File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.13217E-01 0.11998E-08 0.9384 0.00000000E+00 H2O 2 0. 0.55498E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13795E-03 0.9379 0.00000000E+00 SO4-- 4 -2. 0.47647E-04 0.25487E-04 0.8173 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.11922E-04 0.9380 0.00000000E+00 HS- 6 -1. -0.22143E-04 0.52171E-13 0.9379 0.00000000E+00 Al+++ 7 3. 0.26053E-02 0.98133E-24 0.6487 0.00000000E+00 H4SiO4 8 0. 0.83198E-02 0.45880E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.93344E-03 0.71562E-07 0.8168 0.00000000E+00 Mg++ 10 2. 0.63413E-03 0.57252E-09 0.8165 0.00000000E+00 Fe++ 11 2. 0.56969E-03 0.33861E-11 0.8166 0.00000000E+00 K+ 12 1. 0.16964E-03 0.66866E-04 0.9380 0.00000000E+00 Na+ 13 1. 0.11630E-02 0.11559E-02 0.9379 0.00000000E+00 Mn++ 14 2. 0.13854E-04 0.45239E-09 0.8166 0.00000000E+00 HPO4-- 15 -2. 0.47281E-05 0.16418E-05 0.8173 0.00000000E+00 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 100.0000 SLIM = 0.400000E+01 TEMP = 100.0000 SINC = 0.1000E+00 TEMPC = 0.0000 TOTMIX = 0.799000E+00 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 1.3196 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0107 MnO2-2 65 -2. 40.4376 Ca(HSiO3)+ 17 1. 7.6603 HMnO2- 66 -1. 29.1018 Mg(HSiO3)+ 18 1. 7.5653 MnO4- 67 -1. 83.3383 NaHSiO3,aq 19 0. 7.8098 MnO4-2 68 -2. 81.3024 AlO+ 20 1. 6.8891 MnCl+ 69 1. -0.7819 AlOH+2 21 2. 3.1893 MnSO4,aq 70 0. -2.4524 HAlO2,aq 22 0. 10.5878 NaCl,aq 71 0. 0.4861 AlO2- 23 -1. 16.2390 NaOH,aq 72 0. 12.3571 CH4,aq 24 0. 6.0082 O2,aq 73 0. 53.5759 C2H6,aq 25 0. 12.3556 OH- 74 -1. 12.2220 C3H8,aq 26 0. 17.3423 HO2- 75 -1. 50.7897 C4H10,aq 27 0. 22.3397 H2O2,aq 76 0. 40.0297 ethanol,aq 28 0. 15.3114 H3PO2,aq 77 0. 24.3310 CO,aq 29 0. 4.7087 H2PO2- 78 -1. 26.5491 CO2,aq 30 0. -6.3045 HPO3-2 79 -2. 11.9246 CO3-2 31 -2. 10.0340 H3PO3,aq 80 0. 3.5932 CaCO3,aq 32 0. 5.9460 H2PO3- 81 -1. 5.6314 Ca(HCO3)+ 33 1. -1.4013 H3PO4,aq 82 0. -9.8087 CaCl+ 34 1. -0.2023 H2PO4- 83 -1. -7.2438 CaCl2,aq 35 0. 0.4306 PO4-3 84 -3. 12.0588 CaOH+ 36 1. 10.1517 H4P2O7,aq 85 0. -17.7539 CaSO4,aq 37 0. -2.4936 H3P2O7- 86 -1. -15.8646 HCl,aq 38 0. 0.7256 H2P2O7-2 87 -2. -13.3812 HClO,aq 39 0. 32.4377 HP2O7-3 88 -3. -6.6931 ClO- 40 -1. 39.6416 P2O7-4 89 -4. 2.9147 HClO2,aq 41 0. 70.2060 H2S,aq 90 0. -6.4778 Fe+3 42 3. 8.3763 S2-2 91 -2. 1.2336 FeCl+ 43 1. -0.1924 S3-2 92 -2. -8.7963 FeCl2,aq 44 0. 4.3160 S3- 93 -1. -16.3178 FeCl+2 45 2. 6.5223 S4-2 94 -2. -18.6473 FeO,aq 46 0. 16.4029 S5-2 95 -2. -28.3223 FeOH+ 47 1. 7.4795 SO2,aq 96 0. -0.1980 HFeO2- 48 -1. 24.3713 SO3-2 97 -2. 10.2895 FeO+ 49 1. 11.3812 HSO3- 98 -1. 2.5222 FeOH+2 50 2. 9.1115 HSO4- 99 -1. -2.9675 FeO2- 51 -1. 24.0877 HSO5- 100 -1. 38.8657 HFeO2,aq 52 0. 15.9903 S2O3-2 101 -2. -4.5491 H2,aq 53 0. 9.4241 HS2O3- 102 -1. -6.8007 KCl,aq 54 0. 1.7519 H2S2O3,aq 103 0. -7.9944 KHSO4,aq 55 0. -0.4275 S2O4-2 104 -2. 10.5639 KOH,aq 56 0. 12.3606 HS2O4- 105 -1. 7.6762 KSO4- 57 -1. -1.1877 H2S2O4,aq 106 0. 6.6566 MgCO3,aq 58 0. 6.5483 S2O5-2 107 -2. 10.0891 Mg(HCO3)+ 59 1. -1.4098 S2O6-2 108 -2. 11.5737 MgCl+ 60 1. -0.1603 S2O8-2 109 -2. 42.1139 MgOH+ 61 1. 9.4082 S3O6-2 110 -2. 3.8101 Mn+3 62 3. 19.1332 S4O6-2 111 -2. -17.8301 MnO,aq 63 0. 17.9765 S5O6-2 112 -2. -14.1051 MnOH+ 64 1. 8.5115 113 0. 10.3157 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.984 0.0000E+00 osumilite(2) 124 20.895 0.0000E+00 CO2,gas 2 -6.363 0.0000E+00 osumilite-Fe 125 14.657 0.0000E+00 CH4,gas 3 4.809 0.0000E+00 pargasite 126 65.279 0.0000E+00 H2,gas 4 8.287 0.0000E+00 periclase 127 16.149 0.0000E+00 H2S,gas 5 -5.943 0.0000E+00 periclase-Fe 128 11.639 0.0000E+00 S2,gas 6 -7.033 0.0000E+00 perovskite-Al 129 12.395 0.0000E+00 CO,gas 7 3.510 0.0000E+00 perovskite-Ca 130 23.818 0.0000E+00 SO3,gas 8 17.427 0.0000E+00 perovskite-Fe 131 21.158 0.0000E+00 SO2,gas 9 1.136 0.0000E+00 perovskite-Mg 132 23.132 0.0000E+00 HCl,gas 10 5.479 0.0000E+00 phase_A 133 80.267 0.0000E+00 acmite 11 7.737 0.0000E+00 phlogopite-Na 134 29.731 0.0000E+00 akermanite 12 36.495 0.0000E+00 piemontite(ordered) 135 33.876 0.0000E+00 akimotoite 13 16.606 0.0000E+00 prehnite 136 19.466 0.0000E+00 akimotoite-Fe 14 13.083 0.0000E+00 prehnite-Fe 137 22.587 0.0000E+00 albite-high 15 0.750 0.0000E+00 pumpellyite-Fe 138 46.471 0.0000E+00 albite 16 -0.328 0.0000E+00 pumpellyite-Mg 139 49.194 0.0000E+00 almandine 17 24.545 0.0000E+00 px-Mg-tschermaks 140 19.687 0.0000E+00 pyrope 18 37.348 0.0000E+00 px-Ca-tschermaks 141 18.679 0.0000E+00 spessartine 19 24.550 0.0000E+00 pyrite 142 -21.225 0.0000E+00 analcite 20 3.371 0.0000E+00 pyrrhotite 143 -4.244 0.0000E+00 andalusite 21 5.062 0.0000E+00 pyrrhotiteFe0.875 144 -6.001 0.0000E+00 andradite 22 39.088 0.0000E+00 pyroxmangite 145 7.416 0.0000E+00 grossular 23 32.828 0.0000E+00 pyrophyllite 146 -6.098 0.0000E+00 anhydrite 24 -5.280 0.0000E+00 quartz 147 -2.982 0.0000E+00 ankerite 25 -2.093 0.0000E+00 rankinite 148 40.765 0.0000E+00 annite 26 20.209 0.0000E+00 ringwoodite-Fe 149 15.486 0.0000E+00 phlogopite 27 27.147 0.0000E+00 ringwoodite-Mg 150 27.602 0.0000E+00 biotite-Mn 28 33.034 0.0000E+00 rhodochrosite 151 -0.959 0.0000E+00 anorthite 29 12.798 0.0000E+00 rhodonite 152 7.462 0.0000E+00 anthophyllite 30 51.988 0.0000E+00 sanidine 153 -1.221 0.0000E+00 anthophyllite-Fe 31 29.455 0.0000E+00 sapphirine(351) 154 79.204 0.0000E+00 apatite-OH 32 -17.989 0.1019E-05 siderite 155 -2.588 0.0000E+00 apatite-OH-zs 33 -12.572 0.0000E+00 sillimanite 156 5.321 0.0000E+00 apatite-Cl-zs 34 -16.504 0.0000E+00 sodalite 157 50.255 0.0000E+00 aragonite 35 0.986 0.0000E+00 spinel 158 20.934 0.0000E+00 brucite 36 12.577 0.0000E+00 spurrite 159 59.566 0.0000E+00 calcite 37 0.833 0.0000E+00 staurolite-Fe 160 74.138 0.0000E+00 carnegieite-low 38 9.065 0.0000E+00 staurolite-Mg 161 90.336 0.0000E+00 carnegieite-high 39 10.134 0.0000E+00 staurolite-Mn 162 84.438 0.0000E+00 carpholite-Mg 40 8.650 0.0000E+00 stilbite 163 -7.406 0.9283E-03 carpholite-Fe 41 6.783 0.0000E+00 stilpnomelane-Fe 164 13.179 0.0000E+00 celadonite 42 5.401 0.0000E+00 stilpnomelane-Mg 165 27.596 0.0000E+00 celadonite-Fe 43 3.937 0.0000E+00 stishovite 166 2.721 0.0000E+00 chrysotile 44 23.937 0.0000E+00 sudoite-Fe 167 18.437 0.0000E+00 chondrodite 45 56.542 0.0000E+00 sudoite 168 21.216 0.0000E+00 clinochlore 46 39.193 0.1268E-03 sulfur 169 -9.141 0.0000E+00 daphnite 47 29.094 0.7851E-04 sylvite 170 1.345 0.0000E+00 chlorite-Mn 48 46.985 0.2770E-05 talc 171 16.553 0.0000E+00 chlorite-Al-free 49 47.262 0.0000E+00 talc-Fe 172 13.516 0.0000E+00 chloritoid-Mg 50 13.261 0.0000E+00 talc-tschermaks 173 19.189 0.0000E+00 chloritoid-Fe 51 9.239 0.0000E+00 tephroite 174 18.113 0.0000E+00 chloritoid-Mn 52 11.463 0.0000E+00 tilleyite 175 41.473 0.0000E+00 clinohumite 53 97.255 0.0000E+00 titanite-CaSi 176 15.497 0.0000E+00 coesite 54 -2.369 0.0000E+00 topaz-H 177 4.668 0.0000E+00 cordierite-H 55 23.898 0.0000E+00 tridymite 178 -2.615 0.0000E+00 cordierite 56 24.245 0.0000E+00 tremolite 179 48.003 0.0000E+00 cordierite-Fe 57 20.649 0.0000E+00 ferroactinolite 180 38.596 0.0000E+00 cordierite-Mn 58 25.261 0.0000E+00 troilite-low 181 -4.394 0.0000E+00 corundum 59 8.433 0.0000E+00 tschermakite 182 48.414 0.0000E+00 corundum-MgSi 60 18.905 0.0000E+00 vesuvianite 183 224.056 0.0000E+00 cristobalite 61 -2.549 0.0000E+00 wadeite-Si 184 20.233 0.0000E+00 cummingtonite 62 52.233 0.0000E+00 wadsleyite-Fe 185 15.711 0.0000E+00 cymrite-K 63 1.731 0.0000E+00 wadsleyite-Mg 186 25.878 0.0000E+00 deerite 64 95.982 0.0000E+00 wairakite 187 4.058 0.0000E+00 diaspore 65 2.896 0.0000E+00 walstromite 188 11.528 0.0000E+00 diamond 66 -3.107 0.0000E+00 wollastonite 189 10.482 0.0000E+00 diopside 67 16.215 0.0000E+00 pseudo-wollastonite 190 11.020 0.0000E+00 hedenbergite 68 14.244 0.0000E+00 zoisite 191 22.964 0.0000E+00 dolomite,ordered 69 0.587 0.0000E+00 akaganeite 192 7.768 0.0000E+00 eastonite 70 28.605 0.0000E+00 beidellite-Ca 193 -1.560 0.0000E+00 enstatite 71 17.301 0.0000E+00 beidellite-H 194 -2.241 0.0000E+00 clinoenstatite-HiP 72 18.388 0.0000E+00 beidellite-K 195 -1.435 0.0000E+00 clinoenstatite 73 17.202 0.0000E+00 beidellite-Mg 196 -1.707 0.0000E+00 protoenstatite 74 17.860 0.0000E+00 beidellite-Na 197 -1.257 0.0000E+00 epidote 75 24.775 0.0000E+00 calcium 198 84.043 0.0000E+00 clinozoisite 76 22.921 0.0000E+00 chalcedony 199 -2.794 0.0000E+00 epidote-Fe 77 29.937 0.0000E+00 dawsonite 200 1.714 0.0000E+00 fayalite 78 14.079 0.0000E+00 montmorillonite-Ca 201 -2.214 0.0000E+00 ferrosilite 79 11.188 0.0000E+00 montmorillonite-K 202 -2.161 0.0000E+00 forsterite 80 21.047 0.0000E+00 montmorillonite-Mg 203 -2.402 0.0000E+00 gedrite 81 50.725 0.0000E+00 montmorillonite-Na 204 -1.961 0.0000E+00 gehlenite 82 36.717 0.0000E+00 nontronite-Ca 205 3.280 0.0000E+00 gibbsite 83 4.097 0.0000E+00 nontronite-H 206 2.596 0.0000E+00 glaucophane 84 23.111 0.0000E+00 nontronite-K 207 3.404 0.0000E+00 glaucophane-Fe 85 17.417 0.0000E+00 nontronite-Mg 208 3.139 0.0000E+00 graphite 86 -3.549 0.0000E+00 nontronite-Na 209 3.583 0.0000E+00 greenalite 87 16.194 0.0000E+00 sepiolite 210 24.194 0.0000E+00 grunerite 88 31.364 0.0000E+00 alite 211 58.043 0.0000E+00 halite 89 1.582 0.0000E+00 belite 212 30.461 0.0000E+00 hematite 90 12.598 0.8857E-04 ettringite 213 43.354 0.0000E+00 heulandite 91 -5.707 0.0000E+00 gypsum 214 -4.924 0.0000E+00 hercynite 92 17.345 0.0000E+00 hemicarboaluminate 215 71.028 0.0000E+00 hollandite 93 25.702 0.0000E+00 hydrogarnet 216 60.721 0.0000E+00 iron 94 19.095 0.0000E+00 hydrogarnet-Si 217 50.654 0.0000E+00 jadeite 95 4.251 0.0000E+00 jennite 218 24.386 0.0000E+00 julgoldite 96 70.573 0.0000E+00 monosulfoaluminate 219 53.497 0.0000E+00 kalsilite 97 7.620 0.0000E+00 monocarboaluminate 220 61.966 0.0000E+00 kaolinite 98 -1.273 0.0000E+00 portlandite 221 18.282 0.0000E+00 kyanite 99 4.932 0.0000E+00 stratlingite 222 36.573 0.0000E+00 larnite-bredigite 100 30.714 0.0000E+00 tricarboaluminate 223 70.427 0.0000E+00 laumontite 101 2.975 0.0000E+00 tobermorite 224 9.839 0.0000E+00 lawsonite 102 9.678 0.0000E+00 C4AH13 225 81.870 0.0000E+00 leucite 103 4.168 0.0000E+00 C2AH8 226 45.260 0.0000E+00 lime 104 26.009 0.0000E+00 C3A 227 87.049 0.0000E+00 lizardite 105 23.287 0.0000E+00 C4AF 228 117.550 0.0000E+00 magnesite 106 0.709 0.0000E+00 CAH10 229 28.373 0.0000E+00 magnetite 107 20.133 0.0000E+00 alabandite 230 -0.962 0.0000E+00 minnesotaite 108 10.461 0.0000E+00 alunite 231 -10.224 0.0000E+00 minnesotaite-Mg 109 20.669 0.0000E+00 artinite 232 15.139 0.0000E+00 magnesioferrite 110 26.257 0.0000E+00 boehmite 233 4.430 0.0000E+00 majorite 111 53.314 0.0000E+00 dolomite,disordered 234 1.288 0.0000E+00 manganosite 112 14.068 0.0000E+00 ferrous-oxide 235 9.824 0.0000E+00 margarite 113 17.452 0.0000E+00 huntite 236 3.850 0.0000E+00 meionite 114 45.158 0.0000E+00 hydromagnesite 237 20.077 0.0000E+00 merwinite 115 55.988 0.0000E+00 nesquehonite 238 4.735 0.0000E+00 microcline 116 -2.432 0.0000E+00 potassium-oxide 239 69.039 0.0000E+00 monticellite 117 24.371 0.0000E+00 silica-amorphous 240 -2.080 0.0000E+00 mullite-Al 118 363.258 0.0000E+00 sodium-oxide 241 55.173 0.0000E+00 mullite-Si 119 7.324 0.0000E+00 an20ab80 242 2.079 0.0000E+00 muscovite 120 2.679 0.1027E-03 an25ab75 243 2.709 0.0000E+00 paragonite 121 4.337 0.0000E+00 an30ab70 244 3.344 0.0000E+00 nepheline 122 8.378 0.0000E+00 tr.625ac.25prg.125 245 45.308 0.0000E+00 osumilite(1) 123 21.978 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 0.7990000 g log = -0.0975 Original solution: 1000.0103000 g Original solution / Rock added: 1251.58 (Water/Rock Ratio), log = 3.0975 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.7990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .8548490E-03 Osmotic coef. = 0.9830 True ionic strength = .1251229E-02 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11998E-08 -8.9209 0.11258E-08 -8.9485 0.93838E+00 -0.0276 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12938E-03 -3.8881 0.93789E+00 -0.0278 4 SO4-- 0.25487E-04 -4.5937 0.20831E-04 -4.6813 0.81732E+00 -0.0876 5 HCO3- 0.11922E-04 -4.9236 0.11183E-04 -4.9514 0.93801E+00 -0.0278 6 HS- 0.52171E-13 -13.2826 0.48931E-13 -13.3104 0.93790E+00 -0.0278 7 Al+++ 0.98133E-24 -24.0082 0.63664E-24 -24.1961 0.64875E+00 -0.1879 8 H4SiO4 0.45880E-03 -3.3384 0.45880E-03 -3.3384 0.10000E+01 0.0000 9 Ca++ 0.71562E-07 -7.1453 0.58452E-07 -7.2332 0.81680E+00 -0.0879 10 Mg++ 0.57252E-09 -9.2422 0.46745E-09 -9.3303 0.81648E+00 -0.0881 11 Fe++ 0.33861E-11 -11.4703 0.27649E-11 -11.5583 0.81656E+00 -0.0880 12 K+ 0.66866E-04 -4.1748 0.62722E-04 -4.2026 0.93803E+00 -0.0278 13 Na+ 0.11559E-02 -2.9371 0.10841E-02 -2.9649 0.93788E+00 -0.0279 14 Mn++ 0.45239E-09 -9.3445 0.36943E-09 -9.4325 0.81661E+00 -0.0880 15 HPO4-- 0.16418E-05 -5.7847 0.13419E-05 -5.8723 0.81733E+00 -0.0876 16 HSiO3- 0.42393E-03 -3.3727 0.39760E-03 -3.4006 0.93789E+00 -0.0278 17 Ca(HSiO3)+ 0.55510E-09 -9.2556 0.52071E-09 -9.2834 0.93805E+00 -0.0278 18 Mg(HSiO3)+ 0.55247E-11 -11.2577 0.51824E-11 -11.2855 0.93805E+00 -0.0278 19 NaHSiO3,aq 0.68459E-05 -5.1646 0.68459E-05 -5.1646 0.10000E+01 0.0000 20 AlO+ 0.69123E-13 -13.1604 0.64841E-13 -13.1882 0.93805E+00 -0.0278 21 AlOH+2 0.44777E-18 -18.3489 0.36569E-18 -18.4369 0.81668E+00 -0.0879 22 HAlO2,aq 0.11525E-07 -7.9384 0.11525E-07 -7.9384 0.10000E+01 0.0000 23 AlO2- 0.24375E-04 -4.6131 0.22857E-04 -4.6410 0.93774E+00 -0.0279 24 CH4,aq 0.25783E-19 -19.5887 0.25777E-19 -19.5888 0.99973E+00 -0.0001 29 CO,aq 0.29591E-18 -18.5288 0.29591E-18 -18.5288 0.10000E+01 0.0000 30 CO2,aq 0.25391E-07 -7.5953 0.25385E-07 -7.5954 0.99973E+00 -0.0001 31 CO3-2 0.11239E-05 -5.9493 0.91840E-06 -6.0370 0.81716E+00 -0.0877 32 CaCO3,aq 0.65748E-09 -9.1821 0.65748E-09 -9.1821 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.17558E-10 -10.7555 0.16471E-10 -10.7833 0.93805E+00 -0.0278 34 CaCl+ 0.12847E-10 -10.8912 0.12051E-10 -10.9190 0.93805E+00 -0.0278 35 CaCl2,aq 0.36304E-15 -15.4401 0.36304E-15 -15.4401 0.10000E+01 0.0000 36 CaOH+ 0.39027E-08 -8.4086 0.36609E-08 -8.4364 0.93805E+00 -0.0278 37 CaSO4,aq 0.37937E-09 -9.4209 0.37937E-09 -9.4209 0.10000E+01 0.0000 38 HCl,aq 0.27399E-13 -13.5623 0.27399E-13 -13.5623 0.10000E+01 0.0000 43 FeCl+ 0.59397E-15 -15.2262 0.55717E-15 -15.2540 0.93805E+00 -0.0278 46 FeO,aq 0.86260E-10 -10.0642 0.86260E-10 -10.0642 0.10000E+01 0.0000 47 FeOH+ 0.86795E-10 -10.0615 0.81418E-10 -10.0893 0.93805E+00 -0.0278 48 HFeO2- 0.87868E-09 -9.0562 0.82410E-09 -9.0840 0.93789E+00 -0.0278 49 FeO+ 0.99282E-14 -14.0031 0.93131E-14 -14.0309 0.93805E+00 -0.0278 51 FeO2- 0.15397E-08 -8.8126 0.14441E-08 -8.8404 0.93789E+00 -0.0278 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.45272E-09 -9.3442 0.45260E-09 -9.3443 0.99973E+00 -0.0001 54 KCl,aq 0.14369E-09 -9.8426 0.14369E-09 -9.8426 0.10000E+01 0.0000 55 KHSO4,aq 0.39363E-17 -17.4049 0.39363E-17 -17.4049 0.10000E+01 0.0000 56 KOH,aq 0.24287E-07 -7.6146 0.24287E-07 -7.6146 0.10000E+01 0.0000 57 KSO4- 0.21462E-07 -7.6683 0.20129E-07 -7.6962 0.93789E+00 -0.0278 58 MgCO3,aq 0.13139E-11 -11.8815 0.13139E-11 -11.8815 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14319E-12 -12.8441 0.13432E-12 -12.8719 0.93805E+00 -0.0278 60 MgCl+ 0.93268E-13 -13.0303 0.87490E-13 -13.0580 0.93805E+00 -0.0278 61 MgOH+ 0.17291E-09 -9.7622 0.16220E-09 -9.7900 0.93805E+00 -0.0278 63 MnO,aq 0.30767E-09 -9.5119 0.30767E-09 -9.5119 0.10000E+01 0.0000 64 MnOH+ 0.10773E-08 -8.9677 0.10106E-08 -8.9954 0.93805E+00 -0.0278 65 MnO2-2 0.10273E-13 -13.9883 0.83946E-14 -14.0760 0.81716E+00 -0.0877 66 HMnO2- 0.21833E-11 -11.6609 0.20477E-11 -11.6887 0.93789E+00 -0.0278 69 MnCl+ 0.30839E-12 -12.5109 0.28928E-12 -12.5387 0.93805E+00 -0.0278 70 MnSO4,aq 0.21809E-11 -11.6614 0.21809E-11 -11.6614 0.10000E+01 0.0000 71 NaCl,aq 0.45799E-07 -7.3391 0.45799E-07 -7.3391 0.10000E+01 0.0000 72 NaOH,aq 0.42311E-06 -6.3736 0.42311E-06 -6.3736 0.10000E+01 0.0000 74 OH- 0.56816E-03 -3.2455 0.53279E-03 -3.2734 0.93774E+00 -0.0279 79 HPO3-2 0.23475E-17 -17.6294 0.19183E-17 -17.7171 0.81716E+00 -0.0877 82 H3PO4,aq 0.10950E-13 -13.9606 0.10950E-13 -13.9606 0.10000E+01 0.0000 83 H2PO4- 0.28238E-07 -7.5492 0.26487E-07 -7.5770 0.93797E+00 -0.0278 84 PO4-3 0.15976E-08 -8.7965 0.10409E-08 -8.9826 0.65153E+00 -0.1861 87 H2P2O7-2 0.67192E-16 -16.1727 0.54907E-16 -16.2604 0.81716E+00 -0.0877 88 HP2O7-3 0.15414E-13 -13.8121 0.10000E-13 -14.0000 0.64878E+00 -0.1879 89 P2O7-4 0.46530E-14 -14.3323 0.21913E-14 -14.6593 0.47094E+00 -0.3270 90 H2S,aq 0.16556E-15 -15.7810 0.16552E-15 -15.7812 0.99973E+00 -0.0001 97 SO3-2 0.15711E-14 -14.8038 0.12855E-14 -14.8909 0.81820E+00 -0.0871 98 HSO3- 0.90305E-16 -16.0443 0.84697E-16 -16.0721 0.93789E+00 -0.0278 99 HSO4- 0.23196E-10 -10.6346 0.21760E-10 -10.6623 0.93812E+00 -0.0277 Charge balance for all species = 0.4567E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1199771E-08 -.1098003E-02 -.1106584E+01 0.0000 2 H2O 0.1000000E+01 0.5550844E+02 0.9998773E+06 0.0000 3 Cl- 0.1379502E-03 0.1379962E-03 0.4891772E+01 5.0604 4 SO4-- 0.2548667E-04 0.2550864E-04 0.2450097E+01 13.2157 5 HCO3- 0.1192212E-04 0.1307208E-04 0.7975231E+00 3.9971 6 HS- 0.5217058E-13 -.1046662E-09 -.3461093E-05 -4.3619 7 Al+++ 0.9813279E-24 0.2438628E-04 0.6578970E+00 2.6495 8 H4SiO4 0.4588038E-03 0.8895832E-03 0.8549206E+02 -3.3384 9 Ca++ 0.7156184E-07 0.7708688E-07 0.3089106E-02 10.6638 10 Mg++ 0.5725183E-09 0.7525007E-09 0.1829253E-04 8.5668 11 Fe++ 0.3386087E-11 0.2798312E-08 0.1562580E-03 6.3387 12 K+ 0.6686612E-04 0.6691201E-04 0.2616069E+01 4.7459 13 Na+ 0.1155881E-02 0.1163196E-02 0.2673833E+02 5.9836 14 Mn++ 0.4523915E-09 0.1842066E-08 0.1011869E-03 8.4646 15 HPO4-- 0.1641809E-05 0.1671645E-05 0.1604229E+00 12.0248 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1321721E-01 -.1097828E-02 -.1211939E-01 0.0000000E+00 2 H2O 0.5549823E+02 0.5549959E+02 -.1357997E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4764748E-04 0.2550457E-04 0.2214291E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2214301E-04 -.1046495E-09 -.2214291E-04 0.0000000E+00 7 Al+++ 0.2605333E-02 0.2438240E-04 0.2580950E-02 0.0000000E+00 8 H4SiO4 0.8319814E-02 0.8894415E-03 0.7430372E-02 0.0000000E+00 9 Ca++ 0.9334350E-03 0.7707460E-07 0.9333580E-03 0.0000000E+00 10 Mg++ 0.6341270E-03 0.7523808E-09 0.6341262E-03 0.0000000E+00 11 Fe++ 0.5696939E-03 0.2797866E-08 0.5696911E-03 0.0000000E+00 12 K+ 0.1696391E-03 0.6690135E-04 0.1027377E-03 0.0000000E+00 13 Na+ 0.1163011E-02 0.1163011E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1385354E-04 0.1841772E-08 0.1385170E-04 0.0000000E+00 15 HPO4-- 0.4728144E-05 0.1671378E-05 0.3056765E-05 0.0000000E+00 Chg. balance for solid moles: 0.4896E-18 Mass of aqueous solution: 0.999965E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1019E-05 -5.992 0.5118E-03 -3.291 0.6106E-01 0.1626E-03 clinochlore 0.1268E-03 -3.897 0.7049E-01 -1.152 8.410 0.2681E-01 daphnite 0.7851E-04 -4.105 0.5602E-01 -1.252 6.683 0.1697E-01 chlorite-Mn 0.2770E-05 -5.557 0.1964E-02 -2.707 0.2343 0.6259E-03 hematite 0.8857E-04 -4.053 0.1414E-01 -1.849 1.687 0.2681E-02 muscovite 0.1027E-03 -3.988 0.4092E-01 -1.388 4.882 0.1447E-01 stilbite 0.9283E-03 -3.032 0.6542 -0.184 78.04 0.3051 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.838219 g Volume = 0.366843 cm3 Porosity: 72.2004% V(tot) - V(min): 0.95276E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.7990000 g log = -0.0975 Original solution: 1000.0103000 g Original solution / Rock added: 1251.58 (Water/Rock Ratio), log = 3.0975 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2742E-05 1.0073 0.2906E-05 0.2885E-05 CH4,gas 0.3826E-16 1.0129 0.4076E-16 0.4024E-16 H2,gas 0.5898E-06 1.0006 0.6208E-06 0.6204E-06 H2S,gas 0.4608E-14 0.9959 0.4827E-14 0.4847E-14 S2,gas 0.2153E-35 1.0000 0.2265E-35 0.2265E-35 CO,gas 0.4442E-15 1.0000 0.4672E-15 0.4672E-15 SO3,gas 0.9384E-38 1.0000 0.9871E-38 0.9871E-38 SO2,gas 0.2204E-21 1.0000 0.2318E-21 0.2318E-21 HCl,gas 0.4599E-16 1.0000 0.4838E-16 0.4838E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.90 -7.54 -2.512 0.12869E+05 -5.537 3 CH4,gas 4.81 -13.58 -18.39 -4.597 0.31400E+05 -16.390 4 H2,gas 8.29 0.08 -8.21 -4.690 0.14013E+05 -6.207 5 H2S,gas -5.94 -22.26 -16.32 -8.158 0.27860E+05 -14.316 6 S2,gas -7.03 -44.68 -37.64 -5.792 0.64278E+05 -35.645 7 CO,gas 3.51 -13.82 -17.33 -5.332 0.29591E+05 -15.330 8 SO3,gas 17.43 -22.58 -40.01 -10.001 0.68309E+05 -38.006 9 SO2,gas 1.14 -22.50 -23.63 -6.303 0.40356E+05 -21.635 10 HCl,gas 5.48 -12.84 -18.32 -9.158 0.31273E+05 -16.315 11 acmite 7.74 5.61 -2.13 -0.221 0.36399E+04 15 albite-high 0.75 -1.38 -2.13 -0.164 0.36399E+04 16 albite -0.33 -1.38 -1.05 -0.081 0.17992E+04 19 spessartine 24.55 20.68 -3.87 -0.194 0.66120E+04 20 analcite 3.37 1.96 -1.41 -0.157 0.24150E+04 21 andalusite 5.06 1.96 -3.10 -0.310 0.52963E+04 22 andradite 39.09 34.57 -4.51 -0.234 0.77070E+04 26 annite 20.21 16.40 -3.81 -0.212 0.65104E+04 27 phlogopite 27.15 23.08 -4.07 -0.226 0.69425E+04 29 anorthite 12.80 9.29 -3.51 -0.270 0.59961E+04 35 aragonite 0.99 -3.24 -4.22 -1.407 0.72095E+04 36 brucite 12.58 8.57 -4.01 -0.802 0.68467E+04 37 calcite 0.83 -3.24 -4.07 -1.356 0.69482E+04 38 carnegieite-low 9.06 5.29 -3.77 -0.539 0.64370E+04 39 carnegieite-high 10.13 5.29 -4.84 -0.691 0.82638E+04 40 carpholite-Mg 8.65 7.19 -1.46 -0.097 0.24954E+04 41 carpholite-Fe 6.78 4.96 -1.82 -0.121 0.31110E+04 42 celadonite 5.40 2.61 -2.79 -0.164 0.47670E+04 43 celadonite-Fe 3.94 0.38 -3.56 -0.209 0.60723E+04 44 chrysotile 23.94 19.02 -4.91 -0.409 0.83901E+04 50 chloritoid-Mg 13.26 10.53 -2.73 -0.182 0.46681E+04 51 chloritoid-Fe 9.24 8.30 -0.94 -0.063 0.16040E+04 52 chloritoid-Mn 11.46 10.43 -1.04 -0.069 0.17725E+04 54 coesite -2.37 -3.34 -0.97 -0.323 0.16546E+04 59 corundum 8.43 5.30 -3.13 -0.285 0.53521E+04 61 cristobalite -2.55 -3.34 -0.79 -0.263 0.13475E+04 63 cymrite-K 1.73 -2.62 -4.35 -0.363 0.74283E+04 65 diaspore 2.90 2.65 -0.25 -0.041 0.42112E+03 67 diopside 16.22 12.55 -3.66 -0.366 0.62521E+04 68 hedenbergite 14.24 10.33 -3.92 -0.392 0.66909E+04 75 epidote 24.78 22.91 -1.86 -0.090 0.31843E+04 76 clinozoisite 22.92 19.26 -3.66 -0.166 0.62497E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.175 0.57664E+04 78 fayalite 14.08 9.34 -4.74 -0.677 0.80932E+04 83 gibbsite 4.10 2.65 -1.45 -0.207 0.24723E+04 87 greenalite 16.19 12.34 -3.85 -0.321 0.65819E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 1.96 -2.29 -0.229 0.39180E+04 97 kalsilite 7.62 4.06 -3.56 -0.509 0.60841E+04 98 kaolinite -1.27 -1.38 -0.10 -0.010 0.17876E+03 99 kyanite 4.93 1.96 -2.97 -0.297 0.50731E+04 101 laumontite 2.97 2.61 -0.37 -0.024 0.62371E+03 102 lawsonite 9.68 9.29 -0.39 -0.026 0.66995E+03 103 leucite 4.17 0.72 -3.45 -0.345 0.58890E+04 105 lizardite 23.29 19.02 -4.26 -0.355 0.72804E+04 107 magnetite 20.13 18.94 -1.20 -0.098 0.20429E+04 108 minnesotaite 10.46 5.66 -4.80 -0.282 0.81925E+04 113 margarite 17.45 14.58 -2.87 -0.115 0.48951E+04 116 microcline -2.43 -2.62 -0.19 -0.014 0.32087E+03 121 paragonite 4.34 3.92 -0.42 -0.025 0.71679E+03 122 nepheline 8.38 5.29 -3.08 -0.440 0.52649E+04 136 prehnite 19.47 16.61 -2.85 -0.168 0.48746E+04 137 prehnite-Fe 22.59 20.26 -2.33 -0.140 0.39715E+04 138 pumpellyite-Fe 46.47 42.21 -4.26 -0.095 0.72728E+04 139 pumpellyite-Mg 49.19 44.44 -4.75 -0.106 0.81188E+04 145 pyroxmangite 7.42 5.13 -2.29 -0.458 0.39098E+04 146 pyrophyllite -6.10 -8.05 -1.96 -0.122 0.33408E+04 147 quartz -2.98 -3.34 -0.36 -0.119 0.60850E+03 151 rhodochrosite -0.96 -5.44 -4.48 -1.492 0.76441E+04 152 rhodonite 7.46 5.13 -2.34 -0.467 0.39891E+04 153 sanidine -1.22 -2.62 -1.40 -0.108 0.23886E+04 155 siderite -2.59 -7.56 -4.97 -1.658 0.84922E+04 156 sillimanite 5.32 1.96 -3.36 -0.336 0.57385E+04 164 stilpnomelane-Fe 13.18 12.66 -0.52 -0.016 0.88927E+03 165 stilpnomelane-Mg 27.60 23.80 -3.80 -0.113 0.64841E+04 168 sudoite 21.22 17.72 -3.50 -0.113 0.59760E+04 171 talc 16.55 12.35 -4.21 -0.247 0.71825E+04 174 tephroite 18.11 13.59 -4.52 -0.646 0.77214E+04 177 topaz-H 4.67 1.96 -2.71 -0.246 0.46222E+04 178 tridymite -2.61 -3.34 -0.72 -0.241 0.12358E+04 187 wairakite 4.06 2.61 -1.45 -0.085 0.24745E+04 188 walstromite 11.53 7.33 -4.20 -0.840 0.71755E+04 189 wollastonite 10.48 7.33 -3.16 -0.631 0.53894E+04 190 pseudo-wollastonite 11.02 7.33 -3.69 -0.739 0.63080E+04 191 zoisite 22.96 19.26 -3.70 -0.168 0.63223E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.32 -2.76 -0.171 0.47116E+04 194 beidellite-H -2.24 -6.08 -3.84 -0.245 0.65524E+04 195 beidellite-K -1.44 -4.51 -3.08 -0.188 0.52546E+04 196 beidellite-Mg -1.71 -4.67 -2.96 -0.183 0.50510E+04 197 beidellite-Na -1.26 -4.10 -2.85 -0.174 0.48612E+04 199 chalcedony -2.79 -3.34 -0.54 -0.181 0.92882E+03 201 montmorillonite-Ca -2.21 -4.34 -2.13 -0.132 0.36340E+04 202 montmorillonite-K -2.16 -4.54 -2.37 -0.145 0.40548E+04 203 montmorillonite-Mg -2.40 -4.69 -2.29 -0.141 0.39045E+04 204 montmorillonite-Na -1.96 -4.13 -2.17 -0.133 0.36995E+04 205 nontronite-Ca 3.28 2.98 -0.30 -0.019 0.51226E+03 206 nontronite-H 2.60 1.22 -1.38 -0.092 0.23488E+04 207 nontronite-K 3.40 2.79 -0.62 -0.040 0.10544E+04 208 nontronite-Mg 3.14 2.63 -0.51 -0.033 0.86334E+03 209 nontronite-Na 3.58 3.19 -0.39 -0.025 0.66271E+03 224 tobermorite 9.84 5.54 -4.29 -1.172 0.73326E+04 233 boehmite 4.43 2.65 -1.78 -0.297 0.30396E+04 235 ferrous-oxide 9.82 6.34 -3.49 -0.871 0.59514E+04 240 silica-amorphous -2.08 -3.34 -1.26 -0.420 0.21490E+04 242 an20ab80 2.08 0.75 -1.33 -0.102 0.22670E+04 243 an25ab75 2.71 1.28 -1.42 -0.110 0.24318E+04 244 an30ab70 3.34 1.82 -1.53 -0.117 0.26050E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 0.7990000 g New total amount of reactant added: 0.8990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4566E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.8990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .9194339E-03 Osmotic coef. = 0.9824 True ionic strength = .1382906E-02 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10987E-08 -8.9591 0.10287E-08 -8.9877 0.93632E+00 -0.0286 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12909E-03 -3.8891 0.93578E+00 -0.0288 4 SO4-- 0.25485E-04 -4.5937 0.20645E-04 -4.6852 0.81006E+00 -0.0915 5 HCO3- 0.11821E-04 -4.9273 0.11063E-04 -4.9561 0.93591E+00 -0.0288 6 HS- 0.51872E-13 -13.2851 0.48542E-13 -13.3139 0.93579E+00 -0.0288 7 Al+++ 0.67055E-24 -24.1736 0.42634E-24 -24.3702 0.63580E+00 -0.1967 8 H4SiO4 0.49101E-03 -3.3089 0.49101E-03 -3.3089 0.10000E+01 0.0000 9 Ca++ 0.48654E-07 -7.3129 0.39386E-07 -7.4047 0.80951E+00 -0.0918 10 Mg++ 0.48784E-09 -9.3117 0.39474E-09 -9.4037 0.80915E+00 -0.0920 11 Fe++ 0.28852E-11 -11.5398 0.23348E-11 -11.6317 0.80924E+00 -0.0919 12 K+ 0.73845E-04 -4.1317 0.69114E-04 -4.1604 0.93593E+00 -0.0288 13 Na+ 0.12793E-02 -2.8930 0.11972E-02 -2.9218 0.93577E+00 -0.0288 14 Mn++ 0.38548E-09 -9.4140 0.31197E-09 -9.5059 0.80930E+00 -0.0919 15 HPO4-- 0.28360E-05 -5.5473 0.22974E-05 -5.6388 0.81007E+00 -0.0915 16 HSiO3- 0.49765E-03 -3.3031 0.46569E-03 -3.3319 0.93578E+00 -0.0288 17 Ca(HSiO3)+ 0.43907E-09 -9.3575 0.41095E-09 -9.3862 0.93595E+00 -0.0287 18 Mg(HSiO3)+ 0.54765E-11 -11.2615 0.51257E-11 -11.2902 0.93595E+00 -0.0287 19 NaHSiO3,aq 0.88547E-05 -5.0528 0.88547E-05 -5.0528 0.10000E+01 0.0000 20 AlO+ 0.55569E-13 -13.2552 0.52010E-13 -13.2839 0.93595E+00 -0.0287 21 AlOH+2 0.33114E-18 -18.4800 0.26802E-18 -18.5718 0.80938E+00 -0.0918 22 HAlO2,aq 0.10117E-07 -7.9949 0.10117E-07 -7.9949 0.10000E+01 0.0000 23 AlO2- 0.23472E-04 -4.6295 0.21961E-04 -4.6584 0.93562E+00 -0.0289 24 CH4,aq 0.25533E-19 -19.5929 0.25526E-19 -19.5930 0.99971E+00 -0.0001 29 CO,aq 0.27365E-18 -18.5628 0.27365E-18 -18.5628 0.10000E+01 0.0000 30 CO2,aq 0.22953E-07 -7.6392 0.22946E-07 -7.6393 0.99971E+00 -0.0001 31 CO3-2 0.12278E-05 -5.9109 0.99438E-06 -6.0024 0.80990E+00 -0.0916 32 CaCO3,aq 0.47967E-09 -9.3191 0.47967E-09 -9.3191 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.11731E-10 -10.9307 0.10979E-10 -10.9594 0.93595E+00 -0.0287 34 CaCl+ 0.86561E-11 -11.0627 0.81017E-11 -11.0914 0.93595E+00 -0.0287 35 CaCl2,aq 0.24351E-15 -15.6135 0.24351E-15 -15.6135 0.10000E+01 0.0000 36 CaOH+ 0.28845E-08 -8.5399 0.26997E-08 -8.5687 0.93595E+00 -0.0287 37 CaSO4,aq 0.25334E-09 -9.5963 0.25334E-09 -9.5963 0.10000E+01 0.0000 38 HCl,aq 0.24978E-13 -13.6024 0.24978E-13 -13.6024 0.10000E+01 0.0000 43 FeCl+ 0.50156E-15 -15.2997 0.46944E-15 -15.3284 0.93595E+00 -0.0287 46 FeO,aq 0.87249E-10 -10.0592 0.87249E-10 -10.0592 0.10000E+01 0.0000 47 FeOH+ 0.80395E-10 -10.0948 0.75246E-10 -10.1235 0.93595E+00 -0.0287 48 HFeO2- 0.97488E-09 -9.0110 0.91227E-09 -9.0399 0.93578E+00 -0.0288 49 FeO+ 0.90919E-14 -14.0413 0.85096E-14 -14.0701 0.93595E+00 -0.0287 51 FeO2- 0.16889E-08 -8.7724 0.15805E-08 -8.8012 0.93578E+00 -0.0288 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.46317E-09 -9.3343 0.46304E-09 -9.3344 0.99971E+00 -0.0001 54 KCl,aq 0.15797E-09 -9.8014 0.15797E-09 -9.8014 0.10000E+01 0.0000 55 KHSO4,aq 0.39277E-17 -17.4059 0.39277E-17 -17.4059 0.10000E+01 0.0000 56 KOH,aq 0.29289E-07 -7.5333 0.29289E-07 -7.5333 0.10000E+01 0.0000 57 KSO4- 0.23491E-07 -7.6291 0.21982E-07 -7.6579 0.93578E+00 -0.0288 58 MgCO3,aq 0.12013E-11 -11.9204 0.12013E-11 -11.9204 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11989E-12 -12.9212 0.11221E-12 -12.9500 0.93595E+00 -0.0287 60 MgCl+ 0.78758E-13 -13.1037 0.73713E-13 -13.1325 0.93595E+00 -0.0287 61 MgOH+ 0.16016E-09 -9.7955 0.14990E-09 -9.8242 0.93595E+00 -0.0287 63 MnO,aq 0.31121E-09 -9.5069 0.31121E-09 -9.5069 0.10000E+01 0.0000 64 MnOH+ 0.99791E-09 -9.0009 0.93399E-09 -9.0297 0.93595E+00 -0.0287 65 MnO2-2 0.12558E-13 -13.9011 0.10170E-13 -13.9927 0.80990E+00 -0.0916 66 HMnO2- 0.24224E-11 -11.6158 0.22668E-11 -11.6446 0.93578E+00 -0.0288 69 MnCl+ 0.26042E-12 -12.5843 0.24374E-12 -12.6131 0.93595E+00 -0.0287 70 MnSO4,aq 0.18253E-11 -11.7387 0.18253E-11 -11.7387 0.10000E+01 0.0000 71 NaCl,aq 0.50462E-07 -7.2970 0.50462E-07 -7.2970 0.10000E+01 0.0000 72 NaOH,aq 0.51137E-06 -6.2913 0.51137E-06 -6.2913 0.10000E+01 0.0000 74 OH- 0.62323E-03 -3.2054 0.58310E-03 -3.2343 0.93562E+00 -0.0289 79 HPO3-2 0.41487E-17 -17.3821 0.33600E-17 -17.4737 0.80990E+00 -0.0916 82 H3PO4,aq 0.15652E-13 -13.8054 0.15652E-13 -13.8054 0.10000E+01 0.0000 83 H2PO4- 0.44274E-07 -7.3539 0.41434E-07 -7.3826 0.93586E+00 -0.0288 84 PO4-3 0.30532E-08 -8.5152 0.19504E-08 -8.7099 0.63880E+00 -0.1946 87 H2P2O7-2 0.16590E-15 -15.7802 0.13436E-15 -15.8717 0.80990E+00 -0.0916 88 HP2O7-3 0.42123E-13 -13.3755 0.26783E-13 -13.5721 0.63583E+00 -0.1967 89 P2O7-4 0.14133E-13 -13.8498 0.64229E-14 -14.1923 0.45446E+00 -0.3425 90 H2S,aq 0.15008E-15 -15.8237 0.15003E-15 -15.8238 0.99971E+00 -0.0001 97 SO3-2 0.16071E-14 -14.7940 0.13034E-14 -14.8849 0.81102E+00 -0.0910 98 HSO3- 0.83852E-16 -16.0765 0.78467E-16 -16.1053 0.93578E+00 -0.0288 99 HSO4- 0.21052E-10 -10.6767 0.19705E-10 -10.7054 0.93603E+00 -0.0287 Charge balance for all species = 0.4568E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1098668E-08 -.1225369E-02 -.1234929E+01 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9998638E+06 0.0000 3 Cl- 0.1379482E-03 0.1379988E-03 0.4891802E+01 5.0986 4 SO4-- 0.2548525E-04 0.2550914E-04 0.2450114E+01 13.2902 5 HCO3- 0.1182110E-04 0.1307233E-04 0.7975279E+00 4.0316 6 HS- 0.5187231E-13 -.1207045E-09 -.3991392E-05 -4.3262 7 Al+++ 0.6705512E-24 0.2348189E-04 0.6334898E+00 2.5929 8 H4SiO4 0.4910068E-03 0.9975159E-03 0.9586351E+02 -3.3089 9 Ca++ 0.4865385E-07 0.5273077E-07 0.2113054E-02 10.5708 10 Mg++ 0.4878390E-09 0.6548734E-09 0.1591910E-04 8.5717 11 Fe++ 0.2885235E-11 0.3037809E-08 0.1696293E-03 6.3437 12 K+ 0.7384492E-04 0.7389786E-04 0.2889159E+01 4.8273 13 Na+ 0.1279348E-02 0.1288765E-02 0.2962439E+02 6.0659 14 Mn++ 0.3854825E-09 0.1699117E-08 0.9333331E-04 8.4695 15 HPO4-- 0.2836020E-05 0.2883347E-05 0.2767028E+00 12.3367 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1487307E-01 -.1225150E-02 -.1364792E-01 0.0000000E+00 2 H2O 0.5549698E+02 0.5549851E+02 -.1527972E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5041882E-04 0.2550459E-04 0.2491423E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2491435E-04 -.1206829E-09 -.2491423E-04 0.0000000E+00 7 Al+++ 0.2931407E-02 0.2347770E-04 0.2907929E-02 0.0000000E+00 8 H4SiO4 0.9361092E-02 0.9973379E-03 0.8363754E-02 0.0000000E+00 9 Ca++ 0.1048449E-02 0.5272136E-07 0.1048397E-02 0.0000000E+00 10 Mg++ 0.7134921E-03 0.6547565E-09 0.7134914E-03 0.0000000E+00 11 Fe++ 0.6409947E-03 0.3037267E-08 0.6409917E-03 0.0000000E+00 12 K+ 0.1908705E-03 0.7388468E-04 0.1169858E-03 0.0000000E+00 13 Na+ 0.1288535E-02 0.1288535E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1558740E-04 0.1698814E-08 0.1558570E-04 0.0000000E+00 15 HPO4-- 0.5319901E-05 0.2882832E-05 0.2437069E-05 0.0000000E+00 Chg. balance for solid moles: -.3024E-18 Mass of aqueous solution: 0.999958E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.8990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.8124E-06 -6.090 0.4081E-03 -3.389 0.4325E-01 0.1297E-03 clinochlore 0.1427E-03 -3.846 0.7932E-01 -1.101 8.407 0.3017E-01 daphnite 0.8834E-04 -4.054 0.6303E-01 -1.200 6.681 0.1910E-01 chlorite-Mn 0.3117E-05 -5.506 0.2210E-02 -2.656 0.2342 0.7043E-03 hematite 0.9966E-04 -4.001 0.1592E-01 -1.798 1.687 0.3017E-02 muscovite 0.1170E-03 -3.932 0.4660E-01 -1.332 4.939 0.1648E-01 stilbite 0.1044E-02 -2.981 0.7360 -0.133 78.01 0.3433 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 0.943438 g Volume = 0.412863 cm3 Porosity: 69.6335% V(tot) - V(min): 0.94674E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.8990000 g log = -0.0462 Original solution: 1000.0103000 g Original solution / Rock added: 1112.36 (Water/Rock Ratio), log = 3.0462 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2479E-05 1.0073 0.2627E-05 0.2608E-05 CH4,gas 0.3788E-16 1.0129 0.4037E-16 0.3985E-16 H2,gas 0.6034E-06 1.0006 0.6351E-06 0.6347E-06 H2S,gas 0.4177E-14 0.9959 0.4376E-14 0.4394E-14 S2,gas 0.1690E-35 1.0000 0.1778E-35 0.1778E-35 CO,gas 0.4108E-15 1.0000 0.4321E-15 0.4321E-15 SO3,gas 0.7764E-38 1.0000 0.8167E-38 0.8167E-38 SO2,gas 0.1865E-21 1.0000 0.1962E-21 0.1962E-21 HCl,gas 0.4193E-16 1.0000 0.4410E-16 0.4410E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 120 muscovite 2.68 2.68 0.00 0.000 0.30331E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.94 -7.58 -2.527 0.12944E+05 -5.581 3 CH4,gas 4.81 -13.58 -18.39 -4.598 0.31407E+05 -16.394 4 H2,gas 8.29 0.09 -8.20 -4.684 0.13996E+05 -6.197 5 H2S,gas -5.94 -22.30 -16.36 -8.179 0.27932E+05 -14.359 6 S2,gas -7.03 -44.78 -37.75 -5.808 0.64457E+05 -35.750 7 CO,gas 3.51 -13.85 -17.36 -5.343 0.29649E+05 -15.364 8 SO3,gas 17.43 -22.66 -40.09 -10.022 0.68449E+05 -38.088 9 SO2,gas 1.14 -22.57 -23.71 -6.322 0.40479E+05 -21.707 10 HCl,gas 5.48 -12.88 -18.36 -9.178 0.31342E+05 -16.356 11 acmite 7.74 5.75 -1.99 -0.207 0.33988E+04 15 albite-high 0.75 -1.27 -2.02 -0.155 0.34450E+04 16 albite -0.33 -1.27 -0.94 -0.072 0.16044E+04 19 spessartine 24.55 20.67 -3.88 -0.194 0.66288E+04 20 analcite 3.37 2.04 -1.33 -0.148 0.22704E+04 21 andalusite 5.06 1.88 -3.19 -0.319 0.54392E+04 22 andradite 39.09 34.38 -4.70 -0.244 0.80329E+04 26 annite 20.21 16.52 -3.68 -0.205 0.62918E+04 27 phlogopite 27.15 23.21 -3.94 -0.219 0.67240E+04 29 anorthite 12.80 9.14 -3.66 -0.281 0.62476E+04 35 aragonite 0.99 -3.37 -4.36 -1.453 0.74434E+04 36 brucite 12.58 8.57 -4.00 -0.801 0.68382E+04 37 calcite 0.83 -3.37 -4.21 -1.402 0.71820E+04 38 carnegieite-low 9.06 5.35 -3.71 -0.531 0.63428E+04 39 carnegieite-high 10.13 5.35 -4.78 -0.684 0.81696E+04 40 carpholite-Mg 8.65 7.14 -1.51 -0.101 0.25795E+04 41 carpholite-Fe 6.78 4.91 -1.87 -0.125 0.31951E+04 42 celadonite 5.40 2.76 -2.64 -0.156 0.45150E+04 43 celadonite-Fe 3.94 0.53 -3.41 -0.201 0.58203E+04 44 chrysotile 23.94 19.10 -4.84 -0.403 0.82641E+04 50 chloritoid-Mg 13.26 10.45 -2.81 -0.188 0.48025E+04 51 chloritoid-Fe 9.24 8.22 -1.02 -0.068 0.17384E+04 52 chloritoid-Mn 11.46 10.35 -1.12 -0.074 0.19069E+04 54 coesite -2.37 -3.31 -0.94 -0.313 0.16043E+04 59 corundum 8.43 5.19 -3.25 -0.295 0.55453E+04 61 cristobalite -2.55 -3.31 -0.76 -0.253 0.12972E+04 63 cymrite-K 1.73 -2.51 -4.24 -0.353 0.72352E+04 65 diaspore 2.90 2.59 -0.30 -0.051 0.51771E+03 67 diopside 16.22 12.52 -3.69 -0.369 0.63020E+04 68 hedenbergite 14.24 10.30 -3.95 -0.395 0.67408E+04 75 epidote 24.78 22.70 -2.08 -0.101 0.35444E+04 76 clinozoisite 22.92 18.99 -3.93 -0.179 0.67065E+04 77 epidote-Fe 29.94 26.41 -3.53 -0.183 0.60299E+04 78 fayalite 14.08 9.38 -4.70 -0.672 0.80260E+04 83 gibbsite 4.10 2.59 -1.50 -0.215 0.25689E+04 87 greenalite 16.19 12.41 -3.78 -0.315 0.64559E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.04 -2.21 -0.221 0.37735E+04 97 kalsilite 7.62 4.11 -3.51 -0.501 0.59915E+04 98 kaolinite -1.27 -1.43 -0.16 -0.014 0.27134E+03 99 kyanite 4.93 1.88 -3.05 -0.305 0.52160E+04 101 laumontite 2.97 2.52 -0.45 -0.030 0.77462E+03 102 lawsonite 9.68 9.14 -0.54 -0.036 0.92147E+03 103 leucite 4.17 0.80 -3.37 -0.337 0.57462E+04 105 lizardite 23.29 19.10 -4.19 -0.349 0.71544E+04 107 magnetite 20.13 18.94 -1.19 -0.097 0.20344E+04 108 minnesotaite 10.46 5.80 -4.67 -0.274 0.79659E+04 113 margarite 17.45 14.32 -3.13 -0.125 0.53398E+04 116 microcline -2.43 -2.51 -0.07 -0.006 0.12769E+03 121 paragonite 4.34 3.92 -0.42 -0.025 0.71516E+03 122 nepheline 8.38 5.35 -3.03 -0.433 0.51707E+04 136 prehnite 19.47 16.40 -3.07 -0.180 0.52347E+04 137 prehnite-Fe 22.59 20.11 -2.48 -0.149 0.42350E+04 138 pumpellyite-Fe 46.47 41.74 -4.73 -0.105 0.80813E+04 145 pyroxmangite 7.42 5.16 -2.26 -0.451 0.38510E+04 146 pyrophyllite -6.10 -8.05 -1.95 -0.122 0.33327E+04 147 quartz -2.98 -3.31 -0.33 -0.109 0.55820E+03 151 rhodochrosite -0.96 -5.47 -4.52 -1.505 0.77105E+04 152 rhodonite 7.46 5.16 -2.30 -0.460 0.39303E+04 153 sanidine -1.22 -2.51 -1.29 -0.099 0.21954E+04 156 sillimanite 5.32 1.88 -3.44 -0.344 0.58814E+04 164 stilpnomelane-Fe 13.18 12.85 -0.33 -0.010 0.56832E+03 165 stilpnomelane-Mg 27.60 23.99 -3.61 -0.108 0.61631E+04 168 sudoite 21.22 17.59 -3.63 -0.117 0.61946E+04 171 talc 16.55 12.48 -4.07 -0.240 0.69560E+04 174 tephroite 18.11 13.63 -4.48 -0.640 0.76542E+04 177 topaz-H 4.67 1.88 -2.79 -0.254 0.47650E+04 178 tridymite -2.61 -3.31 -0.69 -0.231 0.11855E+04 187 wairakite 4.06 2.52 -1.54 -0.090 0.26254E+04 188 walstromite 11.53 7.26 -4.27 -0.853 0.72841E+04 189 wollastonite 10.48 7.26 -3.22 -0.644 0.54980E+04 190 pseudo-wollastonite 11.02 7.26 -3.76 -0.752 0.64166E+04 191 zoisite 22.96 18.99 -3.97 -0.180 0.67790E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.36 -2.80 -0.173 0.47783E+04 194 beidellite-H -2.24 -6.10 -3.86 -0.246 0.65929E+04 195 beidellite-K -1.44 -4.51 -3.07 -0.188 0.52492E+04 196 beidellite-Mg -1.71 -4.69 -2.98 -0.184 0.50901E+04 197 beidellite-Na -1.26 -4.10 -2.84 -0.174 0.48552E+04 199 chalcedony -2.79 -3.31 -0.51 -0.172 0.87851E+03 201 montmorillonite-Ca -2.21 -4.33 -2.12 -0.131 0.36175E+04 202 montmorillonite-K -2.16 -4.48 -2.32 -0.142 0.39663E+04 203 montmorillonite-Mg -2.40 -4.66 -2.26 -0.140 0.38604E+04 204 montmorillonite-Na -1.96 -4.08 -2.11 -0.129 0.36104E+04 205 nontronite-Ca 3.28 3.05 -0.23 -0.015 0.38575E+03 206 nontronite-H 2.60 1.31 -1.29 -0.086 0.21961E+04 207 nontronite-K 3.40 2.90 -0.50 -0.032 0.85588E+03 208 nontronite-Mg 3.14 2.72 -0.42 -0.027 0.70920E+03 209 nontronite-Na 3.58 3.31 -0.27 -0.017 0.46361E+03 224 tobermorite 9.84 5.50 -4.34 -1.185 0.74147E+04 233 boehmite 4.43 2.59 -1.84 -0.306 0.31361E+04 235 ferrous-oxide 9.82 6.34 -3.48 -0.870 0.59429E+04 240 silica-amorphous -2.08 -3.31 -1.23 -0.410 0.20987E+04 242 an20ab80 2.08 0.81 -1.27 -0.097 0.21614E+04 243 an25ab75 2.71 1.33 -1.38 -0.106 0.23486E+04 244 an30ab70 3.34 1.85 -1.49 -0.115 0.25441E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 0.8990000 g New total amount of reactant added: 0.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4566E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.9990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .9858521E-03 Osmotic coef. = 0.9818 True ionic strength = .1515243E-02 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10156E-08 -8.9933 0.94894E-09 -9.0228 0.93435E+00 -0.0295 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12881E-03 -3.8901 0.93377E+00 -0.0298 4 SO4-- 0.25484E-04 -4.5937 0.20469E-04 -4.6889 0.80321E+00 -0.0952 5 HCO3- 0.11723E-04 -4.9310 0.10948E-04 -4.9607 0.93391E+00 -0.0297 6 HS- 0.52369E-13 -13.2809 0.48901E-13 -13.3107 0.93378E+00 -0.0298 7 Al+++ 0.47852E-24 -24.3201 0.29845E-24 -24.5251 0.62369E+00 -0.2050 8 H4SiO4 0.51939E-03 -3.2845 0.51939E-03 -3.2845 0.10000E+01 0.0000 9 Ca++ 0.35428E-07 -7.4507 0.28435E-07 -7.5462 0.80261E+00 -0.0955 10 Mg++ 0.42379E-09 -9.3728 0.33998E-09 -9.4686 0.80223E+00 -0.0957 11 Fe++ 0.25064E-11 -11.6009 0.20109E-11 -11.6966 0.80232E+00 -0.0957 12 K+ 0.81312E-04 -4.0898 0.75940E-04 -4.1195 0.93393E+00 -0.0297 13 Na+ 0.14026E-02 -2.8531 0.13097E-02 -2.8828 0.93375E+00 -0.0298 14 Mn++ 0.33487E-09 -9.4751 0.26870E-09 -9.5707 0.80239E+00 -0.0956 15 HPO4-- 0.44205E-05 -5.3545 0.35507E-05 -5.4497 0.80322E+00 -0.0952 16 HSiO3- 0.57190E-03 -3.2427 0.53402E-03 -3.2724 0.93377E+00 -0.0298 17 Ca(HSiO3)+ 0.36428E-09 -9.4386 0.34022E-09 -9.4682 0.93395E+00 -0.0297 18 Mg(HSiO3)+ 0.54204E-11 -11.2660 0.50624E-11 -11.2956 0.93395E+00 -0.0297 19 NaHSiO3,aq 0.11108E-04 -4.9544 0.11108E-04 -4.9544 0.10000E+01 0.0000 20 AlO+ 0.45813E-13 -13.3390 0.42787E-13 -13.3687 0.93395E+00 -0.0297 21 AlOH+2 0.25346E-18 -18.5961 0.20339E-18 -18.6917 0.80247E+00 -0.0956 22 HAlO2,aq 0.90228E-08 -8.0447 0.90228E-08 -8.0447 0.10000E+01 0.0000 23 AlO2- 0.22741E-04 -4.6432 0.21231E-04 -4.6730 0.93359E+00 -0.0298 24 CH4,aq 0.25673E-19 -19.5905 0.25665E-19 -19.5907 0.99969E+00 -0.0001 29 CO,aq 0.25591E-18 -18.5919 0.25591E-18 -18.5919 0.10000E+01 0.0000 30 CO2,aq 0.20953E-07 -7.6788 0.20946E-07 -7.6789 0.99969E+00 -0.0001 31 CO3-2 0.13284E-05 -5.8767 0.10667E-05 -5.9719 0.80303E+00 -0.0953 32 CaCO3,aq 0.37149E-09 -9.4300 0.37149E-09 -9.4300 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.83987E-11 -11.0758 0.78440E-11 -11.1055 0.93395E+00 -0.0297 34 CaCl+ 0.62492E-11 -11.2042 0.58364E-11 -11.2339 0.93395E+00 -0.0297 35 CaCl2,aq 0.17504E-15 -15.7569 0.17504E-15 -15.7569 0.10000E+01 0.0000 36 CaOH+ 0.22623E-08 -8.6454 0.21129E-08 -8.6751 0.93395E+00 -0.0297 37 CaSO4,aq 0.18135E-09 -9.7415 0.18135E-09 -9.7415 0.10000E+01 0.0000 38 HCl,aq 0.22991E-13 -13.6384 0.22991E-13 -13.6384 0.10000E+01 0.0000 43 FeCl+ 0.43197E-15 -15.3645 0.40344E-15 -15.3942 0.93395E+00 -0.0297 46 FeO,aq 0.88310E-10 -10.0540 0.88310E-10 -10.0540 0.10000E+01 0.0000 47 FeOH+ 0.75223E-10 -10.1236 0.70255E-10 -10.1533 0.93395E+00 -0.0297 48 HFeO2- 0.10720E-08 -8.9698 0.10010E-08 -8.9996 0.93377E+00 -0.0298 49 FeO+ 0.84048E-14 -14.0755 0.78497E-14 -14.1051 0.93395E+00 -0.0297 51 FeO2- 0.18348E-08 -8.7364 0.17133E-08 -8.7662 0.93377E+00 -0.0298 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.47451E-09 -9.3238 0.47436E-09 -9.3239 0.99969E+00 -0.0001 54 KCl,aq 0.17320E-09 -9.7615 0.17320E-09 -9.7615 0.10000E+01 0.0000 55 KHSO4,aq 0.39471E-17 -17.4037 0.39471E-17 -17.4037 0.10000E+01 0.0000 56 KOH,aq 0.34887E-07 -7.4573 0.34887E-07 -7.4573 0.10000E+01 0.0000 57 KSO4- 0.25646E-07 -7.5910 0.23948E-07 -7.6207 0.93377E+00 -0.0298 58 MgCO3,aq 0.11099E-11 -11.9547 0.11099E-11 -11.9547 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10240E-12 -12.9897 0.95636E-13 -13.0194 0.93395E+00 -0.0297 60 MgCl+ 0.67830E-13 -13.1686 0.63350E-13 -13.1983 0.93395E+00 -0.0297 61 MgOH+ 0.14985E-09 -9.8243 0.13996E-09 -9.8540 0.93395E+00 -0.0297 63 MnO,aq 0.31500E-09 -9.5017 0.31500E-09 -9.5017 0.10000E+01 0.0000 64 MnOH+ 0.93372E-09 -9.0298 0.87205E-09 -9.0595 0.93395E+00 -0.0297 65 MnO2-2 0.15065E-13 -13.8220 0.12098E-13 -13.9173 0.80303E+00 -0.0953 66 HMnO2- 0.26637E-11 -11.5745 0.24873E-11 -11.6043 0.93377E+00 -0.0298 69 MnCl+ 0.22429E-12 -12.6492 0.20947E-12 -12.6789 0.93395E+00 -0.0297 70 MnSO4,aq 0.15587E-11 -11.8072 0.15587E-11 -11.8072 0.10000E+01 0.0000 71 NaCl,aq 0.55083E-07 -7.2590 0.55083E-07 -7.2590 0.10000E+01 0.0000 72 NaOH,aq 0.60644E-06 -6.2172 0.60644E-06 -6.2172 0.10000E+01 0.0000 74 OH- 0.67708E-03 -3.1694 0.63211E-03 -3.1992 0.93359E+00 -0.0298 79 HPO3-2 0.66249E-17 -17.1788 0.53200E-17 -17.2741 0.80303E+00 -0.0953 81 H2PO3- 0.10620E-19 -19.9739 0.99166E-20 -20.0036 0.93377E+00 -0.0298 82 H3PO4,aq 0.20584E-13 -13.6865 0.20584E-13 -13.6865 0.10000E+01 0.0000 83 H2PO4- 0.63256E-07 -7.1989 0.59072E-07 -7.2286 0.93386E+00 -0.0297 84 PO4-3 0.52125E-08 -8.2830 0.32677E-08 -8.4858 0.62690E+00 -0.2028 87 H2P2O7-2 0.34009E-15 -15.4684 0.27311E-15 -15.5637 0.80303E+00 -0.0953 88 HP2O7-3 0.94616E-13 -13.0240 0.59015E-13 -13.2290 0.62373E+00 -0.2050 89 P2O7-4 0.34925E-13 -13.4569 0.15342E-13 -13.8141 0.43930E+00 -0.3572 90 H2S,aq 0.13947E-15 -15.8555 0.13942E-15 -15.8557 0.99969E+00 -0.0001 97 SO3-2 0.16461E-14 -14.7835 0.13239E-14 -14.8781 0.80425E+00 -0.0946 98 HSO3- 0.78736E-16 -16.1038 0.73521E-16 -16.1336 0.93377E+00 -0.0298 99 HSO4- 0.19295E-10 -10.7146 0.18022E-10 -10.7442 0.93404E+00 -0.0296 Charge balance for all species = 0.4567E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1015608E-08 -.1352979E-02 -.1363518E+01 0.0000 2 H2O 0.1000000E+01 0.5550839E+02 0.9998505E+06 0.0000 3 Cl- 0.1379462E-03 0.1380014E-03 0.4891832E+01 5.1327 4 SO4-- 0.2548366E-04 0.2550964E-04 0.2450130E+01 13.3566 5 HCO3- 0.1172288E-04 0.1307258E-04 0.7975329E+00 4.0621 6 HS- 0.5236898E-13 -.1361083E-09 -.4500699E-05 -4.2879 7 Al+++ 0.4785205E-24 0.2275035E-04 0.6137466E+00 2.5432 8 H4SiO4 0.5193881E-03 0.1102394E-02 0.1059412E+03 -3.2845 9 Ca++ 0.3542779E-07 0.3862188E-07 0.1547656E-02 10.4994 10 Mg++ 0.4237907E-09 0.5803459E-09 0.1410726E-04 8.5770 11 Fe++ 0.2506409E-11 0.3276321E-08 0.1829453E-03 6.3489 12 K+ 0.8131175E-04 0.8137245E-04 0.3181349E+01 4.9032 13 Na+ 0.1402569E-02 0.1414339E-02 0.3251049E+02 6.1399 14 Mn++ 0.3348729E-09 0.1588055E-08 0.8723150E-04 8.4748 15 HPO4-- 0.4420544E-05 0.4489013E-05 0.4307865E+00 12.5958 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1652892E-01 -.1352712E-02 -.1517620E-01 0.0000000E+00 2 H2O 0.5549573E+02 0.5549743E+02 -.1700017E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5319017E-04 0.2550461E-04 0.2768556E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2768570E-04 -.1360814E-09 -.2768556E-04 0.0000000E+00 7 Al+++ 0.3257481E-02 0.2274586E-04 0.3234735E-02 0.0000000E+00 8 H4SiO4 0.1040237E-01 0.1102176E-02 0.9300194E-02 0.0000000E+00 9 Ca++ 0.1163464E-02 0.3861425E-07 0.1163425E-02 0.0000000E+00 10 Mg++ 0.7928571E-03 0.5802312E-09 0.7928566E-03 0.0000000E+00 11 Fe++ 0.7122956E-03 0.3275674E-08 0.7122923E-03 0.0000000E+00 12 K+ 0.2121019E-03 0.8135638E-04 0.1307455E-03 0.0000000E+00 13 Na+ 0.1414059E-02 0.1414059E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1732126E-04 0.1587741E-08 0.1731967E-04 0.0000000E+00 15 HPO4-- 0.5911659E-05 0.4488127E-05 0.1423532E-05 0.0000000E+00 Chg. balance for solid moles: -.3151E-17 Mass of aqueous solution: 0.999952E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4745E-06 -6.324 0.2384E-03 -3.623 0.2273E-01 0.7574E-04 clinochlore 0.1586E-03 -3.800 0.8814E-01 -1.055 8.403 0.3353E-01 daphnite 0.9816E-04 -4.008 0.7004E-01 -1.155 6.678 0.2122E-01 chlorite-Mn 0.3464E-05 -5.460 0.2456E-02 -2.610 0.2341 0.7826E-03 hematite 0.1107E-03 -3.956 0.1769E-01 -1.752 1.686 0.3352E-02 muscovite 0.1307E-03 -3.884 0.5208E-01 -1.283 4.965 0.1841E-01 stilbite 0.1161E-02 -2.935 0.8182 -0.087 78.01 0.3816 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.048852 g Volume = 0.459006 cm3 Porosity: 67.2045% V(tot) - V(min): 0.94059E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.9990000 g log = -0.0004 Original solution: 1000.0103000 g Original solution / Rock added: 1001.01 (Water/Rock Ratio), log = 3.0004 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2263E-05 1.0073 0.2398E-05 0.2380E-05 CH4,gas 0.3809E-16 1.0129 0.4059E-16 0.4007E-16 H2,gas 0.6182E-06 1.0006 0.6506E-06 0.6503E-06 H2S,gas 0.3881E-14 0.9959 0.4066E-14 0.4083E-14 S2,gas 0.1391E-35 1.0000 0.1463E-35 0.1463E-35 CO,gas 0.3841E-15 1.0000 0.4041E-15 0.4041E-15 SO3,gas 0.6551E-38 1.0000 0.6891E-38 0.6891E-38 SO2,gas 0.1612E-21 1.0000 0.1696E-21 0.1696E-21 HCl,gas 0.3859E-16 1.0000 0.4060E-16 0.4060E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 116 microcline -2.43 -2.41 0.02 0.002 -0.42114E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.98 -7.62 -2.540 0.13011E+05 -5.620 3 CH4,gas 4.81 -13.58 -18.39 -4.598 0.31403E+05 -16.392 4 H2,gas 8.29 0.10 -8.19 -4.678 0.13979E+05 -6.187 5 H2S,gas -5.94 -22.33 -16.39 -8.195 0.27987E+05 -14.391 6 S2,gas -7.03 -44.87 -37.83 -5.821 0.64602E+05 -35.835 7 CO,gas 3.51 -13.88 -17.39 -5.352 0.29699E+05 -15.394 8 SO3,gas 17.43 -22.73 -40.16 -10.040 0.68575E+05 -38.162 9 SO2,gas 1.14 -22.63 -23.77 -6.339 0.40588E+05 -21.771 10 HCl,gas 5.48 -12.91 -18.39 -9.196 0.31403E+05 -16.392 11 acmite 7.74 5.87 -1.87 -0.194 0.31890E+04 15 albite-high 0.75 -1.17 -1.92 -0.148 0.32785E+04 16 albite -0.33 -1.17 -0.84 -0.065 0.14378E+04 19 spessartine 24.55 20.66 -3.89 -0.195 0.66467E+04 20 analcite 3.37 2.11 -1.26 -0.140 0.21456E+04 21 andalusite 5.06 1.80 -3.26 -0.326 0.55673E+04 22 andradite 39.09 34.24 -4.85 -0.252 0.82736E+04 26 annite 20.21 16.64 -3.57 -0.198 0.60951E+04 27 phlogopite 27.15 23.32 -3.82 -0.212 0.65273E+04 29 anorthite 12.80 9.02 -3.78 -0.291 0.64559E+04 35 aragonite 0.99 -3.48 -4.47 -1.490 0.76329E+04 36 brucite 12.58 8.58 -4.00 -0.800 0.68292E+04 37 calcite 0.83 -3.48 -4.32 -1.439 0.73715E+04 38 carnegieite-low 9.06 5.40 -3.67 -0.524 0.62596E+04 39 carnegieite-high 10.13 5.40 -4.74 -0.677 0.80864E+04 40 carpholite-Mg 8.65 7.09 -1.56 -0.104 0.26570E+04 41 carpholite-Fe 6.78 4.87 -1.92 -0.128 0.32726E+04 42 celadonite 5.40 2.89 -2.52 -0.148 0.42946E+04 43 celadonite-Fe 3.94 0.66 -3.28 -0.193 0.55999E+04 44 chrysotile 23.94 19.16 -4.78 -0.398 0.81539E+04 50 chloritoid-Mg 13.26 10.38 -2.88 -0.192 0.49217E+04 51 chloritoid-Fe 9.24 8.15 -1.09 -0.073 0.18576E+04 52 chloritoid-Mn 11.46 10.28 -1.19 -0.079 0.20261E+04 54 coesite -2.37 -3.28 -0.92 -0.305 0.15626E+04 59 corundum 8.43 5.09 -3.35 -0.304 0.57151E+04 61 cristobalite -2.55 -3.28 -0.74 -0.245 0.12555E+04 63 cymrite-K 1.73 -2.41 -4.14 -0.345 0.70654E+04 65 diaspore 2.90 2.54 -0.35 -0.059 0.60261E+03 67 diopside 16.22 12.51 -3.71 -0.371 0.63315E+04 68 hedenbergite 14.24 10.28 -3.97 -0.397 0.67704E+04 75 epidote 24.78 22.53 -2.24 -0.109 0.38330E+04 76 clinozoisite 22.92 18.77 -4.15 -0.188 0.70799E+04 77 epidote-Fe 29.94 26.29 -3.65 -0.190 0.62336E+04 78 fayalite 14.08 9.41 -4.67 -0.667 0.79664E+04 83 gibbsite 4.10 2.54 -1.55 -0.222 0.26538E+04 87 greenalite 16.19 12.48 -3.72 -0.310 0.63457E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.11 -2.14 -0.214 0.36486E+04 97 kalsilite 7.62 4.16 -3.46 -0.494 0.59051E+04 98 kaolinite -1.27 -1.48 -0.21 -0.019 0.35780E+03 99 kyanite 4.93 1.80 -3.13 -0.313 0.53441E+04 101 laumontite 2.97 2.45 -0.53 -0.035 0.89963E+03 102 lawsonite 9.68 9.02 -0.66 -0.044 0.11298E+04 103 leucite 4.17 0.88 -3.29 -0.329 0.56180E+04 105 lizardite 23.29 19.16 -4.13 -0.344 0.70442E+04 107 magnetite 20.13 18.95 -1.19 -0.097 0.20255E+04 108 minnesotaite 10.46 5.91 -4.55 -0.268 0.77724E+04 113 margarite 17.45 14.10 -3.35 -0.134 0.57180E+04 121 paragonite 4.34 3.92 -0.42 -0.025 0.71841E+03 122 nepheline 8.38 5.40 -2.98 -0.426 0.50875E+04 136 prehnite 19.47 16.23 -3.23 -0.190 0.55233E+04 137 prehnite-Fe 22.59 19.99 -2.60 -0.156 0.44387E+04 145 pyroxmangite 7.42 5.19 -2.23 -0.445 0.38004E+04 146 pyrophyllite -6.10 -8.05 -1.95 -0.122 0.33359E+04 147 quartz -2.98 -3.28 -0.30 -0.101 0.51653E+03 151 rhodochrosite -0.96 -5.51 -4.55 -1.517 0.77692E+04 152 rhodonite 7.46 5.19 -2.27 -0.454 0.38796E+04 153 sanidine -1.22 -2.41 -1.19 -0.091 0.20256E+04 156 sillimanite 5.32 1.80 -3.52 -0.352 0.60095E+04 164 stilpnomelane-Fe 13.18 13.01 -0.17 -0.005 0.29513E+03 165 stilpnomelane-Mg 27.60 24.15 -3.45 -0.103 0.58899E+04 168 sudoite 21.22 17.47 -3.74 -0.121 0.63913E+04 171 talc 16.55 12.59 -3.96 -0.233 0.67624E+04 174 tephroite 18.11 13.67 -4.45 -0.635 0.75945E+04 177 topaz-H 4.67 1.80 -2.87 -0.261 0.48932E+04 178 tridymite -2.61 -3.28 -0.67 -0.223 0.11438E+04 187 wairakite 4.06 2.45 -1.61 -0.095 0.27504E+04 188 walstromite 11.53 7.21 -4.31 -0.863 0.73643E+04 189 wollastonite 10.48 7.21 -3.27 -0.653 0.55782E+04 190 pseudo-wollastonite 11.02 7.21 -3.80 -0.761 0.64969E+04 191 zoisite 22.96 18.77 -4.19 -0.190 0.71525E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.40 -2.84 -0.175 0.48433E+04 194 beidellite-H -2.24 -6.13 -3.89 -0.248 0.66377E+04 195 beidellite-K -1.44 -4.51 -3.08 -0.188 0.52513E+04 196 beidellite-Mg -1.71 -4.71 -3.01 -0.186 0.51335E+04 197 beidellite-Na -1.26 -4.10 -2.85 -0.174 0.48584E+04 199 chalcedony -2.79 -3.28 -0.49 -0.163 0.83684E+03 201 montmorillonite-Ca -2.21 -4.33 -2.11 -0.131 0.36098E+04 202 montmorillonite-K -2.16 -4.44 -2.28 -0.140 0.38956E+04 203 montmorillonite-Mg -2.40 -4.65 -2.24 -0.139 0.38311E+04 204 montmorillonite-Na -1.96 -4.03 -2.07 -0.127 0.35409E+04 205 nontronite-Ca 3.28 3.12 -0.16 -0.011 0.28095E+03 206 nontronite-H 2.60 1.38 -1.21 -0.081 0.20712E+04 207 nontronite-K 3.40 3.00 -0.40 -0.026 0.68817E+03 208 nontronite-Mg 3.14 2.80 -0.34 -0.022 0.58281E+03 209 nontronite-Na 3.58 3.41 -0.17 -0.011 0.29697E+03 224 tobermorite 9.84 5.46 -4.38 -1.194 0.74745E+04 233 boehmite 4.43 2.54 -1.89 -0.314 0.32210E+04 235 ferrous-oxide 9.82 6.35 -3.48 -0.869 0.59340E+04 240 silica-amorphous -2.08 -3.28 -1.20 -0.402 0.20570E+04 242 an20ab80 2.08 0.87 -1.21 -0.093 0.20698E+04 243 an25ab75 2.71 1.38 -1.33 -0.103 0.22757E+04 244 an30ab70 3.34 1.89 -1.46 -0.112 0.24900E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 0.9990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5550E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .9865388E-03 Osmotic coef. = 0.9818 True ionic strength = .1510955E-02 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10141E-08 -8.9939 0.94762E-09 -9.0234 0.93442E+00 -0.0295 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12882E-03 -3.8900 0.93383E+00 -0.0297 4 SO4-- 0.25485E-04 -4.5937 0.20475E-04 -4.6888 0.80343E+00 -0.0951 5 HCO3- 0.11721E-04 -4.9310 0.10948E-04 -4.9607 0.93397E+00 -0.0297 6 HS- 0.50340E-13 -13.2981 0.47009E-13 -13.3278 0.93384E+00 -0.0297 7 Al+++ 0.48996E-24 -24.3098 0.30577E-24 -24.5146 0.62407E+00 -0.2048 8 H4SiO4 0.51374E-03 -3.2893 0.51374E-03 -3.2893 0.10000E+01 0.0000 9 Ca++ 0.36024E-07 -7.4434 0.28921E-07 -7.5388 0.80283E+00 -0.0954 10 Mg++ 0.42048E-09 -9.3763 0.33741E-09 -9.4718 0.80245E+00 -0.0956 11 Fe++ 0.24868E-11 -11.6044 0.19958E-11 -11.6999 0.80254E+00 -0.0955 12 K+ 0.77049E-04 -4.1132 0.71964E-04 -4.1429 0.93400E+00 -0.0297 13 Na+ 0.14027E-02 -2.8530 0.13098E-02 -2.8828 0.93382E+00 -0.0297 14 Mn++ 0.33226E-09 -9.4785 0.26667E-09 -9.5740 0.80261E+00 -0.0955 15 HPO4-- 0.42882E-05 -5.3677 0.34453E-05 -5.4628 0.80344E+00 -0.0950 16 HSiO3- 0.56643E-03 -3.2469 0.52894E-03 -3.2766 0.93383E+00 -0.0297 17 Ca(HSiO3)+ 0.36696E-09 -9.4354 0.34275E-09 -9.4650 0.93402E+00 -0.0296 18 Mg(HSiO3)+ 0.53280E-11 -11.2734 0.49765E-11 -11.3031 0.93402E+00 -0.0296 19 NaHSiO3,aq 0.11004E-04 -4.9585 0.11004E-04 -4.9585 0.10000E+01 0.0000 20 AlO+ 0.47064E-13 -13.3273 0.43958E-13 -13.3570 0.93402E+00 -0.0296 21 AlOH+2 0.25997E-18 -18.5851 0.20867E-18 -18.6805 0.80269E+00 -0.0955 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.23427E-04 -4.6303 0.21873E-04 -4.6601 0.93365E+00 -0.0298 24 CH4,aq 0.24671E-19 -19.6078 0.24663E-19 -19.6079 0.99969E+00 -0.0001 29 CO,aq 0.25310E-18 -18.5967 0.25310E-18 -18.5967 0.10000E+01 0.0000 30 CO2,aq 0.20923E-07 -7.6794 0.20916E-07 -7.6795 0.99969E+00 -0.0001 31 CO3-2 0.13298E-05 -5.8762 0.10681E-05 -5.9714 0.80325E+00 -0.0951 32 CaCO3,aq 0.37835E-09 -9.4221 0.37835E-09 -9.4221 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.85414E-11 -11.0685 0.79778E-11 -11.0981 0.93402E+00 -0.0296 34 CaCl+ 0.63561E-11 -11.1968 0.59367E-11 -11.2265 0.93402E+00 -0.0296 35 CaCl2,aq 0.17806E-15 -15.7494 0.17806E-15 -15.7494 0.10000E+01 0.0000 36 CaOH+ 0.23041E-08 -8.6375 0.21520E-08 -8.6672 0.93402E+00 -0.0296 37 CaSO4,aq 0.18451E-09 -9.7340 0.18451E-09 -9.7340 0.10000E+01 0.0000 38 HCl,aq 0.22961E-13 -13.6390 0.22961E-13 -13.6390 0.10000E+01 0.0000 43 FeCl+ 0.42871E-15 -15.3678 0.40042E-15 -15.3975 0.93402E+00 -0.0296 46 FeO,aq 0.87887E-10 -10.0561 0.87887E-10 -10.0561 0.10000E+01 0.0000 47 FeOH+ 0.74755E-10 -10.1264 0.69822E-10 -10.1560 0.93402E+00 -0.0296 48 HFeO2- 0.10682E-08 -8.9713 0.99756E-09 -9.0011 0.93383E+00 -0.0297 49 FeO+ 0.83926E-14 -14.0761 0.78389E-14 -14.1057 0.93402E+00 -0.0296 51 FeO2- 0.18372E-08 -8.7358 0.17157E-08 -8.7656 0.93383E+00 -0.0297 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.46998E-09 -9.3279 0.46983E-09 -9.3281 0.99969E+00 -0.0001 54 KCl,aq 0.16414E-09 -9.7848 0.16414E-09 -9.7848 0.10000E+01 0.0000 55 KHSO4,aq 0.37365E-17 -17.4275 0.37365E-17 -17.4275 0.10000E+01 0.0000 56 KOH,aq 0.33106E-07 -7.4801 0.33106E-07 -7.4801 0.10000E+01 0.0000 57 KSO4- 0.24310E-07 -7.6142 0.22701E-07 -7.6440 0.93383E+00 -0.0297 58 MgCO3,aq 0.11030E-11 -11.9574 0.11030E-11 -11.9574 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10162E-12 -12.9930 0.94910E-13 -13.0227 0.93402E+00 -0.0296 60 MgCl+ 0.67319E-13 -13.1719 0.62877E-13 -13.2015 0.93402E+00 -0.0296 61 MgOH+ 0.14892E-09 -9.8270 0.13909E-09 -9.8567 0.93402E+00 -0.0296 63 MnO,aq 0.31349E-09 -9.5038 0.31349E-09 -9.5038 0.10000E+01 0.0000 64 MnOH+ 0.92790E-09 -9.0325 0.86668E-09 -9.0621 0.93402E+00 -0.0296 65 MnO2-2 0.15030E-13 -13.8230 0.12073E-13 -13.9182 0.80325E+00 -0.0951 66 HMnO2- 0.26544E-11 -11.5760 0.24788E-11 -11.6058 0.93383E+00 -0.0297 69 MnCl+ 0.22260E-12 -12.6525 0.20791E-12 -12.6821 0.93402E+00 -0.0296 70 MnSO4,aq 0.15474E-11 -11.8104 0.15474E-11 -11.8104 0.10000E+01 0.0000 71 NaCl,aq 0.55095E-07 -7.2589 0.55095E-07 -7.2589 0.10000E+01 0.0000 72 NaOH,aq 0.60736E-06 -6.2166 0.60736E-06 -6.2166 0.10000E+01 0.0000 74 OH- 0.67797E-03 -3.1688 0.63299E-03 -3.1986 0.93365E+00 -0.0298 79 HPO3-2 0.63652E-17 -17.1962 0.51128E-17 -17.2913 0.80325E+00 -0.0951 81 H2PO3- 0.10192E-19 -19.9918 0.95172E-20 -20.0215 0.93383E+00 -0.0297 82 H3PO4,aq 0.19918E-13 -13.7008 0.19918E-13 -13.7008 0.10000E+01 0.0000 83 H2PO4- 0.61290E-07 -7.2126 0.57240E-07 -7.2423 0.93392E+00 -0.0297 84 PO4-3 0.50618E-08 -8.2957 0.31752E-08 -8.4982 0.62727E+00 -0.2025 87 H2P2O7-2 0.31924E-15 -15.4959 0.25643E-15 -15.5910 0.80325E+00 -0.0951 88 HP2O7-3 0.88907E-13 -13.0511 0.55488E-13 -13.2558 0.62411E+00 -0.2047 89 P2O7-4 0.32847E-13 -13.4835 0.14445E-13 -13.8403 0.43977E+00 -0.3568 90 H2S,aq 0.13389E-15 -15.8733 0.13384E-15 -15.8734 0.99969E+00 -0.0001 97 SO3-2 0.16305E-14 -14.7877 0.13117E-14 -14.8822 0.80446E+00 -0.0945 98 HSO3- 0.77895E-16 -16.1085 0.72741E-16 -16.1382 0.93383E+00 -0.0297 99 HSO4- 0.19273E-10 -10.7150 0.18003E-10 -10.7447 0.93411E+00 -0.0296 Charge balance for all species = 0.4561E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1014135E-08 -.1351042E-02 -.1361567E+01 0.0000 2 H2O 0.1000000E+01 0.5550840E+02 0.9998518E+06 0.0000 3 Cl- 0.1379461E-03 0.1380014E-03 0.4891836E+01 5.1333 4 SO4-- 0.2548499E-04 0.2550964E-04 0.2450132E+01 13.3580 5 HCO3- 0.1172148E-04 0.1307258E-04 0.7975335E+00 4.0627 6 HS- 0.5033953E-13 -.1375458E-09 -.4548238E-05 -4.3045 7 Al+++ 0.4899629E-24 0.2343646E-04 0.6322568E+00 2.5555 8 H4SiO4 0.5137408E-03 0.1091170E-02 0.1048627E+03 -3.2893 9 Ca++ 0.3602418E-07 0.3927296E-07 0.1573748E-02 10.5079 10 Mg++ 0.4204802E-09 0.5760008E-09 0.1400165E-04 8.5749 11 Fe++ 0.2486831E-11 0.3274104E-08 0.1828217E-03 6.3468 12 K+ 0.7704943E-04 0.7710701E-04 0.3014590E+01 4.8805 13 Na+ 0.1402672E-02 0.1414338E-02 0.3251052E+02 6.1406 14 Mn++ 0.3322573E-09 0.1578090E-08 0.8668424E-04 8.4727 15 HPO4-- 0.4288224E-05 0.4354576E-05 0.4178857E+00 12.5840 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1652892E-01 -.1350775E-02 -.1517814E-01 0.0000000E+00 2 H2O 0.5549573E+02 0.5549745E+02 -.1725359E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5319017E-04 0.2550461E-04 0.2768556E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2768570E-04 -.1375187E-09 -.2768556E-04 0.0000000E+00 7 Al+++ 0.3257481E-02 0.2343184E-04 0.3234049E-02 0.0000000E+00 8 H4SiO4 0.1040237E-01 0.1090955E-02 0.9311415E-02 0.0000000E+00 9 Ca++ 0.1163464E-02 0.3926522E-07 0.1163424E-02 0.0000000E+00 10 Mg++ 0.7928571E-03 0.5758872E-09 0.7928566E-03 0.0000000E+00 11 Fe++ 0.7122956E-03 0.3273458E-08 0.7122923E-03 0.0000000E+00 12 K+ 0.2121019E-03 0.7709180E-04 0.1350101E-03 0.0000000E+00 13 Na+ 0.1414059E-02 0.1414059E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1732126E-04 0.1577779E-08 0.1731968E-04 0.0000000E+00 15 HPO4-- 0.5911659E-05 0.4353717E-05 0.1557942E-05 0.0000000E+00 Chg. balance for solid moles: -.1279E-17 Mass of aqueous solution: 0.999951E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 0.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5193E-06 -6.285 0.2609E-03 -3.584 0.2485E-01 0.8289E-04 clinochlore 0.1586E-03 -3.800 0.8814E-01 -1.055 8.397 0.3353E-01 daphnite 0.9816E-04 -4.008 0.7004E-01 -1.155 6.673 0.2122E-01 chlorite-Mn 0.3464E-05 -5.460 0.2456E-02 -2.610 0.2340 0.7826E-03 hematite 0.1107E-03 -3.956 0.1769E-01 -1.752 1.685 0.3352E-02 muscovite 0.1285E-03 -3.891 0.5118E-01 -1.291 4.876 0.1810E-01 stilbite 0.1161E-02 -2.935 0.8181 -0.087 77.94 0.3816 microcline 0.6515E-05 -5.186 0.1813E-02 -2.741 0.1728 0.7084E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.049633 g Volume = 0.459331 cm3 Porosity: 67.1813% V(tot) - V(min): 0.94027E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 0.9990000 g log = -0.0004 Original solution: 1000.0103000 g Original solution / Rock added: 1001.01 (Water/Rock Ratio), log = 3.0004 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2259E-05 1.0073 0.2394E-05 0.2377E-05 CH4,gas 0.3660E-16 1.0129 0.3900E-16 0.3850E-16 H2,gas 0.6123E-06 1.0006 0.6444E-06 0.6441E-06 H2S,gas 0.3726E-14 0.9959 0.3904E-14 0.3920E-14 S2,gas 0.1307E-35 1.0000 0.1374E-35 0.1374E-35 CO,gas 0.3799E-15 1.0000 0.3997E-15 0.3997E-15 SO3,gas 0.6535E-38 1.0000 0.6874E-38 0.6874E-38 SO2,gas 0.1593E-21 1.0000 0.1676E-21 0.1676E-21 HCl,gas 0.3854E-16 1.0000 0.4054E-16 0.4054E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -13.98 -7.62 -2.540 0.13012E+05 -5.621 3 CH4,gas 4.81 -13.60 -18.41 -4.602 0.31433E+05 -16.409 4 H2,gas 8.29 0.10 -8.19 -4.680 0.13986E+05 -6.191 5 H2S,gas -5.94 -22.35 -16.41 -8.204 0.28017E+05 -14.409 6 S2,gas -7.03 -44.89 -37.86 -5.825 0.64648E+05 -35.862 7 CO,gas 3.51 -13.89 -17.40 -5.353 0.29707E+05 -15.398 8 SO3,gas 17.43 -22.74 -40.16 -10.041 0.68577E+05 -38.163 9 SO2,gas 1.14 -22.64 -23.78 -6.340 0.40597E+05 -21.776 10 HCl,gas 5.48 -12.91 -18.39 -9.196 0.31404E+05 -16.392 11 acmite 7.74 5.86 -1.88 -0.195 0.32041E+04 15 albite-high 0.75 -1.17 -1.92 -0.148 0.32806E+04 16 albite -0.33 -1.17 -0.84 -0.065 0.14400E+04 19 spessartine 24.55 20.66 -3.89 -0.194 0.66396E+04 20 analcite 3.37 2.12 -1.25 -0.139 0.21396E+04 21 andalusite 5.06 1.82 -3.24 -0.324 0.55333E+04 22 andradite 39.09 34.25 -4.83 -0.251 0.82540E+04 26 annite 20.21 16.61 -3.60 -0.200 0.61479E+04 27 phlogopite 27.15 23.29 -3.85 -0.214 0.65801E+04 29 anorthite 12.80 9.04 -3.76 -0.289 0.64154E+04 35 aragonite 0.99 -3.48 -4.46 -1.487 0.76193E+04 36 brucite 12.58 8.57 -4.00 -0.800 0.68328E+04 37 calcite 0.83 -3.48 -4.31 -1.436 0.73580E+04 38 carnegieite-low 9.06 5.41 -3.66 -0.523 0.62455E+04 39 carnegieite-high 10.13 5.41 -4.73 -0.675 0.80723E+04 40 carpholite-Mg 8.65 7.11 -1.54 -0.103 0.26346E+04 41 carpholite-Fe 6.78 4.88 -1.90 -0.127 0.32503E+04 42 celadonite 5.40 2.85 -2.55 -0.150 0.43484E+04 43 celadonite-Fe 3.94 0.63 -3.31 -0.195 0.56537E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81808E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.191 0.48913E+04 51 chloritoid-Fe 9.24 8.17 -1.07 -0.071 0.18272E+04 52 chloritoid-Mn 11.46 10.29 -1.17 -0.078 0.19956E+04 54 coesite -2.37 -3.29 -0.92 -0.307 0.15707E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.29 -0.74 -0.247 0.12636E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.50 -3.71 -0.371 0.63367E+04 68 hedenbergite 14.24 10.28 -3.97 -0.397 0.67755E+04 75 epidote 24.78 22.56 -2.22 -0.108 0.37859E+04 76 clinozoisite 22.92 18.81 -4.11 -0.187 0.70118E+04 77 epidote-Fe 29.94 26.30 -3.64 -0.189 0.62076E+04 78 fayalite 14.08 9.40 -4.67 -0.668 0.79816E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63726E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.12 -2.13 -0.213 0.36426E+04 97 kalsilite 7.62 4.15 -3.47 -0.496 0.59310E+04 98 kaolinite -1.27 -1.47 -0.19 -0.018 0.33190E+03 99 kyanite 4.93 1.82 -3.11 -0.311 0.53101E+04 101 laumontite 2.97 2.46 -0.51 -0.034 0.87530E+03 102 lawsonite 9.68 9.04 -0.64 -0.043 0.10893E+04 103 leucite 4.17 0.86 -3.31 -0.331 0.56520E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70711E+04 107 magnetite 20.13 18.94 -1.19 -0.097 0.20290E+04 108 minnesotaite 10.46 5.88 -4.58 -0.269 0.78155E+04 113 margarite 17.45 14.15 -3.30 -0.132 0.56353E+04 121 paragonite 4.34 3.94 -0.40 -0.023 0.67843E+03 122 nepheline 8.38 5.41 -2.97 -0.424 0.50734E+04 136 prehnite 19.47 16.26 -3.21 -0.189 0.54762E+04 137 prehnite-Fe 22.59 20.00 -2.58 -0.155 0.44127E+04 145 pyroxmangite 7.42 5.18 -2.23 -0.447 0.38121E+04 146 pyrophyllite -6.10 -8.05 -1.95 -0.122 0.33262E+04 147 quartz -2.98 -3.29 -0.31 -0.102 0.52463E+03 151 rhodochrosite -0.96 -5.51 -4.55 -1.518 0.77738E+04 152 rhodonite 7.46 5.18 -2.28 -0.456 0.38913E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.82 -3.50 -0.350 0.59755E+04 164 stilpnomelane-Fe 13.18 12.97 -0.21 -0.006 0.35509E+03 165 stilpnomelane-Mg 27.60 24.11 -3.48 -0.104 0.59499E+04 168 sudoite 21.22 17.50 -3.71 -0.120 0.63385E+04 171 talc 16.55 12.57 -3.99 -0.234 0.68055E+04 174 tephroite 18.11 13.66 -4.46 -0.637 0.76098E+04 177 topaz-H 4.67 1.82 -2.85 -0.259 0.48592E+04 178 tridymite -2.61 -3.29 -0.67 -0.225 0.11519E+04 187 wairakite 4.06 2.46 -1.60 -0.094 0.27261E+04 188 walstromite 11.53 7.22 -4.31 -0.862 0.73578E+04 189 wollastonite 10.48 7.22 -3.26 -0.653 0.55717E+04 190 pseudo-wollastonite 11.02 7.22 -3.80 -0.760 0.64903E+04 191 zoisite 22.96 18.81 -4.15 -0.189 0.70843E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.38 -2.82 -0.175 0.48215E+04 194 beidellite-H -2.24 -6.12 -3.88 -0.247 0.66184E+04 195 beidellite-K -1.44 -4.51 -3.07 -0.188 0.52448E+04 196 beidellite-Mg -1.71 -4.70 -3.00 -0.185 0.51148E+04 197 beidellite-Na -1.26 -4.09 -2.83 -0.174 0.48387E+04 199 chalcedony -2.79 -3.29 -0.49 -0.165 0.84495E+03 201 montmorillonite-Ca -2.21 -4.33 -2.11 -0.131 0.36058E+04 202 montmorillonite-K -2.16 -4.45 -2.29 -0.140 0.39069E+04 203 montmorillonite-Mg -2.40 -4.64 -2.24 -0.139 0.38301E+04 204 montmorillonite-Na -1.96 -4.03 -2.07 -0.127 0.35389E+04 205 nontronite-Ca 3.28 3.10 -0.18 -0.011 0.30134E+03 206 nontronite-H 2.60 1.37 -1.23 -0.082 0.20940E+04 207 nontronite-K 3.40 2.98 -0.42 -0.027 0.72379E+03 208 nontronite-Mg 3.14 2.78 -0.36 -0.023 0.60621E+03 209 nontronite-Na 3.58 3.40 -0.19 -0.012 0.31940E+03 224 tobermorite 9.84 5.46 -4.38 -1.194 0.74704E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.35 -3.48 -0.869 0.59375E+04 240 silica-amorphous -2.08 -3.29 -1.21 -0.403 0.20651E+04 242 an20ab80 2.08 0.87 -1.21 -0.093 0.20634E+04 243 an25ab75 2.71 1.38 -1.33 -0.102 0.22672E+04 244 an30ab70 3.34 1.89 -1.45 -0.112 0.24793E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 0.9990000 g New total amount of reactant added: 1.0990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4566E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.0990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5549E+02 kg total = 0.9998E+00 Activity = 1.0000 Stoichiometric ionic strength = .1057071E-02 Osmotic coef. = 0.9812 True ionic strength = .1628010E-02 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93905E-09 -9.0273 0.87590E-09 -9.0575 0.93276E+00 -0.0302 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12858E-03 -3.8908 0.93213E+00 -0.0305 4 SO4-- 0.25488E-04 -4.5937 0.20331E-04 -4.6918 0.79768E+00 -0.0982 5 HCO3- 0.11619E-04 -4.9348 0.10833E-04 -4.9653 0.93228E+00 -0.0305 6 HS- 0.44078E-13 -13.3558 0.41087E-13 -13.3863 0.93215E+00 -0.0305 7 Al+++ 0.39327E-24 -24.4053 0.24147E-24 -24.6171 0.61400E+00 -0.2118 8 H4SiO4 0.51900E-03 -3.2848 0.51900E-03 -3.2848 0.10000E+01 0.0000 9 Ca++ 0.28868E-07 -7.5396 0.23009E-07 -7.6381 0.79704E+00 -0.0985 10 Mg++ 0.35966E-09 -9.4441 0.28652E-09 -9.5429 0.79663E+00 -0.0987 11 Fe++ 0.21271E-11 -11.6722 0.16947E-11 -11.7709 0.79673E+00 -0.0987 12 K+ 0.69200E-04 -4.1599 0.64515E-04 -4.1903 0.93231E+00 -0.0304 13 Na+ 0.15261E-02 -2.8164 0.14225E-02 -2.8470 0.93212E+00 -0.0305 14 Mn++ 0.28420E-09 -9.5464 0.22645E-09 -9.6450 0.79680E+00 -0.0987 15 HPO4-- 0.56933E-05 -5.2446 0.45415E-05 -5.3428 0.79769E+00 -0.0982 16 HSiO3- 0.62021E-03 -3.2075 0.57811E-03 -3.2380 0.93213E+00 -0.0305 17 Ca(HSiO3)+ 0.31966E-09 -9.4953 0.29803E-09 -9.5257 0.93233E+00 -0.0304 18 Mg(HSiO3)+ 0.49538E-11 -11.3051 0.46186E-11 -11.3355 0.93233E+00 -0.0304 19 NaHSiO3,aq 0.13061E-04 -4.8840 0.13061E-04 -4.8840 0.10000E+01 0.0000 20 AlO+ 0.43581E-13 -13.3607 0.40631E-13 -13.3911 0.93233E+00 -0.0304 21 AlOH+2 0.22372E-18 -18.6503 0.17828E-18 -18.7489 0.79689E+00 -0.0986 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.25392E-04 -4.5953 0.23664E-04 -4.6259 0.93194E+00 -0.0306 24 CH4,aq 0.21488E-19 -19.6678 0.21481E-19 -19.6679 0.99967E+00 -0.0001 29 CO,aq 0.22868E-18 -18.6408 0.22868E-18 -18.6408 0.10000E+01 0.0000 30 CO2,aq 0.19137E-07 -7.7181 0.19130E-07 -7.7183 0.99967E+00 -0.0001 31 CO3-2 0.14339E-05 -5.8435 0.11435E-05 -5.9418 0.79749E+00 -0.0983 32 CaCO3,aq 0.32223E-09 -9.4918 0.32223E-09 -9.4918 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.67360E-11 -11.1716 0.62802E-11 -11.2020 0.93233E+00 -0.0304 34 CaCl+ 0.50565E-11 -11.2961 0.47143E-11 -11.3266 0.93233E+00 -0.0304 35 CaCl2,aq 0.14114E-15 -15.8503 0.14114E-15 -15.8503 0.10000E+01 0.0000 36 CaOH+ 0.19867E-08 -8.7019 0.18523E-08 -8.7323 0.93233E+00 -0.0304 37 CaSO4,aq 0.14575E-09 -9.8364 0.14575E-09 -9.8364 0.10000E+01 0.0000 38 HCl,aq 0.21184E-13 -13.6740 0.21184E-13 -13.6740 0.10000E+01 0.0000 43 FeCl+ 0.36403E-15 -15.4389 0.33940E-15 -15.4693 0.93233E+00 -0.0304 46 FeO,aq 0.87351E-10 -10.0587 0.87351E-10 -10.0587 0.10000E+01 0.0000 47 FeOH+ 0.68800E-10 -10.1624 0.64144E-10 -10.1928 0.93233E+00 -0.0304 48 HFeO2- 0.11508E-08 -8.9390 0.10727E-08 -8.9695 0.93213E+00 -0.0305 49 FeO+ 0.77715E-14 -14.1095 0.72456E-14 -14.1399 0.93233E+00 -0.0304 51 FeO2- 0.19913E-08 -8.7009 0.18562E-08 -8.7314 0.93213E+00 -0.0305 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.46428E-09 -9.3332 0.46413E-09 -9.3334 0.99967E+00 -0.0001 54 KCl,aq 0.14688E-09 -9.8330 0.14688E-09 -9.8330 0.10000E+01 0.0000 55 KHSO4,aq 0.30744E-17 -17.5122 0.30744E-17 -17.5122 0.10000E+01 0.0000 56 KOH,aq 0.32110E-07 -7.4934 0.32110E-07 -7.4934 0.10000E+01 0.0000 57 KSO4- 0.21680E-07 -7.6639 0.20208E-07 -7.6945 0.93213E+00 -0.0305 58 MgCO3,aq 0.10027E-11 -11.9988 0.10027E-11 -11.9988 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.85536E-13 -13.0679 0.79748E-13 -13.0983 0.93233E+00 -0.0304 60 MgCl+ 0.57162E-13 -13.2429 0.53294E-13 -13.2733 0.93233E+00 -0.0304 61 MgOH+ 0.13706E-09 -9.8631 0.12778E-09 -9.8935 0.93233E+00 -0.0304 63 MnO,aq 0.31158E-09 -9.5064 0.31158E-09 -9.5064 0.10000E+01 0.0000 64 MnOH+ 0.85401E-09 -9.0685 0.79621E-09 -9.0990 0.93233E+00 -0.0304 65 MnO2-2 0.17612E-13 -13.7542 0.14045E-13 -13.8525 0.79749E+00 -0.0983 66 HMnO2- 0.28595E-11 -11.5437 0.26654E-11 -11.5742 0.93213E+00 -0.0305 69 MnCl+ 0.18902E-12 -12.7235 0.17622E-12 -12.7539 0.93233E+00 -0.0304 70 MnSO4,aq 0.13048E-11 -11.8845 0.13048E-11 -11.8845 0.10000E+01 0.0000 71 NaCl,aq 0.59723E-07 -7.2239 0.59723E-07 -7.2239 0.10000E+01 0.0000 72 NaOH,aq 0.71361E-06 -6.1465 0.71361E-06 -6.1465 0.10000E+01 0.0000 74 OH- 0.73483E-03 -3.1338 0.68482E-03 -3.1644 0.93194E+00 -0.0306 79 HPO3-2 0.83483E-17 -17.0784 0.66576E-17 -17.1767 0.79749E+00 -0.0983 81 H2PO3- 0.12289E-19 -19.9105 0.11455E-19 -19.9410 0.93213E+00 -0.0305 82 H3PO4,aq 0.22432E-13 -13.6491 0.22432E-13 -13.6491 0.10000E+01 0.0000 83 H2PO4- 0.74811E-07 -7.1260 0.69741E-07 -7.1565 0.93223E+00 -0.0305 84 PO4-3 0.73343E-08 -8.1346 0.45281E-08 -8.3441 0.61738E+00 -0.2094 87 H2P2O7-2 0.47733E-15 -15.3212 0.38066E-15 -15.4195 0.79749E+00 -0.0983 88 HP2O7-3 0.14513E-12 -12.8382 0.89115E-13 -13.0500 0.61404E+00 -0.2118 89 P2O7-4 0.58736E-13 -13.2311 0.25099E-13 -13.6003 0.42732E+00 -0.3692 90 H2S,aq 0.10816E-15 -15.9659 0.10813E-15 -15.9661 0.99967E+00 -0.0001 97 SO3-2 0.16107E-14 -14.7930 0.12866E-14 -14.8905 0.79878E+00 -0.0976 98 HSO3- 0.70753E-16 -16.1503 0.65952E-16 -16.1808 0.93213E+00 -0.0305 99 HSO4- 0.17721E-10 -10.7515 0.16524E-10 -10.7819 0.93243E+00 -0.0304 Charge balance for all species = 0.4570E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9390467E-09 -.1471799E-02 -.1483252E+01 0.0000 2 H2O 0.1000000E+01 0.5550840E+02 0.9998433E+06 0.0000 3 Cl- 0.1379440E-03 0.1380039E-03 0.4891881E+01 5.1667 4 SO4-- 0.2548811E-04 0.2551011E-04 0.2450157E+01 13.4233 5 HCO3- 0.1161949E-04 0.1307281E-04 0.7975409E+00 4.0923 6 HS- 0.4407771E-13 -.1582341E-09 -.5232293E-05 -4.3288 7 Al+++ 0.3932679E-24 0.2540123E-04 0.6852554E+00 2.5555 8 H4SiO4 0.5190004E-03 0.1152268E-02 0.1107333E+03 -3.2848 9 Ca++ 0.2886780E-07 0.3165394E-07 0.1268427E-02 10.4770 10 Mg++ 0.3596592E-09 0.5028168E-09 0.1222256E-04 8.5722 11 Fe++ 0.2127103E-11 0.3503831E-08 0.1956477E-03 6.3442 12 K+ 0.6919969E-04 0.6925363E-04 0.2707530E+01 4.8672 13 Na+ 0.1526081E-02 0.1539915E-02 0.3539677E+02 6.2106 14 Mn++ 0.2841975E-09 0.1454157E-08 0.7987591E-04 8.4701 15 HPO4-- 0.5693316E-05 0.5775462E-05 0.5542359E+00 12.7723 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1818477E-01 -.1471482E-02 -.1671329E-01 0.0000000E+00 2 H2O 0.5549447E+02 0.5549647E+02 -.1992482E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5596151E-04 0.2550463E-04 0.3045688E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3045704E-04 -.1582000E-09 -.3045688E-04 0.0000000E+00 7 Al+++ 0.3583555E-02 0.2539576E-04 0.3558159E-02 0.0000000E+00 8 H4SiO4 0.1144365E-01 0.1152021E-02 0.1029163E-01 0.0000000E+00 9 Ca++ 0.1278478E-02 0.3164714E-07 0.1278446E-02 0.0000000E+00 10 Mg++ 0.8722222E-03 0.5027087E-09 0.8722217E-03 0.0000000E+00 11 Fe++ 0.7835964E-03 0.3503078E-08 0.7835929E-03 0.0000000E+00 12 K+ 0.2333333E-03 0.6923874E-04 0.1640946E-03 0.0000000E+00 13 Na+ 0.1539584E-02 0.1539584E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.1905512E-04 0.1453844E-08 0.1905366E-04 0.0000000E+00 15 HPO4-- 0.6503417E-05 0.5774220E-05 0.7291966E-06 0.0000000E+00 Chg. balance for solid moles: 0.1810E-17 Mass of aqueous solution: 0.999942E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.0990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2431E-06 -6.614 0.1221E-03 -3.913 0.1054E-01 0.3880E-04 clinochlore 0.1744E-03 -3.758 0.9696E-01 -1.013 8.373 0.3688E-01 daphnite 0.1080E-03 -3.967 0.7705E-01 -1.113 6.653 0.2335E-01 chlorite-Mn 0.3811E-05 -5.419 0.2702E-02 -2.568 0.2333 0.8610E-03 hematite 0.1218E-03 -3.914 0.1946E-01 -1.711 1.680 0.3688E-02 microcline 0.3054E-04 -4.515 0.8499E-02 -2.071 0.7339 0.3320E-02 muscovite 0.1336E-03 -3.874 0.5320E-01 -1.274 4.594 0.1881E-01 stilbite 0.1277E-02 -2.894 0.9001 -0.046 77.72 0.4198 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.158079 g Volume = 0.506767 cm3 Porosity: 64.7981% V(tot) - V(min): 0.93283E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.0990000 g log = 0.0410 Original solution: 1000.0103000 g Original solution / Rock added: 909.93 (Water/Rock Ratio), log = 2.9590 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2067E-05 1.0073 0.2190E-05 0.2174E-05 CH4,gas 0.3188E-16 1.0129 0.3397E-16 0.3354E-16 H2,gas 0.6048E-06 1.0006 0.6366E-06 0.6362E-06 H2S,gas 0.3010E-14 0.9959 0.3154E-14 0.3167E-14 S2,gas 0.8739E-36 1.0000 0.9192E-36 0.9192E-36 CO,gas 0.3433E-15 1.0000 0.3611E-15 0.3611E-15 SO3,gas 0.5544E-38 1.0000 0.5831E-38 0.5831E-38 SO2,gas 0.1335E-21 1.0000 0.1404E-21 0.1404E-21 HCl,gas 0.3556E-16 1.0000 0.3741E-16 0.3741E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 120 muscovite 2.68 2.68 0.00 0.000 0.30331E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.02 -7.66 -2.553 0.13079E+05 -5.660 3 CH4,gas 4.81 -13.66 -18.47 -4.617 0.31535E+05 -16.469 4 H2,gas 8.29 0.09 -8.20 -4.684 0.13995E+05 -6.196 5 H2S,gas -5.94 -22.44 -16.50 -8.251 0.28175E+05 -14.501 6 S2,gas -7.03 -45.07 -38.04 -5.852 0.64946E+05 -36.037 7 CO,gas 3.51 -13.93 -17.44 -5.367 0.29782E+05 -15.442 8 SO3,gas 17.43 -22.81 -40.23 -10.059 0.68699E+05 -38.234 9 SO2,gas 1.14 -22.72 -23.85 -6.361 0.40728E+05 -21.853 10 HCl,gas 5.48 -12.95 -18.43 -9.214 0.31464E+05 -16.427 11 acmite 7.74 5.94 -1.80 -0.187 0.30694E+04 15 albite-high 0.75 -1.09 -1.84 -0.141 0.31384E+04 16 albite -0.33 -1.09 -0.76 -0.058 0.12978E+04 19 spessartine 24.55 20.67 -3.88 -0.194 0.66305E+04 20 analcite 3.37 2.20 -1.17 -0.130 0.20049E+04 21 andalusite 5.06 1.83 -3.24 -0.324 0.55258E+04 22 andradite 39.09 34.17 -4.91 -0.255 0.83900E+04 26 annite 20.21 16.60 -3.61 -0.200 0.61615E+04 27 phlogopite 27.15 23.28 -3.86 -0.215 0.65937E+04 29 anorthite 12.80 9.02 -3.78 -0.291 0.64532E+04 35 aragonite 0.99 -3.55 -4.53 -1.511 0.77384E+04 36 brucite 12.58 8.57 -4.00 -0.801 0.68373E+04 37 calcite 0.83 -3.55 -4.38 -1.460 0.74770E+04 38 carnegieite-low 9.06 5.48 -3.58 -0.512 0.61184E+04 39 carnegieite-high 10.13 5.48 -4.65 -0.665 0.79452E+04 40 carpholite-Mg 8.65 7.11 -1.54 -0.102 0.26241E+04 41 carpholite-Fe 6.78 4.89 -1.90 -0.126 0.32397E+04 42 celadonite 5.40 2.86 -2.54 -0.150 0.43453E+04 43 celadonite-Fe 3.94 0.63 -3.31 -0.195 0.56507E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81793E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.191 0.48882E+04 51 chloritoid-Fe 9.24 8.17 -1.07 -0.071 0.18241E+04 52 chloritoid-Mn 11.46 10.30 -1.17 -0.078 0.19926E+04 54 coesite -2.37 -3.28 -0.92 -0.305 0.15632E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.28 -0.74 -0.245 0.12560E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.48 -3.74 -0.374 0.63790E+04 68 hedenbergite 14.24 10.25 -3.99 -0.399 0.68178E+04 75 epidote 24.78 22.51 -2.27 -0.110 0.38690E+04 76 clinozoisite 22.92 18.77 -4.16 -0.189 0.70949E+04 77 epidote-Fe 29.94 26.25 -3.68 -0.191 0.62907E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79831E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63711E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.20 -2.05 -0.205 0.35080E+04 97 kalsilite 7.62 4.14 -3.48 -0.497 0.59461E+04 98 kaolinite -1.27 -1.46 -0.19 -0.017 0.31679E+03 99 kyanite 4.93 1.83 -3.11 -0.311 0.53025E+04 101 laumontite 2.97 2.45 -0.53 -0.035 0.89796E+03 102 lawsonite 9.68 9.02 -0.66 -0.044 0.11270E+04 103 leucite 4.17 0.85 -3.31 -0.331 0.56596E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70696E+04 107 magnetite 20.13 18.94 -1.19 -0.097 0.20336E+04 108 minnesotaite 10.46 5.89 -4.57 -0.269 0.77989E+04 113 margarite 17.45 14.13 -3.32 -0.133 0.56731E+04 121 paragonite 4.34 4.02 -0.31 -0.018 0.53623E+03 122 nepheline 8.38 5.48 -2.90 -0.414 0.49463E+04 136 prehnite 19.47 16.21 -3.26 -0.192 0.55593E+04 137 prehnite-Fe 22.59 19.95 -2.63 -0.158 0.44958E+04 145 pyroxmangite 7.42 5.19 -2.23 -0.446 0.38090E+04 146 pyrophyllite -6.10 -8.03 -1.93 -0.121 0.32960E+04 147 quartz -2.98 -3.28 -0.30 -0.101 0.51708E+03 151 rhodochrosite -0.96 -5.55 -4.59 -1.531 0.78445E+04 152 rhodonite 7.46 5.19 -2.28 -0.455 0.38883E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.83 -3.50 -0.350 0.59679E+04 164 stilpnomelane-Fe 13.18 12.99 -0.19 -0.006 0.32865E+03 165 stilpnomelane-Mg 27.60 24.13 -3.47 -0.104 0.59235E+04 168 sudoite 21.22 17.51 -3.70 -0.119 0.63249E+04 171 talc 16.55 12.58 -3.98 -0.234 0.67889E+04 174 tephroite 18.11 13.66 -4.46 -0.637 0.76113E+04 177 topaz-H 4.67 1.83 -2.84 -0.258 0.48516E+04 178 tridymite -2.61 -3.28 -0.67 -0.223 0.11444E+04 187 wairakite 4.06 2.45 -1.61 -0.095 0.27488E+04 188 walstromite 11.53 7.19 -4.34 -0.867 0.74031E+04 189 wollastonite 10.48 7.19 -3.29 -0.658 0.56170E+04 190 pseudo-wollastonite 11.02 7.19 -3.83 -0.766 0.65356E+04 191 zoisite 22.96 18.77 -4.20 -0.191 0.71674E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.37 -2.81 -0.174 0.48025E+04 194 beidellite-H -2.24 -6.10 -3.86 -0.246 0.65907E+04 195 beidellite-K -1.44 -4.49 -3.06 -0.187 0.52246E+04 196 beidellite-Mg -1.71 -4.69 -2.98 -0.184 0.50878E+04 197 beidellite-Na -1.26 -4.05 -2.79 -0.171 0.47716E+04 199 chalcedony -2.79 -3.28 -0.49 -0.163 0.83740E+03 201 montmorillonite-Ca -2.21 -4.31 -2.10 -0.130 0.35858E+04 202 montmorillonite-K -2.16 -4.44 -2.28 -0.139 0.38856E+04 203 montmorillonite-Mg -2.40 -4.63 -2.23 -0.138 0.38022E+04 204 montmorillonite-Na -1.96 -3.99 -2.03 -0.124 0.34708E+04 205 nontronite-Ca 3.28 3.11 -0.17 -0.011 0.28234E+03 206 nontronite-H 2.60 1.39 -1.21 -0.081 0.20663E+04 207 nontronite-K 3.40 2.99 -0.41 -0.026 0.70355E+03 208 nontronite-Mg 3.14 2.80 -0.34 -0.022 0.57923E+03 209 nontronite-Na 3.58 3.44 -0.15 -0.009 0.25224E+03 224 tobermorite 9.84 5.44 -4.40 -1.200 0.75069E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.34 -3.48 -0.870 0.59421E+04 240 silica-amorphous -2.08 -3.28 -1.21 -0.402 0.20576E+04 242 an20ab80 2.08 0.93 -1.15 -0.088 0.19572E+04 243 an25ab75 2.71 1.44 -1.27 -0.098 0.21700E+04 244 an30ab70 3.34 1.94 -1.40 -0.108 0.23911E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 1.0990000 g New total amount of reactant added: 1.