File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.33114E+00 0.15252E-09 0.8767 0.00000000E+00 H2O 2 0. 0.55258E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13803E-03 0.8739 0.00000000E+00 SO4-- 4 -2. 0.57974E-03 0.25555E-04 0.6193 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.66254E-05 0.8745 0.00000000E+00 HS- 6 -1. -0.55424E-03 0.13399E-11 0.8739 0.00000000E+00 Al+++ 7 3. 0.65212E-01 0.49998E-27 0.3455 0.00000000E+00 H4SiO4 8 0. 0.20825E+00 0.47501E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.23016E-01 0.39960E-07 0.6169 0.00000000E+00 Mg++ 10 2. 0.15872E-01 0.21863E-10 0.6154 0.00000000E+00 Fe++ 11 2. 0.14259E-01 0.12724E-12 0.6157 0.00000000E+00 K+ 12 1. 0.42461E-02 0.73040E-04 0.8747 0.00000000E+00 Na+ 13 1. 0.25264E-01 0.92775E-02 0.8738 0.00000000E+00 Mn++ 14 2. 0.34675E-03 0.17263E-10 0.6160 0.00000000E+00 HPO4-- 15 -2. 0.11835E-03 0.53331E-06 0.6193 0.00000000E+00 Chg. balance for total moles = 0.2990E-12 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 100.0000 SLIM = 0.400000E+02 TEMP = 100.0000 SINC = 0.1000E+01 TEMPC = 0.0000 TOTMIX = 0.199990E+02 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 8.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0107 MnO2-2 65 -2. 40.4376 Ca(HSiO3)+ 17 1. 7.6603 HMnO2- 66 -1. 29.1018 Mg(HSiO3)+ 18 1. 7.5653 MnO4- 67 -1. 83.3383 NaHSiO3,aq 19 0. 7.8098 MnO4-2 68 -2. 81.3024 AlO+ 20 1. 6.8891 MnCl+ 69 1. -0.7819 AlOH+2 21 2. 3.1893 MnSO4,aq 70 0. -2.4524 HAlO2,aq 22 0. 10.5878 NaCl,aq 71 0. 0.4861 AlO2- 23 -1. 16.2390 NaOH,aq 72 0. 12.3571 CH4,aq 24 0. 6.0082 O2,aq 73 0. 53.5759 C2H6,aq 25 0. 12.3556 OH- 74 -1. 12.2220 C3H8,aq 26 0. 17.3423 HO2- 75 -1. 50.7897 C4H10,aq 27 0. 22.3397 H2O2,aq 76 0. 40.0297 ethanol,aq 28 0. 15.3114 H3PO2,aq 77 0. 24.3310 CO,aq 29 0. 4.7087 H2PO2- 78 -1. 26.5491 CO2,aq 30 0. -6.3045 HPO3-2 79 -2. 11.9246 CO3-2 31 -2. 10.0340 H3PO3,aq 80 0. 3.5932 CaCO3,aq 32 0. 5.9460 H2PO3- 81 -1. 5.6314 Ca(HCO3)+ 33 1. -1.4013 H3PO4,aq 82 0. -9.8087 CaCl+ 34 1. -0.2023 H2PO4- 83 -1. -7.2438 CaCl2,aq 35 0. 0.4306 PO4-3 84 -3. 12.0588 CaOH+ 36 1. 10.1517 H4P2O7,aq 85 0. -17.7539 CaSO4,aq 37 0. -2.4936 H3P2O7- 86 -1. -15.8646 HCl,aq 38 0. 0.7256 H2P2O7-2 87 -2. -13.3812 HClO,aq 39 0. 32.4377 HP2O7-3 88 -3. -6.6931 ClO- 40 -1. 39.6416 P2O7-4 89 -4. 2.9147 HClO2,aq 41 0. 70.2060 H2S,aq 90 0. -6.4778 Fe+3 42 3. 8.3763 S2-2 91 -2. 1.2336 FeCl+ 43 1. -0.1924 S3-2 92 -2. -8.7963 FeCl2,aq 44 0. 4.3160 S3- 93 -1. -16.3178 FeCl+2 45 2. 6.5223 S4-2 94 -2. -18.6473 FeO,aq 46 0. 16.4029 S5-2 95 -2. -28.3223 FeOH+ 47 1. 7.4795 SO2,aq 96 0. -0.1980 HFeO2- 48 -1. 24.3713 SO3-2 97 -2. 10.2895 FeO+ 49 1. 11.3812 HSO3- 98 -1. 2.5222 FeOH+2 50 2. 9.1115 HSO4- 99 -1. -2.9675 FeO2- 51 -1. 24.0877 HSO5- 100 -1. 38.8657 HFeO2,aq 52 0. 15.9903 S2O3-2 101 -2. -4.5491 H2,aq 53 0. 9.4241 HS2O3- 102 -1. -6.8007 KCl,aq 54 0. 1.7519 H2S2O3,aq 103 0. -7.9944 KHSO4,aq 55 0. -0.4275 S2O4-2 104 -2. 10.5639 KOH,aq 56 0. 12.3606 HS2O4- 105 -1. 7.6762 KSO4- 57 -1. -1.1877 H2S2O4,aq 106 0. 6.6566 MgCO3,aq 58 0. 6.5483 S2O5-2 107 -2. 10.0891 Mg(HCO3)+ 59 1. -1.4098 S2O6-2 108 -2. 11.5737 MgCl+ 60 1. -0.1603 S2O8-2 109 -2. 42.1139 MgOH+ 61 1. 9.4082 S3O6-2 110 -2. 3.8101 Mn+3 62 3. 19.1332 S4O6-2 111 -2. -17.8301 MnO,aq 63 0. 17.9765 S5O6-2 112 -2. -14.1051 MnOH+ 64 1. 8.5115 113 0. 10.3157 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.984 0.0000E+00 osumilite(2) 124 20.895 0.0000E+00 CO2,gas 2 -6.363 0.0000E+00 osumilite-Fe 125 14.657 0.0000E+00 CH4,gas 3 4.809 0.0000E+00 pargasite 126 65.279 0.0000E+00 H2,gas 4 8.287 0.0000E+00 periclase 127 16.149 0.0000E+00 H2S,gas 5 -5.943 0.0000E+00 periclase-Fe 128 11.639 0.0000E+00 S2,gas 6 -7.033 0.0000E+00 perovskite-Al 129 12.395 0.0000E+00 CO,gas 7 3.510 0.0000E+00 perovskite-Ca 130 23.818 0.0000E+00 SO3,gas 8 17.427 0.0000E+00 perovskite-Fe 131 21.158 0.0000E+00 SO2,gas 9 1.136 0.0000E+00 perovskite-Mg 132 23.132 0.0000E+00 HCl,gas 10 5.479 0.0000E+00 phase_A 133 80.267 0.0000E+00 acmite 11 7.737 0.0000E+00 phlogopite-Na 134 29.731 0.0000E+00 akermanite 12 36.495 0.0000E+00 piemontite(ordered) 135 33.876 0.0000E+00 akimotoite 13 16.606 0.0000E+00 prehnite 136 19.466 0.0000E+00 akimotoite-Fe 14 13.083 0.0000E+00 prehnite-Fe 137 22.587 0.0000E+00 albite-high 15 0.750 0.0000E+00 pumpellyite-Fe 138 46.471 0.0000E+00 albite 16 -0.328 0.1542E-01 pumpellyite-Mg 139 49.194 0.0000E+00 almandine 17 24.545 0.0000E+00 px-Mg-tschermaks 140 19.687 0.0000E+00 pyrope 18 37.348 0.0000E+00 px-Ca-tschermaks 141 18.679 0.0000E+00 spessartine 19 24.550 0.0000E+00 pyrite 142 -21.225 0.0000E+00 analcite 20 3.371 0.0000E+00 pyrrhotite 143 -4.244 0.0000E+00 andalusite 21 5.062 0.0000E+00 pyrrhotiteFe0.875 144 -6.001 0.0000E+00 andradite 22 39.088 0.1707E-02 pyroxmangite 145 7.416 0.0000E+00 grossular 23 32.828 0.8359E-04 pyrophyllite 146 -6.098 0.0000E+00 anhydrite 24 -5.280 0.0000E+00 quartz 147 -2.982 0.0000E+00 ankerite 25 -2.093 0.0000E+00 rankinite 148 40.765 0.0000E+00 annite 26 20.209 0.0000E+00 ringwoodite-Fe 149 15.486 0.0000E+00 phlogopite 27 27.147 0.0000E+00 ringwoodite-Mg 150 27.602 0.0000E+00 biotite-Mn 28 33.034 0.0000E+00 rhodochrosite 151 -0.959 0.0000E+00 anorthite 29 12.798 0.0000E+00 rhodonite 152 7.462 0.0000E+00 anthophyllite 30 51.988 0.0000E+00 sanidine 153 -1.221 0.0000E+00 anthophyllite-Fe 31 29.455 0.0000E+00 sapphirine(351) 154 79.204 0.0000E+00 apatite-OH 32 -17.989 0.3927E-04 siderite 155 -2.588 0.0000E+00 apatite-OH-zs 33 -12.572 0.0000E+00 sillimanite 156 5.321 0.0000E+00 apatite-Cl-zs 34 -16.504 0.0000E+00 sodalite 157 50.255 0.0000E+00 aragonite 35 0.986 0.0000E+00 spinel 158 20.934 0.0000E+00 brucite 36 12.577 0.0000E+00 spurrite 159 59.566 0.0000E+00 calcite 37 0.833 0.0000E+00 staurolite-Fe 160 74.138 0.0000E+00 carnegieite-low 38 9.065 0.0000E+00 staurolite-Mg 161 90.336 0.0000E+00 carnegieite-high 39 10.134 0.0000E+00 staurolite-Mn 162 84.438 0.0000E+00 carpholite-Mg 40 8.650 0.0000E+00 stilbite 163 -7.406 0.1745E-01 carpholite-Fe 41 6.783 0.0000E+00 stilpnomelane-Fe 164 13.179 0.3048E-04 celadonite 42 5.401 0.0000E+00 stilpnomelane-Mg 165 27.596 0.0000E+00 celadonite-Fe 43 3.937 0.0000E+00 stishovite 166 2.721 0.0000E+00 chrysotile 44 23.937 0.0000E+00 sudoite-Fe 167 18.437 0.0000E+00 chondrodite 45 56.542 0.0000E+00 sudoite 168 21.216 0.0000E+00 clinochlore 46 39.193 0.3174E-02 sulfur 169 -9.141 0.0000E+00 daphnite 47 29.094 0.1935E-02 sylvite 170 1.345 0.0000E+00 chlorite-Mn 48 46.985 0.6935E-04 talc 171 16.553 0.0000E+00 chlorite-Al-free 49 47.262 0.0000E+00 talc-Fe 172 13.516 0.0000E+00 chloritoid-Mg 50 13.261 0.0000E+00 talc-tschermaks 173 19.189 0.0000E+00 chloritoid-Fe 51 9.239 0.0000E+00 tephroite 174 18.113 0.0000E+00 chloritoid-Mn 52 11.463 0.0000E+00 tilleyite 175 41.473 0.0000E+00 clinohumite 53 97.255 0.0000E+00 titanite-CaSi 176 15.497 0.0000E+00 coesite 54 -2.369 0.0000E+00 topaz-H 177 4.668 0.0000E+00 cordierite-H 55 23.898 0.0000E+00 tridymite 178 -2.615 0.0000E+00 cordierite 56 24.245 0.0000E+00 tremolite 179 48.003 0.0000E+00 cordierite-Fe 57 20.649 0.0000E+00 ferroactinolite 180 38.596 0.0000E+00 cordierite-Mn 58 25.261 0.0000E+00 troilite-low 181 -4.394 0.0000E+00 corundum 59 8.433 0.0000E+00 tschermakite 182 48.414 0.0000E+00 corundum-MgSi 60 18.905 0.0000E+00 vesuvianite 183 224.056 0.0000E+00 cristobalite 61 -2.549 0.0000E+00 wadeite-Si 184 20.233 0.0000E+00 cummingtonite 62 52.233 0.0000E+00 wadsleyite-Fe 185 15.711 0.0000E+00 cymrite-K 63 1.731 0.0000E+00 wadsleyite-Mg 186 25.878 0.0000E+00 deerite 64 95.982 0.0000E+00 wairakite 187 4.058 0.0000E+00 diaspore 65 2.896 0.0000E+00 walstromite 188 11.528 0.0000E+00 diamond 66 -3.107 0.0000E+00 wollastonite 189 10.482 0.0000E+00 diopside 67 16.215 0.0000E+00 pseudo-wollastonite 190 11.020 0.0000E+00 hedenbergite 68 14.244 0.0000E+00 zoisite 191 22.964 0.0000E+00 dolomite,ordered 69 0.587 0.0000E+00 akaganeite 192 7.768 0.0000E+00 eastonite 70 28.605 0.0000E+00 beidellite-Ca 193 -1.560 0.0000E+00 enstatite 71 17.301 0.0000E+00 beidellite-H 194 -2.241 0.0000E+00 clinoenstatite-HiP 72 18.388 0.0000E+00 beidellite-K 195 -1.435 0.0000E+00 clinoenstatite 73 17.202 0.0000E+00 beidellite-Mg 196 -1.707 0.0000E+00 protoenstatite 74 17.860 0.0000E+00 beidellite-Na 197 -1.257 0.0000E+00 epidote 75 24.775 0.0000E+00 calcium 198 84.043 0.0000E+00 clinozoisite 76 22.921 0.0000E+00 chalcedony 199 -2.794 0.0000E+00 epidote-Fe 77 29.937 0.0000E+00 dawsonite 200 1.714 0.0000E+00 fayalite 78 14.079 0.0000E+00 montmorillonite-Ca 201 -2.214 0.0000E+00 ferrosilite 79 11.188 0.0000E+00 montmorillonite-K 202 -2.161 0.0000E+00 forsterite 80 21.047 0.0000E+00 montmorillonite-Mg 203 -2.402 0.0000E+00 gedrite 81 50.725 0.0000E+00 montmorillonite-Na 204 -1.961 0.0000E+00 gehlenite 82 36.717 0.0000E+00 nontronite-Ca 205 3.280 0.0000E+00 gibbsite 83 4.097 0.0000E+00 nontronite-H 206 2.596 0.0000E+00 glaucophane 84 23.111 0.0000E+00 nontronite-K 207 3.404 0.0000E+00 glaucophane-Fe 85 17.417 0.0000E+00 nontronite-Mg 208 3.139 0.0000E+00 graphite 86 -3.549 0.0000E+00 nontronite-Na 209 3.583 0.3727E-03 greenalite 87 16.194 0.0000E+00 sepiolite 210 24.194 0.0000E+00 grunerite 88 31.364 0.0000E+00 alite 211 58.043 0.0000E+00 halite 89 1.582 0.0000E+00 belite 212 30.461 0.0000E+00 hematite 90 12.598 0.1369E-03 ettringite 213 43.354 0.0000E+00 heulandite 91 -5.707 0.0000E+00 gypsum 214 -4.924 0.0000E+00 hercynite 92 17.345 0.0000E+00 hemicarboaluminate 215 71.028 0.0000E+00 hollandite 93 25.702 0.0000E+00 hydrogarnet 216 60.721 0.0000E+00 iron 94 19.095 0.0000E+00 hydrogarnet-Si 217 50.654 0.0000E+00 jadeite 95 4.251 0.0000E+00 jennite 218 24.386 0.0000E+00 julgoldite 96 70.573 0.0000E+00 monosulfoaluminate 219 53.497 0.0000E+00 kalsilite 97 7.620 0.0000E+00 monocarboaluminate 220 61.966 0.0000E+00 kaolinite 98 -1.273 0.0000E+00 portlandite 221 18.282 0.0000E+00 kyanite 99 4.932 0.0000E+00 stratlingite 222 36.573 0.0000E+00 larnite-bredigite 100 30.714 0.0000E+00 tricarboaluminate 223 70.427 0.0000E+00 laumontite 101 2.975 0.0000E+00 tobermorite 224 9.839 0.0000E+00 lawsonite 102 9.678 0.0000E+00 C4AH13 225 81.870 0.0000E+00 leucite 103 4.168 0.0000E+00 C2AH8 226 45.260 0.0000E+00 lime 104 26.009 0.0000E+00 C3A 227 87.049 0.0000E+00 lizardite 105 23.287 0.0000E+00 C4AF 228 117.550 0.0000E+00 magnesite 106 0.709 0.0000E+00 CAH10 229 28.373 0.0000E+00 magnetite 107 20.133 0.0000E+00 alabandite 230 -0.962 0.0000E+00 minnesotaite 108 10.461 0.0000E+00 alunite 231 -10.224 0.0000E+00 minnesotaite-Mg 109 20.669 0.0000E+00 artinite 232 15.139 0.0000E+00 magnesioferrite 110 26.257 0.0000E+00 boehmite 233 4.430 0.0000E+00 majorite 111 53.314 0.0000E+00 dolomite,disordered 234 1.288 0.0000E+00 manganosite 112 14.068 0.0000E+00 ferrous-oxide 235 9.824 0.0000E+00 margarite 113 17.452 0.0000E+00 huntite 236 3.850 0.0000E+00 meionite 114 45.158 0.0000E+00 hydromagnesite 237 20.077 0.0000E+00 merwinite 115 55.988 0.0000E+00 nesquehonite 238 4.735 0.0000E+00 microcline 116 -2.432 0.4158E-02 potassium-oxide 239 69.039 0.0000E+00 monticellite 117 24.371 0.0000E+00 silica-amorphous 240 -2.080 0.0000E+00 mullite-Al 118 363.258 0.0000E+00 sodium-oxide 241 55.173 0.0000E+00 mullite-Si 119 7.324 0.0000E+00 an20ab80 242 2.079 0.0000E+00 muscovite 120 2.679 0.0000E+00 an25ab75 243 2.709 0.0000E+00 paragonite 121 4.337 0.0000E+00 an30ab70 244 3.344 0.0000E+00 nepheline 122 8.378 0.0000E+00 tr.625ac.25prg.125 245 45.308 0.0000E+00 osumilite(1) 123 21.978 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 19.9990000 g log = 1.3010 Original solution: 1000.0103000 g Original solution / Rock added: 50.00 (Water/Rock Ratio), log = 1.6990 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 19.9990000 Water: Moles liquid = 0.5536E+02 kg liquid = 0.9973E+00 Moles total = 0.5526E+02 kg total = 0.9955E+00 Activity = 1.0000 Stoichiometric ionic strength = .5200710E-02 Osmotic coef. = 0.9618 True ionic strength = .9383221E-02 Chg. balance for total moles = 0.2990E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15252E-09 -9.8167 0.13371E-09 -9.8738 0.87668E+00 -0.0572 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13803E-03 -3.8600 0.12062E-03 -3.9186 0.87386E+00 -0.0586 4 SO4-- 0.25555E-04 -4.5925 0.15826E-04 -4.8006 0.61930E+00 -0.2081 5 HCO3- 0.66254E-05 -5.1788 0.57942E-05 -5.2370 0.87454E+00 -0.0582 6 HS- 0.13399E-11 -11.8729 0.11710E-11 -11.9315 0.87393E+00 -0.0585 7 Al+++ 0.49998E-27 -27.3010 0.17273E-27 -27.7626 0.34546E+00 -0.4616 8 H4SiO4 0.47501E-03 -3.3233 0.47501E-03 -3.3233 0.10000E+01 0.0000 9 Ca++ 0.39960E-07 -7.3984 0.24651E-07 -7.6082 0.61688E+00 -0.2098 10 Mg++ 0.21863E-10 -10.6603 0.13454E-10 -10.8712 0.61538E+00 -0.2109 11 Fe++ 0.12724E-12 -12.8954 0.78344E-13 -13.1060 0.61574E+00 -0.2106 12 K+ 0.73040E-04 -4.1364 0.63885E-04 -4.1946 0.87465E+00 -0.0582 13 Na+ 0.92775E-02 -2.0326 0.81065E-02 -2.0912 0.87378E+00 -0.0586 14 Mn++ 0.17263E-10 -10.7629 0.10634E-10 -10.9733 0.61601E+00 -0.2104 15 HPO4-- 0.53331E-06 -6.2730 0.33030E-06 -6.4811 0.61934E+00 -0.2081 16 HSiO3- 0.39664E-02 -2.4016 0.34661E-02 -2.4602 0.87386E+00 -0.0586 17 Ca(HSiO3)+ 0.21884E-08 -8.6599 0.19143E-08 -8.7180 0.87475E+00 -0.0581 18 Mg(HSiO3)+ 0.14864E-11 -11.8279 0.13003E-11 -11.8860 0.87475E+00 -0.0581 19 NaHSiO3,aq 0.44626E-03 -3.3504 0.44626E-03 -3.3504 0.10000E+01 0.0000 20 AlO+ 0.14258E-14 -14.8459 0.12472E-14 -14.9041 0.87475E+00 -0.0581 22 HAlO2,aq 0.18666E-08 -8.7290 0.18666E-08 -8.7290 0.10000E+01 0.0000 23 AlO2- 0.35705E-04 -4.4473 0.31171E-04 -4.5062 0.87301E+00 -0.0590 24 CH4,aq 0.42135E-18 -18.3754 0.42067E-18 -18.3761 0.99840E+00 -0.0007 29 CO,aq 0.73481E-19 -19.1338 0.73481E-19 -19.1338 0.10000E+01 0.0000 30 CO2,aq 0.15645E-08 -8.8056 0.15620E-08 -8.8063 0.99840E+00 -0.0007 31 CO3-2 0.64770E-05 -5.1886 0.40066E-05 -5.3972 0.61859E+00 -0.2086 32 CaCO3,aq 0.12096E-08 -8.9173 0.12096E-08 -8.9173 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41142E-11 -11.3857 0.35989E-11 -11.4438 0.87475E+00 -0.0581 34 CaCl+ 0.54162E-11 -11.2663 0.47379E-11 -11.3244 0.87475E+00 -0.0581 35 CaCl2,aq 0.13306E-15 -15.8760 0.13306E-15 -15.8760 0.10000E+01 0.0000 36 CaOH+ 0.14861E-07 -7.8280 0.13000E-07 -7.8861 0.87475E+00 -0.0581 37 CaSO4,aq 0.12155E-09 -9.9152 0.12155E-09 -9.9152 0.10000E+01 0.0000 38 HCl,aq 0.30335E-14 -14.5181 0.30335E-14 -14.5181 0.10000E+01 0.0000 43 FeCl+ 0.16825E-16 -16.7740 0.14718E-16 -16.8322 0.87475E+00 -0.0581 46 FeO,aq 0.17328E-09 -9.7612 0.17328E-09 -9.7612 0.10000E+01 0.0000 47 FeOH+ 0.22206E-10 -10.6535 0.19425E-10 -10.7116 0.87475E+00 -0.0581 48 HFeO2- 0.15952E-07 -7.7972 0.13939E-07 -7.8558 0.87386E+00 -0.0586 49 FeO+ 0.12644E-14 -14.8981 0.11061E-14 -14.9562 0.87475E+00 -0.0581 51 FeO2- 0.13914E-07 -7.8565 0.12159E-07 -7.9151 0.87386E+00 -0.0586 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.18294E-08 -8.7377 0.18265E-08 -8.7384 0.99840E+00 -0.0007 54 KCl,aq 0.13644E-09 -9.8651 0.13644E-09 -9.8651 0.10000E+01 0.0000 55 KHSO4,aq 0.36176E-18 -18.4416 0.36176E-18 -18.4416 0.10000E+01 0.0000 56 KOH,aq 0.20829E-06 -6.6813 0.20829E-06 -6.6813 0.10000E+01 0.0000 57 KSO4- 0.17825E-07 -7.7490 0.15577E-07 -7.8075 0.87386E+00 -0.0586 58 MgCO3,aq 0.16497E-12 -12.7826 0.16497E-12 -12.7826 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22897E-14 -14.6402 0.20030E-14 -14.6983 0.87475E+00 -0.0581 60 MgCl+ 0.26836E-14 -14.5713 0.23475E-14 -14.6294 0.87475E+00 -0.0581 61 MgOH+ 0.44934E-10 -10.3474 0.39306E-10 -10.4055 0.87475E+00 -0.0581 63 MnO,aq 0.62789E-09 -9.2021 0.62789E-09 -9.2021 0.10000E+01 0.0000 64 MnOH+ 0.28000E-09 -9.5528 0.24493E-09 -9.6110 0.87475E+00 -0.0581 65 MnO2-2 0.19635E-11 -11.7070 0.12146E-11 -11.9156 0.61859E+00 -0.2086 66 HMnO2- 0.40265E-10 -10.3951 0.35186E-10 -10.4536 0.87386E+00 -0.0586 69 MnCl+ 0.88743E-14 -14.0519 0.77628E-14 -14.1100 0.87475E+00 -0.0581 70 MnSO4,aq 0.47696E-13 -13.3215 0.47696E-13 -13.3215 0.10000E+01 0.0000 71 NaCl,aq 0.31927E-06 -6.4958 0.31927E-06 -6.4958 0.10000E+01 0.0000 72 NaOH,aq 0.26640E-04 -4.5745 0.26640E-04 -4.5745 0.10000E+01 0.0000 74 OH- 0.51386E-02 -2.2892 0.44861E-02 -2.3481 0.87301E+00 -0.0590 79 HPO3-2 0.30804E-17 -17.5114 0.19055E-17 -17.7200 0.61859E+00 -0.2086 82 H3PO4,aq 0.38018E-16 -16.4200 0.38018E-16 -16.4200 0.10000E+01 0.0000 83 H2PO4- 0.88563E-09 -9.0527 0.77430E-09 -9.1111 0.87430E+00 -0.0583 84 PO4-3 0.60829E-08 -8.2159 0.21573E-08 -8.6661 0.35466E+00 -0.4502 87 H2P2O7-2 0.75855E-19 -19.1200 0.46923E-19 -19.3286 0.61859E+00 -0.2086 88 HP2O7-3 0.20821E-15 -15.6815 0.71960E-16 -16.1429 0.34561E+00 -0.4614 89 P2O7-4 0.85355E-15 -15.0688 0.13277E-15 -15.8769 0.15555E+00 -0.8081 90 H2S,aq 0.47118E-15 -15.3268 0.47043E-15 -15.3275 0.99840E+00 -0.0007 97 SO3-2 0.63226E-14 -14.1991 0.39414E-14 -14.4044 0.62338E+00 -0.2052 98 HSO3- 0.35293E-16 -16.4523 0.30841E-16 -16.5109 0.87386E+00 -0.0586 99 HSO4- 0.22435E-11 -11.6491 0.19635E-11 -11.7070 0.87520E+00 -0.0579 Charge balance for all species = 0.2973E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1525181E-09 -.9727565E-02 -.9797857E+01 0.0000 2 H2O 0.1000000E+01 0.5550907E+02 0.9993043E+06 0.0000 3 Cl- 0.1380265E-03 0.1383459E-03 0.4901303E+01 5.9552 4 SO4-- 0.2555523E-04 0.2557449E-04 0.2454986E+01 14.9470 5 HCO3- 0.6625419E-05 0.1310521E-04 0.7990769E+00 4.6368 6 HS- 0.1339900E-11 -.1306044E-08 -.4316291E-04 -2.0576 7 Al+++ 0.4999834E-27 0.3570699E-04 0.9627456E+00 1.8589 8 H4SiO4 0.4750080E-03 0.4887680E-02 0.4694486E+03 -3.3233 9 Ca++ 0.3996012E-07 0.5835026E-07 0.2336905E-02 12.1395 10 Mg++ 0.2186273E-10 0.6845336E-10 0.1663059E-05 8.8765 11 Fe++ 0.1272366E-12 0.3026521E-07 0.1689024E-02 6.6417 12 K+ 0.7304042E-04 0.7326667E-04 0.2862844E+01 5.6792 13 Na+ 0.9277459E-02 0.9750678E-02 0.2240074E+03 7.7827 14 Mn++ 0.1726283E-10 0.9674437E-09 0.5311178E-04 8.7744 15 HPO4-- 0.5333137E-06 0.5402822E-06 0.5181902E-01 13.2666 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3311407E+00 -.9701429E-02 -.3214393E+00 0.0000000E+00 2 H2O 0.5525755E+02 0.5535993E+02 -.1023780E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5797449E-03 0.2550577E-04 0.5542392E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5542405E-03 -.1302535E-08 -.5542392E-03 0.0000000E+00 7 Al+++ 0.6521157E-01 0.3561105E-04 0.6517596E-01 0.0000000E+00 8 H4SiO4 0.2082452E+00 0.4874548E-02 0.2033707E+00 0.0000000E+00 9 Ca++ 0.2301617E-01 0.5819349E-07 0.2301612E-01 0.0000000E+00 10 Mg++ 0.1587222E-01 0.6826944E-10 0.1587222E-01 0.0000000E+00 11 Fe++ 0.1425946E-01 0.3018389E-07 0.1425943E-01 0.0000000E+00 12 K+ 0.4246072E-02 0.7306982E-04 0.4173002E-02 0.0000000E+00 13 Na+ 0.2526369E-01 0.9724480E-02 0.1553921E-01 0.0000000E+00 14 Mn++ 0.3467546E-03 0.9648444E-09 0.3467536E-03 0.0000000E+00 15 HPO4-- 0.1183456E-03 0.5388306E-06 0.1178068E-03 0.0000000E+00 Chg. balance for solid moles: 0.7383E-16 Mass of aqueous solution: 0.998020E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 19.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1542E-01 -1.812 4.042 0.607 18.52 1.552 andradite 0.1707E-02 -2.768 0.8676 -0.062 3.975 0.2254 grossular 0.8359E-04 -4.078 0.3765E-01 -1.424 0.1725 0.1048E-01 apatite-OH 0.3927E-04 -4.406 0.1973E-01 -1.705 0.9037E-01 0.6268E-02 clinochlore 0.3174E-02 -2.498 1.764 0.247 8.084 0.6711 daphnite 0.1935E-02 -2.713 1.380 0.140 6.324 0.4183 chlorite-Mn 0.6935E-04 -4.159 0.4917E-01 -1.308 0.2253 0.1567E-01 hematite 0.1369E-03 -3.864 0.2187E-01 -1.660 0.1002 0.4144E-02 microcline 0.4158E-02 -2.381 1.157 0.063 5.302 0.4521 stilbite 0.1745E-01 -1.758 12.30 1.090 56.33 5.735 stilpnomelane-Fe 0.3048E-04 -4.516 0.3286E-01 -1.483 0.1505 0.1135E-01 nontronite-Na 0.3727E-03 -3.429 0.1585 -0.800 0.7262 0.4924E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9533E+00 0.9533E+00 1.0000 -0.021 grossular 0.4667E-01 0.4667E-01 1.0000 -1.331 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6130E+00 0.6130E+00 1.0000 -0.213 daphnite 0.3736E+00 0.3736E+00 1.0000 -0.428 chlorite-Mn 0.1339E-01 0.1339E-01 1.0000 -1.873 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 21.827190 g Volume = 9.150594 cm3 Porosity: -1.6778% V(tot) - V(min): -.15099E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 19.9990000 g log = 1.3010 Original solution: 1000.0103000 g Original solution / Rock added: 50.00 (Water/Rock Ratio), log = 1.6990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1687E-06 1.0073 0.1788E-06 0.1775E-06 CH4,gas 0.6243E-15 1.0129 0.6652E-15 0.6568E-15 H2,gas 0.2380E-05 1.0006 0.2505E-05 0.2504E-05 H2S,gas 0.1310E-13 0.9959 0.1372E-13 0.1378E-13 S2,gas 0.1068E-35 1.0000 0.1123E-35 0.1123E-35 CO,gas 0.1103E-15 1.0000 0.1160E-15 0.1160E-15 SO3,gas 0.1006E-39 1.0000 0.1058E-39 0.1058E-39 SO2,gas 0.9530E-23 1.0000 0.1002E-22 0.1002E-22 HCl,gas 0.5092E-17 1.0000 0.5356E-17 0.5356E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 90 hematite 12.60 12.60 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 209 nontronite-Na 3.58 3.58 0.00 0.000 0.68244E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.916 0.14936E+05 -6.748 3 CH4,gas 4.81 -12.37 -17.18 -4.294 0.29329E+05 -15.177 4 H2,gas 8.29 0.69 -7.60 -4.344 0.12979E+05 -5.601 5 H2S,gas -5.94 -21.81 -15.86 -7.931 0.27085E+05 -13.863 6 S2,gas -7.03 -44.98 -37.95 -5.838 0.64798E+05 -35.949 7 CO,gas 3.51 -14.43 -17.94 -5.519 0.30624E+05 -15.935 8 SO3,gas 17.43 -24.55 -41.98 -10.494 0.71672E+05 -39.976 9 SO2,gas 1.14 -23.86 -25.00 -6.666 0.42685E+05 -22.999 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32905E+05 -17.271 11 acmite 7.74 7.43 -0.30 -0.031 0.51654E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.07 -4.48 -0.224 0.76477E+04 20 analcite 3.37 2.99 -0.38 -0.042 0.64150E+03 21 andalusite 5.06 0.39 -4.67 -0.467 0.79704E+04 26 annite 20.21 17.49 -2.72 -0.151 0.46376E+04 27 phlogopite 27.15 24.20 -2.95 -0.164 0.50351E+04 29 anorthite 12.80 9.21 -3.59 -0.276 0.61248E+04 35 aragonite 0.99 -2.97 -3.96 -1.319 0.67574E+04 36 brucite 12.58 8.88 -3.70 -0.740 0.63178E+04 37 calcite 0.83 -2.97 -3.80 -1.268 0.64961E+04 38 carnegieite-low 9.06 6.32 -2.75 -0.392 0.46893E+04 39 carnegieite-high 10.13 6.32 -3.82 -0.545 0.65161E+04 40 carpholite-Mg 8.65 5.95 -2.70 -0.180 0.46148E+04 41 carpholite-Fe 6.78 3.71 -3.07 -0.205 0.52421E+04 42 celadonite 5.40 3.12 -2.28 -0.134 0.38915E+04 43 celadonite-Fe 3.94 0.89 -3.05 -0.179 0.52084E+04 44 chrysotile 23.94 19.98 -3.95 -0.330 0.67520E+04 50 chloritoid-Mg 13.26 9.27 -3.99 -0.266 0.68133E+04 51 chloritoid-Fe 9.24 7.04 -2.20 -0.147 0.37608E+04 52 chloritoid-Mn 11.46 9.17 -2.29 -0.153 0.39176E+04 54 coesite -2.37 -3.32 -0.95 -0.318 0.16288E+04 59 corundum 8.43 3.72 -4.72 -0.429 0.80519E+04 61 cristobalite -2.55 -3.32 -0.77 -0.258 0.13217E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.86 -1.04 -0.173 0.17710E+04 67 diopside 16.22 14.37 -1.85 -0.185 0.31521E+04 68 hedenbergite 14.24 12.13 -2.11 -0.211 0.36025E+04 75 epidote 24.78 24.33 -0.45 -0.022 0.76760E+03 76 clinozoisite 22.92 19.89 -3.04 -0.138 0.51829E+04 77 epidote-Fe 29.94 28.77 -1.17 -0.061 0.19998E+04 78 fayalite 14.08 9.96 -4.12 -0.588 0.70329E+04 79 ferrosilite 11.19 6.64 -4.55 -0.455 0.77706E+04 83 gibbsite 4.10 1.86 -2.24 -0.320 0.38222E+04 84 glaucophane 23.11 19.33 -3.78 -0.102 0.64616E+04 85 glaucophane-Fe 17.42 12.62 -4.80 -0.130 0.81881E+04 87 greenalite 16.19 13.28 -2.92 -0.243 0.49786E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.99 -1.26 -0.126 0.21445E+04 96 julgoldite 70.57 67.10 -3.48 -0.090 0.59353E+04 97 kalsilite 7.62 4.21 -3.41 -0.486 0.58147E+04 98 kaolinite -1.27 -2.93 -1.66 -0.151 0.28271E+04 99 kyanite 4.93 0.39 -4.54 -0.454 0.77472E+04 101 laumontite 2.97 2.56 -0.41 -0.027 0.70092E+03 102 lawsonite 9.68 9.21 -0.47 -0.031 0.79864E+03 103 leucite 4.17 0.89 -3.28 -0.328 0.55939E+04 105 lizardite 23.29 19.98 -3.30 -0.275 0.56423E+04 107 magnetite 20.13 19.24 -0.89 -0.073 0.15256E+04 108 minnesotaite 10.46 6.63 -3.83 -0.225 0.65377E+04 110 magnesioferrite 26.26 21.47 -4.78 -0.390 0.81671E+04 113 margarite 17.45 12.93 -4.52 -0.181 0.77236E+04 120 muscovite 2.68 1.29 -1.39 -0.082 0.23789E+04 121 paragonite 4.34 3.39 -0.95 -0.056 0.16174E+04 122 nepheline 8.38 6.32 -2.06 -0.294 0.35172E+04 128 periclase-Fe 11.64 6.64 -5.00 -1.249 0.85330E+04 134 phlogopite-Na 29.73 26.30 -3.43 -0.191 0.58570E+04 136 prehnite 19.47 18.03 -1.44 -0.085 0.24579E+04 137 prehnite-Fe 22.59 22.47 -0.12 -0.007 0.20487E+03 138 pumpellyite-Fe 46.47 44.55 -1.92 -0.043 0.32721E+04 139 pumpellyite-Mg 49.19 46.79 -2.40 -0.053 0.41064E+04 145 pyroxmangite 7.42 5.45 -1.96 -0.393 0.33551E+04 146 pyrophyllite -6.10 -9.58 -3.48 -0.217 0.59376E+04 147 quartz -2.98 -3.32 -0.34 -0.114 0.58276E+03 152 rhodonite 7.46 5.45 -2.01 -0.402 0.34344E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.39 -4.93 -0.493 0.84126E+04 165 stilpnomelane-Mg 27.60 24.35 -3.24 -0.097 0.55369E+04 171 talc 16.55 13.34 -3.22 -0.189 0.54930E+04 174 tephroite 18.11 14.23 -3.89 -0.555 0.66377E+04 177 topaz-H 4.67 0.39 -4.27 -0.388 0.72962E+04 178 tridymite -2.61 -3.32 -0.71 -0.236 0.12101E+04 187 wairakite 4.06 2.56 -1.49 -0.088 0.25517E+04 188 walstromite 11.53 8.82 -2.71 -0.542 0.46301E+04 189 wollastonite 10.48 8.82 -1.67 -0.333 0.28440E+04 190 pseudo-wollastonite 11.02 8.82 -2.20 -0.441 0.37626E+04 191 zoisite 22.96 19.89 -3.08 -0.140 0.52555E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.86 -4.30 -0.266 0.73467E+04 195 beidellite-K -1.44 -5.99 -4.56 -0.279 0.77795E+04 196 beidellite-Mg -1.71 -6.40 -4.69 -0.290 0.80146E+04 197 beidellite-Na -1.26 -5.30 -4.04 -0.247 0.68983E+04 199 chalcedony -2.79 -3.32 -0.53 -0.176 0.90308E+03 201 montmorillonite-Ca -2.21 -5.26 -3.04 -0.188 0.51951E+04 202 montmorillonite-K -2.16 -5.39 -3.22 -0.197 0.55058E+04 203 montmorillonite-Mg -2.40 -5.80 -3.39 -0.210 0.57941E+04 204 montmorillonite-Na -1.96 -4.69 -2.73 -0.167 0.46626E+04 205 nontronite-Ca 3.28 3.02 -0.26 -0.017 0.44753E+03 206 nontronite-H 2.60 1.01 -1.58 -0.106 0.26999E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11271E+04 224 tobermorite 9.84 6.79 -3.05 -0.832 0.52080E+04 233 boehmite 4.43 1.86 -2.57 -0.428 0.43895E+04 235 ferrous-oxide 9.82 6.64 -3.18 -0.796 0.54341E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.415 0.21233E+04 242 an20ab80 2.08 1.58 -0.50 -0.038 0.85334E+03 243 an25ab75 2.71 2.06 -0.65 -0.050 0.11146E+04 244 an30ab70 3.34 2.53 -0.81 -0.062 0.13842E+04 245 tr.625ac.25prg.125 45.31 40.67 -4.64 -0.125 0.79147E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 19.9990000 g New total amount of reactant added: 20.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2990E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 20.9990000 Water: Moles liquid = 0.5535E+02 kg liquid = 0.9972E+00 Moles total = 0.5525E+02 kg total = 0.9953E+00 Activity = 1.0000 Stoichiometric ionic strength = .5200728E-02 Osmotic coef. = 0.9618 True ionic strength = .9383236E-02 Chg. balance for total moles = 0.2990E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15252E-09 -9.8167 0.13371E-09 -9.8738 0.87668E+00 -0.0572 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13804E-03 -3.8600 0.12063E-03 -3.9186 0.87386E+00 -0.0586 4 SO4-- 0.25558E-04 -4.5925 0.15828E-04 -4.8006 0.61930E+00 -0.2081 5 HCO3- 0.66261E-05 -5.1787 0.57948E-05 -5.2370 0.87454E+00 -0.0582 6 HS- 0.13400E-11 -11.8729 0.11711E-11 -11.9314 0.87393E+00 -0.0585 7 Al+++ 0.49999E-27 -27.3010 0.17273E-27 -27.7626 0.34546E+00 -0.4616 8 H4SiO4 0.47501E-03 -3.3233 0.47501E-03 -3.3233 0.10000E+01 0.0000 9 Ca++ 0.39960E-07 -7.3984 0.24651E-07 -7.6082 0.61688E+00 -0.2098 10 Mg++ 0.21863E-10 -10.6603 0.13454E-10 -10.8712 0.61538E+00 -0.2109 11 Fe++ 0.12724E-12 -12.8954 0.78344E-13 -13.1060 0.61574E+00 -0.2106 12 K+ 0.73041E-04 -4.1364 0.63885E-04 -4.1946 0.87465E+00 -0.0582 13 Na+ 0.92775E-02 -2.0326 0.81065E-02 -2.0912 0.87378E+00 -0.0586 14 Mn++ 0.17263E-10 -10.7629 0.10634E-10 -10.9733 0.61601E+00 -0.2104 15 HPO4-- 0.53331E-06 -6.2730 0.33030E-06 -6.4811 0.61934E+00 -0.2081 16 HSiO3- 0.39664E-02 -2.4016 0.34661E-02 -2.4602 0.87386E+00 -0.0586 17 Ca(HSiO3)+ 0.21884E-08 -8.6599 0.19143E-08 -8.7180 0.87475E+00 -0.0581 18 Mg(HSiO3)+ 0.14864E-11 -11.8279 0.13003E-11 -11.8860 0.87475E+00 -0.0581 19 NaHSiO3,aq 0.44626E-03 -3.3504 0.44626E-03 -3.3504 0.10000E+01 0.0000 20 AlO+ 0.14258E-14 -14.8459 0.12472E-14 -14.9041 0.87475E+00 -0.0581 22 HAlO2,aq 0.18666E-08 -8.7290 0.18666E-08 -8.7290 0.10000E+01 0.0000 23 AlO2- 0.35705E-04 -4.4473 0.31171E-04 -4.5063 0.87301E+00 -0.0590 24 CH4,aq 0.42139E-18 -18.3753 0.42072E-18 -18.3760 0.99840E+00 -0.0007 29 CO,aq 0.73488E-19 -19.1338 0.73488E-19 -19.1338 0.10000E+01 0.0000 30 CO2,aq 0.15647E-08 -8.8056 0.15622E-08 -8.8063 0.99840E+00 -0.0007 31 CO3-2 0.64777E-05 -5.1886 0.40070E-05 -5.3972 0.61859E+00 -0.2086 32 CaCO3,aq 0.12098E-08 -8.9173 0.12098E-08 -8.9173 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41146E-11 -11.3857 0.35993E-11 -11.4438 0.87475E+00 -0.0581 34 CaCl+ 0.54168E-11 -11.2663 0.47383E-11 -11.3244 0.87475E+00 -0.0581 35 CaCl2,aq 0.13308E-15 -15.8759 0.13308E-15 -15.8759 0.10000E+01 0.0000 36 CaOH+ 0.14861E-07 -7.8280 0.13000E-07 -7.8861 0.87475E+00 -0.0581 37 CaSO4,aq 0.12157E-09 -9.9152 0.12157E-09 -9.9152 0.10000E+01 0.0000 38 HCl,aq 0.30338E-14 -14.5180 0.30338E-14 -14.5180 0.10000E+01 0.0000 43 FeCl+ 0.16827E-16 -16.7740 0.14719E-16 -16.8321 0.87475E+00 -0.0581 46 FeO,aq 0.17328E-09 -9.7612 0.17328E-09 -9.7612 0.10000E+01 0.0000 47 FeOH+ 0.22206E-10 -10.6535 0.19425E-10 -10.7116 0.87475E+00 -0.0581 48 HFeO2- 0.15952E-07 -7.7972 0.13939E-07 -7.8558 0.87386E+00 -0.0586 49 FeO+ 0.12644E-14 -14.8981 0.11061E-14 -14.9562 0.87475E+00 -0.0581 51 FeO2- 0.13914E-07 -7.8565 0.12159E-07 -7.9151 0.87386E+00 -0.0586 52 HFeO2,aq 0.20347E-09 -9.6915 0.20347E-09 -9.6915 0.10000E+01 0.0000 53 H2,aq 0.18294E-08 -8.7377 0.18265E-08 -8.7384 0.99840E+00 -0.0007 54 KCl,aq 0.13645E-09 -9.8650 0.13645E-09 -9.8650 0.10000E+01 0.0000 55 KHSO4,aq 0.36180E-18 -18.4415 0.36180E-18 -18.4415 0.10000E+01 0.0000 56 KOH,aq 0.20829E-06 -6.6813 0.20829E-06 -6.6813 0.10000E+01 0.0000 57 KSO4- 0.17827E-07 -7.7489 0.15578E-07 -7.8075 0.87386E+00 -0.0586 58 MgCO3,aq 0.16499E-12 -12.7826 0.16499E-12 -12.7826 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22900E-14 -14.6402 0.20032E-14 -14.6983 0.87475E+00 -0.0581 60 MgCl+ 0.26838E-14 -14.5712 0.23477E-14 -14.6294 0.87475E+00 -0.0581 61 MgOH+ 0.44934E-10 -10.3474 0.39306E-10 -10.4055 0.87475E+00 -0.0581 63 MnO,aq 0.62789E-09 -9.2021 0.62789E-09 -9.2021 0.10000E+01 0.0000 64 MnOH+ 0.28000E-09 -9.5528 0.24493E-09 -9.6110 0.87475E+00 -0.0581 65 MnO2-2 0.19634E-11 -11.7070 0.12146E-11 -11.9156 0.61859E+00 -0.2086 66 HMnO2- 0.40265E-10 -10.3951 0.35186E-10 -10.4536 0.87386E+00 -0.0586 69 MnCl+ 0.88752E-14 -14.0518 0.77636E-14 -14.1099 0.87475E+00 -0.0581 70 MnSO4,aq 0.47700E-13 -13.3215 0.47700E-13 -13.3215 0.10000E+01 0.0000 71 NaCl,aq 0.31930E-06 -6.4958 0.31930E-06 -6.4958 0.10000E+01 0.0000 72 NaOH,aq 0.26640E-04 -4.5745 0.26640E-04 -4.5745 0.10000E+01 0.0000 74 OH- 0.51386E-02 -2.2892 0.44861E-02 -2.3481 0.87301E+00 -0.0590 79 HPO3-2 0.30804E-17 -17.5114 0.19055E-17 -17.7200 0.61859E+00 -0.2086 82 H3PO4,aq 0.38018E-16 -16.4200 0.38018E-16 -16.4200 0.10000E+01 0.0000 83 H2PO4- 0.88563E-09 -9.0527 0.77430E-09 -9.1111 0.87430E+00 -0.0583 84 PO4-3 0.60829E-08 -8.2159 0.21573E-08 -8.6661 0.35466E+00 -0.4502 87 H2P2O7-2 0.75855E-19 -19.1200 0.46923E-19 -19.3286 0.61859E+00 -0.2086 88 HP2O7-3 0.20821E-15 -15.6815 0.71960E-16 -16.1429 0.34561E+00 -0.4614 89 P2O7-4 0.85355E-15 -15.0688 0.13277E-15 -15.8769 0.15555E+00 -0.8081 90 H2S,aq 0.47123E-15 -15.3268 0.47048E-15 -15.3275 0.99840E+00 -0.0007 97 SO3-2 0.63232E-14 -14.1991 0.39418E-14 -14.4043 0.62338E+00 -0.2052 98 HSO3- 0.35296E-16 -16.4523 0.30844E-16 -16.5108 0.87386E+00 -0.0586 99 HSO4- 0.22437E-11 -11.6490 0.19637E-11 -11.7069 0.87520E+00 -0.0579 Charge balance for all species = 0.2966E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1525183E-09 -.9727556E-02 -.9797848E+01 0.0000 2 H2O 0.1000000E+01 0.5550907E+02 0.9993043E+06 0.0000 3 Cl- 0.1380403E-03 0.1383598E-03 0.4901795E+01 5.9553 4 SO4-- 0.2555780E-04 0.2557705E-04 0.2455232E+01 14.9471 5 HCO3- 0.6626087E-05 0.1310653E-04 0.7991571E+00 4.6369 6 HS- 0.1340036E-11 -.1306042E-08 -.4316284E-04 -2.0576 7 Al+++ 0.4999854E-27 0.3570695E-04 0.9627446E+00 1.8589 8 H4SiO4 0.4750080E-03 0.4887676E-02 0.4694481E+03 -3.3233 9 Ca++ 0.3996022E-07 0.5835052E-07 0.2336916E-02 12.1395 10 Mg++ 0.2186279E-10 0.6845349E-10 0.1663062E-05 8.8765 11 Fe++ 0.1272369E-12 0.3026518E-07 0.1689022E-02 6.6417 12 K+ 0.7304051E-04 0.7326676E-04 0.2862848E+01 5.6792 13 Na+ 0.9277471E-02 0.9750689E-02 0.2240076E+03 7.7827 14 Mn++ 0.1726288E-10 0.9674442E-09 0.5311180E-04 8.7744 15 HPO4-- 0.5333127E-06 0.5402812E-06 0.5181892E-01 13.2666 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3476992E+00 -.9700446E-02 -.3379988E+00 0.0000000E+00 2 H2O 0.5524502E+02 0.5535437E+02 -.1093547E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6074583E-03 0.2550577E-04 0.5819526E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5819539E-03 -.1302403E-08 -.5819526E-03 0.0000000E+00 7 Al+++ 0.6847231E-01 0.3560744E-04 0.6843671E-01 0.0000000E+00 8 H4SiO4 0.2186580E+00 0.4874054E-02 0.2137840E+00 0.0000000E+00 9 Ca++ 0.2416632E-01 0.5818790E-07 0.2416626E-01 0.0000000E+00 10 Mg++ 0.1666587E-01 0.6826271E-10 0.1666587E-01 0.0000000E+00 11 Fe++ 0.1497247E-01 0.3018083E-07 0.1497244E-01 0.0000000E+00 12 K+ 0.4458386E-02 0.7306257E-04 0.4385324E-02 0.0000000E+00 13 Na+ 0.2651893E-01 0.9723515E-02 0.1679542E-01 0.0000000E+00 14 Mn++ 0.3640932E-03 0.9647479E-09 0.3640922E-03 0.0000000E+00 15 HPO4-- 0.1242632E-03 0.5387754E-06 0.1237244E-03 0.0000000E+00 Chg. balance for solid moles: 0.7373E-17 Mass of aqueous solution: 0.997920E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 20.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1663E-01 -1.779 4.362 0.640 19.03 1.674 andradite 0.1870E-02 -2.728 0.9503 -0.022 4.146 0.2469 grossular 0.9156E-04 -4.038 0.4124E-01 -1.385 0.1799 0.1148E-01 apatite-OH 0.4124E-04 -4.385 0.2072E-01 -1.684 0.9039E-01 0.6583E-02 clinochlore 0.3333E-02 -2.477 1.853 0.268 8.083 0.7047 daphnite 0.2031E-02 -2.692 1.449 0.161 6.324 0.4392 chlorite-Mn 0.7282E-04 -4.138 0.5163E-01 -1.287 0.2253 0.1645E-01 hematite -.3154E-04 1.000 -.5038E-02 1.000 -.2198E-01 -.9548E-03 microcline 0.4369E-02 -2.360 1.216 0.085 5.306 0.4751 stilbite 0.1808E-01 -1.743 12.74 1.105 55.58 5.941 stilpnomelane-Fe 0.3201E-04 -4.495 0.3450E-01 -1.462 0.1505 0.1192E-01 nontronite-Na 0.4893E-03 -3.310 0.2081 -0.682 0.9078 0.6463E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9533E+00 0.9533E+00 1.0000 -0.021 grossular 0.4667E-01 0.4667E-01 1.0000 -1.331 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6130E+00 0.6130E+00 1.0000 -0.213 daphnite 0.3736E+00 0.3736E+00 1.0000 -0.428 chlorite-Mn 0.1339E-01 0.1339E-01 1.0000 -1.873 hematite 0.1000E+01 0.1000E+01 1.0000 0.000 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 22.919307 g Volume = 9.591542 cm3 Porosity: -2.0420% V(tot) - V(min): -.19194E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 20.9990000 g log = 1.3222 Original solution: 1000.0103000 g Original solution / Rock added: 47.62 (Water/Rock Ratio), log = 1.6778 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1688E-06 1.0073 0.1788E-06 0.1775E-06 CH4,gas 0.6244E-15 1.0129 0.6653E-15 0.6568E-15 H2,gas 0.2380E-05 1.0006 0.2505E-05 0.2504E-05 H2S,gas 0.1310E-13 0.9959 0.1372E-13 0.1378E-13 S2,gas 0.1068E-35 1.0000 0.1124E-35 0.1124E-35 CO,gas 0.1103E-15 1.0000 0.1160E-15 0.1160E-15 SO3,gas 0.1006E-39 1.0000 0.1058E-39 0.1058E-39 SO2,gas 0.9531E-23 1.0000 0.1003E-22 0.1003E-22 HCl,gas 0.5092E-17 1.0000 0.5357E-17 0.5357E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.48529E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.98575E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.916 0.14936E+05 -6.748 3 CH4,gas 4.81 -12.37 -17.18 -4.294 0.29329E+05 -15.177 4 H2,gas 8.29 0.69 -7.60 -4.344 0.12979E+05 -5.601 5 H2S,gas -5.94 -21.81 -15.86 -7.931 0.27085E+05 -13.863 6 S2,gas -7.03 -44.98 -37.95 -5.838 0.64797E+05 -35.949 7 CO,gas 3.51 -14.43 -17.94 -5.519 0.30624E+05 -15.935 8 SO3,gas 17.43 -24.55 -41.98 -10.494 0.71672E+05 -39.976 9 SO2,gas 1.14 -23.86 -25.00 -6.666 0.42685E+05 -22.999 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32905E+05 -17.271 11 acmite 7.74 7.43 -0.30 -0.031 0.51654E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.07 -4.48 -0.224 0.76477E+04 20 analcite 3.37 2.99 -0.38 -0.042 0.64150E+03 21 andalusite 5.06 0.39 -4.67 -0.467 0.79704E+04 26 annite 20.21 17.49 -2.72 -0.151 0.46376E+04 27 phlogopite 27.15 24.20 -2.95 -0.164 0.50351E+04 29 anorthite 12.80 9.21 -3.59 -0.276 0.61248E+04 35 aragonite 0.99 -2.97 -3.96 -1.319 0.67574E+04 36 brucite 12.58 8.88 -3.70 -0.740 0.63178E+04 37 calcite 0.83 -2.97 -3.80 -1.268 0.64960E+04 38 carnegieite-low 9.06 6.32 -2.75 -0.392 0.46893E+04 39 carnegieite-high 10.13 6.32 -3.82 -0.545 0.65161E+04 40 carpholite-Mg 8.65 5.95 -2.70 -0.180 0.46148E+04 41 carpholite-Fe 6.78 3.71 -3.07 -0.205 0.52421E+04 42 celadonite 5.40 3.12 -2.28 -0.134 0.38915E+04 43 celadonite-Fe 3.94 0.89 -3.05 -0.179 0.52084E+04 44 chrysotile 23.94 19.98 -3.95 -0.330 0.67520E+04 50 chloritoid-Mg 13.26 9.27 -3.99 -0.266 0.68133E+04 51 chloritoid-Fe 9.24 7.04 -2.20 -0.147 0.37608E+04 52 chloritoid-Mn 11.46 9.17 -2.29 -0.153 0.39176E+04 54 coesite -2.37 -3.32 -0.95 -0.318 0.16288E+04 59 corundum 8.43 3.72 -4.72 -0.429 0.80519E+04 61 cristobalite -2.55 -3.32 -0.77 -0.258 0.13217E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.86 -1.04 -0.173 0.17710E+04 67 diopside 16.22 14.37 -1.85 -0.185 0.31521E+04 68 hedenbergite 14.24 12.13 -2.11 -0.211 0.36025E+04 75 epidote 24.78 24.33 -0.45 -0.022 0.76760E+03 76 clinozoisite 22.92 19.89 -3.04 -0.138 0.51829E+04 77 epidote-Fe 29.94 28.77 -1.17 -0.061 0.19998E+04 78 fayalite 14.08 9.96 -4.12 -0.588 0.70329E+04 79 ferrosilite 11.19 6.64 -4.55 -0.455 0.77706E+04 83 gibbsite 4.10 1.86 -2.24 -0.320 0.38222E+04 84 glaucophane 23.11 19.33 -3.78 -0.102 0.64616E+04 85 glaucophane-Fe 17.42 12.62 -4.80 -0.130 0.81881E+04 87 greenalite 16.19 13.28 -2.92 -0.243 0.49786E+04 90 hematite 12.60 12.60 0.00 0.000 0.30331E-11 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.99 -1.26 -0.126 0.21445E+04 96 julgoldite 70.57 67.10 -3.48 -0.090 0.59353E+04 97 kalsilite 7.62 4.21 -3.41 -0.486 0.58147E+04 98 kaolinite -1.27 -2.93 -1.66 -0.151 0.28271E+04 99 kyanite 4.93 0.39 -4.54 -0.454 0.77472E+04 101 laumontite 2.97 2.56 -0.41 -0.027 0.70092E+03 102 lawsonite 9.68 9.21 -0.47 -0.031 0.79864E+03 103 leucite 4.17 0.89 -3.28 -0.328 0.55939E+04 105 lizardite 23.29 19.98 -3.30 -0.275 0.56423E+04 107 magnetite 20.13 19.24 -0.89 -0.073 0.15256E+04 108 minnesotaite 10.46 6.63 -3.83 -0.225 0.65377E+04 110 magnesioferrite 26.26 21.47 -4.78 -0.390 0.81671E+04 113 margarite 17.45 12.93 -4.52 -0.181 0.77236E+04 120 muscovite 2.68 1.29 -1.39 -0.082 0.23789E+04 121 paragonite 4.34 3.39 -0.95 -0.056 0.16174E+04 122 nepheline 8.38 6.32 -2.06 -0.294 0.35172E+04 128 periclase-Fe 11.64 6.64 -5.00 -1.249 0.85330E+04 134 phlogopite-Na 29.73 26.30 -3.43 -0.191 0.58570E+04 136 prehnite 19.47 18.03 -1.44 -0.085 0.24579E+04 137 prehnite-Fe 22.59 22.47 -0.12 -0.007 0.20487E+03 138 pumpellyite-Fe 46.47 44.55 -1.92 -0.043 0.32721E+04 139 pumpellyite-Mg 49.19 46.79 -2.40 -0.053 0.41064E+04 145 pyroxmangite 7.42 5.45 -1.96 -0.393 0.33551E+04 146 pyrophyllite -6.10 -9.58 -3.48 -0.217 0.59376E+04 147 quartz -2.98 -3.32 -0.34 -0.114 0.58276E+03 152 rhodonite 7.46 5.45 -2.01 -0.402 0.34344E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.39 -4.93 -0.493 0.84126E+04 165 stilpnomelane-Mg 27.60 24.35 -3.24 -0.097 0.55369E+04 171 talc 16.55 13.34 -3.22 -0.189 0.54930E+04 174 tephroite 18.11 14.23 -3.89 -0.555 0.66377E+04 177 topaz-H 4.67 0.39 -4.27 -0.388 0.72962E+04 178 tridymite -2.61 -3.32 -0.71 -0.236 0.12101E+04 187 wairakite 4.06 2.56 -1.49 -0.088 0.25517E+04 188 walstromite 11.53 8.82 -2.71 -0.542 0.46301E+04 189 wollastonite 10.48 8.82 -1.67 -0.333 0.28440E+04 190 pseudo-wollastonite 11.02 8.82 -2.20 -0.441 0.37626E+04 191 zoisite 22.96 19.89 -3.08 -0.140 0.52555E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25082E+04 193 beidellite-Ca -1.56 -5.86 -4.30 -0.266 0.73467E+04 195 beidellite-K -1.44 -5.99 -4.56 -0.279 0.77795E+04 196 beidellite-Mg -1.71 -6.40 -4.69 -0.290 0.80146E+04 197 beidellite-Na -1.26 -5.30 -4.04 -0.247 0.68983E+04 199 chalcedony -2.79 -3.32 -0.53 -0.176 0.90308E+03 201 montmorillonite-Ca -2.21 -5.26 -3.04 -0.188 0.51951E+04 202 montmorillonite-K -2.16 -5.39 -3.22 -0.197 0.55058E+04 203 montmorillonite-Mg -2.40 -5.80 -3.39 -0.210 0.57941E+04 204 montmorillonite-Na -1.96 -4.69 -2.73 -0.167 0.46626E+04 205 nontronite-Ca 3.28 3.02 -0.26 -0.017 0.44753E+03 206 nontronite-H 2.60 1.01 -1.58 -0.106 0.26999E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11271E+04 224 tobermorite 9.84 6.79 -3.05 -0.832 0.52080E+04 233 boehmite 4.43 1.86 -2.57 -0.428 0.43895E+04 235 ferrous-oxide 9.82 6.64 -3.18 -0.796 0.54341E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.415 0.21233E+04 242 an20ab80 2.08 1.58 -0.50 -0.038 0.85334E+03 243 an25ab75 2.71 2.06 -0.65 -0.050 0.11146E+04 244 an30ab70 3.34 2.53 -0.81 -0.062 0.13842E+04 245 tr.625ac.25prg.125 45.31 40.67 -4.64 -0.125 0.79147E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 20.9990000 Water: Moles liquid = 0.5535E+02 kg liquid = 0.9972E+00 Moles total = 0.5525E+02 kg total = 0.9953E+00 Activity = 1.0000 Stoichiometric ionic strength = .5207016E-02 Osmotic coef. = 0.9618 True ionic strength = .9397132E-02 Chg. balance for total moles = 0.2990E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15251E-09 -9.8167 0.13370E-09 -9.8739 0.87662E+00 -0.0572 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13804E-03 -3.8600 0.12062E-03 -3.9186 0.87379E+00 -0.0586 4 SO4-- 0.25558E-04 -4.5925 0.15823E-04 -4.8007 0.61911E+00 -0.2082 5 HCO3- 0.66250E-05 -5.1788 0.57934E-05 -5.2371 0.87447E+00 -0.0583 6 HS- 0.13769E-11 -11.8611 0.12032E-11 -11.9197 0.87386E+00 -0.0586 7 Al+++ 0.49468E-27 -27.3057 0.17078E-27 -27.7676 0.34523E+00 -0.4619 8 H4SiO4 0.47651E-03 -3.3219 0.47651E-03 -3.3219 0.10000E+01 0.0000 9 Ca++ 0.39958E-07 -7.3984 0.24642E-07 -7.6083 0.61670E+00 -0.2099 10 Mg++ 0.21963E-10 -10.6583 0.13511E-10 -10.8693 0.61519E+00 -0.2110 11 Fe++ 0.12714E-12 -12.8957 0.78264E-13 -13.1064 0.61555E+00 -0.2107 12 K+ 0.73149E-04 -4.1358 0.63975E-04 -4.1940 0.87459E+00 -0.0582 13 Na+ 0.92913E-02 -2.0319 0.81179E-02 -2.0906 0.87372E+00 -0.0586 14 Mn++ 0.17342E-10 -10.7609 0.10679E-10 -10.9715 0.61582E+00 -0.2105 15 HPO4-- 0.53370E-06 -6.2727 0.33045E-06 -6.4809 0.61916E+00 -0.2082 16 HSiO3- 0.39797E-02 -2.4001 0.34774E-02 -2.4587 0.87379E+00 -0.0586 17 Ca(HSiO3)+ 0.21950E-08 -8.6586 0.19199E-08 -8.7167 0.87469E+00 -0.0581 18 Mg(HSiO3)+ 0.14978E-11 -11.8245 0.13101E-11 -11.8827 0.87469E+00 -0.0581 19 NaHSiO3,aq 0.44835E-03 -3.3484 0.44835E-03 -3.3484 0.10000E+01 0.0000 20 AlO+ 0.14101E-14 -14.8507 0.12334E-14 -14.9089 0.87469E+00 -0.0581 22 HAlO2,aq 0.18461E-08 -8.7337 0.18461E-08 -8.7337 0.10000E+01 0.0000 23 AlO2- 0.35321E-04 -4.4520 0.30833E-04 -4.5110 0.87294E+00 -0.0590 24 CH4,aq 0.43297E-18 -18.3635 0.43227E-18 -18.3642 0.99840E+00 -0.0007 29 CO,aq 0.73968E-19 -19.1310 0.73968E-19 -19.1310 0.10000E+01 0.0000 30 CO2,aq 0.15642E-08 -8.8057 0.15616E-08 -8.8064 0.99840E+00 -0.0007 31 CO3-2 0.64788E-05 -5.1885 0.40065E-05 -5.3972 0.61841E+00 -0.2087 32 CaCO3,aq 0.12092E-08 -8.9175 0.12092E-08 -8.9175 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41125E-11 -11.3859 0.35972E-11 -11.4440 0.87469E+00 -0.0581 34 CaCl+ 0.54149E-11 -11.2664 0.47363E-11 -11.3246 0.87469E+00 -0.0581 35 CaCl2,aq 0.13302E-15 -15.8761 0.13302E-15 -15.8761 0.10000E+01 0.0000 36 CaOH+ 0.14859E-07 -7.8280 0.12997E-07 -7.8862 0.87469E+00 -0.0581 37 CaSO4,aq 0.12149E-09 -9.9155 0.12149E-09 -9.9155 0.10000E+01 0.0000 38 HCl,aq 0.30333E-14 -14.5181 0.30333E-14 -14.5181 0.10000E+01 0.0000 43 FeCl+ 0.16809E-16 -16.7744 0.14703E-16 -16.8326 0.87469E+00 -0.0581 46 FeO,aq 0.17314E-09 -9.7616 0.17314E-09 -9.7616 0.10000E+01 0.0000 47 FeOH+ 0.22187E-10 -10.6539 0.19407E-10 -10.7120 0.87469E+00 -0.0581 48 HFeO2- 0.15942E-07 -7.7975 0.13930E-07 -7.8561 0.87379E+00 -0.0586 49 FeO+ 0.12590E-14 -14.9000 0.11013E-14 -14.9581 0.87469E+00 -0.0581 51 FeO2- 0.13858E-07 -7.8583 0.12109E-07 -7.9169 0.87379E+00 -0.0586 52 HFeO2,aq 0.20261E-09 -9.6933 0.20261E-09 -9.6933 0.10000E+01 0.0000 53 H2,aq 0.18420E-08 -8.7347 0.18391E-08 -8.7354 0.99840E+00 -0.0007 54 KCl,aq 0.13663E-09 -9.8644 0.13663E-09 -9.8644 0.10000E+01 0.0000 55 KHSO4,aq 0.36216E-18 -18.4411 0.36216E-18 -18.4411 0.10000E+01 0.0000 56 KOH,aq 0.20861E-06 -6.6807 0.20861E-06 -6.6807 0.10000E+01 0.0000 57 KSO4- 0.17848E-07 -7.7484 0.15596E-07 -7.8070 0.87379E+00 -0.0586 58 MgCO3,aq 0.16567E-12 -12.7808 0.16567E-12 -12.7808 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22994E-14 -14.6384 0.20112E-14 -14.6965 0.87469E+00 -0.0581 60 MgCl+ 0.26953E-14 -14.5694 0.23575E-14 -14.6275 0.87469E+00 -0.0581 61 MgOH+ 0.45134E-10 -10.3455 0.39479E-10 -10.4036 0.87469E+00 -0.0581 63 MnO,aq 0.63071E-09 -9.2002 0.63071E-09 -9.2002 0.10000E+01 0.0000 64 MnOH+ 0.28125E-09 -9.5509 0.24601E-09 -9.6091 0.87469E+00 -0.0581 65 MnO2-2 0.19733E-11 -11.7048 0.12203E-11 -11.9135 0.61841E+00 -0.2087 66 HMnO2- 0.40454E-10 -10.3930 0.35348E-10 -10.4516 0.87379E+00 -0.0586 69 MnCl+ 0.89130E-14 -14.0500 0.77961E-14 -14.1081 0.87469E+00 -0.0581 70 MnSO4,aq 0.47890E-13 -13.3198 0.47890E-13 -13.3198 0.10000E+01 0.0000 71 NaCl,aq 0.31972E-06 -6.4952 0.31972E-06 -6.4952 0.10000E+01 0.0000 72 NaOH,aq 0.26681E-04 -4.5738 0.26681E-04 -4.5738 0.10000E+01 0.0000 74 OH- 0.51396E-02 -2.2891 0.44866E-02 -2.3481 0.87294E+00 -0.0590 79 HPO3-2 0.31039E-17 -17.5081 0.19195E-17 -17.7168 0.61841E+00 -0.2087 82 H3PO4,aq 0.38026E-16 -16.4199 0.38026E-16 -16.4199 0.10000E+01 0.0000 83 H2PO4- 0.88598E-09 -9.0526 0.77455E-09 -9.1109 0.87423E+00 -0.0584 84 PO4-3 0.60901E-08 -8.2154 0.21585E-08 -8.6658 0.35443E+00 -0.4505 87 H2P2O7-2 0.75927E-19 -19.1196 0.46953E-19 -19.3283 0.61841E+00 -0.2087 88 HP2O7-3 0.20851E-15 -15.6809 0.72014E-16 -16.1426 0.34538E+00 -0.4617 89 P2O7-4 0.85530E-15 -15.0679 0.13288E-15 -15.8765 0.15536E+00 -0.8087 90 H2S,aq 0.48409E-15 -15.3151 0.48332E-15 -15.3158 0.99840E+00 -0.0007 97 SO3-2 0.63667E-14 -14.1961 0.39677E-14 -14.4015 0.62320E+00 -0.2054 98 HSO3- 0.35528E-16 -16.4494 0.31044E-16 -16.5080 0.87379E+00 -0.0586 99 HSO4- 0.22429E-11 -11.6492 0.19629E-11 -11.7071 0.87513E+00 -0.0579 Charge balance for all species = 0.2996E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1525125E-09 -.9742432E-02 -.9812815E+01 0.0000 2 H2O 0.1000000E+01 0.5550906E+02 0.9993023E+06 0.0000 3 Cl- 0.1380401E-03 0.1383600E-03 0.4901794E+01 5.9553 4 SO4-- 0.2555782E-04 0.2557708E-04 0.2455231E+01 14.9471 5 HCO3- 0.6625008E-05 0.1310655E-04 0.7991571E+00 4.6368 6 HS- 0.1376870E-11 -.1295709E-08 -.4282128E-04 -2.0458 7 Al+++ 0.4946798E-27 0.3532245E-04 0.9523759E+00 1.8541 8 H4SiO4 0.4765138E-03 0.4904591E-02 0.4710720E+03 -3.3219 9 Ca++ 0.3995837E-07 0.5835218E-07 0.2336978E-02 12.1394 10 Mg++ 0.2196280E-10 0.6876570E-10 0.1670645E-05 8.8785 11 Fe++ 0.1271444E-12 0.3019789E-07 0.1685264E-02 6.6413 12 K+ 0.7314895E-04 0.7337554E-04 0.2867093E+01 5.6799 13 Na+ 0.9291256E-02 0.9766611E-02 0.2243730E+03 7.7833 14 Mn++ 0.1734182E-10 0.9717876E-09 0.5335016E-04 8.7763 15 HPO4-- 0.5337016E-06 0.5406777E-06 0.5185686E-01 13.2669 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3476992E+00 -.9715265E-02 -.3379840E+00 0.0000000E+00 2 H2O 0.5524502E+02 0.5535427E+02 -.1092513E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6074583E-03 0.2550576E-04 0.5819526E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5819539E-03 -.1292096E-08 -.5819526E-03 0.0000000E+00 7 Al+++ 0.6847231E-01 0.3522395E-04 0.6843709E-01 0.0000000E+00 8 H4SiO4 0.2186580E+00 0.4890914E-02 0.2137671E+00 0.0000000E+00 9 Ca++ 0.2416632E-01 0.5818946E-07 0.2416626E-01 0.0000000E+00 10 Mg++ 0.1666587E-01 0.6857394E-10 0.1666587E-01 0.0000000E+00 11 Fe++ 0.1497247E-01 0.3011368E-07 0.1497244E-01 0.0000000E+00 12 K+ 0.4458386E-02 0.7317093E-04 0.4385215E-02 0.0000000E+00 13 Na+ 0.2651893E-01 0.9739377E-02 0.1677956E-01 0.0000000E+00 14 Mn++ 0.3640932E-03 0.9690778E-09 0.3640922E-03 0.0000000E+00 15 HPO4-- 0.1242632E-03 0.5391700E-06 0.1237240E-03 0.0000000E+00 Chg. balance for solid moles: 0.5448E-16 Mass of aqueous solution: 0.997920E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 20.