13.2166 0.37925E+00 -0.4211 90 H2S,aq 0.48020E-16 -16.3186 0.48000E-16 -16.3188 0.99957E+00 -0.0002 97 SO3-2 0.15382E-14 -14.8130 0.11930E-14 -14.9234 0.77560E+00 -0.1104 98 HSO3- 0.49011E-16 -16.3097 0.45340E-16 -16.3435 0.92510E+00 -0.0338 99 HSO4- 0.12853E-10 -10.8910 0.11895E-10 -10.9246 0.92548E+00 -0.0336 Charge balance for all species = 0.4605E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7013855E-09 -.2040613E-02 -.2056410E+01 0.0000 2 H2O 0.1000000E+01 0.5550842E+02 0.9998034E+06 0.0000 3 Cl- 0.1379347E-03 0.1380152E-03 0.4892086E+01 5.2933 4 SO4-- 0.2549796E-04 0.2551230E-04 0.2450269E+01 13.6703 5 HCO3- 0.1116054E-04 0.1307388E-04 0.7975742E+00 4.2014 6 HS- 0.2659123E-13 -.2528286E-09 -.8359895E-05 -4.4216 7 Al+++ 0.1715034E-24 0.3451930E-04 0.9311985E+00 2.5555 8 H4SiO4 0.5393133E-03 0.1439993E-02 0.1383782E+03 -3.2682 9 Ca++ 0.1250012E-07 0.1406252E-07 0.5634866E-03 10.3603 10 Mg++ 0.1991446E-09 0.3037233E-09 0.7382662E-05 8.5622 11 Fe++ 0.1177742E-11 0.4574735E-08 0.2554348E-03 6.3342 12 K+ 0.4606990E-04 0.4611263E-04 0.1802740E+01 4.8172 13 Na+ 0.2085263E-02 0.2111472E-02 0.4853275E+02 6.4728 14 Mn++ 0.1573566E-09 0.1089918E-08 0.5986608E-04 8.4601 15 HPO4-- 0.9124868E-05 0.9228243E-05 0.8855427E+00 13.2240 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2580169E-01 -.2040007E-02 -.2376168E-01 0.0000000E+00 2 H2O 0.5548871E+02 0.5549193E+02 -.3224542E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6870967E-04 0.2550472E-04 0.4320495E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4320520E-04 -.2527535E-09 -.4320495E-04 0.0000000E+00 7 Al+++ 0.5083496E-02 0.3450904E-04 0.5048987E-02 0.0000000E+00 8 H4SiO4 0.1623353E-01 0.1439565E-02 0.1479396E-01 0.0000000E+00 9 Ca++ 0.1807543E-02 0.1405835E-07 0.1807529E-02 0.0000000E+00 10 Mg++ 0.1237302E-02 0.3036330E-09 0.1237301E-02 0.0000000E+00 11 Fe++ 0.1111580E-02 0.4573376E-08 0.1111576E-02 0.0000000E+00 12 K+ 0.3309979E-03 0.4609893E-04 0.2848989E-03 0.0000000E+00 13 Na+ 0.2116996E-02 0.2110845E-02 0.6150452E-05 0.0000000E+00 14 Mn++ 0.2703087E-04 0.1089594E-08 0.2702978E-04 0.0000000E+00 15 HPO4-- 0.9225502E-05 0.9225502E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.3524E-18 Mass of aqueous solution: 0.999900E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.5590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2475E-03 -3.606 0.1375 -0.862 8.305 0.5232E-01 daphnite 0.1532E-03 -3.815 0.1093 -0.961 6.600 0.3312E-01 chlorite-Mn 0.5406E-05 -5.267 0.3833E-02 -2.416 0.2314 0.1221E-02 hematite 0.1542E-03 -3.812 0.2462E-01 -1.609 1.487 0.4667E-02 microcline 0.1195E-03 -3.923 0.3327E-01 -1.478 2.009 0.1299E-01 muscovite 0.1654E-03 -3.782 0.6587E-01 -1.181 3.978 0.2329E-01 stilbite 0.1808E-02 -2.743 1.274 0.105 76.91 0.5941 nontronite-Na 0.1864E-04 -4.730 0.7926E-02 -2.101 0.4786 0.2462E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.656170 g Volume = 0.724203 cm3 Porosity: 55.3952% V(tot) - V(min): 0.89940E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.5590000 g log = 0.1928 Original solution: 1000.0103000 g Original solution / Rock added: 641.44 (Water/Rock Ratio), log = 2.8072 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1461E-05 1.0073 0.1548E-05 0.1537E-05 CH4,gas 0.1874E-16 1.0129 0.1997E-16 0.1971E-16 H2,gas 0.5776E-06 1.0006 0.6079E-06 0.6076E-06 H2S,gas 0.1336E-14 0.9959 0.1400E-14 0.1406E-14 S2,gas 0.1888E-36 1.0000 0.1986E-36 0.1986E-36 CO,gas 0.2317E-15 1.0000 0.2437E-15 0.2437E-15 SO3,gas 0.2959E-38 1.0000 0.3113E-38 0.3113E-38 SO2,gas 0.6805E-22 1.0000 0.7158E-22 0.7158E-22 HCl,gas 0.2616E-16 1.0000 0.2752E-16 0.2752E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.22748E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.17 -7.81 -2.603 0.13336E+05 -5.810 3 CH4,gas 4.81 -13.89 -18.70 -4.675 0.31929E+05 -16.700 4 H2,gas 8.29 0.07 -8.22 -4.695 0.14029E+05 -6.216 5 H2S,gas -5.94 -22.80 -16.85 -8.427 0.28778E+05 -14.854 6 S2,gas -7.03 -45.73 -38.70 -5.954 0.66083E+05 -36.702 7 CO,gas 3.51 -14.10 -17.61 -5.419 0.30074E+05 -15.613 8 SO3,gas 17.43 -23.08 -40.51 -10.127 0.69164E+05 -38.507 9 SO2,gas 1.14 -23.01 -24.15 -6.439 0.41227E+05 -22.145 10 HCl,gas 5.48 -13.08 -18.56 -9.280 0.31691E+05 -16.560 11 acmite 7.74 6.24 -1.50 -0.156 0.25648E+04 15 albite-high 0.75 -0.78 -1.53 -0.117 0.26053E+04 16 albite -0.33 -0.78 -0.45 -0.034 0.76462E+03 19 spessartine 24.55 20.69 -3.86 -0.193 0.65963E+04 20 analcite 3.37 2.49 -0.88 -0.098 0.15003E+04 21 andalusite 5.06 1.84 -3.22 -0.322 0.54973E+04 26 annite 20.21 16.57 -3.64 -0.202 0.62128E+04 27 phlogopite 27.15 23.25 -3.89 -0.216 0.66450E+04 29 anorthite 12.80 8.93 -3.86 -0.297 0.65955E+04 32 apatite-OH -17.99 -18.78 -0.79 -0.061 0.13446E+04 35 aragonite 0.99 -3.81 -4.80 -1.600 0.81950E+04 36 brucite 12.58 8.56 -4.01 -0.803 0.68544E+04 37 calcite 0.83 -3.81 -4.65 -1.549 0.79336E+04 38 carnegieite-low 9.06 5.76 -3.30 -0.472 0.56422E+04 39 carnegieite-high 10.13 5.76 -4.37 -0.625 0.74690E+04 40 carpholite-Mg 8.65 7.14 -1.51 -0.101 0.25842E+04 41 carpholite-Fe 6.78 4.91 -1.87 -0.125 0.31999E+04 42 celadonite 5.40 2.86 -2.54 -0.149 0.43340E+04 43 celadonite-Fe 3.94 0.63 -3.30 -0.194 0.56393E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81736E+04 50 chloritoid-Mg 13.26 10.41 -2.86 -0.190 0.48768E+04 51 chloritoid-Fe 9.24 8.18 -1.06 -0.071 0.18128E+04 52 chloritoid-Mn 11.46 10.30 -1.16 -0.077 0.19812E+04 54 coesite -2.37 -3.27 -0.90 -0.300 0.15347E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.27 -0.72 -0.240 0.12276E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.39 -3.83 -0.383 0.65384E+04 68 hedenbergite 14.24 10.16 -4.09 -0.409 0.69772E+04 75 epidote 24.78 22.33 -2.45 -0.119 0.41822E+04 76 clinozoisite 22.92 18.58 -4.34 -0.197 0.74081E+04 77 epidote-Fe 29.94 26.07 -3.87 -0.201 0.66038E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79888E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.47 -3.73 -0.311 0.63654E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.49 -1.76 -0.176 0.30033E+04 97 kalsilite 7.62 4.10 -3.52 -0.502 0.60030E+04 98 kaolinite -1.27 -1.43 -0.15 -0.014 0.25985E+03 99 kyanite 4.93 1.84 -3.09 -0.309 0.52741E+04 101 laumontite 2.97 2.40 -0.58 -0.038 0.98337E+03 102 lawsonite 9.68 8.93 -0.74 -0.050 0.12694E+04 103 leucite 4.17 0.84 -3.33 -0.333 0.56881E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70639E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20506E+04 108 minnesotaite 10.46 5.93 -4.53 -0.267 0.77362E+04 113 margarite 17.45 14.05 -3.41 -0.136 0.58154E+04 121 paragonite 4.34 4.33 0.00 0.000 0.30831E+01 122 nepheline 8.38 5.76 -2.62 -0.374 0.44701E+04 134 phlogopite-Na 29.73 24.91 -4.82 -0.268 0.82315E+04 136 prehnite 19.47 16.03 -3.44 -0.202 0.58725E+04 137 prehnite-Fe 22.59 19.77 -2.82 -0.169 0.48089E+04 145 pyroxmangite 7.42 5.19 -2.22 -0.445 0.37976E+04 146 pyrophyllite -6.10 -7.96 -1.86 -0.116 0.31821E+04 147 quartz -2.98 -3.27 -0.29 -0.095 0.48861E+03 151 rhodochrosite -0.96 -5.71 -4.75 -1.585 0.81189E+04 152 rhodonite 7.46 5.19 -2.27 -0.454 0.38769E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.84 -3.48 -0.348 0.59395E+04 164 stilpnomelane-Fe 13.18 13.05 -0.13 -0.004 0.22901E+03 165 stilpnomelane-Mg 27.60 24.19 -3.41 -0.102 0.58238E+04 168 sudoite 21.22 17.54 -3.67 -0.119 0.62736E+04 171 talc 16.55 12.61 -3.94 -0.232 0.67263E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76169E+04 177 topaz-H 4.67 1.84 -2.82 -0.257 0.48231E+04 178 tridymite -2.61 -3.27 -0.65 -0.218 0.11159E+04 187 wairakite 4.06 2.40 -1.66 -0.098 0.28342E+04 188 walstromite 11.53 7.09 -4.44 -0.887 0.75739E+04 189 wollastonite 10.48 7.09 -3.39 -0.678 0.57878E+04 190 pseudo-wollastonite 11.02 7.09 -3.93 -0.786 0.67065E+04 191 zoisite 22.96 18.58 -4.38 -0.199 0.74806E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.33 -2.77 -0.171 0.47309E+04 194 beidellite-H -2.24 -6.04 -3.80 -0.242 0.64862E+04 195 beidellite-K -1.44 -4.45 -3.02 -0.185 0.51483E+04 196 beidellite-Mg -1.71 -4.63 -2.92 -0.181 0.49861E+04 197 beidellite-Na -1.26 -3.90 -2.65 -0.162 0.45193E+04 199 chalcedony -2.79 -3.27 -0.47 -0.158 0.80893E+03 201 montmorillonite-Ca -2.21 -4.27 -2.06 -0.127 0.35105E+04 202 montmorillonite-K -2.16 -4.39 -2.23 -0.136 0.38056E+04 203 montmorillonite-Mg -2.40 -4.57 -2.17 -0.134 0.36967E+04 204 montmorillonite-Na -1.96 -3.84 -1.88 -0.115 0.32148E+04 205 nontronite-Ca 3.28 3.16 -0.12 -0.008 0.21074E+03 206 nontronite-H 2.60 1.45 -1.15 -0.077 0.19618E+04 207 nontronite-K 3.40 3.04 -0.37 -0.024 0.62725E+03 208 nontronite-Mg 3.14 2.86 -0.28 -0.018 0.47757E+03 224 tobermorite 9.84 5.36 -4.48 -1.222 0.76445E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59591E+04 240 silica-amorphous -2.08 -3.27 -1.19 -0.396 0.20291E+04 242 an20ab80 2.08 1.17 -0.91 -0.070 0.15592E+04 243 an25ab75 2.71 1.65 -1.06 -0.081 0.18057E+04 244 an30ab70 3.34 2.14 -1.21 -0.093 0.20606E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.5590000 g New total amount of reactant added: 1.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4570E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.5990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1407781E-02 Osmotic coef. = 0.9786 True ionic strength = .2215138E-02 Chg. balance for total moles = 0.4570E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.68424E-09 -9.1648 0.63317E-09 -9.1985 0.92536E+00 -0.0337 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12752E-03 -3.8944 0.92453E+00 -0.0341 4 SO4-- 0.25498E-04 -4.5935 0.19694E-04 -4.7057 0.77235E+00 -0.1122 5 HCO3- 0.11116E-04 -4.9540 0.10280E-04 -4.9880 0.92473E+00 -0.0340 6 HS- 0.26413E-13 -13.5782 0.24420E-13 -13.6123 0.92455E+00 -0.0341 7 Al+++ 0.15981E-24 -24.7964 0.91211E-25 -25.0400 0.57073E+00 -0.2436 8 H4SiO4 0.53703E-03 -3.2700 0.53703E-03 -3.2700 0.10000E+01 0.0000 9 Ca++ 0.12271E-07 -7.9111 0.94670E-08 -8.0238 0.77152E+00 -0.1127 10 Mg++ 0.19025E-09 -9.7207 0.14668E-09 -9.8336 0.77100E+00 -0.1129 11 Fe++ 0.11251E-11 -11.9488 0.86761E-12 -12.0617 0.77113E+00 -0.1129 12 K+ 0.45521E-04 -4.3418 0.42096E-04 -4.3758 0.92477E+00 -0.0340 13 Na+ 0.21327E-02 -2.6711 0.19717E-02 -2.7052 0.92451E+00 -0.0341 14 Mn++ 0.15033E-09 -9.8230 0.11593E-09 -9.9358 0.77122E+00 -0.1128 15 HPO4-- 0.93609E-05 -5.0287 0.72301E-05 -5.1409 0.77236E+00 -0.1122 16 HSiO3- 0.89507E-03 -3.0481 0.82752E-03 -3.0822 0.92453E+00 -0.0341 17 Ca(HSiO3)+ 0.18980E-09 -9.7217 0.17553E-09 -9.7557 0.92479E+00 -0.0340 18 Mg(HSiO3)+ 0.36598E-11 -11.4365 0.33846E-11 -11.4705 0.92479E+00 -0.0340 19 NaHSiO3,aq 0.25915E-04 -4.5865 0.25915E-04 -4.5865 0.10000E+01 0.0000 20 AlO+ 0.31760E-13 -13.4981 0.29371E-13 -13.5321 0.92479E+00 -0.0340 21 AlOH+2 0.12078E-18 -18.9180 0.93159E-19 -19.0308 0.77133E+00 -0.1128 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.35418E-04 -4.4508 0.32736E-04 -4.4850 0.92428E+00 -0.0342 24 CH4,aq 0.12513E-19 -19.9026 0.12508E-19 -19.9028 0.99956E+00 -0.0002 29 CO,aq 0.15057E-18 -18.8223 0.15057E-18 -18.8223 0.10000E+01 0.0000 30 CO2,aq 0.13129E-07 -7.8818 0.13123E-07 -7.8820 0.99956E+00 -0.0002 31 CO3-2 0.19442E-05 -5.7113 0.15011E-05 -5.8236 0.77210E+00 -0.1123 32 CaCO3,aq 0.17405E-09 -9.7593 0.17405E-09 -9.7593 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.26515E-11 -11.5765 0.24521E-11 -11.6105 0.92479E+00 -0.0340 34 CaCl+ 0.20802E-11 -11.6819 0.19238E-11 -11.7158 0.92479E+00 -0.0340 35 CaCl2,aq 0.57122E-16 -16.2432 0.57122E-16 -16.2432 0.10000E+01 0.0000 36 CaOH+ 0.11400E-08 -8.9431 0.10543E-08 -8.9770 0.92479E+00 -0.0340 37 CaSO4,aq 0.58090E-10 -10.2359 0.58090E-10 -10.2359 0.10000E+01 0.0000 38 HCl,aq 0.15188E-13 -13.8185 0.15188E-13 -13.8185 0.10000E+01 0.0000 43 FeCl+ 0.18634E-15 -15.7297 0.17233E-15 -15.7637 0.92479E+00 -0.0340 46 FeO,aq 0.85580E-10 -10.0676 0.85580E-10 -10.0676 0.10000E+01 0.0000 47 FeOH+ 0.49122E-10 -10.3087 0.45428E-10 -10.3427 0.92479E+00 -0.0340 48 HFeO2- 0.15725E-08 -8.8034 0.14538E-08 -8.8375 0.92453E+00 -0.0341 49 FeO+ 0.56636E-14 -14.2469 0.52376E-14 -14.2809 0.92479E+00 -0.0340 51 FeO2- 0.27774E-08 -8.5564 0.25678E-08 -8.5904 0.92453E+00 -0.0341 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44569E-09 -9.3510 0.44549E-09 -9.3512 0.99956E+00 -0.0002 54 KCl,aq 0.95053E-10 -10.0220 0.95053E-10 -10.0220 0.10000E+01 0.0000 55 KHSO4,aq 0.14046E-17 -17.8524 0.14046E-17 -17.8524 0.10000E+01 0.0000 56 KOH,aq 0.28984E-07 -7.5378 0.28984E-07 -7.5378 0.10000E+01 0.0000 57 KSO4- 0.13815E-07 -7.8597 0.12772E-07 -7.8937 0.92453E+00 -0.0341 58 MgCO3,aq 0.67386E-12 -12.1714 0.67386E-12 -12.1714 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.41893E-13 -13.3779 0.38743E-13 -13.4118 0.92479E+00 -0.0340 60 MgCl+ 0.29260E-13 -13.5337 0.27059E-13 -13.5677 0.92479E+00 -0.0340 61 MgOH+ 0.97858E-10 -10.0094 0.90498E-10 -10.0434 0.92479E+00 -0.0340 63 MnO,aq 0.30528E-09 -9.5153 0.30528E-09 -9.5153 0.10000E+01 0.0000 64 MnOH+ 0.60977E-09 -9.2148 0.56391E-09 -9.2488 0.92479E+00 -0.0340 65 MnO2-2 0.34108E-13 -13.4671 0.26335E-13 -13.5795 0.77210E+00 -0.1123 66 HMnO2- 0.39076E-11 -11.4081 0.36127E-11 -11.4422 0.92453E+00 -0.0341 69 MnCl+ 0.96756E-13 -13.0143 0.89479E-13 -13.0483 0.92479E+00 -0.0340 70 MnSO4,aq 0.64705E-12 -12.1891 0.64705E-12 -12.1891 0.10000E+01 0.0000 71 NaCl,aq 0.82103E-07 -7.0856 0.82103E-07 -7.0856 0.10000E+01 0.0000 72 NaOH,aq 0.13683E-05 -5.8638 0.13683E-05 -5.8638 0.10000E+01 0.0000 74 OH- 0.10250E-02 -2.9893 0.94736E-03 -3.0235 0.92428E+00 -0.0342 79 HPO3-2 0.13176E-16 -16.8802 0.10173E-16 -16.9925 0.77210E+00 -0.1123 81 H2PO3- 0.13686E-19 -19.8637 0.12653E-19 -19.8978 0.92453E+00 -0.0341 82 H3PO4,aq 0.18661E-13 -13.7291 0.18661E-13 -13.7291 0.10000E+01 0.0000 83 H2PO4- 0.86798E-07 -7.0615 0.80259E-07 -7.0955 0.92466E+00 -0.0340 84 PO4-3 0.17346E-07 -7.7608 0.99722E-08 -8.0012 0.57491E+00 -0.2404 87 H2P2O7-2 0.65294E-15 -15.1851 0.50414E-15 -15.2974 0.77210E+00 -0.1123 88 HP2O7-3 0.28604E-12 -12.5436 0.16327E-12 -12.7871 0.57078E+00 -0.2435 89 P2O7-4 0.16935E-12 -12.7712 0.63613E-13 -13.1965 0.37563E+00 -0.4252 90 H2S,aq 0.46477E-16 -16.3328 0.46456E-16 -16.3330 0.99956E+00 -0.0002 97 SO3-2 0.15460E-14 -14.8108 0.11962E-14 -14.9222 0.77376E+00 -0.1114 98 HSO3- 0.47944E-16 -16.3193 0.44325E-16 -16.3533 0.92453E+00 -0.0341 99 HSO4- 0.12509E-10 -10.9028 0.11570E-10 -10.9367 0.92492E+00 -0.0339 Charge balance for all species = 0.4604E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6842383E-09 -.2090925E-02 -.2107104E+01 0.0000 2 H2O 0.1000000E+01 0.5550843E+02 0.9998006E+06 0.0000 3 Cl- 0.1379339E-03 0.1380161E-03 0.4892106E+01 5.3041 4 SO4-- 0.2549834E-04 0.2551249E-04 0.2450279E+01 13.6913 5 HCO3- 0.1111647E-04 0.1307398E-04 0.7975775E+00 4.2105 6 HS- 0.2641285E-13 -.2611551E-09 -.8635192E-05 -4.4138 7 Al+++ 0.1598141E-24 0.3542681E-04 0.9556770E+00 2.5555 8 H4SiO4 0.5370275E-03 0.1458015E-02 0.1401096E+03 -3.2700 9 Ca++ 0.1227059E-07 0.1383730E-07 0.5544602E-03 10.3732 10 Mg++ 0.1902479E-09 0.2925102E-09 0.7110084E-05 8.5633 11 Fe++ 0.1125123E-11 0.4689133E-08 0.2618215E-03 6.3353 12 K+ 0.4552053E-04 0.4556342E-04 0.1781264E+01 4.8227 13 Na+ 0.2132721E-02 0.2160086E-02 0.4964999E+02 6.4933 14 Mn++ 0.1503262E-09 0.1070057E-08 0.5877499E-04 8.4612 15 HPO4-- 0.9360938E-05 0.9465083E-05 0.9082671E+00 13.2561 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2646403E-01 -.2090289E-02 -.2437374E-01 0.0000000E+00 2 H2O 0.5548821E+02 0.5549155E+02 -.3343322E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6981821E-04 0.2550473E-04 0.4431348E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4431374E-04 -.2610757E-09 -.4431348E-04 0.0000000E+00 7 Al+++ 0.5213926E-02 0.3541604E-04 0.5178510E-02 0.0000000E+00 8 H4SiO4 0.1665004E-01 0.1457572E-02 0.1519247E-01 0.0000000E+00 9 Ca++ 0.1853549E-02 0.1383309E-07 0.1853535E-02 0.0000000E+00 10 Mg++ 0.1269048E-02 0.2924213E-09 0.1269047E-02 0.0000000E+00 11 Fe++ 0.1140101E-02 0.4687707E-08 0.1140096E-02 0.0000000E+00 12 K+ 0.3394904E-03 0.4554957E-04 0.2939409E-03 0.0000000E+00 13 Na+ 0.2167206E-02 0.2159429E-02 0.7776364E-05 0.0000000E+00 14 Mn++ 0.2772441E-04 0.1069731E-08 0.2772335E-04 0.0000000E+00 15 HPO4-- 0.9462205E-05 0.9462205E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.1755E-17 Mass of aqueous solution: 0.999896E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2538E-03 -3.595 0.1411 -0.851 8.299 0.5366E-01 daphnite 0.1571E-03 -3.804 0.1121 -0.950 6.595 0.3397E-01 chlorite-Mn 0.5545E-05 -5.256 0.3931E-02 -2.405 0.2312 0.1253E-02 hematite 0.1537E-03 -3.813 0.2454E-01 -1.610 1.444 0.4652E-02 microcline 0.1256E-03 -3.901 0.3495E-01 -1.457 2.056 0.1365E-01 muscovite 0.1684E-03 -3.774 0.6707E-01 -1.173 3.946 0.2372E-01 stilbite 0.1854E-02 -2.732 1.306 0.116 76.84 0.6092 nontronite-Na 0.2356E-04 -4.628 0.1002E-01 -1.999 0.5895 0.3113E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.699917 g Volume = 0.743264 cm3 Porosity: 54.6680% V(tot) - V(min): 0.89634E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.5990000 g log = 0.2038 Original solution: 1000.0103000 g Original solution / Rock added: 625.40 (Water/Rock Ratio), log = 2.7962 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1418E-05 1.0073 0.1502E-05 0.1491E-05 CH4,gas 0.1856E-16 1.0129 0.1978E-16 0.1953E-16 H2,gas 0.5805E-06 1.0006 0.6110E-06 0.6107E-06 H2S,gas 0.1293E-14 0.9959 0.1355E-14 0.1360E-14 S2,gas 0.1751E-36 1.0000 0.1842E-36 0.1842E-36 CO,gas 0.2260E-15 1.0000 0.2378E-15 0.2378E-15 SO3,gas 0.2806E-38 1.0000 0.2952E-38 0.2952E-38 SO2,gas 0.6486E-22 1.0000 0.6823E-22 0.6823E-22 HCl,gas 0.2549E-16 1.0000 0.2682E-16 0.2682E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.60662E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 120 muscovite 2.68 2.68 0.00 0.000 0.30331E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.22748E-11 121 paragonite 4.34 4.35 0.01 0.001 -0.22496E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.19 -7.82 -2.608 0.13358E+05 -5.823 3 CH4,gas 4.81 -13.89 -18.70 -4.676 0.31936E+05 -16.704 4 H2,gas 8.29 0.07 -8.21 -4.694 0.14025E+05 -6.214 5 H2S,gas -5.94 -22.81 -16.87 -8.434 0.28802E+05 -14.868 6 S2,gas -7.03 -45.77 -38.73 -5.959 0.66139E+05 -36.735 7 CO,gas 3.51 -14.11 -17.62 -5.423 0.30092E+05 -15.624 8 SO3,gas 17.43 -23.10 -40.53 -10.132 0.69204E+05 -38.530 9 SO2,gas 1.14 -23.03 -24.17 -6.444 0.41263E+05 -22.166 10 HCl,gas 5.48 -13.09 -18.57 -9.286 0.31710E+05 -16.572 11 acmite 7.74 6.25 -1.49 -0.154 0.25360E+04 15 albite-high 0.75 -0.76 -1.51 -0.116 0.25797E+04 16 albite -0.33 -0.76 -0.43 -0.033 0.73904E+03 19 spessartine 24.55 20.68 -3.87 -0.193 0.66000E+04 20 analcite 3.37 2.51 -0.86 -0.096 0.14715E+04 21 andalusite 5.06 1.84 -3.22 -0.322 0.55004E+04 26 annite 20.21 16.57 -3.64 -0.202 0.62071E+04 27 phlogopite 27.15 23.26 -3.89 -0.216 0.66393E+04 29 anorthite 12.80 8.94 -3.85 -0.296 0.65798E+04 32 apatite-OH -17.99 -18.75 -0.76 -0.058 0.12956E+04 35 aragonite 0.99 -3.81 -4.80 -1.600 0.81951E+04 36 brucite 12.58 8.56 -4.01 -0.803 0.68525E+04 37 calcite 0.83 -3.81 -4.65 -1.549 0.79338E+04 38 carnegieite-low 9.06 5.78 -3.29 -0.469 0.56103E+04 39 carnegieite-high 10.13 5.78 -4.36 -0.622 0.74372E+04 40 carpholite-Mg 8.65 7.13 -1.52 -0.101 0.25886E+04 41 carpholite-Fe 6.78 4.91 -1.88 -0.125 0.32043E+04 42 celadonite 5.40 2.86 -2.54 -0.149 0.43352E+04 43 celadonite-Fe 3.94 0.63 -3.30 -0.194 0.56405E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81742E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.190 0.48781E+04 51 chloritoid-Fe 9.24 8.18 -1.06 -0.071 0.18140E+04 52 chloritoid-Mn 11.46 10.30 -1.16 -0.077 0.19825E+04 54 coesite -2.37 -3.27 -0.90 -0.300 0.15378E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.27 -0.72 -0.240 0.12307E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.40 -3.82 -0.382 0.65208E+04 68 hedenbergite 14.24 10.17 -4.08 -0.408 0.69596E+04 75 epidote 24.78 22.35 -2.43 -0.118 0.41476E+04 76 clinozoisite 22.92 18.60 -4.32 -0.196 0.73734E+04 77 epidote-Fe 29.94 26.09 -3.85 -0.200 0.65692E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79882E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.47 -3.73 -0.311 0.63660E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.51 -1.74 -0.174 0.29746E+04 97 kalsilite 7.62 4.11 -3.51 -0.502 0.59967E+04 98 kaolinite -1.27 -1.43 -0.16 -0.014 0.26615E+03 99 kyanite 4.93 1.84 -3.09 -0.309 0.52772E+04 101 laumontite 2.97 2.40 -0.57 -0.038 0.97392E+03 102 lawsonite 9.68 8.94 -0.73 -0.049 0.12536E+04 103 leucite 4.17 0.84 -3.33 -0.333 0.56849E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70645E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20488E+04 108 minnesotaite 10.46 5.93 -4.53 -0.267 0.77432E+04 113 margarite 17.45 14.06 -3.40 -0.136 0.57997E+04 122 nepheline 8.38 5.78 -2.60 -0.371 0.44382E+04 134 phlogopite-Na 29.73 24.93 -4.80 -0.267 0.82002E+04 136 prehnite 19.47 16.05 -3.42 -0.201 0.58378E+04 137 prehnite-Fe 22.59 19.79 -2.80 -0.168 0.47743E+04 145 pyroxmangite 7.42 5.19 -2.22 -0.445 0.37989E+04 146 pyrophyllite -6.10 -7.97 -1.87 -0.117 0.31947E+04 147 quartz -2.98 -3.27 -0.29 -0.096 0.49176E+03 151 rhodochrosite -0.96 -5.73 -4.77 -1.589 0.81392E+04 152 rhodonite 7.46 5.19 -2.27 -0.454 0.38781E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.84 -3.48 -0.348 0.59426E+04 164 stilpnomelane-Fe 13.18 13.04 -0.14 -0.004 0.24003E+03 165 stilpnomelane-Mg 27.60 24.18 -3.42 -0.102 0.58349E+04 168 sudoite 21.22 17.54 -3.68 -0.119 0.62793E+04 171 talc 16.55 12.61 -3.94 -0.232 0.67332E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76163E+04 177 topaz-H 4.67 1.84 -2.83 -0.257 0.48263E+04 178 tridymite -2.61 -3.27 -0.66 -0.218 0.11191E+04 187 wairakite 4.06 2.40 -1.65 -0.097 0.28247E+04 188 walstromite 11.53 7.10 -4.42 -0.885 0.75550E+04 189 wollastonite 10.48 7.10 -3.38 -0.676 0.57689E+04 190 pseudo-wollastonite 11.02 7.10 -3.92 -0.783 0.66876E+04 191 zoisite 22.96 18.60 -4.36 -0.198 0.74460E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.34 -2.78 -0.172 0.47389E+04 194 beidellite-H -2.24 -6.05 -3.81 -0.243 0.64978E+04 195 beidellite-K -1.44 -4.46 -3.02 -0.185 0.51567E+04 196 beidellite-Mg -1.71 -4.63 -2.93 -0.181 0.49974E+04 197 beidellite-Na -1.26 -3.90 -2.65 -0.162 0.45193E+04 199 chalcedony -2.79 -3.27 -0.48 -0.159 0.81208E+03 201 montmorillonite-Ca -2.21 -4.27 -2.06 -0.127 0.35188E+04 202 montmorillonite-K -2.16 -4.39 -2.23 -0.137 0.38144E+04 203 montmorillonite-Mg -2.40 -4.57 -2.17 -0.134 0.37084E+04 204 montmorillonite-Na -1.96 -3.84 -1.88 -0.115 0.32152E+04 205 nontronite-Ca 3.28 3.15 -0.13 -0.008 0.21866E+03 206 nontronite-H 2.60 1.44 -1.16 -0.077 0.19734E+04 207 nontronite-K 3.40 3.03 -0.37 -0.024 0.63569E+03 208 nontronite-Mg 3.14 2.85 -0.29 -0.019 0.48882E+03 224 tobermorite 9.84 5.37 -4.47 -1.219 0.76292E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.34 -3.49 -0.872 0.59573E+04 240 silica-amorphous -2.08 -3.27 -1.19 -0.397 0.20323E+04 242 an20ab80 2.08 1.18 -0.90 -0.069 0.15356E+04 243 an25ab75 2.71 1.67 -1.04 -0.080 0.17826E+04 244 an30ab70 3.34 2.15 -1.19 -0.092 0.20380E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.5990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1383118E-02 Osmotic coef. = 0.9788 True ionic strength = .2174013E-02 Chg. balance for total moles = 0.4570E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.69937E-09 -9.1553 0.64750E-09 -9.1888 0.92584E+00 -0.0335 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12759E-03 -3.8942 0.92502E+00 -0.0338 4 SO4-- 0.25498E-04 -4.5935 0.19735E-04 -4.7048 0.77396E+00 -0.1113 5 HCO3- 0.11155E-04 -4.9525 0.10321E-04 -4.9863 0.92522E+00 -0.0338 6 HS- 0.26572E-13 -13.5756 0.24580E-13 -13.6094 0.92504E+00 -0.0338 7 Al+++ 0.17011E-24 -24.7693 0.97548E-25 -25.0108 0.57344E+00 -0.2415 8 H4SiO4 0.53904E-03 -3.2684 0.53904E-03 -3.2684 0.10000E+01 0.0000 9 Ca++ 0.12475E-07 -7.9040 0.96451E-08 -8.0157 0.77315E+00 -0.1117 10 Mg++ 0.19810E-09 -9.7031 0.15306E-09 -9.8152 0.77264E+00 -0.1120 11 Fe++ 0.11715E-11 -11.9312 0.90531E-12 -12.0432 0.77276E+00 -0.1120 12 K+ 0.46008E-04 -4.3372 0.42569E-04 -4.3709 0.92525E+00 -0.0337 13 Na+ 0.20912E-02 -2.6796 0.19343E-02 -2.7135 0.92500E+00 -0.0339 14 Mn++ 0.15653E-09 -9.8054 0.12097E-09 -9.9173 0.77285E+00 -0.1119 15 HPO4-- 0.93593E-05 -5.0288 0.72439E-05 -5.1400 0.77398E+00 -0.1113 16 HSiO3- 0.87806E-03 -3.0565 0.81223E-03 -3.0903 0.92502E+00 -0.0338 17 Ca(HSiO3)+ 0.18970E-09 -9.7219 0.17552E-09 -9.7557 0.92528E+00 -0.0337 18 Mg(HSiO3)+ 0.37463E-11 -11.4264 0.34664E-11 -11.4601 0.92528E+00 -0.0337 19 NaHSiO3,aq 0.24953E-04 -4.6029 0.24953E-04 -4.6029 0.10000E+01 0.0000 20 AlO+ 0.32462E-13 -13.4886 0.30036E-13 -13.5224 0.92528E+00 -0.0337 21 AlOH+2 0.12604E-18 -18.8995 0.97426E-19 -19.0113 0.77296E+00 -0.1118 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.34615E-04 -4.4607 0.32011E-04 -4.4947 0.92478E+00 -0.0340 24 CH4,aq 0.12620E-19 -19.8989 0.12615E-19 -19.8991 0.99957E+00 -0.0002 29 CO,aq 0.15391E-18 -18.8127 0.15391E-18 -18.8127 0.10000E+01 0.0000 30 CO2,aq 0.13480E-07 -7.8703 0.13474E-07 -7.8705 0.99957E+00 -0.0002 31 CO3-2 0.19048E-05 -5.7201 0.14738E-05 -5.8316 0.77372E+00 -0.1114 32 CaCO3,aq 0.17410E-09 -9.7592 0.17410E-09 -9.7592 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.27109E-11 -11.5669 0.25083E-11 -11.6006 0.92528E+00 -0.0337 34 CaCl+ 0.21194E-11 -11.6738 0.19610E-11 -11.7075 0.92528E+00 -0.0337 35 CaCl2,aq 0.58259E-16 -16.2346 0.58259E-16 -16.2346 0.10000E+01 0.0000 36 CaOH+ 0.11352E-08 -8.9449 0.10503E-08 -8.9787 0.92528E+00 -0.0337 37 CaSO4,aq 0.59306E-10 -10.2269 0.59306E-10 -10.2269 0.10000E+01 0.0000 38 HCl,aq 0.15540E-13 -13.8085 0.15540E-13 -13.8085 0.10000E+01 0.0000 43 FeCl+ 0.19444E-15 -15.7112 0.17991E-15 -15.7449 0.92528E+00 -0.0337 46 FeO,aq 0.85388E-10 -10.0686 0.85388E-10 -10.0686 0.10000E+01 0.0000 47 FeOH+ 0.50096E-10 -10.3002 0.46353E-10 -10.3339 0.92528E+00 -0.0337 48 HFeO2- 0.15334E-08 -8.8143 0.14184E-08 -8.8482 0.92502E+00 -0.0338 49 FeO+ 0.57888E-14 -14.2374 0.53562E-14 -14.2711 0.92528E+00 -0.0337 51 FeO2- 0.27144E-08 -8.5663 0.25109E-08 -8.6002 0.92502E+00 -0.0338 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44369E-09 -9.3529 0.44350E-09 -9.3531 0.99957E+00 -0.0002 54 KCl,aq 0.96174E-10 -10.0169 0.96174E-10 -10.0169 0.10000E+01 0.0000 55 KHSO4,aq 0.14556E-17 -17.8370 0.14556E-17 -17.8370 0.10000E+01 0.0000 56 KOH,aq 0.28661E-07 -7.5427 0.28661E-07 -7.5427 0.10000E+01 0.0000 57 KSO4- 0.13992E-07 -7.8541 0.12943E-07 -7.8880 0.92502E+00 -0.0338 58 MgCO3,aq 0.69035E-12 -12.1609 0.69035E-12 -12.1609 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.43867E-13 -13.3579 0.40590E-13 -13.3916 0.92528E+00 -0.0337 60 MgCl+ 0.30532E-13 -13.5152 0.28251E-13 -13.5490 0.92528E+00 -0.0337 61 MgOH+ 0.99797E-10 -10.0009 0.92340E-10 -10.0346 0.92528E+00 -0.0337 63 MnO,aq 0.30459E-09 -9.5163 0.30459E-09 -9.5163 0.10000E+01 0.0000 64 MnOH+ 0.62185E-09 -9.2063 0.57539E-09 -9.2400 0.92528E+00 -0.0337 65 MnO2-2 0.32473E-13 -13.4885 0.25125E-13 -13.5999 0.77372E+00 -0.1114 66 HMnO2- 0.38105E-11 -11.4190 0.35248E-11 -11.4529 0.92502E+00 -0.0338 69 MnCl+ 0.10096E-12 -12.9958 0.93418E-13 -13.0296 0.92528E+00 -0.0337 70 MnSO4,aq 0.67658E-12 -12.1697 0.67658E-12 -12.1697 0.10000E+01 0.0000 71 NaCl,aq 0.80589E-07 -7.0937 0.80589E-07 -7.0937 0.10000E+01 0.0000 72 NaOH,aq 0.13127E-05 -5.8818 0.13127E-05 -5.8818 0.10000E+01 0.0000 74 OH- 0.10017E-02 -2.9992 0.92638E-03 -3.0332 0.92478E+00 -0.0340 79 HPO3-2 0.13115E-16 -16.8822 0.10147E-16 -16.9936 0.77372E+00 -0.1114 81 H2PO3- 0.13953E-19 -19.8553 0.12906E-19 -19.8892 0.92502E+00 -0.0338 82 H3PO4,aq 0.19552E-13 -13.7088 0.19552E-13 -13.7088 0.10000E+01 0.0000 83 H2PO4- 0.88886E-07 -7.0512 0.82233E-07 -7.0850 0.92515E+00 -0.0338 84 PO4-3 0.16916E-07 -7.7717 0.97701E-08 -8.0101 0.57756E+00 -0.2384 87 H2P2O7-2 0.68402E-15 -15.1649 0.52925E-15 -15.2763 0.77372E+00 -0.1114 88 HP2O7-3 0.29225E-12 -12.5342 0.16760E-12 -12.7757 0.57349E+00 -0.2415 89 P2O7-4 0.16858E-12 -12.7732 0.63857E-13 -13.1948 0.37878E+00 -0.4216 90 H2S,aq 0.47841E-16 -16.3202 0.47820E-16 -16.3204 0.99957E+00 -0.0002 97 SO3-2 0.15391E-14 -14.8127 0.11934E-14 -14.9232 0.77536E+00 -0.1105 98 HSO3- 0.48886E-16 -16.3108 0.45220E-16 -16.3447 0.92502E+00 -0.0338 99 HSO4- 0.12812E-10 -10.8924 0.11856E-10 -10.9260 0.92541E+00 -0.0337 Charge balance for all species = 0.4634E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6993709E-09 -.2046415E-02 -.2062256E+01 0.0000 2 H2O 0.1000000E+01 0.5550842E+02 0.9998030E+06 0.0000 3 Cl- 0.1379353E-03 0.1380159E-03 0.4892112E+01 5.2946 4 SO4-- 0.2549813E-04 0.2551244E-04 0.2450281E+01 13.6727 5 HCO3- 0.1115547E-04 0.1307396E-04 0.7975784E+00 4.2025 6 HS- 0.2657209E-13 -.2537874E-09 -.8391597E-05 -4.4207 7 Al+++ 0.1701102E-24 0.3462410E-04 0.9340254E+00 2.5555 8 H4SiO4 0.5390373E-03 0.1442055E-02 0.1385763E+03 -3.2684 9 Ca++ 0.1247503E-07 0.1403812E-07 0.5625086E-03 10.3618 10 Mg++ 0.1980951E-09 0.3024029E-09 0.7350566E-05 8.5624 11 Fe++ 0.1171534E-11 0.4587954E-08 0.2561728E-03 6.3343 12 K+ 0.4600825E-04 0.4605100E-04 0.1800330E+01 4.8179 13 Na+ 0.2091150E-02 0.2117497E-02 0.4867120E+02 6.4753 14 Mn++ 0.1565274E-09 0.1087593E-08 0.5973834E-04 8.4602 15 HPO4-- 0.9359266E-05 0.9465069E-05 0.9082682E+00 13.2375 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2646403E-01 -.2045796E-02 -.2441823E-01 0.0000000E+00 2 H2O 0.5548821E+02 0.5549162E+02 -.3414782E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6981821E-04 0.2550472E-04 0.4431349E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4431374E-04 -.2537106E-09 -.4431349E-04 0.0000000E+00 7 Al+++ 0.5213926E-02 0.3461362E-04 0.5179312E-02 0.0000000E+00 8 H4SiO4 0.1665004E-01 0.1441619E-02 0.1520842E-01 0.0000000E+00 9 Ca++ 0.1853549E-02 0.1403388E-07 0.1853535E-02 0.0000000E+00 10 Mg++ 0.1269048E-02 0.3023114E-09 0.1269047E-02 0.0000000E+00 11 Fe++ 0.1140101E-02 0.4586566E-08 0.1140096E-02 0.0000000E+00 12 K+ 0.3394904E-03 0.4603707E-04 0.2934534E-03 0.0000000E+00 13 Na+ 0.2167206E-02 0.2116856E-02 0.5034970E-04 0.0000000E+00 14 Mn++ 0.2772441E-04 0.1087263E-08 0.2772333E-04 0.0000000E+00 15 HPO4-- 0.9462205E-05 0.9462205E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1443E-17 Mass of aqueous solution: 0.999895E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2538E-03 -3.595 0.1411 -0.851 8.293 0.5366E-01 daphnite 0.1571E-03 -3.804 0.1121 -0.950 6.590 0.3397E-01 chlorite-Mn 0.5545E-05 -5.256 0.3931E-02 -2.405 0.2311 0.1253E-02 hematite 0.1948E-03 -3.710 0.3112E-01 -1.507 1.829 0.5898E-02 microcline 0.2019E-03 -3.695 0.5619E-01 -1.250 3.303 0.2195E-01 muscovite 0.9159E-04 -4.038 0.3648E-01 -1.438 2.145 0.1290E-01 stilbite 0.1854E-02 -2.732 1.306 0.116 76.79 0.6092 nontronite-Na -.1759E-04 1.000 -.7482E-02 1.000 -.4398 -.2324E-02 paragonite 0.5616E-04 -4.251 0.2146E-01 -1.668 1.262 0.7419E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.701100 g Volume = 0.743971 cm3 Porosity: 54.6248% V(tot) - V(min): 0.89563E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.5990000 g log = 0.2038 Original solution: 1000.0103000 g Original solution / Rock added: 625.40 (Water/Rock Ratio), log = 2.7962 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1456E-05 1.0073 0.1542E-05 0.1531E-05 CH4,gas 0.1872E-16 1.0129 0.1995E-16 0.1969E-16 H2,gas 0.5779E-06 1.0006 0.6083E-06 0.6080E-06 H2S,gas 0.1331E-14 0.9959 0.1395E-14 0.1400E-14 S2,gas 0.1872E-36 1.0000 0.1969E-36 0.1969E-36 CO,gas 0.2310E-15 1.0000 0.2430E-15 0.2430E-15 SO3,gas 0.2941E-38 1.0000 0.3093E-38 0.3093E-38 SO2,gas 0.6767E-22 1.0000 0.7118E-22 0.7118E-22 HCl,gas 0.2608E-16 1.0000 0.2744E-16 0.2744E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.60662E-10 47 daphnite 29.09 29.09 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 0.27298E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 0.30331E-10 121 paragonite 4.34 4.34 0.00 0.000 0.19715E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.18 -7.81 -2.604 0.13338E+05 -5.812 3 CH4,gas 4.81 -13.89 -18.70 -4.675 0.31930E+05 -16.700 4 H2,gas 8.29 0.07 -8.22 -4.695 0.14028E+05 -6.216 5 H2S,gas -5.94 -22.80 -16.86 -8.428 0.28780E+05 -14.856 6 S2,gas -7.03 -45.74 -38.71 -5.955 0.66089E+05 -36.706 7 CO,gas 3.51 -14.10 -17.61 -5.420 0.30076E+05 -15.614 8 SO3,gas 17.43 -23.08 -40.51 -10.127 0.69169E+05 -38.510 9 SO2,gas 1.14 -23.01 -24.15 -6.439 0.41231E+05 -22.148 10 HCl,gas 5.48 -13.08 -18.56 -9.281 0.31693E+05 -16.562 11 acmite 7.74 6.24 -1.50 -0.156 0.25613E+04 15 albite-high 0.75 -0.77 -1.52 -0.117 0.26022E+04 16 albite -0.33 -0.77 -0.45 -0.034 0.76153E+03 19 spessartine 24.55 20.69 -3.86 -0.193 0.65967E+04 20 analcite 3.37 2.49 -0.88 -0.097 0.14968E+04 21 andalusite 5.06 1.84 -3.22 -0.322 0.54977E+04 26 annite 20.21 16.57 -3.64 -0.202 0.62121E+04 27 phlogopite 27.15 23.26 -3.89 -0.216 0.66443E+04 29 anorthite 12.80 8.94 -3.86 -0.297 0.65936E+04 32 apatite-OH -17.99 -18.74 -0.75 -0.058 0.12887E+04 35 aragonite 0.99 -3.81 -4.80 -1.600 0.81949E+04 36 brucite 12.58 8.56 -4.01 -0.803 0.68542E+04 37 calcite 0.83 -3.81 -4.65 -1.549 0.79336E+04 38 carnegieite-low 9.06 5.76 -3.30 -0.472 0.56383E+04 39 carnegieite-high 10.13 5.76 -4.37 -0.625 0.74652E+04 40 carpholite-Mg 8.65 7.14 -1.51 -0.101 0.25847E+04 41 carpholite-Fe 6.78 4.91 -1.87 -0.125 0.32004E+04 42 celadonite 5.40 2.86 -2.54 -0.149 0.43341E+04 43 celadonite-Fe 3.94 0.63 -3.30 -0.194 0.56394E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81737E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.190 0.48770E+04 51 chloritoid-Fe 9.24 8.18 -1.06 -0.071 0.18129E+04 52 chloritoid-Mn 11.46 10.30 -1.16 -0.077 0.19813E+04 54 coesite -2.37 -3.27 -0.90 -0.300 0.15351E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.27 -0.72 -0.240 0.12280E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.39 -3.83 -0.383 0.65363E+04 68 hedenbergite 14.24 10.16 -4.09 -0.409 0.69751E+04 75 epidote 24.78 22.33 -2.45 -0.119 0.41780E+04 76 clinozoisite 22.92 18.58 -4.34 -0.197 0.74039E+04 77 epidote-Fe 29.94 26.07 -3.87 -0.201 0.65997E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79888E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.47 -3.73 -0.311 0.63655E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.49 -1.76 -0.176 0.29998E+04 97 kalsilite 7.62 4.10 -3.52 -0.502 0.60023E+04 98 kaolinite -1.27 -1.43 -0.15 -0.014 0.26061E+03 99 kyanite 4.93 1.84 -3.09 -0.309 0.52744E+04 101 laumontite 2.97 2.40 -0.58 -0.038 0.98223E+03 102 lawsonite 9.68 8.94 -0.74 -0.049 0.12675E+04 103 leucite 4.17 0.84 -3.33 -0.333 0.56877E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70640E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20504E+04 108 minnesotaite 10.46 5.93 -4.53 -0.267 0.77371E+04 113 margarite 17.45 14.05 -3.40 -0.136 0.58135E+04 122 nepheline 8.38 5.76 -2.62 -0.374 0.44663E+04 134 phlogopite-Na 29.73 24.91 -4.82 -0.268 0.82277E+04 136 prehnite 19.47 16.03 -3.44 -0.202 0.58683E+04 137 prehnite-Fe 22.59 19.77 -2.81 -0.169 0.48048E+04 145 pyroxmangite 7.42 5.19 -2.22 -0.445 0.37978E+04 146 pyrophyllite -6.10 -7.96 -1.86 -0.117 0.31836E+04 147 quartz -2.98 -3.27 -0.29 -0.095 0.48899E+03 151 rhodochrosite -0.96 -5.71 -4.76 -1.585 0.81212E+04 152 rhodonite 7.46 5.19 -2.27 -0.454 0.38770E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.84 -3.48 -0.348 0.59398E+04 164 stilpnomelane-Fe 13.18 13.04 -0.13 -0.004 0.23034E+03 165 stilpnomelane-Mg 27.60 24.18 -3.41 -0.102 0.58252E+04 168 sudoite 21.22 17.54 -3.67 -0.119 0.62743E+04 171 talc 16.55 12.61 -3.94 -0.232 0.67271E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76168E+04 177 topaz-H 4.67 1.84 -2.82 -0.257 0.48235E+04 178 tridymite -2.61 -3.27 -0.65 -0.218 0.11163E+04 187 wairakite 4.06 2.40 -1.66 -0.098 0.28330E+04 188 walstromite 11.53 7.09 -4.43 -0.887 0.75717E+04 189 wollastonite 10.48 7.09 -3.39 -0.678 0.57856E+04 190 pseudo-wollastonite 11.02 7.09 -3.93 -0.785 0.67042E+04 191 zoisite 22.96 18.58 -4.38 -0.199 0.74764E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.33 -2.77 -0.171 0.47319E+04 194 beidellite-H -2.24 -6.04 -3.80 -0.242 0.64876E+04 195 beidellite-K -1.44 -4.45 -3.02 -0.185 0.51493E+04 196 beidellite-Mg -1.71 -4.63 -2.92 -0.181 0.49875E+04 197 beidellite-Na -1.26 -3.90 -2.65 -0.162 0.45193E+04 199 chalcedony -2.79 -3.27 -0.47 -0.158 0.80931E+03 201 montmorillonite-Ca -2.21 -4.27 -2.06 -0.127 0.35115E+04 202 montmorillonite-K -2.16 -4.39 -2.23 -0.137 0.38066E+04 203 montmorillonite-Mg -2.40 -4.57 -2.17 -0.134 0.36981E+04 204 montmorillonite-Na -1.96 -3.84 -1.88 -0.115 0.32148E+04 205 nontronite-Ca 3.28 3.16 -0.12 -0.008 0.21169E+03 206 nontronite-H 2.60 1.45 -1.15 -0.077 0.19632E+04 207 nontronite-K 3.40 3.04 -0.37 -0.024 0.62827E+03 208 nontronite-Mg 3.14 2.86 -0.28 -0.018 0.47892E+03 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.30331E-11 224 tobermorite 9.84 5.36 -4.48 -1.221 0.76426E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.872 0.59589E+04 240 silica-amorphous -2.08 -3.27 -1.19 -0.396 0.20295E+04 242 an20ab80 2.08 1.17 -0.91 -0.070 0.15563E+04 243 an25ab75 2.71 1.65 -1.06 -0.081 0.18029E+04 244 an30ab70 3.34 2.14 -1.21 -0.093 0.20579E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.5990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1392949E-02 Osmotic coef. = 0.9787 True ionic strength = .2189922E-02 Chg. balance for total moles = 0.4570E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.69200E-09 -9.1599 0.64055E-09 -9.1934 0.92565E+00 -0.0336 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12757E-03 -3.8943 0.92483E+00 -0.0339 4 SO4-- 0.25498E-04 -4.5935 0.19719E-04 -4.7051 0.77334E+00 -0.1116 5 HCO3- 0.11137E-04 -4.9532 0.10302E-04 -4.9871 0.92503E+00 -0.0338 6 HS- 0.27038E-13 -13.5680 0.25006E-13 -13.6019 0.92485E+00 -0.0339 7 Al+++ 0.16499E-24 -24.7825 0.94439E-25 -25.0248 0.57239E+00 -0.2423 8 H4SiO4 0.53581E-03 -3.2710 0.53581E-03 -3.2710 0.10000E+01 0.0000 9 Ca++ 0.12743E-07 -7.8947 0.98439E-08 -8.0068 0.77252E+00 -0.1121 10 Mg++ 0.19472E-09 -9.7106 0.15033E-09 -9.8230 0.77200E+00 -0.1124 11 Fe++ 0.11516E-11 -11.9387 0.88917E-12 -12.0510 0.77212E+00 -0.1123 12 K+ 0.46350E-04 -4.3339 0.42877E-04 -4.3678 0.92506E+00 -0.0338 13 Na+ 0.21067E-02 -2.6764 0.19483E-02 -2.7103 0.92481E+00 -0.0339 14 Mn++ 0.15386E-09 -9.8129 0.11882E-09 -9.9251 0.77222E+00 -0.1123 15 HPO4-- 0.93601E-05 -5.0287 0.72386E-05 -5.1403 0.77335E+00 -0.1116 16 HSiO3- 0.88247E-03 -3.0543 0.81614E-03 -3.0882 0.92483E+00 -0.0339 17 Ca(HSiO3)+ 0.19458E-09 -9.7109 0.18000E-09 -9.7447 0.92509E+00 -0.0338 18 Mg(HSiO3)+ 0.36980E-11 -11.4320 0.34210E-11 -11.4659 0.92509E+00 -0.0338 19 NaHSiO3,aq 0.25254E-04 -4.5977 0.25254E-04 -4.5977 0.10000E+01 0.0000 20 AlO+ 0.32120E-13 -13.4932 0.29714E-13 -13.5270 0.92509E+00 -0.0338 21 AlOH+2 0.12345E-18 -18.9085 0.95345E-19 -19.0207 0.77233E+00 -0.1122 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.34998E-04 -4.4560 0.32358E-04 -4.4900 0.92459E+00 -0.0341 24 CH4,aq 0.12825E-19 -19.8919 0.12820E-19 -19.8921 0.99957E+00 -0.0002 29 CO,aq 0.15307E-18 -18.8151 0.15307E-18 -18.8151 0.10000E+01 0.0000 30 CO2,aq 0.13311E-07 -7.8758 0.13305E-07 -7.8760 0.99957E+00 -0.0002 31 CO3-2 0.19235E-05 -5.7159 0.14870E-05 -5.8277 0.77309E+00 -0.1118 32 CaCO3,aq 0.17928E-09 -9.7465 0.17928E-09 -9.7465 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.27622E-11 -11.5587 0.25553E-11 -11.5926 0.92509E+00 -0.0338 34 CaCl+ 0.21631E-11 -11.6649 0.20010E-11 -11.6987 0.92509E+00 -0.0338 35 CaCl2,aq 0.59435E-16 -16.2260 0.59435E-16 -16.2260 0.10000E+01 0.0000 36 CaOH+ 0.11714E-08 -8.9313 0.10836E-08 -8.9651 0.92509E+00 -0.0338 37 CaSO4,aq 0.60479E-10 -10.2184 0.60479E-10 -10.2184 0.10000E+01 0.0000 38 HCl,aq 0.15370E-13 -13.8133 0.15370E-13 -13.8133 0.10000E+01 0.0000 43 FeCl+ 0.19097E-15 -15.7190 0.17667E-15 -15.7528 0.92509E+00 -0.0338 46 FeO,aq 0.85696E-10 -10.0670 0.85696E-10 -10.0670 0.10000E+01 0.0000 47 FeOH+ 0.49747E-10 -10.3032 0.46020E-10 -10.3371 0.92509E+00 -0.0338 48 HFeO2- 0.15560E-08 -8.8080 0.14390E-08 -8.8419 0.92483E+00 -0.0339 49 FeO+ 0.57278E-14 -14.2420 0.52987E-14 -14.2758 0.92509E+00 -0.0338 51 FeO2- 0.27444E-08 -8.5615 0.25382E-08 -8.5955 0.92483E+00 -0.0339 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44690E-09 -9.3498 0.44670E-09 -9.3500 0.99957E+00 -0.0002 54 KCl,aq 0.96848E-10 -10.0139 0.96848E-10 -10.0139 0.10000E+01 0.0000 55 KHSO4,aq 0.14492E-17 -17.8389 0.14492E-17 -17.8389 0.10000E+01 0.0000 56 KOH,aq 0.29181E-07 -7.5349 0.29181E-07 -7.5349 0.10000E+01 0.0000 57 KSO4- 0.14084E-07 -7.8513 0.13026E-07 -7.8852 0.92483E+00 -0.0339 58 MgCO3,aq 0.68413E-12 -12.1649 0.68413E-12 -12.1649 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.43014E-13 -13.3664 0.39792E-13 -13.4002 0.92509E+00 -0.0338 60 MgCl+ 0.29987E-13 -13.5231 0.27741E-13 -13.5569 0.92509E+00 -0.0338 61 MgOH+ 0.99101E-10 -10.0039 0.91678E-10 -10.0377 0.92509E+00 -0.0338 63 MnO,aq 0.30569E-09 -9.5147 0.30569E-09 -9.5147 0.10000E+01 0.0000 64 MnOH+ 0.61752E-09 -9.2093 0.57126E-09 -9.2432 0.92509E+00 -0.0338 65 MnO2-2 0.33328E-13 -13.4772 0.25766E-13 -13.5890 0.77309E+00 -0.1118 66 HMnO2- 0.38665E-11 -11.4127 0.35759E-11 -11.4466 0.92483E+00 -0.0339 69 MnCl+ 0.99161E-13 -13.0037 0.91733E-13 -13.0375 0.92509E+00 -0.0338 70 MnSO4,aq 0.66397E-12 -12.1778 0.66397E-12 -12.1778 0.10000E+01 0.0000 71 NaCl,aq 0.81154E-07 -7.0907 0.81154E-07 -7.0907 0.10000E+01 0.0000 72 NaOH,aq 0.13365E-05 -5.8740 0.13365E-05 -5.8740 0.10000E+01 0.0000 74 OH- 0.10128E-02 -2.9945 0.93644E-03 -3.0285 0.92459E+00 -0.0341 79 HPO3-2 0.13211E-16 -16.8791 0.10213E-16 -16.9908 0.77309E+00 -0.1118 81 H2PO3- 0.13895E-19 -19.8571 0.12851E-19 -19.8911 0.92483E+00 -0.0339 82 H3PO4,aq 0.19121E-13 -13.7185 0.19121E-13 -13.7185 0.10000E+01 0.0000 83 H2PO4- 0.87886E-07 -7.0561 0.81291E-07 -7.0900 0.92496E+00 -0.0339 84 PO4-3 0.17118E-07 -7.7665 0.98690E-08 -8.0057 0.57653E+00 -0.2392 87 H2P2O7-2 0.66899E-15 -15.1746 0.51719E-15 -15.2863 0.77309E+00 -0.1118 88 HP2O7-3 0.28923E-12 -12.5388 0.16556E-12 -12.7810 0.57243E+00 -0.2423 89 P2O7-4 0.16889E-12 -12.7724 0.63764E-13 -13.1954 0.37756E+00 -0.4230 90 H2S,aq 0.48147E-16 -16.3174 0.48127E-16 -16.3176 0.99957E+00 -0.0002 97 SO3-2 0.15502E-14 -14.8096 0.12010E-14 -14.9205 0.77474E+00 -0.1108 98 HSO3- 0.48680E-16 -16.3126 0.45021E-16 -16.3466 0.92483E+00 -0.0339 99 HSO4- 0.12667E-10 -10.8973 0.11720E-10 -10.9311 0.92522E+00 -0.0338 Charge balance for all species = 0.4588E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6919996E-09 -.2063780E-02 -.2079753E+01 0.0000 2 H2O 0.1000000E+01 0.5550843E+02 0.9998025E+06 0.0000 3 Cl- 0.1379348E-03 0.1380160E-03 0.4892111E+01 5.2992 4 SO4-- 0.2549805E-04 0.2551246E-04 0.2450281E+01 13.6818 5 HCO3- 0.1113698E-04 0.1307396E-04 0.7975783E+00 4.2064 6 HS- 0.2703823E-13 -.2567386E-09 -.8489176E-05 -4.4085 7 Al+++ 0.1649920E-24 0.3500708E-04 0.9443561E+00 2.5555 8 H4SiO4 0.5358133E-03 0.1443536E-02 0.1387185E+03 -3.2710 9 Ca++ 0.1274257E-07 0.1435320E-07 0.5751335E-03 10.3801 10 Mg++ 0.1947229E-09 0.2982794E-09 0.7250330E-05 8.5639 11 Fe++ 0.1151590E-11 0.4640474E-08 0.2591051E-03 6.3359 12 K+ 0.4635022E-04 0.4639358E-04 0.1813722E+01 4.8257 13 Na+ 0.2106697E-02 0.2133369E-02 0.4903600E+02 6.4831 14 Mn++ 0.1538626E-09 0.1081736E-08 0.5941660E-04 8.4618 15 HPO4-- 0.9360069E-05 0.9465074E-05 0.9082681E+00 13.2465 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2646403E-01 -.2063154E-02 -.2440087E-01 0.0000000E+00 2 H2O 0.5548821E+02 0.5549160E+02 -.3394998E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6981821E-04 0.2550473E-04 0.4431348E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4431374E-04 -.2566608E-09 -.4431348E-04 0.0000000E+00 7 Al+++ 0.5213926E-02 0.3499647E-04 0.5178929E-02 0.0000000E+00 8 H4SiO4 0.1665004E-01 0.1443099E-02 0.1520694E-01 0.0000000E+00 9 Ca++ 0.1853549E-02 0.1434885E-07 0.1853535E-02 0.0000000E+00 10 Mg++ 0.1269048E-02 0.2981890E-09 0.1269047E-02 0.0000000E+00 11 Fe++ 0.1140101E-02 0.4639067E-08 0.1140096E-02 0.0000000E+00 12 K+ 0.3394904E-03 0.4637952E-04 0.2931109E-03 0.0000000E+00 13 Na+ 0.2167206E-02 0.2132722E-02 0.3448314E-04 0.0000000E+00 14 Mn++ 0.2772441E-04 0.1081408E-08 0.2772333E-04 0.0000000E+00 15 HPO4-- 0.9462205E-05 0.9462205E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.6641E-18 Mass of aqueous solution: 0.999895E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2538E-03 -3.595 0.1411 -0.851 8.294 0.5366E-01 daphnite 0.1571E-03 -3.804 0.1121 -0.950 6.591 0.3397E-01 chlorite-Mn 0.5545E-05 -5.256 0.3931E-02 -2.405 0.2311 0.1253E-02 hematite 0.1773E-03 -3.751 0.2831E-01 -1.548 1.664 0.5365E-02 microcline 0.1719E-03 -3.765 0.4786E-01 -1.320 2.813 0.1869E-01 muscovite 0.1212E-03 -3.917 0.4827E-01 -1.316 2.838 0.1707E-01 paragonite 0.3448E-04 -4.462 0.1318E-01 -1.880 0.7748 0.4556E-02 stilbite 0.1854E-02 -2.732 1.306 0.116 76.79 0.6092 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.700943 g Volume = 0.743813 cm3 Porosity: 54.6345% V(tot) - V(min): 0.89579E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.5990000 g log = 0.2038 Original solution: 1000.0103000 g Original solution / Rock added: 625.40 (Water/Rock Ratio), log = 2.7962 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1437E-05 1.0073 0.1523E-05 0.1512E-05 CH4,gas 0.1903E-16 1.0129 0.2027E-16 0.2001E-16 H2,gas 0.5821E-06 1.0006 0.6127E-06 0.6123E-06 H2S,gas 0.1340E-14 0.9959 0.1404E-14 0.1409E-14 S2,gas 0.1869E-36 1.0000 0.1966E-36 0.1966E-36 CO,gas 0.2298E-15 1.0000 0.2417E-15 0.2417E-15 SO3,gas 0.2875E-38 1.0000 0.3025E-38 0.3025E-38 SO2,gas 0.6665E-22 1.0000 0.7011E-22 0.7011E-22 HCl,gas 0.2580E-16 1.0000 0.2714E-16 0.2714E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.18 -7.82 -2.606 0.13348E+05 -5.817 3 CH4,gas 4.81 -13.88 -18.69 -4.673 0.31918E+05 -16.693 4 H2,gas 8.29 0.07 -8.21 -4.693 0.14023E+05 -6.213 5 H2S,gas -5.94 -22.80 -16.85 -8.426 0.28776E+05 -14.853 6 S2,gas -7.03 -45.74 -38.71 -5.955 0.66090E+05 -36.706 7 CO,gas 3.51 -14.11 -17.62 -5.421 0.30080E+05 -15.617 8 SO3,gas 17.43 -23.09 -40.52 -10.130 0.69186E+05 -38.519 9 SO2,gas 1.14 -23.02 -24.15 -6.441 0.41243E+05 -22.154 10 HCl,gas 5.48 -13.09 -18.57 -9.283 0.31702E+05 -16.566 11 acmite 7.74 6.24 -1.50 -0.156 0.25569E+04 15 albite-high 0.75 -0.77 -1.52 -0.117 0.26022E+04 16 albite -0.33 -0.77 -0.45 -0.034 0.76153E+03 19 spessartine 24.55 20.68 -3.87 -0.193 0.66021E+04 20 analcite 3.37 2.50 -0.87 -0.097 0.14924E+04 21 andalusite 5.06 1.84 -3.22 -0.322 0.55021E+04 26 annite 20.21 16.58 -3.63 -0.202 0.62041E+04 27 phlogopite 27.15 23.26 -3.89 -0.216 0.66363E+04 29 anorthite 12.80 8.95 -3.85 -0.296 0.65714E+04 32 apatite-OH -17.99 -18.68 -0.69 -0.053 0.11827E+04 35 aragonite 0.99 -3.80 -4.79 -1.596 0.81731E+04 36 brucite 12.58 8.56 -4.01 -0.803 0.68515E+04 37 calcite 0.83 -3.80 -4.63 -1.545 0.79118E+04 38 carnegieite-low 9.06 5.77 -3.30 -0.471 0.56294E+04 39 carnegieite-high 10.13 5.77 -4.37 -0.624 0.74563E+04 40 carpholite-Mg 8.65 7.13 -1.52 -0.101 0.25910E+04 41 carpholite-Fe 6.78 4.90 -1.88 -0.125 0.32066E+04 42 celadonite 5.40 2.86 -2.54 -0.149 0.43359E+04 43 celadonite-Fe 3.94 0.63 -3.30 -0.194 0.56412E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81746E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.190 0.48788E+04 51 chloritoid-Fe 9.24 8.18 -1.06 -0.071 0.18147E+04 52 chloritoid-Mn 11.46 10.30 -1.16 -0.077 0.19831E+04 54 coesite -2.37 -3.27 -0.90 -0.301 0.15395E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.27 -0.72 -0.241 0.12324E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.40 -3.81 -0.381 0.65114E+04 68 hedenbergite 14.24 10.17 -4.07 -0.407 0.69502E+04 75 epidote 24.78 22.36 -2.42 -0.117 0.41291E+04 76 clinozoisite 22.92 18.61 -4.31 -0.196 0.73549E+04 77 epidote-Fe 29.94 26.10 -3.84 -0.199 0.65507E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79879E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.47 -3.73 -0.311 0.63664E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.50 -1.75 -0.175 0.29954E+04 97 kalsilite 7.62 4.11 -3.51 -0.501 0.59934E+04 98 kaolinite -1.27 -1.43 -0.16 -0.014 0.26951E+03 99 kyanite 4.93 1.84 -3.09 -0.309 0.52789E+04 101 laumontite 2.97 2.41 -0.57 -0.038 0.96889E+03 102 lawsonite 9.68 8.95 -0.73 -0.049 0.12453E+04 103 leucite 4.17 0.84 -3.33 -0.333 0.56832E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70648E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20478E+04 108 minnesotaite 10.46 5.92 -4.54 -0.267 0.77469E+04 113 margarite 17.45 14.06 -3.39 -0.136 0.57913E+04 122 nepheline 8.38 5.77 -2.61 -0.373 0.44574E+04 134 phlogopite-Na 29.73 24.92 -4.81 -0.267 0.82197E+04 136 prehnite 19.47 16.06 -3.41 -0.200 0.58194E+04 137 prehnite-Fe 22.59 19.80 -2.79 -0.168 0.47558E+04 145 pyroxmangite 7.42 5.19 -2.23 -0.445 0.37996E+04 146 pyrophyllite -6.10 -7.97 -1.87 -0.117 0.32014E+04 147 quartz -2.98 -3.27 -0.29 -0.096 0.49344E+03 151 rhodochrosite -0.96 -5.72 -4.76 -1.587 0.81280E+04 152 rhodonite 7.46 5.19 -2.27 -0.454 0.38788E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.84 -3.48 -0.348 0.59443E+04 164 stilpnomelane-Fe 13.18 13.04 -0.14 -0.004 0.24591E+03 165 stilpnomelane-Mg 27.60 24.18 -3.42 -0.102 0.58407E+04 168 sudoite 21.22 17.54 -3.68 -0.119 0.62823E+04 171 talc 16.55 12.61 -3.95 -0.232 0.67369E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76159E+04 177 topaz-H 4.67 1.84 -2.83 -0.257 0.48280E+04 178 tridymite -2.61 -3.27 -0.66 -0.219 0.11207E+04 187 wairakite 4.06 2.41 -1.65 -0.097 0.28197E+04 188 walstromite 11.53 7.11 -4.42 -0.884 0.75450E+04 189 wollastonite 10.48 7.11 -3.37 -0.675 0.57589E+04 190 pseudo-wollastonite 11.02 7.11 -3.91 -0.782 0.66775E+04 191 zoisite 22.96 18.61 -4.35 -0.198 0.74275E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.34 -2.78 -0.172 0.47431E+04 194 beidellite-H -2.24 -6.05 -3.81 -0.243 0.65040E+04 195 beidellite-K -1.44 -4.46 -3.02 -0.185 0.51612E+04 196 beidellite-Mg -1.71 -4.64 -2.93 -0.181 0.50034E+04 197 beidellite-Na -1.26 -3.91 -2.65 -0.163 0.45312E+04 199 chalcedony -2.79 -3.27 -0.48 -0.159 0.81375E+03 201 montmorillonite-Ca -2.21 -4.28 -2.06 -0.128 0.35233E+04 202 montmorillonite-K -2.16 -4.40 -2.24 -0.137 0.38191E+04 203 montmorillonite-Mg -2.40 -4.58 -2.18 -0.135 0.37146E+04 204 montmorillonite-Na -1.96 -3.85 -1.89 -0.116 0.32273E+04 205 nontronite-Ca 3.28 3.15 -0.13 -0.008 0.22288E+03 206 nontronite-H 2.60 1.44 -1.16 -0.078 0.19795E+04 207 nontronite-K 3.40 3.03 -0.37 -0.024 0.64019E+03 208 nontronite-Mg 3.14 2.85 -0.29 -0.019 0.49481E+03 209 nontronite-Na 3.58 3.58 -0.01 0.000 0.11922E+02 224 tobermorite 9.84 5.38 -4.46 -1.218 0.76211E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.34 -3.49 -0.872 0.59562E+04 240 silica-amorphous -2.08 -3.27 -1.19 -0.397 0.20340E+04 242 an20ab80 2.08 1.17 -0.91 -0.070 0.15519E+04 243 an25ab75 2.71 1.66 -1.05 -0.081 0.17974E+04 244 an30ab70 3.34 2.14 -1.20 -0.092 0.20512E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.5990000 g New total amount of reactant added: 1.6390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4570E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.6390000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1416933E-02 Osmotic coef. = 0.9785 True ionic strength = .2228254E-02 Chg. balance for total moles = 0.4570E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.67513E-09 -9.1706 0.62463E-09 -9.2044 0.92521E+00 -0.0338 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12750E-03 -3.8945 0.92438E+00 -0.0342 4 SO4-- 0.25498E-04 -4.5935 0.19680E-04 -4.7060 0.77184E+00 -0.1125 5 HCO3- 0.11093E-04 -4.9549 0.10257E-04 -4.9890 0.92458E+00 -0.0341 6 HS- 0.28167E-13 -13.5503 0.26037E-13 -13.5844 0.92440E+00 -0.0341 7 Al+++ 0.15367E-24 -24.8134 0.87572E-25 -25.0576 0.56987E+00 -0.2442 8 H4SiO4 0.52833E-03 -3.2771 0.52833E-03 -3.2771 0.10000E+01 0.0000 9 Ca++ 0.13397E-07 -7.8730 0.10329E-07 -7.9859 0.77101E+00 -0.1129 10 Mg++ 0.18710E-09 -9.7279 0.14416E-09 -9.8412 0.77048E+00 -0.1132 11 Fe++ 0.11065E-11 -11.9560 0.85269E-12 -12.0692 0.77061E+00 -0.1132 12 K+ 0.47169E-04 -4.3263 0.43613E-04 -4.3604 0.92461E+00 -0.0340 13 Na+ 0.21439E-02 -2.6688 0.19818E-02 -2.7030 0.92436E+00 -0.0342 14 Mn++ 0.14784E-09 -9.8302 0.11394E-09 -9.9433 0.77070E+00 -0.1131 15 HPO4-- 0.95961E-05 -5.0179 0.74068E-05 -5.1304 0.77185E+00 -0.1125 16 HSiO3- 0.89276E-03 -3.0493 0.82525E-03 -3.0834 0.92438E+00 -0.0342 17 Ca(HSiO3)+ 0.20655E-09 -9.6850 0.19098E-09 -9.7190 0.92464E+00 -0.0340 18 Mg(HSiO3)+ 0.35876E-11 -11.4452 0.33172E-11 -11.4792 0.92464E+00 -0.0340 19 NaHSiO3,aq 0.25975E-04 -4.5854 0.25975E-04 -4.5854 0.10000E+01 0.0000 20 AlO+ 0.31337E-13 -13.5039 0.28975E-13 -13.5380 0.92464E+00 -0.0340 21 AlOH+2 0.11762E-18 -18.9295 0.90665E-19 -19.0426 0.77081E+00 -0.1131 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.35908E-04 -4.4448 0.33183E-04 -4.4791 0.92413E+00 -0.0343 24 CH4,aq 0.13321E-19 -19.8755 0.13315E-19 -19.8757 0.99956E+00 -0.0002 29 CO,aq 0.15114E-18 -18.8206 0.15114E-18 -18.8206 0.10000E+01 0.0000 30 CO2,aq 0.12923E-07 -7.8886 0.12917E-07 -7.8888 0.99956E+00 -0.0002 31 CO3-2 0.19676E-05 -5.7061 0.15182E-05 -5.8187 0.77159E+00 -0.1126 32 CaCO3,aq 0.19206E-09 -9.7166 0.19206E-09 -9.7166 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.28870E-11 -11.5396 0.26694E-11 -11.5736 0.92464E+00 -0.0340 34 CaCl+ 0.22696E-11 -11.6440 0.20986E-11 -11.6781 0.92464E+00 -0.0340 35 CaCl2,aq 0.62302E-16 -16.2055 0.62302E-16 -16.2055 0.10000E+01 0.0000 36 CaOH+ 0.12610E-08 -8.8993 0.11660E-08 -8.9333 0.92464E+00 -0.0340 37 CaSO4,aq 0.63337E-10 -10.1983 0.63337E-10 -10.1983 0.10000E+01 0.0000 38 HCl,aq 0.14981E-13 -13.8245 0.14981E-13 -13.8245 0.10000E+01 0.0000 43 FeCl+ 0.18313E-15 -15.7372 0.16933E-15 -15.7713 0.92464E+00 -0.0340 46 FeO,aq 0.86422E-10 -10.0634 0.86422E-10 -10.0634 0.10000E+01 0.0000 47 FeOH+ 0.48945E-10 -10.3103 0.45257E-10 -10.3443 0.92464E+00 -0.0340 48 HFeO2- 0.16099E-08 -8.7932 0.14882E-08 -8.8273 0.92438E+00 -0.0342 49 FeO+ 0.55882E-14 -14.2527 0.51670E-14 -14.2868 0.92464E+00 -0.0340 51 FeO2- 0.28158E-08 -8.5504 0.26028E-08 -8.5846 0.92438E+00 -0.0342 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.45451E-09 -9.3425 0.45431E-09 -9.3427 0.99956E+00 -0.0002 54 KCl,aq 0.98463E-10 -10.0067 0.98463E-10 -10.0067 0.10000E+01 0.0000 55 KHSO4,aq 0.14347E-17 -17.8432 0.14347E-17 -17.8432 0.10000E+01 0.0000 56 KOH,aq 0.30439E-07 -7.5166 0.30439E-07 -7.5166 0.10000E+01 0.0000 57 KSO4- 0.14305E-07 -7.8445 0.13224E-07 -7.8787 0.92438E+00 -0.0342 58 MgCO3,aq 0.66981E-12 -12.1740 0.66981E-12 -12.1740 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.41087E-13 -13.3863 0.37991E-13 -13.4203 0.92464E+00 -0.0340 60 MgCl+ 0.28757E-13 -13.5413 0.26590E-13 -13.5753 0.92464E+00 -0.0340 61 MgOH+ 0.97505E-10 -10.0110 0.90157E-10 -10.0450 0.92464E+00 -0.0340 63 MnO,aq 0.30828E-09 -9.5111 0.30828E-09 -9.5111 0.10000E+01 0.0000 64 MnOH+ 0.60757E-09 -9.2164 0.56179E-09 -9.2504 0.92464E+00 -0.0340 65 MnO2-2 0.35414E-13 -13.4508 0.27326E-13 -13.5634 0.77159E+00 -0.1126 66 HMnO2- 0.40006E-11 -11.3979 0.36981E-11 -11.4320 0.92438E+00 -0.0342 69 MnCl+ 0.95092E-13 -13.0219 0.87926E-13 -13.0559 0.92464E+00 -0.0340 70 MnSO4,aq 0.63550E-12 -12.1969 