File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.66204E-01 0.29391E-09 0.9024 0.00000000E+00 H2O 2 0. 0.55458E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13790E-03 0.9008 0.00000000E+00 SO4-- 4 -2. 0.13633E-03 0.25511E-04 0.6973 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.90121E-05 0.9012 0.00000000E+00 HS- 6 -1. -0.11083E-03 0.72107E-13 0.9008 0.00000000E+00 Al+++ 7 3. 0.13040E-01 0.94533E-26 0.4526 0.00000000E+00 H4SiO4 8 0. 0.41641E-01 0.48260E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.46139E-02 0.12385E-07 0.6958 0.00000000E+00 Mg++ 10 2. 0.31738E-02 0.47265E-10 0.6949 0.00000000E+00 Fe++ 11 2. 0.28513E-02 0.27948E-12 0.6951 0.00000000E+00 K+ 12 1. 0.84904E-03 0.42246E-04 0.9013 0.00000000E+00 Na+ 13 1. 0.51798E-02 0.47158E-02 0.9008 0.00000000E+00 Mn++ 14 2. 0.69337E-04 0.37337E-10 0.6953 0.00000000E+00 HPO4-- 15 -2. 0.23664E-04 0.68043E-05 0.6974 0.00000000E+00 Chg. balance for total moles = -.9361E-13 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 100.0000 SLIM = 0.800000E+01 TEMP = 100.0000 SINC = 0.2000E+00 TEMPC = 0.0000 TOTMIX = 0.399900E+01 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 2.5996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0107 MnO2-2 65 -2. 40.4376 Ca(HSiO3)+ 17 1. 7.6603 HMnO2- 66 -1. 29.1018 Mg(HSiO3)+ 18 1. 7.5653 MnO4- 67 -1. 83.3383 NaHSiO3,aq 19 0. 7.8098 MnO4-2 68 -2. 81.3024 AlO+ 20 1. 6.8891 MnCl+ 69 1. -0.7819 AlOH+2 21 2. 3.1893 MnSO4,aq 70 0. -2.4524 HAlO2,aq 22 0. 10.5878 NaCl,aq 71 0. 0.4861 AlO2- 23 -1. 16.2390 NaOH,aq 72 0. 12.3571 CH4,aq 24 0. 6.0082 O2,aq 73 0. 53.5759 C2H6,aq 25 0. 12.3556 OH- 74 -1. 12.2220 C3H8,aq 26 0. 17.3423 HO2- 75 -1. 50.7897 C4H10,aq 27 0. 22.3397 H2O2,aq 76 0. 40.0297 ethanol,aq 28 0. 15.3114 H3PO2,aq 77 0. 24.3310 CO,aq 29 0. 4.7087 H2PO2- 78 -1. 26.5491 CO2,aq 30 0. -6.3045 HPO3-2 79 -2. 11.9246 CO3-2 31 -2. 10.0340 H3PO3,aq 80 0. 3.5932 CaCO3,aq 32 0. 5.9460 H2PO3- 81 -1. 5.6314 Ca(HCO3)+ 33 1. -1.4013 H3PO4,aq 82 0. -9.8087 CaCl+ 34 1. -0.2023 H2PO4- 83 -1. -7.2438 CaCl2,aq 35 0. 0.4306 PO4-3 84 -3. 12.0588 CaOH+ 36 1. 10.1517 H4P2O7,aq 85 0. -17.7539 CaSO4,aq 37 0. -2.4936 H3P2O7- 86 -1. -15.8646 HCl,aq 38 0. 0.7256 H2P2O7-2 87 -2. -13.3812 HClO,aq 39 0. 32.4377 HP2O7-3 88 -3. -6.6931 ClO- 40 -1. 39.6416 P2O7-4 89 -4. 2.9147 HClO2,aq 41 0. 70.2060 H2S,aq 90 0. -6.4778 Fe+3 42 3. 8.3763 S2-2 91 -2. 1.2336 FeCl+ 43 1. -0.1924 S3-2 92 -2. -8.7963 FeCl2,aq 44 0. 4.3160 S3- 93 -1. -16.3178 FeCl+2 45 2. 6.5223 S4-2 94 -2. -18.6473 FeO,aq 46 0. 16.4029 S5-2 95 -2. -28.3223 FeOH+ 47 1. 7.4795 SO2,aq 96 0. -0.1980 HFeO2- 48 -1. 24.3713 SO3-2 97 -2. 10.2895 FeO+ 49 1. 11.3812 HSO3- 98 -1. 2.5222 FeOH+2 50 2. 9.1115 HSO4- 99 -1. -2.9675 FeO2- 51 -1. 24.0877 HSO5- 100 -1. 38.8657 HFeO2,aq 52 0. 15.9903 S2O3-2 101 -2. -4.5491 H2,aq 53 0. 9.4241 HS2O3- 102 -1. -6.8007 KCl,aq 54 0. 1.7519 H2S2O3,aq 103 0. -7.9944 KHSO4,aq 55 0. -0.4275 S2O4-2 104 -2. 10.5639 KOH,aq 56 0. 12.3606 HS2O4- 105 -1. 7.6762 KSO4- 57 -1. -1.1877 H2S2O4,aq 106 0. 6.6566 MgCO3,aq 58 0. 6.5483 S2O5-2 107 -2. 10.0891 Mg(HCO3)+ 59 1. -1.4098 S2O6-2 108 -2. 11.5737 MgCl+ 60 1. -0.1603 S2O8-2 109 -2. 42.1139 MgOH+ 61 1. 9.4082 S3O6-2 110 -2. 3.8101 Mn+3 62 3. 19.1332 S4O6-2 111 -2. -17.8301 MnO,aq 63 0. 17.9765 S5O6-2 112 -2. -14.1051 MnOH+ 64 1. 8.5115 113 0. 10.3157 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.984 0.0000E+00 osumilite(2) 124 20.895 0.0000E+00 CO2,gas 2 -6.363 0.0000E+00 osumilite-Fe 125 14.657 0.0000E+00 CH4,gas 3 4.809 0.0000E+00 pargasite 126 65.279 0.0000E+00 H2,gas 4 8.287 0.0000E+00 periclase 127 16.149 0.0000E+00 H2S,gas 5 -5.943 0.0000E+00 periclase-Fe 128 11.639 0.0000E+00 S2,gas 6 -7.033 0.0000E+00 perovskite-Al 129 12.395 0.0000E+00 CO,gas 7 3.510 0.0000E+00 perovskite-Ca 130 23.818 0.0000E+00 SO3,gas 8 17.427 0.0000E+00 perovskite-Fe 131 21.158 0.0000E+00 SO2,gas 9 1.136 0.0000E+00 perovskite-Mg 132 23.132 0.0000E+00 HCl,gas 10 5.479 0.0000E+00 phase_A 133 80.267 0.0000E+00 acmite 11 7.737 0.0000E+00 phlogopite-Na 134 29.731 0.0000E+00 akermanite 12 36.495 0.0000E+00 piemontite(ordered) 135 33.876 0.0000E+00 akimotoite 13 16.606 0.0000E+00 prehnite 136 19.466 0.0000E+00 akimotoite-Fe 14 13.083 0.0000E+00 prehnite-Fe 137 22.587 0.0000E+00 albite-high 15 0.750 0.0000E+00 pumpellyite-Fe 138 46.471 0.0000E+00 albite 16 -0.328 0.0000E+00 pumpellyite-Mg 139 49.194 0.0000E+00 almandine 17 24.545 0.0000E+00 px-Mg-tschermaks 140 19.687 0.0000E+00 pyrope 18 37.348 0.0000E+00 px-Ca-tschermaks 141 18.679 0.0000E+00 spessartine 19 24.550 0.0000E+00 pyrite 142 -21.225 0.0000E+00 analcite 20 3.371 0.0000E+00 pyrrhotite 143 -4.244 0.0000E+00 andalusite 21 5.062 0.0000E+00 pyrrhotiteFe0.875 144 -6.001 0.0000E+00 andradite 22 39.088 0.0000E+00 pyroxmangite 145 7.416 0.0000E+00 grossular 23 32.828 0.0000E+00 pyrophyllite 146 -6.098 0.0000E+00 anhydrite 24 -5.280 0.0000E+00 quartz 147 -2.982 0.0000E+00 ankerite 25 -2.093 0.0000E+00 rankinite 148 40.765 0.0000E+00 annite 26 20.209 0.0000E+00 ringwoodite-Fe 149 15.486 0.0000E+00 phlogopite 27 27.147 0.0000E+00 ringwoodite-Mg 150 27.602 0.0000E+00 biotite-Mn 28 33.034 0.0000E+00 rhodochrosite 151 -0.959 0.0000E+00 anorthite 29 12.798 0.0000E+00 rhodonite 152 7.462 0.0000E+00 anthophyllite 30 51.988 0.0000E+00 sanidine 153 -1.221 0.0000E+00 anthophyllite-Fe 31 29.455 0.0000E+00 sapphirine(351) 154 79.204 0.0000E+00 apatite-OH 32 -17.989 0.5602E-05 siderite 155 -2.588 0.0000E+00 apatite-OH-zs 33 -12.572 0.0000E+00 sillimanite 156 5.321 0.0000E+00 apatite-Cl-zs 34 -16.504 0.0000E+00 sodalite 157 50.255 0.0000E+00 aragonite 35 0.986 0.0000E+00 spinel 158 20.934 0.0000E+00 brucite 36 12.577 0.0000E+00 spurrite 159 59.566 0.0000E+00 calcite 37 0.833 0.0000E+00 staurolite-Fe 160 74.138 0.0000E+00 carnegieite-low 38 9.065 0.0000E+00 staurolite-Mg 161 90.336 0.0000E+00 carnegieite-high 39 10.134 0.0000E+00 staurolite-Mn 162 84.438 0.0000E+00 carpholite-Mg 40 8.650 0.0000E+00 stilbite 163 -7.406 0.4586E-02 carpholite-Fe 41 6.783 0.0000E+00 stilpnomelane-Fe 164 13.179 0.0000E+00 celadonite 42 5.401 0.0000E+00 stilpnomelane-Mg 165 27.596 0.0000E+00 celadonite-Fe 43 3.937 0.0000E+00 stishovite 166 2.721 0.0000E+00 chrysotile 44 23.937 0.0000E+00 sudoite-Fe 167 18.437 0.0000E+00 chondrodite 45 56.542 0.0000E+00 sudoite 168 21.216 0.0000E+00 clinochlore 46 39.193 0.6348E-03 sulfur 169 -9.141 0.0000E+00 daphnite 47 29.094 0.3929E-03 sylvite 170 1.345 0.0000E+00 chlorite-Mn 48 46.985 0.1387E-04 talc 171 16.553 0.0000E+00 chlorite-Al-free 49 47.262 0.0000E+00 talc-Fe 172 13.516 0.0000E+00 chloritoid-Mg 50 13.261 0.0000E+00 talc-tschermaks 173 19.189 0.0000E+00 chloritoid-Fe 51 9.239 0.0000E+00 tephroite 174 18.113 0.0000E+00 chloritoid-Mn 52 11.463 0.0000E+00 tilleyite 175 41.473 0.0000E+00 clinohumite 53 97.255 0.0000E+00 titanite-CaSi 176 15.497 0.0000E+00 coesite 54 -2.369 0.0000E+00 topaz-H 177 4.668 0.0000E+00 cordierite-H 55 23.898 0.0000E+00 tridymite 178 -2.615 0.0000E+00 cordierite 56 24.245 0.0000E+00 tremolite 179 48.003 0.0000E+00 cordierite-Fe 57 20.649 0.0000E+00 ferroactinolite 180 38.596 0.0000E+00 cordierite-Mn 58 25.261 0.0000E+00 troilite-low 181 -4.394 0.0000E+00 corundum 59 8.433 0.0000E+00 tschermakite 182 48.414 0.0000E+00 corundum-MgSi 60 18.905 0.0000E+00 vesuvianite 183 224.056 0.0000E+00 cristobalite 61 -2.549 0.0000E+00 wadeite-Si 184 20.233 0.0000E+00 cummingtonite 62 52.233 0.0000E+00 wadsleyite-Fe 185 15.711 0.0000E+00 cymrite-K 63 1.731 0.0000E+00 wadsleyite-Mg 186 25.878 0.0000E+00 deerite 64 95.982 0.0000E+00 wairakite 187 4.058 0.0000E+00 diaspore 65 2.896 0.0000E+00 walstromite 188 11.528 0.0000E+00 diamond 66 -3.107 0.0000E+00 wollastonite 189 10.482 0.0000E+00 diopside 67 16.215 0.0000E+00 pseudo-wollastonite 190 11.020 0.0000E+00 hedenbergite 68 14.244 0.0000E+00 zoisite 191 22.964 0.0000E+00 dolomite,ordered 69 0.587 0.0000E+00 akaganeite 192 7.768 0.0000E+00 eastonite 70 28.605 0.0000E+00 beidellite-Ca 193 -1.560 0.0000E+00 enstatite 71 17.301 0.0000E+00 beidellite-H 194 -2.241 0.0000E+00 clinoenstatite-HiP 72 18.388 0.0000E+00 beidellite-K 195 -1.435 0.0000E+00 clinoenstatite 73 17.202 0.0000E+00 beidellite-Mg 196 -1.707 0.0000E+00 protoenstatite 74 17.860 0.0000E+00 beidellite-Na 197 -1.257 0.0000E+00 epidote 75 24.775 0.0000E+00 calcium 198 84.043 0.0000E+00 clinozoisite 76 22.921 0.0000E+00 chalcedony 199 -2.794 0.0000E+00 epidote-Fe 77 29.937 0.0000E+00 dawsonite 200 1.714 0.0000E+00 fayalite 78 14.079 0.0000E+00 montmorillonite-Ca 201 -2.214 0.0000E+00 ferrosilite 79 11.188 0.0000E+00 montmorillonite-K 202 -2.161 0.0000E+00 forsterite 80 21.047 0.0000E+00 montmorillonite-Mg 203 -2.402 0.0000E+00 gedrite 81 50.725 0.0000E+00 montmorillonite-Na 204 -1.961 0.0000E+00 gehlenite 82 36.717 0.0000E+00 nontronite-Ca 205 3.280 0.0000E+00 gibbsite 83 4.097 0.0000E+00 nontronite-H 206 2.596 0.0000E+00 glaucophane 84 23.111 0.0000E+00 nontronite-K 207 3.404 0.0000E+00 glaucophane-Fe 85 17.417 0.0000E+00 nontronite-Mg 208 3.139 0.0000E+00 graphite 86 -3.549 0.0000E+00 nontronite-Na 209 3.583 0.1499E-03 greenalite 87 16.194 0.0000E+00 sepiolite 210 24.194 0.0000E+00 grunerite 88 31.364 0.0000E+00 alite 211 58.043 0.0000E+00 halite 89 1.582 0.0000E+00 belite 212 30.461 0.0000E+00 hematite 90 12.598 0.2934E-03 ettringite 213 43.354 0.0000E+00 heulandite 91 -5.707 0.0000E+00 gypsum 214 -4.924 0.0000E+00 hercynite 92 17.345 0.0000E+00 hemicarboaluminate 215 71.028 0.0000E+00 hollandite 93 25.702 0.0000E+00 hydrogarnet 216 60.721 0.0000E+00 iron 94 19.095 0.0000E+00 hydrogarnet-Si 217 50.654 0.0000E+00 jadeite 95 4.251 0.0000E+00 jennite 218 24.386 0.0000E+00 julgoldite 96 70.573 0.0000E+00 monosulfoaluminate 219 53.497 0.0000E+00 kalsilite 97 7.620 0.0000E+00 monocarboaluminate 220 61.966 0.0000E+00 kaolinite 98 -1.273 0.0000E+00 portlandite 221 18.282 0.0000E+00 kyanite 99 4.932 0.0000E+00 stratlingite 222 36.573 0.0000E+00 larnite-bredigite 100 30.714 0.0000E+00 tricarboaluminate 223 70.427 0.0000E+00 laumontite 101 2.975 0.0000E+00 tobermorite 224 9.839 0.0000E+00 lawsonite 102 9.678 0.0000E+00 C4AH13 225 81.870 0.0000E+00 leucite 103 4.168 0.0000E+00 C2AH8 226 45.260 0.0000E+00 lime 104 26.009 0.0000E+00 C3A 227 87.049 0.0000E+00 lizardite 105 23.287 0.0000E+00 C4AF 228 117.550 0.0000E+00 magnesite 106 0.709 0.0000E+00 CAH10 229 28.373 0.0000E+00 magnetite 107 20.133 0.0000E+00 alabandite 230 -0.962 0.0000E+00 minnesotaite 108 10.461 0.0000E+00 alunite 231 -10.224 0.0000E+00 minnesotaite-Mg 109 20.669 0.0000E+00 artinite 232 15.139 0.0000E+00 magnesioferrite 110 26.257 0.0000E+00 boehmite 233 4.430 0.0000E+00 majorite 111 53.314 0.0000E+00 dolomite,disordered 234 1.288 0.0000E+00 manganosite 112 14.068 0.0000E+00 ferrous-oxide 235 9.824 0.0000E+00 margarite 113 17.452 0.0000E+00 huntite 236 3.850 0.0000E+00 meionite 114 45.158 0.0000E+00 hydromagnesite 237 20.077 0.0000E+00 merwinite 115 55.988 0.0000E+00 nesquehonite 238 4.735 0.0000E+00 microcline 116 -2.432 0.8068E-03 potassium-oxide 239 69.039 0.0000E+00 monticellite 117 24.371 0.0000E+00 silica-amorphous 240 -2.080 0.0000E+00 mullite-Al 118 363.258 0.0000E+00 sodium-oxide 241 55.173 0.0000E+00 mullite-Si 119 7.324 0.0000E+00 an20ab80 242 2.079 0.0000E+00 muscovite 120 2.679 0.0000E+00 an25ab75 243 2.709 0.0000E+00 paragonite 121 4.337 0.2911E-03 an30ab70 244 3.344 0.0000E+00 nepheline 122 8.378 0.0000E+00 tr.625ac.25prg.125 245 45.308 0.0000E+00 osumilite(1) 123 21.978 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 3.9990000 g log = 0.6020 Original solution: 1000.0103000 g Original solution / Rock added: 250.07 (Water/Rock Ratio), log = 2.3981 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3.9990000 Water: Moles liquid = 0.5547E+02 kg liquid = 0.9993E+00 Moles total = 0.5546E+02 kg total = 0.9991E+00 Activity = 1.0000 Stoichiometric ionic strength = .2832214E-02 Osmotic coef. = 0.9707 True ionic strength = .4794517E-02 Chg. balance for total moles = -.9361E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.29391E-09 -9.5318 0.26523E-09 -9.5764 0.90242E+00 -0.0446 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12422E-03 -3.9058 0.90079E+00 -0.0454 4 SO4-- 0.25511E-04 -4.5933 0.17790E-04 -4.7498 0.69732E+00 -0.1566 5 HCO3- 0.90121E-05 -5.0452 0.81215E-05 -5.0904 0.90118E+00 -0.0452 6 HS- 0.72107E-13 -13.1420 0.64956E-13 -13.1874 0.90083E+00 -0.0454 7 Al+++ 0.94533E-26 -26.0244 0.42786E-26 -26.3687 0.45260E+00 -0.3443 8 H4SiO4 0.48260E-03 -3.3164 0.48260E-03 -3.3164 0.10000E+01 0.0000 9 Ca++ 0.12385E-07 -7.9071 0.86179E-08 -8.0646 0.69582E+00 -0.1575 10 Mg++ 0.47265E-10 -10.3255 0.32843E-10 -10.4836 0.69487E+00 -0.1581 11 Fe++ 0.27948E-12 -12.5536 0.19427E-12 -12.7116 0.69510E+00 -0.1580 12 K+ 0.42246E-04 -4.3742 0.38074E-04 -4.4194 0.90125E+00 -0.0452 13 Na+ 0.47158E-02 -2.3264 0.42477E-02 -2.3718 0.90075E+00 -0.0454 14 Mn++ 0.37337E-10 -10.4279 0.25959E-10 -10.5857 0.69527E+00 -0.1578 15 HPO4-- 0.68043E-05 -5.1672 0.47450E-05 -5.3238 0.69735E+00 -0.1565 16 HSiO3- 0.19708E-02 -2.7054 0.17753E-02 -2.7507 0.90079E+00 -0.0454 17 Ca(HSiO3)+ 0.38031E-09 -9.4199 0.34278E-09 -9.4650 0.90131E+00 -0.0451 18 Mg(HSiO3)+ 0.18038E-11 -11.7438 0.16258E-11 -11.7889 0.90131E+00 -0.0451 19 NaHSiO3,aq 0.11977E-03 -3.9217 0.11977E-03 -3.9217 0.10000E+01 0.0000 20 AlO+ 0.87117E-14 -14.0599 0.78520E-14 -14.1050 0.90131E+00 -0.0451 21 AlOH+2 0.15000E-19 -19.8239 0.10432E-19 -19.9816 0.69547E+00 -0.1577 22 HAlO2,aq 0.59242E-08 -8.2274 0.59242E-08 -8.2274 0.10000E+01 0.0000 23 AlO2- 0.55397E-04 -4.2565 0.49874E-04 -4.3021 0.90030E+00 -0.0456 24 CH4,aq 0.29124E-19 -19.5357 0.29099E-19 -19.5361 0.99912E+00 -0.0004 29 CO,aq 0.81140E-19 -19.0908 0.81140E-19 -19.0908 0.10000E+01 0.0000 30 CO2,aq 0.43468E-08 -8.3618 0.43430E-08 -8.3622 0.99912E+00 -0.0004 31 CO3-2 0.40627E-05 -5.3912 0.28312E-05 -5.5480 0.69688E+00 -0.1568 32 CaCO3,aq 0.29883E-09 -9.5246 0.29883E-09 -9.5246 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.19567E-11 -11.7085 0.17636E-11 -11.7536 0.90131E+00 -0.0451 34 CaCl+ 0.18926E-11 -11.7229 0.17059E-11 -11.7681 0.90131E+00 -0.0451 35 CaCl2,aq 0.49339E-16 -16.3068 0.49339E-16 -16.3068 0.10000E+01 0.0000 36 CaOH+ 0.25420E-08 -8.5948 0.22911E-08 -8.6400 0.90131E+00 -0.0451 37 CaSO4,aq 0.47767E-10 -10.3209 0.47767E-10 -10.3209 0.10000E+01 0.0000 38 HCl,aq 0.61972E-14 -14.2078 0.61972E-14 -14.2078 0.10000E+01 0.0000 43 FeCl+ 0.41701E-16 -16.3799 0.37586E-16 -16.4250 0.90131E+00 -0.0451 46 FeO,aq 0.10920E-09 -9.9618 0.10920E-09 -9.9618 0.10000E+01 0.0000 47 FeOH+ 0.26941E-10 -10.5696 0.24282E-10 -10.6147 0.90131E+00 -0.0451 48 HFeO2- 0.49164E-08 -8.3084 0.44286E-08 -8.3537 0.90079E+00 -0.0454 49 FeO+ 0.24342E-14 -14.6136 0.21940E-14 -14.6588 0.90131E+00 -0.0451 51 FeO2- 0.68050E-08 -8.1672 0.61299E-08 -8.2125 0.90079E+00 -0.0454 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.72603E-09 -9.1390 0.72539E-09 -9.1394 0.99912E+00 -0.0004 54 KCl,aq 0.83744E-10 -10.0770 0.83744E-10 -10.0770 0.10000E+01 0.0000 55 KHSO4,aq 0.48072E-18 -18.3181 0.48072E-18 -18.3181 0.10000E+01 0.0000 56 KOH,aq 0.62581E-07 -7.2036 0.62581E-07 -7.2036 0.10000E+01 0.0000 57 KSO4- 0.11584E-07 -7.9361 0.10435E-07 -7.9815 0.90079E+00 -0.0454 58 MgCO3,aq 0.28458E-12 -12.5458 0.28458E-12 -12.5458 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.76041E-14 -14.1190 0.68536E-14 -14.1641 0.90131E+00 -0.0451 60 MgCl+ 0.65481E-14 -14.1839 0.59019E-14 -14.2290 0.90131E+00 -0.0451 61 MgOH+ 0.53671E-10 -10.2703 0.48374E-10 -10.3154 0.90131E+00 -0.0451 63 MnO,aq 0.38956E-09 -9.4094 0.38956E-09 -9.4094 0.10000E+01 0.0000 64 MnOH+ 0.33444E-09 -9.4757 0.30143E-09 -9.5208 0.90131E+00 -0.0451 65 MnO2-2 0.27481E-12 -12.5610 0.19151E-12 -12.7178 0.69688E+00 -0.1568 66 HMnO2- 0.12217E-10 -10.9130 0.11005E-10 -10.9584 0.90079E+00 -0.0454 69 MnCl+ 0.21654E-13 -13.6645 0.19517E-13 -13.7096 0.90131E+00 -0.0451 70 MnSO4,aq 0.13088E-12 -12.8831 0.13088E-12 -12.8831 0.10000E+01 0.0000 71 NaCl,aq 0.17229E-06 -6.7637 0.17229E-06 -6.7637 0.10000E+01 0.0000 72 NaOH,aq 0.70373E-05 -5.1526 0.70373E-05 -5.1526 0.10000E+01 0.0000 74 OH- 0.25120E-02 -2.6000 0.22616E-02 -2.6456 0.90030E+00 -0.0456 79 HPO3-2 0.15601E-16 -16.8069 0.10872E-16 -16.9637 0.69688E+00 -0.1568 82 H3PO4,aq 0.21489E-14 -14.6678 0.21489E-14 -14.6678 0.10000E+01 0.0000 83 H2PO4- 0.24487E-07 -7.6111 0.22064E-07 -7.6563 0.90104E+00 -0.0453 84 PO4-3 0.34017E-07 -7.4683 0.15624E-07 -7.8062 0.45929E+00 -0.3379 87 H2P2O7-2 0.54675E-16 -16.2622 0.38102E-16 -16.4191 0.69688E+00 -0.1568 88 HP2O7-3 0.65071E-13 -13.1866 0.29457E-13 -13.5308 0.45270E+00 -0.3442 89 P2O7-4 0.10970E-12 -12.9598 0.27399E-13 -13.5623 0.24976E+00 -0.6025 90 H2S,aq 0.51809E-16 -16.2856 0.51763E-16 -16.2860 0.99912E+00 -0.0004 97 SO3-2 0.25140E-14 -14.5996 0.17595E-14 -14.7546 0.69989E+00 -0.1550 98 HSO3- 0.30318E-16 -16.5183 0.27310E-16 -16.5637 0.90079E+00 -0.0454 99 HSO4- 0.48559E-11 -11.3137 0.43779E-11 -11.3587 0.90156E+00 -0.0450 Charge balance for all species = -.9293E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2939094E-09 -.4835387E-02 -.4871962E+01 0.0000 2 H2O 0.1000000E+01 0.5550879E+02 0.9996344E+06 0.0000 3 Cl- 0.1379012E-03 0.1380736E-03 0.4893297E+01 5.6706 4 SO4-- 0.2551121E-04 0.2552354E-04 0.2450918E+01 14.4029 5 HCO3- 0.9012105E-05 0.1307942E-04 0.7977718E+00 4.4860 6 HS- 0.7210711E-13 -.6944752E-09 -.2295911E-04 -3.6110 7 Al+++ 0.9453348E-26 0.5540251E-04 0.1494285E+01 2.3604 8 H4SiO4 0.4825968E-03 0.2573160E-02 0.2472280E+03 -3.3164 9 Ca++ 0.1238527E-07 0.1565802E-07 0.6273080E-03 11.0882 10 Mg++ 0.4726541E-10 0.1030384E-09 0.2504136E-05 8.6692 11 Fe++ 0.2794809E-12 0.1206124E-07 0.6733330E-03 6.4412 12 K+ 0.4224553E-04 0.4231978E-04 0.1654171E+01 5.1570 13 Na+ 0.4715751E-02 0.4842728E-02 0.1112918E+03 7.2045 14 Mn++ 0.3733747E-10 0.7739796E-09 0.4250502E-04 8.5671 15 HPO4-- 0.6804310E-05 0.6862815E-05 0.6584404E+00 13.8290 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6620446E-01 -.4831905E-02 -.6137256E-01 0.0000000E+00 2 H2O 0.5545812E+02 0.5546882E+02 -.1069442E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1363304E-03 0.2550516E-04 0.1108252E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1108259E-03 -.6939751E-09 -.1108252E-03 0.0000000E+00 7 Al+++ 0.1303971E-01 0.5536261E-04 0.1298434E-01 0.0000000E+00 8 H4SiO4 0.4164072E-01 0.2571307E-02 0.3906941E-01 0.0000000E+00 9 Ca++ 0.4613892E-02 0.1564674E-07 0.4613876E-02 0.0000000E+00 10 Mg++ 0.3173810E-02 0.1029642E-09 0.3173809E-02 0.0000000E+00 11 Fe++ 0.2851321E-02 0.1205256E-07 0.2851309E-02 0.0000000E+00 12 K+ 0.8490446E-03 0.4228930E-04 0.8067553E-03 0.0000000E+00 13 Na+ 0.5179790E-02 0.4839240E-02 0.3405500E-03 0.0000000E+00 14 Mn++ 0.6933705E-04 0.7734222E-09 0.6933627E-04 0.0000000E+00 15 HPO4-- 0.2366439E-04 0.6857873E-05 0.1680652E-04 0.0000000E+00 Chg. balance for solid moles: 0.5787E-17 Mass of aqueous solution: 0.999653E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.5602E-05 -5.252 0.2814E-02 -2.551 0.6508E-01 0.8942E-03 clinochlore 0.6348E-03 -3.197 0.3528 -0.452 8.160 0.1342 daphnite 0.3929E-03 -3.406 0.2804 -0.552 6.484 0.8496E-01 chlorite-Mn 0.1387E-04 -4.858 0.9831E-02 -2.007 0.2274 0.3133E-02 hematite 0.2934E-03 -3.533 0.4686E-01 -1.329 1.084 0.8881E-02 microcline 0.8068E-03 -3.093 0.2246 -0.649 5.193 0.8772E-01 paragonite 0.2911E-03 -3.536 0.1113 -0.954 2.573 0.3846E-01 stilbite 0.4586E-02 -2.339 3.232 0.509 74.74 1.507 nontronite-Na 0.1499E-03 -3.824 0.6375E-01 -1.196 1.474 0.1980E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4.323990 g Volume = 1.885392 cm3 Porosity: 27.4738% V(tot) - V(min): 0.71421E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3.9990000 g log = 0.6020 Original solution: 1000.0103000 g Original solution / Rock added: 250.07 (Water/Rock Ratio), log = 2.3981 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.4692E-06 1.0073 0.4971E-06 0.4935E-06 CH4,gas 0.4319E-16 1.0129 0.4602E-16 0.4543E-16 H2,gas 0.9453E-06 1.0006 0.9949E-06 0.9944E-06 H2S,gas 0.1441E-14 0.9959 0.1510E-14 0.1516E-14 S2,gas 0.8198E-37 1.0000 0.8624E-37 0.8624E-37 CO,gas 0.1218E-15 1.0000 0.1281E-15 0.1281E-15 SO3,gas 0.4448E-39 1.0000 0.4679E-39 0.4679E-39 SO2,gas 0.1674E-22 1.0000 0.1761E-22 0.1761E-22 HCl,gas 0.1040E-16 1.0000 0.1094E-16 0.1094E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 121 paragonite 4.34 4.34 0.00 0.000 -0.28814E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 0.22748E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.67 -8.30 -2.768 0.14178E+05 -6.304 3 CH4,gas 4.81 -13.53 -18.34 -4.584 0.31310E+05 -16.337 4 H2,gas 8.29 0.28 -8.00 -4.573 0.13664E+05 -6.002 5 H2S,gas -5.94 -22.76 -16.82 -8.411 0.28722E+05 -14.821 6 S2,gas -7.03 -46.10 -39.06 -6.010 0.66701E+05 -37.064 7 CO,gas 3.51 -14.38 -17.89 -5.505 0.30551E+05 -15.892 8 SO3,gas 17.43 -23.90 -41.33 -10.332 0.70570E+05 -39.330 9 SO2,gas 1.14 -23.62 -24.75 -6.601 0.42267E+05 -22.754 10 HCl,gas 5.48 -13.48 -18.96 -9.480 0.32375E+05 -16.961 11 acmite 7.74 6.87 -0.87 -0.090 0.14802E+04 15 albite-high 0.75 -0.38 -1.13 -0.087 0.19361E+04 16 albite -0.33 -0.38 -0.06 -0.004 0.95453E+02 19 spessartine 24.55 20.47 -4.08 -0.204 0.69615E+04 20 analcite 3.37 2.93 -0.44 -0.049 0.74870E+03 21 andalusite 5.06 1.40 -3.66 -0.366 0.62458E+04 22 andradite 39.09 35.91 -3.17 -0.165 0.54210E+04 23 grossular 32.83 28.04 -4.79 -0.240 0.81823E+04 26 annite 20.21 16.89 -3.32 -0.184 0.56648E+04 27 phlogopite 27.15 23.58 -3.57 -0.198 0.60970E+04 29 anorthite 12.80 9.18 -3.62 -0.279 0.61835E+04 35 aragonite 0.99 -3.58 -4.56 -1.522 0.77943E+04 36 brucite 12.58 8.67 -3.91 -0.781 0.66718E+04 37 calcite 0.83 -3.58 -4.41 -1.471 0.75329E+04 38 carnegieite-low 9.06 6.25 -2.82 -0.402 0.48082E+04 39 carnegieite-high 10.13 6.25 -3.89 -0.555 0.66351E+04 40 carpholite-Mg 8.65 6.76 -1.89 -0.126 0.32324E+04 41 carpholite-Fe 6.78 4.53 -2.25 -0.150 0.38481E+04 42 celadonite 5.40 2.92 -2.48 -0.146 0.42337E+04 43 celadonite-Fe 3.94 0.69 -3.24 -0.191 0.55390E+04 44 chrysotile 23.94 19.37 -4.56 -0.380 0.77904E+04 50 chloritoid-Mg 13.26 10.07 -3.19 -0.213 0.54427E+04 51 chloritoid-Fe 9.24 7.85 -1.39 -0.093 0.23786E+04 52 chloritoid-Mn 11.46 9.97 -1.49 -0.099 0.25470E+04 54 coesite -2.37 -3.32 -0.95 -0.316 0.16171E+04 59 corundum 8.43 4.72 -3.71 -0.338 0.63390E+04 61 cristobalite -2.55 -3.32 -0.77 -0.256 0.13100E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.36 -0.54 -0.089 0.91460E+03 67 diopside 16.22 13.12 -3.09 -0.309 0.52777E+04 68 hedenbergite 14.24 10.90 -3.35 -0.335 0.57165E+04 75 epidote 24.78 23.25 -1.53 -0.074 0.26098E+04 76 clinozoisite 22.92 19.31 -3.61 -0.164 0.61686E+04 77 epidote-Fe 29.94 27.19 -2.75 -0.143 0.46983E+04 78 fayalite 14.08 9.57 -4.51 -0.645 0.77059E+04 79 ferrosilite 11.19 6.25 -4.94 -0.494 0.84319E+04 83 gibbsite 4.10 2.36 -1.74 -0.248 0.29658E+04 84 glaucophane 23.11 18.61 -4.50 -0.122 0.76909E+04 87 greenalite 16.19 12.69 -3.50 -0.292 0.59822E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.93 -1.32 -0.132 0.22517E+04 97 kalsilite 7.62 4.20 -3.42 -0.488 0.58382E+04 98 kaolinite -1.27 -1.91 -0.64 -0.058 0.10907E+04 99 kyanite 4.93 1.40 -3.53 -0.353 0.60225E+04 101 laumontite 2.97 2.54 -0.43 -0.029 0.73618E+03 102 lawsonite 9.68 9.18 -0.50 -0.033 0.85741E+03 103 leucite 4.17 0.88 -3.28 -0.328 0.56057E+04 105 lizardite 23.29 19.37 -3.91 -0.326 0.66807E+04 107 magnetite 20.13 19.04 -1.09 -0.089 0.18680E+04 108 minnesotaite 10.46 6.06 -4.40 -0.259 0.75179E+04 110 magnesioferrite 26.26 21.27 -4.99 -0.407 0.85211E+04 113 margarite 17.45 13.90 -3.55 -0.142 0.60695E+04 120 muscovite 2.68 2.29 -0.39 -0.023 0.66608E+03 122 nepheline 8.38 6.25 -2.13 -0.304 0.36362E+04 134 phlogopite-Na 29.73 25.62 -4.11 -0.228 0.70143E+04 136 prehnite 19.47 16.95 -2.52 -0.148 0.43000E+04 137 prehnite-Fe 22.59 20.89 -1.70 -0.102 0.29034E+04 138 pumpellyite-Fe 46.47 42.70 -3.77 -0.084 0.64423E+04 139 pumpellyite-Mg 49.19 44.93 -4.27 -0.095 0.72883E+04 145 pyroxmangite 7.42 5.25 -2.17 -0.433 0.36973E+04 146 pyrophyllite -6.10 -8.54 -2.45 -0.153 0.41777E+04 147 quartz -2.98 -3.32 -0.33 -0.111 0.57101E+03 152 rhodonite 7.46 5.25 -2.21 -0.442 0.37766E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.40 -3.92 -0.392 0.66879E+04 164 stilpnomelane-Fe 13.18 12.97 -0.21 -0.006 0.35088E+03 165 stilpnomelane-Mg 27.60 24.11 -3.48 -0.104 0.59457E+04 168 sudoite 21.22 16.83 -4.39 -0.141 0.74877E+04 171 talc 16.55 12.74 -3.81 -0.224 0.65079E+04 174 tephroite 18.11 13.82 -4.30 -0.614 0.73339E+04 177 topaz-H 4.67 1.40 -3.26 -0.297 0.55716E+04 178 tridymite -2.61 -3.32 -0.70 -0.234 0.11983E+04 187 wairakite 4.06 2.54 -1.52 -0.089 0.25870E+04 188 walstromite 11.53 7.77 -3.76 -0.751 0.64135E+04 189 wollastonite 10.48 7.77 -2.71 -0.542 0.46274E+04 190 pseudo-wollastonite 11.02 7.77 -3.25 -0.650 0.55460E+04 191 zoisite 22.96 19.31 -3.66 -0.166 0.62412E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.84 -3.28 -0.203 0.56042E+04 194 beidellite-H -2.24 -6.67 -4.43 -0.283 0.75646E+04 195 beidellite-K -1.44 -4.97 -3.53 -0.216 0.60352E+04 196 beidellite-Mg -1.71 -5.24 -3.53 -0.219 0.60344E+04 197 beidellite-Na -1.26 -4.29 -3.04 -0.186 0.51854E+04 199 chalcedony -2.79 -3.32 -0.52 -0.174 0.89132E+03 201 montmorillonite-Ca -2.21 -4.63 -2.42 -0.150 0.41309E+04 202 montmorillonite-K -2.16 -4.76 -2.60 -0.159 0.44396E+04 203 montmorillonite-Mg -2.40 -5.03 -2.63 -0.163 0.44921E+04 204 montmorillonite-Na -1.96 -4.09 -2.12 -0.130 0.36280E+04 205 nontronite-Ca 3.28 3.03 -0.24 -0.016 0.41797E+03 206 nontronite-H 2.60 1.21 -1.39 -0.093 0.23741E+04 207 nontronite-K 3.40 2.91 -0.50 -0.032 0.84808E+03 208 nontronite-Mg 3.14 2.64 -0.50 -0.033 0.85973E+03 224 tobermorite 9.84 5.92 -3.92 -1.069 0.66916E+04 233 boehmite 4.43 2.36 -2.07 -0.345 0.35330E+04 235 ferrous-oxide 9.82 6.44 -3.38 -0.846 0.57765E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.412 0.21115E+04 242 an20ab80 2.08 1.53 -0.55 -0.042 0.94146E+03 243 an25ab75 2.71 2.01 -0.70 -0.054 0.12009E+04 244 an30ab70 3.34 2.48 -0.86 -0.066 0.14686E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 3.9990000 g New total amount of reactant added: 4.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.9360E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 4.1990000 Water: Moles liquid = 0.5547E+02 kg liquid = 0.9992E+00 Moles total = 0.5546E+02 kg total = 0.9991E+00 Activity = 1.0000 Stoichiometric ionic strength = .2953511E-02 Osmotic coef. = 0.9701 True ionic strength = .5013848E-02 Chg. balance for total moles = -.9360E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.28048E-09 -9.5521 0.25268E-09 -9.5974 0.90088E+00 -0.0453 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12400E-03 -3.9066 0.89919E+00 -0.0461 4 SO4-- 0.25512E-04 -4.5933 0.17667E-04 -4.7528 0.69248E+00 -0.1596 5 HCO3- 0.88607E-05 -5.0525 0.79710E-05 -5.0985 0.89959E+00 -0.0460 6 HS- 0.76143E-13 -13.1184 0.68470E-13 -13.1645 0.89923E+00 -0.0461 7 Al+++ 0.81020E-26 -26.0914 0.36094E-26 -26.4426 0.44549E+00 -0.3512 8 H4SiO4 0.47967E-03 -3.3191 0.47967E-03 -3.3191 0.10000E+01 0.0000 9 Ca++ 0.12410E-07 -7.9062 0.85740E-08 -8.0668 0.69092E+00 -0.1606 10 Mg++ 0.43792E-10 -10.3586 0.30214E-10 -10.5198 0.68994E+00 -0.1612 11 Fe++ 0.25894E-12 -12.5868 0.17871E-12 -12.7478 0.69017E+00 -0.1610 12 K+ 0.42084E-04 -4.3759 0.37862E-04 -4.4218 0.89967E+00 -0.0459 13 Na+ 0.49354E-02 -2.3067 0.44377E-02 -2.3528 0.89915E+00 -0.0462 14 Mn++ 0.34593E-10 -10.4610 0.23881E-10 -10.6219 0.69035E+00 -0.1609 15 HPO4-- 0.64779E-05 -5.1886 0.44860E-05 -5.3481 0.69251E+00 -0.1596 16 HSiO3- 0.20598E-02 -2.6862 0.18522E-02 -2.7323 0.89919E+00 -0.0461 17 Ca(HSiO3)+ 0.39546E-09 -9.4029 0.35581E-09 -9.4488 0.89973E+00 -0.0459 18 Mg(HSiO3)+ 0.17343E-11 -11.7609 0.15604E-11 -11.8068 0.89973E+00 -0.0459 19 NaHSiO3,aq 0.13054E-03 -3.8842 0.13054E-03 -3.8842 0.10000E+01 0.0000 20 AlO+ 0.81115E-14 -14.0909 0.72981E-14 -14.1368 0.89973E+00 -0.0459 21 AlOH+2 0.13377E-19 -19.8736 0.92376E-20 -20.0344 0.69056E+00 -0.1608 22 HAlO2,aq 0.57798E-08 -8.2381 0.57798E-08 -8.2381 0.10000E+01 0.0000 23 AlO2- 0.56834E-04 -4.2454 0.51076E-04 -4.2918 0.89868E+00 -0.0464 24 CH4,aq 0.30342E-19 -19.5180 0.30314E-19 -19.5184 0.99909E+00 -0.0004 29 CO,aq 0.77945E-19 -19.1082 0.77945E-19 -19.1082 0.10000E+01 0.0000 30 CO2,aq 0.40645E-08 -8.3910 0.40608E-08 -8.3914 0.99909E+00 -0.0004 31 CO3-2 0.42148E-05 -5.3752 0.29167E-05 -5.5351 0.69202E+00 -0.1599 32 CaCO3,aq 0.30629E-09 -9.5139 0.30629E-09 -9.5139 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.19140E-11 -11.7181 0.17221E-11 -11.7640 0.89973E+00 -0.0459 34 CaCl+ 0.18829E-11 -11.7252 0.16941E-11 -11.7711 0.89973E+00 -0.0459 35 CaCl2,aq 0.48911E-16 -16.3106 0.48911E-16 -16.3106 0.10000E+01 0.0000 36 CaOH+ 0.26594E-08 -8.5752 0.23927E-08 -8.6211 0.89973E+00 -0.0459 37 CaSO4,aq 0.47196E-10 -10.3261 0.47196E-10 -10.3261 0.10000E+01 0.0000 38 HCl,aq 0.58933E-14 -14.2296 0.58933E-14 -14.2296 0.10000E+01 0.0000 43 FeCl+ 0.38361E-16 -16.4161 0.34514E-16 -16.4620 0.89973E+00 -0.0459 46 FeO,aq 0.11069E-09 -9.9559 0.11069E-09 -9.9559 0.10000E+01 0.0000 47 FeOH+ 0.26061E-10 -10.5840 0.23448E-10 -10.6299 0.89973E+00 -0.0459 48 HFeO2- 0.52401E-08 -8.2807 0.47119E-08 -8.3268 0.89919E+00 -0.0461 49 FeO+ 0.23231E-14 -14.6339 0.20902E-14 -14.6798 0.89973E+00 -0.0459 51 FeO2- 0.71557E-08 -8.1453 0.64344E-08 -8.1915 0.89919E+00 -0.0461 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.74594E-09 -9.1273 0.74526E-09 -9.1277 0.99909E+00 -0.0004 54 KCl,aq 0.83127E-10 -10.0803 0.83127E-10 -10.0803 0.10000E+01 0.0000 55 KHSO4,aq 0.45227E-18 -18.3446 0.45227E-18 -18.3446 0.10000E+01 0.0000 56 KOH,aq 0.65323E-07 -7.1849 0.65323E-07 -7.1849 0.10000E+01 0.0000 57 KSO4- 0.11461E-07 -7.9408 0.10305E-07 -7.9869 0.89919E+00 -0.0461 58 MgCO3,aq 0.26970E-12 -12.5691 0.26970E-12 -12.5691 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.68777E-14 -14.1626 0.61881E-14 -14.2084 0.89973E+00 -0.0459 60 MgCl+ 0.60236E-14 -14.2201 0.54196E-14 -14.2660 0.89973E+00 -0.0459 61 MgOH+ 0.51917E-10 -10.2847 0.46711E-10 -10.3306 0.89973E+00 -0.0459 63 MnO,aq 0.39486E-09 -9.4036 0.39486E-09 -9.4036 0.10000E+01 0.0000 64 MnOH+ 0.32352E-09 -9.4901 0.29108E-09 -9.5360 0.89973E+00 -0.0459 65 MnO2-2 0.30907E-12 -12.5099 0.21388E-12 -12.6698 0.69202E+00 -0.1599 66 HMnO2- 0.13022E-10 -10.8853 0.11709E-10 -10.9315 0.89919E+00 -0.0461 69 MnCl+ 0.19919E-13 -13.7007 0.17922E-13 -13.7466 0.89973E+00 -0.0459 70 MnSO4,aq 0.11957E-12 -12.9224 0.11957E-12 -12.9224 0.10000E+01 0.0000 71 NaCl,aq 0.17967E-06 -6.7455 0.17967E-06 -6.7455 0.10000E+01 0.0000 72 NaOH,aq 0.77171E-05 -5.1125 0.77171E-05 -5.1125 0.10000E+01 0.0000 74 OH- 0.26416E-02 -2.5781 0.23739E-02 -2.6245 0.89868E+00 -0.0464 79 HPO3-2 0.15259E-16 -16.8165 0.10560E-16 -16.9763 0.69202E+00 -0.1599 82 H3PO4,aq 0.18439E-14 -14.7343 0.18439E-14 -14.7343 0.10000E+01 0.0000 83 H2PO4- 0.22094E-07 -7.6557 0.19873E-07 -7.7017 0.89945E+00 -0.0460 84 PO4-3 0.34277E-07 -7.4650 0.15505E-07 -7.8095 0.45234E+00 -0.3445 87 H2P2O7-2 0.44664E-16 -16.3500 0.30909E-16 -16.5099 0.69202E+00 -0.1599 88 HP2O7-3 0.56293E-13 -13.2495 0.25083E-13 -13.6006 0.44558E+00 -0.3511 89 P2O7-4 0.10082E-12 -12.9965 0.24489E-13 -13.6110 0.24290E+00 -0.6146 90 H2S,aq 0.52029E-16 -16.2838 0.51981E-16 -16.2842 0.99909E+00 -0.0004 97 SO3-2 0.25825E-14 -14.5880 0.17952E-14 -14.7459 0.69513E+00 -0.1579 98 HSO3- 0.29522E-16 -16.5299 0.26546E-16 -16.5760 0.89919E+00 -0.0461 99 HSO4- 0.46022E-11 -11.3370 0.41419E-11 -11.3828 0.89999E+00 -0.0458 Charge balance for all species = -.9354E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2804792E-09 -.5071319E-02 -.5109601E+01 0.0000 2 H2O 0.1000000E+01 0.5550882E+02 0.9996200E+06 0.0000 3 Cl- 0.1378987E-03 0.1380784E-03 0.4893395E+01 5.6908 4 SO4-- 0.2551223E-04 0.2552448E-04 0.2450971E+01 14.4420 5 HCO3- 0.8860671E-05 0.1307988E-04 0.7977878E+00 4.4989 6 HS- 0.7614284E-13 -.7333365E-09 -.2424349E-04 -3.5671 7 Al+++ 0.8102039E-26 0.5683963E-04 0.1533023E+01 2.3497 8 H4SiO4 0.4796741E-03 0.2670044E-02 0.2565327E+03 -3.3191 9 Ca++ 0.1240959E-07 0.1582169E-07 0.6338558E-03 11.1281 10 Mg++ 0.4379195E-10 0.9772623E-10 0.2374998E-05 8.6751 11 Fe++ 0.2589389E-12 0.1273632E-07 0.7110091E-03 6.4470 12 K+ 0.4208412E-04 0.4216098E-04 0.1647939E+01 5.1756 13 Na+ 0.4935415E-02 0.5073855E-02 0.1166016E+03 7.2446 14 Mn++ 0.3459281E-10 0.7664359E-09 0.4209011E-04 8.5729 15 HPO4-- 0.6477866E-05 0.6534238E-05 0.6269062E+00 13.8467 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6951617E-01 -.5067489E-02 -.6444868E-01 0.0000000E+00 2 H2O 0.5545561E+02 0.5546691E+02 -.1129249E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1418731E-03 0.2550520E-04 0.1163679E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1163686E-03 -.7327827E-09 -.1163679E-03 0.0000000E+00 7 Al+++ 0.1369185E-01 0.5679671E-04 0.1363506E-01 0.0000000E+00 8 H4SiO4 0.4372328E-01 0.2668027E-02 0.4105525E-01 0.0000000E+00 9 Ca++ 0.4843920E-02 0.1580975E-07 0.4843904E-02 0.0000000E+00 10 Mg++ 0.3332540E-02 0.9765243E-10 0.3332540E-02 0.0000000E+00 11 Fe++ 0.2993923E-02 0.1272670E-07 0.2993910E-02 0.0000000E+00 12 K+ 0.8915074E-03 0.4212915E-04 0.8493783E-03 0.0000000E+00 13 Na+ 0.5430839E-02 0.5070024E-02 0.3608153E-03 0.0000000E+00 14 Mn++ 0.7280476E-04 0.7658571E-09 0.7280400E-04 0.0000000E+00 15 HPO4-- 0.2484790E-04 0.6529303E-05 0.1831860E-04 0.0000000E+00 Chg. balance for solid moles: 0.1540E-16 Mass of aqueous solution: 0.999633E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 4.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6106E-05 -5.214 0.3067E-02 -2.513 0.6753E-01 0.9747E-03 clinochlore 0.6665E-03 -3.176 0.3705 -0.431 8.156 0.1409 daphnite 0.4126E-03 -3.384 0.2944 -0.531 6.481 0.8921E-01 chlorite-Mn 0.1456E-04 -4.837 0.1032E-01 -1.986 0.2273 0.3290E-02 hematite 0.2975E-03 -3.526 0.4752E-01 -1.323 1.046 0.9006E-02 microcline 0.8494E-03 -3.071 0.2364 -0.626 5.205 0.9235E-01 paragonite 0.3054E-03 -3.515 0.1167 -0.933 2.570 0.4035E-01 stilbite 0.4813E-02 -2.318 3.392 0.530 74.68 1.582 nontronite-Na 0.1679E-03 -3.775 0.7142E-01 -1.146 1.572 0.2219E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4.542397 g Volume = 1.980404 cm3 Porosity: 26.0933% V(tot) - V(min): 0.69920E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4.1990000 g log = 0.6231 Original solution: 1000.0103000 g Original solution / Rock added: 238.15 (Water/Rock Ratio), log = 2.3769 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.4387E-06 1.0073 0.4648E-06 0.4615E-06 CH4,gas 0.4499E-16 1.0129 0.4794E-16 0.4733E-16 H2,gas 0.9712E-06 1.0006 0.1022E-05 0.1022E-05 H2S,gas 0.1447E-14 0.9959 0.1516E-14 0.1522E-14 S2,gas 0.7833E-37 1.0000 0.8239E-37 0.8239E-37 CO,gas 0.1170E-15 1.0000 0.1231E-15 0.1231E-15 SO3,gas 0.4009E-39 1.0000 0.4217E-39 0.4217E-39 SO2,gas 0.1550E-22 1.0000 0.1631E-22 0.1631E-22 HCl,gas 0.9892E-17 1.0000 0.1041E-16 0.1041E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 0.60662E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.70 -8.33 -2.778 0.14228E+05 -6.333 3 CH4,gas 4.81 -13.51 -18.32 -4.580 0.31280E+05 -16.319 4 H2,gas 8.29 0.30 -7.99 -4.566 0.13644E+05 -5.990 5 H2S,gas -5.94 -22.76 -16.82 -8.410 0.28718E+05 -14.819 6 S2,gas -7.03 -46.12 -39.08 -6.013 0.66735E+05 -37.084 7 CO,gas 3.51 -14.40 -17.91 -5.511 0.30581E+05 -15.910 8 SO3,gas 17.43 -23.95 -41.38 -10.344 0.70647E+05 -39.375 9 SO2,gas 1.14 -23.65 -24.79 -6.610 0.42324E+05 -22.788 10 HCl,gas 5.48 -13.50 -18.98 -9.491 0.32412E+05 -16.983 11 acmite 7.74 6.91 -0.83 -0.086 0.14208E+04 15 albite-high 0.75 -0.36 -1.11 -0.086 0.18995E+04 16 albite -0.33 -0.36 -0.03 -0.003 0.58869E+02 19 spessartine 24.55 20.46 -4.09 -0.204 0.69815E+04 20 analcite 3.37 2.96 -0.41 -0.046 0.70761E+03 21 andalusite 5.06 1.38 -3.68 -0.368 0.62868E+04 22 andradite 39.09 36.02 -3.06 -0.159 0.52302E+04 23 grossular 32.83 28.13 -4.70 -0.235 0.80281E+04 26 annite 20.21 16.91 -3.30 -0.183 0.56347E+04 27 phlogopite 27.15 23.59 -3.55 -0.197 0.60669E+04 29 anorthite 12.80 9.19 -3.61 -0.278 0.61610E+04 35 aragonite 0.99 -3.57 -4.55 -1.518 0.77760E+04 36 brucite 12.58 8.68 -3.90 -0.780 0.66617E+04 37 calcite 0.83 -3.57 -4.40 -1.467 0.75146E+04 38 carnegieite-low 9.06 6.28 -2.79 -0.398 0.47626E+04 39 carnegieite-high 10.13 6.28 -3.86 -0.551 0.65895E+04 40 carpholite-Mg 8.65 6.74 -1.91 -0.128 0.32680E+04 41 carpholite-Fe 6.78 4.51 -2.27 -0.152 0.38837E+04 42 celadonite 5.40 2.92 -2.48 -0.146 0.42282E+04 43 celadonite-Fe 3.94 0.70 -3.24 -0.191 0.55335E+04 44 chrysotile 23.94 19.39 -4.55 -0.379 0.77694E+04 50 chloritoid-Mg 13.26 10.06 -3.21 -0.214 0.54737E+04 51 chloritoid-Fe 9.24 7.83 -1.41 -0.094 0.24096E+04 52 chloritoid-Mn 11.46 9.95 -1.51 -0.101 0.25781E+04 54 coesite -2.37 -3.32 -0.95 -0.317 0.16216E+04 59 corundum 8.43 4.70 -3.73 -0.339 0.63756E+04 61 cristobalite -2.55 -3.32 -0.77 -0.257 0.13145E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.35 -0.55 -0.091 0.93289E+03 67 diopside 16.22 13.17 -3.05 -0.305 0.52086E+04 68 hedenbergite 14.24 10.94 -3.31 -0.331 0.56474E+04 75 epidote 24.78 23.30 -1.48 -0.072 0.25236E+04 76 clinozoisite 22.92 19.35 -3.57 -0.162 0.61008E+04 77 epidote-Fe 29.94 27.25 -2.69 -0.140 0.45939E+04 78 fayalite 14.08 9.57 -4.50 -0.643 0.76904E+04 79 ferrosilite 11.19 6.26 -4.93 -0.493 0.84208E+04 83 gibbsite 4.10 2.35 -1.75 -0.250 0.29841E+04 84 glaucophane 23.11 18.66 -4.45 -0.120 0.75967E+04 87 greenalite 16.19 12.70 -3.49 -0.291 0.59612E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.96 -1.29 -0.129 0.22106E+04 97 kalsilite 7.62 4.21 -3.41 -0.488 0.58292E+04 98 kaolinite -1.27 -1.94 -0.67 -0.060 0.11363E+04 99 kyanite 4.93 1.38 -3.55 -0.355 0.60636E+04 101 laumontite 2.97 2.55 -0.42 -0.028 0.72267E+03 102 lawsonite 9.68 9.19 -0.49 -0.033 0.83489E+03 103 leucite 4.17 0.89 -3.28 -0.328 0.56012E+04 105 lizardite 23.29 19.39 -3.90 -0.325 0.66597E+04 107 magnetite 20.13 19.04 -1.09 -0.089 0.18580E+04 108 minnesotaite 10.46 6.06 -4.40 -0.259 0.75058E+04 110 magnesioferrite 26.26 21.27 -4.98 -0.407 0.85110E+04 113 margarite 17.45 13.89 -3.56 -0.143 0.60836E+04 120 muscovite 2.68 2.27 -0.41 -0.024 0.70266E+03 122 nepheline 8.38 6.28 -2.10 -0.300 0.35906E+04 134 phlogopite-Na 29.73 25.66 -4.07 -0.226 0.69477E+04 136 prehnite 19.47 17.00 -2.47 -0.145 0.42139E+04 137 prehnite-Fe 22.59 20.95 -1.64 -0.099 0.27990E+04 138 pumpellyite-Fe 46.47 42.79 -3.68 -0.082 0.62783E+04 139 pumpellyite-Mg 49.19 45.02 -4.17 -0.093 0.71243E+04 145 pyroxmangite 7.42 5.25 -2.16 -0.432 0.36918E+04 146 pyrophyllite -6.10 -8.58 -2.48 -0.155 0.42323E+04 147 quartz -2.98 -3.32 -0.34 -0.112 0.57551E+03 152 rhodonite 7.46 5.25 -2.21 -0.442 0.37711E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.38 -3.94 -0.394 0.67290E+04 164 stilpnomelane-Fe 13.18 12.97 -0.21 -0.006 0.35750E+03 165 stilpnomelane-Mg 27.60 24.11 -3.49 -0.104 0.59523E+04 168 sudoite 21.22 16.79 -4.42 -0.143 0.75543E+04 171 talc 16.55 12.75 -3.80 -0.224 0.64958E+04 174 tephroite 18.11 13.83 -4.29 -0.612 0.73184E+04 177 topaz-H 4.67 1.38 -3.29 -0.299 0.56127E+04 178 tridymite -2.61 -3.32 -0.70 -0.235 0.12028E+04 187 wairakite 4.06 2.55 -1.51 -0.089 0.25735E+04 188 walstromite 11.53 7.81 -3.72 -0.744 0.63499E+04 189 wollastonite 10.48 7.81 -2.67 -0.535 0.45638E+04 190 pseudo-wollastonite 11.02 7.81 -3.21 -0.642 0.54824E+04 191 zoisite 22.96 19.35 -3.62 -0.164 0.61733E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.87 -3.31 -0.205 0.56522E+04 194 beidellite-H -2.24 -6.71 -4.46 -0.285 0.76238E+04 195 beidellite-K -1.44 -5.00 -3.56 -0.218 0.60838E+04 196 beidellite-Mg -1.71 -5.27 -3.57 -0.221 0.60919E+04 197 beidellite-Na -1.26 -4.32 -3.06 -0.187 0.52220E+04 199 chalcedony -2.79 -3.32 -0.52 -0.175 0.89583E+03 201 montmorillonite-Ca -2.21 -4.65 -2.44 -0.151 0.41649E+04 202 montmorillonite-K -2.16 -4.78 -2.62 -0.160 0.44743E+04 203 montmorillonite-Mg -2.40 -5.06 -2.66 -0.164 0.45357E+04 204 montmorillonite-Na -1.96 -4.10 -2.14 -0.131 0.36507E+04 205 nontronite-Ca 3.28 3.03 -0.25 -0.016 0.42930E+03 206 nontronite-H 2.60 1.19 -1.40 -0.094 0.23967E+04 207 nontronite-K 3.40 2.90 -0.50 -0.032 0.86015E+03 208 nontronite-Mg 3.14 2.62 -0.52 -0.033 0.88065E+03 224 tobermorite 9.84 5.95 -3.89 -1.061 0.66393E+04 233 boehmite 4.43 2.35 -2.08 -0.347 0.35513E+04 235 ferrous-oxide 9.82 6.45 -3.38 -0.844 0.57665E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.413 0.21160E+04 242 an20ab80 2.08 1.55 -0.53 -0.041 0.90769E+03 243 an25ab75 2.71 2.03 -0.68 -0.053 0.11678E+04 244 an30ab70 3.34 2.50 -0.84 -0.065 0.14363E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 4.1990000 g New total amount of reactant added: 4.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.9361E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 4.3990000 Water: Moles liquid = 0.5546E+02 kg liquid = 0.9992E+00 Moles total = 0.5545E+02 kg total = 0.9990E+00 Activity = 1.0000 Stoichiometric ionic strength = .3074753E-02 Osmotic coef. = 0.9696 True ionic strength = .5232850E-02 Chg. balance for total moles = -.9361E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.26827E-09 -9.5714 0.24128E-09 -9.6175 0.89938E+00 -0.0461 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12378E-03 -3.9073 0.89763E+00 -0.0469 4 SO4-- 0.25513E-04 -4.5932 0.17548E-04 -4.7558 0.68780E+00 -0.1625 5 HCO3- 0.87135E-05 -5.0598 0.78251E-05 -5.1065 0.89805E+00 -0.0467 6 HS- 0.80195E-13 -13.0959 0.71989E-13 -13.1427 0.89768E+00 -0.0469 7 Al+++ 0.69976E-26 -26.1551 0.30696E-26 -26.5129 0.43867E+00 -0.3579 8 H4SiO4 0.47691E-03 -3.3216 0.47691E-03 -3.3216 0.10000E+01 0.0000 9 Ca++ 0.12436E-07 -7.9053 0.85333E-08 -8.0689 0.68619E+00 -0.1636 10 Mg++ 0.40729E-10 -10.3901 0.27907E-10 -10.5543 0.68518E+00 -0.1642 11 Fe++ 0.24083E-12 -12.6183 0.16507E-12 -12.7823 0.68542E+00 -0.1640 12 K+ 0.41934E-04 -4.3774 0.37662E-04 -4.4241 0.89813E+00 -0.0467 13 Na+ 0.51547E-02 -2.2878 0.46268E-02 -2.3347 0.89759E+00 -0.0469 14 Mn++ 0.32173E-10 -10.4925 0.22058E-10 -10.6564 0.68560E+00 -0.1639 15 HPO4-- 0.61816E-05 -5.2089 0.42519E-05 -5.3714 0.68783E+00 -0.1625 16 HSiO3- 0.21484E-02 -2.6679 0.19285E-02 -2.7148 0.89763E+00 -0.0469 17 Ca(HSiO3)+ 0.41050E-09 -9.3867 0.36870E-09 -9.4333 0.89819E+00 -0.0466 18 Mg(HSiO3)+ 0.16707E-11 -11.7771 0.15006E-11 -11.8237 0.89819E+00 -0.0466 19 NaHSiO3,aq 0.14171E-03 -3.8486 0.14171E-03 -3.8486 0.10000E+01 0.0000 20 AlO+ 0.75786E-14 -14.1204 0.68070E-14 -14.1670 0.89819E+00 -0.0466 21 AlOH+2 0.11997E-19 -19.9209 0.82274E-20 -20.0847 0.68582E+00 -0.1638 22 HAlO2,aq 0.56455E-08 -8.2483 0.56455E-08 -8.2483 0.10000E+01 0.0000 23 AlO2- 0.58238E-04 -4.2348 0.52245E-04 -4.2820 0.89711E+00 -0.0472 24 CH4,aq 0.31530E-19 -19.5013 0.31501E-19 -19.5017 0.99905E+00 -0.0004 29 CO,aq 0.74974E-19 -19.1251 0.74974E-19 -19.1251 0.10000E+01 0.0000 30 CO2,aq 0.38103E-08 -8.4190 0.38067E-08 -8.4195 0.99905E+00 -0.0004 31 CO3-2 0.43628E-05 -5.3602 0.29986E-05 -5.5231 0.68732E+00 -0.1628 32 CaCO3,aq 0.31339E-09 -9.5039 0.31339E-09 -9.5039 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.18732E-11 -11.7274 0.16825E-11 -11.7740 0.89819E+00 -0.0466 34 CaCl+ 0.18739E-11 -11.7273 0.16831E-11 -11.7739 0.89819E+00 -0.0466 35 CaCl2,aq 0.48509E-16 -16.3142 0.48509E-16 -16.3142 0.10000E+01 0.0000 36 CaOH+ 0.27765E-08 -8.5565 0.24938E-08 -8.6031 0.89819E+00 -0.0466 37 CaSO4,aq 0.46656E-10 -10.3311 0.46656E-10 -10.3311 0.10000E+01 0.0000 38 HCl,aq 0.56177E-14 -14.2504 0.56177E-14 -14.2504 0.10000E+01 0.0000 43 FeCl+ 0.35430E-16 -16.4506 0.31823E-16 -16.4973 0.89819E+00 -0.0466 46 FeO,aq 0.11212E-09 -9.9503 0.11212E-09 -9.9503 0.10000E+01 0.0000 47 FeOH+ 0.25251E-10 -10.5977 0.22681E-10 -10.6443 0.89819E+00 -0.0466 48 HFeO2- 0.55684E-08 -8.2543 0.49984E-08 -8.3012 0.89763E+00 -0.0469 49 FeO+ 0.22221E-14 -14.6532 0.19959E-14 -14.6999 0.89819E+00 -0.0466 51 FeO2- 0.75067E-08 -8.1246 0.67383E-08 -8.1715 0.89763E+00 -0.0469 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.76543E-09 -9.1161 0.76471E-09 -9.1165 0.99905E+00 -0.0004 54 KCl,aq 0.82545E-10 -10.0833 0.82545E-10 -10.0833 0.10000E+01 0.0000 55 KHSO4,aq 0.42671E-18 -18.3699 0.42671E-18 -18.3699 0.10000E+01 0.0000 56 KOH,aq 0.68049E-07 -7.1672 0.68049E-07 -7.1672 0.10000E+01 0.0000 57 KSO4- 0.11343E-07 -7.9453 0.10182E-07 -7.9922 0.89763E+00 -0.0469 58 MgCO3,aq 0.25610E-12 -12.5916 0.25610E-12 -12.5916 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.62470E-14 -14.2043 0.56110E-14 -14.2510 0.89819E+00 -0.0466 60 MgCl+ 0.55634E-14 -14.2547 0.49970E-14 -14.3013 0.89819E+00 -0.0466 61 MgOH+ 0.50304E-10 -10.2984 0.45183E-10 -10.3450 0.89819E+00 -0.0466 63 MnO,aq 0.39997E-09 -9.3980 0.39997E-09 -9.3980 0.10000E+01 0.0000 64 MnOH+ 0.31346E-09 -9.5038 0.28155E-09 -9.5504 0.89819E+00 -0.0466 65 MnO2-2 0.34570E-12 -12.4613 0.23761E-12 -12.6241 0.68732E+00 -0.1628 66 HMnO2- 0.13838E-10 -10.8589 0.12421E-10 -10.9058 0.89763E+00 -0.0469 69 MnCl+ 0.18398E-13 -13.7352 0.16525E-13 -13.7819 0.89819E+00 -0.0466 70 MnSO4,aq 0.10970E-12 -12.9598 0.10970E-12 -12.9598 0.10000E+01 0.0000 71 NaCl,aq 0.18700E-06 -6.7281 0.18700E-06 -6.7281 0.10000E+01 0.0000 72 NaOH,aq 0.84261E-05 -5.0744 0.84261E-05 -5.0744 0.10000E+01 0.0000 74 OH- 0.27712E-02 -2.5573 0.24861E-02 -2.6045 0.89711E+00 -0.0472 79 HPO3-2 0.14942E-16 -16.8256 0.10270E-16 -16.9884 0.68732E+00 -0.1628 82 H3PO4,aq 0.15936E-14 -14.7976 0.15936E-14 -14.7976 0.10000E+01 0.0000 83 H2PO4- 0.20031E-07 -7.6983 0.17986E-07 -7.7451 0.89791E+00 -0.0468 84 PO4-3 0.34531E-07 -7.4618 0.15390E-07 -7.8128 0.44567E+00 -0.3510 87 H2P2O7-2 0.36836E-16 -16.4337 0.25318E-16 -16.5966 0.68732E+00 -0.1628 88 HP2O7-3 0.49040E-13 -13.3095 0.21517E-13 -13.6672 0.43877E+00 -0.3578 89 P2O7-4 0.93057E-13 -13.0312 0.22000E-13 -13.6576 0.23641E+00 -0.6263 90 H2S,aq 0.52238E-16 -16.2820 0.52188E-16 -16.2824 0.99905E+00 -0.0004 97 SO3-2 0.26496E-14 -14.5768 0.18297E-14 -14.7376 0.69054E+00 -0.1608 98 HSO3- 0.28781E-16 -16.5409 0.25835E-16 -16.5878 0.89763E+00 -0.0469 99 HSO4- 0.43725E-11 -11.3593 0.39285E-11 -11.4058 0.89846E+00 -0.0465 Charge balance for all species = -.9350E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2682732E-09 -.5307158E-02 -.5347140E+01 0.0000 2 H2O 0.1000000E+01 0.5550886E+02 0.9996056E+06 0.0000 3 Cl- 0.1378962E-03 0.1380833E-03 0.4893493E+01 5.7101 4 SO4-- 0.2551324E-04 0.2552541E-04 0.2451023E+01 14.4792 5 HCO3- 0.8713456E-05 0.1308034E-04 0.7978037E+00 4.5110 6 HS- 0.8019496E-13 -.7723338E-09 -.2553233E-04 -3.5253 7 Al+++ 0.6997609E-26 0.5824320E-04 0.1570855E+01 2.3395 8 H4SiO4 0.4769051E-03 0.2767006E-02 0.2658447E+03 -3.3216 9 Ca++ 0.1243577E-07 0.1598654E-07 0.6404504E-03 11.1661 10 Mg++ 0.4072925E-10 0.9297196E-10 0.2259423E-05 8.6807 11 Fe++ 0.2408262E-12 0.1341619E-07 0.7489518E-03 6.4526 12 K+ 0.4193436E-04 0.4201383E-04 0.1642163E+01 5.1934 13 Na+ 0.5154713E-02 0.5305040E-02 0.1219126E+03 7.2828 14 Mn++ 0.3217276E-10 0.7599217E-09 0.4173175E-04 8.5785 15 HPO4-- 0.6181583E-05 0.6236145E-05 0.5982978E+00 13.8635 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7282787E-01 -.5302964E-02 -.6752490E-01 0.0000000E+00 2 H2O 0.5545311E+02 0.5546500E+02 -.1189010E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1474158E-03 0.2550524E-04 0.1219105E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1219113E-03 -.7717236E-09 -.1219105E-03 0.0000000E+00 7 Al+++ 0.1434400E-01 0.5819718E-04 0.1428581E-01 0.0000000E+00 8 H4SiO4 0.4580583E-01 0.2764820E-02 0.4304101E-01 0.0000000E+00 9 Ca++ 0.5073949E-02 0.1597391E-07 0.5073933E-02 0.0000000E+00 10 Mg++ 0.3491270E-02 0.9289850E-10 0.3491270E-02 0.0000000E+00 11 Fe++ 0.3136525E-02 0.1340559E-07 0.3136511E-02 0.0000000E+00 12 K+ 0.9339703E-03 0.4198064E-04 0.8919896E-03 0.0000000E+00 13 Na+ 0.5681888E-02 0.5300848E-02 0.3810397E-03 0.0000000E+00 14 Mn++ 0.7627248E-04 0.7593213E-09 0.7627172E-04 0.0000000E+00 15 HPO4-- 0.2603142E-04 0.6231218E-05 0.1980020E-04 0.0000000E+00 Chg. balance for solid moles: 0.1963E-16 Mass of aqueous solution: 0.999613E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 4.