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4567E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.1990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1128875E-02 Osmotic coef. = 0.9807 True ionic strength = .1746503E-02 Chg. balance for total moles = 0.4567E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.87468E-09 -9.0582 0.81446E-09 -9.0891 0.93115E+00 -0.0310 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12835E-03 -3.8916 0.93048E+00 -0.0313 4 SO4-- 0.25491E-04 -4.5936 0.20192E-04 -4.6948 0.79212E+00 -0.1012 5 HCO3- 0.11518E-04 -4.9386 0.10720E-04 -4.9698 0.93064E+00 -0.0312 6 HS- 0.38971E-13 -13.4093 0.36262E-13 -13.4405 0.93050E+00 -0.0313 7 Al+++ 0.32121E-24 -24.4932 0.19413E-24 -24.7119 0.60437E+00 -0.2187 8 H4SiO4 0.52392E-03 -3.2807 0.52392E-03 -3.2807 0.10000E+01 0.0000 9 Ca++ 0.23529E-07 -7.6284 0.18622E-07 -7.7300 0.79145E+00 -0.1016 10 Mg++ 0.31141E-09 -9.5067 0.24633E-09 -9.6085 0.79102E+00 -0.1018 11 Fe++ 0.18417E-11 -11.7348 0.14570E-11 -11.8365 0.79112E+00 -0.1018 12 K+ 0.62659E-04 -4.2030 0.58315E-04 -4.2342 0.93067E+00 -0.0312 13 Na+ 0.16493E-02 -2.7827 0.15346E-02 -2.8140 0.93047E+00 -0.0313 14 Mn++ 0.24607E-09 -9.6089 0.19469E-09 -9.7107 0.79120E+00 -0.1017 15 HPO4-- 0.74027E-05 -5.1306 0.58639E-05 -5.2318 0.79214E+00 -0.1012 16 HSiO3- 0.67452E-03 -3.1710 0.62763E-03 -3.2023 0.93048E+00 -0.0313 17 Ca(HSiO3)+ 0.28136E-09 -9.5507 0.26186E-09 -9.5819 0.93069E+00 -0.0312 18 Mg(HSiO3)+ 0.46319E-11 -11.3342 0.43108E-11 -11.3654 0.93069E+00 -0.0312 19 NaHSiO3,aq 0.15297E-04 -4.8154 0.15297E-04 -4.8154 0.10000E+01 0.0000 20 AlO+ 0.40594E-13 -13.3915 0.37781E-13 -13.4227 0.93069E+00 -0.0312 21 AlOH+2 0.19480E-18 -18.7104 0.15414E-18 -18.8121 0.79129E+00 -0.1017 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.27356E-04 -4.5629 0.25449E-04 -4.5943 0.93028E+00 -0.0314 24 CH4,aq 0.18897E-19 -19.7236 0.18890E-19 -19.7238 0.99965E+00 -0.0002 29 CO,aq 0.20805E-18 -18.6818 0.20805E-18 -18.6818 0.10000E+01 0.0000 30 CO2,aq 0.17609E-07 -7.7543 0.17603E-07 -7.7544 0.99965E+00 -0.0002 31 CO3-2 0.15367E-05 -5.8134 0.12169E-05 -5.9147 0.79192E+00 -0.1013 32 CaCO3,aq 0.27755E-09 -9.5567 0.27755E-09 -9.5567 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.54044E-11 -11.2673 0.50298E-11 -11.2984 0.93069E+00 -0.0312 34 CaCl+ 0.40924E-11 -11.3880 0.38087E-11 -11.4192 0.93069E+00 -0.0312 35 CaCl2,aq 0.11382E-15 -15.9438 0.11382E-15 -15.9438 0.10000E+01 0.0000 36 CaOH+ 0.17323E-08 -8.7614 0.16122E-08 -8.7926 0.93069E+00 -0.0312 37 CaSO4,aq 0.11716E-09 -9.9312 0.11716E-09 -9.9312 0.10000E+01 0.0000 38 HCl,aq 0.19663E-13 -13.7063 0.19663E-13 -13.7063 0.10000E+01 0.0000 43 FeCl+ 0.31296E-15 -15.5045 0.29127E-15 -15.5357 0.93069E+00 -0.0312 46 FeO,aq 0.86858E-10 -10.0612 0.86858E-10 -10.0612 0.10000E+01 0.0000 47 FeOH+ 0.63724E-10 -10.1957 0.59308E-10 -10.2269 0.93069E+00 -0.0312 48 HFeO2- 0.12328E-08 -8.9091 0.11471E-08 -8.9404 0.93048E+00 -0.0313 49 FeO+ 0.72390E-14 -14.1403 0.67373E-14 -14.1715 0.93069E+00 -0.0312 51 FeO2- 0.21453E-08 -8.6685 0.19962E-08 -8.6998 0.93048E+00 -0.0313 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.45906E-09 -9.3381 0.45890E-09 -9.3383 0.99965E+00 -0.0002 54 KCl,aq 0.13253E-09 -9.8777 0.13253E-09 -9.8777 0.10000E+01 0.0000 55 KHSO4,aq 0.25663E-17 -17.5907 0.25663E-17 -17.5907 0.10000E+01 0.0000 56 KOH,aq 0.31214E-07 -7.5057 0.31214E-07 -7.5057 0.10000E+01 0.0000 57 KSO4- 0.19496E-07 -7.7101 0.18141E-07 -7.7413 0.93048E+00 -0.0313 58 MgCO3,aq 0.91739E-12 -12.0374 0.91739E-12 -12.0374 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.72899E-13 -13.1373 0.67846E-13 -13.1685 0.93069E+00 -0.0312 60 MgCl+ 0.49143E-13 -13.3085 0.45737E-13 -13.3397 0.93069E+00 -0.0312 61 MgOH+ 0.12695E-09 -9.8964 0.11815E-09 -9.9276 0.93069E+00 -0.0312 63 MnO,aq 0.30983E-09 -9.5089 0.30983E-09 -9.5089 0.10000E+01 0.0000 64 MnOH+ 0.79101E-09 -9.1018 0.73619E-09 -9.1330 0.93069E+00 -0.0312 65 MnO2-2 0.20397E-13 -13.6904 0.16153E-13 -13.7917 0.79192E+00 -0.1013 66 HMnO2- 0.30633E-11 -11.5138 0.28504E-11 -11.5451 0.93048E+00 -0.0313 69 MnCl+ 0.16250E-12 -12.7891 0.15124E-12 -12.8203 0.93069E+00 -0.0312 70 MnSO4,aq 0.11141E-11 -11.9531 0.11141E-11 -11.9531 0.10000E+01 0.0000 71 NaCl,aq 0.64317E-07 -7.1917 0.64317E-07 -7.1917 0.10000E+01 0.0000 72 NaOH,aq 0.82795E-06 -6.0820 0.82795E-06 -6.0820 0.10000E+01 0.0000 74 OH- 0.79168E-03 -3.1015 0.73649E-03 -3.1328 0.93028E+00 -0.0314 79 HPO3-2 0.10733E-16 -16.9693 0.84995E-17 -17.0706 0.79192E+00 -0.1013 81 H2PO3- 0.14614E-19 -19.8352 0.13598E-19 -19.8665 0.93048E+00 -0.0313 82 H3PO4,aq 0.25042E-13 -13.6013 0.25042E-13 -13.6013 0.10000E+01 0.0000 83 H2PO4- 0.89977E-07 -7.0459 0.83732E-07 -7.0771 0.93059E+00 -0.0312 84 PO4-3 0.10343E-07 -7.9854 0.62877E-08 -8.2015 0.60792E+00 -0.2162 87 H2P2O7-2 0.69289E-15 -15.1593 0.54871E-15 -15.2607 0.79192E+00 -0.1013 88 HP2O7-3 0.22857E-12 -12.6410 0.13815E-12 -12.8597 0.60441E+00 -0.2187 89 P2O7-4 0.10069E-12 -12.9970 0.41845E-13 -13.3784 0.41556E+00 -0.3814 90 H2S,aq 0.88768E-16 -16.0517 0.88737E-16 -16.0519 0.99965E+00 -0.0002 97 SO3-2 0.15926E-14 -14.7979 0.12634E-14 -14.8985 0.79329E+00 -0.1006 98 HSO3- 0.64718E-16 -16.1890 0.60219E-16 -16.2203 0.93048E+00 -0.0313 99 HSO4- 0.16393E-10 -10.7853 0.15259E-10 -10.8165 0.93080E+00 -0.0311 Charge balance for all species = 0.4570E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8746769E-09 -.1593260E-02 -.1605644E+01 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9998346E+06 0.0000 3 Cl- 0.1379419E-03 0.1380063E-03 0.4891926E+01 5.1975 4 SO4-- 0.2549078E-04 0.2551059E-04 0.2450182E+01 13.4834 5 HCO3- 0.1151849E-04 0.1307305E-04 0.7975482E+00 4.1193 6 HS- 0.3897078E-13 -.1787974E-09 -.5912207E-05 -4.3514 7 Al+++ 0.3212108E-24 0.2736572E-04 0.7382455E+00 2.5555 8 H4SiO4 0.5239212E-03 0.1213735E-02 0.1166393E+03 -3.2807 9 Ca++ 0.2352909E-07 0.2594695E-07 0.1039729E-02 10.4483 10 Mg++ 0.3114057E-09 0.4440235E-09 0.1079331E-04 8.5698 11 Fe++ 0.1841706E-11 0.3734021E-08 0.2084993E-03 6.3417 12 K+ 0.6265907E-04 0.6270992E-04 0.2451676E+01 4.8549 13 Na+ 0.1649306E-02 0.1665496E-02 0.3828307E+02 6.2751 14 Mn++ 0.2460676E-09 0.1351262E-08 0.7422332E-04 8.4676 15 HPO4-- 0.7402675E-05 0.7502996E-05 0.7200106E+00 12.9465 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1984062E-01 -.1592889E-02 -.1824773E-01 0.0000000E+00 2 H2O 0.5549322E+02 0.5549548E+02 -.2255410E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5873285E-04 0.2550465E-04 0.3322820E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3322838E-04 -.1787558E-09 -.3322820E-04 0.0000000E+00 7 Al+++ 0.3909629E-02 0.2735934E-04 0.3882270E-02 0.0000000E+00 8 H4SiO4 0.1248493E-01 0.1213452E-02 0.1127147E-01 0.0000000E+00 9 Ca++ 0.1393492E-02 0.2594090E-07 0.1393466E-02 0.0000000E+00 10 Mg++ 0.9515873E-03 0.4439200E-09 0.9515869E-03 0.0000000E+00 11 Fe++ 0.8548973E-03 0.3733151E-08 0.8548936E-03 0.0000000E+00 12 K+ 0.2545648E-03 0.6269531E-04 0.1918695E-03 0.0000000E+00 13 Na+ 0.1665108E-02 0.1665108E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2078898E-04 0.1350947E-08 0.2078763E-04 0.0000000E+00 15 HPO4-- 0.7095174E-05 0.7501248E-05 -.4060740E-06 0.0000000E+00 Chg. balance for solid moles: -.2419E-17 Mass of aqueous solution: 0.999933E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH -.1354E-06 1.000 -.6799E-04 1.000 -.5369E-02 -.2161E-04 clinochlore 0.1903E-03 -3.721 0.1058 -0.976 8.353 0.4024E-01 daphnite 0.1178E-03 -3.929 0.8406E-01 -1.075 6.637 0.2547E-01 chlorite-Mn 0.4158E-05 -5.381 0.2948E-02 -2.531 0.2327 0.9393E-03 hematite 0.1329E-03 -3.876 0.2123E-01 -1.673 1.676 0.4023E-02 microcline 0.5310E-04 -4.275 0.1478E-01 -1.830 1.167 0.5773E-02 muscovite 0.1388E-03 -3.858 0.5527E-01 -1.257 4.364 0.1954E-01 stilbite 0.1394E-02 -2.856 0.9825 -0.008 77.58 0.4582 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.266484 g Volume = 0.554216 cm3 Porosity: 62.5428% V(tot) - V(min): 0.92538E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.1990000 g log = 0.0788 Original solution: 1000.0103000 g Original solution / Rock added: 834.04 (Water/Rock Ratio), log = 2.9212 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1902E-05 1.0073 0.2015E-05 0.2000E-05 CH4,gas 0.2804E-16 1.0129 0.2987E-16 0.2949E-16 H2,gas 0.5980E-06 1.0006 0.6294E-06 0.6291E-06 H2S,gas 0.2470E-14 0.9959 0.2588E-14 0.2599E-14 S2,gas 0.6020E-36 1.0000 0.6333E-36 0.6333E-36 CO,gas 0.3123E-15 1.0000 0.3285E-15 0.3285E-15 SO3,gas 0.4760E-38 1.0000 0.5007E-38 0.5007E-38 SO2,gas 0.1133E-21 1.0000 0.1192E-21 0.1192E-21 HCl,gas 0.3301E-16 1.0000 0.3472E-16 0.3472E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.15165E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.06 -7.70 -2.565 0.13140E+05 -5.696 3 CH4,gas 4.81 -13.72 -18.52 -4.631 0.31630E+05 -16.525 4 H2,gas 8.29 0.09 -8.20 -4.686 0.14003E+05 -6.201 5 H2S,gas -5.94 -22.53 -16.59 -8.294 0.28322E+05 -14.587 6 S2,gas -7.03 -45.23 -38.20 -5.877 0.65223E+05 -36.198 7 CO,gas 3.51 -13.97 -17.48 -5.380 0.29853E+05 -15.483 8 SO3,gas 17.43 -22.87 -40.30 -10.075 0.68812E+05 -38.300 9 SO2,gas 1.14 -22.79 -23.92 -6.380 0.40849E+05 -21.924 10 HCl,gas 5.48 -12.98 -18.46 -9.230 0.31519E+05 -16.459 11 acmite 7.74 6.01 -1.72 -0.179 0.29452E+04 15 albite-high 0.75 -1.01 -1.76 -0.135 0.30072E+04 16 albite -0.33 -1.01 -0.68 -0.053 0.11666E+04 19 spessartine 24.55 20.67 -3.88 -0.194 0.66221E+04 20 analcite 3.37 2.27 -1.10 -0.122 0.18807E+04 21 andalusite 5.06 1.83 -3.23 -0.323 0.55188E+04 22 andradite 39.09 34.10 -4.99 -0.259 0.85159E+04 26 annite 20.21 16.59 -3.62 -0.201 0.61741E+04 27 phlogopite 27.15 23.28 -3.87 -0.215 0.66063E+04 29 anorthite 12.80 9.00 -3.80 -0.292 0.64882E+04 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 35 aragonite 0.99 -3.61 -4.60 -1.532 0.78491E+04 36 brucite 12.58 8.57 -4.01 -0.801 0.68415E+04 37 calcite 0.83 -3.61 -4.44 -1.481 0.75877E+04 38 carnegieite-low 9.06 5.55 -3.51 -0.502 0.60012E+04 39 carnegieite-high 10.13 5.55 -4.58 -0.655 0.78280E+04 40 carpholite-Mg 8.65 7.12 -1.53 -0.102 0.26143E+04 41 carpholite-Fe 6.78 4.89 -1.89 -0.126 0.32299E+04 42 celadonite 5.40 2.86 -2.54 -0.150 0.43425E+04 43 celadonite-Fe 3.94 0.63 -3.31 -0.195 0.56479E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81779E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.191 0.48854E+04 51 chloritoid-Fe 9.24 8.17 -1.07 -0.071 0.18213E+04 52 chloritoid-Mn 11.46 10.30 -1.17 -0.078 0.19898E+04 54 coesite -2.37 -3.28 -0.91 -0.304 0.15562E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.28 -0.73 -0.244 0.12491E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.46 -3.76 -0.376 0.64182E+04 68 hedenbergite 14.24 10.23 -4.02 -0.402 0.68570E+04 75 epidote 24.78 22.46 -2.31 -0.112 0.39460E+04 76 clinozoisite 22.92 18.72 -4.20 -0.191 0.71719E+04 77 epidote-Fe 29.94 26.21 -3.73 -0.194 0.63676E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79845E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63697E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.27 -1.98 -0.198 0.33838E+04 97 kalsilite 7.62 4.13 -3.49 -0.499 0.59601E+04 98 kaolinite -1.27 -1.45 -0.18 -0.016 0.30280E+03 99 kyanite 4.93 1.83 -3.10 -0.310 0.52955E+04 101 laumontite 2.97 2.44 -0.54 -0.036 0.91896E+03 102 lawsonite 9.68 9.00 -0.68 -0.045 0.11620E+04 103 leucite 4.17 0.85 -3.32 -0.332 0.56666E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70682E+04 107 magnetite 20.13 18.94 -1.19 -0.097 0.20378E+04 108 minnesotaite 10.46 5.90 -4.56 -0.268 0.77835E+04 113 margarite 17.45 14.11 -3.34 -0.134 0.57081E+04 121 paragonite 4.34 4.10 -0.24 -0.014 0.40503E+03 122 nepheline 8.38 5.55 -2.83 -0.404 0.48291E+04 136 prehnite 19.47 16.17 -3.30 -0.194 0.56363E+04 137 prehnite-Fe 22.59 19.91 -2.68 -0.161 0.45727E+04 145 pyroxmangite 7.42 5.19 -2.23 -0.446 0.38062E+04 146 pyrophyllite -6.10 -8.01 -1.91 -0.120 0.32680E+04 147 quartz -2.98 -3.28 -0.30 -0.100 0.51008E+03 151 rhodochrosite -0.96 -5.59 -4.63 -1.544 0.79104E+04 152 rhodonite 7.46 5.19 -2.28 -0.455 0.38855E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.83 -3.49 -0.349 0.59609E+04 164 stilpnomelane-Fe 13.18 13.00 -0.18 -0.005 0.30416E+03 165 stilpnomelane-Mg 27.60 24.14 -3.45 -0.103 0.58990E+04 168 sudoite 21.22 17.52 -3.70 -0.119 0.63123E+04 171 talc 16.55 12.59 -3.97 -0.233 0.67735E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76126E+04 177 topaz-H 4.67 1.83 -2.84 -0.258 0.48446E+04 178 tridymite -2.61 -3.28 -0.67 -0.222 0.11374E+04 187 wairakite 4.06 2.44 -1.62 -0.095 0.27698E+04 188 walstromite 11.53 7.17 -4.36 -0.872 0.74451E+04 189 wollastonite 10.48 7.17 -3.31 -0.663 0.56590E+04 190 pseudo-wollastonite 11.02 7.17 -3.85 -0.770 0.65776E+04 191 zoisite 22.96 18.72 -4.24 -0.193 0.72444E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.36 -2.80 -0.173 0.47849E+04 194 beidellite-H -2.24 -6.09 -3.84 -0.245 0.65650E+04 195 beidellite-K -1.44 -4.48 -3.05 -0.187 0.52058E+04 196 beidellite-Mg -1.71 -4.67 -2.97 -0.183 0.50628E+04 197 beidellite-Na -1.26 -4.02 -2.76 -0.169 0.47095E+04 199 chalcedony -2.79 -3.28 -0.49 -0.162 0.83040E+03 201 montmorillonite-Ca -2.21 -4.30 -2.09 -0.129 0.35673E+04 202 montmorillonite-K -2.16 -4.43 -2.26 -0.139 0.38660E+04 203 montmorillonite-Mg -2.40 -4.61 -2.21 -0.137 0.37762E+04 204 montmorillonite-Na -1.96 -3.96 -2.00 -0.122 0.34078E+04 205 nontronite-Ca 3.28 3.12 -0.16 -0.010 0.26474E+03 206 nontronite-H 2.60 1.40 -1.20 -0.080 0.20406E+04 207 nontronite-K 3.40 3.00 -0.40 -0.026 0.68480E+03 208 nontronite-Mg 3.14 2.81 -0.32 -0.021 0.55424E+03 209 nontronite-Na 3.58 3.47 -0.11 -0.007 0.19019E+03 224 tobermorite 9.84 5.42 -4.42 -1.205 0.75407E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.34 -3.48 -0.871 0.59463E+04 240 silica-amorphous -2.08 -3.28 -1.20 -0.400 0.20506E+04 242 an20ab80 2.08 0.99 -1.09 -0.084 0.18593E+04 243 an25ab75 2.71 1.49 -1.22 -0.094 0.20804E+04 244 an30ab70 3.34 1.99 -1.35 -0.104 0.23098E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.1990000 Water: Moles liquid = 0.5550E+02 kg liquid = 0.9998E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1127626E-02 Osmotic coef. = 0.9807 True ionic strength = .1745527E-02 Chg. balance for total moles = 0.4567E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.87583E-09 -9.0576 0.81554E-09 -9.0886 0.93116E+00 -0.0310 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12835E-03 -3.8916 0.93050E+00 -0.0313 4 SO4-- 0.25491E-04 -4.5936 0.20193E-04 -4.6948 0.79217E+00 -0.1012 5 HCO3- 0.11520E-04 -4.9385 0.10721E-04 -4.9697 0.93065E+00 -0.0312 6 HS- 0.38407E-13 -13.4156 0.35738E-13 -13.4469 0.93051E+00 -0.0313 7 Al+++ 0.32245E-24 -24.4915 0.19491E-24 -24.7102 0.60445E+00 -0.2186 8 H4SiO4 0.52567E-03 -3.2793 0.52567E-03 -3.2793 0.10000E+01 0.0000 9 Ca++ 0.23048E-07 -7.6374 0.18242E-07 -7.7389 0.79149E+00 -0.1016 10 Mg++ 0.31159E-09 -9.5064 0.24649E-09 -9.6082 0.79106E+00 -0.1018 11 Fe++ 0.18428E-11 -11.7345 0.14580E-11 -11.8363 0.79116E+00 -0.1017 12 K+ 0.62119E-04 -4.2068 0.57813E-04 -4.2380 0.93068E+00 -0.0312 13 Na+ 0.16493E-02 -2.7827 0.15346E-02 -2.8140 0.93048E+00 -0.0313 14 Mn++ 0.24622E-09 -9.6087 0.19482E-09 -9.7104 0.79124E+00 -0.1017 15 HPO4-- 0.70018E-05 -5.1548 0.55467E-05 -5.2560 0.79218E+00 -0.1012 16 HSiO3- 0.67585E-03 -3.1701 0.62888E-03 -3.2014 0.93050E+00 -0.0313 17 Ca(HSiO3)+ 0.27617E-09 -9.5588 0.25703E-09 -9.5900 0.93071E+00 -0.0312 18 Mg(HSiO3)+ 0.46441E-11 -11.3331 0.43223E-11 -11.3643 0.93071E+00 -0.0312 19 NaHSiO3,aq 0.15328E-04 -4.8145 0.15328E-04 -4.8145 0.10000E+01 0.0000 20 AlO+ 0.40648E-13 -13.3910 0.37831E-13 -13.4221 0.93071E+00 -0.0312 21 AlOH+2 0.19531E-18 -18.7093 0.15455E-18 -18.8109 0.79133E+00 -0.1016 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.27320E-04 -4.5635 0.25415E-04 -4.5949 0.93030E+00 -0.0314 24 CH4,aq 0.18626E-19 -19.7299 0.18619E-19 -19.7300 0.99965E+00 -0.0002 29 CO,aq 0.20753E-18 -18.6829 0.20753E-18 -18.6829 0.10000E+01 0.0000 30 CO2,aq 0.17635E-07 -7.7536 0.17629E-07 -7.7538 0.99965E+00 -0.0002 31 CO3-2 0.15348E-05 -5.8139 0.12155E-05 -5.9152 0.79197E+00 -0.1013 32 CaCO3,aq 0.27157E-09 -9.5661 0.27157E-09 -9.5661 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.52950E-11 -11.2761 0.49281E-11 -11.3073 0.93071E+00 -0.0312 34 CaCl+ 0.40089E-11 -11.3970 0.37311E-11 -11.4282 0.93071E+00 -0.0312 35 CaCl2,aq 0.11151E-15 -15.9527 0.11151E-15 -15.9527 0.10000E+01 0.0000 36 CaOH+ 0.16947E-08 -8.7709 0.15772E-08 -8.8021 0.93071E+00 -0.0312 37 CaSO4,aq 0.11477E-09 -9.9402 0.11477E-09 -9.9402 0.10000E+01 0.0000 38 HCl,aq 0.19690E-13 -13.7058 0.19690E-13 -13.7058 0.10000E+01 0.0000 43 FeCl+ 0.31317E-15 -15.5042 0.29147E-15 -15.5354 0.93071E+00 -0.0312 46 FeO,aq 0.86685E-10 -10.0621 0.86685E-10 -10.0621 0.10000E+01 0.0000 47 FeOH+ 0.63681E-10 -10.1960 0.59268E-10 -10.2272 0.93071E+00 -0.0312 48 HFeO2- 0.12287E-08 -8.9106 0.11433E-08 -8.9418 0.93050E+00 -0.0313 49 FeO+ 0.72485E-14 -14.1398 0.67462E-14 -14.1709 0.93071E+00 -0.0312 51 FeO2- 0.21425E-08 -8.6691 0.19935E-08 -8.7004 0.93050E+00 -0.0313 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.45723E-09 -9.3399 0.45707E-09 -9.3400 0.99965E+00 -0.0002 54 KCl,aq 0.13139E-09 -9.8814 0.13139E-09 -9.8814 0.10000E+01 0.0000 55 KHSO4,aq 0.25477E-17 -17.5938 0.25477E-17 -17.5938 0.10000E+01 0.0000 56 KOH,aq 0.30904E-07 -7.5100 0.30904E-07 -7.5100 0.10000E+01 0.0000 57 KSO4- 0.19329E-07 -7.7138 0.17986E-07 -7.7451 0.93050E+00 -0.0313 58 MgCO3,aq 0.91694E-12 -12.0377 0.91694E-12 -12.0377 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.72958E-13 -13.1369 0.67903E-13 -13.1681 0.93071E+00 -0.0312 60 MgCl+ 0.49175E-13 -13.3083 0.45768E-13 -13.3394 0.93071E+00 -0.0312 61 MgOH+ 0.12686E-09 -9.8967 0.11807E-09 -9.9279 0.93071E+00 -0.0312 63 MnO,aq 0.30921E-09 -9.5097 0.30921E-09 -9.5097 0.10000E+01 0.0000 64 MnOH+ 0.79047E-09 -9.1021 0.73570E-09 -9.1333 0.93071E+00 -0.0312 65 MnO2-2 0.20301E-13 -13.6925 0.16078E-13 -13.7938 0.79197E+00 -0.1013 66 HMnO2- 0.30531E-11 -11.5153 0.28409E-11 -11.5465 0.93050E+00 -0.0313 69 MnCl+ 0.16261E-12 -12.7889 0.15134E-12 -12.8200 0.93071E+00 -0.0312 70 MnSO4,aq 0.11149E-11 -11.9528 0.11149E-11 -11.9528 0.10000E+01 0.0000 71 NaCl,aq 0.64317E-07 -7.1917 0.64317E-07 -7.1917 0.10000E+01 0.0000 72 NaOH,aq 0.82685E-06 -6.0826 0.82685E-06 -6.0826 0.10000E+01 0.0000 74 OH- 0.79062E-03 -3.1020 0.73551E-03 -3.1334 0.93030E+00 -0.0314 79 HPO3-2 0.10111E-16 -16.9952 0.80077E-17 -17.0965 0.79197E+00 -0.1013 81 H2PO3- 0.13786E-19 -19.8605 0.12828E-19 -19.8918 0.93050E+00 -0.0313 82 H3PO4,aq 0.23751E-13 -13.6243 0.23751E-13 -13.6243 0.10000E+01 0.0000 83 H2PO4- 0.85222E-07 -7.0694 0.79307E-07 -7.1007 0.93060E+00 -0.0312 84 PO4-3 0.97693E-08 -8.0101 0.59397E-08 -8.2262 0.60799E+00 -0.2161 87 H2P2O7-2 0.62157E-15 -15.2065 0.49226E-15 -15.3078 0.79197E+00 -0.1013 88 HP2O7-3 0.20475E-12 -12.6888 0.12377E-12 -12.9074 0.60449E+00 -0.2186 89 P2O7-4 0.90075E-13 -13.0454 0.37440E-13 -13.4267 0.41566E+00 -0.3813 90 H2S,aq 0.87601E-16 -16.0575 0.87570E-16 -16.0576 0.99965E+00 -0.0002 97 SO3-2 0.15863E-14 -14.7996 0.12585E-14 -14.9002 0.79334E+00 -0.1005 98 HSO3- 0.64549E-16 -16.1901 0.60062E-16 -16.2214 0.93050E+00 -0.0313 99 HSO4- 0.16416E-10 -10.7847 0.15280E-10 -10.8159 0.93081E+00 -0.0311 Charge balance for all species = 0.4568E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8758272E-09 -.1593420E-02 -.1605805E+01 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9998344E+06 0.0000 3 Cl- 0.1379419E-03 0.1380063E-03 0.4891925E+01 5.1970 4 SO4-- 0.2549095E-04 0.2551059E-04 0.2450181E+01 13.4823 5 HCO3- 0.1152033E-04 0.1307305E-04 0.7975481E+00 4.1188 6 HS- 0.3840677E-13 -.1788952E-09 -.5915439E-05 -4.3583 7 Al+++ 0.3224520E-24 0.2732902E-04 0.7372553E+00 2.5555 8 H4SiO4 0.5256657E-03 0.1216848E-02 0.1169384E+03 -3.2793 9 Ca++ 0.2304777E-07 0.2541426E-07 0.1018383E-02 10.4382 10 Mg++ 0.3115941E-09 0.4441374E-09 0.1079607E-04 8.5689 11 Fe++ 0.1842820E-11 0.3726822E-08 0.2080972E-03 6.3409 12 K+ 0.6211890E-04 0.6216927E-04 0.2430539E+01 4.8506 13 Na+ 0.1649277E-02 0.1665496E-02 0.3828306E+02 6.2746 14 Mn++ 0.2462164E-09 0.1350246E-08 0.7416751E-04 8.4667 15 HPO4-- 0.7001836E-05 0.7096828E-05 0.6810332E+00 12.9211 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1984062E-01 -.1593049E-02 -.1824757E-01 0.0000000E+00 2 H2O 0.5549322E+02 0.5549547E+02 -.2253711E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5873285E-04 0.2550465E-04 0.3322820E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3322838E-04 -.1788535E-09 -.3322820E-04 0.0000000E+00 7 Al+++ 0.3909629E-02 0.2732265E-04 0.3882307E-02 0.0000000E+00 8 H4SiO4 0.1248493E-01 0.1216565E-02 0.1126836E-01 0.0000000E+00 9 Ca++ 0.1393492E-02 0.2540834E-07 0.1393467E-02 0.0000000E+00 10 Mg++ 0.9515873E-03 0.4440339E-09 0.9515869E-03 0.0000000E+00 11 Fe++ 0.8548973E-03 0.3725954E-08 0.8548936E-03 0.0000000E+00 12 K+ 0.2545648E-03 0.6215479E-04 0.1924100E-03 0.0000000E+00 13 Na+ 0.1665108E-02 0.1665108E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2078898E-04 0.1349932E-08 0.2078763E-04 0.0000000E+00 15 HPO4-- 0.7095174E-05 0.7095174E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.4682E-17 Mass of aqueous solution: 0.999933E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.1903E-03 -3.721 0.1058 -0.976 8.354 0.4024E-01 daphnite 0.1178E-03 -3.929 0.8406E-01 -1.075 6.638 0.2547E-01 chlorite-Mn 0.4158E-05 -5.381 0.2948E-02 -2.531 0.2328 0.9393E-03 hematite 0.1329E-03 -3.876 0.2123E-01 -1.673 1.676 0.4023E-02 microcline 0.5322E-04 -4.274 0.1481E-01 -1.829 1.170 0.5786E-02 muscovite 0.1392E-03 -3.856 0.5544E-01 -1.256 4.378 0.1960E-01 stilbite 0.1393E-02 -2.856 0.9820 -0.008 77.55 0.4580 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.266277 g Volume = 0.554088 cm3 Porosity: 62.5515% V(tot) - V(min): 0.92551E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.1990000 g log = 0.0788 Original solution: 1000.0103000 g Original solution / Rock added: 834.04 (Water/Rock Ratio), log = 2.9212 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1904E-05 1.0073 0.2018E-05 0.2003E-05 CH4,gas 0.2763E-16 1.0129 0.2944E-16 0.2907E-16 H2,gas 0.5956E-06 1.0006 0.6269E-06 0.6266E-06 H2S,gas 0.2438E-14 0.9959 0.2554E-14 0.2565E-14 S2,gas 0.5910E-36 1.0000 0.6217E-36 0.6217E-36 CO,gas 0.3115E-15 1.0000 0.3277E-15 0.3277E-15 SO3,gas 0.4773E-38 1.0000 0.5021E-38 0.5021E-38 SO2,gas 0.1132E-21 1.0000 0.1191E-21 0.1191E-21 HCl,gas 0.3305E-16 1.0000 0.3477E-16 0.3477E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.60662E-10 47 daphnite 29.09 29.09 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.60662E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 0.30331E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.06 -7.70 -2.565 0.13139E+05 -5.695 3 CH4,gas 4.81 -13.72 -18.53 -4.633 0.31641E+05 -16.531 4 H2,gas 8.29 0.08 -8.20 -4.687 0.14006E+05 -6.203 5 H2S,gas -5.94 -22.54 -16.59 -8.296 0.28332E+05 -14.593 6 S2,gas -7.03 -45.24 -38.21 -5.878 0.65236E+05 -36.206 7 CO,gas 3.51 -13.97 -17.48 -5.380 0.29854E+05 -15.485 8 SO3,gas 17.43 -22.87 -40.30 -10.075 0.68810E+05 -38.299 9 SO2,gas 1.14 -22.79 -23.92 -6.380 0.40850E+05 -21.924 10 HCl,gas 5.48 -12.98 -18.46 -9.229 0.31518E+05 -16.459 11 acmite 7.74 6.01 -1.72 -0.179 0.29413E+04 15 albite-high 0.75 -1.01 -1.76 -0.135 0.30008E+04 16 albite -0.33 -1.01 -0.68 -0.052 0.11602E+04 19 spessartine 24.55 20.67 -3.88 -0.194 0.66191E+04 20 analcite 3.37 2.27 -1.10 -0.122 0.18768E+04 21 andalusite 5.06 1.83 -3.23 -0.323 0.55163E+04 26 annite 20.21 16.59 -3.62 -0.201 0.61785E+04 27 phlogopite 27.15 23.27 -3.87 -0.215 0.66107E+04 29 anorthite 12.80 8.99 -3.81 -0.293 0.65005E+04 32 apatite-OH -17.99 -18.11 -0.12 -0.009 0.20408E+03 35 aragonite 0.99 -3.62 -4.61 -1.535 0.78652E+04 36 brucite 12.58 8.57 -4.01 -0.802 0.68430E+04 37 calcite 0.83 -3.62 -4.45 -1.484 0.76039E+04 38 carnegieite-low 9.06 5.55 -3.51 -0.502 0.59997E+04 39 carnegieite-high 10.13 5.55 -4.58 -0.655 0.78266E+04 40 carpholite-Mg 8.65 7.12 -1.53 -0.102 0.26108E+04 41 carpholite-Fe 6.78 4.89 -1.89 -0.126 0.32265E+04 42 celadonite 5.40 2.86 -2.54 -0.150 0.43416E+04 43 celadonite-Fe 3.94 0.63 -3.31 -0.195 0.56469E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81774E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.191 0.48844E+04 51 chloritoid-Fe 9.24 8.17 -1.07 -0.071 0.18204E+04 52 chloritoid-Mn 11.46 10.30 -1.16 -0.078 0.19888E+04 54 coesite -2.37 -3.28 -0.91 -0.303 0.15537E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.28 -0.73 -0.243 0.12466E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.45 -3.77 -0.377 0.64320E+04 68 hedenbergite 14.24 10.22 -4.02 -0.402 0.68708E+04 75 epidote 24.78 22.45 -2.33 -0.113 0.39731E+04 76 clinozoisite 22.92 18.70 -4.22 -0.192 0.71990E+04 77 epidote-Fe 29.94 26.19 -3.75 -0.195 0.63948E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79850E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63692E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.27 -1.98 -0.198 0.33798E+04 97 kalsilite 7.62 4.13 -3.49 -0.499 0.59650E+04 98 kaolinite -1.27 -1.45 -0.17 -0.016 0.29787E+03 99 kyanite 4.93 1.83 -3.10 -0.310 0.52931E+04 101 laumontite 2.97 2.43 -0.54 -0.036 0.92635E+03 102 lawsonite 9.68 8.99 -0.69 -0.046 0.11744E+04 103 leucite 4.17 0.85 -3.32 -0.332 0.56691E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70677E+04 107 magnetite 20.13 18.94 -1.19 -0.097 0.20392E+04 108 minnesotaite 10.46 5.91 -4.56 -0.268 0.77780E+04 113 margarite 17.45 14.10 -3.35 -0.134 0.57204E+04 121 paragonite 4.34 4.10 -0.23 -0.014 0.39862E+03 122 nepheline 8.38 5.55 -2.83 -0.404 0.48276E+04 136 prehnite 19.47 16.15 -3.32 -0.195 0.56634E+04 137 prehnite-Fe 22.59 19.89 -2.69 -0.162 0.45999E+04 145 pyroxmangite 7.42 5.19 -2.23 -0.446 0.38052E+04 146 pyrophyllite -6.10 -8.01 -1.91 -0.119 0.32581E+04 147 quartz -2.98 -3.28 -0.30 -0.099 0.50762E+03 151 rhodochrosite -0.96 -5.59 -4.63 -1.544 0.79108E+04 152 rhodonite 7.46 5.19 -2.27 -0.455 0.38845E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.83 -3.49 -0.349 0.59585E+04 164 stilpnomelane-Fe 13.18 13.01 -0.17 -0.005 0.29553E+03 165 stilpnomelane-Mg 27.60 24.15 -3.45 -0.103 0.58903E+04 168 sudoite 21.22 17.52 -3.69 -0.119 0.63078E+04 171 talc 16.55 12.59 -3.96 -0.233 0.67681E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76131E+04 177 topaz-H 4.67 1.83 -2.84 -0.258 0.48422E+04 178 tridymite -2.61 -3.28 -0.66 -0.222 0.11349E+04 187 wairakite 4.06 2.43 -1.63 -0.096 0.27772E+04 188 walstromite 11.53 7.16 -4.37 -0.874 0.74599E+04 189 wollastonite 10.48 7.16 -3.32 -0.665 0.56738E+04 190 pseudo-wollastonite 11.02 7.16 -3.86 -0.772 0.65924E+04 191 zoisite 22.96 18.70 -4.26 -0.194 0.72715E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.36 -2.80 -0.173 0.47787E+04 194 beidellite-H -2.24 -6.08 -3.84 -0.245 0.65560E+04 195 beidellite-K -1.44 -4.48 -3.04 -0.186 0.51992E+04 196 beidellite-Mg -1.71 -4.67 -2.96 -0.183 0.50540E+04 197 beidellite-Na -1.26 -4.01 -2.75 -0.169 0.47008E+04 199 chalcedony -2.79 -3.28 -0.48 -0.162 0.82793E+03 201 montmorillonite-Ca -2.21 -4.30 -2.09 -0.129 0.35608E+04 202 montmorillonite-K -2.16 -4.42 -2.26 -0.138 0.38590E+04 203 montmorillonite-Mg -2.40 -4.61 -2.21 -0.136 0.37671E+04 204 montmorillonite-Na -1.96 -3.95 -1.99 -0.122 0.33988E+04 205 nontronite-Ca 3.28 3.13 -0.15 -0.010 0.25854E+03 206 nontronite-H 2.60 1.41 -1.19 -0.080 0.20316E+04 207 nontronite-K 3.40 3.01 -0.40 -0.025 0.67819E+03 208 nontronite-Mg 3.14 2.82 -0.32 -0.021 0.54544E+03 209 nontronite-Na 3.58 3.48 -0.11 -0.007 0.18147E+03 224 tobermorite 9.84 5.42 -4.42 -1.207 0.75526E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.34 -3.48 -0.871 0.59477E+04 240 silica-amorphous -2.08 -3.28 -1.20 -0.400 0.20481E+04 242 an20ab80 2.08 0.99 -1.09 -0.084 0.18566E+04 243 an25ab75 2.71 1.49 -1.22 -0.094 0.20786E+04 244 an30ab70 3.34 1.99 -1.35 -0.104 0.23090E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 1.1990000 g New total amount of reactant added: 1.2990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4567E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.2990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1196260E-02 Osmotic coef. = 0.9801 True ionic strength = .1862015E-02 Chg. balance for total moles = 0.4567E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.82365E-09 -9.0843 0.76570E-09 -9.1159 0.92964E+00 -0.0317 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12814E-03 -3.8923 0.92894E+00 -0.0320 4 SO4-- 0.25494E-04 -4.5936 0.20062E-04 -4.6976 0.78695E+00 -0.1041 5 HCO3- 0.11427E-04 -4.9421 0.10617E-04 -4.9740 0.92911E+00 -0.0319 6 HS- 0.32591E-13 -13.4869 0.30276E-13 -13.5189 0.92895E+00 -0.0320 7 Al+++ 0.27090E-24 -24.5672 0.16131E-24 -24.7923 0.59546E+00 -0.2251 8 H4SiO4 0.53632E-03 -3.2706 0.53632E-03 -3.2706 0.10000E+01 0.0000 9 Ca++ 0.17773E-07 -7.7502 0.13974E-07 -7.8547 0.78623E+00 -0.1044 10 Mg++ 0.27321E-09 -9.5635 0.21469E-09 -9.6682 0.78578E+00 -0.1047 11 Fe++ 0.16158E-11 -11.7916 0.12699E-11 -11.8962 0.78589E+00 -0.1046 12 K+ 0.55008E-04 -4.2596 0.51109E-04 -4.2915 0.92914E+00 -0.0319 13 Na+ 0.17722E-02 -2.7515 0.16462E-02 -2.7835 0.92892E+00 -0.0320 14 Mn++ 0.21589E-09 -9.6658 0.16968E-09 -9.7704 0.78597E+00 -0.1046 15 HPO4-- 0.75912E-05 -5.1197 0.59740E-05 -5.2237 0.78696E+00 -0.1040 16 HSiO3- 0.73566E-03 -3.1333 0.68338E-03 -3.1653 0.92894E+00 -0.0320 17 Ca(HSiO3)+ 0.23027E-09 -9.6378 0.21396E-09 -9.6697 0.92916E+00 -0.0319 18 Mg(HSiO3)+ 0.44028E-11 -11.3563 0.40909E-11 -11.3882 0.92916E+00 -0.0319 19 NaHSiO3,aq 0.17868E-04 -4.7479 0.17868E-04 -4.7479 0.10000E+01 0.0000 20 AlO+ 0.38227E-13 -13.4176 0.35519E-13 -13.4495 0.92916E+00 -0.0319 21 AlOH+2 0.17332E-18 -18.7611 0.13624E-18 -18.8657 0.78607E+00 -0.1045 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.29147E-04 -4.5354 0.27070E-04 -4.5675 0.92872E+00 -0.0321 24 CH4,aq 0.15728E-19 -19.8033 0.15722E-19 -19.8035 0.99963E+00 -0.0002 29 CO,aq 0.18836E-18 -18.7250 0.18836E-18 -18.7250 0.10000E+01 0.0000 30 CO2,aq 0.16397E-07 -7.7852 0.16391E-07 -7.7854 0.99963E+00 -0.0002 31 CO3-2 0.16295E-05 -5.7879 0.12820E-05 -5.8921 0.78674E+00 -0.1042 32 CaCO3,aq 0.21941E-09 -9.6587 0.21941E-09 -9.6587 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40232E-11 -11.3954 0.37382E-11 -11.4273 0.92916E+00 -0.0319 34 CaCl+ 0.30708E-11 -11.5128 0.28532E-11 -11.5447 0.92916E+00 -0.0319 35 CaCl2,aq 0.85126E-16 -16.0699 0.85126E-16 -16.0699 0.10000E+01 0.0000 36 CaOH+ 0.13849E-08 -8.8586 0.12868E-08 -8.8905 0.92916E+00 -0.0319 37 CaSO4,aq 0.87349E-10 -10.0587 0.87349E-10 -10.0587 0.10000E+01 0.0000 38 HCl,aq 0.18455E-13 -13.7339 0.18455E-13 -13.7339 0.10000E+01 0.0000 43 FeCl+ 0.27275E-15 -15.5642 0.25343E-15 -15.5961 0.92916E+00 -0.0319 46 FeO,aq 0.85648E-10 -10.0673 0.85648E-10 -10.0673 0.10000E+01 0.0000 47 FeOH+ 0.59172E-10 -10.2279 0.54981E-10 -10.2598 0.92916E+00 -0.0319 48 HFeO2- 0.12952E-08 -8.8877 0.12031E-08 -8.9197 0.92894E+00 -0.0320 49 FeO+ 0.68169E-14 -14.1664 0.63340E-14 -14.1983 0.92916E+00 -0.0319 51 FeO2- 0.22857E-08 -8.6410 0.21233E-08 -8.6730 0.92894E+00 -0.0320 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44636E-09 -9.3503 0.44620E-09 -9.3505 0.99963E+00 -0.0002 54 KCl,aq 0.11596E-09 -9.9357 0.11596E-09 -9.9357 0.10000E+01 0.0000 55 KHSO4,aq 0.21010E-17 -17.6776 0.21010E-17 -17.6776 0.10000E+01 0.0000 56 KOH,aq 0.29099E-07 -7.5361 0.29099E-07 -7.5361 0.10000E+01 0.0000 57 KSO4- 0.17006E-07 -7.7694 0.15797E-07 -7.8014 0.92894E+00 -0.0320 58 MgCO3,aq 0.84232E-12 -12.0745 0.84232E-12 -12.0745 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.63030E-13 -13.2005 0.58565E-13 -13.2324 0.92916E+00 -0.0319 60 MgCl+ 0.42829E-13 -13.3683 0.39795E-13 -13.4002 0.92916E+00 -0.0319 61 MgOH+ 0.11788E-09 -9.9286 0.10953E-09 -9.9605 0.92916E+00 -0.0319 63 MnO,aq 0.30551E-09 -9.5150 0.30551E-09 -9.5150 0.10000E+01 0.0000 64 MnOH+ 0.73451E-09 -9.1340 0.68248E-09 -9.1659 0.92916E+00 -0.0319 65 MnO2-2 0.22906E-13 -13.6401 0.18021E-13 -13.7442 0.78674E+00 -0.1042 66 HMnO2- 0.32184E-11 -11.4924 0.29897E-11 -11.5244 0.92894E+00 -0.0320 69 MnCl+ 0.14162E-12 -12.8489 0.13159E-12 -12.8808 0.92916E+00 -0.0319 70 MnSO4,aq 0.96475E-12 -12.0156 0.96475E-12 -12.0156 0.10000E+01 0.0000 71 NaCl,aq 0.68879E-07 -7.1619 0.68879E-07 -7.1619 0.10000E+01 0.0000 72 NaOH,aq 0.94471E-06 -6.0247 0.94471E-06 -6.0247 0.10000E+01 0.0000 74 OH- 0.84350E-03 -3.0739 0.78338E-03 -3.1060 0.92872E+00 -0.0321 79 HPO3-2 0.10702E-16 -16.9706 0.84193E-17 -17.0747 0.78674E+00 -0.1042 81 H2PO3- 0.13632E-19 -19.8654 0.12663E-19 -19.8974 0.92894E+00 -0.0320 82 H3PO4,aq 0.22549E-13 -13.6469 0.22549E-13 -13.6469 0.10000E+01 0.0000 83 H2PO4- 0.86321E-07 -7.0639 0.80196E-07 -7.0958 0.92905E+00 -0.0320 84 PO4-3 0.11372E-07 -7.9442 0.68135E-08 -8.1666 0.59917E+00 -0.2224 87 H2P2O7-2 0.63980E-15 -15.1940 0.50336E-15 -15.2981 0.78674E+00 -0.1042 88 HP2O7-3 0.22636E-12 -12.6452 0.13480E-12 -12.8703 0.59551E+00 -0.2251 89 P2O7-4 0.10728E-12 -12.9695 0.43430E-13 -13.3622 0.40482E+00 -0.3927 90 H2S,aq 0.69678E-16 -16.1569 0.69653E-16 -16.1571 0.99963E+00 -0.0002 97 SO3-2 0.15486E-14 -14.8101 0.12206E-14 -14.9134 0.78818E+00 -0.1034 98 HSO3- 0.58878E-16 -16.2300 0.54694E-16 -16.2621 0.92894E+00 -0.0320 99 HSO4- 0.15338E-10 -10.8142 0.14254E-10 -10.8461 0.92927E+00 -0.0319 Charge balance for all species = 0.4568E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.8236512E-09 -.1716173E-02 -.1729496E+01 0.0000 2 H2O 0.1000000E+01 0.5550840E+02 0.9998248E+06 0.0000 3 Cl- 0.1379398E-03 0.1380088E-03 0.4891967E+01 5.2236 4 SO4-- 0.2549376E-04 0.2551107E-04 0.2450204E+01 13.5343 5 HCO3- 0.1142712E-04 0.1307328E-04 0.7975548E+00 4.1419 6 HS- 0.3259135E-13 -.1995269E-09 -.6597593E-05 -4.4030 7 Al+++ 0.2709047E-24 0.2915635E-04 0.7865439E+00 2.5555 8 H4SiO4 0.5363189E-03 0.1289850E-02 0.1239527E+03 -3.2706 9 Ca++ 0.1777302E-07 0.1970208E-07 0.7894811E-03 10.3772 10 Mg++ 0.2732137E-09 0.3964432E-09 0.9636635E-05 8.5637 11 Fe++ 0.1615819E-11 0.3930800E-08 0.2194848E-03 6.3356 12 K+ 0.5500752E-04 0.5505374E-04 0.2152333E+01 4.8244 13 Na+ 0.1772200E-02 0.1791082E-02 0.4116938E+02 6.3324 14 Mn++ 0.2158878E-09 0.1260260E-08 0.6922398E-04 8.4615 15 HPO4-- 0.7591168E-05 0.7688861E-05 0.7378396E+00 13.0081 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2149647E-01 -.1715743E-02 -.1978073E-01 0.0000000E+00 2 H2O 0.5549197E+02 0.5549447E+02 -.2506171E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6150419E-04 0.2550467E-04 0.3599952E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3599972E-04 -.1994768E-09 -.3599952E-04 0.0000000E+00 7 Al+++ 0.4235703E-02 0.2914904E-04 0.4206554E-02 0.0000000E+00 8 H4SiO4 0.1352621E-01 0.1289527E-02 0.1223668E-01 0.0000000E+00 9 Ca++ 0.1508506E-02 0.1969713E-07 0.1508487E-02 0.0000000E+00 10 Mg++ 0.1030952E-02 0.3963438E-09 0.1030952E-02 0.0000000E+00 11 Fe++ 0.9261982E-03 0.3929814E-08 0.9261942E-03 0.0000000E+00 12 K+ 0.2757962E-03 0.5503993E-04 0.2207563E-03 0.0000000E+00 13 Na+ 0.1790632E-02 0.1790632E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2252284E-04 0.1259943E-08 0.2252158E-04 0.0000000E+00 15 HPO4-- 0.7686932E-05 0.7686932E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1220E-17 Mass of aqueous solution: 0.999925E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.2990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2062E-03 -3.686 0.1146 -0.941 8.342 0.4359E-01 daphnite 0.1276E-03 -3.894 0.9107E-01 -1.041 6.629 0.2760E-01 chlorite-Mn 0.4504E-05 -5.346 0.3193E-02 -2.496 0.2324 0.1018E-02 hematite 0.1440E-03 -3.842 0.2300E-01 -1.638 1.674 0.4359E-02 microcline 0.7468E-04 -4.127 0.2079E-01 -1.682 1.513 0.8120E-02 muscovite 0.1461E-03 -3.835 0.5818E-01 -1.235 4.235 0.2057E-01 stilbite 0.1508E-02 -2.821 1.063 0.027 77.38 0.4958 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.373900 g Volume = 0.601092 cm3 Porosity: 60.4441% V(tot) - V(min): 0.91851E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.2990000 g log = 0.1136 Original solution: 1000.0103000 g Original solution / Rock added: 769.83 (Water/Rock Ratio), log = 2.8864 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1771E-05 1.0073 0.1876E-05 0.1863E-05 CH4,gas 0.2333E-16 1.0129 0.2486E-16 0.2454E-16 H2,gas 0.5815E-06 1.0006 0.6120E-06 0.6117E-06 H2S,gas 0.1939E-14 0.9959 0.2031E-14 0.2040E-14 S2,gas 0.3923E-36 1.0000 0.4127E-36 0.4127E-36 CO,gas 0.2827E-15 1.0000 0.2974E-15 0.2974E-15 SO3,gas 0.4180E-38 1.0000 0.4397E-38 0.4397E-38 SO2,gas 0.9678E-22 1.0000 0.1018E-21 0.1018E-21 HCl,gas 0.3098E-16 1.0000 0.3259E-16 0.3259E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.09 -7.73 -2.576 0.13193E+05 -5.727 3 CH4,gas 4.81 -13.80 -18.60 -4.651 0.31767E+05 -16.604 4 H2,gas 8.29 0.07 -8.21 -4.693 0.14024E+05 -6.213 5 H2S,gas -5.94 -22.63 -16.69 -8.346 0.28501E+05 -14.692 6 S2,gas -7.03 -45.42 -38.38 -5.905 0.65540E+05 -36.384 7 CO,gas 3.51 -14.02 -17.53 -5.393 0.29926E+05 -15.527 8 SO3,gas 17.43 -22.93 -40.36 -10.089 0.68908E+05 -38.357 9 SO2,gas 1.14 -22.86 -23.99 -6.398 0.40966E+05 -21.992 10 HCl,gas 5.48 -13.01 -18.49 -9.243 0.31566E+05 -16.487 11 acmite 7.74 6.09 -1.65 -0.171 0.28127E+04 15 albite-high 0.75 -0.92 -1.67 -0.129 0.28574E+04 16 albite -0.33 -0.92 -0.60 -0.046 0.10167E+04 19 spessartine 24.55 20.68 -3.87 -0.193 0.66013E+04 20 analcite 3.37 2.35 -1.02 -0.114 0.17482E+04 21 andalusite 5.06 1.84 -3.22 -0.322 0.55014E+04 26 annite 20.21 16.58 -3.63 -0.202 0.62053E+04 27 phlogopite 27.15 23.26 -3.89 -0.216 0.66375E+04 29 anorthite 12.80 8.95 -3.85 -0.296 0.65749E+04 32 apatite-OH -17.99 -18.48 -0.49 -0.038 0.84029E+03 35 aragonite 0.99 -3.71 -4.70 -1.566 0.80234E+04 36 brucite 12.58 8.56 -4.01 -0.803 0.68519E+04 37 calcite 0.83 -3.71 -4.55 -1.515 0.77620E+04 38 carnegieite-low 9.06 5.62 -3.45 -0.492 0.58860E+04 39 carnegieite-high 10.13 5.62 -4.52 -0.645 0.77129E+04 40 carpholite-Mg 8.65 7.13 -1.52 -0.101 0.25900E+04 41 carpholite-Fe 6.78 4.91 -1.88 -0.125 0.32056E+04 42 celadonite 5.40 2.86 -2.54 -0.149 0.43356E+04 43 celadonite-Fe 3.94 0.63 -3.30 -0.194 0.56409E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81744E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.190 0.48785E+04 51 chloritoid-Fe 9.24 8.18 -1.06 -0.071 0.18144E+04 52 chloritoid-Mn 11.46 10.30 -1.16 -0.077 0.19829E+04 54 coesite -2.37 -3.27 -0.90 -0.300 0.15388E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.27 -0.72 -0.240 0.12317E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.40 -3.82 -0.382 0.65153E+04 68 hedenbergite 14.24 10.17 -4.07 -0.407 0.69541E+04 75 epidote 24.78 22.35 -2.42 -0.117 0.41368E+04 76 clinozoisite 22.92 18.61 -4.31 -0.196 0.73626E+04 77 epidote-Fe 29.94 26.10 -3.84 -0.200 0.65584E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79880E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.47 -3.73 -0.311 0.63662E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.35 -1.90 -0.190 0.32513E+04 97 kalsilite 7.62 4.11 -3.51 -0.502 0.59948E+04 98 kaolinite -1.27 -1.43 -0.16 -0.014 0.26811E+03 99 kyanite 4.93 1.84 -3.09 -0.309 0.52782E+04 101 laumontite 2.97 2.41 -0.57 -0.038 0.97099E+03 102 lawsonite 9.68 8.95 -0.73 -0.049 0.12488E+04 103 leucite 4.17 0.84 -3.33 -0.333 0.56839E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70647E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20482E+04 108 minnesotaite 10.46 5.92 -4.54 -0.267 0.77453E+04 113 margarite 17.45 14.06 -3.39 -0.136 0.57948E+04 121 paragonite 4.34 4.19 -0.15 -0.009 0.25517E+03 122 nepheline 8.38 5.62 -2.76 -0.394 0.47139E+04 134 phlogopite-Na 29.73 24.77 -4.96 -0.276 0.84761E+04 136 prehnite 19.47 16.05 -3.41 -0.201 0.58271E+04 137 prehnite-Fe 22.59 19.80 -2.79 -0.168 0.47635E+04 145 pyroxmangite 7.42 5.19 -2.23 -0.445 0.37993E+04 146 pyrophyllite -6.10 -7.97 -1.87 -0.117 0.31986E+04 147 quartz -2.98 -3.27 -0.29 -0.096 0.49274E+03 151 rhodochrosite -0.96 -5.63 -4.67 -1.557 0.79737E+04 152 rhodonite 7.46 5.19 -2.27 -0.454 0.38785E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.84 -3.48 -0.348 0.59436E+04 164 stilpnomelane-Fe 13.18 13.04 -0.14 -0.004 0.24346E+03 165 stilpnomelane-Mg 27.60 24.18 -3.42 -0.102 0.58383E+04 168 sudoite 21.22 17.54 -3.68 -0.119 0.62811E+04 171 talc 16.55 12.61 -3.94 -0.232 0.67353E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76161E+04 177 topaz-H 4.67 1.84 -2.83 -0.257 0.48273E+04 178 tridymite -2.61 -3.27 -0.66 -0.219 0.11200E+04 187 wairakite 4.06 2.41 -1.65 -0.097 0.28218E+04 188 walstromite 11.53 7.11 -4.42 -0.884 0.75492E+04 189 wollastonite 10.48 7.11 -3.38 -0.675 0.57631E+04 190 pseudo-wollastonite 11.02 7.11 -3.91 -0.783 0.66817E+04 191 zoisite 22.96 18.61 -4.35 -0.198 0.74352E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.34 -2.78 -0.172 0.47413E+04 194 beidellite-H -2.24 -6.05 -3.81 -0.243 0.65014E+04 195 beidellite-K -1.44 -4.46 -3.02 -0.185 0.51593E+04 196 beidellite-Mg -1.71 -4.64 -2.93 -0.181 0.50009E+04 197 beidellite-Na -1.26 -3.96 -2.70 -0.165 0.46136E+04 199 chalcedony -2.79 -3.27 -0.48 -0.159 0.81305E+03 201 montmorillonite-Ca -2.21 -4.28 -2.06 -0.128 0.35214E+04 202 montmorillonite-K -2.16 -4.40 -2.24 -0.137 0.38172E+04 203 montmorillonite-Mg -2.40 -4.58 -2.17 -0.134 0.37120E+04 204 montmorillonite-Na -1.96 -3.90 -1.94 -0.119 0.33096E+04 205 nontronite-Ca 3.28 3.15 -0.13 -0.008 0.22112E+03 206 nontronite-H 2.60 1.44 -1.16 -0.078 0.19769E+04 207 nontronite-K 3.40 3.03 -0.37 -0.024 0.63832E+03 208 nontronite-Mg 3.14 2.85 -0.29 -0.019 0.49231E+03 209 nontronite-Na 3.58 3.53 -0.06 -0.004 0.94254E+02 224 tobermorite 9.84 5.37 -4.47 -1.218 0.76245E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.34 -3.49 -0.872 0.59567E+04 240 silica-amorphous -2.08 -3.27 -1.19 -0.397 0.20333E+04 242 an20ab80 2.08 1.05 -1.03 -0.079 0.17567E+04 243 an25ab75 2.71 1.54 -1.17 -0.090 0.19896E+04 244 an30ab70 3.34 2.04 -1.31 -0.101 0.22309E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 1.2990000 g New total amount of reactant added: 1.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4567E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.3990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1265189E-02 Osmotic coef. = 0.9796 True ionic strength = .1979201E-02 Chg. balance for total moles = 0.4567E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.77854E-09 -9.1087 0.72262E-09 -9.1411 0.92817E+00 -0.0324 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12793E-03 -3.8930 0.92742E+00 -0.0327 4 SO4-- 0.25496E-04 -4.5935 0.19936E-04 -4.7004 0.78191E+00 -0.1068 5 HCO3- 0.11337E-04 -4.9455 0.10516E-04 -4.9782 0.92760E+00 -0.0326 6 HS- 0.27683E-13 -13.5578 0.25674E-13 -13.5905 0.92744E+00 -0.0327 7 Al+++ 0.23104E-24 -24.6363 0.13559E-24 -24.8678 0.58687E+00 -0.2315 8 H4SiO4 0.54768E-03 -3.2615 0.54768E-03 -3.2615 0.10000E+01 0.0000 9 Ca++ 0.13757E-07 -7.8615 0.10747E-07 -7.9687 0.78116E+00 -0.1073 10 Mg++ 0.24186E-09 -9.6164 0.18882E-09 -9.7240 0.78068E+00 -0.1075 11 Fe++ 0.14304E-11 -11.8445 0.11168E-11 -11.9520 0.78080E+00 -0.1075 12 K+ 0.48827E-04 -4.3113 0.45293E-04 -4.3440 0.92764E+00 -0.0326 13 Na+ 0.18949E-02 -2.7224 0.17573E-02 -2.7551 0.92741E+00 -0.0327 14 Mn++ 0.19111E-09 -9.7187 0.14924E-09 -9.8261 0.78088E+00 -0.1074 15 HPO4-- 0.81805E-05 -5.0872 0.63965E-05 -5.1941 0.78193E+00 -0.1068 16 HSiO3- 0.79734E-03 -3.0984 0.73947E-03 -3.1311 0.92742E+00 -0.0327 17 Ca(HSiO3)+ 0.19194E-09 -9.7168 0.17805E-09 -9.7495 0.92766E+00 -0.0326 18 Mg(HSiO3)+ 0.41968E-11 -11.3771 0.38932E-11 -11.4097 0.92766E+00 -0.0326 19 NaHSiO3,aq 0.20639E-04 -4.6853 0.20639E-04 -4.6853 0.10000E+01 0.0000 20 AlO+ 0.36135E-13 -13.4421 0.33521E-13 -13.4747 0.92766E+00 -0.0326 21 AlOH+2 0.15537E-18 -18.8086 0.12134E-18 -18.9160 0.78098E+00 -0.1074 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.30936E-04 -4.5095 0.28683E-04 -4.5424 0.92720E+00 -0.0328 24 CH4,aq 0.13294E-19 -19.8763 0.13289E-19 -19.8765 0.99961E+00 -0.0002 29 CO,aq 0.17170E-18 -18.7652 0.17170E-18 -18.7652 0.10000E+01 0.0000 30 CO2,aq 0.15327E-07 -7.8145 0.15321E-07 -7.8147 0.99961E+00 -0.0002 31 CO3-2 0.17213E-05 -5.7641 0.13455E-05 -5.8711 0.78169E+00 -0.1070 32 CaCO3,aq 0.17710E-09 -9.7518 0.17710E-09 -9.7518 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.30696E-11 -11.5129 0.28476E-11 -11.5455 0.92766E+00 -0.0326 34 CaCl+ 0.23615E-11 -11.6268 0.21907E-11 -11.6594 0.92766E+00 -0.0326 35 CaCl2,aq 0.65253E-16 -16.1854 0.65253E-16 -16.1854 0.10000E+01 0.0000 36 CaOH+ 0.11304E-08 -8.9468 0.10487E-08 -8.9794 0.92766E+00 -0.0326 37 CaSO4,aq 0.66753E-10 -10.1755 0.66753E-10 -10.1755 0.10000E+01 0.0000 38 HCl,aq 0.17388E-13 -13.7597 0.17388E-13 -13.7597 0.10000E+01 0.0000 43 FeCl+ 0.23988E-15 -15.6200 0.22253E-15 -15.6526 0.92766E+00 -0.0326 46 FeO,aq 0.84577E-10 -10.0727 0.84577E-10 -10.0727 0.10000E+01 0.0000 47 FeOH+ 0.55234E-10 -10.2578 0.51238E-10 -10.2904 0.92766E+00 -0.0326 48 HFeO2- 0.13574E-08 -8.8673 0.12589E-08 -8.9000 0.92742E+00 -0.0327 49 FeO+ 0.64437E-14 -14.1909 0.59776E-14 -14.2235 0.92766E+00 -0.0326 51 FeO2- 0.24260E-08 -8.6151 0.22499E-08 -8.6478 0.92742E+00 -0.0327 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.43528E-09 -9.3612 0.43511E-09 -9.3614 0.99961E+00 -0.0002 54 KCl,aq 0.10260E-09 -9.9889 0.10260E-09 -9.9889 0.10000E+01 0.0000 55 KHSO4,aq 0.17461E-17 -17.7579 0.17461E-17 -17.7579 0.10000E+01 0.0000 56 KOH,aq 0.27325E-07 -7.5634 0.27325E-07 -7.5634 0.10000E+01 0.0000 57 KSO4- 0.15000E-07 -7.8239 0.13911E-07 -7.8566 0.92742E+00 -0.0327 58 MgCO3,aq 0.77752E-12 -12.1093 0.77752E-12 -12.1093 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.54996E-13 -13.2597 0.51018E-13 -13.2923 0.92766E+00 -0.0326 60 MgCl+ 0.37667E-13 -13.4240 0.34942E-13 -13.4566 0.92766E+00 -0.0326 61 MgOH+ 0.11003E-09 -9.9585 0.10207E-09 -9.9911 0.92766E+00 -0.0326 63 MnO,aq 0.30170E-09 -9.5204 0.30170E-09 -9.5204 0.10000E+01 0.0000 64 MnOH+ 0.68563E-09 -9.1639 0.63603E-09 -9.1965 0.92766E+00 -0.0326 65 MnO2-2 0.25561E-13 -13.5924 0.19981E-13 -13.6994 0.78169E+00 -0.1070 66 HMnO2- 0.33731E-11 -11.4720 0.31283E-11 -11.5047 0.92742E+00 -0.0327 69 MnCl+ 0.12456E-12 -12.9046 0.11554E-12 -12.9372 0.92766E+00 -0.0326 70 MnSO4,aq 0.84316E-12 -12.0741 0.84316E-12 -12.0741 0.10000E+01 0.0000 71 NaCl,aq 0.73406E-07 -7.1343 0.73406E-07 -7.1343 0.10000E+01 0.0000 72 NaOH,aq 0.10686E-05 -5.9712 0.10686E-05 -5.9712 0.10000E+01 0.0000 74 OH- 0.89526E-03 -3.0481 0.83008E-03 -3.0809 0.92720E+00 -0.0328 79 HPO3-2 0.11246E-16 -16.9490 0.87909E-17 -17.0560 0.78169E+00 -0.1070 81 H2PO3- 0.13455E-19 -19.8711 0.12478E-19 -19.9038 0.92742E+00 -0.0327 82 H3PO4,aq 0.21504E-13 -13.6675 0.21504E-13 -13.6675 0.10000E+01 0.0000 83 H2PO4- 0.87368E-07 -7.0586 0.81037E-07 -7.0913 0.92754E+00 -0.0327 84 PO4-3 0.13086E-07 -7.8832 0.77304E-08 -8.1118 0.59073E+00 -0.2286 87 H2P2O7-2 0.65751E-15 -15.1821 0.51397E-15 -15.2891 0.78169E+00 -0.1070 88 HP2O7-3 0.24850E-12 -12.6047 0.14585E-12 -12.8361 0.58691E+00 -0.2314 89 P2O7-4 0.12619E-12 -12.8990 0.49791E-13 -13.3028 0.39456E+00 -0.4039 90 H2S,aq 0.55764E-16 -16.2536 0.55742E-16 -16.2538 0.99961E+00 -0.0002 97 SO3-2 0.15101E-14 -14.8210 0.11827E-14 -14.9271 0.78320E+00 -0.1061 98 HSO3- 0.53931E-16 -16.2682 0.50017E-16 -16.3009 0.92742E+00 -0.0327 99 HSO4- 0.14407E-10 -10.8414 0.13367E-10 -10.8740 0.92778E+00 -0.0326 Charge balance for all species = 0.4570E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7785403E-09 -.1839749E-02 -.1854012E+01 0.0000 2 H2O 0.1000000E+01 0.5550839E+02 0.9998149E+06 0.0000 3 Cl- 0.1379378E-03 0.1380113E-03 0.4892007E+01 5.2481 4 SO4-- 0.2549625E-04 0.2551155E-04 0.2450226E+01 13.5818 5 HCO3- 0.1133670E-04 0.1307352E-04 0.7975614E+00 4.1629 6 HS- 0.2768268E-13 -.2198302E-09 -.7268875E-05 -4.4494 7 Al+++ 0.2310373E-24 0.3094490E-04 0.8347849E+00 2.5555 8 H4SiO4 0.5476816E-03 0.1365658E-02 0.1312365E+03 -3.2615 9 Ca++ 0.1375742E-07 0.1532907E-07 0.6142445E-03 10.3135 10 Mg++ 0.2418605E-09 0.3569605E-09 0.8676814E-05 8.5582 11 Fe++ 0.1430382E-11 0.4128105E-08 0.2304995E-03 6.3302 12 K+ 0.4882683E-04 0.4886926E-04 0.1910531E+01 4.7971 13 Na+ 0.1894891E-02 0.1916672E-02 0.4405574E+02 6.3859 14 Mn++ 0.1911118E-09 0.1182804E-08 0.6496882E-04 8.4561 15 HPO4-- 0.8180461E-05 0.8280916E-05 0.7946467E+00 13.0881 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2315232E-01 -.1839254E-02 -.2131307E-01 0.0000000E+00 2 H2O 0.5549071E+02 0.5549347E+02 -.2752957E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6427553E-04 0.2550469E-04 0.3877084E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3877106E-04 -.2197711E-09 -.3877084E-04 0.0000000E+00 7 Al+++ 0.4561778E-02 0.3093658E-04 0.4530841E-02 0.0000000E+00 8 H4SiO4 0.1456748E-01 0.1365291E-02 0.1320219E-01 0.0000000E+00 9 Ca++ 0.1623521E-02 0.1532495E-07 0.1623505E-02 0.0000000E+00 10 Mg++ 0.1110317E-02 0.3568645E-09 0.1110317E-02 0.0000000E+00 11 Fe++ 0.9974990E-03 0.4126995E-08 0.9974949E-03 0.0000000E+00 12 K+ 0.2970276E-03 0.4885612E-04 0.2481715E-03 0.0000000E+00 13 Na+ 0.1916157E-02 0.1916157E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2425670E-04 0.1182486E-08 0.2425551E-04 0.0000000E+00 15 HPO4-- 0.8278690E-05 0.8278690E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.8403E-18 Mass of aqueous solution: 0.999917E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2221E-03 -3.654 0.1234 -0.909 8.332 0.4695E-01 daphnite 0.1375E-03 -3.862 0.9808E-01 -1.008 6.621 0.2972E-01 chlorite-Mn 0.4851E-05 -5.314 0.3439E-02 -2.464 0.2322 0.1096E-02 hematite 0.1551E-03 -3.809 0.2477E-01 -1.606 1.672 0.4694E-02 microcline 0.9472E-04 -4.024 0.2636E-01 -1.579 1.780 0.1030E-01 muscovite 0.1534E-03 -3.814 0.6112E-01 -1.214 4.126 0.2161E-01 stilbite 0.1624E-02 -2.790 1.144 0.058 77.24 0.5336 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.481321 g Volume = 0.648010 cm3 Porosity: 58.4503% V(tot) - V(min): 0.91159E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.3990000 g log = 0.1458 Original solution: 1000.0103000 g Original solution / Rock added: 714.80 (Water/Rock Ratio), log = 2.8542 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1655E-05 1.0073 0.1754E-05 0.1741E-05 CH4,gas 0.1972E-16 1.0129 0.2102E-16 0.2075E-16 H2,gas 0.5670E-06 1.0006 0.5968E-06 0.5965E-06 H2S,gas 0.1552E-14 0.9959 0.1626E-14 0.1632E-14 S2,gas 0.2642E-36 1.0000 0.2780E-36 0.2780E-36 CO,gas 0.2577E-15 1.0000 0.2711E-15 0.2711E-15 SO3,gas 0.3700E-38 1.0000 0.3892E-38 0.3892E-38 SO2,gas 0.8353E-22 1.0000 0.8786E-22 0.8786E-22 HCl,gas 0.2919E-16 1.0000 0.3070E-16 0.3070E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.12 -7.76 -2.585 0.13243E+05 -5.756 3 CH4,gas 4.81 -13.87 -18.68 -4.669 0.31891E+05 -16.677 4 H2,gas 8.29 0.06 -8.22 -4.700 0.14043E+05 -6.224 5 H2S,gas -5.94 -22.73 -16.79 -8.394 0.28667E+05 -14.789 6 S2,gas -7.03 -45.59 -38.56 -5.932 0.65833E+05 -36.556 7 CO,gas 3.51 -14.06 -17.57 -5.405 0.29995E+05 -15.567 8 SO3,gas 17.43 -22.98 -40.41 -10.102 0.68999E+05 -38.410 9 SO2,gas 1.14 -22.92 -24.06 -6.415 0.41075E+05 -22.056 10 HCl,gas 5.48 -13.03 -18.51 -9.256 0.31610E+05 -16.513 11 acmite 7.74 6.16 -1.58 -0.164 0.26903E+04 15 albite-high 0.75 -0.84 -1.59 -0.123 0.27193E+04 16 albite -0.33 -0.84 -0.51 -0.040 0.87869E+03 19 spessartine 24.55 20.69 -3.86 -0.193 0.65826E+04 20 analcite 3.37 2.42 -0.95 -0.106 0.16258E+04 21 andalusite 5.06 1.85 -3.21 -0.321 0.54859E+04 26 annite 20.21 16.56 -3.65 -0.203 0.62333E+04 27 phlogopite 27.15 23.24 -3.90 -0.217 0.66655E+04 29 anorthite 12.80 8.90 -3.90 -0.300 0.66526E+04 32 apatite-OH -17.99 -18.86 -0.87 -0.067 0.14900E+04 35 aragonite 0.99 -3.81 -4.79 -1.597 0.81822E+04 36 brucite 12.58 8.56 -4.02 -0.804 0.68613E+04 37 calcite 0.83 -3.81 -4.64 -1.546 0.79209E+04 38 carnegieite-low 9.06 5.68 -3.38 -0.484 0.57791E+04 39 carnegieite-high 10.13 5.68 -4.45 -0.636 0.76059E+04 40 carpholite-Mg 8.65 7.15 -1.50 -0.100 0.25682E+04 41 carpholite-Fe 6.78 4.92 -1.86 -0.124 0.31839E+04 42 celadonite 5.40 2.86 -2.54 -0.149 0.43294E+04 43 celadonite-Fe 3.94 0.64 -3.30 -0.194 0.56347E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81713E+04 50 chloritoid-Mg 13.26 10.41 -2.85 -0.190 0.48723E+04 51 chloritoid-Fe 9.24 8.18 -1.06 -0.071 0.18082E+04 52 chloritoid-Mn 11.46 10.31 -1.16 -0.077 0.19766E+04 54 coesite -2.37 -3.26 -0.89 -0.297 0.15233E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.26 -0.71 -0.237 0.12162E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.35 -3.87 -0.387 0.66023E+04 68 hedenbergite 14.24 10.12 -4.12 -0.412 0.70412E+04 75 epidote 24.78 22.25 -2.52 -0.122 0.43078E+04 76 clinozoisite 22.92 18.51 -4.41 -0.201 0.75337E+04 77 epidote-Fe 29.94 26.00 -3.94 -0.205 0.67294E+04 78 fayalite 14.08 9.40 -4.68 -0.669 0.79911E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.47 -3.73 -0.311 0.63631E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.42 -1.83 -0.183 0.31288E+04 97 kalsilite 7.62 4.09 -3.53 -0.504 0.60259E+04 98 kaolinite -1.27 -1.41 -0.14 -0.013 0.23702E+03 99 kyanite 4.93 1.85 -3.08 -0.308 0.52626E+04 101 laumontite 2.97 2.38 -0.60 -0.040 0.10176E+04 102 lawsonite 9.68 8.90 -0.78 -0.052 0.13265E+04 103 leucite 4.17 0.83 -3.34 -0.334 0.56995E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70616E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20575E+04 108 minnesotaite 10.46 5.94 -4.52 -0.266 0.77111E+04 113 margarite 17.45 14.01 -3.44 -0.138 0.58725E+04 121 paragonite 4.34 4.27 -0.07 -0.004 0.11716E+03 122 nepheline 8.38 5.68 -2.70 -0.385 0.46070E+04 134 phlogopite-Na 29.73 24.83 -4.90 -0.272 0.83661E+04 136 prehnite 19.47 15.95 -3.51 -0.207 0.59981E+04 137 prehnite-Fe 22.59 19.70 -2.89 -0.174 0.49345E+04 145 pyroxmangite 7.42 5.19 -2.22 -0.444 0.37931E+04 146 pyrophyllite -6.10 -7.93 -1.84 -0.115 0.31364E+04 147 quartz -2.98 -3.26 -0.28 -0.093 0.47719E+03 151 rhodochrosite -0.96 -5.66 -4.70 -1.568 0.80331E+04 152 rhodonite 7.46 5.19 -2.27 -0.454 0.38723E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.85 -3.47 -0.347 0.59280E+04 164 stilpnomelane-Fe 13.18 13.07 -0.11 -0.003 0.18904E+03 165 stilpnomelane-Mg 27.60 24.21 -3.39 -0.101 0.57839E+04 168 sudoite 21.22 17.55 -3.66 -0.118 0.62531E+04 171 talc 16.55 12.63 -3.92 -0.231 0.67011E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76192E+04 177 topaz-H 4.67 1.85 -2.82 -0.256 0.48117E+04 178 tridymite -2.61 -3.26 -0.65 -0.216 0.11045E+04 187 wairakite 4.06 2.38 -1.68 -0.099 0.28684E+04 188 walstromite 11.53 7.05 -4.48 -0.895 0.76425E+04 189 wollastonite 10.48 7.05 -3.43 -0.686 0.58563E+04 190 pseudo-wollastonite 11.02 7.05 -3.97 -0.794 0.67750E+04 191 zoisite 22.96 18.51 -4.45 -0.202 0.76062E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.31 -2.75 -0.170 0.47022E+04 194 beidellite-H -2.24 -6.02 -3.77 -0.241 0.64443E+04 195 beidellite-K -1.44 -4.43 -3.00 -0.184 0.51177E+04 196 beidellite-Mg -1.71 -4.60 -2.90 -0.179 0.49454E+04 197 beidellite-Na -1.26 -3.91 -2.65 -0.162 0.45264E+04 199 chalcedony -2.79 -3.26 -0.47 -0.156 0.79751E+03 201 montmorillonite-Ca -2.21 -4.25 -2.04 -0.126 0.34803E+04 202 montmorillonite-K -2.16 -4.37 -2.21 -0.135 0.37735E+04 203 montmorillonite-Mg -2.40 -4.54 -2.14 -0.132 0.36544E+04 204 montmorillonite-Na -1.96 -3.85 -1.89 -0.115 0.32203E+04 205 nontronite-Ca 3.28 3.17 -0.11 -0.007 0.18202E+03 206 nontronite-H 2.60 1.47 -1.12 -0.075 0.19199E+04 207 nontronite-K 3.40 3.05 -0.35 -0.022 0.59665E+03 208 nontronite-Mg 3.14 2.88 -0.26 -0.017 0.43680E+03 209 nontronite-Na 3.58 3.58 0.00 0.000 0.70443E+01 224 tobermorite 9.84 5.33 -4.51 -1.230 0.76996E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.874 0.59660E+04 240 silica-amorphous -2.08 -3.26 -1.18 -0.394 0.20177E+04 242 an20ab80 2.08 1.11 -0.97 -0.075 0.16619E+04 243 an25ab75 2.71 1.59 -1.12 -0.086 0.19056E+04 244 an30ab70 3.34 2.08 -1.26 -0.097 0.21576E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 1.3990000 g New total amount of reactant added: 1.4990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4567E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.4990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1334363E-02 Osmotic coef. = 0.9791 True ionic strength = .2096972E-02 Chg. balance for total moles = 0.4567E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.73915E-09 -9.1313 0.68501E-09 -9.1643 0.92674E+00 -0.0330 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12772E-03 -3.8937 0.92596E+00 -0.0334 4 SO4-- 0.25498E-04 -4.5935 0.19813E-04 -4.7030 0.77705E+00 -0.1096 5 HCO3- 0.11249E-04 -4.9489 0.10418E-04 -4.9822 0.92614E+00 -0.0333 6 HS- 0.23565E-13 -13.6277 0.21820E-13 -13.6611 0.92598E+00 -0.0334 7 Al+++ 0.19961E-24 -24.6998 0.11550E-24 -24.9374 0.57863E+00 -0.2376 8 H4SiO4 0.55956E-03 -3.2521 0.55956E-03 -3.2521 0.10000E+01 0.0000 9 Ca++ 0.10705E-07 -7.9704 0.83098E-08 -8.0804 0.77626E+00 -0.1100 10 Mg++ 0.21592E-09 -9.6657 0.16750E-09 -9.7760 0.77576E+00 -0.1103 11 Fe++ 0.12769E-11 -11.8938 0.99075E-12 -12.0040 0.77588E+00 -0.1102 12 K+ 0.43467E-04 -4.3618 0.40258E-04 -4.3951 0.92618E+00 -0.0333 13 Na+ 0.20173E-02 -2.6952 0.18679E-02 -2.7286 0.92594E+00 -0.0334 14 Mn++ 0.17061E-09 -9.7680 0.13239E-09 -9.8781 0.77597E+00 -0.1102 15 HPO4-- 0.87697E-05 -5.0570 0.68146E-05 -5.1666 0.77706E+00 -0.1095 16 HSiO3- 0.86073E-03 -3.0651 0.79700E-03 -3.0985 0.92596E+00 -0.0334 17 Ca(HSiO3)+ 0.16021E-09 -9.7953 0.14839E-09 -9.8286 0.92621E+00 -0.0333 18 Mg(HSiO3)+ 0.40190E-11 -11.3959 0.37224E-11 -11.4292 0.92621E+00 -0.0333 19 NaHSiO3,aq 0.23645E-04 -4.6263 0.23645E-04 -4.6263 0.10000E+01 0.0000 20 AlO+ 0.34308E-13 -13.4646 0.31776E-13 -13.4979 0.92621E+00 -0.0333 21 AlOH+2 0.14050E-18 -18.8523 0.10904E-18 -18.9624 0.77607E+00 -0.1101 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.32686E-04 -4.4856 0.30258E-04 -4.5192 0.92572E+00 -0.0335 24 CH4,aq 0.11263E-19 -19.9483 0.11258E-19 -19.9485 0.99959E+00 -0.0002 29 CO,aq 0.15715E-18 -18.8037 0.15715E-18 -18.8037 0.10000E+01 0.0000 30 CO2,aq 0.14395E-07 -7.8418 0.14389E-07 -7.8420 0.99959E+00 -0.0002 31 CO3-2 0.18102E-05 -5.7423 0.14062E-05 -5.8520 0.77681E+00 -0.1097 32 CaCO3,aq 0.14312E-09 -9.8443 0.14312E-09 -9.8443 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.23552E-11 -11.6280 0.21814E-11 -11.6613 0.92621E+00 -0.0333 34 CaCl+ 0.18260E-11 -11.7385 0.16912E-11 -11.7718 0.92621E+00 -0.0333 35 CaCl2,aq 0.50295E-16 -16.2985 0.50295E-16 -16.2985 0.10000E+01 0.0000 36 CaOH+ 0.92354E-09 -9.0345 0.85539E-09 -9.0678 0.92621E+00 -0.0333 37 CaSO4,aq 0.51300E-10 -10.2899 0.51300E-10 -10.2899 0.10000E+01 0.0000 38 HCl,aq 0.16457E-13 -13.7837 0.16457E-13 -13.7837 0.10000E+01 0.0000 43 FeCl+ 0.21279E-15 -15.6720 0.19709E-15 -15.7053 0.92621E+00 -0.0333 46 FeO,aq 0.83495E-10 -10.0783 0.83495E-10 -10.0783 0.10000E+01 0.0000 47 FeOH+ 0.51770E-10 -10.2859 0.47950E-10 -10.3192 0.92621E+00 -0.0333 48 HFeO2- 0.14159E-08 -8.8490 0.13110E-08 -8.8824 0.92596E+00 -0.0334 49 FeO+ 0.61179E-14 -14.2134 0.56665E-14 -14.2467 0.92621E+00 -0.0333 51 FeO2- 0.25632E-08 -8.5912 0.23734E-08 -8.6246 0.92596E+00 -0.0334 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.42422E-09 -9.3724 0.42405E-09 -9.3726 0.99959E+00 -0.0002 54 KCl,aq 0.91045E-10 -10.0407 0.91045E-10 -10.0407 0.10000E+01 0.0000 55 KHSO4,aq 0.14621E-17 -17.8350 0.14621E-17 -17.8350 0.10000E+01 0.0000 56 KOH,aq 0.25621E-07 -7.5914 0.25621E-07 -7.5914 0.10000E+01 0.0000 57 KSO4- 0.13272E-07 -7.8771 0.12289E-07 -7.9105 0.92596E+00 -0.0334 58 MgCO3,aq 0.72085E-12 -12.1422 0.72085E-12 -12.1422 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.48410E-13 -13.3151 0.44838E-13 -13.3484 0.92621E+00 -0.0333 60 MgCl+ 0.33414E-13 -13.4761 0.30948E-13 -13.5094 0.92621E+00 -0.0333 61 MgOH+ 0.10313E-09 -9.9866 0.95522E-10 -10.0199 0.92621E+00 -0.0333 63 MnO,aq 0.29784E-09 -9.5260 0.29784E-09 -9.5260 0.10000E+01 0.0000 64 MnOH+ 0.64264E-09 -9.1920 0.59521E-09 -9.2253 0.92621E+00 -0.0333 65 MnO2-2 0.28258E-13 -13.5489 0.21951E-13 -13.6585 0.77681E+00 -0.1097 66 HMnO2- 0.35184E-11 -11.4537 0.32579E-11 -11.4871 0.92596E+00 -0.0334 69 MnCl+ 0.11049E-12 -12.9567 0.10234E-12 -12.9900 0.92621E+00 -0.0333 70 MnSO4,aq 0.74339E-12 -12.1288 0.74339E-12 -12.1288 0.10000E+01 0.0000 71 NaCl,aq 0.77902E-07 -7.1085 0.77902E-07 -7.1085 0.10000E+01 0.0000 72 NaOH,aq 0.11982E-05 -5.9215 0.11982E-05 -5.9215 0.10000E+01 0.0000 74 OH- 0.94593E-03 -3.0241 0.87566E-03 -3.0577 0.92572E+00 -0.0335 79 HPO3-2 0.11750E-16 -16.9300 0.91273E-17 -17.0397 0.77681E+00 -0.1097 81 H2PO3- 0.13264E-19 -19.8773 0.12282E-19 -19.9107 0.92596E+00 -0.0334 82 H3PO4,aq 0.20586E-13 -13.6864 0.20586E-13 -13.6864 0.10000E+01 0.0000 83 H2PO4- 0.88373E-07 -7.0537 0.81840E-07 -7.0870 0.92608E+00 -0.0334 84 PO4-3 0.14911E-07 -7.8265 0.86879E-08 -8.0611 0.58265E+00 -0.2346 87 H2P2O7-2 0.67482E-15 -15.1708 0.52420E-15 -15.2805 0.77681E+00 -0.1097 88 HP2O7-3 0.27117E-12 -12.5668 0.15692E-12 -12.8043 0.57867E+00 -0.2376 89 P2O7-4 0.14684E-12 -12.8331 0.56513E-13 -13.2479 0.38485E+00 -0.4147 90 H2S,aq 0.44928E-16 -16.3475 0.44909E-16 -16.3477 0.99959E+00 -0.0002 97 SO3-2 0.14717E-14 -14.8322 0.11456E-14 -14.9410 0.77840E+00 -0.1088 98 HSO3- 0.49596E-16 -16.3046 0.45924E-16 -16.3380 0.92596E+00 -0.0334 99 HSO4- 0.13595E-10 -10.8666 0.12593E-10 -10.8999 0.92633E+00 -0.0332 Charge balance for all species = 0.4571E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7391531E-09 -.1964038E-02 -.1979246E+01 0.0000 2 H2O 0.1000000E+01 0.5550838E+02 0.9998047E+06 0.0000 3 Cl- 0.1379358E-03 0.1380138E-03 0.4892046E+01 5.2706 4 SO4-- 0.2549845E-04 0.2551203E-04 0.2450247E+01 13.6256 5 HCO3- 0.1124898E-04 0.1307375E-04 0.7975678E+00 4.1821 6 HS- 0.2356467E-13 -.2397574E-09 -.7927707E-05 -4.4968 7 Al+++ 0.1996072E-24 0.3269573E-04 0.8820075E+00 2.5555 8 H4SiO4 0.5595647E-03 0.1443941E-02 0.1387578E+03 -3.2521 9 Ca++ 0.1070496E-07 0.1198730E-07 0.4803333E-03 10.2482 10 Mg++ 0.2159181E-09 0.3238723E-09 0.7872445E-05 8.5526 11 Fe++ 0.1276946E-11 0.4319123E-08 0.2411630E-03 6.3246 12 K+ 0.4346696E-04 0.4350594E-04 0.1700837E+01 4.7692 13 Na+ 0.2017346E-02 0.2042267E-02 0.4694214E+02 6.4357 14 Mn++ 0.1706114E-09 0.1115485E-08 0.6127054E-04 8.4505 15 HPO4-- 0.8769708E-05 0.8872993E-05 0.8514546E+00 13.1621 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2480817E-01 -.1963475E-02 -.2284470E-01 0.0000000E+00 2 H2O 0.5548946E+02 0.5549245E+02 -.2994734E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6704687E-04 0.2550471E-04 0.4154216E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4154240E-04 -.2396886E-09 -.4154216E-04 0.0000000E+00 7 Al+++ 0.4887852E-02 0.3268635E-04 0.4855165E-02 0.0000000E+00 8 H4SiO4 0.1560876E-01 0.1443527E-02 0.1416524E-01 0.0000000E+00 9 Ca++ 0.1738535E-02 0.1198387E-07 0.1738523E-02 0.0000000E+00 10 Mg++ 0.1189683E-02 0.3237794E-09 0.1189682E-02 0.0000000E+00 11 Fe++ 0.1068800E-02 0.4317884E-08 0.1068796E-02 0.0000000E+00 12 K+ 0.3182590E-03 0.4349346E-04 0.2747656E-03 0.0000000E+00 13 Na+ 0.2041681E-02 0.2041681E-02 0.0000000E+00 0.0000000E+00 14 Mn++ 0.2599056E-04 0.1115165E-08 0.2598944E-04 0.0000000E+00 15 HPO4-- 0.8870447E-05 0.8870447E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.1762E-18 Mass of aqueous solution: 0.999908E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.4990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2379E-03 -3.624 0.1323 -0.879 8.325 0.5031E-01 daphnite 0.1473E-03 -3.832 0.1051 -0.978 6.616 0.3185E-01 chlorite-Mn 0.5198E-05 -5.284 0.3685E-02 -2.434 0.2320 0.1174E-02 hematite 0.1662E-03 -3.779 0.2654E-01 -1.576 1.671 0.5030E-02 microcline 0.1135E-03 -3.945 0.3160E-01 -1.500 1.989 0.1234E-01 muscovite 0.1613E-03 -3.792 0.6423E-01 -1.192 4.043 0.2271E-01 stilbite 0.1739E-02 -2.760 1.225 0.088 77.12 0.5714 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.588564 g Volume = 0.694852 cm3 Porosity: 56.5609% V(tot) - V(min): 0.90475E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.4990000 g log = 0.1758 Original solution: 1000.0103000 g Original solution / Rock added: 667.12 (Water/Rock Ratio), log = 2.8242 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1554E-05 1.0073 0.1647E-05 0.1635E-05 CH4,gas 0.1671E-16 1.0129 0.1780E-16 0.1758E-16 H2,gas 0.5526E-06 1.0006 0.5816E-06 0.5813E-06 H2S,gas 0.1250E-14 0.9959 0.1310E-14 0.1315E-14 S2,gas 0.1806E-36 1.0000 0.1900E-36 0.1900E-36 CO,gas 0.2359E-15 1.0000 0.2481E-15 0.2481E-15 SO3,gas 0.3304E-38 1.0000 0.3476E-38 0.3476E-38 SO2,gas 0.7270E-22 1.0000 0.7648E-22 0.7648E-22 HCl,gas 0.2762E-16 1.0000 0.2906E-16 0.2906E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 209 nontronite-Na 3.58 3.63 0.05 0.003 -0.79389E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.15 -7.78 -2.594 0.13290E+05 -5.783 3 CH4,gas 4.81 -13.94 -18.75 -4.687 0.32014E+05 -16.749 4 H2,gas 8.29 0.05 -8.24 -4.706 0.14062E+05 -6.235 5 H2S,gas -5.94 -22.83 -16.88 -8.441 0.28827E+05 -14.883 6 S2,gas -7.03 -45.75 -38.72 -5.957 0.66116E+05 -36.721 7 CO,gas 3.51 -14.09 -17.61 -5.417 0.30061E+05 -15.605 8 SO3,gas 17.43 -23.03 -40.46 -10.115 0.69083E+05 -38.459 9 SO2,gas 1.14 -22.98 -24.12 -6.431 0.41178E+05 -22.116 10 HCl,gas 5.48 -13.06 -18.54 -9.268 0.31651E+05 -16.537 11 acmite 7.74 6.23 -1.51 -0.157 0.25735E+04 15 albite-high 0.75 -0.77 -1.51 -0.117 0.25867E+04 16 albite -0.33 -0.77 -0.44 -0.034 0.74604E+03 19 spessartine 24.55 20.71 -3.84 -0.192 0.65635E+04 20 analcite 3.37 2.49 -0.88 -0.098 0.15090E+04 21 andalusite 5.06 1.86 -3.20 -0.320 0.54699E+04 26 annite 20.21 16.54 -3.67 -0.204 0.62620E+04 27 phlogopite 27.15 23.23 -3.92 -0.218 0.66942E+04 29 anorthite 12.80 8.85 -3.94 -0.303 0.67322E+04 32 apatite-OH -17.99 -19.24 -1.26 -0.097 0.21441E+04 35 aragonite 0.99 -3.90 -4.88 -1.628 0.83402E+04 36 brucite 12.58 8.55 -4.02 -0.805 0.68708E+04 37 calcite 0.83 -3.90 -4.73 -1.577 0.80789E+04 38 carnegieite-low 9.06 5.74 -3.33 -0.475 0.56783E+04 39 carnegieite-high 10.13 5.74 -4.40 -0.628 0.75051E+04 40 carpholite-Mg 8.65 7.16 -1.49 -0.099 0.25459E+04 41 carpholite-Fe 6.78 4.93 -1.85 -0.123 0.31616E+04 42 celadonite 5.40 2.87 -2.53 -0.149 0.43230E+04 43 celadonite-Fe 3.94 0.64 -3.30 -0.194 0.56284E+04 44 chrysotile 23.94 19.15 -4.78 -0.399 0.81681E+04 50 chloritoid-Mg 13.26 10.41 -2.85 -0.190 0.48659E+04 51 chloritoid-Fe 9.24 8.18 -1.06 -0.070 0.18018E+04 52 chloritoid-Mn 11.46 10.31 -1.15 -0.077 0.19703E+04 54 coesite -2.37 -3.25 -0.88 -0.294 0.15074E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.25 -0.70 -0.234 0.12002E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.30 -3.92 -0.392 0.66915E+04 68 hedenbergite 14.24 10.07 -4.18 -0.418 0.71303E+04 75 epidote 24.78 22.15 -2.63 -0.127 0.44829E+04 76 clinozoisite 22.92 18.41 -4.51 -0.205 0.77087E+04 77 epidote-Fe 29.94 25.89 -4.04 -0.210 0.69045E+04 78 fayalite 14.08 9.40 -4.68 -0.669 0.79943E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.47 -3.72 -0.310 0.63599E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.49 -1.76 -0.176 0.30121E+04 97 kalsilite 7.62 4.07 -3.55 -0.507 0.60577E+04 