File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.13244E+00 0.16176E-09 0.8830 0.00000000E+00 H2O 2 0. 0.55408E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13788E-03 0.8805 0.00000000E+00 SO4-- 4 -2. 0.24718E-03 0.25523E-04 0.6378 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.69046E-05 0.8811 0.00000000E+00 HS- 6 -1. -0.22168E-03 0.28656E-12 0.8805 0.00000000E+00 Al+++ 7 3. 0.26083E-01 0.13421E-26 0.3695 0.00000000E+00 H4SiO4 8 0. 0.83292E-01 0.38296E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.92145E-02 0.36036E-07 0.6356 0.00000000E+00 Mg++ 10 2. 0.63484E-02 0.19438E-10 0.6343 0.00000000E+00 Fe++ 11 2. 0.57034E-02 0.11492E-12 0.6346 0.00000000E+00 K+ 12 1. 0.16983E-02 0.62751E-04 0.8812 0.00000000E+00 Na+ 13 1. 0.10201E-01 0.79695E-02 0.8804 0.00000000E+00 Mn++ 14 2. 0.13869E-03 0.15350E-10 0.6349 0.00000000E+00 HPO4-- 15 -2. 0.47335E-04 0.63903E-06 0.6379 0.00000000E+00 Chg. balance for total moles = 0.8643E-13 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 100.0000 SLIM = 0.200000E+02 TEMP = 100.0000 SINC = 0.4000E+00 TEMPC = 0.0000 TOTMIX = 0.799900E+01 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 4.1996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0107 MnO2-2 65 -2. 40.4376 Ca(HSiO3)+ 17 1. 7.6603 HMnO2- 66 -1. 29.1018 Mg(HSiO3)+ 18 1. 7.5653 MnO4- 67 -1. 83.3383 NaHSiO3,aq 19 0. 7.8098 MnO4-2 68 -2. 81.3024 AlO+ 20 1. 6.8891 MnCl+ 69 1. -0.7819 AlOH+2 21 2. 3.1893 MnSO4,aq 70 0. -2.4524 HAlO2,aq 22 0. 10.5878 NaCl,aq 71 0. 0.4861 AlO2- 23 -1. 16.2390 NaOH,aq 72 0. 12.3571 CH4,aq 24 0. 6.0082 O2,aq 73 0. 53.5759 C2H6,aq 25 0. 12.3556 OH- 74 -1. 12.2220 C3H8,aq 26 0. 17.3423 HO2- 75 -1. 50.7897 C4H10,aq 27 0. 22.3397 H2O2,aq 76 0. 40.0297 ethanol,aq 28 0. 15.3114 H3PO2,aq 77 0. 24.3310 CO,aq 29 0. 4.7087 H2PO2- 78 -1. 26.5491 CO2,aq 30 0. -6.3045 HPO3-2 79 -2. 11.9246 CO3-2 31 -2. 10.0340 H3PO3,aq 80 0. 3.5932 CaCO3,aq 32 0. 5.9460 H2PO3- 81 -1. 5.6314 Ca(HCO3)+ 33 1. -1.4013 H3PO4,aq 82 0. -9.8087 CaCl+ 34 1. -0.2023 H2PO4- 83 -1. -7.2438 CaCl2,aq 35 0. 0.4306 PO4-3 84 -3. 12.0588 CaOH+ 36 1. 10.1517 H4P2O7,aq 85 0. -17.7539 CaSO4,aq 37 0. -2.4936 H3P2O7- 86 -1. -15.8646 HCl,aq 38 0. 0.7256 H2P2O7-2 87 -2. -13.3812 HClO,aq 39 0. 32.4377 HP2O7-3 88 -3. -6.6931 ClO- 40 -1. 39.6416 P2O7-4 89 -4. 2.9147 HClO2,aq 41 0. 70.2060 H2S,aq 90 0. -6.4778 Fe+3 42 3. 8.3763 S2-2 91 -2. 1.2336 FeCl+ 43 1. -0.1924 S3-2 92 -2. -8.7963 FeCl2,aq 44 0. 4.3160 S3- 93 -1. -16.3178 FeCl+2 45 2. 6.5223 S4-2 94 -2. -18.6473 FeO,aq 46 0. 16.4029 S5-2 95 -2. -28.3223 FeOH+ 47 1. 7.4795 SO2,aq 96 0. -0.1980 HFeO2- 48 -1. 24.3713 SO3-2 97 -2. 10.2895 FeO+ 49 1. 11.3812 HSO3- 98 -1. 2.5222 FeOH+2 50 2. 9.1115 HSO4- 99 -1. -2.9675 FeO2- 51 -1. 24.0877 HSO5- 100 -1. 38.8657 HFeO2,aq 52 0. 15.9903 S2O3-2 101 -2. -4.5491 H2,aq 53 0. 9.4241 HS2O3- 102 -1. -6.8007 KCl,aq 54 0. 1.7519 H2S2O3,aq 103 0. -7.9944 KHSO4,aq 55 0. -0.4275 S2O4-2 104 -2. 10.5639 KOH,aq 56 0. 12.3606 HS2O4- 105 -1. 7.6762 KSO4- 57 -1. -1.1877 H2S2O4,aq 106 0. 6.6566 MgCO3,aq 58 0. 6.5483 S2O5-2 107 -2. 10.0891 Mg(HCO3)+ 59 1. -1.4098 S2O6-2 108 -2. 11.5737 MgCl+ 60 1. -0.1603 S2O8-2 109 -2. 42.1139 MgOH+ 61 1. 9.4082 S3O6-2 110 -2. 3.8101 Mn+3 62 3. 19.1332 S4O6-2 111 -2. -17.8301 MnO,aq 63 0. 17.9765 S5O6-2 112 -2. -14.1051 MnOH+ 64 1. 8.5115 113 0. 10.3157 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.984 0.0000E+00 osumilite(2) 124 20.895 0.0000E+00 CO2,gas 2 -6.363 0.0000E+00 osumilite-Fe 125 14.657 0.0000E+00 CH4,gas 3 4.809 0.0000E+00 pargasite 126 65.279 0.0000E+00 H2,gas 4 8.287 0.0000E+00 periclase 127 16.149 0.0000E+00 H2S,gas 5 -5.943 0.0000E+00 periclase-Fe 128 11.639 0.0000E+00 S2,gas 6 -7.033 0.0000E+00 perovskite-Al 129 12.395 0.0000E+00 CO,gas 7 3.510 0.0000E+00 perovskite-Ca 130 23.818 0.0000E+00 SO3,gas 8 17.427 0.0000E+00 perovskite-Fe 131 21.158 0.0000E+00 SO2,gas 9 1.136 0.0000E+00 perovskite-Mg 132 23.132 0.0000E+00 HCl,gas 10 5.479 0.0000E+00 phase_A 133 80.267 0.0000E+00 acmite 11 7.737 0.0000E+00 phlogopite-Na 134 29.731 0.0000E+00 akermanite 12 36.495 0.0000E+00 piemontite(ordered) 135 33.876 0.0000E+00 akimotoite 13 16.606 0.0000E+00 prehnite 136 19.466 0.0000E+00 akimotoite-Fe 14 13.083 0.0000E+00 prehnite-Fe 137 22.587 0.0000E+00 albite-high 15 0.750 0.0000E+00 pumpellyite-Fe 138 46.471 0.0000E+00 albite 16 -0.328 0.1929E-02 pumpellyite-Mg 139 49.194 0.0000E+00 almandine 17 24.545 0.0000E+00 px-Mg-tschermaks 140 19.687 0.0000E+00 pyrope 18 37.348 0.0000E+00 px-Ca-tschermaks 141 18.679 0.0000E+00 spessartine 19 24.550 0.0000E+00 pyrite 142 -21.225 0.0000E+00 analcite 20 3.371 0.0000E+00 pyrrhotite 143 -4.244 0.0000E+00 andalusite 21 5.062 0.0000E+00 pyrrhotiteFe0.875 144 -6.001 0.0000E+00 andradite 22 39.088 0.0000E+00 pyroxmangite 145 7.416 0.0000E+00 grossular 23 32.828 0.0000E+00 pyrophyllite 146 -6.098 0.0000E+00 anhydrite 24 -5.280 0.0000E+00 quartz 147 -2.982 0.0000E+00 ankerite 25 -2.093 0.0000E+00 rankinite 148 40.765 0.0000E+00 annite 26 20.209 0.0000E+00 ringwoodite-Fe 149 15.486 0.0000E+00 phlogopite 27 27.147 0.0000E+00 ringwoodite-Mg 150 27.602 0.0000E+00 biotite-Mn 28 33.034 0.0000E+00 rhodochrosite 151 -0.959 0.0000E+00 anorthite 29 12.798 0.0000E+00 rhodonite 152 7.462 0.0000E+00 anthophyllite 30 51.988 0.0000E+00 sanidine 153 -1.221 0.0000E+00 anthophyllite-Fe 31 29.455 0.0000E+00 sapphirine(351) 154 79.204 0.0000E+00 apatite-OH 32 -17.989 0.1556E-04 siderite 155 -2.588 0.0000E+00 apatite-OH-zs 33 -12.572 0.0000E+00 sillimanite 156 5.321 0.0000E+00 apatite-Cl-zs 34 -16.504 0.0000E+00 sodalite 157 50.255 0.0000E+00 aragonite 35 0.986 0.0000E+00 spinel 158 20.934 0.0000E+00 brucite 36 12.577 0.0000E+00 spurrite 159 59.566 0.0000E+00 calcite 37 0.833 0.0000E+00 staurolite-Fe 160 74.138 0.0000E+00 carnegieite-low 38 9.065 0.0000E+00 staurolite-Mg 161 90.336 0.0000E+00 carnegieite-high 39 10.134 0.0000E+00 staurolite-Mn 162 84.438 0.0000E+00 carpholite-Mg 40 8.650 0.0000E+00 stilbite 163 -7.406 0.8887E-02 carpholite-Fe 41 6.783 0.0000E+00 stilpnomelane-Fe 164 13.179 0.0000E+00 celadonite 42 5.401 0.0000E+00 stilpnomelane-Mg 165 27.596 0.0000E+00 celadonite-Fe 43 3.937 0.0000E+00 stishovite 166 2.721 0.0000E+00 chrysotile 44 23.937 0.0000E+00 sudoite-Fe 167 18.437 0.0000E+00 chondrodite 45 56.542 0.0000E+00 sudoite 168 21.216 0.0000E+00 clinochlore 46 39.193 0.1270E-02 sulfur 169 -9.141 0.0000E+00 daphnite 47 29.094 0.7860E-03 sylvite 170 1.345 0.0000E+00 chlorite-Mn 48 46.985 0.2774E-04 talc 171 16.553 0.0000E+00 chlorite-Al-free 49 47.262 0.0000E+00 talc-Fe 172 13.516 0.0000E+00 chloritoid-Mg 50 13.261 0.0000E+00 talc-tschermaks 173 19.189 0.0000E+00 chloritoid-Fe 51 9.239 0.0000E+00 tephroite 174 18.113 0.0000E+00 chloritoid-Mn 52 11.463 0.0000E+00 tilleyite 175 41.473 0.0000E+00 clinohumite 53 97.255 0.0000E+00 titanite-CaSi 176 15.497 0.0000E+00 coesite 54 -2.369 0.0000E+00 topaz-H 177 4.668 0.0000E+00 cordierite-H 55 23.898 0.0000E+00 tridymite 178 -2.615 0.0000E+00 cordierite 56 24.245 0.0000E+00 tremolite 179 48.003 0.0000E+00 cordierite-Fe 57 20.649 0.0000E+00 ferroactinolite 180 38.596 0.0000E+00 cordierite-Mn 58 25.261 0.0000E+00 troilite-low 181 -4.394 0.0000E+00 corundum 59 8.433 0.0000E+00 tschermakite 182 48.414 0.0000E+00 corundum-MgSi 60 18.905 0.0000E+00 vesuvianite 183 224.056 0.0000E+00 cristobalite 61 -2.549 0.0000E+00 wadeite-Si 184 20.233 0.0000E+00 cummingtonite 62 52.233 0.0000E+00 wadsleyite-Fe 185 15.711 0.0000E+00 cymrite-K 63 1.731 0.0000E+00 wadsleyite-Mg 186 25.878 0.0000E+00 deerite 64 95.982 0.0000E+00 wairakite 187 4.058 0.0000E+00 diaspore 65 2.896 0.0000E+00 walstromite 188 11.528 0.0000E+00 diamond 66 -3.107 0.0000E+00 wollastonite 189 10.482 0.0000E+00 diopside 67 16.215 0.0000E+00 pseudo-wollastonite 190 11.020 0.0000E+00 hedenbergite 68 14.244 0.0000E+00 zoisite 191 22.964 0.0000E+00 dolomite,ordered 69 0.587 0.0000E+00 akaganeite 192 7.768 0.0000E+00 eastonite 70 28.605 0.0000E+00 beidellite-Ca 193 -1.560 0.0000E+00 enstatite 71 17.301 0.0000E+00 beidellite-H 194 -2.241 0.0000E+00 clinoenstatite-HiP 72 18.388 0.0000E+00 beidellite-K 195 -1.435 0.0000E+00 clinoenstatite 73 17.202 0.0000E+00 beidellite-Mg 196 -1.707 0.0000E+00 protoenstatite 74 17.860 0.0000E+00 beidellite-Na 197 -1.257 0.0000E+00 epidote 75 24.775 0.0000E+00 calcium 198 84.043 0.0000E+00 clinozoisite 76 22.921 0.0000E+00 chalcedony 199 -2.794 0.0000E+00 epidote-Fe 77 29.937 0.0000E+00 dawsonite 200 1.714 0.0000E+00 fayalite 78 14.079 0.0000E+00 montmorillonite-Ca 201 -2.214 0.0000E+00 ferrosilite 79 11.188 0.0000E+00 montmorillonite-K 202 -2.161 0.0000E+00 forsterite 80 21.047 0.0000E+00 montmorillonite-Mg 203 -2.402 0.0000E+00 gedrite 81 50.725 0.0000E+00 montmorillonite-Na 204 -1.961 0.0000E+00 gehlenite 82 36.717 0.0000E+00 nontronite-Ca 205 3.280 0.0000E+00 gibbsite 83 4.097 0.0000E+00 nontronite-H 206 2.596 0.0000E+00 glaucophane 84 23.111 0.0000E+00 nontronite-K 207 3.404 0.0000E+00 glaucophane-Fe 85 17.417 0.0000E+00 nontronite-Mg 208 3.139 0.0000E+00 graphite 86 -3.549 0.0000E+00 nontronite-Na 209 3.583 0.0000E+00 greenalite 87 16.194 0.0000E+00 sepiolite 210 24.194 0.0000E+00 grunerite 88 31.364 0.0000E+00 alite 211 58.043 0.0000E+00 halite 89 1.582 0.0000E+00 belite 212 30.461 0.0000E+00 hematite 90 12.598 0.8867E-03 ettringite 213 43.354 0.0000E+00 heulandite 91 -5.707 0.0000E+00 gypsum 214 -4.924 0.0000E+00 hercynite 92 17.345 0.0000E+00 hemicarboaluminate 215 71.028 0.0000E+00 hollandite 93 25.702 0.0000E+00 hydrogarnet 216 60.721 0.0000E+00 iron 94 19.095 0.0000E+00 hydrogarnet-Si 217 50.654 0.0000E+00 jadeite 95 4.251 0.0000E+00 jennite 218 24.386 0.0000E+00 julgoldite 96 70.573 0.0000E+00 monosulfoaluminate 219 53.497 0.0000E+00 kalsilite 97 7.620 0.0000E+00 monocarboaluminate 220 61.966 0.0000E+00 kaolinite 98 -1.273 0.0000E+00 portlandite 221 18.282 0.0000E+00 kyanite 99 4.932 0.0000E+00 stratlingite 222 36.573 0.0000E+00 larnite-bredigite 100 30.714 0.0000E+00 tricarboaluminate 223 70.427 0.0000E+00 laumontite 101 2.975 0.0000E+00 tobermorite 224 9.839 0.0000E+00 lawsonite 102 9.678 0.2498E-03 C4AH13 225 81.870 0.0000E+00 leucite 103 4.168 0.0000E+00 C2AH8 226 45.260 0.0000E+00 lime 104 26.009 0.0000E+00 C3A 227 87.049 0.0000E+00 lizardite 105 23.287 0.0000E+00 C4AF 228 117.550 0.0000E+00 magnesite 106 0.709 0.0000E+00 CAH10 229 28.373 0.0000E+00 magnetite 107 20.133 0.0000E+00 alabandite 230 -0.962 0.0000E+00 minnesotaite 108 10.461 0.0000E+00 alunite 231 -10.224 0.0000E+00 minnesotaite-Mg 109 20.669 0.0000E+00 artinite 232 15.139 0.0000E+00 magnesioferrite 110 26.257 0.0000E+00 boehmite 233 4.430 0.0000E+00 majorite 111 53.314 0.0000E+00 dolomite,disordered 234 1.288 0.0000E+00 manganosite 112 14.068 0.0000E+00 ferrous-oxide 235 9.824 0.0000E+00 margarite 113 17.452 0.0000E+00 huntite 236 3.850 0.0000E+00 meionite 114 45.158 0.0000E+00 hydromagnesite 237 20.077 0.0000E+00 merwinite 115 55.988 0.0000E+00 nesquehonite 238 4.735 0.0000E+00 microcline 116 -2.432 0.1635E-02 potassium-oxide 239 69.039 0.0000E+00 monticellite 117 24.371 0.0000E+00 silica-amorphous 240 -2.080 0.0000E+00 mullite-Al 118 363.258 0.0000E+00 sodium-oxide 241 55.173 0.0000E+00 mullite-Si 119 7.324 0.0000E+00 an20ab80 242 2.079 0.0000E+00 muscovite 120 2.679 0.0000E+00 an25ab75 243 2.709 0.0000E+00 paragonite 121 4.337 0.0000E+00 an30ab70 244 3.344 0.0000E+00 nepheline 122 8.378 0.0000E+00 tr.625ac.25prg.125 245 45.308 0.0000E+00 osumilite(1) 123 21.978 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 7.9990000 g log = 0.9030 Original solution: 1000.0103000 g Original solution / Rock added: 125.02 (Water/Rock Ratio), log = 2.0970 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 7.9990000 Water: Moles liquid = 0.5543E+02 kg liquid = 0.9986E+00 Moles total = 0.5541E+02 kg total = 0.9982E+00 Activity = 1.0000 Stoichiometric ionic strength = .4652466E-02 Osmotic coef. = 0.9636 True ionic strength = .8064724E-02 Chg. balance for total moles = 0.8643E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.16176E-09 -9.7911 0.14283E-09 -9.8452 0.88299E+00 -0.0540 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13788E-03 -3.8605 0.12141E-03 -3.9158 0.88049E+00 -0.0553 4 SO4-- 0.25523E-04 -4.5931 0.16280E-04 -4.7884 0.63783E+00 -0.1953 5 HCO3- 0.69046E-05 -5.1609 0.60836E-05 -5.2158 0.88109E+00 -0.0550 6 HS- 0.28656E-12 -12.5428 0.25233E-12 -12.5980 0.88055E+00 -0.0552 7 Al+++ 0.13421E-26 -26.8722 0.49587E-27 -27.3046 0.36948E+00 -0.4324 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.36036E-07 -7.4433 0.22906E-07 -7.6400 0.63565E+00 -0.1968 10 Mg++ 0.19438E-10 -10.7113 0.12329E-10 -10.9091 0.63428E+00 -0.1977 11 Fe++ 0.11492E-12 -12.9396 0.72928E-13 -13.1371 0.63461E+00 -0.1975 12 K+ 0.62751E-04 -4.2024 0.55295E-04 -4.2573 0.88119E+00 -0.0549 13 Na+ 0.79695E-02 -2.0986 0.70165E-02 -2.1539 0.88042E+00 -0.0553 14 Mn++ 0.15350E-10 -10.8139 0.97453E-11 -11.0112 0.63486E+00 -0.1973 15 HPO4-- 0.63903E-06 -6.1945 0.40762E-06 -6.3897 0.63787E+00 -0.1953 16 HSiO3- 0.29710E-02 -2.5271 0.26159E-02 -2.5824 0.88049E+00 -0.0553 17 Ca(HSiO3)+ 0.15234E-08 -8.8172 0.13426E-08 -8.8721 0.88128E+00 -0.0549 18 Mg(HSiO3)+ 0.10205E-11 -11.9912 0.89934E-12 -12.0461 0.88128E+00 -0.0549 19 NaHSiO3,aq 0.29152E-03 -3.5353 0.29152E-03 -3.5353 0.10000E+01 0.0000 20 AlO+ 0.35605E-14 -14.4485 0.31378E-14 -14.5034 0.88128E+00 -0.0549 22 HAlO2,aq 0.43961E-08 -8.3569 0.43961E-08 -8.3569 0.10000E+01 0.0000 23 AlO2- 0.78118E-04 -4.1073 0.68723E-04 -4.1629 0.87974E+00 -0.0556 24 CH4,aq 0.92661E-19 -19.0331 0.92528E-19 -19.0337 0.99857E+00 -0.0006 29 CO,aq 0.54844E-19 -19.2609 0.54844E-19 -19.2609 0.10000E+01 0.0000 30 CO2,aq 0.17545E-08 -8.7559 0.17520E-08 -8.7565 0.99857E+00 -0.0006 31 CO3-2 0.61804E-05 -5.2090 0.39381E-05 -5.4047 0.63719E+00 -0.1957 32 CaCO3,aq 0.11048E-08 -8.9567 0.11048E-08 -8.9567 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.39843E-11 -11.3996 0.35113E-11 -11.4545 0.88128E+00 -0.0549 34 CaCl+ 0.50284E-11 -11.2986 0.44314E-11 -11.3535 0.88128E+00 -0.0549 35 CaCl2,aq 0.12527E-15 -15.9022 0.12527E-15 -15.9022 0.10000E+01 0.0000 36 CaOH+ 0.12832E-07 -7.8917 0.11308E-07 -7.9466 0.88128E+00 -0.0549 37 CaSO4,aq 0.11619E-09 -9.9348 0.11619E-09 -9.9348 0.10000E+01 0.0000 38 HCl,aq 0.32617E-14 -14.4866 0.32617E-14 -14.4866 0.10000E+01 0.0000 43 FeCl+ 0.15648E-16 -16.8055 0.13790E-16 -16.8604 0.88128E+00 -0.0549 46 FeO,aq 0.14136E-09 -9.8497 0.14136E-09 -9.8497 0.10000E+01 0.0000 47 FeOH+ 0.19207E-10 -10.7165 0.16927E-10 -10.7714 0.88128E+00 -0.0549 48 HFeO2- 0.12090E-07 -7.9176 0.10645E-07 -7.9729 0.88049E+00 -0.0553 49 FeO+ 0.13407E-14 -14.8727 0.11815E-14 -14.9276 0.88128E+00 -0.0549 51 FeO2- 0.12928E-07 -7.8885 0.11383E-07 -7.9438 0.88049E+00 -0.0553 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.12172E-08 -8.9146 0.12155E-08 -8.9153 0.99857E+00 -0.0006 54 KCl,aq 0.11887E-09 -9.9249 0.11887E-09 -9.9249 0.10000E+01 0.0000 55 KHSO4,aq 0.34407E-18 -18.4634 0.34407E-18 -18.4634 0.10000E+01 0.0000 56 KOH,aq 0.16877E-06 -6.7727 0.16877E-06 -6.7727 0.10000E+01 0.0000 57 KSO4- 0.15751E-07 -7.8027 0.13869E-07 -7.8580 0.88049E+00 -0.0553 58 MgCO3,aq 0.14860E-12 -12.8280 0.14860E-12 -12.8280 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21869E-14 -14.6602 0.19273E-14 -14.7151 0.88128E+00 -0.0549 60 MgCl+ 0.24571E-14 -14.6096 0.21654E-14 -14.6645 0.88128E+00 -0.0549 61 MgOH+ 0.38264E-10 -10.4172 0.33721E-10 -10.4721 0.88128E+00 -0.0549 63 MnO,aq 0.50426E-09 -9.2973 0.50426E-09 -9.2973 0.10000E+01 0.0000 64 MnOH+ 0.23844E-09 -9.6226 0.21013E-09 -9.6775 0.88128E+00 -0.0549 65 MnO2-2 0.13415E-11 -11.8724 0.85481E-12 -12.0681 0.63719E+00 -0.1957 66 HMnO2- 0.30044E-10 -10.5222 0.26453E-10 -10.5775 0.88049E+00 -0.0553 69 MnCl+ 0.81253E-14 -14.0902 0.71607E-14 -14.1450 0.88128E+00 -0.0549 70 MnSO4,aq 0.44962E-13 -13.3472 0.44962E-13 -13.3472 0.10000E+01 0.0000 71 NaCl,aq 0.27815E-06 -6.5557 0.27815E-06 -6.5557 0.10000E+01 0.0000 72 NaOH,aq 0.21585E-04 -4.6658 0.21585E-04 -4.6658 0.10000E+01 0.0000 74 OH- 0.47737E-02 -2.3211 0.41996E-02 -2.3768 0.87974E+00 -0.0556 79 HPO3-2 0.24559E-17 -17.6098 0.15649E-17 -17.8055 0.63719E+00 -0.1957 82 H3PO4,aq 0.53538E-16 -16.2713 0.53538E-16 -16.2713 0.10000E+01 0.0000 83 H2PO4- 0.11588E-08 -8.9360 0.10207E-08 -8.9911 0.88088E+00 -0.0551 84 PO4-3 0.65915E-08 -8.1810 0.24923E-08 -8.6034 0.37811E+00 -0.4224 87 H2P2O7-2 0.12798E-18 -18.8929 0.81546E-19 -19.0886 0.63719E+00 -0.1957 88 HP2O7-3 0.31673E-15 -15.4993 0.11707E-15 -15.9316 0.36961E+00 -0.4323 89 P2O7-4 0.11557E-14 -14.9372 0.20220E-15 -15.6942 0.17496E+00 -0.7571 90 H2S,aq 0.10844E-15 -15.9648 0.10829E-15 -15.9654 0.99857E+00 -0.0006 97 SO3-2 0.42055E-14 -14.3762 0.26980E-14 -14.5690 0.64153E+00 -0.1928 98 HSO3- 0.25613E-16 -16.5915 0.22552E-16 -16.6468 0.88049E+00 -0.0553 99 HSO4- 0.24471E-11 -11.6114 0.21575E-11 -11.6660 0.88167E+00 -0.0547 Charge balance for all species = 0.8649E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1617605E-09 -.8376703E-02 -.8438376E+01 0.0000 2 H2O 0.1000000E+01 0.5550994E+02 0.9994552E+06 0.0000 3 Cl- 0.1378846E-03 0.1381629E-03 0.4895483E+01 5.9294 4 SO4-- 0.2552349E-04 0.2554070E-04 0.2452074E+01 14.9020 5 HCO3- 0.6904649E-05 0.1308788E-04 0.7981281E+00 4.6293 6 HS- 0.2865641E-12 -.1336804E-08 -.4418545E-04 -2.7529 7 Al+++ 0.1342066E-26 0.7812205E-04 0.2106642E+01 2.2309 8 H4SiO4 0.3829605E-03 0.3645497E-02 0.3501876E+03 -3.4168 9 Ca++ 0.3603603E-07 0.5162105E-07 0.2067683E-02 12.0503 10 Mg++ 0.1943841E-10 0.5887574E-10 0.1430567E-05 8.7813 11 Fe++ 0.1149179E-12 0.2538172E-07 0.1416681E-02 6.5532 12 K+ 0.6275056E-04 0.6293520E-04 0.2459482E+01 5.5879 13 Na+ 0.7969488E-02 0.8282870E-02 0.1903124E+03 7.6913 14 Mn++ 0.1535046E-10 0.7894874E-09 0.4334801E-04 8.6791 15 HPO4-- 0.6390324E-06 0.6467827E-06 0.6204198E-01 13.3006 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1324385E+00 -.8365260E-02 -.1240733E+00 0.0000000E+00 2 H2O 0.5540798E+02 0.5543411E+02 -.2613001E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2471840E-03 0.2550580E-04 0.2216782E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2216796E-03 -.1334978E-08 -.2216782E-03 0.0000000E+00 7 Al+++ 0.2608267E-01 0.7801533E-04 0.2600466E-01 0.0000000E+00 8 H4SiO4 0.8329185E-01 0.3640517E-02 0.7965133E-01 0.0000000E+00 9 Ca++ 0.9214462E-02 0.5155053E-07 0.9214411E-02 0.0000000E+00 10 Mg++ 0.6348413E-02 0.5879531E-10 0.6348413E-02 0.0000000E+00 11 Fe++ 0.5703356E-02 0.2534705E-07 0.5703330E-02 0.0000000E+00 12 K+ 0.1698301E-02 0.6284923E-04 0.1635452E-02 0.0000000E+00 13 Na+ 0.1020076E-01 0.8271555E-02 0.1929210E-02 0.0000000E+00 14 Mn++ 0.1386914E-03 0.7884089E-09 0.1386906E-03 0.0000000E+00 15 HPO4-- 0.4733470E-04 0.6458991E-06 0.4668880E-04 0.0000000E+00 Chg. balance for solid moles: 0.1480E-16 Mass of aqueous solution: 0.999207E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 7.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1929E-02 -2.715 0.5059 -0.296 5.789 0.1942 apatite-OH 0.1556E-04 -4.808 0.7818E-02 -2.107 0.8947E-01 0.2484E-02 clinochlore 0.1270E-02 -2.896 0.7057 -0.151 8.077 0.2684 daphnite 0.7860E-03 -3.105 0.5608 -0.251 6.418 0.1699 chlorite-Mn 0.2774E-04 -4.557 0.1967E-01 -1.706 0.2251 0.6267E-02 hematite 0.8867E-03 -3.052 0.1416 -0.849 1.621 0.2684E-01 lawsonite 0.2498E-03 -3.602 0.7850E-01 -1.105 0.8984 0.2531E-01 microcline 0.1635E-02 -2.786 0.4552 -0.342 5.210 0.1778 stilbite 0.8887E-02 -2.051 6.263 0.797 71.67 2.921 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8.737911 g Volume = 3.792332 cm3 Porosity: 9.6978% V(tot) - V(min): 0.40727E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7.9990000 g log = 0.9030 Original solution: 1000.0103000 g Original solution / Rock added: 125.02 (Water/Rock Ratio), log = 2.0970 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1893E-06 1.0073 0.2005E-06 0.1991E-06 CH4,gas 0.1373E-15 1.0129 0.1463E-15 0.1445E-15 H2,gas 0.1584E-05 1.0006 0.1667E-05 0.1666E-05 H2S,gas 0.3015E-14 0.9959 0.3158E-14 0.3171E-14 S2,gas 0.1278E-36 1.0000 0.1344E-36 0.1344E-36 CO,gas 0.8232E-16 1.0000 0.8660E-16 0.8660E-16 SO3,gas 0.1180E-39 1.0000 0.1242E-39 0.1242E-39 SO2,gas 0.7444E-23 1.0000 0.7831E-23 0.7831E-23 HCl,gas 0.5475E-17 1.0000 0.5759E-17 0.5759E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.06 -8.70 -2.899 0.14851E+05 -6.698 3 CH4,gas 4.81 -13.03 -17.83 -4.459 0.30452E+05 -15.835 4 H2,gas 8.29 0.51 -7.78 -4.445 0.13281E+05 -5.778 5 H2S,gas -5.94 -22.44 -16.50 -8.250 0.28174E+05 -14.501 6 S2,gas -7.03 -45.90 -38.87 -5.980 0.66372E+05 -36.871 7 CO,gas 3.51 -14.55 -18.06 -5.558 0.30841E+05 -16.062 8 SO3,gas 17.43 -24.48 -41.91 -10.476 0.71553E+05 -39.906 9 SO2,gas 1.14 -23.97 -25.11 -6.695 0.42868E+05 -23.106 10 HCl,gas 5.48 -13.76 -19.24 -9.620 0.32851E+05 -17.240 11 acmite 7.74 7.16 -0.58 -0.060 0.99201E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.25 -4.30 -0.215 0.73443E+04 20 analcite 3.37 3.09 -0.28 -0.031 0.48177E+03 21 andalusite 5.06 1.04 -4.02 -0.402 0.68597E+04 22 andradite 39.09 38.50 -0.59 -0.031 0.10070E+04 23 grossular 32.83 30.36 -2.47 -0.123 0.42107E+04 26 annite 20.21 17.23 -2.98 -0.166 0.50907E+04 27 phlogopite 27.15 23.91 -3.23 -0.180 0.55229E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -3.01 -4.00 -1.332 0.68247E+04 36 brucite 12.58 8.78 -3.80 -0.759 0.64804E+04 37 calcite 0.83 -3.01 -3.84 -1.281 0.65633E+04 38 carnegieite-low 9.06 6.51 -2.56 -0.366 0.43698E+04 39 carnegieite-high 10.13 6.51 -3.63 -0.518 0.61967E+04 40 carpholite-Mg 8.65 6.41 -2.24 -0.149 0.38265E+04 41 carpholite-Fe 6.78 4.18 -2.60 -0.173 0.44421E+04 42 celadonite 5.40 2.93 -2.47 -0.145 0.42138E+04 43 celadonite-Fe 3.94 0.70 -3.23 -0.190 0.55191E+04 44 chrysotile 23.94 19.51 -4.43 -0.369 0.75593E+04 50 chloritoid-Mg 13.26 9.83 -3.44 -0.229 0.58652E+04 51 chloritoid-Fe 9.24 7.60 -1.64 -0.109 0.28011E+04 52 chloritoid-Mn 11.46 9.72 -1.74 -0.116 0.29695E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 4.46 -3.97 -0.361 0.67815E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.23 -0.67 -0.111 0.11358E+04 67 diopside 16.22 14.00 -2.22 -0.222 0.37864E+04 68 hedenbergite 14.24 11.77 -2.47 -0.247 0.42253E+04 75 epidote 24.78 24.61 -0.16 -0.008 0.28099E+03 76 clinozoisite 22.92 20.54 -2.38 -0.108 0.40611E+04 77 epidote-Fe 29.94 28.68 -1.26 -0.065 0.21484E+04 78 fayalite 14.08 9.69 -4.39 -0.627 0.74946E+04 79 ferrosilite 11.19 6.27 -4.91 -0.491 0.83921E+04 83 gibbsite 4.10 2.23 -1.87 -0.267 0.31870E+04 84 glaucophane 23.11 18.85 -4.26 -0.115 0.72688E+04 87 greenalite 16.19 12.83 -3.37 -0.281 0.57511E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.09 -1.16 -0.116 0.19848E+04 96 julgoldite 70.57 66.00 -4.57 -0.119 0.78049E+04 97 kalsilite 7.62 4.40 -3.22 -0.460 0.54953E+04 98 kaolinite -1.27 -2.37 -1.10 -0.100 0.18761E+04 99 kyanite 4.93 1.04 -3.89 -0.389 0.66365E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.99 -3.18 -0.318 0.54342E+04 105 lizardite 23.29 19.51 -3.78 -0.315 0.64495E+04 107 magnetite 20.13 19.15 -0.98 -0.080 0.16766E+04 108 minnesotaite 10.46 5.99 -4.47 -0.263 0.76297E+04 110 magnesioferrite 26.26 21.38 -4.88 -0.398 0.83297E+04 113 margarite 17.45 14.14 -3.31 -0.132 0.56546E+04 120 muscovite 2.68 2.03 -0.65 -0.038 0.11085E+04 121 paragonite 4.34 4.13 -0.20 -0.012 0.34700E+03 122 nepheline 8.38 6.51 -1.87 -0.268 0.31977E+04 134 phlogopite-Na 29.73 26.02 -3.72 -0.206 0.63447E+04 136 prehnite 19.47 18.31 -1.15 -0.068 0.19713E+04 137 prehnite-Fe 22.59 22.38 -0.21 -0.012 0.35347E+03 138 pumpellyite-Fe 46.47 45.41 -1.06 -0.024 0.18147E+04 139 pumpellyite-Mg 49.19 47.64 -1.56 -0.035 0.26606E+04 145 pyroxmangite 7.42 5.26 -2.15 -0.431 0.36774E+04 146 pyrophyllite -6.10 -9.21 -3.11 -0.194 0.53061E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodonite 7.46 5.26 -2.20 -0.440 0.37567E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 1.04 -4.28 -0.428 0.73019E+04 164 stilpnomelane-Fe 13.18 12.69 -0.49 -0.015 0.84046E+03 165 stilpnomelane-Mg 27.60 23.83 -3.77 -0.113 0.64353E+04 168 sudoite 21.22 16.24 -4.98 -0.161 0.85043E+04 171 talc 16.55 12.68 -3.88 -0.228 0.66197E+04 174 tephroite 18.11 13.94 -4.17 -0.596 0.71227E+04 177 topaz-H 4.67 1.04 -3.62 -0.329 0.61856E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 8.63 -2.89 -0.579 0.49421E+04 189 wollastonite 10.48 8.63 -1.85 -0.370 0.31560E+04 190 pseudo-wollastonite 11.02 8.63 -2.39 -0.477 0.40747E+04 191 zoisite 22.96 20.54 -2.42 -0.110 0.41337E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.35 -3.79 -0.235 0.64780E+04 195 beidellite-K -1.44 -5.50 -4.06 -0.249 0.69372E+04 196 beidellite-Mg -1.71 -5.89 -4.19 -0.259 0.71476E+04 197 beidellite-Na -1.26 -4.80 -3.55 -0.217 0.60559E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -5.06 -2.84 -0.176 0.48520E+04 202 montmorillonite-K -2.16 -5.20 -3.04 -0.186 0.51890E+04 203 montmorillonite-Mg -2.40 -5.60 -3.19 -0.198 0.54527E+04 204 montmorillonite-Na -1.96 -4.51 -2.55 -0.156 0.43459E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.79 -1.80 -0.121 0.30764E+04 207 nontronite-K 3.40 2.64 -0.77 -0.049 0.13076E+04 208 nontronite-Mg 3.14 2.24 -0.90 -0.058 0.15305E+04 209 nontronite-Na 3.58 3.33 -0.25 -0.016 0.42807E+03 224 tobermorite 9.84 6.62 -3.22 -0.878 0.54946E+04 233 boehmite 4.43 2.23 -2.20 -0.366 0.37543E+04 235 ferrous-oxide 9.82 6.55 -3.27 -0.818 0.55851E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 1.67 -0.41 -0.031 0.69361E+03 243 an25ab75 2.71 2.17 -0.54 -0.041 0.91492E+03 244 an30ab70 3.34 2.67 -0.67 -0.052 0.11446E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 7.9990000 g New total amount of reactant added: 8.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8640E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8.3990000 Water: Moles liquid = 0.5543E+02 kg liquid = 0.9986E+00 Moles total = 0.5540E+02 kg total = 0.9981E+00 Activity = 1.0000 Stoichiometric ionic strength = .4838651E-02 Osmotic coef. = 0.9630 True ionic strength = .8436842E-02 Chg. balance for total moles = 0.8640E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15495E-09 -9.8098 0.13654E-09 -9.8648 0.88114E+00 -0.0550 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13788E-03 -3.8605 0.12114E-03 -3.9167 0.87855E+00 -0.0562 4 SO4-- 0.25525E-04 -4.5930 0.16141E-04 -4.7921 0.63236E+00 -0.1990 5 HCO3- 0.67368E-05 -5.1715 0.59228E-05 -5.2275 0.87917E+00 -0.0559 6 HS- 0.36091E-12 -12.4426 0.31710E-12 -12.4988 0.87861E+00 -0.0562 7 Al+++ 0.10946E-26 -26.9607 0.39658E-27 -27.4017 0.36230E+00 -0.4409 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.39623E-07 -7.4021 0.24967E-07 -7.6026 0.63011E+00 -0.2006 10 Mg++ 0.18563E-10 -10.7314 0.11671E-10 -10.9329 0.62871E+00 -0.2016 11 Fe++ 0.10974E-12 -12.9596 0.69031E-13 -13.1610 0.62904E+00 -0.2013 12 K+ 0.65655E-04 -4.1827 0.57729E-04 -4.2386 0.87928E+00 -0.0559 13 Na+ 0.83386E-02 -2.0789 0.73253E-02 -2.1352 0.87848E+00 -0.0563 14 Mn++ 0.14659E-10 -10.8339 0.92246E-11 -11.0351 0.62930E+00 -0.2011 15 HPO4-- 0.52578E-06 -6.2792 0.33250E-06 -6.4782 0.63241E+00 -0.1990 16 HSiO3- 0.31149E-02 -2.5066 0.27366E-02 -2.5628 0.87855E+00 -0.0562 17 Ca(HSiO3)+ 0.17408E-08 -8.7592 0.15308E-08 -8.8151 0.87937E+00 -0.0558 18 Mg(HSiO3)+ 0.10127E-11 -11.9945 0.89054E-12 -12.0503 0.87937E+00 -0.0558 19 NaHSiO3,aq 0.31839E-03 -3.4970 0.31839E-03 -3.4970 0.10000E+01 0.0000 20 AlO+ 0.31231E-14 -14.5054 0.27463E-14 -14.5612 0.87937E+00 -0.0558 22 HAlO2,aq 0.40251E-08 -8.3952 0.40251E-08 -8.3952 0.10000E+01 0.0000 23 AlO2- 0.74992E-04 -4.1250 0.65826E-04 -4.1816 0.87777E+00 -0.0566 24 CH4,aq 0.11435E-18 -18.9418 0.11418E-18 -18.9424 0.99851E+00 -0.0006 29 CO,aq 0.54770E-19 -19.2615 0.54770E-19 -19.2615 0.10000E+01 0.0000 30 CO2,aq 0.16329E-08 -8.7870 0.16304E-08 -8.7877 0.99851E+00 -0.0006 31 CO3-2 0.63491E-05 -5.1973 0.40108E-05 -5.3968 0.63170E+00 -0.1995 32 CaCO3,aq 0.12264E-08 -8.9114 0.12264E-08 -8.9114 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.42371E-11 -11.3729 0.37260E-11 -11.4288 0.87937E+00 -0.0558 34 CaCl+ 0.54805E-11 -11.2612 0.48193E-11 -11.3170 0.87937E+00 -0.0558 35 CaCl2,aq 0.13593E-15 -15.8667 0.13593E-15 -15.8667 0.10000E+01 0.0000 36 CaOH+ 0.14663E-07 -7.8338 0.12894E-07 -7.8896 0.87937E+00 -0.0558 37 CaSO4,aq 0.12556E-09 -9.9011 0.12556E-09 -9.9011 0.10000E+01 0.0000 38 HCl,aq 0.31110E-14 -14.5071 0.31110E-14 -14.5071 0.10000E+01 0.0000 43 FeCl+ 0.14811E-16 -16.8294 0.13024E-16 -16.8852 0.87937E+00 -0.0558 46 FeO,aq 0.14643E-09 -9.8344 0.14643E-09 -9.8344 0.10000E+01 0.0000 47 FeOH+ 0.19061E-10 -10.7199 0.16762E-10 -10.7757 0.87937E+00 -0.0558 48 HFeO2- 0.13130E-07 -7.8817 0.11536E-07 -7.9380 0.87855E+00 -0.0562 49 FeO+ 0.12844E-14 -14.8913 0.11294E-14 -14.9471 0.87937E+00 -0.0558 51 FeO2- 0.13554E-07 -7.8679 0.11908E-07 -7.9242 0.87855E+00 -0.0562 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.13062E-08 -8.8840 0.13043E-08 -8.8846 0.99851E+00 -0.0006 54 KCl,aq 0.12382E-09 -9.9072 0.12382E-09 -9.9072 0.10000E+01 0.0000 55 KHSO4,aq 0.34044E-18 -18.4680 0.34044E-18 -18.4680 0.10000E+01 0.0000 56 KOH,aq 0.18432E-06 -6.7344 0.18432E-06 -6.7344 0.10000E+01 0.0000 57 KSO4- 0.16340E-07 -7.7867 0.14356E-07 -7.8430 0.87855E+00 -0.0562 58 MgCO3,aq 0.14325E-12 -12.8439 0.14325E-12 -12.8439 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20197E-14 -14.6947 0.17761E-14 -14.7505 0.87937E+00 -0.0558 60 MgCl+ 0.23257E-14 -14.6335 0.20451E-14 -14.6893 0.87937E+00 -0.0558 61 MgOH+ 0.37972E-10 -10.4205 0.33391E-10 -10.4764 0.87937E+00 -0.0558 63 MnO,aq 0.52236E-09 -9.2820 0.52236E-09 -9.2820 0.10000E+01 0.0000 64 MnOH+ 0.23662E-09 -9.6260 0.20807E-09 -9.6818 0.87937E+00 -0.0558 65 MnO2-2 0.15340E-11 -11.8142 0.96905E-12 -12.0137 0.63170E+00 -0.1995 66 HMnO2- 0.32630E-10 -10.4864 0.28667E-10 -10.5426 0.87855E+00 -0.0562 69 MnCl+ 0.76907E-14 -14.1140 0.67630E-14 -14.1699 0.87937E+00 -0.0558 70 MnSO4,aq 0.42196E-13 -13.3747 0.42196E-13 -13.3747 0.10000E+01 0.0000 71 NaCl,aq 0.28975E-06 -6.5380 0.28975E-06 -6.5380 0.10000E+01 0.0000 72 NaOH,aq 0.23575E-04 -4.6276 0.23575E-04 -4.6276 0.10000E+01 0.0000 74 OH- 0.50050E-02 -2.3006 0.43932E-02 -2.3572 0.87777E+00 -0.0566 79 HPO3-2 0.21684E-17 -17.6639 0.13698E-17 -17.8633 0.63170E+00 -0.1995 82 H3PO4,aq 0.39906E-16 -16.3990 0.39906E-16 -16.3990 0.10000E+01 0.0000 83 H2PO4- 0.90555E-09 -9.0431 0.79593E-09 -9.0991 0.87895E+00 -0.0560 84 PO4-3 0.57310E-08 -8.2418 0.21268E-08 -8.6723 0.37110E+00 -0.4305 87 H2P2O7-2 0.78488E-19 -19.1052 0.49581E-19 -19.3047 0.63170E+00 -0.1995 88 HP2O7-3 0.20545E-15 -15.6873 0.74463E-16 -16.1281 0.36244E+00 -0.4408 89 P2O7-4 0.79585E-15 -15.0992 0.13454E-15 -15.8711 0.16906E+00 -0.7720 90 H2S,aq 0.13028E-15 -15.8851 0.13008E-15 -15.8858 0.99851E+00 -0.0006 97 SO3-2 0.45120E-14 -14.3456 0.28704E-14 -14.5421 0.63617E+00 -0.1964 98 HSO3- 0.26106E-16 -16.5833 0.22936E-16 -16.6395 0.87855E+00 -0.0562 99 HSO4- 0.23242E-11 -11.6337 0.20448E-11 -11.6893 0.87978E+00 -0.0556 Charge balance for all species = 0.8705E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1549530E-09 -.8768490E-02 -.8832816E+01 0.0000 2 H2O 0.1000000E+01 0.5551000E+02 0.9994300E+06 0.0000 3 Cl- 0.1378824E-03 0.1381722E-03 0.4895685E+01 5.9480 4 SO4-- 0.2552461E-04 0.2554247E-04 0.2452181E+01 14.9374 5 HCO3- 0.6736753E-05 0.1308876E-04 0.7981610E+00 4.6373 6 HS- 0.3609062E-12 -.1392736E-08 -.4603295E-04 -2.6341 7 Al+++ 0.1094617E-26 0.7499626E-04 0.2022299E+01 2.1926 8 H4SiO4 0.3829605E-03 0.3816250E-02 0.3665806E+03 -3.4168 9 Ca++ 0.3962288E-07 0.5738814E-07 0.2298624E-02 12.1269 10 Mg++ 0.1856298E-10 0.5769510E-10 0.1401843E-05 8.7966 11 Fe++ 0.1097402E-12 0.2705320E-07 0.1509935E-02 6.5686 12 K+ 0.6565488E-04 0.6585566E-04 0.2573545E+01 5.6261 13 Na+ 0.8338635E-02 0.8680884E-02 0.1994522E+03 7.7296 14 Mn++ 0.1465861E-10 0.8078518E-09 0.4435517E-04 8.6945 15 HPO4-- 0.5257769E-06 0.5324135E-06 0.5106989E-01 13.2513 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1390619E+00 -.8755921E-02 -.1303060E+00 0.0000000E+00 2 H2O 0.5540297E+02 0.5543043E+02 -.2746126E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2582694E-03 0.2550586E-04 0.2327635E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2327649E-03 -.1390739E-08 -.2327635E-03 0.0000000E+00 7 Al+++ 0.2738697E-01 0.7488876E-04 0.2731208E-01 0.0000000E+00 8 H4SiO4 0.8745696E-01 0.3810780E-02 0.8364618E-01 0.0000000E+00 9 Ca++ 0.9674519E-02 0.5730588E-07 0.9674462E-02 0.0000000E+00 10 Mg++ 0.6665873E-02 0.5761240E-10 0.6665873E-02 0.0000000E+00 11 Fe++ 0.5988559E-02 0.2701442E-07 0.5988532E-02 0.0000000E+00 12 K+ 0.1783227E-02 0.6576127E-04 0.1717466E-02 0.0000000E+00 13 Na+ 0.1070286E-01 0.8668441E-02 0.2034421E-02 0.0000000E+00 14 Mn++ 0.1456269E-03 0.8066938E-09 0.1456261E-03 0.0000000E+00 15 HPO4-- 0.4970173E-04 0.5316503E-06 0.4917008E-04 0.0000000E+00 Chg. balance for solid moles: 0.3507E-16 Mass of aqueous solution: 0.999165E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2034E-02 -2.692 0.5335 -0.273 5.814 0.2048 apatite-OH 0.1639E-04 -4.785 0.8233E-02 -2.084 0.8972E-01 0.2616E-02 clinochlore 0.1333E-02 -2.875 0.7410 -0.130 8.076 0.2819 daphnite 0.8253E-03 -3.083 0.5888 -0.230 6.417 0.1784 chlorite-Mn 0.2913E-04 -4.536 0.2065E-01 -1.685 0.2250 0.6580E-02 hematite 0.9311E-03 -3.031 0.1487 -0.828 1.620 0.2818E-01 lawsonite 0.2640E-03 -3.578 0.8295E-01 -1.081 0.9040 0.2675E-01 microcline 0.1717E-02 -2.765 0.4780 -0.321 5.210 0.1867 stilbite 0.9329E-02 -2.030 6.574 0.818 71.64 3.066 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9.175907 g Volume = 3.982188 cm3 Porosity: 8.6570% V(tot) - V(min): 0.37741E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8.3990000 g log = 0.9242 Original solution: 1000.0103000 g Original solution / Rock added: 119.06 (Water/Rock Ratio), log = 2.0758 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1761E-06 1.0073 0.1866E-06 0.1853E-06 CH4,gas 0.1695E-15 1.0129 0.1806E-15 0.1783E-15 H2,gas 0.1700E-05 1.0006 0.1789E-05 0.1788E-05 H2S,gas 0.3621E-14 0.9959 0.3794E-14 0.3809E-14 S2,gas 0.1601E-36 1.0000 0.1685E-36 0.1685E-36 CO,gas 0.8221E-16 1.0000 0.8648E-16 0.8648E-16 SO3,gas 0.1069E-39 1.0000 0.1125E-39 0.1125E-39 SO2,gas 0.7237E-23 1.0000 0.7613E-23 0.7613E-23 HCl,gas 0.5222E-17 1.0000 0.5493E-17 0.5493E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.15165E-10 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.09 -8.73 -2.910 0.14905E+05 -6.729 3 CH4,gas 4.81 -12.93 -17.74 -4.436 0.30296E+05 -15.743 4 H2,gas 8.29 0.54 -7.75 -4.427 0.13228E+05 -5.747 5 H2S,gas -5.94 -22.36 -16.42 -8.210 0.28038E+05 -14.421 6 S2,gas -7.03 -45.81 -38.77 -5.965 0.66205E+05 -36.773 7 CO,gas 3.51 -14.55 -18.06 -5.558 0.30842E+05 -16.063 8 SO3,gas 17.43 -24.52 -41.95 -10.487 0.71627E+05 -39.949 9 SO2,gas 1.14 -23.98 -25.12 -6.698 0.42889E+05 -23.118 10 HCl,gas 5.48 -13.78 -19.26 -9.630 0.32886E+05 -17.260 11 acmite 7.74 7.19 -0.54 -0.056 0.92664E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.22 -4.33 -0.217 0.73966E+04 20 analcite 3.37 3.09 -0.28 -0.031 0.48177E+03 21 andalusite 5.06 0.97 -4.09 -0.409 0.69904E+04 22 andradite 39.09 38.73 -0.36 -0.019 0.61476E+03 23 grossular 32.83 30.52 -2.31 -0.116 0.39493E+04 26 annite 20.21 17.27 -2.94 -0.163 0.50122E+04 27 phlogopite 27.15 23.96 -3.19 -0.177 0.54444E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.97 -3.95 -1.317 0.67472E+04 36 brucite 12.58 8.80 -3.78 -0.756 0.64542E+04 37 calcite 0.83 -2.97 -3.80 -1.266 0.64859E+04 38 carnegieite-low 9.06 6.51 -2.56 -0.366 0.43698E+04 39 carnegieite-high 10.13 6.51 -3.63 -0.518 0.61967E+04 40 carpholite-Mg 8.65 6.35 -2.30 -0.153 0.39311E+04 41 carpholite-Fe 6.78 4.12 -2.66 -0.178 0.45467E+04 42 celadonite 5.40 2.95 -2.45 -0.144 0.41876E+04 43 celadonite-Fe 3.94 0.72 -3.22 -0.189 0.54930E+04 44 chrysotile 23.94 19.56 -4.38 -0.365 0.74808E+04 50 chloritoid-Mg 13.26 9.76 -3.50 -0.233 0.59698E+04 51 chloritoid-Fe 9.24 7.54 -1.70 -0.113 0.29057E+04 52 chloritoid-Mn 11.46 9.66 -1.80 -0.120 0.30741E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 4.39 -4.05 -0.368 0.69122E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.19 -0.70 -0.117 0.12012E+04 67 diopside 16.22 14.09 -2.13 -0.213 0.36295E+04 68 hedenbergite 14.24 11.86 -2.38 -0.238 0.40684E+04 75 epidote 24.78 24.69 -0.09 -0.004 0.15025E+03 76 clinozoisite 22.92 20.58 -2.34 -0.106 0.39957E+04 77 epidote-Fe 29.94 28.79 -1.14 -0.059 0.19522E+04 78 fayalite 14.08 9.72 -4.36 -0.623 0.74423E+04 79 ferrosilite 11.19 6.30 -4.88 -0.488 0.83398E+04 83 gibbsite 4.10 2.19 -1.90 -0.272 0.32524E+04 84 glaucophane 23.11 18.90 -4.21 -0.114 0.71904E+04 87 greenalite 16.19 12.87 -3.32 -0.277 0.56726E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.09 -1.16 -0.116 0.19848E+04 96 julgoldite 70.57 66.34 -4.23 -0.110 0.72296E+04 97 kalsilite 7.62 4.40 -3.22 -0.460 0.54953E+04 98 kaolinite -1.27 -2.45 -1.18 -0.107 0.20069E+04 99 kyanite 4.93 0.97 -3.96 -0.396 0.67672E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.99 -3.18 -0.318 0.54342E+04 105 lizardite 23.29 19.56 -3.73 -0.311 0.63711E+04 107 magnetite 20.13 19.17 -0.97 -0.079 0.16505E+04 108 minnesotaite 10.46 6.04 -4.42 -0.260 0.75512E+04 110 magnesioferrite 26.26 21.39 -4.86 -0.397 0.83035E+04 113 margarite 17.45 14.06 -3.39 -0.136 0.57853E+04 120 muscovite 2.68 1.95 -0.73 -0.043 0.12393E+04 121 paragonite 4.34 4.06 -0.28 -0.016 0.47774E+03 122 nepheline 8.38 6.51 -1.87 -0.268 0.31977E+04 134 phlogopite-Na 29.73 26.06 -3.67 -0.204 0.62663E+04 136 prehnite 19.47 18.39 -1.08 -0.063 0.18405E+04 137 prehnite-Fe 22.59 22.49 -0.09 -0.006 0.15735E+03 138 pumpellyite-Fe 46.47 45.54 -0.93 -0.021 0.15924E+04 139 pumpellyite-Mg 49.19 47.77 -1.43 -0.032 0.24383E+04 145 pyroxmangite 7.42 5.28 -2.14 -0.428 0.36513E+04 146 pyrophyllite -6.10 -9.28 -3.18 -0.199 0.54369E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodonite 7.46 5.28 -2.18 -0.437 0.37305E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.97 -4.35 -0.435 0.74326E+04 164 stilpnomelane-Fe 13.18 12.71 -0.47 -0.014 0.80777E+03 165 stilpnomelane-Mg 27.60 23.85 -3.75 -0.112 0.64026E+04 171 talc 16.55 12.72 -3.83 -0.225 0.65412E+04 174 tephroite 18.11 13.97 -4.14 -0.592 0.70704E+04 177 topaz-H 4.67 0.97 -3.70 -0.336 0.63163E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 8.71 -2.82 -0.564 0.48114E+04 189 wollastonite 10.48 8.71 -1.77 -0.354 0.30253E+04 190 pseudo-wollastonite 11.02 8.71 -2.31 -0.462 0.39439E+04 191 zoisite 22.96 20.58 -2.38 -0.108 0.40683E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.43 -3.87 -0.239 0.66087E+04 195 beidellite-K -1.44 -5.57 -4.14 -0.253 0.70679E+04 196 beidellite-Mg -1.71 -5.98 -4.27 -0.264 0.72956E+04 197 beidellite-Na -1.26 -4.88 -3.62 -0.222 0.61867E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -5.10 -2.89 -0.179 0.49310E+04 202 montmorillonite-K -2.16 -5.25 -3.09 -0.189 0.52680E+04 203 montmorillonite-Mg -2.40 -5.65 -3.25 -0.201 0.55490E+04 204 montmorillonite-Na -1.96 -4.55 -2.59 -0.159 0.44249E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.78 -1.81 -0.122 0.30980E+04 207 nontronite-K 3.40 2.64 -0.77 -0.049 0.13076E+04 208 nontronite-Mg 3.14 2.23 -0.91 -0.059 0.15478E+04 209 nontronite-Na 3.58 3.33 -0.25 -0.016 0.42807E+03 224 tobermorite 9.84 6.68 -3.15 -0.861 0.53857E+04 233 boehmite 4.43 2.19 -2.24 -0.373 0.38196E+04 235 ferrous-oxide 9.82 6.57 -3.26 -0.814 0.55590E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 1.67 -0.41 -0.031 0.69361E+03 243 an25ab75 2.71 2.17 -0.54 -0.041 0.91492E+03 244 an30ab70 3.34 2.67 -0.67 -0.052 0.11446E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 8.3990000 g New total amount of reactant added: 8.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8640E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8.7990000 Water: Moles liquid = 0.5542E+02 kg liquid = 0.9985E+00 Moles total = 0.5540E+02 kg total = 0.9980E+00 Activity = 1.0000 Stoichiometric ionic strength = .5026269E-02 Osmotic coef. = 0.9624 True ionic strength = .8808270E-02 Chg. balance for total moles = 0.8640E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14875E-09 -9.8275 0.13080E-09 -9.8834 0.87935E+00 -0.0558 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13788E-03 -3.8605 0.12087E-03 -3.9177 0.87667E+00 -0.0572 4 SO4-- 0.25526E-04 -4.5930 0.16007E-04 -4.7957 0.62710E+00 -0.2027 5 HCO3- 0.65764E-05 -5.1820 0.57695E-05 -5.2389 0.87731E+00 -0.0568 6 HS- 0.44958E-12 -12.3472 0.39416E-12 -12.4043 0.87673E+00 -0.0571 7 Al+++ 0.90193E-27 -27.0448 0.32061E-27 -27.4940 0.35546E+00 -0.4492 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.43384E-07 -7.3627 0.27105E-07 -7.5669 0.62478E+00 -0.2043 10 Mg++ 0.17771E-10 -10.7503 0.11077E-10 -10.9556 0.62334E+00 -0.2053 11 Fe++ 0.10505E-12 -12.9786 0.65521E-13 -13.1836 0.62368E+00 -0.2050 12 K+ 0.68553E-04 -4.1640 0.60151E-04 -4.2208 0.87742E+00 -0.0568 13 Na+ 0.87071E-02 -2.0601 0.76326E-02 -2.1173 0.87660E+00 -0.0572 14 Mn++ 0.14033E-10 -10.8529 0.87555E-11 -11.0577 0.62394E+00 -0.2049 15 HPO4-- 0.43662E-06 -6.3599 0.27382E-06 -6.5625 0.62714E+00 -0.2026 16 HSiO3- 0.32584E-02 -2.4870 0.28565E-02 -2.5442 0.87667E+00 -0.0572 17 Ca(HSiO3)+ 0.19769E-08 -8.7040 0.17348E-08 -8.7608 0.87752E+00 -0.0567 18 Mg(HSiO3)+ 0.10054E-11 -11.9976 0.88230E-12 -12.0544 0.87752E+00 -0.0567 19 NaHSiO3,aq 0.34628E-03 -3.4606 0.34628E-03 -3.4606 0.10000E+01 0.0000 20 AlO+ 0.27567E-14 -14.5596 0.24191E-14 -14.6164 0.87752E+00 -0.0567 22 HAlO2,aq 0.37009E-08 -8.4317 0.37009E-08 -8.4317 0.10000E+01 0.0000 23 AlO2- 0.72130E-04 -4.1419 0.63176E-04 -4.1994 0.87586E+00 -0.0576 24 CH4,aq 0.13962E-18 -18.8550 0.13941E-18 -18.8557 0.99845E+00 -0.0007 29 CO,aq 0.54665E-19 -19.2623 0.54665E-19 -19.2623 0.10000E+01 0.0000 30 CO2,aq 0.15239E-08 -8.8170 0.15216E-08 -8.8177 0.99845E+00 -0.0007 31 CO3-2 0.65104E-05 -5.1864 0.40783E-05 -5.3895 0.62642E+00 -0.2031 32 CaCO3,aq 0.13539E-08 -8.8684 0.13539E-08 -8.8684 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44904E-11 -11.3477 0.39404E-11 -11.4045 0.87752E+00 -0.0567 34 CaCl+ 0.59496E-11 -11.2255 0.52209E-11 -11.2823 0.87752E+00 -0.0567 35 CaCl2,aq 0.14694E-15 -15.8329 0.14694E-15 -15.8329 0.10000E+01 0.0000 36 CaOH+ 0.16651E-07 -7.7785 0.14612E-07 -7.8353 0.87752E+00 -0.0567 37 CaSO4,aq 0.13519E-09 -9.8691 0.13519E-09 -9.8691 0.10000E+01 0.0000 38 HCl,aq 0.29740E-14 -14.5267 0.29740E-14 -14.5267 0.10000E+01 0.0000 43 FeCl+ 0.14057E-16 -16.8521 0.12335E-16 -16.9089 0.87752E+00 -0.0567 46 FeO,aq 0.15144E-09 -9.8198 0.15144E-09 -9.8198 0.10000E+01 0.0000 47 FeOH+ 0.18924E-10 -10.7230 0.16606E-10 -10.7797 0.87752E+00 -0.0567 48 HFeO2- 0.14205E-07 -7.8476 0.12453E-07 -7.9047 0.87667E+00 -0.0572 49 FeO+ 0.12330E-14 -14.9090 0.10820E-14 -14.9658 0.87752E+00 -0.0567 51 FeO2- 0.14178E-07 -7.8484 0.12430E-07 -7.9055 0.87667E+00 -0.0572 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.13971E-08 -8.8548 0.13949E-08 -8.8555 0.99845E+00 -0.0007 54 KCl,aq 0.12874E-09 -9.8903 0.12874E-09 -9.8903 0.10000E+01 0.0000 55 KHSO4,aq 0.33702E-18 -18.4723 0.33702E-18 -18.4723 0.10000E+01 0.0000 56 KOH,aq 0.20047E-06 -6.6979 0.20047E-06 -6.6979 0.10000E+01 0.0000 57 KSO4- 0.16921E-07 -7.7716 0.14834E-07 -7.8287 0.87667E+00 -0.0572 58 MgCO3,aq 0.13826E-12 -12.8593 0.13826E-12 -12.8593 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18713E-14 -14.7279 0.16421E-14 -14.7846 0.87752E+00 -0.0567 60 MgCl+ 0.22073E-14 -14.6561 0.19369E-14 -14.7129 0.87752E+00 -0.0567 61 MgOH+ 0.37700E-10 -10.4237 0.33082E-10 -10.4804 0.87752E+00 -0.0567 63 MnO,aq 0.54021E-09 -9.2674 0.54021E-09 -9.2674 0.10000E+01 0.0000 64 MnOH+ 0.23492E-09 -9.6291 0.20615E-09 -9.6858 0.87752E+00 -0.0567 65 MnO2-2 0.17431E-11 -11.7587 0.10919E-11 -11.9618 0.62642E+00 -0.2031 66 HMnO2- 0.35299E-10 -10.4522 0.30945E-10 -10.5094 0.87667E+00 -0.0572 69 MnCl+ 0.72992E-14 -14.1367 0.64052E-14 -14.1935 0.87752E+00 -0.0567 70 MnSO4,aq 0.39719E-13 -13.4010 0.39719E-13 -13.4010 0.10000E+01 0.0000 71 NaCl,aq 0.30125E-06 -6.5211 0.30125E-06 -6.5211 0.10000E+01 0.0000 72 NaOH,aq 0.25640E-04 -4.5911 0.25640E-04 -4.5911 0.10000E+01 0.0000 74 OH- 0.52357E-02 -2.2810 0.45858E-02 -2.3386 0.87586E+00 -0.0576 79 HPO3-2 0.19259E-17 -17.7154 0.12064E-17 -17.9185 0.62642E+00 -0.2031 82 H3PO4,aq 0.30162E-16 -16.5205 0.30162E-16 -16.5205 0.10000E+01 0.0000 83 H2PO4- 0.71595E-09 -9.1451 0.62795E-09 -9.2021 0.87709E+00 -0.0570 84 PO4-3 0.50167E-08 -8.2996 0.18282E-08 -8.7380 0.36442E+00 -0.4384 87 H2P2O7-2 0.49266E-19 -19.3075 0.30861E-19 -19.5106 0.62642E+00 -0.2031 88 HP2O7-3 0.13605E-15 -15.8663 0.48379E-16 -16.3153 0.35561E+00 -0.4490 89 P2O7-4 0.55804E-15 -15.2533 0.91245E-16 -16.0398 0.16351E+00 -0.7865 90 H2S,aq 0.15515E-15 -15.8093 0.15491E-15 -15.8099 0.99845E+00 -0.0007 97 SO3-2 0.48247E-14 -14.3165 0.30445E-14 -14.5165 0.63102E+00 -0.2000 98 HSO3- 0.26584E-16 -16.5754 0.23305E-16 -16.6326 0.87667E+00 -0.0572 99 HSO4- 0.22128E-11 -11.6551 0.19427E-11 -11.7116 0.87794E+00 -0.0565 Charge balance for all species = 0.8730E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1487487E-09 -.9161416E-02 -.9228383E+01 0.0000 2 H2O 0.1000000E+01 0.5551005E+02 0.9994048E+06 0.0000 3 Cl- 0.1378802E-03 0.1381816E-03 0.4895887E+01 5.9657 4 SO4-- 0.2552575E-04 0.2554425E-04 0.2452287E+01 14.9711 5 HCO3- 0.6576355E-05 0.1308964E-04 0.7981939E+00 4.6445 6 HS- 0.4495751E-12 -.1447979E-08 -.4785762E-04 -2.5209 7 Al+++ 0.9019335E-27 0.7213357E-04 0.1945055E+01 2.1561 8 H4SiO4 0.3829605E-03 0.3987640E-02 0.3830339E+03 -3.4168 9 Ca++ 0.4338376E-07 0.6351159E-07 0.2543826E-02 12.1998 10 Mg++ 0.1777074E-10 0.5661817E-10 0.1375640E-05 8.8112 11 Fe++ 0.1050546E-12 0.2875658E-07 0.1604964E-02 6.5831 12 K+ 0.6855350E-04 0.6877102E-04 0.2687402E+01 5.6626 13 Na+ 0.8707080E-02 0.9079301E-02 0.2086008E+03 7.7661 14 Mn++ 0.1403251E-10 0.8262520E-09 0.4536424E-04 8.7090 15 HPO4-- 0.4366229E-06 0.4423555E-06 0.4243029E-01 13.2042 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1456853E+00 -.9147667E-02 -.1365377E+00 0.0000000E+00 2 H2O 0.5539795E+02 0.5542674E+02 -.2879141E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2693548E-03 0.2550592E-04 0.2438488E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2438503E-03 -.1445806E-08 -.2438488E-03 0.0000000E+00 7 Al+++ 0.2869127E-01 0.7202532E-04 0.2861924E-01 0.0000000E+00 8 H4SiO4 0.9162208E-01 0.3981655E-02 0.8764042E-01 0.0000000E+00 9 Ca++ 0.1013458E-01 0.6341628E-07 0.1013451E-01 0.0000000E+00 10 Mg++ 0.6983333E-02 0.5653319E-10 0.6983333E-02 0.0000000E+00 11 Fe++ 0.6273763E-02 0.2871343E-07 0.6273734E-02 0.0000000E+00 12 K+ 0.1868153E-02 0.6866781E-04 0.1799485E-02 0.0000000E+00 13 Na+ 0.1120496E-01 0.9065675E-02 0.2139284E-02 0.0000000E+00 14 Mn++ 0.1525623E-03 0.8250120E-09 0.1525615E-03 0.0000000E+00 15 HPO4-- 0.5206876E-04 0.4416916E-06 0.5162706E-04 0.0000000E+00 Chg. balance for solid moles: -.2029E-16 Mass of aqueous solution: 0.999124E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2139E-02 -2.670 0.5610 -0.251 5.835 0.2153 apatite-OH 0.1721E-04 -4.764 0.8644E-02 -2.063 0.8992E-01 0.2747E-02 clinochlore 0.1397E-02 -2.855 0.7763 -0.110 8.075 0.2953 daphnite 0.8646E-03 -3.063 0.6169 -0.210 6.417 0.1869 chlorite-Mn 0.3051E-04 -4.516 0.2163E-01 -1.665 0.2250 0.6894E-02 hematite 0.9754E-03 -3.011 0.1558 -0.808 1.620 0.2952E-01 lawsonite 0.2781E-03 -3.556 0.8739E-01 -1.059 0.9090 0.2818E-01 microcline 0.1799E-02 -2.745 0.5009 -0.300 5.210 0.1957 stilbite 0.9770E-02 -2.010 6.885 0.838 71.62 3.211 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9.613848 g Volume = 4.172026 cm3 Porosity: 7.6904% V(tot) - V(min): 0.34757E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8.7990000 g log = 0.9444 Original solution: 1000.0103000 g Original solution / Rock added: 113.65 (Water/Rock Ratio), log = 2.0556 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1644E-06 1.0073 0.1742E-06 0.1729E-06 CH4,gas 0.2069E-15 1.0129 0.2205E-15 0.2176E-15 H2,gas 0.1818E-05 1.0006 0.1913E-05 0.1912E-05 H2S,gas 0.4312E-14 0.9959 0.4518E-14 0.4536E-14 S2,gas 0.1985E-36 1.0000 0.2089E-36 0.2089E-36 CO,gas 0.8205E-16 1.0000 0.8632E-16 0.8632E-16 SO3,gas 0.9733E-40 1.0000 0.1024E-39 0.1024E-39 SO2,gas 0.7045E-23 1.0000 0.7411E-23 0.7411E-23 HCl,gas 0.4992E-17 1.0000 0.5251E-17 0.5251E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.21232E-10 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 137 prehnite-Fe 22.59 22.60 0.02 0.001 -0.29493E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.12 -8.76 -2.920 0.14956E+05 -6.759 3 CH4,gas 4.81 -12.85 -17.66 -4.414 0.30148E+05 -15.657 4 H2,gas 8.29 0.57 -7.72 -4.410 0.13179E+05 -5.718 5 H2S,gas -5.94 -22.29 -16.35 -8.173 0.27909E+05 -14.345 6 S2,gas -7.03 -45.71 -38.68 -5.951 0.66045E+05 -36.680 7 CO,gas 3.51 -14.55 -18.06 -5.558 0.30844E+05 -16.064 8 SO3,gas 17.43 -24.56 -41.99 -10.497 0.71696E+05 -39.990 9 SO2,gas 1.14 -23.99 -25.13 -6.701 0.42909E+05 -23.130 10 HCl,gas 5.48 -13.80 -19.28 -9.640 0.32920E+05 -17.280 11 acmite 7.74 7.23 -0.51 -0.053 0.86436E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.19 -4.36 -0.218 0.74464E+04 20 analcite 3.37 3.09 -0.28 -0.031 0.48177E+03 21 andalusite 5.06 0.90 -4.17 -0.417 0.71150E+04 22 andradite 39.09 38.95 -0.14 -0.007 0.24108E+03 23 grossular 32.83 30.66 -2.17 -0.108 0.37001E+04 26 annite 20.21 17.32 -2.89 -0.161 0.49375E+04 27 phlogopite 27.15 24.00 -3.14 -0.175 0.53697E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.92 -3.91 -1.303 0.66739E+04 36 brucite 12.58 8.81 -3.77 -0.753 0.64293E+04 37 calcite 0.83 -2.92 -3.76 -1.252 0.64126E+04 38 carnegieite-low 9.06 6.51 -2.56 -0.366 0.43698E+04 39 carnegieite-high 10.13 6.51 -3.63 -0.518 0.61967E+04 40 carpholite-Mg 8.65 6.29 -2.36 -0.157 0.40307E+04 41 carpholite-Fe 6.78 4.06 -2.72 -0.181 0.46464E+04 42 celadonite 5.40 2.96 -2.44 -0.143 0.41627E+04 43 celadonite-Fe 3.94 0.73 -3.20 -0.188 0.54681E+04 44 chrysotile 23.94 19.60 -4.34 -0.361 0.74061E+04 50 chloritoid-Mg 13.26 9.71 -3.55 -0.237 0.60695E+04 51 chloritoid-Fe 9.24 7.48 -1.76 -0.117 0.30054E+04 52 chloritoid-Mn 11.46 9.60 -1.86 -0.124 0.31738E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 4.31 -4.12 -0.375 0.70368E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.16 -0.74 -0.123 0.12635E+04 67 diopside 16.22 14.18 -2.04 -0.204 0.34801E+04 68 hedenbergite 14.24 11.95 -2.30 -0.230 0.39189E+04 75 epidote 24.78 24.76 -0.02 -0.001 0.25687E+02 76 clinozoisite 22.92 20.62 -2.30 -0.105 0.39335E+04 77 epidote-Fe 29.94 28.90 -1.03 -0.054 0.17654E+04 78 fayalite 14.08 9.75 -4.33 -0.619 0.73925E+04 79 ferrosilite 11.19 6.33 -4.86 -0.486 0.82899E+04 83 gibbsite 4.10 2.16 -1.94 -0.277 0.33147E+04 84 glaucophane 23.11 18.94 -4.17 -0.113 0.71157E+04 87 greenalite 16.19 12.92 -3.28 -0.273 0.55979E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.09 -1.16 -0.116 0.19848E+04 96 julgoldite 70.57 66.66 -3.91 -0.102 0.66815E+04 97 kalsilite 7.62 4.40 -3.22 -0.460 0.54953E+04 98 kaolinite -1.27 -2.52 -1.25 -0.113 0.21315E+04 99 kyanite 4.93 0.90 -4.04 -0.404 0.68918E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.99 -3.18 -0.318 0.54342E+04 105 lizardite 23.29 19.60 -3.69 -0.307 0.62964E+04 107 magnetite 20.13 19.18 -0.95 -0.078 0.16256E+04 108 minnesotaite 10.46 6.08 -4.38 -0.258 0.74765E+04 110 magnesioferrite 26.26 21.41 -4.85 -0.396 0.82786E+04 113 margarite 17.45 13.99 -3.46 -0.138 0.59099E+04 120 muscovite 2.68 1.88 -0.80 -0.047 0.13638E+04 121 paragonite 4.34 3.98 -0.35 -0.021 0.60230E+03 122 nepheline 8.38 6.51 -1.87 -0.268 0.31977E+04 134 phlogopite-Na 29.73 26.11 -3.63 -0.201 0.61916E+04 136 prehnite 19.47 18.46 -1.00 -0.059 0.17160E+04 138 pumpellyite-Fe 46.47 45.66 -0.81 -0.018 0.13806E+04 139 pumpellyite-Mg 49.19 47.89 -1.30 -0.029 0.22266E+04 145 pyroxmangite 7.42 5.29 -2.12 -0.425 0.36264E+04 146 pyrophyllite -6.10 -9.36 -3.26 -0.204 0.55614E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodonite 7.46 5.29 -2.17 -0.434 0.37056E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.90 -4.43 -0.443 0.75572E+04 164 stilpnomelane-Fe 13.18 12.72 -0.45 -0.014 0.77663E+03 165 stilpnomelane-Mg 27.60 23.86 -3.73 -0.111 0.63714E+04 171 talc 16.55 12.77 -3.79 -0.223 0.64665E+04 174 tephroite 18.11 14.00 -4.11 -0.587 0.70205E+04 177 topaz-H 4.67 0.90 -3.77 -0.343 0.64409E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 8.78 -2.74 -0.549 0.46868E+04 189 wollastonite 10.48 8.78 -1.70 -0.340 0.29007E+04 190 pseudo-wollastonite 11.02 8.78 -2.24 -0.447 0.38193E+04 191 zoisite 22.96 20.62 -2.35 -0.107 0.40060E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.50 -3.94 -0.244 0.67333E+04 195 beidellite-K -1.44 -5.65 -4.21 -0.258 0.71925E+04 196 beidellite-Mg -1.71 -6.06 -4.36 -0.269 0.74366E+04 197 beidellite-Na -1.26 -4.95 -3.70 -0.226 0.63112E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -5.15 -2.93 -0.181 0.50063E+04 202 montmorillonite-K -2.16 -5.29 -3.13 -0.192 0.53432E+04 203 montmorillonite-Mg -2.40 -5.71 -3.30 -0.204 0.56406E+04 204 montmorillonite-Na -1.96 -4.60 -2.64 -0.161 0.45001E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.77 -1.83 -0.122 0.31186E+04 207 nontronite-K 3.40 2.64 -0.77 -0.049 0.13076E+04 208 nontronite-Mg 3.14 2.22 -0.92 -0.059 0.15642E+04 209 nontronite-Na 3.58 3.33 -0.25 -0.016 0.42807E+03 224 tobermorite 9.84 6.75 -3.09 -0.844 0.52819E+04 233 boehmite 4.43 2.16 -2.27 -0.379 0.38819E+04 235 ferrous-oxide 9.82 6.58 -3.24 -0.810 0.55340E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 1.67 -0.41 -0.031 0.69361E+03 243 an25ab75 2.71 2.17 -0.54 -0.041 0.91492E+03 244 an30ab70 3.34 2.67 -0.67 -0.052 0.11446E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8.7990000 Water: Moles liquid = 0.5543E+02 kg liquid = 0.9985E+00 Moles total = 0.5540E+02 kg total = 0.9980E+00 Activity = 1.0000 Stoichiometric ionic strength = .4995970E-02 Osmotic coef. = 0.9625 True ionic strength = .8748511E-02 Chg. balance for total moles = 0.8640E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14971E-09 -9.8247 0.13169E-09 -9.8804 0.87964E+00 -0.0557 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13788E-03 -3.8605 0.12092E-03 -3.9175 0.87697E+00 -0.0570 4 SO4-- 0.25526E-04 -4.5930 0.16028E-04 -4.7951 0.62793E+00 -0.2021 5 HCO3- 0.66017E-05 -5.1803 0.57937E-05 -5.2370 0.87761E+00 -0.0567 6 HS- 0.43426E-12 -12.3623 0.38086E-12 -12.4192 0.87703E+00 -0.0570 7 Al+++ 0.92989E-27 -27.0316 0.33155E-27 -27.4795 0.35654E+00 -0.4479 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.42766E-07 -7.3689 0.26756E-07 -7.5726 0.62563E+00 -0.2037 10 Mg++ 0.17893E-10 -10.7473 0.11169E-10 -10.9520 0.62419E+00 -0.2047 11 Fe++ 0.10578E-12 -12.9756 0.66062E-13 -13.1800 0.62453E+00 -0.2044 12 K+ 0.68087E-04 -4.1669 0.59761E-04 -4.2236 0.87772E+00 -0.0566 13 Na+ 0.86478E-02 -2.0631 0.75832E-02 -2.1201 0.87690E+00 -0.0571 14 Mn++ 0.14129E-10 -10.8499 0.88279E-11 -11.0541 0.62479E+00 -0.2043 15 HPO4-- 0.44962E-06 -6.3472 0.28235E-06 -6.5492 0.62798E+00 -0.2021 16 HSiO3- 0.32353E-02 -2.4901 0.28373E-02 -2.5471 0.87697E+00 -0.0570 17 Ca(HSiO3)+ 0.19376E-08 -8.7127 0.17009E-08 -8.7693 0.87781E+00 -0.0566 18 Mg(HSiO3)+ 0.10066E-11 -11.9971 0.88359E-12 -12.0537 0.87781E+00 -0.0566 19 NaHSiO3,aq 0.34172E-03 -3.4663 0.34172E-03 -3.4663 0.10000E+01 0.0000 20 AlO+ 0.28115E-14 -14.5511 0.24680E-14 -14.6077 0.87781E+00 -0.0566 22 HAlO2,aq 0.37502E-08 -8.4259 0.37502E-08 -8.4259 0.10000E+01 0.0000 23 AlO2- 0.72574E-04 -4.1392 0.63587E-04 -4.1966 0.87617E+00 -0.0574 24 CH4,aq 0.13530E-18 -18.8687 0.13509E-18 -18.8694 0.99846E+00 -0.0007 29 CO,aq 0.54684E-19 -19.2621 0.54684E-19 -19.2621 0.10000E+01 0.0000 30 CO2,aq 0.15407E-08 -8.8123 0.15383E-08 -8.8130 0.99846E+00 -0.0007 31 CO3-2 0.64850E-05 -5.1881 0.40678E-05 -5.3906 0.62726E+00 -0.2026 32 CaCO3,aq 0.13330E-08 -8.8752 0.13330E-08 -8.8752 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44496E-11 -11.3517 0.39060E-11 -11.4083 0.87781E+00 -0.0566 34 CaCl+ 0.58729E-11 -11.2311 0.51553E-11 -11.2877 0.87781E+00 -0.0566 35 CaCl2,aq 0.14514E-15 -15.8382 0.14514E-15 -15.8382 0.10000E+01 0.0000 36 CaOH+ 0.16320E-07 -7.7873 0.14326E-07 -7.8439 0.87781E+00 -0.0566 37 CaSO4,aq 0.13362E-09 -9.8741 0.13362E-09 -9.8741 0.10000E+01 0.0000 38 HCl,aq 0.29952E-14 -14.5236 0.29952E-14 -14.5236 0.10000E+01 0.0000 43 FeCl+ 0.14173E-16 -16.8485 0.12442E-16 -16.9051 0.87781E+00 -0.0566 46 FeO,aq 0.15063E-09 -9.8221 0.15063E-09 -9.8221 0.10000E+01 0.0000 47 FeOH+ 0.18946E-10 -10.7225 0.16631E-10 -10.7791 0.87781E+00 -0.0566 48 HFeO2- 0.14029E-07 -7.8530 0.12303E-07 -7.9100 0.87697E+00 -0.0570 49 FeO+ 0.12410E-14 -14.9062 0.10894E-14 -14.9628 0.87781E+00 -0.0566 51 FeO2- 0.14078E-07 -7.8515 0.12346E-07 -7.9085 0.87697E+00 -0.0570 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.13823E-08 -8.8594 0.13802E-08 -8.8601 0.99846E+00 -0.0007 54 KCl,aq 0.12795E-09 -9.8930 0.12795E-09 -9.8930 0.10000E+01 0.0000 55 KHSO4,aq 0.33756E-18 -18.4717 0.33756E-18 -18.4717 0.10000E+01 0.0000 56 KOH,aq 0.19783E-06 -6.7037 0.19783E-06 -6.7037 0.10000E+01 0.0000 57 KSO4- 0.16828E-07 -7.7740 0.14757E-07 -7.8310 0.87697E+00 -0.0570 58 MgCO3,aq 0.13904E-12 -12.8569 0.13904E-12 -12.8569 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18941E-14 -14.7226 0.16626E-14 -14.7792 0.87781E+00 -0.0566 60 MgCl+ 0.22256E-14 -14.6526 0.19536E-14 -14.7092 0.87781E+00 -0.0566 61 MgOH+ 0.37742E-10 -10.4232 0.33131E-10 -10.4798 0.87781E+00 -0.0566 63 MnO,aq 0.53735E-09 -9.2697 0.53735E-09 -9.2697 0.10000E+01 0.0000 64 MnOH+ 0.23519E-09 -9.6286 0.20645E-09 -9.6852 0.87781E+00 -0.0566 65 MnO2-2 0.17083E-11 -11.7674 0.10716E-11 -11.9700 0.62726E+00 -0.2026 66 HMnO2- 0.34864E-10 -10.4576 0.30574E-10 -10.5146 0.87697E+00 -0.0570 69 MnCl+ 0.73597E-14 -14.1331 0.64604E-14 -14.1897 0.87781E+00 -0.0566 70 MnSO4,aq 0.40100E-13 -13.3969 0.40100E-13 -13.3969 0.10000E+01 0.0000 71 NaCl,aq 0.29940E-06 -6.5237 0.29940E-06 -6.5237 0.10000E+01 0.0000 72 NaOH,aq 0.25303E-04 -4.5968 0.25303E-04 -4.5968 0.10000E+01 0.0000 74 OH- 0.51986E-02 -2.2841 0.45549E-02 -2.3415 0.87617E+00 -0.0574 79 HPO3-2 0.19623E-17 -17.7072 0.12309E-17 -17.9098 0.62726E+00 -0.2026 82 H3PO4,aq 0.31524E-16 -16.5014 0.31524E-16 -16.5014 0.10000E+01 0.0000 83 H2PO4- 0.74300E-09 -9.1290 0.65189E-09 -9.1858 0.87738E+00 -0.0568 84 PO4-3 0.51232E-08 -8.2905 0.18724E-08 -8.7276 0.36548E+00 -0.4371 87 H2P2O7-2 0.53024E-19 -19.2755 0.33260E-19 -19.4781 0.62726E+00 -0.2026 88 HP2O7-3 0.14519E-15 -15.8381 0.51788E-16 -16.2858 0.35668E+00 -0.4477 89 P2O7-4 0.59019E-15 -15.2290 0.97015E-16 -16.0132 0.16438E+00 -0.7842 90 H2S,aq 0.15093E-15 -15.8212 0.15069E-15 -15.8219 0.99846E+00 -0.0007 97 SO3-2 0.47740E-14 -14.3211 0.30164E-14 -14.5205 0.63183E+00 -0.1994 98 HSO3- 0.26508E-16 -16.5766 0.23247E-16 -16.6336 0.87697E+00 -0.0570 99 HSO4- 0.22301E-11 -11.6517 0.19585E-11 -11.7081 0.87823E+00 -0.0564 Charge balance for all species = 0.9034E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1497104E-09 -.9098074E-02 -.9164616E+01 0.0000 2 H2O 0.1000000E+01 0.5551004E+02 0.9994088E+06 0.0000 3 Cl- 0.1378814E-03 0.1381810E-03 0.4895886E+01 5.9629 4 SO4-- 0.2552573E-04 0.2554413E-04 0.2452286E+01 14.9658 5 HCO3- 0.6601739E-05 0.1308959E-04 0.7981938E+00 4.6434 6 HS- 0.4342565E-12 -.1439129E-08 -.4756532E-04 -2.5388 7 Al+++ 0.9298931E-27 0.7257815E-04 0.1957051E+01 2.1619 8 H4SiO4 0.3829605E-03 0.3959999E-02 0.3803805E+03 -3.4168 9 Ca++ 0.4276643E-07 0.6250130E-07 0.2503371E-02 12.1883 10 Mg++ 0.1789319E-10 0.5678518E-10 0.1379704E-05 8.8089 11 Fe++ 0.1057788E-12 0.2848017E-07 0.1589544E-02 6.5808 12 K+ 0.6808715E-04 0.6830194E-04 0.2669083E+01 5.6569 13 Na+ 0.8647801E-02 0.9015123E-02 0.2071271E+03 7.7603 14 Mn++ 0.1412928E-10 0.8232873E-09 0.4520166E-04 8.7067 15 HPO4-- 0.4496174E-06 0.4554836E-06 0.4368970E-01 13.2117 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1456853E+00 -.9084460E-02 -.1366009E+00 0.0000000E+00 2 H2O 0.5539795E+02 0.5542698E+02 -.2902425E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2693548E-03 0.2550591E-04 0.2438488E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2438503E-03 -.1436976E-08 -.2438488E-03 0.0000000E+00 7 Al+++ 0.2869127E-01 0.7246954E-04 0.2861880E-01 0.0000000E+00 8 H4SiO4 0.9162208E-01 0.3954073E-02 0.8766800E-01 0.0000000E+00 9 Ca++ 0.1013458E-01 0.6240777E-07 0.1013451E-01 0.0000000E+00 10 Mg++ 0.6983333E-02 0.5670020E-10 0.6983333E-02 0.0000000E+00 11 Fe++ 0.6273763E-02 0.2843755E-07 0.6273734E-02 0.0000000E+00 12 K+ 0.1868153E-02 0.6819973E-04 0.1799953E-02 0.0000000E+00 13 Na+ 0.1120496E-01 0.9001632E-02 0.2203328E-02 0.0000000E+00 14 Mn++ 0.1525623E-03 0.8220553E-09 0.1525615E-03 0.0000000E+00 15 HPO4-- 0.5206876E-04 0.4548020E-06 0.5161395E-04 0.0000000E+00 Chg. balance for solid moles: -.9649E-17 Mass of aqueous solution: 0.999124E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2203E-02 -2.657 0.5778 -0.238 6.010 0.2218 apatite-OH 0.1720E-04 -4.764 0.8642E-02 -2.063 0.8989E-01 0.2746E-02 clinochlore 0.1397E-02 -2.855 0.7763 -0.110 8.075 0.2953 daphnite 0.8646E-03 -3.063 0.6169 -0.210 6.417 0.1869 chlorite-Mn 0.3051E-04 -4.516 0.2163E-01 -1.665 0.2250 0.6894E-02 hematite 0.9646E-03 -3.016 0.1540 -0.812 1.602 0.2920E-01 lawsonite 0.2636E-03 -3.579 0.8285E-01 -1.082 0.8618 0.2672E-01 microcline 0.1800E-02 -2.745 0.5010 -0.300 5.211 0.1957 stilbite 0.9742E-02 -2.011 6.865 0.837 71.41 3.202 prehnite-Fe 0.2167E-04 -4.664 0.9560E-02 -2.020 0.9945E-01 0.3207E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9.613718 g Volume = 4.170450 cm3 Porosity: 7.7252% V(tot) - V(min): 0.34915E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8.7990000 g log = 0.9444 Original solution: 1000.0103000 g Original solution / Rock added: 113.65 (Water/Rock Ratio), log = 2.0556 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1662E-06 1.0073 0.1761E-06 0.1748E-06 CH4,gas 0.2005E-15 1.0129 0.2136E-15 0.2109E-15 H2,gas 0.1799E-05 1.0006 0.1893E-05 0.1892E-05 H2S,gas 0.4195E-14 0.9959 0.4395E-14 0.4413E-14 S2,gas 0.1919E-36 1.0000 0.2019E-36 0.2019E-36 CO,gas 0.8208E-16 1.0000 0.8635E-16 0.8635E-16 SO3,gas 0.9879E-40 1.0000 0.1039E-39 0.1039E-39 SO2,gas 0.7075E-23 1.0000 0.7442E-23 0.7442E-23 HCl,gas 0.5028E-17 1.0000 0.5289E-17 0.5289E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 137 prehnite-Fe 22.59 22.59 0.00 0.000 -0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.12 -8.75 -2.918 0.14948E+05 -6.754 3 CH4,gas 4.81 -12.86 -17.67 -4.418 0.30172E+05 -15.670 4 H2,gas 8.29 0.56 -7.72 -4.413 0.13187E+05 -5.723 5 H2S,gas -5.94 -22.30 -16.36 -8.179 0.27929E+05 -14.357 6 S2,gas -7.03 -45.73 -38.69 -5.953 0.66070E+05 -36.695 7 CO,gas 3.51 -14.55 -18.06 -5.558 0.30843E+05 -16.064 8 SO3,gas 17.43 -24.56 -41.98 -10.496 0.71685E+05 -39.983 9 SO2,gas 1.14 -23.99 -25.13 -6.701 0.42906E+05 -23.128 10 HCl,gas 5.48 -13.80 -19.28 -9.638 0.32914E+05 -17.277 11 acmite 7.74 7.23 -0.51 -0.053 0.87419E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.19 -4.36 -0.218 0.74385E+04 20 analcite 3.37 3.09 -0.28 -0.031 0.48177E+03 21 andalusite 5.06 0.91 -4.16 -0.416 0.70953E+04 22 andradite 39.09 38.91 -0.18 -0.009 0.30007E+03 23 grossular 32.83 30.64 -2.19 -0.110 0.37395E+04 26 annite 20.21 17.31 -2.90 -0.161 0.49493E+04 27 phlogopite 27.15 23.99 -3.15 -0.175 0.53815E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.93 -3.92 -1.305 0.66854E+04 36 brucite 12.58 8.81 -3.77 -0.754 0.64333E+04 37 calcite 0.83 -2.93 -3.76 -1.254 0.64241E+04 38 carnegieite-low 9.06 6.51 -2.56 -0.366 0.43698E+04 39 carnegieite-high 10.13 6.51 -3.63 -0.518 0.61967E+04 40 carpholite-Mg 8.65 6.30 -2.35 -0.157 0.40150E+04 41 carpholite-Fe 6.78 4.07 -2.71 -0.181 0.46306E+04 42 celadonite 5.40 2.96 -2.44 -0.144 0.41667E+04 43 celadonite-Fe 3.94 0.73 -3.20 -0.189 0.54720E+04 44 chrysotile 23.94 19.59 -4.34 -0.362 0.74179E+04 50 chloritoid-Mg 13.26 9.72 -3.55 -0.236 0.60537E+04 51 chloritoid-Fe 9.24 7.49 -1.75 -0.117 0.29896E+04 52 chloritoid-Mn 11.46 9.61 -1.85 -0.123 0.31581E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 4.32 -4.11 -0.374 0.70171E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.16 -0.73 -0.122 0.12536E+04 67 diopside 16.22 14.16 -2.05 -0.205 0.35037E+04 68 hedenbergite 14.24 11.94 -2.31 -0.231 0.39425E+04 75 epidote 24.78 24.75 -0.03 -0.001 0.45350E+02 76 clinozoisite 22.92 20.61 -2.31 -0.105 0.39433E+04 77 epidote-Fe 29.94 28.89 -1.05 -0.055 0.17949E+04 78 fayalite 14.08 9.74 -4.33 -0.619 0.74004E+04 79 ferrosilite 11.19 6.33 -4.86 -0.486 0.82978E+04 83 gibbsite 4.10 2.16 -1.94 -0.277 0.33048E+04 84 glaucophane 23.11 18.94 -4.17 -0.113 0.71275E+04 87 greenalite 16.19 12.91 -3.29 -0.274 0.56097E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.09 -1.16 -0.116 0.19848E+04 96 julgoldite 70.57 66.61 -3.96 -0.103 0.67681E+04 97 kalsilite 7.62 4.40 -3.22 -0.460 0.54953E+04 98 kaolinite -1.27 -2.51 -1.24 -0.112 0.21118E+04 99 kyanite 4.93 0.91 -4.02 -0.402 0.68721E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.99 -3.18 -0.318 0.54342E+04 105 lizardite 23.29 19.59 -3.69 -0.308 0.63082E+04 107 magnetite 20.13 19.18 -0.95 -0.078 0.16295E+04 108 minnesotaite 10.46 6.08 -4.39 -0.258 0.74883E+04 110 magnesioferrite 26.26 21.41 -4.85 -0.396 0.82825E+04 113 margarite 17.45 14.00 -3.45 -0.138 0.58902E+04 120 muscovite 2.68 1.89 -0.79 -0.046 0.13442E+04 121 paragonite 4.34 4.00 -0.34 -0.020 0.58264E+03 122 nepheline 8.38 6.51 -1.87 -0.268 0.31977E+04 134 phlogopite-Na 29.73 26.10 -3.63 -0.202 0.62034E+04 136 prehnite 19.47 18.45 -1.02 -0.060 0.17356E+04 138 pumpellyite-Fe 46.47 45.64 -0.83 -0.018 0.14141E+04 139 pumpellyite-Mg 49.19 47.87 -1.32 -0.029 0.22600E+04 145 pyroxmangite 7.42 5.29 -2.13 -0.425 0.36303E+04 146 pyrophyllite -6.10 -9.34 -3.25 -0.203 0.55418E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodonite 7.46 5.29 -2.17 -0.435 0.37096E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.91 -4.41 -0.441 0.75375E+04 164 stilpnomelane-Fe 13.18 12.72 -0.46 -0.014 0.78154E+03 165 stilpnomelane-Mg 27.60 23.86 -3.73 -0.111 0.63764E+04 171 talc 16.55 12.76 -3.79 -0.223 0.64783E+04 174 tephroite 18.11 14.00 -4.12 -0.588 0.70284E+04 177 topaz-H 4.67 0.91 -3.76 -0.342 0.64212E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 8.77 -2.76 -0.551 0.47065E+04 189 wollastonite 10.48 8.77 -1.71 -0.342 0.29204E+04 190 pseudo-wollastonite 11.02 8.77 -2.25 -0.450 0.38390E+04 191 zoisite 22.96 20.61 -2.35 -0.107 0.40158E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.49 -3.93 -0.243 0.67136E+04 195 beidellite-K -1.44 -5.64 -4.20 -0.257 0.71728E+04 196 beidellite-Mg -1.71 -6.05 -4.34 -0.269 0.74143E+04 197 beidellite-Na -1.26 -4.94 -3.68 -0.226 0.62916E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -5.14 -2.93 -0.181 0.49944E+04 202 montmorillonite-K -2.16 -5.28 -3.12 -0.191 0.53314E+04 203 montmorillonite-Mg -2.40 -5.70 -3.30 -0.204 0.56262E+04 204 montmorillonite-Na -1.96 -4.59 -2.63 -0.161 0.44882E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.77 -1.82 -0.122 0.31153E+04 207 nontronite-K 3.40 2.64 -0.77 -0.049 0.13076E+04 208 nontronite-Mg 3.14 2.22 -0.91 -0.059 0.15616E+04 209 nontronite-Na 3.58 3.33 -0.25 -0.016 0.42807E+03 224 tobermorite 9.84 6.74 -3.10 -0.847 0.52983E+04 233 boehmite 4.43 2.16 -2.27 -0.378 0.38721E+04 235 ferrous-oxide 9.82 6.58 -3.24 -0.811 0.55380E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 1.67 -0.41 -0.031 0.69361E+03 243 an25ab75 2.71 2.17 -0.54 -0.041 0.91492E+03 244 an30ab70 3.34 2.67 -0.67 -0.052 0.11446E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 8.7990000 g New total amount of reactant added: 9.