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1663E-01 -1.779 4.360 0.639 19.02 1.674 andradite 0.1867E-02 -2.729 0.9488 -0.023 4.140 0.2465 grossular 0.9079E-04 -4.042 0.4090E-01 -1.388 0.1784 0.1138E-01 apatite-OH 0.4124E-04 -4.385 0.2072E-01 -1.684 0.9039E-01 0.6583E-02 clinochlore 0.3333E-02 -2.477 1.853 0.268 8.084 0.7047 daphnite 0.2021E-02 -2.695 1.442 0.159 6.291 0.4369 chlorite-Mn 0.7282E-04 -4.138 0.5163E-01 -1.287 0.2253 0.1645E-01 microcline 0.4364E-02 -2.360 1.215 0.084 5.300 0.4745 stilbite 0.1809E-01 -1.743 12.75 1.105 55.61 5.945 stilpnomelane-Fe 0.4272E-04 -4.369 0.4606E-01 -1.337 0.2009 0.1591E-01 nontronite-Na 0.4608E-03 -3.336 0.1960 -0.708 0.8550 0.6088E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9536E+00 0.9536E+00 1.0000 -0.021 grossular 0.4637E-01 0.4637E-01 1.0000 -1.334 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6142E+00 0.6142E+00 1.0000 -0.212 daphnite 0.3724E+00 0.3724E+00 1.0000 -0.429 chlorite-Mn 0.1342E-01 0.1342E-01 1.0000 -1.872 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 22.919205 g Volume = 9.592482 cm3 Porosity: -2.0520% V(tot) - V(min): -.19288E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 20.9990000 g log = 1.3222 Original solution: 1000.0103000 g Original solution / Rock added: 47.62 (Water/Rock Ratio), log = 1.6778 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1687E-06 1.0073 0.1788E-06 0.1775E-06 CH4,gas 0.6415E-15 1.0129 0.6836E-15 0.6749E-15 H2,gas 0.2397E-05 1.0006 0.2522E-05 0.2521E-05 H2S,gas 0.1346E-13 0.9959 0.1410E-13 0.1415E-13 S2,gas 0.1112E-35 1.0000 0.1170E-35 0.1170E-35 CO,gas 0.1110E-15 1.0000 0.1168E-15 0.1168E-15 SO3,gas 0.1005E-39 1.0000 0.1057E-39 0.1057E-39 SO2,gas 0.9592E-23 1.0000 0.1009E-22 0.1009E-22 HCl,gas 0.5091E-17 1.0000 0.5356E-17 0.5356E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.19715E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.916 0.14937E+05 -6.748 3 CH4,gas 4.81 -12.36 -17.17 -4.291 0.29309E+05 -15.165 4 H2,gas 8.29 0.69 -7.60 -4.342 0.12974E+05 -5.598 5 H2S,gas -5.94 -21.79 -15.85 -7.925 0.27065E+05 -13.851 6 S2,gas -7.03 -44.96 -37.93 -5.836 0.64768E+05 -35.932 7 CO,gas 3.51 -14.42 -17.93 -5.518 0.30619E+05 -15.933 8 SO3,gas 17.43 -24.55 -41.98 -10.494 0.71672E+05 -39.976 9 SO2,gas 1.14 -23.86 -25.00 -6.666 0.42680E+05 -22.996 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32905E+05 -17.271 11 acmite 7.74 7.44 -0.30 -0.031 0.51386E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.07 -4.48 -0.224 0.76470E+04 20 analcite 3.37 2.99 -0.38 -0.042 0.64384E+03 21 andalusite 5.06 0.39 -4.68 -0.468 0.79844E+04 26 annite 20.21 17.49 -2.72 -0.151 0.46394E+04 27 phlogopite 27.15 24.20 -2.94 -0.164 0.50251E+04 29 anorthite 12.80 9.20 -3.59 -0.276 0.61365E+04 35 aragonite 0.99 -2.97 -3.96 -1.319 0.67577E+04 36 brucite 12.58 8.88 -3.70 -0.740 0.63145E+04 37 calcite 0.83 -2.97 -3.80 -1.268 0.64964E+04 38 carnegieite-low 9.06 6.32 -2.75 -0.393 0.46940E+04 39 carnegieite-high 10.13 6.32 -3.82 -0.546 0.65208E+04 40 carpholite-Mg 8.65 5.94 -2.71 -0.181 0.46231E+04 41 carpholite-Fe 6.78 3.71 -3.08 -0.205 0.52543E+04 42 celadonite 5.40 3.12 -2.28 -0.134 0.38858E+04 43 celadonite-Fe 3.94 0.89 -3.05 -0.179 0.52067E+04 44 chrysotile 23.94 19.99 -3.95 -0.329 0.67373E+04 50 chloritoid-Mg 13.26 9.26 -4.00 -0.266 0.68240E+04 51 chloritoid-Fe 9.24 7.03 -2.21 -0.147 0.37754E+04 52 chloritoid-Mn 11.46 9.16 -2.30 -0.153 0.39283E+04 54 coesite -2.37 -3.32 -0.95 -0.318 0.16265E+04 59 corundum 8.43 3.71 -4.73 -0.430 0.80682E+04 61 cristobalite -2.55 -3.32 -0.77 -0.258 0.13194E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.85 -1.04 -0.174 0.17792E+04 67 diopside 16.22 14.37 -1.84 -0.184 0.31442E+04 68 hedenbergite 14.24 12.14 -2.11 -0.211 0.35985E+04 75 epidote 24.78 24.32 -0.46 -0.022 0.78023E+03 76 clinozoisite 22.92 19.88 -3.05 -0.138 0.52006E+04 77 epidote-Fe 29.94 28.76 -1.18 -0.061 0.20074E+04 78 fayalite 14.08 9.96 -4.12 -0.588 0.70318E+04 79 ferrosilite 11.19 6.64 -4.55 -0.455 0.77671E+04 83 gibbsite 4.10 1.85 -2.24 -0.320 0.38304E+04 84 glaucophane 23.11 19.33 -3.78 -0.102 0.64469E+04 85 glaucophane-Fe 17.42 12.62 -4.79 -0.130 0.81852E+04 87 greenalite 16.19 13.28 -2.91 -0.243 0.49757E+04 90 hematite 12.60 12.59 0.00 0.000 0.62901E+01 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.99 -1.26 -0.126 0.21469E+04 96 julgoldite 70.57 67.10 -3.48 -0.090 0.59354E+04 97 kalsilite 7.62 4.21 -3.41 -0.487 0.58194E+04 98 kaolinite -1.27 -2.94 -1.66 -0.151 0.28387E+04 99 kyanite 4.93 0.39 -4.55 -0.455 0.77611E+04 101 laumontite 2.97 2.56 -0.41 -0.028 0.70796E+03 102 lawsonite 9.68 9.20 -0.47 -0.032 0.81038E+03 103 leucite 4.17 0.89 -3.28 -0.328 0.55963E+04 105 lizardite 23.29 19.99 -3.30 -0.275 0.56276E+04 107 magnetite 20.13 19.24 -0.90 -0.073 0.15325E+04 108 minnesotaite 10.46 6.64 -3.82 -0.225 0.65301E+04 110 magnesioferrite 26.26 21.47 -4.78 -0.391 0.81700E+04 113 margarite 17.45 12.91 -4.54 -0.182 0.77517E+04 120 muscovite 2.68 1.28 -1.40 -0.083 0.23953E+04 121 paragonite 4.34 3.38 -0.96 -0.056 0.16337E+04 122 nepheline 8.38 6.32 -2.06 -0.295 0.35219E+04 128 periclase-Fe 11.64 6.64 -5.00 -1.249 0.85336E+04 134 phlogopite-Na 29.73 26.31 -3.42 -0.190 0.58470E+04 136 prehnite 19.47 18.02 -1.45 -0.085 0.24674E+04 137 prehnite-Fe 22.59 22.46 -0.12 -0.007 0.20933E+03 138 pumpellyite-Fe 46.47 44.54 -1.93 -0.043 0.32998E+04 139 pumpellyite-Mg 49.19 46.78 -2.42 -0.054 0.41302E+04 145 pyroxmangite 7.42 5.45 -1.96 -0.392 0.33495E+04 146 pyrophyllite -6.10 -9.58 -3.48 -0.218 0.59446E+04 147 quartz -2.98 -3.32 -0.34 -0.113 0.58041E+03 152 rhodonite 7.46 5.45 -2.01 -0.402 0.34287E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.39 -4.94 -0.494 0.84265E+04 165 stilpnomelane-Mg 27.60 24.37 -3.23 -0.096 0.55172E+04 171 talc 16.55 13.35 -3.21 -0.189 0.54736E+04 174 tephroite 18.11 14.23 -3.88 -0.555 0.66287E+04 177 topaz-H 4.67 0.39 -4.28 -0.389 0.73102E+04 178 tridymite -2.61 -3.32 -0.71 -0.236 0.12077E+04 187 wairakite 4.06 2.56 -1.50 -0.088 0.25588E+04 188 walstromite 11.53 8.82 -2.71 -0.542 0.46278E+04 189 wollastonite 10.48 8.82 -1.66 -0.333 0.28417E+04 190 pseudo-wollastonite 11.02 8.82 -2.20 -0.440 0.37604E+04 191 zoisite 22.96 19.88 -3.09 -0.140 0.52731E+04 192 akaganeite 7.77 6.30 -1.47 -0.318 0.25113E+04 193 beidellite-Ca -1.56 -5.87 -4.31 -0.267 0.73571E+04 195 beidellite-K -1.44 -6.00 -4.56 -0.279 0.77896E+04 196 beidellite-Mg -1.71 -6.41 -4.70 -0.291 0.80245E+04 197 beidellite-Na -1.26 -5.30 -4.05 -0.248 0.69083E+04 199 chalcedony -2.79 -3.32 -0.53 -0.176 0.90073E+03 201 montmorillonite-Ca -2.21 -5.26 -3.04 -0.188 0.51983E+04 202 montmorillonite-K -2.16 -5.39 -3.23 -0.198 0.55086E+04 203 montmorillonite-Mg -2.40 -5.80 -3.39 -0.210 0.57967E+04 204 montmorillonite-Na -1.96 -4.69 -2.73 -0.167 0.46654E+04 205 nontronite-Ca 3.28 3.02 -0.26 -0.017 0.44792E+03 206 nontronite-H 2.60 1.01 -1.58 -0.106 0.27002E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11269E+04 224 tobermorite 9.84 6.79 -3.05 -0.832 0.52057E+04 233 boehmite 4.43 1.85 -2.58 -0.429 0.43976E+04 235 ferrous-oxide 9.82 6.64 -3.18 -0.796 0.54347E+04 240 silica-amorphous -2.08 -3.32 -1.24 -0.414 0.21209E+04 242 an20ab80 2.08 1.58 -0.50 -0.039 0.85569E+03 243 an25ab75 2.71 2.05 -0.65 -0.050 0.11175E+04 244 an30ab70 3.34 2.53 -0.81 -0.063 0.13877E+04 245 tr.625ac.25prg.125 45.31 40.69 -4.62 -0.124 0.78883E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 20.9990000 g New total amount of reactant added: 21.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2990E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 21.9990000 Water: Moles liquid = 0.5535E+02 kg liquid = 0.9971E+00 Moles total = 0.5523E+02 kg total = 0.9950E+00 Activity = 1.0000 Stoichiometric ionic strength = .5240381E-02 Osmotic coef. = 0.9617 True ionic strength = .9469972E-02 Chg. balance for total moles = 0.2990E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15249E-09 -9.8168 0.13362E-09 -9.8741 0.87629E+00 -0.0574 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13805E-03 -3.8600 0.12058E-03 -3.9187 0.87344E+00 -0.0588 4 SO4-- 0.25560E-04 -4.5924 0.15800E-04 -4.8013 0.61815E+00 -0.2089 5 HCO3- 0.66201E-05 -5.1791 0.57869E-05 -5.2376 0.87413E+00 -0.0584 6 HS- 0.15856E-11 -11.7998 0.13851E-11 -11.8585 0.87351E+00 -0.0587 7 Al+++ 0.46803E-27 -27.3297 0.16101E-27 -27.7932 0.34401E+00 -0.4634 8 H4SiO4 0.48443E-03 -3.3148 0.48443E-03 -3.3148 0.10000E+01 0.0000 9 Ca++ 0.39951E-07 -7.3985 0.24599E-07 -7.6091 0.61573E+00 -0.2106 10 Mg++ 0.22488E-10 -10.6480 0.13813E-10 -10.8597 0.61421E+00 -0.2117 11 Fe++ 0.12667E-12 -12.8973 0.77850E-13 -13.1087 0.61457E+00 -0.2114 12 K+ 0.73717E-04 -4.1324 0.64447E-04 -4.1908 0.87425E+00 -0.0584 13 Na+ 0.93635E-02 -2.0286 0.81778E-02 -2.0874 0.87337E+00 -0.0588 14 Mn++ 0.17757E-10 -10.7506 0.10918E-10 -10.9619 0.61485E+00 -0.2112 15 HPO4-- 0.53572E-06 -6.2711 0.33118E-06 -6.4799 0.61820E+00 -0.2089 16 HSiO3- 0.40496E-02 -2.3926 0.35371E-02 -2.4514 0.87344E+00 -0.0588 17 Ca(HSiO3)+ 0.22296E-08 -8.6518 0.19494E-08 -8.7101 0.87435E+00 -0.0583 18 Mg(HSiO3)+ 0.15581E-11 -11.8074 0.13623E-11 -11.8657 0.87435E+00 -0.0583 19 NaHSiO3,aq 0.45941E-03 -3.3378 0.45941E-03 -3.3378 0.10000E+01 0.0000 20 AlO+ 0.13314E-14 -14.8757 0.11641E-14 -14.9340 0.87435E+00 -0.0583 22 HAlO2,aq 0.17434E-08 -8.7586 0.17434E-08 -8.7586 0.10000E+01 0.0000 23 AlO2- 0.33385E-04 -4.4764 0.29132E-04 -4.5356 0.87259E+00 -0.0592 24 CH4,aq 0.49858E-18 -18.3023 0.49778E-18 -18.3030 0.99839E+00 -0.0007 29 CO,aq 0.76528E-19 -19.1162 0.76528E-19 -19.1162 0.10000E+01 0.0000 30 CO2,aq 0.15616E-08 -8.8064 0.15590E-08 -8.8071 0.99839E+00 -0.0007 31 CO3-2 0.64851E-05 -5.1881 0.40042E-05 -5.3975 0.61744E+00 -0.2094 32 CaCO3,aq 0.12064E-08 -8.9185 0.12064E-08 -8.9185 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41022E-11 -11.3870 0.35868E-11 -11.4453 0.87435E+00 -0.0583 34 CaCl+ 0.54058E-11 -11.2671 0.47265E-11 -11.3255 0.87435E+00 -0.0583 35 CaCl2,aq 0.13270E-15 -15.8771 0.13270E-15 -15.8771 0.10000E+01 0.0000 36 CaOH+ 0.14846E-07 -7.8284 0.12981E-07 -7.8867 0.87435E+00 -0.0583 37 CaSO4,aq 0.12110E-09 -9.9169 0.12110E-09 -9.9169 0.10000E+01 0.0000 38 HCl,aq 0.30307E-14 -14.5185 0.30307E-14 -14.5185 0.10000E+01 0.0000 43 FeCl+ 0.16722E-16 -16.7767 0.14621E-16 -16.8350 0.87435E+00 -0.0583 46 FeO,aq 0.17242E-09 -9.7634 0.17242E-09 -9.7634 0.10000E+01 0.0000 47 FeOH+ 0.22091E-10 -10.6558 0.19315E-10 -10.7141 0.87435E+00 -0.0583 48 HFeO2- 0.15889E-07 -7.7989 0.13879E-07 -7.8577 0.87344E+00 -0.0588 49 FeO+ 0.12314E-14 -14.9096 0.10767E-14 -14.9679 0.87435E+00 -0.0583 51 FeO2- 0.13568E-07 -7.8675 0.11851E-07 -7.9262 0.87344E+00 -0.0588 52 HFeO2,aq 0.19819E-09 -9.7029 0.19819E-09 -9.7029 0.10000E+01 0.0000 53 H2,aq 0.19090E-08 -8.7192 0.19059E-08 -8.7199 0.99839E+00 -0.0007 54 KCl,aq 0.13760E-09 -9.8614 0.13760E-09 -9.8614 0.10000E+01 0.0000 55 KHSO4,aq 0.36411E-18 -18.4388 0.36411E-18 -18.4388 0.10000E+01 0.0000 56 KOH,aq 0.21026E-06 -6.6772 0.21026E-06 -6.6772 0.10000E+01 0.0000 57 KSO4- 0.17961E-07 -7.7457 0.15688E-07 -7.8044 0.87344E+00 -0.0588 58 MgCO3,aq 0.16926E-12 -12.7714 0.16926E-12 -12.7714 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23489E-14 -14.6291 0.20538E-14 -14.6874 0.87435E+00 -0.0583 60 MgCl+ 0.27556E-14 -14.5598 0.24094E-14 -14.6181 0.87435E+00 -0.0583 61 MgOH+ 0.46184E-10 -10.3355 0.40381E-10 -10.3938 0.87435E+00 -0.0583 63 MnO,aq 0.64547E-09 -9.1901 0.64547E-09 -9.1901 0.10000E+01 0.0000 64 MnOH+ 0.28779E-09 -9.5409 0.25163E-09 -9.5992 0.87435E+00 -0.0583 65 MnO2-2 0.20248E-11 -11.6936 0.12502E-11 -11.9030 0.61744E+00 -0.2094 66 HMnO2- 0.41439E-10 -10.3826 0.36195E-10 -10.4414 0.87344E+00 -0.0588 69 MnCl+ 0.91125E-14 -14.0404 0.79675E-14 -14.0987 0.87435E+00 -0.0583 70 MnSO4,aq 0.48887E-13 -13.3108 0.48887E-13 -13.3108 0.10000E+01 0.0000 71 NaCl,aq 0.32198E-06 -6.4922 0.32198E-06 -6.4922 0.10000E+01 0.0000 72 NaOH,aq 0.26892E-04 -4.5704 0.26892E-04 -4.5704 0.10000E+01 0.0000 74 OH- 0.51444E-02 -2.2887 0.44890E-02 -2.3479 0.87259E+00 -0.0592 79 HPO3-2 0.32289E-17 -17.4909 0.19937E-17 -17.7003 0.61744E+00 -0.2094 82 H3PO4,aq 0.38070E-16 -16.4194 0.38070E-16 -16.4194 0.10000E+01 0.0000 83 H2PO4- 0.88782E-09 -9.0517 0.77586E-09 -9.1102 0.87389E+00 -0.0585 84 PO4-3 0.61275E-08 -8.2127 0.21645E-08 -8.6646 0.35324E+00 -0.4519 87 H2P2O7-2 0.76301E-19 -19.1175 0.47112E-19 -19.3269 0.61744E+00 -0.2094 88 HP2O7-3 0.21006E-15 -15.6776 0.72296E-16 -16.1409 0.34416E+00 -0.4632 89 P2O7-4 0.86444E-15 -15.0633 0.13347E-15 -15.8746 0.15441E+00 -0.8113 90 H2S,aq 0.55698E-15 -15.2542 0.55608E-15 -15.2549 0.99839E+00 -0.0007 97 SO3-2 0.65984E-14 -14.1806 0.41060E-14 -14.3866 0.62226E+00 -0.2060 98 HSO3- 0.36760E-16 -16.4346 0.32108E-16 -16.4934 0.87344E+00 -0.0588 99 HSO4- 0.22394E-11 -11.6499 0.19590E-11 -11.7080 0.87480E+00 -0.0581 Charge balance for all species = 0.2987E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1524873E-09 -.9820699E-02 -.9891559E+01 0.0000 2 H2O 0.1000000E+01 0.5550898E+02 0.9992920E+06 0.0000 3 Cl- 0.1380529E-03 0.1383751E-03 0.4902284E+01 5.9554 4 SO4-- 0.2556049E-04 0.2557982E-04 0.2455471E+01 14.9469 5 HCO3- 0.6620143E-05 0.1310797E-04 0.7992369E+00 4.6366 6 HS- 0.1585641E-11 -.1241998E-08 -.4104581E-04 -1.9844 7 Al+++ 0.4680285E-27 0.3338724E-04 0.9001901E+00 1.8292 8 H4SiO4 0.4844253E-03 0.4993432E-02 0.4796007E+03 -3.3148 9 Ca++ 0.3995067E-07 0.5836338E-07 0.2337406E-02 12.1391 10 Mg++ 0.2248825E-10 0.7040449E-10 0.1710443E-05 8.8885 11 Fe++ 0.1266731E-12 0.2985073E-07 0.1665875E-02 6.6395 12 K+ 0.7371736E-04 0.7394572E-04 0.2889347E+01 5.6833 13 Na+ 0.9363517E-02 0.9850140E-02 0.2262899E+03 7.7868 14 Mn++ 0.1775660E-10 0.9945409E-09 0.5459881E-04 8.7864 15 HPO4-- 0.5357198E-06 0.5427352E-06 0.5205373E-01 13.2683 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3642577E+00 -.9792248E-02 -.3544655E+00 0.0000000E+00 2 H2O 0.5523248E+02 0.5534817E+02 -.1156820E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6351718E-03 0.2550571E-04 0.6096660E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6096673E-03 -.1238399E-08 -.6096660E-03 0.0000000E+00 7 Al+++ 0.7173305E-01 0.3329051E-04 0.7169976E-01 0.0000000E+00 8 H4SiO4 0.2290708E+00 0.4978965E-02 0.2240918E+00 0.0000000E+00 9 Ca++ 0.2531646E-01 0.5819430E-07 0.2531640E-01 0.0000000E+00 10 Mg++ 0.1745952E-01 0.7020052E-10 0.1745952E-01 0.0000000E+00 11 Fe++ 0.1568548E-01 0.2976425E-07 0.1568545E-01 0.0000000E+00 12 K+ 0.4670701E-02 0.7373149E-04 0.4596969E-02 0.0000000E+00 13 Na+ 0.2777418E-01 0.9821603E-02 0.1795257E-01 0.0000000E+00 14 Mn++ 0.3814318E-03 0.9916596E-09 0.3814308E-03 0.0000000E+00 15 HPO4-- 0.1301808E-03 0.5411628E-06 0.1296396E-03 0.0000000E+00 Chg. balance for solid moles: -.2786E-16 Mass of aqueous solution: 0.997820E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 21.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1781E-01 -1.749 4.671 0.669 19.45 1.793 andradite 0.2014E-02 -2.696 1.023 0.010 4.262 0.2658 grossular 0.9452E-04 -4.024 0.4258E-01 -1.371 0.1773 0.1185E-01 apatite-OH 0.4321E-04 -4.364 0.2171E-01 -1.663 0.9040E-01 0.6898E-02 clinochlore 0.3492E-02 -2.457 1.941 0.288 8.083 0.7383 daphnite 0.2060E-02 -2.686 1.470 0.167 6.121 0.4453 chlorite-Mn 0.7629E-04 -4.118 0.5408E-01 -1.267 0.2253 0.1724E-01 microcline 0.4546E-02 -2.342 1.265 0.102 5.270 0.4943 stilbite 0.1878E-01 -1.726 13.23 1.122 55.11 6.172 stilpnomelane-Fe 0.1019E-03 -3.992 0.1098 -0.959 0.4574 0.3794E-01 nontronite-Na 0.4252E-03 -3.371 0.1808 -0.743 0.7530 0.5617E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9552E+00 0.9552E+00 1.0000 -0.020 grossular 0.4484E-01 0.4484E-01 1.0000 -1.348 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6205E+00 0.6205E+00 1.0000 -0.207 daphnite 0.3660E+00 0.3660E+00 1.0000 -0.437 chlorite-Mn 0.1355E-01 0.1355E-01 1.0000 -1.868 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 24.010842 g Volume = 10.038441 cm3 Porosity: -2.4372% V(tot) - V(min): -.23884E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 21.9990000 g log = 1.3424 Original solution: 1000.0103000 g Original solution / Rock added: 45.46 (Water/Rock Ratio), log = 1.6576 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1684E-06 1.0073 0.1785E-06 0.1772E-06 CH4,gas 0.7388E-15 1.0129 0.7872E-15 0.7771E-15 H2,gas 0.2484E-05 1.0006 0.2614E-05 0.2613E-05 H2S,gas 0.1548E-13 0.9959 0.1622E-13 0.1628E-13 S2,gas 0.1371E-35 1.0000 0.1442E-35 0.1442E-35 CO,gas 0.1149E-15 1.0000 0.1208E-15 0.1208E-15 SO3,gas 0.1003E-39 1.0000 0.1055E-39 0.1055E-39 SO2,gas 0.9915E-23 1.0000 0.1043E-22 0.1043E-22 HCl,gas 0.5087E-17 1.0000 0.5351E-17 0.5351E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 116 microcline -2.43 -2.43 0.00 0.000 0.18957E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.68244E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.916 0.14938E+05 -6.748 3 CH4,gas 4.81 -12.29 -17.10 -4.276 0.29204E+05 -15.104 4 H2,gas 8.29 0.70 -7.58 -4.333 0.12947E+05 -5.583 5 H2S,gas -5.94 -21.73 -15.79 -7.895 0.26961E+05 -13.790 6 S2,gas -7.03 -44.87 -37.84 -5.822 0.64613E+05 -35.841 7 CO,gas 3.51 -14.41 -17.92 -5.513 0.30594E+05 -15.918 8 SO3,gas 17.43 -24.55 -41.98 -10.494 0.71674E+05 -39.977 9 SO2,gas 1.14 -23.85 -24.98 -6.662 0.42656E+05 -22.982 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32906E+05 -17.272 11 acmite 7.74 7.44 -0.29 -0.030 0.49995E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.07 -4.48 -0.224 0.76439E+04 20 analcite 3.37 2.99 -0.38 -0.043 0.65605E+03 21 andalusite 5.06 0.34 -4.72 -0.472 0.80571E+04 26 annite 20.21 17.49 -2.72 -0.151 0.46488E+04 27 phlogopite 27.15 24.23 -2.91 -0.162 0.49736E+04 29 anorthite 12.80 9.17 -3.63 -0.279 0.61976E+04 35 aragonite 0.99 -2.97 -3.96 -1.320 0.67595E+04 36 brucite 12.58 8.89 -3.69 -0.738 0.62973E+04 37 calcite 0.83 -2.97 -3.81 -1.269 0.64981E+04 38 carnegieite-low 9.06 6.30 -2.76 -0.395 0.47184E+04 39 carnegieite-high 10.13 6.30 -3.83 -0.548 0.65452E+04 40 carpholite-Mg 8.65 5.92 -2.73 -0.182 0.46665E+04 41 carpholite-Fe 6.78 3.67 -3.11 -0.208 0.53180E+04 42 celadonite 5.40 3.14 -2.26 -0.133 0.38564E+04 43 celadonite-Fe 3.94 0.89 -3.04 -0.179 0.51976E+04 44 chrysotile 23.94 20.04 -3.90 -0.325 0.66615E+04 50 chloritoid-Mg 13.26 9.23 -4.03 -0.269 0.68796E+04 51 chloritoid-Fe 9.24 6.98 -2.26 -0.150 0.38513E+04 52 chloritoid-Mn 11.46 9.13 -2.33 -0.156 0.39839E+04 54 coesite -2.37 -3.31 -0.95 -0.315 0.16143E+04 59 corundum 8.43 3.66 -4.78 -0.434 0.81532E+04 61 cristobalite -2.55 -3.31 -0.77 -0.255 0.13072E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.83 -1.07 -0.178 0.18217E+04 67 diopside 16.22 14.40 -1.82 -0.182 0.31031E+04 68 hedenbergite 14.24 12.15 -2.10 -0.210 0.35777E+04 75 epidote 24.78 24.28 -0.50 -0.024 0.84594E+03 76 clinozoisite 22.92 19.82 -3.10 -0.141 0.52924E+04 77 epidote-Fe 29.94 28.74 -1.20 -0.062 0.20470E+04 78 fayalite 14.08 9.96 -4.11 -0.588 0.70258E+04 79 ferrosilite 11.19 6.65 -4.54 -0.454 0.77489E+04 83 gibbsite 4.10 1.83 -2.27 -0.324 0.38729E+04 84 glaucophane 23.11 19.38 -3.73 -0.101 0.63710E+04 85 glaucophane-Fe 17.42 12.63 -4.78 -0.129 0.81702E+04 87 greenalite 16.19 13.29 -2.91 -0.242 0.49607E+04 90 hematite 12.60 12.57 -0.02 -0.003 0.39015E+02 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.99 -1.26 -0.126 0.21591E+04 96 julgoldite 70.57 67.10 -3.48 -0.090 0.59358E+04 97 kalsilite 7.62 4.20 -3.42 -0.489 0.58438E+04 98 kaolinite -1.27 -2.97 -1.70 -0.154 0.28993E+04 99 kyanite 4.93 0.34 -4.59 -0.459 0.78339E+04 101 laumontite 2.97 2.54 -0.44 -0.029 0.74459E+03 102 lawsonite 9.68 9.17 -0.51 -0.034 0.87143E+03 103 leucite 4.17 0.88 -3.28 -0.328 0.56085E+04 105 lizardite 23.29 20.04 -3.25 -0.271 0.55517E+04 107 magnetite 20.13 19.21 -0.92 -0.075 0.15684E+04 108 minnesotaite 10.46 6.66 -3.80 -0.224 0.64907E+04 110 magnesioferrite 26.26 21.46 -4.79 -0.391 0.81856E+04 113 margarite 17.45 12.83 -4.63 -0.185 0.78977E+04 120 muscovite 2.68 1.23 -1.45 -0.085 0.24802E+04 121 paragonite 4.34 3.33 -1.01 -0.059 0.17187E+04 122 nepheline 8.38 6.30 -2.08 -0.297 0.35463E+04 128 periclase-Fe 11.64 6.64 -5.00 -1.250 0.85368E+04 134 phlogopite-Na 29.73 26.34 -3.39 -0.189 0.57955E+04 136 prehnite 19.47 17.99 -1.47 -0.087 0.25167E+04 137 prehnite-Fe 22.59 22.45 -0.14 -0.008 0.23256E+03 138 pumpellyite-Fe 46.47 44.45 -2.02 -0.045 0.34441E+04 139 pumpellyite-Mg 49.19 46.70 -2.49 -0.055 0.42543E+04 145 pyroxmangite 7.42 5.47 -1.94 -0.389 0.33201E+04 146 pyrophyllite -6.10 -9.60 -3.50 -0.219 0.59807E+04 147 quartz -2.98 -3.31 -0.33 -0.111 0.56820E+03 152 rhodonite 7.46 5.47 -1.99 -0.398 0.33993E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 156 sillimanite 5.32 0.34 -4.98 -0.498 0.84993E+04 165 stilpnomelane-Mg 27.60 24.42 -3.17 -0.095 0.54158E+04 171 talc 16.55 13.41 -3.15 -0.185 0.53733E+04 174 tephroite 18.11 14.26 -3.85 -0.551 0.65822E+04 177 topaz-H 4.67 0.34 -4.32 -0.393 0.73830E+04 178 tridymite -2.61 -3.31 -0.70 -0.233 0.11955E+04 187 wairakite 4.06 2.54 -1.52 -0.089 0.25954E+04 188 walstromite 11.53 8.82 -2.70 -0.541 0.46161E+04 189 wollastonite 10.48 8.82 -1.66 -0.331 0.28300E+04 190 pseudo-wollastonite 11.02 8.82 -2.20 -0.439 0.37487E+04 191 zoisite 22.96 19.82 -3.14 -0.143 0.53650E+04 192 akaganeite 7.77 6.29 -1.48 -0.320 0.25277E+04 193 beidellite-Ca -1.56 -5.90 -4.34 -0.269 0.74114E+04 195 beidellite-K -1.44 -6.03 -4.59 -0.281 0.78418E+04 196 beidellite-Mg -1.71 -6.44 -4.73 -0.293 0.80758E+04 197 beidellite-Na -1.26 -5.33 -4.08 -0.250 0.69605E+04 199 chalcedony -2.79 -3.31 -0.52 -0.173 0.88852E+03 201 montmorillonite-Ca -2.21 -5.27 -3.05 -0.189 0.52148E+04 202 montmorillonite-K -2.16 -5.40 -3.23 -0.198 0.55231E+04 203 montmorillonite-Mg -2.40 -5.80 -3.40 -0.211 0.58103E+04 204 montmorillonite-Na -1.96 -4.70 -2.74 -0.168 0.46799E+04 205 nontronite-Ca 3.28 3.02 -0.26 -0.017 0.44993E+03 206 nontronite-H 2.60 1.01 -1.58 -0.106 0.27022E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11260E+04 224 tobermorite 9.84 6.80 -3.04 -0.830 0.51939E+04 233 boehmite 4.43 1.83 -2.60 -0.433 0.44401E+04 235 ferrous-oxide 9.82 6.64 -3.18 -0.796 0.54378E+04 240 silica-amorphous -2.08 -3.31 -1.23 -0.412 0.21087E+04 242 an20ab80 2.08 1.57 -0.51 -0.039 0.86790E+03 243 an25ab75 2.71 2.05 -0.66 -0.051 0.11328E+04 244 an30ab70 3.34 2.52 -0.82 -0.063 0.14060E+04 245 tr.625ac.25prg.125 45.31 40.77 -4.54 -0.122 0.77516E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 21.9990000 g New total amount of reactant added: 22.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2991E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 22.9990000 Water: Moles liquid = 0.5534E+02 kg liquid = 0.9970E+00 Moles total = 0.5522E+02 kg total = 0.9948E+00 Activity = 1.0000 Stoichiometric ionic strength = .5273335E-02 Osmotic coef. = 0.9616 True ionic strength = .9540593E-02 Chg. balance for total moles = 0.2991E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15247E-09 -9.8168 0.13356E-09 -9.8743 0.87597E+00 -0.0575 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13807E-03 -3.8599 0.12055E-03 -3.9188 0.87311E+00 -0.0589 4 SO4-- 0.25563E-04 -4.5924 0.15778E-04 -4.8019 0.61723E+00 -0.2096 5 HCO3- 0.66156E-05 -5.1794 0.57807E-05 -5.2380 0.87380E+00 -0.0586 6 HS- 0.18153E-11 -11.7411 0.15850E-11 -11.8000 0.87318E+00 -0.0589 7 Al+++ 0.44393E-27 -27.3527 0.15220E-27 -27.8176 0.34284E+00 -0.4649 8 H4SiO4 0.49213E-03 -3.3079 0.49213E-03 -3.3079 0.10000E+01 0.0000 9 Ca++ 0.39946E-07 -7.3985 0.24559E-07 -7.6098 0.61479E+00 -0.2113 10 Mg++ 0.23000E-10 -10.6383 0.14105E-10 -10.8506 0.61327E+00 -0.2124 11 Fe++ 0.12624E-12 -12.8988 0.77462E-13 -13.1109 0.61363E+00 -0.2121 12 K+ 0.74268E-04 -4.1292 0.64904E-04 -4.1877 0.87392E+00 -0.0585 13 Na+ 0.94336E-02 -2.0253 0.82358E-02 -2.0843 0.87303E+00 -0.0590 14 Mn++ 0.18160E-10 -10.7409 0.11149E-10 -10.9528 0.61391E+00 -0.2119 15 HPO4-- 0.53765E-06 -6.2695 0.33188E-06 -6.4790 0.61728E+00 -0.2095 16 HSiO3- 0.41175E-02 -2.3854 0.35950E-02 -2.4443 0.87311E+00 -0.0589 17 Ca(HSiO3)+ 0.22633E-08 -8.6453 0.19781E-08 -8.7037 0.87402E+00 -0.0585 18 Mg(HSiO3)+ 0.16177E-11 -11.7911 0.14139E-11 -11.8496 0.87402E+00 -0.0585 19 NaHSiO3,aq 0.47025E-03 -3.3277 0.47025E-03 -3.3277 0.10000E+01 0.0000 20 AlO+ 0.12602E-14 -14.8996 0.11015E-14 -14.9580 0.87402E+00 -0.0585 22 HAlO2,aq 0.16503E-08 -8.7824 0.16503E-08 -8.7824 0.10000E+01 0.0000 23 AlO2- 0.31630E-04 -4.4999 0.27590E-04 -4.5593 0.87225E+00 -0.0594 24 CH4,aq 0.57076E-18 -18.2435 0.56983E-18 -18.2443 0.99838E+00 -0.0007 29 CO,aq 0.79068E-19 -19.1020 0.79068E-19 -19.1020 0.10000E+01 0.0000 30 CO2,aq 0.15592E-08 -8.8071 0.15567E-08 -8.8078 0.99838E+00 -0.0007 31 CO3-2 0.64910E-05 -5.1877 0.40018E-05 -5.3977 0.61652E+00 -0.2101 32 CaCO3,aq 0.12037E-08 -8.9195 0.12037E-08 -8.9195 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40927E-11 -11.3880 0.35771E-11 -11.4465 0.87402E+00 -0.0585 34 CaCl+ 0.53974E-11 -11.2678 0.47174E-11 -11.3263 0.87402E+00 -0.0585 35 CaCl2,aq 0.13241E-15 -15.8781 0.13241E-15 -15.8781 0.10000E+01 0.0000 36 CaOH+ 0.14835E-07 -7.8287 0.12966E-07 -7.8872 0.87402E+00 -0.0585 37 CaSO4,aq 0.12073E-09 -9.9182 0.12073E-09 -9.9182 0.10000E+01 0.0000 38 HCl,aq 0.30284E-14 -14.5188 0.30284E-14 -14.5188 0.10000E+01 0.0000 43 FeCl+ 0.16640E-16 -16.7788 0.14544E-16 -16.8373 0.87402E+00 -0.0585 46 FeO,aq 0.17172E-09 -9.7652 0.17172E-09 -9.7652 0.10000E+01 0.0000 47 FeOH+ 0.21999E-10 -10.6576 0.19228E-10 -10.7161 0.87402E+00 -0.0585 48 HFeO2- 0.15839E-07 -7.8003 0.13829E-07 -7.8592 0.87311E+00 -0.0589 49 FeO+ 0.12055E-14 -14.9188 0.10536E-14 -14.9773 0.87402E+00 -0.0585 51 FeO2- 0.13296E-07 -7.8763 0.11609E-07 -7.9352 0.87311E+00 -0.0589 52 HFeO2,aq 0.19404E-09 -9.7121 0.19404E-09 -9.7121 0.10000E+01 0.0000 53 H2,aq 0.19754E-08 -8.7044 0.19722E-08 -8.7051 0.99838E+00 -0.0007 54 KCl,aq 0.13854E-09 -9.8584 0.13854E-09 -9.8584 0.10000E+01 0.0000 55 KHSO4,aq 0.36601E-18 -18.4365 0.36601E-18 -18.4365 0.10000E+01 0.0000 56 KOH,aq 0.21185E-06 -6.6740 0.21185E-06 -6.6740 0.10000E+01 0.0000 57 KSO4- 0.18070E-07 -7.7430 0.15777E-07 -7.8020 0.87311E+00 -0.0589 58 MgCO3,aq 0.17275E-12 -12.7626 0.17275E-12 -12.7626 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23970E-14 -14.6203 0.20950E-14 -14.6788 0.87402E+00 -0.0585 60 MgCl+ 0.28142E-14 -14.5506 0.24597E-14 -14.6091 0.87402E+00 -0.0585 61 MgOH+ 0.47202E-10 -10.3260 0.41255E-10 -10.3845 0.87402E+00 -0.0585 63 MnO,aq 0.65976E-09 -9.1806 0.65976E-09 -9.1806 0.10000E+01 0.0000 64 MnOH+ 0.29413E-09 -9.5315 0.25708E-09 -9.5899 0.87402E+00 -0.0585 65 MnO2-2 0.20747E-11 -11.6830 0.12791E-11 -11.8931 0.61652E+00 -0.2101 66 HMnO2- 0.42393E-10 -10.3727 0.37014E-10 -10.4316 0.87311E+00 -0.0589 69 MnCl+ 0.93063E-14 -14.0312 0.81339E-14 -14.0897 0.87402E+00 -0.0585 70 MnSO4,aq 0.49853E-13 -13.3023 0.49853E-13 -13.3023 0.10000E+01 0.0000 71 NaCl,aq 0.32417E-06 -6.4892 0.32417E-06 -6.4892 0.10000E+01 0.0000 72 NaOH,aq 0.27095E-04 -4.5671 0.27095E-04 -4.5671 0.10000E+01 0.0000 74 OH- 0.51489E-02 -2.2883 0.44911E-02 -2.3476 0.87225E+00 -0.0594 79 HPO3-2 0.33532E-17 -17.4745 0.20673E-17 -17.6846 0.61652E+00 -0.2101 82 H3PO4,aq 0.38114E-16 -16.4189 0.38114E-16 -16.4189 0.10000E+01 0.0000 83 H2PO4- 0.88960E-09 -9.0508 0.77712E-09 -9.1095 0.87355E+00 -0.0587 84 PO4-3 0.61632E-08 -8.2102 0.21700E-08 -8.6635 0.35210E+00 -0.4533 87 H2P2O7-2 0.76664E-19 -19.1154 0.47265E-19 -19.3255 0.61652E+00 -0.2101 88 HP2O7-3 0.21157E-15 -15.6746 0.72565E-16 -16.1393 0.34299E+00 -0.4647 89 P2O7-4 0.87326E-15 -15.0589 0.13404E-15 -15.8728 0.15349E+00 -0.8139 90 H2S,aq 0.63710E-15 -15.1958 0.63606E-15 -15.1965 0.99838E+00 -0.0007 97 SO3-2 0.68283E-14 -14.1657 0.42428E-14 -14.3723 0.62136E+00 -0.2067 98 HSO3- 0.37982E-16 -16.4204 0.33163E-16 -16.4794 0.87311E+00 -0.0589 99 HSO4- 0.22360E-11 -11.6505 0.19553E-11 -11.7088 0.87447E+00 -0.0583 Charge balance for all species = 0.2987E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1524707E-09 -.9897062E-02 -.9968387E+01 0.0000 2 H2O 0.1000000E+01 0.5550890E+02 0.9992819E+06 0.0000 3 Cl- 0.1380658E-03 0.1383901E-03 0.4902775E+01 5.9555 4 SO4-- 0.2556316E-04 0.2558255E-04 0.2455712E+01 14.9467 5 HCO3- 0.6615638E-05 0.1310940E-04 0.7993169E+00 4.6363 6 HS- 0.1815263E-11 -.1190597E-08 -.3934679E-04 -1.9256 7 Al+++ 0.4439267E-27 0.3163205E-04 0.8528593E+00 1.8054 8 H4SiO4 0.4921272E-03 0.5079875E-02 0.4878990E+03 -3.3079 9 Ca++ 0.3994615E-07 0.5837782E-07 0.2337964E-02 12.1388 10 Mg++ 0.2299979E-10 0.7199735E-10 0.1749126E-05 8.8980 11 Fe++ 0.1262358E-12 0.2952273E-07 0.1647556E-02 6.6377 12 K+ 0.7426845E-04 0.7449851E-04 0.2910921E+01 5.6866 13 Na+ 0.9433577E-02 0.9931243E-02 0.2281512E+03 7.7900 14 Mn++ 0.1816039E-10 0.1016585E-08 0.5580850E-04 8.7959 15 HPO4-- 0.5376458E-06 0.5446986E-06 0.5224159E-01 13.2696 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3808163E+00 -.9867317E-02 -.3709489E+00 0.0000000E+00 2 H2O 0.5521995E+02 0.5534207E+02 -.1221224E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6628852E-03 0.2550566E-04 0.6373795E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6373807E-03 -.1187019E-08 -.6373795E-03 0.0000000E+00 7 Al+++ 0.7499380E-01 0.3153698E-04 0.7496226E-01 0.0000000E+00 8 H4SiO4 0.2394836E+00 0.5064608E-02 0.2344190E+00 0.0000000E+00 9 Ca++ 0.2646660E-01 0.5820236E-07 0.2646654E-01 0.0000000E+00 10 Mg++ 0.1825317E-01 0.7178097E-10 0.1825317E-01 0.0000000E+00 11 Fe++ 0.1639848E-01 0.2943400E-07 0.1639846E-01 0.0000000E+00 12 K+ 0.4883015E-02 0.7427461E-04 0.4808740E-02 0.0000000E+00 13 Na+ 0.2902942E-01 0.9901394E-02 0.1912802E-01 0.0000000E+00 14 Mn++ 0.3987704E-03 0.1013529E-08 0.3987694E-03 0.0000000E+00 15 HPO4-- 0.1360983E-03 0.5430615E-06 0.1355553E-03 0.0000000E+00 Chg. balance for solid moles: -.3188E-16 Mass of aqueous solution: 0.997720E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 22.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1900E-01 -1.721 4.982 0.697 19.85 1.913 andradite 0.2161E-02 -2.665 1.098 0.041 4.374 0.2853 grossular 0.9806E-04 -4.008 0.4417E-01 -1.355 0.1760 0.1229E-01 apatite-OH 0.4519E-04 -4.345 0.2270E-01 -1.644 0.9042E-01 0.7212E-02 clinochlore 0.3651E-02 -2.438 2.029 0.307 8.083 0.7718 daphnite 0.2098E-02 -2.678 1.497 0.175 5.964 0.4537 chlorite-Mn 0.7975E-04 -4.098 0.5654E-01 -1.248 0.2252 0.1802E-01 microcline 0.4728E-02 -2.325 1.316 0.119 5.242 0.5140 stilbite 0.1946E-01 -1.711 13.72 1.137 54.64 6.398 stilpnomelane-Fe 0.1617E-03 -3.791 0.1743 -0.759 0.6942 0.6020E-01 nontronite-Na 0.3890E-03 -3.410 0.1654 -0.781 0.6590 0.5139E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9566E+00 0.9566E+00 1.0000 -0.019 grossular 0.4342E-01 0.4342E-01 1.0000 -1.362 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6263E+00 0.6263E+00 1.0000 -0.203 daphnite 0.3600E+00 0.3600E+00 1.0000 -0.444 chlorite-Mn 0.1368E-01 0.1368E-01 1.0000 -1.864 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 25.102587 g Volume = 10.484387 cm3 Porosity: -2.7921% V(tot) - V(min): -.28479E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 22.9990000 g log = 1.3617 Original solution: 1000.0103000 g Original solution / Rock added: 43.48 (Water/Rock Ratio), log = 1.6383 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1682E-06 1.0073 0.1782E-06 0.1769E-06 CH4,gas 0.8457E-15 1.0129 0.9011E-15 0.8896E-15 H2,gas 0.2570E-05 1.0006 0.2705E-05 0.2703E-05 H2S,gas 0.1771E-13 0.9959 0.1855E-13 0.1863E-13 S2,gas 0.1675E-35 1.0000 0.1762E-35 0.1762E-35 CO,gas 0.1187E-15 1.0000 0.1248E-15 0.1248E-15 SO3,gas 0.1000E-39 1.0000 0.1052E-39 0.1052E-39 SO2,gas 0.1024E-22 1.0000 0.1077E-22 0.1077E-22 HCl,gas 0.5083E-17 1.0000 0.5347E-17 0.5347E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.48529E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.60662E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 209 nontronite-Na 3.58 3.58 0.00 0.000 0.45496E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.916 0.14939E+05 -6.749 3 CH4,gas 4.81 -12.24 -17.05 -4.261 0.29104E+05 -15.045 4 H2,gas 8.29 0.72 -7.57 -4.324 0.12922E+05 -5.568 5 H2S,gas -5.94 -21.67 -15.73 -7.866 0.26861E+05 -13.732 6 S2,gas -7.03 -44.79 -37.75 -5.808 0.64464E+05 -35.754 7 CO,gas 3.51 -14.39 -17.90 -5.509 0.30570E+05 -15.904 8 SO3,gas 17.43 -24.55 -41.98 -10.494 0.71676E+05 -39.978 9 SO2,gas 1.14 -23.83 -24.97 -6.658 0.42632E+05 -22.968 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32906E+05 -17.272 11 acmite 7.74 7.45 -0.29 -0.030 0.48664E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.07 -4.48 -0.224 0.76414E+04 20 analcite 3.37 2.98 -0.39 -0.043 0.66775E+03 21 andalusite 5.06 0.30 -4.76 -0.476 0.81268E+04 26 annite 20.21 17.48 -2.73 -0.152 0.46578E+04 27 phlogopite 27.15 24.26 -2.88 -0.160 0.49249E+04 29 anorthite 12.80 9.13 -3.66 -0.282 0.62560E+04 35 aragonite 0.99 -2.97 -3.96 -1.320 0.67611E+04 36 brucite 12.58 8.90 -3.68 -0.736 0.62811E+04 37 calcite 0.83 -2.97 -3.81 -1.269 0.64998E+04 38 carnegieite-low 9.06 6.29 -2.78 -0.397 0.47418E+04 39 carnegieite-high 10.13 6.29 -3.85 -0.550 0.65686E+04 40 carpholite-Mg 8.65 5.89 -2.76 -0.184 0.47083E+04 41 carpholite-Fe 6.78 3.63 -3.15 -0.210 0.53790E+04 42 celadonite 5.40 3.16 -2.24 -0.132 0.38285E+04 43 celadonite-Fe 3.94 0.90 -3.04 -0.179 0.51889E+04 44 chrysotile 23.94 20.08 -3.86 -0.322 0.65894E+04 50 chloritoid-Mg 13.26 9.20 -4.06 -0.271 0.69330E+04 51 chloritoid-Fe 9.24 6.94 -2.30 -0.153 0.39240E+04 52 chloritoid-Mn 11.46 9.10 -2.36 -0.158 0.40373E+04 54 coesite -2.37 -3.31 -0.94 -0.313 0.16026E+04 59 corundum 8.43 3.61 -4.82 -0.438 0.82346E+04 61 cristobalite -2.55 -3.31 -0.76 -0.253 0.12955E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.81 -1.09 -0.182 0.18624E+04 67 diopside 16.22 14.42 -1.79 -0.179 0.30640E+04 68 hedenbergite 14.24 12.16 -2.08 -0.208 0.35578E+04 75 epidote 24.78 24.24 -0.53 -0.026 0.90892E+03 76 clinozoisite 22.92 19.77 -3.15 -0.143 0.53804E+04 77 epidote-Fe 29.94 28.72 -1.22 -0.063 0.20849E+04 78 fayalite 14.08 9.97 -4.11 -0.587 0.70201E+04 79 ferrosilite 11.19 6.66 -4.53 -0.453 0.77315E+04 83 gibbsite 4.10 1.81 -2.29 -0.327 0.39135E+04 84 glaucophane 23.11 19.42 -3.69 -0.100 0.62989E+04 85 glaucophane-Fe 17.42 12.64 -4.78 -0.129 0.81558E+04 87 greenalite 16.19 13.30 -2.90 -0.241 0.49463E+04 90 hematite 12.60 12.56 -0.04 -0.005 0.70363E+02 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.98 -1.27 -0.127 0.21708E+04 96 julgoldite 70.57 67.10 -3.48 -0.090 0.59364E+04 97 kalsilite 7.62 4.18 -3.44 -0.491 0.58672E+04 98 kaolinite -1.27 -3.01 -1.73 -0.157 0.29573E+04 99 kyanite 4.93 0.30 -4.63 -0.463 0.79036E+04 101 laumontite 2.97 2.52 -0.46 -0.030 0.77969E+03 102 lawsonite 9.68 9.13 -0.54 -0.036 0.92992E+03 103 leucite 4.17 0.88 -3.29 -0.329 0.56202E+04 105 lizardite 23.29 20.08 -3.21 -0.267 0.54796E+04 107 magnetite 20.13 19.19 -0.94 -0.077 0.16027E+04 108 minnesotaite 10.46 6.68 -3.78 -0.222 0.64529E+04 110 magnesioferrite 26.26 21.45 -4.80 -0.392 0.82007E+04 113 margarite 17.45 12.74 -4.71 -0.188 0.80376E+04 120 muscovite 2.68 1.18 -1.50 -0.088 0.25616E+04 121 paragonite 4.34 3.28 -1.05 -0.062 0.18001E+04 122 nepheline 8.38 6.29 -2.09 -0.299 0.35697E+04 134 phlogopite-Na 29.73 26.37 -3.37 -0.187 0.57468E+04 136 prehnite 19.47 17.96 -1.50 -0.088 0.25640E+04 137 prehnite-Fe 22.59 22.44 -0.15 -0.009 0.25485E+03 138 pumpellyite-Fe 46.47 44.37 -2.10 -0.047 0.35824E+04 139 pumpellyite-Mg 49.19 46.63 -2.56 -0.057 0.43733E+04 145 pyroxmangite 7.42 5.49 -1.93 -0.386 0.32921E+04 146 pyrophyllite -6.10 -9.62 -3.52 -0.220 0.60153E+04 147 quartz -2.98 -3.31 -0.33 -0.109 0.55651E+03 152 rhodonite 7.46 5.49 -1.97 -0.395 0.33714E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 24.48 -3.12 -0.093 0.53196E+04 171 talc 16.55 13.46 -3.09 -0.182 0.52778E+04 174 tephroite 18.11 14.28 -3.83 -0.547 0.65380E+04 177 topaz-H 4.67 0.30 -4.36 -0.397 0.74527E+04 178 tridymite -2.61 -3.31 -0.69 -0.231 0.11838E+04 187 wairakite 4.06 2.52 -1.54 -0.091 0.26305E+04 188 walstromite 11.53 8.83 -2.70 -0.539 0.46050E+04 189 wollastonite 10.48 8.83 -1.65 -0.330 0.28189E+04 190 pseudo-wollastonite 11.02 8.83 -2.19 -0.438 0.37375E+04 191 zoisite 22.96 19.77 -3.19 -0.145 0.54529E+04 192 akaganeite 7.77 6.28 -1.49 -0.322 0.25433E+04 193 beidellite-Ca -1.56 -5.93 -4.37 -0.270 0.74633E+04 195 beidellite-K -1.44 -6.06 -4.62 -0.283 0.78918E+04 196 beidellite-Mg -1.71 -6.47 -4.76 -0.294 0.81250E+04 197 beidellite-Na -1.26 -5.36 -4.11 -0.251 0.70106E+04 199 chalcedony -2.79 -3.31 -0.51 -0.171 0.87682E+03 201 montmorillonite-Ca -2.21 -5.28 -3.06 -0.190 0.52307E+04 202 montmorillonite-K -2.16 -5.40 -3.24 -0.199 0.55370E+04 203 montmorillonite-Mg -2.40 -5.81 -3.41 -0.211 0.58234E+04 204 montmorillonite-Na -1.96 -4.71 -2.75 -0.168 0.46939E+04 205 nontronite-Ca 3.28 3.02 -0.26 -0.017 0.45186E+03 206 nontronite-H 2.60 1.01 -1.58 -0.106 0.27040E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11252E+04 224 tobermorite 9.84 6.80 -3.04 -0.828 0.51826E+04 233 boehmite 4.43 1.81 -2.62 -0.437 0.44808E+04 235 ferrous-oxide 9.82 6.64 -3.19 -0.797 0.54408E+04 240 silica-amorphous -2.08 -3.31 -1.23 -0.409 0.20970E+04 242 an20ab80 2.08 1.56 -0.52 -0.040 0.87960E+03 243 an25ab75 2.71 2.04 -0.67 -0.052 0.11474E+04 244 an30ab70 3.34 2.51 -0.83 -0.064 0.14236E+04 245 tr.625ac.25prg.125 45.31 40.84 -4.46 -0.120 0.76214E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 22.9990000 g New total amount of reactant added: 23.