File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.66231E+00 0.13520E-09 0.8671 0.00000000E+00 H2O 2 0. 0.55007E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13827E-03 0.8637 0.00000000E+00 SO4-- 4 -2. 0.11340E-02 0.25604E-04 0.5917 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.60968E-05 0.8645 0.00000000E+00 HS- 6 -1. -0.11085E-02 0.51896E-08 0.8638 0.00000000E+00 Al+++ 7 3. 0.13043E+00 0.15519E-27 0.3114 0.00000000E+00 H4SiO4 8 0. 0.41650E+00 0.56875E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.46019E-01 0.52907E-07 0.5890 0.00000000E+00 Mg++ 10 2. 0.31745E-01 0.25048E-10 0.5872 0.00000000E+00 Fe++ 11 2. 0.28520E-01 0.10555E-12 0.5877 0.00000000E+00 K+ 12 1. 0.84924E-02 0.90897E-04 0.8647 0.00000000E+00 Na+ 13 1. 0.50369E-01 0.11548E-01 0.8636 0.00000000E+00 Mn++ 14 2. 0.69353E-03 0.19774E-10 0.5880 0.00000000E+00 HPO4-- 15 -2. 0.23670E-03 0.31691E-06 0.5918 0.00000000E+00 Chg. balance for total moles = -.1499E-12 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 100.0000 SLIM = 0.800000E+02 TEMP = 100.0000 SINC = 0.2000E+01 TEMPC = 0.0000 TOTMIX = 0.399990E+02 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 16.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0107 MnO2-2 65 -2. 40.4376 Ca(HSiO3)+ 17 1. 7.6603 HMnO2- 66 -1. 29.1018 Mg(HSiO3)+ 18 1. 7.5653 MnO4- 67 -1. 83.3383 NaHSiO3,aq 19 0. 7.8098 MnO4-2 68 -2. 81.3024 AlO+ 20 1. 6.8891 MnCl+ 69 1. -0.7819 AlOH+2 21 2. 3.1893 MnSO4,aq 70 0. -2.4524 HAlO2,aq 22 0. 10.5878 NaCl,aq 71 0. 0.4861 AlO2- 23 -1. 16.2390 NaOH,aq 72 0. 12.3571 CH4,aq 24 0. 6.0082 O2,aq 73 0. 53.5759 C2H6,aq 25 0. 12.3556 OH- 74 -1. 12.2220 C3H8,aq 26 0. 17.3423 HO2- 75 -1. 50.7897 C4H10,aq 27 0. 22.3397 H2O2,aq 76 0. 40.0297 ethanol,aq 28 0. 15.3114 H3PO2,aq 77 0. 24.3310 CO,aq 29 0. 4.7087 H2PO2- 78 -1. 26.5491 CO2,aq 30 0. -6.3045 HPO3-2 79 -2. 11.9246 CO3-2 31 -2. 10.0340 H3PO3,aq 80 0. 3.5932 CaCO3,aq 32 0. 5.9460 H2PO3- 81 -1. 5.6314 Ca(HCO3)+ 33 1. -1.4013 H3PO4,aq 82 0. -9.8087 CaCl+ 34 1. -0.2023 H2PO4- 83 -1. -7.2438 CaCl2,aq 35 0. 0.4306 PO4-3 84 -3. 12.0588 CaOH+ 36 1. 10.1517 H4P2O7,aq 85 0. -17.7539 CaSO4,aq 37 0. -2.4936 H3P2O7- 86 -1. -15.8646 HCl,aq 38 0. 0.7256 H2P2O7-2 87 -2. -13.3812 HClO,aq 39 0. 32.4377 HP2O7-3 88 -3. -6.6931 ClO- 40 -1. 39.6416 P2O7-4 89 -4. 2.9147 HClO2,aq 41 0. 70.2060 H2S,aq 90 0. -6.4778 Fe+3 42 3. 8.3763 S2-2 91 -2. 1.2336 FeCl+ 43 1. -0.1924 S3-2 92 -2. -8.7963 FeCl2,aq 44 0. 4.3160 S3- 93 -1. -16.3178 FeCl+2 45 2. 6.5223 S4-2 94 -2. -18.6473 FeO,aq 46 0. 16.4029 S5-2 95 -2. -28.3223 FeOH+ 47 1. 7.4795 SO2,aq 96 0. -0.1980 HFeO2- 48 -1. 24.3713 SO3-2 97 -2. 10.2895 FeO+ 49 1. 11.3812 HSO3- 98 -1. 2.5222 FeOH+2 50 2. 9.1115 HSO4- 99 -1. -2.9675 FeO2- 51 -1. 24.0877 HSO5- 100 -1. 38.8657 HFeO2,aq 52 0. 15.9903 S2O3-2 101 -2. -4.5491 H2,aq 53 0. 9.4241 HS2O3- 102 -1. -6.8007 KCl,aq 54 0. 1.7519 H2S2O3,aq 103 0. -7.9944 KHSO4,aq 55 0. -0.4275 S2O4-2 104 -2. 10.5639 KOH,aq 56 0. 12.3606 HS2O4- 105 -1. 7.6762 KSO4- 57 -1. -1.1877 H2S2O4,aq 106 0. 6.6566 MgCO3,aq 58 0. 6.5483 S2O5-2 107 -2. 10.0891 Mg(HCO3)+ 59 1. -1.4098 S2O6-2 108 -2. 11.5737 MgCl+ 60 1. -0.1603 S2O8-2 109 -2. 42.1139 MgOH+ 61 1. 9.4082 S3O6-2 110 -2. 3.8101 Mn+3 62 3. 19.1332 S4O6-2 111 -2. -17.8301 MnO,aq 63 0. 17.9765 S5O6-2 112 -2. -14.1051 MnOH+ 64 1. 8.5115 113 0. 10.3157 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.984 0.0000E+00 osumilite(2) 124 20.895 0.0000E+00 CO2,gas 2 -6.363 0.0000E+00 osumilite-Fe 125 14.657 0.0000E+00 CH4,gas 3 4.809 0.0000E+00 pargasite 126 65.279 0.0000E+00 H2,gas 4 8.287 0.0000E+00 periclase 127 16.149 0.0000E+00 H2S,gas 5 -5.943 0.0000E+00 periclase-Fe 128 11.639 0.0000E+00 S2,gas 6 -7.033 0.0000E+00 perovskite-Al 129 12.395 0.0000E+00 CO,gas 7 3.510 0.0000E+00 perovskite-Ca 130 23.818 0.0000E+00 SO3,gas 8 17.427 0.0000E+00 perovskite-Fe 131 21.158 0.0000E+00 SO2,gas 9 1.136 0.0000E+00 perovskite-Mg 132 23.132 0.0000E+00 HCl,gas 10 5.479 0.0000E+00 phase_A 133 80.267 0.0000E+00 acmite 11 7.737 0.0000E+00 phlogopite-Na 134 29.731 0.0000E+00 akermanite 12 36.495 0.0000E+00 piemontite(ordered) 135 33.876 0.0000E+00 akimotoite 13 16.606 0.0000E+00 prehnite 136 19.466 0.0000E+00 akimotoite-Fe 14 13.083 0.0000E+00 prehnite-Fe 137 22.587 0.0000E+00 albite-high 15 0.750 0.0000E+00 pumpellyite-Fe 138 46.471 0.0000E+00 albite 16 -0.328 0.3809E-01 pumpellyite-Mg 139 49.194 0.0000E+00 almandine 17 24.545 0.0000E+00 px-Mg-tschermaks 140 19.687 0.0000E+00 pyrope 18 37.348 0.0000E+00 px-Ca-tschermaks 141 18.679 0.0000E+00 spessartine 19 24.550 0.0000E+00 pyrite 142 -21.225 0.0000E+00 analcite 20 3.371 0.0000E+00 pyrrhotite 143 -4.244 0.0000E+00 andalusite 21 5.062 0.0000E+00 pyrrhotiteFe0.875 144 -6.001 0.0000E+00 andradite 22 39.088 0.4434E-02 pyroxmangite 145 7.416 0.0000E+00 grossular 23 32.828 0.2508E-03 pyrophyllite 146 -6.098 0.0000E+00 anhydrite 24 -5.280 0.0000E+00 quartz 147 -2.982 0.0000E+00 ankerite 25 -2.093 0.0000E+00 rankinite 148 40.765 0.0000E+00 annite 26 20.209 0.0000E+00 ringwoodite-Fe 149 15.486 0.0000E+00 phlogopite 27 27.147 0.0000E+00 ringwoodite-Mg 150 27.602 0.0000E+00 biotite-Mn 28 33.034 0.0000E+00 rhodochrosite 151 -0.959 0.0000E+00 anorthite 29 12.798 0.0000E+00 rhodonite 152 7.462 0.0000E+00 anthophyllite 30 51.988 0.0000E+00 sanidine 153 -1.221 0.0000E+00 anthophyllite-Fe 31 29.455 0.0000E+00 sapphirine(351) 154 79.204 0.0000E+00 apatite-OH 32 -17.989 0.7879E-04 siderite 155 -2.588 0.0000E+00 apatite-OH-zs 33 -12.572 0.0000E+00 sillimanite 156 5.321 0.0000E+00 apatite-Cl-zs 34 -16.504 0.0000E+00 sodalite 157 50.255 0.0000E+00 aragonite 35 0.986 0.0000E+00 spinel 158 20.934 0.0000E+00 brucite 36 12.577 0.0000E+00 spurrite 159 59.566 0.0000E+00 calcite 37 0.833 0.0000E+00 staurolite-Fe 160 74.138 0.0000E+00 carnegieite-low 38 9.065 0.0000E+00 staurolite-Mg 161 90.336 0.0000E+00 carnegieite-high 39 10.134 0.0000E+00 staurolite-Mn 162 84.438 0.0000E+00 carpholite-Mg 40 8.650 0.0000E+00 stilbite 163 -7.406 0.3157E-01 carpholite-Fe 41 6.783 0.0000E+00 stilpnomelane-Fe 164 13.179 0.1128E-02 celadonite 42 5.401 0.0000E+00 stilpnomelane-Mg 165 27.596 0.0000E+00 celadonite-Fe 43 3.937 0.0000E+00 stishovite 166 2.721 0.0000E+00 chrysotile 44 23.937 0.0000E+00 sudoite-Fe 167 18.437 0.0000E+00 chondrodite 45 56.542 0.0000E+00 sudoite 168 21.216 0.0000E+00 clinochlore 46 39.193 0.6349E-02 sulfur 169 -9.141 0.0000E+00 daphnite 47 29.094 0.2802E-02 sylvite 170 1.345 0.0000E+00 chlorite-Mn 48 46.985 0.1387E-03 talc 171 16.553 0.0000E+00 chlorite-Al-free 49 47.262 0.0000E+00 talc-Fe 172 13.516 0.0000E+00 chloritoid-Mg 50 13.261 0.0000E+00 talc-tschermaks 173 19.189 0.0000E+00 chloritoid-Fe 51 9.239 0.0000E+00 tephroite 174 18.113 0.0000E+00 chloritoid-Mn 52 11.463 0.0000E+00 tilleyite 175 41.473 0.0000E+00 clinohumite 53 97.255 0.0000E+00 titanite-CaSi 176 15.497 0.0000E+00 coesite 54 -2.369 0.0000E+00 topaz-H 177 4.668 0.0000E+00 cordierite-H 55 23.898 0.0000E+00 tridymite 178 -2.615 0.0000E+00 cordierite 56 24.245 0.0000E+00 tremolite 179 48.003 0.0000E+00 cordierite-Fe 57 20.649 0.0000E+00 ferroactinolite 180 38.596 0.0000E+00 cordierite-Mn 58 25.261 0.0000E+00 troilite-low 181 -4.394 0.0000E+00 corundum 59 8.433 0.0000E+00 tschermakite 182 48.414 0.0000E+00 corundum-MgSi 60 18.905 0.0000E+00 vesuvianite 183 224.056 0.0000E+00 cristobalite 61 -2.549 0.0000E+00 wadeite-Si 184 20.233 0.0000E+00 cummingtonite 62 52.233 0.0000E+00 wadsleyite-Fe 185 15.711 0.0000E+00 cymrite-K 63 1.731 0.0000E+00 wadsleyite-Mg 186 25.878 0.0000E+00 deerite 64 95.982 0.0000E+00 wairakite 187 4.058 0.0000E+00 diaspore 65 2.896 0.0000E+00 walstromite 188 11.528 0.0000E+00 diamond 66 -3.107 0.0000E+00 wollastonite 189 10.482 0.0000E+00 diopside 67 16.215 0.0000E+00 pseudo-wollastonite 190 11.020 0.0000E+00 hedenbergite 68 14.244 0.0000E+00 zoisite 191 22.964 0.0000E+00 dolomite,ordered 69 0.587 0.0000E+00 akaganeite 192 7.768 0.0000E+00 eastonite 70 28.605 0.0000E+00 beidellite-Ca 193 -1.560 0.0000E+00 enstatite 71 17.301 0.0000E+00 beidellite-H 194 -2.241 0.0000E+00 clinoenstatite-HiP 72 18.388 0.0000E+00 beidellite-K 195 -1.435 0.0000E+00 clinoenstatite 73 17.202 0.0000E+00 beidellite-Mg 196 -1.707 0.0000E+00 protoenstatite 74 17.860 0.0000E+00 beidellite-Na 197 -1.257 0.0000E+00 epidote 75 24.775 0.0000E+00 calcium 198 84.043 0.0000E+00 clinozoisite 76 22.921 0.0000E+00 chalcedony 199 -2.794 0.0000E+00 epidote-Fe 77 29.937 0.0000E+00 dawsonite 200 1.714 0.0000E+00 fayalite 78 14.079 0.0000E+00 montmorillonite-Ca 201 -2.214 0.0000E+00 ferrosilite 79 11.188 0.0000E+00 montmorillonite-K 202 -2.161 0.0000E+00 forsterite 80 21.047 0.0000E+00 montmorillonite-Mg 203 -2.402 0.0000E+00 gedrite 81 50.725 0.0000E+00 montmorillonite-Na 204 -1.961 0.0000E+00 gehlenite 82 36.717 0.0000E+00 nontronite-Ca 205 3.280 0.0000E+00 gibbsite 83 4.097 0.0000E+00 nontronite-H 206 2.596 0.0000E+00 glaucophane 84 23.111 0.0000E+00 nontronite-K 207 3.404 0.0000E+00 glaucophane-Fe 85 17.417 0.0000E+00 nontronite-Mg 208 3.139 0.0000E+00 graphite 86 -3.549 0.0000E+00 nontronite-Na 209 3.583 0.0000E+00 greenalite 87 16.194 0.0000E+00 sepiolite 210 24.194 0.0000E+00 grunerite 88 31.364 0.0000E+00 alite 211 58.043 0.0000E+00 halite 89 1.582 0.0000E+00 belite 212 30.461 0.0000E+00 hematite 90 12.598 0.0000E+00 ettringite 213 43.354 0.0000E+00 heulandite 91 -5.707 0.0000E+00 gypsum 214 -4.924 0.0000E+00 hercynite 92 17.345 0.0000E+00 hemicarboaluminate 215 71.028 0.0000E+00 hollandite 93 25.702 0.0000E+00 hydrogarnet 216 60.721 0.0000E+00 iron 94 19.095 0.0000E+00 hydrogarnet-Si 217 50.654 0.0000E+00 jadeite 95 4.251 0.0000E+00 jennite 218 24.386 0.0000E+00 julgoldite 96 70.573 0.0000E+00 monosulfoaluminate 219 53.497 0.0000E+00 kalsilite 97 7.620 0.0000E+00 monocarboaluminate 220 61.966 0.0000E+00 kaolinite 98 -1.273 0.0000E+00 portlandite 221 18.282 0.0000E+00 kyanite 99 4.932 0.0000E+00 stratlingite 222 36.573 0.0000E+00 larnite-bredigite 100 30.714 0.0000E+00 tricarboaluminate 223 70.427 0.0000E+00 laumontite 101 2.975 0.0000E+00 tobermorite 224 9.839 0.0000E+00 lawsonite 102 9.678 0.0000E+00 C4AH13 225 81.870 0.0000E+00 leucite 103 4.168 0.0000E+00 C2AH8 226 45.260 0.0000E+00 lime 104 26.009 0.0000E+00 C3A 227 87.049 0.0000E+00 lizardite 105 23.287 0.0000E+00 C4AF 228 117.550 0.0000E+00 magnesite 106 0.709 0.0000E+00 CAH10 229 28.373 0.0000E+00 magnetite 107 20.133 0.0000E+00 alabandite 230 -0.962 0.0000E+00 minnesotaite 108 10.461 0.0000E+00 alunite 231 -10.224 0.0000E+00 minnesotaite-Mg 109 20.669 0.0000E+00 artinite 232 15.139 0.0000E+00 magnesioferrite 110 26.257 0.0000E+00 boehmite 233 4.430 0.0000E+00 majorite 111 53.314 0.0000E+00 dolomite,disordered 234 1.288 0.0000E+00 manganosite 112 14.068 0.0000E+00 ferrous-oxide 235 9.824 0.0000E+00 margarite 113 17.452 0.0000E+00 huntite 236 3.850 0.0000E+00 meionite 114 45.158 0.0000E+00 hydromagnesite 237 20.077 0.0000E+00 merwinite 115 55.988 0.0000E+00 nesquehonite 238 4.735 0.0000E+00 microcline 116 -2.432 0.7837E-02 potassium-oxide 239 69.039 0.0000E+00 monticellite 117 24.371 0.0000E+00 silica-amorphous 240 -2.080 0.0000E+00 mullite-Al 118 363.258 0.0000E+00 sodium-oxide 241 55.173 0.0000E+00 mullite-Si 119 7.324 0.0000E+00 an20ab80 242 2.079 0.0000E+00 muscovite 120 2.679 0.0000E+00 an25ab75 243 2.709 0.0000E+00 paragonite 121 4.337 0.0000E+00 an30ab70 244 3.344 0.0000E+00 nepheline 122 8.378 0.0000E+00 tr.625ac.25prg.125 245 45.308 0.0000E+00 osumilite(1) 123 21.978 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 39.9990000 g log = 1.6020 Original solution: 1000.0103000 g Original solution / Rock added: 25.00 (Water/Rock Ratio), log = 1.3980 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 39.9990000 Water: Moles liquid = 0.5524E+02 kg liquid = 0.9951E+00 Moles total = 0.5501E+02 kg total = 0.9910E+00 Activity = 1.0000 Stoichiometric ionic strength = .6418391E-02 Osmotic coef. = 0.9583 True ionic strength = .1167202E-01 Chg. balance for total moles = -.1499E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13520E-09 -9.8690 0.11723E-09 -9.9310 0.86707E+00 -0.0619 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13827E-03 -3.8593 0.11942E-03 -3.9229 0.86372E+00 -0.0636 4 SO4-- 0.25604E-04 -4.5917 0.15151E-04 -4.8196 0.59175E+00 -0.2279 5 HCO3- 0.60968E-05 -5.2149 0.52708E-05 -5.2781 0.86452E+00 -0.0632 6 HS- 0.51896E-08 -8.2849 0.44827E-08 -8.3485 0.86380E+00 -0.0636 7 Al+++ 0.15519E-27 -27.8091 0.48326E-28 -28.3158 0.31140E+00 -0.5067 8 H4SiO4 0.56875E-03 -3.2451 0.56875E-03 -3.2451 0.10000E+01 0.0000 9 Ca++ 0.52907E-07 -7.2765 0.31161E-07 -7.5064 0.58897E+00 -0.2299 10 Mg++ 0.25048E-10 -10.6012 0.14709E-10 -10.8324 0.58725E+00 -0.2312 11 Fe++ 0.10555E-12 -12.9765 0.62029E-13 -13.2074 0.58766E+00 -0.2309 12 K+ 0.90897E-04 -4.0414 0.78595E-04 -4.1046 0.86466E+00 -0.0632 13 Na+ 0.11548E-01 -1.9375 0.99731E-02 -2.0012 0.86362E+00 -0.0637 14 Mn++ 0.19774E-10 -10.7039 0.11626E-10 -10.9346 0.58797E+00 -0.2306 15 HPO4-- 0.31691E-06 -6.4991 0.18755E-06 -6.7269 0.59180E+00 -0.2278 16 HSiO3- 0.54805E-02 -2.2612 0.47336E-02 -2.3248 0.86372E+00 -0.0636 17 Ca(HSiO3)+ 0.38216E-08 -8.4178 0.33048E-08 -8.4809 0.86478E+00 -0.0631 18 Mg(HSiO3)+ 0.22451E-11 -11.6488 0.19415E-11 -11.7119 0.86478E+00 -0.0631 19 NaHSiO3,aq 0.74978E-03 -3.1251 0.74978E-03 -3.1251 0.10000E+01 0.0000 20 AlO+ 0.52496E-15 -15.2799 0.45397E-15 -15.3430 0.86478E+00 -0.0631 22 HAlO2,aq 0.77494E-09 -9.1107 0.77494E-09 -9.1107 0.10000E+01 0.0000 23 AlO2- 0.17109E-04 -4.7668 0.14760E-04 -4.8309 0.86271E+00 -0.0641 24 CH4,aq 0.15333E-14 -14.8144 0.15303E-14 -14.8152 0.99803E+00 -0.0009 29 CO,aq 0.48161E-18 -18.3173 0.48161E-18 -18.3173 0.10000E+01 0.0000 30 CO2,aq 0.12482E-08 -8.9037 0.12458E-08 -8.9046 0.99803E+00 -0.0009 31 CO3-2 0.70348E-05 -5.1527 0.41572E-05 -5.3812 0.59094E+00 -0.2285 32 CaCO3,aq 0.15866E-08 -8.7995 0.15866E-08 -8.7995 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.47855E-11 -11.3201 0.41384E-11 -11.3832 0.86478E+00 -0.0631 34 CaCl+ 0.68570E-11 -11.1639 0.59298E-11 -11.2270 0.86478E+00 -0.0631 35 CaCl2,aq 0.16488E-15 -15.7828 0.16488E-15 -15.7828 0.10000E+01 0.0000 36 CaOH+ 0.21674E-07 -7.6641 0.18743E-07 -7.7272 0.86478E+00 -0.0631 37 CaSO4,aq 0.14710E-09 -9.8324 0.14710E-09 -9.8324 0.10000E+01 0.0000 38 HCl,aq 0.26333E-14 -14.5795 0.26333E-14 -14.5795 0.10000E+01 0.0000 43 FeCl+ 0.13341E-16 -16.8748 0.11537E-16 -16.9379 0.86478E+00 -0.0631 46 FeO,aq 0.17849E-09 -9.7484 0.17849E-09 -9.7484 0.10000E+01 0.0000 47 FeOH+ 0.20285E-10 -10.6928 0.17542E-10 -10.7559 0.86478E+00 -0.0631 48 HFeO2- 0.18961E-07 -7.7221 0.16377E-07 -7.7858 0.86372E+00 -0.0636 49 FeO+ 0.40291E-15 -15.3948 0.34843E-15 -15.4579 0.86478E+00 -0.0631 51 FeO2- 0.57695E-08 -8.2389 0.49832E-08 -8.3025 0.86372E+00 -0.0636 52 HFeO2,aq 0.73109E-10 -10.1360 0.73109E-10 -10.1360 0.10000E+01 0.0000 53 H2,aq 0.15040E-07 -7.8228 0.15010E-07 -7.8236 0.99803E+00 -0.0009 54 KCl,aq 0.16619E-09 -9.7794 0.16619E-09 -9.7794 0.10000E+01 0.0000 55 KHSO4,aq 0.37355E-18 -18.4276 0.37355E-18 -18.4276 0.10000E+01 0.0000 56 KOH,aq 0.29228E-06 -6.5342 0.29228E-06 -6.5342 0.10000E+01 0.0000 57 KSO4- 0.21241E-07 -7.6728 0.18346E-07 -7.7365 0.86372E+00 -0.0636 58 MgCO3,aq 0.18714E-12 -12.7278 0.18714E-12 -12.7278 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23036E-14 -14.6376 0.19921E-14 -14.7007 0.86478E+00 -0.0631 60 MgCl+ 0.29385E-14 -14.5319 0.25411E-14 -14.5950 0.86478E+00 -0.0631 61 MgOH+ 0.56681E-10 -10.2466 0.49017E-10 -10.3097 0.86478E+00 -0.0631 63 MnO,aq 0.89310E-09 -9.0491 0.89310E-09 -9.0491 0.10000E+01 0.0000 64 MnOH+ 0.35321E-09 -9.4520 0.30544E-09 -9.5151 0.86478E+00 -0.0631 65 MnO2-2 0.38033E-11 -11.4198 0.22475E-11 -11.6483 0.59094E+00 -0.2285 66 HMnO2- 0.66092E-10 -10.1799 0.57085E-10 -10.2435 0.86372E+00 -0.0636 69 MnCl+ 0.97173E-14 -14.0125 0.84033E-14 -14.0756 0.86478E+00 -0.0631 70 MnSO4,aq 0.49922E-13 -13.3017 0.49922E-13 -13.3017 0.10000E+01 0.0000 71 NaCl,aq 0.38889E-06 -6.4102 0.38889E-06 -6.4102 0.10000E+01 0.0000 72 NaOH,aq 0.37382E-04 -4.4273 0.37382E-04 -4.4273 0.10000E+01 0.0000 74 OH- 0.59311E-02 -2.2269 0.51168E-02 -2.2910 0.86271E+00 -0.0641 79 HPO3-2 0.15046E-16 -16.8226 0.88915E-17 -17.0510 0.59094E+00 -0.2285 82 H3PO4,aq 0.16593E-16 -16.7801 0.16593E-16 -16.7801 0.10000E+01 0.0000 83 H2PO4- 0.44600E-09 -9.3507 0.38545E-09 -9.4140 0.86424E+00 -0.0634 84 PO4-3 0.43473E-08 -8.3618 0.13972E-08 -8.8548 0.32138E+00 -0.4930 87 H2P2O7-2 0.19677E-19 -19.7060 0.11628E-19 -19.9345 0.59094E+00 -0.2285 88 HP2O7-3 0.65280E-16 -16.1852 0.20340E-16 -16.6917 0.31158E+00 -0.5064 89 P2O7-4 0.32993E-15 -15.4816 0.42803E-16 -16.3685 0.12974E+00 -0.8869 90 H2S,aq 0.15820E-11 -11.8008 0.15789E-11 -11.8016 0.99803E+00 -0.0009 91 S2-2 0.49826E-19 -19.3025 0.29444E-19 -19.5310 0.59094E+00 -0.2285 97 SO3-2 0.51989E-13 -13.2841 0.31008E-13 -13.5085 0.59643E+00 -0.2244 98 HSO3- 0.24629E-15 -15.6085 0.21273E-15 -15.6722 0.86372E+00 -0.0636 99 HSO4- 0.19045E-11 -11.7202 0.16480E-11 -11.7830 0.86531E+00 -0.0628 101 S2O3-2 0.47709E-18 -18.3214 0.28193E-18 -18.5499 0.59094E+00 -0.2285 Charge balance for all species = -.1505E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1351999E-09 -.1227460E-01 -.1236055E+02 0.0000 2 H2O 0.1000000E+01 0.5550802E+02 0.9990639E+06 0.0000 3 Cl- 0.1382656E-03 0.1386547E-03 0.4911154E+01 6.0081 4 SO4-- 0.2560368E-04 0.2562204E-04 0.2459006E+01 15.0424 5 HCO3- 0.6096792E-05 0.1313446E-04 0.8006831E+00 4.6528 6 HS- 0.5189555E-08 0.8220752E-08 0.2716239E-03 1.5825 7 Al+++ 0.1551858E-27 0.1711011E-04 0.4612273E+00 1.4771 8 H4SiO4 0.5687464E-03 0.6799005E-02 0.6528815E+03 -3.2451 9 Ca++ 0.5290678E-07 0.8014762E-07 0.3209170E-02 12.3555 10 Mg++ 0.2504810E-10 0.8416688E-10 0.2044363E-05 9.0295 11 Fe++ 0.1055525E-12 0.2500246E-07 0.1395014E-02 6.6545 12 K+ 0.9089746E-04 0.9121115E-04 0.3563222E+01 5.8264 13 Na+ 0.1154797E-01 0.1233553E-01 0.2833276E+03 7.9298 14 Mn++ 0.1977392E-10 0.1336034E-08 0.7333076E-04 8.9274 15 HPO4-- 0.3169054E-06 0.3216987E-06 0.3084761E-01 13.1350 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6623110E+00 -.1221435E-01 -.6500967E+00 0.0000000E+00 2 H2O 0.5500685E+02 0.5523559E+02 -.2287439E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1134013E-02 0.2549629E-04 0.1108517E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1108509E-02 0.8180404E-08 -.1108517E-02 0.0000000E+00 7 Al+++ 0.1304264E+00 0.1702614E-04 0.1304094E+00 0.0000000E+00 8 H4SiO4 0.4165009E+00 0.6765635E-02 0.4097353E+00 0.0000000E+00 9 Ca++ 0.4601903E-01 0.7975426E-07 0.4601895E-01 0.0000000E+00 10 Mg++ 0.3174524E-01 0.8375379E-10 0.3174524E-01 0.0000000E+00 11 Fe++ 0.2851963E-01 0.2487975E-07 0.2851961E-01 0.0000000E+00 12 K+ 0.8492357E-02 0.9076349E-04 0.8401593E-02 0.0000000E+00 13 Na+ 0.5036856E-01 0.1227499E-01 0.3809358E-01 0.0000000E+00 14 Mn++ 0.6935265E-03 0.1329476E-08 0.6935252E-03 0.0000000E+00 15 HPO4-- 0.2366971E-03 0.3201198E-06 0.2363770E-03 0.0000000E+00 Chg. balance for solid moles: -.1083E-15 Mass of aqueous solution: 0.996018E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 39.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3809E-01 -1.419 9.989 1.000 22.87 3.835 andradite 0.4434E-02 -2.353 2.253 0.353 5.160 0.5854 grossular 0.2508E-03 -3.601 0.1130 -0.947 0.2587 0.3144E-01 apatite-OH 0.7879E-04 -4.104 0.3958E-01 -1.403 0.9064E-01 0.1258E-01 clinochlore 0.6349E-02 -2.197 3.529 0.548 8.082 1.342 daphnite 0.2802E-02 -2.553 1.999 0.301 4.578 0.6058 chlorite-Mn 0.1387E-03 -3.858 0.9834E-01 -1.007 0.2252 0.3134E-01 microcline 0.7837E-02 -2.106 2.181 0.339 4.996 0.8521 stilbite 0.3157E-01 -1.501 22.25 1.347 50.95 10.38 stilpnomelane-Fe 0.1128E-02 -2.948 1.216 0.085 2.785 0.4201 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9465E+00 0.9465E+00 1.0000 -0.024 grossular 0.5354E-01 0.5354E-01 1.0000 -1.271 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6834E+00 0.6834E+00 1.0000 -0.165 daphnite 0.3016E+00 0.3016E+00 1.0000 -0.521 chlorite-Mn 0.1493E-01 0.1493E-01 1.0000 -1.826 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 43.667319 g Volume = 18.092689 cm3 Porosity: -6.4301% V(tot) - V(min): -.10931E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 39.9990000 g log = 1.6020 Original solution: 1000.0103000 g Original solution / Rock added: 25.00 (Water/Rock Ratio), log = 1.3980 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1346E-06 1.0073 0.1426E-06 0.1416E-06 CH4,gas 0.2271E-11 1.0129 0.2420E-11 0.2389E-11 H2,gas 0.1956E-04 1.0006 0.2059E-04 0.2058E-04 H2S,gas 0.4395E-10 0.9959 0.4605E-10 0.4624E-10 S2,gas 0.1781E-30 1.0000 0.1874E-30 0.1874E-30 CO,gas 0.7229E-15 1.0000 0.7605E-15 0.7605E-15 SO3,gas 0.7400E-40 1.0000 0.7784E-40 0.7784E-40 SO2,gas 0.5763E-22 1.0000 0.6062E-22 0.6062E-22 HCl,gas 0.4420E-17 1.0000 0.4650E-17 0.4650E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.21 -8.85 -2.949 0.15104E+05 -6.846 3 CH4,gas 4.81 -8.81 -13.62 -3.404 0.23249E+05 -11.616 4 H2,gas 8.29 1.60 -6.69 -3.821 0.11417E+05 -4.686 5 H2S,gas -5.94 -18.28 -12.34 -6.168 0.21065E+05 -10.337 6 S2,gas -7.03 -39.76 -32.73 -5.035 0.55881E+05 -30.727 7 CO,gas 3.51 -13.61 -17.12 -5.267 0.29230E+05 -15.119 8 SO3,gas 17.43 -24.68 -42.11 -10.527 0.71900E+05 -40.109 9 SO2,gas 1.14 -23.08 -24.22 -6.458 0.41350E+05 -22.217 10 HCl,gas 5.48 -13.85 -19.33 -9.666 0.33010E+05 -17.333 11 acmite 7.74 7.29 -0.44 -0.046 0.75723E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 20.00 -4.55 -0.227 0.77670E+04 20 analcite 3.37 2.92 -0.45 -0.050 0.77505E+03 26 annite 20.21 17.53 -2.68 -0.149 0.45718E+04 27 phlogopite 27.15 24.66 -2.49 -0.138 0.42513E+04 29 anorthite 12.80 8.82 -3.98 -0.306 0.67925E+04 35 aragonite 0.99 -2.85 -3.84 -1.280 0.65563E+04 36 brucite 12.58 9.03 -3.55 -0.709 0.60565E+04 37 calcite 0.83 -2.85 -3.69 -1.229 0.62950E+04 38 carnegieite-low 9.06 6.16 -2.90 -0.415 0.49564E+04 39 carnegieite-high 10.13 6.16 -3.97 -0.568 0.67832E+04 40 carpholite-Mg 8.65 5.49 -3.16 -0.210 0.53902E+04 41 carpholite-Fe 6.78 3.12 -3.66 -0.244 0.62568E+04 42 celadonite 5.40 3.35 -2.05 -0.120 0.34966E+04 43 celadonite-Fe 3.94 0.98 -2.96 -0.174 0.50529E+04 44 chrysotile 23.94 20.60 -3.34 -0.278 0.57011E+04 50 chloritoid-Mg 13.26 8.74 -4.52 -0.302 0.77223E+04 51 chloritoid-Fe 9.24 6.36 -2.88 -0.192 0.49091E+04 52 chloritoid-Mn 11.46 8.64 -2.83 -0.188 0.48266E+04 54 coesite -2.37 -3.25 -0.88 -0.292 0.14953E+04 61 cristobalite -2.55 -3.25 -0.70 -0.232 0.11882E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.48 -1.42 -0.237 0.24229E+04 67 diopside 16.22 14.89 -1.32 -0.132 0.22548E+04 68 hedenbergite 14.24 12.52 -1.72 -0.172 0.29445E+04 75 epidote 24.78 23.78 -0.99 -0.048 0.16920E+04 76 clinozoisite 22.92 19.41 -3.51 -0.160 0.60001E+04 77 epidote-Fe 29.94 28.16 -1.78 -0.092 0.30313E+04 78 fayalite 14.08 10.06 -4.01 -0.574 0.68555E+04 79 ferrosilite 11.19 6.82 -4.37 -0.437 0.74596E+04 83 gibbsite 4.10 1.48 -2.62 -0.374 0.44741E+04 84 glaucophane 23.11 19.94 -3.17 -0.086 0.54107E+04 85 glaucophane-Fe 17.42 12.82 -4.60 -0.124 0.78552E+04 87 greenalite 16.19 13.47 -2.72 -0.227 0.46457E+04 90 hematite 12.60 11.71 -0.89 -0.108 0.15180E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.92 -1.33 -0.133 0.22781E+04 96 julgoldite 70.57 66.68 -3.89 -0.101 0.66506E+04 97 kalsilite 7.62 4.06 -3.56 -0.509 0.60818E+04 98 kaolinite -1.27 -3.54 -2.26 -0.206 0.38638E+04 101 laumontite 2.97 2.33 -0.65 -0.043 0.11016E+04 102 lawsonite 9.68 8.82 -0.86 -0.057 0.14664E+04 103 leucite 4.17 0.81 -3.35 -0.335 0.57275E+04 105 lizardite 23.29 20.60 -2.69 -0.224 0.45914E+04 107 magnetite 20.13 18.36 -1.77 -0.144 0.30217E+04 108 minnesotaite 10.46 6.98 -3.48 -0.205 0.59377E+04 120 muscovite 2.68 0.52 -2.16 -0.127 0.36827E+04 121 paragonite 4.34 2.63 -1.71 -0.101 0.29212E+04 122 nepheline 8.38 6.16 -2.22 -0.317 0.37843E+04 128 periclase-Fe 11.64 6.65 -4.98 -1.246 0.85111E+04 134 phlogopite-Na 29.73 26.76 -2.97 -0.165 0.50732E+04 136 prehnite 19.47 17.93 -1.54 -0.090 0.26232E+04 137 prehnite-Fe 22.59 22.31 -0.28 -0.017 0.47734E+03 138 pumpellyite-Fe 46.47 43.99 -2.48 -0.055 0.42327E+04 139 pumpellyite-Mg 49.19 46.37 -2.83 -0.063 0.48277E+04 145 pyroxmangite 7.42 5.68 -1.73 -0.347 0.29603E+04 146 pyrophyllite -6.10 -10.03 -3.93 -0.246 0.67072E+04 147 quartz -2.98 -3.25 -0.26 -0.088 0.44921E+03 152 rhodonite 7.46 5.68 -1.78 -0.356 0.30395E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.05 -2.54 -0.076 0.43402E+04 171 talc 16.55 14.11 -2.45 -0.144 0.41749E+04 174 tephroite 18.11 14.61 -3.50 -0.500 0.59816E+04 177 topaz-H 4.67 -0.29 -4.96 -0.451 0.84665E+04 178 tridymite -2.61 -3.25 -0.63 -0.210 0.10765E+04 179 tremolite 48.00 43.90 -4.11 -0.111 0.70093E+04 187 wairakite 4.06 2.33 -1.73 -0.102 0.29524E+04 188 walstromite 11.53 9.11 -2.42 -0.483 0.41277E+04 189 wollastonite 10.48 9.11 -1.37 -0.274 0.23416E+04 190 pseudo-wollastonite 11.02 9.11 -1.91 -0.382 0.32602E+04 191 zoisite 22.96 19.41 -3.56 -0.162 0.60727E+04 192 akaganeite 7.77 5.85 -1.91 -0.414 0.32672E+04 193 beidellite-Ca -1.56 -6.43 -4.87 -0.301 0.83145E+04 197 beidellite-Na -1.26 -5.85 -4.59 -0.281 0.78441E+04 199 chalcedony -2.79 -3.25 -0.45 -0.150 0.76952E+03 201 montmorillonite-Ca -2.21 -5.50 -3.28 -0.203 0.56025E+04 202 montmorillonite-K -2.16 -5.61 -3.45 -0.211 0.58911E+04 203 montmorillonite-Mg -2.40 -6.04 -3.64 -0.225 0.62192E+04 204 montmorillonite-Na -1.96 -4.92 -2.96 -0.181 0.50480E+04 205 nontronite-Ca 3.28 2.33 -0.95 -0.062 0.16297E+04 206 nontronite-H 2.60 0.29 -2.31 -0.155 0.39429E+04 207 nontronite-K 3.40 2.21 -1.19 -0.077 0.20397E+04 208 nontronite-Mg 3.14 1.78 -1.36 -0.088 0.23270E+04 209 nontronite-Na 3.58 2.90 -0.68 -0.044 0.11601E+04 224 tobermorite 9.84 7.05 -2.79 -0.762 0.47671E+04 233 boehmite 4.43 1.48 -2.95 -0.492 0.50413E+04 235 ferrous-oxide 9.82 6.65 -3.17 -0.792 0.54122E+04 240 silica-amorphous -2.08 -3.25 -1.17 -0.388 0.19897E+04 242 an20ab80 2.08 1.50 -0.58 -0.044 0.98690E+03 243 an25ab75 2.71 1.96 -0.75 -0.058 0.12815E+04 244 an30ab70 3.34 2.42 -0.93 -0.071 0.15845E+04 245 tr.625ac.25prg.125 45.31 42.16 -3.15 -0.085 0.53804E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 39.9990000 g New total amount of reactant added: 41.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1498E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 8 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 41.9990000 Water: Moles liquid = 0.5522E+02 kg liquid = 0.9949E+00 Moles total = 0.5498E+02 kg total = 0.9905E+00 Activity = 1.0000 Stoichiometric ionic strength = .6644791E-02 Osmotic coef. = 0.9577 True ionic strength = .1207680E-01 Chg. balance for total moles = -.1498E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.13143E-09 -9.8813 0.11376E-09 -9.9440 0.86552E+00 -0.0627 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13829E-03 -3.8592 0.11921E-03 -3.9237 0.86207E+00 -0.0645 4 SO4-- 0.25588E-04 -4.5920 0.15029E-04 -4.8231 0.58737E+00 -0.2311 5 HCO3- 0.59819E-05 -5.2232 0.51618E-05 -5.2872 0.86290E+00 -0.0640 6 HS- 0.26772E-07 -7.5723 0.23081E-07 -7.6367 0.86215E+00 -0.0644 7 Al+++ 0.13306E-27 -27.8759 0.40739E-28 -28.3900 0.30616E+00 -0.5140 8 H4SiO4 0.57222E-03 -3.2424 0.57222E-03 -3.2424 0.10000E+01 0.0000 9 Ca++ 0.56517E-07 -7.2478 0.33036E-07 -7.4810 0.58453E+00 -0.2332 10 Mg++ 0.24586E-10 -10.6093 0.14328E-10 -10.8438 0.58277E+00 -0.2345 11 Fe++ 0.10180E-12 -12.9923 0.59367E-13 -13.2265 0.58319E+00 -0.2342 12 K+ 0.94055E-04 -4.0266 0.81173E-04 -4.0906 0.86304E+00 -0.0640 13 Na+ 0.11950E-01 -1.9226 0.10300E-01 -1.9872 0.86197E+00 -0.0645 14 Mn++ 0.19409E-10 -10.7120 0.11325E-10 -10.9460 0.58351E+00 -0.2340 15 HPO4-- 0.27826E-06 -6.5556 0.16345E-06 -6.7866 0.58742E+00 -0.2311 16 HSiO3- 0.56931E-02 -2.2447 0.49078E-02 -2.3091 0.86207E+00 -0.0645 17 Ca(HSiO3)+ 0.42086E-08 -8.3759 0.36327E-08 -8.4398 0.86316E+00 -0.0639 18 Mg(HSiO3)+ 0.22716E-11 -11.6437 0.19608E-11 -11.7076 0.86316E+00 -0.0639 19 NaHSiO3,aq 0.80288E-03 -3.0954 0.80288E-03 -3.0954 0.10000E+01 0.0000 20 AlO+ 0.47084E-15 -15.3271 0.40641E-15 -15.3910 0.86316E+00 -0.0639 22 HAlO2,aq 0.71493E-09 -9.1457 0.71493E-09 -9.1457 0.10000E+01 0.0000 23 AlO2- 0.16298E-04 -4.7879 0.14033E-04 -4.8529 0.86104E+00 -0.0650 24 CH4,aq 0.77946E-14 -14.1082 0.77787E-14 -14.1091 0.99796E+00 -0.0009 29 CO,aq 0.69603E-18 -18.1574 0.69603E-18 -18.1574 0.10000E+01 0.0000 30 CO2,aq 0.11863E-08 -8.9258 0.11839E-08 -8.9267 0.99796E+00 -0.0009 31 CO3-2 0.71528E-05 -5.1455 0.41954E-05 -5.3772 0.58654E+00 -0.2317 32 CaCO3,aq 0.16975E-08 -8.7702 0.16975E-08 -8.7702 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.49779E-11 -11.3030 0.42967E-11 -11.3669 0.86316E+00 -0.0639 34 CaCl+ 0.72706E-11 -11.1384 0.62757E-11 -11.2023 0.86316E+00 -0.0639 35 CaCl2,aq 0.17419E-15 -15.7590 0.17419E-15 -15.7590 0.10000E+01 0.0000 36 CaOH+ 0.23724E-07 -7.6248 0.20478E-07 -7.6887 0.86316E+00 -0.0639 37 CaSO4,aq 0.15470E-09 -9.8105 0.15470E-09 -9.8105 0.10000E+01 0.0000 38 HCl,aq 0.25508E-14 -14.5933 0.25508E-14 -14.5933 0.10000E+01 0.0000 43 FeCl+ 0.12770E-16 -16.8938 0.11023E-16 -16.9577 0.86316E+00 -0.0639 46 FeO,aq 0.18142E-09 -9.7413 0.18142E-09 -9.7413 0.10000E+01 0.0000 47 FeOH+ 0.20044E-10 -10.6980 0.17302E-10 -10.7619 0.86316E+00 -0.0639 48 HFeO2- 0.19898E-07 -7.7012 0.17153E-07 -7.7657 0.86207E+00 -0.0645 49 FeO+ 0.32285E-15 -15.4910 0.27867E-15 -15.5549 0.86316E+00 -0.0639 51 FeO2- 0.49096E-08 -8.3090 0.42324E-08 -8.3734 0.86207E+00 -0.0645 52 HFeO2,aq 0.60256E-10 -10.2200 0.60256E-10 -10.2200 0.10000E+01 0.0000 53 H2,aq 0.22874E-07 -7.6407 0.22827E-07 -7.6415 0.99796E+00 -0.0009 54 KCl,aq 0.17134E-09 -9.7661 0.17134E-09 -9.7661 0.10000E+01 0.0000 55 KHSO4,aq 0.37137E-18 -18.4302 0.37137E-18 -18.4302 0.10000E+01 0.0000 56 KOH,aq 0.31108E-06 -6.5071 0.31108E-06 -6.5071 0.10000E+01 0.0000 57 KSO4- 0.21803E-07 -7.6615 0.18795E-07 -7.7260 0.86207E+00 -0.0645 58 MgCO3,aq 0.18397E-12 -12.7353 0.18397E-12 -12.7353 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22016E-14 -14.6573 0.19003E-14 -14.7212 0.86316E+00 -0.0639 60 MgCl+ 0.28627E-14 -14.5432 0.24709E-14 -14.6071 0.86316E+00 -0.0639 61 MgOH+ 0.57004E-10 -10.2441 0.49204E-10 -10.3080 0.86316E+00 -0.0639 63 MnO,aq 0.92386E-09 -9.0344 0.92386E-09 -9.0344 0.10000E+01 0.0000 64 MnOH+ 0.35522E-09 -9.4495 0.30661E-09 -9.5134 0.86316E+00 -0.0639 65 MnO2-2 0.42094E-11 -11.3758 0.24690E-11 -11.6075 0.58654E+00 -0.2317 66 HMnO2- 0.70589E-10 -10.1513 0.60853E-10 -10.2157 0.86207E+00 -0.0645 69 MnCl+ 0.94665E-14 -14.0238 0.81711E-14 -14.0877 0.86316E+00 -0.0639 70 MnSO4,aq 0.48237E-13 -13.3166 0.48237E-13 -13.3166 0.10000E+01 0.0000 71 NaCl,aq 0.40094E-06 -6.3969 0.40094E-06 -6.3969 0.10000E+01 0.0000 72 NaOH,aq 0.39786E-04 -4.4003 0.39786E-04 -4.4003 0.10000E+01 0.0000 74 OH- 0.61240E-02 -2.2130 0.52730E-02 -2.2779 0.86104E+00 -0.0650 79 HPO3-2 0.20093E-16 -16.6970 0.11785E-16 -16.9287 0.58654E+00 -0.2317 82 H3PO4,aq 0.13618E-16 -16.8659 0.13618E-16 -16.8659 0.10000E+01 0.0000 83 H2PO4- 0.37791E-09 -9.4226 0.32599E-09 -9.4868 0.86261E+00 -0.0642 84 PO4-3 0.39677E-08 -8.4015 0.12548E-08 -8.9014 0.31626E+00 -0.5000 87 H2P2O7-2 0.14180E-19 -19.8483 0.83172E-20 -20.0800 0.58654E+00 -0.2317 88 HP2O7-3 0.48940E-16 -16.3103 0.14992E-16 -16.8241 0.30634E+00 -0.5138 89 P2O7-4 0.25815E-15 -15.5881 0.32513E-16 -16.4879 0.12595E+00 -0.8998 90 H2S,aq 0.79051E-11 -11.1021 0.78890E-11 -11.1030 0.99796E+00 -0.0009 91 S2-2 0.87513E-18 -18.0579 0.51330E-18 -18.2896 0.58654E+00 -0.2317 97 SO3-2 0.78997E-13 -13.1024 0.46778E-13 -13.3300 0.59215E+00 -0.2276 98 HSO3- 0.36124E-15 -15.4422 0.31141E-15 -15.5067 0.86207E+00 -0.0645 99 HSO4- 0.18367E-11 -11.7360 0.15863E-11 -11.7996 0.86371E+00 -0.0636 101 S2O3-2 0.23824E-17 -17.6230 0.13974E-17 -17.8547 0.58654E+00 -0.2317 Charge balance for all species = -.1414E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1314323E-09 -.1273246E-01 -.1282118E+02 0.0000 2 H2O 0.1000000E+01 0.5550795E+02 0.9990280E+06 0.0000 3 Cl- 0.1382861E-03 0.1386872E-03 0.4912135E+01 6.0203 4 SO4-- 0.2558753E-04 0.2560439E-04 0.2457227E+01 15.0650 5 HCO3- 0.5981890E-05 0.1313754E-04 0.8008430E+00 4.6568 6 HS- 0.2677182E-07 0.3187697E-07 0.1053218E-02 2.3073 7 Al+++ 0.1330622E-27 0.1629843E-04 0.4393319E+00 1.4421 8 H4SiO4 0.5722212E-03 0.7068173E-02 0.6787051E+03 -3.2424 9 Ca++ 0.5651742E-07 0.8631457E-07 0.3455979E-02 12.4070 10 Mg++ 0.2458650E-10 0.8405112E-10 0.2041480E-05 9.0442 11 Fe++ 0.1017977E-12 0.2506932E-07 0.1398696E-02 6.6616 12 K+ 0.9405483E-04 0.9438788E-04 0.3687195E+01 5.8534 13 Na+ 0.1194951E-01 0.1279258E-01 0.2938152E+03 7.9569 14 Mn++ 0.1940883E-10 0.1373340E-08 0.7537578E-04 8.9421 15 HPO4-- 0.2782572E-06 0.2826028E-06 0.2709778E-01 13.1014 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6954280E+00 -.1266700E-01 -.6827611E+00 0.0000000E+00 2 H2O 0.5498178E+02 0.5522257E+02 -.2407989E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1189440E-02 0.2547276E-04 0.1163967E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1163935E-02 0.3171308E-07 -.1163967E-02 0.0000000E+00 7 Al+++ 0.1369479E+00 0.1621463E-04 0.1369317E+00 0.0000000E+00 8 H4SiO4 0.4373265E+00 0.7031834E-02 0.4302946E+00 0.0000000E+00 9 Ca++ 0.4831931E-01 0.8587081E-07 0.4831923E-01 0.0000000E+00 10 Mg++ 0.3333254E-01 0.8361899E-10 0.3333254E-01 0.0000000E+00 11 Fe++ 0.2994565E-01 0.2494043E-07 0.2994562E-01 0.0000000E+00 12 K+ 0.8916985E-02 0.9390261E-04 0.8823083E-02 0.0000000E+00 13 Na+ 0.5287905E-01 0.1272681E-01 0.4015224E-01 0.0000000E+00 14 Mn++ 0.7282037E-03 0.1366279E-08 0.7282023E-03 0.0000000E+00 15 HPO4-- 0.2485323E-03 0.2811499E-06 0.2482512E-03 0.0000000E+00 Chg. balance for solid moles: 0.8858E-16 Mass of aqueous solution: 0.995819E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 41.