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.6600E-05 -5.180 0.3315E-02 -2.479 0.6964E-01 0.1053E-02 clinochlore 0.6983E-03 -3.156 0.3881 -0.411 8.152 0.1476 daphnite 0.4322E-03 -3.364 0.3084 -0.511 6.478 0.9346E-01 chlorite-Mn 0.1525E-04 -4.817 0.1081E-01 -1.966 0.2272 0.3446E-02 hematite 0.3018E-03 -3.520 0.4819E-01 -1.317 1.012 0.9134E-02 microcline 0.8920E-03 -3.050 0.2483 -0.605 5.215 0.9698E-01 paragonite 0.3197E-03 -3.495 0.1222 -0.913 2.567 0.4224E-01 stilbite 0.5041E-02 -2.297 3.552 0.551 74.62 1.657 nontronite-Na 0.1859E-03 -3.731 0.7904E-01 -1.102 1.660 0.2456E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4.760801 g Volume = 2.075418 cm3 Porosity: 24.7928% V(tot) - V(min): 0.68418E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4.3990000 g log = 0.6434 Original solution: 1000.0103000 g Original solution / Rock added: 227.33 (Water/Rock Ratio), log = 2.3567 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.4112E-06 1.0073 0.4357E-06 0.4326E-06 CH4,gas 0.4675E-16 1.0129 0.4981E-16 0.4918E-16 H2,gas 0.9965E-06 1.0006 0.1049E-05 0.1048E-05 H2S,gas 0.1453E-14 0.9959 0.1522E-14 0.1528E-14 S2,gas 0.7499E-37 1.0000 0.7888E-37 0.7888E-37 CO,gas 0.1125E-15 1.0000 0.1184E-15 0.1184E-15 SO3,gas 0.3631E-39 1.0000 0.3819E-39 0.3819E-39 SO2,gas 0.1441E-22 1.0000 0.1515E-22 0.1515E-22 HCl,gas 0.9429E-17 1.0000 0.9919E-17 0.9919E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 0.18198E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.48529E-10 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.45496E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.72 -8.36 -2.787 0.14276E+05 -6.361 3 CH4,gas 4.81 -13.49 -18.30 -4.576 0.31251E+05 -16.303 4 H2,gas 8.29 0.31 -7.98 -4.560 0.13624E+05 -5.979 5 H2S,gas -5.94 -22.76 -16.82 -8.409 0.28716E+05 -14.818 6 S2,gas -7.03 -46.14 -39.10 -6.016 0.66767E+05 -37.103 7 CO,gas 3.51 -14.42 -17.93 -5.516 0.30609E+05 -15.927 8 SO3,gas 17.43 -23.99 -41.42 -10.355 0.70720E+05 -39.418 9 SO2,gas 1.14 -23.68 -24.82 -6.619 0.42379E+05 -22.819 10 HCl,gas 5.48 -13.52 -19.00 -9.502 0.32448E+05 -17.004 11 acmite 7.74 6.94 -0.80 -0.083 0.13642E+04 15 albite-high 0.75 -0.34 -1.09 -0.084 0.18647E+04 16 albite -0.33 -0.34 -0.01 -0.001 0.24004E+02 19 spessartine 24.55 20.45 -4.10 -0.205 0.70006E+04 20 analcite 3.37 2.98 -0.39 -0.043 0.66846E+03 21 andalusite 5.06 1.36 -3.70 -0.370 0.63260E+04 22 andradite 39.09 36.13 -2.96 -0.154 0.50483E+04 23 grossular 32.83 28.21 -4.62 -0.231 0.78811E+04 26 annite 20.21 16.93 -3.28 -0.182 0.56061E+04 27 phlogopite 27.15 23.61 -3.54 -0.196 0.60383E+04 29 anorthite 12.80 9.20 -3.60 -0.277 0.61395E+04 35 aragonite 0.99 -3.56 -4.54 -1.515 0.77590E+04 36 brucite 12.58 8.68 -3.90 -0.779 0.66522E+04 37 calcite 0.83 -3.56 -4.39 -1.464 0.74977E+04 38 carnegieite-low 9.06 6.30 -2.76 -0.395 0.47192E+04 39 carnegieite-high 10.13 6.30 -3.83 -0.548 0.65460E+04 40 carpholite-Mg 8.65 6.72 -1.93 -0.129 0.33019E+04 41 carpholite-Fe 6.78 4.49 -2.29 -0.153 0.39176E+04 42 celadonite 5.40 2.93 -2.47 -0.145 0.42229E+04 43 celadonite-Fe 3.94 0.70 -3.24 -0.190 0.55283E+04 44 chrysotile 23.94 19.40 -4.54 -0.378 0.77493E+04 50 chloritoid-Mg 13.26 10.04 -3.22 -0.215 0.55033E+04 51 chloritoid-Fe 9.24 7.81 -1.43 -0.095 0.24393E+04 52 chloritoid-Mn 11.46 9.94 -1.53 -0.102 0.26077E+04 54 coesite -2.37 -3.32 -0.95 -0.317 0.16259E+04 59 corundum 8.43 4.68 -3.75 -0.341 0.64105E+04 61 cristobalite -2.55 -3.32 -0.77 -0.257 0.13188E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.34 -0.56 -0.093 0.95032E+03 67 diopside 16.22 13.20 -3.01 -0.301 0.51427E+04 68 hedenbergite 14.24 10.98 -3.27 -0.327 0.55815E+04 75 epidote 24.78 23.35 -1.43 -0.069 0.24415E+04 76 clinozoisite 22.92 19.39 -3.54 -0.161 0.60361E+04 77 epidote-Fe 29.94 27.30 -2.63 -0.137 0.44944E+04 78 fayalite 14.08 9.58 -4.50 -0.642 0.76756E+04 79 ferrosilite 11.19 6.26 -4.93 -0.493 0.84103E+04 83 gibbsite 4.10 2.34 -1.76 -0.251 0.30015E+04 84 glaucophane 23.11 18.71 -4.40 -0.119 0.75069E+04 87 greenalite 16.19 12.71 -3.48 -0.290 0.59411E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.98 -1.27 -0.127 0.21715E+04 97 kalsilite 7.62 4.21 -3.41 -0.487 0.58206E+04 98 kaolinite -1.27 -1.96 -0.69 -0.063 0.11798E+04 99 kyanite 4.93 1.36 -3.57 -0.357 0.61028E+04 101 laumontite 2.97 2.56 -0.42 -0.028 0.70979E+03 102 lawsonite 9.68 9.20 -0.48 -0.032 0.81342E+03 103 leucite 4.17 0.89 -3.28 -0.328 0.55969E+04 105 lizardite 23.29 19.40 -3.89 -0.324 0.66396E+04 107 magnetite 20.13 19.05 -1.08 -0.088 0.18484E+04 108 minnesotaite 10.46 6.07 -4.39 -0.258 0.74943E+04 110 magnesioferrite 26.26 21.28 -4.98 -0.406 0.85015E+04 113 margarite 17.45 13.88 -3.57 -0.143 0.60970E+04 120 muscovite 2.68 2.25 -0.43 -0.025 0.73753E+03 122 nepheline 8.38 6.30 -2.08 -0.297 0.35471E+04 134 phlogopite-Na 29.73 25.70 -4.03 -0.224 0.68842E+04 136 prehnite 19.47 17.05 -2.42 -0.142 0.41318E+04 137 prehnite-Fe 22.59 21.01 -1.58 -0.095 0.26995E+04 138 pumpellyite-Fe 46.47 42.89 -3.59 -0.080 0.61220E+04 139 pumpellyite-Mg 49.19 45.11 -4.08 -0.091 0.69680E+04 145 pyroxmangite 7.42 5.26 -2.16 -0.432 0.36866E+04 146 pyrophyllite -6.10 -8.61 -2.51 -0.157 0.42844E+04 147 quartz -2.98 -3.32 -0.34 -0.113 0.57981E+03 152 rhodonite 7.46 5.26 -2.21 -0.441 0.37658E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.36 -3.96 -0.396 0.67682E+04 164 stilpnomelane-Fe 13.18 12.97 -0.21 -0.006 0.36381E+03 165 stilpnomelane-Mg 27.60 24.11 -3.49 -0.104 0.59586E+04 168 sudoite 21.22 16.75 -4.46 -0.144 0.76178E+04 171 talc 16.55 12.76 -3.80 -0.223 0.64844E+04 174 tephroite 18.11 13.84 -4.28 -0.611 0.73036E+04 177 topaz-H 4.67 1.36 -3.31 -0.301 0.56519E+04 178 tridymite -2.61 -3.32 -0.71 -0.236 0.12071E+04 187 wairakite 4.06 2.56 -1.50 -0.088 0.25606E+04 188 walstromite 11.53 7.84 -3.68 -0.737 0.62892E+04 189 wollastonite 10.48 7.84 -2.64 -0.527 0.45031E+04 190 pseudo-wollastonite 11.02 7.84 -3.18 -0.635 0.54218E+04 191 zoisite 22.96 19.39 -3.58 -0.163 0.61087E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.90 -3.34 -0.206 0.56978E+04 194 beidellite-H -2.24 -6.74 -4.50 -0.287 0.76801E+04 195 beidellite-K -1.44 -5.03 -3.59 -0.220 0.61302E+04 196 beidellite-Mg -1.71 -5.31 -3.60 -0.223 0.61467E+04 197 beidellite-Na -1.26 -4.34 -3.08 -0.189 0.52568E+04 199 chalcedony -2.79 -3.32 -0.53 -0.176 0.90012E+03 201 montmorillonite-Ca -2.21 -4.67 -2.46 -0.152 0.41973E+04 202 montmorillonite-K -2.16 -4.80 -2.64 -0.162 0.45075E+04 203 montmorillonite-Mg -2.40 -5.08 -2.68 -0.166 0.45772E+04 204 montmorillonite-Na -1.96 -4.11 -2.15 -0.132 0.36723E+04 205 nontronite-Ca 3.28 3.02 -0.26 -0.017 0.44009E+03 206 nontronite-H 2.60 1.18 -1.42 -0.095 0.24182E+04 207 nontronite-K 3.40 2.89 -0.51 -0.033 0.87165E+03 208 nontronite-Mg 3.14 2.61 -0.53 -0.034 0.90058E+03 224 tobermorite 9.84 5.98 -3.86 -1.053 0.65895E+04 233 boehmite 4.43 2.34 -2.09 -0.348 0.35688E+04 235 ferrous-oxide 9.82 6.45 -3.37 -0.843 0.57569E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.414 0.21203E+04 242 an20ab80 2.08 1.57 -0.51 -0.039 0.87550E+03 243 an25ab75 2.71 2.04 -0.67 -0.051 0.11363E+04 244 an30ab70 3.34 2.52 -0.82 -0.063 0.14054E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 4.3990000 g New total amount of reactant added: 4.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.9360E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 4.5990000 Water: Moles liquid = 0.5546E+02 kg liquid = 0.9992E+00 Moles total = 0.5545E+02 kg total = 0.9990E+00 Activity = 1.0000 Stoichiometric ionic strength = .3195937E-02 Osmotic coef. = 0.9691 True ionic strength = .5451518E-02 Chg. balance for total moles = -.9360E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.25713E-09 -9.5898 0.23089E-09 -9.6366 0.89793E+00 -0.0468 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13789E-03 -3.8605 0.12357E-03 -3.9081 0.89612E+00 -0.0476 4 SO4-- 0.25514E-04 -4.5932 0.17433E-04 -4.7586 0.68327E+00 -0.1654 5 HCO3- 0.85703E-05 -5.0670 0.76838E-05 -5.1144 0.89655E+00 -0.0474 6 HS- 0.84262E-13 -13.0744 0.75512E-13 -13.1220 0.89616E+00 -0.0476 7 Al+++ 0.60862E-26 -26.2157 0.26301E-26 -26.5800 0.43213E+00 -0.3644 8 H4SiO4 0.47428E-03 -3.3240 0.47428E-03 -3.3240 0.10000E+01 0.0000 9 Ca++ 0.12464E-07 -7.9044 0.84953E-08 -8.0708 0.68161E+00 -0.1665 10 Mg++ 0.38013E-10 -10.4201 0.25870E-10 -10.5872 0.68057E+00 -0.1671 11 Fe++ 0.22476E-12 -12.6483 0.15302E-12 -12.8152 0.68082E+00 -0.1670 12 K+ 0.41795E-04 -4.3789 0.37475E-04 -4.4263 0.89663E+00 -0.0474 13 Na+ 0.53736E-02 -2.2697 0.48152E-02 -2.3174 0.89608E+00 -0.0477 14 Mn++ 0.30026E-10 -10.5225 0.20448E-10 -10.6893 0.68101E+00 -0.1668 15 HPO4-- 0.59115E-05 -5.2283 0.40394E-05 -5.3937 0.68330E+00 -0.1654 16 HSiO3- 0.22365E-02 -2.6504 0.20042E-02 -2.6981 0.89612E+00 -0.0476 17 Ca(HSiO3)+ 0.42542E-09 -9.3712 0.38147E-09 -9.4185 0.89670E+00 -0.0474 18 Mg(HSiO3)+ 0.16123E-11 -11.7926 0.14457E-11 -11.8399 0.89670E+00 -0.0474 19 NaHSiO3,aq 0.15327E-03 -3.8145 0.15327E-03 -3.8145 0.10000E+01 0.0000 20 AlO+ 0.71029E-14 -14.1486 0.63692E-14 -14.1959 0.89670E+00 -0.0474 21 AlOH+2 0.10814E-19 -19.9660 0.73666E-20 -20.1327 0.68123E+00 -0.1667 22 HAlO2,aq 0.55202E-08 -8.2580 0.55202E-08 -8.2580 0.10000E+01 0.0000 23 AlO2- 0.59610E-04 -4.2247 0.53385E-04 -4.2726 0.89558E+00 -0.0479 24 CH4,aq 0.32691E-19 -19.4856 0.32659E-19 -19.4860 0.99901E+00 -0.0004 29 CO,aq 0.72202E-19 -19.1415 0.72202E-19 -19.1415 0.10000E+01 0.0000 30 CO2,aq 0.35804E-08 -8.4461 0.35769E-08 -8.4465 0.99901E+00 -0.0004 31 CO3-2 0.45066E-05 -5.3462 0.30770E-05 -5.5119 0.68278E+00 -0.1657 32 CaCO3,aq 0.32015E-09 -9.4946 0.32015E-09 -9.4946 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.18342E-11 -11.7365 0.16448E-11 -11.7839 0.89670E+00 -0.0474 34 CaCl+ 0.18655E-11 -11.7292 0.16728E-11 -11.7766 0.89670E+00 -0.0474 35 CaCl2,aq 0.48128E-16 -16.3176 0.48128E-16 -16.3176 0.10000E+01 0.0000 36 CaOH+ 0.28934E-08 -8.5386 0.25945E-08 -8.5860 0.89670E+00 -0.0474 37 CaSO4,aq 0.46144E-10 -10.3359 0.46144E-10 -10.3359 0.10000E+01 0.0000 38 HCl,aq 0.53665E-14 -14.2703 0.53665E-14 -14.2703 0.10000E+01 0.0000 43 FeCl+ 0.32844E-16 -16.4835 0.29451E-16 -16.5309 0.89670E+00 -0.0474 46 FeO,aq 0.11351E-09 -9.9450 0.11351E-09 -9.9450 0.10000E+01 0.0000 47 FeOH+ 0.24503E-10 -10.6108 0.21972E-10 -10.6581 0.89670E+00 -0.0474 48 HFeO2- 0.59010E-08 -8.2291 0.52880E-08 -8.2767 0.89612E+00 -0.0476 49 FeO+ 0.21300E-14 -14.6716 0.19099E-14 -14.7190 0.89670E+00 -0.0474 51 FeO2- 0.78579E-08 -8.1047 0.70416E-08 -8.1523 0.89612E+00 -0.0476 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.78452E-09 -9.1054 0.78375E-09 -9.1058 0.99901E+00 -0.0004 54 KCl,aq 0.81994E-10 -10.0862 0.81994E-10 -10.0862 0.10000E+01 0.0000 55 KHSO4,aq 0.40364E-18 -18.3940 0.40364E-18 -18.3940 0.10000E+01 0.0000 56 KOH,aq 0.70758E-07 -7.1502 0.70758E-07 -7.1502 0.10000E+01 0.0000 57 KSO4- 0.11232E-07 -7.9496 0.10065E-07 -7.9972 0.89612E+00 -0.0476 58 MgCO3,aq 0.24362E-12 -12.6133 0.24362E-12 -12.6133 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.56960E-14 -14.2444 0.51075E-14 -14.2918 0.89670E+00 -0.0474 60 MgCl+ 0.51573E-14 -14.2876 0.46245E-14 -14.3349 0.89670E+00 -0.0474 61 MgOH+ 0.48814E-10 -10.3115 0.43771E-10 -10.3588 0.89670E+00 -0.0474 63 MnO,aq 0.40492E-09 -9.3926 0.40492E-09 -9.3926 0.10000E+01 0.0000 64 MnOH+ 0.30418E-09 -9.5169 0.27275E-09 -9.5642 0.89670E+00 -0.0474 65 MnO2-2 0.38474E-12 -12.4148 0.26269E-12 -12.5806 0.68278E+00 -0.1657 66 HMnO2- 0.14664E-10 -10.8337 0.13141E-10 -10.8814 0.89612E+00 -0.0476 69 MnCl+ 0.17054E-13 -13.7682 0.15293E-13 -13.8155 0.89670E+00 -0.0474 70 MnSO4,aq 0.10103E-12 -12.9956 0.10103E-12 -12.9956 0.10000E+01 0.0000 71 NaCl,aq 0.19429E-06 -6.7116 0.19429E-06 -6.7116 0.10000E+01 0.0000 72 NaOH,aq 0.91640E-05 -5.0379 0.91640E-05 -5.0379 0.10000E+01 0.0000 74 OH- 0.29009E-02 -2.5375 0.25980E-02 -2.5854 0.89558E+00 -0.0479 79 HPO3-2 0.14645E-16 -16.8343 0.99994E-17 -17.0000 0.68278E+00 -0.1657 82 H3PO4,aq 0.13863E-14 -14.8581 0.13863E-14 -14.8581 0.10000E+01 0.0000 83 H2PO4- 0.18241E-07 -7.7390 0.16351E-07 -7.7865 0.89640E+00 -0.0475 84 PO4-3 0.34780E-07 -7.4587 0.15279E-07 -7.8159 0.43929E+00 -0.3573 87 H2P2O7-2 0.30646E-16 -16.5136 0.20924E-16 -16.6793 0.68278E+00 -0.1657 88 HP2O7-3 0.42994E-13 -13.3666 0.18583E-13 -13.7309 0.43223E+00 -0.3643 89 P2O7-4 0.86232E-13 -13.0643 0.19856E-13 -13.7021 0.23026E+00 -0.6378 90 H2S,aq 0.52436E-16 -16.2804 0.52384E-16 -16.2808 0.99901E+00 -0.0004 97 SO3-2 0.27153E-14 -14.5662 0.18630E-14 -14.7298 0.68609E+00 -0.1636 98 HSO3- 0.28090E-16 -16.5514 0.25172E-16 -16.5991 0.89612E+00 -0.0476 99 HSO4- 0.41636E-11 -11.3805 0.37347E-11 -11.4277 0.89698E+00 -0.0472 Charge balance for all species = -.9349E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2571310E-09 -.5542912E-02 -.5584587E+01 0.0000 2 H2O 0.1000000E+01 0.5550889E+02 0.9995912E+06 0.0000 3 Cl- 0.1378938E-03 0.1380881E-03 0.4893592E+01 5.7285 4 SO4-- 0.2551425E-04 0.2552634E-04 0.2451076E+01 14.5146 5 HCO3- 0.8570322E-05 0.1308079E-04 0.7978197E+00 4.5222 6 HS- 0.8426183E-13 -.8114561E-09 -.2682526E-04 -3.4854 7 Al+++ 0.6086230E-26 0.5961547E-04 0.1607842E+01 2.3298 8 H4SiO4 0.4742755E-03 0.2864045E-02 0.2751637E+03 -3.3240 9 Ca++ 0.1246350E-07 0.1615228E-07 0.6470804E-03 11.2024 10 Mg++ 0.3801269E-10 0.8869324E-10 0.2155409E-05 8.6860 11 Fe++ 0.2247606E-12 0.1410063E-07 0.7871489E-03 6.4580 12 K+ 0.4179495E-04 0.4187702E-04 0.1636791E+01 5.2103 13 Na+ 0.5373645E-02 0.5536276E-02 0.1272247E+03 7.3192 14 Mn++ 0.3002623E-10 0.7542940E-09 0.4142208E-04 8.5839 15 HPO4-- 0.5911527E-05 0.5964548E-05 0.5722321E+00 13.8795 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7613957E-01 -.5538338E-02 -.7060123E-01 0.0000000E+00 2 H2O 0.5545060E+02 0.5546309E+02 -.1248731E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1529584E-03 0.2550528E-04 0.1274532E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1274540E-03 -.8107866E-09 -.1274532E-03 0.0000000E+00 7 Al+++ 0.1499615E-01 0.5956628E-04 0.1493658E-01 0.0000000E+00 8 H4SiO4 0.4788839E-01 0.2861681E-02 0.4502671E-01 0.0000000E+00 9 Ca++ 0.5303977E-02 0.1613895E-07 0.5303961E-02 0.0000000E+00 10 Mg++ 0.3650000E-02 0.8862006E-10 0.3650000E-02 0.0000000E+00 11 Fe++ 0.3279127E-02 0.1408900E-07 0.3279112E-02 0.0000000E+00 12 K+ 0.9764331E-03 0.4184247E-04 0.9345907E-03 0.0000000E+00 13 Na+ 0.5932936E-02 0.5531708E-02 0.4012287E-03 0.0000000E+00 14 Mn++ 0.7974020E-04 0.7536716E-09 0.7973945E-04 0.0000000E+00 15 HPO4-- 0.2721493E-04 0.5959627E-05 0.2125531E-04 0.0000000E+00 Chg. balance for solid moles: 0.2740E-16 Mass of aqueous solution: 0.999593E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 4.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7085E-05 -5.150 0.3559E-02 -2.449 0.7148E-01 0.1131E-02 clinochlore 0.7300E-03 -3.137 0.4058 -0.392 8.149 0.1543 daphnite 0.4519E-03 -3.345 0.3224 -0.492 6.476 0.9771E-01 chlorite-Mn 0.1595E-04 -4.797 0.1131E-01 -1.947 0.2271 0.3603E-02 hematite 0.3061E-03 -3.514 0.4888E-01 -1.311 0.9817 0.9265E-02 microcline 0.9346E-03 -3.029 0.2601 -0.585 5.224 0.1016 paragonite 0.3340E-03 -3.476 0.1277 -0.894 2.564 0.4413E-01 stilbite 0.5269E-02 -2.278 3.713 0.570 74.57 1.732 nontronite-Na 0.2037E-03 -3.691 0.8663E-01 -1.062 1.740 0.2691E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4.979203 g Volume = 2.170435 cm3 Porosity: 23.5655% V(tot) - V(min): 0.66917E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4.5990000 g log = 0.6627 Original solution: 1000.0103000 g Original solution / Rock added: 217.44 (Water/Rock Ratio), log = 2.3373 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3864E-06 1.0073 0.4094E-06 0.4065E-06 CH4,gas 0.4847E-16 1.0129 0.5165E-16 0.5099E-16 H2,gas 0.1021E-05 1.0006 0.1075E-05 0.1074E-05 H2S,gas 0.1458E-14 0.9959 0.1528E-14 0.1534E-14 S2,gas 0.7192E-37 1.0000 0.7566E-37 0.7566E-37 CO,gas 0.1084E-15 1.0000 0.1140E-15 0.1140E-15 SO3,gas 0.3303E-39 1.0000 0.3474E-39 0.3474E-39 SO2,gas 0.1343E-22 1.0000 0.1413E-22 0.1413E-22 HCl,gas 0.9008E-17 1.0000 0.9476E-17 0.9476E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.18198E-10 16 albite -0.33 -0.32 0.01 0.000 -0.92937E+01 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.75 -8.39 -2.796 0.14322E+05 -6.388 3 CH4,gas 4.81 -13.48 -18.29 -4.572 0.31224E+05 -16.287 4 H2,gas 8.29 0.32 -7.97 -4.553 0.13606E+05 -5.969 5 H2S,gas -5.94 -22.76 -16.82 -8.408 0.28713E+05 -14.816 6 S2,gas -7.03 -46.15 -39.12 -6.019 0.66798E+05 -37.121 7 CO,gas 3.51 -14.43 -17.94 -5.521 0.30637E+05 -15.943 8 SO3,gas 17.43 -24.03 -41.46 -10.365 0.70790E+05 -39.459 9 SO2,gas 1.14 -23.71 -24.85 -6.627 0.42431E+05 -22.850 10 HCl,gas 5.48 -13.54 -19.02 -9.512 0.32482E+05 -17.023 11 acmite 7.74 6.97 -0.77 -0.080 0.13102E+04 15 albite-high 0.75 -0.32 -1.07 -0.083 0.18314E+04 19 spessartine 24.55 20.44 -4.11 -0.206 0.70189E+04 20 analcite 3.37 3.00 -0.37 -0.041 0.63106E+03 21 andalusite 5.06 1.34 -3.73 -0.373 0.63634E+04 22 andradite 39.09 36.23 -2.85 -0.148 0.48746E+04 23 grossular 32.83 28.29 -4.53 -0.227 0.77407E+04 26 annite 20.21 16.94 -3.27 -0.182 0.55787E+04 27 phlogopite 27.15 23.63 -3.52 -0.196 0.60109E+04 29 anorthite 12.80 9.21 -3.58 -0.276 0.61190E+04 35 aragonite 0.99 -3.55 -4.53 -1.512 0.77432E+04 36 brucite 12.58 8.69 -3.89 -0.778 0.66431E+04 37 calcite 0.83 -3.55 -4.38 -1.461 0.74818E+04 38 carnegieite-low 9.06 6.33 -2.74 -0.391 0.46777E+04 39 carnegieite-high 10.13 6.33 -3.81 -0.544 0.65045E+04 40 carpholite-Mg 8.65 6.70 -1.95 -0.130 0.33343E+04 41 carpholite-Fe 6.78 4.47 -2.31 -0.154 0.39499E+04 42 celadonite 5.40 2.93 -2.47 -0.145 0.42179E+04 43 celadonite-Fe 3.94 0.70 -3.23 -0.190 0.55232E+04 44 chrysotile 23.94 19.41 -4.53 -0.377 0.77302E+04 50 chloritoid-Mg 13.26 10.02 -3.24 -0.216 0.55316E+04 51 chloritoid-Fe 9.24 7.79 -1.45 -0.096 0.24675E+04 52 chloritoid-Mn 11.46 9.92 -1.54 -0.103 0.26360E+04 54 coesite -2.37 -3.32 -0.95 -0.318 0.16300E+04 59 corundum 8.43 4.66 -3.77 -0.343 0.64438E+04 61 cristobalite -2.55 -3.32 -0.77 -0.258 0.13229E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.33 -0.57 -0.094 0.96697E+03 67 diopside 16.22 13.24 -2.98 -0.298 0.50798E+04 68 hedenbergite 14.24 11.01 -3.23 -0.323 0.55186E+04 75 epidote 24.78 23.39 -1.38 -0.067 0.23631E+04 76 clinozoisite 22.92 19.42 -3.50 -0.159 0.59744E+04 77 epidote-Fe 29.94 27.36 -2.58 -0.134 0.43993E+04 78 fayalite 14.08 9.59 -4.49 -0.641 0.76614E+04 79 ferrosilite 11.19 6.27 -4.92 -0.492 0.84003E+04 83 gibbsite 4.10 2.33 -1.77 -0.253 0.30182E+04 84 glaucophane 23.11 18.76 -4.35 -0.117 0.74212E+04 87 greenalite 16.19 12.73 -3.47 -0.289 0.59220E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.00 -1.25 -0.125 0.21341E+04 97 kalsilite 7.62 4.22 -3.40 -0.486 0.58124E+04 98 kaolinite -1.27 -1.99 -0.72 -0.065 0.12213E+04 99 kyanite 4.93 1.34 -3.60 -0.360 0.61402E+04 101 laumontite 2.97 2.57 -0.41 -0.027 0.69749E+03 102 lawsonite 9.68 9.21 -0.46 -0.031 0.79292E+03 103 leucite 4.17 0.89 -3.28 -0.328 0.55928E+04 105 lizardite 23.29 19.41 -3.88 -0.323 0.66204E+04 107 magnetite 20.13 19.06 -1.08 -0.088 0.18393E+04 108 minnesotaite 10.46 6.08 -4.38 -0.258 0.74834E+04 110 magnesioferrite 26.26 21.28 -4.97 -0.406 0.84924E+04 113 margarite 17.45 13.87 -3.58 -0.143 0.61098E+04 120 muscovite 2.68 2.23 -0.45 -0.027 0.77083E+03 122 nepheline 8.38 6.33 -2.05 -0.293 0.35056E+04 134 phlogopite-Na 29.73 25.74 -4.00 -0.222 0.68235E+04 136 prehnite 19.47 17.09 -2.37 -0.140 0.40534E+04 137 prehnite-Fe 22.59 21.06 -1.53 -0.092 0.26045E+04 138 pumpellyite-Fe 46.47 42.97 -3.50 -0.078 0.59728E+04 139 pumpellyite-Mg 49.19 45.20 -3.99 -0.089 0.68187E+04 145 pyroxmangite 7.42 5.26 -2.16 -0.431 0.36816E+04 146 pyrophyllite -6.10 -8.64 -2.54 -0.159 0.43341E+04 147 quartz -2.98 -3.32 -0.34 -0.114 0.58391E+03 152 rhodonite 7.46 5.26 -2.20 -0.441 0.37608E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.34 -3.99 -0.399 0.68056E+04 164 stilpnomelane-Fe 13.18 12.96 -0.22 -0.006 0.36983E+03 165 stilpnomelane-Mg 27.60 24.10 -3.49 -0.104 0.59647E+04 168 sudoite 21.22 16.72 -4.50 -0.145 0.76785E+04 171 talc 16.55 12.76 -3.79 -0.223 0.64734E+04 174 tephroite 18.11 13.84 -4.27 -0.610 0.72895E+04 177 topaz-H 4.67 1.34 -3.33 -0.303 0.56893E+04 178 tridymite -2.61 -3.32 -0.71 -0.236 0.12112E+04 187 wairakite 4.06 2.57 -1.49 -0.088 0.25483E+04 188 walstromite 11.53 7.88 -3.65 -0.730 0.62313E+04 189 wollastonite 10.48 7.88 -2.60 -0.521 0.44452E+04 190 pseudo-wollastonite 11.02 7.88 -3.14 -0.628 0.53639E+04 191 zoisite 22.96 19.42 -3.54 -0.161 0.60469E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.92 -3.36 -0.208 0.57414E+04 194 beidellite-H -2.24 -6.77 -4.53 -0.289 0.77340E+04 195 beidellite-K -1.44 -5.05 -3.62 -0.221 0.61745E+04 196 beidellite-Mg -1.71 -5.34 -3.63 -0.225 0.61990E+04 197 beidellite-Na -1.26 -4.36 -3.10 -0.190 0.52901E+04 199 chalcedony -2.79 -3.32 -0.53 -0.177 0.90422E+03 201 montmorillonite-Ca -2.21 -4.69 -2.48 -0.153 0.42283E+04 202 montmorillonite-K -2.16 -4.82 -2.66 -0.163 0.45391E+04 203 montmorillonite-Mg -2.40 -5.11 -2.70 -0.167 0.46169E+04 204 montmorillonite-Na -1.96 -4.12 -2.16 -0.132 0.36929E+04 205 nontronite-Ca 3.28 3.02 -0.26 -0.017 0.45041E+03 206 nontronite-H 2.60 1.17 -1.43 -0.096 0.24387E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.88264E+03 208 nontronite-Mg 3.14 2.60 -0.54 -0.035 0.91962E+03 224 tobermorite 9.84 6.01 -3.83 -1.045 0.65420E+04 233 boehmite 4.43 2.33 -2.10 -0.350 0.35854E+04 235 ferrous-oxide 9.82 6.46 -3.37 -0.842 0.57478E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.415 0.21244E+04 242 an20ab80 2.08 1.58 -0.49 -0.038 0.84476E+03 243 an25ab75 2.71 2.06 -0.65 -0.050 0.11062E+04 244 an30ab70 3.34 2.54 -0.81 -0.062 0.13759E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 4.5990000 Water: Moles liquid = 0.5546E+02 kg liquid = 0.9992E+00 Moles total = 0.5545E+02 kg total = 0.9990E+00 Activity = 1.0000 Stoichiometric ionic strength = .3161570E-02 Osmotic coef. = 0.9692 True ionic strength = .5389527E-02 Chg. balance for total moles = -.9360E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.26019E-09 -9.5847 0.23374E-09 -9.6313 0.89834E+00 -0.0466 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12363E-03 -3.9079 0.89655E+00 -0.0474 4 SO4-- 0.25514E-04 -4.5932 0.17465E-04 -4.7578 0.68454E+00 -0.1646 5 HCO3- 0.86106E-05 -5.0650 0.77235E-05 -5.1122 0.89698E+00 -0.0472 6 HS- 0.83107E-13 -13.0804 0.74513E-13 -13.1278 0.89659E+00 -0.0474 7 Al+++ 0.63277E-26 -26.1988 0.27460E-26 -26.5613 0.43396E+00 -0.3626 8 H4SiO4 0.47501E-03 -3.3233 0.47501E-03 -3.3233 0.10000E+01 0.0000 9 Ca++ 0.12455E-07 -7.9046 0.85058E-08 -8.0703 0.68289E+00 -0.1656 10 Mg++ 0.38751E-10 -10.4117 0.26423E-10 -10.5780 0.68186E+00 -0.1663 11 Fe++ 0.22913E-12 -12.6399 0.15629E-12 -12.8061 0.68211E+00 -0.1661 12 K+ 0.41834E-04 -4.3785 0.37527E-04 -4.4257 0.89705E+00 -0.0472 13 Na+ 0.53116E-02 -2.2748 0.47618E-02 -2.3222 0.89650E+00 -0.0474 14 Mn++ 0.30610E-10 -10.5141 0.20885E-10 -10.6802 0.68230E+00 -0.1660 15 HPO4-- 0.59857E-05 -5.2229 0.40976E-05 -5.3875 0.68457E+00 -0.1646 16 HSiO3- 0.22115E-02 -2.6553 0.19828E-02 -2.7027 0.89655E+00 -0.0474 17 Ca(HSiO3)+ 0.42120E-09 -9.3755 0.37786E-09 -9.4227 0.89711E+00 -0.0472 18 Mg(HSiO3)+ 0.16284E-11 -11.7882 0.14608E-11 -11.8354 0.89711E+00 -0.0472 19 NaHSiO3,aq 0.14995E-03 -3.8240 0.14995E-03 -3.8240 0.10000E+01 0.0000 20 AlO+ 0.72326E-14 -14.1407 0.64884E-14 -14.1879 0.89711E+00 -0.0472 21 AlOH+2 0.11131E-19 -19.9535 0.75973E-20 -20.1193 0.68252E+00 -0.1659 22 HAlO2,aq 0.55549E-08 -8.2553 0.55549E-08 -8.2553 0.10000E+01 0.0000 23 AlO2- 0.59224E-04 -4.2275 0.53065E-04 -4.2752 0.89601E+00 -0.0477 24 CH4,aq 0.32365E-19 -19.4899 0.32333E-19 -19.4903 0.99902E+00 -0.0004 29 CO,aq 0.72970E-19 -19.1369 0.72970E-19 -19.1369 0.10000E+01 0.0000 30 CO2,aq 0.36434E-08 -8.4385 0.36398E-08 -8.4389 0.99902E+00 -0.0004 31 CO3-2 0.44662E-05 -5.3501 0.30551E-05 -5.5150 0.68406E+00 -0.1649 32 CaCO3,aq 0.31827E-09 -9.4972 0.31827E-09 -9.4972 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.18451E-11 -11.7340 0.16553E-11 -11.7811 0.89711E+00 -0.0472 34 CaCl+ 0.18678E-11 -11.7287 0.16757E-11 -11.7758 0.89711E+00 -0.0472 35 CaCl2,aq 0.48235E-16 -16.3166 0.48235E-16 -16.3166 0.10000E+01 0.0000 36 CaOH+ 0.28602E-08 -8.5436 0.25660E-08 -8.5908 0.89711E+00 -0.0472 37 CaSO4,aq 0.46287E-10 -10.3345 0.46287E-10 -10.3345 0.10000E+01 0.0000 38 HCl,aq 0.54355E-14 -14.2648 0.54355E-14 -14.2648 0.10000E+01 0.0000 43 FeCl+ 0.33546E-16 -16.4744 0.30095E-16 -16.5215 0.89711E+00 -0.0472 46 FeO,aq 0.11312E-09 -9.9465 0.11312E-09 -9.9465 0.10000E+01 0.0000 47 FeOH+ 0.24710E-10 -10.6071 0.22167E-10 -10.6543 0.89711E+00 -0.0472 48 HFeO2- 0.58062E-08 -8.2361 0.52056E-08 -8.2835 0.89655E+00 -0.0474 49 FeO+ 0.21553E-14 -14.6665 0.19335E-14 -14.7136 0.89711E+00 -0.0472 51 FeO2- 0.77583E-08 -8.1102 0.69556E-08 -8.1577 0.89655E+00 -0.0474 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.77915E-09 -9.1084 0.77839E-09 -9.1088 0.99902E+00 -0.0004 54 KCl,aq 0.82148E-10 -10.0854 0.82148E-10 -10.0854 0.10000E+01 0.0000 55 KHSO4,aq 0.40995E-18 -18.3873 0.40995E-18 -18.3873 0.10000E+01 0.0000 56 KOH,aq 0.69991E-07 -7.1550 0.69991E-07 -7.1550 0.10000E+01 0.0000 57 KSO4- 0.11263E-07 -7.9484 0.10098E-07 -7.9958 0.89655E+00 -0.0474 58 MgCO3,aq 0.24706E-12 -12.6072 0.24706E-12 -12.6072 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.58450E-14 -14.2332 0.52436E-14 -14.2804 0.89711E+00 -0.0472 60 MgCl+ 0.52675E-14 -14.2784 0.47256E-14 -14.3255 0.89711E+00 -0.0472 61 MgOH+ 0.49225E-10 -10.3078 0.44160E-10 -10.3550 0.89711E+00 -0.0472 63 MnO,aq 0.40354E-09 -9.3941 0.40354E-09 -9.3941 0.10000E+01 0.0000 64 MnOH+ 0.30674E-09 -9.5132 0.27518E-09 -9.5604 0.89711E+00 -0.0472 65 MnO2-2 0.37342E-12 -12.4278 0.25544E-12 -12.5927 0.68406E+00 -0.1649 66 HMnO2- 0.14429E-10 -10.8408 0.12936E-10 -10.8882 0.89655E+00 -0.0474 69 MnCl+ 0.17419E-13 -13.7590 0.15627E-13 -13.8061 0.89711E+00 -0.0472 70 MnSO4,aq 0.10338E-12 -12.9856 0.10338E-12 -12.9856 0.10000E+01 0.0000 71 NaCl,aq 0.19223E-06 -6.7162 0.19223E-06 -6.7162 0.10000E+01 0.0000 72 NaOH,aq 0.89518E-05 -5.0481 0.89518E-05 -5.0481 0.10000E+01 0.0000 74 OH- 0.28641E-02 -2.5430 0.25662E-02 -2.5907 0.89601E+00 -0.0477 79 HPO3-2 0.14727E-16 -16.8319 0.10074E-16 -16.9968 0.68406E+00 -0.1649 82 H3PO4,aq 0.14413E-14 -14.8413 0.14413E-14 -14.8413 0.10000E+01 0.0000 83 H2PO4- 0.18724E-07 -7.7276 0.16792E-07 -7.7749 0.89682E+00 -0.0473 84 PO4-3 0.34710E-07 -7.4595 0.15310E-07 -7.8150 0.44107E+00 -0.3555 87 H2P2O7-2 0.32260E-16 -16.4913 0.22068E-16 -16.6562 0.68406E+00 -0.1649 88 HP2O7-3 0.44601E-13 -13.3507 0.19359E-13 -13.7131 0.43406E+00 -0.3625 89 P2O7-4 0.88082E-13 -13.0551 0.20433E-13 -13.6897 0.23197E+00 -0.6346 90 H2S,aq 0.52381E-16 -16.2808 0.52330E-16 -16.2813 0.99902E+00 -0.0004 97 SO3-2 0.26969E-14 -14.5691 0.18536E-14 -14.7320 0.68734E+00 -0.1628 98 HSO3- 0.28282E-16 -16.5485 0.25356E-16 -16.5959 0.89655E+00 -0.0474 99 HSO4- 0.42210E-11 -11.3746 0.37879E-11 -11.4216 0.89740E+00 -0.0470 Charge balance for all species = -.9285E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2601917E-09 -.5476046E-02 -.5517242E+01 0.0000 2 H2O 0.1000000E+01 0.5550888E+02 0.9995953E+06 0.0000 3 Cl- 0.1378955E-03 0.1380878E-03 0.4893601E+01 5.7234 4 SO4-- 0.2551416E-04 0.2552627E-04 0.2451080E+01 14.5047 5 HCO3- 0.8610582E-05 0.1308076E-04 0.7978213E+00 4.5191 6 HS- 0.8310749E-13 -.8003467E-09 -.2645811E-04 -3.4965 7 Al+++ 0.6327691E-26 0.5922927E-04 0.1597433E+01 2.3325 8 H4SiO4 0.4750080E-03 0.2836511E-02 0.2725196E+03 -3.3233 9 Ca++ 0.1245550E-07 0.1610520E-07 0.6451971E-03 11.1922 10 Mg++ 0.3875134E-10 0.8986278E-10 0.2183840E-05 8.6845 11 Fe++ 0.2291289E-12 0.1390603E-07 0.7762888E-03 6.4565 12 K+ 0.4183352E-04 0.4191485E-04 0.1638276E+01 5.2056 13 Na+ 0.5311582E-02 0.5470681E-02 0.1257178E+03 7.3090 14 Mn++ 0.3060988E-10 0.7558077E-09 0.4150538E-04 8.5824 15 HPO4-- 0.5985665E-05 0.6039099E-05 0.5793868E+00 13.8751 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7613957E-01 -.5471540E-02 -.7066803E-01 0.0000000E+00 2 H2O 0.5545060E+02 0.5546320E+02 -.1260407E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1529584E-03 0.2550527E-04 0.1274532E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1274540E-03 -.7996881E-09 -.1274532E-03 0.0000000E+00 7 Al+++ 0.1499615E-01 0.5918053E-04 0.1493697E-01 0.0000000E+00 8 H4SiO4 0.4788839E-01 0.2834177E-02 0.4505421E-01 0.0000000E+00 9 Ca++ 0.5303977E-02 0.1609195E-07 0.5303961E-02 0.0000000E+00 10 Mg++ 0.3650000E-02 0.8978883E-10 0.3650000E-02 0.0000000E+00 11 Fe++ 0.3279127E-02 0.1389459E-07 0.3279113E-02 0.0000000E+00 12 K+ 0.9764331E-03 0.4188036E-04 0.9345528E-03 0.0000000E+00 13 Na+ 0.5932936E-02 0.5466179E-02 0.4667575E-03 0.0000000E+00 14 Mn++ 0.7974020E-04 0.7551857E-09 0.7973945E-04 0.0000000E+00 15 HPO4-- 0.2721493E-04 0.6034130E-05 0.2118081E-04 0.0000000E+00 Chg. balance for solid moles: 0.2175E-16 Mass of aqueous solution: 0.999591E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 4.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) apatite-OH 0.7060E-05 -5.151 0.3547E-02 -2.450 0.7120E-01 0.1127E-02 clinochlore 0.7300E-03 -3.137 0.4058 -0.392 8.146 0.1543 daphnite 0.4519E-03 -3.345 0.3224 -0.492 6.473 0.9771E-01 chlorite-Mn 0.1595E-04 -4.797 0.1131E-01 -1.947 0.2270 0.3603E-02 hematite 0.3695E-03 -3.432 0.5900E-01 -1.229 1.185 0.1118E-01 microcline 0.9346E-03 -3.029 0.2601 -0.585 5.222 0.1016 paragonite 0.3013E-03 -3.521 0.1152 -0.939 2.312 0.3981E-01 stilbite 0.5269E-02 -2.278 3.713 0.570 74.54 1.732 nontronite-Na 0.1403E-03 -3.853 0.5968E-01 -1.224 1.198 0.1854E-01 albite 0.1191E-03 -3.924 0.3124E-01 -1.505 0.6271 0.1199E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 albite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4.981185 g Volume = 2.171687 cm3 Porosity: 23.5214% V(tot) - V(min): 0.66791E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4.5990000 g log = 0.6627 Original solution: 1000.0103000 g Original solution / Rock added: 217.44 (Water/Rock Ratio), log = 2.3373 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3932E-06 1.0073 0.4166E-06 0.4136E-06 CH4,gas 0.4799E-16 1.0129 0.5113E-16 0.5048E-16 H2,gas 0.1014E-05 1.0006 0.1068E-05 0.1067E-05 H2S,gas 0.1457E-14 0.9959 0.1526E-14 0.1532E-14 S2,gas 0.7277E-37 1.0000 0.7655E-37 0.7655E-37 CO,gas 0.1095E-15 1.0000 0.1152E-15 0.1152E-15 SO3,gas 0.3391E-39 1.0000 0.3567E-39 0.3567E-39 SO2,gas 0.1370E-22 1.0000 0.1441E-22 0.1441E-22 HCl,gas 0.9124E-17 1.0000 0.9597E-17 0.9597E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.22748E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.74 -8.38 -2.793 0.14309E+05 -6.380 3 CH4,gas 4.81 -13.48 -18.29 -4.573 0.31232E+05 -16.291 4 H2,gas 8.29 0.32 -7.97 -4.555 0.13611E+05 -5.972 5 H2S,gas -5.94 -22.76 -16.82 -8.408 0.28714E+05 -14.816 6 S2,gas -7.03 -46.15 -39.12 -6.018 0.66790E+05 -37.116 7 CO,gas 3.51 -14.43 -17.94 -5.520 0.30629E+05 -15.938 8 SO3,gas 17.43 -24.02 -41.45 -10.362 0.70771E+05 -39.448 9 SO2,gas 1.14 -23.71 -24.84 -6.624 0.42416E+05 -22.841 10 HCl,gas 5.48 -13.54 -19.02 -9.509 0.32472E+05 -17.018 11 acmite 7.74 6.96 -0.78 -0.081 0.13252E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.44 -4.11 -0.205 0.70138E+04 20 analcite 3.37 2.99 -0.38 -0.042 0.64150E+03 21 andalusite 5.06 1.34 -3.72 -0.372 0.63530E+04 22 andradite 39.09 36.20 -2.88 -0.150 0.49231E+04 23 grossular 32.83 28.27 -4.56 -0.228 0.77799E+04 26 annite 20.21 16.94 -3.27 -0.182 0.55864E+04 27 phlogopite 27.15 23.62 -3.52 -0.196 0.60186E+04 29 anorthite 12.80 9.21 -3.59 -0.276 0.61248E+04 35 aragonite 0.99 -3.55 -4.54 -1.512 0.77475E+04 36 brucite 12.58 8.68 -3.89 -0.778 0.66456E+04 37 calcite 0.83 -3.55 -4.38 -1.461 0.74862E+04 38 carnegieite-low 9.06 6.32 -2.75 -0.392 0.46893E+04 39 carnegieite-high 10.13 6.32 -3.82 -0.545 0.65161E+04 40 carpholite-Mg 8.65 6.70 -1.95 -0.130 0.33252E+04 41 carpholite-Fe 6.78 4.47 -2.31 -0.154 0.39409E+04 42 celadonite 5.40 2.93 -2.47 -0.145 0.42193E+04 43 celadonite-Fe 3.94 0.70 -3.24 -0.190 0.55246E+04 44 chrysotile 23.94 19.41 -4.53 -0.378 0.77355E+04 50 chloritoid-Mg 13.26 10.03 -3.24 -0.216 0.55237E+04 51 chloritoid-Fe 9.24 7.80 -1.44 -0.096 0.24596E+04 52 chloritoid-Mn 11.46 9.92 -1.54 -0.103 0.26281E+04 54 coesite -2.37 -3.32 -0.95 -0.318 0.16288E+04 59 corundum 8.43 4.66 -3.77 -0.343 0.64345E+04 61 cristobalite -2.55 -3.32 -0.77 -0.258 0.13217E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.33 -0.56 -0.094 0.96232E+03 67 diopside 16.22 13.23 -2.99 -0.299 0.50973E+04 68 hedenbergite 14.24 11.00 -3.24 -0.324 0.55361E+04 75 epidote 24.78 23.38 -1.40 -0.068 0.23850E+04 76 clinozoisite 22.92 19.41 -3.51 -0.160 0.59916E+04 77 epidote-Fe 29.94 27.34 -2.59 -0.135 0.44259E+04 78 fayalite 14.08 9.59 -4.49 -0.641 0.76654E+04 79 ferrosilite 11.19 6.27 -4.92 -0.492 0.84031E+04 83 gibbsite 4.10 2.33 -1.76 -0.252 0.30135E+04 84 glaucophane 23.11 18.75 -4.36 -0.118 0.74451E+04 87 greenalite 16.19 12.72 -3.47 -0.289 0.59273E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.99 -1.26 -0.126 0.21445E+04 97 kalsilite 7.62 4.21 -3.41 -0.486 0.58147E+04 98 kaolinite -1.27 -1.98 -0.71 -0.064 0.12097E+04 99 kyanite 4.93 1.34 -3.59 -0.359 0.61297E+04 101 laumontite 2.97 2.56 -0.41 -0.027 0.70092E+03 102 lawsonite 9.68 9.21 -0.47 -0.031 0.79864E+03 103 leucite 4.17 0.89 -3.28 -0.328 0.55939E+04 105 lizardite 23.29 19.41 -3.88 -0.323 0.66258E+04 107 magnetite 20.13 19.05 -1.08 -0.088 0.18419E+04 108 minnesotaite 10.46 6.08 -4.38 -0.258 0.74864E+04 110 magnesioferrite 26.26 21.28 -4.98 -0.406 0.84949E+04 113 margarite 17.45 13.88 -3.58 -0.143 0.61062E+04 120 muscovite 2.68 2.23 -0.45 -0.026 0.76153E+03 122 nepheline 8.38 6.32 -2.06 -0.294 0.35172E+04 134 phlogopite-Na 29.73 25.73 -4.01 -0.223 0.68405E+04 136 prehnite 19.47 17.08 -2.39 -0.140 0.40753E+04 137 prehnite-Fe 22.59 21.05 -1.54 -0.093 0.26310E+04 138 pumpellyite-Fe 46.47 42.95 -3.52 -0.078 0.60144E+04 139 pumpellyite-Mg 49.19 45.18 -4.02 -0.089 0.68604E+04 145 pyroxmangite 7.42 5.26 -2.16 -0.431 0.36830E+04 146 pyrophyllite -6.10 -8.63 -2.53 -0.158 0.43202E+04 147 quartz -2.98 -3.32 -0.34 -0.114 0.58276E+03 152 rhodonite 7.46 5.26 -2.20 -0.441 0.37622E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.34 -3.98 -0.398 0.67952E+04 164 stilpnomelane-Fe 13.18 12.96 -0.22 -0.006 0.36815E+03 165 stilpnomelane-Mg 27.60 24.10 -3.49 -0.104 0.59630E+04 168 sudoite 21.22 16.73 -4.49 -0.145 0.76615E+04 171 talc 16.55 12.76 -3.79 -0.223 0.64765E+04 174 tephroite 18.11 13.84 -4.27 -0.610 0.72934E+04 177 topaz-H 4.67 1.34 -3.33 -0.302 0.56788E+04 178 tridymite -2.61 -3.32 -0.71 -0.236 0.12101E+04 187 wairakite 4.06 2.56 -1.49 -0.088 0.25517E+04 188 walstromite 11.53 7.87 -3.66 -0.732 0.62475E+04 189 wollastonite 10.48 7.87 -2.61 -0.523 0.44614E+04 190 pseudo-wollastonite 11.02 7.87 -3.15 -0.630 0.53800E+04 191 zoisite 22.96 19.41 -3.55 -0.161 0.60642E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.92 -3.36 -0.208 0.57293E+04 194 beidellite-H -2.24 -6.76 -4.52 -0.288 0.77190E+04 195 beidellite-K -1.44 -5.04 -3.61 -0.221 0.61621E+04 196 beidellite-Mg -1.71 -5.33 -3.62 -0.224 0.61844E+04 197 beidellite-Na -1.26 -4.35 -3.09 -0.189 0.52808E+04 199 chalcedony -2.79 -3.32 -0.53 -0.176 0.90308E+03 201 montmorillonite-Ca -2.21 -4.69 -2.47 -0.153 0.42197E+04 202 montmorillonite-K -2.16 -4.81 -2.65 -0.162 0.45303E+04 203 montmorillonite-Mg -2.40 -5.10 -2.70 -0.167 0.46059E+04 204 montmorillonite-Na -1.96 -4.12 -2.16 -0.132 0.36872E+04 205 nontronite-Ca 3.28 3.02 -0.26 -0.017 0.44753E+03 206 nontronite-H 2.60 1.17 -1.42 -0.096 0.24330E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.60 -0.54 -0.035 0.91430E+03 224 tobermorite 9.84 6.00 -3.84 -1.048 0.65553E+04 233 boehmite 4.43 2.33 -2.10 -0.350 0.35808E+04 235 ferrous-oxide 9.82 6.46 -3.37 -0.842 0.57503E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.415 0.21233E+04 242 an20ab80 2.08 1.58 -0.50 -0.038 0.85334E+03 243 an25ab75 2.71 2.06 -0.65 -0.050 0.11146E+04 244 an30ab70 3.34 2.53 -0.81 -0.062 0.13842E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 4.5990000 g New total amount of reactant added: 4.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.9361E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 4.7990000 Water: Moles liquid = 0.5546E+02 kg liquid = 0.9992E+00 Moles total = 0.5545E+02 kg total = 0.9989E+00 Activity = 1.0000 Stoichiometric ionic strength = .3161575E-02 Osmotic coef. = 0.9692 True ionic strength = .5389531E-02 Chg. balance for total moles = -.9361E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.26019E-09 -9.5847 0.23374E-09 -9.6313 0.89834E+00 -0.0466 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12363E-03 -3.9079 0.89655E+00 -0.0474 4 SO4-- 0.25515E-04 -4.5932 0.17466E-04 -4.7578 0.68454E+00 -0.1646 5 HCO3- 0.86108E-05 -5.0650 0.77237E-05 -5.1122 0.89698E+00 -0.0472 6 HS- 0.83110E-13 -13.0803 0.74515E-13 -13.1278 0.89659E+00 -0.0474 7 Al+++ 0.63277E-26 -26.1988 0.27460E-26 -26.5613 0.43396E+00 -0.3626 8 H4SiO4 0.47501E-03 -3.3233 0.47501E-03 -3.3233 0.10000E+01 0.0000 9 Ca++ 0.12456E-07 -7.9046 0.85058E-08 -8.0703 0.68289E+00 -0.1656 10 Mg++ 0.38751E-10 -10.4117 0.26423E-10 -10.5780 0.68186E+00 -0.1663 11 Fe++ 0.22913E-12 -12.6399 0.15629E-12 -12.8061 0.68211E+00 -0.1661 12 K+ 0.41834E-04 -4.3785 0.37527E-04 -4.4257 0.89705E+00 -0.0472 13 Na+ 0.53116E-02 -2.2748 0.47618E-02 -2.3222 0.89650E+00 -0.0474 14 Mn++ 0.30610E-10 -10.5141 0.20885E-10 -10.6802 0.68230E+00 -0.1660 15 HPO4-- 0.59857E-05 -5.2229 0.40976E-05 -5.3875 0.68457E+00 -0.1646 16 HSiO3- 0.22115E-02 -2.6553 0.19828E-02 -2.7027 0.89655E+00 -0.0474 17 Ca(HSiO3)+ 0.42120E-09 -9.3755 0.37786E-09 -9.4227 0.89711E+00 -0.0472 18 Mg(HSiO3)+ 0.16284E-11 -11.7882 0.14608E-11 -11.8354 0.89711E+00 -0.0472 19 NaHSiO3,aq 0.14995E-03 -3.8240 0.14995E-03 -3.8240 0.10000E+01 0.0000 20 AlO+ 0.72326E-14 -14.1407 0.64884E-14 -14.1879 0.89711E+00 -0.0472 21 AlOH+2 0.11131E-19 -19.9535 0.75973E-20 -20.1193 0.68251E+00 -0.1659 22 HAlO2,aq 0.55549E-08 -8.2553 0.55549E-08 -8.2553 0.10000E+01 0.0000 23 AlO2- 0.59224E-04 -4.2275 0.53065E-04 -4.2752 0.89601E+00 -0.0477 24 CH4,aq 0.32366E-19 -19.4899 0.32334E-19 -19.4903 0.99902E+00 -0.0004 29 CO,aq 0.72972E-19 -19.1368 0.72972E-19 -19.1368 0.10000E+01 0.0000 30 CO2,aq 0.36435E-08 -8.4385 0.36399E-08 -8.4389 0.99902E+00 -0.0004 31 CO3-2 0.44663E-05 -5.3500 0.30552E-05 -5.5150 0.68406E+00 -0.1649 32 CaCO3,aq 0.31828E-09 -9.4972 0.31828E-09 -9.4972 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.18452E-11 -11.7340 0.16554E-11 -11.7811 0.89711E+00 -0.0472 34 CaCl+ 0.18679E-11 -11.7286 0.16757E-11 -11.7758 0.89711E+00 -0.0472 35 CaCl2,aq 0.48237E-16 -16.3166 0.48237E-16 -16.3166 0.10000E+01 0.0000 36 CaOH+ 0.28602E-08 -8.5436 0.25660E-08 -8.5908 0.89711E+00 -0.0472 37 CaSO4,aq 0.46288E-10 -10.3345 0.46288E-10 -10.3345 0.10000E+01 0.0000 38 HCl,aq 0.54356E-14 -14.2647 0.54356E-14 -14.2647 0.10000E+01 0.0000 43 FeCl+ 0.33547E-16 -16.4743 0.30095E-16 -16.5215 0.89711E+00 -0.0472 46 FeO,aq 0.11312E-09 -9.9465 0.11312E-09 -9.9465 0.10000E+01 0.0000 47 FeOH+ 0.24710E-10 -10.6071 0.22167E-10 -10.6543 0.89711E+00 -0.0472 48 HFeO2- 0.58062E-08 -8.2361 0.52056E-08 -8.2835 0.89655E+00 -0.0474 49 FeO+ 0.21553E-14 -14.6665 0.19335E-14 -14.7136 0.89711E+00 -0.0472 51 FeO2- 0.77583E-08 -8.1102 0.69556E-08 -8.1577 0.89655E+00 -0.0474 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.77915E-09 -9.1084 0.77839E-09 -9.1088 0.99902E+00 -0.0004 54 KCl,aq 0.82150E-10 -10.0854 0.82150E-10 -10.0854 0.10000E+01 0.0000 55 KHSO4,aq 0.40997E-18 -18.3873 0.40997E-18 -18.3873 0.10000E+01 0.0000 56 KOH,aq 0.69991E-07 -7.1550 0.69991E-07 -7.1550 0.10000E+01 0.0000 57 KSO4- 0.11263E-07 -7.9483 0.10098E-07 -7.9958 0.89655E+00 -0.0474 58 MgCO3,aq 0.24706E-12 -12.6072 0.24706E-12 -12.6072 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.58452E-14 -14.2332 0.52438E-14 -14.2804 0.89711E+00 -0.0472 60 MgCl+ 0.52677E-14 -14.2784 0.47257E-14 -14.3255 0.89711E+00 -0.0472 61 MgOH+ 0.49225E-10 -10.3078 0.44160E-10 -10.3550 0.89711E+00 -0.0472 63 MnO,aq 0.40354E-09 -9.3941 0.40354E-09 -9.3941 0.10000E+01 0.0000 64 MnOH+ 0.30674E-09 -9.5132 0.27518E-09 -9.5604 0.89711E+00 -0.0472 65 MnO2-2 0.37342E-12 -12.4278 0.25544E-12 -12.5927 0.68406E+00 -0.1649 66 HMnO2- 0.14429E-10 -10.8408 0.12936E-10 -10.8882 0.89655E+00 -0.0474 69 MnCl+ 0.17420E-13 -13.7590 0.15627E-13 -13.8061 0.89711E+00 -0.0472 70 MnSO4,aq 0.10338E-12 -12.9856 0.10338E-12 -12.9856 0.10000E+01 0.0000 71 NaCl,aq 0.19223E-06 -6.7162 0.19223E-06 -6.7162 0.10000E+01 0.0000 72 NaOH,aq 0.89518E-05 -5.0481 0.89518E-05 -5.0481 0.10000E+01 0.0000 74 OH- 0.28641E-02 -2.5430 0.25662E-02 -2.5907 0.89601E+00 -0.0477 79 HPO3-2 0.14727E-16 -16.8319 0.10074E-16 -16.9968 0.68406E+00 -0.1649 82 H3PO4,aq 0.14413E-14 -14.8413 0.14413E-14 -14.8413 0.10000E+01 0.0000 83 H2PO4- 0.18724E-07 -7.7276 0.16792E-07 -7.7749 0.89682E+00 -0.0473 84 PO4-3 0.34710E-07 -7.4595 0.15310E-07 -7.8150 0.44107E+00 -0.3555 87 H2P2O7-2 0.32260E-16 -16.4913 0.22068E-16 -16.6562 0.68406E+00 -0.1649 88 HP2O7-3 0.44601E-13 -13.3507 0.19359E-13 -13.7131 0.43406E+00 -0.3625 89 P2O7-4 0.88082E-13 -13.0551 0.20433E-13 -13.6897 0.23197E+00 -0.6346 90 H2S,aq 0.52382E-16 -16.2808 0.52331E-16 -16.2812 0.99902E+00 -0.0004 97 SO3-2 0.26969E-14 -14.5691 0.18537E-14 -14.7320 0.68734E+00 -0.1628 98 HSO3- 0.28282E-16 -16.5485 0.25356E-16 -16.5959 0.89655E+00 -0.0474 99 HSO4- 0.42211E-11 -11.3746 0.37880E-11 -11.4216 0.89740E+00 -0.0470 Charge balance for all species = -.9424E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2601919E-09 -.5476044E-02 -.5517240E+01 0.0000 2 H2O 0.1000000E+01 0.5550888E+02 0.9995953E+06 0.0000 3 Cl- 0.1378992E-03 0.1380915E-03 0.4893733E+01 5.7234 4 SO4-- 0.2551485E-04 0.2552696E-04 0.2451146E+01 14.5047 5 HCO3- 0.8610816E-05 0.1308112E-04 0.7978428E+00 4.5191 6 HS- 0.8310983E-13 -.8003461E-09 -.2645809E-04 -3.4965 7 Al+++ 0.6327703E-26 0.5922924E-04 0.1597432E+01 2.3325 8 H4SiO4 0.4750080E-03 0.2836510E-02 0.2725195E+03 -3.3233 9 Ca++ 0.1245551E-07 0.1610523E-07 0.6451981E-03 11.1922 10 Mg++ 0.3875138E-10 0.8986285E-10 0.2183842E-05 8.6845 11 Fe++ 0.2291292E-12 0.1390603E-07 0.7762885E-03 6.4565 12 K+ 0.4183354E-04 0.4191488E-04 0.1638277E+01 5.2056 13 Na+ 0.5311585E-02 0.5470684E-02 0.1257179E+03 7.3090 14 Mn++ 0.3060993E-10 0.7558081E-09 0.4150540E-04 8.5824 15 HPO4-- 0.5985660E-05 0.6039093E-05 0.5793863E+00 13.8751 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7945128E-01 -.5471390E-02 -.7397989E-01 0.0000000E+00 2 H2O 0.5544809E+02 0.5546171E+02 -.1361278E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1585011E-03 0.2550527E-04 0.1329958E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1329966E-03 -.7996659E-09 -.1329958E-03 0.0000000E+00 7 Al+++ 0.1564830E-01 0.5917891E-04 0.1558912E-01 0.0000000E+00 8 H4SiO4 0.4997095E-01 0.2834099E-02 0.4713685E-01 0.0000000E+00 9 Ca++ 0.5534006E-02 0.1609154E-07 0.5533990E-02 0.0000000E+00 10 Mg++ 0.3808730E-02 0.8978648E-10 0.3808730E-02 0.0000000E+00 11 Fe++ 0.3421728E-02 0.1389421E-07 0.3421714E-02 0.0000000E+00 12 K+ 0.1018896E-02 0.4187926E-04 0.9770167E-03 0.0000000E+00 13 Na+ 0.6183985E-02 0.5466034E-02 0.7179510E-03 0.0000000E+00 14 Mn++ 0.8320792E-04 0.7551658E-09 0.8320717E-04 0.0000000E+00 15 HPO4-- 0.2839845E-04 0.6033961E-05 0.2236449E-04 0.0000000E+00 Chg. balance for solid moles: -.5624E-17 Mass of aqueous solution: 0.999564E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 4.