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8641E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 9.1990000 Water: Moles liquid = 0.5542E+02 kg liquid = 0.9985E+00 Moles total = 0.5539E+02 kg total = 0.9979E+00 Activity = 1.0000 Stoichiometric ionic strength = .4995977E-02 Osmotic coef. = 0.9625 True ionic strength = .8748517E-02 Chg. balance for total moles = 0.8641E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14971E-09 -9.8247 0.13169E-09 -9.8804 0.87964E+00 -0.0557 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13789E-03 -3.8605 0.12092E-03 -3.9175 0.87697E+00 -0.0570 4 SO4-- 0.25527E-04 -4.5930 0.16029E-04 -4.7951 0.62793E+00 -0.2021 5 HCO3- 0.66020E-05 -5.1803 0.57940E-05 -5.2370 0.87761E+00 -0.0567 6 HS- 0.43427E-12 -12.3622 0.38087E-12 -12.4192 0.87703E+00 -0.0570 7 Al+++ 0.92989E-27 -27.0316 0.33155E-27 -27.4795 0.35654E+00 -0.4479 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.42766E-07 -7.3689 0.26756E-07 -7.5726 0.62563E+00 -0.2037 10 Mg++ 0.17893E-10 -10.7473 0.11169E-10 -10.9520 0.62419E+00 -0.2047 11 Fe++ 0.10578E-12 -12.9756 0.66062E-13 -13.1800 0.62453E+00 -0.2044 12 K+ 0.68087E-04 -4.1669 0.59761E-04 -4.2236 0.87772E+00 -0.0566 13 Na+ 0.86478E-02 -2.0631 0.75832E-02 -2.1201 0.87690E+00 -0.0571 14 Mn++ 0.14129E-10 -10.8499 0.88279E-11 -11.0541 0.62479E+00 -0.2043 15 HPO4-- 0.44962E-06 -6.3472 0.28235E-06 -6.5492 0.62798E+00 -0.2021 16 HSiO3- 0.32353E-02 -2.4901 0.28373E-02 -2.5471 0.87697E+00 -0.0570 17 Ca(HSiO3)+ 0.19376E-08 -8.7127 0.17009E-08 -8.7693 0.87781E+00 -0.0566 18 Mg(HSiO3)+ 0.10066E-11 -11.9971 0.88359E-12 -12.0537 0.87781E+00 -0.0566 19 NaHSiO3,aq 0.34172E-03 -3.4663 0.34172E-03 -3.4663 0.10000E+01 0.0000 20 AlO+ 0.28115E-14 -14.5511 0.24680E-14 -14.6077 0.87781E+00 -0.0566 22 HAlO2,aq 0.37502E-08 -8.4259 0.37502E-08 -8.4259 0.10000E+01 0.0000 23 AlO2- 0.72574E-04 -4.1392 0.63587E-04 -4.1966 0.87617E+00 -0.0574 24 CH4,aq 0.13530E-18 -18.8687 0.13509E-18 -18.8694 0.99846E+00 -0.0007 29 CO,aq 0.54686E-19 -19.2621 0.54686E-19 -19.2621 0.10000E+01 0.0000 30 CO2,aq 0.15408E-08 -8.8123 0.15384E-08 -8.8129 0.99846E+00 -0.0007 31 CO3-2 0.64852E-05 -5.1881 0.40679E-05 -5.3906 0.62726E+00 -0.2026 32 CaCO3,aq 0.13330E-08 -8.8752 0.13330E-08 -8.8752 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44498E-11 -11.3517 0.39061E-11 -11.4083 0.87781E+00 -0.0566 34 CaCl+ 0.58732E-11 -11.2311 0.51556E-11 -11.2877 0.87781E+00 -0.0566 35 CaCl2,aq 0.14516E-15 -15.8382 0.14516E-15 -15.8382 0.10000E+01 0.0000 36 CaOH+ 0.16320E-07 -7.7873 0.14326E-07 -7.8439 0.87781E+00 -0.0566 37 CaSO4,aq 0.13363E-09 -9.8741 0.13363E-09 -9.8741 0.10000E+01 0.0000 38 HCl,aq 0.29953E-14 -14.5236 0.29953E-14 -14.5236 0.10000E+01 0.0000 43 FeCl+ 0.14174E-16 -16.8485 0.12442E-16 -16.9051 0.87781E+00 -0.0566 46 FeO,aq 0.15063E-09 -9.8221 0.15063E-09 -9.8221 0.10000E+01 0.0000 47 FeOH+ 0.18946E-10 -10.7225 0.16631E-10 -10.7791 0.87781E+00 -0.0566 48 HFeO2- 0.14029E-07 -7.8530 0.12303E-07 -7.9100 0.87697E+00 -0.0570 49 FeO+ 0.12410E-14 -14.9062 0.10894E-14 -14.9628 0.87781E+00 -0.0566 51 FeO2- 0.14078E-07 -7.8515 0.12346E-07 -7.9085 0.87697E+00 -0.0570 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.13823E-08 -8.8594 0.13802E-08 -8.8601 0.99846E+00 -0.0007 54 KCl,aq 0.12796E-09 -9.8929 0.12796E-09 -9.8929 0.10000E+01 0.0000 55 KHSO4,aq 0.33757E-18 -18.4716 0.33757E-18 -18.4716 0.10000E+01 0.0000 56 KOH,aq 0.19783E-06 -6.7037 0.19783E-06 -6.7037 0.10000E+01 0.0000 57 KSO4- 0.16829E-07 -7.7740 0.14758E-07 -7.8310 0.87697E+00 -0.0570 58 MgCO3,aq 0.13905E-12 -12.8568 0.13905E-12 -12.8568 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18941E-14 -14.7226 0.16627E-14 -14.7792 0.87781E+00 -0.0566 60 MgCl+ 0.22257E-14 -14.6525 0.19537E-14 -14.7091 0.87781E+00 -0.0566 61 MgOH+ 0.37742E-10 -10.4232 0.33131E-10 -10.4798 0.87781E+00 -0.0566 63 MnO,aq 0.53735E-09 -9.2697 0.53735E-09 -9.2697 0.10000E+01 0.0000 64 MnOH+ 0.23519E-09 -9.6286 0.20645E-09 -9.6852 0.87781E+00 -0.0566 65 MnO2-2 0.17083E-11 -11.7674 0.10716E-11 -11.9700 0.62726E+00 -0.2026 66 HMnO2- 0.34864E-10 -10.4576 0.30574E-10 -10.5146 0.87697E+00 -0.0570 69 MnCl+ 0.73600E-14 -14.1331 0.64607E-14 -14.1897 0.87781E+00 -0.0566 70 MnSO4,aq 0.40102E-13 -13.3968 0.40102E-13 -13.3968 0.10000E+01 0.0000 71 NaCl,aq 0.29942E-06 -6.5237 0.29942E-06 -6.5237 0.10000E+01 0.0000 72 NaOH,aq 0.25303E-04 -4.5968 0.25303E-04 -4.5968 0.10000E+01 0.0000 74 OH- 0.51986E-02 -2.2841 0.45549E-02 -2.3415 0.87617E+00 -0.0574 79 HPO3-2 0.19623E-17 -17.7072 0.12309E-17 -17.9098 0.62726E+00 -0.2026 82 H3PO4,aq 0.31524E-16 -16.5014 0.31524E-16 -16.5014 0.10000E+01 0.0000 83 H2PO4- 0.74300E-09 -9.1290 0.65189E-09 -9.1858 0.87738E+00 -0.0568 84 PO4-3 0.51232E-08 -8.2905 0.18724E-08 -8.7276 0.36548E+00 -0.4371 87 H2P2O7-2 0.53024E-19 -19.2755 0.33260E-19 -19.4781 0.62726E+00 -0.2026 88 HP2O7-3 0.14519E-15 -15.8381 0.51788E-16 -16.2858 0.35668E+00 -0.4477 89 P2O7-4 0.59019E-15 -15.2290 0.97015E-16 -16.0132 0.16438E+00 -0.7842 90 H2S,aq 0.15093E-15 -15.8212 0.15070E-15 -15.8219 0.99846E+00 -0.0007 97 SO3-2 0.47742E-14 -14.3211 0.30165E-14 -14.5205 0.63183E+00 -0.1994 98 HSO3- 0.26509E-16 -16.5766 0.23248E-16 -16.6336 0.87697E+00 -0.0570 99 HSO4- 0.22302E-11 -11.6517 0.19586E-11 -11.7081 0.87823E+00 -0.0564 Charge balance for all species = 0.8531E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1497105E-09 -.9098071E-02 -.9164613E+01 0.0000 2 H2O 0.1000000E+01 0.5551004E+02 0.9994088E+06 0.0000 3 Cl- 0.1378870E-03 0.1381865E-03 0.4896084E+01 5.9629 4 SO4-- 0.2552676E-04 0.2554516E-04 0.2452385E+01 14.9658 5 HCO3- 0.6602007E-05 0.1309012E-04 0.7982261E+00 4.6434 6 HS- 0.4342746E-12 -.1439128E-08 -.4756529E-04 -2.5388 7 Al+++ 0.9298947E-27 0.7257811E-04 0.1957050E+01 2.1619 8 H4SiO4 0.3829605E-03 0.3959998E-02 0.3803803E+03 -3.4168 9 Ca++ 0.4276648E-07 0.6250142E-07 0.2503376E-02 12.1883 10 Mg++ 0.1789321E-10 0.5678522E-10 0.1379705E-05 8.8089 11 Fe++ 0.1057789E-12 0.2848016E-07 0.1589543E-02 6.5808 12 K+ 0.6808719E-04 0.6830198E-04 0.2669085E+01 5.6569 13 Na+ 0.8647805E-02 0.9015127E-02 0.2071272E+03 7.7603 14 Mn++ 0.1412930E-10 0.8232876E-09 0.4520168E-04 8.7067 15 HPO4-- 0.4496170E-06 0.4554832E-06 0.4368966E-01 13.2117 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1523087E+00 -.9084089E-02 -.1432247E+00 0.0000000E+00 2 H2O 0.5539294E+02 0.5542474E+02 -.3179997E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2804401E-03 0.2550591E-04 0.2549342E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2549356E-03 -.1436917E-08 -.2549342E-03 0.0000000E+00 7 Al+++ 0.2999556E-01 0.7246658E-04 0.2992310E-01 0.0000000E+00 8 H4SiO4 0.9578719E-01 0.3953912E-02 0.9183328E-01 0.0000000E+00 9 Ca++ 0.1059463E-01 0.6240537E-07 0.1059457E-01 0.0000000E+00 10 Mg++ 0.7300794E-02 0.5669795E-10 0.7300794E-02 0.0000000E+00 11 Fe++ 0.6558966E-02 0.2843639E-07 0.6558938E-02 0.0000000E+00 12 K+ 0.1953079E-02 0.6819701E-04 0.1884882E-02 0.0000000E+00 13 Na+ 0.1170706E-01 0.9001273E-02 0.2705784E-02 0.0000000E+00 14 Mn++ 0.1594977E-03 0.8220224E-09 0.1594969E-03 0.0000000E+00 15 HPO4-- 0.5443579E-04 0.4547832E-06 0.5398100E-04 0.0000000E+00 Chg. balance for solid moles: -.1052E-16 Mass of aqueous solution: 0.999084E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 9.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2706E-02 -2.568 0.7095 -0.149 7.059 0.2724 apatite-OH 0.1799E-04 -4.745 0.9039E-02 -2.044 0.8993E-01 0.2872E-02 clinochlore 0.1460E-02 -2.836 0.8116 -0.091 8.075 0.3087 daphnite 0.9039E-03 -3.044 0.6449 -0.190 6.417 0.1954 chlorite-Mn 0.3190E-04 -4.496 0.2262E-01 -1.646 0.2250 0.7207E-02 hematite 0.9416E-03 -3.026 0.1504 -0.823 1.496 0.2850E-01 lawsonite 0.1881E-03 -3.726 0.5910E-01 -1.228 0.5880 0.1906E-01 microcline 0.1885E-02 -2.725 0.5246 -0.280 5.220 0.2049 prehnite-Fe 0.1562E-03 -3.806 0.6893E-01 -1.162 0.6858 0.2312E-01 stilbite 0.1000E-01 -2.000 7.050 0.848 70.14 3.288 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 10.050829 g Volume = 4.350495 cm3 Porosity: 7.0328% V(tot) - V(min): 0.32911E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 9.1990000 g log = 0.9637 Original solution: 1000.0103000 g Original solution / Rock added: 108.71 (Water/Rock Ratio), log = 2.0363 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1662E-06 1.0073 0.1761E-06 0.1748E-06 CH4,gas 0.2005E-15 1.0129 0.2136E-15 0.2109E-15 H2,gas 0.1799E-05 1.0006 0.1893E-05 0.1892E-05 H2S,gas 0.4195E-14 0.9959 0.4395E-14 0.4413E-14 S2,gas 0.1919E-36 1.0000 0.2019E-36 0.2019E-36 CO,gas 0.8209E-16 1.0000 0.8635E-16 0.8635E-16 SO3,gas 0.9879E-40 1.0000 0.1039E-39 0.1039E-39 SO2,gas 0.7075E-23 1.0000 0.7443E-23 0.7443E-23 HCl,gas 0.5028E-17 1.0000 0.5289E-17 0.5289E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 137 prehnite-Fe 22.59 22.59 0.00 0.000 0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.12 -8.75 -2.918 0.14948E+05 -6.754 3 CH4,gas 4.81 -12.86 -17.67 -4.418 0.30172E+05 -15.670 4 H2,gas 8.29 0.56 -7.72 -4.413 0.13187E+05 -5.723 5 H2S,gas -5.94 -22.30 -16.36 -8.179 0.27929E+05 -14.357 6 S2,gas -7.03 -45.73 -38.69 -5.953 0.66070E+05 -36.695 7 CO,gas 3.51 -14.55 -18.06 -5.558 0.30843E+05 -16.064 8 SO3,gas 17.43 -24.56 -41.98 -10.496 0.71685E+05 -39.983 9 SO2,gas 1.14 -23.99 -25.13 -6.701 0.42906E+05 -23.128 10 HCl,gas 5.48 -13.80 -19.28 -9.638 0.32914E+05 -17.277 11 acmite 7.74 7.23 -0.51 -0.053 0.87419E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.19 -4.36 -0.218 0.74385E+04 20 analcite 3.37 3.09 -0.28 -0.031 0.48177E+03 21 andalusite 5.06 0.91 -4.16 -0.416 0.70953E+04 22 andradite 39.09 38.91 -0.18 -0.009 0.30007E+03 23 grossular 32.83 30.64 -2.19 -0.110 0.37395E+04 26 annite 20.21 17.31 -2.90 -0.161 0.49493E+04 27 phlogopite 27.15 23.99 -3.15 -0.175 0.53815E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.93 -3.92 -1.305 0.66854E+04 36 brucite 12.58 8.81 -3.77 -0.754 0.64333E+04 37 calcite 0.83 -2.93 -3.76 -1.254 0.64241E+04 38 carnegieite-low 9.06 6.51 -2.56 -0.366 0.43698E+04 39 carnegieite-high 10.13 6.51 -3.63 -0.518 0.61967E+04 40 carpholite-Mg 8.65 6.30 -2.35 -0.157 0.40150E+04 41 carpholite-Fe 6.78 4.07 -2.71 -0.181 0.46306E+04 42 celadonite 5.40 2.96 -2.44 -0.144 0.41667E+04 43 celadonite-Fe 3.94 0.73 -3.20 -0.189 0.54720E+04 44 chrysotile 23.94 19.59 -4.34 -0.362 0.74179E+04 50 chloritoid-Mg 13.26 9.72 -3.55 -0.236 0.60537E+04 51 chloritoid-Fe 9.24 7.49 -1.75 -0.117 0.29896E+04 52 chloritoid-Mn 11.46 9.61 -1.85 -0.123 0.31581E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 4.32 -4.11 -0.374 0.70171E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.16 -0.73 -0.122 0.12536E+04 67 diopside 16.22 14.16 -2.05 -0.205 0.35037E+04 68 hedenbergite 14.24 11.94 -2.31 -0.231 0.39425E+04 75 epidote 24.78 24.75 -0.03 -0.001 0.45350E+02 76 clinozoisite 22.92 20.61 -2.31 -0.105 0.39433E+04 77 epidote-Fe 29.94 28.89 -1.05 -0.055 0.17949E+04 78 fayalite 14.08 9.74 -4.33 -0.619 0.74004E+04 79 ferrosilite 11.19 6.33 -4.86 -0.486 0.82978E+04 83 gibbsite 4.10 2.16 -1.94 -0.277 0.33048E+04 84 glaucophane 23.11 18.94 -4.17 -0.113 0.71275E+04 87 greenalite 16.19 12.91 -3.29 -0.274 0.56097E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.09 -1.16 -0.116 0.19848E+04 96 julgoldite 70.57 66.61 -3.96 -0.103 0.67681E+04 97 kalsilite 7.62 4.40 -3.22 -0.460 0.54953E+04 98 kaolinite -1.27 -2.51 -1.24 -0.112 0.21118E+04 99 kyanite 4.93 0.91 -4.02 -0.402 0.68721E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.99 -3.18 -0.318 0.54342E+04 105 lizardite 23.29 19.59 -3.69 -0.308 0.63082E+04 107 magnetite 20.13 19.18 -0.95 -0.078 0.16295E+04 108 minnesotaite 10.46 6.08 -4.39 -0.258 0.74883E+04 110 magnesioferrite 26.26 21.41 -4.85 -0.396 0.82825E+04 113 margarite 17.45 14.00 -3.45 -0.138 0.58902E+04 120 muscovite 2.68 1.89 -0.79 -0.046 0.13442E+04 121 paragonite 4.34 4.00 -0.34 -0.020 0.58264E+03 122 nepheline 8.38 6.51 -1.87 -0.268 0.31977E+04 134 phlogopite-Na 29.73 26.10 -3.63 -0.202 0.62034E+04 136 prehnite 19.47 18.45 -1.02 -0.060 0.17356E+04 138 pumpellyite-Fe 46.47 45.64 -0.83 -0.018 0.14141E+04 139 pumpellyite-Mg 49.19 47.87 -1.32 -0.029 0.22600E+04 145 pyroxmangite 7.42 5.29 -2.13 -0.425 0.36303E+04 146 pyrophyllite -6.10 -9.34 -3.25 -0.203 0.55418E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodonite 7.46 5.29 -2.17 -0.435 0.37096E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.91 -4.41 -0.441 0.75375E+04 164 stilpnomelane-Fe 13.18 12.72 -0.46 -0.014 0.78154E+03 165 stilpnomelane-Mg 27.60 23.86 -3.73 -0.111 0.63764E+04 171 talc 16.55 12.76 -3.79 -0.223 0.64783E+04 174 tephroite 18.11 14.00 -4.12 -0.588 0.70284E+04 177 topaz-H 4.67 0.91 -3.76 -0.342 0.64212E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 8.77 -2.76 -0.551 0.47065E+04 189 wollastonite 10.48 8.77 -1.71 -0.342 0.29204E+04 190 pseudo-wollastonite 11.02 8.77 -2.25 -0.450 0.38390E+04 191 zoisite 22.96 20.61 -2.35 -0.107 0.40158E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.49 -3.93 -0.243 0.67136E+04 195 beidellite-K -1.44 -5.64 -4.20 -0.257 0.71728E+04 196 beidellite-Mg -1.71 -6.05 -4.34 -0.269 0.74143E+04 197 beidellite-Na -1.26 -4.94 -3.68 -0.226 0.62916E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -5.14 -2.93 -0.181 0.49944E+04 202 montmorillonite-K -2.16 -5.28 -3.12 -0.191 0.53314E+04 203 montmorillonite-Mg -2.40 -5.70 -3.30 -0.204 0.56262E+04 204 montmorillonite-Na -1.96 -4.59 -2.63 -0.161 0.44882E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.77 -1.82 -0.122 0.31153E+04 207 nontronite-K 3.40 2.64 -0.77 -0.049 0.13076E+04 208 nontronite-Mg 3.14 2.22 -0.91 -0.059 0.15616E+04 209 nontronite-Na 3.58 3.33 -0.25 -0.016 0.42807E+03 224 tobermorite 9.84 6.74 -3.10 -0.847 0.52983E+04 233 boehmite 4.43 2.16 -2.27 -0.378 0.38721E+04 235 ferrous-oxide 9.82 6.58 -3.24 -0.811 0.55380E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 1.67 -0.41 -0.031 0.69361E+03 243 an25ab75 2.71 2.17 -0.54 -0.041 0.91492E+03 244 an30ab70 3.34 2.67 -0.67 -0.052 0.11446E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 9.1990000 g New total amount of reactant added: 9.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8639E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 9.5990000 Water: Moles liquid = 0.5542E+02 kg liquid = 0.9984E+00 Moles total = 0.5539E+02 kg total = 0.9978E+00 Activity = 1.0000 Stoichiometric ionic strength = .4995985E-02 Osmotic coef. = 0.9625 True ionic strength = .8748523E-02 Chg. balance for total moles = 0.8639E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14971E-09 -9.8247 0.13169E-09 -9.8804 0.87964E+00 -0.0557 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13789E-03 -3.8605 0.12093E-03 -3.9175 0.87697E+00 -0.0570 4 SO4-- 0.25528E-04 -4.5930 0.16030E-04 -4.7951 0.62793E+00 -0.2021 5 HCO3- 0.66023E-05 -5.1803 0.57942E-05 -5.2370 0.87761E+00 -0.0567 6 HS- 0.43429E-12 -12.3622 0.38089E-12 -12.4192 0.87703E+00 -0.0570 7 Al+++ 0.92990E-27 -27.0316 0.33155E-27 -27.4795 0.35654E+00 -0.4479 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.42767E-07 -7.3689 0.26756E-07 -7.5726 0.62563E+00 -0.2037 10 Mg++ 0.17893E-10 -10.7473 0.11169E-10 -10.9520 0.62419E+00 -0.2047 11 Fe++ 0.10578E-12 -12.9756 0.66062E-13 -13.1800 0.62453E+00 -0.2044 12 K+ 0.68087E-04 -4.1669 0.59761E-04 -4.2236 0.87772E+00 -0.0566 13 Na+ 0.86478E-02 -2.0631 0.75832E-02 -2.1201 0.87690E+00 -0.0571 14 Mn++ 0.14129E-10 -10.8499 0.88279E-11 -11.0541 0.62479E+00 -0.2043 15 HPO4-- 0.44962E-06 -6.3472 0.28235E-06 -6.5492 0.62798E+00 -0.2021 16 HSiO3- 0.32353E-02 -2.4901 0.28373E-02 -2.5471 0.87697E+00 -0.0570 17 Ca(HSiO3)+ 0.19376E-08 -8.7127 0.17009E-08 -8.7693 0.87781E+00 -0.0566 18 Mg(HSiO3)+ 0.10066E-11 -11.9971 0.88359E-12 -12.0537 0.87781E+00 -0.0566 19 NaHSiO3,aq 0.34172E-03 -3.4663 0.34172E-03 -3.4663 0.10000E+01 0.0000 20 AlO+ 0.28115E-14 -14.5511 0.24680E-14 -14.6077 0.87781E+00 -0.0566 22 HAlO2,aq 0.37502E-08 -8.4259 0.37502E-08 -8.4259 0.10000E+01 0.0000 23 AlO2- 0.72574E-04 -4.1392 0.63587E-04 -4.1966 0.87617E+00 -0.0574 24 CH4,aq 0.13531E-18 -18.8687 0.13510E-18 -18.8694 0.99846E+00 -0.0007 29 CO,aq 0.54688E-19 -19.2621 0.54688E-19 -19.2621 0.10000E+01 0.0000 30 CO2,aq 0.15408E-08 -8.8122 0.15385E-08 -8.8129 0.99846E+00 -0.0007 31 CO3-2 0.64855E-05 -5.1881 0.40681E-05 -5.3906 0.62726E+00 -0.2026 32 CaCO3,aq 0.13331E-08 -8.8751 0.13331E-08 -8.8751 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44500E-11 -11.3516 0.39063E-11 -11.4082 0.87781E+00 -0.0566 34 CaCl+ 0.58734E-11 -11.2311 0.51558E-11 -11.2877 0.87781E+00 -0.0566 35 CaCl2,aq 0.14517E-15 -15.8381 0.14517E-15 -15.8381 0.10000E+01 0.0000 36 CaOH+ 0.16320E-07 -7.7873 0.14326E-07 -7.8439 0.87781E+00 -0.0566 37 CaSO4,aq 0.13363E-09 -9.8741 0.13363E-09 -9.8741 0.10000E+01 0.0000 38 HCl,aq 0.29954E-14 -14.5235 0.29954E-14 -14.5235 0.10000E+01 0.0000 43 FeCl+ 0.14174E-16 -16.8485 0.12443E-16 -16.9051 0.87781E+00 -0.0566 46 FeO,aq 0.15063E-09 -9.8221 0.15063E-09 -9.8221 0.10000E+01 0.0000 47 FeOH+ 0.18946E-10 -10.7225 0.16631E-10 -10.7791 0.87781E+00 -0.0566 48 HFeO2- 0.14029E-07 -7.8530 0.12303E-07 -7.9100 0.87697E+00 -0.0570 49 FeO+ 0.12410E-14 -14.9062 0.10894E-14 -14.9628 0.87781E+00 -0.0566 51 FeO2- 0.14078E-07 -7.8515 0.12346E-07 -7.9085 0.87697E+00 -0.0570 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.13823E-08 -8.8594 0.13802E-08 -8.8601 0.99846E+00 -0.0007 54 KCl,aq 0.12796E-09 -9.8929 0.12796E-09 -9.8929 0.10000E+01 0.0000 55 KHSO4,aq 0.33759E-18 -18.4716 0.33759E-18 -18.4716 0.10000E+01 0.0000 56 KOH,aq 0.19783E-06 -6.7037 0.19783E-06 -6.7037 0.10000E+01 0.0000 57 KSO4- 0.16829E-07 -7.7739 0.14759E-07 -7.8310 0.87697E+00 -0.0570 58 MgCO3,aq 0.13905E-12 -12.8568 0.13905E-12 -12.8568 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18942E-14 -14.7226 0.16628E-14 -14.7792 0.87781E+00 -0.0566 60 MgCl+ 0.22257E-14 -14.6525 0.19538E-14 -14.7091 0.87781E+00 -0.0566 61 MgOH+ 0.37742E-10 -10.4232 0.33131E-10 -10.4798 0.87781E+00 -0.0566 63 MnO,aq 0.53735E-09 -9.2697 0.53735E-09 -9.2697 0.10000E+01 0.0000 64 MnOH+ 0.23519E-09 -9.6286 0.20645E-09 -9.6852 0.87781E+00 -0.0566 65 MnO2-2 0.17083E-11 -11.7674 0.10716E-11 -11.9700 0.62726E+00 -0.2026 66 HMnO2- 0.34864E-10 -10.4576 0.30574E-10 -10.5146 0.87697E+00 -0.0570 69 MnCl+ 0.73603E-14 -14.1331 0.64610E-14 -14.1897 0.87781E+00 -0.0566 70 MnSO4,aq 0.40104E-13 -13.3968 0.40104E-13 -13.3968 0.10000E+01 0.0000 71 NaCl,aq 0.29943E-06 -6.5237 0.29943E-06 -6.5237 0.10000E+01 0.0000 72 NaOH,aq 0.25303E-04 -4.5968 0.25303E-04 -4.5968 0.10000E+01 0.0000 74 OH- 0.51986E-02 -2.2841 0.45549E-02 -2.3415 0.87617E+00 -0.0574 79 HPO3-2 0.19623E-17 -17.7072 0.12309E-17 -17.9098 0.62726E+00 -0.2026 82 H3PO4,aq 0.31524E-16 -16.5014 0.31524E-16 -16.5014 0.10000E+01 0.0000 83 H2PO4- 0.74300E-09 -9.1290 0.65189E-09 -9.1858 0.87738E+00 -0.0568 84 PO4-3 0.51232E-08 -8.2905 0.18724E-08 -8.7276 0.36548E+00 -0.4371 87 H2P2O7-2 0.53024E-19 -19.2755 0.33260E-19 -19.4781 0.62726E+00 -0.2026 88 HP2O7-3 0.14519E-15 -15.8381 0.51788E-16 -16.2858 0.35668E+00 -0.4477 89 P2O7-4 0.59018E-15 -15.2290 0.97014E-16 -16.0132 0.16438E+00 -0.7842 90 H2S,aq 0.15094E-15 -15.8212 0.15071E-15 -15.8219 0.99846E+00 -0.0007 97 SO3-2 0.47744E-14 -14.3211 0.30166E-14 -14.5205 0.63183E+00 -0.1994 98 HSO3- 0.26510E-16 -16.5766 0.23248E-16 -16.6336 0.87697E+00 -0.0570 99 HSO4- 0.22303E-11 -11.6516 0.19587E-11 -11.7080 0.87823E+00 -0.0564 Charge balance for all species = 0.8522E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1497106E-09 -.9098067E-02 -.9164609E+01 0.0000 2 H2O 0.1000000E+01 0.5551004E+02 0.9994088E+06 0.0000 3 Cl- 0.1378926E-03 0.1381921E-03 0.4896282E+01 5.9630 4 SO4-- 0.2552779E-04 0.2554620E-04 0.2452484E+01 14.9658 5 HCO3- 0.6602275E-05 0.1309065E-04 0.7982583E+00 4.6434 6 HS- 0.4342926E-12 -.1439128E-08 -.4756526E-04 -2.5388 7 Al+++ 0.9298964E-27 0.7257808E-04 0.1957049E+01 2.1619 8 H4SiO4 0.3829605E-03 0.3959996E-02 0.3803802E+03 -3.4168 9 Ca++ 0.4276653E-07 0.6250154E-07 0.2503381E-02 12.1883 10 Mg++ 0.1789323E-10 0.5678526E-10 0.1379706E-05 8.8089 11 Fe++ 0.1057790E-12 0.2848015E-07 0.1589543E-02 6.5808 12 K+ 0.6808722E-04 0.6830201E-04 0.2669086E+01 5.6569 13 Na+ 0.8647810E-02 0.9015132E-02 0.2071273E+03 7.7603 14 Mn++ 0.1412932E-10 0.8232878E-09 0.4520169E-04 8.7067 15 HPO4-- 0.4496166E-06 0.4554828E-06 0.4368963E-01 13.2117 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1589321E+00 -.9083719E-02 -.1498484E+00 0.0000000E+00 2 H2O 0.5538792E+02 0.5542250E+02 -.3457570E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2915255E-03 0.2550591E-04 0.2660196E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2660210E-03 -.1436858E-08 -.2660196E-03 0.0000000E+00 7 Al+++ 0.3129986E-01 0.7246362E-04 0.3122740E-01 0.0000000E+00 8 H4SiO4 0.9995230E-01 0.3953751E-02 0.9599855E-01 0.0000000E+00 9 Ca++ 0.1105469E-01 0.6240297E-07 0.1105463E-01 0.0000000E+00 10 Mg++ 0.7618254E-02 0.5669571E-10 0.7618254E-02 0.0000000E+00 11 Fe++ 0.6844169E-02 0.2843523E-07 0.6844141E-02 0.0000000E+00 12 K+ 0.2038004E-02 0.6819430E-04 0.1969810E-02 0.0000000E+00 13 Na+ 0.1220915E-01 0.9000914E-02 0.3208240E-02 0.0000000E+00 14 Mn++ 0.1664332E-03 0.8219894E-09 0.1664324E-03 0.0000000E+00 15 HPO4-- 0.5680282E-04 0.4547645E-06 0.5634805E-04 0.0000000E+00 Chg. balance for solid moles: 0.1404E-16 Mass of aqueous solution: 0.999044E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 9.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3208E-02 -2.494 0.8413 -0.075 8.021 0.3229 apatite-OH 0.1878E-04 -4.726 0.9435E-02 -2.025 0.8996E-01 0.2998E-02 clinochlore 0.1524E-02 -2.817 0.8469 -0.072 8.075 0.3221 daphnite 0.9432E-03 -3.025 0.6730 -0.172 6.417 0.2039 chlorite-Mn 0.3329E-04 -4.478 0.2360E-01 -1.627 0.2250 0.7520E-02 hematite 0.9187E-03 -3.037 0.1467 -0.834 1.399 0.2781E-01 lawsonite 0.1125E-03 -3.949 0.3534E-01 -1.452 0.3370 0.1140E-01 microcline 0.1970E-02 -2.706 0.5483 -0.261 5.228 0.2142 prehnite-Fe 0.2908E-03 -3.536 0.1283 -0.892 1.223 0.4304E-01 stilbite 0.1027E-01 -1.989 7.235 0.859 68.99 3.375 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 10.487940 g Volume = 4.530539 cm3 Porosity: 6.3861% V(tot) - V(min): 0.30906E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 9.5990000 g log = 0.9822 Original solution: 1000.0103000 g Original solution / Rock added: 104.18 (Water/Rock Ratio), log = 2.0178 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1662E-06 1.0073 0.1761E-06 0.1748E-06 CH4,gas 0.2005E-15 1.0129 0.2136E-15 0.2109E-15 H2,gas 0.1799E-05 1.0006 0.1893E-05 0.1892E-05 H2S,gas 0.4196E-14 0.9959 0.4395E-14 0.4414E-14 S2,gas 0.1920E-36 1.0000 0.2019E-36 0.2019E-36 CO,gas 0.8209E-16 1.0000 0.8635E-16 0.8635E-16 SO3,gas 0.9880E-40 1.0000 0.1039E-39 0.1039E-39 SO2,gas 0.7075E-23 1.0000 0.7443E-23 0.7443E-23 HCl,gas 0.5028E-17 1.0000 0.5289E-17 0.5289E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 137 prehnite-Fe 22.59 22.59 0.00 0.000 -0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.12 -8.75 -2.918 0.14948E+05 -6.754 3 CH4,gas 4.81 -12.86 -17.67 -4.418 0.30172E+05 -15.670 4 H2,gas 8.29 0.56 -7.72 -4.413 0.13187E+05 -5.723 5 H2S,gas -5.94 -22.30 -16.36 -8.178 0.27929E+05 -14.357 6 S2,gas -7.03 -45.73 -38.69 -5.953 0.66070E+05 -36.695 7 CO,gas 3.51 -14.55 -18.06 -5.558 0.30843E+05 -16.064 8 SO3,gas 17.43 -24.56 -41.98 -10.496 0.71685E+05 -39.983 9 SO2,gas 1.14 -23.99 -25.13 -6.701 0.42906E+05 -23.128 10 HCl,gas 5.48 -13.80 -19.28 -9.638 0.32914E+05 -17.277 11 acmite 7.74 7.23 -0.51 -0.053 0.87419E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.19 -4.36 -0.218 0.74385E+04 20 analcite 3.37 3.09 -0.28 -0.031 0.48177E+03 21 andalusite 5.06 0.91 -4.16 -0.416 0.70953E+04 22 andradite 39.09 38.91 -0.18 -0.009 0.30007E+03 23 grossular 32.83 30.64 -2.19 -0.110 0.37395E+04 26 annite 20.21 17.31 -2.90 -0.161 0.49493E+04 27 phlogopite 27.15 23.99 -3.15 -0.175 0.53815E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.93 -3.92 -1.305 0.66854E+04 36 brucite 12.58 8.81 -3.77 -0.754 0.64333E+04 37 calcite 0.83 -2.93 -3.76 -1.254 0.64240E+04 38 carnegieite-low 9.06 6.51 -2.56 -0.366 0.43698E+04 39 carnegieite-high 10.13 6.51 -3.63 -0.518 0.61967E+04 40 carpholite-Mg 8.65 6.30 -2.35 -0.157 0.40150E+04 41 carpholite-Fe 6.78 4.07 -2.71 -0.181 0.46306E+04 42 celadonite 5.40 2.96 -2.44 -0.144 0.41667E+04 43 celadonite-Fe 3.94 0.73 -3.20 -0.189 0.54720E+04 44 chrysotile 23.94 19.59 -4.34 -0.362 0.74179E+04 50 chloritoid-Mg 13.26 9.72 -3.55 -0.236 0.60537E+04 51 chloritoid-Fe 9.24 7.49 -1.75 -0.117 0.29896E+04 52 chloritoid-Mn 11.46 9.61 -1.85 -0.123 0.31581E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 4.32 -4.11 -0.374 0.70171E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.16 -0.73 -0.122 0.12536E+04 67 diopside 16.22 14.16 -2.05 -0.205 0.35037E+04 68 hedenbergite 14.24 11.94 -2.31 -0.231 0.39425E+04 75 epidote 24.78 24.75 -0.03 -0.001 0.45350E+02 76 clinozoisite 22.92 20.61 -2.31 -0.105 0.39433E+04 77 epidote-Fe 29.94 28.89 -1.05 -0.055 0.17949E+04 78 fayalite 14.08 9.74 -4.33 -0.619 0.74004E+04 79 ferrosilite 11.19 6.33 -4.86 -0.486 0.82978E+04 83 gibbsite 4.10 2.16 -1.94 -0.277 0.33048E+04 84 glaucophane 23.11 18.94 -4.17 -0.113 0.71275E+04 87 greenalite 16.19 12.91 -3.29 -0.274 0.56097E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.09 -1.16 -0.116 0.19848E+04 96 julgoldite 70.57 66.61 -3.96 -0.103 0.67681E+04 97 kalsilite 7.62 4.40 -3.22 -0.460 0.54953E+04 98 kaolinite -1.27 -2.51 -1.24 -0.112 0.21118E+04 99 kyanite 4.93 0.91 -4.02 -0.402 0.68721E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.99 -3.18 -0.318 0.54342E+04 105 lizardite 23.29 19.59 -3.69 -0.308 0.63082E+04 107 magnetite 20.13 19.18 -0.95 -0.078 0.16295E+04 108 minnesotaite 10.46 6.08 -4.39 -0.258 0.74883E+04 110 magnesioferrite 26.26 21.41 -4.85 -0.396 0.82825E+04 113 margarite 17.45 14.00 -3.45 -0.138 0.58902E+04 120 muscovite 2.68 1.89 -0.79 -0.046 0.13442E+04 121 paragonite 4.34 4.00 -0.34 -0.020 0.58264E+03 122 nepheline 8.38 6.51 -1.87 -0.268 0.31977E+04 134 phlogopite-Na 29.73 26.10 -3.63 -0.202 0.62034E+04 136 prehnite 19.47 18.45 -1.02 -0.060 0.17356E+04 138 pumpellyite-Fe 46.47 45.64 -0.83 -0.018 0.14141E+04 139 pumpellyite-Mg 49.19 47.87 -1.32 -0.029 0.22600E+04 145 pyroxmangite 7.42 5.29 -2.13 -0.425 0.36303E+04 146 pyrophyllite -6.10 -9.34 -3.25 -0.203 0.55418E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodonite 7.46 5.29 -2.17 -0.435 0.37096E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.91 -4.41 -0.441 0.75375E+04 164 stilpnomelane-Fe 13.18 12.72 -0.46 -0.014 0.78154E+03 165 stilpnomelane-Mg 27.60 23.86 -3.73 -0.111 0.63764E+04 171 talc 16.55 12.76 -3.79 -0.223 0.64783E+04 174 tephroite 18.11 14.00 -4.12 -0.588 0.70284E+04 177 topaz-H 4.67 0.91 -3.76 -0.342 0.64212E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 8.77 -2.76 -0.551 0.47065E+04 189 wollastonite 10.48 8.77 -1.71 -0.342 0.29204E+04 190 pseudo-wollastonite 11.02 8.77 -2.25 -0.450 0.38390E+04 191 zoisite 22.96 20.61 -2.35 -0.107 0.40158E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.49 -3.93 -0.243 0.67136E+04 195 beidellite-K -1.44 -5.64 -4.20 -0.257 0.71728E+04 196 beidellite-Mg -1.71 -6.05 -4.34 -0.269 0.74143E+04 197 beidellite-Na -1.26 -4.94 -3.68 -0.226 0.62916E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -5.14 -2.93 -0.181 0.49944E+04 202 montmorillonite-K -2.16 -5.28 -3.12 -0.191 0.53314E+04 203 montmorillonite-Mg -2.40 -5.70 -3.30 -0.204 0.56262E+04 204 montmorillonite-Na -1.96 -4.59 -2.63 -0.161 0.44882E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.77 -1.82 -0.122 0.31153E+04 207 nontronite-K 3.40 2.64 -0.77 -0.049 0.13076E+04 208 nontronite-Mg 3.14 2.22 -0.91 -0.059 0.15616E+04 209 nontronite-Na 3.58 3.33 -0.25 -0.016 0.42807E+03 224 tobermorite 9.84 6.74 -3.10 -0.847 0.52983E+04 233 boehmite 4.43 2.16 -2.27 -0.378 0.38721E+04 235 ferrous-oxide 9.82 6.58 -3.24 -0.811 0.55380E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 1.67 -0.41 -0.031 0.69361E+03 243 an25ab75 2.71 2.17 -0.54 -0.041 0.91492E+03 244 an30ab70 3.34 2.67 -0.67 -0.052 0.11446E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 9.5990000 g New total amount of reactant added: 9.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8637E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 9.9990000 Water: Moles liquid = 0.5542E+02 kg liquid = 0.9984E+00 Moles total = 0.5538E+02 kg total = 0.9977E+00 Activity = 1.0000 Stoichiometric ionic strength = .4995992E-02 Osmotic coef. = 0.9625 True ionic strength = .8748528E-02 Chg. balance for total moles = 0.8637E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14971E-09 -9.8247 0.13169E-09 -9.8804 0.87964E+00 -0.0557 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12093E-03 -3.9175 0.87697E+00 -0.0570 4 SO4-- 0.25529E-04 -4.5930 0.16030E-04 -4.7951 0.62793E+00 -0.2021 5 HCO3- 0.66025E-05 -5.1803 0.57944E-05 -5.2370 0.87761E+00 -0.0567 6 HS- 0.43431E-12 -12.3622 0.38090E-12 -12.4192 0.87703E+00 -0.0570 7 Al+++ 0.92990E-27 -27.0316 0.33155E-27 -27.4795 0.35654E+00 -0.4479 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.42767E-07 -7.3689 0.26756E-07 -7.5726 0.62563E+00 -0.2037 10 Mg++ 0.17893E-10 -10.7473 0.11169E-10 -10.9520 0.62419E+00 -0.2047 11 Fe++ 0.10578E-12 -12.9756 0.66062E-13 -13.1800 0.62453E+00 -0.2044 12 K+ 0.68087E-04 -4.1669 0.59761E-04 -4.2236 0.87772E+00 -0.0566 13 Na+ 0.86478E-02 -2.0631 0.75832E-02 -2.1201 0.87690E+00 -0.0571 14 Mn++ 0.14129E-10 -10.8499 0.88279E-11 -11.0541 0.62479E+00 -0.2043 15 HPO4-- 0.44962E-06 -6.3472 0.28235E-06 -6.5492 0.62798E+00 -0.2021 16 HSiO3- 0.32353E-02 -2.4901 0.28373E-02 -2.5471 0.87697E+00 -0.0570 17 Ca(HSiO3)+ 0.19376E-08 -8.7127 0.17009E-08 -8.7693 0.87781E+00 -0.0566 18 Mg(HSiO3)+ 0.10066E-11 -11.9971 0.88359E-12 -12.0537 0.87781E+00 -0.0566 19 NaHSiO3,aq 0.34172E-03 -3.4663 0.34172E-03 -3.4663 0.10000E+01 0.0000 20 AlO+ 0.28115E-14 -14.5511 0.24680E-14 -14.6077 0.87781E+00 -0.0566 22 HAlO2,aq 0.37502E-08 -8.4259 0.37502E-08 -8.4259 0.10000E+01 0.0000 23 AlO2- 0.72574E-04 -4.1392 0.63587E-04 -4.1966 0.87617E+00 -0.0574 24 CH4,aq 0.13531E-18 -18.8687 0.13510E-18 -18.8693 0.99846E+00 -0.0007 29 CO,aq 0.54691E-19 -19.2621 0.54691E-19 -19.2621 0.10000E+01 0.0000 30 CO2,aq 0.15409E-08 -8.8122 0.15385E-08 -8.8129 0.99846E+00 -0.0007 31 CO3-2 0.64858E-05 -5.1880 0.40682E-05 -5.3906 0.62726E+00 -0.2026 32 CaCO3,aq 0.13331E-08 -8.8751 0.13331E-08 -8.8751 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44502E-11 -11.3516 0.39064E-11 -11.4082 0.87781E+00 -0.0566 34 CaCl+ 0.58737E-11 -11.2311 0.51560E-11 -11.2877 0.87781E+00 -0.0566 35 CaCl2,aq 0.14518E-15 -15.8381 0.14518E-15 -15.8381 0.10000E+01 0.0000 36 CaOH+ 0.16320E-07 -7.7873 0.14326E-07 -7.8439 0.87781E+00 -0.0566 37 CaSO4,aq 0.13364E-09 -9.8741 0.13364E-09 -9.8741 0.10000E+01 0.0000 38 HCl,aq 0.29956E-14 -14.5235 0.29956E-14 -14.5235 0.10000E+01 0.0000 43 FeCl+ 0.14175E-16 -16.8485 0.12443E-16 -16.9051 0.87781E+00 -0.0566 46 FeO,aq 0.15063E-09 -9.8221 0.15063E-09 -9.8221 0.10000E+01 0.0000 47 FeOH+ 0.18946E-10 -10.7225 0.16631E-10 -10.7791 0.87781E+00 -0.0566 48 HFeO2- 0.14029E-07 -7.8530 0.12303E-07 -7.9100 0.87697E+00 -0.0570 49 FeO+ 0.12410E-14 -14.9062 0.10894E-14 -14.9628 0.87781E+00 -0.0566 51 FeO2- 0.14078E-07 -7.8515 0.12346E-07 -7.9085 0.87697E+00 -0.0570 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.13823E-08 -8.8594 0.13802E-08 -8.8601 0.99846E+00 -0.0007 54 KCl,aq 0.12797E-09 -9.8929 0.12797E-09 -9.8929 0.10000E+01 0.0000 55 KHSO4,aq 0.33760E-18 -18.4716 0.33760E-18 -18.4716 0.10000E+01 0.0000 56 KOH,aq 0.19783E-06 -6.7037 0.19783E-06 -6.7037 0.10000E+01 0.0000 57 KSO4- 0.16830E-07 -7.7739 0.14759E-07 -7.8309 0.87697E+00 -0.0570 58 MgCO3,aq 0.13906E-12 -12.8568 0.13906E-12 -12.8568 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18943E-14 -14.7226 0.16628E-14 -14.7791 0.87781E+00 -0.0566 60 MgCl+ 0.22258E-14 -14.6525 0.19539E-14 -14.7091 0.87781E+00 -0.0566 61 MgOH+ 0.37742E-10 -10.4232 0.33131E-10 -10.4798 0.87781E+00 -0.0566 63 MnO,aq 0.53735E-09 -9.2697 0.53735E-09 -9.2697 0.10000E+01 0.0000 64 MnOH+ 0.23519E-09 -9.6286 0.20645E-09 -9.6852 0.87781E+00 -0.0566 65 MnO2-2 0.17083E-11 -11.7674 0.10716E-11 -11.9700 0.62726E+00 -0.2026 66 HMnO2- 0.34864E-10 -10.4576 0.30574E-10 -10.5146 0.87697E+00 -0.0570 69 MnCl+ 0.73606E-14 -14.1331 0.64612E-14 -14.1897 0.87781E+00 -0.0566 70 MnSO4,aq 0.40105E-13 -13.3968 0.40105E-13 -13.3968 0.10000E+01 0.0000 71 NaCl,aq 0.29944E-06 -6.5237 0.29944E-06 -6.5237 0.10000E+01 0.0000 72 NaOH,aq 0.25303E-04 -4.5968 0.25303E-04 -4.5968 0.10000E+01 0.0000 74 OH- 0.51986E-02 -2.2841 0.45549E-02 -2.3415 0.87617E+00 -0.0574 79 HPO3-2 0.19623E-17 -17.7072 0.12309E-17 -17.9098 0.62726E+00 -0.2026 82 H3PO4,aq 0.31524E-16 -16.5014 0.31524E-16 -16.5014 0.10000E+01 0.0000 83 H2PO4- 0.74299E-09 -9.1290 0.65189E-09 -9.1858 0.87738E+00 -0.0568 84 PO4-3 0.51232E-08 -8.2905 0.18724E-08 -8.7276 0.36548E+00 -0.4371 87 H2P2O7-2 0.53024E-19 -19.2755 0.33260E-19 -19.4781 0.62726E+00 -0.2026 88 HP2O7-3 0.14519E-15 -15.8381 0.51788E-16 -16.2858 0.35668E+00 -0.4477 89 P2O7-4 0.59018E-15 -15.2290 0.97014E-16 -16.0132 0.16438E+00 -0.7842 90 H2S,aq 0.15095E-15 -15.8212 0.15071E-15 -15.8218 0.99846E+00 -0.0007 97 SO3-2 0.47746E-14 -14.3211 0.30167E-14 -14.5205 0.63183E+00 -0.1994 98 HSO3- 0.26511E-16 -16.5766 0.23249E-16 -16.6336 0.87697E+00 -0.0570 99 HSO4- 0.22303E-11 -11.6516 0.19588E-11 -11.7080 0.87823E+00 -0.0564 Charge balance for all species = 0.8526E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1497106E-09 -.9098063E-02 -.9164605E+01 0.0000 2 H2O 0.1000000E+01 0.5551004E+02 0.9994088E+06 0.0000 3 Cl- 0.1378981E-03 0.1381977E-03 0.4896479E+01 5.9630 4 SO4-- 0.2552882E-04 0.2554723E-04 0.2452583E+01 14.9658 5 HCO3- 0.6602543E-05 0.1309117E-04 0.7982906E+00 4.6435 6 HS- 0.4343106E-12 -.1439127E-08 -.4756523E-04 -2.5387 7 Al+++ 0.9298980E-27 0.7257805E-04 0.1957048E+01 2.1619 8 H4SiO4 0.3829605E-03 0.3959995E-02 0.3803800E+03 -3.4168 9 Ca++ 0.4276658E-07 0.6250165E-07 0.2503385E-02 12.1883 10 Mg++ 0.1789325E-10 0.5678530E-10 0.1379707E-05 8.8089 11 Fe++ 0.1057792E-12 0.2848014E-07 0.1589542E-02 6.5808 12 K+ 0.6808726E-04 0.6830205E-04 0.2669088E+01 5.6569 13 Na+ 0.8647815E-02 0.9015136E-02 0.2071274E+03 7.7603 14 Mn++ 0.1412934E-10 0.8232881E-09 0.4520170E-04 8.7067 15 HPO4-- 0.4496163E-06 0.4554824E-06 0.4368959E-01 13.2117 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1655556E+00 -.9083348E-02 -.1564722E+00 0.0000000E+00 2 H2O 0.5538291E+02 0.5542026E+02 -.3735142E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3026108E-03 0.2550591E-04 0.2771049E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2771064E-03 -.1436799E-08 -.2771049E-03 0.0000000E+00 7 Al+++ 0.3260416E-01 0.7246066E-04 0.3253169E-01 0.0000000E+00 8 H4SiO4 0.1041174E+00 0.3953590E-02 0.1001638E+00 0.0000000E+00 9 Ca++ 0.1151475E-01 0.6240056E-07 0.1151469E-01 0.0000000E+00 10 Mg++ 0.7935714E-02 0.5669346E-10 0.7935714E-02 0.0000000E+00 11 Fe++ 0.7129373E-02 0.2843407E-07 0.7129344E-02 0.0000000E+00 12 K+ 0.2122930E-02 0.6819158E-04 0.2054738E-02 0.0000000E+00 13 Na+ 0.1271125E-01 0.9000555E-02 0.3710697E-02 0.0000000E+00 14 Mn++ 0.1733686E-03 0.8219565E-09 0.1733678E-03 0.0000000E+00 15 HPO4-- 0.5916985E-04 0.4547457E-06 0.5871510E-04 0.0000000E+00 Chg. balance for solid moles: 0.4345E-16 Mass of aqueous solution: 0.999003E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 9.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3711E-02 -2.431 0.9730 -0.012 8.906 0.3735 apatite-OH 0.1957E-04 -4.708 0.9831E-02 -2.007 0.8999E-01 0.3124E-02 clinochlore 0.1587E-02 -2.799 0.8822 -0.054 8.075 0.3356 daphnite 0.9825E-03 -3.008 0.7010 -0.154 6.417 0.2124 chlorite-Mn 0.3467E-04 -4.460 0.2458E-01 -1.609 0.2250 0.7834E-02 hematite 0.8957E-03 -3.048 0.1431 -0.845 1.309 0.2711E-01 lawsonite 0.3689E-04 -4.433 0.1159E-01 -1.936 0.1061 0.3738E-02 microcline 0.2055E-02 -2.687 0.5719 -0.243 5.235 0.2234 prehnite-Fe 0.4253E-03 -3.371 0.1877 -0.727 1.718 0.6296E-01 stilbite 0.1053E-01 -1.978 7.420 0.870 67.92 3.461 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 10.925051 g Volume = 4.710584 cm3 Porosity: 5.7808% V(tot) - V(min): 0.28902E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 9.9990000 g log = 1.0000 Original solution: 1000.0103000 g Original solution / Rock added: 100.01 (Water/Rock Ratio), log = 2.0000 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1662E-06 1.0073 0.1761E-06 0.1748E-06 CH4,gas 0.2005E-15 1.0129 0.2137E-15 0.2109E-15 H2,gas 0.1799E-05 1.0006 0.1893E-05 0.1892E-05 H2S,gas 0.4196E-14 0.9959 0.4396E-14 0.4414E-14 S2,gas 0.1920E-36 1.0000 0.2019E-36 0.2019E-36 CO,gas 0.8209E-16 1.0000 0.8636E-16 0.8636E-16 SO3,gas 0.9880E-40 1.0000 0.1039E-39 0.1039E-39 SO2,gas 0.7076E-23 1.0000 0.7443E-23 0.7443E-23 HCl,gas 0.5028E-17 1.0000 0.5289E-17 0.5289E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 102 lawsonite 9.68 9.68 0.00 0.000 -0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 137 prehnite-Fe 22.59 22.59 0.00 0.000 0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.12 -8.75 -2.918 0.14948E+05 -6.754 3 CH4,gas 4.81 -12.86 -17.67 -4.418 0.30172E+05 -15.670 4 H2,gas 8.29 0.56 -7.72 -4.413 0.13187E+05 -5.723 5 H2S,gas -5.94 -22.30 -16.36 -8.178 0.27929E+05 -14.357 6 S2,gas -7.03 -45.73 -38.69 -5.953 0.66070E+05 -36.695 7 CO,gas 3.51 -14.55 -18.06 -5.558 0.30843E+05 -16.064 8 SO3,gas 17.43 -24.56 -41.98 -10.496 0.71685E+05 -39.983 9 SO2,gas 1.14 -23.99 -25.13 -6.701 0.42906E+05 -23.128 10 HCl,gas 5.48 -13.80 -19.28 -9.638 0.32914E+05 -17.277 11 acmite 7.74 7.23 -0.51 -0.053 0.87419E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.19 -4.36 -0.218 0.74385E+04 20 analcite 3.37 3.09 -0.28 -0.031 0.48177E+03 21 andalusite 5.06 0.91 -4.16 -0.416 0.70953E+04 22 andradite 39.09 38.91 -0.18 -0.009 0.30007E+03 23 grossular 32.83 30.64 -2.19 -0.110 0.37395E+04 26 annite 20.21 17.31 -2.90 -0.161 0.49493E+04 27 phlogopite 27.15 23.99 -3.15 -0.175 0.53815E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.93 -3.92 -1.305 0.66853E+04 36 brucite 12.58 8.81 -3.77 -0.754 0.64333E+04 37 calcite 0.83 -2.93 -3.76 -1.254 0.64240E+04 38 carnegieite-low 9.06 6.51 -2.56 -0.366 0.43698E+04 39 carnegieite-high 10.13 6.51 -3.63 -0.518 0.61967E+04 40 carpholite-Mg 8.65 6.30 -2.35 -0.157 0.40150E+04 41 carpholite-Fe 6.78 4.07 -2.71 -0.181 0.46306E+04 42 celadonite 5.40 2.96 -2.44 -0.144 0.41667E+04 43 celadonite-Fe 3.94 0.73 -3.20 -0.189 0.54720E+04 44 chrysotile 23.94 19.59 -4.34 -0.362 0.74179E+04 50 chloritoid-Mg 13.26 9.72 -3.55 -0.236 0.60537E+04 51 chloritoid-Fe 9.24 7.49 -1.75 -0.117 0.29896E+04 52 chloritoid-Mn 11.46 9.61 -1.85 -0.123 0.31581E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 4.32 -4.11 -0.374 0.70171E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.16 -0.73 -0.122 0.12536E+04 67 diopside 16.22 14.16 -2.05 -0.205 0.35037E+04 68 hedenbergite 14.24 11.94 -2.31 -0.231 0.39425E+04 75 epidote 24.78 24.75 -0.03 -0.001 0.45350E+02 76 clinozoisite 22.92 20.61 -2.31 -0.105 0.39433E+04 77 epidote-Fe 29.94 28.89 -1.05 -0.055 0.17949E+04 78 fayalite 14.08 9.74 -4.33 -0.619 0.74004E+04 79 ferrosilite 11.19 6.33 -4.86 -0.486 0.82978E+04 83 gibbsite 4.10 2.16 -1.94 -0.277 0.33048E+04 84 glaucophane 23.11 18.94 -4.17 -0.113 0.71275E+04 87 greenalite 16.19 12.91 -3.29 -0.274 0.56097E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.09 -1.16 -0.116 0.19848E+04 96 julgoldite 70.57 66.61 -3.96 -0.103 0.67681E+04 97 kalsilite 7.62 4.40 -3.22 -0.460 0.54953E+04 98 kaolinite -1.27 -2.51 -1.24 -0.112 0.21118E+04 99 kyanite 4.93 0.91 -4.02 -0.402 0.68721E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 103 leucite 4.17 0.99 -3.18 -0.318 0.54342E+04 105 lizardite 23.29 19.59 -3.69 -0.308 0.63082E+04 107 magnetite 20.13 19.18 -0.95 -0.078 0.16295E+04 108 minnesotaite 10.46 6.08 -4.39 -0.258 0.74883E+04 110 magnesioferrite 26.26 21.41 -4.85 -0.396 0.82825E+04 113 margarite 17.45 14.00 -3.45 -0.138 0.58902E+04 120 muscovite 2.68 1.89 -0.79 -0.046 0.13442E+04 121 paragonite 4.34 4.00 -0.34 -0.020 0.58264E+03 122 nepheline 8.38 6.51 -1.87 -0.268 0.31977E+04 134 phlogopite-Na 29.73 26.10 -3.63 -0.202 0.62034E+04 136 prehnite 19.47 18.45 -1.02 -0.060 0.17356E+04 138 pumpellyite-Fe 46.47 45.64 -0.83 -0.018 0.14141E+04 139 pumpellyite-Mg 49.19 47.87 -1.32 -0.029 0.22600E+04 145 pyroxmangite 7.42 5.29 -2.13 -0.425 0.36303E+04 146 pyrophyllite -6.10 -9.34 -3.25 -0.203 0.55418E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodonite 7.46 5.29 -2.17 -0.435 0.37096E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.91 -4.41 -0.441 0.75375E+04 164 stilpnomelane-Fe 13.18 12.72 -0.46 -0.014 0.78154E+03 165 stilpnomelane-Mg 27.60 23.86 -3.73 -0.111 0.63764E+04 171 talc 16.55 12.76 -3.79 -0.223 0.64783E+04 174 tephroite 18.11 14.00 -4.12 -0.588 0.70284E+04 177 topaz-H 4.67 0.91 -3.76 -0.342 0.64212E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 8.77 -2.76 -0.551 0.47065E+04 189 wollastonite 10.48 8.77 -1.71 -0.342 0.29204E+04 190 pseudo-wollastonite 11.02 8.77 -2.25 -0.450 0.38390E+04 191 zoisite 22.96 20.61 -2.35 -0.107 0.40158E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.49 -3.93 -0.243 0.67136E+04 195 beidellite-K -1.44 -5.64 -4.20 -0.257 0.71728E+04 196 beidellite-Mg -1.71 -6.05 -4.34 -0.269 0.74143E+04 197 beidellite-Na -1.26 -4.94 -3.68 -0.226 0.62916E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -5.14 -2.93 -0.181 0.49944E+04 202 montmorillonite-K -2.16 -5.28 -3.12 -0.191 0.53314E+04 203 montmorillonite-Mg -2.40 -5.70 -3.30 -0.204 0.56262E+04 204 montmorillonite-Na -1.96 -4.59 -2.63 -0.161 0.44882E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.77 -1.82 -0.122 0.31153E+04 207 nontronite-K 3.40 2.64 -0.77 -0.049 0.13076E+04 208 nontronite-Mg 3.14 2.22 -0.91 -0.059 0.15616E+04 209 nontronite-Na 3.58 3.33 -0.25 -0.016 0.42807E+03 224 tobermorite 9.84 6.74 -3.10 -0.847 0.52983E+04 233 boehmite 4.43 2.16 -2.27 -0.378 0.38721E+04 235 ferrous-oxide 9.82 6.58 -3.24 -0.811 0.55380E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 1.67 -0.41 -0.031 0.69361E+03 243 an25ab75 2.71 2.17 -0.54 -0.041 0.91492E+03 244 an30ab70 3.34 2.67 -0.67 -0.052 0.11446E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 9.9990000 g New total amount of reactant added: 10.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8634E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 10.3990000 Water: Moles liquid = 0.5542E+02 kg liquid = 0.9983E+00 Moles total = 0.5538E+02 kg total = 0.9977E+00 Activity = 1.0000 Stoichiometric ionic strength = .4995999E-02 Osmotic coef. = 0.9625 True ionic strength = .8748534E-02 Chg. balance for total moles = 0.8634E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14971E-09 -9.8247 0.13169E-09 -9.8804 0.87964E+00 -0.0557 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12094E-03 -3.9174 0.87697E+00 -0.0570 4 SO4-- 0.25530E-04 -4.5930 0.16031E-04 -4.7950 0.62793E+00 -0.2021 5 HCO3- 0.66028E-05 -5.1803 0.57947E-05 -5.2370 0.87761E+00 -0.0567 6 HS- 0.43433E-12 -12.3622 0.38092E-12 -12.4192 0.87703E+00 -0.0570 7 Al+++ 0.92990E-27 -27.0316 0.33155E-27 -27.4795 0.35654E+00 -0.4479 8 H4SiO4 0.38296E-03 -3.4168 0.38296E-03 -3.4168 0.10000E+01 0.0000 9 Ca++ 0.42767E-07 -7.3689 0.26756E-07 -7.5726 0.62563E+00 -0.2037 10 Mg++ 0.17893E-10 -10.7473 0.11169E-10 -10.9520 0.62419E+00 -0.2047 11 Fe++ 0.10578E-12 -12.9756 0.66062E-13 -13.1800 0.62453E+00 -0.2044 12 K+ 0.68087E-04 -4.1669 0.59762E-04 -4.2236 0.87772E+00 -0.0566 13 Na+ 0.86478E-02 -2.0631 0.75832E-02 -2.1201 0.87690E+00 -0.0571 14 Mn++ 0.14129E-10 -10.8499 0.88279E-11 -11.0541 0.62479E+00 -0.2043 15 HPO4-- 0.44962E-06 -6.3472 0.28235E-06 -6.5492 0.62798E+00 -0.2021 16 HSiO3- 0.32353E-02 -2.4901 0.28373E-02 -2.5471 0.87697E+00 -0.0570 17 Ca(HSiO3)+ 0.19376E-08 -8.7127 0.17009E-08 -8.7693 0.87781E+00 -0.0566 18 Mg(HSiO3)+ 0.10066E-11 -11.9971 0.88360E-12 -12.0537 0.87781E+00 -0.0566 19 NaHSiO3,aq 0.34172E-03 -3.4663 0.34172E-03 -3.4663 0.10000E+01 0.0000 20 AlO+ 0.28115E-14 -14.5511 0.24680E-14 -14.6077 0.87781E+00 -0.0566 22 HAlO2,aq 0.37502E-08 -8.4259 0.37502E-08 -8.4259 0.10000E+01 0.0000 23 AlO2- 0.72574E-04 -4.1392 0.63587E-04 -4.1966 0.87617E+00 -0.0574 24 CH4,aq 0.13532E-18 -18.8686 0.13511E-18 -18.8693 0.99846E+00 -0.0007 29 CO,aq 0.54693E-19 -19.2621 0.54693E-19 -19.2621 0.10000E+01 0.0000 30 CO2,aq 0.15410E-08 -8.8122 0.15386E-08 -8.8129 0.99846E+00 -0.0007 31 CO3-2 0.64860E-05 -5.1880 0.40684E-05 -5.3906 0.62726E+00 -0.2026 32 CaCO3,aq 0.13332E-08 -8.8751 0.13332E-08 -8.8751 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44504E-11 -11.3516 0.39066E-11 -11.4082 0.87781E+00 -0.0566 34 CaCl+ 0.58739E-11 -11.2311 0.51562E-11 -11.2877 0.87781E+00 -0.0566 35 CaCl2,aq 0.14519E-15 -15.8381 0.14519E-15 -15.8381 0.10000E+01 0.0000 36 CaOH+ 0.16320E-07 -7.7873 0.14326E-07 -7.8439 0.87781E+00 -0.0566 37 CaSO4,aq 0.13364E-09 -9.8741 0.13364E-09 -9.8741 0.10000E+01 0.0000 38 HCl,aq 0.29957E-14 -14.5235 0.29957E-14 -14.5235 0.10000E+01 0.0000 43 FeCl+ 0.14176E-16 -16.8485 0.12444E-16 -16.9051 0.87781E+00 -0.0566 46 FeO,aq 0.15063E-09 -9.8221 0.15063E-09 -9.8221 0.10000E+01 0.0000 47 FeOH+ 0.18946E-10 -10.7225 0.16631E-10 -10.7791 0.87781E+00 -0.0566 48 HFeO2- 0.14029E-07 -7.8530 0.12303E-07 -7.9100 0.87697E+00 -0.0570 49 FeO+ 0.12410E-14 -14.9062 0.10894E-14 -14.9628 0.87781E+00 -0.0566 51 FeO2- 0.14078E-07 -7.8515 0.12346E-07 -7.9085 0.87697E+00 -0.0570 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.13823E-08 -8.8594 0.13802E-08 -8.8601 0.99846E+00 -0.0007 54 KCl,aq 0.12797E-09 -9.8929 0.12797E-09 -9.8929 0.10000E+01 0.0000 55 KHSO4,aq 0.33761E-18 -18.4716 0.33761E-18 -18.4716 0.10000E+01 0.0000 56 KOH,aq 0.19783E-06 -6.7037 0.19783E-06 -6.7037 0.10000E+01 0.0000 57 KSO4- 0.16831E-07 -7.7739 0.14760E-07 -7.8309 0.87697E+00 -0.0570 58 MgCO3,aq 0.13906E-12 -12.8568 0.13906E-12 -12.8568 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18944E-14 -14.7225 0.16629E-14 -14.7791 0.87781E+00 -0.0566 60 MgCl+ 0.22259E-14 -14.6525 0.19539E-14 -14.7091 0.87781E+00 -0.0566 61 MgOH+ 0.37742E-10 -10.4232 0.33131E-10 -10.4798 0.87781E+00 -0.0566 63 MnO,aq 0.53735E-09 -9.2697 0.53735E-09 -9.2697 0.10000E+01 0.0000 64 MnOH+ 0.23519E-09 -9.6286 0.20645E-09 -9.6852 0.87781E+00 -0.0566 65 MnO2-2 0.17083E-11 -11.7674 0.10716E-11 -11.9700 0.62726E+00 -0.2026 66 HMnO2- 0.34863E-10 -10.4576 0.30574E-10 -10.5146 0.87697E+00 -0.0570 69 MnCl+ 0.73609E-14 -14.1331 0.64615E-14 -14.1897 0.87781E+00 -0.0566 70 MnSO4,aq 0.40107E-13 -13.3968 0.40107E-13 -13.3968 0.10000E+01 0.0000 71 NaCl,aq 0.29945E-06 -6.5237 0.29945E-06 -6.5237 0.10000E+01 0.0000 72 NaOH,aq 0.25303E-04 -4.5968 0.25303E-04 -4.5968 0.10000E+01 0.0000 74 OH- 0.51986E-02 -2.2841 0.45549E-02 -2.3415 0.87617E+00 -0.0574 79 HPO3-2 0.19623E-17 -17.7072 0.12309E-17 -17.9098 0.62726E+00 -0.2026 82 H3PO4,aq 0.31524E-16 -16.5014 0.31524E-16 -16.5014 0.10000E+01 0.0000 83 H2PO4- 0.74299E-09 -9.1290 0.65189E-09 -9.1858 0.87738E+00 -0.0568 84 PO4-3 0.51232E-08 -8.2905 0.18724E-08 -8.7276 0.36548E+00 -0.4371 87 H2P2O7-2 0.53024E-19 -19.2755 0.33259E-19 -19.4781 0.62726E+00 -0.2026 88 HP2O7-3 0.14519E-15 -15.8381 0.51788E-16 -16.2858 0.35668E+00 -0.4477 89 P2O7-4 0.59018E-15 -15.2290 0.97014E-16 -16.0132 0.16438E+00 -0.7842 90 H2S,aq 0.15095E-15 -15.8212 0.15072E-15 -15.8218 0.99846E+00 -0.0007 97 SO3-2 0.47748E-14 -14.3210 0.30169E-14 -14.5204 0.63183E+00 -0.1994 98 HSO3- 0.26512E-16 -16.5766 0.23250E-16 -16.6336 0.87697E+00 -0.0570 99 HSO4- 0.22304E-11 -11.6516 0.19588E-11 -11.7080 0.87823E+00 -0.0564 Charge balance for all species = 0.8530E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1497107E-09 -.9098060E-02 -.9164601E+01 0.0000 2 H2O 0.1000000E+01 0.5551004E+02 0.9994088E+06 0.0000 3 Cl- 0.1379037E-03 0.1382033E-03 0.4896677E+01 5.9630 4 SO4-- 0.2552985E-04 0.2554826E-04 0.2452682E+01 14.9658 5 HCO3- 0.6602811E-05 0.1309170E-04 0.7983228E+00 4.6435 6 HS- 0.4343286E-12 -.1439126E-08 -.4756520E-04 -2.5387 7 Al+++ 0.9298997E-27 0.7257802E-04 0.1957047E+01 2.1619 8 H4SiO4 0.3829605E-03 0.3959993E-02 0.3803799E+03 -3.4168 9 Ca++ 0.4276662E-07 0.6250177E-07 0.2503390E-02 12.1883 10 Mg++ 0.1789327E-10 0.5678535E-10 0.1379708E-05 8.8089 11 Fe++ 0.1057793E-12 0.2848012E-07 0.1589541E-02 6.5808 12 K+ 0.6808729E-04 0.6830209E-04 0.2669089E+01 5.6569 13 Na+ 0.8647819E-02 0.9015141E-02 0.2071275E+03 7.7603 14 Mn++ 0.1412935E-10 0.8232883E-09 0.4520172E-04 8.7067 15 HPO4-- 0.4496159E-06 0.4554820E-06 0.4368955E-01 13.2117 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1721790E+00 -.9082977E-02 -.1630960E+00 0.0000000E+00 2 H2O 0.5537789E+02 0.5541802E+02 -.4012714E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3136962E-03 0.2550591E-04 0.2881903E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2881917E-03 -.1436740E-08 -.2881903E-03 0.0000000E+00 7 Al+++ 0.3390845E-01 0.7245770E-04 0.3383599E-01 0.0000000E+00 8 H4SiO4 0.1082825E+00 0.3953429E-02 0.1043291E+00 0.0000000E+00 9 Ca++ 0.1197480E-01 0.6239816E-07 0.1197474E-01 0.0000000E+00 10 Mg++ 0.8253175E-02 0.5669121E-10 0.8253175E-02 0.0000000E+00 11 Fe++ 0.7414576E-02 0.2843291E-07 0.7414548E-02 0.0000000E+00 12 K+ 0.2207856E-02 0.6818886E-04 0.2139667E-02 0.0000000E+00 13 Na+ 0.1321335E-01 0.9000196E-02 0.4213153E-02 0.0000000E+00 14 Mn++ 0.1803041E-03 0.8219235E-09 0.1803032E-03 0.0000000E+00 15 HPO4-- 0.6153688E-04 0.4547270E-06 0.6108215E-04 0.0000000E+00 Chg. balance for solid moles: -.8565E-17 Mass of aqueous solution: 0.998963E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 10.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4213E-02 -2.375 1.105 0.043 9.723 0.4241 apatite-OH 0.2036E-04 -4.691 0.1023E-01 -1.990 0.9001E-01 0.3250E-02 clinochlore 0.1651E-02 -2.782 0.9175 -0.037 8.075 0.3490 daphnite 0.1022E-02 -2.991 0.7291 -0.137 6.417 0.2209 chlorite-Mn 0.3606E-04 -4.443 0.2557E-01 -1.592 0.2250 0.8147E-02 hematite 0.8728E-03 -3.059 0.1394 -0.856 1.227 0.2642E-01 lawsonite -.3870E-04 1.000 -.1216E-01 1.000 -.1070 -.3921E-02 microcline 0.2140E-02 -2.670 0.5956 -0.225 5.242 0.2326 prehnite-Fe 0.5599E-03 -3.252 0.2471 -0.607 2.174 0.8288E-01 stilbite 0.1079E-01 -1.967 7.605 0.881 66.93 3.547 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 lawsonite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 11.362162 g Volume = 4.890629 cm3 Porosity: 5.2130% V(tot) - V(min): 0.26897E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 10.3990000 g log = 1.0170 Original solution: 1000.0103000 g Original solution / Rock added: 96.16 (Water/Rock Ratio), log = 1.9830 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1662E-06 1.0073 0.1761E-06 0.1748E-06 CH4,gas 0.2005E-15 1.0129 0.2137E-15 0.2109E-15 H2,gas 0.1799E-05 1.0006 0.1893E-05 0.1892E-05 H2S,gas 0.4196E-14 0.9959 0.4396E-14 0.4414E-14 S2,gas 0.1920E-36 1.0000 0.2020E-36 0.2020E-36 CO,gas 0.8210E-16 1.0000 0.8636E-16 0.8636E-16 SO3,gas 0.9881E-40 1.0000 0.1039E-39 0.1039E-39 SO2,gas 0.7076E-23 1.0000 0.7443E-23 0.7443E-23 HCl,gas 0.5028E-17 1.0000 0.5290E-17 0.5290E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.48529E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 137 prehnite-Fe 22.59 22.59 0.00 0.000 -0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.12 -8.75 -2.918 0.14948E+05 -6.754 3 CH4,gas 4.81 -12.86 -17.67 -4.418 0.30172E+05 -15.670 4 H2,gas 8.29 0.56 -7.72 -4.413 0.13187E+05 -5.723 5 H2S,gas -5.94 -22.30 -16.36 -8.178 0.27929E+05 -14.357 6 S2,gas -7.03 -45.73 -38.69 -5.953 0.66070E+05 -36.695 7 CO,gas 3.51 -14.55 -18.06 -5.558 0.30843E+05 -16.064 8 SO3,gas 17.43 -24.56 -41.98 -10.496 0.71685E+05 -39.983 9 SO2,gas 1.14 -23.99 -25.13 -6.701 0.42906E+05 -23.128 10 HCl,gas 5.48 -13.80 -19.28 -9.638 0.32914E+05 -17.277 11 acmite 7.74 7.23 -0.51 -0.053 0.87419E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.19 -4.36 -0.218 0.74385E+04 20 analcite 3.37 3.09 -0.28 -0.031 0.48177E+03 21 andalusite 5.06 0.91 -4.16 -0.416 0.70953E+04 22 andradite 39.09 38.91 -0.18 -0.009 0.30007E+03 23 grossular 32.83 30.64 -2.19 -0.110 0.37395E+04 26 annite 20.21 17.31 -2.90 -0.161 0.49493E+04 27 phlogopite 27.15 23.99 -3.15 -0.175 0.53815E+04 29 anorthite 12.80 9.68 -3.12 -0.240 0.53261E+04 35 aragonite 0.99 -2.93 -3.92 -1.305 0.66853E+04 36 brucite 12.58 8.81 -3.77 -0.754 0.64333E+04 37 calcite 0.83 -2.93 -3.76 -1.254 0.64240E+04 38 carnegieite-low 9.06 6.51 -2.56 -0.366 0.43698E+04 39 carnegieite-high 10.13 6.51 -3.63 -0.518 0.61967E+04 40 carpholite-Mg 8.65 6.30 -2.35 -0.157 0.40150E+04 41 carpholite-Fe 6.78 4.07 -2.71 -0.181 0.46306E+04 42 celadonite 5.40 2.96 -2.44 -0.144 0.41667E+04 43 celadonite-Fe 3.94 0.73 -3.20 -0.189 0.54720E+04 44 chrysotile 23.94 19.59 -4.34 -0.362 0.74179E+04 50 chloritoid-Mg 13.26 9.72 -3.55 -0.236 0.60537E+04 51 chloritoid-Fe 9.24 7.49 -1.75 -0.117 0.29896E+04 52 chloritoid-Mn 11.46 9.61 -1.85 -0.123 0.31581E+04 54 coesite -2.37 -3.42 -1.05 -0.349 0.17886E+04 59 corundum 8.43 4.32 -4.11 -0.374 0.70171E+04 61 cristobalite -2.55 -3.42 -0.87 -0.289 0.14815E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.16 -0.73 -0.122 0.12536E+04 67 diopside 16.22 14.16 -2.05 -0.205 0.35037E+04 68 hedenbergite 14.24 11.94 -2.31 -0.231 0.39425E+04 75 epidote 24.78 24.75 -0.03 -0.001 0.45350E+02 76 clinozoisite 22.92 20.61 -2.31 -0.105 0.39433E+04 77 epidote-Fe 29.94 28.89 -1.05 -0.055 0.17949E+04 78 fayalite 14.08 9.74 -4.33 -0.619 0.74004E+04 79 ferrosilite 11.19 6.33 -4.86 -0.486 0.82978E+04 83 gibbsite 4.10 2.16 -1.94 -0.277 0.33048E+04 84 glaucophane 23.11 18.94 -4.17 -0.113 0.71275E+04 87 greenalite 16.19 12.91 -3.29 -0.274 0.56097E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.09 -1.16 -0.116 0.19848E+04 96 julgoldite 70.57 66.61 -3.96 -0.103 0.67681E+04 97 kalsilite 7.62 4.40 -3.22 -0.460 0.54953E+04 98 kaolinite -1.27 -2.51 -1.24 -0.112 0.21118E+04 99 kyanite 4.93 0.91 -4.02 -0.402 0.68721E+04 101 laumontite 2.97 2.84 -0.13 -0.009 0.22173E+03 102 lawsonite 9.68 9.68 0.00 0.000 0.12132E-10 103 leucite 4.17 0.99 -3.18 -0.318 0.54342E+04 105 lizardite 23.29 19.59 -3.69 -0.308 0.63082E+04 107 magnetite 20.13 19.18 -0.95 -0.078 0.16295E+04 108 minnesotaite 10.46 6.08 -4.39 -0.258 0.74883E+04 110 magnesioferrite 26.26 21.41 -4.85 -0.396 0.82825E+04 113 margarite 17.45 14.00 -3.45 -0.138 0.58902E+04 120 muscovite 2.68 1.89 -0.79 -0.046 0.13442E+04 121 paragonite 4.34 4.00 -0.34 -0.020 0.58264E+03 122 nepheline 8.38 6.51 -1.87 -0.268 0.31977E+04 134 phlogopite-Na 29.73 26.10 -3.63 -0.202 0.62034E+04 136 prehnite 19.47 18.45 -1.02 -0.060 0.17356E+04 138 pumpellyite-Fe 46.47 45.64 -0.83 -0.018 0.14141E+04 139 pumpellyite-Mg 49.19 47.87 -1.32 -0.029 0.22600E+04 145 pyroxmangite 7.42 5.29 -2.13 -0.425 0.36303E+04 146 pyrophyllite -6.10 -9.34 -3.25 -0.203 0.55418E+04 147 quartz -2.98 -3.42 -0.43 -0.145 0.74249E+03 152 rhodonite 7.46 5.29 -2.17 -0.435 0.37096E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.91 -4.41 -0.441 0.75375E+04 164 stilpnomelane-Fe 13.18 12.72 -0.46 -0.014 0.78154E+03 165 stilpnomelane-Mg 27.60 23.86 -3.73 -0.111 0.63764E+04 171 talc 16.55 12.76 -3.79 -0.223 0.64783E+04 174 tephroite 18.11 14.00 -4.12 -0.588 0.70284E+04 177 topaz-H 4.67 0.91 -3.76 -0.342 0.64212E+04 178 tridymite -2.61 -3.42 -0.80 -0.267 0.13698E+04 187 wairakite 4.06 2.84 -1.21 -0.071 0.20726E+04 188 walstromite 11.53 8.77 -2.76 -0.551 0.47065E+04 189 wollastonite 10.48 8.77 -1.71 -0.342 0.29204E+04 190 pseudo-wollastonite 11.02 8.77 -2.25 -0.450 0.38390E+04 191 zoisite 22.96 20.61 -2.35 -0.107 0.40158E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.49 -3.93 -0.243 0.67136E+04 195 beidellite-K -1.44 -5.64 -4.20 -0.257 0.71728E+04 196 beidellite-Mg -1.71 -6.05 -4.34 -0.269 0.74143E+04 197 beidellite-Na -1.26 -4.94 -3.68 -0.226 0.62916E+04 199 chalcedony -2.79 -3.42 -0.62 -0.207 0.10628E+04 201 montmorillonite-Ca -2.21 -5.14 -2.93 -0.181 0.49944E+04 202 montmorillonite-K -2.16 -5.28 -3.12 -0.191 0.53314E+04 203 montmorillonite-Mg -2.40 -5.70 -3.30 -0.204 0.56262E+04 204 montmorillonite-Na -1.96 -4.59 -2.63 -0.161 0.44882E+04 205 nontronite-Ca 3.28 2.78 -0.50 -0.032 0.84925E+03 206 nontronite-H 2.60 0.77 -1.82 -0.122 0.31153E+04 207 nontronite-K 3.40 2.64 -0.77 -0.049 0.13076E+04 208 nontronite-Mg 3.14 2.22 -0.91 -0.059 0.15616E+04 209 nontronite-Na 3.58 3.33 -0.25 -0.016 0.42807E+03 224 tobermorite 9.84 6.74 -3.10 -0.847 0.52983E+04 233 boehmite 4.43 2.16 -2.27 -0.378 0.38721E+04 235 ferrous-oxide 9.82 6.58 -3.24 -0.811 0.55380E+04 240 silica-amorphous -2.08 -3.42 -1.34 -0.446 0.22830E+04 242 an20ab80 2.08 1.67 -0.41 -0.031 0.69361E+03 243 an25ab75 2.71 2.17 -0.54 -0.041 0.91492E+03 244 an30ab70 3.34 2.67 -0.67 -0.052 0.11446E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 10.3990000 Water: Moles liquid = 0.5542E+02 kg liquid = 0.9983E+00 Moles total = 0.5538E+02 kg total = 0.9977E+00 Activity = 1.0000 Stoichiometric ionic strength = .5027982E-02 Osmotic coef. = 0.9624 True ionic strength = .8845894E-02 Chg. balance for total moles = 0.8634E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14928E-09 -9.8260 0.13124E-09 -9.8819 0.87918E+00 -0.0559 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12087E-03 -3.9177 0.87648E+00 -0.0573 4 SO4-- 0.25530E-04 -4.5930 0.15996E-04 -4.7960 0.62657E+00 -0.2030 5 HCO3- 0.65863E-05 -5.1814 0.57771E-05 -5.2383 0.87713E+00 -0.0569 6 HS- 0.49973E-12 -12.3013 0.43804E-12 -12.3585 0.87654E+00 -0.0572 7 Al+++ 0.85654E-27 -27.0673 0.30389E-27 -27.5173 0.35479E+00 -0.4500 8 H4SiO4 0.39107E-03 -3.4077 0.39107E-03 -3.4077 0.10000E+01 0.0000 9 Ca++ 0.42867E-07 -7.3679 0.26760E-07 -7.5725 0.62425E+00 -0.2046 10 Mg++ 0.18137E-10 -10.7414 0.11296E-10 -10.9471 0.62280E+00 -0.2056 11 Fe++ 0.10722E-12 -12.9697 0.66815E-13 -13.1751 0.62315E+00 -0.2054 12 K+ 0.68847E-04 -4.1621 0.60395E-04 -4.2190 0.87724E+00 -0.0569 13 Na+ 0.87444E-02 -2.0583 0.76637E-02 -2.1156 0.87641E+00 -0.0573 14 Mn++ 0.14322E-10 -10.8440 0.89284E-11 -11.0492 0.62341E+00 -0.2052 15 HPO4-- 0.44843E-06 -6.3483 0.28100E-06 -6.5513 0.62662E+00 -0.2030 16 HSiO3- 0.33170E-02 -2.4793 0.29073E-02 -2.5365 0.87648E+00 -0.0573 17 Ca(HSiO3)+ 0.19868E-08 -8.7018 0.17431E-08 -8.7587 0.87733E+00 -0.0568 18 Mg(HSiO3)+ 0.10437E-11 -11.9814 0.91571E-12 -12.0382 0.87733E+00 -0.0568 19 NaHSiO3,aq 0.35387E-03 -3.4512 0.35387E-03 -3.4512 0.10000E+01 0.0000 20 AlO+ 0.25961E-14 -14.5857 0.22777E-14 -14.6425 0.87733E+00 -0.0568 22 HAlO2,aq 0.34729E-08 -8.4593 0.34729E-08 -8.4593 0.10000E+01 0.0000 23 AlO2- 0.67475E-04 -4.1709 0.59086E-04 -4.2285 0.87567E+00 -0.0577 24 CH4,aq 0.15547E-18 -18.8083 0.15523E-18 -18.8090 0.99845E+00 -0.0007 29 CO,aq 0.56351E-19 -19.2491 0.56351E-19 -19.2491 0.10000E+01 0.0000 30 CO2,aq 0.15310E-08 -8.8150 0.15287E-08 -8.8157 0.99845E+00 -0.0007 31 CO3-2 0.65026E-05 -5.1869 0.40699E-05 -5.3904 0.62590E+00 -0.2035 32 CaCO3,aq 0.13339E-08 -8.8749 0.13339E-08 -8.8749 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44399E-11 -11.3526 0.38953E-11 -11.4095 0.87733E+00 -0.0568 34 CaCl+ 0.58746E-11 -11.2310 0.51540E-11 -11.2879 0.87733E+00 -0.0568 35 CaCl2,aq 0.14505E-15 -15.8385 0.14505E-15 -15.8385 0.10000E+01 0.0000 36 CaOH+ 0.16388E-07 -7.7855 0.14377E-07 -7.8423 0.87733E+00 -0.0568 37 CaSO4,aq 0.13337E-09 -9.8749 0.13337E-09 -9.8749 0.10000E+01 0.0000 38 HCl,aq 0.29838E-14 -14.5252 0.29838E-14 -14.5252 0.10000E+01 0.0000 43 FeCl+ 0.14337E-16 -16.8436 0.12578E-16 -16.9004 0.87733E+00 -0.0568 46 FeO,aq 0.15340E-09 -9.8142 0.15340E-09 -9.8142 0.10000E+01 0.0000 47 FeOH+ 0.19238E-10 -10.7158 0.16878E-10 -10.7727 0.87733E+00 -0.0568 48 HFeO2- 0.14343E-07 -7.8433 0.12572E-07 -7.9006 0.87648E+00 -0.0573 49 FeO+ 0.12374E-14 -14.9075 0.10856E-14 -14.9643 0.87733E+00 -0.0568 51 FeO2- 0.14134E-07 -7.8497 0.12388E-07 -7.9070 0.87648E+00 -0.0573 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.14335E-08 -8.8436 0.14313E-08 -8.8443 0.99845E+00 -0.0007 54 KCl,aq 0.12926E-09 -9.8886 0.12926E-09 -9.8886 0.10000E+01 0.0000 55 KHSO4,aq 0.33929E-18 -18.4694 0.33929E-18 -18.4694 0.10000E+01 0.0000 56 KOH,aq 0.20062E-06 -6.6976 0.20062E-06 -6.6976 0.10000E+01 0.0000 57 KSO4- 0.16982E-07 -7.7700 0.14884E-07 -7.8273 0.87648E+00 -0.0573 58 MgCO3,aq 0.14070E-12 -12.8517 0.14070E-12 -12.8517 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19112E-14 -14.7187 0.16767E-14 -14.7755 0.87733E+00 -0.0568 60 MgCl+ 0.22512E-14 -14.6476 0.19751E-14 -14.7044 0.87733E+00 -0.0568 61 MgOH+ 0.38324E-10 -10.4165 0.33623E-10 -10.4734 0.87733E+00 -0.0568 63 MnO,aq 0.54720E-09 -9.2619 0.54720E-09 -9.2619 0.10000E+01 0.0000 64 MnOH+ 0.23881E-09 -9.6219 0.20952E-09 -9.6788 0.87733E+00 -0.0568 65 MnO2-2 0.17554E-11 -11.7556 0.10987E-11 -11.9591 0.62590E+00 -0.2035 66 HMnO2- 0.35644E-10 -10.4480 0.31241E-10 -10.5053 0.87648E+00 -0.0573 69 MnCl+ 0.74445E-14 -14.1282 0.65313E-14 -14.1850 0.87733E+00 -0.0568 70 MnSO4,aq 0.40476E-13 -13.3928 0.40476E-13 -13.3928 0.10000E+01 0.0000 71 NaCl,aq 0.30246E-06 -6.5193 0.30246E-06 -6.5193 0.10000E+01 0.0000 72 NaOH,aq 0.25659E-04 -4.5908 0.25659E-04 -4.5908 0.10000E+01 0.0000 74 OH- 0.52194E-02 -2.2824 0.45705E-02 -2.3400 0.87567E+00 -0.0577 79 HPO3-2 0.20296E-17 -17.6926 0.12703E-17 -17.8961 0.62590E+00 -0.2035 82 H3PO4,aq 0.31159E-16 -16.5064 0.31159E-16 -16.5064 0.10000E+01 0.0000 83 H2PO4- 0.73732E-09 -9.1323 0.64655E-09 -9.1894 0.87690E+00 -0.0571 84 PO4-3 0.51402E-08 -8.2890 0.18698E-08 -8.7282 0.36376E+00 -0.4392 87 H2P2O7-2 0.52272E-19 -19.2817 0.32717E-19 -19.4852 0.62590E+00 -0.2035 88 HP2O7-3 0.14402E-15 -15.8416 0.51117E-16 -16.2914 0.35493E+00 -0.4499 89 P2O7-4 0.58961E-15 -15.2294 0.96087E-16 -16.0173 0.16297E+00 -0.7879 90 H2S,aq 0.17300E-15 -15.7620 0.17273E-15 -15.7626 0.99845E+00 -0.0007 97 SO3-2 0.49511E-14 -14.3053 0.31217E-14 -14.5056 0.63050E+00 -0.2003 98 HSO3- 0.27355E-16 -16.5630 0.23976E-16 -16.6202 0.87648E+00 -0.0573 99 HSO4- 0.22192E-11 -11.6538 0.19479E-11 -11.7104 0.87776E+00 -0.0566 Charge balance for all species = 0.8408E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1492780E-09 -.9192615E-02 -.9259750E+01 0.0000 2 H2O 0.1000000E+01 0.5550996E+02 0.9993967E+06 0.0000 3 Cl- 0.1379016E-03 0.1382042E-03 0.4896659E+01 5.9642 4 SO4-- 0.2552988E-04 0.2554843E-04 0.2452672E+01 14.9679 5 HCO3- 0.6586346E-05 0.1309179E-04 0.7983198E+00 4.6436 6 HS- 0.4997343E-12 -.1433282E-08 -.4737154E-04 -2.4766 7 Al+++ 0.8565419E-27 0.6747800E-04 0.1819507E+01 2.1285 8 H4SiO4 0.3910711E-03 0.4061930E-02 0.3901674E+03 -3.4077 9 Ca++ 0.4286699E-07 0.6271897E-07 0.2512063E-02 12.1913 10 Mg++ 0.1813725E-10 0.5764961E-10 0.1400692E-05 8.8168 11 Fe++ 0.1072211E-12 0.2885330E-07 0.1610352E-02 6.5887 12 K+ 0.6884712E-04 0.6906485E-04 0.2698867E+01 5.6629 13 Na+ 0.8744403E-02 0.9124231E-02 0.2096317E+03 7.7664 14 Mn++ 0.1432188E-10 0.8377812E-09 0.4599694E-04 8.7146 15 HPO4-- 0.4484312E-06 0.4543087E-06 0.4357654E-01 13.2126 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1721790E+00 -.9177313E-02 -.1630016E+00 0.0000000E+00 2 H2O 0.5537789E+02 0.5541756E+02 -.3966727E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3136962E-03 0.2550590E-04 0.2881903E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2881917E-03 -.1430896E-08 -.2881903E-03 0.0000000E+00 7 Al+++ 0.3390845E-01 0.6736568E-04 0.3384109E-01 0.0000000E+00 8 H4SiO4 0.1082825E+00 0.4055169E-02 0.1042274E+00 0.0000000E+00 9 Ca++ 0.1197480E-01 0.6261458E-07 0.1197474E-01 0.0000000E+00 10 Mg++ 0.8253175E-02 0.5755365E-10 0.8253175E-02 0.0000000E+00 11 Fe++ 0.7414576E-02 0.2880528E-07 0.7414548E-02 0.0000000E+00 12 K+ 0.2207856E-02 0.6894989E-04 0.2138906E-02 0.0000000E+00 13 Na+ 0.1321335E-01 0.9109044E-02 0.4104306E-02 0.0000000E+00 14 Mn++ 0.1803041E-03 0.8363866E-09 0.1803032E-03 0.0000000E+00 15 HPO4-- 0.6153688E-04 0.4535525E-06 0.6108333E-04 0.0000000E+00 Chg. balance for solid moles: 0.2830E-16 Mass of aqueous solution: 0.998967E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 10.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4104E-02 -2.387 1.076 0.032 9.475 0.4131 apatite-OH 0.2036E-04 -4.691 0.1023E-01 -1.990 0.9005E-01 0.3250E-02 clinochlore 0.1651E-02 -2.782 0.9175 -0.037 8.078 0.3490 daphnite 0.1022E-02 -2.991 0.7291 -0.137 6.419 0.2209 chlorite-Mn 0.3606E-04 -4.443 0.2557E-01 -1.592 0.2251 0.8147E-02 hematite 0.8919E-03 -3.050 0.1424 -0.846 1.254 0.2700E-01 microcline 0.2139E-02 -2.670 0.5953 -0.225 5.241 0.2326 prehnite-Fe 0.5217E-03 -3.283 0.2302 -0.638 2.027 0.7722E-01 stilbite 0.1083E-01 -1.965 7.632 0.883 67.19 3.560 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 11.358369 g Volume = 4.890845 cm3 Porosity: 5.2088% V(tot) - V(min): 0.26876E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 10.3990000 g log = 1.0170 Original solution: 1000.0103000 g Original solution / Rock added: 96.16 (Water/Rock Ratio), log = 1.9830 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1651E-06 1.0073 0.1750E-06 0.1737E-06 CH4,gas 0.2304E-15 1.0129 0.2455E-15 0.2424E-15 H2,gas 0.1865E-05 1.0006 0.1963E-05 0.1962E-05 H2S,gas 0.4809E-14 0.9959 0.5038E-14 0.5058E-14 S2,gas 0.2345E-36 1.0000 0.2467E-36 0.2467E-36 CO,gas 0.8459E-16 1.0000 0.8898E-16 0.8898E-16 SO3,gas 0.9792E-40 1.0000 0.1030E-39 0.1030E-39 SO2,gas 0.7272E-23 1.0000 0.7650E-23 0.7650E-23 HCl,gas 0.5008E-17 1.0000 0.5268E-17 0.5268E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 137 prehnite-Fe 22.59 22.59 0.00 0.000 0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.12 -8.76 -2.919 0.14952E+05 -6.757 3 CH4,gas 4.81 -12.80 -17.61 -4.402 0.30069E+05 -15.610 4 H2,gas 8.29 0.58 -7.71 -4.404 0.13160E+05 -5.707 5 H2S,gas -5.94 -22.24 -16.30 -8.149 0.27828E+05 -14.298 6 S2,gas -7.03 -45.64 -38.61 -5.940 0.65922E+05 -36.608 7 CO,gas 3.51 -14.54 -18.05 -5.554 0.30821E+05 -16.051 8 SO3,gas 17.43 -24.56 -41.99 -10.497 0.71692E+05 -39.987 9 SO2,gas 1.14 -23.98 -25.12 -6.698 0.42886E+05 -23.116 10 HCl,gas 5.48 -13.80 -19.28 -9.639 0.32917E+05 -17.278 11 acmite 7.74 7.25 -0.49 -0.051 0.83275E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.18 -4.37 -0.219 0.74654E+04 20 analcite 3.37 3.08 -0.29 -0.032 0.49731E+03 21 andalusite 5.06 0.85 -4.21 -0.421 0.71938E+04 22 andradite 39.09 38.95 -0.14 -0.007 0.23790E+03 23 grossular 32.83 30.61 -2.22 -0.111 0.37913E+04 26 annite 20.21 17.33 -2.87 -0.160 0.49089E+04 27 phlogopite 27.15 24.02 -3.13 -0.174 0.53411E+04 29 anorthite 12.80 9.63 -3.16 -0.243 0.54038E+04 35 aragonite 0.99 -2.93 -3.92 -1.305 0.66849E+04 36 brucite 12.58 8.82 -3.76 -0.752 0.64198E+04 37 calcite 0.83 -2.93 -3.76 -1.254 0.64236E+04 38 carnegieite-low 9.06 6.49 -2.58 -0.368 0.44009E+04 39 carnegieite-high 10.13 6.49 -3.65 -0.521 0.62277E+04 40 carpholite-Mg 8.65 6.26 -2.39 -0.159 0.40844E+04 41 carpholite-Fe 6.78 4.03 -2.75 -0.184 0.47001E+04 42 celadonite 5.40 2.98 -2.42 -0.143 0.41377E+04 43 celadonite-Fe 3.94 0.75 -3.19 -0.188 0.54430E+04 44 chrysotile 23.94 19.63 -4.30 -0.359 0.73464E+04 50 chloritoid-Mg 13.26 9.67 -3.60 -0.240 0.61387E+04 51 chloritoid-Fe 9.24 7.44 -1.80 -0.120 0.30746E+04 52 chloritoid-Mn 11.46 9.56 -1.90 -0.127 0.32430E+04 54 coesite -2.37 -3.41 -1.04 -0.346 0.17730E+04 59 corundum 8.43 4.26 -4.18 -0.380 0.71311E+04 61 cristobalite -2.55 -3.41 -0.86 -0.286 0.14659E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.13 -0.77 -0.128 0.13106E+04 67 diopside 16.22 14.19 -2.02 -0.202 0.34539E+04 68 hedenbergite 14.24 11.96 -2.28 -0.228 0.38928E+04 75 epidote 24.78 24.72 -0.06 -0.003 0.10233E+03 76 clinozoisite 22.92 20.54 -2.38 -0.108 0.40573E+04 77 epidote-Fe 29.94 28.89 -1.05 -0.055 0.17949E+04 78 fayalite 14.08 9.77 -4.31 -0.616 0.73579E+04 79 ferrosilite 11.19 6.36 -4.83 -0.483 0.82398E+04 83 gibbsite 4.10 2.13 -1.97 -0.281 0.33618E+04 84 glaucophane 23.11 18.98 -4.13 -0.112 0.70560E+04 87 greenalite 16.19 12.95 -3.24 -0.270 0.55382E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.08 -1.17 -0.117 0.20003E+04 96 julgoldite 70.57 66.69 -3.88 -0.101 0.66272E+04 97 kalsilite 7.62 4.38 -3.24 -0.462 0.55263E+04 98 kaolinite -1.27 -2.56 -1.29 -0.117 0.21947E+04 99 kyanite 4.93 0.85 -4.08 -0.408 0.69705E+04 101 laumontite 2.97 2.82 -0.16 -0.010 0.26836E+03 102 lawsonite 9.68 9.63 -0.05 -0.003 0.77705E+02 103 leucite 4.17 0.98 -3.19 -0.319 0.54497E+04 105 lizardite 23.29 19.63 -3.65 -0.304 0.62367E+04 107 magnetite 20.13 19.19 -0.95 -0.077 0.16160E+04 108 minnesotaite 10.46 6.14 -4.33 -0.254 0.73857E+04 110 magnesioferrite 26.26 21.41 -4.84 -0.395 0.82691E+04 113 margarite 17.45 13.89 -3.56 -0.142 0.60819E+04 120 muscovite 2.68 1.83 -0.85 -0.050 0.14581E+04 121 paragonite 4.34 3.93 -0.41 -0.024 0.69661E+03 122 nepheline 8.38 6.49 -1.89 -0.270 0.32288E+04 134 phlogopite-Na 29.73 26.12 -3.61 -0.201 0.61630E+04 136 prehnite 19.47 18.42 -1.05 -0.062 0.17926E+04 138 pumpellyite-Fe 46.47 45.55 -0.92 -0.020 0.15716E+04 139 pumpellyite-Mg 49.19 47.78 -1.42 -0.031 0.24175E+04 145 pyroxmangite 7.42 5.31 -2.11 -0.422 0.36013E+04 146 pyrophyllite -6.10 -9.37 -3.28 -0.205 0.55936E+04 147 quartz -2.98 -3.41 -0.43 -0.142 0.72695E+03 152 rhodonite 7.46 5.31 -2.16 -0.431 0.36805E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.85 -4.47 -0.447 0.76359E+04 164 stilpnomelane-Fe 13.18 12.77 -0.41 -0.012 0.69866E+03 165 stilpnomelane-Mg 27.60 23.91 -3.69 -0.110 0.62935E+04 171 talc 16.55 12.82 -3.73 -0.220 0.63757E+04 174 tephroite 18.11 14.02 -4.09 -0.584 0.69859E+04 177 topaz-H 4.67 0.85 -3.82 -0.347 0.65196E+04 178 tridymite -2.61 -3.41 -0.79 -0.264 0.13542E+04 187 wairakite 4.06 2.82 -1.24 -0.073 0.21192E+04 188 walstromite 11.53 8.78 -2.74 -0.549 0.46858E+04 189 wollastonite 10.48 8.78 -1.70 -0.340 0.28997E+04 190 pseudo-wollastonite 11.02 8.78 -2.24 -0.447 0.38183E+04 191 zoisite 22.96 20.54 -2.42 -0.110 0.41298E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.54 -3.98 -0.246 0.67885E+04 195 beidellite-K -1.44 -5.68 -4.24 -0.260 0.72452E+04 196 beidellite-Mg -1.71 -6.09 -4.39 -0.271 0.74879E+04 197 beidellite-Na -1.26 -4.98 -3.73 -0.228 0.63639E+04 199 chalcedony -2.79 -3.41 -0.61 -0.204 0.10473E+04 201 montmorillonite-Ca -2.21 -5.16 -2.94 -0.182 0.50221E+04 202 montmorillonite-K -2.16 -5.30 -3.14 -0.192 0.53565E+04 203 montmorillonite-Mg -2.40 -5.71 -3.31 -0.205 0.56525E+04 204 montmorillonite-Na -1.96 -4.60 -2.64 -0.162 0.45134E+04 205 nontronite-Ca 3.28 2.81 -0.47 -0.031 0.81016E+03 206 nontronite-H 2.60 0.79 -1.80 -0.121 0.30771E+04 207 nontronite-K 3.40 2.66 -0.74 -0.048 0.12660E+04 208 nontronite-Mg 3.14 2.25 -0.89 -0.058 0.15212E+04 209 nontronite-Na 3.58 3.36 -0.23 -0.015 0.38642E+03 224 tobermorite 9.84 6.75 -3.09 -0.843 0.52784E+04 233 boehmite 4.43 2.13 -2.30 -0.384 0.39291E+04 235 ferrous-oxide 9.82 6.59 -3.24 -0.809 0.55245E+04 240 silica-amorphous -2.08 -3.41 -1.33 -0.443 0.22675E+04 242 an20ab80 2.08 1.66 -0.42 -0.032 0.70915E+03 243 an25ab75 2.71 2.16 -0.55 -0.042 0.93435E+03 244 an30ab70 3.34 2.66 -0.68 -0.053 0.11679E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 10.3990000 g New total amount of reactant added: 10.