98 kaolinite -1.27 -1.39 -0.12 -0.011 0.20518E+03 99 kyanite 4.93 1.86 -3.07 -0.307 0.52467E+04 101 laumontite 2.97 2.35 -0.62 -0.042 0.10654E+04 102 lawsonite 9.68 8.85 -0.82 -0.055 0.14061E+04 103 leucite 4.17 0.82 -3.35 -0.335 0.57154E+04 105 lizardite 23.29 19.15 -4.13 -0.344 0.70584E+04 107 magnetite 20.13 18.92 -1.21 -0.099 0.20670E+04 108 minnesotaite 10.46 5.97 -4.50 -0.264 0.76761E+04 113 margarite 17.45 13.97 -3.49 -0.139 0.59521E+04 121 paragonite 4.34 4.35 0.01 0.001 -0.15496E+02 122 nepheline 8.38 5.74 -2.64 -0.377 0.45062E+04 134 phlogopite-Na 29.73 24.89 -4.84 -0.269 0.82621E+04 136 prehnite 19.47 15.85 -3.62 -0.213 0.61732E+04 137 prehnite-Fe 22.59 19.59 -2.99 -0.180 0.51096E+04 145 pyroxmangite 7.42 5.20 -2.22 -0.444 0.37867E+04 146 pyrophyllite -6.10 -7.90 -1.80 -0.112 0.30727E+04 147 quartz -2.98 -3.25 -0.27 -0.090 0.46128E+03 151 rhodochrosite -0.96 -5.70 -4.74 -1.579 0.80892E+04 152 rhodonite 7.46 5.20 -2.26 -0.453 0.38659E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.86 -3.46 -0.346 0.59121E+04 164 stilpnomelane-Fe 13.18 13.10 -0.08 -0.002 0.13333E+03 165 stilpnomelane-Mg 27.60 24.24 -3.35 -0.100 0.57282E+04 168 sudoite 21.22 17.57 -3.65 -0.118 0.62244E+04 171 talc 16.55 12.65 -3.90 -0.230 0.66661E+04 174 tephroite 18.11 13.65 -4.46 -0.638 0.76224E+04 177 topaz-H 4.67 1.86 -2.81 -0.255 0.47958E+04 178 tridymite -2.61 -3.25 -0.64 -0.213 0.10886E+04 187 wairakite 4.06 2.35 -1.71 -0.100 0.29162E+04 188 walstromite 11.53 7.00 -4.53 -0.906 0.77380E+04 189 wollastonite 10.48 7.00 -3.49 -0.697 0.59518E+04 190 pseudo-wollastonite 11.02 7.00 -4.02 -0.805 0.68705E+04 191 zoisite 22.96 18.41 -4.56 -0.207 0.77813E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.29 -2.73 -0.169 0.46622E+04 194 beidellite-H -2.24 -5.98 -3.74 -0.239 0.63859E+04 195 beidellite-K -1.44 -4.41 -2.97 -0.182 0.50750E+04 196 beidellite-Mg -1.71 -4.57 -2.86 -0.177 0.48885E+04 197 beidellite-Na -1.26 -3.86 -2.60 -0.159 0.44399E+04 199 chalcedony -2.79 -3.25 -0.46 -0.153 0.78159E+03 201 montmorillonite-Ca -2.21 -4.23 -2.01 -0.125 0.34381E+04 202 montmorillonite-K -2.16 -4.34 -2.18 -0.134 0.37287E+04 203 montmorillonite-Mg -2.40 -4.51 -2.11 -0.130 0.35955E+04 204 montmorillonite-Na -1.96 -3.79 -1.83 -0.112 0.31318E+04 205 nontronite-Ca 3.28 3.20 -0.08 -0.005 0.14199E+03 206 nontronite-H 2.60 1.51 -1.09 -0.073 0.18615E+04 207 nontronite-K 3.40 3.08 -0.32 -0.021 0.55399E+03 208 nontronite-Mg 3.14 2.92 -0.22 -0.014 0.37996E+03 224 tobermorite 9.84 5.28 -4.55 -1.243 0.77765E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.32 -3.50 -0.875 0.59755E+04 240 silica-amorphous -2.08 -3.25 -1.17 -0.391 0.20018E+04 242 an20ab80 2.08 1.16 -0.92 -0.071 0.15717E+04 243 an25ab75 2.71 1.64 -1.07 -0.082 0.18260E+04 244 an30ab70 3.34 2.12 -1.22 -0.094 0.20886E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.4990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9997E+00 Activity = 1.0000 Stoichiometric ionic strength = .1336338E-02 Osmotic coef. = 0.9791 True ionic strength = .2097153E-02 Chg. balance for total moles = 0.4567E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.72878E-09 -9.1374 0.67539E-09 -9.1704 0.92674E+00 -0.0330 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12772E-03 -3.8937 0.92595E+00 -0.0334 4 SO4-- 0.25497E-04 -4.5935 0.19812E-04 -4.7031 0.77704E+00 -0.1096 5 HCO3- 0.11227E-04 -4.9497 0.10398E-04 -4.9831 0.92614E+00 -0.0333 6 HS- 0.26869E-13 -13.5707 0.24880E-13 -13.6041 0.92597E+00 -0.0334 7 Al+++ 0.19133E-24 -24.7182 0.11070E-24 -24.9558 0.57861E+00 -0.2376 8 H4SiO4 0.54287E-03 -3.2653 0.54287E-03 -3.2653 0.10000E+01 0.0000 9 Ca++ 0.12865E-07 -7.8906 0.99864E-08 -8.0006 0.77625E+00 -0.1100 10 Mg++ 0.21375E-09 -9.6701 0.16582E-09 -9.7804 0.77575E+00 -0.1103 11 Fe++ 0.12641E-11 -11.8982 0.98081E-12 -12.0084 0.77587E+00 -0.1102 12 K+ 0.46934E-04 -4.3285 0.43470E-04 -4.3618 0.92618E+00 -0.0333 13 Na+ 0.20140E-02 -2.6959 0.18649E-02 -2.7294 0.92594E+00 -0.0334 14 Mn++ 0.16890E-09 -9.7724 0.13106E-09 -9.8825 0.77596E+00 -0.1102 15 HPO4-- 0.87707E-05 -5.0570 0.68153E-05 -5.1665 0.77705E+00 -0.1095 16 HSiO3- 0.84693E-03 -3.0722 0.78422E-03 -3.1056 0.92595E+00 -0.0334 17 Ca(HSiO3)+ 0.18945E-09 -9.7225 0.17547E-09 -9.7558 0.92620E+00 -0.0333 18 Mg(HSiO3)+ 0.39149E-11 -11.4073 0.36260E-11 -11.4406 0.92620E+00 -0.0333 19 NaHSiO3,aq 0.23228E-04 -4.6340 0.23228E-04 -4.6340 0.10000E+01 0.0000 20 AlO+ 0.33826E-13 -13.4707 0.31330E-13 -13.5040 0.92620E+00 -0.0333 21 AlOH+2 0.13659E-18 -18.8646 0.10600E-18 -18.9747 0.77607E+00 -0.1101 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.33152E-04 -4.4795 0.30689E-04 -4.5130 0.92572E+00 -0.0335 24 CH4,aq 0.12818E-19 -19.8922 0.12813E-19 -19.8924 0.99959E+00 -0.0002 29 CO,aq 0.16036E-18 -18.7949 0.16036E-18 -18.7949 0.10000E+01 0.0000 30 CO2,aq 0.14165E-07 -7.8488 0.14159E-07 -7.8490 0.99959E+00 -0.0002 31 CO3-2 0.18324E-05 -5.7370 0.14234E-05 -5.8467 0.77681E+00 -0.1097 32 CaCO3,aq 0.17410E-09 -9.7592 0.17410E-09 -9.7592 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.28248E-11 -11.5490 0.26164E-11 -11.5823 0.92620E+00 -0.0333 34 CaCl+ 0.21944E-11 -11.6587 0.20325E-11 -11.6920 0.92620E+00 -0.0333 35 CaCl2,aq 0.60443E-16 -16.2187 0.60443E-16 -16.2187 0.10000E+01 0.0000 36 CaOH+ 0.11257E-08 -8.9486 0.10426E-08 -8.9819 0.92620E+00 -0.0333 37 CaSO4,aq 0.61647E-10 -10.2101 0.61647E-10 -10.2101 0.10000E+01 0.0000 38 HCl,aq 0.16226E-13 -13.7898 0.16226E-13 -13.7898 0.10000E+01 0.0000 43 FeCl+ 0.21066E-15 -15.6764 0.19511E-15 -15.7097 0.92620E+00 -0.0333 46 FeO,aq 0.85026E-10 -10.0704 0.85026E-10 -10.0704 0.10000E+01 0.0000 47 FeOH+ 0.51980E-10 -10.2842 0.48144E-10 -10.3175 0.92620E+00 -0.0333 48 HFeO2- 0.14624E-08 -8.8349 0.13541E-08 -8.8684 0.92595E+00 -0.0334 49 FeO+ 0.60321E-14 -14.2195 0.55869E-14 -14.2528 0.92620E+00 -0.0333 51 FeO2- 0.25997E-08 -8.5851 0.24072E-08 -8.6185 0.92595E+00 -0.0334 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.43993E-09 -9.3566 0.43975E-09 -9.3568 0.99959E+00 -0.0002 54 KCl,aq 0.98307E-10 -10.0074 0.98307E-10 -10.0074 0.10000E+01 0.0000 55 KHSO4,aq 0.15565E-17 -17.8078 0.15565E-17 -17.8078 0.10000E+01 0.0000 56 KOH,aq 0.28058E-07 -7.5519 0.28058E-07 -7.5519 0.10000E+01 0.0000 57 KSO4- 0.14330E-07 -7.8438 0.13269E-07 -7.8772 0.92595E+00 -0.0334 58 MgCO3,aq 0.72236E-12 -12.1412 0.72236E-12 -12.1412 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.47830E-13 -13.3203 0.44301E-13 -13.3536 0.92620E+00 -0.0333 60 MgCl+ 0.33078E-13 -13.4805 0.30637E-13 -13.5137 0.92620E+00 -0.0333 61 MgOH+ 0.10355E-09 -9.9848 0.95909E-10 -10.0181 0.92620E+00 -0.0333 63 MnO,aq 0.30330E-09 -9.5181 0.30330E-09 -9.5181 0.10000E+01 0.0000 64 MnOH+ 0.64524E-09 -9.1903 0.59763E-09 -9.2236 0.92620E+00 -0.0333 65 MnO2-2 0.29602E-13 -13.5287 0.22995E-13 -13.6384 0.77681E+00 -0.1097 66 HMnO2- 0.36339E-11 -11.4396 0.33649E-11 -11.4730 0.92595E+00 -0.0334 69 MnCl+ 0.10938E-12 -12.9611 0.10131E-12 -12.9943 0.92620E+00 -0.0333 70 MnSO4,aq 0.73588E-12 -12.1332 0.73588E-12 -12.1332 0.10000E+01 0.0000 71 NaCl,aq 0.77773E-07 -7.1092 0.77773E-07 -7.1092 0.10000E+01 0.0000 72 NaOH,aq 0.12133E-05 -5.9160 0.12133E-05 -5.9160 0.10000E+01 0.0000 74 OH- 0.95939E-03 -3.0180 0.88813E-03 -3.0515 0.92572E+00 -0.0335 79 HPO3-2 0.12186E-16 -16.9141 0.94662E-17 -17.0238 0.77681E+00 -0.1097 81 H2PO3- 0.13563E-19 -19.8676 0.12559E-19 -19.9011 0.92595E+00 -0.0334 82 H3PO4,aq 0.20015E-13 -13.6987 0.20015E-13 -13.6987 0.10000E+01 0.0000 83 H2PO4- 0.87142E-07 -7.0598 0.80700E-07 -7.0931 0.92608E+00 -0.0334 84 PO4-3 0.15125E-07 -7.8203 0.88125E-08 -8.0549 0.58264E+00 -0.2346 87 H2P2O7-2 0.65615E-15 -15.1830 0.50970E-15 -15.2927 0.77681E+00 -0.1097 88 HP2O7-3 0.26743E-12 -12.5728 0.15475E-12 -12.8104 0.57866E+00 -0.2376 89 P2O7-4 0.14688E-12 -12.8330 0.56525E-13 -13.2478 0.38483E+00 -0.4147 90 H2S,aq 0.50509E-16 -16.2966 0.50488E-16 -16.2968 0.99959E+00 -0.0002 97 SO3-2 0.15261E-14 -14.8164 0.11879E-14 -14.9252 0.77839E+00 -0.1088 98 HSO3- 0.50708E-16 -16.2949 0.46953E-16 -16.3283 0.92595E+00 -0.0334 99 HSO4- 0.13403E-10 -10.8728 0.12416E-10 -10.9060 0.92633E+00 -0.0332 Charge balance for all species = 0.4565E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.7287820E-09 -.1965192E-02 -.1980414E+01 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9998076E+06 0.0000 3 Cl- 0.1379358E-03 0.1380137E-03 0.4892056E+01 5.2767 4 SO4-- 0.2549737E-04 0.2551202E-04 0.2450252E+01 13.6378 5 HCO3- 0.1122699E-04 0.1307375E-04 0.7975694E+00 4.1874 6 HS- 0.2686913E-13 -.2403886E-09 -.7948596E-05 -4.4337 7 Al+++ 0.1913252E-24 0.3316102E-04 0.8945615E+00 2.5555 8 H4SiO4 0.5428673E-03 0.1413029E-02 0.1357876E+03 -3.2653 9 Ca++ 0.1286499E-07 0.1442089E-07 0.5778488E-03 10.3403 10 Mg++ 0.2137527E-09 0.3220215E-09 0.7827476E-05 8.5605 11 Fe++ 0.1264140E-11 0.4403835E-08 0.2458935E-03 6.3325 12 K+ 0.4693450E-04 0.4697699E-04 0.1836540E+01 4.8086 13 Na+ 0.2014030E-02 0.2038549E-02 0.4685679E+02 6.4411 14 Mn++ 0.1689003E-09 0.1121950E-08 0.6162582E-04 8.4584 15 HPO4-- 0.8770721E-05 0.8872989E-05 0.8514563E+00 13.1744 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2480817E-01 -.1964629E-02 -.2284355E-01 0.0000000E+00 2 H2O 0.5548946E+02 0.5549251E+02 -.3046225E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6704687E-04 0.2550471E-04 0.4154216E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4154240E-04 -.2403197E-09 -.4154216E-04 0.0000000E+00 7 Al+++ 0.4887852E-02 0.3315153E-04 0.4854700E-02 0.0000000E+00 8 H4SiO4 0.1560876E-01 0.1412624E-02 0.1419614E-01 0.0000000E+00 9 Ca++ 0.1738535E-02 0.1441676E-07 0.1738520E-02 0.0000000E+00 10 Mg++ 0.1189683E-02 0.3219293E-09 0.1189682E-02 0.0000000E+00 11 Fe++ 0.1068800E-02 0.4402574E-08 0.1068795E-02 0.0000000E+00 12 K+ 0.3182590E-03 0.4696353E-04 0.2712955E-03 0.0000000E+00 13 Na+ 0.2041681E-02 0.2037965E-02 0.3716290E-05 0.0000000E+00 14 Mn++ 0.2599056E-04 0.1121629E-08 0.2598943E-04 0.0000000E+00 15 HPO4-- 0.8870447E-05 0.8870447E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2778E-18 Mass of aqueous solution: 0.999907E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.4990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2379E-03 -3.624 0.1323 -0.879 8.315 0.5031E-01 daphnite 0.1473E-03 -3.832 0.1051 -0.978 6.607 0.3185E-01 chlorite-Mn 0.5198E-05 -5.284 0.3685E-02 -2.434 0.2317 0.1174E-02 hematite 0.1549E-03 -3.810 0.2474E-01 -1.607 1.555 0.4689E-02 microcline 0.1104E-03 -3.957 0.3073E-01 -1.512 1.932 0.1200E-01 muscovite 0.1609E-03 -3.793 0.6409E-01 -1.193 4.029 0.2266E-01 stilbite 0.1739E-02 -2.760 1.225 0.088 77.03 0.5714 nontronite-Na 0.1126E-04 -4.948 0.4789E-02 -2.320 0.3011 0.1488E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.590545 g Volume = 0.695609 cm3 Porosity: 56.5136% V(tot) - V(min): 0.90399E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.4990000 g log = 0.1758 Original solution: 1000.0103000 g Original solution / Rock added: 667.12 (Water/Rock Ratio), log = 2.8242 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1530E-05 1.0073 0.1621E-05 0.1609E-05 CH4,gas 0.1902E-16 1.0129 0.2026E-16 0.2000E-16 H2,gas 0.5731E-06 1.0006 0.6031E-06 0.6028E-06 H2S,gas 0.1406E-14 0.9959 0.1473E-14 0.1479E-14 S2,gas 0.2122E-36 1.0000 0.2232E-36 0.2232E-36 CO,gas 0.2407E-15 1.0000 0.2532E-15 0.2532E-15 SO3,gas 0.3212E-38 1.0000 0.3379E-38 0.3379E-38 SO2,gas 0.7329E-22 1.0000 0.7709E-22 0.7709E-22 HCl,gas 0.2724E-16 1.0000 0.2865E-16 0.2865E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.72794E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.48529E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.53079E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.15 -7.79 -2.597 0.13302E+05 -5.790 3 CH4,gas 4.81 -13.88 -18.69 -4.673 0.31918E+05 -16.693 4 H2,gas 8.29 0.07 -8.22 -4.697 0.14035E+05 -6.220 5 H2S,gas -5.94 -22.77 -16.83 -8.416 0.28740E+05 -14.832 6 S2,gas -7.03 -45.68 -38.65 -5.946 0.65996E+05 -36.651 7 CO,gas 3.51 -14.09 -17.60 -5.414 0.30046E+05 -15.597 8 SO3,gas 17.43 -23.04 -40.47 -10.118 0.69104E+05 -38.471 9 SO2,gas 1.14 -22.98 -24.11 -6.430 0.41172E+05 -22.113 10 HCl,gas 5.48 -13.06 -18.54 -9.271 0.31661E+05 -16.543 11 acmite 7.74 6.21 -1.53 -0.159 0.26092E+04 15 albite-high 0.75 -0.80 -1.55 -0.119 0.26448E+04 16 albite -0.33 -0.80 -0.47 -0.036 0.80417E+03 19 spessartine 24.55 20.69 -3.86 -0.193 0.65904E+04 20 analcite 3.37 2.47 -0.90 -0.101 0.15447E+04 21 andalusite 5.06 1.85 -3.22 -0.322 0.54924E+04 26 annite 20.21 16.57 -3.64 -0.202 0.62215E+04 27 phlogopite 27.15 23.25 -3.90 -0.216 0.66537E+04 29 anorthite 12.80 8.92 -3.88 -0.298 0.66199E+04 32 apatite-OH -17.99 -18.82 -0.83 -0.064 0.14205E+04 35 aragonite 0.99 -3.81 -4.80 -1.600 0.81949E+04 36 brucite 12.58 8.56 -4.02 -0.803 0.68573E+04 37 calcite 0.83 -3.81 -4.65 -1.549 0.79336E+04 38 carnegieite-low 9.06 5.73 -3.33 -0.476 0.56915E+04 39 carnegieite-high 10.13 5.73 -4.40 -0.629 0.75183E+04 40 carpholite-Mg 8.65 7.14 -1.51 -0.101 0.25774E+04 41 carpholite-Fe 6.78 4.91 -1.87 -0.125 0.31930E+04 42 celadonite 5.40 2.86 -2.54 -0.149 0.43320E+04 43 celadonite-Fe 3.94 0.64 -3.30 -0.194 0.56373E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81726E+04 50 chloritoid-Mg 13.26 10.41 -2.86 -0.190 0.48749E+04 51 chloritoid-Fe 9.24 8.18 -1.06 -0.071 0.18108E+04 52 chloritoid-Mn 11.46 10.30 -1.16 -0.077 0.19793E+04 54 coesite -2.37 -3.27 -0.90 -0.299 0.15298E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.27 -0.72 -0.239 0.12227E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.37 -3.85 -0.385 0.65657E+04 68 hedenbergite 14.24 10.14 -4.10 -0.410 0.70045E+04 75 epidote 24.78 22.29 -2.48 -0.120 0.42358E+04 76 clinozoisite 22.92 18.55 -4.37 -0.199 0.74616E+04 77 epidote-Fe 29.94 26.04 -3.90 -0.203 0.66574E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79898E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.47 -3.73 -0.311 0.63644E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.47 -1.78 -0.178 0.30477E+04 97 kalsilite 7.62 4.10 -3.52 -0.503 0.60128E+04 98 kaolinite -1.27 -1.42 -0.15 -0.013 0.25011E+03 99 kyanite 4.93 1.85 -3.09 -0.309 0.52692E+04 101 laumontite 2.97 2.39 -0.58 -0.039 0.99798E+03 102 lawsonite 9.68 8.92 -0.76 -0.051 0.12937E+04 103 leucite 4.17 0.83 -3.33 -0.333 0.56929E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70629E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20536E+04 108 minnesotaite 10.46 5.94 -4.52 -0.266 0.77255E+04 113 margarite 17.45 14.03 -3.42 -0.137 0.58398E+04 121 paragonite 4.34 4.31 -0.02 -0.001 0.42639E+02 122 nepheline 8.38 5.73 -2.65 -0.378 0.45194E+04 134 phlogopite-Na 29.73 24.88 -4.85 -0.269 0.82798E+04 136 prehnite 19.47 16.00 -3.47 -0.204 0.59261E+04 137 prehnite-Fe 22.59 19.74 -2.85 -0.171 0.48625E+04 145 pyroxmangite 7.42 5.19 -2.22 -0.445 0.37957E+04 146 pyrophyllite -6.10 -7.95 -1.85 -0.116 0.31626E+04 147 quartz -2.98 -3.27 -0.28 -0.094 0.48374E+03 151 rhodochrosite -0.96 -5.70 -4.74 -1.579 0.80876E+04 152 rhodonite 7.46 5.19 -2.27 -0.454 0.38749E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.85 -3.48 -0.348 0.59346E+04 164 stilpnomelane-Fe 13.18 13.06 -0.12 -0.004 0.21196E+03 165 stilpnomelane-Mg 27.60 24.20 -3.40 -0.102 0.58068E+04 168 sudoite 21.22 17.55 -3.67 -0.118 0.62649E+04 171 talc 16.55 12.62 -3.93 -0.231 0.67155E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76179E+04 177 topaz-H 4.67 1.85 -2.82 -0.257 0.48183E+04 178 tridymite -2.61 -3.27 -0.65 -0.217 0.11110E+04 187 wairakite 4.06 2.39 -1.67 -0.098 0.28488E+04 188 walstromite 11.53 7.07 -4.45 -0.891 0.76032E+04 189 wollastonite 10.48 7.07 -3.41 -0.681 0.58171E+04 190 pseudo-wollastonite 11.02 7.07 -3.94 -0.789 0.67357E+04 191 zoisite 22.96 18.55 -4.41 -0.201 0.75342E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.32 -2.76 -0.171 0.47187E+04 194 beidellite-H -2.24 -6.03 -3.79 -0.242 0.64684E+04 195 beidellite-K -1.44 -4.44 -3.01 -0.184 0.51352E+04 196 beidellite-Mg -1.71 -4.62 -2.91 -0.180 0.49687E+04 197 beidellite-Na -1.26 -3.90 -2.65 -0.162 0.45193E+04 199 chalcedony -2.79 -3.27 -0.47 -0.157 0.80406E+03 201 montmorillonite-Ca -2.21 -4.26 -2.05 -0.127 0.34976E+04 202 montmorillonite-K -2.16 -4.38 -2.22 -0.136 0.37919E+04 203 montmorillonite-Mg -2.40 -4.56 -2.15 -0.133 0.36787E+04 204 montmorillonite-Na -1.96 -3.84 -1.88 -0.115 0.32141E+04 205 nontronite-Ca 3.28 3.16 -0.12 -0.008 0.19849E+03 206 nontronite-H 2.60 1.46 -1.14 -0.076 0.19439E+04 207 nontronite-K 3.40 3.04 -0.36 -0.023 0.61420E+03 208 nontronite-Mg 3.14 2.87 -0.27 -0.017 0.46018E+03 224 tobermorite 9.84 5.35 -4.49 -1.225 0.76680E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.873 0.59621E+04 240 silica-amorphous -2.08 -3.27 -1.19 -0.395 0.20243E+04 242 an20ab80 2.08 1.14 -0.93 -0.072 0.15957E+04 243 an25ab75 2.71 1.63 -1.08 -0.083 0.18415E+04 244 an30ab70 3.34 2.12 -1.23 -0.094 0.20956E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 1.4990000 g New total amount of reactant added: 1.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4568E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.5990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1407781E-02 Osmotic coef. = 0.9786 True ionic strength = .2215138E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.68424E-09 -9.1648 0.63317E-09 -9.1985 0.92536E+00 -0.0337 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12752E-03 -3.8944 0.92453E+00 -0.0341 4 SO4-- 0.25498E-04 -4.5935 0.19694E-04 -4.7057 0.77235E+00 -0.1122 5 HCO3- 0.11116E-04 -4.9540 0.10280E-04 -4.9880 0.92473E+00 -0.0340 6 HS- 0.26413E-13 -13.5782 0.24420E-13 -13.6123 0.92455E+00 -0.0341 7 Al+++ 0.15981E-24 -24.7964 0.91211E-25 -25.0400 0.57073E+00 -0.2436 8 H4SiO4 0.53703E-03 -3.2700 0.53703E-03 -3.2700 0.10000E+01 0.0000 9 Ca++ 0.12271E-07 -7.9111 0.94670E-08 -8.0238 0.77152E+00 -0.1127 10 Mg++ 0.19025E-09 -9.7207 0.14668E-09 -9.8336 0.77100E+00 -0.1129 11 Fe++ 0.11251E-11 -11.9488 0.86761E-12 -12.0617 0.77113E+00 -0.1129 12 K+ 0.45521E-04 -4.3418 0.42096E-04 -4.3758 0.92477E+00 -0.0340 13 Na+ 0.21327E-02 -2.6711 0.19717E-02 -2.7052 0.92451E+00 -0.0341 14 Mn++ 0.15033E-09 -9.8230 0.11593E-09 -9.9358 0.77122E+00 -0.1128 15 HPO4-- 0.93609E-05 -5.0287 0.72301E-05 -5.1409 0.77236E+00 -0.1122 16 HSiO3- 0.89507E-03 -3.0481 0.82752E-03 -3.0822 0.92453E+00 -0.0341 17 Ca(HSiO3)+ 0.18980E-09 -9.7217 0.17553E-09 -9.7557 0.92479E+00 -0.0340 18 Mg(HSiO3)+ 0.36598E-11 -11.4365 0.33846E-11 -11.4705 0.92479E+00 -0.0340 19 NaHSiO3,aq 0.25915E-04 -4.5865 0.25915E-04 -4.5865 0.10000E+01 0.0000 20 AlO+ 0.31760E-13 -13.4981 0.29371E-13 -13.5321 0.92479E+00 -0.0340 21 AlOH+2 0.12078E-18 -18.9180 0.93159E-19 -19.0308 0.77133E+00 -0.1128 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.35418E-04 -4.4508 0.32736E-04 -4.4850 0.92428E+00 -0.0342 24 CH4,aq 0.12513E-19 -19.9026 0.12508E-19 -19.9028 0.99956E+00 -0.0002 29 CO,aq 0.15057E-18 -18.8223 0.15057E-18 -18.8223 0.10000E+01 0.0000 30 CO2,aq 0.13129E-07 -7.8818 0.13123E-07 -7.8820 0.99956E+00 -0.0002 31 CO3-2 0.19442E-05 -5.7113 0.15011E-05 -5.8236 0.77210E+00 -0.1123 32 CaCO3,aq 0.17405E-09 -9.7593 0.17405E-09 -9.7593 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.26515E-11 -11.5765 0.24521E-11 -11.6105 0.92479E+00 -0.0340 34 CaCl+ 0.20802E-11 -11.6819 0.19238E-11 -11.7158 0.92479E+00 -0.0340 35 CaCl2,aq 0.57122E-16 -16.2432 0.57122E-16 -16.2432 0.10000E+01 0.0000 36 CaOH+ 0.11400E-08 -8.9431 0.10543E-08 -8.9770 0.92479E+00 -0.0340 37 CaSO4,aq 0.58090E-10 -10.2359 0.58090E-10 -10.2359 0.10000E+01 0.0000 38 HCl,aq 0.15188E-13 -13.8185 0.15188E-13 -13.8185 0.10000E+01 0.0000 43 FeCl+ 0.18634E-15 -15.7297 0.17233E-15 -15.7637 0.92479E+00 -0.0340 46 FeO,aq 0.85580E-10 -10.0676 0.85580E-10 -10.0676 0.10000E+01 0.0000 47 FeOH+ 0.49122E-10 -10.3087 0.45428E-10 -10.3427 0.92479E+00 -0.0340 48 HFeO2- 0.15725E-08 -8.8034 0.14538E-08 -8.8375 0.92453E+00 -0.0341 49 FeO+ 0.56636E-14 -14.2469 0.52376E-14 -14.2809 0.92479E+00 -0.0340 51 FeO2- 0.27774E-08 -8.5564 0.25678E-08 -8.5904 0.92453E+00 -0.0341 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44569E-09 -9.3510 0.44549E-09 -9.3512 0.99956E+00 -0.0002 54 KCl,aq 0.95053E-10 -10.0220 0.95053E-10 -10.0220 0.10000E+01 0.0000 55 KHSO4,aq 0.14046E-17 -17.8524 0.14046E-17 -17.8524 0.10000E+01 0.0000 56 KOH,aq 0.28984E-07 -7.5378 0.28984E-07 -7.5378 0.10000E+01 0.0000 57 KSO4- 0.13815E-07 -7.8597 0.12772E-07 -7.8937 0.92453E+00 -0.0341 58 MgCO3,aq 0.67386E-12 -12.1714 0.67386E-12 -12.1714 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.41893E-13 -13.3779 0.38743E-13 -13.4118 0.92479E+00 -0.0340 60 MgCl+ 0.29260E-13 -13.5337 0.27059E-13 -13.5677 0.92479E+00 -0.0340 61 MgOH+ 0.97858E-10 -10.0094 0.90498E-10 -10.0434 0.92479E+00 -0.0340 63 MnO,aq 0.30528E-09 -9.5153 0.30528E-09 -9.5153 0.10000E+01 0.0000 64 MnOH+ 0.60977E-09 -9.2148 0.56391E-09 -9.2488 0.92479E+00 -0.0340 65 MnO2-2 0.34108E-13 -13.4671 0.26335E-13 -13.5795 0.77210E+00 -0.1123 66 HMnO2- 0.39076E-11 -11.4081 0.36127E-11 -11.4422 0.92453E+00 -0.0341 69 MnCl+ 0.96756E-13 -13.0143 0.89479E-13 -13.0483 0.92479E+00 -0.0340 70 MnSO4,aq 0.64705E-12 -12.1891 0.64705E-12 -12.1891 0.10000E+01 0.0000 71 NaCl,aq 0.82103E-07 -7.0856 0.82103E-07 -7.0856 0.10000E+01 0.0000 72 NaOH,aq 0.13683E-05 -5.8638 0.13683E-05 -5.8638 0.10000E+01 0.0000 74 OH- 0.10250E-02 -2.9893 0.94736E-03 -3.0235 0.92428E+00 -0.0342 79 HPO3-2 0.13176E-16 -16.8802 0.10173E-16 -16.9925 0.77210E+00 -0.1123 81 H2PO3- 0.13686E-19 -19.8637 0.12653E-19 -19.8978 0.92453E+00 -0.0341 82 H3PO4,aq 0.18661E-13 -13.7291 0.18661E-13 -13.7291 0.10000E+01 0.0000 83 H2PO4- 0.86798E-07 -7.0615 0.80259E-07 -7.0955 0.92466E+00 -0.0340 84 PO4-3 0.17346E-07 -7.7608 0.99722E-08 -8.0012 0.57491E+00 -0.2404 87 H2P2O7-2 0.65294E-15 -15.1851 0.50414E-15 -15.2974 0.77210E+00 -0.1123 88 HP2O7-3 0.28604E-12 -12.5436 0.16327E-12 -12.7871 0.57078E+00 -0.2435 89 P2O7-4 0.16935E-12 -12.7712 0.63613E-13 -13.1965 0.37563E+00 -0.4252 90 H2S,aq 0.46477E-16 -16.3328 0.46456E-16 -16.3330 0.99956E+00 -0.0002 97 SO3-2 0.15460E-14 -14.8108 0.11962E-14 -14.9222 0.77376E+00 -0.1114 98 HSO3- 0.47944E-16 -16.3193 0.44325E-16 -16.3533 0.92453E+00 -0.0341 99 HSO4- 0.12509E-10 -10.9028 0.11570E-10 -10.9367 0.92492E+00 -0.0339 Charge balance for all species = 0.4570E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6842383E-09 -.2090925E-02 -.2107104E+01 0.0000 2 H2O 0.1000000E+01 0.5550843E+02 0.9998006E+06 0.0000 3 Cl- 0.1379339E-03 0.1380161E-03 0.4892106E+01 5.3041 4 SO4-- 0.2549834E-04 0.2551249E-04 0.2450279E+01 13.6913 5 HCO3- 0.1111647E-04 0.1307398E-04 0.7975775E+00 4.2105 6 HS- 0.2641285E-13 -.2611551E-09 -.8635192E-05 -4.4138 7 Al+++ 0.1598141E-24 0.3542681E-04 0.9556770E+00 2.5555 8 H4SiO4 0.5370275E-03 0.1458015E-02 0.1401096E+03 -3.2700 9 Ca++ 0.1227059E-07 0.1383730E-07 0.5544602E-03 10.3732 10 Mg++ 0.1902479E-09 0.2925102E-09 0.7110084E-05 8.5633 11 Fe++ 0.1125123E-11 0.4689133E-08 0.2618215E-03 6.3353 12 K+ 0.4552053E-04 0.4556342E-04 0.1781264E+01 4.8227 13 Na+ 0.2132721E-02 0.2160086E-02 0.4964999E+02 6.4933 14 Mn++ 0.1503262E-09 0.1070057E-08 0.5877499E-04 8.4612 15 HPO4-- 0.9360938E-05 0.9465083E-05 0.9082671E+00 13.2561 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2646403E-01 -.2090289E-02 -.2437374E-01 0.0000000E+00 2 H2O 0.5548821E+02 0.5549155E+02 -.3343322E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6981821E-04 0.2550473E-04 0.4431348E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4431374E-04 -.2610757E-09 -.4431348E-04 0.0000000E+00 7 Al+++ 0.5213926E-02 0.3541604E-04 0.5178510E-02 0.0000000E+00 8 H4SiO4 0.1665004E-01 0.1457572E-02 0.1519247E-01 0.0000000E+00 9 Ca++ 0.1853549E-02 0.1383309E-07 0.1853535E-02 0.0000000E+00 10 Mg++ 0.1269048E-02 0.2924213E-09 0.1269047E-02 0.0000000E+00 11 Fe++ 0.1140101E-02 0.4687707E-08 0.1140096E-02 0.0000000E+00 12 K+ 0.3394904E-03 0.4554957E-04 0.2939409E-03 0.0000000E+00 13 Na+ 0.2167206E-02 0.2159429E-02 0.7776364E-05 0.0000000E+00 14 Mn++ 0.2772441E-04 0.1069731E-08 0.2772335E-04 0.0000000E+00 15 HPO4-- 0.9462205E-05 0.9462205E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.2575E-18 Mass of aqueous solution: 0.999896E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2538E-03 -3.595 0.1411 -0.851 8.299 0.5366E-01 daphnite 0.1571E-03 -3.804 0.1121 -0.950 6.595 0.3397E-01 chlorite-Mn 0.5545E-05 -5.256 0.3931E-02 -2.405 0.2312 0.1253E-02 hematite 0.1537E-03 -3.813 0.2454E-01 -1.610 1.444 0.4652E-02 microcline 0.1256E-03 -3.901 0.3495E-01 -1.457 2.056 0.1365E-01 muscovite 0.1684E-03 -3.774 0.6707E-01 -1.173 3.946 0.2372E-01 stilbite 0.1854E-02 -2.732 1.306 0.116 76.84 0.6092 nontronite-Na 0.2356E-04 -4.628 0.1002E-01 -1.999 0.5895 0.3113E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.699917 g Volume = 0.743264 cm3 Porosity: 54.6680% V(tot) - V(min): 0.89634E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.5990000 g log = 0.2038 Original solution: 1000.0103000 g Original solution / Rock added: 625.40 (Water/Rock Ratio), log = 2.7962 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1418E-05 1.0073 0.1502E-05 0.1491E-05 CH4,gas 0.1856E-16 1.0129 0.1978E-16 0.1953E-16 H2,gas 0.5805E-06 1.0006 0.6110E-06 0.6107E-06 H2S,gas 0.1293E-14 0.9959 0.1355E-14 0.1360E-14 S2,gas 0.1751E-36 1.0000 0.1842E-36 0.1842E-36 CO,gas 0.2260E-15 1.0000 0.2378E-15 0.2378E-15 SO3,gas 0.2806E-38 1.0000 0.2952E-38 0.2952E-38 SO2,gas 0.6486E-22 1.0000 0.6823E-22 0.6823E-22 HCl,gas 0.2549E-16 1.0000 0.2682E-16 0.2682E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.15924E-10 121 paragonite 4.34 4.35 0.01 0.001 -0.22496E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.19 -7.82 -2.608 0.13358E+05 -5.823 3 CH4,gas 4.81 -13.89 -18.70 -4.676 0.31936E+05 -16.704 4 H2,gas 8.29 0.07 -8.21 -4.694 0.14025E+05 -6.214 5 H2S,gas -5.94 -22.81 -16.87 -8.434 0.28802E+05 -14.868 6 S2,gas -7.03 -45.77 -38.73 -5.959 0.66139E+05 -36.735 7 CO,gas 3.51 -14.11 -17.62 -5.423 0.30092E+05 -15.624 8 SO3,gas 17.43 -23.10 -40.53 -10.132 0.69204E+05 -38.530 9 SO2,gas 1.14 -23.03 -24.17 -6.444 0.41263E+05 -22.166 10 HCl,gas 5.48 -13.09 -18.57 -9.286 0.31710E+05 -16.572 11 acmite 7.74 6.25 -1.49 -0.154 0.25360E+04 15 albite-high 0.75 -0.76 -1.51 -0.116 0.25797E+04 16 albite -0.33 -0.76 -0.43 -0.033 0.73904E+03 19 spessartine 24.55 20.68 -3.87 -0.193 0.66000E+04 20 analcite 3.37 2.51 -0.86 -0.096 0.14715E+04 21 andalusite 5.06 1.84 -3.22 -0.322 0.55004E+04 26 annite 20.21 16.57 -3.64 -0.202 0.62071E+04 27 phlogopite 27.15 23.26 -3.89 -0.216 0.66393E+04 29 anorthite 12.80 8.94 -3.85 -0.296 0.65798E+04 32 apatite-OH -17.99 -18.75 -0.76 -0.058 0.12956E+04 35 aragonite 0.99 -3.81 -4.80 -1.600 0.81951E+04 36 brucite 12.58 8.56 -4.01 -0.803 0.68525E+04 37 calcite 0.83 -3.81 -4.65 -1.549 0.79338E+04 38 carnegieite-low 9.06 5.78 -3.29 -0.469 0.56103E+04 39 carnegieite-high 10.13 5.78 -4.36 -0.622 0.74372E+04 40 carpholite-Mg 8.65 7.13 -1.52 -0.101 0.25886E+04 41 carpholite-Fe 6.78 4.91 -1.88 -0.125 0.32043E+04 42 celadonite 5.40 2.86 -2.54 -0.149 0.43352E+04 43 celadonite-Fe 3.94 0.63 -3.30 -0.194 0.56405E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81742E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.190 0.48781E+04 51 chloritoid-Fe 9.24 8.18 -1.06 -0.071 0.18140E+04 52 chloritoid-Mn 11.46 10.30 -1.16 -0.077 0.19825E+04 54 coesite -2.37 -3.27 -0.90 -0.300 0.15378E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.27 -0.72 -0.240 0.12307E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.40 -3.82 -0.382 0.65208E+04 68 hedenbergite 14.24 10.17 -4.08 -0.408 0.69596E+04 75 epidote 24.78 22.35 -2.43 -0.118 0.41476E+04 76 clinozoisite 22.92 18.60 -4.32 -0.196 0.73734E+04 77 epidote-Fe 29.94 26.09 -3.85 -0.200 0.65692E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79882E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.47 -3.73 -0.311 0.63660E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.51 -1.74 -0.174 0.29746E+04 97 kalsilite 7.62 4.11 -3.51 -0.502 0.59967E+04 98 kaolinite -1.27 -1.43 -0.16 -0.014 0.26615E+03 99 kyanite 4.93 1.84 -3.09 -0.309 0.52772E+04 101 laumontite 2.97 2.40 -0.57 -0.038 0.97392E+03 102 lawsonite 9.68 8.94 -0.73 -0.049 0.12536E+04 103 leucite 4.17 0.84 -3.33 -0.333 0.56849E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70645E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20488E+04 108 minnesotaite 10.46 5.93 -4.53 -0.267 0.77432E+04 113 margarite 17.45 14.06 -3.40 -0.136 0.57997E+04 122 nepheline 8.38 5.78 -2.60 -0.371 0.44382E+04 134 phlogopite-Na 29.73 24.93 -4.80 -0.267 0.82002E+04 136 prehnite 19.47 16.05 -3.42 -0.201 0.58378E+04 137 prehnite-Fe 22.59 19.79 -2.80 -0.168 0.47743E+04 145 pyroxmangite 7.42 5.19 -2.22 -0.445 0.37989E+04 146 pyrophyllite -6.10 -7.97 -1.87 -0.117 0.31947E+04 147 quartz -2.98 -3.27 -0.29 -0.096 0.49176E+03 151 rhodochrosite -0.96 -5.73 -4.77 -1.589 0.81392E+04 152 rhodonite 7.46 5.19 -2.27 -0.454 0.38781E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.84 -3.48 -0.348 0.59426E+04 164 stilpnomelane-Fe 13.18 13.04 -0.14 -0.004 0.24003E+03 165 stilpnomelane-Mg 27.60 24.18 -3.42 -0.102 0.58349E+04 168 sudoite 21.22 17.54 -3.68 -0.119 0.62793E+04 171 talc 16.55 12.61 -3.94 -0.232 0.67332E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76163E+04 177 topaz-H 4.67 1.84 -2.83 -0.257 0.48263E+04 178 tridymite -2.61 -3.27 -0.66 -0.218 0.11191E+04 187 wairakite 4.06 2.40 -1.65 -0.097 0.28247E+04 188 walstromite 11.53 7.10 -4.42 -0.885 0.75550E+04 189 wollastonite 10.48 7.10 -3.38 -0.676 0.57689E+04 190 pseudo-wollastonite 11.02 7.10 -3.92 -0.783 0.66876E+04 191 zoisite 22.96 18.60 -4.36 -0.198 0.74460E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.34 -2.78 -0.172 0.47389E+04 194 beidellite-H -2.24 -6.05 -3.81 -0.243 0.64978E+04 195 beidellite-K -1.44 -4.46 -3.02 -0.185 0.51567E+04 196 beidellite-Mg -1.71 -4.63 -2.93 -0.181 0.49974E+04 197 beidellite-Na -1.26 -3.90 -2.65 -0.162 0.45193E+04 199 chalcedony -2.79 -3.27 -0.48 -0.159 0.81208E+03 201 montmorillonite-Ca -2.21 -4.27 -2.06 -0.127 0.35188E+04 202 montmorillonite-K -2.16 -4.39 -2.23 -0.137 0.38144E+04 203 montmorillonite-Mg -2.40 -4.57 -2.17 -0.134 0.37084E+04 204 montmorillonite-Na -1.96 -3.84 -1.88 -0.115 0.32152E+04 205 nontronite-Ca 3.28 3.15 -0.13 -0.008 0.21866E+03 206 nontronite-H 2.60 1.44 -1.16 -0.077 0.19734E+04 207 nontronite-K 3.40 3.03 -0.37 -0.024 0.63569E+03 208 nontronite-Mg 3.14 2.85 -0.29 -0.019 0.48882E+03 224 tobermorite 9.84 5.37 -4.47 -1.219 0.76292E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.34 -3.49 -0.872 0.59573E+04 240 silica-amorphous -2.08 -3.27 -1.19 -0.397 0.20323E+04 242 an20ab80 2.08 1.18 -0.90 -0.069 0.15356E+04 243 an25ab75 2.71 1.67 -1.04 -0.080 0.17826E+04 244 an30ab70 3.34 2.15 -1.19 -0.092 0.20380E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.5990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1383118E-02 Osmotic coef. = 0.9788 True ionic strength = .2174013E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.69937E-09 -9.1553 0.64750E-09 -9.1888 0.92584E+00 -0.0335 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12759E-03 -3.8942 0.92502E+00 -0.0338 4 SO4-- 0.25498E-04 -4.5935 0.19735E-04 -4.7048 0.77396E+00 -0.1113 5 HCO3- 0.11155E-04 -4.9525 0.10321E-04 -4.9863 0.92522E+00 -0.0338 6 HS- 0.26572E-13 -13.5756 0.24580E-13 -13.6094 0.92504E+00 -0.0338 7 Al+++ 0.17011E-24 -24.7693 0.97548E-25 -25.0108 0.57344E+00 -0.2415 8 H4SiO4 0.53904E-03 -3.2684 0.53904E-03 -3.2684 0.10000E+01 0.0000 9 Ca++ 0.12475E-07 -7.9040 0.96451E-08 -8.0157 0.77315E+00 -0.1117 10 Mg++ 0.19810E-09 -9.7031 0.15306E-09 -9.8152 0.77264E+00 -0.1120 11 Fe++ 0.11715E-11 -11.9312 0.90531E-12 -12.0432 0.77276E+00 -0.1120 12 K+ 0.46008E-04 -4.3372 0.42569E-04 -4.3709 0.92525E+00 -0.0337 13 Na+ 0.20912E-02 -2.6796 0.19343E-02 -2.7135 0.92500E+00 -0.0339 14 Mn++ 0.15653E-09 -9.8054 0.12097E-09 -9.9173 0.77285E+00 -0.1119 15 HPO4-- 0.93593E-05 -5.0288 0.72439E-05 -5.1400 0.77398E+00 -0.1113 16 HSiO3- 0.87806E-03 -3.0565 0.81223E-03 -3.0903 0.92502E+00 -0.0338 17 Ca(HSiO3)+ 0.18970E-09 -9.7219 0.17552E-09 -9.7557 0.92528E+00 -0.0337 18 Mg(HSiO3)+ 0.37463E-11 -11.4264 0.34664E-11 -11.4601 0.92528E+00 -0.0337 19 NaHSiO3,aq 0.24953E-04 -4.6029 0.24953E-04 -4.6029 0.10000E+01 0.0000 20 AlO+ 0.32462E-13 -13.4886 0.30036E-13 -13.5224 0.92528E+00 -0.0337 21 AlOH+2 0.12604E-18 -18.8995 0.97426E-19 -19.0113 0.77296E+00 -0.1118 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.34615E-04 -4.4607 0.32011E-04 -4.4947 0.92478E+00 -0.0340 24 CH4,aq 0.12620E-19 -19.8989 0.12615E-19 -19.8991 0.99957E+00 -0.0002 29 CO,aq 0.15391E-18 -18.8127 0.15391E-18 -18.8127 0.10000E+01 0.0000 30 CO2,aq 0.13480E-07 -7.8703 0.13474E-07 -7.8705 0.99957E+00 -0.0002 31 CO3-2 0.19048E-05 -5.7201 0.14738E-05 -5.8316 0.77372E+00 -0.1114 32 CaCO3,aq 0.17410E-09 -9.7592 0.17410E-09 -9.7592 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.27109E-11 -11.5669 0.25083E-11 -11.6006 0.92528E+00 -0.0337 34 CaCl+ 0.21194E-11 -11.6738 0.19610E-11 -11.7075 0.92528E+00 -0.0337 35 CaCl2,aq 0.58259E-16 -16.2346 0.58259E-16 -16.2346 0.10000E+01 0.0000 36 CaOH+ 0.11352E-08 -8.9449 0.10503E-08 -8.9787 0.92528E+00 -0.0337 37 CaSO4,aq 0.59306E-10 -10.2269 0.59306E-10 -10.2269 0.10000E+01 0.0000 38 HCl,aq 0.15540E-13 -13.8085 0.15540E-13 -13.8085 0.10000E+01 0.0000 43 FeCl+ 0.19444E-15 -15.7112 0.17991E-15 -15.7449 0.92528E+00 -0.0337 46 FeO,aq 0.85388E-10 -10.0686 0.85388E-10 -10.0686 0.10000E+01 0.0000 47 FeOH+ 0.50096E-10 -10.3002 0.46353E-10 -10.3339 0.92528E+00 -0.0337 48 HFeO2- 0.15334E-08 -8.8143 0.14184E-08 -8.8482 0.92502E+00 -0.0338 49 FeO+ 0.57888E-14 -14.2374 0.53562E-14 -14.2711 0.92528E+00 -0.0337 51 FeO2- 0.27144E-08 -8.5663 0.25109E-08 -8.6002 0.92502E+00 -0.0338 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44369E-09 -9.3529 0.44350E-09 -9.3531 0.99957E+00 -0.0002 54 KCl,aq 0.96174E-10 -10.0169 0.96174E-10 -10.0169 0.10000E+01 0.0000 55 KHSO4,aq 0.14556E-17 -17.8370 0.14556E-17 -17.8370 0.10000E+01 0.0000 56 KOH,aq 0.28661E-07 -7.5427 0.28661E-07 -7.5427 0.10000E+01 0.0000 57 KSO4- 0.13992E-07 -7.8541 0.12943E-07 -7.8880 0.92502E+00 -0.0338 58 MgCO3,aq 0.69035E-12 -12.1609 0.69035E-12 -12.1609 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.43867E-13 -13.3579 0.40590E-13 -13.3916 0.92528E+00 -0.0337 60 MgCl+ 0.30532E-13 -13.5152 0.28251E-13 -13.5490 0.92528E+00 -0.0337 61 MgOH+ 0.99797E-10 -10.0009 0.92340E-10 -10.0346 0.92528E+00 -0.0337 63 MnO,aq 0.30459E-09 -9.5163 0.30459E-09 -9.5163 0.10000E+01 0.0000 64 MnOH+ 0.62185E-09 -9.2063 0.57539E-09 -9.2400 0.92528E+00 -0.0337 65 MnO2-2 0.32473E-13 -13.4885 0.25125E-13 -13.5999 0.77372E+00 -0.1114 66 HMnO2- 0.38105E-11 -11.4190 0.35248E-11 -11.4529 0.92502E+00 -0.0338 69 MnCl+ 0.10096E-12 -12.9958 0.93418E-13 -13.0296 0.92528E+00 -0.0337 70 MnSO4,aq 0.67658E-12 -12.1697 0.67658E-12 -12.1697 0.10000E+01 0.0000 71 NaCl,aq 0.80589E-07 -7.0937 0.80589E-07 -7.0937 0.10000E+01 0.0000 72 NaOH,aq 0.13127E-05 -5.8818 0.13127E-05 -5.8818 0.10000E+01 0.0000 74 OH- 0.10017E-02 -2.9992 0.92638E-03 -3.0332 0.92478E+00 -0.0340 79 HPO3-2 0.13115E-16 -16.8822 0.10147E-16 -16.9936 0.77372E+00 -0.1114 81 H2PO3- 0.13953E-19 -19.8553 0.12906E-19 -19.8892 0.92502E+00 -0.0338 82 H3PO4,aq 0.19552E-13 -13.7088 0.19552E-13 -13.7088 0.10000E+01 0.0000 83 H2PO4- 0.88886E-07 -7.0512 0.82233E-07 -7.0850 0.92515E+00 -0.0338 84 PO4-3 0.16916E-07 -7.7717 0.97701E-08 -8.0101 0.57756E+00 -0.2384 87 H2P2O7-2 0.68402E-15 -15.1649 0.52925E-15 -15.2763 0.77372E+00 -0.1114 88 HP2O7-3 0.29225E-12 -12.5342 0.16760E-12 -12.7757 0.57349E+00 -0.2415 89 P2O7-4 0.16858E-12 -12.7732 0.63857E-13 -13.1948 0.37878E+00 -0.4216 90 H2S,aq 0.47841E-16 -16.3202 0.47820E-16 -16.3204 0.99957E+00 -0.0002 97 SO3-2 0.15391E-14 -14.8127 0.11934E-14 -14.9232 0.77536E+00 -0.1105 98 HSO3- 0.48886E-16 -16.3108 0.45220E-16 -16.3447 0.92502E+00 -0.0338 99 HSO4- 0.12812E-10 -10.8924 0.11856E-10 -10.9260 0.92541E+00 -0.0337 Charge balance for all species = 0.4631E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6993709E-09 -.2046415E-02 -.2062256E+01 0.0000 2 H2O 0.1000000E+01 0.5550842E+02 0.9998030E+06 0.0000 3 Cl- 0.1379353E-03 0.1380159E-03 0.4892112E+01 5.2946 4 SO4-- 0.2549813E-04 0.2551244E-04 0.2450281E+01 13.6727 5 HCO3- 0.1115547E-04 0.1307396E-04 0.7975784E+00 4.2025 6 HS- 0.2657209E-13 -.2537874E-09 -.8391597E-05 -4.4207 7 Al+++ 0.1701102E-24 0.3462410E-04 0.9340254E+00 2.5555 8 H4SiO4 0.5390373E-03 0.1442055E-02 0.1385763E+03 -3.2684 9 Ca++ 0.1247503E-07 0.1403812E-07 0.5625086E-03 10.3618 10 Mg++ 0.1980951E-09 0.3024029E-09 0.7350566E-05 8.5624 11 Fe++ 0.1171534E-11 0.4587954E-08 0.2561728E-03 6.3343 12 K+ 0.4600825E-04 0.4605100E-04 0.1800330E+01 4.8179 13 Na+ 0.2091150E-02 0.2117497E-02 0.4867120E+02 6.4753 14 Mn++ 0.1565274E-09 0.1087593E-08 0.5973834E-04 8.4602 15 HPO4-- 0.9359266E-05 0.9465069E-05 0.9082682E+00 13.2375 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2646403E-01 -.2045796E-02 -.2441823E-01 0.0000000E+00 2 H2O 0.5548821E+02 0.5549162E+02 -.3414782E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6981821E-04 0.2550472E-04 0.4431349E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4431374E-04 -.2537106E-09 -.4431349E-04 0.0000000E+00 7 Al+++ 0.5213926E-02 0.3461362E-04 0.5179312E-02 0.0000000E+00 8 H4SiO4 0.1665004E-01 0.1441619E-02 0.1520842E-01 0.0000000E+00 9 Ca++ 0.1853549E-02 0.1403388E-07 0.1853535E-02 0.0000000E+00 10 Mg++ 0.1269048E-02 0.3023114E-09 0.1269047E-02 0.0000000E+00 11 Fe++ 0.1140101E-02 0.4586566E-08 0.1140096E-02 0.0000000E+00 12 K+ 0.3394904E-03 0.4603707E-04 0.2934534E-03 0.0000000E+00 13 Na+ 0.2167206E-02 0.2116856E-02 0.5034970E-04 0.0000000E+00 14 Mn++ 0.2772441E-04 0.1087263E-08 0.2772333E-04 0.0000000E+00 15 HPO4-- 0.9462205E-05 0.9462205E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.3117E-18 Mass of aqueous solution: 0.999895E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2538E-03 -3.595 0.1411 -0.851 8.293 0.5366E-01 daphnite 0.1571E-03 -3.804 0.1121 -0.950 6.590 0.3397E-01 chlorite-Mn 0.5545E-05 -5.256 0.3931E-02 -2.405 0.2311 0.1253E-02 hematite 0.1948E-03 -3.710 0.3112E-01 -1.507 1.829 0.5898E-02 microcline 0.2019E-03 -3.695 0.5619E-01 -1.250 3.303 0.2195E-01 muscovite 0.9159E-04 -4.038 0.3648E-01 -1.438 2.145 0.1290E-01 stilbite 0.1854E-02 -2.732 1.306 0.116 76.79 0.6092 nontronite-Na -.1759E-04 1.000 -.7482E-02 1.000 -.4398 -.2324E-02 paragonite 0.5616E-04 -4.251 0.2146E-01 -1.668 1.262 0.7419E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.701100 g Volume = 0.743971 cm3 Porosity: 54.6248% V(tot) - V(min): 0.89563E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.5990000 g log = 0.2038 Original solution: 1000.0103000 g Original solution / Rock added: 625.40 (Water/Rock Ratio), log = 2.7962 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1456E-05 1.0073 0.1542E-05 0.1531E-05 CH4,gas 0.1872E-16 1.0129 0.1995E-16 0.1969E-16 H2,gas 0.5779E-06 1.0006 0.6083E-06 0.6080E-06 H2S,gas 0.1331E-14 0.9959 0.1395E-14 0.1400E-14 S2,gas 0.1872E-36 1.0000 0.1969E-36 0.1969E-36 CO,gas 0.2310E-15 1.0000 0.2430E-15 0.2430E-15 SO3,gas 0.2941E-38 1.0000 0.3093E-38 0.3093E-38 SO2,gas 0.6767E-22 1.0000 0.7118E-22 0.7118E-22 HCl,gas 0.2608E-16 1.0000 0.2744E-16 0.2744E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.18 -7.81 -2.604 0.13338E+05 -5.812 3 CH4,gas 4.81 -13.89 -18.70 -4.675 0.31930E+05 -16.700 4 H2,gas 8.29 0.07 -8.22 -4.695 0.14028E+05 -6.216 5 H2S,gas -5.94 -22.80 -16.86 -8.428 0.28780E+05 -14.856 6 S2,gas -7.03 -45.74 -38.71 -5.955 0.66089E+05 -36.706 7 CO,gas 3.51 -14.10 -17.61 -5.420 0.30076E+05 -15.614 8 SO3,gas 17.43 -23.08 -40.51 -10.127 0.69169E+05 -38.510 9 SO2,gas 1.14 -23.01 -24.15 -6.439 0.41231E+05 -22.148 10 HCl,gas 5.48 -13.08 -18.56 -9.281 0.31693E+05 -16.562 11 acmite 7.74 6.24 -1.50 -0.156 0.25613E+04 15 albite-high 0.75 -0.77 -1.52 -0.117 0.26022E+04 16 albite -0.33 -0.77 -0.45 -0.034 0.76153E+03 19 spessartine 24.55 20.69 -3.86 -0.193 0.65967E+04 20 analcite 3.37 2.49 -0.88 -0.097 0.14968E+04 21 andalusite 5.06 1.84 -3.22 -0.322 0.54977E+04 26 annite 20.21 16.57 -3.64 -0.202 0.62121E+04 27 phlogopite 27.15 23.26 -3.89 -0.216 0.66443E+04 29 anorthite 12.80 8.94 -3.86 -0.297 0.65936E+04 32 apatite-OH -17.99 -18.74 -0.75 -0.058 0.12887E+04 35 aragonite 0.99 -3.81 -4.80 -1.600 0.81949E+04 36 brucite 12.58 8.56 -4.01 -0.803 0.68542E+04 37 calcite 0.83 -3.81 -4.65 -1.549 0.79336E+04 38 carnegieite-low 9.06 5.76 -3.30 -0.472 0.56383E+04 39 carnegieite-high 10.13 5.76 -4.37 -0.625 0.74652E+04 40 carpholite-Mg 8.65 7.14 -1.51 -0.101 0.25847E+04 41 carpholite-Fe 6.78 4.91 -1.87 -0.125 0.32004E+04 42 celadonite 5.40 2.86 -2.54 -0.149 0.43341E+04 43 celadonite-Fe 3.94 0.63 -3.30 -0.194 0.56394E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81737E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.190 0.48770E+04 51 chloritoid-Fe 9.24 8.18 -1.06 -0.071 0.18129E+04 52 chloritoid-Mn 11.46 10.30 -1.16 -0.077 0.19813E+04 54 coesite -2.37 -3.27 -0.90 -0.300 0.15351E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.27 -0.72 -0.240 0.12280E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.39 -3.83 -0.383 0.65363E+04 68 hedenbergite 14.24 10.16 -4.09 -0.409 0.69751E+04 75 epidote 24.78 22.33 -2.45 -0.119 0.41780E+04 76 clinozoisite 22.92 18.58 -4.34 -0.197 0.74039E+04 77 epidote-Fe 29.94 26.07 -3.87 -0.201 0.65997E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79888E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.47 -3.73 -0.311 0.63655E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.49 -1.76 -0.176 0.29998E+04 97 kalsilite 7.62 4.10 -3.52 -0.502 0.60023E+04 98 kaolinite -1.27 -1.43 -0.15 -0.014 0.26061E+03 99 kyanite 4.93 1.84 -3.09 -0.309 0.52744E+04 101 laumontite 2.97 2.40 -0.58 -0.038 0.98223E+03 102 lawsonite 9.68 8.94 -0.74 -0.049 0.12675E+04 103 leucite 4.17 0.84 -3.33 -0.333 0.56877E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70640E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20504E+04 108 minnesotaite 10.46 5.93 -4.53 -0.267 0.77371E+04 113 margarite 17.45 14.05 -3.40 -0.136 0.58135E+04 122 nepheline 8.38 5.76 -2.62 -0.374 0.44663E+04 134 phlogopite-Na 29.73 24.91 -4.82 -0.268 0.82277E+04 136 prehnite 19.47 16.03 -3.44 -0.202 0.58683E+04 137 prehnite-Fe 22.59 19.77 -2.81 -0.169 0.48048E+04 145 pyroxmangite 7.42 5.19 -2.22 -0.445 0.37978E+04 146 pyrophyllite -6.10 -7.96 -1.86 -0.117 0.31836E+04 147 quartz -2.98 -3.27 -0.29 -0.095 0.48899E+03 151 rhodochrosite -0.96 -5.71 -4.76 -1.585 0.81212E+04 152 rhodonite 7.46 5.19 -2.27 -0.454 0.38770E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.84 -3.48 -0.348 0.59398E+04 164 stilpnomelane-Fe 13.18 13.04 -0.13 -0.004 0.23034E+03 165 stilpnomelane-Mg 27.60 24.18 -3.41 -0.102 0.58252E+04 168 sudoite 21.22 17.54 -3.67 -0.119 0.62743E+04 171 talc 16.55 12.61 -3.94 -0.232 0.67271E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76168E+04 177 topaz-H 4.67 1.84 -2.82 -0.257 0.48235E+04 178 tridymite -2.61 -3.27 -0.65 -0.218 0.11163E+04 187 wairakite 4.06 2.40 -1.66 -0.098 0.28330E+04 188 walstromite 11.53 7.09 -4.43 -0.887 0.75717E+04 189 wollastonite 10.48 7.09 -3.39 -0.678 0.57856E+04 190 pseudo-wollastonite 11.02 7.09 -3.93 -0.785 0.67042E+04 191 zoisite 22.96 18.58 -4.38 -0.199 0.74764E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.33 -2.77 -0.171 0.47319E+04 194 beidellite-H -2.24 -6.04 -3.80 -0.242 0.64876E+04 195 beidellite-K -1.44 -4.45 -3.02 -0.185 0.51493E+04 196 beidellite-Mg -1.71 -4.63 -2.92 -0.181 0.49875E+04 197 beidellite-Na -1.26 -3.90 -2.65 -0.162 0.45193E+04 199 chalcedony -2.79 -3.27 -0.47 -0.158 0.80931E+03 201 montmorillonite-Ca -2.21 -4.27 -2.06 -0.127 0.35115E+04 202 montmorillonite-K -2.16 -4.39 -2.23 -0.137 0.38066E+04 203 montmorillonite-Mg -2.40 -4.57 -2.17 -0.134 0.36981E+04 204 montmorillonite-Na -1.96 -3.84 -1.88 -0.115 0.32148E+04 205 nontronite-Ca 3.28 3.16 -0.12 -0.008 0.21169E+03 206 nontronite-H 2.60 1.45 -1.15 -0.077 0.19632E+04 207 nontronite-K 3.40 3.04 -0.37 -0.024 0.62827E+03 208 nontronite-Mg 3.14 2.86 -0.28 -0.018 0.47892E+03 209 nontronite-Na 3.58 3.58 0.00 0.000 0.15924E-10 224 tobermorite 9.84 5.36 -4.48 -1.221 0.76426E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.33 -3.49 -0.872 0.59589E+04 240 silica-amorphous -2.08 -3.27 -1.19 -0.396 0.20295E+04 242 an20ab80 2.08 1.17 -0.91 -0.070 0.15563E+04 243 an25ab75 2.71 1.65 -1.06 -0.081 0.18029E+04 244 an30ab70 3.34 2.14 -1.21 -0.093 0.20579E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.5990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1392949E-02 Osmotic coef. = 0.9787 True ionic strength = .2189922E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.69200E-09 -9.1599 0.64055E-09 -9.1934 0.92565E+00 -0.0336 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12757E-03 -3.8943 0.92483E+00 -0.0339 4 SO4-- 0.25498E-04 -4.5935 0.19719E-04 -4.7051 0.77334E+00 -0.1116 5 HCO3- 0.11137E-04 -4.9532 0.10302E-04 -4.9871 0.92503E+00 -0.0338 6 HS- 0.27038E-13 -13.5680 0.25006E-13 -13.6019 0.92485E+00 -0.0339 7 Al+++ 0.16499E-24 -24.7825 0.94439E-25 -25.0248 0.57239E+00 -0.2423 8 H4SiO4 0.53581E-03 -3.2710 0.53581E-03 -3.2710 0.10000E+01 0.0000 9 Ca++ 0.12743E-07 -7.8947 0.98439E-08 -8.0068 0.77252E+00 -0.1121 10 Mg++ 0.19472E-09 -9.7106 0.15033E-09 -9.8230 0.77200E+00 -0.1124 11 Fe++ 0.11516E-11 -11.9387 0.88917E-12 -12.0510 0.77212E+00 -0.1123 12 K+ 0.46350E-04 -4.3339 0.42877E-04 -4.3678 0.92506E+00 -0.0338 13 Na+ 0.21067E-02 -2.6764 0.19483E-02 -2.7103 0.92481E+00 -0.0339 14 Mn++ 0.15386E-09 -9.8129 0.11882E-09 -9.9251 0.77222E+00 -0.1123 15 HPO4-- 0.93601E-05 -5.0287 0.72386E-05 -5.1403 0.77335E+00 -0.1116 16 HSiO3- 0.88247E-03 -3.0543 0.81614E-03 -3.0882 0.92483E+00 -0.0339 17 Ca(HSiO3)+ 0.19458E-09 -9.7109 0.18000E-09 -9.7447 0.92509E+00 -0.0338 18 Mg(HSiO3)+ 0.36980E-11 -11.4320 0.34210E-11 -11.4659 0.92509E+00 -0.0338 19 NaHSiO3,aq 0.25254E-04 -4.5977 0.25254E-04 -4.5977 0.10000E+01 0.0000 20 AlO+ 0.32120E-13 -13.4932 0.29714E-13 -13.5270 0.92509E+00 -0.0338 21 AlOH+2 0.12345E-18 -18.9085 0.95345E-19 -19.0207 0.77233E+00 -0.1122 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.34998E-04 -4.4560 0.32358E-04 -4.4900 0.92459E+00 -0.0341 24 CH4,aq 0.12825E-19 -19.8919 0.12820E-19 -19.8921 0.99957E+00 -0.0002 29 CO,aq 0.15307E-18 -18.8151 0.15307E-18 -18.8151 0.10000E+01 0.0000 30 CO2,aq 0.13311E-07 -7.8758 0.13305E-07 -7.8760 0.99957E+00 -0.0002 31 CO3-2 0.19235E-05 -5.7159 0.14870E-05 -5.8277 0.77309E+00 -0.1118 32 CaCO3,aq 0.17928E-09 -9.7465 0.17928E-09 -9.7465 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.27622E-11 -11.5587 0.25553E-11 -11.5926 0.92509E+00 -0.0338 34 CaCl+ 0.21631E-11 -11.6649 0.20010E-11 -11.6987 0.92509E+00 -0.0338 35 CaCl2,aq 0.59435E-16 -16.2260 0.59435E-16 -16.2260 0.10000E+01 0.0000 36 CaOH+ 0.11714E-08 -8.9313 0.10836E-08 -8.9651 0.92509E+00 -0.0338 37 CaSO4,aq 0.60479E-10 -10.2184 0.60479E-10 -10.2184 0.10000E+01 0.0000 38 HCl,aq 0.15370E-13 -13.8133 0.15370E-13 -13.8133 0.10000E+01 0.0000 43 FeCl+ 0.19097E-15 -15.7190 0.17667E-15 -15.7528 0.92509E+00 -0.0338 46 FeO,aq 0.85696E-10 -10.0670 0.85696E-10 -10.0670 0.10000E+01 0.0000 47 FeOH+ 0.49747E-10 -10.3032 0.46020E-10 -10.3371 0.92509E+00 -0.0338 48 HFeO2- 0.15560E-08 -8.8080 0.14390E-08 -8.8419 0.92483E+00 -0.0339 49 FeO+ 0.57278E-14 -14.2420 0.52987E-14 -14.2758 0.92509E+00 -0.0338 51 FeO2- 0.27444E-08 -8.5615 0.25382E-08 -8.5955 0.92483E+00 -0.0339 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.44690E-09 -9.3498 0.44670E-09 -9.3500 0.99957E+00 -0.0002 54 KCl,aq 0.96848E-10 -10.0139 0.96848E-10 -10.0139 0.10000E+01 0.0000 55 KHSO4,aq 0.14492E-17 -17.8389 0.14492E-17 -17.8389 0.10000E+01 0.0000 56 KOH,aq 0.29181E-07 -7.5349 0.29181E-07 -7.5349 0.10000E+01 0.0000 57 KSO4- 0.14084E-07 -7.8513 0.13026E-07 -7.8852 0.92483E+00 -0.0339 58 MgCO3,aq 0.68413E-12 -12.1649 0.68413E-12 -12.1649 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.43014E-13 -13.3664 0.39792E-13 -13.4002 0.92509E+00 -0.0338 60 MgCl+ 0.29987E-13 -13.5231 0.27741E-13 -13.5569 0.92509E+00 -0.0338 61 MgOH+ 0.99101E-10 -10.0039 0.91678E-10 -10.0377 0.92509E+00 -0.0338 63 MnO,aq 0.30569E-09 -9.5147 0.30569E-09 -9.5147 0.10000E+01 0.0000 64 MnOH+ 0.61752E-09 -9.2093 0.57126E-09 -9.2432 0.92509E+00 -0.0338 65 MnO2-2 0.33328E-13 -13.4772 0.25766E-13 -13.5890 0.77309E+00 -0.1118 66 HMnO2- 0.38665E-11 -11.4127 0.35759E-11 -11.4466 0.92483E+00 -0.0339 69 MnCl+ 0.99161E-13 -13.0037 0.91733E-13 -13.0375 0.92509E+00 -0.0338 70 MnSO4,aq 0.66397E-12 -12.1778 0.66397E-12 -12.1778 0.10000E+01 0.0000 71 NaCl,aq 0.81154E-07 -7.0907 0.81154E-07 -7.0907 0.10000E+01 0.0000 72 NaOH,aq 0.13365E-05 -5.8740 0.13365E-05 -5.8740 0.10000E+01 0.0000 74 OH- 0.10128E-02 -2.9945 0.93644E-03 -3.0285 0.92459E+00 -0.0341 79 HPO3-2 0.13211E-16 -16.8791 0.10213E-16 -16.9908 0.77309E+00 -0.1118 81 H2PO3- 0.13895E-19 -19.8571 0.12851E-19 -19.8911 0.92483E+00 -0.0339 82 H3PO4,aq 0.19121E-13 -13.7185 0.19121E-13 -13.7185 0.10000E+01 0.0000 83 H2PO4- 0.87886E-07 -7.0561 0.81291E-07 -7.0900 0.92496E+00 -0.0339 84 PO4-3 0.17118E-07 -7.7665 0.98690E-08 -8.0057 0.57653E+00 -0.2392 87 H2P2O7-2 0.66899E-15 -15.1746 0.51719E-15 -15.2863 0.77309E+00 -0.1118 88 HP2O7-3 0.28923E-12 -12.5388 0.16556E-12 -12.7810 0.57243E+00 -0.2423 89 P2O7-4 0.16889E-12 -12.7724 0.63764E-13 -13.1954 0.37756E+00 -0.4230 90 H2S,aq 0.48147E-16 -16.3174 0.48127E-16 -16.3176 0.99957E+00 -0.0002 97 SO3-2 0.15502E-14 -14.8096 0.12010E-14 -14.9205 0.77474E+00 -0.1108 98 HSO3- 0.48680E-16 -16.3126 0.45021E-16 -16.3466 0.92483E+00 -0.0339 99 HSO4- 0.12667E-10 -10.8973 0.11720E-10 -10.9311 0.92522E+00 -0.0338 Charge balance for all species = 0.4585E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6919996E-09 -.2063780E-02 -.2079753E+01 0.0000 2 H2O 0.1000000E+01 0.5550843E+02 0.9998025E+06 0.0000 3 Cl- 0.1379348E-03 0.1380160E-03 0.4892111E+01 5.2992 4 SO4-- 0.2549805E-04 0.2551246E-04 0.2450281E+01 13.6818 5 HCO3- 0.1113698E-04 0.1307396E-04 0.7975783E+00 4.2064 6 HS- 0.2703823E-13 -.2567386E-09 -.8489176E-05 -4.4085 7 Al+++ 0.1649920E-24 0.3500708E-04 0.9443561E+00 2.5555 8 H4SiO4 0.5358133E-03 0.1443536E-02 0.1387185E+03 -3.2710 9 Ca++ 0.1274257E-07 0.1435320E-07 0.5751335E-03 10.3801 10 Mg++ 0.1947229E-09 0.2982794E-09 0.7250330E-05 8.5639 11 Fe++ 0.1151590E-11 0.4640474E-08 0.2591051E-03 6.3359 12 K+ 0.4635022E-04 0.4639358E-04 0.1813722E+01 4.8257 13 Na+ 0.2106697E-02 0.2133369E-02 0.4903600E+02 6.4831 14 Mn++ 0.1538626E-09 0.1081736E-08 0.5941660E-04 8.4618 15 HPO4-- 0.9360069E-05 0.9465074E-05 0.9082681E+00 13.2465 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2646403E-01 -.2063154E-02 -.2440087E-01 0.0000000E+00 2 H2O 0.5548821E+02 0.5549160E+02 -.3394998E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6981821E-04 0.2550473E-04 0.4431348E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4431374E-04 -.2566608E-09 -.4431348E-04 0.0000000E+00 7 Al+++ 0.5213926E-02 0.3499647E-04 0.5178929E-02 0.0000000E+00 8 H4SiO4 0.1665004E-01 0.1443099E-02 0.1520694E-01 0.0000000E+00 9 Ca++ 0.1853549E-02 0.1434885E-07 0.1853535E-02 0.0000000E+00 10 Mg++ 0.1269048E-02 0.2981890E-09 0.1269047E-02 0.0000000E+00 11 Fe++ 0.1140101E-02 0.4639067E-08 0.1140096E-02 0.0000000E+00 12 K+ 0.3394904E-03 0.4637952E-04 0.2931109E-03 0.0000000E+00 13 Na+ 0.2167206E-02 0.2132722E-02 0.3448314E-04 0.0000000E+00 14 Mn++ 0.2772441E-04 0.1081408E-08 0.2772333E-04 0.0000000E+00 15 HPO4-- 0.9462205E-05 0.9462205E-05 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: 0.3185E-18 Mass of aqueous solution: 0.999895E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2538E-03 -3.595 0.1411 -0.851 8.294 0.5366E-01 daphnite 0.1571E-03 -3.804 0.1121 -0.950 6.591 0.3397E-01 chlorite-Mn 0.5545E-05 -5.256 0.3931E-02 -2.405 0.2311 0.1253E-02 hematite 0.1773E-03 -3.751 0.2831E-01 -1.548 1.664 0.5365E-02 microcline 0.1719E-03 -3.765 0.4786E-01 -1.320 2.813 0.1869E-01 muscovite 0.1212E-03 -3.917 0.4827E-01 -1.316 2.838 0.1707E-01 paragonite 0.3448E-04 -4.462 0.1318E-01 -1.880 0.7748 0.4556E-02 stilbite 0.1854E-02 -2.732 1.306 0.116 76.79 0.6092 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.700943 g Volume = 0.743813 cm3 Porosity: 54.6345% V(tot) - V(min): 0.89579E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.5990000 g log = 0.2038 Original solution: 1000.0103000 g Original solution / Rock added: 625.40 (Water/Rock Ratio), log = 2.7962 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1437E-05 1.0073 0.1523E-05 0.1512E-05 CH4,gas 0.1903E-16 1.0129 0.2027E-16 0.2001E-16 H2,gas 0.5821E-06 1.0006 0.6127E-06 0.6123E-06 H2S,gas 0.1340E-14 0.9959 0.1404E-14 0.1409E-14 S2,gas 0.1869E-36 1.0000 0.1966E-36 0.1966E-36 CO,gas 0.2298E-15 1.0000 0.2417E-15 0.2417E-15 SO3,gas 0.2875E-38 1.0000 0.3025E-38 0.3025E-38 SO2,gas 0.6665E-22 1.0000 0.7011E-22 0.7011E-22 HCl,gas 0.2580E-16 1.0000 0.2714E-16 0.2714E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.18 -7.82 -2.606 0.13348E+05 -5.817 3 CH4,gas 4.81 -13.88 -18.69 -4.673 0.31918E+05 -16.693 4 H2,gas 8.29 0.07 -8.21 -4.693 0.14023E+05 -6.213 5 H2S,gas -5.94 -22.80 -16.85 -8.426 0.28776E+05 -14.853 6 S2,gas -7.03 -45.74 -38.71 -5.955 0.66090E+05 -36.706 7 CO,gas 3.51 -14.11 -17.62 -5.421 0.30080E+05 -15.617 8 SO3,gas 17.43 -23.09 -40.52 -10.130 0.69186E+05 -38.519 9 SO2,gas 1.14 -23.02 -24.15 -6.441 0.41243E+05 -22.154 10 HCl,gas 5.48 -13.09 -18.57 -9.283 0.31702E+05 -16.566 11 acmite 7.74 6.24 -1.50 -0.156 0.25569E+04 15 albite-high 0.75 -0.77 -1.52 -0.117 0.26022E+04 16 albite -0.33 -0.77 -0.45 -0.034 0.76153E+03 19 spessartine 24.55 20.68 -3.87 -0.193 0.66021E+04 20 analcite 3.37 2.50 -0.87 -0.097 0.14924E+04 21 andalusite 5.06 1.84 -3.22 -0.322 0.55021E+04 26 annite 20.21 16.58 -3.63 -0.202 0.62041E+04 27 phlogopite 27.15 23.26 -3.89 -0.216 0.66363E+04 29 anorthite 12.80 8.95 -3.85 -0.296 0.65714E+04 32 apatite-OH -17.99 -18.68 -0.69 -0.053 0.11827E+04 35 aragonite 0.99 -3.80 -4.79 -1.596 0.81731E+04 36 brucite 12.58 8.56 -4.01 -0.803 0.68515E+04 37 calcite 0.83 -3.80 -4.63 -1.545 0.79118E+04 38 carnegieite-low 9.06 5.77 -3.30 -0.471 0.56294E+04 39 carnegieite-high 10.13 5.77 -4.37 -0.624 0.74563E+04 40 carpholite-Mg 8.65 7.13 -1.52 -0.101 0.25910E+04 41 carpholite-Fe 6.78 4.90 -1.88 -0.125 0.32066E+04 42 celadonite 5.40 2.86 -2.54 -0.149 0.43359E+04 43 celadonite-Fe 3.94 0.63 -3.30 -0.194 0.56412E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81746E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.190 0.48788E+04 51 chloritoid-Fe 9.24 8.18 -1.06 -0.071 0.18147E+04 52 chloritoid-Mn 11.46 10.30 -1.16 -0.077 0.19831E+04 54 coesite -2.37 -3.27 -0.90 -0.301 0.15395E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.27 -0.72 -0.241 0.12324E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.40 -3.81 -0.381 0.65114E+04 68 hedenbergite 14.24 10.17 -4.07 -0.407 0.69502E+04 75 epidote 24.78 22.36 -2.42 -0.117 0.41291E+04 76 clinozoisite 22.92 18.61 -4.31 -0.196 0.73549E+04 77 epidote-Fe 29.94 26.10 -3.84 -0.199 0.65507E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79879E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.47 -3.73 -0.311 0.63664E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.50 -1.75 -0.175 0.29954E+04 97 kalsilite 7.62 4.11 -3.51 -0.501 0.59934E+04 98 kaolinite -1.27 -1.43 -0.16 -0.014 0.26951E+03 99 kyanite 4.93 1.84 -3.09 -0.309 0.52789E+04 101 laumontite 2.97 2.41 -0.57 -0.038 0.96889E+03 102 lawsonite 9.68 8.95 -0.73 -0.049 0.12453E+04 103 leucite 4.17 0.84 -3.33 -0.333 0.56832E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70648E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20478E+04 108 minnesotaite 10.46 5.92 -4.54 -0.267 0.77469E+04 113 margarite 17.45 14.06 -3.39 -0.136 0.57913E+04 122 nepheline 8.38 5.77 -2.61 -0.373 0.44574E+04 134 phlogopite-Na 29.73 24.92 -4.81 -0.267 0.82197E+04 136 prehnite 19.47 16.06 -3.41 -0.200 0.58194E+04 137 prehnite-Fe 22.59 19.80 -2.79 -0.168 0.47558E+04 145 pyroxmangite 7.42 5.19 -2.23 -0.445 0.37996E+04 146 pyrophyllite -6.10 -7.97 -1.87 -0.117 0.32014E+04 147 quartz -2.98 -3.27 -0.29 -0.096 0.49344E+03 151 rhodochrosite -0.96 -5.72 -4.76 -1.587 0.81280E+04 152 rhodonite 7.46 5.19 -2.27 -0.454 0.38788E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.84 -3.48 -0.348 0.59443E+04 164 stilpnomelane-Fe 13.18 13.04 -0.14 -0.004 0.24591E+03 165 stilpnomelane-Mg 27.60 24.18 -3.42 -0.102 0.58407E+04 168 sudoite 21.22 17.54 -3.68 -0.119 0.62823E+04 171 talc 16.55 12.61 -3.95 -0.232 0.67369E+04 174 tephroite 18.11 13.65 -4.46 -0.637 0.76159E+04 177 topaz-H 4.67 1.84 -2.83 -0.257 0.48280E+04 178 tridymite -2.61 -3.27 -0.66 -0.219 0.11207E+04 187 wairakite 4.06 2.41 -1.65 -0.097 0.28197E+04 188 walstromite 11.53 7.11 -4.42 -0.884 0.75450E+04 189 wollastonite 10.48 7.11 -3.37 -0.675 0.57589E+04 190 pseudo-wollastonite 11.02 7.11 -3.91 -0.782 0.66775E+04 191 zoisite 22.96 18.61 -4.35 -0.198 0.74275E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.34 -2.78 -0.172 0.47431E+04 194 beidellite-H -2.24 -6.05 -3.81 -0.243 0.65040E+04 195 beidellite-K -1.44 -4.46 -3.02 -0.185 0.51612E+04 196 beidellite-Mg -1.71 -4.64 -2.93 -0.181 0.50034E+04 197 beidellite-Na -1.26 -3.91 -2.65 -0.163 0.45312E+04 199 chalcedony -2.79 -3.27 -0.48 -0.159 0.81375E+03 201 montmorillonite-Ca -2.21 -4.28 -2.06 -0.128 0.35233E+04 202 montmorillonite-K -2.16 -4.40 -2.24 -0.137 0.38191E+04 203 montmorillonite-Mg -2.40 -4.58 -2.18 -0.135 0.37146E+04 204 montmorillonite-Na -1.96 -3.85 -1.89 -0.116 0.32273E+04 205 nontronite-Ca 3.28 3.15 -0.13 -0.008 0.22288E+03 206 nontronite-H 2.60 1.44 -1.16 -0.078 0.19795E+04 207 nontronite-K 3.40 3.03 -0.37 -0.024 0.64019E+03 208 nontronite-Mg 3.14 2.85 -0.29 -0.019 0.49481E+03 209 nontronite-Na 3.58 3.58 -0.01 0.000 0.11922E+02 224 tobermorite 9.84 5.38 -4.46 -1.218 0.76211E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.34 -3.49 -0.872 0.59562E+04 240 silica-amorphous -2.08 -3.27 -1.19 -0.397 0.20340E+04 242 an20ab80 2.08 1.17 -0.91 -0.070 0.15519E+04 243 an25ab75 2.71 1.66 -1.05 -0.081 0.17974E+04 244 an30ab70 3.34 2.14 -1.20 -0.092 0.20512E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 1.5990000 g New total amount of reactant added: 1.6990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4568E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.6990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1452993E-02 Osmotic coef. = 0.9783 True ionic strength = .2285826E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.65119E-09 -9.1863 0.60206E-09 -9.2204 0.92455E+00 -0.0341 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12741E-03 -3.8948 0.92370E+00 -0.0345 4 SO4-- 0.25498E-04 -4.5935 0.19624E-04 -4.7072 0.76962E+00 -0.1137 5 HCO3- 0.11028E-04 -4.9575 0.10189E-04 -4.9919 0.92390E+00 -0.0344 6 HS- 0.29907E-13 -13.5242 0.27626E-13 -13.5587 0.92372E+00 -0.0345 7 Al+++ 0.13851E-24 -24.8585 0.78417E-25 -25.1056 0.56617E+00 -0.2471 8 H4SiO4 0.51756E-03 -3.2860 0.51756E-03 -3.2860 0.10000E+01 0.0000 9 Ca++ 0.14419E-07 -7.8411 0.11085E-07 -7.9553 0.76877E+00 -0.1142 10 Mg++ 0.17650E-09 -9.7533 0.13559E-09 -9.8678 0.76824E+00 -0.1145 11 Fe++ 0.10438E-11 -11.9814 0.80203E-12 -12.0958 0.76836E+00 -0.1144 12 K+ 0.48399E-04 -4.3152 0.44718E-04 -4.3495 0.92394E+00 -0.0344 13 Na+ 0.21998E-02 -2.6576 0.20320E-02 -2.6921 0.92368E+00 -0.0345 14 Mn++ 0.13946E-09 -9.8555 0.10717E-09 -9.9699 0.76846E+00 -0.1144 15 HPO4-- 0.99502E-05 -5.0022 0.76580E-05 -5.1159 0.76964E+00 -0.1137 16 HSiO3- 0.90800E-03 -3.0419 0.83872E-03 -3.0764 0.92370E+00 -0.0345 17 Ca(HSiO3)+ 0.22545E-09 -9.6470 0.20831E-09 -9.6813 0.92397E+00 -0.0343 18 Mg(HSiO3)+ 0.34320E-11 -11.4644 0.31711E-11 -11.4988 0.92397E+00 -0.0343 19 NaHSiO3,aq 0.27068E-04 -4.5676 0.27068E-04 -4.5676 0.10000E+01 0.0000 20 AlO+ 0.30226E-13 -13.5196 0.27928E-13 -13.5540 0.92397E+00 -0.0343 21 AlOH+2 0.10959E-18 -18.9602 0.84231E-19 -19.0745 0.76857E+00 -0.1143 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.37281E-04 -4.4285 0.34427E-04 -4.4631 0.92345E+00 -0.0346 24 CH4,aq 0.14081E-19 -19.8514 0.14075E-19 -19.8516 0.99955E+00 -0.0002 29 CO,aq 0.14834E-18 -18.8288 0.14834E-18 -18.8288 0.10000E+01 0.0000 30 CO2,aq 0.12373E-07 -7.9075 0.12368E-07 -7.9077 0.99955E+00 -0.0002 31 CO3-2 0.20337E-05 -5.6917 0.15647E-05 -5.8056 0.76937E+00 -0.1139 32 CaCO3,aq 0.21243E-09 -9.6728 0.21243E-09 -9.6728 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.30800E-11 -11.5115 0.28458E-11 -11.5458 0.92397E+00 -0.0343 34 CaCl+ 0.24357E-11 -11.6134 0.22505E-11 -11.6477 0.92397E+00 -0.0343 35 CaCl2,aq 0.66764E-16 -16.1755 0.66764E-16 -16.1755 0.10000E+01 0.0000 36 CaOH+ 0.14051E-08 -8.8523 0.12983E-08 -8.8866 0.92397E+00 -0.0343 37 CaSO4,aq 0.67777E-10 -10.1689 0.67777E-10 -10.1689 0.10000E+01 0.0000 38 HCl,aq 0.14429E-13 -13.8408 0.14429E-13 -13.8408 0.10000E+01 0.0000 43 FeCl+ 0.17225E-15 -15.7638 0.15916E-15 -15.7982 0.92397E+00 -0.0343 46 FeO,aq 0.87498E-10 -10.0580 0.87498E-10 -10.0580 0.10000E+01 0.0000 47 FeOH+ 0.47798E-10 -10.3206 0.44164E-10 -10.3549 0.92397E+00 -0.0343 48 HFeO2- 0.16923E-08 -8.7715 0.15632E-08 -8.8060 0.92370E+00 -0.0345 49 FeO+ 0.53901E-14 -14.2684 0.49803E-14 -14.3027 0.92397E+00 -0.0343 51 FeO2- 0.29235E-08 -8.5341 0.27004E-08 -8.5686 0.92370E+00 -0.0345 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.46589E-09 -9.3317 0.46568E-09 -9.3319 0.99955E+00 -0.0002 54 KCl,aq 0.10088E-09 -9.9962 0.10088E-09 -9.9962 0.10000E+01 0.0000 55 KHSO4,aq 0.14138E-17 -17.8496 0.14138E-17 -17.8496 0.10000E+01 0.0000 56 KOH,aq 0.32380E-07 -7.4897 0.32380E-07 -7.4897 0.10000E+01 0.0000 57 KSO4- 0.14636E-07 -7.8346 0.13520E-07 -7.8690 0.92370E+00 -0.0345 58 MgCO3,aq 0.64931E-12 -12.1875 0.64931E-12 -12.1875 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.38418E-13 -13.4155 0.35497E-13 -13.4498 0.92397E+00 -0.0343 60 MgCl+ 0.27048E-13 -13.5679 0.24992E-13 -13.6022 0.92397E+00 -0.0343 61 MgOH+ 0.95220E-10 -10.0213 0.87980E-10 -10.0556 0.92397E+00 -0.0343 63 MnO,aq 0.31212E-09 -9.5057 0.31212E-09 -9.5057 0.10000E+01 0.0000 64 MnOH+ 0.59333E-09 -9.2267 0.54822E-09 -9.2610 0.92397E+00 -0.0343 65 MnO2-2 0.38705E-13 -13.4122 0.29779E-13 -13.5261 0.76937E+00 -0.1139 66 HMnO2- 0.42053E-11 -11.3762 0.38845E-11 -11.4107 0.92370E+00 -0.0345 69 MnCl+ 0.89442E-13 -13.0485 0.82642E-13 -13.0828 0.92397E+00 -0.0343 70 MnSO4,aq 0.59602E-12 -12.2247 0.59602E-12 -12.2247 0.10000E+01 0.0000 71 NaCl,aq 0.84534E-07 -7.0730 0.84534E-07 -7.0730 0.10000E+01 0.0000 72 NaOH,aq 0.14830E-05 -5.8289 0.14830E-05 -5.8289 0.10000E+01 0.0000 74 OH- 0.10789E-02 -2.9670 0.99630E-03 -3.0016 0.92345E+00 -0.0346 79 HPO3-2 0.14641E-16 -16.8344 0.11264E-16 -16.9483 0.76937E+00 -0.1139 81 H2PO3- 0.14422E-19 -19.8410 0.13321E-19 -19.8755 0.92370E+00 -0.0345 82 H3PO4,aq 0.17871E-13 -13.7479 0.17871E-13 -13.7479 0.10000E+01 0.0000 83 H2PO4- 0.87498E-07 -7.0580 0.80833E-07 -7.0924 0.92383E+00 -0.0344 84 PO4-3 0.19473E-07 -7.7106 0.11108E-07 -7.9544 0.57043E+00 -0.2438 87 H2P2O7-2 0.66468E-15 -15.1774 0.51138E-15 -15.2913 0.76937E+00 -0.1139 88 HP2O7-3 0.30760E-12 -12.5120 0.17417E-12 -12.7590 0.56622E+00 -0.2470 89 P2O7-4 0.19270E-12 -12.7151 0.71367E-13 -13.1465 0.37036E+00 -0.4314 90 H2S,aq 0.49996E-16 -16.3011 0.49973E-16 -16.3013 0.99955E+00 -0.0002 97 SO3-2 0.16159E-14 -14.7916 0.12460E-14 -14.9045 0.77107E+00 -0.1129 98 HSO3- 0.47528E-16 -16.3231 0.43901E-16 -16.3575 0.92370E+00 -0.0345 99 HSO4- 0.11863E-10 -10.9258 0.10962E-10 -10.9601 0.92410E+00 -0.0343 Charge balance for all species = 0.4577E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6511910E-09 -.2166605E-02 -.2183366E+01 0.0000 2 H2O 0.1000000E+01 0.5550847E+02 0.9997994E+06 0.0000 3 Cl- 0.1379337E-03 0.1380183E-03 0.4892172E+01 5.3256 4 SO4-- 0.2549791E-04 0.2551290E-04 0.2450314E+01 13.7335 5 HCO3- 0.1102785E-04 0.1307418E-04 0.7975883E+00 4.2285 6 HS- 0.2990705E-13 -.2743658E-09 -.9071990E-05 -4.3383 7 Al+++ 0.1385051E-24 0.3729048E-04 0.1005949E+01 2.5555 8 H4SiO4 0.5175552E-03 0.1452625E-02 0.1395914E+03 -3.2860 9 Ca++ 0.1441915E-07 0.1633542E-07 0.6545585E-03 10.4855 10 Mg++ 0.1765013E-09 0.2758678E-09 0.6705541E-05 8.5730 11 Fe++ 0.1043820E-11 0.4955584E-08 0.2766985E-03 6.3449 12 K+ 0.4839896E-04 0.4844608E-04 0.1893955E+01 4.8708 13 Na+ 0.2199840E-02 0.2228475E-02 0.5122183E+02 6.5283 14 Mn++ 0.1394634E-09 0.1049844E-08 0.5766467E-04 8.4708 15 HPO4-- 0.9950205E-05 0.1005718E-04 0.9650824E+00 13.3248 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2811988E-01 -.2165913E-02 -.2595396E-01 0.0000000E+00 2 H2O 0.5548695E+02 0.5549073E+02 -.3776224E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7258955E-04 0.2550474E-04 0.4708481E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4708508E-04 -.2742781E-09 -.4708481E-04 0.0000000E+00 7 Al+++ 0.5540000E-02 0.3727856E-04 0.5502721E-02 0.0000000E+00 8 H4SiO4 0.1769132E-01 0.1452161E-02 0.1623916E-01 0.0000000E+00 9 Ca++ 0.1968563E-02 0.1633020E-07 0.1968547E-02 0.0000000E+00 10 Mg++ 0.1348413E-02 0.2757796E-09 0.1348412E-02 0.0000000E+00 11 Fe++ 0.1211402E-02 0.4954000E-08 0.1211397E-02 0.0000000E+00 12 K+ 0.3607219E-03 0.4843059E-04 0.3122913E-03 0.0000000E+00 13 Na+ 0.2292730E-02 0.2227763E-02 0.6496712E-04 0.0000000E+00 14 Mn++ 0.2945827E-04 0.1049509E-08 0.2945723E-04 0.0000000E+00 15 HPO4-- 0.1005396E-04 0.1005396E-04 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.3063E-17 Mass of aqueous solution: 0.999883E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.6990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2697E-03 -3.569 0.1499 -0.824 8.269 0.5702E-01 daphnite 0.1669E-03 -3.777 0.1191 -0.924 6.571 0.3610E-01 chlorite-Mn 0.5891E-05 -5.230 0.4177E-02 -2.379 0.2304 0.1331E-02 hematite 0.1883E-03 -3.725 0.3008E-01 -1.522 1.659 0.5701E-02 microcline 0.2256E-03 -3.647 0.6279E-01 -1.202 3.464 0.2453E-01 muscovite 0.8670E-04 -4.062 0.3453E-01 -1.462 1.905 0.1221E-01 paragonite 0.6497E-04 -4.187 0.2483E-01 -1.605 1.370 0.8583E-02 stilbite 0.1969E-02 -2.706 1.387 0.142 76.53 0.6470 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.812698 g Volume = 0.792516 cm3 Porosity: 52.8152% V(tot) - V(min): 0.88708E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.6990000 g log = 0.2302 Original solution: 1000.0103000 g Original solution / Rock added: 588.59 (Water/Rock Ratio), log = 2.7698 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1336E-05 1.0073 0.1416E-05 0.1405E-05 CH4,gas 0.2089E-16 1.0129 0.2226E-16 0.2197E-16 H2,gas 0.6068E-06 1.0006 0.6387E-06 0.6384E-06 H2S,gas 0.1391E-14 0.9959 0.1457E-14 0.1463E-14 S2,gas 0.1854E-36 1.0000 0.1950E-36 0.1950E-36 CO,gas 0.2227E-15 1.0000 0.2342E-15 0.2342E-15 SO3,gas 0.2528E-38 1.0000 0.2659E-38 0.2659E-38 SO2,gas 0.6108E-22 1.0000 0.6425E-22 0.6425E-22 HCl,gas 0.2422E-16 1.0000 0.2548E-16 0.2548E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.48529E-10 90 hematite 12.60 12.60 0.00 0.000 -0.21232E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.21 -7.85 -2.616 0.13402E+05 -5.849 3 CH4,gas 4.81 -13.84 -18.65 -4.663 0.31849E+05 -16.653 4 H2,gas 8.29 0.09 -8.19 -4.683 0.13992E+05 -6.195 5 H2S,gas -5.94 -22.78 -16.84 -8.418 0.28748E+05 -14.836 6 S2,gas -7.03 -45.74 -38.71 -5.955 0.66096E+05 -36.710 7 CO,gas 3.51 -14.12 -17.63 -5.425 0.30103E+05 -15.630 8 SO3,gas 17.43 -23.15 -40.58 -10.144 0.69281E+05 -38.575 9 SO2,gas 1.14 -23.06 -24.19 -6.451 0.41307E+05 -22.192 10 HCl,gas 5.48 -13.12 -18.59 -9.297 0.31749E+05 -16.594 11 acmite 7.74 6.25 -1.48 -0.154 0.25312E+04 15 albite-high 0.75 -0.77 -1.52 -0.117 0.26022E+04 16 albite -0.33 -0.77 -0.45 -0.034 0.76153E+03 19 spessartine 24.55 20.67 -3.88 -0.194 0.66329E+04 20 analcite 3.37 2.51 -0.86 -0.095 0.14666E+04 21 andalusite 5.06 1.82 -3.24 -0.324 0.55278E+04 22 andradite 39.09 34.20 -4.89 -0.254 0.83528E+04 26 annite 20.21 16.60 -3.61 -0.200 0.61578E+04 27 phlogopite 27.15 23.29 -3.86 -0.214 0.65900E+04 29 anorthite 12.80 9.02 -3.77 -0.290 0.64428E+04 32 apatite-OH -17.99 -18.24 -0.25 -0.020 0.43328E+03 35 aragonite 0.99 -3.73 -4.71 -1.571 0.80473E+04 36 brucite 12.58 8.57 -4.00 -0.801 0.68361E+04 37 calcite 0.83 -3.73 -4.56 -1.520 0.77860E+04 38 carnegieite-low 9.06 5.80 -3.27 -0.467 0.55780E+04 39 carnegieite-high 10.13 5.80 -4.34 -0.620 0.74049E+04 40 carpholite-Mg 8.65 7.11 -1.54 -0.103 0.26270E+04 41 carpholite-Fe 6.78 4.88 -1.90 -0.127 0.32426E+04 42 celadonite 5.40 2.86 -2.55 -0.150 0.43462E+04 43 celadonite-Fe 3.94 0.63 -3.31 -0.195 0.56515E+04 44 chrysotile 23.94 19.15 -4.79 -0.399 0.81797E+04 50 chloritoid-Mg 13.26 10.40 -2.86 -0.191 0.48891E+04 51 chloritoid-Fe 9.24 8.17 -1.07 -0.071 0.18250E+04 52 chloritoid-Mn 11.46 10.30 -1.17 -0.078 0.19934E+04 54 coesite -2.37 -3.29 -0.92 -0.306 0.15652E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.29 -0.74 -0.246 0.12581E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.49 -3.73 -0.373 0.63674E+04 68 hedenbergite 14.24 10.26 -3.99 -0.399 0.68062E+04 75 epidote 24.78 22.52 -2.25 -0.109 0.38463E+04 76 clinozoisite 22.92 18.78 -4.14 -0.188 0.70721E+04 77 epidote-Fe 29.94 26.27 -3.67 -0.191 0.62679E+04 78 fayalite 14.08 9.40 -4.68 -0.668 0.79827E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63715E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.51 -1.74 -0.174 0.29697E+04 97 kalsilite 7.62 4.14 -3.48 -0.497 0.59419E+04 98 kaolinite -1.27 -1.46 -0.19 -0.017 0.32093E+03 99 kyanite 4.93 1.82 -3.11 -0.311 0.53046E+04 101 laumontite 2.97 2.45 -0.52 -0.035 0.89176E+03 102 lawsonite 9.68 9.02 -0.65 -0.044 0.11167E+04 103 leucite 4.17 0.85 -3.31 -0.331 0.56575E+04 105 lizardite 23.29 19.15 -4.14 -0.345 0.70700E+04 107 magnetite 20.13 18.94 -1.19 -0.097 0.20323E+04 108 minnesotaite 10.46 5.89 -4.57 -0.269 0.78034E+04 113 margarite 17.45 14.14 -3.32 -0.133 0.56627E+04 122 nepheline 8.38 5.80 -2.58 -0.369 0.44060E+04 134 phlogopite-Na 29.73 24.94 -4.79 -0.266 0.81734E+04 136 prehnite 19.47 16.22 -3.24 -0.191 0.55366E+04 137 prehnite-Fe 22.59 19.97 -2.62 -0.158 0.44730E+04 145 pyroxmangite 7.42 5.18 -2.23 -0.446 0.38098E+04 146 pyrophyllite -6.10 -8.03 -1.94 -0.121 0.33042E+04 147 quartz -2.98 -3.29 -0.30 -0.101 0.51915E+03 151 rhodochrosite -0.96 -5.74 -4.78 -1.594 0.81667E+04 152 rhodonite 7.46 5.18 -2.28 -0.456 0.38891E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.82 -3.50 -0.350 0.59700E+04 164 stilpnomelane-Fe 13.18 12.98 -0.20 -0.006 0.33589E+03 165 stilpnomelane-Mg 27.60 24.12 -3.47 -0.104 0.59307E+04 168 sudoite 21.22 17.51 -3.71 -0.120 0.63286E+04 171 talc 16.55 12.57 -3.98 -0.234 0.67934E+04 174 tephroite 18.11 13.66 -4.46 -0.637 0.76108E+04 177 topaz-H 4.67 1.82 -2.84 -0.258 0.48537E+04 178 tridymite -2.61 -3.29 -0.67 -0.224 0.11464E+04 187 wairakite 4.06 2.45 -1.61 -0.094 0.27426E+04 188 walstromite 11.53 7.20 -4.33 -0.866 0.73907E+04 189 wollastonite 10.48 7.20 -3.28 -0.656 0.56046E+04 190 pseudo-wollastonite 11.02 7.20 -3.82 -0.764 0.65232E+04 191 zoisite 22.96 18.78 -4.18 -0.190 0.71447E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.38 -2.82 -0.174 0.48077E+04 194 beidellite-H -2.24 -6.11 -3.86 -0.247 0.65983E+04 195 beidellite-K -1.44 -4.50 -3.06 -0.188 0.52301E+04 196 beidellite-Mg -1.71 -4.69 -2.98 -0.185 0.50952E+04 197 beidellite-Na -1.26 -3.95 -2.69 -0.165 0.46001E+04 199 chalcedony -2.79 -3.29 -0.49 -0.164 0.83946E+03 201 montmorillonite-Ca -2.21 -4.32 -2.10 -0.130 0.35913E+04 202 montmorillonite-K -2.16 -4.44 -2.28 -0.140 0.38914E+04 203 montmorillonite-Mg -2.40 -4.63 -2.23 -0.138 0.38098E+04 204 montmorillonite-Na -1.96 -3.89 -1.93 -0.118 0.32996E+04 205 nontronite-Ca 3.28 3.11 -0.17 -0.011 0.28754E+03 206 nontronite-H 2.60 1.38 -1.21 -0.081 0.20739E+04 207 nontronite-K 3.40 2.99 -0.42 -0.027 0.70909E+03 208 nontronite-Mg 3.14 2.80 -0.34 -0.022 0.58662E+03 209 nontronite-Na 3.58 3.54 -0.05 -0.003 0.80823E+02 224 tobermorite 9.84 5.45 -4.39 -1.198 0.74969E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.34 -3.48 -0.870 0.59408E+04 240 silica-amorphous -2.08 -3.29 -1.21 -0.402 0.20597E+04 242 an20ab80 2.08 1.19 -0.89 -0.069 0.15262E+04 243 an25ab75 2.71 1.68 -1.03 -0.080 0.17652E+04 244 an30ab70 3.34 2.17 -1.18 -0.091 0.20127E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 1.6990000 g New total amount of reactant added: 1.