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5391E-03 -3.268 0.1414 -0.850 2.715 0.5426E-01 apatite-OH 0.7455E-05 -5.128 0.3745E-02 -2.427 0.7192E-01 0.1190E-02 clinochlore 0.7617E-03 -3.118 0.4234 -0.373 8.132 0.1611 daphnite 0.4715E-03 -3.326 0.3365 -0.473 6.462 0.1020 chlorite-Mn 0.1664E-04 -4.779 0.1180E-01 -1.928 0.2266 0.3760E-02 hematite 0.5972E-03 -3.224 0.9538E-01 -1.021 1.832 0.1808E-01 microcline 0.9770E-03 -3.010 0.2719 -0.566 5.223 0.1062 paragonite 0.2004E-03 -3.698 0.7660E-01 -1.116 1.471 0.2648E-01 stilbite 0.5497E-02 -2.260 3.874 0.588 74.40 1.807 nontronite-Na -.6525E-04 1.000 -.2775E-01 1.000 -.5330 -.8620E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5.206571 g Volume = 2.271119 cm3 Porosity: 22.2113% V(tot) - V(min): 0.64848E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4.7990000 g log = 0.6812 Original solution: 1000.0103000 g Original solution / Rock added: 208.38 (Water/Rock Ratio), log = 2.3189 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3932E-06 1.0073 0.4167E-06 0.4136E-06 CH4,gas 0.4799E-16 1.0129 0.5113E-16 0.5048E-16 H2,gas 0.1014E-05 1.0006 0.1068E-05 0.1067E-05 H2S,gas 0.1457E-14 0.9959 0.1526E-14 0.1533E-14 S2,gas 0.7277E-37 1.0000 0.7655E-37 0.7655E-37 CO,gas 0.1095E-15 1.0000 0.1152E-15 0.1152E-15 SO3,gas 0.3391E-39 1.0000 0.3567E-39 0.3567E-39 SO2,gas 0.1370E-22 1.0000 0.1441E-22 0.1441E-22 HCl,gas 0.9124E-17 1.0000 0.9598E-17 0.9598E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 0.43980E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.74 -8.38 -2.793 0.14309E+05 -6.380 3 CH4,gas 4.81 -13.48 -18.29 -4.573 0.31232E+05 -16.291 4 H2,gas 8.29 0.32 -7.97 -4.555 0.13611E+05 -5.972 5 H2S,gas -5.94 -22.76 -16.82 -8.408 0.28713E+05 -14.816 6 S2,gas -7.03 -46.15 -39.12 -6.018 0.66790E+05 -37.116 7 CO,gas 3.51 -14.43 -17.94 -5.520 0.30629E+05 -15.938 8 SO3,gas 17.43 -24.02 -41.45 -10.362 0.70771E+05 -39.448 9 SO2,gas 1.14 -23.71 -24.84 -6.624 0.42416E+05 -22.841 10 HCl,gas 5.48 -13.54 -19.02 -9.509 0.32472E+05 -17.018 11 acmite 7.74 6.96 -0.78 -0.081 0.13252E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.44 -4.11 -0.205 0.70138E+04 20 analcite 3.37 2.99 -0.38 -0.042 0.64150E+03 21 andalusite 5.06 1.34 -3.72 -0.372 0.63530E+04 22 andradite 39.09 36.20 -2.88 -0.150 0.49231E+04 23 grossular 32.83 28.27 -4.56 -0.228 0.77799E+04 26 annite 20.21 16.94 -3.27 -0.182 0.55864E+04 27 phlogopite 27.15 23.62 -3.52 -0.196 0.60186E+04 29 anorthite 12.80 9.21 -3.59 -0.276 0.61248E+04 35 aragonite 0.99 -3.55 -4.54 -1.512 0.77475E+04 36 brucite 12.58 8.68 -3.89 -0.778 0.66456E+04 37 calcite 0.83 -3.55 -4.38 -1.461 0.74862E+04 38 carnegieite-low 9.06 6.32 -2.75 -0.392 0.46893E+04 39 carnegieite-high 10.13 6.32 -3.82 -0.545 0.65161E+04 40 carpholite-Mg 8.65 6.70 -1.95 -0.130 0.33252E+04 41 carpholite-Fe 6.78 4.47 -2.31 -0.154 0.39409E+04 42 celadonite 5.40 2.93 -2.47 -0.145 0.42193E+04 43 celadonite-Fe 3.94 0.70 -3.24 -0.190 0.55246E+04 44 chrysotile 23.94 19.41 -4.53 -0.378 0.77355E+04 50 chloritoid-Mg 13.26 10.03 -3.24 -0.216 0.55237E+04 51 chloritoid-Fe 9.24 7.80 -1.44 -0.096 0.24596E+04 52 chloritoid-Mn 11.46 9.92 -1.54 -0.103 0.26281E+04 54 coesite -2.37 -3.32 -0.95 -0.318 0.16288E+04 59 corundum 8.43 4.66 -3.77 -0.343 0.64345E+04 61 cristobalite -2.55 -3.32 -0.77 -0.258 0.13217E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.33 -0.56 -0.094 0.96232E+03 67 diopside 16.22 13.23 -2.99 -0.299 0.50973E+04 68 hedenbergite 14.24 11.00 -3.24 -0.324 0.55361E+04 75 epidote 24.78 23.38 -1.40 -0.068 0.23850E+04 76 clinozoisite 22.92 19.41 -3.51 -0.160 0.59916E+04 77 epidote-Fe 29.94 27.34 -2.59 -0.135 0.44259E+04 78 fayalite 14.08 9.59 -4.49 -0.641 0.76654E+04 79 ferrosilite 11.19 6.27 -4.92 -0.492 0.84031E+04 83 gibbsite 4.10 2.33 -1.76 -0.252 0.30135E+04 84 glaucophane 23.11 18.75 -4.36 -0.118 0.74451E+04 87 greenalite 16.19 12.72 -3.47 -0.289 0.59273E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.99 -1.26 -0.126 0.21445E+04 97 kalsilite 7.62 4.21 -3.41 -0.486 0.58147E+04 98 kaolinite -1.27 -1.98 -0.71 -0.064 0.12097E+04 99 kyanite 4.93 1.34 -3.59 -0.359 0.61297E+04 101 laumontite 2.97 2.56 -0.41 -0.027 0.70092E+03 102 lawsonite 9.68 9.21 -0.47 -0.031 0.79864E+03 103 leucite 4.17 0.89 -3.28 -0.328 0.55939E+04 105 lizardite 23.29 19.41 -3.88 -0.323 0.66258E+04 107 magnetite 20.13 19.05 -1.08 -0.088 0.18419E+04 108 minnesotaite 10.46 6.08 -4.38 -0.258 0.74864E+04 110 magnesioferrite 26.26 21.28 -4.98 -0.406 0.84949E+04 113 margarite 17.45 13.88 -3.58 -0.143 0.61062E+04 120 muscovite 2.68 2.23 -0.45 -0.026 0.76153E+03 122 nepheline 8.38 6.32 -2.06 -0.294 0.35172E+04 134 phlogopite-Na 29.73 25.73 -4.01 -0.223 0.68405E+04 136 prehnite 19.47 17.08 -2.39 -0.140 0.40753E+04 137 prehnite-Fe 22.59 21.05 -1.54 -0.093 0.26310E+04 138 pumpellyite-Fe 46.47 42.95 -3.52 -0.078 0.60144E+04 139 pumpellyite-Mg 49.19 45.18 -4.02 -0.089 0.68604E+04 145 pyroxmangite 7.42 5.26 -2.16 -0.431 0.36830E+04 146 pyrophyllite -6.10 -8.63 -2.53 -0.158 0.43202E+04 147 quartz -2.98 -3.32 -0.34 -0.114 0.58276E+03 152 rhodonite 7.46 5.26 -2.20 -0.441 0.37622E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.34 -3.98 -0.398 0.67952E+04 164 stilpnomelane-Fe 13.18 12.96 -0.22 -0.006 0.36815E+03 165 stilpnomelane-Mg 27.60 24.10 -3.49 -0.104 0.59630E+04 168 sudoite 21.22 16.73 -4.49 -0.145 0.76615E+04 171 talc 16.55 12.76 -3.79 -0.223 0.64765E+04 174 tephroite 18.11 13.84 -4.27 -0.610 0.72934E+04 177 topaz-H 4.67 1.34 -3.33 -0.302 0.56788E+04 178 tridymite -2.61 -3.32 -0.71 -0.236 0.12101E+04 187 wairakite 4.06 2.56 -1.49 -0.088 0.25517E+04 188 walstromite 11.53 7.87 -3.66 -0.732 0.62475E+04 189 wollastonite 10.48 7.87 -2.61 -0.523 0.44614E+04 190 pseudo-wollastonite 11.02 7.87 -3.15 -0.630 0.53800E+04 191 zoisite 22.96 19.41 -3.55 -0.161 0.60642E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.92 -3.36 -0.208 0.57293E+04 194 beidellite-H -2.24 -6.76 -4.52 -0.288 0.77190E+04 195 beidellite-K -1.44 -5.04 -3.61 -0.221 0.61621E+04 196 beidellite-Mg -1.71 -5.33 -3.62 -0.224 0.61844E+04 197 beidellite-Na -1.26 -4.35 -3.09 -0.189 0.52808E+04 199 chalcedony -2.79 -3.32 -0.53 -0.176 0.90308E+03 201 montmorillonite-Ca -2.21 -4.69 -2.47 -0.153 0.42197E+04 202 montmorillonite-K -2.16 -4.81 -2.65 -0.162 0.45303E+04 203 montmorillonite-Mg -2.40 -5.10 -2.70 -0.167 0.46059E+04 204 montmorillonite-Na -1.96 -4.12 -2.16 -0.132 0.36872E+04 205 nontronite-Ca 3.28 3.02 -0.26 -0.017 0.44753E+03 206 nontronite-H 2.60 1.17 -1.42 -0.096 0.24330E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.60 -0.54 -0.035 0.91430E+03 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.15165E-11 224 tobermorite 9.84 6.00 -3.84 -1.048 0.65553E+04 233 boehmite 4.43 2.33 -2.10 -0.350 0.35808E+04 235 ferrous-oxide 9.82 6.46 -3.37 -0.842 0.57503E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.415 0.21233E+04 242 an20ab80 2.08 1.58 -0.50 -0.038 0.85334E+03 243 an25ab75 2.71 2.06 -0.65 -0.050 0.11146E+04 244 an30ab70 3.34 2.53 -0.81 -0.062 0.13842E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 4.7990000 Water: Moles liquid = 0.5546E+02 kg liquid = 0.9991E+00 Moles total = 0.5545E+02 kg total = 0.9989E+00 Activity = 1.0000 Stoichiometric ionic strength = .3195513E-02 Osmotic coef. = 0.9691 True ionic strength = .5447765E-02 Chg. balance for total moles = -.9361E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.25652E-09 -9.5909 0.23035E-09 -9.6376 0.89796E+00 -0.0467 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12358E-03 -3.9081 0.89615E+00 -0.0476 4 SO4-- 0.25515E-04 -4.5932 0.17435E-04 -4.7586 0.68335E+00 -0.1654 5 HCO3- 0.85639E-05 -5.0673 0.76782E-05 -5.1147 0.89658E+00 -0.0474 6 HS- 0.85143E-13 -13.0698 0.76305E-13 -13.1174 0.89619E+00 -0.0476 7 Al+++ 0.60801E-26 -26.2161 0.26281E-26 -26.5804 0.43224E+00 -0.3643 8 H4SiO4 0.47106E-03 -3.3269 0.47106E-03 -3.3269 0.10000E+01 0.0000 9 Ca++ 0.12848E-07 -7.8912 0.87581E-08 -8.0576 0.68169E+00 -0.1664 10 Mg++ 0.37891E-10 -10.4215 0.25790E-10 -10.5885 0.68065E+00 -0.1671 11 Fe++ 0.22404E-12 -12.6497 0.15255E-12 -12.8166 0.68090E+00 -0.1669 12 K+ 0.42291E-04 -4.3738 0.37921E-04 -4.4211 0.89666E+00 -0.0474 13 Na+ 0.53697E-02 -2.2700 0.48118E-02 -2.3177 0.89610E+00 -0.0476 14 Mn++ 0.29930E-10 -10.5239 0.20385E-10 -10.6907 0.68109E+00 -0.1668 15 HPO4-- 0.56007E-05 -5.2518 0.38274E-05 -5.4171 0.68338E+00 -0.1653 16 HSiO3- 0.22264E-02 -2.6524 0.19952E-02 -2.7000 0.89615E+00 -0.0476 17 Ca(HSiO3)+ 0.43661E-09 -9.3599 0.39152E-09 -9.4072 0.89672E+00 -0.0473 18 Mg(HSiO3)+ 0.16001E-11 -11.7959 0.14348E-11 -11.8432 0.89672E+00 -0.0473 19 NaHSiO3,aq 0.15248E-03 -3.8168 0.15248E-03 -3.8168 0.10000E+01 0.0000 20 AlO+ 0.71307E-14 -14.1469 0.63942E-14 -14.1942 0.89672E+00 -0.0473 21 AlOH+2 0.10830E-19 -19.9654 0.73783E-20 -20.1320 0.68131E+00 -0.1667 22 HAlO2,aq 0.55549E-08 -8.2553 0.55549E-08 -8.2553 0.10000E+01 0.0000 23 AlO2- 0.60123E-04 -4.2210 0.53847E-04 -4.2688 0.89560E+00 -0.0479 24 CH4,aq 0.33006E-19 -19.4814 0.32973E-19 -19.4818 0.99901E+00 -0.0004 29 CO,aq 0.72209E-19 -19.1414 0.72209E-19 -19.1414 0.10000E+01 0.0000 30 CO2,aq 0.35695E-08 -8.4474 0.35660E-08 -8.4478 0.99901E+00 -0.0004 31 CO3-2 0.45133E-05 -5.3455 0.30820E-05 -5.5112 0.68286E+00 -0.1657 32 CaCO3,aq 0.33059E-09 -9.4807 0.33059E-09 -9.4807 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.18896E-11 -11.7236 0.16944E-11 -11.7710 0.89672E+00 -0.0473 34 CaCl+ 0.19233E-11 -11.7160 0.17246E-11 -11.7633 0.89672E+00 -0.0473 35 CaCl2,aq 0.49623E-16 -16.3043 0.49623E-16 -16.3043 0.10000E+01 0.0000 36 CaOH+ 0.29898E-08 -8.5244 0.26810E-08 -8.5717 0.89672E+00 -0.0473 37 CaSO4,aq 0.47578E-10 -10.3226 0.47578E-10 -10.3226 0.10000E+01 0.0000 38 HCl,aq 0.53543E-14 -14.2713 0.53543E-14 -14.2713 0.10000E+01 0.0000 43 FeCl+ 0.32743E-16 -16.4849 0.29361E-16 -16.5322 0.89672E+00 -0.0473 46 FeO,aq 0.11369E-09 -9.9443 0.11369E-09 -9.9443 0.10000E+01 0.0000 47 FeOH+ 0.24484E-10 -10.6111 0.21955E-10 -10.6585 0.89672E+00 -0.0473 48 HFeO2- 0.59240E-08 -8.2274 0.53088E-08 -8.2750 0.89615E+00 -0.0476 49 FeO+ 0.21249E-14 -14.6727 0.19055E-14 -14.7200 0.89672E+00 -0.0473 51 FeO2- 0.78761E-08 -8.1037 0.70581E-08 -8.1513 0.89615E+00 -0.0476 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.78700E-09 -9.1040 0.78623E-09 -9.1045 0.99901E+00 -0.0004 54 KCl,aq 0.82974E-10 -10.0811 0.82974E-10 -10.0811 0.10000E+01 0.0000 55 KHSO4,aq 0.40754E-18 -18.3898 0.40754E-18 -18.3898 0.10000E+01 0.0000 56 KOH,aq 0.71767E-07 -7.1441 0.71767E-07 -7.1441 0.10000E+01 0.0000 57 KSO4- 0.11367E-07 -7.9444 0.10186E-07 -7.9920 0.89615E+00 -0.0476 58 MgCO3,aq 0.24326E-12 -12.6139 0.24326E-12 -12.6139 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.56741E-14 -14.2461 0.50881E-14 -14.2934 0.89672E+00 -0.0473 60 MgCl+ 0.51415E-14 -14.2889 0.46105E-14 -14.3363 0.89672E+00 -0.0473 61 MgOH+ 0.48775E-10 -10.3118 0.43738E-10 -10.3591 0.89672E+00 -0.0473 63 MnO,aq 0.40556E-09 -9.3919 0.40556E-09 -9.3919 0.10000E+01 0.0000 64 MnOH+ 0.30394E-09 -9.5172 0.27255E-09 -9.5646 0.89672E+00 -0.0473 65 MnO2-2 0.38711E-12 -12.4122 0.26434E-12 -12.5778 0.68286E+00 -0.1657 66 HMnO2- 0.14721E-10 -10.8321 0.13193E-10 -10.8797 0.89615E+00 -0.0476 69 MnCl+ 0.17002E-13 -13.7695 0.15246E-13 -13.8168 0.89672E+00 -0.0473 70 MnSO4,aq 0.10073E-12 -12.9969 0.10073E-12 -12.9969 0.10000E+01 0.0000 71 NaCl,aq 0.19416E-06 -6.7118 0.19416E-06 -6.7118 0.10000E+01 0.0000 72 NaOH,aq 0.91789E-05 -5.0372 0.91789E-05 -5.0372 0.10000E+01 0.0000 74 OH- 0.29076E-02 -2.5365 0.26040E-02 -2.5844 0.89560E+00 -0.0479 79 HPO3-2 0.13919E-16 -16.8564 0.95048E-17 -17.0221 0.68286E+00 -0.1657 82 H3PO4,aq 0.13074E-14 -14.8836 0.13074E-14 -14.8836 0.10000E+01 0.0000 83 H2PO4- 0.17243E-07 -7.7634 0.15457E-07 -7.8109 0.89643E+00 -0.0475 84 PO4-3 0.33025E-07 -7.4812 0.14511E-07 -7.8383 0.43940E+00 -0.3571 87 H2P2O7-2 0.27383E-16 -16.5625 0.18699E-16 -16.7282 0.68286E+00 -0.1657 88 HP2O7-3 0.38501E-13 -13.4145 0.16645E-13 -13.7787 0.43234E+00 -0.3642 89 P2O7-4 0.77386E-13 -13.1113 0.17827E-13 -13.7489 0.23037E+00 -0.6376 90 H2S,aq 0.52862E-16 -16.2769 0.52810E-16 -16.2773 0.99901E+00 -0.0004 97 SO3-2 0.27240E-14 -14.5648 0.18691E-14 -14.7284 0.68616E+00 -0.1636 98 HSO3- 0.28116E-16 -16.5510 0.25196E-16 -16.5987 0.89615E+00 -0.0476 99 HSO4- 0.41544E-11 -11.3815 0.37265E-11 -11.4287 0.89700E+00 -0.0472 Charge balance for all species = -.8865E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2565238E-09 -.5540853E-02 -.5582519E+01 0.0000 2 H2O 0.1000000E+01 0.5550891E+02 0.9995927E+06 0.0000 3 Cl- 0.1378976E-03 0.1380918E-03 0.4893728E+01 5.7296 4 SO4-- 0.2551480E-04 0.2552703E-04 0.2451145E+01 14.5167 5 HCO3- 0.8563895E-05 0.1308114E-04 0.7978420E+00 4.5229 6 HS- 0.8514322E-13 -.8131047E-09 -.2687979E-04 -3.4798 7 Al+++ 0.6080148E-26 0.6012883E-04 0.1621690E+01 2.3325 8 H4SiO4 0.4710565E-03 0.2849988E-02 0.2738135E+03 -3.3269 9 Ca++ 0.1284760E-07 0.1665595E-07 0.6672588E-03 11.2176 10 Mg++ 0.3789090E-10 0.8852051E-10 0.2151213E-05 8.6867 11 Fe++ 0.2240406E-12 0.1414194E-07 0.7894558E-03 6.4586 12 K+ 0.4229103E-04 0.4237424E-04 0.1656227E+01 5.2165 13 Na+ 0.5369703E-02 0.5531557E-02 0.1271164E+03 7.3199 14 Mn++ 0.2993005E-10 0.7546584E-09 0.4144214E-04 8.5845 15 HPO4-- 0.5600745E-05 0.5651012E-05 0.5421524E+00 13.8581 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7945128E-01 -.5536133E-02 -.7391514E-01 0.0000000E+00 2 H2O 0.5544809E+02 0.5546162E+02 -.1352680E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1585011E-03 0.2550528E-04 0.1329958E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1329966E-03 -.8124120E-09 -.1329958E-03 0.0000000E+00 7 Al+++ 0.1564830E-01 0.6007761E-04 0.1558822E-01 0.0000000E+00 8 H4SiO4 0.4997095E-01 0.2847560E-02 0.4712339E-01 0.0000000E+00 9 Ca++ 0.5534006E-02 0.1664176E-07 0.5533989E-02 0.0000000E+00 10 Mg++ 0.3808730E-02 0.8844510E-10 0.3808730E-02 0.0000000E+00 11 Fe++ 0.3421728E-02 0.1412990E-07 0.3421714E-02 0.0000000E+00 12 K+ 0.1018896E-02 0.4233814E-04 0.9765578E-03 0.0000000E+00 13 Na+ 0.6183985E-02 0.5526845E-02 0.6571403E-03 0.0000000E+00 14 Mn++ 0.8320792E-04 0.7540155E-09 0.8320717E-04 0.0000000E+00 15 HPO4-- 0.2839845E-04 0.5646198E-05 0.2275225E-04 0.0000000E+00 Chg. balance for solid moles: 0.1498E-17 Mass of aqueous solution: 0.999565E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 4.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4259E-03 -3.371 0.1117 -0.952 2.145 0.4287E-01 apatite-OH 0.7584E-05 -5.120 0.3810E-02 -2.419 0.7319E-01 0.1211E-02 clinochlore 0.7617E-03 -3.118 0.4234 -0.373 8.134 0.1611 daphnite 0.4715E-03 -3.326 0.3365 -0.473 6.463 0.1020 chlorite-Mn 0.1664E-04 -4.779 0.1180E-01 -1.928 0.2267 0.3760E-02 hematite 0.5320E-03 -3.274 0.8496E-01 -1.071 1.632 0.1610E-01 microcline 0.9766E-03 -3.010 0.2718 -0.566 5.222 0.1062 paragonite 0.2313E-03 -3.636 0.8839E-01 -1.054 1.698 0.3055E-01 stilbite 0.5496E-02 -2.260 3.873 0.588 74.41 1.807 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5.205488 g Volume = 2.270204 cm3 Porosity: 22.2427% V(tot) - V(min): 0.64940E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4.7990000 g log = 0.6812 Original solution: 1000.0103000 g Original solution / Rock added: 208.38 (Water/Rock Ratio), log = 2.3189 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3852E-06 1.0073 0.4082E-06 0.4052E-06 CH4,gas 0.4894E-16 1.0129 0.5214E-16 0.5148E-16 H2,gas 0.1025E-05 1.0006 0.1078E-05 0.1078E-05 H2S,gas 0.1470E-14 0.9959 0.1540E-14 0.1547E-14 S2,gas 0.7264E-37 1.0000 0.7641E-37 0.7641E-37 CO,gas 0.1084E-15 1.0000 0.1140E-15 0.1140E-15 SO3,gas 0.3288E-39 1.0000 0.3459E-39 0.3459E-39 SO2,gas 0.1341E-22 1.0000 0.1411E-22 0.1411E-22 HCl,gas 0.8987E-17 1.0000 0.9454E-17 0.9454E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 0.19715E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.75 -8.39 -2.796 0.14324E+05 -6.389 3 CH4,gas 4.81 -13.47 -18.28 -4.571 0.31217E+05 -16.283 4 H2,gas 8.29 0.32 -7.97 -4.553 0.13604E+05 -5.967 5 H2S,gas -5.94 -22.76 -16.81 -8.406 0.28707E+05 -14.812 6 S2,gas -7.03 -46.15 -39.12 -6.018 0.66791E+05 -37.117 7 CO,gas 3.51 -14.43 -17.94 -5.521 0.30637E+05 -15.943 8 SO3,gas 17.43 -24.03 -41.46 -10.365 0.70794E+05 -39.461 9 SO2,gas 1.14 -23.71 -24.85 -6.627 0.42432E+05 -22.850 10 HCl,gas 5.48 -13.55 -19.02 -9.512 0.32484E+05 -17.024 11 acmite 7.74 6.96 -0.77 -0.080 0.13190E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.44 -4.11 -0.206 0.70212E+04 20 analcite 3.37 3.00 -0.37 -0.041 0.63530E+03 21 andalusite 5.06 1.34 -3.72 -0.372 0.63592E+04 22 andradite 39.09 36.27 -2.82 -0.146 0.48116E+04 23 grossular 32.83 28.34 -4.49 -0.225 0.76684E+04 26 annite 20.21 16.94 -3.27 -0.181 0.55752E+04 27 phlogopite 27.15 23.63 -3.52 -0.195 0.60074E+04 29 anorthite 12.80 9.23 -3.57 -0.275 0.60938E+04 35 aragonite 0.99 -3.53 -4.52 -1.507 0.77194E+04 36 brucite 12.58 8.69 -3.89 -0.778 0.66419E+04 37 calcite 0.83 -3.53 -4.37 -1.456 0.74580E+04 38 carnegieite-low 9.06 6.33 -2.74 -0.391 0.46769E+04 39 carnegieite-high 10.13 6.33 -3.81 -0.544 0.65037E+04 40 carpholite-Mg 8.65 6.70 -1.95 -0.130 0.33339E+04 41 carpholite-Fe 6.78 4.47 -2.31 -0.154 0.39496E+04 42 celadonite 5.40 2.93 -2.47 -0.145 0.42218E+04 43 celadonite-Fe 3.94 0.70 -3.24 -0.190 0.55271E+04 44 chrysotile 23.94 19.41 -4.53 -0.378 0.77367E+04 50 chloritoid-Mg 13.26 10.02 -3.24 -0.216 0.55262E+04 51 chloritoid-Fe 9.24 7.80 -1.44 -0.096 0.24621E+04 52 chloritoid-Mn 11.46 9.92 -1.54 -0.103 0.26305E+04 54 coesite -2.37 -3.33 -0.96 -0.319 0.16350E+04 59 corundum 8.43 4.66 -3.77 -0.343 0.64345E+04 61 cristobalite -2.55 -3.33 -0.78 -0.259 0.13279E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.33 -0.56 -0.094 0.96232E+03 67 diopside 16.22 13.25 -2.96 -0.296 0.50626E+04 68 hedenbergite 14.24 11.02 -3.22 -0.322 0.55015E+04 75 epidote 24.78 23.42 -1.36 -0.066 0.23169E+04 76 clinozoisite 22.92 19.45 -3.47 -0.158 0.59235E+04 77 epidote-Fe 29.94 27.38 -2.55 -0.133 0.43577E+04 78 fayalite 14.08 9.59 -4.49 -0.641 0.76642E+04 79 ferrosilite 11.19 6.26 -4.92 -0.492 0.84080E+04 83 gibbsite 4.10 2.33 -1.76 -0.252 0.30135E+04 84 glaucophane 23.11 18.75 -4.36 -0.118 0.74463E+04 87 greenalite 16.19 12.72 -3.47 -0.289 0.59286E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.00 -1.25 -0.125 0.21383E+04 97 kalsilite 7.62 4.22 -3.40 -0.485 0.58023E+04 98 kaolinite -1.27 -1.99 -0.72 -0.065 0.12221E+04 99 kyanite 4.93 1.34 -3.59 -0.359 0.61359E+04 101 laumontite 2.97 2.57 -0.40 -0.027 0.68234E+03 102 lawsonite 9.68 9.23 -0.45 -0.030 0.76767E+03 103 leucite 4.17 0.90 -3.27 -0.327 0.55877E+04 105 lizardite 23.29 19.41 -3.88 -0.323 0.66270E+04 107 magnetite 20.13 19.06 -1.08 -0.088 0.18381E+04 108 minnesotaite 10.46 6.07 -4.39 -0.258 0.75001E+04 110 magnesioferrite 26.26 21.28 -4.97 -0.406 0.84912E+04 113 margarite 17.45 13.89 -3.56 -0.142 0.60752E+04 120 muscovite 2.68 2.23 -0.45 -0.026 0.76153E+03 122 nepheline 8.38 6.33 -2.05 -0.293 0.35048E+04 134 phlogopite-Na 29.73 25.73 -4.00 -0.222 0.68293E+04 136 prehnite 19.47 17.12 -2.35 -0.138 0.40072E+04 137 prehnite-Fe 22.59 21.09 -1.50 -0.090 0.25628E+04 138 pumpellyite-Fe 46.47 43.03 -3.44 -0.076 0.58744E+04 139 pumpellyite-Mg 49.19 45.26 -3.94 -0.087 0.67204E+04 145 pyroxmangite 7.42 5.26 -2.16 -0.432 0.36854E+04 146 pyrophyllite -6.10 -8.64 -2.54 -0.159 0.43450E+04 147 quartz -2.98 -3.33 -0.34 -0.115 0.58896E+03 152 rhodonite 7.46 5.26 -2.20 -0.441 0.37647E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.34 -3.98 -0.398 0.68013E+04 164 stilpnomelane-Fe 13.18 12.95 -0.23 -0.007 0.38983E+03 165 stilpnomelane-Mg 27.60 24.09 -3.50 -0.105 0.59847E+04 168 sudoite 21.22 16.72 -4.49 -0.145 0.76727E+04 171 talc 16.55 12.75 -3.80 -0.224 0.64901E+04 174 tephroite 18.11 13.84 -4.27 -0.610 0.72922E+04 177 topaz-H 4.67 1.34 -3.33 -0.303 0.56850E+04 178 tridymite -2.61 -3.33 -0.71 -0.237 0.12162E+04 187 wairakite 4.06 2.57 -1.48 -0.087 0.25332E+04 188 walstromite 11.53 7.89 -3.64 -0.727 0.62103E+04 189 wollastonite 10.48 7.89 -2.59 -0.518 0.44242E+04 190 pseudo-wollastonite 11.02 7.89 -3.13 -0.626 0.53429E+04 191 zoisite 22.96 19.45 -3.51 -0.160 0.59960E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.92 -3.36 -0.208 0.57448E+04 194 beidellite-H -2.24 -6.78 -4.53 -0.289 0.77417E+04 195 beidellite-K -1.44 -5.05 -3.62 -0.222 0.61787E+04 196 beidellite-Mg -1.71 -5.34 -3.63 -0.225 0.62065E+04 197 beidellite-Na -1.26 -4.36 -3.10 -0.190 0.52974E+04 199 chalcedony -2.79 -3.33 -0.53 -0.178 0.90927E+03 201 montmorillonite-Ca -2.21 -4.69 -2.48 -0.153 0.42361E+04 202 montmorillonite-K -2.16 -4.82 -2.66 -0.163 0.45477E+04 203 montmorillonite-Mg -2.40 -5.11 -2.71 -0.168 0.46288E+04 204 montmorillonite-Na -1.96 -4.13 -2.17 -0.133 0.37046E+04 205 nontronite-Ca 3.28 3.01 -0.27 -0.018 0.46311E+03 206 nontronite-H 2.60 1.16 -1.44 -0.096 0.24557E+04 207 nontronite-K 3.40 2.88 -0.52 -0.034 0.89618E+03 208 nontronite-Mg 3.14 2.59 -0.55 -0.036 0.93642E+03 209 nontronite-Na 3.58 3.57 -0.01 -0.001 0.16602E+02 224 tobermorite 9.84 6.02 -3.82 -1.043 0.65253E+04 233 boehmite 4.43 2.33 -2.10 -0.350 0.35808E+04 235 ferrous-oxide 9.82 6.46 -3.37 -0.841 0.57466E+04 240 silica-amorphous -2.08 -3.33 -1.25 -0.416 0.21295E+04 242 an20ab80 2.08 1.58 -0.50 -0.038 0.84715E+03 243 an25ab75 2.71 2.06 -0.65 -0.050 0.11068E+04 244 an30ab70 3.34 2.54 -0.81 -0.062 0.13749E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 4.7990000 g New total amount of reactant added: 4.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.9361E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 4.9990000 Water: Moles liquid = 0.5546E+02 kg liquid = 0.9991E+00 Moles total = 0.5545E+02 kg total = 0.9989E+00 Activity = 1.0000 Stoichiometric ionic strength = .3303223E-02 Osmotic coef. = 0.9686 True ionic strength = .5631998E-02 Chg. balance for total moles = -.9361E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.24558E-09 -9.6098 0.22023E-09 -9.6571 0.89676E+00 -0.0473 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12340E-03 -3.9087 0.89490E+00 -0.0482 4 SO4-- 0.25515E-04 -4.5932 0.17341E-04 -4.7609 0.67964E+00 -0.1677 5 HCO3- 0.84183E-05 -5.0748 0.75373E-05 -5.1228 0.89535E+00 -0.0480 6 HS- 0.91730E-13 -13.0375 0.82093E-13 -13.0857 0.89495E+00 -0.0482 7 Al+++ 0.53796E-26 -26.2692 0.22967E-26 -26.6389 0.42692E+00 -0.3697 8 H4SiO4 0.45909E-03 -3.3381 0.45909E-03 -3.3381 0.10000E+01 0.0000 9 Ca++ 0.14138E-07 -7.8496 0.95849E-08 -8.0184 0.67794E+00 -0.1688 10 Mg++ 0.35369E-10 -10.4514 0.23941E-10 -10.6209 0.67687E+00 -0.1695 11 Fe++ 0.20913E-12 -12.6796 0.14161E-12 -12.8489 0.67713E+00 -0.1693 12 K+ 0.43737E-04 -4.3592 0.39163E-04 -4.4071 0.89543E+00 -0.0480 13 Na+ 0.55534E-02 -2.2554 0.49695E-02 -2.3037 0.89486E+00 -0.0482 14 Mn++ 0.27938E-10 -10.5538 0.18923E-10 -10.7230 0.67732E+00 -0.1692 15 HPO4-- 0.45635E-05 -5.3407 0.31016E-05 -5.5084 0.67967E+00 -0.1677 16 HSiO3- 0.22728E-02 -2.6434 0.20339E-02 -2.6917 0.89490E+00 -0.0482 17 Ca(HSiO3)+ 0.48776E-09 -9.3118 0.43679E-09 -9.3597 0.89549E+00 -0.0479 18 Mg(HSiO3)+ 0.15162E-11 -11.8192 0.13577E-11 -11.8672 0.89549E+00 -0.0479 19 NaHSiO3,aq 0.16053E-03 -3.7944 0.16053E-03 -3.7944 0.10000E+01 0.0000 20 AlO+ 0.68268E-14 -14.1658 0.61133E-14 -14.2137 0.89549E+00 -0.0479 22 HAlO2,aq 0.55549E-08 -8.2553 0.55549E-08 -8.2553 0.10000E+01 0.0000 23 AlO2- 0.62975E-04 -4.2008 0.56321E-04 -4.2493 0.89434E+00 -0.0485 24 CH4,aq 0.35049E-19 -19.4553 0.35013E-19 -19.4558 0.99898E+00 -0.0004 29 CO,aq 0.69895E-19 -19.1556 0.69895E-19 -19.1556 0.10000E+01 0.0000 30 CO2,aq 0.33502E-08 -8.4749 0.33467E-08 -8.4754 0.99898E+00 -0.0004 31 CO3-2 0.46595E-05 -5.3317 0.31645E-05 -5.4997 0.67914E+00 -0.1680 32 CaCO3,aq 0.37148E-09 -9.4301 0.37148E-09 -9.4301 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.20328E-11 -11.6919 0.18203E-11 -11.7398 0.89549E+00 -0.0479 34 CaCl+ 0.21048E-11 -11.6768 0.18848E-11 -11.7247 0.89549E+00 -0.0479 35 CaCl2,aq 0.54155E-16 -16.2664 0.54155E-16 -16.2664 0.10000E+01 0.0000 36 CaOH+ 0.34271E-08 -8.4651 0.30689E-08 -8.5130 0.89549E+00 -0.0479 37 CaSO4,aq 0.51788E-10 -10.2858 0.51788E-10 -10.2858 0.10000E+01 0.0000 38 HCl,aq 0.51119E-14 -14.2914 0.51119E-14 -14.2914 0.10000E+01 0.0000 43 FeCl+ 0.30394E-16 -16.5172 0.27217E-16 -16.5652 0.89549E+00 -0.0479 46 FeO,aq 0.11546E-09 -9.9376 0.11546E-09 -9.9376 0.10000E+01 0.0000 47 FeOH+ 0.23805E-10 -10.6233 0.21317E-10 -10.6713 0.89549E+00 -0.0479 48 HFeO2- 0.63014E-08 -8.2006 0.56391E-08 -8.2488 0.89490E+00 -0.0482 49 FeO+ 0.20344E-14 -14.6916 0.18217E-14 -14.7395 0.89549E+00 -0.0479 51 FeO2- 0.82495E-08 -8.0836 0.73824E-08 -8.1318 0.89490E+00 -0.0482 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.81170E-09 -9.0906 0.81088E-09 -9.0910 0.99898E+00 -0.0004 54 KCl,aq 0.85573E-10 -10.0677 0.85573E-10 -10.0677 0.10000E+01 0.0000 55 KHSO4,aq 0.40023E-18 -18.3977 0.40023E-18 -18.3977 0.10000E+01 0.0000 56 KOH,aq 0.77525E-07 -7.1106 0.77525E-07 -7.1106 0.10000E+01 0.0000 57 KSO4- 0.11692E-07 -7.9321 0.10463E-07 -7.9803 0.89490E+00 -0.0482 58 MgCO3,aq 0.23186E-12 -12.6348 0.23186E-12 -12.6348 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.51776E-14 -14.2859 0.46365E-14 -14.3338 0.89549E+00 -0.0479 60 MgCl+ 0.47726E-14 -14.3212 0.42738E-14 -14.3692 0.89549E+00 -0.0479 61 MgOH+ 0.47423E-10 -10.3240 0.42467E-10 -10.3720 0.89549E+00 -0.0479 63 MnO,aq 0.41187E-09 -9.3852 0.41187E-09 -9.3852 0.10000E+01 0.0000 64 MnOH+ 0.29551E-09 -9.5294 0.26463E-09 -9.5774 0.89549E+00 -0.0479 65 MnO2-2 0.43245E-12 -12.3641 0.29369E-12 -12.5321 0.67914E+00 -0.1680 66 HMnO2- 0.15659E-10 -10.8052 0.14013E-10 -10.8535 0.89490E+00 -0.0482 69 MnCl+ 0.15782E-13 -13.8018 0.14133E-13 -13.8498 0.89549E+00 -0.0479 70 MnSO4,aq 0.92997E-13 -13.0315 0.92997E-13 -13.0315 0.10000E+01 0.0000 71 NaCl,aq 0.20024E-06 -6.6984 0.20024E-06 -6.6984 0.10000E+01 0.0000 72 NaOH,aq 0.99153E-05 -5.0037 0.99153E-05 -5.0037 0.10000E+01 0.0000 74 OH- 0.30455E-02 -2.5163 0.27237E-02 -2.5648 0.89434E+00 -0.0485 79 HPO3-2 0.11697E-16 -16.9319 0.79439E-17 -17.1000 0.67914E+00 -0.1680 82 H3PO4,aq 0.96846E-15 -15.0139 0.96846E-15 -15.0139 0.10000E+01 0.0000 83 H2PO4- 0.13378E-07 -7.8736 0.11976E-07 -7.9217 0.89519E+00 -0.0481 84 PO4-3 0.28327E-07 -7.5478 0.12300E-07 -7.9101 0.43420E+00 -0.3623 87 H2P2O7-2 0.16527E-16 -16.7818 0.11224E-16 -16.9498 0.67914E+00 -0.1680 88 HP2O7-3 0.24474E-13 -13.6113 0.10451E-13 -13.9808 0.42703E+00 -0.3695 89 P2O7-4 0.51936E-13 -13.2845 0.11707E-13 -13.9316 0.22541E+00 -0.6470 90 H2S,aq 0.54375E-16 -16.2646 0.54320E-16 -16.2650 0.99898E+00 -0.0004 97 SO3-2 0.28091E-14 -14.5514 0.19173E-14 -14.7173 0.68252E+00 -0.1659 98 HSO3- 0.27612E-16 -16.5589 0.24710E-16 -16.6071 0.89490E+00 -0.0482 99 HSO4- 0.39557E-11 -11.4028 0.35435E-11 -11.4506 0.89578E+00 -0.0478 Charge balance for all species = -.9288E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2455800E-09 -.5745431E-02 -.5788577E+01 0.0000 2 H2O 0.1000000E+01 0.5550900E+02 0.9995844E+06 0.0000 3 Cl- 0.1378961E-03 0.1380965E-03 0.4893844E+01 5.7485 4 SO4-- 0.2551532E-04 0.2552793E-04 0.2451207E+01 14.5533 5 HCO3- 0.8418334E-05 0.1308158E-04 0.7978608E+00 4.5343 6 HS- 0.9172989E-13 -.8535977E-09 -.2821813E-04 -3.4286 7 Al+++ 0.5379642E-26 0.6298036E-04 0.1698579E+01 2.3325 8 H4SiO4 0.4590934E-03 0.2892405E-02 0.2778860E+03 -3.3381 9 Ca++ 0.1413828E-07 0.1848052E-07 0.7403459E-03 11.2958 10 Mg++ 0.3536949E-10 0.8455034E-10 0.2054710E-05 8.6934 11 Fe++ 0.2091297E-12 0.1489378E-07 0.8314178E-03 6.4653 12 K+ 0.4373691E-04 0.4382622E-04 0.1712961E+01 5.2500 13 Na+ 0.5553391E-02 0.5724038E-02 0.1315383E+03 7.3534 14 Mn++ 0.2793786E-10 0.7515204E-09 0.4126940E-04 8.5912 15 HPO4-- 0.4563468E-05 0.4605172E-05 0.4418112E+00 13.8059 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8276298E-01 -.5740343E-02 -.7702264E-01 0.0000000E+00 2 H2O 0.5544559E+02 0.5545985E+02 -.1426274E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1640438E-03 0.2550532E-04 0.1385385E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385393E-03 -.8528419E-09 -.1385385E-03 0.0000000E+00 7 Al+++ 0.1630045E-01 0.6292459E-04 0.1623752E-01 0.0000000E+00 8 H4SiO4 0.5205350E-01 0.2889844E-02 0.4916366E-01 0.0000000E+00 9 Ca++ 0.5764034E-02 0.1846415E-07 0.5764016E-02 0.0000000E+00 10 Mg++ 0.3967460E-02 0.8447548E-10 0.3967460E-02 0.0000000E+00 11 Fe++ 0.3564330E-02 0.1488059E-07 0.3564315E-02 0.0000000E+00 12 K+ 0.1061359E-02 0.4378741E-04 0.1017571E-02 0.0000000E+00 13 Na+ 0.6435034E-02 0.5718970E-02 0.7160639E-03 0.0000000E+00 14 Mn++ 0.8667564E-04 0.7508550E-09 0.8667489E-04 0.0000000E+00 15 HPO4-- 0.2958197E-04 0.4601095E-05 0.2498087E-04 0.0000000E+00 Chg. balance for solid moles: 0.1048E-16 Mass of aqueous solution: 0.999541E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 4.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4885E-03 -3.311 0.1281 -0.892 2.360 0.4918E-01 apatite-OH 0.8327E-05 -5.080 0.4183E-02 -2.379 0.7707E-01 0.1329E-02 clinochlore 0.7935E-03 -3.100 0.4410 -0.356 8.126 0.1678 daphnite 0.4912E-03 -3.309 0.3505 -0.455 6.457 0.1062 chlorite-Mn 0.1733E-04 -4.761 0.1229E-01 -1.910 0.2264 0.3917E-02 hematite 0.5542E-03 -3.256 0.8850E-01 -1.053 1.631 0.1677E-01 microcline 0.1018E-02 -2.992 0.2832 -0.548 5.218 0.1106 paragonite 0.2275E-03 -3.643 0.8696E-01 -1.061 1.602 0.3006E-01 stilbite 0.5722E-02 -2.242 4.033 0.606 74.30 1.881 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5.427468 g Volume = 2.366772 cm3 Porosity: 21.0971% V(tot) - V(min): 0.63283E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4.9990000 g log = 0.6989 Original solution: 1000.0103000 g Original solution / Rock added: 200.04 (Water/Rock Ratio), log = 2.3011 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3615E-06 1.0073 0.3831E-06 0.3803E-06 CH4,gas 0.5196E-16 1.0129 0.5537E-16 0.5466E-16 H2,gas 0.1057E-05 1.0006 0.1112E-05 0.1112E-05 H2S,gas 0.1512E-14 0.9959 0.1584E-14 0.1591E-14 S2,gas 0.7225E-37 1.0000 0.7600E-37 0.7600E-37 CO,gas 0.1049E-15 1.0000 0.1104E-15 0.1104E-15 SO3,gas 0.2989E-39 1.0000 0.3144E-39 0.3144E-39 SO2,gas 0.1258E-22 1.0000 0.1323E-22 0.1323E-22 HCl,gas 0.8580E-17 1.0000 0.9026E-17 0.9026E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.78 -8.42 -2.806 0.14371E+05 -6.417 3 CH4,gas 4.81 -13.45 -18.26 -4.564 0.31173E+05 -16.257 4 H2,gas 8.29 0.33 -7.95 -4.545 0.13581E+05 -5.954 5 H2S,gas -5.94 -22.74 -16.80 -8.400 0.28686E+05 -14.800 6 S2,gas -7.03 -46.15 -39.12 -6.018 0.66795E+05 -37.119 7 CO,gas 3.51 -14.45 -17.96 -5.525 0.30661E+05 -15.957 8 SO3,gas 17.43 -24.08 -41.50 -10.376 0.70864E+05 -39.502 9 SO2,gas 1.14 -23.74 -24.88 -6.634 0.42479E+05 -22.878 10 HCl,gas 5.48 -13.57 -19.04 -9.522 0.32518E+05 -17.045 11 acmite 7.74 6.98 -0.76 -0.079 0.13000E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.42 -4.13 -0.206 0.70441E+04 20 analcite 3.37 3.01 -0.36 -0.040 0.61623E+03 21 andalusite 5.06 1.33 -3.74 -0.374 0.63782E+04 22 andradite 39.09 36.47 -2.62 -0.136 0.44682E+04 23 grossular 32.83 28.54 -4.29 -0.214 0.73250E+04 26 annite 20.21 16.96 -3.25 -0.180 0.55409E+04 27 phlogopite 27.15 23.65 -3.50 -0.194 0.59731E+04 29 anorthite 12.80 9.28 -3.51 -0.270 0.59984E+04 35 aragonite 0.99 -3.48 -4.47 -1.490 0.76329E+04 36 brucite 12.58 8.69 -3.88 -0.777 0.66305E+04 37 calcite 0.83 -3.48 -4.32 -1.439 0.73716E+04 38 carnegieite-low 9.06 6.35 -2.72 -0.388 0.46387E+04 39 carnegieite-high 10.13 6.35 -3.79 -0.541 0.64656E+04 40 carpholite-Mg 8.65 6.68 -1.97 -0.131 0.33606E+04 41 carpholite-Fe 6.78 4.45 -2.33 -0.155 0.39763E+04 42 celadonite 5.40 2.92 -2.48 -0.146 0.42294E+04 43 celadonite-Fe 3.94 0.70 -3.24 -0.191 0.55347E+04 44 chrysotile 23.94 19.40 -4.53 -0.378 0.77406E+04 50 chloritoid-Mg 13.26 10.02 -3.24 -0.216 0.55338E+04 51 chloritoid-Fe 9.24 7.79 -1.45 -0.096 0.24697E+04 52 chloritoid-Mn 11.46 9.92 -1.55 -0.103 0.26382E+04 54 coesite -2.37 -3.34 -0.97 -0.323 0.16541E+04 59 corundum 8.43 4.66 -3.77 -0.343 0.64345E+04 61 cristobalite -2.55 -3.34 -0.79 -0.263 0.13470E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.33 -0.56 -0.094 0.96232E+03 67 diopside 16.22 13.31 -2.90 -0.290 0.49558E+04 68 hedenbergite 14.24 11.08 -3.16 -0.316 0.53946E+04 75 epidote 24.78 23.54 -1.23 -0.060 0.21070E+04 76 clinozoisite 22.92 19.57 -3.35 -0.152 0.57137E+04 77 epidote-Fe 29.94 27.51 -2.43 -0.126 0.41479E+04 78 fayalite 14.08 9.59 -4.49 -0.641 0.76603E+04 79 ferrosilite 11.19 6.25 -4.93 -0.493 0.84233E+04 83 gibbsite 4.10 2.33 -1.76 -0.252 0.30135E+04 84 glaucophane 23.11 18.75 -4.36 -0.118 0.74501E+04 87 greenalite 16.19 12.72 -3.47 -0.290 0.59324E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.01 -1.24 -0.124 0.21193E+04 97 kalsilite 7.62 4.24 -3.38 -0.482 0.57642E+04 98 kaolinite -1.27 -2.01 -0.74 -0.067 0.12602E+04 99 kyanite 4.93 1.33 -3.60 -0.360 0.61550E+04 101 laumontite 2.97 2.61 -0.37 -0.024 0.62511E+03 102 lawsonite 9.68 9.28 -0.39 -0.026 0.67229E+03 103 leucite 4.17 0.91 -3.26 -0.326 0.55686E+04 105 lizardite 23.29 19.40 -3.88 -0.324 0.66308E+04 107 magnetite 20.13 19.06 -1.07 -0.087 0.18267E+04 108 minnesotaite 10.46 6.04 -4.42 -0.260 0.75420E+04 110 magnesioferrite 26.26 21.29 -4.97 -0.405 0.84797E+04 113 margarite 17.45 13.95 -3.50 -0.140 0.59799E+04 120 muscovite 2.68 2.23 -0.45 -0.026 0.76153E+03 122 nepheline 8.38 6.35 -2.03 -0.290 0.34667E+04 134 phlogopite-Na 29.73 25.75 -3.98 -0.221 0.67950E+04 136 prehnite 19.47 17.24 -2.22 -0.131 0.37973E+04 137 prehnite-Fe 22.59 21.21 -1.38 -0.083 0.23530E+04 138 pumpellyite-Fe 46.47 43.28 -3.19 -0.071 0.54433E+04 139 pumpellyite-Mg 49.19 45.51 -3.68 -0.082 0.62893E+04 145 pyroxmangite 7.42 5.25 -2.16 -0.433 0.36931E+04 146 pyrophyllite -6.10 -8.69 -2.59 -0.162 0.44213E+04 147 quartz -2.98 -3.34 -0.36 -0.119 0.60803E+03 152 rhodonite 7.46 5.25 -2.21 -0.442 0.37723E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.33 -3.99 -0.399 0.68204E+04 164 stilpnomelane-Fe 13.18 12.91 -0.27 -0.008 0.45660E+03 165 stilpnomelane-Mg 27.60 24.05 -3.54 -0.106 0.60514E+04 168 sudoite 21.22 16.70 -4.51 -0.146 0.77070E+04 171 talc 16.55 12.73 -3.83 -0.225 0.65321E+04 174 tephroite 18.11 13.84 -4.27 -0.610 0.72884E+04 177 topaz-H 4.67 1.33 -3.34 -0.304 0.57041E+04 178 tridymite -2.61 -3.34 -0.72 -0.241 0.12353E+04 187 wairakite 4.06 2.61 -1.45 -0.085 0.24759E+04 188 walstromite 11.53 7.96 -3.57 -0.714 0.60959E+04 189 wollastonite 10.48 7.96 -2.52 -0.505 0.43098E+04 190 pseudo-wollastonite 11.02 7.96 -3.06 -0.612 0.52284E+04 191 zoisite 22.96 19.57 -3.39 -0.154 0.57862E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.95 -3.39 -0.210 0.57928E+04 194 beidellite-H -2.24 -6.82 -4.58 -0.292 0.78117E+04 195 beidellite-K -1.44 -5.08 -3.65 -0.223 0.62299E+04 196 beidellite-Mg -1.71 -5.38 -3.67 -0.227 0.62746E+04 197 beidellite-Na -1.26 -4.39 -3.13 -0.192 0.53486E+04 199 chalcedony -2.79 -3.34 -0.54 -0.181 0.92835E+03 201 montmorillonite-Ca -2.21 -4.72 -2.51 -0.155 0.42866E+04 202 montmorillonite-K -2.16 -4.86 -2.69 -0.165 0.46013E+04 203 montmorillonite-Mg -2.40 -5.15 -2.75 -0.170 0.46994E+04 204 montmorillonite-Na -1.96 -4.16 -2.20 -0.135 0.37582E+04 205 nontronite-Ca 3.28 2.98 -0.30 -0.019 0.51108E+03 206 nontronite-H 2.60 1.12 -1.48 -0.099 0.25257E+04 207 nontronite-K 3.40 2.85 -0.55 -0.036 0.94730E+03 208 nontronite-Mg 3.14 2.55 -0.59 -0.038 0.10045E+04 209 nontronite-Na 3.58 3.54 -0.04 -0.003 0.67725E+02 224 tobermorite 9.84 6.07 -3.77 -1.028 0.64332E+04 233 boehmite 4.43 2.33 -2.10 -0.350 0.35808E+04 235 ferrous-oxide 9.82 6.47 -3.36 -0.840 0.57352E+04 240 silica-amorphous -2.08 -3.34 -1.26 -0.419 0.21485E+04 242 an20ab80 2.08 1.59 -0.48 -0.037 0.82807E+03 243 an25ab75 2.71 2.07 -0.63 -0.049 0.10830E+04 244 an30ab70 3.34 2.56 -0.79 -0.061 0.13463E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 4.9990000 g New total amount of reactant added: 5.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.9362E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 5.1990000 Water: Moles liquid = 0.5546E+02 kg liquid = 0.9991E+00 Moles total = 0.5544E+02 kg total = 0.9988E+00 Activity = 1.0000 Stoichiometric ionic strength = .3411892E-02 Osmotic coef. = 0.9682 True ionic strength = .5817119E-02 Chg. balance for total moles = -.9362E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.23549E-09 -9.6280 0.21090E-09 -9.6759 0.89559E+00 -0.0479 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13789E-03 -3.8605 0.12323E-03 -3.9093 0.89368E+00 -0.0488 4 SO4-- 0.25516E-04 -4.5932 0.17249E-04 -4.7632 0.67600E+00 -0.1701 5 HCO3- 0.82759E-05 -5.0822 0.73998E-05 -5.1308 0.89413E+00 -0.0486 6 HS- 0.98582E-13 -13.0062 0.88105E-13 -13.0550 0.89372E+00 -0.0488 7 Al+++ 0.47829E-26 -26.3203 0.20172E-26 -26.6953 0.42175E+00 -0.3749 8 H4SiO4 0.44783E-03 -3.3489 0.44783E-03 -3.3489 0.10000E+01 0.0000 9 Ca++ 0.15514E-07 -7.8093 0.10460E-07 -7.9804 0.67426E+00 -0.1712 10 Mg++ 0.33106E-10 -10.4801 0.22286E-10 -10.6520 0.67318E+00 -0.1719 11 Fe++ 0.19575E-12 -12.7083 0.13182E-12 -12.8800 0.67343E+00 -0.1717 12 K+ 0.45188E-04 -4.3450 0.40408E-04 -4.3935 0.89422E+00 -0.0486 13 Na+ 0.57377E-02 -2.2413 0.51274E-02 -2.2901 0.89363E+00 -0.0488 14 Mn++ 0.26150E-10 -10.5825 0.17615E-10 -10.7541 0.67363E+00 -0.1716 15 HPO4-- 0.37437E-05 -5.4267 0.25309E-05 -5.5967 0.67603E+00 -0.1700 16 HSiO3- 0.23182E-02 -2.6349 0.20717E-02 -2.6837 0.89368E+00 -0.0488 17 Ca(HSiO3)+ 0.54294E-09 -9.2652 0.48554E-09 -9.3138 0.89428E+00 -0.0485 18 Mg(HSiO3)+ 0.14396E-11 -11.8418 0.12874E-11 -11.8903 0.89428E+00 -0.0485 19 NaHSiO3,aq 0.16871E-03 -3.7729 0.16871E-03 -3.7729 0.10000E+01 0.0000 20 AlO+ 0.65466E-14 -14.1840 0.58545E-14 -14.2325 0.89428E+00 -0.0485 22 HAlO2,aq 0.55549E-08 -8.2553 0.55549E-08 -8.2553 0.10000E+01 0.0000 23 AlO2- 0.65850E-04 -4.1814 0.58811E-04 -4.2305 0.89310E+00 -0.0491 24 CH4,aq 0.37128E-19 -19.4303 0.37089E-19 -19.4308 0.99895E+00 -0.0005 29 CO,aq 0.67703E-19 -19.1694 0.67703E-19 -19.1694 0.10000E+01 0.0000 30 CO2,aq 0.31499E-08 -8.5017 0.31466E-08 -8.5022 0.99895E+00 -0.0005 31 CO3-2 0.48025E-05 -5.3185 0.32441E-05 -5.4889 0.67549E+00 -0.1704 32 CaCO3,aq 0.41561E-09 -9.3813 0.41561E-09 -9.3813 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.21810E-11 -11.6614 0.19504E-11 -11.7099 0.89428E+00 -0.0485 34 CaCl+ 0.22970E-11 -11.6388 0.20541E-11 -11.6874 0.89428E+00 -0.0485 35 CaCl2,aq 0.58940E-16 -16.2296 0.58940E-16 -16.2296 0.10000E+01 0.0000 36 CaOH+ 0.39108E-08 -8.4077 0.34973E-08 -8.4563 0.89428E+00 -0.0485 37 CaSO4,aq 0.56218E-10 -10.2501 0.56218E-10 -10.2501 0.10000E+01 0.0000 38 HCl,aq 0.48887E-14 -14.3108 0.48887E-14 -14.3108 0.10000E+01 0.0000 43 FeCl+ 0.28293E-16 -16.5483 0.25302E-16 -16.5969 0.89428E+00 -0.0485 46 FeO,aq 0.11719E-09 -9.9311 0.11719E-09 -9.9311 0.10000E+01 0.0000 47 FeOH+ 0.23171E-10 -10.6351 0.20722E-10 -10.6836 0.89428E+00 -0.0485 48 HFeO2- 0.66879E-08 -8.1747 0.59768E-08 -8.2235 0.89368E+00 -0.0488 49 FeO+ 0.19509E-14 -14.7098 0.17446E-14 -14.7583 0.89428E+00 -0.0485 51 FeO2- 0.86259E-08 -8.0642 0.77088E-08 -8.1130 0.89368E+00 -0.0488 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.83630E-09 -9.0776 0.83542E-09 -9.0781 0.99895E+00 -0.0005 54 KCl,aq 0.88171E-10 -10.0547 0.88171E-10 -10.0547 0.10000E+01 0.0000 55 KHSO4,aq 0.39336E-18 -18.4052 0.39336E-18 -18.4052 0.10000E+01 0.0000 56 KOH,aq 0.83525E-07 -7.0782 0.83525E-07 -7.0782 0.10000E+01 0.0000 57 KSO4- 0.12016E-07 -7.9203 0.10738E-07 -7.9691 0.89368E+00 -0.0488 58 MgCO3,aq 0.22126E-12 -12.6551 0.22126E-12 -12.6551 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.47383E-14 -14.3244 0.42374E-14 -14.3729 0.89428E+00 -0.0485 60 MgCl+ 0.44427E-14 -14.3524 0.39730E-14 -14.4009 0.89428E+00 -0.0485 61 MgOH+ 0.46160E-10 -10.3357 0.41280E-10 -10.3843 0.89428E+00 -0.0485 63 MnO,aq 0.41806E-09 -9.3788 0.41806E-09 -9.3788 0.10000E+01 0.0000 64 MnOH+ 0.28764E-09 -9.5412 0.25723E-09 -9.5897 0.89428E+00 -0.0485 65 MnO2-2 0.48119E-12 -12.3177 0.32504E-12 -12.4881 0.67549E+00 -0.1704 66 HMnO2- 0.16620E-10 -10.7794 0.14853E-10 -10.8282 0.89368E+00 -0.0488 69 MnCl+ 0.14691E-13 -13.8329 0.13138E-13 -13.8815 0.89428E+00 -0.0485 70 MnSO4,aq 0.86109E-13 -13.0649 0.86109E-13 -13.0649 0.10000E+01 0.0000 71 NaCl,aq 0.20632E-06 -6.6855 0.20632E-06 -6.6855 0.10000E+01 0.0000 72 NaOH,aq 0.10683E-04 -4.9713 0.10683E-04 -4.9713 0.10000E+01 0.0000 74 OH- 0.31845E-02 -2.4970 0.28441E-02 -2.5461 0.89310E+00 -0.0491 79 HPO3-2 0.98864E-17 -17.0050 0.66782E-17 -17.1753 0.67549E+00 -0.1704 82 H3PO4,aq 0.72475E-15 -15.1398 0.72475E-15 -15.1398 0.10000E+01 0.0000 83 H2PO4- 0.10468E-07 -7.9801 0.93581E-08 -8.0288 0.89397E+00 -0.0487 84 PO4-3 0.24420E-07 -7.6123 0.10480E-07 -7.9796 0.42915E+00 -0.3674 87 H2P2O7-2 0.10147E-16 -16.9937 0.68539E-17 -17.1641 0.67549E+00 -0.1704 88 HP2O7-3 0.15796E-13 -13.8014 0.66638E-14 -14.1763 0.42185E+00 -0.3748 89 P2O7-4 0.35328E-13 -13.4519 0.77948E-14 -14.1082 0.22064E+00 -0.6563 90 H2S,aq 0.55888E-16 -16.2527 0.55830E-16 -16.2531 0.99895E+00 -0.0005 97 SO3-2 0.28938E-14 -14.5385 0.19648E-14 -14.7067 0.67895E+00 -0.1682 98 HSO3- 0.27135E-16 -16.5665 0.24250E-16 -16.6153 0.89368E+00 -0.0488 99 HSO4- 0.37732E-11 -11.4233 0.33754E-11 -11.4717 0.89458E+00 -0.0484 Charge balance for all species = -.9281E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2354921E-09 -.5950471E-02 -.5995097E+01 0.0000 2 H2O 0.1000000E+01 0.5550909E+02 0.9995760E+06 0.0000 3 Cl- 0.1378947E-03 0.1381011E-03 0.4893959E+01 5.7666 4 SO4-- 0.2551586E-04 0.2552883E-04 0.2451268E+01 14.5886 5 HCO3- 0.8275946E-05 0.1308202E-04 0.7978797E+00 4.5451 6 HS- 0.9858168E-13 -.8945017E-09 -.2957003E-04 -3.3791 7 Al+++ 0.4782922E-26 0.6585548E-04 0.1776103E+01 2.3325 8 H4SiO4 0.4478268E-03 0.2934717E-02 0.2819483E+03 -3.3489 9 Ca++ 0.1551394E-07 0.2044396E-07 0.8189949E-03 11.3714 10 Mg++ 0.3310641E-10 0.8093620E-10 0.1966861E-05 8.6999 11 Fe++ 0.1957467E-12 0.1565788E-07 0.8740635E-03 6.4718 12 K+ 0.4518799E-04 0.4528362E-04 0.1769906E+01 5.2824 13 Na+ 0.5737744E-02 0.5917344E-02 0.1359791E+03 7.3858 14 Mn++ 0.2614980E-10 0.7490493E-09 0.4113329E-04 8.5977 15 HPO4-- 0.3743692E-05 0.3778580E-05 0.3625059E+00 13.7551 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8607468E-01 -.5945002E-02 -.8012968E-01 0.0000000E+00 2 H2O 0.5544308E+02 0.5545808E+02 -.1499646E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1695865E-03 0.2550536E-04 0.1440811E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1440820E-03 -.8936796E-09 -.1440811E-03 0.0000000E+00 7 Al+++ 0.1695260E-01 0.6579496E-04 0.1688680E-01 0.0000000E+00 8 H4SiO4 0.5413606E-01 0.2932020E-02 0.5120404E-01 0.0000000E+00 9 Ca++ 0.5994063E-02 0.2042517E-07 0.5994042E-02 0.0000000E+00 10 Mg++ 0.4126190E-02 0.8086181E-10 0.4126190E-02 0.0000000E+00 11 Fe++ 0.3706932E-02 0.1564349E-07 0.3706916E-02 0.0000000E+00 12 K+ 0.1103822E-02 0.4524200E-04 0.1058580E-02 0.0000000E+00 13 Na+ 0.6686083E-02 0.5911906E-02 0.7741770E-03 0.0000000E+00 14 Mn++ 0.9014336E-04 0.7483609E-09 0.9014261E-04 0.0000000E+00 15 HPO4-- 0.3076548E-04 0.3775108E-05 0.2699037E-04 0.0000000E+00 Chg. balance for solid moles: 0.8931E-17 Mass of aqueous solution: 0.999518E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 5.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5503E-03 -3.259 0.1443 -0.841 2.554 0.5540E-01 apatite-OH 0.8997E-05 -5.046 0.4519E-02 -2.345 0.7999E-01 0.1436E-02 clinochlore 0.8252E-03 -3.083 0.4587 -0.338 8.119 0.1745 daphnite 0.5109E-03 -3.292 0.3645 -0.438 6.452 0.1105 chlorite-Mn 0.1803E-04 -4.744 0.1278E-01 -1.893 0.2262 0.4073E-02 hematite 0.5763E-03 -3.239 0.9204E-01 -1.036 1.629 0.1744E-01 microcline 0.1059E-02 -2.975 0.2946 -0.531 5.215 0.1151 paragonite 0.2238E-03 -3.650 0.8555E-01 -1.068 1.514 0.2957E-01 stilbite 0.5949E-02 -2.226 4.192 0.622 74.21 1.955 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5.649458 g Volume = 2.463367 cm3 Porosity: 20.0102% V(tot) - V(min): 0.61623E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 5.1990000 g log = 0.7159 Original solution: 1000.0103000 g Original solution / Rock added: 192.35 (Water/Rock Ratio), log = 2.2841 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3399E-06 1.0073 0.3602E-06 0.3576E-06 CH4,gas 0.5505E-16 1.0129 0.5865E-16 0.5790E-16 H2,gas 0.1089E-05 1.0006 0.1146E-05 0.1145E-05 H2S,gas 0.1554E-14 0.9959 0.1628E-14 0.1635E-14 S2,gas 0.7190E-37 1.0000 0.7564E-37 0.7564E-37 CO,gas 0.1016E-15 1.0000 0.1069E-15 0.1069E-15 SO3,gas 0.2727E-39 1.0000 0.2868E-39 0.2868E-39 SO2,gas 0.1182E-22 1.0000 0.1243E-22 0.1243E-22 HCl,gas 0.8206E-17 1.0000 0.8632E-17 0.8632E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.81 -8.44 -2.814 0.14417E+05 -6.443 3 CH4,gas 4.81 -13.42 -18.23 -4.558 0.31130E+05 -16.232 4 H2,gas 8.29 0.35 -7.94 -4.538 0.13559E+05 -5.941 5 H2S,gas -5.94 -22.73 -16.79 -8.394 0.28666E+05 -14.788 6 S2,gas -7.03 -46.15 -39.12 -6.019 0.66798E+05 -37.121 7 CO,gas 3.51 -14.46 -17.97 -5.530 0.30685E+05 -15.971 8 SO3,gas 17.43 -24.12 -41.54 -10.386 0.70932E+05 -39.542 9 SO2,gas 1.14 -23.77 -24.91 -6.641 0.42525E+05 -22.905 10 HCl,gas 5.48 -13.59 -19.06 -9.532 0.32551E+05 -17.064 11 acmite 7.74 6.99 -0.75 -0.078 0.12815E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.41 -4.14 -0.207 0.70662E+04 20 analcite 3.37 3.02 -0.35 -0.039 0.59780E+03 21 andalusite 5.06 1.32 -3.75 -0.375 0.63967E+04 22 andradite 39.09 36.67 -2.42 -0.126 0.41366E+04 23 grossular 32.83 28.73 -4.10 -0.205 0.69933E+04 26 annite 20.21 16.98 -3.23 -0.179 0.55077E+04 27 phlogopite 27.15 23.67 -3.48 -0.193 0.59399E+04 29 anorthite 12.80 9.34 -3.46 -0.266 0.59063E+04 35 aragonite 0.99 -3.44 -4.42 -1.474 0.75496E+04 36 brucite 12.58 8.70 -3.88 -0.775 0.66194E+04 37 calcite 0.83 -3.44 -4.27 -1.423 0.72883E+04 38 carnegieite-low 9.06 6.37 -2.70 -0.385 0.46019E+04 39 carnegieite-high 10.13 6.37 -3.77 -0.538 0.64287E+04 40 carpholite-Mg 8.65 6.67 -1.98 -0.132 0.33864E+04 41 carpholite-Fe 6.78 4.44 -2.34 -0.156 0.40021E+04 42 celadonite 5.40 2.92 -2.48 -0.146 0.42368E+04 43 celadonite-Fe 3.94 0.69 -3.25 -0.191 0.55421E+04 44 chrysotile 23.94 19.40 -4.54 -0.378 0.77442E+04 50 chloritoid-Mg 13.26 10.02 -3.25 -0.216 0.55412E+04 51 chloritoid-Fe 9.24 7.79 -1.45 -0.097 0.24771E+04 52 chloritoid-Mn 11.46 9.91 -1.55 -0.103 0.26455E+04 54 coesite -2.37 -3.35 -0.98 -0.327 0.16725E+04 59 corundum 8.43 4.66 -3.77 -0.343 0.64345E+04 61 cristobalite -2.55 -3.35 -0.80 -0.267 0.13654E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.33 -0.56 -0.094 0.96232E+03 67 diopside 16.22 13.37 -2.84 -0.284 0.48526E+04 68 hedenbergite 14.24 11.15 -3.10 -0.310 0.52914E+04 75 epidote 24.78 23.66 -1.12 -0.054 0.19044E+04 76 clinozoisite 22.92 19.69 -3.23 -0.147 0.55110E+04 77 epidote-Fe 29.94 27.63 -2.31 -0.120 0.39452E+04 78 fayalite 14.08 9.59 -4.48 -0.641 0.76567E+04 79 ferrosilite 11.19 6.25 -4.94 -0.494 0.84380E+04 83 gibbsite 4.10 2.33 -1.76 -0.252 0.30135E+04 84 glaucophane 23.11 18.75 -4.37 -0.118 0.74538E+04 87 greenalite 16.19 12.72 -3.48 -0.290 0.59361E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.02 -1.23 -0.123 0.21008E+04 97 kalsilite 7.62 4.27 -3.35 -0.479 0.57273E+04 98 kaolinite -1.27 -2.03 -0.76 -0.069 0.12971E+04 99 kyanite 4.93 1.32 -3.62 -0.362 0.61734E+04 101 laumontite 2.97 2.64 -0.33 -0.022 0.56983E+03 102 lawsonite 9.68 9.34 -0.34 -0.023 0.58017E+03 103 leucite 4.17 0.92 -3.25 -0.325 0.55502E+04 105 lizardite 23.29 19.40 -3.89 -0.324 0.66345E+04 107 magnetite 20.13 19.07 -1.06 -0.087 0.18156E+04 108 minnesotaite 10.46 6.02 -4.44 -0.261 0.75826E+04 110 magnesioferrite 26.26 21.30 -4.96 -0.405 0.84687E+04 113 margarite 17.45 14.00 -3.45 -0.138 0.58877E+04 120 muscovite 2.68 2.23 -0.45 -0.026 0.76153E+03 122 nepheline 8.38 6.37 -2.01 -0.287 0.34298E+04 134 phlogopite-Na 29.73 25.77 -3.96 -0.220 0.67618E+04 136 prehnite 19.47 17.36 -2.11 -0.124 0.35946E+04 137 prehnite-Fe 22.59 21.33 -1.26 -0.076 0.21503E+04 138 pumpellyite-Fe 46.47 43.53 -2.94 -0.065 0.50269E+04 139 pumpellyite-Mg 49.19 45.75 -3.44 -0.076 0.58729E+04 145 pyroxmangite 7.42 5.25 -2.17 -0.433 0.37004E+04 146 pyrophyllite -6.10 -8.73 -2.63 -0.165 0.44950E+04 147 quartz -2.98 -3.35 -0.37 -0.122 0.62646E+03 152 rhodonite 7.46 5.25 -2.21 -0.443 0.37797E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.32 -4.01 -0.401 0.68388E+04 164 stilpnomelane-Fe 13.18 12.87 -0.31 -0.009 0.52109E+03 165 stilpnomelane-Mg 27.60 24.01 -3.58 -0.107 0.61159E+04 168 sudoite 21.22 16.68 -4.53 -0.146 0.77402E+04 171 talc 16.55 12.70 -3.85 -0.226 0.65726E+04 174 tephroite 18.11 13.85 -4.27 -0.609 0.72847E+04 177 topaz-H 4.67 1.32 -3.35 -0.305 0.57225E+04 178 tridymite -2.61 -3.35 -0.73 -0.245 0.12537E+04 187 wairakite 4.06 2.64 -1.42 -0.083 0.24207E+04 188 walstromite 11.53 8.02 -3.51 -0.701 0.59853E+04 189 wollastonite 10.48 8.02 -2.46 -0.492 0.41992E+04 190 pseudo-wollastonite 11.02 8.02 -3.00 -0.599 0.51178E+04 191 zoisite 22.96 19.69 -3.27 -0.149 0.55835E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -4.98 -3.42 -0.212 0.58391E+04 194 beidellite-H -2.24 -6.86 -4.61 -0.294 0.78793E+04 195 beidellite-K -1.44 -5.11 -3.68 -0.225 0.62792E+04 196 beidellite-Mg -1.71 -5.42 -3.71 -0.230 0.63404E+04 197 beidellite-Na -1.26 -4.42 -3.16 -0.194 0.53980E+04 199 chalcedony -2.79 -3.35 -0.55 -0.185 0.94677E+03 201 montmorillonite-Ca -2.21 -4.75 -2.54 -0.157 0.43353E+04 202 montmorillonite-K -2.16 -4.89 -2.73 -0.167 0.46532E+04 203 montmorillonite-Mg -2.40 -5.19 -2.79 -0.173 0.47677E+04 204 montmorillonite-Na -1.96 -4.19 -2.23 -0.137 0.38100E+04 205 nontronite-Ca 3.28 2.95 -0.33 -0.021 0.55742E+03 206 nontronite-H 2.60 1.08 -1.52 -0.102 0.25933E+04 207 nontronite-K 3.40 2.82 -0.58 -0.037 0.99668E+03 208 nontronite-Mg 3.14 2.51 -0.63 -0.041 0.10703E+04 209 nontronite-Na 3.58 3.51 -0.07 -0.004 0.11710E+03 224 tobermorite 9.84 6.12 -3.72 -1.014 0.63442E+04 233 boehmite 4.43 2.33 -2.10 -0.350 0.35808E+04 235 ferrous-oxide 9.82 6.47 -3.35 -0.838 0.57241E+04 240 silica-amorphous -2.08 -3.35 -1.27 -0.423 0.21670E+04 242 an20ab80 2.08 1.61 -0.47 -0.036 0.80965E+03 243 an25ab75 2.71 2.09 -0.62 -0.048 0.10600E+04 244 an30ab70 3.34 2.57 -0.77 -0.059 0.13186E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 5.1990000 g New total amount of reactant added: 5.