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2991E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 23.9990000 Water: Moles liquid = 0.5534E+02 kg liquid = 0.9969E+00 Moles total = 0.5521E+02 kg total = 0.9946E+00 Activity = 1.0000 Stoichiometric ionic strength = .5305851E-02 Osmotic coef. = 0.9615 True ionic strength = .9609139E-02 Chg. balance for total moles = 0.2991E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15246E-09 -9.8168 0.13351E-09 -9.8745 0.87567E+00 -0.0577 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13808E-03 -3.8599 0.12051E-03 -3.9190 0.87279E+00 -0.0591 4 SO4-- 0.25566E-04 -4.5923 0.15757E-04 -4.8025 0.61634E+00 -0.2102 5 HCO3- 0.66115E-05 -5.1797 0.57750E-05 -5.2385 0.87348E+00 -0.0587 6 HS- 0.20668E-11 -11.6847 0.18040E-11 -11.7438 0.87285E+00 -0.0591 7 Al+++ 0.42204E-27 -27.3746 0.14422E-27 -27.8410 0.34172E+00 -0.4663 8 H4SiO4 0.49963E-03 -3.3013 0.49963E-03 -3.3013 0.10000E+01 0.0000 9 Ca++ 0.39944E-07 -7.3985 0.24521E-07 -7.6105 0.61389E+00 -0.2119 10 Mg++ 0.23498E-10 -10.6290 0.14389E-10 -10.8420 0.61236E+00 -0.2130 11 Fe++ 0.12583E-12 -12.9002 0.77098E-13 -13.1130 0.61272E+00 -0.2127 12 K+ 0.74803E-04 -4.1261 0.65348E-04 -4.1848 0.87360E+00 -0.0587 13 Na+ 0.95016E-02 -2.0222 0.82921E-02 -2.0813 0.87271E+00 -0.0591 14 Mn++ 0.18554E-10 -10.7316 0.11374E-10 -10.9441 0.61300E+00 -0.2125 15 HPO4-- 0.53949E-06 -6.2680 0.33253E-06 -6.4782 0.61639E+00 -0.2101 16 HSiO3- 0.41836E-02 -2.3785 0.36513E-02 -2.4375 0.87279E+00 -0.0591 17 Ca(HSiO3)+ 0.22961E-08 -8.6390 0.20061E-08 -8.6977 0.87370E+00 -0.0586 18 Mg(HSiO3)+ 0.16768E-11 -11.7755 0.14650E-11 -11.8342 0.87370E+00 -0.0586 19 NaHSiO3,aq 0.48088E-03 -3.3180 0.48088E-03 -3.3180 0.10000E+01 0.0000 20 AlO+ 0.11956E-14 -14.9224 0.10446E-14 -14.9811 0.87370E+00 -0.0586 22 HAlO2,aq 0.15657E-08 -8.8053 0.15657E-08 -8.8053 0.10000E+01 0.0000 23 AlO2- 0.30032E-04 -4.5224 0.26186E-04 -4.5819 0.87192E+00 -0.0595 24 CH4,aq 0.64983E-18 -18.1872 0.64877E-18 -18.1879 0.99837E+00 -0.0007 29 CO,aq 0.81588E-19 -19.0884 0.81588E-19 -19.0884 0.10000E+01 0.0000 30 CO2,aq 0.15570E-08 -8.8077 0.15545E-08 -8.8084 0.99837E+00 -0.0007 31 CO3-2 0.64966E-05 -5.1873 0.39995E-05 -5.3980 0.61562E+00 -0.2107 32 CaCO3,aq 0.12012E-08 -8.9204 0.12012E-08 -8.9204 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40840E-11 -11.3889 0.35682E-11 -11.4476 0.87370E+00 -0.0586 34 CaCl+ 0.53897E-11 -11.2684 0.47090E-11 -11.3271 0.87370E+00 -0.0586 35 CaCl2,aq 0.13213E-15 -15.8790 0.13213E-15 -15.8790 0.10000E+01 0.0000 36 CaOH+ 0.14824E-07 -7.8290 0.12951E-07 -7.8877 0.87370E+00 -0.0586 37 CaSO4,aq 0.12039E-09 -9.9194 0.12039E-09 -9.9194 0.10000E+01 0.0000 38 HCl,aq 0.30263E-14 -14.5191 0.30263E-14 -14.5191 0.10000E+01 0.0000 43 FeCl+ 0.16563E-16 -16.7809 0.14471E-16 -16.8395 0.87370E+00 -0.0586 46 FeO,aq 0.17105E-09 -9.7669 0.17105E-09 -9.7669 0.10000E+01 0.0000 47 FeOH+ 0.21913E-10 -10.6593 0.19145E-10 -10.7179 0.87370E+00 -0.0586 48 HFeO2- 0.15790E-07 -7.8016 0.13781E-07 -7.8607 0.87279E+00 -0.0591 49 FeO+ 0.11813E-14 -14.9277 0.10321E-14 -14.9863 0.87370E+00 -0.0586 51 FeO2- 0.13039E-07 -7.8847 0.11380E-07 -7.9438 0.87279E+00 -0.0591 52 HFeO2,aq 0.19015E-09 -9.7209 0.19015E-09 -9.7209 0.10000E+01 0.0000 53 H2,aq 0.20412E-08 -8.6901 0.20379E-08 -8.6908 0.99837E+00 -0.0007 54 KCl,aq 0.13944E-09 -9.8556 0.13944E-09 -9.8556 0.10000E+01 0.0000 55 KHSO4,aq 0.36787E-18 -18.4343 0.36787E-18 -18.4343 0.10000E+01 0.0000 56 KOH,aq 0.21339E-06 -6.6708 0.21339E-06 -6.6708 0.10000E+01 0.0000 57 KSO4- 0.18176E-07 -7.7405 0.15864E-07 -7.7996 0.87279E+00 -0.0591 58 MgCO3,aq 0.17613E-12 -12.7542 0.17613E-12 -12.7542 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24438E-14 -14.6119 0.21351E-14 -14.6706 0.87370E+00 -0.0586 60 MgCl+ 0.28712E-14 -14.5419 0.25086E-14 -14.6006 0.87370E+00 -0.0586 61 MgOH+ 0.48191E-10 -10.3170 0.42104E-10 -10.3757 0.87370E+00 -0.0586 63 MnO,aq 0.67362E-09 -9.1716 0.67362E-09 -9.1716 0.10000E+01 0.0000 64 MnOH+ 0.30030E-09 -9.5224 0.26237E-09 -9.5811 0.87370E+00 -0.0586 65 MnO2-2 0.21231E-11 -11.6730 0.13070E-11 -11.8837 0.61562E+00 -0.2107 66 HMnO2- 0.43317E-10 -10.3633 0.37806E-10 -10.4224 0.87279E+00 -0.0591 69 MnCl+ 0.94948E-14 -14.0225 0.82956E-14 -14.0812 0.87370E+00 -0.0586 70 MnSO4,aq 0.50790E-13 -13.2942 0.50790E-13 -13.2942 0.10000E+01 0.0000 71 NaCl,aq 0.32630E-06 -6.4864 0.32630E-06 -6.4864 0.10000E+01 0.0000 72 NaOH,aq 0.27292E-04 -4.5640 0.27292E-04 -4.5640 0.10000E+01 0.0000 74 OH- 0.51529E-02 -2.2879 0.44930E-02 -2.3475 0.87192E+00 -0.0595 79 HPO3-2 0.34768E-17 -17.4588 0.21404E-17 -17.6695 0.61562E+00 -0.2107 82 H3PO4,aq 0.38158E-16 -16.4184 0.38158E-16 -16.4184 0.10000E+01 0.0000 83 H2PO4- 0.89132E-09 -9.0500 0.77833E-09 -9.1088 0.87323E+00 -0.0589 84 PO4-3 0.61973E-08 -8.2078 0.21752E-08 -8.6625 0.35100E+00 -0.4547 87 H2P2O7-2 0.77016E-19 -19.1134 0.47413E-19 -19.3241 0.61562E+00 -0.2107 88 HP2O7-3 0.21301E-15 -15.6716 0.72823E-16 -16.1377 0.34187E+00 -0.4661 89 P2O7-4 0.88178E-15 -15.0546 0.13457E-15 -15.8711 0.15261E+00 -0.8164 90 H2S,aq 0.72482E-15 -15.1398 0.72363E-15 -15.1405 0.99837E+00 -0.0007 97 SO3-2 0.70563E-14 -14.1514 0.43784E-14 -14.3587 0.62049E+00 -0.2073 98 HSO3- 0.39194E-16 -16.4068 0.34208E-16 -16.4659 0.87279E+00 -0.0591 99 HSO4- 0.22329E-11 -11.6511 0.19519E-11 -11.7095 0.87415E+00 -0.0584 Charge balance for all species = 0.2987E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1524617E-09 -.9971609E-02 -.1004339E+02 0.0000 2 H2O 0.1000000E+01 0.5550883E+02 0.9992721E+06 0.0000 3 Cl- 0.1380787E-03 0.1384051E-03 0.4903266E+01 5.9555 4 SO4-- 0.2556583E-04 0.2558527E-04 0.2455953E+01 14.9465 5 HCO3- 0.6611458E-05 0.1311082E-04 0.7993970E+00 4.6360 6 HS- 0.2066786E-11 -.1141299E-08 -.3771726E-04 -1.8693 7 Al+++ 0.4220393E-27 0.3003405E-04 0.8097673E+00 1.7825 8 H4SiO4 0.4996321E-03 0.5164066E-02 0.4959809E+03 -3.3013 9 Ca++ 0.3994443E-07 0.5839508E-07 0.2338636E-02 12.1385 10 Mg++ 0.2349831E-10 0.7354731E-10 0.1786766E-05 8.9070 11 Fe++ 0.1258291E-12 0.2921218E-07 0.1630212E-02 6.6360 12 K+ 0.7480334E-04 0.7503504E-04 0.2931861E+01 5.6897 13 Na+ 0.9501577E-02 0.1001007E-01 0.2299602E+03 7.7932 14 Mn++ 0.1855390E-10 0.1037966E-08 0.5698183E-04 8.8049 15 HPO4-- 0.5394865E-06 0.5465751E-06 0.5242112E-01 13.2708 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3973748E+00 -.9940560E-02 -.3874342E+00 0.0000000E+00 2 H2O 0.5520741E+02 0.5533598E+02 -.1285719E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6905986E-03 0.2550561E-04 0.6650930E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6650941E-03 -.1137745E-08 -.6650930E-03 0.0000000E+00 7 Al+++ 0.7825454E-01 0.2994053E-04 0.7822460E-01 0.0000000E+00 8 H4SiO4 0.2498964E+00 0.5147986E-02 0.2447484E+00 0.0000000E+00 9 Ca++ 0.2761674E-01 0.5821325E-07 0.2761669E-01 0.0000000E+00 10 Mg++ 0.1904683E-01 0.7331830E-10 0.1904683E-01 0.0000000E+00 11 Fe++ 0.1711149E-01 0.2912122E-07 0.1711146E-01 0.0000000E+00 12 K+ 0.5095329E-02 0.7480140E-04 0.5020528E-02 0.0000000E+00 13 Na+ 0.3028466E-01 0.9978904E-02 0.2030576E-01 0.0000000E+00 14 Mn++ 0.4161090E-03 0.1034734E-08 0.4161079E-03 0.0000000E+00 15 HPO4-- 0.1420159E-03 0.5448732E-06 0.1414710E-03 0.0000000E+00 Chg. balance for solid moles: 0.2109E-16 Mass of aqueous solution: 0.997620E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 23.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2019E-01 -1.695 5.294 0.724 20.21 2.032 andradite 0.2308E-02 -2.637 1.173 0.069 4.478 0.3047 grossular 0.1014E-03 -3.994 0.4569E-01 -1.340 0.1744 0.1271E-01 apatite-OH 0.4716E-04 -4.326 0.2369E-01 -1.625 0.9043E-01 0.7527E-02 clinochlore 0.3809E-02 -2.419 2.117 0.326 8.083 0.8054 daphnite 0.2136E-02 -2.670 1.524 0.183 5.819 0.4619 chlorite-Mn 0.8322E-04 -4.080 0.5900E-01 -1.229 0.2252 0.1880E-01 microcline 0.4910E-02 -2.309 1.367 0.136 5.217 0.5338 stilbite 0.2015E-01 -1.696 14.20 1.152 54.22 6.624 stilpnomelane-Fe 0.2220E-03 -3.654 0.2394 -0.621 0.9138 0.8268E-01 nontronite-Na 0.3523E-03 -3.453 0.1498 -0.824 0.5720 0.4655E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9579E+00 0.9579E+00 1.0000 -0.019 grossular 0.4209E-01 0.4209E-01 1.0000 -1.376 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6319E+00 0.6319E+00 1.0000 -0.199 daphnite 0.3543E+00 0.3543E+00 1.0000 -0.451 chlorite-Mn 0.1380E-01 0.1380E-01 1.0000 -1.860 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 26.194432 g Volume = 10.930322 cm3 Porosity: -3.1201% V(tot) - V(min): -.33072E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 23.9990000 g log = 1.3802 Original solution: 1000.0103000 g Original solution / Rock added: 41.67 (Water/Rock Ratio), log = 1.6198 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1679E-06 1.0073 0.1779E-06 0.1766E-06 CH4,gas 0.9629E-15 1.0129 0.1026E-14 0.1013E-14 H2,gas 0.2656E-05 1.0006 0.2795E-05 0.2794E-05 H2S,gas 0.2015E-13 0.9959 0.2111E-13 0.2119E-13 S2,gas 0.2030E-35 1.0000 0.2135E-35 0.2135E-35 CO,gas 0.1225E-15 1.0000 0.1288E-15 0.1288E-15 SO3,gas 0.9981E-40 1.0000 0.1050E-39 0.1050E-39 SO2,gas 0.1055E-22 1.0000 0.1110E-22 0.1110E-22 HCl,gas 0.5080E-17 1.0000 0.5344E-17 0.5344E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.54595E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 209 nontronite-Na 3.58 3.58 0.00 0.000 0.60662E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.917 0.14940E+05 -6.750 3 CH4,gas 4.81 -12.18 -16.99 -4.247 0.29008E+05 -14.989 4 H2,gas 8.29 0.73 -7.55 -4.316 0.12898E+05 -5.554 5 H2S,gas -5.94 -21.62 -15.68 -7.838 0.26766E+05 -13.676 6 S2,gas -7.03 -44.70 -37.67 -5.795 0.64321E+05 -35.671 7 CO,gas 3.51 -14.38 -17.89 -5.505 0.30547E+05 -15.890 8 SO3,gas 17.43 -24.55 -41.98 -10.495 0.71678E+05 -39.979 9 SO2,gas 1.14 -23.82 -24.95 -6.655 0.42609E+05 -22.955 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32907E+05 -17.272 11 acmite 7.74 7.46 -0.28 -0.029 0.47388E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.08 -4.47 -0.224 0.76396E+04 20 analcite 3.37 2.97 -0.40 -0.044 0.67897E+03 21 andalusite 5.06 0.26 -4.80 -0.480 0.81936E+04 26 annite 20.21 17.48 -2.73 -0.152 0.46665E+04 27 phlogopite 27.15 24.29 -2.86 -0.159 0.48787E+04 29 anorthite 12.80 9.10 -3.70 -0.284 0.63122E+04 35 aragonite 0.99 -2.97 -3.96 -1.320 0.67627E+04 36 brucite 12.58 8.91 -3.67 -0.734 0.62657E+04 37 calcite 0.83 -2.97 -3.81 -1.269 0.65013E+04 38 carnegieite-low 9.06 6.27 -2.79 -0.399 0.47642E+04 39 carnegieite-high 10.13 6.27 -3.86 -0.551 0.65911E+04 40 carpholite-Mg 8.65 5.87 -2.78 -0.185 0.47485E+04 41 carpholite-Fe 6.78 3.60 -3.18 -0.212 0.54374E+04 42 celadonite 5.40 3.17 -2.23 -0.131 0.38019E+04 43 celadonite-Fe 3.94 0.90 -3.03 -0.178 0.51805E+04 44 chrysotile 23.94 20.12 -3.82 -0.318 0.65207E+04 50 chloritoid-Mg 13.26 9.17 -4.09 -0.273 0.69844E+04 51 chloritoid-Fe 9.24 6.90 -2.34 -0.156 0.39937E+04 52 chloritoid-Mn 11.46 9.07 -2.39 -0.160 0.40887E+04 54 coesite -2.37 -3.30 -0.93 -0.311 0.15914E+04 59 corundum 8.43 3.57 -4.87 -0.443 0.83126E+04 61 cristobalite -2.55 -3.30 -0.75 -0.251 0.12843E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.78 -1.11 -0.186 0.19014E+04 67 diopside 16.22 14.44 -1.77 -0.177 0.30266E+04 68 hedenbergite 14.24 12.17 -2.07 -0.207 0.35388E+04 75 epidote 24.78 24.21 -0.57 -0.028 0.96936E+03 76 clinozoisite 22.92 19.72 -3.20 -0.145 0.54648E+04 77 epidote-Fe 29.94 28.69 -1.24 -0.065 0.21214E+04 78 fayalite 14.08 9.97 -4.11 -0.587 0.70147E+04 79 ferrosilite 11.19 6.67 -4.52 -0.452 0.77149E+04 83 gibbsite 4.10 1.78 -2.31 -0.331 0.39526E+04 84 glaucophane 23.11 19.46 -3.65 -0.099 0.62303E+04 85 glaucophane-Fe 17.42 12.65 -4.77 -0.129 0.81420E+04 87 greenalite 16.19 13.31 -2.89 -0.241 0.49325E+04 90 hematite 12.60 12.54 -0.06 -0.007 0.10044E+03 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.97 -1.28 -0.128 0.21820E+04 96 julgoldite 70.57 67.10 -3.48 -0.090 0.59370E+04 97 kalsilite 7.62 4.17 -3.45 -0.493 0.58897E+04 98 kaolinite -1.27 -3.04 -1.76 -0.160 0.30129E+04 99 kyanite 4.93 0.26 -4.67 -0.467 0.79704E+04 101 laumontite 2.97 2.50 -0.48 -0.032 0.81336E+03 102 lawsonite 9.68 9.10 -0.58 -0.038 0.98603E+03 103 leucite 4.17 0.87 -3.30 -0.330 0.56314E+04 105 lizardite 23.29 20.12 -3.17 -0.264 0.54110E+04 107 magnetite 20.13 19.17 -0.96 -0.078 0.16357E+04 108 minnesotaite 10.46 6.70 -3.76 -0.221 0.64166E+04 110 magnesioferrite 26.26 21.45 -4.81 -0.393 0.82154E+04 113 margarite 17.45 12.67 -4.79 -0.191 0.81717E+04 120 muscovite 2.68 1.13 -1.55 -0.091 0.26397E+04 121 paragonite 4.34 3.24 -1.10 -0.065 0.18781E+04 122 nepheline 8.38 6.27 -2.10 -0.301 0.35922E+04 134 phlogopite-Na 29.73 26.39 -3.34 -0.185 0.57006E+04 136 prehnite 19.47 17.94 -1.53 -0.090 0.26094E+04 137 prehnite-Fe 22.59 22.42 -0.16 -0.010 0.27627E+03 138 pumpellyite-Fe 46.47 44.29 -2.18 -0.048 0.37151E+04 139 pumpellyite-Mg 49.19 46.57 -2.63 -0.058 0.44877E+04 145 pyroxmangite 7.42 5.50 -1.91 -0.382 0.32655E+04 146 pyrophyllite -6.10 -9.64 -3.54 -0.221 0.60484E+04 147 quartz -2.98 -3.30 -0.32 -0.106 0.54528E+03 152 rhodonite 7.46 5.50 -1.96 -0.392 0.33448E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 24.53 -3.06 -0.091 0.52282E+04 171 talc 16.55 13.52 -3.04 -0.179 0.51867E+04 174 tephroite 18.11 14.31 -3.80 -0.543 0.64960E+04 177 topaz-H 4.67 0.26 -4.40 -0.400 0.75195E+04 178 tridymite -2.61 -3.30 -0.69 -0.229 0.11726E+04 187 wairakite 4.06 2.50 -1.56 -0.092 0.26642E+04 188 walstromite 11.53 8.84 -2.69 -0.538 0.45942E+04 189 wollastonite 10.48 8.84 -1.64 -0.329 0.28081E+04 190 pseudo-wollastonite 11.02 8.84 -2.18 -0.437 0.37268E+04 191 zoisite 22.96 19.72 -3.24 -0.147 0.55374E+04 192 akaganeite 7.77 6.27 -1.50 -0.324 0.25584E+04 193 beidellite-Ca -1.56 -5.96 -4.40 -0.272 0.75131E+04 195 beidellite-K -1.44 -6.09 -4.65 -0.285 0.79398E+04 196 beidellite-Mg -1.71 -6.49 -4.79 -0.296 0.81722E+04 197 beidellite-Na -1.26 -5.39 -4.13 -0.253 0.70585E+04 199 chalcedony -2.79 -3.30 -0.51 -0.169 0.86560E+03 201 montmorillonite-Ca -2.21 -5.29 -3.07 -0.190 0.52460E+04 202 montmorillonite-K -2.16 -5.41 -3.25 -0.199 0.55504E+04 203 montmorillonite-Mg -2.40 -5.82 -3.42 -0.211 0.58361E+04 204 montmorillonite-Na -1.96 -4.72 -2.76 -0.169 0.47073E+04 205 nontronite-Ca 3.28 3.01 -0.27 -0.017 0.45371E+03 206 nontronite-H 2.60 1.01 -1.58 -0.106 0.27058E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11244E+04 224 tobermorite 9.84 6.81 -3.03 -0.826 0.51718E+04 233 boehmite 4.43 1.78 -2.65 -0.441 0.45198E+04 235 ferrous-oxide 9.82 6.64 -3.19 -0.797 0.54437E+04 240 silica-amorphous -2.08 -3.30 -1.22 -0.407 0.20858E+04 242 an20ab80 2.08 1.56 -0.52 -0.040 0.89082E+03 243 an25ab75 2.71 2.03 -0.68 -0.052 0.11614E+04 244 an30ab70 3.34 2.50 -0.84 -0.065 0.14404E+04 245 tr.625ac.25prg.125 45.31 40.92 -4.39 -0.118 0.74972E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 23.9990000 g New total amount of reactant added: 24.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2992E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 24.9990000 Water: Moles liquid = 0.5533E+02 kg liquid = 0.9968E+00 Moles total = 0.5519E+02 kg total = 0.9944E+00 Activity = 1.0000 Stoichiometric ionic strength = .5337913E-02 Osmotic coef. = 0.9614 True ionic strength = .9675737E-02 Chg. balance for total moles = 0.2992E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15246E-09 -9.8168 0.13346E-09 -9.8747 0.87537E+00 -0.0578 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13809E-03 -3.8598 0.12048E-03 -3.9191 0.87247E+00 -0.0592 4 SO4-- 0.25569E-04 -4.5923 0.15737E-04 -4.8031 0.61548E+00 -0.2108 5 HCO3- 0.66076E-05 -5.1800 0.57695E-05 -5.2389 0.87317E+00 -0.0589 6 HS- 0.23413E-11 -11.6306 0.20428E-11 -11.6898 0.87254E+00 -0.0592 7 Al+++ 0.40209E-27 -27.3957 0.13696E-27 -27.8634 0.34063E+00 -0.4677 8 H4SiO4 0.50695E-03 -3.2950 0.50695E-03 -3.2950 0.10000E+01 0.0000 9 Ca++ 0.39945E-07 -7.3985 0.24487E-07 -7.6111 0.61302E+00 -0.2125 10 Mg++ 0.23985E-10 -10.6201 0.14666E-10 -10.8337 0.61148E+00 -0.2136 11 Fe++ 0.12545E-12 -12.9015 0.76756E-13 -13.1149 0.61185E+00 -0.2134 12 K+ 0.75323E-04 -4.1231 0.65779E-04 -4.1819 0.87329E+00 -0.0588 13 Na+ 0.95676E-02 -2.0192 0.83468E-02 -2.0785 0.87240E+00 -0.0593 14 Mn++ 0.18938E-10 -10.7227 0.11592E-10 -10.9358 0.61212E+00 -0.2132 15 HPO4-- 0.54125E-06 -6.2666 0.33315E-06 -6.4774 0.61553E+00 -0.2108 16 HSiO3- 0.42479E-02 -2.3718 0.37061E-02 -2.4311 0.87247E+00 -0.0592 17 Ca(HSiO3)+ 0.23281E-08 -8.6330 0.20333E-08 -8.6918 0.87339E+00 -0.0588 18 Mg(HSiO3)+ 0.17353E-11 -11.7606 0.15156E-11 -11.8194 0.87339E+00 -0.0588 19 NaHSiO3,aq 0.49131E-03 -3.3086 0.49131E-03 -3.3086 0.10000E+01 0.0000 20 AlO+ 0.11366E-14 -14.9444 0.99271E-15 -15.0032 0.87339E+00 -0.0588 22 HAlO2,aq 0.14885E-08 -8.8273 0.14885E-08 -8.8273 0.10000E+01 0.0000 23 AlO2- 0.28573E-04 -4.5441 0.24904E-04 -4.6037 0.87161E+00 -0.0597 24 CH4,aq 0.73613E-18 -18.1330 0.73492E-18 -18.1338 0.99836E+00 -0.0007 29 CO,aq 0.84090E-19 -19.0753 0.84090E-19 -19.0753 0.10000E+01 0.0000 30 CO2,aq 0.15550E-08 -8.8083 0.15525E-08 -8.8090 0.99836E+00 -0.0007 31 CO3-2 0.65019E-05 -5.1870 0.39971E-05 -5.3983 0.61476E+00 -0.2113 32 CaCO3,aq 0.11988E-08 -8.9213 0.11988E-08 -8.9213 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40758E-11 -11.3898 0.35598E-11 -11.4486 0.87339E+00 -0.0588 34 CaCl+ 0.53827E-11 -11.2690 0.47012E-11 -11.3278 0.87339E+00 -0.0588 35 CaCl2,aq 0.13188E-15 -15.8798 0.13188E-15 -15.8798 0.10000E+01 0.0000 36 CaOH+ 0.14813E-07 -7.8293 0.12938E-07 -7.8881 0.87339E+00 -0.0588 37 CaSO4,aq 0.12007E-09 -9.9206 0.12007E-09 -9.9206 0.10000E+01 0.0000 38 HCl,aq 0.30244E-14 -14.5194 0.30244E-14 -14.5194 0.10000E+01 0.0000 43 FeCl+ 0.16491E-16 -16.7827 0.14403E-16 -16.8415 0.87339E+00 -0.0588 46 FeO,aq 0.17041E-09 -9.7685 0.17041E-09 -9.7685 0.10000E+01 0.0000 47 FeOH+ 0.21831E-10 -10.6609 0.19067E-10 -10.7197 0.87339E+00 -0.0588 48 HFeO2- 0.15742E-07 -7.8029 0.13734E-07 -7.8622 0.87247E+00 -0.0592 49 FeO+ 0.11585E-14 -14.9361 0.10118E-14 -14.9949 0.87339E+00 -0.0588 51 FeO2- 0.12797E-07 -7.8929 0.11165E-07 -7.9521 0.87247E+00 -0.0592 52 HFeO2,aq 0.18648E-09 -9.7294 0.18648E-09 -9.7294 0.10000E+01 0.0000 53 H2,aq 0.21065E-08 -8.6764 0.21031E-08 -8.6771 0.99836E+00 -0.0007 54 KCl,aq 0.14033E-09 -9.8529 0.14033E-09 -9.8529 0.10000E+01 0.0000 55 KHSO4,aq 0.36968E-18 -18.4322 0.36968E-18 -18.4322 0.10000E+01 0.0000 56 KOH,aq 0.21487E-06 -6.6678 0.21487E-06 -6.6678 0.10000E+01 0.0000 57 KSO4- 0.18279E-07 -7.7380 0.15948E-07 -7.7973 0.87247E+00 -0.0592 58 MgCO3,aq 0.17941E-12 -12.7462 0.17941E-12 -12.7462 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24893E-14 -14.6039 0.21742E-14 -14.6627 0.87339E+00 -0.0588 60 MgCl+ 0.29267E-14 -14.5336 0.25561E-14 -14.5924 0.87339E+00 -0.0588 61 MgOH+ 0.49152E-10 -10.3085 0.42929E-10 -10.3672 0.87339E+00 -0.0588 63 MnO,aq 0.68706E-09 -9.1630 0.68706E-09 -9.1630 0.10000E+01 0.0000 64 MnOH+ 0.30629E-09 -9.5139 0.26751E-09 -9.5727 0.87339E+00 -0.0588 65 MnO2-2 0.21700E-11 -11.6635 0.13340E-11 -11.8748 0.61476E+00 -0.2113 66 HMnO2- 0.44213E-10 -10.3545 0.38574E-10 -10.4137 0.87247E+00 -0.0592 69 MnCl+ 0.96782E-14 -14.0142 0.84529E-14 -14.0730 0.87339E+00 -0.0588 70 MnSO4,aq 0.51700E-13 -13.2865 0.51700E-13 -13.2865 0.10000E+01 0.0000 71 NaCl,aq 0.32836E-06 -6.4836 0.32836E-06 -6.4836 0.10000E+01 0.0000 72 NaOH,aq 0.27481E-04 -4.5610 0.27481E-04 -4.5610 0.10000E+01 0.0000 74 OH- 0.51566E-02 -2.2876 0.44946E-02 -2.3473 0.87161E+00 -0.0597 79 HPO3-2 0.35998E-17 -17.4437 0.22130E-17 -17.6550 0.61476E+00 -0.2113 82 H3PO4,aq 0.38202E-16 -16.4179 0.38202E-16 -16.4179 0.10000E+01 0.0000 83 H2PO4- 0.89299E-09 -9.0492 0.77951E-09 -9.1082 0.87292E+00 -0.0590 84 PO4-3 0.62299E-08 -8.2055 0.21801E-08 -8.6615 0.34993E+00 -0.4560 87 H2P2O7-2 0.77358E-19 -19.1115 0.47556E-19 -19.3228 0.61476E+00 -0.2113 88 HP2O7-3 0.21442E-15 -15.6687 0.73069E-16 -16.1363 0.34078E+00 -0.4675 89 P2O7-4 0.89002E-15 -15.0506 0.13507E-15 -15.8694 0.15176E+00 -0.8188 90 H2S,aq 0.82050E-15 -15.0859 0.81915E-15 -15.0866 0.99836E+00 -0.0007 97 SO3-2 0.72826E-14 -14.1377 0.45126E-14 -14.3456 0.61964E+00 -0.2079 98 HSO3- 0.40396E-16 -16.3937 0.35244E-16 -16.4529 0.87247E+00 -0.0592 99 HSO4- 0.22300E-11 -11.6517 0.19487E-11 -11.7103 0.87385E+00 -0.0586 Charge balance for all species = 0.2987E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1524593E-09 -.1004442E-01 -.1011664E+02 0.0000 2 H2O 0.1000000E+01 0.5550875E+02 0.9992626E+06 0.0000 3 Cl- 0.1380917E-03 0.1384202E-03 0.4903758E+01 5.9556 4 SO4-- 0.2556851E-04 0.2558800E-04 0.2456195E+01 14.9462 5 HCO3- 0.6607573E-05 0.1311225E-04 0.7994771E+00 4.6358 6 HS- 0.2341257E-11 -.1093918E-08 -.3615112E-04 -1.8151 7 Al+++ 0.4020861E-27 0.2857399E-04 0.7703954E+00 1.7606 8 H4SiO4 0.5069512E-03 0.5246134E-02 0.5038590E+03 -3.2950 9 Ca++ 0.3994518E-07 0.5841483E-07 0.2339407E-02 12.1382 10 Mg++ 0.2398463E-10 0.7505706E-10 0.1823429E-05 8.9156 11 Fe++ 0.1254500E-12 0.2891756E-07 0.1613757E-02 6.6344 12 K+ 0.7532303E-04 0.7555632E-04 0.2952204E+01 5.6927 13 Na+ 0.9567646E-02 0.1008677E-01 0.2317202E+03 7.7962 14 Mn++ 0.1893778E-10 0.1058728E-08 0.5812113E-04 8.8135 15 HPO4-- 0.5412483E-06 0.5483712E-06 0.5259294E-01 13.2720 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4139333E+00 -.1001206E-01 -.4039212E+00 0.0000000E+00 2 H2O 0.5519488E+02 0.5532991E+02 -.1350299E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7183120E-03 0.2550556E-04 0.6928064E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6928075E-03 -.1090393E-08 -.6928064E-03 0.0000000E+00 7 Al+++ 0.8151528E-01 0.2848193E-04 0.8148680E-01 0.0000000E+00 8 H4SiO4 0.2603092E+00 0.5229231E-02 0.2550799E+00 0.0000000E+00 9 Ca++ 0.2876689E-01 0.5822663E-07 0.2876683E-01 0.0000000E+00 10 Mg++ 0.1984048E-01 0.7481523E-10 0.1984048E-01 0.0000000E+00 11 Fe++ 0.1782450E-01 0.2882439E-07 0.1782447E-01 0.0000000E+00 12 K+ 0.5307643E-02 0.7531288E-04 0.5232330E-02 0.0000000E+00 13 Na+ 0.3153991E-01 0.1005427E-01 0.2148564E-01 0.0000000E+00 14 Mn++ 0.4334476E-03 0.1055317E-08 0.4334465E-03 0.0000000E+00 15 HPO4-- 0.1479335E-03 0.5466043E-06 0.1473869E-03 0.0000000E+00 Chg. balance for solid moles: 0.4841E-16 Mass of aqueous solution: 0.997520E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 24.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2138E-01 -1.670 5.607 0.749 20.55 2.152 andradite 0.2456E-02 -2.610 1.248 0.096 4.574 0.3243 grossular 0.1046E-03 -3.980 0.4713E-01 -1.327 0.1727 0.1311E-01 apatite-OH 0.4913E-04 -4.309 0.2468E-01 -1.608 0.9044E-01 0.7842E-02 clinochlore 0.3968E-02 -2.401 2.206 0.344 8.083 0.8389 daphnite 0.2173E-02 -2.663 1.551 0.191 5.683 0.4699 chlorite-Mn 0.8669E-04 -4.062 0.6146E-01 -1.211 0.2252 0.1959E-01 microcline 0.5091E-02 -2.293 1.417 0.151 5.193 0.5535 stilbite 0.2084E-01 -1.681 14.69 1.167 53.82 6.850 stilpnomelane-Fe 0.2830E-03 -3.548 0.3050 -0.516 1.118 0.1054 nontronite-Na 0.3152E-03 -3.501 0.1341 -0.873 0.4913 0.4165E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9591E+00 0.9591E+00 1.0000 -0.018 grossular 0.4086E-01 0.4086E-01 1.0000 -1.389 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6371E+00 0.6371E+00 1.0000 -0.196 daphnite 0.3490E+00 0.3490E+00 1.0000 -0.457 chlorite-Mn 0.1392E-01 0.1392E-01 1.0000 -1.856 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 27.286373 g Volume = 11.376246 cm3 Porosity: -3.4242% V(tot) - V(min): -.37665E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 24.9990000 g log = 1.3979 Original solution: 1000.0103000 g Original solution / Rock added: 40.00 (Water/Rock Ratio), log = 1.6021 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1677E-06 1.0073 0.1777E-06 0.1764E-06 CH4,gas 0.1091E-14 1.0129 0.1162E-14 0.1147E-14 H2,gas 0.2741E-05 1.0006 0.2885E-05 0.2883E-05 H2S,gas 0.2280E-13 0.9959 0.2389E-13 0.2399E-13 S2,gas 0.2443E-35 1.0000 0.2569E-35 0.2569E-35 CO,gas 0.1262E-15 1.0000 0.1328E-15 0.1328E-15 SO3,gas 0.9961E-40 1.0000 0.1048E-39 0.1048E-39 SO2,gas 0.1087E-22 1.0000 0.1143E-22 0.1143E-22 HCl,gas 0.5077E-17 1.0000 0.5340E-17 0.5340E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.48529E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.917 0.14941E+05 -6.750 3 CH4,gas 4.81 -12.13 -16.93 -4.234 0.28916E+05 -14.935 4 H2,gas 8.29 0.75 -7.54 -4.309 0.12874E+05 -5.540 5 H2S,gas -5.94 -21.56 -15.62 -7.811 0.26674E+05 -13.622 6 S2,gas -7.03 -44.62 -37.59 -5.783 0.64184E+05 -35.590 7 CO,gas 3.51 -14.37 -17.88 -5.501 0.30524E+05 -15.877 8 SO3,gas 17.43 -24.55 -41.98 -10.495 0.71679E+05 -39.980 9 SO2,gas 1.14 -23.81 -24.94 -6.651 0.42587E+05 -22.942 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32907E+05 -17.272 11 acmite 7.74 7.47 -0.27 -0.028 0.46162E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.08 -4.47 -0.224 0.76383E+04 20 analcite 3.37 2.97 -0.40 -0.045 0.68976E+03 21 andalusite 5.06 0.23 -4.84 -0.484 0.82578E+04 26 annite 20.21 17.47 -2.74 -0.152 0.46748E+04 27 phlogopite 27.15 24.32 -2.83 -0.157 0.48347E+04 29 anorthite 12.80 9.07 -3.73 -0.287 0.63661E+04 35 aragonite 0.99 -2.98 -3.96 -1.320 0.67641E+04 36 brucite 12.58 8.92 -3.66 -0.732 0.62510E+04 37 calcite 0.83 -2.98 -3.81 -1.269 0.65028E+04 38 carnegieite-low 9.06 6.26 -2.80 -0.400 0.47858E+04 39 carnegieite-high 10.13 6.26 -3.87 -0.553 0.66126E+04 40 carpholite-Mg 8.65 5.85 -2.80 -0.187 0.47872E+04 41 carpholite-Fe 6.78 3.57 -3.22 -0.214 0.54936E+04 42 celadonite 5.40 3.19 -2.21 -0.130 0.37764E+04 43 celadonite-Fe 3.94 0.91 -3.03 -0.178 0.51725E+04 44 chrysotile 23.94 20.16 -3.78 -0.315 0.64552E+04 50 chloritoid-Mg 13.26 9.14 -4.12 -0.275 0.70340E+04 51 chloritoid-Fe 9.24 6.86 -2.38 -0.159 0.40606E+04 52 chloritoid-Mn 11.46 9.04 -2.42 -0.162 0.41383E+04 54 coesite -2.37 -3.30 -0.93 -0.309 0.15806E+04 59 corundum 8.43 3.52 -4.91 -0.447 0.83876E+04 61 cristobalite -2.55 -3.30 -0.75 -0.249 0.12735E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.76 -1.14 -0.189 0.19389E+04 67 diopside 16.22 14.46 -1.75 -0.175 0.29909E+04 68 hedenbergite 14.24 12.18 -2.06 -0.206 0.35205E+04 75 epidote 24.78 24.17 -0.60 -0.029 0.10275E+04 76 clinozoisite 22.92 19.67 -3.25 -0.148 0.55460E+04 77 epidote-Fe 29.94 28.67 -1.26 -0.066 0.21565E+04 78 fayalite 14.08 9.97 -4.11 -0.586 0.70094E+04 79 ferrosilite 11.19 6.68 -4.51 -0.451 0.76988E+04 83 gibbsite 4.10 1.76 -2.34 -0.334 0.39901E+04 84 glaucophane 23.11 19.50 -3.61 -0.098 0.61647E+04 85 glaucophane-Fe 17.42 12.66 -4.76 -0.129 0.81288E+04 87 greenalite 16.19 13.31 -2.88 -0.240 0.49192E+04 90 hematite 12.60 12.52 -0.08 -0.009 0.12934E+03 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.97 -1.28 -0.128 0.21928E+04 96 julgoldite 70.57 67.10 -3.48 -0.090 0.59377E+04 97 kalsilite 7.62 4.16 -3.46 -0.495 0.59112E+04 98 kaolinite -1.27 -3.07 -1.80 -0.163 0.30663E+04 99 kyanite 4.93 0.23 -4.71 -0.471 0.80346E+04 101 laumontite 2.97 2.48 -0.50 -0.033 0.84571E+03 102 lawsonite 9.68 9.07 -0.61 -0.041 0.10400E+04 103 leucite 4.17 0.86 -3.30 -0.330 0.56422E+04 105 lizardite 23.29 20.16 -3.13 -0.261 0.53454E+04 107 magnetite 20.13 19.16 -0.98 -0.080 0.16673E+04 108 minnesotaite 10.46 6.72 -3.74 -0.220 0.63818E+04 110 magnesioferrite 26.26 21.44 -4.82 -0.393 0.82296E+04 113 margarite 17.45 12.59 -4.86 -0.194 0.83006E+04 120 muscovite 2.68 1.09 -1.59 -0.094 0.27146E+04 121 paragonite 4.34 3.19 -1.14 -0.067 0.19531E+04 122 nepheline 8.38 6.26 -2.12 -0.302 0.36137E+04 134 phlogopite-Na 29.73 26.42 -3.31 -0.184 0.56566E+04 136 prehnite 19.47 17.91 -1.55 -0.091 0.26531E+04 137 prehnite-Fe 22.59 22.41 -0.17 -0.010 0.29688E+03 138 pumpellyite-Fe 46.47 44.22 -2.25 -0.050 0.38427E+04 139 pumpellyite-Mg 49.19 46.50 -2.69 -0.060 0.45979E+04 145 pyroxmangite 7.42 5.52 -1.90 -0.380 0.32401E+04 146 pyrophyllite -6.10 -9.66 -3.56 -0.223 0.60803E+04 147 quartz -2.98 -3.30 -0.31 -0.104 0.53450E+03 152 rhodonite 7.46 5.52 -1.94 -0.389 0.33193E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 24.59 -3.01 -0.090 0.51410E+04 171 talc 16.55 13.57 -2.99 -0.176 0.50996E+04 174 tephroite 18.11 14.33 -3.78 -0.540 0.64559E+04 177 topaz-H 4.67 0.23 -4.44 -0.404 0.75837E+04 178 tridymite -2.61 -3.30 -0.68 -0.227 0.11618E+04 187 wairakite 4.06 2.48 -1.58 -0.093 0.26965E+04 188 walstromite 11.53 8.84 -2.68 -0.537 0.45840E+04 189 wollastonite 10.48 8.84 -1.64 -0.328 0.27979E+04 190 pseudo-wollastonite 11.02 8.84 -2.18 -0.435 0.37165E+04 191 zoisite 22.96 19.67 -3.29 -0.150 0.56185E+04 192 akaganeite 7.77 6.26 -1.51 -0.326 0.25728E+04 193 beidellite-Ca -1.56 -5.99 -4.43 -0.274 0.75610E+04 195 beidellite-K -1.44 -6.11 -4.68 -0.286 0.79859E+04 196 beidellite-Mg -1.71 -6.52 -4.81 -0.298 0.82175E+04 197 beidellite-Na -1.26 -5.42 -4.16 -0.255 0.71046E+04 199 chalcedony -2.79 -3.30 -0.50 -0.167 0.85481E+03 201 montmorillonite-Ca -2.21 -5.30 -3.08 -0.191 0.52607E+04 202 montmorillonite-K -2.16 -5.42 -3.26 -0.200 0.55634E+04 203 montmorillonite-Mg -2.40 -5.83 -3.43 -0.212 0.58483E+04 204 montmorillonite-Na -1.96 -4.73 -2.76 -0.169 0.47203E+04 205 nontronite-Ca 3.28 3.01 -0.27 -0.017 0.45549E+03 206 nontronite-H 2.60 1.01 -1.59 -0.106 0.27075E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11237E+04 224 tobermorite 9.84 6.82 -3.02 -0.825 0.51615E+04 233 boehmite 4.43 1.76 -2.67 -0.445 0.45573E+04 235 ferrous-oxide 9.82 6.63 -3.19 -0.797 0.54465E+04 240 silica-amorphous -2.08 -3.30 -1.22 -0.405 0.20750E+04 242 an20ab80 2.08 1.55 -0.53 -0.041 0.90160E+03 243 an25ab75 2.71 2.02 -0.69 -0.053 0.11749E+04 244 an30ab70 3.34 2.49 -0.85 -0.066 0.14566E+04 245 tr.625ac.25prg.125 45.31 40.99 -4.32 -0.116 0.73784E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 24.9990000 g New total amount of reactant added: 25.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2992E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 25.9990000 Water: Moles liquid = 0.5532E+02 kg liquid = 0.9967E+00 Moles total = 0.5518E+02 kg total = 0.9941E+00 Activity = 1.0000 Stoichiometric ionic strength = .5369511E-02 Osmotic coef. = 0.9613 True ionic strength = .9740507E-02 Chg. balance for total moles = 0.2992E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15246E-09 -9.8168 0.13342E-09 -9.8748 0.87508E+00 -0.0580 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13810E-03 -3.8598 0.12045E-03 -3.9192 0.87217E+00 -0.0594 4 SO4-- 0.25571E-04 -4.5922 0.15717E-04 -4.8036 0.61465E+00 -0.2114 5 HCO3- 0.66040E-05 -5.1802 0.57644E-05 -5.2392 0.87287E+00 -0.0591 6 HS- 0.26397E-11 -11.5784 0.23025E-11 -11.6378 0.87224E+00 -0.0594 7 Al+++ 0.38383E-27 -27.4159 0.13034E-27 -27.8849 0.33958E+00 -0.4691 8 H4SiO4 0.51409E-03 -3.2890 0.51409E-03 -3.2890 0.10000E+01 0.0000 9 Ca++ 0.39948E-07 -7.3985 0.24455E-07 -7.6116 0.61217E+00 -0.2131 10 Mg++ 0.24459E-10 -10.6116 0.14936E-10 -10.8258 0.61063E+00 -0.2142 11 Fe++ 0.12510E-12 -12.9028 0.76433E-13 -13.1167 0.61100E+00 -0.2140 12 K+ 0.75828E-04 -4.1202 0.66197E-04 -4.1792 0.87299E+00 -0.0590 13 Na+ 0.96319E-02 -2.0163 0.83999E-02 -2.0757 0.87209E+00 -0.0594 14 Mn++ 0.19313E-10 -10.7142 0.11805E-10 -10.9279 0.61128E+00 -0.2138 15 HPO4-- 0.54294E-06 -6.2653 0.33374E-06 -6.4766 0.61469E+00 -0.2113 16 HSiO3- 0.43105E-02 -2.3655 0.37595E-02 -2.4249 0.87217E+00 -0.0594 17 Ca(HSiO3)+ 0.23594E-08 -8.6272 0.20599E-08 -8.6861 0.87309E+00 -0.0589 18 Mg(HSiO3)+ 0.17933E-11 -11.7464 0.15657E-11 -11.8053 0.87309E+00 -0.0589 19 NaHSiO3,aq 0.50156E-03 -3.2997 0.50156E-03 -3.2997 0.10000E+01 0.0000 20 AlO+ 0.10827E-14 -14.9655 0.94530E-15 -15.0244 0.87309E+00 -0.0589 22 HAlO2,aq 0.14178E-08 -8.8484 0.14178E-08 -8.8484 0.10000E+01 0.0000 23 AlO2- 0.27234E-04 -4.5649 0.23729E-04 -4.6247 0.87130E+00 -0.0598 24 CH4,aq 0.82999E-18 -18.0809 0.82862E-18 -18.0816 0.99835E+00 -0.0007 29 CO,aq 0.86573E-19 -19.0626 0.86573E-19 -19.0626 0.10000E+01 0.0000 30 CO2,aq 0.15532E-08 -8.8088 0.15506E-08 -8.8095 0.99835E+00 -0.0007 31 CO3-2 0.65070E-05 -5.1866 0.39948E-05 -5.3985 0.61392E+00 -0.2119 32 CaCO3,aq 0.11965E-08 -8.9221 0.11965E-08 -8.9221 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40683E-11 -11.3906 0.35520E-11 -11.4495 0.87309E+00 -0.0589 34 CaCl+ 0.53761E-11 -11.2695 0.46939E-11 -11.3285 0.87309E+00 -0.0589 35 CaCl2,aq 0.13164E-15 -15.8806 0.13164E-15 -15.8806 0.10000E+01 0.0000 36 CaOH+ 0.14804E-07 -7.8296 0.12925E-07 -7.8886 0.87309E+00 -0.0589 37 CaSO4,aq 0.11976E-09 -9.9217 0.11976E-09 -9.9217 0.10000E+01 0.0000 38 HCl,aq 0.30228E-14 -14.5196 0.30228E-14 -14.5196 0.10000E+01 0.0000 43 FeCl+ 0.16423E-16 -16.7845 0.14339E-16 -16.8435 0.87309E+00 -0.0589 46 FeO,aq 0.16980E-09 -9.7701 0.16980E-09 -9.7701 0.10000E+01 0.0000 47 FeOH+ 0.21753E-10 -10.6625 0.18993E-10 -10.7214 0.87309E+00 -0.0589 48 HFeO2- 0.15696E-07 -7.8042 0.13689E-07 -7.8636 0.87217E+00 -0.0594 49 FeO+ 0.11370E-14 -14.9442 0.99268E-15 -15.0032 0.87309E+00 -0.0589 51 FeO2- 0.12567E-07 -7.9008 0.10961E-07 -7.9602 0.87217E+00 -0.0594 52 HFeO2,aq 0.18301E-09 -9.7375 0.18301E-09 -9.7375 0.10000E+01 0.0000 53 H2,aq 0.21714E-08 -8.6633 0.21678E-08 -8.6640 0.99835E+00 -0.0007 54 KCl,aq 0.14118E-09 -9.8502 0.14118E-09 -9.8502 0.10000E+01 0.0000 55 KHSO4,aq 0.37146E-18 -18.4301 0.37146E-18 -18.4301 0.10000E+01 0.0000 56 KOH,aq 0.21630E-06 -6.6649 0.21630E-06 -6.6649 0.10000E+01 0.0000 57 KSO4- 0.18379E-07 -7.7357 0.16029E-07 -7.7951 0.87217E+00 -0.0594 58 MgCO3,aq 0.18260E-12 -12.7385 0.18260E-12 -12.7385 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.25337E-14 -14.5962 0.22121E-14 -14.6552 0.87309E+00 -0.0589 60 MgCl+ 0.29807E-14 -14.5257 0.26025E-14 -14.5846 0.87309E+00 -0.0589 61 MgOH+ 0.50088E-10 -10.3003 0.43732E-10 -10.3592 0.87309E+00 -0.0589 63 MnO,aq 0.70012E-09 -9.1548 0.70012E-09 -9.1548 0.10000E+01 0.0000 64 MnOH+ 0.31212E-09 -9.5057 0.27251E-09 -9.5646 0.87309E+00 -0.0589 65 MnO2-2 0.22156E-11 -11.6545 0.13602E-11 -11.8664 0.61392E+00 -0.2119 66 HMnO2- 0.45082E-10 -10.3460 0.39320E-10 -10.4054 0.87217E+00 -0.0594 69 MnCl+ 0.98570E-14 -14.0063 0.86061E-14 -14.0652 0.87309E+00 -0.0589 70 MnSO4,aq 0.52584E-13 -13.2791 0.52584E-13 -13.2791 0.10000E+01 0.0000 71 NaCl,aq 0.33037E-06 -6.4810 0.33037E-06 -6.4810 0.10000E+01 0.0000 72 NaOH,aq 0.27665E-04 -4.5581 0.27665E-04 -4.5581 0.10000E+01 0.0000 74 OH- 0.51600E-02 -2.2873 0.44959E-02 -2.3472 0.87130E+00 -0.0598 79 HPO3-2 0.37222E-17 -17.4292 0.22851E-17 -17.6411 0.61392E+00 -0.2119 82 H3PO4,aq 0.38246E-16 -16.4174 0.38246E-16 -16.4174 0.10000E+01 0.0000 83 H2PO4- 0.89459E-09 -9.0484 0.78064E-09 -9.1075 0.87262E+00 -0.0592 84 PO4-3 0.62611E-08 -8.2033 0.21846E-08 -8.6606 0.34891E+00 -0.4573 87 H2P2O7-2 0.77689E-19 -19.1096 0.47695E-19 -19.3215 0.61392E+00 -0.2119 88 HP2O7-3 0.21577E-15 -15.6660 0.73304E-16 -16.1349 0.33973E+00 -0.4689 89 P2O7-4 0.89800E-15 -15.0467 0.13554E-15 -15.8679 0.15094E+00 -0.8212 90 H2S,aq 0.92450E-15 -15.0341 0.92297E-15 -15.0348 0.99835E+00 -0.0007 97 SO3-2 0.75071E-14 -14.1245 0.46456E-14 -14.3330 0.61883E+00 -0.2084 98 HSO3- 0.41588E-16 -16.3810 0.36272E-16 -16.4404 0.87217E+00 -0.0594 99 HSO4- 0.22273E-11 -11.6522 0.19457E-11 -11.7109 0.87355E+00 -0.0587 Charge balance for all species = 0.2989E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1524627E-09 -.1011557E-01 -.1018822E+02 0.0000 2 H2O 0.1000000E+01 0.5550868E+02 0.9992533E+06 0.0000 3 Cl- 0.1381046E-03 0.1384352E-03 0.4904250E+01 5.9556 4 SO4-- 0.2557118E-04 0.2559073E-04 0.2456437E+01 14.9460 5 HCO3- 0.6603955E-05 0.1311367E-04 0.7995574E+00 4.6355 6 HS- 0.2639721E-11 -.1048291E-08 -.3464302E-04 -1.7630 7 Al+++ 0.3838311E-27 0.2723558E-04 0.7343040E+00 1.7394 8 H4SiO4 0.5140950E-03 0.5326199E-02 0.5115447E+03 -3.2890 9 Ca++ 0.3994814E-07 0.5843678E-07 0.2340267E-02 12.1379 10 Mg++ 0.2445948E-10 0.7652904E-10 0.1859174E-05 8.9238 11 Fe++ 0.1250959E-12 0.2863754E-07 0.1598118E-02 6.6329 12 K+ 0.7582844E-04 0.7606326E-04 0.2971988E+01 5.6956 13 Na+ 0.9631901E-02 0.1016146E-01 0.2334341E+03 7.7991 14 Mn++ 0.1931260E-10 0.1078909E-08 0.5922849E-04 8.8217 15 HPO4-- 0.5429368E-06 0.5500925E-06 0.5275761E-01 13.2730 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4304918E+00 -.1008189E-01 -.4204099E+00 0.0000000E+00 2 H2O 0.5518234E+02 0.5532384E+02 -.1414959E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7460254E-03 0.2550551E-04 0.7205199E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7205209E-03 -.1044801E-08 -.7205199E-03 0.0000000E+00 7 Al+++ 0.8477602E-01 0.2714489E-04 0.8474888E-01 0.0000000E+00 8 H4SiO4 0.2707219E+00 0.5308463E-02 0.2654135E+00 0.0000000E+00 9 Ca++ 0.2991703E-01 0.5824218E-07 0.2991697E-01 0.0000000E+00 10 Mg++ 0.2063413E-01 0.7627420E-10 0.2063413E-01 0.0000000E+00 11 Fe++ 0.1853751E-01 0.2854218E-07 0.1853748E-01 0.0000000E+00 12 K+ 0.5519958E-02 0.7580997E-04 0.5444148E-02 0.0000000E+00 13 Na+ 0.3279515E-01 0.1012762E-01 0.2266753E-01 0.0000000E+00 14 Mn++ 0.4507862E-03 0.1075316E-08 0.4507851E-03 0.0000000E+00 15 HPO4-- 0.1538511E-03 0.5482607E-06 0.1533028E-03 0.0000000E+00 Chg. balance for solid moles: 0.5269E-16 Mass of aqueous solution: 0.997420E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 25.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2258E-01 -1.646 5.920 0.772 20.86 2.272 andradite 0.2604E-02 -2.584 1.323 0.122 4.664 0.3439 grossular 0.1077E-03 -3.968 0.4850E-01 -1.314 0.1709 0.1350E-01 apatite-OH 0.5110E-04 -4.292 0.2567E-01 -1.591 0.9045E-01 0.8157E-02 clinochlore 0.4127E-02 -2.384 2.294 0.361 8.083 0.8725 daphnite 0.2210E-02 -2.656 1.577 0.198 5.557 0.4779 chlorite-Mn 0.9016E-04 -4.045 0.6392E-01 -1.194 0.2252 0.2037E-01 microcline 0.5272E-02 -2.278 1.467 0.167 5.171 0.5732 stilbite 0.2153E-01 -1.667 15.17 1.181 53.45 7.075 stilpnomelane-Fe 0.3444E-03 -3.463 0.3713 -0.430 1.308 0.1282 nontronite-Na 0.2777E-03 -3.556 0.1181 -0.928 0.4162 0.3669E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9603E+00 0.9603E+00 1.0000 -0.018 grossular 0.3970E-01 0.3970E-01 1.0000 -1.401 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6421E+00 0.6421E+00 1.0000 -0.192 daphnite 0.3439E+00 0.3439E+00 1.0000 -0.464 chlorite-Mn 0.1403E-01 0.1403E-01 1.0000 -1.853 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 28.378405 g Volume = 11.822160 cm3 Porosity: -3.7068% V(tot) - V(min): -.42256E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 25.9990000 g log = 1.4150 Original solution: 1000.0103000 g Original solution / Rock added: 38.46 (Water/Rock Ratio), log = 1.5850 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1675E-06 1.0073 0.1775E-06 0.1762E-06 CH4,gas 0.1230E-14 1.0129 0.1310E-14 0.1294E-14 H2,gas 0.2825E-05 1.0006 0.2973E-05 0.2972E-05 H2S,gas 0.2569E-13 0.9959 0.2692E-13 0.2703E-13 S2,gas 0.2919E-35 1.0000 0.3070E-35 0.3070E-35 CO,gas 0.1300E-15 1.0000 0.1367E-15 0.1367E-15 SO3,gas 0.9943E-40 1.0000 0.1046E-39 0.1046E-39 SO2,gas 0.1118E-22 1.0000 0.1176E-22 0.1176E-22 HCl,gas 0.5074E-17 1.0000 0.5337E-17 0.5337E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 209 nontronite-Na 3.58 3.58 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.917 0.14942E+05 -6.751 3 CH4,gas 4.81 -12.07 -16.88 -4.221 0.28827E+05 -14.883 4 H2,gas 8.29 0.76 -7.53 -4.301 0.12852E+05 -5.527 5 H2S,gas -5.94 -21.51 -15.57 -7.785 0.26585E+05 -13.570 6 S2,gas -7.03 -44.55 -37.51 -5.771 0.64052E+05 -35.513 7 CO,gas 3.51 -14.35 -17.86 -5.497 0.30503E+05 -15.864 8 SO3,gas 17.43 -24.55 -41.98 -10.495 0.71681E+05 -39.980 9 SO2,gas 1.14 -23.79 -24.93 -6.648 0.42566E+05 -22.929 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32908E+05 -17.273 11 acmite 7.74 7.47 -0.26 -0.027 0.44984E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.08 -4.47 -0.224 0.76374E+04 20 analcite 3.37 2.96 -0.41 -0.046 0.70014E+03 21 andalusite 5.06 0.19 -4.87 -0.487 0.83196E+04 26 annite 20.21 17.47 -2.74 -0.152 0.46828E+04 27 phlogopite 27.15 24.34 -2.81 -0.156 0.47928E+04 29 anorthite 12.80 9.04 -3.76 -0.289 0.64180E+04 35 aragonite 0.99 -2.98 -3.96 -1.321 0.67655E+04 36 brucite 12.58 8.92 -3.65 -0.731 0.62371E+04 37 calcite 0.83 -2.98 -3.81 -1.270 0.65042E+04 38 carnegieite-low 9.06 6.25 -2.82 -0.402 0.48065E+04 39 carnegieite-high 10.13 6.25 -3.88 -0.555 0.66334E+04 40 carpholite-Mg 8.65 5.82 -2.83 -0.188 0.48246E+04 41 carpholite-Fe 6.78 3.53 -3.25 -0.217 0.55477E+04 42 celadonite 5.40 3.20 -2.20 -0.129 0.37521E+04 43 celadonite-Fe 3.94 0.91 -3.02 -0.178 0.51648E+04 44 chrysotile 23.94 20.19 -3.74 -0.312 0.63925E+04 50 chloritoid-Mg 13.26 9.11 -4.15 -0.277 0.70817E+04 51 chloritoid-Fe 9.24 6.82 -2.42 -0.161 0.41250E+04 52 chloritoid-Mn 11.46 9.01 -2.45 -0.163 0.41861E+04 54 coesite -2.37 -3.29 -0.92 -0.307 0.15702E+04 59 corundum 8.43 3.48 -4.95 -0.450 0.84597E+04 61 cristobalite -2.55 -3.29 -0.74 -0.247 0.12631E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.74 -1.16 -0.193 0.19749E+04 67 diopside 16.22 14.48 -1.73 -0.173 0.29567E+04 68 hedenbergite 14.24 12.19 -2.05 -0.205 0.35029E+04 75 epidote 24.78 24.14 -0.63 -0.031 0.10834E+04 76 clinozoisite 22.92 19.63 -3.29 -0.150 0.56240E+04 77 epidote-Fe 29.94 28.65 -1.28 -0.067 0.21902E+04 78 fayalite 14.08 9.98 -4.10 -0.586 0.70044E+04 79 ferrosilite 11.19 6.69 -4.50 -0.450 0.76834E+04 83 gibbsite 4.10 1.74 -2.36 -0.337 0.40261E+04 84 glaucophane 23.11 19.54 -3.57 -0.097 0.61021E+04 85 glaucophane-Fe 17.42 12.66 -4.75 -0.128 0.81160E+04 87 greenalite 16.19 13.32 -2.87 -0.239 0.49065E+04 90 hematite 12.60 12.51 -0.09 -0.011 0.15715E+03 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.96 -1.29 -0.129 0.22032E+04 96 julgoldite 70.57 67.09 -3.48 -0.090 0.59385E+04 97 kalsilite 7.62 4.15 -3.47 -0.496 0.59320E+04 98 kaolinite -1.27 -3.10 -1.83 -0.166 0.31176E+04 99 kyanite 4.93 0.19 -4.74 -0.474 0.80963E+04 101 laumontite 2.97 2.46 -0.51 -0.034 0.87684E+03 102 lawsonite 9.68 9.04 -0.64 -0.043 0.10918E+04 103 leucite 4.17 0.86 -3.31 -0.331 0.56525E+04 105 lizardite 23.29 20.19 -3.09 -0.258 0.52828E+04 107 magnetite 20.13 19.14 -0.99 -0.081 0.16978E+04 108 minnesotaite 10.46 6.74 -3.72 -0.219 0.63483E+04 110 magnesioferrite 26.26 21.43 -4.83 -0.394 0.82435E+04 113 margarite 17.45 12.52 -4.93 -0.197 0.84246E+04 120 muscovite 2.68 1.05 -1.63 -0.096 0.27868E+04 121 paragonite 4.34 3.15 -1.19 -0.070 0.20252E+04 122 nepheline 8.38 6.25 -2.13 -0.304 0.36345E+04 134 phlogopite-Na 29.73 26.44 -3.29 -0.183 0.56147E+04 136 prehnite 19.47 17.89 -1.58 -0.093 0.26951E+04 137 prehnite-Fe 22.59 22.40 -0.19 -0.011 0.31674E+03 138 pumpellyite-Fe 46.47 44.15 -2.32 -0.052 0.39655E+04 139 pumpellyite-Mg 49.19 46.44 -2.75 -0.061 0.47040E+04 145 pyroxmangite 7.42 5.53 -1.88 -0.377 0.32157E+04 146 pyrophyllite -6.10 -9.68 -3.58 -0.224 0.61109E+04 147 quartz -2.98 -3.29 -0.31 -0.102 0.52412E+03 152 rhodonite 7.46 5.53 -1.93 -0.386 0.32950E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 24.63 -2.96 -0.088 0.50579E+04 171 talc 16.55 13.62 -2.94 -0.173 0.50162E+04 174 tephroite 18.11 14.35 -3.76 -0.537 0.64176E+04 177 topaz-H 4.67 0.19 -4.48 -0.407 0.76454E+04 178 tridymite -2.61 -3.29 -0.67 -0.225 0.11514E+04 187 wairakite 4.06 2.46 -1.60 -0.094 0.27277E+04 188 walstromite 11.53 8.85 -2.68 -0.536 0.45741E+04 189 wollastonite 10.48 8.85 -1.63 -0.327 0.27880E+04 190 pseudo-wollastonite 11.02 8.85 -2.17 -0.434 0.37066E+04 191 zoisite 22.96 19.63 -3.34 -0.152 0.56966E+04 192 akaganeite 7.77 6.25 -1.51 -0.328 0.25867E+04 193 beidellite-Ca -1.56 -6.01 -4.46 -0.276 0.76070E+04 195 beidellite-K -1.44 -6.14 -4.70 -0.288 0.80302E+04 196 beidellite-Mg -1.71 -6.55 -4.84 -0.299 0.82612E+04 197 beidellite-Na -1.26 -5.44 -4.19 -0.256 0.71489E+04 199 chalcedony -2.79 -3.29 -0.49 -0.165 0.84444E+03 201 montmorillonite-Ca -2.21 -5.30 -3.09 -0.191 0.52749E+04 202 montmorillonite-K -2.16 -5.43 -3.27 -0.200 0.55759E+04 203 montmorillonite-Mg -2.40 -5.83 -3.43 -0.212 0.58601E+04 204 montmorillonite-Na -1.96 -4.73 -2.77 -0.170 0.47327E+04 205 nontronite-Ca 3.28 3.01 -0.27 -0.017 0.45720E+03 206 nontronite-H 2.60 1.01 -1.59 -0.106 0.27091E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11230E+04 224 tobermorite 9.84 6.82 -3.02 -0.823 0.51515E+04 233 boehmite 4.43 1.74 -2.69 -0.448 0.45934E+04 235 ferrous-oxide 9.82 6.63 -3.19 -0.798 0.54492E+04 240 silica-amorphous -2.08 -3.29 -1.21 -0.403 0.20646E+04 242 an20ab80 2.08 1.55 -0.53 -0.041 0.91198E+03 243 an25ab75 2.71 2.01 -0.70 -0.054 0.11879E+04 244 an30ab70 3.34 2.48 -0.86 -0.066 0.14721E+04 245 tr.625ac.25prg.125 45.31 41.05 -4.25 -0.115 0.72646E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 25.9990000 g New total amount of reactant added: 26.