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4568E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.7990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1513303E-02 Osmotic coef. = 0.9779 True ionic strength = .2381954E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.61462E-09 -9.2114 0.56759E-09 -9.2460 0.92348E+00 -0.0346 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12726E-03 -3.8953 0.92260E+00 -0.0350 4 SO4-- 0.25498E-04 -4.5935 0.19531E-04 -4.7093 0.76600E+00 -0.1158 5 HCO3- 0.10919E-04 -4.9618 0.10076E-04 -4.9967 0.92281E+00 -0.0349 6 HS- 0.32935E-13 -13.4823 0.30386E-13 -13.5173 0.92262E+00 -0.0350 7 Al+++ 0.11730E-24 -24.9307 0.65704E-25 -25.1824 0.56015E+00 -0.2517 8 H4SiO4 0.50070E-03 -3.3004 0.50070E-03 -3.3004 0.10000E+01 0.0000 9 Ca++ 0.16235E-07 -7.7896 0.12422E-07 -7.9058 0.76512E+00 -0.1163 10 Mg++ 0.16078E-09 -9.7938 0.12293E-09 -9.9103 0.76457E+00 -0.1166 11 Fe++ 0.95085E-12 -12.0219 0.72712E-12 -12.1384 0.76470E+00 -0.1165 12 K+ 0.50452E-04 -4.2971 0.46560E-04 -4.3320 0.92285E+00 -0.0349 13 Na+ 0.22932E-02 -2.6396 0.21157E-02 -2.6746 0.92258E+00 -0.0350 14 Mn++ 0.12704E-09 -9.8961 0.97162E-10 -10.0125 0.76480E+00 -0.1165 15 HPO4-- 0.10540E-04 -4.9772 0.80740E-05 -5.0929 0.76602E+00 -0.1158 16 HSiO3- 0.93290E-03 -3.0302 0.86069E-03 -3.0652 0.92260E+00 -0.0350 17 Ca(HSiO3)+ 0.25956E-09 -9.5858 0.23954E-09 -9.6206 0.92288E+00 -0.0349 18 Mg(HSiO3)+ 0.31967E-11 -11.4953 0.29502E-11 -11.5301 0.92288E+00 -0.0349 19 NaHSiO3,aq 0.28921E-04 -4.5388 0.28921E-04 -4.5388 0.10000E+01 0.0000 20 AlO+ 0.28530E-13 -13.5447 0.26329E-13 -13.5796 0.92288E+00 -0.0349 21 AlOH+2 0.97868E-19 -19.0094 0.74861E-19 -19.1257 0.76492E+00 -0.1164 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.39593E-04 -4.4024 0.36518E-04 -4.4375 0.92233E+00 -0.0351 24 CH4,aq 0.15390E-19 -19.8128 0.15383E-19 -19.8130 0.99953E+00 -0.0002 29 CO,aq 0.14390E-18 -18.8419 0.14390E-18 -18.8419 0.10000E+01 0.0000 30 CO2,aq 0.11536E-07 -7.9379 0.11531E-07 -7.9381 0.99953E+00 -0.0002 31 CO3-2 0.21436E-05 -5.6689 0.16414E-05 -5.7848 0.76574E+00 -0.1159 32 CaCO3,aq 0.24971E-09 -9.6026 0.24971E-09 -9.6026 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.34173E-11 -11.4663 0.31537E-11 -11.5012 0.92288E+00 -0.0349 34 CaCl+ 0.27294E-11 -11.5639 0.25189E-11 -11.5988 0.92288E+00 -0.0349 35 CaCl2,aq 0.74634E-16 -16.1271 0.74634E-16 -16.1271 0.10000E+01 0.0000 36 CaOH+ 0.16721E-08 -8.7767 0.15432E-08 -8.8116 0.92288E+00 -0.0349 37 CaSO4,aq 0.75591E-10 -10.1215 0.75591E-10 -10.1215 0.10000E+01 0.0000 38 HCl,aq 0.13586E-13 -13.8669 0.13586E-13 -13.8669 0.10000E+01 0.0000 43 FeCl+ 0.15616E-15 -15.8064 0.14412E-15 -15.8413 0.92288E+00 -0.0349 46 FeO,aq 0.89253E-10 -10.0494 0.89253E-10 -10.0494 0.10000E+01 0.0000 47 FeOH+ 0.46020E-10 -10.3371 0.42471E-10 -10.3719 0.92288E+00 -0.0349 48 HFeO2- 0.18333E-08 -8.7368 0.16914E-08 -8.7718 0.92260E+00 -0.0350 49 FeO+ 0.50875E-14 -14.2935 0.46952E-14 -14.3283 0.92288E+00 -0.0349 51 FeO2- 0.31047E-08 -8.5080 0.28644E-08 -8.5430 0.92260E+00 -0.0350 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.48478E-09 -9.3145 0.48456E-09 -9.3147 0.99953E+00 -0.0002 54 KCl,aq 0.10491E-09 -9.9792 0.10491E-09 -9.9792 0.10000E+01 0.0000 55 KHSO4,aq 0.13812E-17 -17.8597 0.13812E-17 -17.8597 0.10000E+01 0.0000 56 KOH,aq 0.35761E-07 -7.4466 0.35761E-07 -7.4466 0.10000E+01 0.0000 57 KSO4- 0.15186E-07 -7.8186 0.14010E-07 -7.8536 0.92260E+00 -0.0350 58 MgCO3,aq 0.61752E-12 -12.2093 0.61752E-12 -12.2093 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.34486E-13 -13.4624 0.31826E-13 -13.4972 0.92288E+00 -0.0349 60 MgCl+ 0.24521E-13 -13.6105 0.22630E-13 -13.6453 0.92288E+00 -0.0349 61 MgOH+ 0.91677E-10 -10.0377 0.84607E-10 -10.0726 0.92288E+00 -0.0349 63 MnO,aq 0.31838E-09 -9.4971 0.31838E-09 -9.4971 0.10000E+01 0.0000 64 MnOH+ 0.57126E-09 -9.2432 0.52720E-09 -9.2780 0.92288E+00 -0.0349 65 MnO2-2 0.44634E-13 -13.3503 0.34178E-13 -13.4662 0.76574E+00 -0.1159 66 HMnO2- 0.45557E-11 -11.3414 0.42031E-11 -11.3764 0.92260E+00 -0.0350 69 MnCl+ 0.81086E-13 -13.0911 0.74833E-13 -13.1259 0.92288E+00 -0.0349 70 MnSO4,aq 0.53781E-12 -12.2694 0.53781E-12 -12.2694 0.10000E+01 0.0000 71 NaCl,aq 0.87910E-07 -7.0560 0.87910E-07 -7.0560 0.10000E+01 0.0000 72 NaOH,aq 0.16379E-05 -5.7857 0.16379E-05 -5.7857 0.10000E+01 0.0000 74 OH- 0.11458E-02 -2.9409 0.10568E-02 -2.9760 0.92233E+00 -0.0351 79 HPO3-2 0.16138E-16 -16.7922 0.12357E-16 -16.9081 0.76574E+00 -0.1159 81 H2PO3- 0.14933E-19 -19.8258 0.13777E-19 -19.8608 0.92260E+00 -0.0350 82 H3PO4,aq 0.16746E-13 -13.7761 0.16746E-13 -13.7761 0.10000E+01 0.0000 83 H2PO4- 0.87072E-07 -7.0601 0.80344E-07 -7.0950 0.92273E+00 -0.0349 84 PO4-3 0.22006E-07 -7.6575 0.12423E-07 -7.9058 0.56453E+00 -0.2483 87 H2P2O7-2 0.65977E-15 -15.1806 0.50521E-15 -15.2965 0.76574E+00 -0.1159 88 HP2O7-3 0.32581E-12 -12.4870 0.18252E-12 -12.7387 0.56020E+00 -0.2517 89 P2O7-4 0.21827E-12 -12.6610 0.79330E-13 -13.1006 0.36345E+00 -0.4396 90 H2S,aq 0.51844E-16 -16.2853 0.51819E-16 -16.2855 0.99953E+00 -0.0002 97 SO3-2 0.16813E-14 -14.7744 0.12904E-14 -14.8893 0.76750E+00 -0.1149 98 HSO3- 0.46458E-16 -16.3329 0.42862E-16 -16.3679 0.92260E+00 -0.0350 99 HSO4- 0.11144E-10 -10.9530 0.10286E-10 -10.9878 0.92301E+00 -0.0348 Charge balance for all species = 0.4578E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6146185E-09 -.2269789E-02 -.2287339E+01 0.0000 2 H2O 0.1000000E+01 0.5550852E+02 0.9997961E+06 0.0000 3 Cl- 0.1379326E-03 0.1380206E-03 0.4892233E+01 5.3506 4 SO4-- 0.2549777E-04 0.2551334E-04 0.2450346E+01 13.7827 5 HCO3- 0.1091905E-04 0.1307440E-04 0.7975983E+00 4.2493 6 HS- 0.3293490E-13 -.2922992E-09 -.9664923E-05 -4.2714 7 Al+++ 0.1172966E-24 0.3960260E-04 0.1068317E+01 2.5555 8 H4SiO4 0.5006997E-03 0.1462520E-02 0.1405417E+03 -3.3004 9 Ca++ 0.1623480E-07 0.1849793E-07 0.7412071E-03 10.5861 10 Mg++ 0.1607825E-09 0.2563332E-09 0.6230687E-05 8.5816 11 Fe++ 0.9508545E-12 0.5277739E-08 0.2946850E-03 6.3535 12 K+ 0.5045246E-04 0.5050351E-04 0.1974381E+01 4.9140 13 Na+ 0.2293201E-02 0.2323848E-02 0.5341377E+02 6.5714 14 Mn++ 0.1270421E-09 0.1021905E-08 0.5612981E-04 8.4794 15 HPO4-- 0.1054022E-04 0.1064930E-04 0.1021898E+01 13.3990 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2977573E-01 -.2269026E-02 -.2750670E-01 0.0000000E+00 2 H2O 0.5548570E+02 0.5548985E+02 -.4155896E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7536089E-04 0.2550476E-04 0.4985613E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4985642E-04 -.2922009E-09 -.4985613E-04 0.0000000E+00 7 Al+++ 0.5866074E-02 0.3958928E-04 0.5826485E-02 0.0000000E+00 8 H4SiO4 0.1873260E-01 0.1462028E-02 0.1727057E-01 0.0000000E+00 9 Ca++ 0.2083578E-02 0.1849172E-07 0.2083559E-02 0.0000000E+00 10 Mg++ 0.1427778E-02 0.2562470E-09 0.1427778E-02 0.0000000E+00 11 Fe++ 0.1282702E-02 0.5275965E-08 0.1282697E-02 0.0000000E+00 12 K+ 0.3819533E-03 0.5048654E-04 0.3314668E-03 0.0000000E+00 13 Na+ 0.2418254E-02 0.2323066E-02 0.9518781E-04 0.0000000E+00 14 Mn++ 0.3119213E-04 0.1021561E-08 0.3119111E-04 0.0000000E+00 15 HPO4-- 0.1064572E-04 0.1064572E-04 0.0000000E+00 0.0000000E+00 Chg. balance for solid moles: -.3578E-17 Mass of aqueous solution: 0.999870E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2856E-03 -3.544 0.1587 -0.799 8.248 0.6037E-01 daphnite 0.1768E-03 -3.753 0.1261 -0.899 6.554 0.3822E-01 chlorite-Mn 0.6238E-05 -5.205 0.4423E-02 -2.354 0.2298 0.1409E-02 hematite 0.1994E-03 -3.700 0.3185E-01 -1.497 1.655 0.6036E-02 microcline 0.2789E-03 -3.555 0.7762E-01 -1.110 4.033 0.3032E-01 muscovite 0.5260E-04 -4.279 0.2095E-01 -1.679 1.089 0.7409E-02 paragonite 0.9519E-04 -4.021 0.3638E-01 -1.439 1.891 0.1258E-01 stilbite 0.2084E-02 -2.681 1.468 0.167 76.30 0.6849 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.924396 g Volume = 0.841197 cm3 Porosity: 51.0818% V(tot) - V(min): 0.87840E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.7990000 g log = 0.2550 Original solution: 1000.0103000 g Original solution / Rock added: 555.87 (Water/Rock Ratio), log = 2.7450 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1246E-05 1.0073 0.1320E-05 0.1310E-05 CH4,gas 0.2283E-16 1.0129 0.2433E-16 0.2402E-16 H2,gas 0.6314E-06 1.0006 0.6646E-06 0.6642E-06 H2S,gas 0.1443E-14 0.9959 0.1511E-14 0.1518E-14 S2,gas 0.1841E-36 1.0000 0.1937E-36 0.1937E-36 CO,gas 0.2160E-15 1.0000 0.2272E-15 0.2272E-15 SO3,gas 0.2236E-38 1.0000 0.2352E-38 0.2352E-38 SO2,gas 0.5622E-22 1.0000 0.5914E-22 0.5914E-22 HCl,gas 0.2280E-16 1.0000 0.2399E-16 0.2399E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.42463E-10 121 paragonite 4.34 4.34 0.00 0.000 -0.28814E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 32 apatite-OH -17.99 -17.82 0.16 0.013 -0.28137E+03 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.24 -7.88 -2.626 0.13454E+05 -5.879 3 CH4,gas 4.81 -13.80 -18.61 -4.653 0.31783E+05 -16.614 4 H2,gas 8.29 0.11 -8.18 -4.673 0.13963E+05 -6.177 5 H2S,gas -5.94 -22.76 -16.82 -8.410 0.28721E+05 -14.821 6 S2,gas -7.03 -45.75 -38.71 -5.956 0.66101E+05 -36.713 7 CO,gas 3.51 -14.13 -17.64 -5.429 0.30126E+05 -15.644 8 SO3,gas 17.43 -23.20 -40.63 -10.157 0.69372E+05 -38.629 9 SO2,gas 1.14 -23.09 -24.23 -6.461 0.41369E+05 -22.228 10 HCl,gas 5.48 -13.14 -18.62 -9.310 0.31793E+05 -16.620 11 acmite 7.74 6.27 -1.47 -0.153 0.25066E+04 15 albite-high 0.75 -0.77 -1.52 -0.117 0.26022E+04 16 albite -0.33 -0.77 -0.45 -0.034 0.76153E+03 19 spessartine 24.55 20.65 -3.90 -0.195 0.66624E+04 20 analcite 3.37 2.53 -0.84 -0.094 0.14421E+04 21 andalusite 5.06 1.81 -3.25 -0.325 0.55524E+04 22 andradite 39.09 34.45 -4.63 -0.241 0.79108E+04 26 annite 20.21 16.63 -3.58 -0.199 0.61136E+04 27 phlogopite 27.15 23.31 -3.83 -0.213 0.65458E+04 29 anorthite 12.80 9.10 -3.70 -0.285 0.63201E+04 35 aragonite 0.99 -3.66 -4.64 -1.548 0.79274E+04 36 brucite 12.58 8.58 -4.00 -0.799 0.68214E+04 37 calcite 0.83 -3.66 -4.49 -1.497 0.76661E+04 38 carnegieite-low 9.06 5.83 -3.24 -0.463 0.55289E+04 39 carnegieite-high 10.13 5.83 -4.31 -0.615 0.73558E+04 40 carpholite-Mg 8.65 7.09 -1.56 -0.104 0.26613E+04 41 carpholite-Fe 6.78 4.86 -1.92 -0.128 0.32770E+04 42 celadonite 5.40 2.85 -2.55 -0.150 0.43560E+04 43 celadonite-Fe 3.94 0.62 -3.32 -0.195 0.56613E+04 44 chrysotile 23.94 19.14 -4.79 -0.399 0.81846E+04 50 chloritoid-Mg 13.26 10.39 -2.87 -0.191 0.48989E+04 51 chloritoid-Fe 9.24 8.16 -1.07 -0.072 0.18348E+04 52 chloritoid-Mn 11.46 10.29 -1.17 -0.078 0.20032E+04 54 coesite -2.37 -3.30 -0.93 -0.310 0.15898E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.30 -0.75 -0.250 0.12827E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.57 -3.65 -0.365 0.62299E+04 68 hedenbergite 14.24 10.34 -3.91 -0.391 0.66687E+04 75 epidote 24.78 22.68 -2.09 -0.102 0.35762E+04 76 clinozoisite 22.92 18.94 -3.98 -0.181 0.68021E+04 77 epidote-Fe 29.94 26.42 -3.51 -0.182 0.59978E+04 78 fayalite 14.08 9.41 -4.67 -0.667 0.79778E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63764E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.53 -1.72 -0.172 0.29451E+04 97 kalsilite 7.62 4.17 -3.45 -0.493 0.58928E+04 98 kaolinite -1.27 -1.49 -0.22 -0.020 0.37003E+03 99 kyanite 4.93 1.81 -3.12 -0.312 0.53291E+04 101 laumontite 2.97 2.50 -0.48 -0.032 0.81810E+03 102 lawsonite 9.68 9.10 -0.58 -0.039 0.99395E+03 103 leucite 4.17 0.87 -3.30 -0.330 0.56330E+04 105 lizardite 23.29 19.14 -4.14 -0.345 0.70749E+04 107 magnetite 20.13 18.95 -1.18 -0.096 0.20176E+04 108 minnesotaite 10.46 5.86 -4.60 -0.271 0.78574E+04 113 margarite 17.45 14.21 -3.24 -0.130 0.55400E+04 122 nepheline 8.38 5.83 -2.55 -0.365 0.43569E+04 134 phlogopite-Na 29.73 24.97 -4.76 -0.264 0.81292E+04 136 prehnite 19.47 16.38 -3.08 -0.181 0.52665E+04 137 prehnite-Fe 22.59 20.13 -2.46 -0.148 0.42029E+04 138 pumpellyite-Fe 46.47 41.67 -4.80 -0.107 0.81918E+04 145 pyroxmangite 7.42 5.18 -2.24 -0.447 0.38197E+04 146 pyrophyllite -6.10 -8.09 -1.99 -0.125 0.34024E+04 147 quartz -2.98 -3.30 -0.32 -0.106 0.54370E+03 151 rhodochrosite -0.96 -5.76 -4.80 -1.602 0.82039E+04 152 rhodonite 7.46 5.18 -2.28 -0.457 0.38989E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.81 -3.51 -0.351 0.59946E+04 164 stilpnomelane-Fe 13.18 12.93 -0.25 -0.007 0.42182E+03 165 stilpnomelane-Mg 27.60 24.07 -3.52 -0.105 0.60166E+04 168 sudoite 21.22 17.48 -3.73 -0.120 0.63728E+04 171 talc 16.55 12.54 -4.01 -0.236 0.68475E+04 174 tephroite 18.11 13.66 -4.45 -0.636 0.76059E+04 177 topaz-H 4.67 1.81 -2.86 -0.260 0.48782E+04 178 tridymite -2.61 -3.30 -0.69 -0.229 0.11710E+04 187 wairakite 4.06 2.50 -1.56 -0.092 0.26689E+04 188 walstromite 11.53 7.29 -4.24 -0.848 0.72434E+04 189 wollastonite 10.48 7.29 -3.20 -0.639 0.54573E+04 190 pseudo-wollastonite 11.02 7.29 -3.73 -0.747 0.63759E+04 191 zoisite 22.96 18.94 -4.03 -0.183 0.68746E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.41 -2.85 -0.176 0.48695E+04 194 beidellite-H -2.24 -6.16 -3.92 -0.250 0.66884E+04 195 beidellite-K -1.44 -4.54 -3.10 -0.190 0.52959E+04 196 beidellite-Mg -1.71 -4.74 -3.04 -0.188 0.51829E+04 197 beidellite-Na -1.26 -3.99 -2.73 -0.167 0.46659E+04 199 chalcedony -2.79 -3.30 -0.51 -0.169 0.86402E+03 201 montmorillonite-Ca -2.21 -4.36 -2.14 -0.132 0.36563E+04 202 montmorillonite-K -2.16 -4.48 -2.32 -0.142 0.39605E+04 203 montmorillonite-Mg -2.40 -4.69 -2.28 -0.141 0.39007E+04 204 montmorillonite-Na -1.96 -3.93 -1.97 -0.121 0.33687E+04 205 nontronite-Ca 3.28 3.08 -0.20 -0.013 0.34929E+03 206 nontronite-H 2.60 1.33 -1.27 -0.085 0.21640E+04 207 nontronite-K 3.40 2.95 -0.45 -0.029 0.77489E+03 208 nontronite-Mg 3.14 2.74 -0.39 -0.026 0.67429E+03 209 nontronite-Na 3.58 3.50 -0.09 -0.006 0.14662E+03 224 tobermorite 9.84 5.52 -4.32 -1.179 0.73783E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.35 -3.47 -0.868 0.59261E+04 240 silica-amorphous -2.08 -3.30 -1.22 -0.407 0.20842E+04 242 an20ab80 2.08 1.20 -0.88 -0.068 0.15016E+04 243 an25ab75 2.71 1.69 -1.02 -0.078 0.17346E+04 244 an30ab70 3.34 2.19 -1.16 -0.089 0.19758E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.7990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9997E+00 Moles total = 0.5549E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1508422E-02 Osmotic coef. = 0.9779 True ionic strength = .2376315E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.61544E-09 -9.2108 0.56839E-09 -9.2454 0.92354E+00 -0.0345 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12727E-03 -3.8953 0.92266E+00 -0.0350 4 SO4-- 0.25498E-04 -4.5935 0.19537E-04 -4.7092 0.76621E+00 -0.1157 5 HCO3- 0.10922E-04 -4.9617 0.10080E-04 -4.9966 0.92287E+00 -0.0349 6 HS- 0.32817E-13 -13.4839 0.30280E-13 -13.5188 0.92268E+00 -0.0349 7 Al+++ 0.11772E-24 -24.9291 0.65982E-25 -25.1806 0.56050E+00 -0.2514 8 H4SiO4 0.50124E-03 -3.3000 0.50124E-03 -3.3000 0.10000E+01 0.0000 9 Ca++ 0.16153E-07 -7.7917 0.12363E-07 -7.9079 0.76533E+00 -0.1161 10 Mg++ 0.16109E-09 -9.7929 0.12320E-09 -9.9094 0.76478E+00 -0.1165 11 Fe++ 0.95265E-12 -12.0211 0.72870E-12 -12.1375 0.76491E+00 -0.1164 12 K+ 0.50356E-04 -4.2979 0.46474E-04 -4.3328 0.92291E+00 -0.0348 13 Na+ 0.22888E-02 -2.6404 0.21118E-02 -2.6754 0.92264E+00 -0.0350 14 Mn++ 0.12728E-09 -9.8952 0.97373E-10 -10.0116 0.76501E+00 -0.1163 15 HPO4-- 0.93769E-05 -5.0279 0.71848E-05 -5.1436 0.76622E+00 -0.1156 16 HSiO3- 0.93253E-03 -3.0303 0.86041E-03 -3.0653 0.92266E+00 -0.0350 17 Ca(HSiO3)+ 0.25822E-09 -9.5880 0.23832E-09 -9.6228 0.92294E+00 -0.0348 18 Mg(HSiO3)+ 0.32024E-11 -11.4945 0.29556E-11 -11.5293 0.92294E+00 -0.0348 19 NaHSiO3,aq 0.28858E-04 -4.5397 0.28858E-04 -4.5397 0.10000E+01 0.0000 20 AlO+ 0.28568E-13 -13.5441 0.26366E-13 -13.5790 0.92294E+00 -0.0348 21 AlOH+2 0.98117E-19 -19.0083 0.75072E-19 -19.1245 0.76513E+00 -0.1163 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.39535E-04 -4.4030 0.36467E-04 -4.4381 0.92240E+00 -0.0351 24 CH4,aq 0.15337E-19 -19.8143 0.15330E-19 -19.8145 0.99953E+00 -0.0002 29 CO,aq 0.14397E-18 -18.8417 0.14397E-18 -18.8417 0.10000E+01 0.0000 30 CO2,aq 0.11556E-07 -7.9372 0.11551E-07 -7.9374 0.99953E+00 -0.0002 31 CO3-2 0.21407E-05 -5.6695 0.16396E-05 -5.7853 0.76595E+00 -0.1158 32 CaCO3,aq 0.24826E-09 -9.6051 0.24826E-09 -9.6051 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.34019E-11 -11.4683 0.31398E-11 -11.5031 0.92294E+00 -0.0348 34 CaCl+ 0.27164E-11 -11.5660 0.25071E-11 -11.6008 0.92294E+00 -0.0348 35 CaCl2,aq 0.74290E-16 -16.1291 0.74290E-16 -16.1291 0.10000E+01 0.0000 36 CaOH+ 0.16617E-08 -8.7794 0.15337E-08 -8.8143 0.92294E+00 -0.0348 37 CaSO4,aq 0.75253E-10 -10.1235 0.75253E-10 -10.1235 0.10000E+01 0.0000 38 HCl,aq 0.13606E-13 -13.8663 0.13606E-13 -13.8663 0.10000E+01 0.0000 43 FeCl+ 0.15650E-15 -15.8055 0.14444E-15 -15.8403 0.92294E+00 -0.0348 46 FeO,aq 0.89195E-10 -10.0497 0.89195E-10 -10.0497 0.10000E+01 0.0000 47 FeOH+ 0.46052E-10 -10.3368 0.42503E-10 -10.3716 0.92294E+00 -0.0348 48 HFeO2- 0.18294E-08 -8.7377 0.16879E-08 -8.7727 0.92266E+00 -0.0350 49 FeO+ 0.50943E-14 -14.2929 0.47018E-14 -14.3277 0.92294E+00 -0.0348 51 FeO2- 0.31002E-08 -8.5086 0.28604E-08 -8.5436 0.92266E+00 -0.0350 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.48415E-09 -9.3150 0.48393E-09 -9.3152 0.99953E+00 -0.0002 54 KCl,aq 0.10473E-09 -9.9799 0.10473E-09 -9.9799 0.10000E+01 0.0000 55 KHSO4,aq 0.13810E-17 -17.8598 0.13810E-17 -17.8598 0.10000E+01 0.0000 56 KOH,aq 0.35645E-07 -7.4480 0.35645E-07 -7.4480 0.10000E+01 0.0000 57 KSO4- 0.15161E-07 -7.8193 0.13988E-07 -7.8542 0.92266E+00 -0.0350 58 MgCO3,aq 0.61820E-12 -12.2089 0.61820E-12 -12.2089 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.34570E-13 -13.4613 0.31906E-13 -13.4961 0.92294E+00 -0.0348 60 MgCl+ 0.24574E-13 -13.6095 0.22681E-13 -13.6443 0.92294E+00 -0.0348 61 MgOH+ 0.91741E-10 -10.0374 0.84671E-10 -10.0723 0.92294E+00 -0.0348 63 MnO,aq 0.31817E-09 -9.4973 0.31817E-09 -9.4973 0.10000E+01 0.0000 64 MnOH+ 0.57166E-09 -9.2429 0.52761E-09 -9.2777 0.92294E+00 -0.0348 65 MnO2-2 0.44468E-13 -13.3520 0.34060E-13 -13.4678 0.76595E+00 -0.1158 66 HMnO2- 0.45460E-11 -11.3424 0.41944E-11 -11.3773 0.92266E+00 -0.0350 69 MnCl+ 0.81262E-13 -13.0901 0.75000E-13 -13.1249 0.92294E+00 -0.0348 70 MnSO4,aq 0.53912E-12 -12.2683 0.53912E-12 -12.2683 0.10000E+01 0.0000 71 NaCl,aq 0.87755E-07 -7.0567 0.87755E-07 -7.0567 0.10000E+01 0.0000 72 NaOH,aq 0.16326E-05 -5.7871 0.16326E-05 -5.7871 0.10000E+01 0.0000 74 OH- 0.11441E-02 -2.9415 0.10553E-02 -2.9766 0.92240E+00 -0.0351 79 HPO3-2 0.14338E-16 -16.8435 0.10982E-16 -16.9593 0.76595E+00 -0.1158 81 H2PO3- 0.13289E-19 -19.8765 0.12261E-19 -19.9115 0.92266E+00 -0.0350 82 H3PO4,aq 0.14944E-13 -13.8255 0.14944E-13 -13.8255 0.10000E+01 0.0000 83 H2PO4- 0.77587E-07 -7.1102 0.71597E-07 -7.1451 0.92280E+00 -0.0349 84 PO4-3 0.19543E-07 -7.7090 0.11039E-07 -7.9571 0.56487E+00 -0.2480 87 H2P2O7-2 0.52379E-15 -15.2808 0.40119E-15 -15.3966 0.76595E+00 -0.1158 88 HP2O7-3 0.25820E-12 -12.5880 0.14474E-12 -12.8394 0.56055E+00 -0.2514 89 P2O7-4 0.17266E-12 -12.7628 0.62820E-13 -13.2019 0.36384E+00 -0.4391 90 H2S,aq 0.51735E-16 -16.2862 0.51710E-16 -16.2864 0.99953E+00 -0.0002 97 SO3-2 0.16791E-14 -14.7749 0.12891E-14 -14.8897 0.76771E+00 -0.1148 98 HSO3- 0.46473E-16 -16.3328 0.42879E-16 -16.3678 0.92266E+00 -0.0350 99 HSO4- 0.11162E-10 -10.9523 0.10303E-10 -10.9870 0.92308E+00 -0.0348 Charge balance for all species = 0.4562E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.6154430E-09 -.2267430E-02 -.2284962E+01 0.0000 2 H2O 0.1000000E+01 0.5550851E+02 0.9997963E+06 0.0000 3 Cl- 0.1379327E-03 0.1380205E-03 0.4892233E+01 5.3501 4 SO4-- 0.2549779E-04 0.2551333E-04 0.2450346E+01 13.7816 5 HCO3- 0.1092192E-04 0.1307439E-04 0.7975983E+00 4.2488 6 HS- 0.3281720E-13 -.2918838E-09 -.9651190E-05 -4.2735 7 Al+++ 0.1177200E-24 0.3954412E-04 0.1066740E+01 2.5555 8 H4SiO4 0.5012417E-03 0.1462631E-02 0.1405523E+03 -3.3000 9 Ca++ 0.1615329E-07 0.1840288E-07 0.7373984E-03 10.5828 10 Mg++ 0.1610866E-09 0.2567070E-09 0.6239774E-05 8.5813 11 Fe++ 0.9526528E-12 0.5269237E-08 0.2942104E-03 6.3533 12 K+ 0.5035636E-04 0.5040727E-04 0.1970619E+01 4.9126 13 Na+ 0.2288832E-02 0.2319410E-02 0.5331178E+02 6.5700 14 Mn++ 0.1272824E-09 0.1022324E-08 0.5615287E-04 8.4791 15 HPO4-- 0.9376924E-05 0.9474055E-05 0.9091228E+00 13.3471 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2977573E-01 -.2266669E-02 -.2750906E-01 0.0000000E+00 2 H2O 0.5548570E+02 0.5548987E+02 -.4168872E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7536089E-04 0.2550476E-04 0.4985613E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4985642E-04 -.2917857E-09 -.4985613E-04 0.0000000E+00 7 Al+++ 0.5866074E-02 0.3953084E-04 0.5826543E-02 0.0000000E+00 8 H4SiO4 0.1873260E-01 0.1462139E-02 0.1727046E-01 0.0000000E+00 9 Ca++ 0.2083578E-02 0.1839669E-07 0.2083559E-02 0.0000000E+00 10 Mg++ 0.1427778E-02 0.2566208E-09 0.1427778E-02 0.0000000E+00 11 Fe++ 0.1282702E-02 0.5267467E-08 0.1282697E-02 0.0000000E+00 12 K+ 0.3819533E-03 0.5039034E-04 0.3315630E-03 0.0000000E+00 13 Na+ 0.2418254E-02 0.2318631E-02 0.9962325E-04 0.0000000E+00 14 Mn++ 0.3119213E-04 0.1021981E-08 0.3119111E-04 0.0000000E+00 15 HPO4-- 0.1064572E-04 0.9470872E-05 0.1174848E-05 0.0000000E+00 Chg. balance for solid moles: -.3148E-17 Mass of aqueous solution: 0.999870E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) clinochlore 0.2856E-03 -3.544 0.1587 -0.799 8.248 0.6037E-01 daphnite 0.1768E-03 -3.753 0.1261 -0.899 6.554 0.3822E-01 chlorite-Mn 0.6238E-05 -5.205 0.4423E-02 -2.354 0.2298 0.1409E-02 hematite 0.1994E-03 -3.700 0.3185E-01 -1.497 1.655 0.6036E-02 microcline 0.2837E-03 -3.547 0.7896E-01 -1.103 4.103 0.3084E-01 muscovite 0.4789E-04 -4.320 0.1908E-01 -1.720 0.9913 0.6745E-02 paragonite 0.9962E-04 -4.002 0.3808E-01 -1.419 1.979 0.1316E-01 stilbite 0.2082E-02 -2.682 1.467 0.166 76.23 0.6842 apatite-OH 0.3916E-06 -6.407 0.1967E-03 -3.706 0.1022E-01 0.6251E-04 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1.924369 g Volume = 0.841061 cm3 Porosity: 51.0897% V(tot) - V(min): 0.87854E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.7990000 g log = 0.2550 Original solution: 1000.0103000 g Original solution / Rock added: 555.87 (Water/Rock Ratio), log = 2.7450 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1248E-05 1.0073 0.1322E-05 0.1313E-05 CH4,gas 0.2275E-16 1.0129 0.2424E-16 0.2393E-16 H2,gas 0.6306E-06 1.0006 0.6637E-06 0.6634E-06 H2S,gas 0.1440E-14 0.9959 0.1508E-14 0.1514E-14 S2,gas 0.1838E-36 1.0000 0.1934E-36 0.1934E-36 CO,gas 0.2161E-15 1.0000 0.2273E-15 0.2273E-15 SO3,gas 0.2243E-38 1.0000 0.2360E-38 0.2360E-38 SO2,gas 0.5632E-22 1.0000 0.5925E-22 0.5925E-22 HCl,gas 0.2284E-16 1.0000 0.2402E-16 0.2402E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 120 muscovite 2.68 2.68 0.00 0.000 -0.18198E-10 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.24 -7.88 -2.626 0.13453E+05 -5.879 3 CH4,gas 4.81 -13.81 -18.62 -4.654 0.31785E+05 -16.615 4 H2,gas 8.29 0.11 -8.18 -4.673 0.13964E+05 -6.178 5 H2S,gas -5.94 -22.76 -16.82 -8.411 0.28722E+05 -14.822 6 S2,gas -7.03 -45.75 -38.71 -5.956 0.66102E+05 -36.714 7 CO,gas 3.51 -14.13 -17.64 -5.429 0.30126E+05 -15.643 8 SO3,gas 17.43 -23.20 -40.63 -10.157 0.69370E+05 -38.627 9 SO2,gas 1.14 -23.09 -24.23 -6.461 0.41368E+05 -22.227 10 HCl,gas 5.48 -13.14 -18.62 -9.310 0.31792E+05 -16.619 11 acmite 7.74 6.27 -1.47 -0.153 0.25074E+04 15 albite-high 0.75 -0.77 -1.52 -0.117 0.26022E+04 16 albite -0.33 -0.77 -0.45 -0.034 0.76153E+03 19 spessartine 24.55 20.65 -3.90 -0.195 0.66614E+04 20 analcite 3.37 2.53 -0.85 -0.094 0.14429E+04 21 andalusite 5.06 1.81 -3.25 -0.325 0.55516E+04 22 andradite 39.09 34.45 -4.64 -0.241 0.79253E+04 26 annite 20.21 16.63 -3.58 -0.199 0.61150E+04 27 phlogopite 27.15 23.31 -3.83 -0.213 0.65472E+04 29 anorthite 12.80 9.09 -3.70 -0.285 0.63241E+04 35 aragonite 0.99 -3.66 -4.65 -1.548 0.79317E+04 36 brucite 12.58 8.58 -4.00 -0.799 0.68218E+04 37 calcite 0.83 -3.66 -4.49 -1.497 0.76704E+04 38 carnegieite-low 9.06 5.83 -3.24 -0.463 0.55305E+04 39 carnegieite-high 10.13 5.83 -4.31 -0.616 0.73574E+04 40 carpholite-Mg 8.65 7.09 -1.56 -0.104 0.26602E+04 41 carpholite-Fe 6.78 4.86 -1.92 -0.128 0.32759E+04 42 celadonite 5.40 2.85 -2.55 -0.150 0.43557E+04 43 celadonite-Fe 3.94 0.62 -3.32 -0.195 0.56610E+04 44 chrysotile 23.94 19.14 -4.79 -0.399 0.81845E+04 50 chloritoid-Mg 13.26 10.39 -2.87 -0.191 0.48986E+04 51 chloritoid-Fe 9.24 8.16 -1.07 -0.072 0.18345E+04 52 chloritoid-Mn 11.46 10.29 -1.17 -0.078 0.20029E+04 54 coesite -2.37 -3.30 -0.93 -0.310 0.15890E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.30 -0.75 -0.250 0.12819E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.56 -3.65 -0.365 0.62344E+04 68 hedenbergite 14.24 10.34 -3.91 -0.391 0.66732E+04 75 epidote 24.78 22.68 -2.10 -0.102 0.35850E+04 76 clinozoisite 22.92 18.93 -3.99 -0.181 0.68109E+04 77 epidote-Fe 29.94 26.42 -3.52 -0.183 0.60067E+04 78 fayalite 14.08 9.41 -4.67 -0.667 0.79780E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.73 -0.311 0.63763E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.53 -1.73 -0.173 0.29459E+04 97 kalsilite 7.62 4.17 -3.45 -0.493 0.58944E+04 98 kaolinite -1.27 -1.49 -0.22 -0.020 0.36843E+03 99 kyanite 4.93 1.81 -3.12 -0.312 0.53283E+04 101 laumontite 2.97 2.49 -0.48 -0.032 0.82051E+03 102 lawsonite 9.68 9.09 -0.58 -0.039 0.99796E+03 103 leucite 4.17 0.87 -3.30 -0.330 0.56338E+04 105 lizardite 23.29 19.14 -4.14 -0.345 0.70747E+04 107 magnetite 20.13 18.95 -1.18 -0.096 0.20181E+04 108 minnesotaite 10.46 5.86 -4.60 -0.271 0.78557E+04 113 margarite 17.45 14.20 -3.25 -0.130 0.55440E+04 122 nepheline 8.38 5.83 -2.55 -0.365 0.43585E+04 134 phlogopite-Na 29.73 24.97 -4.76 -0.265 0.81307E+04 136 prehnite 19.47 16.38 -3.09 -0.182 0.52753E+04 137 prehnite-Fe 22.59 20.12 -2.47 -0.148 0.42118E+04 138 pumpellyite-Fe 46.47 41.66 -4.81 -0.107 0.82099E+04 145 pyroxmangite 7.42 5.18 -2.24 -0.447 0.38193E+04 146 pyrophyllite -6.10 -8.09 -1.99 -0.124 0.33992E+04 147 quartz -2.98 -3.30 -0.32 -0.106 0.54290E+03 151 rhodochrosite -0.96 -5.76 -4.80 -1.601 0.82031E+04 152 rhodonite 7.46 5.18 -2.28 -0.457 0.38986E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.81 -3.51 -0.351 0.59938E+04 164 stilpnomelane-Fe 13.18 12.93 -0.25 -0.007 0.41901E+03 165 stilpnomelane-Mg 27.60 24.07 -3.52 -0.105 0.60138E+04 168 sudoite 21.22 17.48 -3.73 -0.120 0.63713E+04 171 talc 16.55 12.54 -4.01 -0.236 0.68457E+04 174 tephroite 18.11 13.66 -4.45 -0.636 0.76060E+04 177 topaz-H 4.67 1.81 -2.86 -0.260 0.48774E+04 178 tridymite -2.61 -3.30 -0.69 -0.228 0.11702E+04 187 wairakite 4.06 2.49 -1.56 -0.092 0.26713E+04 188 walstromite 11.53 7.28 -4.24 -0.849 0.72482E+04 189 wollastonite 10.48 7.28 -3.20 -0.640 0.54621E+04 190 pseudo-wollastonite 11.02 7.28 -3.74 -0.747 0.63807E+04 191 zoisite 22.96 18.93 -4.03 -0.183 0.68834E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.41 -2.85 -0.176 0.48675E+04 194 beidellite-H -2.24 -6.16 -3.92 -0.250 0.66855E+04 195 beidellite-K -1.44 -4.54 -3.10 -0.190 0.52938E+04 196 beidellite-Mg -1.71 -4.74 -3.03 -0.188 0.51800E+04 197 beidellite-Na -1.26 -3.99 -2.73 -0.167 0.46638E+04 199 chalcedony -2.79 -3.30 -0.51 -0.169 0.86321E+03 201 montmorillonite-Ca -2.21 -4.35 -2.14 -0.132 0.36542E+04 202 montmorillonite-K -2.16 -4.48 -2.32 -0.142 0.39582E+04 203 montmorillonite-Mg -2.40 -4.68 -2.28 -0.141 0.38978E+04 204 montmorillonite-Na -1.96 -3.93 -1.97 -0.121 0.33664E+04 205 nontronite-Ca 3.28 3.08 -0.20 -0.013 0.34727E+03 206 nontronite-H 2.60 1.33 -1.27 -0.085 0.21610E+04 207 nontronite-K 3.40 2.95 -0.45 -0.029 0.77274E+03 208 nontronite-Mg 3.14 2.75 -0.39 -0.026 0.67143E+03 209 nontronite-Na 3.58 3.50 -0.08 -0.005 0.14447E+03 224 tobermorite 9.84 5.52 -4.32 -1.180 0.73822E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.35 -3.47 -0.868 0.59266E+04 240 silica-amorphous -2.08 -3.30 -1.22 -0.407 0.20834E+04 242 an20ab80 2.08 1.20 -0.88 -0.068 0.15024E+04 243 an25ab75 2.71 1.69 -1.02 -0.078 0.17356E+04 244 an30ab70 3.34 2.19 -1.16 -0.089 0.19770E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 1.7990000 g New total amount of reactant added: 1.8990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4568E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.8990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9996E+00 Moles total = 0.5548E+02 kg total = 0.9996E+00 Activity = 1.0000 Stoichiometric ionic strength = .1558299E-02 Osmotic coef. = 0.9776 True ionic strength = .2460301E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.58406E-09 -9.2335 0.53887E-09 -9.2685 0.92262E+00 -0.0350 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12713E-03 -3.8957 0.92171E+00 -0.0354 4 SO4-- 0.25498E-04 -4.5935 0.19458E-04 -4.7109 0.76312E+00 -0.1174 5 HCO3- 0.10820E-04 -4.9658 0.99752E-05 -5.0011 0.92193E+00 -0.0353 6 HS- 0.35729E-13 -13.4470 0.32932E-13 -13.4824 0.92174E+00 -0.0354 7 Al+++ 0.10124E-24 -24.9947 0.56226E-25 -25.2501 0.55539E+00 -0.2554 8 H4SiO4 0.48670E-03 -3.3127 0.48670E-03 -3.3127 0.10000E+01 0.0000 9 Ca++ 0.17916E-07 -7.7468 0.13656E-07 -7.8647 0.76222E+00 -0.1179 10 Mg++ 0.14797E-09 -9.8298 0.11271E-09 -9.9481 0.76165E+00 -0.1182 11 Fe++ 0.87510E-12 -12.0579 0.66664E-12 -12.1761 0.76179E+00 -0.1182 12 K+ 0.52204E-04 -4.2823 0.48130E-04 -4.3176 0.92197E+00 -0.0353 13 Na+ 0.23728E-02 -2.6247 0.21870E-02 -2.6601 0.92169E+00 -0.0354 14 Mn++ 0.11692E-09 -9.9321 0.89081E-10 -10.0502 0.76189E+00 -0.1181 15 HPO4-- 0.74290E-05 -5.1291 0.56693E-05 -5.2465 0.76314E+00 -0.1174 16 HSiO3- 0.95605E-03 -3.0195 0.88121E-03 -3.0549 0.92171E+00 -0.0354 17 Ca(HSiO3)+ 0.29242E-09 -9.5340 0.26961E-09 -9.5693 0.92200E+00 -0.0353 18 Mg(HSiO3)+ 0.30036E-11 -11.5224 0.27693E-11 -11.5576 0.92200E+00 -0.0353 19 NaHSiO3,aq 0.30609E-04 -4.5142 0.30609E-04 -4.5142 0.10000E+01 0.0000 20 AlO+ 0.27112E-13 -13.5668 0.24997E-13 -13.6021 0.92200E+00 -0.0353 21 AlOH+2 0.88550E-19 -19.0528 0.67476E-19 -19.1708 0.76201E+00 -0.1180 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.41744E-04 -4.3794 0.38465E-04 -4.4149 0.92144E+00 -0.0355 24 CH4,aq 0.16575E-19 -19.7806 0.16567E-19 -19.7808 0.99952E+00 -0.0002 29 CO,aq 0.13994E-18 -18.8541 0.13994E-18 -18.8541 0.10000E+01 0.0000 30 CO2,aq 0.10843E-07 -7.9649 0.10838E-07 -7.9651 0.99952E+00 -0.0002 31 CO3-2 0.22436E-05 -5.6491 0.17116E-05 -5.7666 0.76285E+00 -0.1176 32 CaCO3,aq 0.28626E-09 -9.5432 0.28626E-09 -9.5432 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.37226E-11 -11.4292 0.34323E-11 -11.4644 0.92200E+00 -0.0353 34 CaCl+ 0.30005E-11 -11.5228 0.27664E-11 -11.5581 0.92200E+00 -0.0353 35 CaCl2,aq 0.81891E-16 -16.0868 0.81891E-16 -16.0868 0.10000E+01 0.0000 36 CaOH+ 0.19381E-08 -8.7126 0.17869E-08 -8.7479 0.92200E+00 -0.0353 37 CaSO4,aq 0.82789E-10 -10.0820 0.82789E-10 -10.0820 0.10000E+01 0.0000 38 HCl,aq 0.12886E-13 -13.8899 0.12886E-13 -13.8899 0.10000E+01 0.0000 43 FeCl+ 0.14317E-15 -15.8441 0.13200E-15 -15.8794 0.92200E+00 -0.0353 46 FeO,aq 0.90785E-10 -10.0420 0.90785E-10 -10.0420 0.10000E+01 0.0000 47 FeOH+ 0.44483E-10 -10.3518 0.41014E-10 -10.3871 0.92200E+00 -0.0353 48 HFeO2- 0.19660E-08 -8.7064 0.18121E-08 -8.7418 0.92171E+00 -0.0354 49 FeO+ 0.48347E-14 -14.3156 0.44576E-14 -14.3509 0.92200E+00 -0.0353 51 FeO2- 0.32734E-08 -8.4850 0.30171E-08 -8.5204 0.92171E+00 -0.0354 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.50158E-09 -9.2997 0.50133E-09 -9.2999 0.99952E+00 -0.0002 54 KCl,aq 0.10835E-09 -9.9652 0.10835E-09 -9.9652 0.10000E+01 0.0000 55 KHSO4,aq 0.13504E-17 -17.8695 0.13504E-17 -17.8695 0.10000E+01 0.0000 56 KOH,aq 0.38938E-07 -7.4096 0.38938E-07 -7.4096 0.10000E+01 0.0000 57 KSO4- 0.15654E-07 -7.8054 0.14428E-07 -7.8408 0.92171E+00 -0.0354 58 MgCO3,aq 0.59036E-12 -12.2289 0.59036E-12 -12.2289 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.31330E-13 -13.5040 0.28887E-13 -13.5393 0.92200E+00 -0.0353 60 MgCl+ 0.22481E-13 -13.6482 0.20728E-13 -13.6834 0.92200E+00 -0.0353 61 MgOH+ 0.88616E-10 -10.0525 0.81704E-10 -10.0878 0.92200E+00 -0.0353 63 MnO,aq 0.32385E-09 -9.4897 0.32385E-09 -9.4897 0.10000E+01 0.0000 64 MnOH+ 0.55219E-09 -9.2579 0.50912E-09 -9.2932 0.92200E+00 -0.0353 65 MnO2-2 0.50560E-13 -13.2962 0.38570E-13 -13.4138 0.76285E+00 -0.1176 66 HMnO2- 0.48856E-11 -11.3111 0.45031E-11 -11.3465 0.92171E+00 -0.0354 69 MnCl+ 0.74341E-13 -13.1288 0.68543E-13 -13.1640 0.92200E+00 -0.0353 70 MnSO4,aq 0.49123E-12 -12.3087 0.49123E-12 -12.3087 0.10000E+01 0.0000 71 NaCl,aq 0.90788E-07 -7.0420 0.90788E-07 -7.0420 0.10000E+01 0.0000 72 NaOH,aq 0.17834E-05 -5.7488 0.17834E-05 -5.7488 0.10000E+01 0.0000 74 OH- 0.12080E-02 -2.9179 0.11131E-02 -2.9534 0.92144E+00 -0.0355 79 HPO3-2 0.11768E-16 -16.9293 0.89773E-17 -17.0469 0.76285E+00 -0.1176 81 H2PO3- 0.10310E-19 -19.9868 0.95026E-20 -20.0222 0.92171E+00 -0.0354 82 H3PO4,aq 0.10598E-13 -13.9748 0.10598E-13 -13.9748 0.10000E+01 0.0000 83 H2PO4- 0.58101E-07 -7.2358 0.53561E-07 -7.2712 0.92186E+00 -0.0353 84 PO4-3 0.16411E-07 -7.7849 0.91880E-08 -8.0368 0.55987E+00 -0.2519 87 H2P2O7-2 0.29432E-15 -15.5312 0.22452E-15 -15.6487 0.76285E+00 -0.1176 88 HP2O7-3 0.15382E-12 -12.8130 0.85437E-13 -13.0684 0.55545E+00 -0.2554 89 P2O7-4 0.10925E-12 -12.9616 0.39114E-13 -13.4077 0.35802E+00 -0.4461 90 H2S,aq 0.53345E-16 -16.2729 0.53320E-16 -16.2731 0.99952E+00 -0.0002 97 SO3-2 0.17394E-14 -14.7596 0.13301E-14 -14.8761 0.76466E+00 -0.1165 98 HSO3- 0.45507E-16 -16.3419 0.41944E-16 -16.3773 0.92171E+00 -0.0354 99 HSO4- 0.10550E-10 -10.9767 0.97288E-11 -11.0119 0.92214E+00 -0.0352 Charge balance for all species = 0.4516E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5840586E-09 -.2365744E-02 -.2384028E+01 0.0000 2 H2O 0.1000000E+01 0.5550856E+02 0.9997935E+06 0.0000 3 Cl- 0.1379319E-03 0.1380228E-03 0.4892294E+01 5.3728 4 SO4-- 0.2549770E-04 0.2551376E-04 0.2450378E+01 13.8261 5 HCO3- 0.1081985E-04 0.1307460E-04 0.7976082E+00 4.2674 6 HS- 0.3572875E-13 -.3091742E-09 -.1022287E-04 -4.2139 7 Al+++ 0.1012360E-24 0.4175315E-04 0.1126326E+01 2.5555 8 H4SiO4 0.4866959E-03 0.1473359E-02 0.1415828E+03 -3.3127 9 Ca++ 0.1791556E-07 0.2052180E-07 0.8223001E-03 10.6723 10 Mg++ 0.1479742E-09 0.2402382E-09 0.5839446E-05 8.5890 11 Fe++ 0.8751025E-12 0.5579007E-08 0.3115054E-03 6.3609 12 K+ 0.5220368E-04 0.5225838E-04 0.2042978E+01 4.9509 13 Na+ 0.2372820E-02 0.2405303E-02 0.5528583E+02 6.6084 14 Mn++ 0.1169208E-09 0.9984586E-09 0.5484181E-04 8.4868 15 HPO4-- 0.7428979E-05 0.7503491E-05 0.7200265E+00 13.2906 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3143158E-01 -.2364911E-02 -.2906667E-01 0.0000000E+00 2 H2O 0.5548445E+02 0.5548902E+02 -.4575705E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7813223E-04 0.2550478E-04 0.5262745E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5262776E-04 -.3090654E-09 -.5262745E-04 0.0000000E+00 7 Al+++ 0.6192148E-02 0.4173846E-04 0.6150410E-02 0.0000000E+00 8 H4SiO4 0.1977387E-01 0.1472840E-02 0.1830103E-01 0.0000000E+00 9 Ca++ 0.2198592E-02 0.2051458E-07 0.2198571E-02 0.0000000E+00 10 Mg++ 0.1507143E-02 0.2401537E-09 0.1507143E-02 0.0000000E+00 11 Fe++ 0.1354003E-02 0.5577044E-08 0.1353998E-02 0.0000000E+00 12 K+ 0.4031847E-03 0.5223999E-04 0.3509447E-03 0.0000000E+00 13 Na+ 0.2543779E-02 0.2404456E-02 0.1393223E-03 0.0000000E+00 14 Mn++ 0.3292599E-04 0.9981072E-09 0.3292500E-04 0.0000000E+00 15 HPO4-- 0.1123748E-04 0.7500850E-05 0.3736628E-05 0.0000000E+00 Chg. balance for solid moles: -.3558E-18 Mass of aqueous solution: 0.999858E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.8990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1246E-05 -5.905 0.6257E-03 -3.204 0.3073E-01 0.1988E-03 clinochlore 0.3014E-03 -3.521 0.1675 -0.776 8.229 0.6373E-01 daphnite 0.1866E-03 -3.729 0.1331 -0.876 6.539 0.4034E-01 chlorite-Mn 0.6585E-05 -5.181 0.4669E-02 -2.331 0.2293 0.1488E-02 hematite 0.2105E-03 -3.677 0.3362E-01 -1.473 1.651 0.6372E-02 microcline 0.3471E-03 -3.459 0.9663E-01 -1.015 4.746 0.3774E-01 muscovite 0.3796E-05 -5.421 0.1512E-02 -2.820 0.7427E-01 0.5347E-03 paragonite 0.1393E-03 -3.856 0.5325E-01 -1.274 2.615 0.1841E-01 stilbite 0.2192E-02 -2.659 1.545 0.189 75.88 0.7206 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.035968 g Volume = 0.889428 cm3 Porosity: 49.4529% V(tot) - V(min): 0.87017E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.8990000 g log = 0.2785 Original solution: 1000.0103000 g Original solution / Rock added: 526.60 (Water/Rock Ratio), log = 2.7215 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1171E-05 1.0073 0.1241E-05 0.1232E-05 CH4,gas 0.2459E-16 1.0129 0.2620E-16 0.2586E-16 H2,gas 0.6533E-06 1.0006 0.6876E-06 0.6872E-06 H2S,gas 0.1484E-14 0.9959 0.1555E-14 0.1561E-14 S2,gas 0.1821E-36 1.0000 0.1916E-36 0.1916E-36 CO,gas 0.2101E-15 1.0000 0.2210E-15 0.2210E-15 SO3,gas 0.2008E-38 1.0000 0.2112E-38 0.2112E-38 SO2,gas 0.5223E-22 1.0000 0.5495E-22 0.5495E-22 HCl,gas 0.2163E-16 1.0000 0.2275E-16 0.2275E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.27 -7.91 -2.635 0.13500E+05 -5.906 3 CH4,gas 4.81 -13.77 -18.58 -4.645 0.31728E+05 -16.582 4 H2,gas 8.29 0.12 -8.16 -4.664 0.13938E+05 -6.163 5 H2S,gas -5.94 -22.75 -16.81 -8.404 0.28700E+05 -14.808 6 S2,gas -7.03 -45.75 -38.72 -5.957 0.66109E+05 -36.718 7 CO,gas 3.51 -14.15 -17.66 -5.433 0.30147E+05 -15.656 8 SO3,gas 17.43 -23.25 -40.68 -10.169 0.69452E+05 -38.675 9 SO2,gas 1.14 -23.12 -24.26 -6.469 0.41423E+05 -22.260 10 HCl,gas 5.48 -13.16 -18.64 -9.321 0.31832E+05 -16.643 11 acmite 7.74 6.28 -1.46 -0.151 0.24856E+04 15 albite-high 0.75 -0.77 -1.52 -0.117 0.26022E+04 16 albite -0.33 -0.77 -0.45 -0.034 0.76153E+03 19 spessartine 24.55 20.63 -3.92 -0.196 0.66876E+04 20 analcite 3.37 2.54 -0.83 -0.092 0.14211E+04 21 andalusite 5.06 1.80 -3.26 -0.326 0.55734E+04 22 andradite 39.09 34.68 -4.41 -0.229 0.75322E+04 26 annite 20.21 16.65 -3.56 -0.198 0.60757E+04 27 phlogopite 27.15 23.34 -3.81 -0.212 0.65079E+04 29 anorthite 12.80 9.16 -3.64 -0.280 0.62149E+04 35 aragonite 0.99 -3.60 -4.58 -1.528 0.78262E+04 36 brucite 12.58 8.59 -3.99 -0.798 0.68087E+04 37 calcite 0.83 -3.60 -4.43 -1.477 0.75648E+04 38 carnegieite-low 9.06 5.85 -3.21 -0.459 0.54868E+04 39 carnegieite-high 10.13 5.85 -4.28 -0.612 0.73137E+04 40 carpholite-Mg 8.65 7.07 -1.58 -0.105 0.26908E+04 41 carpholite-Fe 6.78 4.85 -1.94 -0.129 0.33064E+04 42 celadonite 5.40 2.84 -2.56 -0.150 0.43644E+04 43 celadonite-Fe 3.94 0.62 -3.32 -0.195 0.56697E+04 44 chrysotile 23.94 19.14 -4.80 -0.400 0.81888E+04 50 chloritoid-Mg 13.26 10.39 -2.87 -0.192 0.49073E+04 51 chloritoid-Fe 9.24 8.16 -1.08 -0.072 0.18432E+04 52 chloritoid-Mn 11.46 10.29 -1.18 -0.079 0.20116E+04 54 coesite -2.37 -3.31 -0.94 -0.314 0.16108E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.31 -0.76 -0.255 0.13037E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.64 -3.58 -0.358 0.61121E+04 68 hedenbergite 14.24 10.41 -3.84 -0.384 0.65509E+04 75 epidote 24.78 22.82 -1.96 -0.095 0.33448E+04 76 clinozoisite 22.92 19.07 -3.85 -0.175 0.65707E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.175 0.57665E+04 78 fayalite 14.08 9.41 -4.67 -0.667 0.79736E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.46 -3.74 -0.311 0.63806E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.54 -1.71 -0.171 0.29241E+04 97 kalsilite 7.62 4.19 -3.43 -0.490 0.58508E+04 98 kaolinite -1.27 -1.51 -0.24 -0.022 0.41210E+03 99 kyanite 4.93 1.80 -3.13 -0.313 0.53502E+04 101 laumontite 2.97 2.53 -0.44 -0.029 0.75500E+03 102 lawsonite 9.68 9.16 -0.52 -0.035 0.88877E+03 103 leucite 4.17 0.88 -3.29 -0.329 0.56119E+04 105 lizardite 23.29 19.14 -4.15 -0.345 0.70791E+04 107 magnetite 20.13 18.96 -1.17 -0.096 0.20050E+04 108 minnesotaite 10.46 5.83 -4.63 -0.272 0.79037E+04 113 margarite 17.45 14.27 -3.18 -0.127 0.54348E+04 122 nepheline 8.38 5.85 -2.53 -0.361 0.43148E+04 134 phlogopite-Na 29.73 24.99 -4.74 -0.263 0.80914E+04 136 prehnite 19.47 16.52 -2.95 -0.173 0.50351E+04 137 prehnite-Fe 22.59 20.26 -2.33 -0.140 0.39716E+04 138 pumpellyite-Fe 46.47 41.95 -4.52 -0.100 0.77164E+04 145 pyroxmangite 7.42 5.17 -2.24 -0.448 0.38281E+04 146 pyrophyllite -6.10 -8.14 -2.04 -0.128 0.34866E+04 147 quartz -2.98 -3.31 -0.33 -0.110 0.56474E+03 151 rhodochrosite -0.96 -5.78 -4.82 -1.608 0.82373E+04 152 rhodonite 7.46 5.17 -2.29 -0.458 0.39073E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.80 -3.52 -0.352 0.60156E+04 164 stilpnomelane-Fe 13.18 12.89 -0.29 -0.009 0.49545E+03 165 stilpnomelane-Mg 27.60 24.03 -3.57 -0.106 0.60903E+04 168 sudoite 21.22 17.46 -3.75 -0.121 0.64106E+04 171 talc 16.55 12.52 -4.04 -0.237 0.68937E+04 174 tephroite 18.11 13.66 -4.45 -0.636 0.76017E+04 177 topaz-H 4.67 1.80 -2.87 -0.261 0.48993E+04 178 tridymite -2.61 -3.31 -0.70 -0.233 0.11920E+04 187 wairakite 4.06 2.53 -1.53 -0.090 0.26058E+04 188 walstromite 11.53 7.36 -4.17 -0.834 0.71172E+04 189 wollastonite 10.48 7.36 -3.12 -0.624 0.53311E+04 190 pseudo-wollastonite 11.02 7.36 -3.66 -0.732 0.62497E+04 191 zoisite 22.96 19.07 -3.89 -0.177 0.66432E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.44 -2.88 -0.178 0.49224E+04 194 beidellite-H -2.24 -6.20 -3.96 -0.253 0.67656E+04 195 beidellite-K -1.44 -4.57 -3.13 -0.192 0.53523E+04 196 beidellite-Mg -1.71 -4.79 -3.08 -0.190 0.52580E+04 197 beidellite-Na -1.26 -4.02 -2.77 -0.169 0.47223E+04 199 chalcedony -2.79 -3.31 -0.52 -0.173 0.88505E+03 201 montmorillonite-Ca -2.21 -4.39 -2.17 -0.134 0.37120E+04 202 montmorillonite-K -2.16 -4.52 -2.35 -0.144 0.40196E+04 203 montmorillonite-Mg -2.40 -4.73 -2.33 -0.144 0.39786E+04 204 montmorillonite-Na -1.96 -3.97 -2.01 -0.123 0.34278E+04 205 nontronite-Ca 3.28 3.04 -0.24 -0.015 0.40219E+03 206 nontronite-H 2.60 1.28 -1.31 -0.088 0.22412E+04 207 nontronite-K 3.40 2.92 -0.49 -0.031 0.83127E+03 208 nontronite-Mg 3.14 2.70 -0.44 -0.028 0.74941E+03 209 nontronite-Na 3.58 3.46 -0.12 -0.008 0.20300E+03 224 tobermorite 9.84 5.58 -4.26 -1.163 0.72767E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.36 -3.46 -0.866 0.59135E+04 240 silica-amorphous -2.08 -3.31 -1.23 -0.411 0.21052E+04 242 an20ab80 2.08 1.21 -0.87 -0.067 0.14806E+04 243 an25ab75 2.71 1.71 -1.00 -0.077 0.17083E+04 244 an30ab70 3.34 2.21 -1.14 -0.088 0.19443E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 1.8990000 g New total amount of reactant added: 1.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4569E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.9990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9996E+00 Moles total = 0.5548E+02 kg total = 0.9995E+00 Activity = 1.0000 Stoichiometric ionic strength = .1610199E-02 Osmotic coef. = 0.9772 True ionic strength = .2546537E-02 Chg. balance for total moles = 0.4569E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.55528E-09 -9.2555 0.51180E-09 -9.2909 0.92170E+00 -0.0354 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12700E-03 -3.8962 0.92076E+00 -0.0359 4 SO4-- 0.25498E-04 -4.5935 0.19379E-04 -4.7127 0.76003E+00 -0.1192 5 HCO3- 0.10717E-04 -4.9699 0.98705E-05 -5.0057 0.92099E+00 -0.0357 6 HS- 0.38822E-13 -13.4109 0.35747E-13 -13.4468 0.92079E+00 -0.0358 7 Al+++ 0.87538E-25 -25.0578 0.48172E-25 -25.3172 0.55030E+00 -0.2594 8 H4SiO4 0.47294E-03 -3.3252 0.47294E-03 -3.3252 0.10000E+01 0.0000 9 Ca++ 0.19834E-07 -7.7026 0.15056E-07 -7.8223 0.75910E+00 -0.1197 10 Mg++ 0.13636E-09 -9.8653 0.10343E-09 -9.9853 0.75852E+00 -0.1200 11 Fe++ 0.80641E-12 -12.0934 0.61179E-12 -12.2134 0.75866E+00 -0.1200 12 K+ 0.54090E-04 -4.2669 0.49818E-04 -4.3026 0.92103E+00 -0.0357 13 Na+ 0.24586E-02 -2.6093 0.22637E-02 -2.6452 0.92074E+00 -0.0359 14 Mn++ 0.10774E-09 -9.9676 0.81751E-10 -10.0875 0.75876E+00 -0.1199 15 HPO4-- 0.59184E-05 -5.2278 0.44982E-05 -5.3470 0.76004E+00 -0.1192 16 HSiO3- 0.97918E-03 -3.0091 0.90159E-03 -3.0450 0.92076E+00 -0.0359 17 Ca(HSiO3)+ 0.33020E-09 -9.4812 0.30413E-09 -9.5169 0.92106E+00 -0.0357 18 Mg(HSiO3)+ 0.28231E-11 -11.5493 0.26002E-11 -11.5850 0.92106E+00 -0.0357 19 NaHSiO3,aq 0.32415E-04 -4.4893 0.32415E-04 -4.4893 0.10000E+01 0.0000 20 AlO+ 0.25776E-13 -13.5888 0.23741E-13 -13.6245 0.92106E+00 -0.0357 21 AlOH+2 0.80207E-19 -19.0958 0.60868E-19 -19.2156 0.75889E+00 -0.1198 22 HAlO2,aq 0.92827E-08 -8.0323 0.92827E-08 -8.0323 0.10000E+01 0.0000 23 AlO2- 0.43997E-04 -4.3566 0.40499E-04 -4.3926 0.92048E+00 -0.0360 24 CH4,aq 0.17875E-19 -19.7478 0.17866E-19 -19.7480 0.99950E+00 -0.0002 29 CO,aq 0.13611E-18 -18.8661 0.13611E-18 -18.8661 0.10000E+01 0.0000 30 CO2,aq 0.10190E-07 -7.9918 0.10185E-07 -7.9920 0.99950E+00 -0.0002 31 CO3-2 0.23470E-05 -5.6295 0.17832E-05 -5.7488 0.75975E+00 -0.1193 32 CaCO3,aq 0.32881E-09 -9.4831 0.32881E-09 -9.4831 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40654E-11 -11.3909 0.37445E-11 -11.4266 0.92106E+00 -0.0357 34 CaCl+ 0.33081E-11 -11.4804 0.30469E-11 -11.5161 0.92106E+00 -0.0357 35 CaCl2,aq 0.90100E-16 -16.0453 0.90100E-16 -16.0453 0.10000E+01 0.0000 36 CaOH+ 0.22521E-08 -8.6474 0.20743E-08 -8.6831 0.92106E+00 -0.0357 37 CaSO4,aq 0.90907E-10 -10.0414 0.90907E-10 -10.0414 0.10000E+01 0.0000 38 HCl,aq 0.12226E-13 -13.9127 0.12226E-13 -13.9127 0.10000E+01 0.0000 43 FeCl+ 0.13139E-15 -15.8814 0.12102E-15 -15.9172 0.92106E+00 -0.0357 46 FeO,aq 0.92360E-10 -10.0345 0.92360E-10 -10.0345 0.10000E+01 0.0000 47 FeOH+ 0.43026E-10 -10.3663 0.39630E-10 -10.4020 0.92106E+00 -0.0357 48 HFeO2- 0.21081E-08 -8.6761 0.19411E-08 -8.7120 0.92076E+00 -0.0359 49 FeO+ 0.45965E-14 -14.3376 0.42337E-14 -14.3733 0.92106E+00 -0.0357 51 FeO2- 0.34500E-08 -8.4622 0.31767E-08 -8.4980 0.92076E+00 -0.0359 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.51914E-09 -9.2847 0.51888E-09 -9.2849 0.99950E+00 -0.0002 54 KCl,aq 0.11203E-09 -9.9507 0.11203E-09 -9.9507 0.10000E+01 0.0000 55 KHSO4,aq 0.13222E-17 -17.8787 0.13222E-17 -17.8787 0.10000E+01 0.0000 56 KOH,aq 0.42435E-07 -7.3723 0.42435E-07 -7.3723 0.10000E+01 0.0000 57 KSO4- 0.16154E-07 -7.7917 0.14874E-07 -7.8276 0.92076E+00 -0.0359 58 MgCO3,aq 0.56445E-12 -12.2484 0.56445E-12 -12.2484 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28480E-13 -13.5455 0.26232E-13 -13.5812 0.92106E+00 -0.0357 60 MgCl+ 0.20631E-13 -13.6855 0.19003E-13 -13.7212 0.92106E+00 -0.0357 61 MgOH+ 0.85713E-10 -10.0670 0.78947E-10 -10.1027 0.92106E+00 -0.0357 63 MnO,aq 0.32947E-09 -9.4822 0.32947E-09 -9.4822 0.10000E+01 0.0000 64 MnOH+ 0.53410E-09 -9.2724 0.49194E-09 -9.3081 0.92106E+00 -0.0357 65 MnO2-2 0.57254E-13 -13.2422 0.43499E-13 -13.3615 0.75975E+00 -0.1193 66 HMnO2- 0.52386E-11 -11.2808 0.48235E-11 -11.3166 0.92076E+00 -0.0359 69 MnCl+ 0.68223E-13 -13.1661 0.62838E-13 -13.2018 0.92106E+00 -0.0357 70 MnSO4,aq 0.44898E-12 -12.3478 0.44898E-12 -12.3478 0.10000E+01 0.0000 71 NaCl,aq 0.93875E-07 -7.0275 0.93875E-07 -7.0275 0.10000E+01 0.0000 72 NaOH,aq 0.19435E-05 -5.7114 0.19435E-05 -5.7114 0.10000E+01 0.0000 74 OH- 0.12733E-02 -2.8951 0.11720E-02 -2.9311 0.92048E+00 -0.0360 79 HPO3-2 0.97033E-17 -17.0131 0.73721E-17 -17.1324 0.75975E+00 -0.1193 82 H3PO4,aq 0.75856E-14 -14.1200 0.75856E-14 -14.1200 0.10000E+01 0.0000 83 H2PO4- 0.43828E-07 -7.3582 0.40362E-07 -7.3940 0.92091E+00 -0.0358 84 PO4-3 0.13833E-07 -7.8591 0.76755E-08 -8.1149 0.55488E+00 -0.2558 87 H2P2O7-2 0.16782E-15 -15.7752 0.12750E-15 -15.8945 0.75975E+00 -0.1193 88 HP2O7-3 0.92819E-13 -13.0324 0.51083E-13 -13.2917 0.55035E+00 -0.2594 89 P2O7-4 0.69901E-13 -13.1555 0.24623E-13 -13.6087 0.35226E+00 -0.4531 90 H2S,aq 0.54997E-16 -16.2597 0.54969E-16 -16.2599 0.99950E+00 -0.0002 97 SO3-2 0.18002E-14 -14.7447 0.13710E-14 -14.8630 0.76161E+00 -0.1183 98 HSO3- 0.44598E-16 -16.3507 0.41064E-16 -16.3865 0.92076E+00 -0.0359 99 HSO4- 0.99897E-11 -11.0004 0.92026E-11 -11.0361 0.92121E+00 -0.0356 Charge balance for all species = 0.4548E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5552782E-09 -.2465179E-02 -.2484222E+01 0.0000 2 H2O 0.1000000E+01 0.5550860E+02 0.9997905E+06 0.0000 3 Cl- 0.1379310E-03 0.1380250E-03 0.4892355E+01 5.3947 4 SO4-- 0.2549761E-04 0.2551419E-04 0.2450410E+01 13.8691 5 HCO3- 0.1071727E-04 0.1307481E-04 0.7976181E+00 4.2852 6 HS- 0.3882221E-13 -.3268638E-09 -.1080773E-04 -4.1559 7 Al+++ 0.8753760E-25 0.4400656E-04 0.1187109E+01 2.5555 8 H4SiO4 0.4729414E-03 0.1484533E-02 0.1426560E+03 -3.3252 9 Ca++ 0.1983368E-07 0.2284304E-07 0.9153076E-03 10.7595 10 Mg++ 0.1363601E-09 0.2255098E-09 0.5481423E-05 8.5965 11 Fe++ 0.8064130E-12 0.5897785E-08 0.3293033E-03 6.3684 12 K+ 0.5408990E-04 0.5414860E-04 0.2116866E+01 4.9883 13 Na+ 0.2458579E-02 0.2493031E-02 0.5730204E+02 6.6457 14 Mn++ 0.1077431E-09 0.9771224E-09 0.5366968E-04 8.4943 15 HPO4-- 0.5918351E-05 0.5976012E-05 0.5734492E+00 13.2348 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3308743E-01 -.2464272E-02 -.3062316E-01 0.0000000E+00 2 H2O 0.5548319E+02 0.5548817E+02 -.4976717E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8090357E-04 0.2550480E-04 0.5539878E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5539910E-04 -.3267435E-09 -.5539878E-04 0.0000000E+00 7 Al+++ 0.6518222E-02 0.4399036E-04 0.6474232E-02 0.0000000E+00 8 H4SiO4 0.2081515E-01 0.1483987E-02 0.1933117E-01 0.0000000E+00 9 Ca++ 0.2313606E-02 0.2283463E-07 0.2313583E-02 0.0000000E+00 10 Mg++ 0.1586508E-02 0.2254268E-09 0.1586508E-02 0.0000000E+00 11 Fe++ 0.1425304E-02 0.5895614E-08 0.1425298E-02 0.0000000E+00 12 K+ 0.4244161E-03 0.5412867E-04 0.3702875E-03 0.0000000E+00 13 Na+ 0.2669303E-02 0.2492113E-02 0.1771896E-03 0.0000000E+00 14 Mn++ 0.3465985E-04 0.9767627E-09 0.3465888E-04 0.0000000E+00 15 HPO4-- 0.1182924E-04 0.5973813E-05 0.5855423E-05 0.0000000E+00 Chg. balance for solid moles: -.5074E-17 Mass of aqueous solution: 0.999845E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1952E-05 -5.710 0.9804E-03 -3.009 0.4565E-01 0.3115E-03 clinochlore 0.3173E-03 -3.499 0.1764 -0.754 8.212 0.6708E-01 daphnite 0.1964E-03 -3.707 0.1401 -0.853 6.526 0.4247E-01 chlorite-Mn 0.6932E-05 -5.159 0.4914E-02 -2.309 0.2288 0.1566E-02 hematite 0.2216E-03 -3.654 0.3539E-01 -1.451 1.648 0.6707E-02 microcline 0.4086E-03 -3.389 0.1137 -0.944 5.296 0.4442E-01 muscovite -.3829E-04 1.000 -.1525E-01 1.000 -.7102 -.5393E-02 paragonite 0.1772E-03 -3.752 0.6772E-01 -1.169 3.153 0.2341E-01 stilbite 0.2304E-02 -2.638 1.624 0.210 75.60 0.7573 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 muscovite 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.147543 g Volume = 0.937832 cm3 Porosity: 47.8867% V(tot) - V(min): 0.86177E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.9990000 g log = 0.3008 Original solution: 1000.0103000 g Original solution / Rock added: 500.26 (Water/Rock Ratio), log = 2.6992 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1100E-05 1.0073 0.1166E-05 0.1157E-05 CH4,gas 0.2652E-16 1.0129 0.2825E-16 0.2789E-16 H2,gas 0.6762E-06 1.0006 0.7117E-06 0.7113E-06 H2S,gas 0.1530E-14 0.9959 0.1603E-14 0.1610E-14 S2,gas 0.1807E-36 1.0000 0.1901E-36 0.1901E-36 CO,gas 0.2043E-15 1.0000 0.2149E-15 0.2149E-15 SO3,gas 0.1804E-38 1.0000 0.1898E-38 0.1898E-38 SO2,gas 0.4857E-22 1.0000 0.5109E-22 0.5109E-22 HCl,gas 0.2052E-16 1.0000 0.2159E-16 0.2159E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 0.19715E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.30 -7.93 -2.644 0.13546E+05 -5.933 3 CH4,gas 4.81 -13.74 -18.55 -4.637 0.31672E+05 -16.549 4 H2,gas 8.29 0.14 -8.15 -4.656 0.13912E+05 -6.148 5 H2S,gas -5.94 -22.74 -16.80 -8.398 0.28677E+05 -14.795 6 S2,gas -7.03 -45.75 -38.72 -5.957 0.66115E+05 -36.721 7 CO,gas 3.51 -14.16 -17.67 -5.436 0.30167E+05 -15.668 8 SO3,gas 17.43 -23.29 -40.72 -10.180 0.69531E+05 -38.722 9 SO2,gas 1.14 -23.16 -24.29 -6.478 0.41477E+05 -22.292 10 HCl,gas 5.48 -13.19 -18.67 -9.333 0.31871E+05 -16.666 11 acmite 7.74 6.29 -1.44 -0.150 0.24643E+04 15 albite-high 0.75 -0.77 -1.52 -0.117 0.26022E+04 16 albite -0.33 -0.77 -0.45 -0.034 0.76153E+03 19 spessartine 24.55 20.62 -3.93 -0.197 0.67131E+04 20 analcite 3.37 2.55 -0.82 -0.091 0.13998E+04 21 andalusite 5.06 1.79 -3.28 -0.328 0.55947E+04 22 andradite 39.09 34.90 -4.19 -0.218 0.71495E+04 26 annite 20.21 16.67 -3.54 -0.196 0.60375E+04 27 phlogopite 27.15 23.36 -3.79 -0.211 0.64697E+04 29 anorthite 12.80 9.22 -3.58 -0.275 0.61086E+04 35 aragonite 0.99 -3.54 -4.52 -1.508 0.77234E+04 36 brucite 12.58 8.60 -3.98 -0.796 0.67960E+04 37 calcite 0.83 -3.54 -4.37 -1.457 0.74620E+04 38 carnegieite-low 9.06 5.88 -3.19 -0.456 0.54443E+04 39 carnegieite-high 10.13 5.88 -4.26 -0.608 0.72712E+04 40 carpholite-Mg 8.65 7.06 -1.59 -0.106 0.27205E+04 41 carpholite-Fe 6.78 4.83 -1.95 -0.130 0.33362E+04 42 celadonite 5.40 2.84 -2.56 -0.151 0.43729E+04 43 celadonite-Fe 3.94 0.61 -3.33 -0.196 0.56782E+04 44 chrysotile 23.94 19.14 -4.80 -0.400 0.81931E+04 50 chloritoid-Mg 13.26 10.38 -2.88 -0.192 0.49158E+04 51 chloritoid-Fe 9.24 8.15 -1.08 -0.072 0.18517E+04 52 chloritoid-Mn 11.46 10.28 -1.18 -0.079 0.20201E+04 54 coesite -2.37 -3.33 -0.96 -0.319 0.16321E+04 59 corundum 8.43 5.11 -3.32 -0.302 0.56730E+04 61 cristobalite -2.55 -3.33 -0.78 -0.259 0.13250E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.56 -0.34 -0.057 0.58156E+03 67 diopside 16.22 12.71 -3.51 -0.351 0.59931E+04 68 hedenbergite 14.24 10.48 -3.77 -0.377 0.64319E+04 75 epidote 24.78 22.95 -1.82 -0.088 0.31110E+04 76 clinozoisite 22.92 19.21 -3.71 -0.169 0.63368E+04 77 epidote-Fe 29.94 26.70 -3.24 -0.168 0.55326E+04 78 fayalite 14.08 9.41 -4.67 -0.667 0.79694E+04 83 gibbsite 4.10 2.56 -1.54 -0.220 0.26327E+04 87 greenalite 16.19 12.45 -3.74 -0.312 0.63849E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.55 -1.70 -0.170 0.29028E+04 97 kalsilite 7.62 4.22 -3.40 -0.486 0.58082E+04 98 kaolinite -1.27 -1.54 -0.27 -0.024 0.45462E+03 99 kyanite 4.93 1.79 -3.15 -0.315 0.53714E+04 101 laumontite 2.97 2.57 -0.40 -0.027 0.69122E+03 102 lawsonite 9.68 9.22 -0.46 -0.031 0.78248E+03 103 leucite 4.17 0.89 -3.27 -0.327 0.55907E+04 105 lizardite 23.29 19.14 -4.15 -0.346 0.70834E+04 107 magnetite 20.13 18.97 -1.17 -0.095 0.19922E+04 108 minnesotaite 10.46 5.80 -4.66 -0.274 0.79505E+04 113 margarite 17.45 14.33 -3.12 -0.125 0.53285E+04 120 muscovite 2.68 2.68 0.00 0.000 0.60662E-11 122 nepheline 8.38 5.88 -2.50 -0.357 0.42723E+04 134 phlogopite-Na 29.73 25.01 -4.72 -0.262 0.80531E+04 136 prehnite 19.47 16.65 -2.81 -0.165 0.48013E+04 137 prehnite-Fe 22.59 20.40 -2.19 -0.132 0.37377E+04 138 pumpellyite-Fe 46.47 42.23 -4.24 -0.094 0.72360E+04 139 pumpellyite-Mg 49.19 44.46 -4.73 -0.105 0.80819E+04 145 pyroxmangite 7.42 5.17 -2.25 -0.449 0.38366E+04 146 pyrophyllite -6.10 -8.19 -2.09 -0.131 0.35716E+04 147 quartz -2.98 -3.33 -0.34 -0.114 0.58599E+03 151 rhodochrosite -0.96 -5.80 -4.84 -1.615 0.82705E+04 152 rhodonite 7.46 5.17 -2.29 -0.459 0.39158E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.79 -3.54 -0.354 0.60369E+04 164 stilpnomelane-Fe 13.18 12.85 -0.33 -0.010 0.56985E+03 165 stilpnomelane-Mg 27.60 23.99 -3.61 -0.108 0.61647E+04 168 sudoite 21.22 17.44 -3.78 -0.122 0.64489E+04 171 talc 16.55 12.49 -4.06 -0.239 0.69405E+04 174 tephroite 18.11 13.66 -4.45 -0.636 0.75974E+04 177 topaz-H 4.67 1.79 -2.88 -0.262 0.49205E+04 178 tridymite -2.61 -3.33 -0.71 -0.237 0.12133E+04 187 wairakite 4.06 2.57 -1.49 -0.088 0.25420E+04 188 walstromite 11.53 7.43 -4.09 -0.819 0.69896E+04 189 wollastonite 10.48 7.43 -3.05 -0.610 0.52035E+04 190 pseudo-wollastonite 11.02 7.43 -3.59 -0.717 0.61222E+04 191 zoisite 22.96 19.21 -3.75 -0.171 0.64094E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.47 -2.91 -0.180 0.49759E+04 194 beidellite-H -2.24 -6.25 -4.01 -0.256 0.68436E+04 195 beidellite-K -1.44 -4.60 -3.17 -0.194 0.54093E+04 196 beidellite-Mg -1.71 -4.83 -3.12 -0.193 0.53339E+04 197 beidellite-Na -1.26 -4.06 -2.80 -0.171 0.47793E+04 199 chalcedony -2.79 -3.33 -0.53 -0.177 0.90631E+03 201 montmorillonite-Ca -2.21 -4.42 -2.21 -0.137 0.37683E+04 202 montmorillonite-K -2.16 -4.55 -2.39 -0.146 0.40794E+04 203 montmorillonite-Mg -2.40 -4.78 -2.38 -0.147 0.40573E+04 204 montmorillonite-Na -1.96 -4.00 -2.04 -0.125 0.34876E+04 205 nontronite-Ca 3.28 3.01 -0.27 -0.017 0.45566E+03 206 nontronite-H 2.60 1.24 -1.36 -0.091 0.23192E+04 207 nontronite-K 3.40 2.88 -0.52 -0.033 0.88824E+03 208 nontronite-Mg 3.14 2.66 -0.48 -0.031 0.82533E+03 209 nontronite-Na 3.58 3.43 -0.15 -0.010 0.25997E+03 224 tobermorite 9.84 5.64 -4.20 -1.146 0.71740E+04 233 boehmite 4.43 2.56 -1.87 -0.312 0.32000E+04 235 ferrous-oxide 9.82 6.37 -3.46 -0.864 0.59007E+04 240 silica-amorphous -2.08 -3.33 -1.25 -0.415 0.21265E+04 242 an20ab80 2.08 1.22 -0.85 -0.066 0.14593E+04 243 an25ab75 2.71 1.72 -0.98 -0.076 0.16817E+04 244 an30ab70 3.34 2.22 -1.12 -0.086 0.19124E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1.9990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9996E+00 Moles total = 0.5548E+02 kg total = 0.9995E+00 Activity = 1.0000 Stoichiometric ionic strength = .1617837E-02 Osmotic coef. = 0.9772 True ionic strength = .2572087E-02 Chg. balance for total moles = 0.4569E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.55966E-09 -9.2521 0.51569E-09 -9.2876 0.92143E+00 -0.0355 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12696E-03 -3.8963 0.92048E+00 -0.0360 4 SO4-- 0.25499E-04 -4.5935 0.19357E-04 -4.7132 0.75912E+00 -0.1197 5 HCO3- 0.10730E-04 -4.9694 0.98793E-05 -5.0053 0.92071E+00 -0.0359 6 HS- 0.36900E-13 -13.4330 0.33966E-13 -13.4689 0.92051E+00 -0.0360 7 Al+++ 0.86355E-25 -25.0637 0.47393E-25 -25.3243 0.54882E+00 -0.2606 8 H4SiO4 0.49125E-03 -3.3087 0.49125E-03 -3.3087 0.10000E+01 0.0000 9 Ca++ 0.16707E-07 -7.7771 0.12667E-07 -7.8973 0.75819E+00 -0.1202 10 Mg++ 0.13761E-09 -9.8613 0.10426E-09 -9.9819 0.75760E+00 -0.1206 11 Fe++ 0.81383E-12 -12.0895 0.61667E-12 -12.2099 0.75774E+00 -0.1205 12 K+ 0.50581E-04 -4.2960 0.46572E-04 -4.3319 0.92075E+00 -0.0359 13 Na+ 0.24856E-02 -2.6046 0.22879E-02 -2.6406 0.92046E+00 -0.0360 14 Mn++ 0.10873E-09 -9.9636 0.82404E-10 -10.0841 0.75785E+00 -0.1204 15 HPO4-- 0.79823E-05 -5.0979 0.60597E-05 -5.2175 0.75914E+00 -0.1197 16 HSiO3- 0.10097E-02 -2.9958 0.92943E-03 -3.0318 0.92048E+00 -0.0360 17 Ca(HSiO3)+ 0.28648E-09 -9.5429 0.26379E-09 -9.5787 0.92079E+00 -0.0358 18 Mg(HSiO3)+ 0.29344E-11 -11.5325 0.27019E-11 -11.5683 0.92079E+00 -0.0358 19 NaHSiO3,aq 0.33773E-04 -4.4714 0.33773E-04 -4.4714 0.10000E+01 0.0000 20 AlO+ 0.24986E-13 -13.6023 0.23007E-13 -13.6381 0.92079E+00 -0.0358 21 AlOH+2 0.78410E-19 -19.1056 0.59433E-19 -19.2260 0.75797E+00 -0.1203 22 HAlO2,aq 0.89277E-08 -8.0493 0.89277E-08 -8.0493 0.10000E+01 0.0000 23 AlO2- 0.42008E-04 -4.3767 0.38656E-04 -4.4128 0.92020E+00 -0.0361 24 CH4,aq 0.17020E-19 -19.7691 0.17011E-19 -19.7693 0.99950E+00 -0.0002 29 CO,aq 0.13531E-18 -18.8687 0.13531E-18 -18.8687 0.10000E+01 0.0000 30 CO2,aq 0.10277E-07 -7.9881 0.10272E-07 -7.9884 0.99950E+00 -0.0002 31 CO3-2 0.23342E-05 -5.6319 0.17713E-05 -5.7517 0.75885E+00 -0.1198 32 CaCO3,aq 0.27481E-09 -9.5610 0.27481E-09 -9.5610 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.34245E-11 -11.4654 0.31533E-11 -11.5012 0.92079E+00 -0.0358 34 CaCl+ 0.27832E-11 -11.5554 0.25628E-11 -11.5913 0.92079E+00 -0.0358 35 CaCl2,aq 0.75760E-16 -16.1206 0.75760E-16 -16.1206 0.10000E+01 0.0000 36 CaOH+ 0.18811E-08 -8.7256 0.17321E-08 -8.7614 0.92079E+00 -0.0358 37 CaSO4,aq 0.76398E-10 -10.1169 0.76398E-10 -10.1169 0.10000E+01 0.0000 38 HCl,aq 0.12315E-13 -13.9096 0.12315E-13 -13.9096 0.10000E+01 0.0000 43 FeCl+ 0.13244E-15 -15.8780 0.12194E-15 -15.9138 0.92079E+00 -0.0358 46 FeO,aq 0.91699E-10 -10.0376 0.91699E-10 -10.0376 0.10000E+01 0.0000 47 FeOH+ 0.43055E-10 -10.3660 0.39645E-10 -10.4018 0.92079E+00 -0.0358 48 HFeO2- 0.20778E-08 -8.6824 0.19126E-08 -8.7184 0.92048E+00 -0.0360 49 FeO+ 0.46328E-14 -14.3342 0.42658E-14 -14.3700 0.92079E+00 -0.0358 51 FeO2- 0.34251E-08 -8.4653 0.31527E-08 -8.5013 0.92048E+00 -0.0360 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.51173E-09 -9.2910 0.51147E-09 -9.2912 0.99950E+00 -0.0002 54 KCl,aq 0.10470E-09 -9.9801 0.10470E-09 -9.9801 0.10000E+01 0.0000 55 KHSO4,aq 0.12440E-17 -17.9052 0.12440E-17 -17.9052 0.10000E+01 0.0000 56 KOH,aq 0.39371E-07 -7.4048 0.39371E-07 -7.4048 0.10000E+01 0.0000 57 KSO4- 0.15088E-07 -7.8214 0.13889E-07 -7.8573 0.92048E+00 -0.0360 58 MgCO3,aq 0.56517E-12 -12.2478 0.56517E-12 -12.2478 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28741E-13 -13.5415 0.26465E-13 -13.5773 0.92079E+00 -0.0358 60 MgCl+ 0.20796E-13 -13.6820 0.19148E-13 -13.7179 0.92079E+00 -0.0358 61 MgOH+ 0.85771E-10 -10.0667 0.78977E-10 -10.1025 0.92079E+00 -0.0358 63 MnO,aq 0.32711E-09 -9.4853 0.32711E-09 -9.4853 0.10000E+01 0.0000 64 MnOH+ 0.53446E-09 -9.2721 0.49212E-09 -9.3079 0.92079E+00 -0.0358 65 MnO2-2 0.56057E-13 -13.2514 0.42539E-13 -13.3712 0.75885E+00 -0.1198 66 HMnO2- 0.51634E-11 -11.2871 0.47528E-11 -11.3230 0.92048E+00 -0.0360 69 MnCl+ 0.68767E-13 -13.1626 0.63320E-13 -13.1985 0.92079E+00 -0.0358 70 MnSO4,aq 0.45204E-12 -12.3448 0.45204E-12 -12.3448 0.10000E+01 0.0000 71 NaCl,aq 0.94848E-07 -7.0230 0.94848E-07 -7.0230 0.10000E+01 0.0000 72 NaOH,aq 0.19495E-05 -5.7101 0.19495E-05 -5.7101 0.10000E+01 0.0000 74 OH- 0.12640E-02 -2.8982 0.11632E-02 -2.9344 0.92020E+00 -0.0361 79 HPO3-2 0.12901E-16 -16.8894 0.97895E-17 -17.0092 0.75885E+00 -0.1198 81 H2PO3- 0.10773E-19 -19.9677 0.99166E-20 -20.0036 0.92048E+00 -0.0360 82 H3PO4,aq 0.10375E-13 -13.9840 0.10375E-13 -13.9840 0.10000E+01 0.0000 83 H2PO4- 0.59509E-07 -7.2254 0.54786E-07 -7.2613 0.92063E+00 -0.0359 84 PO4-3 0.18543E-07 -7.7318 0.10262E-07 -7.9888 0.55343E+00 -0.2569 87 H2P2O7-2 0.30957E-15 -15.5092 0.23491E-15 -15.6291 0.75885E+00 -0.1198 88 HP2O7-3 0.17018E-12 -12.7691 0.93409E-13 -13.0296 0.54887E+00 -0.2605 89 P2O7-4 0.12746E-12 -12.8946 0.44686E-13 -13.3498 0.35059E+00 -0.4552 90 H2S,aq 0.52655E-16 -16.2786 0.52628E-16 -16.2788 0.99950E+00 -0.0002 97 SO3-2 0.17745E-14 -14.7509 0.13499E-14 -14.8697 0.76072E+00 -0.1188 98 HSO3- 0.44258E-16 -16.3540 0.40739E-16 -16.3900 0.92048E+00 -0.0360 99 HSO4- 0.10057E-10 -10.9975 0.92619E-11 -11.0333 0.92093E+00 -0.0358 Charge balance for all species = 0.4570E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5596600E-09 -.2479889E-02 -.2499034E+01 0.0000 2 H2O 0.1000000E+01 0.5550856E+02 0.9997850E+06 0.0000 3 Cl- 0.1379302E-03 0.1380252E-03 0.4892339E+01 5.3913 4 SO4-- 0.2549872E-04 0.2551423E-04 0.2450402E+01 13.8621 5 HCO3- 0.1073008E-04 0.1307483E-04 0.7976155E+00 4.2823 6 HS- 0.3689972E-13 -.3255965E-09 -.1076578E-04 -4.1813 7 Al+++ 0.8635504E-25 0.4201721E-04 0.1133440E+01 2.5386 8 H4SiO4 0.4912497E-03 0.1534742E-02 0.1474802E+03 -3.3087 9 Ca++ 0.1670731E-07 0.1923228E-07 0.7706232E-03 10.6779 10 Mg++ 0.1376139E-09 0.2269341E-09 0.5516018E-05 8.5933 11 Fe++ 0.8138266E-12 0.5841936E-08 0.3261834E-03 6.3653 12 K+ 0.5058070E-04 0.5063526E-04 0.1979508E+01 4.9557 13 Na+ 0.2485581E-02 0.2521398E-02 0.5795379E+02 6.6470 14 Mn++ 0.1087335E-09 0.9760419E-09 0.5361009E-04 8.4912 15 HPO4-- 0.7982321E-05 0.8060373E-05 0.7734577E+00 13.3577 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3308743E-01 -.2478972E-02 -.3060846E-01 0.0000000E+00 2 H2O 0.5548319E+02 0.5548804E+02 -.4848723E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8090357E-04 0.2550480E-04 0.5539878E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5539910E-04 -.3254762E-09 -.5539878E-04 0.0000000E+00 7 Al+++ 0.6518222E-02 0.4200168E-04 0.6476221E-02 0.0000000E+00 8 H4SiO4 0.2081515E-01 0.1534175E-02 0.1928098E-01 0.0000000E+00 9 Ca++ 0.2313606E-02 0.1922517E-07 0.2313587E-02 0.0000000E+00 10 Mg++ 0.1586508E-02 0.2268502E-09 0.1586508E-02 0.0000000E+00 11 Fe++ 0.1425304E-02 0.5839777E-08 0.1425298E-02 0.0000000E+00 12 K+ 0.4244161E-03 0.5061655E-04 0.3737996E-03 0.0000000E+00 13 Na+ 0.2669303E-02 0.2520466E-02 0.1488367E-03 0.0000000E+00 14 Mn++ 0.3465985E-04 0.9756812E-09 0.3465888E-04 0.0000000E+00 15 HPO4-- 0.1182924E-04 0.8057394E-05 0.3771841E-05 0.0000000E+00 Chg. balance for solid moles: -.4743E-19 Mass of aqueous solution: 0.999849E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1257E-05 -5.901 0.6316E-03 -3.200 0.2945E-01 0.2007E-03 clinochlore 0.3173E-03 -3.499 0.1764 -0.754 8.225 0.6708E-01 daphnite 0.1964E-03 -3.707 0.1401 -0.853 6.536 0.4247E-01 chlorite-Mn 0.6932E-05 -5.159 0.4914E-02 -2.309 0.2292 0.1566E-02 hematite 0.2216E-03 -3.654 0.3539E-01 -1.451 1.650 0.6707E-02 microcline 0.3738E-03 -3.427 0.1040 -0.983 4.852 0.4064E-01 paragonite 0.1488E-03 -3.827 0.5689E-01 -1.245 2.653 0.1966E-01 stilbite 0.2307E-02 -2.637 1.626 0.211 75.83 0.7584 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.144379 g Volume = 0.936729 cm3 Porosity: 47.9479% V(tot) - V(min): 0.86287E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1.9990000 g log = 0.3008 Original solution: 1000.0103000 g Original solution / Rock added: 500.26 (Water/Rock Ratio), log = 2.6992 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1110E-05 1.0073 0.1176E-05 0.1167E-05 CH4,gas 0.2525E-16 1.0129 0.2690E-16 0.2656E-16 H2,gas 0.6665E-06 1.0006 0.7015E-06 0.7011E-06 H2S,gas 0.1465E-14 0.9959 0.1535E-14 0.1541E-14 S2,gas 0.1705E-36 1.0000 0.1793E-36 0.1793E-36 CO,gas 0.2031E-15 1.0000 0.2137E-15 0.2137E-15 SO3,gas 0.1829E-38 1.0000 0.1924E-38 0.1924E-38 SO2,gas 0.4855E-22 1.0000 0.5107E-22 0.5107E-22 HCl,gas 0.2067E-16 1.0000 0.2175E-16 0.2175E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.28814E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.29 -7.93 -2.643 0.13540E+05 -5.930 3 CH4,gas 4.81 -13.76 -18.57 -4.643 0.31708E+05 -16.570 4 H2,gas 8.29 0.13 -8.15 -4.659 0.13923E+05 -6.154 5 H2S,gas -5.94 -22.76 -16.81 -8.407 0.28709E+05 -14.814 6 S2,gas -7.03 -45.78 -38.75 -5.961 0.66158E+05 -36.746 7 CO,gas 3.51 -14.16 -17.67 -5.437 0.30172E+05 -15.670 8 SO3,gas 17.43 -23.29 -40.72 -10.179 0.69521E+05 -38.716 9 SO2,gas 1.14 -23.16 -24.29 -6.478 0.41478E+05 -22.292 10 HCl,gas 5.48 -13.18 -18.66 -9.331 0.31866E+05 -16.663 11 acmite 7.74 6.33 -1.41 -0.146 0.24057E+04 15 albite-high 0.75 -0.74 -1.49 -0.115 0.25443E+04 16 albite -0.33 -0.74 -0.41 -0.032 0.70369E+03 19 spessartine 24.55 20.62 -3.93 -0.196 0.67024E+04 20 analcite 3.37 2.57 -0.80 -0.089 0.13701E+04 21 andalusite 5.06 1.77 -3.29 -0.329 0.56243E+04 22 andradite 39.09 34.71 -4.38 -0.228 0.74830E+04 26 annite 20.21 16.66 -3.55 -0.197 0.60535E+04 27 phlogopite 27.15 23.35 -3.80 -0.211 0.64857E+04 29 anorthite 12.80 9.14 -3.66 -0.282 0.62494E+04 35 aragonite 0.99 -3.61 -4.60 -1.534 0.78564E+04 36 brucite 12.58 8.59 -3.98 -0.797 0.68013E+04 37 calcite 0.83 -3.61 -4.45 -1.483 0.75951E+04 38 carnegieite-low 9.06 5.88 -3.19 -0.455 0.54428E+04 39 carnegieite-high 10.13 5.88 -4.26 -0.608 0.72697E+04 40 carpholite-Mg 8.65 7.05 -1.60 -0.106 0.27274E+04 41 carpholite-Fe 6.78 4.82 -1.96 -0.131 0.33430E+04 42 celadonite 5.40 2.85 -2.55 -0.150 0.43501E+04 43 celadonite-Fe 3.94 0.62 -3.31 -0.195 0.56554E+04 44 chrysotile 23.94 19.16 -4.77 -0.398 0.81527E+04 50 chloritoid-Mg 13.26 10.36 -2.90 -0.193 0.49508E+04 51 chloritoid-Fe 9.24 8.13 -1.10 -0.074 0.18867E+04 52 chloritoid-Mn 11.46 10.26 -1.20 -0.080 0.20551E+04 54 coesite -2.37 -3.31 -0.94 -0.313 0.16039E+04 59 corundum 8.43 5.08 -3.36 -0.305 0.57308E+04 61 cristobalite -2.55 -3.31 -0.76 -0.253 0.12968E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.54 -0.36 -0.060 0.61047E+03 67 diopside 16.22 12.65 -3.56 -0.356 0.60814E+04 68 hedenbergite 14.24 10.43 -3.82 -0.382 0.65202E+04 75 epidote 24.78 22.81 -1.97 -0.095 0.33630E+04 76 clinozoisite 22.92 19.05 -3.88 -0.176 0.66177E+04 77 epidote-Fe 29.94 26.57 -3.37 -0.175 0.57557E+04 78 fayalite 14.08 9.42 -4.66 -0.665 0.79519E+04 83 gibbsite 4.10 2.54 -1.56 -0.223 0.26617E+04 87 greenalite 16.19 12.48 -3.72 -0.310 0.63446E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.57 -1.68 -0.168 0.28732E+04 97 kalsilite 7.62 4.19 -3.43 -0.491 0.58646E+04 98 kaolinite -1.27 -1.54 -0.27 -0.024 0.45613E+03 99 kyanite 4.93 1.77 -3.16 -0.316 0.54011E+04 101 laumontite 2.97 2.52 -0.45 -0.030 0.77572E+03 102 lawsonite 9.68 9.14 -0.54 -0.036 0.92330E+03 103 leucite 4.17 0.88 -3.29 -0.329 0.56188E+04 105 lizardite 23.29 19.16 -4.12 -0.344 0.70430E+04 107 magnetite 20.13 18.96 -1.17 -0.096 0.19975E+04 108 minnesotaite 10.46 5.86 -4.60 -0.271 0.78538E+04 113 margarite 17.45 14.21 -3.24 -0.129 0.55272E+04 120 muscovite 2.68 2.65 -0.03 -0.002 0.57839E+02 122 nepheline 8.38 5.88 -2.50 -0.357 0.42708E+04 134 phlogopite-Na 29.73 25.04 -4.69 -0.261 0.80112E+04 136 prehnite 19.47 16.51 -2.96 -0.174 0.50532E+04 137 prehnite-Fe 22.59 20.27 -2.32 -0.140 0.39608E+04 138 pumpellyite-Fe 46.47 41.92 -4.55 -0.101 0.77742E+04 145 pyroxmangite 7.42 5.18 -2.23 -0.447 0.38137E+04 146 pyrophyllite -6.10 -8.16 -2.06 -0.129 0.35168E+04 147 quartz -2.98 -3.31 -0.33 -0.109 0.55783E+03 151 rhodochrosite -0.96 -5.80 -4.84 -1.614 0.82696E+04 152 rhodonite 7.46 5.18 -2.28 -0.456 0.38930E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.77 -3.55 -0.355 0.60665E+04 164 stilpnomelane-Fe 13.18 12.91 -0.27 -0.008 0.45681E+03 165 stilpnomelane-Mg 27.60 24.05 -3.54 -0.106 0.60516E+04 168 sudoite 21.22 17.41 -3.80 -0.123 0.64908E+04 171 talc 16.55 12.55 -4.01 -0.236 0.68438E+04 174 tephroite 18.11 13.67 -4.44 -0.634 0.75799E+04 177 topaz-H 4.67 1.77 -2.90 -0.264 0.49502E+04 178 tridymite -2.61 -3.31 -0.69 -0.231 0.11851E+04 187 wairakite 4.06 2.52 -1.54 -0.090 0.26265E+04 188 walstromite 11.53 7.37 -4.16 -0.832 0.71008E+04 189 wollastonite 10.48 7.37 -3.11 -0.623 0.53147E+04 190 pseudo-wollastonite 11.02 7.37 -3.65 -0.730 0.62333E+04 191 zoisite 22.96 19.05 -3.92 -0.178 0.66903E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.47 -2.91 -0.180 0.49629E+04 194 beidellite-H -2.24 -6.23 -3.99 -0.254 0.68076E+04 195 beidellite-K -1.44 -4.59 -3.16 -0.193 0.53916E+04 196 beidellite-Mg -1.71 -4.81 -3.10 -0.192 0.52988E+04 197 beidellite-Na -1.26 -4.03 -2.78 -0.170 0.47426E+04 199 chalcedony -2.79 -3.31 -0.51 -0.171 0.87815E+03 201 montmorillonite-Ca -2.21 -4.40 -2.18 -0.135 0.37286E+04 202 montmorillonite-K -2.16 -4.52 -2.36 -0.145 0.40352E+04 203 montmorillonite-Mg -2.40 -4.74 -2.34 -0.145 0.39956E+04 204 montmorillonite-Na -1.96 -3.97 -2.01 -0.123 0.34243E+04 205 nontronite-Ca 3.28 3.05 -0.23 -0.015 0.38483E+03 206 nontronite-H 2.60 1.29 -1.30 -0.087 0.22254E+04 207 nontronite-K 3.40 2.93 -0.48 -0.031 0.81276E+03 208 nontronite-Mg 3.14 2.71 -0.43 -0.028 0.73238E+03 209 nontronite-Na 3.58 3.49 -0.10 -0.006 0.16540E+03 224 tobermorite 9.84 5.59 -4.25 -1.160 0.72619E+04 233 boehmite 4.43 2.54 -1.89 -0.315 0.32289E+04 235 ferrous-oxide 9.82 6.37 -3.46 -0.865 0.59060E+04 240 silica-amorphous -2.08 -3.31 -1.23 -0.410 0.20983E+04 242 an20ab80 2.08 1.24 -0.84 -0.065 0.14412E+04 243 an25ab75 2.71 1.73 -0.98 -0.075 0.16735E+04 244 an30ab70 3.34 2.22 -1.12 -0.086 0.19142E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 1.9990000 g New total amount of reactant added: 2.0990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4568E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2.0990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9996E+00 Moles total = 0.5548E+02 kg total = 0.9995E+00 Activity = 1.0000 Stoichiometric ionic strength = .1678341E-02 Osmotic coef. = 0.9768 True ionic strength = .2686456E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.53780E-09 -9.2694 0.49491E-09 -9.3055 0.92024E+00 -0.0361 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12679E-03 -3.8969 0.91926E+00 -0.0366 4 SO4-- 0.25500E-04 -4.5935 0.19256E-04 -4.7154 0.75515E+00 -0.1220 5 HCO3- 0.10643E-04 -4.9729 0.97862E-05 -5.0094 0.91949E+00 -0.0365 6 HS- 0.37876E-13 -13.4216 0.34819E-13 -13.4582 0.91928E+00 -0.0366 7 Al+++ 0.74163E-25 -25.1298 0.40221E-25 -25.3955 0.54233E+00 -0.2657 8 H4SiO4 0.49733E-03 -3.3034 0.49733E-03 -3.3034 0.10000E+01 0.0000 9 Ca++ 0.15396E-07 -7.8126 0.11611E-07 -7.9351 0.75419E+00 -0.1225 10 Mg++ 0.12856E-09 -9.8909 0.96880E-10 -10.0138 0.75358E+00 -0.1229 11 Fe++ 0.76028E-12 -12.1190 0.57304E-12 -12.2418 0.75373E+00 -0.1228 12 K+ 0.48790E-04 -4.3117 0.44864E-04 -4.3481 0.91954E+00 -0.0364 13 Na+ 0.26008E-02 -2.5849 0.23908E-02 -2.6215 0.91924E+00 -0.0366 14 Mn++ 0.10158E-09 -9.9932 0.76574E-10 -10.1159 0.75384E+00 -0.1227 15 HPO4-- 0.87818E-05 -5.0564 0.66318E-05 -5.1784 0.75517E+00 -0.1220 16 HSiO3- 0.10666E-02 -2.9720 0.98045E-03 -3.0086 0.91926E+00 -0.0366 17 Ca(HSiO3)+ 0.27738E-09 -9.5569 0.25507E-09 -9.5933 0.91957E+00 -0.0364 18 Mg(HSiO3)+ 0.28802E-11 -11.5406 0.26486E-11 -11.5770 0.91957E+00 -0.0364 19 NaHSiO3,aq 0.37229E-04 -4.4291 0.37229E-04 -4.4291 0.10000E+01 0.0000 20 AlO+ 0.23054E-13 -13.6373 0.21199E-13 -13.6737 0.91957E+00 -0.0364 21 AlOH+2 0.69707E-19 -19.1567 0.52557E-19 -19.2794 0.75397E+00 -0.1226 22 HAlO2,aq 0.85718E-08 -8.0669 0.85718E-08 -8.0669 0.10000E+01 0.0000 23 AlO2- 0.42084E-04 -4.3759 0.38674E-04 -4.4126 0.91896E+00 -0.0367 24 CH4,aq 0.17373E-19 -19.7601 0.17364E-19 -19.7604 0.99948E+00 -0.0002 29 CO,aq 0.13094E-18 -18.8829 0.13094E-18 -18.8829 0.10000E+01 0.0000 30 CO2,aq 0.97700E-08 -8.0101 0.97650E-08 -8.0103 0.99948E+00 -0.0002 31 CO3-2 0.24220E-05 -5.6158 0.18283E-05 -5.7380 0.75487E+00 -0.1221 32 CaCO3,aq 0.26000E-09 -9.5850 0.26000E-09 -9.5850 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.31136E-11 -11.5067 0.28632E-11 -11.5432 0.91957E+00 -0.0364 34 CaCl+ 0.25512E-11 -11.5933 0.23460E-11 -11.6297 0.91957E+00 -0.0364 35 CaCl2,aq 0.69258E-16 -16.1595 0.69258E-16 -16.1595 0.10000E+01 0.0000 36 CaOH+ 0.17991E-08 -8.7450 0.16544E-08 -8.7814 0.91957E+00 -0.0364 37 CaSO4,aq 0.69666E-10 -10.1570 0.69666E-10 -10.1570 0.10000E+01 0.0000 38 HCl,aq 0.11803E-13 -13.9280 0.11803E-13 -13.9280 0.10000E+01 0.0000 43 FeCl+ 0.12306E-15 -15.9099 0.11316E-15 -15.9463 0.91957E+00 -0.0364 46 FeO,aq 0.92518E-10 -10.0338 0.92518E-10 -10.0338 0.10000E+01 0.0000 47 FeOH+ 0.41744E-10 -10.3794 0.38387E-10 -10.4158 0.91957E+00 -0.0364 48 HFeO2- 0.21873E-08 -8.6601 0.20107E-08 -8.6966 0.91926E+00 -0.0366 49 FeO+ 0.44520E-14 -14.3514 0.40939E-14 -14.3879 0.91957E+00 -0.0364 51 FeO2- 0.35736E-08 -8.4469 0.32851E-08 -8.4835 0.91926E+00 -0.0366 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.52092E-09 -9.2832 0.52065E-09 -9.2835 0.99948E+00 -0.0002 54 KCl,aq 0.10072E-09 -9.9969 0.10072E-09 -9.9969 0.10000E+01 0.0000 55 KHSO4,aq 0.11441E-17 -17.9415 0.11441E-17 -17.9415 0.10000E+01 0.0000 56 KOH,aq 0.39520E-07 -7.4032 0.39520E-07 -7.4032 0.10000E+01 0.0000 57 KSO4- 0.14479E-07 -7.8393 0.13310E-07 -7.8758 0.91926E+00 -0.0366 58 MgCO3,aq 0.54208E-12 -12.2659 0.54208E-12 -12.2659 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26491E-13 -13.5769 0.24360E-13 -13.6133 0.91957E+00 -0.0364 60 MgCl+ 0.19324E-13 -13.7139 0.17770E-13 -13.7503 0.91957E+00 -0.0364 61 MgOH+ 0.83159E-10 -10.0801 0.76471E-10 -10.1165 0.91957E+00 -0.0364 63 MnO,aq 0.33003E-09 -9.4814 0.33003E-09 -9.4814 0.10000E+01 0.0000 64 MnOH+ 0.51819E-09 -9.2855 0.47651E-09 -9.3219 0.91957E+00 -0.0364 65 MnO2-2 0.61731E-13 -13.2095 0.46599E-13 -13.3316 0.75487E+00 -0.1221 66 HMnO2- 0.54355E-11 -11.2648 0.49967E-11 -11.3013 0.91926E+00 -0.0366 69 MnCl+ 0.63900E-13 -13.1945 0.58761E-13 -13.2309 0.91957E+00 -0.0364 70 MnSO4,aq 0.41788E-12 -12.3789 0.41788E-12 -12.3789 0.10000E+01 0.0000 71 NaCl,aq 0.98981E-07 -7.0044 0.98981E-07 -7.0044 0.10000E+01 0.0000 72 NaOH,aq 0.21227E-05 -5.6731 0.21227E-05 -5.6731 0.10000E+01 0.0000 74 OH- 0.13189E-02 -2.8798 0.12120E-02 -2.9165 0.91896E+00 -0.0367 79 HPO3-2 0.14447E-16 -16.8402 0.10906E-16 -16.9623 0.75487E+00 -0.1221 81 H2PO3- 0.11534E-19 -19.9380 0.10602E-19 -19.9746 0.91926E+00 -0.0366 82 H3PO4,aq 0.10457E-13 -13.9806 0.10457E-13 -13.9806 0.10000E+01 0.0000 83 H2PO4- 0.62586E-07 -7.2035 0.57542E-07 -7.2400 0.91941E+00 -0.0365 84 PO4-3 0.21391E-07 -7.6698 0.11703E-07 -7.9317 0.54707E+00 -0.2620 87 H2P2O7-2 0.34330E-15 -15.4643 0.25914E-15 -15.5865 0.75487E+00 -0.1221 88 HP2O7-3 0.19796E-12 -12.7034 0.10737E-12 -12.9691 0.54239E+00 -0.2657 89 P2O7-4 0.15589E-12 -12.8072 0.53522E-13 -13.2715 0.34333E+00 -0.4643 90 H2S,aq 0.51802E-16 -16.2857 0.51775E-16 -16.2859 0.99948E+00 -0.0002 97 SO3-2 0.18063E-14 -14.7432 0.13670E-14 -14.8642 0.75681E+00 -0.1210 98 HSO3- 0.43070E-16 -16.3658 0.39592E-16 -16.4024 0.91926E+00 -0.0366 99 HSO4- 0.96143E-11 -11.0171 0.88425E-11 -11.0534 0.91972E+00 -0.0363 Charge balance for all species = 0.4572E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5377993E-09 -.2595607E-02 -.2615622E+01 0.0000 2 H2O 0.1000000E+01 0.5550855E+02 0.9997760E+06 0.0000 3 Cl- 0.1379286E-03 0.1380277E-03 0.4892383E+01 5.4086 4 SO4-- 0.2549980E-04 0.2551470E-04 0.2450426E+01 13.8955 5 HCO3- 0.1064304E-04 0.1307507E-04 0.7976226E+00 4.2961 6 HS- 0.3787617E-13 -.3418710E-09 -.1130379E-04 -4.1527 7 Al+++ 0.7416291E-25 0.4209241E-04 0.1135458E+01 2.5209 8 H4SiO4 0.4973317E-03 0.1601127E-02 0.1538580E+03 -3.3034 9 Ca++ 0.1539588E-07 0.1780765E-07 0.7135328E-03 10.6758 10 Mg++ 0.1285600E-09 0.2151873E-09 0.5230446E-05 8.5972 11 Fe++ 0.7602775E-12 0.6099472E-08 0.3405598E-03 6.3691 12 K+ 0.4878993E-04 0.4884403E-04 0.1909465E+01 4.9574 13 Na+ 0.2600848E-02 0.2640299E-02 0.6068616E+02 6.6840 14 Mn++ 0.1015785E-09 0.9557727E-09 0.5249631E-04 8.4950 15 HPO4-- 0.8781837E-05 0.8865815E-05 0.8507388E+00 13.4326 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3474328E-01 -.2594602E-02 -.3214868E-01 0.0000000E+00 2 H2O 0.5548194E+02 0.5548705E+02 -.5108553E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8367492E-04 0.2550481E-04 0.5817010E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5817045E-04 -.3417385E-09 -.5817010E-04 0.0000000E+00 7 Al+++ 0.6844297E-02 0.4207610E-04 0.6802221E-02 0.0000000E+00 8 H4SiO4 0.2185643E-01 0.1600507E-02 0.2025592E-01 0.0000000E+00 9 Ca++ 0.2428620E-02 0.1780075E-07 0.2428603E-02 0.0000000E+00 10 Mg++ 0.1665873E-02 0.2151040E-09 0.1665873E-02 0.0000000E+00 11 Fe++ 0.1496605E-02 0.6097109E-08 0.1496599E-02 0.0000000E+00 12 K+ 0.4456476E-03 0.4882511E-04 0.3968225E-03 0.0000000E+00 13 Na+ 0.2794827E-02 0.2639276E-02 0.1555511E-03 0.0000000E+00 14 Mn++ 0.3639371E-04 0.9554024E-09 0.3639276E-04 0.0000000E+00 15 HPO4-- 0.1242099E-04 0.8862380E-05 0.3558613E-05 0.0000000E+00 Chg. balance for solid moles: 0.4929E-17 Mass of aqueous solution: 0.999840E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2.0990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1186E-05 -5.926 0.5959E-03 -3.225 0.2645E-01 0.1893E-03 clinochlore 0.3332E-03 -3.477 0.1852 -0.732 8.222 0.7044E-01 daphnite 0.2062E-03 -3.686 0.1472 -0.832 6.533 0.4459E-01 chlorite-Mn 0.7279E-05 -5.138 0.5160E-02 -2.287 0.2291 0.1644E-02 hematite 0.2327E-03 -3.633 0.3716E-01 -1.430 1.650 0.7043E-02 microcline 0.3968E-03 -3.401 0.1105 -0.957 4.904 0.4315E-01 paragonite 0.1556E-03 -3.808 0.5945E-01 -1.226 2.639 0.2055E-01 stilbite 0.2423E-02 -2.616 1.707 0.232 75.80 0.7963 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.252472 g Volume = 0.983924 cm3 Porosity: 46.5142% V(tot) - V(min): 0.85568E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.0990000 g log = 0.3220 Original solution: 1000.0103000 g Original solution / Rock added: 476.42 (Water/Rock Ratio), log = 2.6780 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1055E-05 1.0073 0.1118E-05 0.1110E-05 CH4,gas 0.2577E-16 1.0129 0.2746E-16 0.2711E-16 H2,gas 0.6785E-06 1.0006 0.7141E-06 0.7137E-06 H2S,gas 0.1441E-14 0.9959 0.1510E-14 0.1516E-14 S2,gas 0.1592E-36 1.0000 0.1675E-36 0.1675E-36 CO,gas 0.1966E-15 1.0000 0.2068E-15 0.2068E-15 SO3,gas 0.1676E-38 1.0000 0.1763E-38 0.1763E-38 SO2,gas 0.4528E-22 1.0000 0.4763E-22 0.4763E-22 HCl,gas 0.1981E-16 1.0000 0.2084E-16 0.2084E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.28814E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.31 -7.95 -2.651 0.13577E+05 -5.952 3 CH4,gas 4.81 -13.75 -18.56 -4.640 0.31693E+05 -16.561 4 H2,gas 8.29 0.14 -8.15 -4.655 0.13909E+05 -6.146 5 H2S,gas -5.94 -22.76 -16.82 -8.411 0.28721E+05 -14.821 6 S2,gas -7.03 -45.81 -38.78 -5.966 0.66209E+05 -36.776 7 CO,gas 3.51 -14.17 -17.68 -5.441 0.30196E+05 -15.685 8 SO3,gas 17.43 -23.33 -40.75 -10.188 0.69586E+05 -38.754 9 SO2,gas 1.14 -23.19 -24.32 -6.486 0.41529E+05 -22.322 10 HCl,gas 5.48 -13.20 -18.68 -9.341 0.31897E+05 -16.681 11 acmite 7.74 6.38 -1.36 -0.141 0.23243E+04 15 albite-high 0.75 -0.71 -1.45 -0.112 0.24840E+04 16 albite -0.33 -0.71 -0.38 -0.029 0.64336E+03 19 spessartine 24.55 20.62 -3.93 -0.197 0.67156E+04 20 analcite 3.37 2.60 -0.77 -0.086 0.13189E+04 21 andalusite 5.06 1.74 -3.32 -0.332 0.56755E+04 22 andradite 39.09 34.72 -4.37 -0.227 0.74662E+04 26 annite 20.21 16.68 -3.53 -0.196 0.60337E+04 27 phlogopite 27.15 23.36 -3.79 -0.210 0.64659E+04 29 anorthite 12.80 9.11 -3.69 -0.284 0.62951E+04 35 aragonite 0.99 -3.64 -4.63 -1.542 0.78975E+04 36 brucite 12.58 8.60 -3.98 -0.796 0.67947E+04 37 calcite 0.83 -3.64 -4.47 -1.491 0.76361E+04 38 carnegieite-low 9.06 5.90 -3.16 -0.452 0.54007E+04 39 carnegieite-high 10.13 5.90 -4.23 -0.605 0.72276E+04 40 carpholite-Mg 8.65 7.03 -1.62 -0.108 0.27629E+04 41 carpholite-Fe 6.78 4.80 -1.98 -0.132 0.33785E+04 42 celadonite 5.40 2.86 -2.54 -0.149 0.43344E+04 43 celadonite-Fe 3.94 0.63 -3.30 -0.194 0.56397E+04 44 chrysotile 23.94 19.18 -4.75 -0.396 0.81147E+04 50 chloritoid-Mg 13.26 10.34 -2.93 -0.195 0.49954E+04 51 chloritoid-Fe 9.24 8.11 -1.13 -0.075 0.19313E+04 52 chloritoid-Mn 11.46 10.23 -1.23 -0.082 0.20998E+04 54 coesite -2.37 -3.30 -0.93 -0.311 0.15948E+04 59 corundum 8.43 5.04 -3.39 -0.308 0.57911E+04 61 cristobalite -2.55 -3.30 -0.75 -0.251 0.12877E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.52 -0.38 -0.063 0.64064E+03 67 diopside 16.22 12.67 -3.55 -0.355 0.60601E+04 68 hedenbergite 14.24 10.44 -3.81 -0.381 0.64989E+04 75 epidote 24.78 22.78 -1.99 -0.097 0.34030E+04 76 clinozoisite 22.92 19.00 -3.92 -0.178 0.66879E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.175 0.57655E+04 78 fayalite 14.08 9.43 -4.64 -0.663 0.79295E+04 83 gibbsite 4.10 2.52 -1.58 -0.225 0.26918E+04 87 greenalite 16.19 12.50 -3.69 -0.308 0.63065E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.60 -1.65 -0.165 0.28219E+04 97 kalsilite 7.62 4.17 -3.45 -0.492 0.58828E+04 98 kaolinite -1.27 -1.56 -0.29 -0.027 0.49822E+03 99 kyanite 4.93 1.74 -3.19 -0.319 0.54523E+04 101 laumontite 2.97 2.50 -0.47 -0.031 0.80309E+03 102 lawsonite 9.68 9.11 -0.57 -0.038 0.96892E+03 103 leucite 4.17 0.87 -3.30 -0.330 0.56280E+04 105 lizardite 23.29 19.18 -4.10 -0.342 0.70050E+04 107 magnetite 20.13 18.97 -1.17 -0.095 0.19910E+04 108 minnesotaite 10.46 5.89 -4.57 -0.269 0.77975E+04 113 margarite 17.45 14.15 -3.30 -0.132 0.56331E+04 120 muscovite 2.68 2.61 -0.07 -0.004 0.11817E+03 122 nepheline 8.38 5.90 -2.48 -0.354 0.42287E+04 134 phlogopite-Na 29.73 25.09 -4.64 -0.258 0.79311E+04 136 prehnite 19.47 16.48 -2.98 -0.175 0.50933E+04 137 prehnite-Fe 22.59 20.26 -2.33 -0.140 0.39706E+04 138 pumpellyite-Fe 46.47 41.86 -4.61 -0.103 0.78778E+04 145 pyroxmangite 7.42 5.19 -2.22 -0.445 0.37980E+04 146 pyrophyllite -6.10 -8.17 -2.07 -0.130 0.35406E+04 147 quartz -2.98 -3.30 -0.32 -0.107 0.54871E+03 151 rhodochrosite -0.96 -5.82 -4.86 -1.620 0.83005E+04 152 rhodonite 7.46 5.19 -2.27 -0.454 0.38773E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.74 -3.58 -0.358 0.61177E+04 164 stilpnomelane-Fe 13.18 12.94 -0.24 -0.007 0.40979E+03 165 stilpnomelane-Mg 27.60 24.08 -3.52 -0.105 0.60046E+04 168 sudoite 21.22 17.37 -3.85 -0.124 0.65709E+04 171 talc 16.55 12.58 -3.98 -0.234 0.67876E+04 174 tephroite 18.11 13.69 -4.43 -0.632 0.75576E+04 177 topaz-H 4.67 1.74 -2.93 -0.266 0.50014E+04 178 tridymite -2.61 -3.30 -0.69 -0.230 0.11760E+04 187 wairakite 4.06 2.50 -1.55 -0.091 0.26539E+04 188 walstromite 11.53 7.37 -4.16 -0.831 0.70952E+04 189 wollastonite 10.48 7.37 -3.11 -0.622 0.53091E+04 190 pseudo-wollastonite 11.02 7.37 -3.65 -0.729 0.62277E+04 191 zoisite 22.96 19.00 -3.96 -0.180 0.67605E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.49 -2.93 -0.181 0.50002E+04 194 beidellite-H -2.24 -6.25 -4.01 -0.256 0.68445E+04 195 beidellite-K -1.44 -4.61 -3.18 -0.195 0.54275E+04 196 beidellite-Mg -1.71 -4.83 -3.12 -0.193 0.53345E+04 197 beidellite-Na -1.26 -4.04 -2.79 -0.171 0.47585E+04 199 chalcedony -2.79 -3.30 -0.51 -0.170 0.86902E+03 201 montmorillonite-Ca -2.21 -4.40 -2.19 -0.136 0.37409E+04 202 montmorillonite-K -2.16 -4.53 -2.37 -0.145 0.40459E+04 203 montmorillonite-Mg -2.40 -4.75 -2.35 -0.145 0.40062E+04 204 montmorillonite-Na -1.96 -3.96 -2.00 -0.122 0.34151E+04 205 nontronite-Ca 3.28 3.07 -0.21 -0.014 0.36188E+03 206 nontronite-H 2.60 1.31 -1.29 -0.086 0.22018E+04 207 nontronite-K 3.40 2.94 -0.46 -0.030 0.78831E+03 208 nontronite-Mg 3.14 2.72 -0.41 -0.027 0.70777E+03 209 nontronite-Na 3.58 3.51 -0.07 -0.005 0.12104E+03 224 tobermorite 9.84 5.59 -4.25 -1.159 0.72557E+04 233 boehmite 4.43 2.52 -1.91 -0.318 0.32591E+04 235 ferrous-oxide 9.82 6.37 -3.46 -0.864 0.58995E+04 240 silica-amorphous -2.08 -3.30 -1.22 -0.408 0.20892E+04 242 an20ab80 2.08 1.26 -0.82 -0.063 0.14021E+04 243 an25ab75 2.71 1.75 -0.96 -0.074 0.16397E+04 244 an30ab70 3.34 2.24 -1.10 -0.085 0.18856E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 2.0990000 g New total amount of reactant added: 2.