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8635E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 10.7990000 Water: Moles liquid = 0.5541E+02 kg liquid = 0.9983E+00 Moles total = 0.5537E+02 kg total = 0.9976E+00 Activity = 1.0000 Stoichiometric ionic strength = .5096795E-02 Osmotic coef. = 0.9621 True ionic strength = .9037515E-02 Chg. balance for total moles = 0.8635E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14849E-09 -9.8283 0.13041E-09 -9.8847 0.87828E+00 -0.0564 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12074E-03 -3.9182 0.87553E+00 -0.0577 4 SO4-- 0.25531E-04 -4.5929 0.15930E-04 -4.7978 0.62394E+00 -0.2049 5 HCO3- 0.65556E-05 -5.1834 0.57440E-05 -5.2408 0.87619E+00 -0.0574 6 HS- 0.65383E-12 -12.1845 0.57249E-12 -12.2422 0.87560E+00 -0.0577 7 Al+++ 0.73246E-27 -27.1352 0.25738E-27 -27.5894 0.35140E+00 -0.4542 8 H4SiO4 0.40708E-03 -3.3903 0.40708E-03 -3.3903 0.10000E+01 0.0000 9 Ca++ 0.43082E-07 -7.3657 0.26779E-07 -7.5722 0.62158E+00 -0.2065 10 Mg++ 0.18623E-10 -10.7299 0.11549E-10 -10.9375 0.62011E+00 -0.2075 11 Fe++ 0.11009E-12 -12.9582 0.68309E-13 -13.1655 0.62046E+00 -0.2073 12 K+ 0.70343E-04 -4.1528 0.61642E-04 -4.2101 0.87631E+00 -0.0573 13 Na+ 0.89345E-02 -2.0489 0.78218E-02 -2.1067 0.87546E+00 -0.0578 14 Mn++ 0.14705E-10 -10.8325 0.91281E-11 -11.0396 0.62073E+00 -0.2071 15 HPO4-- 0.44601E-06 -6.3507 0.27830E-06 -6.5555 0.62398E+00 -0.2048 16 HSiO3- 0.34785E-02 -2.4586 0.30455E-02 -2.5163 0.87553E+00 -0.0577 17 Ca(HSiO3)+ 0.20850E-08 -8.6809 0.18273E-08 -8.7382 0.87640E+00 -0.0573 18 Mg(HSiO3)+ 0.11190E-11 -11.9512 0.98070E-12 -12.0085 0.87640E+00 -0.0573 19 NaHSiO3,aq 0.37834E-03 -3.4221 0.37834E-03 -3.4221 0.10000E+01 0.0000 20 AlO+ 0.22292E-14 -14.6519 0.19537E-14 -14.7092 0.87640E+00 -0.0573 22 HAlO2,aq 0.29977E-08 -8.5232 0.29977E-08 -8.5232 0.10000E+01 0.0000 23 AlO2- 0.58677E-04 -4.2315 0.51326E-04 -4.2897 0.87471E+00 -0.0581 24 CH4,aq 0.20288E-18 -18.6928 0.20256E-18 -18.6934 0.99843E+00 -0.0007 29 CO,aq 0.59685E-19 -19.2241 0.59685E-19 -19.2241 0.10000E+01 0.0000 30 CO2,aq 0.15127E-08 -8.8202 0.15103E-08 -8.8209 0.99843E+00 -0.0007 31 CO3-2 0.65340E-05 -5.1848 0.40723E-05 -5.3902 0.62325E+00 -0.2053 32 CaCO3,aq 0.13356E-08 -8.8743 0.13356E-08 -8.8743 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44224E-11 -11.3543 0.38758E-11 -11.4116 0.87640E+00 -0.0573 34 CaCl+ 0.58788E-11 -11.2307 0.51522E-11 -11.2880 0.87640E+00 -0.0573 35 CaCl2,aq 0.14484E-15 -15.8391 0.14484E-15 -15.8391 0.10000E+01 0.0000 36 CaOH+ 0.16521E-07 -7.7820 0.14479E-07 -7.8393 0.87640E+00 -0.0573 37 CaSO4,aq 0.13291E-09 -9.8764 0.13291E-09 -9.8764 0.10000E+01 0.0000 38 HCl,aq 0.29618E-14 -14.5284 0.29618E-14 -14.5284 0.10000E+01 0.0000 43 FeCl+ 0.14657E-16 -16.8339 0.12846E-16 -16.8912 0.87640E+00 -0.0573 46 FeO,aq 0.15882E-09 -9.7991 0.15882E-09 -9.7991 0.10000E+01 0.0000 47 FeOH+ 0.19814E-10 -10.7030 0.17365E-10 -10.7603 0.87640E+00 -0.0573 48 HFeO2- 0.14961E-07 -7.8250 0.13099E-07 -7.8828 0.87553E+00 -0.0577 49 FeO+ 0.12309E-14 -14.9098 0.10788E-14 -14.9671 0.87640E+00 -0.0573 51 FeO2- 0.14239E-07 -7.8465 0.12467E-07 -7.9043 0.87553E+00 -0.0577 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.15368E-08 -8.8134 0.15343E-08 -8.8141 0.99843E+00 -0.0007 54 KCl,aq 0.13178E-09 -9.8801 0.13178E-09 -9.8801 0.10000E+01 0.0000 55 KHSO4,aq 0.34268E-18 -18.4651 0.34268E-18 -18.4651 0.10000E+01 0.0000 56 KOH,aq 0.20606E-06 -6.6860 0.20606E-06 -6.6860 0.10000E+01 0.0000 57 KSO4- 0.17279E-07 -7.7625 0.15128E-07 -7.8202 0.87553E+00 -0.0577 58 MgCO3,aq 0.14393E-12 -12.8418 0.14393E-12 -12.8418 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19448E-14 -14.7111 0.17044E-14 -14.7684 0.87640E+00 -0.0573 60 MgCl+ 0.23016E-14 -14.6380 0.20171E-14 -14.6953 0.87640E+00 -0.0573 61 MgOH+ 0.39472E-10 -10.4037 0.34593E-10 -10.4610 0.87640E+00 -0.0573 63 MnO,aq 0.56656E-09 -9.2468 0.56656E-09 -9.2468 0.10000E+01 0.0000 64 MnOH+ 0.24596E-09 -9.6091 0.21556E-09 -9.6664 0.87640E+00 -0.0573 65 MnO2-2 0.18484E-11 -11.7332 0.11520E-11 -11.9385 0.62325E+00 -0.2053 66 HMnO2- 0.37180E-10 -10.4297 0.32552E-10 -10.4874 0.87553E+00 -0.0577 69 MnCl+ 0.76110E-14 -14.1186 0.66703E-14 -14.1759 0.87640E+00 -0.0573 70 MnSO4,aq 0.41209E-13 -13.3850 0.41209E-13 -13.3850 0.10000E+01 0.0000 71 NaCl,aq 0.30837E-06 -6.5109 0.30837E-06 -6.5109 0.10000E+01 0.0000 72 NaOH,aq 0.26354E-04 -4.5792 0.26354E-04 -4.5792 0.10000E+01 0.0000 74 OH- 0.52583E-02 -2.2792 0.45995E-02 -2.3373 0.87471E+00 -0.0581 79 HPO3-2 0.21640E-17 -17.6647 0.13487E-17 -17.8701 0.62325E+00 -0.2053 82 H3PO4,aq 0.30473E-16 -16.5161 0.30473E-16 -16.5161 0.10000E+01 0.0000 83 H2PO4- 0.72642E-09 -9.1388 0.63631E-09 -9.1963 0.87596E+00 -0.0575 84 PO4-3 0.51703E-08 -8.2865 0.18636E-08 -8.7296 0.36045E+00 -0.4432 87 H2P2O7-2 0.50845E-19 -19.2938 0.31689E-19 -19.4991 0.62325E+00 -0.2053 88 HP2O7-3 0.14173E-15 -15.8485 0.49825E-16 -16.3026 0.35154E+00 -0.4540 89 P2O7-4 0.58816E-15 -15.2305 0.94252E-16 -16.0257 0.16025E+00 -0.7952 90 H2S,aq 0.22468E-15 -15.6484 0.22432E-15 -15.6491 0.99843E+00 -0.0007 97 SO3-2 0.53074E-14 -14.2751 0.33326E-14 -14.4772 0.62792E+00 -0.2021 98 HSO3- 0.29050E-16 -16.5368 0.25435E-16 -16.5946 0.87553E+00 -0.0577 99 HSO4- 0.21984E-11 -11.6579 0.19276E-11 -11.7150 0.87684E+00 -0.0571 Charge balance for all species = 0.8067E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1484887E-09 -.9382989E-02 -.9451315E+01 0.0000 2 H2O 0.1000000E+01 0.5550980E+02 0.9993728E+06 0.0000 3 Cl- 0.1379032E-03 0.1382117E-03 0.4896819E+01 5.9665 4 SO4-- 0.2553095E-04 0.2554979E-04 0.2452751E+01 14.9716 5 HCO3- 0.6555638E-05 0.1309250E-04 0.7983459E+00 4.6439 6 HS- 0.6538309E-12 -.1420442E-08 -.4694619E-04 -2.3576 7 Al+++ 0.7324642E-27 0.5868027E-04 0.1582248E+01 2.0646 8 H4SiO4 0.4070815E-03 0.4263880E-02 0.4095569E+03 -3.3903 9 Ca++ 0.4308223E-07 0.6316714E-07 0.2529960E-02 12.1971 10 Mg++ 0.1862340E-10 0.5936218E-10 0.1442271E-05 8.8319 11 Fe++ 0.1100939E-12 0.2958233E-07 0.1651006E-02 6.6038 12 K+ 0.7034254E-04 0.7056601E-04 0.2757471E+01 5.6745 13 Na+ 0.8934498E-02 0.9339500E-02 0.2145731E+03 7.7780 14 Mn++ 0.1470550E-10 0.8663102E-09 0.4756228E-04 8.7297 15 HPO4-- 0.4460052E-06 0.4519019E-06 0.4334478E-01 13.2139 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1788024E+00 -.9366867E-02 -.1694355E+00 0.0000000E+00 2 H2O 0.5537288E+02 0.5541442E+02 -.4153757E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3247816E-03 0.2550589E-04 0.2992757E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2992771E-03 -.1418001E-08 -.2992757E-03 0.0000000E+00 7 Al+++ 0.3521275E-01 0.5857944E-04 0.3515417E-01 0.0000000E+00 8 H4SiO4 0.1124476E+00 0.4256553E-02 0.1081911E+00 0.0000000E+00 9 Ca++ 0.1243486E-01 0.6305860E-07 0.1243480E-01 0.0000000E+00 10 Mg++ 0.8570635E-02 0.5926018E-10 0.8570635E-02 0.0000000E+00 11 Fe++ 0.7699780E-02 0.2953151E-07 0.7699750E-02 0.0000000E+00 12 K+ 0.2292781E-02 0.7044476E-04 0.2222337E-02 0.0000000E+00 13 Na+ 0.1371545E-01 0.9323453E-02 0.4391994E-02 0.0000000E+00 14 Mn++ 0.1872395E-03 0.8648217E-09 0.1872386E-03 0.0000000E+00 15 HPO4-- 0.6390391E-04 0.4511254E-06 0.6345278E-04 0.0000000E+00 Chg. balance for solid moles: 0.2125E-16 Mass of aqueous solution: 0.998934E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 10.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4392E-02 -2.357 1.152 0.061 9.770 0.4421 apatite-OH 0.2115E-04 -4.675 0.1062E-01 -1.974 0.9013E-01 0.3376E-02 clinochlore 0.1714E-02 -2.766 0.9528 -0.021 8.083 0.3624 daphnite 0.1061E-02 -2.974 0.7571 -0.121 6.423 0.2294 chlorite-Mn 0.3745E-04 -4.427 0.2655E-01 -1.576 0.2252 0.8461E-02 hematite 0.9065E-03 -3.043 0.1448 -0.839 1.228 0.2744E-01 microcline 0.2222E-02 -2.653 0.6186 -0.209 5.247 0.2416 prehnite-Fe 0.5812E-03 -3.236 0.2565 -0.591 2.176 0.8603E-01 stilbite 0.1117E-01 -1.952 7.869 0.896 66.76 3.670 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 11.787853 g Volume = 5.071270 cm3 Porosity: 4.6682% V(tot) - V(min): 0.24833E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 10.7990000 g log = 1.0334 Original solution: 1000.0103000 g Original solution / Rock added: 92.60 (Water/Rock Ratio), log = 1.9666 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1632E-06 1.0073 0.1729E-06 0.1716E-06 CH4,gas 0.3006E-15 1.0129 0.3203E-15 0.3162E-15 H2,gas 0.1999E-05 1.0006 0.2104E-05 0.2103E-05 H2S,gas 0.6245E-14 0.9959 0.6543E-14 0.6569E-14 S2,gas 0.3441E-36 1.0000 0.3620E-36 0.3620E-36 CO,gas 0.8959E-16 1.0000 0.9424E-16 0.9424E-16 SO3,gas 0.9629E-40 1.0000 0.1013E-39 0.1013E-39 SO2,gas 0.7666E-23 1.0000 0.8064E-23 0.8064E-23 HCl,gas 0.4971E-17 1.0000 0.5230E-17 0.5230E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 137 prehnite-Fe 22.59 22.59 0.00 0.000 -0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.13 -8.76 -2.921 0.14961E+05 -6.762 3 CH4,gas 4.81 -12.69 -17.49 -4.374 0.29871E+05 -15.494 4 H2,gas 8.29 0.61 -7.68 -4.387 0.13108E+05 -5.677 5 H2S,gas -5.94 -22.13 -16.18 -8.092 0.27634E+05 -14.184 6 S2,gas -7.03 -45.47 -38.44 -5.914 0.65637E+05 -36.441 7 CO,gas 3.51 -14.52 -18.03 -5.546 0.30778E+05 -16.026 8 SO3,gas 17.43 -24.57 -41.99 -10.499 0.71704E+05 -39.994 9 SO2,gas 1.14 -23.96 -25.09 -6.692 0.42846E+05 -23.093 10 HCl,gas 5.48 -13.80 -19.28 -9.641 0.32923E+05 -17.282 11 acmite 7.74 7.30 -0.44 -0.046 0.75340E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.15 -4.40 -0.220 0.75170E+04 20 analcite 3.37 3.06 -0.31 -0.034 0.52706E+03 21 andalusite 5.06 0.74 -4.32 -0.432 0.73822E+04 22 andradite 39.09 39.02 -0.07 -0.004 0.11889E+03 23 grossular 32.83 30.55 -2.28 -0.114 0.38904E+04 26 annite 20.21 17.38 -2.83 -0.157 0.48315E+04 27 phlogopite 27.15 24.06 -3.08 -0.171 0.52637E+04 29 anorthite 12.80 9.55 -3.25 -0.250 0.55526E+04 35 aragonite 0.99 -2.93 -3.91 -1.305 0.66840E+04 36 brucite 12.58 8.83 -3.74 -0.749 0.63940E+04 37 calcite 0.83 -2.93 -3.76 -1.254 0.64226E+04 38 carnegieite-low 9.06 6.45 -2.61 -0.373 0.44604E+04 39 carnegieite-high 10.13 6.45 -3.68 -0.526 0.62873E+04 40 carpholite-Mg 8.65 6.18 -2.47 -0.165 0.42173E+04 41 carpholite-Fe 6.78 3.95 -2.83 -0.189 0.48330E+04 42 celadonite 5.40 3.01 -2.39 -0.141 0.40821E+04 43 celadonite-Fe 3.94 0.78 -3.16 -0.186 0.53875E+04 44 chrysotile 23.94 19.72 -4.22 -0.352 0.72095E+04 50 chloritoid-Mg 13.26 9.57 -3.69 -0.246 0.63013E+04 51 chloritoid-Fe 9.24 7.34 -1.90 -0.126 0.32373E+04 52 chloritoid-Mn 11.46 9.47 -1.99 -0.133 0.34057E+04 54 coesite -2.37 -3.39 -1.02 -0.340 0.17433E+04 59 corundum 8.43 4.13 -4.30 -0.391 0.73493E+04 61 cristobalite -2.55 -3.39 -0.84 -0.280 0.14362E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.06 -0.83 -0.139 0.14197E+04 67 diopside 16.22 14.25 -1.97 -0.197 0.33587E+04 68 hedenbergite 14.24 12.02 -2.22 -0.222 0.37975E+04 75 epidote 24.78 24.65 -0.12 -0.006 0.21143E+03 76 clinozoisite 22.92 20.42 -2.50 -0.114 0.42755E+04 77 epidote-Fe 29.94 28.89 -1.05 -0.055 0.17949E+04 78 fayalite 14.08 9.82 -4.26 -0.609 0.72766E+04 79 ferrosilite 11.19 6.43 -4.76 -0.476 0.81287E+04 83 gibbsite 4.10 2.06 -2.03 -0.290 0.34709E+04 84 glaucophane 23.11 19.06 -4.05 -0.110 0.69191E+04 87 greenalite 16.19 13.03 -3.16 -0.264 0.54013E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.06 -1.19 -0.119 0.20301E+04 96 julgoldite 70.57 66.85 -3.72 -0.097 0.63574E+04 97 kalsilite 7.62 4.35 -3.27 -0.467 0.55858E+04 98 kaolinite -1.27 -2.65 -1.38 -0.125 0.23534E+04 99 kyanite 4.93 0.74 -4.19 -0.419 0.71590E+04 101 laumontite 2.97 2.77 -0.21 -0.014 0.35762E+03 102 lawsonite 9.68 9.55 -0.13 -0.009 0.22647E+03 103 leucite 4.17 0.96 -3.21 -0.321 0.54795E+04 105 lizardite 23.29 19.72 -3.57 -0.298 0.60998E+04 107 magnetite 20.13 19.20 -0.93 -0.076 0.15902E+04 108 minnesotaite 10.46 6.25 -4.21 -0.248 0.71893E+04 110 magnesioferrite 26.26 21.43 -4.83 -0.394 0.82433E+04 113 margarite 17.45 13.67 -3.78 -0.151 0.64489E+04 120 muscovite 2.68 1.70 -0.98 -0.058 0.16763E+04 121 paragonite 4.34 3.80 -0.54 -0.032 0.91480E+03 122 nepheline 8.38 6.45 -1.93 -0.275 0.32883E+04 134 phlogopite-Na 29.73 26.17 -3.56 -0.198 0.60856E+04 136 prehnite 19.47 18.35 -1.11 -0.066 0.19017E+04 138 pumpellyite-Fe 46.47 45.37 -1.10 -0.024 0.18731E+04 139 pumpellyite-Mg 49.19 47.60 -1.59 -0.035 0.27190E+04 145 pyroxmangite 7.42 5.34 -2.08 -0.415 0.35458E+04 146 pyrophyllite -6.10 -9.43 -3.33 -0.208 0.56928E+04 147 quartz -2.98 -3.39 -0.41 -0.136 0.69720E+03 152 rhodonite 7.46 5.34 -2.12 -0.425 0.36250E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.74 -4.58 -0.458 0.78244E+04 164 stilpnomelane-Fe 13.18 12.86 -0.32 -0.009 0.53997E+03 165 stilpnomelane-Mg 27.60 24.00 -3.59 -0.107 0.61348E+04 171 talc 16.55 12.93 -3.62 -0.213 0.61793E+04 174 tephroite 18.11 14.07 -4.04 -0.578 0.69046E+04 177 topaz-H 4.67 0.74 -3.93 -0.357 0.67081E+04 178 tridymite -2.61 -3.39 -0.78 -0.259 0.13245E+04 187 wairakite 4.06 2.77 -1.29 -0.076 0.22084E+04 188 walstromite 11.53 8.81 -2.72 -0.544 0.46461E+04 189 wollastonite 10.48 8.81 -1.67 -0.335 0.28600E+04 190 pseudo-wollastonite 11.02 8.81 -2.21 -0.443 0.37786E+04 191 zoisite 22.96 20.42 -2.55 -0.116 0.43480E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.62 -4.06 -0.251 0.69319E+04 195 beidellite-K -1.44 -5.76 -4.32 -0.265 0.73836E+04 196 beidellite-Mg -1.71 -6.17 -4.47 -0.276 0.76286E+04 197 beidellite-Na -1.26 -5.07 -3.81 -0.233 0.65023E+04 199 chalcedony -2.79 -3.39 -0.60 -0.199 0.10175E+04 201 montmorillonite-Ca -2.21 -5.19 -2.97 -0.184 0.50751E+04 202 montmorillonite-K -2.16 -5.33 -3.17 -0.194 0.54046E+04 203 montmorillonite-Mg -2.40 -5.74 -3.34 -0.207 0.57029E+04 204 montmorillonite-Na -1.96 -4.63 -2.67 -0.164 0.45615E+04 205 nontronite-Ca 3.28 2.85 -0.43 -0.028 0.73533E+03 206 nontronite-H 2.60 0.84 -1.76 -0.118 0.30039E+04 207 nontronite-K 3.40 2.71 -0.69 -0.045 0.11863E+04 208 nontronite-Mg 3.14 2.29 -0.85 -0.055 0.14437E+04 209 nontronite-Na 3.58 3.40 -0.18 -0.012 0.30668E+03 224 tobermorite 9.84 6.77 -3.07 -0.837 0.52404E+04 233 boehmite 4.43 2.06 -2.36 -0.394 0.40382E+04 235 ferrous-oxide 9.82 6.60 -3.22 -0.805 0.54987E+04 240 silica-amorphous -2.08 -3.39 -1.31 -0.437 0.22377E+04 242 an20ab80 2.08 1.65 -0.43 -0.033 0.73891E+03 243 an25ab75 2.71 2.14 -0.57 -0.044 0.97154E+03 244 an30ab70 3.34 2.63 -0.71 -0.055 0.12125E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 10.7990000 g New total amount of reactant added: 11.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8633E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 11.1990000 Water: Moles liquid = 0.5541E+02 kg liquid = 0.9982E+00 Moles total = 0.5537E+02 kg total = 0.9975E+00 Activity = 1.0000 Stoichiometric ionic strength = .5172786E-02 Osmotic coef. = 0.9619 True ionic strength = .9230565E-02 Chg. balance for total moles = 0.8633E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14777E-09 -9.8304 0.12965E-09 -9.8872 0.87738E+00 -0.0568 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13790E-03 -3.8604 0.12061E-03 -3.9186 0.87459E+00 -0.0582 4 SO4-- 0.25532E-04 -4.5929 0.15864E-04 -4.7996 0.62133E+00 -0.2067 5 HCO3- 0.65264E-05 -5.1853 0.57124E-05 -5.2432 0.87526E+00 -0.0579 6 HS- 0.84932E-12 -12.0709 0.74287E-12 -12.1291 0.87466E+00 -0.0582 7 Al+++ 0.62970E-27 -27.2009 0.21917E-27 -27.6592 0.34805E+00 -0.4584 8 H4SiO4 0.42328E-03 -3.3734 0.42328E-03 -3.3734 0.10000E+01 0.0000 9 Ca++ 0.43320E-07 -7.3633 0.26813E-07 -7.5717 0.61894E+00 -0.2084 10 Mg++ 0.19121E-10 -10.7185 0.11806E-10 -10.9279 0.61745E+00 -0.2094 11 Fe++ 0.11303E-12 -12.9468 0.69833E-13 -13.1559 0.61781E+00 -0.2091 12 K+ 0.71849E-04 -4.1436 0.62895E-04 -4.2014 0.87538E+00 -0.0578 13 Na+ 0.91260E-02 -2.0397 0.79809E-02 -2.0980 0.87452E+00 -0.0582 14 Mn++ 0.15098E-10 -10.8211 0.93317E-11 -11.0300 0.61808E+00 -0.2090 15 HPO4-- 0.44346E-06 -6.3531 0.27555E-06 -6.5598 0.62137E+00 -0.2066 16 HSiO3- 0.36421E-02 -2.4386 0.31854E-02 -2.4968 0.87459E+00 -0.0582 17 Ca(HSiO3)+ 0.21858E-08 -8.6604 0.19136E-08 -8.7182 0.87548E+00 -0.0578 18 Mg(HSiO3)+ 0.11978E-11 -11.9216 0.10486E-11 -11.9794 0.87548E+00 -0.0578 19 NaHSiO3,aq 0.40376E-03 -3.3939 0.40376E-03 -3.3939 0.10000E+01 0.0000 20 AlO+ 0.19227E-14 -14.7161 0.16833E-14 -14.7738 0.87548E+00 -0.0578 22 HAlO2,aq 0.25981E-08 -8.5853 0.25981E-08 -8.5853 0.10000E+01 0.0000 23 AlO2- 0.51211E-04 -4.2906 0.44746E-04 -4.3492 0.87376E+00 -0.0586 24 CH4,aq 0.26290E-18 -18.5802 0.26248E-18 -18.5809 0.99841E+00 -0.0007 29 CO,aq 0.63137E-19 -19.1997 0.63137E-19 -19.1997 0.10000E+01 0.0000 30 CO2,aq 0.14956E-08 -8.8252 0.14932E-08 -8.8259 0.99841E+00 -0.0007 31 CO3-2 0.65639E-05 -5.1828 0.40738E-05 -5.3900 0.62063E+00 -0.2072 32 CaCO3,aq 0.13378E-08 -8.8736 0.13378E-08 -8.8736 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44082E-11 -11.3557 0.38592E-11 -11.4135 0.87548E+00 -0.0578 34 CaCl+ 0.58861E-11 -11.2302 0.51531E-11 -11.2879 0.87548E+00 -0.0578 35 CaCl2,aq 0.14471E-15 -15.8395 0.14471E-15 -15.8395 0.10000E+01 0.0000 36 CaOH+ 0.16657E-07 -7.7784 0.14583E-07 -7.8362 0.87548E+00 -0.0578 37 CaSO4,aq 0.13253E-09 -9.8777 0.13253E-09 -9.8777 0.10000E+01 0.0000 38 HCl,aq 0.29413E-14 -14.5315 0.29413E-14 -14.5315 0.10000E+01 0.0000 43 FeCl+ 0.14984E-16 -16.8244 0.13118E-16 -16.8821 0.87548E+00 -0.0578 46 FeO,aq 0.16429E-09 -9.7844 0.16429E-09 -9.7844 0.10000E+01 0.0000 47 FeOH+ 0.20397E-10 -10.6904 0.17857E-10 -10.7482 0.87548E+00 -0.0578 48 HFeO2- 0.15584E-07 -7.8073 0.13630E-07 -7.8655 0.87459E+00 -0.0582 49 FeO+ 0.12250E-14 -14.9119 0.10725E-14 -14.9696 0.87548E+00 -0.0578 51 FeO2- 0.14338E-07 -7.8435 0.12540E-07 -7.9017 0.87459E+00 -0.0582 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.16443E-08 -8.7840 0.16417E-08 -8.7847 0.99841E+00 -0.0007 54 KCl,aq 0.13432E-09 -9.8719 0.13432E-09 -9.8719 0.10000E+01 0.0000 55 KHSO4,aq 0.34616E-18 -18.4607 0.34616E-18 -18.4607 0.10000E+01 0.0000 56 KOH,aq 0.21149E-06 -6.6747 0.21149E-06 -6.6747 0.10000E+01 0.0000 57 KSO4- 0.17576E-07 -7.7551 0.15372E-07 -7.8133 0.87459E+00 -0.0582 58 MgCO3,aq 0.14719E-12 -12.8321 0.14719E-12 -12.8321 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19793E-14 -14.7035 0.17328E-14 -14.7612 0.87548E+00 -0.0578 60 MgCl+ 0.23529E-14 -14.6284 0.20599E-14 -14.6862 0.87548E+00 -0.0578 61 MgOH+ 0.40633E-10 -10.3911 0.35573E-10 -10.4489 0.87548E+00 -0.0578 63 MnO,aq 0.58605E-09 -9.2321 0.58605E-09 -9.2321 0.10000E+01 0.0000 64 MnOH+ 0.25320E-09 -9.5965 0.22167E-09 -9.6543 0.87548E+00 -0.0578 65 MnO2-2 0.19428E-11 -11.7116 0.12058E-11 -11.9187 0.62063E+00 -0.2072 66 HMnO2- 0.38727E-10 -10.4120 0.33870E-10 -10.4702 0.87459E+00 -0.0582 69 MnCl+ 0.77807E-14 -14.1090 0.68118E-14 -14.1667 0.87548E+00 -0.0578 70 MnSO4,aq 0.41954E-13 -13.3772 0.41954E-13 -13.3772 0.10000E+01 0.0000 71 NaCl,aq 0.31431E-06 -6.5026 0.31431E-06 -6.5026 0.10000E+01 0.0000 72 NaOH,aq 0.27049E-04 -4.5679 0.27049E-04 -4.5679 0.10000E+01 0.0000 74 OH- 0.52951E-02 -2.2761 0.46266E-02 -2.3347 0.87376E+00 -0.0586 79 HPO3-2 0.23023E-17 -17.6378 0.14289E-17 -17.8450 0.62063E+00 -0.2072 82 H3PO4,aq 0.29819E-16 -16.5255 0.29819E-16 -16.5255 0.10000E+01 0.0000 83 H2PO4- 0.71579E-09 -9.1452 0.62634E-09 -9.2032 0.87503E+00 -0.0580 84 PO4-3 0.51965E-08 -8.2843 0.18561E-08 -8.7314 0.35719E+00 -0.4471 87 H2P2O7-2 0.49471E-19 -19.3056 0.30703E-19 -19.5128 0.62063E+00 -0.2072 88 HP2O7-3 0.13946E-15 -15.8555 0.48560E-16 -16.3137 0.34820E+00 -0.4582 89 P2O7-4 0.58633E-15 -15.2319 0.92401E-16 -16.0343 0.15759E+00 -0.8025 90 H2S,aq 0.28984E-15 -15.5378 0.28938E-15 -15.5385 0.99841E+00 -0.0007 97 SO3-2 0.56783E-14 -14.2458 0.35511E-14 -14.4496 0.62537E+00 -0.2039 98 HSO3- 0.30806E-16 -16.5114 0.26943E-16 -16.5696 0.87459E+00 -0.0582 99 HSO4- 0.21787E-11 -11.6618 0.19084E-11 -11.7193 0.87592E+00 -0.0575 Charge balance for all species = 0.8159E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1477682E-09 -.9579734E-02 -.9649287E+01 0.0000 2 H2O 0.1000000E+01 0.5550963E+02 0.9993484E+06 0.0000 3 Cl- 0.1379047E-03 0.1382191E-03 0.4896978E+01 5.9686 4 SO4-- 0.2553203E-04 0.2555115E-04 0.2452830E+01 14.9749 5 HCO3- 0.6526442E-05 0.1309320E-04 0.7983719E+00 4.6440 6 HS- 0.8493208E-12 -.1405777E-08 -.4646050E-04 -2.2419 7 Al+++ 0.6297020E-27 0.5121330E-04 0.1380880E+01 2.0025 8 H4SiO4 0.4232802E-03 0.4469164E-02 0.4292659E+03 -3.3734 9 Ca++ 0.4332002E-07 0.6364319E-07 0.2548972E-02 12.2028 10 Mg++ 0.1912081E-10 0.6110286E-10 0.1484531E-05 8.8466 11 Fe++ 0.1130332E-12 0.3031042E-07 0.1691605E-02 6.6185 12 K+ 0.7184909E-04 0.7207828E-04 0.2816505E+01 5.6858 13 Na+ 0.9126011E-02 0.9557137E-02 0.2195685E+03 7.7893 14 Mn++ 0.1509800E-10 0.8950688E-09 0.4914014E-04 8.7444 15 HPO4-- 0.4434589E-06 0.4493712E-06 0.4310112E-01 13.2147 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1854258E+00 -.9562758E-02 -.1758630E+00 0.0000000E+00 2 H2O 0.5536787E+02 0.5541127E+02 -.4340000E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3358669E-03 0.2550587E-04 0.3103611E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3103625E-03 -.1403286E-08 -.3103611E-03 0.0000000E+00 7 Al+++ 0.3651705E-01 0.5112255E-04 0.3646592E-01 0.0000000E+00 8 H4SiO4 0.1166128E+00 0.4461245E-02 0.1121515E+00 0.0000000E+00 9 Ca++ 0.1289492E-01 0.6353041E-07 0.1289486E-01 0.0000000E+00 10 Mg++ 0.8888095E-02 0.6099458E-10 0.8888095E-02 0.0000000E+00 11 Fe++ 0.7984983E-02 0.3025671E-07 0.7984953E-02 0.0000000E+00 12 K+ 0.2377707E-02 0.7195056E-04 0.2305756E-02 0.0000000E+00 13 Na+ 0.1421754E-01 0.9540202E-02 0.4677342E-02 0.0000000E+00 14 Mn++ 0.1941749E-03 0.8934827E-09 0.1941740E-03 0.0000000E+00 15 HPO4-- 0.6627094E-04 0.4485749E-06 0.6582237E-04 0.0000000E+00 Chg. balance for solid moles: 0.1011E-16 Mass of aqueous solution: 0.998901E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 11.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4677E-02 -2.330 1.226 0.089 10.04 0.4708 apatite-OH 0.2194E-04 -4.659 0.1102E-01 -1.958 0.9021E-01 0.3502E-02 clinochlore 0.1778E-02 -2.750 0.9881 -0.005 8.087 0.3758 daphnite 0.1100E-02 -2.958 0.7852 -0.105 6.427 0.2379 chlorite-Mn 0.3883E-04 -4.411 0.2753E-01 -1.560 0.2254 0.8774E-02 hematite 0.9212E-03 -3.036 0.1471 -0.832 1.204 0.2789E-01 microcline 0.2306E-02 -2.637 0.6418 -0.193 5.253 0.2507 prehnite-Fe 0.6404E-03 -3.194 0.2826 -0.549 2.313 0.9479E-01 stilbite 0.1150E-01 -1.939 8.107 0.909 66.36 3.781 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 12.217077 g Volume = 5.251636 cm3 Porosity: 4.1602% V(tot) - V(min): 0.22796E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 11.1990000 g log = 1.0492 Original solution: 1000.0103000 g Original solution / Rock added: 89.29 (Water/Rock Ratio), log = 1.9508 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1613E-06 1.0073 0.1709E-06 0.1697E-06 CH4,gas 0.3896E-15 1.0129 0.4151E-15 0.4098E-15 H2,gas 0.2139E-05 1.0006 0.2252E-05 0.2250E-05 H2S,gas 0.8056E-14 0.9959 0.8440E-14 0.8474E-14 S2,gas 0.5002E-36 1.0000 0.5262E-36 0.5262E-36 CO,gas 0.9477E-16 1.0000 0.9969E-16 0.9969E-16 SO3,gas 0.9477E-40 1.0000 0.9969E-40 0.9969E-40 SO2,gas 0.8073E-23 1.0000 0.8492E-23 0.8492E-23 HCl,gas 0.4937E-17 1.0000 0.5193E-17 0.5193E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 137 prehnite-Fe 22.59 22.59 0.00 0.000 0.36397E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 22 andradite 39.09 39.09 0.00 0.000 0.31465E+01 23 grossular 32.83 30.49 -2.33 -0.117 0.39869E+04 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.13 -8.77 -2.922 0.14970E+05 -6.767 3 CH4,gas 4.81 -12.57 -17.38 -4.345 0.29679E+05 -15.382 4 H2,gas 8.29 0.64 -7.65 -4.370 0.13058E+05 -5.647 5 H2S,gas -5.94 -22.02 -16.07 -8.037 0.27445E+05 -14.074 6 S2,gas -7.03 -45.31 -38.28 -5.889 0.65360E+05 -36.279 7 CO,gas 3.51 -14.49 -18.00 -5.539 0.30737E+05 -16.001 8 SO3,gas 17.43 -24.57 -42.00 -10.500 0.71716E+05 -40.001 9 SO2,gas 1.14 -23.93 -25.07 -6.686 0.42808E+05 -23.071 10 HCl,gas 5.48 -13.81 -19.28 -9.642 0.32928E+05 -17.285 11 acmite 7.74 7.34 -0.40 -0.041 0.67624E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.12 -4.43 -0.222 0.75672E+04 20 analcite 3.37 3.05 -0.33 -0.036 0.55600E+03 21 andalusite 5.06 0.63 -4.43 -0.443 0.75655E+04 26 annite 20.21 17.42 -2.79 -0.155 0.47563E+04 27 phlogopite 27.15 24.11 -3.04 -0.169 0.51885E+04 29 anorthite 12.80 9.46 -3.34 -0.257 0.56973E+04 35 aragonite 0.99 -2.93 -3.91 -1.305 0.66828E+04 36 brucite 12.58 8.85 -3.73 -0.746 0.63689E+04 37 calcite 0.83 -2.93 -3.76 -1.254 0.64214E+04 38 carnegieite-low 9.06 6.42 -2.65 -0.378 0.45183E+04 39 carnegieite-high 10.13 6.42 -3.72 -0.531 0.63451E+04 40 carpholite-Mg 8.65 6.10 -2.55 -0.170 0.43465E+04 41 carpholite-Fe 6.78 3.88 -2.91 -0.194 0.49622E+04 42 celadonite 5.40 3.04 -2.36 -0.139 0.40281E+04 43 celadonite-Fe 3.94 0.81 -3.12 -0.184 0.53334E+04 44 chrysotile 23.94 19.79 -4.14 -0.345 0.70764E+04 50 chloritoid-Mg 13.26 9.48 -3.78 -0.252 0.64595E+04 51 chloritoid-Fe 9.24 7.25 -1.99 -0.133 0.33954E+04 52 chloritoid-Mn 11.46 9.38 -2.09 -0.139 0.35639E+04 54 coesite -2.37 -3.37 -1.00 -0.335 0.17143E+04 59 corundum 8.43 4.00 -4.43 -0.403 0.75615E+04 61 cristobalite -2.55 -3.37 -0.82 -0.275 0.14072E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.00 -0.89 -0.149 0.15258E+04 67 diopside 16.22 14.30 -1.91 -0.191 0.32661E+04 68 hedenbergite 14.24 12.07 -2.17 -0.217 0.37049E+04 75 epidote 24.78 24.59 -0.19 -0.009 0.31753E+03 76 clinozoisite 22.92 20.29 -2.63 -0.119 0.44877E+04 77 epidote-Fe 29.94 28.89 -1.05 -0.055 0.17949E+04 78 fayalite 14.08 9.86 -4.22 -0.602 0.71975E+04 79 ferrosilite 11.19 6.49 -4.70 -0.470 0.80207E+04 83 gibbsite 4.10 2.00 -2.09 -0.299 0.35770E+04 84 glaucophane 23.11 19.14 -3.97 -0.107 0.67860E+04 85 glaucophane-Fe 17.42 12.45 -4.97 -0.134 0.84778E+04 87 greenalite 16.19 13.11 -3.09 -0.257 0.52682E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.05 -1.21 -0.121 0.20590E+04 96 julgoldite 70.57 67.00 -3.57 -0.093 0.60950E+04 97 kalsilite 7.62 4.31 -3.31 -0.472 0.56437E+04 98 kaolinite -1.27 -2.74 -1.47 -0.134 0.25077E+04 99 kyanite 4.93 0.63 -4.30 -0.430 0.73422E+04 101 laumontite 2.97 2.71 -0.26 -0.017 0.44443E+03 102 lawsonite 9.68 9.46 -0.22 -0.014 0.37115E+03 103 leucite 4.17 0.94 -3.23 -0.323 0.55084E+04 105 lizardite 23.29 19.79 -3.49 -0.291 0.59667E+04 107 magnetite 20.13 19.22 -0.92 -0.075 0.15652E+04 108 minnesotaite 10.46 6.36 -4.10 -0.241 0.69983E+04 110 magnesioferrite 26.26 21.44 -4.81 -0.393 0.82182E+04 113 margarite 17.45 13.47 -3.99 -0.159 0.68057E+04 120 muscovite 2.68 1.57 -1.11 -0.065 0.18885E+04 121 paragonite 4.34 3.68 -0.66 -0.039 0.11270E+04 122 nepheline 8.38 6.42 -1.96 -0.280 0.33462E+04 134 phlogopite-Na 29.73 26.21 -3.52 -0.196 0.60104E+04 136 prehnite 19.47 18.29 -1.18 -0.069 0.20078E+04 138 pumpellyite-Fe 46.47 45.20 -1.27 -0.028 0.21663E+04 139 pumpellyite-Mg 49.19 47.43 -1.76 -0.039 0.30122E+04 145 pyroxmangite 7.42 5.37 -2.04 -0.409 0.34918E+04 146 pyrophyllite -6.10 -9.49 -3.39 -0.212 0.57892E+04 147 quartz -2.98 -3.37 -0.39 -0.130 0.66826E+03 152 rhodonite 7.46 5.37 -2.09 -0.418 0.35710E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.63 -4.69 -0.469 0.80076E+04 164 stilpnomelane-Fe 13.18 12.95 -0.23 -0.007 0.38565E+03 165 stilpnomelane-Mg 27.60 24.09 -3.50 -0.105 0.59805E+04 171 talc 16.55 13.05 -3.51 -0.206 0.59884E+04 174 tephroite 18.11 14.12 -4.00 -0.571 0.68255E+04 177 topaz-H 4.67 0.63 -4.04 -0.367 0.68913E+04 178 tridymite -2.61 -3.37 -0.76 -0.253 0.12956E+04 187 wairakite 4.06 2.71 -1.34 -0.079 0.22952E+04 188 walstromite 11.53 8.83 -2.70 -0.540 0.46075E+04 189 wollastonite 10.48 8.83 -1.65 -0.330 0.28214E+04 190 pseudo-wollastonite 11.02 8.83 -2.19 -0.438 0.37400E+04 191 zoisite 22.96 20.29 -2.67 -0.121 0.45602E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.70 -4.14 -0.256 0.70713E+04 195 beidellite-K -1.44 -5.84 -4.40 -0.270 0.75183E+04 196 beidellite-Mg -1.71 -6.25 -4.55 -0.281 0.77655E+04 197 beidellite-Na -1.26 -5.14 -3.89 -0.238 0.66370E+04 199 chalcedony -2.79 -3.37 -0.58 -0.193 0.98857E+03 201 montmorillonite-Ca -2.21 -5.22 -3.00 -0.186 0.51267E+04 202 montmorillonite-K -2.16 -5.35 -3.19 -0.196 0.54514E+04 203 montmorillonite-Mg -2.40 -5.77 -3.37 -0.208 0.57519E+04 204 montmorillonite-Na -1.96 -4.66 -2.70 -0.165 0.46083E+04 205 nontronite-Ca 3.28 2.89 -0.39 -0.025 0.66256E+03 206 nontronite-H 2.60 0.88 -1.72 -0.115 0.29327E+04 207 nontronite-K 3.40 2.75 -0.65 -0.042 0.11087E+04 208 nontronite-Mg 3.14 2.34 -0.80 -0.052 0.13684E+04 209 nontronite-Na 3.58 3.45 -0.13 -0.009 0.22914E+03 224 tobermorite 9.84 6.79 -3.05 -0.831 0.52034E+04 233 boehmite 4.43 2.00 -2.43 -0.405 0.41443E+04 235 ferrous-oxide 9.82 6.62 -3.21 -0.801 0.54736E+04 240 silica-amorphous -2.08 -3.37 -1.29 -0.431 0.22088E+04 242 an20ab80 2.08 1.63 -0.45 -0.035 0.76784E+03 243 an25ab75 2.71 2.12 -0.59 -0.045 0.10077E+04 244 an30ab70 3.34 2.61 -0.74 -0.057 0.12559E+04 245 tr.625ac.25prg.125 45.31 40.33 -4.98 -0.134 0.85026E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 11.1990000 Water: Moles liquid = 0.5541E+02 kg liquid = 0.9982E+00 Moles total = 0.5537E+02 kg total = 0.9975E+00 Activity = 1.0000 Stoichiometric ionic strength = .5101556E-02 Osmotic coef. = 0.9621 True ionic strength = .9050081E-02 Chg. balance for total moles = 0.8633E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14844E-09 -9.8284 0.13036E-09 -9.8848 0.87822E+00 -0.0564 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13791E-03 -3.8604 0.12074E-03 -3.9182 0.87547E+00 -0.0578 4 SO4-- 0.25532E-04 -4.5929 0.15926E-04 -4.7979 0.62377E+00 -0.2050 5 HCO3- 0.65539E-05 -5.1835 0.57421E-05 -5.2409 0.87613E+00 -0.0574 6 HS- 0.66526E-12 -12.1770 0.58246E-12 -12.2347 0.87554E+00 -0.0577 7 Al+++ 0.72516E-27 -27.1396 0.25466E-27 -27.5940 0.35118E+00 -0.4545 8 H4SiO4 0.40813E-03 -3.3892 0.40813E-03 -3.3892 0.10000E+01 0.0000 9 Ca++ 0.43097E-07 -7.3656 0.26781E-07 -7.5722 0.62141E+00 -0.2066 10 Mg++ 0.18656E-10 -10.7292 0.11565E-10 -10.9368 0.61994E+00 -0.2077 11 Fe++ 0.11028E-12 -12.9575 0.68408E-13 -13.1649 0.62029E+00 -0.2074 12 K+ 0.70441E-04 -4.1522 0.61723E-04 -4.2096 0.87624E+00 -0.0574 13 Na+ 0.89470E-02 -2.0483 0.78322E-02 -2.1061 0.87540E+00 -0.0578 14 Mn++ 0.14731E-10 -10.8318 0.91413E-11 -11.0390 0.62056E+00 -0.2072 15 HPO4-- 0.44584E-06 -6.3508 0.27812E-06 -6.5558 0.62381E+00 -0.2049 16 HSiO3- 0.34891E-02 -2.4573 0.30546E-02 -2.5150 0.87547E+00 -0.0578 17 Ca(HSiO3)+ 0.20915E-08 -8.6795 0.18329E-08 -8.7369 0.87634E+00 -0.0573 18 Mg(HSiO3)+ 0.11240E-11 -11.9492 0.98505E-12 -12.0065 0.87634E+00 -0.0573 19 NaHSiO3,aq 0.37997E-03 -3.4203 0.37997E-03 -3.4203 0.10000E+01 0.0000 20 AlO+ 0.22075E-14 -14.6561 0.19345E-14 -14.7134 0.87634E+00 -0.0573 22 HAlO2,aq 0.29695E-08 -8.5273 0.29695E-08 -8.5273 0.10000E+01 0.0000 23 AlO2- 0.58152E-04 -4.2354 0.50863E-04 -4.2936 0.87465E+00 -0.0582 24 CH4,aq 0.20639E-18 -18.6853 0.20607E-18 -18.6860 0.99843E+00 -0.0007 29 CO,aq 0.59909E-19 -19.2225 0.59909E-19 -19.2225 0.10000E+01 0.0000 30 CO2,aq 0.15116E-08 -8.8206 0.15092E-08 -8.8212 0.99843E+00 -0.0007 31 CO3-2 0.65363E-05 -5.1847 0.40726E-05 -5.3901 0.62308E+00 -0.2055 32 CaCO3,aq 0.13358E-08 -8.8743 0.13358E-08 -8.8743 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44216E-11 -11.3544 0.38748E-11 -11.4118 0.87634E+00 -0.0573 34 CaCl+ 0.58794E-11 -11.2307 0.51524E-11 -11.2880 0.87634E+00 -0.0573 35 CaCl2,aq 0.14484E-15 -15.8391 0.14484E-15 -15.8391 0.10000E+01 0.0000 36 CaOH+ 0.16530E-07 -7.7817 0.14486E-07 -7.8391 0.87634E+00 -0.0573 37 CaSO4,aq 0.13289E-09 -9.8765 0.13289E-09 -9.8765 0.10000E+01 0.0000 38 HCl,aq 0.29605E-14 -14.5286 0.29605E-14 -14.5286 0.10000E+01 0.0000 43 FeCl+ 0.14679E-16 -16.8333 0.12864E-16 -16.8906 0.87634E+00 -0.0573 46 FeO,aq 0.15918E-09 -9.7981 0.15918E-09 -9.7981 0.10000E+01 0.0000 47 FeOH+ 0.19852E-10 -10.7022 0.17397E-10 -10.7595 0.87634E+00 -0.0573 48 HFeO2- 0.15002E-07 -7.8239 0.13134E-07 -7.8816 0.87547E+00 -0.0578 49 FeO+ 0.12305E-14 -14.9099 0.10784E-14 -14.9672 0.87634E+00 -0.0573 51 FeO2- 0.14245E-07 -7.8463 0.12472E-07 -7.9041 0.87547E+00 -0.0578 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.15437E-08 -8.8115 0.15412E-08 -8.8121 0.99843E+00 -0.0007 54 KCl,aq 0.13195E-09 -9.8796 0.13195E-09 -9.8796 0.10000E+01 0.0000 55 KHSO4,aq 0.34292E-18 -18.4648 0.34292E-18 -18.4648 0.10000E+01 0.0000 56 KOH,aq 0.20641E-06 -6.6853 0.20641E-06 -6.6853 0.10000E+01 0.0000 57 KSO4- 0.17299E-07 -7.7620 0.15145E-07 -7.8197 0.87547E+00 -0.0578 58 MgCO3,aq 0.14415E-12 -12.8412 0.14415E-12 -12.8412 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19471E-14 -14.7106 0.17063E-14 -14.7679 0.87634E+00 -0.0573 60 MgCl+ 0.23050E-14 -14.6373 0.20199E-14 -14.6947 0.87634E+00 -0.0573 61 MgOH+ 0.39547E-10 -10.4029 0.34657E-10 -10.4602 0.87634E+00 -0.0573 63 MnO,aq 0.56783E-09 -9.2458 0.56783E-09 -9.2458 0.10000E+01 0.0000 64 MnOH+ 0.24643E-09 -9.6083 0.21596E-09 -9.6656 0.87634E+00 -0.0573 65 MnO2-2 0.18546E-11 -11.7318 0.11555E-11 -11.9372 0.62308E+00 -0.2055 66 HMnO2- 0.37280E-10 -10.4285 0.32638E-10 -10.4863 0.87547E+00 -0.0578 69 MnCl+ 0.76223E-14 -14.1179 0.66797E-14 -14.1752 0.87634E+00 -0.0573 70 MnSO4,aq 0.41259E-13 -13.3845 0.41259E-13 -13.3845 0.10000E+01 0.0000 71 NaCl,aq 0.30877E-06 -6.5104 0.30877E-06 -6.5104 0.10000E+01 0.0000 72 NaOH,aq 0.26400E-04 -4.5784 0.26400E-04 -4.5784 0.10000E+01 0.0000 74 OH- 0.52607E-02 -2.2790 0.46013E-02 -2.3371 0.87465E+00 -0.0582 79 HPO3-2 0.21729E-17 -17.6630 0.13539E-17 -17.8684 0.62308E+00 -0.2055 82 H3PO4,aq 0.30429E-16 -16.5167 0.30429E-16 -16.5167 0.10000E+01 0.0000 83 H2PO4- 0.72571E-09 -9.1392 0.63565E-09 -9.1968 0.87590E+00 -0.0575 84 PO4-3 0.51721E-08 -8.2863 0.18632E-08 -8.7297 0.36023E+00 -0.4434 87 H2P2O7-2 0.50753E-19 -19.2945 0.31623E-19 -19.5000 0.62308E+00 -0.2055 88 HP2O7-3 0.14159E-15 -15.8490 0.49742E-16 -16.3033 0.35132E+00 -0.4543 89 P2O7-4 0.58805E-15 -15.2306 0.94132E-16 -16.0263 0.16007E+00 -0.7957 90 H2S,aq 0.22850E-15 -15.6411 0.22814E-15 -15.6418 0.99843E+00 -0.0007 97 SO3-2 0.53313E-14 -14.2732 0.33468E-14 -14.4754 0.62776E+00 -0.2022 98 HSO3- 0.29164E-16 -16.5351 0.25533E-16 -16.5929 0.87547E+00 -0.0578 99 HSO4- 0.21971E-11 -11.6581 0.19264E-11 -11.7153 0.87677E+00 -0.0571 Charge balance for all species = 0.8957E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1484397E-09 -.9395643E-02 -.9464049E+01 0.0000 2 H2O 0.1000000E+01 0.5550978E+02 0.9993712E+06 0.0000 3 Cl- 0.1379087E-03 0.1382176E-03 0.4897023E+01 5.9667 4 SO4-- 0.2553203E-04 0.2555088E-04 0.2452853E+01 14.9718 5 HCO3- 0.6553947E-05 0.1309306E-04 0.7983791E+00 4.6439 6 HS- 0.6652617E-12 -.1419539E-08 -.4691629E-04 -2.3499 7 Al+++ 0.7251580E-27 0.5815493E-04 0.1568081E+01 2.0605 8 H4SiO4 0.4081332E-03 0.4277178E-02 0.4108337E+03 -3.3892 9 Ca++ 0.4309713E-07 0.6319751E-07 0.2531173E-02 12.1975 10 Mg++ 0.1865555E-10 0.5947500E-10 0.1445010E-05 8.8329 11 Fe++ 0.1102839E-12 0.2962988E-07 0.1653657E-02 6.6048 12 K+ 0.7044060E-04 0.7066444E-04 0.2761313E+01 5.6753 13 Na+ 0.8946962E-02 0.9353641E-02 0.2148977E+03 7.7787 14 Mn++ 0.1473087E-10 0.8681808E-09 0.4766491E-04 8.7307 15 HPO4-- 0.4458420E-06 0.4517398E-06 0.4332917E-01 13.2139 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1854258E+00 -.9379097E-02 -.1760467E+00 0.0000000E+00 2 H2O 0.5536787E+02 0.5541203E+02 -.4416202E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3358669E-03 0.2550589E-04 0.3103610E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3103625E-03 -.1417039E-08 -.3103610E-03 0.0000000E+00 7 Al+++ 0.3651705E-01 0.5805251E-04 0.3645899E-01 0.0000000E+00 8 H4SiO4 0.1166128E+00 0.4269645E-02 0.1123431E+00 0.0000000E+00 9 Ca++ 0.1289492E-01 0.6308621E-07 0.1289486E-01 0.0000000E+00 10 Mg++ 0.8888095E-02 0.5937026E-10 0.8888095E-02 0.0000000E+00 11 Fe++ 0.7984983E-02 0.2957770E-07 0.7984954E-02 0.0000000E+00 12 K+ 0.2377707E-02 0.7053999E-04 0.2307167E-02 0.0000000E+00 13 Na+ 0.1421754E-01 0.9337169E-02 0.4880376E-02 0.0000000E+00 14 Mn++ 0.1941749E-03 0.8666519E-09 0.1941741E-03 0.0000000E+00 15 HPO4-- 0.6627094E-04 0.4509443E-06 0.6582000E-04 0.0000000E+00 Chg. balance for solid moles: -.9134E-17 Mass of aqueous solution: 0.998892E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 11.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4880E-02 -2.312 1.280 0.107 10.47 0.4913 apatite-OH 0.2194E-04 -4.659 0.1102E-01 -1.958 0.9014E-01 0.3502E-02 clinochlore 0.1778E-02 -2.750 0.9881 -0.005 8.082 0.3758 daphnite 0.1100E-02 -2.958 0.7852 -0.105 6.422 0.2379 chlorite-Mn 0.3883E-04 -4.411 0.2753E-01 -1.560 0.2252 0.8774E-02 hematite 0.8909E-03 -3.050 0.1423 -0.847 1.164 0.2697E-01 microcline 0.2307E-02 -2.637 0.6422 -0.192 5.253 0.2509 prehnite-Fe 0.5121E-03 -3.291 0.2260 -0.646 1.848 0.7581E-01 stilbite 0.1146E-01 -1.941 8.073 0.907 66.03 3.765 andradite 0.9446E-04 -4.025 0.4800E-01 -1.319 0.3926 0.1247E-01 grossular 0.7357E-05 -5.133 0.3314E-02 -2.480 0.2711E-01 0.9221E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9277E+00 0.9277E+00 1.0000 -0.033 grossular 0.7226E-01 0.7226E-01 1.0000 -1.141 Solid products produced: Mass = 12.226116 g Volume = 5.249639 cm3 Porosity: 4.1967% V(tot) - V(min): 0.22996E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 11.1990000 g log = 1.0492 Original solution: 1000.0103000 g Original solution / Rock added: 89.29 (Water/Rock Ratio), log = 1.9508 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1630E-06 1.0073 0.1728E-06 0.1715E-06 CH4,gas 0.3058E-15 1.0129 0.3259E-15 0.3217E-15 H2,gas 0.2008E-05 1.0006 0.2114E-05 0.2113E-05 H2S,gas 0.6351E-14 0.9959 0.6654E-14 0.6681E-14 S2,gas 0.3528E-36 1.0000 0.3711E-36 0.3711E-36 CO,gas 0.8993E-16 1.0000 0.9460E-16 0.9460E-16 SO3,gas 0.9619E-40 1.0000 0.1012E-39 0.1012E-39 SO2,gas 0.7692E-23 1.0000 0.8092E-23 0.8092E-23 HCl,gas 0.4969E-17 1.0000 0.5227E-17 0.5227E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 137 prehnite-Fe 22.59 22.59 0.00 0.000 0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.13 -8.76 -2.921 0.14962E+05 -6.763 3 CH4,gas 4.81 -12.68 -17.49 -4.372 0.29858E+05 -15.487 4 H2,gas 8.29 0.61 -7.67 -4.386 0.13105E+05 -5.675 5 H2S,gas -5.94 -22.12 -16.18 -8.088 0.27622E+05 -14.177 6 S2,gas -7.03 -45.46 -38.43 -5.912 0.65619E+05 -36.431 7 CO,gas 3.51 -14.51 -18.02 -5.546 0.30776E+05 -16.024 8 SO3,gas 17.43 -24.57 -41.99 -10.499 0.71705E+05 -39.995 9 SO2,gas 1.14 -23.96 -25.09 -6.691 0.42844E+05 -23.092 10 HCl,gas 5.48 -13.80 -19.28 -9.641 0.32923E+05 -17.282 11 acmite 7.74 7.30 -0.44 -0.046 0.74830E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.15 -4.40 -0.220 0.75203E+04 20 analcite 3.37 3.06 -0.31 -0.034 0.52898E+03 21 andalusite 5.06 0.73 -4.33 -0.433 0.73943E+04 26 annite 20.21 17.38 -2.83 -0.157 0.48265E+04 27 phlogopite 27.15 24.07 -3.08 -0.171 0.52587E+04 29 anorthite 12.80 9.54 -3.26 -0.251 0.55622E+04 35 aragonite 0.99 -2.93 -3.91 -1.305 0.66839E+04 36 brucite 12.58 8.83 -3.74 -0.749 0.63923E+04 37 calcite 0.83 -2.93 -3.76 -1.254 0.64225E+04 38 carnegieite-low 9.06 6.45 -2.61 -0.374 0.44642E+04 39 carnegieite-high 10.13 6.45 -3.68 -0.526 0.62911E+04 40 carpholite-Mg 8.65 6.18 -2.47 -0.165 0.42258E+04 41 carpholite-Fe 6.78 3.95 -2.84 -0.189 0.48415E+04 42 celadonite 5.40 3.01 -2.39 -0.141 0.40785E+04 43 celadonite-Fe 3.94 0.78 -3.15 -0.185 0.53839E+04 44 chrysotile 23.94 19.72 -4.22 -0.351 0.72007E+04 50 chloritoid-Mg 13.26 9.56 -3.70 -0.246 0.63118E+04 51 chloritoid-Fe 9.24 7.34 -1.90 -0.127 0.32477E+04 52 chloritoid-Mn 11.46 9.46 -2.00 -0.133 0.34161E+04 54 coesite -2.37 -3.39 -1.02 -0.340 0.17414E+04 59 corundum 8.43 4.12 -4.31 -0.392 0.73633E+04 61 cristobalite -2.55 -3.39 -0.84 -0.280 0.14342E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.06 -0.84 -0.139 0.14267E+04 67 diopside 16.22 14.25 -1.96 -0.196 0.33526E+04 68 hedenbergite 14.24 12.02 -2.22 -0.222 0.37914E+04 75 epidote 24.78 24.65 -0.13 -0.006 0.21845E+03 76 clinozoisite 22.92 20.41 -2.51 -0.114 0.42895E+04 77 epidote-Fe 29.94 28.89 -1.05 -0.055 0.17949E+04 78 fayalite 14.08 9.82 -4.26 -0.608 0.72714E+04 79 ferrosilite 11.19 6.43 -4.76 -0.476 0.81216E+04 83 gibbsite 4.10 2.06 -2.04 -0.291 0.34779E+04 84 glaucophane 23.11 19.06 -4.05 -0.109 0.69103E+04 87 greenalite 16.19 13.04 -3.16 -0.263 0.53925E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.06 -1.19 -0.119 0.20320E+04 96 julgoldite 70.57 66.86 -3.71 -0.096 0.63400E+04 97 kalsilite 7.62 4.35 -3.27 -0.468 0.55897E+04 98 kaolinite -1.27 -2.66 -1.38 -0.126 0.23636E+04 99 kyanite 4.93 0.73 -4.20 -0.420 0.71711E+04 101 laumontite 2.97 2.76 -0.21 -0.014 0.36336E+03 102 lawsonite 9.68 9.54 -0.14 -0.009 0.23604E+03 103 leucite 4.17 0.96 -3.21 -0.321 0.54814E+04 105 lizardite 23.29 19.72 -3.57 -0.297 0.60910E+04 107 magnetite 20.13 19.20 -0.93 -0.076 0.15886E+04 108 minnesotaite 10.46 6.26 -4.20 -0.247 0.71767E+04 110 magnesioferrite 26.26 21.43 -4.83 -0.394 0.82416E+04 113 margarite 17.45 13.66 -3.79 -0.152 0.64724E+04 120 muscovite 2.68 1.69 -0.99 -0.058 0.16904E+04 121 paragonite 4.34 3.79 -0.54 -0.032 0.92884E+03 122 nepheline 8.38 6.45 -1.93 -0.275 0.32922E+04 134 phlogopite-Na 29.73 26.17 -3.56 -0.198 0.60806E+04 136 prehnite 19.47 18.35 -1.12 -0.066 0.19087E+04 138 pumpellyite-Fe 46.47 45.36 -1.11 -0.025 0.18924E+04 139 pumpellyite-Mg 49.19 47.59 -1.60 -0.036 0.27384E+04 145 pyroxmangite 7.42 5.34 -2.07 -0.415 0.35422E+04 146 pyrophyllite -6.10 -9.44 -3.34 -0.209 0.56991E+04 147 quartz -2.98 -3.39 -0.41 -0.136 0.69528E+03 152 rhodonite 7.46 5.34 -2.12 -0.424 0.36214E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.73 -4.59 -0.459 0.78365E+04 164 stilpnomelane-Fe 13.18 12.87 -0.31 -0.009 0.52977E+03 165 stilpnomelane-Mg 27.60 24.01 -3.59 -0.107 0.61246E+04 171 talc 16.55 12.94 -3.61 -0.212 0.61667E+04 174 tephroite 18.11 14.07 -4.04 -0.577 0.68994E+04 177 topaz-H 4.67 0.73 -3.94 -0.358 0.67202E+04 178 tridymite -2.61 -3.39 -0.77 -0.258 0.13226E+04 187 wairakite 4.06 2.76 -1.30 -0.076 0.22142E+04 188 walstromite 11.53 8.81 -2.72 -0.544 0.46435E+04 189 wollastonite 10.48 8.81 -1.67 -0.335 0.28574E+04 190 pseudo-wollastonite 11.02 8.81 -2.21 -0.442 0.37761E+04 191 zoisite 22.96 20.41 -2.55 -0.116 0.43620E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.62 -4.07 -0.251 0.69411E+04 195 beidellite-K -1.44 -5.76 -4.33 -0.265 0.73925E+04 196 beidellite-Mg -1.71 -6.18 -4.47 -0.277 0.76376E+04 197 beidellite-Na -1.26 -5.07 -3.81 -0.234 0.65112E+04 199 chalcedony -2.79 -3.39 -0.59 -0.198 0.10156E+04 201 montmorillonite-Ca -2.21 -5.19 -2.97 -0.184 0.50785E+04 202 montmorillonite-K -2.16 -5.33 -3.17 -0.194 0.54077E+04 203 montmorillonite-Mg -2.40 -5.74 -3.34 -0.207 0.57061E+04 204 montmorillonite-Na -1.96 -4.63 -2.67 -0.164 0.45646E+04 205 nontronite-Ca 3.28 2.85 -0.43 -0.028 0.73052E+03 206 nontronite-H 2.60 0.84 -1.76 -0.118 0.29992E+04 207 nontronite-K 3.40 2.71 -0.69 -0.044 0.11811E+04 208 nontronite-Mg 3.14 2.30 -0.84 -0.055 0.14387E+04 209 nontronite-Na 3.58 3.41 -0.18 -0.011 0.30156E+03 224 tobermorite 9.84 6.77 -3.07 -0.837 0.52380E+04 233 boehmite 4.43 2.06 -2.37 -0.395 0.40452E+04 235 ferrous-oxide 9.82 6.60 -3.22 -0.805 0.54971E+04 240 silica-amorphous -2.08 -3.39 -1.31 -0.436 0.22358E+04 242 an20ab80 2.08 1.65 -0.43 -0.033 0.74082E+03 243 an25ab75 2.71 2.14 -0.57 -0.044 0.97393E+03 244 an30ab70 3.34 2.63 -0.71 -0.055 0.12154E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 11.1990000 g New total amount of reactant added: 11.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8630E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 11.5990000 Water: Moles liquid = 0.5541E+02 kg liquid = 0.9982E+00 Moles total = 0.5536E+02 kg total = 0.9974E+00 Activity = 1.0000 Stoichiometric ionic strength = .5101564E-02 Osmotic coef. = 0.9621 True ionic strength = .9050087E-02 Chg. balance for total moles = 0.8630E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14844E-09 -9.8284 0.13036E-09 -9.8848 0.87822E+00 -0.0564 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13791E-03 -3.8604 0.12074E-03 -3.9181 0.87547E+00 -0.0578 4 SO4-- 0.25533E-04 -4.5929 0.15927E-04 -4.7979 0.62377E+00 -0.2050 5 HCO3- 0.65542E-05 -5.1835 0.57424E-05 -5.2409 0.87613E+00 -0.0574 6 HS- 0.66529E-12 -12.1770 0.58249E-12 -12.2347 0.87554E+00 -0.0577 7 Al+++ 0.72516E-27 -27.1396 0.25466E-27 -27.5940 0.35118E+00 -0.4545 8 H4SiO4 0.40813E-03 -3.3892 0.40813E-03 -3.3892 0.10000E+01 0.0000 9 Ca++ 0.43097E-07 -7.3656 0.26781E-07 -7.5722 0.62141E+00 -0.2066 10 Mg++ 0.18656E-10 -10.7292 0.11565E-10 -10.9368 0.61994E+00 -0.2077 11 Fe++ 0.11028E-12 -12.9575 0.68408E-13 -13.1649 0.62029E+00 -0.2074 12 K+ 0.70441E-04 -4.1522 0.61723E-04 -4.2096 0.87624E+00 -0.0574 13 Na+ 0.89470E-02 -2.0483 0.78322E-02 -2.1061 0.87540E+00 -0.0578 14 Mn++ 0.14731E-10 -10.8318 0.91413E-11 -11.0390 0.62056E+00 -0.2072 15 HPO4-- 0.44584E-06 -6.3508 0.27812E-06 -6.5558 0.62381E+00 -0.2049 16 HSiO3- 0.34891E-02 -2.4573 0.30546E-02 -2.5150 0.87547E+00 -0.0578 17 Ca(HSiO3)+ 0.20915E-08 -8.6795 0.18329E-08 -8.7369 0.87634E+00 -0.0573 18 Mg(HSiO3)+ 0.11240E-11 -11.9492 0.98505E-12 -12.0065 0.87634E+00 -0.0573 19 NaHSiO3,aq 0.37997E-03 -3.4203 0.37997E-03 -3.4203 0.10000E+01 0.0000 20 AlO+ 0.22075E-14 -14.6561 0.19345E-14 -14.7134 0.87634E+00 -0.0573 22 HAlO2,aq 0.29695E-08 -8.5273 0.29695E-08 -8.5273 0.10000E+01 0.0000 23 AlO2- 0.58152E-04 -4.2354 0.50863E-04 -4.2936 0.87465E+00 -0.0582 24 CH4,aq 0.20640E-18 -18.6853 0.20608E-18 -18.6860 0.99843E+00 -0.0007 29 CO,aq 0.59911E-19 -19.2225 0.59911E-19 -19.2225 0.10000E+01 0.0000 30 CO2,aq 0.15117E-08 -8.8205 0.15093E-08 -8.8212 0.99843E+00 -0.0007 31 CO3-2 0.65365E-05 -5.1847 0.40728E-05 -5.3901 0.62308E+00 -0.2055 32 CaCO3,aq 0.13359E-08 -8.8742 0.13359E-08 -8.8742 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44217E-11 -11.3544 0.38750E-11 -11.4117 0.87634E+00 -0.0573 34 CaCl+ 0.58797E-11 -11.2306 0.51526E-11 -11.2880 0.87634E+00 -0.0573 35 CaCl2,aq 0.14485E-15 -15.8391 0.14485E-15 -15.8391 0.10000E+01 0.0000 36 CaOH+ 0.16530E-07 -7.7817 0.14486E-07 -7.8391 0.87634E+00 -0.0573 37 CaSO4,aq 0.13290E-09 -9.8765 0.13290E-09 -9.8765 0.10000E+01 0.0000 38 HCl,aq 0.29606E-14 -14.5286 0.29606E-14 -14.5286 0.10000E+01 0.0000 43 FeCl+ 0.14680E-16 -16.8333 0.12864E-16 -16.8906 0.87634E+00 -0.0573 46 FeO,aq 0.15918E-09 -9.7981 0.15918E-09 -9.7981 0.10000E+01 0.0000 47 FeOH+ 0.19852E-10 -10.7022 0.17397E-10 -10.7595 0.87634E+00 -0.0573 48 HFeO2- 0.15002E-07 -7.8239 0.13134E-07 -7.8816 0.87547E+00 -0.0578 49 FeO+ 0.12305E-14 -14.9099 0.10784E-14 -14.9672 0.87634E+00 -0.0573 51 FeO2- 0.14245E-07 -7.8463 0.12471E-07 -7.9041 0.87547E+00 -0.0578 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.15437E-08 -8.8115 0.15412E-08 -8.8121 0.99843E+00 -0.0007 54 KCl,aq 0.13196E-09 -9.8796 0.13196E-09 -9.8796 0.10000E+01 0.0000 55 KHSO4,aq 0.34293E-18 -18.4648 0.34293E-18 -18.4648 0.10000E+01 0.0000 56 KOH,aq 0.20641E-06 -6.6853 0.20641E-06 -6.6853 0.10000E+01 0.0000 57 KSO4- 0.17300E-07 -7.7620 0.15145E-07 -7.8197 0.87547E+00 -0.0578 58 MgCO3,aq 0.14415E-12 -12.8412 0.14415E-12 -12.8412 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19472E-14 -14.7106 0.17064E-14 -14.7679 0.87634E+00 -0.0573 60 MgCl+ 0.23051E-14 -14.6373 0.20200E-14 -14.6946 0.87634E+00 -0.0573 61 MgOH+ 0.39547E-10 -10.4029 0.34657E-10 -10.4602 0.87634E+00 -0.0573 63 MnO,aq 0.56783E-09 -9.2458 0.56783E-09 -9.2458 0.10000E+01 0.0000 64 MnOH+ 0.24643E-09 -9.6083 0.21596E-09 -9.6656 0.87634E+00 -0.0573 65 MnO2-2 0.18546E-11 -11.7318 0.11555E-11 -11.9372 0.62308E+00 -0.2055 66 HMnO2- 0.37280E-10 -10.4285 0.32638E-10 -10.4863 0.87547E+00 -0.0578 69 MnCl+ 0.76226E-14 -14.1179 0.66800E-14 -14.1752 0.87634E+00 -0.0573 70 MnSO4,aq 0.41261E-13 -13.3845 0.41261E-13 -13.3845 0.10000E+01 0.0000 71 NaCl,aq 0.30878E-06 -6.5103 0.30878E-06 -6.5103 0.10000E+01 0.0000 72 NaOH,aq 0.26400E-04 -4.5784 0.26400E-04 -4.5784 0.10000E+01 0.0000 74 OH- 0.52607E-02 -2.2790 0.46013E-02 -2.3371 0.87465E+00 -0.0582 79 HPO3-2 0.21729E-17 -17.6630 0.13539E-17 -17.8684 0.62308E+00 -0.2055 82 H3PO4,aq 0.30429E-16 -16.5167 0.30429E-16 -16.5167 0.10000E+01 0.0000 83 H2PO4- 0.72571E-09 -9.1392 0.63565E-09 -9.1968 0.87590E+00 -0.0575 84 PO4-3 0.51721E-08 -8.2863 0.18632E-08 -8.7297 0.36023E+00 -0.4434 87 H2P2O7-2 0.50753E-19 -19.2945 0.31623E-19 -19.5000 0.62308E+00 -0.2055 88 HP2O7-3 0.14159E-15 -15.8490 0.49742E-16 -16.3033 0.35132E+00 -0.4543 89 P2O7-4 0.58805E-15 -15.2306 0.94131E-16 -16.0263 0.16007E+00 -0.7957 90 H2S,aq 0.22851E-15 -15.6411 0.22815E-15 -15.6418 0.99843E+00 -0.0007 97 SO3-2 0.53316E-14 -14.2731 0.33469E-14 -14.4754 0.62776E+00 -0.2022 98 HSO3- 0.29166E-16 -16.5351 0.25534E-16 -16.5929 0.87547E+00 -0.0578 99 HSO4- 0.21972E-11 -11.6581 0.19265E-11 -11.7152 0.87677E+00 -0.0571 Charge balance for all species = 0.8525E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1484398E-09 -.9395639E-02 -.9464045E+01 0.0000 2 H2O 0.1000000E+01 0.5550978E+02 0.9993712E+06 0.0000 3 Cl- 0.1379145E-03 0.1382234E-03 0.4897229E+01 5.9667 4 SO4-- 0.2553311E-04 0.2555196E-04 0.2452957E+01 14.9718 5 HCO3- 0.6554225E-05 0.1309361E-04 0.7984128E+00 4.6439 6 HS- 0.6652904E-12 -.1419538E-08 -.4691626E-04 -2.3499 7 Al+++ 0.7251593E-27 0.5815490E-04 0.1568080E+01 2.0605 8 H4SiO4 0.4081332E-03 0.4277176E-02 0.4108335E+03 -3.3892 9 Ca++ 0.4309718E-07 0.6319763E-07 0.2531178E-02 12.1975 10 Mg++ 0.1865557E-10 0.5947505E-10 0.1445011E-05 8.8329 11 Fe++ 0.1102840E-12 0.2962986E-07 0.1653657E-02 6.6048 12 K+ 0.7044063E-04 0.7066447E-04 0.2761315E+01 5.6753 13 Na+ 0.8946967E-02 0.9353646E-02 0.2148978E+03 7.7787 14 Mn++ 0.1473089E-10 0.8681810E-09 0.4766493E-04 8.7307 15 HPO4-- 0.4458416E-06 0.4517394E-06 0.4332913E-01 13.2139 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1920492E+00 -.9378698E-02 -.1826705E+00 0.0000000E+00 2 H2O 0.5536285E+02 0.5540969E+02 -.4683943E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3469523E-03 0.2550589E-04 0.3214464E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3214478E-03 -.1416979E-08 -.3214464E-03 0.0000000E+00 7 Al+++ 0.3782134E-01 0.5805004E-04 0.3776329E-01 0.0000000E+00 8 H4SiO4 0.1207779E+00 0.4269463E-02 0.1165084E+00 0.0000000E+00 9 Ca++ 0.1335498E-01 0.6308367E-07 0.1335491E-01 0.0000000E+00 10 Mg++ 0.9205556E-02 0.5936781E-10 0.9205555E-02 0.0000000E+00 11 Fe++ 0.8270187E-02 0.2957644E-07 0.8270157E-02 0.0000000E+00 12 K+ 0.2462633E-02 0.7053705E-04 0.2392096E-02 0.0000000E+00 13 Na+ 0.1471964E-01 0.9336780E-02 0.5382862E-02 0.0000000E+00 14 Mn++ 0.2011104E-03 0.8666156E-09 0.2011095E-03 0.0000000E+00 15 HPO4-- 0.6863797E-04 0.4509249E-06 0.6818705E-04 0.0000000E+00 Chg. balance for solid moles: 0.3808E-16 Mass of aqueous solution: 0.998850E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 11.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5383E-02 -2.269 1.411 0.150 11.14 0.5418 andradite 0.1955E-03 -3.709 0.9935E-01 -1.003 0.7845 0.2581E-01 grossular 0.1523E-04 -4.817 0.6859E-02 -2.164 0.5416E-01 0.1909E-02 apatite-OH 0.2273E-04 -4.643 0.1142E-01 -1.942 0.9015E-01 0.3628E-02 clinochlore 0.1841E-02 -2.735 1.023 0.010 8.080 0.3893 daphnite 0.1140E-02 -2.943 0.8132 -0.090 6.421 0.2464 chlorite-Mn 0.4022E-04 -4.396 0.2852E-01 -1.545 0.2252 0.9087E-02 hematite 0.8732E-03 -3.059 0.1395 -0.856 1.101 0.2643E-01 microcline 0.2392E-02 -2.621 0.6658 -0.177 5.257 0.2601 prehnite-Fe 0.4341E-03 -3.362 0.1915 -0.718 1.512 0.6426E-01 stilbite 0.1174E-01 -1.930 8.274 0.918 65.33 3.859 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9277E+00 0.9277E+00 1.0000 -0.033 grossular 0.7226E-01 0.7226E-01 1.0000 -1.141 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 12.665003 g Volume = 5.427868 cm3 Porosity: 3.7544% V(tot) - V(min): 0.21173E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 11.5990000 g log = 1.0644 Original solution: 1000.0103000 g Original solution / Rock added: 86.22 (Water/Rock Ratio), log = 1.9356 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1630E-06 1.0073 0.1728E-06 0.1715E-06 CH4,gas 0.3058E-15 1.0129 0.3259E-15 0.3217E-15 H2,gas 0.2008E-05 1.0006 0.2114E-05 0.2113E-05 H2S,gas 0.6352E-14 0.9959 0.6654E-14 0.6681E-14 S2,gas 0.3528E-36 1.0000 0.3711E-36 0.3711E-36 CO,gas 0.8993E-16 1.0000 0.9460E-16 0.9460E-16 SO3,gas 0.9619E-40 1.0000 0.1012E-39 0.1012E-39 SO2,gas 0.7692E-23 1.0000 0.8092E-23 0.8092E-23 HCl,gas 0.4970E-17 1.0000 0.5228E-17 0.5228E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 137 prehnite-Fe 22.59 22.59 0.00 0.000 -0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.13 -8.76 -2.921 0.14962E+05 -6.763 3 CH4,gas 4.81 -12.68 -17.49 -4.372 0.29858E+05 -15.487 4 H2,gas 8.29 0.61 -7.67 -4.386 0.13105E+05 -5.675 5 H2S,gas -5.94 -22.12 -16.18 -8.088 0.27622E+05 -14.177 6 S2,gas -7.03 -45.46 -38.43 -5.912 0.65619E+05 -36.430 7 CO,gas 3.51 -14.51 -18.02 -5.546 0.30776E+05 -16.024 8 SO3,gas 17.43 -24.57 -41.99 -10.499 0.71705E+05 -39.995 9 SO2,gas 1.14 -23.96 -25.09 -6.691 0.42844E+05 -23.092 10 HCl,gas 5.48 -13.80 -19.28 -9.641 0.32923E+05 -17.282 11 acmite 7.74 7.30 -0.44 -0.046 0.74830E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.15 -4.40 -0.220 0.75203E+04 20 analcite 3.37 3.06 -0.31 -0.034 0.52898E+03 21 andalusite 5.06 0.73 -4.33 -0.433 0.73943E+04 26 annite 20.21 17.38 -2.83 -0.157 0.48265E+04 27 phlogopite 27.15 24.07 -3.08 -0.171 0.52587E+04 29 anorthite 12.80 9.54 -3.26 -0.251 0.55622E+04 35 aragonite 0.99 -2.93 -3.91 -1.305 0.66838E+04 36 brucite 12.58 8.83 -3.74 -0.749 0.63923E+04 37 calcite 0.83 -2.93 -3.76 -1.254 0.64225E+04 38 carnegieite-low 9.06 6.45 -2.61 -0.374 0.44642E+04 39 carnegieite-high 10.13 6.45 -3.68 -0.526 0.62911E+04 40 carpholite-Mg 8.65 6.18 -2.47 -0.165 0.42258E+04 41 carpholite-Fe 6.78 3.95 -2.84 -0.189 0.48415E+04 42 celadonite 5.40 3.01 -2.39 -0.141 0.40785E+04 43 celadonite-Fe 3.94 0.78 -3.15 -0.185 0.53839E+04 44 chrysotile 23.94 19.72 -4.22 -0.351 0.72007E+04 50 chloritoid-Mg 13.26 9.56 -3.70 -0.246 0.63118E+04 51 chloritoid-Fe 9.24 7.34 -1.90 -0.127 0.32477E+04 52 chloritoid-Mn 11.46 9.46 -2.00 -0.133 0.34161E+04 54 coesite -2.37 -3.39 -1.02 -0.340 0.17414E+04 59 corundum 8.43 4.12 -4.31 -0.392 0.73633E+04 61 cristobalite -2.55 -3.39 -0.84 -0.280 0.14342E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.06 -0.84 -0.139 0.14267E+04 67 diopside 16.22 14.25 -1.96 -0.196 0.33526E+04 68 hedenbergite 14.24 12.02 -2.22 -0.222 0.37914E+04 75 epidote 24.78 24.65 -0.13 -0.006 0.21845E+03 76 clinozoisite 22.92 20.41 -2.51 -0.114 0.42895E+04 77 epidote-Fe 29.94 28.89 -1.05 -0.055 0.17949E+04 78 fayalite 14.08 9.82 -4.26 -0.608 0.72714E+04 79 ferrosilite 11.19 6.43 -4.76 -0.476 0.81216E+04 83 gibbsite 4.10 2.06 -2.04 -0.291 0.34779E+04 84 glaucophane 23.11 19.06 -4.05 -0.109 0.69103E+04 87 greenalite 16.19 13.04 -3.16 -0.263 0.53925E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.06 -1.19 -0.119 0.20320E+04 96 julgoldite 70.57 66.86 -3.71 -0.096 0.63400E+04 97 kalsilite 7.62 4.35 -3.27 -0.468 0.55897E+04 98 kaolinite -1.27 -2.66 -1.38 -0.126 0.23636E+04 99 kyanite 4.93 0.73 -4.20 -0.420 0.71711E+04 101 laumontite 2.97 2.76 -0.21 -0.014 0.36336E+03 102 lawsonite 9.68 9.54 -0.14 -0.009 0.23604E+03 103 leucite 4.17 0.96 -3.21 -0.321 0.54814E+04 105 lizardite 23.29 19.72 -3.57 -0.297 0.60910E+04 107 magnetite 20.13 19.20 -0.93 -0.076 0.15886E+04 108 minnesotaite 10.46 6.26 -4.20 -0.247 0.71767E+04 110 magnesioferrite 26.26 21.43 -4.83 -0.394 0.82416E+04 113 margarite 17.45 13.66 -3.79 -0.152 0.64724E+04 120 muscovite 2.68 1.69 -0.99 -0.058 0.16904E+04 121 paragonite 4.34 3.79 -0.54 -0.032 0.92884E+03 122 nepheline 8.38 6.45 -1.93 -0.275 0.32922E+04 134 phlogopite-Na 29.73 26.17 -3.56 -0.198 0.60806E+04 136 prehnite 19.47 18.35 -1.12 -0.066 0.19087E+04 138 pumpellyite-Fe 46.47 45.36 -1.11 -0.025 0.18924E+04 139 pumpellyite-Mg 49.19 47.59 -1.60 -0.036 0.27384E+04 145 pyroxmangite 7.42 5.34 -2.07 -0.415 0.35422E+04 146 pyrophyllite -6.10 -9.44 -3.34 -0.209 0.56991E+04 147 quartz -2.98 -3.39 -0.41 -0.136 0.69528E+03 152 rhodonite 7.46 5.34 -2.12 -0.424 0.36214E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.73 -4.59 -0.459 0.78365E+04 164 stilpnomelane-Fe 13.18 12.87 -0.31 -0.009 0.52977E+03 165 stilpnomelane-Mg 27.60 24.01 -3.59 -0.107 0.61246E+04 171 talc 16.55 12.94 -3.61 -0.212 0.61667E+04 174 tephroite 18.11 14.07 -4.04 -0.577 0.68994E+04 177 topaz-H 4.67 0.73 -3.94 -0.358 0.67202E+04 178 tridymite -2.61 -3.39 -0.77 -0.258 0.13226E+04 187 wairakite 4.06 2.76 -1.30 -0.076 0.22142E+04 188 walstromite 11.53 8.81 -2.72 -0.544 0.46435E+04 189 wollastonite 10.48 8.81 -1.67 -0.335 0.28574E+04 190 pseudo-wollastonite 11.02 8.81 -2.21 -0.442 0.37761E+04 191 zoisite 22.96 20.41 -2.55 -0.116 0.43620E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.62 -4.07 -0.251 0.69411E+04 195 beidellite-K -1.44 -5.76 -4.33 -0.265 0.73925E+04 196 beidellite-Mg -1.71 -6.18 -4.47 -0.277 0.76376E+04 197 beidellite-Na -1.26 -5.07 -3.81 -0.234 0.65112E+04 199 chalcedony -2.79 -3.39 -0.59 -0.198 0.10156E+04 201 montmorillonite-Ca -2.21 -5.19 -2.97 -0.184 0.50785E+04 202 montmorillonite-K -2.16 -5.33 -3.17 -0.194 0.54077E+04 203 montmorillonite-Mg -2.40 -5.74 -3.34 -0.207 0.57061E+04 204 montmorillonite-Na -1.96 -4.63 -2.67 -0.164 0.45646E+04 205 nontronite-Ca 3.28 2.85 -0.43 -0.028 0.73052E+03 206 nontronite-H 2.60 0.84 -1.76 -0.118 0.29992E+04 207 nontronite-K 3.40 2.71 -0.69 -0.044 0.11811E+04 208 nontronite-Mg 3.14 2.30 -0.84 -0.055 0.14387E+04 209 nontronite-Na 3.58 3.41 -0.18 -0.011 0.30156E+03 224 tobermorite 9.84 6.77 -3.07 -0.837 0.52380E+04 233 boehmite 4.43 2.06 -2.37 -0.395 0.40452E+04 235 ferrous-oxide 9.82 6.60 -3.22 -0.805 0.54971E+04 240 silica-amorphous -2.08 -3.39 -1.31 -0.436 0.22358E+04 242 an20ab80 2.08 1.65 -0.43 -0.033 0.74082E+03 243 an25ab75 2.71 2.14 -0.57 -0.044 0.97393E+03 244 an30ab70 3.34 2.63 -0.71 -0.055 0.12154E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 11.5990000 g New total amount of reactant added: 11.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8627E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 11.9990000 Water: Moles liquid = 0.5541E+02 kg liquid = 0.9982E+00 Moles total = 0.5536E+02 kg total = 0.9973E+00 Activity = 1.0000 Stoichiometric ionic strength = .5101571E-02 Osmotic coef. = 0.9621 True ionic strength = .9050093E-02 Chg. balance for total moles = 0.8627E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14844E-09 -9.8284 0.13036E-09 -9.8848 0.87822E+00 -0.0564 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13792E-03 -3.8604 0.12075E-03 -3.9181 0.87547E+00 -0.0578 4 SO4-- 0.25534E-04 -4.5929 0.15927E-04 -4.7979 0.62377E+00 -0.2050 5 HCO3- 0.65545E-05 -5.1835 0.57426E-05 -5.2409 0.87613E+00 -0.0574 6 HS- 0.66532E-12 -12.1770 0.58251E-12 -12.2347 0.87554E+00 -0.0577 7 Al+++ 0.72516E-27 -27.1396 0.25466E-27 -27.5940 0.35118E+00 -0.4545 8 H4SiO4 0.40813E-03 -3.3892 0.40813E-03 -3.3892 0.10000E+01 0.0000 9 Ca++ 0.43097E-07 -7.3656 0.26781E-07 -7.5722 0.62141E+00 -0.2066 10 Mg++ 0.18656E-10 -10.7292 0.11565E-10 -10.9368 0.61994E+00 -0.2077 11 Fe++ 0.11028E-12 -12.9575 0.68408E-13 -13.1649 0.62029E+00 -0.2074 12 K+ 0.70441E-04 -4.1522 0.61723E-04 -4.2096 0.87624E+00 -0.0574 13 Na+ 0.89470E-02 -2.0483 0.78322E-02 -2.1061 0.87540E+00 -0.0578 14 Mn++ 0.14731E-10 -10.8318 0.91413E-11 -11.0390 0.62056E+00 -0.2072 15 HPO4-- 0.44584E-06 -6.3508 0.27812E-06 -6.5558 0.62381E+00 -0.2049 16 HSiO3- 0.34891E-02 -2.4573 0.30546E-02 -2.5150 0.87547E+00 -0.0578 17 Ca(HSiO3)+ 0.20915E-08 -8.6795 0.18329E-08 -8.7369 0.87634E+00 -0.0573 18 Mg(HSiO3)+ 0.11240E-11 -11.9492 0.98505E-12 -12.0065 0.87634E+00 -0.0573 19 NaHSiO3,aq 0.37997E-03 -3.4203 0.37997E-03 -3.4203 0.10000E+01 0.0000 20 AlO+ 0.22075E-14 -14.6561 0.19345E-14 -14.7134 0.87634E+00 -0.0573 22 HAlO2,aq 0.29695E-08 -8.5273 0.29695E-08 -8.5273 0.10000E+01 0.0000 23 AlO2- 0.58152E-04 -4.2354 0.50863E-04 -4.2936 0.87465E+00 -0.0582 24 CH4,aq 0.20641E-18 -18.6853 0.20609E-18 -18.6859 0.99843E+00 -0.0007 29 CO,aq 0.59914E-19 -19.2225 0.59914E-19 -19.2225 0.10000E+01 0.0000 30 CO2,aq 0.15117E-08 -8.8205 0.15094E-08 -8.8212 0.99843E+00 -0.0007 31 CO3-2 0.65368E-05 -5.1846 0.40729E-05 -5.3901 0.62308E+00 -0.2055 32 CaCO3,aq 0.13359E-08 -8.8742 0.13359E-08 -8.8742 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44219E-11 -11.3544 0.38751E-11 -11.4117 0.87634E+00 -0.0573 34 CaCl+ 0.58800E-11 -11.2306 0.51528E-11 -11.2880 0.87634E+00 -0.0573 35 CaCl2,aq 0.14487E-15 -15.8390 0.14487E-15 -15.8390 0.10000E+01 0.0000 36 CaOH+ 0.16530E-07 -7.7817 0.14486E-07 -7.8391 0.87634E+00 -0.0573 37 CaSO4,aq 0.13290E-09 -9.8765 0.13290E-09 -9.8765 0.10000E+01 0.0000 38 HCl,aq 0.29608E-14 -14.5286 0.29608E-14 -14.5286 0.10000E+01 0.0000 43 FeCl+ 0.14680E-16 -16.8333 0.12865E-16 -16.8906 0.87634E+00 -0.0573 46 FeO,aq 0.15918E-09 -9.7981 0.15918E-09 -9.7981 0.10000E+01 0.0000 47 FeOH+ 0.19852E-10 -10.7022 0.17397E-10 -10.7595 0.87634E+00 -0.0573 48 HFeO2- 0.15002E-07 -7.8239 0.13134E-07 -7.8816 0.87547E+00 -0.0578 49 FeO+ 0.12305E-14 -14.9099 0.10784E-14 -14.9672 0.87634E+00 -0.0573 51 FeO2- 0.14245E-07 -7.8463 0.12471E-07 -7.9041 0.87547E+00 -0.0578 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.15437E-08 -8.8115 0.15412E-08 -8.8121 0.99843E+00 -0.0007 54 KCl,aq 0.13196E-09 -9.8795 0.13196E-09 -9.8795 0.10000E+01 0.0000 55 KHSO4,aq 0.34295E-18 -18.4648 0.34295E-18 -18.4648 0.10000E+01 0.0000 56 KOH,aq 0.20641E-06 -6.6853 0.20641E-06 -6.6853 0.10000E+01 0.0000 57 KSO4- 0.17300E-07 -7.7619 0.15146E-07 -7.8197 0.87547E+00 -0.0578 58 MgCO3,aq 0.14416E-12 -12.8412 0.14416E-12 -12.8412 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19473E-14 -14.7106 0.17065E-14 -14.7679 0.87634E+00 -0.0573 60 MgCl+ 0.23052E-14 -14.6373 0.20201E-14 -14.6946 0.87634E+00 -0.0573 61 MgOH+ 0.39547E-10 -10.4029 0.34657E-10 -10.4602 0.87634E+00 -0.0573 63 MnO,aq 0.56783E-09 -9.2458 0.56783E-09 -9.2458 0.10000E+01 0.0000 64 MnOH+ 0.24643E-09 -9.6083 0.21596E-09 -9.6656 0.87634E+00 -0.0573 65 MnO2-2 0.18546E-11 -11.7318 0.11555E-11 -11.9372 0.62308E+00 -0.2055 66 HMnO2- 0.37280E-10 -10.4285 0.32638E-10 -10.4863 0.87547E+00 -0.0578 69 MnCl+ 0.76230E-14 -14.1179 0.66803E-14 -14.1752 0.87634E+00 -0.0573 70 MnSO4,aq 0.41263E-13 -13.3844 0.41263E-13 -13.3844 0.10000E+01 0.0000 71 NaCl,aq 0.30879E-06 -6.5103 0.30879E-06 -6.5103 0.10000E+01 0.0000 72 NaOH,aq 0.26400E-04 -4.5784 0.26400E-04 -4.5784 0.10000E+01 0.0000 74 OH- 0.52607E-02 -2.2790 0.46013E-02 -2.3371 0.87465E+00 -0.0582 79 HPO3-2 0.21729E-17 -17.6630 0.13539E-17 -17.8684 0.62308E+00 -0.2055 82 H3PO4,aq 0.30429E-16 -16.5167 0.30429E-16 -16.5167 0.10000E+01 0.0000 83 H2PO4- 0.72571E-09 -9.1392 0.63565E-09 -9.1968 0.87590E+00 -0.0575 84 PO4-3 0.51721E-08 -8.2863 0.18632E-08 -8.7297 0.36023E+00 -0.4434 87 H2P2O7-2 0.50753E-19 -19.2945 0.31623E-19 -19.5000 0.62308E+00 -0.2055 88 HP2O7-3 0.14158E-15 -15.8490 0.49742E-16 -16.3033 0.35132E+00 -0.4543 89 P2O7-4 0.58805E-15 -15.2306 0.94131E-16 -16.0263 0.16007E+00 -0.7957 90 H2S,aq 0.22852E-15 -15.6411 0.22816E-15 -15.6418 0.99843E+00 -0.0007 97 SO3-2 0.53318E-14 -14.2731 0.33471E-14 -14.4753 0.62776E+00 -0.2022 98 HSO3- 0.29167E-16 -16.5351 0.25535E-16 -16.5929 0.87547E+00 -0.0578 99 HSO4- 0.21973E-11 -11.6581 0.19265E-11 -11.7152 0.87677E+00 -0.0571 Charge balance for all species = 0.8516E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1484398E-09 -.9395636E-02 -.9464041E+01 0.0000 2 H2O 0.1000000E+01 0.5550978E+02 0.9993712E+06 0.0000 3 Cl- 0.1379203E-03 0.1382292E-03 0.4897436E+01 5.9667 4 SO4-- 0.2553418E-04 0.2555304E-04 0.2453060E+01 14.9718 5 HCO3- 0.6554503E-05 0.1309416E-04 0.7984464E+00 4.6440 6 HS- 0.6653191E-12 -.1419537E-08 -.4691623E-04 -2.3498 7 Al+++ 0.7251605E-27 0.5815487E-04 0.1568079E+01 2.0605 8 H4SiO4 0.4081332E-03 0.4277174E-02 0.4108334E+03 -3.3892 9 Ca++ 0.4309723E-07 0.6319775E-07 0.2531182E-02 12.1975 10 Mg++ 0.1865559E-10 0.5947510E-10 0.1445013E-05 8.8329 11 Fe++ 0.1102841E-12 0.2962985E-07 0.1653656E-02 6.6048 12 K+ 0.7044067E-04 0.7066451E-04 0.2761316E+01 5.6753 13 Na+ 0.8946972E-02 0.9353651E-02 0.2148979E+03 7.7787 14 Mn++ 0.1473091E-10 0.8681812E-09 0.4766494E-04 8.7307 15 HPO4-- 0.4458412E-06 0.4517390E-06 0.4332910E-01 13.2139 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1986726E+00 -.9378298E-02 -.1892943E+00 0.0000000E+00 2 H2O 0.5535784E+02 0.5540735E+02 -.4951684E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3580377E-03 0.2550589E-04 0.3325318E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3325332E-03 -.1416918E-08 -.3325318E-03 0.0000000E+00 7 Al+++ 0.3912564E-01 0.5804756E-04 0.3906759E-01 0.0000000E+00 8 H4SiO4 0.1249430E+00 0.4269282E-02 0.1206737E+00 0.0000000E+00 9 Ca++ 0.1381503E-01 0.6308113E-07 0.1381497E-01 0.0000000E+00 10 Mg++ 0.9523016E-02 0.5936535E-10 0.9523016E-02 0.0000000E+00 11 Fe++ 0.8555390E-02 0.2957518E-07 0.8555361E-02 0.0000000E+00 12 K+ 0.2547558E-02 0.7053412E-04 0.2477024E-02 0.0000000E+00 13 Na+ 0.1522174E-01 0.9336391E-02 0.5885349E-02 0.0000000E+00 14 Mn++ 0.2080458E-03 0.8665792E-09 0.2080449E-03 0.0000000E+00 15 HPO4-- 0.7100500E-04 0.4509055E-06 0.7055410E-04 0.0000000E+00 Chg. balance for solid moles: -.2711E-17 Mass of aqueous solution: 0.998808E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 11.