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4015E-01 -1.396 10.53 1.022 22.96 4.042 andradite 0.4656E-02 -2.332 2.366 0.374 5.160 0.6147 grossular 0.2948E-03 -3.530 0.1328 -0.877 0.2896 0.3695E-01 apatite-OH 0.8275E-04 -4.082 0.4157E-01 -1.381 0.9066E-01 0.1321E-01 clinochlore 0.6667E-02 -2.176 3.705 0.569 8.082 1.409 daphnite 0.2891E-02 -2.539 2.063 0.314 4.499 0.6250 chlorite-Mn 0.1456E-03 -3.837 0.1033 -0.986 0.2252 0.3290E-01 microcline 0.8205E-02 -2.086 2.284 0.359 4.981 0.8921 stilbite 0.3305E-01 -1.481 23.29 1.367 50.80 10.86 stilpnomelane-Fe 0.1236E-02 -2.908 1.332 0.125 2.906 0.4602 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9404E+00 0.9404E+00 1.0000 -0.027 grossular 0.5955E-01 0.5955E-01 1.0000 -1.225 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6871E+00 0.6871E+00 1.0000 -0.163 daphnite 0.2979E+00 0.2979E+00 1.0000 -0.526 chlorite-Mn 0.1501E-01 0.1501E-01 1.0000 -1.824 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 45.850000 g Volume = 18.990798 cm3 Porosity: -6.6923% V(tot) - V(min): -.11912E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 41.9990000 g log = 1.6232 Original solution: 1000.0103000 g Original solution / Rock added: 23.81 (Water/Rock Ratio), log = 1.3768 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1279E-06 1.0073 0.1355E-06 0.1345E-06 CH4,gas 0.1154E-10 1.0129 0.1230E-10 0.1214E-10 H2,gas 0.2975E-04 1.0006 0.3131E-04 0.3129E-04 H2S,gas 0.2196E-09 0.9959 0.2301E-09 0.2310E-09 S2,gas 0.1923E-29 1.0000 0.2023E-29 0.2023E-29 CO,gas 0.1045E-14 1.0000 0.1099E-14 0.1099E-14 SO3,gas 0.6912E-40 1.0000 0.7271E-40 0.7271E-40 SO2,gas 0.8187E-22 1.0000 0.8612E-22 0.8612E-22 HCl,gas 0.4282E-17 1.0000 0.4504E-17 0.4504E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.23 -8.87 -2.956 0.15142E+05 -6.868 3 CH4,gas 4.81 -8.10 -12.91 -3.228 0.22044E+05 -10.910 4 H2,gas 8.29 1.78 -6.50 -3.717 0.11106E+05 -4.504 5 H2S,gas -5.94 -17.58 -11.64 -5.819 0.19872E+05 -9.638 6 S2,gas -7.03 -38.73 -31.69 -4.876 0.54117E+05 -29.694 7 CO,gas 3.51 -13.45 -16.96 -5.218 0.28957E+05 -14.959 8 SO3,gas 17.43 -24.71 -42.14 -10.535 0.71950E+05 -40.138 9 SO2,gas 1.14 -22.93 -24.06 -6.417 0.41090E+05 -22.065 10 HCl,gas 5.48 -13.87 -19.35 -9.673 0.33033E+05 -17.346 11 acmite 7.74 7.24 -0.50 -0.051 0.84536E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.98 -4.57 -0.228 0.77976E+04 20 analcite 3.37 2.91 -0.46 -0.051 0.77957E+03 26 annite 20.21 17.55 -2.66 -0.148 0.45356E+04 27 phlogopite 27.15 24.70 -2.45 -0.136 0.41759E+04 29 anorthite 12.80 8.81 -3.99 -0.307 0.68151E+04 35 aragonite 0.99 -2.82 -3.81 -1.270 0.65062E+04 36 brucite 12.58 9.04 -3.53 -0.706 0.60314E+04 37 calcite 0.83 -2.82 -3.66 -1.219 0.62448E+04 38 carnegieite-low 9.06 6.16 -2.91 -0.415 0.49654E+04 39 carnegieite-high 10.13 6.16 -3.98 -0.568 0.67923E+04 40 carpholite-Mg 8.65 5.44 -3.21 -0.214 0.54756E+04 41 carpholite-Fe 6.78 3.06 -3.72 -0.248 0.63552E+04 42 celadonite 5.40 3.37 -2.03 -0.119 0.34670E+04 43 celadonite-Fe 3.94 0.99 -2.95 -0.174 0.50363E+04 44 chrysotile 23.94 20.65 -3.29 -0.274 0.56167E+04 50 chloritoid-Mg 13.26 8.69 -4.58 -0.305 0.78122E+04 51 chloritoid-Fe 9.24 6.30 -2.94 -0.196 0.50120E+04 52 chloritoid-Mn 11.46 8.58 -2.88 -0.192 0.49165E+04 54 coesite -2.37 -3.24 -0.87 -0.291 0.14908E+04 61 cristobalite -2.55 -3.24 -0.69 -0.231 0.11837E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.44 -1.45 -0.242 0.24827E+04 67 diopside 16.22 14.97 -1.25 -0.125 0.21328E+04 68 hedenbergite 14.24 12.58 -1.66 -0.166 0.28355E+04 75 epidote 24.78 23.74 -1.03 -0.050 0.17655E+04 76 clinozoisite 22.92 19.41 -3.51 -0.159 0.59901E+04 77 epidote-Fe 29.94 28.07 -1.87 -0.097 0.31884E+04 78 fayalite 14.08 10.08 -4.00 -0.571 0.68268E+04 79 ferrosilite 11.19 6.84 -4.35 -0.435 0.74264E+04 83 gibbsite 4.10 1.44 -2.66 -0.379 0.45339E+04 84 glaucophane 23.11 19.99 -3.12 -0.084 0.53263E+04 85 glaucophane-Fe 17.42 12.84 -4.57 -0.124 0.78100E+04 87 greenalite 16.19 13.50 -2.69 -0.225 0.46004E+04 90 hematite 12.60 11.54 -1.06 -0.128 0.18048E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.91 -1.34 -0.134 0.22826E+04 96 julgoldite 70.57 66.58 -3.99 -0.104 0.68212E+04 97 kalsilite 7.62 4.05 -3.57 -0.510 0.60909E+04 98 kaolinite -1.27 -3.60 -2.33 -0.212 0.39743E+04 101 laumontite 2.97 2.32 -0.65 -0.044 0.11151E+04 102 lawsonite 9.68 8.81 -0.87 -0.058 0.14890E+04 103 leucite 4.17 0.81 -3.36 -0.336 0.57320E+04 105 lizardite 23.29 20.65 -2.64 -0.220 0.45070E+04 107 magnetite 20.13 18.20 -1.93 -0.158 0.32964E+04 108 minnesotaite 10.46 7.02 -3.45 -0.203 0.58834E+04 120 muscovite 2.68 0.45 -2.23 -0.131 0.38023E+04 121 paragonite 4.34 2.56 -1.78 -0.105 0.30407E+04 122 nepheline 8.38 6.16 -2.22 -0.317 0.37933E+04 128 periclase-Fe 11.64 6.66 -4.98 -1.244 0.84990E+04 134 phlogopite-Na 29.73 26.80 -2.93 -0.163 0.49978E+04 136 prehnite 19.47 17.97 -1.50 -0.088 0.25534E+04 137 prehnite-Fe 22.59 22.30 -0.29 -0.017 0.49109E+03 138 pumpellyite-Fe 46.47 44.05 -2.43 -0.054 0.41407E+04 139 pumpellyite-Mg 49.19 46.43 -2.77 -0.061 0.47227E+04 145 pyroxmangite 7.42 5.70 -1.72 -0.343 0.29307E+04 146 pyrophyllite -6.10 -10.09 -3.99 -0.249 0.68086E+04 147 quartz -2.98 -3.24 -0.26 -0.087 0.44469E+03 152 rhodonite 7.46 5.70 -1.76 -0.353 0.30099E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.09 -2.50 -0.075 0.42750E+04 171 talc 16.55 14.16 -2.39 -0.141 0.40815E+04 174 tephroite 18.11 14.64 -3.47 -0.496 0.59269E+04 178 tridymite -2.61 -3.24 -0.63 -0.209 0.10720E+04 179 tremolite 48.00 44.10 -3.91 -0.106 0.66718E+04 187 wairakite 4.06 2.32 -1.74 -0.102 0.29660E+04 188 walstromite 11.53 9.16 -2.36 -0.473 0.40352E+04 189 wollastonite 10.48 9.16 -1.32 -0.263 0.22491E+04 190 pseudo-wollastonite 11.02 9.16 -1.86 -0.371 0.31677E+04 191 zoisite 22.96 19.41 -3.55 -0.161 0.60626E+04 192 akaganeite 7.77 5.77 -2.00 -0.432 0.34106E+04 193 beidellite-Ca -1.56 -6.49 -4.93 -0.305 0.84227E+04 197 beidellite-Na -1.26 -5.91 -4.66 -0.285 0.79515E+04 199 chalcedony -2.79 -3.24 -0.45 -0.149 0.76501E+03 201 montmorillonite-Ca -2.21 -5.53 -3.32 -0.205 0.56614E+04 202 montmorillonite-K -2.16 -5.65 -3.48 -0.213 0.59493E+04 203 montmorillonite-Mg -2.40 -6.08 -3.68 -0.228 0.62885E+04 204 montmorillonite-Na -1.96 -4.95 -2.99 -0.183 0.51062E+04 205 nontronite-Ca 3.28 2.16 -1.12 -0.072 0.19051E+04 206 nontronite-H 2.60 0.12 -2.48 -0.166 0.42328E+04 207 nontronite-K 3.40 2.05 -1.36 -0.087 0.23144E+04 208 nontronite-Mg 3.14 1.61 -1.53 -0.099 0.26128E+04 209 nontronite-Na 3.58 2.74 -0.84 -0.054 0.14348E+04 224 tobermorite 9.84 7.09 -2.75 -0.749 0.46894E+04 233 boehmite 4.43 1.44 -2.99 -0.498 0.51011E+04 235 ferrous-oxide 9.82 6.66 -3.16 -0.791 0.54001E+04 240 silica-amorphous -2.08 -3.24 -1.16 -0.388 0.19852E+04 242 an20ab80 2.08 1.50 -0.58 -0.045 0.99141E+03 243 an25ab75 2.71 1.96 -0.75 -0.058 0.12872E+04 244 an30ab70 3.34 2.41 -0.93 -0.072 0.15913E+04 245 tr.625ac.25prg.125 45.31 42.33 -2.98 -0.080 0.50801E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 41.9990000 g New total amount of reactant added: 43.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1498E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 43.9990000 Water: Moles liquid = 0.5521E+02 kg liquid = 0.9946E+00 Moles total = 0.5496E+02 kg total = 0.9901E+00 Activity = 1.0000 Stoichiometric ionic strength = .6863566E-02 Osmotic coef. = 0.9571 True ionic strength = .1246601E-01 Chg. balance for total moles = -.1498E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12810E-09 -9.8925 0.11068E-09 -9.9559 0.86405E+00 -0.0635 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13831E-03 -3.8592 0.11902E-03 -3.9244 0.86052E+00 -0.0652 4 SO4-- 0.25499E-04 -4.5935 0.14873E-04 -4.8276 0.58327E+00 -0.2341 5 HCO3- 0.58770E-05 -5.2308 0.50622E-05 -5.2957 0.86137E+00 -0.0648 6 HS- 0.12101E-06 -6.9172 0.10415E-06 -6.9824 0.86061E+00 -0.0652 7 Al+++ 0.11523E-27 -27.9384 0.34721E-28 -28.4594 0.30131E+00 -0.5210 8 H4SiO4 0.57609E-03 -3.2395 0.57609E-03 -3.2395 0.10000E+01 0.0000 9 Ca++ 0.60037E-07 -7.2216 0.34844E-07 -7.4579 0.58038E+00 -0.2363 10 Mg++ 0.24212E-10 -10.6160 0.14008E-10 -10.8536 0.57858E+00 -0.2376 11 Fe++ 0.98484E-13 -13.0066 0.57023E-13 -13.2440 0.57901E+00 -0.2373 12 K+ 0.97091E-04 -4.0128 0.83646E-04 -4.0776 0.86151E+00 -0.0647 13 Na+ 0.12336E-01 -1.9088 0.10614E-01 -1.9741 0.86042E+00 -0.0653 14 Mn++ 0.19112E-10 -10.7187 0.11072E-10 -10.9558 0.57933E+00 -0.2371 15 HPO4-- 0.24720E-06 -6.6070 0.14420E-06 -6.8410 0.58333E+00 -0.2341 16 HSiO3- 0.59014E-02 -2.2290 0.50783E-02 -2.2943 0.86052E+00 -0.0652 17 Ca(HSiO3)+ 0.46012E-08 -8.3371 0.39646E-08 -8.4018 0.86164E+00 -0.0647 18 Mg(HSiO3)+ 0.23021E-11 -11.6379 0.19836E-11 -11.7025 0.86164E+00 -0.0647 19 NaHSiO3,aq 0.85607E-03 -3.0675 0.85607E-03 -3.0675 0.10000E+01 0.0000 20 AlO+ 0.42465E-15 -15.3720 0.36590E-15 -15.4366 0.86164E+00 -0.0647 22 HAlO2,aq 0.66154E-09 -9.1794 0.66154E-09 -9.1794 0.10000E+01 0.0000 23 AlO2- 0.15528E-04 -4.8089 0.13346E-04 -4.8747 0.85947E+00 -0.0658 24 CH4,aq 0.34858E-13 -13.4577 0.34784E-13 -13.4586 0.99789E+00 -0.0009 29 CO,aq 0.97719E-18 -18.0100 0.97719E-18 -18.0100 0.10000E+01 0.0000 30 CO2,aq 0.11321E-08 -8.9461 0.11297E-08 -8.9470 0.99789E+00 -0.0009 31 CO3-2 0.72607E-05 -5.1390 0.42288E-05 -5.3738 0.58243E+00 -0.2348 32 CaCO3,aq 0.18047E-08 -8.7436 0.18047E-08 -8.7436 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.51582E-11 -11.2875 0.44445E-11 -11.3522 0.86164E+00 -0.0647 34 CaCl+ 0.76694E-11 -11.1152 0.66082E-11 -11.1799 0.86164E+00 -0.0647 35 CaCl2,aq 0.18312E-15 -15.7373 0.18312E-15 -15.7373 0.10000E+01 0.0000 36 CaOH+ 0.25763E-07 -7.5890 0.22199E-07 -7.6537 0.86164E+00 -0.0647 37 CaSO4,aq 0.16147E-09 -9.7919 0.16147E-09 -9.7919 0.10000E+01 0.0000 38 HCl,aq 0.24778E-14 -14.6059 0.24778E-14 -14.6059 0.10000E+01 0.0000 43 FeCl+ 0.12268E-16 -16.9112 0.10570E-16 -16.9759 0.86164E+00 -0.0647 46 FeO,aq 0.18407E-09 -9.7350 0.18407E-09 -9.7350 0.10000E+01 0.0000 47 FeOH+ 0.19823E-10 -10.7028 0.17080E-10 -10.7675 0.86164E+00 -0.0647 48 HFeO2- 0.20787E-07 -7.6822 0.17888E-07 -7.7474 0.86052E+00 -0.0652 49 FeO+ 0.26322E-15 -15.5797 0.22680E-15 -15.6444 0.86164E+00 -0.0647 51 FeO2- 0.42285E-08 -8.3738 0.36387E-08 -8.4390 0.86052E+00 -0.0652 52 HFeO2,aq 0.50403E-10 -10.2975 0.50403E-10 -10.2975 0.10000E+01 0.0000 53 H2,aq 0.33657E-07 -7.4729 0.33586E-07 -7.4738 0.99789E+00 -0.0009 54 KCl,aq 0.17627E-09 -9.7538 0.17627E-09 -9.7538 0.10000E+01 0.0000 55 KHSO4,aq 0.36846E-18 -18.4336 0.36846E-18 -18.4336 0.10000E+01 0.0000 56 KOH,aq 0.32946E-06 -6.4822 0.32946E-06 -6.4822 0.10000E+01 0.0000 57 KSO4- 0.22273E-07 -7.6522 0.19166E-07 -7.7175 0.86052E+00 -0.0652 58 MgCO3,aq 0.18130E-12 -12.7416 0.18130E-12 -12.7416 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21147E-14 -14.6748 0.18221E-14 -14.7394 0.86164E+00 -0.0647 60 MgCl+ 0.27991E-14 -14.5530 0.24118E-14 -14.6177 0.86164E+00 -0.0647 61 MgOH+ 0.57382E-10 -10.2412 0.49442E-10 -10.3059 0.86164E+00 -0.0647 63 MnO,aq 0.95414E-09 -9.0204 0.95414E-09 -9.0204 0.10000E+01 0.0000 64 MnOH+ 0.35757E-09 -9.4466 0.30810E-09 -9.5113 0.86164E+00 -0.0647 65 MnO2-2 0.46248E-11 -11.3349 0.26936E-11 -11.5697 0.58243E+00 -0.2348 66 HMnO2- 0.75064E-10 -10.1246 0.64594E-10 -10.1898 0.86052E+00 -0.0652 69 MnCl+ 0.92564E-14 -14.0336 0.79757E-14 -14.0982 0.86164E+00 -0.0647 70 MnSO4,aq 0.46670E-13 -13.3310 0.46670E-13 -13.3310 0.10000E+01 0.0000 71 NaCl,aq 0.41248E-06 -6.3846 0.41248E-06 -6.3846 0.10000E+01 0.0000 72 NaOH,aq 0.42138E-04 -4.3753 0.42138E-04 -4.3753 0.10000E+01 0.0000 74 OH- 0.63056E-02 -2.2003 0.54195E-02 -2.2660 0.85947E+00 -0.0658 79 HPO3-2 0.26264E-16 -16.5806 0.15297E-16 -16.8154 0.58243E+00 -0.2348 82 H3PO4,aq 0.11372E-16 -16.9441 0.11372E-16 -16.9441 0.10000E+01 0.0000 83 H2PO4- 0.32496E-09 -9.4882 0.27981E-09 -9.5531 0.86107E+00 -0.0650 84 PO4-3 0.36524E-08 -8.4374 0.11378E-08 -8.9439 0.31152E+00 -0.5065 87 H2P2O7-2 0.10521E-19 -19.9779 0.61277E-20 -20.2127 0.58243E+00 -0.2348 88 HP2O7-3 0.37655E-16 -16.4242 0.11353E-16 -16.9449 0.30149E+00 -0.5207 89 P2O7-4 0.20659E-15 -15.6849 0.25304E-16 -16.5968 0.12248E+00 -0.9119 90 H2S,aq 0.34707E-10 -10.4596 0.34634E-10 -10.4605 0.99789E+00 -0.0009 91 S2-2 0.12195E-16 -16.9138 0.71027E-17 -17.1486 0.58243E+00 -0.2348 97 SO3-2 0.11580E-12 -12.9363 0.68108E-13 -13.1668 0.58815E+00 -0.2305 98 HSO3- 0.51266E-15 -15.2902 0.44116E-15 -15.3554 0.86052E+00 -0.0652 99 HSO4- 0.17715E-11 -11.7517 0.15274E-11 -11.8161 0.86220E+00 -0.0644 101 S2O3-2 0.10423E-16 -16.9820 0.60707E-17 -17.2168 0.58243E+00 -0.2348 Charge balance for all species = -.1500E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1280952E-09 -.1317506E-01 -.1326642E+02 0.0000 2 H2O 0.1000000E+01 0.5550787E+02 0.9989927E+06 0.0000 3 Cl- 0.1383069E-03 0.1387195E-03 0.4913115E+01 6.0315 4 SO4-- 0.2549877E-04 0.2551332E-04 0.2448404E+01 15.0842 5 HCO3- 0.5876965E-05 0.1314061E-04 0.8010027E+00 4.6603 6 HS- 0.1210145E-06 0.1289286E-06 0.4259672E-02 2.9736 7 Al+++ 0.1152331E-27 0.1552874E-04 0.4185705E+00 1.4084 8 H4SiO4 0.5760866E-03 0.7333548E-02 0.7041632E+03 -3.2395 9 Ca++ 0.6003679E-07 0.9238005E-07 0.3698712E-02 12.4540 10 Mg++ 0.2421183E-10 0.8408198E-10 0.2042160E-05 9.0582 11 Fe++ 0.9848378E-13 0.2527039E-07 0.1409867E-02 6.6679 12 K+ 0.9709123E-04 0.9744314E-04 0.3806418E+01 5.8784 13 Na+ 0.1233569E-01 0.1323431E-01 0.3039505E+03 7.9818 14 Mn++ 0.1911241E-10 0.1410568E-08 0.7741643E-04 8.9561 15 HPO4-- 0.2471998E-06 0.2511771E-06 0.2408366E-01 13.0708 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7285451E+00 -.1310427E-01 -.7154408E+00 0.0000000E+00 2 H2O 0.5495670E+02 0.5520962E+02 -.2529116E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1244867E-02 0.2537623E-04 0.1219491E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1219362E-02 0.1282359E-06 -.1219491E-02 0.0000000E+00 7 Al+++ 0.1434694E+00 0.1544530E-04 0.1434539E+00 0.0000000E+00 8 H4SiO4 0.4581520E+00 0.7294143E-02 0.4508579E+00 0.0000000E+00 9 Ca++ 0.5061960E-01 0.9188367E-07 0.5061951E-01 0.0000000E+00 10 Mg++ 0.3491984E-01 0.8363019E-10 0.3491984E-01 0.0000000E+00 11 Fe++ 0.3137167E-01 0.2513460E-07 0.3137164E-01 0.0000000E+00 12 K+ 0.9341614E-02 0.9691955E-04 0.9244694E-02 0.0000000E+00 13 Na+ 0.5538954E-01 0.1316320E-01 0.4222633E-01 0.0000000E+00 14 Mn++ 0.7628809E-03 0.1402989E-08 0.7628795E-03 0.0000000E+00 15 HPO4-- 0.2603675E-03 0.2498274E-06 0.2601176E-03 0.0000000E+00 Chg. balance for solid moles: -.9519E-16 Mass of aqueous solution: 0.995621E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 43.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4223E-01 -1.374 11.07 1.044 23.05 4.251 andradite 0.4878E-02 -2.312 2.479 0.394 5.161 0.6440 grossular 0.3417E-03 -3.466 0.1539 -0.813 0.3204 0.4282E-01 apatite-OH 0.8671E-04 -4.062 0.4355E-01 -1.361 0.9068E-01 0.1384E-01 clinochlore 0.6984E-02 -2.156 3.882 0.589 8.082 1.477 daphnite 0.2975E-02 -2.526 2.123 0.327 4.420 0.6433 chlorite-Mn 0.1526E-03 -3.817 0.1082 -0.966 0.2252 0.3447E-01 microcline 0.8571E-02 -2.067 2.386 0.378 4.967 0.9319 stilbite 0.3453E-01 -1.462 24.33 1.386 50.66 11.35 stilpnomelane-Fe 0.1348E-02 -2.870 1.453 0.162 3.025 0.5019 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9345E+00 0.9345E+00 1.0000 -0.029 grossular 0.6546E-01 0.6546E-01 1.0000 -1.184 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6907E+00 0.6907E+00 1.0000 -0.161 daphnite 0.2942E+00 0.2942E+00 1.0000 -0.531 chlorite-Mn 0.1509E-01 0.1509E-01 1.0000 -1.821 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 48.032362 g Volume = 19.888147 cm3 Porosity: -6.9278% V(tot) - V(min): -.12885E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 43.9990000 g log = 1.6434 Original solution: 1000.0103000 g Original solution / Rock added: 22.73 (Water/Rock Ratio), log = 1.3566 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.1000E+01 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1220E-06 1.0073 0.1293E-06 0.1284E-06 CH4,gas 0.5162E-10 1.0129 0.5501E-10 0.5431E-10 H2,gas 0.4377E-04 1.0006 0.4607E-04 0.4604E-04 H2S,gas 0.9641E-09 0.9959 0.1010E-08 0.1014E-08 S2,gas 0.1712E-28 1.0000 0.1801E-28 0.1801E-28 CO,gas 0.1467E-14 1.0000 0.1543E-14 0.1543E-14 SO3,gas 0.6475E-40 1.0000 0.6811E-40 0.6811E-40 SO2,gas 0.1128E-21 1.0000 0.1187E-21 0.1187E-21 HCl,gas 0.4159E-17 1.0000 0.4375E-17 0.4375E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.66728E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.25 -8.89 -2.963 0.15177E+05 -6.888 3 CH4,gas 4.81 -7.45 -12.26 -3.065 0.20933E+05 -10.260 4 H2,gas 8.29 1.95 -6.34 -3.621 0.10820E+05 -4.337 5 H2S,gas -5.94 -16.94 -11.00 -5.498 0.18775E+05 -8.996 6 S2,gas -7.03 -37.78 -30.74 -4.730 0.52495E+05 -28.745 7 CO,gas 3.51 -13.30 -16.81 -5.173 0.28705E+05 -14.812 8 SO3,gas 17.43 -24.74 -42.17 -10.542 0.71999E+05 -40.167 9 SO2,gas 1.14 -22.79 -23.93 -6.380 0.40852E+05 -21.926 10 HCl,gas 5.48 -13.88 -19.36 -9.680 0.33055E+05 -17.359 11 acmite 7.74 7.20 -0.54 -0.056 0.92520E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.97 -4.58 -0.229 0.78260E+04 20 analcite 3.37 2.91 -0.46 -0.051 0.78456E+03 26 annite 20.21 17.57 -2.64 -0.147 0.45033E+04 27 phlogopite 27.15 24.74 -2.40 -0.134 0.41042E+04 29 anorthite 12.80 8.79 -4.01 -0.308 0.68401E+04 35 aragonite 0.99 -2.80 -3.78 -1.261 0.64608E+04 36 brucite 12.58 9.06 -3.52 -0.704 0.60075E+04 37 calcite 0.83 -2.80 -3.63 -1.210 0.61994E+04 38 carnegieite-low 9.06 6.15 -2.91 -0.416 0.49754E+04 39 carnegieite-high 10.13 6.15 -3.98 -0.569 0.68022E+04 40 carpholite-Mg 8.65 5.40 -3.25 -0.217 0.55568E+04 41 carpholite-Fe 6.78 3.01 -3.78 -0.252 0.64496E+04 42 celadonite 5.40 3.39 -2.01 -0.118 0.34381E+04 43 celadonite-Fe 3.94 1.00 -2.94 -0.173 0.50206E+04 44 chrysotile 23.94 20.70 -3.24 -0.270 0.55350E+04 50 chloritoid-Mg 13.26 8.64 -4.63 -0.308 0.78984E+04 51 chloritoid-Fe 9.24 6.25 -2.99 -0.200 0.51114E+04 52 chloritoid-Mn 11.46 8.53 -2.93 -0.195 0.50027E+04 54 coesite -2.37 -3.24 -0.87 -0.290 0.14858E+04 61 cristobalite -2.55 -3.24 -0.69 -0.230 0.11787E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.41 -1.49 -0.248 0.25402E+04 67 diopside 16.22 15.03 -1.18 -0.118 0.20187E+04 68 hedenbergite 14.24 12.64 -1.60 -0.160 0.27346E+04 75 epidote 24.78 23.70 -1.08 -0.052 0.18377E+04 76 clinozoisite 22.92 19.41 -3.51 -0.159 0.59874E+04 77 epidote-Fe 29.94 27.98 -1.95 -0.101 0.33355E+04 78 fayalite 14.08 10.10 -3.98 -0.569 0.68003E+04 79 ferrosilite 11.19 6.86 -4.33 -0.433 0.73949E+04 83 gibbsite 4.10 1.41 -2.69 -0.384 0.45914E+04 84 glaucophane 23.11 20.04 -3.07 -0.083 0.52446E+04 85 glaucophane-Fe 17.42 12.87 -4.55 -0.123 0.77677E+04 87 greenalite 16.19 13.52 -2.67 -0.222 0.45581E+04 90 hematite 12.60 11.39 -1.21 -0.147 0.20696E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.91 -1.34 -0.134 0.22876E+04 96 julgoldite 70.57 66.49 -4.09 -0.106 0.69787E+04 97 kalsilite 7.62 4.05 -3.57 -0.510 0.61008E+04 98 kaolinite -1.27 -3.66 -2.39 -0.217 0.40794E+04 101 laumontite 2.97 2.31 -0.66 -0.044 0.11301E+04 102 lawsonite 9.68 8.79 -0.89 -0.059 0.15140E+04 103 leucite 4.17 0.81 -3.36 -0.336 0.57370E+04 105 lizardite 23.29 20.70 -2.59 -0.216 0.44253E+04 107 magnetite 20.13 18.05 -2.08 -0.170 0.35504E+04 108 minnesotaite 10.46 7.05 -3.42 -0.201 0.58311E+04 120 muscovite 2.68 0.38 -2.29 -0.135 0.39174E+04 121 paragonite 4.34 2.49 -1.85 -0.109 0.31558E+04 122 nepheline 8.38 6.15 -2.23 -0.318 0.38033E+04 128 periclase-Fe 11.64 6.67 -4.97 -1.243 0.84882E+04 134 phlogopite-Na 29.73 26.85 -2.89 -0.160 0.49261E+04 136 prehnite 19.47 18.01 -1.46 -0.086 0.24932E+04 137 prehnite-Fe 22.59 22.29 -0.30 -0.018 0.50575E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40671E+04 139 pumpellyite-Mg 49.19 46.48 -2.72 -0.060 0.46359E+04 145 pyroxmangite 7.42 5.72 -1.70 -0.340 0.29018E+04 146 pyrophyllite -6.10 -10.14 -4.04 -0.253 0.69038E+04 147 quartz -2.98 -3.24 -0.26 -0.086 0.43970E+03 152 rhodonite 7.46 5.72 -1.75 -0.349 0.29810E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.13 -2.47 -0.074 0.42093E+04 171 talc 16.55 14.22 -2.34 -0.137 0.39898E+04 174 tephroite 18.11 14.67 -3.44 -0.491 0.58741E+04 178 tridymite -2.61 -3.24 -0.62 -0.208 0.10670E+04 179 tremolite 48.00 44.28 -3.72 -0.101 0.63520E+04 187 wairakite 4.06 2.31 -1.75 -0.103 0.29809E+04 188 walstromite 11.53 9.21 -2.31 -0.463 0.39501E+04 189 wollastonite 10.48 9.21 -1.27 -0.253 0.21640E+04 190 pseudo-wollastonite 11.02 9.21 -1.81 -0.361 0.30826E+04 191 zoisite 22.96 19.41 -3.55 -0.161 0.60600E+04 192 akaganeite 7.77 5.69 -2.07 -0.449 0.35430E+04 193 beidellite-Ca -1.56 -6.55 -4.99 -0.309 0.85253E+04 197 beidellite-Na -1.26 -5.97 -4.72 -0.289 0.80533E+04 199 chalcedony -2.79 -3.24 -0.45 -0.148 0.76001E+03 201 montmorillonite-Ca -2.21 -5.56 -3.35 -0.207 0.57165E+04 202 montmorillonite-K -2.16 -5.68 -3.52 -0.215 0.60035E+04 203 montmorillonite-Mg -2.40 -6.12 -3.72 -0.230 0.63528E+04 204 montmorillonite-Na -1.96 -4.98 -3.02 -0.185 0.51604E+04 205 nontronite-Ca 3.28 2.02 -1.26 -0.082 0.21573E+04 206 nontronite-H 2.60 -0.04 -2.63 -0.177 0.44983E+04 207 nontronite-K 3.40 1.90 -1.50 -0.096 0.25658E+04 208 nontronite-Mg 3.14 1.46 -1.68 -0.109 0.28743E+04 209 nontronite-Na 3.58 2.60 -0.99 -0.063 0.16862E+04 224 tobermorite 9.84 7.13 -2.70 -0.738 0.46176E+04 233 boehmite 4.43 1.41 -3.02 -0.504 0.51587E+04 235 ferrous-oxide 9.82 6.67 -3.16 -0.789 0.53893E+04 240 silica-amorphous -2.08 -3.24 -1.16 -0.387 0.19802E+04 242 an20ab80 2.08 1.50 -0.58 -0.045 0.99641E+03 243 an25ab75 2.71 1.95 -0.76 -0.058 0.12934E+04 244 an30ab70 3.34 2.41 -0.94 -0.072 0.15988E+04 245 tr.625ac.25prg.125 45.31 42.50 -2.81 -0.076 0.47971E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 43.9990000 g New total amount of reactant added: 45.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1497E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 45.9990000 Water: Moles liquid = 0.5520E+02 kg liquid = 0.9944E+00 Moles total = 0.5493E+02 kg total = 0.9896E+00 Activity = 1.0000 Stoichiometric ionic strength = .7073319E-02 Osmotic coef. = 0.9567 True ionic strength = .1283768E-01 Chg. balance for total moles = -.1497E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12515E-09 -9.9026 0.10796E-09 -9.9667 0.86269E+00 -0.0641 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13833E-03 -3.8591 0.11883E-03 -3.9251 0.85907E+00 -0.0660 4 SO4-- 0.25148E-04 -4.5995 0.14572E-04 -4.8365 0.57946E+00 -0.2370 5 HCO3- 0.57817E-05 -5.2379 0.49719E-05 -5.3035 0.85994E+00 -0.0655 6 HS- 0.47725E-06 -6.3213 0.41003E-06 -6.3872 0.85916E+00 -0.0659 7 Al+++ 0.10077E-27 -27.9967 0.29911E-28 -28.5242 0.29684E+00 -0.5275 8 H4SiO4 0.58030E-03 -3.2363 0.58030E-03 -3.2363 0.10000E+01 0.0000 9 Ca++ 0.63429E-07 -7.1977 0.36568E-07 -7.4369 0.57652E+00 -0.2392 10 Mg++ 0.23915E-10 -10.6213 0.13743E-10 -10.8619 0.57469E+00 -0.2406 11 Fe++ 0.95562E-13 -13.0197 0.54960E-13 -13.2600 0.57512E+00 -0.2402 12 K+ 0.99993E-04 -4.0000 0.86003E-04 -4.0655 0.86009E+00 -0.0655 13 Na+ 0.12705E-01 -1.8960 0.10913E-01 -1.9621 0.85897E+00 -0.0660 14 Mn++ 0.18877E-10 -10.7241 0.10863E-10 -10.9641 0.57545E+00 -0.2400 15 HPO4-- 0.22210E-06 -6.6535 0.12871E-06 -6.8904 0.57952E+00 -0.2369 16 HSiO3- 0.61045E-02 -2.2144 0.52442E-02 -2.2803 0.85907E+00 -0.0660 17 Ca(HSiO3)+ 0.49949E-08 -8.3015 0.42967E-08 -8.3669 0.86022E+00 -0.0654 18 Mg(HSiO3)+ 0.23362E-11 -11.6315 0.20097E-11 -11.6969 0.86022E+00 -0.0654 19 NaHSiO3,aq 0.90895E-03 -3.0415 0.90895E-03 -3.0415 0.10000E+01 0.0000 20 AlO+ 0.38511E-15 -15.4144 0.33128E-15 -15.4798 0.86022E+00 -0.0654 22 HAlO2,aq 0.61403E-09 -9.2118 0.61403E-09 -9.2118 0.10000E+01 0.0000 23 AlO2- 0.14801E-04 -4.8297 0.12699E-04 -4.8962 0.85800E+00 -0.0665 24 CH4,aq 0.13757E-12 -12.8615 0.13728E-12 -12.8624 0.99783E+00 -0.0009 29 CO,aq 0.13337E-17 -17.8749 0.13337E-17 -17.8749 0.10000E+01 0.0000 30 CO2,aq 0.10846E-08 -8.9647 0.10823E-08 -8.9657 0.99783E+00 -0.0009 31 CO3-2 0.73590E-05 -5.1332 0.42579E-05 -5.3708 0.57861E+00 -0.2376 32 CaCO3,aq 0.19070E-08 -8.7196 0.19070E-08 -8.7196 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53256E-11 -11.2736 0.45812E-11 -11.3390 0.86022E+00 -0.0654 34 CaCl+ 0.80498E-11 -11.0942 0.69246E-11 -11.1596 0.86022E+00 -0.0654 35 CaCl2,aq 0.19160E-15 -15.7176 0.19160E-15 -15.7176 0.10000E+01 0.0000 36 CaOH+ 0.27764E-07 -7.5565 0.23883E-07 -7.6219 0.86022E+00 -0.0654 37 CaSO4,aq 0.16603E-09 -9.7798 0.16603E-09 -9.7798 0.10000E+01 0.0000 38 HCl,aq 0.24132E-14 -14.6174 0.24132E-14 -14.6174 0.10000E+01 0.0000 43 FeCl+ 0.11825E-16 -16.9272 0.10172E-16 -16.9926 0.86022E+00 -0.0654 46 FeO,aq 0.18646E-09 -9.7294 0.18646E-09 -9.7294 0.10000E+01 0.0000 47 FeOH+ 0.19619E-10 -10.7073 0.16877E-10 -10.7727 0.86022E+00 -0.0654 48 HFeO2- 0.21623E-07 -7.6651 0.18576E-07 -7.7310 0.85907E+00 -0.0660 49 FeO+ 0.21826E-15 -15.6610 0.18775E-15 -15.7264 0.86022E+00 -0.0654 51 FeO2- 0.36852E-08 -8.4335 0.31658E-08 -8.4995 0.85907E+00 -0.0660 52 HFeO2,aq 0.42776E-10 -10.3688 0.42776E-10 -10.3688 0.10000E+01 0.0000 53 H2,aq 0.47953E-07 -7.3192 0.47848E-07 -7.3201 0.99783E+00 -0.0009 54 KCl,aq 0.18096E-09 -9.7424 0.18096E-09 -9.7424 0.10000E+01 0.0000 55 KHSO4,aq 0.36208E-18 -18.4412 0.36208E-18 -18.4412 0.10000E+01 0.0000 56 KOH,aq 0.34727E-06 -6.4593 0.34727E-06 -6.4593 0.10000E+01 0.0000 57 KSO4- 0.22476E-07 -7.6483 0.19308E-07 -7.7143 0.85907E+00 -0.0660 58 MgCO3,aq 0.17909E-12 -12.7469 0.17909E-12 -12.7469 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20410E-14 -14.6902 0.17557E-14 -14.7555 0.86022E+00 -0.0654 60 MgCl+ 0.27465E-14 -14.5612 0.23626E-14 -14.6266 0.86022E+00 -0.0654 61 MgOH+ 0.57809E-10 -10.2380 0.49728E-10 -10.3034 0.86022E+00 -0.0654 63 MnO,aq 0.98381E-09 -9.0071 0.98381E-09 -9.0071 0.10000E+01 0.0000 64 MnOH+ 0.36023E-09 -9.4434 0.30988E-09 -9.5088 0.86022E+00 -0.0654 65 MnO2-2 0.50449E-11 -11.2972 0.29190E-11 -11.5348 0.57861E+00 -0.2376 66 HMnO2- 0.79480E-10 -10.0997 0.68279E-10 -10.1657 0.85907E+00 -0.0660 69 MnCl+ 0.90823E-14 -14.0418 0.78128E-14 -14.1072 0.86022E+00 -0.0654 70 MnSO4,aq 0.44862E-13 -13.3481 0.44862E-13 -13.3481 0.10000E+01 0.0000 71 NaCl,aq 0.42345E-06 -6.3732 0.42345E-06 -6.3732 0.10000E+01 0.0000 72 NaOH,aq 0.44416E-04 -4.3525 0.44416E-04 -4.3525 0.10000E+01 0.0000 74 OH- 0.64755E-02 -2.1887 0.55559E-02 -2.2552 0.85800E+00 -0.0665 79 HPO3-2 0.33618E-16 -16.4734 0.19452E-16 -16.7110 0.57861E+00 -0.2376 82 H3PO4,aq 0.96584E-17 -17.0151 0.96584E-17 -17.0151 0.10000E+01 0.0000 83 H2PO4- 0.28340E-09 -9.5476 0.24362E-09 -9.6133 0.85964E+00 -0.0657 84 PO4-3 0.33897E-08 -8.4698 0.10411E-08 -8.9825 0.30714E+00 -0.5127 88 HP2O7-3 0.29703E-16 -16.5272 0.88224E-17 -17.0544 0.29702E+00 -0.5272 89 P2O7-4 0.16895E-15 -15.7723 0.20159E-16 -16.6955 0.11932E+00 -0.9233 90 H2S,aq 0.13330E-09 -9.8752 0.13301E-09 -9.8761 0.99783E+00 -0.0009 91 S2-2 0.13356E-15 -15.8743 0.77280E-16 -16.1119 0.57861E+00 -0.2376 97 SO3-2 0.16268E-12 -12.7887 0.95072E-13 -13.0219 0.58443E+00 -0.2333 98 HSO3- 0.69922E-15 -15.1554 0.60068E-15 -15.2214 0.85907E+00 -0.0660 99 HSO4- 0.16959E-11 -11.7706 0.14598E-11 -11.8357 0.86079E+00 -0.0651 101 S2O3-2 0.39480E-16 -16.4036 0.22843E-16 -16.6412 0.57861E+00 -0.2376 Charge balance for all species = -.1491E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1251472E-09 -.1360038E-01 -.1369423E+02 0.0000 2 H2O 0.1000000E+01 0.5550779E+02 0.9989584E+06 0.0000 3 Cl- 0.1383281E-03 0.1387517E-03 0.4914094E+01 6.0417 4 SO4-- 0.2514818E-04 0.2515930E-04 0.2414351E+01 15.0970 5 HCO3- 0.5781671E-05 0.1314366E-04 0.8011622E+00 4.6632 6 HS- 0.4772466E-06 0.4889022E-06 0.1615230E-01 3.5795 7 Al+++ 0.1007658E-27 0.1480174E-04 0.3989614E+00 1.3760 8 H4SiO4 0.5803013E-03 0.7593752E-02 0.7291239E+03 -3.2363 9 Ca++ 0.6342926E-07 0.9827485E-07 0.3934598E-02 12.4966 10 Mg++ 0.2391456E-10 0.8424323E-10 0.2046010E-05 9.0715 11 Fe++ 0.9556212E-13 0.2555759E-07 0.1425843E-02 6.6735 12 K+ 0.9999259E-04 0.1003625E-03 0.3920329E+01 5.9012 13 Na+ 0.1270472E-01 0.1365852E-01 0.3136828E+03 8.0047 14 Mn++ 0.1887715E-10 0.1447499E-08 0.7944069E-04 8.9694 15 HPO4-- 0.2220951E-06 0.2257682E-06 0.2164667E-01 13.0431 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7616621E+00 -.1352416E-01 -.7481379E+00 0.0000000E+00 2 H2O 0.5493163E+02 0.5519672E+02 -.2650887E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1300294E-02 0.2501831E-04 0.1275275E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1274789E-02 0.4861624E-06 -.1275275E-02 0.0000000E+00 7 Al+++ 0.1499909E+00 0.1471879E-04 0.1499761E+00 0.0000000E+00 8 H4SiO4 0.4789776E+00 0.7551196E-02 0.4714264E+00 0.0000000E+00 9 Ca++ 0.5291988E-01 0.9772412E-07 0.5291979E-01 0.0000000E+00 10 Mg++ 0.3650714E-01 0.8377114E-10 0.3650714E-01 0.0000000E+00 11 Fe++ 0.3279768E-01 0.2541436E-07 0.3279766E-01 0.0000000E+00 12 K+ 0.9766242E-02 0.9980009E-04 0.9666442E-02 0.0000000E+00 13 Na+ 0.5790002E-01 0.1358197E-01 0.4431805E-01 0.0000000E+00 14 Mn++ 0.7975581E-03 0.1439387E-08 0.7975566E-03 0.0000000E+00 15 HPO4-- 0.2722026E-03 0.2245030E-06 0.2719781E-03 0.0000000E+00 Chg. balance for solid moles: -.1405E-15 Mass of aqueous solution: 0.995422E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 45.