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4568E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2.1990000 Water: Moles liquid = 0.5549E+02 kg liquid = 0.9996E+00 Moles total = 0.5548E+02 kg total = 0.9995E+00 Activity = 1.0000 Stoichiometric ionic strength = .1738983E-02 Osmotic coef. = 0.9764 True ionic strength = .2800822E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.51777E-09 -9.2859 0.47587E-09 -9.3225 0.91908E+00 -0.0366 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8604 0.12663E-03 -3.8975 0.91807E+00 -0.0371 4 SO4-- 0.25501E-04 -4.5934 0.19159E-04 -4.7176 0.75130E+00 -0.1242 5 HCO3- 0.10558E-04 -4.9764 0.96951E-05 -5.0134 0.91831E+00 -0.0370 6 HS- 0.38838E-13 -13.4107 0.35657E-13 -13.4479 0.91809E+00 -0.0371 7 Al+++ 0.64170E-25 -25.1927 0.34400E-25 -25.4634 0.53608E+00 -0.2708 8 H4SiO4 0.50313E-03 -3.2983 0.50313E-03 -3.2983 0.10000E+01 0.0000 9 Ca++ 0.14253E-07 -7.8461 0.10694E-07 -7.9708 0.75030E+00 -0.1248 10 Mg++ 0.12050E-09 -9.9190 0.90337E-10 -10.0441 0.74968E+00 -0.1251 11 Fe++ 0.71262E-12 -12.1471 0.53434E-12 -12.2722 0.74983E+00 -0.1250 12 K+ 0.47157E-04 -4.3265 0.43306E-04 -4.3634 0.91835E+00 -0.0370 13 Na+ 0.27159E-02 -2.5661 0.24933E-02 -2.6032 0.91804E+00 -0.0371 14 Mn++ 0.95210E-10 -10.0213 0.71402E-10 -10.1463 0.74994E+00 -0.1250 15 HPO4-- 0.96084E-05 -5.0174 0.72190E-05 -5.1415 0.75132E+00 -0.1242 16 HSiO3- 0.11236E-02 -2.9494 0.10316E-02 -2.9865 0.91807E+00 -0.0371 17 Ca(HSiO3)+ 0.26913E-09 -9.5700 0.24717E-09 -9.6070 0.91839E+00 -0.0370 18 Mg(HSiO3)+ 0.28293E-11 -11.5483 0.25984E-11 -11.5853 0.91839E+00 -0.0370 19 NaHSiO3,aq 0.40850E-04 -4.3888 0.40850E-04 -4.3888 0.10000E+01 0.0000 20 AlO+ 0.21354E-13 -13.6705 0.19611E-13 -13.7075 0.91839E+00 -0.0370 21 AlOH+2 0.62326E-19 -19.2053 0.46749E-19 -19.3302 0.75007E+00 -0.1249 22 HAlO2,aq 0.82467E-08 -8.0837 0.82467E-08 -8.0837 0.10000E+01 0.0000 23 AlO2- 0.42162E-04 -4.3751 0.38695E-04 -4.4123 0.91776E+00 -0.0373 24 CH4,aq 0.17715E-19 -19.7517 0.17706E-19 -19.7519 0.99946E+00 -0.0002 29 CO,aq 0.12688E-18 -18.8966 0.12688E-18 -18.8966 0.10000E+01 0.0000 30 CO2,aq 0.93070E-08 -8.0312 0.93019E-08 -8.0314 0.99946E+00 -0.0002 31 CO3-2 0.25082E-05 -5.6006 0.18837E-05 -5.7250 0.75101E+00 -0.1244 32 CaCO3,aq 0.24673E-09 -9.6078 0.24673E-09 -9.6078 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.28446E-11 -11.5460 0.26125E-11 -11.5829 0.91839E+00 -0.0370 34 CaCl+ 0.23496E-11 -11.6290 0.21579E-11 -11.6660 0.91839E+00 -0.0370 35 CaCl2,aq 0.63621E-16 -16.1964 0.63621E-16 -16.1964 0.10000E+01 0.0000 36 CaOH+ 0.17255E-08 -8.7631 0.15846E-08 -8.8001 0.91839E+00 -0.0370 37 CaSO4,aq 0.63839E-10 -10.1949 0.63839E-10 -10.1949 0.10000E+01 0.0000 38 HCl,aq 0.11334E-13 -13.9456 0.11334E-13 -13.9456 0.10000E+01 0.0000 43 FeCl+ 0.11475E-15 -15.9403 0.10538E-15 -15.9772 0.91839E+00 -0.0370 46 FeO,aq 0.93308E-10 -10.0301 0.93308E-10 -10.0301 0.10000E+01 0.0000 47 FeOH+ 0.40534E-10 -10.3922 0.37226E-10 -10.4292 0.91839E+00 -0.0370 48 HFeO2- 0.22972E-08 -8.6388 0.21090E-08 -8.6759 0.91807E+00 -0.0371 49 FeO+ 0.42863E-14 -14.3679 0.39365E-14 -14.4049 0.91839E+00 -0.0370 51 FeO2- 0.37214E-08 -8.4293 0.34165E-08 -8.4664 0.91807E+00 -0.0371 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.52987E-09 -9.2758 0.52958E-09 -9.2761 0.99946E+00 -0.0002 54 KCl,aq 0.97097E-10 -10.0128 0.97097E-10 -10.0128 0.10000E+01 0.0000 55 KHSO4,aq 0.10566E-17 -17.9761 0.10566E-17 -17.9761 0.10000E+01 0.0000 56 KOH,aq 0.39673E-07 -7.4015 0.39673E-07 -7.4015 0.10000E+01 0.0000 57 KSO4- 0.13923E-07 -7.8563 0.12783E-07 -7.8934 0.91807E+00 -0.0371 58 MgCO3,aq 0.52079E-12 -12.2833 0.52079E-12 -12.2833 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24503E-13 -13.6108 0.22504E-13 -13.6477 0.91839E+00 -0.0370 60 MgCl+ 0.18018E-13 -13.7443 0.16548E-13 -13.7813 0.91839E+00 -0.0370 61 MgOH+ 0.80748E-10 -10.0929 0.74158E-10 -10.1298 0.91839E+00 -0.0370 63 MnO,aq 0.33285E-09 -9.4778 0.33285E-09 -9.4778 0.10000E+01 0.0000 64 MnOH+ 0.50316E-09 -9.2983 0.46210E-09 -9.3353 0.91839E+00 -0.0370 65 MnO2-2 0.67685E-13 -13.1695 0.50832E-13 -13.2939 0.75101E+00 -0.1244 66 HMnO2- 0.57087E-11 -11.2435 0.52409E-11 -11.2806 0.91807E+00 -0.0371 69 MnCl+ 0.59583E-13 -13.2249 0.54720E-13 -13.2619 0.91839E+00 -0.0370 70 MnSO4,aq 0.38769E-12 -12.4115 0.38769E-12 -12.4115 0.10000E+01 0.0000 71 NaCl,aq 0.10309E-06 -6.9868 0.10309E-06 -6.9868 0.10000E+01 0.0000 72 NaOH,aq 0.23023E-05 -5.6378 0.23023E-05 -5.6378 0.10000E+01 0.0000 74 OH- 0.13735E-02 -2.8622 0.12605E-02 -2.8995 0.91776E+00 -0.0373 79 HPO3-2 0.16079E-16 -16.7937 0.12075E-16 -16.9181 0.75101E+00 -0.1244 81 H2PO3- 0.12295E-19 -19.9103 0.11288E-19 -19.9474 0.91807E+00 -0.0371 82 H3PO4,aq 0.10525E-13 -13.9778 0.10525E-13 -13.9778 0.10000E+01 0.0000 83 H2PO4- 0.65592E-07 -7.1832 0.60228E-07 -7.2202 0.91822E+00 -0.0371 84 PO4-3 0.24491E-07 -7.6110 0.13248E-07 -7.8778 0.54095E+00 -0.2668 87 H2P2O7-2 0.37802E-15 -15.4225 0.28390E-15 -15.5468 0.75101E+00 -0.1244 88 HP2O7-3 0.22817E-12 -12.6417 0.12233E-12 -12.9125 0.53614E+00 -0.2707 89 P2O7-4 0.18853E-12 -12.7246 0.63419E-13 -13.1978 0.33638E+00 -0.4732 90 H2S,aq 0.51009E-16 -16.2924 0.50982E-16 -16.2926 0.99946E+00 -0.0002 97 SO3-2 0.18372E-14 -14.7358 0.13834E-14 -14.8590 0.75301E+00 -0.1232 98 HSO3- 0.41965E-16 -16.3771 0.38527E-16 -16.4142 0.91807E+00 -0.0371 99 HSO4- 0.92096E-11 -11.0358 0.84594E-11 -11.0727 0.91855E+00 -0.0369 Charge balance for all species = 0.4569E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.5177671E-09 -.2711421E-02 -.2732304E+01 0.0000 2 H2O 0.1000000E+01 0.5550855E+02 0.9997670E+06 0.0000 3 Cl- 0.1379269E-03 0.1380301E-03 0.4892426E+01 5.4250 4 SO4-- 0.2550081E-04 0.2551517E-04 0.2450449E+01 13.9274 5 HCO3- 0.1055751E-04 0.1307530E-04 0.7976297E+00 4.3091 6 HS- 0.3883811E-13 -.3581039E-09 -.1184041E-04 -4.1253 7 Al+++ 0.6417012E-25 0.4217059E-04 0.1137557E+01 2.5041 8 H4SiO4 0.5031326E-03 0.1667607E-02 0.1602448E+03 -3.2983 9 Ca++ 0.1425328E-07 0.1656363E-07 0.6636803E-03 10.6742 10 Mg++ 0.1205016E-09 0.2046424E-09 0.4974091E-05 8.6009 11 Fe++ 0.7126164E-12 0.6356690E-08 0.3549182E-03 6.3728 12 K+ 0.4715652E-04 0.4721021E-04 0.1845578E+01 4.9591 13 Na+ 0.2715928E-02 0.2759183E-02 0.6341809E+02 6.7193 14 Mn++ 0.9521027E-10 0.9374465E-09 0.5148927E-04 8.4987 15 HPO4-- 0.9608374E-05 0.9698457E-05 0.9306285E+00 13.5035 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3639914E-01 -.2710322E-02 -.3368881E-01 0.0000000E+00 2 H2O 0.5548068E+02 0.5548605E+02 -.5367898E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8644626E-04 0.2550483E-04 0.6094143E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6094179E-04 -.3579588E-09 -.6094143E-04 0.0000000E+00 7 Al+++ 0.7170371E-02 0.4215351E-04 0.7128217E-02 0.0000000E+00 8 H4SiO4 0.2289771E-01 0.1666931E-02 0.2123078E-01 0.0000000E+00 9 Ca++ 0.2543635E-02 0.1655691E-07 0.2543618E-02 0.0000000E+00 10 Mg++ 0.1745238E-02 0.2045594E-09 0.1745238E-02 0.0000000E+00 11 Fe++ 0.1567906E-02 0.6354114E-08 0.1567900E-02 0.0000000E+00 12 K+ 0.4668790E-03 0.4719108E-04 0.4196879E-03 0.0000000E+00 13 Na+ 0.2920352E-02 0.2758065E-02 0.1622869E-03 0.0000000E+00 14 Mn++ 0.3812757E-04 0.9370666E-09 0.3812664E-04 0.0000000E+00 15 HPO4-- 0.1301275E-04 0.9694527E-05 0.3318224E-05 0.0000000E+00 Chg. balance for solid moles: 0.2071E-17 Mass of aqueous solution: 0.999831E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1106E-05 -5.956 0.5556E-03 -3.255 0.2354E-01 0.1766E-03 clinochlore 0.3490E-03 -3.457 0.1940 -0.712 8.219 0.7380E-01 daphnite 0.2161E-03 -3.665 0.1542 -0.812 6.531 0.4672E-01 chlorite-Mn 0.7625E-05 -5.118 0.5406E-02 -2.267 0.2290 0.1723E-02 hematite 0.2438E-03 -3.613 0.3893E-01 -1.410 1.649 0.7379E-02 microcline 0.4197E-03 -3.377 0.1168 -0.932 4.949 0.4563E-01 paragonite 0.1623E-03 -3.790 0.6203E-01 -1.207 2.628 0.2144E-01 stilbite 0.2538E-02 -2.595 1.789 0.253 75.77 0.8343 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.360556 g Volume = 1.031118 cm3 Porosity: 45.1416% V(tot) - V(min): 0.84848E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.1990000 g log = 0.3422 Original solution: 1000.0103000 g Original solution / Rock added: 454.76 (Water/Rock Ratio), log = 2.6578 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1005E-05 1.0073 0.1065E-05 0.1057E-05 CH4,gas 0.2628E-16 1.0129 0.2800E-16 0.2764E-16 H2,gas 0.6901E-06 1.0006 0.7264E-06 0.7260E-06 H2S,gas 0.1419E-14 0.9959 0.1487E-14 0.1493E-14 S2,gas 0.1492E-36 1.0000 0.1570E-36 0.1570E-36 CO,gas 0.1904E-15 1.0000 0.2003E-15 0.2003E-15 SO3,gas 0.1542E-38 1.0000 0.1622E-38 0.1622E-38 SO2,gas 0.4237E-22 1.0000 0.4457E-22 0.4457E-22 HCl,gas 0.1903E-16 1.0000 0.2001E-16 0.2001E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.34 -7.97 -2.658 0.13613E+05 -5.973 3 CH4,gas 4.81 -13.74 -18.55 -4.638 0.31678E+05 -16.553 4 H2,gas 8.29 0.15 -8.14 -4.651 0.13897E+05 -6.139 5 H2S,gas -5.94 -22.77 -16.83 -8.414 0.28733E+05 -14.828 6 S2,gas -7.03 -45.84 -38.80 -5.970 0.66257E+05 -36.804 7 CO,gas 3.51 -14.19 -17.70 -5.446 0.30219E+05 -15.698 8 SO3,gas 17.43 -23.36 -40.79 -10.197 0.69648E+05 -38.790 9 SO2,gas 1.14 -23.21 -24.35 -6.494 0.41579E+05 -22.351 10 HCl,gas 5.48 -13.22 -18.70 -9.349 0.31928E+05 -16.699 11 acmite 7.74 6.42 -1.32 -0.137 0.22469E+04 15 albite-high 0.75 -0.67 -1.42 -0.109 0.24267E+04 16 albite -0.33 -0.67 -0.34 -0.026 0.58601E+03 19 spessartine 24.55 20.61 -3.94 -0.197 0.67282E+04 20 analcite 3.37 2.63 -0.74 -0.083 0.12702E+04 21 andalusite 5.06 1.71 -3.35 -0.335 0.57243E+04 22 andradite 39.09 34.73 -4.36 -0.227 0.74489E+04 26 annite 20.21 16.69 -3.52 -0.196 0.60148E+04 27 phlogopite 27.15 23.37 -3.78 -0.210 0.64469E+04 29 anorthite 12.80 9.09 -3.71 -0.286 0.63380E+04 35 aragonite 0.99 -3.66 -4.65 -1.549 0.79363E+04 36 brucite 12.58 8.60 -3.98 -0.795 0.67884E+04 37 calcite 0.83 -3.66 -4.49 -1.498 0.76750E+04 38 carnegieite-low 9.06 5.93 -3.14 -0.448 0.53606E+04 39 carnegieite-high 10.13 5.93 -4.21 -0.601 0.71874E+04 40 carpholite-Mg 8.65 7.01 -1.64 -0.109 0.27967E+04 41 carpholite-Fe 6.78 4.78 -2.00 -0.133 0.34124E+04 42 celadonite 5.40 2.87 -2.53 -0.149 0.43194E+04 43 celadonite-Fe 3.94 0.64 -3.29 -0.194 0.56248E+04 44 chrysotile 23.94 19.21 -4.73 -0.394 0.80786E+04 50 chloritoid-Mg 13.26 10.31 -2.95 -0.197 0.50379E+04 51 chloritoid-Fe 9.24 8.08 -1.16 -0.077 0.19738E+04 52 chloritoid-Mn 11.46 10.21 -1.25 -0.084 0.21422E+04 54 coesite -2.37 -3.30 -0.93 -0.310 0.15862E+04 59 corundum 8.43 5.01 -3.43 -0.311 0.58485E+04 61 cristobalite -2.55 -3.30 -0.75 -0.250 0.12791E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.50 -0.39 -0.065 0.66932E+03 67 diopside 16.22 12.68 -3.54 -0.354 0.60394E+04 68 hedenbergite 14.24 10.45 -3.79 -0.379 0.64782E+04 75 epidote 24.78 22.76 -2.01 -0.098 0.34402E+04 76 clinozoisite 22.92 18.97 -3.96 -0.180 0.67538E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57741E+04 78 fayalite 14.08 9.45 -4.63 -0.662 0.79083E+04 83 gibbsite 4.10 2.50 -1.59 -0.228 0.27205E+04 87 greenalite 16.19 12.52 -3.67 -0.306 0.62704E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.63 -1.62 -0.162 0.27732E+04 97 kalsilite 7.62 4.16 -3.46 -0.494 0.59000E+04 98 kaolinite -1.27 -1.59 -0.32 -0.029 0.53837E+03 99 kyanite 4.93 1.71 -3.22 -0.322 0.55011E+04 101 laumontite 2.97 2.49 -0.49 -0.032 0.82889E+03 102 lawsonite 9.68 9.09 -0.59 -0.040 0.10119E+04 103 leucite 4.17 0.87 -3.30 -0.330 0.56366E+04 105 lizardite 23.29 19.21 -4.08 -0.340 0.69689E+04 107 magnetite 20.13 18.97 -1.16 -0.095 0.19846E+04 108 minnesotaite 10.46 5.93 -4.54 -0.267 0.77442E+04 113 margarite 17.45 14.09 -3.36 -0.134 0.57335E+04 120 muscovite 2.68 2.58 -0.10 -0.006 0.17552E+03 122 nepheline 8.38 5.93 -2.45 -0.350 0.41885E+04 134 phlogopite-Na 29.73 25.13 -4.60 -0.256 0.78549E+04 136 prehnite 19.47 16.46 -3.00 -0.177 0.51305E+04 137 prehnite-Fe 22.59 20.26 -2.33 -0.140 0.39792E+04 138 pumpellyite-Fe 46.47 41.80 -4.67 -0.104 0.79747E+04 145 pyroxmangite 7.42 5.20 -2.22 -0.443 0.37831E+04 146 pyrophyllite -6.10 -8.19 -2.09 -0.130 0.35636E+04 147 quartz -2.98 -3.30 -0.32 -0.105 0.54011E+03 151 rhodochrosite -0.96 -5.84 -4.88 -1.626 0.83302E+04 152 rhodonite 7.46 5.20 -2.26 -0.452 0.38623E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.71 -3.61 -0.361 0.61665E+04 164 stilpnomelane-Fe 13.18 12.97 -0.21 -0.006 0.36536E+03 165 stilpnomelane-Mg 27.60 24.11 -3.49 -0.104 0.59602E+04 168 sudoite 21.22 17.32 -3.89 -0.126 0.66471E+04 171 talc 16.55 12.61 -3.94 -0.232 0.67342E+04 174 tephroite 18.11 13.70 -4.41 -0.631 0.75364E+04 177 topaz-H 4.67 1.71 -2.96 -0.269 0.50502E+04 178 tridymite -2.61 -3.30 -0.68 -0.228 0.11674E+04 187 wairakite 4.06 2.49 -1.57 -0.092 0.26797E+04 188 walstromite 11.53 7.38 -4.15 -0.830 0.70895E+04 189 wollastonite 10.48 7.38 -3.11 -0.621 0.53033E+04 190 pseudo-wollastonite 11.02 7.38 -3.64 -0.729 0.62220E+04 191 zoisite 22.96 18.97 -4.00 -0.182 0.68264E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.51 -2.95 -0.182 0.50360E+04 194 beidellite-H -2.24 -6.27 -4.03 -0.257 0.68797E+04 195 beidellite-K -1.44 -4.63 -3.20 -0.196 0.54618E+04 196 beidellite-Mg -1.71 -4.85 -3.14 -0.195 0.53687E+04 197 beidellite-Na -1.26 -4.05 -2.80 -0.171 0.47739E+04 199 chalcedony -2.79 -3.30 -0.50 -0.168 0.86042E+03 201 montmorillonite-Ca -2.21 -4.41 -2.20 -0.136 0.37528E+04 202 montmorillonite-K -2.16 -4.54 -2.38 -0.145 0.40564E+04 203 montmorillonite-Mg -2.40 -4.75 -2.35 -0.146 0.40166E+04 204 montmorillonite-Na -1.96 -3.96 -2.00 -0.122 0.34067E+04 205 nontronite-Ca 3.28 3.08 -0.20 -0.013 0.34025E+03 206 nontronite-H 2.60 1.32 -1.28 -0.086 0.21797E+04 207 nontronite-K 3.40 2.96 -0.45 -0.029 0.76526E+03 208 nontronite-Mg 3.14 2.74 -0.40 -0.026 0.68463E+03 209 nontronite-Na 3.58 3.54 -0.05 -0.003 0.79068E+02 224 tobermorite 9.84 5.59 -4.25 -1.158 0.72495E+04 233 boehmite 4.43 2.50 -1.93 -0.321 0.32878E+04 235 ferrous-oxide 9.82 6.37 -3.45 -0.863 0.58931E+04 240 silica-amorphous -2.08 -3.30 -1.22 -0.406 0.20806E+04 242 an20ab80 2.08 1.28 -0.80 -0.061 0.13648E+04 243 an25ab75 2.71 1.77 -0.94 -0.072 0.16074E+04 244 an30ab70 3.34 2.26 -1.09 -0.084 0.18584E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 2.1990000 g New total amount of reactant added: 2.2990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4568E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2.2990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9996E+00 Moles total = 0.5548E+02 kg total = 0.9995E+00 Activity = 1.0000 Stoichiometric ionic strength = .1799752E-02 Osmotic coef. = 0.9761 True ionic strength = .2915166E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.49934E-09 -9.3016 0.45837E-09 -9.3388 0.91796E+00 -0.0372 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8604 0.12646E-03 -3.8980 0.91690E+00 -0.0377 4 SO4-- 0.25502E-04 -4.5934 0.19064E-04 -4.7198 0.74756E+00 -0.1264 5 HCO3- 0.10473E-04 -4.9799 0.96057E-05 -5.0175 0.91715E+00 -0.0376 6 HS- 0.39787E-13 -13.4003 0.36482E-13 -13.4379 0.91693E+00 -0.0377 7 Al+++ 0.55903E-25 -25.2526 0.29631E-25 -25.5283 0.53004E+00 -0.2757 8 H4SiO4 0.50867E-03 -3.2936 0.50867E-03 -3.2936 0.10000E+01 0.0000 9 Ca++ 0.13252E-07 -7.8777 0.98929E-08 -8.0047 0.74653E+00 -0.1270 10 Mg++ 0.11329E-09 -9.9458 0.84501E-10 -10.0731 0.74588E+00 -0.1273 11 Fe++ 0.66996E-12 -12.1739 0.49982E-12 -12.3012 0.74604E+00 -0.1272 12 K+ 0.45661E-04 -4.3405 0.41881E-04 -4.3780 0.91720E+00 -0.0375 13 Na+ 0.28308E-02 -2.5481 0.25955E-02 -2.5858 0.91688E+00 -0.0377 14 Mn++ 0.89511E-10 -10.0481 0.66789E-10 -10.1753 0.74615E+00 -0.1272 15 HPO4-- 0.10459E-04 -4.9805 0.78192E-05 -5.1068 0.74758E+00 -0.1263 16 HSiO3- 0.11809E-02 -2.9278 0.10827E-02 -2.9655 0.91690E+00 -0.0377 17 Ca(HSiO3)+ 0.26164E-09 -9.5823 0.23999E-09 -9.6198 0.91724E+00 -0.0375 18 Mg(HSiO3)+ 0.27813E-11 -11.5557 0.25511E-11 -11.5933 0.91724E+00 -0.0375 19 NaHSiO3,aq 0.44634E-04 -4.3503 0.44634E-04 -4.3503 0.10000E+01 0.0000 20 AlO+ 0.19850E-13 -13.7022 0.18207E-13 -13.7398 0.91724E+00 -0.0375 21 AlOH+2 0.56017E-19 -19.2517 0.41805E-19 -19.3788 0.74629E+00 -0.1271 22 HAlO2,aq 0.79485E-08 -8.0997 0.79485E-08 -8.0997 0.10000E+01 0.0000 23 AlO2- 0.42244E-04 -4.3742 0.38720E-04 -4.4121 0.91658E+00 -0.0378 24 CH4,aq 0.18048E-19 -19.7436 0.18038E-19 -19.7438 0.99944E+00 -0.0002 29 CO,aq 0.12308E-18 -18.9098 0.12308E-18 -18.9098 0.10000E+01 0.0000 30 CO2,aq 0.88822E-08 -8.0515 0.88772E-08 -8.0517 0.99944E+00 -0.0002 31 CO3-2 0.25930E-05 -5.5862 0.19376E-05 -5.7127 0.74726E+00 -0.1265 32 CaCO3,aq 0.23477E-09 -9.6294 0.23477E-09 -9.6294 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.26105E-11 -11.5833 0.23944E-11 -11.6208 0.91724E+00 -0.0375 34 CaCl+ 0.21735E-11 -11.6628 0.19936E-11 -11.7004 0.91724E+00 -0.0375 35 CaCl2,aq 0.58702E-16 -16.2313 0.58702E-16 -16.2313 0.10000E+01 0.0000 36 CaOH+ 0.16592E-08 -8.7801 0.15219E-08 -8.8176 0.91724E+00 -0.0375 37 CaSO4,aq 0.58763E-10 -10.2309 0.58763E-10 -10.2309 0.10000E+01 0.0000 38 HCl,aq 0.10903E-13 -13.9624 0.10903E-13 -13.9624 0.10000E+01 0.0000 43 FeCl+ 0.10733E-15 -15.9693 0.98448E-16 -16.0068 0.91724E+00 -0.0375 46 FeO,aq 0.94073E-10 -10.0265 0.94073E-10 -10.0265 0.10000E+01 0.0000 47 FeOH+ 0.39412E-10 -10.4044 0.36150E-10 -10.4419 0.91724E+00 -0.0375 48 HFeO2- 0.24076E-08 -8.6184 0.22075E-08 -8.6561 0.91690E+00 -0.0377 49 FeO+ 0.41338E-14 -14.3836 0.37917E-14 -14.4212 0.91724E+00 -0.0375 51 FeO2- 0.38684E-08 -8.4125 0.35470E-08 -8.4501 0.91690E+00 -0.0377 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.53860E-09 -9.2687 0.53830E-09 -9.2690 0.99944E+00 -0.0002 54 KCl,aq 0.93780E-10 -10.0279 0.93780E-10 -10.0279 0.10000E+01 0.0000 55 KHSO4,aq 0.97932E-18 -18.0091 0.97932E-18 -18.0091 0.10000E+01 0.0000 56 KOH,aq 0.39832E-07 -7.3998 0.39832E-07 -7.3998 0.10000E+01 0.0000 57 KSO4- 0.13416E-07 -7.8724 0.12301E-07 -7.9101 0.91690E+00 -0.0377 58 MgCO3,aq 0.50108E-12 -12.3001 0.50108E-12 -12.3001 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22738E-13 -13.6433 0.20856E-13 -13.6808 0.91724E+00 -0.0375 60 MgCl+ 0.16854E-13 -13.7733 0.15459E-13 -13.8108 0.91724E+00 -0.0375 61 MgOH+ 0.78514E-10 -10.1051 0.72016E-10 -10.1426 0.91724E+00 -0.0375 63 MnO,aq 0.33558E-09 -9.4742 0.33558E-09 -9.4742 0.10000E+01 0.0000 64 MnOH+ 0.48924E-09 -9.3105 0.44875E-09 -9.3480 0.91724E+00 -0.0375 65 MnO2-2 0.73920E-13 -13.1312 0.55237E-13 -13.2578 0.74726E+00 -0.1265 66 HMnO2- 0.59828E-11 -11.2231 0.54857E-11 -11.2608 0.91690E+00 -0.0377 69 MnCl+ 0.55732E-13 -13.2539 0.51120E-13 -13.2914 0.91724E+00 -0.0375 70 MnSO4,aq 0.36085E-12 -12.4427 0.36085E-12 -12.4427 0.10000E+01 0.0000 71 NaCl,aq 0.10718E-06 -6.9699 0.10718E-06 -6.9699 0.10000E+01 0.0000 72 NaOH,aq 0.24881E-05 -5.6041 0.24881E-05 -5.6041 0.10000E+01 0.0000 74 OH- 0.14277E-02 -2.8454 0.13086E-02 -2.8832 0.91658E+00 -0.0378 79 HPO3-2 0.17791E-16 -16.7498 0.13295E-16 -16.8763 0.74726E+00 -0.1265 81 H2PO3- 0.13055E-19 -19.8842 0.11970E-19 -19.9219 0.91690E+00 -0.0377 82 H3PO4,aq 0.10576E-13 -13.9757 0.10576E-13 -13.9757 0.10000E+01 0.0000 83 H2PO4- 0.68518E-07 -7.1642 0.62836E-07 -7.2018 0.91706E+00 -0.0376 84 PO4-3 0.27844E-07 -7.5553 0.14898E-07 -7.8269 0.53504E+00 -0.2716 87 H2P2O7-2 0.41353E-15 -15.3835 0.30902E-15 -15.5100 0.74726E+00 -0.1265 88 HP2O7-3 0.26078E-12 -12.5837 0.13824E-12 -12.8594 0.53011E+00 -0.2756 89 P2O7-4 0.22564E-12 -12.6466 0.74402E-13 -13.1284 0.32974E+00 -0.4818 90 H2S,aq 0.50271E-16 -16.2987 0.50243E-16 -16.2989 0.99944E+00 -0.0002 97 SO3-2 0.18674E-14 -14.7288 0.13993E-14 -14.8541 0.74932E+00 -0.1253 98 HSO3- 0.40936E-16 -16.3879 0.37534E-16 -16.4256 0.91690E+00 -0.0377 99 HSO4- 0.88380E-11 -11.0536 0.81080E-11 -11.0911 0.91740E+00 -0.0374 Charge balance for all species = 0.4570E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4993357E-09 -.2827320E-02 -.2849071E+01 0.0000 2 H2O 0.1000000E+01 0.5550854E+02 0.9997580E+06 0.0000 3 Cl- 0.1379253E-03 0.1380326E-03 0.4892470E+01 5.4408 4 SO4-- 0.2550178E-04 0.2551564E-04 0.2450472E+01 13.9578 5 HCO3- 0.1047343E-04 0.1307553E-04 0.7976368E+00 4.3213 6 HS- 0.3978732E-13 -.3742971E-09 -.1237572E-04 -4.0991 7 Al+++ 0.5590289E-25 0.4225206E-04 0.1139745E+01 2.4881 8 H4SiO4 0.5086676E-03 0.1734165E-02 0.1666391E+03 -3.2936 9 Ca++ 0.1325179E-07 0.1547093E-07 0.6198922E-03 10.6729 10 Mg++ 0.1132899E-09 0.1951261E-09 0.4742744E-05 8.6044 11 Fe++ 0.6699632E-12 0.6613639E-08 0.3692614E-03 6.3764 12 K+ 0.4566136E-04 0.4571470E-04 0.1787098E+01 4.9608 13 Na+ 0.2830824E-02 0.2878053E-02 0.6614965E+02 6.7530 14 Mn++ 0.8951115E-10 0.9208065E-09 0.5057487E-04 8.5023 15 HPO4-- 0.1045928E-04 0.1055565E-04 0.1012872E+01 13.5707 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3805499E-01 -.2826124E-02 -.3522886E-01 0.0000000E+00 2 H2O 0.5547943E+02 0.5548506E+02 -.5626820E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8921760E-04 0.2550484E-04 0.6371275E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6371313E-04 -.3741388E-09 -.6371275E-04 0.0000000E+00 7 Al+++ 0.7496445E-02 0.4223419E-04 0.7454211E-02 0.0000000E+00 8 H4SiO4 0.2393899E-01 0.1733431E-02 0.2220556E-01 0.0000000E+00 9 Ca++ 0.2658649E-02 0.1546439E-07 0.2658634E-02 0.0000000E+00 10 Mg++ 0.1824603E-02 0.1950436E-09 0.1824603E-02 0.0000000E+00 11 Fe++ 0.1639207E-02 0.6610841E-08 0.1639200E-02 0.0000000E+00 12 K+ 0.4881104E-03 0.4569536E-04 0.4424150E-03 0.0000000E+00 13 Na+ 0.3045876E-02 0.2876836E-02 0.1690406E-03 0.0000000E+00 14 Mn++ 0.3986143E-04 0.9204170E-09 0.3986051E-04 0.0000000E+00 15 HPO4-- 0.1360451E-04 0.1055118E-04 0.3053327E-05 0.0000000E+00 Chg. balance for solid moles: 0.1479E-17 Mass of aqueous solution: 0.999822E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2.2990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1018E-05 -5.992 0.5112E-03 -3.291 0.2071E-01 0.1625E-03 clinochlore 0.3649E-03 -3.438 0.2028 -0.693 8.216 0.7715E-01 daphnite 0.2259E-03 -3.646 0.1612 -0.793 6.529 0.4884E-01 chlorite-Mn 0.7972E-05 -5.098 0.5652E-02 -2.248 0.2290 0.1801E-02 hematite 0.2549E-03 -3.594 0.4070E-01 -1.390 1.649 0.7714E-02 microcline 0.4424E-03 -3.354 0.1231 -0.910 4.988 0.4810E-01 paragonite 0.1690E-03 -3.772 0.6461E-01 -1.190 2.617 0.2233E-01 stilbite 0.2654E-02 -2.576 1.870 0.272 75.75 0.8722 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.468634 g Volume = 1.078312 cm3 Porosity: 43.8262% V(tot) - V(min): 0.84129E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.2990000 g log = 0.3615 Original solution: 1000.0103000 g Original solution / Rock added: 434.98 (Water/Rock Ratio), log = 2.6385 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.9590E-06 1.0073 0.1016E-05 0.1009E-05 CH4,gas 0.2677E-16 1.0129 0.2852E-16 0.2816E-16 H2,gas 0.7015E-06 1.0006 0.7383E-06 0.7379E-06 H2S,gas 0.1399E-14 0.9959 0.1465E-14 0.1471E-14 S2,gas 0.1403E-36 1.0000 0.1475E-36 0.1475E-36 CO,gas 0.1847E-15 1.0000 0.1943E-15 0.1943E-15 SO3,gas 0.1424E-38 1.0000 0.1497E-38 0.1497E-38 SO2,gas 0.3976E-22 1.0000 0.4182E-22 0.4182E-22 HCl,gas 0.1830E-16 1.0000 0.1925E-16 0.1925E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.28814E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.36 -7.99 -2.664 0.13648E+05 -5.993 3 CH4,gas 4.81 -13.74 -18.54 -4.636 0.31665E+05 -16.545 4 H2,gas 8.29 0.16 -8.13 -4.647 0.13885E+05 -6.132 5 H2S,gas -5.94 -22.78 -16.83 -8.417 0.28744E+05 -14.834 6 S2,gas -7.03 -45.86 -38.83 -5.974 0.66303E+05 -36.831 7 CO,gas 3.51 -14.20 -17.71 -5.450 0.30242E+05 -15.711 8 SO3,gas 17.43 -23.40 -40.82 -10.206 0.69707E+05 -38.825 9 SO2,gas 1.14 -23.24 -24.38 -6.501 0.41626E+05 -22.379 10 HCl,gas 5.48 -13.24 -18.72 -9.358 0.31956E+05 -16.716 11 acmite 7.74 6.46 -1.27 -0.132 0.21731E+04 15 albite-high 0.75 -0.64 -1.39 -0.107 0.23721E+04 16 albite -0.33 -0.64 -0.31 -0.024 0.53140E+03 19 spessartine 24.55 20.60 -3.95 -0.197 0.67403E+04 20 analcite 3.37 2.65 -0.72 -0.080 0.12237E+04 21 andalusite 5.06 1.68 -3.38 -0.338 0.57708E+04 22 andradite 39.09 34.74 -4.35 -0.226 0.74312E+04 26 annite 20.21 16.70 -3.51 -0.195 0.59966E+04 27 phlogopite 27.15 23.38 -3.77 -0.209 0.64288E+04 29 anorthite 12.80 9.06 -3.74 -0.287 0.63786E+04 35 aragonite 0.99 -3.68 -4.67 -1.557 0.79732E+04 36 brucite 12.58 8.60 -3.97 -0.794 0.67824E+04 37 calcite 0.83 -3.68 -4.52 -1.506 0.77119E+04 38 carnegieite-low 9.06 5.95 -3.12 -0.445 0.53222E+04 39 carnegieite-high 10.13 5.95 -4.19 -0.598 0.71491E+04 40 carpholite-Mg 8.65 6.99 -1.66 -0.110 0.28290E+04 41 carpholite-Fe 6.78 4.77 -2.02 -0.134 0.34447E+04 42 celadonite 5.40 2.88 -2.52 -0.148 0.43053E+04 43 celadonite-Fe 3.94 0.65 -3.29 -0.193 0.56106E+04 44 chrysotile 23.94 19.23 -4.71 -0.393 0.80442E+04 50 chloritoid-Mg 13.26 10.29 -2.97 -0.198 0.50783E+04 51 chloritoid-Fe 9.24 8.06 -1.18 -0.079 0.20142E+04 52 chloritoid-Mn 11.46 10.18 -1.28 -0.085 0.21826E+04 54 coesite -2.37 -3.29 -0.92 -0.308 0.15781E+04 59 corundum 8.43 4.98 -3.46 -0.314 0.59031E+04 61 cristobalite -2.55 -3.29 -0.74 -0.248 0.12710E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.49 -0.41 -0.068 0.69662E+03 67 diopside 16.22 12.69 -3.53 -0.353 0.60193E+04 68 hedenbergite 14.24 10.46 -3.78 -0.378 0.64581E+04 75 epidote 24.78 22.74 -2.04 -0.099 0.34749E+04 76 clinozoisite 22.92 18.93 -3.99 -0.181 0.68158E+04 77 epidote-Fe 29.94 26.55 -3.39 -0.176 0.57814E+04 78 fayalite 14.08 9.46 -4.62 -0.660 0.78881E+04 83 gibbsite 4.10 2.49 -1.61 -0.230 0.27478E+04 87 greenalite 16.19 12.54 -3.65 -0.304 0.62360E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.65 -1.60 -0.160 0.27267E+04 97 kalsilite 7.62 4.16 -3.46 -0.495 0.59163E+04 98 kaolinite -1.27 -1.61 -0.34 -0.031 0.57675E+03 99 kyanite 4.93 1.68 -3.25 -0.325 0.55476E+04 101 laumontite 2.97 2.47 -0.50 -0.033 0.85323E+03 102 lawsonite 9.68 9.06 -0.62 -0.041 0.10525E+04 103 leucite 4.17 0.86 -3.31 -0.331 0.56447E+04 105 lizardite 23.29 19.23 -4.06 -0.338 0.69345E+04 107 magnetite 20.13 18.97 -1.16 -0.095 0.19786E+04 108 minnesotaite 10.46 5.95 -4.51 -0.265 0.76936E+04 113 margarite 17.45 14.04 -3.41 -0.137 0.58287E+04 120 muscovite 2.68 2.54 -0.13 -0.008 0.23013E+03 122 nepheline 8.38 5.95 -2.43 -0.347 0.41501E+04 134 phlogopite-Na 29.73 25.17 -4.56 -0.253 0.77821E+04 136 prehnite 19.47 16.44 -3.03 -0.178 0.51652E+04 137 prehnite-Fe 22.59 20.25 -2.33 -0.140 0.39865E+04 138 pumpellyite-Fe 46.47 41.75 -4.72 -0.105 0.80652E+04 145 pyroxmangite 7.42 5.21 -2.21 -0.441 0.37689E+04 146 pyrophyllite -6.10 -8.20 -2.10 -0.131 0.35857E+04 147 quartz -2.98 -3.29 -0.31 -0.104 0.53199E+03 151 rhodochrosite -0.96 -5.85 -4.90 -1.632 0.83588E+04 152 rhodonite 7.46 5.21 -2.25 -0.451 0.38482E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.68 -3.64 -0.364 0.62130E+04 164 stilpnomelane-Fe 13.18 12.99 -0.19 -0.006 0.32331E+03 165 stilpnomelane-Mg 27.60 24.13 -3.47 -0.103 0.59181E+04 168 sudoite 21.22 17.28 -3.94 -0.127 0.67199E+04 171 talc 16.55 12.64 -3.91 -0.230 0.66836E+04 174 tephroite 18.11 13.71 -4.40 -0.629 0.75161E+04 177 topaz-H 4.67 1.68 -2.98 -0.271 0.50967E+04 178 tridymite -2.61 -3.29 -0.68 -0.226 0.11593E+04 187 wairakite 4.06 2.47 -1.58 -0.093 0.27040E+04 188 walstromite 11.53 7.38 -4.15 -0.830 0.70835E+04 189 wollastonite 10.48 7.38 -3.10 -0.620 0.52974E+04 190 pseudo-wollastonite 11.02 7.38 -3.64 -0.728 0.62160E+04 191 zoisite 22.96 18.93 -4.03 -0.183 0.68883E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.53 -2.97 -0.184 0.50702E+04 194 beidellite-H -2.24 -6.29 -4.05 -0.258 0.69135E+04 195 beidellite-K -1.44 -4.65 -3.22 -0.197 0.54947E+04 196 beidellite-Mg -1.71 -4.87 -3.16 -0.196 0.54016E+04 197 beidellite-Na -1.26 -4.06 -2.80 -0.172 0.47887E+04 199 chalcedony -2.79 -3.29 -0.50 -0.166 0.85231E+03 201 montmorillonite-Ca -2.21 -4.42 -2.20 -0.136 0.37643E+04 202 montmorillonite-K -2.16 -4.54 -2.38 -0.146 0.40666E+04 203 montmorillonite-Mg -2.40 -4.76 -2.36 -0.146 0.40267E+04 204 montmorillonite-Na -1.96 -3.95 -1.99 -0.122 0.33988E+04 205 nontronite-Ca 3.28 3.09 -0.19 -0.012 0.31984E+03 206 nontronite-H 2.60 1.33 -1.26 -0.085 0.21590E+04 207 nontronite-K 3.40 2.97 -0.44 -0.028 0.74352E+03 208 nontronite-Mg 3.14 2.75 -0.39 -0.025 0.66286E+03 209 nontronite-Na 3.58 3.56 -0.02 -0.001 0.39303E+02 224 tobermorite 9.84 5.60 -4.24 -1.157 0.72432E+04 233 boehmite 4.43 2.49 -1.94 -0.324 0.33151E+04 235 ferrous-oxide 9.82 6.38 -3.45 -0.862 0.58871E+04 240 silica-amorphous -2.08 -3.29 -1.21 -0.405 0.20725E+04 242 an20ab80 2.08 1.30 -0.78 -0.060 0.13292E+04 243 an25ab75 2.71 1.79 -0.92 -0.071 0.15766E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18323E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 2.2990000 g New total amount of reactant added: 2.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4568E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2.3990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9996E+00 Moles total = 0.5548E+02 kg total = 0.9995E+00 Activity = 1.0000 Stoichiometric ionic strength = .1860635E-02 Osmotic coef. = 0.9757 True ionic strength = .3029476E-02 Chg. balance for total moles = 0.4568E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.48231E-09 -9.3167 0.44221E-09 -9.3544 0.91685E+00 -0.0377 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13792E-03 -3.8604 0.12631E-03 -3.8986 0.91576E+00 -0.0382 4 SO4-- 0.25503E-04 -4.5934 0.18972E-04 -4.7219 0.74392E+00 -0.1285 5 HCO3- 0.10391E-04 -4.9834 0.95182E-05 -5.0214 0.91602E+00 -0.0381 6 HS- 0.40725E-13 -13.3901 0.37296E-13 -13.4283 0.91579E+00 -0.0382 7 Al+++ 0.49004E-25 -25.3098 0.25689E-25 -25.5903 0.52421E+00 -0.2805 8 H4SiO4 0.51395E-03 -3.2891 0.51395E-03 -3.2891 0.10000E+01 0.0000 9 Ca++ 0.12369E-07 -7.9077 0.91884E-08 -8.0368 0.74286E+00 -0.1291 10 Mg++ 0.10680E-09 -9.9714 0.79269E-10 -10.1009 0.74219E+00 -0.1295 11 Fe++ 0.63160E-12 -12.1996 0.46887E-12 -12.3289 0.74235E+00 -0.1294 12 K+ 0.44288E-04 -4.3537 0.40571E-04 -4.3918 0.91607E+00 -0.0381 13 Na+ 0.29455E-02 -2.5308 0.26973E-02 -2.5691 0.91574E+00 -0.0382 14 Mn++ 0.84385E-10 -10.0737 0.62654E-10 -10.2031 0.74247E+00 -0.1293 15 HPO4-- 0.11332E-04 -4.9457 0.84304E-05 -5.0742 0.74394E+00 -0.1285 16 HSiO3- 0.12383E-02 -2.9072 0.11340E-02 -2.9454 0.91576E+00 -0.0382 17 Ca(HSiO3)+ 0.25482E-09 -9.5938 0.23345E-09 -9.6318 0.91611E+00 -0.0381 18 Mg(HSiO3)+ 0.27359E-11 -11.5629 0.25064E-11 -11.6010 0.91611E+00 -0.0381 19 NaHSiO3,aq 0.48579E-04 -4.3136 0.48579E-04 -4.3136 0.10000E+01 0.0000 20 AlO+ 0.18512E-13 -13.7326 0.16959E-13 -13.7706 0.91611E+00 -0.0381 21 AlOH+2 0.50588E-19 -19.2960 0.37567E-19 -19.4252 0.74261E+00 -0.1292 22 HAlO2,aq 0.76742E-08 -8.1150 0.76742E-08 -8.1150 0.10000E+01 0.0000 23 AlO2- 0.42329E-04 -4.3734 0.38750E-04 -4.4117 0.91543E+00 -0.0384 24 CH4,aq 0.18371E-19 -19.7359 0.18360E-19 -19.7361 0.99942E+00 -0.0003 29 CO,aq 0.11952E-18 -18.9226 0.11952E-18 -18.9226 0.10000E+01 0.0000 30 CO2,aq 0.84912E-08 -8.0710 0.84863E-08 -8.0713 0.99942E+00 -0.0003 31 CO3-2 0.26763E-05 -5.5725 0.19901E-05 -5.7011 0.74361E+00 -0.1287 32 CaCO3,aq 0.22396E-09 -9.6498 0.22396E-09 -9.6498 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.24055E-11 -11.6188 0.22037E-11 -11.6569 0.91611E+00 -0.0381 34 CaCl+ 0.20187E-11 -11.6949 0.18493E-11 -11.7330 0.91611E+00 -0.0381 35 CaCl2,aq 0.54386E-16 -16.2645 0.54386E-16 -16.2645 0.10000E+01 0.0000 36 CaOH+ 0.15993E-08 -8.7961 0.14651E-08 -8.8341 0.91611E+00 -0.0381 37 CaSO4,aq 0.54315E-10 -10.2651 0.54315E-10 -10.2651 0.10000E+01 0.0000 38 HCl,aq 0.10506E-13 -13.9786 0.10506E-13 -13.9786 0.10000E+01 0.0000 43 FeCl+ 0.10068E-15 -15.9970 0.92237E-16 -16.0351 0.91611E+00 -0.0381 46 FeO,aq 0.94814E-10 -10.0231 0.94814E-10 -10.0231 0.10000E+01 0.0000 47 FeOH+ 0.38370E-10 -10.4160 0.35151E-10 -10.4541 0.91611E+00 -0.0381 48 HFeO2- 0.25183E-08 -8.5989 0.23062E-08 -8.6371 0.91576E+00 -0.0382 49 FeO+ 0.39930E-14 -14.3987 0.36580E-14 -14.4368 0.91611E+00 -0.0381 51 FeO2- 0.40147E-08 -8.3963 0.36766E-08 -8.4346 0.91576E+00 -0.0382 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.54713E-09 -9.2619 0.54682E-09 -9.2622 0.99942E+00 -0.0003 54 KCl,aq 0.90734E-10 -10.0422 0.90734E-10 -10.0422 0.10000E+01 0.0000 55 KHSO4,aq 0.91084E-18 -18.0406 0.91084E-18 -18.0406 0.10000E+01 0.0000 56 KOH,aq 0.39996E-07 -7.3980 0.39996E-07 -7.3980 0.10000E+01 0.0000 57 KSO4- 0.12949E-07 -7.8878 0.11859E-07 -7.9260 0.91576E+00 -0.0382 58 MgCO3,aq 0.48279E-12 -12.3162 0.48279E-12 -12.3162 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21161E-13 -13.6745 0.19386E-13 -13.7125 0.91611E+00 -0.0381 60 MgCl+ 0.15810E-13 -13.8011 0.14483E-13 -13.8391 0.91611E+00 -0.0381 61 MgOH+ 0.76438E-10 -10.1167 0.70025E-10 -10.1547 0.91611E+00 -0.0381 63 MnO,aq 0.33822E-09 -9.4708 0.33822E-09 -9.4708 0.10000E+01 0.0000 64 MnOH+ 0.47630E-09 -9.3221 0.43635E-09 -9.3602 0.91611E+00 -0.0381 65 MnO2-2 0.80439E-13 -13.0945 0.59815E-13 -13.2232 0.74361E+00 -0.1287 66 HMnO2- 0.62581E-11 -11.2036 0.57309E-11 -11.2418 0.91576E+00 -0.0382 69 MnCl+ 0.52280E-13 -13.2817 0.47894E-13 -13.3197 0.91611E+00 -0.0381 70 MnSO4,aq 0.33687E-12 -12.4725 0.33687E-12 -12.4725 0.10000E+01 0.0000 71 NaCl,aq 0.11124E-06 -6.9537 0.11124E-06 -6.9537 0.10000E+01 0.0000 72 NaOH,aq 0.26802E-05 -5.5718 0.26802E-05 -5.5718 0.10000E+01 0.0000 74 OH- 0.14817E-02 -2.8292 0.13564E-02 -2.8676 0.91543E+00 -0.0384 79 HPO3-2 0.19581E-16 -16.7082 0.14561E-16 -16.8368 0.74361E+00 -0.1287 81 H2PO3- 0.13811E-19 -19.8598 0.12648E-19 -19.8980 0.91576E+00 -0.0382 82 H3PO4,aq 0.10613E-13 -13.9741 0.10613E-13 -13.9741 0.10000E+01 0.0000 83 H2PO4- 0.71359E-07 -7.1466 0.65360E-07 -7.1847 0.91593E+00 -0.0381 84 PO4-3 0.31453E-07 -7.5023 0.16649E-07 -7.7786 0.52932E+00 -0.2763 87 H2P2O7-2 0.44962E-15 -15.3472 0.33434E-15 -15.4758 0.74361E+00 -0.1287 88 HP2O7-3 0.29571E-12 -12.5291 0.15503E-12 -12.8096 0.52427E+00 -0.2804 89 P2O7-4 0.26746E-12 -12.5727 0.86489E-13 -13.0630 0.32337E+00 -0.4903 90 H2S,aq 0.49582E-16 -16.3047 0.49553E-16 -16.3049 0.99942E+00 -0.0003 97 SO3-2 0.18968E-14 -14.7220 0.14145E-14 -14.8494 0.74574E+00 -0.1274 98 HSO3- 0.39974E-16 -16.3982 0.36606E-16 -16.4364 0.91576E+00 -0.0382 99 HSO4- 0.84957E-11 -11.0708 0.77844E-11 -11.1088 0.91628E+00 -0.0380 Charge balance for all species = 0.4571E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4823142E-09 -.2943297E-02 -.2965913E+01 0.0000 2 H2O 0.1000000E+01 0.5550853E+02 0.9997489E+06 0.0000 3 Cl- 0.1379237E-03 0.1380350E-03 0.4892513E+01 5.4558 4 SO4-- 0.2550271E-04 0.2551611E-04 0.2450496E+01 13.9869 5 HCO3- 0.1039076E-04 0.1307576E-04 0.7976439E+00 4.3329 6 HS- 0.4072524E-13 -.3904526E-09 -.1290977E-04 -4.0740 7 Al+++ 0.4900450E-25 0.4233692E-04 0.1142023E+01 2.4728 8 H4SiO4 0.5139522E-03 0.1800790E-02 0.1730397E+03 -3.2891 9 Ca++ 0.1236902E-07 0.1450585E-07 0.5812180E-03 10.6720 10 Mg++ 0.1068037E-09 0.1864968E-09 0.4532959E-05 8.6078 11 Fe++ 0.6316010E-12 0.6870362E-08 0.3835917E-03 6.3798 12 K+ 0.4428812E-04 0.4434116E-04 0.1733388E+01 4.9626 13 Na+ 0.2945542E-02 0.2996912E-02 0.6888092E+02 6.7853 14 Mn++ 0.8438536E-10 0.9056394E-09 0.4974138E-04 8.5057 15 HPO4-- 0.1133207E-04 0.1143488E-04 0.1097230E+01 13.6346 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3971084E-01 -.2941999E-02 -.3676884E-01 0.0000000E+00 2 H2O 0.5547818E+02 0.5548406E+02 -.5885372E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9198894E-04 0.2550486E-04 0.6648408E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6648447E-04 -.3902805E-09 -.6648408E-04 0.0000000E+00 7 Al+++ 0.7822519E-02 0.4231825E-04 0.7780201E-02 0.0000000E+00 8 H4SiO4 0.2498027E-01 0.1799997E-02 0.2318027E-01 0.0000000E+00 9 Ca++ 0.2773663E-02 0.1449946E-07 0.2773649E-02 0.0000000E+00 10 Mg++ 0.1903968E-02 0.1864146E-09 0.1903968E-02 0.0000000E+00 11 Fe++ 0.1710508E-02 0.6867333E-08 0.1710501E-02 0.0000000E+00 12 K+ 0.5093418E-03 0.4432161E-04 0.4650202E-03 0.0000000E+00 13 Na+ 0.3171400E-02 0.2995591E-02 0.1758094E-03 0.0000000E+00 14 Mn++ 0.4159529E-04 0.9052401E-09 0.4159439E-04 0.0000000E+00 15 HPO4-- 0.1419627E-04 0.1142984E-04 0.2766426E-05 0.0000000E+00 Chg. balance for solid moles: -.4904E-17 Mass of aqueous solution: 0.999813E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.9221E-06 -6.035 0.4632E-03 -3.334 0.1798E-01 0.1472E-03 clinochlore 0.3808E-03 -3.419 0.2117 -0.674 8.214 0.8051E-01 daphnite 0.2357E-03 -3.628 0.1682 -0.774 6.527 0.5097E-01 chlorite-Mn 0.8319E-05 -5.080 0.5898E-02 -2.229 0.2289 0.1879E-02 hematite 0.2659E-03 -3.575 0.4247E-01 -1.372 1.648 0.8050E-02 microcline 0.4650E-03 -3.333 0.1294 -0.888 5.023 0.5056E-01 paragonite 0.1758E-03 -3.755 0.6719E-01 -1.173 2.608 0.2323E-01 stilbite 0.2769E-02 -2.558 1.951 0.290 75.73 0.9102 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.576705 g Volume = 1.125505 cm3 Porosity: 42.5646% V(tot) - V(min): 0.83409E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.3990000 g log = 0.3800 Original solution: 1000.0103000 g Original solution / Rock added: 416.84 (Water/Rock Ratio), log = 2.6200 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.9167E-06 1.0073 0.9714E-06 0.9643E-06 CH4,gas 0.2725E-16 1.0129 0.2903E-16 0.2866E-16 H2,gas 0.7126E-06 1.0006 0.7500E-06 0.7496E-06 H2S,gas 0.1380E-14 0.9959 0.1445E-14 0.1451E-14 S2,gas 0.1322E-36 1.0000 0.1391E-36 0.1391E-36 CO,gas 0.1794E-15 1.0000 0.1887E-15 0.1887E-15 SO3,gas 0.1319E-38 1.0000 0.1387E-38 0.1387E-38 SO2,gas 0.3741E-22 1.0000 0.3935E-22 0.3935E-22 HCl,gas 0.1763E-16 1.0000 0.1855E-16 0.1855E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.38 -8.01 -2.671 0.13681E+05 -6.013 3 CH4,gas 4.81 -13.73 -18.54 -4.634 0.31652E+05 -16.537 4 H2,gas 8.29 0.16 -8.12 -4.643 0.13873E+05 -6.125 5 H2S,gas -5.94 -22.78 -16.84 -8.420 0.28754E+05 -14.840 6 S2,gas -7.03 -45.89 -38.86 -5.978 0.66347E+05 -36.857 7 CO,gas 3.51 -14.21 -17.72 -5.454 0.30264E+05 -15.724 8 SO3,gas 17.43 -23.43 -40.86 -10.214 0.69764E+05 -38.858 9 SO2,gas 1.14 -23.27 -24.41 -6.508 0.41671E+05 -22.405 10 HCl,gas 5.48 -13.25 -18.73 -9.366 0.31984E+05 -16.732 11 acmite 7.74 6.51 -1.23 -0.128 0.21026E+04 15 albite-high 0.75 -0.61 -1.36 -0.105 0.23200E+04 16 albite -0.33 -0.61 -0.28 -0.022 0.47931E+03 19 spessartine 24.55 20.60 -3.95 -0.198 0.67520E+04 20 analcite 3.37 2.68 -0.69 -0.077 0.11792E+04 21 andalusite 5.06 1.66 -3.41 -0.341 0.58152E+04 22 andradite 39.09 34.75 -4.34 -0.226 0.74128E+04 26 annite 20.21 16.71 -3.50 -0.195 0.59791E+04 27 phlogopite 27.15 23.39 -3.75 -0.209 0.64113E+04 29 anorthite 12.80 9.04 -3.76 -0.289 0.64169E+04 35 aragonite 0.99 -3.70 -4.69 -1.563 0.80081E+04 36 brucite 12.58 8.61 -3.97 -0.794 0.67765E+04 37 calcite 0.83 -3.70 -4.54 -1.512 0.77468E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52854E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71123E+04 40 carpholite-Mg 8.65 6.98 -1.67 -0.112 0.28600E+04 41 carpholite-Fe 6.78 4.75 -2.04 -0.136 0.34756E+04 42 celadonite 5.40 2.89 -2.51 -0.148 0.42918E+04 43 celadonite-Fe 3.94 0.66 -3.28 -0.193 0.55971E+04 44 chrysotile 23.94 19.25 -4.69 -0.391 0.80114E+04 50 chloritoid-Mg 13.26 10.26 -3.00 -0.200 0.51169E+04 51 chloritoid-Fe 9.24 8.04 -1.20 -0.080 0.20528E+04 52 chloritoid-Mn 11.46 10.16 -1.30 -0.087 0.22212E+04 54 coesite -2.37 -3.29 -0.92 -0.307 0.15704E+04 59 corundum 8.43 4.95 -3.49 -0.317 0.59552E+04 61 cristobalite -2.55 -3.29 -0.74 -0.247 0.12633E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.47 -0.42 -0.071 0.72267E+03 67 diopside 16.22 12.70 -3.51 -0.351 0.59997E+04 68 hedenbergite 14.24 10.47 -3.77 -0.377 0.64385E+04 75 epidote 24.78 22.72 -2.05 -0.100 0.35071E+04 76 clinozoisite 22.92 18.90 -4.03 -0.183 0.68740E+04 77 epidote-Fe 29.94 26.55 -3.39 -0.176 0.57876E+04 78 fayalite 14.08 9.47 -4.61 -0.658 0.78688E+04 83 gibbsite 4.10 2.47 -1.62 -0.232 0.27738E+04 87 greenalite 16.19 12.56 -3.63 -0.303 0.62032E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.68 -1.57 -0.157 0.26823E+04 97 kalsilite 7.62 4.15 -3.47 -0.496 0.59316E+04 98 kaolinite -1.27 -1.63 -0.36 -0.033 0.61351E+03 99 kyanite 4.93 1.66 -3.28 -0.328 0.55920E+04 101 laumontite 2.97 2.46 -0.51 -0.034 0.87622E+03 102 lawsonite 9.68 9.04 -0.64 -0.043 0.10908E+04 103 leucite 4.17 0.86 -3.31 -0.331 0.56523E+04 105 lizardite 23.29 19.25 -4.04 -0.337 0.69017E+04 107 magnetite 20.13 18.98 -1.16 -0.094 0.19728E+04 108 minnesotaite 10.46 5.98 -4.48 -0.263 0.76455E+04 113 margarite 17.45 13.99 -3.47 -0.139 0.59191E+04 120 muscovite 2.68 2.51 -0.17 -0.010 0.28222E+03 122 nepheline 8.38 5.97 -2.41 -0.344 0.41134E+04 134 phlogopite-Na 29.73 25.21 -4.52 -0.251 0.77125E+04 136 prehnite 19.47 16.42 -3.04 -0.179 0.51974E+04 137 prehnite-Fe 22.59 20.25 -2.34 -0.141 0.39927E+04 138 pumpellyite-Fe 46.47 41.70 -4.77 -0.106 0.81498E+04 145 pyroxmangite 7.42 5.22 -2.20 -0.440 0.37555E+04 146 pyrophyllite -6.10 -8.21 -2.11 -0.132 0.36072E+04 147 quartz -2.98 -3.29 -0.31 -0.102 0.52433E+03 151 rhodochrosite -0.96 -5.87 -4.91 -1.637 0.83864E+04 152 rhodonite 7.46 5.22 -2.25 -0.449 0.38347E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.66 -3.66 -0.366 0.62574E+04 164 stilpnomelane-Fe 13.18 13.01 -0.17 -0.005 0.28346E+03 165 stilpnomelane-Mg 27.60 24.15 -3.44 -0.103 0.58783E+04 168 sudoite 21.22 17.24 -3.98 -0.128 0.67895E+04 171 talc 16.55 12.67 -3.89 -0.229 0.66355E+04 174 tephroite 18.11 13.72 -4.39 -0.627 0.74968E+04 177 topaz-H 4.67 1.66 -3.01 -0.274 0.51411E+04 178 tridymite -2.61 -3.29 -0.67 -0.225 0.11516E+04 187 wairakite 4.06 2.46 -1.60 -0.094 0.27270E+04 188 walstromite 11.53 7.38 -4.14 -0.829 0.70774E+04 189 wollastonite 10.48 7.38 -3.10 -0.620 0.52913E+04 190 pseudo-wollastonite 11.02 7.38 -3.64 -0.727 0.62099E+04 191 zoisite 22.96 18.90 -4.07 -0.185 0.69466E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.55 -2.99 -0.185 0.51030E+04 194 beidellite-H -2.24 -6.31 -4.07 -0.260 0.69461E+04 195 beidellite-K -1.44 -4.67 -3.24 -0.198 0.55262E+04 196 beidellite-Mg -1.71 -4.89 -3.18 -0.197 0.54332E+04 197 beidellite-Na -1.26 -4.07 -2.81 -0.172 0.48031E+04 199 chalcedony -2.79 -3.29 -0.49 -0.165 0.84464E+03 201 montmorillonite-Ca -2.21 -4.43 -2.21 -0.137 0.37755E+04 202 montmorillonite-K -2.16 -4.55 -2.39 -0.146 0.40765E+04 203 montmorillonite-Mg -2.40 -4.77 -2.36 -0.146 0.40367E+04 204 montmorillonite-Na -1.96 -3.95 -1.99 -0.122 0.33915E+04 205 nontronite-Ca 3.28 3.10 -0.18 -0.011 0.30057E+03 206 nontronite-H 2.60 1.34 -1.25 -0.084 0.21394E+04 207 nontronite-K 3.40 2.98 -0.42 -0.027 0.72298E+03 208 nontronite-Mg 3.14 2.76 -0.38 -0.024 0.64237E+03 209 nontronite-Na 3.58 3.58 0.00 0.000 0.15724E+01 224 tobermorite 9.84 5.60 -4.24 -1.156 0.72368E+04 233 boehmite 4.43 2.47 -1.96 -0.326 0.33411E+04 235 ferrous-oxide 9.82 6.38 -3.44 -0.861 0.58813E+04 240 silica-amorphous -2.08 -3.29 -1.21 -0.403 0.20648E+04 242 an20ab80 2.08 1.32 -0.76 -0.058 0.12952E+04 243 an25ab75 2.71 1.80 -0.91 -0.070 0.15471E+04 244 an30ab70 3.34 2.29 -1.06 -0.081 0.18073E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 2.3990000 g New total amount of reactant added: 2.4990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4567E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2.4990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9995E+00 Moles total = 0.5548E+02 kg total = 0.9994E+00 Activity = 1.0000 Stoichiometric ionic strength = .1921624E-02 Osmotic coef. = 0.9753 True ionic strength = .3143737E-02 Chg. balance for total moles = 0.4567E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.46654E-09 -9.3311 0.42725E-09 -9.3693 0.91578E+00 -0.0382 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13792E-03 -3.8604 0.12615E-03 -3.8991 0.91465E+00 -0.0387 4 SO4-- 0.25504E-04 -4.5934 0.18882E-04 -4.7239 0.74038E+00 -0.1305 5 HCO3- 0.10309E-04 -4.9868 0.94323E-05 -5.0254 0.91492E+00 -0.0386 6 HS- 0.41653E-13 -13.3804 0.38099E-13 -13.4191 0.91468E+00 -0.0387 7 Al+++ 0.43203E-25 -25.3645 0.22403E-25 -25.6497 0.51856E+00 -0.2852 8 H4SiO4 0.51900E-03 -3.2848 0.51900E-03 -3.2848 0.10000E+01 0.0000 9 Ca++ 0.11587E-07 -7.9360 0.85659E-08 -8.0672 0.73929E+00 -0.1312 10 Mg++ 0.10094E-09 -9.9959 0.74556E-10 -10.1275 0.73860E+00 -0.1316 11 Fe++ 0.59694E-12 -12.2241 0.44100E-12 -12.3556 0.73876E+00 -0.1315 12 K+ 0.43023E-04 -4.3663 0.39365E-04 -4.4049 0.91497E+00 -0.0386 13 Na+ 0.30601E-02 -2.5143 0.27988E-02 -2.5530 0.91462E+00 -0.0388 14 Mn++ 0.79754E-10 -10.0982 0.58929E-10 -10.2297 0.73889E+00 -0.1314 15 HPO4-- 0.12224E-04 -4.9128 0.90509E-05 -5.0433 0.74040E+00 -0.1305 16 HSiO3- 0.12958E-02 -2.8875 0.11852E-02 -2.9262 0.91465E+00 -0.0387 17 Ca(HSiO3)+ 0.24859E-09 -9.6045 0.22746E-09 -9.6431 0.91501E+00 -0.0386 18 Mg(HSiO3)+ 0.26928E-11 -11.5698 0.24639E-11 -11.6084 0.91501E+00 -0.0386 19 NaHSiO3,aq 0.52684E-04 -4.2783 0.52684E-04 -4.2783 0.10000E+01 0.0000 20 AlO+ 0.17316E-13 -13.7616 0.15844E-13 -13.8001 0.91501E+00 -0.0386 21 AlOH+2 0.45885E-19 -19.3383 0.33910E-19 -19.4697 0.73903E+00 -0.1313 22 HAlO2,aq 0.74209E-08 -8.1295 0.74209E-08 -8.1295 0.10000E+01 0.0000 23 AlO2- 0.42418E-04 -4.3725 0.38783E-04 -4.4114 0.91431E+00 -0.0389 24 CH4,aq 0.18686E-19 -19.7285 0.18675E-19 -19.7287 0.99941E+00 -0.0003 29 CO,aq 0.11617E-18 -18.9349 0.11617E-18 -18.9349 0.10000E+01 0.0000 30 CO2,aq 0.81300E-08 -8.0899 0.81252E-08 -8.0902 0.99941E+00 -0.0003 31 CO3-2 0.27582E-05 -5.5594 0.20412E-05 -5.6901 0.74006E+00 -0.1307 32 CaCO3,aq 0.21415E-09 -9.6693 0.21415E-09 -9.6693 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.22249E-11 -11.6527 0.20358E-11 -11.6913 0.91501E+00 -0.0386 34 CaCl+ 0.18819E-11 -11.7254 0.17219E-11 -11.7640 0.91501E+00 -0.0386 35 CaCl2,aq 0.50577E-16 -16.2960 0.50577E-16 -16.2960 0.10000E+01 0.0000 36 CaOH+ 0.15450E-08 -8.8111 0.14137E-08 -8.8496 0.91501E+00 -0.0386 37 CaSO4,aq 0.50396E-10 -10.2976 0.50396E-10 -10.2976 0.10000E+01 0.0000 38 HCl,aq 0.10138E-13 -13.9940 0.10138E-13 -13.9940 0.10000E+01 0.0000 43 FeCl+ 0.94696E-16 -16.0237 0.86647E-16 -16.0622 0.91501E+00 -0.0386 46 FeO,aq 0.95534E-10 -10.0198 0.95534E-10 -10.0198 0.10000E+01 0.0000 47 FeOH+ 0.37398E-10 -10.4272 0.34219E-10 -10.4657 0.91501E+00 -0.0386 48 HFeO2- 0.26295E-08 -8.5801 0.24051E-08 -8.6189 0.91465E+00 -0.0387 49 FeO+ 0.38625E-14 -14.4131 0.35343E-14 -14.4517 0.91501E+00 -0.0386 51 FeO2- 0.41604E-08 -8.3809 0.38053E-08 -8.4196 0.91465E+00 -0.0387 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.55548E-09 -9.2553 0.55515E-09 -9.2556 0.99941E+00 -0.0003 54 KCl,aq 0.87928E-10 -10.0559 0.87928E-10 -10.0559 0.10000E+01 0.0000 55 KHSO4,aq 0.84981E-18 -18.0707 0.84981E-18 -18.0707 0.10000E+01 0.0000 56 KOH,aq 0.40166E-07 -7.3961 0.40166E-07 -7.3961 0.10000E+01 0.0000 57 KSO4- 0.12520E-07 -7.9024 0.11451E-07 -7.9411 0.91465E+00 -0.0387 58 MgCO3,aq 0.46575E-12 -12.3318 0.46575E-12 -12.3318 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19748E-13 -13.7045 0.18069E-13 -13.7431 0.91501E+00 -0.0386 60 MgCl+ 0.14870E-13 -13.8277 0.13606E-13 -13.8663 0.91501E+00 -0.0386 61 MgOH+ 0.74501E-10 -10.1278 0.68169E-10 -10.1664 0.91501E+00 -0.0386 63 MnO,aq 0.34079E-09 -9.4675 0.34079E-09 -9.4675 0.10000E+01 0.0000 64 MnOH+ 0.46424E-09 -9.3333 0.42478E-09 -9.3718 0.91501E+00 -0.0386 65 MnO2-2 0.87242E-13 -13.0593 0.64564E-13 -13.1900 0.74006E+00 -0.1307 66 HMnO2- 0.65343E-11 -11.1848 0.59766E-11 -11.2235 0.91465E+00 -0.0387 69 MnCl+ 0.49171E-13 -13.3083 0.44992E-13 -13.3469 0.91501E+00 -0.0386 70 MnSO4,aq 0.31535E-12 -12.5012 0.31535E-12 -12.5012 0.10000E+01 0.0000 71 NaCl,aq 0.11529E-06 -6.9382 0.11529E-06 -6.9382 0.10000E+01 0.0000 72 NaOH,aq 0.28785E-05 -5.5408 0.28785E-05 -5.5408 0.10000E+01 0.0000 74 OH- 0.15355E-02 -2.8137 0.14039E-02 -2.8526 0.91431E+00 -0.0389 79 HPO3-2 0.21445E-16 -16.6687 0.15870E-16 -16.7994 0.74006E+00 -0.1307 81 H2PO3- 0.14562E-19 -19.8368 0.13319E-19 -19.8755 0.91465E+00 -0.0387 82 H3PO4,aq 0.10637E-13 -13.9732 0.10637E-13 -13.9732 0.10000E+01 0.0000 83 H2PO4- 0.74109E-07 -7.1301 0.67796E-07 -7.1688 0.91483E+00 -0.0387 84 PO4-3 0.35320E-07 -7.4520 0.18500E-07 -7.7328 0.52380E+00 -0.2808 87 H2P2O7-2 0.48609E-15 -15.3133 0.35973E-15 -15.4440 0.74006E+00 -0.1307 88 HP2O7-3 0.33290E-12 -12.4777 0.17265E-12 -12.7628 0.51863E+00 -0.2851 89 P2O7-4 0.31421E-12 -12.5028 0.99690E-13 -13.0013 0.31727E+00 -0.4986 90 H2S,aq 0.48937E-16 -16.3104 0.48908E-16 -16.3106 0.99941E+00 -0.0003 97 SO3-2 0.19256E-14 -14.7154 0.14293E-14 -14.8449 0.74225E+00 -0.1295 98 HSO3- 0.39071E-16 -16.4081 0.35737E-16 -16.4469 0.91465E+00 -0.0387 99 HSO4- 0.81792E-11 -11.0873 0.74855E-11 -11.1258 0.91518E+00 -0.0385 Charge balance for all species = 0.4572E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4665414E-09 -.3059343E-02 -.3082824E+01 0.0000 2 H2O 0.1000000E+01 0.5550853E+02 0.9997399E+06 0.0000 3 Cl- 0.1379221E-03 0.1380375E-03 0.4892557E+01 5.4702 4 SO4-- 0.2550359E-04 0.2551658E-04 0.2450519E+01 14.0147 5 HCO3- 0.1030945E-04 0.1307600E-04 0.7976510E+00 4.3439 6 HS- 0.4165301E-13 -.4065721E-09 -.1344262E-04 -4.0498 7 Al+++ 0.4320303E-25 0.4242514E-04 0.1144393E+01 2.4583 8 H4SiO4 0.5190011E-03 0.1867474E-02 0.1794458E+03 -3.2848 9 Ca++ 0.1158678E-07 0.1364905E-07 0.5468828E-03 10.6714 10 Mg++ 0.1009433E-09 0.1786373E-09 0.4341889E-05 8.6111 11 Fe++ 0.5969404E-12 0.7126894E-08 0.3979110E-03 6.3831 12 K+ 0.4302283E-04 0.4307560E-04 0.1683900E+01 4.9644 13 Na+ 0.3060084E-02 0.3115762E-02 0.7161193E+02 6.8163 14 Mn++ 0.7975416E-10 0.8917664E-09 0.4897899E-04 8.5090 15 HPO4-- 0.1222439E-04 0.1233382E-04 0.1183476E+01 13.6953 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4136669E-01 -.3057940E-02 -.3830875E-01 0.0000000E+00 2 H2O 0.5547692E+02 0.5548307E+02 -.6143595E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9476028E-04 0.2550488E-04 0.6925540E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6925581E-04 -.4063857E-09 -.6925540E-04 0.0000000E+00 7 Al+++ 0.8148593E-02 0.4240568E-04 0.8106188E-02 0.0000000E+00 8 H4SiO4 0.2602154E-01 0.1866618E-02 0.2415493E-01 0.0000000E+00 9 Ca++ 0.2888678E-02 0.1364279E-07 0.2888664E-02 0.0000000E+00 10 Mg++ 0.1983333E-02 0.1785554E-09 0.1983333E-02 0.0000000E+00 11 Fe++ 0.1781808E-02 0.7123625E-08 0.1781801E-02 0.0000000E+00 12 K+ 0.5305732E-03 0.4305585E-04 0.4875174E-03 0.0000000E+00 13 Na+ 0.3296925E-02 0.3114333E-02 0.1825914E-03 0.0000000E+00 14 Mn++ 0.4332915E-04 0.8913574E-09 0.4332826E-04 0.0000000E+00 15 HPO4-- 0.1478802E-04 0.1232816E-04 0.2459864E-05 0.0000000E+00 Chg. balance for solid moles: -.6357E-17 Mass of aqueous solution: 0.999804E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2.4990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.8200E-06 -6.086 0.4119E-03 -3.385 0.1534E-01 0.1309E-03 clinochlore 0.3967E-03 -3.402 0.2205 -0.657 8.212 0.8386E-01 daphnite 0.2456E-03 -3.610 0.1752 -0.756 6.526 0.5309E-01 chlorite-Mn 0.8666E-05 -5.062 0.6144E-02 -2.212 0.2288 0.1958E-02 hematite 0.2770E-03 -3.557 0.4424E-01 -1.354 1.648 0.8385E-02 microcline 0.4875E-03 -3.312 0.1357 -0.867 5.054 0.5301E-01 paragonite 0.1826E-03 -3.739 0.6979E-01 -1.156 2.599 0.2412E-01 stilbite 0.2885E-02 -2.540 2.033 0.308 75.72 0.9481 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.684771 g Volume = 1.172698 cm3 Porosity: 41.3534% V(tot) - V(min): 0.82690E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.4990000 g log = 0.3978 Original solution: 1000.0103000 g Original solution / Rock added: 400.16 (Water/Rock Ratio), log = 2.6022 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.8777E-06 1.0073 0.9301E-06 0.9233E-06 CH4,gas 0.2772E-16 1.0129 0.2953E-16 0.2916E-16 H2,gas 0.7234E-06 1.0006 0.7614E-06 0.7610E-06 H2S,gas 0.1362E-14 0.9959 0.1426E-14 0.1432E-14 S2,gas 0.1250E-36 1.0000 0.1314E-36 0.1314E-36 CO,gas 0.1744E-15 1.0000 0.1834E-15 0.1834E-15 SO3,gas 0.1225E-38 1.0000 0.1289E-38 0.1289E-38 SO2,gas 0.3529E-22 1.0000 0.3712E-22 0.3712E-22 HCl,gas 0.1702E-16 1.0000 0.1790E-16 0.1790E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 -0.15165E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 209 nontronite-Na 3.58 3.60 0.02 0.001 -0.34281E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.39 -8.03 -2.677 0.13714E+05 -6.031 3 CH4,gas 4.81 -13.72 -18.53 -4.632 0.31639E+05 -16.530 4 H2,gas 8.29 0.17 -8.12 -4.639 0.13862E+05 -6.118 5 H2S,gas -5.94 -22.79 -16.85 -8.423 0.28764E+05 -14.846 6 S2,gas -7.03 -45.91 -38.88 -5.982 0.66389E+05 -36.881 7 CO,gas 3.51 -14.23 -17.74 -5.457 0.30285E+05 -15.737 8 SO3,gas 17.43 -23.46 -40.89 -10.222 0.69818E+05 -38.890 9 SO2,gas 1.14 -23.29 -24.43 -6.515 0.41714E+05 -22.430 10 HCl,gas 5.48 -13.27 -18.75 -9.374 0.32010E+05 -16.747 11 acmite 7.74 6.55 -1.19 -0.124 0.20352E+04 15 albite-high 0.75 -0.58 -1.33 -0.102 0.22702E+04 16 albite -0.33 -0.58 -0.25 -0.019 0.42954E+03 19 spessartine 24.55 20.59 -3.96 -0.198 0.67632E+04 20 analcite 3.37 2.70 -0.67 -0.074 0.11367E+04 21 andalusite 5.06 1.63 -3.43 -0.343 0.58577E+04 22 andradite 39.09 34.76 -4.33 -0.225 0.73940E+04 26 annite 20.21 16.72 -3.49 -0.194 0.59623E+04 27 phlogopite 27.15 23.40 -3.75 -0.208 0.63945E+04 29 anorthite 12.80 9.02 -3.78 -0.291 0.64532E+04 35 aragonite 0.99 -3.72 -4.71 -1.570 0.80414E+04 36 brucite 12.58 8.61 -3.97 -0.793 0.67709E+04 37 calcite 0.83 -3.72 -4.56 -1.519 0.77800E+04 38 carnegieite-low 9.06 5.99 -3.07 -0.439 0.52502E+04 39 carnegieite-high 10.13 5.99 -4.14 -0.592 0.70770E+04 40 carpholite-Mg 8.65 6.96 -1.69 -0.113 0.28897E+04 41 carpholite-Fe 6.78 4.73 -2.05 -0.137 0.35053E+04 42 celadonite 5.40 2.89 -2.51 -0.147 0.42789E+04 43 celadonite-Fe 3.94 0.67 -3.27 -0.192 0.55843E+04 44 chrysotile 23.94 19.26 -4.67 -0.389 0.79801E+04 50 chloritoid-Mg 13.26 10.24 -3.02 -0.201 0.51538E+04 51 chloritoid-Fe 9.24 8.01 -1.22 -0.082 0.20897E+04 52 chloritoid-Mn 11.46 10.14 -1.32 -0.088 0.22582E+04 54 coesite -2.37 -3.28 -0.92 -0.305 0.15632E+04 59 corundum 8.43 4.92 -3.52 -0.320 0.60050E+04 61 cristobalite -2.55 -3.28 -0.74 -0.245 0.12560E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.46 -0.44 -0.073 0.74755E+03 67 diopside 16.22 12.71 -3.50 -0.350 0.59806E+04 68 hedenbergite 14.24 10.48 -3.76 -0.376 0.64194E+04 75 epidote 24.78 22.70 -2.07 -0.100 0.35370E+04 76 clinozoisite 22.92 18.86 -4.06 -0.184 0.69289E+04 77 epidote-Fe 29.94 26.54 -3.39 -0.176 0.57927E+04 78 fayalite 14.08 9.48 -4.60 -0.657 0.78503E+04 79 ferrosilite 11.19 6.20 -4.99 -0.499 0.85223E+04 83 gibbsite 4.10 2.46 -1.64 -0.234 0.27987E+04 87 greenalite 16.19 12.58 -3.61 -0.301 0.61719E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.70 -1.55 -0.155 0.26397E+04 97 kalsilite 7.62 4.14 -3.48 -0.497 0.59461E+04 98 kaolinite -1.27 -1.65 -0.38 -0.035 0.64879E+03 99 kyanite 4.93 1.63 -3.30 -0.330 0.56345E+04 101 laumontite 2.97 2.45 -0.53 -0.035 0.89797E+03 102 lawsonite 9.68 9.02 -0.66 -0.044 0.11271E+04 103 leucite 4.17 0.85 -3.31 -0.331 0.56596E+04 105 lizardite 23.29 19.26 -4.02 -0.335 0.68704E+04 107 magnetite 20.13 18.98 -1.15 -0.094 0.19672E+04 108 minnesotaite 10.46 6.01 -4.45 -0.262 0.75997E+04 113 margarite 17.45 13.93 -3.52 -0.141 0.60051E+04 120 muscovite 2.68 2.48 -0.19 -0.011 0.33200E+03 122 nepheline 8.38 5.99 -2.39 -0.341 0.40781E+04 134 phlogopite-Na 29.73 25.25 -4.48 -0.249 0.76459E+04 136 prehnite 19.47 16.40 -3.06 -0.180 0.52273E+04 137 prehnite-Fe 22.59 20.25 -2.34 -0.141 0.39978E+04 138 pumpellyite-Fe 46.47 41.65 -4.82 -0.107 0.82291E+04 145 pyroxmangite 7.42 5.22 -2.19 -0.438 0.37426E+04 146 pyrophyllite -6.10 -8.22 -2.12 -0.133 0.36279E+04 147 quartz -2.98 -3.28 -0.30 -0.101 0.51708E+03 151 rhodochrosite -0.96 -5.89 -4.93 -1.642 0.84131E+04 152 rhodonite 7.46 5.22 -2.24 -0.448 0.38218E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.63 -3.69 -0.369 0.62999E+04 164 stilpnomelane-Fe 13.18 13.04 -0.14 -0.004 0.24565E+03 165 stilpnomelane-Mg 27.60 24.18 -3.42 -0.102 0.58405E+04 168 sudoite 21.22 17.20 -4.02 -0.130 0.68561E+04 171 talc 16.55 12.69 -3.86 -0.227 0.65897E+04 174 tephroite 18.11 13.73 -4.38 -0.626 0.74784E+04 177 topaz-H 4.67 1.63 -3.04 -0.276 0.51836E+04 178 tridymite -2.61 -3.28 -0.67 -0.223 0.11444E+04 187 wairakite 4.06 2.45 -1.61 -0.095 0.27488E+04 188 walstromite 11.53 7.39 -4.14 -0.828 0.70711E+04 189 wollastonite 10.48 7.39 -3.10 -0.619 0.52850E+04 190 pseudo-wollastonite 11.02 7.39 -3.63 -0.727 0.62037E+04 191 zoisite 22.96 18.86 -4.10 -0.186 0.70014E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.57 -3.01 -0.186 0.51345E+04 194 beidellite-H -2.24 -6.33 -4.09 -0.261 0.69775E+04 195 beidellite-K -1.44 -4.69 -3.25 -0.199 0.55566E+04 196 beidellite-Mg -1.71 -4.91 -3.20 -0.198 0.54636E+04 197 beidellite-Na -1.26 -4.08 -2.82 -0.173 0.48170E+04 199 chalcedony -2.79 -3.28 -0.49 -0.163 0.83739E+03 201 montmorillonite-Ca -2.21 -4.43 -2.22 -0.137 0.37864E+04 202 montmorillonite-K -2.16 -4.55 -2.39 -0.147 0.40862E+04 203 montmorillonite-Mg -2.40 -4.77 -2.37 -0.147 0.40465E+04 204 montmorillonite-Na -1.96 -3.94 -1.98 -0.121 0.33848E+04 205 nontronite-Ca 3.28 3.11 -0.17 -0.011 0.28234E+03 206 nontronite-H 2.60 1.35 -1.24 -0.083 0.21211E+04 207 nontronite-K 3.40 2.99 -0.41 -0.026 0.70355E+03 208 nontronite-Mg 3.14 2.77 -0.36 -0.024 0.62305E+03 224 tobermorite 9.84 5.60 -4.23 -1.155 0.72304E+04 233 boehmite 4.43 2.46 -1.97 -0.329 0.33660E+04 235 ferrous-oxide 9.82 6.38 -3.44 -0.860 0.58757E+04 240 silica-amorphous -2.08 -3.28 -1.21 -0.402 0.20576E+04 242 an20ab80 2.08 1.34 -0.74 -0.057 0.12627E+04 243 an25ab75 2.71 1.82 -0.89 -0.068 0.15188E+04 244 an30ab70 3.34 2.30 -1.04 -0.080 0.17834E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2.4990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9995E+00 Moles total = 0.5548E+02 kg total = 0.9994E+00 Activity = 1.0000 Stoichiometric ionic strength = .1921344E-02 Osmotic coef. = 0.9753 True ionic strength = .3140320E-02 Chg. balance for total moles = 0.4567E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.46356E-09 -9.3339 0.42453E-09 -9.3721 0.91581E+00 -0.0382 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13792E-03 -3.8604 0.12616E-03 -3.8991 0.91468E+00 -0.0387 4 SO4-- 0.25503E-04 -4.5934 0.18885E-04 -4.7239 0.74048E+00 -0.1305 5 HCO3- 0.10296E-04 -4.9873 0.94202E-05 -5.0259 0.91495E+00 -0.0386 6 HS- 0.42587E-13 -13.3707 0.38954E-13 -13.4094 0.91471E+00 -0.0387 7 Al+++ 0.42898E-25 -25.3676 0.22253E-25 -25.6526 0.51873E+00 -0.2851 8 H4SiO4 0.51169E-03 -3.2910 0.51169E-03 -3.2910 0.10000E+01 0.0000 9 Ca++ 0.12324E-07 -7.9093 0.91120E-08 -8.0404 0.73939E+00 -0.1311 10 Mg++ 0.10000E-09 -10.0000 0.73872E-10 -10.1315 0.73870E+00 -0.1315 11 Fe++ 0.59138E-12 -12.2281 0.43695E-12 -12.3596 0.73887E+00 -0.1314 12 K+ 0.44058E-04 -4.3560 0.40313E-04 -4.3946 0.91500E+00 -0.0386 13 Na+ 0.30569E-02 -2.5147 0.27960E-02 -2.5535 0.91466E+00 -0.0387 14 Mn++ 0.79011E-10 -10.1023 0.58389E-10 -10.2337 0.73899E+00 -0.1314 15 HPO4-- 0.10933E-04 -4.9613 0.80959E-05 -5.0917 0.74050E+00 -0.1305 16 HSiO3- 0.12857E-02 -2.8909 0.11760E-02 -2.9296 0.91468E+00 -0.0387 17 Ca(HSiO3)+ 0.26237E-09 -9.5811 0.24008E-09 -9.6196 0.91504E+00 -0.0386 18 Mg(HSiO3)+ 0.26472E-11 -11.5772 0.24223E-11 -11.6158 0.91504E+00 -0.0386 19 NaHSiO3,aq 0.52222E-04 -4.2821 0.52222E-04 -4.2821 0.10000E+01 0.0000 20 AlO+ 0.17420E-13 -13.7590 0.15940E-13 -13.7975 0.91504E+00 -0.0386 21 AlOH+2 0.45861E-19 -19.3386 0.33898E-19 -19.4698 0.73914E+00 -0.1313 22 HAlO2,aq 0.75135E-08 -8.1242 0.75135E-08 -8.1242 0.10000E+01 0.0000 23 AlO2- 0.43221E-04 -4.3643 0.39519E-04 -4.4032 0.91435E+00 -0.0389 24 CH4,aq 0.19079E-19 -19.7195 0.19067E-19 -19.7197 0.99941E+00 -0.0003 29 CO,aq 0.11611E-18 -18.9351 0.11611E-18 -18.9351 0.10000E+01 0.0000 30 CO2,aq 0.80678E-08 -8.0932 0.80630E-08 -8.0935 0.99941E+00 -0.0003 31 CO3-2 0.27719E-05 -5.5572 0.20517E-05 -5.6879 0.74016E+00 -0.1307 32 CaCO3,aq 0.22896E-09 -9.6402 0.22896E-09 -9.6402 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.23636E-11 -11.6264 0.21628E-11 -11.6650 0.91504E+00 -0.0386 34 CaCl+ 0.20018E-11 -11.6986 0.18318E-11 -11.7371 0.91504E+00 -0.0386 35 CaCl2,aq 0.53805E-16 -16.2692 0.53805E-16 -16.2692 0.10000E+01 0.0000 36 CaOH+ 0.16540E-08 -8.7815 0.15135E-08 -8.8200 0.91504E+00 -0.0386 37 CaSO4,aq 0.53615E-10 -10.2707 0.53615E-10 -10.2707 0.10000E+01 0.0000 38 HCl,aq 0.10074E-13 -13.9968 0.10074E-13 -13.9968 0.10000E+01 0.0000 43 FeCl+ 0.93827E-16 -16.0277 0.85856E-16 -16.0662 0.91504E+00 -0.0386 46 FeO,aq 0.95874E-10 -10.0183 0.95874E-10 -10.0183 0.10000E+01 0.0000 47 FeOH+ 0.37291E-10 -10.4284 0.34123E-10 -10.4670 0.91504E+00 -0.0386 48 HFeO2- 0.26557E-08 -8.5758 0.24291E-08 -8.6146 0.91468E+00 -0.0387 49 FeO+ 0.38378E-14 -14.4159 0.35118E-14 -14.4545 0.91504E+00 -0.0386 51 FeO2- 0.41869E-08 -8.3781 0.38297E-08 -8.4168 0.91468E+00 -0.0387 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.55944E-09 -9.2522 0.55911E-09 -9.2525 0.99941E+00 -0.0003 54 KCl,aq 0.90049E-10 -10.0455 0.90049E-10 -10.0455 0.10000E+01 0.0000 55 KHSO4,aq 0.86485E-18 -18.0631 0.86485E-18 -18.0631 0.10000E+01 0.0000 56 KOH,aq 0.41397E-07 -7.3830 0.41397E-07 -7.3830 0.10000E+01 0.0000 57 KSO4- 0.12823E-07 -7.8920 0.11729E-07 -7.9307 0.91468E+00 -0.0387 58 MgCO3,aq 0.46384E-12 -12.3336 0.46384E-12 -12.3336 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19541E-13 -13.7091 0.17880E-13 -13.7476 0.91504E+00 -0.0386 60 MgCl+ 0.14733E-13 -13.8317 0.13481E-13 -13.8703 0.91504E+00 -0.0386 61 MgOH+ 0.74288E-10 -10.1291 0.67976E-10 -10.1676 0.91504E+00 -0.0386 63 MnO,aq 0.34200E-09 -9.4660 0.34200E-09 -9.4660 0.10000E+01 0.0000 64 MnOH+ 0.46291E-09 -9.3345 0.42358E-09 -9.3731 0.91504E+00 -0.0386 65 MnO2-2 0.88666E-13 -13.0522 0.65627E-13 -13.1829 0.74016E+00 -0.1307 66 HMnO2- 0.65994E-11 -11.1805 0.60364E-11 -11.2192 0.91468E+00 -0.0387 69 MnCl+ 0.48720E-13 -13.3123 0.44581E-13 -13.3509 0.91504E+00 -0.0386 70 MnSO4,aq 0.31249E-12 -12.5052 0.31249E-12 -12.5052 0.10000E+01 0.0000 71 NaCl,aq 0.11518E-06 -6.9386 0.11518E-06 -6.9386 0.10000E+01 0.0000 72 NaOH,aq 0.28940E-05 -5.5385 0.28940E-05 -5.5385 0.10000E+01 0.0000 74 OH- 0.15453E-02 -2.8110 0.14129E-02 -2.8499 0.91435E+00 -0.0389 79 HPO3-2 0.19316E-16 -16.7141 0.14297E-16 -16.8447 0.74016E+00 -0.1307 81 H2PO3- 0.13035E-19 -19.8849 0.11923E-19 -19.9236 0.91468E+00 -0.0387 82 H3PO4,aq 0.93935E-14 -14.0272 0.93935E-14 -14.0272 0.10000E+01 0.0000 83 H2PO4- 0.65864E-07 -7.1814 0.60256E-07 -7.2200 0.91486E+00 -0.0386 84 PO4-3 0.31786E-07 -7.4978 0.16654E-07 -7.7785 0.52396E+00 -0.2807 87 H2P2O7-2 0.38393E-15 -15.4158 0.28417E-15 -15.5464 0.74016E+00 -0.1307 88 HP2O7-3 0.26457E-12 -12.5775 0.13726E-12 -12.8625 0.51879E+00 -0.2850 89 P2O7-4 0.25126E-12 -12.5999 0.79762E-13 -13.0982 0.31745E+00 -0.4983 90 H2S,aq 0.49717E-16 -16.3035 0.49687E-16 -16.3038 0.99941E+00 -0.0003 97 SO3-2 0.19393E-14 -14.7123 0.14397E-14 -14.8417 0.74235E+00 -0.1294 98 HSO3- 0.39104E-16 -16.4078 0.35767E-16 -16.4465 0.91468E+00 -0.0387 99 HSO4- 0.81279E-11 -11.0900 0.74388E-11 -11.1285 0.91522E+00 -0.0385 Charge balance for all species = 0.4506E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4635551E-09 -.3061785E-02 -.3085289E+01 0.0000 2 H2O 0.1000000E+01 0.5550855E+02 0.9997417E+06 0.0000 3 Cl- 0.1379222E-03 0.1380374E-03 0.4892562E+01 5.4730 4 SO4-- 0.2550328E-04 0.2551657E-04 0.2450522E+01 14.0203 5 HCO3- 0.1029579E-04 0.1307599E-04 0.7976519E+00 4.3462 6 HS- 0.4258663E-13 -.4088929E-09 -.1351937E-04 -4.0374 7 Al+++ 0.4289819E-25 0.4322809E-04 0.1166054E+01 2.4637 8 H4SiO4 0.5116855E-03 0.1849571E-02 0.1777257E+03 -3.2910 9 Ca++ 0.1232364E-07 0.1452696E-07 0.5820592E-03 10.7038 10 Mg++ 0.1000029E-09 0.1774360E-09 0.4312697E-05 8.6127 11 Fe++ 0.5913793E-12 0.7179811E-08 0.4008661E-03 6.3846 12 K+ 0.4405753E-04 0.4411184E-04 0.1724410E+01 4.9775 13 Na+ 0.3056919E-02 0.3112151E-02 0.7152902E+02 6.8186 14 Mn++ 0.7901119E-10 0.8909731E-09 0.4893549E-04 8.5105 15 HPO4-- 0.1093293E-04 0.1103058E-04 0.1058427E+01 13.6524 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4136669E-01 -.3060382E-02 -.3830631E-01 0.0000000E+00 2 H2O 0.5547692E+02 0.5548311E+02 -.6186290E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9476028E-04 0.2550488E-04 0.6925540E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6925581E-04 -.4087055E-09 -.6925540E-04 0.0000000E+00 7 Al+++ 0.8148593E-02 0.4320828E-04 0.8105385E-02 0.0000000E+00 8 H4SiO4 0.2602154E-01 0.1848723E-02 0.2417282E-01 0.0000000E+00 9 Ca++ 0.2888678E-02 0.1452030E-07 0.2888663E-02 0.0000000E+00 10 Mg++ 0.1983333E-02 0.1773547E-09 0.1983333E-02 0.0000000E+00 11 Fe++ 0.1781808E-02 0.7176521E-08 0.1781801E-02 0.0000000E+00 12 K+ 0.5305732E-03 0.4409163E-04 0.4864816E-03 0.0000000E+00 13 Na+ 0.3296925E-02 0.3110724E-02 0.1862004E-03 0.0000000E+00 14 Mn++ 0.4332915E-04 0.8905649E-09 0.4332826E-04 0.0000000E+00 15 HPO4-- 0.1478802E-04 0.1102552E-04 0.3762501E-05 0.0000000E+00 Chg. balance for solid moles: -.1856E-17 Mass of aqueous solution: 0.999803E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2.4990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1254E-05 -5.902 0.6300E-03 -3.201 0.2346E-01 0.2002E-03 clinochlore 0.3967E-03 -3.402 0.2205 -0.657 8.209 0.8386E-01 daphnite 0.2456E-03 -3.610 0.1752 -0.756 6.523 0.5309E-01 chlorite-Mn 0.8666E-05 -5.062 0.6144E-02 -2.212 0.2287 0.1958E-02 hematite 0.2676E-03 -3.573 0.4273E-01 -1.369 1.591 0.8099E-02 microcline 0.4865E-03 -3.313 0.1354 -0.868 5.041 0.5289E-01 paragonite 0.1831E-03 -3.737 0.6997E-01 -1.155 2.605 0.2419E-01 stilbite 0.2882E-02 -2.540 2.031 0.308 75.63 0.9474 nontronite-Na 0.9470E-05 -5.024 0.4027E-02 -2.395 0.1499 0.1251E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.685870 g Volume = 1.172969 cm3 Porosity: 41.3398% V(tot) - V(min): 0.82663E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.4990000 g log = 0.3978 Original solution: 1000.0103000 g Original solution / Rock added: 400.16 (Water/Rock Ratio), log = 2.6022 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.8710E-06 1.0073 0.9230E-06 0.9162E-06 CH4,gas 0.2830E-16 1.0129 0.3015E-16 0.2977E-16 H2,gas 0.7286E-06 1.0006 0.7669E-06 0.7664E-06 H2S,gas 0.1383E-14 0.9959 0.1449E-14 0.1455E-14 S2,gas 0.1272E-36 1.0000 0.1338E-36 0.1338E-36 CO,gas 0.1743E-15 1.0000 0.1833E-15 0.1833E-15 SO3,gas 0.1210E-38 1.0000 0.1272E-38 0.1272E-38 SO2,gas 0.3509E-22 1.0000 0.3691E-22 0.3691E-22 HCl,gas 0.1691E-16 1.0000 0.1779E-16 0.1779E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 0.19715E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.22748E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.40 -8.03 -2.678 0.13719E+05 -6.035 3 CH4,gas 4.81 -13.71 -18.52 -4.630 0.31624E+05 -16.521 4 H2,gas 8.29 0.17 -8.12 -4.637 0.13857E+05 -6.115 5 H2S,gas -5.94 -22.78 -16.84 -8.419 0.28752E+05 -14.839 6 S2,gas -7.03 -45.91 -38.87 -5.981 0.66376E+05 -36.874 7 CO,gas 3.51 -14.23 -17.74 -5.457 0.30285E+05 -15.737 8 SO3,gas 17.43 -23.47 -40.90 -10.224 0.69828E+05 -38.895 9 SO2,gas 1.14 -23.30 -24.43 -6.515 0.41718E+05 -22.433 10 HCl,gas 5.48 -13.27 -18.75 -9.375 0.32015E+05 -16.750 11 acmite 7.74 6.54 -1.20 -0.125 0.20523E+04 15 albite-high 0.75 -0.59 -1.34 -0.103 0.22886E+04 16 albite -0.33 -0.59 -0.26 -0.020 0.44793E+03 19 spessartine 24.55 20.59 -3.96 -0.198 0.67685E+04 20 analcite 3.37 2.70 -0.67 -0.074 0.11446E+04 21 andalusite 5.06 1.64 -3.43 -0.343 0.58499E+04 22 andradite 39.09 34.84 -4.25 -0.221 0.72597E+04 26 annite 20.21 16.72 -3.49 -0.194 0.59544E+04 27 phlogopite 27.15 23.41 -3.74 -0.208 0.63866E+04 29 anorthite 12.80 9.05 -3.75 -0.288 0.64005E+04 35 aragonite 0.99 -3.69 -4.68 -1.560 0.79918E+04 36 brucite 12.58 8.61 -3.96 -0.793 0.67683E+04 37 calcite 0.83 -3.69 -4.53 -1.509 0.77304E+04 38 carnegieite-low 9.06 5.99 -3.07 -0.439 0.52475E+04 39 carnegieite-high 10.13 5.99 -4.14 -0.592 0.70744E+04 40 carpholite-Mg 8.65 6.96 -1.69 -0.113 0.28897E+04 41 carpholite-Fe 6.78 4.73 -2.05 -0.137 0.35053E+04 42 celadonite 5.40 2.89 -2.51 -0.148 0.42868E+04 43 celadonite-Fe 3.94 0.66 -3.28 -0.193 0.55922E+04 44 chrysotile 23.94 19.26 -4.68 -0.390 0.79932E+04 50 chloritoid-Mg 13.26 10.25 -3.01 -0.201 0.51433E+04 51 chloritoid-Fe 9.24 8.02 -1.22 -0.081 0.20792E+04 52 chloritoid-Mn 11.46 10.15 -1.32 -0.088 0.22477E+04 54 coesite -2.37 -3.29 -0.92 -0.307 0.15737E+04 59 corundum 8.43 4.93 -3.51 -0.319 0.59866E+04 61 cristobalite -2.55 -3.29 -0.74 -0.247 0.12666E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.46 -0.43 -0.072 0.73836E+03 67 diopside 16.22 12.73 -3.48 -0.348 0.59437E+04 68 hedenbergite 14.24 10.51 -3.74 -0.374 0.63825E+04 75 epidote 24.78 22.76 -2.01 -0.098 0.34396E+04 76 clinozoisite 22.92 18.93 -4.00 -0.182 0.68223E+04 77 epidote-Fe 29.94 26.60 -3.34 -0.174 0.57045E+04 78 fayalite 14.08 9.48 -4.60 -0.657 0.78556E+04 83 gibbsite 4.10 2.46 -1.63 -0.233 0.27895E+04 87 greenalite 16.19 12.57 -3.62 -0.302 0.61850E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.70 -1.55 -0.155 0.26476E+04 97 kalsilite 7.62 4.15 -3.47 -0.496 0.59250E+04 98 kaolinite -1.27 -1.65 -0.38 -0.035 0.65145E+03 99 kyanite 4.93 1.64 -3.30 -0.330 0.56267E+04 101 laumontite 2.97 2.47 -0.51 -0.034 0.86639E+03 102 lawsonite 9.68 9.05 -0.63 -0.042 0.10744E+04 103 leucite 4.17 0.86 -3.31 -0.331 0.56491E+04 105 lizardite 23.29 19.26 -4.03 -0.336 0.68835E+04 107 magnetite 20.13 18.98 -1.15 -0.094 0.19645E+04 108 minnesotaite 10.46 5.99 -4.47 -0.263 0.76339E+04 113 margarite 17.45 13.98 -3.48 -0.139 0.59341E+04 120 muscovite 2.68 2.50 -0.18 -0.011 0.31361E+03 122 nepheline 8.38 5.99 -2.39 -0.341 0.40754E+04 134 phlogopite-Na 29.73 25.25 -4.48 -0.249 0.76564E+04 136 prehnite 19.47 16.46 -3.00 -0.177 0.51299E+04 137 prehnite-Fe 22.59 20.30 -2.29 -0.138 0.39096E+04 138 pumpellyite-Fe 46.47 41.77 -4.70 -0.104 0.80224E+04 145 pyroxmangite 7.42 5.22 -2.20 -0.439 0.37505E+04 146 pyrophyllite -6.10 -8.24 -2.14 -0.134 0.36517E+04 147 quartz -2.98 -3.29 -0.31 -0.103 0.52761E+03 151 rhodochrosite -0.96 -5.89 -4.93 -1.643 0.84161E+04 152 rhodonite 7.46 5.22 -2.24 -0.449 0.38297E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.64 -3.69 -0.369 0.62921E+04 164 stilpnomelane-Fe 13.18 13.01 -0.17 -0.005 0.28709E+03 165 stilpnomelane-Mg 27.60 24.15 -3.44 -0.103 0.58819E+04 168 sudoite 21.22 17.21 -4.01 -0.129 0.68456E+04 171 talc 16.55 12.67 -3.88 -0.228 0.66239E+04 174 tephroite 18.11 13.73 -4.38 -0.626 0.74836E+04 177 topaz-H 4.67 1.64 -3.03 -0.276 0.51757E+04 178 tridymite -2.61 -3.29 -0.68 -0.225 0.11549E+04 187 wairakite 4.06 2.47 -1.59 -0.094 0.27172E+04 188 walstromite 11.53 7.41 -4.12 -0.823 0.70264E+04 189 wollastonite 10.48 7.41 -3.07 -0.614 0.52403E+04 190 pseudo-wollastonite 11.02 7.41 -3.61 -0.721 0.61589E+04 191 zoisite 22.96 18.93 -4.04 -0.184 0.68948E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.57 -3.01 -0.186 0.51426E+04 194 beidellite-H -2.24 -6.34 -4.10 -0.261 0.69947E+04 195 beidellite-K -1.44 -4.70 -3.26 -0.200 0.55664E+04 196 beidellite-Mg -1.71 -4.92 -3.21 -0.199 0.54804E+04 197 beidellite-Na -1.26 -4.09 -2.83 -0.173 0.48329E+04 199 chalcedony -2.79 -3.29 -0.50 -0.166 0.84792E+03 201 montmorillonite-Ca -2.21 -4.44 -2.23 -0.138 0.38031E+04 202 montmorillonite-K -2.16 -4.56 -2.40 -0.147 0.41046E+04 203 montmorillonite-Mg -2.40 -4.79 -2.38 -0.148 0.40719E+04 204 montmorillonite-Na -1.96 -3.96 -2.00 -0.122 0.34093E+04 205 nontronite-Ca 3.28 3.10 -0.18 -0.012 0.30881E+03 206 nontronite-H 2.60 1.33 -1.26 -0.085 0.21567E+04 207 nontronite-K 3.40 2.98 -0.43 -0.028 0.73176E+03 208 nontronite-Mg 3.14 2.75 -0.39 -0.025 0.65822E+03 224 tobermorite 9.84 5.63 -4.21 -1.150 0.71948E+04 233 boehmite 4.43 2.46 -1.97 -0.328 0.33568E+04 235 ferrous-oxide 9.82 6.38 -3.44 -0.860 0.58730E+04 240 silica-amorphous -2.08 -3.29 -1.21 -0.404 0.20681E+04 242 an20ab80 2.08 1.34 -0.74 -0.057 0.12668E+04 243 an25ab75 2.71 1.82 -0.89 -0.068 0.15195E+04 244 an30ab70 3.34 2.30 -1.04 -0.080 0.17805E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 2.4990000 g New total amount of reactant added: 2.