0.63550E-12 -12.1969 0.10000E+01 0.0000 71 NaCl,aq 0.82507E-07 -7.0835 0.82507E-07 -7.0835 0.10000E+01 0.0000 72 NaOH,aq 0.13941E-05 -5.8557 0.13941E-05 -5.8557 0.10000E+01 0.0000 74 OH- 0.10391E-02 -2.9833 0.96030E-03 -3.0176 0.92413E+00 -0.0343 79 HPO3-2 0.13775E-16 -16.8609 0.10628E-16 -16.9735 0.77159E+00 -0.1126 81 H2PO3- 0.14108E-19 -19.8505 0.13041E-19 -19.8847 0.92438E+00 -0.0342 82 H3PO4,aq 0.18605E-13 -13.7304 0.18605E-13 -13.7304 0.10000E+01 0.0000 83 H2PO4- 0.87736E-07 -7.0568 0.81112E-07 -7.0909 0.92451E+00 -0.0341 84 PO4-3 0.18039E-07 -7.7438 0.10356E-07 -7.9848 0.57407E+00 -0.2410 87 H2P2O7-2 0.66735E-15 -15.1756 0.51492E-15 -15.2883 0.77159E+00 -0.1126 88 HP2O7-3 0.29660E-12 -12.5278 0.16904E-12 -12.7720 0.56992E+00 -0.2442 89 P2O7-4 0.17820E-12 -12.7491 0.66762E-13 -13.1755 0.37464E+00 -0.4264 90 H2S,aq 0.48887E-16 -16.3108 0.48865E-16 -16.3110 0.99956E+00 -0.0002 97 SO3-2 0.15765E-14 -14.8023 0.12191E-14 -14.9140 0.77326E+00 -0.1117 98 HSO3- 0.48209E-16 -16.3169 0.44563E-16 -16.3510 0.92438E+00 -0.0342 99 HSO4- 0.12334E-10 -10.9089 0.11406E-10 -10.9429 0.92477E+00 -0.0340 Charge balance for all species = 0.4753E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6751250E-09 -.2104864E-02 -.2121152E+01 0.0000 2 H2O 0.1000000E+01 0.5550844E+02 0.9998013E+06 0.0000 3 Cl- 0.1379343E-03 0.1380169E-03 0.4892135E+01 5.3099 4 SO4-- 0.2549799E-04 0.2551264E-04 0.2450294E+01 13.7028 5 HCO3- 0.1109330E-04 0.1307405E-04 0.7975823E+00 4.2154 6 HS- 0.2816667E-13 -.2637513E-09 -.8721038E-05 -4.3800 7 Al+++ 0.1536683E-24 0.3591683E-04 0.9688962E+00 2.5555 8 H4SiO4 0.5283308E-03 0.1447066E-02 0.1390575E+03 -3.2771 9 Ca++ 0.1339681E-07 0.1512496E-07 0.6060570E-03 10.4228 10 Mg++ 0.1871017E-09 0.2889339E-09 0.7023157E-05 8.5676 11 Fe++ 0.1106515E-11 0.4765649E-08 0.2660940E-03 6.3395 12 K+ 0.4716908E-04 0.4721392E-04 0.1845790E+01 4.8440 13 Na+ 0.2143925E-02 0.2171376E-02 0.4990953E+02 6.5014 14 Mn++ 0.1478401E-09 0.1068461E-08 0.5868737E-04 8.4654 15 HPO4-- 0.9596137E-05 0.9701913E-05 0.9309937E+00 13.2784 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2712637E-01 -.2104212E-02 -.2502216E-01 0.0000000E+00 2 H2O 0.5548770E+02 0.5549125E+02 -.3547693E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7092675E-04 0.2550473E-04 0.4542201E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4542228E-04 -.2636696E-09 -.4542201E-04 0.0000000E+00 7 Al+++ 0.5344356E-02 0.3590571E-04 0.5308450E-02 0.0000000E+00 8 H4SiO4 0.1706655E-01 0.1446618E-02 0.1561993E-01 0.0000000E+00 9 Ca++ 0.1899555E-02 0.1512028E-07 0.1899540E-02 0.0000000E+00 10 Mg++ 0.1300794E-02 0.2888445E-09 0.1300793E-02 0.0000000E+00 11 Fe++ 0.1168621E-02 0.4764173E-08 0.1168616E-02 0.0000000E+00 12 K+ 0.3479830E-03 0.4719930E-04 0.3007837E-03 0.0000000E+00 13 Na+ 0.2217415E-02 0.2170704E-02 0.4671133E-04 0.0000000E+00 14 Mn++ 0.2841796E-04 0.1068130E-08 0.2841689E-04 0.0000000E+00 15 HPO4-- 0.9698908E-05 0.9698908E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1409E-17 Mass of aqueous solution: 0.999890E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.6390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2602E-03 -3.585 0.1446 -0.840 8.284 0.5500E-01 daphnite 0.1610E-03 -3.793 0.1149 -0.940 6.583 0.3482E-01 chlorite-Mn 0.5683E-05 -5.245 0.4029E-02 -2.395 0.2308 0.1284E-02 hematite 0.1817E-03 -3.741 0.2902E-01 -1.537 1.662 0.5500E-02 microcline 0.1934E-03 -3.713 0.5384E-01 -1.269 3.084 0.2103E-01 muscovite 0.1073E-03 -3.969 0.4275E-01 -1.369 2.449 0.1512E-01 paragonite 0.4671E-04 -4.331 0.1785E-01 -1.748 1.023 0.6171E-02 stilbite 0.1900E-02 -2.721 1.339 0.127 76.68 0.6244 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.745652 g Volume = 0.763297 cm3 Porosity: 53.8960% V(tot) - V(min): 0.89230E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.6390000 g log = 0.2146 Original solution: 1000.0103000 g Original solution / Rock added: 610.13 (Water/Rock Ratio), log = 2.7854 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1395E-05 1.0073 0.1479E-05 0.1468E-05 CH4,gas 0.1976E-16 1.0129 0.2106E-16 0.2079E-16 H2,gas 0.5920E-06 1.0006 0.6231E-06 0.6228E-06 H2S,gas 0.1360E-14 0.9959 0.1425E-14 0.1431E-14 S2,gas 0.1863E-36 1.0000 0.1959E-36 0.1959E-36 CO,gas 0.2269E-15 1.0000 0.2387E-15 0.2387E-15 SO3,gas 0.2729E-38 1.0000 0.2871E-38 0.2871E-38 SO2,gas 0.6433E-22 1.0000 0.6767E-22 0.6767E-22 HCl,gas 0.2515E-16 1.0000 0.2645E-16 0.2645E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.19 -7.83 -2.610 0.13370E+05 -5.830 3 CH4,gas 4.81 -13.87 -18.68 -4.669 0.31890E+05 -16.677 4 H2,gas 8.29 0.08 -8.21 -4.689 0.14011E+05 -6.205 5 H2S,gas -5.94 -22.79 -16.85 -8.423 0.28764E+05 -14.846 6 S2,gas -7.03 -45.74 -38.71 -5.955 0.66093E+05 -36.708 7 CO,gas 3.51 -14.11 -17.62 -5.422 0.30089E+05 -15.622 8 SO3,gas 17.43 -23.11 -40.54 -10.136 0.69224E+05 -38.542 9 SO2,gas 1.14 -23.03 -24.17 -6.445 0.41269E+05 -22.170 10 HCl,gas 5.48 -13.10 -18.58 -9.289 0.31721E+05 -16.578 11 acmite 7.74 6.25 -1.49 -0.155 0.25464E+04 15 albite-high 0.75 -0.77 -1.52 -0.117 0.26022E+04 16 albite -0.33 -0.77 -0.45 -0.034 0.76153E+03 19 spessartine 24.55 20.68 -3.87 -0.194 0.66146E+04 20 analcite 3.37 2.50 -0.87 -0.096 0.14819E+04 21 andalusite 5.06 1.83 -3.23 -0.323 0.55125E+04 26 annite 20.21 16.59 -3.62 -0.201 0.61853E+04 27 phlogopite 27.15 23.27 -3.88 -0.215 0.66175E+04 29 anorthite 12.80 8.98 -3.82 -0.294 0.65192E+04 32 apatite-OH -17.99 -18.50 -0.51 -0.040 0.87855E+03 35 aragonite 0.99 -3.77 -4.76 -1.586 0.81221E+04 36 brucite 12.58 8.57 -4.01 -0.802 0.68453E+04 37 calcite 0.83 -3.77 -4.60 -1.535 0.78607E+04 38 carnegieite-low 9.06 5.78 -3.28 -0.469 0.56086E+04 39 carnegieite-high 10.13 5.78 -4.35 -0.622 0.74354E+04 40 carpholite-Mg 8.65 7.12 -1.53 -0.102 0.26056E+04 41 carpholite-Fe 6.78 4.90 -1.89 -0.126 0.32212E+04 42 celadonite 5.40 2.86 -2.54 -0.150 0.43401E+04 43 celadonite-Fe 3.94 0.63 -3.31 -0.194 0.56454E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81766E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.191 0.48829E+04 51 chloritoid-Fe 9.24 8.17 -1.07 -0.071 0.18189E+04 52 chloritoid-Mn 11.46 10.30 -1.16 -0.078 0.19873E+04 54 coesite -2.37 -3.28 -0.91 -0.303 0.15499E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.28 -0.73 -0.243 0.12428E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.44 -3.78 -0.378 0.64530E+04 68 hedenbergite 14.24 10.21 -4.04 -0.404 0.68918E+04 75 epidote 24.78 22.42 -2.35 -0.114 0.40144E+04 76 clinozoisite 22.92 18.68 -4.24 -0.193 0.72402E+04 77 epidote-Fe 29.94 26.17 -3.77 -0.196 0.64360E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79858E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63685E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.50 -1.75 -0.175 0.29850E+04 97 kalsilite 7.62 4.12 -3.50 -0.500 0.59725E+04 98 kaolinite -1.27 -1.44 -0.17 -0.015 0.29037E+03 99 kyanite 4.93 1.83 -3.10 -0.310 0.52893E+04 101 laumontite 2.97 2.43 -0.55 -0.037 0.93760E+03 102 lawsonite 9.68 8.98 -0.70 -0.047 0.11931E+04 103 leucite 4.17 0.85 -3.32 -0.332 0.56728E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70669E+04 107 magnetite 20.13 18.94 -1.20 -0.098 0.20415E+04 108 minnesotaite 10.46 5.91 -4.55 -0.268 0.77698E+04 113 margarite 17.45 14.09 -3.36 -0.134 0.57392E+04 122 nepheline 8.38 5.78 -2.60 -0.371 0.44365E+04 134 phlogopite-Na 29.73 24.93 -4.80 -0.267 0.82009E+04 136 prehnite 19.47 16.13 -3.34 -0.197 0.57047E+04 137 prehnite-Fe 22.59 19.87 -2.72 -0.163 0.46411E+04 145 pyroxmangite 7.42 5.19 -2.23 -0.446 0.38037E+04 146 pyrophyllite -6.10 -8.00 -1.90 -0.119 0.32431E+04 147 quartz -2.98 -3.28 -0.30 -0.098 0.50387E+03 151 rhodochrosite -0.96 -5.73 -4.77 -1.590 0.81436E+04 152 rhodonite 7.46 5.19 -2.27 -0.455 0.38830E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.83 -3.49 -0.349 0.59547E+04 164 stilpnomelane-Fe 13.18 13.01 -0.17 -0.005 0.28241E+03 165 stilpnomelane-Mg 27.60 24.15 -3.44 -0.103 0.58772E+04 168 sudoite 21.22 17.53 -3.69 -0.119 0.63011E+04 171 talc 16.55 12.59 -3.96 -0.233 0.67598E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76138E+04 177 topaz-H 4.67 1.83 -2.83 -0.258 0.48384E+04 178 tridymite -2.61 -3.28 -0.66 -0.221 0.11312E+04 187 wairakite 4.06 2.43 -1.63 -0.096 0.27884E+04 188 walstromite 11.53 7.15 -4.38 -0.876 0.74824E+04 189 wollastonite 10.48 7.15 -3.34 -0.667 0.56963E+04 190 pseudo-wollastonite 11.02 7.15 -3.87 -0.775 0.66149E+04 191 zoisite 22.96 18.68 -4.28 -0.195 0.73128E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.35 -2.79 -0.173 0.47693E+04 194 beidellite-H -2.24 -6.07 -3.83 -0.245 0.65422E+04 195 beidellite-K -1.44 -4.47 -3.04 -0.186 0.51892E+04 196 beidellite-Mg -1.71 -4.66 -2.95 -0.183 0.50406E+04 197 beidellite-Na -1.26 -3.93 -2.67 -0.164 0.45592E+04 199 chalcedony -2.79 -3.28 -0.48 -0.161 0.82418E+03 201 montmorillonite-Ca -2.21 -4.29 -2.08 -0.129 0.35509E+04 202 montmorillonite-K -2.16 -4.41 -2.25 -0.138 0.38485E+04 203 montmorillonite-Mg -2.40 -4.60 -2.20 -0.136 0.37532E+04 204 montmorillonite-Na -1.96 -3.87 -1.91 -0.117 0.32567E+04 205 nontronite-Ca 3.28 3.13 -0.15 -0.009 0.24911E+03 206 nontronite-H 2.60 1.41 -1.18 -0.079 0.20178E+04 207 nontronite-K 3.40 3.01 -0.39 -0.025 0.66814E+03 208 nontronite-Mg 3.14 2.83 -0.31 -0.020 0.53205E+03 209 nontronite-Na 3.58 3.56 -0.02 -0.001 0.39870E+02 224 tobermorite 9.84 5.41 -4.43 -1.210 0.75708E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.34 -3.48 -0.871 0.59500E+04 240 silica-amorphous -2.08 -3.28 -1.20 -0.399 0.20444E+04 242 an20ab80 2.08 1.18 -0.90 -0.069 0.15415E+04 243 an25ab75 2.71 1.66 -1.05 -0.080 0.17843E+04 244 an30ab70 3.34 2.15 -1.19 -0.092 0.20356E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.6390000 g New total amount of reactant added: 1.6790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4570E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.6790000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1440962E-02 Osmotic coef. = 0.9784 True ionic strength = .2266626E-02 Chg. balance for total moles = 0.4570E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.65899E-09 -9.1811 0.60942E-09 -9.2151 0.92477E+00 -0.0340 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12744E-03 -3.8947 0.92393E+00 -0.0344 4 SO4-- 0.25498E-04 -4.5935 0.19642E-04 -4.7068 0.77035E+00 -0.1133 5 HCO3- 0.11050E-04 -4.9567 0.10211E-04 -4.9909 0.92413E+00 -0.0343 6 HS- 0.29321E-13 -13.5328 0.27091E-13 -13.5672 0.92395E+00 -0.0344 7 Al+++ 0.14333E-24 -24.8437 0.81327E-25 -25.0898 0.56740E+00 -0.2461 8 H4SiO4 0.52109E-03 -3.2831 0.52109E-03 -3.2831 0.10000E+01 0.0000 9 Ca++ 0.14073E-07 -7.8516 0.10829E-07 -7.9654 0.76951E+00 -0.1138 10 Mg++ 0.17993E-09 -9.7449 0.13836E-09 -9.8590 0.76898E+00 -0.1141 11 Fe++ 0.10641E-11 -11.9730 0.81841E-12 -12.0870 0.76911E+00 -0.1140 12 K+ 0.47989E-04 -4.3189 0.44350E-04 -4.3531 0.92416E+00 -0.0343 13 Na+ 0.21812E-02 -2.6613 0.20152E-02 -2.6957 0.92391E+00 -0.0344 14 Mn++ 0.14217E-09 -9.8472 0.10936E-09 -9.9611 0.76920E+00 -0.1140 15 HPO4-- 0.98322E-05 -5.0073 0.75744E-05 -5.1207 0.77037E+00 -0.1133 16 HSiO3- 0.90295E-03 -3.0443 0.83426E-03 -3.0787 0.92393E+00 -0.0344 17 Ca(HSiO3)+ 0.21902E-09 -9.6595 0.20242E-09 -9.6938 0.92419E+00 -0.0342 18 Mg(HSiO3)+ 0.34826E-11 -11.4581 0.32186E-11 -11.4923 0.92419E+00 -0.0342 19 NaHSiO3,aq 0.26702E-04 -4.5735 0.26702E-04 -4.5735 0.10000E+01 0.0000 20 AlO+ 0.30588E-13 -13.5144 0.28270E-13 -13.5487 0.92419E+00 -0.0342 21 AlOH+2 0.11218E-18 -18.9501 0.86302E-19 -19.0640 0.76932E+00 -0.1139 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.36822E-04 -4.4339 0.34012E-04 -4.4684 0.92367E+00 -0.0345 24 CH4,aq 0.13826E-19 -19.8593 0.13819E-19 -19.8595 0.99955E+00 -0.0002 29 CO,aq 0.14926E-18 -18.8261 0.14926E-18 -18.8261 0.10000E+01 0.0000 30 CO2,aq 0.12552E-07 -7.9013 0.12547E-07 -7.9015 0.99955E+00 -0.0002 31 CO3-2 0.20117E-05 -5.6964 0.15492E-05 -5.8099 0.77011E+00 -0.1134 32 CaCO3,aq 0.20548E-09 -9.6872 0.20548E-09 -9.6872 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.30148E-11 -11.5207 0.27863E-11 -11.5550 0.92419E+00 -0.0342 34 CaCl+ 0.23795E-11 -11.6235 0.21992E-11 -11.6577 0.92419E+00 -0.0342 35 CaCl2,aq 0.65255E-16 -16.1854 0.65255E-16 -16.1854 0.10000E+01 0.0000 36 CaOH+ 0.13558E-08 -8.8678 0.12530E-08 -8.9020 0.92419E+00 -0.0342 37 CaSO4,aq 0.66276E-10 -10.1786 0.66276E-10 -10.1786 0.10000E+01 0.0000 38 HCl,aq 0.14608E-13 -13.8354 0.14608E-13 -13.8354 0.10000E+01 0.0000 43 FeCl+ 0.17577E-15 -15.7551 0.16245E-15 -15.7893 0.92419E+00 -0.0342 46 FeO,aq 0.87141E-10 -10.0598 0.87141E-10 -10.0598 0.10000E+01 0.0000 47 FeOH+ 0.48173E-10 -10.3172 0.44522E-10 -10.3514 0.92419E+00 -0.0342 48 HFeO2- 0.16646E-08 -8.7787 0.15380E-08 -8.8130 0.92393E+00 -0.0344 49 FeO+ 0.54547E-14 -14.2632 0.50412E-14 -14.2975 0.92419E+00 -0.0342 51 FeO2- 0.28875E-08 -8.5395 0.26678E-08 -8.5738 0.92393E+00 -0.0344 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.46210E-09 -9.3353 0.46189E-09 -9.3355 0.99955E+00 -0.0002 54 KCl,aq 0.10008E-09 -9.9997 0.10008E-09 -9.9997 0.10000E+01 0.0000 55 KHSO4,aq 0.14206E-17 -17.8475 0.14206E-17 -17.8475 0.10000E+01 0.0000 56 KOH,aq 0.31726E-07 -7.4986 0.31726E-07 -7.4986 0.10000E+01 0.0000 57 KSO4- 0.14526E-07 -7.8379 0.13421E-07 -7.8722 0.92393E+00 -0.0344 58 MgCO3,aq 0.65602E-12 -12.1831 0.65602E-12 -12.1831 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.39280E-13 -13.4058 0.36302E-13 -13.4401 0.92419E+00 -0.0342 60 MgCl+ 0.27600E-13 -13.5591 0.25508E-13 -13.5933 0.92419E+00 -0.0342 61 MgOH+ 0.95967E-10 -10.0179 0.88693E-10 -10.0521 0.92419E+00 -0.0342 63 MnO,aq 0.31085E-09 -9.5075 0.31085E-09 -9.5075 0.10000E+01 0.0000 64 MnOH+ 0.59799E-09 -9.2233 0.55266E-09 -9.2575 0.92419E+00 -0.0342 65 MnO2-2 0.37587E-13 -13.4250 0.28946E-13 -13.5384 0.77011E+00 -0.1134 66 HMnO2- 0.41366E-11 -11.3834 0.38219E-11 -11.4177 0.92393E+00 -0.0344 69 MnCl+ 0.91268E-13 -13.0397 0.84349E-13 -13.0739 0.92419E+00 -0.0342 70 MnSO4,aq 0.60877E-12 -12.2155 0.60877E-12 -12.2155 0.10000E+01 0.0000 71 NaCl,aq 0.83858E-07 -7.0765 0.83858E-07 -7.0765 0.10000E+01 0.0000 72 NaOH,aq 0.14530E-05 -5.8377 0.14530E-05 -5.8377 0.10000E+01 0.0000 74 OH- 0.10656E-02 -2.9724 0.98428E-03 -3.0069 0.92367E+00 -0.0345 79 HPO3-2 0.14349E-16 -16.8432 0.11050E-16 -16.9566 0.77011E+00 -0.1134 81 H2PO3- 0.14318E-19 -19.8441 0.13228E-19 -19.8785 0.92393E+00 -0.0344 82 H3PO4,aq 0.18110E-13 -13.7421 0.18110E-13 -13.7421 0.10000E+01 0.0000 83 H2PO4- 0.87579E-07 -7.0576 0.80928E-07 -7.0919 0.92406E+00 -0.0343 84 PO4-3 0.18988E-07 -7.7215 0.10854E-07 -7.9644 0.57164E+00 -0.2429 87 H2P2O7-2 0.66560E-15 -15.1768 0.51258E-15 -15.2902 0.77011E+00 -0.1134 88 HP2O7-3 0.30394E-12 -12.5172 0.17247E-12 -12.7633 0.56745E+00 -0.2461 89 P2O7-4 0.18780E-12 -12.7263 0.69818E-13 -13.1560 0.37178E+00 -0.4297 90 H2S,aq 0.49626E-16 -16.3043 0.49604E-16 -16.3045 0.99955E+00 -0.0002 97 SO3-2 0.16028E-14 -14.7951 0.12371E-14 -14.9076 0.77180E+00 -0.1125 98 HSO3- 0.47751E-16 -16.3210 0.44119E-16 -16.3554 0.92393E+00 -0.0344 99 HSO4- 0.12016E-10 -10.9202 0.11107E-10 -10.9544 0.92432E+00 -0.0342 Charge balance for all species = 0.4749E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6589929E-09 -.2146010E-02 -.2162613E+01 0.0000 2 H2O 0.1000000E+01 0.5550846E+02 0.9998000E+06 0.0000 3 Cl- 0.1379339E-03 0.1380178E-03 0.4892160E+01 5.3204 4 SO4-- 0.2549793E-04 0.2551281E-04 0.2450307E+01 13.7234 5 HCO3- 0.1104965E-04 0.1307414E-04 0.7975863E+00 4.2242 6 HS- 0.2932057E-13 -.2708152E-09 -.8954593E-05 -4.3521 7 Al+++ 0.1433340E-24 0.3683142E-04 0.9935667E+00 2.5555 8 H4SiO4 0.5210892E-03 0.1450738E-02 0.1394102E+03 -3.2831 9 Ca++ 0.1407286E-07 0.1592481E-07 0.6381058E-03 10.4648 10 Mg++ 0.1799296E-09 0.2801026E-09 0.6808481E-05 8.5712 11 Fe++ 0.1064097E-11 0.4891987E-08 0.2731477E-03 6.3431 12 K+ 0.4798880E-04 0.4803515E-04 0.1877892E+01 4.8620 13 Na+ 0.2181192E-02 0.2209431E-02 0.5078414E+02 6.5194 14 Mn++ 0.1421726E-09 0.1055885E-08 0.5799651E-04 8.4690 15 HPO4-- 0.9832187E-05 0.9938755E-05 0.9537195E+00 13.3095 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2778871E-01 -.2145331E-02 -.2564338E-01 0.0000000E+00 2 H2O 0.5548720E+02 0.5549090E+02 -.3700112E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7203528E-04 0.2550474E-04 0.4653054E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4653081E-04 -.2707295E-09 -.4653054E-04 0.0000000E+00 7 Al+++ 0.5474785E-02 0.3681977E-04 0.5437965E-02 0.0000000E+00 8 H4SiO4 0.1748306E-01 0.1450279E-02 0.1603278E-01 0.0000000E+00 9 Ca++ 0.1945561E-02 0.1591977E-07 0.1945545E-02 0.0000000E+00 10 Mg++ 0.1332540E-02 0.2800140E-09 0.1332539E-02 0.0000000E+00 11 Fe++ 0.1197141E-02 0.4890439E-08 0.1197137E-02 0.0000000E+00 12 K+ 0.3564756E-03 0.4801996E-04 0.3084556E-03 0.0000000E+00 13 Na+ 0.2267625E-02 0.2208732E-02 0.5889286E-04 0.0000000E+00 14 Mn++ 0.2911150E-04 0.1055551E-08 0.2911045E-04 0.0000000E+00 15 HPO4-- 0.9935611E-05 0.9935611E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.3381E-17 Mass of aqueous solution: 0.999885E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.6790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2665E-03 -3.574 0.1481 -0.829 8.274 0.5635E-01 daphnite 0.1650E-03 -3.783 0.1177 -0.929 6.575 0.3567E-01 chlorite-Mn 0.5822E-05 -5.235 0.4128E-02 -2.384 0.2306 0.1315E-02 hematite 0.1861E-03 -3.730 0.2972E-01 -1.527 1.660 0.5634E-02 microcline 0.2149E-03 -3.668 0.5981E-01 -1.223 3.341 0.2336E-01 muscovite 0.9356E-04 -4.029 0.3727E-01 -1.429 2.082 0.1318E-01 paragonite 0.5889E-04 -4.230 0.2251E-01 -1.648 1.257 0.7780E-02 stilbite 0.1946E-02 -2.711 1.371 0.137 76.58 0.6395 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.790352 g Volume = 0.782778 cm3 Porosity: 53.1720% V(tot) - V(min): 0.88882E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.6790000 g log = 0.2251 Original solution: 1000.0103000 g Original solution / Rock added: 595.60 (Water/Rock Ratio), log = 2.7750 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1355E-05 1.0073 0.1436E-05 0.1426E-05 CH4,gas 0.2051E-16 1.0129 0.2185E-16 0.2157E-16 H2,gas 0.6019E-06 1.0006 0.6335E-06 0.6332E-06 H2S,gas 0.1381E-14 0.9959 0.1447E-14 0.1453E-14 S2,gas 0.1857E-36 1.0000 0.1953E-36 0.1953E-36 CO,gas 0.2240E-15 1.0000 0.2357E-15 0.2357E-15 SO3,gas 0.2593E-38 1.0000 0.2727E-38 0.2727E-38 SO2,gas 0.6213E-22 1.0000 0.6536E-22 0.6536E-22 HCl,gas 0.2452E-16 1.0000 0.2579E-16 0.2579E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 121 paragonite 4.34 4.34 0.00 0.000 0.19715E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.21 -7.84 -2.614 0.13391E+05 -5.843 3 CH4,gas 4.81 -13.85 -18.66 -4.665 0.31862E+05 -16.660 4 H2,gas 8.29 0.09 -8.20 -4.685 0.13998E+05 -6.198 5 H2S,gas -5.94 -22.78 -16.84 -8.420 0.28753E+05 -14.840 6 S2,gas -7.03 -45.74 -38.71 -5.955 0.66095E+05 -36.709 7 CO,gas 3.51 -14.12 -17.63 -5.424 0.30099E+05 -15.628 8 SO3,gas 17.43 -23.14 -40.56 -10.141 0.69262E+05 -38.564 9 SO2,gas 1.14 -23.05 -24.18 -6.449 0.41295E+05 -22.185 10 HCl,gas 5.48 -13.11 -18.59 -9.294 0.31739E+05 -16.588 11 acmite 7.74 6.25 -1.49 -0.154 0.25362E+04 15 albite-high 0.75 -0.77 -1.52 -0.117 0.26022E+04 16 albite -0.33 -0.77 -0.45 -0.034 0.76153E+03 19 spessartine 24.55 20.67 -3.88 -0.194 0.66268E+04 20 analcite 3.37 2.51 -0.86 -0.096 0.14717E+04 21 andalusite 5.06 1.83 -3.23 -0.323 0.55228E+04 22 andradite 39.09 34.14 -4.95 -0.257 0.84436E+04 26 annite 20.21 16.60 -3.61 -0.201 0.61669E+04 27 phlogopite 27.15 23.28 -3.86 -0.215 0.65991E+04 29 anorthite 12.80 9.01 -3.79 -0.291 0.64681E+04 32 apatite-OH -17.99 -18.33 -0.34 -0.026 0.58028E+03 35 aragonite 0.99 -3.74 -4.73 -1.576 0.80720E+04 36 brucite 12.58 8.57 -4.01 -0.801 0.68391E+04 37 calcite 0.83 -3.74 -4.57 -1.525 0.78107E+04 38 carnegieite-low 9.06 5.79 -3.27 -0.468 0.55881E+04 39 carnegieite-high 10.13 5.79 -4.34 -0.620 0.74150E+04 40 carpholite-Mg 8.65 7.12 -1.53 -0.102 0.26199E+04 41 carpholite-Fe 6.78 4.89 -1.89 -0.126 0.32356E+04 42 celadonite 5.40 2.86 -2.54 -0.150 0.43441E+04 43 celadonite-Fe 3.94 0.63 -3.31 -0.195 0.56495E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81787E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.191 0.48870E+04 51 chloritoid-Fe 9.24 8.17 -1.07 -0.071 0.18229E+04 52 chloritoid-Mn 11.46 10.30 -1.17 -0.078 0.19914E+04 54 coesite -2.37 -3.28 -0.91 -0.305 0.15602E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.28 -0.73 -0.245 0.12531E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.47 -3.75 -0.375 0.63957E+04 68 hedenbergite 14.24 10.24 -4.00 -0.400 0.68345E+04 75 epidote 24.78 22.49 -2.29 -0.111 0.39018E+04 76 clinozoisite 22.92 18.75 -4.17 -0.190 0.71277E+04 77 epidote-Fe 29.94 26.23 -3.70 -0.192 0.63234E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79837E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63705E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.51 -1.74 -0.174 0.29747E+04 97 kalsilite 7.62 4.13 -3.49 -0.498 0.59520E+04 98 kaolinite -1.27 -1.46 -0.18 -0.017 0.31084E+03 99 kyanite 4.93 1.83 -3.10 -0.310 0.52996E+04 101 laumontite 2.97 2.44 -0.53 -0.035 0.90690E+03 102 lawsonite 9.68 9.01 -0.67 -0.045 0.11419E+04 103 leucite 4.17 0.85 -3.32 -0.332 0.56626E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70690E+04 107 magnetite 20.13 18.94 -1.19 -0.097 0.20354E+04 108 minnesotaite 10.46 5.90 -4.56 -0.268 0.77923E+04 113 margarite 17.45 14.12 -3.33 -0.133 0.56880E+04 122 nepheline 8.38 5.79 -2.59 -0.369 0.44160E+04 134 phlogopite-Na 29.73 24.94 -4.79 -0.266 0.81825E+04 136 prehnite 19.47 16.19 -3.28 -0.193 0.55921E+04 137 prehnite-Fe 22.59 19.93 -2.65 -0.160 0.45285E+04 145 pyroxmangite 7.42 5.19 -2.23 -0.446 0.38078E+04 146 pyrophyllite -6.10 -8.02 -1.92 -0.120 0.32840E+04 147 quartz -2.98 -3.28 -0.30 -0.100 0.51410E+03 151 rhodochrosite -0.96 -5.74 -4.78 -1.593 0.81591E+04 152 rhodonite 7.46 5.19 -2.28 -0.455 0.38871E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.83 -3.49 -0.349 0.59650E+04 164 stilpnomelane-Fe 13.18 12.99 -0.19 -0.006 0.31823E+03 165 stilpnomelane-Mg 27.60 24.13 -3.46 -0.103 0.59130E+04 168 sudoite 21.22 17.52 -3.70 -0.119 0.63195E+04 171 talc 16.55 12.58 -3.97 -0.234 0.67823E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76118E+04 177 topaz-H 4.67 1.83 -2.84 -0.258 0.48486E+04 178 tridymite -2.61 -3.28 -0.67 -0.223 0.11414E+04 187 wairakite 4.06 2.44 -1.62 -0.095 0.27577E+04 188 walstromite 11.53 7.18 -4.35 -0.869 0.74210E+04 189 wollastonite 10.48 7.18 -3.30 -0.660 0.56349E+04 190 pseudo-wollastonite 11.02 7.18 -3.84 -0.768 0.65535E+04 191 zoisite 22.96 18.75 -4.22 -0.192 0.72002E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.37 -2.81 -0.174 0.47950E+04 194 beidellite-H -2.24 -6.09 -3.85 -0.246 0.65798E+04 195 beidellite-K -1.44 -4.49 -3.06 -0.187 0.52166E+04 196 beidellite-Mg -1.71 -4.68 -2.97 -0.184 0.50772E+04 197 beidellite-Na -1.26 -3.94 -2.69 -0.164 0.45866E+04 199 chalcedony -2.79 -3.28 -0.49 -0.163 0.83442E+03 201 montmorillonite-Ca -2.21 -4.31 -2.10 -0.130 0.35780E+04 202 montmorillonite-K -2.16 -4.43 -2.27 -0.139 0.38773E+04 203 montmorillonite-Mg -2.40 -4.62 -2.22 -0.137 0.37911E+04 204 montmorillonite-Na -1.96 -3.88 -1.92 -0.118 0.32854E+04 205 nontronite-Ca 3.28 3.12 -0.16 -0.010 0.27485E+03 206 nontronite-H 2.60 1.39 -1.20 -0.081 0.20553E+04 207 nontronite-K 3.40 3.00 -0.41 -0.026 0.69557E+03 208 nontronite-Mg 3.14 2.81 -0.33 -0.022 0.56860E+03 209 nontronite-Na 3.58 3.54 -0.04 -0.003 0.67298E+02 224 tobermorite 9.84 5.43 -4.40 -1.202 0.75213E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.34 -3.48 -0.870 0.59438E+04 240 silica-amorphous -2.08 -3.28 -1.20 -0.401 0.20546E+04 242 an20ab80 2.08 1.18 -0.90 -0.069 0.15312E+04 243 an25ab75 2.71 1.67 -1.04 -0.080 0.17716E+04 244 an30ab70 3.34 2.16 -1.18 -0.091 0.20202E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.6790000 g New total amount of reactant added: 1.7190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4571E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.7190000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1465035E-02 Osmotic coef. = 0.9782 True ionic strength = .2305035E-02 Chg. balance for total moles = 0.4571E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.64356E-09 -9.1914 0.59486E-09 -9.2256 0.92434E+00 -0.0342 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12738E-03 -3.8949 0.92348E+00 -0.0346 4 SO4-- 0.25498E-04 -4.5935 0.19605E-04 -4.7076 0.76889E+00 -0.1141 5 HCO3- 0.11006E-04 -4.9584 0.10166E-04 -4.9928 0.92368E+00 -0.0345 6 HS- 0.30500E-13 -13.5157 0.28167E-13 -13.5503 0.92350E+00 -0.0346 7 Al+++ 0.13389E-24 -24.8733 0.75639E-25 -25.1213 0.56495E+00 -0.2480 8 H4SiO4 0.51408E-03 -3.2890 0.51408E-03 -3.2890 0.10000E+01 0.0000 9 Ca++ 0.14771E-07 -7.8306 0.11345E-07 -7.9452 0.76803E+00 -0.1146 10 Mg++ 0.17317E-09 -9.7615 0.13291E-09 -9.8764 0.76750E+00 -0.1149 11 Fe++ 0.10241E-11 -11.9896 0.78615E-12 -12.1045 0.76762E+00 -0.1149 12 K+ 0.48809E-04 -4.3115 0.45086E-04 -4.3460 0.92372E+00 -0.0345 13 Na+ 0.22185E-02 -2.6539 0.20487E-02 -2.6885 0.92346E+00 -0.0346 14 Mn++ 0.13683E-09 -9.8638 0.10505E-09 -9.9786 0.76772E+00 -0.1148 15 HPO4-- 0.10068E-04 -4.9970 0.77415E-05 -5.1112 0.76890E+00 -0.1141 16 HSiO3- 0.91303E-03 -3.0395 0.84316E-03 -3.0741 0.92348E+00 -0.0346 17 Ca(HSiO3)+ 0.23201E-09 -9.6345 0.21432E-09 -9.6689 0.92375E+00 -0.0344 18 Mg(HSiO3)+ 0.33827E-11 -11.4707 0.31248E-11 -11.5052 0.92375E+00 -0.0344 19 NaHSiO3,aq 0.27435E-04 -4.5617 0.27435E-04 -4.5617 0.10000E+01 0.0000 20 AlO+ 0.29872E-13 -13.5247 0.27595E-13 -13.5592 0.92375E+00 -0.0344 21 AlOH+2 0.10709E-18 -18.9702 0.82229E-19 -19.0850 0.76784E+00 -0.1147 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.37741E-04 -4.4232 0.34844E-04 -4.4579 0.92322E+00 -0.0347 24 CH4,aq 0.14339E-19 -19.8435 0.14332E-19 -19.8437 0.99955E+00 -0.0002 29 CO,aq 0.14743E-18 -18.8314 0.14743E-18 -18.8314 0.10000E+01 0.0000 30 CO2,aq 0.12198E-07 -7.9137 0.12193E-07 -7.9139 0.99955E+00 -0.0002 31 CO3-2 0.20557E-05 -5.6870 0.15801E-05 -5.8013 0.76863E+00 -0.1143 32 CaCO3,aq 0.21955E-09 -9.6585 0.21955E-09 -9.6585 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.31459E-11 -11.5023 0.29060E-11 -11.5367 0.92375E+00 -0.0344 34 CaCl+ 0.24928E-11 -11.6033 0.23027E-11 -11.6378 0.92375E+00 -0.0344 35 CaCl2,aq 0.68294E-16 -16.1656 0.68294E-16 -16.1656 0.10000E+01 0.0000 36 CaOH+ 0.14557E-08 -8.8369 0.13447E-08 -8.8714 0.92375E+00 -0.0344 37 CaSO4,aq 0.69298E-10 -10.1593 0.69298E-10 -10.1593 0.10000E+01 0.0000 38 HCl,aq 0.14253E-13 -13.8461 0.14253E-13 -13.8461 0.10000E+01 0.0000 43 FeCl+ 0.16884E-15 -15.7725 0.15597E-15 -15.8070 0.92375E+00 -0.0344 46 FeO,aq 0.87852E-10 -10.0562 0.87852E-10 -10.0562 0.10000E+01 0.0000 47 FeOH+ 0.47430E-10 -10.3240 0.43813E-10 -10.3584 0.92375E+00 -0.0344 48 HFeO2- 0.17201E-08 -8.7644 0.15885E-08 -8.7990 0.92348E+00 -0.0346 49 FeO+ 0.53270E-14 -14.2735 0.49208E-14 -14.3080 0.92375E+00 -0.0344 51 FeO2- 0.29596E-08 -8.5288 0.27331E-08 -8.5633 0.92348E+00 -0.0346 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.46968E-09 -9.3282 0.46946E-09 -9.3284 0.99955E+00 -0.0002 54 KCl,aq 0.10169E-09 -9.9927 0.10169E-09 -9.9927 0.10000E+01 0.0000 55 KHSO4,aq 0.14070E-17 -17.8517 0.14070E-17 -17.8517 0.10000E+01 0.0000 56 KOH,aq 0.33042E-07 -7.4809 0.33042E-07 -7.4809 0.10000E+01 0.0000 57 KSO4- 0.14746E-07 -7.8313 0.13618E-07 -7.8659 0.92348E+00 -0.0346 58 MgCO3,aq 0.64273E-12 -12.1920 0.64273E-12 -12.1920 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.37583E-13 -13.4250 0.34717E-13 -13.4595 0.92375E+00 -0.0344 60 MgCl+ 0.26512E-13 -13.5766 0.24491E-13 -13.6110 0.92375E+00 -0.0344 61 MgOH+ 0.94486E-10 -10.0246 0.87281E-10 -10.0591 0.92375E+00 -0.0344 63 MnO,aq 0.31338E-09 -9.5039 0.31338E-09 -9.5039 0.10000E+01 0.0000 64 MnOH+ 0.58876E-09 -9.2301 0.54387E-09 -9.2645 0.92375E+00 -0.0344 65 MnO2-2 0.39846E-13 -13.3996 0.30627E-13 -13.5139 0.76863E+00 -0.1143 66 HMnO2- 0.42745E-11 -11.3691 0.39474E-11 -11.4037 0.92348E+00 -0.0346 69 MnCl+ 0.87670E-13 -13.0571 0.80986E-13 -13.0916 0.92375E+00 -0.0344 70 MnSO4,aq 0.58366E-12 -12.2338 0.58366E-12 -12.2338 0.10000E+01 0.0000 71 NaCl,aq 0.85210E-07 -7.0695 0.85210E-07 -7.0695 0.10000E+01 0.0000 72 NaOH,aq 0.15133E-05 -5.8201 0.15133E-05 -5.8201 0.10000E+01 0.0000 74 OH- 0.10922E-02 -2.9617 0.10084E-02 -2.9964 0.92322E+00 -0.0347 79 HPO3-2 0.14935E-16 -16.8258 0.11479E-16 -16.9401 0.76863E+00 -0.1143 81 H2PO3- 0.14525E-19 -19.8379 0.13414E-19 -19.8725 0.92348E+00 -0.0346 82 H3PO4,aq 0.17636E-13 -13.7536 0.17636E-13 -13.7536 0.10000E+01 0.0000 83 H2PO4- 0.87415E-07 -7.0584 0.80737E-07 -7.0929 0.92361E+00 -0.0345 84 PO4-3 0.19966E-07 -7.6997 0.11365E-07 -7.9444 0.56924E+00 -0.2447 87 H2P2O7-2 0.66374E-15 -15.1780 0.51017E-15 -15.2923 0.76863E+00 -0.1143 88 HP2O7-3 0.31126E-12 -12.5069 0.17586E-12 -12.7548 0.56500E+00 -0.2480 89 P2O7-4 0.19767E-12 -12.7041 0.72931E-13 -13.1371 0.36895E+00 -0.4330 90 H2S,aq 0.50365E-16 -16.2979 0.50342E-16 -16.2981 0.99955E+00 -0.0002 97 SO3-2 0.16290E-14 -14.7881 0.12549E-14 -14.9014 0.77035E+00 -0.1133 98 HSO3- 0.47307E-16 -16.3251 0.43687E-16 -16.3596 0.92348E+00 -0.0346 99 HSO4- 0.11712E-10 -10.9314 0.10821E-10 -10.9657 0.92388E+00 -0.0344 Charge balance for all species = 0.4745E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6435582E-09 -.2187215E-02 -.2204134E+01 0.0000 2 H2O 0.1000000E+01 0.5550848E+02 0.9997987E+06 0.0000 3 Cl- 0.1379334E-03 0.1380187E-03 0.4892185E+01 5.3307 4 SO4-- 0.2549788E-04 0.2551299E-04 0.2450320E+01 13.7435 5 HCO3- 0.1100606E-04 0.1307422E-04 0.7975903E+00 4.2327 6 HS- 0.3049990E-13 -.2779287E-09 -.9189792E-05 -4.3247 7 Al+++ 0.1338859E-24 0.3775068E-04 0.1018363E+01 2.5555 8 H4SiO4 0.5140772E-03 0.1454544E-02 0.1397757E+03 -3.2890 9 Ca++ 0.1477101E-07 0.1675325E-07 0.6713002E-03 10.5060 10 Mg++ 0.1731726E-09 0.2717477E-09 0.6605388E-05 8.5747 11 Fe++ 0.1024134E-11 0.5019463E-08 0.2802650E-03 6.3467 12 K+ 0.4880931E-04 0.4885720E-04 0.1910026E+01 4.8796 13 Na+ 0.2218496E-02 0.2247530E-02 0.5165976E+02 6.5371 14 Mn++ 0.1368330E-09 0.1043961E-08 0.5734148E-04 8.4726 15 HPO4-- 0.1006822E-04 0.1017560E-04 0.9764455E+00 13.3400 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2845105E-01 -.2186509E-02 -.2626454E-01 0.0000000E+00 2 H2O 0.5548670E+02 0.5549055E+02 -.3852274E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7314382E-04 0.2550475E-04 0.4763907E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4763935E-04 -.2778390E-09 -.4763907E-04 0.0000000E+00 7 Al+++ 0.5605215E-02 0.3773849E-04 0.5567476E-02 0.0000000E+00 8 H4SiO4 0.1789957E-01 0.1454074E-02 0.1644550E-01 0.0000000E+00 9 Ca++ 0.1991566E-02 0.1674784E-07 0.1991550E-02 0.0000000E+00 10 Mg++ 0.1364286E-02 0.2716599E-09 0.1364285E-02 0.0000000E+00 11 Fe++ 0.1225662E-02 0.5017843E-08 0.1225657E-02 0.0000000E+00 12 K+ 0.3649682E-03 0.4884142E-04 0.3161267E-03 0.0000000E+00 13 Na+ 0.2317835E-02 0.2246804E-02 0.7103088E-04 0.0000000E+00 14 Mn++ 0.2980505E-04 0.1043624E-08 0.2980400E-04 0.0000000E+00 15 HPO4-- 0.1017231E-04 0.1017231E-04 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.5150E-18 Mass of aqueous solution: 0.999880E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.7190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2729E-03 -3.564 0.1517 -0.819 8.265 0.5769E-01 daphnite 0.1689E-03 -3.772 0.1205 -0.919 6.568 0.3652E-01 chlorite-Mn 0.5961E-05 -5.225 0.4226E-02 -2.374 0.2303 0.1347E-02 hematite 0.1906E-03 -3.720 0.3043E-01 -1.517 1.658 0.5768E-02 microcline 0.2363E-03 -3.627 0.6576E-01 -1.182 3.584 0.2569E-01 muscovite 0.7985E-04 -4.098 0.3181E-01 -1.497 1.733 0.1125E-01 paragonite 0.7103E-04 -4.149 0.2715E-01 -1.566 1.479 0.9384E-02 stilbite 0.1992E-02 -2.701 1.403 0.147 76.48 0.6546 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.835042 g Volume = 0.802254 cm3 Porosity: 52.4618% V(tot) - V(min): 0.88535E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.7190000 g log = 0.2353 Original solution: 1000.0103000 g Original solution / Rock added: 581.74 (Water/Rock Ratio), log = 2.7647 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1317E-05 1.0073 0.1396E-05 0.1386E-05 CH4,gas 0.2127E-16 1.0129 0.2266E-16 0.2238E-16 H2,gas 0.6118E-06 1.0006 0.6439E-06 0.6435E-06 H2S,gas 0.1402E-14 0.9959 0.1468E-14 0.1474E-14 S2,gas 0.1851E-36 1.0000 0.1948E-36 0.1948E-36 CO,gas 0.2213E-15 1.0000 0.2328E-15 0.2328E-15 SO3,gas 0.2466E-38 1.0000 0.2594E-38 0.2594E-38 SO2,gas 0.6006E-22 1.0000 0.6318E-22 0.6318E-22 HCl,gas 0.2392E-16 1.0000 0.2517E-16 0.2517E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 121 paragonite 4.34 4.34 0.00 0.000 0.19715E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.22 -7.86 -2.618 0.13413E+05 -5.855 3 CH4,gas 4.81 -13.84 -18.64 -4.661 0.31835E+05 -16.645 4 H2,gas 8.29 0.10 -8.19 -4.681 0.13986E+05 -6.191 5 H2S,gas -5.94 -22.78 -16.83 -8.417 0.28742E+05 -14.833 6 S2,gas -7.03 -45.74 -38.71 -5.955 0.66097E+05 -36.711 7 CO,gas 3.51 -14.12 -17.63 -5.426 0.30108E+05 -15.633 8 SO3,gas 17.43 -23.16 -40.59 -10.147 0.69300E+05 -38.586 9 SO2,gas 1.14 -23.06 -24.20 -6.453 0.41320E+05 -22.199 10 HCl,gas 5.48 -13.12 -18.60 -9.300 0.31758E+05 -16.599 11 acmite 7.74 6.26 -1.48 -0.154 0.25262E+04 15 albite-high 0.75 -0.77 -1.52 -0.117 0.26022E+04 16 albite -0.33 -0.77 -0.45 -0.034 0.76153E+03 19 spessartine 24.55 20.66 -3.89 -0.194 0.66389E+04 20 analcite 3.37 2.51 -0.86 -0.095 0.14616E+04 21 andalusite 5.06 1.82 -3.24 -0.324 0.55328E+04 22 andradite 39.09 34.25 -4.84 -0.251 0.82628E+04 26 annite 20.21 16.61 -3.60 -0.200 0.61488E+04 27 phlogopite 27.15 23.29 -3.85 -0.214 0.65810E+04 29 anorthite 12.80 9.04 -3.76 -0.289 0.64178E+04 32 apatite-OH -17.99 -18.16 -0.17 -0.013 0.28767E+03 35 aragonite 0.99 -3.71 -4.70 -1.566 0.80229E+04 36 brucite 12.58 8.57 -4.00 -0.800 0.68331E+04 37 calcite 0.83 -3.71 -4.55 -1.515 0.77616E+04 38 carnegieite-low 9.06 5.80 -3.26 -0.466 0.55680E+04 39 carnegieite-high 10.13 5.80 -4.33 -0.619 0.73949E+04 40 carpholite-Mg 8.65 7.11 -1.54 -0.103 0.26340E+04 41 carpholite-Fe 6.78 4.88 -1.90 -0.127 0.32496E+04 42 celadonite 5.40 2.85 -2.55 -0.150 0.43482E+04 43 celadonite-Fe 3.94 0.63 -3.31 -0.195 0.56535E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81807E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.191 0.48911E+04 51 chloritoid-Fe 9.24 8.17 -1.07 -0.071 0.18270E+04 52 chloritoid-Mn 11.46 10.29 -1.17 -0.078 0.19954E+04 54 coesite -2.37 -3.29 -0.92 -0.307 0.15702E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.29 -0.74 -0.247 0.12631E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.50 -3.71 -0.371 0.63394E+04 68 hedenbergite 14.24 10.27 -3.97 -0.397 0.67782E+04 75 epidote 24.78 22.55 -2.22 -0.108 0.37913E+04 76 clinozoisite 22.92 18.81 -4.11 -0.187 0.70171E+04 77 epidote-Fe 29.94 26.30 -3.64 -0.189 0.62129E+04 78 fayalite 14.08 9.40 -4.67 -0.668 0.79817E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63725E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.51 -1.74 -0.174 0.29647E+04 97 kalsilite 7.62 4.15 -3.47 -0.496 0.59319E+04 98 kaolinite -1.27 -1.47 -0.19 -0.018 0.33093E+03 99 kyanite 4.93 1.82 -3.11 -0.311 0.53096E+04 101 laumontite 2.97 2.46 -0.51 -0.034 0.87676E+03 102 lawsonite 9.68 9.04 -0.64 -0.043 0.10917E+04 103 leucite 4.17 0.86 -3.31 -0.331 0.56525E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70710E+04 107 magnetite 20.13 18.94 -1.19 -0.097 0.20293E+04 108 minnesotaite 10.46 5.88 -4.58 -0.269 0.78144E+04 113 margarite 17.45 14.15 -3.30 -0.132 0.56377E+04 122 nepheline 8.38 5.80 -2.57 -0.368 0.43960E+04 134 phlogopite-Na 29.73 24.95 -4.78 -0.266 0.81644E+04 136 prehnite 19.47 16.26 -3.21 -0.189 0.54816E+04 137 prehnite-Fe 22.59 20.00 -2.59 -0.156 0.44180E+04 145 pyroxmangite 7.42 5.18 -2.23 -0.446 0.38118E+04 146 pyrophyllite -6.10 -8.04 -1.95 -0.122 0.33242E+04 147 quartz -2.98 -3.29 -0.31 -0.102 0.52415E+03 151 rhodochrosite -0.96 -5.75 -4.79 -1.596 0.81742E+04 152 rhodonite 7.46 5.18 -2.28 -0.456 0.38911E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.82 -3.50 -0.350 0.59750E+04 164 stilpnomelane-Fe 13.18 12.97 -0.21 -0.006 0.35339E+03 165 stilpnomelane-Mg 27.60 24.11 -3.48 -0.104 0.59482E+04 168 sudoite 21.22 17.50 -3.71 -0.120 0.63376E+04 171 talc 16.55 12.57 -3.99 -0.234 0.68044E+04 174 tephroite 18.11 13.66 -4.46 -0.637 0.76098E+04 177 topaz-H 4.67 1.82 -2.85 -0.259 0.48587E+04 178 tridymite -2.61 -3.29 -0.67 -0.225 0.11514E+04 187 wairakite 4.06 2.46 -1.60 -0.094 0.27276E+04 188 walstromite 11.53 7.22 -4.31 -0.862 0.73607E+04 189 wollastonite 10.48 7.22 -3.26 -0.653 0.55746E+04 190 pseudo-wollastonite 11.02 7.22 -3.80 -0.761 0.64932E+04 191 zoisite 22.96 18.81 -4.15 -0.189 0.70897E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.38 -2.82 -0.175 0.48203E+04 194 beidellite-H -2.24 -6.12 -3.88 -0.247 0.66167E+04 195 beidellite-K -1.44 -4.51 -3.07 -0.188 0.52435E+04 196 beidellite-Mg -1.71 -4.70 -2.99 -0.185 0.51130E+04 197 beidellite-Na -1.26 -3.96 -2.70 -0.165 0.46135E+04 199 chalcedony -2.79 -3.29 -0.49 -0.165 0.84446E+03 201 montmorillonite-Ca -2.21 -4.33 -2.11 -0.131 0.36045E+04 202 montmorillonite-K -2.16 -4.45 -2.29 -0.140 0.39055E+04 203 montmorillonite-Mg -2.40 -4.64 -2.24 -0.139 0.38283E+04 204 montmorillonite-Na -1.96 -3.90 -1.94 -0.119 0.33137E+04 205 nontronite-Ca 3.28 3.10 -0.18 -0.011 0.30012E+03 206 nontronite-H 2.60 1.37 -1.23 -0.082 0.20922E+04 207 nontronite-K 3.40 2.98 -0.42 -0.027 0.72249E+03 208 nontronite-Mg 3.14 2.79 -0.35 -0.023 0.60447E+03 209 nontronite-Na 3.58 3.53 -0.06 -0.004 0.94223E+02 224 tobermorite 9.84 5.46 -4.38 -1.194 0.74728E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.35 -3.48 -0.869 0.59378E+04 240 silica-amorphous -2.08 -3.29 -1.21 -0.403 0.20647E+04 242 an20ab80 2.08 1.19 -0.89 -0.069 0.15212E+04 243 an25ab75 2.71 1.68 -1.03 -0.079 0.17590E+04 244 an30ab70 3.34 2.17 -1.17 -0.090 0.20052E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.7190000 g New total amount of reactant added: 1.7590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4571E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.7590000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1489149E-02 Osmotic coef. = 0.9780 True ionic strength = .2343479E-02 Chg. balance for total moles = 0.4571E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.62878E-09 -9.2015 0.58093E-09 -9.2359 0.92391E+00 -0.0344 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12732E-03 -3.8951 0.92304E+00 -0.0348 4 SO4-- 0.25498E-04 -4.5935 0.19568E-04 -4.7085 0.76743E+00 -0.1150 5 HCO3- 0.10963E-04 -4.9601 0.10121E-04 -4.9948 0.92324E+00 -0.0347 6 HS- 0.31705E-13 -13.4989 0.29265E-13 -13.5336 0.92306E+00 -0.0348 7 Al+++ 0.12523E-24 -24.9023 0.70448E-25 -25.1521 0.56253E+00 -0.2499 8 H4SiO4 0.50728E-03 -3.2947 0.50728E-03 -3.2947 0.10000E+01 0.0000 9 Ca++ 0.15492E-07 -7.8099 0.11875E-07 -7.9254 0.76657E+00 -0.1154 10 Mg++ 0.16680E-09 -9.7778 0.12777E-09 -9.8936 0.76602E+00 -0.1158 11 Fe++ 0.98644E-12 -12.0059 0.75577E-12 -12.1216 0.76616E+00 -0.1157 12 K+ 0.49631E-04 -4.3043 0.45823E-04 -4.3389 0.92328E+00 -0.0347 13 Na+ 0.22558E-02 -2.6467 0.20822E-02 -2.6815 0.92302E+00 -0.0348 14 Mn++ 0.13180E-09 -9.8801 0.10099E-09 -9.9957 0.76625E+00 -0.1156 15 HPO4-- 0.10304E-04 -4.9870 0.79080E-05 -5.1019 0.76745E+00 -0.1149 16 HSiO3- 0.92301E-03 -3.0348 0.85198E-03 -3.0696 0.92304E+00 -0.0348 17 Ca(HSiO3)+ 0.24551E-09 -9.6099 0.22669E-09 -9.6446 0.92331E+00 -0.0347 18 Mg(HSiO3)+ 0.32875E-11 -11.4831 0.30354E-11 -11.5178 0.92331E+00 -0.0347 19 NaHSiO3,aq 0.28175E-04 -4.5501 0.28175E-04 -4.5501 0.10000E+01 0.0000 20 AlO+ 0.29187E-13 -13.5348 0.26948E-13 -13.5695 0.92331E+00 -0.0347 21 AlOH+2 0.10233E-18 -18.9900 0.78423E-19 -19.1056 0.76637E+00 -0.1156 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.38665E-04 -4.4127 0.35679E-04 -4.4476 0.92277E+00 -0.0349 24 CH4,aq 0.14860E-19 -19.8280 0.14853E-19 -19.8282 0.99954E+00 -0.0002 29 CO,aq 0.14564E-18 -18.8367 0.14564E-18 -18.8367 0.10000E+01 0.0000 30 CO2,aq 0.11860E-07 -7.9259 0.11855E-07 -7.9261 0.99954E+00 -0.0002 31 CO3-2 0.20997E-05 -5.6778 0.16108E-05 -5.7929 0.76718E+00 -0.1151 32 CaCO3,aq 0.23429E-09 -9.6302 0.23429E-09 -9.6302 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.32800E-11 -11.4841 0.30285E-11 -11.5188 0.92331E+00 -0.0347 34 CaCl+ 0.26094E-11 -11.5835 0.24093E-11 -11.6181 0.92331E+00 -0.0347 35 CaCl2,aq 0.71420E-16 -16.1462 0.71420E-16 -16.1462 0.10000E+01 0.0000 36 CaOH+ 0.15611E-08 -8.8066 0.14414E-08 -8.8412 0.92331E+00 -0.0347 37 CaSO4,aq 0.72403E-10 -10.1402 0.72403E-10 -10.1402 0.10000E+01 0.0000 38 HCl,aq 0.13912E-13 -13.8566 0.13912E-13 -13.8566 0.10000E+01 0.0000 43 FeCl+ 0.16231E-15 -15.7896 0.14987E-15 -15.8243 0.92331E+00 -0.0347 46 FeO,aq 0.88556E-10 -10.0528 0.88556E-10 -10.0528 0.10000E+01 0.0000 47 FeOH+ 0.46712E-10 -10.3306 0.43130E-10 -10.3652 0.92331E+00 -0.0347 48 HFeO2- 0.17763E-08 -8.7505 0.16396E-08 -8.7853 0.92304E+00 -0.0348 49 FeO+ 0.52047E-14 -14.2836 0.48056E-14 -14.3183 0.92331E+00 -0.0347 51 FeO2- 0.30320E-08 -8.5183 0.27986E-08 -8.5531 0.92304E+00 -0.0348 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.47724E-09 -9.3213 0.47702E-09 -9.3215 0.99954E+00 -0.0002 54 KCl,aq 0.10330E-09 -9.9859 0.10330E-09 -9.9859 0.10000E+01 0.0000 55 KHSO4,aq 0.13939E-17 -17.8558 0.13939E-17 -17.8558 0.10000E+01 0.0000 56 KOH,aq 0.34387E-07 -7.4636 0.34387E-07 -7.4636 0.10000E+01 0.0000 57 KSO4- 0.14966E-07 -7.8249 0.13814E-07 -7.8597 0.92304E+00 -0.0348 58 MgCO3,aq 0.62990E-12 -12.2007 0.62990E-12 -12.2007 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.35987E-13 -13.4438 0.33228E-13 -13.4785 0.92331E+00 -0.0347 60 MgCl+ 0.25487E-13 -13.5937 0.23533E-13 -13.6283 0.92331E+00 -0.0347 61 MgOH+ 0.93056E-10 -10.0313 0.85920E-10 -10.0659 0.92331E+00 -0.0347 63 MnO,aq 0.31589E-09 -9.5005 0.31589E-09 -9.5005 0.10000E+01 0.0000 64 MnOH+ 0.57986E-09 -9.2367 0.53539E-09 -9.2713 0.92331E+00 -0.0347 65 MnO2-2 0.42195E-13 -13.3747 0.32371E-13 -13.4898 0.76718E+00 -0.1151 66 HMnO2- 0.44142E-11 -11.3552 0.40744E-11 -11.3899 0.92304E+00 -0.0348 69 MnCl+ 0.84282E-13 -13.0743 0.77818E-13 -13.1089 0.92331E+00 -0.0347 70 MnSO4,aq 0.56005E-12 -12.2518 0.56005E-12 -12.2518 0.10000E+01 0.0000 71 NaCl,aq 0.86560E-07 -7.0627 0.86560E-07 -7.0627 0.10000E+01 0.0000 72 NaOH,aq 0.15749E-05 -5.8027 0.15749E-05 -5.8027 0.10000E+01 0.0000 74 OH- 0.11189E-02 -2.9512 0.10325E-02 -2.9861 0.92277E+00 -0.0349 79 HPO3-2 0.15531E-16 -16.8088 0.11915E-16 -16.9239 0.76718E+00 -0.1151 81 H2PO3- 0.14730E-19 -19.8318 0.13597E-19 -19.8666 0.92304E+00 -0.0348 82 H3PO4,aq 0.17182E-13 -13.7649 0.17182E-13 -13.7649 0.10000E+01 0.0000 83 H2PO4- 0.87246E-07 -7.0593 0.80542E-07 -7.0940 0.92317E+00 -0.0347 84 PO4-3 0.20971E-07 -7.6784 0.11888E-07 -7.9249 0.56687E+00 -0.2465 87 H2P2O7-2 0.66179E-15 -15.1793 0.50771E-15 -15.2944 0.76718E+00 -0.1151 88 HP2O7-3 0.31854E-12 -12.4968 0.17921E-12 -12.7466 0.56259E+00 -0.2498 89 P2O7-4 0.20783E-12 -12.6823 0.76102E-13 -13.1186 0.36618E+00 -0.4363 90 H2S,aq 0.51104E-16 -16.2915 0.51081E-16 -16.2917 0.99954E+00 -0.0002 97 SO3-2 0.16552E-14 -14.7811 0.12727E-14 -14.8953 0.76892E+00 -0.1141 98 HSO3- 0.46877E-16 -16.3290 0.43269E-16 -16.3638 0.92304E+00 -0.0348 99 HSO4- 0.11422E-10 -10.9423 0.10548E-10 -10.9768 0.92345E+00 -0.0346 Charge balance for all species = 0.4740E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6287796E-09 -.2228476E-02 -.2245710E+01 0.0000 2 H2O 0.1000000E+01 0.5550850E+02 0.9997974E+06 0.0000 3 Cl- 0.1379330E-03 0.1380197E-03 0.4892209E+01 5.3408 4 SO4-- 0.2549783E-04 0.2551316E-04 0.2450333E+01 13.7633 5 HCO3- 0.1096252E-04 0.1307431E-04 0.7975943E+00 4.2411 6 HS- 0.3170468E-13 -.2850906E-09 -.9426584E-05 -4.2978 7 Al+++ 0.1252335E-24 0.3867446E-04 0.1043281E+01 2.5555 8 H4SiO4 0.5072840E-03 0.1458474E-02 0.1401531E+03 -3.2947 9 Ca++ 0.1549156E-07 0.1761079E-07 0.7056605E-03 10.5464 10 Mg++ 0.1667997E-09 0.2638350E-09 0.6413043E-05 8.5782 11 Fe++ 0.9864418E-12 0.5148055E-08 0.2874445E-03 6.3501 12 K+ 0.4963055E-04 0.4968001E-04 0.1942190E+01 4.8970 13 Na+ 0.2255833E-02 0.2285669E-02 0.5253632E+02 6.5544 14 Mn++ 0.1317970E-09 0.1032647E-08 0.5671996E-04 8.4760 15 HPO4-- 0.1030423E-04 0.1041245E-04 0.9991717E+00 13.3698 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2911339E-01 -.2227742E-02 -.2688565E-01 0.0000000E+00 2 H2O 0.5548620E+02 0.5549020E+02 -.4004196E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7425236E-04 0.2550475E-04 0.4874760E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4874789E-04 -.2849966E-09 -.4874760E-04 0.0000000E+00 7 Al+++ 0.5735644E-02 0.3866171E-04 0.5696983E-02 0.0000000E+00 8 H4SiO4 0.1831609E-01 0.1457993E-02 0.1685809E-01 0.0000000E+00 9 Ca++ 0.2037572E-02 0.1760498E-07 0.2037554E-02 0.0000000E+00 10 Mg++ 0.1396032E-02 0.2637481E-09 0.1396031E-02 0.0000000E+00 11 Fe++ 0.1254182E-02 0.5146358E-08 0.1254177E-02 0.0000000E+00 12 K+ 0.3734607E-03 0.4966363E-04 0.3237971E-03 0.0000000E+00 13 Na+ 0.2368045E-02 0.2284916E-02 0.8312829E-04 0.0000000E+00 14 Mn++ 0.3049859E-04 0.1032307E-08 0.3049756E-04 0.0000000E+00 15 HPO4-- 0.1040902E-04 0.1040902E-04 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2284E-17 Mass of aqueous solution: 0.999875E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.7590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2792E-03 -3.554 0.1552 -0.809 8.256 0.5903E-01 daphnite 0.1728E-03 -3.762 0.1233 -0.909 6.561 0.3737E-01 chlorite-Mn 0.6100E-05 -5.215 0.4324E-02 -2.364 0.2301 0.1378E-02 hematite 0.1950E-03 -3.710 0.3114E-01 -1.507 1.657 0.5902E-02 microcline 0.2576E-03 -3.589 0.7170E-01 -1.144 3.814 0.2801E-01 muscovite 0.6620E-04 -4.179 0.2637E-01 -1.579 1.403 0.9324E-02 paragonite 0.8313E-04 -4.080 0.3177E-01 -1.498 1.690 0.1098E-01 stilbite 0.2038E-02 -2.691 1.436 0.157 76.39 0.6697 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.879723 g Volume = 0.821727 cm3 Porosity: 51.7653% V(tot) - V(min): 0.88187E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.7590000 g log = 0.2453 Original solution: 1000.0103000 g Original solution / Rock added: 568.51 (Water/Rock Ratio), log = 2.7547 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1281E-05 1.0073 0.1357E-05 0.1347E-05 CH4,gas 0.2204E-16 1.0129 0.2349E-16 0.2319E-16 H2,gas 0.6216E-06 1.0006 0.6543E-06 0.6539E-06 H2S,gas 0.1422E-14 0.9959 0.1490E-14 0.1496E-14 S2,gas 0.1846E-36 1.0000 0.1942E-36 0.1942E-36 CO,gas 0.2186E-15 1.0000 0.2300E-15 0.2300E-15 SO3,gas 0.2347E-38 1.0000 0.2469E-38 0.2469E-38 SO2,gas 0.5809E-22 1.0000 0.6111E-22 0.6111E-22 HCl,gas 0.2335E-16 1.0000 0.2456E-16 0.2456E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.23 -7.87 -2.622 0.13433E+05 -5.867 3 CH4,gas 4.81 -13.82 -18.63 -4.657 0.31809E+05 -16.629 4 H2,gas 8.29 0.10 -8.18 -4.677 0.13974E+05 -6.184 5 H2S,gas -5.94 -22.77 -16.83 -8.413 0.28731E+05 -14.827 6 S2,gas -7.03 -45.74 -38.71 -5.956 0.66099E+05 -36.712 7 CO,gas 3.51 -14.13 -17.64 -5.427 0.30117E+05 -15.638 8 SO3,gas 17.43 -23.18 -40.61 -10.152 0.69336E+05 -38.608 9 SO2,gas 1.14 -23.08 -24.21 -6.457 0.41345E+05 -22.214 10 HCl,gas 5.48 -13.13 -18.61 -9.305 0.31776E+05 -16.610 11 acmite 7.74 6.26 -1.47 -0.153 0.25163E+04 15 albite-high 0.75 -0.77 -1.52 -0.117 0.26022E+04 16 albite -0.33 -0.77 -0.45 -0.034 0.76153E+03 19 spessartine 24.55 20.65 -3.90 -0.195 0.66507E+04 20 analcite 3.37 2.52 -0.85 -0.094 0.14518E+04 21 andalusite 5.06 1.82 -3.25 -0.325 0.55427E+04 22 andradite 39.09 34.35 -4.74 -0.246 0.80852E+04 26 annite 20.21 16.62 -3.59 -0.199 0.61310E+04 27 phlogopite 27.15 23.30 -3.84 -0.214 0.65632E+04 29 anorthite 12.80 9.07 -3.73 -0.287 0.63685E+04 32 apatite-OH -17.99 -17.99 0.00 0.000 0.51053E+00 35 aragonite 0.99 -3.68 -4.67 -1.557 0.79747E+04 36 brucite 12.58 8.58 -4.00 -0.800 0.68272E+04 37 calcite 0.83 -3.68 -4.52 -1.506 0.77134E+04 38 carnegieite-low 9.06 5.82 -3.25 -0.464 0.55483E+04 39 carnegieite-high 10.13 5.82 -4.32 -0.617 0.73751E+04 40 carpholite-Mg 8.65 7.10 -1.55 -0.103 0.26478E+04 41 carpholite-Fe 6.78 4.87 -1.91 -0.127 0.32634E+04 42 celadonite 5.40 2.85 -2.55 -0.150 0.43521E+04 43 celadonite-Fe 3.94 0.62 -3.31 -0.195 0.56574E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81827E+04 50 chloritoid-Mg 13.26 10.39 -2.87 -0.191 0.48950E+04 51 chloritoid-Fe 9.24 8.17 -1.07 -0.071 0.18309E+04 52 chloritoid-Mn 11.46 10.29 -1.17 -0.078 0.19994E+04 54 coesite -2.37 -3.29 -0.93 -0.308 0.15801E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.29 -0.75 -0.249 0.12730E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.54 -3.68 -0.368 0.62842E+04 68 hedenbergite 14.24 10.31 -3.94 -0.394 0.67230E+04 75 epidote 24.78 22.62 -2.16 -0.105 0.36828E+04 76 clinozoisite 22.92 18.88 -4.05 -0.184 0.69086E+04 77 epidote-Fe 29.94 26.36 -3.58 -0.186 0.61044E+04 78 fayalite 14.08 9.41 -4.67 -0.668 0.79798E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63745E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.52 -1.73 -0.173 0.29548E+04 97 kalsilite 7.62 4.16 -3.46 -0.495 0.59122E+04 98 kaolinite -1.27 -1.48 -0.21 -0.019 0.35066E+03 99 kyanite 4.93 1.82 -3.12 -0.312 0.53195E+04 101 laumontite 2.97 2.48 -0.50 -0.033 0.84717E+03 102 lawsonite 9.68 9.07 -0.61 -0.041 0.10424E+04 103 leucite 4.17 0.86 -3.30 -0.330 0.56427E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70730E+04 107 magnetite 20.13 18.95 -1.19 -0.097 0.20234E+04 108 minnesotaite 10.46 5.87 -4.59 -0.270 0.78361E+04 113 margarite 17.45 14.18 -3.27 -0.131 0.55884E+04 122 nepheline 8.38 5.82 -2.56 -0.366 0.43762E+04 134 phlogopite-Na 29.73 24.96 -4.77 -0.265 0.81467E+04 136 prehnite 19.47 16.32 -3.15 -0.185 0.53731E+04 137 prehnite-Fe 22.59 20.06 -2.52 -0.152 0.43095E+04 138 pumpellyite-Fe 46.47 41.54 -4.93 -0.109 0.84108E+04 145 pyroxmangite 7.42 5.18 -2.23 -0.447 0.38158E+04 146 pyrophyllite -6.10 -8.07 -1.97 -0.123 0.33637E+04 147 quartz -2.98 -3.29 -0.31 -0.104 0.53401E+03 151 rhodochrosite -0.96 -5.75 -4.80 -1.599 0.81892E+04 152 rhodonite 7.46 5.18 -2.28 -0.456 0.38950E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.82 -3.51 -0.351 0.59849E+04 164 stilpnomelane-Fe 13.18 12.95 -0.23 -0.007 0.38791E+03 165 stilpnomelane-Mg 27.60 24.09 -3.50 -0.105 0.59827E+04 168 sudoite 21.22 17.49 -3.72 -0.120 0.63553E+04 171 talc 16.55 12.56 -4.00 -0.235 0.68261E+04 174 tephroite 18.11 13.66 -4.46 -0.637 0.76078E+04 177 topaz-H 4.67 1.82 -2.85 -0.259 0.48685E+04 178 tridymite -2.61 -3.29 -0.68 -0.227 0.11613E+04 187 wairakite 4.06 2.48 -1.58 -0.093 0.26980E+04 188 walstromite 11.53 7.25 -4.28 -0.855 0.73015E+04 189 wollastonite 10.48 7.25 -3.23 -0.646 0.55154E+04 190 pseudo-wollastonite 11.02 7.25 -3.77 -0.754 0.64340E+04 191 zoisite 22.96 18.88 -4.09 -0.186 0.69812E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.40 -2.84 -0.176 0.48451E+04 194 beidellite-H -2.24 -6.14 -3.90 -0.249 0.66529E+04 195 beidellite-K -1.44 -4.52 -3.09 -0.189 0.52700E+04 196 beidellite-Mg -1.71 -4.72 -3.02 -0.187 0.51483E+04 197 beidellite-Na -1.26 -3.97 -2.72 -0.166 0.46400E+04 199 chalcedony -2.79 -3.29 -0.50 -0.167 0.85433E+03 201 montmorillonite-Ca -2.21 -4.34 -2.13 -0.132 0.36307E+04 202 montmorillonite-K -2.16 -4.46 -2.30 -0.141 0.39332E+04 203 montmorillonite-Mg -2.40 -4.67 -2.26 -0.140 0.38649E+04 204 montmorillonite-Na -1.96 -3.92 -1.96 -0.120 0.33414E+04 205 nontronite-Ca 3.28 3.09 -0.19 -0.012 0.32492E+03 206 nontronite-H 2.60 1.35 -1.25 -0.084 0.21284E+04 207 nontronite-K 3.40 2.97 -0.44 -0.028 0.74893E+03 208 nontronite-Mg 3.14 2.76 -0.37 -0.024 0.63970E+03 209 nontronite-Na 3.58 3.51 -0.07 -0.005 0.12066E+03 224 tobermorite 9.84 5.49 -4.35 -1.187 0.74251E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.35 -3.47 -0.869 0.59319E+04 240 silica-amorphous -2.08 -3.29 -1.21 -0.405 0.20745E+04 242 an20ab80 2.08 1.19 -0.89 -0.068 0.15113E+04 243 an25ab75 2.71 1.69 -1.02 -0.079 0.17467E+04 244 an30ab70 3.34 2.18 -1.17 -0.090 0.19904E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.7590000 g New total amount of reactant added: 1.