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2992E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 26.9990000 Water: Moles liquid = 0.5532E+02 kg liquid = 0.9966E+00 Moles total = 0.5517E+02 kg total = 0.9939E+00 Activity = 1.0000 Stoichiometric ionic strength = .5400640E-02 Osmotic coef. = 0.9612 True ionic strength = .9803552E-02 Chg. balance for total moles = 0.2992E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15247E-09 -9.8168 0.13338E-09 -9.8749 0.87480E+00 -0.0581 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13812E-03 -3.8598 0.12042E-03 -3.9193 0.87188E+00 -0.0595 4 SO4-- 0.25574E-04 -4.5922 0.15698E-04 -4.8041 0.61384E+00 -0.2119 5 HCO3- 0.66006E-05 -5.1804 0.57595E-05 -5.2396 0.87258E+00 -0.0592 6 HS- 0.29632E-11 -11.5282 0.25838E-11 -11.5877 0.87195E+00 -0.0595 7 Al+++ 0.36707E-27 -27.4352 0.12428E-27 -27.9056 0.33857E+00 -0.4704 8 H4SiO4 0.52107E-03 -3.2831 0.52107E-03 -3.2831 0.10000E+01 0.0000 9 Ca++ 0.39953E-07 -7.3984 0.24426E-07 -7.6122 0.61136E+00 -0.2137 10 Mg++ 0.24924E-10 -10.6034 0.15199E-10 -10.8182 0.60981E+00 -0.2148 11 Fe++ 0.12476E-12 -12.9039 0.76128E-13 -13.1185 0.61018E+00 -0.2145 12 K+ 0.76320E-04 -4.1174 0.66605E-04 -4.1765 0.87270E+00 -0.0591 13 Na+ 0.96944E-02 -2.0135 0.84516E-02 -2.0731 0.87180E+00 -0.0596 14 Mn++ 0.19679E-10 -10.7060 0.12013E-10 -10.9203 0.61046E+00 -0.2143 15 HPO4-- 0.54456E-06 -6.2640 0.33430E-06 -6.4759 0.61389E+00 -0.2119 16 HSiO3- 0.43717E-02 -2.3594 0.38115E-02 -2.4189 0.87188E+00 -0.0595 17 Ca(HSiO3)+ 0.23899E-08 -8.6216 0.20859E-08 -8.6807 0.87280E+00 -0.0591 18 Mg(HSiO3)+ 0.18507E-11 -11.7327 0.16153E-11 -11.7917 0.87280E+00 -0.0591 19 NaHSiO3,aq 0.51163E-03 -3.2910 0.51163E-03 -3.2910 0.10000E+01 0.0000 20 AlO+ 0.10332E-14 -14.9858 0.90181E-15 -15.0449 0.87280E+00 -0.0591 22 HAlO2,aq 0.13530E-08 -8.8687 0.13530E-08 -8.8687 0.10000E+01 0.0000 23 AlO2- 0.26004E-04 -4.5850 0.22649E-04 -4.6449 0.87100E+00 -0.0600 24 CH4,aq 0.93174E-18 -18.0307 0.93019E-18 -18.0314 0.99834E+00 -0.0007 29 CO,aq 0.89038E-19 -19.0504 0.89038E-19 -19.0504 0.10000E+01 0.0000 30 CO2,aq 0.15515E-08 -8.8093 0.15489E-08 -8.8100 0.99834E+00 -0.0007 31 CO3-2 0.65118E-05 -5.1863 0.39925E-05 -5.3988 0.61312E+00 -0.2125 32 CaCO3,aq 0.11944E-08 -8.9229 0.11944E-08 -8.9229 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40613E-11 -11.3913 0.35447E-11 -11.4504 0.87280E+00 -0.0591 34 CaCl+ 0.53701E-11 -11.2700 0.46870E-11 -11.3291 0.87280E+00 -0.0591 35 CaCl2,aq 0.13142E-15 -15.8813 0.13142E-15 -15.8813 0.10000E+01 0.0000 36 CaOH+ 0.14794E-07 -7.8299 0.12913E-07 -7.8890 0.87280E+00 -0.0591 37 CaSO4,aq 0.11947E-09 -9.9227 0.11947E-09 -9.9227 0.10000E+01 0.0000 38 HCl,aq 0.30212E-14 -14.5198 0.30212E-14 -14.5198 0.10000E+01 0.0000 43 FeCl+ 0.16359E-16 -16.7862 0.14278E-16 -16.8453 0.87280E+00 -0.0591 46 FeO,aq 0.16921E-09 -9.7716 0.16921E-09 -9.7716 0.10000E+01 0.0000 47 FeOH+ 0.21679E-10 -10.6640 0.18922E-10 -10.7230 0.87280E+00 -0.0591 48 HFeO2- 0.15651E-07 -7.8055 0.13645E-07 -7.8650 0.87188E+00 -0.0595 49 FeO+ 0.11167E-14 -14.9521 0.97466E-15 -15.0111 0.87280E+00 -0.0591 51 FeO2- 0.12350E-07 -7.9083 0.10767E-07 -7.9679 0.87188E+00 -0.0595 52 HFeO2,aq 0.17974E-09 -9.7454 0.17974E-09 -9.7454 0.10000E+01 0.0000 53 H2,aq 0.22357E-08 -8.6506 0.22320E-08 -8.6513 0.99834E+00 -0.0007 54 KCl,aq 0.14202E-09 -9.8477 0.14202E-09 -9.8477 0.10000E+01 0.0000 55 KHSO4,aq 0.37320E-18 -18.4281 0.37320E-18 -18.4281 0.10000E+01 0.0000 56 KOH,aq 0.21769E-06 -6.6622 0.21769E-06 -6.6622 0.10000E+01 0.0000 57 KSO4- 0.18476E-07 -7.7334 0.16109E-07 -7.7929 0.87188E+00 -0.0595 58 MgCO3,aq 0.18571E-12 -12.7312 0.18571E-12 -12.7312 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.25770E-14 -14.5889 0.22492E-14 -14.6480 0.87280E+00 -0.0591 60 MgCl+ 0.30335E-14 -14.5181 0.26476E-14 -14.5771 0.87280E+00 -0.0591 61 MgOH+ 0.51000E-10 -10.2924 0.44513E-10 -10.3515 0.87280E+00 -0.0591 63 MnO,aq 0.71281E-09 -9.1470 0.71281E-09 -9.1470 0.10000E+01 0.0000 64 MnOH+ 0.31780E-09 -9.4978 0.27738E-09 -9.5569 0.87280E+00 -0.0591 65 MnO2-2 0.22600E-11 -11.6459 0.13856E-11 -11.8584 0.61312E+00 -0.2125 66 HMnO2- 0.45927E-10 -10.3379 0.40043E-10 -10.3975 0.87188E+00 -0.0595 69 MnCl+ 0.10031E-13 -13.9986 0.87554E-14 -14.0577 0.87280E+00 -0.0591 70 MnSO4,aq 0.53445E-13 -13.2721 0.53445E-13 -13.2721 0.10000E+01 0.0000 71 NaCl,aq 0.33232E-06 -6.4784 0.33232E-06 -6.4784 0.10000E+01 0.0000 72 NaOH,aq 0.27842E-04 -4.5553 0.27842E-04 -4.5553 0.10000E+01 0.0000 74 OH- 0.51632E-02 -2.2871 0.44971E-02 -2.3471 0.87100E+00 -0.0600 79 HPO3-2 0.38439E-17 -17.4152 0.23567E-17 -17.6277 0.61312E+00 -0.2125 82 H3PO4,aq 0.38289E-16 -16.4169 0.38289E-16 -16.4169 0.10000E+01 0.0000 83 H2PO4- 0.89615E-09 -9.0476 0.78174E-09 -9.1069 0.87233E+00 -0.0593 84 PO4-3 0.62911E-08 -8.2013 0.21888E-08 -8.6598 0.34792E+00 -0.4585 87 H2P2O7-2 0.78010E-19 -19.1078 0.47829E-19 -19.3203 0.61312E+00 -0.2125 88 HP2O7-3 0.21708E-15 -15.6634 0.73530E-16 -16.1335 0.33872E+00 -0.4702 89 P2O7-4 0.90572E-15 -15.0430 0.13600E-15 -15.8665 0.15015E+00 -0.8235 90 H2S,aq 0.10372E-14 -14.9841 0.10355E-14 -14.9849 0.99834E+00 -0.0007 97 SO3-2 0.77300E-14 -14.1118 0.47774E-14 -14.3208 0.61804E+00 -0.2090 98 HSO3- 0.42772E-16 -16.3688 0.37292E-16 -16.4284 0.87188E+00 -0.0595 99 HSO4- 0.22248E-11 -11.6527 0.19428E-11 -11.7116 0.87327E+00 -0.0589 Charge balance for all species = 0.2989E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1524713E-09 -.1018514E-01 -.1025821E+02 0.0000 2 H2O 0.1000000E+01 0.5550861E+02 0.9992442E+06 0.0000 3 Cl- 0.1381177E-03 0.1384502E-03 0.4904743E+01 5.9556 4 SO4-- 0.2557385E-04 0.2559346E-04 0.2456680E+01 14.9457 5 HCO3- 0.6600582E-05 0.1311509E-04 0.7996377E+00 4.6353 6 HS- 0.2963219E-11 -.1004277E-08 -.3318819E-04 -1.7128 7 Al+++ 0.3670746E-27 0.2600492E-04 0.7011184E+00 1.7191 8 H4SiO4 0.5210728E-03 0.5404370E-02 0.5190484E+03 -3.2831 9 Ca++ 0.3995306E-07 0.5846065E-07 0.2341205E-02 12.1376 10 Mg++ 0.2492353E-10 0.7796547E-10 0.1894056E-05 8.9316 11 Fe++ 0.1247645E-12 0.2837094E-07 0.1583227E-02 6.6313 12 K+ 0.7632039E-04 0.7655670E-04 0.2991245E+01 5.6984 13 Na+ 0.9694445E-02 0.1023425E-01 0.2351046E+03 7.8018 14 Mn++ 0.1967888E-10 0.1098542E-08 0.6030582E-04 8.8295 15 HPO4-- 0.5445570E-06 0.5517443E-06 0.5291561E-01 13.2739 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4470503E+00 -.1015013E-01 -.4369002E+00 0.0000000E+00 2 H2O 0.5516981E+02 0.5531778E+02 -.1479696E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7737388E-03 0.2550547E-04 0.7482333E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7482343E-03 -.1000824E-08 -.7482333E-03 0.0000000E+00 7 Al+++ 0.8803676E-01 0.2591551E-04 0.8801085E-01 0.0000000E+00 8 H4SiO4 0.2811347E+00 0.5385790E-02 0.2757489E+00 0.0000000E+00 9 Ca++ 0.3106717E-01 0.5825967E-07 0.3106711E-01 0.0000000E+00 10 Mg++ 0.2142778E-01 0.7769743E-10 0.2142778E-01 0.0000000E+00 11 Fe++ 0.1925052E-01 0.2827340E-07 0.1925049E-01 0.0000000E+00 12 K+ 0.5732272E-02 0.7629351E-04 0.5655978E-02 0.0000000E+00 13 Na+ 0.3405039E-01 0.1019907E-01 0.2385133E-01 0.0000000E+00 14 Mn++ 0.4681248E-03 0.1094765E-08 0.4681237E-03 0.0000000E+00 15 HPO4-- 0.1597687E-03 0.5498474E-06 0.1592188E-03 0.0000000E+00 Chg. balance for solid moles: 0.1216E-15 Mass of aqueous solution: 0.997320E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 26.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2377E-01 -1.624 6.234 0.795 21.15 2.393 andradite 0.2753E-02 -2.560 1.399 0.146 4.747 0.3635 grossular 0.1106E-03 -3.956 0.4982E-01 -1.303 0.1690 0.1386E-01 apatite-OH 0.5307E-04 -4.275 0.2666E-01 -1.574 0.9046E-01 0.8471E-02 clinochlore 0.4286E-02 -2.368 2.382 0.377 8.083 0.9061 daphnite 0.2247E-02 -2.648 1.603 0.205 5.439 0.4857 chlorite-Mn 0.9362E-04 -4.029 0.6638E-01 -1.178 0.2252 0.2115E-01 microcline 0.5453E-02 -2.263 1.518 0.181 5.150 0.5929 stilbite 0.2221E-01 -1.653 15.65 1.195 53.11 7.301 stilpnomelane-Fe 0.4064E-03 -3.391 0.4381 -0.358 1.486 0.1513 nontronite-Na 0.2398E-03 -3.620 0.1020 -0.991 0.3461 0.3168E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9614E+00 0.9614E+00 1.0000 -0.017 grossular 0.3862E-01 0.3862E-01 1.0000 -1.413 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6468E+00 0.6468E+00 1.0000 -0.189 daphnite 0.3391E+00 0.3391E+00 1.0000 -0.470 chlorite-Mn 0.1413E-01 0.1413E-01 1.0000 -1.850 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 29.470523 g Volume = 12.268065 cm3 Porosity: -3.9702% V(tot) - V(min): -.46847E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 26.9990000 g log = 1.4313 Original solution: 1000.0103000 g Original solution / Rock added: 37.04 (Water/Rock Ratio), log = 1.5687 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1673E-06 1.0073 0.1773E-06 0.1760E-06 CH4,gas 0.1381E-14 1.0129 0.1471E-14 0.1452E-14 H2,gas 0.2909E-05 1.0006 0.3061E-05 0.3060E-05 H2S,gas 0.2883E-13 0.9959 0.3020E-13 0.3032E-13 S2,gas 0.3465E-35 1.0000 0.3645E-35 0.3645E-35 CO,gas 0.1337E-15 1.0000 0.1406E-15 0.1406E-15 SO3,gas 0.9926E-40 1.0000 0.1044E-39 0.1044E-39 SO2,gas 0.1149E-22 1.0000 0.1209E-22 0.1209E-22 HCl,gas 0.5071E-17 1.0000 0.5335E-17 0.5335E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.11374E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.917 0.14943E+05 -6.751 3 CH4,gas 4.81 -12.02 -16.83 -4.208 0.28741E+05 -14.832 4 H2,gas 8.29 0.77 -7.51 -4.294 0.12830E+05 -5.514 5 H2S,gas -5.94 -21.46 -15.52 -7.760 0.26500E+05 -13.520 6 S2,gas -7.03 -44.47 -37.44 -5.760 0.63925E+05 -35.438 7 CO,gas 3.51 -14.34 -17.85 -5.493 0.30482E+05 -15.852 8 SO3,gas 17.43 -24.55 -41.98 -10.495 0.71682E+05 -39.981 9 SO2,gas 1.14 -23.78 -24.92 -6.645 0.42546E+05 -22.918 10 HCl,gas 5.48 -13.79 -19.27 -9.636 0.32908E+05 -17.273 11 acmite 7.74 7.48 -0.26 -0.027 0.43850E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.08 -4.47 -0.224 0.76369E+04 20 analcite 3.37 2.95 -0.42 -0.046 0.71013E+03 21 andalusite 5.06 0.16 -4.91 -0.491 0.83790E+04 26 annite 20.21 17.46 -2.75 -0.153 0.46905E+04 27 phlogopite 27.15 24.36 -2.78 -0.155 0.47529E+04 29 anorthite 12.80 9.01 -3.79 -0.291 0.64680E+04 35 aragonite 0.99 -2.98 -3.96 -1.321 0.67669E+04 36 brucite 12.58 8.93 -3.64 -0.729 0.62237E+04 37 calcite 0.83 -2.98 -3.81 -1.270 0.65055E+04 38 carnegieite-low 9.06 6.24 -2.83 -0.404 0.48265E+04 39 carnegieite-high 10.13 6.24 -3.90 -0.557 0.66534E+04 40 carpholite-Mg 8.65 5.80 -2.85 -0.190 0.48608E+04 41 carpholite-Fe 6.78 3.50 -3.28 -0.219 0.55997E+04 42 celadonite 5.40 3.22 -2.18 -0.128 0.37288E+04 43 celadonite-Fe 3.94 0.92 -3.02 -0.178 0.51574E+04 44 chrysotile 23.94 20.23 -3.71 -0.309 0.63325E+04 50 chloritoid-Mg 13.26 9.09 -4.17 -0.278 0.71279E+04 51 chloritoid-Fe 9.24 6.79 -2.45 -0.163 0.41871E+04 52 chloritoid-Mn 11.46 8.98 -2.48 -0.165 0.42322E+04 54 coesite -2.37 -3.28 -0.91 -0.305 0.15602E+04 59 corundum 8.43 3.44 -5.00 -0.454 0.85292E+04 61 cristobalite -2.55 -3.28 -0.73 -0.245 0.12531E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.72 -1.18 -0.196 0.20097E+04 67 diopside 16.22 14.50 -1.71 -0.171 0.29239E+04 68 hedenbergite 14.24 12.20 -2.04 -0.204 0.34860E+04 75 epidote 24.78 24.11 -0.67 -0.032 0.11373E+04 76 clinozoisite 22.92 19.58 -3.34 -0.152 0.56993E+04 77 epidote-Fe 29.94 28.63 -1.30 -0.068 0.22228E+04 78 fayalite 14.08 9.98 -4.10 -0.586 0.69995E+04 79 ferrosilite 11.19 6.70 -4.49 -0.449 0.76686E+04 83 gibbsite 4.10 1.72 -2.38 -0.340 0.40609E+04 84 glaucophane 23.11 19.57 -3.54 -0.096 0.60421E+04 85 glaucophane-Fe 17.42 12.67 -4.75 -0.128 0.81038E+04 87 greenalite 16.19 13.33 -2.87 -0.239 0.48942E+04 90 hematite 12.60 12.49 -0.11 -0.013 0.18394E+03 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.95 -1.30 -0.130 0.22132E+04 96 julgoldite 70.57 67.09 -3.48 -0.090 0.59393E+04 97 kalsilite 7.62 4.13 -3.49 -0.498 0.59520E+04 98 kaolinite -1.27 -3.13 -1.85 -0.169 0.31671E+04 99 kyanite 4.93 0.16 -4.78 -0.478 0.81558E+04 101 laumontite 2.97 2.44 -0.53 -0.035 0.90683E+03 102 lawsonite 9.68 9.01 -0.67 -0.045 0.11418E+04 103 leucite 4.17 0.85 -3.32 -0.332 0.56625E+04 105 lizardite 23.29 20.23 -3.06 -0.255 0.52228E+04 107 magnetite 20.13 19.12 -1.01 -0.083 0.17272E+04 108 minnesotaite 10.46 6.76 -3.70 -0.218 0.63161E+04 110 magnesioferrite 26.26 21.42 -4.84 -0.395 0.82570E+04 120 muscovite 2.68 1.01 -1.67 -0.098 0.28562E+04 121 paragonite 4.34 3.11 -1.23 -0.072 0.20947E+04 122 nepheline 8.38 6.24 -2.14 -0.306 0.36545E+04 134 phlogopite-Na 29.73 26.47 -3.26 -0.181 0.55748E+04 136 prehnite 19.47 17.86 -1.60 -0.094 0.27356E+04 137 prehnite-Fe 22.59 22.39 -0.20 -0.012 0.33590E+03 138 pumpellyite-Fe 46.47 44.08 -2.39 -0.053 0.40838E+04 139 pumpellyite-Mg 49.19 46.38 -2.81 -0.063 0.48064E+04 145 pyroxmangite 7.42 5.55 -1.87 -0.374 0.31924E+04 146 pyrophyllite -6.10 -9.69 -3.60 -0.225 0.61404E+04 147 quartz -2.98 -3.28 -0.30 -0.100 0.51413E+03 152 rhodonite 7.46 5.55 -1.92 -0.383 0.32717E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 24.68 -2.92 -0.087 0.49784E+04 171 talc 16.55 13.66 -2.89 -0.170 0.49362E+04 174 tephroite 18.11 14.38 -3.74 -0.534 0.63810E+04 177 topaz-H 4.67 0.16 -4.51 -0.410 0.77049E+04 178 tridymite -2.61 -3.28 -0.67 -0.223 0.11414E+04 187 wairakite 4.06 2.44 -1.62 -0.095 0.27576E+04 188 walstromite 11.53 8.85 -2.67 -0.535 0.45646E+04 189 wollastonite 10.48 8.85 -1.63 -0.325 0.27785E+04 190 pseudo-wollastonite 11.02 8.85 -2.17 -0.433 0.36971E+04 191 zoisite 22.96 19.58 -3.38 -0.154 0.57718E+04 192 akaganeite 7.77 6.24 -1.52 -0.329 0.26001E+04 193 beidellite-Ca -1.56 -6.04 -4.48 -0.277 0.76513E+04 195 beidellite-K -1.44 -6.16 -4.73 -0.290 0.80729E+04 196 beidellite-Mg -1.71 -6.57 -4.86 -0.301 0.83032E+04 197 beidellite-Na -1.26 -5.47 -4.21 -0.258 0.71916E+04 199 chalcedony -2.79 -3.28 -0.49 -0.163 0.83444E+03 201 montmorillonite-Ca -2.21 -5.31 -3.10 -0.192 0.52886E+04 202 montmorillonite-K -2.16 -5.43 -3.27 -0.200 0.55879E+04 203 montmorillonite-Mg -2.40 -5.84 -3.44 -0.213 0.58715E+04 204 montmorillonite-Na -1.96 -4.74 -2.78 -0.170 0.47448E+04 205 nontronite-Ca 3.28 3.01 -0.27 -0.017 0.45885E+03 206 nontronite-H 2.60 1.01 -1.59 -0.106 0.27107E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11224E+04 224 tobermorite 9.84 6.83 -3.01 -0.822 0.51420E+04 233 boehmite 4.43 1.72 -2.71 -0.452 0.46281E+04 235 ferrous-oxide 9.82 6.63 -3.19 -0.798 0.54517E+04 240 silica-amorphous -2.08 -3.28 -1.20 -0.401 0.20546E+04 242 an20ab80 2.08 1.54 -0.54 -0.042 0.92198E+03 243 an25ab75 2.71 2.01 -0.70 -0.054 0.12004E+04 244 an30ab70 3.34 2.47 -0.87 -0.067 0.14871E+04 245 tr.625ac.25prg.125 45.31 41.12 -4.19 -0.113 0.71555E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 26.9990000 g New total amount of reactant added: 27.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2992E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 27.9990000 Water: Moles liquid = 0.5531E+02 kg liquid = 0.9965E+00 Moles total = 0.5516E+02 kg total = 0.9937E+00 Activity = 1.0000 Stoichiometric ionic strength = .5431299E-02 Osmotic coef. = 0.9611 True ionic strength = .9864972E-02 Chg. balance for total moles = 0.2992E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15248E-09 -9.8168 0.13335E-09 -9.8750 0.87453E+00 -0.0582 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13813E-03 -3.8597 0.12039E-03 -3.9194 0.87159E+00 -0.0597 4 SO4-- 0.25577E-04 -4.5922 0.15680E-04 -4.8047 0.61306E+00 -0.2125 5 HCO3- 0.65974E-05 -5.1806 0.57549E-05 -5.2400 0.87230E+00 -0.0593 6 HS- 0.33128E-11 -11.4798 0.28876E-11 -11.5395 0.87166E+00 -0.0597 7 Al+++ 0.35165E-27 -27.4539 0.11871E-27 -27.9255 0.33758E+00 -0.4716 8 H4SiO4 0.52789E-03 -3.2775 0.52789E-03 -3.2775 0.10000E+01 0.0000 9 Ca++ 0.39960E-07 -7.3984 0.24398E-07 -7.6126 0.61057E+00 -0.2143 10 Mg++ 0.25377E-10 -10.5956 0.15455E-10 -10.8109 0.60901E+00 -0.2154 11 Fe++ 0.12445E-12 -12.9050 0.75840E-13 -13.1201 0.60938E+00 -0.2151 12 K+ 0.76800E-04 -4.1146 0.67002E-04 -4.1739 0.87242E+00 -0.0593 13 Na+ 0.97554E-02 -2.0108 0.85019E-02 -2.0705 0.87151E+00 -0.0597 14 Mn++ 0.20037E-10 -10.6982 0.12216E-10 -10.9131 0.60966E+00 -0.2149 15 HPO4-- 0.54611E-06 -6.2627 0.33483E-06 -6.4752 0.61311E+00 -0.2125 16 HSiO3- 0.44313E-02 -2.3535 0.38623E-02 -2.4132 0.87159E+00 -0.0597 17 Ca(HSiO3)+ 0.24198E-08 -8.6162 0.21113E-08 -8.6754 0.87252E+00 -0.0592 18 Mg(HSiO3)+ 0.19076E-11 -11.7195 0.16644E-11 -11.7787 0.87252E+00 -0.0592 19 NaHSiO3,aq 0.52153E-03 -3.2827 0.52153E-03 -3.2827 0.10000E+01 0.0000 20 AlO+ 0.98769E-15 -15.0054 0.86178E-15 -15.0646 0.87252E+00 -0.0592 22 HAlO2,aq 0.12932E-08 -8.8883 0.12932E-08 -8.8883 0.10000E+01 0.0000 23 AlO2- 0.24869E-04 -4.6043 0.21654E-04 -4.6645 0.87071E+00 -0.0601 24 CH4,aq 0.10417E-17 -17.9823 0.10400E-17 -17.9830 0.99833E+00 -0.0007 29 CO,aq 0.91486E-19 -19.0386 0.91486E-19 -19.0386 0.10000E+01 0.0000 30 CO2,aq 0.15499E-08 -8.8097 0.15473E-08 -8.8104 0.99833E+00 -0.0007 31 CO3-2 0.65163E-05 -5.1860 0.39902E-05 -5.3990 0.61233E+00 -0.2130 32 CaCO3,aq 0.11923E-08 -8.9236 0.11923E-08 -8.9236 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40548E-11 -11.3920 0.35379E-11 -11.4513 0.87252E+00 -0.0592 34 CaCl+ 0.53645E-11 -11.2705 0.46807E-11 -11.3297 0.87252E+00 -0.0592 35 CaCl2,aq 0.13121E-15 -15.8820 0.13121E-15 -15.8820 0.10000E+01 0.0000 36 CaOH+ 0.14786E-07 -7.8302 0.12901E-07 -7.8894 0.87252E+00 -0.0592 37 CaSO4,aq 0.11920E-09 -9.9237 0.11920E-09 -9.9237 0.10000E+01 0.0000 38 HCl,aq 0.30199E-14 -14.5200 0.30199E-14 -14.5200 0.10000E+01 0.0000 43 FeCl+ 0.16299E-16 -16.7878 0.14221E-16 -16.8471 0.87252E+00 -0.0592 46 FeO,aq 0.16865E-09 -9.7730 0.16865E-09 -9.7730 0.10000E+01 0.0000 47 FeOH+ 0.21609E-10 -10.6654 0.18854E-10 -10.7246 0.87252E+00 -0.0592 48 HFeO2- 0.15607E-07 -7.8067 0.13603E-07 -7.8664 0.87159E+00 -0.0597 49 FeO+ 0.10975E-14 -14.9596 0.95761E-15 -15.0188 0.87252E+00 -0.0592 51 FeO2- 0.12143E-07 -7.9157 0.10584E-07 -7.9754 0.87159E+00 -0.0597 52 HFeO2,aq 0.17663E-09 -9.7529 0.17663E-09 -9.7529 0.10000E+01 0.0000 53 H2,aq 0.22995E-08 -8.6384 0.22957E-08 -8.6391 0.99833E+00 -0.0007 54 KCl,aq 0.14283E-09 -9.8452 0.14283E-09 -9.8452 0.10000E+01 0.0000 55 KHSO4,aq 0.37490E-18 -18.4261 0.37490E-18 -18.4261 0.10000E+01 0.0000 56 KOH,aq 0.21904E-06 -6.6595 0.21904E-06 -6.6595 0.10000E+01 0.0000 57 KSO4- 0.18570E-07 -7.7312 0.16186E-07 -7.7909 0.87159E+00 -0.0597 58 MgCO3,aq 0.18873E-12 -12.7242 0.18873E-12 -12.7242 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26192E-14 -14.5818 0.22853E-14 -14.6411 0.87252E+00 -0.0592 60 MgCl+ 0.30849E-14 -14.5108 0.26917E-14 -14.5700 0.87252E+00 -0.0592 61 MgOH+ 0.51889E-10 -10.2849 0.45274E-10 -10.3441 0.87252E+00 -0.0592 63 MnO,aq 0.72516E-09 -9.1396 0.72516E-09 -9.1396 0.10000E+01 0.0000 64 MnOH+ 0.32334E-09 -9.4903 0.28212E-09 -9.5496 0.87252E+00 -0.0592 65 MnO2-2 0.23031E-11 -11.6377 0.14103E-11 -11.8507 0.61233E+00 -0.2130 66 HMnO2- 0.46749E-10 -10.3302 0.40746E-10 -10.3899 0.87159E+00 -0.0597 69 MnCl+ 0.10202E-13 -13.9913 0.89011E-14 -14.0506 0.87252E+00 -0.0592 70 MnSO4,aq 0.54284E-13 -13.2653 0.54284E-13 -13.2653 0.10000E+01 0.0000 71 NaCl,aq 0.33422E-06 -6.4760 0.33422E-06 -6.4760 0.10000E+01 0.0000 72 NaOH,aq 0.28015E-04 -4.5526 0.28015E-04 -4.5526 0.10000E+01 0.0000 74 OH- 0.51660E-02 -2.2868 0.44981E-02 -2.3470 0.87071E+00 -0.0601 79 HPO3-2 0.39649E-17 -17.4018 0.24278E-17 -17.6148 0.61233E+00 -0.2130 82 H3PO4,aq 0.38333E-16 -16.4164 0.38333E-16 -16.4164 0.10000E+01 0.0000 83 H2PO4- 0.89766E-09 -9.0469 0.78281E-09 -9.1063 0.87205E+00 -0.0595 84 PO4-3 0.63199E-08 -8.1993 0.21927E-08 -8.6590 0.34696E+00 -0.4597 87 H2P2O7-2 0.78323E-19 -19.1061 0.47960E-19 -19.3191 0.61233E+00 -0.2130 88 HP2O7-3 0.21835E-15 -15.6608 0.73746E-16 -16.1323 0.33774E+00 -0.4714 89 P2O7-4 0.91322E-15 -15.0394 0.13643E-15 -15.8651 0.14939E+00 -0.8257 90 H2S,aq 0.11589E-14 -14.9359 0.11570E-14 -14.9367 0.99833E+00 -0.0007 97 SO3-2 0.79512E-14 -14.0996 0.49081E-14 -14.3091 0.61728E+00 -0.2095 98 HSO3- 0.43946E-16 -16.3571 0.38303E-16 -16.4168 0.87159E+00 -0.0597 99 HSO4- 0.22224E-11 -11.6532 0.19401E-11 -11.7122 0.87299E+00 -0.0590 Charge balance for all species = 0.2987E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1524844E-09 -.1025320E-01 -.1032668E+02 0.0000 2 H2O 0.1000000E+01 0.5550854E+02 0.9992353E+06 0.0000 3 Cl- 0.1381308E-03 0.1384651E-03 0.4905236E+01 5.9556 4 SO4-- 0.2557653E-04 0.2559619E-04 0.2456923E+01 14.9453 5 HCO3- 0.6597432E-05 0.1311651E-04 0.7997182E+00 4.6350 6 HS- 0.3312789E-11 -.9617452E-09 -.3178242E-04 -1.6645 7 Al+++ 0.3516461E-27 0.2487009E-04 0.6705173E+00 1.6995 8 H4SiO4 0.5278932E-03 0.5480745E-02 0.5263796E+03 -3.2775 9 Ca++ 0.3995973E-07 0.5848624E-07 0.2342212E-02 12.1374 10 Mg++ 0.2537737E-10 0.7936834E-10 0.1928122E-05 8.9391 11 Fe++ 0.1244537E-12 0.2811670E-07 0.1569028E-02 6.6299 12 K+ 0.7679965E-04 0.7703740E-04 0.3010004E+01 5.7011 13 Na+ 0.9755376E-02 0.1030526E-01 0.2367339E+03 7.8045 14 Mn++ 0.2003711E-10 0.1117660E-08 0.6135486E-04 8.8369 15 HPO4-- 0.5461136E-06 0.5533312E-06 0.5306740E-01 13.2748 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4636088E+00 -.1021684E-01 -.4533920E+00 0.0000000E+00 2 H2O 0.5515727E+02 0.5531172E+02 -.1544504E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8014522E-03 0.2550543E-04 0.7759468E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7759477E-03 -.9583351E-09 -.7759468E-03 0.0000000E+00 7 Al+++ 0.9129750E-01 0.2478191E-04 0.9127272E-01 0.0000000E+00 8 H4SiO4 0.2915475E+00 0.5461311E-02 0.2860862E+00 0.0000000E+00 9 Ca++ 0.3221732E-01 0.5827886E-07 0.3221726E-01 0.0000000E+00 10 Mg++ 0.2222143E-01 0.7908692E-10 0.2222143E-01 0.0000000E+00 11 Fe++ 0.1996353E-01 0.2801700E-07 0.1996350E-01 0.0000000E+00 12 K+ 0.5944586E-02 0.7676425E-04 0.5867822E-02 0.0000000E+00 13 Na+ 0.3530564E-01 0.1026872E-01 0.2503692E-01 0.0000000E+00 14 Mn++ 0.4854633E-03 0.1113697E-08 0.4854622E-03 0.0000000E+00 15 HPO4-- 0.1656862E-03 0.5513692E-06 0.1651349E-03 0.0000000E+00 Chg. balance for solid moles: 0.1708E-16 Mass of aqueous solution: 0.997220E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 27.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2497E-01 -1.603 6.548 0.816 21.42 2.514 andradite 0.2902E-02 -2.537 1.475 0.169 4.826 0.3832 grossular 0.1134E-03 -3.945 0.5108E-01 -1.292 0.1671 0.1421E-01 apatite-OH 0.5504E-04 -4.259 0.2765E-01 -1.558 0.9047E-01 0.8786E-02 clinochlore 0.4444E-02 -2.352 2.470 0.393 8.083 0.9396 daphnite 0.2282E-02 -2.642 1.629 0.212 5.328 0.4935 chlorite-Mn 0.9709E-04 -4.013 0.6884E-01 -1.162 0.2252 0.2194E-01 microcline 0.5633E-02 -2.249 1.568 0.195 5.130 0.6125 stilbite 0.2290E-01 -1.640 16.13 1.208 52.79 7.526 stilpnomelane-Fe 0.4688E-03 -3.329 0.5053 -0.296 1.653 0.1746 nontronite-Na 0.2016E-03 -3.696 0.8572E-01 -1.067 0.2805 0.2663E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9624E+00 0.9624E+00 1.0000 -0.017 grossular 0.3760E-01 0.3760E-01 1.0000 -1.425 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6513E+00 0.6513E+00 1.0000 -0.186 daphnite 0.3345E+00 0.3345E+00 1.0000 -0.476 chlorite-Mn 0.1423E-01 0.1423E-01 1.0000 -1.847 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 30.562723 g Volume = 12.713962 cm3 Porosity: -4.2162% V(tot) - V(min): -.51436E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 27.9990000 g log = 1.4471 Original solution: 1000.0103000 g Original solution / Rock added: 35.72 (Water/Rock Ratio), log = 1.5529 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1671E-06 1.0073 0.1771E-06 0.1758E-06 CH4,gas 0.1543E-14 1.0129 0.1645E-14 0.1624E-14 H2,gas 0.2992E-05 1.0006 0.3149E-05 0.3147E-05 H2S,gas 0.3221E-13 0.9959 0.3374E-13 0.3388E-13 S2,gas 0.4089E-35 1.0000 0.4302E-35 0.4302E-35 CO,gas 0.1373E-15 1.0000 0.1445E-15 0.1445E-15 SO3,gas 0.9910E-40 1.0000 0.1042E-39 0.1042E-39 SO2,gas 0.1180E-22 1.0000 0.1242E-22 0.1242E-22 HCl,gas 0.5069E-17 1.0000 0.5332E-17 0.5332E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.15165E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.11 -8.75 -2.917 0.14943E+05 -6.752 3 CH4,gas 4.81 -11.97 -16.78 -4.196 0.28658E+05 -14.784 4 H2,gas 8.29 0.79 -7.50 -4.287 0.12809E+05 -5.502 5 H2S,gas -5.94 -21.41 -15.47 -7.736 0.26418E+05 -13.472 6 S2,gas -7.03 -44.40 -37.37 -5.749 0.63802E+05 -35.366 7 CO,gas 3.51 -14.33 -17.84 -5.489 0.30462E+05 -15.840 8 SO3,gas 17.43 -24.55 -41.98 -10.495 0.71683E+05 -39.982 9 SO2,gas 1.14 -23.77 -24.91 -6.642 0.42526E+05 -22.906 10 HCl,gas 5.48 -13.79 -19.27 -9.637 0.32908E+05 -17.273 11 acmite 7.74 7.49 -0.25 -0.026 0.42757E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.08 -4.47 -0.224 0.76367E+04 20 analcite 3.37 2.95 -0.42 -0.047 0.71978E+03 21 andalusite 5.06 0.12 -4.94 -0.494 0.84364E+04 26 annite 20.21 17.46 -2.75 -0.153 0.46980E+04 27 phlogopite 27.15 24.39 -2.76 -0.153 0.47146E+04 29 anorthite 12.80 8.98 -3.82 -0.294 0.65162E+04 35 aragonite 0.99 -2.98 -3.96 -1.321 0.67681E+04 36 brucite 12.58 8.94 -3.64 -0.728 0.62110E+04 37 calcite 0.83 -2.98 -3.81 -1.270 0.65068E+04 38 carnegieite-low 9.06 6.23 -2.84 -0.405 0.48458E+04 39 carnegieite-high 10.13 6.23 -3.91 -0.558 0.66727E+04 40 carpholite-Mg 8.65 5.78 -2.87 -0.191 0.48957E+04 41 carpholite-Fe 6.78 3.47 -3.31 -0.221 0.56499E+04 42 celadonite 5.40 3.23 -2.17 -0.128 0.37064E+04 43 celadonite-Fe 3.94 0.92 -3.02 -0.177 0.51502E+04 44 chrysotile 23.94 20.26 -3.68 -0.306 0.62750E+04 50 chloritoid-Mg 13.26 9.06 -4.20 -0.280 0.71725E+04 51 chloritoid-Fe 9.24 6.75 -2.49 -0.166 0.42469E+04 52 chloritoid-Mn 11.46 8.96 -2.50 -0.167 0.42768E+04 54 coesite -2.37 -3.28 -0.91 -0.303 0.15506E+04 61 cristobalite -2.55 -3.28 -0.73 -0.243 0.12434E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.70 -1.20 -0.199 0.20432E+04 67 diopside 16.22 14.52 -1.69 -0.169 0.28924E+04 68 hedenbergite 14.24 12.21 -2.03 -0.203 0.34697E+04 75 epidote 24.78 24.08 -0.70 -0.034 0.11893E+04 76 clinozoisite 22.92 19.54 -3.38 -0.154 0.57719E+04 77 epidote-Fe 29.94 28.62 -1.32 -0.069 0.22542E+04 78 fayalite 14.08 9.98 -4.10 -0.585 0.69949E+04 79 ferrosilite 11.19 6.70 -4.48 -0.448 0.76543E+04 83 gibbsite 4.10 1.70 -2.40 -0.343 0.40944E+04 84 glaucophane 23.11 19.61 -3.50 -0.095 0.59846E+04 85 glaucophane-Fe 17.42 12.68 -4.74 -0.128 0.80919E+04 87 greenalite 16.19 13.33 -2.86 -0.238 0.48824E+04 90 hematite 12.60 12.47 -0.12 -0.015 0.20979E+03 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.95 -1.30 -0.130 0.22228E+04 96 julgoldite 70.57 67.09 -3.48 -0.090 0.59401E+04 97 kalsilite 7.62 4.12 -3.50 -0.500 0.59713E+04 98 kaolinite -1.27 -3.16 -1.88 -0.171 0.32148E+04 99 kyanite 4.93 0.12 -4.81 -0.481 0.82132E+04 101 laumontite 2.97 2.43 -0.55 -0.037 0.93576E+03 102 lawsonite 9.68 8.98 -0.70 -0.046 0.11900E+04 103 leucite 4.17 0.85 -3.32 -0.332 0.56722E+04 105 lizardite 23.29 20.26 -3.03 -0.252 0.51653E+04 107 magnetite 20.13 19.10 -1.03 -0.084 0.17555E+04 108 minnesotaite 10.46 6.78 -3.68 -0.217 0.62850E+04 110 magnesioferrite 26.26 21.41 -4.84 -0.395 0.82701E+04 120 muscovite 2.68 0.97 -1.71 -0.101 0.29232E+04 121 paragonite 4.34 3.07 -1.27 -0.074 0.21617E+04 122 nepheline 8.38 6.23 -2.15 -0.307 0.36738E+04 134 phlogopite-Na 29.73 26.49 -3.24 -0.180 0.55365E+04 136 prehnite 19.47 17.84 -1.63 -0.096 0.27747E+04 137 prehnite-Fe 22.59 22.38 -0.21 -0.012 0.35441E+03 138 pumpellyite-Fe 46.47 44.01 -2.46 -0.055 0.41979E+04 139 pumpellyite-Mg 49.19 46.32 -2.87 -0.064 0.49053E+04 145 pyroxmangite 7.42 5.56 -1.86 -0.371 0.31700E+04 146 pyrophyllite -6.10 -9.71 -3.61 -0.226 0.61688E+04 147 quartz -2.98 -3.28 -0.30 -0.098 0.50448E+03 152 rhodonite 7.46 5.56 -1.90 -0.381 0.32493E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 24.73 -2.87 -0.086 0.49022E+04 171 talc 16.55 13.71 -2.85 -0.167 0.48594E+04 174 tephroite 18.11 14.40 -3.72 -0.531 0.63458E+04 177 topaz-H 4.67 0.12 -4.55 -0.413 0.77622E+04 178 tridymite -2.61 -3.28 -0.66 -0.221 0.11318E+04 187 wairakite 4.06 2.43 -1.63 -0.096 0.27866E+04 188 walstromite 11.53 8.86 -2.67 -0.534 0.45555E+04 189 wollastonite 10.48 8.86 -1.62 -0.324 0.27694E+04 190 pseudo-wollastonite 11.02 8.86 -2.16 -0.432 0.36880E+04 191 zoisite 22.96 19.54 -3.42 -0.156 0.58444E+04 192 akaganeite 7.77 6.24 -1.53 -0.331 0.26131E+04 193 beidellite-Ca -1.56 -6.07 -4.51 -0.279 0.76941E+04 195 beidellite-K -1.44 -6.19 -4.75 -0.291 0.81140E+04 196 beidellite-Mg -1.71 -6.59 -4.89 -0.302 0.83438E+04 197 beidellite-Na -1.26 -5.49 -4.24 -0.259 0.72328E+04 199 chalcedony -2.79 -3.28 -0.48 -0.161 0.82480E+03 201 montmorillonite-Ca -2.21 -5.32 -3.11 -0.192 0.53019E+04 202 montmorillonite-K -2.16 -5.44 -3.28 -0.201 0.55996E+04 203 montmorillonite-Mg -2.40 -5.85 -3.45 -0.213 0.58826E+04 204 montmorillonite-Na -1.96 -4.75 -2.79 -0.171 0.47565E+04 205 nontronite-Ca 3.28 3.01 -0.27 -0.017 0.46044E+03 206 nontronite-H 2.60 1.01 -1.59 -0.106 0.27122E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11218E+04 224 tobermorite 9.84 6.83 -3.01 -0.820 0.51327E+04 233 boehmite 4.43 1.70 -2.73 -0.455 0.46616E+04 235 ferrous-oxide 9.82 6.63 -3.19 -0.799 0.54542E+04 240 silica-amorphous -2.08 -3.28 -1.20 -0.399 0.20450E+04 242 an20ab80 2.08 1.53 -0.55 -0.042 0.93162E+03 243 an25ab75 2.71 2.00 -0.71 -0.055 0.12124E+04 244 an30ab70 3.34 2.46 -0.88 -0.068 0.15016E+04 245 tr.625ac.25prg.125 45.31 41.18 -4.13 -0.111 0.70507E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 27.9990000 g New total amount of reactant added: 28.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2992E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 28.9990000 Water: Moles liquid = 0.5531E+02 kg liquid = 0.9963E+00 Moles total = 0.5514E+02 kg total = 0.9935E+00 Activity = 1.0000 Stoichiometric ionic strength = .5461490E-02 Osmotic coef. = 0.9610 True ionic strength = .9924853E-02 Chg. balance for total moles = 0.2992E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15250E-09 -9.8167 0.13333E-09 -9.8751 0.87427E+00 -0.0584 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13814E-03 -3.8597 0.12037E-03 -3.9195 0.87132E+00 -0.0598 4 SO4-- 0.25579E-04 -4.5921 0.15662E-04 -4.8051 0.61230E+00 -0.2130 5 HCO3- 0.65945E-05 -5.1808 0.57506E-05 -5.2403 0.87203E+00 -0.0595 6 HS- 0.36895E-11 -11.4330 0.32149E-11 -11.4928 0.87139E+00 -0.0598 7 Al+++ 0.33740E-27 -27.4719 0.11358E-27 -27.9447 0.33663E+00 -0.4728 8 H4SiO4 0.53456E-03 -3.2720 0.53456E-03 -3.2720 0.10000E+01 0.0000 9 Ca++ 0.39968E-07 -7.3983 0.24372E-07 -7.6131 0.60980E+00 -0.2148 10 Mg++ 0.25822E-10 -10.5880 0.15706E-10 -10.8039 0.60824E+00 -0.2159 11 Fe++ 0.12416E-12 -12.9060 0.75566E-13 -13.1217 0.60861E+00 -0.2157 12 K+ 0.77267E-04 -4.1120 0.67388E-04 -4.1714 0.87215E+00 -0.0594 13 Na+ 0.98148E-02 -2.0081 0.85510E-02 -2.0680 0.87124E+00 -0.0599 14 Mn++ 0.20388E-10 -10.6906 0.12414E-10 -10.9061 0.60889E+00 -0.2155 15 HPO4-- 0.54761E-06 -6.2615 0.33533E-06 -6.4745 0.61235E+00 -0.2130 16 HSiO3- 0.44896E-02 -2.3478 0.39118E-02 -2.4076 0.87132E+00 -0.0598 17 Ca(HSiO3)+ 0.24490E-08 -8.6110 0.21361E-08 -8.6704 0.87225E+00 -0.0594 18 Mg(HSiO3)+ 0.19640E-11 -11.7069 0.17131E-11 -11.7662 0.87225E+00 -0.0594 19 NaHSiO3,aq 0.53127E-03 -3.2747 0.53127E-03 -3.2747 0.10000E+01 0.0000 20 AlO+ 0.94566E-15 -15.0243 0.82485E-15 -15.0836 0.87225E+00 -0.0594 22 HAlO2,aq 0.12380E-08 -8.9073 0.12380E-08 -8.9073 0.10000E+01 0.0000 23 AlO2- 0.23820E-04 -4.6231 0.20733E-04 -4.6833 0.87043E+00 -0.0603 24 CH4,aq 0.11602E-17 -17.9355 0.11583E-17 -17.9362 0.99832E+00 -0.0007 29 CO,aq 0.93917E-19 -19.0273 0.93917E-19 -19.0273 0.10000E+01 0.0000 30 CO2,aq 0.15484E-08 -8.8101 0.15458E-08 -8.8108 0.99832E+00 -0.0007 31 CO3-2 0.65207E-05 -5.1857 0.39879E-05 -5.3993 0.61157E+00 -0.2136 32 CaCO3,aq 0.11904E-08 -8.9243 0.11904E-08 -8.9243 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40487E-11 -11.3927 0.35315E-11 -11.4520 0.87225E+00 -0.0594 34 CaCl+ 0.53594E-11 -11.2709 0.46747E-11 -11.3302 0.87225E+00 -0.0594 35 CaCl2,aq 0.13101E-15 -15.8827 0.13101E-15 -15.8827 0.10000E+01 0.0000 36 CaOH+ 0.14778E-07 -7.8304 0.12890E-07 -7.8898 0.87225E+00 -0.0594 37 CaSO4,aq 0.11894E-09 -9.9247 0.11894E-09 -9.9247 0.10000E+01 0.0000 38 HCl,aq 0.30186E-14 -14.5202 0.30186E-14 -14.5202 0.10000E+01 0.0000 43 FeCl+ 0.16241E-16 -16.7894 0.14167E-16 -16.8487 0.87225E+00 -0.0594 46 FeO,aq 0.16810E-09 -9.7744 0.16810E-09 -9.7744 0.10000E+01 0.0000 47 FeOH+ 0.21542E-10 -10.6667 0.18790E-10 -10.7261 0.87225E+00 -0.0594 48 HFeO2- 0.15564E-07 -7.8079 0.13561E-07 -7.8677 0.87132E+00 -0.0598 49 FeO+ 0.10793E-14 -14.9668 0.94145E-15 -15.0262 0.87225E+00 -0.0594 51 FeO2- 0.11946E-07 -7.9228 0.10409E-07 -7.9826 0.87132E+00 -0.0598 52 HFeO2,aq 0.17368E-09 -9.7602 0.17368E-09 -9.7602 0.10000E+01 0.0000 53 H2,aq 0.23629E-08 -8.6266 0.23589E-08 -8.6273 0.99832E+00 -0.0007 54 KCl,aq 0.14362E-09 -9.8428 0.14362E-09 -9.8428 0.10000E+01 0.0000 55 KHSO4,aq 0.37656E-18 -18.4242 0.37656E-18 -18.4242 0.10000E+01 0.0000 56 KOH,aq 0.22034E-06 -6.6569 0.22034E-06 -6.6569 0.10000E+01 0.0000 57 KSO4- 0.18662E-07 -7.7290 0.16261E-07 -7.7889 0.87132E+00 -0.0598 58 MgCO3,aq 0.19168E-12 -12.7174 0.19168E-12 -12.7174 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26605E-14 -14.5750 0.23206E-14 -14.6344 0.87225E+00 -0.0594 60 MgCl+ 0.31352E-14 -14.5037 0.27347E-14 -14.5631 0.87225E+00 -0.0594 61 MgOH+ 0.52756E-10 -10.2777 0.46017E-10 -10.3371 0.87225E+00 -0.0594 63 MnO,aq 0.73720E-09 -9.1324 0.73720E-09 -9.1324 0.10000E+01 0.0000 64 MnOH+ 0.32875E-09 -9.4831 0.28675E-09 -9.5425 0.87225E+00 -0.0594 65 MnO2-2 0.23451E-11 -11.6298 0.14342E-11 -11.8434 0.61157E+00 -0.2136 66 HMnO2- 0.47549E-10 -10.3229 0.41430E-10 -10.3827 0.87132E+00 -0.0598 69 MnCl+ 0.10368E-13 -13.9843 0.90434E-14 -14.0437 0.87225E+00 -0.0594 70 MnSO4,aq 0.55102E-13 -13.2588 0.55102E-13 -13.2588 0.10000E+01 0.0000 71 NaCl,aq 0.33608E-06 -6.4736 0.33608E-06 -6.4736 0.10000E+01 0.0000 72 NaOH,aq 0.28181E-04 -4.5500 0.28181E-04 -4.5500 0.10000E+01 0.0000 74 OH- 0.51686E-02 -2.2866 0.44990E-02 -2.3469 0.87043E+00 -0.0603 79 HPO3-2 0.40853E-17 -17.3888 0.24985E-17 -17.6023 0.61157E+00 -0.2136 82 H3PO4,aq 0.38376E-16 -16.4159 0.38376E-16 -16.4159 0.10000E+01 0.0000 83 H2PO4- 0.89913E-09 -9.0462 0.78384E-09 -9.1058 0.87178E+00 -0.0596 84 PO4-3 0.63475E-08 -8.1974 0.21964E-08 -8.6583 0.34603E+00 -0.4609 87 H2P2O7-2 0.78627E-19 -19.1044 0.48086E-19 -19.3180 0.61157E+00 -0.2136 88 HP2O7-3 0.21959E-15 -15.6584 0.73955E-16 -16.1310 0.33679E+00 -0.4726 89 P2O7-4 0.92049E-15 -15.0360 0.13684E-15 -15.8638 0.14866E+00 -0.8278 90 H2S,aq 0.12901E-14 -14.8894 0.12879E-14 -14.8901 0.99832E+00 -0.0007 97 SO3-2 0.81707E-14 -14.0877 0.50376E-14 -14.2978 0.61654E+00 -0.2100 98 HSO3- 0.45111E-16 -16.3457 0.39306E-16 -16.4055 0.87132E+00 -0.0598 99 HSO4- 0.22201E-11 -11.6536 0.19376E-11 -11.7127 0.87272E+00 -0.0591 Charge balance for all species = 0.2989E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1525016E-09 -.1031981E-01 -.1039368E+02 0.0000 2 H2O 0.1000000E+01 0.5550847E+02 0.9992266E+06 0.0000 3 Cl- 0.1381439E-03 0.1384801E-03 0.4905730E+01 5.9556 4 SO4-- 0.2557921E-04 0.2559891E-04 0.2457166E+01 14.9450 5 HCO3- 0.6594487E-05 0.1311793E-04 0.7997987E+00 4.6348 6 HS- 0.3689464E-11 -.9205835E-09 -.3042194E-04 -1.6177 7 Al+++ 0.3373996E-27 0.2382085E-04 0.6422240E+00 1.6805 8 H4SiO4 0.5345642E-03 0.5555415E-02 0.5335471E+03 -3.2720 9 Ca++ 0.3996797E-07 0.5851333E-07 0.2343279E-02 12.1371 10 Mg++ 0.2582156E-10 0.8073949E-10 0.1961417E-05 8.9462 11 Fe++ 0.1241618E-12 0.2787388E-07 0.1555466E-02 6.6285 12 K+ 0.7726691E-04 0.7750606E-04 0.3028293E+01 5.7037 13 Na+ 0.9814782E-02 0.1037457E-01 0.2383244E+03 7.8071 14 Mn++ 0.2038772E-10 0.1136291E-08 0.6237717E-04 8.8441 15 HPO4-- 0.5476107E-06 0.5548574E-06 0.5321338E-01 13.2756 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4801673E+00 -.1028210E-01 -.4698852E+00 0.0000000E+00 2 H2O 0.5514474E+02 0.5530567E+02 -.1609380E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8291656E-03 0.2550539E-04 0.8036602E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8036611E-03 -.9172202E-09 -.8036602E-03 0.0000000E+00 7 Al+++ 0.9455825E-01 0.2373382E-04 0.9453451E-01 0.0000000E+00 8 H4SiO4 0.3019603E+00 0.5535119E-02 0.2964252E+00 0.0000000E+00 9 Ca++ 0.3336746E-01 0.5829955E-07 0.3336740E-01 0.0000000E+00 10 Mg++ 0.2301508E-01 0.8044451E-10 0.2301508E-01 0.0000000E+00 11 Fe++ 0.2067654E-01 0.2777205E-07 0.2067651E-01 0.0000000E+00 12 K+ 0.6156900E-02 0.7722289E-04 0.6079677E-02 0.0000000E+00 13 Na+ 0.3656088E-01 0.1033666E-01 0.2622422E-01 0.0000000E+00 14 Mn++ 0.5028019E-03 0.1132140E-08 0.5028008E-03 0.0000000E+00 15 HPO4-- 0.1716038E-03 0.5528302E-06 0.1710510E-03 0.0000000E+00 Chg. balance for solid moles: -.5047E-16 Mass of aqueous solution: 0.997119E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 28.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2617E-01 -1.582 6.862 0.836 21.68 2.634 andradite 0.3052E-02 -2.515 1.551 0.191 4.899 0.4029 grossular 0.1161E-03 -3.935 0.5229E-01 -1.282 0.1652 0.1455E-01 apatite-OH 0.5702E-04 -4.244 0.2864E-01 -1.543 0.9048E-01 0.9101E-02 clinochlore 0.4603E-02 -2.337 2.558 0.408 8.082 0.9732 daphnite 0.2318E-02 -2.635 1.654 0.218 5.224 0.5011 chlorite-Mn 0.1006E-03 -3.998 0.7129E-01 -1.147 0.2252 0.2272E-01 microcline 0.5814E-02 -2.236 1.618 0.209 5.112 0.6321 stilbite 0.2358E-01 -1.627 16.62 1.221 52.49 7.750 stilpnomelane-Fe 0.5316E-03 -3.274 0.5731 -0.242 1.810 0.1980 nontronite-Na 0.1630E-03 -3.788 0.6931E-01 -1.159 0.2190 0.2153E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9634E+00 0.9634E+00 1.0000 -0.016 grossular 0.3665E-01 0.3665E-01 1.0000 -1.436 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6556E+00 0.6556E+00 1.0000 -0.183 daphnite 0.3301E+00 0.3301E+00 1.0000 -0.481 chlorite-Mn 0.1432E-01 0.1432E-01 1.0000 -1.844 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 31.655001 g Volume = 13.159850 cm3 Porosity: -4.4466% V(tot) - V(min): -.56025E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 28.9990000 g log = 1.4624 Original solution: 1000.0103000 g Original solution / Rock added: 34.48 (Water/Rock Ratio), log = 1.5376 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1670E-06 1.0073 0.1769E-06 0.1757E-06 CH4,gas 0.1719E-14 1.0129 0.1832E-14 0.1808E-14 H2,gas 0.3074E-05 1.0006 0.3235E-05 0.3234E-05 H2S,gas 0.3585E-13 0.9959 0.3756E-13 0.3772E-13 S2,gas 0.4799E-35 1.0000 0.5048E-35 0.5048E-35 CO,gas 0.1410E-15 1.0000 0.1483E-15 0.1483E-15 SO3,gas 0.9895E-40 1.0000 0.1041E-39 0.1041E-39 SO2,gas 0.1211E-22 1.0000 0.1274E-22 0.1274E-22 HCl,gas 0.5067E-17 1.0000 0.5330E-17 0.5330E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 209 nontronite-Na 3.58 3.58 0.00 0.000 0.13649E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.12 -8.75 -2.917 0.14944E+05 -6.752 3 CH4,gas 4.81 -11.93 -16.74 -4.184 0.28578E+05 -14.737 4 H2,gas 8.29 0.80 -7.49 -4.280 0.12789E+05 -5.490 5 H2S,gas -5.94 -21.37 -15.43 -7.713 0.26338E+05 -13.425 6 S2,gas -7.03 -44.33 -37.30 -5.738 0.63683E+05 -35.297 7 CO,gas 3.51 -14.32 -17.83 -5.486 0.30442E+05 -15.829 8 SO3,gas 17.43 -24.56 -41.98 -10.496 0.71684E+05 -39.983 9 SO2,gas 1.14 -23.76 -24.89 -6.639 0.42507E+05 -22.895 10 HCl,gas 5.48 -13.79 -19.27 -9.637 0.32909E+05 -17.273 11 acmite 7.74 7.49 -0.24 -0.025 0.41701E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.08 -4.47 -0.224 0.76369E+04 20 analcite 3.37 2.94 -0.43 -0.047 0.72909E+03 21 andalusite 5.06 0.09 -4.97 -0.497 0.84918E+04 26 annite 20.21 17.45 -2.76 -0.153 0.47052E+04 27 phlogopite 27.15 24.41 -2.74 -0.152 0.46780E+04 29 anorthite 12.80 8.95 -3.84 -0.296 0.65627E+04 35 aragonite 0.99 -2.98 -3.96 -1.322 0.67693E+04 36 brucite 12.58 8.95 -3.63 -0.726 0.61988E+04 37 calcite 0.83 -2.98 -3.81 -1.270 0.65080E+04 38 carnegieite-low 9.06 6.22 -2.85 -0.407 0.48644E+04 39 carnegieite-high 10.13 6.22 -3.92 -0.560 0.66913E+04 40 carpholite-Mg 8.65 5.76 -2.89 -0.192 0.49296E+04 41 carpholite-Fe 6.78 3.45 -3.34 -0.222 0.56984E+04 42 celadonite 5.40 3.24 -2.16 -0.127 0.36849E+04 43 celadonite-Fe 3.94 0.92 -3.01 -0.177 0.51433E+04 44 chrysotile 23.94 20.29 -3.64 -0.304 0.62198E+04 50 chloritoid-Mg 13.26 9.04 -4.23 -0.282 0.72157E+04 51 chloritoid-Fe 9.24 6.72 -2.52 -0.168 0.43047E+04 52 chloritoid-Mn 11.46 8.93 -2.53 -0.169 0.43200E+04 54 coesite -2.37 -3.27 -0.90 -0.301 0.15413E+04 61 cristobalite -2.55 -3.27 -0.72 -0.241 0.12341E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.68 -1.22 -0.203 0.20755E+04 67 diopside 16.22 14.54 -1.68 -0.168 0.28621E+04 68 hedenbergite 14.24 12.22 -2.02 -0.202 0.34540E+04 75 epidote 24.78 24.05 -0.73 -0.035 0.12395E+04 76 clinozoisite 22.92 19.50 -3.42 -0.156 0.58420E+04 77 epidote-Fe 29.94 28.60 -1.34 -0.070 0.22846E+04 78 fayalite 14.08 9.98 -4.09 -0.585 0.69904E+04 79 ferrosilite 11.19 6.71 -4.47 -0.447 0.76405E+04 83 gibbsite 4.10 1.68 -2.42 -0.345 0.41267E+04 84 glaucophane 23.11 19.64 -3.47 -0.094 0.59294E+04 85 glaucophane-Fe 17.42 12.68 -4.73 -0.128 0.80805E+04 87 greenalite 16.19 13.34 -2.85 -0.238 0.48710E+04 90 hematite 12.60 12.46 -0.14 -0.017 0.23475E+03 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.94 -1.31 -0.131 0.22321E+04 96 julgoldite 70.57 67.09 -3.48 -0.090 0.59409E+04 97 kalsilite 7.62 4.11 -3.51 -0.501 0.59899E+04 98 kaolinite -1.27 -3.18 -1.91 -0.174 0.32609E+04 99 kyanite 4.93 0.09 -4.84 -0.484 0.82685E+04 101 laumontite 2.97 2.41 -0.56 -0.038 0.96370E+03 102 lawsonite 9.68 8.95 -0.72 -0.048 0.12366E+04 103 leucite 4.17 0.84 -3.33 -0.333 0.56815E+04 105 lizardite 23.29 20.29 -2.99 -0.249 0.51101E+04 107 magnetite 20.13 19.09 -1.04 -0.085 0.17829E+04 108 minnesotaite 10.46 6.80 -3.66 -0.215 0.62549E+04 110 magnesioferrite 26.26 21.41 -4.85 -0.396 0.82828E+04 120 muscovite 2.68 0.93 -1.75 -0.103 0.29879E+04 121 paragonite 4.34 3.03 -1.30 -0.077 0.22264E+04 122 nepheline 8.38 6.22 -2.16 -0.309 0.36924E+04 134 phlogopite-Na 29.73 26.51 -3.22 -0.179 0.54999E+04 136 prehnite 19.47 17.82 -1.65 -0.097 0.28124E+04 137 prehnite-Fe 22.59 22.37 -0.22 -0.013 0.37229E+03 138 pumpellyite-Fe 46.47 43.95 -2.52 -0.056 0.43082E+04 139 pumpellyite-Mg 49.19 46.27 -2.93 -0.065 0.50010E+04 145 pyroxmangite 7.42 5.57 -1.84 -0.369 0.31485E+04 146 pyrophyllite -6.10 -9.73 -3.63 -0.227 0.61962E+04 147 quartz -2.98 -3.27 -0.29 -0.097 0.49517E+03 152 rhodonite 7.46 5.57 -1.89 -0.378 0.32278E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 24.77 -2.83 -0.084 0.48292E+04 171 talc 16.55 13.75 -2.80 -0.165 0.47856E+04 174 tephroite 18.11 14.42 -3.70 -0.528 0.63121E+04 177 topaz-H 4.67 0.09 -4.58 -0.416 0.78176E+04 178 tridymite -2.61 -3.27 -0.66 -0.219 0.11225E+04 187 wairakite 4.06 2.41 -1.65 -0.097 0.28145E+04 188 walstromite 11.53 8.87 -2.66 -0.533 0.45467E+04 189 wollastonite 10.48 8.87 -1.62 -0.323 0.27606E+04 190 pseudo-wollastonite 11.02 8.87 -2.15 -0.431 0.36792E+04 191 zoisite 22.96 19.50 -3.46 -0.157 0.59145E+04 192 akaganeite 7.77 6.23 -1.54 -0.332 0.26255E+04 193 beidellite-Ca -1.56 -6.09 -4.53 -0.280 0.77353E+04 195 beidellite-K -1.44 -6.21 -4.78 -0.292 0.81538E+04 196 beidellite-Mg -1.71 -6.62 -4.91 -0.304 0.83829E+04 197 beidellite-Na -1.26 -5.52 -4.26 -0.261 0.72725E+04 199 chalcedony -2.79 -3.27 -0.48 -0.159 0.81549E+03 201 montmorillonite-Ca -2.21 -5.33 -3.11 -0.193 0.53147E+04 202 montmorillonite-K -2.16 -5.45 -3.29 -0.201 0.56109E+04 203 montmorillonite-Mg -2.40 -5.85 -3.45 -0.214 0.58933E+04 204 montmorillonite-Na -1.96 -4.75 -2.79 -0.171 0.47677E+04 205 nontronite-Ca 3.28 3.01 -0.27 -0.018 0.46198E+03 206 nontronite-H 2.60 1.01 -1.59 -0.107 0.27136E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11212E+04 224 tobermorite 9.84 6.84 -3.00 -0.819 0.51238E+04 233 boehmite 4.43 1.68 -2.75 -0.458 0.46939E+04 235 ferrous-oxide 9.82 6.63 -3.20 -0.799 0.54566E+04 240 silica-amorphous -2.08 -3.27 -1.19 -0.397 0.20357E+04 242 an20ab80 2.08 1.53 -0.55 -0.042 0.94093E+03 243 an25ab75 2.71 1.99 -0.72 -0.055 0.12241E+04 244 an30ab70 3.34 2.46 -0.89 -0.068 0.15156E+04 245 tr.625ac.25prg.125 45.31 41.24 -4.07 -0.110 0.69499E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 28.9990000 g New total amount of reactant added: 29.