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5885E-02 -2.230 1.543 0.188 11.78 0.5924 andradite 0.2966E-03 -3.528 0.1507 -0.822 1.150 0.3915E-01 grossular 0.2310E-04 -4.636 0.1040E-01 -1.983 0.7940E-01 0.2895E-02 apatite-OH 0.2352E-04 -4.629 0.1181E-01 -1.928 0.9015E-01 0.3754E-02 clinochlore 0.1905E-02 -2.720 1.059 0.025 8.079 0.4027 daphnite 0.1179E-02 -2.928 0.8412 -0.075 6.420 0.2549 chlorite-Mn 0.4161E-04 -4.381 0.2950E-01 -1.530 0.2251 0.9401E-02 hematite 0.8555E-03 -3.068 0.1366 -0.864 1.043 0.2590E-01 microcline 0.2477E-02 -2.606 0.6895 -0.161 5.261 0.2693 prehnite-Fe 0.3561E-03 -3.448 0.1571 -0.804 1.199 0.5271E-01 stilbite 0.1203E-01 -1.920 8.475 0.928 64.68 3.953 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9277E+00 0.9277E+00 1.0000 -0.033 grossular 0.7226E-01 0.7226E-01 1.0000 -1.141 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 13.103890 g Volume = 5.606097 cm3 Porosity: 3.3365% V(tot) - V(min): 0.19350E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 11.9990000 g log = 1.0791 Original solution: 1000.0103000 g Original solution / Rock added: 83.34 (Water/Rock Ratio), log = 1.9209 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1631E-06 1.0073 0.1728E-06 0.1715E-06 CH4,gas 0.3059E-15 1.0129 0.3259E-15 0.3217E-15 H2,gas 0.2008E-05 1.0006 0.2114E-05 0.2113E-05 H2S,gas 0.6352E-14 0.9959 0.6654E-14 0.6682E-14 S2,gas 0.3528E-36 1.0000 0.3712E-36 0.3712E-36 CO,gas 0.8993E-16 1.0000 0.9460E-16 0.9460E-16 SO3,gas 0.9620E-40 1.0000 0.1012E-39 0.1012E-39 SO2,gas 0.7693E-23 1.0000 0.8092E-23 0.8092E-23 HCl,gas 0.4970E-17 1.0000 0.5228E-17 0.5228E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.18198E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.18957E-10 137 prehnite-Fe 22.59 22.59 0.00 0.000 -0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.13 -8.76 -2.921 0.14962E+05 -6.763 3 CH4,gas 4.81 -12.68 -17.49 -4.372 0.29858E+05 -15.487 4 H2,gas 8.29 0.61 -7.67 -4.386 0.13105E+05 -5.675 5 H2S,gas -5.94 -22.12 -16.18 -8.088 0.27622E+05 -14.177 6 S2,gas -7.03 -45.46 -38.43 -5.912 0.65619E+05 -36.430 7 CO,gas 3.51 -14.51 -18.02 -5.546 0.30776E+05 -16.024 8 SO3,gas 17.43 -24.57 -41.99 -10.499 0.71705E+05 -39.995 9 SO2,gas 1.14 -23.96 -25.09 -6.691 0.42844E+05 -23.092 10 HCl,gas 5.48 -13.80 -19.28 -9.641 0.32923E+05 -17.282 11 acmite 7.74 7.30 -0.44 -0.046 0.74830E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.15 -4.40 -0.220 0.75203E+04 20 analcite 3.37 3.06 -0.31 -0.034 0.52898E+03 21 andalusite 5.06 0.73 -4.33 -0.433 0.73943E+04 26 annite 20.21 17.38 -2.83 -0.157 0.48265E+04 27 phlogopite 27.15 24.07 -3.08 -0.171 0.52587E+04 29 anorthite 12.80 9.54 -3.26 -0.251 0.55622E+04 35 aragonite 0.99 -2.93 -3.91 -1.305 0.66838E+04 36 brucite 12.58 8.83 -3.74 -0.749 0.63923E+04 37 calcite 0.83 -2.93 -3.76 -1.254 0.64225E+04 38 carnegieite-low 9.06 6.45 -2.61 -0.374 0.44642E+04 39 carnegieite-high 10.13 6.45 -3.68 -0.526 0.62911E+04 40 carpholite-Mg 8.65 6.18 -2.47 -0.165 0.42258E+04 41 carpholite-Fe 6.78 3.95 -2.84 -0.189 0.48415E+04 42 celadonite 5.40 3.01 -2.39 -0.141 0.40785E+04 43 celadonite-Fe 3.94 0.78 -3.15 -0.185 0.53839E+04 44 chrysotile 23.94 19.72 -4.22 -0.351 0.72007E+04 50 chloritoid-Mg 13.26 9.56 -3.70 -0.246 0.63118E+04 51 chloritoid-Fe 9.24 7.34 -1.90 -0.127 0.32477E+04 52 chloritoid-Mn 11.46 9.46 -2.00 -0.133 0.34161E+04 54 coesite -2.37 -3.39 -1.02 -0.340 0.17414E+04 59 corundum 8.43 4.12 -4.31 -0.392 0.73633E+04 61 cristobalite -2.55 -3.39 -0.84 -0.280 0.14342E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.06 -0.84 -0.139 0.14267E+04 67 diopside 16.22 14.25 -1.96 -0.196 0.33526E+04 68 hedenbergite 14.24 12.02 -2.22 -0.222 0.37914E+04 75 epidote 24.78 24.65 -0.13 -0.006 0.21845E+03 76 clinozoisite 22.92 20.41 -2.51 -0.114 0.42895E+04 77 epidote-Fe 29.94 28.89 -1.05 -0.055 0.17949E+04 78 fayalite 14.08 9.82 -4.26 -0.608 0.72714E+04 79 ferrosilite 11.19 6.43 -4.76 -0.476 0.81216E+04 83 gibbsite 4.10 2.06 -2.04 -0.291 0.34779E+04 84 glaucophane 23.11 19.06 -4.05 -0.109 0.69103E+04 87 greenalite 16.19 13.04 -3.16 -0.263 0.53925E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.06 -1.19 -0.119 0.20320E+04 96 julgoldite 70.57 66.86 -3.71 -0.096 0.63400E+04 97 kalsilite 7.62 4.35 -3.27 -0.468 0.55897E+04 98 kaolinite -1.27 -2.66 -1.38 -0.126 0.23636E+04 99 kyanite 4.93 0.73 -4.20 -0.420 0.71711E+04 101 laumontite 2.97 2.76 -0.21 -0.014 0.36336E+03 102 lawsonite 9.68 9.54 -0.14 -0.009 0.23604E+03 103 leucite 4.17 0.96 -3.21 -0.321 0.54814E+04 105 lizardite 23.29 19.72 -3.57 -0.297 0.60910E+04 107 magnetite 20.13 19.20 -0.93 -0.076 0.15886E+04 108 minnesotaite 10.46 6.26 -4.20 -0.247 0.71767E+04 110 magnesioferrite 26.26 21.43 -4.83 -0.394 0.82416E+04 113 margarite 17.45 13.66 -3.79 -0.152 0.64724E+04 120 muscovite 2.68 1.69 -0.99 -0.058 0.16904E+04 121 paragonite 4.34 3.79 -0.54 -0.032 0.92884E+03 122 nepheline 8.38 6.45 -1.93 -0.275 0.32922E+04 134 phlogopite-Na 29.73 26.17 -3.56 -0.198 0.60806E+04 136 prehnite 19.47 18.35 -1.12 -0.066 0.19087E+04 138 pumpellyite-Fe 46.47 45.36 -1.11 -0.025 0.18924E+04 139 pumpellyite-Mg 49.19 47.59 -1.60 -0.036 0.27384E+04 145 pyroxmangite 7.42 5.34 -2.07 -0.415 0.35422E+04 146 pyrophyllite -6.10 -9.44 -3.34 -0.209 0.56991E+04 147 quartz -2.98 -3.39 -0.41 -0.136 0.69528E+03 152 rhodonite 7.46 5.34 -2.12 -0.424 0.36214E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.73 -4.59 -0.459 0.78365E+04 164 stilpnomelane-Fe 13.18 12.87 -0.31 -0.009 0.52977E+03 165 stilpnomelane-Mg 27.60 24.01 -3.59 -0.107 0.61246E+04 171 talc 16.55 12.94 -3.61 -0.212 0.61667E+04 174 tephroite 18.11 14.07 -4.04 -0.577 0.68994E+04 177 topaz-H 4.67 0.73 -3.94 -0.358 0.67202E+04 178 tridymite -2.61 -3.39 -0.77 -0.258 0.13226E+04 187 wairakite 4.06 2.76 -1.30 -0.076 0.22142E+04 188 walstromite 11.53 8.81 -2.72 -0.544 0.46435E+04 189 wollastonite 10.48 8.81 -1.67 -0.335 0.28574E+04 190 pseudo-wollastonite 11.02 8.81 -2.21 -0.442 0.37761E+04 191 zoisite 22.96 20.41 -2.55 -0.116 0.43620E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.62 -4.07 -0.251 0.69411E+04 195 beidellite-K -1.44 -5.76 -4.33 -0.265 0.73925E+04 196 beidellite-Mg -1.71 -6.18 -4.47 -0.277 0.76376E+04 197 beidellite-Na -1.26 -5.07 -3.81 -0.234 0.65112E+04 199 chalcedony -2.79 -3.39 -0.59 -0.198 0.10156E+04 201 montmorillonite-Ca -2.21 -5.19 -2.97 -0.184 0.50785E+04 202 montmorillonite-K -2.16 -5.33 -3.17 -0.194 0.54077E+04 203 montmorillonite-Mg -2.40 -5.74 -3.34 -0.207 0.57061E+04 204 montmorillonite-Na -1.96 -4.63 -2.67 -0.164 0.45646E+04 205 nontronite-Ca 3.28 2.85 -0.43 -0.028 0.73052E+03 206 nontronite-H 2.60 0.84 -1.76 -0.118 0.29992E+04 207 nontronite-K 3.40 2.71 -0.69 -0.044 0.11811E+04 208 nontronite-Mg 3.14 2.30 -0.84 -0.055 0.14387E+04 209 nontronite-Na 3.58 3.41 -0.18 -0.011 0.30156E+03 224 tobermorite 9.84 6.77 -3.07 -0.837 0.52380E+04 233 boehmite 4.43 2.06 -2.37 -0.395 0.40452E+04 235 ferrous-oxide 9.82 6.60 -3.22 -0.805 0.54971E+04 240 silica-amorphous -2.08 -3.39 -1.31 -0.436 0.22358E+04 242 an20ab80 2.08 1.65 -0.43 -0.033 0.74082E+03 243 an25ab75 2.71 2.14 -0.57 -0.044 0.97393E+03 244 an30ab70 3.34 2.63 -0.71 -0.055 0.12154E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 11.9990000 g New total amount of reactant added: 12.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8628E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 12.3990000 Water: Moles liquid = 0.5540E+02 kg liquid = 0.9981E+00 Moles total = 0.5535E+02 kg total = 0.9972E+00 Activity = 1.0000 Stoichiometric ionic strength = .5101579E-02 Osmotic coef. = 0.9621 True ionic strength = .9050099E-02 Chg. balance for total moles = 0.8628E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14844E-09 -9.8284 0.13036E-09 -9.8848 0.87822E+00 -0.0564 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8604 0.12075E-03 -3.9181 0.87547E+00 -0.0578 4 SO4-- 0.25535E-04 -4.5929 0.15928E-04 -4.7978 0.62377E+00 -0.2050 5 HCO3- 0.65548E-05 -5.1834 0.57428E-05 -5.2409 0.87613E+00 -0.0574 6 HS- 0.66535E-12 -12.1770 0.58254E-12 -12.2347 0.87554E+00 -0.0577 7 Al+++ 0.72516E-27 -27.1396 0.25466E-27 -27.5940 0.35118E+00 -0.4545 8 H4SiO4 0.40813E-03 -3.3892 0.40813E-03 -3.3892 0.10000E+01 0.0000 9 Ca++ 0.43097E-07 -7.3656 0.26781E-07 -7.5722 0.62141E+00 -0.2066 10 Mg++ 0.18656E-10 -10.7292 0.11565E-10 -10.9368 0.61994E+00 -0.2077 11 Fe++ 0.11028E-12 -12.9575 0.68408E-13 -13.1649 0.62029E+00 -0.2074 12 K+ 0.70441E-04 -4.1522 0.61723E-04 -4.2096 0.87624E+00 -0.0574 13 Na+ 0.89470E-02 -2.0483 0.78322E-02 -2.1061 0.87540E+00 -0.0578 14 Mn++ 0.14731E-10 -10.8318 0.91413E-11 -11.0390 0.62056E+00 -0.2072 15 HPO4-- 0.44584E-06 -6.3508 0.27812E-06 -6.5558 0.62381E+00 -0.2049 16 HSiO3- 0.34891E-02 -2.4573 0.30546E-02 -2.5150 0.87547E+00 -0.0578 17 Ca(HSiO3)+ 0.20915E-08 -8.6795 0.18329E-08 -8.7369 0.87634E+00 -0.0573 18 Mg(HSiO3)+ 0.11240E-11 -11.9492 0.98505E-12 -12.0065 0.87634E+00 -0.0573 19 NaHSiO3,aq 0.37997E-03 -3.4203 0.37997E-03 -3.4203 0.10000E+01 0.0000 20 AlO+ 0.22075E-14 -14.6561 0.19345E-14 -14.7134 0.87634E+00 -0.0573 22 HAlO2,aq 0.29695E-08 -8.5273 0.29695E-08 -8.5273 0.10000E+01 0.0000 23 AlO2- 0.58152E-04 -4.2354 0.50862E-04 -4.2936 0.87465E+00 -0.0582 24 CH4,aq 0.20642E-18 -18.6852 0.20610E-18 -18.6859 0.99843E+00 -0.0007 29 CO,aq 0.59917E-19 -19.2225 0.59917E-19 -19.2225 0.10000E+01 0.0000 30 CO2,aq 0.15118E-08 -8.8205 0.15094E-08 -8.8212 0.99843E+00 -0.0007 31 CO3-2 0.65371E-05 -5.1846 0.40731E-05 -5.3901 0.62308E+00 -0.2055 32 CaCO3,aq 0.13360E-08 -8.8742 0.13360E-08 -8.8742 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44221E-11 -11.3544 0.38753E-11 -11.4117 0.87634E+00 -0.0573 34 CaCl+ 0.58802E-11 -11.2306 0.51531E-11 -11.2879 0.87634E+00 -0.0573 35 CaCl2,aq 0.14488E-15 -15.8390 0.14488E-15 -15.8390 0.10000E+01 0.0000 36 CaOH+ 0.16530E-07 -7.7817 0.14486E-07 -7.8391 0.87634E+00 -0.0573 37 CaSO4,aq 0.13291E-09 -9.8764 0.13291E-09 -9.8764 0.10000E+01 0.0000 38 HCl,aq 0.29609E-14 -14.5286 0.29609E-14 -14.5286 0.10000E+01 0.0000 43 FeCl+ 0.14681E-16 -16.8332 0.12866E-16 -16.8906 0.87634E+00 -0.0573 46 FeO,aq 0.15918E-09 -9.7981 0.15918E-09 -9.7981 0.10000E+01 0.0000 47 FeOH+ 0.19852E-10 -10.7022 0.17397E-10 -10.7595 0.87634E+00 -0.0573 48 HFeO2- 0.15002E-07 -7.8239 0.13134E-07 -7.8816 0.87547E+00 -0.0578 49 FeO+ 0.12305E-14 -14.9099 0.10784E-14 -14.9672 0.87634E+00 -0.0573 51 FeO2- 0.14245E-07 -7.8463 0.12471E-07 -7.9041 0.87547E+00 -0.0578 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.15437E-08 -8.8115 0.15412E-08 -8.8121 0.99843E+00 -0.0007 54 KCl,aq 0.13197E-09 -9.8795 0.13197E-09 -9.8795 0.10000E+01 0.0000 55 KHSO4,aq 0.34296E-18 -18.4648 0.34296E-18 -18.4648 0.10000E+01 0.0000 56 KOH,aq 0.20641E-06 -6.6853 0.20641E-06 -6.6853 0.10000E+01 0.0000 57 KSO4- 0.17301E-07 -7.7619 0.15146E-07 -7.8197 0.87547E+00 -0.0578 58 MgCO3,aq 0.14417E-12 -12.8411 0.14417E-12 -12.8411 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19474E-14 -14.7106 0.17066E-14 -14.7679 0.87634E+00 -0.0573 60 MgCl+ 0.23053E-14 -14.6373 0.20202E-14 -14.6946 0.87634E+00 -0.0573 61 MgOH+ 0.39547E-10 -10.4029 0.34657E-10 -10.4602 0.87634E+00 -0.0573 63 MnO,aq 0.56783E-09 -9.2458 0.56783E-09 -9.2458 0.10000E+01 0.0000 64 MnOH+ 0.24643E-09 -9.6083 0.21596E-09 -9.6656 0.87634E+00 -0.0573 65 MnO2-2 0.18546E-11 -11.7318 0.11555E-11 -11.9372 0.62308E+00 -0.2055 66 HMnO2- 0.37280E-10 -10.4285 0.32638E-10 -10.4863 0.87547E+00 -0.0578 69 MnCl+ 0.76233E-14 -14.1179 0.66806E-14 -14.1752 0.87634E+00 -0.0573 70 MnSO4,aq 0.41264E-13 -13.3844 0.41264E-13 -13.3844 0.10000E+01 0.0000 71 NaCl,aq 0.30881E-06 -6.5103 0.30881E-06 -6.5103 0.10000E+01 0.0000 72 NaOH,aq 0.26400E-04 -4.5784 0.26400E-04 -4.5784 0.10000E+01 0.0000 74 OH- 0.52607E-02 -2.2790 0.46013E-02 -2.3371 0.87465E+00 -0.0582 79 HPO3-2 0.21729E-17 -17.6630 0.13539E-17 -17.8684 0.62308E+00 -0.2055 82 H3PO4,aq 0.30429E-16 -16.5167 0.30429E-16 -16.5167 0.10000E+01 0.0000 83 H2PO4- 0.72571E-09 -9.1392 0.63565E-09 -9.1968 0.87590E+00 -0.0575 84 PO4-3 0.51721E-08 -8.2863 0.18632E-08 -8.7297 0.36023E+00 -0.4434 87 H2P2O7-2 0.50753E-19 -19.2945 0.31623E-19 -19.5000 0.62308E+00 -0.2055 88 HP2O7-3 0.14158E-15 -15.8490 0.49742E-16 -16.3033 0.35132E+00 -0.4543 89 P2O7-4 0.58805E-15 -15.2306 0.94131E-16 -16.0263 0.16007E+00 -0.7957 90 H2S,aq 0.22853E-15 -15.6411 0.22817E-15 -15.6417 0.99843E+00 -0.0007 97 SO3-2 0.53320E-14 -14.2731 0.33472E-14 -14.4753 0.62776E+00 -0.2022 98 HSO3- 0.29168E-16 -16.5351 0.25536E-16 -16.5928 0.87547E+00 -0.0578 99 HSO4- 0.21974E-11 -11.6581 0.19266E-11 -11.7152 0.87677E+00 -0.0571 Charge balance for all species = 0.8529E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1484399E-09 -.9395632E-02 -.9464038E+01 0.0000 2 H2O 0.1000000E+01 0.5550978E+02 0.9993712E+06 0.0000 3 Cl- 0.1379261E-03 0.1382351E-03 0.4897642E+01 5.9667 4 SO4-- 0.2553526E-04 0.2555412E-04 0.2453163E+01 14.9719 5 HCO3- 0.6554780E-05 0.1309471E-04 0.7984801E+00 4.6440 6 HS- 0.6653477E-12 -.1419537E-08 -.4691620E-04 -2.3498 7 Al+++ 0.7251618E-27 0.5815485E-04 0.1568078E+01 2.0605 8 H4SiO4 0.4081332E-03 0.4277173E-02 0.4108332E+03 -3.3892 9 Ca++ 0.4309728E-07 0.6319787E-07 0.2531187E-02 12.1975 10 Mg++ 0.1865561E-10 0.5947514E-10 0.1445014E-05 8.8329 11 Fe++ 0.1102843E-12 0.2962984E-07 0.1653655E-02 6.6048 12 K+ 0.7044071E-04 0.7066455E-04 0.2761318E+01 5.6753 13 Na+ 0.8946976E-02 0.9353655E-02 0.2148980E+03 7.7787 14 Mn++ 0.1473092E-10 0.8681815E-09 0.4766495E-04 8.7307 15 HPO4-- 0.4458409E-06 0.4517387E-06 0.4332906E-01 13.2139 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2052960E+00 -.9377899E-02 -.1959181E+00 0.0000000E+00 2 H2O 0.5535282E+02 0.5540502E+02 -.5219425E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3691230E-03 0.2550589E-04 0.3436171E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3436186E-03 -.1416857E-08 -.3436171E-03 0.0000000E+00 7 Al+++ 0.4042994E-01 0.5804509E-04 0.4037189E-01 0.0000000E+00 8 H4SiO4 0.1291081E+00 0.4269100E-02 0.1248390E+00 0.0000000E+00 9 Ca++ 0.1427509E-01 0.6307860E-07 0.1427503E-01 0.0000000E+00 10 Mg++ 0.9840476E-02 0.5936289E-10 0.9840476E-02 0.0000000E+00 11 Fe++ 0.8840594E-02 0.2957392E-07 0.8840564E-02 0.0000000E+00 12 K+ 0.2632484E-02 0.7053118E-04 0.2561953E-02 0.0000000E+00 13 Na+ 0.1572384E-01 0.9336002E-02 0.6387835E-02 0.0000000E+00 14 Mn++ 0.2149813E-03 0.8665429E-09 0.2149804E-03 0.0000000E+00 15 HPO4-- 0.7337203E-04 0.4508861E-06 0.7292115E-04 0.0000000E+00 Chg. balance for solid moles: 0.4564E-16 Mass of aqueous solution: 0.998766E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 12.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6388E-02 -2.195 1.675 0.224 12.37 0.6430 andradite 0.3976E-03 -3.401 0.2021 -0.695 1.492 0.5250E-01 grossular 0.3097E-04 -4.509 0.1395E-01 -1.855 0.1030 0.3881E-02 apatite-OH 0.2431E-04 -4.614 0.1221E-01 -1.913 0.9016E-01 0.3880E-02 clinochlore 0.1968E-02 -2.706 1.094 0.039 8.078 0.4161 daphnite 0.1218E-02 -2.914 0.8693 -0.061 6.419 0.2634 chlorite-Mn 0.4300E-04 -4.367 0.3048E-01 -1.516 0.2251 0.9714E-02 hematite 0.8378E-03 -3.077 0.1338 -0.874 0.9880 0.2536E-01 microcline 0.2562E-02 -2.591 0.7131 -0.147 5.265 0.2786 prehnite-Fe 0.2781E-03 -3.556 0.1227 -0.911 0.9059 0.4116E-01 stilbite 0.1231E-01 -1.910 8.676 0.938 64.07 4.047 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9277E+00 0.9277E+00 1.0000 -0.033 grossular 0.7226E-01 0.7226E-01 1.0000 -1.141 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 13.542776 g Volume = 5.784325 cm3 Porosity: 2.9410% V(tot) - V(min): 0.17527E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 12.3990000 g log = 1.0934 Original solution: 1000.0103000 g Original solution / Rock added: 80.65 (Water/Rock Ratio), log = 1.9066 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1631E-06 1.0073 0.1728E-06 0.1715E-06 CH4,gas 0.3059E-15 1.0129 0.3259E-15 0.3218E-15 H2,gas 0.2008E-05 1.0006 0.2114E-05 0.2113E-05 H2S,gas 0.6352E-14 0.9959 0.6655E-14 0.6682E-14 S2,gas 0.3529E-36 1.0000 0.3712E-36 0.3712E-36 CO,gas 0.8994E-16 1.0000 0.9461E-16 0.9461E-16 SO3,gas 0.9620E-40 1.0000 0.1012E-39 0.1012E-39 SO2,gas 0.7693E-23 1.0000 0.8093E-23 0.8093E-23 HCl,gas 0.4970E-17 1.0000 0.5228E-17 0.5228E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.48529E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.48529E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 137 prehnite-Fe 22.59 22.59 0.00 0.000 -0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.13 -8.76 -2.921 0.14962E+05 -6.763 3 CH4,gas 4.81 -12.68 -17.49 -4.372 0.29858E+05 -15.487 4 H2,gas 8.29 0.61 -7.67 -4.386 0.13105E+05 -5.675 5 H2S,gas -5.94 -22.12 -16.18 -8.088 0.27622E+05 -14.177 6 S2,gas -7.03 -45.46 -38.43 -5.912 0.65619E+05 -36.430 7 CO,gas 3.51 -14.51 -18.02 -5.546 0.30776E+05 -16.024 8 SO3,gas 17.43 -24.57 -41.99 -10.499 0.71705E+05 -39.995 9 SO2,gas 1.14 -23.96 -25.09 -6.691 0.42844E+05 -23.092 10 HCl,gas 5.48 -13.80 -19.28 -9.641 0.32923E+05 -17.282 11 acmite 7.74 7.30 -0.44 -0.046 0.74830E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.15 -4.40 -0.220 0.75203E+04 20 analcite 3.37 3.06 -0.31 -0.034 0.52898E+03 21 andalusite 5.06 0.73 -4.33 -0.433 0.73943E+04 26 annite 20.21 17.38 -2.83 -0.157 0.48265E+04 27 phlogopite 27.15 24.07 -3.08 -0.171 0.52587E+04 29 anorthite 12.80 9.54 -3.26 -0.251 0.55622E+04 35 aragonite 0.99 -2.93 -3.91 -1.305 0.66838E+04 36 brucite 12.58 8.83 -3.74 -0.749 0.63923E+04 37 calcite 0.83 -2.93 -3.76 -1.254 0.64224E+04 38 carnegieite-low 9.06 6.45 -2.61 -0.374 0.44642E+04 39 carnegieite-high 10.13 6.45 -3.68 -0.526 0.62911E+04 40 carpholite-Mg 8.65 6.18 -2.47 -0.165 0.42258E+04 41 carpholite-Fe 6.78 3.95 -2.84 -0.189 0.48415E+04 42 celadonite 5.40 3.01 -2.39 -0.141 0.40785E+04 43 celadonite-Fe 3.94 0.78 -3.15 -0.185 0.53839E+04 44 chrysotile 23.94 19.72 -4.22 -0.351 0.72007E+04 50 chloritoid-Mg 13.26 9.56 -3.70 -0.246 0.63118E+04 51 chloritoid-Fe 9.24 7.34 -1.90 -0.127 0.32477E+04 52 chloritoid-Mn 11.46 9.46 -2.00 -0.133 0.34161E+04 54 coesite -2.37 -3.39 -1.02 -0.340 0.17414E+04 59 corundum 8.43 4.12 -4.31 -0.392 0.73633E+04 61 cristobalite -2.55 -3.39 -0.84 -0.280 0.14342E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.06 -0.84 -0.139 0.14267E+04 67 diopside 16.22 14.25 -1.96 -0.196 0.33526E+04 68 hedenbergite 14.24 12.02 -2.22 -0.222 0.37914E+04 75 epidote 24.78 24.65 -0.13 -0.006 0.21845E+03 76 clinozoisite 22.92 20.41 -2.51 -0.114 0.42895E+04 77 epidote-Fe 29.94 28.89 -1.05 -0.055 0.17949E+04 78 fayalite 14.08 9.82 -4.26 -0.608 0.72714E+04 79 ferrosilite 11.19 6.43 -4.76 -0.476 0.81216E+04 83 gibbsite 4.10 2.06 -2.04 -0.291 0.34779E+04 84 glaucophane 23.11 19.06 -4.05 -0.109 0.69103E+04 87 greenalite 16.19 13.04 -3.16 -0.263 0.53925E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.06 -1.19 -0.119 0.20320E+04 96 julgoldite 70.57 66.86 -3.71 -0.096 0.63400E+04 97 kalsilite 7.62 4.35 -3.27 -0.468 0.55897E+04 98 kaolinite -1.27 -2.66 -1.38 -0.126 0.23636E+04 99 kyanite 4.93 0.73 -4.20 -0.420 0.71711E+04 101 laumontite 2.97 2.76 -0.21 -0.014 0.36336E+03 102 lawsonite 9.68 9.54 -0.14 -0.009 0.23604E+03 103 leucite 4.17 0.96 -3.21 -0.321 0.54814E+04 105 lizardite 23.29 19.72 -3.57 -0.297 0.60910E+04 107 magnetite 20.13 19.20 -0.93 -0.076 0.15886E+04 108 minnesotaite 10.46 6.26 -4.20 -0.247 0.71767E+04 110 magnesioferrite 26.26 21.43 -4.83 -0.394 0.82416E+04 113 margarite 17.45 13.66 -3.79 -0.152 0.64724E+04 120 muscovite 2.68 1.69 -0.99 -0.058 0.16904E+04 121 paragonite 4.34 3.79 -0.54 -0.032 0.92884E+03 122 nepheline 8.38 6.45 -1.93 -0.275 0.32922E+04 134 phlogopite-Na 29.73 26.17 -3.56 -0.198 0.60806E+04 136 prehnite 19.47 18.35 -1.12 -0.066 0.19087E+04 138 pumpellyite-Fe 46.47 45.36 -1.11 -0.025 0.18924E+04 139 pumpellyite-Mg 49.19 47.59 -1.60 -0.036 0.27384E+04 145 pyroxmangite 7.42 5.34 -2.07 -0.415 0.35422E+04 146 pyrophyllite -6.10 -9.44 -3.34 -0.209 0.56991E+04 147 quartz -2.98 -3.39 -0.41 -0.136 0.69528E+03 152 rhodonite 7.46 5.34 -2.12 -0.424 0.36214E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.73 -4.59 -0.459 0.78365E+04 164 stilpnomelane-Fe 13.18 12.87 -0.31 -0.009 0.52977E+03 165 stilpnomelane-Mg 27.60 24.01 -3.59 -0.107 0.61246E+04 171 talc 16.55 12.94 -3.61 -0.212 0.61667E+04 174 tephroite 18.11 14.07 -4.04 -0.577 0.68994E+04 177 topaz-H 4.67 0.73 -3.94 -0.358 0.67202E+04 178 tridymite -2.61 -3.39 -0.77 -0.258 0.13226E+04 187 wairakite 4.06 2.76 -1.30 -0.076 0.22142E+04 188 walstromite 11.53 8.81 -2.72 -0.544 0.46435E+04 189 wollastonite 10.48 8.81 -1.67 -0.335 0.28574E+04 190 pseudo-wollastonite 11.02 8.81 -2.21 -0.442 0.37761E+04 191 zoisite 22.96 20.41 -2.55 -0.116 0.43620E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.62 -4.07 -0.251 0.69411E+04 195 beidellite-K -1.44 -5.76 -4.33 -0.265 0.73925E+04 196 beidellite-Mg -1.71 -6.18 -4.47 -0.277 0.76376E+04 197 beidellite-Na -1.26 -5.07 -3.81 -0.234 0.65112E+04 199 chalcedony -2.79 -3.39 -0.59 -0.198 0.10156E+04 201 montmorillonite-Ca -2.21 -5.19 -2.97 -0.184 0.50785E+04 202 montmorillonite-K -2.16 -5.33 -3.17 -0.194 0.54077E+04 203 montmorillonite-Mg -2.40 -5.74 -3.34 -0.207 0.57061E+04 204 montmorillonite-Na -1.96 -4.63 -2.67 -0.164 0.45646E+04 205 nontronite-Ca 3.28 2.85 -0.43 -0.028 0.73052E+03 206 nontronite-H 2.60 0.84 -1.76 -0.118 0.29992E+04 207 nontronite-K 3.40 2.71 -0.69 -0.044 0.11811E+04 208 nontronite-Mg 3.14 2.30 -0.84 -0.055 0.14387E+04 209 nontronite-Na 3.58 3.41 -0.18 -0.011 0.30156E+03 224 tobermorite 9.84 6.77 -3.07 -0.837 0.52380E+04 233 boehmite 4.43 2.06 -2.37 -0.395 0.40452E+04 235 ferrous-oxide 9.82 6.60 -3.22 -0.805 0.54971E+04 240 silica-amorphous -2.08 -3.39 -1.31 -0.436 0.22358E+04 242 an20ab80 2.08 1.65 -0.43 -0.033 0.74082E+03 243 an25ab75 2.71 2.14 -0.57 -0.044 0.97393E+03 244 an30ab70 3.34 2.63 -0.71 -0.055 0.12154E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 12.3990000 g New total amount of reactant added: 12.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8626E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 12.7990000 Water: Moles liquid = 0.5540E+02 kg liquid = 0.9981E+00 Moles total = 0.5535E+02 kg total = 0.9971E+00 Activity = 1.0000 Stoichiometric ionic strength = .5101587E-02 Osmotic coef. = 0.9621 True ionic strength = .9050105E-02 Chg. balance for total moles = 0.8626E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14844E-09 -9.8284 0.13036E-09 -9.8848 0.87822E+00 -0.0564 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13793E-03 -3.8603 0.12076E-03 -3.9181 0.87547E+00 -0.0578 4 SO4-- 0.25536E-04 -4.5928 0.15929E-04 -4.7978 0.62377E+00 -0.2050 5 HCO3- 0.65551E-05 -5.1834 0.57431E-05 -5.2409 0.87613E+00 -0.0574 6 HS- 0.66538E-12 -12.1769 0.58256E-12 -12.2347 0.87554E+00 -0.0577 7 Al+++ 0.72516E-27 -27.1396 0.25466E-27 -27.5940 0.35118E+00 -0.4545 8 H4SiO4 0.40813E-03 -3.3892 0.40813E-03 -3.3892 0.10000E+01 0.0000 9 Ca++ 0.43097E-07 -7.3655 0.26781E-07 -7.5722 0.62141E+00 -0.2066 10 Mg++ 0.18656E-10 -10.7292 0.11565E-10 -10.9368 0.61994E+00 -0.2077 11 Fe++ 0.11028E-12 -12.9575 0.68408E-13 -13.1649 0.62029E+00 -0.2074 12 K+ 0.70441E-04 -4.1522 0.61723E-04 -4.2096 0.87624E+00 -0.0574 13 Na+ 0.89470E-02 -2.0483 0.78322E-02 -2.1061 0.87540E+00 -0.0578 14 Mn++ 0.14731E-10 -10.8318 0.91414E-11 -11.0390 0.62055E+00 -0.2072 15 HPO4-- 0.44584E-06 -6.3508 0.27812E-06 -6.5558 0.62381E+00 -0.2049 16 HSiO3- 0.34891E-02 -2.4573 0.30546E-02 -2.5150 0.87547E+00 -0.0578 17 Ca(HSiO3)+ 0.20915E-08 -8.6795 0.18329E-08 -8.7369 0.87634E+00 -0.0573 18 Mg(HSiO3)+ 0.11240E-11 -11.9492 0.98505E-12 -12.0065 0.87634E+00 -0.0573 19 NaHSiO3,aq 0.37997E-03 -3.4203 0.37997E-03 -3.4203 0.10000E+01 0.0000 20 AlO+ 0.22075E-14 -14.6561 0.19345E-14 -14.7134 0.87634E+00 -0.0573 22 HAlO2,aq 0.29695E-08 -8.5273 0.29695E-08 -8.5273 0.10000E+01 0.0000 23 AlO2- 0.58152E-04 -4.2354 0.50862E-04 -4.2936 0.87465E+00 -0.0582 24 CH4,aq 0.20643E-18 -18.6852 0.20611E-18 -18.6859 0.99843E+00 -0.0007 29 CO,aq 0.59919E-19 -19.2224 0.59919E-19 -19.2224 0.10000E+01 0.0000 30 CO2,aq 0.15119E-08 -8.8205 0.15095E-08 -8.8212 0.99843E+00 -0.0007 31 CO3-2 0.65374E-05 -5.1846 0.40733E-05 -5.3901 0.62308E+00 -0.2055 32 CaCO3,aq 0.13361E-08 -8.8742 0.13361E-08 -8.8742 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44223E-11 -11.3543 0.38755E-11 -11.4117 0.87634E+00 -0.0573 34 CaCl+ 0.58805E-11 -11.2306 0.51533E-11 -11.2879 0.87634E+00 -0.0573 35 CaCl2,aq 0.14489E-15 -15.8390 0.14489E-15 -15.8390 0.10000E+01 0.0000 36 CaOH+ 0.16530E-07 -7.7817 0.14486E-07 -7.8391 0.87634E+00 -0.0573 37 CaSO4,aq 0.13292E-09 -9.8764 0.13292E-09 -9.8764 0.10000E+01 0.0000 38 HCl,aq 0.29610E-14 -14.5286 0.29610E-14 -14.5286 0.10000E+01 0.0000 43 FeCl+ 0.14682E-16 -16.8332 0.12866E-16 -16.8906 0.87634E+00 -0.0573 46 FeO,aq 0.15918E-09 -9.7981 0.15918E-09 -9.7981 0.10000E+01 0.0000 47 FeOH+ 0.19852E-10 -10.7022 0.17397E-10 -10.7595 0.87634E+00 -0.0573 48 HFeO2- 0.15002E-07 -7.8239 0.13134E-07 -7.8816 0.87547E+00 -0.0578 49 FeO+ 0.12305E-14 -14.9099 0.10784E-14 -14.9672 0.87634E+00 -0.0573 51 FeO2- 0.14245E-07 -7.8463 0.12471E-07 -7.9041 0.87547E+00 -0.0578 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.15437E-08 -8.8115 0.15412E-08 -8.8121 0.99843E+00 -0.0007 54 KCl,aq 0.13197E-09 -9.8795 0.13197E-09 -9.8795 0.10000E+01 0.0000 55 KHSO4,aq 0.34298E-18 -18.4647 0.34298E-18 -18.4647 0.10000E+01 0.0000 56 KOH,aq 0.20641E-06 -6.6853 0.20641E-06 -6.6853 0.10000E+01 0.0000 57 KSO4- 0.17302E-07 -7.7619 0.15147E-07 -7.8197 0.87547E+00 -0.0578 58 MgCO3,aq 0.14417E-12 -12.8411 0.14417E-12 -12.8411 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19474E-14 -14.7105 0.17066E-14 -14.7679 0.87634E+00 -0.0573 60 MgCl+ 0.23054E-14 -14.6373 0.20203E-14 -14.6946 0.87634E+00 -0.0573 61 MgOH+ 0.39547E-10 -10.4029 0.34657E-10 -10.4602 0.87634E+00 -0.0573 63 MnO,aq 0.56783E-09 -9.2458 0.56783E-09 -9.2458 0.10000E+01 0.0000 64 MnOH+ 0.24643E-09 -9.6083 0.21596E-09 -9.6656 0.87634E+00 -0.0573 65 MnO2-2 0.18546E-11 -11.7318 0.11555E-11 -11.9372 0.62308E+00 -0.2055 66 HMnO2- 0.37280E-10 -10.4285 0.32638E-10 -10.4863 0.87547E+00 -0.0578 69 MnCl+ 0.76236E-14 -14.1178 0.66809E-14 -14.1752 0.87634E+00 -0.0573 70 MnSO4,aq 0.41266E-13 -13.3844 0.41266E-13 -13.3844 0.10000E+01 0.0000 71 NaCl,aq 0.30882E-06 -6.5103 0.30882E-06 -6.5103 0.10000E+01 0.0000 72 NaOH,aq 0.26400E-04 -4.5784 0.26400E-04 -4.5784 0.10000E+01 0.0000 74 OH- 0.52607E-02 -2.2790 0.46013E-02 -2.3371 0.87465E+00 -0.0582 79 HPO3-2 0.21729E-17 -17.6630 0.13539E-17 -17.8684 0.62308E+00 -0.2055 82 H3PO4,aq 0.30429E-16 -16.5167 0.30429E-16 -16.5167 0.10000E+01 0.0000 83 H2PO4- 0.72571E-09 -9.1392 0.63565E-09 -9.1968 0.87590E+00 -0.0575 84 PO4-3 0.51721E-08 -8.2863 0.18632E-08 -8.7298 0.36023E+00 -0.4434 87 H2P2O7-2 0.50753E-19 -19.2945 0.31623E-19 -19.5000 0.62308E+00 -0.2055 88 HP2O7-3 0.14158E-15 -15.8490 0.49741E-16 -16.3033 0.35132E+00 -0.4543 89 P2O7-4 0.58805E-15 -15.2306 0.94131E-16 -16.0263 0.16007E+00 -0.7957 90 H2S,aq 0.22854E-15 -15.6410 0.22818E-15 -15.6417 0.99843E+00 -0.0007 97 SO3-2 0.53322E-14 -14.2731 0.33473E-14 -14.4753 0.62776E+00 -0.2022 98 HSO3- 0.29169E-16 -16.5351 0.25537E-16 -16.5928 0.87547E+00 -0.0578 99 HSO4- 0.21975E-11 -11.6581 0.19267E-11 -11.7152 0.87677E+00 -0.0571 Charge balance for all species = 0.8515E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1484400E-09 -.9395628E-02 -.9464034E+01 0.0000 2 H2O 0.1000000E+01 0.5550978E+02 0.9993712E+06 0.0000 3 Cl- 0.1379320E-03 0.1382409E-03 0.4897849E+01 5.9668 4 SO4-- 0.2553634E-04 0.2555519E-04 0.2453267E+01 14.9719 5 HCO3- 0.6555058E-05 0.1309527E-04 0.7985138E+00 4.6440 6 HS- 0.6653764E-12 -.1419536E-08 -.4691617E-04 -2.3498 7 Al+++ 0.7251631E-27 0.5815482E-04 0.1568078E+01 2.0605 8 H4SiO4 0.4081332E-03 0.4277171E-02 0.4108331E+03 -3.3892 9 Ca++ 0.4309733E-07 0.6319799E-07 0.2531192E-02 12.1975 10 Mg++ 0.1865563E-10 0.5947519E-10 0.1445015E-05 8.8329 11 Fe++ 0.1102844E-12 0.2962983E-07 0.1653654E-02 6.6048 12 K+ 0.7044074E-04 0.7066459E-04 0.2761319E+01 5.6753 13 Na+ 0.8946981E-02 0.9353660E-02 0.2148981E+03 7.7787 14 Mn++ 0.1473094E-10 0.8681817E-09 0.4766496E-04 8.7307 15 HPO4-- 0.4458405E-06 0.4517383E-06 0.4332902E-01 13.2139 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2119194E+00 -.9377499E-02 -.2025419E+00 0.0000000E+00 2 H2O 0.5534781E+02 0.5540268E+02 -.5487166E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3802084E-03 0.2550589E-04 0.3547025E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3547039E-03 -.1416797E-08 -.3547025E-03 0.0000000E+00 7 Al+++ 0.4173423E-01 0.5804261E-04 0.4167619E-01 0.0000000E+00 8 H4SiO4 0.1332732E+00 0.4268918E-02 0.1290043E+00 0.0000000E+00 9 Ca++ 0.1473515E-01 0.6307606E-07 0.1473508E-01 0.0000000E+00 10 Mg++ 0.1015794E-01 0.5936043E-10 0.1015794E-01 0.0000000E+00 11 Fe++ 0.9125797E-02 0.2957266E-07 0.9125767E-02 0.0000000E+00 12 K+ 0.2717410E-02 0.7052824E-04 0.2646882E-02 0.0000000E+00 13 Na+ 0.1622593E-01 0.9335612E-02 0.6890322E-02 0.0000000E+00 14 Mn++ 0.2219167E-03 0.8665065E-09 0.2219158E-03 0.0000000E+00 15 HPO4-- 0.7573906E-04 0.4508667E-06 0.7528820E-04 0.0000000E+00 Chg. balance for solid moles: -.2166E-16 Mass of aqueous solution: 0.998724E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 12.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6890E-02 -2.162 1.807 0.257 12.92 0.6936 andradite 0.4987E-03 -3.302 0.2534 -0.596 1.812 0.6584E-01 grossular 0.3884E-04 -4.411 0.1750E-01 -1.757 0.1251 0.4868E-02 apatite-OH 0.2510E-04 -4.600 0.1261E-01 -1.899 0.9016E-01 0.4006E-02 clinochlore 0.2032E-02 -2.692 1.129 0.053 8.076 0.4295 daphnite 0.1258E-02 -2.900 0.8973 -0.047 6.418 0.2719 chlorite-Mn 0.4438E-04 -4.353 0.3147E-01 -1.502 0.2251 0.1003E-01 hematite 0.8201E-03 -3.086 0.1310 -0.883 0.9368 0.2482E-01 microcline 0.2647E-02 -2.577 0.7367 -0.133 5.269 0.2878 prehnite-Fe 0.2000E-03 -3.699 0.8826E-01 -1.054 0.6312 0.2961E-01 stilbite 0.1260E-01 -1.900 8.877 0.948 63.49 4.141 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9277E+00 0.9277E+00 1.0000 -0.033 grossular 0.7226E-01 0.7226E-01 1.0000 -1.141 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 13.981663 g Volume = 5.962554 cm3 Porosity: 2.5663% V(tot) - V(min): 0.15705E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 12.7990000 g log = 1.1072 Original solution: 1000.0103000 g Original solution / Rock added: 78.13 (Water/Rock Ratio), log = 1.8928 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1631E-06 1.0073 0.1728E-06 0.1715E-06 CH4,gas 0.3059E-15 1.0129 0.3259E-15 0.3218E-15 H2,gas 0.2008E-05 1.0006 0.2114E-05 0.2113E-05 H2S,gas 0.6352E-14 0.9959 0.6655E-14 0.6682E-14 S2,gas 0.3529E-36 1.0000 0.3712E-36 0.3712E-36 CO,gas 0.8994E-16 1.0000 0.9461E-16 0.9461E-16 SO3,gas 0.9621E-40 1.0000 0.1012E-39 0.1012E-39 SO2,gas 0.7693E-23 1.0000 0.8093E-23 0.8093E-23 HCl,gas 0.4970E-17 1.0000 0.5228E-17 0.5228E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.72794E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 137 prehnite-Fe 22.59 22.59 0.00 0.000 0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.13 -8.76 -2.921 0.14962E+05 -6.762 3 CH4,gas 4.81 -12.68 -17.49 -4.372 0.29858E+05 -15.487 4 H2,gas 8.29 0.61 -7.67 -4.386 0.13105E+05 -5.675 5 H2S,gas -5.94 -22.12 -16.18 -8.088 0.27622E+05 -14.177 6 S2,gas -7.03 -45.46 -38.43 -5.912 0.65619E+05 -36.430 7 CO,gas 3.51 -14.51 -18.02 -5.546 0.30776E+05 -16.024 8 SO3,gas 17.43 -24.57 -41.99 -10.499 0.71705E+05 -39.995 9 SO2,gas 1.14 -23.96 -25.09 -6.691 0.42844E+05 -23.092 10 HCl,gas 5.48 -13.80 -19.28 -9.641 0.32923E+05 -17.282 11 acmite 7.74 7.30 -0.44 -0.046 0.74830E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.15 -4.40 -0.220 0.75203E+04 20 analcite 3.37 3.06 -0.31 -0.034 0.52898E+03 21 andalusite 5.06 0.73 -4.33 -0.433 0.73943E+04 26 annite 20.21 17.38 -2.83 -0.157 0.48265E+04 27 phlogopite 27.15 24.07 -3.08 -0.171 0.52587E+04 29 anorthite 12.80 9.54 -3.26 -0.251 0.55622E+04 35 aragonite 0.99 -2.93 -3.91 -1.305 0.66837E+04 36 brucite 12.58 8.83 -3.74 -0.749 0.63923E+04 37 calcite 0.83 -2.93 -3.76 -1.254 0.64224E+04 38 carnegieite-low 9.06 6.45 -2.61 -0.374 0.44642E+04 39 carnegieite-high 10.13 6.45 -3.68 -0.526 0.62911E+04 40 carpholite-Mg 8.65 6.18 -2.47 -0.165 0.42258E+04 41 carpholite-Fe 6.78 3.95 -2.84 -0.189 0.48415E+04 42 celadonite 5.40 3.01 -2.39 -0.141 0.40785E+04 43 celadonite-Fe 3.94 0.78 -3.15 -0.185 0.53839E+04 44 chrysotile 23.94 19.72 -4.22 -0.351 0.72007E+04 50 chloritoid-Mg 13.26 9.56 -3.70 -0.246 0.63118E+04 51 chloritoid-Fe 9.24 7.34 -1.90 -0.127 0.32477E+04 52 chloritoid-Mn 11.46 9.46 -2.00 -0.133 0.34161E+04 54 coesite -2.37 -3.39 -1.02 -0.340 0.17414E+04 59 corundum 8.43 4.12 -4.31 -0.392 0.73633E+04 61 cristobalite -2.55 -3.39 -0.84 -0.280 0.14342E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.06 -0.84 -0.139 0.14267E+04 67 diopside 16.22 14.25 -1.96 -0.196 0.33526E+04 68 hedenbergite 14.24 12.02 -2.22 -0.222 0.37914E+04 75 epidote 24.78 24.65 -0.13 -0.006 0.21845E+03 76 clinozoisite 22.92 20.41 -2.51 -0.114 0.42895E+04 77 epidote-Fe 29.94 28.89 -1.05 -0.055 0.17949E+04 78 fayalite 14.08 9.82 -4.26 -0.608 0.72714E+04 79 ferrosilite 11.19 6.43 -4.76 -0.476 0.81216E+04 83 gibbsite 4.10 2.06 -2.04 -0.291 0.34779E+04 84 glaucophane 23.11 19.06 -4.05 -0.109 0.69103E+04 87 greenalite 16.19 13.04 -3.16 -0.263 0.53925E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.06 -1.19 -0.119 0.20320E+04 96 julgoldite 70.57 66.86 -3.71 -0.096 0.63400E+04 97 kalsilite 7.62 4.35 -3.27 -0.468 0.55897E+04 98 kaolinite -1.27 -2.66 -1.38 -0.126 0.23636E+04 99 kyanite 4.93 0.73 -4.20 -0.420 0.71711E+04 101 laumontite 2.97 2.76 -0.21 -0.014 0.36336E+03 102 lawsonite 9.68 9.54 -0.14 -0.009 0.23604E+03 103 leucite 4.17 0.96 -3.21 -0.321 0.54814E+04 105 lizardite 23.29 19.72 -3.57 -0.297 0.60910E+04 107 magnetite 20.13 19.20 -0.93 -0.076 0.15886E+04 108 minnesotaite 10.46 6.26 -4.20 -0.247 0.71767E+04 110 magnesioferrite 26.26 21.43 -4.83 -0.394 0.82416E+04 113 margarite 17.45 13.66 -3.79 -0.152 0.64724E+04 120 muscovite 2.68 1.69 -0.99 -0.058 0.16904E+04 121 paragonite 4.34 3.79 -0.54 -0.032 0.92884E+03 122 nepheline 8.38 6.45 -1.93 -0.275 0.32922E+04 134 phlogopite-Na 29.73 26.17 -3.56 -0.198 0.60806E+04 136 prehnite 19.47 18.35 -1.12 -0.066 0.19087E+04 138 pumpellyite-Fe 46.47 45.36 -1.11 -0.025 0.18924E+04 139 pumpellyite-Mg 49.19 47.59 -1.60 -0.036 0.27384E+04 145 pyroxmangite 7.42 5.34 -2.07 -0.415 0.35422E+04 146 pyrophyllite -6.10 -9.44 -3.34 -0.209 0.56991E+04 147 quartz -2.98 -3.39 -0.41 -0.136 0.69528E+03 152 rhodonite 7.46 5.34 -2.12 -0.424 0.36214E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.73 -4.59 -0.459 0.78365E+04 164 stilpnomelane-Fe 13.18 12.87 -0.31 -0.009 0.52977E+03 165 stilpnomelane-Mg 27.60 24.01 -3.59 -0.107 0.61246E+04 171 talc 16.55 12.94 -3.61 -0.212 0.61667E+04 174 tephroite 18.11 14.07 -4.04 -0.577 0.68994E+04 177 topaz-H 4.67 0.73 -3.94 -0.358 0.67202E+04 178 tridymite -2.61 -3.39 -0.77 -0.258 0.13226E+04 187 wairakite 4.06 2.76 -1.30 -0.076 0.22142E+04 188 walstromite 11.53 8.81 -2.72 -0.544 0.46435E+04 189 wollastonite 10.48 8.81 -1.67 -0.335 0.28574E+04 190 pseudo-wollastonite 11.02 8.81 -2.21 -0.442 0.37761E+04 191 zoisite 22.96 20.41 -2.55 -0.116 0.43620E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.62 -4.07 -0.251 0.69411E+04 195 beidellite-K -1.44 -5.76 -4.33 -0.265 0.73925E+04 196 beidellite-Mg -1.71 -6.18 -4.47 -0.277 0.76376E+04 197 beidellite-Na -1.26 -5.07 -3.81 -0.234 0.65112E+04 199 chalcedony -2.79 -3.39 -0.59 -0.198 0.10156E+04 201 montmorillonite-Ca -2.21 -5.19 -2.97 -0.184 0.50785E+04 202 montmorillonite-K -2.16 -5.33 -3.17 -0.194 0.54077E+04 203 montmorillonite-Mg -2.40 -5.74 -3.34 -0.207 0.57061E+04 204 montmorillonite-Na -1.96 -4.63 -2.67 -0.164 0.45646E+04 205 nontronite-Ca 3.28 2.85 -0.43 -0.028 0.73052E+03 206 nontronite-H 2.60 0.84 -1.76 -0.118 0.29992E+04 207 nontronite-K 3.40 2.71 -0.69 -0.044 0.11811E+04 208 nontronite-Mg 3.14 2.30 -0.84 -0.055 0.14387E+04 209 nontronite-Na 3.58 3.41 -0.18 -0.011 0.30156E+03 224 tobermorite 9.84 6.77 -3.07 -0.837 0.52380E+04 233 boehmite 4.43 2.06 -2.37 -0.395 0.40452E+04 235 ferrous-oxide 9.82 6.60 -3.22 -0.805 0.54971E+04 240 silica-amorphous -2.08 -3.39 -1.31 -0.436 0.22358E+04 242 an20ab80 2.08 1.65 -0.43 -0.033 0.74082E+03 243 an25ab75 2.71 2.14 -0.57 -0.044 0.97393E+03 244 an30ab70 3.34 2.63 -0.71 -0.055 0.12154E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 12.7990000 g New total amount of reactant added: 13.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8625E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 13.1990000 Water: Moles liquid = 0.5540E+02 kg liquid = 0.9980E+00 Moles total = 0.5534E+02 kg total = 0.9970E+00 Activity = 1.0000 Stoichiometric ionic strength = .5101594E-02 Osmotic coef. = 0.9621 True ionic strength = .9050111E-02 Chg. balance for total moles = 0.8625E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14844E-09 -9.8284 0.13036E-09 -9.8848 0.87822E+00 -0.0564 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12076E-03 -3.9181 0.87547E+00 -0.0578 4 SO4-- 0.25537E-04 -4.5928 0.15929E-04 -4.7978 0.62377E+00 -0.2050 5 HCO3- 0.65553E-05 -5.1834 0.57433E-05 -5.2408 0.87613E+00 -0.0574 6 HS- 0.66540E-12 -12.1769 0.58259E-12 -12.2346 0.87554E+00 -0.0577 7 Al+++ 0.72516E-27 -27.1396 0.25466E-27 -27.5940 0.35118E+00 -0.4545 8 H4SiO4 0.40813E-03 -3.3892 0.40813E-03 -3.3892 0.10000E+01 0.0000 9 Ca++ 0.43097E-07 -7.3655 0.26781E-07 -7.5722 0.62141E+00 -0.2066 10 Mg++ 0.18656E-10 -10.7292 0.11565E-10 -10.9368 0.61994E+00 -0.2077 11 Fe++ 0.11028E-12 -12.9575 0.68408E-13 -13.1649 0.62029E+00 -0.2074 12 K+ 0.70441E-04 -4.1522 0.61723E-04 -4.2096 0.87624E+00 -0.0574 13 Na+ 0.89470E-02 -2.0483 0.78322E-02 -2.1061 0.87540E+00 -0.0578 14 Mn++ 0.14731E-10 -10.8318 0.91414E-11 -11.0390 0.62055E+00 -0.2072 15 HPO4-- 0.44584E-06 -6.3508 0.27812E-06 -6.5558 0.62381E+00 -0.2049 16 HSiO3- 0.34891E-02 -2.4573 0.30546E-02 -2.5150 0.87547E+00 -0.0578 17 Ca(HSiO3)+ 0.20915E-08 -8.6795 0.18329E-08 -8.7369 0.87634E+00 -0.0573 18 Mg(HSiO3)+ 0.11240E-11 -11.9492 0.98505E-12 -12.0065 0.87634E+00 -0.0573 19 NaHSiO3,aq 0.37997E-03 -3.4203 0.37997E-03 -3.4203 0.10000E+01 0.0000 20 AlO+ 0.22075E-14 -14.6561 0.19345E-14 -14.7134 0.87634E+00 -0.0573 22 HAlO2,aq 0.29695E-08 -8.5273 0.29695E-08 -8.5273 0.10000E+01 0.0000 23 AlO2- 0.58152E-04 -4.2354 0.50862E-04 -4.2936 0.87465E+00 -0.0582 24 CH4,aq 0.20644E-18 -18.6852 0.20612E-18 -18.6859 0.99843E+00 -0.0007 29 CO,aq 0.59922E-19 -19.2224 0.59922E-19 -19.2224 0.10000E+01 0.0000 30 CO2,aq 0.15119E-08 -8.8205 0.15096E-08 -8.8211 0.99843E+00 -0.0007 31 CO3-2 0.65376E-05 -5.1846 0.40735E-05 -5.3900 0.62308E+00 -0.2055 32 CaCO3,aq 0.13361E-08 -8.8742 0.13361E-08 -8.8742 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44225E-11 -11.3543 0.38756E-11 -11.4117 0.87634E+00 -0.0573 34 CaCl+ 0.58807E-11 -11.2306 0.51535E-11 -11.2879 0.87634E+00 -0.0573 35 CaCl2,aq 0.14490E-15 -15.8389 0.14490E-15 -15.8389 0.10000E+01 0.0000 36 CaOH+ 0.16530E-07 -7.7817 0.14486E-07 -7.8391 0.87634E+00 -0.0573 37 CaSO4,aq 0.13292E-09 -9.8764 0.13292E-09 -9.8764 0.10000E+01 0.0000 38 HCl,aq 0.29611E-14 -14.5285 0.29611E-14 -14.5285 0.10000E+01 0.0000 43 FeCl+ 0.14682E-16 -16.8332 0.12867E-16 -16.8905 0.87634E+00 -0.0573 46 FeO,aq 0.15918E-09 -9.7981 0.15918E-09 -9.7981 0.10000E+01 0.0000 47 FeOH+ 0.19852E-10 -10.7022 0.17397E-10 -10.7595 0.87634E+00 -0.0573 48 HFeO2- 0.15002E-07 -7.8239 0.13134E-07 -7.8816 0.87547E+00 -0.0578 49 FeO+ 0.12305E-14 -14.9099 0.10784E-14 -14.9672 0.87634E+00 -0.0573 51 FeO2- 0.14245E-07 -7.8463 0.12471E-07 -7.9041 0.87547E+00 -0.0578 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.15437E-08 -8.8115 0.15412E-08 -8.8121 0.99843E+00 -0.0007 54 KCl,aq 0.13198E-09 -9.8795 0.13198E-09 -9.8795 0.10000E+01 0.0000 55 KHSO4,aq 0.34299E-18 -18.4647 0.34299E-18 -18.4647 0.10000E+01 0.0000 56 KOH,aq 0.20641E-06 -6.6853 0.20641E-06 -6.6853 0.10000E+01 0.0000 57 KSO4- 0.17302E-07 -7.7619 0.15148E-07 -7.8197 0.87547E+00 -0.0578 58 MgCO3,aq 0.14418E-12 -12.8411 0.14418E-12 -12.8411 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19475E-14 -14.7105 0.17067E-14 -14.7678 0.87634E+00 -0.0573 60 MgCl+ 0.23055E-14 -14.6372 0.20204E-14 -14.6946 0.87634E+00 -0.0573 61 MgOH+ 0.39547E-10 -10.4029 0.34657E-10 -10.4602 0.87634E+00 -0.0573 63 MnO,aq 0.56783E-09 -9.2458 0.56783E-09 -9.2458 0.10000E+01 0.0000 64 MnOH+ 0.24643E-09 -9.6083 0.21596E-09 -9.6656 0.87634E+00 -0.0573 65 MnO2-2 0.18546E-11 -11.7318 0.11555E-11 -11.9372 0.62308E+00 -0.2055 66 HMnO2- 0.37280E-10 -10.4285 0.32638E-10 -10.4863 0.87547E+00 -0.0578 69 MnCl+ 0.76239E-14 -14.1178 0.66812E-14 -14.1751 0.87634E+00 -0.0573 70 MnSO4,aq 0.41268E-13 -13.3844 0.41268E-13 -13.3844 0.10000E+01 0.0000 71 NaCl,aq 0.30883E-06 -6.5103 0.30883E-06 -6.5103 0.10000E+01 0.0000 72 NaOH,aq 0.26400E-04 -4.5784 0.26400E-04 -4.5784 0.10000E+01 0.0000 74 OH- 0.52607E-02 -2.2790 0.46013E-02 -2.3371 0.87465E+00 -0.0582 79 HPO3-2 0.21729E-17 -17.6630 0.13539E-17 -17.8684 0.62308E+00 -0.2055 82 H3PO4,aq 0.30429E-16 -16.5167 0.30429E-16 -16.5167 0.10000E+01 0.0000 83 H2PO4- 0.72571E-09 -9.1392 0.63565E-09 -9.1968 0.87590E+00 -0.0575 84 PO4-3 0.51721E-08 -8.2863 0.18632E-08 -8.7298 0.36023E+00 -0.4434 87 H2P2O7-2 0.50753E-19 -19.2945 0.31623E-19 -19.5000 0.62308E+00 -0.2055 88 HP2O7-3 0.14158E-15 -15.8490 0.49741E-16 -16.3033 0.35132E+00 -0.4543 89 P2O7-4 0.58805E-15 -15.2306 0.94131E-16 -16.0263 0.16007E+00 -0.7957 90 H2S,aq 0.22855E-15 -15.6410 0.22819E-15 -15.6417 0.99843E+00 -0.0007 97 SO3-2 0.53325E-14 -14.2731 0.33475E-14 -14.4753 0.62776E+00 -0.2022 98 HSO3- 0.29171E-16 -16.5351 0.25538E-16 -16.5928 0.87547E+00 -0.0578 99 HSO4- 0.21976E-11 -11.6581 0.19268E-11 -11.7152 0.87677E+00 -0.0571 Charge balance for all species = 0.8517E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1484401E-09 -.9395624E-02 -.9464030E+01 0.0000 2 H2O 0.1000000E+01 0.5550978E+02 0.9993712E+06 0.0000 3 Cl- 0.1379378E-03 0.1382467E-03 0.4898055E+01 5.9668 4 SO4-- 0.2553741E-04 0.2555627E-04 0.2453370E+01 14.9719 5 HCO3- 0.6555336E-05 0.1309582E-04 0.7985475E+00 4.6440 6 HS- 0.6654050E-12 -.1419535E-08 -.4691614E-04 -2.3498 7 Al+++ 0.7251644E-27 0.5815479E-04 0.1568077E+01 2.0605 8 H4SiO4 0.4081332E-03 0.4277170E-02 0.4108329E+03 -3.3892 9 Ca++ 0.4309738E-07 0.6319812E-07 0.2531197E-02 12.1975 10 Mg++ 0.1865565E-10 0.5947523E-10 0.1445016E-05 8.8329 11 Fe++ 0.1102845E-12 0.2962981E-07 0.1653654E-02 6.6048 12 K+ 0.7044078E-04 0.7066463E-04 0.2761321E+01 5.6753 13 Na+ 0.8946986E-02 0.9353665E-02 0.2148982E+03 7.7787 14 Mn++ 0.1473096E-10 0.8681819E-09 0.4766497E-04 8.7307 15 HPO4-- 0.4458401E-06 0.4517379E-06 0.4332899E-01 13.2139 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2185428E+00 -.9377100E-02 -.2091657E+00 0.0000000E+00 2 H2O 0.5534280E+02 0.5540034E+02 -.5754907E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3912938E-03 0.2550589E-04 0.3657879E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3657893E-03 -.1416736E-08 -.3657879E-03 0.0000000E+00 7 Al+++ 0.4303853E-01 0.5804014E-04 0.4298049E-01 0.0000000E+00 8 H4SiO4 0.1374383E+00 0.4268737E-02 0.1331696E+00 0.0000000E+00 9 Ca++ 0.1519520E-01 0.6307352E-07 0.1519514E-01 0.0000000E+00 10 Mg++ 0.1047540E-01 0.5935798E-10 0.1047540E-01 0.0000000E+00 11 Fe++ 0.9411000E-02 0.2957140E-07 0.9410971E-02 0.0000000E+00 12 K+ 0.2802335E-02 0.7052531E-04 0.2731810E-02 0.0000000E+00 13 Na+ 0.1672803E-01 0.9335223E-02 0.7392808E-02 0.0000000E+00 14 Mn++ 0.2288521E-03 0.8664702E-09 0.2288513E-03 0.0000000E+00 15 HPO4-- 0.7810609E-04 0.4508473E-06 0.7765525E-04 0.0000000E+00 Chg. balance for solid moles: -.1464E-17 Mass of aqueous solution: 0.998682E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 13.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7393E-02 -2.131 1.939 0.287 13.44 0.7442 andradite 0.5997E-03 -3.222 0.3048 -0.516 2.113 0.7918E-01 grossular 0.4671E-04 -4.331 0.2104E-01 -1.677 0.1459 0.5854E-02 apatite-OH 0.2589E-04 -4.587 0.1300E-01 -1.886 0.9017E-01 0.4132E-02 clinochlore 0.2095E-02 -2.679 1.165 0.066 8.075 0.4429 daphnite 0.1297E-02 -2.887 0.9254 -0.034 6.417 0.2804 chlorite-Mn 0.4577E-04 -4.339 0.3245E-01 -1.489 0.2250 0.1034E-01 hematite 0.8024E-03 -3.096 0.1281 -0.892 0.8887 0.2429E-01 microcline 0.2732E-02 -2.564 0.7604 -0.119 5.273 0.2970 prehnite-Fe 0.1220E-03 -3.914 0.5383E-01 -1.269 0.3733 0.1806E-01 stilbite 0.1288E-01 -1.890 9.079 0.958 62.96 4.234 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9277E+00 0.9277E+00 1.0000 -0.033 grossular 0.7226E-01 0.7226E-01 1.0000 -1.141 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 14.420549 g Volume = 6.140783 cm3 Porosity: 2.2106% V(tot) - V(min): 0.13882E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 13.1990000 g log = 1.1205 Original solution: 1000.0103000 g Original solution / Rock added: 75.76 (Water/Rock Ratio), log = 1.8795 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1631E-06 1.0073 0.1728E-06 0.1715E-06 CH4,gas 0.3059E-15 1.0129 0.3259E-15 0.3218E-15 H2,gas 0.2008E-05 1.0006 0.2114E-05 0.2113E-05 H2S,gas 0.6353E-14 0.9959 0.6655E-14 0.6683E-14 S2,gas 0.3529E-36 1.0000 0.3713E-36 0.3713E-36 CO,gas 0.8995E-16 1.0000 0.9462E-16 0.9462E-16 SO3,gas 0.9621E-40 1.0000 0.1012E-39 0.1012E-39 SO2,gas 0.7694E-23 1.0000 0.8093E-23 0.8093E-23 HCl,gas 0.4970E-17 1.0000 0.5229E-17 0.5229E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 137 prehnite-Fe 22.59 22.59 0.00 0.000 -0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.13 -8.76 -2.921 0.14962E+05 -6.762 3 CH4,gas 4.81 -12.68 -17.49 -4.372 0.29858E+05 -15.487 4 H2,gas 8.29 0.61 -7.67 -4.386 0.13105E+05 -5.675 5 H2S,gas -5.94 -22.12 -16.18 -8.088 0.27622E+05 -14.177 6 S2,gas -7.03 -45.46 -38.43 -5.912 0.65619E+05 -36.430 7 CO,gas 3.51 -14.51 -18.02 -5.546 0.30776E+05 -16.024 8 SO3,gas 17.43 -24.57 -41.99 -10.499 0.71705E+05 -39.995 9 SO2,gas 1.14 -23.96 -25.09 -6.691 0.42844E+05 -23.092 10 HCl,gas 5.48 -13.80 -19.28 -9.641 0.32923E+05 -17.282 11 acmite 7.74 7.30 -0.44 -0.046 0.74830E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.15 -4.40 -0.220 0.75203E+04 20 analcite 3.37 3.06 -0.31 -0.034 0.52898E+03 21 andalusite 5.06 0.73 -4.33 -0.433 0.73943E+04 26 annite 20.21 17.38 -2.83 -0.157 0.48265E+04 27 phlogopite 27.15 24.07 -3.08 -0.171 0.52587E+04 29 anorthite 12.80 9.54 -3.26 -0.251 0.55622E+04 35 aragonite 0.99 -2.93 -3.91 -1.305 0.66837E+04 36 brucite 12.58 8.83 -3.74 -0.749 0.63923E+04 37 calcite 0.83 -2.93 -3.76 -1.254 0.64224E+04 38 carnegieite-low 9.06 6.45 -2.61 -0.374 0.44642E+04 39 carnegieite-high 10.13 6.45 -3.68 -0.526 0.62911E+04 40 carpholite-Mg 8.65 6.18 -2.47 -0.165 0.42258E+04 41 carpholite-Fe 6.78 3.95 -2.84 -0.189 0.48415E+04 42 celadonite 5.40 3.01 -2.39 -0.141 0.40785E+04 43 celadonite-Fe 3.94 0.78 -3.15 -0.185 0.53839E+04 44 chrysotile 23.94 19.72 -4.22 -0.351 0.72007E+04 50 chloritoid-Mg 13.26 9.56 -3.70 -0.246 0.63118E+04 51 chloritoid-Fe 9.24 7.34 -1.90 -0.127 0.32477E+04 52 chloritoid-Mn 11.46 9.46 -2.00 -0.133 0.34161E+04 54 coesite -2.37 -3.39 -1.02 -0.340 0.17414E+04 59 corundum 8.43 4.12 -4.31 -0.392 0.73633E+04 61 cristobalite -2.55 -3.39 -0.84 -0.280 0.14342E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.06 -0.84 -0.139 0.14267E+04 67 diopside 16.22 14.25 -1.96 -0.196 0.33526E+04 68 hedenbergite 14.24 12.02 -2.22 -0.222 0.37914E+04 75 epidote 24.78 24.65 -0.13 -0.006 0.21845E+03 76 clinozoisite 22.92 20.41 -2.51 -0.114 0.42895E+04 77 epidote-Fe 29.94 28.89 -1.05 -0.055 0.17949E+04 78 fayalite 14.08 9.82 -4.26 -0.608 0.72714E+04 79 ferrosilite 11.19 6.43 -4.76 -0.476 0.81216E+04 83 gibbsite 4.10 2.06 -2.04 -0.291 0.34779E+04 84 glaucophane 23.11 19.06 -4.05 -0.109 0.69103E+04 87 greenalite 16.19 13.04 -3.16 -0.263 0.53925E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.06 -1.19 -0.119 0.20320E+04 96 julgoldite 70.57 66.86 -3.71 -0.096 0.63400E+04 97 kalsilite 7.62 4.35 -3.27 -0.468 0.55897E+04 98 kaolinite -1.27 -2.66 -1.38 -0.126 0.23636E+04 99 kyanite 4.93 0.73 -4.20 -0.420 0.71711E+04 101 laumontite 2.97 2.76 -0.21 -0.014 0.36336E+03 102 lawsonite 9.68 9.54 -0.14 -0.009 0.23604E+03 103 leucite 4.17 0.96 -3.21 -0.321 0.54814E+04 105 lizardite 23.29 19.72 -3.57 -0.297 0.60910E+04 107 magnetite 20.13 19.20 -0.93 -0.076 0.15886E+04 108 minnesotaite 10.46 6.26 -4.20 -0.247 0.71767E+04 110 magnesioferrite 26.26 21.43 -4.83 -0.394 0.82416E+04 113 margarite 17.45 13.66 -3.79 -0.152 0.64724E+04 120 muscovite 2.68 1.69 -0.99 -0.058 0.16904E+04 121 paragonite 4.34 3.79 -0.54 -0.032 0.92884E+03 122 nepheline 8.38 6.45 -1.93 -0.275 0.32922E+04 134 phlogopite-Na 29.73 26.17 -3.56 -0.198 0.60806E+04 136 prehnite 19.47 18.35 -1.12 -0.066 0.19087E+04 138 pumpellyite-Fe 46.47 45.36 -1.11 -0.025 0.18924E+04 139 pumpellyite-Mg 49.19 47.59 -1.60 -0.036 0.27384E+04 145 pyroxmangite 7.42 5.34 -2.07 -0.415 0.35422E+04 146 pyrophyllite -6.10 -9.44 -3.34 -0.209 0.56991E+04 147 quartz -2.98 -3.39 -0.41 -0.136 0.69528E+03 152 rhodonite 7.46 5.34 -2.12 -0.424 0.36214E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.73 -4.59 -0.459 0.78365E+04 164 stilpnomelane-Fe 13.18 12.87 -0.31 -0.009 0.52977E+03 165 stilpnomelane-Mg 27.60 24.01 -3.59 -0.107 0.61246E+04 171 talc 16.55 12.94 -3.61 -0.212 0.61667E+04 174 tephroite 18.11 14.07 -4.04 -0.577 0.68994E+04 177 topaz-H 4.67 0.73 -3.94 -0.358 0.67202E+04 178 tridymite -2.61 -3.39 -0.77 -0.258 0.13226E+04 187 wairakite 4.06 2.76 -1.30 -0.076 0.22142E+04 188 walstromite 11.53 8.81 -2.72 -0.544 0.46435E+04 189 wollastonite 10.48 8.81 -1.67 -0.335 0.28574E+04 190 pseudo-wollastonite 11.02 8.81 -2.21 -0.442 0.37761E+04 191 zoisite 22.96 20.41 -2.55 -0.116 0.43620E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.62 -4.07 -0.251 0.69411E+04 195 beidellite-K -1.44 -5.76 -4.33 -0.265 0.73925E+04 196 beidellite-Mg -1.71 -6.18 -4.47 -0.277 0.76376E+04 197 beidellite-Na -1.26 -5.07 -3.81 -0.234 0.65112E+04 199 chalcedony -2.79 -3.39 -0.59 -0.198 0.10156E+04 201 montmorillonite-Ca -2.21 -5.19 -2.97 -0.184 0.50785E+04 202 montmorillonite-K -2.16 -5.33 -3.17 -0.194 0.54077E+04 203 montmorillonite-Mg -2.40 -5.74 -3.34 -0.207 0.57061E+04 204 montmorillonite-Na -1.96 -4.63 -2.67 -0.164 0.45646E+04 205 nontronite-Ca 3.28 2.85 -0.43 -0.028 0.73052E+03 206 nontronite-H 2.60 0.84 -1.76 -0.118 0.29992E+04 207 nontronite-K 3.40 2.71 -0.69 -0.044 0.11811E+04 208 nontronite-Mg 3.14 2.30 -0.84 -0.055 0.14387E+04 209 nontronite-Na 3.58 3.41 -0.18 -0.011 0.30156E+03 224 tobermorite 9.84 6.77 -3.07 -0.837 0.52380E+04 233 boehmite 4.43 2.06 -2.37 -0.395 0.40452E+04 235 ferrous-oxide 9.82 6.60 -3.22 -0.805 0.54971E+04 240 silica-amorphous -2.08 -3.39 -1.31 -0.436 0.22358E+04 242 an20ab80 2.08 1.65 -0.43 -0.033 0.74082E+03 243 an25ab75 2.71 2.14 -0.57 -0.044 0.97393E+03 244 an30ab70 3.34 2.63 -0.71 -0.055 0.12154E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 13.1990000 g New total amount of reactant added: 13.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8620E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 13.5990000 Water: Moles liquid = 0.5540E+02 kg liquid = 0.9980E+00 Moles total = 0.5534E+02 kg total = 0.9969E+00 Activity = 1.0000 Stoichiometric ionic strength = .5101602E-02 Osmotic coef. = 0.9621 True ionic strength = .9050118E-02 Chg. balance for total moles = 0.8620E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14844E-09 -9.8284 0.13036E-09 -9.8848 0.87822E+00 -0.0564 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13794E-03 -3.8603 0.12077E-03 -3.9181 0.87547E+00 -0.0578 4 SO4-- 0.25538E-04 -4.5928 0.15930E-04 -4.7978 0.62377E+00 -0.2050 5 HCO3- 0.65556E-05 -5.1834 0.57436E-05 -5.2408 0.87613E+00 -0.0574 6 HS- 0.66543E-12 -12.1769 0.58261E-12 -12.2346 0.87554E+00 -0.0577 7 Al+++ 0.72517E-27 -27.1396 0.25466E-27 -27.5940 0.35118E+00 -0.4545 8 H4SiO4 0.40813E-03 -3.3892 0.40813E-03 -3.3892 0.10000E+01 0.0000 9 Ca++ 0.43097E-07 -7.3655 0.26781E-07 -7.5722 0.62141E+00 -0.2066 10 Mg++ 0.18656E-10 -10.7292 0.11565E-10 -10.9368 0.61994E+00 -0.2077 11 Fe++ 0.11028E-12 -12.9575 0.68408E-13 -13.1649 0.62029E+00 -0.2074 12 K+ 0.70441E-04 -4.1522 0.61723E-04 -4.2096 0.87624E+00 -0.0574 13 Na+ 0.89470E-02 -2.0483 0.78322E-02 -2.1061 0.87540E+00 -0.0578 14 Mn++ 0.14731E-10 -10.8318 0.91414E-11 -11.0390 0.62055E+00 -0.2072 15 HPO4-- 0.44584E-06 -6.3508 0.27812E-06 -6.5558 0.62381E+00 -0.2049 16 HSiO3- 0.34891E-02 -2.4573 0.30546E-02 -2.5150 0.87547E+00 -0.0578 17 Ca(HSiO3)+ 0.20915E-08 -8.6795 0.18329E-08 -8.7369 0.87634E+00 -0.0573 18 Mg(HSiO3)+ 0.11241E-11 -11.9492 0.98505E-12 -12.0065 0.87634E+00 -0.0573 19 NaHSiO3,aq 0.37997E-03 -3.4203 0.37997E-03 -3.4203 0.10000E+01 0.0000 20 AlO+ 0.22075E-14 -14.6561 0.19345E-14 -14.7134 0.87634E+00 -0.0573 22 HAlO2,aq 0.29695E-08 -8.5273 0.29695E-08 -8.5273 0.10000E+01 0.0000 23 AlO2- 0.58152E-04 -4.2354 0.50862E-04 -4.2936 0.87465E+00 -0.0582 24 CH4,aq 0.20645E-18 -18.6852 0.20612E-18 -18.6859 0.99843E+00 -0.0007 29 CO,aq 0.59924E-19 -19.2224 0.59924E-19 -19.2224 0.10000E+01 0.0000 30 CO2,aq 0.15120E-08 -8.8204 0.15096E-08 -8.8211 0.99843E+00 -0.0007 31 CO3-2 0.65379E-05 -5.1846 0.40736E-05 -5.3900 0.62308E+00 -0.2055 32 CaCO3,aq 0.13362E-08 -8.8741 0.13362E-08 -8.8741 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44227E-11 -11.3543 0.38758E-11 -11.4116 0.87634E+00 -0.0573 34 CaCl+ 0.58810E-11 -11.2306 0.51537E-11 -11.2879 0.87634E+00 -0.0573 35 CaCl2,aq 0.14492E-15 -15.8389 0.14492E-15 -15.8389 0.10000E+01 0.0000 36 CaOH+ 0.16530E-07 -7.7817 0.14486E-07 -7.8391 0.87634E+00 -0.0573 37 CaSO4,aq 0.13293E-09 -9.8764 0.13293E-09 -9.8764 0.10000E+01 0.0000 38 HCl,aq 0.29613E-14 -14.5285 0.29613E-14 -14.5285 0.10000E+01 0.0000 43 FeCl+ 0.14683E-16 -16.8332 0.12867E-16 -16.8905 0.87634E+00 -0.0573 46 FeO,aq 0.15918E-09 -9.7981 0.15918E-09 -9.7981 0.10000E+01 0.0000 47 FeOH+ 0.19852E-10 -10.7022 0.17397E-10 -10.7595 0.87634E+00 -0.0573 48 HFeO2- 0.15002E-07 -7.8239 0.13134E-07 -7.8816 0.87547E+00 -0.0578 49 FeO+ 0.12305E-14 -14.9099 0.10784E-14 -14.9672 0.87634E+00 -0.0573 51 FeO2- 0.14245E-07 -7.8463 0.12471E-07 -7.9041 0.87547E+00 -0.0578 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.15437E-08 -8.8115 0.15412E-08 -8.8121 0.99843E+00 -0.0007 54 KCl,aq 0.13199E-09 -9.8795 0.13199E-09 -9.8795 0.10000E+01 0.0000 55 KHSO4,aq 0.34301E-18 -18.4647 0.34301E-18 -18.4647 0.10000E+01 0.0000 56 KOH,aq 0.20641E-06 -6.6853 0.20641E-06 -6.6853 0.10000E+01 0.0000 57 KSO4- 0.17303E-07 -7.7619 0.15148E-07 -7.8196 0.87547E+00 -0.0578 58 MgCO3,aq 0.14419E-12 -12.8411 0.14419E-12 -12.8411 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19476E-14 -14.7105 0.17068E-14 -14.7678 0.87634E+00 -0.0573 60 MgCl+ 0.23056E-14 -14.6372 0.20205E-14 -14.6945 0.87634E+00 -0.0573 61 MgOH+ 0.39547E-10 -10.4029 0.34657E-10 -10.4602 0.87634E+00 -0.0573 63 MnO,aq 0.56783E-09 -9.2458 0.56783E-09 -9.2458 0.10000E+01 0.0000 64 MnOH+ 0.24643E-09 -9.6083 0.21596E-09 -9.6656 0.87634E+00 -0.0573 65 MnO2-2 0.18546E-11 -11.7318 0.11555E-11 -11.9372 0.62308E+00 -0.2055 66 HMnO2- 0.37280E-10 -10.4285 0.32638E-10 -10.4863 0.87547E+00 -0.0578 69 MnCl+ 0.76243E-14 -14.1178 0.66815E-14 -14.1751 0.87634E+00 -0.0573 70 MnSO4,aq 0.41270E-13 -13.3844 0.41270E-13 -13.3844 0.10000E+01 0.0000 71 NaCl,aq 0.30885E-06 -6.5103 0.30885E-06 -6.5103 0.10000E+01 0.0000 72 NaOH,aq 0.26400E-04 -4.5784 0.26400E-04 -4.5784 0.10000E+01 0.0000 74 OH- 0.52607E-02 -2.2790 0.46013E-02 -2.3371 0.87465E+00 -0.0582 79 HPO3-2 0.21729E-17 -17.6630 0.13539E-17 -17.8684 0.62308E+00 -0.2055 82 H3PO4,aq 0.30429E-16 -16.5167 0.30429E-16 -16.5167 0.10000E+01 0.0000 83 H2PO4- 0.72571E-09 -9.1392 0.63565E-09 -9.1968 0.87590E+00 -0.0575 84 PO4-3 0.51721E-08 -8.2863 0.18632E-08 -8.7298 0.36023E+00 -0.4434 87 H2P2O7-2 0.50753E-19 -19.2945 0.31623E-19 -19.5000 0.62308E+00 -0.2055 88 HP2O7-3 0.14158E-15 -15.8490 0.49741E-16 -16.3033 0.35132E+00 -0.4543 89 P2O7-4 0.58805E-15 -15.2306 0.94130E-16 -16.0263 0.16007E+00 -0.7957 90 H2S,aq 0.22856E-15 -15.6410 0.22820E-15 -15.6417 0.99843E+00 -0.0007 97 SO3-2 0.53327E-14 -14.2731 0.33476E-14 -14.4753 0.62776E+00 -0.2022 98 HSO3- 0.29172E-16 -16.5350 0.25539E-16 -16.5928 0.87547E+00 -0.0578 99 HSO4- 0.21977E-11 -11.6580 0.19269E-11 -11.7151 0.87677E+00 -0.0571 Charge balance for all species = 0.8518E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1484402E-09 -.9395620E-02 -.9464026E+01 0.0000 2 H2O 0.1000000E+01 0.5550978E+02 0.9993712E+06 0.0000 3 Cl- 0.1379436E-03 0.1382526E-03 0.4898262E+01 5.9668 4 SO4-- 0.2553849E-04 0.2555735E-04 0.2453474E+01 14.9719 5 HCO3- 0.6555614E-05 0.1309637E-04 0.7985811E+00 4.6440 6 HS- 0.6654336E-12 -.1419534E-08 -.4691611E-04 -2.3498 7 Al+++ 0.7251657E-27 0.5815477E-04 0.1568076E+01 2.0605 8 H4SiO4 0.4081332E-03 0.4277168E-02 0.4108328E+03 -3.3892 9 Ca++ 0.4309742E-07 0.6319824E-07 0.2531202E-02 12.1975 10 Mg++ 0.1865567E-10 0.5947528E-10 0.1445017E-05 8.8329 11 Fe++ 0.1102847E-12 0.2962980E-07 0.1653653E-02 6.6048 12 K+ 0.7044082E-04 0.7066466E-04 0.2761322E+01 5.6753 13 Na+ 0.8946991E-02 0.9353669E-02 0.2148983E+03 7.7787 14 Mn++ 0.1473098E-10 0.8681821E-09 0.4766498E-04 8.7307 15 HPO4-- 0.4458397E-06 0.4517375E-06 0.4332895E-01 13.2139 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2251662E+00 -.9376701E-02 -.2157895E+00 0.0000000E+00 2 H2O 0.5533778E+02 0.5539801E+02 -.6022648E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4023791E-03 0.2550589E-04 0.3768732E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3768746E-03 -.1416675E-08 -.3768732E-03 0.0000000E+00 7 Al+++ 0.4434283E-01 0.5803766E-04 0.4428479E-01 0.0000000E+00 8 H4SiO4 0.1416034E+00 0.4268555E-02 0.1373349E+00 0.0000000E+00 9 Ca++ 0.1565526E-01 0.6307098E-07 0.1565520E-01 0.0000000E+00 10 Mg++ 0.1079286E-01 0.5935552E-10 0.1079286E-01 0.0000000E+00 11 Fe++ 0.9696204E-02 0.2957014E-07 0.9696174E-02 0.0000000E+00 12 K+ 0.2887261E-02 0.7052237E-04 0.2816739E-02 0.0000000E+00 13 Na+ 0.1723013E-01 0.9334834E-02 0.7895295E-02 0.0000000E+00 14 Mn++ 0.2357876E-03 0.8664339E-09 0.2357867E-03 0.0000000E+00 15 HPO4-- 0.8047312E-04 0.4508279E-06 0.8002230E-04 0.0000000E+00 Chg. balance for solid moles: 0.2345E-16 Mass of aqueous solution: 0.998640E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 13.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7895E-02 -2.103 2.070 0.316 13.93 0.7947 andradite 0.7008E-03 -3.154 0.3561 -0.448 2.397 0.9252E-01 grossular 0.5458E-04 -4.263 0.2459E-01 -1.609 0.1655 0.6841E-02 apatite-OH 0.2667E-04 -4.574 0.1340E-01 -1.873 0.9017E-01 0.4258E-02 clinochlore 0.2159E-02 -2.666 1.200 0.079 8.074 0.4564 daphnite 0.1336E-02 -2.874 0.9534 -0.021 6.416 0.2889 chlorite-Mn 0.4716E-04 -4.326 0.3343E-01 -1.476 0.2250 0.1065E-01 hematite 0.7847E-03 -3.105 0.1253 -0.902 0.8434 0.2375E-01 microcline 0.2817E-02 -2.550 0.7840 -0.106 5.276 0.3063 prehnite-Fe 0.4396E-04 -4.357 0.1940E-01 -1.712 0.1305 0.6507E-02 stilbite 0.1317E-01 -1.880 9.280 0.968 62.45 4.328 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9277E+00 0.9277E+00 1.0000 -0.033 grossular 0.7226E-01 0.7226E-01 1.0000 -1.141 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 14.859436 g Volume = 6.319011 cm3 Porosity: 1.8726% V(tot) - V(min): 0.12059E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 13.5990000 g log = 1.1335 Original solution: 1000.0103000 g Original solution / Rock added: 73.54 (Water/Rock Ratio), log = 1.8665 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1631E-06 1.0073 0.1728E-06 0.1715E-06 CH4,gas 0.3059E-15 1.0129 0.3260E-15 0.3218E-15 H2,gas 0.2008E-05 1.0006 0.2114E-05 0.2113E-05 H2S,gas 0.6353E-14 0.9959 0.6656E-14 0.6683E-14 S2,gas 0.3530E-36 1.0000 0.3713E-36 0.3713E-36 CO,gas 0.8995E-16 1.0000 0.9462E-16 0.9462E-16 SO3,gas 0.9621E-40 1.0000 0.1012E-39 0.1012E-39 SO2,gas 0.7694E-23 1.0000 0.8094E-23 0.8094E-23 HCl,gas 0.4971E-17 1.0000 0.5229E-17 0.5229E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 -0.21232E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 137 prehnite-Fe 22.59 22.59 0.00 0.000 -0.12132E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.13 -8.76 -2.921 0.14962E+05 -6.762 3 CH4,gas 4.81 -12.68 -17.49 -4.372 0.29858E+05 -15.487 4 H2,gas 8.29 0.61 -7.67 -4.386 0.13105E+05 -5.675 5 H2S,gas -5.94 -22.12 -16.18 -8.088 0.27621E+05 -14.177 6 S2,gas -7.03 -45.46 -38.43 -5.912 0.65619E+05 -36.430 7 CO,gas 3.51 -14.51 -18.02 -5.546 0.30776E+05 -16.024 8 SO3,gas 17.43 -24.57 -41.99 -10.499 0.71705E+05 -39.995 9 SO2,gas 1.14 -23.96 -25.09 -6.691 0.42844E+05 -23.092 10 HCl,gas 5.48 -13.80 -19.28 -9.641 0.32923E+05 -17.282 11 acmite 7.74 7.30 -0.44 -0.046 0.74830E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.15 -4.40 -0.220 0.75203E+04 20 analcite 3.37 3.06 -0.31 -0.034 0.52898E+03 21 andalusite 5.06 0.73 -4.33 -0.433 0.73943E+04 26 annite 20.21 17.38 -2.83 -0.157 0.48265E+04 27 phlogopite 27.15 24.07 -3.08 -0.171 0.52587E+04 29 anorthite 12.80 9.54 -3.26 -0.251 0.55622E+04 35 aragonite 0.99 -2.93 -3.91 -1.305 0.66837E+04 36 brucite 12.58 8.83 -3.74 -0.749 0.63923E+04 37 calcite 0.83 -2.93 -3.76 -1.254 0.64223E+04 38 carnegieite-low 9.06 6.45 -2.61 -0.374 0.44642E+04 39 carnegieite-high 10.13 6.45 -3.68 -0.526 0.62911E+04 40 carpholite-Mg 8.65 6.18 -2.47 -0.165 0.42258E+04 41 carpholite-Fe 6.78 3.95 -2.84 -0.189 0.48415E+04 42 celadonite 5.40 3.01 -2.39 -0.141 0.40785E+04 43 celadonite-Fe 3.94 0.78 -3.15 -0.185 0.53839E+04 44 chrysotile 23.94 19.72 -4.22 -0.351 0.72007E+04 50 chloritoid-Mg 13.26 9.56 -3.70 -0.246 0.63118E+04 51 chloritoid-Fe 9.24 7.34 -1.90 -0.127 0.32477E+04 52 chloritoid-Mn 11.46 9.46 -2.00 -0.133 0.34161E+04 54 coesite -2.37 -3.39 -1.02 -0.340 0.17414E+04 59 corundum 8.43 4.12 -4.31 -0.392 0.73633E+04 61 cristobalite -2.55 -3.39 -0.84 -0.280 0.14342E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.06 -0.84 -0.139 0.14267E+04 67 diopside 16.22 14.25 -1.96 -0.196 0.33526E+04 68 hedenbergite 14.24 12.02 -2.22 -0.222 0.37914E+04 75 epidote 24.78 24.65 -0.13 -0.006 0.21845E+03 76 clinozoisite 22.92 20.41 -2.51 -0.114 0.42895E+04 77 epidote-Fe 29.94 28.89 -1.05 -0.055 0.17949E+04 78 fayalite 14.08 9.82 -4.26 -0.608 0.72714E+04 79 ferrosilite 11.19 6.43 -4.76 -0.476 0.81216E+04 83 gibbsite 4.10 2.06 -2.04 -0.291 0.34779E+04 84 glaucophane 23.11 19.06 -4.05 -0.109 0.69103E+04 87 greenalite 16.19 13.04 -3.16 -0.263 0.53925E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.06 -1.19 -0.119 0.20320E+04 96 julgoldite 70.57 66.86 -3.71 -0.096 0.63400E+04 97 kalsilite 7.62 4.35 -3.27 -0.468 0.55897E+04 98 kaolinite -1.27 -2.66 -1.38 -0.126 0.23636E+04 99 kyanite 4.93 0.73 -4.20 -0.420 0.71711E+04 101 laumontite 2.97 2.76 -0.21 -0.014 0.36336E+03 102 lawsonite 9.68 9.54 -0.14 -0.009 0.23604E+03 103 leucite 4.17 0.96 -3.21 -0.321 0.54814E+04 105 lizardite 23.29 19.72 -3.57 -0.297 0.60910E+04 107 magnetite 20.13 19.20 -0.93 -0.076 0.15886E+04 108 minnesotaite 10.46 6.26 -4.20 -0.247 0.71767E+04 110 magnesioferrite 26.26 21.43 -4.83 -0.394 0.82416E+04 113 margarite 17.45 13.66 -3.79 -0.152 0.64724E+04 120 muscovite 2.68 1.69 -0.99 -0.058 0.16904E+04 121 paragonite 4.34 3.79 -0.54 -0.032 0.92884E+03 122 nepheline 8.38 6.45 -1.93 -0.275 0.32922E+04 134 phlogopite-Na 29.73 26.17 -3.56 -0.198 0.60806E+04 136 prehnite 19.47 18.35 -1.12 -0.066 0.19087E+04 138 pumpellyite-Fe 46.47 45.36 -1.11 -0.025 0.18924E+04 139 pumpellyite-Mg 49.19 47.59 -1.60 -0.036 0.27384E+04 145 pyroxmangite 7.42 5.34 -2.07 -0.415 0.35422E+04 146 pyrophyllite -6.10 -9.44 -3.34 -0.209 0.56991E+04 147 quartz -2.98 -3.39 -0.41 -0.136 0.69528E+03 152 rhodonite 7.46 5.34 -2.12 -0.424 0.36214E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.73 -4.59 -0.459 0.78365E+04 164 stilpnomelane-Fe 13.18 12.87 -0.31 -0.009 0.52976E+03 165 stilpnomelane-Mg 27.60 24.01 -3.59 -0.107 0.61246E+04 171 talc 16.55 12.94 -3.61 -0.212 0.61667E+04 174 tephroite 18.11 14.07 -4.04 -0.577 0.68994E+04 177 topaz-H 4.67 0.73 -3.94 -0.358 0.67202E+04 178 tridymite -2.61 -3.39 -0.77 -0.258 0.13226E+04 187 wairakite 4.06 2.76 -1.30 -0.076 0.22142E+04 188 walstromite 11.53 8.81 -2.72 -0.544 0.46435E+04 189 wollastonite 10.48 8.81 -1.67 -0.335 0.28574E+04 190 pseudo-wollastonite 11.02 8.81 -2.21 -0.442 0.37761E+04 191 zoisite 22.96 20.41 -2.55 -0.116 0.43620E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.62 -4.07 -0.251 0.69411E+04 195 beidellite-K -1.44 -5.76 -4.33 -0.265 0.73925E+04 196 beidellite-Mg -1.71 -6.18 -4.47 -0.277 0.76376E+04 197 beidellite-Na -1.26 -5.07 -3.81 -0.234 0.65112E+04 199 chalcedony -2.79 -3.39 -0.59 -0.198 0.10156E+04 201 montmorillonite-Ca -2.21 -5.19 -2.97 -0.184 0.50785E+04 202 montmorillonite-K -2.16 -5.33 -3.17 -0.194 0.54077E+04 203 montmorillonite-Mg -2.40 -5.74 -3.34 -0.207 0.57061E+04 204 montmorillonite-Na -1.96 -4.63 -2.67 -0.164 0.45646E+04 205 nontronite-Ca 3.28 2.85 -0.43 -0.028 0.73052E+03 206 nontronite-H 2.60 0.84 -1.76 -0.118 0.29992E+04 207 nontronite-K 3.40 2.71 -0.69 -0.044 0.11811E+04 208 nontronite-Mg 3.14 2.30 -0.84 -0.055 0.14387E+04 209 nontronite-Na 3.58 3.41 -0.18 -0.011 0.30156E+03 224 tobermorite 9.84 6.77 -3.07 -0.837 0.52380E+04 233 boehmite 4.43 2.06 -2.37 -0.395 0.40452E+04 235 ferrous-oxide 9.82 6.60 -3.22 -0.805 0.54971E+04 240 silica-amorphous -2.08 -3.39 -1.31 -0.436 0.22358E+04 242 an20ab80 2.08 1.65 -0.43 -0.033 0.74082E+03 243 an25ab75 2.71 2.14 -0.57 -0.044 0.97393E+03 244 an30ab70 3.34 2.63 -0.71 -0.055 0.12154E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 13.5990000 g New total amount of reactant added: 13.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8621E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 13.9990000 Water: Moles liquid = 0.5539E+02 kg liquid = 0.9979E+00 Moles total = 0.5533E+02 kg total = 0.9968E+00 Activity = 1.0000 Stoichiometric ionic strength = .5101610E-02 Osmotic coef. = 0.9621 True ionic strength = .9050124E-02 Chg. balance for total moles = 0.8621E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14844E-09 -9.8284 0.13036E-09 -9.8848 0.87822E+00 -0.0564 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12077E-03 -3.9180 0.87547E+00 -0.0578 4 SO4-- 0.25540E-04 -4.5928 0.15931E-04 -4.7978 0.62377E+00 -0.2050 5 HCO3- 0.65559E-05 -5.1834 0.57438E-05 -5.2408 0.87613E+00 -0.0574 6 HS- 0.66546E-12 -12.1769 0.58264E-12 -12.2346 0.87554E+00 -0.0577 7 Al+++ 0.72517E-27 -27.1396 0.25466E-27 -27.5940 0.35118E+00 -0.4545 8 H4SiO4 0.40813E-03 -3.3892 0.40813E-03 -3.3892 0.10000E+01 0.0000 9 Ca++ 0.43097E-07 -7.3655 0.26781E-07 -7.5722 0.62141E+00 -0.2066 10 Mg++ 0.18656E-10 -10.7292 0.11565E-10 -10.9368 0.61994E+00 -0.2077 11 Fe++ 0.11028E-12 -12.9575 0.68408E-13 -13.1649 0.62029E+00 -0.2074 12 K+ 0.70441E-04 -4.1522 0.61723E-04 -4.2096 0.87624E+00 -0.0574 13 Na+ 0.89470E-02 -2.0483 0.78322E-02 -2.1061 0.87540E+00 -0.0578 14 Mn++ 0.14731E-10 -10.8318 0.91414E-11 -11.0390 0.62055E+00 -0.2072 15 HPO4-- 0.44584E-06 -6.3508 0.27812E-06 -6.5558 0.62381E+00 -0.2049 16 HSiO3- 0.34891E-02 -2.4573 0.30546E-02 -2.5150 0.87547E+00 -0.0578 17 Ca(HSiO3)+ 0.20915E-08 -8.6795 0.18329E-08 -8.7369 0.87634E+00 -0.0573 18 Mg(HSiO3)+ 0.11241E-11 -11.9492 0.98505E-12 -12.0065 0.87634E+00 -0.0573 19 NaHSiO3,aq 0.37997E-03 -3.4203 0.37997E-03 -3.4203 0.10000E+01 0.0000 20 AlO+ 0.22075E-14 -14.6561 0.19345E-14 -14.7134 0.87634E+00 -0.0573 22 HAlO2,aq 0.29695E-08 -8.5273 0.29695E-08 -8.5273 0.10000E+01 0.0000 23 AlO2- 0.58152E-04 -4.2354 0.50862E-04 -4.2936 0.87465E+00 -0.0582 24 CH4,aq 0.20646E-18 -18.6852 0.20613E-18 -18.6859 0.99843E+00 -0.0007 29 CO,aq 0.59927E-19 -19.2224 0.59927E-19 -19.2224 0.10000E+01 0.0000 30 CO2,aq 0.15121E-08 -8.8204 0.15097E-08 -8.8211 0.99843E+00 -0.0007 31 CO3-2 0.65382E-05 -5.1845 0.40738E-05 -5.3900 0.62308E+00 -0.2055 32 CaCO3,aq 0.13362E-08 -8.8741 0.13362E-08 -8.8741 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44229E-11 -11.3543 0.38760E-11 -11.4116 0.87634E+00 -0.0573 34 CaCl+ 0.58812E-11 -11.2305 0.51540E-11 -11.2879 0.87634E+00 -0.0573 35 CaCl2,aq 0.14493E-15 -15.8388 0.14493E-15 -15.8388 0.10000E+01 0.0000 36 CaOH+ 0.16530E-07 -7.7817 0.14486E-07 -7.8391 0.87634E+00 -0.0573 37 CaSO4,aq 0.13293E-09 -9.8764 0.13293E-09 -9.8764 0.10000E+01 0.0000 38 HCl,aq 0.29614E-14 -14.5285 0.29614E-14 -14.5285 0.10000E+01 0.0000 43 FeCl+ 0.14683E-16 -16.8332 0.12868E-16 -16.8905 0.87634E+00 -0.0573 46 FeO,aq 0.15918E-09 -9.7981 0.15918E-09 -9.7981 0.10000E+01 0.0000 47 FeOH+ 0.19852E-10 -10.7022 0.17397E-10 -10.7595 0.87634E+00 -0.0573 48 HFeO2- 0.15002E-07 -7.8239 0.13134E-07 -7.8816 0.87547E+00 -0.0578 49 FeO+ 0.12305E-14 -14.9099 0.10784E-14 -14.9672 0.87634E+00 -0.0573 51 FeO2- 0.14245E-07 -7.8463 0.12471E-07 -7.9041 0.87547E+00 -0.0578 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.15437E-08 -8.8115 0.15412E-08 -8.8121 0.99843E+00 -0.0007 54 KCl,aq 0.13199E-09 -9.8795 0.13199E-09 -9.8795 0.10000E+01 0.0000 55 KHSO4,aq 0.34302E-18 -18.4647 0.34302E-18 -18.4647 0.10000E+01 0.0000 56 KOH,aq 0.20641E-06 -6.6853 0.20641E-06 -6.6853 0.10000E+01 0.0000 57 KSO4- 0.17304E-07 -7.7619 0.15149E-07 -7.8196 0.87547E+00 -0.0578 58 MgCO3,aq 0.14419E-12 -12.8411 0.14419E-12 -12.8411 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19477E-14 -14.7105 0.17068E-14 -14.7678 0.87634E+00 -0.0573 60 MgCl+ 0.23057E-14 -14.6372 0.20206E-14 -14.6945 0.87634E+00 -0.0573 61 MgOH+ 0.39547E-10 -10.4029 0.34657E-10 -10.4602 0.87634E+00 -0.0573 63 MnO,aq 0.56783E-09 -9.2458 0.56783E-09 -9.2458 0.10000E+01 0.0000 64 MnOH+ 0.24643E-09 -9.6083 0.21596E-09 -9.6656 0.87634E+00 -0.0573 65 MnO2-2 0.18546E-11 -11.7318 0.11555E-11 -11.9372 0.62308E+00 -0.2055 66 HMnO2- 0.37280E-10 -10.4285 0.32638E-10 -10.4863 0.87547E+00 -0.0578 69 MnCl+ 0.76246E-14 -14.1178 0.66818E-14 -14.1751 0.87634E+00 -0.0573 70 MnSO4,aq 0.41271E-13 -13.3844 0.41271E-13 -13.3844 0.10000E+01 0.0000 71 NaCl,aq 0.30886E-06 -6.5102 0.30886E-06 -6.5102 0.10000E+01 0.0000 72 NaOH,aq 0.26400E-04 -4.5784 0.26400E-04 -4.5784 0.10000E+01 0.0000 74 OH- 0.52607E-02 -2.2790 0.46013E-02 -2.3371 0.87465E+00 -0.0582 79 HPO3-2 0.21729E-17 -17.6630 0.13539E-17 -17.8684 0.62308E+00 -0.2055 82 H3PO4,aq 0.30429E-16 -16.5167 0.30429E-16 -16.5167 0.10000E+01 0.0000 83 H2PO4- 0.72571E-09 -9.1392 0.63565E-09 -9.1968 0.87590E+00 -0.0575 84 PO4-3 0.51721E-08 -8.2863 0.18631E-08 -8.7298 0.36023E+00 -0.4434 87 H2P2O7-2 0.50753E-19 -19.2945 0.31623E-19 -19.5000 0.62308E+00 -0.2055 88 HP2O7-3 0.14158E-15 -15.8490 0.49741E-16 -16.3033 0.35132E+00 -0.4543 89 P2O7-4 0.58805E-15 -15.2306 0.94130E-16 -16.0263 0.16007E+00 -0.7957 90 H2S,aq 0.22857E-15 -15.6410 0.22821E-15 -15.6417 0.99843E+00 -0.0007 97 SO3-2 0.53329E-14 -14.2730 0.33478E-14 -14.4752 0.62776E+00 -0.2022 98 HSO3- 0.29173E-16 -16.5350 0.25540E-16 -16.5928 0.87547E+00 -0.0578 99 HSO4- 0.21978E-11 -11.6580 0.19270E-11 -11.7151 0.87677E+00 -0.0571 Charge balance for all species = 0.8513E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1484402E-09 -.9395616E-02 -.9464022E+01 0.0000 2 H2O 0.1000000E+01 0.5550978E+02 0.9993712E+06 0.0000 3 Cl- 0.1379494E-03 0.1382584E-03 0.4898468E+01 5.9668 4 SO4-- 0.2553957E-04 0.2555843E-04 0.2453577E+01 14.9719 5 HCO3- 0.6555891E-05 0.1309692E-04 0.7986148E+00 4.6440 6 HS- 0.6654621E-12 -.1419533E-08 -.4691608E-04 -2.3498 7 Al+++ 0.7251670E-27 0.5815474E-04 0.1568076E+01 2.0605 8 H4SiO4 0.4081332E-03 0.4277166E-02 0.4108326E+03 -3.3892 9 Ca++ 0.4309747E-07 0.6319836E-07 0.2531207E-02 12.1975 10 Mg++ 0.1865569E-10 0.5947533E-10 0.1445018E-05 8.8329 11 Fe++ 0.1102848E-12 0.2962979E-07 0.1653652E-02 6.6048 12 K+ 0.7044086E-04 0.7066470E-04 0.2761324E+01 5.6753 13 Na+ 0.8946995E-02 0.9353674E-02 0.2148984E+03 7.7787 14 Mn++ 0.1473100E-10 0.8681823E-09 0.4766499E-04 8.7307 15 HPO4-- 0.4458393E-06 0.4517371E-06 0.4332891E-01 13.2139 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2317896E+00 -.9376301E-02 -.2224133E+00 0.0000000E+00 2 H2O 0.5533277E+02 0.5539567E+02 -.6290388E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4134645E-03 0.2550589E-04 0.3879586E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3879600E-03 -.1416615E-08 -.3879586E-03 0.0000000E+00 7 Al+++ 0.4564712E-01 0.5803519E-04 0.4558909E-01 0.0000000E+00 8 H4SiO4 0.1457685E+00 0.4268374E-02 0.1415002E+00 0.0000000E+00 9 Ca++ 0.1611532E-01 0.6306844E-07 0.1611525E-01 0.0000000E+00 10 Mg++ 0.1111032E-01 0.5935306E-10 0.1111032E-01 0.0000000E+00 11 Fe++ 0.9981407E-02 0.2956888E-07 0.9981378E-02 0.0000000E+00 12 K+ 0.2972187E-02 0.7051943E-04 0.2901667E-02 0.0000000E+00 13 Na+ 0.1773223E-01 0.9334445E-02 0.8397781E-02 0.0000000E+00 14 Mn++ 0.2427230E-03 0.8663975E-09 0.2427221E-03 0.0000000E+00 15 HPO4-- 0.8284015E-04 0.4508085E-06 0.8238935E-04 0.0000000E+00 Chg. balance for solid moles: -.2168E-18 Mass of aqueous solution: 0.998598E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 13.