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.9363E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 5.3990000 Water: Moles liquid = 0.5546E+02 kg liquid = 0.9990E+00 Moles total = 0.5544E+02 kg total = 0.9988E+00 Activity = 1.0000 Stoichiometric ionic strength = .3521304E-02 Osmotic coef. = 0.9677 True ionic strength = .6002879E-02 Chg. balance for total moles = -.9363E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.22617E-09 -9.6456 0.20230E-09 -9.6940 0.89443E+00 -0.0485 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13789E-03 -3.8605 0.12307E-03 -3.9099 0.89247E+00 -0.0494 4 SO4-- 0.25516E-04 -4.5932 0.17158E-04 -4.7655 0.67244E+00 -0.1723 5 HCO3- 0.81368E-05 -5.0895 0.72657E-05 -5.1387 0.89294E+00 -0.0492 6 HS- 0.10569E-12 -12.9760 0.94334E-13 -13.0253 0.89252E+00 -0.0494 7 Al+++ 0.42718E-26 -26.3694 0.17801E-26 -26.7496 0.41671E+00 -0.3802 8 H4SiO4 0.43720E-03 -3.3593 0.43720E-03 -3.3593 0.10000E+01 0.0000 9 Ca++ 0.16976E-07 -7.7702 0.11385E-07 -7.9437 0.67067E+00 -0.1735 10 Mg++ 0.31068E-10 -10.5077 0.20802E-10 -10.6819 0.66955E+00 -0.1742 11 Fe++ 0.18369E-12 -12.7359 0.12304E-12 -12.9100 0.66982E+00 -0.1740 12 K+ 0.46643E-04 -4.3312 0.41653E-04 -4.3804 0.89303E+00 -0.0491 13 Na+ 0.59226E-02 -2.2275 0.52854E-02 -2.2769 0.89242E+00 -0.0494 14 Mn++ 0.24539E-10 -10.6101 0.16442E-10 -10.7841 0.67002E+00 -0.1739 15 HPO4-- 0.30913E-05 -5.5099 0.20788E-05 -5.6822 0.67248E+00 -0.1723 16 HSiO3- 0.23627E-02 -2.6266 0.21086E-02 -2.6760 0.89247E+00 -0.0494 17 Ca(HSiO3)+ 0.60228E-09 -9.2202 0.53789E-09 -9.2693 0.89309E+00 -0.0491 18 Mg(HSiO3)+ 0.13695E-11 -11.8635 0.12231E-11 -11.9126 0.89309E+00 -0.0491 19 NaHSiO3,aq 0.17701E-03 -3.7520 0.17701E-03 -3.7520 0.10000E+01 0.0000 20 AlO+ 0.62877E-14 -14.2015 0.56155E-14 -14.2506 0.89309E+00 -0.0491 22 HAlO2,aq 0.55549E-08 -8.2553 0.55549E-08 -8.2553 0.10000E+01 0.0000 23 AlO2- 0.68746E-04 -4.1628 0.61313E-04 -4.2124 0.89188E+00 -0.0497 24 CH4,aq 0.39240E-19 -19.4063 0.39197E-19 -19.4067 0.99891E+00 -0.0005 29 CO,aq 0.65626E-19 -19.1829 0.65626E-19 -19.1829 0.10000E+01 0.0000 30 CO2,aq 0.29667E-08 -8.5277 0.29634E-08 -8.5282 0.99891E+00 -0.0005 31 CO3-2 0.49422E-05 -5.3061 0.33208E-05 -5.4788 0.67192E+00 -0.1727 32 CaCO3,aq 0.46306E-09 -9.3344 0.46306E-09 -9.3344 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.23338E-11 -11.6319 0.20843E-11 -11.6810 0.89309E+00 -0.0491 34 CaCl+ 0.25000E-11 -11.6021 0.22327E-11 -11.6512 0.89309E+00 -0.0491 35 CaCl2,aq 0.63976E-16 -16.1940 0.63976E-16 -16.1940 0.10000E+01 0.0000 36 CaOH+ 0.44435E-08 -8.3523 0.39685E-08 -8.4014 0.89309E+00 -0.0491 37 CaSO4,aq 0.60867E-10 -10.2156 0.60867E-10 -10.2156 0.10000E+01 0.0000 38 HCl,aq 0.46828E-14 -14.3295 0.46828E-14 -14.3295 0.10000E+01 0.0000 43 FeCl+ 0.26407E-16 -16.5783 0.23584E-16 -16.6274 0.89309E+00 -0.0491 46 FeO,aq 0.11889E-09 -9.9248 0.11889E-09 -9.9248 0.10000E+01 0.0000 47 FeOH+ 0.22578E-10 -10.6463 0.20164E-10 -10.6954 0.89309E+00 -0.0491 48 HFeO2- 0.70832E-08 -8.1498 0.63216E-08 -8.1992 0.89247E+00 -0.0494 49 FeO+ 0.18737E-14 -14.7273 0.16734E-14 -14.7764 0.89309E+00 -0.0491 51 FeO2- 0.90051E-08 -8.0455 0.80368E-08 -8.0949 0.89247E+00 -0.0494 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.86077E-09 -9.0651 0.85984E-09 -9.0656 0.99891E+00 -0.0005 54 KCl,aq 0.90765E-10 -10.0421 0.90765E-10 -10.0421 0.10000E+01 0.0000 55 KHSO4,aq 0.38689E-18 -18.4124 0.38689E-18 -18.4124 0.10000E+01 0.0000 56 KOH,aq 0.89763E-07 -7.0469 0.89763E-07 -7.0469 0.10000E+01 0.0000 57 KSO4- 0.12338E-07 -7.9088 0.11011E-07 -7.9582 0.89247E+00 -0.0494 58 MgCO3,aq 0.21141E-12 -12.6749 0.21141E-12 -12.6749 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.43482E-14 -14.3617 0.38834E-14 -14.4108 0.89309E+00 -0.0491 60 MgCl+ 0.41466E-14 -14.3823 0.37033E-14 -14.4314 0.89309E+00 -0.0491 61 MgOH+ 0.44978E-10 -10.3470 0.40169E-10 -10.3961 0.89309E+00 -0.0491 63 MnO,aq 0.42413E-09 -9.3725 0.42413E-09 -9.3725 0.10000E+01 0.0000 64 MnOH+ 0.28027E-09 -9.5524 0.25031E-09 -9.6015 0.89309E+00 -0.0491 65 MnO2-2 0.53342E-12 -12.2729 0.35842E-12 -12.4456 0.67192E+00 -0.1727 66 HMnO2- 0.17602E-10 -10.7544 0.15709E-10 -10.8038 0.89247E+00 -0.0494 69 MnCl+ 0.13712E-13 -13.8629 0.12246E-13 -13.9120 0.89309E+00 -0.0491 70 MnSO4,aq 0.79951E-13 -13.0972 0.79951E-13 -13.0972 0.10000E+01 0.0000 71 NaCl,aq 0.21239E-06 -6.6729 0.21239E-06 -6.6729 0.10000E+01 0.0000 72 NaOH,aq 0.11481E-04 -4.9400 0.11481E-04 -4.9400 0.10000E+01 0.0000 74 OH- 0.33246E-02 -2.4783 0.29651E-02 -2.5280 0.89188E+00 -0.0497 79 HPO3-2 0.84024E-17 -17.0756 0.56457E-17 -17.2483 0.67192E+00 -0.1727 82 H3PO4,aq 0.54769E-15 -15.2615 0.54769E-15 -15.2615 0.10000E+01 0.0000 83 H2PO4- 0.82583E-08 -8.0831 0.73729E-08 -8.1324 0.89278E+00 -0.0493 84 PO4-3 0.21154E-07 -7.6746 0.89743E-08 -8.0470 0.42423E+00 -0.3724 87 H2P2O7-2 0.63317E-17 -17.1985 0.42544E-17 -17.3712 0.67192E+00 -0.1727 88 HP2O7-3 0.10346E-13 -13.9852 0.43124E-14 -14.3653 0.41682E+00 -0.3800 89 P2O7-4 0.24343E-13 -13.6136 0.52590E-14 -14.2791 0.21604E+00 -0.6655 90 H2S,aq 0.57399E-16 -16.2411 0.57337E-16 -16.2416 0.99891E+00 -0.0005 97 SO3-2 0.29781E-14 -14.5261 0.20116E-14 -14.6965 0.67546E+00 -0.1704 98 HSO3- 0.26684E-16 -16.5737 0.23815E-16 -16.6232 0.89247E+00 -0.0494 99 HSO4- 0.36049E-11 -11.4431 0.32206E-11 -11.4921 0.89340E+00 -0.0490 Charge balance for all species = -.9291E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2261710E-09 -.6155860E-02 -.6201964E+01 0.0000 2 H2O 0.1000000E+01 0.5550918E+02 0.9995676E+06 0.0000 3 Cl- 0.1378933E-03 0.1381058E-03 0.4894075E+01 5.7842 4 SO4-- 0.2551639E-04 0.2552973E-04 0.2451330E+01 14.6225 5 HCO3- 0.8136786E-05 0.1308246E-04 0.7978985E+00 4.5553 6 HS- 0.1056937E-12 -.9357781E-09 -.3093422E-04 -3.3313 7 Al+++ 0.4271792E-26 0.6875164E-04 0.1854193E+01 2.3325 8 H4SiO4 0.4372028E-03 0.2976892E-02 0.2859973E+03 -3.3593 9 Ca++ 0.1697608E-07 0.2255066E-07 0.9033814E-03 11.4444 10 Mg++ 0.3106802E-10 0.7763516E-10 0.1886622E-05 8.7061 11 Fe++ 0.1836924E-12 0.1643351E-07 0.9173523E-03 6.4781 12 K+ 0.4664270E-04 0.4674489E-04 0.1827002E+01 5.3137 13 Na+ 0.5922566E-02 0.6111268E-02 0.1404340E+03 7.4171 14 Mn++ 0.2453927E-10 0.7471672E-09 0.4102953E-04 8.6040 15 HPO4-- 0.3091293E-05 0.3120706E-05 0.2993884E+00 13.7058 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8938638E-01 -.6149995E-02 -.8323639E-01 0.0000000E+00 2 H2O 0.5544057E+02 0.5545630E+02 -.1572859E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1751292E-03 0.2550540E-04 0.1496238E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1496247E-03 -.9348866E-09 -.1496238E-03 0.0000000E+00 7 Al+++ 0.1760474E-01 0.6868614E-04 0.1753606E-01 0.0000000E+00 8 H4SiO4 0.5621862E-01 0.2974056E-02 0.5324456E-01 0.0000000E+00 9 Ca++ 0.6224091E-02 0.2252918E-07 0.6224069E-02 0.0000000E+00 10 Mg++ 0.4284921E-02 0.7756120E-10 0.4284921E-02 0.0000000E+00 11 Fe++ 0.3849533E-02 0.1641786E-07 0.3849517E-02 0.0000000E+00 12 K+ 0.1146285E-02 0.4670036E-04 0.1099584E-02 0.0000000E+00 13 Na+ 0.6937131E-02 0.6105446E-02 0.8316851E-03 0.0000000E+00 14 Mn++ 0.9361108E-04 0.7464554E-09 0.9361033E-04 0.0000000E+00 15 HPO4-- 0.3194900E-04 0.3117733E-05 0.2883126E-04 0.0000000E+00 Chg. balance for solid moles: -.6322E-17 Mass of aqueous solution: 0.999494E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 5.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6115E-03 -3.214 0.1604 -0.795 2.731 0.6156E-01 apatite-OH 0.9610E-05 -5.017 0.4828E-02 -2.316 0.8222E-01 0.1534E-02 clinochlore 0.8570E-03 -3.067 0.4763 -0.322 8.113 0.1812 daphnite 0.5305E-03 -3.275 0.3785 -0.422 6.447 0.1147 chlorite-Mn 0.1872E-04 -4.728 0.1327E-01 -1.877 0.2261 0.4230E-02 hematite 0.5985E-03 -3.223 0.9558E-01 -1.020 1.628 0.1812E-01 microcline 0.1100E-02 -2.959 0.3061 -0.514 5.213 0.1196 paragonite 0.2202E-03 -3.657 0.8415E-01 -1.075 1.433 0.2909E-01 stilbite 0.6176E-02 -2.209 4.352 0.639 74.13 2.030 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5.871460 g Volume = 2.559985 cm3 Porosity: 18.9776% V(tot) - V(min): 0.59962E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 5.3990000 g log = 0.7323 Original solution: 1000.0103000 g Original solution / Rock added: 185.22 (Water/Rock Ratio), log = 2.2677 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3201E-06 1.0073 0.3392E-06 0.3368E-06 CH4,gas 0.5817E-16 1.0129 0.6199E-16 0.6119E-16 H2,gas 0.1120E-05 1.0006 0.1179E-05 0.1179E-05 H2S,gas 0.1596E-14 0.9959 0.1672E-14 0.1679E-14 S2,gas 0.7159E-37 1.0000 0.7531E-37 0.7531E-37 CO,gas 0.9851E-16 1.0000 0.1036E-15 0.1036E-15 SO3,gas 0.2496E-39 1.0000 0.2625E-39 0.2625E-39 SO2,gas 0.1113E-22 1.0000 0.1171E-22 0.1171E-22 HCl,gas 0.7860E-17 1.0000 0.8268E-17 0.8268E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 0.19715E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.83 -8.47 -2.823 0.14461E+05 -6.470 3 CH4,gas 4.81 -13.40 -18.21 -4.552 0.31089E+05 -16.208 4 H2,gas 8.29 0.36 -7.93 -4.530 0.13537E+05 -5.928 5 H2S,gas -5.94 -22.72 -16.78 -8.388 0.28646E+05 -14.777 6 S2,gas -7.03 -46.16 -39.12 -6.019 0.66802E+05 -37.123 7 CO,gas 3.51 -14.47 -17.98 -5.534 0.30708E+05 -15.985 8 SO3,gas 17.43 -24.15 -41.58 -10.395 0.70998E+05 -39.581 9 SO2,gas 1.14 -23.80 -24.93 -6.648 0.42570E+05 -22.931 10 HCl,gas 5.48 -13.60 -19.08 -9.541 0.32583E+05 -17.083 11 acmite 7.74 7.00 -0.74 -0.077 0.12637E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.40 -4.15 -0.208 0.70876E+04 20 analcite 3.37 3.03 -0.34 -0.038 0.58000E+03 21 andalusite 5.06 1.31 -3.76 -0.376 0.64145E+04 22 andradite 39.09 36.85 -2.23 -0.116 0.38161E+04 23 grossular 32.83 28.92 -3.91 -0.195 0.66729E+04 26 annite 20.21 17.00 -3.21 -0.178 0.54757E+04 27 phlogopite 27.15 23.69 -3.46 -0.192 0.59079E+04 29 anorthite 12.80 9.39 -3.41 -0.262 0.58173E+04 35 aragonite 0.99 -3.39 -4.37 -1.458 0.74695E+04 36 brucite 12.58 8.71 -3.87 -0.774 0.66087E+04 37 calcite 0.83 -3.39 -4.22 -1.407 0.72082E+04 38 carnegieite-low 9.06 6.39 -2.67 -0.382 0.45663E+04 39 carnegieite-high 10.13 6.39 -3.74 -0.535 0.63931E+04 40 carpholite-Mg 8.65 6.65 -2.00 -0.133 0.34113E+04 41 carpholite-Fe 6.78 4.42 -2.36 -0.157 0.40270E+04 42 celadonite 5.40 2.92 -2.49 -0.146 0.42439E+04 43 celadonite-Fe 3.94 0.69 -3.25 -0.191 0.55492E+04 44 chrysotile 23.94 19.40 -4.54 -0.378 0.77478E+04 50 chloritoid-Mg 13.26 10.01 -3.25 -0.217 0.55483E+04 51 chloritoid-Fe 9.24 7.78 -1.45 -0.097 0.24842E+04 52 chloritoid-Mn 11.46 9.91 -1.55 -0.104 0.26527E+04 54 coesite -2.37 -3.36 -0.99 -0.330 0.16903E+04 59 corundum 8.43 4.66 -3.77 -0.343 0.64345E+04 61 cristobalite -2.55 -3.36 -0.81 -0.270 0.13832E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.33 -0.56 -0.094 0.96232E+03 67 diopside 16.22 13.43 -2.78 -0.278 0.47529E+04 68 hedenbergite 14.24 11.20 -3.04 -0.304 0.51917E+04 75 epidote 24.78 23.77 -1.00 -0.049 0.17085E+04 76 clinozoisite 22.92 19.81 -3.11 -0.141 0.53151E+04 77 epidote-Fe 29.94 27.74 -2.20 -0.114 0.37494E+04 78 fayalite 14.08 9.60 -4.48 -0.640 0.76531E+04 79 ferrosilite 11.19 6.24 -4.95 -0.495 0.84523E+04 83 gibbsite 4.10 2.33 -1.76 -0.252 0.30135E+04 84 glaucophane 23.11 18.74 -4.37 -0.118 0.74574E+04 87 greenalite 16.19 12.72 -3.48 -0.290 0.59396E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.03 -1.22 -0.122 0.20830E+04 97 kalsilite 7.62 4.29 -3.33 -0.476 0.56917E+04 98 kaolinite -1.27 -2.05 -0.78 -0.071 0.13327E+04 99 kyanite 4.93 1.31 -3.63 -0.363 0.61912E+04 101 laumontite 2.97 2.67 -0.30 -0.020 0.51642E+03 102 lawsonite 9.68 9.39 -0.29 -0.019 0.49115E+03 103 leucite 4.17 0.93 -3.24 -0.324 0.55324E+04 105 lizardite 23.29 19.40 -3.89 -0.324 0.66381E+04 107 magnetite 20.13 19.08 -1.06 -0.086 0.18050E+04 108 minnesotaite 10.46 6.00 -4.46 -0.263 0.76217E+04 110 magnesioferrite 26.26 21.30 -4.95 -0.404 0.84580E+04 113 margarite 17.45 14.06 -3.40 -0.136 0.57987E+04 120 muscovite 2.68 2.23 -0.45 -0.026 0.76153E+03 122 nepheline 8.38 6.39 -1.99 -0.284 0.33942E+04 134 phlogopite-Na 29.73 25.79 -3.94 -0.219 0.67298E+04 136 prehnite 19.47 17.48 -1.99 -0.117 0.33988E+04 137 prehnite-Fe 22.59 21.44 -1.14 -0.069 0.19545E+04 138 pumpellyite-Fe 46.47 43.76 -2.71 -0.060 0.46245E+04 139 pumpellyite-Mg 49.19 45.99 -3.20 -0.071 0.54705E+04 145 pyroxmangite 7.42 5.24 -2.17 -0.434 0.37076E+04 146 pyrophyllite -6.10 -8.77 -2.67 -0.167 0.45662E+04 147 quartz -2.98 -3.36 -0.38 -0.126 0.64426E+03 152 rhodonite 7.46 5.24 -2.22 -0.444 0.37868E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.31 -4.02 -0.402 0.68567E+04 164 stilpnomelane-Fe 13.18 12.84 -0.34 -0.010 0.58340E+03 165 stilpnomelane-Mg 27.60 23.98 -3.62 -0.108 0.61782E+04 168 sudoite 21.22 16.66 -4.55 -0.147 0.77722E+04 171 talc 16.55 12.68 -3.87 -0.228 0.66118E+04 174 tephroite 18.11 13.85 -4.26 -0.609 0.72811E+04 177 topaz-H 4.67 1.31 -3.36 -0.306 0.57403E+04 178 tridymite -2.61 -3.36 -0.74 -0.248 0.12716E+04 187 wairakite 4.06 2.67 -1.39 -0.082 0.23672E+04 188 walstromite 11.53 8.09 -3.44 -0.689 0.58785E+04 189 wollastonite 10.48 8.09 -2.40 -0.479 0.40924E+04 190 pseudo-wollastonite 11.02 8.09 -2.93 -0.587 0.50110E+04 191 zoisite 22.96 19.81 -3.16 -0.143 0.53877E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.01 -3.45 -0.213 0.58839E+04 194 beidellite-H -2.24 -6.89 -4.65 -0.297 0.79447E+04 195 beidellite-K -1.44 -5.14 -3.71 -0.227 0.63269E+04 196 beidellite-Mg -1.71 -5.46 -3.75 -0.232 0.64040E+04 197 beidellite-Na -1.26 -4.45 -3.19 -0.195 0.54457E+04 199 chalcedony -2.79 -3.36 -0.56 -0.188 0.96458E+03 201 montmorillonite-Ca -2.21 -4.78 -2.57 -0.159 0.43825E+04 202 montmorillonite-K -2.16 -4.92 -2.75 -0.169 0.47032E+04 203 montmorillonite-Mg -2.40 -5.23 -2.83 -0.175 0.48336E+04 204 montmorillonite-Na -1.96 -4.22 -2.26 -0.138 0.38601E+04 205 nontronite-Ca 3.28 2.93 -0.35 -0.023 0.60220E+03 206 nontronite-H 2.60 1.04 -1.56 -0.104 0.26587E+04 207 nontronite-K 3.40 2.79 -0.61 -0.039 0.10444E+04 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11339E+04 209 nontronite-Na 3.58 3.49 -0.10 -0.006 0.16482E+03 224 tobermorite 9.84 6.17 -3.67 -1.000 0.62582E+04 233 boehmite 4.43 2.33 -2.10 -0.350 0.35808E+04 235 ferrous-oxide 9.82 6.48 -3.35 -0.837 0.57134E+04 240 silica-amorphous -2.08 -3.36 -1.28 -0.427 0.21848E+04 242 an20ab80 2.08 1.62 -0.46 -0.036 0.79184E+03 243 an25ab75 2.71 2.10 -0.61 -0.047 0.10377E+04 244 an30ab70 3.34 2.59 -0.76 -0.058 0.12919E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 5.3990000 g New total amount of reactant added: 5.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.9365E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 5.5990000 Water: Moles liquid = 0.5545E+02 kg liquid = 0.9990E+00 Moles total = 0.5544E+02 kg total = 0.9987E+00 Activity = 1.0000 Stoichiometric ionic strength = .3631296E-02 Osmotic coef. = 0.9673 True ionic strength = .6189090E-02 Chg. balance for total moles = -.9365E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.21754E-09 -9.6625 0.19433E-09 -9.7115 0.89330E+00 -0.0490 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13789E-03 -3.8605 0.12290E-03 -3.9104 0.89129E+00 -0.0500 4 SO4-- 0.25517E-04 -4.5932 0.17070E-04 -4.7678 0.66896E+00 -0.1746 5 HCO3- 0.80009E-05 -5.0969 0.71349E-05 -5.1466 0.89177E+00 -0.0497 6 HS- 0.11306E-12 -12.9467 0.10078E-12 -12.9966 0.89134E+00 -0.0500 7 Al+++ 0.38316E-26 -26.4166 0.15780E-26 -26.8019 0.41182E+00 -0.3853 8 H4SiO4 0.42717E-03 -3.3694 0.42717E-03 -3.3694 0.10000E+01 0.0000 9 Ca++ 0.18526E-07 -7.7322 0.12360E-07 -7.9080 0.66714E+00 -0.1758 10 Mg++ 0.29226E-10 -10.5342 0.19465E-10 -10.7108 0.66601E+00 -0.1765 11 Fe++ 0.17280E-12 -12.7625 0.11513E-12 -12.9388 0.66628E+00 -0.1763 12 K+ 0.48100E-04 -4.3179 0.42898E-04 -4.3676 0.89186E+00 -0.0497 13 Na+ 0.61077E-02 -2.2141 0.54434E-02 -2.2641 0.89124E+00 -0.0500 14 Mn++ 0.23084E-10 -10.6367 0.15385E-10 -10.8129 0.66648E+00 -0.1762 15 HPO4-- 0.25685E-05 -5.5903 0.17183E-05 -5.7649 0.66900E+00 -0.1746 16 HSiO3- 0.24063E-02 -2.6186 0.21447E-02 -2.6686 0.89129E+00 -0.0500 17 Ca(HSiO3)+ 0.66588E-09 -9.1766 0.59392E-09 -9.2263 0.89193E+00 -0.0497 18 Mg(HSiO3)+ 0.13051E-11 -11.8844 0.11640E-11 -11.9340 0.89193E+00 -0.0497 19 NaHSiO3,aq 0.18542E-03 -3.7318 0.18542E-03 -3.7318 0.10000E+01 0.0000 20 AlO+ 0.60480E-14 -14.2184 0.53944E-14 -14.2681 0.89193E+00 -0.0497 22 HAlO2,aq 0.55549E-08 -8.2553 0.55549E-08 -8.2553 0.10000E+01 0.0000 23 AlO2- 0.71661E-04 -4.1447 0.63827E-04 -4.1950 0.89068E+00 -0.0503 24 CH4,aq 0.41380E-19 -19.3832 0.41334E-19 -19.3837 0.99888E+00 -0.0005 29 CO,aq 0.63656E-19 -19.1962 0.63656E-19 -19.1962 0.10000E+01 0.0000 30 CO2,aq 0.27986E-08 -8.5531 0.27955E-08 -8.5535 0.99888E+00 -0.0005 31 CO3-2 0.50787E-05 -5.2942 0.33948E-05 -5.4692 0.66843E+00 -0.1749 32 CaCO3,aq 0.51389E-09 -9.2891 0.51389E-09 -9.2891 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.24913E-11 -11.6036 0.22220E-11 -11.6533 0.89193E+00 -0.0497 34 CaCl+ 0.27138E-11 -11.5664 0.24205E-11 -11.6161 0.89193E+00 -0.0497 35 CaCl2,aq 0.69266E-16 -16.1595 0.69266E-16 -16.1595 0.10000E+01 0.0000 36 CaOH+ 0.50282E-08 -8.2986 0.44848E-08 -8.3483 0.89193E+00 -0.0497 37 CaSO4,aq 0.65736E-10 -10.1822 0.65736E-10 -10.1822 0.10000E+01 0.0000 38 HCl,aq 0.44923E-14 -14.3475 0.44923E-14 -14.3475 0.10000E+01 0.0000 43 FeCl+ 0.24709E-16 -16.6071 0.22038E-16 -16.6568 0.89193E+00 -0.0497 46 FeO,aq 0.12056E-09 -9.9188 0.12056E-09 -9.9188 0.10000E+01 0.0000 47 FeOH+ 0.22021E-10 -10.6572 0.19642E-10 -10.7068 0.89193E+00 -0.0497 48 HFeO2- 0.74870E-08 -8.1257 0.66731E-08 -8.1757 0.89129E+00 -0.0500 49 FeO+ 0.18023E-14 -14.7442 0.16075E-14 -14.7938 0.89193E+00 -0.0497 51 FeO2- 0.93868E-08 -8.0275 0.83664E-08 -8.0775 0.89129E+00 -0.0500 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.88512E-09 -9.0530 0.88412E-09 -9.0535 0.99888E+00 -0.0005 54 KCl,aq 0.93353E-10 -10.0299 0.93353E-10 -10.0299 0.10000E+01 0.0000 55 KHSO4,aq 0.38079E-18 -18.4193 0.38079E-18 -18.4193 0.10000E+01 0.0000 56 KOH,aq 0.96236E-07 -7.0167 0.96236E-07 -7.0167 0.10000E+01 0.0000 57 KSO4- 0.12658E-07 -7.8976 0.11282E-07 -7.9476 0.89129E+00 -0.0500 58 MgCO3,aq 0.20222E-12 -12.6942 0.20222E-12 -12.6942 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.40007E-14 -14.3979 0.35684E-14 -14.4475 0.89193E+00 -0.0497 60 MgCl+ 0.38799E-14 -14.4112 0.34606E-14 -14.4609 0.89193E+00 -0.0497 61 MgOH+ 0.43870E-10 -10.3578 0.39128E-10 -10.4075 0.89193E+00 -0.0497 63 MnO,aq 0.43007E-09 -9.3665 0.43007E-09 -9.3665 0.10000E+01 0.0000 64 MnOH+ 0.27337E-09 -9.5633 0.24382E-09 -9.6129 0.89193E+00 -0.0497 65 MnO2-2 0.58924E-12 -12.2297 0.39386E-12 -12.4047 0.66843E+00 -0.1749 66 HMnO2- 0.18606E-10 -10.7304 0.16583E-10 -10.7803 0.89129E+00 -0.0500 69 MnCl+ 0.12830E-13 -13.8918 0.11444E-13 -13.9414 0.89193E+00 -0.0497 70 MnSO4,aq 0.74426E-13 -13.1283 0.74426E-13 -13.1283 0.10000E+01 0.0000 71 NaCl,aq 0.21845E-06 -6.6607 0.21845E-06 -6.6607 0.10000E+01 0.0000 72 NaOH,aq 0.12309E-04 -4.9098 0.12309E-04 -4.9098 0.10000E+01 0.0000 74 OH- 0.34656E-02 -2.4602 0.30867E-02 -2.5105 0.89068E+00 -0.0503 79 HPO3-2 0.71789E-17 -17.1439 0.47985E-17 -17.3189 0.66843E+00 -0.1749 82 H3PO4,aq 0.41776E-15 -15.3791 0.41776E-15 -15.3791 0.10000E+01 0.0000 83 H2PO4- 0.65661E-08 -8.1827 0.58543E-08 -8.2325 0.89160E+00 -0.0498 84 PO4-3 0.18410E-07 -7.7349 0.77223E-08 -8.1123 0.41945E+00 -0.3773 87 H2P2O7-2 0.40129E-17 -17.3965 0.26824E-17 -17.5715 0.66843E+00 -0.1749 88 HP2O7-3 0.68711E-14 -14.1630 0.28304E-14 -14.5481 0.41193E+00 -0.3852 89 P2O7-4 0.16980E-13 -13.7700 0.35932E-14 -14.4445 0.21161E+00 -0.6745 90 H2S,aq 0.58906E-16 -16.2298 0.58840E-16 -16.2303 0.99888E+00 -0.0005 97 SO3-2 0.30619E-14 -14.5140 0.20578E-14 -14.6866 0.67205E+00 -0.1726 98 HSO3- 0.26256E-16 -16.5808 0.23402E-16 -16.6308 0.89129E+00 -0.0500 99 HSO4- 0.34495E-11 -11.4622 0.30778E-11 -11.5118 0.89224E+00 -0.0495 Charge balance for all species = -.9299E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2175383E-09 -.6361510E-02 -.6409090E+01 0.0000 2 H2O 0.1000000E+01 0.5550928E+02 0.9995593E+06 0.0000 3 Cl- 0.1378919E-03 0.1381104E-03 0.4894191E+01 5.8010 4 SO4-- 0.2551693E-04 0.2553063E-04 0.2451392E+01 14.6552 5 HCO3- 0.8000871E-05 0.1308291E-04 0.7979174E+00 4.5649 6 HS- 0.1130619E-12 -.9773950E-09 -.3230963E-04 -3.2852 7 Al+++ 0.3831643E-26 0.7166670E-04 0.1932791E+01 2.3325 8 H4SiO4 0.4271712E-03 0.3018904E-02 0.2900306E+03 -3.3694 9 Ca++ 0.1852624E-07 0.2480515E-07 0.9936866E-03 11.5149 10 Mg++ 0.2922568E-10 0.7461038E-10 0.1813099E-05 8.7122 11 Fe++ 0.1727975E-12 0.1722007E-07 0.9612496E-03 6.4841 12 K+ 0.4809989E-04 0.4820887E-04 0.1884202E+01 5.3439 13 Na+ 0.6107709E-02 0.6305656E-02 0.1448995E+03 7.4473 14 Mn++ 0.2308366E-10 0.7458071E-09 0.4095442E-04 8.6100 15 HPO4-- 0.2568538E-05 0.2593515E-05 0.2488092E+00 13.6580 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9269809E-01 -.6355235E-02 -.8634285E-01 0.0000000E+00 2 H2O 0.5543806E+02 0.5545452E+02 -.1645961E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1806718E-03 0.2550545E-04 0.1551664E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1551674E-03 -.9764308E-09 -.1551664E-03 0.0000000E+00 7 Al+++ 0.1825689E-01 0.7159601E-04 0.1818530E-01 0.0000000E+00 8 H4SiO4 0.5830117E-01 0.3015926E-02 0.5528525E-01 0.0000000E+00 9 Ca++ 0.6454120E-02 0.2478069E-07 0.6454095E-02 0.0000000E+00 10 Mg++ 0.4443651E-02 0.7453679E-10 0.4443651E-02 0.0000000E+00 11 Fe++ 0.3992135E-02 0.1720308E-07 0.3992118E-02 0.0000000E+00 12 K+ 0.1188747E-02 0.4816132E-04 0.1140586E-02 0.0000000E+00 13 Na+ 0.7188180E-02 0.6299436E-02 0.8887437E-03 0.0000000E+00 14 Mn++ 0.9707880E-04 0.7450714E-09 0.9707805E-04 0.0000000E+00 15 HPO4-- 0.3313251E-04 0.2590957E-05 0.3054155E-04 0.0000000E+00 Chg. balance for solid moles: -.8253E-17 Mass of aqueous solution: 0.999470E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 5.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6723E-03 -3.172 0.1763 -0.754 2.893 0.6767E-01 apatite-OH 0.1018E-04 -4.992 0.5114E-02 -2.291 0.8392E-01 0.1625E-02 clinochlore 0.8887E-03 -3.051 0.4940 -0.306 8.107 0.1879 daphnite 0.5502E-03 -3.260 0.3925 -0.406 6.442 0.1190 chlorite-Mn 0.1942E-04 -4.712 0.1377E-01 -1.861 0.2259 0.4387E-02 hematite 0.6207E-03 -3.207 0.9912E-01 -1.004 1.627 0.1879E-01 microcline 0.1141E-02 -2.943 0.3175 -0.498 5.210 0.1240 paragonite 0.2165E-03 -3.665 0.8274E-01 -1.082 1.358 0.2860E-01 stilbite 0.6403E-02 -2.194 4.512 0.654 74.05 2.105 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6.093474 g Volume = 2.656622 cm3 Porosity: 17.9954% V(tot) - V(min): 0.58298E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 5.5990000 g log = 0.7481 Original solution: 1000.0103000 g Original solution / Rock added: 178.61 (Water/Rock Ratio), log = 2.2519 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.3020E-06 1.0073 0.3200E-06 0.3177E-06 CH4,gas 0.6134E-16 1.0129 0.6536E-16 0.6453E-16 H2,gas 0.1152E-05 1.0006 0.1213E-05 0.1212E-05 H2S,gas 0.1638E-14 0.9959 0.1716E-14 0.1723E-14 S2,gas 0.7131E-37 1.0000 0.7501E-37 0.7501E-37 CO,gas 0.9555E-16 1.0000 0.1005E-15 0.1005E-15 SO3,gas 0.2291E-39 1.0000 0.2410E-39 0.2410E-39 SO2,gas 0.1051E-22 1.0000 0.1106E-22 0.1106E-22 HCl,gas 0.7541E-17 1.0000 0.7932E-17 0.7932E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.15165E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.86 -8.49 -2.832 0.14505E+05 -6.495 3 CH4,gas 4.81 -13.38 -18.18 -4.546 0.31050E+05 -16.185 4 H2,gas 8.29 0.37 -7.92 -4.524 0.13517E+05 -5.916 5 H2S,gas -5.94 -22.71 -16.77 -8.383 0.28627E+05 -14.765 6 S2,gas -7.03 -46.16 -39.12 -6.019 0.66805E+05 -37.125 7 CO,gas 3.51 -14.49 -18.00 -5.538 0.30731E+05 -15.998 8 SO3,gas 17.43 -24.19 -41.62 -10.405 0.71062E+05 -39.618 9 SO2,gas 1.14 -23.82 -24.96 -6.655 0.42612E+05 -22.956 10 HCl,gas 5.48 -13.62 -19.10 -9.550 0.32614E+05 -17.101 11 acmite 7.74 7.01 -0.73 -0.076 0.12465E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.39 -4.16 -0.208 0.71082E+04 20 analcite 3.37 3.04 -0.33 -0.037 0.56278E+03 21 andalusite 5.06 1.30 -3.77 -0.377 0.64317E+04 22 andradite 39.09 37.03 -2.05 -0.107 0.35063E+04 23 grossular 32.83 29.10 -3.73 -0.186 0.63630E+04 26 annite 20.21 17.02 -3.19 -0.177 0.54447E+04 27 phlogopite 27.15 23.70 -3.44 -0.191 0.58769E+04 29 anorthite 12.80 9.44 -3.36 -0.258 0.57312E+04 35 aragonite 0.99 -3.34 -4.33 -1.443 0.73923E+04 36 brucite 12.58 8.71 -3.86 -0.773 0.65984E+04 37 calcite 0.83 -3.34 -4.18 -1.392 0.71309E+04 38 carnegieite-low 9.06 6.41 -2.65 -0.379 0.45318E+04 39 carnegieite-high 10.13 6.41 -3.72 -0.532 0.63587E+04 40 carpholite-Mg 8.65 6.64 -2.01 -0.134 0.34354E+04 41 carpholite-Fe 6.78 4.41 -2.37 -0.158 0.40511E+04 42 celadonite 5.40 2.91 -2.49 -0.146 0.42508E+04 43 celadonite-Fe 3.94 0.68 -3.25 -0.191 0.55561E+04 44 chrysotile 23.94 19.40 -4.54 -0.378 0.77513E+04 50 chloritoid-Mg 13.26 10.01 -3.25 -0.217 0.55552E+04 51 chloritoid-Fe 9.24 7.78 -1.46 -0.097 0.24911E+04 52 chloritoid-Mn 11.46 9.91 -1.56 -0.104 0.26595E+04 54 coesite -2.37 -3.37 -1.00 -0.333 0.17076E+04 59 corundum 8.43 4.66 -3.77 -0.343 0.64345E+04 61 cristobalite -2.55 -3.37 -0.82 -0.273 0.14004E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.33 -0.56 -0.094 0.96232E+03 67 diopside 16.22 13.49 -2.73 -0.273 0.46565E+04 68 hedenbergite 14.24 11.26 -2.98 -0.298 0.50953E+04 75 epidote 24.78 23.89 -0.89 -0.043 0.15192E+04 76 clinozoisite 22.92 19.92 -3.00 -0.136 0.51258E+04 77 epidote-Fe 29.94 27.85 -2.08 -0.108 0.35600E+04 78 fayalite 14.08 9.60 -4.48 -0.640 0.76497E+04 79 ferrosilite 11.19 6.23 -4.96 -0.496 0.84660E+04 83 gibbsite 4.10 2.33 -1.76 -0.252 0.30135E+04 84 glaucophane 23.11 18.74 -4.37 -0.118 0.74608E+04 87 greenalite 16.19 12.71 -3.48 -0.290 0.59431E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.04 -1.21 -0.121 0.20658E+04 97 kalsilite 7.62 4.31 -3.31 -0.473 0.56573E+04 98 kaolinite -1.27 -2.07 -0.80 -0.073 0.13671E+04 99 kyanite 4.93 1.30 -3.64 -0.364 0.62085E+04 101 laumontite 2.97 2.70 -0.27 -0.018 0.46478E+03 102 lawsonite 9.68 9.44 -0.24 -0.016 0.40508E+03 103 leucite 4.17 0.94 -3.23 -0.323 0.55152E+04 105 lizardite 23.29 19.40 -3.89 -0.324 0.66415E+04 107 magnetite 20.13 19.08 -1.05 -0.086 0.17946E+04 108 minnesotaite 10.46 5.97 -4.49 -0.264 0.76596E+04 110 magnesioferrite 26.26 21.31 -4.95 -0.404 0.84477E+04 113 margarite 17.45 14.11 -3.35 -0.134 0.57127E+04 120 muscovite 2.68 2.23 -0.45 -0.026 0.76153E+03 122 nepheline 8.38 6.41 -1.97 -0.281 0.33598E+04 134 phlogopite-Na 29.73 25.81 -3.92 -0.218 0.66988E+04 136 prehnite 19.47 17.59 -1.88 -0.111 0.32095E+04 137 prehnite-Fe 22.59 21.55 -1.03 -0.062 0.17651E+04 138 pumpellyite-Fe 46.47 43.99 -2.48 -0.055 0.42355E+04 139 pumpellyite-Mg 49.19 46.22 -2.98 -0.066 0.50815E+04 145 pyroxmangite 7.42 5.24 -2.18 -0.435 0.37144E+04 146 pyrophyllite -6.10 -8.81 -2.71 -0.170 0.46351E+04 147 quartz -2.98 -3.37 -0.39 -0.129 0.66147E+03 152 rhodonite 7.46 5.24 -2.22 -0.444 0.37937E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.30 -4.03 -0.403 0.68739E+04 164 stilpnomelane-Fe 13.18 12.80 -0.38 -0.011 0.64365E+03 165 stilpnomelane-Mg 27.60 23.94 -3.65 -0.109 0.62385E+04 168 sudoite 21.22 16.65 -4.57 -0.147 0.78032E+04 171 talc 16.55 12.66 -3.89 -0.229 0.66496E+04 174 tephroite 18.11 13.85 -4.26 -0.609 0.72777E+04 177 topaz-H 4.67 1.30 -3.37 -0.307 0.57575E+04 178 tridymite -2.61 -3.37 -0.75 -0.252 0.12888E+04 187 wairakite 4.06 2.70 -1.36 -0.080 0.23156E+04 188 walstromite 11.53 8.15 -3.38 -0.676 0.57752E+04 189 wollastonite 10.48 8.15 -2.34 -0.467 0.39891E+04 190 pseudo-wollastonite 11.02 8.15 -2.87 -0.575 0.49077E+04 191 zoisite 22.96 19.92 -3.04 -0.138 0.51983E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.03 -3.47 -0.215 0.59272E+04 194 beidellite-H -2.24 -6.93 -4.69 -0.299 0.80078E+04 195 beidellite-K -1.44 -5.17 -3.73 -0.229 0.63731E+04 196 beidellite-Mg -1.71 -5.49 -3.79 -0.234 0.64655E+04 197 beidellite-Na -1.26 -4.47 -3.22 -0.197 0.54918E+04 199 chalcedony -2.79 -3.37 -0.57 -0.192 0.98179E+03 201 montmorillonite-Ca -2.21 -4.81 -2.59 -0.160 0.44280E+04 202 montmorillonite-K -2.16 -4.94 -2.78 -0.170 0.47516E+04 203 montmorillonite-Mg -2.40 -5.27 -2.87 -0.177 0.48973E+04 204 montmorillonite-Na -1.96 -4.25 -2.29 -0.140 0.39085E+04 205 nontronite-Ca 3.28 2.90 -0.38 -0.025 0.64549E+03 206 nontronite-H 2.60 1.00 -1.59 -0.107 0.27219E+04 207 nontronite-K 3.40 2.77 -0.64 -0.041 0.10905E+04 208 nontronite-Mg 3.14 2.44 -0.70 -0.045 0.11954E+04 209 nontronite-Na 3.58 3.46 -0.12 -0.008 0.21095E+03 224 tobermorite 9.84 6.22 -3.62 -0.987 0.61750E+04 233 boehmite 4.43 2.33 -2.10 -0.350 0.35808E+04 235 ferrous-oxide 9.82 6.48 -3.34 -0.835 0.57031E+04 240 silica-amorphous -2.08 -3.37 -1.29 -0.430 0.22020E+04 242 an20ab80 2.08 1.63 -0.45 -0.035 0.77463E+03 243 an25ab75 2.71 2.11 -0.60 -0.046 0.10162E+04 244 an30ab70 3.34 2.60 -0.74 -0.057 0.12661E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 5.5990000 g New total amount of reactant added: 5.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.9366E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 5.7990000 Water: Moles liquid = 0.5545E+02 kg liquid = 0.9990E+00 Moles total = 0.5544E+02 kg total = 0.9987E+00 Activity = 1.0000 Stoichiometric ionic strength = .3741742E-02 Osmotic coef. = 0.9668 True ionic strength = .6375612E-02 Chg. balance for total moles = -.9366E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.20952E-09 -9.6788 0.18694E-09 -9.7283 0.89219E+00 -0.0495 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13789E-03 -3.8605 0.12274E-03 -3.9110 0.89013E+00 -0.0505 4 SO4-- 0.25517E-04 -4.5932 0.16983E-04 -4.7700 0.66555E+00 -0.1768 5 HCO3- 0.78682E-05 -5.1041 0.70076E-05 -5.1544 0.89062E+00 -0.0503 6 HS- 0.12068E-12 -12.9184 0.10743E-12 -12.9689 0.89017E+00 -0.0505 7 Al+++ 0.34507E-26 -26.4621 0.14047E-26 -26.8524 0.40706E+00 -0.3903 8 H4SiO4 0.41769E-03 -3.3792 0.41769E-03 -3.3792 0.10000E+01 0.0000 9 Ca++ 0.20166E-07 -7.6954 0.13384E-07 -7.8734 0.66370E+00 -0.1780 10 Mg++ 0.27555E-10 -10.5598 0.18256E-10 -10.7386 0.66254E+00 -0.1788 11 Fe++ 0.16292E-12 -12.7880 0.10798E-12 -12.9666 0.66281E+00 -0.1786 12 K+ 0.49559E-04 -4.3049 0.44142E-04 -4.3551 0.89071E+00 -0.0503 13 Na+ 0.62931E-02 -2.2011 0.56013E-02 -2.2517 0.89007E+00 -0.0506 14 Mn++ 0.21764E-10 -10.6623 0.14430E-10 -10.8407 0.66302E+00 -0.1785 15 HPO4-- 0.21469E-05 -5.6682 0.14289E-05 -5.8450 0.66559E+00 -0.1768 16 HSiO3- 0.24491E-02 -2.6110 0.21800E-02 -2.6615 0.89013E+00 -0.0505 17 Ca(HSiO3)+ 0.73389E-09 -9.1344 0.65373E-09 -9.1846 0.89078E+00 -0.0502 18 Mg(HSiO3)+ 0.12458E-11 -11.9046 0.11097E-11 -11.9548 0.89078E+00 -0.0502 19 NaHSiO3,aq 0.19394E-03 -3.7123 0.19394E-03 -3.7123 0.10000E+01 0.0000 20 AlO+ 0.58254E-14 -14.2347 0.51892E-14 -14.2849 0.89078E+00 -0.0502 22 HAlO2,aq 0.55549E-08 -8.2553 0.55549E-08 -8.2553 0.10000E+01 0.0000 23 AlO2- 0.74593E-04 -4.1273 0.66351E-04 -4.1782 0.88951E+00 -0.0509 24 CH4,aq 0.43547E-19 -19.3610 0.43496E-19 -19.3615 0.99885E+00 -0.0005 29 CO,aq 0.61784E-19 -19.2091 0.61784E-19 -19.2091 0.10000E+01 0.0000 30 CO2,aq 0.26442E-08 -8.5777 0.26412E-08 -8.5782 0.99885E+00 -0.0005 31 CO3-2 0.52119E-05 -5.2830 0.34660E-05 -5.4602 0.66501E+00 -0.1772 32 CaCO3,aq 0.56816E-09 -9.2455 0.56816E-09 -9.2455 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.26530E-11 -11.5763 0.23632E-11 -11.6265 0.89078E+00 -0.0502 34 CaCl+ 0.29387E-11 -11.5318 0.26177E-11 -11.5821 0.89078E+00 -0.0502 35 CaCl2,aq 0.74811E-16 -16.1260 0.74811E-16 -16.1260 0.10000E+01 0.0000 36 CaOH+ 0.56676E-08 -8.2466 0.50486E-08 -8.2968 0.89078E+00 -0.0502 37 CaSO4,aq 0.70824E-10 -10.1498 0.70824E-10 -10.1498 0.10000E+01 0.0000 38 HCl,aq 0.43158E-14 -14.3649 0.43158E-14 -14.3649 0.10000E+01 0.0000 43 FeCl+ 0.23174E-16 -16.6350 0.20643E-16 -16.6852 0.89078E+00 -0.0502 46 FeO,aq 0.12220E-09 -9.9129 0.12220E-09 -9.9129 0.10000E+01 0.0000 47 FeOH+ 0.21499E-10 -10.6676 0.19151E-10 -10.7178 0.89078E+00 -0.0502 48 HFeO2- 0.78989E-08 -8.1024 0.70310E-08 -8.1530 0.89013E+00 -0.0505 49 FeO+ 0.17360E-14 -14.7605 0.15464E-14 -14.8107 0.89078E+00 -0.0502 51 FeO2- 0.97707E-08 -8.0101 0.86972E-08 -8.0606 0.89013E+00 -0.0505 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.90932E-09 -9.0413 0.90827E-09 -9.0418 0.99885E+00 -0.0005 54 KCl,aq 0.95934E-10 -10.0180 0.95934E-10 -10.0180 0.10000E+01 0.0000 55 KHSO4,aq 0.37501E-18 -18.4260 0.37501E-18 -18.4260 0.10000E+01 0.0000 56 KOH,aq 0.10294E-06 -6.9874 0.10294E-06 -6.9874 0.10000E+01 0.0000 57 KSO4- 0.12976E-07 -7.8869 0.11550E-07 -7.9374 0.89013E+00 -0.0505 58 MgCO3,aq 0.19365E-12 -12.7130 0.19365E-12 -12.7130 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.36901E-14 -14.4330 0.32871E-14 -14.4832 0.89078E+00 -0.0502 60 MgCl+ 0.36390E-14 -14.4390 0.32415E-14 -14.4893 0.89078E+00 -0.0502 61 MgOH+ 0.42828E-10 -10.3683 0.38151E-10 -10.4185 0.89078E+00 -0.0502 63 MnO,aq 0.43591E-09 -9.3606 0.43591E-09 -9.3606 0.10000E+01 0.0000 64 MnOH+ 0.26688E-09 -9.5737 0.23773E-09 -9.6239 0.89078E+00 -0.0502 65 MnO2-2 0.64871E-12 -12.1879 0.43140E-12 -12.3651 0.66501E+00 -0.1772 66 HMnO2- 0.19629E-10 -10.7071 0.17472E-10 -10.7576 0.89013E+00 -0.0505 69 MnCl+ 0.12034E-13 -13.9196 0.10719E-13 -13.9698 0.89078E+00 -0.0502 70 MnSO4,aq 0.69452E-13 -13.1583 0.69452E-13 -13.1583 0.10000E+01 0.0000 71 NaCl,aq 0.22449E-06 -6.6488 0.22449E-06 -6.6488 0.10000E+01 0.0000 72 NaOH,aq 0.13166E-04 -4.8805 0.13166E-04 -4.8805 0.10000E+01 0.0000 74 OH- 0.36074E-02 -2.4428 0.32088E-02 -2.4937 0.88951E+00 -0.0509 79 HPO3-2 0.61644E-17 -17.2101 0.40994E-17 -17.3873 0.66501E+00 -0.1772 82 H3PO4,aq 0.32147E-15 -15.4929 0.32147E-15 -15.4929 0.10000E+01 0.0000 83 H2PO4- 0.52593E-08 -8.2791 0.46831E-08 -8.3295 0.89045E+00 -0.0504 84 PO4-3 0.16093E-07 -7.7934 0.66756E-08 -8.1755 0.41481E+00 -0.3822 87 H2P2O7-2 0.25812E-17 -17.5882 0.17165E-17 -17.7654 0.66501E+00 -0.1772 88 HP2O7-3 0.46242E-14 -14.3350 0.18829E-14 -14.7252 0.40718E+00 -0.3902 89 P2O7-4 0.11984E-13 -13.9214 0.24848E-14 -14.6047 0.20734E+00 -0.6833 90 H2S,aq 0.60408E-16 -16.2189 0.60338E-16 -16.2194 0.99885E+00 -0.0005 97 SO3-2 0.31453E-14 -14.5023 0.21032E-14 -14.6771 0.66870E+00 -0.1748 98 HSO3- 0.25849E-16 -16.5876 0.23009E-16 -16.6381 0.89013E+00 -0.0505 99 HSO4- 0.33057E-11 -11.4807 0.29457E-11 -11.5308 0.89110E+00 -0.0501 Charge balance for all species = -.9306E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2095246E-09 -.6567357E-02 -.6616409E+01 0.0000 2 H2O 0.1000000E+01 0.5550938E+02 0.9995509E+06 0.0000 3 Cl- 0.1378905E-03 0.1381151E-03 0.4894306E+01 5.8173 4 SO4-- 0.2551747E-04 0.2553154E-04 0.2451454E+01 14.6866 5 HCO3- 0.7868191E-05 0.1308335E-04 0.7979363E+00 4.5739 6 HS- 0.1206826E-12 -.1019325E-08 -.3369537E-04 -3.2406 7 Al+++ 0.3450687E-26 0.7459892E-04 0.2011850E+01 2.3325 8 H4SiO4 0.4176855E-03 0.3060733E-02 0.2940461E+03 -3.3792 9 Ca++ 0.2016604E-07 0.2721209E-07 0.1090097E-02 11.5832 10 Mg++ 0.2755503E-10 0.7183019E-10 0.1745520E-05 8.7180 11 Fe++ 0.1629180E-12 0.1801701E-07 0.1005726E-02 6.4900 12 K+ 0.4955867E-04 0.4967469E-04 0.1941472E+01 5.3732 13 Na+ 0.6293061E-02 0.6500390E-02 0.1493728E+03 7.4766 14 Mn++ 0.2176371E-10 0.7449107E-09 0.4090478E-04 8.6159 15 HPO4-- 0.2146873E-05 0.2168226E-05 0.2080069E+00 13.6116 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9600979E-01 -.6560657E-02 -.8944913E-01 0.0000000E+00 2 H2O 0.5543556E+02 0.5545275E+02 -.1718989E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1862145E-03 0.2550549E-04 0.1607090E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1607101E-03 -.1018285E-08 -.1607090E-03 0.0000000E+00 7 Al+++ 0.1890904E-01 0.7452281E-04 0.1883452E-01 0.0000000E+00 8 H4SiO4 0.6038373E-01 0.3057610E-02 0.5732612E-01 0.0000000E+00 9 Ca++ 0.6684148E-02 0.2718433E-07 0.6684121E-02 0.0000000E+00 10 Mg++ 0.4602381E-02 0.7175691E-10 0.4602381E-02 0.0000000E+00 11 Fe++ 0.4134737E-02 0.1799863E-07 0.4134719E-02 0.0000000E+00 12 K+ 0.1231210E-02 0.4962401E-04 0.1181586E-02 0.0000000E+00 13 Na+ 0.7439229E-02 0.6493758E-02 0.9454704E-03 0.0000000E+00 14 Mn++ 0.1005465E-03 0.7441507E-09 0.1005458E-03 0.0000000E+00 15 HPO4-- 0.3431603E-04 0.2166014E-05 0.3215001E-04 0.0000000E+00 Chg. balance for solid moles: -.7942E-17 Mass of aqueous solution: 0.999447E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 5.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7327E-03 -3.135 0.1921 -0.716 3.042 0.7375E-01 apatite-OH 0.1072E-04 -4.970 0.5383E-02 -2.269 0.8524E-01 0.1711E-02 clinochlore 0.9205E-03 -3.036 0.5116 -0.291 8.101 0.1946 daphnite 0.5698E-03 -3.244 0.4066 -0.391 6.438 0.1232 chlorite-Mn 0.2011E-04 -4.697 0.1426E-01 -1.846 0.2257 0.4543E-02 hematite 0.6428E-03 -3.192 0.1027 -0.989 1.626 0.1946E-01 microcline 0.1182E-02 -2.928 0.3289 -0.483 5.208 0.1285 paragonite 0.2128E-03 -3.672 0.8133E-01 -1.090 1.288 0.2811E-01 stilbite 0.6631E-02 -2.178 4.673 0.670 73.99 2.179 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6.315502 g Volume = 2.753275 cm3 Porosity: 17.0600% V(tot) - V(min): 0.56633E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 5.7990000 g log = 0.7634 Original solution: 1000.0103000 g Original solution / Rock added: 172.45 (Water/Rock Ratio), log = 2.2367 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2853E-06 1.0073 0.3023E-06 0.3001E-06 CH4,gas 0.6455E-16 1.0129 0.6878E-16 0.6791E-16 H2,gas 0.1184E-05 1.0006 0.1246E-05 0.1245E-05 H2S,gas 0.1680E-14 0.9959 0.1760E-14 0.1767E-14 S2,gas 0.7105E-37 1.0000 0.7474E-37 0.7474E-37 CO,gas 0.9274E-16 1.0000 0.9756E-16 0.9756E-16 SO3,gas 0.2109E-39 1.0000 0.2219E-39 0.2219E-39 SO2,gas 0.9940E-23 1.0000 0.1046E-22 0.1046E-22 HCl,gas 0.7244E-17 1.0000 0.7620E-17 0.7620E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 0.19715E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.88 -8.52 -2.840 0.14547E+05 -6.520 3 CH4,gas 4.81 -13.35 -18.16 -4.541 0.31012E+05 -16.163 4 H2,gas 8.29 0.38 -7.90 -4.517 0.13497E+05 -5.905 5 H2S,gas -5.94 -22.70 -16.75 -8.377 0.28608E+05 -14.755 6 S2,gas -7.03 -46.16 -39.13 -6.019 0.66807E+05 -37.126 7 CO,gas 3.51 -14.50 -18.01 -5.542 0.30753E+05 -16.011 8 SO3,gas 17.43 -24.23 -41.65 -10.413 0.71123E+05 -39.654 9 SO2,gas 1.14 -23.84 -24.98 -6.661 0.42654E+05 -22.981 10 HCl,gas 5.48 -13.64 -19.12 -9.559 0.32644E+05 -17.118 11 acmite 7.74 7.02 -0.72 -0.075 0.12299E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.38 -4.17 -0.209 0.71282E+04 20 analcite 3.37 3.05 -0.32 -0.036 0.54613E+03 21 andalusite 5.06 1.29 -3.78 -0.378 0.64483E+04 22 andradite 39.09 37.21 -1.88 -0.098 0.32065E+04 23 grossular 32.83 29.28 -3.55 -0.178 0.60633E+04 26 annite 20.21 17.04 -3.17 -0.176 0.54147E+04 27 phlogopite 27.15 23.72 -3.42 -0.190 0.58469E+04 29 anorthite 12.80 9.49 -3.31 -0.254 0.56479E+04 35 aragonite 0.99 -3.30 -4.29 -1.429 0.73178E+04 36 brucite 12.58 8.72 -3.86 -0.772 0.65884E+04 37 calcite 0.83 -3.30 -4.13 -1.378 0.70565E+04 38 carnegieite-low 9.06 6.43 -2.63 -0.376 0.44985E+04 39 carnegieite-high 10.13 6.43 -3.70 -0.529 0.63254E+04 40 carpholite-Mg 8.65 6.62 -2.03 -0.135 0.34588E+04 41 carpholite-Fe 6.78 4.40 -2.39 -0.159 0.40744E+04 42 celadonite 5.40 2.91 -2.49 -0.147 0.42575E+04 43 celadonite-Fe 3.94 0.68 -3.26 -0.192 0.55628E+04 44 chrysotile 23.94 19.40 -4.54 -0.378 0.77546E+04 50 chloritoid-Mg 13.26 10.00 -3.26 -0.217 0.55619E+04 51 chloritoid-Fe 9.24 7.78 -1.46 -0.098 0.24978E+04 52 chloritoid-Mn 11.46 9.90 -1.56 -0.104 0.26662E+04 54 coesite -2.37 -3.38 -1.01 -0.337 0.17242E+04 59 corundum 8.43 4.66 -3.77 -0.343 0.64345E+04 61 cristobalite -2.55 -3.38 -0.83 -0.277 0.14171E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.33 -0.56 -0.094 0.96232E+03 67 diopside 16.22 13.54 -2.67 -0.267 0.45633E+04 68 hedenbergite 14.24 11.31 -2.93 -0.293 0.50021E+04 75 epidote 24.78 23.99 -0.78 -0.038 0.13360E+04 76 clinozoisite 22.92 20.03 -2.89 -0.132 0.49426E+04 77 epidote-Fe 29.94 27.96 -1.98 -0.103 0.33769E+04 78 fayalite 14.08 9.60 -4.48 -0.640 0.76463E+04 79 ferrosilite 11.19 6.22 -4.97 -0.497 0.84794E+04 83 gibbsite 4.10 2.33 -1.76 -0.252 0.30135E+04 84 glaucophane 23.11 18.74 -4.37 -0.118 0.74642E+04 87 greenalite 16.19 12.71 -3.48 -0.290 0.59464E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.05 -1.20 -0.120 0.20492E+04 97 kalsilite 7.62 4.33 -3.29 -0.471 0.56240E+04 98 kaolinite -1.27 -2.09 -0.82 -0.075 0.14004E+04 99 kyanite 4.93 1.29 -3.65 -0.365 0.62251E+04 101 laumontite 2.97 2.73 -0.24 -0.016 0.41483E+03 102 lawsonite 9.68 9.49 -0.19 -0.013 0.32182E+03 103 leucite 4.17 0.95 -3.22 -0.322 0.54985E+04 105 lizardite 23.29 19.40 -3.89 -0.324 0.66449E+04 107 magnetite 20.13 19.09 -1.05 -0.085 0.17846E+04 108 minnesotaite 10.46 5.95 -4.51 -0.265 0.76962E+04 110 magnesioferrite 26.26 21.32 -4.94 -0.403 0.84377E+04 113 margarite 17.45 14.15 -3.30 -0.132 0.56294E+04 120 muscovite 2.68 2.23 -0.45 -0.026 0.76153E+03 122 nepheline 8.38 6.43 -1.95 -0.278 0.33265E+04 134 phlogopite-Na 29.73 25.83 -3.91 -0.217 0.66688E+04 136 prehnite 19.47 17.69 -1.77 -0.104 0.30263E+04 137 prehnite-Fe 22.59 21.66 -0.93 -0.056 0.15820E+04 138 pumpellyite-Fe 46.47 44.21 -2.26 -0.050 0.38592E+04 139 pumpellyite-Mg 49.19 46.44 -2.76 -0.061 0.47051E+04 145 pyroxmangite 7.42 5.24 -2.18 -0.436 0.37211E+04 146 pyrophyllite -6.10 -8.85 -2.75 -0.172 0.47017E+04 147 quartz -2.98 -3.38 -0.40 -0.132 0.67813E+03 152 rhodonite 7.46 5.24 -2.23 -0.445 0.38003E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.29 -4.04 -0.404 0.68905E+04 164 stilpnomelane-Fe 13.18 12.77 -0.41 -0.012 0.70193E+03 165 stilpnomelane-Mg 27.60 23.91 -3.69 -0.110 0.62967E+04 168 sudoite 21.22 16.63 -4.59 -0.148 0.78332E+04 171 talc 16.55 12.64 -3.92 -0.230 0.66863E+04 174 tephroite 18.11 13.85 -4.26 -0.609 0.72743E+04 177 topaz-H 4.67 1.29 -3.38 -0.307 0.57742E+04 178 tridymite -2.61 -3.38 -0.76 -0.255 0.13054E+04 187 wairakite 4.06 2.73 -1.33 -0.078 0.22656E+04 188 walstromite 11.53 8.20 -3.32 -0.665 0.56753E+04 189 wollastonite 10.48 8.20 -2.28 -0.456 0.38892E+04 190 pseudo-wollastonite 11.02 8.20 -2.82 -0.563 0.48078E+04 191 zoisite 22.96 20.03 -2.94 -0.134 0.50152E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.06 -3.50 -0.216 0.59691E+04 194 beidellite-H -2.24 -6.97 -4.73 -0.302 0.80689E+04 195 beidellite-K -1.44 -5.19 -3.76 -0.230 0.64177E+04 196 beidellite-Mg -1.71 -5.53 -3.82 -0.236 0.65249E+04 197 beidellite-Na -1.26 -4.50 -3.24 -0.199 0.55364E+04 199 chalcedony -2.79 -3.38 -0.58 -0.195 0.99844E+03 201 montmorillonite-Ca -2.21 -4.83 -2.62 -0.162 0.44721E+04 202 montmorillonite-K -2.16 -4.97 -2.81 -0.172 0.47985E+04 203 montmorillonite-Mg -2.40 -5.31 -2.90 -0.180 0.49590E+04 204 montmorillonite-Na -1.96 -4.28 -2.32 -0.142 0.39553E+04 205 nontronite-Ca 3.28 2.88 -0.40 -0.026 0.68737E+03 206 nontronite-H 2.60 0.97 -1.63 -0.109 0.27830E+04 207 nontronite-K 3.40 2.74 -0.66 -0.043 0.11352E+04 208 nontronite-Mg 3.14 2.40 -0.73 -0.048 0.12549E+04 209 nontronite-Na 3.58 3.43 -0.15 -0.010 0.25558E+03 224 tobermorite 9.84 6.27 -3.57 -0.974 0.60946E+04 233 boehmite 4.43 2.33 -2.10 -0.350 0.35808E+04 235 ferrous-oxide 9.82 6.49 -3.33 -0.834 0.56931E+04 240 silica-amorphous -2.08 -3.38 -1.30 -0.433 0.22186E+04 242 an20ab80 2.08 1.64 -0.44 -0.034 0.75798E+03 243 an25ab75 2.71 2.13 -0.58 -0.045 0.99538E+03 244 an30ab70 3.34 2.62 -0.73 -0.056 0.12411E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 5.7990000 g New total amount of reactant added: 5.