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4432E-01 -1.353 11.62 1.065 23.14 4.461 andradite 0.5101E-02 -2.292 2.592 0.414 5.162 0.6735 grossular 0.3908E-03 -3.408 0.1760 -0.754 0.3506 0.4898E-01 apatite-OH 0.9066E-04 -4.043 0.4554E-01 -1.342 0.9069E-01 0.1447E-01 clinochlore 0.7301E-02 -2.137 4.058 0.608 8.082 1.544 daphnite 0.3056E-02 -2.515 2.180 0.339 4.342 0.6607 chlorite-Mn 0.1595E-03 -3.797 0.1131 -0.947 0.2252 0.3604E-01 microcline 0.8935E-02 -2.049 2.487 0.396 4.953 0.9715 stilbite 0.3599E-01 -1.444 25.36 1.404 50.51 11.83 stilpnomelane-Fe 0.1463E-02 -2.835 1.577 0.198 3.141 0.5449 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9288E+00 0.9288E+00 1.0000 -0.032 grossular 0.7116E-01 0.7116E-01 1.0000 -1.148 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6943E+00 0.6943E+00 1.0000 -0.158 daphnite 0.2906E+00 0.2906E+00 1.0000 -0.537 chlorite-Mn 0.1517E-01 0.1517E-01 1.0000 -1.819 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 50.214478 g Volume = 20.784734 cm3 Porosity: -7.1400% V(tot) - V(min): -.13851E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 45.9990000 g log = 1.6627 Original solution: 1000.0103000 g Original solution / Rock added: 21.74 (Water/Rock Ratio), log = 1.3373 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1169E-06 1.0073 0.1239E-06 0.1230E-06 CH4,gas 0.2037E-09 1.0129 0.2171E-09 0.2143E-09 H2,gas 0.6235E-04 1.0006 0.6563E-04 0.6559E-04 H2S,gas 0.3703E-08 0.9959 0.3879E-08 0.3895E-08 S2,gas 0.1244E-27 1.0000 0.1309E-27 0.1309E-27 CO,gas 0.2002E-14 1.0000 0.2106E-14 0.2106E-14 SO3,gas 0.6036E-40 1.0000 0.6350E-40 0.6350E-40 SO2,gas 0.1499E-21 1.0000 0.1577E-21 0.1577E-21 HCl,gas 0.4050E-17 1.0000 0.4261E-17 0.4261E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.48529E-10 47 daphnite 29.09 29.09 0.00 0.000 0.54595E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.27 -8.91 -2.969 0.15208E+05 -6.907 3 CH4,gas 4.81 -6.85 -11.66 -2.916 0.19915E+05 -9.663 4 H2,gas 8.29 2.10 -6.18 -3.533 0.10557E+05 -4.183 5 H2S,gas -5.94 -16.35 -10.41 -5.206 0.17777E+05 -8.411 6 S2,gas -7.03 -36.92 -29.88 -4.597 0.51025E+05 -27.883 7 CO,gas 3.51 -13.17 -16.68 -5.131 0.28475E+05 -14.677 8 SO3,gas 17.43 -24.77 -42.20 -10.549 0.72051E+05 -40.197 9 SO2,gas 1.14 -22.67 -23.80 -6.347 0.40642E+05 -21.802 10 HCl,gas 5.48 -13.89 -19.37 -9.685 0.33075E+05 -17.370 11 acmite 7.74 7.15 -0.58 -0.061 0.99702E+03 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.95 -4.60 -0.230 0.78522E+04 20 analcite 3.37 2.91 -0.46 -0.051 0.78997E+03 26 annite 20.21 17.59 -2.62 -0.146 0.44747E+04 27 phlogopite 27.15 24.78 -2.36 -0.131 0.40360E+04 29 anorthite 12.80 8.78 -4.02 -0.309 0.68671E+04 35 aragonite 0.99 -2.77 -3.76 -1.253 0.64199E+04 36 brucite 12.58 9.07 -3.51 -0.701 0.59848E+04 37 calcite 0.83 -2.77 -3.61 -1.202 0.61585E+04 38 carnegieite-low 9.06 6.14 -2.92 -0.417 0.49862E+04 39 carnegieite-high 10.13 6.14 -3.99 -0.570 0.68131E+04 40 carpholite-Mg 8.65 5.35 -3.30 -0.220 0.56338E+04 41 carpholite-Fe 6.78 2.95 -3.83 -0.255 0.65397E+04 42 celadonite 5.40 3.40 -2.00 -0.117 0.34100E+04 43 celadonite-Fe 3.94 1.01 -2.93 -0.172 0.50056E+04 44 chrysotile 23.94 20.74 -3.20 -0.266 0.54561E+04 50 chloritoid-Mg 13.26 8.59 -4.67 -0.312 0.79808E+04 51 chloritoid-Fe 9.24 6.19 -3.05 -0.203 0.52069E+04 52 chloritoid-Mn 11.46 8.49 -2.98 -0.199 0.50851E+04 54 coesite -2.37 -3.24 -0.87 -0.289 0.14804E+04 61 cristobalite -2.55 -3.24 -0.69 -0.229 0.11733E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.38 -1.52 -0.253 0.25955E+04 67 diopside 16.22 15.10 -1.12 -0.112 0.19125E+04 68 hedenbergite 14.24 12.70 -1.55 -0.155 0.26416E+04 75 epidote 24.78 23.66 -1.12 -0.054 0.19083E+04 76 clinozoisite 22.92 19.41 -3.51 -0.160 0.59916E+04 77 epidote-Fe 29.94 27.90 -2.03 -0.106 0.34725E+04 78 fayalite 14.08 10.11 -3.97 -0.567 0.67758E+04 79 ferrosilite 11.19 6.87 -4.31 -0.431 0.73650E+04 83 gibbsite 4.10 1.38 -2.72 -0.389 0.46467E+04 84 glaucophane 23.11 20.09 -3.03 -0.082 0.51656E+04 85 glaucophane-Fe 17.42 12.89 -4.53 -0.122 0.77282E+04 87 greenalite 16.19 13.55 -2.65 -0.221 0.45187E+04 90 hematite 12.60 11.24 -1.35 -0.164 0.23130E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.91 -1.34 -0.134 0.22930E+04 96 julgoldite 70.57 66.40 -4.17 -0.108 0.71231E+04 97 kalsilite 7.62 4.04 -3.58 -0.511 0.61117E+04 98 kaolinite -1.27 -3.72 -2.45 -0.223 0.41791E+04 101 laumontite 2.97 2.30 -0.67 -0.045 0.11463E+04 102 lawsonite 9.68 8.78 -0.90 -0.060 0.15410E+04 103 leucite 4.17 0.80 -3.36 -0.336 0.57424E+04 105 lizardite 23.29 20.74 -2.55 -0.212 0.43463E+04 107 magnetite 20.13 17.92 -2.22 -0.181 0.37842E+04 108 minnesotaite 10.46 7.08 -3.39 -0.199 0.57809E+04 120 muscovite 2.68 0.32 -2.36 -0.139 0.40279E+04 121 paragonite 4.34 2.42 -1.91 -0.113 0.32663E+04 122 nepheline 8.38 6.14 -2.23 -0.319 0.38141E+04 128 periclase-Fe 11.64 6.67 -4.97 -1.241 0.84787E+04 134 phlogopite-Na 29.73 26.89 -2.85 -0.158 0.48579E+04 136 prehnite 19.47 18.04 -1.43 -0.084 0.24421E+04 137 prehnite-Fe 22.59 22.28 -0.31 -0.018 0.52110E+03 138 pumpellyite-Fe 46.47 44.12 -2.35 -0.052 0.40107E+04 139 pumpellyite-Mg 49.19 46.52 -2.67 -0.059 0.45663E+04 144 pyrrhotiteFe0.875 -6.00 -10.78 -4.77 -1.756 0.81523E+04 145 pyroxmangite 7.42 5.73 -1.68 -0.337 0.28736E+04 146 pyrophyllite -6.10 -10.19 -4.10 -0.256 0.69927E+04 147 quartz -2.98 -3.24 -0.25 -0.085 0.43429E+03 152 rhodonite 7.46 5.73 -1.73 -0.346 0.29529E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.17 -2.43 -0.072 0.41435E+04 171 talc 16.55 14.27 -2.28 -0.134 0.39001E+04 174 tephroite 18.11 14.70 -3.41 -0.487 0.58233E+04 178 tridymite -2.61 -3.24 -0.62 -0.207 0.10616E+04 179 tremolite 48.00 44.46 -3.54 -0.096 0.60498E+04 187 wairakite 4.06 2.30 -1.76 -0.103 0.29971E+04 188 walstromite 11.53 9.26 -2.27 -0.454 0.38720E+04 189 wollastonite 10.48 9.26 -1.22 -0.244 0.20859E+04 190 pseudo-wollastonite 11.02 9.26 -1.76 -0.352 0.30045E+04 191 zoisite 22.96 19.41 -3.55 -0.161 0.60642E+04 192 akaganeite 7.77 5.62 -2.15 -0.464 0.36646E+04 197 beidellite-Na -1.26 -6.03 -4.77 -0.292 0.81493E+04 199 chalcedony -2.79 -3.24 -0.44 -0.147 0.75461E+03 201 montmorillonite-Ca -2.21 -5.59 -3.38 -0.209 0.57676E+04 202 montmorillonite-K -2.16 -5.71 -3.55 -0.217 0.60538E+04 203 montmorillonite-Mg -2.40 -6.16 -3.76 -0.232 0.64123E+04 204 montmorillonite-Na -1.96 -5.01 -3.05 -0.187 0.52107E+04 205 nontronite-Ca 3.28 1.88 -1.40 -0.091 0.23871E+04 206 nontronite-H 2.60 -0.18 -2.78 -0.186 0.47400E+04 207 nontronite-K 3.40 1.77 -1.64 -0.105 0.27946E+04 208 nontronite-Mg 3.14 1.32 -1.82 -0.118 0.31123E+04 209 nontronite-Na 3.58 2.46 -1.12 -0.072 0.19151E+04 224 tobermorite 9.84 7.17 -2.67 -0.727 0.45516E+04 233 boehmite 4.43 1.38 -3.05 -0.509 0.52139E+04 235 ferrous-oxide 9.82 6.67 -3.15 -0.788 0.53798E+04 240 silica-amorphous -2.08 -3.24 -1.16 -0.386 0.19748E+04 242 an20ab80 2.08 1.49 -0.59 -0.045 0.10018E+04 243 an25ab75 2.71 1.95 -0.76 -0.059 0.13002E+04 244 an30ab70 3.34 2.40 -0.94 -0.072 0.16069E+04 245 tr.625ac.25prg.125 45.31 42.65 -2.65 -0.071 0.45315E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 45.9990000 g New total amount of reactant added: 47.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1497E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 47.9990000 Water: Moles liquid = 0.5518E+02 kg liquid = 0.9942E+00 Moles total = 0.5491E+02 kg total = 0.9892E+00 Activity = 1.0000 Stoichiometric ionic strength = .7269664E-02 Osmotic coef. = 0.9566 True ionic strength = .1318503E-01 Chg. balance for total moles = -.1497E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12259E-09 -9.9115 0.10560E-09 -9.9763 0.86144E+00 -0.0648 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13835E-03 -3.8590 0.11867E-03 -3.9257 0.85775E+00 -0.0666 4 SO4-- 0.24047E-04 -4.6189 0.13851E-04 -4.8585 0.57599E+00 -0.2396 5 HCO3- 0.56969E-05 -5.2444 0.48916E-05 -5.3106 0.85864E+00 -0.0662 6 HS- 0.15849E-05 -5.8000 0.13596E-05 -5.8666 0.85784E+00 -0.0666 7 Al+++ 0.89072E-28 -28.0503 0.26079E-28 -28.5837 0.29279E+00 -0.5334 8 H4SiO4 0.58485E-03 -3.2330 0.58485E-03 -3.2330 0.10000E+01 0.0000 9 Ca++ 0.66609E-07 -7.1765 0.38167E-07 -7.4183 0.57300E+00 -0.2418 10 Mg++ 0.23694E-10 -10.6254 0.13533E-10 -10.8686 0.57114E+00 -0.2433 11 Fe++ 0.93025E-13 -13.0314 0.53171E-13 -13.2743 0.57158E+00 -0.2429 12 K+ 0.10271E-03 -3.9884 0.88206E-04 -4.0545 0.85879E+00 -0.0661 13 Na+ 0.13050E-01 -1.8844 0.11193E-01 -1.9511 0.85765E+00 -0.0667 14 Mn++ 0.18703E-10 -10.7281 0.10696E-10 -10.9708 0.57191E+00 -0.2427 15 HPO4-- 0.20202E-06 -6.6946 0.11637E-06 -6.9342 0.57605E+00 -0.2395 16 HSiO3- 0.62995E-02 -2.2007 0.54034E-02 -2.2673 0.85775E+00 -0.0666 17 Ca(HSiO3)+ 0.53796E-08 -8.2693 0.46206E-08 -8.3353 0.85892E+00 -0.0660 18 Mg(HSiO3)+ 0.23738E-11 -11.6246 0.20389E-11 -11.6906 0.85892E+00 -0.0660 19 NaHSiO3,aq 0.96054E-03 -3.0175 0.96054E-03 -3.0175 0.10000E+01 0.0000 20 AlO+ 0.35148E-15 -15.4541 0.30189E-15 -15.5202 0.85892E+00 -0.0660 22 HAlO2,aq 0.57206E-09 -9.2426 0.57206E-09 -9.2426 0.10000E+01 0.0000 23 AlO2- 0.14120E-04 -4.8502 0.12096E-04 -4.9174 0.85665E+00 -0.0672 24 CH4,aq 0.47223E-12 -12.3259 0.47117E-12 -12.3268 0.99777E+00 -0.0010 29 CO,aq 0.17638E-17 -17.7535 0.17638E-17 -17.7535 0.10000E+01 0.0000 30 CO2,aq 0.10438E-08 -8.9814 0.10415E-08 -8.9823 0.99777E+00 -0.0010 31 CO3-2 0.74467E-05 -5.1280 0.42827E-05 -5.3683 0.57512E+00 -0.2402 32 CaCO3,aq 0.20020E-08 -8.6985 0.20020E-08 -8.6985 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.54769E-11 -11.2615 0.47042E-11 -11.3275 0.85892E+00 -0.0660 34 CaCl+ 0.84028E-11 -11.0756 0.72173E-11 -11.1416 0.85892E+00 -0.0660 35 CaCl2,aq 0.19942E-15 -15.7002 0.19942E-15 -15.7002 0.10000E+01 0.0000 36 CaOH+ 0.29670E-07 -7.5277 0.25484E-07 -7.5937 0.85892E+00 -0.0660 37 CaSO4,aq 0.16471E-09 -9.7833 0.16471E-09 -9.7833 0.10000E+01 0.0000 38 HCl,aq 0.23572E-14 -14.6276 0.23572E-14 -14.6276 0.10000E+01 0.0000 43 FeCl+ 0.11442E-16 -16.9415 0.98275E-17 -17.0076 0.85892E+00 -0.0660 46 FeO,aq 0.18854E-09 -9.7246 0.18854E-09 -9.7246 0.10000E+01 0.0000 47 FeOH+ 0.19434E-10 -10.7114 0.16692E-10 -10.7775 0.85892E+00 -0.0660 48 HFeO2- 0.22388E-07 -7.6500 0.19203E-07 -7.7166 0.85775E+00 -0.0666 49 FeO+ 0.18443E-15 -15.7342 0.15841E-15 -15.8002 0.85892E+00 -0.0660 51 FeO2- 0.32547E-08 -8.4875 0.27917E-08 -8.5541 0.85775E+00 -0.0666 52 HFeO2,aq 0.36896E-10 -10.4330 0.36896E-10 -10.4330 0.10000E+01 0.0000 53 H2,aq 0.65902E-07 -7.1811 0.65755E-07 -7.1821 0.99777E+00 -0.0010 54 KCl,aq 0.18534E-09 -9.7320 0.18534E-09 -9.7320 0.10000E+01 0.0000 55 KHSO4,aq 0.34524E-18 -18.4619 0.34524E-18 -18.4619 0.10000E+01 0.0000 56 KOH,aq 0.36413E-06 -6.4387 0.36413E-06 -6.4387 0.10000E+01 0.0000 57 KSO4- 0.21944E-07 -7.6587 0.18822E-07 -7.7253 0.85775E+00 -0.0666 58 MgCO3,aq 0.17737E-12 -12.7511 0.17737E-12 -12.7511 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19802E-14 -14.7033 0.17008E-14 -14.7693 0.85892E+00 -0.0660 60 MgCl+ 0.27047E-14 -14.5679 0.23231E-14 -14.6339 0.85892E+00 -0.0660 61 MgOH+ 0.58282E-10 -10.2345 0.50059E-10 -10.3005 0.85892E+00 -0.0660 63 MnO,aq 0.10125E-08 -8.9946 0.10125E-08 -8.9946 0.10000E+01 0.0000 64 MnOH+ 0.36318E-09 -9.4399 0.31194E-09 -9.5059 0.85892E+00 -0.0660 65 MnO2-2 0.54594E-11 -11.2629 0.31398E-11 -11.5031 0.57512E+00 -0.2402 66 HMnO2- 0.83753E-10 -10.0770 0.71839E-10 -10.1436 0.85775E+00 -0.0666 69 MnCl+ 0.89441E-14 -14.0485 0.76823E-14 -14.1145 0.85892E+00 -0.0660 70 MnSO4,aq 0.41986E-13 -13.3769 0.41986E-13 -13.3769 0.10000E+01 0.0000 71 NaCl,aq 0.43370E-06 -6.3628 0.43370E-06 -6.3628 0.10000E+01 0.0000 72 NaOH,aq 0.46571E-04 -4.3319 0.46571E-04 -4.3319 0.10000E+01 0.0000 74 OH- 0.66306E-02 -2.1784 0.56801E-02 -2.2456 0.85665E+00 -0.0672 79 HPO3-2 0.42025E-16 -16.3765 0.24169E-16 -16.6167 0.57512E+00 -0.2402 82 H3PO4,aq 0.83550E-17 -17.0781 0.83550E-17 -17.0781 0.10000E+01 0.0000 83 H2PO4- 0.25102E-09 -9.6003 0.21545E-09 -9.6666 0.85832E+00 -0.0663 84 PO4-3 0.31741E-08 -8.4984 0.96235E-09 -9.0167 0.30318E+00 -0.5183 88 HP2O7-3 0.24079E-16 -16.6184 0.70544E-17 -17.1515 0.29297E+00 -0.5332 89 P2O7-4 0.14146E-15 -15.8494 0.16480E-16 -16.7831 0.11650E+00 -0.9337 90 H2S,aq 0.43236E-09 -9.3642 0.43139E-09 -9.3651 0.99777E+00 -0.0010 91 S2-2 0.10751E-14 -14.9686 0.61829E-15 -15.2088 0.57512E+00 -0.2402 97 SO3-2 0.21372E-12 -12.6701 0.12418E-12 -12.9059 0.58103E+00 -0.2358 98 HSO3- 0.89472E-15 -15.0483 0.76745E-15 -15.1150 0.85775E+00 -0.0666 99 HSO4- 0.15790E-11 -11.8016 0.13572E-11 -11.8674 0.85950E+00 -0.0658 101 S2O3-2 0.12244E-15 -15.9121 0.70420E-16 -16.1523 0.57512E+00 -0.2402 Charge balance for all species = -.1475E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1225901E-09 -.1400159E-01 -.1409777E+02 0.0000 2 H2O 0.1000000E+01 0.5550770E+02 0.9989255E+06 0.0000 3 Cl- 0.1383498E-03 0.1387837E-03 0.4915072E+01 6.0507 4 SO4-- 0.2404664E-04 0.2405269E-04 0.2308085E+01 15.0941 5 HCO3- 0.5696914E-05 0.1314669E-04 0.8013218E+00 4.6658 6 HS- 0.1584926E-05 0.1601423E-05 0.5290599E-01 4.1097 7 Al+++ 0.8907173E-28 0.1412020E-04 0.3805795E+00 1.3453 8 H4SiO4 0.5848479E-03 0.7844879E-02 0.7532127E+03 -3.2330 9 Ca++ 0.6660901E-07 0.1038395E-06 0.4157259E-02 12.5343 10 Mg++ 0.2369412E-10 0.8453167E-10 0.2052951E-05 9.0840 11 Fe++ 0.9302451E-13 0.2588742E-07 0.1444199E-02 6.6783 12 K+ 0.1027101E-03 0.1030963E-03 0.4026990E+01 5.9218 13 Na+ 0.1305037E-01 0.1405791E-01 0.3228453E+03 8.0253 14 Mn++ 0.1870259E-10 0.1483634E-08 0.8142129E-04 8.9819 15 HPO4-- 0.2020155E-06 0.2054406E-06 0.1969704E-01 13.0185 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7947791E+00 -.1391991E-01 -.7808592E+00 0.0000000E+00 2 H2O 0.5490656E+02 0.5518392E+02 -.2773531E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1355720E-02 0.2391239E-04 0.1331808E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1330216E-02 0.1592081E-05 -.1331808E-02 0.0000000E+00 7 Al+++ 0.1565123E+00 0.1403784E-04 0.1564983E+00 0.0000000E+00 8 H4SiO4 0.4998032E+00 0.7799119E-02 0.4920040E+00 0.0000000E+00 9 Ca++ 0.5522017E-01 0.1032338E-06 0.5522007E-01 0.0000000E+00 10 Mg++ 0.3809444E-01 0.8403860E-10 0.3809444E-01 0.0000000E+00 11 Fe++ 0.3422370E-01 0.2573641E-07 0.3422367E-01 0.0000000E+00 12 K+ 0.1019087E-01 0.1024949E-03 0.1008838E-01 0.0000000E+00 13 Na+ 0.6041051E-01 0.1397591E-01 0.4643460E-01 0.0000000E+00 14 Mn++ 0.8322353E-03 0.1474980E-08 0.8322338E-03 0.0000000E+00 15 HPO4-- 0.2840378E-03 0.2042423E-06 0.2838335E-03 0.0000000E+00 Chg. balance for solid moles: -.1596E-15 Mass of aqueous solution: 0.995224E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 47.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4643E-01 -1.333 12.18 1.086 23.24 4.674 andradite 0.5327E-02 -2.273 2.707 0.433 5.167 0.7033 grossular 0.4408E-03 -3.356 0.1986 -0.702 0.3790 0.5525E-01 apatite-OH 0.9461E-04 -4.024 0.4753E-01 -1.323 0.9070E-01 0.1510E-01 clinochlore 0.7619E-02 -2.118 4.235 0.627 8.082 1.611 daphnite 0.3133E-02 -2.504 2.235 0.349 4.266 0.6774 chlorite-Mn 0.1664E-03 -3.779 0.1180 -0.928 0.2252 0.3761E-01 microcline 0.9298E-02 -2.032 2.588 0.413 4.939 1.011 stilbite 0.3744E-01 -1.427 26.39 1.421 50.36 12.31 stilpnomelane-Fe 0.1581E-02 -2.801 1.704 0.232 3.252 0.5887 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9236E+00 0.9236E+00 1.0000 -0.035 grossular 0.7642E-01 0.7642E-01 1.0000 -1.117 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.6978E+00 0.6978E+00 1.0000 -0.156 daphnite 0.2869E+00 0.2869E+00 1.0000 -0.542 chlorite-Mn 0.1524E-01 0.1524E-01 1.0000 -1.817 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 52.396495 g Volume = 21.680476 cm3 Porosity: -7.3312% V(tot) - V(min): -.14809E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 47.9990000 g log = 1.6812 Original solution: 1000.0103000 g Original solution / Rock added: 20.83 (Water/Rock Ratio), log = 1.3188 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0520 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1125E-06 1.0073 0.1192E-06 0.1184E-06 CH4,gas 0.6992E-09 1.0129 0.7451E-09 0.7356E-09 H2,gas 0.8568E-04 1.0006 0.9019E-04 0.9014E-04 H2S,gas 0.1201E-07 0.9959 0.1258E-07 0.1263E-07 S2,gas 0.6929E-27 1.0000 0.7290E-27 0.7290E-27 CO,gas 0.2647E-14 1.0000 0.2785E-14 0.2785E-14 SO3,gas 0.5489E-40 1.0000 0.5775E-40 0.5775E-40 SO2,gas 0.1873E-21 1.0000 0.1970E-21 0.1970E-21 HCl,gas 0.3956E-17 1.0000 0.4162E-17 0.4162E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.29 -8.92 -2.975 0.15237E+05 -6.924 3 CH4,gas 4.81 -6.32 -11.13 -2.782 0.19000E+05 -9.128 4 H2,gas 8.29 2.24 -6.04 -3.454 0.10321E+05 -4.045 5 H2S,gas -5.94 -15.84 -9.90 -4.950 0.16904E+05 -7.900 6 S2,gas -7.03 -36.17 -29.14 -4.483 0.49751E+05 -27.137 7 CO,gas 3.51 -13.04 -16.56 -5.094 0.28267E+05 -14.555 8 SO3,gas 17.43 -24.81 -42.24 -10.560 0.72121E+05 -40.238 9 SO2,gas 1.14 -22.57 -23.71 -6.321 0.40476E+05 -21.705 10 HCl,gas 5.48 -13.90 -19.38 -9.690 0.33092E+05 -17.381 11 acmite 7.74 7.12 -0.62 -0.064 0.10599E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.94 -4.61 -0.231 0.78759E+04 20 analcite 3.37 2.90 -0.47 -0.052 0.79575E+03 26 annite 20.21 17.60 -2.61 -0.145 0.44500E+04 27 phlogopite 27.15 24.82 -2.33 -0.129 0.39721E+04 29 anorthite 12.80 8.76 -4.04 -0.311 0.68961E+04 35 aragonite 0.99 -2.75 -3.74 -1.246 0.63838E+04 36 brucite 12.58 9.08 -3.49 -0.699 0.59635E+04 37 calcite 0.83 -2.75 -3.59 -1.195 0.61225E+04 38 carnegieite-low 9.06 6.14 -2.93 -0.418 0.49978E+04 39 carnegieite-high 10.13 6.14 -4.00 -0.571 0.68246E+04 40 carpholite-Mg 8.65 5.31 -3.34 -0.223 0.57059E+04 41 carpholite-Fe 6.78 2.90 -3.88 -0.259 0.66249E+04 42 celadonite 5.40 3.42 -1.98 -0.117 0.33829E+04 43 celadonite-Fe 3.94 1.01 -2.92 -0.172 0.49916E+04 44 chrysotile 23.94 20.79 -3.15 -0.263 0.53806E+04 50 chloritoid-Mg 13.26 8.54 -4.72 -0.315 0.80587E+04 51 chloritoid-Fe 9.24 6.14 -3.10 -0.207 0.52979E+04 52 chloritoid-Mn 11.46 8.44 -3.02 -0.202 0.51630E+04 54 coesite -2.37 -3.23 -0.86 -0.288 0.14746E+04 61 cristobalite -2.55 -3.23 -0.68 -0.228 0.11675E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.35 -1.55 -0.258 0.26480E+04 67 diopside 16.22 15.15 -1.06 -0.106 0.18151E+04 68 hedenbergite 14.24 12.75 -1.50 -0.150 0.25573E+04 75 epidote 24.78 23.62 -1.16 -0.056 0.19766E+04 76 clinozoisite 22.92 19.41 -3.52 -0.160 0.60028E+04 77 epidote-Fe 29.94 27.83 -2.11 -0.109 0.35979E+04 78 fayalite 14.08 10.12 -3.96 -0.565 0.67535E+04 79 ferrosilite 11.19 6.89 -4.30 -0.430 0.73370E+04 83 gibbsite 4.10 1.35 -2.75 -0.393 0.46992E+04 84 glaucophane 23.11 20.13 -2.98 -0.081 0.50901E+04 85 glaucophane-Fe 17.42 12.91 -4.50 -0.122 0.76919E+04 87 greenalite 16.19 13.57 -2.63 -0.219 0.44824E+04 90 hematite 12.60 11.11 -1.48 -0.180 0.25322E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.90 -1.35 -0.135 0.22988E+04 96 julgoldite 70.57 66.33 -4.25 -0.110 0.72525E+04 97 kalsilite 7.62 4.03 -3.59 -0.512 0.61232E+04 98 kaolinite -1.27 -3.78 -2.50 -0.227 0.42725E+04 101 laumontite 2.97 2.29 -0.68 -0.045 0.11637E+04 102 lawsonite 9.68 8.76 -0.92 -0.061 0.15699E+04 103 leucite 4.17 0.80 -3.37 -0.337 0.57482E+04 105 lizardite 23.29 20.79 -2.50 -0.208 0.42708E+04 107 magnetite 20.13 17.79 -2.34 -0.191 0.39953E+04 108 minnesotaite 10.46 7.10 -3.36 -0.198 0.57330E+04 120 muscovite 2.68 0.26 -2.42 -0.142 0.41329E+04 121 paragonite 4.34 2.36 -1.97 -0.116 0.33714E+04 122 nepheline 8.38 6.14 -2.24 -0.320 0.38257E+04 128 periclase-Fe 11.64 6.68 -4.96 -1.240 0.84705E+04 134 phlogopite-Na 29.73 26.92 -2.81 -0.156 0.47940E+04 136 prehnite 19.47 18.06 -1.41 -0.083 0.24008E+04 137 prehnite-Fe 22.59 22.27 -0.31 -0.019 0.53689E+03 138 pumpellyite-Fe 46.47 44.14 -2.33 -0.052 0.39722E+04 139 pumpellyite-Mg 49.19 46.55 -2.64 -0.059 0.45148E+04 143 pyrrhotite -4.24 -9.16 -4.92 -1.640 0.84025E+04 144 pyrrhotiteFe0.875 -6.00 -10.28 -4.28 -1.573 0.73018E+04 145 pyroxmangite 7.42 5.75 -1.67 -0.333 0.28466E+04 146 pyrophyllite -6.10 -10.24 -4.14 -0.259 0.70745E+04 147 quartz -2.98 -3.23 -0.25 -0.084 0.42850E+03 152 rhodonite 7.46 5.75 -1.71 -0.343 0.29258E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.21 -2.39 -0.071 0.40781E+04 171 talc 16.55 14.32 -2.23 -0.131 0.38130E+04 174 tephroite 18.11 14.73 -3.38 -0.483 0.57749E+04 178 tridymite -2.61 -3.23 -0.62 -0.206 0.10558E+04 179 tremolite 48.00 44.63 -3.38 -0.091 0.57680E+04 181 troilite-low -4.39 -9.16 -4.77 -1.590 0.81457E+04 187 wairakite 4.06 2.29 -1.77 -0.104 0.30145E+04 188 walstromite 11.53 9.30 -2.23 -0.445 0.38017E+04 189 wollastonite 10.48 9.30 -1.18 -0.236 0.20156E+04 190 pseudo-wollastonite 11.02 9.30 -1.72 -0.344 0.29342E+04 191 zoisite 22.96 19.41 -3.56 -0.162 0.60753E+04 192 akaganeite 7.77 5.56 -2.21 -0.478 0.37743E+04 197 beidellite-Na -1.26 -6.08 -4.83 -0.295 0.82388E+04 199 chalcedony -2.79 -3.23 -0.44 -0.146 0.74882E+03 201 montmorillonite-Ca -2.21 -5.62 -3.41 -0.211 0.58145E+04 202 montmorillonite-K -2.16 -5.73 -3.57 -0.219 0.60997E+04 203 montmorillonite-Mg -2.40 -6.19 -3.79 -0.234 0.64663E+04 204 montmorillonite-Na -1.96 -5.04 -3.08 -0.189 0.52566E+04 205 nontronite-Ca 3.28 1.76 -1.52 -0.098 0.25918E+04 206 nontronite-H 2.60 -0.31 -2.90 -0.195 0.49554E+04 207 nontronite-K 3.40 1.65 -1.76 -0.113 0.29984E+04 208 nontronite-Mg 3.14 1.19 -1.95 -0.126 0.33242E+04 209 nontronite-Na 3.58 2.34 -1.24 -0.080 0.21188E+04 224 tobermorite 9.84 7.21 -2.63 -0.718 0.44921E+04 233 boehmite 4.43 1.35 -3.08 -0.514 0.52664E+04 235 ferrous-oxide 9.82 6.68 -3.15 -0.786 0.53715E+04 240 silica-amorphous -2.08 -3.23 -1.15 -0.384 0.19690E+04 242 an20ab80 2.08 1.49 -0.59 -0.045 0.10076E+04 243 an25ab75 2.71 1.94 -0.77 -0.059 0.13074E+04 244 an30ab70 3.34 2.40 -0.95 -0.073 0.16156E+04 245 tr.625ac.25prg.125 45.31 42.80 -2.51 -0.068 0.42854E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 47.9990000 g New total amount of reactant added: 49.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1496E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 49.9990000 Water: Moles liquid = 0.5517E+02 kg liquid = 0.9939E+00 Moles total = 0.5488E+02 kg total = 0.9887E+00 Activity = 1.0000 Stoichiometric ionic strength = .7446148E-02 Osmotic coef. = 0.9570 True ionic strength = .1349812E-01 Chg. balance for total moles = -.1496E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.12045E-09 -9.9192 0.10362E-09 -9.9845 0.86033E+00 -0.0653 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13837E-03 -3.8590 0.11853E-03 -3.9262 0.85657E+00 -0.0672 4 SO4-- 0.21473E-04 -4.6681 0.12302E-04 -4.9100 0.57292E+00 -0.2419 5 HCO3- 0.56242E-05 -5.2499 0.48227E-05 -5.3167 0.85748E+00 -0.0668 6 HS- 0.41662E-05 -5.3803 0.35690E-05 -5.4475 0.85667E+00 -0.0672 7 Al+++ 0.79738E-28 -28.0983 0.23064E-28 -28.6371 0.28924E+00 -0.5387 8 H4SiO4 0.58970E-03 -3.2294 0.58970E-03 -3.2294 0.10000E+01 0.0000 9 Ca++ 0.69455E-07 -7.1583 0.39582E-07 -7.4025 0.56989E+00 -0.2442 10 Mg++ 0.23553E-10 -10.6279 0.13378E-10 -10.8736 0.56800E+00 -0.2456 11 Fe++ 0.90881E-13 -13.0415 0.51662E-13 -13.2868 0.56845E+00 -0.2453 12 K+ 0.10517E-03 -3.9781 0.90199E-04 -4.0448 0.85763E+00 -0.0667 13 Na+ 0.13364E-01 -1.8741 0.11445E-01 -1.9414 0.85647E+00 -0.0673 14 Mn++ 0.18591E-10 -10.7307 0.10574E-10 -10.9757 0.56879E+00 -0.2450 15 HPO4-- 0.18637E-06 -6.7296 0.10679E-06 -6.9715 0.57298E+00 -0.2419 16 HSiO3- 0.64821E-02 -2.1883 0.55524E-02 -2.2555 0.85657E+00 -0.0672 17 Ca(HSiO3)+ 0.57406E-08 -8.2410 0.49241E-08 -8.3077 0.85776E+00 -0.0666 18 Mg(HSiO3)+ 0.24147E-11 -11.6171 0.20713E-11 -11.6838 0.85776E+00 -0.0666 19 NaHSiO3,aq 0.10093E-02 -2.9960 0.10093E-02 -2.9960 0.10000E+01 0.0000 20 AlO+ 0.32327E-15 -15.4904 0.27729E-15 -15.5571 0.85776E+00 -0.0666 22 HAlO2,aq 0.53548E-09 -9.2713 0.53548E-09 -9.2713 0.10000E+01 0.0000 23 AlO2- 0.13488E-04 -4.8700 0.11539E-04 -4.9378 0.85545E+00 -0.0678 24 CH4,aq 0.13760E-11 -11.8614 0.13729E-11 -11.8624 0.99772E+00 -0.0010 29 CO,aq 0.22479E-17 -17.6482 0.22479E-17 -17.6482 0.10000E+01 0.0000 30 CO2,aq 0.10099E-08 -8.9957 0.10076E-08 -8.9967 0.99772E+00 -0.0010 31 CO3-2 0.75224E-05 -5.1236 0.43031E-05 -5.3662 0.57204E+00 -0.2426 32 CaCO3,aq 0.20861E-08 -8.6807 0.20861E-08 -8.6807 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.56075E-11 -11.2512 0.48099E-11 -11.3179 0.85776E+00 -0.0666 34 CaCl+ 0.87155E-11 -11.0597 0.74759E-11 -11.1263 0.85776E+00 -0.0666 35 CaCl2,aq 0.20631E-15 -15.6855 0.20631E-15 -15.6855 0.10000E+01 0.0000 36 CaOH+ 0.31401E-07 -7.5031 0.26935E-07 -7.5697 0.85776E+00 -0.0666 37 CaSO4,aq 0.15172E-09 -9.8190 0.15172E-09 -9.8190 0.10000E+01 0.0000 38 HCl,aq 0.23102E-14 -14.6363 0.23102E-14 -14.6363 0.10000E+01 0.0000 43 FeCl+ 0.11119E-16 -16.9540 0.95371E-17 -17.0206 0.85776E+00 -0.0666 46 FeO,aq 0.19026E-09 -9.7207 0.19026E-09 -9.7207 0.10000E+01 0.0000 47 FeOH+ 0.19269E-10 -10.7151 0.16528E-10 -10.7818 0.85776E+00 -0.0666 48 HFeO2- 0.23055E-07 -7.6372 0.19749E-07 -7.7045 0.85657E+00 -0.0672 49 FeO+ 0.15932E-15 -15.7977 0.13666E-15 -15.8644 0.85776E+00 -0.0666 51 FeO2- 0.29202E-08 -8.5346 0.25014E-08 -8.6018 0.85657E+00 -0.0672 52 HFeO2,aq 0.32439E-10 -10.4889 0.32439E-10 -10.4889 0.10000E+01 0.0000 53 H2,aq 0.86823E-07 -7.0614 0.86625E-07 -7.0624 0.99772E+00 -0.0010 54 KCl,aq 0.18930E-09 -9.7229 0.18930E-09 -9.7229 0.10000E+01 0.0000 55 KHSO4,aq 0.30769E-18 -18.5119 0.30769E-18 -18.5119 0.10000E+01 0.0000 56 KOH,aq 0.37947E-06 -6.4208 0.37947E-06 -6.4208 0.10000E+01 0.0000 57 KSO4- 0.19958E-07 -7.6999 0.17095E-07 -7.7671 0.85657E+00 -0.0672 58 MgCO3,aq 0.17618E-12 -12.7540 0.17618E-12 -12.7540 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19327E-14 -14.7138 0.16578E-14 -14.7805 0.85776E+00 -0.0666 60 MgCl+ 0.26742E-14 -14.5728 0.22939E-14 -14.6394 0.85776E+00 -0.0666 61 MgOH+ 0.58798E-10 -10.2306 0.50435E-10 -10.2973 0.85776E+00 -0.0666 63 MnO,aq 0.10396E-08 -8.9831 0.10396E-08 -8.9831 0.10000E+01 0.0000 64 MnOH+ 0.36640E-09 -9.4360 0.31428E-09 -9.5027 0.85776E+00 -0.0666 65 MnO2-2 0.58531E-11 -11.2326 0.33482E-11 -11.4752 0.57204E+00 -0.2426 66 HMnO2- 0.87759E-10 -10.0567 0.75172E-10 -10.1239 0.85657E+00 -0.0672 69 MnCl+ 0.88435E-14 -14.0534 0.75856E-14 -14.1200 0.85776E+00 -0.0666 70 MnSO4,aq 0.36867E-13 -13.4334 0.36867E-13 -13.4334 0.10000E+01 0.0000 71 NaCl,aq 0.44296E-06 -6.3536 0.44296E-06 -6.3536 0.10000E+01 0.0000 72 NaOH,aq 0.48534E-04 -4.3140 0.48534E-04 -4.3140 0.10000E+01 0.0000 74 OH- 0.67667E-02 -2.1696 0.57886E-02 -2.2374 0.85545E+00 -0.0678 79 HPO3-2 0.51077E-16 -16.2918 0.29218E-16 -16.5343 0.57204E+00 -0.2426 82 H3PO4,aq 0.73822E-17 -17.1318 0.73822E-17 -17.1318 0.10000E+01 0.0000 83 H2PO4- 0.22633E-09 -9.6453 0.19400E-09 -9.7122 0.85716E+00 -0.0669 84 PO4-3 0.30028E-08 -8.5225 0.89999E-09 -9.0458 0.29972E+00 -0.5233 88 HP2O7-3 0.20140E-16 -16.6959 0.58291E-17 -17.2344 0.28943E+00 -0.5385 89 P2O7-4 0.12168E-15 -15.9148 0.13877E-16 -16.8577 0.11405E+00 -0.9429 90 H2S,aq 0.11137E-08 -8.9532 0.11112E-08 -8.9542 0.99772E+00 -0.0010 91 S2-2 0.56536E-14 -14.2477 0.32341E-14 -14.4902 0.57204E+00 -0.2426 97 SO3-2 0.25137E-12 -12.5997 0.14530E-12 -12.8377 0.57804E+00 -0.2380 98 HSO3- 0.10287E-14 -14.9877 0.88115E-15 -15.0550 0.85657E+00 -0.0672 99 HSO4- 0.13780E-11 -11.8608 0.11828E-11 -11.9271 0.85836E+00 -0.0663 101 S2O3-2 0.28164E-15 -15.5503 0.16111E-15 -15.7929 0.57204E+00 -0.2426 Charge balance for all species = -.1468E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1204457E-09 -.1436864E-01 -.1446693E+02 0.0000 2 H2O 0.1000000E+01 0.5550760E+02 0.9988950E+06 0.0000 3 Cl- 0.1383722E-03 0.1388154E-03 0.4916052E+01 6.0584 4 SO4-- 0.2147255E-04 0.2147133E-04 0.2060320E+01 15.0591 5 HCO3- 0.5624231E-05 0.1314969E-04 0.8014815E+00 4.6678 6 HS- 0.4166187E-05 0.4188639E-05 0.1383755E+00 4.5371 7 Al+++ 0.7973823E-28 0.1348883E-04 0.3635517E+00 1.3166 8 H4SiO4 0.5897027E-03 0.8081088E-02 0.7758695E+03 -3.2294 9 Ca++ 0.6945545E-07 0.1088491E-06 0.4357693E-02 12.5666 10 Mg++ 0.2355343E-10 0.8494713E-10 0.2062981E-05 9.0955 11 Fe++ 0.9088129E-13 0.2621749E-07 0.1462571E-02 6.6823 12 K+ 0.1051718E-03 0.1055714E-03 0.4123549E+01 5.9397 13 Na+ 0.1336351E-01 0.1442181E-01 0.3311927E+03 8.0432 14 Mn++ 0.1859104E-10 0.1518234E-08 0.8331775E-04 8.9933 15 HPO4-- 0.1863721E-06 0.1896012E-06 0.1817788E-01 12.9976 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8278962E+00 -.1428157E-01 -.8136146E+00 0.0000000E+00 2 H2O 0.5488149E+02 0.5517123E+02 -.2897389E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1411147E-02 0.2134121E-04 0.1389806E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385643E-02 0.4163256E-05 -.1389806E-02 0.0000000E+00 7 Al+++ 0.1630338E+00 0.1340709E-04 0.1630204E+00 0.0000000E+00 8 H4SiO4 0.5206287E+00 0.8032118E-02 0.5125966E+00 0.0000000E+00 9 Ca++ 0.5752045E-01 0.1081894E-06 0.5752035E-01 0.0000000E+00 10 Mg++ 0.3968175E-01 0.8443236E-10 0.3968175E-01 0.0000000E+00 11 Fe++ 0.3564972E-01 0.2605862E-07 0.3564969E-01 0.0000000E+00 12 K+ 0.1061550E-01 0.1049316E-03 0.1051057E-01 0.0000000E+00 13 Na+ 0.6292100E-01 0.1433441E-01 0.4858659E-01 0.0000000E+00 14 Mn++ 0.8669125E-03 0.1509034E-08 0.8669110E-03 0.0000000E+00 15 HPO4-- 0.2958729E-03 0.1884522E-06 0.2956845E-03 0.0000000E+00 Chg. balance for solid moles: 0.1517E-15 Mass of aqueous solution: 0.995026E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 49.