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8398E-02 -2.076 2.202 0.343 14.39 0.8453 andradite 0.8018E-03 -3.096 0.4075 -0.390 2.663 0.1059 grossular 0.6245E-04 -4.204 0.2813E-01 -1.551 0.1839 0.7827E-02 apatite-OH 0.2746E-04 -4.561 0.1380E-01 -1.860 0.9018E-01 0.4384E-02 clinochlore 0.2222E-02 -2.653 1.235 0.092 8.073 0.4698 daphnite 0.1376E-02 -2.862 0.9815 -0.008 6.415 0.2974 chlorite-Mn 0.4854E-04 -4.314 0.3442E-01 -1.463 0.2250 0.1097E-01 hematite 0.7670E-03 -3.115 0.1225 -0.912 0.8007 0.2322E-01 microcline 0.2902E-02 -2.537 0.8077 -0.093 5.279 0.3155 prehnite-Fe -.3407E-04 1.000 -.1503E-01 1.000 -.9826E-01 -.5043E-02 stilbite 0.1345E-01 -1.871 9.481 0.977 61.97 4.422 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9277E+00 0.9277E+00 1.0000 -0.033 grossular 0.7226E-01 0.7226E-01 1.0000 -1.141 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 prehnite-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 15.298323 g Volume = 6.497240 cm3 Porosity: 1.5510% V(tot) - V(min): 0.10236E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 13.9990000 g log = 1.1461 Original solution: 1000.0103000 g Original solution / Rock added: 71.43 (Water/Rock Ratio), log = 1.8539 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1631E-06 1.0073 0.1728E-06 0.1716E-06 CH4,gas 0.3059E-15 1.0129 0.3260E-15 0.3218E-15 H2,gas 0.2008E-05 1.0006 0.2114E-05 0.2113E-05 H2S,gas 0.6353E-14 0.9959 0.6656E-14 0.6683E-14 S2,gas 0.3530E-36 1.0000 0.3713E-36 0.3713E-36 CO,gas 0.8995E-16 1.0000 0.9463E-16 0.9463E-16 SO3,gas 0.9622E-40 1.0000 0.1012E-39 0.1012E-39 SO2,gas 0.7694E-23 1.0000 0.8094E-23 0.8094E-23 HCl,gas 0.4971E-17 1.0000 0.5229E-17 0.5229E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.13 -8.76 -2.921 0.14962E+05 -6.762 3 CH4,gas 4.81 -12.68 -17.49 -4.372 0.29858E+05 -15.487 4 H2,gas 8.29 0.61 -7.67 -4.386 0.13105E+05 -5.675 5 H2S,gas -5.94 -22.12 -16.18 -8.088 0.27621E+05 -14.177 6 S2,gas -7.03 -45.46 -38.43 -5.912 0.65619E+05 -36.430 7 CO,gas 3.51 -14.51 -18.02 -5.546 0.30775E+05 -16.024 8 SO3,gas 17.43 -24.57 -41.99 -10.499 0.71705E+05 -39.995 9 SO2,gas 1.14 -23.96 -25.09 -6.691 0.42844E+05 -23.092 10 HCl,gas 5.48 -13.80 -19.28 -9.641 0.32923E+05 -17.282 11 acmite 7.74 7.30 -0.44 -0.046 0.74830E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.15 -4.40 -0.220 0.75203E+04 20 analcite 3.37 3.06 -0.31 -0.034 0.52898E+03 21 andalusite 5.06 0.73 -4.33 -0.433 0.73943E+04 26 annite 20.21 17.38 -2.83 -0.157 0.48265E+04 27 phlogopite 27.15 24.07 -3.08 -0.171 0.52587E+04 29 anorthite 12.80 9.54 -3.26 -0.251 0.55622E+04 35 aragonite 0.99 -2.93 -3.91 -1.305 0.66836E+04 36 brucite 12.58 8.83 -3.74 -0.749 0.63923E+04 37 calcite 0.83 -2.93 -3.76 -1.254 0.64223E+04 38 carnegieite-low 9.06 6.45 -2.61 -0.374 0.44642E+04 39 carnegieite-high 10.13 6.45 -3.68 -0.526 0.62911E+04 40 carpholite-Mg 8.65 6.18 -2.47 -0.165 0.42258E+04 41 carpholite-Fe 6.78 3.95 -2.84 -0.189 0.48415E+04 42 celadonite 5.40 3.01 -2.39 -0.141 0.40785E+04 43 celadonite-Fe 3.94 0.78 -3.15 -0.185 0.53839E+04 44 chrysotile 23.94 19.72 -4.22 -0.351 0.72007E+04 50 chloritoid-Mg 13.26 9.56 -3.70 -0.246 0.63118E+04 51 chloritoid-Fe 9.24 7.34 -1.90 -0.127 0.32477E+04 52 chloritoid-Mn 11.46 9.46 -2.00 -0.133 0.34161E+04 54 coesite -2.37 -3.39 -1.02 -0.340 0.17414E+04 59 corundum 8.43 4.12 -4.31 -0.392 0.73633E+04 61 cristobalite -2.55 -3.39 -0.84 -0.280 0.14342E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.06 -0.84 -0.139 0.14267E+04 67 diopside 16.22 14.25 -1.96 -0.196 0.33526E+04 68 hedenbergite 14.24 12.02 -2.22 -0.222 0.37914E+04 75 epidote 24.78 24.65 -0.13 -0.006 0.21845E+03 76 clinozoisite 22.92 20.41 -2.51 -0.114 0.42895E+04 77 epidote-Fe 29.94 28.89 -1.05 -0.055 0.17949E+04 78 fayalite 14.08 9.82 -4.26 -0.608 0.72714E+04 79 ferrosilite 11.19 6.43 -4.76 -0.476 0.81216E+04 83 gibbsite 4.10 2.06 -2.04 -0.291 0.34779E+04 84 glaucophane 23.11 19.06 -4.05 -0.109 0.69103E+04 87 greenalite 16.19 13.04 -3.16 -0.263 0.53925E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.06 -1.19 -0.119 0.20320E+04 96 julgoldite 70.57 66.86 -3.71 -0.096 0.63400E+04 97 kalsilite 7.62 4.35 -3.27 -0.468 0.55897E+04 98 kaolinite -1.27 -2.66 -1.38 -0.126 0.23636E+04 99 kyanite 4.93 0.73 -4.20 -0.420 0.71711E+04 101 laumontite 2.97 2.76 -0.21 -0.014 0.36336E+03 102 lawsonite 9.68 9.54 -0.14 -0.009 0.23604E+03 103 leucite 4.17 0.96 -3.21 -0.321 0.54814E+04 105 lizardite 23.29 19.72 -3.57 -0.297 0.60910E+04 107 magnetite 20.13 19.20 -0.93 -0.076 0.15886E+04 108 minnesotaite 10.46 6.26 -4.20 -0.247 0.71767E+04 110 magnesioferrite 26.26 21.43 -4.83 -0.394 0.82416E+04 113 margarite 17.45 13.66 -3.79 -0.152 0.64724E+04 120 muscovite 2.68 1.69 -0.99 -0.058 0.16904E+04 121 paragonite 4.34 3.79 -0.54 -0.032 0.92884E+03 122 nepheline 8.38 6.45 -1.93 -0.275 0.32922E+04 134 phlogopite-Na 29.73 26.17 -3.56 -0.198 0.60806E+04 136 prehnite 19.47 18.35 -1.12 -0.066 0.19087E+04 137 prehnite-Fe 22.59 22.59 0.00 0.000 -0.12132E-10 138 pumpellyite-Fe 46.47 45.36 -1.11 -0.025 0.18924E+04 139 pumpellyite-Mg 49.19 47.59 -1.60 -0.036 0.27384E+04 145 pyroxmangite 7.42 5.34 -2.07 -0.415 0.35422E+04 146 pyrophyllite -6.10 -9.44 -3.34 -0.209 0.56991E+04 147 quartz -2.98 -3.39 -0.41 -0.136 0.69528E+03 152 rhodonite 7.46 5.34 -2.12 -0.424 0.36214E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.73 -4.59 -0.459 0.78365E+04 164 stilpnomelane-Fe 13.18 12.87 -0.31 -0.009 0.52976E+03 165 stilpnomelane-Mg 27.60 24.01 -3.59 -0.107 0.61246E+04 171 talc 16.55 12.94 -3.61 -0.212 0.61667E+04 174 tephroite 18.11 14.07 -4.04 -0.577 0.68994E+04 177 topaz-H 4.67 0.73 -3.94 -0.358 0.67202E+04 178 tridymite -2.61 -3.39 -0.77 -0.258 0.13226E+04 187 wairakite 4.06 2.76 -1.30 -0.076 0.22142E+04 188 walstromite 11.53 8.81 -2.72 -0.544 0.46435E+04 189 wollastonite 10.48 8.81 -1.67 -0.335 0.28574E+04 190 pseudo-wollastonite 11.02 8.81 -2.21 -0.442 0.37761E+04 191 zoisite 22.96 20.41 -2.55 -0.116 0.43620E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.62 -4.07 -0.251 0.69411E+04 195 beidellite-K -1.44 -5.76 -4.33 -0.265 0.73925E+04 196 beidellite-Mg -1.71 -6.18 -4.47 -0.277 0.76376E+04 197 beidellite-Na -1.26 -5.07 -3.81 -0.234 0.65112E+04 199 chalcedony -2.79 -3.39 -0.59 -0.198 0.10156E+04 201 montmorillonite-Ca -2.21 -5.19 -2.97 -0.184 0.50785E+04 202 montmorillonite-K -2.16 -5.33 -3.17 -0.194 0.54077E+04 203 montmorillonite-Mg -2.40 -5.74 -3.34 -0.207 0.57061E+04 204 montmorillonite-Na -1.96 -4.63 -2.67 -0.164 0.45646E+04 205 nontronite-Ca 3.28 2.85 -0.43 -0.028 0.73052E+03 206 nontronite-H 2.60 0.84 -1.76 -0.118 0.29992E+04 207 nontronite-K 3.40 2.71 -0.69 -0.044 0.11811E+04 208 nontronite-Mg 3.14 2.30 -0.84 -0.055 0.14387E+04 209 nontronite-Na 3.58 3.41 -0.18 -0.011 0.30156E+03 224 tobermorite 9.84 6.77 -3.07 -0.837 0.52380E+04 233 boehmite 4.43 2.06 -2.37 -0.395 0.40452E+04 235 ferrous-oxide 9.82 6.60 -3.22 -0.805 0.54971E+04 240 silica-amorphous -2.08 -3.39 -1.31 -0.436 0.22358E+04 242 an20ab80 2.08 1.65 -0.43 -0.033 0.74082E+03 243 an25ab75 2.71 2.14 -0.57 -0.044 0.97393E+03 244 an30ab70 3.34 2.63 -0.71 -0.055 0.12154E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 13.9990000 Water: Moles liquid = 0.5539E+02 kg liquid = 0.9979E+00 Moles total = 0.5533E+02 kg total = 0.9968E+00 Activity = 1.0000 Stoichiometric ionic strength = .5106335E-02 Osmotic coef. = 0.9621 True ionic strength = .9072869E-02 Chg. balance for total moles = 0.8621E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14870E-09 -9.8277 0.13057E-09 -9.8841 0.87811E+00 -0.0565 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12075E-03 -3.9181 0.87536E+00 -0.0578 4 SO4-- 0.25540E-04 -4.5928 0.15923E-04 -4.7980 0.62346E+00 -0.2052 5 HCO3- 0.65599E-05 -5.1831 0.57466E-05 -5.2406 0.87602E+00 -0.0575 6 HS- 0.70332E-12 -12.1528 0.61571E-12 -12.2106 0.87543E+00 -0.0578 7 Al+++ 0.70580E-27 -27.1513 0.24758E-27 -27.6063 0.35078E+00 -0.4550 8 H4SiO4 0.41254E-03 -3.3845 0.41254E-03 -3.3845 0.10000E+01 0.0000 9 Ca++ 0.42863E-07 -7.3679 0.26622E-07 -7.5748 0.62110E+00 -0.2068 10 Mg++ 0.18852E-10 -10.7246 0.11681E-10 -10.9325 0.61962E+00 -0.2079 11 Fe++ 0.11145E-12 -12.9529 0.69094E-13 -13.1606 0.61997E+00 -0.2076 12 K+ 0.70618E-04 -4.1511 0.61871E-04 -4.2085 0.87613E+00 -0.0574 13 Na+ 0.89696E-02 -2.0472 0.78509E-02 -2.1051 0.87529E+00 -0.0578 14 Mn++ 0.14886E-10 -10.8272 0.92331E-11 -11.0347 0.62024E+00 -0.2074 15 HPO4-- 0.45148E-06 -6.3454 0.28150E-06 -6.5505 0.62350E+00 -0.2052 16 HSiO3- 0.35215E-02 -2.4533 0.30826E-02 -2.5111 0.87536E+00 -0.0578 17 Ca(HSiO3)+ 0.20984E-08 -8.6781 0.18387E-08 -8.7355 0.87623E+00 -0.0574 18 Mg(HSiO3)+ 0.11459E-11 -11.9409 0.10041E-11 -11.9982 0.87623E+00 -0.0574 19 NaHSiO3,aq 0.38438E-03 -3.4152 0.38438E-03 -3.4152 0.10000E+01 0.0000 20 AlO+ 0.21395E-14 -14.6697 0.18747E-14 -14.7271 0.87623E+00 -0.0574 22 HAlO2,aq 0.28730E-08 -8.5417 0.28730E-08 -8.5417 0.10000E+01 0.0000 23 AlO2- 0.56179E-04 -4.2504 0.49131E-04 -4.3086 0.87454E+00 -0.0582 24 CH4,aq 0.21839E-18 -18.6608 0.21805E-18 -18.6614 0.99843E+00 -0.0007 29 CO,aq 0.60871E-19 -19.2156 0.60871E-19 -19.2156 0.10000E+01 0.0000 30 CO2,aq 0.15152E-08 -8.8195 0.15129E-08 -8.8202 0.99843E+00 -0.0007 31 CO3-2 0.65341E-05 -5.1848 0.40693E-05 -5.3905 0.62277E+00 -0.2057 32 CaCO3,aq 0.13268E-08 -8.8772 0.13268E-08 -8.8772 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43993E-11 -11.3566 0.38548E-11 -11.4140 0.87623E+00 -0.0574 34 CaCl+ 0.58462E-11 -11.2331 0.51226E-11 -11.2905 0.87623E+00 -0.0574 35 CaCl2,aq 0.14403E-15 -15.8416 0.14403E-15 -15.8416 0.10000E+01 0.0000 36 CaOH+ 0.16407E-07 -7.7850 0.14377E-07 -7.8423 0.87623E+00 -0.0574 37 CaSO4,aq 0.13208E-09 -9.8792 0.13208E-09 -9.8792 0.10000E+01 0.0000 38 HCl,aq 0.29658E-14 -14.5279 0.29658E-14 -14.5279 0.10000E+01 0.0000 43 FeCl+ 0.14831E-16 -16.8288 0.12995E-16 -16.8862 0.87623E+00 -0.0574 46 FeO,aq 0.16026E-09 -9.7952 0.16026E-09 -9.7952 0.10000E+01 0.0000 47 FeOH+ 0.20021E-10 -10.6985 0.17543E-10 -10.7559 0.87623E+00 -0.0574 48 HFeO2- 0.15081E-07 -7.8216 0.13201E-07 -7.8794 0.87536E+00 -0.0578 49 FeO+ 0.12327E-14 -14.9091 0.10801E-14 -14.9665 0.87623E+00 -0.0574 51 FeO2- 0.14224E-07 -7.8470 0.12451E-07 -7.9048 0.87536E+00 -0.0578 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.15647E-08 -8.8056 0.15622E-08 -8.8063 0.99843E+00 -0.0007 54 KCl,aq 0.13229E-09 -9.8785 0.13229E-09 -9.8785 0.10000E+01 0.0000 55 KHSO4,aq 0.34422E-18 -18.4632 0.34422E-18 -18.4632 0.10000E+01 0.0000 56 KOH,aq 0.20657E-06 -6.6849 0.20657E-06 -6.6849 0.10000E+01 0.0000 57 KSO4- 0.17339E-07 -7.7610 0.15178E-07 -7.8188 0.87536E+00 -0.0578 58 MgCO3,aq 0.14548E-12 -12.8372 0.14548E-12 -12.8372 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19684E-14 -14.7059 0.17248E-14 -14.7633 0.87623E+00 -0.0574 60 MgCl+ 0.23288E-14 -14.6329 0.20406E-14 -14.6903 0.87623E+00 -0.0574 61 MgOH+ 0.39885E-10 -10.3992 0.34948E-10 -10.4566 0.87623E+00 -0.0574 63 MnO,aq 0.57169E-09 -9.2428 0.57169E-09 -9.2428 0.10000E+01 0.0000 64 MnOH+ 0.24854E-09 -9.6046 0.21778E-09 -9.6620 0.87623E+00 -0.0574 65 MnO2-2 0.18621E-11 -11.7300 0.11596E-11 -11.9357 0.62277E+00 -0.2057 66 HMnO2- 0.37478E-10 -10.4262 0.32806E-10 -10.4840 0.87536E+00 -0.0578 69 MnCl+ 0.77010E-14 -14.1135 0.67479E-14 -14.1708 0.87623E+00 -0.0574 70 MnSO4,aq 0.41665E-13 -13.3802 0.41665E-13 -13.3802 0.10000E+01 0.0000 71 NaCl,aq 0.30956E-06 -6.5093 0.30956E-06 -6.5093 0.10000E+01 0.0000 72 NaOH,aq 0.26420E-04 -4.5781 0.26420E-04 -4.5781 0.10000E+01 0.0000 74 OH- 0.52529E-02 -2.2796 0.45939E-02 -2.3378 0.87454E+00 -0.0582 79 HPO3-2 0.22304E-17 -17.6516 0.13890E-17 -17.8573 0.62277E+00 -0.2057 82 H3PO4,aq 0.30898E-16 -16.5101 0.30898E-16 -16.5101 0.10000E+01 0.0000 83 H2PO4- 0.73581E-09 -9.1332 0.64441E-09 -9.1908 0.87579E+00 -0.0576 84 PO4-3 0.52322E-08 -8.2813 0.18828E-08 -8.7252 0.35985E+00 -0.4439 87 H2P2O7-2 0.52188E-19 -19.2824 0.32501E-19 -19.4881 0.62277E+00 -0.2057 88 HP2O7-3 0.14545E-15 -15.8373 0.51040E-16 -16.2921 0.35092E+00 -0.4548 89 P2O7-4 0.60363E-15 -15.2192 0.96433E-16 -16.0158 0.15976E+00 -0.7965 90 H2S,aq 0.24193E-15 -15.6163 0.24155E-15 -15.6170 0.99843E+00 -0.0007 97 SO3-2 0.54054E-14 -14.2672 0.33917E-14 -14.4696 0.62745E+00 -0.2024 98 HSO3- 0.29607E-16 -16.5286 0.25917E-16 -16.5864 0.87536E+00 -0.0578 99 HSO4- 0.22005E-11 -11.6575 0.19291E-11 -11.7146 0.87667E+00 -0.0572 Charge balance for all species = 0.8579E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1486971E-09 -.9416860E-02 -.9485386E+01 0.0000 2 H2O 0.1000000E+01 0.5550974E+02 0.9993667E+06 0.0000 3 Cl- 0.1379489E-03 0.1382586E-03 0.4898456E+01 5.9661 4 SO4-- 0.2553956E-04 0.2555845E-04 0.2453570E+01 14.9703 5 HCO3- 0.6559946E-05 0.1309694E-04 0.7986128E+00 4.6436 6 HS- 0.7033243E-12 -.1411605E-08 -.4665388E-04 -2.3265 7 Al+++ 0.7057989E-27 0.5618226E-04 0.1514884E+01 2.0462 8 H4SiO4 0.4125435E-03 0.4318467E-02 0.4147982E+03 -3.3845 9 Ca++ 0.4286279E-07 0.6283760E-07 0.2516748E-02 12.1935 10 Mg++ 0.1885238E-10 0.6003260E-10 0.1458552E-05 8.8358 11 Fe++ 0.1114474E-12 0.2968940E-07 0.1656973E-02 6.6077 12 K+ 0.7061838E-04 0.7084243E-04 0.2768258E+01 5.6756 13 Na+ 0.8969563E-02 0.9380670E-02 0.2155179E+03 7.7791 14 Mn++ 0.1488628E-10 0.8744983E-09 0.4801158E-04 8.7336 15 HPO4-- 0.4514842E-06 0.4574522E-06 0.4387692E-01 13.2178 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2317896E+00 -.9397490E-02 -.2223921E+00 0.0000000E+00 2 H2O 0.5533277E+02 0.5539556E+02 -.6279095E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4134645E-03 0.2550588E-04 0.3879586E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3879600E-03 -.1408701E-08 -.3879586E-03 0.0000000E+00 7 Al+++ 0.4564712E-01 0.5606670E-04 0.4559106E-01 0.0000000E+00 8 H4SiO4 0.1457685E+00 0.4309585E-02 0.1414590E+00 0.0000000E+00 9 Ca++ 0.1611532E-01 0.6270835E-07 0.1611526E-01 0.0000000E+00 10 Mg++ 0.1111032E-01 0.5990912E-10 0.1111032E-01 0.0000000E+00 11 Fe++ 0.9981407E-02 0.2962833E-07 0.9981378E-02 0.0000000E+00 12 K+ 0.2972187E-02 0.7069671E-04 0.2901490E-02 0.0000000E+00 13 Na+ 0.1773223E-01 0.9361375E-02 0.8370852E-02 0.0000000E+00 14 Mn++ 0.2427230E-03 0.8726995E-09 0.2427221E-03 0.0000000E+00 15 HPO4-- 0.8284015E-04 0.4565112E-06 0.8238364E-04 0.0000000E+00 Chg. balance for solid moles: 0.3212E-16 Mass of aqueous solution: 0.998600E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 13.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8371E-02 -2.077 2.195 0.341 14.35 0.8426 andradite 0.7823E-03 -3.107 0.3975 -0.401 2.599 0.1033 grossular 0.5895E-04 -4.230 0.2655E-01 -1.576 0.1736 0.7388E-02 apatite-OH 0.2746E-04 -4.561 0.1379E-01 -1.860 0.9018E-01 0.4383E-02 clinochlore 0.2222E-02 -2.653 1.235 0.092 8.075 0.4698 daphnite 0.1376E-02 -2.862 0.9815 -0.008 6.417 0.2974 chlorite-Mn 0.4854E-04 -4.314 0.3442E-01 -1.463 0.2250 0.1097E-01 hematite 0.7696E-03 -3.114 0.1229 -0.910 0.8035 0.2329E-01 microcline 0.2901E-02 -2.537 0.8076 -0.093 5.280 0.3155 stilbite 0.1345E-01 -1.871 9.481 0.977 61.99 4.422 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9299E+00 0.9299E+00 1.0000 -0.032 grossular 0.7008E-01 0.7008E-01 1.0000 -1.154 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 15.295844 g Volume = 6.496939 cm3 Porosity: 1.5556% V(tot) - V(min): 0.10266E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 13.9990000 g log = 1.1461 Original solution: 1000.0103000 g Original solution / Rock added: 71.43 (Water/Rock Ratio), log = 1.8539 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1634E-06 1.0073 0.1732E-06 0.1719E-06 CH4,gas 0.3236E-15 1.0129 0.3448E-15 0.3404E-15 H2,gas 0.2036E-05 1.0006 0.2143E-05 0.2141E-05 H2S,gas 0.6725E-14 0.9959 0.7045E-14 0.7074E-14 S2,gas 0.3849E-36 1.0000 0.4049E-36 0.4049E-36 CO,gas 0.9137E-16 1.0000 0.9612E-16 0.9612E-16 SO3,gas 0.9648E-40 1.0000 0.1015E-39 0.1015E-39 SO2,gas 0.7820E-23 1.0000 0.8227E-23 0.8227E-23 HCl,gas 0.4978E-17 1.0000 0.5237E-17 0.5237E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.12 -8.76 -2.921 0.14960E+05 -6.762 3 CH4,gas 4.81 -12.65 -17.46 -4.366 0.29817E+05 -15.462 4 H2,gas 8.29 0.62 -7.67 -4.382 0.13095E+05 -5.669 5 H2S,gas -5.94 -22.09 -16.15 -8.076 0.27579E+05 -14.152 6 S2,gas -7.03 -45.43 -38.39 -5.907 0.65554E+05 -36.393 7 CO,gas 3.51 -14.51 -18.02 -5.544 0.30764E+05 -16.017 8 SO3,gas 17.43 -24.57 -41.99 -10.498 0.71703E+05 -39.994 9 SO2,gas 1.14 -23.95 -25.08 -6.689 0.42832E+05 -23.085 10 HCl,gas 5.48 -13.80 -19.28 -9.640 0.32922E+05 -17.281 11 acmite 7.74 7.31 -0.43 -0.045 0.73178E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.14 -4.41 -0.221 0.75304E+04 20 analcite 3.37 3.06 -0.31 -0.035 0.53695E+03 21 andalusite 5.06 0.71 -4.35 -0.435 0.74353E+04 26 annite 20.21 17.39 -2.82 -0.157 0.48115E+04 27 phlogopite 27.15 24.08 -3.07 -0.171 0.52437E+04 29 anorthite 12.80 9.52 -3.28 -0.252 0.56020E+04 35 aragonite 0.99 -2.93 -3.92 -1.306 0.66889E+04 36 brucite 12.58 8.84 -3.74 -0.748 0.63873E+04 37 calcite 0.83 -2.93 -3.76 -1.255 0.64276E+04 38 carnegieite-low 9.06 6.44 -2.62 -0.375 0.44802E+04 39 carnegieite-high 10.13 6.44 -3.69 -0.528 0.63070E+04 40 carpholite-Mg 8.65 6.16 -2.49 -0.166 0.42539E+04 41 carpholite-Fe 6.78 3.93 -2.85 -0.190 0.48695E+04 42 celadonite 5.40 3.02 -2.38 -0.140 0.40656E+04 43 celadonite-Fe 3.94 0.79 -3.15 -0.185 0.53709E+04 44 chrysotile 23.94 19.74 -4.20 -0.350 0.71697E+04 50 chloritoid-Mg 13.26 9.54 -3.72 -0.248 0.63478E+04 51 chloritoid-Fe 9.24 7.32 -1.92 -0.128 0.32837E+04 52 chloritoid-Mn 11.46 9.44 -2.02 -0.135 0.34521E+04 54 coesite -2.37 -3.38 -1.02 -0.338 0.17334E+04 59 corundum 8.43 4.09 -4.34 -0.395 0.74123E+04 61 cristobalite -2.55 -3.38 -0.84 -0.278 0.14263E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.05 -0.85 -0.142 0.14512E+04 67 diopside 16.22 14.26 -1.96 -0.196 0.33385E+04 68 hedenbergite 14.24 12.03 -2.21 -0.221 0.37773E+04 75 epidote 24.78 24.62 -0.15 -0.007 0.25713E+03 76 clinozoisite 22.92 20.37 -2.55 -0.116 0.43527E+04 77 epidote-Fe 29.94 28.88 -1.06 -0.055 0.18091E+04 78 fayalite 14.08 9.83 -4.25 -0.607 0.72534E+04 79 ferrosilite 11.19 6.45 -4.74 -0.474 0.80956E+04 83 gibbsite 4.10 2.05 -2.05 -0.293 0.35024E+04 84 glaucophane 23.11 19.08 -4.03 -0.109 0.68793E+04 87 greenalite 16.19 13.05 -3.14 -0.262 0.53615E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.06 -1.19 -0.119 0.20400E+04 96 julgoldite 70.57 66.88 -3.70 -0.096 0.63094E+04 97 kalsilite 7.62 4.34 -3.28 -0.469 0.56056E+04 98 kaolinite -1.27 -2.68 -1.40 -0.128 0.23966E+04 99 kyanite 4.93 0.71 -4.22 -0.422 0.72121E+04 101 laumontite 2.97 2.75 -0.23 -0.015 0.38727E+03 102 lawsonite 9.68 9.52 -0.16 -0.011 0.27589E+03 103 leucite 4.17 0.95 -3.21 -0.321 0.54894E+04 105 lizardite 23.29 19.74 -3.55 -0.296 0.60600E+04 107 magnetite 20.13 19.21 -0.93 -0.076 0.15836E+04 108 minnesotaite 10.46 6.29 -4.18 -0.246 0.71298E+04 110 magnesioferrite 26.26 21.43 -4.82 -0.394 0.82366E+04 113 margarite 17.45 13.61 -3.84 -0.154 0.65613E+04 120 muscovite 2.68 1.66 -1.02 -0.060 0.17394E+04 121 paragonite 4.34 3.76 -0.57 -0.034 0.97782E+03 122 nepheline 8.38 6.44 -1.94 -0.277 0.33081E+04 134 phlogopite-Na 29.73 26.18 -3.55 -0.197 0.60656E+04 136 prehnite 19.47 18.33 -1.14 -0.067 0.19474E+04 137 prehnite-Fe 22.59 22.58 -0.01 -0.001 0.14197E+02 138 pumpellyite-Fe 46.47 45.31 -1.17 -0.026 0.19893E+04 139 pumpellyite-Mg 49.19 47.53 -1.66 -0.037 0.28352E+04 145 pyroxmangite 7.42 5.35 -2.07 -0.413 0.35292E+04 146 pyrophyllite -6.10 -9.45 -3.35 -0.209 0.57162E+04 147 quartz -2.98 -3.38 -0.40 -0.134 0.68731E+03 152 rhodonite 7.46 5.35 -2.11 -0.423 0.36084E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.71 -4.61 -0.461 0.78775E+04 164 stilpnomelane-Fe 13.18 12.89 -0.29 -0.009 0.48962E+03 165 stilpnomelane-Mg 27.60 24.03 -3.56 -0.106 0.60844E+04 171 talc 16.55 12.97 -3.58 -0.211 0.61198E+04 174 tephroite 18.11 14.08 -4.03 -0.576 0.68814E+04 177 topaz-H 4.67 0.71 -3.96 -0.360 0.67612E+04 178 tridymite -2.61 -3.38 -0.77 -0.257 0.13146E+04 187 wairakite 4.06 2.75 -1.31 -0.077 0.22381E+04 188 walstromite 11.53 8.81 -2.72 -0.544 0.46424E+04 189 wollastonite 10.48 8.81 -1.67 -0.335 0.28563E+04 190 pseudo-wollastonite 11.02 8.81 -2.21 -0.442 0.37749E+04 191 zoisite 22.96 20.37 -2.59 -0.118 0.44252E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.64 -4.08 -0.253 0.69700E+04 195 beidellite-K -1.44 -5.78 -4.35 -0.266 0.74201E+04 196 beidellite-Mg -1.71 -6.20 -4.49 -0.278 0.76646E+04 197 beidellite-Na -1.26 -5.09 -3.83 -0.235 0.65389E+04 199 chalcedony -2.79 -3.38 -0.59 -0.197 0.10076E+04 201 montmorillonite-Ca -2.21 -5.19 -2.98 -0.184 0.50870E+04 202 montmorillonite-K -2.16 -5.33 -3.17 -0.194 0.54149E+04 203 montmorillonite-Mg -2.40 -5.75 -3.35 -0.207 0.57127E+04 204 montmorillonite-Na -1.96 -4.64 -2.68 -0.164 0.45718E+04 205 nontronite-Ca 3.28 2.86 -0.42 -0.027 0.71047E+03 206 nontronite-H 2.60 0.85 -1.74 -0.117 0.29780E+04 207 nontronite-K 3.40 2.72 -0.68 -0.044 0.11598E+04 208 nontronite-Mg 3.14 2.31 -0.83 -0.054 0.14167E+04 209 nontronite-Na 3.58 3.42 -0.16 -0.011 0.28020E+03 224 tobermorite 9.84 6.77 -3.07 -0.837 0.52357E+04 233 boehmite 4.43 2.05 -2.38 -0.397 0.40697E+04 235 ferrous-oxide 9.82 6.61 -3.22 -0.804 0.54921E+04 240 silica-amorphous -2.08 -3.38 -1.30 -0.435 0.22278E+04 242 an20ab80 2.08 1.64 -0.44 -0.034 0.74879E+03 243 an25ab75 2.71 2.13 -0.58 -0.044 0.98389E+03 244 an30ab70 3.34 2.63 -0.72 -0.055 0.12273E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 13.9990000 g New total amount of reactant added: 14.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8618E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 14.3990000 Water: Moles liquid = 0.5539E+02 kg liquid = 0.9979E+00 Moles total = 0.5533E+02 kg total = 0.9967E+00 Activity = 1.0000 Stoichiometric ionic strength = .5118435E-02 Osmotic coef. = 0.9621 True ionic strength = .9124830E-02 Chg. balance for total moles = 0.8618E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14930E-09 -9.8259 0.13106E-09 -9.8825 0.87787E+00 -0.0566 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13795E-03 -3.8603 0.12072E-03 -3.9182 0.87511E+00 -0.0579 4 SO4-- 0.25541E-04 -4.5928 0.15905E-04 -4.7985 0.62275E+00 -0.2057 5 HCO3- 0.65698E-05 -5.1825 0.57536E-05 -5.2401 0.87577E+00 -0.0576 6 HS- 0.79713E-12 -12.0985 0.69762E-12 -12.1564 0.87517E+00 -0.0579 7 Al+++ 0.66412E-27 -27.1778 0.23236E-27 -27.6338 0.34987E+00 -0.4561 8 H4SiO4 0.42271E-03 -3.3740 0.42271E-03 -3.3740 0.10000E+01 0.0000 9 Ca++ 0.42338E-07 -7.3733 0.26266E-07 -7.5806 0.62038E+00 -0.2073 10 Mg++ 0.19309E-10 -10.7142 0.11951E-10 -10.9226 0.61890E+00 -0.2084 11 Fe++ 0.11415E-12 -12.9425 0.70687E-13 -13.1507 0.61926E+00 -0.2081 12 K+ 0.71024E-04 -4.1486 0.62209E-04 -4.2061 0.87588E+00 -0.0576 13 Na+ 0.90211E-02 -2.0447 0.78938E-02 -2.1027 0.87503E+00 -0.0580 14 Mn++ 0.15247E-10 -10.8168 0.94459E-11 -11.0248 0.61952E+00 -0.2079 15 HPO4-- 0.46457E-06 -6.3329 0.28933E-06 -6.5386 0.62280E+00 -0.2057 16 HSiO3- 0.35958E-02 -2.4442 0.31467E-02 -2.5021 0.87511E+00 -0.0579 17 Ca(HSiO3)+ 0.21140E-08 -8.6749 0.18518E-08 -8.7324 0.87598E+00 -0.0575 18 Mg(HSiO3)+ 0.11970E-11 -11.9219 0.10486E-11 -11.9794 0.87598E+00 -0.0575 19 NaHSiO3,aq 0.39451E-03 -3.4039 0.39451E-03 -3.4039 0.10000E+01 0.0000 20 AlO+ 0.19935E-14 -14.7004 0.17462E-14 -14.7579 0.87598E+00 -0.0575 22 HAlO2,aq 0.26662E-08 -8.5741 0.26662E-08 -8.5741 0.10000E+01 0.0000 23 AlO2- 0.51955E-04 -4.2844 0.45423E-04 -4.3427 0.87428E+00 -0.0584 24 CH4,aq 0.24802E-18 -18.6055 0.24763E-18 -18.6062 0.99842E+00 -0.0007 29 CO,aq 0.63072E-19 -19.2002 0.63072E-19 -19.2002 0.10000E+01 0.0000 30 CO2,aq 0.15228E-08 -8.8174 0.15204E-08 -8.8180 0.99842E+00 -0.0007 31 CO3-2 0.65249E-05 -5.1854 0.40589E-05 -5.3916 0.62206E+00 -0.2062 32 CaCO3,aq 0.13057E-08 -8.8841 0.13057E-08 -8.8841 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43470E-11 -11.3618 0.38079E-11 -11.4193 0.87598E+00 -0.0575 34 CaCl+ 0.57682E-11 -11.2390 0.50528E-11 -11.2965 0.87598E+00 -0.0575 35 CaCl2,aq 0.14203E-15 -15.8476 0.14203E-15 -15.8476 0.10000E+01 0.0000 36 CaOH+ 0.16132E-07 -7.7923 0.14131E-07 -7.8498 0.87598E+00 -0.0575 37 CaSO4,aq 0.13017E-09 -9.8855 0.13017E-09 -9.8855 0.10000E+01 0.0000 38 HCl,aq 0.29762E-14 -14.5263 0.29762E-14 -14.5263 0.10000E+01 0.0000 43 FeCl+ 0.15173E-16 -16.8189 0.13291E-16 -16.8764 0.87598E+00 -0.0575 46 FeO,aq 0.16273E-09 -9.7885 0.16273E-09 -9.7885 0.10000E+01 0.0000 47 FeOH+ 0.20412E-10 -10.6901 0.17880E-10 -10.7476 0.87598E+00 -0.0575 48 HFeO2- 0.15260E-07 -7.8164 0.13354E-07 -7.8744 0.87511E+00 -0.0579 49 FeO+ 0.12377E-14 -14.9074 0.10842E-14 -14.9649 0.87598E+00 -0.0575 51 FeO2- 0.14175E-07 -7.8485 0.12405E-07 -7.9064 0.87511E+00 -0.0579 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.16132E-08 -8.7923 0.16107E-08 -8.7930 0.99842E+00 -0.0007 54 KCl,aq 0.13298E-09 -9.8762 0.13298E-09 -9.8762 0.10000E+01 0.0000 55 KHSO4,aq 0.34703E-18 -18.4596 0.34703E-18 -18.4596 0.10000E+01 0.0000 56 KOH,aq 0.20692E-06 -6.6842 0.20692E-06 -6.6842 0.10000E+01 0.0000 57 KSO4- 0.17420E-07 -7.7590 0.15244E-07 -7.8169 0.87511E+00 -0.0579 58 MgCO3,aq 0.14845E-12 -12.8284 0.14845E-12 -12.8284 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20168E-14 -14.6953 0.17667E-14 -14.7528 0.87598E+00 -0.0575 60 MgCl+ 0.23825E-14 -14.6230 0.20871E-14 -14.6805 0.87598E+00 -0.0575 61 MgOH+ 0.40663E-10 -10.3908 0.35620E-10 -10.4483 0.87598E+00 -0.0575 63 MnO,aq 0.58049E-09 -9.2362 0.58049E-09 -9.2362 0.10000E+01 0.0000 64 MnOH+ 0.25339E-09 -9.5962 0.22196E-09 -9.6537 0.87598E+00 -0.0575 65 MnO2-2 0.18787E-11 -11.7261 0.11687E-11 -11.9323 0.62206E+00 -0.2062 66 HMnO2- 0.37923E-10 -10.4211 0.33187E-10 -10.4790 0.87511E+00 -0.0579 69 MnCl+ 0.78788E-14 -14.1035 0.69016E-14 -14.1610 0.87598E+00 -0.0575 70 MnSO4,aq 0.42579E-13 -13.3708 0.42579E-13 -13.3708 0.10000E+01 0.0000 71 NaCl,aq 0.31117E-06 -6.5070 0.31117E-06 -6.5070 0.10000E+01 0.0000 72 NaOH,aq 0.26465E-04 -4.5773 0.26465E-04 -4.5773 0.10000E+01 0.0000 74 OH- 0.52348E-02 -2.2811 0.45767E-02 -2.3395 0.87428E+00 -0.0584 79 HPO3-2 0.23663E-17 -17.6259 0.14720E-17 -17.8321 0.62206E+00 -0.2062 82 H3PO4,aq 0.31997E-16 -16.4949 0.31997E-16 -16.4949 0.10000E+01 0.0000 83 H2PO4- 0.75935E-09 -9.1196 0.66484E-09 -9.1773 0.87554E+00 -0.0577 84 PO4-3 0.53707E-08 -8.2700 0.19279E-08 -8.7149 0.35896E+00 -0.4449 87 H2P2O7-2 0.55611E-19 -19.2548 0.34594E-19 -19.4610 0.62206E+00 -0.2062 88 HP2O7-3 0.15463E-15 -15.8107 0.54123E-16 -16.2666 0.35002E+00 -0.4559 89 P2O7-4 0.64057E-15 -15.1934 0.10187E-15 -15.9919 0.15904E+00 -0.7985 90 H2S,aq 0.27515E-15 -15.5604 0.27472E-15 -15.5611 0.99842E+00 -0.0007 97 SO3-2 0.55733E-14 -14.2539 0.34931E-14 -14.4568 0.62676E+00 -0.2029 98 HSO3- 0.30616E-16 -16.5140 0.26792E-16 -16.5720 0.87511E+00 -0.0579 99 HSO4- 0.22070E-11 -11.6562 0.19342E-11 -11.7135 0.87642E+00 -0.0573 Charge balance for all species = 0.8521E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1492974E-09 -.9466289E-02 -.9535094E+01 0.0000 2 H2O 0.1000000E+01 0.5550963E+02 0.9993563E+06 0.0000 3 Cl- 0.1379535E-03 0.1382648E-03 0.4898635E+01 5.9643 4 SO4-- 0.2554063E-04 0.2555958E-04 0.2453658E+01 14.9666 5 HCO3- 0.6569755E-05 0.1309753E-04 0.7986420E+00 4.6425 6 HS- 0.7971275E-12 -.1393221E-08 -.4604592E-04 -2.2739 7 Al+++ 0.6641158E-27 0.5195752E-04 0.1400958E+01 2.0137 8 H4SiO4 0.4227093E-03 0.4413068E-02 0.4238812E+03 -3.3740 9 Ca++ 0.4233827E-07 0.6203012E-07 0.2484387E-02 12.1844 10 Mg++ 0.1930936E-10 0.6132184E-10 0.1489863E-05 8.8424 11 Fe++ 0.1141485E-12 0.2982232E-07 0.1664377E-02 6.6144 12 K+ 0.7102391E-04 0.7124839E-04 0.2784098E+01 5.6764 13 Na+ 0.9021114E-02 0.9442404E-02 0.2169344E+03 7.7798 14 Mn++ 0.1524704E-10 0.8889732E-09 0.4880587E-04 8.7403 15 HPO4-- 0.4645709E-06 0.4707010E-06 0.4514731E-01 13.2264 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2384130E+00 -.9446394E-02 -.2289666E+00 0.0000000E+00 2 H2O 0.5532775E+02 0.5539296E+02 -.6521046E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4245498E-03 0.2550586E-04 0.3990440E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3990454E-03 -.1390293E-08 -.3990440E-03 0.0000000E+00 7 Al+++ 0.4695142E-01 0.5184832E-04 0.4689957E-01 0.0000000E+00 8 H4SiO4 0.1499337E+00 0.4403793E-02 0.1455299E+00 0.0000000E+00 9 Ca++ 0.1657538E-01 0.6189975E-07 0.1657531E-01 0.0000000E+00 10 Mg++ 0.1142778E-01 0.6119297E-10 0.1142778E-01 0.0000000E+00 11 Fe++ 0.1026661E-01 0.2975964E-07 0.1026658E-01 0.0000000E+00 12 K+ 0.3057113E-02 0.7109865E-04 0.2986014E-02 0.0000000E+00 13 Na+ 0.1823432E-01 0.9422559E-02 0.8811765E-02 0.0000000E+00 14 Mn++ 0.2496584E-03 0.8871049E-09 0.2496576E-03 0.0000000E+00 15 HPO4-- 0.8520719E-04 0.4697117E-06 0.8473747E-04 0.0000000E+00 Chg. balance for solid moles: 0.6494E-16 Mass of aqueous solution: 0.998564E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 14.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8812E-02 -2.055 2.311 0.364 14.69 0.8870 andradite 0.8387E-03 -3.076 0.4262 -0.370 2.710 0.1107 grossular 0.5865E-04 -4.232 0.2642E-01 -1.578 0.1680 0.7351E-02 apatite-OH 0.2825E-04 -4.549 0.1419E-01 -1.848 0.9021E-01 0.4509E-02 clinochlore 0.2286E-02 -2.641 1.270 0.104 8.077 0.4832 daphnite 0.1415E-02 -2.849 1.010 0.004 6.418 0.3059 chlorite-Mn 0.4993E-04 -4.302 0.3540E-01 -1.451 0.2251 0.1128E-01 hematite 0.7574E-03 -3.121 0.1210 -0.917 0.7690 0.2293E-01 microcline 0.2986E-02 -2.525 0.8311 -0.080 5.284 0.3247 stilbite 0.1374E-01 -1.862 9.684 0.986 61.57 4.517 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9346E+00 0.9346E+00 1.0000 -0.029 grossular 0.6536E-01 0.6536E-01 1.0000 -1.185 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 15.729035 g Volume = 6.674472 cm3 Porosity: 1.2594% V(tot) - V(min): 0.85128E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 14.3990000 g log = 1.1583 Original solution: 1000.0103000 g Original solution / Rock added: 69.45 (Water/Rock Ratio), log = 1.8417 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1642E-06 1.0073 0.1740E-06 0.1728E-06 CH4,gas 0.3675E-15 1.0129 0.3916E-15 0.3866E-15 H2,gas 0.2099E-05 1.0006 0.2209E-05 0.2208E-05 H2S,gas 0.7648E-14 0.9959 0.8012E-14 0.8045E-14 S2,gas 0.4684E-36 1.0000 0.4927E-36 0.4927E-36 CO,gas 0.9467E-16 1.0000 0.9959E-16 0.9959E-16 SO3,gas 0.9710E-40 1.0000 0.1021E-39 0.1021E-39 SO2,gas 0.8115E-23 1.0000 0.8536E-23 0.8536E-23 HCl,gas 0.4996E-17 1.0000 0.5255E-17 0.5255E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.12 -8.76 -2.920 0.14956E+05 -6.759 3 CH4,gas 4.81 -12.60 -17.41 -4.352 0.29722E+05 -15.407 4 H2,gas 8.29 0.63 -7.66 -4.375 0.13072E+05 -5.656 5 H2S,gas -5.94 -22.04 -16.10 -8.048 0.27484E+05 -14.096 6 S2,gas -7.03 -45.34 -38.31 -5.893 0.65409E+05 -36.307 7 CO,gas 3.51 -14.49 -18.00 -5.539 0.30738E+05 -16.002 8 SO3,gas 17.43 -24.56 -41.99 -10.498 0.71698E+05 -39.991 9 SO2,gas 1.14 -23.93 -25.07 -6.685 0.42804E+05 -23.069 10 HCl,gas 5.48 -13.80 -19.28 -9.640 0.32919E+05 -17.279 11 acmite 7.74 7.33 -0.41 -0.042 0.69443E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.13 -4.42 -0.221 0.75530E+04 20 analcite 3.37 3.05 -0.33 -0.036 0.55500E+03 21 andalusite 5.06 0.65 -4.41 -0.441 0.75281E+04 26 annite 20.21 17.41 -2.80 -0.155 0.47775E+04 27 phlogopite 27.15 24.10 -3.05 -0.170 0.52097E+04 29 anorthite 12.80 9.46 -3.33 -0.256 0.56923E+04 35 aragonite 0.99 -2.94 -3.92 -1.308 0.67008E+04 36 brucite 12.58 8.84 -3.73 -0.747 0.63760E+04 37 calcite 0.83 -2.94 -3.77 -1.257 0.64394E+04 38 carnegieite-low 9.06 6.42 -2.64 -0.378 0.45163E+04 39 carnegieite-high 10.13 6.42 -3.71 -0.531 0.63431E+04 40 carpholite-Mg 8.65 6.12 -2.53 -0.169 0.43172E+04 41 carpholite-Fe 6.78 3.89 -2.89 -0.193 0.49329E+04 42 celadonite 5.40 3.04 -2.36 -0.139 0.40362E+04 43 celadonite-Fe 3.94 0.81 -3.13 -0.184 0.53415E+04 44 chrysotile 23.94 19.78 -4.16 -0.346 0.70996E+04 50 chloritoid-Mg 13.26 9.50 -3.77 -0.251 0.64292E+04 51 chloritoid-Fe 9.24 7.27 -1.97 -0.131 0.33651E+04 52 chloritoid-Mn 11.46 9.39 -2.07 -0.138 0.35336E+04 54 coesite -2.37 -3.37 -1.00 -0.335 0.17153E+04 59 corundum 8.43 4.03 -4.41 -0.401 0.75231E+04 61 cristobalite -2.55 -3.37 -0.82 -0.275 0.14082E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 2.01 -0.88 -0.147 0.15066E+04 67 diopside 16.22 14.28 -1.94 -0.194 0.33066E+04 68 hedenbergite 14.24 12.05 -2.19 -0.219 0.37454E+04 75 epidote 24.78 24.57 -0.20 -0.010 0.34489E+03 76 clinozoisite 22.92 20.29 -2.63 -0.120 0.44958E+04 77 epidote-Fe 29.94 28.86 -1.08 -0.056 0.18414E+04 78 fayalite 14.08 9.85 -4.22 -0.603 0.72126E+04 79 ferrosilite 11.19 6.48 -4.71 -0.471 0.80368E+04 83 gibbsite 4.10 2.01 -2.08 -0.298 0.35578E+04 84 glaucophane 23.11 19.12 -3.99 -0.108 0.68092E+04 85 glaucophane-Fe 17.42 12.44 -4.98 -0.135 0.85010E+04 87 greenalite 16.19 13.10 -3.10 -0.258 0.52914E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.05 -1.21 -0.121 0.20580E+04 96 julgoldite 70.57 66.92 -3.65 -0.095 0.62407E+04 97 kalsilite 7.62 4.32 -3.30 -0.472 0.56417E+04 98 kaolinite -1.27 -2.72 -1.45 -0.132 0.24713E+04 99 kyanite 4.93 0.65 -4.28 -0.428 0.73049E+04 101 laumontite 2.97 2.72 -0.26 -0.017 0.44142E+03 102 lawsonite 9.68 9.46 -0.21 -0.014 0.36615E+03 103 leucite 4.17 0.94 -3.23 -0.323 0.55074E+04 105 lizardite 23.29 19.78 -3.51 -0.292 0.59899E+04 107 magnetite 20.13 19.21 -0.92 -0.075 0.15722E+04 108 minnesotaite 10.46 6.35 -4.11 -0.242 0.70236E+04 110 magnesioferrite 26.26 21.44 -4.82 -0.393 0.82253E+04 113 margarite 17.45 13.49 -3.96 -0.158 0.67623E+04 120 muscovite 2.68 1.60 -1.08 -0.064 0.18502E+04 121 paragonite 4.34 3.70 -0.64 -0.038 0.10886E+04 122 nepheline 8.38 6.42 -1.96 -0.280 0.33442E+04 134 phlogopite-Na 29.73 26.20 -3.53 -0.196 0.60316E+04 136 prehnite 19.47 18.27 -1.19 -0.070 0.20352E+04 137 prehnite-Fe 22.59 22.56 -0.03 -0.002 0.46550E+02 138 pumpellyite-Fe 46.47 45.18 -1.29 -0.029 0.22089E+04 139 pumpellyite-Mg 49.19 47.40 -1.79 -0.040 0.30548E+04 145 pyroxmangite 7.42 5.37 -2.05 -0.410 0.34998E+04 146 pyrophyllite -6.10 -9.47 -3.37 -0.211 0.57548E+04 147 quartz -2.98 -3.37 -0.39 -0.131 0.66926E+03 152 rhodonite 7.46 5.37 -2.10 -0.419 0.35791E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.65 -4.67 -0.467 0.79703E+04 164 stilpnomelane-Fe 13.18 12.95 -0.23 -0.007 0.39874E+03 165 stilpnomelane-Mg 27.60 24.09 -3.51 -0.105 0.59936E+04 171 talc 16.55 13.03 -3.52 -0.207 0.60136E+04 174 tephroite 18.11 14.11 -4.01 -0.572 0.68407E+04 177 topaz-H 4.67 0.65 -4.01 -0.365 0.68540E+04 178 tridymite -2.61 -3.37 -0.76 -0.253 0.12966E+04 187 wairakite 4.06 2.72 -1.34 -0.079 0.22922E+04 188 walstromite 11.53 8.81 -2.72 -0.543 0.46399E+04 189 wollastonite 10.48 8.81 -1.67 -0.334 0.28538E+04 190 pseudo-wollastonite 11.02 8.81 -2.21 -0.442 0.37724E+04 191 zoisite 22.96 20.29 -2.68 -0.122 0.45684E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.68 -4.12 -0.255 0.70354E+04 195 beidellite-K -1.44 -5.82 -4.38 -0.268 0.74826E+04 196 beidellite-Mg -1.71 -6.23 -4.52 -0.280 0.77256E+04 197 beidellite-Na -1.26 -5.12 -3.87 -0.237 0.66013E+04 199 chalcedony -2.79 -3.37 -0.58 -0.193 0.98958E+03 201 montmorillonite-Ca -2.21 -5.20 -2.99 -0.185 0.51062E+04 202 montmorillonite-K -2.16 -5.34 -3.18 -0.195 0.54311E+04 203 montmorillonite-Mg -2.40 -5.76 -3.35 -0.208 0.57274E+04 204 montmorillonite-Na -1.96 -4.65 -2.69 -0.165 0.45879E+04 205 nontronite-Ca 3.28 2.89 -0.39 -0.025 0.66507E+03 206 nontronite-H 2.60 0.88 -1.72 -0.115 0.29301E+04 207 nontronite-K 3.40 2.75 -0.65 -0.042 0.11114E+04 208 nontronite-Mg 3.14 2.34 -0.80 -0.052 0.13669E+04 209 nontronite-Na 3.58 3.45 -0.14 -0.009 0.23182E+03 224 tobermorite 9.84 6.78 -3.06 -0.836 0.52306E+04 233 boehmite 4.43 2.01 -2.42 -0.403 0.41251E+04 235 ferrous-oxide 9.82 6.61 -3.21 -0.802 0.54807E+04 240 silica-amorphous -2.08 -3.37 -1.29 -0.431 0.22098E+04 242 an20ab80 2.08 1.63 -0.45 -0.035 0.76684E+03 243 an25ab75 2.71 2.12 -0.59 -0.045 0.10065E+04 244 an30ab70 3.34 2.61 -0.73 -0.057 0.12544E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 14.3990000 g New total amount of reactant added: 14.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8620E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 14.7990000 Water: Moles liquid = 0.5539E+02 kg liquid = 0.9979E+00 Moles total = 0.5532E+02 kg total = 0.9967E+00 Activity = 1.0000 Stoichiometric ionic strength = .5132162E-02 Osmotic coef. = 0.9620 True ionic strength = .9176635E-02 Chg. balance for total moles = 0.8620E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14991E-09 -9.8242 0.13157E-09 -9.8808 0.87763E+00 -0.0567 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8603 0.12069E-03 -3.9183 0.87485E+00 -0.0581 4 SO4-- 0.25542E-04 -4.5928 0.15888E-04 -4.7989 0.62205E+00 -0.2062 5 HCO3- 0.65799E-05 -5.1818 0.57608E-05 -5.2395 0.87552E+00 -0.0577 6 HS- 0.90156E-12 -12.0450 0.78879E-12 -12.1030 0.87492E+00 -0.0580 7 Al+++ 0.62582E-27 -27.2035 0.21840E-27 -27.6607 0.34898E+00 -0.4572 8 H4SiO4 0.43297E-03 -3.3635 0.43297E-03 -3.3635 0.10000E+01 0.0000 9 Ca++ 0.41831E-07 -7.3785 0.25922E-07 -7.5863 0.61967E+00 -0.2078 10 Mg++ 0.19775E-10 -10.7039 0.12225E-10 -10.9128 0.61819E+00 -0.2089 11 Fe++ 0.11690E-12 -12.9322 0.72310E-13 -13.1408 0.61854E+00 -0.2086 12 K+ 0.71428E-04 -4.1461 0.62545E-04 -4.2038 0.87564E+00 -0.0577 13 Na+ 0.90725E-02 -2.0423 0.79364E-02 -2.1004 0.87478E+00 -0.0581 14 Mn++ 0.15615E-10 -10.8065 0.96627E-11 -11.0149 0.61881E+00 -0.2084 15 HPO4-- 0.47788E-06 -6.3207 0.29729E-06 -6.5268 0.62210E+00 -0.2061 16 HSiO3- 0.36700E-02 -2.4353 0.32107E-02 -2.4934 0.87485E+00 -0.0581 17 Ca(HSiO3)+ 0.21293E-08 -8.6718 0.18647E-08 -8.7294 0.87573E+00 -0.0576 18 Mg(HSiO3)+ 0.12498E-11 -11.9032 0.10945E-11 -11.9608 0.87573E+00 -0.0576 19 NaHSiO3,aq 0.40471E-03 -3.3929 0.40471E-03 -3.3929 0.10000E+01 0.0000 20 AlO+ 0.18599E-14 -14.7305 0.16288E-14 -14.7881 0.87573E+00 -0.0576 22 HAlO2,aq 0.24773E-08 -8.6060 0.24773E-08 -8.6060 0.10000E+01 0.0000 23 AlO2- 0.48103E-04 -4.3178 0.42043E-04 -4.3763 0.87402E+00 -0.0585 24 CH4,aq 0.28109E-18 -18.5512 0.28064E-18 -18.5518 0.99842E+00 -0.0007 29 CO,aq 0.65326E-19 -19.1849 0.65326E-19 -19.1849 0.10000E+01 0.0000 30 CO2,aq 0.15306E-08 -8.8151 0.15282E-08 -8.8158 0.99842E+00 -0.0007 31 CO3-2 0.65154E-05 -5.1861 0.40484E-05 -5.3927 0.62136E+00 -0.2067 32 CaCO3,aq 0.12853E-08 -8.8910 0.12853E-08 -8.8910 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.42966E-11 -11.3669 0.37627E-11 -11.4245 0.87573E+00 -0.0576 34 CaCl+ 0.56928E-11 -11.2447 0.49853E-11 -11.3023 0.87573E+00 -0.0576 35 CaCl2,aq 0.14010E-15 -15.8536 0.14010E-15 -15.8536 0.10000E+01 0.0000 36 CaOH+ 0.15864E-07 -7.7996 0.13892E-07 -7.8572 0.87573E+00 -0.0576 37 CaSO4,aq 0.12832E-09 -9.8917 0.12832E-09 -9.8917 0.10000E+01 0.0000 38 HCl,aq 0.29869E-14 -14.5248 0.29869E-14 -14.5248 0.10000E+01 0.0000 43 FeCl+ 0.15522E-16 -16.8091 0.13593E-16 -16.8667 0.87573E+00 -0.0576 46 FeO,aq 0.16519E-09 -9.7820 0.16519E-09 -9.7820 0.10000E+01 0.0000 47 FeOH+ 0.20806E-10 -10.6818 0.18221E-10 -10.7394 0.87573E+00 -0.0576 48 HFeO2- 0.15436E-07 -7.8115 0.13504E-07 -7.8695 0.87485E+00 -0.0581 49 FeO+ 0.12428E-14 -14.9056 0.10884E-14 -14.9632 0.87573E+00 -0.0576 51 FeO2- 0.14125E-07 -7.8500 0.12357E-07 -7.9081 0.87485E+00 -0.0581 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.16624E-08 -8.7793 0.16598E-08 -8.7800 0.99842E+00 -0.0007 54 KCl,aq 0.13366E-09 -9.8740 0.13366E-09 -9.8740 0.10000E+01 0.0000 55 KHSO4,aq 0.34987E-18 -18.4561 0.34987E-18 -18.4561 0.10000E+01 0.0000 56 KOH,aq 0.20724E-06 -6.6835 0.20724E-06 -6.6835 0.10000E+01 0.0000 57 KSO4- 0.17500E-07 -7.7570 0.15310E-07 -7.8150 0.87485E+00 -0.0581 58 MgCO3,aq 0.15147E-12 -12.8197 0.15147E-12 -12.8197 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20663E-14 -14.6848 0.18095E-14 -14.7424 0.87573E+00 -0.0576 60 MgCl+ 0.24373E-14 -14.6131 0.21344E-14 -14.6707 0.87573E+00 -0.0576 61 MgOH+ 0.41448E-10 -10.3825 0.36298E-10 -10.4401 0.87573E+00 -0.0576 63 MnO,aq 0.58927E-09 -9.2297 0.58927E-09 -9.2297 0.10000E+01 0.0000 64 MnOH+ 0.25828E-09 -9.5879 0.22619E-09 -9.6455 0.87573E+00 -0.0576 65 MnO2-2 0.18947E-11 -11.7225 0.11773E-11 -11.9291 0.62136E+00 -0.2067 66 HMnO2- 0.38360E-10 -10.4161 0.33559E-10 -10.4742 0.87485E+00 -0.0581 69 MnCl+ 0.80599E-14 -14.0937 0.70583E-14 -14.1513 0.87573E+00 -0.0576 70 MnSO4,aq 0.43509E-13 -13.3614 0.43509E-13 -13.3614 0.10000E+01 0.0000 71 NaCl,aq 0.31277E-06 -6.5048 0.31277E-06 -6.5048 0.10000E+01 0.0000 72 NaOH,aq 0.26506E-04 -4.5767 0.26506E-04 -4.5767 0.10000E+01 0.0000 74 OH- 0.52162E-02 -2.2826 0.45591E-02 -2.3411 0.87402E+00 -0.0585 79 HPO3-2 0.25082E-17 -17.6006 0.15585E-17 -17.8073 0.62136E+00 -0.2067 82 H3PO4,aq 0.33131E-16 -16.4798 0.33131E-16 -16.4798 0.10000E+01 0.0000 83 H2PO4- 0.78345E-09 -9.1060 0.68574E-09 -9.1638 0.87529E+00 -0.0579 84 PO4-3 0.55106E-08 -8.2588 0.19733E-08 -8.7048 0.35809E+00 -0.4460 87 H2P2O7-2 0.59231E-19 -19.2275 0.36804E-19 -19.4341 0.62136E+00 -0.2067 88 HP2O7-3 0.16429E-15 -15.7844 0.57359E-16 -16.2414 0.34913E+00 -0.4570 89 P2O7-4 0.67930E-15 -15.1679 0.10755E-15 -15.9684 0.15833E+00 -0.8004 90 H2S,aq 0.31231E-15 -15.5054 0.31181E-15 -15.5061 0.99842E+00 -0.0007 97 SO3-2 0.57431E-14 -14.2409 0.35956E-14 -14.4442 0.62608E+00 -0.2034 98 HSO3- 0.31645E-16 -16.4997 0.27685E-16 -16.5578 0.87485E+00 -0.0581 99 HSO4- 0.22137E-11 -11.6549 0.19396E-11 -11.7123 0.87617E+00 -0.0574 Charge balance for all species = 0.8532E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1499136E-09 -.9516739E-02 -.9585831E+01 0.0000 2 H2O 0.1000000E+01 0.5550951E+02 0.9993460E+06 0.0000 3 Cl- 0.1379581E-03 0.1382710E-03 0.4898814E+01 5.9625 4 SO4-- 0.2554170E-04 0.2556070E-04 0.2453746E+01 14.9628 5 HCO3- 0.6579880E-05 0.1309811E-04 0.7986711E+00 4.6413 6 HS- 0.9015550E-12 -.1374535E-08 -.4542796E-04 -2.2222 7 Al+++ 0.6258224E-27 0.4810504E-04 0.1297070E+01 1.9818 8 H4SiO4 0.4329683E-03 0.4507719E-02 0.4329690E+03 -3.3635 9 Ca++ 0.4183105E-07 0.6124774E-07 0.2453031E-02 12.1754 10 Mg++ 0.1977545E-10 0.6262939E-10 0.1521619E-05 8.8489 11 Fe++ 0.1169035E-12 0.2995057E-07 0.1671521E-02 6.6209 12 K+ 0.7142823E-04 0.7165310E-04 0.2799890E+01 5.6770 13 Na+ 0.9072511E-02 0.9504044E-02 0.2183487E+03 7.7805 14 Mn++ 0.1561500E-10 0.9034673E-09 0.4960120E-04 8.7468 15 HPO4-- 0.4778781E-06 0.4841722E-06 0.4643901E-01 13.2349 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2450364E+00 -.9496312E-02 -.2355401E+00 0.0000000E+00 2 H2O 0.5532274E+02 0.5539037E+02 -.6763079E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4356352E-03 0.2550584E-04 0.4101294E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4101307E-03 -.1371585E-08 -.4101294E-03 0.0000000E+00 7 Al+++ 0.4825572E-01 0.4800178E-04 0.4820771E-01 0.0000000E+00 8 H4SiO4 0.1540988E+00 0.4498044E-02 0.1496007E+00 0.0000000E+00 9 Ca++ 0.1703543E-01 0.6111627E-07 0.1703537E-01 0.0000000E+00 10 Mg++ 0.1174524E-01 0.6249496E-10 0.1174524E-01 0.0000000E+00 11 Fe++ 0.1055181E-01 0.2988629E-07 0.1055178E-01 0.0000000E+00 12 K+ 0.3142038E-02 0.7149931E-04 0.3070539E-02 0.0000000E+00 13 Na+ 0.1873642E-01 0.9483645E-02 0.9252777E-02 0.0000000E+00 14 Mn++ 0.2565939E-03 0.9015281E-09 0.2565930E-03 0.0000000E+00 15 HPO4-- 0.8757422E-04 0.4831329E-06 0.8709108E-04 0.0000000E+00 Chg. balance for solid moles: -.5258E-17 Mass of aqueous solution: 0.998527E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 14.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9253E-02 -2.034 2.426 0.385 15.01 0.9314 andradite 0.8954E-03 -3.048 0.4550 -0.342 2.815 0.1182 grossular 0.5818E-04 -4.235 0.2621E-01 -1.582 0.1622 0.7292E-02 apatite-OH 0.2903E-04 -4.537 0.1458E-01 -1.836 0.9023E-01 0.4634E-02 clinochlore 0.2349E-02 -2.629 1.306 0.116 8.079 0.4966 daphnite 0.1454E-02 -2.837 1.038 0.016 6.420 0.3144 chlorite-Mn 0.5132E-04 -4.290 0.3638E-01 -1.439 0.2251 0.1159E-01 hematite 0.7451E-03 -3.128 0.1190 -0.924 0.7363 0.2255E-01 microcline 0.3071E-02 -2.513 0.8547 -0.068 5.288 0.3338 stilbite 0.1403E-01 -1.853 9.887 0.995 61.17 4.611 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9390E+00 0.9390E+00 1.0000 -0.027 grossular 0.6101E-01 0.6101E-01 1.0000 -1.215 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 16.162200 g Volume = 6.851993 cm3 Porosity: 0.9770% V(tot) - V(min): 0.67607E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 14.7990000 g log = 1.1702 Original solution: 1000.0103000 g Original solution / Rock added: 67.57 (Water/Rock Ratio), log = 1.8298 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1651E-06 1.0073 0.1749E-06 0.1737E-06 CH4,gas 0.4165E-15 1.0129 0.4438E-15 0.4381E-15 H2,gas 0.2163E-05 1.0006 0.2276E-05 0.2275E-05 H2S,gas 0.8681E-14 0.9959 0.9094E-14 0.9132E-14 S2,gas 0.5682E-36 1.0000 0.5977E-36 0.5977E-36 CO,gas 0.9806E-16 1.0000 0.1032E-15 0.1032E-15 SO3,gas 0.9775E-40 1.0000 0.1028E-39 0.1028E-39 SO2,gas 0.8418E-23 1.0000 0.8855E-23 0.8855E-23 HCl,gas 0.5014E-17 1.0000 0.5274E-17 0.5274E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.48529E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.60662E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.12 -8.76 -2.919 0.14953E+05 -6.757 3 CH4,gas 4.81 -12.54 -17.35 -4.338 0.29629E+05 -15.353 4 H2,gas 8.29 0.64 -7.64 -4.367 0.13050E+05 -5.643 5 H2S,gas -5.94 -21.98 -16.04 -8.021 0.27390E+05 -14.041 6 S2,gas -7.03 -45.26 -38.22 -5.881 0.65266E+05 -36.223 7 CO,gas 3.51 -14.48 -17.99 -5.534 0.30712E+05 -15.987 8 SO3,gas 17.43 -24.56 -41.99 -10.497 0.71693E+05 -39.988 9 SO2,gas 1.14 -23.92 -25.05 -6.681 0.42777E+05 -23.053 10 HCl,gas 5.48 -13.80 -19.28 -9.639 0.32916E+05 -17.278 11 acmite 7.74 7.35 -0.39 -0.040 0.65772E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.11 -4.44 -0.222 0.75753E+04 20 analcite 3.37 3.04 -0.34 -0.037 0.57278E+03 21 andalusite 5.06 0.60 -4.46 -0.446 0.76193E+04 26 annite 20.21 17.43 -2.78 -0.154 0.47441E+04 27 phlogopite 27.15 24.12 -3.03 -0.168 0.51763E+04 29 anorthite 12.80 9.41 -3.39 -0.260 0.57812E+04 35 aragonite 0.99 -2.95 -3.93 -1.310 0.67125E+04 36 brucite 12.58 8.85 -3.73 -0.746 0.63649E+04 37 calcite 0.83 -2.95 -3.78 -1.259 0.64511E+04 38 carnegieite-low 9.06 6.40 -2.67 -0.381 0.45518E+04 39 carnegieite-high 10.13 6.40 -3.74 -0.534 0.63787E+04 40 carpholite-Mg 8.65 6.09 -2.56 -0.171 0.43795E+04 41 carpholite-Fe 6.78 3.86 -2.93 -0.195 0.49952E+04 42 celadonite 5.40 3.05 -2.35 -0.138 0.40073E+04 43 celadonite-Fe 3.94 0.83 -3.11 -0.183 0.53126E+04 44 chrysotile 23.94 19.82 -4.12 -0.343 0.70307E+04 50 chloritoid-Mg 13.26 9.45 -3.81 -0.254 0.65093E+04 51 chloritoid-Fe 9.24 7.22 -2.02 -0.135 0.34452E+04 52 chloritoid-Mn 11.46 9.35 -2.12 -0.141 0.36136E+04 54 coesite -2.37 -3.36 -0.99 -0.331 0.16976E+04 59 corundum 8.43 3.96 -4.47 -0.406 0.76321E+04 61 cristobalite -2.55 -3.36 -0.81 -0.271 0.13904E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.98 -0.91 -0.152 0.15611E+04 67 diopside 16.22 14.30 -1.92 -0.192 0.32754E+04 68 hedenbergite 14.24 12.07 -2.18 -0.218 0.37142E+04 75 epidote 24.78 24.52 -0.25 -0.012 0.43151E+03 76 clinozoisite 22.92 20.21 -2.72 -0.123 0.46369E+04 77 epidote-Fe 29.94 28.84 -1.10 -0.057 0.18736E+04 78 fayalite 14.08 9.88 -4.20 -0.600 0.71726E+04 79 ferrosilite 11.19 6.51 -4.67 -0.467 0.79790E+04 83 gibbsite 4.10 1.98 -2.12 -0.302 0.36123E+04 84 glaucophane 23.11 19.16 -3.95 -0.107 0.67403E+04 85 glaucophane-Fe 17.42 12.48 -4.94 -0.133 0.84320E+04 87 greenalite 16.19 13.14 -3.06 -0.255 0.52225E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.04 -1.22 -0.122 0.20758E+04 96 julgoldite 70.57 66.96 -3.62 -0.094 0.61737E+04 97 kalsilite 7.62 4.30 -3.32 -0.475 0.56773E+04 98 kaolinite -1.27 -2.76 -1.49 -0.135 0.25447E+04 99 kyanite 4.93 0.60 -4.33 -0.433 0.73961E+04 101 laumontite 2.97 2.68 -0.29 -0.019 0.49477E+03 102 lawsonite 9.68 9.41 -0.27 -0.018 0.45506E+03 103 leucite 4.17 0.93 -3.24 -0.324 0.55252E+04 105 lizardite 23.29 19.82 -3.47 -0.289 0.59210E+04 107 magnetite 20.13 19.22 -0.91 -0.075 0.15611E+04 108 minnesotaite 10.46 6.41 -4.05 -0.238 0.69191E+04 110 magnesioferrite 26.26 21.45 -4.81 -0.393 0.82142E+04 113 margarite 17.45 13.38 -4.08 -0.163 0.69602E+04 120 muscovite 2.68 1.53 -1.15 -0.067 0.19591E+04 121 paragonite 4.34 3.64 -0.70 -0.041 0.11976E+04 122 nepheline 8.38 6.40 -1.98 -0.283 0.33798E+04 134 phlogopite-Na 29.73 26.22 -3.51 -0.195 0.59982E+04 136 prehnite 19.47 18.22 -1.24 -0.073 0.21218E+04 137 prehnite-Fe 22.59 22.54 -0.05 -0.003 0.78672E+02 138 pumpellyite-Fe 46.47 45.05 -1.42 -0.032 0.24255E+04 139 pumpellyite-Mg 49.19 47.28 -1.92 -0.043 0.32714E+04 145 pyroxmangite 7.42 5.38 -2.03 -0.407 0.34709E+04 146 pyrophyllite -6.10 -9.49 -3.39 -0.212 0.57927E+04 147 quartz -2.98 -3.36 -0.38 -0.127 0.65148E+03 152 rhodonite 7.46 5.38 -2.08 -0.416 0.35502E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.60 -4.72 -0.472 0.80615E+04 164 stilpnomelane-Fe 13.18 13.00 -0.18 -0.005 0.30926E+03 165 stilpnomelane-Mg 27.60 24.14 -3.46 -0.103 0.59041E+04 171 talc 16.55 13.09 -3.46 -0.204 0.59091E+04 174 tephroite 18.11 14.13 -3.98 -0.569 0.68006E+04 177 topaz-H 4.67 0.60 -4.07 -0.370 0.69452E+04 178 tridymite -2.61 -3.36 -0.75 -0.250 0.12788E+04 187 wairakite 4.06 2.68 -1.37 -0.081 0.23456E+04 188 walstromite 11.53 8.81 -2.72 -0.543 0.46376E+04 189 wollastonite 10.48 8.81 -1.67 -0.334 0.28515E+04 190 pseudo-wollastonite 11.02 8.81 -2.21 -0.442 0.37701E+04 191 zoisite 22.96 20.21 -2.76 -0.125 0.47095E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.72 -4.16 -0.257 0.70997E+04 195 beidellite-K -1.44 -5.85 -4.42 -0.271 0.75439E+04 196 beidellite-Mg -1.71 -6.27 -4.56 -0.282 0.77855E+04 197 beidellite-Na -1.26 -5.16 -3.90 -0.239 0.66626E+04 199 chalcedony -2.79 -3.36 -0.57 -0.190 0.97179E+03 201 montmorillonite-Ca -2.21 -5.22 -3.00 -0.186 0.51249E+04 202 montmorillonite-K -2.16 -5.35 -3.19 -0.195 0.54469E+04 203 montmorillonite-Mg -2.40 -5.76 -3.36 -0.208 0.57418E+04 204 montmorillonite-Na -1.96 -4.66 -2.70 -0.165 0.46038E+04 205 nontronite-Ca 3.28 2.92 -0.36 -0.024 0.62035E+03 206 nontronite-H 2.60 0.91 -1.69 -0.113 0.28828E+04 207 nontronite-K 3.40 2.78 -0.62 -0.040 0.10637E+04 208 nontronite-Mg 3.14 2.37 -0.77 -0.050 0.13178E+04 209 nontronite-Na 3.58 3.47 -0.11 -0.007 0.18416E+03 224 tobermorite 9.84 6.78 -3.06 -0.835 0.52257E+04 233 boehmite 4.43 1.98 -2.45 -0.408 0.41796E+04 235 ferrous-oxide 9.82 6.62 -3.20 -0.801 0.54696E+04 240 silica-amorphous -2.08 -3.36 -1.28 -0.428 0.21920E+04 242 an20ab80 2.08 1.62 -0.46 -0.035 0.78463E+03 243 an25ab75 2.71 2.11 -0.60 -0.046 0.10287E+04 244 an30ab70 3.34 2.59 -0.75 -0.058 0.12811E+04 245 tr.625ac.25prg.125 45.31 40.35 -4.96 -0.133 0.84616E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 14.7990000 g New total amount of reactant added: 15.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8624E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 15.1990000 Water: Moles liquid = 0.5539E+02 kg liquid = 0.9978E+00 Moles total = 0.5532E+02 kg total = 0.9966E+00 Activity = 1.0000 Stoichiometric ionic strength = .5147369E-02 Osmotic coef. = 0.9620 True ionic strength = .9228333E-02 Chg. balance for total moles = 0.8624E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15054E-09 -9.8223 0.13209E-09 -9.8791 0.87739E+00 -0.0568 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13796E-03 -3.8602 0.12066E-03 -3.9184 0.87460E+00 -0.0582 4 SO4-- 0.25543E-04 -4.5927 0.15871E-04 -4.7994 0.62136E+00 -0.2067 5 HCO3- 0.65903E-05 -5.1811 0.57683E-05 -5.2390 0.87527E+00 -0.0579 6 HS- 0.10177E-11 -11.9924 0.89013E-12 -12.0505 0.87467E+00 -0.0582 7 Al+++ 0.59055E-27 -27.2287 0.20557E-27 -27.6870 0.34809E+00 -0.4583 8 H4SiO4 0.44332E-03 -3.3533 0.44332E-03 -3.3533 0.10000E+01 0.0000 9 Ca++ 0.41340E-07 -7.3836 0.25588E-07 -7.5920 0.61897E+00 -0.2083 10 Mg++ 0.20251E-10 -10.6936 0.12504E-10 -10.9029 0.61748E+00 -0.2094 11 Fe++ 0.11971E-12 -12.9219 0.73963E-13 -13.1310 0.61784E+00 -0.2091 12 K+ 0.71832E-04 -4.1437 0.62881E-04 -4.2015 0.87539E+00 -0.0578 13 Na+ 0.91238E-02 -2.0398 0.79790E-02 -2.0981 0.87453E+00 -0.0582 14 Mn++ 0.15990E-10 -10.7961 0.98837E-11 -11.0051 0.61811E+00 -0.2089 15 HPO4-- 0.49141E-06 -6.3086 0.30536E-06 -6.5152 0.62140E+00 -0.2066 16 HSiO3- 0.37442E-02 -2.4266 0.32747E-02 -2.4848 0.87460E+00 -0.0582 17 Ca(HSiO3)+ 0.21444E-08 -8.6687 0.18774E-08 -8.7264 0.87549E+00 -0.0578 18 Mg(HSiO3)+ 0.13042E-11 -11.8847 0.11418E-11 -11.9424 0.87549E+00 -0.0578 19 NaHSiO3,aq 0.41498E-03 -3.3820 0.41498E-03 -3.3820 0.10000E+01 0.0000 20 AlO+ 0.17374E-14 -14.7601 0.15211E-14 -14.8178 0.87549E+00 -0.0578 22 HAlO2,aq 0.23044E-08 -8.6374 0.23044E-08 -8.6374 0.10000E+01 0.0000 23 AlO2- 0.44583E-04 -4.3508 0.38956E-04 -4.4094 0.87377E+00 -0.0586 24 CH4,aq 0.31795E-18 -18.4976 0.31745E-18 -18.4983 0.99841E+00 -0.0007 29 CO,aq 0.67634E-19 -19.1698 0.67634E-19 -19.1698 0.10000E+01 0.0000 30 CO2,aq 0.15386E-08 -8.8129 0.15362E-08 -8.8136 0.99841E+00 -0.0007 31 CO3-2 0.65056E-05 -5.1867 0.40378E-05 -5.3939 0.62066E+00 -0.2071 32 CaCO3,aq 0.12654E-08 -8.8978 0.12654E-08 -8.8978 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.42481E-11 -11.3718 0.37191E-11 -11.4296 0.87549E+00 -0.0578 34 CaCl+ 0.56197E-11 -11.2503 0.49200E-11 -11.3080 0.87549E+00 -0.0578 35 CaCl2,aq 0.13823E-15 -15.8594 0.13823E-15 -15.8594 0.10000E+01 0.0000 36 CaOH+ 0.15603E-07 -7.8068 0.13660E-07 -7.8645 0.87549E+00 -0.0578 37 CaSO4,aq 0.12654E-09 -9.8978 0.12654E-09 -9.8978 0.10000E+01 0.0000 38 HCl,aq 0.29979E-14 -14.5232 0.29979E-14 -14.5232 0.10000E+01 0.0000 43 FeCl+ 0.15877E-16 -16.7992 0.13900E-16 -16.8570 0.87549E+00 -0.0578 46 FeO,aq 0.16764E-09 -9.7756 0.16764E-09 -9.7756 0.10000E+01 0.0000 47 FeOH+ 0.21204E-10 -10.6736 0.18564E-10 -10.7313 0.87549E+00 -0.0578 48 HFeO2- 0.15609E-07 -7.8066 0.13651E-07 -7.8648 0.87460E+00 -0.0582 49 FeO+ 0.12480E-14 -14.9038 0.10926E-14 -14.9615 0.87549E+00 -0.0578 51 FeO2- 0.14073E-07 -7.8516 0.12309E-07 -7.9098 0.87460E+00 -0.0582 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.17122E-08 -8.7665 0.17095E-08 -8.7671 0.99841E+00 -0.0007 54 KCl,aq 0.13435E-09 -9.8718 0.13435E-09 -9.8718 0.10000E+01 0.0000 55 KHSO4,aq 0.35275E-18 -18.4525 0.35275E-18 -18.4525 0.10000E+01 0.0000 56 KOH,aq 0.20754E-06 -6.6829 0.20754E-06 -6.6829 0.10000E+01 0.0000 57 KSO4- 0.17580E-07 -7.7550 0.15375E-07 -7.8132 0.87460E+00 -0.0582 58 MgCO3,aq 0.15452E-12 -12.8110 0.15452E-12 -12.8110 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21169E-14 -14.6743 0.18533E-14 -14.7321 0.87549E+00 -0.0578 60 MgCl+ 0.24931E-14 -14.6033 0.21827E-14 -14.6610 0.87549E+00 -0.0578 61 MgOH+ 0.42242E-10 -10.3743 0.36982E-10 -10.4320 0.87549E+00 -0.0578 63 MnO,aq 0.59802E-09 -9.2233 0.59802E-09 -9.2233 0.10000E+01 0.0000 64 MnOH+ 0.26322E-09 -9.5797 0.23045E-09 -9.6374 0.87549E+00 -0.0578 65 MnO2-2 0.19099E-11 -11.7190 0.11854E-11 -11.9261 0.62066E+00 -0.2071 66 HMnO2- 0.38788E-10 -10.4113 0.33924E-10 -10.4695 0.87460E+00 -0.0582 69 MnCl+ 0.82444E-14 -14.0838 0.72179E-14 -14.1416 0.87549E+00 -0.0578 70 MnSO4,aq 0.44456E-13 -13.3521 0.44456E-13 -13.3521 0.10000E+01 0.0000 71 NaCl,aq 0.31437E-06 -6.5026 0.31437E-06 -6.5026 0.10000E+01 0.0000 72 NaOH,aq 0.26544E-04 -4.5760 0.26544E-04 -4.5760 0.10000E+01 0.0000 74 OH- 0.51973E-02 -2.2842 0.45412E-02 -2.3428 0.87377E+00 -0.0586 79 HPO3-2 0.26565E-17 -17.5757 0.16488E-17 -17.7828 0.62066E+00 -0.2071 82 H3PO4,aq 0.34299E-16 -16.4647 0.34299E-16 -16.4647 0.10000E+01 0.0000 83 H2PO4- 0.80813E-09 -9.0925 0.70714E-09 -9.1505 0.87504E+00 -0.0580 84 PO4-3 0.56518E-08 -8.2478 0.20190E-08 -8.6949 0.35722E+00 -0.4471 87 H2P2O7-2 0.63056E-19 -19.2003 0.39136E-19 -19.4074 0.62066E+00 -0.2071 88 HP2O7-3 0.17447E-15 -15.7583 0.60756E-16 -16.2164 0.34824E+00 -0.4581 89 P2O7-4 0.71991E-15 -15.1427 0.11347E-15 -15.9451 0.15762E+00 -0.8024 90 H2S,aq 0.35382E-15 -15.4512 0.35326E-15 -15.4519 0.99841E+00 -0.0007 97 SO3-2 0.59152E-14 -14.2280 0.36993E-14 -14.4319 0.62540E+00 -0.2038 98 HSO3- 0.32695E-16 -16.4855 0.28596E-16 -16.5437 0.87460E+00 -0.0582 99 HSO4- 0.22207E-11 -11.6535 0.19451E-11 -11.7110 0.87593E+00 -0.0575 Charge balance for all species = 0.8523E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1505445E-09 -.9568148E-02 -.9637533E+01 0.0000 2 H2O 0.1000000E+01 0.5550940E+02 0.9993356E+06 0.0000 3 Cl- 0.1379627E-03 0.1382772E-03 0.4898992E+01 5.9607 4 SO4-- 0.2554277E-04 0.2556183E-04 0.2453833E+01 14.9589 5 HCO3- 0.6590293E-05 0.1309870E-04 0.7987002E+00 4.6402 6 HS- 0.1017672E-11 -.1355555E-08 -.4480029E-04 -2.1714 7 Al+++ 0.5905548E-27 0.4458574E-04 0.1202169E+01 1.9504 8 H4SiO4 0.4433247E-03 0.4602471E-02 0.4420662E+03 -3.3533 9 Ca++ 0.4134030E-07 0.6048940E-07 0.2422638E-02 12.1663 10 Mg++ 0.2025084E-10 0.6395577E-10 0.1553831E-05 8.8553 11 Fe++ 0.1197136E-12 0.3007453E-07 0.1678425E-02 6.6273 12 K+ 0.7183171E-04 0.7205696E-04 0.2815647E+01 5.6777 13 Na+ 0.9123802E-02 0.9565645E-02 0.2197621E+03 7.7811 14 Mn++ 0.1599030E-10 0.9179887E-09 0.5039802E-04 8.7532 15 HPO4-- 0.4914065E-06 0.4978664E-06 0.4775208E-01 13.2431 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2516598E+00 -.9547183E-02 -.2421127E+00 0.0000000E+00 2 H2O 0.5531772E+02 0.5538778E+02 -.7005168E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4467206E-03 0.2550582E-04 0.4212147E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4212161E-03 -.1352584E-08 -.4212147E-03 0.0000000E+00 7 Al+++ 0.4956001E-01 0.4448805E-04 0.4951552E-01 0.0000000E+00 8 H4SiO4 0.1582639E+00 0.4592386E-02 0.1536715E+00 0.0000000E+00 9 Ca++ 0.1749549E-01 0.6035686E-07 0.1749543E-01 0.0000000E+00 10 Mg++ 0.1206270E-01 0.6381563E-10 0.1206270E-01 0.0000000E+00 11 Fe++ 0.1083702E-01 0.3000864E-07 0.1083699E-01 0.0000000E+00 12 K+ 0.3226964E-02 0.7189907E-04 0.3155065E-02 0.0000000E+00 13 Na+ 0.1923852E-01 0.9544685E-02 0.9693834E-02 0.0000000E+00 14 Mn++ 0.2635293E-03 0.9159773E-09 0.2635284E-03 0.0000000E+00 15 HPO4-- 0.8994125E-04 0.4967755E-06 0.8944447E-04 0.0000000E+00 Chg. balance for solid moles: 0.1743E-16 Mass of aqueous solution: 0.998491E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 15.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9694E-02 -2.014 2.542 0.405 15.32 0.9758 andradite 0.9522E-03 -3.021 0.4839 -0.315 2.916 0.1257 grossular 0.5755E-04 -4.240 0.2593E-01 -1.586 0.1562 0.7214E-02 apatite-OH 0.2981E-04 -4.526 0.1498E-01 -1.825 0.9025E-01 0.4759E-02 clinochlore 0.2413E-02 -2.618 1.341 0.127 8.080 0.5101 daphnite 0.1493E-02 -2.826 1.066 0.028 6.421 0.3229 chlorite-Mn 0.5271E-04 -4.278 0.3737E-01 -1.428 0.2252 0.1191E-01 hematite 0.7326E-03 -3.135 0.1170 -0.932 0.7050 0.2218E-01 microcline 0.3155E-02 -2.501 0.8782 -0.056 5.292 0.3430 stilbite 0.1432E-01 -1.844 10.09 1.004 60.80 4.706 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9430E+00 0.9430E+00 1.0000 -0.025 grossular 0.5700E-01 0.5700E-01 1.0000 -1.244 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 16.595339 g Volume = 7.029504 cm3 Porosity: 0.7076% V(tot) - V(min): 0.50096E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 15.1990000 g log = 1.1818 Original solution: 1000.0103000 g Original solution / Rock added: 65.79 (Water/Rock Ratio), log = 1.8182 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1659E-06 1.0073 0.1758E-06 0.1746E-06 CH4,gas 0.4711E-15 1.0129 0.5020E-15 0.4956E-15 H2,gas 0.2228E-05 1.0006 0.2345E-05 0.2343E-05 H2S,gas 0.9835E-14 0.9959 0.1030E-13 0.1035E-13 S2,gas 0.6875E-36 1.0000 0.7232E-36 0.7232E-36 CO,gas 0.1015E-15 1.0000 0.1068E-15 0.1068E-15 SO3,gas 0.9841E-40 1.0000 0.1035E-39 0.1035E-39 SO2,gas 0.8729E-23 1.0000 0.9182E-23 0.9182E-23 HCl,gas 0.5032E-17 1.0000 0.5293E-17 0.5293E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.12 -8.75 -2.918 0.14949E+05 -6.755 3 CH4,gas 4.81 -12.49 -17.30 -4.325 0.29538E+05 -15.299 4 H2,gas 8.29 0.66 -7.63 -4.360 0.13028E+05 -5.630 5 H2S,gas -5.94 -21.93 -15.99 -7.994 0.27297E+05 -13.987 6 S2,gas -7.03 -45.17 -38.14 -5.868 0.65124E+05 -36.141 7 CO,gas 3.51 -14.46 -17.97 -5.530 0.30686E+05 -15.971 8 SO3,gas 17.43 -24.56 -41.98 -10.496 0.71688E+05 -39.985 9 SO2,gas 1.14 -23.90 -25.04 -6.677 0.42750E+05 -23.037 10 HCl,gas 5.48 -13.80 -19.28 -9.638 0.32914E+05 -17.276 11 acmite 7.74 7.37 -0.36 -0.038 0.62160E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.10 -4.45 -0.222 0.75972E+04 20 analcite 3.37 3.02 -0.35 -0.038 0.59031E+03 21 andalusite 5.06 0.55 -4.51 -0.451 0.77090E+04 26 annite 20.21 17.45 -2.76 -0.153 0.47113E+04 27 phlogopite 27.15 24.13 -3.01 -0.167 0.51435E+04 29 anorthite 12.80 9.36 -3.44 -0.264 0.58688E+04 35 aragonite 0.99 -2.95 -3.94 -1.313 0.67240E+04 36 brucite 12.58 8.86 -3.72 -0.744 0.63539E+04 37 calcite 0.83 -2.95 -3.78 -1.262 0.64627E+04 38 carnegieite-low 9.06 6.38 -2.69 -0.384 0.45869E+04 39 carnegieite-high 10.13 6.38 -3.76 -0.537 0.64137E+04 40 carpholite-Mg 8.65 6.05 -2.60 -0.173 0.44408E+04 41 carpholite-Fe 6.78 3.82 -2.96 -0.197 0.50565E+04 42 celadonite 5.40 3.07 -2.33 -0.137 0.39788E+04 43 celadonite-Fe 3.94 0.84 -3.09 -0.182 0.52841E+04 44 chrysotile 23.94 19.86 -4.08 -0.340 0.69628E+04 50 chloritoid-Mg 13.26 9.40 -3.86 -0.257 0.65881E+04 51 chloritoid-Fe 9.24 7.17 -2.06 -0.138 0.35240E+04 52 chloritoid-Mn 11.46 9.30 -2.16 -0.144 0.36924E+04 54 coesite -2.37 -3.35 -0.98 -0.328 0.16800E+04 59 corundum 8.43 3.90 -4.53 -0.412 0.77394E+04 61 cristobalite -2.55 -3.35 -0.80 -0.268 0.13729E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.95 -0.95 -0.158 0.16148E+04 67 diopside 16.22 14.32 -1.90 -0.190 0.32448E+04 68 hedenbergite 14.24 12.09 -2.16 -0.216 0.36836E+04 75 epidote 24.78 24.47 -0.30 -0.015 0.51704E+03 76 clinozoisite 22.92 20.12 -2.80 -0.127 0.47761E+04 77 epidote-Fe 29.94 28.82 -1.12 -0.058 0.19055E+04 78 fayalite 14.08 9.90 -4.18 -0.597 0.71332E+04 79 ferrosilite 11.19 6.55 -4.64 -0.464 0.79221E+04 83 gibbsite 4.10 1.95 -2.15 -0.307 0.36660E+04 84 glaucophane 23.11 19.20 -3.91 -0.106 0.66724E+04 85 glaucophane-Fe 17.42 12.52 -4.90 -0.132 0.83642E+04 87 greenalite 16.19 13.18 -3.02 -0.252 0.51546E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.02 -1.23 -0.123 0.20933E+04 96 julgoldite 70.57 67.00 -3.58 -0.093 0.61083E+04 97 kalsilite 7.62 4.27 -3.35 -0.478 0.57123E+04 98 kaolinite -1.27 -2.81 -1.53 -0.139 0.26170E+04 99 kyanite 4.93 0.55 -4.38 -0.438 0.74858E+04 101 laumontite 2.97 2.65 -0.32 -0.021 0.54736E+03 102 lawsonite 9.68 9.36 -0.32 -0.021 0.54270E+03 103 leucite 4.17 0.92 -3.25 -0.325 0.55427E+04 105 lizardite 23.29 19.86 -3.43 -0.286 0.58531E+04 107 magnetite 20.13 19.22 -0.91 -0.074 0.15502E+04 108 minnesotaite 10.46 6.47 -3.99 -0.235 0.68161E+04 110 magnesioferrite 26.26 21.45 -4.80 -0.392 0.82032E+04 113 margarite 17.45 13.26 -4.19 -0.168 0.71552E+04 120 muscovite 2.68 1.47 -1.21 -0.071 0.20664E+04 121 paragonite 4.34 3.57 -0.76 -0.045 0.13049E+04 122 nepheline 8.38 6.38 -2.00 -0.286 0.34148E+04 134 phlogopite-Na 29.73 26.24 -3.49 -0.194 0.59654E+04 136 prehnite 19.47 18.17 -1.29 -0.076 0.22073E+04 137 prehnite-Fe 22.59 22.52 -0.06 -0.004 0.11057E+03 138 pumpellyite-Fe 46.47 44.92 -1.55 -0.034 0.26393E+04 139 pumpellyite-Mg 49.19 47.15 -2.04 -0.045 0.34852E+04 145 pyroxmangite 7.42 5.40 -2.02 -0.403 0.34425E+04 146 pyrophyllite -6.10 -9.51 -3.41 -0.213 0.58299E+04 147 quartz -2.98 -3.35 -0.37 -0.124 0.63395E+03 152 rhodonite 7.46 5.40 -2.06 -0.413 0.35217E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.55 -4.77 -0.477 0.81512E+04 164 stilpnomelane-Fe 13.18 13.05 -0.13 -0.004 0.22109E+03 165 stilpnomelane-Mg 27.60 24.19 -3.41 -0.102 0.58159E+04 171 talc 16.55 13.15 -3.40 -0.200 0.58061E+04 174 tephroite 18.11 14.15 -3.96 -0.566 0.67612E+04 177 topaz-H 4.67 0.55 -4.12 -0.375 0.70349E+04 178 tridymite -2.61 -3.35 -0.74 -0.246 0.12612E+04 187 wairakite 4.06 2.65 -1.40 -0.083 0.23982E+04 188 walstromite 11.53 8.81 -2.71 -0.543 0.46355E+04 189 wollastonite 10.48 8.81 -1.67 -0.334 0.28494E+04 190 pseudo-wollastonite 11.02 8.81 -2.21 -0.441 0.37680E+04 191 zoisite 22.96 20.12 -2.84 -0.129 0.48487E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.75 -4.20 -0.260 0.71629E+04 195 beidellite-K -1.44 -5.89 -4.45 -0.273 0.76042E+04 196 beidellite-Mg -1.71 -6.30 -4.59 -0.284 0.78443E+04 197 beidellite-Na -1.26 -5.19 -3.94 -0.241 0.67229E+04 199 chalcedony -2.79 -3.35 -0.56 -0.186 0.95427E+03 201 montmorillonite-Ca -2.21 -5.23 -3.01 -0.186 0.51433E+04 202 montmorillonite-K -2.16 -5.36 -3.20 -0.196 0.54624E+04 203 montmorillonite-Mg -2.40 -5.77 -3.37 -0.209 0.57558E+04 204 montmorillonite-Na -1.96 -4.67 -2.71 -0.166 0.46193E+04 205 nontronite-Ca 3.28 2.94 -0.34 -0.022 0.57627E+03 206 nontronite-H 2.60 0.93 -1.66 -0.111 0.28362E+04 207 nontronite-K 3.40 2.81 -0.60 -0.038 0.10168E+04 208 nontronite-Mg 3.14 2.40 -0.74 -0.048 0.12693E+04 209 nontronite-Na 3.58 3.50 -0.08 -0.005 0.13718E+03 224 tobermorite 9.84 6.78 -3.06 -0.834 0.52210E+04 233 boehmite 4.43 1.95 -2.48 -0.413 0.42332E+04 235 ferrous-oxide 9.82 6.63 -3.20 -0.799 0.54587E+04 240 silica-amorphous -2.08 -3.35 -1.27 -0.424 0.21745E+04 242 an20ab80 2.08 1.61 -0.47 -0.036 0.80215E+03 243 an25ab75 2.71 2.09 -0.62 -0.047 0.10506E+04 244 an30ab70 3.34 2.58 -0.77 -0.059 0.13074E+04 245 tr.625ac.25prg.125 45.31 40.43 -4.87 -0.131 0.83232E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 15.1990000 g New total amount of reactant added: 15.