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2993E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 29.9990000 Water: Moles liquid = 0.5530E+02 kg liquid = 0.9962E+00 Moles total = 0.5513E+02 kg total = 0.9932E+00 Activity = 1.0000 Stoichiometric ionic strength = .5491218E-02 Osmotic coef. = 0.9609 True ionic strength = .9983278E-02 Chg. balance for total moles = 0.2993E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15252E-09 -9.8167 0.13331E-09 -9.8751 0.87402E+00 -0.0585 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13816E-03 -3.8596 0.12034E-03 -3.9196 0.87105E+00 -0.0600 4 SO4-- 0.25582E-04 -4.5921 0.15645E-04 -4.8056 0.61157E+00 -0.2136 5 HCO3- 0.65917E-05 -5.1810 0.57464E-05 -5.2406 0.87176E+00 -0.0596 6 HS- 0.40943E-11 -11.3878 0.35666E-11 -11.4477 0.87112E+00 -0.0599 7 Al+++ 0.32421E-27 -27.4892 0.10884E-27 -27.9632 0.33571E+00 -0.4740 8 H4SiO4 0.54109E-03 -3.2667 0.54109E-03 -3.2667 0.10000E+01 0.0000 9 Ca++ 0.39978E-07 -7.3982 0.24349E-07 -7.6135 0.60905E+00 -0.2153 10 Mg++ 0.26257E-10 -10.5808 0.15951E-10 -10.7972 0.60749E+00 -0.2165 11 Fe++ 0.12389E-12 -12.9070 0.75306E-13 -13.1232 0.60786E+00 -0.2162 12 K+ 0.77723E-04 -4.1095 0.67765E-04 -4.1690 0.87188E+00 -0.0595 13 Na+ 0.98727E-02 -2.0056 0.85988E-02 -2.0656 0.87097E+00 -0.0600 14 Mn++ 0.20731E-10 -10.6834 0.12607E-10 -10.8994 0.60814E+00 -0.2160 15 HPO4-- 0.54905E-06 -6.2604 0.33581E-06 -6.4739 0.61162E+00 -0.2135 16 HSiO3- 0.45465E-02 -2.3423 0.39602E-02 -2.4023 0.87105E+00 -0.0600 17 Ca(HSiO3)+ 0.24776E-08 -8.6060 0.21604E-08 -8.6655 0.87199E+00 -0.0595 18 Mg(HSiO3)+ 0.20199E-11 -11.6947 0.17613E-11 -11.7542 0.87199E+00 -0.0595 19 NaHSiO3,aq 0.54085E-03 -3.2669 0.54085E-03 -3.2669 0.10000E+01 0.0000 20 AlO+ 0.90676E-15 -15.0425 0.79068E-15 -15.1020 0.87199E+00 -0.0595 22 HAlO2,aq 0.11869E-08 -8.9256 0.11869E-08 -8.9256 0.10000E+01 0.0000 23 AlO2- 0.22847E-04 -4.6412 0.19881E-04 -4.7016 0.87016E+00 -0.0604 24 CH4,aq 0.12876E-17 -17.8902 0.12855E-17 -17.8909 0.99831E+00 -0.0007 29 CO,aq 0.96332E-19 -19.0162 0.96332E-19 -19.0162 0.10000E+01 0.0000 30 CO2,aq 0.15471E-08 -8.8105 0.15445E-08 -8.8112 0.99831E+00 -0.0007 31 CO3-2 0.65249E-05 -5.1854 0.39856E-05 -5.3995 0.61083E+00 -0.2141 32 CaCO3,aq 0.11886E-08 -8.9250 0.11886E-08 -8.9250 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40431E-11 -11.3933 0.35255E-11 -11.4528 0.87199E+00 -0.0595 34 CaCl+ 0.53546E-11 -11.2713 0.46691E-11 -11.3308 0.87199E+00 -0.0595 35 CaCl2,aq 0.13083E-15 -15.8833 0.13083E-15 -15.8833 0.10000E+01 0.0000 36 CaOH+ 0.14770E-07 -7.8306 0.12879E-07 -7.8901 0.87199E+00 -0.0595 37 CaSO4,aq 0.11869E-09 -9.9256 0.11869E-09 -9.9256 0.10000E+01 0.0000 38 HCl,aq 0.30175E-14 -14.5204 0.30175E-14 -14.5204 0.10000E+01 0.0000 43 FeCl+ 0.16187E-16 -16.7908 0.14115E-16 -16.8503 0.87199E+00 -0.0595 46 FeO,aq 0.16757E-09 -9.7758 0.16757E-09 -9.7758 0.10000E+01 0.0000 47 FeOH+ 0.21477E-10 -10.6680 0.18728E-10 -10.7275 0.87199E+00 -0.0595 48 HFeO2- 0.15523E-07 -7.8090 0.13521E-07 -7.8690 0.87105E+00 -0.0600 49 FeO+ 0.10621E-14 -14.9738 0.92612E-15 -15.0333 0.87199E+00 -0.0595 51 FeO2- 0.11759E-07 -7.9296 0.10243E-07 -7.9896 0.87105E+00 -0.0600 52 HFeO2,aq 0.17088E-09 -9.7673 0.17088E-09 -9.7673 0.10000E+01 0.0000 53 H2,aq 0.24258E-08 -8.6151 0.24217E-08 -8.6159 0.99831E+00 -0.0007 54 KCl,aq 0.14440E-09 -9.8404 0.14440E-09 -9.8404 0.10000E+01 0.0000 55 KHSO4,aq 0.37820E-18 -18.4223 0.37820E-18 -18.4223 0.10000E+01 0.0000 56 KOH,aq 0.22161E-06 -6.6544 0.22161E-06 -6.6544 0.10000E+01 0.0000 57 KSO4- 0.18752E-07 -7.7270 0.16334E-07 -7.7869 0.87105E+00 -0.0600 58 MgCO3,aq 0.19456E-12 -12.7109 0.19456E-12 -12.7109 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27008E-14 -14.5685 0.23551E-14 -14.6280 0.87199E+00 -0.0595 60 MgCl+ 0.31844E-14 -14.4970 0.27768E-14 -14.5565 0.87199E+00 -0.0595 61 MgOH+ 0.53604E-10 -10.2708 0.46742E-10 -10.3303 0.87199E+00 -0.0595 63 MnO,aq 0.74892E-09 -9.1256 0.74892E-09 -9.1256 0.10000E+01 0.0000 64 MnOH+ 0.33403E-09 -9.4762 0.29127E-09 -9.5357 0.87199E+00 -0.0595 65 MnO2-2 0.23860E-11 -11.6223 0.14575E-11 -11.8364 0.61083E+00 -0.2141 66 HMnO2- 0.48328E-10 -10.3158 0.42096E-10 -10.3758 0.87105E+00 -0.0600 69 MnCl+ 0.10531E-13 -13.9776 0.91825E-14 -14.0370 0.87199E+00 -0.0595 70 MnSO4,aq 0.55899E-13 -13.2526 0.55899E-13 -13.2526 0.10000E+01 0.0000 71 NaCl,aq 0.33789E-06 -6.4712 0.33789E-06 -6.4712 0.10000E+01 0.0000 72 NaOH,aq 0.28344E-04 -4.5475 0.28344E-04 -4.5475 0.10000E+01 0.0000 74 OH- 0.51711E-02 -2.2864 0.44996E-02 -2.3468 0.87016E+00 -0.0604 79 HPO3-2 0.42051E-17 -17.3762 0.25686E-17 -17.5903 0.61083E+00 -0.2141 82 H3PO4,aq 0.38419E-16 -16.4155 0.38419E-16 -16.4155 0.10000E+01 0.0000 83 H2PO4- 0.90055E-09 -9.0455 0.78483E-09 -9.1052 0.87151E+00 -0.0597 84 PO4-3 0.63741E-08 -8.1956 0.21999E-08 -8.6576 0.34513E+00 -0.4620 87 H2P2O7-2 0.78922E-19 -19.1028 0.48208E-19 -19.3169 0.61083E+00 -0.2141 88 HP2O7-3 0.22079E-15 -15.6560 0.74154E-16 -16.1299 0.33587E+00 -0.4738 89 P2O7-4 0.92755E-15 -15.0327 0.13723E-15 -15.8625 0.14795E+00 -0.8299 90 H2S,aq 0.14309E-14 -14.8444 0.14285E-14 -14.8451 0.99831E+00 -0.0007 97 SO3-2 0.83888E-14 -14.0763 0.51659E-14 -14.2868 0.61582E+00 -0.2105 98 HSO3- 0.46268E-16 -16.3347 0.40301E-16 -16.3947 0.87105E+00 -0.0600 99 HSO4- 0.22180E-11 -11.6540 0.19351E-11 -11.7133 0.87246E+00 -0.0593 Charge balance for all species = 0.2989E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1525224E-09 -.1038503E-01 -.1045929E+02 0.0000 2 H2O 0.1000000E+01 0.5550841E+02 0.9992181E+06 0.0000 3 Cl- 0.1381570E-03 0.1384951E-03 0.4906224E+01 5.9556 4 SO4-- 0.2558188E-04 0.2560164E-04 0.2457410E+01 14.9447 5 HCO3- 0.6591731E-05 0.1311934E-04 0.7998792E+00 4.6345 6 HS- 0.4094271E-11 -.8806894E-09 -.2910337E-04 -1.5726 7 Al+++ 0.3242091E-27 0.2284830E-04 0.6159990E+00 1.6622 8 H4SiO4 0.5410931E-03 0.5628466E-02 0.5405589E+03 -3.2667 9 Ca++ 0.3997761E-07 0.5854177E-07 0.2344401E-02 12.1368 10 Mg++ 0.2625659E-10 0.8208060E-10 0.1993982E-05 8.9531 11 Fe++ 0.1238872E-12 0.2764165E-07 0.1542495E-02 6.6271 12 K+ 0.7772280E-04 0.7796330E-04 0.3046136E+01 5.7062 13 Na+ 0.9872742E-02 0.1044227E-01 0.2398779E+03 7.8096 14 Mn++ 0.2073109E-10 0.1154462E-08 0.6337421E-04 8.8509 15 HPO4-- 0.5490521E-06 0.5563268E-06 0.5335391E-01 13.2764 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4967259E+00 -.1034597E-01 -.4863799E+00 0.0000000E+00 2 H2O 0.5513220E+02 0.5529963E+02 -.1674320E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8568790E-03 0.2550535E-04 0.8313737E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8313746E-03 -.8773770E-09 -.8313737E-03 0.0000000E+00 7 Al+++ 0.9781899E-01 0.2276236E-04 0.9779623E-01 0.0000000E+00 8 H4SiO4 0.3123731E+00 0.5607296E-02 0.3067658E+00 0.0000000E+00 9 Ca++ 0.3451760E-01 0.5832158E-07 0.3451754E-01 0.0000000E+00 10 Mg++ 0.2380873E-01 0.8177188E-10 0.2380873E-01 0.0000000E+00 11 Fe++ 0.2138954E-01 0.2753769E-07 0.2138952E-01 0.0000000E+00 12 K+ 0.6369214E-02 0.7767007E-04 0.6291544E-02 0.0000000E+00 13 Na+ 0.3781612E-01 0.1040300E-01 0.2741313E-01 0.0000000E+00 14 Mn++ 0.5201405E-03 0.1150120E-08 0.5201394E-03 0.0000000E+00 15 HPO4-- 0.1775214E-03 0.5542344E-06 0.1769671E-03 0.0000000E+00 Chg. balance for solid moles: -.2456E-16 Mass of aqueous solution: 0.997019E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 29.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2737E-01 -1.563 7.178 0.856 21.92 2.755 andradite 0.3201E-02 -2.495 1.627 0.211 4.968 0.4227 grossular 0.1187E-03 -3.926 0.5346E-01 -1.272 0.1632 0.1487E-01 apatite-OH 0.5899E-04 -4.229 0.2963E-01 -1.528 0.9048E-01 0.9416E-02 clinochlore 0.4762E-02 -2.322 2.647 0.423 8.082 1.007 daphnite 0.2353E-02 -2.628 1.679 0.225 5.126 0.5087 chlorite-Mn 0.1040E-03 -3.983 0.7375E-01 -1.132 0.2252 0.2350E-01 microcline 0.5994E-02 -2.222 1.668 0.222 5.095 0.6517 stilbite 0.2426E-01 -1.615 17.10 1.233 52.21 7.975 stilpnomelane-Fe 0.5949E-03 -3.226 0.6413 -0.193 1.958 0.2215 nontronite-Na 0.1241E-03 -3.906 0.5277E-01 -1.278 0.1611 0.1639E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9643E+00 0.9643E+00 1.0000 -0.016 grossular 0.3574E-01 0.3574E-01 1.0000 -1.447 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6597E+00 0.6597E+00 1.0000 -0.181 daphnite 0.3259E+00 0.3259E+00 1.0000 -0.487 chlorite-Mn 0.1441E-01 0.1441E-01 1.0000 -1.841 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 32.747354 g Volume = 13.605731 cm3 Porosity: -4.6627% V(tot) - V(min): -.60613E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 29.9990000 g log = 1.4771 Original solution: 1000.0103000 g Original solution / Rock added: 33.33 (Water/Rock Ratio), log = 1.5229 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1668E-06 1.0073 0.1768E-06 0.1755E-06 CH4,gas 0.1908E-14 1.0129 0.2033E-14 0.2007E-14 H2,gas 0.3156E-05 1.0006 0.3322E-05 0.3320E-05 H2S,gas 0.3977E-13 0.9959 0.4166E-13 0.4183E-13 S2,gas 0.5602E-35 1.0000 0.5893E-35 0.5893E-35 CO,gas 0.1446E-15 1.0000 0.1521E-15 0.1521E-15 SO3,gas 0.9881E-40 1.0000 0.1039E-39 0.1039E-39 SO2,gas 0.1242E-22 1.0000 0.1306E-22 0.1306E-22 HCl,gas 0.5065E-17 1.0000 0.5328E-17 0.5328E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 0.37914E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.12 -8.75 -2.918 0.14945E+05 -6.753 3 CH4,gas 4.81 -11.88 -16.69 -4.173 0.28501E+05 -14.692 4 H2,gas 8.29 0.81 -7.48 -4.274 0.12770E+05 -5.479 5 H2S,gas -5.94 -21.32 -15.38 -7.690 0.26261E+05 -13.380 6 S2,gas -7.03 -44.26 -37.23 -5.728 0.63569E+05 -35.230 7 CO,gas 3.51 -14.31 -17.82 -5.482 0.30423E+05 -15.818 8 SO3,gas 17.43 -24.56 -41.98 -10.496 0.71685E+05 -39.983 9 SO2,gas 1.14 -23.75 -24.88 -6.636 0.42489E+05 -22.884 10 HCl,gas 5.48 -13.79 -19.27 -9.637 0.32909E+05 -17.273 11 acmite 7.74 7.50 -0.24 -0.025 0.40682E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.08 -4.47 -0.224 0.76373E+04 20 analcite 3.37 2.94 -0.43 -0.048 0.73809E+03 26 annite 20.21 17.45 -2.76 -0.153 0.47122E+04 27 phlogopite 27.15 24.43 -2.72 -0.151 0.46429E+04 29 anorthite 12.80 8.93 -3.87 -0.298 0.66077E+04 35 aragonite 0.99 -2.98 -3.97 -1.322 0.67705E+04 36 brucite 12.58 8.95 -3.62 -0.725 0.61871E+04 37 calcite 0.83 -2.98 -3.81 -1.271 0.65091E+04 38 carnegieite-low 9.06 6.21 -2.86 -0.408 0.48824E+04 39 carnegieite-high 10.13 6.21 -3.93 -0.561 0.67093E+04 40 carpholite-Mg 8.65 5.74 -2.91 -0.194 0.49624E+04 41 carpholite-Fe 6.78 3.42 -3.36 -0.224 0.57452E+04 42 celadonite 5.40 3.25 -2.15 -0.126 0.36642E+04 43 celadonite-Fe 3.94 0.93 -3.01 -0.177 0.51367E+04 44 chrysotile 23.94 20.33 -3.61 -0.301 0.61667E+04 50 chloritoid-Mg 13.26 9.01 -4.25 -0.283 0.72575E+04 51 chloritoid-Fe 9.24 6.68 -2.55 -0.170 0.43606E+04 52 chloritoid-Mn 11.46 8.91 -2.55 -0.170 0.43618E+04 54 coesite -2.37 -3.27 -0.90 -0.299 0.15322E+04 61 cristobalite -2.55 -3.27 -0.72 -0.239 0.12251E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.66 -1.23 -0.206 0.21068E+04 67 diopside 16.22 14.56 -1.66 -0.166 0.28328E+04 68 hedenbergite 14.24 12.23 -2.01 -0.201 0.34388E+04 75 epidote 24.78 24.02 -0.75 -0.037 0.12881E+04 76 clinozoisite 22.92 19.46 -3.46 -0.157 0.59097E+04 77 epidote-Fe 29.94 28.58 -1.36 -0.070 0.23139E+04 78 fayalite 14.08 9.99 -4.09 -0.584 0.69860E+04 79 ferrosilite 11.19 6.72 -4.47 -0.447 0.76271E+04 83 gibbsite 4.10 1.66 -2.44 -0.348 0.41580E+04 84 glaucophane 23.11 19.67 -3.44 -0.093 0.58763E+04 85 glaucophane-Fe 17.42 12.69 -4.73 -0.128 0.80695E+04 87 greenalite 16.19 13.35 -2.85 -0.237 0.48600E+04 90 hematite 12.60 12.45 -0.15 -0.018 0.25887E+03 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.94 -1.31 -0.131 0.22411E+04 96 julgoldite 70.57 67.09 -3.48 -0.090 0.59418E+04 97 kalsilite 7.62 4.10 -3.52 -0.503 0.60079E+04 98 kaolinite -1.27 -3.21 -1.94 -0.176 0.33054E+04 99 kyanite 4.93 0.06 -4.87 -0.487 0.83220E+04 101 laumontite 2.97 2.39 -0.58 -0.039 0.99070E+03 102 lawsonite 9.68 8.93 -0.75 -0.050 0.12816E+04 103 leucite 4.17 0.83 -3.33 -0.333 0.56905E+04 105 lizardite 23.29 20.33 -2.96 -0.247 0.50570E+04 107 magnetite 20.13 19.07 -1.06 -0.087 0.18093E+04 108 minnesotaite 10.46 6.81 -3.65 -0.214 0.62259E+04 110 magnesioferrite 26.26 21.40 -4.86 -0.397 0.82952E+04 120 muscovite 2.68 0.89 -1.79 -0.105 0.30504E+04 121 paragonite 4.34 3.00 -1.34 -0.079 0.22889E+04 122 nepheline 8.38 6.21 -2.17 -0.310 0.37104E+04 134 phlogopite-Na 29.73 26.53 -3.20 -0.178 0.54648E+04 136 prehnite 19.47 17.80 -1.67 -0.098 0.28489E+04 137 prehnite-Fe 22.59 22.36 -0.23 -0.014 0.38960E+03 138 pumpellyite-Fe 46.47 43.88 -2.59 -0.057 0.44148E+04 139 pumpellyite-Mg 49.19 46.21 -2.98 -0.066 0.50935E+04 145 pyroxmangite 7.42 5.58 -1.83 -0.366 0.31278E+04 146 pyrophyllite -6.10 -9.74 -3.64 -0.228 0.62227E+04 147 quartz -2.98 -3.27 -0.28 -0.095 0.48617E+03 152 rhodonite 7.46 5.58 -1.88 -0.376 0.32070E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 24.81 -2.79 -0.083 0.47591E+04 171 talc 16.55 13.79 -2.76 -0.162 0.47145E+04 174 tephroite 18.11 14.44 -3.68 -0.525 0.62797E+04 177 topaz-H 4.67 0.06 -4.61 -0.419 0.78711E+04 178 tridymite -2.61 -3.27 -0.65 -0.217 0.11135E+04 187 wairakite 4.06 2.39 -1.66 -0.098 0.28415E+04 188 walstromite 11.53 8.87 -2.66 -0.532 0.45382E+04 189 wollastonite 10.48 8.87 -1.61 -0.322 0.27521E+04 190 pseudo-wollastonite 11.02 8.87 -2.15 -0.430 0.36707E+04 191 zoisite 22.96 19.46 -3.50 -0.159 0.59823E+04 192 akaganeite 7.77 6.22 -1.54 -0.334 0.26376E+04 193 beidellite-Ca -1.56 -6.11 -4.55 -0.282 0.77752E+04 195 beidellite-K -1.44 -6.23 -4.80 -0.294 0.81922E+04 196 beidellite-Mg -1.71 -6.64 -4.93 -0.305 0.84208E+04 197 beidellite-Na -1.26 -5.54 -4.28 -0.262 0.73109E+04 199 chalcedony -2.79 -3.27 -0.47 -0.157 0.80648E+03 201 montmorillonite-Ca -2.21 -5.33 -3.12 -0.193 0.53271E+04 202 montmorillonite-K -2.16 -5.45 -3.29 -0.202 0.56218E+04 203 montmorillonite-Mg -2.40 -5.86 -3.46 -0.214 0.59037E+04 204 montmorillonite-Na -1.96 -4.76 -2.80 -0.171 0.47787E+04 205 nontronite-Ca 3.28 3.01 -0.27 -0.018 0.46347E+03 206 nontronite-H 2.60 1.01 -1.59 -0.107 0.27150E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11207E+04 224 tobermorite 9.84 6.84 -3.00 -0.817 0.51153E+04 233 boehmite 4.43 1.66 -2.77 -0.461 0.47252E+04 235 ferrous-oxide 9.82 6.63 -3.20 -0.799 0.54590E+04 240 silica-amorphous -2.08 -3.27 -1.19 -0.396 0.20267E+04 242 an20ab80 2.08 1.52 -0.56 -0.043 0.94994E+03 243 an25ab75 2.71 1.99 -0.72 -0.056 0.12353E+04 244 an30ab70 3.34 2.45 -0.90 -0.069 0.15291E+04 245 tr.625ac.25prg.125 45.31 41.29 -4.01 -0.108 0.68528E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 29.9990000 g New total amount of reactant added: 30.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2995E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 30.9990000 Water: Moles liquid = 0.5529E+02 kg liquid = 0.9961E+00 Moles total = 0.5512E+02 kg total = 0.9930E+00 Activity = 1.0000 Stoichiometric ionic strength = .5520488E-02 Osmotic coef. = 0.9608 True ionic strength = .1004032E-01 Chg. balance for total moles = 0.2995E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15255E-09 -9.8166 0.13329E-09 -9.8752 0.87377E+00 -0.0586 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13817E-03 -3.8596 0.12032E-03 -3.9197 0.87079E+00 -0.0601 4 SO4-- 0.25585E-04 -4.5920 0.15628E-04 -4.8061 0.61085E+00 -0.2141 5 HCO3- 0.65891E-05 -5.1812 0.57425E-05 -5.2409 0.87150E+00 -0.0597 6 HS- 0.45282E-11 -11.3441 0.39434E-11 -11.4041 0.87086E+00 -0.0601 7 Al+++ 0.31197E-27 -27.5059 0.10445E-27 -27.9811 0.33482E+00 -0.4752 8 H4SiO4 0.54749E-03 -3.2616 0.54749E-03 -3.2616 0.10000E+01 0.0000 9 Ca++ 0.39989E-07 -7.3981 0.24326E-07 -7.6139 0.60833E+00 -0.2159 10 Mg++ 0.26683E-10 -10.5738 0.16190E-10 -10.7908 0.60676E+00 -0.2170 11 Fe++ 0.12363E-12 -12.9079 0.75059E-13 -13.1246 0.60713E+00 -0.2167 12 K+ 0.78168E-04 -4.1070 0.68133E-04 -4.1666 0.87163E+00 -0.0597 13 Na+ 0.99293E-02 -2.0031 0.86455E-02 -2.0632 0.87071E+00 -0.0601 14 Mn++ 0.21068E-10 -10.6764 0.12797E-10 -10.8929 0.60742E+00 -0.2165 15 HPO4-- 0.55044E-06 -6.2593 0.33627E-06 -6.4733 0.61090E+00 -0.2140 16 HSiO3- 0.46022E-02 -2.3370 0.40075E-02 -2.3971 0.87079E+00 -0.0601 17 Ca(HSiO3)+ 0.25056E-08 -8.6011 0.21842E-08 -8.6607 0.87173E+00 -0.0596 18 Mg(HSiO3)+ 0.20754E-11 -11.6829 0.18092E-11 -11.7425 0.87173E+00 -0.0596 19 NaHSiO3,aq 0.55028E-03 -3.2594 0.55028E-03 -3.2594 0.10000E+01 0.0000 20 AlO+ 0.87067E-15 -15.0601 0.75899E-15 -15.1198 0.87173E+00 -0.0596 22 HAlO2,aq 0.11395E-08 -8.9433 0.11395E-08 -8.9433 0.10000E+01 0.0000 23 AlO2- 0.21944E-04 -4.6587 0.19089E-04 -4.7192 0.86989E+00 -0.0605 24 CH4,aq 0.14242E-17 -17.8464 0.14218E-17 -17.8472 0.99830E+00 -0.0007 29 CO,aq 0.98731E-19 -19.0055 0.98731E-19 -19.0055 0.10000E+01 0.0000 30 CO2,aq 0.15459E-08 -8.8108 0.15432E-08 -8.8116 0.99830E+00 -0.0007 31 CO3-2 0.65289E-05 -5.1852 0.39834E-05 -5.3997 0.61012E+00 -0.2146 32 CaCO3,aq 0.11868E-08 -8.9256 0.11868E-08 -8.9256 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40378E-11 -11.3939 0.35198E-11 -11.4535 0.87173E+00 -0.0596 34 CaCl+ 0.53502E-11 -11.2716 0.46639E-11 -11.3312 0.87173E+00 -0.0596 35 CaCl2,aq 0.13066E-15 -15.8839 0.13066E-15 -15.8839 0.10000E+01 0.0000 36 CaOH+ 0.14763E-07 -7.8308 0.12869E-07 -7.8905 0.87173E+00 -0.0596 37 CaSO4,aq 0.11846E-09 -9.9264 0.11846E-09 -9.9264 0.10000E+01 0.0000 38 HCl,aq 0.30165E-14 -14.5205 0.30165E-14 -14.5205 0.10000E+01 0.0000 43 FeCl+ 0.16135E-16 -16.7922 0.14066E-16 -16.8518 0.87173E+00 -0.0596 46 FeO,aq 0.16707E-09 -9.7771 0.16707E-09 -9.7771 0.10000E+01 0.0000 47 FeOH+ 0.21416E-10 -10.6693 0.18669E-10 -10.7289 0.87173E+00 -0.0596 48 HFeO2- 0.15482E-07 -7.8102 0.13482E-07 -7.8703 0.87079E+00 -0.0601 49 FeO+ 0.10457E-14 -14.9806 0.91154E-15 -15.0402 0.87173E+00 -0.0596 51 FeO2- 0.11580E-07 -7.9363 0.10084E-07 -7.9964 0.87079E+00 -0.0601 52 HFeO2,aq 0.16821E-09 -9.7741 0.16821E-09 -9.7741 0.10000E+01 0.0000 53 H2,aq 0.24882E-08 -8.6041 0.24840E-08 -8.6048 0.99830E+00 -0.0007 54 KCl,aq 0.14515E-09 -9.8382 0.14515E-09 -9.8382 0.10000E+01 0.0000 55 KHSO4,aq 0.37980E-18 -18.4204 0.37980E-18 -18.4204 0.10000E+01 0.0000 56 KOH,aq 0.22284E-06 -6.6520 0.22284E-06 -6.6520 0.10000E+01 0.0000 57 KSO4- 0.18839E-07 -7.7249 0.16405E-07 -7.7850 0.87079E+00 -0.0601 58 MgCO3,aq 0.19737E-12 -12.7047 0.19737E-12 -12.7047 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27403E-14 -14.5622 0.23888E-14 -14.6218 0.87173E+00 -0.0596 60 MgCl+ 0.32325E-14 -14.4905 0.28179E-14 -14.5501 0.87173E+00 -0.0596 61 MgOH+ 0.54432E-10 -10.2641 0.47450E-10 -10.3238 0.87173E+00 -0.0596 63 MnO,aq 0.76036E-09 -9.1190 0.76036E-09 -9.1190 0.10000E+01 0.0000 64 MnOH+ 0.33919E-09 -9.4696 0.29568E-09 -9.5292 0.87173E+00 -0.0596 65 MnO2-2 0.24259E-11 -11.6151 0.14801E-11 -11.8297 0.61012E+00 -0.2146 66 HMnO2- 0.49087E-10 -10.3090 0.42744E-10 -10.3691 0.87079E+00 -0.0601 69 MnCl+ 0.10690E-13 -13.9710 0.93185E-14 -14.0307 0.87173E+00 -0.0596 70 MnSO4,aq 0.56679E-13 -13.2466 0.56679E-13 -13.2466 0.10000E+01 0.0000 71 NaCl,aq 0.33965E-06 -6.4690 0.33965E-06 -6.4690 0.10000E+01 0.0000 72 NaOH,aq 0.28501E-04 -4.5451 0.28501E-04 -4.5451 0.10000E+01 0.0000 74 OH- 0.51733E-02 -2.2862 0.45002E-02 -2.3468 0.86989E+00 -0.0605 79 HPO3-2 0.43243E-17 -17.3641 0.26383E-17 -17.5787 0.61012E+00 -0.2146 82 H3PO4,aq 0.38462E-16 -16.4150 0.38462E-16 -16.4150 0.10000E+01 0.0000 83 H2PO4- 0.90192E-09 -9.0448 0.78580E-09 -9.1047 0.87125E+00 -0.0599 84 PO4-3 0.63998E-08 -8.1938 0.22032E-08 -8.6569 0.34426E+00 -0.4631 87 H2P2O7-2 0.79210E-19 -19.1012 0.48327E-19 -19.3158 0.61012E+00 -0.2146 88 HP2O7-3 0.22195E-15 -15.6537 0.74347E-16 -16.1287 0.33497E+00 -0.4750 89 P2O7-4 0.93442E-15 -15.0295 0.13760E-15 -15.8614 0.14726E+00 -0.8319 90 H2S,aq 0.15820E-14 -14.8008 0.15793E-14 -14.8015 0.99830E+00 -0.0007 97 SO3-2 0.86053E-14 -14.0652 0.52933E-14 -14.2763 0.61512E+00 -0.2110 98 HSO3- 0.47416E-16 -16.3241 0.41289E-16 -16.3842 0.87079E+00 -0.0601 99 HSO4- 0.22160E-11 -11.6544 0.19328E-11 -11.7138 0.87220E+00 -0.0594 Charge balance for all species = 0.2988E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1525463E-09 -.1044892E-01 -.1052357E+02 0.0000 2 H2O 0.1000000E+01 0.5550834E+02 0.9992098E+06 0.0000 3 Cl- 0.1381702E-03 0.1385100E-03 0.4906719E+01 5.9555 4 SO4-- 0.2558456E-04 0.2560436E-04 0.2457654E+01 14.9443 5 HCO3- 0.6589149E-05 0.1312076E-04 0.7999599E+00 4.6343 6 HS- 0.4528233E-11 -.8419712E-09 -.2782368E-04 -1.5289 7 Al+++ 0.3119658E-27 0.2194472E-04 0.5916339E+00 1.6445 8 H4SiO4 0.5474866E-03 0.5699973E-02 0.5474226E+03 -3.2616 9 Ca++ 0.3998851E-07 0.5857139E-07 0.2345570E-02 12.1365 10 Mg++ 0.2668294E-10 0.8339318E-10 0.2025854E-05 8.9597 11 Fe++ 0.1236284E-12 0.2741924E-07 0.1530073E-02 6.6258 12 K+ 0.7816790E-04 0.7840972E-04 0.3063556E+01 5.7086 13 Na+ 0.9929332E-02 0.1050845E-01 0.2413965E+03 7.8120 14 Mn++ 0.2106761E-10 0.1172197E-08 0.6434730E-04 8.8575 15 HPO4-- 0.5504411E-06 0.5577429E-06 0.5348933E-01 13.2771 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5132844E+00 -.1040849E-01 -.5028759E+00 0.0000000E+00 2 H2O 0.5511967E+02 0.5529360E+02 -.1739321E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8845924E-03 0.2550531E-04 0.8590871E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8590880E-03 -.8387139E-09 -.8590871E-03 0.0000000E+00 7 Al+++ 0.1010797E+00 0.2185982E-04 0.1010579E+00 0.0000000E+00 8 H4SiO4 0.3227859E+00 0.5677921E-02 0.3171079E+00 0.0000000E+00 9 Ca++ 0.3566774E-01 0.5834479E-07 0.3566768E-01 0.0000000E+00 10 Mg++ 0.2460238E-01 0.8307055E-10 0.2460238E-01 0.0000000E+00 11 Fe++ 0.2210255E-01 0.2731317E-07 0.2210253E-01 0.0000000E+00 12 K+ 0.6581529E-02 0.7810638E-04 0.6503422E-02 0.0000000E+00 13 Na+ 0.3907137E-01 0.1046780E-01 0.2860357E-01 0.0000000E+00 14 Mn++ 0.5374791E-03 0.1167662E-08 0.5374780E-03 0.0000000E+00 15 HPO4-- 0.1834390E-03 0.5555851E-06 0.1828834E-03 0.0000000E+00 Chg. balance for solid moles: -.2656E-17 Mass of aqueous solution: 0.996918E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 30.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2858E-01 -1.544 7.493 0.875 22.14 2.876 andradite 0.3351E-02 -2.475 1.703 0.231 5.033 0.4425 grossular 0.1212E-03 -3.917 0.5458E-01 -1.263 0.1613 0.1519E-01 apatite-OH 0.6096E-04 -4.215 0.3062E-01 -1.514 0.9049E-01 0.9731E-02 clinochlore 0.4920E-02 -2.308 2.735 0.437 8.082 1.040 daphnite 0.2387E-02 -2.622 1.703 0.231 5.034 0.5162 chlorite-Mn 0.1075E-03 -3.969 0.7621E-01 -1.118 0.2252 0.2429E-01 microcline 0.6174E-02 -2.209 1.719 0.235 5.078 0.6713 stilbite 0.2494E-01 -1.603 17.58 1.245 51.95 8.199 stilpnomelane-Fe 0.6586E-03 -3.181 0.7099 -0.149 2.098 0.2452 nontronite-Na 0.8488E-04 -4.071 0.3609E-01 -1.443 0.1067 0.1121E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9651E+00 0.9651E+00 1.0000 -0.015 grossular 0.3489E-01 0.3489E-01 1.0000 -1.457 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6635E+00 0.6635E+00 1.0000 -0.178 daphnite 0.3220E+00 0.3220E+00 1.0000 -0.492 chlorite-Mn 0.1450E-01 0.1450E-01 1.0000 -1.839 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 33.839779 g Volume = 14.051605 cm3 Porosity: -4.8659% V(tot) - V(min): -.65200E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 30.9990000 g log = 1.4913 Original solution: 1000.0103000 g Original solution / Rock added: 32.26 (Water/Rock Ratio), log = 1.5087 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1667E-06 1.0073 0.1767E-06 0.1754E-06 CH4,gas 0.2110E-14 1.0129 0.2248E-14 0.2220E-14 H2,gas 0.3237E-05 1.0006 0.3407E-05 0.3405E-05 H2S,gas 0.4397E-13 0.9959 0.4606E-13 0.4625E-13 S2,gas 0.6508E-35 1.0000 0.6846E-35 0.6846E-35 CO,gas 0.1482E-15 1.0000 0.1559E-15 0.1559E-15 SO3,gas 0.9868E-40 1.0000 0.1038E-39 0.1038E-39 SO2,gas 0.1272E-22 1.0000 0.1338E-22 0.1338E-22 HCl,gas 0.5063E-17 1.0000 0.5326E-17 0.5326E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.16682E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.12 -8.75 -2.918 0.14945E+05 -6.753 3 CH4,gas 4.81 -11.84 -16.65 -4.162 0.28426E+05 -14.648 4 H2,gas 8.29 0.82 -7.47 -4.267 0.12751E+05 -5.468 5 H2S,gas -5.94 -21.28 -15.34 -7.668 0.26187E+05 -13.337 6 S2,gas -7.03 -44.20 -37.16 -5.718 0.63458E+05 -35.165 7 CO,gas 3.51 -14.30 -17.81 -5.479 0.30405E+05 -15.807 8 SO3,gas 17.43 -24.56 -41.98 -10.496 0.71686E+05 -39.984 9 SO2,gas 1.14 -23.74 -24.87 -6.633 0.42471E+05 -22.874 10 HCl,gas 5.48 -13.79 -19.27 -9.637 0.32909E+05 -17.274 11 acmite 7.74 7.50 -0.23 -0.024 0.39696E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.08 -4.47 -0.224 0.76379E+04 20 analcite 3.37 2.93 -0.44 -0.049 0.74680E+03 26 annite 20.21 17.45 -2.76 -0.154 0.47189E+04 27 phlogopite 27.15 24.45 -2.70 -0.150 0.46092E+04 29 anorthite 12.80 8.90 -3.90 -0.300 0.66513E+04 35 aragonite 0.99 -2.98 -3.97 -1.322 0.67716E+04 36 brucite 12.58 8.96 -3.62 -0.723 0.61758E+04 37 calcite 0.83 -2.98 -3.81 -1.271 0.65102E+04 38 carnegieite-low 9.06 6.19 -2.87 -0.410 0.48999E+04 39 carnegieite-high 10.13 6.19 -3.94 -0.563 0.67267E+04 40 carpholite-Mg 8.65 5.73 -2.92 -0.195 0.49942E+04 41 carpholite-Fe 6.78 3.39 -3.39 -0.226 0.57905E+04 42 celadonite 5.40 3.27 -2.13 -0.126 0.36442E+04 43 celadonite-Fe 3.94 0.93 -3.00 -0.177 0.51302E+04 44 chrysotile 23.94 20.36 -3.58 -0.298 0.61155E+04 50 chloritoid-Mg 13.26 8.99 -4.27 -0.285 0.72980E+04 51 chloritoid-Fe 9.24 6.65 -2.59 -0.172 0.44146E+04 52 chloritoid-Mn 11.46 8.88 -2.58 -0.172 0.44023E+04 54 coesite -2.37 -3.26 -0.89 -0.297 0.15235E+04 61 cristobalite -2.55 -3.26 -0.71 -0.237 0.12164E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.64 -1.25 -0.209 0.21370E+04 67 diopside 16.22 14.57 -1.64 -0.164 0.28047E+04 68 hedenbergite 14.24 12.24 -2.01 -0.201 0.34241E+04 75 epidote 24.78 23.99 -0.78 -0.038 0.13351E+04 76 clinozoisite 22.92 19.42 -3.50 -0.159 0.59753E+04 77 epidote-Fe 29.94 28.56 -1.37 -0.071 0.23424E+04 78 fayalite 14.08 9.99 -4.09 -0.584 0.69818E+04 79 ferrosilite 11.19 6.73 -4.46 -0.446 0.76142E+04 83 gibbsite 4.10 1.64 -2.45 -0.350 0.41882E+04 84 glaucophane 23.11 19.70 -3.41 -0.092 0.58251E+04 85 glaucophane-Fe 17.42 12.70 -4.72 -0.128 0.80588E+04 87 greenalite 16.19 13.35 -2.84 -0.237 0.48493E+04 90 hematite 12.60 12.43 -0.17 -0.020 0.28222E+03 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.93 -1.32 -0.132 0.22498E+04 96 julgoldite 70.57 67.09 -3.48 -0.090 0.59427E+04 97 kalsilite 7.62 4.09 -3.53 -0.504 0.60253E+04 98 kaolinite -1.27 -3.23 -1.96 -0.178 0.33485E+04 99 kyanite 4.93 0.03 -4.90 -0.490 0.83738E+04 101 laumontite 2.97 2.38 -0.60 -0.040 0.10168E+04 102 lawsonite 9.68 8.90 -0.78 -0.052 0.13252E+04 103 leucite 4.17 0.83 -3.34 -0.334 0.56992E+04 105 lizardite 23.29 20.36 -2.93 -0.244 0.50058E+04 107 magnetite 20.13 19.06 -1.07 -0.088 0.18349E+04 108 minnesotaite 10.46 6.83 -3.63 -0.214 0.61978E+04 110 magnesioferrite 26.26 21.39 -4.87 -0.397 0.83073E+04 120 muscovite 2.68 0.86 -1.82 -0.107 0.31109E+04 121 paragonite 4.34 2.96 -1.38 -0.081 0.23494E+04 122 nepheline 8.38 6.19 -2.18 -0.312 0.37278E+04 134 phlogopite-Na 29.73 26.55 -3.18 -0.177 0.54311E+04 136 prehnite 19.47 17.78 -1.69 -0.099 0.28843E+04 137 prehnite-Fe 22.59 22.35 -0.24 -0.014 0.40637E+03 138 pumpellyite-Fe 46.47 43.82 -2.65 -0.059 0.45179E+04 139 pumpellyite-Mg 49.19 46.16 -3.04 -0.067 0.51832E+04 145 pyroxmangite 7.42 5.60 -1.82 -0.364 0.31079E+04 146 pyrophyllite -6.10 -9.76 -3.66 -0.229 0.62484E+04 147 quartz -2.98 -3.26 -0.28 -0.093 0.47746E+03 152 rhodonite 7.46 5.60 -1.87 -0.373 0.31871E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 24.85 -2.75 -0.082 0.46916E+04 171 talc 16.55 13.83 -2.72 -0.160 0.46459E+04 174 tephroite 18.11 14.45 -3.66 -0.523 0.62485E+04 177 topaz-H 4.67 0.03 -4.64 -0.422 0.79229E+04 178 tridymite -2.61 -3.26 -0.65 -0.216 0.11047E+04 187 wairakite 4.06 2.38 -1.68 -0.099 0.28676E+04 188 walstromite 11.53 8.87 -2.65 -0.531 0.45300E+04 189 wollastonite 10.48 8.87 -1.61 -0.321 0.27438E+04 190 pseudo-wollastonite 11.02 8.87 -2.14 -0.429 0.36625E+04 191 zoisite 22.96 19.42 -3.54 -0.161 0.60478E+04 192 akaganeite 7.77 6.22 -1.55 -0.335 0.26493E+04 193 beidellite-Ca -1.56 -6.14 -4.58 -0.283 0.78138E+04 195 beidellite-K -1.44 -6.25 -4.82 -0.295 0.82293E+04 196 beidellite-Mg -1.71 -6.66 -4.95 -0.306 0.84574E+04 197 beidellite-Na -1.26 -5.56 -4.30 -0.264 0.73480E+04 199 chalcedony -2.79 -3.26 -0.47 -0.156 0.79777E+03 201 montmorillonite-Ca -2.21 -5.34 -3.13 -0.193 0.53391E+04 202 montmorillonite-K -2.16 -5.46 -3.30 -0.202 0.56324E+04 203 montmorillonite-Mg -2.40 -5.87 -3.46 -0.214 0.59138E+04 204 montmorillonite-Na -1.96 -4.77 -2.80 -0.172 0.47893E+04 205 nontronite-Ca 3.28 3.01 -0.27 -0.018 0.46490E+03 206 nontronite-H 2.60 1.00 -1.59 -0.107 0.27164E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11202E+04 224 tobermorite 9.84 6.85 -2.99 -0.816 0.51070E+04 233 boehmite 4.43 1.64 -2.79 -0.464 0.47554E+04 235 ferrous-oxide 9.82 6.63 -3.20 -0.800 0.54612E+04 240 silica-amorphous -2.08 -3.26 -1.18 -0.394 0.20180E+04 242 an20ab80 2.08 1.52 -0.56 -0.043 0.95865E+03 243 an25ab75 2.71 1.98 -0.73 -0.056 0.12462E+04 244 an30ab70 3.34 2.44 -0.90 -0.069 0.15421E+04 245 tr.625ac.25prg.125 45.31 41.35 -3.96 -0.107 0.67592E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 30.9990000 g New total amount of reactant added: 31.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2994E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 31.9990000 Water: Moles liquid = 0.5529E+02 kg liquid = 0.9960E+00 Moles total = 0.5511E+02 kg total = 0.9928E+00 Activity = 1.0000 Stoichiometric ionic strength = .5549307E-02 Osmotic coef. = 0.9608 True ionic strength = .1009605E-01 Chg. balance for total moles = 0.2994E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15257E-09 -9.8165 0.13328E-09 -9.8752 0.87353E+00 -0.0587 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13818E-03 -3.8595 0.12029E-03 -3.9198 0.87053E+00 -0.0602 4 SO4-- 0.25587E-04 -4.5920 0.15612E-04 -4.8065 0.61016E+00 -0.2146 5 HCO3- 0.65867E-05 -5.1813 0.57387E-05 -5.2412 0.87125E+00 -0.0599 6 HS- 0.49924E-11 -11.3017 0.43464E-11 -11.3619 0.87060E+00 -0.0602 7 Al+++ 0.30057E-27 -27.5220 0.10038E-27 -27.9984 0.33395E+00 -0.4763 8 H4SiO4 0.55375E-03 -3.2567 0.55375E-03 -3.2567 0.10000E+01 0.0000 9 Ca++ 0.40001E-07 -7.3979 0.24305E-07 -7.6143 0.60763E+00 -0.2164 10 Mg++ 0.27101E-10 -10.5670 0.16425E-10 -10.7845 0.60605E+00 -0.2175 11 Fe++ 0.12338E-12 -12.9087 0.74823E-13 -13.1260 0.60642E+00 -0.2172 12 K+ 0.78603E-04 -4.1046 0.68492E-04 -4.1644 0.87138E+00 -0.0598 13 Na+ 0.99846E-02 -2.0007 0.86911E-02 -2.0609 0.87045E+00 -0.0603 14 Mn++ 0.21398E-10 -10.6696 0.12982E-10 -10.8867 0.60671E+00 -0.2170 15 HPO4-- 0.55178E-06 -6.2582 0.33670E-06 -6.4728 0.61021E+00 -0.2145 16 HSiO3- 0.46567E-02 -2.3319 0.40538E-02 -2.3921 0.87053E+00 -0.0602 17 Ca(HSiO3)+ 0.25331E-08 -8.5963 0.22076E-08 -8.6561 0.87148E+00 -0.0597 18 Mg(HSiO3)+ 0.21303E-11 -11.6716 0.18565E-11 -11.7313 0.87148E+00 -0.0597 19 NaHSiO3,aq 0.55957E-03 -3.2521 0.55957E-03 -3.2521 0.10000E+01 0.0000 20 AlO+ 0.83711E-15 -15.0772 0.72953E-15 -15.1370 0.87148E+00 -0.0597 22 HAlO2,aq 0.10954E-08 -8.9604 0.10954E-08 -8.9604 0.10000E+01 0.0000 23 AlO2- 0.21102E-04 -4.6757 0.18351E-04 -4.7363 0.86964E+00 -0.0607 24 CH4,aq 0.15704E-17 -17.8040 0.15677E-17 -17.8047 0.99829E+00 -0.0007 29 CO,aq 0.10111E-18 -18.9952 0.10111E-18 -18.9952 0.10000E+01 0.0000 30 CO2,aq 0.15447E-08 -8.8112 0.15421E-08 -8.8119 0.99829E+00 -0.0007 31 CO3-2 0.65327E-05 -5.1849 0.39812E-05 -5.4000 0.60942E+00 -0.2151 32 CaCO3,aq 0.11851E-08 -8.9262 0.11851E-08 -8.9262 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40328E-11 -11.3944 0.35145E-11 -11.4541 0.87148E+00 -0.0597 34 CaCl+ 0.53461E-11 -11.2720 0.46590E-11 -11.3317 0.87148E+00 -0.0597 35 CaCl2,aq 0.13049E-15 -15.8844 0.13049E-15 -15.8844 0.10000E+01 0.0000 36 CaOH+ 0.14756E-07 -7.8310 0.12859E-07 -7.8908 0.87148E+00 -0.0597 37 CaSO4,aq 0.11823E-09 -9.9273 0.11823E-09 -9.9273 0.10000E+01 0.0000 38 HCl,aq 0.30156E-14 -14.5206 0.30156E-14 -14.5206 0.10000E+01 0.0000 43 FeCl+ 0.16086E-16 -16.7935 0.14019E-16 -16.8533 0.87148E+00 -0.0597 46 FeO,aq 0.16658E-09 -9.7784 0.16658E-09 -9.7784 0.10000E+01 0.0000 47 FeOH+ 0.21357E-10 -10.6705 0.18612E-10 -10.7302 0.87148E+00 -0.0597 48 HFeO2- 0.15443E-07 -7.8113 0.13443E-07 -7.8715 0.87053E+00 -0.0602 49 FeO+ 0.10300E-14 -14.9871 0.89766E-15 -15.0469 0.87148E+00 -0.0597 51 FeO2- 0.11410E-07 -7.9427 0.99324E-08 -8.0029 0.87053E+00 -0.0602 52 HFeO2,aq 0.16567E-09 -9.7808 0.16567E-09 -9.7808 0.10000E+01 0.0000 53 H2,aq 0.25503E-08 -8.5934 0.25459E-08 -8.5942 0.99829E+00 -0.0007 54 KCl,aq 0.14589E-09 -9.8360 0.14589E-09 -9.8360 0.10000E+01 0.0000 55 KHSO4,aq 0.38137E-18 -18.4187 0.38137E-18 -18.4187 0.10000E+01 0.0000 56 KOH,aq 0.22404E-06 -6.6497 0.22404E-06 -6.6497 0.10000E+01 0.0000 57 KSO4- 0.18925E-07 -7.7230 0.16474E-07 -7.7832 0.87053E+00 -0.0602 58 MgCO3,aq 0.20012E-12 -12.6987 0.20012E-12 -12.6987 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27790E-14 -14.5561 0.24218E-14 -14.6159 0.87148E+00 -0.0597 60 MgCl+ 0.32796E-14 -14.4842 0.28581E-14 -14.5439 0.87148E+00 -0.0597 61 MgOH+ 0.55241E-10 -10.2577 0.48142E-10 -10.3175 0.87148E+00 -0.0597 63 MnO,aq 0.77153E-09 -9.1126 0.77153E-09 -9.1126 0.10000E+01 0.0000 64 MnOH+ 0.34423E-09 -9.4632 0.29999E-09 -9.5229 0.87148E+00 -0.0597 65 MnO2-2 0.24649E-11 -11.6082 0.15021E-11 -11.8233 0.60942E+00 -0.2151 66 HMnO2- 0.49827E-10 -10.3025 0.43376E-10 -10.3628 0.87053E+00 -0.0602 69 MnCl+ 0.10845E-13 -13.9648 0.94516E-14 -14.0245 0.87148E+00 -0.0597 70 MnSO4,aq 0.57440E-13 -13.2408 0.57440E-13 -13.2408 0.10000E+01 0.0000 71 NaCl,aq 0.34138E-06 -6.4668 0.34138E-06 -6.4668 0.10000E+01 0.0000 72 NaOH,aq 0.28654E-04 -4.5428 0.28654E-04 -4.5428 0.10000E+01 0.0000 74 OH- 0.51754E-02 -2.2861 0.45007E-02 -2.3467 0.86964E+00 -0.0607 79 HPO3-2 0.44428E-17 -17.3523 0.27075E-17 -17.5674 0.60942E+00 -0.2151 82 H3PO4,aq 0.38504E-16 -16.4145 0.38504E-16 -16.4145 0.10000E+01 0.0000 83 H2PO4- 0.90326E-09 -9.0442 0.78674E-09 -9.1042 0.87100E+00 -0.0600 84 PO4-3 0.64245E-08 -8.1922 0.22063E-08 -8.6563 0.34341E+00 -0.4642 87 H2P2O7-2 0.79490E-19 -19.0997 0.48443E-19 -19.3148 0.60942E+00 -0.2151 88 HP2O7-3 0.22308E-15 -15.6515 0.74532E-16 -16.1277 0.33411E+00 -0.4761 89 P2O7-4 0.94110E-15 -15.0264 0.13796E-15 -15.8602 0.14659E+00 -0.8339 90 H2S,aq 0.17434E-14 -14.7586 0.17405E-14 -14.7593 0.99829E+00 -0.0007 97 SO3-2 0.88203E-14 -14.0545 0.54195E-14 -14.2660 0.61444E+00 -0.2115 98 HSO3- 0.48556E-16 -16.3138 0.42270E-16 -16.3740 0.87053E+00 -0.0602 99 HSO4- 0.22142E-11 -11.6548 0.19306E-11 -11.7143 0.87195E+00 -0.0595 Charge balance for all species = 0.2990E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1525731E-09 -.1051154E-01 -.1058656E+02 0.0000 2 H2O 0.1000000E+01 0.5550828E+02 0.9992017E+06 0.0000 3 Cl- 0.1381835E-03 0.1385250E-03 0.4907214E+01 5.9555 4 SO4-- 0.2558724E-04 0.2560709E-04 0.2457898E+01 14.9440 5 HCO3- 0.6586728E-05 0.1312218E-04 0.8000406E+00 4.6341 6 HS- 0.4992365E-11 -.8043460E-09 -.2658014E-04 -1.4866 7 Al+++ 0.3005747E-27 0.2110336E-04 0.5689466E+00 1.6274 8 H4SiO4 0.5537509E-03 0.5770008E-02 0.5541449E+03 -3.2567 9 Ca++ 0.4000054E-07 0.5860206E-07 0.2346782E-02 12.1362 10 Mg++ 0.2710101E-10 0.8467866E-10 0.2057068E-05 8.9660 11 Fe++ 0.1233843E-12 0.2720598E-07 0.1518162E-02 6.6245 12 K+ 0.7860275E-04 0.7884586E-04 0.3080575E+01 5.7109 13 Na+ 0.9984619E-02 0.1057318E-01 0.2428818E+03 7.8143 14 Mn++ 0.2139759E-10 0.1189518E-08 0.6529766E-04 8.8638 15 HPO4-- 0.5517810E-06 0.5591088E-06 0.5361996E-01 13.2777 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5298429E+00 -.1046974E-01 -.5193732E+00 0.0000000E+00 2 H2O 0.5510713E+02 0.5528757E+02 -.1804381E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9123058E-03 0.2550527E-04 0.8868006E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8868014E-03 -.8011478E-09 -.8868006E-03 0.0000000E+00 7 Al+++ 0.1043405E+00 0.2101944E-04 0.1043195E+00 0.0000000E+00 8 H4SiO4 0.3331986E+00 0.5747066E-02 0.3274516E+00 0.0000000E+00 9 Ca++ 0.3681789E-01 0.5836905E-07 0.3681783E-01 0.0000000E+00 10 Mg++ 0.2539603E-01 0.8434196E-10 0.2539603E-01 0.0000000E+00 11 Fe++ 0.2281556E-01 0.2709780E-07 0.2281553E-01 0.0000000E+00 12 K+ 0.6793843E-02 0.7853235E-04 0.6715311E-02 0.0000000E+00 13 Na+ 0.4032661E-01 0.1053114E-01 0.2979547E-01 0.0000000E+00 14 Mn++ 0.5548177E-03 0.1184788E-08 0.5548165E-03 0.0000000E+00 15 HPO4-- 0.1893565E-03 0.5568857E-06 0.1887996E-03 0.0000000E+00 Chg. balance for solid moles: 0.1128E-15 Mass of aqueous solution: 0.996818E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 31.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2978E-01 -1.526 7.809 0.893 22.35 2.998 andradite 0.3502E-02 -2.456 1.780 0.250 5.094 0.4623 grossular 0.1236E-03 -3.908 0.5566E-01 -1.254 0.1593 0.1549E-01 apatite-OH 0.6293E-04 -4.201 0.3161E-01 -1.500 0.9050E-01 0.1005E-01 clinochlore 0.5079E-02 -2.294 2.823 0.451 8.082 1.074 daphnite 0.2422E-02 -2.616 1.728 0.238 4.946 0.5236 chlorite-Mn 0.1110E-03 -3.955 0.7867E-01 -1.104 0.2252 0.2507E-01 microcline 0.6354E-02 -2.197 1.769 0.248 5.063 0.6908 stilbite 0.2563E-01 -1.591 18.06 1.257 51.70 8.423 stilpnomelane-Fe 0.7226E-03 -3.141 0.7790 -0.108 2.230 0.2691 nontronite-Na 0.4539E-04 -4.343 0.1930E-01 -1.714 0.5525E-01 0.5996E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9659E+00 0.9659E+00 1.0000 -0.015 grossular 0.3408E-01 0.3408E-01 1.0000 -1.467 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6673E+00 0.6673E+00 1.0000 -0.176 daphnite 0.3181E+00 0.3181E+00 1.0000 -0.497 chlorite-Mn 0.1458E-01 0.1458E-01 1.0000 -1.836 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 34.932271 g Volume = 14.497472 cm3 Porosity: -5.0572% V(tot) - V(min): -.69787E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 31.9990000 g log = 1.5051 Original solution: 1000.0103000 g Original solution / Rock added: 31.25 (Water/Rock Ratio), log = 1.4949 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1666E-06 1.0073 0.1765E-06 0.1752E-06 CH4,gas 0.2327E-14 1.0129 0.2479E-14 0.2447E-14 H2,gas 0.3318E-05 1.0006 0.3492E-05 0.3490E-05 H2S,gas 0.4845E-13 0.9959 0.5076E-13 0.5097E-13 S2,gas 0.7524E-35 1.0000 0.7915E-35 0.7915E-35 CO,gas 0.1518E-15 1.0000 0.1597E-15 0.1597E-15 SO3,gas 0.9856E-40 1.0000 0.1037E-39 0.1037E-39 SO2,gas 0.1302E-22 1.0000 0.1370E-22 0.1370E-22 HCl,gas 0.5062E-17 1.0000 0.5325E-17 0.5325E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 209 nontronite-Na 3.58 3.58 0.00 0.000 -0.68244E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.12 -8.75 -2.918 0.14946E+05 -6.753 3 CH4,gas 4.81 -11.80 -16.61 -4.151 0.28354E+05 -14.606 4 H2,gas 8.29 0.83 -7.46 -4.261 0.12733E+05 -5.457 5 H2S,gas -5.94 -21.24 -15.29 -7.647 0.26115E+05 -13.294 6 S2,gas -7.03 -44.13 -37.10 -5.708 0.63350E+05 -35.102 7 CO,gas 3.51 -14.29 -17.80 -5.476 0.30388E+05 -15.797 8 SO3,gas 17.43 -24.56 -41.98 -10.496 0.71687E+05 -39.984 9 SO2,gas 1.14 -23.73 -24.86 -6.630 0.42454E+05 -22.863 10 HCl,gas 5.48 -13.80 -19.27 -9.637 0.32909E+05 -17.274 11 acmite 7.74 7.51 -0.23 -0.024 0.38742E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.08 -4.47 -0.224 0.76387E+04 20 analcite 3.37 2.93 -0.44 -0.049 0.75524E+03 26 annite 20.21 17.44 -2.77 -0.154 0.47255E+04 27 phlogopite 27.15 24.47 -2.68 -0.149 0.45768E+04 29 anorthite 12.80 8.88 -3.92 -0.302 0.66935E+04 35 aragonite 0.99 -2.98 -3.97 -1.322 0.67726E+04 36 brucite 12.58 8.97 -3.61 -0.722 0.61650E+04 37 calcite 0.83 -2.98 -3.81 -1.271 0.65113E+04 38 carnegieite-low 9.06 6.19 -2.88 -0.411 0.49167E+04 39 carnegieite-high 10.13 6.19 -3.95 -0.564 0.67436E+04 40 carpholite-Mg 8.65 5.71 -2.94 -0.196 0.50251E+04 41 carpholite-Fe 6.78 3.37 -3.42 -0.228 0.58344E+04 42 celadonite 5.40 3.28 -2.12 -0.125 0.36250E+04 43 celadonite-Fe 3.94 0.94 -3.00 -0.177 0.51239E+04 44 chrysotile 23.94 20.38 -3.55 -0.296 0.60662E+04 50 chloritoid-Mg 13.26 8.96 -4.30 -0.286 0.73373E+04 51 chloritoid-Fe 9.24 6.62 -2.62 -0.174 0.44669E+04 52 chloritoid-Mn 11.46 8.86 -2.60 -0.173 0.44417E+04 54 coesite -2.37 -3.26 -0.89 -0.296 0.15151E+04 61 cristobalite -2.55 -3.26 -0.71 -0.236 0.12080E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.63 -1.27 -0.211 0.21663E+04 67 diopside 16.22 14.59 -1.63 -0.163 0.27775E+04 68 hedenbergite 14.24 12.25 -2.00 -0.200 0.34099E+04 75 epidote 24.78 23.97 -0.81 -0.039 0.13806E+04 76 clinozoisite 22.92 19.38 -3.54 -0.161 0.60388E+04 77 epidote-Fe 29.94 28.55 -1.39 -0.072 0.23699E+04 78 fayalite 14.08 9.99 -4.09 -0.584 0.69777E+04 79 ferrosilite 11.19 6.74 -4.45 -0.445 0.76017E+04 83 gibbsite 4.10 1.63 -2.47 -0.353 0.42175E+04 84 glaucophane 23.11 19.73 -3.38 -0.091 0.57758E+04 85 glaucophane-Fe 17.42 12.70 -4.71 -0.127 0.80485E+04 87 greenalite 16.19 13.36 -2.83 -0.236 0.48390E+04 90 hematite 12.60 12.42 -0.18 -0.022 0.30483E+03 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.93 -1.32 -0.132 0.22583E+04 96 julgoldite 70.57 67.09 -3.48 -0.090 0.59436E+04 97 kalsilite 7.62 4.08 -3.54 -0.506 0.60422E+04 98 kaolinite -1.27 -3.26 -1.99 -0.180 0.33902E+04 99 kyanite 4.93 0.00 -4.93 -0.493 0.84240E+04 101 laumontite 2.97 2.36 -0.61 -0.041 0.10421E+04 102 lawsonite 9.68 8.88 -0.80 -0.053 0.13673E+04 103 leucite 4.17 0.82 -3.34 -0.334 0.57076E+04 105 lizardite 23.29 20.38 -2.90 -0.242 0.49565E+04 107 magnetite 20.13 19.04 -1.09 -0.089 0.18597E+04 108 minnesotaite 10.46 6.85 -3.61 -0.213 0.61706E+04 110 magnesioferrite 26.26 21.39 -4.87 -0.398 0.83191E+04 120 muscovite 2.68 0.82 -1.86 -0.109 0.31695E+04 121 paragonite 4.34 2.93 -1.41 -0.083 0.24079E+04 122 nepheline 8.38 6.19 -2.19 -0.313 0.37447E+04 134 phlogopite-Na 29.73 26.57 -3.16 -0.176 0.53987E+04 136 prehnite 19.47 17.76 -1.71 -0.101 0.29185E+04 137 prehnite-Fe 22.59 22.34 -0.25 -0.015 0.42262E+03 138 pumpellyite-Fe 46.47 43.77 -2.70 -0.060 0.46178E+04 139 pumpellyite-Mg 49.19 46.11 -3.09 -0.069 0.52702E+04 145 pyroxmangite 7.42 5.61 -1.81 -0.362 0.30886E+04 146 pyrophyllite -6.10 -9.77 -3.67 -0.230 0.62732E+04 147 quartz -2.98 -3.26 -0.27 -0.092 0.46902E+03 152 rhodonite 7.46 5.61 -1.86 -0.371 0.31678E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 24.89 -2.71 -0.081 0.46266E+04 171 talc 16.55 13.87 -2.68 -0.158 0.45797E+04 174 tephroite 18.11 14.47 -3.64 -0.520 0.62185E+04 177 topaz-H 4.67 0.00 -4.67 -0.424 0.79730E+04 178 tridymite -2.61 -3.26 -0.64 -0.214 0.10963E+04 179 tremolite 48.00 43.05 -4.95 -0.134 0.84594E+04 187 wairakite 4.06 2.36 -1.69 -0.100 0.28930E+04 188 walstromite 11.53 8.88 -2.65 -0.530 0.45220E+04 189 wollastonite 10.48 8.88 -1.60 -0.320 0.27359E+04 190 pseudo-wollastonite 11.02 8.88 -2.14 -0.428 0.36545E+04 191 zoisite 22.96 19.38 -3.58 -0.163 0.61113E+04 192 akaganeite 7.77 6.21 -1.56 -0.337 0.26606E+04 193 beidellite-Ca -1.56 -6.16 -4.60 -0.284 0.78511E+04 195 beidellite-K -1.44 -6.28 -4.84 -0.296 0.82653E+04 196 beidellite-Mg -1.71 -6.68 -4.97 -0.308 0.84929E+04 197 beidellite-Na -1.26 -5.58 -4.32 -0.265 0.73840E+04 199 chalcedony -2.79 -3.26 -0.46 -0.154 0.78934E+03 201 montmorillonite-Ca -2.21 -5.35 -3.13 -0.194 0.53508E+04 202 montmorillonite-K -2.16 -5.47 -3.30 -0.202 0.56427E+04 203 montmorillonite-Mg -2.40 -5.87 -3.47 -0.215 0.59236E+04 204 montmorillonite-Na -1.96 -4.77 -2.81 -0.172 0.47995E+04 205 nontronite-Ca 3.28 3.01 -0.27 -0.018 0.46630E+03 206 nontronite-H 2.60 1.00 -1.59 -0.107 0.27177E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11197E+04 224 tobermorite 9.84 6.85 -2.99 -0.815 0.50989E+04 233 boehmite 4.43 1.63 -2.80 -0.467 0.47847E+04 235 ferrous-oxide 9.82 6.62 -3.20 -0.800 0.54634E+04 240 silica-amorphous -2.08 -3.26 -1.18 -0.392 0.20095E+04 242 an20ab80 2.08 1.51 -0.57 -0.044 0.96708E+03 243 an25ab75 2.71 1.97 -0.74 -0.057 0.12568E+04 244 an30ab70 3.34 2.43 -0.91 -0.070 0.15548E+04 245 tr.625ac.25prg.125 45.31 41.40 -3.91 -0.105 0.66688E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 31.9990000 g New total amount of reactant added: 32.