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4859E-01 -1.313 12.74 1.105 23.34 4.891 andradite 0.5559E-02 -2.255 2.825 0.451 5.176 0.7340 grossular 0.4898E-03 -3.310 0.2206 -0.656 0.4042 0.6138E-01 apatite-OH 0.9856E-04 -4.006 0.4951E-01 -1.305 0.9071E-01 0.1573E-01 clinochlore 0.7936E-02 -2.100 4.411 0.645 8.082 1.678 daphnite 0.3207E-02 -2.494 2.289 0.360 4.193 0.6935 chlorite-Mn 0.1734E-03 -3.761 0.1229 -0.910 0.2252 0.3917E-01 microcline 0.9661E-02 -2.015 2.689 0.430 4.927 1.050 stilbite 0.3888E-01 -1.410 27.40 1.438 50.20 12.78 stilpnomelane-Fe 0.1699E-02 -2.770 1.831 0.263 3.355 0.6326 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9190E+00 0.9190E+00 1.0000 -0.037 grossular 0.8096E-01 0.8096E-01 1.0000 -1.092 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7013E+00 0.7013E+00 1.0000 -0.154 daphnite 0.2834E+00 0.2834E+00 1.0000 -0.548 chlorite-Mn 0.1532E-01 0.1532E-01 1.0000 -1.815 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 54.578641 g Volume = 22.575252 cm3 Porosity: -7.5032% V(tot) - V(min): -.15757E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 49.9990000 g log = 1.6990 Original solution: 1000.0103000 g Original solution / Rock added: 20.00 (Water/Rock Ratio), log = 1.3010 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1088E-06 1.0073 0.1153E-06 0.1145E-06 CH4,gas 0.2037E-08 1.0129 0.2171E-08 0.2143E-08 H2,gas 0.1129E-03 1.0006 0.1188E-03 0.1187E-03 H2S,gas 0.3093E-07 0.9959 0.3241E-07 0.3254E-07 S2,gas 0.2649E-26 1.0000 0.2787E-26 0.2787E-26 CO,gas 0.3374E-14 1.0000 0.3550E-14 0.3550E-14 SO3,gas 0.4694E-40 1.0000 0.4939E-40 0.4939E-40 SO2,gas 0.2110E-21 1.0000 0.2220E-21 0.2220E-21 HCl,gas 0.3877E-17 1.0000 0.4079E-17 0.4079E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 -0.36397E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.30 -8.94 -2.979 0.15261E+05 -6.938 3 CH4,gas 4.81 -5.85 -10.66 -2.666 0.18207E+05 -8.663 4 H2,gas 8.29 2.36 -5.93 -3.386 0.10117E+05 -3.925 5 H2S,gas -5.94 -15.43 -9.49 -4.745 0.16203E+05 -7.489 6 S2,gas -7.03 -35.59 -28.55 -4.393 0.48757E+05 -26.555 7 CO,gas 3.51 -12.94 -16.45 -5.061 0.28088E+05 -14.450 8 SO3,gas 17.43 -24.88 -42.31 -10.577 0.72237E+05 -40.306 9 SO2,gas 1.14 -22.52 -23.65 -6.308 0.40388E+05 -21.654 10 HCl,gas 5.48 -13.91 -19.39 -9.695 0.33107E+05 -17.389 11 acmite 7.74 7.09 -0.65 -0.068 0.11125E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.93 -4.62 -0.231 0.78968E+04 20 analcite 3.37 2.90 -0.47 -0.052 0.80188E+03 26 annite 20.21 17.61 -2.59 -0.144 0.44298E+04 27 phlogopite 27.15 24.85 -2.29 -0.127 0.39134E+04 29 anorthite 12.80 8.74 -4.06 -0.312 0.69267E+04 35 aragonite 0.99 -2.73 -3.72 -1.240 0.63533E+04 36 brucite 12.58 9.10 -3.48 -0.696 0.59439E+04 37 calcite 0.83 -2.73 -3.57 -1.189 0.60920E+04 38 carnegieite-low 9.06 6.13 -2.93 -0.419 0.50100E+04 39 carnegieite-high 10.13 6.13 -4.00 -0.572 0.68369E+04 40 carpholite-Mg 8.65 5.27 -3.38 -0.225 0.57721E+04 41 carpholite-Fe 6.78 2.86 -3.93 -0.262 0.67039E+04 42 celadonite 5.40 3.43 -1.97 -0.116 0.33572E+04 43 celadonite-Fe 3.94 1.02 -2.92 -0.172 0.49787E+04 44 chrysotile 23.94 20.83 -3.11 -0.259 0.53095E+04 50 chloritoid-Mg 13.26 8.50 -4.76 -0.317 0.81310E+04 51 chloritoid-Fe 9.24 6.09 -3.15 -0.210 0.53831E+04 52 chloritoid-Mn 11.46 8.40 -3.07 -0.204 0.52353E+04 54 coesite -2.37 -3.23 -0.86 -0.287 0.14685E+04 61 cristobalite -2.55 -3.23 -0.68 -0.227 0.11613E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.32 -1.58 -0.263 0.26970E+04 67 diopside 16.22 15.20 -1.01 -0.101 0.17282E+04 68 hedenbergite 14.24 12.79 -1.45 -0.145 0.24832E+04 75 epidote 24.78 23.58 -1.20 -0.058 0.20415E+04 76 clinozoisite 22.92 19.39 -3.53 -0.160 0.60212E+04 77 epidote-Fe 29.94 27.76 -2.17 -0.113 0.37093E+04 78 fayalite 14.08 10.14 -3.94 -0.563 0.67339E+04 79 ferrosilite 11.19 6.91 -4.28 -0.428 0.73112E+04 83 gibbsite 4.10 1.32 -2.78 -0.397 0.47482E+04 84 glaucophane 23.11 20.17 -2.94 -0.079 0.50191E+04 85 glaucophane-Fe 17.42 12.93 -4.49 -0.121 0.76595E+04 87 greenalite 16.19 13.59 -2.61 -0.217 0.44500E+04 90 hematite 12.60 11.00 -1.59 -0.193 0.27232E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.90 -1.35 -0.135 0.23049E+04 96 julgoldite 70.57 66.26 -4.31 -0.112 0.73638E+04 97 kalsilite 7.62 4.03 -3.59 -0.513 0.61355E+04 98 kaolinite -1.27 -3.83 -2.55 -0.232 0.43583E+04 101 laumontite 2.97 2.28 -0.69 -0.046 0.11821E+04 102 lawsonite 9.68 8.74 -0.94 -0.062 0.16006E+04 103 leucite 4.17 0.80 -3.37 -0.337 0.57543E+04 105 lizardite 23.29 20.83 -2.46 -0.205 0.41998E+04 107 magnetite 20.13 17.68 -2.45 -0.200 0.41795E+04 108 minnesotaite 10.46 7.13 -3.33 -0.196 0.56883E+04 120 muscovite 2.68 0.20 -2.48 -0.146 0.42309E+04 121 paragonite 4.34 2.30 -2.03 -0.120 0.34694E+04 122 nepheline 8.38 6.13 -2.25 -0.321 0.38380E+04 128 periclase-Fe 11.64 6.68 -4.96 -1.239 0.84637E+04 134 phlogopite-Na 29.73 26.96 -2.77 -0.154 0.47353E+04 136 prehnite 19.47 18.08 -1.39 -0.082 0.23702E+04 137 prehnite-Fe 22.59 22.26 -0.32 -0.019 0.55281E+03 138 pumpellyite-Fe 46.47 44.16 -2.32 -0.051 0.39534E+04 139 pumpellyite-Mg 49.19 46.57 -2.63 -0.058 0.44831E+04 143 pyrrhotite -4.24 -8.75 -4.51 -1.502 0.76942E+04 144 pyrrhotiteFe0.875 -6.00 -9.88 -3.88 -1.426 0.66197E+04 145 pyroxmangite 7.42 5.76 -1.65 -0.330 0.28208E+04 146 pyrophyllite -6.10 -10.28 -4.19 -0.262 0.71480E+04 147 quartz -2.98 -3.23 -0.25 -0.082 0.42237E+03 152 rhodonite 7.46 5.76 -1.70 -0.340 0.29001E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.25 -2.35 -0.070 0.40138E+04 171 talc 16.55 14.37 -2.18 -0.128 0.37297E+04 174 tephroite 18.11 14.76 -3.36 -0.479 0.57296E+04 178 tridymite -2.61 -3.23 -0.61 -0.205 0.10497E+04 179 tremolite 48.00 44.78 -3.23 -0.087 0.55108E+04 181 troilite-low -4.39 -8.75 -4.36 -1.452 0.74374E+04 187 wairakite 4.06 2.28 -1.78 -0.104 0.30329E+04 188 walstromite 11.53 9.34 -2.19 -0.438 0.37405E+04 189 wollastonite 10.48 9.34 -1.14 -0.229 0.19544E+04 190 pseudo-wollastonite 11.02 9.34 -1.68 -0.337 0.28730E+04 191 zoisite 22.96 19.39 -3.57 -0.162 0.60938E+04 192 akaganeite 7.77 5.50 -2.27 -0.490 0.38698E+04 197 beidellite-Na -1.26 -6.13 -4.87 -0.298 0.83204E+04 199 chalcedony -2.79 -3.23 -0.43 -0.145 0.74269E+03 201 montmorillonite-Ca -2.21 -5.64 -3.43 -0.212 0.58563E+04 202 montmorillonite-K -2.16 -5.76 -3.60 -0.220 0.61404E+04 203 montmorillonite-Mg -2.40 -6.22 -3.81 -0.236 0.65139E+04 204 montmorillonite-Na -1.96 -5.06 -3.10 -0.190 0.52973E+04 205 nontronite-Ca 3.28 1.66 -1.62 -0.105 0.27673E+04 206 nontronite-H 2.60 -0.41 -3.01 -0.202 0.51400E+04 207 nontronite-K 3.40 1.55 -1.86 -0.119 0.31729E+04 208 nontronite-Mg 3.14 1.09 -2.05 -0.133 0.35055E+04 209 nontronite-Na 3.58 2.24 -1.34 -0.086 0.22934E+04 224 tobermorite 9.84 7.24 -2.60 -0.710 0.44401E+04 233 boehmite 4.43 1.32 -3.11 -0.519 0.53154E+04 235 ferrous-oxide 9.82 6.68 -3.14 -0.785 0.53648E+04 240 silica-amorphous -2.08 -3.23 -1.15 -0.383 0.19629E+04 242 an20ab80 2.08 1.49 -0.59 -0.046 0.10137E+04 243 an25ab75 2.71 1.94 -0.77 -0.059 0.13151E+04 244 an30ab70 3.34 2.39 -0.95 -0.073 0.16247E+04 245 tr.625ac.25prg.125 45.31 42.93 -2.38 -0.064 0.40629E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 49.9990000 g New total amount of reactant added: 51.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1495E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 51.9990000 Water: Moles liquid = 0.5516E+02 kg liquid = 0.9937E+00 Moles total = 0.5486E+02 kg total = 0.9883E+00 Activity = 1.0000 Stoichiometric ionic strength = .7601889E-02 Osmotic coef. = 0.9581 True ionic strength = .1377608E-01 Chg. balance for total moles = -.1495E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11867E-09 -9.9257 0.10198E-09 -9.9915 0.85936E+00 -0.0658 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13840E-03 -3.8589 0.11840E-03 -3.9266 0.85555E+00 -0.0678 4 SO4-- 0.17225E-04 -4.7638 0.98225E-05 -5.0078 0.57026E+00 -0.2439 5 HCO3- 0.55627E-05 -5.2547 0.47643E-05 -5.3220 0.85647E+00 -0.0673 6 HS- 0.84224E-05 -5.0746 0.72066E-05 -5.1423 0.85564E+00 -0.0677 7 Al+++ 0.72250E-28 -28.1412 0.20676E-28 -28.6845 0.28618E+00 -0.5434 8 H4SiO4 0.59477E-03 -3.2256 0.59477E-03 -3.2256 0.10000E+01 0.0000 9 Ca++ 0.71948E-07 -7.1430 0.40808E-07 -7.3893 0.56719E+00 -0.2463 10 Mg++ 0.23480E-10 -10.6293 0.13273E-10 -10.8770 0.56528E+00 -0.2477 11 Fe++ 0.89082E-13 -13.0502 0.50397E-13 -13.2976 0.56573E+00 -0.2474 12 K+ 0.10737E-03 -3.9691 0.91977E-04 -4.0363 0.85662E+00 -0.0672 13 Na+ 0.13643E-01 -1.8651 0.11671E-01 -1.9329 0.85544E+00 -0.0678 14 Mn++ 0.18533E-10 -10.7321 0.10491E-10 -10.9792 0.56608E+00 -0.2471 15 HPO4-- 0.17420E-06 -6.7589 0.99352E-07 -7.0028 0.57032E+00 -0.2439 16 HSiO3- 0.66513E-02 -2.1771 0.56905E-02 -2.2448 0.85555E+00 -0.0678 17 Ca(HSiO3)+ 0.60728E-08 -8.2166 0.52029E-08 -8.2838 0.85676E+00 -0.0671 18 Mg(HSiO3)+ 0.24582E-11 -11.6094 0.21060E-11 -11.6765 0.85676E+00 -0.0671 19 NaHSiO3,aq 0.10548E-02 -2.9768 0.10548E-02 -2.9768 0.10000E+01 0.0000 20 AlO+ 0.29959E-15 -15.5235 0.25667E-15 -15.5906 0.85676E+00 -0.0671 22 HAlO2,aq 0.50367E-09 -9.2979 0.50367E-09 -9.2979 0.10000E+01 0.0000 23 AlO2- 0.12908E-04 -4.8892 0.11028E-04 -4.9575 0.85441E+00 -0.0683 24 CH4,aq 0.34380E-11 -11.4637 0.34299E-11 -11.4647 0.99767E+00 -0.0010 29 CO,aq 0.27670E-17 -17.5580 0.27670E-17 -17.5580 0.10000E+01 0.0000 30 CO2,aq 0.98185E-09 -9.0080 0.97956E-09 -9.0090 0.99767E+00 -0.0010 31 CO3-2 0.75868E-05 -5.1199 0.43196E-05 -5.3646 0.56936E+00 -0.2446 32 CaCO3,aq 0.21589E-08 -8.6658 0.21589E-08 -8.6658 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.57179E-11 -11.2428 0.48988E-11 -11.3099 0.85676E+00 -0.0671 34 CaCl+ 0.89867E-11 -11.0464 0.76994E-11 -11.1135 0.85676E+00 -0.0671 35 CaCl2,aq 0.21226E-15 -15.6731 0.21226E-15 -15.6731 0.10000E+01 0.0000 36 CaOH+ 0.32935E-07 -7.4823 0.28217E-07 -7.5495 0.85676E+00 -0.0671 37 CaSO4,aq 0.12489E-09 -9.9035 0.12489E-09 -9.9035 0.10000E+01 0.0000 38 HCl,aq 0.22712E-14 -14.6438 0.22712E-14 -14.6438 0.10000E+01 0.0000 43 FeCl+ 0.10848E-16 -16.9647 0.92939E-17 -17.0318 0.85676E+00 -0.0671 46 FeO,aq 0.19164E-09 -9.7175 0.19164E-09 -9.7175 0.10000E+01 0.0000 47 FeOH+ 0.19123E-10 -10.7184 0.16384E-10 -10.7856 0.85676E+00 -0.0671 48 HFeO2- 0.23626E-07 -7.6266 0.20213E-07 -7.6944 0.85555E+00 -0.0678 49 FeO+ 0.14052E-15 -15.8523 0.12039E-15 -15.9194 0.85676E+00 -0.0671 51 FeO2- 0.26595E-08 -8.5752 0.22753E-08 -8.6430 0.85555E+00 -0.0678 52 HFeO2,aq 0.29039E-10 -10.5370 0.29039E-10 -10.5370 0.10000E+01 0.0000 53 H2,aq 0.10993E-06 -6.9589 0.10968E-06 -6.9599 0.99767E+00 -0.0010 54 KCl,aq 0.19283E-09 -9.7148 0.19283E-09 -9.7148 0.10000E+01 0.0000 55 KHSO4,aq 0.24654E-18 -18.6081 0.24654E-18 -18.6081 0.10000E+01 0.0000 56 KOH,aq 0.39320E-06 -6.4054 0.39320E-06 -6.4054 0.10000E+01 0.0000 57 KSO4- 0.16269E-07 -7.7886 0.13919E-07 -7.8564 0.85555E+00 -0.0678 58 MgCO3,aq 0.17547E-12 -12.7558 0.17547E-12 -12.7558 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18964E-14 -14.7221 0.16248E-14 -14.7892 0.85676E+00 -0.0671 60 MgCl+ 0.26535E-14 -14.5762 0.22734E-14 -14.6433 0.85676E+00 -0.0671 61 MgOH+ 0.59346E-10 -10.2266 0.50845E-10 -10.2938 0.85676E+00 -0.0671 63 MnO,aq 0.10650E-08 -8.9727 0.10650E-08 -8.9727 0.10000E+01 0.0000 64 MnOH+ 0.36981E-09 -9.4320 0.31684E-09 -9.4992 0.85676E+00 -0.0671 65 MnO2-2 0.62203E-11 -11.2062 0.35416E-11 -11.4508 0.56936E+00 -0.2446 66 HMnO2- 0.91462E-10 -10.0388 0.78250E-10 -10.1065 0.85555E+00 -0.0678 69 MnCl+ 0.87750E-14 -14.0568 0.75180E-14 -14.1239 0.85676E+00 -0.0671 70 MnSO4,aq 0.29204E-13 -13.5346 0.29204E-13 -13.5346 0.10000E+01 0.0000 71 NaCl,aq 0.45123E-06 -6.3456 0.45123E-06 -6.3456 0.10000E+01 0.0000 72 NaOH,aq 0.50290E-04 -4.2985 0.50290E-04 -4.2985 0.10000E+01 0.0000 74 OH- 0.68844E-02 -2.1621 0.58821E-02 -2.2305 0.85441E+00 -0.0683 79 HPO3-2 0.60449E-16 -16.2186 0.34417E-16 -16.4632 0.56936E+00 -0.2446 82 H3PO4,aq 0.66516E-17 -17.1771 0.66516E-17 -17.1771 0.10000E+01 0.0000 83 H2PO4- 0.20747E-09 -9.6830 0.17763E-09 -9.7505 0.85614E+00 -0.0675 84 PO4-3 0.28675E-08 -8.5425 0.85083E-09 -9.0702 0.29672E+00 -0.5277 88 HP2O7-3 0.17339E-16 -16.7610 0.49653E-17 -17.3041 0.28637E+00 -0.5431 89 P2O7-4 0.10730E-15 -15.9694 0.12012E-16 -16.9204 0.11195E+00 -0.9510 90 H2S,aq 0.22132E-08 -8.6550 0.22081E-08 -8.6560 0.99767E+00 -0.0010 91 S2-2 0.18291E-13 -13.7378 0.10414E-13 -13.9824 0.56936E+00 -0.2446 97 SO3-2 0.25527E-12 -12.5930 0.14689E-12 -12.8330 0.57543E+00 -0.2400 98 HSO3- 0.10246E-14 -14.9894 0.87662E-15 -15.0572 0.85555E+00 -0.0678 99 HSO4- 0.10840E-11 -11.9650 0.92941E-12 -12.0318 0.85736E+00 -0.0668 101 S2O3-2 0.44895E-15 -15.3478 0.25561E-15 -15.5924 0.56936E+00 -0.2446 Charge balance for all species = -.1484E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1186655E-09 -.1470059E-01 -.1480076E+02 0.0000 2 H2O 0.1000000E+01 0.5550751E+02 0.9988669E+06 0.0000 3 Cl- 0.1383953E-03 0.1388468E-03 0.4917033E+01 6.0649 4 SO4-- 0.1722473E-04 0.1721398E-04 0.1651755E+01 14.9752 5 HCO3- 0.5562720E-05 0.1315266E-04 0.8016415E+00 4.6695 6 HS- 0.8422423E-05 0.8451787E-05 0.2792051E+00 4.8492 7 Al+++ 0.7224954E-28 0.1290815E-04 0.3478920E+00 1.2900 8 H4SiO4 0.5947747E-03 0.8300948E-02 0.7969574E+03 -3.2256 9 Ca++ 0.7194776E-07 0.1132537E-06 0.4533910E-02 12.5937 10 Mg++ 0.2348035E-10 0.8546434E-10 0.2075487E-05 9.1060 11 Fe++ 0.8908241E-13 0.2652530E-07 0.1479703E-02 6.6854 12 K+ 0.1073725E-03 0.1077822E-03 0.4209789E+01 5.9552 13 Na+ 0.1364346E-01 0.1474904E-01 0.3386985E+03 8.0586 14 Mn++ 0.1853293E-10 0.1551019E-08 0.8511468E-04 9.0038 15 HPO4-- 0.1742041E-06 0.1772790E-06 0.1699605E-01 12.9802 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8610132E+00 -.1460821E-01 -.8464050E+00 0.0000000E+00 2 H2O 0.5485642E+02 0.5515867E+02 -.3022490E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1466574E-02 0.1710580E-04 0.1449468E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1441070E-02 0.8398672E-05 -.1449468E-02 0.0000000E+00 7 Al+++ 0.1695553E+00 0.1282703E-04 0.1695425E+00 0.0000000E+00 8 H4SiO4 0.5414543E+00 0.8248781E-02 0.5332055E+00 0.0000000E+00 9 Ca++ 0.5982074E-01 0.1125420E-06 0.5982063E-01 0.0000000E+00 10 Mg++ 0.4126905E-01 0.8492724E-10 0.4126905E-01 0.0000000E+00 11 Fe++ 0.3707573E-01 0.2635861E-07 0.3707571E-01 0.0000000E+00 12 K+ 0.1104013E-01 0.1071048E-03 0.1093302E-01 0.0000000E+00 13 Na+ 0.6543148E-01 0.1465635E-01 0.5077514E-01 0.0000000E+00 14 Mn++ 0.9015897E-03 0.1541272E-08 0.9015881E-03 0.0000000E+00 15 HPO4-- 0.3077081E-03 0.1761649E-06 0.3075319E-03 0.0000000E+00 Chg. balance for solid moles: 0.1558E-15 Mass of aqueous solution: 0.994827E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 51.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5078E-01 -1.294 13.31 1.124 23.46 5.111 andradite 0.5798E-02 -2.237 2.946 0.469 5.191 0.7655 grossular 0.5367E-03 -3.270 0.2418 -0.617 0.4259 0.6727E-01 apatite-OH 0.1025E-03 -3.989 0.5149E-01 -1.288 0.9072E-01 0.1636E-01 clinochlore 0.8254E-02 -2.083 4.588 0.662 8.083 1.745 daphnite 0.3280E-02 -2.484 2.340 0.369 4.123 0.7092 chlorite-Mn 0.1803E-03 -3.744 0.1278 -0.893 0.2252 0.4074E-01 microcline 0.1002E-01 -1.999 2.790 0.446 4.916 1.090 stilbite 0.4030E-01 -1.395 28.40 1.453 50.04 13.25 stilpnomelane-Fe 0.1816E-02 -2.741 1.958 0.292 3.449 0.6762 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9153E+00 0.9153E+00 1.0000 -0.038 grossular 0.8472E-01 0.8472E-01 1.0000 -1.072 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7046E+00 0.7046E+00 1.0000 -0.152 daphnite 0.2800E+00 0.2800E+00 1.0000 -0.553 chlorite-Mn 0.1539E-01 0.1539E-01 1.0000 -1.813 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 56.761039 g Volume = 23.469133 cm3 Porosity: -7.6585% V(tot) - V(min): -.16695E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 51.9990000 g log = 1.7160 Original solution: 1000.0103000 g Original solution / Rock added: 19.23 (Water/Rock Ratio), log = 1.2840 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9999E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1058E-06 1.0073 0.1121E-06 0.1113E-06 CH4,gas 0.5090E-08 1.0129 0.5424E-08 0.5355E-08 H2,gas 0.1429E-03 1.0006 0.1504E-03 0.1503E-03 H2S,gas 0.6146E-07 0.9959 0.6440E-07 0.6466E-07 S2,gas 0.6525E-26 1.0000 0.6864E-26 0.6864E-26 CO,gas 0.4153E-14 1.0000 0.4369E-14 0.4369E-14 SO3,gas 0.3630E-40 1.0000 0.3819E-40 0.3819E-40 SO2,gas 0.2066E-21 1.0000 0.2173E-21 0.2173E-21 HCl,gas 0.3812E-17 1.0000 0.4010E-17 0.4010E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.31 -8.95 -2.983 0.15282E+05 -6.950 3 CH4,gas 4.81 -5.46 -10.27 -2.566 0.17528E+05 -8.266 4 H2,gas 8.29 2.46 -5.82 -3.327 0.99420E+04 -3.823 5 H2S,gas -5.94 -15.13 -9.19 -4.596 0.15694E+05 -7.191 6 S2,gas -7.03 -35.20 -28.16 -4.333 0.48088E+05 -26.163 7 CO,gas 3.51 -12.85 -16.36 -5.034 0.27934E+05 -14.360 8 SO3,gas 17.43 -24.99 -42.42 -10.605 0.72428E+05 -40.418 9 SO2,gas 1.14 -22.53 -23.66 -6.310 0.40404E+05 -21.663 10 HCl,gas 5.48 -13.92 -19.40 -9.698 0.33120E+05 -17.397 11 acmite 7.74 7.06 -0.68 -0.070 0.11556E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.91 -4.64 -0.232 0.79149E+04 20 analcite 3.37 2.90 -0.47 -0.053 0.80823E+03 26 annite 20.21 17.62 -2.58 -0.144 0.44137E+04 27 phlogopite 27.15 24.89 -2.26 -0.126 0.38597E+04 29 anorthite 12.80 8.72 -4.08 -0.313 0.69585E+04 35 aragonite 0.99 -2.72 -3.71 -1.235 0.63279E+04 36 brucite 12.58 9.11 -3.47 -0.694 0.59260E+04 37 calcite 0.83 -2.72 -3.55 -1.184 0.60665E+04 38 carnegieite-low 9.06 6.12 -2.94 -0.420 0.50227E+04 39 carnegieite-high 10.13 6.12 -4.01 -0.573 0.68496E+04 40 carpholite-Mg 8.65 5.23 -3.42 -0.228 0.58323E+04 41 carpholite-Fe 6.78 2.81 -3.97 -0.265 0.67767E+04 42 celadonite 5.40 3.45 -1.95 -0.115 0.33330E+04 43 celadonite-Fe 3.94 1.03 -2.91 -0.171 0.49670E+04 44 chrysotile 23.94 20.87 -3.07 -0.256 0.52432E+04 50 chloritoid-Mg 13.26 8.46 -4.80 -0.320 0.81976E+04 51 chloritoid-Fe 9.24 6.04 -3.20 -0.213 0.54622E+04 52 chloritoid-Mn 11.46 8.36 -3.11 -0.207 0.53019E+04 54 coesite -2.37 -3.23 -0.86 -0.285 0.14621E+04 61 cristobalite -2.55 -3.23 -0.68 -0.225 0.11550E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.29 -1.61 -0.268 0.27424E+04 67 diopside 16.22 15.25 -0.97 -0.097 0.16512E+04 68 hedenbergite 14.24 12.83 -1.42 -0.142 0.24188E+04 75 epidote 24.78 23.54 -1.23 -0.060 0.21027E+04 76 clinozoisite 22.92 19.38 -3.54 -0.161 0.60457E+04 77 epidote-Fe 29.94 27.71 -2.23 -0.116 0.38072E+04 78 fayalite 14.08 10.15 -3.93 -0.562 0.67169E+04 79 ferrosilite 11.19 6.92 -4.27 -0.427 0.72878E+04 83 gibbsite 4.10 1.29 -2.81 -0.401 0.47936E+04 84 glaucophane 23.11 20.21 -2.90 -0.078 0.49528E+04 85 glaucophane-Fe 17.42 12.95 -4.47 -0.121 0.76307E+04 87 greenalite 16.19 13.60 -2.59 -0.216 0.44212E+04 90 hematite 12.60 10.91 -1.69 -0.205 0.28874E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.90 -1.35 -0.135 0.23113E+04 96 julgoldite 70.57 66.20 -4.37 -0.113 0.74580E+04 97 kalsilite 7.62 4.02 -3.60 -0.514 0.61482E+04 98 kaolinite -1.27 -3.87 -2.60 -0.236 0.44364E+04 101 laumontite 2.97 2.27 -0.70 -0.047 0.12011E+04 102 lawsonite 9.68 8.72 -0.96 -0.064 0.16323E+04 103 leucite 4.17 0.79 -3.37 -0.337 0.57606E+04 105 lizardite 23.29 20.87 -2.42 -0.202 0.41335E+04 107 magnetite 20.13 17.59 -2.54 -0.207 0.43384E+04 108 minnesotaite 10.46 7.15 -3.31 -0.195 0.56468E+04 120 muscovite 2.68 0.15 -2.53 -0.149 0.43217E+04 121 paragonite 4.34 2.25 -2.09 -0.123 0.35602E+04 122 nepheline 8.38 6.12 -2.26 -0.322 0.38507E+04 128 periclase-Fe 11.64 6.69 -4.95 -1.238 0.84584E+04 134 phlogopite-Na 29.73 26.99 -2.74 -0.152 0.46816E+04 136 prehnite 19.47 18.09 -1.38 -0.081 0.23492E+04 137 prehnite-Fe 22.59 22.25 -0.33 -0.020 0.56855E+03 138 pumpellyite-Fe 46.47 44.16 -2.31 -0.051 0.39515E+04 139 pumpellyite-Mg 49.19 46.58 -2.62 -0.058 0.44687E+04 142 pyrite -21.23 -26.05 -4.82 -1.134 0.82318E+04 143 pyrrhotite -4.24 -8.45 -4.20 -1.402 0.71796E+04 144 pyrrhotiteFe0.875 -6.00 -9.59 -3.59 -1.320 0.61275E+04 145 pyroxmangite 7.42 5.78 -1.64 -0.328 0.27966E+04 146 pyrophyllite -6.10 -10.32 -4.22 -0.264 0.72134E+04 147 quartz -2.98 -3.23 -0.24 -0.081 0.41602E+03 152 rhodonite 7.46 5.78 -1.68 -0.337 0.28758E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.28 -2.31 -0.069 0.39513E+04 171 talc 16.55 14.42 -2.14 -0.126 0.36507E+04 174 tephroite 18.11 14.78 -3.33 -0.476 0.56874E+04 178 tridymite -2.61 -3.23 -0.61 -0.204 0.10433E+04 179 tremolite 48.00 44.91 -3.09 -0.084 0.52779E+04 181 troilite-low -4.39 -8.45 -4.05 -1.351 0.69228E+04 187 wairakite 4.06 2.27 -1.79 -0.105 0.30519E+04 188 walstromite 11.53 9.37 -2.16 -0.432 0.36878E+04 189 wollastonite 10.48 9.37 -1.11 -0.223 0.19017E+04 190 pseudo-wollastonite 11.02 9.37 -1.65 -0.330 0.28203E+04 191 zoisite 22.96 19.38 -3.58 -0.163 0.61182E+04 192 akaganeite 7.77 5.45 -2.31 -0.500 0.39519E+04 197 beidellite-Na -1.26 -6.17 -4.92 -0.301 0.83942E+04 199 chalcedony -2.79 -3.23 -0.43 -0.144 0.73634E+03 201 montmorillonite-Ca -2.21 -5.67 -3.45 -0.214 0.58931E+04 202 montmorillonite-K -2.16 -5.78 -3.62 -0.222 0.61763E+04 203 montmorillonite-Mg -2.40 -6.24 -3.84 -0.238 0.65554E+04 204 montmorillonite-Na -1.96 -5.08 -3.12 -0.191 0.53331E+04 205 nontronite-Ca 3.28 1.57 -1.71 -0.111 0.29156E+04 206 nontronite-H 2.60 -0.51 -3.10 -0.208 0.52959E+04 207 nontronite-K 3.40 1.46 -1.94 -0.125 0.33201E+04 208 nontronite-Mg 3.14 1.00 -2.14 -0.139 0.36585E+04 209 nontronite-Na 3.58 2.15 -1.43 -0.092 0.24406E+04 224 tobermorite 9.84 7.26 -2.57 -0.702 0.43951E+04 233 boehmite 4.43 1.29 -3.14 -0.523 0.53608E+04 235 ferrous-oxide 9.82 6.69 -3.14 -0.785 0.53594E+04 240 silica-amorphous -2.08 -3.23 -1.15 -0.382 0.19565E+04 242 an20ab80 2.08 1.48 -0.60 -0.046 0.10201E+04 243 an25ab75 2.71 1.93 -0.77 -0.060 0.13230E+04 244 an30ab70 3.34 2.39 -0.96 -0.074 0.16343E+04 245 tr.625ac.25prg.125 45.31 43.05 -2.26 -0.061 0.38631E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 51.9990000 g New total amount of reactant added: 53.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1494E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 53.9990000 Water: Moles liquid = 0.5515E+02 kg liquid = 0.9935E+00 Moles total = 0.5483E+02 kg total = 0.9878E+00 Activity = 1.0000 Stoichiometric ionic strength = .7745732E-02 Osmotic coef. = 0.9600 True ionic strength = .1403346E-01 Chg. balance for total moles = -.1494E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11711E-09 -9.9314 0.10053E-09 -9.9977 0.85848E+00 -0.0663 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13842E-03 -3.8588 0.11829E-03 -3.9270 0.85461E+00 -0.0682 4 SO4-- 0.12092E-04 -4.9175 0.68662E-05 -5.1633 0.56783E+00 -0.2458 5 HCO3- 0.55080E-05 -5.2590 0.47123E-05 -5.3268 0.85554E+00 -0.0678 6 HS- 0.13564E-04 -4.8676 0.11593E-04 -4.9358 0.85470E+00 -0.0682 7 Al+++ 0.65968E-28 -28.1807 0.18695E-28 -28.7283 0.28340E+00 -0.5476 8 H4SiO4 0.59993E-03 -3.2219 0.59993E-03 -3.2219 0.10000E+01 0.0000 9 Ca++ 0.74238E-07 -7.1294 0.41924E-07 -7.3775 0.56472E+00 -0.2482 10 Mg++ 0.23444E-10 -10.6300 0.13194E-10 -10.8796 0.56279E+00 -0.2497 11 Fe++ 0.87497E-13 -13.0580 0.49283E-13 -13.3073 0.56325E+00 -0.2493 12 K+ 0.10942E-03 -3.9609 0.93630E-04 -4.0286 0.85570E+00 -0.0677 13 Na+ 0.13904E-01 -1.8569 0.11881E-01 -1.9252 0.85450E+00 -0.0683 14 Mn++ 0.18504E-10 -10.7327 0.10429E-10 -10.9818 0.56360E+00 -0.2490 15 HPO4-- 0.16410E-06 -6.7849 0.93193E-07 -7.0306 0.56789E+00 -0.2457 16 HSiO3- 0.68128E-02 -2.1667 0.58223E-02 -2.2349 0.85461E+00 -0.0682 17 Ca(HSiO3)+ 0.63902E-08 -8.1945 0.54689E-08 -8.2621 0.85583E+00 -0.0676 18 Mg(HSiO3)+ 0.25028E-11 -11.6016 0.21420E-11 -11.6692 0.85583E+00 -0.0676 19 NaHSiO3,aq 0.10986E-02 -2.9591 0.10986E-02 -2.9591 0.10000E+01 0.0000 20 AlO+ 0.27902E-15 -15.5544 0.23879E-15 -15.6220 0.85583E+00 -0.0676 22 HAlO2,aq 0.47532E-09 -9.3230 0.47532E-09 -9.3230 0.10000E+01 0.0000 23 AlO2- 0.12370E-04 -4.9076 0.10557E-04 -4.9765 0.85346E+00 -0.0688 24 CH4,aq 0.78261E-11 -11.1065 0.78075E-11 -11.1075 0.99762E+00 -0.0010 29 CO,aq 0.33351E-17 -17.4769 0.33351E-17 -17.4769 0.10000E+01 0.0000 30 CO2,aq 0.95743E-09 -9.0189 0.95516E-09 -9.0199 0.99762E+00 -0.0010 31 CO3-2 0.76445E-05 -5.1167 0.43338E-05 -5.3631 0.56693E+00 -0.2465 32 CaCO3,aq 0.22253E-08 -8.6526 0.22253E-08 -8.6526 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.58164E-11 -11.2353 0.49779E-11 -11.3030 0.85583E+00 -0.0676 34 CaCl+ 0.92339E-11 -11.0346 0.79027E-11 -11.1022 0.85583E+00 -0.0676 35 CaCl2,aq 0.21767E-15 -15.6622 0.21767E-15 -15.6622 0.10000E+01 0.0000 36 CaOH+ 0.34358E-07 -7.4640 0.29405E-07 -7.5316 0.85583E+00 -0.0676 37 CaSO4,aq 0.89690E-10 -10.0473 0.89690E-10 -10.0473 0.10000E+01 0.0000 38 HCl,aq 0.22369E-14 -14.6503 0.22369E-14 -14.6503 0.10000E+01 0.0000 43 FeCl+ 0.10610E-16 -16.9743 0.90802E-17 -17.0419 0.85583E+00 -0.0676 46 FeO,aq 0.19282E-09 -9.7148 0.19282E-09 -9.7148 0.10000E+01 0.0000 47 FeOH+ 0.18990E-10 -10.7215 0.16252E-10 -10.7891 0.85583E+00 -0.0676 48 HFeO2- 0.24140E-07 -7.6173 0.20630E-07 -7.6855 0.85461E+00 -0.0682 49 FeO+ 0.12551E-15 -15.9013 0.10741E-15 -15.9689 0.85583E+00 -0.0676 51 FeO2- 0.24441E-08 -8.6119 0.20888E-08 -8.6801 0.85461E+00 -0.0682 52 HFeO2,aq 0.26280E-10 -10.5804 0.26280E-10 -10.5804 0.10000E+01 0.0000 53 H2,aq 0.13589E-06 -6.8668 0.13557E-06 -6.8678 0.99762E+00 -0.0010 54 KCl,aq 0.19612E-09 -9.7075 0.19612E-09 -9.7075 0.10000E+01 0.0000 55 KHSO4,aq 0.17295E-18 -18.7621 0.17295E-18 -18.7621 0.10000E+01 0.0000 56 KOH,aq 0.40601E-06 -6.3915 0.40601E-06 -6.3915 0.10000E+01 0.0000 57 KSO4- 0.11589E-07 -7.9359 0.99045E-08 -8.0042 0.85461E+00 -0.0682 58 MgCO3,aq 0.17500E-12 -12.7570 0.17500E-12 -12.7570 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18666E-14 -14.7289 0.15975E-14 -14.7965 0.85583E+00 -0.0676 60 MgCl+ 0.26382E-14 -14.5787 0.22579E-14 -14.6463 0.85583E+00 -0.0676 61 MgOH+ 0.59905E-10 -10.2225 0.51269E-10 -10.2901 0.85583E+00 -0.0676 63 MnO,aq 0.10893E-08 -8.9629 0.10893E-08 -8.9629 0.10000E+01 0.0000 64 MnOH+ 0.37330E-09 -9.4279 0.31948E-09 -9.4956 0.85583E+00 -0.0676 65 MnO2-2 0.65744E-11 -11.1821 0.37272E-11 -11.4286 0.56693E+00 -0.2465 66 HMnO2- 0.94996E-10 -10.0223 0.81185E-10 -10.0905 0.85461E+00 -0.0682 69 MnCl+ 0.87242E-14 -14.0593 0.74665E-14 -14.1269 0.85583E+00 -0.0676 70 MnSO4,aq 0.20293E-13 -13.6926 0.20293E-13 -13.6926 0.10000E+01 0.0000 71 NaCl,aq 0.45891E-06 -6.3383 0.45891E-06 -6.3383 0.10000E+01 0.0000 72 NaOH,aq 0.51928E-04 -4.2846 0.51928E-04 -4.2846 0.10000E+01 0.0000 74 OH- 0.69910E-02 -2.1555 0.59665E-02 -2.2243 0.85346E+00 -0.0688 79 HPO3-2 0.70389E-16 -16.1525 0.39906E-16 -16.3990 0.56693E+00 -0.2465 82 H3PO4,aq 0.60639E-17 -17.2172 0.60639E-17 -17.2172 0.10000E+01 0.0000 83 H2PO4- 0.19207E-09 -9.7165 0.16426E-09 -9.7845 0.85521E+00 -0.0679 84 PO4-3 0.27536E-08 -8.5601 0.80955E-09 -9.0918 0.29400E+00 -0.5317 88 HP2O7-3 0.15187E-16 -16.8185 0.43070E-17 -17.3658 0.28359E+00 -0.5473 89 P2O7-4 0.96030E-16 -16.0176 0.10569E-16 -16.9760 0.11006E+00 -0.9584 90 H2S,aq 0.35103E-08 -8.4547 0.35019E-08 -8.4557 0.99762E+00 -0.0010 91 S2-2 0.38462E-13 -13.4150 0.21805E-13 -13.6614 0.56693E+00 -0.2465 97 SO3-2 0.22148E-12 -12.6547 0.12692E-12 -12.8965 0.57306E+00 -0.2418 98 HSO3- 0.87375E-15 -15.0586 0.74672E-15 -15.1268 0.85461E+00 -0.0682 99 HSO4- 0.74783E-12 -12.1262 0.64048E-12 -12.1935 0.85645E+00 -0.0673 101 S2O3-2 0.49986E-15 -15.3012 0.28338E-15 -15.5476 0.56693E+00 -0.2465 Charge balance for all species = -.1510E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1171063E-09 -.1501202E-01 -.1511393E+02 0.0000 2 H2O 0.1000000E+01 0.5550741E+02 0.9988403E+06 0.0000 3 Cl- 0.1384188E-03 0.1388780E-03 0.4918016E+01 6.0707 4 SO4-- 0.1209200E-04 0.1207001E-04 0.1158140E+01 14.8321 5 HCO3- 0.5507959E-05 0.1315561E-04 0.8018017E+00 4.6709 6 HS- 0.1356434E-04 0.1360152E-04 0.4493157E+00 5.0619 7 Al+++ 0.6596760E-28 0.1237013E-04 0.3333834E+00 1.2648 8 H4SiO4 0.5999282E-03 0.8511327E-02 0.8171351E+03 -3.2219 9 Ca++ 0.7423820E-07 0.1173167E-06 0.4696447E-02 12.6178 10 Mg++ 0.2344416E-10 0.8603194E-10 0.2089219E-05 9.1158 11 Fe++ 0.8749741E-13 0.2682214E-07 0.1496225E-02 6.6881 12 K+ 0.1094195E-03 0.1098373E-03 0.4289953E+01 5.9691 13 Na+ 0.1390386E-01 0.1505489E-01 0.3457136E+03 8.0725 14 Mn++ 0.1850396E-10 0.1582662E-08 0.8684897E-04 9.0136 15 HPO4-- 0.1641048E-06 0.1670504E-06 0.1601502E-01 12.9648 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8941302E+00 -.1491433E-01 -.8792159E+00 0.0000000E+00 2 H2O 0.5483135E+02 0.5514618E+02 -.3148329E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1522001E-02 0.1199146E-04 0.1510009E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1496496E-02 0.1351301E-04 -.1510009E-02 0.0000000E+00 7 Al+++ 0.1760768E+00 0.1228963E-04 0.1760645E+00 0.0000000E+00 8 H4SiO4 0.5622799E+00 0.8455938E-02 0.5538239E+00 0.0000000E+00 9 Ca++ 0.6212102E-01 0.1165532E-06 0.6212091E-01 0.0000000E+00 10 Mg++ 0.4285635E-01 0.8547207E-10 0.4285635E-01 0.0000000E+00 11 Fe++ 0.3850175E-01 0.2664760E-07 0.3850172E-01 0.0000000E+00 12 K+ 0.1146476E-01 0.1091225E-03 0.1135563E-01 0.0000000E+00 13 Na+ 0.6794197E-01 0.1495692E-01 0.5298505E-01 0.0000000E+00 14 Mn++ 0.9362668E-03 0.1572363E-08 0.9362653E-03 0.0000000E+00 15 HPO4-- 0.3195432E-03 0.1659633E-06 0.3193773E-03 0.0000000E+00 Chg. balance for solid moles: -.7676E-16 Mass of aqueous solution: 0.994629E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 53.