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4572E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.7990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1513303E-02 Osmotic coef. = 0.9779 True ionic strength = .2381954E-02 Chg. balance for total moles = 0.4572E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.61462E-09 -9.2114 0.56759E-09 -9.2460 0.92348E+00 -0.0346 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12726E-03 -3.8953 0.92260E+00 -0.0350 4 SO4-- 0.25498E-04 -4.5935 0.19531E-04 -4.7093 0.76600E+00 -0.1158 5 HCO3- 0.10919E-04 -4.9618 0.10076E-04 -4.9967 0.92281E+00 -0.0349 6 HS- 0.32935E-13 -13.4823 0.30386E-13 -13.5173 0.92262E+00 -0.0350 7 Al+++ 0.11730E-24 -24.9307 0.65704E-25 -25.1824 0.56015E+00 -0.2517 8 H4SiO4 0.50070E-03 -3.3004 0.50070E-03 -3.3004 0.10000E+01 0.0000 9 Ca++ 0.16235E-07 -7.7896 0.12422E-07 -7.9058 0.76512E+00 -0.1163 10 Mg++ 0.16078E-09 -9.7938 0.12293E-09 -9.9103 0.76457E+00 -0.1166 11 Fe++ 0.95085E-12 -12.0219 0.72712E-12 -12.1384 0.76470E+00 -0.1165 12 K+ 0.50452E-04 -4.2971 0.46560E-04 -4.3320 0.92285E+00 -0.0349 13 Na+ 0.22932E-02 -2.6396 0.21157E-02 -2.6746 0.92258E+00 -0.0350 14 Mn++ 0.12704E-09 -9.8961 0.97162E-10 -10.0125 0.76480E+00 -0.1165 15 HPO4-- 0.10540E-04 -4.9772 0.80740E-05 -5.0929 0.76602E+00 -0.1158 16 HSiO3- 0.93290E-03 -3.0302 0.86069E-03 -3.0652 0.92260E+00 -0.0350 17 Ca(HSiO3)+ 0.25956E-09 -9.5858 0.23954E-09 -9.6206 0.92288E+00 -0.0349 18 Mg(HSiO3)+ 0.31967E-11 -11.4953 0.29502E-11 -11.5301 0.92288E+00 -0.0349 19 NaHSiO3,aq 0.28921E-04 -4.5388 0.28921E-04 -4.5388 0.10000E+01 0.0000 20 AlO+ 0.28530E-13 -13.5447 0.26329E-13 -13.5796 0.92288E+00 -0.0349 21 AlOH+2 0.97868E-19 -19.0094 0.74861E-19 -19.1257 0.76492E+00 -0.1164 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.39593E-04 -4.4024 0.36518E-04 -4.4375 0.92233E+00 -0.0351 24 CH4,aq 0.15390E-19 -19.8128 0.15383E-19 -19.8130 0.99953E+00 -0.0002 29 CO,aq 0.14390E-18 -18.8419 0.14390E-18 -18.8419 0.10000E+01 0.0000 30 CO2,aq 0.11536E-07 -7.9379 0.11531E-07 -7.9381 0.99953E+00 -0.0002 31 CO3-2 0.21436E-05 -5.6689 0.16414E-05 -5.7848 0.76574E+00 -0.1159 32 CaCO3,aq 0.24971E-09 -9.6026 0.24971E-09 -9.6026 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.34173E-11 -11.4663 0.31537E-11 -11.5012 0.92288E+00 -0.0349 34 CaCl+ 0.27294E-11 -11.5639 0.25189E-11 -11.5988 0.92288E+00 -0.0349 35 CaCl2,aq 0.74634E-16 -16.1271 0.74634E-16 -16.1271 0.10000E+01 0.0000 36 CaOH+ 0.16721E-08 -8.7767 0.15432E-08 -8.8116 0.92288E+00 -0.0349 37 CaSO4,aq 0.75591E-10 -10.1215 0.75591E-10 -10.1215 0.10000E+01 0.0000 38 HCl,aq 0.13586E-13 -13.8669 0.13586E-13 -13.8669 0.10000E+01 0.0000 43 FeCl+ 0.15616E-15 -15.8064 0.14412E-15 -15.8413 0.92288E+00 -0.0349 46 FeO,aq 0.89253E-10 -10.0494 0.89253E-10 -10.0494 0.10000E+01 0.0000 47 FeOH+ 0.46020E-10 -10.3371 0.42471E-10 -10.3719 0.92288E+00 -0.0349 48 HFeO2- 0.18333E-08 -8.7368 0.16914E-08 -8.7718 0.92260E+00 -0.0350 49 FeO+ 0.50875E-14 -14.2935 0.46952E-14 -14.3283 0.92288E+00 -0.0349 51 FeO2- 0.31047E-08 -8.5080 0.28644E-08 -8.5430 0.92260E+00 -0.0350 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.48478E-09 -9.3145 0.48456E-09 -9.3147 0.99953E+00 -0.0002 54 KCl,aq 0.10491E-09 -9.9792 0.10491E-09 -9.9792 0.10000E+01 0.0000 55 KHSO4,aq 0.13812E-17 -17.8597 0.13812E-17 -17.8597 0.10000E+01 0.0000 56 KOH,aq 0.35761E-07 -7.4466 0.35761E-07 -7.4466 0.10000E+01 0.0000 57 KSO4- 0.15186E-07 -7.8186 0.14010E-07 -7.8536 0.92260E+00 -0.0350 58 MgCO3,aq 0.61752E-12 -12.2093 0.61752E-12 -12.2093 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.34486E-13 -13.4624 0.31826E-13 -13.4972 0.92288E+00 -0.0349 60 MgCl+ 0.24521E-13 -13.6105 0.22630E-13 -13.6453 0.92288E+00 -0.0349 61 MgOH+ 0.91677E-10 -10.0377 0.84607E-10 -10.0726 0.92288E+00 -0.0349 63 MnO,aq 0.31838E-09 -9.4971 0.31838E-09 -9.4971 0.10000E+01 0.0000 64 MnOH+ 0.57126E-09 -9.2432 0.52720E-09 -9.2780 0.92288E+00 -0.0349 65 MnO2-2 0.44634E-13 -13.3503 0.34178E-13 -13.4662 0.76574E+00 -0.1159 66 HMnO2- 0.45557E-11 -11.3414 0.42031E-11 -11.3764 0.92260E+00 -0.0350 69 MnCl+ 0.81086E-13 -13.0911 0.74833E-13 -13.1259 0.92288E+00 -0.0349 70 MnSO4,aq 0.53781E-12 -12.2694 0.53781E-12 -12.2694 0.10000E+01 0.0000 71 NaCl,aq 0.87910E-07 -7.0560 0.87910E-07 -7.0560 0.10000E+01 0.0000 72 NaOH,aq 0.16379E-05 -5.7857 0.16379E-05 -5.7857 0.10000E+01 0.0000 74 OH- 0.11458E-02 -2.9409 0.10568E-02 -2.9760 0.92233E+00 -0.0351 79 HPO3-2 0.16138E-16 -16.7922 0.12357E-16 -16.9081 0.76574E+00 -0.1159 81 H2PO3- 0.14933E-19 -19.8258 0.13777E-19 -19.8608 0.92260E+00 -0.0350 82 H3PO4,aq 0.16746E-13 -13.7761 0.16746E-13 -13.7761 0.10000E+01 0.0000 83 H2PO4- 0.87072E-07 -7.0601 0.80344E-07 -7.0950 0.92273E+00 -0.0349 84 PO4-3 0.22006E-07 -7.6575 0.12423E-07 -7.9058 0.56453E+00 -0.2483 87 H2P2O7-2 0.65977E-15 -15.1806 0.50521E-15 -15.2965 0.76574E+00 -0.1159 88 HP2O7-3 0.32581E-12 -12.4870 0.18252E-12 -12.7387 0.56020E+00 -0.2517 89 P2O7-4 0.21827E-12 -12.6610 0.79330E-13 -13.1006 0.36345E+00 -0.4396 90 H2S,aq 0.51844E-16 -16.2853 0.51819E-16 -16.2855 0.99953E+00 -0.0002 97 SO3-2 0.16813E-14 -14.7744 0.12904E-14 -14.8893 0.76750E+00 -0.1149 98 HSO3- 0.46458E-16 -16.3329 0.42862E-16 -16.3679 0.92260E+00 -0.0350 99 HSO4- 0.11144E-10 -10.9530 0.10286E-10 -10.9878 0.92301E+00 -0.0348 Charge balance for all species = 0.4738E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6146185E-09 -.2269789E-02 -.2287339E+01 0.0000 2 H2O 0.1000000E+01 0.5550852E+02 0.9997961E+06 0.0000 3 Cl- 0.1379326E-03 0.1380206E-03 0.4892233E+01 5.3506 4 SO4-- 0.2549777E-04 0.2551334E-04 0.2450346E+01 13.7827 5 HCO3- 0.1091905E-04 0.1307440E-04 0.7975983E+00 4.2493 6 HS- 0.3293490E-13 -.2922992E-09 -.9664923E-05 -4.2714 7 Al+++ 0.1172966E-24 0.3960260E-04 0.1068317E+01 2.5555 8 H4SiO4 0.5006997E-03 0.1462520E-02 0.1405417E+03 -3.3004 9 Ca++ 0.1623480E-07 0.1849793E-07 0.7412071E-03 10.5861 10 Mg++ 0.1607825E-09 0.2563332E-09 0.6230687E-05 8.5816 11 Fe++ 0.9508545E-12 0.5277739E-08 0.2946850E-03 6.3535 12 K+ 0.5045246E-04 0.5050351E-04 0.1974381E+01 4.9140 13 Na+ 0.2293201E-02 0.2323848E-02 0.5341377E+02 6.5714 14 Mn++ 0.1270421E-09 0.1021905E-08 0.5612981E-04 8.4794 15 HPO4-- 0.1054022E-04 0.1064930E-04 0.1021898E+01 13.3990 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2977573E-01 -.2269026E-02 -.2750670E-01 0.0000000E+00 2 H2O 0.5548570E+02 0.5548985E+02 -.4155896E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7536089E-04 0.2550476E-04 0.4985613E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4985642E-04 -.2922009E-09 -.4985613E-04 0.0000000E+00 7 Al+++ 0.5866074E-02 0.3958928E-04 0.5826485E-02 0.0000000E+00 8 H4SiO4 0.1873260E-01 0.1462028E-02 0.1727057E-01 0.0000000E+00 9 Ca++ 0.2083578E-02 0.1849172E-07 0.2083559E-02 0.0000000E+00 10 Mg++ 0.1427778E-02 0.2562470E-09 0.1427778E-02 0.0000000E+00 11 Fe++ 0.1282702E-02 0.5275965E-08 0.1282697E-02 0.0000000E+00 12 K+ 0.3819533E-03 0.5048654E-04 0.3314668E-03 0.0000000E+00 13 Na+ 0.2418254E-02 0.2323066E-02 0.9518781E-04 0.0000000E+00 14 Mn++ 0.3119213E-04 0.1021561E-08 0.3119111E-04 0.0000000E+00 15 HPO4-- 0.1064572E-04 0.1064572E-04 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.5692E-18 Mass of aqueous solution: 0.999870E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2856E-03 -3.544 0.1587 -0.799 8.248 0.6037E-01 daphnite 0.1768E-03 -3.753 0.1261 -0.899 6.554 0.3822E-01 chlorite-Mn 0.6238E-05 -5.205 0.4423E-02 -2.354 0.2298 0.1409E-02 hematite 0.1994E-03 -3.700 0.3185E-01 -1.497 1.655 0.6036E-02 microcline 0.2789E-03 -3.555 0.7762E-01 -1.110 4.033 0.3032E-01 muscovite 0.5260E-04 -4.279 0.2095E-01 -1.679 1.089 0.7409E-02 paragonite 0.9519E-04 -4.021 0.3638E-01 -1.439 1.891 0.1258E-01 stilbite 0.2084E-02 -2.681 1.468 0.167 76.30 0.6849 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.924396 g Volume = 0.841197 cm3 Porosity: 51.0818% V(tot) - V(min): 0.87840E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.7990000 g log = 0.2550 Original solution: 1000.0103000 g Original solution / Rock added: 555.87 (Water/Rock Ratio), log = 2.7450 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1246E-05 1.0073 0.1320E-05 0.1310E-05 CH4,gas 0.2283E-16 1.0129 0.2433E-16 0.2402E-16 H2,gas 0.6314E-06 1.0006 0.6646E-06 0.6642E-06 H2S,gas 0.1443E-14 0.9959 0.1511E-14 0.1518E-14 S2,gas 0.1841E-36 1.0000 0.1937E-36 0.1937E-36 CO,gas 0.2160E-15 1.0000 0.2272E-15 0.2272E-15 SO3,gas 0.2236E-38 1.0000 0.2352E-38 0.2352E-38 SO2,gas 0.5622E-22 1.0000 0.5914E-22 0.5914E-22 HCl,gas 0.2280E-16 1.0000 0.2399E-16 0.2399E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 32 apatite-OH -17.99 -17.82 0.16 0.013 -0.28137E+03 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.24 -7.88 -2.626 0.13454E+05 -5.879 3 CH4,gas 4.81 -13.80 -18.61 -4.653 0.31783E+05 -16.614 4 H2,gas 8.29 0.11 -8.18 -4.673 0.13963E+05 -6.177 5 H2S,gas -5.94 -22.76 -16.82 -8.410 0.28721E+05 -14.821 6 S2,gas -7.03 -45.75 -38.71 -5.956 0.66101E+05 -36.713 7 CO,gas 3.51 -14.13 -17.64 -5.429 0.30126E+05 -15.644 8 SO3,gas 17.43 -23.20 -40.63 -10.157 0.69372E+05 -38.629 9 SO2,gas 1.14 -23.09 -24.23 -6.461 0.41369E+05 -22.228 10 HCl,gas 5.48 -13.14 -18.62 -9.310 0.31793E+05 -16.620 11 acmite 7.74 6.27 -1.47 -0.153 0.25066E+04 15 albite-high 0.75 -0.77 -1.52 -0.117 0.26022E+04 16 albite -0.33 -0.77 -0.45 -0.034 0.76153E+03 19 spessartine 24.55 20.65 -3.90 -0.195 0.66624E+04 20 analcite 3.37 2.53 -0.84 -0.094 0.14421E+04 21 andalusite 5.06 1.81 -3.25 -0.325 0.55524E+04 22 andradite 39.09 34.45 -4.63 -0.241 0.79108E+04 26 annite 20.21 16.63 -3.58 -0.199 0.61136E+04 27 phlogopite 27.15 23.31 -3.83 -0.213 0.65458E+04 29 anorthite 12.80 9.10 -3.70 -0.285 0.63201E+04 35 aragonite 0.99 -3.66 -4.64 -1.548 0.79274E+04 36 brucite 12.58 8.58 -4.00 -0.799 0.68214E+04 37 calcite 0.83 -3.66 -4.49 -1.497 0.76661E+04 38 carnegieite-low 9.06 5.83 -3.24 -0.463 0.55289E+04 39 carnegieite-high 10.13 5.83 -4.31 -0.615 0.73558E+04 40 carpholite-Mg 8.65 7.09 -1.56 -0.104 0.26613E+04 41 carpholite-Fe 6.78 4.86 -1.92 -0.128 0.32770E+04 42 celadonite 5.40 2.85 -2.55 -0.150 0.43560E+04 43 celadonite-Fe 3.94 0.62 -3.32 -0.195 0.56613E+04 44 chrysotile 23.94 19.14 -4.79 -0.399 0.81846E+04 50 chloritoid-Mg 13.26 10.39 -2.87 -0.191 0.48989E+04 51 chloritoid-Fe 9.24 8.16 -1.07 -0.072 0.18348E+04 52 chloritoid-Mn 11.46 10.29 -1.17 -0.078 0.20032E+04 54 coesite -2.37 -3.30 -0.93 -0.310 0.15898E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.30 -0.75 -0.250 0.12827E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.57 -3.65 -0.365 0.62299E+04 68 hedenbergite 14.24 10.34 -3.91 -0.391 0.66687E+04 75 epidote 24.78 22.68 -2.09 -0.102 0.35762E+04 76 clinozoisite 22.92 18.94 -3.98 -0.181 0.68021E+04 77 epidote-Fe 29.94 26.42 -3.51 -0.182 0.59978E+04 78 fayalite 14.08 9.41 -4.67 -0.667 0.79778E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63764E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.53 -1.72 -0.172 0.29451E+04 97 kalsilite 7.62 4.17 -3.45 -0.493 0.58928E+04 98 kaolinite -1.27 -1.49 -0.22 -0.020 0.37003E+03 99 kyanite 4.93 1.81 -3.12 -0.312 0.53291E+04 101 laumontite 2.97 2.50 -0.48 -0.032 0.81810E+03 102 lawsonite 9.68 9.10 -0.58 -0.039 0.99395E+03 103 leucite 4.17 0.87 -3.30 -0.330 0.56330E+04 105 lizardite 23.29 19.14 -4.14 -0.345 0.70749E+04 107 magnetite 20.13 18.95 -1.18 -0.096 0.20176E+04 108 minnesotaite 10.46 5.86 -4.60 -0.271 0.78574E+04 113 margarite 17.45 14.21 -3.24 -0.130 0.55400E+04 122 nepheline 8.38 5.83 -2.55 -0.365 0.43569E+04 134 phlogopite-Na 29.73 24.97 -4.76 -0.264 0.81292E+04 136 prehnite 19.47 16.38 -3.08 -0.181 0.52665E+04 137 prehnite-Fe 22.59 20.13 -2.46 -0.148 0.42029E+04 138 pumpellyite-Fe 46.47 41.67 -4.80 -0.107 0.81918E+04 145 pyroxmangite 7.42 5.18 -2.24 -0.447 0.38197E+04 146 pyrophyllite -6.10 -8.09 -1.99 -0.125 0.34024E+04 147 quartz -2.98 -3.30 -0.32 -0.106 0.54370E+03 151 rhodochrosite -0.96 -5.76 -4.80 -1.602 0.82039E+04 152 rhodonite 7.46 5.18 -2.28 -0.457 0.38989E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.81 -3.51 -0.351 0.59946E+04 164 stilpnomelane-Fe 13.18 12.93 -0.25 -0.007 0.42182E+03 165 stilpnomelane-Mg 27.60 24.07 -3.52 -0.105 0.60166E+04 168 sudoite 21.22 17.48 -3.73 -0.120 0.63728E+04 171 talc 16.55 12.54 -4.01 -0.236 0.68475E+04 174 tephroite 18.11 13.66 -4.45 -0.636 0.76059E+04 177 topaz-H 4.67 1.81 -2.86 -0.260 0.48782E+04 178 tridymite -2.61 -3.30 -0.69 -0.229 0.11710E+04 187 wairakite 4.06 2.50 -1.56 -0.092 0.26689E+04 188 walstromite 11.53 7.29 -4.24 -0.848 0.72434E+04 189 wollastonite 10.48 7.29 -3.20 -0.639 0.54573E+04 190 pseudo-wollastonite 11.02 7.29 -3.73 -0.747 0.63759E+04 191 zoisite 22.96 18.94 -4.03 -0.183 0.68746E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.41 -2.85 -0.176 0.48695E+04 194 beidellite-H -2.24 -6.16 -3.92 -0.250 0.66884E+04 195 beidellite-K -1.44 -4.54 -3.10 -0.190 0.52959E+04 196 beidellite-Mg -1.71 -4.74 -3.04 -0.188 0.51829E+04 197 beidellite-Na -1.26 -3.99 -2.73 -0.167 0.46659E+04 199 chalcedony -2.79 -3.30 -0.51 -0.169 0.86402E+03 201 montmorillonite-Ca -2.21 -4.36 -2.14 -0.132 0.36563E+04 202 montmorillonite-K -2.16 -4.48 -2.32 -0.142 0.39605E+04 203 montmorillonite-Mg -2.40 -4.69 -2.28 -0.141 0.39007E+04 204 montmorillonite-Na -1.96 -3.93 -1.97 -0.121 0.33687E+04 205 nontronite-Ca 3.28 3.08 -0.20 -0.013 0.34929E+03 206 nontronite-H 2.60 1.33 -1.27 -0.085 0.21640E+04 207 nontronite-K 3.40 2.95 -0.45 -0.029 0.77489E+03 208 nontronite-Mg 3.14 2.74 -0.39 -0.026 0.67429E+03 209 nontronite-Na 3.58 3.50 -0.09 -0.006 0.14662E+03 224 tobermorite 9.84 5.52 -4.32 -1.179 0.73783E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.35 -3.47 -0.868 0.59261E+04 240 silica-amorphous -2.08 -3.30 -1.22 -0.407 0.20842E+04 242 an20ab80 2.08 1.20 -0.88 -0.068 0.15016E+04 243 an25ab75 2.71 1.69 -1.02 -0.078 0.17346E+04 244 an30ab70 3.34 2.19 -1.16 -0.089 0.19758E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.7990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1508422E-02 Osmotic coef. = 0.9779 True ionic strength = .2376315E-02 Chg. balance for total moles = 0.4572E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.61544E-09 -9.2108 0.56839E-09 -9.2454 0.92354E+00 -0.0345 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12727E-03 -3.8953 0.92266E+00 -0.0350 4 SO4-- 0.25498E-04 -4.5935 0.19537E-04 -4.7092 0.76621E+00 -0.1157 5 HCO3- 0.10922E-04 -4.9617 0.10080E-04 -4.9966 0.92287E+00 -0.0349 6 HS- 0.32817E-13 -13.4839 0.30280E-13 -13.5188 0.92268E+00 -0.0349 7 Al+++ 0.11772E-24 -24.9291 0.65982E-25 -25.1806 0.56050E+00 -0.2514 8 H4SiO4 0.50124E-03 -3.3000 0.50124E-03 -3.3000 0.10000E+01 0.0000 9 Ca++ 0.16153E-07 -7.7917 0.12363E-07 -7.9079 0.76533E+00 -0.1161 10 Mg++ 0.16109E-09 -9.7929 0.12320E-09 -9.9094 0.76478E+00 -0.1165 11 Fe++ 0.95265E-12 -12.0211 0.72870E-12 -12.1375 0.76491E+00 -0.1164 12 K+ 0.50356E-04 -4.2979 0.46474E-04 -4.3328 0.92291E+00 -0.0348 13 Na+ 0.22888E-02 -2.6404 0.21118E-02 -2.6754 0.92264E+00 -0.0350 14 Mn++ 0.12728E-09 -9.8952 0.97373E-10 -10.0116 0.76501E+00 -0.1163 15 HPO4-- 0.93769E-05 -5.0279 0.71848E-05 -5.1436 0.76622E+00 -0.1156 16 HSiO3- 0.93253E-03 -3.0303 0.86041E-03 -3.0653 0.92266E+00 -0.0350 17 Ca(HSiO3)+ 0.25822E-09 -9.5880 0.23832E-09 -9.6228 0.92294E+00 -0.0348 18 Mg(HSiO3)+ 0.32024E-11 -11.4945 0.29556E-11 -11.5293 0.92294E+00 -0.0348 19 NaHSiO3,aq 0.28858E-04 -4.5397 0.28858E-04 -4.5397 0.10000E+01 0.0000 20 AlO+ 0.28568E-13 -13.5441 0.26366E-13 -13.5790 0.92294E+00 -0.0348 21 AlOH+2 0.98117E-19 -19.0083 0.75072E-19 -19.1245 0.76513E+00 -0.1163 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.39535E-04 -4.4030 0.36467E-04 -4.4381 0.92240E+00 -0.0351 24 CH4,aq 0.15337E-19 -19.8143 0.15330E-19 -19.8145 0.99953E+00 -0.0002 29 CO,aq 0.14397E-18 -18.8417 0.14397E-18 -18.8417 0.10000E+01 0.0000 30 CO2,aq 0.11556E-07 -7.9372 0.11551E-07 -7.9374 0.99953E+00 -0.0002 31 CO3-2 0.21407E-05 -5.6695 0.16396E-05 -5.7853 0.76595E+00 -0.1158 32 CaCO3,aq 0.24826E-09 -9.6051 0.24826E-09 -9.6051 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.34019E-11 -11.4683 0.31398E-11 -11.5031 0.92294E+00 -0.0348 34 CaCl+ 0.27164E-11 -11.5660 0.25071E-11 -11.6008 0.92294E+00 -0.0348 35 CaCl2,aq 0.74290E-16 -16.1291 0.74290E-16 -16.1291 0.10000E+01 0.0000 36 CaOH+ 0.16617E-08 -8.7794 0.15337E-08 -8.8143 0.92294E+00 -0.0348 37 CaSO4,aq 0.75253E-10 -10.1235 0.75253E-10 -10.1235 0.10000E+01 0.0000 38 HCl,aq 0.13606E-13 -13.8663 0.13606E-13 -13.8663 0.10000E+01 0.0000 43 FeCl+ 0.15650E-15 -15.8055 0.14444E-15 -15.8403 0.92294E+00 -0.0348 46 FeO,aq 0.89195E-10 -10.0497 0.89195E-10 -10.0497 0.10000E+01 0.0000 47 FeOH+ 0.46052E-10 -10.3368 0.42503E-10 -10.3716 0.92294E+00 -0.0348 48 HFeO2- 0.18294E-08 -8.7377 0.16879E-08 -8.7727 0.92266E+00 -0.0350 49 FeO+ 0.50943E-14 -14.2929 0.47018E-14 -14.3277 0.92294E+00 -0.0348 51 FeO2- 0.31002E-08 -8.5086 0.28604E-08 -8.5436 0.92266E+00 -0.0350 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.48415E-09 -9.3150 0.48393E-09 -9.3152 0.99953E+00 -0.0002 54 KCl,aq 0.10473E-09 -9.9799 0.10473E-09 -9.9799 0.10000E+01 0.0000 55 KHSO4,aq 0.13810E-17 -17.8598 0.13810E-17 -17.8598 0.10000E+01 0.0000 56 KOH,aq 0.35645E-07 -7.4480 0.35645E-07 -7.4480 0.10000E+01 0.0000 57 KSO4- 0.15161E-07 -7.8193 0.13988E-07 -7.8542 0.92266E+00 -0.0350 58 MgCO3,aq 0.61820E-12 -12.2089 0.61820E-12 -12.2089 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.34570E-13 -13.4613 0.31906E-13 -13.4961 0.92294E+00 -0.0348 60 MgCl+ 0.24574E-13 -13.6095 0.22681E-13 -13.6443 0.92294E+00 -0.0348 61 MgOH+ 0.91741E-10 -10.0374 0.84671E-10 -10.0723 0.92294E+00 -0.0348 63 MnO,aq 0.31817E-09 -9.4973 0.31817E-09 -9.4973 0.10000E+01 0.0000 64 MnOH+ 0.57166E-09 -9.2429 0.52761E-09 -9.2777 0.92294E+00 -0.0348 65 MnO2-2 0.44468E-13 -13.3520 0.34060E-13 -13.4678 0.76595E+00 -0.1158 66 HMnO2- 0.45460E-11 -11.3424 0.41944E-11 -11.3773 0.92266E+00 -0.0350 69 MnCl+ 0.81262E-13 -13.0901 0.75000E-13 -13.1249 0.92294E+00 -0.0348 70 MnSO4,aq 0.53912E-12 -12.2683 0.53912E-12 -12.2683 0.10000E+01 0.0000 71 NaCl,aq 0.87755E-07 -7.0567 0.87755E-07 -7.0567 0.10000E+01 0.0000 72 NaOH,aq 0.16326E-05 -5.7871 0.16326E-05 -5.7871 0.10000E+01 0.0000 74 OH- 0.11441E-02 -2.9415 0.10553E-02 -2.9766 0.92240E+00 -0.0351 79 HPO3-2 0.14338E-16 -16.8435 0.10982E-16 -16.9593 0.76595E+00 -0.1158 81 H2PO3- 0.13289E-19 -19.8765 0.12261E-19 -19.9115 0.92266E+00 -0.0350 82 H3PO4,aq 0.14944E-13 -13.8255 0.14944E-13 -13.8255 0.10000E+01 0.0000 83 H2PO4- 0.77587E-07 -7.1102 0.71597E-07 -7.1451 0.92280E+00 -0.0349 84 PO4-3 0.19543E-07 -7.7090 0.11039E-07 -7.9571 0.56487E+00 -0.2480 87 H2P2O7-2 0.52379E-15 -15.2808 0.40119E-15 -15.3966 0.76595E+00 -0.1158 88 HP2O7-3 0.25820E-12 -12.5880 0.14474E-12 -12.8394 0.56055E+00 -0.2514 89 P2O7-4 0.17266E-12 -12.7628 0.62820E-13 -13.2019 0.36384E+00 -0.4391 90 H2S,aq 0.51735E-16 -16.2862 0.51710E-16 -16.2864 0.99953E+00 -0.0002 97 SO3-2 0.16791E-14 -14.7749 0.12891E-14 -14.8897 0.76771E+00 -0.1148 98 HSO3- 0.46473E-16 -16.3328 0.42879E-16 -16.3678 0.92266E+00 -0.0350 99 HSO4- 0.11162E-10 -10.9523 0.10303E-10 -10.9870 0.92308E+00 -0.0348 Charge balance for all species = 0.4565E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6154430E-09 -.2267430E-02 -.2284962E+01 0.0000 2 H2O 0.1000000E+01 0.5550851E+02 0.9997963E+06 0.0000 3 Cl- 0.1379327E-03 0.1380205E-03 0.4892233E+01 5.3501 4 SO4-- 0.2549779E-04 0.2551333E-04 0.2450346E+01 13.7816 5 HCO3- 0.1092192E-04 0.1307439E-04 0.7975983E+00 4.2488 6 HS- 0.3281720E-13 -.2918838E-09 -.9651190E-05 -4.2735 7 Al+++ 0.1177200E-24 0.3954412E-04 0.1066740E+01 2.5555 8 H4SiO4 0.5012417E-03 0.1462631E-02 0.1405523E+03 -3.3000 9 Ca++ 0.1615329E-07 0.1840288E-07 0.7373984E-03 10.5828 10 Mg++ 0.1610866E-09 0.2567070E-09 0.6239774E-05 8.5813 11 Fe++ 0.9526528E-12 0.5269237E-08 0.2942104E-03 6.3533 12 K+ 0.5035636E-04 0.5040727E-04 0.1970619E+01 4.9126 13 Na+ 0.2288832E-02 0.2319410E-02 0.5331178E+02 6.5700 14 Mn++ 0.1272824E-09 0.1022324E-08 0.5615287E-04 8.4791 15 HPO4-- 0.9376924E-05 0.9474055E-05 0.9091228E+00 13.3471 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2977573E-01 -.2266669E-02 -.2750906E-01 0.0000000E+00 2 H2O 0.5548570E+02 0.5548987E+02 -.4168872E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7536089E-04 0.2550476E-04 0.4985613E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4985642E-04 -.2917857E-09 -.4985613E-04 0.0000000E+00 7 Al+++ 0.5866074E-02 0.3953084E-04 0.5826543E-02 0.0000000E+00 8 H4SiO4 0.1873260E-01 0.1462139E-02 0.1727046E-01 0.0000000E+00 9 Ca++ 0.2083578E-02 0.1839669E-07 0.2083559E-02 0.0000000E+00 10 Mg++ 0.1427778E-02 0.2566208E-09 0.1427778E-02 0.0000000E+00 11 Fe++ 0.1282702E-02 0.5267467E-08 0.1282697E-02 0.0000000E+00 12 K+ 0.3819533E-03 0.5039034E-04 0.3315630E-03 0.0000000E+00 13 Na+ 0.2418254E-02 0.2318631E-02 0.9962325E-04 0.0000000E+00 14 Mn++ 0.3119213E-04 0.1021981E-08 0.3119111E-04 0.0000000E+00 15 HPO4-- 0.1064572E-04 0.9470872E-05 0.1174848E-05 0.0000000E+00 Chg. balance for solid moles: -.2119E-17 Mass of aqueous solution: 0.999870E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2856E-03 -3.544 0.1587 -0.799 8.248 0.6037E-01 daphnite 0.1768E-03 -3.753 0.1261 -0.899 6.554 0.3822E-01 chlorite-Mn 0.6238E-05 -5.205 0.4423E-02 -2.354 0.2298 0.1409E-02 hematite 0.1994E-03 -3.700 0.3185E-01 -1.497 1.655 0.6036E-02 microcline 0.2837E-03 -3.547 0.7896E-01 -1.103 4.103 0.3084E-01 muscovite 0.4789E-04 -4.320 0.1908E-01 -1.720 0.9913 0.6745E-02 paragonite 0.9962E-04 -4.002 0.3808E-01 -1.419 1.979 0.1316E-01 stilbite 0.2082E-02 -2.682 1.467 0.166 76.23 0.6842 apatite-OH 0.3916E-06 -6.407 0.1967E-03 -3.706 0.1022E-01 0.6251E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.924369 g Volume = 0.841061 cm3 Porosity: 51.0897% V(tot) - V(min): 0.87854E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.7990000 g log = 0.2550 Original solution: 1000.0103000 g Original solution / Rock added: 555.87 (Water/Rock Ratio), log = 2.7450 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1248E-05 1.0073 0.1322E-05 0.1313E-05 CH4,gas 0.2275E-16 1.0129 0.2424E-16 0.2393E-16 H2,gas 0.6306E-06 1.0006 0.6637E-06 0.6634E-06 H2S,gas 0.1440E-14 0.9959 0.1508E-14 0.1514E-14 S2,gas 0.1838E-36 1.0000 0.1934E-36 0.1934E-36 CO,gas 0.2161E-15 1.0000 0.2273E-15 0.2273E-15 SO3,gas 0.2243E-38 1.0000 0.2360E-38 0.2360E-38 SO2,gas 0.5632E-22 1.0000 0.5925E-22 0.5925E-22 HCl,gas 0.2284E-16 1.0000 0.2402E-16 0.2402E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.21232E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 121 paragonite 4.34 4.34 0.00 0.000 0.43980E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.24 -7.88 -2.626 0.13453E+05 -5.879 3 CH4,gas 4.81 -13.81 -18.62 -4.654 0.31785E+05 -16.615 4 H2,gas 8.29 0.11 -8.18 -4.673 0.13964E+05 -6.178 5 H2S,gas -5.94 -22.76 -16.82 -8.411 0.28722E+05 -14.822 6 S2,gas -7.03 -45.75 -38.71 -5.956 0.66102E+05 -36.714 7 CO,gas 3.51 -14.13 -17.64 -5.429 0.30126E+05 -15.643 8 SO3,gas 17.43 -23.20 -40.63 -10.157 0.69370E+05 -38.627 9 SO2,gas 1.14 -23.09 -24.23 -6.461 0.41368E+05 -22.227 10 HCl,gas 5.48 -13.14 -18.62 -9.310 0.31792E+05 -16.619 11 acmite 7.74 6.27 -1.47 -0.153 0.25074E+04 15 albite-high 0.75 -0.77 -1.52 -0.117 0.26022E+04 16 albite -0.33 -0.77 -0.45 -0.034 0.76153E+03 19 spessartine 24.55 20.65 -3.90 -0.195 0.66614E+04 20 analcite 3.37 2.53 -0.85 -0.094 0.14429E+04 21 andalusite 5.06 1.81 -3.25 -0.325 0.55516E+04 22 andradite 39.09 34.45 -4.64 -0.241 0.79253E+04 26 annite 20.21 16.63 -3.58 -0.199 0.61150E+04 27 phlogopite 27.15 23.31 -3.83 -0.213 0.65472E+04 29 anorthite 12.80 9.09 -3.70 -0.285 0.63241E+04 35 aragonite 0.99 -3.66 -4.65 -1.548 0.79317E+04 36 brucite 12.58 8.58 -4.00 -0.799 0.68218E+04 37 calcite 0.83 -3.66 -4.49 -1.497 0.76704E+04 38 carnegieite-low 9.06 5.83 -3.24 -0.463 0.55305E+04 39 carnegieite-high 10.13 5.83 -4.31 -0.616 0.73574E+04 40 carpholite-Mg 8.65 7.09 -1.56 -0.104 0.26602E+04 41 carpholite-Fe 6.78 4.86 -1.92 -0.128 0.32759E+04 42 celadonite 5.40 2.85 -2.55 -0.150 0.43557E+04 43 celadonite-Fe 3.94 0.62 -3.32 -0.195 0.56610E+04 44 chrysotile 23.94 19.14 -4.79 -0.399 0.81845E+04 50 chloritoid-Mg 13.26 10.39 -2.87 -0.191 0.48986E+04 51 chloritoid-Fe 9.24 8.16 -1.07 -0.072 0.18345E+04 52 chloritoid-Mn 11.46 10.29 -1.17 -0.078 0.20029E+04 54 coesite -2.37 -3.30 -0.93 -0.310 0.15890E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.30 -0.75 -0.250 0.12819E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.56 -3.65 -0.365 0.62344E+04 68 hedenbergite 14.24 10.34 -3.91 -0.391 0.66732E+04 75 epidote 24.78 22.68 -2.10 -0.102 0.35850E+04 76 clinozoisite 22.92 18.93 -3.99 -0.181 0.68109E+04 77 epidote-Fe 29.94 26.42 -3.52 -0.183 0.60067E+04 78 fayalite 14.08 9.41 -4.67 -0.667 0.79780E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63763E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.53 -1.73 -0.173 0.29459E+04 97 kalsilite 7.62 4.17 -3.45 -0.493 0.58944E+04 98 kaolinite -1.27 -1.49 -0.22 -0.020 0.36843E+03 99 kyanite 4.93 1.81 -3.12 -0.312 0.53283E+04 101 laumontite 2.97 2.49 -0.48 -0.032 0.82051E+03 102 lawsonite 9.68 9.09 -0.58 -0.039 0.99796E+03 103 leucite 4.17 0.87 -3.30 -0.330 0.56338E+04 105 lizardite 23.29 19.14 -4.14 -0.345 0.70747E+04 107 magnetite 20.13 18.95 -1.18 -0.096 0.20181E+04 108 minnesotaite 10.46 5.86 -4.60 -0.271 0.78557E+04 113 margarite 17.45 14.20 -3.25 -0.130 0.55440E+04 122 nepheline 8.38 5.83 -2.55 -0.365 0.43585E+04 134 phlogopite-Na 29.73 24.97 -4.76 -0.265 0.81307E+04 136 prehnite 19.47 16.38 -3.09 -0.182 0.52753E+04 137 prehnite-Fe 22.59 20.12 -2.47 -0.148 0.42118E+04 138 pumpellyite-Fe 46.47 41.66 -4.81 -0.107 0.82099E+04 145 pyroxmangite 7.42 5.18 -2.24 -0.447 0.38193E+04 146 pyrophyllite -6.10 -8.09 -1.99 -0.124 0.33992E+04 147 quartz -2.98 -3.30 -0.32 -0.106 0.54290E+03 151 rhodochrosite -0.96 -5.76 -4.80 -1.601 0.82031E+04 152 rhodonite 7.46 5.18 -2.28 -0.457 0.38986E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.81 -3.51 -0.351 0.59938E+04 164 stilpnomelane-Fe 13.18 12.93 -0.25 -0.007 0.41901E+03 165 stilpnomelane-Mg 27.60 24.07 -3.52 -0.105 0.60138E+04 168 sudoite 21.22 17.48 -3.73 -0.120 0.63713E+04 171 talc 16.55 12.54 -4.01 -0.236 0.68457E+04 174 tephroite 18.11 13.66 -4.45 -0.636 0.76060E+04 177 topaz-H 4.67 1.81 -2.86 -0.260 0.48774E+04 178 tridymite -2.61 -3.30 -0.69 -0.228 0.11702E+04 187 wairakite 4.06 2.49 -1.56 -0.092 0.26713E+04 188 walstromite 11.53 7.28 -4.24 -0.849 0.72482E+04 189 wollastonite 10.48 7.28 -3.20 -0.640 0.54621E+04 190 pseudo-wollastonite 11.02 7.28 -3.74 -0.747 0.63807E+04 191 zoisite 22.96 18.93 -4.03 -0.183 0.68834E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.41 -2.85 -0.176 0.48675E+04 194 beidellite-H -2.24 -6.16 -3.92 -0.250 0.66855E+04 195 beidellite-K -1.44 -4.54 -3.10 -0.190 0.52938E+04 196 beidellite-Mg -1.71 -4.74 -3.03 -0.188 0.51800E+04 197 beidellite-Na -1.26 -3.99 -2.73 -0.167 0.46638E+04 199 chalcedony -2.79 -3.30 -0.51 -0.169 0.86321E+03 201 montmorillonite-Ca -2.21 -4.35 -2.14 -0.132 0.36542E+04 202 montmorillonite-K -2.16 -4.48 -2.32 -0.142 0.39582E+04 203 montmorillonite-Mg -2.40 -4.68 -2.28 -0.141 0.38978E+04 204 montmorillonite-Na -1.96 -3.93 -1.97 -0.121 0.33664E+04 205 nontronite-Ca 3.28 3.08 -0.20 -0.013 0.34727E+03 206 nontronite-H 2.60 1.33 -1.27 -0.085 0.21610E+04 207 nontronite-K 3.40 2.95 -0.45 -0.029 0.77274E+03 208 nontronite-Mg 3.14 2.75 -0.39 -0.026 0.67143E+03 209 nontronite-Na 3.58 3.50 -0.08 -0.005 0.14447E+03 224 tobermorite 9.84 5.52 -4.32 -1.180 0.73822E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.35 -3.47 -0.868 0.59266E+04 240 silica-amorphous -2.08 -3.30 -1.22 -0.407 0.20834E+04 242 an20ab80 2.08 1.20 -0.88 -0.068 0.15024E+04 243 an25ab75 2.71 1.69 -1.02 -0.078 0.17356E+04 244 an30ab70 3.34 2.19 -1.16 -0.089 0.19770E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.7990000 g New total amount of reactant added: 1.8390000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4572E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.8390000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1528097E-02 Osmotic coef. = 0.9778 True ionic strength = .2409601E-02 Chg. balance for total moles = 0.4572E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.60256E-09 -9.2200 0.55627E-09 -9.2547 0.92318E+00 -0.0347 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12721E-03 -3.8955 0.92228E+00 -0.0351 4 SO4-- 0.25498E-04 -4.5935 0.19505E-04 -4.7099 0.76498E+00 -0.1164 5 HCO3- 0.10881E-04 -4.9633 0.10038E-04 -4.9984 0.92250E+00 -0.0350 6 HS- 0.33960E-13 -13.4690 0.31321E-13 -13.5042 0.92230E+00 -0.0351 7 Al+++ 0.11075E-24 -24.9556 0.61851E-25 -25.2087 0.55846E+00 -0.2530 8 H4SiO4 0.49533E-03 -3.3051 0.49533E-03 -3.3051 0.10000E+01 0.0000 9 Ca++ 0.16840E-07 -7.7737 0.12867E-07 -7.8905 0.76409E+00 -0.1169 10 Mg++ 0.15565E-09 -9.8079 0.11884E-09 -9.9250 0.76353E+00 -0.1172 11 Fe++ 0.92049E-12 -12.0360 0.70295E-12 -12.1531 0.76367E+00 -0.1171 12 K+ 0.51090E-04 -4.2917 0.47132E-04 -4.3267 0.92254E+00 -0.0350 13 Na+ 0.23222E-02 -2.6341 0.21417E-02 -2.6692 0.92226E+00 -0.0351 14 Mn++ 0.12299E-09 -9.9101 0.93932E-10 -10.0272 0.76377E+00 -0.1170 15 HPO4-- 0.85377E-05 -5.0687 0.65313E-05 -5.1850 0.76499E+00 -0.1163 16 HSiO3- 0.94199E-03 -3.0260 0.86878E-03 -3.0611 0.92228E+00 -0.0351 17 Ca(HSiO3)+ 0.27148E-09 -9.5663 0.25046E-09 -9.6013 0.92257E+00 -0.0350 18 Mg(HSiO3)+ 0.31206E-11 -11.5058 0.28789E-11 -11.5408 0.92257E+00 -0.0350 19 NaHSiO3,aq 0.29551E-04 -4.5294 0.29551E-04 -4.5294 0.10000E+01 0.0000 20 AlO+ 0.27970E-13 -13.5533 0.25804E-13 -13.5883 0.92257E+00 -0.0350 21 AlOH+2 0.94131E-19 -19.0263 0.71905E-19 -19.1432 0.76389E+00 -0.1170 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.40413E-04 -4.3935 0.37261E-04 -4.4287 0.92202E+00 -0.0353 24 CH4,aq 0.15824E-19 -19.8007 0.15817E-19 -19.8009 0.99953E+00 -0.0002 29 CO,aq 0.14233E-18 -18.8467 0.14233E-18 -18.8467 0.10000E+01 0.0000 30 CO2,aq 0.11263E-07 -7.9483 0.11258E-07 -7.9485 0.99953E+00 -0.0002 31 CO3-2 0.21818E-05 -5.6612 0.16684E-05 -5.7777 0.76471E+00 -0.1165 32 CaCO3,aq 0.26293E-09 -9.5802 0.26293E-09 -9.5802 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.35275E-11 -11.4525 0.32544E-11 -11.4875 0.92257E+00 -0.0350 34 CaCl+ 0.28272E-11 -11.5486 0.26083E-11 -11.5836 0.92257E+00 -0.0350 35 CaCl2,aq 0.77257E-16 -16.1121 0.77257E-16 -16.1121 0.10000E+01 0.0000 36 CaOH+ 0.17679E-08 -8.7525 0.16310E-08 -8.7875 0.92257E+00 -0.0350 37 CaSO4,aq 0.78197E-10 -10.1068 0.78197E-10 -10.1068 0.10000E+01 0.0000 38 HCl,aq 0.13311E-13 -13.8758 0.13311E-13 -13.8758 0.10000E+01 0.0000 43 FeCl+ 0.15097E-15 -15.8211 0.13928E-15 -15.8561 0.92257E+00 -0.0350 46 FeO,aq 0.89833E-10 -10.0466 0.89833E-10 -10.0466 0.10000E+01 