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2995E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 32.9990000 Water: Moles liquid = 0.5528E+02 kg liquid = 0.9959E+00 Moles total = 0.5509E+02 kg total = 0.9925E+00 Activity = 1.0000 Stoichiometric ionic strength = .5577684E-02 Osmotic coef. = 0.9607 True ionic strength = .1015053E-01 Chg. balance for total moles = 0.2995E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15260E-09 -9.8164 0.13327E-09 -9.8753 0.87329E+00 -0.0588 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13820E-03 -3.8595 0.12027E-03 -3.9198 0.87028E+00 -0.0603 4 SO4-- 0.25590E-04 -4.5919 0.15597E-04 -4.8070 0.60948E+00 -0.2150 5 HCO3- 0.65845E-05 -5.1815 0.57351E-05 -5.2415 0.87101E+00 -0.0600 6 HS- 0.54877E-11 -11.2606 0.47762E-11 -11.3209 0.87036E+00 -0.0603 7 Al+++ 0.28995E-27 -27.5377 0.96586E-28 -28.0151 0.33311E+00 -0.4774 8 H4SiO4 0.55989E-03 -3.2519 0.55989E-03 -3.2519 0.10000E+01 0.0000 9 Ca++ 0.40014E-07 -7.3978 0.24286E-07 -7.6146 0.60694E+00 -0.2169 10 Mg++ 0.27511E-10 -10.5605 0.16654E-10 -10.7785 0.60536E+00 -0.2180 11 Fe++ 0.12315E-12 -12.9096 0.74599E-13 -13.1273 0.60574E+00 -0.2177 12 K+ 0.79028E-04 -4.1022 0.68844E-04 -4.1621 0.87113E+00 -0.0599 13 Na+ 0.10039E-01 -1.9983 0.87357E-02 -2.0587 0.87020E+00 -0.0604 14 Mn++ 0.21721E-10 -10.6631 0.13164E-10 -10.8806 0.60602E+00 -0.2175 15 HPO4-- 0.55307E-06 -6.2572 0.33712E-06 -6.4722 0.60953E+00 -0.2150 16 HSiO3- 0.47100E-02 -2.3270 0.40991E-02 -2.3873 0.87028E+00 -0.0603 17 Ca(HSiO3)+ 0.25601E-08 -8.5917 0.22304E-08 -8.6516 0.87124E+00 -0.0599 18 Mg(HSiO3)+ 0.21848E-11 -11.6606 0.19035E-11 -11.7204 0.87124E+00 -0.0599 19 NaHSiO3,aq 0.56872E-03 -3.2451 0.56872E-03 -3.2451 0.10000E+01 0.0000 20 AlO+ 0.80584E-15 -15.0938 0.70208E-15 -15.1536 0.87124E+00 -0.0599 22 HAlO2,aq 0.10542E-08 -8.9771 0.10542E-08 -8.9771 0.10000E+01 0.0000 23 AlO2- 0.20317E-04 -4.6921 0.17663E-04 -4.7529 0.86938E+00 -0.0608 24 CH4,aq 0.17263E-17 -17.7629 0.17234E-17 -17.7636 0.99828E+00 -0.0007 29 CO,aq 0.10348E-18 -18.9851 0.10348E-18 -18.9851 0.10000E+01 0.0000 30 CO2,aq 0.15436E-08 -8.8115 0.15410E-08 -8.8122 0.99828E+00 -0.0007 31 CO3-2 0.65364E-05 -5.1847 0.39790E-05 -5.4002 0.60874E+00 -0.2156 32 CaCO3,aq 0.11835E-08 -8.9268 0.11835E-08 -8.9268 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40282E-11 -11.3949 0.35095E-11 -11.4548 0.87124E+00 -0.0599 34 CaCl+ 0.53423E-11 -11.2723 0.46544E-11 -11.3321 0.87124E+00 -0.0599 35 CaCl2,aq 0.13034E-15 -15.8849 0.13034E-15 -15.8849 0.10000E+01 0.0000 36 CaOH+ 0.14749E-07 -7.8312 0.12850E-07 -7.8911 0.87124E+00 -0.0599 37 CaSO4,aq 0.11802E-09 -9.9280 0.11802E-09 -9.9280 0.10000E+01 0.0000 38 HCl,aq 0.30148E-14 -14.5207 0.30148E-14 -14.5207 0.10000E+01 0.0000 43 FeCl+ 0.16039E-16 -16.7948 0.13974E-16 -16.8547 0.87124E+00 -0.0599 46 FeO,aq 0.16610E-09 -9.7796 0.16610E-09 -9.7796 0.10000E+01 0.0000 47 FeOH+ 0.21300E-10 -10.6716 0.18558E-10 -10.7315 0.87124E+00 -0.0599 48 HFeO2- 0.15404E-07 -7.8124 0.13406E-07 -7.8727 0.87028E+00 -0.0603 49 FeO+ 0.10151E-14 -14.9935 0.88442E-15 -15.0533 0.87124E+00 -0.0599 51 FeO2- 0.11246E-07 -7.9490 0.97874E-08 -8.0093 0.87028E+00 -0.0603 52 HFeO2,aq 0.16324E-09 -9.7872 0.16324E-09 -9.7872 0.10000E+01 0.0000 53 H2,aq 0.26118E-08 -8.5831 0.26073E-08 -8.5838 0.99828E+00 -0.0007 54 KCl,aq 0.14661E-09 -9.8338 0.14661E-09 -9.8338 0.10000E+01 0.0000 55 KHSO4,aq 0.38291E-18 -18.4169 0.38291E-18 -18.4169 0.10000E+01 0.0000 56 KOH,aq 0.22520E-06 -6.6474 0.22520E-06 -6.6474 0.10000E+01 0.0000 57 KSO4- 0.19008E-07 -7.7211 0.16542E-07 -7.7814 0.87028E+00 -0.0603 58 MgCO3,aq 0.20280E-12 -12.6929 0.20280E-12 -12.6929 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28168E-14 -14.5502 0.24541E-14 -14.6101 0.87124E+00 -0.0599 60 MgCl+ 0.33258E-14 -14.4781 0.28975E-14 -14.5380 0.87124E+00 -0.0599 61 MgOH+ 0.56033E-10 -10.2516 0.48818E-10 -10.3114 0.87124E+00 -0.0599 63 MnO,aq 0.78243E-09 -9.1066 0.78243E-09 -9.1066 0.10000E+01 0.0000 64 MnOH+ 0.34917E-09 -9.4570 0.30421E-09 -9.5168 0.87124E+00 -0.0599 65 MnO2-2 0.25029E-11 -11.6016 0.15236E-11 -11.8171 0.60874E+00 -0.2156 66 HMnO2- 0.50550E-10 -10.2963 0.43992E-10 -10.3566 0.87028E+00 -0.0603 69 MnCl+ 0.10998E-13 -13.9587 0.95819E-14 -14.0185 0.87124E+00 -0.0599 70 MnSO4,aq 0.58185E-13 -13.2352 0.58185E-13 -13.2352 0.10000E+01 0.0000 71 NaCl,aq 0.34306E-06 -6.4646 0.34306E-06 -6.4646 0.10000E+01 0.0000 72 NaOH,aq 0.28803E-04 -4.5406 0.28803E-04 -4.5406 0.10000E+01 0.0000 74 OH- 0.51772E-02 -2.2859 0.45010E-02 -2.3467 0.86938E+00 -0.0608 79 HPO3-2 0.45607E-17 -17.3410 0.27763E-17 -17.5565 0.60874E+00 -0.2156 82 H3PO4,aq 0.38545E-16 -16.4140 0.38545E-16 -16.4140 0.10000E+01 0.0000 83 H2PO4- 0.90456E-09 -9.0436 0.78765E-09 -9.1037 0.87075E+00 -0.0601 84 PO4-3 0.64484E-08 -8.1905 0.22092E-08 -8.6558 0.34259E+00 -0.4652 87 H2P2O7-2 0.79763E-19 -19.0982 0.48555E-19 -19.3138 0.60874E+00 -0.2156 88 HP2O7-3 0.22418E-15 -15.6494 0.74710E-16 -16.1266 0.33326E+00 -0.4772 89 P2O7-4 0.94761E-15 -15.0234 0.13830E-15 -15.8592 0.14595E+00 -0.8358 90 H2S,aq 0.19157E-14 -14.7177 0.19124E-14 -14.7184 0.99828E+00 -0.0007 97 SO3-2 0.90338E-14 -14.0441 0.55447E-14 -14.2561 0.61378E+00 -0.2120 98 HSO3- 0.49689E-16 -16.3037 0.43243E-16 -16.3641 0.87028E+00 -0.0603 99 HSO4- 0.22124E-11 -11.6551 0.19286E-11 -11.7148 0.87171E+00 -0.0596 Charge balance for all species = 0.2991E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1526025E-09 -.1057293E-01 -.1064832E+02 0.0000 2 H2O 0.1000000E+01 0.5550822E+02 0.9991937E+06 0.0000 3 Cl- 0.1381967E-03 0.1385399E-03 0.4907709E+01 5.9554 4 SO4-- 0.2558991E-04 0.2560982E-04 0.2458143E+01 14.9436 5 HCO3- 0.6584456E-05 0.1312359E-04 0.8001214E+00 4.6338 6 HS- 0.5487677E-11 -.7677391E-09 -.2537027E-04 -1.4456 7 Al+++ 0.2899530E-27 0.2031829E-04 0.5477775E+00 1.6107 8 H4SiO4 0.5598918E-03 0.5838639E-02 0.5607322E+03 -3.2519 9 Ca++ 0.4001358E-07 0.5863367E-07 0.2348032E-02 12.1359 10 Mg++ 0.2751120E-10 0.8593833E-10 0.2087654E-05 8.9721 11 Fe++ 0.1231537E-12 0.2700124E-07 0.1506727E-02 6.6233 12 K+ 0.7902785E-04 0.7927221E-04 0.3097211E+01 5.7131 13 Na+ 0.1003867E-01 0.1063653E-01 0.2443353E+03 7.8166 14 Mn++ 0.2172135E-10 0.1206445E-08 0.6622640E-04 8.8699 15 HPO4-- 0.5530746E-06 0.5604276E-06 0.5374606E-01 13.2783 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5464014E+00 -.1052975E-01 -.5358717E+00 0.0000000E+00 2 H2O 0.5509459E+02 0.5528154E+02 -.1869496E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9400193E-03 0.2550523E-04 0.9145140E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9145148E-03 -.7646039E-09 -.9145140E-03 0.0000000E+00 7 Al+++ 0.1076012E+00 0.2023532E-04 0.1075810E+00 0.0000000E+00 8 H4SiO4 0.3436114E+00 0.5814796E-02 0.3377966E+00 0.0000000E+00 9 Ca++ 0.3796803E-01 0.5839423E-07 0.3796797E-01 0.0000000E+00 10 Mg++ 0.2618968E-01 0.8558739E-10 0.2618968E-01 0.0000000E+00 11 Fe++ 0.2352857E-01 0.2689098E-07 0.2352854E-01 0.0000000E+00 12 K+ 0.7006157E-02 0.7894849E-04 0.6927209E-02 0.0000000E+00 13 Na+ 0.4158186E-01 0.1059310E-01 0.3098876E-01 0.0000000E+00 14 Mn++ 0.5721563E-03 0.1201518E-08 0.5721551E-03 0.0000000E+00 15 HPO4-- 0.1952741E-03 0.5581390E-06 0.1947160E-03 0.0000000E+00 Chg. balance for solid moles: 0.4836E-16 Mass of aqueous solution: 0.996717E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 32.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3099E-01 -1.509 8.125 0.910 22.55 3.119 andradite 0.3652E-02 -2.437 1.856 0.269 5.152 0.4822 grossular 0.1259E-03 -3.900 0.5671E-01 -1.246 0.1574 0.1578E-01 apatite-OH 0.6491E-04 -4.188 0.3260E-01 -1.487 0.9050E-01 0.1036E-01 clinochlore 0.5238E-02 -2.281 2.911 0.464 8.082 1.107 daphnite 0.2455E-02 -2.610 1.752 0.244 4.863 0.5309 chlorite-Mn 0.1144E-03 -3.941 0.8113E-01 -1.091 0.2252 0.2585E-01 microcline 0.6534E-02 -2.185 1.819 0.260 5.048 0.7104 stilbite 0.2631E-01 -1.580 18.54 1.268 51.46 8.647 stilpnomelane-Fe 0.7870E-03 -3.104 0.8484 -0.071 2.355 0.2931 nontronite-Na 0.5633E-05 -5.249 0.2395E-02 -2.621 0.6650E-02 0.7442E-03 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9667E+00 0.9667E+00 1.0000 -0.015 grossular 0.3332E-01 0.3332E-01 1.0000 -1.477 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6709E+00 0.6709E+00 1.0000 -0.173 daphnite 0.3145E+00 0.3145E+00 1.0000 -0.502 chlorite-Mn 0.1466E-01 0.1466E-01 1.0000 -1.834 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 36.024829 g Volume = 14.943332 cm3 Porosity: -5.2377% V(tot) - V(min): -.74373E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 32.9990000 g log = 1.5185 Original solution: 1000.0103000 g Original solution / Rock added: 30.30 (Water/Rock Ratio), log = 1.4815 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1665E-06 1.0073 0.1764E-06 0.1751E-06 CH4,gas 0.2558E-14 1.0129 0.2725E-14 0.2691E-14 H2,gas 0.3398E-05 1.0006 0.3576E-05 0.3574E-05 H2S,gas 0.5324E-13 0.9959 0.5578E-13 0.5601E-13 S2,gas 0.8662E-35 1.0000 0.9112E-35 0.9112E-35 CO,gas 0.1553E-15 1.0000 0.1634E-15 0.1634E-15 SO3,gas 0.9844E-40 1.0000 0.1036E-39 0.1036E-39 SO2,gas 0.1332E-22 1.0000 0.1401E-22 0.1401E-22 HCl,gas 0.5060E-17 1.0000 0.5323E-17 0.5323E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 209 nontronite-Na 3.58 3.58 0.00 0.000 0.37914E-11 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.12 -8.75 -2.918 0.14946E+05 -6.754 3 CH4,gas 4.81 -11.76 -16.56 -4.141 0.28284E+05 -14.565 4 H2,gas 8.29 0.84 -7.45 -4.255 0.12715E+05 -5.447 5 H2S,gas -5.94 -21.20 -15.25 -7.627 0.26045E+05 -13.254 6 S2,gas -7.03 -44.07 -37.04 -5.699 0.63245E+05 -35.040 7 CO,gas 3.51 -14.28 -17.79 -5.473 0.30370E+05 -15.787 8 SO3,gas 17.43 -24.56 -41.98 -10.496 0.71688E+05 -39.985 9 SO2,gas 1.14 -23.72 -24.85 -6.628 0.42437E+05 -22.854 10 HCl,gas 5.48 -13.80 -19.27 -9.637 0.32910E+05 -17.274 11 acmite 7.74 7.52 -0.22 -0.023 0.37817E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.08 -4.47 -0.224 0.76397E+04 20 analcite 3.37 2.92 -0.45 -0.050 0.76342E+03 26 annite 20.21 17.44 -2.77 -0.154 0.47318E+04 27 phlogopite 27.15 24.48 -2.66 -0.148 0.45455E+04 29 anorthite 12.80 8.85 -3.94 -0.303 0.67344E+04 35 aragonite 0.99 -2.98 -3.97 -1.322 0.67736E+04 36 brucite 12.58 8.97 -3.60 -0.721 0.61546E+04 37 calcite 0.83 -2.98 -3.81 -1.271 0.65123E+04 38 carnegieite-low 9.06 6.18 -2.89 -0.413 0.49331E+04 39 carnegieite-high 10.13 6.18 -3.96 -0.566 0.67600E+04 40 carpholite-Mg 8.65 5.69 -2.96 -0.197 0.50551E+04 41 carpholite-Fe 6.78 3.34 -3.44 -0.229 0.58769E+04 42 celadonite 5.40 3.29 -2.11 -0.124 0.36064E+04 43 celadonite-Fe 3.94 0.94 -3.00 -0.176 0.51179E+04 44 chrysotile 23.94 20.41 -3.52 -0.294 0.60187E+04 50 chloritoid-Mg 13.26 8.94 -4.32 -0.288 0.73755E+04 51 chloritoid-Fe 9.24 6.59 -2.65 -0.176 0.45176E+04 52 chloritoid-Mn 11.46 8.84 -2.62 -0.175 0.44798E+04 54 coesite -2.37 -3.25 -0.88 -0.294 0.15069E+04 61 cristobalite -2.55 -3.25 -0.70 -0.234 0.11998E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.61 -1.29 -0.214 0.21947E+04 67 diopside 16.22 14.60 -1.61 -0.161 0.27512E+04 68 hedenbergite 14.24 12.26 -1.99 -0.199 0.33962E+04 75 epidote 24.78 23.94 -0.83 -0.040 0.14248E+04 76 clinozoisite 22.92 19.35 -3.57 -0.162 0.61004E+04 77 epidote-Fe 29.94 28.53 -1.40 -0.073 0.23967E+04 78 fayalite 14.08 9.99 -4.08 -0.583 0.69738E+04 79 ferrosilite 11.19 6.74 -4.44 -0.444 0.75895E+04 83 gibbsite 4.10 1.61 -2.49 -0.355 0.42459E+04 84 glaucophane 23.11 19.76 -3.35 -0.091 0.57282E+04 85 glaucophane-Fe 17.42 12.71 -4.71 -0.127 0.80385E+04 87 greenalite 16.19 13.37 -2.83 -0.236 0.48290E+04 90 hematite 12.60 12.41 -0.19 -0.023 0.32674E+03 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.92 -1.33 -0.133 0.22664E+04 96 julgoldite 70.57 67.09 -3.48 -0.090 0.59446E+04 97 kalsilite 7.62 4.07 -3.55 -0.507 0.60586E+04 98 kaolinite -1.27 -3.28 -2.01 -0.183 0.34306E+04 99 kyanite 4.93 -0.03 -4.96 -0.496 0.84725E+04 101 laumontite 2.97 2.35 -0.62 -0.042 0.10667E+04 102 lawsonite 9.68 8.85 -0.82 -0.055 0.14082E+04 103 leucite 4.17 0.82 -3.35 -0.335 0.57158E+04 105 lizardite 23.29 20.41 -2.87 -0.240 0.49089E+04 107 magnetite 20.13 19.03 -1.10 -0.090 0.18838E+04 108 minnesotaite 10.46 6.86 -3.60 -0.212 0.61442E+04 110 magnesioferrite 26.26 21.38 -4.88 -0.398 0.83306E+04 120 muscovite 2.68 0.79 -1.89 -0.111 0.32262E+04 121 paragonite 4.34 2.89 -1.44 -0.085 0.24647E+04 122 nepheline 8.38 6.18 -2.20 -0.315 0.37610E+04 134 phlogopite-Na 29.73 26.59 -3.14 -0.175 0.53674E+04 136 prehnite 19.47 17.74 -1.73 -0.102 0.29517E+04 137 prehnite-Fe 22.59 22.33 -0.26 -0.015 0.43839E+03 138 pumpellyite-Fe 46.47 43.71 -2.76 -0.061 0.47147E+04 139 pumpellyite-Mg 49.19 46.06 -3.14 -0.070 0.53545E+04 145 pyroxmangite 7.42 5.62 -1.80 -0.360 0.30700E+04 146 pyrophyllite -6.10 -9.79 -3.69 -0.231 0.62973E+04 147 quartz -2.98 -3.25 -0.27 -0.090 0.46084E+03 152 rhodonite 7.46 5.62 -1.84 -0.369 0.31493E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 24.92 -2.67 -0.080 0.45640E+04 171 talc 16.55 13.91 -2.64 -0.156 0.45158E+04 174 tephroite 18.11 14.49 -3.62 -0.518 0.61895E+04 177 topaz-H 4.67 -0.03 -4.70 -0.427 0.80216E+04 178 tridymite -2.61 -3.25 -0.64 -0.212 0.10881E+04 179 tremolite 48.00 43.12 -4.89 -0.132 0.83429E+04 187 wairakite 4.06 2.35 -1.71 -0.101 0.29175E+04 188 walstromite 11.53 8.88 -2.64 -0.529 0.45143E+04 189 wollastonite 10.48 8.88 -1.60 -0.320 0.27282E+04 190 pseudo-wollastonite 11.02 8.88 -2.14 -0.427 0.36468E+04 191 zoisite 22.96 19.35 -3.62 -0.164 0.61729E+04 192 akaganeite 7.77 6.20 -1.56 -0.338 0.26715E+04 193 beidellite-Ca -1.56 -6.18 -4.62 -0.286 0.78873E+04 195 beidellite-K -1.44 -6.30 -4.86 -0.298 0.83001E+04 196 beidellite-Mg -1.71 -6.70 -4.99 -0.309 0.85273E+04 197 beidellite-Na -1.26 -5.60 -4.34 -0.266 0.74188E+04 199 chalcedony -2.79 -3.25 -0.46 -0.152 0.78116E+03 201 montmorillonite-Ca -2.21 -5.35 -3.14 -0.194 0.53621E+04 202 montmorillonite-K -2.16 -5.47 -3.31 -0.203 0.56526E+04 203 montmorillonite-Mg -2.40 -5.88 -3.47 -0.215 0.59332E+04 204 montmorillonite-Na -1.96 -4.78 -2.82 -0.172 0.48095E+04 205 nontronite-Ca 3.28 3.01 -0.27 -0.018 0.46764E+03 206 nontronite-H 2.60 1.00 -1.59 -0.107 0.27190E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11193E+04 224 tobermorite 9.84 6.86 -2.98 -0.814 0.50911E+04 233 boehmite 4.43 1.61 -2.82 -0.470 0.48131E+04 235 ferrous-oxide 9.82 6.62 -3.20 -0.800 0.54655E+04 240 silica-amorphous -2.08 -3.25 -1.17 -0.391 0.20014E+04 242 an20ab80 2.08 1.51 -0.57 -0.044 0.97526E+03 243 an25ab75 2.71 1.97 -0.74 -0.057 0.12670E+04 244 an30ab70 3.34 2.43 -0.92 -0.071 0.15670E+04 245 tr.625ac.25prg.125 45.31 41.45 -3.85 -0.104 0.65814E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 32.9990000 g New total amount of reactant added: 33.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2995E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 33.9990000 Water: Moles liquid = 0.5528E+02 kg liquid = 0.9958E+00 Moles total = 0.5508E+02 kg total = 0.9923E+00 Activity = 1.0000 Stoichiometric ionic strength = .5605626E-02 Osmotic coef. = 0.9606 True ionic strength = .1020382E-01 Chg. balance for total moles = 0.2995E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.15263E-09 -9.8163 0.13326E-09 -9.8753 0.87306E+00 -0.0590 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13821E-03 -3.8595 0.12025E-03 -3.9199 0.87004E+00 -0.0605 4 SO4-- 0.25593E-04 -4.5919 0.15581E-04 -4.8074 0.60882E+00 -0.2155 5 HCO3- 0.65823E-05 -5.1816 0.57317E-05 -5.2417 0.87077E+00 -0.0601 6 HS- 0.60152E-11 -11.2208 0.52339E-11 -11.2812 0.87012E+00 -0.0604 7 Al+++ 0.28003E-27 -27.5528 0.93050E-28 -28.0313 0.33229E+00 -0.4785 8 H4SiO4 0.56591E-03 -3.2472 0.56591E-03 -3.2472 0.10000E+01 0.0000 9 Ca++ 0.40028E-07 -7.3976 0.24268E-07 -7.6150 0.60628E+00 -0.2173 10 Mg++ 0.27914E-10 -10.5542 0.16879E-10 -10.7726 0.60469E+00 -0.2185 11 Fe++ 0.12294E-12 -12.9103 0.74384E-13 -13.1285 0.60507E+00 -0.2182 12 K+ 0.79444E-04 -4.0999 0.69187E-04 -4.1600 0.87089E+00 -0.0600 13 Na+ 0.10092E-01 -1.9960 0.87792E-02 -2.0565 0.86996E+00 -0.0605 14 Mn++ 0.22039E-10 -10.6568 0.13341E-10 -10.8748 0.60535E+00 -0.2180 15 HPO4-- 0.55432E-06 -6.2562 0.33751E-06 -6.4717 0.60887E+00 -0.2155 16 HSiO3- 0.47623E-02 -2.3222 0.41434E-02 -2.3826 0.87004E+00 -0.0605 17 Ca(HSiO3)+ 0.25865E-08 -8.5873 0.22529E-08 -8.6473 0.87100E+00 -0.0600 18 Mg(HSiO3)+ 0.22389E-11 -11.6500 0.19501E-11 -11.7099 0.87100E+00 -0.0600 19 NaHSiO3,aq 0.57774E-03 -3.2383 0.57774E-03 -3.2383 0.10000E+01 0.0000 20 AlO+ 0.77664E-15 -15.1098 0.67645E-15 -15.1698 0.87100E+00 -0.0600 22 HAlO2,aq 0.10158E-08 -8.9932 0.10158E-08 -8.9932 0.10000E+01 0.0000 23 AlO2- 0.19583E-04 -4.7081 0.17021E-04 -4.7690 0.86914E+00 -0.0609 24 CH4,aq 0.18925E-17 -17.7230 0.18892E-17 -17.7237 0.99828E+00 -0.0007 29 CO,aq 0.10583E-18 -18.9754 0.10583E-18 -18.9754 0.10000E+01 0.0000 30 CO2,aq 0.15426E-08 -8.8117 0.15400E-08 -8.8125 0.99828E+00 -0.0007 31 CO3-2 0.65400E-05 -5.1844 0.39768E-05 -5.4005 0.60808E+00 -0.2160 32 CaCO3,aq 0.11820E-08 -8.9274 0.11820E-08 -8.9274 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40239E-11 -11.3954 0.35048E-11 -11.4553 0.87100E+00 -0.0600 34 CaCl+ 0.53388E-11 -11.2726 0.46501E-11 -11.3325 0.87100E+00 -0.0600 35 CaCl2,aq 0.13019E-15 -15.8854 0.13019E-15 -15.8854 0.10000E+01 0.0000 36 CaOH+ 0.14743E-07 -7.8314 0.12841E-07 -7.8914 0.87100E+00 -0.0600 37 CaSO4,aq 0.11782E-09 -9.9288 0.11782E-09 -9.9288 0.10000E+01 0.0000 38 HCl,aq 0.30141E-14 -14.5208 0.30141E-14 -14.5208 0.10000E+01 0.0000 43 FeCl+ 0.15995E-16 -16.7960 0.13931E-16 -16.8560 0.87100E+00 -0.0600 46 FeO,aq 0.16564E-09 -9.7808 0.16564E-09 -9.7808 0.10000E+01 0.0000 47 FeOH+ 0.21246E-10 -10.6727 0.18505E-10 -10.7327 0.87100E+00 -0.0600 48 HFeO2- 0.15367E-07 -7.8134 0.13370E-07 -7.8739 0.87004E+00 -0.0605 49 FeO+ 0.10009E-14 -14.9996 0.87178E-15 -15.0596 0.87100E+00 -0.0600 51 FeO2- 0.11090E-07 -7.9551 0.96486E-08 -8.0155 0.87004E+00 -0.0605 52 HFeO2,aq 0.16091E-09 -9.7934 0.16091E-09 -9.7934 0.10000E+01 0.0000 53 H2,aq 0.26730E-08 -8.5730 0.26684E-08 -8.5738 0.99828E+00 -0.0007 54 KCl,aq 0.14731E-09 -9.8318 0.14731E-09 -9.8318 0.10000E+01 0.0000 55 KHSO4,aq 0.38442E-18 -18.4152 0.38442E-18 -18.4152 0.10000E+01 0.0000 56 KOH,aq 0.22634E-06 -6.6452 0.22634E-06 -6.6452 0.10000E+01 0.0000 57 KSO4- 0.19089E-07 -7.7192 0.16609E-07 -7.7797 0.87004E+00 -0.0605 58 MgCO3,aq 0.20543E-12 -12.6873 0.20543E-12 -12.6873 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28540E-14 -14.5446 0.24858E-14 -14.6045 0.87100E+00 -0.0600 60 MgCl+ 0.33710E-14 -14.4722 0.29362E-14 -14.5322 0.87100E+00 -0.0600 61 MgOH+ 0.56809E-10 -10.2456 0.49481E-10 -10.3056 0.87100E+00 -0.0600 63 MnO,aq 0.79309E-09 -9.1007 0.79309E-09 -9.1007 0.10000E+01 0.0000 64 MnOH+ 0.35400E-09 -9.4510 0.30833E-09 -9.5110 0.87100E+00 -0.0600 65 MnO2-2 0.25400E-11 -11.5952 0.15445E-11 -11.8112 0.60808E+00 -0.2160 66 HMnO2- 0.51255E-10 -10.2903 0.44594E-10 -10.3507 0.87004E+00 -0.0605 69 MnCl+ 0.11148E-13 -13.9528 0.97096E-14 -14.0128 0.87100E+00 -0.0600 70 MnSO4,aq 0.58913E-13 -13.2298 0.58913E-13 -13.2298 0.10000E+01 0.0000 71 NaCl,aq 0.34471E-06 -6.4625 0.34471E-06 -6.4625 0.10000E+01 0.0000 72 NaOH,aq 0.28949E-04 -4.5384 0.28949E-04 -4.5384 0.10000E+01 0.0000 74 OH- 0.51790E-02 -2.2858 0.45013E-02 -2.3467 0.86914E+00 -0.0609 79 HPO3-2 0.46780E-17 -17.3299 0.28446E-17 -17.5460 0.60808E+00 -0.2160 82 H3PO4,aq 0.38586E-16 -16.4136 0.38586E-16 -16.4136 0.10000E+01 0.0000 83 H2PO4- 0.90583E-09 -9.0430 0.78854E-09 -9.1032 0.87051E+00 -0.0602 84 PO4-3 0.64715E-08 -8.1890 0.22119E-08 -8.6552 0.34179E+00 -0.4662 87 H2P2O7-2 0.80029E-19 -19.0968 0.48664E-19 -19.3128 0.60808E+00 -0.2160 88 HP2O7-3 0.22525E-15 -15.6473 0.74882E-16 -16.1256 0.33245E+00 -0.4783 89 P2O7-4 0.95394E-15 -15.0205 0.13863E-15 -15.8582 0.14532E+00 -0.8377 90 H2S,aq 0.20992E-14 -14.6779 0.20956E-14 -14.6787 0.99828E+00 -0.0007 97 SO3-2 0.92459E-14 -14.0341 0.56690E-14 -14.2465 0.61313E+00 -0.2124 98 HSO3- 0.50813E-16 -16.2940 0.44210E-16 -16.3545 0.87004E+00 -0.0605 99 HSO4- 0.22107E-11 -11.6555 0.19266E-11 -11.7152 0.87148E+00 -0.0597 Charge balance for all species = 0.2993E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1526341E-09 -.1063315E-01 -.1070889E+02 0.0000 2 H2O 0.1000000E+01 0.5550816E+02 0.9991859E+06 0.0000 3 Cl- 0.1382100E-03 0.1385549E-03 0.4908205E+01 5.9554 4 SO4-- 0.2559259E-04 0.2561254E-04 0.2458388E+01 14.9432 5 HCO3- 0.6582322E-05 0.1312501E-04 0.8002023E+00 4.6336 6 HS- 0.6015170E-11 -.7320824E-09 -.2419181E-04 -1.4059 7 Al+++ 0.2800281E-27 0.1958432E-04 0.5279862E+00 1.5946 8 H4SiO4 0.5659146E-03 0.5905926E-02 0.5671905E+03 -3.2472 9 Ca++ 0.4002755E-07 0.5866610E-07 0.2349315E-02 12.1356 10 Mg++ 0.2791387E-10 0.8717339E-10 0.2117642E-05 8.9780 11 Fe++ 0.1229356E-12 0.2680446E-07 0.1495736E-02 6.6221 12 K+ 0.7944366E-04 0.7968923E-04 0.3113484E+01 5.7153 13 Na+ 0.1009153E-01 0.1069856E-01 0.2457585E+03 7.8188 14 Mn++ 0.2203917E-10 0.1222997E-08 0.6713458E-04 8.8758 15 HPO4-- 0.5543245E-06 0.5617019E-06 0.5386790E-01 13.2789 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5629599E+00 -.1058859E-01 -.5523713E+00 0.0000000E+00 2 H2O 0.5508206E+02 0.5527553E+02 -.1934665E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9677327E-03 0.2550520E-04 0.9422275E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9422282E-03 -.7290143E-09 -.9422275E-03 0.0000000E+00 7 Al+++ 0.1108620E+00 0.1950224E-04 0.1108425E+00 0.0000000E+00 8 H4SiO4 0.3540242E+00 0.5881174E-02 0.3481430E+00 0.0000000E+00 9 Ca++ 0.3911817E-01 0.5842023E-07 0.3911811E-01 0.0000000E+00 10 Mg++ 0.2698333E-01 0.8680805E-10 0.2698333E-01 0.0000000E+00 11 Fe++ 0.2424158E-01 0.2669213E-07 0.2424155E-01 0.0000000E+00 12 K+ 0.7218471E-02 0.7935526E-04 0.7139116E-02 0.0000000E+00 13 Na+ 0.4283710E-01 0.1065373E-01 0.3218337E-01 0.0000000E+00 14 Mn++ 0.5894949E-03 0.1217872E-08 0.5894937E-03 0.0000000E+00 15 HPO4-- 0.2011917E-03 0.5593478E-06 0.2006323E-03 0.0000000E+00 Chg. balance for solid moles: -.1306E-15 Mass of aqueous solution: 0.996617E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 33.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3219E-01 -1.492 8.442 0.926 22.74 3.241 andradite 0.3803E-02 -2.420 1.933 0.286 5.207 0.5021 grossular 0.1281E-03 -3.892 0.5772E-01 -1.239 0.1555 0.1606E-01 apatite-OH 0.6688E-04 -4.175 0.3359E-01 -1.474 0.9051E-01 0.1067E-01 clinochlore 0.5397E-02 -2.268 3.000 0.477 8.081 1.141 daphnite 0.2489E-02 -2.604 1.776 0.249 4.785 0.5382 chlorite-Mn 0.1179E-03 -3.928 0.8359E-01 -1.078 0.2252 0.2664E-01 microcline 0.6713E-02 -2.173 1.869 0.272 5.034 0.7299 stilbite 0.2699E-01 -1.569 19.02 1.279 51.24 8.871 stilpnomelane-Fe 0.8518E-03 -3.070 0.9182 -0.037 2.474 0.3172 nontronite-Na -.3437E-04 1.000 -.1462E-01 1.000 -.3938E-01 -.4541E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9674E+00 0.9674E+00 1.0000 -0.014 grossular 0.3259E-01 0.3259E-01 1.0000 -1.487 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6743E+00 0.6743E+00 1.0000 -0.171 daphnite 0.3110E+00 0.3110E+00 1.0000 -0.507 chlorite-Mn 0.1473E-01 0.1473E-01 1.0000 -1.832 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 nontronite-Na 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 37.117450 g Volume = 15.389187 cm3 Porosity: -5.4083% V(tot) - V(min): -.78959E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 33.9990000 g log = 1.5315 Original solution: 1000.0103000 g Original solution / Rock added: 29.41 (Water/Rock Ratio), log = 1.4685 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1664E-06 1.0073 0.1763E-06 0.1750E-06 CH4,gas 0.2804E-14 1.0129 0.2988E-14 0.2949E-14 H2,gas 0.3477E-05 1.0006 0.3660E-05 0.3658E-05 H2S,gas 0.5834E-13 0.9959 0.6112E-13 0.6137E-13 S2,gas 0.9930E-35 1.0000 0.1045E-34 0.1045E-34 CO,gas 0.1589E-15 1.0000 0.1671E-15 0.1671E-15 SO3,gas 0.9834E-40 1.0000 0.1034E-39 0.1034E-39 SO2,gas 0.1361E-22 1.0000 0.1432E-22 0.1432E-22 HCl,gas 0.5059E-17 1.0000 0.5322E-17 0.5322E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.12 -8.75 -2.918 0.14947E+05 -6.754 3 CH4,gas 4.81 -11.72 -16.52 -4.131 0.28215E+05 -14.525 4 H2,gas 8.29 0.85 -7.44 -4.249 0.12698E+05 -5.437 5 H2S,gas -5.94 -21.16 -15.21 -7.607 0.25977E+05 -13.214 6 S2,gas -7.03 -44.01 -36.98 -5.689 0.63144E+05 -34.981 7 CO,gas 3.51 -14.27 -17.78 -5.470 0.30354E+05 -15.777 8 SO3,gas 17.43 -24.56 -41.99 -10.496 0.71689E+05 -39.985 9 SO2,gas 1.14 -23.71 -24.84 -6.625 0.42420E+05 -22.844 10 HCl,gas 5.48 -13.80 -19.27 -9.637 0.32910E+05 -17.274 11 acmite 7.74 7.52 -0.22 -0.022 0.36921E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.07 -4.47 -0.224 0.76409E+04 20 analcite 3.37 2.92 -0.45 -0.050 0.77135E+03 26 annite 20.21 17.43 -2.77 -0.154 0.47380E+04 27 phlogopite 27.15 24.50 -2.64 -0.147 0.45154E+04 29 anorthite 12.80 8.83 -3.97 -0.305 0.67740E+04 35 aragonite 0.99 -2.98 -3.97 -1.323 0.67746E+04 36 brucite 12.58 8.98 -3.60 -0.720 0.61446E+04 37 calcite 0.83 -2.98 -3.81 -1.272 0.65132E+04 38 carnegieite-low 9.06 6.17 -2.90 -0.414 0.49490E+04 39 carnegieite-high 10.13 6.17 -3.97 -0.567 0.67758E+04 40 carpholite-Mg 8.65 5.67 -2.98 -0.199 0.50843E+04 41 carpholite-Fe 6.78 3.32 -3.47 -0.231 0.59182E+04 42 celadonite 5.40 3.30 -2.10 -0.124 0.35884E+04 43 celadonite-Fe 3.94 0.94 -2.99 -0.176 0.51120E+04 44 chrysotile 23.94 20.44 -3.50 -0.291 0.59727E+04 50 chloritoid-Mg 13.26 8.92 -4.34 -0.289 0.74126E+04 51 chloritoid-Fe 9.24 6.56 -2.67 -0.178 0.45668E+04 52 chloritoid-Mn 11.46 8.82 -2.65 -0.176 0.45169E+04 54 coesite -2.37 -3.25 -0.88 -0.293 0.14990E+04 61 cristobalite -2.55 -3.25 -0.70 -0.233 0.11919E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.59 -1.30 -0.217 0.22222E+04 67 diopside 16.22 14.62 -1.60 -0.160 0.27258E+04 68 hedenbergite 14.24 12.26 -1.98 -0.198 0.33828E+04 75 epidote 24.78 23.92 -0.86 -0.042 0.14676E+04 76 clinozoisite 22.92 19.31 -3.61 -0.164 0.61601E+04 77 epidote-Fe 29.94 28.52 -1.42 -0.074 0.24226E+04 78 fayalite 14.08 10.00 -4.08 -0.583 0.69700E+04 79 ferrosilite 11.19 6.75 -4.44 -0.444 0.75778E+04 83 gibbsite 4.10 1.59 -2.50 -0.358 0.42734E+04 84 glaucophane 23.11 19.78 -3.33 -0.090 0.56823E+04 85 glaucophane-Fe 17.42 12.72 -4.70 -0.127 0.80288E+04 87 greenalite 16.19 13.37 -2.82 -0.235 0.48193E+04 90 hematite 12.60 12.39 -0.20 -0.025 0.34801E+03 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.92 -1.33 -0.133 0.22744E+04 96 julgoldite 70.57 67.09 -3.48 -0.090 0.59455E+04 97 kalsilite 7.62 4.06 -3.56 -0.508 0.60744E+04 98 kaolinite -1.27 -3.31 -2.03 -0.185 0.34698E+04 99 kyanite 4.93 -0.06 -4.99 -0.499 0.85197E+04 101 laumontite 2.97 2.34 -0.64 -0.043 0.10905E+04 102 lawsonite 9.68 8.83 -0.85 -0.057 0.14479E+04 103 leucite 4.17 0.82 -3.35 -0.335 0.57238E+04 105 lizardite 23.29 20.44 -2.85 -0.237 0.48630E+04 107 magnetite 20.13 19.02 -1.12 -0.091 0.19071E+04 108 minnesotaite 10.46 6.88 -3.58 -0.211 0.61187E+04 110 magnesioferrite 26.26 21.37 -4.89 -0.399 0.83419E+04 120 muscovite 2.68 0.76 -1.92 -0.113 0.32813E+04 121 paragonite 4.34 2.86 -1.48 -0.087 0.25198E+04 122 nepheline 8.38 6.17 -2.21 -0.316 0.37769E+04 134 phlogopite-Na 29.73 26.61 -3.13 -0.174 0.53373E+04 136 prehnite 19.47 17.72 -1.75 -0.103 0.29839E+04 137 prehnite-Fe 22.59 22.32 -0.27 -0.016 0.45370E+03 138 pumpellyite-Fe 46.47 43.65 -2.82 -0.063 0.48087E+04 139 pumpellyite-Mg 49.19 46.01 -3.18 -0.071 0.54364E+04 145 pyroxmangite 7.42 5.63 -1.79 -0.357 0.30521E+04 146 pyrophyllite -6.10 -9.80 -3.70 -0.231 0.63206E+04 147 quartz -2.98 -3.25 -0.27 -0.088 0.45291E+03 152 rhodonite 7.46 5.63 -1.83 -0.367 0.31313E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 24.96 -2.64 -0.079 0.45036E+04 171 talc 16.55 13.94 -2.61 -0.153 0.44539E+04 174 tephroite 18.11 14.50 -3.61 -0.516 0.61615E+04 177 topaz-H 4.67 -0.06 -4.73 -0.430 0.80688E+04 178 tridymite -2.61 -3.25 -0.63 -0.211 0.10802E+04 179 tremolite 48.00 43.18 -4.82 -0.130 0.82302E+04 187 wairakite 4.06 2.34 -1.72 -0.101 0.29413E+04 188 walstromite 11.53 8.89 -2.64 -0.528 0.45068E+04 189 wollastonite 10.48 8.89 -1.59 -0.319 0.27207E+04 190 pseudo-wollastonite 11.02 8.89 -2.13 -0.426 0.36394E+04 191 zoisite 22.96 19.31 -3.65 -0.166 0.62327E+04 192 akaganeite 7.77 6.20 -1.57 -0.340 0.26822E+04 193 beidellite-Ca -1.56 -6.20 -4.64 -0.287 0.79225E+04 195 beidellite-K -1.44 -6.32 -4.88 -0.299 0.83339E+04 197 beidellite-Na -1.26 -5.62 -4.36 -0.267 0.74526E+04 199 chalcedony -2.79 -3.25 -0.45 -0.151 0.77322E+03 201 montmorillonite-Ca -2.21 -5.36 -3.15 -0.195 0.53731E+04 202 montmorillonite-K -2.16 -5.48 -3.32 -0.203 0.56623E+04 203 montmorillonite-Mg -2.40 -5.88 -3.48 -0.215 0.59424E+04 204 montmorillonite-Na -1.96 -4.78 -2.82 -0.173 0.48192E+04 205 nontronite-Ca 3.28 3.00 -0.27 -0.018 0.46895E+03 206 nontronite-H 2.60 1.00 -1.59 -0.107 0.27202E+04 207 nontronite-K 3.40 2.89 -0.52 -0.033 0.87958E+03 208 nontronite-Mg 3.14 2.48 -0.66 -0.043 0.11188E+04 209 nontronite-Na 3.58 3.58 0.00 0.000 0.83410E-11 224 tobermorite 9.84 6.86 -2.98 -0.812 0.50836E+04 233 boehmite 4.43 1.59 -2.83 -0.472 0.48406E+04 235 ferrous-oxide 9.82 6.62 -3.20 -0.801 0.54676E+04 240 silica-amorphous -2.08 -3.25 -1.17 -0.389 0.19934E+04 242 an20ab80 2.08 1.50 -0.58 -0.044 0.98320E+03 243 an25ab75 2.71 1.96 -0.75 -0.058 0.12769E+04 244 an30ab70 3.34 2.42 -0.92 -0.071 0.15789E+04 245 tr.625ac.25prg.125 45.31 41.50 -3.81 -0.102 0.64970E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 33.9990000 Water: Moles liquid = 0.5528E+02 kg liquid = 0.9958E+00 Moles total = 0.5508E+02 kg total = 0.9923E+00 Activity = 1.0000 Stoichiometric ionic strength = .5691904E-02 Osmotic coef. = 0.9603 True ionic strength = .1035919E-01 Chg. balance for total moles = 0.2995E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14994E-09 -9.8241 0.13081E-09 -9.8834 0.87240E+00 -0.0593 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13821E-03 -3.8595 0.12015E-03 -3.9203 0.86934E+00 -0.0608 4 SO4-- 0.25593E-04 -4.5919 0.15533E-04 -4.8088 0.60692E+00 -0.2169 5 HCO3- 0.65138E-05 -5.1862 0.56675E-05 -5.2466 0.87008E+00 -0.0604 6 HS- 0.14783E-10 -10.8302 0.12852E-10 -10.8910 0.86942E+00 -0.0608 7 Al+++ 0.26448E-27 -27.5776 0.87260E-28 -28.0592 0.32993E+00 -0.4816 8 H4SiO4 0.56135E-03 -3.2508 0.56135E-03 -3.2508 0.10000E+01 0.0000 9 Ca++ 0.41661E-07 -7.3803 0.25178E-07 -7.5990 0.60435E+00 -0.2187 10 Mg++ 0.27149E-10 -10.5662 0.16364E-10 -10.7861 0.60274E+00 -0.2199 11 Fe++ 0.12041E-12 -12.9193 0.72621E-13 -13.1389 0.60313E+00 -0.2196 12 K+ 0.80656E-04 -4.0934 0.70187E-04 -4.1537 0.87021E+00 -0.0604 13 Na+ 0.10246E-01 -1.9895 0.89062E-02 -2.0503 0.86926E+00 -0.0608 14 Mn++ 0.21435E-10 -10.6689 0.12934E-10 -10.8883 0.60342E+00 -0.2194 15 HPO4-- 0.51020E-06 -6.2923 0.30967E-06 -6.5091 0.60697E+00 -0.2168 16 HSiO3- 0.48161E-02 -2.3173 0.41869E-02 -2.3781 0.86934E+00 -0.0608 17 Ca(HSiO3)+ 0.27138E-08 -8.5664 0.23619E-08 -8.6267 0.87031E+00 -0.0603 18 Mg(HSiO3)+ 0.21951E-11 -11.6585 0.19105E-11 -11.7189 0.87031E+00 -0.0603 19 NaHSiO3,aq 0.59224E-03 -3.2275 0.59224E-03 -3.2275 0.10000E+01 0.0000 20 AlO+ 0.75644E-15 -15.1212 0.65834E-15 -15.1816 0.87031E+00 -0.0603 22 HAlO2,aq 0.10071E-08 -8.9969 0.10071E-08 -8.9969 0.10000E+01 0.0000 23 AlO2- 0.19795E-04 -4.7034 0.17191E-04 -4.7647 0.86843E+00 -0.0613 24 CH4,aq 0.46097E-17 -17.3363 0.46016E-17 -17.3371 0.99825E+00 -0.0008 29 CO,aq 0.12929E-18 -18.8884 0.12929E-18 -18.8884 0.10000E+01 0.0000 30 CO2,aq 0.14974E-08 -8.8247 0.14948E-08 -8.8254 0.99825E+00 -0.0008 31 CO3-2 0.66086E-05 -5.1799 0.40059E-05 -5.3973 0.60617E+00 -0.2174 32 CaCO3,aq 0.12353E-08 -8.9082 0.12353E-08 -8.9082 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41313E-11 -11.3839 0.35955E-11 -11.4442 0.87031E+00 -0.0603 34 CaCl+ 0.55387E-11 -11.2566 0.48204E-11 -11.3169 0.87031E+00 -0.0603 35 CaCl2,aq 0.13485E-15 -15.8701 0.13485E-15 -15.8701 0.10000E+01 0.0000 36 CaOH+ 0.15594E-07 -7.8070 0.13572E-07 -7.8674 0.87031E+00 -0.0603 37 CaSO4,aq 0.12185E-09 -9.9142 0.12185E-09 -9.9142 0.10000E+01 0.0000 38 HCl,aq 0.29563E-14 -14.5293 0.29563E-14 -14.5293 0.10000E+01 0.0000 43 FeCl+ 0.15615E-16 -16.8065 0.13590E-16 -16.8668 0.87031E+00 -0.0603 46 FeO,aq 0.16783E-09 -9.7751 0.16783E-09 -9.7751 0.10000E+01 0.0000 47 FeOH+ 0.21148E-10 -10.6747 0.18405E-10 -10.7351 0.87031E+00 -0.0603 48 HFeO2- 0.15874E-07 -7.7993 0.13800E-07 -7.8601 0.86934E+00 -0.0608 49 FeO+ 0.88802E-15 -15.0516 0.77286E-15 -15.1119 0.87031E+00 -0.0603 51 FeO2- 0.10211E-07 -7.9909 0.88771E-08 -8.0517 0.86934E+00 -0.0608 52 HFeO2,aq 0.14533E-09 -9.8377 0.14533E-09 -9.8377 0.10000E+01 0.0000 53 H2,aq 0.33643E-08 -8.4731 0.33584E-08 -8.4739 0.99825E+00 -0.0008 54 KCl,aq 0.14932E-09 -9.8259 0.14932E-09 -9.8259 0.10000E+01 0.0000 55 KHSO4,aq 0.38162E-18 -18.4184 0.38162E-18 -18.4184 0.10000E+01 0.0000 56 KOH,aq 0.23391E-06 -6.6309 0.23391E-06 -6.6309 0.10000E+01 0.0000 57 KSO4- 0.19320E-07 -7.7140 0.16796E-07 -7.7748 0.86934E+00 -0.0608 58 MgCO3,aq 0.20062E-12 -12.6976 0.20062E-12 -12.6976 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27381E-14 -14.5626 0.23830E-14 -14.6229 0.87031E+00 -0.0603 60 MgCl+ 0.32681E-14 -14.4857 0.28442E-14 -14.5460 0.87031E+00 -0.0603 61 MgOH+ 0.56151E-10 -10.2506 0.48869E-10 -10.3110 0.87031E+00 -0.0603 63 MnO,aq 0.79796E-09 -9.0980 0.79796E-09 -9.0980 0.10000E+01 0.0000 64 MnOH+ 0.34990E-09 -9.4561 0.30452E-09 -9.5164 0.87031E+00 -0.0603 65 MnO2-2 0.26606E-11 -11.5750 0.16128E-11 -11.7924 0.60617E+00 -0.2174 66 HMnO2- 0.52577E-10 -10.2792 0.45708E-10 -10.3400 0.86934E+00 -0.0608 69 MnCl+ 0.10807E-13 -13.9663 0.94056E-14 -14.0266 0.87031E+00 -0.0603 70 MnSO4,aq 0.56937E-13 -13.2446 0.56937E-13 -13.2446 0.10000E+01 0.0000 71 NaCl,aq 0.34940E-06 -6.4567 0.34940E-06 -6.4567 0.10000E+01 0.0000 72 NaOH,aq 0.29917E-04 -4.5241 0.29917E-04 -4.5241 0.10000E+01 0.0000 74 OH- 0.52803E-02 -2.2773 0.45855E-02 -2.3386 0.86843E+00 -0.0613 79 HPO3-2 0.54192E-17 -17.2661 0.32850E-17 -17.4835 0.60617E+00 -0.2174 82 H3PO4,aq 0.34114E-16 -16.4671 0.34114E-16 -16.4671 0.10000E+01 0.0000 83 H2PO4- 0.81649E-09 -9.0881 0.71020E-09 -9.1486 0.86982E+00 -0.0606 84 PO4-3 0.60900E-08 -8.2154 0.20674E-08 -8.6846 0.33948E+00 -0.4692 87 H2P2O7-2 0.65122E-19 -19.1863 0.39475E-19 -19.4037 0.60617E+00 -0.2174 88 HP2O7-3 0.18747E-15 -15.7271 0.61880E-16 -16.2084 0.33008E+00 -0.4814 89 P2O7-4 0.81315E-15 -15.0898 0.11670E-15 -15.9329 0.14352E+00 -0.8431 90 H2S,aq 0.50602E-14 -14.2958 0.50513E-14 -14.2966 0.99825E+00 -0.0008 97 SO3-2 0.11636E-13 -13.9342 0.71128E-14 -14.1480 0.61127E+00 -0.2138 98 HSO3- 0.62633E-16 -16.2032 0.54450E-16 -16.2640 0.86934E+00 -0.0608 99 HSO4- 0.21650E-11 -11.6645 0.18853E-11 -11.7246 0.87080E+00 -0.0601 Charge balance for all species = 0.3079E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1499424E-09 -.1080470E-01 -.1088155E+02 0.0000 2 H2O 0.1000000E+01 0.5550819E+02 0.9991760E+06 0.0000 3 Cl- 0.1382067E-03 0.1385563E-03 0.4908203E+01 5.9631 4 SO4-- 0.2559261E-04 0.2561250E-04 0.2458359E+01 14.9580 5 HCO3- 0.6513809E-05 0.1312514E-04 0.8002019E+00 4.6368 6 HS- 0.1478264E-10 -.4386985E-09 -.1449673E-04 -1.0077 7 Al+++ 0.2644849E-27 0.1979646E-04 0.5336998E+00 1.5909 8 H4SiO4 0.5613470E-03 0.5969739E-02 0.5733129E+03 -3.2508 9 Ca++ 0.4166083E-07 0.6133581E-07 0.2456199E-02 12.1677 10 Mg++ 0.2714949E-10 0.8570259E-10 0.2081891E-05 8.9806 11 Fe++ 0.1204074E-12 0.2641944E-07 0.1474236E-02 6.6278 12 K+ 0.8065583E-04 0.8090921E-04 0.3161115E+01 5.7296 13 Na+ 0.1024566E-01 0.1086816E-01 0.2496519E+03 7.8330 14 Mn++ 0.2143536E-10 0.1224604E-08 0.6722205E-04 8.8785 15 HPO4-- 0.5101955E-06 0.5171020E-06 0.4959020E-01 13.2576 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5629599E+00 -.1075931E-01 -.5522006E+00 0.0000000E+00 2 H2O 0.5508206E+02 0.5527500E+02 -.1929450E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9677327E-03 0.2550491E-04 0.9422278E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9422282E-03 -.4368556E-09 -.9422278E-03 0.0000000E+00 7 Al+++ 0.1108620E+00 0.1971330E-04 0.1108422E+00 0.0000000E+00 8 H4SiO4 0.3540242E+00 0.5944660E-02 0.3480795E+00 0.0000000E+00 9 Ca++ 0.3911817E-01 0.6107814E-07 0.3911811E-01 0.0000000E+00 10 Mg++ 0.2698333E-01 0.8534256E-10 0.2698333E-01 0.0000000E+00 11 Fe++ 0.2424158E-01 0.2630846E-07 0.2424155E-01 0.0000000E+00 12 K+ 0.7218471E-02 0.8056931E-04 0.7137902E-02 0.0000000E+00 13 Na+ 0.4283710E-01 0.1082251E-01 0.3201459E-01 0.0000000E+00 14 Mn++ 0.5894949E-03 0.1219459E-08 0.5894937E-03 0.0000000E+00 15 HPO4-- 0.2011917E-03 0.5149297E-06 0.2006768E-03 0.0000000E+00 Chg. balance for solid moles: 0.1263E-15 Mass of aqueous solution: 0.996617E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 33.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3201E-01 -1.495 8.395 0.924 22.62 3.223 andradite 0.3769E-02 -2.424 1.915 0.282 5.160 0.4976 grossular 0.1394E-03 -3.856 0.6279E-01 -1.202 0.1692 0.1747E-01 apatite-OH 0.6689E-04 -4.175 0.3360E-01 -1.474 0.9053E-01 0.1068E-01 clinochlore 0.5397E-02 -2.268 3.000 0.477 8.082 1.141 daphnite 0.2506E-02 -2.601 1.788 0.252 4.818 0.5419 chlorite-Mn 0.1179E-03 -3.928 0.8359E-01 -1.078 0.2252 0.2664E-01 microcline 0.6721E-02 -2.173 1.871 0.272 5.040 0.7307 stilbite 0.2706E-01 -1.568 19.07 1.280 51.37 8.894 stilpnomelane-Fe 0.8343E-03 -3.079 0.8994 -0.046 2.423 0.3107 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9643E+00 0.9643E+00 1.0000 -0.016 grossular 0.3567E-01 0.3567E-01 1.0000 -1.448 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6728E+00 0.6728E+00 1.0000 -0.172 daphnite 0.3125E+00 0.3125E+00 1.0000 -0.505 chlorite-Mn 0.1470E-01 0.1470E-01 1.0000 -1.833 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 37.116986 g Volume = 15.393329 cm3 Porosity: -5.4366% V(tot) - V(min): -.79373E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 33.9990000 g log = 1.5315 Original solution: 1000.0103000 g Original solution / Rock added: 29.41 (Water/Rock Ratio), log = 1.4685 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1615E-06 1.0073 0.1711E-06 0.1699E-06 CH4,gas 0.6829E-14 1.0129 0.7277E-14 0.7184E-14 H2,gas 0.4376E-05 1.0006 0.4606E-05 0.4604E-05 H2S,gas 0.1406E-12 0.9959 0.1473E-12 0.1479E-12 S2,gas 0.3642E-34 1.0000 0.3831E-34 0.3831E-34 CO,gas 0.1941E-15 1.0000 0.2042E-15 0.2042E-15 SO3,gas 0.9446E-40 1.0000 0.9936E-40 0.9936E-40 SO2,gas 0.1646E-22 1.0000 0.1732E-22 0.1732E-22 HCl,gas 0.4962E-17 1.0000 0.5220E-17 0.5220E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.13 -8.77 -2.922 0.14969E+05 -6.767 3 CH4,gas 4.81 -11.33 -16.14 -4.035 0.27555E+05 -14.138 4 H2,gas 8.29 0.95 -7.34 -4.192 0.12527E+05 -5.337 5 H2S,gas -5.94 -20.77 -14.83 -7.416 0.25325E+05 -12.832 6 S2,gas -7.03 -43.45 -36.42 -5.603 0.62180E+05 -34.417 7 CO,gas 3.51 -14.18 -17.69 -5.443 0.30205E+05 -15.690 8 SO3,gas 17.43 -24.58 -42.00 -10.501 0.71719E+05 -40.003 9 SO2,gas 1.14 -23.63 -24.76 -6.603 0.42280E+05 -22.762 10 HCl,gas 5.48 -13.80 -19.28 -9.641 0.32924E+05 -17.282 11 acmite 7.74 7.48 -0.25 -0.026 0.43238E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.06 -4.49 -0.224 0.76580E+04 20 analcite 3.37 2.92 -0.45 -0.050 0.76534E+03 26 annite 20.21 17.45 -2.76 -0.153 0.47088E+04 27 phlogopite 27.15 24.51 -2.64 -0.146 0.45018E+04 29 anorthite 12.80 8.85 -3.95 -0.304 0.67440E+04 35 aragonite 0.99 -2.96 -3.95 -1.316 0.67419E+04 36 brucite 12.58 8.98 -3.60 -0.719 0.61400E+04 37 calcite 0.83 -2.96 -3.80 -1.265 0.64805E+04 38 carnegieite-low 9.06 6.17 -2.89 -0.413 0.49369E+04 39 carnegieite-high 10.13 6.17 -3.96 -0.566 0.67638E+04 40 carpholite-Mg 8.65 5.66 -2.99 -0.199 0.51045E+04 41 carpholite-Fe 6.78 3.31 -3.47 -0.232 0.59332E+04 42 celadonite 5.40 3.30 -2.10 -0.124 0.35899E+04 43 celadonite-Fe 3.94 0.95 -2.99 -0.176 0.51083E+04 44 chrysotile 23.94 20.44 -3.50 -0.291 0.59711E+04 50 chloritoid-Mg 13.26 8.91 -4.35 -0.290 0.74268E+04 51 chloritoid-Fe 9.24 6.56 -2.68 -0.179 0.45758E+04 52 chloritoid-Mn 11.46 8.81 -2.65 -0.177 0.45312E+04 54 coesite -2.37 -3.25 -0.88 -0.294 0.15050E+04 61 cristobalite -2.55 -3.25 -0.70 -0.234 0.11979E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.59 -1.31 -0.218 0.22286E+04 67 diopside 16.22 14.65 -1.57 -0.157 0.26784E+04 68 hedenbergite 14.24 12.29 -1.95 -0.195 0.33303E+04 75 epidote 24.78 23.92 -0.86 -0.042 0.14643E+04 76 clinozoisite 22.92 19.36 -3.57 -0.162 0.60877E+04 77 epidote-Fe 29.94 28.48 -1.46 -0.076 0.24885E+04 78 fayalite 14.08 10.00 -4.07 -0.582 0.69565E+04 79 ferrosilite 11.19 6.75 -4.43 -0.443 0.75704E+04 83 gibbsite 4.10 1.59 -2.51 -0.358 0.42798E+04 84 glaucophane 23.11 19.78 -3.33 -0.090 0.56807E+04 85 glaucophane-Fe 17.42 12.73 -4.69 -0.127 0.80116E+04 87 greenalite 16.19 13.38 -2.81 -0.234 0.48021E+04 90 hematite 12.60 12.31 -0.29 -0.035 0.49912E+03 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.92 -1.33 -0.133 0.22684E+04 96 julgoldite 70.57 67.03 -3.54 -0.092 0.60451E+04 97 kalsilite 7.62 4.07 -3.55 -0.507 0.60624E+04 98 kaolinite -1.27 -3.32 -2.05 -0.186 0.34945E+04 101 laumontite 2.97 2.35 -0.63 -0.042 0.10725E+04 102 lawsonite 9.68 8.85 -0.83 -0.055 0.14179E+04 103 leucite 4.17 0.82 -3.35 -0.335 0.57178E+04 105 lizardite 23.29 20.44 -2.85 -0.237 0.48614E+04 107 magnetite 20.13 18.93 -1.20 -0.098 0.20485E+04 108 minnesotaite 10.46 6.88 -3.58 -0.211 0.61135E+04 110 magnesioferrite 26.26 21.29 -4.97 -0.406 0.84885E+04 120 muscovite 2.68 0.75 -1.93 -0.113 0.32941E+04 121 paragonite 4.34 2.85 -1.48 -0.087 0.25325E+04 122 nepheline 8.38 6.17 -2.20 -0.315 0.37649E+04 134 phlogopite-Na 29.73 26.61 -3.12 -0.173 0.53237E+04 136 prehnite 19.47 17.76 -1.70 -0.100 0.29051E+04 137 prehnite-Fe 22.59 22.33 -0.26 -0.016 0.44404E+03 138 pumpellyite-Fe 46.47 43.75 -2.72 -0.060 0.46477E+04 139 pumpellyite-Mg 49.19 46.10 -3.09 -0.069 0.52806E+04 145 pyroxmangite 7.42 5.63 -1.79 -0.358 0.30535E+04 146 pyrophyllite -6.10 -9.82 -3.72 -0.233 0.63574E+04 147 quartz -2.98 -3.25 -0.27 -0.090 0.45892E+03 152 rhodonite 7.46 5.63 -1.83 -0.367 0.31328E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 24.94 -2.65 -0.079 0.45295E+04 171 talc 16.55 13.94 -2.61 -0.154 0.44644E+04 174 tephroite 18.11 14.51 -3.61 -0.515 0.61584E+04 177 topaz-H 4.67 -0.07 -4.74 -0.431 0.80875E+04 178 tridymite -2.61 -3.25 -0.64 -0.212 0.10862E+04 179 tremolite 48.00 43.23 -4.77 -0.129 0.81460E+04 187 wairakite 4.06 2.35 -1.71 -0.101 0.29233E+04 188 walstromite 11.53 8.92 -2.61 -0.522 0.44580E+04 189 wollastonite 10.48 8.92 -1.56 -0.313 0.26719E+04 190 pseudo-wollastonite 11.02 8.92 -2.10 -0.421 0.35906E+04 191 zoisite 22.96 19.36 -3.61 -0.164 0.61602E+04 192 akaganeite 7.77 6.15 -1.62 -0.349 0.27577E+04 193 beidellite-Ca -1.56 -6.22 -4.66 -0.288 0.79503E+04 195 beidellite-K -1.44 -6.33 -4.90 -0.300 0.83628E+04 197 beidellite-Na -1.26 -5.64 -4.38 -0.268 0.74815E+04 199 chalcedony -2.79 -3.25 -0.46 -0.152 0.77923E+03 201 montmorillonite-Ca -2.21 -5.38 -3.16 -0.196 0.53973E+04 202 montmorillonite-K -2.16 -5.49 -3.33 -0.204 0.56875E+04 203 montmorillonite-Mg -2.40 -5.90 -3.50 -0.216 0.59749E+04 204 montmorillonite-Na -1.96 -4.80 -2.84 -0.174 0.48444E+04 205 nontronite-Ca 3.28 2.91 -0.37 -0.024 0.63518E+03 206 nontronite-H 2.60 0.90 -1.70 -0.114 0.28955E+04 207 nontronite-K 3.40 2.79 -0.61 -0.039 0.10468E+04 208 nontronite-Mg 3.14 2.38 -0.76 -0.049 0.12934E+04 209 nontronite-Na 3.58 3.48 -0.10 -0.006 0.16722E+03 224 tobermorite 9.84 6.88 -2.95 -0.806 0.50440E+04 233 boehmite 4.43 1.59 -2.84 -0.473 0.48470E+04 235 ferrous-oxide 9.82 6.63 -3.20 -0.799 0.54578E+04 240 silica-amorphous -2.08 -3.25 -1.17 -0.390 0.19994E+04 242 an20ab80 2.08 1.51 -0.57 -0.044 0.97719E+03 243 an25ab75 2.71 1.97 -0.74 -0.057 0.12694E+04 244 an30ab70 3.34 2.42 -0.92 -0.071 0.15699E+04 245 tr.625ac.25prg.125 45.31 41.56 -3.75 -0.101 0.64047E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 33.9990000 g New total amount of reactant added: 34.