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8618E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 15.5990000 Water: Moles liquid = 0.5538E+02 kg liquid = 0.9978E+00 Moles total = 0.5531E+02 kg total = 0.9965E+00 Activity = 1.0000 Stoichiometric ionic strength = .5163927E-02 Osmotic coef. = 0.9619 True ionic strength = .9279967E-02 Chg. balance for total moles = 0.8618E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15119E-09 -9.8205 0.13262E-09 -9.8774 0.87716E+00 -0.0569 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13797E-03 -3.8602 0.12063E-03 -3.9185 0.87435E+00 -0.0583 4 SO4-- 0.25544E-04 -4.5927 0.15854E-04 -4.7999 0.62067E+00 -0.2071 5 HCO3- 0.66010E-05 -5.1804 0.57760E-05 -5.2384 0.87503E+00 -0.0580 6 HS- 0.11466E-11 -11.9406 0.10026E-11 -11.9989 0.87442E+00 -0.0583 7 Al+++ 0.55800E-27 -27.2534 0.19374E-27 -27.7128 0.34721E+00 -0.4594 8 H4SiO4 0.45378E-03 -3.3432 0.45378E-03 -3.3432 0.10000E+01 0.0000 9 Ca++ 0.40865E-07 -7.3886 0.25266E-07 -7.5975 0.61827E+00 -0.2088 10 Mg++ 0.20736E-10 -10.6833 0.12789E-10 -10.8932 0.61678E+00 -0.2099 11 Fe++ 0.12258E-12 -12.9116 0.75648E-13 -13.1212 0.61713E+00 -0.2096 12 K+ 0.72235E-04 -4.1413 0.63216E-04 -4.1992 0.87514E+00 -0.0579 13 Na+ 0.91750E-02 -2.0374 0.80215E-02 -2.0957 0.87428E+00 -0.0583 14 Mn++ 0.16373E-10 -10.7859 0.10109E-10 -10.9953 0.61740E+00 -0.2094 15 HPO4-- 0.50516E-06 -6.2966 0.31356E-06 -6.5037 0.62071E+00 -0.2071 16 HSiO3- 0.38183E-02 -2.4181 0.33385E-02 -2.4764 0.87435E+00 -0.0583 17 Ca(HSiO3)+ 0.21593E-08 -8.6657 0.18899E-08 -8.7236 0.87524E+00 -0.0579 18 Mg(HSiO3)+ 0.13603E-11 -11.8664 0.11906E-11 -11.9243 0.87524E+00 -0.0579 19 NaHSiO3,aq 0.42533E-03 -3.3713 0.42533E-03 -3.3713 0.10000E+01 0.0000 20 AlO+ 0.16249E-14 -14.7892 0.14222E-14 -14.8471 0.87524E+00 -0.0579 22 HAlO2,aq 0.21459E-08 -8.6684 0.21459E-08 -8.6684 0.10000E+01 0.0000 23 AlO2- 0.41363E-04 -4.3834 0.36132E-04 -4.4421 0.87351E+00 -0.0587 24 CH4,aq 0.35901E-18 -18.4449 0.35844E-18 -18.4456 0.99841E+00 -0.0007 29 CO,aq 0.69999E-19 -19.1549 0.69999E-19 -19.1549 0.10000E+01 0.0000 30 CO2,aq 0.15469E-08 -8.8105 0.15444E-08 -8.8112 0.99841E+00 -0.0007 31 CO3-2 0.64955E-05 -5.1874 0.40270E-05 -5.3950 0.61997E+00 -0.2076 32 CaCO3,aq 0.12461E-08 -8.9044 0.12461E-08 -8.9044 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.42013E-11 -11.3766 0.36772E-11 -11.4345 0.87524E+00 -0.0579 34 CaCl+ 0.55490E-11 -11.2558 0.48568E-11 -11.3137 0.87524E+00 -0.0579 35 CaCl2,aq 0.13641E-15 -15.8651 0.13641E-15 -15.8651 0.10000E+01 0.0000 36 CaOH+ 0.15349E-07 -7.8139 0.13434E-07 -7.8718 0.87524E+00 -0.0579 37 CaSO4,aq 0.12481E-09 -9.9038 0.12481E-09 -9.9038 0.10000E+01 0.0000 38 HCl,aq 0.30091E-14 -14.5216 0.30091E-14 -14.5216 0.10000E+01 0.0000 43 FeCl+ 0.16239E-16 -16.7894 0.14213E-16 -16.8473 0.87524E+00 -0.0579 46 FeO,aq 0.17009E-09 -9.7693 0.17009E-09 -9.7693 0.10000E+01 0.0000 47 FeOH+ 0.21607E-10 -10.6654 0.18911E-10 -10.7233 0.87524E+00 -0.0579 48 HFeO2- 0.15778E-07 -7.8019 0.13796E-07 -7.8603 0.87435E+00 -0.0583 49 FeO+ 0.12534E-14 -14.9019 0.10970E-14 -14.9598 0.87524E+00 -0.0579 51 FeO2- 0.14021E-07 -7.8532 0.12260E-07 -7.9115 0.87435E+00 -0.0583 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.17626E-08 -8.7538 0.17598E-08 -8.7545 0.99841E+00 -0.0007 54 KCl,aq 0.13503E-09 -9.8696 0.13503E-09 -9.8696 0.10000E+01 0.0000 55 KHSO4,aq 0.35567E-18 -18.4490 0.35567E-18 -18.4490 0.10000E+01 0.0000 56 KOH,aq 0.20781E-06 -6.6823 0.20781E-06 -6.6823 0.10000E+01 0.0000 57 KSO4- 0.17660E-07 -7.7530 0.15441E-07 -7.8113 0.87435E+00 -0.0583 58 MgCO3,aq 0.15762E-12 -12.8024 0.15762E-12 -12.8024 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21686E-14 -14.6638 0.18981E-14 -14.7217 0.87524E+00 -0.0579 60 MgCl+ 0.25499E-14 -14.5935 0.22318E-14 -14.6513 0.87524E+00 -0.0579 61 MgOH+ 0.43043E-10 -10.3661 0.37673E-10 -10.4240 0.87524E+00 -0.0579 63 MnO,aq 0.60676E-09 -9.2170 0.60676E-09 -9.2170 0.10000E+01 0.0000 64 MnOH+ 0.26822E-09 -9.5715 0.23476E-09 -9.6294 0.87524E+00 -0.0579 65 MnO2-2 0.19245E-11 -11.7157 0.11931E-11 -11.9233 0.61997E+00 -0.2076 66 HMnO2- 0.39209E-10 -10.4066 0.34283E-10 -10.4649 0.87435E+00 -0.0583 69 MnCl+ 0.84324E-14 -14.0740 0.73804E-14 -14.1319 0.87524E+00 -0.0579 70 MnSO4,aq 0.45420E-13 -13.3428 0.45420E-13 -13.3428 0.10000E+01 0.0000 71 NaCl,aq 0.31596E-06 -6.5004 0.31596E-06 -6.5004 0.10000E+01 0.0000 72 NaOH,aq 0.26578E-04 -4.5755 0.26578E-04 -4.5755 0.10000E+01 0.0000 74 OH- 0.51780E-02 -2.2858 0.45231E-02 -2.3446 0.87351E+00 -0.0587 79 HPO3-2 0.28113E-17 -17.5511 0.17429E-17 -17.7587 0.61997E+00 -0.2076 82 H3PO4,aq 0.35503E-16 -16.4497 0.35503E-16 -16.4497 0.10000E+01 0.0000 83 H2PO4- 0.83338E-09 -9.0792 0.72903E-09 -9.1373 0.87479E+00 -0.0581 84 PO4-3 0.57942E-08 -8.2370 0.20649E-08 -8.6851 0.35636E+00 -0.4481 87 H2P2O7-2 0.67095E-19 -19.1733 0.41597E-19 -19.3809 0.61997E+00 -0.2076 88 HP2O7-3 0.18516E-15 -15.7324 0.64318E-16 -16.1917 0.34736E+00 -0.4592 89 P2O7-4 0.76244E-15 -15.1178 0.11965E-15 -15.9221 0.15693E+00 -0.8043 90 H2S,aq 0.40014E-15 -15.3978 0.39951E-15 -15.3985 0.99841E+00 -0.0007 97 SO3-2 0.60894E-14 -14.2154 0.38042E-14 -14.4197 0.62472E+00 -0.2043 98 HSO3- 0.33767E-16 -16.4715 0.29524E-16 -16.5298 0.87435E+00 -0.0583 99 HSO4- 0.22278E-11 -11.6521 0.19509E-11 -11.7098 0.87568E+00 -0.0577 Charge balance for all species = 0.8539E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1511893E-09 -.9620462E-02 -.9690144E+01 0.0000 2 H2O 0.1000000E+01 0.5550929E+02 0.9993252E+06 0.0000 3 Cl- 0.1379673E-03 0.1382834E-03 0.4899170E+01 5.9589 4 SO4-- 0.2554383E-04 0.2556296E-04 0.2453921E+01 14.9549 5 HCO3- 0.6600967E-05 0.1309929E-04 0.7987293E+00 4.6390 6 HS- 0.1146639E-11 -.1336288E-08 -.4416315E-04 -2.1215 7 Al+++ 0.5579989E-27 0.4136553E-04 0.1115332E+01 1.9194 8 H4SiO4 0.4537819E-03 0.4697366E-02 0.4511770E+03 -3.3432 9 Ca++ 0.4086527E-07 0.5975411E-07 0.2393170E-02 12.1573 10 Mg++ 0.2073574E-10 0.6530148E-10 0.1586512E-05 8.8617 11 Fe++ 0.1225797E-12 0.3019453E-07 0.1685108E-02 6.6336 12 K+ 0.7223468E-04 0.7246028E-04 0.2831383E+01 5.6782 13 Na+ 0.9175029E-02 0.9627254E-02 0.2211756E+03 7.7817 14 Mn++ 0.1637310E-10 0.9325448E-09 0.5119672E-04 8.7595 15 HPO4-- 0.5051565E-06 0.5117842E-06 0.4908657E-01 13.2511 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2582832E+00 -.9598952E-02 -.2486843E+00 0.0000000E+00 2 H2O 0.5531271E+02 0.5538518E+02 -.7247289E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4578059E-03 0.2550580E-04 0.4323001E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4323015E-03 -.1333300E-08 -.4323001E-03 0.0000000E+00 7 Al+++ 0.5086431E-01 0.4127304E-04 0.5082304E-01 0.0000000E+00 8 H4SiO4 0.1624290E+00 0.4686863E-02 0.1577421E+00 0.0000000E+00 9 Ca++ 0.1795555E-01 0.5962051E-07 0.1795549E-01 0.0000000E+00 10 Mg++ 0.1238016E-01 0.6515547E-10 0.1238016E-01 0.0000000E+00 11 Fe++ 0.1112222E-01 0.3012702E-07 0.1112219E-01 0.0000000E+00 12 K+ 0.3311890E-02 0.7229827E-04 0.3239591E-02 0.0000000E+00 13 Na+ 0.1974062E-01 0.9605728E-02 0.1013489E-01 0.0000000E+00 14 Mn++ 0.2704648E-03 0.9304597E-09 0.2704638E-03 0.0000000E+00 15 HPO4-- 0.9230828E-04 0.5106399E-06 0.9179764E-04 0.0000000E+00 Chg. balance for solid moles: 0.2927E-17 Mass of aqueous solution: 0.998454E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 15.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1013E-01 -1.994 2.658 0.424 15.61 1.020 andradite 0.1009E-02 -2.996 0.5128 -0.290 3.012 0.1332 grossular 0.5680E-04 -4.246 0.2559E-01 -1.592 0.1503 0.7119E-02 apatite-OH 0.3060E-04 -4.514 0.1537E-01 -1.813 0.9026E-01 0.4884E-02 clinochlore 0.2476E-02 -2.606 1.376 0.139 8.082 0.5235 daphnite 0.1533E-02 -2.815 1.094 0.039 6.422 0.3314 chlorite-Mn 0.5409E-04 -4.267 0.3835E-01 -1.416 0.2252 0.1222E-01 hematite 0.7200E-03 -3.143 0.1150 -0.939 0.6753 0.2179E-01 microcline 0.3240E-02 -2.490 0.9017 -0.045 5.295 0.3522 stilbite 0.1460E-01 -1.836 10.29 1.013 60.44 4.800 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9467E+00 0.9467E+00 1.0000 -0.024 grossular 0.5329E-01 0.5329E-01 1.0000 -1.273 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 17.028452 g Volume = 7.207006 cm3 Porosity: 0.4502% V(tot) - V(min): 0.32594E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 15.5990000 g log = 1.1931 Original solution: 1000.0103000 g Original solution / Rock added: 64.11 (Water/Rock Ratio), log = 1.8069 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1668E-06 1.0073 0.1768E-06 0.1755E-06 CH4,gas 0.5320E-15 1.0129 0.5668E-15 0.5596E-15 H2,gas 0.2293E-05 1.0006 0.2414E-05 0.2412E-05 H2S,gas 0.1112E-13 0.9959 0.1165E-13 0.1170E-13 S2,gas 0.8298E-36 1.0000 0.8728E-36 0.8728E-36 CO,gas 0.1051E-15 1.0000 0.1105E-15 0.1105E-15 SO3,gas 0.9910E-40 1.0000 0.1042E-39 0.1042E-39 SO2,gas 0.9048E-23 1.0000 0.9518E-23 0.9518E-23 HCl,gas 0.5051E-17 1.0000 0.5313E-17 0.5313E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.12 -8.75 -2.918 0.14945E+05 -6.753 3 CH4,gas 4.81 -12.44 -17.25 -4.312 0.29448E+05 -15.247 4 H2,gas 8.29 0.67 -7.62 -4.353 0.13006E+05 -5.617 5 H2S,gas -5.94 -21.88 -15.93 -7.967 0.27206E+05 -13.934 6 S2,gas -7.03 -45.09 -38.06 -5.855 0.64985E+05 -36.059 7 CO,gas 3.51 -14.45 -17.96 -5.525 0.30660E+05 -15.957 8 SO3,gas 17.43 -24.55 -41.98 -10.495 0.71683E+05 -39.982 9 SO2,gas 1.14 -23.89 -25.02 -6.672 0.42723E+05 -23.021 10 HCl,gas 5.48 -13.80 -19.27 -9.637 0.32911E+05 -17.275 11 acmite 7.74 7.39 -0.34 -0.036 0.58606E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.09 -4.46 -0.223 0.76187E+04 20 analcite 3.37 3.01 -0.36 -0.040 0.60760E+03 21 andalusite 5.06 0.50 -4.57 -0.457 0.77974E+04 26 annite 20.21 17.47 -2.74 -0.152 0.46790E+04 27 phlogopite 27.15 24.15 -2.99 -0.166 0.51112E+04 29 anorthite 12.80 9.31 -3.49 -0.268 0.59553E+04 35 aragonite 0.99 -2.96 -3.94 -1.315 0.67354E+04 36 brucite 12.58 8.86 -3.71 -0.743 0.63432E+04 37 calcite 0.83 -2.96 -3.79 -1.264 0.64741E+04 38 carnegieite-low 9.06 6.36 -2.71 -0.387 0.46215E+04 39 carnegieite-high 10.13 6.36 -3.78 -0.540 0.64483E+04 40 carpholite-Mg 8.65 6.01 -2.64 -0.176 0.45012E+04 41 carpholite-Fe 6.78 3.79 -3.00 -0.200 0.51168E+04 42 celadonite 5.40 3.09 -2.31 -0.136 0.39508E+04 43 celadonite-Fe 3.94 0.86 -3.08 -0.181 0.52561E+04 44 chrysotile 23.94 19.90 -4.04 -0.337 0.68959E+04 50 chloritoid-Mg 13.26 9.36 -3.90 -0.260 0.66657E+04 51 chloritoid-Fe 9.24 7.13 -2.11 -0.141 0.36017E+04 52 chloritoid-Mn 11.46 9.26 -2.21 -0.147 0.37701E+04 54 coesite -2.37 -3.34 -0.97 -0.325 0.16627E+04 59 corundum 8.43 3.84 -4.59 -0.418 0.78451E+04 61 cristobalite -2.55 -3.34 -0.79 -0.265 0.13556E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.92 -0.98 -0.163 0.16676E+04 67 diopside 16.22 14.33 -1.88 -0.188 0.32148E+04 68 hedenbergite 14.24 12.10 -2.14 -0.214 0.36536E+04 75 epidote 24.78 24.42 -0.35 -0.017 0.60154E+03 76 clinozoisite 22.92 20.04 -2.88 -0.131 0.49135E+04 77 epidote-Fe 29.94 28.80 -1.13 -0.059 0.19371E+04 78 fayalite 14.08 9.92 -4.15 -0.594 0.70944E+04 79 ferrosilite 11.19 6.58 -4.61 -0.461 0.78660E+04 83 gibbsite 4.10 1.92 -2.18 -0.311 0.37188E+04 84 glaucophane 23.11 19.24 -3.87 -0.105 0.66055E+04 85 glaucophane-Fe 17.42 12.56 -4.86 -0.131 0.82973E+04 87 greenalite 16.19 13.21 -2.98 -0.248 0.50878E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.01 -1.24 -0.124 0.21106E+04 96 julgoldite 70.57 67.03 -3.54 -0.092 0.60444E+04 97 kalsilite 7.62 4.25 -3.37 -0.481 0.57469E+04 98 kaolinite -1.27 -2.85 -1.57 -0.143 0.26881E+04 99 kyanite 4.93 0.50 -4.44 -0.444 0.75742E+04 101 laumontite 2.97 2.62 -0.35 -0.023 0.59922E+03 102 lawsonite 9.68 9.31 -0.37 -0.025 0.62915E+03 103 leucite 4.17 0.91 -3.26 -0.326 0.55600E+04 105 lizardite 23.29 19.90 -3.39 -0.282 0.57862E+04 107 magnetite 20.13 19.23 -0.90 -0.074 0.15394E+04 108 minnesotaite 10.46 6.53 -3.93 -0.231 0.67147E+04 110 magnesioferrite 26.26 21.46 -4.80 -0.392 0.81925E+04 113 margarite 17.45 13.15 -4.30 -0.172 0.73473E+04 120 muscovite 2.68 1.41 -1.27 -0.075 0.21721E+04 121 paragonite 4.34 3.51 -0.83 -0.049 0.14106E+04 122 nepheline 8.38 6.36 -2.02 -0.289 0.34494E+04 134 phlogopite-Na 29.73 26.26 -3.47 -0.193 0.59331E+04 136 prehnite 19.47 18.12 -1.34 -0.079 0.22918E+04 137 prehnite-Fe 22.59 22.50 -0.08 -0.005 0.14223E+03 138 pumpellyite-Fe 46.47 44.80 -1.67 -0.037 0.28503E+04 139 pumpellyite-Mg 49.19 47.03 -2.16 -0.048 0.36963E+04 145 pyroxmangite 7.42 5.42 -2.00 -0.400 0.34144E+04 146 pyrophyllite -6.10 -9.53 -3.44 -0.215 0.58664E+04 147 quartz -2.98 -3.34 -0.36 -0.120 0.61666E+03 152 rhodonite 7.46 5.42 -2.05 -0.409 0.34936E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.50 -4.83 -0.483 0.82396E+04 164 stilpnomelane-Fe 13.18 13.10 -0.08 -0.002 0.13416E+03 165 stilpnomelane-Mg 27.60 24.24 -3.36 -0.100 0.57290E+04 171 talc 16.55 13.21 -3.34 -0.197 0.57047E+04 174 tephroite 18.11 14.18 -3.94 -0.562 0.67224E+04 177 topaz-H 4.67 0.50 -4.17 -0.379 0.71233E+04 178 tridymite -2.61 -3.34 -0.73 -0.243 0.12440E+04 187 wairakite 4.06 2.62 -1.43 -0.084 0.24500E+04 188 walstromite 11.53 8.81 -2.71 -0.543 0.46335E+04 189 wollastonite 10.48 8.81 -1.67 -0.334 0.28474E+04 190 pseudo-wollastonite 11.02 8.81 -2.21 -0.441 0.37661E+04 191 zoisite 22.96 20.04 -2.92 -0.133 0.49860E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.79 -4.23 -0.262 0.72251E+04 195 beidellite-K -1.44 -5.92 -4.49 -0.275 0.76636E+04 196 beidellite-Mg -1.71 -6.33 -4.63 -0.286 0.79022E+04 197 beidellite-Na -1.26 -5.23 -3.97 -0.243 0.67823E+04 199 chalcedony -2.79 -3.34 -0.55 -0.183 0.93698E+03 201 montmorillonite-Ca -2.21 -5.24 -3.02 -0.187 0.51614E+04 202 montmorillonite-K -2.16 -5.37 -3.21 -0.196 0.54776E+04 203 montmorillonite-Mg -2.40 -5.78 -3.38 -0.209 0.57696E+04 204 montmorillonite-Na -1.96 -4.67 -2.71 -0.166 0.46345E+04 205 nontronite-Ca 3.28 2.97 -0.31 -0.020 0.53279E+03 206 nontronite-H 2.60 0.96 -1.63 -0.110 0.27901E+04 207 nontronite-K 3.40 2.84 -0.57 -0.036 0.97043E+03 208 nontronite-Mg 3.14 2.42 -0.72 -0.046 0.12216E+04 209 nontronite-Na 3.58 3.53 -0.05 -0.003 0.90851E+02 224 tobermorite 9.84 6.78 -3.06 -0.834 0.52165E+04 233 boehmite 4.43 1.92 -2.51 -0.418 0.42860E+04 235 ferrous-oxide 9.82 6.63 -3.19 -0.798 0.54479E+04 240 silica-amorphous -2.08 -3.34 -1.26 -0.421 0.21572E+04 242 an20ab80 2.08 1.60 -0.48 -0.037 0.81944E+03 243 an25ab75 2.71 2.08 -0.63 -0.048 0.10722E+04 244 an30ab70 3.34 2.56 -0.78 -0.060 0.13333E+04 245 tr.625ac.25prg.125 45.31 40.51 -4.79 -0.129 0.81871E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 15.5990000 g New total amount of reactant added: 15.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8621E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 15.9990000 Water: Moles liquid = 0.5538E+02 kg liquid = 0.9977E+00 Moles total = 0.5531E+02 kg total = 0.9964E+00 Activity = 1.0000 Stoichiometric ionic strength = .5181721E-02 Osmotic coef. = 0.9619 True ionic strength = .9331574E-02 Chg. balance for total moles = 0.8621E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15185E-09 -9.8186 0.13316E-09 -9.8756 0.87692E+00 -0.0570 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13797E-03 -3.8602 0.12060E-03 -3.9186 0.87410E+00 -0.0584 4 SO4-- 0.25545E-04 -4.5927 0.15837E-04 -4.8003 0.61998E+00 -0.2076 5 HCO3- 0.66119E-05 -5.1797 0.57839E-05 -5.2378 0.87478E+00 -0.0581 6 HS- 0.12897E-11 -11.8895 0.11274E-11 -11.9479 0.87417E+00 -0.0584 7 Al+++ 0.52788E-27 -27.2775 0.18282E-27 -27.7380 0.34634E+00 -0.4605 8 H4SiO4 0.46434E-03 -3.3332 0.46434E-03 -3.3332 0.10000E+01 0.0000 9 Ca++ 0.40405E-07 -7.3936 0.24953E-07 -7.6029 0.61758E+00 -0.2093 10 Mg++ 0.21230E-10 -10.6730 0.13079E-10 -10.8834 0.61607E+00 -0.2104 11 Fe++ 0.12550E-12 -12.9013 0.77364E-13 -13.1115 0.61643E+00 -0.2101 12 K+ 0.72637E-04 -4.1388 0.63550E-04 -4.1969 0.87490E+00 -0.0580 13 Na+ 0.92262E-02 -2.0350 0.80640E-02 -2.0934 0.87403E+00 -0.0585 14 Mn++ 0.16764E-10 -10.7756 0.10338E-10 -10.9856 0.61670E+00 -0.2099 15 HPO4-- 0.51913E-06 -6.2847 0.32187E-06 -6.4923 0.62003E+00 -0.2076 16 HSiO3- 0.38923E-02 -2.4098 0.34023E-02 -2.4682 0.87410E+00 -0.0584 17 Ca(HSiO3)+ 0.21739E-08 -8.6628 0.19022E-08 -8.7207 0.87500E+00 -0.0580 18 Mg(HSiO3)+ 0.14181E-11 -11.8483 0.12408E-11 -11.9063 0.87500E+00 -0.0580 19 NaHSiO3,aq 0.43575E-03 -3.3608 0.43575E-03 -3.3608 0.10000E+01 0.0000 20 AlO+ 0.15213E-14 -14.8178 0.13311E-14 -14.8758 0.87500E+00 -0.0580 22 HAlO2,aq 0.20004E-08 -8.6989 0.20004E-08 -8.6989 0.10000E+01 0.0000 23 AlO2- 0.38412E-04 -4.4155 0.33544E-04 -4.4744 0.87326E+00 -0.0589 24 CH4,aq 0.40468E-18 -18.3929 0.40403E-18 -18.3936 0.99840E+00 -0.0007 29 CO,aq 0.72421E-19 -19.1401 0.72421E-19 -19.1401 0.10000E+01 0.0000 30 CO2,aq 0.15553E-08 -8.8082 0.15528E-08 -8.8089 0.99840E+00 -0.0007 31 CO3-2 0.64852E-05 -5.1881 0.40161E-05 -5.3962 0.61928E+00 -0.2081 32 CaCO3,aq 0.12274E-08 -8.9110 0.12274E-08 -8.9110 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41562E-11 -11.3813 0.36367E-11 -11.4393 0.87500E+00 -0.0580 34 CaCl+ 0.54806E-11 -11.2612 0.47955E-11 -11.3192 0.87500E+00 -0.0580 35 CaCl2,aq 0.13466E-15 -15.8708 0.13466E-15 -15.8708 0.10000E+01 0.0000 36 CaOH+ 0.15102E-07 -7.8210 0.13214E-07 -7.8790 0.87500E+00 -0.0580 37 CaSO4,aq 0.12313E-09 -9.9096 0.12313E-09 -9.9096 0.10000E+01 0.0000 38 HCl,aq 0.30207E-14 -14.5199 0.30207E-14 -14.5199 0.10000E+01 0.0000 43 FeCl+ 0.16608E-16 -16.7797 0.14532E-16 -16.8377 0.87500E+00 -0.0580 46 FeO,aq 0.17254E-09 -9.7631 0.17254E-09 -9.7631 0.10000E+01 0.0000 47 FeOH+ 0.22013E-10 -10.6573 0.19261E-10 -10.7153 0.87500E+00 -0.0580 48 HFeO2- 0.15945E-07 -7.7974 0.13937E-07 -7.8558 0.87410E+00 -0.0584 49 FeO+ 0.12589E-14 -14.9000 0.11015E-14 -14.9580 0.87500E+00 -0.0580 51 FeO2- 0.13968E-07 -7.8549 0.12210E-07 -7.9133 0.87410E+00 -0.0584 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.18137E-08 -8.7414 0.18108E-08 -8.7421 0.99840E+00 -0.0007 54 KCl,aq 0.13571E-09 -9.8674 0.13571E-09 -9.8674 0.10000E+01 0.0000 55 KHSO4,aq 0.35863E-18 -18.4454 0.35863E-18 -18.4454 0.10000E+01 0.0000 56 KOH,aq 0.20806E-06 -6.6818 0.20806E-06 -6.6818 0.10000E+01 0.0000 57 KSO4- 0.17739E-07 -7.7511 0.15506E-07 -7.8095 0.87410E+00 -0.0584 58 MgCO3,aq 0.16076E-12 -12.7938 0.16076E-12 -12.7938 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22215E-14 -14.6534 0.19438E-14 -14.7114 0.87500E+00 -0.0580 60 MgCl+ 0.26079E-14 -14.5837 0.22819E-14 -14.6417 0.87500E+00 -0.0580 61 MgOH+ 0.43853E-10 -10.3580 0.38371E-10 -10.4160 0.87500E+00 -0.0580 63 MnO,aq 0.61550E-09 -9.2108 0.61550E-09 -9.2108 0.10000E+01 0.0000 64 MnOH+ 0.27327E-09 -9.5634 0.23911E-09 -9.6214 0.87500E+00 -0.0580 65 MnO2-2 0.19385E-11 -11.7125 0.12005E-11 -11.9206 0.61928E+00 -0.2081 66 HMnO2- 0.39623E-10 -10.4021 0.34635E-10 -10.4605 0.87410E+00 -0.0584 69 MnCl+ 0.86240E-14 -14.0643 0.75459E-14 -14.1223 0.87500E+00 -0.0580 70 MnSO4,aq 0.46401E-13 -13.3335 0.46401E-13 -13.3335 0.10000E+01 0.0000 71 NaCl,aq 0.31756E-06 -6.4982 0.31756E-06 -6.4982 0.10000E+01 0.0000 72 NaOH,aq 0.26610E-04 -4.5749 0.26610E-04 -4.5749 0.10000E+01 0.0000 74 OH- 0.51585E-02 -2.2875 0.45047E-02 -2.3463 0.87326E+00 -0.0589 79 HPO3-2 0.29728E-17 -17.5268 0.18410E-17 -17.7350 0.61928E+00 -0.2081 82 H3PO4,aq 0.36742E-16 -16.4348 0.36742E-16 -16.4348 0.10000E+01 0.0000 83 H2PO4- 0.85922E-09 -9.0659 0.75142E-09 -9.1241 0.87454E+00 -0.0582 84 PO4-3 0.59380E-08 -8.2264 0.21110E-08 -8.6755 0.35551E+00 -0.4492 87 H2P2O7-2 0.71359E-19 -19.1465 0.44191E-19 -19.3547 0.61928E+00 -0.2081 88 HP2O7-3 0.19641E-15 -15.7068 0.68051E-16 -16.1672 0.34648E+00 -0.4603 89 P2O7-4 0.80698E-15 -15.0931 0.12608E-15 -15.8994 0.15623E+00 -0.8062 90 H2S,aq 0.45179E-15 -15.3451 0.45107E-15 -15.3458 0.99840E+00 -0.0007 97 SO3-2 0.62660E-14 -14.2030 0.39103E-14 -14.4078 0.62405E+00 -0.2048 98 HSO3- 0.34860E-16 -16.4577 0.30471E-16 -16.5161 0.87410E+00 -0.0584 99 HSO4- 0.22351E-11 -11.6507 0.19567E-11 -11.7085 0.87544E+00 -0.0578 Charge balance for all species = 0.8520E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1518473E-09 -.9673632E-02 -.9743617E+01 0.0000 2 H2O 0.1000000E+01 0.5550918E+02 0.9993148E+06 0.0000 3 Cl- 0.1379719E-03 0.1382896E-03 0.4899349E+01 5.9570 4 SO4-- 0.2554490E-04 0.2556409E-04 0.2454008E+01 14.9509 5 HCO3- 0.6611880E-05 0.1309988E-04 0.7987583E+00 4.6379 6 HS- 0.1289719E-11 -.1316740E-08 -.4351675E-04 -2.0723 7 Al+++ 0.5278822E-27 0.3841446E-04 0.1035755E+01 1.8889 8 H4SiO4 0.4643433E-03 0.4792441E-02 0.4603050E+03 -3.3332 9 Ca++ 0.4040525E-07 0.5904096E-07 0.2364588E-02 12.1484 10 Mg++ 0.2123032E-10 0.6666701E-10 0.1619674E-05 8.8679 11 Fe++ 0.1255031E-12 0.3031087E-07 0.1691586E-02 6.6398 12 K+ 0.7263744E-04 0.7286337E-04 0.2847110E+01 5.6788 13 Na+ 0.9226230E-02 0.9688912E-02 0.2225903E+03 7.7822 14 Mn++ 0.1676355E-10 0.9471419E-09 0.5199767E-04 8.7657 15 HPO4-- 0.5191285E-06 0.5259257E-06 0.5044249E-01 13.2590 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2649066E+00 -.9651570E-02 -.2552551E+00 0.0000000E+00 2 H2O 0.5530770E+02 0.5538259E+02 -.7489424E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4688913E-03 0.2550578E-04 0.4433855E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4433868E-03 -.1313737E-08 -.4433855E-03 0.0000000E+00 7 Al+++ 0.5216861E-01 0.3832686E-04 0.5213028E-01 0.0000000E+00 8 H4SiO4 0.1665941E+00 0.4781511E-02 0.1618126E+00 0.0000000E+00 9 Ca++ 0.1841560E-01 0.5890631E-07 0.1841554E-01 0.0000000E+00 10 Mg++ 0.1269762E-01 0.6651497E-10 0.1269762E-01 0.0000000E+00 11 Fe++ 0.1140742E-01 0.3024174E-07 0.1140739E-01 0.0000000E+00 12 K+ 0.3396815E-02 0.7269720E-04 0.3324118E-02 0.0000000E+00 13 Na+ 0.2024271E-01 0.9666816E-02 0.1057590E-01 0.0000000E+00 14 Mn++ 0.2774002E-03 0.9449818E-09 0.2773993E-03 0.0000000E+00 15 HPO4-- 0.9467531E-04 0.5247262E-06 0.9415058E-04 0.0000000E+00 Chg. balance for solid moles: 0.8674E-17 Mass of aqueous solution: 0.998418E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 15.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1058E-01 -1.976 2.773 0.443 15.88 1.065 andradite 0.1066E-02 -2.972 0.5418 -0.266 3.103 0.1408 grossular 0.5594E-04 -4.252 0.2520E-01 -1.599 0.1443 0.7012E-02 apatite-OH 0.3138E-04 -4.503 0.1576E-01 -1.802 0.9028E-01 0.5009E-02 clinochlore 0.2540E-02 -2.595 1.412 0.150 8.084 0.5369 daphnite 0.1572E-02 -2.804 1.122 0.050 6.424 0.3399 chlorite-Mn 0.5548E-04 -4.256 0.3933E-01 -1.405 0.2253 0.1253E-01 hematite 0.7073E-03 -3.150 0.1130 -0.947 0.6469 0.2141E-01 microcline 0.3324E-02 -2.478 0.9252 -0.034 5.299 0.3614 stilbite 0.1489E-01 -1.827 10.49 1.021 60.10 4.895 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9501E+00 0.9501E+00 1.0000 -0.022 grossular 0.4985E-01 0.4985E-01 1.0000 -1.302 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 17.461539 g Volume = 7.384499 cm3 Porosity: 0.2041% V(tot) - V(min): 0.15101E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 15.9990000 g log = 1.2041 Original solution: 1000.0103000 g Original solution / Rock added: 62.50 (Water/Rock Ratio), log = 1.7959 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1677E-06 1.0073 0.1777E-06 0.1765E-06 CH4,gas 0.5996E-15 1.0129 0.6389E-15 0.6308E-15 H2,gas 0.2360E-05 1.0006 0.2484E-05 0.2482E-05 H2S,gas 0.1256E-13 0.9959 0.1316E-13 0.1321E-13 S2,gas 0.9990E-36 1.0000 0.1051E-35 0.1051E-35 CO,gas 0.1087E-15 1.0000 0.1144E-15 0.1144E-15 SO3,gas 0.9980E-40 1.0000 0.1050E-39 0.1050E-39 SO2,gas 0.9377E-23 1.0000 0.9864E-23 0.9864E-23 HCl,gas 0.5070E-17 1.0000 0.5334E-17 0.5334E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.917 0.14941E+05 -6.750 3 CH4,gas 4.81 -12.39 -17.19 -4.299 0.29359E+05 -15.195 4 H2,gas 8.29 0.68 -7.60 -4.346 0.12985E+05 -5.605 5 H2S,gas -5.94 -21.82 -15.88 -7.940 0.27116E+05 -13.881 6 S2,gas -7.03 -45.01 -37.98 -5.843 0.64847E+05 -35.978 7 CO,gas 3.51 -14.43 -17.94 -5.521 0.30635E+05 -15.942 8 SO3,gas 17.43 -24.55 -41.98 -10.495 0.71678E+05 -39.979 9 SO2,gas 1.14 -23.87 -25.01 -6.668 0.42697E+05 -23.006 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32908E+05 -17.273 11 acmite 7.74 7.41 -0.32 -0.034 0.55104E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.08 -4.47 -0.224 0.76399E+04 20 analcite 3.37 3.00 -0.37 -0.041 0.62466E+03 21 andalusite 5.06 0.44 -4.62 -0.462 0.78845E+04 26 annite 20.21 17.49 -2.72 -0.151 0.46472E+04 27 phlogopite 27.15 24.17 -2.97 -0.165 0.50794E+04 29 anorthite 12.80 9.26 -3.54 -0.272 0.60406E+04 35 aragonite 0.99 -2.97 -3.95 -1.317 0.67466E+04 36 brucite 12.58 8.87 -3.71 -0.742 0.63326E+04 37 calcite 0.83 -2.97 -3.80 -1.266 0.64853E+04 38 carnegieite-low 9.06 6.34 -2.73 -0.390 0.46556E+04 39 carnegieite-high 10.13 6.34 -3.80 -0.542 0.64824E+04 40 carpholite-Mg 8.65 5.98 -2.67 -0.178 0.45606E+04 41 carpholite-Fe 6.78 3.75 -3.03 -0.202 0.51763E+04 42 celadonite 5.40 3.10 -2.30 -0.135 0.39231E+04 43 celadonite-Fe 3.94 0.87 -3.06 -0.180 0.52284E+04 44 chrysotile 23.94 19.94 -4.00 -0.333 0.68300E+04 50 chloritoid-Mg 13.26 9.31 -3.95 -0.263 0.67422E+04 51 chloritoid-Fe 9.24 7.08 -2.15 -0.144 0.36782E+04 52 chloritoid-Mn 11.46 9.21 -2.25 -0.150 0.38466E+04 54 coesite -2.37 -3.33 -0.96 -0.321 0.16457E+04 59 corundum 8.43 3.78 -4.66 -0.423 0.79492E+04 61 cristobalite -2.55 -3.33 -0.78 -0.261 0.13386E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.89 -1.01 -0.168 0.17197E+04 67 diopside 16.22 14.35 -1.87 -0.187 0.31854E+04 68 hedenbergite 14.24 12.12 -2.12 -0.212 0.36242E+04 75 epidote 24.78 24.37 -0.40 -0.019 0.68506E+03 76 clinozoisite 22.92 19.96 -2.96 -0.134 0.50490E+04 77 epidote-Fe 29.94 28.78 -1.15 -0.060 0.19686E+04 78 fayalite 14.08 9.95 -4.13 -0.590 0.70561E+04 79 ferrosilite 11.19 6.61 -4.57 -0.457 0.78107E+04 83 gibbsite 4.10 1.89 -2.21 -0.315 0.37709E+04 84 glaucophane 23.11 19.28 -3.83 -0.104 0.65396E+04 85 glaucophane-Fe 17.42 12.60 -4.82 -0.130 0.82314E+04 87 greenalite 16.19 13.25 -2.94 -0.245 0.50219E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.00 -1.25 -0.125 0.21277E+04 96 julgoldite 70.57 67.07 -3.50 -0.091 0.59819E+04 97 kalsilite 7.62 4.23 -3.39 -0.484 0.57810E+04 98 kaolinite -1.27 -2.89 -1.62 -0.147 0.27581E+04 99 kyanite 4.93 0.44 -4.49 -0.449 0.76613E+04 101 laumontite 2.97 2.59 -0.38 -0.025 0.65041E+03 102 lawsonite 9.68 9.26 -0.42 -0.028 0.71445E+03 103 leucite 4.17 0.90 -3.27 -0.327 0.55771E+04 105 lizardite 23.29 19.94 -3.35 -0.279 0.57203E+04 107 magnetite 20.13 19.24 -0.90 -0.073 0.15288E+04 108 minnesotaite 10.46 6.59 -3.87 -0.228 0.66147E+04 110 magnesioferrite 26.26 21.47 -4.79 -0.391 0.81819E+04 113 margarite 17.45 13.04 -4.41 -0.177 0.75367E+04 120 muscovite 2.68 1.35 -1.33 -0.078 0.22763E+04 121 paragonite 4.34 3.45 -0.89 -0.052 0.15147E+04 122 nepheline 8.38 6.34 -2.04 -0.291 0.34835E+04 128 periclase-Fe 11.64 6.64 -5.00 -1.250 0.85362E+04 134 phlogopite-Na 29.73 26.28 -3.46 -0.192 0.59013E+04 136 prehnite 19.47 18.08 -1.39 -0.082 0.23753E+04 137 prehnite-Fe 22.59 22.49 -0.10 -0.006 0.17367E+03 138 pumpellyite-Fe 46.47 44.68 -1.79 -0.040 0.30588E+04 139 pumpellyite-Mg 49.19 46.91 -2.29 -0.051 0.39048E+04 145 pyroxmangite 7.42 5.43 -1.98 -0.397 0.33867E+04 146 pyrophyllite -6.10 -9.55 -3.46 -0.216 0.59023E+04 147 quartz -2.98 -3.33 -0.35 -0.117 0.59960E+03 152 rhodonite 7.46 5.43 -2.03 -0.406 0.34660E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.44 -4.88 -0.488 0.83267E+04 164 stilpnomelane-Fe 13.18 13.15 -0.03 -0.001 0.48404E+02 165 stilpnomelane-Mg 27.60 24.29 -3.31 -0.099 0.56432E+04 171 talc 16.55 13.27 -3.28 -0.193 0.56047E+04 174 tephroite 18.11 14.20 -3.91 -0.559 0.66841E+04 177 topaz-H 4.67 0.44 -4.22 -0.384 0.72104E+04 178 tridymite -2.61 -3.33 -0.72 -0.240 0.12269E+04 187 wairakite 4.06 2.59 -1.46 -0.086 0.25012E+04 188 walstromite 11.53 8.82 -2.71 -0.543 0.46318E+04 189 wollastonite 10.48 8.82 -1.67 -0.333 0.28456E+04 190 pseudo-wollastonite 11.02 8.82 -2.20 -0.441 0.37643E+04 191 zoisite 22.96 19.96 -3.00 -0.136 0.51216E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.83 -4.27 -0.264 0.72863E+04 195 beidellite-K -1.44 -5.96 -4.52 -0.277 0.77220E+04 196 beidellite-Mg -1.71 -6.37 -4.66 -0.288 0.79592E+04 197 beidellite-Na -1.26 -5.26 -4.01 -0.245 0.68407E+04 199 chalcedony -2.79 -3.33 -0.54 -0.180 0.91992E+03 201 montmorillonite-Ca -2.21 -5.25 -3.03 -0.188 0.51791E+04 202 montmorillonite-K -2.16 -5.38 -3.22 -0.197 0.54925E+04 203 montmorillonite-Mg -2.40 -5.79 -3.39 -0.210 0.57830E+04 204 montmorillonite-Na -1.96 -4.68 -2.72 -0.167 0.46494E+04 205 nontronite-Ca 3.28 2.99 -0.29 -0.019 0.48988E+03 206 nontronite-H 2.60 0.99 -1.61 -0.108 0.27447E+04 207 nontronite-K 3.40 2.86 -0.54 -0.035 0.92470E+03 208 nontronite-Mg 3.14 2.45 -0.69 -0.045 0.11744E+04 209 nontronite-Na 3.58 3.56 -0.03 -0.002 0.45127E+02 224 tobermorite 9.84 6.79 -3.05 -0.833 0.52121E+04 233 boehmite 4.43 1.89 -2.54 -0.423 0.43381E+04 235 ferrous-oxide 9.82 6.64 -3.18 -0.796 0.54373E+04 240 silica-amorphous -2.08 -3.33 -1.25 -0.418 0.21401E+04 242 an20ab80 2.08 1.59 -0.49 -0.038 0.83650E+03 243 an25ab75 2.71 2.07 -0.64 -0.049 0.10935E+04 244 an30ab70 3.34 2.55 -0.80 -0.061 0.13589E+04 245 tr.625ac.25prg.125 45.31 40.59 -4.72 -0.127 0.80532E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 15.9990000 g New total amount of reactant added: 16.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8622E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 16.3990000 Water: Moles liquid = 0.5538E+02 kg liquid = 0.9977E+00 Moles total = 0.5530E+02 kg total = 0.9963E+00 Activity = 1.0000 Stoichiometric ionic strength = .5200651E-02 Osmotic coef. = 0.9618 True ionic strength = .9383186E-02 Chg. balance for total moles = 0.8622E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15252E-09 -9.8167 0.13371E-09 -9.8738 0.87668E+00 -0.0572 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13798E-03 -3.8602 0.12057E-03 -3.9188 0.87386E+00 -0.0586 4 SO4-- 0.25546E-04 -4.5927 0.15821E-04 -4.8008 0.61930E+00 -0.2081 5 HCO3- 0.66230E-05 -5.1789 0.57921E-05 -5.2372 0.87454E+00 -0.0582 6 HS- 0.14483E-11 -11.8391 0.12657E-11 -11.8977 0.87393E+00 -0.0585 7 Al+++ 0.49997E-27 -27.3011 0.17272E-27 -27.7627 0.34547E+00 -0.4616 8 H4SiO4 0.47501E-03 -3.3233 0.47501E-03 -3.3233 0.10000E+01 0.0000 9 Ca++ 0.39960E-07 -7.3984 0.24650E-07 -7.6082 0.61688E+00 -0.2098 10 Mg++ 0.21735E-10 -10.6628 0.13375E-10 -10.8737 0.61538E+00 -0.2109 11 Fe++ 0.12848E-12 -12.8911 0.79113E-13 -13.1018 0.61574E+00 -0.2106 12 K+ 0.73040E-04 -4.1364 0.63885E-04 -4.1946 0.87465E+00 -0.0582 13 Na+ 0.92774E-02 -2.0326 0.81065E-02 -2.0912 0.87378E+00 -0.0586 14 Mn++ 0.17162E-10 -10.7654 0.10572E-10 -10.9759 0.61601E+00 -0.2104 15 HPO4-- 0.53332E-06 -6.2730 0.33031E-06 -6.4811 0.61934E+00 -0.2081 16 HSiO3- 0.39665E-02 -2.4016 0.34661E-02 -2.4602 0.87386E+00 -0.0586 17 Ca(HSiO3)+ 0.21884E-08 -8.6599 0.19143E-08 -8.7180 0.87475E+00 -0.0581 18 Mg(HSiO3)+ 0.14778E-11 -11.8304 0.12927E-11 -11.8885 0.87475E+00 -0.0581 19 NaHSiO3,aq 0.44626E-03 -3.3504 0.44626E-03 -3.3504 0.10000E+01 0.0000 20 AlO+ 0.14258E-14 -14.8460 0.12472E-14 -14.9041 0.87475E+00 -0.0581 22 HAlO2,aq 0.18665E-08 -8.7290 0.18665E-08 -8.7290 0.10000E+01 0.0000 23 AlO2- 0.35704E-04 -4.4473 0.31170E-04 -4.5063 0.87301E+00 -0.0590 24 CH4,aq 0.45543E-18 -18.3416 0.45470E-18 -18.3423 0.99840E+00 -0.0007 29 CO,aq 0.74903E-19 -19.1255 0.74903E-19 -19.1255 0.10000E+01 0.0000 30 CO2,aq 0.15640E-08 -8.8058 0.15615E-08 -8.8065 0.99840E+00 -0.0007 31 CO3-2 0.64747E-05 -5.1888 0.40052E-05 -5.3974 0.61859E+00 -0.2086 32 CaCO3,aq 0.12092E-08 -8.9175 0.12092E-08 -8.9175 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41127E-11 -11.3859 0.35976E-11 -11.4440 0.87475E+00 -0.0581 34 CaCl+ 0.54142E-11 -11.2665 0.47361E-11 -11.3246 0.87475E+00 -0.0581 35 CaCl2,aq 0.13296E-15 -15.8763 0.13296E-15 -15.8763 0.10000E+01 0.0000 36 CaOH+ 0.14861E-07 -7.8280 0.13000E-07 -7.8861 0.87475E+00 -0.0581 37 CaSO4,aq 0.12151E-09 -9.9154 0.12151E-09 -9.9154 0.10000E+01 0.0000 38 HCl,aq 0.30324E-14 -14.5182 0.30324E-14 -14.5182 0.10000E+01 0.0000 43 FeCl+ 0.16984E-16 -16.7700 0.14857E-16 -16.8281 0.87475E+00 -0.0581 46 FeO,aq 0.17499E-09 -9.7570 0.17499E-09 -9.7570 0.10000E+01 0.0000 47 FeOH+ 0.22424E-10 -10.6493 0.19615E-10 -10.7074 0.87475E+00 -0.0581 48 HFeO2- 0.16108E-07 -7.7930 0.14076E-07 -7.8515 0.87386E+00 -0.0586 49 FeO+ 0.12644E-14 -14.8981 0.11061E-14 -14.9562 0.87475E+00 -0.0581 51 FeO2- 0.13914E-07 -7.8565 0.12159E-07 -7.9151 0.87386E+00 -0.0586 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.18655E-08 -8.7292 0.18625E-08 -8.7299 0.99840E+00 -0.0007 54 KCl,aq 0.13639E-09 -9.8652 0.13639E-09 -9.8652 0.10000E+01 0.0000 55 KHSO4,aq 0.36163E-18 -18.4417 0.36163E-18 -18.4417 0.10000E+01 0.0000 56 KOH,aq 0.20829E-06 -6.6813 0.20829E-06 -6.6813 0.10000E+01 0.0000 57 KSO4- 0.17819E-07 -7.7491 0.15571E-07 -7.8077 0.87386E+00 -0.0586 58 MgCO3,aq 0.16395E-12 -12.7853 0.16395E-12 -12.7853 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22755E-14 -14.6429 0.19905E-14 -14.7010 0.87475E+00 -0.0581 60 MgCl+ 0.26669E-14 -14.5740 0.23329E-14 -14.6321 0.87475E+00 -0.0581 61 MgOH+ 0.44671E-10 -10.3500 0.39076E-10 -10.4081 0.87475E+00 -0.0581 63 MnO,aq 0.62422E-09 -9.2047 0.62422E-09 -9.2047 0.10000E+01 0.0000 64 MnOH+ 0.27837E-09 -9.5554 0.24350E-09 -9.6135 0.87475E+00 -0.0581 65 MnO2-2 0.19520E-11 -11.7095 0.12075E-11 -11.9181 0.61859E+00 -0.2086 66 HMnO2- 0.40030E-10 -10.3976 0.34980E-10 -10.4562 0.87386E+00 -0.0586 69 MnCl+ 0.88191E-14 -14.0546 0.77146E-14 -14.1127 0.87475E+00 -0.0581 70 MnSO4,aq 0.47399E-13 -13.3242 0.47399E-13 -13.3242 0.10000E+01 0.0000 71 NaCl,aq 0.31915E-06 -6.4960 0.31915E-06 -6.4960 0.10000E+01 0.0000 72 NaOH,aq 0.26640E-04 -4.5745 0.26640E-04 -4.5745 0.10000E+01 0.0000 74 OH- 0.51386E-02 -2.2892 0.44861E-02 -2.3481 0.87301E+00 -0.0590 79 HPO3-2 0.31413E-17 -17.5029 0.19432E-17 -17.7115 0.61859E+00 -0.2086 82 H3PO4,aq 0.38019E-16 -16.4200 0.38019E-16 -16.4200 0.10000E+01 0.0000 83 H2PO4- 0.88564E-09 -9.0527 0.77431E-09 -9.1111 0.87430E+00 -0.0583 84 PO4-3 0.60830E-08 -8.2159 0.21574E-08 -8.6661 0.35466E+00 -0.4502 87 H2P2O7-2 0.75857E-19 -19.1200 0.46925E-19 -19.3286 0.61859E+00 -0.2086 88 HP2O7-3 0.20822E-15 -15.6815 0.71962E-16 -16.1429 0.34561E+00 -0.4614 89 P2O7-4 0.85358E-15 -15.0688 0.13277E-15 -15.8769 0.15555E+00 -0.8081 90 H2S,aq 0.50929E-15 -15.2930 0.50848E-15 -15.2937 0.99840E+00 -0.0007 97 SO3-2 0.64450E-14 -14.1908 0.40177E-14 -14.3960 0.62338E+00 -0.2052 98 HSO3- 0.35976E-16 -16.4440 0.31438E-16 -16.5025 0.87386E+00 -0.0586 99 HSO4- 0.22426E-11 -11.6492 0.19628E-11 -11.7071 0.87520E+00 -0.0579 Charge balance for all species = 0.8554E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1525177E-09 -.9727617E-02 -.9797910E+01 0.0000 2 H2O 0.1000000E+01 0.5550907E+02 0.9993043E+06 0.0000 3 Cl- 0.1379765E-03 0.1382958E-03 0.4899527E+01 5.9551 4 SO4-- 0.2554597E-04 0.2556521E-04 0.2454096E+01 14.9469 5 HCO3- 0.6623011E-05 0.1310046E-04 0.7987874E+00 4.6367 6 HS- 0.1448284E-11 -.1296917E-08 -.4286126E-04 -2.0238 7 Al+++ 0.4999668E-27 0.3570623E-04 0.9627254E+00 1.8589 8 H4SiO4 0.4750116E-03 0.4887728E-02 0.4694531E+03 -3.3233 9 Ca++ 0.3995960E-07 0.5834909E-07 0.2336858E-02 12.1395 10 Mg++ 0.2173477E-10 0.6805280E-10 0.1653328E-05 8.8740 11 Fe++ 0.1284848E-12 0.3042379E-07 0.1697874E-02 6.6459 12 K+ 0.7304024E-04 0.7326648E-04 0.2862837E+01 5.6792 13 Na+ 0.9277436E-02 0.9750658E-02 0.2240069E+03 7.7827 14 Mn++ 0.1716178E-10 0.9617857E-09 0.5280116E-04 8.7718 15 HPO4-- 0.5333224E-06 0.5402910E-06 0.5181986E-01 13.2666 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2715301E+00 -.9704997E-02 -.2618251E+00 0.0000000E+00 2 H2O 0.5530268E+02 0.5538000E+02 -.7731554E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4799767E-03 0.2550576E-04 0.4544709E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4544722E-03 -.1293901E-08 -.4544709E-03 0.0000000E+00 7 Al+++ 0.5347290E-01 0.3562321E-04 0.5343728E-01 0.0000000E+00 8 H4SiO4 0.1707592E+00 0.4876362E-02 0.1658829E+00 0.0000000E+00 9 Ca++ 0.1887566E-01 0.5821341E-07 0.1887560E-01 0.0000000E+00 10 Mg++ 0.1301508E-01 0.6789456E-10 0.1301508E-01 0.0000000E+00 11 Fe++ 0.1169263E-01 0.3035305E-07 0.1169260E-01 0.0000000E+00 12 K+ 0.3481741E-02 0.7309611E-04 0.3408645E-02 0.0000000E+00 13 Na+ 0.2074481E-01 0.9727985E-02 0.1101683E-01 0.0000000E+00 14 Mn++ 0.2843356E-03 0.9595492E-09 0.2843347E-03 0.0000000E+00 15 HPO4-- 0.9704234E-04 0.5390346E-06 0.9650330E-04 0.0000000E+00 Chg. balance for solid moles: -.4364E-17 Mass of aqueous solution: 0.998382E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 16.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1102E-01 -1.958 2.889 0.461 16.14 1.109 andradite 0.1123E-02 -2.949 0.5709 -0.243 3.190 0.1483 grossular 0.5500E-04 -4.260 0.2477E-01 -1.606 0.1384 0.6893E-02 apatite-OH 0.3217E-04 -4.493 0.1616E-01 -1.792 0.9030E-01 0.5135E-02 clinochlore 0.2603E-02 -2.585 1.447 0.160 8.085 0.5503 daphnite 0.1611E-02 -2.793 1.150 0.061 6.425 0.3484 chlorite-Mn 0.5687E-04 -4.245 0.4032E-01 -1.395 0.2253 0.1285E-01 hematite 0.6945E-03 -3.158 0.1109 -0.955 0.6198 0.2102E-01 microcline 0.3409E-02 -2.467 0.9488 -0.023 5.302 0.3706 stilbite 0.1518E-01 -1.819 10.70 1.029 59.78 4.989 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9533E+00 0.9533E+00 1.0000 -0.021 grossular 0.4667E-01 0.4667E-01 1.0000 -1.331 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6094E+00 0.6094E+00 1.0000 -0.215 daphnite 0.3773E+00 0.3773E+00 1.0000 -0.423 chlorite-Mn 0.1331E-01 0.1331E-01 1.0000 -1.876 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 17.894600 g Volume = 7.561983 cm3 Porosity: -0.0315% V(tot) - V(min): -.23833E-02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 16.3990000 g log = 1.2148 Original solution: 1000.0103000 g Original solution / Rock added: 60.98 (Water/Rock Ratio), log = 1.7852 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1687E-06 1.0073 0.1787E-06 0.1774E-06 CH4,gas 0.6748E-15 1.0129 0.7191E-15 0.7099E-15 H2,gas 0.2427E-05 1.0006 0.2555E-05 0.2553E-05 H2S,gas 0.1416E-13 0.9959 0.1483E-13 0.1489E-13 S2,gas 0.1200E-35 1.0000 0.1262E-35 0.1262E-35 CO,gas 0.1124E-15 1.0000 0.1183E-15 0.1183E-15 SO3,gas 0.1005E-39 1.0000 0.1057E-39 0.1057E-39 SO2,gas 0.9714E-23 1.0000 0.1022E-22 0.1022E-22 HCl,gas 0.5090E-17 1.0000 0.5354E-17 0.5354E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.20 0.02 0.001 -0.36230E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.916 0.14937E+05 -6.748 3 CH4,gas 4.81 -12.33 -17.14 -4.286 0.29272E+05 -15.143 4 H2,gas 8.29 0.69 -7.59 -4.339 0.12964E+05 -5.593 5 H2S,gas -5.94 -21.77 -15.83 -7.914 0.27027E+05 -13.829 6 S2,gas -7.03 -44.93 -37.90 -5.831 0.64711E+05 -35.899 7 CO,gas 3.51 -14.42 -17.93 -5.516 0.30610E+05 -15.927 8 SO3,gas 17.43 -24.55 -41.98 -10.494 0.71672E+05 -39.976 9 SO2,gas 1.14 -23.85 -24.99 -6.664 0.42671E+05 -22.991 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32905E+05 -17.271 11 acmite 7.74 7.43 -0.30 -0.031 0.51652E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.06 -4.49 -0.224 0.76607E+04 20 analcite 3.37 2.99 -0.38 -0.042 0.64150E+03 21 andalusite 5.06 0.39 -4.67 -0.467 0.79704E+04 26 annite 20.21 17.51 -2.70 -0.150 0.46159E+04 27 phlogopite 27.15 24.19 -2.96 -0.164 0.50481E+04 29 anorthite 12.80 9.21 -3.59 -0.276 0.61248E+04 35 aragonite 0.99 -2.97 -3.96 -1.319 0.67577E+04 36 brucite 12.58 8.87 -3.70 -0.741 0.63221E+04 37 calcite 0.83 -2.97 -3.80 -1.268 0.64964E+04 38 carnegieite-low 9.06 6.32 -2.75 -0.392 0.46893E+04 39 carnegieite-high 10.13 6.32 -3.82 -0.545 0.65161E+04 40 carpholite-Mg 8.65 5.95 -2.71 -0.180 0.46192E+04 41 carpholite-Fe 6.78 3.72 -3.07 -0.204 0.52348E+04 42 celadonite 5.40 3.12 -2.28 -0.134 0.38958E+04 43 celadonite-Fe 3.94 0.89 -3.05 -0.179 0.52011E+04 44 chrysotile 23.94 19.98 -3.96 -0.330 0.67650E+04 50 chloritoid-Mg 13.26 9.27 -3.99 -0.266 0.68177E+04 51 chloritoid-Fe 9.24 7.04 -2.20 -0.147 0.37536E+04 52 chloritoid-Mn 11.46 9.17 -2.30 -0.153 0.39220E+04 54 coesite -2.37 -3.32 -0.95 -0.318 0.16288E+04 59 corundum 8.43 3.72 -4.72 -0.429 0.80519E+04 61 cristobalite -2.55 -3.32 -0.77 -0.258 0.13217E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.86 -1.04 -0.173 0.17710E+04 67 diopside 16.22 14.37 -1.85 -0.185 0.31564E+04 68 hedenbergite 14.24 12.14 -2.11 -0.211 0.35952E+04 75 epidote 24.78 24.33 -0.45 -0.022 0.76763E+03 76 clinozoisite 22.92 19.89 -3.04 -0.138 0.51830E+04 77 epidote-Fe 29.94 28.77 -1.17 -0.061 0.19998E+04 78 fayalite 14.08 9.97 -4.11 -0.587 0.70184E+04 79 ferrosilite 11.19 6.65 -4.54 -0.454 0.77561E+04 83 gibbsite 4.10 1.86 -2.24 -0.320 0.38222E+04 84 glaucophane 23.11 19.32 -3.79 -0.102 0.64746E+04 85 glaucophane-Fe 17.42 12.63 -4.78 -0.129 0.81664E+04 87 greenalite 16.19 13.29 -2.90 -0.242 0.49569E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.99 -1.26 -0.126 0.21445E+04 96 julgoldite 70.57 67.11 -3.47 -0.090 0.59208E+04 97 kalsilite 7.62 4.21 -3.41 -0.486 0.58147E+04 98 kaolinite -1.27 -2.93 -1.66 -0.151 0.28271E+04 99 kyanite 4.93 0.39 -4.54 -0.454 0.77472E+04 101 laumontite 2.97 2.56 -0.41 -0.027 0.70094E+03 102 lawsonite 9.68 9.21 -0.47 -0.031 0.79867E+03 103 leucite 4.17 0.89 -3.28 -0.328 0.55939E+04 105 lizardite 23.29 19.98 -3.31 -0.276 0.56553E+04 107 magnetite 20.13 19.24 -0.89 -0.073 0.15184E+04 108 minnesotaite 10.46 6.64 -3.82 -0.224 0.65160E+04 110 magnesioferrite 26.26 21.47 -4.79 -0.391 0.81714E+04 113 margarite 17.45 12.93 -4.52 -0.181 0.77237E+04 120 muscovite 2.68 1.29 -1.39 -0.082 0.23790E+04 121 paragonite 4.34 3.39 -0.95 -0.056 0.16174E+04 122 nepheline 8.38 6.32 -2.06 -0.294 0.35172E+04 128 periclase-Fe 11.64 6.65 -4.99 -1.248 0.85258E+04 134 phlogopite-Na 29.73 26.29 -3.44 -0.191 0.58700E+04 136 prehnite 19.47 18.03 -1.44 -0.085 0.24579E+04 137 prehnite-Fe 22.59 22.47 -0.12 -0.007 0.20488E+03 138 pumpellyite-Fe 46.47 44.56 -1.91 -0.042 0.32649E+04 139 pumpellyite-Mg 49.19 46.79 -2.41 -0.054 0.41109E+04 145 pyroxmangite 7.42 5.45 -1.97 -0.394 0.33595E+04 146 pyrophyllite -6.10 -9.58 -3.48 -0.217 0.59376E+04 147 quartz -2.98 -3.32 -0.34 -0.114 0.58276E+03 152 rhodonite 7.46 5.45 -2.01 -0.403 0.34387E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.39 -4.93 -0.493 0.84126E+04 165 stilpnomelane-Mg 27.60 24.34 -3.26 -0.097 0.55586E+04 171 talc 16.55 13.33 -3.22 -0.190 0.55060E+04 174 tephroite 18.11 14.22 -3.89 -0.556 0.66464E+04 177 topaz-H 4.67 0.39 -4.27 -0.388 0.72963E+04 178 tridymite -2.61 -3.32 -0.71 -0.236 0.12100E+04 187 wairakite 4.06 2.56 -1.49 -0.088 0.25518E+04 188 walstromite 11.53 8.82 -2.71 -0.542 0.46301E+04 189 wollastonite 10.48 8.82 -1.67 -0.333 0.28440E+04 190 pseudo-wollastonite 11.02 8.82 -2.20 -0.441 0.37626E+04 191 zoisite 22.96 19.89 -3.08 -0.140 0.52555E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.86 -4.30 -0.266 0.73467E+04 195 beidellite-K -1.44 -5.99 -4.56 -0.279 0.77796E+04 196 beidellite-Mg -1.71 -6.40 -4.69 -0.290 0.80153E+04 197 beidellite-Na -1.26 -5.30 -4.04 -0.247 0.68983E+04 199 chalcedony -2.79 -3.32 -0.53 -0.176 0.90307E+03 201 montmorillonite-Ca -2.21 -5.26 -3.04 -0.188 0.51966E+04 202 montmorillonite-K -2.16 -5.39 -3.23 -0.198 0.55072E+04 203 montmorillonite-Mg -2.40 -5.80 -3.39 -0.210 0.57963E+04 204 montmorillonite-Na -1.96 -4.69 -2.73 -0.167 0.46641E+04 205 nontronite-Ca 3.28 3.02 -0.26 -0.017 0.44751E+03 206 nontronite-H 2.60 1.01 -1.58 -0.106 0.26998E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87956E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11278E+04 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.15339E-01 224 tobermorite 9.84 6.79 -3.05 -0.832 0.52080E+04 233 boehmite 4.43 1.86 -2.57 -0.428 0.43895E+04 235 ferrous-oxide 9.82 6.65 -3.18 -0.795 0.54269E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.415 0.21233E+04 242 an20ab80 2.08 1.58 -0.50 -0.038 0.85335E+03 243 an25ab75 2.71 2.06 -0.65 -0.050 0.11146E+04 244 an30ab70 3.34 2.53 -0.81 -0.062 0.13842E+04 245 tr.625ac.25prg.125 45.31 40.67 -4.64 -0.125 0.79214E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 16.3990000 Water: Moles liquid = 0.5538E+02 kg liquid = 0.9977E+00 Moles total = 0.5530E+02 kg total = 0.9963E+00 Activity = 1.0000 Stoichiometric ionic strength = .5194871E-02 Osmotic coef. = 0.9618 True ionic strength = .9367730E-02 Chg. balance for total moles = 0.8622E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15232E-09 -9.8173 0.13354E-09 -9.8744 0.87675E+00 -0.0571 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13798E-03 -3.8602 0.12058E-03 -3.9187 0.87393E+00 -0.0585 4 SO4-- 0.25546E-04 -4.5927 0.15826E-04 -4.8006 0.61950E+00 -0.2080 5 HCO3- 0.66197E-05 -5.1792 0.57897E-05 -5.2373 0.87461E+00 -0.0582 6 HS- 0.13663E-11 -11.8645 0.11941E-11 -11.9229 0.87400E+00 -0.0585 7 Al+++ 0.50811E-27 -27.2940 0.17567E-27 -27.7553 0.34573E+00 -0.4613 8 H4SiO4 0.47181E-03 -3.3262 0.47181E-03 -3.3262 0.10000E+01 0.0000 9 Ca++ 0.40092E-07 -7.3969 0.24740E-07 -7.6066 0.61709E+00 -0.2097 10 Mg++ 0.21621E-10 -10.6651 0.13310E-10 -10.8758 0.61559E+00 -0.2107 11 Fe++ 0.12721E-12 -12.8955 0.78353E-13 -13.1059 0.61594E+00 -0.2105 12 K+ 0.72920E-04 -4.1372 0.63785E-04 -4.1953 0.87473E+00 -0.0581 13 Na+ 0.92621E-02 -2.0333 0.80937E-02 -2.0919 0.87386E+00 -0.0586 14 Mn++ 0.17072E-10 -10.7677 0.10520E-10 -10.9780 0.61622E+00 -0.2103 15 HPO4-- 0.52905E-06 -6.2765 0.32777E-06 -6.4844 0.61955E+00 -0.2079 16 HSiO3- 0.39443E-02 -2.4040 0.34470E-02 -2.4626 0.87393E+00 -0.0585 17 Ca(HSiO3)+ 0.21841E-08 -8.6607 0.19107E-08 -8.7188 0.87483E+00 -0.0581 18 Mg(HSiO3)+ 0.14623E-11 -11.8350 0.12793E-11 -11.8930 0.87483E+00 -0.0581 19 NaHSiO3,aq 0.44311E-03 -3.3535 0.44311E-03 -3.3535 0.10000E+01 0.0000 20 AlO+ 0.14536E-14 -14.8376 0.12716E-14 -14.8956 0.87483E+00 -0.0581 22 HAlO2,aq 0.19055E-08 -8.7200 0.19055E-08 -8.7200 0.10000E+01 0.0000 23 AlO2- 0.36491E-04 -4.4378 0.31860E-04 -4.4968 0.87309E+00 -0.0589 24 CH4,aq 0.42936E-18 -18.3672 0.42868E-18 -18.3679 0.99840E+00 -0.0007 29 CO,aq 0.73716E-19 -19.1324 0.73716E-19 -19.1324 0.10000E+01 0.0000 30 CO2,aq 0.15614E-08 -8.8065 0.15589E-08 -8.8072 0.99840E+00 -0.0007 31 CO3-2 0.64779E-05 -5.1886 0.40085E-05 -5.3970 0.61880E+00 -0.2085 32 CaCO3,aq 0.12146E-08 -8.9156 0.12146E-08 -8.9156 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41256E-11 -11.3845 0.36092E-11 -11.4426 0.87483E+00 -0.0581 34 CaCl+ 0.54339E-11 -11.2649 0.47537E-11 -11.3230 0.87483E+00 -0.0581 35 CaCl2,aq 0.13347E-15 -15.8746 0.13347E-15 -15.8746 0.10000E+01 0.0000 36 CaOH+ 0.14932E-07 -7.8259 0.13063E-07 -7.8840 0.87483E+00 -0.0581 37 CaSO4,aq 0.12199E-09 -9.9137 0.12199E-09 -9.9137 0.10000E+01 0.0000 38 HCl,aq 0.30289E-14 -14.5187 0.30289E-14 -14.5187 0.10000E+01 0.0000 43 FeCl+ 0.16821E-16 -16.7742 0.14715E-16 -16.8322 0.87483E+00 -0.0581 46 FeO,aq 0.17374E-09 -9.7601 0.17374E-09 -9.7601 0.10000E+01 0.0000 47 FeOH+ 0.22234E-10 -10.6530 0.19451E-10 -10.7111 0.87483E+00 -0.0581 48 HFeO2- 0.16012E-07 -7.7956 0.13993E-07 -7.8541 0.87393E+00 -0.0585 49 FeO+ 0.12628E-14 -14.8987 0.11047E-14 -14.9568 0.87483E+00 -0.0581 51 FeO2- 0.13931E-07 -7.8560 0.12174E-07 -7.9146 0.87393E+00 -0.0585 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.18390E-08 -8.7354 0.18360E-08 -8.7361 0.99840E+00 -0.0007 54 KCl,aq 0.13619E-09 -9.8659 0.13619E-09 -9.8659 0.10000E+01 0.0000 55 KHSO4,aq 0.36073E-18 -18.4428 0.36073E-18 -18.4428 0.10000E+01 0.0000 56 KOH,aq 0.20822E-06 -6.6815 0.20822E-06 -6.6815 0.10000E+01 0.0000 57 KSO4- 0.17795E-07 -7.7497 0.15552E-07 -7.8082 0.87393E+00 -0.0585 58 MgCO3,aq 0.16328E-12 -12.7871 0.16328E-12 -12.7871 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22633E-14 -14.6453 0.19800E-14 -14.7033 0.87483E+00 -0.0581 60 MgCl+ 0.26539E-14 -14.5761 0.23217E-14 -14.6342 0.87483E+00 -0.0581 61 MgOH+ 0.44505E-10 -10.3516 0.38934E-10 -10.4097 0.87483E+00 -0.0581 63 MnO,aq 0.62272E-09 -9.2057 0.62272E-09 -9.2057 0.10000E+01 0.0000 64 MnOH+ 0.27733E-09 -9.5570 0.24262E-09 -9.6151 0.87483E+00 -0.0581 65 MnO2-2 0.19515E-11 -11.7096 0.12076E-11 -11.9181 0.61880E+00 -0.2085 66 HMnO2- 0.39980E-10 -10.3982 0.34940E-10 -10.4567 0.87393E+00 -0.0585 69 MnCl+ 0.87761E-14 -14.0567 0.76776E-14 -14.1148 0.87483E+00 -0.0581 70 MnSO4,aq 0.47184E-13 -13.3262 0.47184E-13 -13.3262 0.10000E+01 0.0000 71 NaCl,aq 0.31868E-06 -6.4967 0.31868E-06 -6.4967 0.10000E+01 0.0000 72 NaOH,aq 0.26631E-04 -4.5746 0.26631E-04 -4.5746 0.10000E+01 0.0000 74 OH- 0.51446E-02 -2.2886 0.44917E-02 -2.3476 0.87309E+00 -0.0589 79 HPO3-2 0.30718E-17 -17.5126 0.19008E-17 -17.7211 0.61880E+00 -0.2085 82 H3PO4,aq 0.37633E-16 -16.4244 0.37633E-16 -16.4244 0.10000E+01 0.0000 83 H2PO4- 0.87767E-09 -9.0567 0.76741E-09 -9.1150 0.87437E+00 -0.0583 84 PO4-3 0.60394E-08 -8.2190 0.21435E-08 -8.6689 0.35491E+00 -0.4499 87 H2P2O7-2 0.74485E-19 -19.1279 0.46091E-19 -19.3364 0.61880E+00 -0.2085 88 HP2O7-3 0.20462E-15 -15.6891 0.70772E-16 -16.1501 0.34587E+00 -0.4611 89 P2O7-4 0.83940E-15 -15.0760 0.13074E-15 -15.8836 0.15575E+00 -0.8076 90 H2S,aq 0.47990E-15 -15.3188 0.47914E-15 -15.3195 0.99840E+00 -0.0007 97 SO3-2 0.63534E-14 -14.1970 0.39619E-14 -14.4021 0.62358E+00 -0.2051 98 HSO3- 0.35429E-16 -16.4506 0.30963E-16 -16.5092 0.87393E+00 -0.0585 99 HSO4- 0.22404E-11 -11.6497 0.19610E-11 -11.7075 0.87527E+00 -0.0579 Charge balance for all species = 0.8710E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1523157E-09 -.9711367E-02 -.9781567E+01 0.0000 2 H2O 0.1000000E+01 0.5550911E+02 0.9993074E+06 0.0000 3 Cl- 0.1379768E-03 0.1382956E-03 0.4899534E+01 5.9557 4 SO4-- 0.2554597E-04 0.2556519E-04 0.2454100E+01 14.9481 5 HCO3- 0.6619738E-05 0.1310045E-04 0.7987885E+00 4.6370 6 HS- 0.1366291E-11 -.1305650E-08 -.4314999E-04 -2.0486 7 Al+++ 0.5081083E-27 0.3649318E-04 0.9839457E+00 1.8678 8 H4SiO4 0.4718056E-03 0.4859169E-02 0.4667114E+03 -3.3262 9 Ca++ 0.4009159E-07 0.5855412E-07 0.2345076E-02 12.1422 10 Mg++ 0.2162141E-10 0.6775707E-10 0.1646147E-05 8.8729 11 Fe++ 0.1272078E-12 0.3034216E-07 0.1693322E-02 6.6428 12 K+ 0.7291961E-04 0.7314576E-04 0.2858127E+01 5.6791 13 Na+ 0.9262102E-02 0.9732159E-02 0.2235825E+03 7.7825 14 Mn++ 0.1707230E-10 0.9591137E-09 0.5265460E-04 8.7708 15 HPO4-- 0.5290486E-06 0.5359657E-06 0.5140514E-01 13.2643 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2715301E+00 -.9688796E-02 -.2618413E+00 0.0000000E+00 2 H2O 0.5530268E+02 0.5538009E+02 -.7741018E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4799767E-03 0.2550577E-04 0.4544709E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4544722E-03 -.1302616E-08 -.4544709E-03 0.0000000E+00 7 Al+++ 0.5347290E-01 0.3640836E-04 0.5343649E-01 0.0000000E+00 8 H4SiO4 0.1707592E+00 0.4847876E-02 0.1659114E+00 0.0000000E+00 9 Ca++ 0.1887566E-01 0.5841803E-07 0.1887560E-01 0.0000000E+00 10 Mg++ 0.1301508E-01 0.6759959E-10 0.1301508E-01 0.0000000E+00 11 Fe++ 0.1169263E-01 0.3027163E-07 0.1169260E-01 0.0000000E+00 12 K+ 0.3481741E-02 0.7297576E-04 0.3408765E-02 0.0000000E+00 13 Na+ 0.2074481E-01 0.9709539E-02 0.1103527E-01 0.0000000E+00 14 Mn++ 0.2843356E-03 0.9568845E-09 0.2843347E-03 0.0000000E+00 15 HPO4-- 0.9704234E-04 0.5347200E-06 0.9650762E-04 0.0000000E+00 Chg. balance for solid moles: -.1518E-17 Mass of aqueous solution: 0.998380E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 16.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1104E-01 -1.957 2.894 0.461 16.17 1.111 andradite 0.1125E-02 -2.949 0.5718 -0.243 3.195 0.1486 grossular 0.5623E-04 -4.250 0.2533E-01 -1.596 0.1415 0.7048E-02 apatite-OH 0.3217E-04 -4.493 0.1616E-01 -1.792 0.9030E-01 0.5135E-02 clinochlore 0.2603E-02 -2.585 1.447 0.160 8.085 0.5503 daphnite 0.1604E-02 -2.795 1.144 0.059 6.394 0.3467 chlorite-Mn 0.5687E-04 -4.245 0.4032E-01 -1.395 0.2253 0.1285E-01 hematite 0.6928E-03 -3.159 0.1106 -0.956 0.6182 0.2097E-01 microcline 0.3405E-02 -2.468 0.9477 -0.023 5.296 0.3702 stilbite 0.1517E-01 -1.819 10.69 1.029 59.74 4.987 stilpnomelane-Fe 0.7652E-05 -5.116 0.8249E-02 -2.084 0.4609E-01 0.2849E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9524E+00 0.9524E+00 1.0000 -0.021 grossular 0.4760E-01 0.4760E-01 1.0000 -1.322 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6105E+00 0.6105E+00 1.0000 -0.214 daphnite 0.3761E+00 0.3761E+00 1.0000 -0.425 chlorite-Mn 0.1334E-01 0.1334E-01 1.0000 -1.875 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 17.896024 g Volume = 7.562009 cm3 Porosity: -0.0319% V(tot) - V(min): -.24088E-02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 16.3990000 g log = 1.2148 Original solution: 1000.0103000 g Original solution / Rock added: 60.98 (Water/Rock Ratio), log = 1.7852 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1684E-06 1.0073 0.1784E-06 0.1771E-06 CH4,gas 0.6362E-15 1.0129 0.6779E-15 0.6693E-15 H2,gas 0.2393E-05 1.0006 0.2518E-05 0.2517E-05 H2S,gas 0.1334E-13 0.9959 0.1397E-13 0.1403E-13 S2,gas 0.1096E-35 1.0000 0.1153E-35 0.1153E-35 CO,gas 0.1107E-15 1.0000 0.1164E-15 0.1164E-15 SO3,gas 0.1003E-39 1.0000 0.1055E-39 0.1055E-39 SO2,gas 0.9556E-23 1.0000 0.1005E-22 0.1005E-22 HCl,gas 0.5084E-17 1.0000 0.5348E-17 0.5348E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.916 0.14938E+05 -6.749 3 CH4,gas 4.81 -12.36 -17.17 -4.292 0.29315E+05 -15.169 4 H2,gas 8.29 0.69 -7.60 -4.342 0.12975E+05 -5.599 5 H2S,gas -5.94 -21.80 -15.85 -7.927 0.27071E+05 -13.855 6 S2,gas -7.03 -44.97 -37.94 -5.837 0.64778E+05 -35.938 7 CO,gas 3.51 -14.42 -17.93 -5.518 0.30622E+05 -15.934 8 SO3,gas 17.43 -24.55 -41.98 -10.494 0.71674E+05 -39.977 9 SO2,gas 1.14 -23.86 -25.00 -6.666 0.42683E+05 -22.998 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32906E+05 -17.272 11 acmite 7.74 7.43 -0.31 -0.032 0.52681E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.07 -4.48 -0.224 0.76505E+04 20 analcite 3.37 3.00 -0.37 -0.041 0.63648E+03 21 andalusite 5.06 0.41 -4.65 -0.465 0.79448E+04 26 annite 20.21 17.50 -2.71 -0.151 0.46318E+04 27 phlogopite 27.15 24.19 -2.96 -0.164 0.50534E+04 29 anorthite 12.80 9.23 -3.57 -0.275 0.60997E+04 35 aragonite 0.99 -2.97 -3.96 -1.319 0.67544E+04 36 brucite 12.58 8.87 -3.70 -0.741 0.63239E+04 37 calcite 0.83 -2.97 -3.80 -1.268 0.64931E+04 38 carnegieite-low 9.06 6.32 -2.74 -0.391 0.46792E+04 39 carnegieite-high 10.13 6.32 -3.81 -0.544 0.65061E+04 40 carpholite-Mg 8.65 5.96 -2.69 -0.180 0.46004E+04 41 carpholite-Fe 6.78 3.73 -3.06 -0.204 0.52196E+04 42 celadonite 5.40 3.11 -2.29 -0.134 0.39026E+04 43 celadonite-Fe 3.94 0.88 -3.05 -0.180 0.52115E+04 44 chrysotile 23.94 19.97 -3.97 -0.331 0.67804E+04 50 chloritoid-Mg 13.26 9.28 -3.98 -0.265 0.67939E+04 51 chloritoid-Fe 9.24 7.05 -2.19 -0.146 0.37333E+04 52 chloritoid-Mn 11.46 9.18 -2.28 -0.152 0.38982E+04 54 coesite -2.37 -3.33 -0.96 -0.319 0.16339E+04 59 corundum 8.43 3.74 -4.70 -0.427 0.80213E+04 61 cristobalite -2.55 -3.33 -0.78 -0.259 0.13267E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.87 -1.03 -0.171 0.17557E+04 67 diopside 16.22 14.36 -1.85 -0.185 0.31637E+04 68 hedenbergite 14.24 12.13 -2.11 -0.211 0.36061E+04 75 epidote 24.78 24.34 -0.44 -0.021 0.74300E+03 76 clinozoisite 22.92 19.91 -3.01 -0.137 0.51430E+04 77 epidote-Fe 29.94 28.77 -1.17 -0.061 0.19905E+04 78 fayalite 14.08 9.96 -4.12 -0.589 0.70341E+04 79 ferrosilite 11.19 6.63 -4.55 -0.455 0.77768E+04 83 gibbsite 4.10 1.87 -2.23 -0.319 0.38069E+04 84 glaucophane 23.11 19.31 -3.80 -0.103 0.64900E+04 85 glaucophane-Fe 17.42 12.62 -4.80 -0.130 0.81924E+04 87 greenalite 16.19 13.28 -2.92 -0.243 0.49828E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 3.00 -1.25 -0.125 0.21395E+04 96 julgoldite 70.57 67.09 -3.48 -0.090 0.59434E+04 97 kalsilite 7.62 4.22 -3.40 -0.486 0.58047E+04 98 kaolinite -1.27 -2.92 -1.64 -0.149 0.28066E+04 99 kyanite 4.93 0.41 -4.52 -0.452 0.77216E+04 101 laumontite 2.97 2.57 -0.40 -0.027 0.68587E+03 102 lawsonite 9.68 9.23 -0.45 -0.030 0.77356E+03 103 leucite 4.17 0.89 -3.27 -0.327 0.55889E+04 105 lizardite 23.29 19.97 -3.32 -0.277 0.56707E+04 107 magnetite 20.13 19.24 -0.89 -0.073 0.15237E+04 108 minnesotaite 10.46 6.62 -3.84 -0.226 0.65520E+04 110 magnesioferrite 26.26 21.47 -4.79 -0.391 0.81732E+04 113 margarite 17.45 12.96 -4.49 -0.180 0.76680E+04 120 muscovite 2.68 1.30 -1.38 -0.081 0.23484E+04 121 paragonite 4.34 3.41 -0.93 -0.055 0.15868E+04 122 nepheline 8.38 6.32 -2.05 -0.293 0.35072E+04 128 periclase-Fe 11.64 6.64 -5.00 -1.249 0.85311E+04 134 phlogopite-Na 29.73 26.29 -3.44 -0.191 0.58753E+04 136 prehnite 19.47 18.04 -1.43 -0.084 0.24333E+04 137 prehnite-Fe 22.59 22.47 -0.11 -0.007 0.19556E+03 138 pumpellyite-Fe 46.47 44.59 -1.88 -0.042 0.32057E+04 139 pumpellyite-Mg 49.19 46.82 -2.37 -0.053 0.40481E+04 145 pyroxmangite 7.42 5.44 -1.97 -0.394 0.33663E+04 146 pyrophyllite -6.10 -9.57 -3.47 -0.217 0.59271E+04 147 quartz -2.98 -3.33 -0.34 -0.115 0.58778E+03 152 rhodonite 7.46 5.44 -2.02 -0.404 0.34455E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.41 -4.91 -0.491 0.83870E+04 165 stilpnomelane-Mg 27.60 24.33 -3.27 -0.098 0.55772E+04 171 talc 16.55 13.31 -3.24 -0.191 0.55314E+04 174 tephroite 18.11 14.22 -3.90 -0.557 0.66550E+04 177 topaz-H 4.67 0.41 -4.26 -0.387 0.72707E+04 178 tridymite -2.61 -3.33 -0.71 -0.237 0.12151E+04 187 wairakite 4.06 2.57 -1.49 -0.087 0.25367E+04 188 walstromite 11.53 8.82 -2.71 -0.542 0.46306E+04 189 wollastonite 10.48 8.82 -1.67 -0.333 0.28445E+04 190 pseudo-wollastonite 11.02 8.82 -2.20 -0.441 0.37631E+04 191 zoisite 22.96 19.91 -3.05 -0.139 0.52156E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.85 -4.29 -0.266 0.73287E+04 195 beidellite-K -1.44 -5.98 -4.55 -0.278 0.77624E+04 196 beidellite-Mg -1.71 -6.39 -4.68 -0.290 0.79984E+04 197 beidellite-Na -1.26 -5.29 -4.03 -0.247 0.68811E+04 199 chalcedony -2.79 -3.33 -0.53 -0.177 0.90809E+03 201 montmorillonite-Ca -2.21 -5.25 -3.04 -0.188 0.51909E+04 202 montmorillonite-K -2.16 -5.38 -3.22 -0.197 0.55024E+04 203 montmorillonite-Mg -2.40 -5.79 -3.39 -0.210 0.57917E+04 204 montmorillonite-Na -1.96 -4.69 -2.73 -0.167 0.46593E+04 205 nontronite-Ca 3.28 3.01 -0.27 -0.017 0.46014E+03 206 nontronite-H 2.60 1.01 -1.59 -0.107 0.27132E+04 207 nontronite-K 3.40 2.88 -0.52 -0.034 0.89302E+03 208 nontronite-Mg 3.14 2.47 -0.67 -0.043 0.11415E+04 209 nontronite-Na 3.58 3.57 -0.01 -0.001 0.13443E+02 224 tobermorite 9.84 6.79 -3.05 -0.832 0.52092E+04 233 boehmite 4.43 1.87 -2.56 -0.427 0.43742E+04 235 ferrous-oxide 9.82 6.64 -3.18 -0.795 0.54322E+04 240 silica-amorphous -2.08 -3.33 -1.25 -0.415 0.21283E+04 242 an20ab80 2.08 1.58 -0.50 -0.038 0.84833E+03 243 an25ab75 2.71 2.06 -0.65 -0.050 0.11083E+04 244 an30ab70 3.34 2.54 -0.81 -0.062 0.13766E+04 245 tr.625ac.25prg.125 45.31 40.65 -4.66 -0.126 0.79586E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 16.3990000 g New total amount of reactant added: 16.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8626E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 16.7990000 Water: Moles liquid = 0.5538E+02 kg liquid = 0.9976E+00 Moles total = 0.5530E+02 kg total = 0.9962E+00 Activity = 1.0000 Stoichiometric ionic strength = .5200625E-02 Osmotic coef. = 0.9618 True ionic strength = .9383104E-02 Chg. balance for total moles = 0.8626E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15252E-09 -9.8167 0.13371E-09 -9.8738 0.87668E+00 -0.0572 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13798E-03 -3.8602 0.12058E-03 -3.9187 0.87386E+00 -0.0586 4 SO4-- 0.25547E-04 -4.5927 0.15821E-04 -4.8008 0.61930E+00 -0.2081 5 HCO3- 0.66233E-05 -5.1789 0.57923E-05 -5.2371 0.87454E+00 -0.0582 6 HS- 0.13396E-11 -11.8730 0.11707E-11 -11.9316 0.87393E+00 -0.0585 7 Al+++ 0.50001E-27 -27.3010 0.17274E-27 -27.7626 0.34547E+00 -0.4616 8 H4SiO4 0.47499E-03 -3.3233 0.47499E-03 -3.3233 0.10000E+01 0.0000 9 Ca++ 0.39960E-07 -7.3984 0.24651E-07 -7.6082 0.61688E+00 -0.2098 10 Mg++ 0.21861E-10 -10.6603 0.13453E-10 -10.8712 0.61538E+00 -0.2109 11 Fe++ 0.12724E-12 -12.8954 0.78344E-13 -13.1060 0.61574E+00 -0.2106 12 K+ 0.73040E-04 -4.1364 0.63884E-04 -4.1946 0.87465E+00 -0.0582 13 Na+ 0.92774E-02 -2.0326 0.81064E-02 -2.0912 0.87378E+00 -0.0586 14 Mn++ 0.17262E-10 -10.7629 0.10633E-10 -10.9733 0.61601E+00 -0.2104 15 HPO4-- 0.53330E-06 -6.2730 0.33029E-06 -6.4811 0.61934E+00 -0.2081 16 HSiO3- 0.39663E-02 -2.4016 0.34660E-02 -2.4602 0.87386E+00 -0.0586 17 Ca(HSiO3)+ 0.21884E-08 -8.6599 0.19143E-08 -8.7180 0.87475E+00 -0.0581 18 Mg(HSiO3)+ 0.14863E-11 -11.8279 0.13002E-11 -11.8860 0.87475E+00 -0.0581 19 NaHSiO3,aq 0.44624E-03 -3.3504 0.44624E-03 -3.3504 0.10000E+01 0.0000 20 AlO+ 0.14259E-14 -14.8459 0.12473E-14 -14.9040 0.87475E+00 -0.0581 22 HAlO2,aq 0.18668E-08 -8.7289 0.18668E-08 -8.7289 0.10000E+01 0.0000 23 AlO2- 0.35709E-04 -4.4472 0.31174E-04 -4.5062 0.87301E+00 -0.0590 24 CH4,aq 0.42125E-18 -18.3755 0.42057E-18 -18.3762 0.99840E+00 -0.0007 29 CO,aq 0.73458E-19 -19.1340 0.73458E-19 -19.1340 0.10000E+01 0.0000 30 CO2,aq 0.15640E-08 -8.8058 0.15615E-08 -8.8065 0.99840E+00 -0.0007 31 CO3-2 0.64750E-05 -5.1888 0.40054E-05 -5.3974 0.61859E+00 -0.2086 32 CaCO3,aq 0.12093E-08 -8.9175 0.12093E-08 -8.9175 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41129E-11 -11.3859 0.35978E-11 -11.4440 0.87475E+00 -0.0581 34 CaCl+ 0.54145E-11 -11.2664 0.47364E-11 -11.3246 0.87475E+00 -0.0581 35 CaCl2,aq 0.13297E-15 -15.8762 0.13297E-15 -15.8762 0.10000E+01 0.0000 36 CaOH+ 0.14861E-07 -7.8279 0.13000E-07 -7.8861 0.87475E+00 -0.0581 37 CaSO4,aq 0.12152E-09 -9.9154 0.12152E-09 -9.9154 0.10000E+01 0.0000 38 HCl,aq 0.30325E-14 -14.5182 0.30325E-14 -14.5182 0.10000E+01 0.0000 43 FeCl+ 0.16819E-16 -16.7742 0.14713E-16 -16.8323 0.87475E+00 -0.0581 46 FeO,aq 0.17329E-09 -9.7612 0.17329E-09 -9.7612 0.10000E+01 0.0000 47 FeOH+ 0.22206E-10 -10.6535 0.19425E-10 -10.7116 0.87475E+00 -0.0581 48 HFeO2- 0.15952E-07 -7.7972 0.13940E-07 -7.8557 0.87386E+00 -0.0586 49 FeO+ 0.12644E-14 -14.8981 0.11061E-14 -14.9562 0.87475E+00 -0.0581 51 FeO2- 0.13915E-07 -7.8565 0.12159E-07 -7.9151 0.87386E+00 -0.0586 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.18295E-08 -8.7377 0.18265E-08 -8.7384 0.99840E+00 -0.0007 54 KCl,aq 0.13639E-09 -9.8652 0.13639E-09 -9.8652 0.10000E+01 0.0000 55 KHSO4,aq 0.36164E-18 -18.4417 0.36164E-18 -18.4417 0.10000E+01 0.0000 56 KOH,aq 0.20829E-06 -6.6813 0.20829E-06 -6.6813 0.10000E+01 0.0000 57 KSO4- 0.17819E-07 -7.7491 0.15572E-07 -7.8077 0.87386E+00 -0.0586 58 MgCO3,aq 0.16491E-12 -12.7828 0.16491E-12 -12.7828 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22889E-14 -14.6404 0.20022E-14 -14.6985 0.87475E+00 -0.0581 60 MgCl+ 0.26826E-14 -14.5715 0.23466E-14 -14.6296 0.87475E+00 -0.0581 61 MgOH+ 0.44932E-10 -10.3474 0.39305E-10 -10.4056 0.87475E+00 -0.0581 63 MnO,aq 0.62787E-09 -9.2021 0.62787E-09 -9.2021 0.10000E+01 0.0000 64 MnOH+ 0.27999E-09 -9.5529 0.24492E-09 -9.6110 0.87475E+00 -0.0581 65 MnO2-2 0.19634E-11 -11.7070 0.12146E-11 -11.9156 0.61859E+00 -0.2086 66 HMnO2- 0.40264E-10 -10.3951 0.35185E-10 -10.4536 0.87386E+00 -0.0586 69 MnCl+ 0.88709E-14 -14.0520 0.77599E-14 -14.1101 0.87475E+00 -0.0581 70 MnSO4,aq 0.47678E-13 -13.3217 0.47678E-13 -13.3217 0.10000E+01 0.0000 71 NaCl,aq 0.31916E-06 -6.4960 0.31916E-06 -6.4960 0.10000E+01 0.0000 72 NaOH,aq 0.26640E-04 -4.5745 0.26640E-04 -4.5745 0.10000E+01 0.0000 74 OH- 0.51387E-02 -2.2891 0.44861E-02 -2.3481 0.87301E+00 -0.0590 79 HPO3-2 0.30804E-17 -17.5114 0.19055E-17 -17.7200 0.61859E+00 -0.2086 82 H3PO4,aq 0.38016E-16 -16.4200 0.38016E-16 -16.4200 0.10000E+01 0.0000 83 H2PO4- 0.88559E-09 -9.0528 0.77427E-09 -9.1111 0.87430E+00 -0.0583 84 PO4-3 0.60827E-08 -8.2159 0.21573E-08 -8.6661 0.35466E+00 -0.4502 87 H2P2O7-2 0.75849E-19 -19.1200 0.46920E-19 -19.3286 0.61859E+00 -0.2086 88 HP2O7-3 0.20820E-15 -15.6815 0.71955E-16 -16.1429 0.34561E+00 -0.4614 89 P2O7-4 0.85350E-15 -15.0688 0.13276E-15 -15.8769 0.15555E+00 -0.8081 90 H2S,aq 0.47107E-15 -15.3269 0.47031E-15 -15.3276 0.99840E+00 -0.0007 97 SO3-2 0.63207E-14 -14.1992 0.39402E-14 -14.4045 0.62338E+00 -0.2052 98 HSO3- 0.35282E-16 -16.4524 0.30832E-16 -16.5110 0.87386E+00 -0.0586 99 HSO4- 0.22427E-11 -11.6492 0.19628E-11 -11.7071 0.87520E+00 -0.0579 Charge balance for all species = 0.8574E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1525166E-09 -.9727520E-02 -.9797812E+01 0.0000 2 H2O 0.1000000E+01 0.5550907E+02 0.9993043E+06 0.0000 3 Cl- 0.1379821E-03 0.1383014E-03 0.4899728E+01 5.9551 4 SO4-- 0.2554702E-04 0.2556627E-04 0.2454197E+01 14.9469 5 HCO3- 0.6623266E-05 0.1310100E-04 0.7988202E+00 4.6367 6 HS- 0.1339588E-11 -.1306049E-08 -.4316306E-04 -2.0577 7 Al+++ 0.5000138E-27 0.3571067E-04 0.9628450E+00 1.8589 8 H4SiO4 0.4749933E-03 0.4887562E-02 0.4694373E+03 -3.3233 9 Ca++ 0.3996039E-07 0.5835036E-07 0.2336909E-02 12.1395 10 Mg++ 0.2186144E-10 0.6844974E-10 0.1662971E-05 8.8765 11 Fe++ 0.1272354E-12 0.3026566E-07 0.1689049E-02 6.6417 12 K+ 0.7303958E-04 0.7326583E-04 0.2862811E+01 5.6792 13 Na+ 0.9277353E-02 0.9750557E-02 0.2240046E+03 7.7827 14 Mn++ 0.1726180E-10 0.9674039E-09 0.5310959E-04 8.7744 15 HPO4-- 0.5332974E-06 0.5402657E-06 0.5181744E-01 13.2666 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2781535E+00 -.9704501E-02 -.2684490E+00 0.0000000E+00 2 H2O 0.5529767E+02 0.5537772E+02 -.8005325E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4910620E-03 0.2550577E-04 0.4655563E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4655576E-03 -.1302958E-08 -.4655563E-03 0.0000000E+00 7 Al+++ 0.5477720E-01 0.3562617E-04 0.5474157E-01 0.0000000E+00 8 H4SiO4 0.1749243E+00 0.4875997E-02 0.1700483E+00 0.0000000E+00 9 Ca++ 0.1933572E-01 0.5821229E-07 0.1933566E-01 0.0000000E+00 10 Mg++ 0.1333254E-01 0.6828777E-10 0.1333254E-01 0.0000000E+00 11 Fe++ 0.1197783E-01 0.3019404E-07 0.1197780E-01 0.0000000E+00 12 K+ 0.3566667E-02 0.7309246E-04 0.3493574E-02 0.0000000E+00 13 Na+ 0.2124691E-01 0.9727484E-02 0.1151942E-01 0.0000000E+00 14 Mn++ 0.2912711E-03 0.9651146E-09 0.2912701E-03 0.0000000E+00 15 HPO4-- 0.9940937E-04 0.5389873E-06 0.9887038E-04 0.0000000E+00 Chg. balance for solid moles: 0.6166E-16 Mass of aqueous solution: 0.998341E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 16.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1152E-01 -1.939 3.021 0.480 16.48 1.160 andradite 0.1186E-02 -2.926 0.6029 -0.220 3.289 0.1567 grossular 0.5809E-04 -4.236 0.2617E-01 -1.582 0.1427 0.7281E-02 apatite-OH 0.3296E-04 -4.482 0.1655E-01 -1.781 0.9030E-01 0.5261E-02 clinochlore 0.2667E-02 -2.574 1.482 0.171 8.085 0.5638 daphnite 0.1625E-02 -2.789 1.160 0.064 6.325 0.3514 chlorite-Mn 0.5825E-04 -4.235 0.4130E-01 -1.384 0.2253 0.1316E-01 hematite 0.6757E-03 -3.170 0.1079 -0.967 0.5887 0.2045E-01 microcline 0.3481E-02 -2.458 0.9688 -0.014 5.285 0.3785 stilbite 0.1544E-01 -1.811 10.88 1.037 59.34 5.074 stilpnomelane-Fe 0.2552E-04 -4.593 0.2751E-01 -1.560 0.1501 0.9504E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9533E+00 0.9533E+00 1.0000 -0.021 grossular 0.4668E-01 0.4668E-01 1.0000 -1.331 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6130E+00 0.6130E+00 1.0000 -0.213 daphnite 0.3736E+00 0.3736E+00 1.0000 -0.428 chlorite-Mn 0.1339E-01 0.1339E-01 1.0000 -1.873 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 18.332419 g Volume = 7.739554 cm3 Porosity: -0.2585% V(tot) - V(min): -.19954E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 16.7990000 g log = 1.2253 Original solution: 1000.0103000 g Original solution / Rock added: 59.53 (Water/Rock Ratio), log = 1.7747 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1687E-06 1.0073 0.1787E-06 0.1774E-06 CH4,gas 0.6242E-15 1.0129 0.6651E-15 0.6566E-15 H2,gas 0.2380E-05 1.0006 0.2505E-05 0.2504E-05 H2S,gas 0.1309E-13 0.9959 0.1372E-13 0.1377E-13 S2,gas 0.1067E-35 1.0000 0.1123E-35 0.1123E-35 CO,gas 0.1103E-15 1.0000 0.1160E-15 0.1160E-15 SO3,gas 0.1005E-39 1.0000 0.1057E-39 0.1057E-39 SO2,gas 0.9527E-23 1.0000 0.1002E-22 0.1002E-22 HCl,gas 0.5090E-17 1.0000 0.5355E-17 0.5355E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.18957E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.916 0.14937E+05 -6.748 3 CH4,gas 4.81 -12.37 -17.18 -4.294 0.29329E+05 -15.177 4 H2,gas 8.29 0.69 -7.60 -4.344 0.12979E+05 -5.601 5 H2S,gas -5.94 -21.81 -15.86 -7.931 0.27085E+05 -13.863 6 S2,gas -7.03 -44.98 -37.95 -5.838 0.64798E+05 -35.950 7 CO,gas 3.51 -14.43 -17.94 -5.519 0.30625E+05 -15.936 8 SO3,gas 17.43 -24.55 -41.98 -10.494 0.71672E+05 -39.976 9 SO2,gas 1.14 -23.86 -25.00 -6.666 0.42685E+05 -22.999 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32905E+05 -17.271 11 acmite 7.74 7.43 -0.30 -0.031 0.51658E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.07 -4.48 -0.224 0.76477E+04 20 analcite 3.37 2.99 -0.38 -0.042 0.64147E+03 21 andalusite 5.06 0.39 -4.67 -0.467 0.79703E+04 26 annite 20.21 17.49 -2.72 -0.151 0.46376E+04 27 phlogopite 27.15 24.20 -2.95 -0.164 0.50351E+04 29 anorthite 12.80 9.21 -3.59 -0.276 0.61247E+04 35 aragonite 0.99 -2.97 -3.96 -1.319 0.67577E+04 36 brucite 12.58 8.88 -3.70 -0.740 0.63178E+04 37 calcite 0.83 -2.97 -3.80 -1.268 0.64963E+04 38 carnegieite-low 9.06 6.32 -2.75 -0.392 0.46892E+04 39 carnegieite-high 10.13 6.32 -3.82 -0.545 0.65161E+04 40 carpholite-Mg 8.65 5.95 -2.70 -0.180 0.46148E+04 41 carpholite-Fe 6.78 3.71 -3.07 -0.205 0.52420E+04 42 celadonite 5.40 3.12 -2.28 -0.134 0.38915E+04 43 celadonite-Fe 3.94 0.89 -3.05 -0.179 0.52084E+04 44 chrysotile 23.94 19.98 -3.95 -0.330 0.67521E+04 50 chloritoid-Mg 13.26 9.27 -3.99 -0.266 0.68132E+04 51 chloritoid-Fe 9.24 7.04 -2.20 -0.147 0.37607E+04 52 chloritoid-Mn 11.46 9.17 -2.29 -0.153 0.39175E+04 54 coesite -2.37 -3.32 -0.95 -0.318 0.16289E+04 59 corundum 8.43 3.72 -4.72 -0.429 0.80518E+04 61 cristobalite -2.55 -3.32 -0.77 -0.258 0.13218E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.86 -1.04 -0.173 0.17710E+04 67 diopside 16.22 14.37 -1.85 -0.185 0.31521E+04 68 hedenbergite 14.24 12.13 -2.11 -0.211 0.36025E+04 75 epidote 24.78 24.33 -0.45 -0.022 0.76749E+03 76 clinozoisite 22.92 19.89 -3.04 -0.138 0.51827E+04 77 epidote-Fe 29.94 28.77 -1.17 -0.061 0.19997E+04 78 fayalite 14.08 9.96 -4.12 -0.588 0.70329E+04 79 ferrosilite 11.19 6.64 -4.55 -0.455 0.77706E+04 83 gibbsite 4.10 1.86 -2.24 -0.320 0.38221E+04 84 glaucophane 23.11 19.33 -3.78 -0.102 0.64617E+04 85 glaucophane-Fe 17.42 12.62 -4.80 -0.130 0.81882E+04 87 greenalite 16.19 13.28 -2.92 -0.243 0.49786E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.99 -1.26 -0.126 0.21445E+04 96 julgoldite 70.57 67.10 -3.48 -0.090 0.59353E+04 97 kalsilite 7.62 4.21 -3.41 -0.486 0.58147E+04 98 kaolinite -1.27 -2.93 -1.66 -0.151 0.28270E+04 99 kyanite 4.93 0.39 -4.54 -0.454 0.77470E+04 101 laumontite 2.97 2.56 -0.41 -0.027 0.70085E+03 102 lawsonite 9.68 9.21 -0.47 -0.031 0.79853E+03 103 leucite 4.17 0.89 -3.28 -0.328 0.55939E+04 105 lizardite 23.29 19.98 -3.30 -0.275 0.56424E+04 107 magnetite 20.13 19.24 -0.89 -0.073 0.15256E+04 108 minnesotaite 10.46 6.63 -3.83 -0.225 0.65378E+04 110 magnesioferrite 26.26 21.47 -4.78 -0.390 0.81671E+04 113 margarite 17.45 12.93 -4.52 -0.181 0.77234E+04 120 muscovite 2.68 1.29 -1.39 -0.082 0.23788E+04 121 paragonite 4.34 3.39 -0.95 -0.056 0.16173E+04 122 nepheline 8.38 6.32 -2.06 -0.294 0.35172E+04 128 periclase-Fe 11.64 6.64 -5.00 -1.249 0.85330E+04 134 phlogopite-Na 29.73 26.30 -3.43 -0.191 0.58570E+04 136 prehnite 19.47 18.03 -1.44 -0.085 0.24578E+04 137 prehnite-Fe 22.59 22.47 -0.12 -0.007 0.20483E+03 138 pumpellyite-Fe 46.47 44.55 -1.92 -0.043 0.32718E+04 139 pumpellyite-Mg 49.19 46.79 -2.40 -0.053 0.41062E+04 145 pyroxmangite 7.42 5.45 -1.96 -0.393 0.33552E+04 146 pyrophyllite -6.10 -9.58 -3.48 -0.217 0.59376E+04 147 quartz -2.98 -3.32 -0.34 -0.114 0.58278E+03 152 rhodonite 7.46 5.45 -2.01 -0.402 0.34344E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.39 -4.93 -0.493 0.84124E+04 165 stilpnomelane-Mg 27.60 24.35 -3.24 -0.097 0.55370E+04 171 talc 16.55 13.34 -3.22 -0.189 0.54931E+04 174 tephroite 18.11 14.23 -3.89 -0.555 0.66378E+04 177 topaz-H 4.67 0.39 -4.27 -0.388 0.72961E+04 178 tridymite -2.61 -3.32 -0.71 -0.236 0.12101E+04 187 wairakite 4.06 2.56 -1.49 -0.088 0.25517E+04 188 walstromite 11.53 8.82 -2.71 -0.542 0.46301E+04 189 wollastonite 10.48 8.82 -1.67 -0.333 0.28440E+04 190 pseudo-wollastonite 11.02 8.82 -2.20 -0.441 0.37626E+04 191 zoisite 22.96 19.89 -3.08 -0.140 0.52553E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.86 -4.30 -0.266 0.73466E+04 195 beidellite-K -1.44 -5.99 -4.56 -0.279 0.77795E+04 196 beidellite-Mg -1.71 -6.40 -4.69 -0.290 0.80145E+04 197 beidellite-Na -1.26 -5.30 -4.04 -0.247 0.68982E+04 199 chalcedony -2.79 -3.32 -0.53 -0.176 0.90310E+03 201 montmorillonite-Ca -2.21 -5.26 -3.04 -0.188 0.51951E+04 202 montmorillonite-K -2.16 -5.39 -3.22 -0.197 0.55058E+04 203 montmorillonite-Mg -2.40 -5.80 -3.39 -0.210 0.57941E+04 204 montmorillonite-Na -1.96 -4.69 -2.73 -0.167 0.46626E+04 205 nontronite-Ca 3.28 3.02 -0.26 -0.017 0.44759E+03 206 nontronite-H 2.60 1.01 -1.58 -0.106 0.26999E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87964E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11271E+04 209 nontronite-Na 3.58 3.58 0.00 0.000 0.61610E-01 224 tobermorite 9.84 6.79 -3.05 -0.832 0.52080E+04 233 boehmite 4.43 1.86 -2.57 -0.428 0.43894E+04 235 ferrous-oxide 9.82 6.64 -3.18 -0.796 0.54341E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.415 0.21233E+04 242 an20ab80 2.08 1.58 -0.50 -0.038 0.85332E+03 243 an25ab75 2.71 2.06 -0.65 -0.050 0.11146E+04 244 an30ab70 3.34 2.53 -0.81 -0.062 0.13841E+04 245 tr.625ac.25prg.125 45.31 40.67 -4.64 -0.125 0.79149E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 16.7990000 g New total amount of reactant added: 17.