0.0000 47 FeOH+ 0.45410E-10 -10.3428 0.41894E-10 -10.3778 0.92257E+00 -0.0350 48 HFeO2- 0.18834E-08 -8.7251 0.17370E-08 -8.7602 0.92228E+00 -0.0351 49 FeO+ 0.49878E-14 -14.3021 0.46015E-14 -14.3371 0.92257E+00 -0.0350 51 FeO2- 0.31690E-08 -8.4991 0.29227E-08 -8.5342 0.92228E+00 -0.0351 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.49110E-09 -9.3088 0.49087E-09 -9.3090 0.99953E+00 -0.0002 54 KCl,aq 0.10617E-09 -9.9740 0.10617E-09 -9.9740 0.10000E+01 0.0000 55 KHSO4,aq 0.13685E-17 -17.8638 0.13685E-17 -17.8638 0.10000E+01 0.0000 56 KOH,aq 0.36937E-07 -7.4325 0.36937E-07 -7.4325 0.10000E+01 0.0000 57 KSO4- 0.15357E-07 -7.8137 0.14163E-07 -7.8488 0.92228E+00 -0.0351 58 MgCO3,aq 0.60682E-12 -12.2169 0.60682E-12 -12.2169 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.33224E-13 -13.4785 0.30651E-13 -13.5136 0.92257E+00 -0.0350 60 MgCl+ 0.23706E-13 -13.6251 0.21870E-13 -13.6601 0.92257E+00 -0.0350 61 MgOH+ 0.90463E-10 -10.0435 0.83458E-10 -10.0785 0.92257E+00 -0.0350 63 MnO,aq 0.32045E-09 -9.4942 0.32045E-09 -9.4942 0.10000E+01 0.0000 64 MnOH+ 0.56370E-09 -9.2490 0.52005E-09 -9.2840 0.92257E+00 -0.0350 65 MnO2-2 0.46833E-13 -13.3294 0.35814E-13 -13.4459 0.76471E+00 -0.1165 66 HMnO2- 0.46802E-11 -11.3297 0.43164E-11 -11.3649 0.92228E+00 -0.0351 69 MnCl+ 0.78390E-13 -13.1057 0.72320E-13 -13.1407 0.92257E+00 -0.0350 70 MnSO4,aq 0.51924E-12 -12.2846 0.51924E-12 -12.2846 0.10000E+01 0.0000 71 NaCl,aq 0.88961E-07 -7.0508 0.88961E-07 -7.0508 0.10000E+01 0.0000 72 NaOH,aq 0.16917E-05 -5.7717 0.16917E-05 -5.7717 0.10000E+01 0.0000 74 OH- 0.11695E-02 -2.9320 0.10783E-02 -2.9673 0.92202E+00 -0.0353 79 HPO3-2 0.13242E-16 -16.8781 0.10126E-16 -16.9946 0.76471E+00 -0.1165 81 H2PO3- 0.11997E-19 -19.9209 0.11065E-19 -19.9561 0.92228E+00 -0.0351 82 H3PO4,aq 0.13011E-13 -13.8857 0.13011E-13 -13.8857 0.10000E+01 0.0000 83 H2PO4- 0.69054E-07 -7.1608 0.63696E-07 -7.1959 0.92242E+00 -0.0351 84 PO4-3 0.18217E-07 -7.7395 0.10254E-07 -7.9891 0.56287E+00 -0.2496 87 H2P2O7-2 0.41524E-15 -15.3817 0.31754E-15 -15.4982 0.76471E+00 -0.1165 88 HP2O7-3 0.20958E-12 -12.6787 0.11705E-12 -12.9316 0.55851E+00 -0.2530 89 P2O7-4 0.14359E-12 -12.8429 0.51911E-13 -13.2847 0.36151E+00 -0.4419 90 H2S,aq 0.52373E-16 -16.2809 0.52348E-16 -16.2811 0.99953E+00 -0.0002 97 SO3-2 0.17032E-14 -14.7687 0.13055E-14 -14.8842 0.76649E+00 -0.1155 98 HSO3- 0.46079E-16 -16.3365 0.42498E-16 -16.3716 0.92228E+00 -0.0351 99 HSO4- 0.10911E-10 -10.9621 0.10067E-10 -10.9971 0.92270E+00 -0.0349 Charge balance for all species = 0.4568E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6025618E-09 -.2306604E-02 -.2324436E+01 0.0000 2 H2O 0.1000000E+01 0.5550853E+02 0.9997952E+06 0.0000 3 Cl- 0.1379324E-03 0.1380214E-03 0.4892258E+01 5.3592 4 SO4-- 0.2549776E-04 0.2551350E-04 0.2450359E+01 13.7996 5 HCO3- 0.1088118E-04 0.1307448E-04 0.7976022E+00 4.2564 6 HS- 0.3395960E-13 -.2987488E-09 -.9878168E-05 -4.2494 7 Al+++ 0.1107540E-24 0.4042196E-04 0.1090419E+01 2.5555 8 H4SiO4 0.4953277E-03 0.1466866E-02 0.1409591E+03 -3.3051 9 Ca++ 0.1683958E-07 0.1922645E-07 0.7703979E-03 10.6189 10 Mg++ 0.1556484E-09 0.2498959E-09 0.6074208E-05 8.5844 11 Fe++ 0.9204898E-12 0.5392003E-08 0.3010647E-03 6.3564 12 K+ 0.5108996E-04 0.5114236E-04 0.1999354E+01 4.9280 13 Na+ 0.2322185E-02 0.2353517E-02 0.5409565E+02 6.5855 14 Mn++ 0.1229851E-09 0.1012455E-08 0.5561073E-04 8.4822 15 HPO4-- 0.8537678E-05 0.8624949E-05 0.8276421E+00 13.3244 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3043807E-01 -.2305815E-02 -.2813226E-01 0.0000000E+00 2 H2O 0.5548520E+02 0.5548953E+02 -.4332396E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7646943E-04 0.2550477E-04 0.5096466E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5096496E-04 -.2986465E-09 -.5096466E-04 0.0000000E+00 7 Al+++ 0.5996504E-02 0.4040812E-04 0.5956096E-02 0.0000000E+00 8 H4SiO4 0.1914911E-01 0.1466363E-02 0.1768274E-01 0.0000000E+00 9 Ca++ 0.2129583E-02 0.1921987E-07 0.2129564E-02 0.0000000E+00 10 Mg++ 0.1459524E-02 0.2498104E-09 0.1459524E-02 0.0000000E+00 11 Fe++ 0.1311223E-02 0.5390157E-08 0.1311217E-02 0.0000000E+00 12 K+ 0.3904459E-03 0.5112486E-04 0.3393210E-03 0.0000000E+00 13 Na+ 0.2468464E-02 0.2352711E-02 0.1157529E-03 0.0000000E+00 14 Mn++ 0.3188568E-04 0.1012109E-08 0.3188467E-04 0.0000000E+00 15 HPO4-- 0.1088242E-04 0.8621997E-05 0.2260426E-05 0.0000000E+00 Chg. balance for solid moles: 0.1753E-17 Mass of aqueous solution: 0.999865E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.8390000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7535E-06 -6.123 0.3785E-03 -3.422 0.1922E-01 0.1203E-03 clinochlore 0.2919E-03 -3.535 0.1622 -0.790 8.240 0.6172E-01 daphnite 0.1807E-03 -3.743 0.1289 -0.890 6.548 0.3907E-01 chlorite-Mn 0.6377E-05 -5.195 0.4521E-02 -2.345 0.2296 0.1441E-02 hematite 0.2039E-03 -3.691 0.3256E-01 -1.487 1.653 0.6171E-02 microcline 0.3093E-03 -3.510 0.8610E-01 -1.065 4.373 0.3363E-01 muscovite 0.2998E-04 -4.523 0.1194E-01 -1.923 0.6065 0.4222E-02 paragonite 0.1158E-03 -3.936 0.4424E-01 -1.354 2.247 0.1529E-01 stilbite 0.2126E-02 -2.672 1.498 0.176 76.08 0.6987 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.969012 g Volume = 0.860402 cm3 Porosity: 50.4262% V(tot) - V(min): 0.87520E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.8390000 g log = 0.2646 Original solution: 1000.0103000 g Original solution / Rock added: 543.78 (Water/Rock Ratio), log = 2.7354 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1216E-05 1.0073 0.1289E-05 0.1279E-05 CH4,gas 0.2347E-16 1.0129 0.2501E-16 0.2469E-16 H2,gas 0.6397E-06 1.0006 0.6733E-06 0.6729E-06 H2S,gas 0.1457E-14 0.9959 0.1527E-14 0.1533E-14 S2,gas 0.1831E-36 1.0000 0.1926E-36 0.1926E-36 CO,gas 0.2136E-15 1.0000 0.2247E-15 0.2247E-15 SO3,gas 0.2145E-38 1.0000 0.2256E-38 0.2256E-38 SO2,gas 0.5463E-22 1.0000 0.5747E-22 0.5747E-22 HCl,gas 0.2234E-16 1.0000 0.2350E-16 0.2350E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 121 paragonite 4.34 4.34 0.00 0.000 0.19715E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.25 -7.89 -2.630 0.13472E+05 -5.890 3 CH4,gas 4.81 -13.79 -18.60 -4.650 0.31762E+05 -16.602 4 H2,gas 8.29 0.12 -8.17 -4.670 0.13953E+05 -6.172 5 H2S,gas -5.94 -22.76 -16.82 -8.408 0.28713E+05 -14.816 6 S2,gas -7.03 -45.75 -38.72 -5.956 0.66105E+05 -36.715 7 CO,gas 3.51 -14.14 -17.65 -5.430 0.30134E+05 -15.648 8 SO3,gas 17.43 -23.22 -40.65 -10.162 0.69403E+05 -38.647 9 SO2,gas 1.14 -23.10 -24.24 -6.464 0.41390E+05 -22.241 10 HCl,gas 5.48 -13.15 -18.63 -9.314 0.31808E+05 -16.629 11 acmite 7.74 6.27 -1.46 -0.152 0.24986E+04 15 albite-high 0.75 -0.77 -1.52 -0.117 0.26022E+04 16 albite -0.33 -0.77 -0.45 -0.034 0.76153E+03 19 spessartine 24.55 20.64 -3.91 -0.195 0.66720E+04 20 analcite 3.37 2.53 -0.84 -0.093 0.14341E+04 21 andalusite 5.06 1.81 -3.26 -0.326 0.55604E+04 22 andradite 39.09 34.54 -4.55 -0.236 0.77668E+04 26 annite 20.21 16.64 -3.57 -0.198 0.60992E+04 27 phlogopite 27.15 23.32 -3.83 -0.213 0.65314E+04 29 anorthite 12.80 9.12 -3.68 -0.283 0.62801E+04 35 aragonite 0.99 -3.63 -4.62 -1.540 0.78892E+04 36 brucite 12.58 8.58 -3.99 -0.798 0.68166E+04 37 calcite 0.83 -3.63 -4.47 -1.489 0.76279E+04 38 carnegieite-low 9.06 5.84 -3.23 -0.461 0.55129E+04 39 carnegieite-high 10.13 5.84 -4.30 -0.614 0.73398E+04 40 carpholite-Mg 8.65 7.09 -1.57 -0.104 0.26725E+04 41 carpholite-Fe 6.78 4.86 -1.93 -0.128 0.32882E+04 42 celadonite 5.40 2.85 -2.55 -0.150 0.43592E+04 43 celadonite-Fe 3.94 0.62 -3.32 -0.195 0.56645E+04 44 chrysotile 23.94 19.14 -4.79 -0.400 0.81862E+04 50 chloritoid-Mg 13.26 10.39 -2.87 -0.191 0.49021E+04 51 chloritoid-Fe 9.24 8.16 -1.08 -0.072 0.18380E+04 52 chloritoid-Mn 11.46 10.29 -1.18 -0.078 0.20064E+04 54 coesite -2.37 -3.31 -0.94 -0.312 0.15978E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.31 -0.76 -0.252 0.12907E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.59 -3.62 -0.362 0.61851E+04 68 hedenbergite 14.24 10.37 -3.88 -0.388 0.66239E+04 75 epidote 24.78 22.73 -2.04 -0.099 0.34882E+04 76 clinozoisite 22.92 18.99 -3.93 -0.179 0.67141E+04 77 epidote-Fe 29.94 26.48 -3.46 -0.180 0.59099E+04 78 fayalite 14.08 9.41 -4.67 -0.667 0.79762E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.74 -0.311 0.63780E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.53 -1.72 -0.172 0.29371E+04 97 kalsilite 7.62 4.18 -3.44 -0.492 0.58768E+04 98 kaolinite -1.27 -1.50 -0.23 -0.021 0.38603E+03 99 kyanite 4.93 1.81 -3.13 -0.313 0.53371E+04 101 laumontite 2.97 2.51 -0.47 -0.031 0.79411E+03 102 lawsonite 9.68 9.12 -0.56 -0.037 0.95395E+03 103 leucite 4.17 0.87 -3.29 -0.329 0.56250E+04 105 lizardite 23.29 19.14 -4.14 -0.345 0.70765E+04 107 magnetite 20.13 18.95 -1.18 -0.096 0.20128E+04 108 minnesotaite 10.46 5.85 -4.61 -0.271 0.78750E+04 113 margarite 17.45 14.23 -3.22 -0.129 0.55000E+04 122 nepheline 8.38 5.84 -2.54 -0.363 0.43409E+04 134 phlogopite-Na 29.73 24.98 -4.75 -0.264 0.81148E+04 136 prehnite 19.47 16.43 -3.03 -0.178 0.51785E+04 137 prehnite-Fe 22.59 20.18 -2.41 -0.145 0.41150E+04 138 pumpellyite-Fe 46.47 41.78 -4.69 -0.104 0.80110E+04 145 pyroxmangite 7.42 5.18 -2.24 -0.448 0.38229E+04 146 pyrophyllite -6.10 -8.11 -2.01 -0.126 0.34344E+04 147 quartz -2.98 -3.31 -0.32 -0.108 0.55170E+03 151 rhodochrosite -0.96 -5.77 -4.81 -1.604 0.82169E+04 152 rhodonite 7.46 5.18 -2.29 -0.457 0.39021E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.81 -3.52 -0.352 0.60026E+04 164 stilpnomelane-Fe 13.18 12.92 -0.26 -0.008 0.44982E+03 165 stilpnomelane-Mg 27.60 24.06 -3.54 -0.106 0.60446E+04 168 sudoite 21.22 17.48 -3.74 -0.121 0.63872E+04 171 talc 16.55 12.53 -4.02 -0.237 0.68651E+04 174 tephroite 18.11 13.66 -4.45 -0.636 0.76043E+04 177 topaz-H 4.67 1.81 -2.86 -0.260 0.48862E+04 178 tridymite -2.61 -3.31 -0.69 -0.230 0.11790E+04 187 wairakite 4.06 2.51 -1.55 -0.091 0.26449E+04 188 walstromite 11.53 7.31 -4.21 -0.843 0.71954E+04 189 wollastonite 10.48 7.31 -3.17 -0.634 0.54093E+04 190 pseudo-wollastonite 11.02 7.31 -3.71 -0.741 0.63279E+04 191 zoisite 22.96 18.99 -3.97 -0.181 0.67866E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.42 -2.86 -0.177 0.48896E+04 194 beidellite-H -2.24 -6.18 -3.93 -0.251 0.67178E+04 195 beidellite-K -1.44 -4.55 -3.11 -0.191 0.53174E+04 196 beidellite-Mg -1.71 -4.76 -3.05 -0.189 0.52114E+04 197 beidellite-Na -1.26 -4.00 -2.75 -0.168 0.46874E+04 199 chalcedony -2.79 -3.31 -0.51 -0.170 0.87201E+03 201 montmorillonite-Ca -2.21 -4.37 -2.15 -0.133 0.36775E+04 202 montmorillonite-K -2.16 -4.49 -2.33 -0.143 0.39830E+04 203 montmorillonite-Mg -2.40 -4.70 -2.30 -0.142 0.39303E+04 204 montmorillonite-Na -1.96 -3.95 -1.99 -0.122 0.33912E+04 205 nontronite-Ca 3.28 3.06 -0.22 -0.014 0.36941E+03 206 nontronite-H 2.60 1.31 -1.28 -0.086 0.21933E+04 207 nontronite-K 3.40 2.94 -0.47 -0.030 0.79633E+03 208 nontronite-Mg 3.14 2.73 -0.41 -0.027 0.70286E+03 209 nontronite-Na 3.58 3.48 -0.10 -0.006 0.16806E+03 224 tobermorite 9.84 5.54 -4.30 -1.173 0.73397E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.36 -3.47 -0.867 0.59213E+04 240 silica-amorphous -2.08 -3.31 -1.23 -0.408 0.20922E+04 242 an20ab80 2.08 1.20 -0.87 -0.067 0.14936E+04 243 an25ab75 2.71 1.70 -1.01 -0.078 0.17246E+04 244 an30ab70 3.34 2.19 -1.15 -0.088 0.19638E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.8390000 g New total amount of reactant added: 1.8790000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4573E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.8790000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5548E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1548146E-02 Osmotic coef. = 0.9776 True ionic strength = .2443305E-02 Chg. balance for total moles = 0.4573E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.59012E-09 -9.2291 0.54457E-09 -9.2639 0.92281E+00 -0.0349 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12716E-03 -3.8956 0.92190E+00 -0.0353 4 SO4-- 0.25498E-04 -4.5935 0.19474E-04 -4.7106 0.76374E+00 -0.1171 5 HCO3- 0.10840E-04 -4.9650 0.99961E-05 -5.0002 0.92212E+00 -0.0352 6 HS- 0.35132E-13 -13.4543 0.32389E-13 -13.4896 0.92193E+00 -0.0353 7 Al+++ 0.10429E-24 -24.9818 0.58029E-25 -25.2364 0.55641E+00 -0.2546 8 H4SiO4 0.48954E-03 -3.3102 0.48954E-03 -3.3102 0.10000E+01 0.0000 9 Ca++ 0.17551E-07 -7.7557 0.13388E-07 -7.8733 0.76284E+00 -0.1176 10 Mg++ 0.15047E-09 -9.8225 0.11470E-09 -9.9404 0.76228E+00 -0.1179 11 Fe++ 0.88986E-12 -12.0507 0.67845E-12 -12.1685 0.76242E+00 -0.1178 12 K+ 0.51831E-04 -4.2854 0.47796E-04 -4.3206 0.92216E+00 -0.0352 13 Na+ 0.23559E-02 -2.6278 0.21718E-02 -2.6632 0.92188E+00 -0.0353 14 Mn++ 0.11889E-09 -9.9248 0.90658E-10 -10.0426 0.76252E+00 -0.1178 15 HPO4-- 0.77799E-05 -5.1090 0.59419E-05 -5.2261 0.76376E+00 -0.1170 16 HSiO3- 0.95138E-03 -3.0216 0.87708E-03 -3.0570 0.92190E+00 -0.0353 17 Ca(HSiO3)+ 0.28530E-09 -9.5447 0.26310E-09 -9.5799 0.92219E+00 -0.0352 18 Mg(HSiO3)+ 0.30418E-11 -11.5169 0.28051E-11 -11.5520 0.92219E+00 -0.0352 19 NaHSiO3,aq 0.30254E-04 -4.5192 0.30254E-04 -4.5192 0.10000E+01 0.0000 20 AlO+ 0.27393E-13 -13.5624 0.25261E-13 -13.5975 0.92219E+00 -0.0352 21 AlOH+2 0.90360E-19 -19.0440 0.68912E-19 -19.1617 0.76264E+00 -0.1177 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.41298E-04 -4.3841 0.38062E-04 -4.4195 0.92163E+00 -0.0354 24 CH4,aq 0.16322E-19 -19.7872 0.16314E-19 -19.7874 0.99952E+00 -0.0002 29 CO,aq 0.14072E-18 -18.8516 0.14072E-18 -18.8516 0.10000E+01 0.0000 30 CO2,aq 0.10981E-07 -7.9594 0.10975E-07 -7.9596 0.99952E+00 -0.0002 31 CO3-2 0.22230E-05 -5.6531 0.16972E-05 -5.7703 0.76348E+00 -0.1172 32 CaCO3,aq 0.27830E-09 -9.5555 0.27830E-09 -9.5555 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.36567E-11 -11.4369 0.33722E-11 -11.4721 0.92219E+00 -0.0352 34 CaCl+ 0.29418E-11 -11.5314 0.27129E-11 -11.5666 0.92219E+00 -0.0352 35 CaCl2,aq 0.80322E-16 -16.0952 0.80322E-16 -16.0952 0.10000E+01 0.0000 36 CaOH+ 0.18799E-08 -8.7259 0.17336E-08 -8.7611 0.92219E+00 -0.0352 37 CaSO4,aq 0.81235E-10 -10.0903 0.81235E-10 -10.0903 0.10000E+01 0.0000 38 HCl,aq 0.13025E-13 -13.8852 0.13025E-13 -13.8852 0.10000E+01 0.0000 43 FeCl+ 0.14571E-15 -15.8365 0.13437E-15 -15.8717 0.92219E+00 -0.0352 46 FeO,aq 0.90468E-10 -10.0435 0.90468E-10 -10.0435 0.10000E+01 0.0000 47 FeOH+ 0.44788E-10 -10.3488 0.41303E-10 -10.3840 0.92219E+00 -0.0352 48 HFeO2- 0.19383E-08 -8.7126 0.17869E-08 -8.7479 0.92190E+00 -0.0353 49 FeO+ 0.48848E-14 -14.3112 0.45047E-14 -14.3463 0.92219E+00 -0.0352 51 FeO2- 0.32384E-08 -8.4897 0.29855E-08 -8.5250 0.92190E+00 -0.0353 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.49808E-09 -9.3027 0.49784E-09 -9.3029 0.99952E+00 -0.0002 54 KCl,aq 0.10762E-09 -9.9681 0.10762E-09 -9.9681 0.10000E+01 0.0000 55 KHSO4,aq 0.13564E-17 -17.8676 0.13564E-17 -17.8676 0.10000E+01 0.0000 56 KOH,aq 0.38263E-07 -7.4172 0.38263E-07 -7.4172 0.10000E+01 0.0000 57 KSO4- 0.15554E-07 -7.8081 0.14340E-07 -7.8435 0.92190E+00 -0.0353 58 MgCO3,aq 0.59577E-12 -12.2249 0.59577E-12 -12.2249 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.31945E-13 -13.4956 0.29460E-13 -13.5308 0.92219E+00 -0.0352 60 MgCl+ 0.22879E-13 -13.6406 0.21099E-13 -13.6757 0.92219E+00 -0.0352 61 MgOH+ 0.89223E-10 -10.0495 0.82281E-10 -10.0847 0.92219E+00 -0.0352 63 MnO,aq 0.32272E-09 -9.4912 0.32272E-09 -9.4912 0.10000E+01 0.0000 64 MnOH+ 0.55597E-09 -9.2549 0.51271E-09 -9.2901 0.92219E+00 -0.0352 65 MnO2-2 0.49294E-13 -13.3072 0.37635E-13 -13.4244 0.76348E+00 -0.1172 66 HMnO2- 0.48165E-11 -11.3173 0.44404E-11 -11.3526 0.92190E+00 -0.0353 69 MnCl+ 0.75658E-13 -13.1211 0.69771E-13 -13.1563 0.92219E+00 -0.0352 70 MnSO4,aq 0.50033E-12 -12.3007 0.50033E-12 -12.3007 0.10000E+01 0.0000 71 NaCl,aq 0.90177E-07 -7.0449 0.90177E-07 -7.0449 0.10000E+01 0.0000 72 NaOH,aq 0.17524E-05 -5.7564 0.17524E-05 -5.7564 0.10000E+01 0.0000 74 OH- 0.11952E-02 -2.9226 0.11015E-02 -2.9580 0.92163E+00 -0.0354 79 HPO3-2 0.12238E-16 -16.9123 0.93434E-17 -17.0295 0.76348E+00 -0.1172 81 H2PO3- 0.10841E-19 -19.9649 0.99947E-20 -20.0002 0.92190E+00 -0.0353 82 H3PO4,aq 0.11344E-13 -13.9452 0.11344E-13 -13.9452 0.10000E+01 0.0000 83 H2PO4- 0.61526E-07 -7.2109 0.56730E-07 -7.2462 0.92204E+00 -0.0352 84 PO4-3 0.16990E-07 -7.7698 0.95290E-08 -8.0210 0.56087E+00 -0.2511 87 H2P2O7-2 0.32991E-15 -15.4816 0.25188E-15 -15.5988 0.76348E+00 -0.1172 88 HP2O7-3 0.17044E-12 -12.7684 0.94843E-13 -13.0230 0.55647E+00 -0.2546 89 P2O7-4 0.11962E-12 -12.9222 0.42966E-13 -13.3669 0.35918E+00 -0.4447 90 H2S,aq 0.53020E-16 -16.2756 0.52994E-16 -16.2758 0.99952E+00 -0.0002 97 SO3-2 0.17273E-14 -14.7626 0.13219E-14 -14.8788 0.76527E+00 -0.1162 98 HSO3- 0.45695E-16 -16.3401 0.42127E-16 -16.3754 0.92190E+00 -0.0353 99 HSO4- 0.10668E-10 -10.9719 0.98397E-11 -11.0070 0.92233E+00 -0.0351 Charge balance for all species = 0.4571E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5901197E-09 -.2345983E-02 -.2364116E+01 0.0000 2 H2O 0.1000000E+01 0.5550855E+02 0.9997941E+06 0.0000 3 Cl- 0.1379320E-03 0.1380223E-03 0.4892282E+01 5.3683 4 SO4-- 0.2549772E-04 0.2551367E-04 0.2450372E+01 13.8173 5 HCO3- 0.1084032E-04 0.1307456E-04 0.7976062E+00 4.2638 6 HS- 0.3513169E-13 -.3056826E-09 -.1010742E-04 -4.2257 7 Al+++ 0.1042913E-24 0.4130758E-04 0.1114307E+01 2.5555 8 H4SiO4 0.4895413E-03 0.1471176E-02 0.1413731E+03 -3.3102 9 Ca++ 0.1755068E-07 0.2008197E-07 0.8046771E-03 10.6546 10 Mg++ 0.1504702E-09 0.2433855E-09 0.5915950E-05 8.5875 11 Fe++ 0.8898643E-12 0.5516303E-08 0.3080045E-03 6.3594 12 K+ 0.5183078E-04 0.5188471E-04 0.2028372E+01 4.9433 13 Na+ 0.2355866E-02 0.2387963E-02 0.5488731E+02 6.6008 14 Mn++ 0.1188932E-09 0.1003020E-08 0.5509239E-04 8.4853 15 HPO4-- 0.7779877E-05 0.7858394E-05 0.7540831E+00 13.3018 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3110041E-01 -.2345165E-02 -.2875525E-01 0.0000000E+00 2 H2O 0.5548470E+02 0.5548919E+02 -.4494849E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7757797E-04 0.2550478E-04 0.5207319E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5207350E-04 -.3055760E-09 -.5207319E-04 0.0000000E+00 7 Al+++ 0.6126933E-02 0.4129317E-04 0.6085640E-02 0.0000000E+00 8 H4SiO4 0.1956562E-01 0.1470663E-02 0.1809496E-01 0.0000000E+00 9 Ca++ 0.2175589E-02 0.2007497E-07 0.2175569E-02 0.0000000E+00 10 Mg++ 0.1491270E-02 0.2433006E-09 0.1491270E-02 0.0000000E+00 11 Fe++ 0.1339743E-02 0.5514379E-08 0.1339738E-02 0.0000000E+00 12 K+ 0.3989384E-03 0.5186661E-04 0.3470718E-03 0.0000000E+00 13 Na+ 0.2518674E-02 0.2387130E-02 0.1315438E-03 0.0000000E+00 14 Mn++ 0.3257922E-04 0.1002670E-08 0.3257822E-04 0.0000000E+00 15 HPO4-- 0.1111913E-04 0.7855653E-05 0.3263473E-05 0.0000000E+00 Chg. balance for solid moles: -.1094E-17 Mass of aqueous solution: 0.999860E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.8790000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1088E-05 -5.963 0.5464E-03 -3.262 0.2714E-01 0.1736E-03 clinochlore 0.2983E-03 -3.525 0.1658 -0.780 8.233 0.6306E-01 daphnite 0.1846E-03 -3.734 0.1317 -0.880 6.542 0.3992E-01 chlorite-Mn 0.6516E-05 -5.186 0.4619E-02 -2.335 0.2294 0.1472E-02 hematite 0.2083E-03 -3.681 0.3326E-01 -1.478 1.652 0.6305E-02 microcline 0.3346E-03 -3.475 0.9314E-01 -1.031 4.626 0.3638E-01 muscovite 0.1244E-04 -4.905 0.4954E-02 -2.305 0.2460 0.1752E-02 paragonite 0.1315E-03 -3.881 0.5028E-01 -1.299 2.497 0.1738E-01 stilbite 0.2170E-02 -2.664 1.529 0.185 75.95 0.7133 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.013651 g Volume = 0.879751 cm3 Porosity: 49.7744% V(tot) - V(min): 0.87185E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.8790000 g log = 0.2739 Original solution: 1000.0103000 g Original solution / Rock added: 532.20 (Water/Rock Ratio), log = 2.7261 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1186E-05 1.0073 0.1256E-05 0.1247E-05 CH4,gas 0.2421E-16 1.0129 0.2580E-16 0.2547E-16 H2,gas 0.6488E-06 1.0006 0.6828E-06 0.6824E-06 H2S,gas 0.1475E-14 0.9959 0.1546E-14 0.1552E-14 S2,gas 0.1824E-36 1.0000 0.1919E-36 0.1919E-36 CO,gas 0.2112E-15 1.0000 0.2222E-15 0.2222E-15 SO3,gas 0.2052E-38 1.0000 0.2159E-38 0.2159E-38 SO2,gas 0.5302E-22 1.0000 0.5577E-22 0.5577E-22 HCl,gas 0.2186E-16 1.0000 0.2300E-16 0.2300E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 121 paragonite 4.34 4.34 0.00 0.000 0.19715E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.26 -7.90 -2.634 0.13491E+05 -5.901 3 CH4,gas 4.81 -13.78 -18.59 -4.647 0.31739E+05 -16.588 4 H2,gas 8.29 0.12 -8.17 -4.666 0.13943E+05 -6.166 5 H2S,gas -5.94 -22.75 -16.81 -8.405 0.28704E+05 -14.811 6 S2,gas -7.03 -45.75 -38.72 -5.956 0.66108E+05 -36.717 7 CO,gas 3.51 -14.14 -17.65 -5.432 0.30142E+05 -15.653 8 SO3,gas 17.43 -23.24 -40.67 -10.166 0.69436E+05 -38.666 9 SO2,gas 1.14 -23.12 -24.25 -6.468 0.41412E+05 -22.254 10 HCl,gas 5.48 -13.16 -18.64 -9.319 0.31824E+05 -16.638 11 acmite 7.74 6.28 -1.46 -0.152 0.24899E+04 15 albite-high 0.75 -0.77 -1.52 -0.117 0.26022E+04 16 albite -0.33 -0.77 -0.45 -0.034 0.76153E+03 19 spessartine 24.55 20.64 -3.91 -0.196 0.66824E+04 20 analcite 3.37 2.54 -0.83 -0.093 0.14254E+04 21 andalusite 5.06 1.80 -3.26 -0.326 0.55691E+04 22 andradite 39.09 34.63 -4.46 -0.232 0.76100E+04 26 annite 20.21 16.65 -3.56 -0.198 0.60835E+04 27 phlogopite 27.15 23.33 -3.82 -0.212 0.65157E+04 29 anorthite 12.80 9.15 -3.65 -0.281 0.62365E+04 35 aragonite 0.99 -3.61 -4.60 -1.532 0.78471E+04 36 brucite 12.58 8.59 -3.99 -0.798 0.68113E+04 37 calcite 0.83 -3.61 -4.44 -1.481 0.75857E+04 38 carnegieite-low 9.06 5.85 -3.22 -0.460 0.54955E+04 39 carnegieite-high 10.13 5.85 -4.29 -0.613 0.73223E+04 40 carpholite-Mg 8.65 7.08 -1.57 -0.105 0.26847E+04 41 carpholite-Fe 6.78 4.85 -1.93 -0.129 0.33004E+04 42 celadonite 5.40 2.85 -2.56 -0.150 0.43627E+04 43 celadonite-Fe 3.94 0.62 -3.32 -0.195 0.56680E+04 44 chrysotile 23.94 19.14 -4.80 -0.400 0.81880E+04 50 chloritoid-Mg 13.26 10.39 -2.87 -0.192 0.49056E+04 51 chloritoid-Fe 9.24 8.16 -1.08 -0.072 0.18415E+04 52 chloritoid-Mn 11.46 10.29 -1.18 -0.078 0.20099E+04 54 coesite -2.37 -3.31 -0.94 -0.314 0.16065E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.31 -0.76 -0.254 0.12994E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.62 -3.59 -0.359 0.61363E+04 68 hedenbergite 14.24 10.39 -3.85 -0.385 0.65751E+04 75 epidote 24.78 22.79 -1.99 -0.096 0.33924E+04 76 clinozoisite 22.92 19.05 -3.88 -0.176 0.66182E+04 77 epidote-Fe 29.94 26.53 -3.41 -0.177 0.58140E+04 78 fayalite 14.08 9.41 -4.67 -0.667 0.79745E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.74 -0.311 0.63798E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.54 -1.72 -0.172 0.29284E+04 97 kalsilite 7.62 4.19 -3.43 -0.490 0.58594E+04 98 kaolinite -1.27 -1.51 -0.24 -0.021 0.40346E+03 99 kyanite 4.93 1.80 -3.13 -0.313 0.53459E+04 101 laumontite 2.97 2.52 -0.45 -0.030 0.76797E+03 102 lawsonite 9.68 9.15 -0.53 -0.036 0.91039E+03 103 leucite 4.17 0.88 -3.29 -0.329 0.56163E+04 105 lizardite 23.29 19.14 -4.15 -0.345 0.70782E+04 107 magnetite 20.13 18.96 -1.18 -0.096 0.20076E+04 108 minnesotaite 10.46 5.84 -4.62 -0.272 0.78942E+04 113 margarite 17.45 14.26 -3.20 -0.128 0.54564E+04 122 nepheline 8.38 5.85 -2.53 -0.362 0.43234E+04 134 phlogopite-Na 29.73 24.99 -4.74 -0.264 0.80991E+04 136 prehnite 19.47 16.49 -2.98 -0.175 0.50827E+04 137 prehnite-Fe 22.59 20.23 -2.35 -0.142 0.40191E+04 138 pumpellyite-Fe 46.47 41.89 -4.58 -0.102 0.78141E+04 145 pyroxmangite 7.42 5.18 -2.24 -0.448 0.38263E+04 146 pyrophyllite -6.10 -8.13 -2.03 -0.127 0.34693E+04 147 quartz -2.98 -3.31 -0.33 -0.109 0.56041E+03 151 rhodochrosite -0.96 -5.78 -4.82 -1.607 0.82305E+04 152 rhodonite 7.46 5.18 -2.29 -0.457 0.39056E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.80 -3.52 -0.352 0.60113E+04 164 stilpnomelane-Fe 13.18 12.90 -0.28 -0.008 0.48032E+03 165 stilpnomelane-Mg 27.60 24.04 -3.56 -0.106 0.60751E+04 168 sudoite 21.22 17.47 -3.75 -0.121 0.64029E+04 171 talc 16.55 12.52 -4.03 -0.237 0.68842E+04 174 tephroite 18.11 13.66 -4.45 -0.636 0.76025E+04 177 topaz-H 4.67 1.80 -2.87 -0.261 0.48949E+04 178 tridymite -2.61 -3.31 -0.70 -0.232 0.11877E+04 187 wairakite 4.06 2.52 -1.53 -0.090 0.26188E+04 188 walstromite 11.53 7.34 -4.18 -0.837 0.71431E+04 189 wollastonite 10.48 7.34 -3.14 -0.627 0.53570E+04 190 pseudo-wollastonite 11.02 7.34 -3.68 -0.735 0.62756E+04 191 zoisite 22.96 19.05 -3.92 -0.178 0.66908E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.44 -2.88 -0.178 0.49115E+04 194 beidellite-H -2.24 -6.19 -3.95 -0.252 0.67497E+04 195 beidellite-K -1.44 -4.56 -3.13 -0.192 0.53407E+04 196 beidellite-Mg -1.71 -4.78 -3.07 -0.190 0.52425E+04 197 beidellite-Na -1.26 -4.02 -2.76 -0.169 0.47107E+04 199 chalcedony -2.79 -3.31 -0.52 -0.172 0.88073E+03 201 montmorillonite-Ca -2.21 -4.38 -2.17 -0.134 0.37005E+04 202 montmorillonite-K -2.16 -4.51 -2.35 -0.144 0.40075E+04 203 montmorillonite-Mg -2.40 -4.72 -2.32 -0.144 0.39626E+04 204 montmorillonite-Na -1.96 -3.96 -2.00 -0.122 0.34157E+04 205 nontronite-Ca 3.28 3.05 -0.23 -0.015 0.39132E+03 206 nontronite-H 2.60 1.29 -1.30 -0.087 0.22253E+04 207 nontronite-K 3.40 2.92 -0.48 -0.031 0.81968E+03 208 nontronite-Mg 3.14 2.71 -0.43 -0.028 0.73397E+03 209 nontronite-Na 3.58 3.47 -0.11 -0.007 0.19141E+03 224 tobermorite 9.84 5.57 -4.27 -1.166 0.72976E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.36 -3.46 -0.866 0.59161E+04 240 silica-amorphous -2.08 -3.31 -1.23 -0.410 0.21009E+04 242 an20ab80 2.08 1.21 -0.87 -0.067 0.14849E+04 243 an25ab75 2.71 1.71 -1.00 -0.077 0.17137E+04 244 an30ab70 3.34 2.20 -1.14 -0.088 0.19508E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.8790000 g New total amount of reactant added: 1.9190000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4572E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.9190000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9996E+00 Moles total = 0.5548E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1568533E-02 Osmotic coef. = 0.9775 True ionic strength = .2477387E-02 Chg. balance for total moles = 0.4572E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.57810E-09 -9.2380 0.53326E-09 -9.2731 0.92244E+00 -0.0351 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12711E-03 -3.8958 0.92152E+00 -0.0355 4 SO4-- 0.25498E-04 -4.5935 0.19442E-04 -4.7113 0.76250E+00 -0.1178 5 HCO3- 0.10799E-04 -4.9666 0.99542E-05 -5.0020 0.92174E+00 -0.0354 6 HS- 0.36333E-13 -13.4397 0.33483E-13 -13.4752 0.92155E+00 -0.0355 7 Al+++ 0.98292E-25 -25.0075 0.54490E-25 -25.2637 0.55437E+00 -0.2562 8 H4SiO4 0.48388E-03 -3.3153 0.48388E-03 -3.3153 0.10000E+01 0.0000 9 Ca++ 0.18287E-07 -7.7379 0.13927E-07 -7.8561 0.76160E+00 -0.1183 10 Mg++ 0.14554E-09 -9.8370 0.11076E-09 -9.9556 0.76103E+00 -0.1186 11 Fe++ 0.86069E-12 -12.0652 0.65513E-12 -12.1837 0.76116E+00 -0.1185 12 K+ 0.52578E-04 -4.2792 0.48466E-04 -4.3146 0.92178E+00 -0.0354 13 Na+ 0.23898E-02 -2.6216 0.22023E-02 -2.6571 0.92150E+00 -0.0355 14 Mn++ 0.11500E-09 -9.9393 0.87542E-10 -10.0578 0.76127E+00 -0.1185 15 HPO4-- 0.70955E-05 -5.1490 0.54104E-05 -5.2668 0.76252E+00 -0.1177 16 HSiO3- 0.96071E-03 -3.0174 0.88532E-03 -3.0529 0.92152E+00 -0.0355 17 Ca(HSiO3)+ 0.29969E-09 -9.5233 0.27625E-09 -9.5587 0.92181E+00 -0.0354 18 Mg(HSiO3)+ 0.29661E-11 -11.5278 0.27342E-11 -11.5632 0.92181E+00 -0.0354 19 NaHSiO3,aq 0.30966E-04 -4.5091 0.30966E-04 -4.5091 0.10000E+01 0.0000 20 AlO+ 0.26835E-13 -13.5713 0.24737E-13 -13.6067 0.92181E+00 -0.0354 21 AlOH+2 0.86790E-19 -19.0615 0.66081E-19 -19.1799 0.76139E+00 -0.1184 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.42191E-04 -4.3748 0.38869E-04 -4.4104 0.92125E+00 -0.0356 24 CH4,aq 0.16830E-19 -19.7739 0.16822E-19 -19.7741 0.99951E+00 -0.0002 29 CO,aq 0.13916E-18 -18.8565 0.13916E-18 -18.8565 0.10000E+01 0.0000 30 CO2,aq 0.10708E-07 -7.9703 0.10702E-07 -7.9705 0.99951E+00 -0.0002 31 CO3-2 0.22643E-05 -5.6451 0.17259E-05 -5.7630 0.76223E+00 -0.1179 32 CaCO3,aq 0.29439E-09 -9.5311 0.29439E-09 -9.5311 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.37894E-11 -11.4214 0.34932E-11 -11.4568 0.92181E+00 -0.0354 34 CaCl+ 0.30601E-11 -11.5143 0.28209E-11 -11.5496 0.92181E+00 -0.0354 35 CaCl2,aq 0.83484E-16 -16.0784 0.83484E-16 -16.0784 0.10000E+01 0.0000 36 CaOH+ 0.19978E-08 -8.6995 0.18416E-08 -8.7348 0.92181E+00 -0.0354 37 CaSO4,aq 0.84366E-10 -10.0738 0.84366E-10 -10.0738 0.10000E+01 0.0000 38 HCl,aq 0.12750E-13 -13.8945 0.12750E-13 -13.8945 0.10000E+01 0.0000 43 FeCl+ 0.14070E-15 -15.8517 0.12970E-15 -15.8871 0.92181E+00 -0.0354 46 FeO,aq 0.91102E-10 -10.0405 0.91102E-10 -10.0405 0.10000E+01 0.0000 47 FeOH+ 0.44183E-10 -10.3547 0.40729E-10 -10.3901 0.92181E+00 -0.0354 48 HFeO2- 0.19940E-08 -8.7003 0.18375E-08 -8.7358 0.92152E+00 -0.0355 49 FeO+ 0.47854E-14 -14.3201 0.44112E-14 -14.3554 0.92181E+00 -0.0354 51 FeO2- 0.33084E-08 -8.4804 0.30488E-08 -8.5159 0.92152E+00 -0.0355 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.50508E-09 -9.2966 0.50483E-09 -9.2969 0.99951E+00 -0.0002 54 KCl,aq 0.10908E-09 -9.9623 0.10908E-09 -9.9623 0.10000E+01 0.0000 55 KHSO4,aq 0.13446E-17 -17.8714 0.13446E-17 -17.8714 0.10000E+01 0.0000 56 KOH,aq 0.39621E-07 -7.4021 0.39621E-07 -7.4021 0.10000E+01 0.0000 57 KSO4- 0.15753E-07 -7.8026 0.14517E-07 -7.8381 0.92152E+00 -0.0355 58 MgCO3,aq 0.58503E-12 -12.2328 0.58503E-12 -12.2328 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.30731E-13 -13.5124 0.28328E-13 -13.5478 0.92181E+00 -0.0354 60 MgCl+ 0.22093E-13 -13.6557 0.20366E-13 -13.6911 0.92181E+00 -0.0354 61 MgOH+ 0.88018E-10 -10.0554 0.81137E-10 -10.0908 0.92181E+00 -0.0354 63 MnO,aq 0.32498E-09 -9.4881 0.32498E-09 -9.4881 0.10000E+01 0.0000 64 MnOH+ 0.54846E-09 -9.2609 0.50558E-09 -9.2962 0.92181E+00 -0.0354 65 MnO2-2 0.51850E-13 -13.2853 0.39522E-13 -13.4032 0.76223E+00 -0.1179 66 HMnO2- 0.49551E-11 -11.3049 0.45663E-11 -11.3404 0.92152E+00 -0.0355 69 MnCl+ 0.73057E-13 -13.1363 0.67345E-13 -13.1717 0.92181E+00 -0.0354 70 MnSO4,aq 0.48235E-12 -12.3166 0.48235E-12 -12.3166 0.10000E+01 0.0000 71 NaCl,aq 0.91402E-07 -7.0390 0.91402E-07 -7.0390 0.10000E+01 0.0000 72 NaOH,aq 0.18146E-05 -5.7412 0.18146E-05 -5.7412 0.10000E+01 0.0000 74 OH- 0.12210E-02 -2.9133 0.11248E-02 -2.9489 0.92125E+00 -0.0356 79 HPO3-2 0.11318E-16 -16.9462 0.86272E-17 -17.0641 0.76223E+00 -0.1179 82 H3PO4,aq 0.99052E-14 -14.0041 0.99052E-14 -14.0041 0.10000E+01 0.0000 83 H2PO4- 0.54882E-07 -7.2606 0.50583E-07 -7.2960 0.92167E+00 -0.0354 84 PO4-3 0.15854E-07 -7.7998 0.88605E-08 -8.0525 0.55887E+00 -0.2527 87 H2P2O7-2 0.26272E-15 -15.5805 0.20025E-15 -15.6984 0.76223E+00 -0.1179 88 HP2O7-3 0.13889E-12 -12.8573 0.77003E-13 -13.1135 0.55442E+00 -0.2562 89 P2O7-4 0.99822E-13 -13.0008 0.35623E-13 -13.4483 0.35686E+00 -0.4475 90 H2S,aq 0.53673E-16 -16.2702 0.53647E-16 -16.2705 0.99951E+00 -0.0002 97 SO3-2 0.17515E-14 -14.7566 0.13383E-14 -14.8735 0.76405E+00 -0.1169 98 HSO3- 0.45320E-16 -16.3437 0.41764E-16 -16.3792 0.92152E+00 -0.0355 99 HSO4- 0.10434E-10 -10.9815 0.96198E-11 -11.0168 0.92196E+00 -0.0353 Charge balance for all species = 0.4572E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5781017E-09 -.2385549E-02 -.2403984E+01 0.0000 2 H2O 0.1000000E+01 0.5550857E+02 0.9997929E+06 0.0000 3 Cl- 0.1379317E-03 0.1380232E-03 0.4892306E+01 5.3772 4 SO4-- 0.2549768E-04 0.2551384E-04 0.2450385E+01 13.8349 5 HCO3- 0.1079936E-04 0.1307464E-04 0.7976102E+00 4.2711 6 HS- 0.3633308E-13 -.3126818E-09 -.1033884E-04 -4.2021 7 Al+++ 0.9829170E-25 0.4220050E-04 0.1138393E+01 2.5555 8 H4SiO4 0.4838822E-03 0.1475559E-02 0.1417941E+03 -3.3153 9 Ca++ 0.1828667E-07 0.2096972E-07 0.8402473E-03 10.6900 10 Mg++ 0.1455381E-09 0.2371605E-09 0.5764632E-05 8.5905 11 Fe++ 0.8606946E-12 0.5642072E-08 0.3150264E-03 6.3624 12 K+ 0.5257812E-04 0.5263361E-04 0.2057646E+01 4.9585 13 Na+ 0.2389844E-02 0.2422716E-02 0.5568603E+02 6.6159 14 Mn++ 0.1149958E-09 0.9939984E-09 0.5459679E-04 8.4883 15 HPO4-- 0.7095484E-05 0.7166222E-05 0.6876620E+00 13.2793 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3176275E-01 -.2384702E-02 -.2937805E-01 0.0000000E+00 2 H2O 0.5548419E+02 0.5548885E+02 -.4656329E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7868650E-04 0.2550478E-04 0.5318172E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5318203E-04 -.3125708E-09 -.5318172E-04 0.0000000E+00 7 Al+++ 0.6257363E-02 0.4218552E-04 0.6215178E-02 0.0000000E+00 8 H4SiO4 0.1998213E-01 0.1475035E-02 0.1850710E-01 0.0000000E+00 9 Ca++ 0.2221595E-02 0.2096227E-07 0.2221574E-02 0.0000000E+00 10 Mg++ 0.1523016E-02 0.2370763E-09 0.1523016E-02 0.0000000E+00 11 Fe++ 0.1368263E-02 0.5640068E-08 0.1368258E-02 0.0000000E+00 12 K+ 0.4074310E-03 0.5261491E-04 0.3548161E-03 0.0000000E+00 13 Na+ 0.2568884E-02 0.2421856E-02 0.1470279E-03 0.0000000E+00 14 Mn++ 0.3327277E-04 0.9936454E-09 0.3327177E-04 0.0000000E+00 15 HPO4-- 0.1135583E-04 0.7163677E-05 0.4192153E-05 0.0000000E+00 Chg. balance for solid moles: -.1118E-18 Mass of aqueous solution: 0.999855E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.9190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1397E-05 -5.855 0.7019E-03 -3.154 0.3410E-01 0.2230E-03 clinochlore 0.3046E-03 -3.516 0.1693 -0.771 8.226 0.6440E-01 daphnite 0.1886E-03 -3.725 0.1345 -0.871 6.537 0.4077E-01 chlorite-Mn 0.6654E-05 -5.177 0.4718E-02 -2.326 0.2292 0.1503E-02 hematite 0.2127E-03 -3.672 0.3397E-01 -1.469 1.651 0.6439E-02 microcline 0.3596E-03 -3.444 0.1001 -1.000 4.863 0.3910E-01 muscovite -.4766E-05 1.000 -.1898E-02 1.000 -.9223E-01 -.6713E-03 paragonite 0.1470E-03 -3.833 0.5619E-01 -1.250 2.730 0.1942E-01 stilbite 0.2215E-02 -2.655 1.561 0.193 75.82 0.7279 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.058285 g Volume = 0.899106 cm3 Porosity: 49.1341% V(tot) - V(min): 0.86849E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.9190000 g log = 0.2831 Original solution: 1000.0103000 g Original solution / Rock added: 521.11 (Water/Rock Ratio), log = 2.7169 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1156E-05 1.0073 0.1225E-05 0.1216E-05 CH4,gas 0.2497E-16 1.0129 0.2660E-16 0.2626E-16 H2,gas 0.6579E-06 1.0006 0.6924E-06 0.6920E-06 H2S,gas 0.1493E-14 0.9959 0.1565E-14 0.1571E-14 S2,gas 0.1818E-36 1.0000 0.1913E-36 0.1913E-36 CO,gas 0.2089E-15 1.0000 0.2197E-15 0.2197E-15 SO3,gas 0.1965E-38 1.0000 0.2067E-38 0.2067E-38 SO2,gas 0.5147E-22 1.0000 0.5414E-22 0.5414E-22 HCl,gas 0.2140E-16 1.0000 0.2251E-16 0.2251E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.15165E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 0.19715E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.28 -7.91 -2.637 0.13509E+05 -5.912 3 CH4,gas 4.81 -13.77 -18.58 -4.644 0.31716E+05 -16.575 4 H2,gas 8.29 0.13 -8.16 -4.663 0.13932E+05 -6.160 5 H2S,gas -5.94 -22.75 -16.81 -8.403 0.28695E+05 -14.806 6 S2,gas -7.03 -45.75 -38.72 -5.957 0.66111E+05 -36.718 7 CO,gas 3.51 -14.15 -17.66 -5.433 0.30151E+05 -15.658 8 SO3,gas 17.43 -23.26 -40.68 -10.171 0.69468E+05 -38.685 9 SO2,gas 1.14 -23.13 -24.27 -6.471 0.41434E+05 -22.266 10 HCl,gas 5.48 -13.17 -18.65 -9.324 0.31840E+05 -16.648 11 acmite 7.74 6.28 -1.45 -0.151 0.24813E+04 15 albite-high 0.75 -0.77 -1.52 -0.117 0.26022E+04 16 albite -0.33 -0.77 -0.45 -0.034 0.76153E+03 19 spessartine 24.55 20.63 -3.92 -0.196 0.66927E+04 20 analcite 3.37 2.54 -0.83 -0.092 0.14168E+04 21 andalusite 5.06 1.80 -3.27 -0.327 0.55777E+04 22 andradite 39.09 34.72 -4.37 -0.227 0.74548E+04 26 annite 20.21 16.66 -3.55 -0.197 0.60680E+04 27 phlogopite 27.15 23.34 -3.81 -0.211 0.65002E+04 29 anorthite 12.80 9.17 -3.63 -0.279 0.61934E+04 35 aragonite 0.99 -3.59 -4.57 -1.524 0.78054E+04 36 brucite 12.58 8.59 -3.99 -0.797 0.68062E+04 37 calcite 0.83 -3.59 -4.42 -1.473 0.75440E+04 38 carnegieite-low 9.06 5.86 -3.21 -0.458 0.54782E+04 39 carnegieite-high 10.13 5.86 -4.28 -0.611 0.73051E+04 40 carpholite-Mg 8.65 7.07 -1.58 -0.105 0.26968E+04 41 carpholite-Fe 6.78 4.84 -1.94 -0.129 0.33125E+04 42 celadonite 5.40 2.84 -2.56 -0.150 0.43661E+04 43 celadonite-Fe 3.94 0.62 -3.32 -0.195 0.56715E+04 44 chrysotile 23.94 19.14 -4.80 -0.400 0.81897E+04 50 chloritoid-Mg 13.26 10.39 -2.88 -0.192 0.49090E+04 51 chloritoid-Fe 9.24 8.16 -1.08 -0.072 0.18449E+04 52 chloritoid-Mn 11.46 10.28 -1.18 -0.079 0.20134E+04 54 coesite -2.37 -3.32 -0.95 -0.315 0.16151E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.32 -0.77 -0.255 0.13080E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.65 -3.57 -0.357 0.60880E+04 68 hedenbergite 14.24 10.42 -3.82 -0.382 0.65268E+04 75 epidote 24.78 22.84 -1.93 -0.094 0.32975E+04 76 clinozoisite 22.92 19.10 -3.82 -0.174 0.65234E+04 77 epidote-Fe 29.94 26.59 -3.35 -0.174 0.57192E+04 78 fayalite 14.08 9.41 -4.67 -0.667 0.79728E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.74 -0.311 0.63815E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.54 -1.71 -0.171 0.29198E+04 97 kalsilite 7.62 4.20 -3.42 -0.489 0.58422E+04 98 kaolinite -1.27 -1.52 -0.25 -0.022 0.42070E+03 99 kyanite 4.93 1.80 -3.14 -0.314 0.53545E+04 101 laumontite 2.97 2.54 -0.43 -0.029 0.74210E+03 102 lawsonite 9.68 9.17 -0.51 -0.034 0.86727E+03 103 leucite 4.17 0.88 -3.28 -0.328 0.56076E+04 105 lizardite 23.29 19.14 -4.15 -0.346 0.70800E+04 107 magnetite 20.13 18.96 -1.17 -0.096 0.20024E+04 108 minnesotaite 10.46 5.83 -4.63 -0.273 0.79132E+04 113 margarite 17.45 14.28 -3.17 -0.127 0.54133E+04 120 muscovite 2.68 2.68 0.00 0.000 0.30331E-10 122 nepheline 8.38 5.86 -2.52 -0.360 0.43062E+04 134 phlogopite-Na 29.73 25.00 -4.73 -0.263 0.80836E+04 136 prehnite 19.47 16.55 -2.92 -0.172 0.49878E+04 137 prehnite-Fe 22.59 20.29 -2.30 -0.138 0.39243E+04 138 pumpellyite-Fe 46.47 42.01 -4.46 -0.099 0.76192E+04 139 pumpellyite-Mg 49.19 44.24 -4.96 -0.110 0.84652E+04 145 pyroxmangite 7.42 5.17 -2.24 -0.449 0.38298E+04 146 pyrophyllite -6.10 -8.15 -2.05 -0.128 0.35038E+04 147 quartz -2.98 -3.32 -0.33 -0.111 0.56904E+03 151 rhodochrosite -0.96 -5.79 -4.83 -1.609 0.82440E+04 152 rhodonite 7.46 5.17 -2.29 -0.458 0.39090E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.80 -3.53 -0.353 0.60199E+04 164 stilpnomelane-Fe 13.18 12.88 -0.30 -0.009 0.51049E+03 165 stilpnomelane-Mg 27.60 24.02 -3.58 -0.107 0.61053E+04 168 sudoite 21.22 17.46 -3.76 -0.121 0.64184E+04 171 talc 16.55 12.51 -4.04 -0.238 0.69032E+04 174 tephroite 18.11 13.66 -4.45 -0.636 0.76008E+04 177 topaz-H 4.67 1.80 -2.87 -0.261 0.49036E+04 178 tridymite -2.61 -3.32 -0.70 -0.234 0.11963E+04 187 wairakite 4.06 2.54 -1.52 -0.089 0.25929E+04 188 walstromite 11.53 7.37 -4.15 -0.831 0.70914E+04 189 wollastonite 10.48 7.37 -3.11 -0.621 0.53053E+04 190 pseudo-wollastonite 11.02 7.37 -3.65 -0.729 0.62239E+04 191 zoisite 22.96 19.10 -3.86 -0.176 0.65959E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.45 -2.89 -0.179 0.49332E+04 194 beidellite-H -2.24 -6.21 -3.97 -0.253 0.67814E+04 195 beidellite-K -1.44 -4.58 -3.14 -0.192 0.53638E+04 196 beidellite-Mg -1.71 -4.80 -3.09 -0.191 0.52733E+04 197 beidellite-Na -1.26 -4.03 -2.77 -0.170 0.47338E+04 199 chalcedony -2.79 -3.32 -0.52 -0.174 0.88935E+03 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37234E+04 202 montmorillonite-K -2.16 -4.52 -2.36 -0.145 0.40317E+04 203 montmorillonite-Mg -2.40 -4.74 -2.34 -0.145 0.39945E+04 204 montmorillonite-Na -1.96 -3.98 -2.01 -0.123 0.34399E+04 205 nontronite-Ca 3.28 3.04 -0.24 -0.016 0.41301E+03 206 nontronite-H 2.60 1.27 -1.32 -0.089 0.22570E+04 207 nontronite-K 3.40 2.91 -0.49 -0.032 0.84279E+03 208 nontronite-Mg 3.14 2.69 -0.45 -0.029 0.76477E+03 209 nontronite-Na 3.58 3.46 -0.13 -0.008 0.21452E+03 224 tobermorite 9.84 5.59 -4.25 -1.159 0.72559E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.36 -3.46 -0.865 0.59109E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.412 0.21095E+04 242 an20ab80 2.08 1.21 -0.86 -0.067 0.14763E+04 243 an25ab75 2.71 1.71 -1.00 -0.077 0.17029E+04 244 an30ab70 3.34 2.21 -1.13 -0.087 0.19378E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.9190000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9996E+00 Moles total = 0.5548E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1569541E-02 Osmotic coef. = 0.9775 True ionic strength = .2480602E-02 Chg. balance for total moles = 0.4572E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.57865E-09 -9.2376 0.53375E-09 -9.2727 0.92240E+00 -0.0351 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12710E-03 -3.8958 0.92149E+00 -0.0355 4 SO4-- 0.25498E-04 -4.5935 0.19439E-04 -4.7113 0.76239E+00 -0.1178 5 HCO3- 0.10801E-04 -4.9665 0.99552E-05 -5.0019 0.92171E+00 -0.0354 6 HS- 0.36107E-13 -13.4424 0.33273E-13 -13.4779 0.92151E+00 -0.0355 7 Al+++ 0.98114E-25 -25.0083 0.54373E-25 -25.2646 0.55418E+00 -0.2563 8 H4SiO4 0.48617E-03 -3.3132 0.48617E-03 -3.3132 0.10000E+01 0.0000 9 Ca++ 0.17901E-07 -7.7471 0.13631E-07 -7.8655 0.76148E+00 -0.1183 10 Mg++ 0.14570E-09 -9.8366 0.11086E-09 -9.9552 0.76091E+00 -0.1187 11 Fe++ 0.86163E-12 -12.0647 0.65574E-12 -12.1833 0.76105E+00 -0.1186 12 K+ 0.52142E-04 -4.2828 0.48061E-04 -4.3182 0.92175E+00 -0.0354 13 Na+ 0.23932E-02 -2.6210 0.22053E-02 -2.6565 0.92147E+00 -0.0355 14 Mn++ 0.11512E-09 -9.9388 0.87624E-10 -10.0574 0.76115E+00 -0.1185 15 HPO4-- 0.73640E-05 -5.1329 0.56144E-05 -5.2507 0.76240E+00 -0.1178 16 HSiO3- 0.96442E-03 -3.0157 0.88870E-03 -3.0512 0.92149E+00 -0.0355 17 Ca(HSiO3)+ 0.29445E-09 -9.5310 0.27142E-09 -9.5664 0.92178E+00 -0.0354 18 Mg(HSiO3)+ 0.29803E-11 -11.5257 0.27472E-11 -11.5611 0.92178E+00 -0.0354 19 NaHSiO3,aq 0.31127E-04 -4.5069 0.31127E-04 -4.5069 0.10000E+01 0.0000 20 AlO+ 0.26730E-13 -13.5730 0.24639E-13 -13.6084 0.92178E+00 -0.0354 21 AlOH+2 0.86538E-19 -19.0628 0.65878E-19 -19.1813 0.76127E+00 -0.1185 22 HAlO2,aq 0.92376E-08 -8.0344 0.92376E-08 -8.0344 0.10000E+01 0.0000 23 AlO2- 0.41950E-04 -4.3773 0.38645E-04 -4.4129 0.92121E+00 -0.0356 24 CH4,aq 0.16728E-19 -19.7765 0.16720E-19 -19.7768 0.99951E+00 -0.0002 29 CO,aq 0.13905E-18 -18.8568 0.13905E-18 -18.8568 0.10000E+01 0.0000 30 CO2,aq 0.10718E-07 -7.9699 0.10713E-07 -7.9701 0.99951E+00 -0.0002 31 CO3-2 0.22628E-05 -5.6454 0.17245E-05 -5.7633 0.76212E+00 -0.1180 32 CaCO3,aq 0.28791E-09 -9.5407 0.28791E-09 -9.5407 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.37094E-11 -11.4307 0.34193E-11 -11.4661 0.92178E+00 -0.0354 34 CaCl+ 0.29951E-11 -11.5236 0.27608E-11 -11.5590 0.92178E+00 -0.0354 35 CaCl2,aq 0.81704E-16 -16.0878 0.81704E-16 -16.0878 0.10000E+01 0.0000 36 CaOH+ 0.19536E-08 -8.7092 0.18008E-08 -8.7445 0.92178E+00 -0.0354 37 CaSO4,aq 0.82562E-10 -10.0832 0.82562E-10 -10.0832 0.10000E+01 0.0000 38 HCl,aq 0.12761E-13 -13.8941 0.12761E-13 -13.8941 0.10000E+01 0.0000 43 FeCl+ 0.14083E-15 -15.8513 0.12981E-15 -15.8867 0.92178E+00 -0.0354 46 FeO,aq 0.91021E-10 -10.0409 0.91021E-10 -10.0409 0.10000E+01 0.0000 47 FeOH+ 0.44186E-10 -10.3547 0.40730E-10 -10.3901 0.92178E+00 -0.0354 48 HFeO2- 0.19905E-08 -8.7010 0.18343E-08 -8.7365 0.92149E+00 -0.0355 49 FeO+ 0.47899E-14 -14.3197 0.44152E-14 -14.3550 0.92178E+00 -0.0354 51 FeO2- 0.33056E-08 -8.4808 0.30460E-08 -8.5163 0.92149E+00 -0.0355 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.50419E-09 -9.2974 0.50394E-09 -9.2976 0.99951E+00 -0.0002 54 KCl,aq 0.10816E-09 -9.9659 0.10816E-09 -9.9659 0.10000E+01 0.0000 55 KHSO4,aq 0.13344E-17 -17.8747 0.13344E-17 -17.8747 0.10000E+01 0.0000 56 KOH,aq 0.39255E-07 -7.4061 0.39255E-07 -7.4061 0.10000E+01 0.0000 57 KSO4- 0.15620E-07 -7.8063 0.14394E-07 -7.8418 0.92149E+00 -0.0355 58 MgCO3,aq 0.58510E-12 -12.2328 0.58510E-12 -12.2328 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.30764E-13 -13.5120 0.28357E-13 -13.5473 0.92178E+00 -0.0354 60 MgCl+ 0.22114E-13 -13.6553 0.20384E-13 -13.6907 0.92178E+00 -0.0354 61 MgOH+ 0.88024E-10 -10.0554 0.81139E-10 -10.0908 0.92178E+00 -0.0354 63 MnO,aq 0.32469E-09 -9.4885 0.32469E-09 -9.4885 0.10000E+01 0.0000 64 MnOH+ 0.54850E-09 -9.2608 0.50560E-09 -9.2962 0.92178E+00 -0.0354 65 MnO2-2 0.51718E-13 -13.2864 0.39415E-13 -13.4043 0.76212E+00 -0.1180 66 HMnO2- 0.49465E-11 -11.3057 0.45581E-11 -11.3412 0.92149E+00 -0.0355 69 MnCl+ 0.73125E-13 -13.1359 0.67405E-13 -13.1713 0.92178E+00 -0.0354 70 MnSO4,aq 0.48273E-12 -12.3163 0.48273E-12 -12.3163 0.10000E+01 0.0000 71 NaCl,aq 0.91524E-07 -7.0385 0.91524E-07 -7.0385 0.10000E+01 0.0000 72 NaOH,aq 0.18155E-05 -5.7410 0.18155E-05 -5.7410 0.10000E+01 0.0000 74 OH- 0.12199E-02 -2.9137 0.11238E-02 -2.9493 0.92121E+00 -0.0356 79 HPO3-2 0.11726E-16 -16.9309 0.89365E-17 -17.0488 0.76212E+00 -0.1180 81 H2PO3- 0.10168E-19 -19.9928 0.93696E-20 -20.0283 0.92149E+00 -0.0355 82 H3PO4,aq 0.10297E-13 -13.9873 0.10297E-13 -13.9873 0.10000E+01 0.0000 83 H2PO4- 0.57005E-07 -7.2441 0.52537E-07 -7.2795 0.92163E+00 -0.0354 84 PO4-3 0.16443E-07 -7.7840 0.91861E-08 -8.0369 0.55868E+00 -0.2528 87 H2P2O7-2 0.28345E-15 -15.5475 0.21602E-15 -15.6655 0.76212E+00 -0.1180 88 HP2O7-3 0.14974E-12 -12.8247 0.82992E-13 -13.0810 0.55423E+00 -0.2563 89 P2O7-4 0.10755E-12 -12.9684 0.38359E-13 -13.4161 0.35665E+00 -0.4478 90 H2S,aq 0.53385E-16 -16.2726 0.53359E-16 -16.2728 0.99951E+00 -0.0002 97 SO3-2 0.17485E-14 -14.7573 0.13357E-14 -14.8743 0.76394E+00 -0.1169 98 HSO3- 0.45277E-16 -16.3441 0.41722E-16 -16.3796 0.92149E+00 -0.0355 99 HSO4- 0.10442E-10 -10.9812 0.96271E-11 -11.0165 0.92192E+00 -0.0353 Charge balance for all species = 0.4575E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5786478E-09 -.2387390E-02 -.2405837E+01 0.0000 2 H2O 0.1000000E+01 0.5550856E+02 0.9997922E+06 0.0000 3 Cl- 0.1379316E-03 0.1380232E-03 0.4892304E+01 5.3768 4 SO4-- 0.2549782E-04 0.2551385E-04 0.2450384E+01 13.8340 5 HCO3- 0.1080084E-04 0.1307465E-04 0.7976099E+00 4.2707 6 HS- 0.3610662E-13 -.3125456E-09 -.1033433E-04 -4.2052 7 Al+++ 0.9811391E-25 0.4195882E-04 0.1131873E+01 2.5534 8 H4SiO4 0.4861713E-03 0.1481717E-02 0.1423858E+03 -3.3132 9 Ca++ 0.1790096E-07 0.2052620E-07 0.8224754E-03 10.6799 10 Mg++ 0.1456964E-09 0.2373387E-09 0.5768961E-05 8.5901 11 Fe++ 0.8616303E-12 0.5635640E-08 0.3146671E-03 6.3621 12 K+ 0.5214157E-04 0.5219655E-04 0.2040559E+01 4.9545 13 Na+ 0.2393228E-02 0.2426262E-02 0.5576750E+02 6.6161 14 Mn++ 0.1151208E-09 0.9938637E-09 0.5458936E-04 8.4880 15 HPO4-- 0.7364023E-05 0.7437471E-05 0.7136903E+00 13.2946 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3176275E-01 -.2386541E-02 -.2937621E-01 0.0000000E+00 2 H2O 0.5548419E+02 0.5548884E+02 -.4640459E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7868650E-04 0.2550478E-04 0.5318172E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5318203E-04 -.3124345E-09 -.5318172E-04 0.0000000E+00 7 Al+++ 0.6257363E-02 0.4194391E-04 0.6215419E-02 0.0000000E+00 8 H4SiO4 0.1998213E-01 0.1481190E-02 0.1850094E-01 0.0000000E+00 9 Ca++ 0.2221595E-02 0.2051891E-07 0.2221574E-02 0.0000000E+00 10 Mg++ 0.1523016E-02 0.2372544E-09 0.1523016E-02 0.0000000E+00 11 Fe++ 0.1368263E-02 0.5633637E-08 0.1368258E-02 0.0000000E+00 12 K+ 0.4074310E-03 0.5217800E-04 0.3552530E-03 0.0000000E+00 13 Na+ 0.2568884E-02 0.2425400E-02 0.1434837E-03 0.0000000E+00 14 Mn++ 0.3327277E-04 0.9935106E-09 0.3327177E-04 0.0000000E+00 15 HPO4-- 0.1135583E-04 0.7434828E-05 0.3921002E-05 0.0000000E+00 Chg. balance for solid moles: 0.1064E-17 Mass of aqueous solution: 0.999856E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.9190000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1307E-05 -5.884 0.6565E-03 -3.183 0.3190E-01 0.2086E-03 clinochlore 0.3046E-03 -3.516 0.1693 -0.771 8.227 0.6440E-01 daphnite 0.1886E-03 -3.725 0.1345 -0.871 6.538 0.4077E-01 chlorite-Mn 0.6654E-05 -5.177 0.4718E-02 -2.326 0.2293 0.1503E-02 hematite 0.2127E-03 -3.672 0.3397E-01 -1.469 1.651 0.6439E-02 microcline 0.3553E-03 -3.449 0.9888E-01 -1.005 4.805 0.3863E-01 paragonite 0.1435E-03 -3.843 0.5484E-01 -1.261 2.665 0.1896E-01 stilbite 0.2215E-02 -2.655 1.561 0.193 75.85 0.7281 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.057897 g Volume = 0.898972 cm3 Porosity: 49.1416% V(tot) - V(min): 0.86863E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.9190000 g log = 0.2831 Original solution: 1000.0103000 g Original solution / Rock added: 521.11 (Water/Rock Ratio), log = 2.7169 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1157E-05 1.0073 0.1226E-05 0.1217E-05 CH4,gas 0.2482E-16 1.0129 0.2644E-16 0.2610E-16 H2,gas 0.6567E-06 1.0006 0.6912E-06 0.6908E-06 H2S,gas 0.1485E-14 0.9959 0.1556E-14 0.1563E-14 S2,gas 0.1805E-36 1.0000 0.1899E-36 0.1899E-36 CO,gas 0.2087E-15 1.0000 0.2196E-15 0.2196E-15 SO3,gas 0.1968E-38 1.0000 0.2070E-38 0.2070E-38 SO2,gas 0.5146E-22 1.0000 0.5414E-22 0.5414E-22 HCl,gas 0.2142E-16 1.0000 0.2253E-16 0.2253E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.27 -7.91 -2.637 0.13508E+05 -5.911 3 CH4,gas 4.81 -13.77 -18.58 -4.644 0.31721E+05 -16.578 4 H2,gas 8.29 0.13 -8.16 -4.663 0.13934E+05 -6.160 5 H2S,gas -5.94 -22.75 -16.81 -8.404 0.28699E+05 -14.808 6 S2,gas -7.03 -45.75 -38.72 -5.957 0.66116E+05 -36.722 7 CO,gas 3.51 -14.15 -17.66 -5.433 0.30151E+05 -15.658 8 SO3,gas 17.43 -23.26 -40.68 -10.171 0.69467E+05 -38.684 9 SO2,gas 1.14 -23.13 -24.27 -6.471 0.41434E+05 -22.267 10 HCl,gas 5.48 -13.17 -18.65 -9.324 0.31840E+05 -16.647 11 acmite 7.74 6.29 -1.45 -0.151 0.24739E+04 15 albite-high 0.75 -0.77 -1.52 -0.117 0.25950E+04 16 albite -0.33 -0.77 -0.44 -0.034 0.75430E+03 19 spessartine 24.55 20.63 -3.92 -0.196 0.66914E+04 20 analcite 3.37 2.54 -0.83 -0.092 0.14130E+04 21 andalusite 5.06 1.79 -3.27 -0.327 0.55814E+04 22 andradite 39.09 34.70 -4.39 -0.228 0.74961E+04 26 annite 20.21 16.65 -3.55 -0.197 0.60700E+04 27 phlogopite 27.15 23.34 -3.81 -0.212 0.65021E+04 29 anorthite 12.80 9.16 -3.64 -0.280 0.62109E+04 35 aragonite 0.99 -3.59 -4.58 -1.527 0.78219E+04 36 brucite 12.58 8.59 -3.99 -0.797 0.68068E+04 37 calcite 0.83 -3.59 -4.43 -1.476 0.75605E+04 38 carnegieite-low 9.06 5.86 -3.21 -0.458 0.54780E+04 39 carnegieite-high 10.13 5.86 -4.28 -0.611 0.73049E+04 40 carpholite-Mg 8.65 7.07 -1.58 -0.105 0.26977E+04 41 carpholite-Fe 6.78 4.84 -1.94 -0.129 0.33133E+04 42 celadonite 5.40 2.85 -2.56 -0.150 0.43633E+04 43 celadonite-Fe 3.94 0.62 -3.32 -0.195 0.56686E+04 44 chrysotile 23.94 19.14 -4.79 -0.399 0.81846E+04 50 chloritoid-Mg 13.26 10.38 -2.88 -0.192 0.49134E+04 51 chloritoid-Fe 9.24 8.16 -1.08 -0.072 0.18493E+04 52 chloritoid-Mn 11.46 10.28 -1.18 -0.079 0.20177E+04 54 coesite -2.37 -3.31 -0.94 -0.315 0.16116E+04 59 corundum 8.43 5.11 -3.33 -0.302 0.56802E+04 61 cristobalite -2.55 -3.31 -0.76 -0.255 0.13045E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.55 -0.34 -0.057 0.58517E+03 67 diopside 16.22 12.64 -3.57 -0.357 0.60989E+04 68 hedenbergite 14.24 10.42 -3.83 -0.383 0.65378E+04 75 epidote 24.78 22.83 -1.95 -0.095 0.33288E+04 76 clinozoisite 22.92 19.08 -3.84 -0.175 0.65583E+04 77 epidote-Fe 29.94 26.57 -3.37 -0.175 0.57468E+04 78 fayalite 14.08 9.41 -4.67 -0.667 0.79706E+04 83 gibbsite 4.10 2.55 -1.54 -0.221 0.26364E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63765E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.54 -1.71 -0.171 0.29161E+04 97 kalsilite 7.62 4.19 -3.43 -0.489 0.58492E+04 98 kaolinite -1.27 -1.52 -0.25 -0.022 0.42094E+03 99 kyanite 4.93 1.79 -3.14 -0.314 0.53582E+04 101 laumontite 2.97 2.53 -0.44 -0.029 0.75260E+03 102 lawsonite 9.68 9.16 -0.52 -0.035 0.88477E+03 103 leucite 4.17 0.88 -3.29 -0.329 0.56111E+04 105 lizardite 23.29 19.14 -4.14 -0.345 0.70749E+04 107 magnetite 20.13 18.96 -1.17 -0.096 0.20030E+04 108 minnesotaite 10.46 5.83 -4.63 -0.272 0.79011E+04 113 margarite 17.45 14.27 -3.18 -0.127 0.54380E+04 120 muscovite 2.68 2.67 0.00 0.000 0.72317E+01 122 nepheline 8.38 5.86 -2.52 -0.360 0.43059E+04 134 phlogopite-Na 29.73 25.00 -4.73 -0.263 0.80783E+04 136 prehnite 19.47 16.53 -2.94 -0.173 0.50191E+04 137 prehnite-Fe 22.59 20.27 -2.31 -0.139 0.39519E+04 138 pumpellyite-Fe 46.47 41.97 -4.50 -0.100 0.76860E+04 139 pumpellyite-Mg 49.19 44.20 -5.00 -0.111 0.85320E+04 145 pyroxmangite 7.42 5.17 -2.24 -0.448 0.38269E+04 146 pyrophyllite -6.10 -8.15 -2.05 -0.128 0.34970E+04 147 quartz -2.98 -3.31 -0.33 -0.110 0.56554E+03 151 rhodochrosite -0.96 -5.79 -4.83 -1.609 0.82439E+04 152 rhodonite 7.46 5.17 -2.29 -0.458 0.39062E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.79 -3.53 -0.353 0.60236E+04 164 stilpnomelane-Fe 13.18 12.89 -0.29 -0.009 0.49644E+03 165 stilpnomelane-Mg 27.60 24.03 -3.57 -0.106 0.60913E+04 168 sudoite 21.22 17.45 -3.76 -0.121 0.64237E+04 171 talc 16.55 12.52 -4.04 -0.237 0.68912E+04 174 tephroite 18.11 13.66 -4.45 -0.636 0.75986E+04 177 topaz-H 4.67 1.79 -2.87 -0.261 0.49073E+04 178 tridymite -2.61 -3.31 -0.70 -0.233 0.11928E+04 187 wairakite 4.06 2.53 -1.52 -0.090 0.26034E+04 188 walstromite 11.53 7.37 -4.16 -0.832 0.71052E+04 189 wollastonite 10.48 7.37 -3.12 -0.623 0.53191E+04 190 pseudo-wollastonite 11.02 7.37 -3.65 -0.731 0.62377E+04 191 zoisite 22.96 19.08 -3.88 -0.177 0.66308E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.45 -2.89 -0.179 0.49316E+04 194 beidellite-H -2.24 -6.21 -3.97 -0.253 0.67770E+04 195 beidellite-K -1.44 -4.58 -3.14 -0.192 0.53617E+04 196 beidellite-Mg -1.71 -4.79 -3.09 -0.191 0.52690E+04 197 beidellite-Na -1.26 -4.03 -2.77 -0.170 0.47293E+04 199 chalcedony -2.79 -3.31 -0.52 -0.173 0.88585E+03 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37185E+04 202 montmorillonite-K -2.16 -4.52 -2.36 -0.144 0.40263E+04 203 montmorillonite-Mg -2.40 -4.74 -2.33 -0.144 0.39869E+04 204 montmorillonite-Na -1.96 -3.97 -2.01 -0.123 0.34321E+04 205 nontronite-Ca 3.28 3.04 -0.24 -0.015 0.40421E+03 206 nontronite-H 2.60 1.28 -1.31 -0.088 0.22453E+04 207 nontronite-K 3.40 2.92 -0.49 -0.031 0.83341E+03 208 nontronite-Mg 3.14 2.70 -0.44 -0.029 0.75322E+03 209 nontronite-Na 3.58 3.46 -0.12 -0.008 0.20275E+03 224 tobermorite 9.84 5.58 -4.26 -1.161 0.72668E+04 233 boehmite 4.43 2.55 -1.88 -0.313 0.32036E+04 235 ferrous-oxide 9.82 6.36 -3.46 -0.866 0.59115E+04 240 silica-amorphous -2.08 -3.31 -1.23 -0.411 0.21060E+04 242 an20ab80 2.08 1.22 -0.86 -0.066 0.14740E+04 243 an25ab75 2.71 1.71 -1.00 -0.077 0.17018E+04 244 an30ab70 3.34 2.21 -1.14 -0.087 0.19380E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.9190000 g New total amount of reactant added: 1.9590000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4573E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.9590000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9996E+00 Moles total = 0.5548E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1593677E-02 Osmotic coef. = 0.9773 True ionic strength = .2526342E-02 Chg. balance for total moles = 0.4573E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.56898E-09 -9.2449 0.52455E-09 -9.2802 0.92191E+00 -0.0353 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12703E-03 -3.8961 0.92098E+00 -0.0357 4 SO4-- 0.25498E-04 -4.5935 0.19398E-04 -4.7123 0.76074E+00 -0.1188 5 HCO3- 0.10765E-04 -4.9680 0.99171E-05 -5.0036 0.92121E+00 -0.0356 6 HS- 0.36505E-13 -13.4377 0.33621E-13 -13.4734 0.92101E+00 -0.0357 7 Al+++ 0.91984E-25 -25.0363 0.50727E-25 -25.2948 0.55148E+00 -0.2585 8 H4SiO4 0.48873E-03 -3.3109 0.48873E-03 -3.3109 0.10000E+01 0.0000 9 Ca++ 0.17287E-07 -7.7623 0.13135E-07 -7.8816 0.75982E+00 -0.1193 10 Mg++ 0.14155E-09 -9.8491 0.10747E-09 -9.9687 0.75925E+00 -0.1196 11 Fe++ 0.83713E-12 -12.0772 0.63570E-12 -12.1967 0.75938E+00 -0.1195 