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.9364E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 5.9990000 Water: Moles liquid = 0.5545E+02 kg liquid = 0.9989E+00 Moles total = 0.5543E+02 kg total = 0.9986E+00 Activity = 1.0000 Stoichiometric ionic strength = .3852547E-02 Osmotic coef. = 0.9664 True ionic strength = .6562338E-02 Chg. balance for total moles = -.9364E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.20207E-09 -9.6945 0.18006E-09 -9.7446 0.89110E+00 -0.0501 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13789E-03 -3.8605 0.12258E-03 -3.9116 0.88898E+00 -0.0511 4 SO4-- 0.25518E-04 -4.5932 0.16899E-04 -4.7722 0.66222E+00 -0.1790 5 HCO3- 0.77387E-05 -5.1113 0.68835E-05 -5.1622 0.88949E+00 -0.0509 6 HS- 0.12855E-12 -12.8909 0.11429E-12 -12.9420 0.88903E+00 -0.0511 7 Al+++ 0.31194E-26 -26.5059 0.12554E-26 -26.9012 0.40244E+00 -0.3953 8 H4SiO4 0.40870E-03 -3.3886 0.40870E-03 -3.3886 0.10000E+01 0.0000 9 Ca++ 0.21897E-07 -7.6596 0.14459E-07 -7.8399 0.66033E+00 -0.1802 10 Mg++ 0.26035E-10 -10.5844 0.17161E-10 -10.7655 0.65914E+00 -0.1810 11 Fe++ 0.15393E-12 -12.8127 0.10151E-12 -12.9935 0.65943E+00 -0.1808 12 K+ 0.51018E-04 -4.2923 0.45385E-04 -4.3431 0.88958E+00 -0.0508 13 Na+ 0.64785E-02 -2.1885 0.57590E-02 -2.2397 0.88893E+00 -0.0511 14 Mn++ 0.20563E-10 -10.6869 0.13564E-10 -10.8676 0.65964E+00 -0.1807 15 HPO4-- 0.18046E-05 -5.7436 0.11951E-05 -5.9226 0.66226E+00 -0.1790 16 HSiO3- 0.24911E-02 -2.6036 0.22145E-02 -2.6547 0.88898E+00 -0.0511 17 Ca(HSiO3)+ 0.80642E-09 -9.0934 0.71743E-09 -9.1442 0.88965E+00 -0.0508 18 Mg(HSiO3)+ 0.11911E-11 -11.9240 0.10597E-11 -11.9748 0.88965E+00 -0.0508 19 NaHSiO3,aq 0.20256E-03 -3.6935 0.20256E-03 -3.6935 0.10000E+01 0.0000 20 AlO+ 0.56184E-14 -14.2504 0.49984E-14 -14.3012 0.88965E+00 -0.0508 22 HAlO2,aq 0.55549E-08 -8.2553 0.55549E-08 -8.2553 0.10000E+01 0.0000 23 AlO2- 0.77541E-04 -4.1105 0.68884E-04 -4.1619 0.88835E+00 -0.0514 24 CH4,aq 0.45736E-19 -19.3397 0.45682E-19 -19.3403 0.99881E+00 -0.0005 29 CO,aq 0.60004E-19 -19.2218 0.60004E-19 -19.2218 0.10000E+01 0.0000 30 CO2,aq 0.25020E-08 -8.6017 0.24990E-08 -8.6022 0.99881E+00 -0.0005 31 CO3-2 0.53419E-05 -5.2723 0.35346E-05 -5.4517 0.66167E+00 -0.1794 32 CaCO3,aq 0.62594E-09 -9.2035 0.62594E-09 -9.2035 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.28189E-11 -11.5499 0.25079E-11 -11.6007 0.88965E+00 -0.0508 34 CaCl+ 0.31747E-11 -11.4983 0.28244E-11 -11.5491 0.88965E+00 -0.0508 35 CaCl2,aq 0.80611E-16 -16.0936 0.80611E-16 -16.0936 0.10000E+01 0.0000 36 CaOH+ 0.63646E-08 -8.1962 0.56623E-08 -8.2470 0.88965E+00 -0.0508 37 CaSO4,aq 0.76131E-10 -10.1184 0.76131E-10 -10.1184 0.10000E+01 0.0000 38 HCl,aq 0.41517E-14 -14.3818 0.41517E-14 -14.3818 0.10000E+01 0.0000 43 FeCl+ 0.21783E-16 -16.6619 0.19380E-16 -16.7127 0.88965E+00 -0.0508 46 FeO,aq 0.12380E-09 -9.9073 0.12380E-09 -9.9073 0.10000E+01 0.0000 47 FeOH+ 0.21007E-10 -10.6776 0.18689E-10 -10.7284 0.88965E+00 -0.0508 48 HFeO2- 0.83188E-08 -8.0799 0.73952E-08 -8.1310 0.88898E+00 -0.0511 49 FeO+ 0.16743E-14 -14.7762 0.14895E-14 -14.8270 0.88965E+00 -0.0508 51 FeO2- 0.10157E-07 -7.9932 0.90291E-08 -8.0444 0.88898E+00 -0.0511 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.93339E-09 -9.0299 0.93228E-09 -9.0305 0.99881E+00 -0.0005 54 KCl,aq 0.98507E-10 -10.0065 0.98507E-10 -10.0065 0.10000E+01 0.0000 55 KHSO4,aq 0.36954E-18 -18.4323 0.36954E-18 -18.4323 0.10000E+01 0.0000 56 KOH,aq 0.10988E-06 -6.9591 0.10988E-06 -6.9591 0.10000E+01 0.0000 57 KSO4- 0.13291E-07 -7.8764 0.11816E-07 -7.9275 0.88898E+00 -0.0511 58 MgCO3,aq 0.18564E-12 -12.7313 0.18564E-12 -12.7313 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.34117E-14 -14.4670 0.30352E-14 -14.5178 0.88965E+00 -0.0508 60 MgCl+ 0.34205E-14 -14.4659 0.30431E-14 -14.5167 0.88965E+00 -0.0508 61 MgOH+ 0.41848E-10 -10.3783 0.37231E-10 -10.4291 0.88965E+00 -0.0508 63 MnO,aq 0.44163E-09 -9.3549 0.44163E-09 -9.3549 0.10000E+01 0.0000 64 MnOH+ 0.26077E-09 -9.5837 0.23200E-09 -9.6345 0.88965E+00 -0.0508 65 MnO2-2 0.71193E-12 -12.1476 0.47106E-12 -12.3269 0.66167E+00 -0.1794 66 HMnO2- 0.20672E-10 -10.6846 0.18377E-10 -10.7357 0.88898E+00 -0.0511 69 MnCl+ 0.11311E-13 -13.9465 0.10063E-13 -13.9973 0.88965E+00 -0.0508 70 MnSO4,aq 0.64960E-13 -13.1874 0.64960E-13 -13.1874 0.10000E+01 0.0000 71 NaCl,aq 0.23051E-06 -6.6373 0.23051E-06 -6.6373 0.10000E+01 0.0000 72 NaOH,aq 0.14054E-04 -4.8522 0.14054E-04 -4.8522 0.10000E+01 0.0000 74 OH- 0.37499E-02 -2.4260 0.33312E-02 -2.4774 0.88835E+00 -0.0514 79 HPO3-2 0.53185E-17 -17.2742 0.35191E-17 -17.4536 0.66167E+00 -0.1794 82 H3PO4,aq 0.24946E-15 -15.6030 0.24946E-15 -15.6030 0.10000E+01 0.0000 83 H2PO4- 0.42423E-08 -8.3724 0.37727E-08 -8.4233 0.88931E+00 -0.0509 84 PO4-3 0.14127E-07 -7.8499 0.57962E-08 -8.2369 0.41029E+00 -0.3869 87 H2P2O7-2 0.16836E-17 -17.7738 0.11140E-17 -17.9531 0.66167E+00 -0.1794 88 HP2O7-3 0.31513E-14 -14.5015 0.12686E-14 -14.8967 0.40255E+00 -0.3952 89 P2O7-4 0.85523E-14 -14.0679 0.17380E-14 -14.7599 0.20323E+00 -0.6920 90 H2S,aq 0.61905E-16 -16.2083 0.61831E-16 -16.2088 0.99881E+00 -0.0005 97 SO3-2 0.32281E-14 -14.4911 0.21481E-14 -14.6680 0.66543E+00 -0.1769 98 HSO3- 0.25462E-16 -16.5941 0.22635E-16 -16.6452 0.88898E+00 -0.0511 99 HSO4- 0.31723E-11 -11.4986 0.28233E-11 -11.5492 0.88999E+00 -0.0506 Charge balance for all species = -.9302E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.2020690E-09 -.6773347E-02 -.6823869E+01 0.0000 2 H2O 0.1000000E+01 0.5550948E+02 0.9995425E+06 0.0000 3 Cl- 0.1378891E-03 0.1381198E-03 0.4894422E+01 5.8330 4 SO4-- 0.2551801E-04 0.2553244E-04 0.2451516E+01 14.7170 5 HCO3- 0.7738718E-05 0.1308379E-04 0.7979552E+00 4.5824 6 HS- 0.1285528E-12 -.1061545E-08 -.3509065E-04 -3.1974 7 Al+++ 0.3119366E-26 0.7754679E-04 0.2091330E+01 2.3325 8 H4SiO4 0.4087032E-03 0.3102362E-02 0.2980425E+03 -3.3886 9 Ca++ 0.2189714E-07 0.2977620E-07 0.1192801E-02 11.6493 10 Mg++ 0.2603529E-10 0.6926725E-10 0.1683221E-05 8.7237 11 Fe++ 0.1539310E-12 0.1882389E-07 0.1050756E-02 6.4956 12 K+ 0.5101840E-04 0.5114167E-04 0.1998787E+01 5.4015 13 Na+ 0.6478539E-02 0.6695379E-02 0.1538520E+03 7.5049 14 Mn++ 0.2056299E-10 0.7444278E-09 0.4087785E-04 8.6215 15 HPO4-- 0.1804562E-05 0.1822931E-05 0.1748796E+00 13.5665 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9932149E-01 -.6766208E-02 -.9255529E-01 0.0000000E+00 2 H2O 0.5543305E+02 0.5545097E+02 -.1791969E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1917572E-03 0.2550553E-04 0.1662517E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1662527E-03 -.1060426E-08 -.1662517E-03 0.0000000E+00 7 Al+++ 0.1956119E-01 0.7746506E-04 0.1948372E-01 0.0000000E+00 8 H4SiO4 0.6246628E-01 0.3099093E-02 0.5936719E-01 0.0000000E+00 9 Ca++ 0.6914177E-02 0.2974482E-07 0.6914147E-02 0.0000000E+00 10 Mg++ 0.4761111E-02 0.6919424E-10 0.4761111E-02 0.0000000E+00 11 Fe++ 0.4277339E-02 0.1880405E-07 0.4277320E-02 0.0000000E+00 12 K+ 0.1273673E-02 0.5108777E-04 0.1222585E-02 0.0000000E+00 13 Na+ 0.7690278E-02 0.6688323E-02 0.1001955E-02 0.0000000E+00 14 Mn++ 0.1040142E-03 0.7436432E-09 0.1040135E-03 0.0000000E+00 15 HPO4-- 0.3549954E-04 0.1821010E-05 0.3367853E-04 0.0000000E+00 Chg. balance for solid moles: -.9487E-19 Mass of aqueous solution: 0.999423E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 5.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7929E-03 -3.101 0.2079 -0.682 3.180 0.7981E-01 apatite-OH 0.1123E-04 -4.950 0.5639E-02 -2.249 0.8626E-01 0.1792E-02 clinochlore 0.9522E-03 -3.021 0.5293 -0.276 8.096 0.2013 daphnite 0.5895E-03 -3.230 0.4206 -0.376 6.433 0.1275 chlorite-Mn 0.2080E-04 -4.682 0.1475E-01 -1.831 0.2256 0.4700E-02 hematite 0.6650E-03 -3.177 0.1062 -0.974 1.624 0.2013E-01 microcline 0.1223E-02 -2.913 0.3403 -0.468 5.205 0.1329 paragonite 0.2091E-03 -3.680 0.7991E-01 -1.097 1.222 0.2762E-01 stilbite 0.6858E-02 -2.164 4.833 0.684 73.93 2.254 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6.537544 g Volume = 2.849943 cm3 Porosity: 16.1683% V(tot) - V(min): 0.54966E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 5.9990000 g log = 0.7781 Original solution: 1000.0103000 g Original solution / Rock added: 166.70 (Water/Rock Ratio), log = 2.2219 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2700E-06 1.0073 0.2861E-06 0.2840E-06 CH4,gas 0.6780E-16 1.0129 0.7224E-16 0.7132E-16 H2,gas 0.1215E-05 1.0006 0.1279E-05 0.1278E-05 H2S,gas 0.1721E-14 0.9959 0.1803E-14 0.1811E-14 S2,gas 0.7082E-37 1.0000 0.7450E-37 0.7450E-37 CO,gas 0.9007E-16 1.0000 0.9475E-16 0.9475E-16 SO3,gas 0.1947E-39 1.0000 0.2048E-39 0.2048E-39 SO2,gas 0.9419E-23 1.0000 0.9908E-23 0.9908E-23 HCl,gas 0.6969E-17 1.0000 0.7331E-17 0.7331E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.18198E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.28814E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.91 -8.54 -2.848 0.14588E+05 -6.544 3 CH4,gas 4.81 -13.33 -18.14 -4.535 0.30976E+05 -16.141 4 H2,gas 8.29 0.39 -7.89 -4.510 0.13477E+05 -5.893 5 H2S,gas -5.94 -22.69 -16.74 -8.372 0.28590E+05 -14.744 6 S2,gas -7.03 -46.16 -39.13 -6.020 0.66810E+05 -37.128 7 CO,gas 3.51 -14.51 -18.02 -5.546 0.30775E+05 -16.023 8 SO3,gas 17.43 -24.26 -41.69 -10.422 0.71182E+05 -39.689 9 SO2,gas 1.14 -23.87 -25.00 -6.668 0.42694E+05 -23.004 10 HCl,gas 5.48 -13.66 -19.13 -9.567 0.32672E+05 -17.135 11 acmite 7.74 7.03 -0.71 -0.074 0.12138E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.36 -4.19 -0.209 0.71476E+04 20 analcite 3.37 3.06 -0.31 -0.034 0.53001E+03 21 andalusite 5.06 1.28 -3.79 -0.379 0.64645E+04 22 andradite 39.09 37.38 -1.71 -0.089 0.29164E+04 23 grossular 32.83 29.45 -3.38 -0.169 0.57731E+04 26 annite 20.21 17.06 -3.15 -0.175 0.53857E+04 27 phlogopite 27.15 23.74 -3.41 -0.189 0.58179E+04 29 anorthite 12.80 9.54 -3.26 -0.251 0.55673E+04 35 aragonite 0.99 -3.26 -4.24 -1.415 0.72460E+04 36 brucite 12.58 8.72 -3.85 -0.771 0.65787E+04 37 calcite 0.83 -3.26 -4.09 -1.364 0.69846E+04 38 carnegieite-low 9.06 6.45 -2.62 -0.374 0.44663E+04 39 carnegieite-high 10.13 6.45 -3.69 -0.527 0.62931E+04 40 carpholite-Mg 8.65 6.61 -2.04 -0.136 0.34813E+04 41 carpholite-Fe 6.78 4.38 -2.40 -0.160 0.40970E+04 42 celadonite 5.40 2.90 -2.50 -0.147 0.42639E+04 43 celadonite-Fe 3.94 0.68 -3.26 -0.192 0.55692E+04 44 chrysotile 23.94 19.39 -4.54 -0.379 0.77578E+04 50 chloritoid-Mg 13.26 10.00 -3.26 -0.217 0.55683E+04 51 chloritoid-Fe 9.24 7.77 -1.47 -0.098 0.25042E+04 52 chloritoid-Mn 11.46 9.90 -1.57 -0.104 0.26727E+04 54 coesite -2.37 -3.39 -1.02 -0.340 0.17403E+04 59 corundum 8.43 4.66 -3.77 -0.343 0.64345E+04 61 cristobalite -2.55 -3.39 -0.84 -0.280 0.14332E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.33 -0.56 -0.094 0.96232E+03 67 diopside 16.22 13.60 -2.62 -0.262 0.44730E+04 68 hedenbergite 14.24 11.37 -2.88 -0.288 0.49118E+04 75 epidote 24.78 24.10 -0.68 -0.033 0.11587E+04 76 clinozoisite 22.92 20.13 -2.79 -0.127 0.47653E+04 77 epidote-Fe 29.94 28.06 -1.87 -0.097 0.31995E+04 78 fayalite 14.08 9.60 -4.48 -0.639 0.76431E+04 79 ferrosilite 11.19 6.21 -4.97 -0.497 0.84923E+04 83 gibbsite 4.10 2.33 -1.76 -0.252 0.30135E+04 84 glaucophane 23.11 18.74 -4.37 -0.118 0.74674E+04 87 greenalite 16.19 12.71 -3.48 -0.290 0.59496E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.06 -1.19 -0.119 0.20330E+04 97 kalsilite 7.62 4.35 -3.27 -0.468 0.55917E+04 98 kaolinite -1.27 -2.11 -0.84 -0.076 0.14327E+04 99 kyanite 4.93 1.28 -3.66 -0.366 0.62412E+04 101 laumontite 2.97 2.76 -0.21 -0.014 0.36646E+03 102 lawsonite 9.68 9.54 -0.14 -0.009 0.24121E+03 103 leucite 4.17 0.96 -3.21 -0.321 0.54824E+04 105 lizardite 23.29 19.39 -3.89 -0.324 0.66481E+04 107 magnetite 20.13 19.09 -1.04 -0.085 0.17750E+04 108 minnesotaite 10.46 5.93 -4.53 -0.266 0.77317E+04 110 magnesioferrite 26.26 21.32 -4.94 -0.403 0.84280E+04 113 margarite 17.45 14.20 -3.25 -0.130 0.55488E+04 120 muscovite 2.68 2.23 -0.45 -0.026 0.76153E+03 122 nepheline 8.38 6.45 -1.93 -0.276 0.32942E+04 134 phlogopite-Na 29.73 25.84 -3.89 -0.216 0.66398E+04 136 prehnite 19.47 17.80 -1.67 -0.098 0.28489E+04 137 prehnite-Fe 22.59 21.76 -0.82 -0.049 0.14046E+04 138 pumpellyite-Fe 46.47 44.42 -2.05 -0.045 0.34949E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.056 0.43408E+04 145 pyroxmangite 7.42 5.23 -2.18 -0.437 0.37276E+04 146 pyrophyllite -6.10 -8.89 -2.79 -0.174 0.47662E+04 147 quartz -2.98 -3.39 -0.41 -0.136 0.69425E+03 152 rhodonite 7.46 5.23 -2.23 -0.446 0.38068E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.28 -4.04 -0.404 0.69066E+04 164 stilpnomelane-Fe 13.18 12.74 -0.44 -0.013 0.75835E+03 165 stilpnomelane-Mg 27.60 23.88 -3.72 -0.111 0.63532E+04 168 sudoite 21.22 16.61 -4.60 -0.149 0.78622E+04 171 talc 16.55 12.62 -3.94 -0.232 0.67217E+04 174 tephroite 18.11 13.85 -4.26 -0.608 0.72711E+04 177 topaz-H 4.67 1.28 -3.39 -0.308 0.57903E+04 178 tridymite -2.61 -3.39 -0.77 -0.258 0.13215E+04 187 wairakite 4.06 2.76 -1.30 -0.076 0.22173E+04 188 walstromite 11.53 8.26 -3.27 -0.653 0.55786E+04 189 wollastonite 10.48 8.26 -2.22 -0.444 0.37925E+04 190 pseudo-wollastonite 11.02 8.26 -2.76 -0.552 0.47111E+04 191 zoisite 22.96 20.13 -2.83 -0.129 0.48378E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.08 -3.52 -0.218 0.60096E+04 194 beidellite-H -2.24 -7.00 -4.76 -0.304 0.81281E+04 195 beidellite-K -1.44 -5.22 -3.78 -0.232 0.64609E+04 196 beidellite-Mg -1.71 -5.56 -3.86 -0.238 0.65825E+04 197 beidellite-Na -1.26 -4.52 -3.27 -0.200 0.55796E+04 199 chalcedony -2.79 -3.39 -0.59 -0.198 0.10146E+04 201 montmorillonite-Ca -2.21 -4.86 -2.64 -0.164 0.45148E+04 202 montmorillonite-K -2.16 -5.00 -2.84 -0.174 0.48438E+04 203 montmorillonite-Mg -2.40 -5.34 -2.94 -0.182 0.50187E+04 204 montmorillonite-Na -1.96 -4.30 -2.34 -0.143 0.40007E+04 205 nontronite-Ca 3.28 2.85 -0.43 -0.028 0.72791E+03 206 nontronite-H 2.60 0.93 -1.66 -0.112 0.28421E+04 207 nontronite-K 3.40 2.71 -0.69 -0.044 0.11784E+04 208 nontronite-Mg 3.14 2.37 -0.77 -0.050 0.13124E+04 209 nontronite-Na 3.58 3.41 -0.17 -0.011 0.29878E+03 224 tobermorite 9.84 6.32 -3.52 -0.961 0.60167E+04 233 boehmite 4.43 2.33 -2.10 -0.350 0.35808E+04 235 ferrous-oxide 9.82 6.50 -3.33 -0.832 0.56835E+04 240 silica-amorphous -2.08 -3.39 -1.31 -0.436 0.22348E+04 242 an20ab80 2.08 1.64 -0.43 -0.033 0.74186E+03 243 an25ab75 2.71 2.14 -0.57 -0.044 0.97522E+03 244 an30ab70 3.34 2.63 -0.71 -0.055 0.12169E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 5.9990000 g New total amount of reactant added: 6.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.9367E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 6.1990000 Water: Moles liquid = 0.5545E+02 kg liquid = 0.9989E+00 Moles total = 0.5543E+02 kg total = 0.9986E+00 Activity = 1.0000 Stoichiometric ionic strength = .3963637E-02 Osmotic coef. = 0.9660 True ionic strength = .6749186E-02 Chg. balance for total moles = -.9367E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.19512E-09 -9.7097 0.17366E-09 -9.7603 0.89002E+00 -0.0506 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13789E-03 -3.8605 0.12243E-03 -3.9121 0.88786E+00 -0.0517 4 SO4-- 0.25519E-04 -4.5931 0.16816E-04 -4.7743 0.65896E+00 -0.1811 5 HCO3- 0.76124E-05 -5.1185 0.67627E-05 -5.1699 0.88838E+00 -0.0514 6 HS- 0.13667E-12 -12.8643 0.12135E-12 -12.9160 0.88791E+00 -0.0516 7 Al+++ 0.28299E-26 -26.5482 0.11261E-26 -26.9484 0.39794E+00 -0.4002 8 H4SiO4 0.40019E-03 -3.3977 0.40019E-03 -3.3977 0.10000E+01 0.0000 9 Ca++ 0.23721E-07 -7.6249 0.15586E-07 -7.8073 0.65703E+00 -0.1824 10 Mg++ 0.24649E-10 -10.6082 0.16165E-10 -10.7914 0.65582E+00 -0.1832 11 Fe++ 0.14573E-12 -12.8364 0.95615E-13 -13.0195 0.65611E+00 -0.1830 12 K+ 0.52479E-04 -4.2800 0.46626E-04 -4.3314 0.88847E+00 -0.0514 13 Na+ 0.66641E-02 -2.1763 0.59164E-02 -2.2279 0.88781E+00 -0.0517 14 Mn++ 0.19467E-10 -10.7107 0.12777E-10 -10.8936 0.65633E+00 -0.1829 15 HPO4-- 0.15250E-05 -5.8167 0.10049E-05 -5.9979 0.65900E+00 -0.1811 16 HSiO3- 0.25323E-02 -2.5965 0.22484E-02 -2.6481 0.88786E+00 -0.0517 17 Ca(HSiO3)+ 0.88360E-09 -9.0537 0.78512E-09 -9.1051 0.88855E+00 -0.0513 18 Mg(HSiO3)+ 0.11405E-11 -11.9429 0.10134E-11 -11.9942 0.88855E+00 -0.0513 19 NaHSiO3,aq 0.21127E-03 -3.6752 0.21127E-03 -3.6752 0.10000E+01 0.0000 20 AlO+ 0.54253E-14 -14.2656 0.48206E-14 -14.3169 0.88855E+00 -0.0513 22 HAlO2,aq 0.55549E-08 -8.2553 0.55549E-08 -8.2553 0.10000E+01 0.0000 23 AlO2- 0.80504E-04 -4.0942 0.71424E-04 -4.1462 0.88721E+00 -0.0520 24 CH4,aq 0.47947E-19 -19.3192 0.47889E-19 -19.3198 0.99878E+00 -0.0005 29 CO,aq 0.58310E-19 -19.2343 0.58310E-19 -19.2343 0.10000E+01 0.0000 30 CO2,aq 0.23707E-08 -8.6251 0.23678E-08 -8.6256 0.99878E+00 -0.0005 31 CO3-2 0.54688E-05 -5.2621 0.36006E-05 -5.4436 0.65839E+00 -0.1815 32 CaCO3,aq 0.68730E-09 -9.1629 0.68730E-09 -9.1629 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.29889E-11 -11.5245 0.26558E-11 -11.5758 0.88855E+00 -0.0513 34 CaCl+ 0.34219E-11 -11.4657 0.30405E-11 -11.5171 0.88855E+00 -0.0513 35 CaCl2,aq 0.86669E-16 -16.0621 0.86669E-16 -16.0621 0.10000E+01 0.0000 36 CaOH+ 0.71221E-08 -8.1474 0.63284E-08 -8.1987 0.88855E+00 -0.0513 37 CaSO4,aq 0.81658E-10 -10.0880 0.81658E-10 -10.0880 0.10000E+01 0.0000 38 HCl,aq 0.39990E-14 -14.3980 0.39990E-14 -14.3980 0.10000E+01 0.0000 43 FeCl+ 0.20519E-16 -16.6879 0.18232E-16 -16.7392 0.88855E+00 -0.0513 46 FeO,aq 0.12538E-09 -9.9018 0.12538E-09 -9.9018 0.10000E+01 0.0000 47 FeOH+ 0.20543E-10 -10.6873 0.18253E-10 -10.7387 0.88855E+00 -0.0513 48 HFeO2- 0.87462E-08 -8.0582 0.77654E-08 -8.1098 0.88786E+00 -0.0517 49 FeO+ 0.16167E-14 -14.7914 0.14365E-14 -14.8427 0.88855E+00 -0.0513 51 FeO2- 0.10545E-07 -7.9770 0.93621E-08 -8.0286 0.88786E+00 -0.0517 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.95731E-09 -9.0189 0.95614E-09 -9.0195 0.99878E+00 -0.0005 54 KCl,aq 0.10107E-09 -9.9954 0.10107E-09 -9.9954 0.10000E+01 0.0000 55 KHSO4,aq 0.36435E-18 -18.4385 0.36435E-18 -18.4385 0.10000E+01 0.0000 56 KOH,aq 0.11705E-06 -6.9316 0.11705E-06 -6.9316 0.10000E+01 0.0000 57 KSO4- 0.13605E-07 -7.8663 0.12079E-07 -7.9180 0.88786E+00 -0.0517 58 MgCO3,aq 0.17813E-12 -12.7493 0.17813E-12 -12.7493 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.31612E-14 -14.5001 0.28089E-14 -14.5515 0.88855E+00 -0.0513 60 MgCl+ 0.32219E-14 -14.4919 0.28628E-14 -14.5432 0.88855E+00 -0.0513 61 MgOH+ 0.40924E-10 -10.3880 0.36363E-10 -10.4393 0.88855E+00 -0.0513 63 MnO,aq 0.44725E-09 -9.3495 0.44725E-09 -9.3495 0.10000E+01 0.0000 64 MnOH+ 0.25501E-09 -9.5934 0.22659E-09 -9.6448 0.88855E+00 -0.0513 65 MnO2-2 0.77899E-12 -12.1085 0.51288E-12 -12.2900 0.65839E+00 -0.1815 66 HMnO2- 0.21735E-10 -10.6628 0.19297E-10 -10.7145 0.88786E+00 -0.0517 69 MnCl+ 0.10655E-13 -13.9725 0.94671E-14 -14.0238 0.88855E+00 -0.0513 70 MnSO4,aq 0.60890E-13 -13.2155 0.60890E-13 -13.2155 0.10000E+01 0.0000 71 NaCl,aq 0.23651E-06 -6.6262 0.23651E-06 -6.6262 0.10000E+01 0.0000 72 NaOH,aq 0.14970E-04 -4.8248 0.14970E-04 -4.8248 0.10000E+01 0.0000 74 OH- 0.38932E-02 -2.4097 0.34541E-02 -2.4617 0.88721E+00 -0.0520 79 HPO3-2 0.46096E-17 -17.3363 0.30349E-17 -17.5179 0.65839E+00 -0.1815 82 H3PO4,aq 0.19511E-15 -15.7097 0.19511E-15 -15.7097 0.10000E+01 0.0000 83 H2PO4- 0.34448E-08 -8.4628 0.30596E-08 -8.5143 0.88820E+00 -0.0515 84 PO4-3 0.12451E-07 -7.9048 0.50537E-08 -8.2964 0.40590E+00 -0.3916 87 H2P2O7-2 0.11128E-17 -17.9536 0.73267E-18 -18.1351 0.65839E+00 -0.1815 88 HP2O7-3 0.21733E-14 -14.6629 0.86512E-15 -15.0629 0.39806E+00 -0.4001 89 P2O7-4 0.61677E-14 -14.2099 0.12290E-14 -14.9105 0.19926E+00 -0.7006 90 H2S,aq 0.63395E-16 -16.1979 0.63317E-16 -16.1985 0.99878E+00 -0.0005 97 SO3-2 0.33104E-14 -14.4801 0.21922E-14 -14.6591 0.66224E+00 -0.1790 98 HSO3- 0.25093E-16 -16.6004 0.22279E-16 -16.6521 0.88786E+00 -0.0517 99 HSO4- 0.30482E-11 -11.5160 0.27095E-11 -11.5671 0.88889E+00 -0.0512 Charge balance for all species = -.9318E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1951177E-09 -.6979443E-02 -.7031430E+01 0.0000 2 H2O 0.1000000E+01 0.5550958E+02 0.9995342E+06 0.0000 3 Cl- 0.1378878E-03 0.1381244E-03 0.4894538E+01 5.8482 4 SO4-- 0.2551855E-04 0.2553335E-04 0.2451579E+01 14.7463 5 HCO3- 0.7612408E-05 0.1308423E-04 0.7979741E+00 4.5904 6 HS- 0.1366696E-12 -.1104034E-08 -.3649482E-04 -3.1557 7 Al+++ 0.2829885E-26 0.8050906E-04 0.2171196E+01 2.3325 8 H4SiO4 0.4001855E-03 0.3143781E-02 0.3020185E+03 -3.3977 9 Ca++ 0.2372123E-07 0.3250233E-07 0.1301993E-02 11.7133 10 Mg++ 0.2464865E-10 0.6689796E-10 0.1625630E-05 8.7292 11 Fe++ 0.1457310E-12 0.1964029E-07 0.1096316E-02 6.5011 12 K+ 0.5247857E-04 0.5260932E-04 0.2056127E+01 5.4289 13 Na+ 0.6664078E-02 0.6890556E-02 0.1583353E+03 7.5324 14 Mn++ 0.1946745E-10 0.7443146E-09 0.4087122E-04 8.6270 15 HPO4-- 0.1524954E-05 0.1540850E-05 0.1478171E+00 13.5227 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1026332E+00 -.6971850E-02 -.9566135E-01 0.0000000E+00 2 H2O 0.5543054E+02 0.5544919E+02 -.1864924E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1972999E-03 0.2550557E-04 0.1717943E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1717954E-03 -.1102833E-08 -.1717943E-03 0.0000000E+00 7 Al+++ 0.2021334E-01 0.8042148E-04 0.2013292E-01 0.0000000E+00 8 H4SiO4 0.6454884E-01 0.3140362E-02 0.6140848E-01 0.0000000E+00 9 Ca++ 0.7144205E-02 0.3246697E-07 0.7144173E-02 0.0000000E+00 10 Mg++ 0.4919841E-02 0.6682519E-10 0.4919841E-02 0.0000000E+00 11 Fe++ 0.4419940E-02 0.1961892E-07 0.4419921E-02 0.0000000E+00 12 K+ 0.1316136E-02 0.5255209E-04 0.1263584E-02 0.0000000E+00 13 Na+ 0.7941326E-02 0.6883061E-02 0.1058266E-02 0.0000000E+00 14 Mn++ 0.1074820E-03 0.7435050E-09 0.1074812E-03 0.0000000E+00 15 HPO4-- 0.3668306E-04 0.1539173E-05 0.3514388E-04 0.0000000E+00 Chg. balance for solid moles: 0.8267E-17 Mass of aqueous solution: 0.999399E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 6.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8529E-03 -3.069 0.2237 -0.650 3.309 0.8585E-01 apatite-OH 0.1171E-04 -4.931 0.5884E-02 -2.230 0.8705E-01 0.1870E-02 clinochlore 0.9840E-03 -3.007 0.5469 -0.262 8.091 0.2080 daphnite 0.6091E-03 -3.215 0.4346 -0.362 6.429 0.1317 chlorite-Mn 0.2150E-04 -4.668 0.1524E-01 -1.817 0.2255 0.4857E-02 hematite 0.6872E-03 -3.163 0.1097 -0.960 1.624 0.2080E-01 microcline 0.1264E-02 -2.898 0.3517 -0.454 5.203 0.1374 paragonite 0.2054E-03 -3.687 0.7849E-01 -1.105 1.161 0.2713E-01 stilbite 0.7086E-02 -2.150 4.993 0.698 73.87 2.329 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6.759601 g Volume = 2.946623 cm3 Porosity: 15.3172% V(tot) - V(min): 0.53298E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6.1990000 g log = 0.7923 Original solution: 1000.0103000 g Original solution / Rock added: 161.32 (Water/Rock Ratio), log = 2.2077 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2558E-06 1.0073 0.2710E-06 0.2691E-06 CH4,gas 0.7107E-16 1.0129 0.7573E-16 0.7476E-16 H2,gas 0.1246E-05 1.0006 0.1311E-05 0.1311E-05 H2S,gas 0.1763E-14 0.9959 0.1847E-14 0.1854E-14 S2,gas 0.7060E-37 1.0000 0.7427E-37 0.7427E-37 CO,gas 0.8753E-16 1.0000 0.9207E-16 0.9207E-16 SO3,gas 0.1802E-39 1.0000 0.1896E-39 0.1896E-39 SO2,gas 0.8941E-23 1.0000 0.9406E-23 0.9406E-23 HCl,gas 0.6712E-17 1.0000 0.7061E-17 0.7061E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.93 -8.57 -2.856 0.14628E+05 -6.567 3 CH4,gas 4.81 -13.31 -18.12 -4.530 0.30941E+05 -16.121 4 H2,gas 8.29 0.40 -7.88 -4.504 0.13459E+05 -5.882 5 H2S,gas -5.94 -22.68 -16.73 -8.367 0.28572E+05 -14.734 6 S2,gas -7.03 -46.16 -39.13 -6.020 0.66812E+05 -37.129 7 CO,gas 3.51 -14.53 -18.04 -5.549 0.30796E+05 -16.036 8 SO3,gas 17.43 -24.29 -41.72 -10.431 0.71240E+05 -39.722 9 SO2,gas 1.14 -23.89 -25.03 -6.674 0.42732E+05 -23.027 10 HCl,gas 5.48 -13.67 -19.15 -9.576 0.32700E+05 -17.151 11 acmite 7.74 7.04 -0.70 -0.073 0.11981E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.35 -4.20 -0.210 0.71663E+04 20 analcite 3.37 3.07 -0.30 -0.033 0.51439E+03 21 andalusite 5.06 1.27 -3.80 -0.380 0.64801E+04 22 andradite 39.09 37.54 -1.54 -0.080 0.26353E+04 23 grossular 32.83 29.61 -3.22 -0.161 0.54920E+04 26 annite 20.21 17.07 -3.14 -0.174 0.53576E+04 27 phlogopite 27.15 23.76 -3.39 -0.188 0.57898E+04 29 anorthite 12.80 9.58 -3.21 -0.247 0.54893E+04 35 aragonite 0.99 -3.22 -4.20 -1.401 0.71766E+04 36 brucite 12.58 8.73 -3.85 -0.769 0.65694E+04 37 calcite 0.83 -3.22 -4.05 -1.350 0.69153E+04 38 carnegieite-low 9.06 6.47 -2.60 -0.371 0.44351E+04 39 carnegieite-high 10.13 6.47 -3.67 -0.524 0.62619E+04 40 carpholite-Mg 8.65 6.60 -2.05 -0.137 0.35032E+04 41 carpholite-Fe 6.78 4.37 -2.41 -0.161 0.41188E+04 42 celadonite 5.40 2.90 -2.50 -0.147 0.42701E+04 43 celadonite-Fe 3.94 0.67 -3.27 -0.192 0.55755E+04 44 chrysotile 23.94 19.39 -4.55 -0.379 0.77609E+04 50 chloritoid-Mg 13.26 10.00 -3.26 -0.218 0.55746E+04 51 chloritoid-Fe 9.24 7.77 -1.47 -0.098 0.25105E+04 52 chloritoid-Mn 11.46 9.89 -1.57 -0.105 0.26789E+04 54 coesite -2.37 -3.40 -1.03 -0.343 0.17559E+04 59 corundum 8.43 4.66 -3.77 -0.343 0.64345E+04 61 cristobalite -2.55 -3.40 -0.85 -0.283 0.14488E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.33 -0.56 -0.094 0.96232E+03 67 diopside 16.22 13.65 -2.57 -0.257 0.43855E+04 68 hedenbergite 14.24 11.42 -2.83 -0.283 0.48244E+04 75 epidote 24.78 24.20 -0.58 -0.028 0.98687E+03 76 clinozoisite 22.92 20.23 -2.69 -0.122 0.45935E+04 77 epidote-Fe 29.94 28.16 -1.77 -0.092 0.30277E+04 78 fayalite 14.08 9.60 -4.47 -0.639 0.76400E+04 79 ferrosilite 11.19 6.21 -4.98 -0.498 0.85048E+04 83 gibbsite 4.10 2.33 -1.76 -0.252 0.30135E+04 84 glaucophane 23.11 18.74 -4.38 -0.118 0.74705E+04 87 greenalite 16.19 12.71 -3.49 -0.291 0.59527E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.07 -1.18 -0.118 0.20174E+04 97 kalsilite 7.62 4.36 -3.26 -0.465 0.55605E+04 98 kaolinite -1.27 -2.13 -0.86 -0.078 0.14639E+04 99 kyanite 4.93 1.27 -3.66 -0.366 0.62568E+04 101 laumontite 2.97 2.79 -0.19 -0.012 0.31961E+03 102 lawsonite 9.68 9.58 -0.10 -0.006 0.16313E+03 103 leucite 4.17 0.97 -3.20 -0.320 0.54668E+04 105 lizardite 23.29 19.39 -3.90 -0.325 0.66512E+04 107 magnetite 20.13 19.10 -1.03 -0.084 0.17656E+04 108 minnesotaite 10.46 5.91 -4.55 -0.268 0.77661E+04 110 magnesioferrite 26.26 21.33 -4.93 -0.402 0.84186E+04 113 margarite 17.45 14.25 -3.20 -0.128 0.54707E+04 120 muscovite 2.68 2.23 -0.45 -0.026 0.76153E+03 122 nepheline 8.38 6.47 -1.91 -0.273 0.32630E+04 134 phlogopite-Na 29.73 25.86 -3.87 -0.215 0.66117E+04 136 prehnite 19.47 17.90 -1.57 -0.092 0.26772E+04 137 prehnite-Fe 22.59 21.86 -0.72 -0.043 0.12328E+04 138 pumpellyite-Fe 46.47 44.63 -1.84 -0.041 0.31419E+04 139 pumpellyite-Mg 49.19 46.86 -2.34 -0.052 0.39878E+04 145 pyroxmangite 7.42 5.23 -2.19 -0.437 0.37338E+04 146 pyrophyllite -6.10 -8.93 -2.83 -0.177 0.48286E+04 147 quartz -2.98 -3.40 -0.42 -0.139 0.70987E+03 152 rhodonite 7.46 5.23 -2.23 -0.447 0.38130E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.27 -4.05 -0.405 0.69223E+04 164 stilpnomelane-Fe 13.18 12.70 -0.48 -0.014 0.81302E+03 165 stilpnomelane-Mg 27.60 23.84 -3.75 -0.112 0.64078E+04 168 sudoite 21.22 16.60 -4.62 -0.149 0.78903E+04 171 talc 16.55 12.60 -3.96 -0.233 0.67561E+04 174 tephroite 18.11 13.86 -4.26 -0.608 0.72680E+04 177 topaz-H 4.67 1.27 -3.40 -0.309 0.58059E+04 178 tridymite -2.61 -3.40 -0.78 -0.261 0.13372E+04 187 wairakite 4.06 2.79 -1.27 -0.075 0.21704E+04 188 walstromite 11.53 8.32 -3.21 -0.642 0.54849E+04 189 wollastonite 10.48 8.32 -2.17 -0.433 0.36988E+04 190 pseudo-wollastonite 11.02 8.32 -2.70 -0.541 0.46174E+04 191 zoisite 22.96 20.23 -2.73 -0.124 0.46660E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.10 -3.54 -0.219 0.60489E+04 194 beidellite-H -2.24 -7.03 -4.79 -0.306 0.81854E+04 195 beidellite-K -1.44 -5.24 -3.81 -0.233 0.65028E+04 196 beidellite-Mg -1.71 -5.59 -3.89 -0.241 0.66383E+04 197 beidellite-Na -1.26 -4.55 -3.29 -0.202 0.56215E+04 199 chalcedony -2.79 -3.40 -0.60 -0.201 0.10302E+04 201 montmorillonite-Ca -2.21 -4.88 -2.67 -0.165 0.45561E+04 202 montmorillonite-K -2.16 -5.02 -2.86 -0.175 0.48877E+04 203 montmorillonite-Mg -2.40 -5.37 -2.97 -0.184 0.50765E+04 204 montmorillonite-Na -1.96 -4.33 -2.37 -0.145 0.40446E+04 205 nontronite-Ca 3.28 2.83 -0.45 -0.029 0.76719E+03 206 nontronite-H 2.60 0.90 -1.70 -0.114 0.28995E+04 207 nontronite-K 3.40 2.69 -0.71 -0.046 0.12202E+04 208 nontronite-Mg 3.14 2.34 -0.80 -0.052 0.13682E+04 209 nontronite-Na 3.58 3.38 -0.20 -0.013 0.34064E+03 224 tobermorite 9.84 6.36 -3.48 -0.949 0.59412E+04 233 boehmite 4.43 2.33 -2.10 -0.350 0.35808E+04 235 ferrous-oxide 9.82 6.50 -3.32 -0.831 0.56741E+04 240 silica-amorphous -2.08 -3.40 -1.32 -0.439 0.22504E+04 242 an20ab80 2.08 1.65 -0.43 -0.033 0.72624E+03 243 an25ab75 2.71 2.15 -0.56 -0.043 0.95570E+03 244 an30ab70 3.34 2.64 -0.70 -0.054 0.11935E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 6.1990000 g New total amount of reactant added: 6.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.9367E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 6.3990000 Water: Moles liquid = 0.5545E+02 kg liquid = 0.9989E+00 Moles total = 0.5543E+02 kg total = 0.9986E+00 Activity = 1.0000 Stoichiometric ionic strength = .4074954E-02 Osmotic coef. = 0.9656 True ionic strength = .6936097E-02 Chg. balance for total moles = -.9367E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.18862E-09 -9.7244 0.16768E-09 -9.7755 0.88897E+00 -0.0511 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13789E-03 -3.8605 0.12227E-03 -3.9127 0.88676E+00 -0.0522 4 SO4-- 0.25519E-04 -4.5931 0.16735E-04 -4.7764 0.65577E+00 -0.1833 5 HCO3- 0.74892E-05 -5.1256 0.66451E-05 -5.1775 0.88729E+00 -0.0519 6 HS- 0.14503E-12 -12.8385 0.12861E-12 -12.8907 0.88681E+00 -0.0522 7 Al+++ 0.25759E-26 -26.5891 0.10138E-26 -26.9941 0.39357E+00 -0.4050 8 H4SiO4 0.39210E-03 -3.4066 0.39210E-03 -3.4066 0.10000E+01 0.0000 9 Ca++ 0.25640E-07 -7.5911 0.16763E-07 -7.7756 0.65380E+00 -0.1846 10 Mg++ 0.23380E-10 -10.6312 0.15257E-10 -10.8165 0.65257E+00 -0.1854 11 Fe++ 0.13823E-12 -12.8594 0.90244E-13 -13.0446 0.65286E+00 -0.1852 12 K+ 0.53939E-04 -4.2681 0.47864E-04 -4.3200 0.88738E+00 -0.0519 13 Na+ 0.68496E-02 -2.1643 0.60736E-02 -2.2166 0.88670E+00 -0.0522 14 Mn++ 0.18465E-10 -10.7337 0.12059E-10 -10.9187 0.65308E+00 -0.1850 15 HPO4-- 0.12952E-05 -5.8877 0.84941E-06 -6.0709 0.65580E+00 -0.1832 16 HSiO3- 0.25728E-02 -2.5896 0.22815E-02 -2.6418 0.88676E+00 -0.0522 17 Ca(HSiO3)+ 0.96555E-09 -9.0152 0.85689E-09 -9.0671 0.88746E+00 -0.0519 18 Mg(HSiO3)+ 0.10937E-11 -11.9611 0.97057E-12 -12.0130 0.88746E+00 -0.0519 19 NaHSiO3,aq 0.22008E-03 -3.6574 0.22008E-03 -3.6574 0.10000E+01 0.0000 20 AlO+ 0.52449E-14 -14.2803 0.46547E-14 -14.3321 0.88746E+00 -0.0519 22 HAlO2,aq 0.55549E-08 -8.2553 0.55549E-08 -8.2553 0.10000E+01 0.0000 23 AlO2- 0.83479E-04 -4.0784 0.73970E-04 -4.1309 0.88610E+00 -0.0525 24 CH4,aq 0.50178E-19 -19.2995 0.50114E-19 -19.3000 0.99874E+00 -0.0005 29 CO,aq 0.56695E-19 -19.2465 0.56695E-19 -19.2465 0.10000E+01 0.0000 30 CO2,aq 0.22494E-08 -8.6479 0.22466E-08 -8.6485 0.99874E+00 -0.0005 31 CO3-2 0.55925E-05 -5.2524 0.36641E-05 -5.4360 0.65519E+00 -0.1836 32 CaCO3,aq 0.75229E-09 -9.1236 0.75229E-09 -9.1236 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.31627E-11 -11.4999 0.28068E-11 -11.5518 0.88746E+00 -0.0519 34 CaCl+ 0.36804E-11 -11.4341 0.32662E-11 -11.4860 0.88746E+00 -0.0519 35 CaCl2,aq 0.92986E-16 -16.0316 0.92986E-16 -16.0316 0.10000E+01 0.0000 36 CaOH+ 0.79433E-08 -8.1000 0.70493E-08 -8.1519 0.88746E+00 -0.0519 37 CaSO4,aq 0.87406E-10 -10.0585 0.87406E-10 -10.0585 0.10000E+01 0.0000 38 HCl,aq 0.38565E-14 -14.4138 0.38565E-14 -14.4138 0.10000E+01 0.0000 43 FeCl+ 0.19365E-16 -16.7130 0.17186E-16 -16.7648 0.88746E+00 -0.0519 46 FeO,aq 0.12692E-09 -9.8965 0.12692E-09 -9.8965 0.10000E+01 0.0000 47 FeOH+ 0.20105E-10 -10.6967 0.17842E-10 -10.7486 0.88746E+00 -0.0519 48 HFeO2- 0.91811E-08 -8.0371 0.81415E-08 -8.0893 0.88676E+00 -0.0522 49 FeO+ 0.15630E-14 -14.8060 0.13871E-14 -14.8579 0.88746E+00 -0.0519 51 FeO2- 0.10934E-07 -7.9612 0.96959E-08 -8.0134 0.88676E+00 -0.0522 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.98109E-09 -9.0083 0.97986E-09 -9.0088 0.99874E+00 -0.0005 54 KCl,aq 0.10363E-09 -9.9845 0.10363E-09 -9.9845 0.10000E+01 0.0000 55 KHSO4,aq 0.35941E-18 -18.4444 0.35941E-18 -18.4444 0.10000E+01 0.0000 56 KOH,aq 0.12444E-06 -6.9050 0.12444E-06 -6.9050 0.10000E+01 0.0000 57 KSO4- 0.13916E-07 -7.8565 0.12340E-07 -7.9087 0.88676E+00 -0.0522 58 MgCO3,aq 0.17109E-12 -12.7668 0.17109E-12 -12.7668 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.29353E-14 -14.5323 0.26050E-14 -14.5842 0.88746E+00 -0.0519 60 MgCl+ 0.30408E-14 -14.5170 0.26986E-14 -14.5689 0.88746E+00 -0.0519 61 MgOH+ 0.40051E-10 -10.3974 0.35544E-10 -10.4492 0.88746E+00 -0.0519 63 MnO,aq 0.45276E-09 -9.3441 0.45276E-09 -9.3441 0.10000E+01 0.0000 64 MnOH+ 0.24958E-09 -9.6028 0.22149E-09 -9.6546 0.88746E+00 -0.0519 65 MnO2-2 0.84997E-12 -12.0706 0.55689E-12 -12.2542 0.65519E+00 -0.1836 66 HMnO2- 0.22816E-10 -10.6418 0.20232E-10 -10.6940 0.88676E+00 -0.0522 69 MnCl+ 0.10056E-13 -13.9976 0.89241E-14 -14.0494 0.88746E+00 -0.0519 70 MnSO4,aq 0.57192E-13 -13.2427 0.57192E-13 -13.2427 0.10000E+01 0.0000 71 NaCl,aq 0.24249E-06 -6.6153 0.24249E-06 -6.6153 0.10000E+01 0.0000 72 NaOH,aq 0.15916E-04 -4.7982 0.15916E-04 -4.7982 0.10000E+01 0.0000 74 OH- 0.40371E-02 -2.3939 0.35772E-02 -2.4465 0.88610E+00 -0.0525 79 HPO3-2 0.40123E-17 -17.3966 0.26289E-17 -17.5802 0.65519E+00 -0.1836 82 H3PO4,aq 0.15376E-15 -15.8132 0.15376E-15 -15.8132 0.10000E+01 0.0000 83 H2PO4- 0.28149E-08 -8.5505 0.24971E-08 -8.6026 0.88710E+00 -0.0520 84 PO4-3 0.11015E-07 -7.9580 0.44239E-08 -8.3542 0.40163E+00 -0.3962 87 H2P2O7-2 0.74484E-18 -18.1279 0.48801E-18 -18.3116 0.65519E+00 -0.1836 88 HP2O7-3 0.15159E-14 -14.8193 0.59678E-15 -15.2242 0.39369E+00 -0.4048 89 P2O7-4 0.44925E-14 -14.3475 0.87800E-15 -15.0565 0.19544E+00 -0.7090 90 H2S,aq 0.64879E-16 -16.1879 0.64797E-16 -16.1884 0.99874E+00 -0.0005 97 SO3-2 0.33922E-14 -14.4695 0.22358E-14 -14.6506 0.65911E+00 -0.1810 98 HSO3- 0.24741E-16 -16.6066 0.21940E-16 -16.6588 0.88676E+00 -0.0522 99 HSO4- 0.29327E-11 -11.5327 0.26036E-11 -11.5844 0.88781E+00 -0.0517 Charge balance for all species = -.9312E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1886231E-09 -.7185612E-02 -.7239062E+01 0.0000 2 H2O 0.1000000E+01 0.5550968E+02 0.9995258E+06 0.0000 3 Cl- 0.1378865E-03 0.1381291E-03 0.4894654E+01 5.8628 4 SO4-- 0.2551910E-04 0.2553426E-04 0.2451641E+01 14.7746 5 HCO3- 0.7489207E-05 0.1308468E-04 0.7979930E+00 4.5980 6 HS- 0.1450306E-12 -.1146775E-08 -.3790728E-04 -3.1152 7 Al+++ 0.2575858E-26 0.8348463E-04 0.2251420E+01 2.3325 8 H4SiO4 0.3920972E-03 0.3184981E-02 0.3059734E+03 -3.4066 9 Ca++ 0.2564002E-07 0.3539537E-07 0.1417870E-02 11.7754 10 Mg++ 0.2337981E-10 0.6470186E-10 0.1572249E-05 8.7345 11 Fe++ 0.1382278E-12 0.2046585E-07 0.1142388E-02 6.5065 12 K+ 0.5393879E-04 0.5407725E-04 0.2113476E+01 5.4555 13 Na+ 0.6849632E-02 0.7085867E-02 0.1628216E+03 7.5590 14 Mn++ 0.1846498E-10 0.7445332E-09 0.4088281E-04 8.6324 15 HPO4-- 0.1295214E-05 0.1309044E-05 0.1255782E+00 13.4801 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1059449E+00 -.7177553E-02 -.9876735E-01 0.0000000E+00 2 H2O 0.5542804E+02 0.5544741E+02 -.1937869E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2028426E-03 0.2550562E-04 0.1773370E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1773381E-03 -.1145489E-08 -.1773370E-03 0.0000000E+00 7 Al+++ 0.2086549E-01 0.8339099E-04 0.2078209E-01 0.0000000E+00 8 H4SiO4 0.6663140E-01 0.3181408E-02 0.6344999E-01 0.0000000E+00 9 Ca++ 0.7374234E-02 0.3535567E-07 0.7374199E-02 0.0000000E+00 10 Mg++ 0.5078571E-02 0.6462928E-10 0.5078571E-02 0.0000000E+00 11 Fe++ 0.4562542E-02 0.2044290E-07 0.4562522E-02 0.0000000E+00 12 K+ 0.1358599E-02 0.5401659E-04 0.1304582E-02 0.0000000E+00 13 Na+ 0.8192375E-02 0.7077919E-02 0.1114456E-02 0.0000000E+00 14 Mn++ 0.1109497E-03 0.7436981E-09 0.1109489E-03 0.0000000E+00 15 HPO4-- 0.3786657E-04 0.1307575E-05 0.3655900E-04 0.0000000E+00 Chg. balance for solid moles: 0.4296E-17 Mass of aqueous solution: 0.999376E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 6.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9129E-03 -3.040 0.2394 -0.621 3.429 0.9189E-01 apatite-OH 0.1219E-04 -4.914 0.6121E-02 -2.213 0.8768E-01 0.1945E-02 clinochlore 0.1016E-02 -2.993 0.5646 -0.248 8.086 0.2147 daphnite 0.6288E-03 -3.202 0.4486 -0.348 6.426 0.1359 chlorite-Mn 0.2219E-04 -4.654 0.1573E-01 -1.803 0.2253 0.5013E-02 hematite 0.7093E-03 -3.149 0.1133 -0.946 1.623 0.2147E-01 microcline 0.1305E-02 -2.885 0.3631 -0.440 5.201 0.1418 paragonite 0.2016E-03 -3.696 0.7705E-01 -1.113 1.104 0.2663E-01 stilbite 0.7313E-02 -2.136 5.154 0.712 73.82 2.404 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6.981673 g Volume = 3.043315 cm3 Porosity: 14.5040% V(tot) - V(min): 0.51628E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6.3990000 g log = 0.8061 Original solution: 1000.0103000 g Original solution / Rock added: 156.28 (Water/Rock Ratio), log = 2.1939 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2427E-06 1.0073 0.2572E-06 0.2553E-06 CH4,gas 0.7438E-16 1.0129 0.7925E-16 0.7824E-16 H2,gas 0.1277E-05 1.0006 0.1344E-05 0.1343E-05 H2S,gas 0.1804E-14 0.9959 0.1890E-14 0.1898E-14 S2,gas 0.7041E-37 1.0000 0.7406E-37 0.7406E-37 CO,gas 0.8510E-16 1.0000 0.8952E-16 0.8952E-16 SO3,gas 0.1672E-39 1.0000 0.1759E-39 0.1759E-39 SO2,gas 0.8502E-23 1.0000 0.8943E-23 0.8943E-23 HCl,gas 0.6473E-17 1.0000 0.6809E-17 0.6809E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.15165E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.95 -8.59 -2.863 0.14667E+05 -6.590 3 CH4,gas 4.81 -13.29 -18.10 -4.525 0.30907E+05 -16.101 4 H2,gas 8.29 0.42 -7.87 -4.498 0.13441E+05 -5.872 5 H2S,gas -5.94 -22.67 -16.72 -8.362 0.28555E+05 -14.724 6 S2,gas -7.03 -46.16 -39.13 -6.020 0.66814E+05 -37.130 7 CO,gas 3.51 -14.54 -18.05 -5.553 0.30817E+05 -16.048 8 SO3,gas 17.43 -24.33 -41.75 -10.439 0.71295E+05 -39.755 9 SO2,gas 1.14 -23.91 -25.05 -6.680 0.42770E+05 -23.049 10 HCl,gas 5.48 -13.69 -19.17 -9.583 0.32727E+05 -17.167 11 acmite 7.74 7.04 -0.69 -0.072 0.11830E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.34 -4.21 -0.210 0.71845E+04 20 analcite 3.37 3.08 -0.29 -0.032 0.49925E+03 21 andalusite 5.06 1.26 -3.80 -0.380 0.64952E+04 22 andradite 39.09 37.70 -1.38 -0.072 0.23627E+04 23 grossular 32.83 29.77 -3.06 -0.153 0.52195E+04 26 annite 20.21 17.09 -3.12 -0.173 0.53303E+04 27 phlogopite 27.15 23.77 -3.37 -0.187 0.57625E+04 29 anorthite 12.80 9.63 -3.17 -0.244 0.54135E+04 35 aragonite 0.99 -3.18 -4.16 -1.388 0.71096E+04 36 brucite 12.58 8.73 -3.84 -0.768 0.65603E+04 37 calcite 0.83 -3.18 -4.01 -1.337 0.68483E+04 38 carnegieite-low 9.06 6.48 -2.58 -0.369 0.44048E+04 39 carnegieite-high 10.13 6.48 -3.65 -0.521 0.62316E+04 40 carpholite-Mg 8.65 6.59 -2.06 -0.138 0.35244E+04 41 carpholite-Fe 6.78 4.36 -2.42 -0.162 0.41400E+04 42 celadonite 5.40 2.90 -2.50 -0.147 0.42762E+04 43 celadonite-Fe 3.94 0.67 -3.27 -0.192 0.55815E+04 44 chrysotile 23.94 19.39 -4.55 -0.379 0.77640E+04 50 chloritoid-Mg 13.26 9.99 -3.27 -0.218 0.55806E+04 51 chloritoid-Fe 9.24 7.76 -1.47 -0.098 0.25165E+04 52 chloritoid-Mn 11.46 9.89 -1.57 -0.105 0.26850E+04 54 coesite -2.37 -3.41 -1.04 -0.346 0.17711E+04 59 corundum 8.43 4.66 -3.77 -0.343 0.64345E+04 61 cristobalite -2.55 -3.41 -0.86 -0.286 0.14640E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.33 -0.56 -0.094 0.96232E+03 67 diopside 16.22 13.70 -2.52 -0.252 0.43008E+04 68 hedenbergite 14.24 11.47 -2.78 -0.278 0.47396E+04 75 epidote 24.78 24.29 -0.48 -0.023 0.82032E+03 76 clinozoisite 22.92 20.33 -2.59 -0.118 0.44269E+04 77 epidote-Fe 29.94 28.26 -1.68 -0.087 0.28612E+04 78 fayalite 14.08 9.61 -4.47 -0.639 0.76369E+04 79 ferrosilite 11.19 6.20 -4.99 -0.499 0.85169E+04 83 gibbsite 4.10 2.33 -1.76 -0.252 0.30135E+04 84 glaucophane 23.11 18.73 -4.38 -0.118 0.74735E+04 87 greenalite 16.19 12.71 -3.49 -0.291 0.59558E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.08 -1.17 -0.117 0.20023E+04 97 kalsilite 7.62 4.38 -3.24 -0.463 0.55302E+04 98 kaolinite -1.27 -2.15 -0.88 -0.080 0.14942E+04 99 kyanite 4.93 1.26 -3.67 -0.367 0.62720E+04 101 laumontite 2.97 2.81 -0.16 -0.011 0.27419E+03 102 lawsonite 9.68 9.63 -0.05 -0.003 0.87421E+02 103 leucite 4.17 0.97 -3.19 -0.319 0.54517E+04 105 lizardite 23.29 19.39 -3.90 -0.325 0.66542E+04 107 magnetite 20.13 19.10 -1.03 -0.084 0.17565E+04 108 minnesotaite 10.46 5.89 -4.57 -0.269 0.77994E+04 110 magnesioferrite 26.26 21.33 -4.93 -0.402 0.84096E+04 113 margarite 17.45 14.29 -3.16 -0.126 0.53950E+04 120 muscovite 2.68 2.23 -0.45 -0.026 0.76153E+03 122 nepheline 8.38 6.48 -1.89 -0.270 0.32327E+04 134 phlogopite-Na 29.73 25.88 -3.86 -0.214 0.65844E+04 136 prehnite 19.47 18.00 -1.47 -0.086 0.25106E+04 137 prehnite-Fe 22.59 21.96 -0.62 -0.038 0.10663E+04 138 pumpellyite-Fe 46.47 44.83 -1.64 -0.036 0.27997E+04 139 pumpellyite-Mg 49.19 47.06 -2.14 -0.047 0.36456E+04 145 pyroxmangite 7.42 5.23 -2.19 -0.438 0.37399E+04 146 pyrophyllite -6.10 -8.96 -2.86 -0.179 0.48892E+04 147 quartz -2.98 -3.41 -0.42 -0.142 0.72501E+03 152 rhodonite 7.46 5.23 -2.24 -0.447 0.38191E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.26 -4.06 -0.406 0.69374E+04 164 stilpnomelane-Fe 13.18 12.67 -0.51 -0.015 0.86601E+03 165 stilpnomelane-Mg 27.60 23.81 -3.78 -0.113 0.64608E+04 168 sudoite 21.22 16.58 -4.64 -0.150 0.79176E+04 171 talc 16.55 12.58 -3.98 -0.234 0.67894E+04 174 tephroite 18.11 13.86 -4.25 -0.608 0.72650E+04 177 topaz-H 4.67 1.26 -3.41 -0.310 0.58211E+04 178 tridymite -2.61 -3.41 -0.79 -0.264 0.13523E+04 187 wairakite 4.06 2.81 -1.24 -0.073 0.21250E+04 188 walstromite 11.53 8.37 -3.16 -0.632 0.53940E+04 189 wollastonite 10.48 8.37 -2.11 -0.423 0.36079E+04 190 pseudo-wollastonite 11.02 8.37 -2.65 -0.530 0.45266E+04 191 zoisite 22.96 20.33 -2.64 -0.120 0.44995E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.12 -3.56 -0.221 0.60870E+04 194 beidellite-H -2.24 -7.07 -4.83 -0.308 0.82410E+04 195 beidellite-K -1.44 -5.27 -3.83 -0.235 0.65433E+04 196 beidellite-Mg -1.71 -5.63 -3.92 -0.242 0.66924E+04 197 beidellite-Na -1.26 -4.57 -3.32 -0.203 0.56621E+04 199 chalcedony -2.79 -3.41 -0.61 -0.204 0.10453E+04 201 montmorillonite-Ca -2.21 -4.91 -2.69 -0.167 0.45962E+04 202 montmorillonite-K -2.16 -5.05 -2.89 -0.177 0.49303E+04 203 montmorillonite-Mg -2.40 -5.41 -3.01 -0.186 0.51326E+04 204 montmorillonite-Na -1.96 -4.35 -2.39 -0.147 0.40872E+04 205 nontronite-Ca 3.28 2.81 -0.47 -0.031 0.80527E+03 206 nontronite-H 2.60 0.87 -1.73 -0.116 0.29550E+04 207 nontronite-K 3.40 2.67 -0.74 -0.047 0.12608E+04 208 nontronite-Mg 3.14 2.31 -0.83 -0.054 0.14223E+04 209 nontronite-Na 3.58 3.36 -0.22 -0.014 0.38122E+03 224 tobermorite 9.84 6.40 -3.44 -0.938 0.58681E+04 233 boehmite 4.43 2.33 -2.10 -0.350 0.35808E+04 235 ferrous-oxide 9.82 6.51 -3.32 -0.829 0.56650E+04 240 silica-amorphous -2.08 -3.41 -1.33 -0.442 0.22655E+04 242 an20ab80 2.08 1.66 -0.42 -0.032 0.71110E+03 243 an25ab75 2.71 2.16 -0.55 -0.042 0.93678E+03 244 an30ab70 3.34 2.66 -0.69 -0.053 0.11708E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 6.3990000 g New total amount of reactant added: 6.