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5299E-01 -1.276 13.89 1.143 23.57 5.333 andradite 0.6040E-02 -2.219 3.069 0.487 5.207 0.7975 grossular 0.5830E-03 -3.234 0.2626 -0.581 0.4455 0.7307E-01 apatite-OH 0.1065E-03 -3.973 0.5348E-01 -1.272 0.9072E-01 0.1699E-01 clinochlore 0.8571E-02 -2.067 4.764 0.678 8.083 1.812 daphnite 0.3351E-02 -2.475 2.391 0.379 4.056 0.7245 chlorite-Mn 0.1873E-03 -3.728 0.1328 -0.877 0.2252 0.4231E-01 microcline 0.1039E-01 -1.983 2.892 0.461 4.906 1.130 stilbite 0.4172E-01 -1.380 29.40 1.468 49.88 13.71 stilpnomelane-Fe 0.1934E-02 -2.714 2.084 0.319 3.536 0.7200 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9120E+00 0.9120E+00 1.0000 -0.040 grossular 0.8803E-01 0.8803E-01 1.0000 -1.055 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7078E+00 0.7078E+00 1.0000 -0.150 daphnite 0.2767E+00 0.2767E+00 1.0000 -0.558 chlorite-Mn 0.1546E-01 0.1546E-01 1.0000 -1.811 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 58.943551 g Volume = 24.362448 cm3 Porosity: -7.8003% V(tot) - V(min): -.17628E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 53.9990000 g log = 1.7324 Original solution: 1000.0103000 g Original solution / Rock added: 18.52 (Water/Rock Ratio), log = 1.2676 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0521 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9998E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1032E-06 1.0073 0.1093E-06 0.1085E-06 CH4,gas 0.1159E-07 1.0129 0.1235E-07 0.1219E-07 H2,gas 0.1766E-03 1.0006 0.1859E-03 0.1858E-03 H2S,gas 0.9747E-07 0.9959 0.1021E-06 0.1026E-06 S2,gas 0.1074E-25 1.0000 0.1130E-25 0.1130E-25 CO,gas 0.5005E-14 1.0000 0.5266E-14 0.5266E-14 SO3,gas 0.2466E-40 1.0000 0.2594E-40 0.2594E-40 SO2,gas 0.1735E-21 1.0000 0.1825E-21 0.1825E-21 HCl,gas 0.3754E-17 1.0000 0.3950E-17 0.3950E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.32 -8.96 -2.987 0.15301E+05 -6.961 3 CH4,gas 4.81 -5.10 -9.91 -2.477 0.16918E+05 -7.908 4 H2,gas 8.29 2.56 -5.73 -3.275 0.97849E+04 -3.731 5 H2S,gas -5.94 -14.93 -8.99 -4.495 0.15352E+05 -6.991 6 S2,gas -7.03 -34.98 -27.95 -4.300 0.47719E+05 -25.947 7 CO,gas 3.51 -12.77 -16.28 -5.009 0.27795E+05 -14.279 8 SO3,gas 17.43 -25.16 -42.59 -10.646 0.72714E+05 -40.586 9 SO2,gas 1.14 -22.60 -23.74 -6.330 0.40533E+05 -21.739 10 HCl,gas 5.48 -13.92 -19.40 -9.702 0.33131E+05 -17.403 11 acmite 7.74 7.04 -0.70 -0.073 0.11930E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.90 -4.65 -0.232 0.79315E+04 20 analcite 3.37 2.89 -0.48 -0.053 0.81463E+03 26 annite 20.21 17.63 -2.58 -0.143 0.44000E+04 27 phlogopite 27.15 24.92 -2.23 -0.124 0.38095E+04 29 anorthite 12.80 8.70 -4.09 -0.315 0.69904E+04 35 aragonite 0.99 -2.71 -3.69 -1.231 0.63054E+04 36 brucite 12.58 9.12 -3.46 -0.692 0.59093E+04 37 calcite 0.83 -2.71 -3.54 -1.180 0.60441E+04 38 carnegieite-low 9.06 6.12 -2.95 -0.421 0.50355E+04 39 carnegieite-high 10.13 6.12 -4.02 -0.574 0.68624E+04 40 carpholite-Mg 8.65 5.20 -3.45 -0.230 0.58887E+04 41 carpholite-Fe 6.78 2.77 -4.01 -0.267 0.68453E+04 42 celadonite 5.40 3.46 -1.94 -0.114 0.33098E+04 43 celadonite-Fe 3.94 1.03 -2.90 -0.171 0.49560E+04 44 chrysotile 23.94 20.90 -3.03 -0.253 0.51802E+04 50 chloritoid-Mg 13.26 8.42 -4.84 -0.323 0.82604E+04 51 chloritoid-Fe 9.24 6.00 -3.24 -0.216 0.55371E+04 52 chloritoid-Mn 11.46 8.32 -3.14 -0.209 0.53647E+04 54 coesite -2.37 -3.22 -0.85 -0.284 0.14557E+04 61 cristobalite -2.55 -3.22 -0.67 -0.224 0.11486E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.26 -1.63 -0.272 0.27854E+04 67 diopside 16.22 15.29 -0.93 -0.093 0.15805E+04 68 hedenbergite 14.24 12.86 -1.38 -0.138 0.23602E+04 75 epidote 24.78 23.51 -1.27 -0.061 0.21611E+04 76 clinozoisite 22.92 19.36 -3.56 -0.162 0.60731E+04 77 epidote-Fe 29.94 27.65 -2.28 -0.119 0.38966E+04 78 fayalite 14.08 10.15 -3.92 -0.561 0.67013E+04 79 ferrosilite 11.19 6.93 -4.26 -0.426 0.72659E+04 83 gibbsite 4.10 1.26 -2.83 -0.405 0.48366E+04 84 glaucophane 23.11 20.25 -2.86 -0.077 0.48898E+04 85 glaucophane-Fe 17.42 12.96 -4.45 -0.120 0.76042E+04 87 greenalite 16.19 13.62 -2.57 -0.214 0.43946E+04 90 hematite 12.60 10.82 -1.78 -0.215 0.30354E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.89 -1.36 -0.136 0.23177E+04 96 julgoldite 70.57 66.16 -4.42 -0.115 0.75419E+04 97 kalsilite 7.62 4.01 -3.61 -0.515 0.61610E+04 98 kaolinite -1.27 -3.91 -2.64 -0.240 0.45095E+04 101 laumontite 2.97 2.26 -0.71 -0.048 0.12203E+04 102 lawsonite 9.68 8.70 -0.97 -0.065 0.16643E+04 103 leucite 4.17 0.79 -3.38 -0.338 0.57670E+04 105 lizardite 23.29 20.90 -2.38 -0.199 0.40705E+04 107 magnetite 20.13 17.51 -2.62 -0.214 0.44818E+04 108 minnesotaite 10.46 7.18 -3.28 -0.193 0.56075E+04 120 muscovite 2.68 0.10 -2.58 -0.152 0.44076E+04 121 paragonite 4.34 2.20 -2.14 -0.126 0.36461E+04 122 nepheline 8.38 6.12 -2.26 -0.323 0.38635E+04 128 periclase-Fe 11.64 6.69 -4.95 -1.238 0.84538E+04 134 phlogopite-Na 29.73 27.02 -2.71 -0.151 0.46314E+04 136 prehnite 19.47 18.10 -1.37 -0.080 0.23337E+04 137 prehnite-Fe 22.59 22.24 -0.34 -0.021 0.58402E+03 138 pumpellyite-Fe 46.47 44.15 -2.32 -0.052 0.39588E+04 139 pumpellyite-Mg 49.19 46.58 -2.61 -0.058 0.44638E+04 142 pyrite -21.23 -25.74 -4.51 -1.061 0.77004E+04 143 pyrrhotite -4.24 -8.25 -4.00 -1.334 0.68330E+04 144 pyrrhotiteFe0.875 -6.00 -9.40 -3.40 -1.250 0.58010E+04 145 pyroxmangite 7.42 5.79 -1.62 -0.325 0.27735E+04 146 pyrophyllite -6.10 -10.36 -4.26 -0.266 0.72738E+04 147 quartz -2.98 -3.22 -0.24 -0.080 0.40963E+03 152 rhodonite 7.46 5.79 -1.67 -0.334 0.28527E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.32 -2.28 -0.068 0.38905E+04 171 talc 16.55 14.46 -2.09 -0.123 0.35749E+04 174 tephroite 18.11 14.81 -3.31 -0.473 0.56476E+04 178 tridymite -2.61 -3.22 -0.61 -0.202 0.10369E+04 179 tremolite 48.00 45.04 -2.96 -0.080 0.50607E+04 181 troilite-low -4.39 -8.25 -3.85 -1.284 0.65762E+04 187 wairakite 4.06 2.26 -1.80 -0.106 0.30711E+04 188 walstromite 11.53 9.40 -2.13 -0.426 0.36402E+04 189 wollastonite 10.48 9.40 -1.09 -0.217 0.18541E+04 190 pseudo-wollastonite 11.02 9.40 -1.62 -0.325 0.27727E+04 191 zoisite 22.96 19.36 -3.60 -0.164 0.61456E+04 192 akaganeite 7.77 5.41 -2.36 -0.510 0.40259E+04 197 beidellite-Na -1.26 -6.21 -4.96 -0.304 0.84630E+04 199 chalcedony -2.79 -3.22 -0.43 -0.142 0.72994E+03 201 montmorillonite-Ca -2.21 -5.69 -3.47 -0.215 0.59270E+04 202 montmorillonite-K -2.16 -5.80 -3.64 -0.223 0.62091E+04 203 montmorillonite-Mg -2.40 -6.26 -3.86 -0.239 0.65933E+04 204 montmorillonite-Na -1.96 -5.10 -3.14 -0.192 0.53659E+04 205 nontronite-Ca 3.28 1.49 -1.78 -0.116 0.30475E+04 206 nontronite-H 2.60 -0.59 -3.18 -0.213 0.54346E+04 207 nontronite-K 3.40 1.38 -2.02 -0.130 0.34510E+04 208 nontronite-Mg 3.14 0.92 -2.22 -0.144 0.37945E+04 209 nontronite-Na 3.58 2.08 -1.51 -0.097 0.25714E+04 224 tobermorite 9.84 7.29 -2.55 -0.696 0.43545E+04 230 alabandite -0.96 -5.92 -4.96 -1.652 0.84647E+04 233 boehmite 4.43 1.26 -3.16 -0.527 0.54038E+04 235 ferrous-oxide 9.82 6.69 -3.14 -0.784 0.53549E+04 240 silica-amorphous -2.08 -3.22 -1.14 -0.381 0.19501E+04 242 an20ab80 2.08 1.48 -0.60 -0.046 0.10265E+04 243 an25ab75 2.71 1.93 -0.78 -0.060 0.13310E+04 244 an30ab70 3.34 2.38 -0.96 -0.074 0.16439E+04 245 tr.625ac.25prg.125 45.31 43.15 -2.15 -0.058 0.36780E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 53.9990000 g New total amount of reactant added: 55.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1493E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 55.9990000 Water: Moles liquid = 0.5513E+02 kg liquid = 0.9933E+00 Moles total = 0.5481E+02 kg total = 0.9874E+00 Activity = 1.0000 Stoichiometric ionic strength = .7890123E-02 Osmotic coef. = 0.9621 True ionic strength = .1429022E-01 Chg. balance for total moles = -.1493E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11561E-09 -9.9370 0.99152E-10 -10.0037 0.85761E+00 -0.0667 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13844E-03 -3.8587 0.11819E-03 -3.9274 0.85369E+00 -0.0687 4 SO4-- 0.72904E-05 -5.1372 0.41224E-05 -5.3849 0.56545E+00 -0.2476 5 HCO3- 0.54548E-05 -5.2632 0.46619E-05 -5.3314 0.85463E+00 -0.0682 6 HS- 0.18375E-04 -4.7358 0.15688E-04 -4.8044 0.85378E+00 -0.0687 7 Al+++ 0.60368E-28 -28.2192 0.16945E-28 -28.7710 0.28069E+00 -0.5518 8 H4SiO4 0.60507E-03 -3.2182 0.60507E-03 -3.2182 0.10000E+01 0.0000 9 Ca++ 0.76543E-07 -7.1161 0.43041E-07 -7.3661 0.56231E+00 -0.2500 10 Mg++ 0.23414E-10 -10.6305 0.13120E-10 -10.8821 0.56036E+00 -0.2515 11 Fe++ 0.85990E-13 -13.0656 0.48225E-13 -13.3167 0.56082E+00 -0.2512 12 K+ 0.11146E-03 -3.9529 0.95274E-04 -4.0210 0.85479E+00 -0.0681 13 Na+ 0.14163E-01 -1.8488 0.12089E-01 -1.9176 0.85358E+00 -0.0688 14 Mn++ 0.18480E-10 -10.7333 0.10370E-10 -10.9842 0.56117E+00 -0.2509 15 HPO4-- 0.15485E-06 -6.8101 0.87569E-07 -7.0577 0.56551E+00 -0.2476 16 HSiO3- 0.69743E-02 -2.1565 0.59539E-02 -2.2252 0.85369E+00 -0.0687 17 Ca(HSiO3)+ 0.67158E-08 -8.1729 0.57416E-08 -8.2410 0.85493E+00 -0.0681 18 Mg(HSiO3)+ 0.25478E-11 -11.5938 0.21782E-11 -11.6619 0.85493E+00 -0.0681 19 NaHSiO3,aq 0.11432E-02 -2.9419 0.11432E-02 -2.9419 0.10000E+01 0.0000 20 AlO+ 0.26026E-15 -15.5846 0.22251E-15 -15.6527 0.85493E+00 -0.0681 22 HAlO2,aq 0.44906E-09 -9.3477 0.44906E-09 -9.3477 0.10000E+01 0.0000 23 AlO2- 0.11862E-04 -4.9258 0.10113E-04 -4.9951 0.85252E+00 -0.0693 24 CH4,aq 0.17451E-10 -10.7582 0.17409E-10 -10.7592 0.99758E+00 -0.0011 29 CO,aq 0.40009E-17 -17.3978 0.40009E-17 -17.3978 0.10000E+01 0.0000 30 CO2,aq 0.93422E-09 -9.0296 0.93196E-09 -9.0306 0.99758E+00 -0.0011 31 CO3-2 0.77005E-05 -5.1135 0.43472E-05 -5.3618 0.56453E+00 -0.2483 32 CaCO3,aq 0.22916E-08 -8.6399 0.22916E-08 -8.6399 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.59137E-11 -11.2281 0.50558E-11 -11.2962 0.85493E+00 -0.0681 34 CaCl+ 0.94813E-11 -11.0231 0.81058E-11 -11.0912 0.85493E+00 -0.0681 35 CaCl2,aq 0.22306E-15 -15.6516 0.22306E-15 -15.6516 0.10000E+01 0.0000 36 CaOH+ 0.35803E-07 -7.4461 0.30609E-07 -7.5142 0.85493E+00 -0.0681 37 CaSO4,aq 0.55283E-10 -10.2574 0.55283E-10 -10.2574 0.10000E+01 0.0000 38 HCl,aq 0.22042E-14 -14.6567 0.22042E-14 -14.6567 0.10000E+01 0.0000 43 FeCl+ 0.10383E-16 -16.9837 0.88771E-17 -17.0517 0.85493E+00 -0.0681 46 FeO,aq 0.19398E-09 -9.7122 0.19398E-09 -9.7122 0.10000E+01 0.0000 47 FeOH+ 0.18861E-10 -10.7244 0.16124E-10 -10.7925 0.85493E+00 -0.0681 48 HFeO2- 0.24649E-07 -7.6082 0.21043E-07 -7.6769 0.85369E+00 -0.0687 49 FeO+ 0.11242E-15 -15.9492 0.96110E-16 -16.0172 0.85493E+00 -0.0681 51 FeO2- 0.22507E-08 -8.6477 0.19214E-08 -8.7164 0.85369E+00 -0.0687 52 HFeO2,aq 0.23843E-10 -10.6226 0.23843E-10 -10.6226 0.10000E+01 0.0000 53 H2,aq 0.16709E-06 -6.7771 0.16668E-06 -6.7781 0.99758E+00 -0.0011 54 KCl,aq 0.19938E-09 -9.7003 0.19938E-09 -9.7003 0.10000E+01 0.0000 55 KHSO4,aq 0.10421E-18 -18.9821 0.10421E-18 -18.9821 0.10000E+01 0.0000 56 KOH,aq 0.41890E-06 -6.3779 0.41890E-06 -6.3779 0.10000E+01 0.0000 57 KSO4- 0.70880E-08 -8.1495 0.60509E-08 -8.2182 0.85369E+00 -0.0687 58 MgCO3,aq 0.17455E-12 -12.7581 0.17455E-12 -12.7581 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18382E-14 -14.7356 0.15716E-14 -14.8037 0.85493E+00 -0.0681 60 MgCl+ 0.26238E-14 -14.5811 0.22431E-14 -14.6491 0.85493E+00 -0.0681 61 MgOH+ 0.60463E-10 -10.2185 0.51691E-10 -10.2866 0.85493E+00 -0.0681 63 MnO,aq 0.11135E-08 -8.9533 0.11135E-08 -8.9533 0.10000E+01 0.0000 64 MnOH+ 0.37677E-09 -9.4239 0.32211E-09 -9.4920 0.85493E+00 -0.0681 65 MnO2-2 0.69386E-11 -11.1587 0.39171E-11 -11.4070 0.56453E+00 -0.2483 66 HMnO2- 0.98571E-10 -10.0062 0.84149E-10 -10.0749 0.85369E+00 -0.0687 69 MnCl+ 0.86765E-14 -14.0617 0.74178E-14 -14.1297 0.85493E+00 -0.0681 70 MnSO4,aq 0.12115E-13 -13.9167 0.12115E-13 -13.9167 0.10000E+01 0.0000 71 NaCl,aq 0.46654E-06 -6.3311 0.46654E-06 -6.3311 0.10000E+01 0.0000 72 NaOH,aq 0.53576E-04 -4.2710 0.53576E-04 -4.2710 0.10000E+01 0.0000 74 OH- 0.70962E-02 -2.1490 0.60496E-02 -2.2183 0.85252E+00 -0.0693 79 HPO3-2 0.81666E-16 -16.0880 0.46103E-16 -16.3363 0.56453E+00 -0.2483 81 H2PO3- 0.10518E-19 -19.9780 0.89794E-20 -20.0468 0.85369E+00 -0.0687 82 H3PO4,aq 0.55425E-17 -17.2563 0.55425E-17 -17.2563 0.10000E+01 0.0000 83 H2PO4- 0.17819E-09 -9.7491 0.15222E-09 -9.8175 0.85430E+00 -0.0684 84 PO4-3 0.26473E-08 -8.5772 0.77129E-09 -9.1128 0.29135E+00 -0.5356 88 HP2O7-3 0.13353E-16 -16.8744 0.37506E-17 -17.4259 0.28088E+00 -0.5515 89 P2O7-4 0.86221E-16 -16.0644 0.93318E-17 -17.0300 0.10823E+00 -0.9656 90 H2S,aq 0.46850E-08 -8.3293 0.46737E-08 -8.3303 0.99758E+00 -0.0011 91 S2-2 0.57526E-13 -13.2401 0.32475E-13 -13.4884 0.56453E+00 -0.2483 97 SO3-2 0.16416E-12 -12.7847 0.93690E-13 -13.0283 0.57073E+00 -0.2436 98 HSO3- 0.63682E-15 -15.1960 0.54364E-15 -15.2647 0.85369E+00 -0.0687 99 HSO4- 0.44329E-12 -12.3533 0.37925E-12 -12.4211 0.85555E+00 -0.0678 101 S2O3-2 0.40222E-15 -15.3955 0.22707E-15 -15.6438 0.56453E+00 -0.2483 Charge balance for all species = -.1538E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1156148E-09 -.1532304E-01 -.1542668E+02 0.0000 2 H2O 0.1000000E+01 0.5550731E+02 0.9988136E+06 0.0000 3 Cl- 0.1384424E-03 0.1389091E-03 0.4918997E+01 6.0763 4 SO4-- 0.7290444E-05 0.7256083E-05 0.6962173E+00 14.6225 5 HCO3- 0.5454826E-05 0.1315857E-04 0.8019617E+00 4.6723 6 HS- 0.1837502E-04 0.1842121E-04 0.6085153E+00 5.1993 7 Al+++ 0.6036794E-28 0.1186269E-04 0.3196996E+00 1.2401 8 H4SiO4 0.6050655E-03 0.8722607E-02 0.8373983E+03 -3.2182 9 Ca++ 0.7654306E-07 0.1214238E-06 0.4860741E-02 12.6413 10 Mg++ 0.2341391E-10 0.8660344E-10 0.2103045E-05 9.1253 11 Fe++ 0.8599021E-13 0.2713651E-07 0.1513724E-02 6.6907 12 K+ 0.1114591E-03 0.1118853E-03 0.4369832E+01 5.9827 13 Na+ 0.1416333E-01 0.1536058E-01 0.3527246E+03 8.0861 14 Mn++ 0.1847968E-10 0.1614308E-08 0.8858334E-04 9.0232 15 HPO4-- 0.1548499E-06 0.1576754E-06 0.1511586E-01 12.9497 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9272473E+00 -.1521991E-01 -.9120274E+00 0.0000000E+00 2 H2O 0.5480628E+02 0.5513370E+02 -.3274216E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1577428E-02 0.7207244E-05 0.1570220E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1551923E-02 0.1829723E-04 -.1570220E-02 0.0000000E+00 7 Al+++ 0.1825983E+00 0.1178284E-04 0.1825865E+00 0.0000000E+00 8 H4SiO4 0.5831054E+00 0.8663898E-02 0.5744415E+00 0.0000000E+00 9 Ca++ 0.6442131E-01 0.1206065E-06 0.6442119E-01 0.0000000E+00 10 Mg++ 0.4444365E-01 0.8602053E-10 0.4444365E-01 0.0000000E+00 11 Fe++ 0.3992777E-01 0.2695386E-07 0.3992774E-01 0.0000000E+00 12 K+ 0.1188938E-01 0.1111322E-03 0.1177825E-01 0.0000000E+00 13 Na+ 0.7045246E-01 0.1525720E-01 0.5519526E-01 0.0000000E+00 14 Mn++ 0.9709440E-03 0.1603443E-08 0.9709424E-03 0.0000000E+00 15 HPO4-- 0.3313784E-03 0.1566141E-06 0.3312218E-03 0.0000000E+00 Chg. balance for solid moles: 0.1052E-15 Mass of aqueous solution: 0.994430E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 55.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5520E-01 -1.258 14.47 1.161 23.68 5.556 andradite 0.6281E-02 -2.202 3.192 0.504 5.222 0.8293 grossular 0.6313E-03 -3.200 0.2844 -0.546 0.4652 0.7913E-01 apatite-OH 0.1104E-03 -3.957 0.5546E-01 -1.256 0.9073E-01 0.1762E-01 clinochlore 0.8889E-02 -2.051 4.941 0.694 8.083 1.879 daphnite 0.3419E-02 -2.466 2.440 0.387 3.991 0.7393 chlorite-Mn 0.1942E-03 -3.712 0.1377 -0.861 0.2252 0.4387E-01 microcline 0.1075E-01 -1.969 2.993 0.476 4.896 1.169 stilbite 0.4313E-01 -1.365 30.40 1.483 49.73 14.18 stilpnomelane-Fe 0.2054E-02 -2.687 2.214 0.345 3.622 0.7648 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9087E+00 0.9087E+00 1.0000 -0.042 grossular 0.9134E-01 0.9134E-01 1.0000 -1.039 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7110E+00 0.7110E+00 1.0000 -0.148 daphnite 0.2735E+00 0.2735E+00 1.0000 -0.563 chlorite-Mn 0.1553E-01 0.1553E-01 1.0000 -1.809 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 61.125884 g Volume = 25.255571 cm3 Porosity: -7.9316% V(tot) - V(min): -.18560E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 55.9990000 g log = 1.7482 Original solution: 1000.0103000 g Original solution / Rock added: 17.86 (Water/Rock Ratio), log = 1.2518 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0522 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9998E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.1007E-06 1.0073 0.1067E-06 0.1059E-06 CH4,gas 0.2583E-07 1.0129 0.2753E-07 0.2718E-07 H2,gas 0.2172E-03 1.0006 0.2286E-03 0.2285E-03 H2S,gas 0.1301E-06 0.9959 0.1363E-06 0.1369E-06 S2,gas 0.1265E-25 1.0000 0.1332E-25 0.1332E-25 CO,gas 0.6004E-14 1.0000 0.6317E-14 0.6317E-14 SO3,gas 0.1440E-40 1.0000 0.1515E-40 0.1515E-40 SO2,gas 0.1245E-21 1.0000 0.1310E-21 0.1310E-21 HCl,gas 0.3699E-17 1.0000 0.3892E-17 0.3892E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.34 -8.97 -2.991 0.15319E+05 -6.972 3 CH4,gas 4.81 -4.75 -9.56 -2.390 0.16324E+05 -7.560 4 H2,gas 8.29 2.65 -5.64 -3.223 0.96317E+04 -3.641 5 H2S,gas -5.94 -14.81 -8.87 -4.433 0.15138E+05 -6.865 6 S2,gas -7.03 -34.91 -27.88 -4.289 0.47597E+05 -25.876 7 CO,gas 3.51 -12.69 -16.20 -4.984 0.27660E+05 -14.199 8 SO3,gas 17.43 -25.39 -42.82 -10.705 0.73113E+05 -40.820 9 SO2,gas 1.14 -22.75 -23.88 -6.369 0.40779E+05 -21.883 10 HCl,gas 5.48 -13.93 -19.41 -9.705 0.33142E+05 -17.410 11 acmite 7.74 7.02 -0.72 -0.075 0.12294E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.90 -4.65 -0.233 0.79477E+04 20 analcite 3.37 2.89 -0.48 -0.053 0.82095E+03 26 annite 20.21 17.64 -2.57 -0.143 0.43867E+04 27 phlogopite 27.15 24.94 -2.20 -0.122 0.37605E+04 29 anorthite 12.80 8.69 -4.11 -0.316 0.70221E+04 35 aragonite 0.99 -2.69 -3.68 -1.227 0.62836E+04 36 brucite 12.58 9.13 -3.45 -0.690 0.58929E+04 37 calcite 0.83 -2.69 -3.53 -1.176 0.60223E+04 38 carnegieite-low 9.06 6.11 -2.96 -0.422 0.50482E+04 39 carnegieite-high 10.13 6.11 -4.03 -0.575 0.68750E+04 40 carpholite-Mg 8.65 5.17 -3.48 -0.232 0.59440E+04 41 carpholite-Fe 6.78 2.73 -4.05 -0.270 0.69125E+04 42 celadonite 5.40 3.48 -1.93 -0.113 0.32872E+04 43 celadonite-Fe 3.94 1.04 -2.90 -0.170 0.49453E+04 44 chrysotile 23.94 20.94 -3.00 -0.250 0.51186E+04 50 chloritoid-Mg 13.26 8.39 -4.87 -0.325 0.83220E+04 51 chloritoid-Fe 9.24 5.95 -3.29 -0.219 0.56107E+04 52 chloritoid-Mn 11.46 8.29 -3.18 -0.212 0.54263E+04 54 coesite -2.37 -3.22 -0.85 -0.283 0.14494E+04 61 cristobalite -2.55 -3.22 -0.67 -0.223 0.11423E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.24 -1.66 -0.276 0.28275E+04 67 diopside 16.22 15.33 -0.89 -0.089 0.15116E+04 68 hedenbergite 14.24 12.90 -1.35 -0.135 0.23032E+04 75 epidote 24.78 23.48 -1.30 -0.063 0.22186E+04 76 clinozoisite 22.92 19.35 -3.57 -0.162 0.61005E+04 77 epidote-Fe 29.94 27.60 -2.33 -0.121 0.39842E+04 78 fayalite 14.08 10.16 -3.92 -0.559 0.66862E+04 79 ferrosilite 11.19 6.94 -4.24 -0.424 0.72444E+04 83 gibbsite 4.10 1.24 -2.86 -0.408 0.48787E+04 84 glaucophane 23.11 20.28 -2.83 -0.076 0.48281E+04 85 glaucophane-Fe 17.42 12.98 -4.44 -0.120 0.75783E+04 87 greenalite 16.19 13.64 -2.56 -0.213 0.43687E+04 90 hematite 12.60 10.74 -1.86 -0.226 0.31798E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.89 -1.36 -0.136 0.23240E+04 96 julgoldite 70.57 66.11 -4.46 -0.116 0.76238E+04 97 kalsilite 7.62 4.00 -3.62 -0.517 0.61736E+04 98 kaolinite -1.27 -3.96 -2.68 -0.244 0.45812E+04 101 laumontite 2.97 2.25 -0.73 -0.048 0.12393E+04 102 lawsonite 9.68 8.69 -0.99 -0.066 0.16959E+04 103 leucite 4.17 0.79 -3.38 -0.338 0.57734E+04 105 lizardite 23.29 20.94 -2.35 -0.196 0.40088E+04 107 magnetite 20.13 17.43 -2.71 -0.221 0.46218E+04 108 minnesotaite 10.46 7.20 -3.26 -0.192 0.55689E+04 120 muscovite 2.68 0.05 -2.63 -0.155 0.44919E+04 121 paragonite 4.34 2.15 -2.18 -0.129 0.37304E+04 122 nepheline 8.38 6.11 -2.27 -0.324 0.38761E+04 128 periclase-Fe 11.64 6.69 -4.95 -1.237 0.84494E+04 134 phlogopite-Na 29.73 27.05 -2.68 -0.149 0.45824E+04 136 prehnite 19.47 18.11 -1.36 -0.080 0.23190E+04 137 prehnite-Fe 22.59 22.24 -0.35 -0.021 0.59936E+03 138 pumpellyite-Fe 46.47 44.15 -2.32 -0.052 0.39671E+04 139 pumpellyite-Mg 49.19 46.58 -2.61 -0.058 0.44602E+04 142 pyrite -21.23 -25.57 -4.35 -1.023 0.74211E+04 143 pyrrhotite -4.24 -8.12 -3.87 -1.291 0.66146E+04 144 pyrrhotiteFe0.875 -6.00 -9.28 -3.28 -1.207 0.56020E+04 145 pyroxmangite 7.42 5.80 -1.61 -0.322 0.27508E+04 146 pyrophyllite -6.10 -10.39 -4.29 -0.268 0.73328E+04 147 quartz -2.98 -3.22 -0.24 -0.079 0.40330E+03 152 rhodonite 7.46 5.80 -1.66 -0.331 0.28300E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.35 -2.24 -0.067 0.38309E+04 171 talc 16.55 14.50 -2.05 -0.121 0.35006E+04 174 tephroite 18.11 14.83 -3.28 -0.469 0.56086E+04 178 tridymite -2.61 -3.22 -0.60 -0.201 0.10306E+04 179 tremolite 48.00 45.16 -2.84 -0.077 0.48484E+04 181 troilite-low -4.39 -8.12 -3.72 -1.241 0.63578E+04 187 wairakite 4.06 2.25 -1.81 -0.106 0.30901E+04 188 walstromite 11.53 9.42 -2.10 -0.421 0.35939E+04 189 wollastonite 10.48 9.42 -1.06 -0.212 0.18078E+04 190 pseudo-wollastonite 11.02 9.42 -1.60 -0.319 0.27264E+04 191 zoisite 22.96 19.35 -3.62 -0.164 0.61730E+04 192 akaganeite 7.77 5.37 -2.40 -0.519 0.40981E+04 197 beidellite-Na -1.26 -6.25 -5.00 -0.306 0.85303E+04 199 chalcedony -2.79 -3.22 -0.42 -0.141 0.72362E+03 201 montmorillonite-Ca -2.21 -5.70 -3.49 -0.216 0.59601E+04 202 montmorillonite-K -2.16 -5.82 -3.66 -0.224 0.62411E+04 203 montmorillonite-Mg -2.40 -6.28 -3.88 -0.240 0.66303E+04 204 montmorillonite-Na -1.96 -5.12 -3.16 -0.194 0.53980E+04 205 nontronite-Ca 3.28 1.42 -1.86 -0.121 0.31760E+04 206 nontronite-H 2.60 -0.67 -3.26 -0.219 0.55697E+04 207 nontronite-K 3.40 1.31 -2.10 -0.135 0.35785E+04 208 nontronite-Mg 3.14 0.84 -2.30 -0.149 0.39268E+04 209 nontronite-Na 3.58 2.00 -1.58 -0.101 0.26989E+04 224 tobermorite 9.84 7.31 -2.53 -0.690 0.43148E+04 230 alabandite -0.96 -5.78 -4.82 -1.608 0.82343E+04 233 boehmite 4.43 1.24 -3.19 -0.532 0.54459E+04 235 ferrous-oxide 9.82 6.69 -3.13 -0.783 0.53505E+04 240 silica-amorphous -2.08 -3.22 -1.14 -0.379 0.19438E+04 242 an20ab80 2.08 1.47 -0.60 -0.047 0.10328E+04 243 an25ab75 2.71 1.93 -0.78 -0.060 0.13389E+04 244 an30ab70 3.34 2.38 -0.97 -0.074 0.16534E+04 245 tr.625ac.25prg.125 45.31 43.26 -2.05 -0.055 0.34971E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 55.9990000 g New total amount of reactant added: 57.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1493E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 57.9990000 Water: Moles liquid = 0.5512E+02 kg liquid = 0.9930E+00 Moles total = 0.5478E+02 kg total = 0.9869E+00 Activity = 1.0000 Stoichiometric ionic strength = .8044223E-02 Osmotic coef. = 0.9639 True ionic strength = .1456082E-01 Chg. balance for total moles = -.1493E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11410E-09 -9.9427 0.97748E-10 -10.0099 0.85671E+00 -0.0672 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13847E-03 -3.8587 0.11807E-03 -3.9278 0.85273E+00 -0.0692 4 SO4-- 0.37651E-05 -5.4242 0.21197E-05 -5.6737 0.56298E+00 -0.2495 5 HCO3- 0.54000E-05 -5.2676 0.46099E-05 -5.3363 0.85369E+00 -0.0687 6 HS- 0.21909E-04 -4.6594 0.18684E-04 -4.7285 0.85282E+00 -0.0691 7 Al+++ 0.55166E-28 -28.2583 0.15330E-28 -28.8144 0.27789E+00 -0.5561 8 H4SiO4 0.61016E-03 -3.2146 0.61016E-03 -3.2146 0.10000E+01 0.0000 9 Ca++ 0.79021E-07 -7.1023 0.44236E-07 -7.3542 0.55980E+00 -0.2520 10 Mg++ 0.23372E-10 -10.6313 0.13038E-10 -10.8848 0.55783E+00 -0.2535 11 Fe++ 0.84479E-13 -13.0733 0.47165E-13 -13.3264 0.55830E+00 -0.2531 12 K+ 0.11360E-03 -3.9446 0.96994E-04 -4.0133 0.85385E+00 -0.0686 13 Na+ 0.14435E-01 -1.8406 0.12308E-01 -1.9098 0.85261E+00 -0.0692 14 Mn++ 0.18446E-10 -10.7341 0.10305E-10 -10.9869 0.55866E+00 -0.2529 15 HPO4-- 0.14579E-06 -6.8363 0.82085E-07 -7.0857 0.56304E+00 -0.2495 16 HSiO3- 0.71421E-02 -2.1462 0.60903E-02 -2.2154 0.85273E+00 -0.0692 17 Ca(HSiO3)+ 0.70683E-08 -8.1507 0.60362E-08 -8.2192 0.85399E+00 -0.0685 18 Mg(HSiO3)+ 0.25926E-11 -11.5863 0.22141E-11 -11.6548 0.85399E+00 -0.0685 19 NaHSiO3,aq 0.11905E-02 -2.9243 0.11905E-02 -2.9243 0.10000E+01 0.0000 20 AlO+ 0.24255E-15 -15.6152 0.20713E-15 -15.6837 0.85399E+00 -0.0685 22 HAlO2,aq 0.42405E-09 -9.3726 0.42405E-09 -9.3726 0.10000E+01 0.0000 23 AlO2- 0.11375E-04 -4.9440 0.96866E-05 -5.0138 0.85154E+00 -0.0698 24 CH4,aq 0.39972E-10 -10.3982 0.39874E-10 -10.3993 0.99753E+00 -0.0011 29 CO,aq 0.48288E-17 -17.3162 0.48288E-17 -17.3162 0.10000E+01 0.0000 30 CO2,aq 0.91077E-09 -9.0406 0.90852E-09 -9.0417 0.99753E+00 -0.0011 31 CO3-2 0.77582E-05 -5.1102 0.43605E-05 -5.3605 0.56205E+00 -0.2502 32 CaCO3,aq 0.23625E-08 -8.6266 0.23625E-08 -8.6266 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.60168E-11 -11.2206 0.51383E-11 -11.2892 0.85399E+00 -0.0685 34 CaCl+ 0.97460E-11 -11.0112 0.83230E-11 -11.0797 0.85399E+00 -0.0685 35 CaCl2,aq 0.22881E-15 -15.6405 0.22881E-15 -15.6405 0.10000E+01 0.0000 36 CaOH+ 0.37367E-07 -7.4275 0.31911E-07 -7.4961 0.85399E+00 -0.0685 37 CaSO4,aq 0.29215E-10 -10.5344 0.29215E-10 -10.5344 0.10000E+01 0.0000 38 HCl,aq 0.21709E-14 -14.6634 0.21709E-14 -14.6634 0.10000E+01 0.0000 43 FeCl+ 0.10157E-16 -16.9933 0.86736E-17 -17.0618 0.85399E+00 -0.0685 46 FeO,aq 0.19520E-09 -9.7095 0.19520E-09 -9.7095 0.10000E+01 0.0000 47 FeOH+ 0.18732E-10 -10.7274 0.15996E-10 -10.7960 0.85399E+00 -0.0685 48 HFeO2- 0.25189E-07 -7.5988 0.21480E-07 -7.6680 0.85273E+00 -0.0692 49 FeO+ 0.10034E-15 -15.9985 0.85691E-16 -16.0671 0.85399E+00 -0.0685 51 FeO2- 0.20671E-08 -8.6846 0.17627E-08 -8.7538 0.85273E+00 -0.0692 52 HFeO2,aq 0.21563E-10 -10.6663 0.21563E-10 -10.6663 0.10000E+01 0.0000 53 H2,aq 0.20688E-06 -6.6843 0.20637E-06 -6.6854 0.99753E+00 -0.0011 54 KCl,aq 0.20278E-09 -9.6930 0.20278E-09 -9.6930 0.10000E+01 0.0000 55 KHSO4,aq 0.53777E-19 -19.2694 0.53777E-19 -19.2694 0.10000E+01 0.0000 56 KOH,aq 0.43258E-06 -6.3639 0.43258E-06 -6.3639 0.10000E+01 0.0000 57 KSO4- 0.37145E-08 -8.4301 0.31675E-08 -8.4993 0.85273E+00 -0.0692 58 MgCO3,aq 0.17399E-12 -12.7595 0.17399E-12 -12.7595 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18083E-14 -14.7427 0.15443E-14 -14.8113 0.85399E+00 -0.0685 60 MgCl+ 0.26077E-14 -14.5837 0.22269E-14 -14.6523 0.85399E+00 -0.0685 61 MgOH+ 0.61013E-10 -10.2146 0.52105E-10 -10.2831 0.85399E+00 -0.0685 63 MnO,aq 0.11386E-08 -8.9436 0.11386E-08 -8.9436 0.10000E+01 0.0000 64 MnOH+ 0.38020E-09 -9.4200 0.32469E-09 -9.4885 0.85399E+00 -0.0685 65 MnO2-2 0.73321E-11 -11.1348 0.41210E-11 -11.3850 0.56205E+00 -0.2502 66 HMnO2- 0.10235E-09 -9.9899 0.87277E-10 -10.0591 0.85273E+00 -0.0692 69 MnCl+ 0.86233E-14 -14.0643 0.73642E-14 -14.1329 0.85399E+00 -0.0685 70 MnSO4,aq 0.61905E-14 -14.2083 0.61905E-14 -14.2083 0.10000E+01 0.0000 71 NaCl,aq 0.47451E-06 -6.3238 0.47451E-06 -6.3238 0.10000E+01 0.0000 72 NaOH,aq 0.55327E-04 -4.2571 0.55327E-04 -4.2571 0.10000E+01 0.0000 74 OH- 0.72064E-02 -2.1423 0.61365E-02 -2.2121 0.85154E+00 -0.0698 79 HPO3-2 0.95194E-16 -16.0214 0.53504E-16 -16.2716 0.56205E+00 -0.2502 81 H2PO3- 0.12048E-19 -19.9191 0.10273E-19 -19.9883 0.85273E+00 -0.0692 82 H3PO4,aq 0.50492E-17 -17.2968 0.50492E-17 -17.2968 0.10000E+01 0.0000 83 H2PO4- 0.16485E-09 -9.7829 0.14067E-09 -9.8518 0.85335E+00 -0.0689 84 PO4-3 0.25410E-08 -8.5950 0.73337E-09 -9.1347 0.28861E+00 -0.5397 88 HP2O7-3 0.11683E-16 -16.9325 0.32489E-17 -17.4883 0.27809E+00 -0.5558 89 P2O7-4 0.77093E-16 -16.1130 0.81995E-17 -17.0862 0.10636E+00 -0.9732 90 H2S,aq 0.55010E-08 -8.2596 0.54874E-08 -8.2606 0.99753E+00 -0.0011 91 S2-2 0.66196E-13 -13.1792 0.37206E-13 -13.4294 0.56205E+00 -0.2502 97 SO3-2 0.10495E-12 -12.9790 0.59643E-13 -13.2244 0.56832E+00 -0.2454 98 HSO3- 0.40010E-15 -15.3978 0.34118E-15 -15.4670 0.85273E+00 -0.0692 99 HSO4- 0.22495E-12 -12.6479 0.19225E-12 -12.7161 0.85462E+00 -0.0682 101 S2O3-2 0.24390E-15 -15.6128 0.13708E-15 -15.8630 0.56205E+00 -0.2502 Charge balance for all species = -.1592E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1140976E-09 -.1564825E-01 -.1575367E+02 0.0000 2 H2O 0.1000000E+01 0.5550720E+02 0.9987856E+06 0.0000 3 Cl- 0.1384657E-03 0.1389405E-03 0.4919977E+01 6.0820 4 SO4-- 0.3765105E-05 0.3717350E-05 0.3566685E+00 14.3461 5 HCO3- 0.5400032E-05 0.1316153E-04 0.8021215E+00 4.6736 6 HS- 0.2190874E-04 0.2196573E-04 0.7255838E+00 5.2814 7 Al+++ 0.5516645E-28 0.1137583E-04 0.3065707E+00 1.2152 8 H4SiO4 0.6101619E-03 0.8942821E-02 0.8585171E+03 -3.2146 9 Ca++ 0.7902087E-07 0.1258633E-06 0.5038329E-02 12.6656 10 Mg++ 0.2337224E-10 0.8715669E-10 0.2116425E-05 9.1350 11 Fe++ 0.8447901E-13 0.2749197E-07 0.1533512E-02 6.6934 12 K+ 0.1135966E-03 0.1140331E-03 0.4453600E+01 5.9966 13 Na+ 0.1443526E-01 0.1568158E-01 0.3600861E+03 8.1001 14 Mn++ 0.1844638E-10 0.1646901E-08 0.9036947E-04 9.0328 15 HPO4-- 0.1457889E-06 0.1484948E-06 0.1423537E-01 12.9340 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9603643E+00 -.1553942E-01 -.9448249E+00 0.0000000E+00 2 H2O 0.5478121E+02 0.5512117E+02 -.3399649E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1632854E-02 0.3691498E-05 0.1629163E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1607350E-02 0.2181297E-04 -.1629163E-02 0.0000000E+00 7 Al+++ 0.1891198E+00 0.1129672E-04 0.1891085E+00 0.0000000E+00 8 H4SiO4 0.6039310E+00 0.8880628E-02 0.5950504E+00 0.0000000E+00 9 Ca++ 0.6672159E-01 0.1249880E-06 0.6672147E-01 0.0000000E+00 10 Mg++ 0.4603095E-01 0.8655055E-10 0.4603095E-01 0.0000000E+00 11 Fe++ 0.4135379E-01 0.2730077E-07 0.4135376E-01 0.0000000E+00 12 K+ 0.1231401E-01 0.1132400E-03 0.1220077E-01 0.0000000E+00 13 Na+ 0.7296295E-01 0.1557252E-01 0.5739043E-01 0.0000000E+00 14 Mn++ 0.1005621E-02 0.1635447E-08 0.1005620E-02 0.0000000E+00 15 HPO4-- 0.3432135E-03 0.1474621E-06 0.3430661E-03 0.0000000E+00 Chg. balance for solid moles: -.1580E-15 Mass of aqueous solution: 0.994232E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 57.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5739E-01 -1.241 15.05 1.178 23.77 5.777 andradite 0.6517E-02 -2.186 3.312 0.520 5.231 0.8604 grossular 0.6839E-03 -3.165 0.3081 -0.511 0.4866 0.8572E-01 apatite-OH 0.1144E-03 -3.942 0.5744E-01 -1.241 0.9074E-01 0.1825E-01 clinochlore 0.9206E-02 -2.036 5.117 0.709 8.083 1.946 daphnite 0.3485E-02 -2.458 2.487 0.396 3.928 0.7536 chlorite-Mn 0.2011E-03 -3.697 0.1426 -0.846 0.2252 0.4544E-01 microcline 0.1111E-01 -1.954 3.093 0.490 4.885 1.208 stilbite 0.4455E-01 -1.351 31.39 1.497 49.59 14.64 stilpnomelane-Fe 0.2179E-02 -2.662 2.349 0.371 3.710 0.8112 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9050E+00 0.9050E+00 1.0000 -0.043 grossular 0.9498E-01 0.9498E-01 1.0000 -1.022 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7141E+00 0.7141E+00 1.0000 -0.146 daphnite 0.2703E+00 0.2703E+00 1.0000 -0.568 chlorite-Mn 0.1560E-01 0.1560E-01 1.0000 -1.807 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 63.307774 g Volume = 26.148735 cm3 Porosity: -8.0544% V(tot) - V(min): -.19491E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 57.9990000 g log = 1.7634 Original solution: 1000.0103000 g Original solution / Rock added: 17.24 (Water/Rock Ratio), log = 1.2366 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0522 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.9812E-07 1.0073 0.1040E-06 0.1032E-06 CH4,gas 0.5916E-07 1.0129 0.6306E-07 0.6225E-07 H2,gas 0.2689E-03 1.0006 0.2830E-03 0.2829E-03 H2S,gas 0.1527E-06 0.9959 0.1600E-06 0.1607E-06 S2,gas 0.1138E-25 1.0000 0.1197E-25 0.1197E-25 CO,gas 0.7246E-14 1.0000 0.7625E-14 0.7625E-14 SO3,gas 0.7196E-41 1.0000 0.7572E-41 0.7572E-41 SO2,gas 0.7705E-22 1.0000 0.8107E-22 0.8107E-22 HCl,gas 0.3643E-17 1.0000 0.3833E-17 0.3833E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.48529E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.35 -8.98 -2.994 0.15338E+05 -6.983 3 CH4,gas 4.81 -4.39 -9.20 -2.300 0.15709E+05 -7.200 4 H2,gas 8.29 2.74 -5.55 -3.170 0.94733E+04 -3.548 5 H2S,gas -5.94 -14.74 -8.80 -4.398 0.15019E+05 -6.796 6 S2,gas -7.03 -34.95 -27.92 -4.296 0.47676E+05 -25.922 7 CO,gas 3.51 -12.61 -16.12 -4.959 0.27521E+05 -14.118 8 SO3,gas 17.43 -25.69 -43.12 -10.780 0.73628E+05 -41.121 9 SO2,gas 1.14 -22.95 -24.09 -6.424 0.41135E+05 -22.091 10 HCl,gas 5.48 -13.94 -19.42 -9.708 0.33153E+05 -17.416 11 acmite 7.74 6.99 -0.74 -0.077 0.12677E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.89 -4.66 -0.233 0.79646E+04 20 analcite 3.37 2.89 -0.48 -0.054 0.82717E+03 26 annite 20.21 17.65 -2.56 -0.142 0.43727E+04 27 phlogopite 27.15 24.97 -2.17 -0.121 0.37111E+04 29 anorthite 12.80 8.67 -4.13 -0.318 0.70532E+04 35 aragonite 0.99 -2.68 -3.67 -1.222 0.62611E+04 36 brucite 12.58 9.13 -3.44 -0.688 0.58765E+04 37 calcite 0.83 -2.68 -3.51 -1.171 0.59997E+04 38 carnegieite-low 9.06 6.10 -2.96 -0.423 0.50606E+04 39 carnegieite-high 10.13 6.10 -4.03 -0.576 0.68875E+04 40 carpholite-Mg 8.65 5.14 -3.51 -0.234 0.60001E+04 41 carpholite-Fe 6.78 2.69 -4.09 -0.273 0.69804E+04 42 celadonite 5.40 3.49 -1.91 -0.112 0.32645E+04 43 celadonite-Fe 3.94 1.05 -2.89 -0.170 0.49344E+04 44 chrysotile 23.94 20.98 -2.96 -0.247 0.50567E+04 50 chloritoid-Mg 13.26 8.35 -4.91 -0.327 0.83843E+04 51 chloritoid-Fe 9.24 5.91 -3.33 -0.222 0.56848E+04 52 chloritoid-Mn 11.46 8.25 -3.21 -0.214 0.54886E+04 54 coesite -2.37 -3.21 -0.85 -0.282 0.14432E+04 61 cristobalite -2.55 -3.21 -0.67 -0.222 0.11361E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.22 -1.68 -0.280 0.28700E+04 67 diopside 16.22 15.37 -0.84 -0.084 0.14412E+04 68 hedenbergite 14.24 12.93 -1.31 -0.131 0.22446E+04 75 epidote 24.78 23.44 -1.33 -0.065 0.22765E+04 76 clinozoisite 22.92 19.33 -3.59 -0.163 0.61264E+04 77 epidote-Fe 29.94 27.55 -2.39 -0.124 0.40741E+04 78 fayalite 14.08 10.17 -3.91 -0.558 0.66706E+04 79 ferrosilite 11.19 6.96 -4.23 -0.423 0.72226E+04 83 gibbsite 4.10 1.22 -2.88 -0.412 0.49212E+04 84 glaucophane 23.11 20.32 -2.79 -0.075 0.47662E+04 85 glaucophane-Fe 17.42 12.99 -4.42 -0.120 0.75518E+04 87 greenalite 16.19 13.65 -2.54 -0.212 0.43423E+04 90 hematite 12.60 10.65 -1.95 -0.236 0.33289E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.89 -1.36 -0.136 0.23302E+04 96 julgoldite 70.57 66.06 -4.52 -0.117 0.77094E+04 97 kalsilite 7.62 4.00 -3.62 -0.518 0.61861E+04 98 kaolinite -1.27 -4.00 -2.73 -0.248 0.46537E+04 101 laumontite 2.97 2.24 -0.74 -0.049 0.12580E+04 102 lawsonite 9.68 8.67 -1.01 -0.067 0.17270E+04 103 leucite 4.17 0.78 -3.38 -0.338 0.57796E+04 105 lizardite 23.29 20.98 -2.31 -0.193 0.39469E+04 107 magnetite 20.13 17.34 -2.79 -0.228 0.47661E+04 108 minnesotaite 10.46 7.22 -3.24 -0.191 0.55301E+04 120 muscovite 2.68 0.00 -2.68 -0.158 0.45769E+04 121 paragonite 4.34 2.10 -2.23 -0.131 0.38154E+04 122 nepheline 8.38 6.10 -2.28 -0.325 0.38886E+04 128 periclase-Fe 11.64 6.69 -4.95 -1.236 0.84447E+04 134 phlogopite-Na 29.73 27.08 -2.65 -0.147 0.45330E+04 136 prehnite 19.47 18.12 -1.35 -0.079 0.23024E+04 137 prehnite-Fe 22.59 22.23 -0.36 -0.022 0.61479E+03 138 pumpellyite-Fe 46.47 44.14 -2.33 -0.052 0.39717E+04 139 pumpellyite-Mg 49.19 46.59 -2.61 -0.058 0.44530E+04 142 pyrite -21.23 -25.52 -4.30 -1.011 0.73368E+04 143 pyrrhotite -4.24 -8.05 -3.80 -1.267 0.64909E+04 144 pyrrhotiteFe0.875 -6.00 -9.22 -3.22 -1.184 0.54986E+04 145 pyroxmangite 7.42 5.82 -1.60 -0.320 0.27281E+04 146 pyrophyllite -6.10 -10.43 -4.33 -0.271 0.73929E+04 147 quartz -2.98 -3.21 -0.23 -0.078 0.39708E+03 152 rhodonite 7.46 5.82 -1.64 -0.329 0.28073E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.39 -2.21 -0.066 0.37718E+04 171 talc 16.55 14.55 -2.01 -0.118 0.34263E+04 174 tephroite 18.11 14.85 -3.26 -0.466 0.55694E+04 178 tridymite -2.61 -3.21 -0.60 -0.200 0.10244E+04 179 tremolite 48.00 45.29 -2.71 -0.073 0.46333E+04 181 troilite-low -4.39 -8.05 -3.65 -1.217 0.62341E+04 187 wairakite 4.06 2.24 -1.82 -0.107 0.31088E+04 188 walstromite 11.53 9.45 -2.08 -0.415 0.35462E+04 189 wollastonite 10.48 9.45 -1.03 -0.206 0.17601E+04 190 pseudo-wollastonite 11.02 9.45 -1.57 -0.314 0.26787E+04 191 zoisite 22.96 19.33 -3.63 -0.165 0.61989E+04 192 akaganeite 7.77 5.32 -2.44 -0.528 0.41726E+04 199 chalcedony -2.79 -3.21 -0.42 -0.140 0.71740E+03 201 montmorillonite-Ca -2.21 -5.72 -3.51 -0.217 0.59939E+04 202 montmorillonite-K -2.16 -5.84 -3.67 -0.225 0.62739E+04 203 montmorillonite-Mg -2.40 -6.31 -3.91 -0.242 0.66683E+04 204 montmorillonite-Na -1.96 -5.14 -3.18 -0.195 0.54308E+04 205 nontronite-Ca 3.28 1.34 -1.94 -0.126 0.33094E+04 206 nontronite-H 2.60 -0.75 -3.34 -0.224 0.57099E+04 207 nontronite-K 3.40 1.23 -2.17 -0.139 0.37108E+04 208 nontronite-Mg 3.14 0.76 -2.38 -0.154 0.40643E+04 209 nontronite-Na 3.58 1.92 -1.66 -0.106 0.28312E+04 224 tobermorite 9.84 7.34 -2.50 -0.683 0.42741E+04 230 alabandite -0.96 -5.71 -4.74 -1.581 0.80988E+04 233 boehmite 4.43 1.22 -3.21 -0.536 0.54884E+04 235 ferrous-oxide 9.82 6.69 -3.13 -0.783 0.53458E+04 240 silica-amorphous -2.08 -3.21 -1.13 -0.378 0.19376E+04 242 an20ab80 2.08 1.47 -0.61 -0.047 0.10390E+04 243 an25ab75 2.71 1.92 -0.79 -0.061 0.13467E+04 244 an30ab70 3.34 2.37 -0.97 -0.075 0.16627E+04 245 tr.625ac.25prg.125 45.31 43.37 -1.94 -0.052 0.33134E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 57.9990000 g New total amount of reactant added: 59.