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2995E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 34.9990000 Water: Moles liquid = 0.5527E+02 kg liquid = 0.9957E+00 Moles total = 0.5507E+02 kg total = 0.9921E+00 Activity = 1.0000 Stoichiometric ionic strength = .5818224E-02 Osmotic coef. = 0.9600 True ionic strength = .1058897E-01 Chg. balance for total moles = 0.2995E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14704E-09 -9.8326 0.12814E-09 -9.8923 0.87144E+00 -0.0598 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13822E-03 -3.8594 0.12002E-03 -3.9208 0.86833E+00 -0.0613 4 SO4-- 0.25595E-04 -4.5918 0.15463E-04 -4.8107 0.60415E+00 -0.2189 5 HCO3- 0.64356E-05 -5.1914 0.55930E-05 -5.2524 0.86907E+00 -0.0609 6 HS- 0.43962E-10 -10.3569 0.38177E-10 -10.4182 0.86840E+00 -0.0613 7 Al+++ 0.23991E-27 -27.6199 0.78332E-28 -28.1061 0.32650E+00 -0.4861 8 H4SiO4 0.56221E-03 -3.2501 0.56221E-03 -3.2501 0.10000E+01 0.0000 9 Ca++ 0.43569E-07 -7.3608 0.26209E-07 -7.5816 0.60154E+00 -0.2207 10 Mg++ 0.26705E-10 -10.5734 0.16021E-10 -10.7953 0.59992E+00 -0.2219 11 Fe++ 0.11746E-12 -12.9301 0.70514E-13 -13.1517 0.60030E+00 -0.2216 12 K+ 0.82449E-04 -4.0838 0.71664E-04 -4.1447 0.86920E+00 -0.0609 13 Na+ 0.10474E-01 -1.9799 0.90936E-02 -2.0413 0.86824E+00 -0.0614 14 Mn++ 0.21084E-10 -10.6760 0.12663E-10 -10.8975 0.60060E+00 -0.2214 15 HPO4-- 0.46637E-06 -6.3313 0.28178E-06 -6.5501 0.60420E+00 -0.2188 16 HSiO3- 0.49298E-02 -2.3072 0.42807E-02 -2.3685 0.86833E+00 -0.0613 17 Ca(HSiO3)+ 0.28916E-08 -8.5389 0.25137E-08 -8.5997 0.86931E+00 -0.0608 18 Mg(HSiO3)+ 0.21998E-11 -11.6576 0.19123E-11 -11.7184 0.86931E+00 -0.0608 19 NaHSiO3,aq 0.61826E-03 -3.2088 0.61826E-03 -3.2088 0.10000E+01 0.0000 20 AlO+ 0.70846E-15 -15.1497 0.61587E-15 -15.2105 0.86931E+00 -0.0608 22 HAlO2,aq 0.96178E-09 -9.0169 0.96178E-09 -9.0169 0.10000E+01 0.0000 23 AlO2- 0.19322E-04 -4.7140 0.16760E-04 -4.7757 0.86740E+00 -0.0618 24 CH4,aq 0.13574E-16 -16.8673 0.13550E-16 -16.8681 0.99821E+00 -0.0008 29 CO,aq 0.16512E-18 -18.7822 0.16512E-18 -18.7822 0.10000E+01 0.0000 30 CO2,aq 0.14476E-08 -8.8394 0.14450E-08 -8.8401 0.99821E+00 -0.0008 31 CO3-2 0.66883E-05 -5.1747 0.40357E-05 -5.3941 0.60339E+00 -0.2194 32 CaCO3,aq 0.12954E-08 -8.8876 0.12954E-08 -8.8876 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.42488E-11 -11.3717 0.36935E-11 -11.4326 0.86931E+00 -0.0608 34 CaCl+ 0.57658E-11 -11.2391 0.50123E-11 -11.3000 0.86931E+00 -0.0608 35 CaCl2,aq 0.14006E-15 -15.8537 0.14006E-15 -15.8537 0.10000E+01 0.0000 36 CaOH+ 0.16590E-07 -7.7801 0.14422E-07 -7.8410 0.86931E+00 -0.0608 37 CaSO4,aq 0.12627E-09 -9.8987 0.12627E-09 -9.8987 0.10000E+01 0.0000 38 HCl,aq 0.28927E-14 -14.5387 0.28927E-14 -14.5387 0.10000E+01 0.0000 43 FeCl+ 0.15163E-16 -16.8192 0.13181E-16 -16.8800 0.86931E+00 -0.0608 46 FeO,aq 0.16982E-09 -9.7700 0.16982E-09 -9.7700 0.10000E+01 0.0000 47 FeOH+ 0.20986E-10 -10.6781 0.18244E-10 -10.7389 0.86931E+00 -0.0608 48 HFeO2- 0.16417E-07 -7.7847 0.14255E-07 -7.8460 0.86833E+00 -0.0613 49 FeO+ 0.76672E-15 -15.1154 0.66652E-15 -15.1762 0.86931E+00 -0.0608 51 FeO2- 0.91880E-08 -8.0368 0.79781E-08 -8.0981 0.86833E+00 -0.0613 52 HFeO2,aq 0.12794E-09 -9.8930 0.12794E-09 -9.8930 0.10000E+01 0.0000 53 H2,aq 0.44447E-08 -8.3522 0.44368E-08 -8.3529 0.99821E+00 -0.0008 54 KCl,aq 0.15229E-09 -9.8173 0.15229E-09 -9.8173 0.10000E+01 0.0000 55 KHSO4,aq 0.37999E-18 -18.4202 0.37999E-18 -18.4202 0.10000E+01 0.0000 56 KOH,aq 0.24381E-06 -6.6129 0.24381E-06 -6.6129 0.10000E+01 0.0000 57 KSO4- 0.19662E-07 -7.7064 0.17073E-07 -7.7677 0.86833E+00 -0.0613 58 MgCO3,aq 0.19787E-12 -12.7036 0.19787E-12 -12.7036 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26485E-14 -14.5770 0.23024E-14 -14.6378 0.86931E+00 -0.0608 60 MgCl+ 0.31997E-14 -14.4949 0.27815E-14 -14.5557 0.86931E+00 -0.0608 61 MgOH+ 0.56185E-10 -10.2504 0.48842E-10 -10.3112 0.86931E+00 -0.0608 63 MnO,aq 0.81414E-09 -9.0893 0.81414E-09 -9.0893 0.10000E+01 0.0000 64 MnOH+ 0.35011E-09 -9.4558 0.30435E-09 -9.5166 0.86931E+00 -0.0608 65 MnO2-2 0.28419E-11 -11.5464 0.17148E-11 -11.7658 0.60339E+00 -0.2194 66 HMnO2- 0.54826E-10 -10.2610 0.47607E-10 -10.3223 0.86833E+00 -0.0613 69 MnCl+ 0.10581E-13 -13.9755 0.91982E-14 -14.0363 0.86931E+00 -0.0608 70 MnSO4,aq 0.55495E-13 -13.2557 0.55495E-13 -13.2557 0.10000E+01 0.0000 71 NaCl,aq 0.35636E-06 -6.4481 0.35636E-06 -6.4481 0.10000E+01 0.0000 72 NaOH,aq 0.31183E-04 -4.5061 0.31183E-04 -4.5061 0.10000E+01 0.0000 74 OH- 0.53968E-02 -2.2679 0.46811E-02 -2.3296 0.86740E+00 -0.0618 79 HPO3-2 0.65444E-17 -17.1841 0.39488E-17 -17.4035 0.60339E+00 -0.2194 82 H3PO4,aq 0.29787E-16 -16.5260 0.29787E-16 -16.5260 0.10000E+01 0.0000 83 H2PO4- 0.72862E-09 -9.1375 0.63303E-09 -9.1986 0.86881E+00 -0.0611 84 PO4-3 0.57133E-08 -8.2431 0.19204E-08 -8.7166 0.33613E+00 -0.4735 87 H2P2O7-2 0.51978E-19 -19.2842 0.31363E-19 -19.5036 0.60339E+00 -0.2194 88 HP2O7-3 0.15364E-15 -15.8135 0.50189E-16 -16.2994 0.32666E+00 -0.4859 89 P2O7-4 0.68566E-15 -15.1639 0.96625E-16 -16.0149 0.14092E+00 -0.8510 90 H2S,aq 0.14725E-13 -13.8320 0.14698E-13 -13.8327 0.99821E+00 -0.0008 97 SO3-2 0.15372E-13 -13.8133 0.93546E-14 -14.0290 0.60856E+00 -0.2157 98 HSO3- 0.80787E-16 -16.0927 0.70150E-16 -16.1540 0.86833E+00 -0.0613 99 HSO4- 0.21137E-11 -11.6750 0.18385E-11 -11.7355 0.86980E+00 -0.0606 Charge balance for all species = 0.3009E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1470433E-09 -.1106039E-01 -.1113885E+02 0.0000 2 H2O 0.1000000E+01 0.5550817E+02 0.9991569E+06 0.0000 3 Cl- 0.1382162E-03 0.1385728E-03 0.4908696E+01 5.9716 4 SO4-- 0.2559528E-04 0.2561513E-04 0.2458564E+01 14.9739 5 HCO3- 0.6435618E-05 0.1312670E-04 0.8002823E+00 4.6400 6 HS- 0.4396228E-10 -.9325994E-11 -.3081703E-06 -0.5259 7 Al+++ 0.2399126E-27 0.1932266E-04 0.5209168E+00 1.5709 8 H4SiO4 0.5622060E-03 0.6110316E-02 0.5868025E+03 -3.2501 9 Ca++ 0.4356889E-07 0.6448251E-07 0.2582160E-02 12.2031 10 Mg++ 0.2670548E-10 0.8529354E-10 0.2071916E-05 8.9893 11 Fe++ 0.1174644E-12 0.2592356E-07 0.1446538E-02 6.6329 12 K+ 0.8244857E-04 0.8271220E-04 0.3231497E+01 5.7476 13 Na+ 0.1047360E-01 0.1112340E-01 0.2555100E+03 7.8511 14 Mn++ 0.2108435E-10 0.1243065E-08 0.6823418E-04 8.8872 15 HPO4-- 0.4663689E-06 0.4728108E-06 0.4534182E-01 13.2346 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5795184E+00 -.1101261E-01 -.5685058E+00 0.0000000E+00 2 H2O 0.5506952E+02 0.5526839E+02 -.1988708E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9954461E-03 0.2550448E-04 0.9699416E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9699416E-03 -.9285709E-11 -.9699416E-03 0.0000000E+00 7 Al+++ 0.1141227E+00 0.1923920E-04 0.1141035E+00 0.0000000E+00 8 H4SiO4 0.3644370E+00 0.6083922E-02 0.3583531E+00 0.0000000E+00 9 Ca++ 0.4026831E-01 0.6420397E-07 0.4026825E-01 0.0000000E+00 10 Mg++ 0.2777698E-01 0.8492511E-10 0.2777698E-01 0.0000000E+00 11 Fe++ 0.2495459E-01 0.2581158E-07 0.2495456E-01 0.0000000E+00 12 K+ 0.7430786E-02 0.8235491E-04 0.7348431E-02 0.0000000E+00 13 Na+ 0.4409234E-01 0.1107535E-01 0.3301699E-01 0.0000000E+00 14 Mn++ 0.6068335E-03 0.1237695E-08 0.6068323E-03 0.0000000E+00 15 HPO4-- 0.2071093E-03 0.4707685E-06 0.2066385E-03 0.0000000E+00 Chg. balance for solid moles: -.1171E-16 Mass of aqueous solution: 0.996517E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 34.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3302E-01 -1.481 8.658 0.937 22.66 3.323 andradite 0.3880E-02 -2.411 1.972 0.295 5.160 0.5122 grossular 0.1557E-03 -3.808 0.7011E-01 -1.154 0.1835 0.1951E-01 apatite-OH 0.6888E-04 -4.162 0.3460E-01 -1.461 0.9055E-01 0.1099E-01 clinochlore 0.5555E-02 -2.255 3.088 0.490 8.081 1.175 daphnite 0.2559E-02 -2.592 1.826 0.261 4.779 0.5533 chlorite-Mn 0.1214E-03 -3.916 0.8605E-01 -1.065 0.2252 0.2742E-01 microcline 0.6908E-02 -2.161 1.923 0.284 5.033 0.7511 stilbite 0.2782E-01 -1.556 19.60 1.292 51.31 9.143 stilpnomelane-Fe 0.8800E-03 -3.056 0.9486 -0.023 2.483 0.3277 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9614E+00 0.9614E+00 1.0000 -0.017 grossular 0.3857E-01 0.3857E-01 1.0000 -1.414 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6745E+00 0.6745E+00 1.0000 -0.171 daphnite 0.3107E+00 0.3107E+00 1.0000 -0.508 chlorite-Mn 0.1474E-01 0.1474E-01 1.0000 -1.832 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 38.208968 g Volume = 15.843785 cm3 Porosity: -5.6281% V(tot) - V(min): -.84419E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 34.9990000 g log = 1.5441 Original solution: 1000.0103000 g Original solution / Rock added: 28.57 (Water/Rock Ratio), log = 1.4559 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1561E-06 1.0073 0.1654E-06 0.1642E-06 CH4,gas 0.2011E-13 1.0129 0.2143E-13 0.2115E-13 H2,gas 0.5782E-05 1.0006 0.6085E-05 0.6082E-05 H2S,gas 0.4092E-12 0.9959 0.4287E-12 0.4304E-12 S2,gas 0.1767E-33 1.0000 0.1859E-33 0.1859E-33 CO,gas 0.2479E-15 1.0000 0.2607E-15 0.2607E-15 SO3,gas 0.9024E-40 1.0000 0.9492E-40 0.9492E-40 SO2,gas 0.2077E-22 1.0000 0.2185E-22 0.2185E-22 HCl,gas 0.4855E-17 1.0000 0.5108E-17 0.5108E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 -0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.14 -8.78 -2.927 0.14994E+05 -6.781 3 CH4,gas 4.81 -10.86 -15.67 -3.917 0.26754E+05 -13.669 4 H2,gas 8.29 1.07 -7.22 -4.123 0.12321E+05 -5.216 5 H2S,gas -5.94 -20.31 -14.37 -7.184 0.24533E+05 -12.368 6 S2,gas -7.03 -42.76 -35.73 -5.497 0.61009E+05 -33.731 7 CO,gas 3.51 -14.07 -17.58 -5.410 0.30024E+05 -15.584 8 SO3,gas 17.43 -24.60 -42.02 -10.506 0.71752E+05 -40.023 9 SO2,gas 1.14 -23.52 -24.66 -6.576 0.42107E+05 -22.661 10 HCl,gas 5.48 -13.81 -19.29 -9.646 0.32940E+05 -17.292 11 acmite 7.74 7.45 -0.29 -0.030 0.49384E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.05 -4.50 -0.225 0.76783E+04 20 analcite 3.37 2.92 -0.45 -0.050 0.76647E+03 26 annite 20.21 17.47 -2.74 -0.152 0.46825E+04 27 phlogopite 27.15 24.54 -2.61 -0.145 0.44572E+04 29 anorthite 12.80 8.84 -3.95 -0.304 0.67497E+04 35 aragonite 0.99 -2.94 -3.93 -1.309 0.67066E+04 36 brucite 12.58 8.99 -3.59 -0.717 0.61252E+04 37 calcite 0.83 -2.94 -3.77 -1.258 0.64453E+04 38 carnegieite-low 9.06 6.17 -2.89 -0.413 0.49392E+04 39 carnegieite-high 10.13 6.17 -3.96 -0.566 0.67661E+04 40 carpholite-Mg 8.65 5.63 -3.02 -0.201 0.51556E+04 41 carpholite-Fe 6.78 3.27 -3.51 -0.234 0.59905E+04 42 celadonite 5.40 3.31 -2.09 -0.123 0.35739E+04 43 celadonite-Fe 3.94 0.95 -2.99 -0.176 0.50984E+04 44 chrysotile 23.94 20.47 -3.47 -0.289 0.59242E+04 50 chloritoid-Mg 13.26 8.88 -4.38 -0.292 0.74791E+04 51 chloritoid-Fe 9.24 6.52 -2.71 -0.181 0.46342E+04 52 chloritoid-Mn 11.46 8.78 -2.68 -0.179 0.45834E+04 54 coesite -2.37 -3.25 -0.88 -0.294 0.15039E+04 61 cristobalite -2.55 -3.25 -0.70 -0.234 0.11968E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.57 -1.33 -0.221 0.22627E+04 67 diopside 16.22 14.69 -1.52 -0.152 0.26009E+04 68 hedenbergite 14.24 12.34 -1.91 -0.191 0.32589E+04 75 epidote 24.78 23.89 -0.88 -0.043 0.15030E+04 76 clinozoisite 22.92 19.37 -3.55 -0.161 0.60660E+04 77 epidote-Fe 29.94 28.42 -1.52 -0.079 0.25875E+04 78 fayalite 14.08 10.02 -4.06 -0.580 0.69379E+04 79 ferrosilite 11.19 6.77 -4.42 -0.442 0.75506E+04 83 gibbsite 4.10 1.57 -2.53 -0.361 0.43139E+04 84 glaucophane 23.11 19.81 -3.30 -0.089 0.56338E+04 85 glaucophane-Fe 17.42 12.74 -4.68 -0.126 0.79831E+04 87 greenalite 16.19 13.40 -2.80 -0.233 0.47735E+04 90 hematite 12.60 12.19 -0.40 -0.049 0.68807E+03 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.92 -1.33 -0.133 0.22695E+04 96 julgoldite 70.57 66.97 -3.61 -0.094 0.61572E+04 97 kalsilite 7.62 4.07 -3.55 -0.507 0.60647E+04 98 kaolinite -1.27 -3.36 -2.09 -0.190 0.35605E+04 101 laumontite 2.97 2.34 -0.63 -0.042 0.10759E+04 102 lawsonite 9.68 8.84 -0.83 -0.056 0.14235E+04 103 leucite 4.17 0.82 -3.35 -0.335 0.57189E+04 105 lizardite 23.29 20.47 -2.82 -0.235 0.48145E+04 107 magnetite 20.13 18.83 -1.31 -0.107 0.22286E+04 108 minnesotaite 10.46 6.90 -3.56 -0.210 0.60827E+04 120 muscovite 2.68 0.71 -1.97 -0.116 0.33623E+04 121 paragonite 4.34 2.81 -1.52 -0.090 0.26008E+04 122 nepheline 8.38 6.17 -2.21 -0.315 0.37672E+04 134 phlogopite-Na 29.73 26.64 -3.09 -0.172 0.52791E+04 136 prehnite 19.47 17.80 -1.67 -0.098 0.28492E+04 137 prehnite-Fe 22.59 22.32 -0.26 -0.016 0.44855E+03 138 pumpellyite-Fe 46.47 43.80 -2.67 -0.059 0.45614E+04 139 pumpellyite-Mg 49.19 46.16 -3.04 -0.068 0.51882E+04 145 pyroxmangite 7.42 5.64 -1.78 -0.356 0.30375E+04 146 pyrophyllite -6.10 -9.86 -3.76 -0.235 0.64211E+04 147 quartz -2.98 -3.25 -0.27 -0.089 0.45778E+03 152 rhodonite 7.46 5.64 -1.83 -0.365 0.31168E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 24.96 -2.63 -0.079 0.44989E+04 171 talc 16.55 13.97 -2.59 -0.152 0.44152E+04 174 tephroite 18.11 14.52 -3.59 -0.513 0.61275E+04 177 topaz-H 4.67 -0.11 -4.78 -0.434 0.81547E+04 178 tridymite -2.61 -3.25 -0.64 -0.212 0.10851E+04 179 tremolite 48.00 43.35 -4.65 -0.126 0.79418E+04 187 wairakite 4.06 2.34 -1.71 -0.101 0.29267E+04 188 walstromite 11.53 8.95 -2.57 -0.515 0.43966E+04 189 wollastonite 10.48 8.95 -1.53 -0.306 0.26105E+04 190 pseudo-wollastonite 11.02 8.95 -2.07 -0.413 0.35291E+04 191 zoisite 22.96 19.37 -3.60 -0.163 0.61385E+04 192 akaganeite 7.77 6.10 -1.67 -0.361 0.28522E+04 193 beidellite-Ca -1.56 -6.25 -4.69 -0.290 0.80158E+04 195 beidellite-K -1.44 -6.37 -4.94 -0.302 0.84280E+04 197 beidellite-Na -1.26 -5.68 -4.42 -0.271 0.75467E+04 199 chalcedony -2.79 -3.25 -0.46 -0.152 0.77810E+03 201 montmorillonite-Ca -2.21 -5.40 -3.18 -0.197 0.54349E+04 202 montmorillonite-K -2.16 -5.51 -3.35 -0.205 0.57249E+04 203 montmorillonite-Mg -2.40 -5.93 -3.53 -0.218 0.60200E+04 204 montmorillonite-Na -1.96 -4.82 -2.86 -0.175 0.48818E+04 205 nontronite-Ca 3.28 2.80 -0.48 -0.031 0.82128E+03 206 nontronite-H 2.60 0.79 -1.81 -0.121 0.30915E+04 207 nontronite-K 3.40 2.68 -0.72 -0.046 0.12327E+04 208 nontronite-Mg 3.14 2.27 -0.87 -0.056 0.14870E+04 209 nontronite-Na 3.58 3.38 -0.21 -0.013 0.35313E+03 224 tobermorite 9.84 6.92 -2.92 -0.798 0.49926E+04 233 boehmite 4.43 1.57 -2.86 -0.476 0.48812E+04 235 ferrous-oxide 9.82 6.63 -3.19 -0.798 0.54491E+04 240 silica-amorphous -2.08 -3.25 -1.17 -0.390 0.19983E+04 242 an20ab80 2.08 1.51 -0.57 -0.044 0.97832E+03 243 an25ab75 2.71 1.96 -0.74 -0.057 0.12708E+04 244 an30ab70 3.34 2.42 -0.92 -0.071 0.15716E+04 245 tr.625ac.25prg.125 45.31 41.67 -3.64 -0.098 0.62192E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 34.9990000 g New total amount of reactant added: 35.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2996E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 35.9990000 Water: Moles liquid = 0.5526E+02 kg liquid = 0.9956E+00 Moles total = 0.5506E+02 kg total = 0.9919E+00 Activity = 1.0000 Stoichiometric ionic strength = .5942376E-02 Osmotic coef. = 0.9596 True ionic strength = .1081419E-01 Chg. balance for total moles = 0.2996E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14434E-09 -9.8406 0.12565E-09 -9.9008 0.87050E+00 -0.0602 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13823E-03 -3.8594 0.11989E-03 -3.9212 0.86734E+00 -0.0618 4 SO4-- 0.25598E-04 -4.5918 0.15397E-04 -4.8126 0.60149E+00 -0.2208 5 HCO3- 0.63612E-05 -5.1965 0.55222E-05 -5.2579 0.86810E+00 -0.0614 6 HS- 0.12446E-09 -9.9050 0.10796E-09 -9.9667 0.86742E+00 -0.0618 7 Al+++ 0.21844E-27 -27.6607 0.70606E-28 -28.1512 0.32322E+00 -0.4905 8 H4SiO4 0.56323E-03 -3.2493 0.56323E-03 -3.2493 0.10000E+01 0.0000 9 Ca++ 0.45466E-07 -7.3423 0.27227E-07 -7.5650 0.59884E+00 -0.2227 10 Mg++ 0.26304E-10 -10.5800 0.15709E-10 -10.8039 0.59719E+00 -0.2239 11 Fe++ 0.11473E-12 -12.9403 0.68563E-13 -13.1639 0.59759E+00 -0.2236 12 K+ 0.84206E-04 -4.0747 0.73110E-04 -4.1360 0.86823E+00 -0.0614 13 Na+ 0.10697E-01 -1.9707 0.92770E-02 -2.0326 0.86726E+00 -0.0619 14 Mn++ 0.20767E-10 -10.6826 0.12416E-10 -10.9060 0.59788E+00 -0.2234 15 HPO4-- 0.42826E-06 -6.3683 0.25761E-06 -6.5890 0.60154E+00 -0.2207 16 HSiO3- 0.50423E-02 -2.2974 0.43734E-02 -2.3592 0.86734E+00 -0.0618 17 Ca(HSiO3)+ 0.30724E-08 -8.5125 0.26679E-08 -8.5738 0.86834E+00 -0.0613 18 Mg(HSiO3)+ 0.22061E-11 -11.6564 0.19156E-11 -11.7177 0.86834E+00 -0.0613 19 NaHSiO3,aq 0.64438E-03 -3.1909 0.64438E-03 -3.1909 0.10000E+01 0.0000 20 AlO+ 0.66486E-15 -15.1773 0.57733E-15 -15.2386 0.86834E+00 -0.0613 22 HAlO2,aq 0.91944E-09 -9.0365 0.91944E-09 -9.0365 0.10000E+01 0.0000 23 AlO2- 0.18858E-04 -4.7245 0.16339E-04 -4.7868 0.86640E+00 -0.0623 24 CH4,aq 0.38065E-16 -16.4195 0.37996E-16 -16.4203 0.99817E+00 -0.0008 29 CO,aq 0.20855E-18 -18.6808 0.20855E-18 -18.6808 0.10000E+01 0.0000 30 CO2,aq 0.14015E-08 -8.8534 0.13990E-08 -8.8542 0.99817E+00 -0.0008 31 CO3-2 0.67643E-05 -5.1698 0.40634E-05 -5.3911 0.60072E+00 -0.2213 32 CaCO3,aq 0.13550E-08 -8.8681 0.13550E-08 -8.8681 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43628E-11 -11.3602 0.37884E-11 -11.4215 0.86834E+00 -0.0613 34 CaCl+ 0.59902E-11 -11.2226 0.52015E-11 -11.2839 0.86834E+00 -0.0613 35 CaCl2,aq 0.14520E-15 -15.8380 0.14520E-15 -15.8380 0.10000E+01 0.0000 36 CaOH+ 0.17596E-07 -7.7546 0.15279E-07 -7.8159 0.86834E+00 -0.0613 37 CaSO4,aq 0.13062E-09 -9.8840 0.13062E-09 -9.8840 0.10000E+01 0.0000 38 HCl,aq 0.28335E-14 -14.5477 0.28335E-14 -14.5477 0.10000E+01 0.0000 43 FeCl+ 0.14744E-16 -16.8314 0.12803E-16 -16.8927 0.86834E+00 -0.0613 46 FeO,aq 0.17173E-09 -9.7652 0.17173E-09 -9.7652 0.10000E+01 0.0000 47 FeOH+ 0.20833E-10 -10.6813 0.18090E-10 -10.7426 0.86834E+00 -0.0613 48 HFeO2- 0.16949E-07 -7.7709 0.14700E-07 -7.8327 0.86734E+00 -0.0618 49 FeO+ 0.66637E-15 -15.1763 0.57864E-15 -15.2376 0.86834E+00 -0.0613 51 FeO2- 0.83049E-08 -8.0807 0.72031E-08 -8.1425 0.86734E+00 -0.0618 52 HFeO2,aq 0.11327E-09 -9.9459 0.11327E-09 -9.9459 0.10000E+01 0.0000 53 H2,aq 0.57987E-08 -8.2367 0.57881E-08 -8.2375 0.99817E+00 -0.0008 54 KCl,aq 0.15520E-09 -9.8091 0.15520E-09 -9.8091 0.10000E+01 0.0000 55 KHSO4,aq 0.37849E-18 -18.4219 0.37849E-18 -18.4219 0.10000E+01 0.0000 56 KOH,aq 0.25365E-06 -6.5958 0.25365E-06 -6.5958 0.10000E+01 0.0000 57 KSO4- 0.19995E-07 -7.6991 0.17342E-07 -7.7609 0.86734E+00 -0.0618 58 MgCO3,aq 0.19535E-12 -12.7092 0.19535E-12 -12.7092 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.25668E-14 -14.5906 0.22289E-14 -14.6519 0.86834E+00 -0.0613 60 MgCl+ 0.31375E-14 -14.5034 0.27244E-14 -14.5647 0.86834E+00 -0.0613 61 MgOH+ 0.56242E-10 -10.2499 0.48838E-10 -10.3112 0.86834E+00 -0.0613 63 MnO,aq 0.83018E-09 -9.0808 0.83018E-09 -9.0808 0.10000E+01 0.0000 64 MnOH+ 0.35047E-09 -9.4554 0.30433E-09 -9.5167 0.86834E+00 -0.0613 65 MnO2-2 0.30272E-11 -11.5190 0.18185E-11 -11.7403 0.60072E+00 -0.2213 66 HMnO2- 0.57078E-10 -10.2435 0.49506E-10 -10.3053 0.86734E+00 -0.0618 69 MnCl+ 0.10375E-13 -13.9840 0.90093E-14 -14.0453 0.86834E+00 -0.0613 70 MnSO4,aq 0.54178E-13 -13.2662 0.54178E-13 -13.2662 0.10000E+01 0.0000 71 NaCl,aq 0.36317E-06 -6.4399 0.36317E-06 -6.4399 0.10000E+01 0.0000 72 NaOH,aq 0.32442E-04 -4.4889 0.32442E-04 -4.4889 0.10000E+01 0.0000 74 OH- 0.55099E-02 -2.2589 0.47738E-02 -2.3211 0.86640E+00 -0.0623 79 HPO3-2 0.78400E-17 -17.1057 0.47096E-17 -17.3270 0.60072E+00 -0.2213 82 H3PO4,aq 0.26185E-16 -16.5819 0.26185E-16 -16.5819 0.10000E+01 0.0000 83 H2PO4- 0.65393E-09 -9.1845 0.56750E-09 -9.2460 0.86783E+00 -0.0616 84 PO4-3 0.53779E-08 -8.2694 0.17905E-08 -8.7470 0.33293E+00 -0.4776 87 H2P2O7-2 0.41960E-19 -19.3772 0.25206E-19 -19.5985 0.60072E+00 -0.2213 88 HP2O7-3 0.12720E-15 -15.8955 0.41134E-16 -16.3858 0.32339E+00 -0.4903 89 P2O7-4 0.58328E-15 -15.2341 0.80761E-16 -16.0928 0.13846E+00 -0.8587 90 H2S,aq 0.40834E-13 -13.3890 0.40759E-13 -13.3898 0.99817E+00 -0.0008 97 SO3-2 0.20053E-13 -13.6978 0.12151E-13 -13.9154 0.60596E+00 -0.2176 98 HSO3- 0.10302E-15 -15.9871 0.89351E-16 -16.0489 0.86734E+00 -0.0618 99 HSO4- 0.20660E-11 -11.6849 0.17951E-11 -11.7459 0.86884E+00 -0.0611 101 S2O3-2 0.12312E-19 -19.9097 0.73961E-20 -20.1310 0.60072E+00 -0.2213 Charge balance for all species = 0.3010E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1443436E-09 -.1131164E-01 -.1139167E+02 0.0000 2 H2O 0.1000000E+01 0.5550814E+02 0.9991379E+06 0.0000 3 Cl- 0.1382259E-03 0.1385892E-03 0.4909189E+01 5.9796 4 SO4-- 0.2559791E-04 0.2561764E-04 0.2458760E+01 14.9891 5 HCO3- 0.6361193E-05 0.1312826E-04 0.8003626E+00 4.6429 6 HS- 0.1244644E-09 0.5219072E-09 0.1724571E-04 -0.0659 7 Al+++ 0.2184445E-27 0.1885927E-04 0.5084149E+00 1.5513 8 H4SiO4 0.5632293E-03 0.6249920E-02 0.6001982E+03 -3.2493 9 Ca++ 0.4546610E-07 0.6763027E-07 0.2708161E-02 12.2367 10 Mg++ 0.2630416E-10 0.8495350E-10 0.2063617E-05 8.9978 11 Fe++ 0.1147337E-12 0.2555932E-07 0.1426187E-02 6.6378 12 K+ 0.8420569E-04 0.8447949E-04 0.3300483E+01 5.7648 13 Na+ 0.1069702E-01 0.1137421E-01 0.2612665E+03 7.8682 14 Mn++ 0.2076709E-10 0.1261585E-08 0.6924947E-04 8.8957 15 HPO4-- 0.4282567E-06 0.4342885E-06 0.4164682E-01 13.2126 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5960770E+00 -.1126144E-01 -.5848155E+00 0.0000000E+00 2 H2O 0.5505699E+02 0.5526180E+02 -.2048135E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1023159E-02 0.2550395E-04 0.9976555E-03 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9976550E-03 0.5195910E-09 -.9976555E-03 0.0000000E+00 7 Al+++ 0.1173834E+00 0.1877557E-04 0.1173647E+00 0.0000000E+00 8 H4SiO4 0.3748498E+00 0.6222183E-02 0.3686276E+00 0.0000000E+00 9 Ca++ 0.4141846E-01 0.6733013E-07 0.4141839E-01 0.0000000E+00 10 Mg++ 0.2857063E-01 0.8457648E-10 0.2857063E-01 0.0000000E+00 11 Fe++ 0.2566760E-01 0.2544589E-07 0.2566757E-01 0.0000000E+00 12 K+ 0.7643100E-02 0.8410457E-04 0.7558995E-02 0.0000000E+00 13 Na+ 0.4534759E-01 0.1132373E-01 0.3402385E-01 0.0000000E+00 14 Mn++ 0.6241721E-03 0.1255986E-08 0.6241709E-03 0.0000000E+00 15 HPO4-- 0.2130268E-03 0.4323612E-06 0.2125945E-03 0.0000000E+00 Chg. balance for solid moles: -.2049E-16 Mass of aqueous solution: 0.996417E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 35.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3402E-01 -1.468 8.922 0.950 22.70 3.425 andradite 0.3991E-02 -2.399 2.028 0.307 5.160 0.5269 grossular 0.1729E-03 -3.762 0.7787E-01 -1.109 0.1981 0.2167E-01 apatite-OH 0.7086E-04 -4.150 0.3560E-01 -1.449 0.9058E-01 0.1131E-01 clinochlore 0.5714E-02 -2.243 3.176 0.502 8.081 1.208 daphnite 0.2610E-02 -2.583 1.862 0.270 4.739 0.5644 chlorite-Mn 0.1248E-03 -3.904 0.8850E-01 -1.053 0.2252 0.2820E-01 microcline 0.7095E-02 -2.149 1.975 0.296 5.025 0.7715 stilbite 0.2857E-01 -1.544 20.14 1.304 51.24 9.392 stilpnomelane-Fe 0.9271E-03 -3.033 0.9994 0.000 2.543 0.3452 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9585E+00 0.9585E+00 1.0000 -0.018 grossular 0.4152E-01 0.4152E-01 1.0000 -1.382 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6763E+00 0.6763E+00 1.0000 -0.170 daphnite 0.3089E+00 0.3089E+00 1.0000 -0.510 chlorite-Mn 0.1477E-01 0.1477E-01 1.0000 -1.830 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 39.300842 g Volume = 16.294008 cm3 Porosity: -5.8080% V(tot) - V(min): -.89441E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 35.9990000 g log = 1.5563 Original solution: 1000.0103000 g Original solution / Rock added: 27.78 (Water/Rock Ratio), log = 1.4437 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1511E-06 1.0073 0.1601E-06 0.1590E-06 CH4,gas 0.5639E-13 1.0129 0.6009E-13 0.5932E-13 H2,gas 0.7543E-05 1.0006 0.7939E-05 0.7934E-05 H2S,gas 0.1135E-11 0.9959 0.1189E-11 0.1194E-11 S2,gas 0.7984E-33 1.0000 0.8398E-33 0.8398E-33 CO,gas 0.3130E-15 1.0000 0.3293E-15 0.3293E-15 SO3,gas 0.8639E-40 1.0000 0.9088E-40 0.9088E-40 SO2,gas 0.2595E-22 1.0000 0.2729E-22 0.2729E-22 HCl,gas 0.4756E-17 1.0000 0.5003E-17 0.5003E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.48529E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.16 -8.80 -2.932 0.15018E+05 -6.796 3 CH4,gas 4.81 -10.41 -15.22 -3.805 0.25990E+05 -13.221 4 H2,gas 8.29 1.19 -7.10 -4.057 0.12123E+05 -5.100 5 H2S,gas -5.94 -19.87 -13.92 -6.962 0.23776E+05 -11.925 6 S2,gas -7.03 -42.11 -35.08 -5.396 0.59891E+05 -33.076 7 CO,gas 3.51 -13.97 -17.48 -5.379 0.29851E+05 -15.482 8 SO3,gas 17.43 -24.61 -42.04 -10.510 0.71785E+05 -40.042 9 SO2,gas 1.14 -23.43 -24.56 -6.550 0.41942E+05 -22.564 10 HCl,gas 5.48 -13.82 -19.30 -9.650 0.32956E+05 -17.301 11 acmite 7.74 7.41 -0.32 -0.034 0.55212E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.04 -4.51 -0.225 0.76976E+04 20 analcite 3.37 2.92 -0.45 -0.050 0.76782E+03 26 annite 20.21 17.48 -2.73 -0.152 0.46577E+04 27 phlogopite 27.15 24.56 -2.58 -0.144 0.44138E+04 29 anorthite 12.80 8.84 -3.96 -0.304 0.67564E+04 35 aragonite 0.99 -2.92 -3.91 -1.303 0.66733E+04 36 brucite 12.58 9.00 -3.58 -0.716 0.61107E+04 37 calcite 0.83 -2.92 -3.76 -1.252 0.64119E+04 38 carnegieite-low 9.06 6.17 -2.89 -0.413 0.49419E+04 39 carnegieite-high 10.13 6.17 -3.96 -0.566 0.67688E+04 40 carpholite-Mg 8.65 5.60 -3.05 -0.203 0.52053E+04 41 carpholite-Fe 6.78 3.24 -3.54 -0.236 0.60463E+04 42 celadonite 5.40 3.32 -2.08 -0.123 0.35581E+04 43 celadonite-Fe 3.94 0.96 -2.98 -0.175 0.50888E+04 44 chrysotile 23.94 20.49 -3.44 -0.287 0.58781E+04 50 chloritoid-Mg 13.26 8.85 -4.41 -0.294 0.75301E+04 51 chloritoid-Fe 9.24 6.49 -2.75 -0.183 0.46914E+04 52 chloritoid-Mn 11.46 8.75 -2.71 -0.181 0.46344E+04 54 coesite -2.37 -3.25 -0.88 -0.293 0.15025E+04 61 cristobalite -2.55 -3.25 -0.70 -0.233 0.11954E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.55 -1.34 -0.224 0.22961E+04 67 diopside 16.22 14.74 -1.48 -0.148 0.25264E+04 68 hedenbergite 14.24 12.38 -1.87 -0.187 0.31906E+04 75 epidote 24.78 23.87 -0.90 -0.044 0.15413E+04 76 clinozoisite 22.92 19.38 -3.54 -0.161 0.60474E+04 77 epidote-Fe 29.94 28.37 -1.57 -0.082 0.26828E+04 78 fayalite 14.08 10.03 -4.05 -0.579 0.69200E+04 79 ferrosilite 11.19 6.78 -4.41 -0.441 0.75313E+04 83 gibbsite 4.10 1.55 -2.55 -0.364 0.43473E+04 84 glaucophane 23.11 19.84 -3.27 -0.088 0.55877E+04 85 glaucophane-Fe 17.42 12.76 -4.66 -0.126 0.79556E+04 87 greenalite 16.19 13.41 -2.78 -0.232 0.47460E+04 90 hematite 12.60 12.09 -0.51 -0.062 0.86869E+03 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.92 -1.33 -0.133 0.22709E+04 96 julgoldite 70.57 66.90 -3.67 -0.095 0.62645E+04 97 kalsilite 7.62 4.07 -3.55 -0.508 0.60674E+04 98 kaolinite -1.27 -3.40 -2.12 -0.193 0.36246E+04 101 laumontite 2.97 2.34 -0.63 -0.042 0.10799E+04 102 lawsonite 9.68 8.84 -0.84 -0.056 0.14303E+04 103 leucite 4.17 0.82 -3.35 -0.335 0.57202E+04 105 lizardite 23.29 20.49 -2.79 -0.233 0.47684E+04 107 magnetite 20.13 18.73 -1.41 -0.115 0.24010E+04 108 minnesotaite 10.46 6.92 -3.54 -0.209 0.60525E+04 120 muscovite 2.68 0.67 -2.01 -0.118 0.34291E+04 121 paragonite 4.34 2.77 -1.56 -0.092 0.26676E+04 122 nepheline 8.38 6.17 -2.21 -0.315 0.37698E+04 134 phlogopite-Na 29.73 26.67 -3.07 -0.170 0.52357E+04 136 prehnite 19.47 17.83 -1.64 -0.096 0.27973E+04 137 prehnite-Fe 22.59 22.32 -0.27 -0.016 0.45352E+03 138 pumpellyite-Fe 46.47 43.85 -2.63 -0.058 0.44827E+04 139 pumpellyite-Mg 49.19 46.21 -2.99 -0.066 0.51032E+04 145 pyroxmangite 7.42 5.65 -1.77 -0.354 0.30217E+04 146 pyrophyllite -6.10 -9.89 -3.80 -0.237 0.64825E+04 147 quartz -2.98 -3.25 -0.27 -0.089 0.45644E+03 152 rhodonite 7.46 5.65 -1.82 -0.363 0.31009E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 24.98 -2.62 -0.078 0.44679E+04 171 talc 16.55 14.00 -2.56 -0.150 0.43664E+04 174 tephroite 18.11 14.54 -3.57 -0.510 0.60972E+04 177 topaz-H 4.67 -0.15 -4.81 -0.438 0.82201E+04 178 tridymite -2.61 -3.25 -0.63 -0.212 0.10837E+04 179 tremolite 48.00 43.47 -4.54 -0.123 0.77440E+04 187 wairakite 4.06 2.34 -1.72 -0.101 0.29307E+04 188 walstromite 11.53 8.99 -2.54 -0.508 0.43379E+04 189 wollastonite 10.48 8.99 -1.49 -0.299 0.25518E+04 190 pseudo-wollastonite 11.02 8.99 -2.03 -0.406 0.34704E+04 191 zoisite 22.96 19.38 -3.58 -0.163 0.61200E+04 192 akaganeite 7.77 6.04 -1.72 -0.373 0.29425E+04 193 beidellite-Ca -1.56 -6.29 -4.73 -0.293 0.80791E+04 195 beidellite-K -1.44 -6.41 -4.97 -0.305 0.84912E+04 197 beidellite-Na -1.26 -5.71 -4.46 -0.273 0.76099E+04 199 chalcedony -2.79 -3.25 -0.45 -0.152 0.77675E+03 201 montmorillonite-Ca -2.21 -5.42 -3.20 -0.198 0.54710E+04 202 montmorillonite-K -2.16 -5.53 -3.37 -0.207 0.57608E+04 203 montmorillonite-Mg -2.40 -5.95 -3.55 -0.220 0.60632E+04 204 montmorillonite-Na -1.96 -4.84 -2.88 -0.176 0.49177E+04 205 nontronite-Ca 3.28 2.69 -0.58 -0.038 0.99851E+03 206 nontronite-H 2.60 0.68 -1.92 -0.129 0.32782E+04 207 nontronite-K 3.40 2.58 -0.83 -0.053 0.14097E+04 208 nontronite-Mg 3.14 2.16 -0.98 -0.063 0.16713E+04 209 nontronite-Na 3.58 3.27 -0.31 -0.020 0.53014E+03 224 tobermorite 9.84 6.94 -2.90 -0.790 0.49434E+04 233 boehmite 4.43 1.55 -2.88 -0.480 0.49146E+04 235 ferrous-oxide 9.82 6.64 -3.19 -0.797 0.54408E+04 240 silica-amorphous -2.08 -3.25 -1.17 -0.390 0.19969E+04 242 an20ab80 2.08 1.51 -0.57 -0.044 0.97967E+03 243 an25ab75 2.71 1.96 -0.75 -0.057 0.12725E+04 244 an30ab70 3.34 2.42 -0.92 -0.071 0.15737E+04 245 tr.625ac.25prg.125 45.31 41.77 -3.54 -0.095 0.60401E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 35.9990000 g New total amount of reactant added: 36.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2996E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 36.9990000 Water: Moles liquid = 0.5526E+02 kg liquid = 0.9954E+00 Moles total = 0.5504E+02 kg total = 0.9916E+00 Activity = 1.0000 Stoichiometric ionic strength = .6064411E-02 Osmotic coef. = 0.9593 True ionic strength = .1103498E-01 Chg. balance for total moles = 0.2996E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.14182E-09 -9.8482 0.12333E-09 -9.9089 0.86960E+00 -0.0607 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13824E-03 -3.8594 0.11977E-03 -3.9217 0.86639E+00 -0.0623 4 SO4-- 0.25600E-04 -4.5918 0.15333E-04 -4.8144 0.59892E+00 -0.2226 5 HCO3- 0.62903E-05 -5.2013 0.54547E-05 -5.2632 0.86716E+00 -0.0619 6 HS- 0.33652E-09 -9.4730 0.29158E-09 -9.5352 0.86647E+00 -0.0622 7 Al+++ 0.19960E-27 -27.6998 0.63888E-28 -28.1946 0.32008E+00 -0.4947 8 H4SiO4 0.56441E-03 -3.2484 0.56441E-03 -3.2484 0.10000E+01 0.0000 9 Ca++ 0.47350E-07 -7.3247 0.28232E-07 -7.5493 0.59624E+00 -0.2246 10 Mg++ 0.25941E-10 -10.5860 0.15424E-10 -10.8118 0.59457E+00 -0.2258 11 Fe++ 0.11219E-12 -12.9500 0.66752E-13 -13.1755 0.59497E+00 -0.2255 12 K+ 0.85928E-04 -4.0659 0.74525E-04 -4.1277 0.86729E+00 -0.0618 13 Na+ 0.10916E-01 -1.9619 0.94566E-02 -2.0243 0.86630E+00 -0.0623 14 Mn++ 0.20480E-10 -10.6887 0.12191E-10 -10.9140 0.59527E+00 -0.2253 15 HPO4-- 0.39494E-06 -6.4035 0.23656E-06 -6.6261 0.59897E+00 -0.2226 16 HSiO3- 0.51535E-02 -2.2879 0.44650E-02 -2.3502 0.86639E+00 -0.0623 17 Ca(HSiO3)+ 0.32560E-08 -8.4873 0.28243E-08 -8.5491 0.86741E+00 -0.0618 18 Mg(HSiO3)+ 0.22138E-11 -11.6549 0.19203E-11 -11.7166 0.86741E+00 -0.0618 19 NaHSiO3,aq 0.67061E-03 -3.1735 0.67061E-03 -3.1735 0.10000E+01 0.0000 20 AlO+ 0.62512E-15 -15.2040 0.54224E-15 -15.2658 0.86741E+00 -0.0618 22 HAlO2,aq 0.87980E-09 -9.0556 0.87980E-09 -9.0556 0.10000E+01 0.0000 23 AlO2- 0.18405E-04 -4.7351 0.15929E-04 -4.7978 0.86543E+00 -0.0628 24 CH4,aq 0.10198E-15 -15.9915 0.10179E-15 -15.9923 0.99814E+00 -0.0008 29 CO,aq 0.26069E-18 -18.5839 0.26069E-18 -18.5839 0.10000E+01 0.0000 30 CO2,aq 0.13589E-08 -8.8668 0.13564E-08 -8.8676 0.99814E+00 -0.0008 31 CO3-2 0.68367E-05 -5.1652 0.40893E-05 -5.3883 0.59814E+00 -0.2232 32 CaCO3,aq 0.14140E-08 -8.8496 0.14140E-08 -8.8496 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.44734E-11 -11.3494 0.38803E-11 -11.4111 0.86741E+00 -0.0618 34 CaCl+ 0.62116E-11 -11.2068 0.53880E-11 -11.2686 0.86741E+00 -0.0618 35 CaCl2,aq 0.15025E-15 -15.8232 0.15025E-15 -15.8232 0.10000E+01 0.0000 36 CaOH+ 0.18609E-07 -7.7303 0.16141E-07 -7.7921 0.86741E+00 -0.0618 37 CaSO4,aq 0.13487E-09 -9.8701 0.13487E-09 -9.8701 0.10000E+01 0.0000 38 HCl,aq 0.27784E-14 -14.5562 0.27784E-14 -14.5562 0.10000E+01 0.0000 43 FeCl+ 0.14355E-16 -16.8430 0.12452E-16 -16.9048 0.86741E+00 -0.0618 46 FeO,aq 0.17354E-09 -9.7606 0.17354E-09 -9.7606 0.10000E+01 0.0000 47 FeOH+ 0.20686E-10 -10.6843 0.17944E-10 -10.7461 0.86741E+00 -0.0618 48 HFeO2- 0.17469E-07 -7.7577 0.15135E-07 -7.8200 0.86639E+00 -0.0623 49 FeO+ 0.58274E-15 -15.2345 0.50547E-15 -15.2963 0.86741E+00 -0.0618 51 FeO2- 0.75386E-08 -8.1227 0.65314E-08 -8.1850 0.86639E+00 -0.0623 52 HFeO2,aq 0.10081E-09 -9.9965 0.10081E-09 -9.9965 0.10000E+01 0.0000 53 H2,aq 0.74764E-08 -8.1263 0.74625E-08 -8.1271 0.99814E+00 -0.0008 54 KCl,aq 0.15804E-09 -9.8012 0.15804E-09 -9.8012 0.10000E+01 0.0000 55 KHSO4,aq 0.37711E-18 -18.4235 0.37711E-18 -18.4235 0.10000E+01 0.0000 56 KOH,aq 0.26343E-06 -6.5793 0.26343E-06 -6.5793 0.10000E+01 0.0000 57 KSO4- 0.20319E-07 -7.6921 0.17604E-07 -7.7544 0.86639E+00 -0.0623 58 MgCO3,aq 0.19303E-12 -12.7144 0.19303E-12 -12.7144 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24922E-14 -14.6034 0.21617E-14 -14.6652 0.86741E+00 -0.0618 60 MgCl+ 0.30807E-14 -14.5113 0.26723E-14 -14.5731 0.86741E+00 -0.0618 61 MgOH+ 0.56322E-10 -10.2493 0.48854E-10 -10.3111 0.86741E+00 -0.0618 63 MnO,aq 0.84609E-09 -9.0726 0.84609E-09 -9.0726 0.10000E+01 0.0000 64 MnOH+ 0.35097E-09 -9.4547 0.30443E-09 -9.5165 0.86741E+00 -0.0618 65 MnO2-2 0.32162E-11 -11.4927 0.19237E-11 -11.7159 0.59814E+00 -0.2232 66 HMnO2- 0.59331E-10 -10.2267 0.51404E-10 -10.2890 0.86639E+00 -0.0623 69 MnCl+ 0.10188E-13 -13.9919 0.88369E-14 -14.0537 0.86741E+00 -0.0618 70 MnSO4,aq 0.52974E-13 -13.2759 0.52974E-13 -13.2759 0.10000E+01 0.0000 71 NaCl,aq 0.36981E-06 -6.4320 0.36981E-06 -6.4320 0.10000E+01 0.0000 72 NaOH,aq 0.33692E-04 -4.4725 0.33692E-04 -4.4725 0.10000E+01 0.0000 74 OH- 0.56199E-02 -2.2503 0.48636E-02 -2.3130 0.86543E+00 -0.0628 79 HPO3-2 0.93219E-17 -17.0305 0.55758E-17 -17.2537 0.59814E+00 -0.2232 82 H3PO4,aq 0.23165E-16 -16.6352 0.23165E-16 -16.6352 0.10000E+01 0.0000 83 H2PO4- 0.59003E-09 -9.2291 0.51150E-09 -9.2912 0.86689E+00 -0.0620 84 PO4-3 0.50780E-08 -8.2943 0.16751E-08 -8.7760 0.32986E+00 -0.4817 87 H2P2O7-2 0.34233E-19 -19.4656 0.20476E-19 -19.6887 0.59814E+00 -0.2232 88 HP2O7-3 0.10631E-15 -15.9734 0.34044E-16 -16.4680 0.32025E+00 -0.4945 89 P2O7-4 0.50029E-15 -15.3008 0.68098E-16 -16.1669 0.13612E+00 -0.8661 90 H2S,aq 0.10825E-12 -12.9656 0.10805E-12 -12.9664 0.99814E+00 -0.0008 97 SO3-2 0.25853E-13 -13.5875 0.15601E-13 -13.8068 0.60345E+00 -0.2194 98 HSO3- 0.12997E-15 -15.8862 0.11260E-15 -15.9485 0.86639E+00 -0.0623 99 HSO4- 0.20216E-11 -11.6943 0.17546E-11 -11.7558 0.86792E+00 -0.0615 101 S2O3-2 0.32642E-19 -19.4862 0.19525E-19 -19.7094 0.59814E+00 -0.2232 Charge balance for all species = 0.3008E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1418249E-09 -.1155856E-01 -.1164013E+02 0.0000 2 H2O 0.1000000E+01 0.5550812E+02 0.9991191E+06 0.0000 3 Cl- 0.1382357E-03 0.1386057E-03 0.4909681E+01 5.9873 4 SO4-- 0.2560041E-04 0.2561995E-04 0.2458937E+01 15.0035 5 HCO3- 0.6290308E-05 0.1312982E-04 0.8004428E+00 4.6457 6 HS- 0.3365196E-09 0.1250808E-08 0.4133047E-04 0.3737 7 Al+++ 0.1995991E-27 0.1840629E-04 0.4961943E+00 1.5322 8 H4SiO4 0.5644056E-03 0.6388570E-02 0.6135019E+03 -3.2484 9 Ca++ 0.4735023E-07 0.7077447E-07 0.2834014E-02 12.2686 10 Mg++ 0.2594133E-10 0.8467620E-10 0.2056844E-05 9.0060 11 Fe++ 0.1121945E-12 0.2530272E-07 0.1411843E-02 6.6423 12 K+ 0.8592811E-04 0.8621202E-04 0.3368109E+01 5.7812 13 Na+ 0.1091604E-01 0.1162072E-01 0.2669238E+03 7.8847 14 Mn++ 0.2048023E-10 0.1280152E-08 0.7026734E-04 8.9039 15 HPO4-- 0.3949387E-06 0.4006067E-06 0.3841614E-01 13.1918 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6126355E+00 -.1150590E-01 -.6011296E+00 0.0000000E+00 2 H2O 0.5504445E+02 0.5525523E+02 -.2107726E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1050873E-02 0.2550322E-04 0.1025370E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1025368E-02 0.1245109E-08 -.1025370E-02 0.0000000E+00 7 Al+++ 0.1206442E+00 0.1832244E-04 0.1206259E+00 0.0000000E+00 8 H4SiO4 0.3852626E+00 0.6359464E-02 0.3789031E+00 0.0000000E+00 9 Ca++ 0.4256860E-01 0.7045203E-07 0.4256853E-01 0.0000000E+00 10 Mg++ 0.2936429E-01 0.8429042E-10 0.2936429E-01 0.0000000E+00 11 Fe++ 0.2638060E-01 0.2518744E-07 0.2638058E-01 0.0000000E+00 12 K+ 0.7855414E-02 0.8581924E-04 0.7769595E-02 0.0000000E+00 13 Na+ 0.4660283E-01 0.1156777E-01 0.3503506E-01 0.0000000E+00 14 Mn++ 0.6415107E-03 0.1274319E-08 0.6415094E-03 0.0000000E+00 15 HPO4-- 0.2189444E-03 0.3987816E-06 0.2185456E-03 0.0000000E+00 Chg. balance for solid moles: 0.5323E-16 Mass of aqueous solution: 0.996317E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 36.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3504E-01 -1.455 9.187 0.963 22.74 3.527 andradite 0.4101E-02 -2.387 2.084 0.319 5.160 0.5415 grossular 0.1910E-03 -3.719 0.8605E-01 -1.065 0.2130 0.2394E-01 apatite-OH 0.7285E-04 -4.138 0.3659E-01 -1.437 0.9059E-01 0.1163E-01 clinochlore 0.5873E-02 -2.231 3.264 0.514 8.081 1.242 daphnite 0.2660E-02 -2.575 1.898 0.278 4.699 0.5751 chlorite-Mn 0.1283E-03 -3.892 0.9096E-01 -1.041 0.2252 0.2899E-01 microcline 0.7282E-02 -2.138 2.027 0.307 5.018 0.7917 stilbite 0.2933E-01 -1.533 20.67 1.315 51.17 9.640 stilpnomelane-Fe 0.9755E-03 -3.011 1.052 0.022 2.603 0.3632 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9555E+00 0.9555E+00 1.0000 -0.020 grossular 0.4450E-01 0.4450E-01 1.0000 -1.352 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6781E+00 0.6781E+00 1.0000 -0.169 daphnite 0.3071E+00 0.3071E+00 1.0000 -0.513 chlorite-Mn 0.1481E-01 0.1481E-01 1.0000 -1.829 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 40.392610 g Volume = 16.744003 cm3 Porosity: -5.9774% V(tot) - V(min): -.94440E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 36.9990000 g log = 1.5682 Original solution: 1000.0103000 g Original solution / Rock added: 27.03 (Water/Rock Ratio), log = 1.4318 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1465E-06 1.0073 0.1553E-06 0.1541E-06 CH4,gas 0.1511E-12 1.0129 0.1610E-12 0.1589E-12 H2,gas 0.9725E-05 1.0006 0.1024E-04 0.1023E-04 H2S,gas 0.3008E-11 0.9959 0.3151E-11 0.3164E-11 S2,gas 0.3375E-32 1.0000 0.3550E-32 0.3550E-32 CO,gas 0.3913E-15 1.0000 0.4116E-15 0.4116E-15 SO3,gas 0.8288E-40 1.0000 0.8719E-40 0.8719E-40 SO2,gas 0.3209E-22 1.0000 0.3376E-22 0.3376E-22 HCl,gas 0.4664E-17 1.0000 0.4906E-17 0.4906E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.17 -8.81 -2.936 0.15041E+05 -6.809 3 CH4,gas 4.81 -9.98 -14.79 -3.698 0.25259E+05 -12.793 4 H2,gas 8.29 1.30 -6.99 -3.994 0.11935E+05 -4.990 5 H2S,gas -5.94 -19.44 -13.50 -6.751 0.23053E+05 -11.502 6 S2,gas -7.03 -41.48 -34.45 -5.300 0.58822E+05 -32.450 7 CO,gas 3.51 -13.88 -17.39 -5.349 0.29685E+05 -15.385 8 SO3,gas 17.43 -24.63 -42.06 -10.515 0.71816E+05 -40.060 9 SO2,gas 1.14 -23.34 -24.47 -6.526 0.41785E+05 -22.472 10 HCl,gas 5.48 -13.83 -19.31 -9.655 0.32970E+05 -17.309 11 acmite 7.74 7.38 -0.36 -0.037 0.60740E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.03 -4.52 -0.226 0.77161E+04 20 analcite 3.37 2.92 -0.45 -0.050 0.76937E+03 26 annite 20.21 17.50 -2.71 -0.151 0.46344E+04 27 phlogopite 27.15 24.59 -2.56 -0.142 0.43715E+04 29 anorthite 12.80 8.84 -3.96 -0.305 0.67641E+04 35 aragonite 0.99 -2.90 -3.89 -1.297 0.66417E+04 36 brucite 12.58 9.01 -3.57 -0.714 0.60966E+04 37 calcite 0.83 -2.90 -3.74 -1.246 0.63804E+04 38 carnegieite-low 9.06 6.17 -2.90 -0.414 0.49450E+04 39 carnegieite-high 10.13 6.17 -3.97 -0.567 0.67719E+04 40 carpholite-Mg 8.65 5.57 -3.08 -0.205 0.52534E+04 41 carpholite-Fe 6.78 3.21 -3.57 -0.238 0.61008E+04 42 celadonite 5.40 3.33 -2.07 -0.122 0.35424E+04 43 celadonite-Fe 3.94 0.96 -2.97 -0.175 0.50794E+04 44 chrysotile 23.94 20.52 -3.42 -0.285 0.58327E+04 50 chloritoid-Mg 13.26 8.82 -4.44 -0.296 0.75798E+04 51 chloritoid-Fe 9.24 6.46 -2.78 -0.185 0.47474E+04 52 chloritoid-Mn 11.46 8.72 -2.74 -0.183 0.46841E+04 54 coesite -2.37 -3.25 -0.88 -0.293 0.15010E+04 61 cristobalite -2.55 -3.25 -0.70 -0.233 0.11939E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.53 -1.36 -0.227 0.23288E+04 67 diopside 16.22 14.78 -1.44 -0.144 0.24547E+04 68 hedenbergite 14.24 12.41 -1.83 -0.183 0.31252E+04 75 epidote 24.78 23.85 -0.93 -0.045 0.15794E+04 76 clinozoisite 22.92 19.39 -3.53 -0.161 0.60318E+04 77 epidote-Fe 29.94 28.31 -1.62 -0.084 0.27746E+04 78 fayalite 14.08 10.04 -4.04 -0.578 0.69028E+04 79 ferrosilite 11.19 6.79 -4.40 -0.440 0.75127E+04 83 gibbsite 4.10 1.53 -2.57 -0.366 0.43800E+04 84 glaucophane 23.11 19.86 -3.25 -0.088 0.55423E+04 85 glaucophane-Fe 17.42 12.77 -4.64 -0.126 0.79291E+04 87 greenalite 16.19 13.43 -2.76 -0.230 0.47196E+04 90 hematite 12.60 11.99 -0.61 -0.074 0.10415E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.92 -1.33 -0.133 0.22724E+04 96 julgoldite 70.57 66.84 -3.73 -0.097 0.63672E+04 97 kalsilite 7.62 4.07 -3.56 -0.508 0.60705E+04 98 kaolinite -1.27 -3.43 -2.16 -0.196 0.36869E+04 101 laumontite 2.97 2.34 -0.64 -0.042 0.10845E+04 102 lawsonite 9.68 8.84 -0.84 -0.056 0.14380E+04 103 leucite 4.17 0.82 -3.35 -0.335 0.57218E+04 105 lizardite 23.29 20.52 -2.77 -0.231 0.47230E+04 107 magnetite 20.13 18.63 -1.50 -0.123 0.25660E+04 108 minnesotaite 10.46 6.93 -3.53 -0.207 0.60229E+04 120 muscovite 2.68 0.63 -2.05 -0.120 0.34945E+04 121 paragonite 4.34 2.74 -1.60 -0.094 0.27330E+04 122 nepheline 8.38 6.17 -2.21 -0.316 0.37729E+04 128 periclase-Fe 11.64 6.64 -5.00 -1.249 0.85319E+04 134 phlogopite-Na 29.73 26.69 -3.04 -0.169 0.51934E+04 136 prehnite 19.47 17.86 -1.61 -0.095 0.27490E+04 137 prehnite-Fe 22.59 22.32 -0.27 -0.016 0.45893E+03 138 pumpellyite-Fe 46.47 43.89 -2.58 -0.057 0.44109E+04 139 pumpellyite-Mg 49.19 46.25 -2.94 -0.065 0.50252E+04 145 pyroxmangite 7.42 5.66 -1.76 -0.352 0.30061E+04 146 pyrophyllite -6.10 -9.93 -3.83 -0.239 0.65417E+04 147 quartz -2.98 -3.25 -0.27 -0.089 0.45489E+03 152 rhodonite 7.46 5.66 -1.81 -0.361 0.30853E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.00 -2.60 -0.078 0.44365E+04 171 talc 16.55 14.02 -2.53 -0.149 0.43180E+04 174 tephroite 18.11 14.56 -3.55 -0.508 0.60675E+04 177 topaz-H 4.67 -0.18 -4.85 -0.441 0.82839E+04 178 tridymite -2.61 -3.25 -0.63 -0.211 0.10822E+04 179 tremolite 48.00 43.58 -4.42 -0.120 0.75522E+04 187 wairakite 4.06 2.34 -1.72 -0.101 0.29354E+04 188 walstromite 11.53 9.02 -2.51 -0.502 0.42818E+04 189 wollastonite 10.48 9.02 -1.46 -0.292 0.24957E+04 190 pseudo-wollastonite 11.02 9.02 -2.00 -0.400 0.34143E+04 191 zoisite 22.96 19.39 -3.58 -0.163 0.61043E+04 192 akaganeite 7.77 5.99 -1.77 -0.384 0.30289E+04 193 beidellite-Ca -1.56 -6.33 -4.77 -0.295 0.81406E+04 197 beidellite-Na -1.26 -5.75 -4.49 -0.275 0.76711E+04 199 chalcedony -2.79 -3.25 -0.45 -0.151 0.77520E+03 201 montmorillonite-Ca -2.21 -5.44 -3.22 -0.199 0.55058E+04 202 montmorillonite-K -2.16 -5.56 -3.39 -0.208 0.57953E+04 203 montmorillonite-Mg -2.40 -5.98 -3.58 -0.221 0.61046E+04 204 montmorillonite-Na -1.96 -4.86 -2.90 -0.178 0.49522E+04 205 nontronite-Ca 3.28 2.60 -0.68 -0.044 0.11675E+04 206 nontronite-H 2.60 0.57 -2.02 -0.136 0.34562E+04 207 nontronite-K 3.40 2.48 -0.92 -0.059 0.15784E+04 208 nontronite-Mg 3.14 2.06 -1.08 -0.070 0.18469E+04 209 nontronite-Na 3.58 3.17 -0.41 -0.026 0.69883E+03 224 tobermorite 9.84 6.97 -2.87 -0.782 0.48965E+04 233 boehmite 4.43 1.53 -2.90 -0.483 0.49472E+04 235 ferrous-oxide 9.82 6.64 -3.18 -0.795 0.54330E+04 240 silica-amorphous -2.08 -3.25 -1.17 -0.390 0.19954E+04 242 an20ab80 2.08 1.50 -0.57 -0.044 0.98122E+03 243 an25ab75 2.71 1.96 -0.75 -0.057 0.12744E+04 244 an30ab70 3.34 2.42 -0.92 -0.071 0.15760E+04 245 tr.625ac.25prg.125 45.31 41.87 -3.44 -0.093 0.58671E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 36.9990000 g New total amount of reactant added: 37.