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8626E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 17.1990000 Water: Moles liquid = 0.5537E+02 kg liquid = 0.9976E+00 Moles total = 0.5529E+02 kg total = 0.9961E+00 Activity = 1.0000 Stoichiometric ionic strength = .5206330E-02 Osmotic coef. = 0.9618 True ionic strength = .9398110E-02 Chg. balance for total moles = 0.8626E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15271E-09 -9.8161 0.13387E-09 -9.8733 0.87662E+00 -0.0572 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13799E-03 -3.8602 0.12057E-03 -3.9188 0.87379E+00 -0.0586 4 SO4-- 0.25548E-04 -4.5926 0.15817E-04 -4.8009 0.61910E+00 -0.2082 5 HCO3- 0.66267E-05 -5.1787 0.57949E-05 -5.2370 0.87447E+00 -0.0583 6 HS- 0.13141E-11 -11.8814 0.11483E-11 -11.9399 0.87385E+00 -0.0586 7 Al+++ 0.49228E-27 -27.3078 0.16994E-27 -27.7697 0.34521E+00 -0.4619 8 H4SiO4 0.47811E-03 -3.3205 0.47811E-03 -3.3205 0.10000E+01 0.0000 9 Ca++ 0.39834E-07 -7.3998 0.24565E-07 -7.6097 0.61668E+00 -0.2099 10 Mg++ 0.22097E-10 -10.6557 0.13593E-10 -10.8667 0.61518E+00 -0.2110 11 Fe++ 0.12726E-12 -12.8953 0.78336E-13 -13.1060 0.61553E+00 -0.2107 12 K+ 0.73157E-04 -4.1357 0.63982E-04 -4.1939 0.87458E+00 -0.0582 13 Na+ 0.92922E-02 -2.0319 0.81187E-02 -2.0905 0.87371E+00 -0.0586 14 Mn++ 0.17448E-10 -10.7583 0.10744E-10 -10.9688 0.61581E+00 -0.2106 15 HPO4-- 0.53746E-06 -6.2697 0.33277E-06 -6.4779 0.61915E+00 -0.2082 16 HSiO3- 0.39879E-02 -2.3993 0.34845E-02 -2.4579 0.87379E+00 -0.0586 17 Ca(HSiO3)+ 0.21926E-08 -8.6590 0.19178E-08 -8.7172 0.87468E+00 -0.0581 18 Mg(HSiO3)+ 0.15100E-11 -11.8210 0.13208E-11 -11.8792 0.87468E+00 -0.0581 19 NaHSiO3,aq 0.44931E-03 -3.3474 0.44931E-03 -3.3474 0.10000E+01 0.0000 20 AlO+ 0.13996E-14 -14.8540 0.12242E-14 -14.9122 0.87468E+00 -0.0581 22 HAlO2,aq 0.18299E-08 -8.7376 0.18299E-08 -8.7376 0.10000E+01 0.0000 23 AlO2- 0.34964E-04 -4.4564 0.30521E-04 -4.5154 0.87294E+00 -0.0590 24 CH4,aq 0.41350E-18 -18.3835 0.41284E-18 -18.3842 0.99840E+00 -0.0007 29 CO,aq 0.73209E-19 -19.1354 0.73209E-19 -19.1354 0.10000E+01 0.0000 30 CO2,aq 0.15666E-08 -8.8050 0.15641E-08 -8.8057 0.99840E+00 -0.0007 31 CO3-2 0.64720E-05 -5.1890 0.40023E-05 -5.3977 0.61839E+00 -0.2087 32 CaCO3,aq 0.12041E-08 -8.9193 0.12041E-08 -8.9193 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41007E-11 -11.3871 0.35868E-11 -11.4453 0.87468E+00 -0.0581 34 CaCl+ 0.53958E-11 -11.2679 0.47196E-11 -11.3261 0.87468E+00 -0.0581 35 CaCl2,aq 0.13250E-15 -15.8778 0.13250E-15 -15.8778 0.10000E+01 0.0000 36 CaOH+ 0.14792E-07 -7.8300 0.12939E-07 -7.8881 0.87468E+00 -0.0581 37 CaSO4,aq 0.12106E-09 -9.9170 0.12106E-09 -9.9170 0.10000E+01 0.0000 38 HCl,aq 0.30361E-14 -14.5177 0.30361E-14 -14.5177 0.10000E+01 0.0000 43 FeCl+ 0.16818E-16 -16.7742 0.14711E-16 -16.8324 0.87468E+00 -0.0581 46 FeO,aq 0.17285E-09 -9.7623 0.17285E-09 -9.7623 0.10000E+01 0.0000 47 FeOH+ 0.22179E-10 -10.6541 0.19399E-10 -10.7122 0.87468E+00 -0.0581 48 HFeO2- 0.15894E-07 -7.7988 0.13888E-07 -7.8574 0.87379E+00 -0.0586 49 FeO+ 0.12661E-14 -14.8975 0.11074E-14 -14.9557 0.87468E+00 -0.0581 51 FeO2- 0.13899E-07 -7.8570 0.12145E-07 -7.9156 0.87379E+00 -0.0586 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.18202E-08 -8.7399 0.18173E-08 -8.7406 0.99840E+00 -0.0007 54 KCl,aq 0.13659E-09 -9.8646 0.13659E-09 -9.8646 0.10000E+01 0.0000 55 KHSO4,aq 0.36253E-18 -18.4407 0.36253E-18 -18.4407 0.10000E+01 0.0000 56 KOH,aq 0.20835E-06 -6.6812 0.20835E-06 -6.6812 0.10000E+01 0.0000 57 KSO4- 0.17843E-07 -7.7485 0.15591E-07 -7.8071 0.87379E+00 -0.0586 58 MgCO3,aq 0.16650E-12 -12.7786 0.16650E-12 -12.7786 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23140E-14 -14.6356 0.20240E-14 -14.6938 0.87468E+00 -0.0581 60 MgCl+ 0.27106E-14 -14.5669 0.23710E-14 -14.6251 0.87468E+00 -0.0581 61 MgOH+ 0.45350E-10 -10.3434 0.39667E-10 -10.4016 0.87468E+00 -0.0581 63 MnO,aq 0.63288E-09 -9.1987 0.63288E-09 -9.1987 0.10000E+01 0.0000 64 MnOH+ 0.28259E-09 -9.5488 0.24718E-09 -9.6070 0.87468E+00 -0.0581 65 MnO2-2 0.19749E-11 -11.7044 0.12213E-11 -11.9132 0.61839E+00 -0.2087 66 HMnO2- 0.40540E-10 -10.3921 0.35423E-10 -10.4507 0.87379E+00 -0.0586 69 MnCl+ 0.89638E-14 -14.0475 0.78405E-14 -14.1057 0.87468E+00 -0.0581 70 MnSO4,aq 0.48162E-13 -13.3173 0.48162E-13 -13.3173 0.10000E+01 0.0000 71 NaCl,aq 0.31963E-06 -6.4954 0.31963E-06 -6.4954 0.10000E+01 0.0000 72 NaOH,aq 0.26648E-04 -4.5743 0.26648E-04 -4.5743 0.10000E+01 0.0000 74 OH- 0.51329E-02 -2.2896 0.44807E-02 -2.3487 0.87294E+00 -0.0590 79 HPO3-2 0.30888E-17 -17.5102 0.19101E-17 -17.7189 0.61839E+00 -0.2087 82 H3PO4,aq 0.38394E-16 -16.4157 0.38394E-16 -16.4157 0.10000E+01 0.0000 83 H2PO4- 0.89338E-09 -9.0490 0.78102E-09 -9.1073 0.87423E+00 -0.0584 84 PO4-3 0.61251E-08 -8.2129 0.21708E-08 -8.6634 0.35441E+00 -0.4505 87 H2P2O7-2 0.77201E-19 -19.1124 0.47741E-19 -19.3211 0.61839E+00 -0.2087 88 HP2O7-3 0.21174E-15 -15.6742 0.73126E-16 -16.1359 0.34536E+00 -0.4617 89 P2O7-4 0.86744E-15 -15.0618 0.13476E-15 -15.8705 0.15535E+00 -0.8087 90 H2S,aq 0.46264E-15 -15.3348 0.46189E-15 -15.3355 0.99840E+00 -0.0007 97 SO3-2 0.62890E-14 -14.2014 0.39192E-14 -14.4068 0.62319E+00 -0.2054 98 HSO3- 0.35140E-16 -16.4542 0.30705E-16 -16.5128 0.87379E+00 -0.0586 99 HSO4- 0.22450E-11 -11.6488 0.19647E-11 -11.7067 0.87513E+00 -0.0579 Charge balance for all species = 0.8575E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1527137E-09 -.9743350E-02 -.9813732E+01 0.0000 2 H2O 0.1000000E+01 0.5550904E+02 0.9993013E+06 0.0000 3 Cl- 0.1379875E-03 0.1383073E-03 0.4899923E+01 5.9546 4 SO4-- 0.2554808E-04 0.2556735E-04 0.2454295E+01 14.9457 5 HCO3- 0.6626733E-05 0.1310155E-04 0.7988520E+00 4.6364 6 HS- 0.1314117E-11 -.1306412E-08 -.4317496E-04 -2.0666 7 Al+++ 0.4922845E-27 0.3496577E-04 0.9427585E+00 1.8502 8 H4SiO4 0.4781134E-03 0.4915291E-02 0.4720994E+03 -3.3205 9 Ca++ 0.3983353E-07 0.5815327E-07 0.2329010E-02 12.1369 10 Mg++ 0.2209685E-10 0.6912795E-10 0.1679444E-05 8.8800 11 Fe++ 0.1272645E-12 0.3019121E-07 0.1684890E-02 6.6406 12 K+ 0.7315669E-04 0.7338302E-04 0.2867383E+01 5.6794 13 Na+ 0.9292240E-02 0.9768522E-02 0.2244167E+03 7.7828 14 Mn++ 0.1744766E-10 0.9754933E-09 0.5355356E-04 8.7778 15 HPO4-- 0.5374628E-06 0.5444813E-06 0.5222162E-01 13.2688 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2847769E+00 -.9719884E-02 -.2750570E+00 0.0000000E+00 2 H2O 0.5529265E+02 0.5537535E+02 -.8269839E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5021474E-03 0.2550577E-04 0.4766416E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4766429E-03 -.1303266E-08 -.4766416E-03 0.0000000E+00 7 Al+++ 0.5608149E-01 0.3488156E-04 0.5604661E-01 0.0000000E+00 8 H4SiO4 0.1790895E+00 0.4903453E-02 0.1741860E+00 0.0000000E+00 9 Ca++ 0.1979577E-01 0.5801321E-07 0.1979572E-01 0.0000000E+00 10 Mg++ 0.1365000E-01 0.6896146E-10 0.1365000E-01 0.0000000E+00 11 Fe++ 0.1226303E-01 0.3011850E-07 0.1226300E-01 0.0000000E+00 12 K+ 0.3651592E-02 0.7320628E-04 0.3578386E-02 0.0000000E+00 13 Na+ 0.2174901E-01 0.9744995E-02 0.1200401E-01 0.0000000E+00 14 Mn++ 0.2982065E-03 0.9731439E-09 0.2982055E-03 0.0000000E+00 15 HPO4-- 0.1017764E-03 0.5431699E-06 0.1012332E-03 0.0000000E+00 Chg. balance for solid moles: 0.7679E-16 Mass of aqueous solution: 0.998301E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 17.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1200E-01 -1.921 3.148 0.498 16.77 1.208 andradite 0.1248E-02 -2.904 0.6342 -0.198 3.379 0.1648 grossular 0.5990E-04 -4.223 0.2698E-01 -1.569 0.1438 0.7507E-02 apatite-OH 0.3374E-04 -4.472 0.1695E-01 -1.771 0.9031E-01 0.5386E-02 clinochlore 0.2730E-02 -2.564 1.517 0.181 8.085 0.5772 daphnite 0.1646E-02 -2.783 1.175 0.070 6.259 0.3560 chlorite-Mn 0.5964E-04 -4.224 0.4228E-01 -1.374 0.2253 0.1347E-01 hematite 0.6586E-03 -3.181 0.1052 -0.978 0.5604 0.1994E-01 microcline 0.3557E-02 -2.449 0.9900 -0.004 5.274 0.3867 stilbite 0.1570E-01 -1.804 11.07 1.044 58.96 5.162 stilpnomelane-Fe 0.4348E-04 -4.362 0.4687E-01 -1.329 0.2497 0.1619E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9542E+00 0.9542E+00 1.0000 -0.020 grossular 0.4580E-01 0.4580E-01 1.0000 -1.339 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6154E+00 0.6154E+00 1.0000 -0.211 daphnite 0.3712E+00 0.3712E+00 1.0000 -0.430 chlorite-Mn 0.1344E-01 0.1344E-01 1.0000 -1.871 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 18.768849 g Volume = 7.917104 cm3 Porosity: -0.4760% V(tot) - V(min): -.37504E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 17.1990000 g log = 1.2355 Original solution: 1000.0103000 g Original solution / Rock added: 58.14 (Water/Rock Ratio), log = 1.7645 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1690E-06 1.0073 0.1790E-06 0.1777E-06 CH4,gas 0.6127E-15 1.0129 0.6529E-15 0.6445E-15 H2,gas 0.2368E-05 1.0006 0.2493E-05 0.2491E-05 H2S,gas 0.1286E-13 0.9959 0.1347E-13 0.1353E-13 S2,gas 0.1040E-35 1.0000 0.1094E-35 0.1094E-35 CO,gas 0.1099E-15 1.0000 0.1156E-15 0.1156E-15 SO3,gas 0.1007E-39 1.0000 0.1060E-39 0.1060E-39 SO2,gas 0.9499E-23 1.0000 0.9993E-23 0.9993E-23 HCl,gas 0.5096E-17 1.0000 0.5361E-17 0.5361E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 209 nontronite-Na 3.58 3.59 0.01 0.000 -0.12950E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.916 0.14935E+05 -6.747 3 CH4,gas 4.81 -12.38 -17.19 -4.296 0.29343E+05 -15.185 4 H2,gas 8.29 0.68 -7.60 -4.345 0.12983E+05 -5.603 5 H2S,gas -5.94 -21.81 -15.87 -7.935 0.27099E+05 -13.871 6 S2,gas -7.03 -44.99 -37.96 -5.840 0.64817E+05 -35.961 7 CO,gas 3.51 -14.43 -17.94 -5.519 0.30627E+05 -15.937 8 SO3,gas 17.43 -24.55 -41.97 -10.494 0.71671E+05 -39.975 9 SO2,gas 1.14 -23.86 -25.00 -6.667 0.42687E+05 -23.000 10 HCl,gas 5.48 -13.79 -19.27 -9.635 0.32904E+05 -17.271 11 acmite 7.74 7.44 -0.30 -0.031 0.50664E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.07 -4.48 -0.224 0.76450E+04 20 analcite 3.37 2.99 -0.38 -0.042 0.64633E+03 21 andalusite 5.06 0.38 -4.68 -0.468 0.79950E+04 26 annite 20.21 17.49 -2.72 -0.151 0.46432E+04 27 phlogopite 27.15 24.21 -2.94 -0.163 0.50175E+04 29 anorthite 12.80 9.20 -3.60 -0.277 0.61489E+04 35 aragonite 0.99 -2.97 -3.96 -1.320 0.67608E+04 36 brucite 12.58 8.88 -3.70 -0.739 0.63119E+04 37 calcite 0.83 -2.97 -3.81 -1.269 0.64995E+04 38 carnegieite-low 9.06 6.31 -2.75 -0.393 0.46989E+04 39 carnegieite-high 10.13 6.31 -3.82 -0.546 0.65258E+04 40 carpholite-Mg 8.65 5.94 -2.71 -0.181 0.46287E+04 41 carpholite-Fe 6.78 3.70 -3.08 -0.206 0.52637E+04 42 celadonite 5.40 3.13 -2.27 -0.134 0.38808E+04 43 celadonite-Fe 3.94 0.89 -3.05 -0.179 0.52054E+04 44 chrysotile 23.94 20.00 -3.94 -0.328 0.67247E+04 50 chloritoid-Mg 13.26 9.26 -4.00 -0.267 0.68320E+04 51 chloritoid-Fe 9.24 7.02 -2.22 -0.148 0.37873E+04 52 chloritoid-Mn 11.46 9.16 -2.31 -0.154 0.39364E+04 54 coesite -2.37 -3.32 -0.95 -0.317 0.16240E+04 59 corundum 8.43 3.70 -4.73 -0.430 0.80814E+04 61 cristobalite -2.55 -3.32 -0.77 -0.257 0.13169E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.85 -1.05 -0.174 0.17857E+04 67 diopside 16.22 14.38 -1.84 -0.184 0.31409E+04 68 hedenbergite 14.24 12.14 -2.11 -0.211 0.35991E+04 75 epidote 24.78 24.31 -0.46 -0.022 0.79131E+03 76 clinozoisite 22.92 19.86 -3.06 -0.139 0.52214E+04 77 epidote-Fe 29.94 28.76 -1.18 -0.061 0.20087E+04 78 fayalite 14.08 9.96 -4.12 -0.588 0.70318E+04 79 ferrosilite 11.19 6.64 -4.55 -0.455 0.77647E+04 83 gibbsite 4.10 1.85 -2.25 -0.321 0.38369E+04 84 glaucophane 23.11 19.34 -3.77 -0.102 0.64343E+04 85 glaucophane-Fe 17.42 12.62 -4.79 -0.130 0.81841E+04 87 greenalite 16.19 13.28 -2.91 -0.243 0.49745E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.99 -1.26 -0.126 0.21494E+04 96 julgoldite 70.57 67.10 -3.47 -0.090 0.59275E+04 97 kalsilite 7.62 4.21 -3.41 -0.487 0.58244E+04 98 kaolinite -1.27 -2.94 -1.67 -0.152 0.28469E+04 99 kyanite 4.93 0.38 -4.55 -0.455 0.77718E+04 101 laumontite 2.97 2.56 -0.42 -0.028 0.71542E+03 102 lawsonite 9.68 9.20 -0.48 -0.032 0.82281E+03 103 leucite 4.17 0.89 -3.28 -0.328 0.55987E+04 105 lizardite 23.29 20.00 -3.29 -0.274 0.56150E+04 107 magnetite 20.13 19.24 -0.89 -0.073 0.15275E+04 108 minnesotaite 10.46 6.64 -3.82 -0.225 0.65240E+04 110 magnesioferrite 26.26 21.48 -4.78 -0.390 0.81612E+04 113 margarite 17.45 12.90 -4.55 -0.182 0.77772E+04 120 muscovite 2.68 1.27 -1.41 -0.083 0.24084E+04 121 paragonite 4.34 3.37 -0.96 -0.057 0.16469E+04 122 nepheline 8.38 6.31 -2.07 -0.295 0.35269E+04 128 periclase-Fe 11.64 6.64 -5.00 -1.250 0.85349E+04 134 phlogopite-Na 29.73 26.31 -3.42 -0.190 0.58393E+04 136 prehnite 19.47 18.01 -1.45 -0.085 0.24816E+04 137 prehnite-Fe 22.59 22.46 -0.13 -0.008 0.21385E+03 138 pumpellyite-Fe 46.47 44.52 -1.95 -0.043 0.33361E+04 139 pumpellyite-Mg 49.19 46.76 -2.44 -0.054 0.41627E+04 145 pyroxmangite 7.42 5.46 -1.96 -0.392 0.33444E+04 146 pyrophyllite -6.10 -9.58 -3.48 -0.218 0.59477E+04 147 quartz -2.98 -3.32 -0.34 -0.113 0.57793E+03 152 rhodonite 7.46 5.46 -2.01 -0.401 0.34237E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.38 -4.94 -0.494 0.84372E+04 165 stilpnomelane-Mg 27.60 24.38 -3.22 -0.096 0.54982E+04 171 talc 16.55 13.36 -3.20 -0.188 0.54560E+04 174 tephroite 18.11 14.24 -3.88 -0.554 0.66212E+04 177 topaz-H 4.67 0.38 -4.29 -0.390 0.73209E+04 178 tridymite -2.61 -3.32 -0.71 -0.235 0.12052E+04 187 wairakite 4.06 2.56 -1.50 -0.088 0.25662E+04 188 walstromite 11.53 8.82 -2.71 -0.542 0.46296E+04 189 wollastonite 10.48 8.82 -1.67 -0.333 0.28435E+04 190 pseudo-wollastonite 11.02 8.82 -2.20 -0.441 0.37622E+04 191 zoisite 22.96 19.86 -3.10 -0.141 0.52939E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.87 -4.31 -0.267 0.73640E+04 195 beidellite-K -1.44 -6.00 -4.57 -0.280 0.77960E+04 196 beidellite-Mg -1.71 -6.41 -4.70 -0.291 0.80302E+04 197 beidellite-Na -1.26 -5.31 -4.05 -0.248 0.69148E+04 199 chalcedony -2.79 -3.32 -0.53 -0.175 0.89824E+03 201 montmorillonite-Ca -2.21 -5.26 -3.04 -0.188 0.51992E+04 202 montmorillonite-K -2.16 -5.39 -3.23 -0.198 0.55090E+04 203 montmorillonite-Mg -2.40 -5.80 -3.39 -0.210 0.57965E+04 204 montmorillonite-Na -1.96 -4.69 -2.73 -0.167 0.46659E+04 205 nontronite-Ca 3.28 3.02 -0.25 -0.017 0.43538E+03 206 nontronite-H 2.60 1.02 -1.57 -0.105 0.26870E+04 207 nontronite-K 3.40 2.90 -0.51 -0.033 0.86663E+03 208 nontronite-Mg 3.14 2.49 -0.65 -0.042 0.11132E+04 224 tobermorite 9.84 6.79 -3.05 -0.832 0.52068E+04 233 boehmite 4.43 1.85 -2.58 -0.430 0.44042E+04 235 ferrous-oxide 9.82 6.64 -3.18 -0.796 0.54360E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.414 0.21184E+04 242 an20ab80 2.08 1.58 -0.50 -0.039 0.85817E+03 243 an25ab75 2.71 2.05 -0.66 -0.050 0.11206E+04 244 an30ab70 3.34 2.53 -0.81 -0.063 0.13914E+04 245 tr.625ac.25prg.125 45.31 40.70 -4.61 -0.124 0.78725E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 17.1990000 Water: Moles liquid = 0.5537E+02 kg liquid = 0.9976E+00 Moles total = 0.5529E+02 kg total = 0.9961E+00 Activity = 1.0000 Stoichiometric ionic strength = .5200659E-02 Osmotic coef. = 0.9618 True ionic strength = .9383180E-02 Chg. balance for total moles = 0.8626E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15252E-09 -9.8167 0.13371E-09 -9.8738 0.87668E+00 -0.0572 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13799E-03 -3.8602 0.12058E-03 -3.9187 0.87386E+00 -0.0586 4 SO4-- 0.25548E-04 -4.5926 0.15822E-04 -4.8007 0.61930E+00 -0.2081 5 HCO3- 0.66235E-05 -5.1789 0.57925E-05 -5.2371 0.87454E+00 -0.0582 6 HS- 0.13395E-11 -11.8731 0.11706E-11 -11.9316 0.87393E+00 -0.0585 7 Al+++ 0.49998E-27 -27.3010 0.17273E-27 -27.7626 0.34547E+00 -0.4616 8 H4SiO4 0.47501E-03 -3.3233 0.47501E-03 -3.3233 0.10000E+01 0.0000 9 Ca++ 0.39960E-07 -7.3984 0.24651E-07 -7.6082 0.61688E+00 -0.2098 10 Mg++ 0.21863E-10 -10.6603 0.13454E-10 -10.8712 0.61538E+00 -0.2109 11 Fe++ 0.12724E-12 -12.8954 0.78344E-13 -13.1060 0.61574E+00 -0.2106 12 K+ 0.73040E-04 -4.1364 0.63885E-04 -4.1946 0.87465E+00 -0.0582 13 Na+ 0.92774E-02 -2.0326 0.81065E-02 -2.0912 0.87378E+00 -0.0586 14 Mn++ 0.17263E-10 -10.7629 0.10634E-10 -10.9733 0.61601E+00 -0.2104 15 HPO4-- 0.53332E-06 -6.2730 0.33031E-06 -6.4811 0.61934E+00 -0.2081 16 HSiO3- 0.39664E-02 -2.4016 0.34661E-02 -2.4602 0.87386E+00 -0.0586 17 Ca(HSiO3)+ 0.21884E-08 -8.6599 0.19143E-08 -8.7180 0.87475E+00 -0.0581 18 Mg(HSiO3)+ 0.14864E-11 -11.8279 0.13003E-11 -11.8860 0.87475E+00 -0.0581 19 NaHSiO3,aq 0.44626E-03 -3.3504 0.44626E-03 -3.3504 0.10000E+01 0.0000 20 AlO+ 0.14258E-14 -14.8459 0.12472E-14 -14.9041 0.87475E+00 -0.0581 22 HAlO2,aq 0.18666E-08 -8.7290 0.18666E-08 -8.7290 0.10000E+01 0.0000 23 AlO2- 0.35705E-04 -4.4473 0.31171E-04 -4.5062 0.87301E+00 -0.0590 24 CH4,aq 0.42123E-18 -18.3755 0.42055E-18 -18.3762 0.99840E+00 -0.0007 29 CO,aq 0.73460E-19 -19.1340 0.73460E-19 -19.1340 0.10000E+01 0.0000 30 CO2,aq 0.15641E-08 -8.8057 0.15616E-08 -8.8064 0.99840E+00 -0.0007 31 CO3-2 0.64752E-05 -5.1887 0.40055E-05 -5.3973 0.61859E+00 -0.2086 32 CaCO3,aq 0.12093E-08 -8.9175 0.12093E-08 -8.9175 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41130E-11 -11.3858 0.35979E-11 -11.4440 0.87475E+00 -0.0581 34 CaCl+ 0.54147E-11 -11.2664 0.47365E-11 -11.3245 0.87475E+00 -0.0581 35 CaCl2,aq 0.13298E-15 -15.8762 0.13298E-15 -15.8762 0.10000E+01 0.0000 36 CaOH+ 0.14861E-07 -7.8280 0.13000E-07 -7.8861 0.87475E+00 -0.0581 37 CaSO4,aq 0.12152E-09 -9.9154 0.12152E-09 -9.9154 0.10000E+01 0.0000 38 HCl,aq 0.30327E-14 -14.5182 0.30327E-14 -14.5182 0.10000E+01 0.0000 43 FeCl+ 0.16820E-16 -16.7742 0.14713E-16 -16.8323 0.87475E+00 -0.0581 46 FeO,aq 0.17328E-09 -9.7612 0.17328E-09 -9.7612 0.10000E+01 0.0000 47 FeOH+ 0.22206E-10 -10.6535 0.19425E-10 -10.7116 0.87475E+00 -0.0581 48 HFeO2- 0.15952E-07 -7.7972 0.13940E-07 -7.8558 0.87386E+00 -0.0586 49 FeO+ 0.12644E-14 -14.8981 0.11061E-14 -14.9562 0.87475E+00 -0.0581 51 FeO2- 0.13914E-07 -7.8565 0.12159E-07 -7.9151 0.87386E+00 -0.0586 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.18294E-08 -8.7377 0.18265E-08 -8.7384 0.99840E+00 -0.0007 54 KCl,aq 0.13640E-09 -9.8652 0.13640E-09 -9.8652 0.10000E+01 0.0000 55 KHSO4,aq 0.36166E-18 -18.4417 0.36166E-18 -18.4417 0.10000E+01 0.0000 56 KOH,aq 0.20829E-06 -6.6813 0.20829E-06 -6.6813 0.10000E+01 0.0000 57 KSO4- 0.17820E-07 -7.7491 0.15572E-07 -7.8076 0.87386E+00 -0.0586 58 MgCO3,aq 0.16492E-12 -12.7827 0.16492E-12 -12.7827 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22891E-14 -14.6403 0.20024E-14 -14.6985 0.87475E+00 -0.0581 60 MgCl+ 0.26828E-14 -14.5714 0.23468E-14 -14.6295 0.87475E+00 -0.0581 61 MgOH+ 0.44934E-10 -10.3474 0.39306E-10 -10.4055 0.87475E+00 -0.0581 63 MnO,aq 0.62789E-09 -9.2021 0.62789E-09 -9.2021 0.10000E+01 0.0000 64 MnOH+ 0.28000E-09 -9.5528 0.24493E-09 -9.6110 0.87475E+00 -0.0581 65 MnO2-2 0.19635E-11 -11.7070 0.12146E-11 -11.9156 0.61859E+00 -0.2086 66 HMnO2- 0.40265E-10 -10.3951 0.35186E-10 -10.4536 0.87386E+00 -0.0586 69 MnCl+ 0.88717E-14 -14.0520 0.77606E-14 -14.1101 0.87475E+00 -0.0581 70 MnSO4,aq 0.47682E-13 -13.3216 0.47682E-13 -13.3216 0.10000E+01 0.0000 71 NaCl,aq 0.31917E-06 -6.4960 0.31917E-06 -6.4960 0.10000E+01 0.0000 72 NaOH,aq 0.26640E-04 -4.5745 0.26640E-04 -4.5745 0.10000E+01 0.0000 74 OH- 0.51386E-02 -2.2892 0.44861E-02 -2.3481 0.87301E+00 -0.0590 79 HPO3-2 0.30805E-17 -17.5114 0.19055E-17 -17.7200 0.61859E+00 -0.2086 82 H3PO4,aq 0.38018E-16 -16.4200 0.38018E-16 -16.4200 0.10000E+01 0.0000 83 H2PO4- 0.88563E-09 -9.0527 0.77431E-09 -9.1111 0.87430E+00 -0.0583 84 PO4-3 0.60829E-08 -8.2159 0.21574E-08 -8.6661 0.35466E+00 -0.4502 87 H2P2O7-2 0.75856E-19 -19.1200 0.46924E-19 -19.3286 0.61859E+00 -0.2086 88 HP2O7-3 0.20821E-15 -15.6815 0.71961E-16 -16.1429 0.34561E+00 -0.4614 89 P2O7-4 0.85356E-15 -15.0688 0.13277E-15 -15.8769 0.15555E+00 -0.8081 90 H2S,aq 0.47105E-15 -15.3269 0.47029E-15 -15.3276 0.99840E+00 -0.0007 97 SO3-2 0.63208E-14 -14.1992 0.39403E-14 -14.4045 0.62338E+00 -0.2052 98 HSO3- 0.35283E-16 -16.4524 0.30832E-16 -16.5110 0.87386E+00 -0.0586 99 HSO4- 0.22428E-11 -11.6492 0.19629E-11 -11.7071 0.87520E+00 -0.0579 Charge balance for all species = 0.8768E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1525176E-09 -.9727591E-02 -.9797883E+01 0.0000 2 H2O 0.1000000E+01 0.5550907E+02 0.9993043E+06 0.0000 3 Cl- 0.1379877E-03 0.1383070E-03 0.4899925E+01 5.9551 4 SO4-- 0.2554805E-04 0.2556730E-04 0.2454296E+01 14.9469 5 HCO3- 0.6623548E-05 0.1310153E-04 0.7988523E+00 4.6367 6 HS- 0.1339520E-11 -.1306050E-08 -.4316309E-04 -2.0577 7 Al+++ 0.4999776E-27 0.3570709E-04 0.9627485E+00 1.8589 8 H4SiO4 0.4750080E-03 0.4887692E-02 0.4694497E+03 -3.3233 9 Ca++ 0.3995983E-07 0.5834953E-07 0.2336876E-02 12.1395 10 Mg++ 0.2186257E-10 0.6845300E-10 0.1663050E-05 8.8765 11 Fe++ 0.1272356E-12 0.3026530E-07 0.1689029E-02 6.6417 12 K+ 0.7304017E-04 0.7326642E-04 0.2862834E+01 5.6792 13 Na+ 0.9277428E-02 0.9750646E-02 0.2240066E+03 7.7827 14 Mn++ 0.1726270E-10 0.9674423E-09 0.5311170E-04 8.7744 15 HPO4-- 0.5333166E-06 0.5402852E-06 0.5181930E-01 13.2666 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2847769E+00 -.9704182E-02 -.2750727E+00 0.0000000E+00 2 H2O 0.5529265E+02 0.5537550E+02 -.8284324E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5021474E-03 0.2550577E-04 0.4766416E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4766429E-03 -.1302907E-08 -.4766416E-03 0.0000000E+00 7 Al+++ 0.5608149E-01 0.3562117E-04 0.5604587E-01 0.0000000E+00 8 H4SiO4 0.1790895E+00 0.4875930E-02 0.1742135E+00 0.0000000E+00 9 Ca++ 0.1979577E-01 0.5820912E-07 0.1979572E-01 0.0000000E+00 10 Mg++ 0.1365000E-01 0.6828827E-10 0.1365000E-01 0.0000000E+00 11 Fe++ 0.1226303E-01 0.3019246E-07 0.1226300E-01 0.0000000E+00 12 K+ 0.3651592E-02 0.7309011E-04 0.3578502E-02 0.0000000E+00 13 Na+ 0.2174901E-01 0.9727182E-02 0.1202182E-01 0.0000000E+00 14 Mn++ 0.2982065E-03 0.9651142E-09 0.2982055E-03 0.0000000E+00 15 HPO4-- 0.1017764E-03 0.5389850E-06 0.1012374E-03 0.0000000E+00 Chg. balance for solid moles: -.2196E-17 Mass of aqueous solution: 0.998301E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 17.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1201E-01 -1.921 3.148 0.498 16.77 1.209 andradite 0.1252E-02 -2.903 0.6360 -0.197 3.389 0.1652 grossular 0.6128E-04 -4.213 0.2760E-01 -1.559 0.1471 0.7680E-02 apatite-OH 0.3375E-04 -4.472 0.1695E-01 -1.771 0.9031E-01 0.5386E-02 clinochlore 0.2730E-02 -2.564 1.517 0.181 8.085 0.5772 daphnite 0.1664E-02 -2.779 1.187 0.074 6.325 0.3597 chlorite-Mn 0.5964E-04 -4.224 0.4228E-01 -1.374 0.2253 0.1347E-01 hematite 0.6086E-03 -3.216 0.9719E-01 -1.012 0.5178 0.1842E-01 microcline 0.3565E-02 -2.448 0.9924 -0.003 5.287 0.3877 stilbite 0.1569E-01 -1.804 11.06 1.044 58.90 5.157 stilpnomelane-Fe 0.2621E-04 -4.581 0.2826E-01 -1.549 0.1506 0.9761E-02 nontronite-Na 0.4640E-04 -4.333 0.1973E-01 -1.705 0.1051 0.6130E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9533E+00 0.9533E+00 1.0000 -0.021 grossular 0.4667E-01 0.4667E-01 1.0000 -1.331 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6130E+00 0.6130E+00 1.0000 -0.213 daphnite 0.3736E+00 0.3736E+00 1.0000 -0.428 chlorite-Mn 0.1339E-01 0.1339E-01 1.0000 -1.873 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 18.769264 g Volume = 7.915939 cm3 Porosity: -0.4612% V(tot) - V(min): -.36339E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 17.1990000 g log = 1.2355 Original solution: 1000.0103000 g Original solution / Rock added: 58.14 (Water/Rock Ratio), log = 1.7645 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1687E-06 1.0073 0.1788E-06 0.1775E-06 CH4,gas 0.6242E-15 1.0129 0.6651E-15 0.6566E-15 H2,gas 0.2380E-05 1.0006 0.2505E-05 0.2504E-05 H2S,gas 0.1309E-13 0.9959 0.1372E-13 0.1377E-13 S2,gas 0.1067E-35 1.0000 0.1123E-35 0.1123E-35 CO,gas 0.1103E-15 1.0000 0.1160E-15 0.1160E-15 SO3,gas 0.1005E-39 1.0000 0.1058E-39 0.1058E-39 SO2,gas 0.9527E-23 1.0000 0.1002E-22 0.1002E-22 HCl,gas 0.5090E-17 1.0000 0.5355E-17 0.5355E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 -0.48529E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.11374E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.916 0.14937E+05 -6.748 3 CH4,gas 4.81 -12.37 -17.18 -4.294 0.29330E+05 -15.177 4 H2,gas 8.29 0.69 -7.60 -4.344 0.12979E+05 -5.601 5 H2S,gas -5.94 -21.81 -15.86 -7.931 0.27085E+05 -13.863 6 S2,gas -7.03 -44.98 -37.95 -5.838 0.64798E+05 -35.950 7 CO,gas 3.51 -14.43 -17.94 -5.519 0.30624E+05 -15.936 8 SO3,gas 17.43 -24.55 -41.98 -10.494 0.71672E+05 -39.976 9 SO2,gas 1.14 -23.86 -25.00 -6.666 0.42685E+05 -22.999 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32905E+05 -17.271 11 acmite 7.74 7.43 -0.30 -0.031 0.51654E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.07 -4.48 -0.224 0.76477E+04 20 analcite 3.37 2.99 -0.38 -0.042 0.64150E+03 21 andalusite 5.06 0.39 -4.67 -0.467 0.79704E+04 26 annite 20.21 17.49 -2.72 -0.151 0.46376E+04 27 phlogopite 27.15 24.20 -2.95 -0.164 0.50351E+04 29 anorthite 12.80 9.21 -3.59 -0.276 0.61248E+04 35 aragonite 0.99 -2.97 -3.96 -1.319 0.67576E+04 36 brucite 12.58 8.88 -3.70 -0.740 0.63178E+04 37 calcite 0.83 -2.97 -3.80 -1.268 0.64963E+04 38 carnegieite-low 9.06 6.32 -2.75 -0.392 0.46893E+04 39 carnegieite-high 10.13 6.32 -3.82 -0.545 0.65161E+04 40 carpholite-Mg 8.65 5.95 -2.70 -0.180 0.46148E+04 41 carpholite-Fe 6.78 3.71 -3.07 -0.205 0.52421E+04 42 celadonite 5.40 3.12 -2.28 -0.134 0.38915E+04 43 celadonite-Fe 3.94 0.89 -3.05 -0.179 0.52084E+04 44 chrysotile 23.94 19.98 -3.95 -0.330 0.67520E+04 50 chloritoid-Mg 13.26 9.27 -3.99 -0.266 0.68133E+04 51 chloritoid-Fe 9.24 7.04 -2.20 -0.147 0.37608E+04 52 chloritoid-Mn 11.46 9.17 -2.29 -0.153 0.39176E+04 54 coesite -2.37 -3.32 -0.95 -0.318 0.16288E+04 59 corundum 8.43 3.72 -4.72 -0.429 0.80519E+04 61 cristobalite -2.55 -3.32 -0.77 -0.258 0.13217E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.86 -1.04 -0.173 0.17710E+04 67 diopside 16.22 14.37 -1.85 -0.185 0.31521E+04 68 hedenbergite 14.24 12.13 -2.11 -0.211 0.36025E+04 75 epidote 24.78 24.33 -0.45 -0.022 0.76760E+03 76 clinozoisite 22.92 19.89 -3.04 -0.138 0.51829E+04 77 epidote-Fe 29.94 28.77 -1.17 -0.061 0.19998E+04 78 fayalite 14.08 9.96 -4.12 -0.588 0.70329E+04 79 ferrosilite 11.19 6.64 -4.55 -0.455 0.77706E+04 83 gibbsite 4.10 1.86 -2.24 -0.320 0.38222E+04 84 glaucophane 23.11 19.33 -3.78 -0.102 0.64616E+04 85 glaucophane-Fe 17.42 12.62 -4.80 -0.130 0.81881E+04 87 greenalite 16.19 13.28 -2.92 -0.243 0.49786E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.99 -1.26 -0.126 0.21445E+04 96 julgoldite 70.57 67.10 -3.48 -0.090 0.59353E+04 97 kalsilite 7.62 4.21 -3.41 -0.486 0.58147E+04 98 kaolinite -1.27 -2.93 -1.66 -0.151 0.28271E+04 99 kyanite 4.93 0.39 -4.54 -0.454 0.77472E+04 101 laumontite 2.97 2.56 -0.41 -0.027 0.70092E+03 102 lawsonite 9.68 9.21 -0.47 -0.031 0.79864E+03 103 leucite 4.17 0.89 -3.28 -0.328 0.55939E+04 105 lizardite 23.29 19.98 -3.30 -0.275 0.56423E+04 107 magnetite 20.13 19.24 -0.89 -0.073 0.15256E+04 108 minnesotaite 10.46 6.63 -3.83 -0.225 0.65377E+04 110 magnesioferrite 26.26 21.47 -4.78 -0.390 0.81671E+04 113 margarite 17.45 12.93 -4.52 -0.181 0.77236E+04 120 muscovite 2.68 1.29 -1.39 -0.082 0.23789E+04 121 paragonite 4.34 3.39 -0.95 -0.056 0.16174E+04 122 nepheline 8.38 6.32 -2.06 -0.294 0.35172E+04 128 periclase-Fe 11.64 6.64 -5.00 -1.249 0.85330E+04 134 phlogopite-Na 29.73 26.30 -3.43 -0.191 0.58570E+04 136 prehnite 19.47 18.03 -1.44 -0.085 0.24579E+04 137 prehnite-Fe 22.59 22.47 -0.12 -0.007 0.20487E+03 138 pumpellyite-Fe 46.47 44.55 -1.92 -0.043 0.32721E+04 139 pumpellyite-Mg 49.19 46.79 -2.40 -0.053 0.41064E+04 145 pyroxmangite 7.42 5.45 -1.96 -0.393 0.33551E+04 146 pyrophyllite -6.10 -9.58 -3.48 -0.217 0.59376E+04 147 quartz -2.98 -3.32 -0.34 -0.114 0.58276E+03 152 rhodonite 7.46 5.45 -2.01 -0.402 0.34344E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.39 -4.93 -0.493 0.84126E+04 165 stilpnomelane-Mg 27.60 24.35 -3.24 -0.097 0.55369E+04 171 talc 16.55 13.34 -3.22 -0.189 0.54930E+04 174 tephroite 18.11 14.23 -3.89 -0.555 0.66377E+04 177 topaz-H 4.67 0.39 -4.27 -0.388 0.72962E+04 178 tridymite -2.61 -3.32 -0.71 -0.236 0.12101E+04 187 wairakite 4.06 2.56 -1.49 -0.088 0.25517E+04 188 walstromite 11.53 8.82 -2.71 -0.542 0.46301E+04 189 wollastonite 10.48 8.82 -1.67 -0.333 0.28440E+04 190 pseudo-wollastonite 11.02 8.82 -2.20 -0.441 0.37626E+04 191 zoisite 22.96 19.89 -3.08 -0.140 0.52555E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.86 -4.30 -0.266 0.73467E+04 195 beidellite-K -1.44 -5.99 -4.56 -0.279 0.77795E+04 196 beidellite-Mg -1.71 -6.40 -4.69 -0.290 0.80146E+04 197 beidellite-Na -1.26 -5.30 -4.04 -0.247 0.68983E+04 199 chalcedony -2.79 -3.32 -0.53 -0.176 0.90308E+03 201 montmorillonite-Ca -2.21 -5.26 -3.04 -0.188 0.51951E+04 202 montmorillonite-K -2.16 -5.39 -3.22 -0.197 0.55058E+04 203 montmorillonite-Mg -2.40 -5.80 -3.39 -0.210 0.57941E+04 204 montmorillonite-Na -1.96 -4.69 -2.73 -0.167 0.46626E+04 205 nontronite-Ca 3.28 3.02 -0.26 -0.017 0.44753E+03 206 nontronite-H 2.60 1.01 -1.58 -0.106 0.26999E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11271E+04 224 tobermorite 9.84 6.79 -3.05 -0.832 0.52080E+04 233 boehmite 4.43 1.86 -2.57 -0.428 0.43895E+04 235 ferrous-oxide 9.82 6.64 -3.18 -0.796 0.54341E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.415 0.21233E+04 242 an20ab80 2.08 1.58 -0.50 -0.038 0.85334E+03 243 an25ab75 2.71 2.06 -0.65 -0.050 0.11146E+04 244 an30ab70 3.34 2.53 -0.81 -0.062 0.13842E+04 245 tr.625ac.25prg.125 45.31 40.67 -4.64 -0.125 0.79147E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 17.1990000 g New total amount of reactant added: 17.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8623E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 17.5990000 Water: Moles liquid = 0.5537E+02 kg liquid = 0.9976E+00 Moles total = 0.5529E+02 kg total = 0.9960E+00 Activity = 1.0000 Stoichiometric ionic strength = .5200666E-02 Osmotic coef. = 0.9618 True ionic strength = .9383186E-02 Chg. balance for total moles = 0.8623E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15252E-09 -9.8167 0.13371E-09 -9.8738 0.87668E+00 -0.0572 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13799E-03 -3.8601 0.12059E-03 -3.9187 0.87386E+00 -0.0586 4 SO4-- 0.25549E-04 -4.5926 0.15822E-04 -4.8007 0.61930E+00 -0.2081 5 HCO3- 0.66238E-05 -5.1789 0.57928E-05 -5.2371 0.87454E+00 -0.0582 6 HS- 0.13396E-11 -11.8730 0.11707E-11 -11.9316 0.87393E+00 -0.0585 7 Al+++ 0.49998E-27 -27.3010 0.17273E-27 -27.7626 0.34547E+00 -0.4616 8 H4SiO4 0.47501E-03 -3.3233 0.47501E-03 -3.3233 0.10000E+01 0.0000 9 Ca++ 0.39960E-07 -7.3984 0.24651E-07 -7.6082 0.61688E+00 -0.2098 10 Mg++ 0.21863E-10 -10.6603 0.13454E-10 -10.8712 0.61538E+00 -0.2109 11 Fe++ 0.12724E-12 -12.8954 0.78344E-13 -13.1060 0.61574E+00 -0.2106 12 K+ 0.73040E-04 -4.1364 0.63885E-04 -4.1946 0.87465E+00 -0.0582 13 Na+ 0.92774E-02 -2.0326 0.81065E-02 -2.0912 0.87378E+00 -0.0586 14 Mn++ 0.17263E-10 -10.7629 0.10634E-10 -10.9733 0.61601E+00 -0.2104 15 HPO4-- 0.53332E-06 -6.2730 0.33031E-06 -6.4811 0.61934E+00 -0.2081 16 HSiO3- 0.39664E-02 -2.4016 0.34661E-02 -2.4602 0.87386E+00 -0.0586 17 Ca(HSiO3)+ 0.21884E-08 -8.6599 0.19143E-08 -8.7180 0.87475E+00 -0.0581 18 Mg(HSiO3)+ 0.14864E-11 -11.8279 0.13003E-11 -11.8860 0.87475E+00 -0.0581 19 NaHSiO3,aq 0.44626E-03 -3.3504 0.44626E-03 -3.3504 0.10000E+01 0.0000 20 AlO+ 0.14258E-14 -14.8459 0.12472E-14 -14.9041 0.87475E+00 -0.0581 22 HAlO2,aq 0.18666E-08 -8.7290 0.18666E-08 -8.7290 0.10000E+01 0.0000 23 AlO2- 0.35705E-04 -4.4473 0.31171E-04 -4.5062 0.87301E+00 -0.0590 24 CH4,aq 0.42124E-18 -18.3755 0.42057E-18 -18.3762 0.99840E+00 -0.0007 29 CO,aq 0.73463E-19 -19.1339 0.73463E-19 -19.1339 0.10000E+01 0.0000 30 CO2,aq 0.15642E-08 -8.8057 0.15616E-08 -8.8064 0.99840E+00 -0.0007 31 CO3-2 0.64755E-05 -5.1887 0.40057E-05 -5.3973 0.61859E+00 -0.2086 32 CaCO3,aq 0.12094E-08 -8.9174 0.12094E-08 -8.9174 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41132E-11 -11.3858 0.35980E-11 -11.4439 0.87475E+00 -0.0581 34 CaCl+ 0.54149E-11 -11.2664 0.47367E-11 -11.3245 0.87475E+00 -0.0581 35 CaCl2,aq 0.13299E-15 -15.8762 0.13299E-15 -15.8762 0.10000E+01 0.0000 36 CaOH+ 0.14861E-07 -7.8280 0.13000E-07 -7.8861 0.87475E+00 -0.0581 37 CaSO4,aq 0.12153E-09 -9.9153 0.12153E-09 -9.9153 0.10000E+01 0.0000 38 HCl,aq 0.30328E-14 -14.5182 0.30328E-14 -14.5182 0.10000E+01 0.0000 43 FeCl+ 0.16821E-16 -16.7742 0.14714E-16 -16.8323 0.87475E+00 -0.0581 46 FeO,aq 0.17328E-09 -9.7612 0.17328E-09 -9.7612 0.10000E+01 0.0000 47 FeOH+ 0.22206E-10 -10.6535 0.19425E-10 -10.7116 0.87475E+00 -0.0581 48 HFeO2- 0.15952E-07 -7.7972 0.13940E-07 -7.8558 0.87386E+00 -0.0586 49 FeO+ 0.12644E-14 -14.8981 0.11061E-14 -14.9562 0.87475E+00 -0.0581 51 FeO2- 0.13914E-07 -7.8565 0.12159E-07 -7.9151 0.87386E+00 -0.0586 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.18294E-08 -8.7377 0.18265E-08 -8.7384 0.99840E+00 -0.0007 54 KCl,aq 0.13640E-09 -9.8652 0.13640E-09 -9.8652 0.10000E+01 0.0000 55 KHSO4,aq 0.36167E-18 -18.4417 0.36167E-18 -18.4417 0.10000E+01 0.0000 56 KOH,aq 0.20829E-06 -6.6813 0.20829E-06 -6.6813 0.10000E+01 0.0000 57 KSO4- 0.17821E-07 -7.7491 0.15573E-07 -7.8076 0.87386E+00 -0.0586 58 MgCO3,aq 0.16493E-12 -12.7827 0.16493E-12 -12.7827 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22892E-14 -14.6403 0.20025E-14 -14.6984 0.87475E+00 -0.0581 60 MgCl+ 0.26829E-14 -14.5714 0.23469E-14 -14.6295 0.87475E+00 -0.0581 61 MgOH+ 0.44934E-10 -10.3474 0.39306E-10 -10.4055 0.87475E+00 -0.0581 63 MnO,aq 0.62789E-09 -9.2021 0.62789E-09 -9.2021 0.10000E+01 0.0000 64 MnOH+ 0.28000E-09 -9.5528 0.24493E-09 -9.6110 0.87475E+00 -0.0581 65 MnO2-2 0.19635E-11 -11.7070 0.12146E-11 -11.9156 0.61859E+00 -0.2086 66 HMnO2- 0.40265E-10 -10.3951 0.35186E-10 -10.4536 0.87386E+00 -0.0586 69 MnCl+ 0.88721E-14 -14.0520 0.77609E-14 -14.1101 0.87475E+00 -0.0581 70 MnSO4,aq 0.47684E-13 -13.3216 0.47684E-13 -13.3216 0.10000E+01 0.0000 71 NaCl,aq 0.31919E-06 -6.4960 0.31919E-06 -6.4960 0.10000E+01 0.0000 72 NaOH,aq 0.26640E-04 -4.5745 0.26640E-04 -4.5745 0.10000E+01 0.0000 74 OH- 0.51386E-02 -2.2892 0.44861E-02 -2.3481 0.87301E+00 -0.0590 79 HPO3-2 0.30805E-17 -17.5114 0.19055E-17 -17.7200 0.61859E+00 -0.2086 82 H3PO4,aq 0.38018E-16 -16.4200 0.38018E-16 -16.4200 0.10000E+01 0.0000 83 H2PO4- 0.88563E-09 -9.0527 0.77430E-09 -9.1111 0.87430E+00 -0.0583 84 PO4-3 0.60829E-08 -8.2159 0.21574E-08 -8.6661 0.35466E+00 -0.4502 87 H2P2O7-2 0.75855E-19 -19.1200 0.46924E-19 -19.3286 0.61859E+00 -0.2086 88 HP2O7-3 0.20821E-15 -15.6815 0.71961E-16 -16.1429 0.34561E+00 -0.4614 89 P2O7-4 0.85356E-15 -15.0688 0.13277E-15 -15.8769 0.15555E+00 -0.8081 90 H2S,aq 0.47107E-15 -15.3269 0.47031E-15 -15.3276 0.99840E+00 -0.0007 97 SO3-2 0.63210E-14 -14.1992 0.39404E-14 -14.4045 0.62338E+00 -0.2052 98 HSO3- 0.35284E-16 -16.4524 0.30833E-16 -16.5110 0.87386E+00 -0.0586 99 HSO4- 0.22429E-11 -11.6492 0.19630E-11 -11.7071 0.87520E+00 -0.0579 Charge balance for all species = 0.8507E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1525177E-09 -.9727587E-02 -.9797879E+01 0.0000 2 H2O 0.1000000E+01 0.5550907E+02 0.9993043E+06 0.0000 3 Cl- 0.1379932E-03 0.1383126E-03 0.4900122E+01 5.9551 4 SO4-- 0.2554907E-04 0.2556832E-04 0.2454394E+01 14.9469 5 HCO3- 0.6623816E-05 0.1310205E-04 0.7988844E+00 4.6367 6 HS- 0.1339574E-11 -.1306049E-08 -.4316306E-04 -2.0577 7 Al+++ 0.4999785E-27 0.3570708E-04 0.9627481E+00 1.8589 8 H4SiO4 0.4750080E-03 0.4887690E-02 0.4694495E+03 -3.3233 9 Ca++ 0.3995987E-07 0.5834964E-07 0.2336880E-02 12.1395 10 Mg++ 0.2186260E-10 0.6845305E-10 0.1663052E-05 8.8765 11 Fe++ 0.1272358E-12 0.3026528E-07 0.1689028E-02 6.6417 12 K+ 0.7304021E-04 0.7326645E-04 0.2862836E+01 5.6792 13 Na+ 0.9277432E-02 0.9750651E-02 0.2240067E+03 7.7827 14 Mn++ 0.1726272E-10 0.9674425E-09 0.5311171E-04 8.7744 15 HPO4-- 0.5333162E-06 0.5402848E-06 0.5181926E-01 13.2666 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2914003E+00 -.9703789E-02 -.2816965E+00 0.0000000E+00 2 H2O 0.5528764E+02 0.5537327E+02 -.8563391E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5132328E-03 0.2550577E-04 0.4877270E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4877283E-03 -.1302854E-08 -.4877270E-03 0.0000000E+00 7 Al+++ 0.5738579E-01 0.3561972E-04 0.5735017E-01 0.0000000E+00 8 H4SiO4 0.1832546E+00 0.4875732E-02 0.1783788E+00 0.0000000E+00 9 Ca++ 0.2025583E-01 0.5820689E-07 0.2025577E-01 0.0000000E+00 10 Mg++ 0.1396746E-01 0.6828558E-10 0.1396746E-01 0.0000000E+00 11 Fe++ 0.1254824E-01 0.3019124E-07 0.1254821E-01 0.0000000E+00 12 K+ 0.3736518E-02 0.7308721E-04 0.3663431E-02 0.0000000E+00 13 Na+ 0.2225110E-01 0.9726796E-02 0.1252431E-01 0.0000000E+00 14 Mn++ 0.3051420E-03 0.9650757E-09 0.3051410E-03 0.0000000E+00 15 HPO4-- 0.1041434E-03 0.5389630E-06 0.1036045E-03 0.0000000E+00 Chg. balance for solid moles: -.3564E-16 Mass of aqueous solution: 0.998261E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 17.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1249E-01 -1.903 3.276 0.515 17.06 1.258 andradite 0.1317E-02 -2.881 0.6691 -0.175 3.484 0.1738 grossular 0.6446E-04 -4.191 0.2904E-01 -1.537 0.1512 0.8079E-02 apatite-OH 0.3453E-04 -4.462 0.1735E-01 -1.761 0.9032E-01 0.5512E-02 clinochlore 0.2793E-02 -2.554 1.553 0.191 8.084 0.5906 daphnite 0.1702E-02 -2.769 1.215 0.084 6.325 0.3681 chlorite-Mn 0.6103E-04 -4.214 0.4327E-01 -1.364 0.2253 0.1379E-01 hematite 0.5412E-03 -3.267 0.8643E-01 -1.063 0.4500 0.1638E-01 microcline 0.3650E-02 -2.438 1.016 0.007 5.290 0.3969 stilbite 0.1594E-01 -1.798 11.23 1.050 58.49 5.239 stilpnomelane-Fe 0.2682E-04 -4.571 0.2892E-01 -1.539 0.1506 0.9988E-02 nontronite-Na 0.9301E-04 -4.031 0.3956E-01 -1.403 0.2060 0.1229E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9533E+00 0.9533E+00 1.0000 -0.021 grossular 0.4667E-01 0.4667E-01 1.0000 -1.331 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6130E+00 0.6130E+00 1.0000 -0.213 daphnite 0.3736E+00 0.3736E+00 1.0000 -0.428 chlorite-Mn 0.1339E-01 0.1339E-01 1.0000 -1.873 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 19.206111 g Volume = 8.092318 cm3 Porosity: -0.6557% V(tot) - V(min): -.52718E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 17.5990000 g log = 1.2455 Original solution: 1000.0103000 g Original solution / Rock added: 56.82 (Water/Rock Ratio), log = 1.7545 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1687E-06 1.0073 0.1788E-06 0.1775E-06 CH4,gas 0.6242E-15 1.0129 0.6651E-15 0.6566E-15 H2,gas 0.2380E-05 1.0006 0.2505E-05 0.2504E-05 H2S,gas 0.1309E-13 0.9959 0.1372E-13 0.1377E-13 S2,gas 0.1068E-35 1.0000 0.1123E-35 0.1123E-35 CO,gas 0.1103E-15 1.0000 0.1160E-15 0.1160E-15 SO3,gas 0.1005E-39 1.0000 0.1058E-39 0.1058E-39 SO2,gas 0.9528E-23 1.0000 0.1002E-22 0.1002E-22 HCl,gas 0.5091E-17 1.0000 0.5355E-17 0.5355E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.15165E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.916 0.14937E+05 -6.748 3 CH4,gas 4.81 -12.37 -17.18 -4.294 0.29329E+05 -15.177 4 H2,gas 8.29 0.69 -7.60 -4.344 0.12979E+05 -5.601 5 H2S,gas -5.94 -21.81 -15.86 -7.931 0.27085E+05 -13.863 6 S2,gas -7.03 -44.98 -37.95 -5.838 0.64798E+05 -35.950 7 CO,gas 3.51 -14.43 -17.94 -5.519 0.30624E+05 -15.936 8 SO3,gas 17.43 -24.55 -41.98 -10.494 0.71672E+05 -39.976 9 SO2,gas 1.14 -23.86 -25.00 -6.666 0.42685E+05 -22.999 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32905E+05 -17.271 11 acmite 7.74 7.43 -0.30 -0.031 0.51654E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.07 -4.48 -0.224 0.76477E+04 20 analcite 3.37 2.99 -0.38 -0.042 0.64150E+03 21 andalusite 5.06 0.39 -4.67 -0.467 0.79704E+04 26 annite 20.21 17.49 -2.72 -0.151 0.46376E+04 27 phlogopite 27.15 24.20 -2.95 -0.164 0.50351E+04 29 anorthite 12.80 9.21 -3.59 -0.276 0.61248E+04 35 aragonite 0.99 -2.97 -3.96 -1.319 0.67576E+04 36 brucite 12.58 8.88 -3.70 -0.740 0.63178E+04 37 calcite 0.83 -2.97 -3.80 -1.268 0.64963E+04 38 carnegieite-low 9.06 6.32 -2.75 -0.392 0.46893E+04 39 carnegieite-high 10.13 6.32 -3.82 -0.545 0.65161E+04 40 carpholite-Mg 8.65 5.95 -2.70 -0.180 0.46148E+04 41 carpholite-Fe 6.78 3.71 -3.07 -0.205 0.52421E+04 42 celadonite 5.40 3.12 -2.28 -0.134 0.38915E+04 43 celadonite-Fe 3.94 0.89 -3.05 -0.179 0.52084E+04 44 chrysotile 23.94 19.98 -3.95 -0.330 0.67520E+04 50 chloritoid-Mg 13.26 9.27 -3.99 -0.266 0.68133E+04 51 chloritoid-Fe 9.24 7.04 -2.20 -0.147 0.37608E+04 52 chloritoid-Mn 11.46 9.17 -2.29 -0.153 0.39176E+04 54 coesite -2.37 -3.32 -0.95 -0.318 0.16288E+04 59 corundum 8.43 3.72 -4.72 -0.429 0.80519E+04 61 cristobalite -2.55 -3.32 -0.77 -0.258 0.13217E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.86 -1.04 -0.173 0.17710E+04 67 diopside 16.22 14.37 -1.85 -0.185 0.31521E+04 68 hedenbergite 14.24 12.13 -2.11 -0.211 0.36025E+04 75 epidote 24.78 24.33 -0.45 -0.022 0.76760E+03 76 clinozoisite 22.92 19.89 -3.04 -0.138 0.51829E+04 77 epidote-Fe 29.94 28.77 -1.17 -0.061 0.19998E+04 78 fayalite 14.08 9.96 -4.12 -0.588 0.70329E+04 79 ferrosilite 11.19 6.64 -4.55 -0.455 0.77706E+04 83 gibbsite 4.10 1.86 -2.24 -0.320 0.38222E+04 84 glaucophane 23.11 19.33 -3.78 -0.102 0.64616E+04 85 glaucophane-Fe 17.42 12.62 -4.80 -0.130 0.81881E+04 87 greenalite 16.19 13.28 -2.92 -0.243 0.49786E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.99 -1.26 -0.126 0.21445E+04 96 julgoldite 70.57 67.10 -3.48 -0.090 0.59353E+04 97 kalsilite 7.62 4.21 -3.41 -0.486 0.58147E+04 98 kaolinite -1.27 -2.93 -1.66 -0.151 0.28271E+04 99 kyanite 4.93 0.39 -4.54 -0.454 0.77472E+04 101 laumontite 2.97 2.56 -0.41 -0.027 0.70092E+03 102 lawsonite 9.68 9.21 -0.47 -0.031 0.79864E+03 103 leucite 4.17 0.89 -3.28 -0.328 0.55939E+04 105 lizardite 23.29 19.98 -3.30 -0.275 0.56423E+04 107 magnetite 20.13 19.24 -0.89 -0.073 0.15256E+04 108 minnesotaite 10.46 6.63 -3.83 -0.225 0.65377E+04 110 magnesioferrite 26.26 21.47 -4.78 -0.390 0.81671E+04 113 margarite 17.45 12.93 -4.52 -0.181 0.77236E+04 120 muscovite 2.68 1.29 -1.39 -0.082 0.23789E+04 121 paragonite 4.34 3.39 -0.95 -0.056 0.16174E+04 122 nepheline 8.38 6.32 -2.06 -0.294 0.35172E+04 128 periclase-Fe 11.64 6.64 -5.00 -1.249 0.85330E+04 134 phlogopite-Na 29.73 26.30 -3.43 -0.191 0.58570E+04 136 prehnite 19.47 18.03 -1.44 -0.085 0.24579E+04 137 prehnite-Fe 22.59 22.47 -0.12 -0.007 0.20487E+03 138 pumpellyite-Fe 46.47 44.55 -1.92 -0.043 0.32721E+04 139 pumpellyite-Mg 49.19 46.79 -2.40 -0.053 0.41064E+04 145 pyroxmangite 7.42 5.45 -1.96 -0.393 0.33551E+04 146 pyrophyllite -6.10 -9.58 -3.48 -0.217 0.59376E+04 147 quartz -2.98 -3.32 -0.34 -0.114 0.58276E+03 152 rhodonite 7.46 5.45 -2.01 -0.402 0.34344E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.39 -4.93 -0.493 0.84126E+04 165 stilpnomelane-Mg 27.60 24.35 -3.24 -0.097 0.55369E+04 171 talc 16.55 13.34 -3.22 -0.189 0.54930E+04 174 tephroite 18.11 14.23 -3.89 -0.555 0.66377E+04 177 topaz-H 4.67 0.39 -4.27 -0.388 0.72962E+04 178 tridymite -2.61 -3.32 -0.71 -0.236 0.12101E+04 187 wairakite 4.06 2.56 -1.49 -0.088 0.25517E+04 188 walstromite 11.53 8.82 -2.71 -0.542 0.46301E+04 189 wollastonite 10.48 8.82 -1.67 -0.333 0.28440E+04 190 pseudo-wollastonite 11.02 8.82 -2.20 -0.441 0.37626E+04 191 zoisite 22.96 19.89 -3.08 -0.140 0.52555E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.86 -4.30 -0.266 0.73467E+04 195 beidellite-K -1.44 -5.99 -4.56 -0.279 0.77795E+04 196 beidellite-Mg -1.71 -6.40 -4.69 -0.290 0.80146E+04 197 beidellite-Na -1.26 -5.30 -4.04 -0.247 0.68983E+04 199 chalcedony -2.79 -3.32 -0.53 -0.176 0.90308E+03 201 montmorillonite-Ca -2.21 -5.26 -3.04 -0.188 0.51951E+04 202 montmorillonite-K -2.16 -5.39 -3.22 -0.197 0.55058E+04 203 montmorillonite-Mg -2.40 -5.80 -3.39 -0.210 0.57941E+04 204 montmorillonite-Na -1.96 -4.69 -2.73 -0.167 0.46626E+04 205 nontronite-Ca 3.28 3.02 -0.26 -0.017 0.44753E+03 206 nontronite-H 2.60 1.01 -1.58 -0.106 0.26999E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11271E+04 224 tobermorite 9.84 6.79 -3.05 -0.832 0.52080E+04 233 boehmite 4.43 1.86 -2.57 -0.428 0.43895E+04 235 ferrous-oxide 9.82 6.64 -3.18 -0.796 0.54341E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.415 0.21233E+04 242 an20ab80 2.08 1.58 -0.50 -0.038 0.85334E+03 243 an25ab75 2.71 2.06 -0.65 -0.050 0.11146E+04 244 an30ab70 3.34 2.53 -0.81 -0.062 0.13842E+04 245 tr.625ac.25prg.125 45.31 40.67 -4.64 -0.125 0.79147E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 17.5990000 g New total amount of reactant added: 17.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8630E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 17.9990000 Water: Moles liquid = 0.5537E+02 kg liquid = 0.9975E+00 Moles total = 0.5528E+02 kg total = 0.9959E+00 Activity = 1.0000 Stoichiometric ionic strength = .5200674E-02 Osmotic coef. = 0.9618 True ionic strength = .9383192E-02 Chg. balance for total moles = 0.8630E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15252E-09 -9.8167 0.13371E-09 -9.8738 0.87668E+00 -0.0572 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13800E-03 -3.8601 0.12059E-03 -3.9187 0.87386E+00 -0.0586 4 SO4-- 0.25550E-04 -4.5926 0.15823E-04 -4.8007 0.61930E+00 -0.2081 5 HCO3- 0.66241E-05 -5.1789 0.57930E-05 -5.2371 0.87454E+00 -0.0582 6 HS- 0.13396E-11 -11.8730 0.11707E-11 -11.9315 0.87393E+00 -0.0585 7 Al+++ 0.49998E-27 -27.3010 0.17273E-27 -27.7626 0.34547E+00 -0.4616 8 H4SiO4 0.47501E-03 -3.3233 0.47501E-03 -3.3233 0.10000E+01 0.0000 9 Ca++ 0.39960E-07 -7.3984 0.24651E-07 -7.6082 0.61688E+00 -0.2098 10 Mg++ 0.21863E-10 -10.6603 0.13454E-10 -10.8712 0.61538E+00 -0.2109 11 Fe++ 0.12724E-12 -12.8954 0.78344E-13 -13.1060 0.61574E+00 -0.2106 12 K+ 0.73040E-04 -4.1364 0.63885E-04 -4.1946 0.87465E+00 -0.0582 13 Na+ 0.92774E-02 -2.0326 0.81065E-02 -2.0912 0.87378E+00 -0.0586 14 Mn++ 0.17263E-10 -10.7629 0.10634E-10 -10.9733 0.61601E+00 -0.2104 15 HPO4-- 0.53332E-06 -6.2730 0.33031E-06 -6.4811 0.61934E+00 -0.2081 16 HSiO3- 0.39664E-02 -2.4016 0.34661E-02 -2.4602 0.87386E+00 -0.0586 17 Ca(HSiO3)+ 0.21884E-08 -8.6599 0.19143E-08 -8.7180 0.87475E+00 -0.0581 18 Mg(HSiO3)+ 0.14864E-11 -11.8279 0.13003E-11 -11.8860 0.87475E+00 -0.0581 19 NaHSiO3,aq 0.44626E-03 -3.3504 0.44626E-03 -3.3504 0.10000E+01 0.0000 20 AlO+ 0.14258E-14 -14.8459 0.12472E-14 -14.9041 0.87475E+00 -0.0581 22 HAlO2,aq 0.18666E-08 -8.7290 0.18666E-08 -8.7290 0.10000E+01 0.0000 23 AlO2- 0.35705E-04 -4.4473 0.31171E-04 -4.5062 0.87301E+00 -0.0590 24 CH4,aq 0.42126E-18 -18.3754 0.42059E-18 -18.3761 0.99840E+00 -0.0007 29 CO,aq 0.73466E-19 -19.1339 0.73466E-19 -19.1339 0.10000E+01 0.0000 30 CO2,aq 0.15642E-08 -8.8057 0.15617E-08 -8.8064 0.99840E+00 -0.0007 31 CO3-2 0.64757E-05 -5.1887 0.40058E-05 -5.3973 0.61859E+00 -0.2086 32 CaCO3,aq 0.12094E-08 -8.9174 0.12094E-08 -8.9174 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41133E-11 -11.3858 0.35982E-11 -11.4439 0.87475E+00 -0.0581 34 CaCl+ 0.54151E-11 -11.2664 0.47369E-11 -11.3245 0.87475E+00 -0.0581 35 CaCl2,aq 0.13300E-15 -15.8761 0.13300E-15 -15.8761 0.10000E+01 0.0000 36 CaOH+ 0.14861E-07 -7.8280 0.13000E-07 -7.8861 0.87475E+00 -0.0581 37 CaSO4,aq 0.12153E-09 -9.9153 0.12153E-09 -9.9153 0.10000E+01 0.0000 38 HCl,aq 0.30329E-14 -14.5181 0.30329E-14 -14.5181 0.10000E+01 0.0000 43 FeCl+ 0.16822E-16 -16.7741 0.14715E-16 -16.8322 0.87475E+00 -0.0581 46 FeO,aq 0.17328E-09 -9.7612 0.17328E-09 -9.7612 0.10000E+01 0.0000 47 FeOH+ 0.22206E-10 -10.6535 0.19425E-10 -10.7116 0.87475E+00 -0.0581 48 HFeO2- 0.15952E-07 -7.7972 0.13940E-07 -7.8558 0.87386E+00 -0.0586 49 FeO+ 0.12644E-14 -14.8981 0.11061E-14 -14.9562 0.87475E+00 -0.0581 51 FeO2- 0.13914E-07 -7.8565 0.12159E-07 -7.9151 0.87386E+00 -0.0586 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.18294E-08 -8.7377 0.18265E-08 -8.7384 0.99840E+00 -0.0007 54 KCl,aq 0.13641E-09 -9.8652 0.13641E-09 -9.8652 0.10000E+01 0.0000 55 KHSO4,aq 0.36169E-18 -18.4417 0.36169E-18 -18.4417 0.10000E+01 0.0000 56 KOH,aq 0.20829E-06 -6.6813 0.20829E-06 -6.6813 0.10000E+01 0.0000 57 KSO4- 0.17822E-07 -7.7491 0.15574E-07 -7.8076 0.87386E+00 -0.0586 58 MgCO3,aq 0.16494E-12 -12.7827 0.16494E-12 -12.7827 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22893E-14 -14.6403 0.20025E-14 -14.6984 0.87475E+00 -0.0581 60 MgCl+ 0.26830E-14 -14.5714 0.23470E-14 -14.6295 0.87475E+00 -0.0581 61 MgOH+ 0.44934E-10 -10.3474 0.39306E-10 -10.4055 0.87475E+00 -0.0581 63 MnO,aq 0.62789E-09 -9.2021 0.62789E-09 -9.2021 0.10000E+01 0.0000 64 MnOH+ 0.28000E-09 -9.5528 0.24493E-09 -9.6110 0.87475E+00 -0.0581 65 MnO2-2 0.19635E-11 -11.7070 0.12146E-11 -11.9156 0.61859E+00 -0.2086 66 HMnO2- 0.40265E-10 -10.3951 0.35186E-10 -10.4536 0.87386E+00 -0.0586 69 MnCl+ 0.88724E-14 -14.0520 0.77612E-14 -14.1101 0.87475E+00 -0.0581 70 MnSO4,aq 0.47686E-13 -13.3216 0.47686E-13 -13.3216 0.10000E+01 0.0000 71 NaCl,aq 0.31920E-06 -6.4959 0.31920E-06 -6.4959 0.10000E+01 0.0000 72 NaOH,aq 0.26640E-04 -4.5745 0.26640E-04 -4.5745 0.10000E+01 0.0000 74 OH- 0.51386E-02 -2.2892 0.44861E-02 -2.3481 0.87301E+00 -0.0590 79 HPO3-2 0.30805E-17 -17.5114 0.19055E-17 -17.7200 0.61859E+00 -0.2086 82 H3PO4,aq 0.38018E-16 -16.4200 0.38018E-16 -16.4200 0.10000E+01 0.0000 83 H2PO4- 0.88563E-09 -9.0527 0.77430E-09 -9.1111 0.87430E+00 -0.0583 84 PO4-3 0.60829E-08 -8.2159 0.21574E-08 -8.6661 0.35466E+00 -0.4502 87 H2P2O7-2 0.75855E-19 -19.1200 0.46924E-19 -19.3286 0.61859E+00 -0.2086 88 HP2O7-3 0.20821E-15 -15.6815 0.71961E-16 -16.1429 0.34561E+00 -0.4614 89 P2O7-4 0.85356E-15 -15.0688 0.13277E-15 -15.8769 0.15555E+00 -0.8081 90 H2S,aq 0.47109E-15 -15.3269 0.47033E-15 -15.3276 0.99840E+00 -0.0007 97 SO3-2 0.63213E-14 -14.1992 0.39406E-14 -14.4044 0.62338E+00 -0.2052 98 HSO3- 0.35286E-16 -16.4524 0.30835E-16 -16.5110 0.87386E+00 -0.0586 99 HSO4- 0.22430E-11 -11.6492 0.19631E-11 -11.7071 0.87520E+00 -0.0579 Charge balance for all species = 0.8524E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1525178E-09 -.9727584E-02 -.9797876E+01 0.0000 2 H2O 0.1000000E+01 0.5550907E+02 0.9993043E+06 0.0000 3 Cl- 0.1379988E-03 0.1383181E-03 0.4900319E+01 5.9552 4 SO4-- 0.2555010E-04 0.2556935E-04 0.2454493E+01 14.9470 5 HCO3- 0.6624083E-05 0.1310258E-04 0.7989165E+00 4.6367 6 HS- 0.1339629E-11 -.1306048E-08 -.4316304E-04 -2.0577 7 Al+++ 0.4999793E-27 0.3570706E-04 0.9627477E+00 1.8589 8 H4SiO4 0.4750080E-03 0.4887688E-02 0.4694494E+03 -3.3233 9 Ca++ 0.3995991E-07 0.5834974E-07 0.2336884E-02 12.1395 10 Mg++ 0.2186262E-10 0.6845310E-10 0.1663053E-05 8.8765 11 Fe++ 0.1272359E-12 0.3026527E-07 0.1689027E-02 6.6417 12 K+ 0.7304024E-04 0.7326649E-04 0.2862837E+01 5.6792 13 Na+ 0.9277437E-02 0.9750655E-02 0.2240068E+03 7.7827 14 Mn++ 0.1726274E-10 0.9674427E-09 0.5311172E-04 8.7744 15 HPO4-- 0.5333158E-06 0.5402843E-06 0.5181922E-01 13.2666 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2980237E+00 -.9703396E-02 -.2883203E+00 0.0000000E+00 2 H2O 0.5528263E+02 0.5537105E+02 -.8842459E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5243181E-03 0.2550577E-04 0.4988123E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4988136E-03 -.1302801E-08 -.4988123E-03 0.0000000E+00 7 Al+++ 0.5869009E-01 0.3561828E-04 0.5865447E-01 0.0000000E+00 8 H4SiO4 0.1874197E+00 0.4875535E-02 0.1825441E+00 0.0000000E+00 9 Ca++ 0.2071589E-01 0.5820465E-07 0.2071583E-01 0.0000000E+00 10 Mg++ 0.1428492E-01 0.6828289E-10 0.1428492E-01 0.0000000E+00 11 Fe++ 0.1283344E-01 0.3019002E-07 0.1283341E-01 0.0000000E+00 12 K+ 0.3821444E-02 0.7308431E-04 0.3748359E-02 0.0000000E+00 13 Na+ 0.2275320E-01 0.9726410E-02 0.1302679E-01 0.0000000E+00 14 Mn++ 0.3120774E-03 0.9650371E-09 0.3120764E-03 0.0000000E+00 15 HPO4-- 0.1065105E-03 0.5389409E-06 0.1059715E-03 0.0000000E+00 Chg. balance for solid moles: 0.7394E-16 Mass of aqueous solution: 0.998221E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 17.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1298E-01 -1.887 3.404 0.532 17.33 1.307 andradite 0.1382E-02 -2.860 0.7022 -0.154 3.575 0.1824 grossular 0.6765E-04 -4.170 0.3047E-01 -1.516 0.1551 0.8479E-02 apatite-OH 0.3532E-04 -4.452 0.1774E-01 -1.751 0.9033E-01 0.5638E-02 clinochlore 0.2857E-02 -2.544 1.588 0.201 8.084 0.6040 daphnite 0.1741E-02 -2.759 1.242 0.094 6.325 0.3765 chlorite-Mn 0.6242E-04 -4.205 0.4425E-01 -1.354 0.2253 0.1410E-01 hematite 0.4738E-03 -3.324 0.7567E-01 -1.121 0.3852 0.1434E-01 microcline 0.3735E-02 -2.428 1.040 0.017 5.292 0.4061 stilbite 0.1619E-01 -1.791 11.41 1.057 58.09 5.322 stilpnomelane-Fe 0.2743E-04 -4.562 0.2957E-01 -1.529 0.1506 0.1022E-01 nontronite-Na 0.1396E-03 -3.855 0.5938E-01 -1.226 0.3023 0.1845E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9533E+00 0.9533E+00 1.0000 -0.021 grossular 0.4667E-01 0.4667E-01 1.0000 -1.331 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6130E+00 0.6130E+00 1.0000 -0.213 daphnite 0.3736E+00 0.3736E+00 1.0000 -0.428 chlorite-Mn 0.1339E-01 0.1339E-01 1.0000 -1.873 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 19.642957 g Volume = 8.268697 cm3 Porosity: -0.8427% V(tot) - V(min): -.69097E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 17.9990000 g log = 1.2552 Original solution: 1000.0103000 g Original solution / Rock added: 55.56 (Water/Rock Ratio), log = 1.7448 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1687E-06 1.0073 0.1788E-06 0.1775E-06 CH4,gas 0.6242E-15 1.0129 0.6651E-15 0.6566E-15 H2,gas 0.2380E-05 1.0006 0.2505E-05 0.2504E-05 H2S,gas 0.1309E-13 0.9959 0.1372E-13 0.1377E-13 S2,gas 0.1068E-35 1.0000 0.1123E-35 0.1123E-35 CO,gas 0.1103E-15 1.0000 0.1160E-15 0.1160E-15 SO3,gas 0.1005E-39 1.0000 0.1058E-39 0.1058E-39 SO2,gas 0.9528E-23 1.0000 0.1002E-22 0.1002E-22 HCl,gas 0.5091E-17 1.0000 0.5355E-17 0.5355E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 90 hematite 12.60 12.60 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.68244E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.916 0.14936E+05 -6.748 3 CH4,gas 4.81 -12.37 -17.18 -4.294 0.29329E+05 -15.177 4 H2,gas 8.29 0.69 -7.60 -4.344 0.12979E+05 -5.601 5 H2S,gas -5.94 -21.81 -15.86 -7.931 0.27085E+05 -13.863 6 S2,gas -7.03 -44.98 -37.95 -5.838 0.64798E+05 -35.950 7 CO,gas 3.51 -14.43 -17.94 -5.519 0.30624E+05 -15.936 8 SO3,gas 17.43 -24.55 -41.98 -10.494 0.71672E+05 -39.976 9 SO2,gas 1.14 -23.86 -25.00 -6.666 0.42685E+05 -22.999 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32905E+05 -17.271 11 acmite 7.74 7.43 -0.30 -0.031 0.51654E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.07 -4.48 -0.224 0.76477E+04 20 analcite 3.37 2.99 -0.38 -0.042 0.64150E+03 21 andalusite 5.06 0.39 -4.67 -0.467 0.79704E+04 26 annite 20.21 17.49 -2.72 -0.151 0.46376E+04 27 phlogopite 27.15 24.20 -2.95 -0.164 0.50351E+04 29 anorthite 12.80 9.21 -3.59 -0.276 0.61248E+04 35 aragonite 0.99 -2.97 -3.96 -1.319 0.67576E+04 36 brucite 12.58 8.88 -3.70 -0.740 0.63178E+04 37 calcite 0.83 -2.97 -3.80 -1.268 0.64963E+04 38 carnegieite-low 9.06 6.32 -2.75 -0.392 0.46893E+04 39 carnegieite-high 10.13 6.32 -3.82 -0.545 0.65161E+04 40 carpholite-Mg 8.65 5.95 -2.70 -0.180 0.46148E+04 41 carpholite-Fe 6.78 3.71 -3.07 -0.205 0.52421E+04 42 celadonite 5.40 3.12 -2.28 -0.134 0.38915E+04 43 celadonite-Fe 3.94 0.89 -3.05 -0.179 0.52084E+04 44 chrysotile 23.94 19.98 -3.95 -0.330 0.67520E+04 50 chloritoid-Mg 13.26 9.27 -3.99 -0.266 0.68133E+04 51 chloritoid-Fe 9.24 7.04 -2.20 -0.147 0.37608E+04 52 chloritoid-Mn 11.46 9.17 -2.29 -0.153 0.39176E+04 54 coesite -2.37 -3.32 -0.95 -0.318 0.16288E+04 59 corundum 8.43 3.72 -4.72 -0.429 0.80519E+04 61 cristobalite -2.55 -3.32 -0.77 -0.258 0.13217E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.86 -1.04 -0.173 0.17710E+04 67 diopside 16.22 14.37 -1.85 -0.185 0.31521E+04 68 hedenbergite 14.24 12.13 -2.11 -0.211 0.36025E+04 75 epidote 24.78 24.33 -0.45 -0.022 0.76760E+03 76 clinozoisite 22.92 19.89 -3.04 -0.138 0.51829E+04 77 epidote-Fe 29.94 28.77 -1.17 -0.061 0.19998E+04 78 fayalite 14.08 9.96 -4.12 -0.588 0.70329E+04 79 ferrosilite 11.19 6.64 -4.55 -0.455 0.77706E+04 83 gibbsite 4.10 1.86 -2.24 -0.320 0.38222E+04 84 glaucophane 23.11 19.33 -3.78 -0.102 0.64616E+04 85 glaucophane-Fe 17.42 12.62 -4.80 -0.130 0.81881E+04 87 greenalite 16.19 13.28 -2.92 -0.243 0.49786E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.99 -1.26 -0.126 0.21445E+04 96 julgoldite 70.57 67.10 -3.48 -0.090 0.59353E+04 97 kalsilite 7.62 4.21 -3.41 -0.486 0.58147E+04 98 kaolinite -1.27 -2.93 -1.66 -0.151 0.28271E+04 99 kyanite 4.93 0.39 -4.54 -0.454 0.77472E+04 101 laumontite 2.97 2.56 -0.41 -0.027 0.70092E+03 102 lawsonite 9.68 9.21 -0.47 -0.031 0.79864E+03 103 leucite 4.17 0.89 -3.28 -0.328 0.55939E+04 105 lizardite 23.29 19.98 -3.30 -0.275 0.56423E+04 107 magnetite 20.13 19.24 -0.89 -0.073 0.15256E+04 108 minnesotaite 10.46 6.63 -3.83 -0.225 0.65377E+04 110 magnesioferrite 26.26 21.47 -4.78 -0.390 0.81671E+04 113 margarite 17.45 12.93 -4.52 -0.181 0.77236E+04 120 muscovite 2.68 1.29 -1.39 -0.082 0.23789E+04 121 paragonite 4.34 3.39 -0.95 -0.056 0.16174E+04 122 nepheline 8.38 6.32 -2.06 -0.294 0.35172E+04 128 periclase-Fe 11.64 6.64 -5.00 -1.249 0.85330E+04 134 phlogopite-Na 29.73 26.30 -3.43 -0.191 0.58570E+04 136 prehnite 19.47 18.03 -1.44 -0.085 0.24579E+04 137 prehnite-Fe 22.59 22.47 -0.12 -0.007 0.20487E+03 138 pumpellyite-Fe 46.47 44.55 -1.92 -0.043 0.32721E+04 139 pumpellyite-Mg 49.19 46.79 -2.40 -0.053 0.41064E+04 145 pyroxmangite 7.42 5.45 -1.96 -0.393 0.33551E+04 146 pyrophyllite -6.10 -9.58 -3.48 -0.217 0.59376E+04 147 quartz -2.98 -3.32 -0.34 -0.114 0.58276E+03 152 rhodonite 7.46 5.45 -2.01 -0.402 0.34344E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.39 -4.93 -0.493 0.84126E+04 165 stilpnomelane-Mg 27.60 24.35 -3.24 -0.097 0.55369E+04 171 talc 16.55 13.34 -3.22 -0.189 0.54930E+04 174 tephroite 18.11 14.23 -3.89 -0.555 0.66377E+04 177 topaz-H 4.67 0.39 -4.27 -0.388 0.72962E+04 178 tridymite -2.61 -3.32 -0.71 -0.236 0.12101E+04 187 wairakite 4.06 2.56 -1.49 -0.088 0.25517E+04 188 walstromite 11.53 8.82 -2.71 -0.542 0.46301E+04 189 wollastonite 10.48 8.82 -1.67 -0.333 0.28440E+04 190 pseudo-wollastonite 11.02 8.82 -2.20 -0.441 0.37626E+04 191 zoisite 22.96 19.89 -3.08 -0.140 0.52555E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.86 -4.30 -0.266 0.73467E+04 195 beidellite-K -1.44 -5.99 -4.56 -0.279 0.77795E+04 196 beidellite-Mg -1.71 -6.40 -4.69 -0.290 0.80146E+04 197 beidellite-Na -1.26 -5.30 -4.04 -0.247 0.68983E+04 199 chalcedony -2.79 -3.32 -0.53 -0.176 0.90308E+03 201 montmorillonite-Ca -2.21 -5.26 -3.04 -0.188 0.51951E+04 202 montmorillonite-K -2.16 -5.39 -3.22 -0.197 0.55058E+04 203 montmorillonite-Mg -2.40 -5.80 -3.39 -0.210 0.57941E+04 204 montmorillonite-Na -1.96 -4.69 -2.73 -0.167 0.46626E+04 205 nontronite-Ca 3.28 3.02 -0.26 -0.017 0.44753E+03 206 nontronite-H 2.60 1.01 -1.58 -0.106 0.26999E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11271E+04 224 tobermorite 9.84 6.79 -3.05 -0.832 0.52080E+04 233 boehmite 4.43 1.86 -2.57 -0.428 0.43895E+04 235 ferrous-oxide 9.82 6.64 -3.18 -0.796 0.54341E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.415 0.21233E+04 242 an20ab80 2.08 1.58 -0.50 -0.038 0.85334E+03 243 an25ab75 2.71 2.06 -0.65 -0.050 0.11146E+04 244 an30ab70 3.34 2.53 -0.81 -0.062 0.13842E+04 245 tr.625ac.25prg.125 45.31 40.67 -4.64 -0.125 0.79147E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 17.9990000 g New total amount of reactant added: 18.3990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8628E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 18.3990000 Water: Moles liquid = 0.5537E+02 kg liquid = 0.9975E+00 Moles total = 0.5528E+02 kg total = 0.9958E+00 Activity = 1.0000 Stoichiometric ionic strength = .5200681E-02 Osmotic coef. = 0.9618 True ionic strength = .9383198E-02 Chg. balance for total moles = 0.8628E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15252E-09 -9.8167 0.13371E-09 -9.8738 0.87668E+00 -0.0572 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13800E-03 -3.8601 0.12060E-03 -3.9187 0.87386E+00 -0.0586 4 SO4-- 0.25551E-04 -4.5926 0.15824E-04 -4.8007 0.61930E+00 -0.2081 5 HCO3- 0.66243E-05 -5.1789 0.57932E-05 -5.2371 0.87454E+00 -0.0582 6 HS- 0.13397E-11 -11.8730 0.11708E-11 -11.9315 0.87393E+00 -0.0585 7 Al+++ 0.49998E-27 -27.3010 0.17273E-27 -27.7626 0.34547E+00 -0.4616 8 H4SiO4 0.47501E-03 -3.3233 0.47501E-03 -3.3233 0.10000E+01 0.0000 9 Ca++ 0.39960E-07 -7.3984 0.24651E-07 -7.6082 0.61688E+00 -0.2098 10 Mg++ 0.21863E-10 -10.6603 0.13454E-10 -10.8712 0.61538E+00 -0.2109 11 Fe++ 0.12724E-12 -12.8954 0.78344E-13 -13.1060 0.61574E+00 -0.2106 12 K+ 0.73040E-04 -4.1364 0.63885E-04 -4.1946 0.87465E+00 -0.0582 13 Na+ 0.92774E-02 -2.0326 0.81065E-02 -2.0912 0.87378E+00 -0.0586 14 Mn++ 0.17263E-10 -10.7629 0.10634E-10 -10.9733 0.61601E+00 -0.2104 15 HPO4-- 0.53332E-06 -6.2730 0.33031E-06 -6.4811 0.61934E+00 -0.2081 16 HSiO3- 0.39664E-02 -2.4016 0.34661E-02 -2.4602 0.87386E+00 -0.0586 17 Ca(HSiO3)+ 0.21884E-08 -8.6599 0.19143E-08 -8.7180 0.87475E+00 -0.0581 18 Mg(HSiO3)+ 0.14864E-11 -11.8279 0.13003E-11 -11.8860 0.87475E+00 -0.0581 19 NaHSiO3,aq 0.44626E-03 -3.3504 0.44626E-03 -3.3504 0.10000E+01 0.0000 20 AlO+ 0.14258E-14 -14.8459 0.12472E-14 -14.9041 0.87475E+00 -0.0581 22 HAlO2,aq 0.18666E-08 -8.7290 0.18666E-08 -8.7290 0.10000E+01 0.0000 23 AlO2- 0.35705E-04 -4.4473 0.31171E-04 -4.5062 0.87301E+00 -0.0590 24 CH4,aq 0.42128E-18 -18.3754 0.42060E-18 -18.3761 0.99840E+00 -0.0007 29 CO,aq 0.73469E-19 -19.1339 0.73469E-19 -19.1339 0.10000E+01 0.0000 30 CO2,aq 0.15643E-08 -8.8057 0.15618E-08 -8.8064 0.99840E+00 -0.0007 31 CO3-2 0.64760E-05 -5.1887 0.40060E-05 -5.3973 0.61859E+00 -0.2086 32 CaCO3,aq 0.12095E-08 -8.9174 0.12095E-08 -8.9174 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41135E-11 -11.3858 0.35983E-11 -11.4439 0.87475E+00 -0.0581 34 CaCl+ 0.54153E-11 -11.2664 0.47371E-11 -11.3245 0.87475E+00 -0.0581 35 CaCl2,aq 0.13301E-15 -15.8761 0.13301E-15 -15.8761 0.10000E+01 0.0000 36 CaOH+ 0.14861E-07 -7.8280 0.13000E-07 -7.8861 0.87475E+00 -0.0581 37 CaSO4,aq 0.12154E-09 -9.9153 0.12154E-09 -9.9153 0.10000E+01 0.0000 38 HCl,aq 0.30330E-14 -14.5181 0.30330E-14 -14.5181 0.10000E+01 0.0000 43 FeCl+ 0.16822E-16 -16.7741 0.14715E-16 -16.8322 0.87475E+00 -0.0581 46 FeO,aq 0.17328E-09 -9.7612 0.17328E-09 -9.7612 0.10000E+01 0.0000 47 FeOH+ 0.22206E-10 -10.6535 0.19425E-10 -10.7116 0.87475E+00 -0.0581 48 HFeO2- 0.15952E-07 -7.7972 0.13940E-07 -7.8558 0.87386E+00 -0.0586 49 FeO+ 0.12644E-14 -14.8981 0.11061E-14 -14.9562 0.87475E+00 -0.0581 51 FeO2- 0.13914E-07 -7.8565 0.12159E-07 -7.9151 0.87386E+00 -0.0586 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.18294E-08 -8.7377 0.18265E-08 -8.7384 0.99840E+00 -0.0007 54 KCl,aq 0.13642E-09 -9.8651 0.13642E-09 -9.8651 0.10000E+01 0.0000 55 KHSO4,aq 0.36170E-18 -18.4416 0.36170E-18 -18.4416 0.10000E+01 0.0000 56 KOH,aq 0.20829E-06 -6.6813 0.20829E-06 -6.6813 0.10000E+01 0.0000 57 KSO4- 0.17822E-07 -7.7490 0.15574E-07 -7.8076 0.87386E+00 -0.0586 58 MgCO3,aq 0.16494E-12 -12.7827 0.16494E-12 -12.7827 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22894E-14 -14.6403 0.20026E-14 -14.6984 0.87475E+00 -0.0581 60 MgCl+ 0.26831E-14 -14.5714 0.23471E-14 -14.6295 0.87475E+00 -0.0581 61 MgOH+ 0.44934E-10 -10.3474 0.39306E-10 -10.4055 0.87475E+00 -0.0581 63 MnO,aq 0.62789E-09 -9.2021 0.62789E-09 -9.2021 0.10000E+01 0.0000 64 MnOH+ 0.28000E-09 -9.5528 0.24493E-09 -9.6110 0.87475E+00 -0.0581 65 MnO2-2 0.19635E-11 -11.7070 0.12146E-11 -11.9156 0.61859E+00 -0.2086 66 HMnO2- 0.40265E-10 -10.3951 0.35186E-10 -10.4536 0.87386E+00 -0.0586 69 MnCl+ 0.88728E-14 -14.0519 0.77615E-14 -14.1101 0.87475E+00 -0.0581 70 MnSO4,aq 0.47688E-13 -13.3216 0.47688E-13 -13.3216 0.10000E+01 0.0000 71 NaCl,aq 0.31921E-06 -6.4959 0.31921E-06 -6.4959 0.10000E+01 0.0000 72 NaOH,aq 0.26640E-04 -4.5745 0.26640E-04 -4.5745 0.10000E+01 0.0000 74 OH- 0.51386E-02 -2.2892 0.44861E-02 -2.3481 0.87301E+00 -0.0590 79 HPO3-2 0.30804E-17 -17.5114 0.19055E-17 -17.7200 0.61859E+00 -0.2086 82 H3PO4,aq 0.38018E-16 -16.4200 0.38018E-16 -16.4200 0.10000E+01 0.0000 83 H2PO4- 0.88563E-09 -9.0527 0.77430E-09 -9.1111 0.87430E+00 -0.0583 84 PO4-3 0.60829E-08 -8.2159 0.21574E-08 -8.6661 0.35466E+00 -0.4502 87 H2P2O7-2 0.75855E-19 -19.1200 0.46923E-19 -19.3286 0.61859E+00 -0.2086 88 HP2O7-3 0.20821E-15 -15.6815 0.71960E-16 -16.1429 0.34561E+00 -0.4614 89 P2O7-4 0.85356E-15 -15.0688 0.13277E-15 -15.8769 0.15555E+00 -0.8081 90 H2S,aq 0.47110E-15 -15.3269 0.47035E-15 -15.3276 0.99840E+00 -0.0007 97 SO3-2 0.63216E-14 -14.1992 0.39407E-14 -14.4044 0.62338E+00 -0.2052 98 HSO3- 0.35287E-16 -16.4524 0.30836E-16 -16.5109 0.87386E+00 -0.0586 99 HSO4- 0.22431E-11 -11.6492 0.19632E-11 -11.7070 0.87520E+00 -0.0579 Charge balance for all species = 0.8531E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1525178E-09 -.9727580E-02 -.9797872E+01 0.0000 2 H2O 0.1000000E+01 0.5550907E+02 0.9993043E+06 0.0000 3 Cl- 0.1380043E-03 0.1383237E-03 0.4900515E+01 5.9552 4 SO4-- 0.2555112E-04 0.2557038E-04 0.2454592E+01 14.9470 5 HCO3- 0.6624350E-05 0.1310311E-04 0.7989485E+00 4.6368 6 HS- 0.1339683E-11 -.1306048E-08 -.4316301E-04 -2.0577 7 Al+++ 0.4999801E-27 0.3570705E-04 0.9627473E+00 1.8589 8 H4SiO4 0.4750080E-03 0.4887687E-02 0.4694492E+03 -3.3233 9 Ca++ 0.3995996E-07 0.5834984E-07 0.2336889E-02 12.1395 10 Mg++ 0.2186264E-10 0.6845315E-10 0.1663054E-05 8.8765 11 Fe++ 0.1272360E-12 0.3026526E-07 0.1689027E-02 