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1492E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 59.9990000 Water: Moles liquid = 0.5511E+02 kg liquid = 0.9928E+00 Moles total = 0.5476E+02 kg total = 0.9865E+00 Activity = 1.0000 Stoichiometric ionic strength = .8209739E-02 Osmotic coef. = 0.9650 True ionic strength = .1484779E-01 Chg. balance for total moles = -.1492E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11255E-09 -9.9487 0.96315E-10 -10.0163 0.85576E+00 -0.0676 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13849E-03 -3.8586 0.11795E-03 -3.9283 0.85172E+00 -0.0697 4 SO4-- 0.17265E-05 -5.7628 0.96753E-06 -6.0143 0.56040E+00 -0.2515 5 HCO3- 0.53433E-05 -5.2722 0.45562E-05 -5.3414 0.85270E+00 -0.0692 6 HS- 0.23955E-04 -4.6206 0.20405E-04 -4.6903 0.85182E+00 -0.0697 7 Al+++ 0.50317E-28 -28.2983 0.13837E-28 -28.8590 0.27500E+00 -0.5607 8 H4SiO4 0.61525E-03 -3.2109 0.61525E-03 -3.2109 0.10000E+01 0.0000 9 Ca++ 0.81700E-07 -7.0878 0.45522E-07 -7.3418 0.55719E+00 -0.2540 10 Mg++ 0.23320E-10 -10.6323 0.12947E-10 -10.8878 0.55519E+00 -0.2556 11 Fe++ 0.82958E-13 -13.0811 0.46097E-13 -13.3363 0.55567E+00 -0.2552 12 K+ 0.11585E-03 -3.9361 0.98803E-04 -4.0052 0.85286E+00 -0.0691 13 Na+ 0.14722E-01 -1.8320 0.12537E-01 -1.9018 0.85161E+00 -0.0698 14 Mn++ 0.18405E-10 -10.7351 0.10233E-10 -10.9900 0.55603E+00 -0.2549 15 HPO4-- 0.13690E-06 -6.8636 0.76729E-07 -7.1150 0.56046E+00 -0.2515 16 HSiO3- 0.73175E-02 -2.1356 0.62325E-02 -2.2053 0.85172E+00 -0.0697 17 Ca(HSiO3)+ 0.74522E-08 -8.1277 0.63567E-08 -8.1968 0.85300E+00 -0.0691 18 Mg(HSiO3)+ 0.26377E-11 -11.5788 0.22500E-11 -11.6478 0.85300E+00 -0.0691 19 NaHSiO3,aq 0.12410E-02 -2.9062 0.12410E-02 -2.9062 0.10000E+01 0.0000 20 AlO+ 0.22575E-15 -15.6464 0.19256E-15 -15.7154 0.85300E+00 -0.0691 22 HAlO2,aq 0.40008E-09 -9.3978 0.40008E-09 -9.3978 0.10000E+01 0.0000 23 AlO2- 0.10905E-04 -4.9624 0.92752E-05 -5.0327 0.85052E+00 -0.0703 24 CH4,aq 0.94527E-10 -10.0244 0.94289E-10 -10.0255 0.99748E+00 -0.0011 29 CO,aq 0.58702E-17 -17.2313 0.58702E-17 -17.2313 0.10000E+01 0.0000 30 CO2,aq 0.88700E-09 -9.0521 0.88476E-09 -9.0532 0.99748E+00 -0.0011 31 CO3-2 0.78178E-05 -5.1069 0.43738E-05 -5.3591 0.55947E+00 -0.2522 32 CaCO3,aq 0.24386E-08 -8.6129 0.24386E-08 -8.6129 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.61267E-11 -11.2128 0.52261E-11 -11.2818 0.85300E+00 -0.0691 34 CaCl+ 0.10031E-10 -10.9987 0.85563E-11 -11.0677 0.85300E+00 -0.0691 35 CaCl2,aq 0.23499E-15 -15.6289 0.23499E-15 -15.6289 0.10000E+01 0.0000 36 CaOH+ 0.39071E-07 -7.4081 0.33327E-07 -7.4772 0.85300E+00 -0.0691 37 CaSO4,aq 0.13723E-10 -10.8625 0.13723E-10 -10.8625 0.10000E+01 0.0000 38 HCl,aq 0.21369E-14 -14.6702 0.21369E-14 -14.6702 0.10000E+01 0.0000 43 FeCl+ 0.99282E-17 -17.0031 0.84688E-17 -17.0722 0.85300E+00 -0.0691 46 FeO,aq 0.19650E-09 -9.7066 0.19650E-09 -9.7066 0.10000E+01 0.0000 47 FeOH+ 0.18602E-10 -10.7305 0.15867E-10 -10.7995 0.85300E+00 -0.0691 48 HFeO2- 0.25765E-07 -7.5890 0.21945E-07 -7.6587 0.85172E+00 -0.0697 49 FeO+ 0.89187E-16 -16.0497 0.76077E-16 -16.1187 0.85300E+00 -0.0691 51 FeO2- 0.18924E-08 -8.7230 0.16118E-08 -8.7927 0.85172E+00 -0.0697 52 HFeO2,aq 0.19429E-10 -10.7116 0.19429E-10 -10.7116 0.10000E+01 0.0000 53 H2,aq 0.25826E-06 -6.5879 0.25761E-06 -6.5890 0.99748E+00 -0.0011 54 KCl,aq 0.20636E-09 -9.6854 0.20636E-09 -9.6854 0.10000E+01 0.0000 55 KHSO4,aq 0.24638E-19 -19.6084 0.24638E-19 -19.6084 0.10000E+01 0.0000 56 KOH,aq 0.44721E-06 -6.3495 0.44721E-06 -6.3495 0.10000E+01 0.0000 57 KSO4- 0.17292E-08 -8.7622 0.14728E-08 -8.8319 0.85172E+00 -0.0697 58 MgCO3,aq 0.17330E-12 -12.7612 0.17330E-12 -12.7612 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.17769E-14 -14.7503 0.15157E-14 -14.8194 0.85300E+00 -0.0691 60 MgCl+ 0.25899E-14 -14.5867 0.22092E-14 -14.6558 0.85300E+00 -0.0691 61 MgOH+ 0.61562E-10 -10.2107 0.52512E-10 -10.2797 0.85300E+00 -0.0691 63 MnO,aq 0.11645E-08 -8.9338 0.11645E-08 -8.9338 0.10000E+01 0.0000 64 MnOH+ 0.38362E-09 -9.4161 0.32722E-09 -9.4852 0.85300E+00 -0.0691 65 MnO2-2 0.77600E-11 -11.1101 0.43415E-11 -11.3624 0.55947E+00 -0.2522 66 HMnO2- 0.10637E-09 -9.9732 0.90597E-10 -10.0429 0.85172E+00 -0.0697 69 MnCl+ 0.85645E-14 -14.0673 0.73056E-14 -14.1363 0.85300E+00 -0.0691 70 MnSO4,aq 0.28060E-14 -14.5519 0.28060E-14 -14.5519 0.10000E+01 0.0000 71 NaCl,aq 0.48288E-06 -6.3162 0.48288E-06 -6.3162 0.10000E+01 0.0000 72 NaOH,aq 0.57198E-04 -4.2426 0.57198E-04 -4.2426 0.10000E+01 0.0000 74 OH- 0.73224E-02 -2.1353 0.62279E-02 -2.2057 0.85052E+00 -0.0703 79 HPO3-2 0.11159E-15 -15.9524 0.62432E-16 -16.2046 0.55947E+00 -0.2522 81 H2PO3- 0.13868E-19 -19.8580 0.11812E-19 -19.9277 0.85172E+00 -0.0697 82 H3PO4,aq 0.45824E-17 -17.3389 0.45824E-17 -17.3389 0.10000E+01 0.0000 83 H2PO4- 0.15201E-09 -9.8181 0.12956E-09 -9.8875 0.85235E+00 -0.0694 84 PO4-3 0.24345E-08 -8.6136 0.69572E-09 -9.1576 0.28578E+00 -0.5440 88 HP2O7-3 0.10164E-16 -16.9929 0.27971E-17 -17.5533 0.27520E+00 -0.5604 89 P2O7-4 0.68604E-16 -16.1637 0.71645E-17 -17.1448 0.10443E+00 -0.9812 90 H2S,aq 0.59198E-08 -8.2277 0.59049E-08 -8.2288 0.99748E+00 -0.0011 91 S2-2 0.63539E-13 -13.1970 0.35548E-13 -13.4492 0.55947E+00 -0.2522 97 SO3-2 0.60063E-13 -13.2214 0.33984E-13 -13.4687 0.56581E+00 -0.2473 98 HSO3- 0.22490E-15 -15.6480 0.19155E-15 -15.7177 0.85172E+00 -0.0697 99 HSO4- 0.10129E-12 -12.9944 0.86465E-13 -13.0632 0.85365E+00 -0.0687 101 S2O3-2 0.12035E-15 -15.9195 0.67333E-16 -16.1718 0.55947E+00 -0.2522 Charge balance for all species = -.1515E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1125487E-09 -.1599024E-01 -.1609752E+02 0.0000 2 H2O 0.1000000E+01 0.5550709E+02 0.9987560E+06 0.0000 3 Cl- 0.1384888E-03 0.1389719E-03 0.4920955E+01 6.0880 4 SO4-- 0.1726502E-05 0.1663825E-05 0.1596345E+00 14.0183 5 HCO3- 0.5343274E-05 0.1316451E-04 0.8022809E+00 4.6749 6 HS- 0.2395473E-04 0.2402507E-04 0.7935871E+00 5.3260 7 Al+++ 0.5031710E-28 0.1090573E-04 0.2938937E+00 1.1900 8 H4SiO4 0.6152510E-03 0.9173794E-02 0.8806663E+03 -3.2109 9 Ca++ 0.8169992E-07 0.1306912E-06 0.5231447E-02 12.6908 10 Mg++ 0.2331975E-10 0.8769678E-10 0.2129481E-05 9.1448 11 Fe++ 0.8295799E-13 0.2789222E-07 0.1555795E-02 6.6963 12 K+ 0.1158500E-03 0.1162991E-03 0.4541975E+01 6.0111 13 Na+ 0.1472196E-01 0.1602067E-01 0.3678623E+03 8.1145 14 Mn++ 0.1840452E-10 0.1680698E-08 0.9222144E-04 9.0426 15 HPO4-- 0.1369033E-06 0.1394898E-06 0.1337175E-01 12.9176 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9934813E+00 -.1587544E-01 -.9776059E+00 0.0000000E+00 2 H2O 0.5475614E+02 0.5510859E+02 -.3524541E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1688281E-02 0.1651879E-05 0.1686629E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1662777E-02 0.2385259E-04 -.1686629E-02 0.0000000E+00 7 Al+++ 0.1956412E+00 0.1082743E-04 0.1956304E+00 0.0000000E+00 8 H4SiO4 0.6247566E+00 0.9107932E-02 0.6156486E+00 0.0000000E+00 9 Ca++ 0.6902188E-01 0.1297529E-06 0.6902175E-01 0.0000000E+00 10 Mg++ 0.4761825E-01 0.8706718E-10 0.4761825E-01 0.0000000E+00 11 Fe++ 0.4277980E-01 0.2769197E-07 0.4277977E-01 0.0000000E+00 12 K+ 0.1273864E-01 0.1154642E-03 0.1262318E-01 0.0000000E+00 13 Na+ 0.7547343E-01 0.1590565E-01 0.5956778E-01 0.0000000E+00 14 Mn++ 0.1040298E-02 0.1668632E-08 0.1040297E-02 0.0000000E+00 15 HPO4-- 0.3550487E-03 0.1384884E-06 0.3549102E-03 0.0000000E+00 Chg. balance for solid moles: -.1935E-15 Mass of aqueous solution: 0.994034E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 59.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.5957E-01 -1.225 15.62 1.194 23.85 5.996 andradite 0.6747E-02 -2.171 3.428 0.535 5.235 0.8907 grossular 0.7414E-03 -3.130 0.3340 -0.476 0.5100 0.9293E-01 apatite-OH 0.1183E-03 -3.927 0.5943E-01 -1.226 0.9074E-01 0.1888E-01 clinochlore 0.9524E-02 -2.021 5.294 0.724 8.083 2.014 daphnite 0.3549E-02 -2.450 2.532 0.403 3.866 0.7673 chlorite-Mn 0.2081E-03 -3.682 0.1475 -0.831 0.2252 0.4701E-01 microcline 0.1147E-01 -1.940 3.192 0.504 4.874 1.247 stilbite 0.4597E-01 -1.338 32.39 1.510 49.46 15.11 stilpnomelane-Fe 0.2309E-02 -2.637 2.489 0.396 3.800 0.8596 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.9010E+00 0.9010E+00 1.0000 -0.045 grossular 0.9902E-01 0.9902E-01 1.0000 -1.004 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7171E+00 0.7171E+00 1.0000 -0.144 daphnite 0.2672E+00 0.2672E+00 1.0000 -0.573 chlorite-Mn 0.1567E-01 0.1567E-01 1.0000 -1.805 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 65.489133 g Volume = 27.041950 cm3 Porosity: -8.1695% V(tot) - V(min): -.20424E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 59.9990000 g log = 1.7781 Original solution: 1000.0103000 g Original solution / Rock added: 16.67 (Water/Rock Ratio), log = 1.2219 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0523 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9997E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.9554E-07 1.0073 0.1013E-06 0.1005E-06 CH4,gas 0.1399E-06 1.0129 0.1491E-06 0.1472E-06 H2,gas 0.3356E-03 1.0006 0.3533E-03 0.3531E-03 H2S,gas 0.1643E-06 0.9959 0.1722E-06 0.1729E-06 S2,gas 0.8456E-26 1.0000 0.8899E-26 0.8899E-26 CO,gas 0.8809E-14 1.0000 0.9269E-14 0.9269E-14 SO3,gas 0.3189E-41 1.0000 0.3355E-41 0.3355E-41 SO2,gas 0.4262E-22 1.0000 0.4485E-22 0.4485E-22 HCl,gas 0.3586E-17 1.0000 0.3773E-17 0.3773E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.36 -8.99 -2.998 0.15358E+05 -6.994 3 CH4,gas 4.81 -4.02 -8.83 -2.207 0.15071E+05 -6.827 4 H2,gas 8.29 2.84 -5.45 -3.115 0.93088E+04 -3.452 5 H2S,gas -5.94 -14.71 -8.76 -4.382 0.14964E+05 -6.764 6 S2,gas -7.03 -35.08 -28.05 -4.315 0.47896E+05 -26.051 7 CO,gas 3.51 -12.52 -16.03 -4.933 0.27376E+05 -14.033 8 SO3,gas 17.43 -26.05 -43.47 -10.869 0.74231E+05 -41.474 9 SO2,gas 1.14 -23.21 -24.35 -6.493 0.41574E+05 -22.348 10 HCl,gas 5.48 -13.94 -19.42 -9.712 0.33165E+05 -17.423 11 acmite 7.74 6.97 -0.77 -0.080 0.13080E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.88 -4.67 -0.234 0.79822E+04 20 analcite 3.37 2.88 -0.49 -0.054 0.83333E+03 26 annite 20.21 17.66 -2.55 -0.142 0.43579E+04 27 phlogopite 27.15 25.00 -2.14 -0.119 0.36609E+04 29 anorthite 12.80 8.65 -4.15 -0.319 0.70840E+04 35 aragonite 0.99 -2.67 -3.65 -1.218 0.62375E+04 36 brucite 12.58 9.14 -3.43 -0.686 0.58597E+04 37 calcite 0.83 -2.67 -3.50 -1.167 0.59762E+04 38 carnegieite-low 9.06 6.09 -2.97 -0.424 0.50729E+04 39 carnegieite-high 10.13 6.09 -4.04 -0.577 0.68998E+04 40 carpholite-Mg 8.65 5.10 -3.55 -0.237 0.60573E+04 41 carpholite-Fe 6.78 2.65 -4.13 -0.275 0.70494E+04 42 celadonite 5.40 3.50 -1.90 -0.112 0.32416E+04 43 celadonite-Fe 3.94 1.05 -2.88 -0.170 0.49233E+04 44 chrysotile 23.94 21.01 -2.92 -0.244 0.49942E+04 50 chloritoid-Mg 13.26 8.31 -4.95 -0.330 0.84477E+04 51 chloritoid-Fe 9.24 5.87 -3.37 -0.225 0.57600E+04 52 chloritoid-Mn 11.46 8.21 -3.25 -0.217 0.55520E+04 54 coesite -2.37 -3.21 -0.84 -0.281 0.14370E+04 61 cristobalite -2.55 -3.21 -0.66 -0.221 0.11299E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.19 -1.71 -0.284 0.29132E+04 67 diopside 16.22 15.41 -0.80 -0.080 0.13690E+04 68 hedenbergite 14.24 12.97 -1.28 -0.128 0.21842E+04 75 epidote 24.78 23.41 -1.37 -0.066 0.23353E+04 76 clinozoisite 22.92 19.32 -3.60 -0.164 0.61510E+04 77 epidote-Fe 29.94 27.50 -2.44 -0.127 0.41670E+04 78 fayalite 14.08 10.18 -3.90 -0.557 0.66546E+04 79 ferrosilite 11.19 6.97 -4.22 -0.422 0.72004E+04 83 gibbsite 4.10 1.19 -2.91 -0.415 0.49643E+04 84 glaucophane 23.11 20.36 -2.75 -0.074 0.47037E+04 85 glaucophane-Fe 17.42 13.01 -4.41 -0.119 0.75247E+04 87 greenalite 16.19 13.67 -2.53 -0.211 0.43152E+04 90 hematite 12.60 10.56 -2.04 -0.247 0.34834E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.88 -1.37 -0.137 0.23364E+04 96 julgoldite 70.57 66.01 -4.57 -0.119 0.77991E+04 97 kalsilite 7.62 3.99 -3.63 -0.519 0.61984E+04 98 kaolinite -1.27 -4.04 -2.77 -0.252 0.47277E+04 101 laumontite 2.97 2.23 -0.75 -0.050 0.12764E+04 102 lawsonite 9.68 8.65 -1.03 -0.069 0.17578E+04 103 leucite 4.17 0.78 -3.39 -0.339 0.57857E+04 105 lizardite 23.29 21.01 -2.27 -0.190 0.38844E+04 107 magnetite 20.13 17.25 -2.88 -0.235 0.49158E+04 108 minnesotaite 10.46 7.25 -3.22 -0.189 0.54906E+04 120 muscovite 2.68 -0.05 -2.73 -0.161 0.46632E+04 121 paragonite 4.34 2.05 -2.29 -0.134 0.39017E+04 122 nepheline 8.38 6.09 -2.28 -0.326 0.39009E+04 128 periclase-Fe 11.64 6.70 -4.94 -1.236 0.84398E+04 134 phlogopite-Na 29.73 27.11 -2.63 -0.146 0.44828E+04 136 prehnite 19.47 18.13 -1.34 -0.079 0.22838E+04 137 prehnite-Fe 22.59 22.22 -0.37 -0.022 0.63042E+03 138 pumpellyite-Fe 46.47 44.14 -2.33 -0.052 0.39729E+04 139 pumpellyite-Mg 49.19 46.59 -2.60 -0.058 0.44424E+04 142 pyrite -21.23 -25.55 -4.33 -1.018 0.73875E+04 143 pyrrhotite -4.24 -8.01 -3.77 -1.256 0.64316E+04 144 pyrrhotiteFe0.875 -6.00 -9.20 -3.20 -1.176 0.54603E+04 145 pyroxmangite 7.42 5.83 -1.58 -0.317 0.27052E+04 146 pyrophyllite -6.10 -10.46 -4.37 -0.273 0.74545E+04 147 quartz -2.98 -3.21 -0.23 -0.076 0.39092E+03 152 rhodonite 7.46 5.83 -1.63 -0.326 0.27845E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.42 -2.17 -0.065 0.37128E+04 171 talc 16.55 14.59 -1.96 -0.115 0.33514E+04 174 tephroite 18.11 14.87 -3.24 -0.463 0.55298E+04 178 tridymite -2.61 -3.21 -0.60 -0.199 0.10182E+04 179 tremolite 48.00 45.42 -2.59 -0.070 0.44141E+04 181 troilite-low -4.39 -8.01 -3.62 -1.205 0.61748E+04 187 wairakite 4.06 2.23 -1.83 -0.108 0.31272E+04 188 walstromite 11.53 9.48 -2.05 -0.410 0.34969E+04 189 wollastonite 10.48 9.48 -1.00 -0.200 0.17108E+04 190 pseudo-wollastonite 11.02 9.48 -1.54 -0.308 0.26294E+04 191 zoisite 22.96 19.32 -3.64 -0.166 0.62236E+04 192 akaganeite 7.77 5.28 -2.49 -0.538 0.42499E+04 199 chalcedony -2.79 -3.21 -0.42 -0.139 0.71124E+03 201 montmorillonite-Ca -2.21 -5.74 -3.53 -0.218 0.60287E+04 202 montmorillonite-K -2.16 -5.86 -3.69 -0.226 0.63076E+04 203 montmorillonite-Mg -2.40 -6.33 -3.93 -0.243 0.67074E+04 204 montmorillonite-Na -1.96 -5.16 -3.20 -0.196 0.54645E+04 205 nontronite-Ca 3.28 1.26 -2.02 -0.131 0.34485E+04 206 nontronite-H 2.60 -0.83 -3.43 -0.230 0.58562E+04 207 nontronite-K 3.40 1.15 -2.25 -0.145 0.38489E+04 208 nontronite-Mg 3.14 0.67 -2.46 -0.160 0.42078E+04 209 nontronite-Na 3.58 1.84 -1.74 -0.112 0.29693E+04 224 tobermorite 9.84 7.36 -2.48 -0.676 0.42319E+04 230 alabandite -0.96 -5.66 -4.70 -1.567 0.80277E+04 233 boehmite 4.43 1.19 -3.24 -0.540 0.55316E+04 235 ferrous-oxide 9.82 6.70 -3.13 -0.782 0.53409E+04 240 silica-amorphous -2.08 -3.21 -1.13 -0.377 0.19314E+04 242 an20ab80 2.08 1.47 -0.61 -0.047 0.10452E+04 243 an25ab75 2.71 1.92 -0.79 -0.061 0.13544E+04 244 an30ab70 3.34 2.36 -0.98 -0.075 0.16719E+04 245 tr.625ac.25prg.125 45.31 43.48 -1.83 -0.049 0.31256E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 59.9990000 g New total amount of reactant added: 61.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1494E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 61.9990000 Water: Moles liquid = 0.5510E+02 kg liquid = 0.9926E+00 Moles total = 0.5473E+02 kg total = 0.9860E+00 Activity = 1.0000 Stoichiometric ionic strength = .8382328E-02 Osmotic coef. = 0.9654 True ionic strength = .1514414E-01 Chg. balance for total moles = -.1494E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.11102E-09 -9.9546 0.94897E-10 -10.0227 0.85480E+00 -0.0681 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13851E-03 -3.8585 0.11783E-03 -3.9287 0.85070E+00 -0.0702 4 SO4-- 0.74837E-06 -6.1259 0.41743E-06 -6.3794 0.55779E+00 -0.2535 5 HCO3- 0.52863E-05 -5.2768 0.45023E-05 -5.3466 0.85169E+00 -0.0697 6 HS- 0.24940E-04 -4.6031 0.21219E-04 -4.6733 0.85080E+00 -0.0702 7 Al+++ 0.45888E-28 -28.3383 0.12485E-28 -28.9036 0.27208E+00 -0.5653 8 H4SiO4 0.62038E-03 -3.2073 0.62038E-03 -3.2073 0.10000E+01 0.0000 9 Ca++ 0.84503E-07 -7.0731 0.46860E-07 -7.3292 0.55454E+00 -0.2561 10 Mg++ 0.23267E-10 -10.6333 0.12856E-10 -10.8909 0.55252E+00 -0.2577 11 Fe++ 0.81468E-13 -13.0890 0.45052E-13 -13.3463 0.55300E+00 -0.2573 12 K+ 0.11817E-03 -3.9275 0.10066E-03 -3.9971 0.85185E+00 -0.0696 13 Na+ 0.15017E-01 -1.8234 0.12773E-01 -1.8937 0.85058E+00 -0.0703 14 Mn++ 0.18363E-10 -10.7361 0.10161E-10 -10.9930 0.55337E+00 -0.2570 15 HPO4-- 0.12850E-06 -6.8911 0.71682E-07 -7.1446 0.55785E+00 -0.2535 16 HSiO3- 0.74977E-02 -2.1251 0.63783E-02 -2.1953 0.85070E+00 -0.0702 17 Ca(HSiO3)+ 0.78600E-08 -8.1046 0.66967E-08 -8.1741 0.85200E+00 -0.0696 18 Mg(HSiO3)+ 0.26836E-11 -11.5713 0.22864E-11 -11.6409 0.85200E+00 -0.0696 19 NaHSiO3,aq 0.12940E-02 -2.8881 0.12940E-02 -2.8881 0.10000E+01 0.0000 20 AlO+ 0.21007E-15 -15.6776 0.17898E-15 -15.7472 0.85200E+00 -0.0696 22 HAlO2,aq 0.37741E-09 -9.4232 0.37741E-09 -9.4232 0.10000E+01 0.0000 23 AlO2- 0.10454E-04 -4.9807 0.88801E-05 -5.0516 0.84948E+00 -0.0708 24 CH4,aq 0.22515E-09 -9.6475 0.22457E-09 -9.6487 0.99743E+00 -0.0011 29 CO,aq 0.71478E-17 -17.1458 0.71478E-17 -17.1458 0.10000E+01 0.0000 30 CO2,aq 0.86364E-09 -9.0637 0.86143E-09 -9.0648 0.99743E+00 -0.0011 31 CO3-2 0.78776E-05 -5.1036 0.43866E-05 -5.3579 0.55684E+00 -0.2543 32 CaCO3,aq 0.25176E-08 -8.5990 0.25176E-08 -8.5990 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.62395E-11 -11.2049 0.53160E-11 -11.2744 0.85200E+00 -0.0696 34 CaCl+ 0.10327E-10 -10.9860 0.87987E-11 -11.0556 0.85200E+00 -0.0696 35 CaCl2,aq 0.24140E-15 -15.6173 0.24140E-15 -15.6173 0.10000E+01 0.0000 36 CaOH+ 0.40868E-07 -7.3886 0.34819E-07 -7.4582 0.85200E+00 -0.0696 37 CaSO4,aq 0.60947E-11 -11.2150 0.60947E-11 -11.2150 0.10000E+01 0.0000 38 HCl,aq 0.21033E-14 -14.6771 0.21033E-14 -14.6771 0.10000E+01 0.0000 43 FeCl+ 0.97045E-17 -17.0130 0.82682E-17 -17.0826 0.85200E+00 -0.0696 46 FeO,aq 0.19783E-09 -9.7037 0.19783E-09 -9.7037 0.10000E+01 0.0000 47 FeOH+ 0.18473E-10 -10.7335 0.15739E-10 -10.8030 0.85200E+00 -0.0696 48 HFeO2- 0.26358E-07 -7.5791 0.22423E-07 -7.6493 0.85070E+00 -0.0702 49 FeO+ 0.79201E-16 -16.1013 0.67479E-16 -16.1708 0.85200E+00 -0.0696 51 FeO2- 0.17312E-08 -8.7617 0.14727E-08 -8.8319 0.85070E+00 -0.0702 52 HFeO2,aq 0.17490E-10 -10.7572 0.17490E-10 -10.7572 0.10000E+01 0.0000 53 H2,aq 0.32300E-06 -6.4908 0.32217E-06 -6.4919 0.99743E+00 -0.0011 54 KCl,aq 0.21002E-09 -9.6777 0.21002E-09 -9.6777 0.10000E+01 0.0000 55 KHSO4,aq 0.10670E-19 -19.9718 0.10670E-19 -19.9718 0.10000E+01 0.0000 56 KOH,aq 0.46243E-06 -6.3350 0.46243E-06 -6.3350 0.10000E+01 0.0000 57 KSO4- 0.76098E-09 -9.1186 0.64736E-09 -9.1889 0.85070E+00 -0.0702 58 MgCO3,aq 0.17259E-12 -12.7630 0.17259E-12 -12.7630 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.17455E-14 -14.7581 0.14872E-14 -14.8276 0.85200E+00 -0.0696 60 MgCl+ 0.25720E-14 -14.5897 0.21913E-14 -14.6593 0.85200E+00 -0.0696 61 MgOH+ 0.62114E-10 -10.2068 0.52921E-10 -10.2764 0.85200E+00 -0.0696 63 MnO,aq 0.11911E-08 -8.9240 0.11911E-08 -8.9240 0.10000E+01 0.0000 64 MnOH+ 0.38706E-09 -9.4122 0.32977E-09 -9.4818 0.85200E+00 -0.0696 65 MnO2-2 0.82145E-11 -11.0854 0.45742E-11 -11.3397 0.55684E+00 -0.2543 66 HMnO2- 0.11055E-09 -9.9564 0.94049E-10 -10.0266 0.85070E+00 -0.0702 69 MnCl+ 0.85054E-14 -14.0703 0.72465E-14 -14.1399 0.85200E+00 -0.0696 70 MnSO4,aq 0.12021E-14 -14.9201 0.12021E-14 -14.9201 0.10000E+01 0.0000 71 NaCl,aq 0.49145E-06 -6.3085 0.49145E-06 -6.3085 0.10000E+01 0.0000 72 NaOH,aq 0.59144E-04 -4.2281 0.59144E-04 -4.2281 0.10000E+01 0.0000 74 OH- 0.74409E-02 -2.1284 0.63209E-02 -2.1992 0.84948E+00 -0.0708 79 HPO3-2 0.13099E-15 -15.8828 0.72942E-16 -16.1370 0.55684E+00 -0.2543 81 H2PO3- 0.15983E-19 -19.7963 0.13597E-19 -19.8666 0.85070E+00 -0.0702 82 H3PO4,aq 0.41559E-17 -17.3813 0.41559E-17 -17.3813 0.10000E+01 0.0000 83 H2PO4- 0.14009E-09 -9.8536 0.11926E-09 -9.9235 0.85134E+00 -0.0699 84 PO4-3 0.23317E-08 -8.6323 0.65966E-09 -9.1807 0.28291E+00 -0.5483 88 HP2O7-3 0.88341E-17 -17.0538 0.24053E-17 -17.6188 0.27228E+00 -0.5650 89 P2O7-4 0.61000E-16 -16.2147 0.62529E-17 -17.2039 0.10251E+00 -0.9892 90 H2S,aq 0.60655E-08 -8.2171 0.60499E-08 -8.2182 0.99743E+00 -0.0011 91 S2-2 0.55196E-13 -13.2581 0.30736E-13 -13.5124 0.55684E+00 -0.2543 97 SO3-2 0.32555E-13 -13.4874 0.18337E-13 -13.7367 0.56325E+00 -0.2493 98 HSO3- 0.11971E-15 -15.9219 0.10183E-15 -15.9921 0.85070E+00 -0.0702 99 HSO4- 0.43107E-13 -13.3655 0.36755E-13 -13.4347 0.85265E+00 -0.0692 101 S2O3-2 0.53450E-16 -16.2720 0.29764E-16 -16.5263 0.55684E+00 -0.2543 Charge balance for all species = -.1532E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1110174E-09 -.1634203E-01 -.1645120E+02 0.0000 2 H2O 0.1000000E+01 0.5550698E+02 0.9987255E+06 0.0000 3 Cl- 0.1385118E-03 0.1390034E-03 0.4921931E+01 6.0940 4 SO4-- 0.7483668E-06 0.6683777E-06 0.6412522E-01 13.6661 5 HCO3- 0.5286280E-05 0.1316750E-04 0.8024400E+00 4.6762 6 HS- 0.2493953E-04 0.2502635E-04 0.8266373E+00 5.3495 7 Al+++ 0.4588803E-28 0.1045400E-04 0.2817121E+00 1.1646 8 H4SiO4 0.6203776E-03 0.9412012E-02 0.9035090E+03 -3.2073 9 Ca++ 0.8450323E-07 0.1357711E-06 0.5434637E-02 12.7163 10 Mg++ 0.2326739E-10 0.8824150E-10 0.2142647E-05 9.1546 11 Fe++ 0.8146850E-13 0.2832292E-07 0.1579774E-02 6.6992 12 K+ 0.1181682E-03 0.1186316E-03 0.4632936E+01 6.0256 13 Na+ 0.1501691E-01 0.1637050E-01 0.3758842E+03 8.1290 14 Mn++ 0.1836275E-10 0.1715323E-08 0.9411865E-04 9.0524 15 HPO4-- 0.1284965E-06 0.1309682E-06 0.1255449E-01 12.9009 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1026598E+01 -.1622102E-01 -.1010377E+01 0.0000000E+00 2 H2O 0.5473107E+02 0.5509598E+02 -.3649128E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1743708E-02 0.6634288E-06 0.1743045E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1718204E-02 0.2484104E-04 -.1743045E-02 0.0000000E+00 7 Al+++ 0.2021627E+00 0.1037659E-04 0.2021523E+00 0.0000000E+00 8 H4SiO4 0.6455821E+00 0.9342321E-02 0.6362398E+00 0.0000000E+00 9 Ca++ 0.7132217E-01 0.1347658E-06 0.7132203E-01 0.0000000E+00 10 Mg++ 0.4920556E-01 0.8758812E-10 0.4920556E-01 0.0000000E+00 11 Fe++ 0.4420582E-01 0.2811320E-07 0.4420579E-01 0.0000000E+00 12 K+ 0.1316327E-01 0.1177532E-03 0.1304552E-01 0.0000000E+00 13 Na+ 0.7798392E-01 0.1624928E-01 0.6173464E-01 0.0000000E+00 14 Mn++ 0.1074976E-02 0.1702622E-08 0.1074974E-02 0.0000000E+00 15 HPO4-- 0.3668838E-03 0.1299985E-06 0.3667538E-03 0.0000000E+00 Chg. balance for solid moles: 0.1571E-15 Mass of aqueous solution: 0.993837E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 61.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6173E-01 -1.209 16.19 1.209 23.92 6.214 andradite 0.6972E-02 -2.157 3.543 0.549 5.236 0.9205 grossular 0.8029E-03 -3.095 0.3617 -0.442 0.5345 0.1006 apatite-OH 0.1223E-03 -3.913 0.6141E-01 -1.212 0.9075E-01 0.1951E-01 clinochlore 0.9841E-02 -2.007 5.470 0.738 8.083 2.081 daphnite 0.3609E-02 -2.443 2.575 0.411 3.806 0.7804 chlorite-Mn 0.2150E-03 -3.668 0.1524 -0.817 0.2252 0.4857E-01 microcline 0.1182E-01 -1.927 3.291 0.517 4.863 1.286 stilbite 0.4739E-01 -1.324 33.39 1.524 49.35 15.58 stilpnomelane-Fe 0.2443E-02 -2.612 2.633 0.421 3.892 0.9097 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8967E+00 0.8967E+00 1.0000 -0.047 grossular 0.1033E+00 0.1033E+00 1.0000 -0.986 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7201E+00 0.7201E+00 1.0000 -0.143 daphnite 0.2641E+00 0.2641E+00 1.0000 -0.578 chlorite-Mn 0.1573E-01 0.1573E-01 1.0000 -1.803 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 67.670058 g Volume = 27.935086 cm3 Porosity: -8.2772% V(tot) - V(min): -.21355E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 61.9990000 g log = 1.7924 Original solution: 1000.0103000 g Original solution / Rock added: 16.13 (Water/Rock Ratio), log = 1.2076 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0524 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9996E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.9302E-07 1.0073 0.9861E-07 0.9789E-07 CH4,gas 0.3331E-06 1.0129 0.3551E-06 0.3506E-06 H2,gas 0.4197E-03 1.0006 0.4419E-03 0.4416E-03 H2S,gas 0.1684E-06 0.9959 0.1764E-06 0.1772E-06 S2,gas 0.5675E-26 1.0000 0.5972E-26 0.5972E-26 CO,gas 0.1072E-13 1.0000 0.1129E-13 0.1129E-13 SO3,gas 0.1335E-41 1.0000 0.1405E-41 0.1405E-41 SO2,gas 0.2232E-22 1.0000 0.2349E-22 0.2349E-22 HCl,gas 0.3529E-17 1.0000 0.3714E-17 0.3714E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.48529E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.66728E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.37 -9.01 -3.002 0.15378E+05 -7.006 3 CH4,gas 4.81 -3.64 -8.45 -2.112 0.14427E+05 -6.450 4 H2,gas 8.29 2.93 -5.35 -3.060 0.91430E+04 -3.355 5 H2S,gas -5.94 -14.70 -8.75 -4.377 0.14946E+05 -6.753 6 S2,gas -7.03 -35.26 -28.22 -4.342 0.48191E+05 -26.224 7 CO,gas 3.51 -12.44 -15.95 -4.907 0.27230E+05 -13.947 8 SO3,gas 17.43 -26.42 -43.85 -10.963 0.74876E+05 -41.852 9 SO2,gas 1.14 -23.49 -24.63 -6.568 0.42053E+05 -22.629 10 HCl,gas 5.48 -13.95 -19.43 -9.715 0.33177E+05 -17.430 11 acmite 7.74 6.95 -0.79 -0.082 0.13488E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.86 -4.69 -0.234 0.80001E+04 20 analcite 3.37 2.88 -0.49 -0.055 0.83949E+03 26 annite 20.21 17.67 -2.54 -0.141 0.43429E+04 27 phlogopite 27.15 25.03 -2.11 -0.117 0.36107E+04 29 anorthite 12.80 8.63 -4.17 -0.321 0.71147E+04 35 aragonite 0.99 -2.65 -3.64 -1.213 0.62139E+04 36 brucite 12.58 9.15 -3.42 -0.684 0.58430E+04 37 calcite 0.83 -2.65 -3.49 -1.162 0.59526E+04 38 carnegieite-low 9.06 6.09 -2.98 -0.425 0.50852E+04 39 carnegieite-high 10.13 6.09 -4.05 -0.578 0.69121E+04 40 carpholite-Mg 8.65 5.07 -3.58 -0.239 0.61148E+04 41 carpholite-Fe 6.78 2.61 -4.17 -0.278 0.71187E+04 42 celadonite 5.40 3.52 -1.89 -0.111 0.32187E+04 43 celadonite-Fe 3.94 1.06 -2.88 -0.169 0.49122E+04 44 chrysotile 23.94 21.05 -2.89 -0.241 0.49316E+04 50 chloritoid-Mg 13.26 8.28 -4.98 -0.332 0.85113E+04 51 chloritoid-Fe 9.24 5.82 -3.42 -0.228 0.58354E+04 52 chloritoid-Mn 11.46 8.17 -3.29 -0.219 0.56156E+04 54 coesite -2.37 -3.21 -0.84 -0.279 0.14309E+04 61 cristobalite -2.55 -3.21 -0.66 -0.219 0.11237E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.16 -1.73 -0.289 0.29564E+04 67 diopside 16.22 15.46 -0.76 -0.076 0.12964E+04 68 hedenbergite 14.24 13.00 -1.24 -0.124 0.21234E+04 75 epidote 24.78 23.37 -1.40 -0.068 0.23944E+04 76 clinozoisite 22.92 19.30 -3.62 -0.164 0.61754E+04 77 epidote-Fe 29.94 27.44 -2.50 -0.130 0.42608E+04 78 fayalite 14.08 10.19 -3.89 -0.555 0.66385E+04 79 ferrosilite 11.19 6.98 -4.20 -0.420 0.71781E+04 83 gibbsite 4.10 1.16 -2.93 -0.419 0.50076E+04 84 glaucophane 23.11 20.39 -2.72 -0.073 0.46412E+04 85 glaucophane-Fe 17.42 13.03 -4.39 -0.119 0.74975E+04 87 greenalite 16.19 13.68 -2.51 -0.209 0.42879E+04 90 hematite 12.60 10.47 -2.13 -0.258 0.36393E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.88 -1.37 -0.137 0.23425E+04 96 julgoldite 70.57 65.95 -4.62 -0.120 0.78901E+04 97 kalsilite 7.62 3.98 -3.64 -0.520 0.62107E+04 98 kaolinite -1.27 -4.09 -2.81 -0.256 0.48019E+04 101 laumontite 2.97 2.22 -0.76 -0.051 0.12949E+04 102 lawsonite 9.68 8.63 -1.05 -0.070 0.17886E+04 103 leucite 4.17 0.78 -3.39 -0.339 0.57919E+04 105 lizardite 23.29 21.05 -2.24 -0.187 0.38219E+04 107 magnetite 20.13 17.17 -2.97 -0.242 0.50667E+04 108 minnesotaite 10.46 7.27 -3.19 -0.188 0.54511E+04 120 muscovite 2.68 -0.10 -2.78 -0.164 0.47497E+04 121 paragonite 4.34 2.00 -2.34 -0.137 0.39882E+04 122 nepheline 8.38 6.09 -2.29 -0.327 0.39132E+04 128 periclase-Fe 11.64 6.70 -4.94 -1.235 0.84348E+04 134 phlogopite-Na 29.73 27.14 -2.60 -0.144 0.44326E+04 136 prehnite 19.47 18.14 -1.33 -0.078 0.22650E+04 137 prehnite-Fe 22.59 22.21 -0.38 -0.023 0.64623E+03 138 pumpellyite-Fe 46.47 44.14 -2.33 -0.052 0.39734E+04 139 pumpellyite-Mg 49.19 46.60 -2.60 -0.058 0.44312E+04 142 pyrite -21.23 -25.63 -4.40 -1.035 0.75124E+04 143 pyrrhotite -4.24 -8.00 -3.75 -1.251 0.64086E+04 144 pyrrhotiteFe0.875 -6.00 -9.20 -3.20 -1.176 0.54585E+04 145 pyroxmangite 7.42 5.85 -1.57 -0.314 0.26823E+04 146 pyrophyllite -6.10 -10.50 -4.40 -0.275 0.75165E+04 147 quartz -2.98 -3.21 -0.23 -0.075 0.38477E+03 152 rhodonite 7.46 5.85 -1.62 -0.323 0.27616E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.46 -2.14 -0.064 0.36540E+04 171 talc 16.55 14.63 -1.92 -0.113 0.32766E+04 174 tephroite 18.11 14.90 -3.22 -0.459 0.54901E+04 178 tridymite -2.61 -3.21 -0.59 -0.198 0.10121E+04 179 tremolite 48.00 45.55 -2.46 -0.066 0.41942E+04 181 troilite-low -4.39 -8.00 -3.60 -1.201 0.61518E+04 187 wairakite 4.06 2.22 -1.84 -0.108 0.31457E+04 188 walstromite 11.53 9.51 -2.02 -0.404 0.34472E+04 189 wollastonite 10.48 9.51 -0.97 -0.195 0.16611E+04 190 pseudo-wollastonite 11.02 9.51 -1.51 -0.302 0.25798E+04 191 zoisite 22.96 19.30 -3.66 -0.166 0.62480E+04 192 akaganeite 7.77 5.23 -2.53 -0.548 0.43278E+04 199 chalcedony -2.79 -3.21 -0.41 -0.138 0.70509E+03 201 montmorillonite-Ca -2.21 -5.77 -3.55 -0.220 0.60636E+04 202 montmorillonite-K -2.16 -5.87 -3.71 -0.227 0.63416E+04 203 montmorillonite-Mg -2.40 -6.35 -3.95 -0.244 0.67467E+04 204 montmorillonite-Na -1.96 -5.18 -3.22 -0.197 0.54984E+04 205 nontronite-Ca 3.28 1.18 -2.10 -0.136 0.35889E+04 206 nontronite-H 2.60 -0.92 -3.52 -0.236 0.60037E+04 207 nontronite-K 3.40 1.07 -2.34 -0.150 0.39883E+04 208 nontronite-Mg 3.14 0.59 -2.55 -0.165 0.43526E+04 209 nontronite-Na 3.58 1.76 -1.82 -0.117 0.31087E+04 224 tobermorite 9.84 7.39 -2.45 -0.669 0.41896E+04 230 alabandite -0.96 -5.64 -4.68 -1.560 0.79930E+04 233 boehmite 4.43 1.16 -3.26 -0.544 0.55749E+04 235 ferrous-oxide 9.82 6.70 -3.13 -0.781 0.53359E+04 240 silica-amorphous -2.08 -3.21 -1.13 -0.376 0.19253E+04 242 an20ab80 2.08 1.46 -0.62 -0.047 0.10513E+04 243 an25ab75 2.71 1.91 -0.80 -0.061 0.13621E+04 244 an30ab70 3.34 2.36 -0.98 -0.076 0.16812E+04 245 tr.625ac.25prg.125 45.31 43.59 -1.72 -0.046 0.29372E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 61.9990000 g New total amount of reactant added: 63.