12 K+ 0.51346E-04 -4.2895 0.47302E-04 -4.3251 0.92125E+00 -0.0356 13 Na+ 0.24394E-02 -2.6127 0.22466E-02 -2.6485 0.92096E+00 -0.0358 14 Mn++ 0.11185E-09 -9.9514 0.84947E-10 -10.0709 0.75949E+00 -0.1195 15 HPO4-- 0.76707E-05 -5.1152 0.58356E-05 -5.2339 0.76076E+00 -0.1188 16 HSiO3- 0.98705E-03 -3.0057 0.90906E-03 -3.0414 0.92098E+00 -0.0357 17 Ca(HSiO3)+ 0.29038E-09 -9.5370 0.26752E-09 -9.5726 0.92128E+00 -0.0356 18 Mg(HSiO3)+ 0.29570E-11 -11.5291 0.27242E-11 -11.5648 0.92128E+00 -0.0356 19 NaHSiO3,aq 0.32437E-04 -4.4890 0.32437E-04 -4.4890 0.10000E+01 0.0000 20 AlO+ 0.25834E-13 -13.5878 0.23800E-13 -13.6234 0.92128E+00 -0.0356 21 AlOH+2 0.82331E-19 -19.0844 0.62539E-19 -19.2038 0.75961E+00 -0.1194 22 HAlO2,aq 0.90796E-08 -8.0419 0.90796E-08 -8.0419 0.10000E+01 0.0000 23 AlO2- 0.41979E-04 -4.3770 0.38650E-04 -4.4128 0.92071E+00 -0.0359 24 CH4,aq 0.16875E-19 -19.7728 0.16867E-19 -19.7730 0.99951E+00 -0.0002 29 CO,aq 0.13715E-18 -18.8628 0.13715E-18 -18.8628 0.10000E+01 0.0000 30 CO2,aq 0.10493E-07 -7.9791 0.10488E-07 -7.9793 0.99951E+00 -0.0002 31 CO3-2 0.22986E-05 -5.6385 0.17480E-05 -5.7574 0.76047E+00 -0.1189 32 CaCO3,aq 0.28121E-09 -9.5510 0.28121E-09 -9.5510 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.35626E-11 -11.4482 0.32821E-11 -11.4838 0.92128E+00 -0.0356 34 CaCl+ 0.28860E-11 -11.5397 0.26588E-11 -11.5753 0.92128E+00 -0.0356 35 CaCl2,aq 0.78642E-16 -16.1043 0.78642E-16 -16.1043 0.10000E+01 0.0000 36 CaOH+ 0.19165E-08 -8.7175 0.17657E-08 -8.7531 0.92128E+00 -0.0356 37 CaSO4,aq 0.79385E-10 -10.1003 0.79385E-10 -10.1003 0.10000E+01 0.0000 38 HCl,aq 0.12534E-13 -13.9019 0.12534E-13 -13.9019 0.10000E+01 0.0000 43 FeCl+ 0.13652E-15 -15.8648 0.12578E-15 -15.9004 0.92128E+00 -0.0356 46 FeO,aq 0.91363E-10 -10.0392 0.91363E-10 -10.0392 0.10000E+01 0.0000 47 FeOH+ 0.43611E-10 -10.3604 0.40178E-10 -10.3960 0.92128E+00 -0.0356 48 HFeO2- 0.20342E-08 -8.6916 0.18734E-08 -8.7274 0.92098E+00 -0.0357 49 FeO+ 0.47099E-14 -14.3270 0.43391E-14 -14.3626 0.92128E+00 -0.0356 51 FeO2- 0.33654E-08 -8.4730 0.30995E-08 -8.5087 0.92098E+00 -0.0357 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.50798E-09 -9.2942 0.50773E-09 -9.2944 0.99951E+00 -0.0002 54 KCl,aq 0.10640E-09 -9.9731 0.10640E-09 -9.9731 0.10000E+01 0.0000 55 KHSO4,aq 0.12879E-17 -17.8901 0.12879E-17 -17.8901 0.10000E+01 0.0000 56 KOH,aq 0.39313E-07 -7.4055 0.39313E-07 -7.4055 0.10000E+01 0.0000 57 KSO4- 0.15349E-07 -7.8139 0.14136E-07 -7.8497 0.92098E+00 -0.0357 58 MgCO3,aq 0.57496E-12 -12.2404 0.57496E-12 -12.2404 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.29726E-13 -13.5269 0.27386E-13 -13.5625 0.92128E+00 -0.0356 60 MgCl+ 0.21438E-13 -13.6688 0.19750E-13 -13.7044 0.92128E+00 -0.0356 61 MgOH+ 0.86878E-10 -10.0611 0.80039E-10 -10.0967 0.92128E+00 -0.0356 63 MnO,aq 0.32591E-09 -9.4869 0.32591E-09 -9.4869 0.10000E+01 0.0000 64 MnOH+ 0.54136E-09 -9.2665 0.49874E-09 -9.3021 0.92128E+00 -0.0356 65 MnO2-2 0.53865E-13 -13.2687 0.40963E-13 -13.3876 0.76047E+00 -0.1189 66 HMnO2- 0.50549E-11 -11.2963 0.46554E-11 -11.3320 0.92098E+00 -0.0357 69 MnCl+ 0.70890E-13 -13.1494 0.65310E-13 -13.1850 0.92128E+00 -0.0356 70 MnSO4,aq 0.46698E-12 -12.3307 0.46698E-12 -12.3307 0.10000E+01 0.0000 71 NaCl,aq 0.93188E-07 -7.0306 0.93188E-07 -7.0306 0.10000E+01 0.0000 72 NaOH,aq 0.18820E-05 -5.7254 0.18820E-05 -5.7254 0.10000E+01 0.0000 74 OH- 0.12420E-02 -2.9059 0.11435E-02 -2.9418 0.92071E+00 -0.0359 79 HPO3-2 0.12306E-16 -16.9099 0.93585E-17 -17.0288 0.76047E+00 -0.1189 81 H2PO3- 0.10470E-19 -19.9800 0.96428E-20 -20.0158 0.92098E+00 -0.0357 82 H3PO4,aq 0.10337E-13 -13.9856 0.10337E-13 -13.9856 0.10000E+01 0.0000 83 H2PO4- 0.58261E-07 -7.2346 0.53666E-07 -7.2703 0.92113E+00 -0.0357 84 PO4-3 0.17473E-07 -7.7576 0.97156E-08 -8.0125 0.55603E+00 -0.2549 87 H2P2O7-2 0.29640E-15 -15.5281 0.22541E-15 -15.6470 0.76047E+00 -0.1189 88 HP2O7-3 0.15976E-12 -12.7965 0.88115E-13 -13.0549 0.55153E+00 -0.2584 89 P2O7-4 0.11720E-12 -12.9311 0.41441E-13 -13.3826 0.35359E+00 -0.4515 90 H2S,aq 0.53014E-16 -16.2756 0.52988E-16 -16.2758 0.99951E+00 -0.0002 97 SO3-2 0.17616E-14 -14.7541 0.13429E-14 -14.8720 0.76232E+00 -0.1179 98 HSO3- 0.44759E-16 -16.3491 0.41223E-16 -16.3849 0.92098E+00 -0.0357 99 HSO4- 0.10246E-10 -10.9894 0.94410E-11 -11.0250 0.92142E+00 -0.0355 Charge balance for all species = 0.4616E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5689760E-09 -.2433630E-02 -.2452427E+01 0.0000 2 H2O 0.1000000E+01 0.5550856E+02 0.9997886E+06 0.0000 3 Cl- 0.1379309E-03 0.1380242E-03 0.4892322E+01 5.3841 4 SO4-- 0.2549828E-04 0.2551404E-04 0.2450393E+01 13.8482 5 HCO3- 0.1076533E-04 0.1307474E-04 0.7976127E+00 4.2766 6 HS- 0.3650459E-13 -.3190746E-09 -.1055017E-04 -4.1932 7 Al+++ 0.9198370E-25 0.4198785E-04 0.1132652E+01 2.5459 8 H4SiO4 0.4887347E-03 0.1508220E-02 0.1449320E+03 -3.3109 9 Ca++ 0.1728662E-07 0.1986058E-07 0.7958013E-03 10.6789 10 Mg++ 0.1415541E-09 0.2320156E-09 0.5639552E-05 8.5917 11 Fe++ 0.8371310E-12 0.5738820E-08 0.3204271E-03 6.3637 12 K+ 0.5134597E-04 0.5140073E-04 0.2009440E+01 4.9551 13 Na+ 0.2439420E-02 0.2473832E-02 0.5686069E+02 6.6317 14 Mn++ 0.1118473E-09 0.9847614E-09 0.5408921E-04 8.4896 15 HPO4-- 0.7670698E-05 0.7746432E-05 0.7433352E+00 13.3265 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3242509E-01 -.2432748E-02 -.2999234E-01 0.0000000E+00 2 H2O 0.5548369E+02 0.5548844E+02 -.4744639E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7979504E-04 0.2550479E-04 0.5429025E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5429057E-04 -.3189590E-09 -.5429025E-04 0.0000000E+00 7 Al+++ 0.6387793E-02 0.4197263E-04 0.6345820E-02 0.0000000E+00 8 H4SiO4 0.2039864E-01 0.1507673E-02 0.1889097E-01 0.0000000E+00 9 Ca++ 0.2267601E-02 0.1985338E-07 0.2267581E-02 0.0000000E+00 10 Mg++ 0.1554762E-02 0.2319315E-09 0.1554762E-02 0.0000000E+00 11 Fe++ 0.1396784E-02 0.5736740E-08 0.1396778E-02 0.0000000E+00 12 K+ 0.4159236E-03 0.5138210E-04 0.3645415E-03 0.0000000E+00 13 Na+ 0.2619093E-02 0.2472935E-02 0.1461580E-03 0.0000000E+00 14 Mn++ 0.3396631E-04 0.9844044E-09 0.3396533E-04 0.0000000E+00 15 HPO4-- 0.1159253E-04 0.7743624E-05 0.3848908E-05 0.0000000E+00 Chg. balance for solid moles: -.8132E-18 Mass of aqueous solution: 0.999852E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.9590000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1283E-05 -5.892 0.6445E-03 -3.191 0.3067E-01 0.2048E-03 clinochlore 0.3110E-03 -3.507 0.1728 -0.762 8.226 0.6574E-01 daphnite 0.1925E-03 -3.716 0.1373 -0.862 6.537 0.4162E-01 chlorite-Mn 0.6793E-05 -5.168 0.4816E-02 -2.317 0.2292 0.1535E-02 hematite 0.2172E-03 -3.663 0.3468E-01 -1.460 1.651 0.6573E-02 microcline 0.3645E-03 -3.438 0.1015 -0.994 4.829 0.3964E-01 paragonite 0.1462E-03 -3.835 0.5586E-01 -1.253 2.659 0.1931E-01 stilbite 0.2261E-02 -2.646 1.593 0.202 75.84 0.7432 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.101139 g Volume = 0.917851 cm3 Porosity: 48.5394% V(tot) - V(min): 0.86575E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.9590000 g log = 0.2920 Original solution: 1000.0103000 g Original solution / Rock added: 510.47 (Water/Rock Ratio), log = 2.7080 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1133E-05 1.0073 0.1201E-05 0.1192E-05 CH4,gas 0.2503E-16 1.0129 0.2667E-16 0.2633E-16 H2,gas 0.6616E-06 1.0006 0.6964E-06 0.6960E-06 H2S,gas 0.1475E-14 0.9959 0.1545E-14 0.1552E-14 S2,gas 0.1754E-36 1.0000 0.1845E-36 0.1845E-36 CO,gas 0.2059E-15 1.0000 0.2166E-15 0.2166E-15 SO3,gas 0.1897E-38 1.0000 0.1995E-38 0.1995E-38 SO2,gas 0.4997E-22 1.0000 0.5257E-22 0.5257E-22 HCl,gas 0.2104E-16 1.0000 0.2213E-16 0.2213E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.28 -7.92 -2.640 0.13524E+05 -5.921 3 CH4,gas 4.81 -13.76 -18.57 -4.643 0.31714E+05 -16.574 4 H2,gas 8.29 0.13 -8.16 -4.661 0.13928E+05 -6.157 5 H2S,gas -5.94 -22.75 -16.81 -8.405 0.28704E+05 -14.811 6 S2,gas -7.03 -45.77 -38.73 -5.959 0.66137E+05 -36.734 7 CO,gas 3.51 -14.15 -17.66 -5.435 0.30162E+05 -15.664 8 SO3,gas 17.43 -23.27 -40.70 -10.175 0.69494E+05 -38.700 9 SO2,gas 1.14 -23.14 -24.28 -6.474 0.41456E+05 -22.279 10 HCl,gas 5.48 -13.18 -18.66 -9.328 0.31853E+05 -16.655 11 acmite 7.74 6.31 -1.43 -0.148 0.24395E+04 15 albite-high 0.75 -0.76 -1.50 -0.116 0.25694E+04 16 albite -0.33 -0.76 -0.43 -0.033 0.72873E+03 19 spessartine 24.55 20.63 -3.92 -0.196 0.66970E+04 20 analcite 3.37 2.56 -0.81 -0.091 0.13913E+04 21 andalusite 5.06 1.78 -3.28 -0.328 0.56031E+04 22 andradite 39.09 34.70 -4.39 -0.228 0.74896E+04 26 annite 20.21 16.66 -3.55 -0.197 0.60616E+04 27 phlogopite 27.15 23.34 -3.80 -0.211 0.64938E+04 29 anorthite 12.80 9.15 -3.65 -0.281 0.62304E+04 35 aragonite 0.99 -3.60 -4.59 -1.530 0.78393E+04 36 brucite 12.58 8.59 -3.98 -0.797 0.68040E+04 37 calcite 0.83 -3.60 -4.44 -1.479 0.75780E+04 38 carnegieite-low 9.06 5.87 -3.20 -0.457 0.54602E+04 39 carnegieite-high 10.13 5.87 -4.27 -0.610 0.72871E+04 40 carpholite-Mg 8.65 7.06 -1.59 -0.106 0.27127E+04 41 carpholite-Fe 6.78 4.83 -1.95 -0.130 0.33283E+04 42 celadonite 5.40 2.85 -2.55 -0.150 0.43566E+04 43 celadonite-Fe 3.94 0.62 -3.32 -0.195 0.56619E+04 44 chrysotile 23.94 19.15 -4.78 -0.399 0.81685E+04 50 chloritoid-Mg 13.26 10.37 -2.89 -0.193 0.49323E+04 51 chloritoid-Fe 9.24 8.14 -1.09 -0.073 0.18682E+04 52 chloritoid-Mn 11.46 10.27 -1.19 -0.080 0.20366E+04 54 coesite -2.37 -3.31 -0.94 -0.314 0.16077E+04 59 corundum 8.43 5.09 -3.34 -0.304 0.57058E+04 61 cristobalite -2.55 -3.31 -0.76 -0.254 0.13006E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.55 -0.35 -0.058 0.59796E+03 67 diopside 16.22 12.65 -3.57 -0.357 0.60901E+04 68 hedenbergite 14.24 10.42 -3.82 -0.382 0.65289E+04 75 epidote 24.78 22.82 -1.96 -0.095 0.33461E+04 76 clinozoisite 22.92 19.06 -3.86 -0.175 0.65884E+04 77 epidote-Fe 29.94 26.57 -3.37 -0.175 0.57513E+04 78 fayalite 14.08 9.42 -4.66 -0.666 0.79611E+04 83 gibbsite 4.10 2.55 -1.55 -0.222 0.26491E+04 87 greenalite 16.19 12.47 -3.72 -0.310 0.63603E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.56 -1.70 -0.170 0.28944E+04 97 kalsilite 7.62 4.19 -3.43 -0.490 0.58570E+04 98 kaolinite -1.27 -1.53 -0.26 -0.023 0.43871E+03 99 kyanite 4.93 1.78 -3.15 -0.315 0.53799E+04 101 laumontite 2.97 2.53 -0.45 -0.030 0.76430E+03 102 lawsonite 9.68 9.15 -0.53 -0.035 0.90427E+03 103 leucite 4.17 0.88 -3.29 -0.329 0.56150E+04 105 lizardite 23.29 19.15 -4.13 -0.345 0.70588E+04 107 magnetite 20.13 18.96 -1.17 -0.096 0.20003E+04 108 minnesotaite 10.46 5.85 -4.61 -0.271 0.78772E+04 113 margarite 17.45 14.24 -3.21 -0.128 0.54831E+04 120 muscovite 2.68 2.66 -0.02 -0.001 0.32806E+02 122 nepheline 8.38 5.87 -2.51 -0.359 0.42882E+04 134 phlogopite-Na 29.73 25.02 -4.71 -0.262 0.80444E+04 136 prehnite 19.47 16.52 -2.95 -0.174 0.50364E+04 137 prehnite-Fe 22.59 20.27 -2.32 -0.139 0.39564E+04 138 pumpellyite-Fe 46.47 41.94 -4.53 -0.101 0.77307E+04 145 pyroxmangite 7.42 5.18 -2.24 -0.447 0.38203E+04 146 pyrophyllite -6.10 -8.15 -2.05 -0.128 0.35070E+04 147 quartz -2.98 -3.31 -0.33 -0.110 0.56164E+03 151 rhodochrosite -0.96 -5.79 -4.84 -1.612 0.82569E+04 152 rhodonite 7.46 5.18 -2.28 -0.457 0.38995E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.78 -3.54 -0.354 0.60453E+04 164 stilpnomelane-Fe 13.18 12.90 -0.28 -0.008 0.47639E+03 165 stilpnomelane-Mg 27.60 24.04 -3.56 -0.106 0.60712E+04 168 sudoite 21.22 17.43 -3.78 -0.122 0.64576E+04 171 talc 16.55 12.53 -4.02 -0.237 0.68672E+04 174 tephroite 18.11 13.67 -4.44 -0.635 0.75892E+04 177 topaz-H 4.67 1.78 -2.89 -0.262 0.49290E+04 178 tridymite -2.61 -3.31 -0.70 -0.232 0.11889E+04 187 wairakite 4.06 2.53 -1.53 -0.090 0.26151E+04 188 walstromite 11.53 7.37 -4.16 -0.832 0.71030E+04 189 wollastonite 10.48 7.37 -3.11 -0.623 0.53169E+04 190 pseudo-wollastonite 11.02 7.37 -3.65 -0.730 0.62355E+04 191 zoisite 22.96 19.06 -3.90 -0.177 0.66609E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.46 -2.90 -0.179 0.49474E+04 194 beidellite-H -2.24 -6.22 -3.98 -0.254 0.67925E+04 195 beidellite-K -1.44 -4.58 -3.15 -0.193 0.53768E+04 196 beidellite-Mg -1.71 -4.80 -3.09 -0.191 0.52840E+04 197 beidellite-Na -1.26 -4.03 -2.77 -0.170 0.47360E+04 199 chalcedony -2.79 -3.31 -0.52 -0.172 0.88195E+03 201 montmorillonite-Ca -2.21 -4.39 -2.18 -0.135 0.37236E+04 202 montmorillonite-K -2.16 -4.52 -2.36 -0.145 0.40307E+04 203 montmorillonite-Mg -2.40 -4.74 -2.34 -0.145 0.39913E+04 204 montmorillonite-Na -1.96 -3.97 -2.01 -0.123 0.34281E+04 205 nontronite-Ca 3.28 3.05 -0.23 -0.015 0.39440E+03 206 nontronite-H 2.60 1.29 -1.31 -0.088 0.22352E+04 207 nontronite-K 3.40 2.92 -0.48 -0.031 0.82296E+03 208 nontronite-Mg 3.14 2.70 -0.43 -0.028 0.74267E+03 209 nontronite-Na 3.58 3.48 -0.11 -0.007 0.18386E+03 224 tobermorite 9.84 5.58 -4.25 -1.161 0.72643E+04 233 boehmite 4.43 2.55 -1.88 -0.314 0.32164E+04 235 ferrous-oxide 9.82 6.36 -3.46 -0.865 0.59088E+04 240 silica-amorphous -2.08 -3.31 -1.23 -0.410 0.21021E+04 242 an20ab80 2.08 1.23 -0.85 -0.066 0.14574E+04 243 an25ab75 2.71 1.72 -0.99 -0.076 0.16875E+04 244 an30ab70 3.34 2.22 -1.13 -0.087 0.19260E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.9590000 g New total amount of reactant added: 1.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4574E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.9990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9996E+00 Moles total = 0.5548E+02 kg total = 0.9995E+00 Activity = 1.0000 Stoichiometric ionic strength = .1617837E-02 Osmotic coef. = 0.9772 True ionic strength = .2572087E-02 Chg. balance for total moles = 0.4574E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.55966E-09 -9.2521 0.51569E-09 -9.2876 0.92143E+00 -0.0355 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12696E-03 -3.8963 0.92048E+00 -0.0360 4 SO4-- 0.25499E-04 -4.5935 0.19357E-04 -4.7132 0.75912E+00 -0.1197 5 HCO3- 0.10730E-04 -4.9694 0.98793E-05 -5.0053 0.92071E+00 -0.0359 6 HS- 0.36900E-13 -13.4330 0.33966E-13 -13.4689 0.92051E+00 -0.0360 7 Al+++ 0.86355E-25 -25.0637 0.47393E-25 -25.3243 0.54882E+00 -0.2606 8 H4SiO4 0.49125E-03 -3.3087 0.49125E-03 -3.3087 0.10000E+01 0.0000 9 Ca++ 0.16707E-07 -7.7771 0.12667E-07 -7.8973 0.75819E+00 -0.1202 10 Mg++ 0.13761E-09 -9.8613 0.10426E-09 -9.9819 0.75760E+00 -0.1206 11 Fe++ 0.81383E-12 -12.0895 0.61667E-12 -12.2099 0.75774E+00 -0.1205 12 K+ 0.50581E-04 -4.2960 0.46572E-04 -4.3319 0.92075E+00 -0.0359 13 Na+ 0.24856E-02 -2.6046 0.22879E-02 -2.6406 0.92046E+00 -0.0360 14 Mn++ 0.10873E-09 -9.9636 0.82404E-10 -10.0841 0.75785E+00 -0.1204 15 HPO4-- 0.79823E-05 -5.0979 0.60597E-05 -5.2175 0.75914E+00 -0.1197 16 HSiO3- 0.10097E-02 -2.9958 0.92943E-03 -3.0318 0.92048E+00 -0.0360 17 Ca(HSiO3)+ 0.28648E-09 -9.5429 0.26379E-09 -9.5787 0.92079E+00 -0.0358 18 Mg(HSiO3)+ 0.29344E-11 -11.5325 0.27019E-11 -11.5683 0.92079E+00 -0.0358 19 NaHSiO3,aq 0.33773E-04 -4.4714 0.33773E-04 -4.4714 0.10000E+01 0.0000 20 AlO+ 0.24986E-13 -13.6023 0.23007E-13 -13.6381 0.92079E+00 -0.0358 21 AlOH+2 0.78410E-19 -19.1056 0.59433E-19 -19.2260 0.75797E+00 -0.1203 22 HAlO2,aq 0.89277E-08 -8.0493 0.89277E-08 -8.0493 0.10000E+01 0.0000 23 AlO2- 0.42008E-04 -4.3767 0.38656E-04 -4.4128 0.92020E+00 -0.0361 24 CH4,aq 0.17020E-19 -19.7691 0.17011E-19 -19.7693 0.99950E+00 -0.0002 29 CO,aq 0.13531E-18 -18.8687 0.13531E-18 -18.8687 0.10000E+01 0.0000 30 CO2,aq 0.10277E-07 -7.9881 0.10272E-07 -7.9884 0.99950E+00 -0.0002 31 CO3-2 0.23342E-05 -5.6319 0.17713E-05 -5.7517 0.75885E+00 -0.1198 32 CaCO3,aq 0.27481E-09 -9.5610 0.27481E-09 -9.5610 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.34245E-11 -11.4654 0.31533E-11 -11.5012 0.92079E+00 -0.0358 34 CaCl+ 0.27832E-11 -11.5554 0.25628E-11 -11.5913 0.92079E+00 -0.0358 35 CaCl2,aq 0.75760E-16 -16.1206 0.75760E-16 -16.1206 0.10000E+01 0.0000 36 CaOH+ 0.18811E-08 -8.7256 0.17321E-08 -8.7614 0.92079E+00 -0.0358 37 CaSO4,aq 0.76398E-10 -10.1169 0.76398E-10 -10.1169 0.10000E+01 0.0000 38 HCl,aq 0.12315E-13 -13.9096 0.12315E-13 -13.9096 0.10000E+01 0.0000 43 FeCl+ 0.13244E-15 -15.8780 0.12194E-15 -15.9138 0.92079E+00 -0.0358 46 FeO,aq 0.91699E-10 -10.0376 0.91699E-10 -10.0376 0.10000E+01 0.0000 47 FeOH+ 0.43055E-10 -10.3660 0.39645E-10 -10.4018 0.92079E+00 -0.0358 48 HFeO2- 0.20778E-08 -8.6824 0.19126E-08 -8.7184 0.92048E+00 -0.0360 49 FeO+ 0.46328E-14 -14.3342 0.42658E-14 -14.3700 0.92079E+00 -0.0358 51 FeO2- 0.34251E-08 -8.4653 0.31527E-08 -8.5013 0.92048E+00 -0.0360 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.51173E-09 -9.2910 0.51147E-09 -9.2912 0.99950E+00 -0.0002 54 KCl,aq 0.10470E-09 -9.9801 0.10470E-09 -9.9801 0.10000E+01 0.0000 55 KHSO4,aq 0.12440E-17 -17.9052 0.12440E-17 -17.9052 0.10000E+01 0.0000 56 KOH,aq 0.39371E-07 -7.4048 0.39371E-07 -7.4048 0.10000E+01 0.0000 57 KSO4- 0.15088E-07 -7.8214 0.13889E-07 -7.8573 0.92048E+00 -0.0360 58 MgCO3,aq 0.56517E-12 -12.2478 0.56517E-12 -12.2478 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28741E-13 -13.5415 0.26465E-13 -13.5773 0.92079E+00 -0.0358 60 MgCl+ 0.20796E-13 -13.6820 0.19148E-13 -13.7179 0.92079E+00 -0.0358 61 MgOH+ 0.85771E-10 -10.0667 0.78977E-10 -10.1025 0.92079E+00 -0.0358 63 MnO,aq 0.32711E-09 -9.4853 0.32711E-09 -9.4853 0.10000E+01 0.0000 64 MnOH+ 0.53446E-09 -9.2721 0.49212E-09 -9.3079 0.92079E+00 -0.0358 65 MnO2-2 0.56057E-13 -13.2514 0.42539E-13 -13.3712 0.75885E+00 -0.1198 66 HMnO2- 0.51634E-11 -11.2871 0.47528E-11 -11.3230 0.92048E+00 -0.0360 69 MnCl+ 0.68767E-13 -13.1626 0.63320E-13 -13.1985 0.92079E+00 -0.0358 70 MnSO4,aq 0.45204E-12 -12.3448 0.45204E-12 -12.3448 0.10000E+01 0.0000 71 NaCl,aq 0.94848E-07 -7.0230 0.94848E-07 -7.0230 0.10000E+01 0.0000 72 NaOH,aq 0.19495E-05 -5.7101 0.19495E-05 -5.7101 0.10000E+01 0.0000 74 OH- 0.12640E-02 -2.8982 0.11632E-02 -2.9344 0.92020E+00 -0.0361 79 HPO3-2 0.12901E-16 -16.8894 0.97895E-17 -17.0092 0.75885E+00 -0.1198 81 H2PO3- 0.10773E-19 -19.9677 0.99166E-20 -20.0036 0.92048E+00 -0.0360 82 H3PO4,aq 0.10375E-13 -13.9840 0.10375E-13 -13.9840 0.10000E+01 0.0000 83 H2PO4- 0.59509E-07 -7.2254 0.54786E-07 -7.2613 0.92063E+00 -0.0359 84 PO4-3 0.18543E-07 -7.7318 0.10262E-07 -7.9888 0.55343E+00 -0.2569 87 H2P2O7-2 0.30957E-15 -15.5092 0.23491E-15 -15.6291 0.75885E+00 -0.1198 88 HP2O7-3 0.17018E-12 -12.7691 0.93409E-13 -13.0296 0.54887E+00 -0.2605 89 P2O7-4 0.12746E-12 -12.8946 0.44686E-13 -13.3498 0.35059E+00 -0.4552 90 H2S,aq 0.52655E-16 -16.2786 0.52628E-16 -16.2788 0.99950E+00 -0.0002 97 SO3-2 0.17745E-14 -14.7509 0.13499E-14 -14.8697 0.76072E+00 -0.1188 98 HSO3- 0.44258E-16 -16.3540 0.40739E-16 -16.3900 0.92048E+00 -0.0360 99 HSO4- 0.10057E-10 -10.9975 0.92619E-11 -11.0333 0.92093E+00 -0.0358 Charge balance for all species = 0.4620E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5596600E-09 -.2479889E-02 -.2499034E+01 0.0000 2 H2O 0.1000000E+01 0.5550856E+02 0.9997850E+06 0.0000 3 Cl- 0.1379302E-03 0.1380252E-03 0.4892339E+01 5.3913 4 SO4-- 0.2549872E-04 0.2551423E-04 0.2450402E+01 13.8621 5 HCO3- 0.1073008E-04 0.1307483E-04 0.7976155E+00 4.2823 6 HS- 0.3689972E-13 -.3255965E-09 -.1076578E-04 -4.1813 7 Al+++ 0.8635504E-25 0.4201721E-04 0.1133440E+01 2.5386 8 H4SiO4 0.4912497E-03 0.1534742E-02 0.1474802E+03 -3.3087 9 Ca++ 0.1670731E-07 0.1923228E-07 0.7706232E-03 10.6779 10 Mg++ 0.1376139E-09 0.2269341E-09 0.5516018E-05 8.5933 11 Fe++ 0.8138266E-12 0.5841936E-08 0.3261834E-03 6.3653 12 K+ 0.5058070E-04 0.5063526E-04 0.1979508E+01 4.9557 13 Na+ 0.2485581E-02 0.2521398E-02 0.5795379E+02 6.6470 14 Mn++ 0.1087335E-09 0.9760419E-09 0.5361009E-04 8.4912 15 HPO4-- 0.7982321E-05 0.8060373E-05 0.7734577E+00 13.3577 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3308743E-01 -.2478972E-02 -.3060846E-01 0.0000000E+00 2 H2O 0.5548319E+02 0.5548804E+02 -.4848723E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8090357E-04 0.2550480E-04 0.5539878E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5539910E-04 -.3254762E-09 -.5539878E-04 0.0000000E+00 7 Al+++ 0.6518222E-02 0.4200168E-04 0.6476221E-02 0.0000000E+00 8 H4SiO4 0.2081515E-01 0.1534175E-02 0.1928098E-01 0.0000000E+00 9 Ca++ 0.2313606E-02 0.1922517E-07 0.2313587E-02 0.0000000E+00 10 Mg++ 0.1586508E-02 0.2268502E-09 0.1586508E-02 0.0000000E+00 11 Fe++ 0.1425304E-02 0.5839777E-08 0.1425298E-02 0.0000000E+00 12 K+ 0.4244161E-03 0.5061655E-04 0.3737996E-03 0.0000000E+00 13 Na+ 0.2669303E-02 0.2520466E-02 0.1488367E-03 0.0000000E+00 14 Mn++ 0.3465985E-04 0.9756812E-09 0.3465888E-04 0.0000000E+00 15 HPO4-- 0.1182924E-04 0.8057394E-05 0.3771841E-05 0.0000000E+00 Chg. balance for solid moles: -.2858E-17 Mass of aqueous solution: 0.999849E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1257E-05 -5.901 0.6316E-03 -3.200 0.2945E-01 0.2007E-03 clinochlore 0.3173E-03 -3.499 0.1764 -0.754 8.225 0.6708E-01 daphnite 0.1964E-03 -3.707 0.1401 -0.853 6.536 0.4247E-01 chlorite-Mn 0.6932E-05 -5.159 0.4914E-02 -2.309 0.2292 0.1566E-02 hematite 0.2216E-03 -3.654 0.3539E-01 -1.451 1.650 0.6707E-02 microcline 0.3738E-03 -3.427 0.1040 -0.983 4.852 0.4064E-01 paragonite 0.1488E-03 -3.827 0.5689E-01 -1.245 2.653 0.1966E-01 stilbite 0.2307E-02 -2.637 1.626 0.211 75.83 0.7584 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.144379 g Volume = 0.936729 cm3 Porosity: 47.9479% V(tot) - V(min): 0.86287E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.9990000 g log = 0.3008 Original solution: 1000.0103000 g Original solution / Rock added: 500.26 (Water/Rock Ratio), log = 2.6992 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1110E-05 1.0073 0.1176E-05 0.1167E-05 CH4,gas 0.2525E-16 1.0129 0.2690E-16 0.2656E-16 H2,gas 0.6665E-06 1.0006 0.7015E-06 0.7011E-06 H2S,gas 0.1465E-14 0.9959 0.1535E-14 0.1541E-14 S2,gas 0.1705E-36 1.0000 0.1793E-36 0.1793E-36 CO,gas 0.2031E-15 1.0000 0.2137E-15 0.2137E-15 SO3,gas 0.1829E-38 1.0000 0.1924E-38 0.1924E-38 SO2,gas 0.4855E-22 1.0000 0.5107E-22 0.5107E-22 HCl,gas 0.2067E-16 1.0000 0.2175E-16 0.2175E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.28814E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.29 -7.93 -2.643 0.13540E+05 -5.930 3 CH4,gas 4.81 -13.76 -18.57 -4.643 0.31708E+05 -16.570 4 H2,gas 8.29 0.13 -8.15 -4.659 0.13923E+05 -6.154 5 H2S,gas -5.94 -22.76 -16.81 -8.407 0.28709E+05 -14.814 6 S2,gas -7.03 -45.78 -38.75 -5.961 0.66158E+05 -36.746 7 CO,gas 3.51 -14.16 -17.67 -5.437 0.30172E+05 -15.670 8 SO3,gas 17.43 -23.29 -40.72 -10.179 0.69521E+05 -38.716 9 SO2,gas 1.14 -23.16 -24.29 -6.478 0.41478E+05 -22.292 10 HCl,gas 5.48 -13.18 -18.66 -9.331 0.31866E+05 -16.663 11 acmite 7.74 6.33 -1.41 -0.146 0.24057E+04 15 albite-high 0.75 -0.74 -1.49 -0.115 0.25443E+04 16 albite -0.33 -0.74 -0.41 -0.032 0.70369E+03 19 spessartine 24.55 20.62 -3.93 -0.196 0.67024E+04 20 analcite 3.37 2.57 -0.80 -0.089 0.13701E+04 21 andalusite 5.06 1.77 -3.29 -0.329 0.56243E+04 22 andradite 39.09 34.71 -4.38 -0.228 0.74830E+04 26 annite 20.21 16.66 -3.55 -0.197 0.60535E+04 27 phlogopite 27.15 23.35 -3.80 -0.211 0.64857E+04 29 anorthite 12.80 9.14 -3.66 -0.282 0.62494E+04 35 aragonite 0.99 -3.61 -4.60 -1.534 0.78564E+04 36 brucite 12.58 8.59 -3.98 -0.797 0.68013E+04 37 calcite 0.83 -3.61 -4.45 -1.483 0.75951E+04 38 carnegieite-low 9.06 5.88 -3.19 -0.455 0.54428E+04 39 carnegieite-high 10.13 5.88 -4.26 -0.608 0.72697E+04 40 carpholite-Mg 8.65 7.05 -1.60 -0.106 0.27274E+04 41 carpholite-Fe 6.78 4.82 -1.96 -0.131 0.33430E+04 42 celadonite 5.40 2.85 -2.55 -0.150 0.43501E+04 43 celadonite-Fe 3.94 0.62 -3.31 -0.195 0.56554E+04 44 chrysotile 23.94 19.16 -4.77 -0.398 0.81527E+04 50 chloritoid-Mg 13.26 10.36 -2.90 -0.193 0.49508E+04 51 chloritoid-Fe 9.24 8.13 -1.10 -0.074 0.18867E+04 52 chloritoid-Mn 11.46 10.26 -1.20 -0.080 0.20551E+04 54 coesite -2.37 -3.31 -0.94 -0.313 0.16039E+04 59 corundum 8.43 5.08 -3.36 -0.305 0.57308E+04 61 cristobalite -2.55 -3.31 -0.76 -0.253 0.12968E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.54 -0.36 -0.060 0.61047E+03 67 diopside 16.22 12.65 -3.56 -0.356 0.60814E+04 68 hedenbergite 14.24 10.43 -3.82 -0.382 0.65202E+04 75 epidote 24.78 22.81 -1.97 -0.095 0.33630E+04 76 clinozoisite 22.92 19.05 -3.88 -0.176 0.66177E+04 77 epidote-Fe 29.94 26.57 -3.37 -0.175 0.57557E+04 78 fayalite 14.08 9.42 -4.66 -0.665 0.79519E+04 83 gibbsite 4.10 2.54 -1.56 -0.223 0.26617E+04 87 greenalite 16.19 12.48 -3.72 -0.310 0.63446E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.57 -1.68 -0.168 0.28732E+04 97 kalsilite 7.62 4.19 -3.43 -0.491 0.58646E+04 98 kaolinite -1.27 -1.54 -0.27 -0.024 0.45613E+03 99 kyanite 4.93 1.77 -3.16 -0.316 0.54011E+04 101 laumontite 2.97 2.52 -0.45 -0.030 0.77572E+03 102 lawsonite 9.68 9.14 -0.54 -0.036 0.92330E+03 103 leucite 4.17 0.88 -3.29 -0.329 0.56188E+04 105 lizardite 23.29 19.16 -4.12 -0.344 0.70430E+04 107 magnetite 20.13 18.96 -1.17 -0.096 0.19975E+04 108 minnesotaite 10.46 5.86 -4.60 -0.271 0.78538E+04 113 margarite 17.45 14.21 -3.24 -0.129 0.55272E+04 120 muscovite 2.68 2.65 -0.03 -0.002 0.57839E+02 122 nepheline 8.38 5.88 -2.50 -0.357 0.42708E+04 134 phlogopite-Na 29.73 25.04 -4.69 -0.261 0.80112E+04 136 prehnite 19.47 16.51 -2.96 -0.174 0.50532E+04 137 prehnite-Fe 22.59 20.27 -2.32 -0.140 0.39608E+04 138 pumpellyite-Fe 46.47 41.92 -4.55 -0.101 0.77742E+04 145 pyroxmangite 7.42 5.18 -2.23 -0.447 0.38137E+04 146 pyrophyllite -6.10 -8.16 -2.06 -0.129 0.35168E+04 147 quartz -2.98 -3.31 -0.33 -0.109 0.55783E+03 151 rhodochrosite -0.96 -5.80 -4.84 -1.614 0.82696E+04 152 rhodonite 7.46 5.18 -2.28 -0.456 0.38930E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.77 -3.55 -0.355 0.60665E+04 164 stilpnomelane-Fe 13.18 12.91 -0.27 -0.008 0.45681E+03 165 stilpnomelane-Mg 27.60 24.05 -3.54 -0.106 0.60516E+04 168 sudoite 21.22 17.41 -3.80 -0.123 0.64908E+04 171 talc 16.55 12.55 -4.01 -0.236 0.68438E+04 174 tephroite 18.11 13.67 -4.44 -0.634 0.75799E+04 177 topaz-H 4.67 1.77 -2.90 -0.264 0.49502E+04 178 tridymite -2.61 -3.31 -0.69 -0.231 0.11851E+04 187 wairakite 4.06 2.52 -1.54 -0.090 0.26265E+04 188 walstromite 11.53 7.37 -4.16 -0.832 0.71008E+04 189 wollastonite 10.48 7.37 -3.11 -0.623 0.53147E+04 190 pseudo-wollastonite 11.02 7.37 -3.65 -0.730 0.62333E+04 191 zoisite 22.96 19.05 -3.92 -0.178 0.66903E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.47 -2.91 -0.180 0.49629E+04 194 beidellite-H -2.24 -6.23 -3.99 -0.254 0.68076E+04 195 beidellite-K -1.44 -4.59 -3.16 -0.193 0.53916E+04 196 beidellite-Mg -1.71 -4.81 -3.10 -0.192 0.52988E+04 197 beidellite-Na -1.26 -4.03 -2.78 -0.170 0.47426E+04 199 chalcedony -2.79 -3.31 -0.51 -0.171 0.87815E+03 201 montmorillonite-Ca -2.21 -4.40 -2.18 -0.135 0.37286E+04 202 montmorillonite-K -2.16 -4.52 -2.36 -0.145 0.40352E+04 203 montmorillonite-Mg -2.40 -4.74 -2.34 -0.145 0.39956E+04 204 montmorillonite-Na -1.96 -3.97 -2.01 -0.123 0.34243E+04 205 nontronite-Ca 3.28 3.05 -0.23 -0.015 0.38483E+03 206 nontronite-H 2.60 1.29 -1.30 -0.087 0.22254E+04 207 nontronite-K 3.40 2.93 -0.48 -0.031 0.81276E+03 208 nontronite-Mg 3.14 2.71 -0.43 -0.028 0.73238E+03 209 nontronite-Na 3.58 3.49 -0.10 -0.006 0.16540E+03 224 tobermorite 9.84 5.59 -4.25 -1.160 0.72619E+04 233 boehmite 4.43 2.54 -1.89 -0.315 0.32289E+04 235 ferrous-oxide 9.82 6.37 -3.46 -0.865 0.59060E+04 240 silica-amorphous -2.08 -3.31 -1.23 -0.410 0.20983E+04 242 an20ab80 2.08 1.24 -0.84 -0.065 0.14412E+04 243 an25ab75 2.71 1.73 -0.98 -0.075 0.16735E+04 244 an30ab70 3.34 2.22 -1.12 -0.086 0.19142E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.0400000 g Current total amount of reactant added: 1.9990000 g New total amount of reactant added: 2.0390000 g Mixing fraction reached given limit of 0.2000E+01 TOTMIX = 0.2039E+01 Execution stopped.