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2996E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 37.9990000 Water: Moles liquid = 0.5525E+02 kg liquid = 0.9953E+00 Moles total = 0.5503E+02 kg total = 0.9914E+00 Activity = 1.0000 Stoichiometric ionic strength = .6184386E-02 Osmotic coef. = 0.9589 True ionic strength = .1125146E-01 Chg. balance for total moles = 0.2996E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13947E-09 -9.8555 0.12116E-09 -9.9166 0.86873E+00 -0.0611 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13825E-03 -3.8593 0.11965E-03 -3.9221 0.86547E+00 -0.0627 4 SO4-- 0.25603E-04 -4.5917 0.15270E-04 -4.8161 0.59644E+00 -0.2244 5 HCO3- 0.62227E-05 -5.2060 0.53905E-05 -5.2684 0.86625E+00 -0.0624 6 HS- 0.87146E-09 -9.0598 0.75429E-09 -9.1225 0.86555E+00 -0.0627 7 Al+++ 0.18298E-27 -27.7376 0.58019E-28 -28.2364 0.31707E+00 -0.4988 8 H4SiO4 0.56572E-03 -3.2474 0.56572E-03 -3.2474 0.10000E+01 0.0000 9 Ca++ 0.49219E-07 -7.3079 0.29223E-07 -7.5343 0.59373E+00 -0.2264 10 Mg++ 0.25613E-10 -10.5915 0.15164E-10 -10.8192 0.59204E+00 -0.2276 11 Fe++ 0.10983E-12 -12.9593 0.65067E-13 -13.1866 0.59244E+00 -0.2274 12 K+ 0.87617E-04 -4.0574 0.75910E-04 -4.1197 0.86639E+00 -0.0623 13 Na+ 0.11131E-01 -1.9535 0.96324E-02 -2.0163 0.86538E+00 -0.0628 14 Mn++ 0.20221E-10 -10.6942 0.11986E-10 -10.9213 0.59275E+00 -0.2271 15 HPO4-- 0.36567E-06 -6.4369 0.21812E-06 -6.6613 0.59650E+00 -0.2244 16 HSiO3- 0.52636E-02 -2.2787 0.45555E-02 -2.3415 0.86547E+00 -0.0627 17 Ca(HSiO3)+ 0.34423E-08 -8.4632 0.29827E-08 -8.5254 0.86650E+00 -0.0622 18 Mg(HSiO3)+ 0.22230E-11 -11.6531 0.19262E-11 -11.7153 0.86650E+00 -0.0622 19 NaHSiO3,aq 0.69693E-03 -3.1568 0.69693E-03 -3.1568 0.10000E+01 0.0000 20 AlO+ 0.58881E-15 -15.2300 0.51020E-15 -15.2923 0.86650E+00 -0.0622 22 HAlO2,aq 0.84264E-09 -9.0744 0.84264E-09 -9.0744 0.10000E+01 0.0000 23 AlO2- 0.17963E-04 -4.7456 0.15529E-04 -4.8089 0.86449E+00 -0.0632 24 CH4,aq 0.26177E-15 -15.5821 0.26127E-15 -15.5829 0.99810E+00 -0.0008 29 CO,aq 0.32273E-18 -18.4912 0.32273E-18 -18.4912 0.10000E+01 0.0000 30 CO2,aq 0.13193E-08 -8.8796 0.13168E-08 -8.8805 0.99810E+00 -0.0008 31 CO3-2 0.69058E-05 -5.1608 0.41135E-05 -5.3858 0.59565E+00 -0.2250 32 CaCO3,aq 0.14723E-08 -8.8320 0.14723E-08 -8.8320 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.45807E-11 -11.3391 0.39692E-11 -11.4013 0.86650E+00 -0.0622 34 CaCl+ 0.64300E-11 -11.1918 0.55716E-11 -11.2540 0.86650E+00 -0.0622 35 CaCl2,aq 0.15521E-15 -15.8091 0.15521E-15 -15.8091 0.10000E+01 0.0000 36 CaOH+ 0.19627E-07 -7.7071 0.17007E-07 -7.7694 0.86650E+00 -0.0622 37 CaSO4,aq 0.13904E-09 -9.8569 0.13904E-09 -9.8569 0.10000E+01 0.0000 38 HCl,aq 0.27268E-14 -14.5643 0.27268E-14 -14.5643 0.10000E+01 0.0000 43 FeCl+ 0.13994E-16 -16.8541 0.12125E-16 -16.9163 0.86650E+00 -0.0622 46 FeO,aq 0.17527E-09 -9.7563 0.17527E-09 -9.7563 0.10000E+01 0.0000 47 FeOH+ 0.20547E-10 -10.6873 0.17804E-10 -10.7495 0.86650E+00 -0.0622 48 HFeO2- 0.17978E-07 -7.7453 0.15559E-07 -7.8080 0.86547E+00 -0.0627 49 FeO+ 0.51257E-15 -15.2902 0.44414E-15 -15.3525 0.86650E+00 -0.0622 51 FeO2- 0.68704E-08 -8.1630 0.59461E-08 -8.2258 0.86547E+00 -0.0627 52 HFeO2,aq 0.90165E-10 -10.0450 0.90165E-10 -10.0450 0.10000E+01 0.0000 53 H2,aq 0.95339E-08 -8.0207 0.95158E-08 -8.0216 0.99810E+00 -0.0008 54 KCl,aq 0.16082E-09 -9.7937 0.16082E-09 -9.7937 0.10000E+01 0.0000 55 KHSO4,aq 0.37584E-18 -18.4250 0.37584E-18 -18.4250 0.10000E+01 0.0000 56 KOH,aq 0.27313E-06 -6.5636 0.27313E-06 -6.5636 0.10000E+01 0.0000 57 KSO4- 0.20635E-07 -7.6854 0.17859E-07 -7.7481 0.86547E+00 -0.0627 58 MgCO3,aq 0.19090E-12 -12.7192 0.19090E-12 -12.7192 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24239E-14 -14.6155 0.21003E-14 -14.6777 0.86650E+00 -0.0622 60 MgCl+ 0.30290E-14 -14.5187 0.26246E-14 -14.5809 0.86650E+00 -0.0622 61 MgOH+ 0.56423E-10 -10.2485 0.48891E-10 -10.3108 0.86650E+00 -0.0622 63 MnO,aq 0.86188E-09 -9.0646 0.86188E-09 -9.0646 0.10000E+01 0.0000 64 MnOH+ 0.35160E-09 -9.4540 0.30466E-09 -9.5162 0.86650E+00 -0.0622 65 MnO2-2 0.34087E-11 -11.4674 0.20304E-11 -11.6924 0.59565E+00 -0.2250 66 HMnO2- 0.61585E-10 -10.2105 0.53300E-10 -10.2733 0.86547E+00 -0.0627 69 MnCl+ 0.10017E-13 -13.9993 0.86794E-14 -14.0615 0.86650E+00 -0.0622 70 MnSO4,aq 0.51871E-13 -13.2851 0.51871E-13 -13.2851 0.10000E+01 0.0000 71 NaCl,aq 0.37632E-06 -6.4244 0.37632E-06 -6.4244 0.10000E+01 0.0000 72 NaOH,aq 0.34933E-04 -4.4568 0.34933E-04 -4.4568 0.10000E+01 0.0000 74 OH- 0.57267E-02 -2.2421 0.49507E-02 -2.3053 0.86449E+00 -0.0632 79 HPO3-2 0.11006E-16 -16.9584 0.65557E-17 -17.1834 0.59565E+00 -0.2250 82 H3PO4,aq 0.20615E-16 -16.6858 0.20615E-16 -16.6858 0.10000E+01 0.0000 83 H2PO4- 0.53504E-09 -9.2716 0.46333E-09 -9.3341 0.86598E+00 -0.0625 84 PO4-3 0.48089E-08 -8.3180 0.15721E-08 -8.8035 0.32692E+00 -0.4856 87 H2P2O7-2 0.28207E-19 -19.5496 0.16802E-19 -19.7746 0.59565E+00 -0.2250 88 HP2O7-3 0.89632E-16 -16.0475 0.28435E-16 -16.5461 0.31724E+00 -0.4986 89 P2O7-4 0.43242E-15 -15.3641 0.57896E-16 -16.2374 0.13389E+00 -0.8733 90 H2S,aq 0.27512E-12 -12.5605 0.27459E-12 -12.5613 0.99810E+00 -0.0008 97 SO3-2 0.32965E-13 -13.4819 0.19813E-13 -13.7031 0.60102E+00 -0.2211 98 HSO3- 0.16232E-15 -15.7896 0.14049E-15 -15.8524 0.86547E+00 -0.0627 99 HSO4- 0.19800E-11 -11.7033 0.17167E-11 -11.7653 0.86702E+00 -0.0620 101 S2O3-2 0.82966E-19 -19.0811 0.49419E-19 -19.3061 0.59565E+00 -0.2250 Charge balance for all species = 0.3112E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1394709E-09 -.1180128E-01 -.1188435E+02 0.0000 2 H2O 0.1000000E+01 0.5550809E+02 0.9991006E+06 0.0000 3 Cl- 0.1382456E-03 0.1386220E-03 0.4910172E+01 5.9945 4 SO4-- 0.2560258E-04 0.2562184E-04 0.2459074E+01 15.0171 5 HCO3- 0.6222745E-05 0.1313137E-04 0.8005229E+00 4.6483 6 HS- 0.8714593E-09 0.2385140E-08 0.7881080E-04 0.7942 7 Al+++ 0.1829820E-27 0.1796376E-04 0.4842557E+00 1.5135 8 H4SiO4 0.5657240E-03 0.6526287E-02 0.6267157E+03 -3.2474 9 Ca++ 0.4921939E-07 0.7391106E-07 0.2959558E-02 12.2990 10 Mg++ 0.2561321E-10 0.8445600E-10 0.2051458E-05 9.0141 11 Fe++ 0.1098284E-12 0.2513436E-07 0.1402424E-02 6.6466 12 K+ 0.8761687E-04 0.8791079E-04 0.3434414E+01 5.7969 13 Na+ 0.1113079E-01 0.1186302E-01 0.2724846E+03 7.9004 14 Mn++ 0.2022079E-10 0.1298755E-08 0.7128720E-04 8.9119 15 HPO4-- 0.3656651E-06 0.3710091E-06 0.3557723E-01 13.1720 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6291940E+00 -.1174613E-01 -.6174479E+00 0.0000000E+00 2 H2O 0.5503192E+02 0.5524866E+02 -.2167477E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1078586E-02 0.2550210E-04 0.1053084E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1053082E-02 0.2373993E-08 -.1053084E-02 0.0000000E+00 7 Al+++ 0.1239049E+00 0.1787980E-04 0.1238870E+00 0.0000000E+00 8 H4SiO4 0.3956753E+00 0.6495786E-02 0.3891796E+00 0.0000000E+00 9 Ca++ 0.4371874E-01 0.7356563E-07 0.4371867E-01 0.0000000E+00 10 Mg++ 0.3015794E-01 0.8406129E-10 0.3015794E-01 0.0000000E+00 11 Fe++ 0.2709361E-01 0.2501690E-07 0.2709359E-01 0.0000000E+00 12 K+ 0.8067728E-02 0.8749993E-04 0.7980228E-02 0.0000000E+00 13 Na+ 0.4785807E-01 0.1180758E-01 0.3605049E-01 0.0000000E+00 14 Mn++ 0.6588493E-03 0.1292685E-08 0.6588480E-03 0.0000000E+00 15 HPO4-- 0.2248620E-03 0.3692751E-06 0.2244927E-03 0.0000000E+00 Chg. balance for solid moles: 0.6549E-16 Mass of aqueous solution: 0.996217E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 37.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3605E-01 -1.443 9.453 0.976 22.79 3.629 andradite 0.4212E-02 -2.375 2.141 0.331 5.160 0.5562 grossular 0.2101E-03 -3.678 0.9464E-01 -1.024 0.2281 0.2633E-01 apatite-OH 0.7483E-04 -4.126 0.3759E-01 -1.425 0.9061E-01 0.1194E-01 clinochlore 0.6032E-02 -2.220 3.353 0.525 8.081 1.275 daphnite 0.2709E-02 -2.567 1.933 0.286 4.659 0.5856 chlorite-Mn 0.1318E-03 -3.880 0.9342E-01 -1.030 0.2252 0.2977E-01 microcline 0.7468E-02 -2.127 2.079 0.318 5.010 0.8119 stilbite 0.3008E-01 -1.522 21.20 1.326 51.09 9.886 stilpnomelane-Fe 0.1025E-02 -2.989 1.105 0.043 2.664 0.3817 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9525E+00 0.9525E+00 1.0000 -0.021 grossular 0.4751E-01 0.4751E-01 1.0000 -1.323 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6798E+00 0.6798E+00 1.0000 -0.168 daphnite 0.3053E+00 0.3053E+00 1.0000 -0.515 chlorite-Mn 0.1485E-01 0.1485E-01 1.0000 -1.828 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 41.484277 g Volume = 17.193777 cm3 Porosity: -6.1370% V(tot) - V(min): -.99418E+00 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 37.9990000 g log = 1.5798 Original solution: 1000.0103000 g Original solution / Rock added: 26.32 (Water/Rock Ratio), log = 1.4202 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1422E-06 1.0073 0.1507E-06 0.1496E-06 CH4,gas 0.3878E-12 1.0129 0.4132E-12 0.4079E-12 H2,gas 0.1240E-04 1.0006 0.1305E-04 0.1304E-04 H2S,gas 0.7644E-11 0.9959 0.8009E-11 0.8042E-11 S2,gas 0.1341E-31 1.0000 0.1410E-31 0.1410E-31 CO,gas 0.4844E-15 1.0000 0.5096E-15 0.5096E-15 SO3,gas 0.7967E-40 1.0000 0.8381E-40 0.8381E-40 SO2,gas 0.3934E-22 1.0000 0.4138E-22 0.4138E-22 HCl,gas 0.4577E-17 1.0000 0.4815E-17 0.4815E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.48529E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.19 -8.82 -2.941 0.15063E+05 -6.822 3 CH4,gas 4.81 -9.57 -14.38 -3.596 0.24560E+05 -12.384 4 H2,gas 8.29 1.40 -6.88 -3.934 0.11755E+05 -4.884 5 H2S,gas -5.94 -19.04 -13.10 -6.548 0.22362E+05 -11.096 6 S2,gas -7.03 -40.88 -33.85 -5.208 0.57799E+05 -31.851 7 CO,gas 3.51 -13.78 -17.29 -5.321 0.29527E+05 -15.293 8 SO3,gas 17.43 -24.65 -42.08 -10.519 0.71845E+05 -40.077 9 SO2,gas 1.14 -23.25 -24.38 -6.502 0.41634E+05 -22.383 10 HCl,gas 5.48 -13.84 -19.32 -9.659 0.32984E+05 -17.317 11 acmite 7.74 7.35 -0.39 -0.040 0.65990E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.02 -4.53 -0.226 0.77338E+04 20 analcite 3.37 2.92 -0.45 -0.050 0.77110E+03 26 annite 20.21 17.51 -2.70 -0.150 0.46123E+04 27 phlogopite 27.15 24.61 -2.54 -0.141 0.43304E+04 29 anorthite 12.80 8.83 -3.97 -0.305 0.67728E+04 35 aragonite 0.99 -2.89 -3.87 -1.291 0.66117E+04 36 brucite 12.58 9.01 -3.56 -0.713 0.60829E+04 37 calcite 0.83 -2.89 -3.72 -1.240 0.63504E+04 38 carnegieite-low 9.06 6.17 -2.90 -0.414 0.49485E+04 39 carnegieite-high 10.13 6.17 -3.97 -0.567 0.67753E+04 40 carpholite-Mg 8.65 5.55 -3.10 -0.207 0.53003E+04 41 carpholite-Fe 6.78 3.18 -3.60 -0.240 0.61540E+04 42 celadonite 5.40 3.33 -2.07 -0.122 0.35270E+04 43 celadonite-Fe 3.94 0.97 -2.97 -0.175 0.50703E+04 44 chrysotile 23.94 20.55 -3.39 -0.282 0.57882E+04 50 chloritoid-Mg 13.26 8.79 -4.47 -0.298 0.76284E+04 51 chloritoid-Fe 9.24 6.43 -2.81 -0.188 0.48023E+04 52 chloritoid-Mn 11.46 8.69 -2.77 -0.185 0.47327E+04 54 coesite -2.37 -3.25 -0.88 -0.293 0.14992E+04 61 cristobalite -2.55 -3.25 -0.70 -0.233 0.11921E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.51 -1.38 -0.230 0.23608E+04 67 diopside 16.22 14.82 -1.40 -0.140 0.23857E+04 68 hedenbergite 14.24 12.45 -1.79 -0.179 0.30625E+04 75 epidote 24.78 23.83 -0.95 -0.046 0.16172E+04 76 clinozoisite 22.92 19.40 -3.52 -0.160 0.60188E+04 77 epidote-Fe 29.94 28.26 -1.68 -0.087 0.28632E+04 78 fayalite 14.08 10.05 -4.03 -0.576 0.68864E+04 79 ferrosilite 11.19 6.80 -4.39 -0.439 0.74945E+04 83 gibbsite 4.10 1.51 -2.58 -0.369 0.44120E+04 84 glaucophane 23.11 19.89 -3.22 -0.087 0.54977E+04 85 glaucophane-Fe 17.42 12.79 -4.63 -0.125 0.79036E+04 87 greenalite 16.19 13.45 -2.75 -0.229 0.46941E+04 90 hematite 12.60 11.89 -0.71 -0.086 0.12071E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.92 -1.33 -0.133 0.22741E+04 96 julgoldite 70.57 66.79 -3.79 -0.098 0.64656E+04 97 kalsilite 7.62 4.06 -3.56 -0.508 0.60739E+04 98 kaolinite -1.27 -3.47 -2.19 -0.200 0.37474E+04 101 laumontite 2.97 2.34 -0.64 -0.043 0.10897E+04 102 lawsonite 9.68 8.83 -0.85 -0.056 0.14467E+04 103 leucite 4.17 0.82 -3.35 -0.335 0.57235E+04 105 lizardite 23.29 20.55 -2.74 -0.228 0.46784E+04 107 magnetite 20.13 18.54 -1.60 -0.130 0.27242E+04 108 minnesotaite 10.46 6.95 -3.51 -0.206 0.59940E+04 120 muscovite 2.68 0.60 -2.08 -0.123 0.35585E+04 121 paragonite 4.34 2.70 -1.64 -0.096 0.27970E+04 122 nepheline 8.38 6.17 -2.21 -0.316 0.37764E+04 128 periclase-Fe 11.64 6.65 -4.99 -1.248 0.85246E+04 134 phlogopite-Na 29.73 26.71 -3.02 -0.168 0.51523E+04 136 prehnite 19.47 17.88 -1.58 -0.093 0.27040E+04 137 prehnite-Fe 22.59 22.31 -0.27 -0.016 0.46472E+03 138 pumpellyite-Fe 46.47 43.93 -2.55 -0.057 0.43456E+04 139 pumpellyite-Mg 49.19 46.29 -2.90 -0.064 0.49535E+04 145 pyroxmangite 7.42 5.66 -1.75 -0.350 0.29906E+04 146 pyrophyllite -6.10 -9.96 -3.86 -0.242 0.65988E+04 147 quartz -2.98 -3.25 -0.27 -0.088 0.45316E+03 152 rhodonite 7.46 5.66 -1.80 -0.360 0.30699E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.02 -2.58 -0.077 0.44047E+04 171 talc 16.55 14.05 -2.50 -0.147 0.42699E+04 174 tephroite 18.11 14.58 -3.54 -0.505 0.60384E+04 177 topaz-H 4.67 -0.22 -4.89 -0.444 0.83462E+04 178 tridymite -2.61 -3.25 -0.63 -0.211 0.10804E+04 179 tremolite 48.00 43.69 -4.31 -0.117 0.73660E+04 187 wairakite 4.06 2.34 -1.72 -0.101 0.29405E+04 188 walstromite 11.53 9.05 -2.48 -0.495 0.42282E+04 189 wollastonite 10.48 9.05 -1.43 -0.286 0.24421E+04 190 pseudo-wollastonite 11.02 9.05 -1.97 -0.394 0.33607E+04 191 zoisite 22.96 19.40 -3.57 -0.162 0.60913E+04 192 akaganeite 7.77 5.95 -1.82 -0.394 0.31117E+04 193 beidellite-Ca -1.56 -6.36 -4.80 -0.297 0.82003E+04 197 beidellite-Na -1.26 -5.78 -4.53 -0.277 0.77305E+04 199 chalcedony -2.79 -3.25 -0.45 -0.151 0.77347E+03 201 montmorillonite-Ca -2.21 -5.46 -3.24 -0.201 0.55392E+04 202 montmorillonite-K -2.16 -5.57 -3.41 -0.209 0.58284E+04 203 montmorillonite-Mg -2.40 -6.00 -3.60 -0.223 0.61444E+04 204 montmorillonite-Na -1.96 -4.88 -2.92 -0.179 0.49853E+04 205 nontronite-Ca 3.28 2.50 -0.78 -0.050 0.13286E+04 206 nontronite-H 2.60 0.47 -2.12 -0.142 0.36259E+04 207 nontronite-K 3.40 2.39 -1.02 -0.065 0.17393E+04 208 nontronite-Mg 3.14 1.96 -1.18 -0.077 0.20144E+04 209 nontronite-Na 3.58 3.08 -0.50 -0.032 0.85973E+03 224 tobermorite 9.84 7.00 -2.84 -0.775 0.48515E+04 233 boehmite 4.43 1.51 -2.92 -0.486 0.49792E+04 235 ferrous-oxide 9.82 6.65 -3.18 -0.794 0.54257E+04 240 silica-amorphous -2.08 -3.25 -1.17 -0.389 0.19937E+04 242 an20ab80 2.08 1.50 -0.58 -0.044 0.98295E+03 243 an25ab75 2.71 1.96 -0.75 -0.058 0.12766E+04 244 an30ab70 3.34 2.42 -0.92 -0.071 0.15786E+04 245 tr.625ac.25prg.125 45.31 41.97 -3.34 -0.090 0.56996E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 37.9990000 g New total amount of reactant added: 38.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2995E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 7 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 38.9990000 Water: Moles liquid = 0.5524E+02 kg liquid = 0.9952E+00 Moles total = 0.5502E+02 kg total = 0.9912E+00 Activity = 1.0000 Stoichiometric ionic strength = .6302360E-02 Osmotic coef. = 0.9586 True ionic strength = .1146377E-01 Chg. balance for total moles = 0.2995E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13727E-09 -9.8624 0.11913E-09 -9.9240 0.86789E+00 -0.0615 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13826E-03 -3.8593 0.11953E-03 -3.9225 0.86458E+00 -0.0632 4 SO4-- 0.25604E-04 -4.5917 0.15210E-04 -4.8179 0.59406E+00 -0.2262 5 HCO3- 0.61583E-05 -5.2105 0.53292E-05 -5.2733 0.86537E+00 -0.0628 6 HS- 0.21674E-08 -8.6641 0.18740E-08 -8.7272 0.86466E+00 -0.0632 7 Al+++ 0.16827E-27 -27.7740 0.52867E-28 -28.2768 0.31418E+00 -0.5028 8 H4SiO4 0.56717E-03 -3.2463 0.56717E-03 -3.2463 0.10000E+01 0.0000 9 Ca++ 0.51072E-07 -7.2918 0.30199E-07 -7.5200 0.59131E+00 -0.2282 10 Mg++ 0.25316E-10 -10.5966 0.14927E-10 -10.8260 0.58960E+00 -0.2294 11 Fe++ 0.10762E-12 -12.9681 0.63496E-13 -13.1973 0.59001E+00 -0.2291 12 K+ 0.89273E-04 -4.0493 0.77267E-04 -4.1120 0.86551E+00 -0.0627 13 Na+ 0.11341E-01 -1.9453 0.98045E-02 -2.0086 0.86449E+00 -0.0632 14 Mn++ 0.19986E-10 -10.6993 0.11798E-10 -10.9282 0.59032E+00 -0.2289 15 HPO4-- 0.33982E-06 -6.4687 0.20189E-06 -6.6949 0.59411E+00 -0.2261 16 HSiO3- 0.53726E-02 -2.2698 0.46450E-02 -2.3330 0.86458E+00 -0.0632 17 Ca(HSiO3)+ 0.36308E-08 -8.4400 0.31429E-08 -8.5027 0.86563E+00 -0.0627 18 Mg(HSiO3)+ 0.22334E-11 -11.6510 0.19333E-11 -11.7137 0.86563E+00 -0.0627 19 NaHSiO3,aq 0.72332E-03 -3.1407 0.72332E-03 -3.1407 0.10000E+01 0.0000 20 AlO+ 0.55553E-15 -15.2553 0.48088E-15 -15.3180 0.86563E+00 -0.0627 22 HAlO2,aq 0.80775E-09 -9.0927 0.80775E-09 -9.0927 0.10000E+01 0.0000 23 AlO2- 0.17531E-04 -4.7562 0.15139E-04 -4.8199 0.86359E+00 -0.0637 24 CH4,aq 0.64555E-15 -15.1901 0.64430E-15 -15.1909 0.99806E+00 -0.0008 29 CO,aq 0.39592E-18 -18.4024 0.39592E-18 -18.4024 0.10000E+01 0.0000 30 CO2,aq 0.12825E-08 -8.8919 0.12801E-08 -8.8928 0.99806E+00 -0.0008 31 CO3-2 0.69718E-05 -5.1567 0.41361E-05 -5.3834 0.59326E+00 -0.2268 32 CaCO3,aq 0.15298E-08 -8.8154 0.15298E-08 -8.8154 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.46847E-11 -11.3293 0.40552E-11 -11.3920 0.86563E+00 -0.0627 34 CaCl+ 0.66452E-11 -11.1775 0.57522E-11 -11.2402 0.86563E+00 -0.0627 35 CaCl2,aq 0.16009E-15 -15.7956 0.16009E-15 -15.7956 0.10000E+01 0.0000 36 CaOH+ 0.20649E-07 -7.6851 0.17875E-07 -7.7478 0.86563E+00 -0.0627 37 CaSO4,aq 0.14312E-09 -9.8443 0.14312E-09 -9.8443 0.10000E+01 0.0000 38 HCl,aq 0.26785E-14 -14.5721 0.26785E-14 -14.5721 0.10000E+01 0.0000 43 FeCl+ 0.13656E-16 -16.8647 0.11821E-16 -16.9273 0.86563E+00 -0.0627 46 FeO,aq 0.17692E-09 -9.7522 0.17692E-09 -9.7522 0.10000E+01 0.0000 47 FeOH+ 0.20413E-10 -10.6901 0.17670E-10 -10.7528 0.86563E+00 -0.0627 48 HFeO2- 0.18475E-07 -7.7334 0.15973E-07 -7.7966 0.86458E+00 -0.0632 49 FeO+ 0.45329E-15 -15.3436 0.39238E-15 -15.4063 0.86563E+00 -0.0627 51 FeO2- 0.62849E-08 -8.2017 0.54338E-08 -8.2649 0.86458E+00 -0.0632 52 HFeO2,aq 0.81015E-10 -10.0914 0.81015E-10 -10.0914 0.10000E+01 0.0000 53 H2,aq 0.12033E-07 -7.9196 0.12009E-07 -7.9205 0.99806E+00 -0.0008 54 KCl,aq 0.16354E-09 -9.7864 0.16354E-09 -9.7864 0.10000E+01 0.0000 55 KHSO4,aq 0.37466E-18 -18.4264 0.37466E-18 -18.4264 0.10000E+01 0.0000 56 KOH,aq 0.28275E-06 -6.5486 0.28275E-06 -6.5486 0.10000E+01 0.0000 57 KSO4- 0.20942E-07 -7.6790 0.18106E-07 -7.7422 0.86458E+00 -0.0632 58 MgCO3,aq 0.18894E-12 -12.7237 0.18894E-12 -12.7237 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23612E-14 -14.6269 0.20439E-14 -14.6895 0.86563E+00 -0.0627 60 MgCl+ 0.29817E-14 -14.5255 0.25811E-14 -14.5882 0.86563E+00 -0.0627 61 MgOH+ 0.56544E-10 -10.2476 0.48946E-10 -10.3103 0.86563E+00 -0.0627 63 MnO,aq 0.87755E-09 -9.0567 0.87755E-09 -9.0567 0.10000E+01 0.0000 64 MnOH+ 0.35235E-09 -9.4530 0.30500E-09 -9.5157 0.86563E+00 -0.0627 65 MnO2-2 0.36044E-11 -11.4432 0.21384E-11 -11.6699 0.59326E+00 -0.2268 66 HMnO2- 0.63839E-10 -10.1949 0.55194E-10 -10.2581 0.86458E+00 -0.0632 69 MnCl+ 0.98603E-14 -14.0061 0.85353E-14 -14.0688 0.86563E+00 -0.0627 70 MnSO4,aq 0.50857E-13 -13.2936 0.50857E-13 -13.2936 0.10000E+01 0.0000 71 NaCl,aq 0.38267E-06 -6.4172 0.38267E-06 -6.4172 0.10000E+01 0.0000 72 NaOH,aq 0.36163E-04 -4.4417 0.36163E-04 -4.4417 0.10000E+01 0.0000 74 OH- 0.58304E-02 -2.2343 0.50350E-02 -2.2980 0.86359E+00 -0.0637 79 HPO3-2 0.12909E-16 -16.8891 0.76581E-17 -17.1159 0.59326E+00 -0.2268 82 H3PO4,aq 0.18447E-16 -16.7341 0.18447E-16 -16.7341 0.10000E+01 0.0000 83 H2PO4- 0.48744E-09 -9.3121 0.42168E-09 -9.3750 0.86509E+00 -0.0629 84 PO4-3 0.45665E-08 -8.3404 0.14800E-08 -8.8297 0.32410E+00 -0.4893 87 H2P2O7-2 0.23458E-19 -19.6297 0.13916E-19 -19.8565 0.59326E+00 -0.2268 88 HP2O7-3 0.76199E-16 -16.1180 0.23953E-16 -16.6206 0.31435E+00 -0.5026 89 P2O7-4 0.37645E-15 -15.4243 0.49602E-16 -16.3045 0.13176E+00 -0.8802 90 H2S,aq 0.67209E-12 -12.1726 0.67079E-12 -12.1734 0.99806E+00 -0.0008 91 S2-2 0.10841E-19 -19.9649 0.64318E-20 -20.1917 0.59326E+00 -0.2268 97 SO3-2 0.41601E-13 -13.3809 0.24906E-13 -13.6037 0.59869E+00 -0.2228 98 HSO3- 0.20084E-15 -15.6972 0.17364E-15 -15.7603 0.86458E+00 -0.0632 99 HSO4- 0.19411E-11 -11.7119 0.16813E-11 -11.7744 0.86615E+00 -0.0624 101 S2O3-2 0.20269E-18 -18.6932 0.12025E-18 -18.9199 0.59326E+00 -0.2268 Charge balance for all species = 0.3065E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1372669E-09 -.1203992E-01 -.1212445E+02 0.0000 2 H2O 0.1000000E+01 0.5550806E+02 0.9990822E+06 0.0000 3 Cl- 0.1382555E-03 0.1386384E-03 0.4910664E+01 6.0015 4 SO4-- 0.2560399E-04 0.2562287E-04 0.2459129E+01 15.0301 5 HCO3- 0.6158303E-05 0.1313292E-04 0.8006030E+00 4.6506 6 HS- 0.2167357E-08 0.4380448E-08 0.1447380E-03 1.1967 7 Al+++ 0.1682674E-27 0.1753169E-04 0.4725999E+00 1.4951 8 H4SiO4 0.5671742E-03 0.6663092E-02 0.6398416E+03 -3.2463 9 Ca++ 0.5107202E-07 0.7703649E-07 0.3084652E-02 12.3279 10 Mg++ 0.2531645E-10 0.8428777E-10 0.2047335E-05 9.0219 11 Fe++ 0.1076192E-12 0.2503855E-07 0.1397052E-02 6.6507 12 K+ 0.8927298E-04 0.8957683E-04 0.3499438E+01 5.8120 13 Na+ 0.1134139E-01 0.1210125E-01 0.2779516E+03 7.9154 14 Mn++ 0.1998614E-10 0.1317386E-08 0.7230852E-04 8.9198 15 HPO4-- 0.3398223E-06 0.3448762E-06 0.3307068E-01 13.1531 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6457525E+00 -.1198224E-01 -.6337703E+00 0.0000000E+00 2 H2O 0.5501938E+02 0.5524212E+02 -.2227383E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1106300E-02 0.2550011E-04 0.1080800E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1080795E-02 0.4359462E-08 -.1080800E-02 0.0000000E+00 7 Al+++ 0.1271657E+00 0.1744770E-04 0.1271482E+00 0.0000000E+00 8 H4SiO4 0.4060881E+00 0.6631170E-02 0.3994570E+00 0.0000000E+00 9 Ca++ 0.4486888E-01 0.7666742E-07 0.4486881E-01 0.0000000E+00 10 Mg++ 0.3095159E-01 0.8388395E-10 0.3095159E-01 0.0000000E+00 11 Fe++ 0.2780662E-01 0.2491859E-07 0.2780660E-01 0.0000000E+00 12 K+ 0.8280042E-02 0.8914767E-04 0.8190895E-02 0.0000000E+00 13 Na+ 0.4911332E-01 0.1204328E-01 0.3707004E-01 0.0000000E+00 14 Mn++ 0.6761879E-03 0.1311074E-08 0.6761866E-03 0.0000000E+00 15 HPO4-- 0.2307796E-03 0.3432239E-06 0.2304363E-03 0.0000000E+00 Chg. balance for solid moles: -.3117E-16 Mass of aqueous solution: 0.996118E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 38.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3707E-01 -1.431 9.721 0.988 22.83 3.731 andradite 0.4323E-02 -2.364 2.197 0.342 5.160 0.5708 grossular 0.2300E-03 -3.638 0.1036 -0.985 0.2434 0.2883E-01 apatite-OH 0.7681E-04 -4.115 0.3858E-01 -1.414 0.9062E-01 0.1226E-01 clinochlore 0.6190E-02 -2.208 3.441 0.537 8.081 1.309 daphnite 0.2756E-02 -2.560 1.966 0.294 4.619 0.5959 chlorite-Mn 0.1352E-03 -3.869 0.9588E-01 -1.018 0.2252 0.3055E-01 microcline 0.7653E-02 -2.116 2.130 0.328 5.003 0.8321 stilbite 0.3083E-01 -1.511 21.72 1.337 51.02 10.13 stilpnomelane-Fe 0.1076E-02 -2.968 1.160 0.064 2.725 0.4007 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9495E+00 0.9495E+00 1.0000 -0.023 grossular 0.5052E-01 0.5052E-01 1.0000 -1.297 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6816E+00 0.6816E+00 1.0000 -0.166 daphnite 0.3035E+00 0.3035E+00 1.0000 -0.518 chlorite-Mn 0.1489E-01 0.1489E-01 1.0000 -1.827 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 42.575845 g Volume = 17.643336 cm3 Porosity: -6.2877% V(tot) - V(min): -.10437E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 38.9990000 g log = 1.5911 Original solution: 1000.0103000 g Original solution / Rock added: 25.64 (Water/Rock Ratio), log = 1.4090 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0519 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1383E-06 1.0073 0.1465E-06 0.1455E-06 CH4,gas 0.9562E-12 1.0129 0.1019E-11 0.1006E-11 H2,gas 0.1565E-04 1.0006 0.1647E-04 0.1646E-04 H2S,gas 0.1867E-10 0.9959 0.1956E-10 0.1964E-10 S2,gas 0.5023E-31 1.0000 0.5284E-31 0.5284E-31 CO,gas 0.5943E-15 1.0000 0.6252E-15 0.6252E-15 SO3,gas 0.7672E-40 1.0000 0.8070E-40 0.8070E-40 SO2,gas 0.4780E-22 1.0000 0.5029E-22 0.5029E-22 HCl,gas 0.4496E-17 1.0000 0.4730E-17 0.4730E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.20 -8.83 -2.945 0.15084E+05 -6.834 3 CH4,gas 4.81 -9.18 -13.99 -3.498 0.23891E+05 -11.992 4 H2,gas 8.29 1.50 -6.78 -3.876 0.11582E+05 -4.783 5 H2S,gas -5.94 -18.65 -12.71 -6.354 0.21699E+05 -10.709 6 S2,gas -7.03 -40.31 -33.28 -5.120 0.56820E+05 -31.277 7 CO,gas 3.51 -13.69 -17.20 -5.294 0.29375E+05 -15.204 8 SO3,gas 17.43 -24.67 -42.09 -10.523 0.71873E+05 -40.093 9 SO2,gas 1.14 -23.16 -24.30 -6.480 0.41489E+05 -22.299 10 HCl,gas 5.48 -13.85 -19.33 -9.663 0.32997E+05 -17.325 11 acmite 7.74 7.32 -0.42 -0.043 0.70979E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.01 -4.54 -0.227 0.77507E+04 20 analcite 3.37 2.92 -0.45 -0.050 0.77300E+03 26 annite 20.21 17.52 -2.69 -0.149 0.45915E+04 27 phlogopite 27.15 24.63 -2.51 -0.140 0.42903E+04 29 anorthite 12.80 8.83 -3.97 -0.306 0.67823E+04 35 aragonite 0.99 -2.87 -3.86 -1.285 0.65833E+04 36 brucite 12.58 9.02 -3.55 -0.711 0.60695E+04 37 calcite 0.83 -2.87 -3.70 -1.234 0.63220E+04 38 carnegieite-low 9.06 6.16 -2.90 -0.414 0.49523E+04 39 carnegieite-high 10.13 6.16 -3.97 -0.567 0.67791E+04 40 carpholite-Mg 8.65 5.52 -3.13 -0.209 0.53458E+04 41 carpholite-Fe 6.78 3.15 -3.63 -0.242 0.62059E+04 42 celadonite 5.40 3.34 -2.06 -0.121 0.35117E+04 43 celadonite-Fe 3.94 0.97 -2.96 -0.174 0.50615E+04 44 chrysotile 23.94 20.57 -3.36 -0.280 0.57443E+04 50 chloritoid-Mg 13.26 8.77 -4.50 -0.300 0.76758E+04 51 chloritoid-Fe 9.24 6.39 -2.84 -0.190 0.48562E+04 52 chloritoid-Mn 11.46 8.66 -2.80 -0.187 0.47802E+04 54 coesite -2.37 -3.25 -0.88 -0.292 0.14973E+04 61 cristobalite -2.55 -3.25 -0.70 -0.232 0.11902E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.50 -1.40 -0.233 0.23922E+04 67 diopside 16.22 14.86 -1.36 -0.136 0.23191E+04 68 hedenbergite 14.24 12.49 -1.76 -0.176 0.30023E+04 75 epidote 24.78 23.81 -0.97 -0.047 0.16547E+04 76 clinozoisite 22.92 19.40 -3.52 -0.160 0.60083E+04 77 epidote-Fe 29.94 28.21 -1.73 -0.090 0.29487E+04 78 fayalite 14.08 10.06 -4.02 -0.575 0.68706E+04 79 ferrosilite 11.19 6.81 -4.38 -0.438 0.74768E+04 83 gibbsite 4.10 1.50 -2.60 -0.372 0.44433E+04 84 glaucophane 23.11 19.92 -3.19 -0.086 0.54539E+04 85 glaucophane-Fe 17.42 12.80 -4.61 -0.125 0.78790E+04 87 greenalite 16.19 13.46 -2.73 -0.228 0.46694E+04 90 hematite 12.60 11.80 -0.80 -0.097 0.13658E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.92 -1.33 -0.133 0.22760E+04 96 julgoldite 70.57 66.73 -3.84 -0.100 0.65600E+04 97 kalsilite 7.62 4.06 -3.56 -0.508 0.60777E+04 98 kaolinite -1.27 -3.50 -2.23 -0.203 0.38064E+04 101 laumontite 2.97 2.33 -0.64 -0.043 0.10954E+04 102 lawsonite 9.68 8.83 -0.85 -0.057 0.14562E+04 103 leucite 4.17 0.81 -3.35 -0.335 0.57254E+04 105 lizardite 23.29 20.57 -2.71 -0.226 0.46346E+04 107 magnetite 20.13 18.45 -1.68 -0.137 0.28760E+04 108 minnesotaite 10.46 6.97 -3.49 -0.206 0.59655E+04 120 muscovite 2.68 0.56 -2.12 -0.125 0.36212E+04 121 paragonite 4.34 2.66 -1.67 -0.099 0.28597E+04 122 nepheline 8.38 6.16 -2.21 -0.316 0.37802E+04 128 periclase-Fe 11.64 6.65 -4.99 -1.247 0.85176E+04 134 phlogopite-Na 29.73 26.74 -2.99 -0.166 0.51122E+04 136 prehnite 19.47 17.91 -1.56 -0.092 0.26621E+04 137 prehnite-Fe 22.59 22.31 -0.28 -0.017 0.47087E+03 138 pumpellyite-Fe 46.47 43.96 -2.51 -0.056 0.42863E+04 139 pumpellyite-Mg 49.19 46.33 -2.86 -0.064 0.48878E+04 145 pyroxmangite 7.42 5.67 -1.74 -0.349 0.29754E+04 146 pyrophyllite -6.10 -9.99 -3.90 -0.244 0.66539E+04 147 quartz -2.98 -3.25 -0.26 -0.088 0.45126E+03 152 rhodonite 7.46 5.67 -1.79 -0.358 0.30546E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.04 -2.56 -0.076 0.43726E+04 171 talc 16.55 14.08 -2.47 -0.145 0.42222E+04 174 tephroite 18.11 14.59 -3.52 -0.503 0.60097E+04 177 topaz-H 4.67 -0.26 -4.92 -0.448 0.84070E+04 178 tridymite -2.61 -3.25 -0.63 -0.211 0.10786E+04 179 tremolite 48.00 43.80 -4.21 -0.114 0.71851E+04 187 wairakite 4.06 2.33 -1.73 -0.101 0.29462E+04 188 walstromite 11.53 9.08 -2.45 -0.489 0.41768E+04 189 wollastonite 10.48 9.08 -1.40 -0.280 0.23907E+04 190 pseudo-wollastonite 11.02 9.08 -1.94 -0.388 0.33094E+04 191 zoisite 22.96 19.40 -3.56 -0.162 0.60809E+04 192 akaganeite 7.77 5.90 -1.87 -0.404 0.31910E+04 193 beidellite-Ca -1.56 -6.40 -4.84 -0.299 0.82582E+04 197 beidellite-Na -1.26 -5.82 -4.56 -0.279 0.77881E+04 199 chalcedony -2.79 -3.25 -0.45 -0.151 0.77157E+03 201 montmorillonite-Ca -2.21 -5.48 -3.26 -0.202 0.55714E+04 202 montmorillonite-K -2.16 -5.59 -3.43 -0.210 0.58603E+04 203 montmorillonite-Mg -2.40 -6.02 -3.62 -0.224 0.61825E+04 204 montmorillonite-Na -1.96 -4.90 -2.94 -0.180 0.50172E+04 205 nontronite-Ca 3.28 2.41 -0.87 -0.056 0.14826E+04 206 nontronite-H 2.60 0.38 -2.22 -0.149 0.37880E+04 207 nontronite-K 3.40 2.30 -1.11 -0.071 0.18929E+04 208 nontronite-Mg 3.14 1.87 -1.27 -0.083 0.21743E+04 209 nontronite-Na 3.58 2.99 -0.59 -0.038 0.10133E+04 224 tobermorite 9.84 7.02 -2.82 -0.768 0.48084E+04 233 boehmite 4.43 1.50 -2.93 -0.489 0.50106E+04 235 ferrous-oxide 9.82 6.65 -3.17 -0.793 0.54187E+04 240 silica-amorphous -2.08 -3.25 -1.17 -0.389 0.19918E+04 242 an20ab80 2.08 1.50 -0.58 -0.044 0.98484E+03 243 an25ab75 2.71 1.96 -0.75 -0.058 0.12790E+04 244 an30ab70 3.34 2.42 -0.93 -0.071 0.15814E+04 245 tr.625ac.25prg.125 45.31 42.07 -3.24 -0.087 0.55375E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 38.9990000 g New total amount of reactant added: 39.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.2998E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 6 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 39.9990000 Water: Moles liquid = 0.5524E+02 kg liquid = 0.9951E+00 Moles total = 0.5501E+02 kg total = 0.9910E+00 Activity = 1.0000 Stoichiometric ionic strength = .6418391E-02 Osmotic coef. = 0.9583 True ionic strength = .1167202E-01 Chg. balance for total moles = 0.2998E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13520E-09 -9.8690 0.11723E-09 -9.9310 0.86707E+00 -0.0619 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13827E-03 -3.8593 0.11942E-03 -3.9229 0.86372E+00 -0.0636 4 SO4-- 0.25604E-04 -4.5917 0.15151E-04 -4.8196 0.59175E+00 -0.2279 5 HCO3- 0.60968E-05 -5.2149 0.52708E-05 -5.2781 0.86452E+00 -0.0632 6 HS- 0.51896E-08 -8.2849 0.44827E-08 -8.3485 0.86380E+00 -0.0636 7 Al+++ 0.15519E-27 -27.8091 0.48326E-28 -28.3158 0.31140E+00 -0.5067 8 H4SiO4 0.56875E-03 -3.2451 0.56875E-03 -3.2451 0.10000E+01 0.0000 9 Ca++ 0.52907E-07 -7.2765 0.31161E-07 -7.5064 0.58897E+00 -0.2299 10 Mg++ 0.25048E-10 -10.6012 0.14709E-10 -10.8324 0.58725E+00 -0.2312 11 Fe++ 0.10555E-12 -12.9765 0.62029E-13 -13.2074 0.58766E+00 -0.2309 12 K+ 0.90897E-04 -4.0414 0.78595E-04 -4.1046 0.86466E+00 -0.0632 13 Na+ 0.11548E-01 -1.9375 0.99731E-02 -2.0012 0.86362E+00 -0.0637 14 Mn++ 0.19774E-10 -10.7039 0.11626E-10 -10.9346 0.58797E+00 -0.2306 15 HPO4-- 0.31691E-06 -6.4991 0.18755E-06 -6.7269 0.59180E+00 -0.2278 16 HSiO3- 0.54805E-02 -2.2612 0.47336E-02 -2.3248 0.86372E+00 -0.0636 17 Ca(HSiO3)+ 0.38216E-08 -8.4178 0.33048E-08 -8.4809 0.86478E+00 -0.0631 18 Mg(HSiO3)+ 0.22451E-11 -11.6488 0.19415E-11 -11.7119 0.86478E+00 -0.0631 19 NaHSiO3,aq 0.74978E-03 -3.1251 0.74978E-03 -3.1251 0.10000E+01 0.0000 20 AlO+ 0.52496E-15 -15.2799 0.45397E-15 -15.3430 0.86478E+00 -0.0631 22 HAlO2,aq 0.77494E-09 -9.1107 0.77494E-09 -9.1107 0.10000E+01 0.0000 23 AlO2- 0.17109E-04 -4.7668 0.14760E-04 -4.8309 0.86271E+00 -0.0641 24 CH4,aq 0.15333E-14 -14.8144 0.15303E-14 -14.8152 0.99803E+00 -0.0009 29 CO,aq 0.48161E-18 -18.3173 0.48161E-18 -18.3173 0.10000E+01 0.0000 30 CO2,aq 0.12482E-08 -8.9037 0.12458E-08 -8.9046 0.99803E+00 -0.0009 31 CO3-2 0.70348E-05 -5.1527 0.41572E-05 -5.3812 0.59094E+00 -0.2285 32 CaCO3,aq 0.15866E-08 -8.7995 0.15866E-08 -8.7995 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.47855E-11 -11.3201 0.41384E-11 -11.3832 0.86478E+00 -0.0631 34 CaCl+ 0.68570E-11 -11.1639 0.59298E-11 -11.2270 0.86478E+00 -0.0631 35 CaCl2,aq 0.16488E-15 -15.7828 0.16488E-15 -15.7828 0.10000E+01 0.0000 36 CaOH+ 0.21674E-07 -7.6641 0.18743E-07 -7.7272 0.86478E+00 -0.0631 37 CaSO4,aq 0.14710E-09 -9.8324 0.14710E-09 -9.8324 0.10000E+01 0.0000 38 HCl,aq 0.26333E-14 -14.5795 0.26333E-14 -14.5795 0.10000E+01 0.0000 43 FeCl+ 0.13341E-16 -16.8748 0.11537E-16 -16.9379 0.86478E+00 -0.0631 46 FeO,aq 0.17849E-09 -9.7484 0.17849E-09 -9.7484 0.10000E+01 0.0000 47 FeOH+ 0.20285E-10 -10.6928 0.17542E-10 -10.7559 0.86478E+00 -0.0631 48 HFeO2- 0.18961E-07 -7.7221 0.16377E-07 -7.7858 0.86372E+00 -0.0636 49 FeO+ 0.40291E-15 -15.3948 0.34843E-15 -15.4579 0.86478E+00 -0.0631 51 FeO2- 0.57695E-08 -8.2389 0.49832E-08 -8.3025 0.86372E+00 -0.0636 52 HFeO2,aq 0.73109E-10 -10.1360 0.73109E-10 -10.1360 0.10000E+01 0.0000 53 H2,aq 0.15040E-07 -7.8228 0.15010E-07 -7.8236 0.99803E+00 -0.0009 54 KCl,aq 0.16619E-09 -9.7794 0.16619E-09 -9.7794 0.10000E+01 0.0000 55 KHSO4,aq 0.37355E-18 -18.4276 0.37355E-18 -18.4276 0.10000E+01 0.0000 56 KOH,aq 0.29228E-06 -6.5342 0.29228E-06 -6.5342 0.10000E+01 0.0000 57 KSO4- 0.21241E-07 -7.6728 0.18346E-07 -7.7365 0.86372E+00 -0.0636 58 MgCO3,aq 0.18714E-12 -12.7278 0.18714E-12 -12.7278 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23036E-14 -14.6376 0.19921E-14 -14.7007 0.86478E+00 -0.0631 60 MgCl+ 0.29385E-14 -14.5319 0.25411E-14 -14.5950 0.86478E+00 -0.0631 61 MgOH+ 0.56681E-10 -10.2466 0.49017E-10 -10.3097 0.86478E+00 -0.0631 63 MnO,aq 0.89310E-09 -9.0491 0.89310E-09 -9.0491 0.10000E+01 0.0000 64 MnOH+ 0.35321E-09 -9.4520 0.30544E-09 -9.5151 0.86478E+00 -0.0631 65 MnO2-2 0.38033E-11 -11.4198 0.22475E-11 -11.6483 0.59094E+00 -0.2285 66 HMnO2- 0.66092E-10 -10.1799 0.57085E-10 -10.2435 0.86372E+00 -0.0636 69 MnCl+ 0.97173E-14 -14.0125 0.84033E-14 -14.0756 0.86478E+00 -0.0631 70 MnSO4,aq 0.49922E-13 -13.3017 0.49922E-13 -13.3017 0.10000E+01 0.0000 71 NaCl,aq 0.38889E-06 -6.4102 0.38889E-06 -6.4102 0.10000E+01 0.0000 72 NaOH,aq 0.37382E-04 -4.4273 0.37382E-04 -4.4273 0.10000E+01 0.0000 74 OH- 0.59311E-02 -2.2269 0.51168E-02 -2.2910 0.86271E+00 -0.0641 79 HPO3-2 0.15046E-16 -16.8226 0.88915E-17 -17.0510 0.59094E+00 -0.2285 82 H3PO4,aq 0.16593E-16 -16.7801 0.16593E-16 -16.7801 0.10000E+01 0.0000 83 H2PO4- 0.44600E-09 -9.3507 0.38545E-09 -9.4140 0.86424E+00 -0.0634 84 PO4-3 0.43473E-08 -8.3618 0.13972E-08 -8.8548 0.32138E+00 -0.4930 87 H2P2O7-2 0.19677E-19 -19.7060 0.11628E-19 -19.9345 0.59094E+00 -0.2285 88 HP2O7-3 0.65280E-16 -16.1852 0.20340E-16 -16.6917 0.31158E+00 -0.5064 89 P2O7-4 0.32993E-15 -15.4816 0.42803E-16 -16.3685 0.12974E+00 -0.8869 90 H2S,aq 0.15820E-11 -11.8008 0.15789E-11 -11.8016 0.99803E+00 -0.0009 91 S2-2 0.49826E-19 -19.3025 0.29444E-19 -19.5310 0.59094E+00 -0.2285 97 SO3-2 0.51989E-13 -13.2841 0.31008E-13 -13.5085 0.59643E+00 -0.2244 98 HSO3- 0.24629E-15 -15.6085 0.21273E-15 -15.6722 0.86372E+00 -0.0636 99 HSO4- 0.19045E-11 -11.7202 0.16480E-11 -11.7830 0.86531E+00 -0.0628 101 S2O3-2 0.47709E-18 -18.3214 0.28193E-18 -18.5499 0.59094E+00 -0.2285 Charge balance for all species = 0.3059E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1351999E-09 -.1227460E-01 -.1236055E+02 0.0000 2 H2O 0.1000000E+01 0.5550802E+02 0.9990639E+06 0.0000 3 Cl- 0.1382656E-03 0.1386547E-03 0.4911154E+01 6.0081 4 SO4-- 0.2560368E-04 0.2562204E-04 0.2459006E+01 15.0424 5 HCO3- 0.6096792E-05 0.1313446E-04 0.8006831E+00 4.6528 6 HS- 0.5189555E-08 0.8220751E-08 0.2716239E-03 1.5825 7 Al+++ 0.1551858E-27 0.1711011E-04 0.4612273E+00 1.4771 8 H4SiO4 0.5687464E-03 0.6799005E-02 0.6528815E+03 -3.2451 9 Ca++ 0.5290678E-07 0.8014762E-07 0.3209170E-02 12.3555 10 Mg++ 0.2504810E-10 0.8416688E-10 0.2044363E-05 9.0295 11 Fe++ 0.1055525E-12 0.2500246E-07 0.1395014E-02 6.6545 12 K+ 0.9089746E-04 0.9121115E-04 0.3563222E+01 5.8264 13 Na+ 0.1154797E-01 0.1233553E-01 0.2833276E+03 7.9298 14 Mn++ 0.1977392E-10 0.1336034E-08 0.7333076E-04 8.9274 15 HPO4-- 0.3169054E-06 0.3216987E-06 0.3084761E-01 13.1350 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6623110E+00 -.1221435E-01 -.6500967E+00 0.0000000E+00 2 H2O 0.5500685E+02 0.5523559E+02 -.2287439E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1134013E-02 0.2549629E-04 0.1108517E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1108509E-02 0.8180404E-08 -.1108517E-02 0.0000000E+00 7 Al+++ 0.1304264E+00 0.1702614E-04 0.1304094E+00 0.0000000E+00 8 H4SiO4 0.4165009E+00 0.6765635E-02 0.4097353E+00 0.0000000E+00 9 Ca++ 0.4601903E-01 0.7975426E-07 0.4601895E-01 0.0000000E+00 10 Mg++ 0.3174524E-01 0.8375379E-10 0.3174524E-01 0.0000000E+00 11 Fe++ 0.2851963E-01 0.2487975E-07 0.2851961E-01 0.0000000E+00 12 K+ 0.8492357E-02 0.9076349E-04 0.8401593E-02 0.0000000E+00 13 Na+ 0.5036856E-01 0.1227499E-01 0.3809358E-01 0.0000000E+00 14 Mn++ 0.6935265E-03 0.1329476E-08 0.6935252E-03 0.0000000E+00 15 HPO4-- 0.2366971E-03 0.3201198E-06 0.2363770E-03 0.0000000E+00 Chg. balance for solid moles: -.1194E-15 Mass of aqueous solution: 0.996018E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 39.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3809E-01 -1.419 9.989 1.000 22.87 3.835 andradite 0.4434E-02 -2.353 2.253 0.353 5.160 0.5854 grossular 0.2508E-03 -3.601 0.1130 -0.947 0.2587 0.3144E-01 apatite-OH 0.7879E-04 -4.104 0.3958E-01 -1.403 0.9064E-01 0.1258E-01 clinochlore 0.6349E-02 -2.197 3.529 0.548 8.082 1.342 daphnite 0.2802E-02 -2.553 1.999 0.301 4.578 0.6058 chlorite-Mn 0.1387E-03 -3.858 0.9834E-01 -1.007 0.2252 0.3134E-01 microcline 0.7837E-02 -2.106 2.181 0.339 4.996 0.8521 stilbite 0.3157E-01 -1.501 22.25 1.347 50.95 10.38 stilpnomelane-Fe 0.1128E-02 -2.948 1.216 0.085 2.785 0.4201 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9465E+00 0.9465E+00 1.0000 -0.024 grossular 0.5354E-01 0.5354E-01 1.0000 -1.271 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6834E+00 0.6834E+00 1.0000 -0.165 daphnite 0.3016E+00 0.3016E+00 1.0000 -0.521 chlorite-Mn 0.1493E-01 0.1493E-01 1.0000 -1.826 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 43.667319 g Volume = 18.092689 cm3 Porosity: -6.4301% V(tot) - V(min): -.10931E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 39.9990000 g log = 1.6020 Original solution: 1000.0103000 g Original solution / Rock added: 25.00 (Water/Rock Ratio), log = 1.3980 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1346E-06 1.0073 0.1426E-06 0.1416E-06 CH4,gas 0.2271E-11 1.0129 0.2420E-11 0.2389E-11 H2,gas 0.1956E-04 1.0006 0.2059E-04 0.2058E-04 H2S,gas 0.4395E-10 0.9959 0.4605E-10 0.4624E-10 S2,gas 0.1781E-30 1.0000 0.1874E-30 0.1874E-30 CO,gas 0.7229E-15 1.0000 0.7605E-15 0.7605E-15 SO3,gas 0.7400E-40 1.0000 0.7784E-40 0.7784E-40 SO2,gas 0.5763E-22 1.0000 0.6062E-22 0.6062E-22 HCl,gas 0.4420E-17 1.0000 0.4650E-17 0.4650E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.54595E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.21 -8.85 -2.949 0.15104E+05 -6.846 3 CH4,gas 4.81 -8.81 -13.62 -3.404 0.23249E+05 -11.616 4 H2,gas 8.29 1.60 -6.69 -3.821 0.11417E+05 -4.686 5 H2S,gas -5.94 -18.28 -12.34 -6.168 0.21065E+05 -10.337 6 S2,gas -7.03 -39.76 -32.73 -5.035 0.55881E+05 -30.727 7 CO,gas 3.51 -13.61 -17.12 -5.267 0.29230E+05 -15.119 8 SO3,gas 17.43 -24.68 -42.11 -10.527 0.71900E+05 -40.109 9 SO2,gas 1.14 -23.08 -24.22 -6.458 0.41350E+05 -22.217 10 HCl,gas 5.48 -13.85 -19.33 -9.666 0.33010E+05 -17.333 11 acmite 7.74 7.29 -0.44 -0.046 0.75723E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.00 -4.55 -0.227 0.77670E+04 20 analcite 3.37 2.92 -0.45 -0.050 0.77505E+03 26 annite 20.21 17.53 -2.68 -0.149 0.45718E+04 27 phlogopite 27.15 24.66 -2.49 -0.138 0.42513E+04 29 anorthite 12.80 8.82 -3.98 -0.306 0.67925E+04 35 aragonite 0.99 -2.85 -3.84 -1.280 0.65563E+04 36 brucite 12.58 9.03 -3.55 -0.709 0.60565E+04 37 calcite 0.83 -2.85 -3.69 -1.229 0.62950E+04 38 carnegieite-low 9.06 6.16 -2.90 -0.415 0.49564E+04 39 carnegieite-high 10.13 6.16 -3.97 -0.568 0.67832E+04 40 carpholite-Mg 8.65 5.49 -3.16 -0.210 0.53902E+04 41 carpholite-Fe 6.78 3.12 -3.66 -0.244 0.62568E+04 42 celadonite 5.40 3.35 -2.05 -0.120 0.34966E+04 43 celadonite-Fe 3.94 0.98 -2.96 -0.174 0.50529E+04 44 chrysotile 23.94 20.60 -3.34 -0.278 0.57011E+04 50 chloritoid-Mg 13.26 8.74 -4.52 -0.302 0.77223E+04 51 chloritoid-Fe 9.24 6.36 -2.88 -0.192 0.49091E+04 52 chloritoid-Mn 11.46 8.64 -2.83 -0.188 0.48266E+04 54 coesite -2.37 -3.25 -0.88 -0.292 0.14953E+04 61 cristobalite -2.55 -3.25 -0.70 -0.232 0.11882E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.48 -1.42 -0.237 0.24229E+04 67 diopside 16.22 14.89 -1.32 -0.132 0.22548E+04 68 hedenbergite 14.24 12.52 -1.72 -0.172 0.29445E+04 75 epidote 24.78 23.78 -0.99 -0.048 0.16920E+04 76 clinozoisite 22.92 19.41 -3.51 -0.160 0.60001E+04 77 epidote-Fe 29.94 28.16 -1.78 -0.092 0.30313E+04 78 fayalite 14.08 10.06 -4.01 -0.574 0.68555E+04 79 ferrosilite 11.19 6.82 -4.37 -0.437 0.74596E+04 83 gibbsite 4.10 1.48 -2.62 -0.374 0.44741E+04 84 glaucophane 23.11 19.94 -3.17 -0.086 0.54107E+04 85 glaucophane-Fe 17.42 12.82 -4.60 -0.124 0.78552E+04 87 greenalite 16.19 13.47 -2.72 -0.227 0.46457E+04 90 hematite 12.60 11.71 -0.89 -0.108 0.15180E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.92 -1.33 -0.133 0.22781E+04 96 julgoldite 70.57 66.68 -3.89 -0.101 0.66506E+04 97 kalsilite 7.62 4.06 -3.56 -0.509 0.60818E+04 98 kaolinite -1.27 -3.54 -2.26 -0.206 0.38638E+04 101 laumontite 2.97 2.33 -0.65 -0.043 0.11016E+04 102 lawsonite 9.68 8.82 -0.86 -0.057 0.14664E+04 103 leucite 4.17 0.81 -3.35 -0.335 0.57275E+04 105 lizardite 23.29 20.60 -2.69 -0.224 0.45914E+04 107 magnetite 20.13 18.36 -1.77 -0.144 0.30217E+04 108 minnesotaite 10.46 6.98 -3.48 -0.205 0.59377E+04 120 muscovite 2.68 0.52 -2.16 -0.127 0.36827E+04 121 paragonite 4.34 2.63 -1.71 -0.101 0.29212E+04 122 nepheline 8.38 6.16 -2.22 -0.317 0.37843E+04 128 periclase-Fe 11.64 6.65 -4.98 -1.246 0.85111E+04 134 phlogopite-Na 29.73 26.76 -2.97 -0.165 0.50732E+04 136 prehnite 19.47 17.93 -1.54 -0.090 0.26232E+04 137 prehnite-Fe 22.59 22.31 -0.28 -0.017 0.47734E+03 138 pumpellyite-Fe 46.47 43.99 -2.48 -0.055 0.42327E+04 139 pumpellyite-Mg 49.19 46.37 -2.83 -0.063 0.48277E+04 145 pyroxmangite 7.42 5.68 -1.73 -0.347 0.29603E+04 146 pyrophyllite -6.10 -10.03 -3.93 -0.246 0.67072E+04 147 quartz -2.98 -3.25 -0.26 -0.088 0.44921E+03 152 rhodonite 7.46 5.68 -1.78 -0.356 0.30395E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.05 -2.54 -0.076 0.43402E+04 171 talc 16.55 14.11 -2.45 -0.144 0.41749E+04 174 tephroite 18.11 14.61 -3.50 -0.500 0.59816E+04 177 topaz-H 4.67 -0.29 -4.96 -0.451 0.84665E+04 178 tridymite -2.61 -3.25 -0.63 -0.210 0.10765E+04 179 tremolite 48.00 43.90 -4.11 -0.111 0.70093E+04 187 wairakite 4.06 2.33 -1.73 -0.102 0.29524E+04 188 walstromite 11.53 9.11 -2.42 -0.483 0.41277E+04 189 wollastonite 10.48 9.11 -1.37 -0.274 0.23416E+04 190 pseudo-wollastonite 11.02 9.11 -1.91 -0.382 0.32602E+04 191 zoisite 22.96 19.41 -3.56 -0.162 0.60727E+04 192 akaganeite 7.77 5.85 -1.91 -0.414 0.32672E+04 193 beidellite-Ca -1.56 -6.43 -4.87 -0.301 0.83145E+04 197 beidellite-Na -1.26 -5.85 -4.59 -0.281 0.78441E+04 199 chalcedony -2.79 -3.25 -0.45 -0.150 0.76952E+03 201 montmorillonite-Ca -2.21 -5.50 -3.28 -0.203 0.56025E+04 202 montmorillonite-K -2.16 -5.61 -3.45 -0.211 0.58911E+04 203 montmorillonite-Mg -2.40 -6.04 -3.64 -0.225 0.62192E+04 204 montmorillonite-Na -1.96 -4.92 -2.96 -0.181 0.50480E+04 205 nontronite-Ca 3.28 2.33 -0.95 -0.062 0.16297E+04 206 nontronite-H 2.60 0.29 -2.31 -0.155 0.39429E+04 207 nontronite-K 3.40 2.21 -1.19 -0.077 0.20397E+04 208 nontronite-Mg 3.14 1.78 -1.36 -0.088 0.23270E+04 209 nontronite-Na 3.58 2.90 -0.68 -0.044 0.11601E+04 224 tobermorite 9.84 7.05 -2.79 -0.762 0.47671E+04 233 boehmite 4.43 1.48 -2.95 -0.492 0.50413E+04 235 ferrous-oxide 9.82 6.65 -3.17 -0.792 0.54122E+04 240 silica-amorphous -2.08 -3.25 -1.17 -0.388 0.19897E+04 242 an20ab80 2.08 1.50 -0.58 -0.044 0.98690E+03 243 an25ab75 2.71 1.96 -0.75 -0.058 0.12815E+04 244 an30ab70 3.34 2.42 -0.93 -0.071 0.15845E+04 245 tr.625ac.25prg.125 45.31 42.16 -3.15 -0.085 0.53804E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 1.0000000 g Current total amount of reactant added: 39.9990000 g New total amount of reactant added: 40.9990000 g Mixing fraction reached given limit of 0.4000E+02 TOTMIX = 0.4100E+02 Execution stopped.