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1495E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 63.9990000 Water: Moles liquid = 0.5508E+02 kg liquid = 0.9924E+00 Moles total = 0.5471E+02 kg total = 0.9855E+00 Activity = 1.0000 Stoichiometric ionic strength = .8557123E-02 Osmotic coef. = 0.9655 True ionic strength = .1544223E-01 Chg. balance for total moles = -.1495E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10955E-09 -9.9604 0.93537E-10 -10.0290 0.85384E+00 -0.0686 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13853E-03 -3.8584 0.11771E-03 -3.9292 0.84969E+00 -0.0707 4 SO4-- 0.32250E-06 -6.4915 0.17906E-06 -6.7470 0.55520E+00 -0.2555 5 HCO3- 0.52307E-05 -5.2814 0.44497E-05 -5.3517 0.85069E+00 -0.0702 6 HS- 0.25372E-04 -4.5957 0.21560E-04 -4.6663 0.84979E+00 -0.0707 7 Al+++ 0.41919E-28 -28.3776 0.11285E-28 -28.9475 0.26920E+00 -0.5699 8 H4SiO4 0.62556E-03 -3.2037 0.62556E-03 -3.2037 0.10000E+01 0.0000 9 Ca++ 0.87345E-07 -7.0588 0.48207E-07 -7.3169 0.55192E+00 -0.2581 10 Mg++ 0.23224E-10 -10.6341 0.12771E-10 -10.8938 0.54988E+00 -0.2597 11 Fe++ 0.80047E-13 -13.0967 0.44055E-13 -13.3560 0.55036E+00 -0.2593 12 K+ 0.12050E-03 -3.9190 0.10252E-03 -3.9892 0.85085E+00 -0.0701 13 Na+ 0.15313E-01 -1.8149 0.13009E-01 -1.8857 0.84957E+00 -0.0708 14 Mn++ 0.18328E-10 -10.7369 0.10094E-10 -10.9959 0.55073E+00 -0.2591 15 HPO4-- 0.12079E-06 -6.9180 0.67071E-07 -7.1735 0.55527E+00 -0.2555 16 HSiO3- 0.76795E-02 -2.1147 0.65252E-02 -2.1854 0.84969E+00 -0.0707 17 Ca(HSiO3)+ 0.82818E-08 -8.0819 0.70478E-08 -8.1519 0.85100E+00 -0.0701 18 Mg(HSiO3)+ 0.27304E-11 -11.5638 0.23235E-11 -11.6339 0.85100E+00 -0.0701 19 NaHSiO3,aq 0.13482E-02 -2.8702 0.13482E-02 -2.8702 0.10000E+01 0.0000 20 AlO+ 0.19566E-15 -15.7085 0.16651E-15 -15.7786 0.85100E+00 -0.0701 22 HAlO2,aq 0.35623E-09 -9.4483 0.35623E-09 -9.4483 0.10000E+01 0.0000 23 AlO2- 0.10023E-04 -4.9990 0.85038E-05 -5.0704 0.84845E+00 -0.0714 24 CH4,aq 0.52714E-09 -9.2781 0.52576E-09 -9.2792 0.99738E+00 -0.0011 29 CO,aq 0.86696E-17 -17.0620 0.86696E-17 -17.0620 0.10000E+01 0.0000 30 CO2,aq 0.84136E-09 -9.0750 0.83916E-09 -9.0762 0.99738E+00 -0.0011 31 CO3-2 0.79358E-05 -5.1004 0.43984E-05 -5.3567 0.55425E+00 -0.2563 32 CaCO3,aq 0.25969E-08 -8.5855 0.25969E-08 -8.5855 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.63513E-11 -11.1971 0.54049E-11 -11.2672 0.85100E+00 -0.0701 34 CaCl+ 0.10625E-10 -10.9737 0.90423E-11 -11.0437 0.85100E+00 -0.0701 35 CaCl2,aq 0.24783E-15 -15.6059 0.24783E-15 -15.6059 0.10000E+01 0.0000 36 CaOH+ 0.42704E-07 -7.3695 0.36341E-07 -7.4396 0.85100E+00 -0.0701 37 CaSO4,aq 0.26895E-11 -11.5703 0.26895E-11 -11.5703 0.10000E+01 0.0000 38 HCl,aq 0.20710E-14 -14.6838 0.20710E-14 -14.6838 0.10000E+01 0.0000 43 FeCl+ 0.94910E-17 -17.0227 0.80769E-17 -17.0928 0.85100E+00 -0.0701 46 FeO,aq 0.19912E-09 -9.7009 0.19912E-09 -9.7009 0.10000E+01 0.0000 47 FeOH+ 0.18348E-10 -10.7364 0.15615E-10 -10.8065 0.85100E+00 -0.0701 48 HFeO2- 0.26948E-07 -7.5695 0.22897E-07 -7.6402 0.84969E+00 -0.0707 49 FeO+ 0.70500E-16 -16.1518 0.59995E-16 -16.2219 0.85100E+00 -0.0701 51 FeO2- 0.15862E-08 -8.7997 0.13477E-08 -8.8704 0.84969E+00 -0.0707 52 HFeO2,aq 0.15777E-10 -10.8020 0.15777E-10 -10.8020 0.10000E+01 0.0000 53 H2,aq 0.40219E-06 -6.3956 0.40113E-06 -6.3967 0.99738E+00 -0.0011 54 KCl,aq 0.21369E-09 -9.6702 0.21369E-09 -9.6702 0.10000E+01 0.0000 56 KOH,aq 0.47784E-06 -6.3207 0.47784E-06 -6.3207 0.10000E+01 0.0000 57 KSO4- 0.33285E-09 -9.4777 0.28282E-09 -9.5485 0.84969E+00 -0.0707 58 MgCO3,aq 0.17191E-12 -12.7647 0.17191E-12 -12.7647 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.17157E-14 -14.7656 0.14601E-14 -14.8356 0.85100E+00 -0.0701 60 MgCl+ 0.25553E-14 -14.5926 0.21746E-14 -14.6626 0.85100E+00 -0.0701 61 MgOH+ 0.62673E-10 -10.2029 0.53335E-10 -10.2730 0.85100E+00 -0.0701 63 MnO,aq 0.12179E-08 -8.9144 0.12179E-08 -8.9144 0.10000E+01 0.0000 64 MnOH+ 0.39054E-09 -9.4083 0.33235E-09 -9.4784 0.85100E+00 -0.0701 65 MnO2-2 0.86859E-11 -11.0612 0.48141E-11 -11.3175 0.55425E+00 -0.2563 66 HMnO2- 0.11482E-09 -9.9400 0.97563E-10 -10.0107 0.84969E+00 -0.0707 69 MnCl+ 0.84502E-14 -14.0731 0.71911E-14 -14.1432 0.85100E+00 -0.0701 70 MnSO4,aq 0.51221E-15 -15.2905 0.51221E-15 -15.2905 0.10000E+01 0.0000 71 NaCl,aq 0.50003E-06 -6.3010 0.50003E-06 -6.3010 0.10000E+01 0.0000 72 NaOH,aq 0.61114E-04 -4.2139 0.61114E-04 -4.2139 0.10000E+01 0.0000 74 OH- 0.75583E-02 -2.1216 0.64128E-02 -2.1930 0.84845E+00 -0.0714 79 HPO3-2 0.15332E-15 -15.8144 0.84978E-16 -16.0707 0.55425E+00 -0.2563 81 H2PO3- 0.18376E-19 -19.7358 0.15614E-19 -19.8065 0.84969E+00 -0.0707 82 H3PO4,aq 0.37778E-17 -17.4228 0.37778E-17 -17.4228 0.10000E+01 0.0000 83 H2PO4- 0.12935E-09 -9.8882 0.10999E-09 -9.9587 0.85034E+00 -0.0704 84 PO4-3 0.22356E-08 -8.6506 0.62621E-09 -9.2033 0.28010E+00 -0.5527 88 HP2O7-3 0.77044E-17 -17.1133 0.20756E-17 -17.6829 0.26941E+00 -0.5696 89 P2O7-4 0.54402E-16 -16.2644 0.54743E-17 -17.2617 0.10063E+00 -0.9973 90 H2S,aq 0.60752E-08 -8.2164 0.60593E-08 -8.2176 0.99738E+00 -0.0011 91 S2-2 0.45986E-13 -13.3374 0.25488E-13 -13.5937 0.55425E+00 -0.2563 97 SO3-2 0.17465E-13 -13.7578 0.97932E-14 -14.0091 0.56073E+00 -0.2512 98 HSO3- 0.63091E-16 -16.2000 0.53607E-16 -16.2708 0.84969E+00 -0.0707 99 HSO4- 0.18247E-13 -13.7388 0.15540E-13 -13.8085 0.85167E+00 -0.0697 101 S2O3-2 0.23070E-16 -16.6369 0.12787E-16 -16.8932 0.55425E+00 -0.2563 Charge balance for all species = -.1517E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1095477E-09 -.1669590E-01 -.1680695E+02 0.0000 2 H2O 0.1000000E+01 0.5550686E+02 0.9986946E+06 0.0000 3 Cl- 0.1385347E-03 0.1390350E-03 0.4922906E+01 6.0998 4 SO4-- 0.3225031E-06 0.2219654E-06 0.2129510E-01 13.3110 5 HCO3- 0.5230685E-05 0.1317049E-04 0.8025990E+00 4.6773 6 HS- 0.2537164E-04 0.2547859E-04 0.8415509E+00 5.3627 7 Al+++ 0.4191900E-28 0.1002313E-04 0.2700933E+00 1.1395 8 H4SiO4 0.6255633E-03 0.9653298E-02 0.9266446E+03 -3.2037 9 Ca++ 0.8734492E-07 0.1409472E-06 0.5641662E-02 12.7411 10 Mg++ 0.2322426E-10 0.8880358E-10 0.2156233E-05 9.1642 11 Fe++ 0.8004697E-13 0.2876740E-07 0.1604520E-02 6.7020 12 K+ 0.1204955E-03 0.1209738E-03 0.4724273E+01 6.0398 13 Na+ 0.1531303E-01 0.1672289E-01 0.3839644E+03 8.1433 14 Mn++ 0.1832826E-10 0.1750293E-08 0.9603466E-04 9.0621 15 HPO4-- 0.1207898E-06 0.1231547E-06 0.1180516E-01 12.8846 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1059715E+01 -.1656851E-01 -.1043147E+01 0.0000000E+00 2 H2O 0.5470600E+02 0.5508336E+02 -.3773675E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1799135E-02 0.2202719E-06 0.1798915E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1773630E-02 0.2528420E-04 -.1798915E-02 0.0000000E+00 7 Al+++ 0.2086842E+00 0.9946653E-05 0.2086743E+00 0.0000000E+00 8 H4SiO4 0.6664077E+00 0.9579646E-02 0.6568281E+00 0.0000000E+00 9 Ca++ 0.7362245E-01 0.1398718E-06 0.7362231E-01 0.0000000E+00 10 Mg++ 0.5079286E-01 0.8812604E-10 0.5079286E-01 0.0000000E+00 11 Fe++ 0.4563184E-01 0.2854792E-07 0.4563181E-01 0.0000000E+00 12 K+ 0.1358790E-01 0.1200509E-03 0.1346785E-01 0.0000000E+00 13 Na+ 0.8049441E-01 0.1659530E-01 0.6389911E-01 0.0000000E+00 14 Mn++ 0.1109653E-02 0.1736938E-08 0.1109651E-02 0.0000000E+00 15 HPO4-- 0.3787190E-03 0.1222151E-06 0.3785968E-03 0.0000000E+00 Chg. balance for solid moles: 0.1063E-16 Mass of aqueous solution: 0.993640E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 63.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6390E-01 -1.195 16.76 1.224 23.99 6.432 andradite 0.7196E-02 -2.143 3.657 0.563 5.235 0.9500 grossular 0.8671E-03 -3.062 0.3906 -0.408 0.5592 0.1087 apatite-OH 0.1262E-03 -3.899 0.6339E-01 -1.198 0.9075E-01 0.2014E-01 clinochlore 0.1016E-01 -1.993 5.646 0.752 8.084 2.148 daphnite 0.3668E-02 -2.436 2.617 0.418 3.746 0.7930 chlorite-Mn 0.2219E-03 -3.654 0.1573 -0.803 0.2253 0.5014E-01 microcline 0.1218E-01 -1.914 3.390 0.530 4.853 1.324 stilbite 0.4880E-01 -1.312 34.39 1.536 49.24 16.04 stilpnomelane-Fe 0.2580E-02 -2.588 2.782 0.444 3.982 0.9609 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8925E+00 0.8925E+00 1.0000 -0.049 grossular 0.1075E+00 0.1075E+00 1.0000 -0.968 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7231E+00 0.7231E+00 1.0000 -0.141 daphnite 0.2611E+00 0.2611E+00 1.0000 -0.583 chlorite-Mn 0.1580E-01 0.1580E-01 1.0000 -1.801 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 69.850687 g Volume = 28.828023 cm3 Porosity: -8.3777% V(tot) - V(min): -.22284E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 63.9990000 g log = 1.8062 Original solution: 1000.0103000 g Original solution / Rock added: 15.63 (Water/Rock Ratio), log = 1.1938 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0525 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9995E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.9060E-07 1.0073 0.9606E-07 0.9536E-07 CH4,gas 0.7799E-06 1.0129 0.8314E-06 0.8208E-06 H2,gas 0.5225E-03 1.0006 0.5502E-03 0.5499E-03 H2S,gas 0.1686E-06 0.9959 0.1767E-06 0.1774E-06 S2,gas 0.3672E-26 1.0000 0.3864E-26 0.3864E-26 CO,gas 0.1301E-13 1.0000 0.1369E-13 0.1369E-13 SO3,gas 0.5565E-42 1.0000 0.5857E-42 0.5857E-42 SO2,gas 0.1158E-22 1.0000 0.1219E-22 0.1219E-22 HCl,gas 0.3474E-17 1.0000 0.3657E-17 0.3657E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.38 -9.02 -3.006 0.15397E+05 -7.017 3 CH4,gas 4.81 -3.27 -8.08 -2.020 0.13797E+05 -6.080 4 H2,gas 8.29 3.03 -5.26 -3.005 0.89804E+04 -3.259 5 H2S,gas -5.94 -14.70 -8.75 -4.376 0.14945E+05 -6.753 6 S2,gas -7.03 -35.45 -28.41 -4.371 0.48514E+05 -26.413 7 CO,gas 3.51 -12.35 -15.86 -4.881 0.27087E+05 -13.864 8 SO3,gas 17.43 -26.81 -44.23 -11.058 0.75526E+05 -42.232 9 SO2,gas 1.14 -23.78 -24.91 -6.644 0.42540E+05 -22.914 10 HCl,gas 5.48 -13.96 -19.44 -9.718 0.33188E+05 -17.437 11 acmite 7.74 6.92 -0.81 -0.084 0.13886E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.85 -4.70 -0.235 0.80178E+04 20 analcite 3.37 2.88 -0.50 -0.055 0.84566E+03 26 annite 20.21 17.67 -2.54 -0.141 0.43285E+04 27 phlogopite 27.15 25.06 -2.09 -0.116 0.35612E+04 29 anorthite 12.80 8.61 -4.18 -0.322 0.71456E+04 35 aragonite 0.99 -2.64 -3.63 -1.209 0.61909E+04 36 brucite 12.58 9.16 -3.41 -0.682 0.58265E+04 37 calcite 0.83 -2.64 -3.47 -1.158 0.59296E+04 38 carnegieite-low 9.06 6.08 -2.99 -0.426 0.50976E+04 39 carnegieite-high 10.13 6.08 -4.06 -0.579 0.69244E+04 40 carpholite-Mg 8.65 5.04 -3.61 -0.241 0.61716E+04 41 carpholite-Fe 6.78 2.57 -4.21 -0.281 0.71871E+04 42 celadonite 5.40 3.53 -1.87 -0.110 0.31960E+04 43 celadonite-Fe 3.94 1.07 -2.87 -0.169 0.49012E+04 44 chrysotile 23.94 21.09 -2.85 -0.238 0.48698E+04 51 chloritoid-Fe 9.24 5.78 -3.46 -0.231 0.59100E+04 52 chloritoid-Mn 11.46 8.14 -3.33 -0.222 0.56786E+04 54 coesite -2.37 -3.20 -0.83 -0.278 0.14247E+04 61 cristobalite -2.55 -3.20 -0.65 -0.218 0.11176E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.14 -1.76 -0.293 0.29992E+04 67 diopside 16.22 15.50 -0.72 -0.072 0.12252E+04 68 hedenbergite 14.24 13.04 -1.21 -0.121 0.20638E+04 75 epidote 24.78 23.34 -1.44 -0.070 0.24531E+04 76 clinozoisite 22.92 19.29 -3.63 -0.165 0.62005E+04 77 epidote-Fe 29.94 27.39 -2.55 -0.132 0.43531E+04 78 fayalite 14.08 10.20 -3.88 -0.554 0.66226E+04 79 ferrosilite 11.19 7.00 -4.19 -0.419 0.71562E+04 83 gibbsite 4.10 1.14 -2.96 -0.423 0.50504E+04 84 glaucophane 23.11 20.43 -2.68 -0.072 0.45794E+04 85 glaucophane-Fe 17.42 13.04 -4.38 -0.118 0.74706E+04 87 greenalite 16.19 13.70 -2.50 -0.208 0.42611E+04 90 hematite 12.60 10.38 -2.22 -0.269 0.37922E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.88 -1.38 -0.138 0.23487E+04 96 julgoldite 70.57 65.90 -4.67 -0.121 0.79795E+04 97 kalsilite 7.62 3.98 -3.64 -0.521 0.62230E+04 98 kaolinite -1.27 -4.13 -2.86 -0.260 0.48752E+04 101 laumontite 2.97 2.21 -0.77 -0.051 0.13134E+04 102 lawsonite 9.68 8.61 -1.07 -0.071 0.18195E+04 103 leucite 4.17 0.77 -3.40 -0.340 0.57981E+04 105 lizardite 23.29 21.09 -2.20 -0.184 0.37601E+04 107 magnetite 20.13 17.08 -3.05 -0.249 0.52148E+04 108 minnesotaite 10.46 7.29 -3.17 -0.186 0.54119E+04 120 muscovite 2.68 -0.15 -2.83 -0.167 0.48354E+04 121 paragonite 4.34 1.95 -2.39 -0.140 0.40738E+04 122 nepheline 8.38 6.08 -2.30 -0.328 0.39255E+04 128 periclase-Fe 11.64 6.70 -4.94 -1.234 0.84300E+04 134 phlogopite-Na 29.73 27.16 -2.57 -0.143 0.43831E+04 136 prehnite 19.47 18.15 -1.32 -0.077 0.22472E+04 137 prehnite-Fe 22.59 22.20 -0.39 -0.023 0.66212E+03 138 pumpellyite-Fe 46.47 44.14 -2.33 -0.052 0.39760E+04 139 pumpellyite-Mg 49.19 46.60 -2.59 -0.058 0.44221E+04 142 pyrite -21.23 -25.72 -4.49 -1.057 0.76679E+04 143 pyrrhotite -4.24 -7.99 -3.75 -1.250 0.64026E+04 144 pyrrhotiteFe0.875 -6.00 -9.21 -3.21 -1.179 0.54733E+04 145 pyroxmangite 7.42 5.86 -1.56 -0.312 0.26597E+04 146 pyrophyllite -6.10 -10.54 -4.44 -0.277 0.75774E+04 147 quartz -2.98 -3.20 -0.22 -0.074 0.37860E+03 152 rhodonite 7.46 5.86 -1.60 -0.321 0.27389E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.49 -2.11 -0.063 0.35957E+04 171 talc 16.55 14.68 -1.88 -0.110 0.32024E+04 174 tephroite 18.11 14.92 -3.19 -0.456 0.54510E+04 178 tridymite -2.61 -3.20 -0.59 -0.196 0.10059E+04 179 tremolite 48.00 45.67 -2.33 -0.063 0.39775E+04 181 troilite-low -4.39 -7.99 -3.60 -1.200 0.61458E+04 187 wairakite 4.06 2.21 -1.85 -0.109 0.31642E+04 188 walstromite 11.53 9.54 -1.99 -0.398 0.33986E+04 189 wollastonite 10.48 9.54 -0.94 -0.189 0.16125E+04 190 pseudo-wollastonite 11.02 9.54 -1.48 -0.296 0.25312E+04 191 zoisite 22.96 19.29 -3.67 -0.167 0.62730E+04 192 akaganeite 7.77 5.19 -2.58 -0.558 0.44043E+04 199 chalcedony -2.79 -3.20 -0.41 -0.136 0.69891E+03 201 montmorillonite-Ca -2.21 -5.79 -3.57 -0.221 0.60980E+04 202 montmorillonite-K -2.16 -5.89 -3.73 -0.229 0.63749E+04 203 montmorillonite-Mg -2.40 -6.38 -3.97 -0.246 0.67854E+04 204 montmorillonite-Na -1.96 -5.20 -3.24 -0.198 0.55318E+04 205 nontronite-Ca 3.28 1.10 -2.18 -0.142 0.37263E+04 206 nontronite-H 2.60 -1.00 -3.60 -0.241 0.61481E+04 207 nontronite-K 3.40 0.99 -2.42 -0.155 0.41247E+04 208 nontronite-Mg 3.14 0.51 -2.63 -0.171 0.44943E+04 209 nontronite-Na 3.58 1.68 -1.90 -0.122 0.32451E+04 224 tobermorite 9.84 7.41 -2.43 -0.663 0.41481E+04 230 alabandite -0.96 -5.63 -4.67 -1.557 0.79754E+04 233 boehmite 4.43 1.14 -3.29 -0.548 0.56177E+04 235 ferrous-oxide 9.82 6.70 -3.12 -0.781 0.53311E+04 240 silica-amorphous -2.08 -3.20 -1.12 -0.375 0.19191E+04 242 an20ab80 2.08 1.46 -0.62 -0.048 0.10575E+04 243 an25ab75 2.71 1.91 -0.80 -0.062 0.13698E+04 244 an30ab70 3.34 2.35 -0.99 -0.076 0.16904E+04 245 tr.625ac.25prg.125 45.31 43.70 -1.61 -0.043 0.27517E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 63.9990000 g New total amount of reactant added: 65.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1493E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 65.9990000 Water: Moles liquid = 0.5507E+02 kg liquid = 0.9921E+00 Moles total = 0.5468E+02 kg total = 0.9851E+00 Activity = 1.0000 Stoichiometric ionic strength = .8731345E-02 Osmotic coef. = 0.9653 True ionic strength = .1573774E-01 Chg. balance for total moles = -.1493E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10816E-09 -9.9659 0.92250E-10 -10.0350 0.85291E+00 -0.0691 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13856E-03 -3.8584 0.11759E-03 -3.9296 0.84869E+00 -0.0712 4 SO4-- 0.14173E-06 -6.8485 0.78333E-07 -7.1061 0.55269E+00 -0.2575 5 HCO3- 0.51772E-05 -5.2859 0.43991E-05 -5.3566 0.84971E+00 -0.0707 6 HS- 0.25558E-04 -4.5925 0.21694E-04 -4.6637 0.84880E+00 -0.0712 7 Al+++ 0.38392E-28 -28.4158 0.10229E-28 -28.9902 0.26642E+00 -0.5744 8 H4SiO4 0.63081E-03 -3.2001 0.63081E-03 -3.2001 0.10000E+01 0.0000 9 Ca++ 0.90176E-07 -7.0449 0.49539E-07 -7.3050 0.54936E+00 -0.2601 10 Mg++ 0.23194E-10 -10.6346 0.12694E-10 -10.8964 0.54730E+00 -0.2618 11 Fe++ 0.78708E-13 -13.1040 0.43116E-13 -13.3654 0.54779E+00 -0.2614 12 K+ 0.12280E-03 -3.9108 0.10437E-03 -3.9814 0.84988E+00 -0.0706 13 Na+ 0.15606E-01 -1.8067 0.13243E-01 -1.8780 0.84857E+00 -0.0713 14 Mn++ 0.18304E-10 -10.7375 0.10034E-10 -10.9985 0.54817E+00 -0.2611 15 HPO4-- 0.11383E-06 -6.9438 0.62919E-07 -7.2012 0.55275E+00 -0.2575 16 HSiO3- 0.78611E-02 -2.1045 0.66717E-02 -2.1758 0.84869E+00 -0.0712 17 Ca(HSiO3)+ 0.87117E-08 -8.0599 0.74052E-08 -8.1305 0.85003E+00 -0.0706 18 Mg(HSiO3)+ 0.27781E-11 -11.5562 0.23615E-11 -11.6268 0.85003E+00 -0.0706 19 NaHSiO3,aq 0.14033E-02 -2.8529 0.14033E-02 -2.8529 0.10000E+01 0.0000 20 AlO+ 0.18254E-15 -15.7386 0.15517E-15 -15.8092 0.85003E+00 -0.0706 22 HAlO2,aq 0.33659E-09 -9.4729 0.33659E-09 -9.4729 0.10000E+01 0.0000 23 AlO2- 0.96138E-05 -5.0171 0.81471E-05 -5.0890 0.84744E+00 -0.0719 24 CH4,aq 0.11987E-08 -8.9213 0.11955E-08 -8.9225 0.99733E+00 -0.0012 29 CO,aq 0.10446E-16 -16.9810 0.10446E-16 -16.9810 0.10000E+01 0.0000 30 CO2,aq 0.82041E-09 -9.0860 0.81821E-09 -9.0871 0.99733E+00 -0.0012 31 CO3-2 0.79916E-05 -5.0974 0.44091E-05 -5.3556 0.55172E+00 -0.2583 32 CaCO3,aq 0.26752E-08 -8.5726 0.26752E-08 -8.5726 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.64600E-11 -11.1898 0.54912E-11 -11.2603 0.85003E+00 -0.0706 34 CaCl+ 0.10921E-10 -10.9618 0.92829E-11 -11.0323 0.85003E+00 -0.0706 35 CaCl2,aq 0.25417E-15 -15.5949 0.25417E-15 -15.5949 0.10000E+01 0.0000 36 CaOH+ 0.44547E-07 -7.3512 0.37866E-07 -7.4217 0.85003E+00 -0.0706 37 CaSO4,aq 0.12091E-11 -11.9175 0.12091E-11 -11.9175 0.10000E+01 0.0000 38 HCl,aq 0.20405E-14 -14.6903 0.20405E-14 -14.6903 0.10000E+01 0.0000 43 FeCl+ 0.92900E-17 -17.0320 0.78968E-17 -17.1025 0.85003E+00 -0.0706 46 FeO,aq 0.20035E-09 -9.6982 0.20035E-09 -9.6982 0.10000E+01 0.0000 47 FeOH+ 0.18229E-10 -10.7392 0.15495E-10 -10.8098 0.85003E+00 -0.0706 48 HFeO2- 0.27525E-07 -7.5603 0.23360E-07 -7.6315 0.84869E+00 -0.0712 49 FeO+ 0.63005E-16 -16.2006 0.53556E-16 -16.2712 0.85003E+00 -0.0706 51 FeO2- 0.14574E-08 -8.8364 0.12369E-08 -8.9077 0.84869E+00 -0.0712 52 HFeO2,aq 0.14280E-10 -10.8453 0.14280E-10 -10.8453 0.10000E+01 0.0000 53 H2,aq 0.49703E-06 -6.3036 0.49570E-06 -6.3048 0.99733E+00 -0.0012 54 KCl,aq 0.21731E-09 -9.6629 0.21731E-09 -9.6629 0.10000E+01 0.0000 56 KOH,aq 0.49320E-06 -6.3070 0.49320E-06 -6.3070 0.10000E+01 0.0000 57 KSO4- 0.14841E-09 -9.8285 0.12595E-09 -9.8998 0.84869E+00 -0.0712 58 MgCO3,aq 0.17129E-12 -12.7663 0.17129E-12 -12.7663 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16880E-14 -14.7726 0.14348E-14 -14.8432 0.85003E+00 -0.0706 60 MgCl+ 0.25404E-14 -14.5951 0.21594E-14 -14.6657 0.85003E+00 -0.0706 61 MgOH+ 0.63239E-10 -10.1990 0.53755E-10 -10.2696 0.85003E+00 -0.0706 63 MnO,aq 0.12446E-08 -8.9050 0.12446E-08 -8.9050 0.10000E+01 0.0000 64 MnOH+ 0.39407E-09 -9.4044 0.33497E-09 -9.4750 0.85003E+00 -0.0706 65 MnO2-2 0.91677E-11 -11.0377 0.50580E-11 -11.2960 0.55172E+00 -0.2583 66 HMnO2- 0.11912E-09 -9.9240 0.10109E-09 -9.9953 0.84869E+00 -0.0712 69 MnCl+ 0.84009E-14 -14.0757 0.71410E-14 -14.1462 0.85003E+00 -0.0706 70 MnSO4,aq 0.22274E-15 -15.6522 0.22274E-15 -15.6522 0.10000E+01 0.0000 71 NaCl,aq 0.50850E-06 -6.2937 0.50850E-06 -6.2937 0.10000E+01 0.0000 72 NaOH,aq 0.63080E-04 -4.2001 0.63080E-04 -4.2001 0.10000E+01 0.0000 74 OH- 0.76729E-02 -2.1150 0.65023E-02 -2.1869 0.84744E+00 -0.0719 79 HPO3-2 0.17855E-15 -15.7482 0.98512E-16 -16.0065 0.55172E+00 -0.2583 81 H2PO3- 0.21034E-19 -19.6771 0.17851E-19 -19.7483 0.84869E+00 -0.0712 82 H3PO4,aq 0.34471E-17 -17.4625 0.34471E-17 -17.4625 0.10000E+01 0.0000 83 H2PO4- 0.11981E-09 -9.9215 0.10176E-09 -9.9924 0.84935E+00 -0.0709 84 PO4-3 0.21474E-08 -8.6681 0.59564E-09 -9.2250 0.27738E+00 -0.5569 88 HP2O7-3 0.67565E-17 -17.1703 0.18015E-17 -17.7444 0.26663E+00 -0.5741 89 P2O7-4 0.48749E-16 -16.3120 0.48175E-17 -17.3172 0.98823E-01 -1.0051 90 H2S,aq 0.60290E-08 -8.2198 0.60129E-08 -8.2209 0.99733E+00 -0.0012 91 S2-2 0.37847E-13 -13.4220 0.20881E-13 -13.6802 0.55172E+00 -0.2583 97 SO3-2 0.94835E-14 -14.0230 0.52944E-14 -14.2762 0.55828E+00 -0.2532 98 HSO3- 0.33678E-16 -16.4726 0.28583E-16 -16.5439 0.84869E+00 -0.0712 99 HSO4- 0.78816E-14 -14.1034 0.67049E-14 -14.1736 0.85070E+00 -0.0702 101 S2O3-2 0.10061E-16 -16.9973 0.55511E-17 -17.2556 0.55172E+00 -0.2583 Charge balance for all species = -.1509E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1081586E-09 -.1704752E-01 -.1716042E+02 0.0000 2 H2O 0.1000000E+01 0.5550674E+02 0.9986637E+06 0.0000 3 Cl- 0.1385578E-03 0.1390665E-03 0.4923880E+01 6.1054 4 SO4-- 0.1417313E-06 0.1660837E-07 0.1593341E-02 12.9640 5 HCO3- 0.5177211E-05 0.1317347E-04 0.8027578E+00 4.6784 6 HS- 0.2555847E-04 0.2568978E-04 0.8485018E+00 5.3714 7 Al+++ 0.3839230E-28 0.9614103E-05 0.2590639E+00 1.1149 8 H4SiO4 0.6308085E-03 0.9895171E-02 0.9498353E+03 -3.2001 9 Ca++ 0.9017566E-07 0.1461282E-06 0.5848872E-02 12.7650 10 Mg++ 0.2319399E-10 0.8938706E-10 0.2170338E-05 9.1737 11 Fe++ 0.7870786E-13 0.2921507E-07 0.1629442E-02 6.7047 12 K+ 0.1228007E-03 0.1232943E-03 0.4814752E+01 6.0536 13 Na+ 0.1560636E-01 0.1707322E-01 0.3919970E+03 8.1570 14 Mn++ 0.1830393E-10 0.1785307E-08 0.9795299E-04 9.0715 15 HPO4-- 0.1138282E-06 0.1160954E-06 0.1112815E-01 12.8688 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1092832E+01 -.1691362E-01 -.1075919E+01 0.0000000E+00 2 H2O 0.5468093E+02 0.5507076E+02 -.3898326E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1854562E-02 0.1647792E-07 0.1854545E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1829057E-02 0.2548799E-04 -.1854545E-02 0.0000000E+00 7 Al+++ 0.2152057E+00 0.9538588E-05 0.2151961E+00 0.0000000E+00 8 H4SiO4 0.6872333E+00 0.9817448E-02 0.6774158E+00 0.0000000E+00 9 Ca++ 0.7592274E-01 0.1449804E-06 0.7592259E-01 0.0000000E+00 10 Mg++ 0.5238016E-01 0.8868496E-10 0.5238016E-01 0.0000000E+00 11 Fe++ 0.4705785E-01 0.2898560E-07 0.4705783E-01 0.0000000E+00 12 K+ 0.1401253E-01 0.1223259E-03 0.1389020E-01 0.0000000E+00 13 Na+ 0.8300490E-01 0.1693912E-01 0.6606577E-01 0.0000000E+00 14 Mn++ 0.1144330E-02 0.1771284E-08 0.1144328E-02 0.0000000E+00 15 HPO4-- 0.3905541E-03 0.1151835E-06 0.3904390E-03 0.0000000E+00 Chg. balance for solid moles: -.2416E-15 Mass of aqueous solution: 0.993444E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 65.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6607E-01 -1.180 17.32 1.239 24.05 6.650 andradite 0.7418E-02 -2.130 3.770 0.576 5.234 0.9794 grossular 0.9332E-03 -3.030 0.4203 -0.376 0.5836 0.1170 apatite-OH 0.1301E-03 -3.886 0.6538E-01 -1.185 0.9076E-01 0.2077E-01 clinochlore 0.1048E-01 -1.980 5.823 0.765 8.084 2.215 daphnite 0.3724E-02 -2.429 2.657 0.424 3.689 0.8052 chlorite-Mn 0.2289E-03 -3.640 0.1623 -0.790 0.2253 0.5171E-01 microcline 0.1253E-01 -1.902 3.488 0.543 4.842 1.362 stilbite 0.5022E-01 -1.299 35.39 1.549 49.13 16.51 stilpnomelane-Fe 0.2720E-02 -2.565 2.933 0.467 4.071 1.013 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8883E+00 0.8883E+00 1.0000 -0.051 grossular 0.1117E+00 0.1117E+00 1.0000 -0.952 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7261E+00 0.7261E+00 1.0000 -0.139 daphnite 0.2581E+00 0.2581E+00 1.0000 -0.588 chlorite-Mn 0.1586E-01 0.1586E-01 1.0000 -1.800 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 72.031115 g Volume = 29.720705 cm3 Porosity: -8.4713% V(tot) - V(min): -.23211E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 65.9990000 g log = 1.8195 Original solution: 1000.0103000 g Original solution / Rock added: 15.15 (Water/Rock Ratio), log = 1.1805 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0526 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9994E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.8833E-07 1.0073 0.9366E-07 0.9298E-07 CH4,gas 0.1773E-05 1.0129 0.1891E-05 0.1866E-05 H2,gas 0.6455E-03 1.0006 0.6799E-03 0.6795E-03 H2S,gas 0.1673E-06 0.9959 0.1754E-06 0.1761E-06 S2,gas 0.2367E-26 1.0000 0.2492E-26 0.2492E-26 CO,gas 0.1567E-13 1.0000 0.1649E-13 0.1649E-13 SO3,gas 0.2368E-42 1.0000 0.2492E-42 0.2492E-42 SO2,gas 0.6089E-23 1.0000 0.6410E-23 0.6410E-23 HCl,gas 0.3423E-17 1.0000 0.3603E-17 0.3603E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.60662E-10 47 daphnite 29.09 29.09 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 116 microcline -2.43 -2.43 0.00 0.000 0.18957E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.39 -9.03 -3.009 0.15416E+05 -7.028 3 CH4,gas 4.81 -2.91 -7.72 -1.931 0.13188E+05 -5.723 4 H2,gas 8.29 3.12 -5.17 -2.953 0.88235E+04 -3.168 5 H2S,gas -5.94 -14.70 -8.76 -4.378 0.14951E+05 -6.756 6 S2,gas -7.03 -35.64 -28.60 -4.401 0.48840E+05 -26.603 7 CO,gas 3.51 -12.27 -15.78 -4.856 0.26948E+05 -13.783 8 SO3,gas 17.43 -27.18 -44.60 -11.151 0.76159E+05 -42.603 9 SO2,gas 1.14 -24.06 -25.19 -6.718 0.43017E+05 -23.193 10 HCl,gas 5.48 -13.96 -19.44 -9.722 0.33199E+05 -17.443 11 acmite 7.74 6.90 -0.84 -0.087 0.14267E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.84 -4.71 -0.235 0.80350E+04 20 analcite 3.37 2.87 -0.50 -0.055 0.85185E+03 26 annite 20.21 17.68 -2.53 -0.140 0.43148E+04 27 phlogopite 27.15 25.09 -2.06 -0.114 0.35129E+04 29 anorthite 12.80 8.59 -4.20 -0.323 0.71765E+04 35 aragonite 0.99 -2.63 -3.61 -1.204 0.61689E+04 36 brucite 12.58 9.17 -3.40 -0.681 0.58104E+04 37 calcite 0.83 -2.63 -3.46 -1.153 0.59075E+04 38 carnegieite-low 9.06 6.07 -2.99 -0.428 0.51100E+04 39 carnegieite-high 10.13 6.07 -4.06 -0.580 0.69368E+04 40 carpholite-Mg 8.65 5.00 -3.65 -0.243 0.62273E+04 41 carpholite-Fe 6.78 2.53 -4.25 -0.283 0.72543E+04 42 celadonite 5.40 3.54 -1.86 -0.109 0.31737E+04 43 celadonite-Fe 3.94 1.07 -2.86 -0.168 0.48904E+04 44 chrysotile 23.94 21.12 -2.82 -0.235 0.48091E+04 51 chloritoid-Fe 9.24 5.73 -3.50 -0.234 0.59834E+04 52 chloritoid-Mn 11.46 8.10 -3.36 -0.224 0.57404E+04 54 coesite -2.37 -3.20 -0.83 -0.277 0.14185E+04 61 cristobalite -2.55 -3.20 -0.65 -0.217 0.11114E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.11 -1.78 -0.297 0.30413E+04 67 diopside 16.22 15.54 -0.68 -0.068 0.11559E+04 68 hedenbergite 14.24 13.07 -1.17 -0.117 0.20061E+04 75 epidote 24.78 23.30 -1.47 -0.071 0.25110E+04 76 clinozoisite 22.92 19.27 -3.65 -0.166 0.62266E+04 77 epidote-Fe 29.94 27.33 -2.60 -0.135 0.44429E+04 78 fayalite 14.08 10.21 -3.87 -0.553 0.66073E+04 79 ferrosilite 11.19 7.01 -4.18 -0.418 0.71346E+04 83 gibbsite 4.10 1.11 -2.98 -0.426 0.50925E+04 84 glaucophane 23.11 20.46 -2.65 -0.072 0.45187E+04 85 glaucophane-Fe 17.42 13.06 -4.36 -0.118 0.74446E+04 87 greenalite 16.19 13.71 -2.48 -0.207 0.42350E+04 90 hematite 12.60 10.29 -2.31 -0.280 0.39401E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.87 -1.38 -0.138 0.23549E+04 96 julgoldite 70.57 65.85 -4.72 -0.123 0.80658E+04 97 kalsilite 7.62 3.97 -3.65 -0.522 0.62354E+04 98 kaolinite -1.27 -4.17 -2.90 -0.263 0.49469E+04 101 laumontite 2.97 2.19 -0.78 -0.052 0.13320E+04 102 lawsonite 9.68 8.59 -1.08 -0.072 0.18504E+04 103 leucite 4.17 0.77 -3.40 -0.340 0.58043E+04 105 lizardite 23.29 21.12 -2.17 -0.181 0.36994E+04 107 magnetite 20.13 16.99 -3.14 -0.256 0.53581E+04 108 minnesotaite 10.46 7.31 -3.15 -0.185 0.53734E+04 112 manganosite 14.07 9.07 -5.00 -1.249 0.85313E+04 120 muscovite 2.68 -0.20 -2.88 -0.169 0.49195E+04 121 paragonite 4.34 1.90 -2.44 -0.143 0.41580E+04 122 nepheline 8.38 6.07 -2.31 -0.329 0.39379E+04 128 periclase-Fe 11.64 6.70 -4.93 -1.234 0.84254E+04 134 phlogopite-Na 29.73 27.19 -2.54 -0.141 0.43348E+04 136 prehnite 19.47 18.16 -1.31 -0.077 0.22312E+04 137 prehnite-Fe 22.59 22.19 -0.40 -0.024 0.67800E+03 138 pumpellyite-Fe 46.47 44.14 -2.33 -0.052 0.39815E+04 139 pumpellyite-Mg 49.19 46.61 -2.59 -0.057 0.44160E+04 142 pyrite -21.23 -25.81 -4.59 -1.079 0.78317E+04 143 pyrrhotite -4.24 -7.99 -3.75 -1.250 0.64038E+04 144 pyrrhotiteFe0.875 -6.00 -9.22 -3.22 -1.183 0.54944E+04 145 pyroxmangite 7.42 5.87 -1.54 -0.309 0.26374E+04 146 pyrophyllite -6.10 -10.57 -4.47 -0.280 0.76367E+04 147 quartz -2.98 -3.20 -0.22 -0.073 0.37241E+03 152 rhodonite 7.46 5.87 -1.59 -0.318 0.27166E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.52 -2.07 -0.062 0.35380E+04 171 talc 16.55 14.72 -1.83 -0.108 0.31294E+04 174 tephroite 18.11 14.94 -3.17 -0.453 0.54126E+04 178 tridymite -2.61 -3.20 -0.59 -0.195 0.99970E+03 179 tremolite 48.00 45.80 -2.21 -0.060 0.37660E+04 181 troilite-low -4.39 -7.99 -3.60 -1.200 0.61469E+04 187 wairakite 4.06 2.19 -1.86 -0.110 0.31828E+04 188 walstromite 11.53 9.56 -1.96 -0.393 0.33517E+04 189 wollastonite 10.48 9.56 -0.92 -0.183 0.15656E+04 190 pseudo-wollastonite 11.02 9.56 -1.45 -0.291 0.24842E+04 191 zoisite 22.96 19.27 -3.69 -0.168 0.62991E+04 192 akaganeite 7.77 5.15 -2.62 -0.567 0.44782E+04 199 chalcedony -2.79 -3.20 -0.41 -0.135 0.69272E+03 201 montmorillonite-Ca -2.21 -5.80 -3.59 -0.222 0.61314E+04 202 montmorillonite-K -2.16 -5.91 -3.75 -0.230 0.64073E+04 203 montmorillonite-Mg -2.40 -6.40 -4.00 -0.247 0.68229E+04 204 montmorillonite-Na -1.96 -5.22 -3.26 -0.200 0.55642E+04 205 nontronite-Ca 3.28 1.02 -2.26 -0.147 0.38586E+04 206 nontronite-H 2.60 -1.09 -3.68 -0.247 0.62871E+04 207 nontronite-K 3.40 0.91 -2.49 -0.160 0.42559E+04 208 nontronite-Mg 3.14 0.43 -2.71 -0.176 0.46306E+04 209 nontronite-Na 3.58 1.61 -1.98 -0.127 0.33763E+04 224 tobermorite 9.84 7.43 -2.41 -0.656 0.41079E+04 230 alabandite -0.96 -5.63 -4.66 -1.555 0.79650E+04 233 boehmite 4.43 1.11 -3.31 -0.552 0.56597E+04 235 ferrous-oxide 9.82 6.70 -3.12 -0.780 0.53265E+04 240 silica-amorphous -2.08 -3.20 -1.12 -0.373 0.19129E+04 242 an20ab80 2.08 1.46 -0.62 -0.048 0.10637E+04 243 an25ab75 2.71 1.90 -0.81 -0.062 0.13775E+04 244 an30ab70 3.34 2.35 -1.00 -0.077 0.16997E+04 245 tr.625ac.25prg.125 45.31 43.80 -1.51 -0.041 0.25710E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 65.9990000 g New total amount of reactant added: 67.