6.6417 12 K+ 0.7304028E-04 0.7326653E-04 0.2862838E+01 5.6792 13 Na+ 0.9277441E-02 0.9750660E-02 0.2240069E+03 7.7827 14 Mn++ 0.1726276E-10 0.9674429E-09 0.5311173E-04 8.7744 15 HPO4-- 0.5333154E-06 0.5402839E-06 0.5181918E-01 13.2666 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3046471E+00 -.9703003E-02 -.2949441E+00 0.0000000E+00 2 H2O 0.5527761E+02 0.5536883E+02 -.9121526E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5354035E-03 0.2550577E-04 0.5098977E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5098990E-03 -.1302748E-08 -.5098977E-03 0.0000000E+00 7 Al+++ 0.5999438E-01 0.3561683E-04 0.5995877E-01 0.0000000E+00 8 H4SiO4 0.1915848E+00 0.4875337E-02 0.1867095E+00 0.0000000E+00 9 Ca++ 0.2117595E-01 0.5820242E-07 0.2117589E-01 0.0000000E+00 10 Mg++ 0.1460238E-01 0.6828020E-10 0.1460238E-01 0.0000000E+00 11 Fe++ 0.1311865E-01 0.3018879E-07 0.1311861E-01 0.0000000E+00 12 K+ 0.3906369E-02 0.7308141E-04 0.3833288E-02 0.0000000E+00 13 Na+ 0.2325530E-01 0.9726024E-02 0.1352927E-01 0.0000000E+00 14 Mn++ 0.3190128E-03 0.9649986E-09 0.3190119E-03 0.0000000E+00 15 HPO4-- 0.1088775E-03 0.5389188E-06 0.1083386E-03 0.0000000E+00 Chg. balance for solid moles: -.3713E-16 Mass of aqueous solution: 0.998180E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 18.3990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1347E-01 -1.871 3.532 0.548 17.59 1.356 andradite 0.1447E-02 -2.840 0.7353 -0.134 3.662 0.1910 grossular 0.7084E-04 -4.150 0.3191E-01 -1.496 0.1589 0.8878E-02 apatite-OH 0.3611E-04 -4.442 0.1814E-01 -1.741 0.9034E-01 0.5764E-02 clinochlore 0.2920E-02 -2.535 1.623 0.210 8.084 0.6175 daphnite 0.1780E-02 -2.750 1.270 0.104 6.324 0.3848 chlorite-Mn 0.6380E-04 -4.195 0.4523E-01 -1.345 0.2253 0.1441E-01 hematite 0.4064E-03 -3.391 0.6491E-01 -1.188 0.3233 0.1230E-01 microcline 0.3819E-02 -2.418 1.063 0.027 5.294 0.4153 stilbite 0.1644E-01 -1.784 11.59 1.064 57.71 5.404 stilpnomelane-Fe 0.2804E-04 -4.552 0.3023E-01 -1.520 0.1505 0.1044E-01 nontronite-Na 0.1862E-03 -3.730 0.7920E-01 -1.101 0.3944 0.2460E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9533E+00 0.9533E+00 1.0000 -0.021 grossular 0.4667E-01 0.4667E-01 1.0000 -1.331 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6130E+00 0.6130E+00 1.0000 -0.213 daphnite 0.3736E+00 0.3736E+00 1.0000 -0.428 chlorite-Mn 0.1339E-01 0.1339E-01 1.0000 -1.873 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 20.079804 g Volume = 8.445077 cm3 Porosity: -1.0225% V(tot) - V(min): -.85477E-01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 18.3990000 g log = 1.2648 Original solution: 1000.0103000 g Original solution / Rock added: 54.35 (Water/Rock Ratio), log = 1.7352 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1687E-06 1.0073 0.1788E-06 0.1775E-06 CH4,gas 0.6242E-15 1.0129 0.6651E-15 0.6566E-15 H2,gas 0.2380E-05 1.0006 0.2505E-05 0.2504E-05 H2S,gas 0.1309E-13 0.9959 0.1372E-13 0.1377E-13 S2,gas 0.1068E-35 1.0000 0.1123E-35 0.1123E-35 CO,gas 0.1103E-15 1.0000 0.1160E-15 0.1160E-15 SO3,gas 0.1005E-39 1.0000 0.1058E-39 0.1058E-39 SO2,gas 0.9528E-23 1.0000 0.1002E-22 0.1002E-22 HCl,gas 0.5091E-17 1.0000 0.5355E-17 0.5355E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 0.22748E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.916 0.14936E+05 -6.748 3 CH4,gas 4.81 -12.37 -17.18 -4.294 0.29329E+05 -15.177 4 H2,gas 8.29 0.69 -7.60 -4.344 0.12979E+05 -5.601 5 H2S,gas -5.94 -21.81 -15.86 -7.931 0.27085E+05 -13.863 6 S2,gas -7.03 -44.98 -37.95 -5.838 0.64798E+05 -35.950 7 CO,gas 3.51 -14.43 -17.94 -5.519 0.30624E+05 -15.936 8 SO3,gas 17.43 -24.55 -41.98 -10.494 0.71672E+05 -39.976 9 SO2,gas 1.14 -23.86 -25.00 -6.666 0.42685E+05 -22.999 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32905E+05 -17.271 11 acmite 7.74 7.43 -0.30 -0.031 0.51654E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.07 -4.48 -0.224 0.76477E+04 20 analcite 3.37 2.99 -0.38 -0.042 0.64150E+03 21 andalusite 5.06 0.39 -4.67 -0.467 0.79704E+04 26 annite 20.21 17.49 -2.72 -0.151 0.46376E+04 27 phlogopite 27.15 24.20 -2.95 -0.164 0.50351E+04 29 anorthite 12.80 9.21 -3.59 -0.276 0.61248E+04 35 aragonite 0.99 -2.97 -3.96 -1.319 0.67576E+04 36 brucite 12.58 8.88 -3.70 -0.740 0.63178E+04 37 calcite 0.83 -2.97 -3.80 -1.268 0.64962E+04 38 carnegieite-low 9.06 6.32 -2.75 -0.392 0.46893E+04 39 carnegieite-high 10.13 6.32 -3.82 -0.545 0.65161E+04 40 carpholite-Mg 8.65 5.95 -2.70 -0.180 0.46148E+04 41 carpholite-Fe 6.78 3.71 -3.07 -0.205 0.52421E+04 42 celadonite 5.40 3.12 -2.28 -0.134 0.38915E+04 43 celadonite-Fe 3.94 0.89 -3.05 -0.179 0.52084E+04 44 chrysotile 23.94 19.98 -3.95 -0.330 0.67520E+04 50 chloritoid-Mg 13.26 9.27 -3.99 -0.266 0.68133E+04 51 chloritoid-Fe 9.24 7.04 -2.20 -0.147 0.37608E+04 52 chloritoid-Mn 11.46 9.17 -2.29 -0.153 0.39176E+04 54 coesite -2.37 -3.32 -0.95 -0.318 0.16288E+04 59 corundum 8.43 3.72 -4.72 -0.429 0.80519E+04 61 cristobalite -2.55 -3.32 -0.77 -0.258 0.13217E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.86 -1.04 -0.173 0.17710E+04 67 diopside 16.22 14.37 -1.85 -0.185 0.31521E+04 68 hedenbergite 14.24 12.13 -2.11 -0.211 0.36025E+04 75 epidote 24.78 24.33 -0.45 -0.022 0.76760E+03 76 clinozoisite 22.92 19.89 -3.04 -0.138 0.51829E+04 77 epidote-Fe 29.94 28.77 -1.17 -0.061 0.19998E+04 78 fayalite 14.08 9.96 -4.12 -0.588 0.70329E+04 79 ferrosilite 11.19 6.64 -4.55 -0.455 0.77706E+04 83 gibbsite 4.10 1.86 -2.24 -0.320 0.38222E+04 84 glaucophane 23.11 19.33 -3.78 -0.102 0.64616E+04 85 glaucophane-Fe 17.42 12.62 -4.80 -0.130 0.81881E+04 87 greenalite 16.19 13.28 -2.92 -0.243 0.49786E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.99 -1.26 -0.126 0.21445E+04 96 julgoldite 70.57 67.10 -3.48 -0.090 0.59353E+04 97 kalsilite 7.62 4.21 -3.41 -0.486 0.58147E+04 98 kaolinite -1.27 -2.93 -1.66 -0.151 0.28271E+04 99 kyanite 4.93 0.39 -4.54 -0.454 0.77472E+04 101 laumontite 2.97 2.56 -0.41 -0.027 0.70092E+03 102 lawsonite 9.68 9.21 -0.47 -0.031 0.79864E+03 103 leucite 4.17 0.89 -3.28 -0.328 0.55939E+04 105 lizardite 23.29 19.98 -3.30 -0.275 0.56423E+04 107 magnetite 20.13 19.24 -0.89 -0.073 0.15256E+04 108 minnesotaite 10.46 6.63 -3.83 -0.225 0.65377E+04 110 magnesioferrite 26.26 21.47 -4.78 -0.390 0.81671E+04 113 margarite 17.45 12.93 -4.52 -0.181 0.77236E+04 120 muscovite 2.68 1.29 -1.39 -0.082 0.23789E+04 121 paragonite 4.34 3.39 -0.95 -0.056 0.16174E+04 122 nepheline 8.38 6.32 -2.06 -0.294 0.35172E+04 128 periclase-Fe 11.64 6.64 -5.00 -1.249 0.85330E+04 134 phlogopite-Na 29.73 26.30 -3.43 -0.191 0.58570E+04 136 prehnite 19.47 18.03 -1.44 -0.085 0.24579E+04 137 prehnite-Fe 22.59 22.47 -0.12 -0.007 0.20487E+03 138 pumpellyite-Fe 46.47 44.55 -1.92 -0.043 0.32721E+04 139 pumpellyite-Mg 49.19 46.79 -2.40 -0.053 0.41064E+04 145 pyroxmangite 7.42 5.45 -1.96 -0.393 0.33551E+04 146 pyrophyllite -6.10 -9.58 -3.48 -0.217 0.59376E+04 147 quartz -2.98 -3.32 -0.34 -0.114 0.58276E+03 152 rhodonite 7.46 5.45 -2.01 -0.402 0.34344E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.39 -4.93 -0.493 0.84126E+04 165 stilpnomelane-Mg 27.60 24.35 -3.24 -0.097 0.55369E+04 171 talc 16.55 13.34 -3.22 -0.189 0.54930E+04 174 tephroite 18.11 14.23 -3.89 -0.555 0.66377E+04 177 topaz-H 4.67 0.39 -4.27 -0.388 0.72962E+04 178 tridymite -2.61 -3.32 -0.71 -0.236 0.12101E+04 187 wairakite 4.06 2.56 -1.49 -0.088 0.25517E+04 188 walstromite 11.53 8.82 -2.71 -0.542 0.46301E+04 189 wollastonite 10.48 8.82 -1.67 -0.333 0.28440E+04 190 pseudo-wollastonite 11.02 8.82 -2.20 -0.441 0.37626E+04 191 zoisite 22.96 19.89 -3.08 -0.140 0.52555E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.86 -4.30 -0.266 0.73467E+04 195 beidellite-K -1.44 -5.99 -4.56 -0.279 0.77795E+04 196 beidellite-Mg -1.71 -6.40 -4.69 -0.290 0.80146E+04 197 beidellite-Na -1.26 -5.30 -4.04 -0.247 0.68983E+04 199 chalcedony -2.79 -3.32 -0.53 -0.176 0.90308E+03 201 montmorillonite-Ca -2.21 -5.26 -3.04 -0.188 0.51951E+04 202 montmorillonite-K -2.16 -5.39 -3.22 -0.197 0.55058E+04 203 montmorillonite-Mg -2.40 -5.80 -3.39 -0.210 0.57941E+04 204 montmorillonite-Na -1.96 -4.69 -2.73 -0.167 0.46626E+04 205 nontronite-Ca 3.28 3.02 -0.26 -0.017 0.44753E+03 206 nontronite-H 2.60 1.01 -1.58 -0.106 0.26999E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11271E+04 224 tobermorite 9.84 6.79 -3.05 -0.832 0.52080E+04 233 boehmite 4.43 1.86 -2.57 -0.428 0.43895E+04 235 ferrous-oxide 9.82 6.64 -3.18 -0.796 0.54341E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.415 0.21233E+04 242 an20ab80 2.08 1.58 -0.50 -0.038 0.85334E+03 243 an25ab75 2.71 2.06 -0.65 -0.050 0.11146E+04 244 an30ab70 3.34 2.53 -0.81 -0.062 0.13842E+04 245 tr.625ac.25prg.125 45.31 40.67 -4.64 -0.125 0.79147E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 18.3990000 g New total amount of reactant added: 18.7990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8634E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 18.7990000 Water: Moles liquid = 0.5537E+02 kg liquid = 0.9974E+00 Moles total = 0.5527E+02 kg total = 0.9958E+00 Activity = 1.0000 Stoichiometric ionic strength = .5200688E-02 Osmotic coef. = 0.9618 True ionic strength = .9383204E-02 Chg. balance for total moles = 0.8634E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15252E-09 -9.8167 0.13371E-09 -9.8738 0.87668E+00 -0.0572 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13801E-03 -3.8601 0.12060E-03 -3.9186 0.87386E+00 -0.0586 4 SO4-- 0.25552E-04 -4.5926 0.15824E-04 -4.8007 0.61930E+00 -0.2081 5 HCO3- 0.66246E-05 -5.1788 0.57935E-05 -5.2371 0.87454E+00 -0.0582 6 HS- 0.13397E-11 -11.8730 0.11708E-11 -11.9315 0.87393E+00 -0.0585 7 Al+++ 0.49998E-27 -27.3010 0.17273E-27 -27.7626 0.34547E+00 -0.4616 8 H4SiO4 0.47501E-03 -3.3233 0.47501E-03 -3.3233 0.10000E+01 0.0000 9 Ca++ 0.39960E-07 -7.3984 0.24651E-07 -7.6082 0.61688E+00 -0.2098 10 Mg++ 0.21863E-10 -10.6603 0.13454E-10 -10.8712 0.61538E+00 -0.2109 11 Fe++ 0.12724E-12 -12.8954 0.78344E-13 -13.1060 0.61574E+00 -0.2106 12 K+ 0.73040E-04 -4.1364 0.63885E-04 -4.1946 0.87465E+00 -0.0582 13 Na+ 0.92774E-02 -2.0326 0.81065E-02 -2.0912 0.87378E+00 -0.0586 14 Mn++ 0.17263E-10 -10.7629 0.10634E-10 -10.9733 0.61601E+00 -0.2104 15 HPO4-- 0.53331E-06 -6.2730 0.33030E-06 -6.4811 0.61934E+00 -0.2081 16 HSiO3- 0.39664E-02 -2.4016 0.34661E-02 -2.4602 0.87386E+00 -0.0586 17 Ca(HSiO3)+ 0.21884E-08 -8.6599 0.19143E-08 -8.7180 0.87475E+00 -0.0581 18 Mg(HSiO3)+ 0.14864E-11 -11.8279 0.13003E-11 -11.8860 0.87475E+00 -0.0581 19 NaHSiO3,aq 0.44626E-03 -3.3504 0.44626E-03 -3.3504 0.10000E+01 0.0000 20 AlO+ 0.14258E-14 -14.8459 0.12472E-14 -14.9041 0.87475E+00 -0.0581 22 HAlO2,aq 0.18666E-08 -8.7290 0.18666E-08 -8.7290 0.10000E+01 0.0000 23 AlO2- 0.35705E-04 -4.4473 0.31171E-04 -4.5062 0.87301E+00 -0.0590 24 CH4,aq 0.42130E-18 -18.3754 0.42062E-18 -18.3761 0.99840E+00 -0.0007 29 CO,aq 0.73472E-19 -19.1339 0.73472E-19 -19.1339 0.10000E+01 0.0000 30 CO2,aq 0.15643E-08 -8.8057 0.15618E-08 -8.8064 0.99840E+00 -0.0007 31 CO3-2 0.64762E-05 -5.1887 0.40061E-05 -5.3973 0.61859E+00 -0.2086 32 CaCO3,aq 0.12095E-08 -8.9174 0.12095E-08 -8.9174 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41137E-11 -11.3858 0.35985E-11 -11.4439 0.87475E+00 -0.0581 34 CaCl+ 0.54156E-11 -11.2664 0.47373E-11 -11.3245 0.87475E+00 -0.0581 35 CaCl2,aq 0.13302E-15 -15.8761 0.13302E-15 -15.8761 0.10000E+01 0.0000 36 CaOH+ 0.14861E-07 -7.8280 0.13000E-07 -7.8861 0.87475E+00 -0.0581 37 CaSO4,aq 0.12154E-09 -9.9153 0.12154E-09 -9.9153 0.10000E+01 0.0000 38 HCl,aq 0.30332E-14 -14.5181 0.30332E-14 -14.5181 0.10000E+01 0.0000 43 FeCl+ 0.16823E-16 -16.7741 0.14716E-16 -16.8322 0.87475E+00 -0.0581 46 FeO,aq 0.17328E-09 -9.7612 0.17328E-09 -9.7612 0.10000E+01 0.0000 47 FeOH+ 0.22206E-10 -10.6535 0.19425E-10 -10.7116 0.87475E+00 -0.0581 48 HFeO2- 0.15952E-07 -7.7972 0.13940E-07 -7.8558 0.87386E+00 -0.0586 49 FeO+ 0.12644E-14 -14.8981 0.11061E-14 -14.9562 0.87475E+00 -0.0581 51 FeO2- 0.13914E-07 -7.8565 0.12159E-07 -7.9151 0.87386E+00 -0.0586 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.18294E-08 -8.7377 0.18265E-08 -8.7384 0.99840E+00 -0.0007 54 KCl,aq 0.13642E-09 -9.8651 0.13642E-09 -9.8651 0.10000E+01 0.0000 55 KHSO4,aq 0.36172E-18 -18.4416 0.36172E-18 -18.4416 0.10000E+01 0.0000 56 KOH,aq 0.20829E-06 -6.6813 0.20829E-06 -6.6813 0.10000E+01 0.0000 57 KSO4- 0.17823E-07 -7.7490 0.15575E-07 -7.8076 0.87386E+00 -0.0586 58 MgCO3,aq 0.16495E-12 -12.7826 0.16495E-12 -12.7826 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22895E-14 -14.6403 0.20027E-14 -14.6984 0.87475E+00 -0.0581 60 MgCl+ 0.26832E-14 -14.5713 0.23472E-14 -14.6295 0.87475E+00 -0.0581 61 MgOH+ 0.44934E-10 -10.3474 0.39306E-10 -10.4055 0.87475E+00 -0.0581 63 MnO,aq 0.62789E-09 -9.2021 0.62789E-09 -9.2021 0.10000E+01 0.0000 64 MnOH+ 0.28000E-09 -9.5528 0.24493E-09 -9.6110 0.87475E+00 -0.0581 65 MnO2-2 0.19635E-11 -11.7070 0.12146E-11 -11.9156 0.61859E+00 -0.2086 66 HMnO2- 0.40265E-10 -10.3951 0.35186E-10 -10.4536 0.87386E+00 -0.0586 69 MnCl+ 0.88732E-14 -14.0519 0.77618E-14 -14.1100 0.87475E+00 -0.0581 70 MnSO4,aq 0.47690E-13 -13.3216 0.47690E-13 -13.3216 0.10000E+01 0.0000 71 NaCl,aq 0.31923E-06 -6.4959 0.31923E-06 -6.4959 0.10000E+01 0.0000 72 NaOH,aq 0.26640E-04 -4.5745 0.26640E-04 -4.5745 0.10000E+01 0.0000 74 OH- 0.51386E-02 -2.2892 0.44861E-02 -2.3481 0.87301E+00 -0.0590 79 HPO3-2 0.30804E-17 -17.5114 0.19055E-17 -17.7200 0.61859E+00 -0.2086 82 H3PO4,aq 0.38018E-16 -16.4200 0.38018E-16 -16.4200 0.10000E+01 0.0000 83 H2PO4- 0.88563E-09 -9.0527 0.77430E-09 -9.1111 0.87430E+00 -0.0583 84 PO4-3 0.60829E-08 -8.2159 0.21573E-08 -8.6661 0.35466E+00 -0.4502 87 H2P2O7-2 0.75855E-19 -19.1200 0.46923E-19 -19.3286 0.61859E+00 -0.2086 88 HP2O7-3 0.20821E-15 -15.6815 0.71960E-16 -16.1429 0.34561E+00 -0.4614 89 P2O7-4 0.85356E-15 -15.0688 0.13277E-15 -15.8769 0.15555E+00 -0.8081 90 H2S,aq 0.47112E-15 -15.3269 0.47037E-15 -15.3276 0.99840E+00 -0.0007 97 SO3-2 0.63218E-14 -14.1992 0.39409E-14 -14.4044 0.62338E+00 -0.2052 98 HSO3- 0.35289E-16 -16.4524 0.30837E-16 -16.5109 0.87386E+00 -0.0586 99 HSO4- 0.22432E-11 -11.6491 0.19632E-11 -11.7070 0.87520E+00 -0.0579 Charge balance for all species = 0.8535E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1525179E-09 -.9727576E-02 -.9797868E+01 0.0000 2 H2O 0.1000000E+01 0.5550907E+02 0.9993043E+06 0.0000 3 Cl- 0.1380099E-03 0.1383292E-03 0.4900712E+01 5.9552 4 SO4-- 0.2555215E-04 0.2557141E-04 0.2454690E+01 14.9470 5 HCO3- 0.6624617E-05 0.1310363E-04 0.7989806E+00 4.6368 6 HS- 0.1339737E-11 -.1306047E-08 -.4316299E-04 -2.0577 7 Al+++ 0.4999809E-27 0.3570703E-04 0.9627469E+00 1.8589 8 H4SiO4 0.4750080E-03 0.4887685E-02 0.4694490E+03 -3.3233 9 Ca++ 0.3996000E-07 0.5834995E-07 0.2336893E-02 12.1395 10 Mg++ 0.2186266E-10 0.6845320E-10 0.1663055E-05 8.8765 11 Fe++ 0.1272362E-12 0.3026525E-07 0.1689026E-02 6.6417 12 K+ 0.7304031E-04 0.7326656E-04 0.2862840E+01 5.6792 13 Na+ 0.9277446E-02 0.9750664E-02 0.2240070E+03 7.7827 14 Mn++ 0.1726277E-10 0.9674431E-09 0.5311174E-04 8.7744 15 HPO4-- 0.5333150E-06 0.5402835E-06 0.5181914E-01 13.2666 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3112705E+00 -.9702609E-02 -.3015679E+00 0.0000000E+00 2 H2O 0.5527260E+02 0.5536660E+02 -.9400594E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5464888E-03 0.2550577E-04 0.5209831E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5209844E-03 -.1302695E-08 -.5209831E-03 0.0000000E+00 7 Al+++ 0.6129868E-01 0.3561538E-04 0.6126307E-01 0.0000000E+00 8 H4SiO4 0.1957499E+00 0.4875140E-02 0.1908748E+00 0.0000000E+00 9 Ca++ 0.2163600E-01 0.5820019E-07 0.2163594E-01 0.0000000E+00 10 Mg++ 0.1491984E-01 0.6827751E-10 0.1491984E-01 0.0000000E+00 11 Fe++ 0.1340385E-01 0.3018757E-07 0.1340382E-01 0.0000000E+00 12 K+ 0.3991295E-02 0.7307851E-04 0.3918217E-02 0.0000000E+00 13 Na+ 0.2375740E-01 0.9725638E-02 0.1403176E-01 0.0000000E+00 14 Mn++ 0.3259483E-03 0.9649600E-09 0.3259473E-03 0.0000000E+00 15 HPO4-- 0.1112445E-03 0.5388968E-06 0.1107056E-03 0.0000000E+00 Chg. balance for solid moles: 0.5570E-16 Mass of aqueous solution: 0.998140E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 18.7990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1395E-01 -1.855 3.659 0.563 17.84 1.405 andradite 0.1512E-02 -2.820 0.7684 -0.114 3.745 0.1996 grossular 0.7403E-04 -4.131 0.3335E-01 -1.477 0.1625 0.9278E-02 apatite-OH 0.3690E-04 -4.433 0.1854E-01 -1.732 0.9035E-01 0.5890E-02 clinochlore 0.2984E-02 -2.525 1.659 0.220 8.084 0.6309 daphnite 0.1819E-02 -2.740 1.298 0.113 6.324 0.3932 chlorite-Mn 0.6519E-04 -4.186 0.4622E-01 -1.335 0.2253 0.1473E-01 hematite 0.3391E-03 -3.470 0.5415E-01 -1.266 0.2639 0.1026E-01 microcline 0.3904E-02 -2.409 1.087 0.036 5.296 0.4245 stilbite 0.1669E-01 -1.777 11.76 1.071 57.34 5.487 stilpnomelane-Fe 0.2865E-04 -4.543 0.3089E-01 -1.510 0.1505 0.1067E-01 nontronite-Na 0.2329E-03 -3.633 0.9903E-01 -1.004 0.4827 0.3076E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9533E+00 0.9533E+00 1.0000 -0.021 grossular 0.4667E-01 0.4667E-01 1.0000 -1.331 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6130E+00 0.6130E+00 1.0000 -0.213 daphnite 0.3736E+00 0.3736E+00 1.0000 -0.428 chlorite-Mn 0.1339E-01 0.1339E-01 1.0000 -1.873 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 20.516651 g Volume = 8.621456 cm3 Porosity: -1.1956% V(tot) - V(min): -.10186E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 18.7990000 g log = 1.2741 Original solution: 1000.0103000 g Original solution / Rock added: 53.19 (Water/Rock Ratio), log = 1.7259 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1687E-06 1.0073 0.1788E-06 0.1775E-06 CH4,gas 0.6243E-15 1.0129 0.6652E-15 0.6567E-15 H2,gas 0.2380E-05 1.0006 0.2505E-05 0.2504E-05 H2S,gas 0.1309E-13 0.9959 0.1372E-13 0.1377E-13 S2,gas 0.1068E-35 1.0000 0.1123E-35 0.1123E-35 CO,gas 0.1103E-15 1.0000 0.1160E-15 0.1160E-15 SO3,gas 0.1005E-39 1.0000 0.1058E-39 0.1058E-39 SO2,gas 0.9529E-23 1.0000 0.1002E-22 0.1002E-22 HCl,gas 0.5091E-17 1.0000 0.5356E-17 0.5356E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 90 hematite 12.60 12.60 0.00 0.000 0.15165E-10 116 microcline -2.43 -2.43 0.00 0.000 0.18957E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 209 nontronite-Na 3.58 3.58 0.00 0.000 0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.916 0.14936E+05 -6.748 3 CH4,gas 4.81 -12.37 -17.18 -4.294 0.29329E+05 -15.177 4 H2,gas 8.29 0.69 -7.60 -4.344 0.12979E+05 -5.601 5 H2S,gas -5.94 -21.81 -15.86 -7.931 0.27085E+05 -13.863 6 S2,gas -7.03 -44.98 -37.95 -5.838 0.64798E+05 -35.950 7 CO,gas 3.51 -14.43 -17.94 -5.519 0.30624E+05 -15.935 8 SO3,gas 17.43 -24.55 -41.98 -10.494 0.71672E+05 -39.976 9 SO2,gas 1.14 -23.86 -25.00 -6.666 0.42685E+05 -22.999 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32905E+05 -17.271 11 acmite 7.74 7.43 -0.30 -0.031 0.51654E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.07 -4.48 -0.224 0.76477E+04 20 analcite 3.37 2.99 -0.38 -0.042 0.64150E+03 21 andalusite 5.06 0.39 -4.67 -0.467 0.79704E+04 26 annite 20.21 17.49 -2.72 -0.151 0.46376E+04 27 phlogopite 27.15 24.20 -2.95 -0.164 0.50351E+04 29 anorthite 12.80 9.21 -3.59 -0.276 0.61248E+04 35 aragonite 0.99 -2.97 -3.96 -1.319 0.67575E+04 36 brucite 12.58 8.88 -3.70 -0.740 0.63178E+04 37 calcite 0.83 -2.97 -3.80 -1.268 0.64962E+04 38 carnegieite-low 9.06 6.32 -2.75 -0.392 0.46893E+04 39 carnegieite-high 10.13 6.32 -3.82 -0.545 0.65161E+04 40 carpholite-Mg 8.65 5.95 -2.70 -0.180 0.46148E+04 41 carpholite-Fe 6.78 3.71 -3.07 -0.205 0.52421E+04 42 celadonite 5.40 3.12 -2.28 -0.134 0.38915E+04 43 celadonite-Fe 3.94 0.89 -3.05 -0.179 0.52084E+04 44 chrysotile 23.94 19.98 -3.95 -0.330 0.67520E+04 50 chloritoid-Mg 13.26 9.27 -3.99 -0.266 0.68133E+04 51 chloritoid-Fe 9.24 7.04 -2.20 -0.147 0.37608E+04 52 chloritoid-Mn 11.46 9.17 -2.29 -0.153 0.39176E+04 54 coesite -2.37 -3.32 -0.95 -0.318 0.16288E+04 59 corundum 8.43 3.72 -4.72 -0.429 0.80519E+04 61 cristobalite -2.55 -3.32 -0.77 -0.258 0.13217E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.86 -1.04 -0.173 0.17710E+04 67 diopside 16.22 14.37 -1.85 -0.185 0.31521E+04 68 hedenbergite 14.24 12.13 -2.11 -0.211 0.36025E+04 75 epidote 24.78 24.33 -0.45 -0.022 0.76760E+03 76 clinozoisite 22.92 19.89 -3.04 -0.138 0.51829E+04 77 epidote-Fe 29.94 28.77 -1.17 -0.061 0.19998E+04 78 fayalite 14.08 9.96 -4.12 -0.588 0.70329E+04 79 ferrosilite 11.19 6.64 -4.55 -0.455 0.77706E+04 83 gibbsite 4.10 1.86 -2.24 -0.320 0.38222E+04 84 glaucophane 23.11 19.33 -3.78 -0.102 0.64616E+04 85 glaucophane-Fe 17.42 12.62 -4.80 -0.130 0.81881E+04 87 greenalite 16.19 13.28 -2.92 -0.243 0.49786E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.99 -1.26 -0.126 0.21445E+04 96 julgoldite 70.57 67.10 -3.48 -0.090 0.59353E+04 97 kalsilite 7.62 4.21 -3.41 -0.486 0.58147E+04 98 kaolinite -1.27 -2.93 -1.66 -0.151 0.28271E+04 99 kyanite 4.93 0.39 -4.54 -0.454 0.77472E+04 101 laumontite 2.97 2.56 -0.41 -0.027 0.70092E+03 102 lawsonite 9.68 9.21 -0.47 -0.031 0.79864E+03 103 leucite 4.17 0.89 -3.28 -0.328 0.55939E+04 105 lizardite 23.29 19.98 -3.30 -0.275 0.56423E+04 107 magnetite 20.13 19.24 -0.89 -0.073 0.15256E+04 108 minnesotaite 10.46 6.63 -3.83 -0.225 0.65377E+04 110 magnesioferrite 26.26 21.47 -4.78 -0.390 0.81671E+04 113 margarite 17.45 12.93 -4.52 -0.181 0.77236E+04 120 muscovite 2.68 1.29 -1.39 -0.082 0.23789E+04 121 paragonite 4.34 3.39 -0.95 -0.056 0.16174E+04 122 nepheline 8.38 6.32 -2.06 -0.294 0.35172E+04 128 periclase-Fe 11.64 6.64 -5.00 -1.249 0.85330E+04 134 phlogopite-Na 29.73 26.30 -3.43 -0.191 0.58570E+04 136 prehnite 19.47 18.03 -1.44 -0.085 0.24579E+04 137 prehnite-Fe 22.59 22.47 -0.12 -0.007 0.20487E+03 138 pumpellyite-Fe 46.47 44.55 -1.92 -0.043 0.32721E+04 139 pumpellyite-Mg 49.19 46.79 -2.40 -0.053 0.41064E+04 145 pyroxmangite 7.42 5.45 -1.96 -0.393 0.33551E+04 146 pyrophyllite -6.10 -9.58 -3.48 -0.217 0.59376E+04 147 quartz -2.98 -3.32 -0.34 -0.114 0.58276E+03 152 rhodonite 7.46 5.45 -2.01 -0.402 0.34344E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.39 -4.93 -0.493 0.84126E+04 165 stilpnomelane-Mg 27.60 24.35 -3.24 -0.097 0.55369E+04 171 talc 16.55 13.34 -3.22 -0.189 0.54930E+04 174 tephroite 18.11 14.23 -3.89 -0.555 0.66377E+04 177 topaz-H 4.67 0.39 -4.27 -0.388 0.72962E+04 178 tridymite -2.61 -3.32 -0.71 -0.236 0.12101E+04 187 wairakite 4.06 2.56 -1.49 -0.088 0.25517E+04 188 walstromite 11.53 8.82 -2.71 -0.542 0.46301E+04 189 wollastonite 10.48 8.82 -1.67 -0.333 0.28440E+04 190 pseudo-wollastonite 11.02 8.82 -2.20 -0.441 0.37626E+04 191 zoisite 22.96 19.89 -3.08 -0.140 0.52555E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.86 -4.30 -0.266 0.73467E+04 195 beidellite-K -1.44 -5.99 -4.56 -0.279 0.77795E+04 196 beidellite-Mg -1.71 -6.40 -4.69 -0.290 0.80146E+04 197 beidellite-Na -1.26 -5.30 -4.04 -0.247 0.68983E+04 199 chalcedony -2.79 -3.32 -0.53 -0.176 0.90308E+03 201 montmorillonite-Ca -2.21 -5.26 -3.04 -0.188 0.51951E+04 202 montmorillonite-K -2.16 -5.39 -3.22 -0.197 0.55058E+04 203 montmorillonite-Mg -2.40 -5.80 -3.39 -0.210 0.57941E+04 204 montmorillonite-Na -1.96 -4.69 -2.73 -0.167 0.46626E+04 205 nontronite-Ca 3.28 3.02 -0.26 -0.017 0.44753E+03 206 nontronite-H 2.60 1.01 -1.58 -0.106 0.26999E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11271E+04 224 tobermorite 9.84 6.79 -3.05 -0.832 0.52080E+04 233 boehmite 4.43 1.86 -2.57 -0.428 0.43895E+04 235 ferrous-oxide 9.82 6.64 -3.18 -0.796 0.54341E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.415 0.21233E+04 242 an20ab80 2.08 1.58 -0.50 -0.038 0.85334E+03 243 an25ab75 2.71 2.06 -0.65 -0.050 0.11146E+04 244 an30ab70 3.34 2.53 -0.81 -0.062 0.13842E+04 245 tr.625ac.25prg.125 45.31 40.67 -4.64 -0.125 0.79147E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 18.7990000 g New total amount of reactant added: 19.1990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8634E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 19.1990000 Water: Moles liquid = 0.5536E+02 kg liquid = 0.9974E+00 Moles total = 0.5527E+02 kg total = 0.9957E+00 Activity = 1.0000 Stoichiometric ionic strength = .5200696E-02 Osmotic coef. = 0.9618 True ionic strength = .9383210E-02 Chg. balance for total moles = 0.8634E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15252E-09 -9.8167 0.13371E-09 -9.8738 0.87668E+00 -0.0572 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13802E-03 -3.8601 0.12061E-03 -3.9186 0.87386E+00 -0.0586 4 SO4-- 0.25553E-04 -4.5926 0.15825E-04 -4.8007 0.61930E+00 -0.2081 5 HCO3- 0.66249E-05 -5.1788 0.57937E-05 -5.2370 0.87454E+00 -0.0582 6 HS- 0.13398E-11 -11.8730 0.11709E-11 -11.9315 0.87393E+00 -0.0585 7 Al+++ 0.49998E-27 -27.3010 0.17273E-27 -27.7626 0.34547E+00 -0.4616 8 H4SiO4 0.47501E-03 -3.3233 0.47501E-03 -3.3233 0.10000E+01 0.0000 9 Ca++ 0.39960E-07 -7.3984 0.24651E-07 -7.6082 0.61688E+00 -0.2098 10 Mg++ 0.21863E-10 -10.6603 0.13454E-10 -10.8712 0.61538E+00 -0.2109 11 Fe++ 0.12724E-12 -12.8954 0.78344E-13 -13.1060 0.61574E+00 -0.2106 12 K+ 0.73040E-04 -4.1364 0.63885E-04 -4.1946 0.87465E+00 -0.0582 13 Na+ 0.92775E-02 -2.0326 0.81065E-02 -2.0912 0.87378E+00 -0.0586 14 Mn++ 0.17263E-10 -10.7629 0.10634E-10 -10.9733 0.61601E+00 -0.2104 15 HPO4-- 0.53331E-06 -6.2730 0.33030E-06 -6.4811 0.61934E+00 -0.2081 16 HSiO3- 0.39664E-02 -2.4016 0.34661E-02 -2.4602 0.87386E+00 -0.0586 17 Ca(HSiO3)+ 0.21884E-08 -8.6599 0.19143E-08 -8.7180 0.87475E+00 -0.0581 18 Mg(HSiO3)+ 0.14864E-11 -11.8279 0.13003E-11 -11.8860 0.87475E+00 -0.0581 19 NaHSiO3,aq 0.44626E-03 -3.3504 0.44626E-03 -3.3504 0.10000E+01 0.0000 20 AlO+ 0.14258E-14 -14.8459 0.12472E-14 -14.9041 0.87475E+00 -0.0581 22 HAlO2,aq 0.18666E-08 -8.7290 0.18666E-08 -8.7290 0.10000E+01 0.0000 23 AlO2- 0.35705E-04 -4.4473 0.31171E-04 -4.5062 0.87301E+00 -0.0590 24 CH4,aq 0.42131E-18 -18.3754 0.42064E-18 -18.3761 0.99840E+00 -0.0007 29 CO,aq 0.73475E-19 -19.1339 0.73475E-19 -19.1339 0.10000E+01 0.0000 30 CO2,aq 0.15644E-08 -8.8056 0.15619E-08 -8.8063 0.99840E+00 -0.0007 31 CO3-2 0.64765E-05 -5.1887 0.40063E-05 -5.3973 0.61859E+00 -0.2086 32 CaCO3,aq 0.12095E-08 -8.9174 0.12095E-08 -8.9174 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41139E-11 -11.3858 0.35986E-11 -11.4439 0.87475E+00 -0.0581 34 CaCl+ 0.54158E-11 -11.2663 0.47375E-11 -11.3245 0.87475E+00 -0.0581 35 CaCl2,aq 0.13303E-15 -15.8760 0.13303E-15 -15.8760 0.10000E+01 0.0000 36 CaOH+ 0.14861E-07 -7.8280 0.13000E-07 -7.8861 0.87475E+00 -0.0581 37 CaSO4,aq 0.12155E-09 -9.9153 0.12155E-09 -9.9153 0.10000E+01 0.0000 38 HCl,aq 0.30333E-14 -14.5181 0.30333E-14 -14.5181 0.10000E+01 0.0000 43 FeCl+ 0.16824E-16 -16.7741 0.14717E-16 -16.8322 0.87475E+00 -0.0581 46 FeO,aq 0.17328E-09 -9.7612 0.17328E-09 -9.7612 0.10000E+01 0.0000 47 FeOH+ 0.22206E-10 -10.6535 0.19425E-10 -10.7116 0.87475E+00 -0.0581 48 HFeO2- 0.15952E-07 -7.7972 0.13939E-07 -7.8558 0.87386E+00 -0.0586 49 FeO+ 0.12644E-14 -14.8981 0.11061E-14 -14.9562 0.87475E+00 -0.0581 51 FeO2- 0.13914E-07 -7.8565 0.12159E-07 -7.9151 0.87386E+00 -0.0586 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.18294E-08 -8.7377 0.18265E-08 -8.7384 0.99840E+00 -0.0007 54 KCl,aq 0.13643E-09 -9.8651 0.13643E-09 -9.8651 0.10000E+01 0.0000 55 KHSO4,aq 0.36173E-18 -18.4416 0.36173E-18 -18.4416 0.10000E+01 0.0000 56 KOH,aq 0.20829E-06 -6.6813 0.20829E-06 -6.6813 0.10000E+01 0.0000 57 KSO4- 0.17824E-07 -7.7490 0.15576E-07 -7.8076 0.87386E+00 -0.0586 58 MgCO3,aq 0.16496E-12 -12.7826 0.16496E-12 -12.7826 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22896E-14 -14.6402 0.20028E-14 -14.6984 0.87475E+00 -0.0581 60 MgCl+ 0.26833E-14 -14.5713 0.23473E-14 -14.6294 0.87475E+00 -0.0581 61 MgOH+ 0.44934E-10 -10.3474 0.39306E-10 -10.4055 0.87475E+00 -0.0581 63 MnO,aq 0.62789E-09 -9.2021 0.62789E-09 -9.2021 0.10000E+01 0.0000 64 MnOH+ 0.28000E-09 -9.5528 0.24493E-09 -9.6110 0.87475E+00 -0.0581 65 MnO2-2 0.19635E-11 -11.7070 0.12146E-11 -11.9156 0.61859E+00 -0.2086 66 HMnO2- 0.40265E-10 -10.3951 0.35186E-10 -10.4536 0.87386E+00 -0.0586 69 MnCl+ 0.88735E-14 -14.0519 0.77622E-14 -14.1100 0.87475E+00 -0.0581 70 MnSO4,aq 0.47692E-13 -13.3216 0.47692E-13 -13.3216 0.10000E+01 0.0000 71 NaCl,aq 0.31924E-06 -6.4959 0.31924E-06 -6.4959 0.10000E+01 0.0000 72 NaOH,aq 0.26640E-04 -4.5745 0.26640E-04 -4.5745 0.10000E+01 0.0000 74 OH- 0.51386E-02 -2.2892 0.44861E-02 -2.3481 0.87301E+00 -0.0590 79 HPO3-2 0.30804E-17 -17.5114 0.19055E-17 -17.7200 0.61859E+00 -0.2086 82 H3PO4,aq 0.38018E-16 -16.4200 0.38018E-16 -16.4200 0.10000E+01 0.0000 83 H2PO4- 0.88563E-09 -9.0527 0.77430E-09 -9.1111 0.87430E+00 -0.0583 84 PO4-3 0.60829E-08 -8.2159 0.21573E-08 -8.6661 0.35466E+00 -0.4502 87 H2P2O7-2 0.75855E-19 -19.1200 0.46923E-19 -19.3286 0.61859E+00 -0.2086 88 HP2O7-3 0.20821E-15 -15.6815 0.71960E-16 -16.1429 0.34561E+00 -0.4614 89 P2O7-4 0.85356E-15 -15.0688 0.13277E-15 -15.8769 0.15555E+00 -0.8081 90 H2S,aq 0.47114E-15 -15.3268 0.47039E-15 -15.3275 0.99840E+00 -0.0007 97 SO3-2 0.63221E-14 -14.1991 0.39410E-14 -14.4044 0.62338E+00 -0.2052 98 HSO3- 0.35290E-16 -16.4523 0.30838E-16 -16.5109 0.87386E+00 -0.0586 99 HSO4- 0.22433E-11 -11.6491 0.19633E-11 -11.7070 0.87520E+00 -0.0579 Charge balance for all species = 0.8514E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1525180E-09 -.9727573E-02 -.9797865E+01 0.0000 2 H2O 0.1000000E+01 0.5550907E+02 0.9993043E+06 0.0000 3 Cl- 0.1380154E-03 0.1383348E-03 0.4900909E+01 5.9552 4 SO4-- 0.2555318E-04 0.2557243E-04 0.2454789E+01 14.9470 5 HCO3- 0.6624884E-05 0.1310416E-04 0.7990127E+00 4.6368 6 HS- 0.1339792E-11 -.1306046E-08 -.4316296E-04 -2.0577 7 Al+++ 0.4999817E-27 0.3570702E-04 0.9627465E+00 1.8589 8 H4SiO4 0.4750080E-03 0.4887683E-02 0.4694489E+03 -3.3233 9 Ca++ 0.3996004E-07 0.5835005E-07 0.2336897E-02 12.1395 10 Mg++ 0.2186269E-10 0.6845325E-10 0.1663057E-05 8.8765 11 Fe++ 0.1272363E-12 0.3026523E-07 0.1689025E-02 6.6417 12 K+ 0.7304035E-04 0.7326660E-04 0.2862841E+01 5.6792 13 Na+ 0.9277450E-02 0.9750669E-02 0.2240071E+03 7.7827 14 Mn++ 0.1726279E-10 0.9674433E-09 0.5311175E-04 8.7744 15 HPO4-- 0.5333145E-06 0.5402831E-06 0.5181910E-01 13.2666 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3178939E+00 -.9702216E-02 -.3081917E+00 0.0000000E+00 2 H2O 0.5526758E+02 0.5536438E+02 -.9679661E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5575742E-03 0.2550577E-04 0.5320684E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5320697E-03 -.1302642E-08 -.5320684E-03 0.0000000E+00 7 Al+++ 0.6260298E-01 0.3561394E-04 0.6256736E-01 0.0000000E+00 8 H4SiO4 0.1999150E+00 0.4874943E-02 0.1950401E+00 0.0000000E+00 9 Ca++ 0.2209606E-01 0.5819795E-07 0.2209600E-01 0.0000000E+00 10 Mg++ 0.1523730E-01 0.6827482E-10 0.1523730E-01 0.0000000E+00 11 Fe++ 0.1368905E-01 0.3018634E-07 0.1368902E-01 0.0000000E+00 12 K+ 0.4076221E-02 0.7307561E-04 0.4003145E-02 0.0000000E+00 13 Na+ 0.2425949E-01 0.9725252E-02 0.1453424E-01 0.0000000E+00 14 Mn++ 0.3328837E-03 0.9649215E-09 0.3328827E-03 0.0000000E+00 15 HPO4-- 0.1136116E-03 0.5388747E-06 0.1130727E-03 0.0000000E+00 Chg. balance for solid moles: -.1681E-17 Mass of aqueous solution: 0.998100E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 19.1990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1444E-01 -1.840 3.787 0.578 18.07 1.454 andradite 0.1577E-02 -2.802 0.8015 -0.096 3.825 0.2082 grossular 0.7721E-04 -4.112 0.3478E-01 -1.459 0.1660 0.9678E-02 apatite-OH 0.3769E-04 -4.424 0.1893E-01 -1.723 0.9036E-01 0.6016E-02 clinochlore 0.3047E-02 -2.516 1.694 0.229 8.084 0.6443 daphnite 0.1857E-02 -2.731 1.325 0.122 6.324 0.4016 chlorite-Mn 0.6658E-04 -4.177 0.4720E-01 -1.326 0.2253 0.1504E-01 hematite 0.2717E-03 -3.566 0.4339E-01 -1.363 0.2071 0.8223E-02 microcline 0.3989E-02 -2.399 1.110 0.045 5.298 0.4337 stilbite 0.1694E-01 -1.771 11.94 1.077 56.99 5.570 stilpnomelane-Fe 0.2926E-04 -4.534 0.3154E-01 -1.501 0.1505 0.1090E-01 nontronite-Na 0.2795E-03 -3.554 0.1189 -0.925 0.5672 0.3692E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9533E+00 0.9533E+00 1.0000 -0.021 grossular 0.4667E-01 0.4667E-01 1.0000 -1.331 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6130E+00 0.6130E+00 1.0000 -0.213 daphnite 0.3736E+00 0.3736E+00 1.0000 -0.428 chlorite-Mn 0.1339E-01 0.1339E-01 1.0000 -1.873 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 20.953497 g Volume = 8.797835 cm3 Porosity: -1.3622% V(tot) - V(min): -.11824E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 19.1990000 g log = 1.2833 Original solution: 1000.0103000 g Original solution / Rock added: 52.09 (Water/Rock Ratio), log = 1.7167 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1687E-06 1.0073 0.1788E-06 0.1775E-06 CH4,gas 0.6243E-15 1.0129 0.6652E-15 0.6567E-15 H2,gas 0.2380E-05 1.0006 0.2505E-05 0.2504E-05 H2S,gas 0.1310E-13 0.9959 0.1372E-13 0.1378E-13 S2,gas 0.1068E-35 1.0000 0.1123E-35 0.1123E-35 CO,gas 0.1103E-15 1.0000 0.1160E-15 0.1160E-15 SO3,gas 0.1006E-39 1.0000 0.1058E-39 0.1058E-39 SO2,gas 0.9529E-23 1.0000 0.1002E-22 0.1002E-22 HCl,gas 0.5091E-17 1.0000 0.5356E-17 0.5356E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.54595E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 209 nontronite-Na 3.58 3.58 0.00 0.000 0.60662E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.916 0.14936E+05 -6.748 3 CH4,gas 4.81 -12.37 -17.18 -4.294 0.29329E+05 -15.177 4 H2,gas 8.29 0.69 -7.60 -4.344 0.12979E+05 -5.601 5 H2S,gas -5.94 -21.81 -15.86 -7.931 0.27085E+05 -13.863 6 S2,gas -7.03 -44.98 -37.95 -5.838 0.64798E+05 -35.950 7 CO,gas 3.51 -14.43 -17.94 -5.519 0.30624E+05 -15.935 8 SO3,gas 17.43 -24.55 -41.98 -10.494 0.71672E+05 -39.976 9 SO2,gas 1.14 -23.86 -25.00 -6.666 0.42685E+05 -22.999 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32905E+05 -17.271 11 acmite 7.74 7.43 -0.30 -0.031 0.51654E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.07 -4.48 -0.224 0.76477E+04 20 analcite 3.37 2.99 -0.38 -0.042 0.64150E+03 21 andalusite 5.06 0.39 -4.67 -0.467 0.79704E+04 26 annite 20.21 17.49 -2.72 -0.151 0.46376E+04 27 phlogopite 27.15 24.20 -2.95 -0.164 0.50351E+04 29 anorthite 12.80 9.21 -3.59 -0.276 0.61248E+04 35 aragonite 0.99 -2.97 -3.96 -1.319 0.67575E+04 36 brucite 12.58 8.88 -3.70 -0.740 0.63178E+04 37 calcite 0.83 -2.97 -3.80 -1.268 0.64962E+04 38 carnegieite-low 9.06 6.32 -2.75 -0.392 0.46893E+04 39 carnegieite-high 10.13 6.32 -3.82 -0.545 0.65161E+04 40 carpholite-Mg 8.65 5.95 -2.70 -0.180 0.46148E+04 41 carpholite-Fe 6.78 3.71 -3.07 -0.205 0.52421E+04 42 celadonite 5.40 3.12 -2.28 -0.134 0.38915E+04 43 celadonite-Fe 3.94 0.89 -3.05 -0.179 0.52084E+04 44 chrysotile 23.94 19.98 -3.95 -0.330 0.67520E+04 50 chloritoid-Mg 13.26 9.27 -3.99 -0.266 0.68133E+04 51 chloritoid-Fe 9.24 7.04 -2.20 -0.147 0.37608E+04 52 chloritoid-Mn 11.46 9.17 -2.29 -0.153 0.39176E+04 54 coesite -2.37 -3.32 -0.95 -0.318 0.16288E+04 59 corundum 8.43 3.72 -4.72 -0.429 0.80519E+04 61 cristobalite -2.55 -3.32 -0.77 -0.258 0.13217E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.86 -1.04 -0.173 0.17710E+04 67 diopside 16.22 14.37 -1.85 -0.185 0.31521E+04 68 hedenbergite 14.24 12.13 -2.11 -0.211 0.36025E+04 75 epidote 24.78 24.33 -0.45 -0.022 0.76760E+03 76 clinozoisite 22.92 19.89 -3.04 -0.138 0.51829E+04 77 epidote-Fe 29.94 28.77 -1.17 -0.061 0.19998E+04 78 fayalite 14.08 9.96 -4.12 -0.588 0.70329E+04 79 ferrosilite 11.19 6.64 -4.55 -0.455 0.77706E+04 83 gibbsite 4.10 1.86 -2.24 -0.320 0.38222E+04 84 glaucophane 23.11 19.33 -3.78 -0.102 0.64616E+04 85 glaucophane-Fe 17.42 12.62 -4.80 -0.130 0.81881E+04 87 greenalite 16.19 13.28 -2.92 -0.243 0.49786E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.99 -1.26 -0.126 0.21445E+04 96 julgoldite 70.57 67.10 -3.48 -0.090 0.59353E+04 97 kalsilite 7.62 4.21 -3.41 -0.486 0.58147E+04 98 kaolinite -1.27 -2.93 -1.66 -0.151 0.28271E+04 99 kyanite 4.93 0.39 -4.54 -0.454 0.77472E+04 101 laumontite 2.97 2.56 -0.41 -0.027 0.70092E+03 102 lawsonite 9.68 9.21 -0.47 -0.031 0.79864E+03 103 leucite 4.17 0.89 -3.28 -0.328 0.55939E+04 105 lizardite 23.29 19.98 -3.30 -0.275 0.56423E+04 107 magnetite 20.13 19.24 -0.89 -0.073 0.15256E+04 108 minnesotaite 10.46 6.63 -3.83 -0.225 0.65377E+04 110 magnesioferrite 26.26 21.47 -4.78 -0.390 0.81671E+04 113 margarite 17.45 12.93 -4.52 -0.181 0.77236E+04 120 muscovite 2.68 1.29 -1.39 -0.082 0.23789E+04 121 paragonite 4.34 3.39 -0.95 -0.056 0.16174E+04 122 nepheline 8.38 6.32 -2.06 -0.294 0.35172E+04 128 periclase-Fe 11.64 6.64 -5.00 -1.249 0.85330E+04 134 phlogopite-Na 29.73 26.30 -3.43 -0.191 0.58570E+04 136 prehnite 19.47 18.03 -1.44 -0.085 0.24579E+04 137 prehnite-Fe 22.59 22.47 -0.12 -0.007 0.20487E+03 138 pumpellyite-Fe 46.47 44.55 -1.92 -0.043 0.32721E+04 139 pumpellyite-Mg 49.19 46.79 -2.40 -0.053 0.41064E+04 145 pyroxmangite 7.42 5.45 -1.96 -0.393 0.33551E+04 146 pyrophyllite -6.10 -9.58 -3.48 -0.217 0.59376E+04 147 quartz -2.98 -3.32 -0.34 -0.114 0.58276E+03 152 rhodonite 7.46 5.45 -2.01 -0.402 0.34344E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.39 -4.93 -0.493 0.84126E+04 165 stilpnomelane-Mg 27.60 24.35 -3.24 -0.097 0.55369E+04 171 talc 16.55 13.34 -3.22 -0.189 0.54930E+04 174 tephroite 18.11 14.23 -3.89 -0.555 0.66377E+04 177 topaz-H 4.67 0.39 -4.27 -0.388 0.72962E+04 178 tridymite -2.61 -3.32 -0.71 -0.236 0.12101E+04 187 wairakite 4.06 2.56 -1.49 -0.088 0.25517E+04 188 walstromite 11.53 8.82 -2.71 -0.542 0.46301E+04 189 wollastonite 10.48 8.82 -1.67 -0.333 0.28440E+04 190 pseudo-wollastonite 11.02 8.82 -2.20 -0.441 0.37626E+04 191 zoisite 22.96 19.89 -3.08 -0.140 0.52555E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.86 -4.30 -0.266 0.73467E+04 195 beidellite-K -1.44 -5.99 -4.56 -0.279 0.77795E+04 196 beidellite-Mg -1.71 -6.40 -4.69 -0.290 0.80146E+04 197 beidellite-Na -1.26 -5.30 -4.04 -0.247 0.68983E+04 199 chalcedony -2.79 -3.32 -0.53 -0.176 0.90308E+03 201 montmorillonite-Ca -2.21 -5.26 -3.04 -0.188 0.51951E+04 202 montmorillonite-K -2.16 -5.39 -3.22 -0.197 0.55058E+04 203 montmorillonite-Mg -2.40 -5.80 -3.39 -0.210 0.57941E+04 204 montmorillonite-Na -1.96 -4.69 -2.73 -0.167 0.46626E+04 205 nontronite-Ca 3.28 3.02 -0.26 -0.017 0.44753E+03 206 nontronite-H 2.60 1.01 -1.58 -0.106 0.26999E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11271E+04 224 tobermorite 9.84 6.79 -3.05 -0.832 0.52080E+04 233 boehmite 4.43 1.86 -2.57 -0.428 0.43895E+04 235 ferrous-oxide 9.82 6.64 -3.18 -0.796 0.54341E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.415 0.21233E+04 242 an20ab80 2.08 1.58 -0.50 -0.038 0.85334E+03 243 an25ab75 2.71 2.06 -0.65 -0.050 0.11146E+04 244 an30ab70 3.34 2.53 -0.81 -0.062 0.13842E+04 245 tr.625ac.25prg.125 45.31 40.67 -4.64 -0.125 0.79147E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 19.1990000 g New total amount of reactant added: 19.5990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8632E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 19.5990000 Water: Moles liquid = 0.5536E+02 kg liquid = 0.9974E+00 Moles total = 0.5526E+02 kg total = 0.9956E+00 Activity = 1.0000 Stoichiometric ionic strength = .5200703E-02 Osmotic coef. = 0.9618 True ionic strength = .9383215E-02 Chg. balance for total moles = 0.8632E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15252E-09 -9.8167 0.13371E-09 -9.8738 0.87668E+00 -0.0572 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13802E-03 -3.8601 0.12061E-03 -3.9186 0.87386E+00 -0.0586 4 SO4-- 0.25554E-04 -4.5925 0.15826E-04 -4.8006 0.61930E+00 -0.2081 5 HCO3- 0.66252E-05 -5.1788 0.57939E-05 -5.2370 0.87454E+00 -0.0582 6 HS- 0.13398E-11 -11.8729 0.11709E-11 -11.9315 0.87393E+00 -0.0585 7 Al+++ 0.49998E-27 -27.3010 0.17273E-27 -27.7626 0.34547E+00 -0.4616 8 H4SiO4 0.47501E-03 -3.3233 0.47501E-03 -3.3233 0.10000E+01 0.0000 9 Ca++ 0.39960E-07 -7.3984 0.24651E-07 -7.6082 0.61688E+00 -0.2098 10 Mg++ 0.21863E-10 -10.6603 0.13454E-10 -10.8712 0.61538E+00 -0.2109 11 Fe++ 0.12724E-12 -12.8954 0.78344E-13 -13.1060 0.61574E+00 -0.2106 12 K+ 0.73040E-04 -4.1364 0.63885E-04 -4.1946 0.87465E+00 -0.0582 13 Na+ 0.92775E-02 -2.0326 0.81065E-02 -2.0912 0.87378E+00 -0.0586 14 Mn++ 0.17263E-10 -10.7629 0.10634E-10 -10.9733 0.61601E+00 -0.2104 15 HPO4-- 0.53331E-06 -6.2730 0.33030E-06 -6.4811 0.61934E+00 -0.2081 16 HSiO3- 0.39664E-02 -2.4016 0.34661E-02 -2.4602 0.87386E+00 -0.0586 17 Ca(HSiO3)+ 0.21884E-08 -8.6599 0.19143E-08 -8.7180 0.87475E+00 -0.0581 18 Mg(HSiO3)+ 0.14864E-11 -11.8279 0.13003E-11 -11.8860 0.87475E+00 -0.0581 19 NaHSiO3,aq 0.44626E-03 -3.3504 0.44626E-03 -3.3504 0.10000E+01 0.0000 20 AlO+ 0.14258E-14 -14.8459 0.12472E-14 -14.9041 0.87475E+00 -0.0581 22 HAlO2,aq 0.18666E-08 -8.7290 0.18666E-08 -8.7290 0.10000E+01 0.0000 23 AlO2- 0.35705E-04 -4.4473 0.31171E-04 -4.5062 0.87301E+00 -0.0590 24 CH4,aq 0.42133E-18 -18.3754 0.42066E-18 -18.3761 0.99840E+00 -0.0007 29 CO,aq 0.73478E-19 -19.1338 0.73478E-19 -19.1338 0.10000E+01 0.0000 30 CO2,aq 0.15645E-08 -8.8056 0.15620E-08 -8.8063 0.99840E+00 -0.0007 31 CO3-2 0.64768E-05 -5.1886 0.40065E-05 -5.3972 0.61859E+00 -0.2086 32 CaCO3,aq 0.12096E-08 -8.9174 0.12096E-08 -8.9174 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41140E-11 -11.3857 0.35988E-11 -11.4438 0.87475E+00 -0.0581 34 CaCl+ 0.54160E-11 -11.2663 0.47377E-11 -11.3244 0.87475E+00 -0.0581 35 CaCl2,aq 0.13305E-15 -15.8760 0.13305E-15 -15.8760 0.10000E+01 0.0000 36 CaOH+ 0.14861E-07 -7.8280 0.13000E-07 -7.8861 0.87475E+00 -0.0581 37 CaSO4,aq 0.12155E-09 -9.9152 0.12155E-09 -9.9152 0.10000E+01 0.0000 38 HCl,aq 0.30334E-14 -14.5181 0.30334E-14 -14.5181 0.10000E+01 0.0000 43 FeCl+ 0.16824E-16 -16.7741 0.14717E-16 -16.8322 0.87475E+00 -0.0581 46 FeO,aq 0.17328E-09 -9.7612 0.17328E-09 -9.7612 0.10000E+01 0.0000 47 FeOH+ 0.22206E-10 -10.6535 0.19425E-10 -10.7116 0.87475E+00 -0.0581 48 HFeO2- 0.15952E-07 -7.7972 0.13939E-07 -7.8558 0.87386E+00 -0.0586 49 FeO+ 0.12644E-14 -14.8981 0.11061E-14 -14.9562 0.87475E+00 -0.0581 51 FeO2- 0.13914E-07 -7.8565 0.12159E-07 -7.9151 0.87386E+00 -0.0586 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.18294E-08 -8.7377 0.18265E-08 -8.7384 0.99840E+00 -0.0007 54 KCl,aq 0.13643E-09 -9.8651 0.13643E-09 -9.8651 0.10000E+01 0.0000 55 KHSO4,aq 0.36175E-18 -18.4416 0.36175E-18 -18.4416 0.10000E+01 0.0000 56 KOH,aq 0.20829E-06 -6.6813 0.20829E-06 -6.6813 0.10000E+01 0.0000 57 KSO4- 0.17825E-07 -7.7490 0.15576E-07 -7.8075 0.87386E+00 -0.0586 58 MgCO3,aq 0.16496E-12 -12.7826 0.16496E-12 -12.7826 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22896E-14 -14.6402 0.20029E-14 -14.6983 0.87475E+00 -0.0581 60 MgCl+ 0.26835E-14 -14.5713 0.23474E-14 -14.6294 0.87475E+00 -0.0581 61 MgOH+ 0.44934E-10 -10.3474 0.39306E-10 -10.4055 0.87475E+00 -0.0581 63 MnO,aq 0.62789E-09 -9.2021 0.62789E-09 -9.2021 0.10000E+01 0.0000 64 MnOH+ 0.28000E-09 -9.5528 0.24493E-09 -9.6110 0.87475E+00 -0.0581 65 MnO2-2 0.19635E-11 -11.7070 0.12146E-11 -11.9156 0.61859E+00 -0.2086 66 HMnO2- 0.40265E-10 -10.3951 0.35186E-10 -10.4536 0.87386E+00 -0.0586 69 MnCl+ 0.88739E-14 -14.0519 0.77625E-14 -14.1100 0.87475E+00 -0.0581 70 MnSO4,aq 0.47694E-13 -13.3215 0.47694E-13 -13.3215 0.10000E+01 0.0000 71 NaCl,aq 0.31925E-06 -6.4959 0.31925E-06 -6.4959 0.10000E+01 0.0000 72 NaOH,aq 0.26640E-04 -4.5745 0.26640E-04 -4.5745 0.10000E+01 0.0000 74 OH- 0.51386E-02 -2.2892 0.44861E-02 -2.3481 0.87301E+00 -0.0590 79 HPO3-2 0.30804E-17 -17.5114 0.19055E-17 -17.7200 0.61859E+00 -0.2086 82 H3PO4,aq 0.38018E-16 -16.4200 0.38018E-16 -16.4200 0.10000E+01 0.0000 83 H2PO4- 0.88563E-09 -9.0527 0.77430E-09 -9.1111 0.87430E+00 -0.0583 84 PO4-3 0.60829E-08 -8.2159 0.21573E-08 -8.6661 0.35466E+00 -0.4502 87 H2P2O7-2 0.75855E-19 -19.1200 0.46923E-19 -19.3286 0.61859E+00 -0.2086 88 HP2O7-3 0.20821E-15 -15.6815 0.71960E-16 -16.1429 0.34561E+00 -0.4614 89 P2O7-4 0.85356E-15 -15.0688 0.13277E-15 -15.8769 0.15555E+00 -0.8081 90 H2S,aq 0.47116E-15 -15.3268 0.47041E-15 -15.3275 0.99840E+00 -0.0007 97 SO3-2 0.63223E-14 -14.1991 0.39412E-14 -14.4044 0.62338E+00 -0.2052 98 HSO3- 0.35291E-16 -16.4523 0.30840E-16 -16.5109 0.87386E+00 -0.0586 99 HSO4- 0.22434E-11 -11.6491 0.19634E-11 -11.7070 0.87520E+00 -0.0579 Charge balance for all species = 0.8518E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1525181E-09 -.9727569E-02 -.9797861E+01 0.0000 2 H2O 0.1000000E+01 0.5550907E+02 0.9993043E+06 0.0000 3 Cl- 0.1380209E-03 0.1383403E-03 0.4901106E+01 5.9552 4 SO4-- 0.2555420E-04 0.2557346E-04 0.2454887E+01 14.9470 5 HCO3- 0.6625152E-05 0.1310468E-04 0.7990448E+00 4.6368 6 HS- 0.1339846E-11 -.1306045E-08 -.4316293E-04 -2.0576 7 Al+++ 0.4999826E-27 0.3570700E-04 0.9627460E+00 1.8589 8 H4SiO4 0.4750080E-03 0.4887682E-02 0.4694487E+03 -3.3233 9 Ca++ 0.3996008E-07 0.5835016E-07 0.2336901E-02 12.1395 10 Mg++ 0.2186271E-10 0.6845331E-10 0.1663058E-05 8.8765 11 Fe++ 0.1272364E-12 0.3026522E-07 0.1689025E-02 6.6417 12 K+ 0.7304038E-04 0.7326663E-04 0.2862843E+01 5.6792 13 Na+ 0.9277455E-02 0.9750673E-02 0.2240073E+03 7.7827 14 Mn++ 0.1726281E-10 0.9674435E-09 0.5311176E-04 8.7744 15 HPO4-- 0.5333141E-06 0.5402826E-06 0.5181906E-01 13.2666 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3245173E+00 -.9701823E-02 -.3148155E+00 0.0000000E+00 2 H2O 0.5526257E+02 0.5536216E+02 -.9958729E-01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5686596E-03 0.2550577E-04 0.5431538E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5431551E-03 -.1302588E-08 -.5431538E-03 0.0000000E+00 7 Al+++ 0.6390727E-01 0.3561249E-04 0.6387166E-01 0.0000000E+00 8 H4SiO4 0.2040801E+00 0.4874745E-02 0.1992054E+00 0.0000000E+00 9 Ca++ 0.2255612E-01 0.5819572E-07 0.2255606E-01 0.0000000E+00 10 Mg++ 0.1555476E-01 0.6827213E-10 0.1555476E-01 0.0000000E+00 11 Fe++ 0.1397426E-01 0.3018512E-07 0.1397423E-01 0.0000000E+00 12 K+ 0.4161146E-02 0.7307272E-04 0.4088074E-02 0.0000000E+00 13 Na+ 0.2476159E-01 0.9724866E-02 0.1503673E-01 0.0000000E+00 14 Mn++ 0.3398191E-03 0.9648829E-09 0.3398182E-03 0.0000000E+00 15 HPO4-- 0.1159786E-03 0.5388527E-06 0.1154397E-03 0.0000000E+00 Chg. balance for solid moles: -.6885E-17 Mass of aqueous solution: 0.998060E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 19.5990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1493E-01 -1.826 3.915 0.593 18.30 1.503 andradite 0.1642E-02 -2.785 0.8345 -0.079 3.902 0.2168 grossular 0.8040E-04 -4.095 0.3622E-01 -1.441 0.1693 0.1008E-01 apatite-OH 0.3848E-04 -4.415 0.1933E-01 -1.714 0.9036E-01 0.6142E-02 clinochlore 0.3111E-02 -2.507 1.729 0.238 8.084 0.6577 daphnite 0.1896E-02 -2.722 1.353 0.131 6.324 0.4099 chlorite-Mn 0.6796E-04 -4.168 0.4818E-01 -1.317 0.2253 0.1536E-01 hematite 0.2043E-03 -3.690 0.3263E-01 -1.486 0.1525 0.6184E-02 microcline 0.4073E-02 -2.390 1.134 0.055 5.300 0.4429 stilbite 0.1720E-01 -1.765 12.12 1.083 56.65 5.652 stilpnomelane-Fe 0.2987E-04 -4.525 0.3220E-01 -1.492 0.1505 0.1112E-01 nontronite-Na 0.3261E-03 -3.487 0.1387 -0.858 0.6483 0.4308E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9533E+00 0.9533E+00 1.0000 -0.021 grossular 0.4667E-01 0.4667E-01 1.0000 -1.331 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6130E+00 0.6130E+00 1.0000 -0.213 daphnite 0.3736E+00 0.3736E+00 1.0000 -0.428 chlorite-Mn 0.1339E-01 0.1339E-01 1.0000 -1.873 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 21.390344 g Volume = 8.974215 cm3 Porosity: -1.5229% V(tot) - V(min): -.13461E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 19.5990000 g log = 1.2922 Original solution: 1000.0103000 g Original solution / Rock added: 51.02 (Water/Rock Ratio), log = 1.7078 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1687E-06 1.0073 0.1788E-06 0.1775E-06 CH4,gas 0.6243E-15 1.0129 0.6652E-15 0.6567E-15 H2,gas 0.2380E-05 1.0006 0.2505E-05 0.2504E-05 H2S,gas 0.1310E-13 0.9959 0.1372E-13 0.1378E-13 S2,gas 0.1068E-35 1.0000 0.1123E-35 0.1123E-35 CO,gas 0.1103E-15 1.0000 0.1160E-15 0.1160E-15 SO3,gas 0.1006E-39 1.0000 0.1058E-39 0.1058E-39 SO2,gas 0.9530E-23 1.0000 0.1002E-22 0.1002E-22 HCl,gas 0.5092E-17 1.0000 0.5356E-17 0.5356E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.15165E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.916 0.14936E+05 -6.748 3 CH4,gas 4.81 -12.37 -17.18 -4.294 0.29329E+05 -15.177 4 H2,gas 8.29 0.69 -7.60 -4.344 0.12979E+05 -5.601 5 H2S,gas -5.94 -21.81 -15.86 -7.931 0.27085E+05 -13.863 6 S2,gas -7.03 -44.98 -37.95 -5.838 0.64798E+05 -35.949 7 CO,gas 3.51 -14.43 -17.94 -5.519 0.30624E+05 -15.935 8 SO3,gas 17.43 -24.55 -41.98 -10.494 0.71672E+05 -39.976 9 SO2,gas 1.14 -23.86 -25.00 -6.666 0.42685E+05 -22.999 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32905E+05 -17.271 11 acmite 7.74 7.43 -0.30 -0.031 0.51654E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.07 -4.48 -0.224 0.76477E+04 20 analcite 3.37 2.99 -0.38 -0.042 0.64150E+03 21 andalusite 5.06 0.39 -4.67 -0.467 0.79704E+04 26 annite 20.21 17.49 -2.72 -0.151 0.46376E+04 27 phlogopite 27.15 24.20 -2.95 -0.164 0.50351E+04 29 anorthite 12.80 9.21 -3.59 -0.276 0.61248E+04 35 aragonite 0.99 -2.97 -3.96 -1.319 0.67575E+04 36 brucite 12.58 8.88 -3.70 -0.740 0.63178E+04 37 calcite 0.83 -2.97 -3.80 -1.268 0.64961E+04 38 carnegieite-low 9.06 6.32 -2.75 -0.392 0.46893E+04 39 carnegieite-high 10.13 6.32 -3.82 -0.545 0.65161E+04 40 carpholite-Mg 8.65 5.95 -2.70 -0.180 0.46148E+04 41 carpholite-Fe 6.78 3.71 -3.07 -0.205 0.52421E+04 42 celadonite 5.40 3.12 -2.28 -0.134 0.38915E+04 43 celadonite-Fe 3.94 0.89 -3.05 -0.179 0.52084E+04 44 chrysotile 23.94 19.98 -3.95 -0.330 0.67520E+04 50 chloritoid-Mg 13.26 9.27 -3.99 -0.266 0.68133E+04 51 chloritoid-Fe 9.24 7.04 -2.20 -0.147 0.37608E+04 52 chloritoid-Mn 11.46 9.17 -2.29 -0.153 0.39176E+04 54 coesite -2.37 -3.32 -0.95 -0.318 0.16288E+04 59 corundum 8.43 3.72 -4.72 -0.429 0.80519E+04 61 cristobalite -2.55 -3.32 -0.77 -0.258 0.13217E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.86 -1.04 -0.173 0.17710E+04 67 diopside 16.22 14.37 -1.85 -0.185 0.31521E+04 68 hedenbergite 14.24 12.13 -2.11 -0.211 0.36025E+04 75 epidote 24.78 24.33 -0.45 -0.022 0.76760E+03 76 clinozoisite 22.92 19.89 -3.04 -0.138 0.51829E+04 77 epidote-Fe 29.94 28.77 -1.17 -0.061 0.19998E+04 78 fayalite 14.08 9.96 -4.12 -0.588 0.70329E+04 79 ferrosilite 11.19 6.64 -4.55 -0.455 0.77706E+04 83 gibbsite 4.10 1.86 -2.24 -0.320 0.38222E+04 84 glaucophane 23.11 19.33 -3.78 -0.102 0.64616E+04 85 glaucophane-Fe 17.42 12.62 -4.80 -0.130 0.81881E+04 87 greenalite 16.19 13.28 -2.92 -0.243 0.49786E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.99 -1.26 -0.126 0.21445E+04 96 julgoldite 70.57 67.10 -3.48 -0.090 0.59353E+04 97 kalsilite 7.62 4.21 -3.41 -0.486 0.58147E+04 98 kaolinite -1.27 -2.93 -1.66 -0.151 0.28271E+04 99 kyanite 4.93 0.39 -4.54 -0.454 0.77472E+04 101 laumontite 2.97 2.56 -0.41 -0.027 0.70092E+03 102 lawsonite 9.68 9.21 -0.47 -0.031 0.79864E+03 103 leucite 4.17 0.89 -3.28 -0.328 0.55939E+04 105 lizardite 23.29 19.98 -3.30 -0.275 0.56423E+04 107 magnetite 20.13 19.24 -0.89 -0.073 0.15256E+04 108 minnesotaite 10.46 6.63 -3.83 -0.225 0.65377E+04 110 magnesioferrite 26.26 21.47 -4.78 -0.390 0.81671E+04 113 margarite 17.45 12.93 -4.52 -0.181 0.77236E+04 120 muscovite 2.68 1.29 -1.39 -0.082 0.23789E+04 121 paragonite 4.34 3.39 -0.95 -0.056 0.16174E+04 122 nepheline 8.38 6.32 -2.06 -0.294 0.35172E+04 128 periclase-Fe 11.64 6.64 -5.00 -1.249 0.85330E+04 134 phlogopite-Na 29.73 26.30 -3.43 -0.191 0.58570E+04 136 prehnite 19.47 18.03 -1.44 -0.085 0.24579E+04 137 prehnite-Fe 22.59 22.47 -0.12 -0.007 0.20487E+03 138 pumpellyite-Fe 46.47 44.55 -1.92 -0.043 0.32721E+04 139 pumpellyite-Mg 49.19 46.79 -2.40 -0.053 0.41064E+04 145 pyroxmangite 7.42 5.45 -1.96 -0.393 0.33551E+04 146 pyrophyllite -6.10 -9.58 -3.48 -0.217 0.59376E+04 147 quartz -2.98 -3.32 -0.34 -0.114 0.58276E+03 152 rhodonite 7.46 5.45 -2.01 -0.402 0.34344E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.39 -4.93 -0.493 0.84126E+04 165 stilpnomelane-Mg 27.60 24.35 -3.24 -0.097 0.55369E+04 171 talc 16.55 13.34 -3.22 -0.189 0.54930E+04 174 tephroite 18.11 14.23 -3.89 -0.555 0.66377E+04 177 topaz-H 4.67 0.39 -4.27 -0.388 0.72962E+04 178 tridymite -2.61 -3.32 -0.71 -0.236 0.12101E+04 187 wairakite 4.06 2.56 -1.49 -0.088 0.25517E+04 188 walstromite 11.53 8.82 -2.71 -0.542 0.46301E+04 189 wollastonite 10.48 8.82 -1.67 -0.333 0.28440E+04 190 pseudo-wollastonite 11.02 8.82 -2.20 -0.441 0.37626E+04 191 zoisite 22.96 19.89 -3.08 -0.140 0.52555E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.86 -4.30 -0.266 0.73467E+04 195 beidellite-K -1.44 -5.99 -4.56 -0.279 0.77795E+04 196 beidellite-Mg -1.71 -6.40 -4.69 -0.290 0.80146E+04 197 beidellite-Na -1.26 -5.30 -4.04 -0.247 0.68983E+04 199 chalcedony -2.79 -3.32 -0.53 -0.176 0.90308E+03 201 montmorillonite-Ca -2.21 -5.26 -3.04 -0.188 0.51951E+04 202 montmorillonite-K -2.16 -5.39 -3.22 -0.197 0.55058E+04 203 montmorillonite-Mg -2.40 -5.80 -3.39 -0.210 0.57941E+04 204 montmorillonite-Na -1.96 -4.69 -2.73 -0.167 0.46626E+04 205 nontronite-Ca 3.28 3.02 -0.26 -0.017 0.44753E+03 206 nontronite-H 2.60 1.01 -1.58 -0.106 0.26999E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11271E+04 224 tobermorite 9.84 6.79 -3.05 -0.832 0.52080E+04 233 boehmite 4.43 1.86 -2.57 -0.428 0.43895E+04 235 ferrous-oxide 9.82 6.64 -3.18 -0.796 0.54341E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.415 0.21233E+04 242 an20ab80 2.08 1.58 -0.50 -0.038 0.85334E+03 243 an25ab75 2.71 2.06 -0.65 -0.050 0.11146E+04 244 an30ab70 3.34 2.53 -0.81 -0.062 0.13842E+04 245 tr.625ac.25prg.125 45.31 40.67 -4.64 -0.125 0.79147E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 19.5990000 g New total amount of reactant added: 19.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.8639E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 19.9990000 Water: Moles liquid = 0.5536E+02 kg liquid = 0.9973E+00 Moles total = 0.5526E+02 kg total = 0.9955E+00 Activity = 1.0000 Stoichiometric ionic strength = .5200710E-02 Osmotic coef. = 0.9618 True ionic strength = .9383221E-02 Chg. balance for total moles = 0.8639E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15252E-09 -9.8167 0.13371E-09 -9.8738 0.87668E+00 -0.0572 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13803E-03 -3.8600 0.12062E-03 -3.9186 0.87386E+00 -0.0586 4 SO4-- 0.25555E-04 -4.5925 0.15826E-04 -4.8006 0.61930E+00 -0.2081 5 HCO3- 0.66254E-05 -5.1788 0.57942E-05 -5.2370 0.87454E+00 -0.0582 6 HS- 0.13399E-11 -11.8729 0.11710E-11 -11.9315 0.87393E+00 -0.0585 7 Al+++ 0.49998E-27 -27.3010 0.17273E-27 -27.7626 0.34546E+00 -0.4616 8 H4SiO4 0.47501E-03 -3.3233 0.47501E-03 -3.3233 0.10000E+01 0.0000 9 Ca++ 0.39960E-07 -7.3984 0.24651E-07 -7.6082 0.61688E+00 -0.2098 10 Mg++ 0.21863E-10 -10.6603 0.13454E-10 -10.8712 0.61538E+00 -0.2109 11 Fe++ 0.12724E-12 -12.8954 0.78344E-13 -13.1060 0.61574E+00 -0.2106 12 K+ 0.73040E-04 -4.1364 0.63885E-04 -4.1946 0.87465E+00 -0.0582 13 Na+ 0.92775E-02 -2.0326 0.81065E-02 -2.0912 0.87378E+00 -0.0586 14 Mn++ 0.17263E-10 -10.7629 0.10634E-10 -10.9733 0.61601E+00 -0.2104 15 HPO4-- 0.53331E-06 -6.2730 0.33030E-06 -6.4811 0.61934E+00 -0.2081 16 HSiO3- 0.39664E-02 -2.4016 0.34661E-02 -2.4602 0.87386E+00 -0.0586 17 Ca(HSiO3)+ 0.21884E-08 -8.6599 0.19143E-08 -8.7180 0.87475E+00 -0.0581 18 Mg(HSiO3)+ 0.14864E-11 -11.8279 0.13003E-11 -11.8860 0.87475E+00 -0.0581 19 NaHSiO3,aq 0.44626E-03 -3.3504 0.44626E-03 -3.3504 0.10000E+01 0.0000 20 AlO+ 0.14258E-14 -14.8459 0.12472E-14 -14.9041 0.87475E+00 -0.0581 22 HAlO2,aq 0.18666E-08 -8.7290 0.18666E-08 -8.7290 0.10000E+01 0.0000 23 AlO2- 0.35705E-04 -4.4473 0.31171E-04 -4.5062 0.87301E+00 -0.0590 24 CH4,aq 0.42135E-18 -18.3754 0.42067E-18 -18.3761 0.99840E+00 -0.0007 29 CO,aq 0.73481E-19 -19.1338 0.73481E-19 -19.1338 0.10000E+01 0.0000 30 CO2,aq 0.15645E-08 -8.8056 0.15620E-08 -8.8063 0.99840E+00 -0.0007 31 CO3-2 0.64770E-05 -5.1886 0.40066E-05 -5.3972 0.61859E+00 -0.2086 32 CaCO3,aq 0.12096E-08 -8.9173 0.12096E-08 -8.9173 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41142E-11 -11.3857 0.35989E-11 -11.4438 0.87475E+00 -0.0581 34 CaCl+ 0.54162E-11 -11.2663 0.47379E-11 -11.3244 0.87475E+00 -0.0581 35 CaCl2,aq 0.13306E-15 -15.8760 0.13306E-15 -15.8760 0.10000E+01 0.0000 36 CaOH+ 0.14861E-07 -7.8280 0.13000E-07 -7.8861 0.87475E+00 -0.0581 37 CaSO4,aq 0.12155E-09 -9.9152 0.12155E-09 -9.9152 0.10000E+01 0.0000 38 HCl,aq 0.30335E-14 -14.5181 0.30335E-14 -14.5181 0.10000E+01 0.0000 43 FeCl+ 0.16825E-16 -16.7740 0.14718E-16 -16.8322 0.87475E+00 -0.0581 46 FeO,aq 0.17328E-09 -9.7612 0.17328E-09 -9.7612 0.10000E+01 0.0000 47 FeOH+ 0.22206E-10 -10.6535 0.19425E-10 -10.7116 0.87475E+00 -0.0581 48 HFeO2- 0.15952E-07 -7.7972 0.13939E-07 -7.8558 0.87386E+00 -0.0586 49 FeO+ 0.12644E-14 -14.8981 0.11061E-14 -14.9562 0.87475E+00 -0.0581 51 FeO2- 0.13914E-07 -7.8565 0.12159E-07 -7.9151 0.87386E+00 -0.0586 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.18294E-08 -8.7377 0.18265E-08 -8.7384 0.99840E+00 -0.0007 54 KCl,aq 0.13644E-09 -9.8651 0.13644E-09 -9.8651 0.10000E+01 0.0000 55 KHSO4,aq 0.36176E-18 -18.4416 0.36176E-18 -18.4416 0.10000E+01 0.0000 56 KOH,aq 0.20829E-06 -6.6813 0.20829E-06 -6.6813 0.10000E+01 0.0000 57 KSO4- 0.17825E-07 -7.7490 0.15577E-07 -7.8075 0.87386E+00 -0.0586 58 MgCO3,aq 0.16497E-12 -12.7826 0.16497E-12 -12.7826 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22897E-14 -14.6402 0.20030E-14 -14.6983 0.87475E+00 -0.0581 60 MgCl+ 0.26836E-14 -14.5713 0.23475E-14 -14.6294 0.87475E+00 -0.0581 61 MgOH+ 0.44934E-10 -10.3474 0.39306E-10 -10.4055 0.87475E+00 -0.0581 63 MnO,aq 0.62789E-09 -9.2021 0.62789E-09 -9.2021 0.10000E+01 0.0000 64 MnOH+ 0.28000E-09 -9.5528 0.24493E-09 -9.6110 0.87475E+00 -0.0581 65 MnO2-2 0.19635E-11 -11.7070 0.12146E-11 -11.9156 0.61859E+00 -0.2086 66 HMnO2- 0.40265E-10 -10.3951 0.35186E-10 -10.4536 0.87386E+00 -0.0586 69 MnCl+ 0.88743E-14 -14.0519 0.77628E-14 -14.1100 0.87475E+00 -0.0581 70 MnSO4,aq 0.47696E-13 -13.3215 0.47696E-13 -13.3215 0.10000E+01 0.0000 71 NaCl,aq 0.31927E-06 -6.4958 0.31927E-06 -6.4958 0.10000E+01 0.0000 72 NaOH,aq 0.26640E-04 -4.5745 0.26640E-04 -4.5745 0.10000E+01 0.0000 74 OH- 0.51386E-02 -2.2892 0.44861E-02 -2.3481 0.87301E+00 -0.0590 79 HPO3-2 0.30804E-17 -17.5114 0.19055E-17 -17.7200 0.61859E+00 -0.2086 82 H3PO4,aq 0.38018E-16 -16.4200 0.38018E-16 -16.4200 0.10000E+01 0.0000 83 H2PO4- 0.88563E-09 -9.0527 0.77430E-09 -9.1111 0.87430E+00 -0.0583 84 PO4-3 0.60829E-08 -8.2159 0.21573E-08 -8.6661 0.35466E+00 -0.4502 87 H2P2O7-2 0.75855E-19 -19.1200 0.46923E-19 -19.3286 0.61859E+00 -0.2086 88 HP2O7-3 0.20821E-15 -15.6815 0.71960E-16 -16.1429 0.34561E+00 -0.4614 89 P2O7-4 0.85355E-15 -15.0688 0.13277E-15 -15.8769 0.15555E+00 -0.8081 90 H2S,aq 0.47118E-15 -15.3268 0.47043E-15 -15.3275 0.99840E+00 -0.0007 97 SO3-2 0.63226E-14 -14.1991 0.39414E-14 -14.4044 0.62338E+00 -0.2052 98 HSO3- 0.35293E-16 -16.4523 0.30841E-16 -16.5109 0.87386E+00 -0.0586 99 HSO4- 0.22435E-11 -11.6491 0.19635E-11 -11.7070 0.87520E+00 -0.0579 Charge balance for all species = 0.8544E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1525181E-09 -.9727565E-02 -.9797857E+01 0.0000 2 H2O 0.1000000E+01 0.5550907E+02 0.9993043E+06 0.0000 3 Cl- 0.1380265E-03 0.1383459E-03 0.4901303E+01 5.9552 4 SO4-- 0.2555523E-04 0.2557449E-04 0.2454986E+01 14.9470 5 HCO3- 0.6625419E-05 0.1310521E-04 0.7990769E+00 4.6368 6 HS- 0.1339900E-11 -.1306044E-08 -.4316291E-04 -2.0576 7 Al+++ 0.4999834E-27 0.3570699E-04 0.9627456E+00 1.8589 8 H4SiO4 0.4750080E-03 0.4887680E-02 0.4694486E+03 -3.3233 9 Ca++ 0.3996012E-07 0.5835026E-07 0.2336905E-02 12.1395 10 Mg++ 0.2186273E-10 0.6845336E-10 0.1663059E-05 8.8765 11 Fe++ 0.1272366E-12 0.3026521E-07 0.1689024E-02 6.6417 12 K+ 0.7304042E-04 0.7326667E-04 0.2862844E+01 5.6792 13 Na+ 0.9277459E-02 0.9750678E-02 0.2240074E+03 7.7827 14 Mn++ 0.1726283E-10 0.9674437E-09 0.5311178E-04 8.7744 15 HPO4-- 0.5333137E-06 0.5402822E-06 0.5181902E-01 13.2666 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3311407E+00 -.9701429E-02 -.3214393E+00 0.0000000E+00 2 H2O 0.5525755E+02 0.5535993E+02 -.1023780E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5797449E-03 0.2550577E-04 0.5542392E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5542405E-03 -.1302535E-08 -.5542392E-03 0.0000000E+00 7 Al+++ 0.6521157E-01 0.3561105E-04 0.6517596E-01 0.0000000E+00 8 H4SiO4 0.2082452E+00 0.4874548E-02 0.2033707E+00 0.0000000E+00 9 Ca++ 0.2301617E-01 0.5819349E-07 0.2301612E-01 0.0000000E+00 10 Mg++ 0.1587222E-01 0.6826944E-10 0.1587222E-01 0.0000000E+00 11 Fe++ 0.1425946E-01 0.3018389E-07 0.1425943E-01 0.0000000E+00 12 K+ 0.4246072E-02 0.7306982E-04 0.4173002E-02 0.0000000E+00 13 Na+ 0.2526369E-01 0.9724480E-02 0.1553921E-01 0.0000000E+00 14 Mn++ 0.3467546E-03 0.9648444E-09 0.3467536E-03 0.0000000E+00 15 HPO4-- 0.1183456E-03 0.5388306E-06 0.1178068E-03 0.0000000E+00 Chg. balance for solid moles: -.3293E-16 Mass of aqueous solution: 0.998020E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 19.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1542E-01 -1.812 4.042 0.607 18.52 1.552 andradite 0.1707E-02 -2.768 0.8676 -0.062 3.975 0.2254 grossular 0.8359E-04 -4.078 0.3765E-01 -1.424 0.1725 0.1048E-01 apatite-OH 0.3927E-04 -4.406 0.1973E-01 -1.705 0.9037E-01 0.6268E-02 clinochlore 0.3174E-02 -2.498 1.764 0.247 8.084 0.6711 daphnite 0.1935E-02 -2.713 1.380 0.140 6.324 0.4183 chlorite-Mn 0.6935E-04 -4.159 0.4917E-01 -1.308 0.2253 0.1567E-01 hematite 0.1369E-03 -3.864 0.2187E-01 -1.660 0.1002 0.4144E-02 microcline 0.4158E-02 -2.381 1.157 0.063 5.302 0.4521 stilbite 0.1745E-01 -1.758 12.30 1.090 56.33 5.735 stilpnomelane-Fe 0.3048E-04 -4.516 0.3286E-01 -1.483 0.1505 0.1135E-01 nontronite-Na 0.3727E-03 -3.429 0.1585 -0.800 0.7262 0.4924E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9533E+00 0.9533E+00 1.0000 -0.021 grossular 0.4667E-01 0.4667E-01 1.0000 -1.331 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6130E+00 0.6130E+00 1.0000 -0.213 daphnite 0.3736E+00 0.3736E+00 1.0000 -0.428 chlorite-Mn 0.1339E-01 0.1339E-01 1.0000 -1.873 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 21.827190 g Volume = 9.150594 cm3 Porosity: -1.6778% V(tot) - V(min): -.15099E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 19.9990000 g log = 1.3010 Original solution: 1000.0103000 g Original solution / Rock added: 50.00 (Water/Rock Ratio), log = 1.6990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1687E-06 1.0073 0.1788E-06 0.1775E-06 CH4,gas 0.6243E-15 1.0129 0.6652E-15 0.6568E-15 H2,gas 0.2380E-05 1.0006 0.2505E-05 0.2504E-05 H2S,gas 0.1310E-13 0.9959 0.1372E-13 0.1378E-13 S2,gas 0.1068E-35 1.0000 0.1123E-35 0.1123E-35 CO,gas 0.1103E-15 1.0000 0.1160E-15 0.1160E-15 SO3,gas 0.1006E-39 1.0000 0.1058E-39 0.1058E-39 SO2,gas 0.9530E-23 1.0000 0.1002E-22 0.1002E-22 HCl,gas 0.5092E-17 1.0000 0.5356E-17 0.5356E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.15165E-10 116 microcline -2.43 -2.43 0.00 0.000 0.18957E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 0.90992E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.916 0.14936E+05 -6.748 3 CH4,gas 4.81 -12.37 -17.18 -4.294 0.29329E+05 -15.177 4 H2,gas 8.29 0.69 -7.60 -4.344 0.12979E+05 -5.601 5 H2S,gas -5.94 -21.81 -15.86 -7.931 0.27085E+05 -13.863 6 S2,gas -7.03 -44.98 -37.95 -5.838 0.64798E+05 -35.949 7 CO,gas 3.51 -14.43 -17.94 -5.519 0.30624E+05 -15.935 8 SO3,gas 17.43 -24.55 -41.98 -10.494 0.71672E+05 -39.976 9 SO2,gas 1.14 -23.86 -25.00 -6.666 0.42685E+05 -22.999 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32905E+05 -17.271 11 acmite 7.74 7.43 -0.30 -0.031 0.51654E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.07 -4.48 -0.224 0.76477E+04 20 analcite 3.37 2.99 -0.38 -0.042 0.64150E+03 21 andalusite 5.06 0.39 -4.67 -0.467 0.79704E+04 26 annite 20.21 17.49 -2.72 -0.151 0.46376E+04 27 phlogopite 27.15 24.20 -2.95 -0.164 0.50351E+04 29 anorthite 12.80 9.21 -3.59 -0.276 0.61248E+04 35 aragonite 0.99 -2.97 -3.96 -1.319 0.67574E+04 36 brucite 12.58 8.88 -3.70 -0.740 0.63178E+04 37 calcite 0.83 -2.97 -3.80 -1.268 0.64961E+04 38 carnegieite-low 9.06 6.32 -2.75 -0.392 0.46893E+04 39 carnegieite-high 10.13 6.32 -3.82 -0.545 0.65161E+04 40 carpholite-Mg 8.65 5.95 -2.70 -0.180 0.46148E+04 41 carpholite-Fe 6.78 3.71 -3.07 -0.205 0.52421E+04 42 celadonite 5.40 3.12 -2.28 -0.134 0.38915E+04 43 celadonite-Fe 3.94 0.89 -3.05 -0.179 0.52084E+04 44 chrysotile 23.94 19.98 -3.95 -0.330 0.67520E+04 50 chloritoid-Mg 13.26 9.27 -3.99 -0.266 0.68133E+04 51 chloritoid-Fe 9.24 7.04 -2.20 -0.147 0.37608E+04 52 chloritoid-Mn 11.46 9.17 -2.29 -0.153 0.39176E+04 54 coesite -2.37 -3.32 -0.95 -0.318 0.16288E+04 59 corundum 8.43 3.72 -4.72 -0.429 0.80519E+04 61 cristobalite -2.55 -3.32 -0.77 -0.258 0.13217E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.86 -1.04 -0.173 0.17710E+04 67 diopside 16.22 14.37 -1.85 -0.185 0.31521E+04 68 hedenbergite 14.24 12.13 -2.11 -0.211 0.36025E+04 75 epidote 24.78 24.33 -0.45 -0.022 0.76760E+03 76 clinozoisite 22.92 19.89 -3.04 -0.138 0.51829E+04 77 epidote-Fe 29.94 28.77 -1.17 -0.061 0.19998E+04 78 fayalite 14.08 9.96 -4.12 -0.588 0.70329E+04 79 ferrosilite 11.19 6.64 -4.55 -0.455 0.77706E+04 83 gibbsite 4.10 1.86 -2.24 -0.320 0.38222E+04 84 glaucophane 23.11 19.33 -3.78 -0.102 0.64616E+04 85 glaucophane-Fe 17.42 12.62 -4.80 -0.130 0.81881E+04 87 greenalite 16.19 13.28 -2.92 -0.243 0.49786E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.99 -1.26 -0.126 0.21445E+04 96 julgoldite 70.57 67.10 -3.48 -0.090 0.59353E+04 97 kalsilite 7.62 4.21 -3.41 -0.486 0.58147E+04 98 kaolinite -1.27 -2.93 -1.66 -0.151 0.28271E+04 99 kyanite 4.93 0.39 -4.54 -0.454 0.77472E+04 101 laumontite 2.97 2.56 -0.41 -0.027 0.70092E+03 102 lawsonite 9.68 9.21 -0.47 -0.031 0.79864E+03 103 leucite 4.17 0.89 -3.28 -0.328 0.55939E+04 105 lizardite 23.29 19.98 -3.30 -0.275 0.56423E+04 107 magnetite 20.13 19.24 -0.89 -0.073 0.15256E+04 108 minnesotaite 10.46 6.63 -3.83 -0.225 0.65377E+04 110 magnesioferrite 26.26 21.47 -4.78 -0.390 0.81671E+04 113 margarite 17.45 12.93 -4.52 -0.181 0.77236E+04 120 muscovite 2.68 1.29 -1.39 -0.082 0.23789E+04 121 paragonite 4.34 3.39 -0.95 -0.056 0.16174E+04 122 nepheline 8.38 6.32 -2.06 -0.294 0.35172E+04 128 periclase-Fe 11.64 6.64 -5.00 -1.249 0.85330E+04 134 phlogopite-Na 29.73 26.30 -3.43 -0.191 0.58570E+04 136 prehnite 19.47 18.03 -1.44 -0.085 0.24579E+04 137 prehnite-Fe 22.59 22.47 -0.12 -0.007 0.20487E+03 138 pumpellyite-Fe 46.47 44.55 -1.92 -0.043 0.32721E+04 139 pumpellyite-Mg 49.19 46.79 -2.40 -0.053 0.41064E+04 145 pyroxmangite 7.42 5.45 -1.96 -0.393 0.33551E+04 146 pyrophyllite -6.10 -9.58 -3.48 -0.217 0.59376E+04 147 quartz -2.98 -3.32 -0.34 -0.114 0.58276E+03 152 rhodonite 7.46 5.45 -2.01 -0.402 0.34344E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.39 -4.93 -0.493 0.84126E+04 165 stilpnomelane-Mg 27.60 24.35 -3.24 -0.097 0.55369E+04 171 talc 16.55 13.34 -3.22 -0.189 0.54930E+04 174 tephroite 18.11 14.23 -3.89 -0.555 0.66377E+04 177 topaz-H 4.67 0.39 -4.27 -0.388 0.72962E+04 178 tridymite -2.61 -3.32 -0.71 -0.236 0.12101E+04 187 wairakite 4.06 2.56 -1.49 -0.088 0.25517E+04 188 walstromite 11.53 8.82 -2.71 -0.542 0.46301E+04 189 wollastonite 10.48 8.82 -1.67 -0.333 0.28440E+04 190 pseudo-wollastonite 11.02 8.82 -2.20 -0.441 0.37626E+04 191 zoisite 22.96 19.89 -3.08 -0.140 0.52555E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.86 -4.30 -0.266 0.73467E+04 195 beidellite-K -1.44 -5.99 -4.56 -0.279 0.77795E+04 196 beidellite-Mg -1.71 -6.40 -4.69 -0.290 0.80146E+04 197 beidellite-Na -1.26 -5.30 -4.04 -0.247 0.68983E+04 199 chalcedony -2.79 -3.32 -0.53 -0.176 0.90308E+03 201 montmorillonite-Ca -2.21 -5.26 -3.04 -0.188 0.51951E+04 202 montmorillonite-K -2.16 -5.39 -3.22 -0.197 0.55058E+04 203 montmorillonite-Mg -2.40 -5.80 -3.39 -0.210 0.57941E+04 204 montmorillonite-Na -1.96 -4.69 -2.73 -0.167 0.46626E+04 205 nontronite-Ca 3.28 3.02 -0.26 -0.017 0.44753E+03 206 nontronite-H 2.60 1.01 -1.58 -0.106 0.26999E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11271E+04 224 tobermorite 9.84 6.79 -3.05 -0.832 0.52080E+04 233 boehmite 4.43 1.86 -2.57 -0.428 0.43895E+04 235 ferrous-oxide 9.82 6.64 -3.18 -0.796 0.54341E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.415 0.21233E+04 242 an20ab80 2.08 1.58 -0.50 -0.038 0.85334E+03 243 an25ab75 2.71 2.06 -0.65 -0.050 0.11146E+04 244 an30ab70 3.34 2.53 -0.81 -0.062 0.13842E+04 245 tr.625ac.25prg.125 45.31 40.67 -4.64 -0.125 0.79147E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 0.4000000 g Current total amount of reactant added: 19.9990000 g New total amount of reactant added: 20.3990000 g Mixing fraction reached given limit of 0.2000E+02 TOTMIX = 0.2040E+02 Execution stopped.