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.9370E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 6.5990000 Water: Moles liquid = 0.5544E+02 kg liquid = 0.9988E+00 Moles total = 0.5543E+02 kg total = 0.9985E+00 Activity = 1.0000 Stoichiometric ionic strength = .4186455E-02 Osmotic coef. = 0.9652 True ionic strength = .7123021E-02 Chg. balance for total moles = -.9370E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.18254E-09 -9.7386 0.16209E-09 -9.7903 0.88794E+00 -0.0516 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13789E-03 -3.8605 0.12212E-03 -3.9132 0.88568E+00 -0.0527 4 SO4-- 0.25520E-04 -4.5931 0.16655E-04 -4.7785 0.65264E+00 -0.1853 5 HCO3- 0.73691E-05 -5.1326 0.65306E-05 -5.1850 0.88622E+00 -0.0525 6 HS- 0.15363E-12 -12.8135 0.13608E-12 -12.8662 0.88573E+00 -0.0527 7 Al+++ 0.23520E-26 -26.6286 0.91567E-27 -27.0383 0.38931E+00 -0.4097 8 H4SiO4 0.38441E-03 -3.4152 0.38441E-03 -3.4152 0.10000E+01 0.0000 9 Ca++ 0.27655E-07 -7.5582 0.17994E-07 -7.7449 0.65064E+00 -0.1867 10 Mg++ 0.22216E-10 -10.6533 0.14426E-10 -10.8408 0.64938E+00 -0.1875 11 Fe++ 0.13134E-12 -12.8816 0.85331E-13 -13.0689 0.64968E+00 -0.1873 12 K+ 0.55399E-04 -4.2565 0.49101E-04 -4.3089 0.88631E+00 -0.0524 13 Na+ 0.70352E-02 -2.1527 0.62305E-02 -2.2055 0.88562E+00 -0.0528 14 Mn++ 0.17545E-10 -10.7558 0.11403E-10 -10.9430 0.64991E+00 -0.1871 15 HPO4-- 0.11054E-05 -5.9565 0.72146E-06 -6.1418 0.65268E+00 -0.1853 16 HSiO3- 0.26126E-02 -2.5829 0.23139E-02 -2.6357 0.88568E+00 -0.0527 17 Ca(HSiO3)+ 0.10524E-08 -8.9778 0.93285E-09 -9.0302 0.88639E+00 -0.0524 18 Mg(HSiO3)+ 0.10501E-11 -11.9788 0.93079E-12 -12.0311 0.88639E+00 -0.0524 19 NaHSiO3,aq 0.22897E-03 -3.6402 0.22897E-03 -3.6402 0.10000E+01 0.0000 20 AlO+ 0.50761E-14 -14.2945 0.44994E-14 -14.3468 0.88639E+00 -0.0524 22 HAlO2,aq 0.55549E-08 -8.2553 0.55549E-08 -8.2553 0.10000E+01 0.0000 23 AlO2- 0.86467E-04 -4.0631 0.76523E-04 -4.1162 0.88500E+00 -0.0531 24 CH4,aq 0.52425E-19 -19.2805 0.52357E-19 -19.2810 0.99871E+00 -0.0006 29 CO,aq 0.55156E-19 -19.2584 0.55156E-19 -19.2584 0.10000E+01 0.0000 30 CO2,aq 0.21370E-08 -8.6702 0.21342E-08 -8.6708 0.99871E+00 -0.0006 31 CO3-2 0.57131E-05 -5.2431 0.37253E-05 -5.4288 0.65205E+00 -0.1857 32 CaCO3,aq 0.82096E-09 -9.0857 0.82096E-09 -9.0857 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.33404E-11 -11.4762 0.29609E-11 -11.5286 0.88639E+00 -0.0524 34 CaCl+ 0.39503E-11 -11.4034 0.35015E-11 -11.4557 0.88639E+00 -0.0524 35 CaCl2,aq 0.99564E-16 -16.0019 0.99564E-16 -16.0019 0.10000E+01 0.0000 36 CaOH+ 0.88310E-08 -8.0540 0.78277E-08 -8.1064 0.88639E+00 -0.0524 37 CaSO4,aq 0.93375E-10 -10.0298 0.93375E-10 -10.0298 0.10000E+01 0.0000 38 HCl,aq 0.37233E-14 -14.4291 0.37233E-14 -14.4291 0.10000E+01 0.0000 43 FeCl+ 0.18311E-16 -16.7373 0.16231E-16 -16.7897 0.88639E+00 -0.0524 46 FeO,aq 0.12844E-09 -9.8913 0.12844E-09 -9.8913 0.10000E+01 0.0000 47 FeOH+ 0.19690E-10 -10.7057 0.17453E-10 -10.7581 0.88639E+00 -0.0524 48 HFeO2- 0.96233E-08 -8.0167 0.85231E-08 -8.0694 0.88568E+00 -0.0527 49 FeO+ 0.15127E-14 -14.8203 0.13408E-14 -14.8726 0.88639E+00 -0.0524 51 FeO2- 0.11325E-07 -7.9460 0.10030E-07 -7.9987 0.88568E+00 -0.0527 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.10047E-08 -8.9980 0.10034E-08 -8.9985 0.99871E+00 -0.0006 54 KCl,aq 0.10617E-09 -9.9740 0.10617E-09 -9.9740 0.10000E+01 0.0000 55 KHSO4,aq 0.35470E-18 -18.4501 0.35470E-18 -18.4501 0.10000E+01 0.0000 56 KOH,aq 0.13206E-06 -6.8792 0.13206E-06 -6.8792 0.10000E+01 0.0000 57 KSO4- 0.14225E-07 -7.8469 0.12599E-07 -7.8997 0.88568E+00 -0.0527 58 MgCO3,aq 0.16447E-12 -12.7839 0.16447E-12 -12.7839 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27310E-14 -14.5637 0.24207E-14 -14.6161 0.88639E+00 -0.0524 60 MgCl+ 0.28752E-14 -14.5413 0.25486E-14 -14.5937 0.88639E+00 -0.0524 61 MgOH+ 0.39225E-10 -10.4064 0.34769E-10 -10.4588 0.88639E+00 -0.0524 63 MnO,aq 0.45817E-09 -9.3390 0.45817E-09 -9.3390 0.10000E+01 0.0000 64 MnOH+ 0.24443E-09 -9.6118 0.21666E-09 -9.6642 0.88639E+00 -0.0524 65 MnO2-2 0.92495E-12 -12.0339 0.60312E-12 -12.2196 0.65205E+00 -0.1857 66 HMnO2- 0.23914E-10 -10.6213 0.21180E-10 -10.6741 0.88568E+00 -0.0527 69 MnCl+ 0.95081E-14 -14.0219 0.84279E-14 -14.0743 0.88639E+00 -0.0524 70 MnSO4,aq 0.53822E-13 -13.2690 0.53822E-13 -13.2690 0.10000E+01 0.0000 71 NaCl,aq 0.24845E-06 -6.6048 0.24845E-06 -6.6048 0.10000E+01 0.0000 72 NaOH,aq 0.16890E-04 -4.7724 0.16890E-04 -4.7724 0.10000E+01 0.0000 74 OH- 0.41816E-02 -2.3787 0.37007E-02 -2.4317 0.88500E+00 -0.0531 79 HPO3-2 0.35067E-17 -17.4551 0.22866E-17 -17.6408 0.65205E+00 -0.1857 82 H3PO4,aq 0.12203E-15 -15.9135 0.12203E-15 -15.9135 0.10000E+01 0.0000 83 H2PO4- 0.23139E-08 -8.6357 0.20502E-08 -8.6882 0.88603E+00 -0.0526 84 PO4-3 0.97798E-08 -8.0097 0.38872E-08 -8.4104 0.39747E+00 -0.4007 87 H2P2O7-2 0.50451E-18 -18.2971 0.32897E-18 -18.4828 0.65205E+00 -0.1857 88 HP2O7-3 0.10687E-14 -14.9712 0.41617E-15 -15.3807 0.38943E+00 -0.4096 89 P2O7-4 0.33034E-14 -14.4810 0.63342E-15 -15.1983 0.19175E+00 -0.7173 90 H2S,aq 0.66356E-16 -16.1781 0.66270E-16 -16.1787 0.99871E+00 -0.0006 97 SO3-2 0.34734E-14 -14.4592 0.22787E-14 -14.6423 0.65604E+00 -0.1831 98 HSO3- 0.24405E-16 -16.6125 0.21615E-16 -16.6652 0.88568E+00 -0.0527 99 HSO4- 0.28247E-11 -11.5490 0.25048E-11 -11.6012 0.88675E+00 -0.0522 Charge balance for all species = -.9321E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1825433E-09 -.7391833E-02 -.7446740E+01 0.0000 2 H2O 0.1000000E+01 0.5550978E+02 0.9995175E+06 0.0000 3 Cl- 0.1378852E-03 0.1381338E-03 0.4894770E+01 5.8770 4 SO4-- 0.2551965E-04 0.2553516E-04 0.2451703E+01 14.8021 5 HCO3- 0.7369053E-05 0.1308512E-04 0.7980119E+00 4.6052 6 HS- 0.1536336E-12 -.1189753E-08 -.3932753E-04 -3.0760 7 Al+++ 0.2352019E-26 0.8647257E-04 0.2331975E+01 2.3325 8 H4SiO4 0.3844063E-03 0.3225955E-02 0.3099065E+03 -3.4152 9 Ca++ 0.2765524E-07 0.3846028E-07 0.1540628E-02 11.8356 10 Mg++ 0.2221560E-10 0.6266115E-10 0.1522644E-05 8.7397 11 Fe++ 0.1313433E-12 0.2130027E-07 0.1188952E-02 6.5116 12 K+ 0.5539878E-04 0.5554517E-04 0.2170824E+01 5.4813 13 Na+ 0.7035161E-02 0.7281272E-02 0.1673100E+03 7.5848 14 Mn++ 0.1754519E-10 0.7450501E-09 0.4091077E-04 8.6375 15 HPO4-- 0.1105382E-05 0.1117476E-05 0.1071997E+00 13.4387 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1092566E+00 -.7383291E-02 -.1018733E+00 0.0000000E+00 2 H2O 0.5542553E+02 0.5544564E+02 -.2010816E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2083853E-03 0.2550566E-04 0.1828796E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1828808E-03 -.1188378E-08 -.1828796E-03 0.0000000E+00 7 Al+++ 0.2151763E-01 0.8637265E-04 0.2143126E-01 0.0000000E+00 8 H4SiO4 0.6871395E-01 0.3222227E-02 0.6549173E-01 0.0000000E+00 9 Ca++ 0.7604262E-02 0.3841584E-07 0.7604224E-02 0.0000000E+00 10 Mg++ 0.5237302E-02 0.6258874E-10 0.5237302E-02 0.0000000E+00 11 Fe++ 0.4705144E-02 0.2127565E-07 0.4705122E-02 0.0000000E+00 12 K+ 0.1401062E-02 0.5548098E-04 0.1345581E-02 0.0000000E+00 13 Na+ 0.8443424E-02 0.7272858E-02 0.1170566E-02 0.0000000E+00 14 Mn++ 0.1144174E-03 0.7441892E-09 0.1144167E-03 0.0000000E+00 15 HPO4-- 0.3905009E-04 0.1116184E-05 0.3793390E-04 0.0000000E+00 Chg. balance for solid moles: -.4106E-17 Mass of aqueous solution: 0.999352E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 6.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9728E-03 -3.012 0.2551 -0.593 3.541 0.9792E-01 apatite-OH 0.1264E-04 -4.898 0.6352E-02 -2.197 0.8817E-01 0.2018E-02 clinochlore 0.1047E-02 -2.980 0.5822 -0.235 8.082 0.2215 daphnite 0.6484E-03 -3.188 0.4627 -0.335 6.422 0.1402 chlorite-Mn 0.2288E-04 -4.640 0.1622E-01 -1.790 0.2252 0.5170E-02 hematite 0.7315E-03 -3.136 0.1168 -0.932 1.622 0.2214E-01 microcline 0.1346E-02 -2.871 0.3745 -0.427 5.199 0.1463 paragonite 0.1978E-03 -3.704 0.7560E-01 -1.121 1.049 0.2613E-01 stilbite 0.7541E-02 -2.123 5.314 0.725 73.77 2.479 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.203761 g Volume = 3.140018 cm3 Porosity: 13.7263% V(tot) - V(min): 0.49958E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6.5990000 g log = 0.8195 Original solution: 1000.0103000 g Original solution / Rock added: 151.54 (Water/Rock Ratio), log = 2.1805 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2305E-06 1.0073 0.2443E-06 0.2425E-06 CH4,gas 0.7770E-16 1.0129 0.8280E-16 0.8174E-16 H2,gas 0.1308E-05 1.0006 0.1376E-05 0.1376E-05 H2S,gas 0.1845E-14 0.9959 0.1933E-14 0.1941E-14 S2,gas 0.7022E-37 1.0000 0.7387E-37 0.7387E-37 CO,gas 0.8279E-16 1.0000 0.8709E-16 0.8709E-16 SO3,gas 0.1555E-39 1.0000 0.1636E-39 0.1636E-39 SO2,gas 0.8097E-23 1.0000 0.8517E-23 0.8517E-23 HCl,gas 0.6250E-17 1.0000 0.6574E-17 0.6574E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.28814E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.98 -8.61 -2.871 0.14705E+05 -6.612 3 CH4,gas 4.81 -13.27 -18.08 -4.520 0.30875E+05 -16.082 4 H2,gas 8.29 0.43 -7.86 -4.492 0.13423E+05 -5.861 5 H2S,gas -5.94 -22.66 -16.71 -8.357 0.28538E+05 -14.714 6 S2,gas -7.03 -46.16 -39.13 -6.020 0.66816E+05 -37.132 7 CO,gas 3.51 -14.55 -18.06 -5.557 0.30837E+05 -16.060 8 SO3,gas 17.43 -24.36 -41.79 -10.447 0.71349E+05 -39.786 9 SO2,gas 1.14 -23.93 -25.07 -6.685 0.42806E+05 -23.070 10 HCl,gas 5.48 -13.70 -19.18 -9.591 0.32753E+05 -17.182 11 acmite 7.74 7.05 -0.68 -0.071 0.11683E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.33 -4.22 -0.211 0.72021E+04 20 analcite 3.37 3.09 -0.28 -0.032 0.48456E+03 21 andalusite 5.06 1.25 -3.81 -0.381 0.65099E+04 22 andradite 39.09 37.86 -1.23 -0.064 0.20983E+04 23 grossular 32.83 29.93 -2.90 -0.145 0.49550E+04 26 annite 20.21 17.10 -3.11 -0.173 0.53039E+04 27 phlogopite 27.15 23.79 -3.36 -0.187 0.57361E+04 29 anorthite 12.80 9.67 -3.13 -0.241 0.53401E+04 35 aragonite 0.99 -3.14 -4.13 -1.375 0.70449E+04 36 brucite 12.58 8.74 -3.84 -0.767 0.65515E+04 37 calcite 0.83 -3.14 -3.97 -1.324 0.67835E+04 38 carnegieite-low 9.06 6.50 -2.56 -0.366 0.43754E+04 39 carnegieite-high 10.13 6.50 -3.63 -0.519 0.62022E+04 40 carpholite-Mg 8.65 6.57 -2.08 -0.138 0.35450E+04 41 carpholite-Fe 6.78 4.35 -2.44 -0.162 0.41606E+04 42 celadonite 5.40 2.89 -2.51 -0.148 0.42821E+04 43 celadonite-Fe 3.94 0.66 -3.27 -0.192 0.55874E+04 44 chrysotile 23.94 19.39 -4.55 -0.379 0.77669E+04 50 chloritoid-Mg 13.26 9.99 -3.27 -0.218 0.55865E+04 51 chloritoid-Fe 9.24 7.76 -1.48 -0.098 0.25224E+04 52 chloritoid-Mn 11.46 9.89 -1.58 -0.105 0.26908E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17858E+04 59 corundum 8.43 4.66 -3.77 -0.343 0.64345E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14787E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.33 -0.56 -0.094 0.96232E+03 67 diopside 16.22 13.74 -2.47 -0.247 0.42185E+04 68 hedenbergite 14.24 11.52 -2.73 -0.273 0.46573E+04 75 epidote 24.78 24.39 -0.39 -0.019 0.65873E+03 76 clinozoisite 22.92 20.42 -2.50 -0.114 0.42654E+04 77 epidote-Fe 29.94 28.36 -1.58 -0.082 0.26996E+04 78 fayalite 14.08 9.61 -4.47 -0.639 0.76340E+04 79 ferrosilite 11.19 6.19 -4.99 -0.499 0.85286E+04 83 gibbsite 4.10 2.33 -1.76 -0.252 0.30135E+04 84 glaucophane 23.11 18.73 -4.38 -0.118 0.74765E+04 87 greenalite 16.19 12.70 -3.49 -0.291 0.59587E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.09 -1.16 -0.116 0.19876E+04 97 kalsilite 7.62 4.40 -3.22 -0.460 0.55008E+04 98 kaolinite -1.27 -2.17 -0.89 -0.081 0.15236E+04 99 kyanite 4.93 1.25 -3.68 -0.368 0.62867E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.23012E+03 102 lawsonite 9.68 9.67 -0.01 -0.001 0.13971E+02 103 leucite 4.17 0.98 -3.18 -0.318 0.54370E+04 105 lizardite 23.29 19.39 -3.90 -0.325 0.66572E+04 107 magnetite 20.13 19.11 -1.02 -0.084 0.17477E+04 108 minnesotaite 10.46 5.87 -4.59 -0.270 0.78317E+04 110 magnesioferrite 26.26 21.34 -4.92 -0.402 0.84007E+04 113 margarite 17.45 14.34 -3.12 -0.125 0.53215E+04 120 muscovite 2.68 2.23 -0.45 -0.026 0.76153E+03 122 nepheline 8.38 6.50 -1.88 -0.268 0.32033E+04 134 phlogopite-Na 29.73 25.89 -3.84 -0.213 0.65580E+04 136 prehnite 19.47 18.09 -1.38 -0.081 0.23490E+04 137 prehnite-Fe 22.59 22.06 -0.53 -0.032 0.90470E+03 138 pumpellyite-Fe 46.47 45.03 -1.45 -0.032 0.24677E+04 139 pumpellyite-Mg 49.19 47.25 -1.94 -0.043 0.33137E+04 145 pyroxmangite 7.42 5.22 -2.19 -0.439 0.37457E+04 146 pyrophyllite -6.10 -9.00 -2.90 -0.181 0.49480E+04 147 quartz -2.98 -3.42 -0.43 -0.144 0.73970E+03 152 rhodonite 7.46 5.22 -2.24 -0.448 0.38250E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.25 -4.07 -0.407 0.69521E+04 164 stilpnomelane-Fe 13.18 12.64 -0.54 -0.016 0.91742E+03 165 stilpnomelane-Mg 27.60 23.78 -3.81 -0.114 0.65122E+04 168 sudoite 21.22 16.56 -4.65 -0.150 0.79440E+04 171 talc 16.55 12.56 -4.00 -0.235 0.68217E+04 174 tephroite 18.11 13.86 -4.25 -0.608 0.72620E+04 177 topaz-H 4.67 1.25 -3.42 -0.311 0.58358E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13670E+04 187 wairakite 4.06 2.84 -1.22 -0.072 0.20809E+04 188 walstromite 11.53 8.42 -3.11 -0.621 0.53059E+04 189 wollastonite 10.48 8.42 -2.06 -0.412 0.35198E+04 190 pseudo-wollastonite 11.02 8.42 -2.60 -0.520 0.44384E+04 191 zoisite 22.96 20.42 -2.54 -0.115 0.43379E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.15 -3.59 -0.222 0.61239E+04 194 beidellite-H -2.24 -7.10 -4.86 -0.310 0.82949E+04 195 beidellite-K -1.44 -5.29 -3.86 -0.236 0.65827E+04 196 beidellite-Mg -1.71 -5.66 -3.95 -0.244 0.67448E+04 197 beidellite-Na -1.26 -4.60 -3.34 -0.204 0.57014E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10600E+04 201 montmorillonite-Ca -2.21 -4.93 -2.71 -0.168 0.46351E+04 202 montmorillonite-K -2.16 -5.07 -2.91 -0.178 0.49716E+04 203 montmorillonite-Mg -2.40 -5.44 -3.04 -0.188 0.51870E+04 204 montmorillonite-Na -1.96 -4.38 -2.42 -0.148 0.41285E+04 205 nontronite-Ca 3.28 2.79 -0.49 -0.032 0.84222E+03 206 nontronite-H 2.60 0.83 -1.76 -0.118 0.30089E+04 207 nontronite-K 3.40 2.64 -0.76 -0.049 0.13002E+04 208 nontronite-Mg 3.14 2.28 -0.86 -0.056 0.14747E+04 209 nontronite-Na 3.58 3.34 -0.25 -0.016 0.42058E+03 224 tobermorite 9.84 6.44 -3.40 -0.926 0.57971E+04 233 boehmite 4.43 2.33 -2.10 -0.350 0.35808E+04 235 ferrous-oxide 9.82 6.51 -3.31 -0.828 0.56562E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.445 0.22802E+04 242 an20ab80 2.08 1.67 -0.41 -0.031 0.69641E+03 243 an25ab75 2.71 2.17 -0.54 -0.041 0.91841E+03 244 an30ab70 3.34 2.67 -0.67 -0.052 0.11488E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 6.5990000 g New total amount of reactant added: 6.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.9368E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 6.7990000 Water: Moles liquid = 0.5544E+02 kg liquid = 0.9988E+00 Moles total = 0.5542E+02 kg total = 0.9985E+00 Activity = 1.0000 Stoichiometric ionic strength = .4298102E-02 Osmotic coef. = 0.9648 True ionic strength = .7309923E-02 Chg. balance for total moles = -.9368E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.17684E-09 -9.7524 0.15684E-09 -9.8045 0.88692E+00 -0.0521 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13788E-03 -3.8605 0.12197E-03 -3.9137 0.88461E+00 -0.0532 4 SO4-- 0.25520E-04 -4.5931 0.16577E-04 -4.7805 0.64958E+00 -0.1874 5 HCO3- 0.72519E-05 -5.1395 0.64191E-05 -5.1925 0.88517E+00 -0.0530 6 HS- 0.16248E-12 -12.7892 0.14374E-12 -12.8424 0.88467E+00 -0.0532 7 Al+++ 0.21540E-26 -26.6668 0.82965E-27 -27.0811 0.38517E+00 -0.4144 8 H4SiO4 0.37708E-03 -3.4236 0.37708E-03 -3.4236 0.10000E+01 0.0000 9 Ca++ 0.29769E-07 -7.5262 0.19276E-07 -7.7150 0.64754E+00 -0.1887 10 Mg++ 0.21145E-10 -10.6748 0.13665E-10 -10.8644 0.64627E+00 -0.1896 11 Fe++ 0.12501E-12 -12.9031 0.80828E-13 -13.0924 0.64657E+00 -0.1894 12 K+ 0.56858E-04 -4.2452 0.50335E-04 -4.2981 0.88526E+00 -0.0529 13 Na+ 0.72206E-02 -2.1414 0.63870E-02 -2.1947 0.88455E+00 -0.0533 14 Mn++ 0.16699E-10 -10.7773 0.10801E-10 -10.9665 0.64680E+00 -0.1892 15 HPO4-- 0.94768E-06 -6.0233 0.61563E-06 -6.2107 0.64962E+00 -0.1873 16 HSiO3- 0.26517E-02 -2.5765 0.23457E-02 -2.6297 0.88461E+00 -0.0532 17 Ca(HSiO3)+ 0.11443E-08 -8.9415 0.10131E-08 -8.9944 0.88534E+00 -0.0529 18 Mg(HSiO3)+ 0.10095E-11 -11.9959 0.89378E-12 -12.0488 0.88534E+00 -0.0529 19 NaHSiO3,aq 0.23795E-03 -3.6235 0.23795E-03 -3.6235 0.10000E+01 0.0000 20 AlO+ 0.49177E-14 -14.3082 0.43539E-14 -14.3611 0.88534E+00 -0.0529 22 HAlO2,aq 0.55549E-08 -8.2553 0.55549E-08 -8.2553 0.10000E+01 0.0000 23 AlO2- 0.89466E-04 -4.0483 0.79081E-04 -4.1019 0.88392E+00 -0.0536 24 CH4,aq 0.54687E-19 -19.2621 0.54615E-19 -19.2627 0.99867E+00 -0.0006 29 CO,aq 0.53685E-19 -19.2701 0.53685E-19 -19.2701 0.10000E+01 0.0000 30 CO2,aq 0.20326E-08 -8.6919 0.20299E-08 -8.6925 0.99867E+00 -0.0006 31 CO3-2 0.58308E-05 -5.2343 0.37841E-05 -5.4220 0.64898E+00 -0.1878 32 CaCO3,aq 0.89338E-09 -9.0490 0.89338E-09 -9.0490 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.35216E-11 -11.4533 0.31178E-11 -11.5061 0.88534E+00 -0.0529 34 CaCl+ 0.42319E-11 -11.3735 0.37467E-11 -11.4264 0.88534E+00 -0.0529 35 CaCl2,aq 0.10640E-15 -15.9730 0.10640E-15 -15.9730 0.10000E+01 0.0000 36 CaOH+ 0.97885E-08 -8.0093 0.86662E-08 -8.0622 0.88534E+00 -0.0529 37 CaSO4,aq 0.99566E-10 -10.0019 0.99566E-10 -10.0019 0.10000E+01 0.0000 38 HCl,aq 0.35985E-14 -14.4439 0.35985E-14 -14.4439 0.10000E+01 0.0000 43 FeCl+ 0.17344E-16 -16.7609 0.15355E-16 -16.8137 0.88534E+00 -0.0529 46 FeO,aq 0.12993E-09 -9.8863 0.12993E-09 -9.8863 0.10000E+01 0.0000 47 FeOH+ 0.19297E-10 -10.7145 0.17085E-10 -10.7674 0.88534E+00 -0.0529 48 HFeO2- 0.10073E-07 -7.9969 0.89103E-08 -8.0501 0.88461E+00 -0.0532 49 FeO+ 0.14655E-14 -14.8340 0.12974E-14 -14.8869 0.88534E+00 -0.0529 51 FeO2- 0.11718E-07 -7.9312 0.10366E-07 -7.9844 0.88461E+00 -0.0532 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.10282E-08 -8.9879 0.10269E-08 -8.9885 0.99867E+00 -0.0006 54 KCl,aq 0.10871E-09 -9.9637 0.10871E-09 -9.9637 0.10000E+01 0.0000 55 KHSO4,aq 0.35021E-18 -18.4557 0.35021E-18 -18.4557 0.10000E+01 0.0000 56 KOH,aq 0.13990E-06 -6.8542 0.13990E-06 -6.8542 0.10000E+01 0.0000 57 KSO4- 0.14532E-07 -7.8377 0.12855E-07 -7.8909 0.88461E+00 -0.0532 58 MgCO3,aq 0.15825E-12 -12.8006 0.15825E-12 -12.8006 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.25457E-14 -14.5942 0.22538E-14 -14.6471 0.88534E+00 -0.0529 60 MgCl+ 0.27234E-14 -14.5649 0.24112E-14 -14.6178 0.88534E+00 -0.0529 61 MgOH+ 0.38443E-10 -10.4152 0.34035E-10 -10.4681 0.88534E+00 -0.0529 63 MnO,aq 0.46349E-09 -9.3340 0.46349E-09 -9.3340 0.10000E+01 0.0000 64 MnOH+ 0.23955E-09 -9.6206 0.21209E-09 -9.6735 0.88534E+00 -0.0529 65 MnO2-2 0.10040E-11 -11.9983 0.65159E-12 -12.1860 0.64898E+00 -0.1878 66 HMnO2- 0.25031E-10 -10.6015 0.22142E-10 -10.6548 0.88461E+00 -0.0532 69 MnCl+ 0.90060E-14 -14.0455 0.79734E-14 -14.0984 0.88534E+00 -0.0529 70 MnSO4,aq 0.50744E-13 -13.2946 0.50744E-13 -13.2946 0.10000E+01 0.0000 71 NaCl,aq 0.25438E-06 -6.5945 0.25438E-06 -6.5945 0.10000E+01 0.0000 72 NaOH,aq 0.17894E-04 -4.7473 0.17894E-04 -4.7473 0.10000E+01 0.0000 74 OH- 0.43266E-02 -2.3638 0.38244E-02 -2.4174 0.88392E+00 -0.0536 79 HPO3-2 0.30767E-17 -17.5119 0.19967E-17 -17.6997 0.64898E+00 -0.1878 82 H3PO4,aq 0.97500E-16 -16.0110 0.97500E-16 -16.0110 0.10000E+01 0.0000 83 H2PO4- 0.19129E-08 -8.7183 0.16929E-08 -8.7714 0.88497E+00 -0.0531 84 PO4-3 0.87129E-08 -8.0598 0.34279E-08 -8.4650 0.39342E+00 -0.4051 87 H2P2O7-2 0.34560E-18 -18.4614 0.22429E-18 -18.6492 0.64898E+00 -0.1878 88 HP2O7-3 0.76107E-15 -15.1186 0.29323E-15 -15.5328 0.38529E+00 -0.4142 89 P2O7-4 0.24509E-14 -14.6107 0.46122E-15 -15.3361 0.18818E+00 -0.7254 90 H2S,aq 0.67826E-16 -16.1686 0.67736E-16 -16.1692 0.99867E+00 -0.0006 97 SO3-2 0.35542E-14 -14.4493 0.23210E-14 -14.6343 0.65304E+00 -0.1851 98 HSO3- 0.24083E-16 -16.6183 0.21304E-16 -16.6715 0.88461E+00 -0.0532 99 HSO4- 0.27238E-11 -11.5648 0.24125E-11 -11.6175 0.88571E+00 -0.0527 Charge balance for all species = -.9321E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1768409E-09 -.7598084E-02 -.7654446E+01 0.0000 2 H2O 0.1000000E+01 0.5550988E+02 0.9995092E+06 0.0000 3 Cl- 0.1378840E-03 0.1381385E-03 0.4894887E+01 5.8908 4 SO4-- 0.2552021E-04 0.2553607E-04 0.2451765E+01 14.8286 5 HCO3- 0.7251880E-05 0.1308556E-04 0.7980309E+00 4.6120 6 HS- 0.1624763E-12 -.1232953E-08 -.4075511E-04 -3.0379 7 Al+++ 0.2154008E-26 0.8947204E-04 0.2412839E+01 2.3325 8 H4SiO4 0.3770835E-03 0.3266699E-02 0.3138174E+03 -3.4236 9 Ca++ 0.2976864E-07 0.4170210E-07 0.1670471E-02 11.8941 10 Mg++ 0.2114462E-10 0.6076030E-10 0.1476439E-05 8.7447 11 Fe++ 0.1250101E-12 0.2214324E-07 0.1235993E-02 6.5166 12 K+ 0.5685831E-04 0.5701285E-04 0.2228162E+01 5.5064 13 Na+ 0.7220639E-02 0.7476738E-02 0.1717997E+03 7.6098 14 Mn++ 0.1669906E-10 0.7458362E-09 0.4095352E-04 8.6425 15 HPO4-- 0.9476809E-06 0.9583067E-06 0.9192967E-01 13.3984 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1125683E+00 -.7589047E-02 -.1049793E+00 0.0000000E+00 2 H2O 0.5542302E+02 0.5544386E+02 -.2083775E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2139279E-03 0.2550570E-04 0.1884222E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1884235E-03 -.1231487E-08 -.1884222E-03 0.0000000E+00 7 Al+++ 0.2216978E-01 0.8936562E-04 0.2208042E-01 0.0000000E+00 8 H4SiO4 0.7079651E-01 0.3262813E-02 0.6753370E-01 0.0000000E+00 9 Ca++ 0.7834291E-02 0.4165249E-07 0.7834249E-02 0.0000000E+00 10 Mg++ 0.5396032E-02 0.6068803E-10 0.5396032E-02 0.0000000E+00 11 Fe++ 0.4847745E-02 0.2211690E-07 0.4847723E-02 0.0000000E+00 12 K+ 0.1443524E-02 0.5694504E-04 0.1386579E-02 0.0000000E+00 13 Na+ 0.8694472E-02 0.7467845E-02 0.1226628E-02 0.0000000E+00 14 Mn++ 0.1178851E-03 0.7449491E-09 0.1178844E-03 0.0000000E+00 15 HPO4-- 0.4023360E-04 0.9571669E-06 0.3927644E-04 0.0000000E+00 Chg. balance for solid moles: 0.9975E-17 Mass of aqueous solution: 0.999328E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 6.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1033E-02 -2.986 0.2708 -0.567 3.647 0.1039 apatite-OH 0.1309E-04 -4.883 0.6576E-02 -2.182 0.8856E-01 0.2090E-02 clinochlore 0.1079E-02 -2.967 0.5999 -0.222 8.078 0.2282 daphnite 0.6681E-03 -3.175 0.4767 -0.322 6.419 0.1444 chlorite-Mn 0.2358E-04 -4.628 0.1672E-01 -1.777 0.2251 0.5327E-02 hematite 0.7537E-03 -3.123 0.1204 -0.920 1.621 0.2281E-01 microcline 0.1387E-02 -2.858 0.3859 -0.413 5.197 0.1508 paragonite 0.1940E-03 -3.712 0.7413E-01 -1.130 0.9983 0.2562E-01 stilbite 0.7769E-02 -2.110 5.475 0.738 73.73 2.554 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.425864 g Volume = 3.236731 cm3 Porosity: 12.9817% V(tot) - V(min): 0.48287E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6.7990000 g log = 0.8324 Original solution: 1000.0103000 g Original solution / Rock added: 147.08 (Water/Rock Ratio), log = 2.1676 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2193E-06 1.0073 0.2324E-06 0.2307E-06 CH4,gas 0.8106E-16 1.0129 0.8637E-16 0.8527E-16 H2,gas 0.1338E-05 1.0006 0.1408E-05 0.1408E-05 H2S,gas 0.1886E-14 0.9959 0.1976E-14 0.1984E-14 S2,gas 0.7006E-37 1.0000 0.7369E-37 0.7369E-37 CO,gas 0.8058E-16 1.0000 0.8477E-16 0.8477E-16 SO3,gas 0.1449E-39 1.0000 0.1525E-39 0.1525E-39 SO2,gas 0.7722E-23 1.0000 0.8123E-23 0.8123E-23 HCl,gas 0.6040E-17 1.0000 0.6354E-17 0.6354E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.28814E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 102 lawsonite 9.68 9.71 0.03 0.002 -0.57341E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.00 -8.63 -2.878 0.14742E+05 -6.634 3 CH4,gas 4.81 -13.25 -18.06 -4.516 0.30843E+05 -16.064 4 H2,gas 8.29 0.44 -7.85 -4.486 0.13406E+05 -5.851 5 H2S,gas -5.94 -22.65 -16.70 -8.352 0.28522E+05 -14.704 6 S2,gas -7.03 -46.17 -39.13 -6.020 0.66818E+05 -37.133 7 CO,gas 3.51 -14.56 -18.07 -5.561 0.30857E+05 -16.072 8 SO3,gas 17.43 -24.39 -41.82 -10.454 0.71401E+05 -39.817 9 SO2,gas 1.14 -23.95 -25.09 -6.691 0.42841E+05 -23.090 10 HCl,gas 5.48 -13.72 -19.20 -9.598 0.32778E+05 -17.197 11 acmite 7.74 7.06 -0.68 -0.070 0.11540E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.32 -4.23 -0.211 0.72192E+04 20 analcite 3.37 3.10 -0.28 -0.031 0.47030E+03 21 andalusite 5.06 1.24 -3.82 -0.382 0.65242E+04 22 andradite 39.09 38.01 -1.08 -0.056 0.18416E+04 23 grossular 32.83 30.08 -2.75 -0.138 0.46983E+04 26 annite 20.21 17.12 -3.09 -0.172 0.52782E+04 27 phlogopite 27.15 23.80 -3.34 -0.186 0.57104E+04 29 anorthite 12.80 9.71 -3.09 -0.237 0.52688E+04 35 aragonite 0.99 -3.10 -4.09 -1.363 0.69822E+04 36 brucite 12.58 8.74 -3.83 -0.766 0.65429E+04 37 calcite 0.83 -3.10 -3.94 -1.312 0.67208E+04 38 carnegieite-low 9.06 6.52 -2.55 -0.364 0.43469E+04 39 carnegieite-high 10.13 6.52 -3.62 -0.517 0.61737E+04 40 carpholite-Mg 8.65 6.56 -2.09 -0.139 0.35649E+04 41 carpholite-Fe 6.78 4.33 -2.45 -0.163 0.41806E+04 42 celadonite 5.40 2.89 -2.51 -0.148 0.42878E+04 43 celadonite-Fe 3.94 0.66 -3.28 -0.193 0.55931E+04 44 chrysotile 23.94 19.39 -4.55 -0.379 0.77697E+04 50 chloritoid-Mg 13.26 9.99 -3.28 -0.218 0.55922E+04 51 chloritoid-Fe 9.24 7.76 -1.48 -0.099 0.25281E+04 52 chloritoid-Mn 11.46 9.88 -1.58 -0.105 0.26965E+04 54 coesite -2.37 -3.42 -1.05 -0.351 0.18000E+04 59 corundum 8.43 4.66 -3.77 -0.343 0.64345E+04 61 cristobalite -2.55 -3.42 -0.87 -0.291 0.14929E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.33 -0.56 -0.094 0.96232E+03 67 diopside 16.22 13.79 -2.42 -0.242 0.41386E+04 68 hedenbergite 14.24 11.56 -2.68 -0.268 0.45774E+04 75 epidote 24.78 24.48 -0.29 -0.014 0.50184E+03 76 clinozoisite 22.92 20.51 -2.41 -0.109 0.41085E+04 77 epidote-Fe 29.94 28.45 -1.49 -0.077 0.25427E+04 78 fayalite 14.08 9.61 -4.47 -0.638 0.76312E+04 83 gibbsite 4.10 2.33 -1.76 -0.252 0.30135E+04 84 glaucophane 23.11 18.73 -4.38 -0.118 0.74793E+04 87 greenalite 16.19 12.70 -3.49 -0.291 0.59616E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.10 -1.16 -0.116 0.19733E+04 97 kalsilite 7.62 4.42 -3.20 -0.458 0.54723E+04 98 kaolinite -1.27 -2.18 -0.91 -0.083 0.15521E+04 99 kyanite 4.93 1.24 -3.69 -0.369 0.63009E+04 101 laumontite 2.97 2.86 -0.11 -0.007 0.18733E+03 103 leucite 4.17 0.99 -3.18 -0.318 0.54227E+04 105 lizardite 23.29 19.39 -3.90 -0.325 0.66600E+04 107 magnetite 20.13 19.11 -1.02 -0.083 0.17391E+04 108 minnesotaite 10.46 5.86 -4.61 -0.271 0.78631E+04 110 magnesioferrite 26.26 21.34 -4.91 -0.401 0.83922E+04 113 margarite 17.45 14.38 -3.07 -0.123 0.52502E+04 120 muscovite 2.68 2.23 -0.45 -0.026 0.76153E+03 122 nepheline 8.38 6.52 -1.86 -0.266 0.31748E+04 134 phlogopite-Na 29.73 25.91 -3.83 -0.213 0.65323E+04 136 prehnite 19.47 18.18 -1.28 -0.076 0.21921E+04 137 prehnite-Fe 22.59 22.15 -0.44 -0.026 0.74781E+03 138 pumpellyite-Fe 46.47 45.21 -1.26 -0.028 0.21454E+04 139 pumpellyite-Mg 49.19 47.44 -1.75 -0.039 0.29913E+04 145 pyroxmangite 7.42 5.22 -2.20 -0.439 0.37514E+04 146 pyrophyllite -6.10 -9.03 -2.93 -0.183 0.50050E+04 147 quartz -2.98 -3.42 -0.44 -0.147 0.75396E+03 152 rhodonite 7.46 5.22 -2.24 -0.449 0.38307E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.24 -4.08 -0.408 0.69663E+04 164 stilpnomelane-Fe 13.18 12.61 -0.57 -0.017 0.96734E+03 165 stilpnomelane-Mg 27.60 23.75 -3.84 -0.115 0.65622E+04 168 sudoite 21.22 16.55 -4.67 -0.151 0.79697E+04 171 talc 16.55 12.54 -4.01 -0.236 0.68531E+04 174 tephroite 18.11 13.86 -4.25 -0.607 0.72592E+04 177 topaz-H 4.67 1.24 -3.43 -0.311 0.58500E+04 178 tridymite -2.61 -3.42 -0.81 -0.270 0.13813E+04 187 wairakite 4.06 2.86 -1.19 -0.070 0.20381E+04 188 walstromite 11.53 8.47 -3.06 -0.611 0.52203E+04 189 wollastonite 10.48 8.47 -2.01 -0.402 0.34342E+04 190 pseudo-wollastonite 11.02 8.47 -2.55 -0.510 0.43528E+04 191 zoisite 22.96 20.51 -2.45 -0.111 0.41810E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.17 -3.61 -0.223 0.61598E+04 194 beidellite-H -2.24 -7.13 -4.89 -0.312 0.83472E+04 195 beidellite-K -1.44 -5.31 -3.88 -0.237 0.66209E+04 196 beidellite-Mg -1.71 -5.69 -3.98 -0.246 0.67957E+04 197 beidellite-Na -1.26 -4.62 -3.36 -0.206 0.57397E+04 199 chalcedony -2.79 -3.42 -0.63 -0.210 0.10743E+04 201 montmorillonite-Ca -2.21 -4.95 -2.74 -0.169 0.46728E+04 202 montmorillonite-K -2.16 -5.10 -2.94 -0.180 0.50117E+04 203 montmorillonite-Mg -2.40 -5.47 -3.07 -0.190 0.52398E+04 204 montmorillonite-Na -1.96 -4.40 -2.44 -0.150 0.41686E+04 205 nontronite-Ca 3.28 2.77 -0.51 -0.033 0.87809E+03 206 nontronite-H 2.60 0.80 -1.79 -0.120 0.30613E+04 207 nontronite-K 3.40 2.62 -0.78 -0.050 0.13384E+04 208 nontronite-Mg 3.14 2.25 -0.89 -0.058 0.15256E+04 209 nontronite-Na 3.58 3.31 -0.27 -0.017 0.45881E+03 224 tobermorite 9.84 6.48 -3.35 -0.915 0.57282E+04 233 boehmite 4.43 2.33 -2.10 -0.350 0.35808E+04 235 ferrous-oxide 9.82 6.52 -3.31 -0.827 0.56476E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.448 0.22945E+04 242 an20ab80 2.08 1.68 -0.40 -0.031 0.68215E+03 243 an25ab75 2.71 2.18 -0.53 -0.041 0.90059E+03 244 an30ab70 3.34 2.68 -0.66 -0.051 0.11274E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 6.7990000 Water: Moles liquid = 0.5544E+02 kg liquid = 0.9988E+00 Moles total = 0.5542E+02 kg total = 0.9985E+00 Activity = 1.0000 Stoichiometric ionic strength = .4208065E-02 Osmotic coef. = 0.9651 True ionic strength = .7159216E-02 Chg. balance for total moles = -.9368E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.18141E-09 -9.7413 0.16105E-09 -9.7931 0.88774E+00 -0.0517 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13789E-03 -3.8605 0.12209E-03 -3.9133 0.88547E+00 -0.0528 4 SO4-- 0.25520E-04 -4.5931 0.16640E-04 -4.7788 0.65204E+00 -0.1857 5 HCO3- 0.73463E-05 -5.1339 0.65089E-05 -5.1865 0.88601E+00 -0.0526 6 HS- 0.15533E-12 -12.8087 0.13755E-12 -12.8615 0.88552E+00 -0.0528 7 Al+++ 0.23118E-26 -26.6361 0.89813E-27 -27.0467 0.38850E+00 -0.4106 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.28057E-07 -7.5520 0.18238E-07 -7.7390 0.65003E+00 -0.1871 10 Mg++ 0.22001E-10 -10.6576 0.14274E-10 -10.8455 0.64877E+00 -0.1879 11 Fe++ 0.13008E-12 -12.8858 0.84429E-13 -13.0735 0.64908E+00 -0.1877 12 K+ 0.55681E-04 -4.2543 0.49340E-04 -4.3068 0.88611E+00 -0.0525 13 Na+ 0.70711E-02 -2.1505 0.62608E-02 -2.2034 0.88541E+00 -0.0529 14 Mn++ 0.17376E-10 -10.7601 0.11282E-10 -10.9476 0.64930E+00 -0.1876 15 HPO4-- 0.10725E-05 -5.9696 0.69939E-06 -6.1553 0.65208E+00 -0.1857 16 HSiO3- 0.26202E-02 -2.5817 0.23201E-02 -2.6345 0.88547E+00 -0.0528 17 Ca(HSiO3)+ 0.10698E-08 -8.9707 0.94805E-09 -9.0232 0.88619E+00 -0.0525 18 Mg(HSiO3)+ 0.10420E-11 -11.9821 0.92342E-12 -12.0346 0.88619E+00 -0.0525 19 NaHSiO3,aq 0.23070E-03 -3.6369 0.23070E-03 -3.6369 0.10000E+01 0.0000 20 AlO+ 0.50446E-14 -14.2972 0.44705E-14 -14.3496 0.88619E+00 -0.0525 22 HAlO2,aq 0.55549E-08 -8.2553 0.55549E-08 -8.2553 0.10000E+01 0.0000 23 AlO2- 0.87047E-04 -4.0602 0.77018E-04 -4.1134 0.88479E+00 -0.0532 24 CH4,aq 0.52863E-19 -19.2769 0.52794E-19 -19.2774 0.99870E+00 -0.0006 29 CO,aq 0.54866E-19 -19.2607 0.54866E-19 -19.2607 0.10000E+01 0.0000 30 CO2,aq 0.21162E-08 -8.6744 0.21134E-08 -8.6750 0.99870E+00 -0.0006 31 CO3-2 0.57362E-05 -5.2414 0.37369E-05 -5.4275 0.65146E+00 -0.1861 32 CaCO3,aq 0.83471E-09 -9.0785 0.83471E-09 -9.0785 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.33752E-11 -11.4717 0.29911E-11 -11.5242 0.88619E+00 -0.0525 34 CaCl+ 0.40040E-11 -11.3975 0.35483E-11 -11.4500 0.88619E+00 -0.0525 35 CaCl2,aq 0.10087E-15 -15.9962 0.10087E-15 -15.9962 0.10000E+01 0.0000 36 CaOH+ 0.90109E-08 -8.0452 0.79853E-08 -8.0977 0.88619E+00 -0.0525 37 CaSO4,aq 0.94558E-10 -10.0243 0.94558E-10 -10.0243 0.10000E+01 0.0000 38 HCl,aq 0.36985E-14 -14.4320 0.36985E-14 -14.4320 0.10000E+01 0.0000 43 FeCl+ 0.18117E-16 -16.7419 0.16055E-16 -16.7944 0.88619E+00 -0.0525 46 FeO,aq 0.12873E-09 -9.8903 0.12873E-09 -9.8903 0.10000E+01 0.0000 47 FeOH+ 0.19612E-10 -10.7075 0.17380E-10 -10.7599 0.88619E+00 -0.0525 48 HFeO2- 0.97097E-08 -8.0128 0.85977E-08 -8.0656 0.88547E+00 -0.0528 49 FeO+ 0.15033E-14 -14.8230 0.13322E-14 -14.8754 0.88619E+00 -0.0525 51 FeO2- 0.11401E-07 -7.9431 0.10095E-07 -7.9959 0.88547E+00 -0.0528 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.10093E-08 -8.9960 0.10080E-08 -8.9965 0.99870E+00 -0.0006 54 KCl,aq 0.10667E-09 -9.9720 0.10667E-09 -9.9720 0.10000E+01 0.0000 55 KHSO4,aq 0.35382E-18 -18.4512 0.35382E-18 -18.4512 0.10000E+01 0.0000 56 KOH,aq 0.13356E-06 -6.8743 0.13356E-06 -6.8743 0.10000E+01 0.0000 57 KSO4- 0.14285E-07 -7.8451 0.12649E-07 -7.8979 0.88547E+00 -0.0528 58 MgCO3,aq 0.16324E-12 -12.7872 0.16324E-12 -12.7872 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26938E-14 -14.5696 0.23872E-14 -14.6221 0.88619E+00 -0.0525 60 MgCl+ 0.28449E-14 -14.5459 0.25211E-14 -14.5984 0.88619E+00 -0.0525 61 MgOH+ 0.39071E-10 -10.4082 0.34624E-10 -10.4606 0.88619E+00 -0.0525 63 MnO,aq 0.45921E-09 -9.3380 0.45921E-09 -9.3380 0.10000E+01 0.0000 64 MnOH+ 0.24346E-09 -9.6136 0.21576E-09 -9.6660 0.88619E+00 -0.0525 65 MnO2-2 0.93994E-12 -12.0269 0.61233E-12 -12.2130 0.65146E+00 -0.1861 66 HMnO2- 0.24129E-10 -10.6175 0.21366E-10 -10.6703 0.88547E+00 -0.0528 69 MnCl+ 0.94077E-14 -14.0265 0.83370E-14 -14.0790 0.88619E+00 -0.0525 70 MnSO4,aq 0.53206E-13 -13.2740 0.53206E-13 -13.2740 0.10000E+01 0.0000 71 NaCl,aq 0.24960E-06 -6.6028 0.24960E-06 -6.6028 0.10000E+01 0.0000 72 NaOH,aq 0.17082E-04 -4.7675 0.17082E-04 -4.7675 0.10000E+01 0.0000 74 OH- 0.42096E-02 -2.3758 0.37246E-02 -2.4289 0.88479E+00 -0.0532 79 HPO3-2 0.34180E-17 -17.4662 0.22267E-17 -17.6523 0.65146E+00 -0.1861 82 H3PO4,aq 0.11678E-15 -15.9326 0.11678E-15 -15.9326 0.10000E+01 0.0000 83 H2PO4- 0.22292E-08 -8.6518 0.19747E-08 -8.7045 0.88582E+00 -0.0527 84 PO4-3 0.95610E-08 -8.0195 0.37926E-08 -8.4211 0.39668E+00 -0.4016 87 H2P2O7-2 0.46847E-18 -18.3293 0.30519E-18 -18.5154 0.65146E+00 -0.1861 88 HP2O7-3 0.99991E-15 -15.0000 0.38859E-15 -15.4105 0.38862E+00 -0.4105 89 P2O7-4 0.31158E-14 -14.5064 0.59526E-15 -15.2253 0.19105E+00 -0.7189 90 H2S,aq 0.66642E-16 -16.1763 0.66556E-16 -16.1768 0.99870E+00 -0.0006 97 SO3-2 0.34892E-14 -14.4573 0.22870E-14 -14.6407 0.65546E+00 -0.1835 98 HSO3- 0.24342E-16 -16.6136 0.21554E-16 -16.6665 0.88547E+00 -0.0528 99 HSO4- 0.28047E-11 -11.5521 0.24865E-11 -11.6044 0.88655E+00 -0.0523 Charge balance for all species = -.8859E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1814108E-09 -.7431765E-02 -.7486954E+01 0.0000 2 H2O 0.1000000E+01 0.5550980E+02 0.9995159E+06 0.0000 3 Cl- 0.1378873E-03 0.1381370E-03 0.4894875E+01 5.8797 4 SO4-- 0.2552019E-04 0.2553577E-04 0.2451756E+01 14.8073 5 HCO3- 0.7346258E-05 0.1308543E-04 0.7980290E+00 4.6066 6 HS- 0.1553298E-12 -.1198101E-08 -.3960338E-04 -3.0685 7 Al+++ 0.2311786E-26 0.8705246E-04 0.2347608E+01 2.3325 8 H4SiO4 0.3829605E-03 0.3233861E-02 0.3106654E+03 -3.4168 9 Ca++ 0.2805675E-07 0.3907406E-07 0.1565212E-02 11.8471 10 Mg++ 0.2200129E-10 0.6228264E-10 0.1513444E-05 8.7406 11 Fe++ 0.1300759E-12 0.2146283E-07 0.1198023E-02 6.5126 12 K+ 0.5568144E-04 0.5582939E-04 0.2181928E+01 5.4862 13 Na+ 0.7071082E-02 0.7319117E-02 0.1681793E+03 7.5897 14 Mn++ 0.1737587E-10 0.7451823E-09 0.4091795E-04 8.6385 15 HPO4-- 0.1072548E-05 0.1084338E-05 0.1040207E+00 13.4308 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1125683E+00 -.7423004E-02 -.1051453E+00 0.0000000E+00 2 H2O 0.5542302E+02 0.5544436E+02 -.2134134E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2139279E-03 0.2550567E-04 0.1884223E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1884235E-03 -.1196688E-08 -.1884223E-03 0.0000000E+00 7 Al+++ 0.2216978E-01 0.8694984E-04 0.2208283E-01 0.0000000E+00 8 H4SiO4 0.7079651E-01 0.3230049E-02 0.6756646E-01 0.0000000E+00 9 Ca++ 0.7834291E-02 0.3902800E-07 0.7834252E-02 0.0000000E+00 10 Mg++ 0.5396032E-02 0.6220922E-10 0.5396032E-02 0.0000000E+00 11 Fe++ 0.4847745E-02 0.2143753E-07 0.4847724E-02 0.0000000E+00 12 K+ 0.1443524E-02 0.5576358E-04 0.1387761E-02 0.0000000E+00 13 Na+ 0.8694472E-02 0.7310489E-02 0.1383983E-02 0.0000000E+00 14 Mn++ 0.1178851E-03 0.7443038E-09 0.1178844E-03 0.0000000E+00 15 HPO4-- 0.4023360E-04 0.1083060E-05 0.3915054E-04 0.0000000E+00 Chg. balance for solid moles: -.1927E-16 Mass of aqueous solution: 0.999331E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 6.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1268E-02 -2.897 0.3326 -0.478 4.480 0.1277 apatite-OH 0.1305E-04 -4.884 0.6555E-02 -2.183 0.8831E-01 0.2083E-02 clinochlore 0.1079E-02 -2.967 0.5999 -0.222 8.081 0.2282 daphnite 0.6681E-03 -3.175 0.4767 -0.322 6.421 0.1444 chlorite-Mn 0.2358E-04 -4.628 0.1672E-01 -1.777 0.2252 0.5327E-02 hematite 0.7537E-03 -3.123 0.1204 -0.920 1.621 0.2281E-01 microcline 0.1388E-02 -2.858 0.3863 -0.413 5.203 0.1509 paragonite 0.1157E-03 -3.937 0.4422E-01 -1.354 0.5956 0.1528E-01 stilbite 0.7680E-02 -2.115 5.412 0.733 72.91 2.524 lawsonite 0.8887E-04 -4.051 0.2793E-01 -1.554 0.3762 0.9005E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.423492 g Volume = 3.230095 cm3 Porosity: 13.1601% V(tot) - V(min): 0.48950E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6.7990000 g log = 0.8324 Original solution: 1000.0103000 g Original solution / Rock added: 147.08 (Water/Rock Ratio), log = 2.1676 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2283E-06 1.0073 0.2419E-06 0.2402E-06 CH4,gas 0.7835E-16 1.0129 0.8349E-16 0.8242E-16 H2,gas 0.1314E-05 1.0006 0.1383E-05 0.1382E-05 H2S,gas 0.1853E-14 0.9959 0.1941E-14 0.1949E-14 S2,gas 0.7019E-37 1.0000 0.7384E-37 0.7384E-37 CO,gas 0.8236E-16 1.0000 0.8663E-16 0.8663E-16 SO3,gas 0.1534E-39 1.0000 0.1613E-39 0.1613E-39 SO2,gas 0.8022E-23 1.0000 0.8438E-23 0.8438E-23 HCl,gas 0.6208E-17 1.0000 0.6531E-17 0.6531E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 0.19715E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.98 -8.62 -2.872 0.14712E+05 -6.616 3 CH4,gas 4.81 -13.27 -18.08 -4.520 0.30868E+05 -16.078 4 H2,gas 8.29 0.43 -7.86 -4.491 0.13420E+05 -5.859 5 H2S,gas -5.94 -22.65 -16.71 -8.356 0.28535E+05 -14.712 6 S2,gas -7.03 -46.16 -39.13 -6.020 0.66816E+05 -37.132 7 CO,gas 3.51 -14.55 -18.06 -5.558 0.30841E+05 -16.062 8 SO3,gas 17.43 -24.36 -41.79 -10.448 0.71359E+05 -39.792 9 SO2,gas 1.14 -23.94 -25.07 -6.686 0.42813E+05 -23.074 10 HCl,gas 5.48 -13.71 -19.19 -9.593 0.32758E+05 -17.185 11 acmite 7.74 7.05 -0.68 -0.071 0.11655E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.33 -4.22 -0.211 0.72055E+04 20 analcite 3.37 3.09 -0.28 -0.031 0.48177E+03 21 andalusite 5.06 1.25 -3.81 -0.381 0.65127E+04 22 andradite 39.09 37.89 -1.20 -0.062 0.20480E+04 23 grossular 32.83 29.96 -2.87 -0.144 0.49047E+04 26 annite 20.21 17.11 -3.10 -0.172 0.52989E+04 27 phlogopite 27.15 23.79 -3.36 -0.186 0.57311E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -3.13 -4.12 -1.373 0.70326E+04 36 brucite 12.58 8.74 -3.84 -0.767 0.65498E+04 37 calcite 0.83 -3.13 -3.97 -1.322 0.67712E+04 38 carnegieite-low 9.06 6.51 -2.56 -0.366 0.43698E+04 39 carnegieite-high 10.13 6.51 -3.63 -0.518 0.61967E+04 40 carpholite-Mg 8.65 6.57 -2.08 -0.139 0.35489E+04 41 carpholite-Fe 6.78 4.34 -2.44 -0.163 0.41645E+04 42 celadonite 5.40 2.89 -2.51 -0.148 0.42832E+04 43 celadonite-Fe 3.94 0.66 -3.27 -0.193 0.55885E+04 44 chrysotile 23.94 19.39 -4.55 -0.379 0.77675E+04 50 chloritoid-Mg 13.26 9.99 -3.27 -0.218 0.55876E+04 51 chloritoid-Fe 9.24 7.76 -1.48 -0.099 0.25235E+04 52 chloritoid-Mn 11.46 9.89 -1.58 -0.105 0.26920E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 4.66 -3.77 -0.343 0.64345E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.33 -0.56 -0.094 0.96232E+03 67 diopside 16.22 13.75 -2.46 -0.246 0.42028E+04 68 hedenbergite 14.24 11.53 -2.72 -0.272 0.46417E+04 75 epidote 24.78 24.41 -0.37 -0.018 0.62799E+03 76 clinozoisite 22.92 20.44 -2.48 -0.113 0.42346E+04 77 epidote-Fe 29.94 28.37 -1.56 -0.081 0.26689E+04 78 fayalite 14.08 9.61 -4.47 -0.639 0.76334E+04 79 ferrosilite 11.19 6.19 -5.00 -0.500 0.85309E+04 83 gibbsite 4.10 2.33 -1.76 -0.252 0.30135E+04 84 glaucophane 23.11 18.73 -4.38 -0.118 0.74770E+04 87 greenalite 16.19 12.70 -3.49 -0.291 0.59593E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.09 -1.16 -0.116 0.19848E+04 97 kalsilite 7.62 4.40 -3.22 -0.460 0.54953E+04 98 kaolinite -1.27 -2.17 -0.90 -0.081 0.15291E+04 99 kyanite 4.93 1.25 -3.68 -0.368 0.62895E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.99 -3.18 -0.318 0.54342E+04 105 lizardite 23.29 19.39 -3.90 -0.325 0.66577E+04 107 magnetite 20.13 19.11 -1.02 -0.083 0.17460E+04 108 minnesotaite 10.46 5.87 -4.59 -0.270 0.78378E+04 110 magnesioferrite 26.26 21.34 -4.92 -0.402 0.83991E+04 113 margarite 17.45 14.34 -3.11 -0.124 0.53076E+04 120 muscovite 2.68 2.23 -0.45 -0.026 0.76153E+03 122 nepheline 8.38 6.51 -1.87 -0.268 0.31977E+04 134 phlogopite-Na 29.73 25.89 -3.84 -0.213 0.65529E+04 136 prehnite 19.47 18.11 -1.36 -0.080 0.23183E+04 137 prehnite-Fe 22.59 22.07 -0.51 -0.031 0.87396E+03 138 pumpellyite-Fe 46.47 45.06 -1.41 -0.031 0.24046E+04 139 pumpellyite-Mg 49.19 47.29 -1.90 -0.042 0.32505E+04 145 pyroxmangite 7.42 5.22 -2.19 -0.439 0.37468E+04 146 pyrophyllite -6.10 -9.00 -2.90 -0.182 0.49591E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodonite 7.46 5.22 -2.24 -0.448 0.38261E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.25 -4.07 -0.407 0.69549E+04 164 stilpnomelane-Fe 13.18 12.64 -0.54 -0.016 0.92720E+03 165 stilpnomelane-Mg 27.60 23.78 -3.82 -0.114 0.65220E+04 168 sudoite 21.22 16.56 -4.66 -0.150 0.79491E+04 171 talc 16.55 12.55 -4.00 -0.235 0.68279E+04 174 tephroite 18.11 13.86 -4.25 -0.608 0.72615E+04 177 topaz-H 4.67 1.25 -3.42 -0.311 0.58386E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 8.43 -3.10 -0.620 0.52891E+04 189 wollastonite 10.48 8.43 -2.05 -0.410 0.35030E+04 190 pseudo-wollastonite 11.02 8.43 -2.59 -0.518 0.44216E+04 191 zoisite 22.96 20.44 -2.52 -0.115 0.43072E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.15 -3.59 -0.222 0.61310E+04 194 beidellite-H -2.24 -7.11 -4.86 -0.310 0.83052E+04 195 beidellite-K -1.44 -5.29 -3.86 -0.236 0.65902E+04 196 beidellite-Mg -1.71 -5.66 -3.96 -0.245 0.67548E+04 197 beidellite-Na -1.26 -4.60 -3.34 -0.205 0.57089E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.93 -2.72 -0.168 0.46425E+04 202 montmorillonite-K -2.16 -5.08 -2.92 -0.179 0.49794E+04 203 montmorillonite-Mg -2.40 -5.45 -3.04 -0.188 0.51973E+04 204 montmorillonite-Na -1.96 -4.38 -2.42 -0.148 0.41363E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.83 -1.77 -0.119 0.30192E+04 207 nontronite-K 3.40 2.64 -0.77 -0.049 0.13076E+04 208 nontronite-Mg 3.14 2.27 -0.87 -0.056 0.14847E+04 209 nontronite-Na 3.58 3.33 -0.25 -0.016 0.42807E+03 224 tobermorite 9.84 6.45 -3.39 -0.924 0.57836E+04 233 boehmite 4.43 2.33 -2.10 -0.350 0.35808E+04 235 ferrous-oxide 9.82 6.51 -3.31 -0.828 0.56545E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 1.67 -0.41 -0.031 0.69361E+03 243 an25ab75 2.71 2.17 -0.54 -0.041 0.91492E+03 244 an30ab70 3.34 2.67 -0.67 -0.052 0.11446E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 6.7990000 g New total amount of reactant added: 6.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.9371E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 6.9990000 Water: Moles liquid = 0.5544E+02 kg liquid = 0.9988E+00 Moles total = 0.5542E+02 kg total = 0.9984E+00 Activity = 1.0000 Stoichiometric ionic strength = .4208069E-02 Osmotic coef. = 0.9651 True ionic strength = .7159218E-02 Chg. balance for total moles = -.9371E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.18141E-09 -9.7413 0.16105E-09 -9.7931 0.88774E+00 -0.0517 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13789E-03 -3.8605 0.12210E-03 -3.9133 0.88547E+00 -0.0528 4 SO4-- 0.25521E-04 -4.5931 0.16641E-04 -4.7788 0.65204E+00 -0.1857 5 HCO3- 0.73464E-05 -5.1339 0.65090E-05 -5.1865 0.88601E+00 -0.0526 6 HS- 0.15533E-12 -12.8087 0.13755E-12 -12.8615 0.88552E+00 -0.0528 7 Al+++ 0.23118E-26 -26.6361 0.89813E-27 -27.0467 0.38850E+00 -0.4106 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.28057E-07 -7.5520 0.18238E-07 -7.7390 0.65003E+00 -0.1871 10 Mg++ 0.22001E-10 -10.6576 0.14274E-10 -10.8455 0.64877E+00 -0.1879 11 Fe++ 0.13008E-12 -12.8858 0.84429E-13 -13.0735 0.64908E+00 -0.1877 12 K+ 0.55681E-04 -4.2543 0.49340E-04 -4.3068 0.88611E+00 -0.0525 13 Na+ 0.70711E-02 -2.1505 0.62608E-02 -2.2034 0.88541E+00 -0.0529 14 Mn++ 0.17376E-10 -10.7601 0.11282E-10 -10.9476 0.64930E+00 -0.1876 15 HPO4-- 0.10725E-05 -5.9696 0.69939E-06 -6.1553 0.65208E+00 -0.1857 16 HSiO3- 0.26202E-02 -2.5817 0.23201E-02 -2.6345 0.88547E+00 -0.0528 17 Ca(HSiO3)+ 0.10698E-08 -8.9707 0.94805E-09 -9.0232 0.88619E+00 -0.0525 18 Mg(HSiO3)+ 0.10420E-11 -11.9821 0.92342E-12 -12.0346 0.88619E+00 -0.0525 19 NaHSiO3,aq 0.23070E-03 -3.6369 0.23070E-03 -3.6369 0.10000E+01 0.0000 20 AlO+ 0.50446E-14 -14.2972 0.44705E-14 -14.3496 0.88619E+00 -0.0525 22 HAlO2,aq 0.55549E-08 -8.2553 0.55549E-08 -8.2553 0.10000E+01 0.0000 23 AlO2- 0.87047E-04 -4.0602 0.77018E-04 -4.1134 0.88479E+00 -0.0532 24 CH4,aq 0.52864E-19 -19.2768 0.52795E-19 -19.2774 0.99870E+00 -0.0006 29 CO,aq 0.54868E-19 -19.2607 0.54868E-19 -19.2607 0.10000E+01 0.0000 30 CO2,aq 0.21162E-08 -8.6744 0.21135E-08 -8.6750 0.99870E+00 -0.0006 31 CO3-2 0.57363E-05 -5.2414 0.37370E-05 -5.4275 0.65146E+00 -0.1861 32 CaCO3,aq 0.83472E-09 -9.0785 0.83472E-09 -9.0785 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.33753E-11 -11.4717 0.29912E-11 -11.5242 0.88619E+00 -0.0525 34 CaCl+ 0.40041E-11 -11.3975 0.35484E-11 -11.4500 0.88619E+00 -0.0525 35 CaCl2,aq 0.10088E-15 -15.9962 0.10088E-15 -15.9962 0.10000E+01 0.0000 36 CaOH+ 0.90109E-08 -8.0452 0.79853E-08 -8.0977 0.88619E+00 -0.0525 37 CaSO4,aq 0.94560E-10 -10.0243 0.94560E-10 -10.0243 0.10000E+01 0.0000 38 HCl,aq 0.36986E-14 -14.4320 0.36986E-14 -14.4320 0.10000E+01 0.0000 43 FeCl+ 0.18118E-16 -16.7419 0.16056E-16 -16.7944 0.88619E+00 -0.0525 46 FeO,aq 0.12873E-09 -9.8903 0.12873E-09 -9.8903 0.10000E+01 0.0000 47 FeOH+ 0.19612E-10 -10.7075 0.17380E-10 -10.7599 0.88619E+00 -0.0525 48 HFeO2- 0.97097E-08 -8.0128 0.85977E-08 -8.0656 0.88547E+00 -0.0528 49 FeO+ 0.15033E-14 -14.8230 0.13322E-14 -14.8754 0.88619E+00 -0.0525 51 FeO2- 0.11401E-07 -7.9431 0.10095E-07 -7.9959 0.88547E+00 -0.0528 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.10093E-08 -8.9960 0.10080E-08 -8.9965 0.99870E+00 -0.0006 54 KCl,aq 0.10667E-09 -9.9720 0.10667E-09 -9.9720 0.10000E+01 0.0000 55 KHSO4,aq 0.35383E-18 -18.4512 0.35383E-18 -18.4512 0.10000E+01 0.0000 56 KOH,aq 0.13356E-06 -6.8743 0.13356E-06 -6.8743 0.10000E+01 0.0000 57 KSO4- 0.14285E-07 -7.8451 0.12649E-07 -7.8979 0.88547E+00 -0.0528 58 MgCO3,aq 0.16325E-12 -12.7872 0.16325E-12 -12.7872 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26938E-14 -14.5696 0.23872E-14 -14.6221 0.88619E+00 -0.0525 60 MgCl+ 0.28449E-14 -14.5459 0.25211E-14 -14.5984 0.88619E+00 -0.0525 61 MgOH+ 0.39071E-10 -10.4082 0.34624E-10 -10.4606 0.88619E+00 -0.0525 63 MnO,aq 0.45921E-09 -9.3380 0.45921E-09 -9.3380 0.10000E+01 0.0000 64 MnOH+ 0.24346E-09 -9.6136 0.21576E-09 -9.6660 0.88619E+00 -0.0525 65 MnO2-2 0.93994E-12 -12.0269 0.61233E-12 -12.2130 0.65146E+00 -0.1861 66 HMnO2- 0.24129E-10 -10.6175 0.21366E-10 -10.6703 0.88547E+00 -0.0528 69 MnCl+ 0.94079E-14 -14.0265 0.83371E-14 -14.0790 0.88619E+00 -0.0525 70 MnSO4,aq 0.53207E-13 -13.2740 0.53207E-13 -13.2740 0.10000E+01 0.0000 71 NaCl,aq 0.24961E-06 -6.6027 0.24961E-06 -6.6027 0.10000E+01 0.0000 72 NaOH,aq 0.17082E-04 -4.7675 0.17082E-04 -4.7675 0.10000E+01 0.0000 74 OH- 0.42096E-02 -2.3758 0.37246E-02 -2.4289 0.88479E+00 -0.0532 79 HPO3-2 0.34180E-17 -17.4662 0.22267E-17 -17.6523 0.65146E+00 -0.1861 82 H3PO4,aq 0.11678E-15 -15.9326 0.11678E-15 -15.9326 0.10000E+01 0.0000 83 H2PO4- 0.22292E-08 -8.6518 0.19747E-08 -8.7045 0.88582E+00 -0.0527 84 PO4-3 0.95610E-08 -8.0195 0.37926E-08 -8.4211 0.39668E+00 -0.4016 87 H2P2O7-2 0.46847E-18 -18.3293 0.30519E-18 -18.5154 0.65146E+00 -0.1861 88 HP2O7-3 0.99991E-15 -15.0000 0.38859E-15 -15.4105 0.38862E+00 -0.4105 89 P2O7-4 0.31158E-14 -14.5064 0.59526E-15 -15.2253 0.19105E+00 -0.7189 90 H2S,aq 0.66644E-16 -16.1762 0.66557E-16 -16.1768 0.99870E+00 -0.0006 97 SO3-2 0.34892E-14 -14.4573 0.22870E-14 -14.6407 0.65546E+00 -0.1835 98 HSO3- 0.24343E-16 -16.6136 0.21555E-16 -16.6665 0.88547E+00 -0.0528 99 HSO4- 0.28048E-11 -11.5521 0.24866E-11 -11.6044 0.88655E+00 -0.0523 Charge balance for all species = -.9436E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1814108E-09 -.7431763E-02 -.7486952E+01 0.0000 2 H2O 0.1000000E+01 0.5550980E+02 0.9995159E+06 0.0000 3 Cl- 0.1378902E-03 0.1381399E-03 0.4894977E+01 5.8798 4 SO4-- 0.2552072E-04 0.2553630E-04 0.2451807E+01 14.8073 5 HCO3- 0.7346412E-05 0.1308570E-04 0.7980456E+00 4.6066 6 HS- 0.1553332E-12 -.1198100E-08 -.3960336E-04 -3.0685 7 Al+++ 0.2311789E-26 0.8705243E-04 0.2347608E+01 2.3325 8 H4SiO4 0.3829605E-03 0.3233861E-02 0.3106653E+03 -3.4168 9 Ca++ 0.2805677E-07 0.3907410E-07 0.1565213E-02 11.8471 10 Mg++ 0.2200130E-10 0.6228267E-10 0.1513444E-05 8.7406 11 Fe++ 0.1300760E-12 0.2146282E-07 0.1198023E-02 6.5126 12 K+ 0.5568146E-04 0.5582941E-04 0.2181929E+01 5.4862 13 Na+ 0.7071084E-02 0.7319120E-02 0.1681793E+03 7.5897 14 Mn++ 0.1737589E-10 0.7451825E-09 0.4091796E-04 8.6385 15 HPO4-- 0.1072548E-05 0.1084338E-05 0.1040206E+00 13.4308 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1158800E+00 -.7422848E-02 -.1084572E+00 0.0000000E+00 2 H2O 0.5542051E+02 0.5544321E+02 -.2269546E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2194706E-03 0.2550567E-04 0.1939650E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1939661E-03 -.1196663E-08 -.1939650E-03 0.0000000E+00 7 Al+++ 0.2282193E-01 0.8694800E-04 0.2273498E-01 0.0000000E+00 8 H4SiO4 0.7287907E-01 0.3229981E-02 0.6964909E-01 0.0000000E+00 9 Ca++ 0.8064319E-02 0.3902723E-07 0.8064280E-02 0.0000000E+00 10 Mg++ 0.5554762E-02 0.6220795E-10 0.5554762E-02 0.0000000E+00 11 Fe++ 0.4990347E-02 0.2143707E-07 0.4990326E-02 0.0000000E+00 12 K+ 0.1485987E-02 0.5576244E-04 0.1430225E-02 0.0000000E+00 13 Na+ 0.8945521E-02 0.7310340E-02 0.1635182E-02 0.0000000E+00 14 Mn++ 0.1213528E-03 0.7442886E-09 0.1213521E-03 0.0000000E+00 15 HPO4-- 0.4141712E-04 0.1083037E-05 0.4033408E-04 0.0000000E+00 Chg. balance for solid moles: 0.5475E-17 Mass of aqueous solution: 0.999310E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 6.