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4567E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2.5990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9995E+00 Moles total = 0.5548E+02 kg total = 0.9994E+00 Activity = 1.0000 Stoichiometric ionic strength = .1982062E-02 Osmotic coef. = 0.9750 True ionic strength = .3250988E-02 Chg. balance for total moles = 0.4567E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.44612E-09 -9.3506 0.40810E-09 -9.3892 0.91479E+00 -0.0387 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13792E-03 -3.8604 0.12601E-03 -3.8996 0.91363E+00 -0.0392 4 SO4-- 0.25504E-04 -4.5934 0.18800E-04 -4.7258 0.73714E+00 -0.1325 5 HCO3- 0.10202E-04 -4.9913 0.93232E-05 -5.0304 0.91391E+00 -0.0391 6 HS- 0.44500E-13 -13.3516 0.40658E-13 -13.3909 0.91366E+00 -0.0392 7 Al+++ 0.37748E-25 -25.4231 0.19381E-25 -25.7126 0.51342E+00 -0.2895 8 H4SiO4 0.50920E-03 -3.2931 0.50920E-03 -3.2931 0.10000E+01 0.0000 9 Ca++ 0.12316E-07 -7.9095 0.90648E-08 -8.0426 0.73601E+00 -0.1331 10 Mg++ 0.93854E-10 -10.0275 0.69011E-10 -10.1611 0.73531E+00 -0.1335 11 Fe++ 0.55501E-12 -12.2557 0.40820E-12 -12.3891 0.73548E+00 -0.1334 12 K+ 0.43886E-04 -4.3577 0.40110E-04 -4.3967 0.91396E+00 -0.0391 13 Na+ 0.31681E-02 -2.4992 0.28944E-02 -2.5384 0.91360E+00 -0.0392 14 Mn++ 0.74152E-10 -10.1299 0.54546E-10 -10.2632 0.73560E+00 -0.1334 15 HPO4-- 0.10510E-04 -4.9784 0.77477E-05 -5.1108 0.73716E+00 -0.1324 16 HSiO3- 0.13324E-02 -2.8754 0.12174E-02 -2.9146 0.91363E+00 -0.0392 17 Ca(HSiO3)+ 0.27051E-09 -9.5678 0.24724E-09 -9.6069 0.91400E+00 -0.0391 18 Mg(HSiO3)+ 0.25630E-11 -11.5913 0.23425E-11 -11.6303 0.91400E+00 -0.0391 19 NaHSiO3,aq 0.55961E-04 -4.2521 0.55961E-04 -4.2521 0.10000E+01 0.0000 20 AlO+ 0.16436E-13 -13.7842 0.15023E-13 -13.8233 0.91400E+00 -0.0391 21 AlOH+2 0.41741E-19 -19.3794 0.30711E-19 -19.5127 0.73575E+00 -0.1333 22 HAlO2,aq 0.73662E-08 -8.1328 0.73662E-08 -8.1328 0.10000E+01 0.0000 23 AlO2- 0.44130E-04 -4.3553 0.40303E-04 -4.3947 0.91328E+00 -0.0394 24 CH4,aq 0.19797E-19 -19.7034 0.19785E-19 -19.7037 0.99939E+00 -0.0003 29 CO,aq 0.11289E-18 -18.9473 0.11289E-18 -18.9473 0.10000E+01 0.0000 30 CO2,aq 0.76761E-08 -8.1149 0.76713E-08 -8.1151 0.99939E+00 -0.0003 31 CO3-2 0.28668E-05 -5.5426 0.21123E-05 -5.6753 0.73681E+00 -0.1326 32 CaCO3,aq 0.23451E-09 -9.6298 0.23451E-09 -9.6298 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.23299E-11 -11.6327 0.21295E-11 -11.6717 0.91400E+00 -0.0391 34 CaCl+ 0.19914E-11 -11.7008 0.18202E-11 -11.7399 0.91400E+00 -0.0391 35 CaCl2,aq 0.53402E-16 -16.2724 0.53402E-16 -16.2724 0.10000E+01 0.0000 36 CaOH+ 0.17136E-08 -8.7661 0.15662E-08 -8.8051 0.91400E+00 -0.0391 37 CaSO4,aq 0.53098E-10 -10.2749 0.53098E-10 -10.2749 0.10000E+01 0.0000 38 HCl,aq 0.96728E-14 -14.0144 0.96728E-14 -14.0144 0.10000E+01 0.0000 43 FeCl+ 0.87651E-16 -16.0572 0.80113E-16 -16.0963 0.91400E+00 -0.0391 46 FeO,aq 0.96920E-10 -10.0136 0.96920E-10 -10.0136 0.10000E+01 0.0000 47 FeOH+ 0.36280E-10 -10.4403 0.33160E-10 -10.4794 0.91400E+00 -0.0391 48 HFeO2- 0.27959E-08 -8.5535 0.25544E-08 -8.5927 0.91363E+00 -0.0392 49 FeO+ 0.36935E-14 -14.4326 0.33759E-14 -14.4716 0.91400E+00 -0.0391 51 FeO2- 0.43604E-08 -8.3605 0.39838E-08 -8.3997 0.91363E+00 -0.0392 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.57172E-09 -9.2428 0.57137E-09 -9.2431 0.99939E+00 -0.0003 54 KCl,aq 0.89493E-10 -10.0482 0.89493E-10 -10.0482 0.10000E+01 0.0000 55 KHSO4,aq 0.82350E-18 -18.0843 0.82350E-18 -18.0843 0.10000E+01 0.0000 56 KOH,aq 0.42847E-07 -7.3681 0.42847E-07 -7.3681 0.10000E+01 0.0000 57 KSO4- 0.12716E-07 -7.8957 0.11617E-07 -7.9349 0.91363E+00 -0.0392 58 MgCO3,aq 0.44612E-12 -12.3506 0.44612E-12 -12.3506 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18087E-13 -13.7426 0.16532E-13 -13.7817 0.91400E+00 -0.0391 60 MgCl+ 0.13763E-13 -13.8613 0.12580E-13 -13.9003 0.91400E+00 -0.0391 61 MgOH+ 0.72275E-10 -10.1410 0.66059E-10 -10.1801 0.91400E+00 -0.0391 63 MnO,aq 0.34573E-09 -9.4613 0.34573E-09 -9.4613 0.10000E+01 0.0000 64 MnOH+ 0.45037E-09 -9.3464 0.41163E-09 -9.3855 0.91400E+00 -0.0391 65 MnO2-2 0.97435E-13 -13.0113 0.71791E-13 -13.1439 0.73681E+00 -0.1326 66 HMnO2- 0.69479E-11 -11.1581 0.63478E-11 -11.1974 0.91363E+00 -0.0392 69 MnCl+ 0.45513E-13 -13.3419 0.41599E-13 -13.3809 0.91400E+00 -0.0391 70 MnSO4,aq 0.29062E-12 -12.5367 0.29062E-12 -12.5367 0.10000E+01 0.0000 71 NaCl,aq 0.11909E-06 -6.9241 0.11909E-06 -6.9241 0.10000E+01 0.0000 72 NaOH,aq 0.31164E-05 -5.5063 0.31164E-05 -5.5063 0.10000E+01 0.0000 74 OH- 0.16094E-02 -2.7933 0.14698E-02 -2.8327 0.91328E+00 -0.0394 79 HPO3-2 0.18977E-16 -16.7218 0.13982E-16 -16.8544 0.73681E+00 -0.1326 81 H2PO3- 0.12268E-19 -19.9112 0.11209E-19 -19.9504 0.91363E+00 -0.0392 82 H3PO4,aq 0.83073E-14 -14.0805 0.83073E-14 -14.0805 0.10000E+01 0.0000 83 H2PO4- 0.60662E-07 -7.2171 0.55434E-07 -7.2562 0.91381E+00 -0.0391 84 PO4-3 0.31959E-07 -7.4954 0.16579E-07 -7.7804 0.51877E+00 -0.2850 87 H2P2O7-2 0.32641E-15 -15.4862 0.24050E-15 -15.6189 0.73681E+00 -0.1326 88 HP2O7-3 0.23533E-12 -12.6283 0.12084E-12 -12.9178 0.51349E+00 -0.2895 89 P2O7-4 0.23431E-12 -12.6302 0.73048E-13 -13.1364 0.31176E+00 -0.5062 90 H2S,aq 0.49884E-16 -16.3020 0.49853E-16 -16.3023 0.99939E+00 -0.0003 97 SO3-2 0.19817E-14 -14.7030 0.14646E-14 -14.8343 0.73906E+00 -0.1313 98 HSO3- 0.38286E-16 -16.4170 0.34979E-16 -16.4562 0.91363E+00 -0.0392 99 HSO4- 0.77871E-11 -11.1086 0.71188E-11 -11.1476 0.91418E+00 -0.0390 Charge balance for all species = 0.5691E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4461170E-09 -.3180326E-02 -.3204717E+01 0.0000 2 H2O 0.1000000E+01 0.5550856E+02 0.9997346E+06 0.0000 3 Cl- 0.1379207E-03 0.1380398E-03 0.4892611E+01 5.4896 4 SO4-- 0.2550383E-04 0.2551703E-04 0.2450548E+01 14.0526 5 HCO3- 0.1020152E-04 0.1307622E-04 0.7976599E+00 4.3588 6 HS- 0.4449982E-13 -.4275131E-09 -.1413491E-04 -4.0016 7 Al+++ 0.3774819E-25 0.4413739E-04 0.1190573E+01 2.4551 8 H4SiO4 0.5091967E-03 0.1897594E-02 0.1823390E+03 -3.2931 9 Ca++ 0.1231613E-07 0.1459218E-07 0.5846683E-03 10.7358 10 Mg++ 0.9385363E-10 0.1691693E-09 0.4111738E-05 8.6174 11 Fe++ 0.5550110E-12 0.7493567E-08 0.4183808E-03 6.3893 12 K+ 0.4388649E-04 0.4394214E-04 0.1717764E+01 4.9925 13 Na+ 0.3168084E-02 0.3227281E-02 0.7417461E+02 6.8508 14 Mn++ 0.7415188E-10 0.8776320E-09 0.4820239E-04 8.5152 15 HPO4-- 0.1051018E-04 0.1060280E-04 0.1017373E+01 13.6676 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4302254E-01 -.3178814E-02 -.3984373E-01 0.0000000E+00 2 H2O 0.5547567E+02 0.5548216E+02 -.6488699E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9753162E-04 0.2550490E-04 0.7202672E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7202715E-04 -.4273097E-09 -.7202672E-04 0.0000000E+00 7 Al+++ 0.8474667E-02 0.4411639E-04 0.8430551E-02 0.0000000E+00 8 H4SiO4 0.2706282E-01 0.1896692E-02 0.2516613E-01 0.0000000E+00 9 Ca++ 0.3003692E-02 0.1458524E-07 0.3003677E-02 0.0000000E+00 10 Mg++ 0.2062698E-02 0.1690888E-09 0.2062698E-02 0.0000000E+00 11 Fe++ 0.1853109E-02 0.7490003E-08 0.1853102E-02 0.0000000E+00 12 K+ 0.5518047E-03 0.4392124E-04 0.5078834E-03 0.0000000E+00 13 Na+ 0.3422449E-02 0.3225746E-02 0.1967031E-03 0.0000000E+00 14 Mn++ 0.4506301E-04 0.8772145E-09 0.4506213E-04 0.0000000E+00 15 HPO4-- 0.1537978E-04 0.1059776E-04 0.4782025E-05 0.0000000E+00 Chg. balance for solid moles: 0.9385E-18 Mass of aqueous solution: 0.999793E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1594E-05 -5.798 0.8007E-03 -3.097 0.2865E-01 0.2544E-03 clinochlore 0.4125E-03 -3.385 0.2293 -0.640 8.204 0.8722E-01 daphnite 0.2554E-03 -3.593 0.1822 -0.739 6.519 0.5522E-01 chlorite-Mn 0.9012E-05 -5.045 0.6390E-02 -2.195 0.2286 0.2036E-02 hematite 0.2688E-03 -3.571 0.4293E-01 -1.367 1.536 0.8138E-02 microcline 0.5079E-03 -3.294 0.1414 -0.850 5.058 0.5522E-01 paragonite 0.1903E-03 -3.720 0.7275E-01 -1.138 2.603 0.2515E-01 stilbite 0.2996E-02 -2.524 2.111 0.325 75.53 0.9847 nontronite-Na 0.1927E-04 -4.715 0.8193E-02 -2.087 0.2931 0.2545E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.795083 g Volume = 1.220449 cm3 Porosity: 40.1624% V(tot) - V(min): 0.81915E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.5990000 g log = 0.4148 Original solution: 1000.0103000 g Original solution / Rock added: 384.77 (Water/Rock Ratio), log = 2.5852 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.8287E-06 1.0073 0.8781E-06 0.8717E-06 CH4,gas 0.2936E-16 1.0129 0.3129E-16 0.3089E-16 H2,gas 0.7446E-06 1.0006 0.7837E-06 0.7832E-06 H2S,gas 0.1388E-14 0.9959 0.1454E-14 0.1460E-14 S2,gas 0.1226E-36 1.0000 0.1289E-36 0.1289E-36 CO,gas 0.1695E-15 1.0000 0.1783E-15 0.1783E-15 SO3,gas 0.1113E-38 1.0000 0.1171E-38 0.1171E-38 SO2,gas 0.3299E-22 1.0000 0.3470E-22 0.3470E-22 HCl,gas 0.1624E-16 1.0000 0.1708E-16 0.1708E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 0.43980E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.11374E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.42 -8.06 -2.685 0.13756E+05 -6.056 3 CH4,gas 4.81 -13.70 -18.50 -4.626 0.31596E+05 -16.505 4 H2,gas 8.29 0.18 -8.11 -4.632 0.13841E+05 -6.106 5 H2S,gas -5.94 -22.78 -16.84 -8.419 0.28749E+05 -14.837 6 S2,gas -7.03 -45.92 -38.89 -5.983 0.66403E+05 -36.890 7 CO,gas 3.51 -14.24 -17.75 -5.461 0.30306E+05 -15.749 8 SO3,gas 17.43 -23.50 -40.93 -10.233 0.69890E+05 -38.932 9 SO2,gas 1.14 -23.32 -24.46 -6.523 0.41764E+05 -22.460 10 HCl,gas 5.48 -13.29 -18.77 -9.384 0.32045E+05 -16.768 11 acmite 7.74 6.56 -1.17 -0.122 0.20046E+04 15 albite-high 0.75 -0.57 -1.32 -0.102 0.22592E+04 16 albite -0.33 -0.57 -0.25 -0.019 0.41856E+03 19 spessartine 24.55 20.58 -3.97 -0.199 0.67845E+04 20 analcite 3.37 2.72 -0.65 -0.072 0.11116E+04 21 andalusite 5.06 1.62 -3.45 -0.345 0.58829E+04 22 andradite 39.09 34.93 -4.16 -0.216 0.71065E+04 26 annite 20.21 16.74 -3.47 -0.193 0.59303E+04 27 phlogopite 27.15 23.42 -3.73 -0.207 0.63625E+04 29 anorthite 12.80 9.06 -3.74 -0.288 0.63825E+04 35 aragonite 0.99 -3.68 -4.67 -1.557 0.79740E+04 36 brucite 12.58 8.62 -3.96 -0.792 0.67603E+04 37 calcite 0.83 -3.68 -4.52 -1.506 0.77127E+04 38 carnegieite-low 9.06 6.01 -3.05 -0.436 0.52109E+04 39 carnegieite-high 10.13 6.01 -4.12 -0.589 0.70378E+04 40 carpholite-Mg 8.65 6.94 -1.71 -0.114 0.29182E+04 41 carpholite-Fe 6.78 4.71 -2.07 -0.138 0.35339E+04 42 celadonite 5.40 2.89 -2.51 -0.148 0.42824E+04 43 celadonite-Fe 3.94 0.66 -3.27 -0.193 0.55877E+04 44 chrysotile 23.94 19.27 -4.67 -0.389 0.79763E+04 50 chloritoid-Mg 13.26 10.23 -3.03 -0.202 0.51683E+04 51 chloritoid-Fe 9.24 8.01 -1.23 -0.082 0.21042E+04 52 chloritoid-Mn 11.46 10.13 -1.33 -0.089 0.22726E+04 54 coesite -2.37 -3.29 -0.92 -0.308 0.15773E+04 59 corundum 8.43 4.91 -3.52 -0.320 0.60159E+04 61 cristobalite -2.55 -3.29 -0.74 -0.248 0.12702E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.46 -0.44 -0.074 0.75304E+03 67 diopside 16.22 12.77 -3.45 -0.345 0.58882E+04 68 hedenbergite 14.24 10.54 -3.71 -0.371 0.63270E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33705E+04 76 clinozoisite 22.92 18.96 -3.96 -0.180 0.67678E+04 77 epidote-Fe 29.94 26.64 -3.29 -0.171 0.56207E+04 78 fayalite 14.08 9.49 -4.59 -0.656 0.78431E+04 79 ferrosilite 11.19 6.19 -5.00 -0.500 0.85293E+04 83 gibbsite 4.10 2.46 -1.64 -0.235 0.28042E+04 84 glaucophane 23.11 18.12 -4.99 -0.135 0.85230E+04 87 greenalite 16.19 12.58 -3.61 -0.301 0.61682E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.72 -1.53 -0.153 0.26146E+04 97 kalsilite 7.62 4.15 -3.47 -0.495 0.59178E+04 98 kaolinite -1.27 -1.68 -0.40 -0.037 0.68805E+03 99 kyanite 4.93 1.62 -3.31 -0.331 0.56596E+04 101 laumontite 2.97 2.47 -0.50 -0.033 0.85554E+03 102 lawsonite 9.68 9.06 -0.62 -0.041 0.10563E+04 103 leucite 4.17 0.86 -3.31 -0.331 0.56454E+04 105 lizardite 23.29 19.27 -4.02 -0.335 0.68666E+04 107 magnetite 20.13 18.99 -1.15 -0.094 0.19565E+04 108 minnesotaite 10.46 6.00 -4.47 -0.263 0.76242E+04 113 margarite 17.45 13.97 -3.48 -0.139 0.59454E+04 120 muscovite 2.68 2.48 -0.20 -0.012 0.34297E+03 122 nepheline 8.38 6.01 -2.37 -0.338 0.40388E+04 134 phlogopite-Na 29.73 25.28 -4.45 -0.247 0.76029E+04 136 prehnite 19.47 16.50 -2.96 -0.174 0.50608E+04 137 prehnite-Fe 22.59 20.35 -2.24 -0.135 0.38258E+04 138 pumpellyite-Fe 46.47 41.85 -4.62 -0.103 0.78908E+04 145 pyroxmangite 7.42 5.22 -2.19 -0.439 0.37461E+04 146 pyrophyllite -6.10 -8.26 -2.16 -0.135 0.36955E+04 147 quartz -2.98 -3.29 -0.31 -0.104 0.53122E+03 151 rhodochrosite -0.96 -5.90 -4.95 -1.649 0.84450E+04 152 rhodonite 7.46 5.22 -2.24 -0.448 0.38253E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.62 -3.70 -0.370 0.63250E+04 164 stilpnomelane-Fe 13.18 13.01 -0.17 -0.005 0.29240E+03 165 stilpnomelane-Mg 27.60 24.15 -3.45 -0.103 0.58872E+04 168 sudoite 21.22 17.18 -4.04 -0.130 0.68991E+04 171 talc 16.55 12.68 -3.87 -0.228 0.66142E+04 174 tephroite 18.11 13.74 -4.38 -0.625 0.74712E+04 177 topaz-H 4.67 1.62 -3.05 -0.277 0.52087E+04 178 tridymite -2.61 -3.29 -0.68 -0.226 0.11585E+04 187 wairakite 4.06 2.47 -1.59 -0.093 0.27064E+04 188 walstromite 11.53 7.44 -4.09 -0.817 0.69753E+04 189 wollastonite 10.48 7.44 -3.04 -0.608 0.51892E+04 190 pseudo-wollastonite 11.02 7.44 -3.58 -0.715 0.61078E+04 191 zoisite 22.96 18.96 -4.01 -0.182 0.68404E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.59 -3.03 -0.188 0.51811E+04 194 beidellite-H -2.24 -6.37 -4.12 -0.263 0.70422E+04 195 beidellite-K -1.44 -4.72 -3.28 -0.201 0.56054E+04 196 beidellite-Mg -1.71 -4.94 -3.24 -0.200 0.55265E+04 197 beidellite-Na -1.26 -4.10 -2.85 -0.174 0.48623E+04 199 chalcedony -2.79 -3.29 -0.50 -0.166 0.85154E+03 201 montmorillonite-Ca -2.21 -4.46 -2.24 -0.139 0.38304E+04 202 montmorillonite-K -2.16 -4.58 -2.42 -0.148 0.41325E+04 203 montmorillonite-Mg -2.40 -4.81 -2.41 -0.149 0.41069E+04 204 montmorillonite-Na -1.96 -3.97 -2.01 -0.123 0.34276E+04 205 nontronite-Ca 3.28 3.09 -0.19 -0.012 0.31791E+03 206 nontronite-H 2.60 1.32 -1.27 -0.085 0.21748E+04 207 nontronite-K 3.40 2.97 -0.43 -0.028 0.74145E+03 208 nontronite-Mg 3.14 2.74 -0.40 -0.026 0.67500E+03 224 tobermorite 9.84 5.65 -4.19 -1.143 0.71529E+04 233 boehmite 4.43 2.46 -1.97 -0.329 0.33715E+04 235 ferrous-oxide 9.82 6.39 -3.43 -0.859 0.58650E+04 240 silica-amorphous -2.08 -3.29 -1.21 -0.404 0.20717E+04 242 an20ab80 2.08 1.35 -0.73 -0.056 0.12397E+04 243 an25ab75 2.71 1.83 -0.87 -0.067 0.14929E+04 244 an30ab70 3.34 2.32 -1.03 -0.079 0.17545E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 2.5990000 g New total amount of reactant added: 2.6990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4566E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2.6990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9995E+00 Moles total = 0.5547E+02 kg total = 0.9994E+00 Activity = 1.0000 Stoichiometric ionic strength = .2042797E-02 Osmotic coef. = 0.9746 True ionic strength = .3361623E-02 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.42998E-09 -9.3666 0.39291E-09 -9.4057 0.91379E+00 -0.0392 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13792E-03 -3.8604 0.12586E-03 -3.9001 0.91260E+00 -0.0397 4 SO4-- 0.25504E-04 -4.5934 0.18717E-04 -4.7278 0.73387E+00 -0.1344 5 HCO3- 0.10109E-04 -4.9953 0.92279E-05 -5.0349 0.91288E+00 -0.0396 6 HS- 0.46423E-13 -13.3333 0.42367E-13 -13.3730 0.91263E+00 -0.0397 7 Al+++ 0.33386E-25 -25.4764 0.16969E-25 -25.7703 0.50828E+00 -0.2939 8 H4SiO4 0.50681E-03 -3.2952 0.50681E-03 -3.2952 0.10000E+01 0.0000 9 Ca++ 0.12311E-07 -7.9097 0.90206E-08 -8.0448 0.73272E+00 -0.1351 10 Mg++ 0.88307E-10 -10.0540 0.64640E-10 -10.1895 0.73199E+00 -0.1355 11 Fe++ 0.52221E-12 -12.2822 0.38234E-12 -12.4175 0.73217E+00 -0.1354 12 K+ 0.43726E-04 -4.3593 0.39919E-04 -4.3988 0.91294E+00 -0.0396 13 Na+ 0.32792E-02 -2.4842 0.29925E-02 -2.5240 0.91257E+00 -0.0397 14 Mn++ 0.69769E-10 -10.1563 0.51092E-10 -10.2917 0.73230E+00 -0.1353 15 HPO4-- 0.10118E-04 -4.9949 0.74258E-05 -5.1293 0.73389E+00 -0.1344 16 HSiO3- 0.13790E-02 -2.8604 0.12585E-02 -2.9001 0.91260E+00 -0.0397 17 Ca(HSiO3)+ 0.27860E-09 -9.5550 0.25436E-09 -9.5946 0.91298E+00 -0.0395 18 Mg(HSiO3)+ 0.24845E-11 -11.6048 0.22683E-11 -11.6443 0.91298E+00 -0.0395 19 NaHSiO3,aq 0.59814E-04 -4.2232 0.59814E-04 -4.2232 0.10000E+01 0.0000 20 AlO+ 0.15543E-13 -13.8085 0.14190E-13 -13.8480 0.91298E+00 -0.0395 21 AlOH+2 0.38132E-19 -19.4187 0.27930E-19 -19.5539 0.73245E+00 -0.1352 22 HAlO2,aq 0.72271E-08 -8.1410 0.72271E-08 -8.1410 0.10000E+01 0.0000 23 AlO2- 0.45022E-04 -4.3466 0.41071E-04 -4.3865 0.91224E+00 -0.0399 24 CH4,aq 0.20509E-19 -19.6880 0.20496E-19 -19.6883 0.99937E+00 -0.0003 29 CO,aq 0.10985E-18 -18.9592 0.10985E-18 -18.9592 0.10000E+01 0.0000 30 CO2,aq 0.73149E-08 -8.1358 0.73103E-08 -8.1361 0.99937E+00 -0.0003 31 CO3-2 0.29603E-05 -5.5287 0.21715E-05 -5.6632 0.73353E+00 -0.1346 32 CaCO3,aq 0.23991E-09 -9.6200 0.23991E-09 -9.6200 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.22974E-11 -11.6388 0.20974E-11 -11.6783 0.91298E+00 -0.0395 34 CaCl+ 0.19817E-11 -11.7030 0.18092E-11 -11.7425 0.91298E+00 -0.0395 35 CaCl2,aq 0.53021E-16 -16.2756 0.53021E-16 -16.2756 0.10000E+01 0.0000 36 CaOH+ 0.17732E-08 -8.7512 0.16189E-08 -8.7908 0.91298E+00 -0.0395 37 CaSO4,aq 0.52606E-10 -10.2790 0.52606E-10 -10.2790 0.10000E+01 0.0000 38 HCl,aq 0.93021E-14 -14.0314 0.93021E-14 -14.0314 0.10000E+01 0.0000 43 FeCl+ 0.82097E-16 -16.0857 0.74953E-16 -16.1252 0.91298E+00 -0.0395 46 FeO,aq 0.97937E-10 -10.0091 0.97937E-10 -10.0091 0.10000E+01 0.0000 47 FeOH+ 0.35336E-10 -10.4518 0.32261E-10 -10.4913 0.91298E+00 -0.0395 48 HFeO2- 0.29378E-08 -8.5320 0.26810E-08 -8.5717 0.91260E+00 -0.0397 49 FeO+ 0.35600E-14 -14.4485 0.32502E-14 -14.4881 0.91298E+00 -0.0395 51 FeO2- 0.45342E-08 -8.3435 0.41379E-08 -8.3832 0.91260E+00 -0.0397 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.58380E-09 -9.2337 0.58343E-09 -9.2340 0.99937E+00 -0.0003 54 KCl,aq 0.88964E-10 -10.0508 0.88964E-10 -10.0508 0.10000E+01 0.0000 55 KHSO4,aq 0.78557E-18 -18.1048 0.78557E-18 -18.1048 0.10000E+01 0.0000 56 KOH,aq 0.44291E-07 -7.3537 0.44291E-07 -7.3537 0.10000E+01 0.0000 57 KSO4- 0.12613E-07 -7.8992 0.11511E-07 -7.9389 0.91260E+00 -0.0397 58 MgCO3,aq 0.42958E-12 -12.3670 0.42958E-12 -12.3670 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16787E-13 -13.7750 0.15326E-13 -13.8146 0.91298E+00 -0.0395 60 MgCl+ 0.12891E-13 -13.8897 0.11769E-13 -13.9292 0.91298E+00 -0.0395 61 MgOH+ 0.70393E-10 -10.1525 0.64267E-10 -10.1920 0.91298E+00 -0.0395 63 MnO,aq 0.34936E-09 -9.4567 0.34936E-09 -9.4567 0.10000E+01 0.0000 64 MnOH+ 0.43864E-09 -9.3579 0.40047E-09 -9.3974 0.91298E+00 -0.0395 65 MnO2-2 0.10669E-12 -12.9719 0.78263E-13 -13.1064 0.73353E+00 -0.1346 66 HMnO2- 0.73005E-11 -11.1366 0.66624E-11 -11.1764 0.91260E+00 -0.0397 69 MnCl+ 0.42630E-13 -13.3703 0.38920E-13 -13.4098 0.91298E+00 -0.0395 70 MnSO4,aq 0.27101E-12 -12.5670 0.27101E-12 -12.5670 0.10000E+01 0.0000 71 NaCl,aq 0.12298E-06 -6.9101 0.12298E-06 -6.9101 0.10000E+01 0.0000 72 NaOH,aq 0.33466E-05 -5.4754 0.33466E-05 -5.4754 0.10000E+01 0.0000 74 OH- 0.16735E-02 -2.7764 0.15266E-02 -2.8163 0.91224E+00 -0.0399 79 HPO3-2 0.18655E-16 -16.7292 0.13684E-16 -16.8638 0.73353E+00 -0.1346 81 H2PO3- 0.11573E-19 -19.9366 0.10561E-19 -19.9763 0.91260E+00 -0.0397 82 H3PO4,aq 0.73804E-14 -14.1319 0.73804E-14 -14.1319 0.10000E+01 0.0000 83 H2PO4- 0.56040E-07 -7.2515 0.51153E-07 -7.2911 0.91278E+00 -0.0396 84 PO4-3 0.32128E-07 -7.4931 0.16505E-07 -7.7824 0.51373E+00 -0.2893 87 H2P2O7-2 0.27918E-15 -15.5541 0.20479E-15 -15.6887 0.73353E+00 -0.1346 88 HP2O7-3 0.21024E-12 -12.6773 0.10687E-12 -12.9711 0.50835E+00 -0.2938 89 P2O7-4 0.21910E-12 -12.6594 0.67104E-13 -13.1733 0.30628E+00 -0.5139 90 H2S,aq 0.50047E-16 -16.3006 0.50015E-16 -16.3009 0.99937E+00 -0.0003 97 SO3-2 0.20235E-14 -14.6939 0.14889E-14 -14.8271 0.73584E+00 -0.1332 98 HSO3- 0.37515E-16 -16.4258 0.34236E-16 -16.4655 0.91260E+00 -0.0397 99 HSO4- 0.74724E-11 -11.1265 0.68236E-11 -11.1660 0.91316E+00 -0.0395 Charge balance for all species = 0.5636E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4299785E-09 -.3298813E-02 -.3324087E+01 0.0000 2 H2O 0.1000000E+01 0.5550858E+02 0.9997275E+06 0.0000 3 Cl- 0.1379192E-03 0.1380422E-03 0.4892660E+01 5.5056 4 SO4-- 0.2550438E-04 0.2551750E-04 0.2450575E+01 14.0836 5 HCO3- 0.1010854E-04 0.1307645E-04 0.7976679E+00 4.3708 6 HS- 0.4642290E-13 -.4462074E-09 -.1475290E-04 -3.9673 7 Al+++ 0.3338607E-25 0.4502948E-04 0.1214627E+01 2.4468 8 H4SiO4 0.5068118E-03 0.1945658E-02 0.1869560E+03 -3.2952 9 Ca++ 0.1231121E-07 0.1465978E-07 0.5873722E-03 10.7666 10 Mg++ 0.8830712E-10 0.1616441E-09 0.3928807E-05 8.6219 11 Fe++ 0.5222075E-12 0.7809237E-08 0.4360020E-03 6.3939 12 K+ 0.4372565E-04 0.4378264E-04 0.1711516E+01 5.0069 13 Na+ 0.3279178E-02 0.3342461E-02 0.7682129E+02 6.8817 14 Mn++ 0.6976889E-10 0.8654939E-09 0.4753537E-04 8.5198 15 HPO4-- 0.1011830E-04 0.1020647E-04 0.9793364E+00 13.6822 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4467839E-01 -.3297187E-02 -.4138121E-01 0.0000000E+00 2 H2O 0.5547442E+02 0.5548121E+02 -.6790730E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1003030E-03 0.2550492E-04 0.7479804E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7479849E-04 -.4459874E-09 -.7479804E-04 0.0000000E+00 7 Al+++ 0.8800742E-02 0.4500728E-04 0.8755734E-02 0.0000000E+00 8 H4SiO4 0.2810410E-01 0.1944699E-02 0.2615940E-01 0.0000000E+00 9 Ca++ 0.3118706E-02 0.1465255E-07 0.3118691E-02 0.0000000E+00 10 Mg++ 0.2142063E-02 0.1615644E-09 0.2142063E-02 0.0000000E+00 11 Fe++ 0.1924410E-02 0.7805386E-08 0.1924402E-02 0.0000000E+00 12 K+ 0.5730361E-03 0.4376105E-04 0.5292750E-03 0.0000000E+00 13 Na+ 0.3547974E-02 0.3340813E-02 0.2071604E-03 0.0000000E+00 14 Mn++ 0.4679687E-04 0.8650671E-09 0.4679601E-04 0.0000000E+00 15 HPO4-- 0.1597154E-04 0.1020144E-04 0.5770100E-05 0.0000000E+00 Chg. balance for solid moles: -.9555E-18 Mass of aqueous solution: 0.999783E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2.6990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.1923E-05 -5.716 0.9661E-03 -3.015 0.3327E-01 0.3070E-03 clinochlore 0.4284E-03 -3.368 0.2381 -0.623 8.199 0.9058E-01 daphnite 0.2652E-03 -3.576 0.1892 -0.723 6.515 0.5734E-01 chlorite-Mn 0.9359E-05 -5.029 0.6635E-02 -2.178 0.2285 0.2115E-02 hematite 0.2702E-03 -3.568 0.4315E-01 -1.365 1.486 0.8179E-02 microcline 0.5293E-03 -3.276 0.1473 -0.832 5.072 0.5755E-01 paragonite 0.1976E-03 -3.704 0.7552E-01 -1.122 2.600 0.2611E-01 stilbite 0.3109E-02 -2.507 2.191 0.341 75.44 1.022 nontronite-Na 0.2897E-04 -4.538 0.1232E-01 -1.909 0.4242 0.3828E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2.904295 g Volume = 1.267931 cm3 Porosity: 39.0300% V(tot) - V(min): 0.81167E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.6990000 g log = 0.4312 Original solution: 1000.0103000 g Original solution / Rock added: 370.51 (Water/Rock Ratio), log = 2.5688 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.7897E-06 1.0073 0.8368E-06 0.8307E-06 CH4,gas 0.3042E-16 1.0129 0.3241E-16 0.3200E-16 H2,gas 0.7603E-06 1.0006 0.8002E-06 0.7998E-06 H2S,gas 0.1392E-14 0.9959 0.1459E-14 0.1465E-14 S2,gas 0.1183E-36 1.0000 0.1245E-36 0.1245E-36 CO,gas 0.1649E-15 1.0000 0.1734E-15 0.1734E-15 SO3,gas 0.1027E-38 1.0000 0.1080E-38 0.1080E-38 SO2,gas 0.3109E-22 1.0000 0.3270E-22 0.3270E-22 HCl,gas 0.1561E-16 1.0000 0.1642E-16 0.1642E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 121 paragonite 4.34 4.34 0.00 0.000 0.19715E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 0.17440E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.44 -8.08 -2.692 0.13792E+05 -6.077 3 CH4,gas 4.81 -13.68 -18.49 -4.622 0.31570E+05 -16.489 4 H2,gas 8.29 0.19 -8.10 -4.627 0.13825E+05 -6.097 5 H2S,gas -5.94 -22.78 -16.84 -8.418 0.28747E+05 -14.836 6 S2,gas -7.03 -45.94 -38.90 -5.985 0.66429E+05 -36.905 7 CO,gas 3.51 -14.25 -17.76 -5.465 0.30326E+05 -15.761 8 SO3,gas 17.43 -23.54 -40.97 -10.242 0.69949E+05 -38.966 9 SO2,gas 1.14 -23.35 -24.49 -6.529 0.41808E+05 -22.485 10 HCl,gas 5.48 -13.31 -18.78 -9.392 0.32074E+05 -16.785 11 acmite 7.74 6.59 -1.15 -0.119 0.19587E+04 15 albite-high 0.75 -0.56 -1.31 -0.101 0.22309E+04 16 albite -0.33 -0.56 -0.23 -0.018 0.39029E+03 19 spessartine 24.55 20.57 -3.98 -0.199 0.68000E+04 20 analcite 3.37 2.74 -0.63 -0.070 0.10798E+04 21 andalusite 5.06 1.60 -3.46 -0.346 0.59146E+04 22 andradite 39.09 35.01 -4.08 -0.212 0.69590E+04 26 annite 20.21 16.75 -3.46 -0.192 0.59070E+04 27 phlogopite 27.15 23.43 -3.71 -0.206 0.63392E+04 29 anorthite 12.80 9.07 -3.73 -0.287 0.63651E+04 35 aragonite 0.99 -3.67 -4.66 -1.553 0.79571E+04 36 brucite 12.58 8.62 -3.95 -0.791 0.67525E+04 37 calcite 0.83 -3.67 -4.51 -1.502 0.76958E+04 38 carnegieite-low 9.06 6.03 -3.03 -0.433 0.51757E+04 39 carnegieite-high 10.13 6.03 -4.10 -0.586 0.70025E+04 40 carpholite-Mg 8.65 6.93 -1.73 -0.115 0.29457E+04 41 carpholite-Fe 6.78 4.70 -2.09 -0.139 0.35614E+04 42 celadonite 5.40 2.89 -2.51 -0.147 0.42781E+04 43 celadonite-Fe 3.94 0.67 -3.27 -0.192 0.55835E+04 44 chrysotile 23.94 19.28 -4.66 -0.388 0.79601E+04 50 chloritoid-Mg 13.26 10.22 -3.04 -0.203 0.51923E+04 51 chloritoid-Fe 9.24 7.99 -1.25 -0.083 0.21282E+04 52 chloritoid-Mn 11.46 10.12 -1.35 -0.090 0.22966E+04 54 coesite -2.37 -3.30 -0.93 -0.309 0.15808E+04 59 corundum 8.43 4.89 -3.54 -0.322 0.60442E+04 61 cristobalite -2.55 -3.30 -0.75 -0.249 0.12737E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.45 -0.45 -0.075 0.76718E+03 67 diopside 16.22 12.80 -3.42 -0.342 0.58348E+04 68 hedenbergite 14.24 10.57 -3.67 -0.367 0.62736E+04 75 epidote 24.78 22.84 -1.93 -0.094 0.33039E+04 76 clinozoisite 22.92 18.99 -3.93 -0.179 0.67154E+04 77 epidote-Fe 29.94 26.69 -3.24 -0.169 0.55400E+04 78 fayalite 14.08 9.49 -4.59 -0.655 0.78311E+04 79 ferrosilite 11.19 6.20 -4.99 -0.499 0.85207E+04 83 gibbsite 4.10 2.45 -1.65 -0.236 0.28184E+04 84 glaucophane 23.11 18.16 -4.95 -0.134 0.84502E+04 87 greenalite 16.19 12.59 -3.60 -0.300 0.61519E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.74 -1.51 -0.151 0.25829E+04 97 kalsilite 7.62 4.16 -3.46 -0.495 0.59108E+04 98 kaolinite -1.27 -1.70 -0.42 -0.039 0.72328E+03 99 kyanite 4.93 1.60 -3.33 -0.333 0.56914E+04 101 laumontite 2.97 2.48 -0.49 -0.033 0.84510E+03 102 lawsonite 9.68 9.07 -0.61 -0.041 0.10389E+04 103 leucite 4.17 0.86 -3.30 -0.330 0.56420E+04 105 lizardite 23.29 19.28 -4.01 -0.334 0.68504E+04 107 magnetite 20.13 18.99 -1.14 -0.093 0.19487E+04 108 minnesotaite 10.46 6.00 -4.46 -0.262 0.76149E+04 113 margarite 17.45 13.96 -3.49 -0.140 0.59562E+04 120 muscovite 2.68 2.46 -0.22 -0.013 0.37124E+03 122 nepheline 8.38 6.03 -2.34 -0.335 0.40036E+04 134 phlogopite-Na 29.73 25.31 -4.42 -0.246 0.75514E+04 136 prehnite 19.47 16.54 -2.92 -0.172 0.49942E+04 137 prehnite-Fe 22.59 20.39 -2.19 -0.132 0.37451E+04 138 pumpellyite-Fe 46.47 41.92 -4.55 -0.101 0.77640E+04 145 pyroxmangite 7.42 5.22 -2.19 -0.438 0.37418E+04 146 pyrophyllite -6.10 -8.29 -2.19 -0.137 0.37377E+04 147 quartz -2.98 -3.30 -0.31 -0.104 0.53470E+03 151 rhodochrosite -0.96 -5.92 -4.96 -1.654 0.84730E+04 152 rhodonite 7.46 5.22 -2.24 -0.448 0.38210E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.60 -3.72 -0.372 0.63568E+04 164 stilpnomelane-Fe 13.18 13.01 -0.17 -0.005 0.29752E+03 165 stilpnomelane-Mg 27.60 24.15 -3.45 -0.103 0.58923E+04 168 sudoite 21.22 17.15 -4.07 -0.131 0.69506E+04 171 talc 16.55 12.69 -3.87 -0.228 0.66049E+04 174 tephroite 18.11 13.74 -4.37 -0.624 0.74592E+04 177 topaz-H 4.67 1.60 -3.07 -0.279 0.52405E+04 178 tridymite -2.61 -3.30 -0.68 -0.227 0.11620E+04 187 wairakite 4.06 2.48 -1.58 -0.093 0.26959E+04 188 walstromite 11.53 7.47 -4.06 -0.811 0.69261E+04 189 wollastonite 10.48 7.47 -3.01 -0.602 0.51400E+04 190 pseudo-wollastonite 11.02 7.47 -3.55 -0.710 0.60587E+04 191 zoisite 22.96 18.99 -3.98 -0.181 0.67880E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.62 -3.06 -0.189 0.52181E+04 194 beidellite-H -2.24 -6.39 -4.15 -0.265 0.70879E+04 195 beidellite-K -1.44 -4.74 -3.30 -0.202 0.56430E+04 196 beidellite-Mg -1.71 -4.97 -3.26 -0.202 0.55710E+04 197 beidellite-Na -1.26 -4.12 -2.86 -0.175 0.48906E+04 199 chalcedony -2.79 -3.30 -0.50 -0.167 0.85502E+03 201 montmorillonite-Ca -2.21 -4.47 -2.26 -0.140 0.38567E+04 202 montmorillonite-K -2.16 -4.60 -2.44 -0.149 0.41594E+04 203 montmorillonite-Mg -2.40 -4.83 -2.43 -0.150 0.41406E+04 204 montmorillonite-Na -1.96 -3.98 -2.02 -0.124 0.34451E+04 205 nontronite-Ca 3.28 3.09 -0.19 -0.012 0.32666E+03 206 nontronite-H 2.60 1.31 -1.28 -0.086 0.21922E+04 207 nontronite-K 3.40 2.96 -0.44 -0.028 0.75078E+03 208 nontronite-Mg 3.14 2.73 -0.40 -0.026 0.69117E+03 224 tobermorite 9.84 5.67 -4.17 -1.137 0.71125E+04 233 boehmite 4.43 2.45 -1.98 -0.330 0.33856E+04 235 ferrous-oxide 9.82 6.39 -3.43 -0.858 0.58572E+04 240 silica-amorphous -2.08 -3.30 -1.22 -0.405 0.20752E+04 242 an20ab80 2.08 1.37 -0.71 -0.055 0.12136E+04 243 an25ab75 2.71 1.85 -0.86 -0.066 0.14674E+04 244 an30ab70 3.34 2.33 -1.01 -0.078 0.17295E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 2.6990000 g New total amount of reactant added: 2.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4566E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2.7990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9995E+00 Moles total = 0.5547E+02 kg total = 0.9994E+00 Activity = 1.0000 Stoichiometric ionic strength = .2103541E-02 Osmotic coef. = 0.9743 True ionic strength = .3472218E-02 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.41500E-09 -9.3820 0.37882E-09 -9.4216 0.91282E+00 -0.0396 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13792E-03 -3.8604 0.12572E-03 -3.9006 0.91159E+00 -0.0402 4 SO4-- 0.25505E-04 -4.5934 0.18636E-04 -4.7296 0.73068E+00 -0.1363 5 HCO3- 0.10017E-04 -4.9993 0.91342E-05 -5.0393 0.91188E+00 -0.0401 6 HS- 0.48355E-13 -13.3156 0.44081E-13 -13.3557 0.91162E+00 -0.0402 7 Al+++ 0.29668E-25 -25.5277 0.14931E-25 -25.8259 0.50328E+00 -0.2982 8 H4SiO4 0.50452E-03 -3.2971 0.50452E-03 -3.2971 0.10000E+01 0.0000 9 Ca++ 0.12309E-07 -7.9098 0.89791E-08 -8.0468 0.72950E+00 -0.1370 10 Mg++ 0.83285E-10 -10.0794 0.60694E-10 -10.2169 0.72876E+00 -0.1374 11 Fe++ 0.49250E-12 -12.3076 0.35900E-12 -12.4449 0.72893E+00 -0.1373 12 K+ 0.43574E-04 -4.3608 0.39737E-04 -4.4008 0.91193E+00 -0.0400 13 Na+ 0.33902E-02 -2.4698 0.30904E-02 -2.5100 0.91156E+00 -0.0402 14 Mn++ 0.65800E-10 -10.1818 0.47973E-10 -10.3190 0.72907E+00 -0.1372 15 HPO4-- 0.97541E-05 -5.0108 0.71274E-05 -5.1471 0.73071E+00 -0.1363 16 HSiO3- 0.14255E-02 -2.8460 0.12994E-02 -2.8862 0.91159E+00 -0.0402 17 Ca(HSiO3)+ 0.28665E-09 -9.5426 0.26142E-09 -9.5827 0.91198E+00 -0.0400 18 Mg(HSiO3)+ 0.24114E-11 -11.6177 0.21991E-11 -11.6578 0.91198E+00 -0.0400 19 NaHSiO3,aq 0.63779E-04 -4.1953 0.63779E-04 -4.1953 0.10000E+01 0.0000 20 AlO+ 0.14729E-13 -13.8318 0.13432E-13 -13.8719 0.91198E+00 -0.0400 21 AlOH+2 0.34954E-19 -19.4565 0.25489E-19 -19.5936 0.72923E+00 -0.1371 22 HAlO2,aq 0.70955E-08 -8.1490 0.70955E-08 -8.1490 0.10000E+01 0.0000 23 AlO2- 0.45898E-04 -4.3382 0.41823E-04 -4.3786 0.91122E+00 -0.0404 24 CH4,aq 0.21215E-19 -19.6734 0.21201E-19 -19.6736 0.99935E+00 -0.0003 29 CO,aq 0.10696E-18 -18.9708 0.10696E-18 -18.9708 0.10000E+01 0.0000 30 CO2,aq 0.69810E-08 -8.1561 0.69764E-08 -8.1564 0.99935E+00 -0.0003 31 CO3-2 0.30526E-05 -5.5153 0.22294E-05 -5.6518 0.73033E+00 -0.1365 32 CaCO3,aq 0.24517E-09 -9.6105 0.24517E-09 -9.6105 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.22660E-11 -11.6447 0.20666E-11 -11.6847 0.91198E+00 -0.0400 34 CaCl+ 0.19725E-11 -11.7050 0.17989E-11 -11.7450 0.91198E+00 -0.0400 35 CaCl2,aq 0.52659E-16 -16.2785 0.52659E-16 -16.2785 0.10000E+01 0.0000 36 CaOH+ 0.18327E-08 -8.7369 0.16714E-08 -8.7769 0.91198E+00 -0.0400 37 CaSO4,aq 0.52138E-10 -10.2828 0.52138E-10 -10.2828 0.10000E+01 0.0000 38 HCl,aq 0.89584E-14 -14.0478 0.89584E-14 -14.0478 0.10000E+01 0.0000 43 FeCl+ 0.77084E-16 -16.1130 0.70299E-16 -16.1531 0.91198E+00 -0.0400 46 FeO,aq 0.98928E-10 -10.0047 0.98928E-10 -10.0047 0.10000E+01 0.0000 47 FeOH+ 0.34451E-10 -10.4628 0.31418E-10 -10.5028 0.91198E+00 -0.0400 48 HFeO2- 0.30813E-08 -8.5113 0.28089E-08 -8.5515 0.91159E+00 -0.0402 49 FeO+ 0.34361E-14 -14.4639 0.31336E-14 -14.5040 0.91198E+00 -0.0400 51 FeO2- 0.47081E-08 -8.3272 0.42918E-08 -8.3674 0.91159E+00 -0.0402 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.59568E-09 -9.2250 0.59530E-09 -9.2253 0.99935E+00 -0.0003 54 KCl,aq 0.88459E-10 -10.0533 0.88459E-10 -10.0533 0.10000E+01 0.0000 55 KHSO4,aq 0.75068E-18 -18.1245 0.75068E-18 -18.1245 0.10000E+01 0.0000 56 KOH,aq 0.45729E-07 -7.3398 0.45729E-07 -7.3398 0.10000E+01 0.0000 57 KSO4- 0.12515E-07 -7.9026 0.11409E-07 -7.9428 0.91159E+00 -0.0402 58 MgCO3,aq 0.41411E-12 -12.3829 0.41411E-12 -12.3829 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15620E-13 -13.8063 0.14245E-13 -13.8463 0.91198E+00 -0.0400 60 MgCl+ 0.12104E-13 -13.9171 0.11039E-13 -13.9571 0.91198E+00 -0.0400 61 MgOH+ 0.68630E-10 -10.1635 0.62589E-10 -10.2035 0.91198E+00 -0.0400 63 MnO,aq 0.35290E-09 -9.4524 0.35290E-09 -9.4524 0.10000E+01 0.0000 64 MnOH+ 0.42766E-09 -9.3689 0.39001E-09 -9.4089 0.91198E+00 -0.0400 65 MnO2-2 0.11645E-12 -12.9339 0.85046E-13 -13.0703 0.73033E+00 -0.1365 66 HMnO2- 0.76572E-11 -11.1159 0.69802E-11 -11.1561 0.91159E+00 -0.0402 69 MnCl+ 0.40026E-13 -13.3977 0.36503E-13 -13.4377 0.91198E+00 -0.0400 70 MnSO4,aq 0.25337E-12 -12.5963 0.25337E-12 -12.5963 0.10000E+01 0.0000 71 NaCl,aq 0.12687E-06 -6.8967 0.12687E-06 -6.8967 0.10000E+01 0.0000 72 NaOH,aq 0.35846E-05 -5.4456 0.35846E-05 -5.4456 0.10000E+01 0.0000 74 OH- 0.17377E-02 -2.7600 0.15834E-02 -2.8004 0.91122E+00 -0.0404 79 HPO3-2 0.18350E-16 -16.7364 0.13401E-16 -16.8729 0.73033E+00 -0.1365 81 H2PO3- 0.10939E-19 -19.9610 0.99723E-20 -20.0012 0.91159E+00 -0.0402 82 H3PO4,aq 0.65848E-14 -14.1815 0.65848E-14 -14.1815 0.10000E+01 0.0000 83 H2PO4- 0.51916E-07 -7.2847 0.47336E-07 -7.3248 0.91178E+00 -0.0401 84 PO4-3 0.32292E-07 -7.4909 0.16431E-07 -7.7843 0.50884E+00 -0.2934 87 H2P2O7-2 0.24012E-15 -15.6196 0.17537E-15 -15.7560 0.73033E+00 -0.1365 88 HP2O7-3 0.18859E-12 -12.7245 0.94927E-13 -13.0226 0.50335E+00 -0.2981 89 P2O7-4 0.20538E-12 -12.6874 0.61820E-13 -13.2089 0.30100E+00 -0.5214 90 H2S,aq 0.50205E-16 -16.2992 0.50173E-16 -16.2995 0.99935E+00 -0.0003 97 SO3-2 0.20645E-14 -14.6852 0.15126E-14 -14.8203 0.73270E+00 -0.1351 98 HSO3- 0.36786E-16 -16.4343 0.33534E-16 -16.4745 0.91159E+00 -0.0402 99 HSO4- 0.71811E-11 -11.1438 0.65504E-11 -11.1837 0.91217E+00 -0.0399 Charge balance for all species = 0.5595E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4149995E-09 -.3417248E-02 -.3443405E+01 0.0000 2 H2O 0.1000000E+01 0.5550859E+02 0.9997204E+06 0.0000 3 Cl- 0.1379177E-03 0.1380447E-03 0.4892709E+01 5.5210 4 SO4-- 0.2550492E-04 0.2551796E-04 0.2450601E+01 14.1135 5 HCO3- 0.1001686E-04 0.1307668E-04 0.7976759E+00 4.3822 6 HS- 0.4835527E-13 -.4649719E-09 -.1537319E-04 -3.9342 7 Al+++ 0.2966773E-25 0.4590532E-04 0.1238243E+01 2.4388 8 H4SiO4 0.5045232E-03 0.1993759E-02 0.1915766E+03 -3.2971 9 Ca++ 0.1230855E-07 0.1472943E-07 0.5901586E-03 10.7964 10 Mg++ 0.8328456E-10 0.1547680E-09 0.3761651E-05 8.6263 11 Fe++ 0.4925030E-12 0.8126752E-08 0.4537260E-03 6.3982 12 K+ 0.4357402E-04 0.4363235E-04 0.1705628E+01 5.0208 13 Na+ 0.3390195E-02 0.3457686E-02 0.7946896E+02 6.9116 14 Mn++ 0.6579996E-10 0.8544206E-09 0.4692685E-04 8.5241 15 HPO4-- 0.9754124E-05 0.9838333E-05 0.9440056E+00 13.6961 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4633424E-01 -.3415504E-02 -.4291874E-01 0.0000000E+00 2 H2O 0.5547316E+02 0.5548026E+02 -.7092419E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1030743E-03 0.2550493E-04 0.7756937E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7756983E-04 -.4647345E-09 -.7756937E-04 0.0000000E+00 7 Al+++ 0.9126816E-02 0.4588189E-04 0.9080934E-02 0.0000000E+00 8 H4SiO4 0.2914538E-01 0.1992741E-02 0.2715264E-01 0.0000000E+00 9 Ca++ 0.3233720E-02 0.1472191E-07 0.3233706E-02 0.0000000E+00 10 Mg++ 0.2221429E-02 0.1546889E-09 0.2221428E-02 0.0000000E+00 11 Fe++ 0.1995711E-02 0.8122603E-08 0.1995703E-02 0.0000000E+00 12 K+ 0.5942675E-03 0.4361008E-04 0.5506574E-03 0.0000000E+00 13 Na+ 0.3673498E-02 0.3455921E-02 0.2175773E-03 0.0000000E+00 14 Mn++ 0.4853073E-04 0.8539844E-09 0.4852988E-04 0.0000000E+00 15 HPO4-- 0.1656330E-04 0.9833310E-05 0.6729987E-05 0.0000000E+00 Chg. balance for solid moles: -.2236E-17 Mass of aqueous solution: 0.999773E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2243E-05 -5.649 0.1127E-02 -2.948 0.3739E-01 0.3581E-03 clinochlore 0.4443E-03 -3.352 0.2469 -0.607 8.195 0.9393E-01 daphnite 0.2750E-03 -3.561 0.1962 -0.707 6.512 0.5947E-01 chlorite-Mn 0.9706E-05 -5.013 0.6881E-02 -2.162 0.2283 0.2193E-02 hematite 0.2717E-03 -3.566 0.4339E-01 -1.363 1.440 0.8223E-02 microcline 0.5507E-03 -3.259 0.1533 -0.815 5.086 0.5987E-01 paragonite 0.2048E-03 -3.689 0.7829E-01 -1.106 2.598 0.2706E-01 stilbite 0.3222E-02 -2.492 2.271 0.356 75.36 1.059 nontronite-Na 0.3860E-04 -4.413 0.1642E-01 -1.785 0.5447 0.5099E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.013506 g Volume = 1.315417 cm3 Porosity: 37.9403% V(tot) - V(min): 0.80418E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.7990000 g log = 0.4470 Original solution: 1000.0103000 g Original solution / Rock added: 357.27 (Water/Rock Ratio), log = 2.5530 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.7536E-06 1.0073 0.7986E-06 0.7928E-06 CH4,gas 0.3147E-16 1.0129 0.3353E-16 0.3310E-16 H2,gas 0.7757E-06 1.0006 0.8165E-06 0.8160E-06 H2S,gas 0.1397E-14 0.9959 0.1463E-14 0.1469E-14 S2,gas 0.1144E-36 1.0000 0.1203E-36 0.1203E-36 CO,gas 0.1606E-15 1.0000 0.1689E-15 0.1689E-15 SO3,gas 0.9504E-39 1.0000 0.9998E-39 0.9998E-39 SO2,gas 0.2936E-22 1.0000 0.3088E-22 0.3088E-22 HCl,gas 0.1504E-16 1.0000 0.1582E-16 0.1582E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.46 -8.10 -2.699 0.13827E+05 -6.098 3 CH4,gas 4.81 -13.67 -18.47 -4.619 0.31545E+05 -16.475 4 H2,gas 8.29 0.20 -8.09 -4.622 0.13810E+05 -6.088 5 H2S,gas -5.94 -22.78 -16.83 -8.417 0.28745E+05 -14.835 6 S2,gas -7.03 -45.95 -38.92 -5.988 0.66454E+05 -36.920 7 CO,gas 3.51 -14.26 -17.77 -5.468 0.30346E+05 -15.772 8 SO3,gas 17.43 -23.57 -41.00 -10.250 0.70007E+05 -39.000 9 SO2,gas 1.14 -23.37 -24.51 -6.536 0.41851E+05 -22.510 10 HCl,gas 5.48 -13.32 -18.80 -9.400 0.32102E+05 -16.801 11 acmite 7.74 6.62 -1.12 -0.116 0.19145E+04 15 albite-high 0.75 -0.54 -1.29 -0.099 0.22037E+04 16 albite -0.33 -0.54 -0.21 -0.016 0.36303E+03 19 spessartine 24.55 20.56 -3.99 -0.200 0.68150E+04 20 analcite 3.37 2.76 -0.61 -0.068 0.10492E+04 21 andalusite 5.06 1.58 -3.48 -0.348 0.59452E+04 22 andradite 39.09 35.10 -3.99 -0.207 0.68169E+04 26 annite 20.21 16.76 -3.45 -0.191 0.58847E+04 27 phlogopite 27.15 23.45 -3.70 -0.206 0.63168E+04 29 anorthite 12.80 9.08 -3.72 -0.286 0.63483E+04 35 aragonite 0.99 -3.66 -4.65 -1.550 0.79410E+04 36 brucite 12.58 8.63 -3.95 -0.790 0.67451E+04 37 calcite 0.83 -3.66 -4.50 -1.499 0.76797E+04 38 carnegieite-low 9.06 6.05 -3.01 -0.430 0.51417E+04 39 carnegieite-high 10.13 6.05 -4.08 -0.583 0.69686E+04 40 carpholite-Mg 8.65 6.91 -1.74 -0.116 0.29722E+04 41 carpholite-Fe 6.78 4.68 -2.10 -0.140 0.35879E+04 42 celadonite 5.40 2.90 -2.50 -0.147 0.42740E+04 43 celadonite-Fe 3.94 0.67 -3.27 -0.192 0.55794E+04 44 chrysotile 23.94 19.28 -4.65 -0.388 0.79444E+04 50 chloritoid-Mg 13.26 10.21 -3.05 -0.204 0.52154E+04 51 chloritoid-Fe 9.24 7.98 -1.26 -0.084 0.21513E+04 52 chloritoid-Mn 11.46 10.10 -1.36 -0.091 0.23198E+04 54 coesite -2.37 -3.30 -0.93 -0.309 0.15841E+04 59 corundum 8.43 4.88 -3.56 -0.323 0.60715E+04 61 cristobalite -2.55 -3.30 -0.75 -0.249 0.12770E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.44 -0.46 -0.076 0.78080E+03 67 diopside 16.22 12.83 -3.39 -0.339 0.57833E+04 68 hedenbergite 14.24 10.60 -3.64 -0.364 0.62221E+04 75 epidote 24.78 22.88 -1.90 -0.092 0.32398E+04 76 clinozoisite 22.92 19.02 -3.90 -0.177 0.66649E+04 77 epidote-Fe 29.94 26.74 -3.20 -0.166 0.54622E+04 78 fayalite 14.08 9.50 -4.58 -0.654 0.78195E+04 79 ferrosilite 11.19 6.20 -4.99 -0.499 0.85125E+04 83 gibbsite 4.10 2.44 -1.66 -0.237 0.28320E+04 84 glaucophane 23.11 18.20 -4.91 -0.133 0.83800E+04 87 greenalite 16.19 12.60 -3.59 -0.299 0.61362E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.76 -1.49 -0.149 0.25523E+04 97 kalsilite 7.62 4.16 -3.46 -0.494 0.59041E+04 98 kaolinite -1.27 -1.72 -0.44 -0.040 0.75725E+03 99 kyanite 4.93 1.58 -3.35 -0.335 0.57220E+04 101 laumontite 2.97 2.49 -0.49 -0.033 0.83503E+03 102 lawsonite 9.68 9.08 -0.60 -0.040 0.10222E+04 103 leucite 4.17 0.87 -3.30 -0.330 0.56386E+04 105 lizardite 23.29 19.28 -4.00 -0.334 0.68347E+04 107 magnetite 20.13 19.00 -1.14 -0.093 0.19413E+04 108 minnesotaite 10.46 6.01 -4.45 -0.262 0.76059E+04 113 margarite 17.45 13.96 -3.49 -0.140 0.59667E+04 120 muscovite 2.68 2.45 -0.23 -0.014 0.39850E+03 122 nepheline 8.38 6.05 -2.32 -0.332 0.39696E+04 134 phlogopite-Na 29.73 25.34 -4.39 -0.244 0.75018E+04 136 prehnite 19.47 16.58 -2.89 -0.170 0.49301E+04 137 prehnite-Fe 22.59 20.44 -2.15 -0.129 0.36673E+04 138 pumpellyite-Fe 46.47 42.00 -4.48 -0.099 0.76419E+04 139 pumpellyite-Mg 49.19 44.22 -4.97 -0.110 0.84878E+04 145 pyroxmangite 7.42 5.23 -2.19 -0.438 0.37377E+04 146 pyrophyllite -6.10 -8.31 -2.21 -0.138 0.37784E+04 147 quartz -2.98 -3.30 -0.32 -0.105 0.53806E+03 151 rhodochrosite -0.96 -5.94 -4.98 -1.659 0.85002E+04 152 rhodonite 7.46 5.23 -2.24 -0.447 0.38169E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.58 -3.74 -0.374 0.63874E+04 164 stilpnomelane-Fe 13.18 13.00 -0.18 -0.005 0.30245E+03 165 stilpnomelane-Mg 27.60 24.14 -3.45 -0.103 0.58973E+04 168 sudoite 21.22 17.12 -4.10 -0.132 0.70002E+04 171 talc 16.55 12.69 -3.86 -0.227 0.65959E+04 174 tephroite 18.11 13.75 -4.36 -0.623 0.74476E+04 177 topaz-H 4.67 1.58 -3.09 -0.281 0.52711E+04 178 tridymite -2.61 -3.30 -0.68 -0.228 0.11654E+04 187 wairakite 4.06 2.49 -1.57 -0.093 0.26858E+04 188 walstromite 11.53 7.50 -4.03 -0.806 0.68788E+04 189 wollastonite 10.48 7.50 -2.98 -0.597 0.50926E+04 190 pseudo-wollastonite 11.02 7.50 -3.52 -0.704 0.60113E+04 191 zoisite 22.96 19.02 -3.95 -0.179 0.67374E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.64 -3.08 -0.190 0.52538E+04 194 beidellite-H -2.24 -6.42 -4.18 -0.267 0.71320E+04 195 beidellite-K -1.44 -4.76 -3.33 -0.204 0.56793E+04 196 beidellite-Mg -1.71 -4.99 -3.29 -0.203 0.56138E+04 197 beidellite-Na -1.26 -4.14 -2.88 -0.176 0.49178E+04 199 chalcedony -2.79 -3.30 -0.50 -0.168 0.85837E+03 201 montmorillonite-Ca -2.21 -4.49 -2.27 -0.141 0.38821E+04 202 montmorillonite-K -2.16 -4.61 -2.45 -0.150 0.41853E+04 203 montmorillonite-Mg -2.40 -4.85 -2.44 -0.151 0.41731E+04 204 montmorillonite-Na -1.96 -3.99 -2.03 -0.124 0.34620E+04 205 nontronite-Ca 3.28 3.08 -0.20 -0.013 0.33510E+03 206 nontronite-H 2.60 1.30 -1.29 -0.087 0.22090E+04 207 nontronite-K 3.40 2.96 -0.44 -0.029 0.75977E+03 208 nontronite-Mg 3.14 2.73 -0.41 -0.027 0.70675E+03 224 tobermorite 9.84 5.70 -4.14 -1.130 0.70736E+04 233 boehmite 4.43 2.44 -1.99 -0.332 0.33992E+04 235 ferrous-oxide 9.82 6.40 -3.43 -0.856 0.58498E+04 240 silica-amorphous -2.08 -3.30 -1.22 -0.406 0.20786E+04 242 an20ab80 2.08 1.38 -0.70 -0.054 0.11885E+04 243 an25ab75 2.71 1.86 -0.84 -0.065 0.14427E+04 244 an30ab70 3.34 2.35 -1.00 -0.077 0.17053E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 2.7990000 g New total amount of reactant added: 2.8990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4566E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2.8990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9995E+00 Moles total = 0.5547E+02 kg total = 0.9993E+00 Activity = 1.0000 Stoichiometric ionic strength = .2164291E-02 Osmotic coef. = 0.9740 True ionic strength = .3582766E-02 Chg. balance for total moles = 0.4566E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.40106E-09 -9.3968 0.36571E-09 -9.4369 0.91186E+00 -0.0401 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13792E-03 -3.8604 0.12559E-03 -3.9011 0.91060E+00 -0.0407 4 SO4-- 0.25505E-04 -4.5934 0.18557E-04 -4.7315 0.72757E+00 -0.1381 5 HCO3- 0.99264E-05 -5.0032 0.90420E-05 -5.0437 0.91090E+00 -0.0405 6 HS- 0.50296E-13 -13.2985 0.45801E-13 -13.3391 0.91063E+00 -0.0407 7 Al+++ 0.26479E-25 -25.5771 0.13198E-25 -25.8795 0.49842E+00 -0.3024 8 H4SiO4 0.50232E-03 -3.2990 0.50232E-03 -3.2990 0.10000E+01 0.0000 9 Ca++ 0.12308E-07 -7.9098 0.89399E-08 -8.0487 0.72636E+00 -0.1388 10 Mg++ 0.78720E-10 -10.1039 0.57119E-10 -10.2432 0.72560E+00 -0.1393 11 Fe++ 0.46551E-12 -12.3321 0.33785E-12 -12.4713 0.72578E+00 -0.1392 12 K+ 0.43431E-04 -4.3622 0.39563E-04 -4.4027 0.91095E+00 -0.0405 13 Na+ 0.35011E-02 -2.4558 0.31880E-02 -2.4965 0.91057E+00 -0.0407 14 Mn++ 0.62193E-10 -10.2063 0.45147E-10 -10.3454 0.72592E+00 -0.1391 15 HPO4-- 0.94149E-05 -5.0262 0.68502E-05 -5.1643 0.72759E+00 -0.1381 16 HSiO3- 0.14717E-02 -2.8322 0.13401E-02 -2.8729 0.91060E+00 -0.0407 17 Ca(HSiO3)+ 0.29466E-09 -9.5307 0.26843E-09 -9.5712 0.91100E+00 -0.0405 18 Mg(HSiO3)+ 0.23429E-11 -11.6302 0.21344E-11 -11.6707 0.91100E+00 -0.0405 19 NaHSiO3,aq 0.67856E-04 -4.1684 0.67856E-04 -4.1684 0.10000E+01 0.0000 20 AlO+ 0.13984E-13 -13.8544 0.12739E-13 -13.8949 0.91100E+00 -0.0405 21 AlOH+2 0.32143E-19 -19.4929 0.23338E-19 -19.6319 0.72608E+00 -0.1390 22 HAlO2,aq 0.69707E-08 -8.1567 0.69707E-08 -8.1567 0.10000E+01 0.0000 23 AlO2- 0.46759E-04 -4.3301 0.42561E-04 -4.3710 0.91022E+00 -0.0409 24 CH4,aq 0.21913E-19 -19.6593 0.21899E-19 -19.6596 0.99933E+00 -0.0003 29 CO,aq 0.10423E-18 -18.9820 0.10423E-18 -18.9820 0.10000E+01 0.0000 30 CO2,aq 0.66715E-08 -8.1758 0.66670E-08 -8.1761 0.99933E+00 -0.0003 31 CO3-2 0.31435E-05 -5.5026 0.22860E-05 -5.6409 0.72721E+00 -0.1383 32 CaCO3,aq 0.25030E-09 -9.6015 0.25030E-09 -9.6015 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.22358E-11 -11.6506 0.20368E-11 -11.6911 0.91100E+00 -0.0405 34 CaCl+ 0.19638E-11 -11.7069 0.17891E-11 -11.7474 0.91100E+00 -0.0405 35 CaCl2,aq 0.52314E-16 -16.2814 0.52314E-16 -16.2814 0.10000E+01 0.0000 36 CaOH+ 0.18921E-08 -8.7231 0.17237E-08 -8.7635 0.91100E+00 -0.0405 37 CaSO4,aq 0.51690E-10 -10.2866 0.51690E-10 -10.2866 0.10000E+01 0.0000 38 HCl,aq 0.86389E-14 -14.0635 0.86389E-14 -14.0635 0.10000E+01 0.0000 43 FeCl+ 0.72541E-16 -16.1394 0.66085E-16 -16.1799 0.91100E+00 -0.0405 46 FeO,aq 0.99894E-10 -10.0005 0.99894E-10 -10.0005 0.10000E+01 0.0000 47 FeOH+ 0.33620E-10 -10.4734 0.30627E-10 -10.5139 0.91100E+00 -0.0405 48 HFeO2- 0.32265E-08 -8.4913 0.29380E-08 -8.5319 0.91060E+00 -0.0407 49 FeO+ 0.33208E-14 -14.4788 0.30252E-14 -14.5192 0.91100E+00 -0.0405 51 FeO2- 0.48821E-08 -8.3114 0.44456E-08 -8.3521 0.91060E+00 -0.0407 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.60738E-09 -9.2165 0.60698E-09 -9.2168 0.99933E+00 -0.0003 54 KCl,aq 0.87976E-10 -10.0556 0.87976E-10 -10.0556 0.10000E+01 0.0000 55 KHSO4,aq 0.71848E-18 -18.1436 0.71848E-18 -18.1436 0.10000E+01 0.0000 56 KOH,aq 0.47162E-07 -7.3264 0.47162E-07 -7.3264 0.10000E+01 0.0000 57 KSO4- 0.12422E-07 -7.9058 0.11311E-07 -7.9465 0.91060E+00 -0.0407 58 MgCO3,aq 0.39961E-12 -12.3984 0.39961E-12 -12.3984 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14567E-13 -13.8366 0.13270E-13 -13.8771 0.91100E+00 -0.0405 60 MgCl+ 0.11391E-13 -13.9434 0.10377E-13 -13.9839 0.91100E+00 -0.0405 61 MgOH+ 0.66974E-10 -10.1741 0.61013E-10 -10.2146 0.91100E+00 -0.0405 63 MnO,aq 0.35634E-09 -9.4481 0.35634E-09 -9.4481 0.10000E+01 0.0000 64 MnOH+ 0.41734E-09 -9.3795 0.38019E-09 -9.4200 0.91100E+00 -0.0405 65 MnO2-2 0.12671E-12 -12.8972 0.92143E-13 -13.0355 0.72721E+00 -0.1383 66 HMnO2- 0.80179E-11 -11.0959 0.73010E-11 -11.1366 0.91060E+00 -0.0407 69 MnCl+ 0.37668E-13 -13.4240 0.34315E-13 -13.4645 0.91100E+00 -0.0405 70 MnSO4,aq 0.23743E-12 -12.6245 0.23743E-12 -12.6245 0.10000E+01 0.0000 71 NaCl,aq 0.13073E-06 -6.8836 0.13073E-06 -6.8836 0.10000E+01 0.0000 72 NaOH,aq 0.38305E-05 -5.4167 0.38305E-05 -5.4167 0.10000E+01 0.0000 74 OH- 0.18020E-02 -2.7442 0.16402E-02 -2.7851 0.91022E+00 -0.0409 79 HPO3-2 0.18059E-16 -16.7433 0.13133E-16 -16.8816 0.72721E+00 -0.1383 81 H2PO3- 0.10361E-19 -19.9846 0.94344E-20 -20.0253 0.91060E+00 -0.0407 82 H3PO4,aq 0.58982E-14 -14.2293 0.58982E-14 -14.2293 0.10000E+01 0.0000 83 H2PO4- 0.48223E-07 -7.3167 0.43921E-07 -7.3573 0.91079E+00 -0.0406 84 PO4-3 0.32451E-07 -7.4888 0.16358E-07 -7.7863 0.50409E+00 -0.2975 87 H2P2O7-2 0.20761E-15 -15.6828 0.15098E-15 -15.8211 0.72721E+00 -0.1383 88 HP2O7-3 0.16982E-12 -12.7700 0.84652E-13 -13.0724 0.49850E+00 -0.3023 89 P2O7-4 0.19298E-12 -12.7145 0.57104E-13 -13.2433 0.29590E+00 -0.5288 90 H2S,aq 0.50360E-16 -16.2979 0.50326E-16 -16.2982 0.99933E+00 -0.0003 97 SO3-2 0.21049E-14 -14.6768 0.15358E-14 -14.8137 0.72963E+00 -0.1369 98 HSO3- 0.36096E-16 -16.4425 0.32869E-16 -16.4832 0.91060E+00 -0.0407 99 HSO4- 0.69106E-11 -11.1605 0.62969E-11 -11.2009 0.91119E+00 -0.0404 Charge balance for all species = 0.5556E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.4010595E-09 -.3535635E-02 -.3562671E+01 0.0000 2 H2O 0.1000000E+01 0.5550861E+02 0.9997132E+06 0.0000 3 Cl- 0.1379162E-03 0.1380471E-03 0.4892758E+01 5.5358 4 SO4-- 0.2550546E-04 0.2551843E-04 0.2450627E+01 14.1422 5 HCO3- 0.9926445E-05 0.1307690E-04 0.7976839E+00 4.3931 6 HS- 0.5029640E-13 -.4838027E-09 -.1599566E-04 -3.9023 7 Al+++ 0.2647937E-25 0.4676578E-04 0.1261444E+01 2.4311 8 H4SiO4 0.5023238E-03 0.2041894E-02 0.1962003E+03 -3.2990 9 Ca++ 0.1230791E-07 0.1480088E-07 0.5930170E-03 10.8251 10 Mg++ 0.7871983E-10 0.1484626E-09 0.3608373E-05 8.6305 11 Fe++ 0.4655062E-12 0.8446048E-08 0.4715492E-03 6.4025 12 K+ 0.4343077E-04 0.4349044E-04 0.1700068E+01 5.0342 13 Na+ 0.3501134E-02 0.3572951E-02 0.8211752E+02 6.9404 14 Mn++ 0.6219283E-10 0.8442942E-09 0.4637034E-04 8.5284 15 HPO4-- 0.9414874E-05 0.9495548E-05 0.9111080E+00 13.7094 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4799010E-01 -.3533769E-02 -.4445633E-01 0.0000000E+00 2 H2O 0.5547191E+02 0.5547930E+02 -.7393796E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1058456E-03 0.2550495E-04 0.8034069E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8034117E-04 -.4835472E-09 -.8034069E-04 0.0000000E+00 7 Al+++ 0.9452890E-02 0.4674109E-04 0.9406149E-02 0.0000000E+00 8 H4SiO4 0.3018666E-01 0.2040816E-02 0.2814584E-01 0.0000000E+00 9 Ca++ 0.3348735E-02 0.1479306E-07 0.3348720E-02 0.0000000E+00 10 Mg++ 0.2300794E-02 0.1483842E-09 0.2300794E-02 0.0000000E+00 11 Fe++ 0.2067012E-02 0.8441589E-08 0.2067003E-02 0.0000000E+00 12 K+ 0.6154989E-03 0.4346748E-04 0.5720315E-03 0.0000000E+00 13 Na+ 0.3799022E-02 0.3571064E-02 0.2279580E-03 0.0000000E+00 14 Mn++ 0.5026459E-04 0.8438485E-09 0.5026375E-04 0.0000000E+00 15 HPO4-- 0.1715505E-04 0.9490535E-05 0.7664520E-05 0.0000000E+00 Chg. balance for solid moles: -.1049E-16 Mass of aqueous solution: 0.999763E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2.8990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2555E-05 -5.593 0.1283E-02 -2.892 0.4110E-01 0.4078E-03 clinochlore 0.4602E-03 -3.337 0.2558 -0.592 8.191 0.9729E-01 daphnite 0.2849E-03 -3.545 0.2032 -0.692 6.509 0.6159E-01 chlorite-Mn 0.1005E-04 -4.998 0.7127E-02 -2.147 0.2282 0.2271E-02 hematite 0.2732E-03 -3.564 0.4363E-01 -1.360 1.397 0.8270E-02 microcline 0.5720E-03 -3.243 0.1592 -0.798 5.099 0.6220E-01 paragonite 0.2121E-03 -3.674 0.8105E-01 -1.091 2.596 0.2802E-01 stilbite 0.3336E-02 -2.477 2.351 0.371 75.28 1.097 nontronite-Na 0.4815E-04 -4.317 0.2048E-01 -1.689 0.6558 0.6362E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.122716 g Volume = 1.362906 cm3 Porosity: 36.8908% V(tot) - V(min): 0.79669E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.8990000 g log = 0.4622 Original solution: 1000.0103000 g Original solution / Rock added: 344.95 (Water/Rock Ratio), log = 2.5378 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.7202E-06 1.0073 0.7632E-06 0.7576E-06 CH4,gas 0.3250E-16 1.0129 0.3463E-16 0.3419E-16 H2,gas 0.7910E-06 1.0006 0.8325E-06 0.8321E-06 H2S,gas 0.1401E-14 0.9959 0.1468E-14 0.1474E-14 S2,gas 0.1107E-36 1.0000 0.1164E-36 0.1164E-36 CO,gas 0.1564E-15 1.0000 0.1646E-15 0.1646E-15 SO3,gas 0.8821E-39 1.0000 0.9279E-39 0.9279E-39 SO2,gas 0.2778E-22 1.0000 0.2922E-22 0.2922E-22 HCl,gas 0.1450E-16 1.0000 0.1525E-16 0.1525E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 0.19715E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 0.28056E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.48 -8.12 -2.706 0.13860E+05 -6.117 3 CH4,gas 4.81 -13.65 -18.46 -4.615 0.31521E+05 -16.461 4 H2,gas 8.29 0.21 -8.08 -4.617 0.13796E+05 -6.080 5 H2S,gas -5.94 -22.78 -16.83 -8.417 0.28742E+05 -14.833 6 S2,gas -7.03 -45.97 -38.93 -5.990 0.66479E+05 -36.934 7 CO,gas 3.51 -14.27 -17.78 -5.472 0.30365E+05 -15.784 8 SO3,gas 17.43 -23.61 -41.03 -10.258 0.70062E+05 -39.033 9 SO2,gas 1.14 -23.40 -24.53 -6.542 0.41892E+05 -22.534 10 HCl,gas 5.48 -13.34 -18.82 -9.408 0.32129E+05 -16.817 11 acmite 7.74 6.64 -1.10 -0.114 0.18718E+04 15 albite-high 0.75 -0.53 -1.28 -0.098 0.21774E+04 16 albite -0.33 -0.53 -0.20 -0.015 0.33672E+03 19 spessartine 24.55 20.55 -4.00 -0.200 0.68294E+04 20 analcite 3.37 2.77 -0.60 -0.066 0.10197E+04 21 andalusite 5.06 1.56 -3.50 -0.350 0.59748E+04 22 andradite 39.09 35.18 -3.91 -0.203 0.66796E+04 26 annite 20.21 16.78 -3.43 -0.191 0.58630E+04 27 phlogopite 27.15 23.46 -3.69 -0.205 0.62952E+04 29 anorthite 12.80 9.09 -3.71 -0.285 0.63321E+04 35 aragonite 0.99 -3.66 -4.64 -1.547 0.79257E+04 36 brucite 12.58 8.63 -3.95 -0.789 0.67378E+04 37 calcite 0.83 -3.66 -4.49 -1.496 0.76643E+04 38 carnegieite-low 9.06 6.07 -2.99 -0.427 0.51089E+04 39 carnegieite-high 10.13 6.07 -4.06 -0.580 0.69358E+04 40 carpholite-Mg 8.65 6.89 -1.76 -0.117 0.29978E+04 41 carpholite-Fe 6.78 4.67 -2.12 -0.141 0.36135E+04 42 celadonite 5.40 2.90 -2.50 -0.147 0.42701E+04 43 celadonite-Fe 3.94 0.67 -3.27 -0.192 0.55754E+04 44 chrysotile 23.94 19.29 -4.64 -0.387 0.79293E+04 50 chloritoid-Mg 13.26 10.19 -3.07 -0.205 0.52378E+04 51 chloritoid-Fe 9.24 7.97 -1.27 -0.085 0.21737E+04 52 chloritoid-Mn 11.46 10.09 -1.37 -0.091 0.23421E+04 54 coesite -2.37 -3.30 -0.93 -0.310 0.15874E+04 59 corundum 8.43 4.86 -3.57 -0.325 0.60978E+04 61 cristobalite -2.55 -3.30 -0.75 -0.250 0.12803E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.43 -0.46 -0.077 0.79396E+03 67 diopside 16.22 12.86 -3.36 -0.336 0.57336E+04 68 hedenbergite 14.24 10.63 -3.61 -0.361 0.61724E+04 75 epidote 24.78 22.91 -1.86 -0.090 0.31778E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66161E+04 77 epidote-Fe 29.94 26.78 -3.15 -0.164 0.53870E+04 78 fayalite 14.08 9.51 -4.57 -0.653 0.78084E+04 79 ferrosilite 11.19 6.21 -4.98 -0.498 0.85046E+04 83 gibbsite 4.10 2.43 -1.67 -0.238 0.28451E+04 84 glaucophane 23.11 18.24 -4.87 -0.132 0.83123E+04 87 greenalite 16.19 12.61 -3.58 -0.299 0.61211E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.77 -1.48 -0.148 0.25227E+04 97 kalsilite 7.62 4.17 -3.45 -0.493 0.58976E+04 98 kaolinite -1.27 -1.74 -0.46 -0.042 0.79004E+03 99 kyanite 4.93 1.56 -3.37 -0.337 0.57516E+04 101 laumontite 2.97 2.49 -0.48 -0.032 0.82531E+03 102 lawsonite 9.68 9.09 -0.59 -0.039 0.10060E+04 103 leucite 4.17 0.87 -3.30 -0.330 0.56354E+04 105 lizardite 23.29 19.29 -3.99 -0.333 0.68195E+04 107 magnetite 20.13 19.00 -1.13 -0.092 0.19341E+04 108 minnesotaite 10.46 6.01 -4.45 -0.262 0.75973E+04 113 margarite 17.45 13.95 -3.50 -0.140 0.59768E+04 120 muscovite 2.68 2.43 -0.25 -0.015 0.42481E+03 122 nepheline 8.38 6.07 -2.31 -0.329 0.39368E+04 134 phlogopite-Na 29.73 25.37 -4.37 -0.243 0.74538E+04 136 prehnite 19.47 16.62 -2.85 -0.168 0.48681E+04 137 prehnite-Fe 22.59 20.48 -2.10 -0.127 0.35922E+04 138 pumpellyite-Fe 46.47 42.06 -4.41 -0.098 0.75239E+04 139 pumpellyite-Mg 49.19 44.29 -4.90 -0.109 0.83699E+04 145 pyroxmangite 7.42 5.23 -2.19 -0.437 0.37337E+04 146 pyrophyllite -6.10 -8.33 -2.24 -0.140 0.38176E+04 147 quartz -2.98 -3.30 -0.32 -0.106 0.54130E+03 151 rhodochrosite -0.96 -5.95 -4.99 -1.665 0.85266E+04 152 rhodonite 7.46 5.23 -2.23 -0.447 0.38130E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.56 -3.76 -0.376 0.64170E+04 164 stilpnomelane-Fe 13.18 13.00 -0.18 -0.005 0.30721E+03 165 stilpnomelane-Mg 27.60 24.14 -3.46 -0.103 0.59020E+04 168 sudoite 21.22 17.09 -4.13 -0.133 0.70482E+04 171 talc 16.55 12.70 -3.86 -0.227 0.65873E+04 174 tephroite 18.11 13.76 -4.36 -0.622 0.74364E+04 177 topaz-H 4.67 1.56 -3.10 -0.282 0.53006E+04 178 tridymite -2.61 -3.30 -0.68 -0.228 0.11686E+04 187 wairakite 4.06 2.49 -1.57 -0.092 0.26761E+04 188 walstromite 11.53 7.53 -4.00 -0.800 0.68330E+04 189 wollastonite 10.48 7.53 -2.96 -0.591 0.50469E+04 190 pseudo-wollastonite 11.02 7.53 -3.49 -0.699 0.59655E+04 191 zoisite 22.96 19.05 -3.92 -0.178 0.66886E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.66 -3.10 -0.192 0.52883E+04 194 beidellite-H -2.24 -6.44 -4.20 -0.268 0.71745E+04 195 beidellite-K -1.44 -4.78 -3.35 -0.205 0.57143E+04 196 beidellite-Mg -1.71 -5.02 -3.31 -0.205 0.56552E+04 197 beidellite-Na -1.26 -4.15 -2.90 -0.177 0.49441E+04 199 chalcedony -2.79 -3.30 -0.50 -0.168 0.86161E+03 201 montmorillonite-Ca -2.21 -4.50 -2.29 -0.142 0.39065E+04 202 montmorillonite-K -2.16 -4.63 -2.47 -0.151 0.42103E+04 203 montmorillonite-Mg -2.40 -4.86 -2.46 -0.152 0.42045E+04 204 montmorillonite-Na -1.96 -4.00 -2.04 -0.125 0.34783E+04 205 nontronite-Ca 3.28 3.08 -0.20 -0.013 0.34325E+03 206 nontronite-H 2.60 1.29 -1.30 -0.087 0.22253E+04 207 nontronite-K 3.40 2.95 -0.45 -0.029 0.76846E+03 208 nontronite-Mg 3.14 2.72 -0.42 -0.027 0.72179E+03 224 tobermorite 9.84 5.72 -4.12 -1.124 0.70361E+04 233 boehmite 4.43 2.43 -2.00 -0.333 0.34124E+04 235 ferrous-oxide 9.82 6.40 -3.42 -0.855 0.58426E+04 240 silica-amorphous -2.08 -3.30 -1.22 -0.406 0.20818E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11642E+04 243 an25ab75 2.71 1.88 -0.83 -0.064 0.14190E+04 244 an30ab70 3.34 2.36 -0.99 -0.076 0.16821E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 2.8990000 g New total amount of reactant added: 2.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4565E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2.9990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9995E+00 Moles total = 0.5547E+02 kg total = 0.9993E+00 Activity = 1.0000 Stoichiometric ionic strength = .2225043E-02 Osmotic coef. = 0.9737 True ionic strength = .3693262E-02 Chg. balance for total moles = 0.4565E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.38805E-09 -9.4111 0.35349E-09 -9.4516 0.91092E+00 -0.0405 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13791E-03 -3.8604 0.12545E-03 -3.9015 0.90962E+00 -0.0411 4 SO4-- 0.25506E-04 -4.5934 0.18480E-04 -4.7333 0.72452E+00 -0.1399 5 HCO3- 0.98373E-05 -5.0071 0.89513E-05 -5.0481 0.90993E+00 -0.0410 6 HS- 0.52246E-13 -13.2819 0.47526E-13 -13.3231 0.90965E+00 -0.0411 7 Al+++ 0.23730E-25 -25.6247 0.11716E-25 -25.9312 0.49370E+00 -0.3065 8 H4SiO4 0.50021E-03 -3.3008 0.50021E-03 -3.3008 0.10000E+01 0.0000 9 Ca++ 0.12309E-07 -7.9098 0.89029E-08 -8.0505 0.72328E+00 -0.1407 10 Mg++ 0.74557E-10 -10.1275 0.53868E-10 -10.2687 0.72250E+00 -0.1412 11 Fe++ 0.44089E-12 -12.3557 0.31862E-12 -12.4967 0.72269E+00 -0.1410 12 K+ 0.43295E-04 -4.3636 0.39398E-04 -4.4045 0.90999E+00 -0.0410 13 Na+ 0.36120E-02 -2.4423 0.32854E-02 -2.4834 0.90959E+00 -0.0412 14 Mn++ 0.58903E-10 -10.2299 0.42577E-10 -10.3708 0.72283E+00 -0.1410 15 HPO4-- 0.90981E-05 -5.0410 0.65920E-05 -5.1810 0.72455E+00 -0.1399 16 HSiO3- 0.15178E-02 -2.8188 0.13806E-02 -2.8599 0.90962E+00 -0.0411 17 Ca(HSiO3)+ 0.30262E-09 -9.5191 0.27540E-09 -9.5600 0.91004E+00 -0.0409 18 Mg(HSiO3)+ 0.22788E-11 -11.6423 0.20738E-11 -11.6832 0.91004E+00 -0.0409 19 NaHSiO3,aq 0.72043E-04 -4.1424 0.72043E-04 -4.1424 0.10000E+01 0.0000 20 AlO+ 0.13301E-13 -13.8761 0.12104E-13 -13.9171 0.91004E+00 -0.0409 21 AlOH+2 0.29645E-19 -19.5280 0.21434E-19 -19.6689 0.72300E+00 -0.1409 22 HAlO2,aq 0.68523E-08 -8.1642 0.68523E-08 -8.1642 0.10000E+01 0.0000 23 AlO2- 0.47605E-04 -4.3223 0.43284E-04 -4.3637 0.90923E+00 -0.0413 24 CH4,aq 0.22605E-19 -19.6458 0.22589E-19 -19.6461 0.99931E+00 -0.0003 29 CO,aq 0.10162E-18 -18.9930 0.10162E-18 -18.9930 0.10000E+01 0.0000 30 CO2,aq 0.63840E-08 -8.1949 0.63796E-08 -8.1952 0.99931E+00 -0.0003 31 CO3-2 0.32332E-05 -5.4904 0.23413E-05 -5.6305 0.72416E+00 -0.1402 32 CaCO3,aq 0.25530E-09 -9.5930 0.25530E-09 -9.5930 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.22065E-11 -11.6563 0.20080E-11 -11.6972 0.91004E+00 -0.0409 34 CaCl+ 0.19557E-11 -11.7087 0.17797E-11 -11.7496 0.91004E+00 -0.0409 35 CaCl2,aq 0.51985E-16 -16.2841 0.51985E-16 -16.2841 0.10000E+01 0.0000 36 CaOH+ 0.19515E-08 -8.7096 0.17759E-08 -8.7506 0.91004E+00 -0.0409 37 CaSO4,aq 0.51262E-10 -10.2902 0.51262E-10 -10.2902 0.10000E+01 0.0000 38 HCl,aq 0.83412E-14 -14.0788 0.83412E-14 -14.0788 0.10000E+01 0.0000 43 FeCl+ 0.68411E-16 -16.1649 0.62256E-16 -16.2058 0.91004E+00 -0.0409 46 FeO,aq 0.10084E-09 -9.9964 0.10084E-09 -9.9964 0.10000E+01 0.0000 47 FeOH+ 0.32837E-10 -10.4836 0.29883E-10 -10.5246 0.91004E+00 -0.0409 48 HFeO2- 0.33731E-08 -8.4720 0.30683E-08 -8.5131 0.90962E+00 -0.0411 49 FeO+ 0.32132E-14 -14.4931 0.29241E-14 -14.5340 0.91004E+00 -0.0409 51 FeO2- 0.50563E-08 -8.2962 0.45994E-08 -8.3373 0.90962E+00 -0.0411 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.61891E-09 -9.2084 0.61849E-09 -9.2087 0.99931E+00 -0.0003 54 KCl,aq 0.87515E-10 -10.0579 0.87515E-10 -10.0579 0.10000E+01 0.0000 55 KHSO4,aq 0.68869E-18 -18.1620 0.68869E-18 -18.1620 0.10000E+01 0.0000 56 KOH,aq 0.48589E-07 -7.3135 0.48589E-07 -7.3135 0.10000E+01 0.0000 57 KSO4- 0.12331E-07 -7.9090 0.11217E-07 -7.9501 0.90962E+00 -0.0411 58 MgCO3,aq 0.38599E-12 -12.4134 0.38599E-12 -12.4134 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13614E-13 -13.8660 0.12389E-13 -13.9069 0.91004E+00 -0.0409 60 MgCl+ 0.10742E-13 -13.9689 0.97758E-14 -14.0098 0.91004E+00 -0.0409 61 MgOH+ 0.65416E-10 -10.1843 0.59530E-10 -10.2253 0.91004E+00 -0.0409 63 MnO,aq 0.35971E-09 -9.4441 0.35971E-09 -9.4441 0.10000E+01 0.0000 64 MnOH+ 0.40763E-09 -9.3897 0.37095E-09 -9.4307 0.91004E+00 -0.0409 65 MnO2-2 0.13748E-12 -12.8618 0.99557E-13 -13.0019 0.72416E+00 -0.1402 66 HMnO2- 0.83823E-11 -11.0766 0.76248E-11 -11.1178 0.90962E+00 -0.0411 69 MnCl+ 0.35523E-13 -13.4495 0.32327E-13 -13.4904 0.91004E+00 -0.0409 70 MnSO4,aq 0.22298E-12 -12.6517 0.22298E-12 -12.6517 0.10000E+01 0.0000 71 NaCl,aq 0.13458E-06 -6.8710 0.13458E-06 -6.8710 0.10000E+01 0.0000 72 NaOH,aq 0.40840E-05 -5.3889 0.40840E-05 -5.3889 0.10000E+01 0.0000 74 OH- 0.18663E-02 -2.7290 0.16969E-02 -2.7703 0.90923E+00 -0.0413 79 HPO3-2 0.17783E-16 -16.7500 0.12878E-16 -16.8902 0.72416E+00 -0.1402 82 H3PO4,aq 0.53029E-14 -14.2755 0.53029E-14 -14.2755 0.10000E+01 0.0000 83 H2PO4- 0.44902E-07 -7.3477 0.40853E-07 -7.3888 0.90982E+00 -0.0410 84 PO4-3 0.32607E-07 -7.4867 0.16286E-07 -7.7882 0.49947E+00 -0.3015 87 H2P2O7-2 0.18038E-15 -15.7438 0.13062E-15 -15.8840 0.72416E+00 -0.1402 88 HP2O7-3 0.15345E-12 -12.8140 0.75772E-13 -13.1205 0.49377E+00 -0.3065 89 P2O7-4 0.18173E-12 -12.7406 0.52881E-13 -13.2767 0.29099E+00 -0.5361 90 H2S,aq 0.50510E-16 -16.2966 0.50476E-16 -16.2969 0.99931E+00 -0.0003 97 SO3-2 0.21447E-14 -14.6686 0.15584E-14 -14.8073 0.72664E+00 -0.1387 98 HSO3- 0.35441E-16 -16.4505 0.32238E-16 -16.4916 0.90962E+00 -0.0411 99 HSO4- 0.66588E-11 -11.1766 0.60611E-11 -11.2175 0.91024E+00 -0.0408 Charge balance for all species = 0.5525E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3880540E-09 -.3653977E-02 -.3681891E+01 0.0000 2 H2O 0.1000000E+01 0.5550863E+02 0.9997061E+06 0.0000 3 Cl- 0.1379148E-03 0.1380495E-03 0.4892807E+01 5.5501 4 SO4-- 0.2550600E-04 0.2551889E-04 0.2450654E+01 14.1699 5 HCO3- 0.9837299E-05 0.1307713E-04 0.7976918E+00 4.4035 6 HS- 0.5224581E-13 -.5026963E-09 -.1662021E-04 -3.8714 7 Al+++ 0.2373039E-25 0.4761164E-04 0.1284250E+01 2.4236 8 H4SiO4 0.5002075E-03 0.2090061E-02 0.2008271E+03 -3.3008 9 Ca++ 0.1230904E-07 0.1487390E-07 0.5959382E-03 10.8528 10 Mg++ 0.7455711E-10 0.1426618E-09 0.3467359E-05 8.6346 11 Fe++ 0.4408870E-12 0.8767067E-08 0.4894682E-03 6.4065 12 K+ 0.4329515E-04 0.4335615E-04 0.1694806E+01 5.0471 13 Na+ 0.3611991E-02 0.3688252E-02 0.8476687E+02 6.9682 14 Mn++ 0.5890337E-10 0.8350133E-09 0.4586027E-04 8.5324 15 HPO4-- 0.9098136E-05 0.9175646E-05 0.8804065E+00 13.7223 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4964595E-01 -.3651984E-02 -.4599396E-01 0.0000000E+00 2 H2O 0.5547066E+02 0.5547835E+02 -.7694891E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1086170E-03 0.2550497E-04 0.8311201E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8311251E-04 -.5024221E-09 -.8311201E-04 0.0000000E+00 7 Al+++ 0.9778964E-02 0.4758567E-04 0.9731378E-02 0.0000000E+00 8 H4SiO4 0.3122794E-01 0.2088921E-02 0.2913902E-01 0.0000000E+00 9 Ca++ 0.3463749E-02 0.1486579E-07 0.3463734E-02 0.0000000E+00 10 Mg++ 0.2380159E-02 0.1425840E-09 0.2380159E-02 0.0000000E+00 11 Fe++ 0.2138313E-02 0.8762285E-08 0.2138304E-02 0.0000000E+00 12 K+ 0.6367304E-03 0.4333251E-04 0.5933979E-03 0.0000000E+00 13 Na+ 0.3924547E-02 0.3686241E-02 0.2383061E-03 0.0000000E+00 14 Mn++ 0.5199845E-04 0.8345579E-09 0.5199761E-04 0.0000000E+00 15 HPO4-- 0.1774681E-04 0.9170641E-05 0.8576171E-05 0.0000000E+00 Chg. balance for solid moles: -.3341E-17 Mass of aqueous solution: 0.999753E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.2859E-05 -5.544 0.1436E-02 -2.843 0.4443E-01 0.4563E-03 clinochlore 0.4760E-03 -3.322 0.2646 -0.577 8.187 0.1006 daphnite 0.2947E-03 -3.531 0.2103 -0.677 6.506 0.6371E-01 chlorite-Mn 0.1040E-04 -4.983 0.7373E-02 -2.132 0.2281 0.2350E-02 hematite 0.2748E-03 -3.561 0.4389E-01 -1.358 1.358 0.8318E-02 microcline 0.5934E-03 -3.227 0.1652 -0.782 5.110 0.6452E-01 paragonite 0.2193E-03 -3.659 0.8381E-01 -1.077 2.593 0.2897E-01 stilbite 0.3449E-02 -2.462 2.431 0.386 75.21 1.134 nontronite-Na 0.5764E-04 -4.239 0.2451E-01 -1.611 0.7585 0.7615E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.231926 g Volume = 1.410396 cm3 Porosity: 35.8794% V(tot) - V(min): 0.78920E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2.9990000 g log = 0.4770 Original solution: 1000.0103000 g Original solution / Rock added: 333.45 (Water/Rock Ratio), log = 2.5230 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.6892E-06 1.0073 0.7303E-06 0.7249E-06 CH4,gas 0.3353E-16 1.0129 0.3572E-16 0.3527E-16 H2,gas 0.8060E-06 1.0006 0.8483E-06 0.8478E-06 H2S,gas 0.1405E-14 0.9959 0.1472E-14 0.1478E-14 S2,gas 0.1072E-36 1.0000 0.1128E-36 0.1128E-36 CO,gas 0.1525E-15 1.0000 0.1605E-15 0.1605E-15 SO3,gas 0.8206E-39 1.0000 0.8633E-39 0.8633E-39 SO2,gas 0.2634E-22 1.0000 0.2770E-22 0.2770E-22 HCl,gas 0.1400E-16 1.0000 0.1473E-16 0.1473E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.37914E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.30331E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.50 -8.14 -2.712 0.13893E+05 -6.137 3 CH4,gas 4.81 -13.64 -18.45 -4.612 0.31498E+05 -16.447 4 H2,gas 8.29 0.22 -8.07 -4.612 0.13782E+05 -6.071 5 H2S,gas -5.94 -22.77 -16.83 -8.416 0.28740E+05 -14.832 6 S2,gas -7.03 -45.98 -38.95 -5.992 0.66502E+05 -36.948 7 CO,gas 3.51 -14.28 -17.79 -5.475 0.30384E+05 -15.795 8 SO3,gas 17.43 -23.64 -41.06 -10.266 0.70115E+05 -39.064 9 SO2,gas 1.14 -23.42 -24.56 -6.549 0.41931E+05 -22.557 10 HCl,gas 5.48 -13.35 -18.83 -9.416 0.32155E+05 -16.832 11 acmite 7.74 6.67 -1.07 -0.111 0.18305E+04 15 albite-high 0.75 -0.51 -1.26 -0.097 0.21520E+04 16 albite -0.33 -0.51 -0.18 -0.014 0.31130E+03 19 spessartine 24.55 20.54 -4.01 -0.200 0.68433E+04 20 analcite 3.37 2.79 -0.58 -0.064 0.99113E+03 21 andalusite 5.06 1.55 -3.52 -0.352 0.60033E+04 22 andradite 39.09 35.25 -3.83 -0.199 0.65470E+04 26 annite 20.21 16.79 -3.42 -0.190 0.58421E+04 27 phlogopite 27.15 23.47 -3.67 -0.204 0.62743E+04 29 anorthite 12.80 9.10 -3.70 -0.285 0.63164E+04 35 aragonite 0.99 -3.65 -4.63 -1.544 0.79110E+04 36 brucite 12.58 8.63 -3.94 -0.788 0.67309E+04 37 calcite 0.83 -3.65 -4.48 -1.493 0.76497E+04 38 carnegieite-low 9.06 6.09 -2.97 -0.425 0.50772E+04 39 carnegieite-high 10.13 6.09 -4.04 -0.578 0.69041E+04 40 carpholite-Mg 8.65 6.88 -1.77 -0.118 0.30225E+04 41 carpholite-Fe 6.78 4.65 -2.13 -0.142 0.36382E+04 42 celadonite 5.40 2.90 -2.50 -0.147 0.42662E+04 43 celadonite-Fe 3.94 0.67 -3.26 -0.192 0.55716E+04 44 chrysotile 23.94 19.30 -4.64 -0.386 0.79146E+04 50 chloritoid-Mg 13.26 10.18 -3.08 -0.205 0.52594E+04 51 chloritoid-Fe 9.24 7.95 -1.29 -0.086 0.21953E+04 52 chloritoid-Mn 11.46 10.08 -1.38 -0.092 0.23637E+04 54 coesite -2.37 -3.30 -0.93 -0.310 0.15905E+04 59 corundum 8.43 4.85 -3.59 -0.326 0.61232E+04 61 cristobalite -2.55 -3.30 -0.75 -0.251 0.12834E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.42 -0.47 -0.079 0.80667E+03 67 diopside 16.22 12.89 -3.33 -0.333 0.56855E+04 68 hedenbergite 14.24 10.66 -3.59 -0.359 0.61244E+04 75 epidote 24.78 22.95 -1.83 -0.089 0.31180E+04 76 clinozoisite 22.92 19.07 -3.85 -0.175 0.65689E+04 77 epidote-Fe 29.94 26.82 -3.11 -0.162 0.53145E+04 78 fayalite 14.08 9.51 -4.57 -0.652 0.77976E+04 79 ferrosilite 11.19 6.21 -4.98 -0.498 0.84969E+04 83 gibbsite 4.10 2.42 -1.67 -0.239 0.28579E+04 84 glaucophane 23.11 18.28 -4.83 -0.131 0.82468E+04 87 greenalite 16.19 12.62 -3.58 -0.298 0.61064E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.79 -1.46 -0.146 0.24942E+04 97 kalsilite 7.62 4.17 -3.45 -0.493 0.58914E+04 98 kaolinite -1.27 -1.75 -0.48 -0.044 0.82173E+03 99 kyanite 4.93 1.55 -3.39 -0.339 0.57801E+04 101 laumontite 2.97 2.50 -0.48 -0.032 0.81592E+03 102 lawsonite 9.68 9.10 -0.58 -0.039 0.99030E+03 103 leucite 4.17 0.87 -3.30 -0.330 0.56322E+04 105 lizardite 23.29 19.30 -3.99 -0.332 0.68049E+04 107 magnetite 20.13 19.00 -1.13 -0.092 0.19271E+04 108 minnesotaite 10.46 6.02 -4.44 -0.261 0.75889E+04 113 margarite 17.45 13.95 -3.51 -0.140 0.59866E+04 120 muscovite 2.68 2.42 -0.26 -0.016 0.45023E+03 122 nepheline 8.38 6.09 -2.29 -0.327 0.39052E+04 134 phlogopite-Na 29.73 25.39 -4.34 -0.241 0.74075E+04 136 prehnite 19.47 16.65 -2.82 -0.166 0.48082E+04 137 prehnite-Fe 22.59 20.53 -2.06 -0.124 0.35196E+04 138 pumpellyite-Fe 46.47 42.13 -4.34 -0.096 0.74099E+04 139 pumpellyite-Mg 49.19 44.36 -4.84 -0.107 0.82559E+04 145 pyroxmangite 7.42 5.23 -2.18 -0.437 0.37299E+04 146 pyrophyllite -6.10 -8.36 -2.26 -0.141 0.38556E+04 147 quartz -2.98 -3.30 -0.32 -0.106 0.54443E+03 152 rhodonite 7.46 5.23 -2.23 -0.446 0.38091E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.55 -3.77 -0.377 0.64455E+04 164 stilpnomelane-Fe 13.18 13.00 -0.18 -0.005 0.31182E+03 165 stilpnomelane-Mg 27.60 24.14 -3.46 -0.103 0.59066E+04 168 sudoite 21.22 17.06 -4.15 -0.134 0.70945E+04 171 talc 16.55 12.70 -3.85 -0.227 0.65789E+04 174 tephroite 18.11 13.76 -4.35 -0.621 0.74256E+04 177 topaz-H 4.67 1.55 -3.12 -0.284 0.53292E+04 178 tridymite -2.61 -3.30 -0.69 -0.229 0.11717E+04 187 wairakite 4.06 2.50 -1.56 -0.092 0.26667E+04 188 walstromite 11.53 7.55 -3.98 -0.795 0.67888E+04 189 wollastonite 10.48 7.55 -2.93 -0.586 0.50027E+04 190 pseudo-wollastonite 11.02 7.55 -3.47 -0.694 0.59213E+04 191 zoisite 22.96 19.07 -3.89 -0.177 0.66415E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.68 -3.12 -0.193 0.53216E+04 194 beidellite-H -2.24 -6.47 -4.23 -0.270 0.72156E+04 195 beidellite-K -1.44 -4.80 -3.37 -0.206 0.57481E+04 196 beidellite-Mg -1.71 -5.04 -3.34 -0.206 0.56951E+04 197 beidellite-Na -1.26 -4.17 -2.91 -0.178 0.49695E+04 199 chalcedony -2.79 -3.30 -0.51 -0.169 0.86475E+03 201 montmorillonite-Ca -2.21 -4.52 -2.30 -0.142 0.39302E+04 202 montmorillonite-K -2.16 -4.64 -2.48 -0.152 0.42345E+04 203 montmorillonite-Mg -2.40 -4.88 -2.48 -0.153 0.42348E+04 204 montmorillonite-Na -1.96 -4.01 -2.05 -0.125 0.34941E+04 205 nontronite-Ca 3.28 3.07 -0.21 -0.013 0.35112E+03 206 nontronite-H 2.60 1.28 -1.31 -0.088 0.22409E+04 207 nontronite-K 3.40 2.95 -0.45 -0.029 0.77685E+03 208 nontronite-Mg 3.14 2.71 -0.43 -0.028 0.73633E+03 224 tobermorite 9.84 5.74 -4.10 -1.119 0.69998E+04 233 boehmite 4.43 2.42 -2.01 -0.334 0.34251E+04 235 ferrous-oxide 9.82 6.41 -3.42 -0.854 0.58356E+04 240 silica-amorphous -2.08 -3.30 -1.22 -0.407 0.20849E+04 242 an20ab80 2.08 1.41 -0.67 -0.051 0.11407E+04 243 an25ab75 2.71 1.89 -0.82 -0.063 0.13960E+04 244 an30ab70 3.34 2.37 -0.97 -0.075 0.16596E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 2.9990000 g New total amount of reactant added: 3.0990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4565E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3.0990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9994E+00 Moles total = 0.5547E+02 kg total = 0.9993E+00 Activity = 1.0000 Stoichiometric ionic strength = .2285794E-02 Osmotic coef. = 0.9733 True ionic strength = .3803699E-02 Chg. balance for total moles = 0.4565E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.37589E-09 -9.4249 0.34206E-09 -9.4659 0.91000E+00 -0.0410 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13791E-03 -3.8604 0.12532E-03 -3.9020 0.90867E+00 -0.0416 4 SO4-- 0.25507E-04 -4.5933 0.18404E-04 -4.7351 0.72154E+00 -0.1417 5 HCO3- 0.97494E-05 -5.0110 0.88621E-05 -5.0525 0.90899E+00 -0.0414 6 HS- 0.54203E-13 -13.2660 0.49254E-13 -13.3076 0.90870E+00 -0.0416 7 Al+++ 0.21348E-25 -25.6706 0.10441E-25 -25.9812 0.48911E+00 -0.3106 8 H4SiO4 0.49817E-03 -3.3026 0.49817E-03 -3.3026 0.10000E+01 0.0000 9 Ca++ 0.12312E-07 -7.9097 0.88679E-08 -8.0522 0.72028E+00 -0.1425 10 Mg++ 0.70749E-10 -10.1503 0.50903E-10 -10.2933 0.71948E+00 -0.1430 11 Fe++ 0.41836E-12 -12.3784 0.30109E-12 -12.5213 0.71967E+00 -0.1429 12 K+ 0.43167E-04 -4.3649 0.39240E-04 -4.4063 0.90905E+00 -0.0414 13 Na+ 0.37228E-02 -2.4291 0.33826E-02 -2.4707 0.90864E+00 -0.0416 14 Mn++ 0.55894E-10 -10.2526 0.40233E-10 -10.3954 0.71982E+00 -0.1428 15 HPO4-- 0.88018E-05 -5.0554 0.63511E-05 -5.1972 0.72157E+00 -0.1417 16 HSiO3- 0.15637E-02 -2.8058 0.14209E-02 -2.8474 0.90867E+00 -0.0416 17 Ca(HSiO3)+ 0.31055E-09 -9.5079 0.28232E-09 -9.5493 0.90909E+00 -0.0414 18 Mg(HSiO3)+ 0.22185E-11 -11.6539 0.20168E-11 -11.6953 0.90909E+00 -0.0414 19 NaHSiO3,aq 0.76339E-04 -4.1173 0.76339E-04 -4.1173 0.10000E+01 0.0000 20 AlO+ 0.12672E-13 -13.8971 0.11520E-13 -13.9385 0.90909E+00 -0.0414 21 AlOH+2 0.27418E-19 -19.5620 0.19740E-19 -19.7046 0.71998E+00 -0.1427 22 HAlO2,aq 0.67395E-08 -8.1714 0.67395E-08 -8.1714 0.10000E+01 0.0000 23 AlO2- 0.48437E-04 -4.3148 0.43994E-04 -4.3566 0.90827E+00 -0.0418 24 CH4,aq 0.23289E-19 -19.6328 0.23273E-19 -19.6331 0.99929E+00 -0.0003 29 CO,aq 0.99143E-19 -19.0037 0.99143E-19 -19.0037 0.10000E+01 0.0000 30 CO2,aq 0.61162E-08 -8.2135 0.61119E-08 -8.2138 0.99929E+00 -0.0003 31 CO3-2 0.33216E-05 -5.4787 0.23954E-05 -5.6206 0.72117E+00 -0.1420 32 CaCO3,aq 0.26017E-09 -9.5847 0.26017E-09 -9.5847 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.21782E-11 -11.6619 0.19802E-11 -11.7033 0.90909E+00 -0.0414 34 CaCl+ 0.19479E-11 -11.7104 0.17709E-11 -11.7518 0.90909E+00 -0.0414 35 CaCl2,aq 0.51671E-16 -16.2868 0.51671E-16 -16.2868 0.10000E+01 0.0000 36 CaOH+ 0.20108E-08 -8.6966 0.18280E-08 -8.7380 0.90909E+00 -0.0414 37 CaSO4,aq 0.50851E-10 -10.2937 0.50851E-10 -10.2937 0.10000E+01 0.0000 38 HCl,aq 0.80630E-14 -14.0935 0.80630E-14 -14.0935 0.10000E+01 0.0000 43 FeCl+ 0.64644E-16 -16.1895 0.58767E-16 -16.2309 0.90909E+00 -0.0414 46 FeO,aq 0.10176E-09 -9.9924 0.10176E-09 -9.9924 0.10000E+01 0.0000 47 FeOH+ 0.32099E-10 -10.4935 0.29181E-10 -10.5349 0.90909E+00 -0.0414 48 HFeO2- 0.35213E-08 -8.4533 0.31997E-08 -8.4949 0.90867E+00 -0.0416 49 FeO+ 0.31125E-14 -14.5069 0.28296E-14 -14.5483 0.90909E+00 -0.0414 51 FeO2- 0.52307E-08 -8.2814 0.47530E-08 -8.3230 0.90867E+00 -0.0416 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.63027E-09 -9.2005 0.62983E-09 -9.2008 0.99929E+00 -0.0003 54 KCl,aq 0.87072E-10 -10.0601 0.87072E-10 -10.0601 0.10000E+01 0.0000 55 KHSO4,aq 0.66105E-18 -18.1798 0.66105E-18 -18.1798 0.10000E+01 0.0000 56 KOH,aq 0.50011E-07 -7.3009 0.50011E-07 -7.3009 0.10000E+01 0.0000 57 KSO4- 0.12245E-07 -7.9121 0.11126E-07 -7.9537 0.90867E+00 -0.0416 58 MgCO3,aq 0.37317E-12 -12.4281 0.37317E-12 -12.4281 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12750E-13 -13.8945 0.11591E-13 -13.9359 0.90909E+00 -0.0414 60 MgCl+ 0.10151E-13 -13.9935 0.92279E-14 -14.0349 0.90909E+00 -0.0414 61 MgOH+ 0.63945E-10 -10.1942 0.58132E-10 -10.2356 0.90909E+00 -0.0414 63 MnO,aq 0.36299E-09 -9.4401 0.36299E-09 -9.4401 0.10000E+01 0.0000 64 MnOH+ 0.39847E-09 -9.3996 0.36224E-09 -9.4410 0.90909E+00 -0.0414 65 MnO2-2 0.14877E-12 -12.8275 0.10729E-12 -12.9694 0.72117E+00 -0.1420 66 HMnO2- 0.87505E-11 -11.0580 0.79513E-11 -11.0996 0.90867E+00 -0.0416 69 MnCl+ 0.33567E-13 -13.4741 0.30515E-13 -13.5155 0.90909E+00 -0.0414 70 MnSO4,aq 0.20985E-12 -12.6781 0.20985E-12 -12.6781 0.10000E+01 0.0000 71 NaCl,aq 0.13842E-06 -6.8588 0.13842E-06 -6.8588 0.10000E+01 0.0000 72 NaOH,aq 0.43453E-05 -5.3620 0.43453E-05 -5.3620 0.10000E+01 0.0000 74 OH- 0.19307E-02 -2.7143 0.17536E-02 -2.7561 0.90827E+00 -0.0418 79 HPO3-2 0.17519E-16 -16.7565 0.12634E-16 -16.8984 0.72117E+00 -0.1420 82 H3PO4,aq 0.47842E-14 -14.3202 0.47842E-14 -14.3202 0.10000E+01 0.0000 83 H2PO4- 0.41907E-07 -7.3777 0.38088E-07 -7.4192 0.90888E+00 -0.0415 84 PO4-3 0.32759E-07 -7.4847 0.16215E-07 -7.7901 0.49497E+00 -0.3054 87 H2P2O7-2 0.15744E-15 -15.8029 0.11354E-15 -15.9449 0.72117E+00 -0.1420 88 HP2O7-3 0.13913E-12 -12.8566 0.68062E-13 -13.1671 0.48918E+00 -0.3105 89 P2O7-4 0.17149E-12 -12.7658 0.49087E-13 -13.3090 0.28624E+00 -0.5433 90 H2S,aq 0.50657E-16 -16.2954 0.50621E-16 -16.2957 0.99929E+00 -0.0003 97 SO3-2 0.21839E-14 -14.6608 0.15805E-14 -14.8012 0.72371E+00 -0.1404 98 HSO3- 0.34818E-16 -16.4582 0.31638E-16 -16.4998 0.90867E+00 -0.0416 99 HSO4- 0.64238E-11 -11.1922 0.58412E-11 -11.2335 0.90930E+00 -0.0413 Charge balance for all species = 0.5502E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3758920E-09 -.3772276E-02 -.3801065E+01 0.0000 2 H2O 0.1000000E+01 0.5550864E+02 0.9996989E+06 0.0000 3 Cl- 0.1379134E-03 0.1380519E-03 0.4892856E+01 5.5639 4 SO4-- 0.2550653E-04 0.2551936E-04 0.2450680E+01 14.1967 5 HCO3- 0.9749404E-05 0.1307736E-04 0.7976998E+00 4.4134 6 HS- 0.5420304E-13 -.5216494E-09 -.1724671E-04 -3.8417 7 Al+++ 0.2134807E-25 0.4844363E-04 0.1306682E+01 2.4164 8 H4SiO4 0.4981685E-03 0.2138258E-02 0.2054566E+03 -3.3026 9 Ca++ 0.1231176E-07 0.1494829E-07 0.5989145E-03 10.8796 10 Mg++ 0.7074893E-10 0.1373089E-09 0.3337232E-05 8.6385 11 Fe++ 0.4183648E-12 0.9089752E-08 0.5074801E-03 6.4105 12 K+ 0.4316650E-04 0.4322885E-04 0.1689817E+01 5.0596 13 Na+ 0.3722764E-02 0.3803587E-02 0.8741695E+02 6.9952 14 Mn++ 0.5589411E-10 0.8264904E-09 0.4539184E-04 8.5364 15 HPO4-- 0.8801793E-05 0.8876459E-05 0.8516931E+00 13.7346 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5130180E-01 -.3770153E-02 -.4753165E-01 0.0000000E+00 2 H2O 0.5546940E+02 0.5547740E+02 -.7995727E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1113883E-03 0.2550499E-04 0.8588333E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8588385E-04 -.5213558E-09 -.8588333E-04 0.0000000E+00 7 Al+++ 0.1010504E-01 0.4841636E-04 0.1005662E-01 0.0000000E+00 8 H4SiO4 0.3226921E-01 0.2137054E-02 0.3013216E-01 0.0000000E+00 9 Ca++ 0.3578763E-02 0.1493988E-07 0.3578748E-02 0.0000000E+00 10 Mg++ 0.2459524E-02 0.1372316E-09 0.2459524E-02 0.0000000E+00 11 Fe++ 0.2209614E-02 0.9084636E-08 0.2209605E-02 0.0000000E+00 12 K+ 0.6579618E-03 0.4320451E-04 0.6147573E-03 0.0000000E+00 13 Na+ 0.4050071E-02 0.3801446E-02 0.2486249E-03 0.0000000E+00 14 Mn++ 0.5373231E-04 0.8260252E-09 0.5373148E-04 0.0000000E+00 15 HPO4-- 0.1833857E-04 0.8871463E-05 0.9467107E-05 0.0000000E+00 Chg. balance for solid moles: 0.9951E-17 Mass of aqueous solution: 0.999743E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3.0990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3156E-05 -5.501 0.1585E-02 -2.800 0.4744E-01 0.5037E-03 clinochlore 0.4919E-03 -3.308 0.2734 -0.563 8.183 0.1040 daphnite 0.3045E-03 -3.516 0.2173 -0.663 6.503 0.6584E-01 chlorite-Mn 0.1075E-04 -4.969 0.7619E-02 -2.118 0.2280 0.2428E-02 hematite 0.2765E-03 -3.558 0.4415E-01 -1.355 1.321 0.8368E-02 microcline 0.6148E-03 -3.211 0.1711 -0.767 5.121 0.6684E-01 paragonite 0.2265E-03 -3.645 0.8657E-01 -1.063 2.591 0.2992E-01 stilbite 0.3563E-02 -2.448 2.511 0.400 75.15 1.171 nontronite-Na 0.6707E-04 -4.173 0.2852E-01 -1.545 0.8537 0.8861E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.341135 g Volume = 1.457889 cm3 Porosity: 34.9040% V(tot) - V(min): 0.78171E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.0990000 g log = 0.4912 Original solution: 1000.0103000 g Original solution / Rock added: 322.69 (Water/Rock Ratio), log = 2.5088 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.6602E-06 1.0073 0.6996E-06 0.6945E-06 CH4,gas 0.3454E-16 1.0129 0.3680E-16 0.3633E-16 H2,gas 0.8207E-06 1.0006 0.8639E-06 0.8634E-06 H2S,gas 0.1409E-14 0.9959 0.1476E-14 0.1482E-14 S2,gas 0.1040E-36 1.0000 0.1094E-36 0.1094E-36 CO,gas 0.1488E-15 1.0000 0.1565E-15 0.1565E-15 SO3,gas 0.7653E-39 1.0000 0.8051E-39 0.8051E-39 SO2,gas 0.2501E-22 1.0000 0.2631E-22 0.2631E-22 HCl,gas 0.1353E-16 1.0000 0.1424E-16 0.1424E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.28814E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 0.12891E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.52 -8.16 -2.718 0.13925E+05 -6.155 3 CH4,gas 4.81 -13.62 -18.43 -4.609 0.31476E+05 -16.434 4 H2,gas 8.29 0.22 -8.06 -4.608 0.13768E+05 -6.064 5 H2S,gas -5.94 -22.77 -16.83 -8.415 0.28738E+05 -14.831 6 S2,gas -7.03 -45.99 -38.96 -5.994 0.66525E+05 -36.961 7 CO,gas 3.51 -14.30 -17.81 -5.479 0.30402E+05 -15.805 8 SO3,gas 17.43 -23.67 -41.09 -10.274 0.70167E+05 -39.094 9 SO2,gas 1.14 -23.44 -24.58 -6.555 0.41970E+05 -22.580 10 HCl,gas 5.48 -13.37 -18.85 -9.423 0.32180E+05 -16.847 11 acmite 7.74 6.69 -1.05 -0.109 0.17906E+04 15 albite-high 0.75 -0.50 -1.25 -0.096 0.21274E+04 16 albite -0.33 -0.50 -0.17 -0.013 0.28670E+03 19 spessartine 24.55 20.53 -4.02 -0.201 0.68568E+04 20 analcite 3.37 2.81 -0.56 -0.063 0.96350E+03 21 andalusite 5.06 1.53 -3.53 -0.353 0.60310E+04 22 andradite 39.09 35.33 -3.76 -0.195 0.64187E+04 26 annite 20.21 16.80 -3.41 -0.189 0.58219E+04 27 phlogopite 27.15 23.48 -3.66 -0.203 0.62541E+04 29 anorthite 12.80 9.11 -3.69 -0.284 0.63013E+04 35 aragonite 0.99 -3.64 -4.62 -1.542 0.78970E+04 36 brucite 12.58 8.64 -3.94 -0.788 0.67241E+04 37 calcite 0.83 -3.64 -4.47 -1.491 0.76357E+04 38 carnegieite-low 9.06 6.11 -2.96 -0.422 0.50466E+04 39 carnegieite-high 10.13 6.11 -4.03 -0.575 0.68734E+04 40 carpholite-Mg 8.65 6.87 -1.78 -0.119 0.30465E+04 41 carpholite-Fe 6.78 4.64 -2.14 -0.143 0.36621E+04 42 celadonite 5.40 2.90 -2.50 -0.147 0.42625E+04 43 celadonite-Fe 3.94 0.68 -3.26 -0.192 0.55679E+04 44 chrysotile 23.94 19.31 -4.63 -0.386 0.79005E+04 50 chloritoid-Mg 13.26 10.17 -3.09 -0.206 0.52802E+04 51 chloritoid-Fe 9.24 7.94 -1.30 -0.087 0.22162E+04 52 chloritoid-Mn 11.46 10.07 -1.40 -0.093 0.23846E+04 54 coesite -2.37 -3.30 -0.93 -0.311 0.15935E+04 59 corundum 8.43 4.83 -3.60 -0.327 0.61478E+04 61 cristobalite -2.55 -3.30 -0.75 -0.251 0.12864E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.42 -0.48 -0.080 0.81897E+03 67 diopside 16.22 12.91 -3.30 -0.330 0.56391E+04 68 hedenbergite 14.24 10.68 -3.56 -0.356 0.60779E+04 75 epidote 24.78 22.98 -1.79 -0.087 0.30600E+04 76 clinozoisite 22.92 19.10 -3.82 -0.174 0.65233E+04 77 epidote-Fe 29.94 26.87 -3.07 -0.160 0.52443E+04 78 fayalite 14.08 9.52 -4.56 -0.652 0.77871E+04 79 ferrosilite 11.19 6.22 -4.97 -0.497 0.84895E+04 83 gibbsite 4.10 2.42 -1.68 -0.240 0.28702E+04 84 glaucophane 23.11 18.32 -4.79 -0.130 0.81835E+04 87 greenalite 16.19 12.63 -3.57 -0.297 0.60923E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.81 -1.44 -0.144 0.24665E+04 97 kalsilite 7.62 4.17 -3.45 -0.492 0.58853E+04 98 kaolinite -1.27 -1.77 -0.50 -0.045 0.85238E+03 99 kyanite 4.93 1.53 -3.40 -0.340 0.58077E+04 101 laumontite 2.97 2.50 -0.47 -0.032 0.80683E+03 102 lawsonite 9.68 9.11 -0.57 -0.038 0.97516E+03 103 leucite 4.17 0.87 -3.30 -0.330 0.56292E+04 105 lizardite 23.29 19.31 -3.98 -0.331 0.67908E+04 107 magnetite 20.13 19.01 -1.12 -0.092 0.19204E+04 108 minnesotaite 10.46 6.02 -4.44 -0.261 0.75808E+04 113 margarite 17.45 13.94 -3.51 -0.140 0.59960E+04 120 muscovite 2.68 2.40 -0.28 -0.016 0.47483E+03 122 nepheline 8.38 6.11 -2.27 -0.324 0.38745E+04 134 phlogopite-Na 29.73 25.42 -4.31 -0.240 0.73627E+04 136 prehnite 19.47 16.68 -2.78 -0.164 0.47503E+04 137 prehnite-Fe 22.59 20.57 -2.02 -0.122 0.34494E+04 138 pumpellyite-Fe 46.47 42.20 -4.28 -0.095 0.72997E+04 139 pumpellyite-Mg 49.19 44.42 -4.77 -0.106 0.81456E+04 145 pyroxmangite 7.42 5.23 -2.18 -0.436 0.37262E+04 146 pyrophyllite -6.10 -8.38 -2.28 -0.142 0.38923E+04 147 quartz -2.98 -3.30 -0.32 -0.107 0.54746E+03 152 rhodonite 7.46 5.23 -2.23 -0.446 0.38054E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.53 -3.79 -0.379 0.64731E+04 164 stilpnomelane-Fe 13.18 12.99 -0.19 -0.006 0.31627E+03 165 stilpnomelane-Mg 27.60 24.13 -3.46 -0.103 0.59111E+04 168 sudoite 21.22 17.03 -4.18 -0.135 0.71393E+04 171 talc 16.55 12.71 -3.85 -0.226 0.65708E+04 174 tephroite 18.11 13.77 -4.34 -0.620 0.74152E+04 177 topaz-H 4.67 1.53 -3.14 -0.285 0.53568E+04 178 tridymite -2.61 -3.30 -0.69 -0.229 0.11748E+04 187 wairakite 4.06 2.50 -1.56 -0.092 0.26576E+04 188 walstromite 11.53 7.58 -3.95 -0.790 0.67460E+04 189 wollastonite 10.48 7.58 -2.90 -0.581 0.49599E+04 190 pseudo-wollastonite 11.02 7.58 -3.44 -0.689 0.58785E+04 191 zoisite 22.96 19.10 -3.86 -0.176 0.65959E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.70 -3.14 -0.194 0.53538E+04 194 beidellite-H -2.24 -6.49 -4.25 -0.271 0.72554E+04 195 beidellite-K -1.44 -4.82 -3.39 -0.207 0.57808E+04 196 beidellite-Mg -1.71 -5.06 -3.36 -0.208 0.57338E+04 197 beidellite-Na -1.26 -4.18 -2.92 -0.179 0.49941E+04 199 chalcedony -2.79 -3.30 -0.51 -0.169 0.86777E+03 201 montmorillonite-Ca -2.21 -4.53 -2.32 -0.143 0.39530E+04 202 montmorillonite-K -2.16 -4.65 -2.49 -0.153 0.42579E+04 203 montmorillonite-Mg -2.40 -4.90 -2.50 -0.154 0.42641E+04 204 montmorillonite-Na -1.96 -4.02 -2.06 -0.126 0.35093E+04 205 nontronite-Ca 3.28 3.07 -0.21 -0.014 0.35874E+03 206 nontronite-H 2.60 1.27 -1.32 -0.089 0.22561E+04 207 nontronite-K 3.40 2.94 -0.46 -0.030 0.78496E+03 208 nontronite-Mg 3.14 2.70 -0.44 -0.029 0.75039E+03 224 tobermorite 9.84 5.76 -4.08 -1.113 0.69646E+04 233 boehmite 4.43 2.42 -2.01 -0.336 0.34374E+04 235 ferrous-oxide 9.82 6.41 -3.41 -0.853 0.58289E+04 240 silica-amorphous -2.08 -3.30 -1.22 -0.408 0.20880E+04 242 an20ab80 2.08 1.42 -0.65 -0.050 0.11180E+04 243 an25ab75 2.71 1.90 -0.80 -0.062 0.13737E+04 244 an30ab70 3.34 2.38 -0.96 -0.074 0.16378E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 3.0990000 g New total amount of reactant added: 3.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4565E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3.1990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9994E+00 Moles total = 0.5547E+02 kg total = 0.9993E+00 Activity = 1.0000 Stoichiometric ionic strength = .2346542E-02 Osmotic coef. = 0.9730 True ionic strength = .3914075E-02 Chg. balance for total moles = 0.4565E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.36449E-09 -9.4383 0.33136E-09 -9.4797 0.90910E+00 -0.0414 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13791E-03 -3.8604 0.12519E-03 -3.9024 0.90773E+00 -0.0420 4 SO4-- 0.25507E-04 -4.5933 0.18330E-04 -4.7368 0.71863E+00 -0.1435 5 HCO3- 0.96627E-05 -5.0149 0.87743E-05 -5.0568 0.90806E+00 -0.0419 6 HS- 0.56168E-13 -13.2505 0.50987E-13 -13.2925 0.90777E+00 -0.0420 7 Al+++ 0.19274E-25 -25.7150 0.93406E-26 -26.0296 0.48463E+00 -0.3146 8 H4SiO4 0.49620E-03 -3.3043 0.49620E-03 -3.3043 0.10000E+01 0.0000 9 Ca++ 0.12316E-07 -7.9095 0.88346E-08 -8.0538 0.71734E+00 -0.1443 10 Mg++ 0.67255E-10 -10.1723 0.48190E-10 -10.3170 0.71652E+00 -0.1448 11 Fe++ 0.39770E-12 -12.4004 0.28504E-12 -12.5451 0.71672E+00 -0.1447 12 K+ 0.43044E-04 -4.3661 0.39089E-04 -4.4079 0.90812E+00 -0.0419 13 Na+ 0.38335E-02 -2.4164 0.34796E-02 -2.4585 0.90770E+00 -0.0421 14 Mn++ 0.53133E-10 -10.2746 0.38089E-10 -10.4192 0.71686E+00 -0.1446 15 HPO4-- 0.85240E-05 -5.0694 0.61258E-05 -5.2128 0.71866E+00 -0.1435 16 HSiO3- 0.16095E-02 -2.7933 0.14610E-02 -2.8353 0.90773E+00 -0.0420 17 Ca(HSiO3)+ 0.31844E-09 -9.4970 0.28920E-09 -9.5388 0.90817E+00 -0.0418 18 Mg(HSiO3)+ 0.21617E-11 -11.6652 0.19632E-11 -11.7070 0.90817E+00 -0.0418 19 NaHSiO3,aq 0.80744E-04 -4.0929 0.80744E-04 -4.0929 0.10000E+01 0.0000 20 AlO+ 0.12093E-13 -13.9175 0.10982E-13 -13.9593 0.90817E+00 -0.0418 21 AlOH+2 0.25423E-19 -19.5948 0.18229E-19 -19.7392 0.71704E+00 -0.1445 22 HAlO2,aq 0.66322E-08 -8.1783 0.66322E-08 -8.1783 0.10000E+01 0.0000 23 AlO2- 0.49256E-04 -4.3075 0.44691E-04 -4.3498 0.90732E+00 -0.0422 24 CH4,aq 0.23967E-19 -19.6204 0.23949E-19 -19.6207 0.99927E+00 -0.0003 29 CO,aq 0.96779E-19 -19.0142 0.96779E-19 -19.0142 0.10000E+01 0.0000 30 CO2,aq 0.58663E-08 -8.2316 0.58621E-08 -8.2320 0.99927E+00 -0.0003 31 CO3-2 0.34087E-05 -5.4674 0.24483E-05 -5.6111 0.71825E+00 -0.1437 32 CaCO3,aq 0.26491E-09 -9.5769 0.26491E-09 -9.5769 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.21507E-11 -11.6674 0.19532E-11 -11.7092 0.90817E+00 -0.0418 34 CaCl+ 0.19406E-11 -11.7121 0.17624E-11 -11.7539 0.90817E+00 -0.0418 35 CaCl2,aq 0.51370E-16 -16.2893 0.51370E-16 -16.2893 0.10000E+01 0.0000 36 CaOH+ 0.20701E-08 -8.6840 0.18800E-08 -8.7258 0.90817E+00 -0.0418 37 CaSO4,aq 0.50457E-10 -10.2971 0.50457E-10 -10.2971 0.10000E+01 0.0000 38 HCl,aq 0.78027E-14 -14.1078 0.78027E-14 -14.1078 0.10000E+01 0.0000 43 FeCl+ 0.61197E-16 -16.2133 0.55577E-16 -16.2551 0.90817E+00 -0.0418 46 FeO,aq 0.10266E-09 -9.9886 0.10266E-09 -9.9886 0.10000E+01 0.0000 47 FeOH+ 0.31402E-10 -10.5030 0.28518E-10 -10.5449 0.90817E+00 -0.0418 48 HFeO2- 0.36709E-08 -8.4352 0.33322E-08 -8.4773 0.90773E+00 -0.0420 49 FeO+ 0.30182E-14 -14.5202 0.27411E-14 -14.5621 0.90817E+00 -0.0418 51 FeO2- 0.54052E-08 -8.2672 0.49065E-08 -8.3092 0.90773E+00 -0.0420 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.64147E-09 -9.1928 0.64101E-09 -9.1931 0.99927E+00 -0.0003 54 KCl,aq 0.86646E-10 -10.0622 0.86646E-10 -10.0622 0.10000E+01 0.0000 55 KHSO4,aq 0.63534E-18 -18.1970 0.63534E-18 -18.1970 0.10000E+01 0.0000 56 KOH,aq 0.51427E-07 -7.2888 0.51427E-07 -7.2888 0.10000E+01 0.0000 57 KSO4- 0.12161E-07 -7.9150 0.11039E-07 -7.9571 0.90773E+00 -0.0420 58 MgCO3,aq 0.36108E-12 -12.4424 0.36108E-12 -12.4424 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11963E-13 -13.9222 0.10864E-13 -13.9640 0.90817E+00 -0.0418 60 MgCl+ 0.96094E-14 -14.0173 0.87270E-14 -14.0591 0.90817E+00 -0.0418 61 MgOH+ 0.62556E-10 -10.2037 0.56811E-10 -10.2456 0.90817E+00 -0.0418 63 MnO,aq 0.36620E-09 -9.4363 0.36620E-09 -9.4363 0.10000E+01 0.0000 64 MnOH+ 0.38981E-09 -9.4091 0.35401E-09 -9.4510 0.90817E+00 -0.0418 65 MnO2-2 0.16058E-12 -12.7943 0.11534E-12 -12.9380 0.71825E+00 -0.1437 66 HMnO2- 0.91223E-11 -11.0399 0.82807E-11 -11.0819 0.90773E+00 -0.0420 69 MnCl+ 0.31777E-13 -13.4979 0.28859E-13 -13.5397 0.90817E+00 -0.0418 70 MnSO4,aq 0.19787E-12 -12.7036 0.19787E-12 -12.7036 0.10000E+01 0.0000 71 NaCl,aq 0.14224E-06 -6.8470 0.14224E-06 -6.8470 0.10000E+01 0.0000 72 NaOH,aq 0.46142E-05 -5.3359 0.46142E-05 -5.3359 0.10000E+01 0.0000 74 OH- 0.19951E-02 -2.7000 0.18102E-02 -2.7423 0.90732E+00 -0.0422 79 HPO3-2 0.17268E-16 -16.7628 0.12403E-16 -16.9065 0.71825E+00 -0.1437 82 H3PO4,aq 0.43303E-14 -14.3635 0.43303E-14 -14.3635 0.10000E+01 0.0000 83 H2PO4- 0.39196E-07 -7.4068 0.35587E-07 -7.4487 0.90794E+00 -0.0419 84 PO4-3 0.32908E-07 -7.4827 0.16145E-07 -7.7920 0.49060E+00 -0.3093 87 H2P2O7-2 0.13800E-15 -15.8601 0.99120E-16 -16.0038 0.71825E+00 -0.1437 88 HP2O7-3 0.12655E-12 -12.8978 0.61338E-13 -13.2123 0.48471E+00 -0.3145 89 P2O7-4 0.16213E-12 -12.7901 0.45666E-13 -13.3404 0.28166E+00 -0.5503 90 H2S,aq 0.50799E-16 -16.2941 0.50762E-16 -16.2945 0.99927E+00 -0.0003 97 SO3-2 0.22225E-14 -14.6532 0.16021E-14 -14.7953 0.72084E+00 -0.1422 98 HSO3- 0.34225E-16 -16.4657 0.31067E-16 -16.5077 0.90773E+00 -0.0420 99 HSO4- 0.62042E-11 -11.2073 0.56357E-11 -11.2490 0.90838E+00 -0.0417 Charge balance for all species = 0.5482E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3644942E-09 -.3890535E-02 -.3920197E+01 0.0000 2 H2O 0.1000000E+01 0.5550866E+02 0.9996918E+06 0.0000 3 Cl- 0.1379120E-03 0.1380543E-03 0.4892905E+01 5.5773 4 SO4-- 0.2550706E-04 0.2551982E-04 0.2450707E+01 14.2226 5 HCO3- 0.9662746E-05 0.1307759E-04 0.7977078E+00 4.4229 6 HS- 0.5616764E-13 -.5406592E-09 -.1787508E-04 -3.8128 7 Al+++ 0.1927356E-25 0.4926242E-04 0.1328757E+01 2.4095 8 H4SiO4 0.4962019E-03 0.2186483E-02 0.2100888E+03 -3.3043 9 Ca++ 0.1231590E-07 0.1502390E-07 0.6019391E-03 10.9056 10 Mg++ 0.6725479E-10 0.1323551E-09 0.3216810E-05 8.6424 11 Fe++ 0.3976999E-12 0.9414052E-08 0.5255818E-03 6.4143 12 K+ 0.4304426E-04 0.4310794E-04 0.1685078E+01 5.0718 13 Na+ 0.3833452E-02 0.3918952E-02 0.9006770E+02 7.0212 14 Mn++ 0.5313300E-10 0.8186495E-09 0.4496087E-04 8.5402 15 HPO4-- 0.8523979E-05 0.8596083E-05 0.8247849E+00 13.7466 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5295765E-01 -.3888277E-02 -.4906937E-01 0.0000000E+00 2 H2O 0.5546815E+02 0.5547645E+02 -.8296325E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1141597E-03 0.2550501E-04 0.8865465E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8865520E-04 -.5403454E-09 -.8865465E-04 0.0000000E+00 7 Al+++ 0.1043111E-01 0.4923383E-04 0.1038188E-01 0.0000000E+00 8 H4SiO4 0.3331049E-01 0.2185214E-02 0.3112528E-01 0.0000000E+00 9 Ca++ 0.3693777E-02 0.1501518E-07 0.3693762E-02 0.0000000E+00 10 Mg++ 0.2538889E-02 0.1322783E-09 0.2538889E-02 0.0000000E+00 11 Fe++ 0.2280914E-02 0.9408589E-08 0.2280905E-02 0.0000000E+00 12 K+ 0.6791932E-03 0.4308292E-04 0.6361103E-03 0.0000000E+00 13 Na+ 0.4175595E-02 0.3916678E-02 0.2589173E-03 0.0000000E+00 14 Mn++ 0.5546617E-04 0.8181745E-09 0.5546535E-04 0.0000000E+00 15 HPO4-- 0.1893033E-04 0.8591095E-05 0.1033923E-04 0.0000000E+00 Chg. balance for solid moles: 0.2494E-17 Mass of aqueous solution: 0.999733E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3446E-05 -5.463 0.1731E-02 -2.762 0.5017E-01 0.5501E-03 clinochlore 0.5078E-03 -3.294 0.2822 -0.549 8.180 0.1074 daphnite 0.3143E-03 -3.503 0.2243 -0.649 6.500 0.6796E-01 chlorite-Mn 0.1109E-04 -4.955 0.7865E-02 -2.104 0.2279 0.2506E-02 hematite 0.2782E-03 -3.556 0.4442E-01 -1.352 1.288 0.8420E-02 microcline 0.6361E-03 -3.196 0.1771 -0.752 5.132 0.6916E-01 paragonite 0.2337E-03 -3.631 0.8932E-01 -1.049 2.589 0.3087E-01 stilbite 0.3677E-02 -2.435 2.591 0.413 75.09 1.208 nontronite-Na 0.7644E-04 -4.117 0.3251E-01 -1.488 0.9422 0.1010E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.450343 g Volume = 1.505384 cm3 Porosity: 33.9628% V(tot) - V(min): 0.77422E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.1990000 g log = 0.5050 Original solution: 1000.0103000 g Original solution / Rock added: 312.60 (Water/Rock Ratio), log = 2.4950 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.6333E-06 1.0073 0.6710E-06 0.6661E-06 CH4,gas 0.3554E-16 1.0129 0.3787E-16 0.3739E-16 H2,gas 0.8353E-06 1.0006 0.8792E-06 0.8787E-06 H2S,gas 0.1413E-14 0.9959 0.1481E-14 0.1487E-14 S2,gas 0.1010E-36 1.0000 0.1062E-36 0.1062E-36 CO,gas 0.1453E-15 1.0000 0.1528E-15 0.1528E-15 SO3,gas 0.7153E-39 1.0000 0.7524E-39 0.7524E-39 SO2,gas 0.2379E-22 1.0000 0.2503E-22 0.2503E-22 HCl,gas 0.1310E-16 1.0000 0.1378E-16 0.1378E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.28814E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.98575E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.54 -8.17 -2.724 0.13956E+05 -6.173 3 CH4,gas 4.81 -13.61 -18.42 -4.605 0.31455E+05 -16.422 4 H2,gas 8.29 0.23 -8.06 -4.603 0.13755E+05 -6.056 5 H2S,gas -5.94 -22.77 -16.83 -8.415 0.28736E+05 -14.830 6 S2,gas -7.03 -46.01 -38.97 -5.996 0.66547E+05 -36.974 7 CO,gas 3.51 -14.31 -17.82 -5.482 0.30420E+05 -15.816 8 SO3,gas 17.43 -23.70 -41.12 -10.281 0.70217E+05 -39.124 9 SO2,gas 1.14 -23.47 -24.60 -6.560 0.42007E+05 -22.602 10 HCl,gas 5.48 -13.38 -18.86 -9.430 0.32204E+05 -16.861 11 acmite 7.74 6.71 -1.03 -0.107 0.17519E+04 15 albite-high 0.75 -0.48 -1.23 -0.095 0.21035E+04 16 albite -0.33 -0.48 -0.15 -0.012 0.26288E+03 19 spessartine 24.55 20.53 -4.02 -0.201 0.68698E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.93675E+03 21 andalusite 5.06 1.51 -3.55 -0.355 0.60577E+04 22 andradite 39.09 35.40 -3.69 -0.192 0.62944E+04 26 annite 20.21 16.81 -3.40 -0.189 0.58024E+04 27 phlogopite 27.15 23.50 -3.65 -0.203 0.62346E+04 29 anorthite 12.80 9.12 -3.68 -0.283 0.62866E+04 35 aragonite 0.99 -3.63 -4.62 -1.539 0.78836E+04 36 brucite 12.58 8.64 -3.93 -0.787 0.67176E+04 37 calcite 0.83 -3.63 -4.46 -1.488 0.76223E+04 38 carnegieite-low 9.06 6.13 -2.94 -0.420 0.50169E+04 39 carnegieite-high 10.13 6.13 -4.01 -0.573 0.68437E+04 40 carpholite-Mg 8.65 6.85 -1.80 -0.120 0.30696E+04 41 carpholite-Fe 6.78 4.62 -2.16 -0.144 0.36853E+04 42 celadonite 5.40 2.91 -2.49 -0.147 0.42589E+04 43 celadonite-Fe 3.94 0.68 -3.26 -0.192 0.55643E+04 44 chrysotile 23.94 19.32 -4.62 -0.385 0.78868E+04 50 chloritoid-Mg 13.26 10.16 -3.10 -0.207 0.53005E+04 51 chloritoid-Fe 9.24 7.93 -1.31 -0.087 0.22364E+04 52 chloritoid-Mn 11.46 10.05 -1.41 -0.094 0.24048E+04 54 coesite -2.37 -3.30 -0.93 -0.312 0.15965E+04 59 corundum 8.43 4.82 -3.61 -0.329 0.61716E+04 61 cristobalite -2.55 -3.30 -0.76 -0.252 0.12894E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.41 -0.49 -0.081 0.83088E+03 67 diopside 16.22 12.94 -3.28 -0.328 0.55940E+04 68 hedenbergite 14.24 10.71 -3.53 -0.353 0.60329E+04 75 epidote 24.78 23.02 -1.76 -0.085 0.30040E+04 76 clinozoisite 22.92 19.13 -3.79 -0.172 0.64791E+04 77 epidote-Fe 29.94 26.91 -3.03 -0.157 0.51763E+04 78 fayalite 14.08 9.52 -4.55 -0.651 0.77770E+04 79 ferrosilite 11.19 6.22 -4.97 -0.497 0.84823E+04 83 gibbsite 4.10 2.41 -1.69 -0.241 0.28821E+04 84 glaucophane 23.11 18.35 -4.76 -0.129 0.81221E+04 87 greenalite 16.19 12.63 -3.56 -0.297 0.60786E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24398E+04 97 kalsilite 7.62 4.18 -3.44 -0.492 0.58795E+04 98 kaolinite -1.27 -1.79 -0.52 -0.047 0.88207E+03 99 kyanite 4.93 1.51 -3.42 -0.342 0.58345E+04 101 laumontite 2.97 2.51 -0.47 -0.031 0.79803E+03 102 lawsonite 9.68 9.12 -0.56 -0.038 0.96049E+03 103 leucite 4.17 0.87 -3.30 -0.330 0.56263E+04 105 lizardite 23.29 19.32 -3.97 -0.331 0.67770E+04 107 magnetite 20.13 19.01 -1.12 -0.091 0.19138E+04 108 minnesotaite 10.46 6.03 -4.44 -0.261 0.75730E+04 113 margarite 17.45 13.93 -3.52 -0.141 0.60052E+04 120 muscovite 2.68 2.39 -0.29 -0.017 0.49865E+03 122 nepheline 8.38 6.13 -2.25 -0.322 0.38448E+04 134 phlogopite-Na 29.73 25.44 -4.29 -0.238 0.73193E+04 136 prehnite 19.47 16.72 -2.75 -0.162 0.46942E+04 137 prehnite-Fe 22.59 20.61 -1.98 -0.119 0.33814E+04 138 pumpellyite-Fe 46.47 42.26 -4.21 -0.094 0.71929E+04 139 pumpellyite-Mg 49.19 44.49 -4.71 -0.105 0.80388E+04 145 pyroxmangite 7.42 5.24 -2.18 -0.436 0.37226E+04 146 pyrophyllite -6.10 -8.40 -2.30 -0.144 0.39279E+04 147 quartz -2.98 -3.30 -0.32 -0.107 0.55039E+03 152 rhodonite 7.46 5.24 -2.23 -0.445 0.38018E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.51 -3.81 -0.381 0.64999E+04 164 stilpnomelane-Fe 13.18 12.99 -0.19 -0.006 0.32058E+03 165 stilpnomelane-Mg 27.60 24.13 -3.46 -0.103 0.59154E+04 168 sudoite 21.22 17.01 -4.21 -0.136 0.71827E+04 171 talc 16.55 12.71 -3.84 -0.226 0.65630E+04 174 tephroite 18.11 13.78 -4.34 -0.620 0.74050E+04 177 topaz-H 4.67 1.51 -3.15 -0.287 0.53836E+04 178 tridymite -2.61 -3.30 -0.69 -0.230 0.11777E+04 187 wairakite 4.06 2.51 -1.55 -0.091 0.26488E+04 188 walstromite 11.53 7.60 -3.93 -0.785 0.67046E+04 189 wollastonite 10.48 7.60 -2.88 -0.576 0.49185E+04 190 pseudo-wollastonite 11.02 7.60 -3.42 -0.684 0.58371E+04 191 zoisite 22.96 19.13 -3.84 -0.174 0.65517E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.71 -3.15 -0.195 0.53850E+04 194 beidellite-H -2.24 -6.51 -4.27 -0.273 0.72939E+04 195 beidellite-K -1.44 -4.84 -3.40 -0.208 0.58125E+04 196 beidellite-Mg -1.71 -5.09 -3.38 -0.209 0.57712E+04 197 beidellite-Na -1.26 -4.20 -2.94 -0.180 0.50180E+04 199 chalcedony -2.79 -3.30 -0.51 -0.170 0.87071E+03 201 montmorillonite-Ca -2.21 -4.54 -2.33 -0.144 0.39752E+04 202 montmorillonite-K -2.16 -4.67 -2.51 -0.154 0.42805E+04 203 montmorillonite-Mg -2.40 -4.92 -2.51 -0.156 0.42925E+04 204 montmorillonite-Na -1.96 -4.02 -2.06 -0.126 0.35241E+04 205 nontronite-Ca 3.28 3.07 -0.21 -0.014 0.36612E+03 206 nontronite-H 2.60 1.27 -1.33 -0.089 0.22708E+04 207 nontronite-K 3.40 2.94 -0.46 -0.030 0.79283E+03 208 nontronite-Mg 3.14 2.69 -0.45 -0.029 0.76401E+03 224 tobermorite 9.84 5.78 -4.06 -1.108 0.69306E+04 233 boehmite 4.43 2.41 -2.02 -0.337 0.34493E+04 235 ferrous-oxide 9.82 6.41 -3.41 -0.852 0.58223E+04 240 silica-amorphous -2.08 -3.30 -1.22 -0.408 0.20909E+04 242 an20ab80 2.08 1.44 -0.64 -0.049 0.10960E+04 243 an25ab75 2.71 1.92 -0.79 -0.061 0.13522E+04 244 an30ab70 3.34 2.40 -0.95 -0.073 0.16167E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 3.1990000 g New total amount of reactant added: 3.2990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4565E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3.2990000 Water: Moles liquid = 0.5548E+02 kg liquid = 0.9994E+00 Moles total = 0.5547E+02 kg total = 0.9993E+00 Activity = 1.0000 Stoichiometric ionic strength = .2407284E-02 Osmotic coef. = 0.9727 True ionic strength = .4024386E-02 Chg. balance for total moles = 0.4565E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.35379E-09 -9.4513 0.32132E-09 -9.4931 0.90821E+00 -0.0418 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13791E-03 -3.8604 0.12506E-03 -3.9029 0.90681E+00 -0.0425 4 SO4-- 0.25508E-04 -4.5933 0.18258E-04 -4.7386 0.71578E+00 -0.1452 5 HCO3- 0.95773E-05 -5.0188 0.86880E-05 -5.0611 0.90715E+00 -0.0423 6 HS- 0.58139E-13 -13.2355 0.52723E-13 -13.2780 0.90685E+00 -0.0425 7 Al+++ 0.17459E-25 -25.7580 0.83851E-26 -26.0765 0.48028E+00 -0.3185 8 H4SiO4 0.49430E-03 -3.3060 0.49430E-03 -3.3060 0.10000E+01 0.0000 9 Ca++ 0.12321E-07 -7.9093 0.88030E-08 -8.0554 0.71446E+00 -0.1460 10 Mg++ 0.64040E-10 -10.1935 0.45700E-10 -10.3401 0.71362E+00 -0.1465 11 Fe++ 0.37869E-12 -12.4217 0.27032E-12 -12.5681 0.71382E+00 -0.1464 12 K+ 0.42928E-04 -4.3673 0.38945E-04 -4.4096 0.90721E+00 -0.0423 13 Na+ 0.39441E-02 -2.4041 0.35764E-02 -2.4466 0.90678E+00 -0.0425 14 Mn++ 0.50593E-10 -10.2959 0.36122E-10 -10.4422 0.71397E+00 -0.1463 15 HPO4-- 0.82630E-05 -5.0829 0.59147E-05 -5.2281 0.71580E+00 -0.1452 16 HSiO3- 0.16552E-02 -2.7812 0.15009E-02 -2.8236 0.90681E+00 -0.0425 17 Ca(HSiO3)+ 0.32630E-09 -9.4864 0.29604E-09 -9.5287 0.90726E+00 -0.0423 18 Mg(HSiO3)+ 0.21082E-11 -11.6761 0.19126E-11 -11.7184 0.90726E+00 -0.0423 19 NaHSiO3,aq 0.85256E-04 -4.0693 0.85256E-04 -4.0693 0.10000E+01 0.0000 20 AlO+ 0.11557E-13 -13.9372 0.10485E-13 -13.9794 0.90726E+00 -0.0423 21 AlOH+2 0.23631E-19 -19.6265 0.16876E-19 -19.7727 0.71415E+00 -0.1462 22 HAlO2,aq 0.65297E-08 -8.1851 0.65297E-08 -8.1851 0.10000E+01 0.0000 23 AlO2- 0.50062E-04 -4.3005 0.45376E-04 -4.3432 0.90639E+00 -0.0427 24 CH4,aq 0.24637E-19 -19.6084 0.24618E-19 -19.6087 0.99926E+00 -0.0003 29 CO,aq 0.94520E-19 -19.0245 0.94520E-19 -19.0245 0.10000E+01 0.0000 30 CO2,aq 0.56326E-08 -8.2493 0.56284E-08 -8.2496 0.99926E+00 -0.0003 31 CO3-2 0.34946E-05 -5.4566 0.25000E-05 -5.6021 0.71539E+00 -0.1455 32 CaCO3,aq 0.26954E-09 -9.5694 0.26954E-09 -9.5694 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.21241E-11 -11.6728 0.19271E-11 -11.7151 0.90726E+00 -0.0423 34 CaCl+ 0.19336E-11 -11.7136 0.17543E-11 -11.7559 0.90726E+00 -0.0423 35 CaCl2,aq 0.51081E-16 -16.2917 0.51081E-16 -16.2917 0.10000E+01 0.0000 36 CaOH+ 0.21293E-08 -8.6718 0.19318E-08 -8.7140 0.90726E+00 -0.0423 37 CaSO4,aq 0.50078E-10 -10.3004 0.50078E-10 -10.3004 0.10000E+01 0.0000 38 HCl,aq 0.75584E-14 -14.1216 0.75584E-14 -14.1216 0.10000E+01 0.0000 43 FeCl+ 0.58035E-16 -16.2363 0.52652E-16 -16.2786 0.90726E+00 -0.0423 46 FeO,aq 0.10353E-09 -9.9849 0.10353E-09 -9.9849 0.10000E+01 0.0000 47 FeOH+ 0.30741E-10 -10.5123 0.27890E-10 -10.5545 0.90726E+00 -0.0423 48 HFeO2- 0.38220E-08 -8.4177 0.34658E-08 -8.4602 0.90681E+00 -0.0425 49 FeO+ 0.29297E-14 -14.5332 0.26580E-14 -14.5754 0.90726E+00 -0.0423 51 FeO2- 0.55798E-08 -8.2534 0.50599E-08 -8.2959 0.90681E+00 -0.0425 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.65252E-09 -9.1854 0.65203E-09 -9.1857 0.99926E+00 -0.0003 54 KCl,aq 0.86237E-10 -10.0643 0.86237E-10 -10.0643 0.10000E+01 0.0000 55 KHSO4,aq 0.61138E-18 -18.2137 0.61138E-18 -18.2137 0.10000E+01 0.0000 56 KOH,aq 0.52838E-07 -7.2771 0.52838E-07 -7.2771 0.10000E+01 0.0000 57 KSO4- 0.12080E-07 -7.9179 0.10955E-07 -7.9604 0.90681E+00 -0.0425 58 MgCO3,aq 0.34966E-12 -12.4564 0.34966E-12 -12.4564 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11245E-13 -13.9491 0.10202E-13 -13.9913 0.90726E+00 -0.0423 60 MgCl+ 0.91129E-14 -14.0403 0.82677E-14 -14.0826 0.90726E+00 -0.0423 61 MgOH+ 0.61241E-10 -10.2130 0.55561E-10 -10.2552 0.90726E+00 -0.0423 63 MnO,aq 0.36933E-09 -9.4326 0.36933E-09 -9.4326 0.10000E+01 0.0000 64 MnOH+ 0.38161E-09 -9.4184 0.34622E-09 -9.4606 0.90726E+00 -0.0423 65 MnO2-2 0.17293E-12 -12.7621 0.12371E-12 -12.9076 0.71539E+00 -0.1455 66 HMnO2- 0.94977E-11 -11.0224 0.86126E-11 -11.0649 0.90681E+00 -0.0425 69 MnCl+ 0.30135E-13 -13.5209 0.27340E-13 -13.5632 0.90726E+00 -0.0423 70 MnSO4,aq 0.18690E-12 -12.7284 0.18690E-12 -12.7284 0.10000E+01 0.0000 71 NaCl,aq 0.14604E-06 -6.8355 0.14604E-06 -6.8355 0.10000E+01 0.0000 72 NaOH,aq 0.48908E-05 -5.3106 0.48908E-05 -5.3106 0.10000E+01 0.0000 74 OH- 0.20596E-02 -2.6862 0.18668E-02 -2.7289 0.90639E+00 -0.0427 79 HPO3-2 0.17027E-16 -16.7689 0.12181E-16 -16.9143 0.71539E+00 -0.1455 82 H3PO4,aq 0.39314E-14 -14.4055 0.39314E-14 -14.4055 0.10000E+01 0.0000 83 H2PO4- 0.36735E-07 -7.4349 0.33320E-07 -7.4773 0.90703E+00 -0.0424 84 PO4-3 0.33055E-07 -7.4808 0.16076E-07 -7.7938 0.48634E+00 -0.3131 87 H2P2O7-2 0.12146E-15 -15.9156 0.86890E-16 -16.0610 0.71539E+00 -0.1455 88 HP2O7-3 0.11544E-12 -12.9377 0.55450E-13 -13.2561 0.48036E+00 -0.3184 89 P2O7-4 0.15357E-12 -12.8137 0.42573E-13 -13.3709 0.27722E+00 -0.5572 90 H2S,aq 0.50938E-16 -16.2930 0.50900E-16 -16.2933 0.99926E+00 -0.0003 97 SO3-2 0.22606E-14 -14.6458 0.16232E-14 -14.7896 0.71804E+00 -0.1439 98 HSO3- 0.33659E-16 -16.4729 0.30523E-16 -16.5154 0.90681E+00 -0.0425 99 HSO4- 0.59983E-11 -11.2220 0.54433E-11 -11.2641 0.90747E+00 -0.0422 Charge balance for all species = 0.5464E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3537906E-09 -.4008756E-02 -.4039289E+01 0.0000 2 H2O 0.1000000E+01 0.5550867E+02 0.9996846E+06 0.0000 3 Cl- 0.1379106E-03 0.1380567E-03 0.4892954E+01 5.5902 4 SO4-- 0.2550759E-04 0.2552028E-04 0.2450733E+01 14.2476 5 HCO3- 0.9577310E-05 0.1307782E-04 0.7977158E+00 4.4320 6 HS- 0.5813923E-13 -.5597228E-09 -.1850521E-04 -3.7849 7 Al+++ 0.1745897E-25 0.5006862E-04 0.1350493E+01 2.4027 8 H4SiO4 0.4943030E-03 0.2234735E-02 0.2147235E+03 -3.3060 9 Ca++ 0.1232129E-07 0.1510056E-07 0.6050063E-03 10.9308 10 Mg++ 0.6403988E-10 0.1277587E-09 0.3105072E-05 8.6461 11 Fe++ 0.3786865E-12 0.9739918E-08 0.5437707E-03 6.4180 12 K+ 0.4292792E-04 0.4299292E-04 0.1680570E+01 5.0835 13 Na+ 0.3944053E-02 0.4034346E-02 0.9271905E+02 7.0465 14 Mn++ 0.5059256E-10 0.8114244E-09 0.4456373E-04 8.5439 15 HPO4-- 0.8263045E-05 0.8332835E-05 0.7995206E+00 13.7581 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5461350E-01 -.4006359E-02 -.5060714E-01 0.0000000E+00 2 H2O 0.5546690E+02 0.5547549E+02 -.8596704E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1169310E-03 0.2550503E-04 0.9142598E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9142654E-04 -.5593882E-09 -.9142598E-04 0.0000000E+00 7 Al+++ 0.1075719E-01 0.5003869E-04 0.1070715E-01 0.0000000E+00 8 H4SiO4 0.3435177E-01 0.2233399E-02 0.3211837E-01 0.0000000E+00 9 Ca++ 0.3808792E-02 0.1509154E-07 0.3808777E-02 0.0000000E+00 10 Mg++ 0.2618254E-02 0.1276823E-09 0.2618254E-02 0.0000000E+00 11 Fe++ 0.2352215E-02 0.9734096E-08 0.2352206E-02 0.0000000E+00 12 K+ 0.7004246E-03 0.4296722E-04 0.6574574E-03 0.0000000E+00 13 Na+ 0.4301120E-02 0.4031934E-02 0.2691857E-03 0.0000000E+00 14 Mn++ 0.5720003E-04 0.8109393E-09 0.5719922E-04 0.0000000E+00 15 HPO4-- 0.1952209E-04 0.8327854E-05 0.1119423E-04 0.0000000E+00 Chg. balance for solid moles: 0.4577E-17 Mass of aqueous solution: 0.999723E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3.2990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.3731E-05 -5.428 0.1874E-02 -2.727 0.5266E-01 0.5956E-03 clinochlore 0.5237E-03 -3.281 0.2911 -0.536 8.177 0.1107 daphnite 0.3242E-03 -3.489 0.2313 -0.636 6.498 0.7009E-01 chlorite-Mn 0.1144E-04 -4.942 0.8111E-02 -2.091 0.2279 0.2585E-02 hematite 0.2799E-03 -3.553 0.4471E-01 -1.350 1.256 0.8473E-02 microcline 0.6575E-03 -3.182 0.1830 -0.738 5.141 0.7148E-01 paragonite 0.2409E-03 -3.618 0.9207E-01 -1.036 2.586 0.3182E-01 stilbite 0.3790E-02 -2.421 2.671 0.427 75.04 1.246 nontronite-Na 0.8577E-04 -4.067 0.3647E-01 -1.438 1.025 0.1133E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.559551 g Volume = 1.552880 cm3 Porosity: 33.0540% V(tot) - V(min): 0.76672E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.2990000 g log = 0.5184 Original solution: 1000.0103000 g Original solution / Rock added: 303.13 (Water/Rock Ratio), log = 2.4816 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.6080E-06 1.0073 0.6443E-06 0.6396E-06 CH4,gas 0.3654E-16 1.0129 0.3893E-16 0.3843E-16 H2,gas 0.8497E-06 1.0006 0.8943E-06 0.8938E-06 H2S,gas 0.1417E-14 0.9959 0.1485E-14 0.1491E-14 S2,gas 0.9811E-37 1.0000 0.1032E-36 0.1032E-36 CO,gas 0.1419E-15 1.0000 0.1492E-15 0.1492E-15 SO3,gas 0.6699E-39 1.0000 0.7047E-39 0.7047E-39 SO2,gas 0.2266E-22 1.0000 0.2384E-22 0.2384E-22 HCl,gas 0.1269E-16 1.0000 0.1335E-16 0.1335E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.25023E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.55 -8.19 -2.730 0.13986E+05 -6.191 3 CH4,gas 4.81 -13.60 -18.41 -4.602 0.31434E+05 -16.410 4 H2,gas 8.29 0.24 -8.05 -4.599 0.13743E+05 -6.049 5 H2S,gas -5.94 -22.77 -16.83 -8.414 0.28734E+05 -14.828 6 S2,gas -7.03 -46.02 -38.99 -5.998 0.66568E+05 -36.986 7 CO,gas 3.51 -14.32 -17.83 -5.485 0.30438E+05 -15.826 8 SO3,gas 17.43 -23.72 -41.15 -10.288 0.70266E+05 -39.152 9 SO2,gas 1.14 -23.49 -24.62 -6.566 0.42043E+05 -22.623 10 HCl,gas 5.48 -13.40 -18.87 -9.437 0.32228E+05 -16.875 11 acmite 7.74 6.73 -1.00 -0.104 0.17144E+04 15 albite-high 0.75 -0.47 -1.22 -0.094 0.20804E+04 16 albite -0.33 -0.47 -0.14 -0.011 0.23979E+03 19 spessartine 24.55 20.52 -4.03 -0.202 0.68825E+04 20 analcite 3.37 2.84 -0.53 -0.059 0.91081E+03 21 andalusite 5.06 1.50 -3.56 -0.356 0.60836E+04 22 andradite 39.09 35.47 -3.62 -0.188 0.61740E+04 26 annite 20.21 16.82 -3.39 -0.188 0.57834E+04 27 phlogopite 27.15 23.51 -3.64 -0.202 0.62156E+04 29 anorthite 12.80 9.12 -3.67 -0.283 0.62724E+04 35 aragonite 0.99 -3.62 -4.61 -1.537 0.78708E+04 36 brucite 12.58 8.65 -3.93 -0.786 0.67113E+04 37 calcite 0.83 -3.62 -4.46 -1.486 0.76094E+04 38 carnegieite-low 9.06 6.14 -2.92 -0.417 0.49881E+04 39 carnegieite-high 10.13 6.14 -3.99 -0.570 0.68150E+04 40 carpholite-Mg 8.65 6.84 -1.81 -0.121 0.30921E+04 41 carpholite-Fe 6.78 4.61 -2.17 -0.145 0.37077E+04 42 celadonite 5.40 2.91 -2.49 -0.147 0.42555E+04 43 celadonite-Fe 3.94 0.68 -3.26 -0.192 0.55608E+04 44 chrysotile 23.94 19.33 -4.61 -0.384 0.78735E+04 50 chloritoid-Mg 13.26 10.15 -3.12 -0.208 0.53201E+04 51 chloritoid-Fe 9.24 7.92 -1.32 -0.088 0.22560E+04 52 chloritoid-Mn 11.46 10.04 -1.42 -0.095 0.24244E+04 54 coesite -2.37 -3.31 -0.94 -0.312 0.15993E+04 59 corundum 8.43 4.81 -3.63 -0.330 0.61947E+04 61 cristobalite -2.55 -3.31 -0.76 -0.252 0.12922E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.40 -0.49 -0.082 0.84243E+03 67 diopside 16.22 12.96 -3.25 -0.325 0.55504E+04 68 hedenbergite 14.24 10.74 -3.51 -0.351 0.59892E+04 75 epidote 24.78 23.05 -1.73 -0.084 0.29496E+04 76 clinozoisite 22.92 19.15 -3.77 -0.171 0.64363E+04 77 epidote-Fe 29.94 26.94 -2.99 -0.155 0.51103E+04 78 fayalite 14.08 9.53 -4.55 -0.650 0.77672E+04 79 ferrosilite 11.19 6.22 -4.96 -0.496 0.84754E+04 83 gibbsite 4.10 2.40 -1.69 -0.242 0.28936E+04 84 glaucophane 23.11 18.39 -4.72 -0.128 0.80626E+04 87 greenalite 16.19 12.64 -3.55 -0.296 0.60653E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.84 -1.41 -0.141 0.24138E+04 97 kalsilite 7.62 4.18 -3.44 -0.491 0.58738E+04 98 kaolinite -1.27 -1.81 -0.53 -0.048 0.91085E+03 99 kyanite 4.93 1.50 -3.43 -0.343 0.58604E+04 101 laumontite 2.97 2.51 -0.46 -0.031 0.78950E+03 102 lawsonite 9.68 9.12 -0.55 -0.037 0.94628E+03 103 leucite 4.17 0.87 -3.29 -0.329 0.56234E+04 105 lizardite 23.29 19.33 -3.96 -0.330 0.67638E+04 107 magnetite 20.13 19.02 -1.12 -0.091 0.19075E+04 108 minnesotaite 10.46 6.03 -4.43 -0.261 0.75654E+04 113 margarite 17.45 13.93 -3.52 -0.141 0.60141E+04 120 muscovite 2.68 2.37 -0.31 -0.018 0.52174E+03 122 nepheline 8.38 6.14 -2.23 -0.319 0.38160E+04 134 phlogopite-Na 29.73 25.47 -4.26 -0.237 0.72773E+04 136 prehnite 19.47 16.75 -2.72 -0.160 0.46399E+04 137 prehnite-Fe 22.59 20.65 -1.94 -0.117 0.33155E+04 138 pumpellyite-Fe 46.47 42.32 -4.15 -0.092 0.70894E+04 139 pumpellyite-Mg 49.19 44.55 -4.65 -0.103 0.79353E+04 145 pyroxmangite 7.42 5.24 -2.18 -0.436 0.37191E+04 146 pyrophyllite -6.10 -8.42 -2.32 -0.145 0.39623E+04 147 quartz -2.98 -3.31 -0.32 -0.108 0.55324E+03 152 rhodonite 7.46 5.24 -2.22 -0.445 0.37983E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.50 -3.82 -0.382 0.65258E+04 164 stilpnomelane-Fe 13.18 12.99 -0.19 -0.006 0.32476E+03 165 stilpnomelane-Mg 27.60 24.13 -3.47 -0.103 0.59196E+04 168 sudoite 21.22 16.98 -4.23 -0.136 0.72247E+04 171 talc 16.55 12.71 -3.84 -0.226 0.65554E+04 174 tephroite 18.11 13.78 -4.33 -0.619 0.73952E+04 177 topaz-H 4.67 1.50 -3.17 -0.288 0.54095E+04 178 tridymite -2.61 -3.31 -0.69 -0.230 0.11805E+04 187 wairakite 4.06 2.51 -1.55 -0.091 0.26403E+04 188 walstromite 11.53 7.62 -3.90 -0.781 0.66645E+04 189 wollastonite 10.48 7.62 -2.86 -0.571 0.48783E+04 190 pseudo-wollastonite 11.02 7.62 -3.40 -0.679 0.57970E+04 191 zoisite 22.96 19.15 -3.81 -0.173 0.65089E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.73 -3.17 -0.196 0.54152E+04 194 beidellite-H -2.24 -6.53 -4.29 -0.274 0.73312E+04 195 beidellite-K -1.44 -4.86 -3.42 -0.210 0.58432E+04 196 beidellite-Mg -1.71 -5.11 -3.40 -0.210 0.58075E+04 197 beidellite-Na -1.26 -4.21 -2.95 -0.181 0.50411E+04 199 chalcedony -2.79 -3.31 -0.51 -0.171 0.87355E+03 201 montmorillonite-Ca -2.21 -4.55 -2.34 -0.145 0.39967E+04 202 montmorillonite-K -2.16 -4.68 -2.52 -0.154 0.43024E+04 203 montmorillonite-Mg -2.40 -4.93 -2.53 -0.157 0.43200E+04 204 montmorillonite-Na -1.96 -4.03 -2.07 -0.127 0.35384E+04 205 nontronite-Ca 3.28 3.06 -0.22 -0.014 0.37327E+03 206 nontronite-H 2.60 1.26 -1.34 -0.090 0.22851E+04 207 nontronite-K 3.40 2.94 -0.47 -0.030 0.80044E+03 208 nontronite-Mg 3.14 2.68 -0.46 -0.030 0.77721E+03 224 tobermorite 9.84 5.80 -4.04 -1.102 0.68976E+04 233 boehmite 4.43 2.40 -2.03 -0.338 0.34609E+04 235 ferrous-oxide 9.82 6.42 -3.41 -0.852 0.58160E+04 240 silica-amorphous -2.08 -3.31 -1.23 -0.409 0.20937E+04 242 an20ab80 2.08 1.45 -0.63 -0.048 0.10747E+04 243 an25ab75 2.71 1.93 -0.78 -0.060 0.13313E+04 244 an30ab70 3.34 2.41 -0.93 -0.072 0.15963E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 3.2990000 g New total amount of reactant added: 3.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4564E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3.3990000 Water: Moles liquid = 0.5547E+02 kg liquid = 0.9994E+00 Moles total = 0.5547E+02 kg total = 0.9992E+00 Activity = 1.0000 Stoichiometric ionic strength = .2468020E-02 Osmotic coef. = 0.9724 True ionic strength = .4134628E-02 Chg. balance for total moles = 0.4564E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.34372E-09 -9.4638 0.31187E-09 -9.5060 0.90734E+00 -0.0422 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13791E-03 -3.8604 0.12493E-03 -3.9033 0.90591E+00 -0.0429 4 SO4-- 0.25508E-04 -4.5933 0.18187E-04 -4.7402 0.71298E+00 -0.1469 5 HCO3- 0.94931E-05 -5.0226 0.86031E-05 -5.0653 0.90625E+00 -0.0428 6 HS- 0.60117E-13 -13.2210 0.54463E-13 -13.2639 0.90594E+00 -0.0429 7 Al+++ 0.15865E-25 -25.7996 0.75522E-26 -26.1219 0.47603E+00 -0.3224 8 H4SiO4 0.49247E-03 -3.3076 0.49247E-03 -3.3076 0.10000E+01 0.0000 9 Ca++ 0.12328E-07 -7.9091 0.87729E-08 -8.0569 0.71163E+00 -0.1477 10 Mg++ 0.61074E-10 -10.2141 0.43411E-10 -10.3624 0.71079E+00 -0.1483 11 Fe++ 0.36115E-12 -12.4423 0.25677E-12 -12.5905 0.71099E+00 -0.1481 12 K+ 0.42817E-04 -4.3684 0.38806E-04 -4.4111 0.90631E+00 -0.0427 13 Na+ 0.40546E-02 -2.3921 0.36729E-02 -2.4350 0.90588E+00 -0.0429 14 Mn++ 0.48249E-10 -10.3165 0.34312E-10 -10.4646 0.71114E+00 -0.1480 15 HPO4-- 0.80175E-05 -5.0960 0.57166E-05 -5.2429 0.71301E+00 -0.1469 16 HSiO3- 0.17007E-02 -2.7694 0.15407E-02 -2.8123 0.90591E+00 -0.0429 17 Ca(HSiO3)+ 0.33411E-09 -9.4761 0.30283E-09 -9.5188 0.90636E+00 -0.0427 18 Mg(HSiO3)+ 0.20575E-11 -11.6867 0.18649E-11 -11.7293 0.90636E+00 -0.0427 19 NaHSiO3,aq 0.89874E-04 -4.0464 0.89874E-04 -4.0464 0.10000E+01 0.0000 20 AlO+ 0.11060E-13 -13.9563 0.10024E-13 -13.9990 0.90636E+00 -0.0427 21 AlOH+2 0.22016E-19 -19.6573 0.15660E-19 -19.8052 0.71132E+00 -0.1479 22 HAlO2,aq 0.64318E-08 -8.1917 0.64318E-08 -8.1917 0.10000E+01 0.0000 23 AlO2- 0.50856E-04 -4.2937 0.46049E-04 -4.3368 0.90548E+00 -0.0431 24 CH4,aq 0.25300E-19 -19.5969 0.25280E-19 -19.5972 0.99924E+00 -0.0003 29 CO,aq 0.92361E-19 -19.0345 0.92361E-19 -19.0345 0.10000E+01 0.0000 30 CO2,aq 0.54137E-08 -8.2665 0.54096E-08 -8.2668 0.99924E+00 -0.0003 31 CO3-2 0.35793E-05 -5.4462 0.25505E-05 -5.5934 0.71259E+00 -0.1472 32 CaCO3,aq 0.27405E-09 -9.5622 0.27405E-09 -9.5622 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.20982E-11 -11.6782 0.19017E-11 -11.7209 0.90636E+00 -0.0427 34 CaCl+ 0.19269E-11 -11.7151 0.17465E-11 -11.7578 0.90636E+00 -0.0427 35 CaCl2,aq 0.50804E-16 -16.2941 0.50804E-16 -16.2941 0.10000E+01 0.0000 36 CaOH+ 0.21884E-08 -8.6599 0.19835E-08 -8.7026 0.90636E+00 -0.0427 37 CaSO4,aq 0.49713E-10 -10.3035 0.49713E-10 -10.3035 0.10000E+01 0.0000 38 HCl,aq 0.73288E-14 -14.1350 0.73288E-14 -14.1350 0.10000E+01 0.0000 43 FeCl+ 0.55126E-16 -16.2586 0.49964E-16 -16.3013 0.90636E+00 -0.0427 46 FeO,aq 0.10440E-09 -9.9813 0.10440E-09 -9.9813 0.10000E+01 0.0000 47 FeOH+ 0.30115E-10 -10.5212 0.27295E-10 -10.5639 0.90636E+00 -0.0427 48 HFeO2- 0.39744E-08 -8.4007 0.36005E-08 -8.4436 0.90591E+00 -0.0429 49 FeO+ 0.28464E-14 -14.5457 0.25798E-14 -14.5884 0.90636E+00 -0.0427 51 FeO2- 0.57546E-08 -8.2400 0.52131E-08 -8.2829 0.90591E+00 -0.0429 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.66342E-09 -9.1782 0.66291E-09 -9.1785 0.99924E+00 -0.0003 54 KCl,aq 0.85843E-10 -10.0663 0.85843E-10 -10.0663 0.10000E+01 0.0000 55 KHSO4,aq 0.58899E-18 -18.2299 0.58899E-18 -18.2299 0.10000E+01 0.0000 56 KOH,aq 0.54244E-07 -7.2656 0.54244E-07 -7.2656 0.10000E+01 0.0000 57 KSO4- 0.12002E-07 -7.9207 0.10873E-07 -7.9636 0.90591E+00 -0.0429 58 MgCO3,aq 0.33885E-12 -12.4700 0.33885E-12 -12.4700 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10587E-13 -13.9752 0.95960E-14 -14.0179 0.90636E+00 -0.0427 60 MgCl+ 0.86561E-14 -14.0627 0.78456E-14 -14.1054 0.90636E+00 -0.0427 61 MgOH+ 0.59993E-10 -10.2219 0.54376E-10 -10.2646 0.90636E+00 -0.0427 63 MnO,aq 0.37240E-09 -9.4290 0.37240E-09 -9.4290 0.10000E+01 0.0000 64 MnOH+ 0.37384E-09 -9.4273 0.33883E-09 -9.4700 0.90636E+00 -0.0427 65 MnO2-2 0.18582E-12 -12.7309 0.13241E-12 -12.8781 0.71259E+00 -0.1472 66 HMnO2- 0.98765E-11 -11.0054 0.89472E-11 -11.0483 0.90591E+00 -0.0429 69 MnCl+ 0.28624E-13 -13.5433 0.25944E-13 -13.5860 0.90636E+00 -0.0427 70 MnSO4,aq 0.17685E-12 -12.7524 0.17685E-12 -12.7524 0.10000E+01 0.0000 71 NaCl,aq 0.14983E-06 -6.8244 0.14983E-06 -6.8244 0.10000E+01 0.0000 72 NaOH,aq 0.51749E-05 -5.2861 0.51749E-05 -5.2861 0.10000E+01 0.0000 74 OH- 0.21241E-02 -2.6728 0.19233E-02 -2.7159 0.90548E+00 -0.0431 79 HPO3-2 0.16797E-16 -16.7748 0.11970E-16 -16.9219 0.71259E+00 -0.1472 82 H3PO4,aq 0.35796E-14 -14.4462 0.35796E-14 -14.4462 0.10000E+01 0.0000 83 H2PO4- 0.34495E-07 -7.4622 0.31257E-07 -7.5051 0.90613E+00 -0.0428 84 PO4-3 0.33198E-07 -7.4789 0.16008E-07 -7.7957 0.48219E+00 -0.3168 87 H2P2O7-2 0.10730E-15 -15.9694 0.76464E-16 -16.1165 0.71259E+00 -0.1472 88 HP2O7-3 0.10559E-12 -12.9764 0.50274E-13 -13.2987 0.47611E+00 -0.3223 89 P2O7-4 0.14571E-12 -12.8365 0.39768E-13 -13.4005 0.27292E+00 -0.5640 90 H2S,aq 0.51073E-16 -16.2918 0.51034E-16 -16.2921 0.99924E+00 -0.0003 97 SO3-2 0.22982E-14 -14.6386 0.16439E-14 -14.7841 0.71529E+00 -0.1455 98 HSO3- 0.33119E-16 -16.4799 0.30003E-16 -16.5228 0.90591E+00 -0.0429 99 HSO4- 0.58051E-11 -11.2362 0.52628E-11 -11.2788 0.90659E+00 -0.0426 Charge balance for all species = 0.5451E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3437196E-09 -.4126940E-02 -.4158343E+01 0.0000 2 H2O 0.1000000E+01 0.5550869E+02 0.9996775E+06 0.0000 3 Cl- 0.1379092E-03 0.1380591E-03 0.4893003E+01 5.6027 4 SO4-- 0.2550811E-04 0.2552075E-04 0.2450759E+01 14.2718 5 HCO3- 0.9493080E-05 0.1307805E-04 0.7977238E+00 4.4407 6 HS- 0.6011742E-13 -.5788375E-09 -.1913703E-04 -3.7579 7 Al+++ 0.1586502E-25 0.5086280E-04 0.1371904E+01 2.3961 8 H4SiO4 0.4924677E-03 0.2283012E-02 0.2193606E+03 -3.3076 9 Ca++ 0.1232782E-07 0.1517817E-07 0.6081109E-03 10.9552 10 Mg++ 0.6107418E-10 0.1234830E-09 0.3001134E-05 8.6496 11 Fe++ 0.3611469E-12 0.1006730E-07 0.5620442E-03 6.4216 12 K+ 0.4281700E-04 0.4288334E-04 0.1676274E+01 5.0949 13 Na+ 0.4054566E-02 0.4149765E-02 0.9537095E+02 7.0710 14 Mn++ 0.4824905E-10 0.8047570E-09 0.4419723E-04 8.5475 15 HPO4-- 0.8017531E-05 0.8085224E-05 0.7757570E+00 13.7692 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5626935E-01 -.4124401E-02 -.5214495E-01 0.0000000E+00 2 H2O 0.5546564E+02 0.5547454E+02 -.8896881E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1197023E-03 0.2550505E-04 0.9419730E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9419788E-04 -.5784814E-09 -.9419730E-04 0.0000000E+00 7 Al+++ 0.1108326E-01 0.5083151E-04 0.1103243E-01 0.0000000E+00 8 H4SiO4 0.3539305E-01 0.2281608E-02 0.3311144E-01 0.0000000E+00 9 Ca++ 0.3923806E-02 0.1516883E-07 0.3923791E-02 0.0000000E+00 10 Mg++ 0.2697619E-02 0.1234071E-09 0.2697619E-02 0.0000000E+00 11 Fe++ 0.2423516E-02 0.1006111E-07 0.2423506E-02 0.0000000E+00 12 K+ 0.7216561E-03 0.4285695E-04 0.6787991E-03 0.0000000E+00 13 Na+ 0.4426644E-02 0.4147212E-02 0.2794324E-03 0.0000000E+00 14 Mn++ 0.5893389E-04 0.8042618E-09 0.5893308E-04 0.0000000E+00 15 HPO4-- 0.2011384E-04 0.8080250E-05 0.1203359E-04 0.0000000E+00 Chg. balance for solid moles: -.5628E-17 Mass of aqueous solution: 0.999713E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4011E-05 -5.397 0.2015E-02 -2.696 0.5492E-01 0.6403E-03 clinochlore 0.5395E-03 -3.268 0.2999 -0.523 8.174 0.1141 daphnite 0.3340E-03 -3.476 0.2383 -0.623 6.495 0.7221E-01 chlorite-Mn 0.1179E-04 -4.929 0.8356E-02 -2.078 0.2278 0.2663E-02 hematite 0.2817E-03 -3.550 0.4499E-01 -1.347 1.226 0.8528E-02 microcline 0.6788E-03 -3.168 0.1889 -0.724 5.150 0.7380E-01 paragonite 0.2481E-03 -3.605 0.9481E-01 -1.023 2.584 0.3277E-01 stilbite 0.3904E-02 -2.409 2.751 0.439 74.99 1.283 nontronite-Na 0.9504E-04 -4.022 0.4042E-01 -1.393 1.102 0.1256E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.668758 g Volume = 1.600378 cm3 Porosity: 32.1759% V(tot) - V(min): 0.75922E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.3990000 g log = 0.5314 Original solution: 1000.0103000 g Original solution / Rock added: 294.21 (Water/Rock Ratio), log = 2.4687 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.5844E-06 1.0073 0.6192E-06 0.6147E-06 CH4,gas 0.3752E-16 1.0129 0.3998E-16 0.3947E-16 H2,gas 0.8639E-06 1.0006 0.9092E-06 0.9087E-06 H2S,gas 0.1421E-14 0.9959 0.1488E-14 0.1495E-14 S2,gas 0.9542E-37 1.0000 0.1004E-36 0.1004E-36 CO,gas 0.1386E-15 1.0000 0.1458E-15 0.1458E-15 SO3,gas 0.6287E-39 1.0000 0.6613E-39 0.6613E-39 SO2,gas 0.2162E-22 1.0000 0.2275E-22 0.2275E-22 HCl,gas 0.1230E-16 1.0000 0.1294E-16 0.1294E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 0.83410E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.57 -8.21 -2.736 0.14015E+05 -6.208 3 CH4,gas 4.81 -13.59 -18.40 -4.600 0.31414E+05 -16.398 4 H2,gas 8.29 0.25 -8.04 -4.595 0.13730E+05 -6.041 5 H2S,gas -5.94 -22.77 -16.83 -8.414 0.28732E+05 -14.827 6 S2,gas -7.03 -46.03 -39.00 -6.000 0.66589E+05 -36.998 7 CO,gas 3.51 -14.33 -17.84 -5.488 0.30455E+05 -15.836 8 SO3,gas 17.43 -23.75 -41.18 -10.295 0.70313E+05 -39.180 9 SO2,gas 1.14 -23.51 -24.64 -6.571 0.42077E+05 -22.643 10 HCl,gas 5.48 -13.41 -18.89 -9.444 0.32251E+05 -16.888 11 acmite 7.74 6.75 -0.98 -0.102 0.16781E+04 15 albite-high 0.75 -0.46 -1.21 -0.093 0.20580E+04 16 albite -0.33 -0.46 -0.13 -0.010 0.21739E+03 19 spessartine 24.55 20.51 -4.04 -0.202 0.68947E+04 20 analcite 3.37 2.85 -0.52 -0.058 0.88565E+03 21 andalusite 5.06 1.48 -3.58 -0.358 0.61088E+04 22 andradite 39.09 35.54 -3.55 -0.184 0.60571E+04 26 annite 20.21 16.83 -3.38 -0.188 0.57650E+04 27 phlogopite 27.15 23.52 -3.63 -0.202 0.61972E+04 29 anorthite 12.80 9.13 -3.67 -0.282 0.62586E+04 35 aragonite 0.99 -3.62 -4.60 -1.534 0.78585E+04 36 brucite 12.58 8.65 -3.93 -0.785 0.67052E+04 37 calcite 0.83 -3.62 -4.45 -1.483 0.75971E+04 38 carnegieite-low 9.06 6.16 -2.90 -0.415 0.49602E+04 39 carnegieite-high 10.13 6.16 -3.97 -0.568 0.67870E+04 40 carpholite-Mg 8.65 6.83 -1.82 -0.122 0.31139E+04 41 carpholite-Fe 6.78 4.60 -2.18 -0.146 0.37295E+04 42 celadonite 5.40 2.91 -2.49 -0.146 0.42521E+04 43 celadonite-Fe 3.94 0.68 -3.25 -0.191 0.55574E+04 44 chrysotile 23.94 19.33 -4.60 -0.384 0.78606E+04 50 chloritoid-Mg 13.26 10.13 -3.13 -0.208 0.53391E+04 51 chloritoid-Fe 9.24 7.91 -1.33 -0.089 0.22750E+04 52 chloritoid-Mn 11.46 10.03 -1.43 -0.095 0.24434E+04 54 coesite -2.37 -3.31 -0.94 -0.313 0.16021E+04 59 corundum 8.43 4.79 -3.64 -0.331 0.62171E+04 61 cristobalite -2.55 -3.31 -0.76 -0.253 0.12950E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.40 -0.50 -0.083 0.85363E+03 67 diopside 16.22 12.99 -3.23 -0.323 0.55081E+04 68 hedenbergite 14.24 10.76 -3.48 -0.348 0.59469E+04 75 epidote 24.78 23.08 -1.70 -0.082 0.28968E+04 76 clinozoisite 22.92 19.18 -3.75 -0.170 0.63948E+04 77 epidote-Fe 29.94 26.98 -2.96 -0.154 0.50464E+04 78 fayalite 14.08 9.54 -4.54 -0.649 0.77577E+04 79 ferrosilite 11.19 6.23 -4.96 -0.496 0.84686E+04 83 gibbsite 4.10 2.40 -1.70 -0.243 0.29048E+04 84 glaucophane 23.11 18.42 -4.69 -0.127 0.80049E+04 87 greenalite 16.19 12.65 -3.54 -0.295 0.60524E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.85 -1.40 -0.140 0.23887E+04 97 kalsilite 7.62 4.18 -3.44 -0.491 0.58683E+04 98 kaolinite -1.27 -1.82 -0.55 -0.050 0.93877E+03 99 kyanite 4.93 1.48 -3.45 -0.345 0.58856E+04 101 laumontite 2.97 2.52 -0.46 -0.031 0.78122E+03 102 lawsonite 9.68 9.13 -0.55 -0.036 0.93248E+03 103 leucite 4.17 0.88 -3.29 -0.329 0.56207E+04 105 lizardite 23.29 19.33 -3.95 -0.329 0.67509E+04 107 magnetite 20.13 19.02 -1.11 -0.091 0.19014E+04 108 minnesotaite 10.46 6.03 -4.43 -0.260 0.75580E+04 113 margarite 17.45 13.92 -3.53 -0.141 0.60227E+04 120 muscovite 2.68 2.36 -0.32 -0.019 0.54415E+03 122 nepheline 8.38 6.16 -2.22 -0.317 0.37881E+04 134 phlogopite-Na 29.73 25.49 -4.24 -0.235 0.72365E+04 136 prehnite 19.47 16.78 -2.69 -0.158 0.45871E+04 137 prehnite-Fe 22.59 20.68 -1.90 -0.115 0.32515E+04 138 pumpellyite-Fe 46.47 42.38 -4.09 -0.091 0.69889E+04 139 pumpellyite-Mg 49.19 44.61 -4.59 -0.102 0.78349E+04 145 pyroxmangite 7.42 5.24 -2.18 -0.435 0.37157E+04 146 pyrophyllite -6.10 -8.44 -2.34 -0.146 0.39958E+04 147 quartz -2.98 -3.31 -0.33 -0.109 0.55599E+03 152 rhodonite 7.46 5.24 -2.22 -0.445 0.37950E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.48 -3.84 -0.384 0.65510E+04 164 stilpnomelane-Fe 13.18 12.99 -0.19 -0.006 0.32881E+03 165 stilpnomelane-Mg 27.60 24.13 -3.47 -0.104 0.59236E+04 168 sudoite 21.22 16.96 -4.26 -0.137 0.72655E+04 171 talc 16.55 12.72 -3.83 -0.226 0.65480E+04 174 tephroite 18.11 13.79 -4.33 -0.618 0.73857E+04 177 topaz-H 4.67 1.48 -3.18 -0.289 0.54347E+04 178 tridymite -2.61 -3.31 -0.69 -0.231 0.11833E+04 187 wairakite 4.06 2.52 -1.54 -0.091 0.26320E+04 188 walstromite 11.53 7.65 -3.88 -0.776 0.66255E+04 189 wollastonite 10.48 7.65 -2.83 -0.567 0.48394E+04 190 pseudo-wollastonite 11.02 7.65 -3.37 -0.674 0.57580E+04 191 zoisite 22.96 19.18 -3.79 -0.172 0.64673E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.75 -3.19 -0.197 0.54445E+04 194 beidellite-H -2.24 -6.56 -4.31 -0.275 0.73675E+04 195 beidellite-K -1.44 -4.87 -3.44 -0.211 0.58730E+04 196 beidellite-Mg -1.71 -5.13 -3.42 -0.212 0.58427E+04 197 beidellite-Na -1.26 -4.22 -2.97 -0.182 0.50635E+04 199 chalcedony -2.79 -3.31 -0.51 -0.171 0.87631E+03 201 montmorillonite-Ca -2.21 -4.57 -2.35 -0.146 0.40175E+04 202 montmorillonite-K -2.16 -4.69 -2.53 -0.155 0.43237E+04 203 montmorillonite-Mg -2.40 -4.95 -2.55 -0.157 0.43467E+04 204 montmorillonite-Na -1.96 -4.04 -2.08 -0.127 0.35523E+04 205 nontronite-Ca 3.28 3.06 -0.22 -0.014 0.38021E+03 206 nontronite-H 2.60 1.25 -1.35 -0.090 0.22989E+04 207 nontronite-K 3.40 2.93 -0.47 -0.030 0.80784E+03 208 nontronite-Mg 3.14 2.68 -0.46 -0.030 0.79002E+03 224 tobermorite 9.84 5.82 -4.02 -1.097 0.68657E+04 233 boehmite 4.43 2.40 -2.03 -0.339 0.34721E+04 235 ferrous-oxide 9.82 6.42 -3.40 -0.851 0.58099E+04 240 silica-amorphous -2.08 -3.31 -1.23 -0.409 0.20965E+04 242 an20ab80 2.08 1.46 -0.62 -0.047 0.10540E+04 243 an25ab75 2.71 1.94 -0.77 -0.059 0.13111E+04 244 an30ab70 3.34 2.42 -0.92 -0.071 0.15765E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 3.3990000 g New total amount of reactant added: 3.4990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4563E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3.4990000 Water: Moles liquid = 0.5547E+02 kg liquid = 0.9994E+00 Moles total = 0.5546E+02 kg total = 0.9992E+00 Activity = 1.0000 Stoichiometric ionic strength = .2528746E-02 Osmotic coef. = 0.9721 True ionic strength = .4244799E-02 Chg. balance for total moles = 0.4563E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.33423E-09 -9.4760 0.30297E-09 -9.5186 0.90649E+00 -0.0426 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13791E-03 -3.8604 0.12481E-03 -3.9038 0.90502E+00 -0.0433 4 SO4-- 0.25509E-04 -4.5933 0.18117E-04 -4.7419 0.71025E+00 -0.1486 5 HCO3- 0.94100E-05 -5.0264 0.85196E-05 -5.0696 0.90537E+00 -0.0432 6 HS- 0.62102E-13 -13.2069 0.56206E-13 -13.2502 0.90506E+00 -0.0433 7 Al+++ 0.14459E-25 -25.8399 0.68232E-26 -26.1660 0.47189E+00 -0.3262 8 H4SiO4 0.49069E-03 -3.3092 0.49069E-03 -3.3092 0.10000E+01 0.0000 9 Ca++ 0.12335E-07 -7.9088 0.87442E-08 -8.0583 0.70887E+00 -0.1494 10 Mg++ 0.58332E-10 -10.2341 0.41299E-10 -10.3841 0.70800E+00 -0.1500 11 Fe++ 0.34493E-12 -12.4623 0.24428E-12 -12.6121 0.70821E+00 -0.1498 12 K+ 0.42711E-04 -4.3695 0.38672E-04 -4.4126 0.90543E+00 -0.0431 13 Na+ 0.41650E-02 -2.3804 0.37693E-02 -2.4237 0.90499E+00 -0.0434 14 Mn++ 0.46082E-10 -10.3365 0.32643E-10 -10.4862 0.70837E+00 -0.1497 15 HPO4-- 0.77861E-05 -5.1087 0.55303E-05 -5.2573 0.71027E+00 -0.1486 16 HSiO3- 0.17460E-02 -2.7579 0.15802E-02 -2.8013 0.90502E+00 -0.0433 17 Ca(HSiO3)+ 0.34190E-09 -9.4661 0.30958E-09 -9.5092 0.90549E+00 -0.0431 18 Mg(HSiO3)+ 0.20096E-11 -11.6969 0.18197E-11 -11.7400 0.90549E+00 -0.0431 19 NaHSiO3,aq 0.94598E-04 -4.0241 0.94598E-04 -4.0241 0.10000E+01 0.0000 20 AlO+ 0.10598E-13 -13.9748 0.95961E-14 -14.0179 0.90549E+00 -0.0431 21 AlOH+2 0.20555E-19 -19.6871 0.14564E-19 -19.8367 0.70855E+00 -0.1496 22 HAlO2,aq 0.63382E-08 -8.1980 0.63382E-08 -8.1980 0.10000E+01 0.0000 23 AlO2- 0.51639E-04 -4.2870 0.46712E-04 -4.3306 0.90458E+00 -0.0436 24 CH4,aq 0.25955E-19 -19.5858 0.25935E-19 -19.5861 0.99922E+00 -0.0003 29 CO,aq 0.90293E-19 -19.0443 0.90293E-19 -19.0443 0.10000E+01 0.0000 30 CO2,aq 0.52083E-08 -8.2833 0.52042E-08 -8.2836 0.99922E+00 -0.0003 31 CO3-2 0.36627E-05 -5.4362 0.26000E-05 -5.5850 0.70984E+00 -0.1488 32 CaCO3,aq 0.27844E-09 -9.5553 0.27844E-09 -9.5553 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.20730E-11 -11.6834 0.18771E-11 -11.7265 0.90549E+00 -0.0431 34 CaCl+ 0.19206E-11 -11.7166 0.17391E-11 -11.7597 0.90549E+00 -0.0431 35 CaCl2,aq 0.50538E-16 -16.2964 0.50538E-16 -16.2964 0.10000E+01 0.0000 36 CaOH+ 0.22475E-08 -8.6483 0.20351E-08 -8.6914 0.90549E+00 -0.0431 37 CaSO4,aq 0.49361E-10 -10.3066 0.49361E-10 -10.3066 0.10000E+01 0.0000 38 HCl,aq 0.71127E-14 -14.1480 0.71127E-14 -14.1480 0.10000E+01 0.0000 43 FeCl+ 0.52443E-16 -16.2803 0.47486E-16 -16.3234 0.90549E+00 -0.0431 46 FeO,aq 0.10524E-09 -9.9778 0.10524E-09 -9.9778 0.10000E+01 0.0000 47 FeOH+ 0.29520E-10 -10.5299 0.26730E-10 -10.5730 0.90549E+00 -0.0431 48 HFeO2- 0.41282E-08 -8.3842 0.37361E-08 -8.4276 0.90502E+00 -0.0433 49 FeO+ 0.27678E-14 -14.5579 0.25062E-14 -14.6010 0.90549E+00 -0.0431 51 FeO2- 0.59294E-08 -8.2270 0.53662E-08 -8.2703 0.90502E+00 -0.0433 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.67418E-09 -9.1712 0.67365E-09 -9.1716 0.99922E+00 -0.0003 54 KCl,aq 0.85463E-10 -10.0682 0.85463E-10 -10.0682 0.10000E+01 0.0000 55 KHSO4,aq 0.56804E-18 -18.2456 0.56804E-18 -18.2456 0.10000E+01 0.0000 56 KOH,aq 0.55646E-07 -7.2546 0.55646E-07 -7.2546 0.10000E+01 0.0000 57 KSO4- 0.11927E-07 -7.9235 0.10794E-07 -7.9668 0.90502E+00 -0.0433 58 MgCO3,aq 0.32862E-12 -12.4833 0.32862E-12 -12.4833 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.99842E-14 -14.0007 0.90405E-14 -14.0438 0.90549E+00 -0.0431 60 MgCl+ 0.82349E-14 -14.0843 0.74565E-14 -14.1275 0.90549E+00 -0.0431 61 MgOH+ 0.58808E-10 -10.2306 0.53250E-10 -10.2737 0.90549E+00 -0.0431 63 MnO,aq 0.37541E-09 -9.4255 0.37541E-09 -9.4255 0.10000E+01 0.0000 64 MnOH+ 0.36646E-09 -9.4360 0.33182E-09 -9.4791 0.90549E+00 -0.0431 65 MnO2-2 0.19925E-12 -12.7006 0.14144E-12 -12.8494 0.70984E+00 -0.1488 66 HMnO2- 0.10259E-10 -10.9889 0.92843E-11 -11.0322 0.90502E+00 -0.0433 69 MnCl+ 0.27232E-13 -13.5649 0.24658E-13 -13.6080 0.90549E+00 -0.0431 70 MnSO4,aq 0.16761E-12 -12.7757 0.16761E-12 -12.7757 0.10000E+01 0.0000 71 NaCl,aq 0.15361E-06 -6.8136 0.15361E-06 -6.8136 0.10000E+01 0.0000 72 NaOH,aq 0.54666E-05 -5.2623 0.54666E-05 -5.2623 0.10000E+01 0.0000 74 OH- 0.21887E-02 -2.6598 0.19798E-02 -2.7034 0.90458E+00 -0.0436 79 HPO3-2 0.16577E-16 -16.7805 0.11767E-16 -16.9293 0.70984E+00 -0.1488 82 H3PO4,aq 0.32681E-14 -14.4857 0.32681E-14 -14.4857 0.10000E+01 0.0000 83 H2PO4- 0.32450E-07 -7.4888 0.29375E-07 -7.5320 0.90525E+00 -0.0432 84 PO4-3 0.33340E-07 -7.4770 0.15941E-07 -7.7975 0.47814E+00 -0.3204 87 H2P2O7-2 0.95141E-16 -16.0216 0.67535E-16 -16.1705 0.70984E+00 -0.1488 88 HP2O7-3 0.96846E-13 -13.0139 0.45708E-13 -13.3400 0.47197E+00 -0.3261 89 P2O7-4 0.13848E-12 -12.8586 0.37219E-13 -13.4292 0.26876E+00 -0.5706 90 H2S,aq 0.51204E-16 -16.2907 0.51164E-16 -16.2910 0.99922E+00 -0.0003 97 SO3-2 0.23353E-14 -14.6317 0.16641E-14 -14.7788 0.71260E+00 -0.1472 98 HSO3- 0.32602E-16 -16.4868 0.29505E-16 -16.5301 0.90502E+00 -0.0433 99 HSO4- 0.56233E-11 -11.2500 0.50931E-11 -11.2930 0.90571E+00 -0.0430 Charge balance for all species = 0.5443E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3342268E-09 -.4245091E-02 -.4277360E+01 0.0000 2 H2O 0.1000000E+01 0.5550871E+02 0.9996703E+06 0.0000 3 Cl- 0.1379078E-03 0.1380615E-03 0.4893052E+01 5.6148 4 SO4-- 0.2550864E-04 0.2552122E-04 0.2450786E+01 14.2953 5 HCO3- 0.9410040E-05 0.1307827E-04 0.7977318E+00 4.4490 6 HS- 0.6210188E-13 -.5980010E-09 -.1977045E-04 -3.7316 7 Al+++ 0.1445932E-25 0.5164549E-04 0.1393005E+01 2.3898 8 H4SiO4 0.4906921E-03 0.2331314E-02 0.2240000E+03 -3.3092 9 Ca++ 0.1233538E-07 0.1525659E-07 0.6112484E-03 10.9789 10 Mg++ 0.5833166E-10 0.1194965E-09 0.2904224E-05 8.6531 11 Fe++ 0.3449274E-12 0.1039617E-07 0.5803997E-03 6.4251 12 K+ 0.4271112E-04 0.4277878E-04 0.1672174E+01 5.1060 13 Na+ 0.4164990E-02 0.4265208E-02 0.9802336E+02 7.0949 14 Mn++ 0.4608191E-10 0.7985962E-09 0.4385855E-04 8.5510 15 HPO4-- 0.7786136E-05 0.7851926E-05 0.7533670E+00 13.7799 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5792521E-01 -.4242405E-02 -.5368280E-01 0.0000000E+00 2 H2O 0.5546439E+02 0.5547359E+02 -.9196870E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1224737E-03 0.2550507E-04 0.9696862E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9696922E-04 -.5976226E-09 -.9696862E-04 0.0000000E+00 7 Al+++ 0.1140933E-01 0.5161282E-04 0.1135772E-01 0.0000000E+00 8 H4SiO4 0.3643433E-01 0.2329839E-02 0.3410449E-01 0.0000000E+00 9 Ca++ 0.4038820E-02 0.1524694E-07 0.4038805E-02 0.0000000E+00 10 Mg++ 0.2776984E-02 0.1194209E-09 0.2776984E-02 0.0000000E+00 11 Fe++ 0.2494817E-02 0.1038959E-07 0.2494807E-02 0.0000000E+00 12 K+ 0.7428875E-03 0.4275171E-04 0.7001358E-03 0.0000000E+00 13 Na+ 0.4552168E-02 0.4262509E-02 0.2896592E-03 0.0000000E+00 14 Mn++ 0.6066775E-04 0.7980909E-09 0.6066695E-04 0.0000000E+00 15 HPO4-- 0.2070560E-04 0.7846958E-05 0.1285864E-04 0.0000000E+00 Chg. balance for solid moles: 0.8586E-17 Mass of aqueous solution: 0.999703E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3.4990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4286E-05 -5.368 0.2153E-02 -2.667 0.5699E-01 0.6842E-03 clinochlore 0.5554E-03 -3.255 0.3087 -0.510 8.171 0.1174 daphnite 0.3438E-03 -3.464 0.2453 -0.610 6.493 0.7434E-01 chlorite-Mn 0.1213E-04 -4.916 0.8602E-02 -2.065 0.2277 0.2741E-02 hematite 0.2836E-03 -3.547 0.4529E-01 -1.344 1.199 0.8584E-02 microcline 0.7001E-03 -3.155 0.1949 -0.710 5.158 0.7612E-01 paragonite 0.2552E-03 -3.593 0.9756E-01 -1.011 2.582 0.3372E-01 stilbite 0.4017E-02 -2.396 2.831 0.452 74.94 1.320 nontronite-Na 0.1043E-03 -3.982 0.4434E-01 -1.353 1.174 0.1378E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.777965 g Volume = 1.647878 cm3 Porosity: 31.3270% V(tot) - V(min): 0.75172E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.4990000 g log = 0.5439 Original solution: 1000.0103000 g Original solution / Rock added: 285.80 (Water/Rock Ratio), log = 2.4561 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.5622E-06 1.0073 0.5957E-06 0.5914E-06 CH4,gas 0.3849E-16 1.0129 0.4101E-16 0.4049E-16 H2,gas 0.8779E-06 1.0006 0.9240E-06 0.9234E-06 H2S,gas 0.1424E-14 0.9959 0.1492E-14 0.1498E-14 S2,gas 0.9287E-37 1.0000 0.9770E-37 0.9770E-37 CO,gas 0.1355E-15 1.0000 0.1426E-15 0.1426E-15 SO3,gas 0.5910E-39 1.0000 0.6217E-39 0.6217E-39 SO2,gas 0.2066E-22 1.0000 0.2173E-22 0.2173E-22 HCl,gas 0.1194E-16 1.0000 0.1256E-16 0.1256E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.28814E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.45496E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.59 -8.22 -2.742 0.14044E+05 -6.225 3 CH4,gas 4.81 -13.58 -18.39 -4.597 0.31395E+05 -16.387 4 H2,gas 8.29 0.25 -8.03 -4.591 0.13718E+05 -6.034 5 H2S,gas -5.94 -22.77 -16.83 -8.413 0.28730E+05 -14.826 6 S2,gas -7.03 -46.04 -39.01 -6.002 0.66609E+05 -37.010 7 CO,gas 3.51 -14.34 -17.85 -5.491 0.30471E+05 -15.846 8 SO3,gas 17.43 -23.78 -41.21 -10.302 0.70359E+05 -39.206 9 SO2,gas 1.14 -23.53 -24.66 -6.577 0.42111E+05 -22.663 10 HCl,gas 5.48 -13.42 -18.90 -9.451 0.32273E+05 -16.901 11 acmite 7.74 6.78 -0.96 -0.100 0.16428E+04 15 albite-high 0.75 -0.44 -1.19 -0.092 0.20363E+04 16 albite -0.33 -0.44 -0.11 -0.009 0.19563E+03 19 spessartine 24.55 20.50 -4.04 -0.202 0.69066E+04 20 analcite 3.37 2.87 -0.50 -0.056 0.86122E+03 21 andalusite 5.06 1.47 -3.59 -0.359 0.61332E+04 22 andradite 39.09 35.61 -3.48 -0.181 0.59436E+04 26 annite 20.21 16.84 -3.37 -0.187 0.57471E+04 27 phlogopite 27.15 23.53 -3.62 -0.201 0.61793E+04 29 anorthite 12.80 9.14 -3.66 -0.281 0.62452E+04 35 aragonite 0.99 -3.61 -4.60 -1.532 0.78467E+04 36 brucite 12.58 8.65 -3.92 -0.785 0.66992E+04 37 calcite 0.83 -3.61 -4.44 -1.481 0.75853E+04 38 carnegieite-low 9.06 6.18 -2.89 -0.413 0.49331E+04 39 carnegieite-high 10.13 6.18 -3.96 -0.566 0.67599E+04 40 carpholite-Mg 8.65 6.81 -1.84 -0.122 0.31350E+04 41 carpholite-Fe 6.78 4.59 -2.20 -0.146 0.37507E+04 42 celadonite 5.40 2.91 -2.49 -0.146 0.42488E+04 43 celadonite-Fe 3.94 0.68 -3.25 -0.191 0.55541E+04 44 chrysotile 23.94 19.34 -4.60 -0.383 0.78481E+04 50 chloritoid-Mg 13.26 10.12 -3.14 -0.209 0.53576E+04 51 chloritoid-Fe 9.24 7.90 -1.34 -0.090 0.22935E+04 52 chloritoid-Mn 11.46 10.02 -1.44 -0.096 0.24619E+04 54 coesite -2.37 -3.31 -0.94 -0.313 0.16048E+04 59 corundum 8.43 4.78 -3.65 -0.332 0.62389E+04 61 cristobalite -2.55 -3.31 -0.76 -0.253 0.12976E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.39 -0.51 -0.084 0.86450E+03 67 diopside 16.22 13.01 -3.20 -0.320 0.54670E+04 68 hedenbergite 14.24 10.79 -3.46 -0.346 0.59058E+04 75 epidote 24.78 23.11 -1.67 -0.081 0.28456E+04 76 clinozoisite 22.92 19.20 -3.72 -0.169 0.63544E+04 77 epidote-Fe 29.94 27.02 -2.92 -0.152 0.49843E+04 78 fayalite 14.08 9.54 -4.54 -0.648 0.77485E+04 79 ferrosilite 11.19 6.23 -4.96 -0.496 0.84621E+04 83 gibbsite 4.10 2.39 -1.71 -0.244 0.29157E+04 84 glaucophane 23.11 18.46 -4.66 -0.126 0.79489E+04 87 greenalite 16.19 12.66 -3.54 -0.295 0.60399E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.87 -1.38 -0.138 0.23643E+04 97 kalsilite 7.62 4.19 -3.43 -0.491 0.58629E+04 98 kaolinite -1.27 -1.84 -0.57 -0.051 0.96588E+03 99 kyanite 4.93 1.47 -3.46 -0.346 0.59100E+04 101 laumontite 2.97 2.52 -0.45 -0.030 0.77319E+03 102 lawsonite 9.68 9.14 -0.54 -0.036 0.91909E+03 103 leucite 4.17 0.88 -3.29 -0.329 0.56180E+04 105 lizardite 23.29 19.34 -3.95 -0.329 0.67384E+04 107 magnetite 20.13 19.02 -1.11 -0.091 0.18954E+04 108 minnesotaite 10.46 6.04 -4.42 -0.260 0.75508E+04 113 margarite 17.45 13.92 -3.53 -0.141 0.60310E+04 120 muscovite 2.68 2.35 -0.33 -0.019 0.56590E+03 122 nepheline 8.38 6.18 -2.20 -0.315 0.37610E+04 134 phlogopite-Na 29.73 25.52 -4.21 -0.234 0.71968E+04 136 prehnite 19.47 16.81 -2.66 -0.156 0.45359E+04 137 prehnite-Fe 22.59 20.72 -1.87 -0.112 0.31894E+04 138 pumpellyite-Fe 46.47 42.43 -4.04 -0.090 0.68914E+04 139 pumpellyite-Mg 49.19 44.66 -4.53 -0.101 0.77374E+04 145 pyroxmangite 7.42 5.24 -2.17 -0.435 0.37125E+04 146 pyrophyllite -6.10 -8.46 -2.36 -0.147 0.40282E+04 147 quartz -2.98 -3.31 -0.33 -0.109 0.55867E+03 152 rhodonite 7.46 5.24 -2.22 -0.444 0.37917E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.47 -3.85 -0.385 0.65754E+04 164 stilpnomelane-Fe 13.18 12.98 -0.19 -0.006 0.33275E+03 165 stilpnomelane-Mg 27.60 24.12 -3.47 -0.104 0.59276E+04 168 sudoite 21.22 16.94 -4.28 -0.138 0.73052E+04 171 talc 16.55 12.72 -3.83 -0.225 0.65409E+04 174 tephroite 18.11 13.79 -4.32 -0.617 0.73765E+04 177 topaz-H 4.67 1.47 -3.20 -0.291 0.54591E+04 178 tridymite -2.61 -3.31 -0.69 -0.232 0.11860E+04 187 wairakite 4.06 2.52 -1.54 -0.090 0.26240E+04 188 walstromite 11.53 7.67 -3.86 -0.772 0.65877E+04 189 wollastonite 10.48 7.67 -2.81 -0.562 0.48016E+04 190 pseudo-wollastonite 11.02 7.67 -3.35 -0.670 0.57202E+04 191 zoisite 22.96 19.20 -3.76 -0.171 0.64270E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.77 -3.21 -0.198 0.54730E+04 194 beidellite-H -2.24 -6.58 -4.34 -0.277 0.74026E+04 195 beidellite-K -1.44 -4.89 -3.46 -0.212 0.59019E+04 196 beidellite-Mg -1.71 -5.15 -3.44 -0.213 0.58769E+04 197 beidellite-Na -1.26 -4.24 -2.98 -0.182 0.50852E+04 199 chalcedony -2.79 -3.31 -0.51 -0.172 0.87899E+03 201 montmorillonite-Ca -2.21 -4.58 -2.36 -0.146 0.40377E+04 202 montmorillonite-K -2.16 -4.71 -2.54 -0.156 0.43444E+04 203 montmorillonite-Mg -2.40 -4.96 -2.56 -0.158 0.43727E+04 204 montmorillonite-Na -1.96 -4.05 -2.09 -0.128 0.35658E+04 205 nontronite-Ca 3.28 3.05 -0.23 -0.015 0.38694E+03 206 nontronite-H 2.60 1.24 -1.35 -0.091 0.23123E+04 207 nontronite-K 3.40 2.93 -0.48 -0.031 0.81502E+03 208 nontronite-Mg 3.14 2.67 -0.47 -0.030 0.80246E+03 224 tobermorite 9.84 5.84 -4.00 -1.092 0.68346E+04 233 boehmite 4.43 2.39 -2.04 -0.340 0.34829E+04 235 ferrous-oxide 9.82 6.43 -3.40 -0.850 0.58039E+04 240 silica-amorphous -2.08 -3.31 -1.23 -0.410 0.20992E+04 242 an20ab80 2.08 1.47 -0.61 -0.047 0.10339E+04 243 an25ab75 2.71 1.95 -0.76 -0.058 0.12914E+04 244 an30ab70 3.34 2.43 -0.91 -0.070 0.15572E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 3.4990000 g New total amount of reactant added: 3.