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1620E-02 -2.790 0.4249 -0.372 5.560 0.1631 apatite-OH 0.1344E-04 -4.871 0.6754E-02 -2.170 0.8837E-01 0.2146E-02 clinochlore 0.1111E-02 -2.954 0.6175 -0.209 8.080 0.2349 daphnite 0.6877E-03 -3.163 0.4907 -0.309 6.420 0.1487 chlorite-Mn 0.2427E-04 -4.615 0.1721E-01 -1.764 0.2251 0.5483E-02 hematite 0.7759E-03 -3.110 0.1239 -0.907 1.621 0.2348E-01 lawsonite 0.1991E-03 -3.701 0.6256E-01 -1.204 0.8185 0.2017E-01 microcline 0.1430E-02 -2.845 0.3981 -0.400 5.209 0.1555 paragonite 0.1479E-04 -4.830 0.5652E-02 -2.248 0.7395E-01 0.1954E-02 stilbite 0.7798E-02 -2.108 5.495 0.740 71.90 2.563 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.642654 g Volume = 3.318580 cm3 Porosity: 12.6597% V(tot) - V(min): 0.48102E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6.9990000 g log = 0.8450 Original solution: 1000.0103000 g Original solution / Rock added: 142.88 (Water/Rock Ratio), log = 2.1550 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2283E-06 1.0073 0.2419E-06 0.2402E-06 CH4,gas 0.7836E-16 1.0129 0.8349E-16 0.8242E-16 H2,gas 0.1314E-05 1.0006 0.1383E-05 0.1382E-05 H2S,gas 0.1853E-14 0.9959 0.1941E-14 0.1949E-14 S2,gas 0.7020E-37 1.0000 0.7384E-37 0.7384E-37 CO,gas 0.8236E-16 1.0000 0.8664E-16 0.8664E-16 SO3,gas 0.1534E-39 1.0000 0.1613E-39 0.1613E-39 SO2,gas 0.8022E-23 1.0000 0.8439E-23 0.8439E-23 HCl,gas 0.6208E-17 1.0000 0.6531E-17 0.6531E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 -0.15165E-10 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.98 -8.62 -2.872 0.14712E+05 -6.616 3 CH4,gas 4.81 -13.27 -18.08 -4.520 0.30868E+05 -16.078 4 H2,gas 8.29 0.43 -7.86 -4.491 0.13420E+05 -5.859 5 H2S,gas -5.94 -22.65 -16.71 -8.356 0.28535E+05 -14.712 6 S2,gas -7.03 -46.16 -39.13 -6.020 0.66816E+05 -37.132 7 CO,gas 3.51 -14.55 -18.06 -5.558 0.30841E+05 -16.062 8 SO3,gas 17.43 -24.36 -41.79 -10.448 0.71359E+05 -39.792 9 SO2,gas 1.14 -23.94 -25.07 -6.686 0.42813E+05 -23.074 10 HCl,gas 5.48 -13.71 -19.19 -9.593 0.32758E+05 -17.185 11 acmite 7.74 7.05 -0.68 -0.071 0.11655E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.33 -4.22 -0.211 0.72055E+04 20 analcite 3.37 3.09 -0.28 -0.031 0.48177E+03 21 andalusite 5.06 1.25 -3.81 -0.381 0.65127E+04 22 andradite 39.09 37.89 -1.20 -0.062 0.20480E+04 23 grossular 32.83 29.96 -2.87 -0.144 0.49047E+04 26 annite 20.21 17.11 -3.10 -0.172 0.52989E+04 27 phlogopite 27.15 23.79 -3.36 -0.186 0.57311E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -3.13 -4.12 -1.373 0.70325E+04 36 brucite 12.58 8.74 -3.84 -0.767 0.65498E+04 37 calcite 0.83 -3.13 -3.97 -1.322 0.67712E+04 38 carnegieite-low 9.06 6.51 -2.56 -0.366 0.43698E+04 39 carnegieite-high 10.13 6.51 -3.63 -0.518 0.61967E+04 40 carpholite-Mg 8.65 6.57 -2.08 -0.139 0.35489E+04 41 carpholite-Fe 6.78 4.34 -2.44 -0.163 0.41645E+04 42 celadonite 5.40 2.89 -2.51 -0.148 0.42832E+04 43 celadonite-Fe 3.94 0.66 -3.27 -0.193 0.55885E+04 44 chrysotile 23.94 19.39 -4.55 -0.379 0.77675E+04 50 chloritoid-Mg 13.26 9.99 -3.27 -0.218 0.55876E+04 51 chloritoid-Fe 9.24 7.76 -1.48 -0.099 0.25235E+04 52 chloritoid-Mn 11.46 9.89 -1.58 -0.105 0.26920E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 4.66 -3.77 -0.343 0.64345E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.33 -0.56 -0.094 0.96232E+03 67 diopside 16.22 13.75 -2.46 -0.246 0.42028E+04 68 hedenbergite 14.24 11.53 -2.72 -0.272 0.46417E+04 75 epidote 24.78 24.41 -0.37 -0.018 0.62799E+03 76 clinozoisite 22.92 20.44 -2.48 -0.113 0.42346E+04 77 epidote-Fe 29.94 28.37 -1.56 -0.081 0.26689E+04 78 fayalite 14.08 9.61 -4.47 -0.639 0.76334E+04 79 ferrosilite 11.19 6.19 -5.00 -0.500 0.85309E+04 83 gibbsite 4.10 2.33 -1.76 -0.252 0.30135E+04 84 glaucophane 23.11 18.73 -4.38 -0.118 0.74770E+04 87 greenalite 16.19 12.70 -3.49 -0.291 0.59593E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.09 -1.16 -0.116 0.19848E+04 97 kalsilite 7.62 4.40 -3.22 -0.460 0.54953E+04 98 kaolinite -1.27 -2.17 -0.90 -0.081 0.15291E+04 99 kyanite 4.93 1.25 -3.68 -0.368 0.62895E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.99 -3.18 -0.318 0.54342E+04 105 lizardite 23.29 19.39 -3.90 -0.325 0.66577E+04 107 magnetite 20.13 19.11 -1.02 -0.083 0.17460E+04 108 minnesotaite 10.46 5.87 -4.59 -0.270 0.78378E+04 110 magnesioferrite 26.26 21.34 -4.92 -0.402 0.83991E+04 113 margarite 17.45 14.34 -3.11 -0.124 0.53076E+04 120 muscovite 2.68 2.23 -0.45 -0.026 0.76153E+03 122 nepheline 8.38 6.51 -1.87 -0.268 0.31977E+04 134 phlogopite-Na 29.73 25.89 -3.84 -0.213 0.65529E+04 136 prehnite 19.47 18.11 -1.36 -0.080 0.23183E+04 137 prehnite-Fe 22.59 22.07 -0.51 -0.031 0.87396E+03 138 pumpellyite-Fe 46.47 45.06 -1.41 -0.031 0.24046E+04 139 pumpellyite-Mg 49.19 47.29 -1.90 -0.042 0.32505E+04 145 pyroxmangite 7.42 5.22 -2.19 -0.439 0.37468E+04 146 pyrophyllite -6.10 -9.00 -2.90 -0.182 0.49591E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodonite 7.46 5.22 -2.24 -0.448 0.38261E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.25 -4.07 -0.407 0.69549E+04 164 stilpnomelane-Fe 13.18 12.64 -0.54 -0.016 0.92720E+03 165 stilpnomelane-Mg 27.60 23.78 -3.82 -0.114 0.65220E+04 168 sudoite 21.22 16.56 -4.66 -0.150 0.79491E+04 171 talc 16.55 12.55 -4.00 -0.235 0.68279E+04 174 tephroite 18.11 13.86 -4.25 -0.608 0.72615E+04 177 topaz-H 4.67 1.25 -3.42 -0.311 0.58386E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 8.43 -3.10 -0.620 0.52891E+04 189 wollastonite 10.48 8.43 -2.05 -0.410 0.35030E+04 190 pseudo-wollastonite 11.02 8.43 -2.59 -0.518 0.44216E+04 191 zoisite 22.96 20.44 -2.52 -0.115 0.43072E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.15 -3.59 -0.222 0.61310E+04 194 beidellite-H -2.24 -7.11 -4.86 -0.310 0.83052E+04 195 beidellite-K -1.44 -5.29 -3.86 -0.236 0.65902E+04 196 beidellite-Mg -1.71 -5.66 -3.96 -0.245 0.67548E+04 197 beidellite-Na -1.26 -4.60 -3.34 -0.205 0.57089E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.93 -2.72 -0.168 0.46425E+04 202 montmorillonite-K -2.16 -5.08 -2.92 -0.179 0.49794E+04 203 montmorillonite-Mg -2.40 -5.45 -3.04 -0.188 0.51973E+04 204 montmorillonite-Na -1.96 -4.38 -2.42 -0.148 0.41363E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.83 -1.77 -0.119 0.30192E+04 207 nontronite-K 3.40 2.64 -0.77 -0.049 0.13076E+04 208 nontronite-Mg 3.14 2.27 -0.87 -0.056 0.14847E+04 209 nontronite-Na 3.58 3.33 -0.25 -0.016 0.42807E+03 224 tobermorite 9.84 6.45 -3.39 -0.924 0.57836E+04 233 boehmite 4.43 2.33 -2.10 -0.350 0.35808E+04 235 ferrous-oxide 9.82 6.51 -3.31 -0.828 0.56545E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 1.67 -0.41 -0.031 0.69361E+03 243 an25ab75 2.71 2.17 -0.54 -0.041 0.91492E+03 244 an30ab70 3.34 2.67 -0.67 -0.052 0.11446E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 6.9990000 g New total amount of reactant added: 7.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.9371E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 7.1990000 Water: Moles liquid = 0.5544E+02 kg liquid = 0.9988E+00 Moles total = 0.5542E+02 kg total = 0.9984E+00 Activity = 1.0000 Stoichiometric ionic strength = .4208073E-02 Osmotic coef. = 0.9651 True ionic strength = .7159221E-02 Chg. balance for total moles = -.9371E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.18141E-09 -9.7413 0.16105E-09 -9.7931 0.88774E+00 -0.0517 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13789E-03 -3.8605 0.12210E-03 -3.9133 0.88547E+00 -0.0528 4 SO4-- 0.25521E-04 -4.5931 0.16641E-04 -4.7788 0.65204E+00 -0.1857 5 HCO3- 0.73466E-05 -5.1339 0.65092E-05 -5.1865 0.88601E+00 -0.0526 6 HS- 0.15534E-12 -12.8087 0.13755E-12 -12.8615 0.88552E+00 -0.0528 7 Al+++ 0.23118E-26 -26.6361 0.89813E-27 -27.0467 0.38850E+00 -0.4106 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.28057E-07 -7.5520 0.18238E-07 -7.7390 0.65003E+00 -0.1871 10 Mg++ 0.22001E-10 -10.6576 0.14274E-10 -10.8455 0.64877E+00 -0.1879 11 Fe++ 0.13008E-12 -12.8858 0.84429E-13 -13.0735 0.64908E+00 -0.1877 12 K+ 0.55681E-04 -4.2543 0.49340E-04 -4.3068 0.88611E+00 -0.0525 13 Na+ 0.70711E-02 -2.1505 0.62608E-02 -2.2034 0.88541E+00 -0.0529 14 Mn++ 0.17376E-10 -10.7601 0.11282E-10 -10.9476 0.64930E+00 -0.1876 15 HPO4-- 0.10725E-05 -5.9696 0.69939E-06 -6.1553 0.65208E+00 -0.1857 16 HSiO3- 0.26202E-02 -2.5817 0.23201E-02 -2.6345 0.88547E+00 -0.0528 17 Ca(HSiO3)+ 0.10698E-08 -8.9707 0.94805E-09 -9.0232 0.88619E+00 -0.0525 18 Mg(HSiO3)+ 0.10420E-11 -11.9821 0.92342E-12 -12.0346 0.88619E+00 -0.0525 19 NaHSiO3,aq 0.23070E-03 -3.6369 0.23070E-03 -3.6369 0.10000E+01 0.0000 20 AlO+ 0.50446E-14 -14.2972 0.44705E-14 -14.3496 0.88619E+00 -0.0525 22 HAlO2,aq 0.55549E-08 -8.2553 0.55549E-08 -8.2553 0.10000E+01 0.0000 23 AlO2- 0.87047E-04 -4.0602 0.77018E-04 -4.1134 0.88479E+00 -0.0532 24 CH4,aq 0.52865E-19 -19.2768 0.52796E-19 -19.2774 0.99870E+00 -0.0006 29 CO,aq 0.54869E-19 -19.2607 0.54869E-19 -19.2607 0.10000E+01 0.0000 30 CO2,aq 0.21163E-08 -8.6744 0.21135E-08 -8.6750 0.99870E+00 -0.0006 31 CO3-2 0.57364E-05 -5.2414 0.37370E-05 -5.4275 0.65146E+00 -0.1861 32 CaCO3,aq 0.83474E-09 -9.0784 0.83474E-09 -9.0784 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.33754E-11 -11.4717 0.29912E-11 -11.5242 0.88619E+00 -0.0525 34 CaCl+ 0.40042E-11 -11.3975 0.35485E-11 -11.4500 0.88619E+00 -0.0525 35 CaCl2,aq 0.10088E-15 -15.9962 0.10088E-15 -15.9962 0.10000E+01 0.0000 36 CaOH+ 0.90109E-08 -8.0452 0.79853E-08 -8.0977 0.88619E+00 -0.0525 37 CaSO4,aq 0.94562E-10 -10.0243 0.94562E-10 -10.0243 0.10000E+01 0.0000 38 HCl,aq 0.36987E-14 -14.4320 0.36987E-14 -14.4320 0.10000E+01 0.0000 43 FeCl+ 0.18118E-16 -16.7419 0.16056E-16 -16.7944 0.88619E+00 -0.0525 46 FeO,aq 0.12873E-09 -9.8903 0.12873E-09 -9.8903 0.10000E+01 0.0000 47 FeOH+ 0.19613E-10 -10.7075 0.17380E-10 -10.7599 0.88619E+00 -0.0525 48 HFeO2- 0.97097E-08 -8.0128 0.85977E-08 -8.0656 0.88547E+00 -0.0528 49 FeO+ 0.15033E-14 -14.8230 0.13322E-14 -14.8754 0.88619E+00 -0.0525 51 FeO2- 0.11401E-07 -7.9431 0.10095E-07 -7.9959 0.88547E+00 -0.0528 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.10093E-08 -8.9960 0.10080E-08 -8.9965 0.99870E+00 -0.0006 54 KCl,aq 0.10667E-09 -9.9720 0.10667E-09 -9.9720 0.10000E+01 0.0000 55 KHSO4,aq 0.35384E-18 -18.4512 0.35384E-18 -18.4512 0.10000E+01 0.0000 56 KOH,aq 0.13356E-06 -6.8743 0.13356E-06 -6.8743 0.10000E+01 0.0000 57 KSO4- 0.14286E-07 -7.8451 0.12650E-07 -7.8979 0.88547E+00 -0.0528 58 MgCO3,aq 0.16325E-12 -12.7871 0.16325E-12 -12.7871 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26939E-14 -14.5696 0.23873E-14 -14.6221 0.88619E+00 -0.0525 60 MgCl+ 0.28450E-14 -14.5459 0.25212E-14 -14.5984 0.88619E+00 -0.0525 61 MgOH+ 0.39071E-10 -10.4082 0.34624E-10 -10.4606 0.88619E+00 -0.0525 63 MnO,aq 0.45921E-09 -9.3380 0.45921E-09 -9.3380 0.10000E+01 0.0000 64 MnOH+ 0.24346E-09 -9.6136 0.21576E-09 -9.6660 0.88619E+00 -0.0525 65 MnO2-2 0.93994E-12 -12.0269 0.61233E-12 -12.2130 0.65146E+00 -0.1861 66 HMnO2- 0.24129E-10 -10.6175 0.21366E-10 -10.6703 0.88547E+00 -0.0528 69 MnCl+ 0.94081E-14 -14.0265 0.83373E-14 -14.0790 0.88619E+00 -0.0525 70 MnSO4,aq 0.53208E-13 -13.2740 0.53208E-13 -13.2740 0.10000E+01 0.0000 71 NaCl,aq 0.24961E-06 -6.6027 0.24961E-06 -6.6027 0.10000E+01 0.0000 72 NaOH,aq 0.17082E-04 -4.7675 0.17082E-04 -4.7675 0.10000E+01 0.0000 74 OH- 0.42096E-02 -2.3758 0.37246E-02 -2.4289 0.88479E+00 -0.0532 79 HPO3-2 0.34180E-17 -17.4662 0.22267E-17 -17.6523 0.65146E+00 -0.1861 82 H3PO4,aq 0.11678E-15 -15.9326 0.11678E-15 -15.9326 0.10000E+01 0.0000 83 H2PO4- 0.22292E-08 -8.6518 0.19747E-08 -8.7045 0.88582E+00 -0.0527 84 PO4-3 0.95610E-08 -8.0195 0.37926E-08 -8.4211 0.39668E+00 -0.4016 87 H2P2O7-2 0.46847E-18 -18.3293 0.30519E-18 -18.5154 0.65146E+00 -0.1861 88 HP2O7-3 0.99991E-15 -15.0000 0.38859E-15 -15.4105 0.38862E+00 -0.4105 89 P2O7-4 0.31158E-14 -14.5064 0.59526E-15 -15.2253 0.19105E+00 -0.7189 90 H2S,aq 0.66645E-16 -16.1762 0.66559E-16 -16.1768 0.99870E+00 -0.0006 97 SO3-2 0.34893E-14 -14.4573 0.22871E-14 -14.6407 0.65546E+00 -0.1835 98 HSO3- 0.24343E-16 -16.6136 0.21555E-16 -16.6665 0.88547E+00 -0.0528 99 HSO4- 0.28048E-11 -11.5521 0.24866E-11 -11.6044 0.88655E+00 -0.0523 Charge balance for all species = -.9436E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1814109E-09 -.7431761E-02 -.7486951E+01 0.0000 2 H2O 0.1000000E+01 0.5550980E+02 0.9995159E+06 0.0000 3 Cl- 0.1378930E-03 0.1381428E-03 0.4895079E+01 5.8798 4 SO4-- 0.2552125E-04 0.2553683E-04 0.2451858E+01 14.8073 5 HCO3- 0.7346565E-05 0.1308597E-04 0.7980622E+00 4.6066 6 HS- 0.1553365E-12 -.1198100E-08 -.3960335E-04 -3.0685 7 Al+++ 0.2311791E-26 0.8705241E-04 0.2347607E+01 2.3325 8 H4SiO4 0.3829605E-03 0.3233860E-02 0.3106653E+03 -3.4168 9 Ca++ 0.2805679E-07 0.3907414E-07 0.1565215E-02 11.8471 10 Mg++ 0.2200132E-10 0.6228270E-10 0.1513445E-05 8.7406 11 Fe++ 0.1300761E-12 0.2146282E-07 0.1198023E-02 6.5126 12 K+ 0.5568148E-04 0.5582943E-04 0.2181929E+01 5.4862 13 Na+ 0.7071086E-02 0.7319122E-02 0.1681794E+03 7.5897 14 Mn++ 0.1737590E-10 0.7451827E-09 0.4091797E-04 8.6385 15 HPO4-- 0.1072547E-05 0.1084337E-05 0.1040205E+00 13.4308 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1191917E+00 -.7422692E-02 -.1117690E+00 0.0000000E+00 2 H2O 0.5541801E+02 0.5544206E+02 -.2404957E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2250133E-03 0.2550567E-04 0.1995076E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1995088E-03 -.1196637E-08 -.1995076E-03 0.0000000E+00 7 Al+++ 0.2347408E-01 0.8694617E-04 0.2338713E-01 0.0000000E+00 8 H4SiO4 0.7496162E-01 0.3229913E-02 0.7173171E-01 0.0000000E+00 9 Ca++ 0.8294348E-02 0.3902646E-07 0.8294309E-02 0.0000000E+00 10 Mg++ 0.5713492E-02 0.6220669E-10 0.5713492E-02 0.0000000E+00 11 Fe++ 0.5132949E-02 0.2143662E-07 0.5132927E-02 0.0000000E+00 12 K+ 0.1528450E-02 0.5576130E-04 0.1472689E-02 0.0000000E+00 13 Na+ 0.9196570E-02 0.7310190E-02 0.1886380E-02 0.0000000E+00 14 Mn++ 0.1248206E-03 0.7442733E-09 0.1248198E-03 0.0000000E+00 15 HPO4-- 0.4260063E-04 0.1083014E-05 0.4151762E-04 0.0000000E+00 Chg. balance for solid moles: 0.3388E-18 Mass of aqueous solution: 0.999289E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 7.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1972E-02 -2.705 0.5172 -0.286 6.579 0.1986 apatite-OH 0.1384E-04 -4.859 0.6952E-02 -2.158 0.8842E-01 0.2209E-02 clinochlore 0.1143E-02 -2.942 0.6351 -0.197 8.079 0.2416 daphnite 0.7074E-03 -3.150 0.5047 -0.297 6.420 0.1529 chlorite-Mn 0.2496E-04 -4.603 0.1770E-01 -1.752 0.2251 0.5640E-02 hematite 0.7980E-03 -3.098 0.1274 -0.895 1.621 0.2416E-01 lawsonite 0.3093E-03 -3.510 0.9719E-01 -1.012 1.236 0.3134E-01 microcline 0.1473E-02 -2.832 0.4099 -0.387 5.214 0.1601 paragonite -.8612E-04 1.000 -.3291E-01 1.000 -.4187 -.1138E-01 stilbite 0.7916E-02 -2.102 5.578 0.747 70.96 2.602 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 paragonite 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.861817 g Volume = 3.407066 cm3 Porosity: 12.1800% V(tot) - V(min): 0.47253E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7.1990000 g log = 0.8573 Original solution: 1000.0103000 g Original solution / Rock added: 138.91 (Water/Rock Ratio), log = 2.1427 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2283E-06 1.0073 0.2419E-06 0.2402E-06 CH4,gas 0.7836E-16 1.0129 0.8349E-16 0.8243E-16 H2,gas 0.1314E-05 1.0006 0.1383E-05 0.1382E-05 H2S,gas 0.1853E-14 0.9959 0.1941E-14 0.1949E-14 S2,gas 0.7020E-37 1.0000 0.7384E-37 0.7384E-37 CO,gas 0.8236E-16 1.0000 0.8664E-16 0.8664E-16 SO3,gas 0.1534E-39 1.0000 0.1614E-39 0.1614E-39 SO2,gas 0.8022E-23 1.0000 0.8439E-23 0.8439E-23 HCl,gas 0.6208E-17 1.0000 0.6531E-17 0.6531E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.98 -8.62 -2.872 0.14712E+05 -6.616 3 CH4,gas 4.81 -13.27 -18.08 -4.520 0.30868E+05 -16.078 4 H2,gas 8.29 0.43 -7.86 -4.491 0.13420E+05 -5.859 5 H2S,gas -5.94 -22.65 -16.71 -8.356 0.28535E+05 -14.712 6 S2,gas -7.03 -46.16 -39.13 -6.020 0.66816E+05 -37.132 7 CO,gas 3.51 -14.55 -18.06 -5.558 0.30841E+05 -16.062 8 SO3,gas 17.43 -24.36 -41.79 -10.448 0.71359E+05 -39.792 9 SO2,gas 1.14 -23.94 -25.07 -6.686 0.42813E+05 -23.074 10 HCl,gas 5.48 -13.71 -19.19 -9.593 0.32758E+05 -17.185 11 acmite 7.74 7.05 -0.68 -0.071 0.11655E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.33 -4.22 -0.211 0.72055E+04 20 analcite 3.37 3.09 -0.28 -0.031 0.48177E+03 21 andalusite 5.06 1.25 -3.81 -0.381 0.65127E+04 22 andradite 39.09 37.89 -1.20 -0.062 0.20480E+04 23 grossular 32.83 29.96 -2.87 -0.144 0.49047E+04 26 annite 20.21 17.11 -3.10 -0.172 0.52989E+04 27 phlogopite 27.15 23.79 -3.36 -0.186 0.57311E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -3.13 -4.12 -1.373 0.70325E+04 36 brucite 12.58 8.74 -3.84 -0.767 0.65498E+04 37 calcite 0.83 -3.13 -3.97 -1.322 0.67712E+04 38 carnegieite-low 9.06 6.51 -2.56 -0.366 0.43698E+04 39 carnegieite-high 10.13 6.51 -3.63 -0.518 0.61967E+04 40 carpholite-Mg 8.65 6.57 -2.08 -0.139 0.35489E+04 41 carpholite-Fe 6.78 4.34 -2.44 -0.163 0.41645E+04 42 celadonite 5.40 2.89 -2.51 -0.148 0.42832E+04 43 celadonite-Fe 3.94 0.66 -3.27 -0.193 0.55885E+04 44 chrysotile 23.94 19.39 -4.55 -0.379 0.77675E+04 50 chloritoid-Mg 13.26 9.99 -3.27 -0.218 0.55876E+04 51 chloritoid-Fe 9.24 7.76 -1.48 -0.099 0.25235E+04 52 chloritoid-Mn 11.46 9.89 -1.58 -0.105 0.26920E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 4.66 -3.77 -0.343 0.64345E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.33 -0.56 -0.094 0.96232E+03 67 diopside 16.22 13.75 -2.46 -0.246 0.42028E+04 68 hedenbergite 14.24 11.53 -2.72 -0.272 0.46417E+04 75 epidote 24.78 24.41 -0.37 -0.018 0.62799E+03 76 clinozoisite 22.92 20.44 -2.48 -0.113 0.42346E+04 77 epidote-Fe 29.94 28.37 -1.56 -0.081 0.26689E+04 78 fayalite 14.08 9.61 -4.47 -0.639 0.76334E+04 79 ferrosilite 11.19 6.19 -5.00 -0.500 0.85309E+04 83 gibbsite 4.10 2.33 -1.76 -0.252 0.30135E+04 84 glaucophane 23.11 18.73 -4.38 -0.118 0.74770E+04 87 greenalite 16.19 12.70 -3.49 -0.291 0.59593E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.09 -1.16 -0.116 0.19848E+04 97 kalsilite 7.62 4.40 -3.22 -0.460 0.54953E+04 98 kaolinite -1.27 -2.17 -0.90 -0.081 0.15291E+04 99 kyanite 4.93 1.25 -3.68 -0.368 0.62895E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.99 -3.18 -0.318 0.54342E+04 105 lizardite 23.29 19.39 -3.90 -0.325 0.66577E+04 107 magnetite 20.13 19.11 -1.02 -0.083 0.17460E+04 108 minnesotaite 10.46 5.87 -4.59 -0.270 0.78378E+04 110 magnesioferrite 26.26 21.34 -4.92 -0.402 0.83991E+04 113 margarite 17.45 14.34 -3.11 -0.124 0.53076E+04 120 muscovite 2.68 2.23 -0.45 -0.026 0.76153E+03 121 paragonite 4.34 4.34 0.00 0.000 -0.45496E-11 122 nepheline 8.38 6.51 -1.87 -0.268 0.31977E+04 134 phlogopite-Na 29.73 25.89 -3.84 -0.213 0.65529E+04 136 prehnite 19.47 18.11 -1.36 -0.080 0.23183E+04 137 prehnite-Fe 22.59 22.07 -0.51 -0.031 0.87396E+03 138 pumpellyite-Fe 46.47 45.06 -1.41 -0.031 0.24046E+04 139 pumpellyite-Mg 49.19 47.29 -1.90 -0.042 0.32505E+04 145 pyroxmangite 7.42 5.22 -2.19 -0.439 0.37468E+04 146 pyrophyllite -6.10 -9.00 -2.90 -0.182 0.49591E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodonite 7.46 5.22 -2.24 -0.448 0.38261E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.25 -4.07 -0.407 0.69549E+04 164 stilpnomelane-Fe 13.18 12.64 -0.54 -0.016 0.92720E+03 165 stilpnomelane-Mg 27.60 23.78 -3.82 -0.114 0.65220E+04 168 sudoite 21.22 16.56 -4.66 -0.150 0.79491E+04 171 talc 16.55 12.55 -4.00 -0.235 0.68279E+04 174 tephroite 18.11 13.86 -4.25 -0.608 0.72615E+04 177 topaz-H 4.67 1.25 -3.42 -0.311 0.58386E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 8.43 -3.10 -0.620 0.52891E+04 189 wollastonite 10.48 8.43 -2.05 -0.410 0.35030E+04 190 pseudo-wollastonite 11.02 8.43 -2.59 -0.518 0.44216E+04 191 zoisite 22.96 20.44 -2.52 -0.115 0.43072E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.15 -3.59 -0.222 0.61310E+04 194 beidellite-H -2.24 -7.11 -4.86 -0.310 0.83052E+04 195 beidellite-K -1.44 -5.29 -3.86 -0.236 0.65902E+04 196 beidellite-Mg -1.71 -5.66 -3.96 -0.245 0.67548E+04 197 beidellite-Na -1.26 -4.60 -3.34 -0.205 0.57089E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.93 -2.72 -0.168 0.46425E+04 202 montmorillonite-K -2.16 -5.08 -2.92 -0.179 0.49794E+04 203 montmorillonite-Mg -2.40 -5.45 -3.04 -0.188 0.51973E+04 204 montmorillonite-Na -1.96 -4.38 -2.42 -0.148 0.41363E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.83 -1.77 -0.119 0.30192E+04 207 nontronite-K 3.40 2.64 -0.77 -0.049 0.13076E+04 208 nontronite-Mg 3.14 2.27 -0.87 -0.056 0.14847E+04 209 nontronite-Na 3.58 3.33 -0.25 -0.016 0.42807E+03 224 tobermorite 9.84 6.45 -3.39 -0.924 0.57836E+04 233 boehmite 4.43 2.33 -2.10 -0.350 0.35808E+04 235 ferrous-oxide 9.82 6.51 -3.31 -0.828 0.56545E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 1.67 -0.41 -0.031 0.69361E+03 243 an25ab75 2.71 2.17 -0.54 -0.041 0.91492E+03 244 an30ab70 3.34 2.67 -0.67 -0.052 0.11446E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 7.1990000 Water: Moles liquid = 0.5544E+02 kg liquid = 0.9988E+00 Moles total = 0.5542E+02 kg total = 0.9984E+00 Activity = 1.0000 Stoichiometric ionic strength = .4285326E-02 Osmotic coef. = 0.9648 True ionic strength = .7318664E-02 Chg. balance for total moles = -.9371E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.17758E-09 -9.7506 0.15749E-09 -9.8027 0.88687E+00 -0.0521 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13789E-03 -3.8605 0.12197E-03 -3.9137 0.88456E+00 -0.0533 4 SO4-- 0.25521E-04 -4.5931 0.16575E-04 -4.7806 0.64944E+00 -0.1875 5 HCO3- 0.72650E-05 -5.1388 0.64304E-05 -5.1918 0.88512E+00 -0.0530 6 HS- 0.17403E-12 -12.7594 0.15395E-12 -12.8126 0.88462E+00 -0.0532 7 Al+++ 0.20892E-26 -26.6800 0.80430E-27 -27.0946 0.38498E+00 -0.4146 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.29385E-07 -7.5319 0.19024E-07 -7.7207 0.64740E+00 -0.1888 10 Mg++ 0.21498E-10 -10.6676 0.13890E-10 -10.8573 0.64612E+00 -0.1897 11 Fe++ 0.12710E-12 -12.8959 0.82159E-13 -13.0853 0.64643E+00 -0.1895 12 K+ 0.56926E-04 -4.2447 0.50392E-04 -4.2976 0.88521E+00 -0.0530 13 Na+ 0.72293E-02 -2.1409 0.63943E-02 -2.1942 0.88450E+00 -0.0533 14 Mn++ 0.16978E-10 -10.7701 0.10979E-10 -10.9594 0.64666E+00 -0.1893 15 HPO4-- 0.97428E-06 -6.0113 0.63278E-06 -6.1987 0.64948E+00 -0.1874 16 HSiO3- 0.26821E-02 -2.5715 0.23724E-02 -2.6248 0.88456E+00 -0.0533 17 Ca(HSiO3)+ 0.11422E-08 -8.9422 0.10112E-08 -8.9952 0.88530E+00 -0.0529 18 Mg(HSiO3)+ 0.10379E-11 -11.9838 0.91886E-12 -12.0367 0.88530E+00 -0.0529 19 NaHSiO3,aq 0.24094E-03 -3.6181 0.24094E-03 -3.6181 0.10000E+01 0.0000 20 AlO+ 0.47285E-14 -14.3253 0.41861E-14 -14.3782 0.88530E+00 -0.0529 22 HAlO2,aq 0.53189E-08 -8.2742 0.53189E-08 -8.2742 0.10000E+01 0.0000 23 AlO2- 0.85318E-04 -4.0690 0.75410E-04 -4.1226 0.88387E+00 -0.0536 24 CH4,aq 0.58686E-19 -19.2315 0.58608E-19 -19.2320 0.99868E+00 -0.0006 29 CO,aq 0.54882E-19 -19.2606 0.54882E-19 -19.2606 0.10000E+01 0.0000 30 CO2,aq 0.20446E-08 -8.6894 0.20419E-08 -8.6900 0.99868E+00 -0.0006 31 CO3-2 0.58182E-05 -5.2352 0.37751E-05 -5.4231 0.64884E+00 -0.1879 32 CaCO3,aq 0.87959E-09 -9.0557 0.87959E-09 -9.0557 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.34818E-11 -11.4582 0.30824E-11 -11.5111 0.88530E+00 -0.0529 34 CaCl+ 0.41766E-11 -11.3792 0.36975E-11 -11.4321 0.88530E+00 -0.0529 35 CaCl2,aq 0.10501E-15 -15.9788 0.10501E-15 -15.9788 0.10000E+01 0.0000 36 CaOH+ 0.96211E-08 -8.0168 0.85175E-08 -8.0697 0.88530E+00 -0.0529 37 CaSO4,aq 0.98245E-10 -10.0077 0.98245E-10 -10.0077 0.10000E+01 0.0000 38 HCl,aq 0.36133E-14 -14.4421 0.36133E-14 -14.4421 0.10000E+01 0.0000 43 FeCl+ 0.17630E-16 -16.7537 0.15608E-16 -16.8067 0.88530E+00 -0.0529 46 FeO,aq 0.13098E-09 -9.8828 0.13098E-09 -9.8828 0.10000E+01 0.0000 47 FeOH+ 0.19535E-10 -10.7092 0.17295E-10 -10.7621 0.88530E+00 -0.0529 48 HFeO2- 0.10113E-07 -7.9951 0.89456E-08 -8.0484 0.88456E+00 -0.0533 49 FeO+ 0.14716E-14 -14.8322 0.13028E-14 -14.8851 0.88530E+00 -0.0529 51 FeO2- 0.11670E-07 -7.9329 0.10323E-07 -7.9862 0.88456E+00 -0.0533 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.10450E-08 -8.9809 0.10436E-08 -8.9815 0.99868E+00 -0.0006 54 KCl,aq 0.10883E-09 -9.9632 0.10883E-09 -9.9632 0.10000E+01 0.0000 55 KHSO4,aq 0.35200E-18 -18.4535 0.35200E-18 -18.4535 0.10000E+01 0.0000 56 KOH,aq 0.13949E-06 -6.8555 0.13949E-06 -6.8555 0.10000E+01 0.0000 57 KSO4- 0.14547E-07 -7.8372 0.12868E-07 -7.8905 0.88456E+00 -0.0533 58 MgCO3,aq 0.16048E-12 -12.7946 0.16048E-12 -12.7946 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.25923E-14 -14.5863 0.22950E-14 -14.6392 0.88530E+00 -0.0529 60 MgCl+ 0.27684E-14 -14.5578 0.24508E-14 -14.6107 0.88530E+00 -0.0529 61 MgOH+ 0.38917E-10 -10.4099 0.34453E-10 -10.4628 0.88530E+00 -0.0529 63 MnO,aq 0.46725E-09 -9.3304 0.46725E-09 -9.3304 0.10000E+01 0.0000 64 MnOH+ 0.24251E-09 -9.6153 0.21469E-09 -9.6682 0.88530E+00 -0.0529 65 MnO2-2 0.10041E-11 -11.9982 0.65148E-12 -12.1861 0.64884E+00 -0.1879 66 HMnO2- 0.25131E-10 -10.5998 0.22230E-10 -10.6531 0.88456E+00 -0.0533 69 MnCl+ 0.91547E-14 -14.0384 0.81046E-14 -14.0913 0.88530E+00 -0.0529 70 MnSO4,aq 0.51570E-13 -13.2876 0.51570E-13 -13.2876 0.10000E+01 0.0000 71 NaCl,aq 0.25467E-06 -6.5940 0.25467E-06 -6.5940 0.10000E+01 0.0000 72 NaOH,aq 0.17840E-04 -4.7486 0.17840E-04 -4.7486 0.10000E+01 0.0000 74 OH- 0.43091E-02 -2.3656 0.38087E-02 -2.4192 0.88387E+00 -0.0536 79 HPO3-2 0.32146E-17 -17.4929 0.20858E-17 -17.6807 0.64884E+00 -0.1879 82 H3PO4,aq 0.10105E-15 -15.9955 0.10105E-15 -15.9955 0.10000E+01 0.0000 83 H2PO4- 0.19744E-08 -8.7046 0.17472E-08 -8.7577 0.88492E+00 -0.0531 84 PO4-3 0.89229E-08 -8.0495 0.35088E-08 -8.4548 0.39324E+00 -0.4053 87 H2P2O7-2 0.36823E-18 -18.4339 0.23892E-18 -18.6217 0.64884E+00 -0.1879 88 HP2O7-3 0.80777E-15 -15.0927 0.31107E-15 -15.5071 0.38510E+00 -0.4144 89 P2O7-4 0.25916E-14 -14.5864 0.48727E-15 -15.3122 0.18802E+00 -0.7258 90 H2S,aq 0.72945E-16 -16.1370 0.72848E-16 -16.1376 0.99868E+00 -0.0006 97 SO3-2 0.36123E-14 -14.4422 0.23585E-14 -14.6274 0.65290E+00 -0.1852 98 HSO3- 0.24574E-16 -16.6095 0.21737E-16 -16.6628 0.88456E+00 -0.0533 99 HSO4- 0.27347E-11 -11.5631 0.24221E-11 -11.6158 0.88566E+00 -0.0527 Charge balance for all species = -.9370E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1775813E-09 -.7597237E-02 -.7653570E+01 0.0000 2 H2O 0.1000000E+01 0.5550982E+02 0.9995052E+06 0.0000 3 Cl- 0.1378895E-03 0.1381443E-03 0.4895078E+01 5.8890 4 SO4-- 0.2552127E-04 0.2553714E-04 0.2451860E+01 14.8249 5 HCO3- 0.7264986E-05 0.1308611E-04 0.7980621E+00 4.6110 6 HS- 0.1740297E-12 -.1222804E-08 -.4041950E-04 -3.0099 7 Al+++ 0.2089216E-26 0.8532310E-04 0.2300946E+01 2.3136 8 H4SiO4 0.3829605E-03 0.3305956E-02 0.3175878E+03 -3.4168 9 Ca++ 0.2938536E-07 0.4113417E-07 0.1647716E-02 11.8848 10 Mg++ 0.2149768E-10 0.6161850E-10 0.1497289E-05 8.7482 11 Fe++ 0.1270974E-12 0.2213749E-07 0.1235669E-02 6.5201 12 K+ 0.5692645E-04 0.5708059E-04 0.2230803E+01 5.5051 13 Na+ 0.7229298E-02 0.7488333E-02 0.1720656E+03 7.6085 14 Mn++ 0.1697788E-10 0.7529365E-09 0.4134328E-04 8.6460 15 HPO4-- 0.9742841E-06 0.9851814E-06 0.9450747E-01 13.4067 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1191917E+00 -.7587882E-02 -.1116038E+00 0.0000000E+00 2 H2O 0.5541801E+02 0.5544147E+02 -.2346360E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2250133E-03 0.2550569E-04 0.1995076E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1995088E-03 -.1221298E-08 -.1995076E-03 0.0000000E+00 7 Al+++ 0.2347408E-01 0.8521804E-04 0.2338886E-01 0.0000000E+00 8 H4SiO4 0.7496162E-01 0.3301885E-02 0.7165974E-01 0.0000000E+00 9 Ca++ 0.8294348E-02 0.4108352E-07 0.8294307E-02 0.0000000E+00 10 Mg++ 0.5713492E-02 0.6154263E-10 0.5713492E-02 0.0000000E+00 11 Fe++ 0.5132949E-02 0.2211023E-07 0.5132927E-02 0.0000000E+00 12 K+ 0.1528450E-02 0.5701030E-04 0.1471440E-02 0.0000000E+00 13 Na+ 0.9196570E-02 0.7479112E-02 0.1717458E-02 0.0000000E+00 14 Mn++ 0.1248206E-03 0.7520093E-09 0.1248198E-03 0.0000000E+00 15 HPO4-- 0.4260063E-04 0.9839683E-06 0.4161667E-04 0.0000000E+00 Chg. balance for solid moles: -.1794E-16 Mass of aqueous solution: 0.999289E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 7.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1717E-02 -2.765 0.4504 -0.346 5.728 0.1729 apatite-OH 0.1387E-04 -4.858 0.6968E-02 -2.157 0.8864E-01 0.2214E-02 clinochlore 0.1143E-02 -2.942 0.6351 -0.197 8.079 0.2416 daphnite 0.7074E-03 -3.150 0.5047 -0.297 6.420 0.1529 chlorite-Mn 0.2496E-04 -4.603 0.1770E-01 -1.752 0.2251 0.5640E-02 hematite 0.7980E-03 -3.098 0.1274 -0.895 1.621 0.2416E-01 lawsonite 0.2213E-03 -3.655 0.6955E-01 -1.158 0.8847 0.2243E-01 microcline 0.1471E-02 -2.832 0.4096 -0.388 5.210 0.1600 stilbite 0.8004E-02 -2.097 5.640 0.751 71.74 2.631 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7.861745 g Volume = 3.412579 cm3 Porosity: 12.0379% V(tot) - V(min): 0.46702E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7.1990000 g log = 0.8573 Original solution: 1000.0103000 g Original solution / Rock added: 138.91 (Water/Rock Ratio), log = 2.1427 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2206E-06 1.0073 0.2337E-06 0.2320E-06 CH4,gas 0.8698E-16 1.0129 0.9268E-16 0.9150E-16 H2,gas 0.1360E-05 1.0006 0.1431E-05 0.1431E-05 H2S,gas 0.2028E-14 0.9959 0.2125E-14 0.2133E-14 S2,gas 0.7845E-37 1.0000 0.8253E-37 0.8253E-37 CO,gas 0.8238E-16 1.0000 0.8666E-16 0.8666E-16 SO3,gas 0.1461E-39 1.0000 0.1537E-39 0.1537E-39 SO2,gas 0.7912E-23 1.0000 0.8322E-23 0.8322E-23 HCl,gas 0.6065E-17 1.0000 0.6380E-17 0.6380E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -14.99 -8.63 -2.877 0.14738E+05 -6.631 3 CH4,gas 4.81 -13.22 -18.03 -4.508 0.30791E+05 -16.033 4 H2,gas 8.29 0.44 -7.84 -4.482 0.13394E+05 -5.844 5 H2S,gas -5.94 -22.62 -16.67 -8.336 0.28468E+05 -14.673 6 S2,gas -7.03 -46.12 -39.08 -6.013 0.66734E+05 -37.083 7 CO,gas 3.51 -14.55 -18.06 -5.558 0.30841E+05 -16.062 8 SO3,gas 17.43 -24.39 -41.81 -10.453 0.71395E+05 -39.813 9 SO2,gas 1.14 -23.94 -25.08 -6.688 0.42823E+05 -23.080 10 HCl,gas 5.48 -13.72 -19.20 -9.598 0.32775E+05 -17.195 11 acmite 7.74 7.07 -0.66 -0.069 0.11333E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.31 -4.24 -0.212 0.72312E+04 20 analcite 3.37 3.09 -0.28 -0.031 0.48177E+03 21 andalusite 5.06 1.21 -3.85 -0.385 0.65771E+04 22 andradite 39.09 38.00 -1.09 -0.056 0.18548E+04 23 grossular 32.83 30.03 -2.80 -0.140 0.47760E+04 26 annite 20.21 17.13 -3.08 -0.171 0.52602E+04 27 phlogopite 27.15 23.81 -3.33 -0.185 0.56924E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -3.11 -4.10 -1.365 0.69937E+04 36 brucite 12.58 8.75 -3.83 -0.766 0.65369E+04 37 calcite 0.83 -3.11 -3.94 -1.314 0.67324E+04 38 carnegieite-low 9.06 6.51 -2.56 -0.366 0.43698E+04 39 carnegieite-high 10.13 6.51 -3.63 -0.518 0.61967E+04 40 carpholite-Mg 8.65 6.54 -2.11 -0.141 0.36004E+04 41 carpholite-Fe 6.78 4.31 -2.47 -0.165 0.42160E+04 42 celadonite 5.40 2.90 -2.50 -0.147 0.42703E+04 43 celadonite-Fe 3.94 0.67 -3.27 -0.192 0.55757E+04 44 chrysotile 23.94 19.41 -4.53 -0.377 0.77288E+04 50 chloritoid-Mg 13.26 9.96 -3.30 -0.220 0.56391E+04 51 chloritoid-Fe 9.24 7.73 -1.51 -0.101 0.25750E+04 52 chloritoid-Mn 11.46 9.86 -1.61 -0.107 0.27435E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 4.63 -3.81 -0.346 0.64989E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.31 -0.58 -0.097 0.99451E+03 67 diopside 16.22 13.80 -2.42 -0.242 0.41256E+04 68 hedenbergite 14.24 11.57 -2.67 -0.267 0.45644E+04 75 epidote 24.78 24.45 -0.33 -0.016 0.56361E+03 76 clinozoisite 22.92 20.46 -2.46 -0.112 0.42024E+04 77 epidote-Fe 29.94 28.43 -1.51 -0.078 0.25723E+04 78 fayalite 14.08 9.62 -4.46 -0.637 0.76077E+04 79 ferrosilite 11.19 6.21 -4.98 -0.498 0.85051E+04 83 gibbsite 4.10 2.31 -1.78 -0.255 0.30457E+04 84 glaucophane 23.11 18.75 -4.36 -0.118 0.74384E+04 87 greenalite 16.19 12.73 -3.47 -0.289 0.59206E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.09 -1.16 -0.116 0.19848E+04 97 kalsilite 7.62 4.40 -3.22 -0.460 0.54953E+04 98 kaolinite -1.27 -2.21 -0.93 -0.085 0.15935E+04 99 kyanite 4.93 1.21 -3.72 -0.372 0.63539E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.99 -3.18 -0.318 0.54342E+04 105 lizardite 23.29 19.41 -3.88 -0.323 0.66191E+04 107 magnetite 20.13 19.12 -1.02 -0.083 0.17331E+04 108 minnesotaite 10.46 5.89 -4.57 -0.269 0.77992E+04 110 magnesioferrite 26.26 21.35 -4.91 -0.401 0.83862E+04 113 margarite 17.45 14.31 -3.15 -0.126 0.53720E+04 120 muscovite 2.68 2.20 -0.48 -0.028 0.82592E+03 121 paragonite 4.34 4.30 -0.04 -0.002 0.64385E+02 122 nepheline 8.38 6.51 -1.87 -0.268 0.31977E+04 134 phlogopite-Na 29.73 25.92 -3.82 -0.212 0.65143E+04 136 prehnite 19.47 18.15 -1.32 -0.078 0.22539E+04 137 prehnite-Fe 22.59 22.13 -0.46 -0.027 0.77739E+03 138 pumpellyite-Fe 46.47 45.13 -1.34 -0.030 0.22951E+04 139 pumpellyite-Mg 49.19 47.35 -1.84 -0.041 0.31411E+04 145 pyroxmangite 7.42 5.23 -2.19 -0.437 0.37340E+04 146 pyrophyllite -6.10 -9.04 -2.94 -0.184 0.50235E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodonite 7.46 5.23 -2.23 -0.447 0.38132E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.21 -4.11 -0.411 0.70193E+04 164 stilpnomelane-Fe 13.18 12.65 -0.53 -0.016 0.91111E+03 165 stilpnomelane-Mg 27.60 23.79 -3.81 -0.114 0.65059E+04 168 sudoite 21.22 16.50 -4.72 -0.152 0.80521E+04 171 talc 16.55 12.58 -3.98 -0.234 0.67892E+04 174 tephroite 18.11 13.88 -4.24 -0.605 0.72357E+04 177 topaz-H 4.67 1.21 -3.46 -0.314 0.59029E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 8.47 -3.06 -0.612 0.52248E+04 189 wollastonite 10.48 8.47 -2.01 -0.403 0.34386E+04 190 pseudo-wollastonite 11.02 8.47 -2.55 -0.510 0.43573E+04 191 zoisite 22.96 20.46 -2.50 -0.114 0.42750E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.19 -3.63 -0.224 0.61954E+04 194 beidellite-H -2.24 -7.15 -4.91 -0.313 0.83802E+04 195 beidellite-K -1.44 -5.33 -3.90 -0.239 0.66546E+04 196 beidellite-Mg -1.71 -5.71 -4.00 -0.247 0.68277E+04 197 beidellite-Na -1.26 -4.64 -3.38 -0.207 0.57733E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.96 -2.74 -0.170 0.46814E+04 202 montmorillonite-K -2.16 -5.10 -2.94 -0.180 0.50183E+04 203 montmorillonite-Mg -2.40 -5.47 -3.07 -0.190 0.52447E+04 204 montmorillonite-Na -1.96 -4.41 -2.45 -0.150 0.41752E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.82 -1.77 -0.119 0.30298E+04 207 nontronite-K 3.40 2.64 -0.77 -0.049 0.13076E+04 208 nontronite-Mg 3.14 2.26 -0.87 -0.057 0.14932E+04 209 nontronite-Na 3.58 3.33 -0.25 -0.016 0.42807E+03 224 tobermorite 9.84 6.48 -3.36 -0.916 0.57300E+04 233 boehmite 4.43 2.31 -2.12 -0.353 0.36129E+04 235 ferrous-oxide 9.82 6.52 -3.30 -0.826 0.56416E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 1.67 -0.41 -0.031 0.69361E+03 243 an25ab75 2.71 2.17 -0.54 -0.041 0.91492E+03 244 an30ab70 3.34 2.67 -0.67 -0.052 0.11446E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 7.1990000 g New total amount of reactant added: 7.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.9373E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 7.3990000 Water: Moles liquid = 0.5544E+02 kg liquid = 0.9987E+00 Moles total = 0.5542E+02 kg total = 0.9983E+00 Activity = 1.0000 Stoichiometric ionic strength = .4376370E-02 Osmotic coef. = 0.9645 True ionic strength = .7505382E-02 Chg. balance for total moles = -.9373E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.17331E-09 -9.7612 0.15353E-09 -9.8138 0.88588E+00 -0.0526 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13789E-03 -3.8605 0.12183E-03 -3.9143 0.88352E+00 -0.0538 4 SO4-- 0.25522E-04 -4.5931 0.16499E-04 -4.7826 0.64645E+00 -0.1895 5 HCO3- 0.71717E-05 -5.1444 0.63404E-05 -5.1979 0.88408E+00 -0.0535 6 HS- 0.19814E-12 -12.7030 0.17507E-12 -12.7568 0.88357E+00 -0.0538 7 Al+++ 0.18615E-26 -26.7301 0.70914E-27 -27.1493 0.38095E+00 -0.4191 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.30983E-07 -7.5089 0.19964E-07 -7.6997 0.64437E+00 -0.1909 10 Mg++ 0.20939E-10 -10.6790 0.13465E-10 -10.8708 0.64307E+00 -0.1917 11 Fe++ 0.12379E-12 -12.9073 0.79645E-13 -13.0988 0.64338E+00 -0.1915 12 K+ 0.58384E-04 -4.2337 0.51622E-04 -4.2872 0.88418E+00 -0.0535 13 Na+ 0.74146E-02 -2.1299 0.65504E-02 -2.1837 0.88346E+00 -0.0538 14 Mn++ 0.16536E-10 -10.7816 0.10643E-10 -10.9729 0.64362E+00 -0.1914 15 HPO4-- 0.87304E-06 -6.0590 0.56441E-06 -6.2484 0.64649E+00 -0.1894 16 HSiO3- 0.27544E-02 -2.5600 0.24336E-02 -2.6138 0.88352E+00 -0.0538 17 Ca(HSiO3)+ 0.12310E-08 -8.9097 0.10886E-08 -8.9631 0.88427E+00 -0.0534 18 Mg(HSiO3)+ 0.10333E-11 -11.9858 0.91371E-12 -12.0392 0.88427E+00 -0.0534 19 NaHSiO3,aq 0.25318E-03 -3.5966 0.25318E-03 -3.5966 0.10000E+01 0.0000 20 AlO+ 0.43918E-14 -14.3574 0.38836E-14 -14.4108 0.88427E+00 -0.0534 22 HAlO2,aq 0.50617E-08 -8.2957 0.50617E-08 -8.2957 0.10000E+01 0.0000 23 AlO2- 0.83384E-04 -4.0789 0.73613E-04 -4.1330 0.88281E+00 -0.0541 24 CH4,aq 0.66109E-19 -19.1797 0.66020E-19 -19.1803 0.99865E+00 -0.0006 29 CO,aq 0.54888E-19 -19.2605 0.54888E-19 -19.2605 0.10000E+01 0.0000 30 CO2,aq 0.19654E-08 -8.7066 0.19627E-08 -8.7071 0.99865E+00 -0.0006 31 CO3-2 0.59120E-05 -5.2283 0.38182E-05 -5.4181 0.64584E+00 -0.1899 32 CaCO3,aq 0.93361E-09 -9.0298 0.93361E-09 -9.0298 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.36069E-11 -11.4429 0.31895E-11 -11.4963 0.88427E+00 -0.0534 34 CaCl+ 0.43829E-11 -11.3582 0.38757E-11 -11.4117 0.88427E+00 -0.0534 35 CaCl2,aq 0.10994E-15 -15.9589 0.10994E-15 -15.9589 0.10000E+01 0.0000 36 CaOH+ 0.10369E-07 -7.9843 0.91689E-08 -8.0377 0.88427E+00 -0.0534 37 CaSO4,aq 0.10263E-09 -9.9887 0.10263E-09 -9.9887 0.10000E+01 0.0000 38 HCl,aq 0.35183E-14 -14.4537 0.35183E-14 -14.4537 0.10000E+01 0.0000 43 FeCl+ 0.17090E-16 -16.7672 0.15112E-16 -16.8207 0.88427E+00 -0.0534 46 FeO,aq 0.13361E-09 -9.8742 0.13361E-09 -9.8742 0.10000E+01 0.0000 47 FeOH+ 0.19449E-10 -10.7111 0.17198E-10 -10.7645 0.88427E+00 -0.0534 48 HFeO2- 0.10594E-07 -7.9749 0.93600E-08 -8.0287 0.88352E+00 -0.0538 49 FeO+ 0.14363E-14 -14.8428 0.12701E-14 -14.8962 0.88427E+00 -0.0534 51 FeO2- 0.11985E-07 -7.9214 0.10589E-07 -7.9751 0.88352E+00 -0.0538 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.10873E-08 -8.9637 0.10858E-08 -8.9642 0.99865E+00 -0.0006 54 KCl,aq 0.11136E-09 -9.9533 0.11136E-09 -9.9533 0.10000E+01 0.0000 55 KHSO4,aq 0.34992E-18 -18.4560 0.34992E-18 -18.4560 0.10000E+01 0.0000 56 KOH,aq 0.14658E-06 -6.8339 0.14658E-06 -6.8339 0.10000E+01 0.0000 57 KSO4- 0.14851E-07 -7.8282 0.13122E-07 -7.8820 0.88352E+00 -0.0538 58 MgCO3,aq 0.15734E-12 -12.8031 0.15734E-12 -12.8031 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24807E-14 -14.6054 0.21936E-14 -14.6588 0.88427E+00 -0.0534 60 MgCl+ 0.26836E-14 -14.5713 0.23730E-14 -14.6247 0.88427E+00 -0.0534 61 MgOH+ 0.38744E-10 -10.4118 0.34260E-10 -10.4652 0.88427E+00 -0.0534 63 MnO,aq 0.47661E-09 -9.3218 0.47661E-09 -9.3218 0.10000E+01 0.0000 64 MnOH+ 0.24143E-09 -9.6172 0.21349E-09 -9.6706 0.88427E+00 -0.0534 65 MnO2-2 0.10827E-11 -11.9655 0.69923E-12 -12.1554 0.64584E+00 -0.1899 66 HMnO2- 0.26327E-10 -10.5796 0.23260E-10 -10.6334 0.88352E+00 -0.0538 69 MnCl+ 0.88744E-14 -14.0519 0.78473E-14 -14.1053 0.88427E+00 -0.0534 70 MnSO4,aq 0.49763E-13 -13.3031 0.49763E-13 -13.3031 0.10000E+01 0.0000 71 NaCl,aq 0.26057E-06 -6.5841 0.26057E-06 -6.5841 0.10000E+01 0.0000 72 NaOH,aq 0.18747E-04 -4.7271 0.18747E-04 -4.7271 0.10000E+01 0.0000 74 OH- 0.44255E-02 -2.3540 0.39068E-02 -2.4082 0.88281E+00 -0.0541 79 HPO3-2 0.29972E-17 -17.5233 0.19357E-17 -17.7132 0.64584E+00 -0.1899 82 H3PO4,aq 0.85656E-16 -16.0672 0.85656E-16 -16.0672 0.10000E+01 0.0000 83 H2PO4- 0.17189E-08 -8.7648 0.15193E-08 -8.8184 0.88388E+00 -0.0536 84 PO4-3 0.82465E-08 -8.0837 0.32104E-08 -8.4934 0.38931E+00 -0.4097 87 H2P2O7-2 0.27971E-18 -18.5533 0.18065E-18 -18.7432 0.64584E+00 -0.1899 88 HP2O7-3 0.63312E-15 -15.1985 0.24127E-15 -15.6175 0.38108E+00 -0.4190 89 P2O7-4 0.21002E-14 -14.6777 0.38767E-15 -15.4115 0.18459E+00 -0.7338 90 H2S,aq 0.80871E-16 -16.0922 0.80762E-16 -16.0928 0.99865E+00 -0.0006 97 SO3-2 0.37580E-14 -14.4250 0.24426E-14 -14.6121 0.64997E+00 -0.1871 98 HSO3- 0.24841E-16 -16.6048 0.21947E-16 -16.6586 0.88352E+00 -0.0538 99 HSO4- 0.26569E-11 -11.5756 0.23504E-11 -11.6289 0.88464E+00 -0.0532 Charge balance for all species = -.9366E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1733136E-09 -.7791526E-02 -.7849198E+01 0.0000 2 H2O 0.1000000E+01 0.5550985E+02 0.9994927E+06 0.0000 3 Cl- 0.1378883E-03 0.1381489E-03 0.4895180E+01 5.8995 4 SO4-- 0.2552182E-04 0.2553803E-04 0.2451914E+01 14.8450 5 HCO3- 0.7171663E-05 0.1308656E-04 0.7980786E+00 4.6159 6 HS- 0.1981424E-12 -.1251577E-08 -.4137005E-04 -2.9430 7 Al+++ 0.1861499E-26 0.8338951E-04 0.2248773E+01 2.2921 8 H4SiO4 0.3829605E-03 0.3390590E-02 0.3257139E+03 -3.4168 9 Ca++ 0.3098257E-07 0.4362671E-07 0.1747538E-02 11.9278 10 Mg++ 0.2093880E-10 0.6087855E-10 0.1479289E-05 8.7568 11 Fe++ 0.1237919E-12 0.2293596E-07 0.1280221E-02 6.5287 12 K+ 0.5838424E-04 0.5854578E-04 0.2288035E+01 5.5266 13 Na+ 0.7414561E-02 0.7686753E-02 0.1766226E+03 7.6301 14 Mn++ 0.1653620E-10 0.7620451E-09 0.4184288E-04 8.6546 15 HPO4-- 0.8730428E-06 0.8830081E-06 0.8470499E-01 13.3792 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1225034E+00 -.7781669E-02 -.1147217E+00 0.0000000E+00 2 H2O 0.5541550E+02 0.5543963E+02 -.2413075E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2305560E-03 0.2550572E-04 0.2050503E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2050515E-03 -.1249994E-08 -.2050503E-03 0.0000000E+00 7 Al+++ 0.2412623E-01 0.8328402E-04 0.2404294E-01 0.0000000E+00 8 H4SiO4 0.7704418E-01 0.3386301E-02 0.7365788E-01 0.0000000E+00 9 Ca++ 0.8524377E-02 0.4357152E-07 0.8524333E-02 0.0000000E+00 10 Mg++ 0.5872222E-02 0.6080154E-10 0.5872222E-02 0.0000000E+00 11 Fe++ 0.5275551E-02 0.2290694E-07 0.5275528E-02 0.0000000E+00 12 K+ 0.1570913E-02 0.5847172E-04 0.1512441E-02 0.0000000E+00 13 Na+ 0.9447619E-02 0.7677029E-02 0.1770589E-02 0.0000000E+00 14 Mn++ 0.1282883E-03 0.7610811E-09 0.1282875E-03 0.0000000E+00 15 HPO4-- 0.4378415E-04 0.8818911E-06 0.4290226E-04 0.0000000E+00 Chg. balance for solid moles: -.1362E-16 Mass of aqueous solution: 0.999268E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 7.