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4562E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3.5990000 Water: Moles liquid = 0.5547E+02 kg liquid = 0.9993E+00 Moles total = 0.5546E+02 kg total = 0.9992E+00 Activity = 1.0000 Stoichiometric ionic strength = .2589463E-02 Osmotic coef. = 0.9718 True ionic strength = .4354897E-02 Chg. balance for total moles = 0.4562E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.32526E-09 -9.4878 0.29457E-09 -9.5308 0.90564E+00 -0.0430 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13791E-03 -3.8604 0.12469E-03 -3.9042 0.90415E+00 -0.0438 4 SO4-- 0.25509E-04 -4.5933 0.18049E-04 -4.7435 0.70756E+00 -0.1502 5 HCO3- 0.93282E-05 -5.0302 0.84374E-05 -5.0738 0.90451E+00 -0.0436 6 HS- 0.64092E-13 -13.1932 0.57951E-13 -13.2369 0.90418E+00 -0.0437 7 Al+++ 0.13215E-25 -25.8789 0.61826E-26 -26.2088 0.46785E+00 -0.3299 8 H4SiO4 0.48897E-03 -3.3107 0.48897E-03 -3.3107 0.10000E+01 0.0000 9 Ca++ 0.12344E-07 -7.9085 0.87167E-08 -8.0596 0.70616E+00 -0.1511 10 Mg++ 0.55790E-10 -10.2534 0.39347E-10 -10.4051 0.70528E+00 -0.1516 11 Fe++ 0.32989E-12 -12.4816 0.23274E-12 -12.6331 0.70549E+00 -0.1515 12 K+ 0.42610E-04 -4.3705 0.38544E-04 -4.4140 0.90457E+00 -0.0436 13 Na+ 0.42753E-02 -2.3690 0.38654E-02 -2.4128 0.90411E+00 -0.0438 14 Mn++ 0.44073E-10 -10.3558 0.31100E-10 -10.5072 0.70565E+00 -0.1514 15 HPO4-- 0.75677E-05 -5.1210 0.53548E-05 -5.2713 0.70759E+00 -0.1502 16 HSiO3- 0.17912E-02 -2.7468 0.16195E-02 -2.7906 0.90415E+00 -0.0438 17 Ca(HSiO3)+ 0.34965E-09 -9.4564 0.31630E-09 -9.4999 0.90462E+00 -0.0435 18 Mg(HSiO3)+ 0.19642E-11 -11.7068 0.17769E-11 -11.7503 0.90462E+00 -0.0435 19 NaHSiO3,aq 0.99426E-04 -4.0025 0.99426E-04 -4.0025 0.10000E+01 0.0000 20 AlO+ 0.10168E-13 -13.9928 0.91981E-14 -14.0363 0.90462E+00 -0.0435 21 AlOH+2 0.19230E-19 -19.7160 0.13573E-19 -19.8673 0.70583E+00 -0.1513 22 HAlO2,aq 0.62485E-08 -8.2042 0.62485E-08 -8.2042 0.10000E+01 0.0000 23 AlO2- 0.52411E-04 -4.2806 0.47364E-04 -4.3246 0.90370E+00 -0.0440 24 CH4,aq 0.26604E-19 -19.5751 0.26582E-19 -19.5754 0.99920E+00 -0.0003 29 CO,aq 0.88312E-19 -19.0540 0.88312E-19 -19.0540 0.10000E+01 0.0000 30 CO2,aq 0.50151E-08 -8.2997 0.50111E-08 -8.3001 0.99920E+00 -0.0003 31 CO3-2 0.37450E-05 -5.4265 0.26483E-05 -5.5770 0.70715E+00 -0.1505 32 CaCO3,aq 0.28273E-09 -9.5486 0.28273E-09 -9.5486 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.20485E-11 -11.6886 0.18532E-11 -11.7321 0.90462E+00 -0.0435 34 CaCl+ 0.19145E-11 -11.7179 0.17319E-11 -11.7615 0.90462E+00 -0.0435 35 CaCl2,aq 0.50281E-16 -16.2986 0.50281E-16 -16.2986 0.10000E+01 0.0000 36 CaOH+ 0.23065E-08 -8.6370 0.20865E-08 -8.6806 0.90462E+00 -0.0435 37 CaSO4,aq 0.49021E-10 -10.3096 0.49021E-10 -10.3096 0.10000E+01 0.0000 38 HCl,aq 0.69087E-14 -14.1606 0.69087E-14 -14.1606 0.10000E+01 0.0000 43 FeCl+ 0.49963E-16 -16.3013 0.45198E-16 -16.3449 0.90462E+00 -0.0435 46 FeO,aq 0.10606E-09 -9.9744 0.10606E-09 -9.9744 0.10000E+01 0.0000 47 FeOH+ 0.28955E-10 -10.5383 0.26193E-10 -10.5818 0.90462E+00 -0.0435 48 HFeO2- 0.42833E-08 -8.3682 0.38727E-08 -8.4120 0.90415E+00 -0.0438 49 FeO+ 0.26937E-14 -14.5697 0.24367E-14 -14.6132 0.90462E+00 -0.0435 51 FeO2- 0.61043E-08 -8.2144 0.55192E-08 -8.2581 0.90415E+00 -0.0438 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.68480E-09 -9.1644 0.68425E-09 -9.1648 0.99920E+00 -0.0003 54 KCl,aq 0.85096E-10 -10.0701 0.85096E-10 -10.0701 0.10000E+01 0.0000 55 KHSO4,aq 0.54839E-18 -18.2609 0.54839E-18 -18.2609 0.10000E+01 0.0000 56 KOH,aq 0.57042E-07 -7.2438 0.57042E-07 -7.2438 0.10000E+01 0.0000 57 KSO4- 0.11854E-07 -7.9261 0.10718E-07 -7.9699 0.90415E+00 -0.0438 58 MgCO3,aq 0.31891E-12 -12.4963 0.31891E-12 -12.4963 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.94295E-14 -14.0255 0.85302E-14 -14.0690 0.90462E+00 -0.0435 60 MgCl+ 0.78455E-14 -14.1054 0.70972E-14 -14.1489 0.90462E+00 -0.0435 61 MgOH+ 0.57681E-10 -10.2390 0.52180E-10 -10.2825 0.90462E+00 -0.0435 63 MnO,aq 0.37835E-09 -9.4221 0.37835E-09 -9.4221 0.10000E+01 0.0000 64 MnOH+ 0.35943E-09 -9.4444 0.32515E-09 -9.4879 0.90462E+00 -0.0435 65 MnO2-2 0.21324E-12 -12.6711 0.15079E-12 -12.8216 0.70715E+00 -0.1505 66 HMnO2- 0.10644E-10 -10.9729 0.96239E-11 -11.0166 0.90415E+00 -0.0438 69 MnCl+ 0.25944E-13 -13.5860 0.23469E-13 -13.6295 0.90462E+00 -0.0435 70 MnSO4,aq 0.15908E-12 -12.7984 0.15908E-12 -12.7984 0.10000E+01 0.0000 71 NaCl,aq 0.15737E-06 -6.8031 0.15737E-06 -6.8031 0.10000E+01 0.0000 72 NaOH,aq 0.57659E-05 -5.2391 0.57659E-05 -5.2391 0.10000E+01 0.0000 74 OH- 0.22533E-02 -2.6472 0.20363E-02 -2.6912 0.90370E+00 -0.0440 79 HPO3-2 0.16366E-16 -16.7861 0.11573E-16 -16.9366 0.70715E+00 -0.1505 82 H3PO4,aq 0.29914E-14 -14.5241 0.29914E-14 -14.5241 0.10000E+01 0.0000 83 H2PO4- 0.30579E-07 -7.5146 0.27655E-07 -7.5582 0.90438E+00 -0.0436 84 PO4-3 0.33479E-07 -7.4752 0.15875E-07 -7.7993 0.47419E+00 -0.3241 87 H2P2O7-2 0.84644E-16 -16.0724 0.59856E-16 -16.2229 0.70715E+00 -0.1505 88 HP2O7-3 0.89044E-13 -13.0504 0.41666E-13 -13.3802 0.46793E+00 -0.3298 89 P2O7-4 0.13181E-12 -12.8800 0.34895E-13 -13.4572 0.26473E+00 -0.5772 90 H2S,aq 0.51332E-16 -16.2896 0.51290E-16 -16.2900 0.99920E+00 -0.0003 97 SO3-2 0.23719E-14 -14.6249 0.16840E-14 -14.7737 0.70996E+00 -0.1488 98 HSO3- 0.32107E-16 -16.4934 0.29030E-16 -16.5372 0.90415E+00 -0.0438 99 HSO4- 0.54520E-11 -11.2634 0.49333E-11 -11.3069 0.90486E+00 -0.0434 Charge balance for all species = 0.5433E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3252637E-09 -.4363209E-02 -.4396343E+01 0.0000 2 H2O 0.1000000E+01 0.5550872E+02 0.9996631E+06 0.0000 3 Cl- 0.1379065E-03 0.1380639E-03 0.4893101E+01 5.6266 4 SO4-- 0.2550915E-04 0.2552168E-04 0.2450812E+01 14.3181 5 HCO3- 0.9328173E-05 0.1307850E-04 0.7977398E+00 4.4570 6 HS- 0.6409226E-13 -.6172110E-09 -.2040540E-04 -3.7061 7 Al+++ 0.1321497E-25 0.5241718E-04 0.1413809E+01 2.3836 8 H4SiO4 0.4889727E-03 0.2379639E-02 0.2286415E+03 -3.3107 9 Ca++ 0.1234384E-07 0.1533574E-07 0.6144149E-03 11.0020 10 Mg++ 0.5578967E-10 0.1157714E-09 0.2813669E-05 8.6565 11 Fe++ 0.3298938E-12 0.1072646E-07 0.5988351E-03 6.4285 12 K+ 0.4260990E-04 0.4267888E-04 0.1668257E+01 5.1168 13 Na+ 0.4275324E-02 0.4380673E-02 0.1006762E+03 7.1180 14 Mn++ 0.4407324E-10 0.7928970E-09 0.4354523E-04 8.5544 15 HPO4-- 0.7567700E-05 0.7631759E-05 0.7322372E+00 13.7904 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5958106E-01 -.4360372E-02 -.5522069E-01 0.0000000E+00 2 H2O 0.5546314E+02 0.5547263E+02 -.9496685E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1252450E-03 0.2550509E-04 0.9973994E-04 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9974056E-04 -.6168097E-09 -.9973994E-04 0.0000000E+00 7 Al+++ 0.1173541E-01 0.5238310E-04 0.1168303E-01 0.0000000E+00 8 H4SiO4 0.3747561E-01 0.2378092E-02 0.3509751E-01 0.0000000E+00 9 Ca++ 0.4153834E-02 0.1532577E-07 0.4153819E-02 0.0000000E+00 10 Mg++ 0.2856349E-02 0.1156962E-09 0.2856349E-02 0.0000000E+00 11 Fe++ 0.2566118E-02 0.1071949E-07 0.2566107E-02 0.0000000E+00 12 K+ 0.7641189E-03 0.4265113E-04 0.7214678E-03 0.0000000E+00 13 Na+ 0.4677693E-02 0.4377825E-02 0.2998679E-03 0.0000000E+00 14 Mn++ 0.6240161E-04 0.7923814E-09 0.6240081E-04 0.0000000E+00 15 HPO4-- 0.2129736E-04 0.7626796E-05 0.1367056E-04 0.0000000E+00 Chg. balance for solid moles: -.2771E-17 Mass of aqueous solution: 0.999693E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4557E-05 -5.341 0.2289E-02 -2.640 0.5889E-01 0.7274E-03 clinochlore 0.5713E-03 -3.243 0.3175 -0.498 8.169 0.1208 daphnite 0.3536E-03 -3.451 0.2523 -0.598 6.491 0.7646E-01 chlorite-Mn 0.1248E-04 -4.904 0.8848E-02 -2.053 0.2276 0.2820E-02 hematite 0.2855E-03 -3.544 0.4559E-01 -1.341 1.173 0.8642E-02 microcline 0.7215E-03 -3.142 0.2008 -0.697 5.166 0.7844E-01 paragonite 0.2624E-03 -3.581 0.1003 -0.999 2.580 0.3467E-01 stilbite 0.4131E-02 -2.384 2.911 0.464 74.89 1.358 nontronite-Na 0.1135E-03 -3.945 0.4825E-01 -1.316 1.241 0.1499E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.887171 g Volume = 1.695379 cm3 Porosity: 30.5059% V(tot) - V(min): 0.74422E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.5990000 g log = 0.5562 Original solution: 1000.0103000 g Original solution / Rock added: 277.86 (Water/Rock Ratio), log = 2.4438 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.5413E-06 1.0073 0.5736E-06 0.5694E-06 CH4,gas 0.3945E-16 1.0129 0.4204E-16 0.4150E-16 H2,gas 0.8917E-06 1.0006 0.9385E-06 0.9380E-06 H2S,gas 0.1428E-14 0.9959 0.1496E-14 0.1502E-14 S2,gas 0.9046E-37 1.0000 0.9516E-37 0.9516E-37 CO,gas 0.1326E-15 1.0000 0.1394E-15 0.1394E-15 SO3,gas 0.5566E-39 1.0000 0.5855E-39 0.5855E-39 SO2,gas 0.1976E-22 1.0000 0.2079E-22 0.2079E-22 HCl,gas 0.1160E-16 1.0000 0.1220E-16 0.1220E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 0.19715E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.60 -8.24 -2.747 0.14072E+05 -6.241 3 CH4,gas 4.81 -13.57 -18.38 -4.594 0.31377E+05 -16.376 4 H2,gas 8.29 0.26 -8.03 -4.587 0.13707E+05 -6.028 5 H2S,gas -5.94 -22.77 -16.83 -8.413 0.28728E+05 -14.825 6 S2,gas -7.03 -46.05 -39.02 -6.003 0.66628E+05 -37.022 7 CO,gas 3.51 -14.35 -17.86 -5.494 0.30488E+05 -15.856 8 SO3,gas 17.43 -23.81 -41.23 -10.308 0.70403E+05 -39.232 9 SO2,gas 1.14 -23.55 -24.68 -6.582 0.42144E+05 -22.682 10 HCl,gas 5.48 -13.43 -18.91 -9.457 0.32295E+05 -16.914 11 acmite 7.74 6.80 -0.94 -0.098 0.16085E+04 15 albite-high 0.75 -0.43 -1.18 -0.091 0.20152E+04 16 albite -0.33 -0.43 -0.10 -0.008 0.17449E+03 19 spessartine 24.55 20.50 -4.05 -0.203 0.69182E+04 20 analcite 3.37 2.88 -0.49 -0.054 0.83748E+03 21 andalusite 5.06 1.46 -3.61 -0.361 0.61570E+04 22 andradite 39.09 35.67 -3.42 -0.177 0.58334E+04 23 grossular 32.83 27.84 -4.99 -0.249 0.85156E+04 26 annite 20.21 16.85 -3.36 -0.186 0.57297E+04 27 phlogopite 27.15 23.54 -3.61 -0.200 0.61619E+04 29 anorthite 12.80 9.15 -3.65 -0.281 0.62322E+04 35 aragonite 0.99 -3.60 -4.59 -1.530 0.78353E+04 36 brucite 12.58 8.66 -3.92 -0.784 0.66934E+04 37 calcite 0.83 -3.60 -4.44 -1.479 0.75740E+04 38 carnegieite-low 9.06 6.19 -2.87 -0.411 0.49067E+04 39 carnegieite-high 10.13 6.19 -3.94 -0.563 0.67336E+04 40 carpholite-Mg 8.65 6.80 -1.85 -0.123 0.31556E+04 41 carpholite-Fe 6.78 4.57 -2.21 -0.147 0.37712E+04 42 celadonite 5.40 2.91 -2.49 -0.146 0.42456E+04 43 celadonite-Fe 3.94 0.69 -3.25 -0.191 0.55509E+04 44 chrysotile 23.94 19.35 -4.59 -0.382 0.78359E+04 50 chloritoid-Mg 13.26 10.11 -3.15 -0.210 0.53755E+04 51 chloritoid-Fe 9.24 7.88 -1.35 -0.090 0.23115E+04 52 chloritoid-Mn 11.46 10.01 -1.45 -0.097 0.24799E+04 54 coesite -2.37 -3.31 -0.94 -0.314 0.16074E+04 59 corundum 8.43 4.77 -3.67 -0.333 0.62600E+04 61 cristobalite -2.55 -3.31 -0.76 -0.254 0.13002E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.38 -0.51 -0.085 0.87507E+03 67 diopside 16.22 13.04 -3.18 -0.318 0.54270E+04 68 hedenbergite 14.24 10.81 -3.44 -0.344 0.58659E+04 75 epidote 24.78 23.14 -1.64 -0.079 0.27959E+04 76 clinozoisite 22.92 19.22 -3.70 -0.168 0.63152E+04 77 epidote-Fe 29.94 27.05 -2.88 -0.150 0.49240E+04 78 fayalite 14.08 9.55 -4.53 -0.648 0.77395E+04 79 ferrosilite 11.19 6.24 -4.95 -0.495 0.84557E+04 83 gibbsite 4.10 2.38 -1.71 -0.245 0.29263E+04 84 glaucophane 23.11 18.49 -4.62 -0.125 0.78945E+04 87 greenalite 16.19 12.66 -3.53 -0.294 0.60277E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.88 -1.37 -0.137 0.23405E+04 97 kalsilite 7.62 4.19 -3.43 -0.490 0.58577E+04 98 kaolinite -1.27 -1.85 -0.58 -0.053 0.99222E+03 99 kyanite 4.93 1.46 -3.48 -0.348 0.59338E+04 101 laumontite 2.97 2.53 -0.45 -0.030 0.76538E+03 102 lawsonite 9.68 9.15 -0.53 -0.035 0.90608E+03 103 leucite 4.17 0.88 -3.29 -0.329 0.56154E+04 105 lizardite 23.29 19.35 -3.94 -0.328 0.67262E+04 107 magnetite 20.13 19.03 -1.11 -0.090 0.18896E+04 108 minnesotaite 10.46 6.04 -4.42 -0.260 0.75439E+04 113 margarite 17.45 13.91 -3.54 -0.141 0.60392E+04 120 muscovite 2.68 2.34 -0.34 -0.020 0.58704E+03 122 nepheline 8.38 6.19 -2.19 -0.312 0.37347E+04 134 phlogopite-Na 29.73 25.54 -4.19 -0.233 0.71583E+04 136 prehnite 19.47 16.84 -2.63 -0.155 0.44861E+04 137 prehnite-Fe 22.59 20.75 -1.83 -0.110 0.31291E+04 138 pumpellyite-Fe 46.47 42.49 -3.98 -0.088 0.67967E+04 139 pumpellyite-Mg 49.19 44.72 -4.48 -0.099 0.76426E+04 145 pyroxmangite 7.42 5.24 -2.17 -0.434 0.37093E+04 146 pyrophyllite -6.10 -8.48 -2.38 -0.149 0.40598E+04 147 quartz -2.98 -3.31 -0.33 -0.110 0.56128E+03 152 rhodonite 7.46 5.24 -2.22 -0.444 0.37885E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.46 -3.86 -0.386 0.65992E+04 164 stilpnomelane-Fe 13.18 12.98 -0.20 -0.006 0.33657E+03 165 stilpnomelane-Mg 27.60 24.12 -3.47 -0.104 0.59314E+04 168 sudoite 21.22 16.92 -4.30 -0.139 0.73437E+04 171 talc 16.55 12.73 -3.83 -0.225 0.65339E+04 174 tephroite 18.11 13.80 -4.31 -0.616 0.73675E+04 177 topaz-H 4.67 1.46 -3.21 -0.292 0.54828E+04 178 tridymite -2.61 -3.31 -0.70 -0.232 0.11886E+04 187 wairakite 4.06 2.53 -1.53 -0.090 0.26162E+04 188 walstromite 11.53 7.69 -3.84 -0.767 0.65509E+04 189 wollastonite 10.48 7.69 -2.79 -0.558 0.47648E+04 190 pseudo-wollastonite 11.02 7.69 -3.33 -0.666 0.56834E+04 191 zoisite 22.96 19.22 -3.74 -0.170 0.63878E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.78 -3.22 -0.199 0.55007E+04 194 beidellite-H -2.24 -6.60 -4.36 -0.278 0.74368E+04 195 beidellite-K -1.44 -4.91 -3.47 -0.213 0.59301E+04 196 beidellite-Mg -1.71 -5.17 -3.46 -0.214 0.59101E+04 197 beidellite-Na -1.26 -4.25 -2.99 -0.183 0.51064E+04 199 chalcedony -2.79 -3.31 -0.52 -0.172 0.88159E+03 201 montmorillonite-Ca -2.21 -4.59 -2.38 -0.147 0.40574E+04 202 montmorillonite-K -2.16 -4.72 -2.56 -0.157 0.43645E+04 203 montmorillonite-Mg -2.40 -4.98 -2.58 -0.159 0.43979E+04 204 montmorillonite-Na -1.96 -4.06 -2.10 -0.128 0.35789E+04 205 nontronite-Ca 3.28 3.05 -0.23 -0.015 0.39349E+03 206 nontronite-H 2.60 1.23 -1.36 -0.091 0.23253E+04 207 nontronite-K 3.40 2.92 -0.48 -0.031 0.82199E+03 208 nontronite-Mg 3.14 2.66 -0.48 -0.031 0.81454E+03 224 tobermorite 9.84 5.85 -3.99 -1.087 0.68044E+04 233 boehmite 4.43 2.38 -2.05 -0.341 0.34935E+04 235 ferrous-oxide 9.82 6.43 -3.40 -0.849 0.57981E+04 240 silica-amorphous -2.08 -3.31 -1.23 -0.410 0.21018E+04 242 an20ab80 2.08 1.49 -0.59 -0.046 0.10144E+04 243 an25ab75 2.71 1.96 -0.75 -0.057 0.12723E+04 244 an30ab70 3.34 2.44 -0.90 -0.069 0.15385E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 3.5990000 g New total amount of reactant added: 3.6990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4564E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3.6990000 Water: Moles liquid = 0.5547E+02 kg liquid = 0.9993E+00 Moles total = 0.5546E+02 kg total = 0.9992E+00 Activity = 1.0000 Stoichiometric ionic strength = .2650169E-02 Osmotic coef. = 0.9715 True ionic strength = .4464919E-02 Chg. balance for total moles = 0.4564E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.31679E-09 -9.4992 0.28663E-09 -9.5427 0.90482E+00 -0.0434 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13791E-03 -3.8604 0.12457E-03 -3.9046 0.90329E+00 -0.0442 4 SO4-- 0.25510E-04 -4.5933 0.17983E-04 -4.7451 0.70493E+00 -0.1519 5 HCO3- 0.92475E-05 -5.0340 0.83565E-05 -5.0780 0.90365E+00 -0.0440 6 HS- 0.66088E-13 -13.1799 0.59699E-13 -13.2240 0.90333E+00 -0.0442 7 Al+++ 0.12110E-25 -25.9169 0.56176E-26 -26.2504 0.46390E+00 -0.3336 8 H4SiO4 0.48731E-03 -3.3122 0.48731E-03 -3.3122 0.10000E+01 0.0000 9 Ca++ 0.12353E-07 -7.9082 0.86904E-08 -8.0610 0.70350E+00 -0.1527 10 Mg++ 0.53428E-10 -10.2722 0.37539E-10 -10.4255 0.70260E+00 -0.1533 11 Fe++ 0.31593E-12 -12.5004 0.22204E-12 -12.6536 0.70282E+00 -0.1532 12 K+ 0.42513E-04 -4.3715 0.38420E-04 -4.4154 0.90372E+00 -0.0440 13 Na+ 0.43856E-02 -2.3580 0.39613E-02 -2.4022 0.90325E+00 -0.0442 14 Mn++ 0.42207E-10 -10.3746 0.29671E-10 -10.5277 0.70298E+00 -0.1531 15 HPO4-- 0.73612E-05 -5.1331 0.51893E-05 -5.2849 0.70496E+00 -0.1518 16 HSiO3- 0.18363E-02 -2.7361 0.16587E-02 -2.7802 0.90329E+00 -0.0442 17 Ca(HSiO3)+ 0.35736E-09 -9.4469 0.32297E-09 -9.4908 0.90377E+00 -0.0439 18 Mg(HSiO3)+ 0.19211E-11 -11.7165 0.17362E-11 -11.7604 0.90377E+00 -0.0439 19 NaHSiO3,aq 0.10436E-03 -3.9815 0.10436E-03 -3.9815 0.10000E+01 0.0000 20 AlO+ 0.97668E-14 -14.0102 0.88270E-14 -14.0542 0.90377E+00 -0.0439 21 AlOH+2 0.18025E-19 -19.7441 0.12674E-19 -19.8971 0.70317E+00 -0.1529 22 HAlO2,aq 0.61624E-08 -8.2102 0.61624E-08 -8.2102 0.10000E+01 0.0000 23 AlO2- 0.53172E-04 -4.2743 0.48005E-04 -4.3187 0.90283E+00 -0.0444 24 CH4,aq 0.27245E-19 -19.5647 0.27222E-19 -19.5651 0.99918E+00 -0.0004 29 CO,aq 0.86410E-19 -19.0634 0.86410E-19 -19.0634 0.10000E+01 0.0000 30 CO2,aq 0.48333E-08 -8.3158 0.48293E-08 -8.3161 0.99918E+00 -0.0004 31 CO3-2 0.38261E-05 -5.4172 0.26956E-05 -5.5694 0.70451E+00 -0.1521 32 CaCO3,aq 0.28691E-09 -9.5423 0.28691E-09 -9.5423 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.20247E-11 -11.6936 0.18299E-11 -11.7376 0.90377E+00 -0.0439 34 CaCl+ 0.19087E-11 -11.7193 0.17250E-11 -11.7632 0.90377E+00 -0.0439 35 CaCl2,aq 0.50033E-16 -16.3007 0.50033E-16 -16.3007 0.10000E+01 0.0000 36 CaOH+ 0.23655E-08 -8.6261 0.21379E-08 -8.6700 0.90377E+00 -0.0439 37 CaSO4,aq 0.48692E-10 -10.3125 0.48692E-10 -10.3125 0.10000E+01 0.0000 38 HCl,aq 0.67161E-14 -14.1729 0.67161E-14 -14.1729 0.10000E+01 0.0000 43 FeCl+ 0.47666E-16 -16.3218 0.43079E-16 -16.3657 0.90377E+00 -0.0439 46 FeO,aq 0.10687E-09 -9.9711 0.10687E-09 -9.9711 0.10000E+01 0.0000 47 FeOH+ 0.28416E-10 -10.5464 0.25681E-10 -10.5904 0.90377E+00 -0.0439 48 HFeO2- 0.44397E-08 -8.3526 0.40103E-08 -8.3968 0.90329E+00 -0.0442 49 FeO+ 0.26235E-14 -14.5811 0.23711E-14 -14.6251 0.90377E+00 -0.0439 51 FeO2- 0.62794E-08 -8.2021 0.56721E-08 -8.2463 0.90329E+00 -0.0442 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.69529E-09 -9.1578 0.69472E-09 -9.1582 0.99918E+00 -0.0004 54 KCl,aq 0.84741E-10 -10.0719 0.84741E-10 -10.0719 0.10000E+01 0.0000 55 KHSO4,aq 0.52993E-18 -18.2758 0.52993E-18 -18.2758 0.10000E+01 0.0000 56 KOH,aq 0.58434E-07 -7.2333 0.58434E-07 -7.2333 0.10000E+01 0.0000 57 KSO4- 0.11784E-07 -7.9287 0.10644E-07 -7.9729 0.90329E+00 -0.0442 58 MgCO3,aq 0.30968E-12 -12.5091 0.30968E-12 -12.5091 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.89183E-14 -14.0497 0.80601E-14 -14.0937 0.90377E+00 -0.0439 60 MgCl+ 0.74848E-14 -14.1258 0.67645E-14 -14.1698 0.90377E+00 -0.0439 61 MgOH+ 0.56608E-10 -10.2471 0.51161E-10 -10.2911 0.90377E+00 -0.0439 63 MnO,aq 0.38123E-09 -9.4188 0.38123E-09 -9.4188 0.10000E+01 0.0000 64 MnOH+ 0.35274E-09 -9.4525 0.31880E-09 -9.4965 0.90377E+00 -0.0439 65 MnO2-2 0.22778E-12 -12.6425 0.16047E-12 -12.7946 0.70451E+00 -0.1521 66 HMnO2- 0.11033E-10 -10.9573 0.99658E-11 -11.0015 0.90329E+00 -0.0442 69 MnCl+ 0.24751E-13 -13.6064 0.22369E-13 -13.6503 0.90377E+00 -0.0439 70 MnSO4,aq 0.15121E-12 -12.8204 0.15121E-12 -12.8204 0.10000E+01 0.0000 71 NaCl,aq 0.16112E-06 -6.7928 0.16112E-06 -6.7928 0.10000E+01 0.0000 72 NaOH,aq 0.60726E-05 -5.2166 0.60726E-05 -5.2166 0.10000E+01 0.0000 74 OH- 0.23179E-02 -2.6349 0.20927E-02 -2.6793 0.90283E+00 -0.0444 79 HPO3-2 0.16163E-16 -16.7915 0.11387E-16 -16.9436 0.70451E+00 -0.1521 82 H3PO4,aq 0.27448E-14 -14.5615 0.27448E-14 -14.5615 0.10000E+01 0.0000 83 H2PO4- 0.28862E-07 -7.5397 0.26078E-07 -7.5837 0.90353E+00 -0.0441 84 PO4-3 0.33616E-07 -7.4735 0.15811E-07 -7.8010 0.47033E+00 -0.3276 87 H2P2O7-2 0.75548E-16 -16.1218 0.53224E-16 -16.2739 0.70451E+00 -0.1521 88 HP2O7-3 0.82062E-13 -13.0859 0.38076E-13 -13.4193 0.46399E+00 -0.3335 89 P2O7-4 0.12565E-12 -12.9008 0.32771E-13 -13.4845 0.26082E+00 -0.5837 90 H2S,aq 0.51456E-16 -16.2886 0.51414E-16 -16.2889 0.99918E+00 -0.0004 97 SO3-2 0.24081E-14 -14.6183 0.17034E-14 -14.7687 0.70737E+00 -0.1504 98 HSO3- 0.31633E-16 -16.4999 0.28573E-16 -16.5440 0.90329E+00 -0.0442 99 HSO4- 0.52904E-11 -11.2765 0.47826E-11 -11.3203 0.90401E+00 -0.0438 Charge balance for all species = 0.5431E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3167870E-09 -.4481296E-02 -.4515294E+01 0.0000 2 H2O 0.1000000E+01 0.5550874E+02 0.9996559E+06 0.0000 3 Cl- 0.1379052E-03 0.1380664E-03 0.4893150E+01 5.6381 4 SO4-- 0.2550967E-04 0.2552215E-04 0.2450839E+01 14.3402 5 HCO3- 0.9247463E-05 0.1307873E-04 0.7977478E+00 4.4647 6 HS- 0.6608825E-13 -.6364654E-09 -.2104180E-04 -3.6814 7 Al+++ 0.1210958E-25 0.5317831E-04 0.1434328E+01 2.3776 8 H4SiO4 0.4873063E-03 0.2427987E-02 0.2332851E+03 -3.3122 9 Ca++ 0.1235314E-07 0.1541553E-07 0.6176070E-03 11.0244 10 Mg++ 0.5342841E-10 0.1122833E-09 0.2728876E-05 8.6598 11 Fe++ 0.3159292E-12 0.1105815E-07 0.6173481E-03 6.4318 12 K+ 0.4251302E-04 0.4258332E-04 0.1664509E+01 5.1272 13 Na+ 0.4385567E-02 0.4496159E-02 0.1033296E+03 7.1405 14 Mn++ 0.4220739E-10 0.7876194E-09 0.4325506E-04 8.5577 15 HPO4-- 0.7361186E-05 0.7423665E-05 0.7122661E+00 13.8005 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6123691E-01 -.4478304E-02 -.5675860E-01 0.0000000E+00 2 H2O 0.5546188E+02 0.5547168E+02 -.9796337E-02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1280164E-03 0.2550511E-04 0.1025113E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1025119E-03 -.6360404E-09 -.1025113E-03 0.0000000E+00 7 Al+++ 0.1206148E-01 0.5314281E-04 0.1200834E-01 0.0000000E+00 8 H4SiO4 0.3851688E-01 0.2426366E-02 0.3609052E-01 0.0000000E+00 9 Ca++ 0.4268849E-02 0.1540524E-07 0.4268833E-02 0.0000000E+00 10 Mg++ 0.2935714E-02 0.1122084E-09 0.2935714E-02 0.0000000E+00 11 Fe++ 0.2637419E-02 0.1105077E-07 0.2637408E-02 0.0000000E+00 12 K+ 0.7853503E-03 0.4255489E-04 0.7427954E-03 0.0000000E+00 13 Na+ 0.4803217E-02 0.4493157E-02 0.3100600E-03 0.0000000E+00 14 Mn++ 0.6413547E-04 0.7870935E-09 0.6413468E-04 0.0000000E+00 15 HPO4-- 0.2188912E-04 0.7418708E-05 0.1447041E-04 0.0000000E+00 Chg. balance for solid moles: -.1408E-16 Mass of aqueous solution: 0.999683E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3.6990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.4823E-05 -5.317 0.2423E-02 -2.616 0.6063E-01 0.7699E-03 clinochlore 0.5871E-03 -3.231 0.3264 -0.486 8.166 0.1241 daphnite 0.3635E-03 -3.440 0.2593 -0.586 6.489 0.7859E-01 chlorite-Mn 0.1283E-04 -4.892 0.9094E-02 -2.041 0.2276 0.2898E-02 hematite 0.2874E-03 -3.541 0.4590E-01 -1.338 1.149 0.8700E-02 microcline 0.7428E-03 -3.129 0.2067 -0.685 5.173 0.8076E-01 paragonite 0.2696E-03 -3.569 0.1030 -0.987 2.578 0.3562E-01 stilbite 0.4245E-02 -2.372 2.991 0.476 74.85 1.395 nontronite-Na 0.1226E-03 -3.911 0.5215E-01 -1.283 1.305 0.1620E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3.996377 g Volume = 1.742880 cm3 Porosity: 29.7112% V(tot) - V(min): 0.73672E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.6990000 g log = 0.5681 Original solution: 1000.0103000 g Original solution / Rock added: 270.35 (Water/Rock Ratio), log = 2.4319 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.5217E-06 1.0073 0.5528E-06 0.5488E-06 CH4,gas 0.4040E-16 1.0129 0.4305E-16 0.4250E-16 H2,gas 0.9053E-06 1.0006 0.9529E-06 0.9523E-06 H2S,gas 0.1431E-14 0.9959 0.1500E-14 0.1506E-14 S2,gas 0.8818E-37 1.0000 0.9276E-37 0.9276E-37 CO,gas 0.1297E-15 1.0000 0.1364E-15 0.1364E-15 SO3,gas 0.5251E-39 1.0000 0.5523E-39 0.5523E-39 SO2,gas 0.1893E-22 1.0000 0.1991E-22 0.1991E-22 HCl,gas 0.1127E-16 1.0000 0.1186E-16 0.1186E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.37914E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.62 -8.26 -2.752 0.14099E+05 -6.257 3 CH4,gas 4.81 -13.56 -18.37 -4.592 0.31360E+05 -16.366 4 H2,gas 8.29 0.27 -8.02 -4.583 0.13696E+05 -6.021 5 H2S,gas -5.94 -22.77 -16.82 -8.412 0.28727E+05 -14.824 6 S2,gas -7.03 -46.07 -39.03 -6.005 0.66647E+05 -37.033 7 CO,gas 3.51 -14.35 -17.87 -5.497 0.30504E+05 -15.865 8 SO3,gas 17.43 -23.83 -41.26 -10.314 0.70447E+05 -39.258 9 SO2,gas 1.14 -23.56 -24.70 -6.587 0.42176E+05 -22.701 10 HCl,gas 5.48 -13.45 -18.93 -9.463 0.32316E+05 -16.926 11 acmite 7.74 6.81 -0.92 -0.096 0.15751E+04 15 albite-high 0.75 -0.42 -1.17 -0.090 0.19946E+04 16 albite -0.33 -0.42 -0.09 -0.007 0.15394E+03 19 spessartine 24.55 20.49 -4.06 -0.203 0.69295E+04 20 analcite 3.37 2.89 -0.48 -0.053 0.81439E+03 21 andalusite 5.06 1.44 -3.62 -0.362 0.61801E+04 22 andradite 39.09 35.73 -3.35 -0.174 0.57261E+04 23 grossular 32.83 27.89 -4.94 -0.247 0.84289E+04 26 annite 20.21 16.86 -3.35 -0.186 0.57128E+04 27 phlogopite 27.15 23.55 -3.60 -0.200 0.61450E+04 29 anorthite 12.80 9.16 -3.64 -0.280 0.62195E+04 35 aragonite 0.99 -3.60 -4.58 -1.527 0.78245E+04 36 brucite 12.58 8.66 -3.92 -0.783 0.66878E+04 37 calcite 0.83 -3.60 -4.43 -1.476 0.75631E+04 38 carnegieite-low 9.06 6.21 -2.86 -0.408 0.48811E+04 39 carnegieite-high 10.13 6.21 -3.93 -0.561 0.67080E+04 40 carpholite-Mg 8.65 6.79 -1.86 -0.124 0.31756E+04 41 carpholite-Fe 6.78 4.56 -2.22 -0.148 0.37912E+04 42 celadonite 5.40 2.92 -2.48 -0.146 0.42425E+04 43 celadonite-Fe 3.94 0.69 -3.25 -0.191 0.55478E+04 44 chrysotile 23.94 19.36 -4.58 -0.382 0.78241E+04 50 chloritoid-Mg 13.26 10.10 -3.16 -0.211 0.53930E+04 51 chloritoid-Fe 9.24 7.87 -1.36 -0.091 0.23289E+04 52 chloritoid-Mn 11.46 10.00 -1.46 -0.098 0.24973E+04 54 coesite -2.37 -3.31 -0.94 -0.314 0.16099E+04 59 corundum 8.43 4.76 -3.68 -0.334 0.62806E+04 61 cristobalite -2.55 -3.31 -0.76 -0.254 0.13028E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.38 -0.52 -0.086 0.88535E+03 67 diopside 16.22 13.06 -3.16 -0.316 0.53882E+04 68 hedenbergite 14.24 10.83 -3.41 -0.341 0.58270E+04 75 epidote 24.78 23.17 -1.61 -0.078 0.27474E+04 76 clinozoisite 22.92 19.24 -3.68 -0.167 0.62771E+04 77 epidote-Fe 29.94 27.09 -2.85 -0.148 0.48653E+04 78 fayalite 14.08 9.55 -4.53 -0.647 0.77308E+04 79 ferrosilite 11.19 6.24 -4.95 -0.495 0.84495E+04 83 gibbsite 4.10 2.38 -1.72 -0.246 0.29365E+04 84 glaucophane 23.11 18.52 -4.59 -0.124 0.78415E+04 87 greenalite 16.19 12.67 -3.52 -0.294 0.60159E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.89 -1.36 -0.136 0.23174E+04 97 kalsilite 7.62 4.19 -3.43 -0.490 0.58526E+04 98 kaolinite -1.27 -1.87 -0.60 -0.054 0.10178E+04 99 kyanite 4.93 1.44 -3.49 -0.349 0.59569E+04 101 laumontite 2.97 2.53 -0.44 -0.030 0.75779E+03 102 lawsonite 9.68 9.16 -0.52 -0.035 0.89342E+03 103 leucite 4.17 0.88 -3.29 -0.329 0.56129E+04 105 lizardite 23.29 19.36 -3.93 -0.328 0.67144E+04 107 magnetite 20.13 19.03 -1.10 -0.090 0.18840E+04 108 minnesotaite 10.46 6.05 -4.41 -0.260 0.75371E+04 110 magnesioferrite 26.26 21.26 -5.00 -0.408 0.85371E+04 113 margarite 17.45 13.91 -3.54 -0.142 0.60471E+04 120 muscovite 2.68 2.32 -0.36 -0.021 0.60760E+03 122 nepheline 8.38 6.21 -2.17 -0.310 0.37090E+04 134 phlogopite-Na 29.73 25.56 -4.17 -0.232 0.71209E+04 136 prehnite 19.47 16.87 -2.60 -0.153 0.44377E+04 137 prehnite-Fe 22.59 20.79 -1.80 -0.108 0.30704E+04 138 pumpellyite-Fe 46.47 42.54 -3.93 -0.087 0.67045E+04 139 pumpellyite-Mg 49.19 44.77 -4.42 -0.098 0.75504E+04 145 pyroxmangite 7.42 5.25 -2.17 -0.434 0.37062E+04 146 pyrophyllite -6.10 -8.49 -2.40 -0.150 0.40905E+04 147 quartz -2.98 -3.31 -0.33 -0.110 0.56381E+03 152 rhodonite 7.46 5.25 -2.22 -0.443 0.37854E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.44 -3.88 -0.388 0.66223E+04 164 stilpnomelane-Fe 13.18 12.98 -0.20 -0.006 0.34029E+03 165 stilpnomelane-Mg 27.60 24.12 -3.48 -0.104 0.59351E+04 168 sudoite 21.22 16.89 -4.32 -0.139 0.73811E+04 171 talc 16.55 12.73 -3.82 -0.225 0.65271E+04 174 tephroite 18.11 13.80 -4.31 -0.616 0.73588E+04 177 topaz-H 4.67 1.44 -3.22 -0.293 0.55059E+04 178 tridymite -2.61 -3.31 -0.70 -0.233 0.11911E+04 187 wairakite 4.06 2.53 -1.53 -0.090 0.26086E+04 188 walstromite 11.53 7.71 -3.82 -0.763 0.65152E+04 189 wollastonite 10.48 7.71 -2.77 -0.554 0.47291E+04 190 pseudo-wollastonite 11.02 7.71 -3.31 -0.662 0.56477E+04 191 zoisite 22.96 19.24 -3.72 -0.169 0.63496E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.80 -3.24 -0.200 0.55276E+04 194 beidellite-H -2.24 -6.62 -4.37 -0.279 0.74701E+04 195 beidellite-K -1.44 -4.92 -3.49 -0.214 0.59574E+04 196 beidellite-Mg -1.71 -5.19 -3.48 -0.215 0.59425E+04 197 beidellite-Na -1.26 -4.26 -3.00 -0.184 0.51269E+04 199 chalcedony -2.79 -3.31 -0.52 -0.173 0.88412E+03 201 montmorillonite-Ca -2.21 -4.60 -2.39 -0.148 0.40765E+04 202 montmorillonite-K -2.16 -4.73 -2.57 -0.157 0.43840E+04 203 montmorillonite-Mg -2.40 -4.99 -2.59 -0.160 0.44224E+04 204 montmorillonite-Na -1.96 -4.06 -2.10 -0.129 0.35917E+04 205 nontronite-Ca 3.28 3.05 -0.23 -0.015 0.39986E+03 206 nontronite-H 2.60 1.23 -1.37 -0.092 0.23380E+04 207 nontronite-K 3.40 2.92 -0.49 -0.031 0.82878E+03 208 nontronite-Mg 3.14 2.66 -0.48 -0.031 0.82630E+03 224 tobermorite 9.84 5.87 -3.97 -1.083 0.67751E+04 233 boehmite 4.43 2.38 -2.05 -0.342 0.35038E+04 235 ferrous-oxide 9.82 6.43 -3.39 -0.848 0.57925E+04 240 silica-amorphous -2.08 -3.31 -1.23 -0.411 0.21043E+04 242 an20ab80 2.08 1.50 -0.58 -0.045 0.99545E+03 243 an25ab75 2.71 1.97 -0.73 -0.056 0.12537E+04 244 an30ab70 3.34 2.45 -0.89 -0.068 0.15204E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 3.6990000 g New total amount of reactant added: 3.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4562E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3.7990000 Water: Moles liquid = 0.5547E+02 kg liquid = 0.9993E+00 Moles total = 0.5546E+02 kg total = 0.9991E+00 Activity = 1.0000 Stoichiometric ionic strength = .2710863E-02 Osmotic coef. = 0.9712 True ionic strength = .4574864E-02 Chg. balance for total moles = 0.4562E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.30876E-09 -9.5104 0.27912E-09 -9.5542 0.90400E+00 -0.0438 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12445E-03 -3.9050 0.90244E+00 -0.0446 4 SO4-- 0.25510E-04 -4.5933 0.17917E-04 -4.7467 0.70235E+00 -0.1534 5 HCO3- 0.91679E-05 -5.0377 0.82769E-05 -5.0821 0.90282E+00 -0.0444 6 HS- 0.68090E-13 -13.1669 0.61450E-13 -13.2115 0.90248E+00 -0.0446 7 Al+++ 0.11124E-25 -25.9537 0.51177E-26 -26.2909 0.46005E+00 -0.3372 8 H4SiO4 0.48569E-03 -3.3136 0.48569E-03 -3.3136 0.10000E+01 0.0000 9 Ca++ 0.12363E-07 -7.9079 0.86653E-08 -8.0622 0.70089E+00 -0.1543 10 Mg++ 0.51231E-10 -10.2905 0.35860E-10 -10.4454 0.69998E+00 -0.1549 11 Fe++ 0.30293E-12 -12.5187 0.21211E-12 -12.6734 0.70019E+00 -0.1548 12 K+ 0.42420E-04 -4.3724 0.38300E-04 -4.4168 0.90288E+00 -0.0444 13 Na+ 0.44957E-02 -2.3472 0.40570E-02 -2.3918 0.90241E+00 -0.0446 14 Mn++ 0.40471E-10 -10.3929 0.28344E-10 -10.5475 0.70036E+00 -0.1547 15 HPO4-- 0.71657E-05 -5.1447 0.50330E-05 -5.2982 0.70238E+00 -0.1534 16 HSiO3- 0.18813E-02 -2.7255 0.16977E-02 -2.7701 0.90244E+00 -0.0446 17 Ca(HSiO3)+ 0.36504E-09 -9.4377 0.32961E-09 -9.4820 0.90294E+00 -0.0443 18 Mg(HSiO3)+ 0.18801E-11 -11.7258 0.16976E-11 -11.7702 0.90294E+00 -0.0443 19 NaHSiO3,aq 0.10939E-03 -3.9610 0.10939E-03 -3.9610 0.10000E+01 0.0000 20 AlO+ 0.93919E-14 -14.0272 0.84803E-14 -14.0716 0.90294E+00 -0.0443 21 AlOH+2 0.16926E-19 -19.7715 0.11857E-19 -19.9260 0.70055E+00 -0.1546 22 HAlO2,aq 0.60799E-08 -8.2161 0.60799E-08 -8.2161 0.10000E+01 0.0000 23 AlO2- 0.53923E-04 -4.2682 0.48637E-04 -4.3130 0.90198E+00 -0.0448 24 CH4,aq 0.27879E-19 -19.5547 0.27855E-19 -19.5551 0.99916E+00 -0.0004 29 CO,aq 0.84584E-19 -19.0727 0.84584E-19 -19.0727 0.10000E+01 0.0000 30 CO2,aq 0.46618E-08 -8.3314 0.46579E-08 -8.3318 0.99916E+00 -0.0004 31 CO3-2 0.39061E-05 -5.4083 0.27418E-05 -5.5620 0.70192E+00 -0.1537 32 CaCO3,aq 0.29098E-09 -9.5361 0.29098E-09 -9.5361 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.20014E-11 -11.6987 0.18072E-11 -11.7430 0.90294E+00 -0.0443 34 CaCl+ 0.19031E-11 -11.7205 0.17184E-11 -11.7649 0.90294E+00 -0.0443 35 CaCl2,aq 0.49794E-16 -16.3028 0.49794E-16 -16.3028 0.10000E+01 0.0000 36 CaOH+ 0.24244E-08 -8.6154 0.21891E-08 -8.6597 0.90294E+00 -0.0443 37 CaSO4,aq 0.48374E-10 -10.3154 0.48374E-10 -10.3154 0.10000E+01 0.0000 38 HCl,aq 0.65338E-14 -14.1848 0.65338E-14 -14.1848 0.10000E+01 0.0000 43 FeCl+ 0.45534E-16 -16.3417 0.41114E-16 -16.3860 0.90294E+00 -0.0443 46 FeO,aq 0.10766E-09 -9.9679 0.10766E-09 -9.9679 0.10000E+01 0.0000 47 FeOH+ 0.27902E-10 -10.5544 0.25194E-10 -10.5987 0.90294E+00 -0.0443 48 HFeO2- 0.45974E-08 -8.3375 0.41489E-08 -8.3821 0.90244E+00 -0.0446 49 FeO+ 0.25571E-14 -14.5923 0.23089E-14 -14.6366 0.90294E+00 -0.0443 51 FeO2- 0.64545E-08 -8.1901 0.58248E-08 -8.2347 0.90244E+00 -0.0446 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.70566E-09 -9.1514 0.70507E-09 -9.1518 0.99916E+00 -0.0004 54 KCl,aq 0.84398E-10 -10.0737 0.84398E-10 -10.0737 0.10000E+01 0.0000 55 KHSO4,aq 0.51255E-18 -18.2903 0.51255E-18 -18.2903 0.10000E+01 0.0000 56 KOH,aq 0.59820E-07 -7.2232 0.59820E-07 -7.2232 0.10000E+01 0.0000 57 KSO4- 0.11715E-07 -7.9312 0.10572E-07 -7.9758 0.90244E+00 -0.0446 58 MgCO3,aq 0.30090E-12 -12.5216 0.30090E-12 -12.5216 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.84461E-14 -14.0733 0.76264E-14 -14.1177 0.90294E+00 -0.0443 60 MgCl+ 0.71499E-14 -14.1457 0.64559E-14 -14.1900 0.90294E+00 -0.0443 61 MgOH+ 0.55584E-10 -10.2551 0.50189E-10 -10.2994 0.90294E+00 -0.0443 63 MnO,aq 0.38406E-09 -9.4156 0.38406E-09 -9.4156 0.10000E+01 0.0000 64 MnOH+ 0.34636E-09 -9.4605 0.31274E-09 -9.5048 0.90294E+00 -0.0443 65 MnO2-2 0.24289E-12 -12.6146 0.17049E-12 -12.7683 0.70192E+00 -0.1537 66 HMnO2- 0.11425E-10 -10.9422 0.10310E-10 -10.9867 0.90244E+00 -0.0446 69 MnCl+ 0.23644E-13 -13.6263 0.21349E-13 -13.6706 0.90294E+00 -0.0443 70 MnSO4,aq 0.14392E-12 -12.8419 0.14392E-12 -12.8419 0.10000E+01 0.0000 71 NaCl,aq 0.16486E-06 -6.7829 0.16486E-06 -6.7829 0.10000E+01 0.0000 72 NaOH,aq 0.63867E-05 -5.1947 0.63867E-05 -5.1947 0.10000E+01 0.0000 74 OH- 0.23826E-02 -2.6230 0.21490E-02 -2.6678 0.90198E+00 -0.0448 79 HPO3-2 0.15968E-16 -16.7967 0.11208E-16 -16.9505 0.70192E+00 -0.1537 82 H3PO4,aq 0.25244E-14 -14.5978 0.25244E-14 -14.5978 0.10000E+01 0.0000 83 H2PO4- 0.27284E-07 -7.5641 0.24629E-07 -7.6086 0.90269E+00 -0.0445 84 PO4-3 0.33752E-07 -7.4717 0.15747E-07 -7.8028 0.46656E+00 -0.3311 87 H2P2O7-2 0.67636E-16 -16.1698 0.47475E-16 -16.3235 0.70192E+00 -0.1537 88 HP2O7-3 0.75797E-13 -13.1203 0.34877E-13 -13.4575 0.46014E+00 -0.3371 89 P2O7-4 0.11993E-12 -12.9211 0.30826E-13 -13.5111 0.25702E+00 -0.5900 90 H2S,aq 0.51577E-16 -16.2875 0.51533E-16 -16.2879 0.99916E+00 -0.0004 97 SO3-2 0.24438E-14 -14.6119 0.17225E-14 -14.7639 0.70483E+00 -0.1519 98 HSO3- 0.31177E-16 -16.5062 0.28136E-16 -16.5507 0.90244E+00 -0.0446 99 HSO4- 0.51376E-11 -11.2892 0.46402E-11 -11.3335 0.90318E+00 -0.0442 Charge balance for all species = 0.5429E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3087583E-09 -.4599354E-02 -.4634213E+01 0.0000 2 H2O 0.1000000E+01 0.5550876E+02 0.9996488E+06 0.0000 3 Cl- 0.1379038E-03 0.1380688E-03 0.4893199E+01 5.6492 4 SO4-- 0.2551019E-04 0.2552261E-04 0.2450865E+01 14.3617 5 HCO3- 0.9167893E-05 0.1307896E-04 0.7977558E+00 4.4721 6 HS- 0.6808958E-13 -.6557621E-09 -.2167960E-04 -3.6573 7 Al+++ 0.1112433E-25 0.5392932E-04 0.1454573E+01 2.3717 8 H4SiO4 0.4856899E-03 0.2476357E-02 0.2379308E+03 -3.3136 9 Ca++ 0.1236319E-07 0.1549589E-07 0.6208217E-03 11.0462 10 Mg++ 0.5123052E-10 0.1090108E-09 0.2649322E-05 8.6630 11 Fe++ 0.3029307E-12 0.1139120E-07 0.6359368E-03 6.4350 12 K+ 0.4242017E-04 0.4249179E-04 0.1660919E+01 5.1374 13 Na+ 0.4495720E-02 0.4611664E-02 0.1059833E+03 7.1624 14 Mn++ 0.4047063E-10 0.7827279E-09 0.4298610E-04 8.5609 15 HPO4-- 0.7165662E-05 0.7226698E-05 0.6933628E+00 13.8102 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6289276E-01 -.4596203E-02 -.5829656E-01 0.0000000E+00 2 H2O 0.5546063E+02 0.5547072E+02 -.1009584E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1307877E-03 0.2550513E-04 0.1052826E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1052832E-03 -.6553128E-09 -.1052826E-03 0.0000000E+00 7 Al+++ 0.1238756E-01 0.5389237E-04 0.1233367E-01 0.0000000E+00 8 H4SiO4 0.3955816E-01 0.2474660E-02 0.3708350E-01 0.0000000E+00 9 Ca++ 0.4383863E-02 0.1548527E-07 0.4383848E-02 0.0000000E+00 10 Mg++ 0.3015079E-02 0.1089361E-09 0.3015079E-02 0.0000000E+00 11 Fe++ 0.2708720E-02 0.1138340E-07 0.2708708E-02 0.0000000E+00 12 K+ 0.8065817E-03 0.4246268E-04 0.7641191E-03 0.0000000E+00 13 Na+ 0.4928742E-02 0.4608505E-02 0.3202370E-03 0.0000000E+00 14 Mn++ 0.6586933E-04 0.7821916E-09 0.6586854E-04 0.0000000E+00 15 HPO4-- 0.2248087E-04 0.7221746E-05 0.1525913E-04 0.0000000E+00 Chg. balance for solid moles: -.7007E-17 Mass of aqueous solution: 0.999673E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5086E-05 -5.294 0.2555E-02 -2.593 0.6223E-01 0.8119E-03 clinochlore 0.6030E-03 -3.220 0.3352 -0.475 8.164 0.1275 daphnite 0.3733E-03 -3.428 0.2663 -0.575 6.487 0.8071E-01 chlorite-Mn 0.1317E-04 -4.880 0.9340E-02 -2.030 0.2275 0.2976E-02 hematite 0.2894E-03 -3.539 0.4621E-01 -1.335 1.126 0.8759E-02 microcline 0.7641E-03 -3.117 0.2127 -0.672 5.180 0.8308E-01 paragonite 0.2768E-03 -3.558 0.1058 -0.976 2.576 0.3656E-01 stilbite 0.4358E-02 -2.361 3.071 0.487 74.81 1.433 nontronite-Na 0.1317E-03 -3.880 0.5603E-01 -1.252 1.365 0.1741E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4.105582 g Volume = 1.790383 cm3 Porosity: 28.9418% V(tot) - V(min): 0.72922E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.7990000 g log = 0.5797 Original solution: 1000.0103000 g Original solution / Rock added: 263.23 (Water/Rock Ratio), log = 2.4203 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.5032E-06 1.0073 0.5332E-06 0.5293E-06 CH4,gas 0.4134E-16 1.0129 0.4405E-16 0.4349E-16 H2,gas 0.9188E-06 1.0006 0.9671E-06 0.9665E-06 H2S,gas 0.1435E-14 0.9959 0.1503E-14 0.1509E-14 S2,gas 0.8601E-37 1.0000 0.9048E-37 0.9048E-37 CO,gas 0.1270E-15 1.0000 0.1336E-15 0.1336E-15 SO3,gas 0.4961E-39 1.0000 0.5218E-39 0.5218E-39 SO2,gas 0.1815E-22 1.0000 0.1909E-22 0.1909E-22 HCl,gas 0.1097E-16 1.0000 0.1154E-16 0.1154E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.24265E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.60662E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.60662E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 0.26539E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.64 -8.27 -2.758 0.14126E+05 -6.273 3 CH4,gas 4.81 -13.55 -18.36 -4.589 0.31342E+05 -16.356 4 H2,gas 8.29 0.27 -8.01 -4.580 0.13685E+05 -6.015 5 H2S,gas -5.94 -22.77 -16.82 -8.412 0.28725E+05 -14.823 6 S2,gas -7.03 -46.08 -39.04 -6.007 0.66666E+05 -37.043 7 CO,gas 3.51 -14.36 -17.87 -5.500 0.30520E+05 -15.874 8 SO3,gas 17.43 -23.86 -41.28 -10.321 0.70489E+05 -39.282 9 SO2,gas 1.14 -23.58 -24.72 -6.592 0.42207E+05 -22.719 10 HCl,gas 5.48 -13.46 -18.94 -9.469 0.32336E+05 -16.938 11 acmite 7.74 6.83 -0.90 -0.094 0.15426E+04 15 albite-high 0.75 -0.41 -1.16 -0.089 0.19746E+04 16 albite -0.33 -0.41 -0.08 -0.006 0.13393E+03 19 spessartine 24.55 20.49 -4.06 -0.203 0.69404E+04 20 analcite 3.37 2.91 -0.46 -0.052 0.79192E+03 21 andalusite 5.06 1.43 -3.63 -0.363 0.62025E+04 22 andradite 39.09 35.80 -3.29 -0.171 0.56217E+04 23 grossular 32.83 27.94 -4.89 -0.244 0.83446E+04 26 annite 20.21 16.87 -3.34 -0.185 0.56964E+04 27 phlogopite 27.15 23.56 -3.59 -0.199 0.61286E+04 29 anorthite 12.80 9.16 -3.64 -0.280 0.62072E+04 35 aragonite 0.99 -3.59 -4.58 -1.525 0.78140E+04 36 brucite 12.58 8.66 -3.91 -0.783 0.66823E+04 37 calcite 0.83 -3.59 -4.42 -1.474 0.75527E+04 38 carnegieite-low 9.06 6.22 -2.84 -0.406 0.48562E+04 39 carnegieite-high 10.13 6.22 -3.91 -0.559 0.66830E+04 40 carpholite-Mg 8.65 6.78 -1.87 -0.125 0.31950E+04 41 carpholite-Fe 6.78 4.55 -2.23 -0.149 0.38107E+04 42 celadonite 5.40 2.92 -2.48 -0.146 0.42395E+04 43 celadonite-Fe 3.94 0.69 -3.25 -0.191 0.55448E+04 44 chrysotile 23.94 19.36 -4.58 -0.381 0.78126E+04 50 chloritoid-Mg 13.26 10.09 -3.17 -0.211 0.54100E+04 51 chloritoid-Fe 9.24 7.86 -1.37 -0.092 0.23459E+04 52 chloritoid-Mn 11.46 9.99 -1.47 -0.098 0.25143E+04 54 coesite -2.37 -3.31 -0.94 -0.315 0.16124E+04 59 corundum 8.43 4.74 -3.69 -0.335 0.63006E+04 61 cristobalite -2.55 -3.31 -0.76 -0.255 0.13052E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.37 -0.52 -0.087 0.89536E+03 67 diopside 16.22 13.08 -3.13 -0.313 0.53504E+04 68 hedenbergite 14.24 10.85 -3.39 -0.339 0.57892E+04 75 epidote 24.78 23.19 -1.58 -0.077 0.27003E+04 76 clinozoisite 22.92 19.27 -3.65 -0.166 0.62400E+04 77 epidote-Fe 29.94 27.12 -2.82 -0.146 0.48082E+04 78 fayalite 14.08 9.56 -4.52 -0.646 0.77223E+04 79 ferrosilite 11.19 6.24 -4.94 -0.494 0.84435E+04 83 gibbsite 4.10 2.37 -1.73 -0.247 0.29465E+04 84 glaucophane 23.11 18.55 -4.56 -0.123 0.77900E+04 87 greenalite 16.19 12.68 -3.52 -0.293 0.60044E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.91 -1.34 -0.134 0.22949E+04 97 kalsilite 7.62 4.20 -3.42 -0.489 0.58477E+04 98 kaolinite -1.27 -1.88 -0.61 -0.056 0.10428E+04 99 kyanite 4.93 1.43 -3.50 -0.350 0.59793E+04 101 laumontite 2.97 2.54 -0.44 -0.029 0.75039E+03 102 lawsonite 9.68 9.16 -0.52 -0.034 0.88110E+03 103 leucite 4.17 0.88 -3.29 -0.329 0.56104E+04 105 lizardite 23.29 19.36 -3.93 -0.327 0.67028E+04 107 magnetite 20.13 19.03 -1.10 -0.090 0.18785E+04 108 minnesotaite 10.46 6.05 -4.41 -0.259 0.75305E+04 110 magnesioferrite 26.26 21.26 -5.00 -0.408 0.85316E+04 113 margarite 17.45 13.91 -3.55 -0.142 0.60547E+04 120 muscovite 2.68 2.31 -0.37 -0.022 0.62761E+03 122 nepheline 8.38 6.22 -2.16 -0.308 0.36841E+04 134 phlogopite-Na 29.73 25.58 -4.15 -0.231 0.70844E+04 136 prehnite 19.47 16.89 -2.57 -0.151 0.43906E+04 137 prehnite-Fe 22.59 20.82 -1.76 -0.106 0.30133E+04 138 pumpellyite-Fe 46.47 42.60 -3.87 -0.086 0.66148E+04 139 pumpellyite-Mg 49.19 44.82 -4.37 -0.097 0.74608E+04 145 pyroxmangite 7.42 5.25 -2.17 -0.434 0.37031E+04 146 pyrophyllite -6.10 -8.51 -2.41 -0.151 0.41203E+04 147 quartz -2.98 -3.31 -0.33 -0.111 0.56627E+03 152 rhodonite 7.46 5.25 -2.22 -0.443 0.37824E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.43 -3.89 -0.389 0.66447E+04 164 stilpnomelane-Fe 13.18 12.98 -0.20 -0.006 0.34392E+03 165 stilpnomelane-Mg 27.60 24.12 -3.48 -0.104 0.59387E+04 168 sudoite 21.22 16.87 -4.34 -0.140 0.74176E+04 171 talc 16.55 12.73 -3.82 -0.225 0.65205E+04 174 tephroite 18.11 13.81 -4.30 -0.615 0.73503E+04 177 topaz-H 4.67 1.43 -3.24 -0.294 0.55284E+04 178 tridymite -2.61 -3.31 -0.70 -0.233 0.11936E+04 187 wairakite 4.06 2.54 -1.52 -0.090 0.26012E+04 188 walstromite 11.53 7.73 -3.80 -0.759 0.64804E+04 189 wollastonite 10.48 7.73 -2.75 -0.550 0.46943E+04 190 pseudo-wollastonite 11.02 7.73 -3.29 -0.657 0.56129E+04 191 zoisite 22.96 19.27 -3.70 -0.168 0.63125E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.81 -3.25 -0.201 0.55539E+04 194 beidellite-H -2.24 -6.63 -4.39 -0.280 0.75024E+04 195 beidellite-K -1.44 -4.94 -3.50 -0.215 0.59840E+04 196 beidellite-Mg -1.71 -5.21 -3.50 -0.216 0.59739E+04 197 beidellite-Na -1.26 -4.27 -3.01 -0.185 0.51469E+04 199 chalcedony -2.79 -3.31 -0.52 -0.173 0.88659E+03 201 montmorillonite-Ca -2.21 -4.61 -2.40 -0.148 0.40951E+04 202 montmorillonite-K -2.16 -4.74 -2.58 -0.158 0.44030E+04 203 montmorillonite-Mg -2.40 -5.01 -2.60 -0.161 0.44462E+04 204 montmorillonite-Na -1.96 -4.07 -2.11 -0.129 0.36041E+04 205 nontronite-Ca 3.28 3.04 -0.24 -0.015 0.40605E+03 206 nontronite-H 2.60 1.22 -1.38 -0.092 0.23504E+04 207 nontronite-K 3.40 2.91 -0.49 -0.031 0.83538E+03 208 nontronite-Mg 3.14 2.65 -0.49 -0.032 0.83773E+03 224 tobermorite 9.84 5.89 -3.95 -1.078 0.67465E+04 233 boehmite 4.43 2.37 -2.06 -0.343 0.35138E+04 235 ferrous-oxide 9.82 6.43 -3.39 -0.847 0.57870E+04 240 silica-amorphous -2.08 -3.31 -1.23 -0.411 0.21068E+04 242 an20ab80 2.08 1.51 -0.57 -0.044 0.97698E+03 243 an25ab75 2.71 1.99 -0.72 -0.056 0.12356E+04 244 an30ab70 3.34 2.46 -0.88 -0.068 0.15027E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 3.7990000 g New total amount of reactant added: 3.8990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4561E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3.8990000 Water: Moles liquid = 0.5547E+02 kg liquid = 0.9993E+00 Moles total = 0.5546E+02 kg total = 0.9991E+00 Activity = 1.0000 Stoichiometric ionic strength = .2771545E-02 Osmotic coef. = 0.9709 True ionic strength = .4684731E-02 Chg. balance for total moles = 0.4561E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.30114E-09 -9.5212 0.27199E-09 -9.5654 0.90320E+00 -0.0442 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12433E-03 -3.9054 0.90161E+00 -0.0450 4 SO4-- 0.25511E-04 -4.5933 0.17853E-04 -4.7483 0.69981E+00 -0.1550 5 HCO3- 0.90894E-05 -5.0415 0.81986E-05 -5.0863 0.90199E+00 -0.0448 6 HS- 0.70096E-13 -13.1543 0.63202E-13 -13.1993 0.90165E+00 -0.0450 7 Al+++ 0.10243E-25 -25.9896 0.46739E-26 -26.3303 0.45628E+00 -0.3408 8 H4SiO4 0.48412E-03 -3.3150 0.48412E-03 -3.3150 0.10000E+01 0.0000 9 Ca++ 0.12374E-07 -7.9075 0.86411E-08 -8.0634 0.69833E+00 -0.1559 10 Mg++ 0.49181E-10 -10.3082 0.34299E-10 -10.4647 0.69740E+00 -0.1565 11 Fe++ 0.29081E-12 -12.5364 0.20287E-12 -12.6928 0.69762E+00 -0.1564 12 K+ 0.42331E-04 -4.3733 0.38185E-04 -4.4181 0.90206E+00 -0.0448 13 Na+ 0.46058E-02 -2.3367 0.41524E-02 -2.3817 0.90157E+00 -0.0450 14 Mn++ 0.38851E-10 -10.4106 0.27110E-10 -10.5669 0.69779E+00 -0.1563 15 HPO4-- 0.69803E-05 -5.1561 0.48851E-05 -5.3111 0.69984E+00 -0.1550 16 HSiO3- 0.19261E-02 -2.7153 0.17366E-02 -2.7603 0.90161E+00 -0.0450 17 Ca(HSiO3)+ 0.37269E-09 -9.4286 0.33621E-09 -9.4734 0.90212E+00 -0.0447 18 Mg(HSiO3)+ 0.18410E-11 -11.7349 0.16608E-11 -11.7797 0.90212E+00 -0.0447 19 NaHSiO3,aq 0.11453E-03 -3.9411 0.11453E-03 -3.9411 0.10000E+01 0.0000 20 AlO+ 0.90409E-14 -14.0438 0.81560E-14 -14.0885 0.90212E+00 -0.0447 21 AlOH+2 0.15921E-19 -19.7980 0.11113E-19 -19.9542 0.69799E+00 -0.1562 22 HAlO2,aq 0.60005E-08 -8.2218 0.60005E-08 -8.2218 0.10000E+01 0.0000 23 AlO2- 0.54665E-04 -4.2623 0.49260E-04 -4.3075 0.90113E+00 -0.0452 24 CH4,aq 0.28505E-19 -19.5451 0.28481E-19 -19.5454 0.99914E+00 -0.0004 29 CO,aq 0.82829E-19 -19.0818 0.82829E-19 -19.0818 0.10000E+01 0.0000 30 CO2,aq 0.44999E-08 -8.3468 0.44961E-08 -8.3472 0.99914E+00 -0.0004 31 CO3-2 0.39849E-05 -5.3996 0.27870E-05 -5.5549 0.69938E+00 -0.1553 32 CaCO3,aq 0.29495E-09 -9.5302 0.29495E-09 -9.5302 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.19788E-11 -11.7036 0.17851E-11 -11.7483 0.90212E+00 -0.0447 34 CaCl+ 0.18978E-11 -11.7218 0.17120E-11 -11.7665 0.90212E+00 -0.0447 35 CaCl2,aq 0.49562E-16 -16.3048 0.49562E-16 -16.3048 0.10000E+01 0.0000 36 CaOH+ 0.24832E-08 -8.6050 0.22402E-08 -8.6497 0.90212E+00 -0.0447 37 CaSO4,aq 0.48066E-10 -10.3182 0.48066E-10 -10.3182 0.10000E+01 0.0000 38 HCl,aq 0.63611E-14 -14.1965 0.63611E-14 -14.1965 0.10000E+01 0.0000 43 FeCl+ 0.43550E-16 -16.3610 0.39287E-16 -16.4058 0.90212E+00 -0.0447 46 FeO,aq 0.10844E-09 -9.9648 0.10844E-09 -9.9648 0.10000E+01 0.0000 47 FeOH+ 0.27411E-10 -10.5621 0.24728E-10 -10.6068 0.90212E+00 -0.0447 48 HFeO2- 0.47563E-08 -8.3227 0.42883E-08 -8.3677 0.90161E+00 -0.0450 49 FeO+ 0.24941E-14 -14.6031 0.22500E-14 -14.6478 0.90212E+00 -0.0447 51 FeO2- 0.66297E-08 -8.1785 0.59774E-08 -8.2235 0.90161E+00 -0.0450 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.71590E-09 -9.1451 0.71529E-09 -9.1455 0.99914E+00 -0.0004 54 KCl,aq 0.84066E-10 -10.0754 0.84066E-10 -10.0754 0.10000E+01 0.0000 55 KHSO4,aq 0.49618E-18 -18.3044 0.49618E-18 -18.3044 0.10000E+01 0.0000 56 KOH,aq 0.61203E-07 -7.2132 0.61203E-07 -7.2132 0.10000E+01 0.0000 57 KSO4- 0.11649E-07 -7.9337 0.10503E-07 -7.9787 0.90161E+00 -0.0450 58 MgCO3,aq 0.29254E-12 -12.5338 0.29254E-12 -12.5338 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.80092E-14 -14.0964 0.72252E-14 -14.1411 0.90212E+00 -0.0447 60 MgCl+ 0.68384E-14 -14.1650 0.61690E-14 -14.2098 0.90212E+00 -0.0447 61 MgOH+ 0.54606E-10 -10.2628 0.49261E-10 -10.3075 0.90212E+00 -0.0447 63 MnO,aq 0.38683E-09 -9.4125 0.38683E-09 -9.4125 0.10000E+01 0.0000 64 MnOH+ 0.34027E-09 -9.4682 0.30696E-09 -9.5129 0.90212E+00 -0.0447 65 MnO2-2 0.25856E-12 -12.5874 0.18083E-12 -12.7427 0.69938E+00 -0.1553 66 HMnO2- 0.11820E-10 -10.9274 0.10657E-10 -10.9724 0.90161E+00 -0.0450 69 MnCl+ 0.22614E-13 -13.6456 0.20400E-13 -13.6904 0.90212E+00 -0.0447 70 MnSO4,aq 0.13716E-12 -12.8628 0.13716E-12 -12.8628 0.10000E+01 0.0000 71 NaCl,aq 0.16858E-06 -6.7732 0.16858E-06 -6.7732 0.10000E+01 0.0000 72 NaOH,aq 0.67083E-05 -5.1734 0.67083E-05 -5.1734 0.10000E+01 0.0000 74 OH- 0.24473E-02 -2.6113 0.22053E-02 -2.6565 0.90113E+00 -0.0452 79 HPO3-2 0.15781E-16 -16.8019 0.11037E-16 -16.9572 0.69938E+00 -0.1553 82 H3PO4,aq 0.23267E-14 -14.6333 0.23267E-14 -14.6333 0.10000E+01 0.0000 83 H2PO4- 0.25830E-07 -7.5879 0.23295E-07 -7.6327 0.90186E+00 -0.0449 84 PO4-3 0.33885E-07 -7.4700 0.15685E-07 -7.8045 0.46289E+00 -0.3345 87 H2P2O7-2 0.60727E-16 -16.2166 0.42471E-16 -16.3719 0.69938E+00 -0.1553 88 HP2O7-3 0.70159E-13 -13.1539 0.32019E-13 -13.4946 0.45637E+00 -0.3407 89 P2O7-4 0.11463E-12 -12.9407 0.29041E-13 -13.5370 0.25334E+00 -0.5963 90 H2S,aq 0.51694E-16 -16.2866 0.51650E-16 -16.2869 0.99914E+00 -0.0004 97 SO3-2 0.24791E-14 -14.6057 0.17412E-14 -14.7592 0.70234E+00 -0.1535 98 HSO3- 0.30739E-16 -16.5123 0.27715E-16 -16.5573 0.90161E+00 -0.0450 99 HSO4- 0.49930E-11 -11.3016 0.45055E-11 -11.3463 0.90237E+00 -0.0446 Charge balance for all species = 0.5427E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.3011428E-09 -.4717384E-02 -.4753101E+01 0.0000 2 H2O 0.1000000E+01 0.5550877E+02 0.9996416E+06 0.0000 3 Cl- 0.1379025E-03 0.1380712E-03 0.4893248E+01 5.6600 4 SO4-- 0.2551070E-04 0.2552308E-04 0.2450891E+01 14.3826 5 HCO3- 0.9089446E-05 0.1307919E-04 0.7977638E+00 4.4792 6 HS- 0.7009595E-13 -.6750993E-09 -.2231872E-04 -3.6338 7 Al+++ 0.1024339E-25 0.5467060E-04 0.1474555E+01 2.3660 8 H4SiO4 0.4841210E-03 0.2524748E-02 0.2425784E+03 -3.3150 9 Ca++ 0.1237392E-07 0.1557673E-07 0.6240561E-03 11.0675 10 Mg++ 0.4918068E-10 0.1059348E-09 0.2574545E-05 8.6662 11 Fe++ 0.2908079E-12 0.1172558E-07 0.6545990E-03 6.4381 12 K+ 0.4233109E-04 0.4240402E-04 0.1657476E+01 5.1473 13 Na+ 0.4605781E-02 0.4727188E-02 0.1086374E+03 7.1837 14 Mn++ 0.3885088E-10 0.7781907E-09 0.4273661E-04 8.5640 15 HPO4-- 0.6980288E-05 0.7040004E-05 0.6754455E+00 13.8198 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6454861E-01 -.4714069E-02 -.5983454E-01 0.0000000E+00 2 H2O 0.5545937E+02 0.5546977E+02 -.1039519E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1335591E-03 0.2550514E-04 0.1080539E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1080546E-03 -.6746249E-09 -.1080539E-03 0.0000000E+00 7 Al+++ 0.1271363E-01 0.5463218E-04 0.1265900E-01 0.0000000E+00 8 H4SiO4 0.4059944E-01 0.2522974E-02 0.3807647E-01 0.0000000E+00 9 Ca++ 0.4498877E-02 0.1556579E-07 0.4498862E-02 0.0000000E+00 10 Mg++ 0.3094444E-02 0.1058604E-09 0.3094444E-02 0.0000000E+00 11 Fe++ 0.2780021E-02 0.1171734E-07 0.2780009E-02 0.0000000E+00 12 K+ 0.8278132E-03 0.4237423E-04 0.7854389E-03 0.0000000E+00 13 Na+ 0.5054266E-02 0.4723866E-02 0.3303999E-03 0.0000000E+00 14 Mn++ 0.6760319E-04 0.7776439E-09 0.6760241E-04 0.0000000E+00 15 HPO4-- 0.2307263E-04 0.7035057E-05 0.1603757E-04 0.0000000E+00 Chg. balance for solid moles: -.3984E-17 Mass of aqueous solution: 0.999663E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3.8990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5346E-05 -5.272 0.2685E-02 -2.571 0.6371E-01 0.8533E-03 clinochlore 0.6189E-03 -3.208 0.3440 -0.463 8.162 0.1308 daphnite 0.3831E-03 -3.417 0.2734 -0.563 6.486 0.8284E-01 chlorite-Mn 0.1352E-04 -4.869 0.9586E-02 -2.018 0.2274 0.3055E-02 hematite 0.2914E-03 -3.536 0.4653E-01 -1.332 1.104 0.8820E-02 microcline 0.7854E-03 -3.105 0.2186 -0.660 5.187 0.8540E-01 paragonite 0.2839E-03 -3.547 0.1085 -0.965 2.575 0.3751E-01 stilbite 0.4472E-02 -2.349 3.152 0.499 74.77 1.470 nontronite-Na 0.1408E-03 -3.851 0.5989E-01 -1.223 1.421 0.1861E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4.214786 g Volume = 1.837887 cm3 Porosity: 28.1963% V(tot) - V(min): 0.72171E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.8990000 g log = 0.5910 Original solution: 1000.0103000 g Original solution / Rock added: 256.48 (Water/Rock Ratio), log = 2.4091 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.4857E-06 1.0073 0.5147E-06 0.5109E-06 CH4,gas 0.4227E-16 1.0129 0.4504E-16 0.4446E-16 H2,gas 0.9321E-06 1.0006 0.9811E-06 0.9805E-06 H2S,gas 0.1438E-14 0.9959 0.1506E-14 0.1513E-14 S2,gas 0.8395E-37 1.0000 0.8831E-37 0.8831E-37 CO,gas 0.1243E-15 1.0000 0.1308E-15 0.1308E-15 SO3,gas 0.4694E-39 1.0000 0.4938E-39 0.4938E-39 SO2,gas 0.1742E-22 1.0000 0.1833E-22 0.1833E-22 HCl,gas 0.1068E-16 1.0000 0.1123E-16 0.1123E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 0.15165E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.65 -8.29 -2.763 0.14152E+05 -6.288 3 CH4,gas 4.81 -13.54 -18.35 -4.587 0.31326E+05 -16.346 4 H2,gas 8.29 0.28 -8.01 -4.576 0.13674E+05 -6.008 5 H2S,gas -5.94 -22.76 -16.82 -8.411 0.28723E+05 -14.822 6 S2,gas -7.03 -46.09 -39.05 -6.008 0.66684E+05 -37.054 7 CO,gas 3.51 -14.37 -17.88 -5.503 0.30535E+05 -15.883 8 SO3,gas 17.43 -23.88 -41.31 -10.327 0.70530E+05 -39.306 9 SO2,gas 1.14 -23.60 -24.74 -6.597 0.42238E+05 -22.737 10 HCl,gas 5.48 -13.47 -18.95 -9.475 0.32356E+05 -16.950 11 acmite 7.74 6.85 -0.88 -0.092 0.15110E+04 15 albite-high 0.75 -0.40 -1.15 -0.088 0.19551E+04 16 albite -0.33 -0.40 -0.07 -0.005 0.11444E+03 19 spessartine 24.55 20.48 -4.07 -0.204 0.69511E+04 20 analcite 3.37 2.92 -0.45 -0.050 0.77003E+03 21 andalusite 5.06 1.42 -3.65 -0.365 0.62244E+04 22 andradite 39.09 35.85 -3.23 -0.168 0.55201E+04 23 grossular 32.83 27.99 -4.84 -0.242 0.82624E+04 26 annite 20.21 16.88 -3.33 -0.185 0.56804E+04 27 phlogopite 27.15 23.57 -3.58 -0.199 0.61126E+04 29 anorthite 12.80 9.17 -3.63 -0.279 0.61952E+04 35 aragonite 0.99 -3.58 -4.57 -1.523 0.78040E+04 36 brucite 12.58 8.67 -3.91 -0.782 0.66770E+04 37 calcite 0.83 -3.58 -4.42 -1.472 0.75426E+04 38 carnegieite-low 9.06 6.23 -2.83 -0.404 0.48319E+04 39 carnegieite-high 10.13 6.23 -3.90 -0.557 0.66587E+04 40 carpholite-Mg 8.65 6.77 -1.88 -0.125 0.32140E+04 41 carpholite-Fe 6.78 4.54 -2.24 -0.150 0.38296E+04 42 celadonite 5.40 2.92 -2.48 -0.146 0.42366E+04 43 celadonite-Fe 3.94 0.69 -3.25 -0.191 0.55419E+04 44 chrysotile 23.94 19.37 -4.57 -0.381 0.78014E+04 50 chloritoid-Mg 13.26 10.08 -3.18 -0.212 0.54265E+04 51 chloritoid-Fe 9.24 7.86 -1.38 -0.092 0.23625E+04 52 chloritoid-Mn 11.46 9.98 -1.48 -0.099 0.25309E+04 54 coesite -2.37 -3.32 -0.95 -0.315 0.16148E+04 59 corundum 8.43 4.73 -3.70 -0.336 0.63201E+04 61 cristobalite -2.55 -3.32 -0.77 -0.255 0.13076E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.37 -0.53 -0.088 0.90510E+03 67 diopside 16.22 13.10 -3.11 -0.311 0.53136E+04 68 hedenbergite 14.24 10.88 -3.37 -0.337 0.57524E+04 75 epidote 24.78 23.22 -1.55 -0.075 0.26545E+04 76 clinozoisite 22.92 19.29 -3.63 -0.165 0.62039E+04 77 epidote-Fe 29.94 27.15 -2.78 -0.145 0.47525E+04 78 fayalite 14.08 9.56 -4.52 -0.645 0.77140E+04 79 ferrosilite 11.19 6.25 -4.94 -0.494 0.84376E+04 83 gibbsite 4.10 2.37 -1.73 -0.247 0.29563E+04 84 glaucophane 23.11 18.58 -4.53 -0.123 0.77398E+04 87 greenalite 16.19 12.68 -3.51 -0.292 0.59932E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.92 -1.33 -0.133 0.22731E+04 97 kalsilite 7.62 4.20 -3.42 -0.489 0.58429E+04 98 kaolinite -1.27 -1.90 -0.62 -0.057 0.10671E+04 99 kyanite 4.93 1.42 -3.51 -0.351 0.60012E+04 101 laumontite 2.97 2.54 -0.44 -0.029 0.74320E+03 102 lawsonite 9.68 9.17 -0.51 -0.034 0.86910E+03 103 leucite 4.17 0.88 -3.28 -0.328 0.56080E+04 105 lizardite 23.29 19.37 -3.92 -0.327 0.66916E+04 107 magnetite 20.13 19.04 -1.10 -0.090 0.18732E+04 108 minnesotaite 10.46 6.05 -4.41 -0.259 0.75241E+04 110 magnesioferrite 26.26 21.26 -4.99 -0.408 0.85263E+04 113 margarite 17.45 13.90 -3.55 -0.142 0.60622E+04 120 muscovite 2.68 2.30 -0.38 -0.022 0.64709E+03 122 nepheline 8.38 6.23 -2.14 -0.306 0.36598E+04 134 phlogopite-Na 29.73 25.60 -4.13 -0.229 0.70489E+04 136 prehnite 19.47 16.92 -2.54 -0.150 0.43447E+04 137 prehnite-Fe 22.59 20.85 -1.73 -0.104 0.29577E+04 138 pumpellyite-Fe 46.47 42.65 -3.82 -0.085 0.65275E+04 139 pumpellyite-Mg 49.19 44.88 -4.32 -0.096 0.73734E+04 145 pyroxmangite 7.42 5.25 -2.17 -0.433 0.37002E+04 146 pyrophyllite -6.10 -8.53 -2.43 -0.152 0.41494E+04 147 quartz -2.98 -3.32 -0.33 -0.111 0.56867E+03 152 rhodonite 7.46 5.25 -2.21 -0.443 0.37794E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.42 -3.90 -0.390 0.66666E+04 164 stilpnomelane-Fe 13.18 12.98 -0.20 -0.006 0.34744E+03 165 stilpnomelane-Mg 27.60 24.12 -3.48 -0.104 0.59423E+04 168 sudoite 21.22 16.85 -4.36 -0.141 0.74531E+04 171 talc 16.55 12.74 -3.82 -0.224 0.65141E+04 174 tephroite 18.11 13.81 -4.30 -0.614 0.73420E+04 177 topaz-H 4.67 1.42 -3.25 -0.296 0.55503E+04 178 tridymite -2.61 -3.32 -0.70 -0.233 0.11960E+04 187 wairakite 4.06 2.54 -1.52 -0.089 0.25940E+04 188 walstromite 11.53 7.75 -3.78 -0.755 0.64465E+04 189 wollastonite 10.48 7.75 -2.73 -0.546 0.46604E+04 190 pseudo-wollastonite 11.02 7.75 -3.27 -0.653 0.55790E+04 191 zoisite 22.96 19.29 -3.68 -0.167 0.62764E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.83 -3.27 -0.202 0.55794E+04 194 beidellite-H -2.24 -6.65 -4.41 -0.282 0.75339E+04 195 beidellite-K -1.44 -4.95 -3.52 -0.216 0.60099E+04 196 beidellite-Mg -1.71 -5.22 -3.52 -0.218 0.60045E+04 197 beidellite-Na -1.26 -4.28 -3.03 -0.185 0.51664E+04 199 chalcedony -2.79 -3.32 -0.52 -0.174 0.88898E+03 201 montmorillonite-Ca -2.21 -4.62 -2.41 -0.149 0.41132E+04 202 montmorillonite-K -2.16 -4.75 -2.59 -0.159 0.44215E+04 203 montmorillonite-Mg -2.40 -5.02 -2.62 -0.162 0.44694E+04 204 montmorillonite-Na -1.96 -4.08 -2.12 -0.130 0.36162E+04 205 nontronite-Ca 3.28 3.04 -0.24 -0.016 0.41209E+03 206 nontronite-H 2.60 1.21 -1.38 -0.093 0.23624E+04 207 nontronite-K 3.40 2.91 -0.49 -0.032 0.84181E+03 208 nontronite-Mg 3.14 2.64 -0.50 -0.032 0.84887E+03 224 tobermorite 9.84 5.90 -3.93 -1.074 0.67187E+04 233 boehmite 4.43 2.37 -2.06 -0.344 0.35235E+04 235 ferrous-oxide 9.82 6.44 -3.39 -0.847 0.57817E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.412 0.21092E+04 242 an20ab80 2.08 1.52 -0.56 -0.043 0.95899E+03 243 an25ab75 2.71 2.00 -0.71 -0.055 0.12180E+04 244 an30ab70 3.34 2.47 -0.87 -0.067 0.14854E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 3.8990000 g New total amount of reactant added: 3.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.4563E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3.9990000 Water: Moles liquid = 0.5547E+02 kg liquid = 0.9993E+00 Moles total = 0.5546E+02 kg total = 0.9991E+00 Activity = 1.0000 Stoichiometric ionic strength = .2832214E-02 Osmotic coef. = 0.9707 True ionic strength = .4794517E-02 Chg. balance for total moles = 0.4563E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.29391E-09 -9.5318 0.26523E-09 -9.5764 0.90242E+00 -0.0446 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12422E-03 -3.9058 0.90079E+00 -0.0454 4 SO4-- 0.25511E-04 -4.5933 0.17790E-04 -4.7498 0.69732E+00 -0.1566 5 HCO3- 0.90121E-05 -5.0452 0.81215E-05 -5.0904 0.90118E+00 -0.0452 6 HS- 0.72107E-13 -13.1420 0.64956E-13 -13.1874 0.90083E+00 -0.0454 7 Al+++ 0.94533E-26 -26.0244 0.42786E-26 -26.3687 0.45260E+00 -0.3443 8 H4SiO4 0.48260E-03 -3.3164 0.48260E-03 -3.3164 0.10000E+01 0.0000 9 Ca++ 0.12385E-07 -7.9071 0.86179E-08 -8.0646 0.69582E+00 -0.1575 10 Mg++ 0.47265E-10 -10.3255 0.32843E-10 -10.4836 0.69487E+00 -0.1581 11 Fe++ 0.27948E-12 -12.5536 0.19427E-12 -12.7116 0.69510E+00 -0.1580 12 K+ 0.42246E-04 -4.3742 0.38074E-04 -4.4194 0.90125E+00 -0.0452 13 Na+ 0.47158E-02 -2.3264 0.42477E-02 -2.3718 0.90075E+00 -0.0454 14 Mn++ 0.37337E-10 -10.4279 0.25959E-10 -10.5857 0.69527E+00 -0.1578 15 HPO4-- 0.68043E-05 -5.1672 0.47450E-05 -5.3238 0.69735E+00 -0.1565 16 HSiO3- 0.19708E-02 -2.7054 0.17753E-02 -2.7507 0.90079E+00 -0.0454 17 Ca(HSiO3)+ 0.38031E-09 -9.4199 0.34278E-09 -9.4650 0.90131E+00 -0.0451 18 Mg(HSiO3)+ 0.18038E-11 -11.7438 0.16258E-11 -11.7889 0.90131E+00 -0.0451 19 NaHSiO3,aq 0.11977E-03 -3.9217 0.11977E-03 -3.9217 0.10000E+01 0.0000 20 AlO+ 0.87117E-14 -14.0599 0.78520E-14 -14.1050 0.90131E+00 -0.0451 21 AlOH+2 0.15000E-19 -19.8239 0.10432E-19 -19.9816 0.69547E+00 -0.1577 22 HAlO2,aq 0.59242E-08 -8.2274 0.59242E-08 -8.2274 0.10000E+01 0.0000 23 AlO2- 0.55397E-04 -4.2565 0.49874E-04 -4.3021 0.90030E+00 -0.0456 24 CH4,aq 0.29124E-19 -19.5357 0.29099E-19 -19.5361 0.99912E+00 -0.0004 29 CO,aq 0.81140E-19 -19.0908 0.81140E-19 -19.0908 0.10000E+01 0.0000 30 CO2,aq 0.43468E-08 -8.3618 0.43430E-08 -8.3622 0.99912E+00 -0.0004 31 CO3-2 0.40627E-05 -5.3912 0.28312E-05 -5.5480 0.69688E+00 -0.1568 32 CaCO3,aq 0.29883E-09 -9.5246 0.29883E-09 -9.5246 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.19567E-11 -11.7085 0.17636E-11 -11.7536 0.90131E+00 -0.0451 34 CaCl+ 0.18926E-11 -11.7229 0.17059E-11 -11.7681 0.90131E+00 -0.0451 35 CaCl2,aq 0.49339E-16 -16.3068 0.49339E-16 -16.3068 0.10000E+01 0.0000 36 CaOH+ 0.25420E-08 -8.5948 0.22911E-08 -8.6400 0.90131E+00 -0.0451 37 CaSO4,aq 0.47767E-10 -10.3209 0.47767E-10 -10.3209 0.10000E+01 0.0000 38 HCl,aq 0.61972E-14 -14.2078 0.61972E-14 -14.2078 0.10000E+01 0.0000 43 FeCl+ 0.41701E-16 -16.3799 0.37586E-16 -16.4250 0.90131E+00 -0.0451 46 FeO,aq 0.10920E-09 -9.9618 0.10920E-09 -9.9618 0.10000E+01 0.0000 47 FeOH+ 0.26941E-10 -10.5696 0.24282E-10 -10.6147 0.90131E+00 -0.0451 48 HFeO2- 0.49164E-08 -8.3084 0.44286E-08 -8.3537 0.90079E+00 -0.0454 49 FeO+ 0.24342E-14 -14.6136 0.21940E-14 -14.6588 0.90131E+00 -0.0451 51 FeO2- 0.68050E-08 -8.1672 0.61299E-08 -8.2125 0.90079E+00 -0.0454 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.72603E-09 -9.1390 0.72539E-09 -9.1394 0.99912E+00 -0.0004 54 KCl,aq 0.83744E-10 -10.0770 0.83744E-10 -10.0770 0.10000E+01 0.0000 55 KHSO4,aq 0.48072E-18 -18.3181 0.48072E-18 -18.3181 0.10000E+01 0.0000 56 KOH,aq 0.62581E-07 -7.2036 0.62581E-07 -7.2036 0.10000E+01 0.0000 57 KSO4- 0.11584E-07 -7.9361 0.10435E-07 -7.9815 0.90079E+00 -0.0454 58 MgCO3,aq 0.28458E-12 -12.5458 0.28458E-12 -12.5458 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.76041E-14 -14.1190 0.68536E-14 -14.1641 0.90131E+00 -0.0451 60 MgCl+ 0.65481E-14 -14.1839 0.59019E-14 -14.2290 0.90131E+00 -0.0451 61 MgOH+ 0.53671E-10 -10.2703 0.48374E-10 -10.3154 0.90131E+00 -0.0451 63 MnO,aq 0.38956E-09 -9.4094 0.38956E-09 -9.4094 0.10000E+01 0.0000 64 MnOH+ 0.33444E-09 -9.4757 0.30143E-09 -9.5208 0.90131E+00 -0.0451 65 MnO2-2 0.27481E-12 -12.5610 0.19151E-12 -12.7178 0.69688E+00 -0.1568 66 HMnO2- 0.12217E-10 -10.9130 0.11005E-10 -10.9584 0.90079E+00 -0.0454 69 MnCl+ 0.21654E-13 -13.6645 0.19517E-13 -13.7096 0.90131E+00 -0.0451 70 MnSO4,aq 0.13088E-12 -12.8831 0.13088E-12 -12.8831 0.10000E+01 0.0000 71 NaCl,aq 0.17229E-06 -6.7637 0.17229E-06 -6.7637 0.10000E+01 0.0000 72 NaOH,aq 0.70373E-05 -5.1526 0.70373E-05 -5.1526 0.10000E+01 0.0000 74 OH- 0.25120E-02 -2.6000 0.22616E-02 -2.6456 0.90030E+00 -0.0456 79 HPO3-2 0.15601E-16 -16.8069 0.10872E-16 -16.9637 0.69688E+00 -0.1568 82 H3PO4,aq 0.21489E-14 -14.6678 0.21489E-14 -14.6678 0.10000E+01 0.0000 83 H2PO4- 0.24487E-07 -7.6111 0.22064E-07 -7.6563 0.90104E+00 -0.0453 84 PO4-3 0.34017E-07 -7.4683 0.15624E-07 -7.8062 0.45929E+00 -0.3379 87 H2P2O7-2 0.54675E-16 -16.2622 0.38102E-16 -16.4191 0.69688E+00 -0.1568 88 HP2O7-3 0.65071E-13 -13.1866 0.29457E-13 -13.5308 0.45270E+00 -0.3442 89 P2O7-4 0.10970E-12 -12.9598 0.27399E-13 -13.5623 0.24976E+00 -0.6025 90 H2S,aq 0.51809E-16 -16.2856 0.51763E-16 -16.2860 0.99912E+00 -0.0004 97 SO3-2 0.25140E-14 -14.5996 0.17595E-14 -14.7546 0.69989E+00 -0.1550 98 HSO3- 0.30318E-16 -16.5183 0.27310E-16 -16.5637 0.90079E+00 -0.0454 99 HSO4- 0.48559E-11 -11.3137 0.43779E-11 -11.3587 0.90156E+00 -0.0450 Charge balance for all species = 0.5432E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2939094E-09 -.4835387E-02 -.4871962E+01 0.0000 2 H2O 0.1000000E+01 0.5550879E+02 0.9996344E+06 0.0000 3 Cl- 0.1379012E-03 0.1380736E-03 0.4893297E+01 5.6706 4 SO4-- 0.2551121E-04 0.2552354E-04 0.2450918E+01 14.4029 5 HCO3- 0.9012105E-05 0.1307942E-04 0.7977718E+00 4.4860 6 HS- 0.7210711E-13 -.6944752E-09 -.2295911E-04 -3.6110 7 Al+++ 0.9453348E-26 0.5540251E-04 0.1494285E+01 2.3604 8 H4SiO4 0.4825968E-03 0.2573160E-02 0.2472280E+03 -3.3164 9 Ca++ 0.1238527E-07 0.1565802E-07 0.6273080E-03 11.0882 10 Mg++ 0.4726541E-10 0.1030384E-09 0.2504136E-05 8.6692 11 Fe++ 0.2794809E-12 0.1206124E-07 0.6733330E-03 6.4412 12 K+ 0.4224553E-04 0.4231978E-04 0.1654171E+01 5.1570 13 Na+ 0.4715751E-02 0.4842728E-02 0.1112918E+03 7.2045 14 Mn++ 0.3733747E-10 0.7739796E-09 0.4250502E-04 8.5671 15 HPO4-- 0.6804310E-05 0.6862815E-05 0.6584404E+00 13.8290 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6620446E-01 -.4831905E-02 -.6137256E-01 0.0000000E+00 2 H2O 0.5545812E+02 0.5546882E+02 -.1069442E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1363304E-03 0.2550516E-04 0.1108252E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1108259E-03 -.6939751E-09 -.1108252E-03 0.0000000E+00 7 Al+++ 0.1303971E-01 0.5536261E-04 0.1298434E-01 0.0000000E+00 8 H4SiO4 0.4164072E-01 0.2571307E-02 0.3906941E-01 0.0000000E+00 9 Ca++ 0.4613892E-02 0.1564674E-07 0.4613876E-02 0.0000000E+00 10 Mg++ 0.3173810E-02 0.1029642E-09 0.3173809E-02 0.0000000E+00 11 Fe++ 0.2851321E-02 0.1205256E-07 0.2851309E-02 0.0000000E+00 12 K+ 0.8490446E-03 0.4228930E-04 0.8067553E-03 0.0000000E+00 13 Na+ 0.5179790E-02 0.4839240E-02 0.3405500E-03 0.0000000E+00 14 Mn++ 0.6933705E-04 0.7734222E-09 0.6933627E-04 0.0000000E+00 15 HPO4-- 0.2366439E-04 0.6857873E-05 0.1680652E-04 0.0000000E+00 Chg. balance for solid moles: 0.3740E-17 Mass of aqueous solution: 0.999653E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5602E-05 -5.252 0.2814E-02 -2.551 0.6508E-01 0.8942E-03 clinochlore 0.6348E-03 -3.197 0.3528 -0.452 8.160 0.1342 daphnite 0.3929E-03 -3.406 0.2804 -0.552 6.484 0.8496E-01 chlorite-Mn 0.1387E-04 -4.858 0.9831E-02 -2.007 0.2274 0.3133E-02 hematite 0.2934E-03 -3.533 0.4686E-01 -1.329 1.084 0.8881E-02 microcline 0.8068E-03 -3.093 0.2246 -0.649 5.193 0.8772E-01 paragonite 0.2911E-03 -3.536 0.1113 -0.954 2.573 0.3846E-01 stilbite 0.4586E-02 -2.339 3.232 0.509 74.74 1.507 nontronite-Na 0.1499E-03 -3.824 0.6375E-01 -1.196 1.474 0.1980E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4.323990 g Volume = 1.885392 cm3 Porosity: 27.4738% V(tot) - V(min): 0.71421E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.9990000 g log = 0.6020 Original solution: 1000.0103000 g Original solution / Rock added: 250.07 (Water/Rock Ratio), log = 2.3981 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.4692E-06 1.0073 0.4971E-06 0.4935E-06 CH4,gas 0.4319E-16 1.0129 0.4602E-16 0.4543E-16 H2,gas 0.9453E-06 1.0006 0.9949E-06 0.9944E-06 H2S,gas 0.1441E-14 0.9959 0.1510E-14 0.1516E-14 S2,gas 0.8198E-37 1.0000 0.8624E-37 0.8624E-37 CO,gas 0.1218E-15 1.0000 0.1281E-15 0.1281E-15 SO3,gas 0.4448E-39 1.0000 0.4679E-39 0.4679E-39 SO2,gas 0.1674E-22 1.0000 0.1761E-22 0.1761E-22 HCl,gas 0.1040E-16 1.0000 0.1094E-16 0.1094E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.28814E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.75827E-12 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.67 -8.30 -2.768 0.14178E+05 -6.304 3 CH4,gas 4.81 -13.53 -18.34 -4.584 0.31310E+05 -16.337 4 H2,gas 8.29 0.28 -8.00 -4.573 0.13664E+05 -6.002 5 H2S,gas -5.94 -22.76 -16.82 -8.411 0.28722E+05 -14.821 6 S2,gas -7.03 -46.10 -39.06 -6.010 0.66701E+05 -37.064 7 CO,gas 3.51 -14.38 -17.89 -5.505 0.30551E+05 -15.892 8 SO3,gas 17.43 -23.90 -41.33 -10.332 0.70570E+05 -39.330 9 SO2,gas 1.14 -23.62 -24.75 -6.601 0.42267E+05 -22.754 10 HCl,gas 5.48 -13.48 -18.96 -9.480 0.32375E+05 -16.961 11 acmite 7.74 6.87 -0.87 -0.090 0.14802E+04 15 albite-high 0.75 -0.38 -1.13 -0.087 0.19361E+04 16 albite -0.33 -0.38 -0.06 -0.004 0.95453E+02 19 spessartine 24.55 20.47 -4.08 -0.204 0.69615E+04 20 analcite 3.37 2.93 -0.44 -0.049 0.74870E+03 21 andalusite 5.06 1.40 -3.66 -0.366 0.62458E+04 22 andradite 39.09 35.91 -3.17 -0.165 0.54210E+04 23 grossular 32.83 28.04 -4.79 -0.240 0.81823E+04 26 annite 20.21 16.89 -3.32 -0.184 0.56648E+04 27 phlogopite 27.15 23.58 -3.57 -0.198 0.60970E+04 29 anorthite 12.80 9.18 -3.62 -0.279 0.61835E+04 35 aragonite 0.99 -3.58 -4.56 -1.522 0.77943E+04 36 brucite 12.58 8.67 -3.91 -0.781 0.66718E+04 37 calcite 0.83 -3.58 -4.41 -1.471 0.75329E+04 38 carnegieite-low 9.06 6.25 -2.82 -0.402 0.48082E+04 39 carnegieite-high 10.13 6.25 -3.89 -0.555 0.66351E+04 40 carpholite-Mg 8.65 6.76 -1.89 -0.126 0.32324E+04 41 carpholite-Fe 6.78 4.53 -2.25 -0.150 0.38481E+04 42 celadonite 5.40 2.92 -2.48 -0.146 0.42337E+04 43 celadonite-Fe 3.94 0.69 -3.24 -0.191 0.55390E+04 44 chrysotile 23.94 19.37 -4.56 -0.380 0.77904E+04 50 chloritoid-Mg 13.26 10.07 -3.19 -0.213 0.54427E+04 51 chloritoid-Fe 9.24 7.85 -1.39 -0.093 0.23786E+04 52 chloritoid-Mn 11.46 9.97 -1.49 -0.099 0.25470E+04 54 coesite -2.37 -3.32 -0.95 -0.316 0.16171E+04 59 corundum 8.43 4.72 -3.71 -0.338 0.63390E+04 61 cristobalite -2.55 -3.32 -0.77 -0.256 0.13100E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.36 -0.54 -0.089 0.91460E+03 67 diopside 16.22 13.12 -3.09 -0.309 0.52777E+04 68 hedenbergite 14.24 10.90 -3.35 -0.335 0.57165E+04 75 epidote 24.78 23.25 -1.53 -0.074 0.26098E+04 76 clinozoisite 22.92 19.31 -3.61 -0.164 0.61686E+04 77 epidote-Fe 29.94 27.19 -2.75 -0.143 0.46983E+04 78 fayalite 14.08 9.57 -4.51 -0.645 0.77059E+04 79 ferrosilite 11.19 6.25 -4.94 -0.494 0.84319E+04 83 gibbsite 4.10 2.36 -1.74 -0.248 0.29658E+04 84 glaucophane 23.11 18.61 -4.50 -0.122 0.76909E+04 87 greenalite 16.19 12.69 -3.50 -0.292 0.59822E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.93 -1.32 -0.132 0.22517E+04 97 kalsilite 7.62 4.20 -3.42 -0.488 0.58382E+04 98 kaolinite -1.27 -1.91 -0.64 -0.058 0.10907E+04 99 kyanite 4.93 1.40 -3.53 -0.353 0.60225E+04 101 laumontite 2.97 2.54 -0.43 -0.029 0.73618E+03 102 lawsonite 9.68 9.18 -0.50 -0.033 0.85741E+03 103 leucite 4.17 0.88 -3.28 -0.328 0.56057E+04 105 lizardite 23.29 19.37 -3.91 -0.326 0.66807E+04 107 magnetite 20.13 19.04 -1.09 -0.089 0.18680E+04 108 minnesotaite 10.46 6.06 -4.40 -0.259 0.75179E+04 110 magnesioferrite 26.26 21.27 -4.99 -0.407 0.85211E+04 113 margarite 17.45 13.90 -3.55 -0.142 0.60695E+04 120 muscovite 2.68 2.29 -0.39 -0.023 0.66608E+03 122 nepheline 8.38 6.25 -2.13 -0.304 0.36362E+04 134 phlogopite-Na 29.73 25.62 -4.11 -0.228 0.70143E+04 136 prehnite 19.47 16.95 -2.52 -0.148 0.43000E+04 137 prehnite-Fe 22.59 20.89 -1.70 -0.102 0.29034E+04 138 pumpellyite-Fe 46.47 42.70 -3.77 -0.084 0.64423E+04 139 pumpellyite-Mg 49.19 44.93 -4.27 -0.095 0.72883E+04 145 pyroxmangite 7.42 5.25 -2.17 -0.433 0.36973E+04 146 pyrophyllite -6.10 -8.54 -2.45 -0.153 0.41777E+04 147 quartz -2.98 -3.32 -0.33 -0.111 0.57101E+03 152 rhodonite 7.46 5.25 -2.21 -0.442 0.37766E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.40 -3.92 -0.392 0.66879E+04 164 stilpnomelane-Fe 13.18 12.97 -0.21 -0.006 0.35088E+03 165 stilpnomelane-Mg 27.60 24.11 -3.48 -0.104 0.59457E+04 168 sudoite 21.22 16.83 -4.39 -0.141 0.74877E+04 171 talc 16.55 12.74 -3.81 -0.224 0.65079E+04 174 tephroite 18.11 13.82 -4.30 -0.614 0.73339E+04 177 topaz-H 4.67 1.40 -3.26 -0.297 0.55716E+04 178 tridymite -2.61 -3.32 -0.70 -0.234 0.11983E+04 187 wairakite 4.06 2.54 -1.52 -0.089 0.25870E+04 188 walstromite 11.53 7.77 -3.76 -0.751 0.64135E+04 189 wollastonite 10.48 7.77 -2.71 -0.542 0.46274E+04 190 pseudo-wollastonite 11.02 7.77 -3.25 -0.650 0.55460E+04 191 zoisite 22.96 19.31 -3.66 -0.166 0.62412E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.84 -3.28 -0.203 0.56042E+04 194 beidellite-H -2.24 -6.67 -4.43 -0.283 0.75646E+04 195 beidellite-K -1.44 -4.97 -3.53 -0.216 0.60352E+04 196 beidellite-Mg -1.71 -5.24 -3.53 -0.219 0.60344E+04 197 beidellite-Na -1.26 -4.29 -3.04 -0.186 0.51854E+04 199 chalcedony -2.79 -3.32 -0.52 -0.174 0.89132E+03 201 montmorillonite-Ca -2.21 -4.63 -2.42 -0.150 0.41309E+04 202 montmorillonite-K -2.16 -4.76 -2.60 -0.159 0.44396E+04 203 montmorillonite-Mg -2.40 -5.03 -2.63 -0.163 0.44921E+04 204 montmorillonite-Na -1.96 -4.09 -2.12 -0.130 0.36280E+04 205 nontronite-Ca 3.28 3.03 -0.24 -0.016 0.41797E+03 206 nontronite-H 2.60 1.21 -1.39 -0.093 0.23741E+04 207 nontronite-K 3.40 2.91 -0.50 -0.032 0.84808E+03 208 nontronite-Mg 3.14 2.64 -0.50 -0.033 0.85973E+03 224 tobermorite 9.84 5.92 -3.92 -1.069 0.66916E+04 233 boehmite 4.43 2.36 -2.07 -0.345 0.35330E+04 235 ferrous-oxide 9.82 6.44 -3.38 -0.846 0.57765E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.412 0.21115E+04 242 an20ab80 2.08 1.53 -0.55 -0.042 0.94146E+03 243 an25ab75 2.71 2.01 -0.70 -0.054 0.12009E+04 244 an30ab70 3.34 2.48 -0.86 -0.066 0.14686E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.1000000 g Current total amount of reactant added: 3.9990000 g New total amount of reactant added: 4.0990000 g Mixing fraction reached given limit of 0.4000E+01 TOTMIX = 0.4099E+01 Execution stopped.