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1771E-02 -2.752 0.4643 -0.333 5.746 0.1782 apatite-OH 0.1430E-04 -4.845 0.7184E-02 -2.144 0.8890E-01 0.2283E-02 clinochlore 0.1174E-02 -2.930 0.6528 -0.185 8.078 0.2483 daphnite 0.7270E-03 -3.138 0.5187 -0.285 6.419 0.1572 chlorite-Mn 0.2566E-04 -4.591 0.1819E-01 -1.740 0.2251 0.5797E-02 hematite 0.8202E-03 -3.086 0.1310 -0.883 1.621 0.2483E-01 lawsonite 0.2285E-03 -3.641 0.7180E-01 -1.144 0.8885 0.2315E-01 microcline 0.1512E-02 -2.820 0.4210 -0.376 5.210 0.1644 stilbite 0.8224E-02 -2.085 5.796 0.763 71.72 2.703 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8.080809 g Volume = 3.507522 cm3 Porosity: 11.4173% V(tot) - V(min): 0.45208E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7.3990000 g log = 0.8692 Original solution: 1000.0103000 g Original solution / Rock added: 135.15 (Water/Rock Ratio), log = 2.1308 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2120E-06 1.0073 0.2247E-06 0.2230E-06 CH4,gas 0.9798E-16 1.0129 0.1044E-15 0.1031E-15 H2,gas 0.1415E-05 1.0006 0.1489E-05 0.1488E-05 H2S,gas 0.2248E-14 0.9959 0.2355E-14 0.2365E-14 S2,gas 0.8907E-37 1.0000 0.9370E-37 0.9370E-37 CO,gas 0.8239E-16 1.0000 0.8667E-16 0.8667E-16 SO3,gas 0.1382E-39 1.0000 0.1454E-39 0.1454E-39 SO2,gas 0.7787E-23 1.0000 0.8192E-23 0.8192E-23 HCl,gas 0.5906E-17 1.0000 0.6212E-17 0.6212E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.01 -8.65 -2.883 0.14767E+05 -6.648 3 CH4,gas 4.81 -13.17 -17.98 -4.495 0.30703E+05 -15.981 4 H2,gas 8.29 0.46 -7.83 -4.473 0.13364E+05 -5.827 5 H2S,gas -5.94 -22.57 -16.63 -8.314 0.28392E+05 -14.628 6 S2,gas -7.03 -46.06 -39.03 -6.004 0.66640E+05 -37.028 7 CO,gas 3.51 -14.55 -18.06 -5.558 0.30841E+05 -16.062 8 SO3,gas 17.43 -24.41 -41.84 -10.459 0.71436E+05 -39.837 9 SO2,gas 1.14 -23.95 -25.09 -6.690 0.42835E+05 -23.087 10 HCl,gas 5.48 -13.73 -19.21 -9.603 0.32795E+05 -17.207 11 acmite 7.74 7.10 -0.64 -0.067 0.10966E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.30 -4.25 -0.213 0.72606E+04 20 analcite 3.37 3.09 -0.28 -0.031 0.48177E+03 21 andalusite 5.06 1.17 -3.89 -0.389 0.66506E+04 22 andradite 39.09 38.13 -0.96 -0.050 0.16343E+04 23 grossular 32.83 30.12 -2.71 -0.136 0.46289E+04 26 annite 20.21 17.15 -3.05 -0.170 0.52161E+04 27 phlogopite 27.15 23.84 -3.31 -0.184 0.56483E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -3.08 -4.07 -1.357 0.69495E+04 36 brucite 12.58 8.76 -3.82 -0.764 0.65222E+04 37 calcite 0.83 -3.08 -3.92 -1.306 0.66882E+04 38 carnegieite-low 9.06 6.51 -2.56 -0.366 0.43698E+04 39 carnegieite-high 10.13 6.51 -3.63 -0.518 0.61967E+04 40 carpholite-Mg 8.65 6.51 -2.14 -0.143 0.36592E+04 41 carpholite-Fe 6.78 4.28 -2.50 -0.167 0.42748E+04 42 celadonite 5.40 2.91 -2.49 -0.147 0.42556E+04 43 celadonite-Fe 3.94 0.68 -3.26 -0.192 0.55609E+04 44 chrysotile 23.94 19.44 -4.50 -0.375 0.76847E+04 50 chloritoid-Mg 13.26 9.92 -3.34 -0.222 0.56979E+04 51 chloritoid-Fe 9.24 7.70 -1.54 -0.103 0.26339E+04 52 chloritoid-Mn 11.46 9.82 -1.64 -0.109 0.28023E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 4.58 -3.85 -0.350 0.65724E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.29 -0.60 -0.101 0.10313E+04 67 diopside 16.22 13.85 -2.36 -0.236 0.40374E+04 68 hedenbergite 14.24 11.62 -2.62 -0.262 0.44762E+04 75 epidote 24.78 24.49 -0.29 -0.014 0.49009E+03 76 clinozoisite 22.92 20.48 -2.44 -0.111 0.41657E+04 77 epidote-Fe 29.94 28.49 -1.44 -0.075 0.24620E+04 78 fayalite 14.08 9.64 -4.44 -0.634 0.75783E+04 79 ferrosilite 11.19 6.22 -4.96 -0.496 0.84757E+04 83 gibbsite 4.10 2.29 -1.81 -0.258 0.30825E+04 84 glaucophane 23.11 18.78 -4.33 -0.117 0.73943E+04 87 greenalite 16.19 12.75 -3.44 -0.287 0.58765E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.09 -1.16 -0.116 0.19848E+04 97 kalsilite 7.62 4.40 -3.22 -0.460 0.54953E+04 98 kaolinite -1.27 -2.25 -0.98 -0.089 0.16670E+04 99 kyanite 4.93 1.17 -3.76 -0.376 0.64274E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.99 -3.18 -0.318 0.54342E+04 105 lizardite 23.29 19.44 -3.85 -0.321 0.65750E+04 107 magnetite 20.13 19.13 -1.01 -0.082 0.17184E+04 108 minnesotaite 10.46 5.92 -4.54 -0.267 0.77551E+04 110 magnesioferrite 26.26 21.35 -4.90 -0.400 0.83715E+04 113 margarite 17.45 14.26 -3.19 -0.128 0.54455E+04 120 muscovite 2.68 2.15 -0.53 -0.031 0.89944E+03 121 paragonite 4.34 4.26 -0.08 -0.005 0.13790E+03 122 nepheline 8.38 6.51 -1.87 -0.268 0.31977E+04 134 phlogopite-Na 29.73 25.94 -3.79 -0.211 0.64702E+04 136 prehnite 19.47 18.19 -1.28 -0.075 0.21804E+04 137 prehnite-Fe 22.59 22.20 -0.39 -0.024 0.66711E+03 138 pumpellyite-Fe 46.47 45.20 -1.27 -0.028 0.21701E+04 139 pumpellyite-Mg 49.19 47.43 -1.77 -0.039 0.30161E+04 145 pyroxmangite 7.42 5.24 -2.18 -0.436 0.37193E+04 146 pyrophyllite -6.10 -9.08 -2.99 -0.187 0.50970E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodonite 7.46 5.24 -2.22 -0.445 0.37985E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.17 -4.15 -0.415 0.70928E+04 164 stilpnomelane-Fe 13.18 12.66 -0.52 -0.016 0.89273E+03 165 stilpnomelane-Mg 27.60 23.80 -3.80 -0.113 0.64875E+04 168 sudoite 21.22 16.43 -4.78 -0.154 0.81697E+04 171 talc 16.55 12.60 -3.95 -0.232 0.67451E+04 174 tephroite 18.11 13.89 -4.22 -0.603 0.72063E+04 177 topaz-H 4.67 1.17 -3.50 -0.318 0.59765E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 8.51 -3.02 -0.603 0.51512E+04 189 wollastonite 10.48 8.51 -1.97 -0.394 0.33651E+04 190 pseudo-wollastonite 11.02 8.51 -2.51 -0.502 0.42837E+04 191 zoisite 22.96 20.48 -2.48 -0.113 0.42382E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.23 -3.67 -0.227 0.62689E+04 194 beidellite-H -2.24 -7.20 -4.96 -0.316 0.84658E+04 195 beidellite-K -1.44 -5.38 -3.94 -0.241 0.67281E+04 196 beidellite-Mg -1.71 -5.75 -4.05 -0.250 0.69109E+04 197 beidellite-Na -1.26 -4.68 -3.42 -0.210 0.58468E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -4.98 -2.77 -0.171 0.47258E+04 202 montmorillonite-K -2.16 -5.13 -2.97 -0.182 0.50627E+04 203 montmorillonite-Mg -2.40 -5.50 -3.10 -0.192 0.52988E+04 204 montmorillonite-Na -1.96 -4.43 -2.47 -0.151 0.42196E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.81 -1.78 -0.119 0.30419E+04 207 nontronite-K 3.40 2.64 -0.77 -0.049 0.13076E+04 208 nontronite-Mg 3.14 2.26 -0.88 -0.057 0.15029E+04 209 nontronite-Na 3.58 3.33 -0.25 -0.016 0.42807E+03 224 tobermorite 9.84 6.52 -3.32 -0.906 0.56687E+04 233 boehmite 4.43 2.29 -2.14 -0.356 0.36497E+04 235 ferrous-oxide 9.82 6.53 -3.30 -0.824 0.56269E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 1.67 -0.41 -0.031 0.69361E+03 243 an25ab75 2.71 2.17 -0.54 -0.041 0.91492E+03 244 an30ab70 3.34 2.67 -0.67 -0.052 0.11446E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 7.3990000 g New total amount of reactant added: 7.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.9371E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 7.5990000 Water: Moles liquid = 0.5544E+02 kg liquid = 0.9987E+00 Moles total = 0.5541E+02 kg total = 0.9983E+00 Activity = 1.0000 Stoichiometric ionic strength = .4467933E-02 Osmotic coef. = 0.9642 True ionic strength = .7691973E-02 Chg. balance for total moles = -.9371E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.16927E-09 -9.7714 0.14978E-09 -9.8245 0.88490E+00 -0.0531 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13789E-03 -3.8605 0.12168E-03 -3.9148 0.88249E+00 -0.0543 4 SO4-- 0.25522E-04 -4.5931 0.16424E-04 -4.7845 0.64352E+00 -0.1914 5 HCO3- 0.70805E-05 -5.1499 0.62526E-05 -5.2039 0.88307E+00 -0.0540 6 HS- 0.22481E-12 -12.6482 0.19840E-12 -12.7024 0.88255E+00 -0.0543 7 Al+++ 0.16641E-26 -26.7788 0.62740E-27 -27.2025 0.37703E+00 -0.4236 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.32623E-07 -7.4865 0.20925E-07 -7.6793 0.64141E+00 -0.1929 10 Mg++ 0.20411E-10 -10.6901 0.13065E-10 -10.8839 0.64008E+00 -0.1938 11 Fe++ 0.12067E-12 -12.9184 0.77277E-13 -13.1120 0.64040E+00 -0.1935 12 K+ 0.59841E-04 -4.2230 0.52850E-04 -4.2770 0.88317E+00 -0.0540 13 Na+ 0.75997E-02 -2.1192 0.67062E-02 -2.1735 0.88243E+00 -0.0543 14 Mn++ 0.16119E-10 -10.7927 0.10326E-10 -10.9860 0.64064E+00 -0.1934 15 HPO4-- 0.78463E-06 -6.1053 0.50496E-06 -6.2967 0.64356E+00 -0.1914 16 HSiO3- 0.28267E-02 -2.5487 0.24946E-02 -2.6030 0.88249E+00 -0.0543 17 Ca(HSiO3)+ 0.13241E-08 -8.8781 0.11695E-08 -8.9320 0.88325E+00 -0.0539 18 Mg(HSiO3)+ 0.10289E-11 -11.9876 0.90875E-12 -12.0416 0.88325E+00 -0.0539 19 NaHSiO3,aq 0.26570E-03 -3.5756 0.26570E-03 -3.5756 0.10000E+01 0.0000 20 AlO+ 0.40874E-14 -14.3886 0.36102E-14 -14.4425 0.88325E+00 -0.0539 22 HAlO2,aq 0.48233E-08 -8.3167 0.48233E-08 -8.3167 0.10000E+01 0.0000 23 AlO2- 0.81544E-04 -4.0886 0.71903E-04 -4.1433 0.88177E+00 -0.0546 24 CH4,aq 0.74219E-19 -19.1295 0.74117E-19 -19.1301 0.99862E+00 -0.0006 29 CO,aq 0.54883E-19 -19.2606 0.54883E-19 -19.2606 0.10000E+01 0.0000 30 CO2,aq 0.18908E-08 -8.7233 0.18882E-08 -8.7239 0.99862E+00 -0.0006 31 CO3-2 0.60036E-05 -5.2216 0.38597E-05 -5.4134 0.64290E+00 -0.1919 32 CaCO3,aq 0.98916E-09 -9.0047 0.98916E-09 -9.0047 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.37324E-11 -11.4280 0.32967E-11 -11.4819 0.88325E+00 -0.0539 34 CaCl+ 0.45937E-11 -11.3378 0.40574E-11 -11.3918 0.88325E+00 -0.0539 35 CaCl2,aq 0.11496E-15 -15.9395 0.11496E-15 -15.9395 0.10000E+01 0.0000 36 CaOH+ 0.11153E-07 -7.9526 0.98508E-08 -8.0065 0.88325E+00 -0.0539 37 CaSO4,aq 0.10708E-09 -9.9703 0.10708E-09 -9.9703 0.10000E+01 0.0000 38 HCl,aq 0.34283E-14 -14.4649 0.34283E-14 -14.4649 0.10000E+01 0.0000 43 FeCl+ 0.16582E-16 -16.7804 0.14646E-16 -16.8343 0.88325E+00 -0.0539 46 FeO,aq 0.13621E-09 -9.8658 0.13621E-09 -9.8658 0.10000E+01 0.0000 47 FeOH+ 0.19365E-10 -10.7130 0.17104E-10 -10.7669 0.88325E+00 -0.0539 48 HFeO2- 0.11084E-07 -7.9553 0.97814E-08 -8.0096 0.88249E+00 -0.0543 49 FeO+ 0.14028E-14 -14.8530 0.12390E-14 -14.9069 0.88325E+00 -0.0539 51 FeO2- 0.12300E-07 -7.9101 0.10855E-07 -7.9644 0.88249E+00 -0.0543 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.11301E-08 -8.9469 0.11285E-08 -8.9475 0.99862E+00 -0.0006 54 KCl,aq 0.11387E-09 -9.9436 0.11387E-09 -9.9436 0.10000E+01 0.0000 55 KHSO4,aq 0.34791E-18 -18.4585 0.34791E-18 -18.4585 0.10000E+01 0.0000 56 KOH,aq 0.15382E-06 -6.8130 0.15382E-06 -6.8130 0.10000E+01 0.0000 57 KSO4- 0.15154E-07 -7.8195 0.13373E-07 -7.8738 0.88249E+00 -0.0543 58 MgCO3,aq 0.15432E-12 -12.8116 0.15432E-12 -12.8116 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23763E-14 -14.6241 0.20989E-14 -14.6780 0.88325E+00 -0.0539 60 MgCl+ 0.26037E-14 -14.5844 0.22998E-14 -14.6383 0.88325E+00 -0.0539 61 MgOH+ 0.38578E-10 -10.4137 0.34074E-10 -10.4676 0.88325E+00 -0.0539 63 MnO,aq 0.48590E-09 -9.3135 0.48590E-09 -9.3135 0.10000E+01 0.0000 64 MnOH+ 0.24039E-09 -9.6191 0.21233E-09 -9.6730 0.88325E+00 -0.0539 65 MnO2-2 0.11651E-11 -11.9337 0.74902E-12 -12.1255 0.64290E+00 -0.1919 66 HMnO2- 0.27544E-10 -10.5600 0.24307E-10 -10.6143 0.88249E+00 -0.0543 69 MnCl+ 0.86103E-14 -14.0650 0.76050E-14 -14.1189 0.88325E+00 -0.0539 70 MnSO4,aq 0.48066E-13 -13.3182 0.48066E-13 -13.3182 0.10000E+01 0.0000 71 NaCl,aq 0.26646E-06 -6.5744 0.26646E-06 -6.5744 0.10000E+01 0.0000 72 NaOH,aq 0.19673E-04 -4.7061 0.19673E-04 -4.7061 0.10000E+01 0.0000 74 OH- 0.45417E-02 -2.3428 0.40047E-02 -2.3974 0.88177E+00 -0.0546 79 HPO3-2 0.27997E-17 -17.5529 0.17999E-17 -17.7447 0.64290E+00 -0.1919 82 H3PO4,aq 0.72933E-16 -16.1371 0.72933E-16 -16.1371 0.10000E+01 0.0000 83 H2PO4- 0.15019E-08 -8.8233 0.13260E-08 -8.8775 0.88286E+00 -0.0541 84 PO4-3 0.76377E-08 -8.1170 0.29442E-08 -8.5310 0.38548E+00 -0.4140 87 H2P2O7-2 0.21405E-18 -18.6695 0.13761E-18 -18.8613 0.64290E+00 -0.1919 88 HP2O7-3 0.49951E-15 -15.3015 0.18839E-15 -15.7249 0.37716E+00 -0.4235 89 P2O7-4 0.17118E-14 -14.7666 0.31029E-15 -15.5082 0.18127E+00 -0.7417 90 H2S,aq 0.89411E-16 -16.0486 0.89288E-16 -16.0492 0.99862E+00 -0.0006 97 SO3-2 0.39055E-14 -14.4083 0.25273E-14 -14.5973 0.64710E+00 -0.1890 98 HSO3- 0.25103E-16 -16.6003 0.22153E-16 -16.6546 0.88249E+00 -0.0543 99 HSO4- 0.25832E-11 -11.5878 0.22826E-11 -11.6416 0.88363E+00 -0.0537 Charge balance for all species = -.9373E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1692651E-09 -.7986219E-02 -.8045227E+01 0.0000 2 H2O 0.1000000E+01 0.5550988E+02 0.9994802E+06 0.0000 3 Cl- 0.1378870E-03 0.1381536E-03 0.4895281E+01 5.9098 4 SO4-- 0.2552237E-04 0.2553892E-04 0.2451967E+01 14.8646 5 HCO3- 0.7080546E-05 0.1308700E-04 0.7980951E+00 4.6206 6 HS- 0.2248084E-12 -.1280166E-08 -.4231450E-04 -2.8779 7 Al+++ 0.1664064E-26 0.8154908E-04 0.2199113E+01 2.2712 8 H4SiO4 0.3829605E-03 0.3475393E-02 0.3338561E+03 -3.4168 9 Ca++ 0.3262344E-07 0.4620490E-07 0.1850787E-02 11.9697 10 Mg++ 0.2041092E-10 0.6017672E-10 0.1462216E-05 8.7652 11 Fe++ 0.1206698E-12 0.2374289E-07 0.1325244E-02 6.5371 12 K+ 0.5984091E-04 0.6001000E-04 0.2345228E+01 5.5476 13 Na+ 0.7599688E-02 0.7885325E-02 0.1811829E+03 7.6510 14 Mn++ 0.1611902E-10 0.7711752E-09 0.4234365E-04 8.6630 15 HPO4-- 0.7846325E-06 0.7937722E-06 0.7614379E-01 13.3523 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1258151E+00 -.7975847E-02 -.1178393E+00 0.0000000E+00 2 H2O 0.5541299E+02 0.5543779E+02 -.2479751E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2360987E-03 0.2550575E-04 0.2105929E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2105942E-03 -.1278504E-08 -.2105929E-03 0.0000000E+00 7 Al+++ 0.2477838E-01 0.8144317E-04 0.2469693E-01 0.0000000E+00 8 H4SiO4 0.7912674E-01 0.3470879E-02 0.7565586E-01 0.0000000E+00 9 Ca++ 0.8754405E-02 0.4614489E-07 0.8754359E-02 0.0000000E+00 10 Mg++ 0.6030952E-02 0.6009856E-10 0.6030952E-02 0.0000000E+00 11 Fe++ 0.5418152E-02 0.2371205E-07 0.5418129E-02 0.0000000E+00 12 K+ 0.1613376E-02 0.5993207E-04 0.1553444E-02 0.0000000E+00 13 Na+ 0.9698667E-02 0.7875084E-02 0.1823583E-02 0.0000000E+00 14 Mn++ 0.1317560E-03 0.7701737E-09 0.1317552E-03 0.0000000E+00 15 HPO4-- 0.4496766E-04 0.7927413E-06 0.4417492E-04 0.0000000E+00 Chg. balance for solid moles: -.1206E-17 Mass of aqueous solution: 0.999248E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 7.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1824E-02 -2.739 0.4782 -0.320 5.761 0.1836 apatite-OH 0.1472E-04 -4.832 0.7397E-02 -2.131 0.8912E-01 0.2350E-02 clinochlore 0.1206E-02 -2.919 0.6704 -0.174 8.078 0.2550 daphnite 0.7467E-03 -3.127 0.5328 -0.273 6.419 0.1614 chlorite-Mn 0.2635E-04 -4.579 0.1868E-01 -1.729 0.2251 0.5954E-02 hematite 0.8424E-03 -3.074 0.1345 -0.871 1.621 0.2550E-01 lawsonite 0.2356E-03 -3.628 0.7404E-01 -1.131 0.8920 0.2387E-01 microcline 0.1553E-02 -2.809 0.4324 -0.364 5.210 0.1689 stilbite 0.8445E-02 -2.073 5.951 0.775 71.71 2.776 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8.299858 g Volume = 3.602462 cm3 Porosity: 10.8213% V(tot) - V(min): 0.43714E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7.5990000 g log = 0.8808 Original solution: 1000.0103000 g Original solution / Rock added: 131.60 (Water/Rock Ratio), log = 2.1192 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.2040E-06 1.0073 0.2161E-06 0.2146E-06 CH4,gas 0.1100E-15 1.0129 0.1172E-15 0.1157E-15 H2,gas 0.1471E-05 1.0006 0.1548E-05 0.1547E-05 H2S,gas 0.2486E-14 0.9959 0.2604E-14 0.2615E-14 S2,gas 0.1008E-36 1.0000 0.1060E-36 0.1060E-36 CO,gas 0.8238E-16 1.0000 0.8666E-16 0.8666E-16 SO3,gas 0.1310E-39 1.0000 0.1378E-39 0.1378E-39 SO2,gas 0.7668E-23 1.0000 0.8066E-23 0.8066E-23 HCl,gas 0.5754E-17 1.0000 0.6053E-17 0.6053E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.03 -8.67 -2.888 0.14796E+05 -6.665 3 CH4,gas 4.81 -13.12 -17.93 -4.483 0.30617E+05 -15.931 4 H2,gas 8.29 0.48 -7.81 -4.463 0.13336E+05 -5.810 5 H2S,gas -5.94 -22.53 -16.58 -8.292 0.28317E+05 -14.584 6 S2,gas -7.03 -46.01 -38.97 -5.996 0.66548E+05 -36.975 7 CO,gas 3.51 -14.55 -18.06 -5.558 0.30841E+05 -16.062 8 SO3,gas 17.43 -24.43 -41.86 -10.465 0.71476E+05 -39.861 9 SO2,gas 1.14 -23.96 -25.09 -6.692 0.42846E+05 -23.093 10 HCl,gas 5.48 -13.74 -19.22 -9.609 0.32814E+05 -17.218 11 acmite 7.74 7.12 -0.62 -0.065 0.10608E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.28 -4.27 -0.213 0.72892E+04 20 analcite 3.37 3.09 -0.28 -0.031 0.48177E+03 21 andalusite 5.06 1.13 -3.94 -0.394 0.67221E+04 22 andradite 39.09 38.26 -0.83 -0.043 0.14197E+04 23 grossular 32.83 30.20 -2.63 -0.131 0.44858E+04 26 annite 20.21 17.18 -3.03 -0.168 0.51732E+04 27 phlogopite 27.15 23.86 -3.28 -0.182 0.56054E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -3.06 -4.04 -1.348 0.69067E+04 36 brucite 12.58 8.77 -3.81 -0.762 0.65079E+04 37 calcite 0.83 -3.06 -3.89 -1.297 0.66453E+04 38 carnegieite-low 9.06 6.51 -2.56 -0.366 0.43698E+04 39 carnegieite-high 10.13 6.51 -3.63 -0.518 0.61967E+04 40 carpholite-Mg 8.65 6.47 -2.18 -0.145 0.37164E+04 41 carpholite-Fe 6.78 4.25 -2.54 -0.169 0.43321E+04 42 celadonite 5.40 2.92 -2.48 -0.146 0.42413E+04 43 celadonite-Fe 3.94 0.69 -3.25 -0.191 0.55466E+04 44 chrysotile 23.94 19.46 -4.48 -0.373 0.76418E+04 50 chloritoid-Mg 13.26 9.89 -3.37 -0.225 0.57552E+04 51 chloritoid-Fe 9.24 7.66 -1.58 -0.105 0.26911E+04 52 chloritoid-Mn 11.46 9.79 -1.67 -0.112 0.28595E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 4.54 -3.89 -0.354 0.66439E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.27 -0.62 -0.104 0.10670E+04 67 diopside 16.22 13.90 -2.31 -0.231 0.39515E+04 68 hedenbergite 14.24 11.67 -2.57 -0.257 0.43903E+04 75 epidote 24.78 24.53 -0.25 -0.012 0.41855E+03 76 clinozoisite 22.92 20.50 -2.42 -0.110 0.41299E+04 77 epidote-Fe 29.94 28.56 -1.38 -0.072 0.23547E+04 78 fayalite 14.08 9.66 -4.42 -0.632 0.75497E+04 79 ferrosilite 11.19 6.24 -4.95 -0.495 0.84471E+04 83 gibbsite 4.10 2.27 -1.83 -0.261 0.31182E+04 84 glaucophane 23.11 18.81 -4.31 -0.116 0.73514E+04 87 greenalite 16.19 12.78 -3.42 -0.285 0.58336E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.09 -1.16 -0.116 0.19848E+04 96 julgoldite 70.57 65.65 -4.93 -0.128 0.84101E+04 97 kalsilite 7.62 4.40 -3.22 -0.460 0.54953E+04 98 kaolinite -1.27 -2.29 -1.02 -0.093 0.17386E+04 99 kyanite 4.93 1.13 -3.81 -0.381 0.64989E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.99 -3.18 -0.318 0.54342E+04 105 lizardite 23.29 19.46 -3.83 -0.319 0.65321E+04 107 magnetite 20.13 19.13 -1.00 -0.081 0.17041E+04 108 minnesotaite 10.46 5.94 -4.52 -0.266 0.77122E+04 110 magnesioferrite 26.26 21.36 -4.89 -0.400 0.83572E+04 113 margarite 17.45 14.22 -3.23 -0.129 0.55170E+04 120 muscovite 2.68 2.11 -0.57 -0.033 0.97098E+03 121 paragonite 4.34 4.21 -0.12 -0.007 0.20945E+03 122 nepheline 8.38 6.51 -1.87 -0.268 0.31977E+04 134 phlogopite-Na 29.73 25.97 -3.76 -0.209 0.64273E+04 136 prehnite 19.47 18.23 -1.24 -0.073 0.21088E+04 137 prehnite-Fe 22.59 22.26 -0.33 -0.020 0.55979E+03 138 pumpellyite-Fe 46.47 45.27 -1.20 -0.027 0.20485E+04 139 pumpellyite-Mg 49.19 47.50 -1.70 -0.038 0.28944E+04 145 pyroxmangite 7.42 5.25 -2.17 -0.434 0.37050E+04 146 pyrophyllite -6.10 -9.13 -3.03 -0.189 0.51686E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodonite 7.46 5.25 -2.22 -0.443 0.37842E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.13 -4.20 -0.420 0.71643E+04 164 stilpnomelane-Fe 13.18 12.67 -0.51 -0.015 0.87484E+03 165 stilpnomelane-Mg 27.60 23.81 -3.79 -0.113 0.64697E+04 168 sudoite 21.22 16.36 -4.85 -0.157 0.82842E+04 171 talc 16.55 12.63 -3.93 -0.231 0.67022E+04 174 tephroite 18.11 13.91 -4.20 -0.601 0.71777E+04 177 topaz-H 4.67 1.13 -3.54 -0.322 0.60480E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 8.55 -2.97 -0.595 0.50797E+04 189 wollastonite 10.48 8.55 -1.93 -0.386 0.32936E+04 190 pseudo-wollastonite 11.02 8.55 -2.47 -0.493 0.42122E+04 191 zoisite 22.96 20.50 -2.46 -0.112 0.42024E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.27 -3.71 -0.230 0.63404E+04 195 beidellite-K -1.44 -5.42 -3.98 -0.244 0.67997E+04 196 beidellite-Mg -1.71 -5.80 -4.09 -0.253 0.69919E+04 197 beidellite-Na -1.26 -4.72 -3.47 -0.212 0.59184E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -5.01 -2.79 -0.173 0.47690E+04 202 montmorillonite-K -2.16 -5.15 -2.99 -0.183 0.51060E+04 203 montmorillonite-Mg -2.40 -5.54 -3.13 -0.194 0.53515E+04 204 montmorillonite-Na -1.96 -4.46 -2.50 -0.153 0.42628E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.81 -1.79 -0.120 0.30537E+04 207 nontronite-K 3.40 2.64 -0.77 -0.049 0.13076E+04 208 nontronite-Mg 3.14 2.25 -0.89 -0.057 0.15123E+04 209 nontronite-Na 3.58 3.33 -0.25 -0.016 0.42807E+03 224 tobermorite 9.84 6.55 -3.29 -0.896 0.56091E+04 233 boehmite 4.43 2.27 -2.16 -0.360 0.36855E+04 235 ferrous-oxide 9.82 6.54 -3.29 -0.822 0.56126E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 1.67 -0.41 -0.031 0.69361E+03 243 an25ab75 2.71 2.17 -0.54 -0.041 0.91492E+03 244 an30ab70 3.34 2.67 -0.67 -0.052 0.11446E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 7.5990000 g New total amount of reactant added: 7.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.9372E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 7.7990000 Water: Moles liquid = 0.5543E+02 kg liquid = 0.9987E+00 Moles total = 0.5541E+02 kg total = 0.9982E+00 Activity = 1.0000 Stoichiometric ionic strength = .4559977E-02 Osmotic coef. = 0.9639 True ionic strength = .7878424E-02 Chg. balance for total moles = -.9372E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.16542E-09 -9.7814 0.14622E-09 -9.8350 0.88394E+00 -0.0536 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13789E-03 -3.8605 0.12154E-03 -3.9153 0.88148E+00 -0.0548 4 SO4-- 0.25523E-04 -4.5931 0.16351E-04 -4.7865 0.64065E+00 -0.1934 5 HCO3- 0.69916E-05 -5.1554 0.61670E-05 -5.2099 0.88207E+00 -0.0545 6 HS- 0.25422E-12 -12.5948 0.22410E-12 -12.6496 0.88154E+00 -0.0548 7 Al+++ 0.14922E-26 -26.8262 0.55690E-27 -27.2542 0.37321E+00 -0.4281 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.34308E-07 -7.4646 0.21906E-07 -7.6594 0.63850E+00 -0.1948 10 Mg++ 0.19912E-10 -10.7009 0.12687E-10 -10.8966 0.63716E+00 -0.1958 11 Fe++ 0.11772E-12 -12.9292 0.75041E-13 -13.1247 0.63748E+00 -0.1955 12 K+ 0.61296E-04 -4.2126 0.54074E-04 -4.2670 0.88217E+00 -0.0544 13 Na+ 0.77847E-02 -2.1088 0.68615E-02 -2.1636 0.88142E+00 -0.0548 14 Mn++ 0.15724E-10 -10.8034 0.10028E-10 -10.9988 0.63772E+00 -0.1954 15 HPO4-- 0.70716E-06 -6.1505 0.45307E-06 -6.3438 0.64069E+00 -0.1934 16 HSiO3- 0.28989E-02 -2.5378 0.25553E-02 -2.5926 0.88148E+00 -0.0548 17 Ca(HSiO3)+ 0.14215E-08 -8.8472 0.12542E-08 -8.9016 0.88226E+00 -0.0544 18 Mg(HSiO3)+ 0.10246E-11 -11.9894 0.90396E-12 -12.0439 0.88226E+00 -0.0544 19 NaHSiO3,aq 0.27848E-03 -3.5552 0.27848E-03 -3.5552 0.10000E+01 0.0000 20 AlO+ 0.38114E-14 -14.4189 0.33626E-14 -14.4733 0.88226E+00 -0.0544 22 HAlO2,aq 0.46020E-08 -8.3371 0.46020E-08 -8.3371 0.10000E+01 0.0000 23 AlO2- 0.79791E-04 -4.0980 0.70275E-04 -4.1532 0.88074E+00 -0.0551 24 CH4,aq 0.83056E-19 -19.0806 0.82939E-19 -19.0812 0.99859E+00 -0.0006 29 CO,aq 0.54868E-19 -19.2607 0.54868E-19 -19.2607 0.10000E+01 0.0000 30 CO2,aq 0.18207E-08 -8.7398 0.18181E-08 -8.7404 0.99859E+00 -0.0006 31 CO3-2 0.60930E-05 -5.2152 0.38996E-05 -5.4090 0.64002E+00 -0.1938 32 CaCO3,aq 0.10462E-08 -8.9804 0.10462E-08 -8.9804 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.38582E-11 -11.4136 0.34039E-11 -11.4680 0.88226E+00 -0.0544 34 CaCl+ 0.48088E-11 -11.3180 0.42426E-11 -11.3724 0.88226E+00 -0.0544 35 CaCl2,aq 0.12007E-15 -15.9206 0.12007E-15 -15.9206 0.10000E+01 0.0000 36 CaOH+ 0.11973E-07 -7.9218 0.10564E-07 -7.9762 0.88226E+00 -0.0544 37 CaSO4,aq 0.11160E-09 -9.9523 0.11160E-09 -9.9523 0.10000E+01 0.0000 38 HCl,aq 0.33429E-14 -14.4759 0.33429E-14 -14.4759 0.10000E+01 0.0000 43 FeCl+ 0.16102E-16 -16.7931 0.14206E-16 -16.8475 0.88226E+00 -0.0544 46 FeO,aq 0.13879E-09 -9.8576 0.13879E-09 -9.8576 0.10000E+01 0.0000 47 FeOH+ 0.19285E-10 -10.7148 0.17014E-10 -10.7692 0.88226E+00 -0.0544 48 HFeO2- 0.11583E-07 -7.9362 0.10210E-07 -7.9910 0.88148E+00 -0.0548 49 FeO+ 0.13710E-14 -14.8630 0.12095E-14 -14.9174 0.88226E+00 -0.0544 51 FeO2- 0.12614E-07 -7.8991 0.11119E-07 -7.9539 0.88148E+00 -0.0548 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.11734E-08 -8.9306 0.11718E-08 -8.9312 0.99859E+00 -0.0006 54 KCl,aq 0.11637E-09 -9.9341 0.11637E-09 -9.9341 0.10000E+01 0.0000 55 KHSO4,aq 0.34596E-18 -18.4610 0.34596E-18 -18.4610 0.10000E+01 0.0000 56 KOH,aq 0.16122E-06 -6.7926 0.16122E-06 -6.7926 0.10000E+01 0.0000 57 KSO4- 0.15453E-07 -7.8110 0.13622E-07 -7.8658 0.88148E+00 -0.0548 58 MgCO3,aq 0.15141E-12 -12.8198 0.15141E-12 -12.8198 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22786E-14 -14.6423 0.20103E-14 -14.6967 0.88226E+00 -0.0544 60 MgCl+ 0.25283E-14 -14.5972 0.22307E-14 -14.6516 0.88226E+00 -0.0544 61 MgOH+ 0.38418E-10 -10.4155 0.33894E-10 -10.4699 0.88226E+00 -0.0544 63 MnO,aq 0.49511E-09 -9.3053 0.49511E-09 -9.3053 0.10000E+01 0.0000 64 MnOH+ 0.23940E-09 -9.6209 0.21121E-09 -9.6753 0.88226E+00 -0.0544 65 MnO2-2 0.12513E-11 -11.9026 0.80087E-12 -12.0964 0.64002E+00 -0.1938 66 HMnO2- 0.28783E-10 -10.5409 0.25372E-10 -10.5956 0.88148E+00 -0.0548 69 MnCl+ 0.83609E-14 -14.0777 0.73765E-14 -14.1321 0.88226E+00 -0.0544 70 MnSO4,aq 0.46468E-13 -13.3328 0.46468E-13 -13.3328 0.10000E+01 0.0000 71 NaCl,aq 0.27231E-06 -6.5649 0.27231E-06 -6.5649 0.10000E+01 0.0000 72 NaOH,aq 0.20620E-04 -4.6857 0.20620E-04 -4.6857 0.10000E+01 0.0000 74 OH- 0.46577E-02 -2.3318 0.41023E-02 -2.3870 0.88074E+00 -0.0551 79 HPO3-2 0.26200E-17 -17.5817 0.16768E-17 -17.7755 0.64002E+00 -0.1938 82 H3PO4,aq 0.62362E-16 -16.2051 0.62362E-16 -16.2051 0.10000E+01 0.0000 83 H2PO4- 0.13170E-08 -8.8804 0.11614E-08 -8.9350 0.88186E+00 -0.0546 84 PO4-3 0.70884E-08 -8.1494 0.27060E-08 -8.5677 0.38175E+00 -0.4182 87 H2P2O7-2 0.16496E-18 -18.7826 0.10558E-18 -18.9764 0.64002E+00 -0.1938 88 HP2O7-3 0.39658E-15 -15.4017 0.14806E-15 -15.8296 0.37334E+00 -0.4279 89 P2O7-4 0.14028E-14 -14.8530 0.24980E-15 -15.6024 0.17807E+00 -0.7494 90 H2S,aq 0.98593E-16 -16.0062 0.98454E-16 -16.0068 0.99859E+00 -0.0006 97 SO3-2 0.40547E-14 -14.3920 0.26124E-14 -14.5830 0.64429E+00 -0.1909 98 HSO3- 0.25360E-16 -16.5959 0.22354E-16 -16.6506 0.88148E+00 -0.0548 99 HSO4- 0.25133E-11 -11.5997 0.22184E-11 -11.6540 0.88265E+00 -0.0542 Charge balance for all species = -.9376E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1654190E-09 -.8181286E-02 -.8241628E+01 0.0000 2 H2O 0.1000000E+01 0.5550991E+02 0.9994677E+06 0.0000 3 Cl- 0.1378858E-03 0.1381583E-03 0.4895382E+01 5.9197 4 SO4-- 0.2552293E-04 0.2553981E-04 0.2452021E+01 14.8835 5 HCO3- 0.6991565E-05 0.1308744E-04 0.7981116E+00 4.6251 6 HS- 0.2542166E-12 -.1308574E-08 -.4325294E-04 -2.8146 7 Al+++ 0.1492210E-26 0.7979525E-04 0.2151790E+01 2.2508 8 H4SiO4 0.3829605E-03 0.3560363E-02 0.3420140E+03 -3.4168 9 Ca++ 0.3430794E-07 0.4886945E-07 0.1957493E-02 12.0105 10 Mg++ 0.1991155E-10 0.5951001E-10 0.1445997E-05 8.7733 11 Fe++ 0.1177163E-12 0.2455817E-07 0.1370732E-02 6.5453 12 K+ 0.6129638E-04 0.6147317E-04 0.2402378E+01 5.5680 13 Na+ 0.7784666E-02 0.8084034E-02 0.1857463E+03 7.6714 14 Mn++ 0.1572437E-10 0.7803236E-09 0.4284541E-04 8.6712 15 HPO4-- 0.7071556E-06 0.7155610E-06 0.6864037E-01 13.3261 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1291268E+00 -.8170386E-02 -.1209564E+00 0.0000000E+00 2 H2O 0.5541049E+02 0.5543595E+02 -.2546393E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2416413E-03 0.2550578E-04 0.2161356E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2161369E-03 -.1306831E-08 -.2161356E-03 0.0000000E+00 7 Al+++ 0.2543052E-01 0.7968893E-04 0.2535083E-01 0.0000000E+00 8 H4SiO4 0.8120929E-01 0.3555619E-02 0.7765368E-01 0.0000000E+00 9 Ca++ 0.8984434E-02 0.4880434E-07 0.8984385E-02 0.0000000E+00 10 Mg++ 0.6189683E-02 0.5943072E-10 0.6189682E-02 0.0000000E+00 11 Fe++ 0.5560754E-02 0.2452545E-07 0.5560729E-02 0.0000000E+00 12 K+ 0.1655839E-02 0.6139126E-04 0.1594447E-02 0.0000000E+00 13 Na+ 0.9949716E-02 0.8073263E-02 0.1876453E-02 0.0000000E+00 14 Mn++ 0.1352237E-03 0.7792839E-09 0.1352229E-03 0.0000000E+00 15 HPO4-- 0.4615118E-04 0.7146076E-06 0.4543657E-04 0.0000000E+00 Chg. balance for solid moles: 0.3551E-17 Mass of aqueous solution: 0.999227E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 7.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1876E-02 -2.727 0.4920 -0.308 5.776 0.1889 apatite-OH 0.1515E-04 -4.820 0.7608E-02 -2.119 0.8931E-01 0.2418E-02 clinochlore 0.1238E-02 -2.907 0.6881 -0.162 8.077 0.2617 daphnite 0.7663E-03 -3.116 0.5468 -0.262 6.418 0.1657 chlorite-Mn 0.2704E-04 -4.568 0.1917E-01 -1.717 0.2251 0.6110E-02 hematite 0.8645E-03 -3.063 0.1381 -0.860 1.621 0.2617E-01 lawsonite 0.2427E-03 -3.615 0.7627E-01 -1.118 0.8953 0.2460E-01 microcline 0.1594E-02 -2.797 0.4438 -0.353 5.210 0.1734 stilbite 0.8666E-02 -2.062 6.107 0.786 71.69 2.848 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8.518892 g Volume = 3.697399 cm3 Porosity: 10.2486% V(tot) - V(min): 0.42220E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7.7990000 g log = 0.8920 Original solution: 1000.0103000 g Original solution / Rock added: 128.22 (Water/Rock Ratio), log = 2.1080 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1964E-06 1.0073 0.2081E-06 0.2066E-06 CH4,gas 0.1231E-15 1.0129 0.1312E-15 0.1295E-15 H2,gas 0.1527E-05 1.0006 0.1607E-05 0.1606E-05 H2S,gas 0.2741E-14 0.9959 0.2871E-14 0.2883E-14 S2,gas 0.1137E-36 1.0000 0.1196E-36 0.1196E-36 CO,gas 0.8236E-16 1.0000 0.8664E-16 0.8664E-16 SO3,gas 0.1242E-39 1.0000 0.1307E-39 0.1307E-39 SO2,gas 0.7554E-23 1.0000 0.7946E-23 0.7946E-23 HCl,gas 0.5611E-17 1.0000 0.5903E-17 0.5903E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.48529E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.04 -8.68 -2.894 0.14824E+05 -6.682 3 CH4,gas 4.81 -13.07 -17.88 -4.471 0.30533E+05 -15.882 4 H2,gas 8.29 0.49 -7.79 -4.454 0.13308E+05 -5.794 5 H2S,gas -5.94 -22.48 -16.54 -8.271 0.28245E+05 -14.542 6 S2,gas -7.03 -45.96 -38.92 -5.988 0.66459E+05 -36.922 7 CO,gas 3.51 -14.55 -18.06 -5.558 0.30841E+05 -16.062 8 SO3,gas 17.43 -24.46 -41.88 -10.471 0.71515E+05 -39.884 9 SO2,gas 1.14 -23.96 -25.10 -6.693 0.42857E+05 -23.100 10 HCl,gas 5.48 -13.75 -19.23 -9.614 0.32833E+05 -17.229 11 acmite 7.74 7.14 -0.60 -0.062 0.10260E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.26 -4.29 -0.214 0.73171E+04 20 analcite 3.37 3.09 -0.28 -0.031 0.48177E+03 21 andalusite 5.06 1.08 -3.98 -0.398 0.67918E+04 22 andradite 39.09 38.38 -0.71 -0.037 0.12107E+04 23 grossular 32.83 30.28 -2.55 -0.127 0.43465E+04 26 annite 20.21 17.20 -3.01 -0.167 0.51314E+04 27 phlogopite 27.15 23.89 -3.26 -0.181 0.55636E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -3.03 -4.02 -1.340 0.68651E+04 36 brucite 12.58 8.77 -3.80 -0.761 0.64940E+04 37 calcite 0.83 -3.03 -3.87 -1.289 0.66037E+04 38 carnegieite-low 9.06 6.51 -2.56 -0.366 0.43698E+04 39 carnegieite-high 10.13 6.51 -3.63 -0.518 0.61967E+04 40 carpholite-Mg 8.65 6.44 -2.21 -0.147 0.37722E+04 41 carpholite-Fe 6.78 4.21 -2.57 -0.171 0.43878E+04 42 celadonite 5.40 2.92 -2.48 -0.146 0.42274E+04 43 celadonite-Fe 3.94 0.70 -3.24 -0.191 0.55327E+04 44 chrysotile 23.94 19.49 -4.45 -0.371 0.76000E+04 50 chloritoid-Mg 13.26 9.86 -3.40 -0.227 0.58109E+04 51 chloritoid-Fe 9.24 7.63 -1.61 -0.107 0.27468E+04 52 chloritoid-Mn 11.46 9.76 -1.71 -0.114 0.29152E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 4.50 -3.93 -0.357 0.67136E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.25 -0.65 -0.108 0.11019E+04 67 diopside 16.22 13.95 -2.27 -0.227 0.38679E+04 68 hedenbergite 14.24 11.72 -2.52 -0.252 0.43067E+04 75 epidote 24.78 24.57 -0.20 -0.010 0.34888E+03 76 clinozoisite 22.92 20.52 -2.40 -0.109 0.40951E+04 77 epidote-Fe 29.94 28.62 -1.32 -0.068 0.22502E+04 78 fayalite 14.08 9.67 -4.41 -0.629 0.75218E+04 79 ferrosilite 11.19 6.26 -4.93 -0.493 0.84192E+04 83 gibbsite 4.10 2.25 -1.85 -0.264 0.31531E+04 84 glaucophane 23.11 18.83 -4.28 -0.116 0.73096E+04 87 greenalite 16.19 12.80 -3.39 -0.283 0.57918E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.09 -1.16 -0.116 0.19848E+04 96 julgoldite 70.57 65.83 -4.75 -0.123 0.81036E+04 97 kalsilite 7.62 4.40 -3.22 -0.460 0.54953E+04 98 kaolinite -1.27 -2.33 -1.06 -0.096 0.18083E+04 99 kyanite 4.93 1.08 -3.85 -0.385 0.65686E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.99 -3.18 -0.318 0.54342E+04 105 lizardite 23.29 19.49 -3.80 -0.317 0.64903E+04 107 magnetite 20.13 19.14 -0.99 -0.081 0.16902E+04 108 minnesotaite 10.46 5.97 -4.49 -0.264 0.76704E+04 110 magnesioferrite 26.26 21.37 -4.89 -0.399 0.83432E+04 113 margarite 17.45 14.18 -3.27 -0.131 0.55867E+04 120 muscovite 2.68 2.07 -0.61 -0.036 0.10406E+04 121 paragonite 4.34 4.17 -0.16 -0.010 0.27911E+03 122 nepheline 8.38 6.51 -1.87 -0.268 0.31977E+04 134 phlogopite-Na 29.73 25.99 -3.74 -0.208 0.63855E+04 136 prehnite 19.47 18.27 -1.19 -0.070 0.20392E+04 137 prehnite-Fe 22.59 22.32 -0.27 -0.016 0.45529E+03 138 pumpellyite-Fe 46.47 45.34 -1.13 -0.025 0.19301E+04 139 pumpellyite-Mg 49.19 47.57 -1.63 -0.036 0.27760E+04 145 pyroxmangite 7.42 5.25 -2.16 -0.432 0.36910E+04 146 pyrophyllite -6.10 -9.17 -3.07 -0.192 0.52382E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodonite 7.46 5.25 -2.21 -0.442 0.37703E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.08 -4.24 -0.424 0.72340E+04 164 stilpnomelane-Fe 13.18 12.68 -0.50 -0.015 0.85743E+03 165 stilpnomelane-Mg 27.60 23.82 -3.78 -0.113 0.64522E+04 168 sudoite 21.22 16.30 -4.92 -0.159 0.83956E+04 171 talc 16.55 12.65 -3.90 -0.229 0.66604E+04 174 tephroite 18.11 13.93 -4.19 -0.598 0.71498E+04 177 topaz-H 4.67 1.08 -3.58 -0.326 0.61177E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 8.59 -2.93 -0.587 0.50100E+04 189 wollastonite 10.48 8.59 -1.89 -0.378 0.32239E+04 190 pseudo-wollastonite 11.02 8.59 -2.43 -0.485 0.41425E+04 191 zoisite 22.96 20.52 -2.44 -0.111 0.41676E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.31 -3.75 -0.232 0.64101E+04 195 beidellite-K -1.44 -5.46 -4.02 -0.246 0.68693E+04 196 beidellite-Mg -1.71 -5.85 -4.14 -0.256 0.70707E+04 197 beidellite-Na -1.26 -4.76 -3.51 -0.215 0.59880E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -5.03 -2.82 -0.174 0.48110E+04 202 montmorillonite-K -2.16 -5.18 -3.02 -0.185 0.51480E+04 203 montmorillonite-Mg -2.40 -5.57 -3.16 -0.196 0.54028E+04 204 montmorillonite-Na -1.96 -4.48 -2.52 -0.154 0.43049E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.80 -1.80 -0.120 0.30652E+04 207 nontronite-K 3.40 2.64 -0.77 -0.049 0.13076E+04 208 nontronite-Mg 3.14 2.25 -0.89 -0.058 0.15215E+04 209 nontronite-Na 3.58 3.33 -0.25 -0.016 0.42807E+03 224 tobermorite 9.84 6.59 -3.25 -0.887 0.55511E+04 233 boehmite 4.43 2.25 -2.18 -0.363 0.37203E+04 235 ferrous-oxide 9.82 6.55 -3.28 -0.820 0.55987E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 1.67 -0.41 -0.031 0.69361E+03 243 an25ab75 2.71 2.17 -0.54 -0.041 0.91492E+03 244 an30ab70 3.34 2.67 -0.67 -0.052 0.11446E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 7.7990000 g New total amount of reactant added: 7.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.9372E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 7.9990000 Water: Moles liquid = 0.5543E+02 kg liquid = 0.9986E+00 Moles total = 0.5541E+02 kg total = 0.9982E+00 Activity = 1.0000 Stoichiometric ionic strength = .4652466E-02 Osmotic coef. = 0.9636 True ionic strength = .8064724E-02 Chg. balance for total moles = -.9372E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.16176E-09 -9.7911 0.14283E-09 -9.8452 0.88299E+00 -0.0540 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13788E-03 -3.8605 0.12141E-03 -3.9158 0.88049E+00 -0.0553 4 SO4-- 0.25523E-04 -4.5931 0.16280E-04 -4.7884 0.63783E+00 -0.1953 5 HCO3- 0.69046E-05 -5.1609 0.60836E-05 -5.2158 0.88109E+00 -0.0550 6 HS- 0.28656E-12 -12.5428 0.25233E-12 -12.5980 0.88055E+00 -0.0552 7 Al+++ 0.13421E-26 -26.8722 0.49587E-27 -27.3046 0.36948E+00 -0.4324 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.36036E-07 -7.4433 0.22906E-07 -7.6400 0.63565E+00 -0.1968 10 Mg++ 0.19438E-10 -10.7113 0.12329E-10 -10.9091 0.63428E+00 -0.1977 11 Fe++ 0.11492E-12 -12.9396 0.72928E-13 -13.1371 0.63461E+00 -0.1975 12 K+ 0.62751E-04 -4.2024 0.55295E-04 -4.2573 0.88119E+00 -0.0549 13 Na+ 0.79695E-02 -2.0986 0.70165E-02 -2.1539 0.88042E+00 -0.0553 14 Mn++ 0.15350E-10 -10.8139 0.97453E-11 -11.0112 0.63486E+00 -0.1973 15 HPO4-- 0.63903E-06 -6.1945 0.40762E-06 -6.3897 0.63787E+00 -0.1953 16 HSiO3- 0.29710E-02 -2.5271 0.26159E-02 -2.5824 0.88049E+00 -0.0553 17 Ca(HSiO3)+ 0.15234E-08 -8.8172 0.13426E-08 -8.8721 0.88128E+00 -0.0549 18 Mg(HSiO3)+ 0.10205E-11 -11.9912 0.89934E-12 -12.0461 0.88128E+00 -0.0549 19 NaHSiO3,aq 0.29152E-03 -3.5353 0.29152E-03 -3.5353 0.10000E+01 0.0000 20 AlO+ 0.35605E-14 -14.4485 0.31378E-14 -14.5034 0.88128E+00 -0.0549 22 HAlO2,aq 0.43961E-08 -8.3569 0.43961E-08 -8.3569 0.10000E+01 0.0000 23 AlO2- 0.78118E-04 -4.1073 0.68723E-04 -4.1629 0.87974E+00 -0.0556 24 CH4,aq 0.92661E-19 -19.0331 0.92528E-19 -19.0337 0.99857E+00 -0.0006 29 CO,aq 0.54844E-19 -19.2609 0.54844E-19 -19.2609 0.10000E+01 0.0000 30 CO2,aq 0.17545E-08 -8.7559 0.17520E-08 -8.7565 0.99857E+00 -0.0006 31 CO3-2 0.61804E-05 -5.2090 0.39381E-05 -5.4047 0.63719E+00 -0.1957 32 CaCO3,aq 0.11048E-08 -8.9567 0.11048E-08 -8.9567 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.39843E-11 -11.3996 0.35113E-11 -11.4545 0.88128E+00 -0.0549 34 CaCl+ 0.50284E-11 -11.2986 0.44314E-11 -11.3535 0.88128E+00 -0.0549 35 CaCl2,aq 0.12527E-15 -15.9022 0.12527E-15 -15.9022 0.10000E+01 0.0000 36 CaOH+ 0.12832E-07 -7.8917 0.11308E-07 -7.9466 0.88128E+00 -0.0549 37 CaSO4,aq 0.11619E-09 -9.9348 0.11619E-09 -9.9348 0.10000E+01 0.0000 38 HCl,aq 0.32617E-14 -14.4866 0.32617E-14 -14.4866 0.10000E+01 0.0000 43 FeCl+ 0.15648E-16 -16.8055 0.13790E-16 -16.8604 0.88128E+00 -0.0549 46 FeO,aq 0.14136E-09 -9.8497 0.14136E-09 -9.8497 0.10000E+01 0.0000 47 FeOH+ 0.19207E-10 -10.7165 0.16927E-10 -10.7714 0.88128E+00 -0.0549 48 HFeO2- 0.12090E-07 -7.9176 0.10645E-07 -7.9729 0.88049E+00 -0.0553 49 FeO+ 0.13407E-14 -14.8727 0.11815E-14 -14.9276 0.88128E+00 -0.0549 51 FeO2- 0.12928E-07 -7.8885 0.11383E-07 -7.9438 0.88049E+00 -0.0553 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.12172E-08 -8.9146 0.12155E-08 -8.9153 0.99857E+00 -0.0006 54 KCl,aq 0.11887E-09 -9.9249 0.11887E-09 -9.9249 0.10000E+01 0.0000 55 KHSO4,aq 0.34407E-18 -18.4634 0.34407E-18 -18.4634 0.10000E+01 0.0000 56 KOH,aq 0.16877E-06 -6.7727 0.16877E-06 -6.7727 0.10000E+01 0.0000 57 KSO4- 0.15751E-07 -7.8027 0.13869E-07 -7.8580 0.88049E+00 -0.0553 58 MgCO3,aq 0.14860E-12 -12.8280 0.14860E-12 -12.8280 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21869E-14 -14.6602 0.19273E-14 -14.7151 0.88128E+00 -0.0549 60 MgCl+ 0.24571E-14 -14.6096 0.21654E-14 -14.6645 0.88128E+00 -0.0549 61 MgOH+ 0.38264E-10 -10.4172 0.33721E-10 -10.4721 0.88128E+00 -0.0549 63 MnO,aq 0.50426E-09 -9.2973 0.50426E-09 -9.2973 0.10000E+01 0.0000 64 MnOH+ 0.23844E-09 -9.6226 0.21013E-09 -9.6775 0.88128E+00 -0.0549 65 MnO2-2 0.13415E-11 -11.8724 0.85481E-12 -12.0681 0.63719E+00 -0.1957 66 HMnO2- 0.30044E-10 -10.5222 0.26453E-10 -10.5775 0.88049E+00 -0.0553 69 MnCl+ 0.81253E-14 -14.0902 0.71607E-14 -14.1450 0.88128E+00 -0.0549 70 MnSO4,aq 0.44962E-13 -13.3472 0.44962E-13 -13.3472 0.10000E+01 0.0000 71 NaCl,aq 0.27815E-06 -6.5557 0.27815E-06 -6.5557 0.10000E+01 0.0000 72 NaOH,aq 0.21585E-04 -4.6658 0.21585E-04 -4.6658 0.10000E+01 0.0000 74 OH- 0.47737E-02 -2.3211 0.41996E-02 -2.3768 0.87974E+00 -0.0556 79 HPO3-2 0.24559E-17 -17.6098 0.15649E-17 -17.8055 0.63719E+00 -0.1957 82 H3PO4,aq 0.53538E-16 -16.2713 0.53538E-16 -16.2713 0.10000E+01 0.0000 83 H2PO4- 0.11588E-08 -8.9360 0.10207E-08 -8.9911 0.88088E+00 -0.0551 84 PO4-3 0.65915E-08 -8.1810 0.24923E-08 -8.6034 0.37811E+00 -0.4224 87 H2P2O7-2 0.12798E-18 -18.8929 0.81546E-19 -19.0886 0.63719E+00 -0.1957 88 HP2O7-3 0.31673E-15 -15.4993 0.11707E-15 -15.9316 0.36961E+00 -0.4323 89 P2O7-4 0.11557E-14 -14.9372 0.20220E-15 -15.6942 0.17496E+00 -0.7571 90 H2S,aq 0.10844E-15 -15.9648 0.10829E-15 -15.9654 0.99857E+00 -0.0006 97 SO3-2 0.42055E-14 -14.3762 0.26980E-14 -14.5690 0.64153E+00 -0.1928 98 HSO3- 0.25613E-16 -16.5915 0.22552E-16 -16.6468 0.88049E+00 -0.0553 99 HSO4- 0.24471E-11 -11.6114 0.21575E-11 -11.6660 0.88167E+00 -0.0547 Charge balance for all species = -.9370E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1617605E-09 -.8376703E-02 -.8438376E+01 0.0000 2 H2O 0.1000000E+01 0.5550994E+02 0.9994552E+06 0.0000 3 Cl- 0.1378846E-03 0.1381629E-03 0.4895483E+01 5.9294 4 SO4-- 0.2552349E-04 0.2554070E-04 0.2452074E+01 14.9020 5 HCO3- 0.6904649E-05 0.1308788E-04 0.7981281E+00 4.6293 6 HS- 0.2865641E-12 -.1336804E-08 -.4418544E-04 -2.7529 7 Al+++ 0.1342066E-26 0.7812205E-04 0.2106642E+01 2.2309 8 H4SiO4 0.3829605E-03 0.3645497E-02 0.3501876E+03 -3.4168 9 Ca++ 0.3603603E-07 0.5162105E-07 0.2067683E-02 12.0503 10 Mg++ 0.1943841E-10 0.5887574E-10 0.1430567E-05 8.7813 11 Fe++ 0.1149179E-12 0.2538172E-07 0.1416681E-02 6.5532 12 K+ 0.6275056E-04 0.6293520E-04 0.2459482E+01 5.5879 13 Na+ 0.7969488E-02 0.8282870E-02 0.1903124E+03 7.6913 14 Mn++ 0.1535046E-10 0.7894874E-09 0.4334801E-04 8.6791 15 HPO4-- 0.6390324E-06 0.6467827E-06 0.6204198E-01 13.3006 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1324385E+00 -.8365260E-02 -.1240733E+00 0.0000000E+00 2 H2O 0.5540798E+02 0.5543411E+02 -.2613001E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2471840E-03 0.2550580E-04 0.2216782E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2216796E-03 -.1334978E-08 -.2216782E-03 0.0000000E+00 7 Al+++ 0.2608267E-01 0.7801533E-04 0.2600466E-01 0.0000000E+00 8 H4SiO4 0.8329185E-01 0.3640517E-02 0.7965133E-01 0.0000000E+00 9 Ca++ 0.9214462E-02 0.5155053E-07 0.9214411E-02 0.0000000E+00 10 Mg++ 0.6348413E-02 0.5879531E-10 0.6348413E-02 0.0000000E+00 11 Fe++ 0.5703356E-02 0.2534705E-07 0.5703330E-02 0.0000000E+00 12 K+ 0.1698301E-02 0.6284923E-04 0.1635452E-02 0.0000000E+00 13 Na+ 0.1020076E-01 0.8271555E-02 0.1929210E-02 0.0000000E+00 14 Mn++ 0.1386914E-03 0.7884089E-09 0.1386906E-03 0.0000000E+00 15 HPO4-- 0.4733470E-04 0.6458991E-06 0.4668880E-04 0.0000000E+00 Chg. balance for solid moles: -.3984E-17 Mass of aqueous solution: 0.999207E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 7.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1929E-02 -2.715 0.5059 -0.296 5.789 0.1942 apatite-OH 0.1556E-04 -4.808 0.7818E-02 -2.107 0.8947E-01 0.2484E-02 clinochlore 0.1270E-02 -2.896 0.7057 -0.151 8.077 0.2684 daphnite 0.7860E-03 -3.105 0.5608 -0.251 6.418 0.1699 chlorite-Mn 0.2774E-04 -4.557 0.1967E-01 -1.706 0.2251 0.6267E-02 hematite 0.8867E-03 -3.052 0.1416 -0.849 1.621 0.2684E-01 lawsonite 0.2498E-03 -3.602 0.7850E-01 -1.105 0.8984 0.2531E-01 microcline 0.1635E-02 -2.786 0.4552 -0.342 5.210 0.1778 stilbite 0.8887E-02 -2.051 6.263 0.797 71.67 2.921 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8.737911 g Volume = 3.792332 cm3 Porosity: 9.6978% V(tot) - V(min): 0.40727E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7.9990000 g log = 0.9030 Original solution: 1000.0103000 g Original solution / Rock added: 125.02 (Water/Rock Ratio), log = 2.0970 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1893E-06 1.0073 0.2005E-06 0.1991E-06 CH4,gas 0.1373E-15 1.0129 0.1463E-15 0.1445E-15 H2,gas 0.1584E-05 1.0006 0.1667E-05 0.1666E-05 H2S,gas 0.3015E-14 0.9959 0.3158E-14 0.3171E-14 S2,gas 0.1278E-36 1.0000 0.1344E-36 0.1344E-36 CO,gas 0.8232E-16 1.0000 0.8660E-16 0.8660E-16 SO3,gas 0.1180E-39 1.0000 0.1242E-39 0.1242E-39 SO2,gas 0.7444E-23 1.0000 0.7831E-23 0.7831E-23 HCl,gas 0.5475E-17 1.0000 0.5759E-17 0.5759E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.06 -8.70 -2.899 0.14851E+05 -6.698 3 CH4,gas 4.81 -13.03 -17.83 -4.459 0.30452E+05 -15.835 4 H2,gas 8.29 0.51 -7.78 -4.445 0.13281E+05 -5.778 5 H2S,gas -5.94 -22.44 -16.50 -8.250 0.28174E+05 -14.501 6 S2,gas -7.03 -45.90 -38.87 -5.980 0.66372E+05 -36.871 7 CO,gas 3.51 -14.55 -18.06 -5.558 0.30841E+05 -16.062 8 SO3,gas 17.43 -24.48 -41.91 -10.476 0.71553E+05 -39.906 9 SO2,gas 1.14 -23.97 -25.11 -6.695 0.42868E+05 -23.106 10 HCl,gas 5.48 -13.76 -19.24 -9.620 0.32851E+05 -17.240 11 acmite 7.74 7.16 -0.58 -0.060 0.99201E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.25 -4.30 -0.215 0.73443E+04 20 analcite 3.37 3.09 -0.28 -0.031 0.48177E+03 21 andalusite 5.06 1.04 -4.02 -0.402 0.68597E+04 22 andradite 39.09 38.50 -0.59 -0.031 0.10070E+04 23 grossular 32.83 30.36 -2.47 -0.123 0.42107E+04 26 annite 20.21 17.23 -2.98 -0.166 0.50907E+04 27 phlogopite 27.15 23.91 -3.23 -0.180 0.55229E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -3.01 -4.00 -1.332 0.68247E+04 36 brucite 12.58 8.78 -3.80 -0.759 0.64804E+04 37 calcite 0.83 -3.01 -3.84 -1.281 0.65633E+04 38 carnegieite-low 9.06 6.51 -2.56 -0.366 0.43698E+04 39 carnegieite-high 10.13 6.51 -3.63 -0.518 0.61967E+04 40 carpholite-Mg 8.65 6.41 -2.24 -0.149 0.38265E+04 41 carpholite-Fe 6.78 4.18 -2.60 -0.173 0.44421E+04 42 celadonite 5.40 2.93 -2.47 -0.145 0.42138E+04 43 celadonite-Fe 3.94 0.70 -3.23 -0.190 0.55191E+04 44 chrysotile 23.94 19.51 -4.43 -0.369 0.75593E+04 50 chloritoid-Mg 13.26 9.83 -3.44 -0.229 0.58652E+04 51 chloritoid-Fe 9.24 7.60 -1.64 -0.109 0.28011E+04 52 chloritoid-Mn 11.46 9.72 -1.74 -0.116 0.29695E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 4.46 -3.97 -0.361 0.67815E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.23 -0.67 -0.111 0.11358E+04 67 diopside 16.22 14.00 -2.22 -0.222 0.37864E+04 68 hedenbergite 14.24 11.77 -2.47 -0.247 0.42253E+04 75 epidote 24.78 24.61 -0.16 -0.008 0.28099E+03 76 clinozoisite 22.92 20.54 -2.38 -0.108 0.40611E+04 77 epidote-Fe 29.94 28.68 -1.26 -0.065 0.21484E+04 78 fayalite 14.08 9.69 -4.39 -0.627 0.74946E+04 79 ferrosilite 11.19 6.27 -4.91 -0.491 0.83921E+04 83 gibbsite 4.10 2.23 -1.87 -0.267 0.31870E+04 84 glaucophane 23.11 18.85 -4.26 -0.115 0.72688E+04 87 greenalite 16.19 12.83 -3.37 -0.281 0.57511E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.09 -1.16 -0.116 0.19848E+04 96 julgoldite 70.57 66.00 -4.57 -0.119 0.78049E+04 97 kalsilite 7.62 4.40 -3.22 -0.460 0.54953E+04 98 kaolinite -1.27 -2.37 -1.10 -0.100 0.18761E+04 99 kyanite 4.93 1.04 -3.89 -0.389 0.66365E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.99 -3.18 -0.318 0.54342E+04 105 lizardite 23.29 19.51 -3.78 -0.315 0.64495E+04 107 magnetite 20.13 19.15 -0.98 -0.080 0.16766E+04 108 minnesotaite 10.46 5.99 -4.47 -0.263 0.76297E+04 110 magnesioferrite 26.26 21.38 -4.88 -0.398 0.83297E+04 113 margarite 17.45 14.14 -3.31 -0.132 0.56546E+04 120 muscovite 2.68 2.03 -0.65 -0.038 0.11085E+04 121 paragonite 4.34 4.13 -0.20 -0.012 0.34700E+03 122 nepheline 8.38 6.51 -1.87 -0.268 0.31977E+04 134 phlogopite-Na 29.73 26.02 -3.72 -0.206 0.63447E+04 136 prehnite 19.47 18.31 -1.15 -0.068 0.19713E+04 137 prehnite-Fe 22.59 22.38 -0.21 -0.012 0.35347E+03 138 pumpellyite-Fe 46.47 45.41 -1.06 -0.024 0.18147E+04 139 pumpellyite-Mg 49.19 47.64 -1.56 -0.035 0.26606E+04 145 pyroxmangite 7.42 5.26 -2.15 -0.431 0.36774E+04 146 pyrophyllite -6.10 -9.21 -3.11 -0.194 0.53061E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodonite 7.46 5.26 -2.20 -0.440 0.37567E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.04 -4.28 -0.428 0.73019E+04 164 stilpnomelane-Fe 13.18 12.69 -0.49 -0.015 0.84046E+03 165 stilpnomelane-Mg 27.60 23.83 -3.77 -0.113 0.64353E+04 168 sudoite 21.22 16.24 -4.98 -0.161 0.85043E+04 171 talc 16.55 12.68 -3.88 -0.228 0.66197E+04 174 tephroite 18.11 13.94 -4.17 -0.596 0.71227E+04 177 topaz-H 4.67 1.04 -3.62 -0.329 0.61856E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 8.63 -2.89 -0.579 0.49421E+04 189 wollastonite 10.48 8.63 -1.85 -0.370 0.31560E+04 190 pseudo-wollastonite 11.02 8.63 -2.39 -0.477 0.40747E+04 191 zoisite 22.96 20.54 -2.42 -0.110 0.41337E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.35 -3.79 -0.235 0.64780E+04 195 beidellite-K -1.44 -5.50 -4.06 -0.249 0.69372E+04 196 beidellite-Mg -1.71 -5.89 -4.19 -0.259 0.71476E+04 197 beidellite-Na -1.26 -4.80 -3.55 -0.217 0.60559E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -5.06 -2.84 -0.176 0.48520E+04 202 montmorillonite-K -2.16 -5.20 -3.04 -0.186 0.51890E+04 203 montmorillonite-Mg -2.40 -5.60 -3.19 -0.198 0.54527E+04 204 montmorillonite-Na -1.96 -4.51 -2.55 -0.156 0.43459E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.79 -1.80 -0.121 0.30764E+04 207 nontronite-K 3.40 2.64 -0.77 -0.049 0.13076E+04 208 nontronite-Mg 3.14 2.24 -0.90 -0.058 0.15305E+04 209 nontronite-Na 3.58 3.33 -0.25 -0.016 0.42807E+03 224 tobermorite 9.84 6.62 -3.22 -0.878 0.54946E+04 233 boehmite 4.43 2.23 -2.20 -0.366 0.37543E+04 235 ferrous-oxide 9.82 6.55 -3.27 -0.818 0.55851E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 1.67 -0.41 -0.031 0.69361E+03 243 an25ab75 2.71 2.17 -0.54 -0.041 0.91492E+03 244 an30ab70 3.34 2.67 -0.67 -0.052 0.11446E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.2000000 g Current total amount of reactant added: 7.9990000 g New total amount of reactant added: 8.1990000 g Mixing fraction reached given limit of 0.8000E+01 TOTMIX = 0.8199E+01 Execution stopped.