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1492E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 67.9990000 Water: Moles liquid = 0.5506E+02 kg liquid = 0.9919E+00 Moles total = 0.5466E+02 kg total = 0.9846E+00 Activity = 1.0000 Stoichiometric ionic strength = .8903834E-02 Osmotic coef. = 0.9651 True ionic strength = .1602896E-01 Chg. balance for total moles = -.1492E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10685E-09 -9.9712 0.91039E-10 -10.0408 0.85201E+00 -0.0696 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13858E-03 -3.8583 0.11748E-03 -3.9300 0.84773E+00 -0.0717 4 SO4-- 0.64112E-07 -7.1931 0.35278E-07 -7.4525 0.55025E+00 -0.2594 5 HCO3- 0.51259E-05 -5.2902 0.43507E-05 -5.3614 0.84876E+00 -0.0712 6 HS- 0.25642E-04 -4.5910 0.21740E-04 -4.6627 0.84783E+00 -0.0717 7 Al+++ 0.35263E-28 -28.4527 0.93002E-29 -29.0315 0.26374E+00 -0.5788 8 H4SiO4 0.63610E-03 -3.1965 0.63610E-03 -3.1965 0.10000E+01 0.0000 9 Ca++ 0.92975E-07 -7.0316 0.50847E-07 -7.2937 0.54689E+00 -0.2621 10 Mg++ 0.23177E-10 -10.6349 0.12627E-10 -10.8987 0.54481E+00 -0.2638 11 Fe++ 0.77452E-13 -13.1110 0.42235E-13 -13.3743 0.54530E+00 -0.2634 12 K+ 0.12507E-03 -3.9028 0.10618E-03 -3.9740 0.84893E+00 -0.0711 13 Na+ 0.15895E-01 -1.7987 0.13473E-01 -1.8705 0.84761E+00 -0.0718 14 Mn++ 0.18290E-10 -10.7378 0.99805E-11 -11.0008 0.54568E+00 -0.2631 15 HPO4-- 0.10756E-06 -6.9683 0.59193E-07 -7.2277 0.55031E+00 -0.2594 16 HSiO3- 0.80417E-02 -2.0947 0.68172E-02 -2.1664 0.84773E+00 -0.0717 17 Ca(HSiO3)+ 0.91468E-08 -8.0387 0.77664E-08 -8.1098 0.84908E+00 -0.0711 18 Mg(HSiO3)+ 0.28269E-11 -11.5487 0.24002E-11 -11.6197 0.84908E+00 -0.0711 19 NaHSiO3,aq 0.14588E-02 -2.8360 0.14588E-02 -2.8360 0.10000E+01 0.0000 20 AlO+ 0.17061E-15 -15.7680 0.14486E-15 -15.8390 0.84908E+00 -0.0711 22 HAlO2,aq 0.31842E-09 -9.4970 0.31842E-09 -9.4970 0.10000E+01 0.0000 23 AlO2- 0.92264E-05 -5.0350 0.78097E-05 -5.1074 0.84646E+00 -0.0724 24 CH4,aq 0.26381E-08 -8.5787 0.26309E-08 -8.5799 0.99727E+00 -0.0012 29 CO,aq 0.12493E-16 -16.9033 0.12493E-16 -16.9033 0.10000E+01 0.0000 30 CO2,aq 0.80076E-09 -9.0965 0.79858E-09 -9.0977 0.99727E+00 -0.0012 31 CO3-2 0.80443E-05 -5.0945 0.44186E-05 -5.3547 0.54928E+00 -0.2602 32 CaCO3,aq 0.27517E-08 -8.5604 0.27517E-08 -8.5604 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.65648E-11 -11.1828 0.55741E-11 -11.2538 0.84908E+00 -0.0711 34 CaCl+ 0.11211E-10 -10.9504 0.95187E-11 -11.0214 0.84908E+00 -0.0711 35 CaCl2,aq 0.26037E-15 -15.5844 0.26037E-15 -15.5844 0.10000E+01 0.0000 36 CaOH+ 0.46383E-07 -7.3336 0.39383E-07 -7.4047 0.84908E+00 -0.0711 37 CaSO4,aq 0.55889E-12 -12.2527 0.55889E-12 -12.2527 0.10000E+01 0.0000 38 HCl,aq 0.20117E-14 -14.6964 0.20117E-14 -14.6964 0.10000E+01 0.0000 43 FeCl+ 0.91015E-17 -17.0409 0.77279E-17 -17.1119 0.84908E+00 -0.0711 46 FeO,aq 0.20151E-09 -9.6957 0.20151E-09 -9.6957 0.10000E+01 0.0000 47 FeOH+ 0.18114E-10 -10.7420 0.15380E-10 -10.8130 0.84908E+00 -0.0711 48 HFeO2- 0.28084E-07 -7.5515 0.23808E-07 -7.6233 0.84773E+00 -0.0717 49 FeO+ 0.56558E-16 -16.2475 0.48022E-16 -16.3186 0.84908E+00 -0.0711 51 FeO2- 0.13433E-08 -8.8718 0.11388E-08 -8.9436 0.84773E+00 -0.0717 52 HFeO2,aq 0.12975E-10 -10.8869 0.12975E-10 -10.8869 0.10000E+01 0.0000 53 H2,aq 0.60909E-06 -6.2153 0.60743E-06 -6.2165 0.99727E+00 -0.0012 54 KCl,aq 0.22086E-09 -9.6559 0.22086E-09 -9.6559 0.10000E+01 0.0000 56 KOH,aq 0.50844E-06 -6.2938 0.50844E-06 -6.2938 0.10000E+01 0.0000 57 KSO4- 0.68073E-10 -10.1670 0.57707E-10 -10.2388 0.84773E+00 -0.0717 58 MgCO3,aq 0.17075E-12 -12.7676 0.17075E-12 -12.7676 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16624E-14 -14.7793 0.14115E-14 -14.8503 0.84908E+00 -0.0711 60 MgCl+ 0.25273E-14 -14.5973 0.21459E-14 -14.6684 0.84908E+00 -0.0711 61 MgOH+ 0.63813E-10 -10.1951 0.54182E-10 -10.2661 0.84908E+00 -0.0711 63 MnO,aq 0.12712E-08 -8.8958 0.12712E-08 -8.8958 0.10000E+01 0.0000 64 MnOH+ 0.39764E-09 -9.4005 0.33763E-09 -9.4716 0.84908E+00 -0.0711 65 MnO2-2 0.96570E-11 -11.0152 0.53043E-11 -11.2754 0.54928E+00 -0.2602 66 HMnO2- 0.12342E-09 -9.9086 0.10463E-09 -9.9804 0.84773E+00 -0.0717 69 MnCl+ 0.83576E-14 -14.0779 0.70963E-14 -14.1490 0.84908E+00 -0.0711 70 MnSO4,aq 0.99783E-16 -16.0009 0.99783E-16 -16.0009 0.10000E+01 0.0000 71 NaCl,aq 0.51682E-06 -6.2867 0.51682E-06 -6.2867 0.10000E+01 0.0000 72 NaOH,aq 0.65029E-04 -4.1869 0.65029E-04 -4.1869 0.10000E+01 0.0000 74 OH- 0.77839E-02 -2.1088 0.65888E-02 -2.1812 0.84646E+00 -0.0724 79 HPO3-2 0.20676E-15 -15.6845 0.11357E-15 -15.9447 0.54928E+00 -0.2602 81 H2PO3- 0.23957E-19 -19.6206 0.20309E-19 -19.6923 0.84773E+00 -0.0717 82 H3PO4,aq 0.31584E-17 -17.5005 0.31584E-17 -17.5005 0.10000E+01 0.0000 83 H2PO4- 0.11136E-09 -9.9533 0.94478E-10 -10.0247 0.84840E+00 -0.0714 84 PO4-3 0.20667E-08 -8.6847 0.56782E-09 -9.2458 0.27475E+00 -0.5611 88 HP2O7-3 0.59614E-17 -17.2247 0.15735E-17 -17.8031 0.26395E+00 -0.5785 89 P2O7-4 0.43914E-16 -16.3574 0.42639E-17 -17.3702 0.97097E-01 -1.0128 90 H2S,aq 0.59629E-08 -8.2245 0.59466E-08 -8.2257 0.99727E+00 -0.0012 91 S2-2 0.31156E-13 -13.5065 0.17113E-13 -13.7667 0.54928E+00 -0.2602 97 SO3-2 0.52560E-14 -14.2793 0.29218E-14 -14.5343 0.55590E+00 -0.2550 98 HSO3- 0.18363E-16 -16.7361 0.15567E-16 -16.8078 0.84773E+00 -0.0717 99 HSO4- 0.35068E-14 -14.4551 0.29799E-14 -14.5258 0.84977E+00 -0.0707 101 S2O3-2 0.45012E-17 -17.3467 0.24724E-17 -17.6069 0.54928E+00 -0.2602 Charge balance for all species = -.1581E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1068524E-09 -.1739515E-01 -.1750985E+02 0.0000 2 H2O 0.1000000E+01 0.5550662E+02 0.9986329E+06 0.0000 3 Cl- 0.1385809E-03 0.1390980E-03 0.4924854E+01 6.1107 4 SO4-- 0.6411211E-07 -.9056119E-07 -.8687834E-02 12.6290 5 HCO3- 0.5125910E-05 0.1317646E-04 0.8029166E+00 4.6793 6 HS- 0.2564206E-04 0.2580277E-04 0.8522094E+00 5.3780 7 Al+++ 0.3526267E-28 0.9226670E-05 0.2486169E+00 1.0908 8 H4SiO4 0.6361048E-03 0.1013653E-01 0.9729757E+03 -3.1965 9 Ca++ 0.9297463E-07 0.1512742E-06 0.6054670E-02 12.7878 10 Mg++ 0.2317694E-10 0.8999126E-10 0.2184945E-05 9.1828 11 Fe++ 0.7745173E-13 0.2966047E-07 0.1654236E-02 6.7072 12 K+ 0.1250716E-03 0.1255803E-03 0.4903884E+01 6.0668 13 Na+ 0.1589533E-01 0.1741964E-01 0.3999392E+03 8.1702 14 Mn++ 0.1829005E-10 0.1820223E-08 0.9986583E-04 9.0807 15 HPO4-- 0.1075623E-06 0.1097403E-06 0.1051869E-01 12.8538 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1125949E+01 -.1725461E-01 -.1108695E+01 0.0000000E+00 2 H2O 0.5465585E+02 0.5505817E+02 -.4023140E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1909989E-02 -.8982953E-07 0.1910078E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1884484E-02 0.2559430E-04 -.1910078E-02 0.0000000E+00 7 Al+++ 0.2217272E+00 0.9152126E-05 0.2217180E+00 0.0000000E+00 8 H4SiO4 0.7080588E+00 0.1005464E-01 0.6980042E+00 0.0000000E+00 9 Ca++ 0.7822302E-01 0.1500520E-06 0.7822287E-01 0.0000000E+00 10 Mg++ 0.5396746E-01 0.8926420E-10 0.5396746E-01 0.0000000E+00 11 Fe++ 0.4848387E-01 0.2942084E-07 0.4848384E-01 0.0000000E+00 12 K+ 0.1443715E-01 0.1245657E-03 0.1431259E-01 0.0000000E+00 13 Na+ 0.8551538E-01 0.1727890E-01 0.6823648E-01 0.0000000E+00 14 Mn++ 0.1179007E-02 0.1805517E-08 0.1179005E-02 0.0000000E+00 15 HPO4-- 0.4023893E-03 0.1088537E-06 0.4022804E-03 0.0000000E+00 Chg. balance for solid moles: -.8370E-16 Mass of aqueous solution: 0.993247E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 67.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.6824E-01 -1.166 17.89 1.253 24.11 6.869 andradite 0.7640E-02 -2.117 3.883 0.589 5.232 1.009 grossular 0.1001E-02 -3.000 0.4508 -0.346 0.6074 0.1254 apatite-OH 0.1341E-03 -3.873 0.6736E-01 -1.172 0.9076E-01 0.2140E-01 clinochlore 0.1079E-01 -1.967 5.999 0.778 8.084 2.282 daphnite 0.3778E-02 -2.423 2.696 0.431 3.633 0.8169 chlorite-Mn 0.2358E-03 -3.627 0.1672 -0.777 0.2253 0.5327E-01 microcline 0.1288E-01 -1.890 3.585 0.555 4.831 1.401 stilbite 0.5163E-01 -1.287 36.38 1.561 49.03 16.97 stilpnomelane-Fe 0.2862E-02 -2.543 3.086 0.489 4.158 1.066 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8842E+00 0.8842E+00 1.0000 -0.053 grossular 0.1158E+00 0.1158E+00 1.0000 -0.936 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7289E+00 0.7289E+00 1.0000 -0.137 daphnite 0.2552E+00 0.2552E+00 1.0000 -0.593 chlorite-Mn 0.1592E-01 0.1592E-01 1.0000 -1.798 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 74.211391 g Volume = 30.613123 cm3 Porosity: -8.5587% V(tot) - V(min): -.24135E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 67.9990000 g log = 1.8325 Original solution: 1000.0103000 g Original solution / Rock added: 14.71 (Water/Rock Ratio), log = 1.1675 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0528 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9992E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.8620E-07 1.0073 0.9141E-07 0.9075E-07 CH4,gas 0.3901E-05 1.0129 0.4160E-05 0.4107E-05 H2,gas 0.7909E-03 1.0006 0.8331E-03 0.8327E-03 H2S,gas 0.1654E-06 0.9959 0.1734E-06 0.1741E-06 S2,gas 0.1542E-26 1.0000 0.1623E-26 0.1623E-26 CO,gas 0.1874E-13 1.0000 0.1973E-13 0.1973E-13 SO3,gas 0.1038E-42 1.0000 0.1093E-42 0.1093E-42 SO2,gas 0.3272E-23 1.0000 0.3445E-23 0.3445E-23 HCl,gas 0.3374E-17 1.0000 0.3552E-17 0.3552E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.40 -9.04 -3.013 0.15434E+05 -7.039 3 CH4,gas 4.81 -2.57 -7.38 -1.845 0.12603E+05 -5.381 4 H2,gas 8.29 3.21 -5.08 -2.902 0.86727E+04 -3.079 5 H2S,gas -5.94 -14.70 -8.76 -4.380 0.14959E+05 -6.761 6 S2,gas -7.03 -35.82 -28.79 -4.429 0.49158E+05 -26.790 7 CO,gas 3.51 -12.19 -15.70 -4.832 0.26816E+05 -13.705 8 SO3,gas 17.43 -27.53 -44.96 -11.240 0.76770E+05 -42.961 9 SO2,gas 1.14 -24.33 -25.46 -6.790 0.43477E+05 -23.463 10 HCl,gas 5.48 -13.97 -19.45 -9.725 0.33210E+05 -17.450 11 acmite 7.74 6.88 -0.86 -0.089 0.14628E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80517E+04 20 analcite 3.37 2.87 -0.50 -0.056 0.85805E+03 26 annite 20.21 17.69 -2.52 -0.140 0.43019E+04 27 phlogopite 27.15 25.12 -2.03 -0.113 0.34659E+04 29 anorthite 12.80 8.58 -4.22 -0.325 0.72075E+04 35 aragonite 0.99 -2.61 -3.60 -1.200 0.61480E+04 36 brucite 12.58 9.18 -3.39 -0.679 0.57947E+04 37 calcite 0.83 -2.61 -3.45 -1.149 0.58866E+04 38 carnegieite-low 9.06 6.06 -3.00 -0.429 0.51224E+04 39 carnegieite-high 10.13 6.06 -4.07 -0.581 0.69492E+04 40 carpholite-Mg 8.65 4.97 -3.68 -0.245 0.62815E+04 41 carpholite-Fe 6.78 2.50 -4.29 -0.286 0.73199E+04 42 celadonite 5.40 3.55 -1.85 -0.109 0.31519E+04 43 celadonite-Fe 3.94 1.08 -2.86 -0.168 0.48799E+04 44 chrysotile 23.94 21.16 -2.78 -0.232 0.47497E+04 49 chlorite-Al-free 47.26 42.31 -4.95 -0.206 0.84528E+04 51 chloritoid-Fe 9.24 5.69 -3.55 -0.236 0.60552E+04 52 chloritoid-Mn 11.46 8.07 -3.40 -0.226 0.58009E+04 54 coesite -2.37 -3.20 -0.83 -0.276 0.14123E+04 61 cristobalite -2.55 -3.20 -0.65 -0.216 0.11052E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.09 -1.81 -0.301 0.30825E+04 67 diopside 16.22 15.58 -0.64 -0.064 0.10889E+04 68 hedenbergite 14.24 13.10 -1.14 -0.114 0.19505E+04 75 epidote 24.78 23.27 -1.50 -0.073 0.25680E+04 76 clinozoisite 22.92 19.26 -3.66 -0.166 0.62536E+04 77 epidote-Fe 29.94 27.28 -2.65 -0.138 0.45298E+04 78 fayalite 14.08 10.22 -3.86 -0.552 0.65925E+04 79 ferrosilite 11.19 7.02 -4.17 -0.417 0.71137E+04 83 gibbsite 4.10 1.09 -3.01 -0.430 0.51336E+04 84 glaucophane 23.11 20.50 -2.61 -0.071 0.44593E+04 85 glaucophane-Fe 17.42 13.07 -4.35 -0.117 0.74193E+04 87 greenalite 16.19 13.73 -2.47 -0.205 0.42098E+04 90 hematite 12.60 10.21 -2.39 -0.290 0.40822E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.87 -1.38 -0.138 0.23611E+04 96 julgoldite 70.57 65.80 -4.77 -0.124 0.81487E+04 97 kalsilite 7.62 3.96 -3.66 -0.523 0.62478E+04 98 kaolinite -1.27 -4.21 -2.94 -0.267 0.50168E+04 101 laumontite 2.97 2.18 -0.79 -0.053 0.13506E+04 102 lawsonite 9.68 8.58 -1.10 -0.073 0.18814E+04 103 leucite 4.17 0.76 -3.40 -0.340 0.58105E+04 105 lizardite 23.29 21.16 -2.13 -0.178 0.36400E+04 107 magnetite 20.13 16.91 -3.22 -0.263 0.54959E+04 108 minnesotaite 10.46 7.34 -3.12 -0.184 0.53358E+04 112 manganosite 14.07 9.08 -4.99 -1.247 0.85156E+04 120 muscovite 2.68 -0.25 -2.93 -0.172 0.50018E+04 121 paragonite 4.34 1.85 -2.48 -0.146 0.42403E+04 122 nepheline 8.38 6.06 -2.31 -0.331 0.39503E+04 128 periclase-Fe 11.64 6.71 -4.93 -1.233 0.84211E+04 134 phlogopite-Na 29.73 27.22 -2.51 -0.140 0.42878E+04 136 prehnite 19.47 18.17 -1.30 -0.076 0.22171E+04 137 prehnite-Fe 22.59 22.18 -0.41 -0.024 0.69380E+03 138 pumpellyite-Fe 46.47 44.13 -2.34 -0.052 0.39901E+04 139 pumpellyite-Mg 49.19 46.61 -2.58 -0.057 0.44133E+04 142 pyrite -21.23 -25.91 -4.68 -1.102 0.79945E+04 143 pyrrhotite -4.24 -8.00 -3.75 -1.251 0.64077E+04 144 pyrrhotiteFe0.875 -6.00 -9.23 -3.23 -1.188 0.55176E+04 145 pyroxmangite 7.42 5.88 -1.53 -0.306 0.26155E+04 146 pyrophyllite -6.10 -10.60 -4.51 -0.282 0.76943E+04 147 quartz -2.98 -3.20 -0.21 -0.071 0.36621E+03 152 rhodonite 7.46 5.88 -1.58 -0.316 0.26947E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.56 -2.04 -0.061 0.34811E+04 171 talc 16.55 14.76 -1.79 -0.105 0.30576E+04 174 tephroite 18.11 14.96 -3.15 -0.450 0.53751E+04 178 tridymite -2.61 -3.20 -0.58 -0.194 0.99350E+03 179 tremolite 48.00 45.92 -2.09 -0.056 0.35602E+04 181 troilite-low -4.39 -8.00 -3.60 -1.201 0.61509E+04 187 wairakite 4.06 2.18 -1.87 -0.110 0.32014E+04 188 walstromite 11.53 9.59 -1.94 -0.387 0.33066E+04 189 wollastonite 10.48 9.59 -0.89 -0.178 0.15205E+04 190 pseudo-wollastonite 11.02 9.59 -1.43 -0.286 0.24391E+04 191 zoisite 22.96 19.26 -3.70 -0.168 0.63261E+04 192 akaganeite 7.77 5.10 -2.66 -0.576 0.45493E+04 199 chalcedony -2.79 -3.20 -0.40 -0.134 0.68652E+03 201 montmorillonite-Ca -2.21 -5.82 -3.61 -0.223 0.61637E+04 202 montmorillonite-K -2.16 -5.93 -3.77 -0.231 0.64386E+04 203 montmorillonite-Mg -2.40 -6.42 -4.02 -0.249 0.68591E+04 204 montmorillonite-Na -1.96 -5.24 -3.28 -0.201 0.55955E+04 205 nontronite-Ca 3.28 0.95 -2.33 -0.151 0.39851E+04 206 nontronite-H 2.60 -1.16 -3.76 -0.252 0.64201E+04 207 nontronite-K 3.40 0.84 -2.57 -0.165 0.43814E+04 208 nontronite-Mg 3.14 0.35 -2.79 -0.181 0.47610E+04 209 nontronite-Na 3.58 1.53 -2.05 -0.132 0.35019E+04 224 tobermorite 9.84 7.46 -2.38 -0.650 0.40693E+04 230 alabandite -0.96 -5.62 -4.66 -1.553 0.79575E+04 233 boehmite 4.43 1.09 -3.34 -0.556 0.57009E+04 235 ferrous-oxide 9.82 6.71 -3.12 -0.779 0.53222E+04 240 silica-amorphous -2.08 -3.20 -1.12 -0.372 0.19067E+04 242 an20ab80 2.08 1.45 -0.63 -0.048 0.10699E+04 243 an25ab75 2.71 1.90 -0.81 -0.062 0.13853E+04 244 an30ab70 3.34 2.34 -1.00 -0.077 0.17090E+04 245 tr.625ac.25prg.125 45.31 43.91 -1.40 -0.038 0.23955E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 67.9990000 g New total amount of reactant added: 69.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1492E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 69.9990000 Water: Moles liquid = 0.5505E+02 kg liquid = 0.9917E+00 Moles total = 0.5463E+02 kg total = 0.9842E+00 Activity = 1.0000 Stoichiometric ionic strength = .9074211E-02 Osmotic coef. = 0.9649 True ionic strength = .1631538E-01 Chg. balance for total moles = -.1492E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10562E-09 -9.9762 0.89900E-10 -10.0462 0.85113E+00 -0.0700 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13860E-03 -3.8582 0.11737E-03 -3.9304 0.84679E+00 -0.0722 4 SO4-- 0.29913E-07 -7.5241 0.16389E-07 -7.7854 0.54789E+00 -0.2613 5 HCO3- 0.50764E-05 -5.2944 0.43040E-05 -5.3661 0.84784E+00 -0.0717 6 HS- 0.25682E-04 -4.5904 0.21750E-04 -4.6625 0.84690E+00 -0.0722 7 Al+++ 0.32480E-28 -28.4884 0.84826E-29 -29.0715 0.26116E+00 -0.5831 8 H4SiO4 0.64144E-03 -3.1928 0.64144E-03 -3.1928 0.10000E+01 0.0000 9 Ca++ 0.95735E-07 -7.0189 0.52127E-07 -7.2829 0.54450E+00 -0.2640 10 Mg++ 0.23172E-10 -10.6350 0.12568E-10 -10.9007 0.54239E+00 -0.2657 11 Fe++ 0.76274E-13 -13.1176 0.41409E-13 -13.3829 0.54290E+00 -0.2653 12 K+ 0.12730E-03 -3.8952 0.10796E-03 -3.9668 0.84801E+00 -0.0716 13 Na+ 0.16179E-01 -1.7910 0.13699E-01 -1.8633 0.84667E+00 -0.0723 14 Mn++ 0.18286E-10 -10.7379 0.99343E-11 -11.0029 0.54328E+00 -0.2650 15 HPO4-- 0.10191E-06 -6.9918 0.55845E-07 -7.2530 0.54796E+00 -0.2613 16 HSiO3- 0.82209E-02 -2.0851 0.69614E-02 -2.1573 0.84679E+00 -0.0722 17 Ca(HSiO3)+ 0.95859E-08 -8.0184 0.81304E-08 -8.0899 0.84816E+00 -0.0715 18 Mg(HSiO3)+ 0.28764E-11 -11.5411 0.24397E-11 -11.6127 0.84816E+00 -0.0715 19 NaHSiO3,aq 0.15146E-02 -2.8197 0.15146E-02 -2.8197 0.10000E+01 0.0000 20 AlO+ 0.15975E-15 -15.7966 0.13549E-15 -15.8681 0.84816E+00 -0.0715 22 HAlO2,aq 0.30160E-09 -9.5206 0.30160E-09 -9.5206 0.10000E+01 0.0000 23 AlO2- 0.88597E-05 -5.0526 0.74909E-05 -5.1255 0.84550E+00 -0.0729 24 CH4,aq 0.56205E-08 -8.2502 0.56049E-08 -8.2514 0.99722E+00 -0.0012 29 CO,aq 0.14832E-16 -16.8288 0.14832E-16 -16.8288 0.10000E+01 0.0000 30 CO2,aq 0.78230E-09 -9.1066 0.78013E-09 -9.1078 0.99722E+00 -0.0012 31 CO3-2 0.80938E-05 -5.0918 0.44265E-05 -5.3539 0.54691E+00 -0.2621 32 CaCO3,aq 0.28260E-08 -8.5488 0.28260E-08 -8.5488 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.66651E-11 -11.1762 0.56531E-11 -11.2477 0.84816E+00 -0.0715 34 CaCl+ 0.11494E-10 -10.9395 0.97492E-11 -11.0110 0.84816E+00 -0.0715 35 CaCl2,aq 0.26643E-15 -15.5744 0.26643E-15 -15.5744 0.10000E+01 0.0000 36 CaOH+ 0.48205E-07 -7.3169 0.40886E-07 -7.3884 0.84816E+00 -0.0715 37 CaSO4,aq 0.26618E-12 -12.5748 0.26618E-12 -12.5748 0.10000E+01 0.0000 38 HCl,aq 0.19847E-14 -14.7023 0.19847E-14 -14.7023 0.10000E+01 0.0000 43 FeCl+ 0.89248E-17 -17.0494 0.75697E-17 -17.1209 0.84816E+00 -0.0715 46 FeO,aq 0.20261E-09 -9.6933 0.20261E-09 -9.6933 0.10000E+01 0.0000 47 FeOH+ 0.18004E-10 -10.7446 0.15270E-10 -10.8162 0.84816E+00 -0.0715 48 HFeO2- 0.28626E-07 -7.5432 0.24241E-07 -7.6155 0.84679E+00 -0.0722 49 FeO+ 0.50994E-16 -16.2925 0.43252E-16 -16.3640 0.84816E+00 -0.0715 51 FeO2- 0.12421E-08 -8.9058 0.10518E-08 -8.9781 0.84679E+00 -0.0722 52 HFeO2,aq 0.11834E-10 -10.9269 0.11834E-10 -10.9269 0.10000E+01 0.0000 53 H2,aq 0.74022E-06 -6.1306 0.73816E-06 -6.1318 0.99722E+00 -0.0012 54 KCl,aq 0.22435E-09 -9.6491 0.22435E-09 -9.6491 0.10000E+01 0.0000 56 KOH,aq 0.52350E-06 -6.2811 0.52350E-06 -6.2811 0.10000E+01 0.0000 57 KSO4- 0.32190E-10 -10.4923 0.27258E-10 -10.5645 0.84679E+00 -0.0722 58 MgCO3,aq 0.17027E-12 -12.7689 0.17027E-12 -12.7689 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16387E-14 -14.7855 0.13899E-14 -14.8570 0.84816E+00 -0.0715 60 MgCl+ 0.25160E-14 -14.5993 0.21340E-14 -14.6708 0.84816E+00 -0.0715 61 MgOH+ 0.64391E-10 -10.1912 0.54614E-10 -10.2627 0.84816E+00 -0.0715 63 MnO,aq 0.12976E-08 -8.8869 0.12976E-08 -8.8869 0.10000E+01 0.0000 64 MnOH+ 0.40125E-09 -9.3966 0.34032E-09 -9.4681 0.84816E+00 -0.0715 65 MnO2-2 0.10152E-10 -10.9934 0.55524E-11 -11.2555 0.54691E+00 -0.2621 66 HMnO2- 0.12772E-09 -9.8938 0.10815E-09 -9.9660 0.84679E+00 -0.0722 69 MnCl+ 0.83201E-14 -14.0799 0.70568E-14 -14.1514 0.84816E+00 -0.0715 70 MnSO4,aq 0.46141E-16 -16.3359 0.46141E-16 -16.3359 0.10000E+01 0.0000 71 NaCl,aq 0.52499E-06 -6.2798 0.52499E-06 -6.2798 0.10000E+01 0.0000 72 NaOH,aq 0.66955E-04 -4.1742 0.66955E-04 -4.1742 0.10000E+01 0.0000 74 OH- 0.78914E-02 -2.1028 0.66722E-02 -2.1757 0.84550E+00 -0.0729 79 HPO3-2 0.23807E-15 -15.6233 0.13020E-15 -15.8854 0.54691E+00 -0.2621 81 H2PO3- 0.27153E-19 -19.5662 0.22993E-19 -19.6384 0.84679E+00 -0.0722 82 H3PO4,aq 0.29057E-17 -17.5367 0.29057E-17 -17.5367 0.10000E+01 0.0000 83 H2PO4- 0.10386E-09 -9.9835 0.88019E-10 -10.0554 0.84747E+00 -0.0719 84 PO4-3 0.19928E-08 -8.7005 0.54249E-09 -9.2656 0.27223E+00 -0.5651 88 HP2O7-3 0.52913E-17 -17.2764 0.13830E-17 -17.8592 0.26137E+00 -0.5827 89 P2O7-4 0.39761E-16 -16.4005 0.37952E-17 -17.4208 0.95449E-01 -1.0202 90 H2S,aq 0.58913E-08 -8.2298 0.58750E-08 -8.2310 0.99722E+00 -0.0012 91 S2-2 0.25773E-13 -13.5888 0.14095E-13 -13.8509 0.54691E+00 -0.2621 97 SO3-2 0.29797E-14 -14.5258 0.16495E-14 -14.7826 0.55359E+00 -0.2568 98 HSO3- 0.10248E-16 -16.9893 0.86783E-17 -17.0616 0.84679E+00 -0.0722 99 HSO4- 0.16105E-14 -14.7930 0.13671E-14 -14.8642 0.84886E+00 -0.0712 101 S2O3-2 0.20749E-17 -17.6830 0.11348E-17 -17.9451 0.54691E+00 -0.2621 Charge balance for all species = -.1546E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1056249E-09 -.1773827E-01 -.1785473E+02 0.0000 2 H2O 0.1000000E+01 0.5550649E+02 0.9986022E+06 0.0000 3 Cl- 0.1386042E-03 0.1391294E-03 0.4925828E+01 6.1158 4 SO4-- 0.2991290E-07 -.1605730E-06 -.1540386E-01 12.3070 5 HCO3- 0.5076438E-05 0.1317943E-04 0.8030754E+00 4.6801 6 HS- 0.2568218E-04 0.2587859E-04 0.8546894E+00 5.3837 7 Al+++ 0.3248004E-28 0.8859966E-05 0.2387291E+00 1.0672 8 H4SiO4 0.6414426E-03 0.1037696E-01 0.9960255E+03 -3.1928 9 Ca++ 0.9573474E-07 0.1563702E-06 0.6258457E-02 12.8095 10 Mg++ 0.2317221E-10 0.9061393E-10 0.2200001E-05 9.1918 11 Fe++ 0.7627366E-13 0.3010088E-07 0.1678751E-02 6.7096 12 K+ 0.1273046E-03 0.1278284E-03 0.4991529E+01 6.0795 13 Na+ 0.1617950E-01 0.1776156E-01 0.4077779E+03 8.1829 14 Mn++ 0.1828590E-10 0.1854977E-08 0.1017698E-03 9.0896 15 HPO4-- 0.1019148E-06 0.1040114E-06 0.9969298E-02 12.8395 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1159066E+01 -.1759099E-01 -.1141475E+01 0.0000000E+00 2 H2O 0.5463078E+02 0.5504560E+02 -.4148133E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1965415E-02 -.1592397E-06 0.1965575E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1939911E-02 0.2566371E-04 -.1965575E-02 0.0000000E+00 7 Al+++ 0.2282487E+00 0.8786398E-05 0.2282399E+00 0.0000000E+00 8 H4SiO4 0.7288844E+00 0.1029080E-01 0.7185936E+00 0.0000000E+00 9 Ca++ 0.8052331E-01 0.1550718E-06 0.8052315E-01 0.0000000E+00 10 Mg++ 0.5555476E-01 0.8986152E-10 0.5555476E-01 0.0000000E+00 11 Fe++ 0.4990989E-01 0.2985094E-07 0.4990986E-01 0.0000000E+00 12 K+ 0.1486178E-01 0.1267670E-03 0.1473502E-01 0.0000000E+00 13 Na+ 0.8802587E-01 0.1761408E-01 0.7041179E-01 0.0000000E+00 14 Mn++ 0.1213684E-02 0.1839575E-08 0.1213683E-02 0.0000000E+00 15 HPO4-- 0.4142244E-03 0.1031478E-06 0.4141213E-03 0.0000000E+00 Chg. balance for solid moles: 0.6505E-18 Mass of aqueous solution: 0.993051E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 69.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7041E-01 -1.152 18.46 1.266 24.17 7.088 andradite 0.7862E-02 -2.104 3.995 0.602 5.230 1.038 grossular 0.1069E-02 -2.971 0.4817 -0.317 0.6306 0.1340 apatite-OH 0.1380E-03 -3.860 0.6934E-01 -1.159 0.9077E-01 0.2203E-01 clinochlore 0.1111E-01 -1.954 6.176 0.791 8.084 2.349 daphnite 0.3831E-02 -2.417 2.734 0.437 3.578 0.8283 chlorite-Mn 0.2427E-03 -3.615 0.1721 -0.764 0.2253 0.5484E-01 microcline 0.1323E-01 -1.878 3.683 0.566 4.821 1.439 stilbite 0.5304E-01 -1.275 37.38 1.573 48.93 17.43 stilpnomelane-Fe 0.3006E-02 -2.522 3.240 0.511 4.242 1.119 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8803E+00 0.8803E+00 1.0000 -0.055 grossular 0.1197E+00 0.1197E+00 1.0000 -0.922 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7317E+00 0.7317E+00 1.0000 -0.136 daphnite 0.2523E+00 0.2523E+00 1.0000 -0.598 chlorite-Mn 0.1599E-01 0.1599E-01 1.0000 -1.796 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 76.391543 g Volume = 31.505283 cm3 Porosity: -8.6404% V(tot) - V(min): -.25057E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 69.9990000 g log = 1.8451 Original solution: 1000.0103000 g Original solution / Rock added: 14.29 (Water/Rock Ratio), log = 1.1549 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0530 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9990E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.8419E-07 1.0073 0.8930E-07 0.8865E-07 CH4,gas 0.8310E-05 1.0129 0.8863E-05 0.8750E-05 H2,gas 0.9610E-03 1.0006 0.1012E-02 0.1012E-02 H2S,gas 0.1634E-06 0.9959 0.1713E-06 0.1721E-06 S2,gas 0.1019E-26 1.0000 0.1073E-26 0.1073E-26 CO,gas 0.2224E-13 1.0000 0.2342E-13 0.2342E-13 SO3,gas 0.4703E-43 1.0000 0.4952E-43 0.4952E-43 SO2,gas 0.1801E-23 1.0000 0.1897E-23 0.1897E-23 HCl,gas 0.3328E-17 1.0000 0.3504E-17 0.3504E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.48529E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.41 -9.05 -3.016 0.15451E+05 -7.049 3 CH4,gas 4.81 -2.24 -7.05 -1.763 0.12042E+05 -5.052 4 H2,gas 8.29 3.29 -4.99 -2.854 0.85282E+04 -2.995 5 H2S,gas -5.94 -14.71 -8.77 -4.383 0.14968E+05 -6.766 6 S2,gas -7.03 -36.00 -28.97 -4.457 0.49465E+05 -26.969 7 CO,gas 3.51 -12.12 -15.63 -4.809 0.26689E+05 -13.630 8 SO3,gas 17.43 -27.88 -45.31 -11.326 0.77357E+05 -43.305 9 SO2,gas 1.14 -24.59 -25.72 -6.859 0.43920E+05 -23.722 10 HCl,gas 5.48 -13.98 -19.46 -9.728 0.33220E+05 -17.455 11 acmite 7.74 6.86 -0.88 -0.091 0.14970E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80679E+04 20 analcite 3.37 2.86 -0.51 -0.056 0.86425E+03 26 annite 20.21 17.70 -2.51 -0.140 0.42899E+04 27 phlogopite 27.15 25.14 -2.00 -0.111 0.34202E+04 29 anorthite 12.80 8.56 -4.24 -0.326 0.72385E+04 35 aragonite 0.99 -2.60 -3.59 -1.196 0.61282E+04 36 brucite 12.58 9.19 -3.38 -0.677 0.57795E+04 37 calcite 0.83 -2.60 -3.44 -1.145 0.58669E+04 38 carnegieite-low 9.06 6.06 -3.01 -0.430 0.51348E+04 39 carnegieite-high 10.13 6.06 -4.08 -0.582 0.69616E+04 40 carpholite-Mg 8.65 4.94 -3.71 -0.247 0.63344E+04 41 carpholite-Fe 6.78 2.46 -4.32 -0.288 0.73840E+04 42 celadonite 5.40 3.57 -1.83 -0.108 0.31304E+04 43 celadonite-Fe 3.94 1.08 -2.85 -0.168 0.48697E+04 44 chrysotile 23.94 21.19 -2.75 -0.229 0.46917E+04 49 chlorite-Al-free 47.26 42.38 -4.88 -0.203 0.83367E+04 51 chloritoid-Fe 9.24 5.65 -3.59 -0.239 0.61255E+04 52 chloritoid-Mn 11.46 8.03 -3.43 -0.229 0.58599E+04 54 coesite -2.37 -3.19 -0.82 -0.274 0.14061E+04 61 cristobalite -2.55 -3.19 -0.64 -0.215 0.10990E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.07 -1.83 -0.305 0.31227E+04 67 diopside 16.22 15.62 -0.60 -0.060 0.10242E+04 68 hedenbergite 14.24 13.13 -1.11 -0.111 0.18970E+04 75 epidote 24.78 23.24 -1.54 -0.075 0.26239E+04 76 clinozoisite 22.92 19.24 -3.68 -0.167 0.62815E+04 77 epidote-Fe 29.94 27.23 -2.70 -0.140 0.46138E+04 78 fayalite 14.08 10.23 -3.85 -0.550 0.65783E+04 79 ferrosilite 11.19 7.03 -4.15 -0.415 0.70932E+04 83 gibbsite 4.10 1.07 -3.03 -0.433 0.51739E+04 84 glaucophane 23.11 20.53 -2.58 -0.070 0.44013E+04 85 glaucophane-Fe 17.42 13.09 -4.33 -0.117 0.73949E+04 87 greenalite 16.19 13.74 -2.45 -0.204 0.41853E+04 90 hematite 12.60 10.13 -2.47 -0.299 0.42187E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.86 -1.39 -0.139 0.23673E+04 96 julgoldite 70.57 65.75 -4.82 -0.125 0.82281E+04 97 kalsilite 7.62 3.95 -3.67 -0.524 0.62602E+04 98 kaolinite -1.27 -4.25 -2.98 -0.271 0.50849E+04 101 laumontite 2.97 2.17 -0.80 -0.053 0.13692E+04 102 lawsonite 9.68 8.56 -1.12 -0.075 0.19124E+04 103 leucite 4.17 0.76 -3.41 -0.341 0.58167E+04 105 lizardite 23.29 21.19 -2.10 -0.175 0.35820E+04 107 magnetite 20.13 16.84 -3.30 -0.269 0.56284E+04 108 minnesotaite 10.46 7.36 -3.10 -0.183 0.52989E+04 112 manganosite 14.07 9.09 -4.98 -1.245 0.85004E+04 120 muscovite 2.68 -0.30 -2.98 -0.175 0.50823E+04 121 paragonite 4.34 1.81 -2.53 -0.149 0.43208E+04 122 nepheline 8.38 6.06 -2.32 -0.332 0.39627E+04 128 periclase-Fe 11.64 6.71 -4.93 -1.232 0.84171E+04 134 phlogopite-Na 29.73 27.25 -2.48 -0.138 0.42421E+04 136 prehnite 19.47 18.18 -1.29 -0.076 0.22048E+04 137 prehnite-Fe 22.59 22.17 -0.42 -0.025 0.70949E+03 138 pumpellyite-Fe 46.47 44.13 -2.34 -0.052 0.40017E+04 139 pumpellyite-Mg 49.19 46.61 -2.58 -0.057 0.44137E+04 142 pyrite -21.23 -26.00 -4.77 -1.124 0.81531E+04 143 pyrrhotite -4.24 -8.00 -3.76 -1.252 0.64127E+04 144 pyrrhotiteFe0.875 -6.00 -9.25 -3.25 -1.194 0.55410E+04 145 pyroxmangite 7.42 5.90 -1.52 -0.304 0.25941E+04 146 pyrophyllite -6.10 -10.64 -4.54 -0.284 0.77500E+04 147 quartz -2.98 -3.19 -0.21 -0.070 0.36001E+03 152 rhodonite 7.46 5.90 -1.57 -0.313 0.26733E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.59 -2.01 -0.060 0.34251E+04 171 talc 16.55 14.80 -1.75 -0.103 0.29871E+04 174 tephroite 18.11 14.99 -3.13 -0.447 0.53384E+04 178 tridymite -2.61 -3.19 -0.58 -0.193 0.98730E+03 179 tremolite 48.00 46.04 -1.97 -0.053 0.33603E+04 180 ferroactinolite 38.60 33.62 -4.97 -0.134 0.84900E+04 181 troilite-low -4.39 -8.00 -3.61 -1.202 0.61558E+04 187 wairakite 4.06 2.17 -1.89 -0.111 0.32200E+04 188 walstromite 11.53 9.62 -1.91 -0.382 0.32633E+04 189 wollastonite 10.48 9.62 -0.87 -0.173 0.14772E+04 190 pseudo-wollastonite 11.02 9.62 -1.40 -0.281 0.23958E+04 191 zoisite 22.96 19.24 -3.72 -0.169 0.63541E+04 192 akaganeite 7.77 5.06 -2.70 -0.585 0.46175E+04 199 chalcedony -2.79 -3.19 -0.40 -0.133 0.68033E+03 201 montmorillonite-Ca -2.21 -5.84 -3.63 -0.224 0.61950E+04 202 montmorillonite-K -2.16 -5.95 -3.79 -0.232 0.64689E+04 203 montmorillonite-Mg -2.40 -6.44 -4.04 -0.250 0.68940E+04 204 montmorillonite-Na -1.96 -5.26 -3.29 -0.202 0.56258E+04 205 nontronite-Ca 3.28 0.87 -2.40 -0.156 0.41061E+04 206 nontronite-H 2.60 -1.24 -3.83 -0.257 0.65471E+04 207 nontronite-K 3.40 0.77 -2.64 -0.169 0.45013E+04 208 nontronite-Mg 3.14 0.28 -2.86 -0.186 0.48856E+04 209 nontronite-Na 3.58 1.46 -2.12 -0.136 0.36218E+04 224 tobermorite 9.84 7.48 -2.36 -0.644 0.40322E+04 230 alabandite -0.96 -5.62 -4.66 -1.552 0.79513E+04 233 boehmite 4.43 1.07 -3.36 -0.560 0.57411E+04 235 ferrous-oxide 9.82 6.71 -3.11 -0.779 0.53182E+04 240 silica-amorphous -2.08 -3.19 -1.11 -0.371 0.19005E+04 242 an20ab80 2.08 1.45 -0.63 -0.048 0.10761E+04 243 an25ab75 2.71 1.89 -0.82 -0.063 0.13930E+04 244 an30ab70 3.34 2.34 -1.01 -0.077 0.17183E+04 245 tr.625ac.25prg.125 45.31 44.00 -1.30 -0.035 0.22255E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 69.9990000 g New total amount of reactant added: 71.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1492E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 71.9990000 Water: Moles liquid = 0.5503E+02 kg liquid = 0.9915E+00 Moles total = 0.5461E+02 kg total = 0.9837E+00 Activity = 1.0000 Stoichiometric ionic strength = .9242402E-02 Osmotic coef. = 0.9647 True ionic strength = .1659697E-01 Chg. balance for total moles = -.1492E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10447E-09 -9.9810 0.88828E-10 -10.0514 0.85027E+00 -0.0704 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13863E-03 -3.8582 0.11726E-03 -3.9308 0.84589E+00 -0.0727 4 SO4-- 0.14386E-07 -7.8421 0.78491E-08 -8.1052 0.54561E+00 -0.2631 5 HCO3- 0.50281E-05 -5.2986 0.42585E-05 -5.3707 0.84694E+00 -0.0721 6 HS- 0.25704E-04 -4.5900 0.21745E-04 -4.6626 0.84599E+00 -0.0726 7 Al+++ 0.29998E-28 -28.5229 0.77599E-29 -29.1101 0.25868E+00 -0.5872 8 H4SiO4 0.64681E-03 -3.1892 0.64681E-03 -3.1892 0.10000E+01 0.0000 9 Ca++ 0.98454E-07 -7.0068 0.53380E-07 -7.2726 0.54218E+00 -0.2659 10 Mg++ 0.23179E-10 -10.6349 0.12518E-10 -10.9025 0.54006E+00 -0.2676 11 Fe++ 0.75167E-13 -13.1240 0.40633E-13 -13.3911 0.54056E+00 -0.2672 12 K+ 0.12950E-03 -3.8877 0.10970E-03 -3.9598 0.84712E+00 -0.0721 13 Na+ 0.16459E-01 -1.7836 0.13920E-01 -1.8564 0.84576E+00 -0.0728 14 Mn++ 0.18290E-10 -10.7378 0.98942E-11 -11.0046 0.54095E+00 -0.2668 15 HPO4-- 0.96808E-07 -7.0141 0.52826E-07 -7.2772 0.54567E+00 -0.2631 16 HSiO3- 0.83988E-02 -2.0758 0.71044E-02 -2.1485 0.84589E+00 -0.0727 17 Ca(HSiO3)+ 0.10028E-07 -7.9988 0.84969E-08 -8.0707 0.84727E+00 -0.0720 18 Mg(HSiO3)+ 0.29267E-11 -11.5336 0.24797E-11 -11.6056 0.84727E+00 -0.0720 19 NaHSiO3,aq 0.15707E-02 -2.8039 0.15707E-02 -2.8039 0.10000E+01 0.0000 20 AlO+ 0.14985E-15 -15.8244 0.12696E-15 -15.8963 0.84727E+00 -0.0720 22 HAlO2,aq 0.28602E-09 -9.5436 0.28602E-09 -9.5436 0.10000E+01 0.0000 23 AlO2- 0.85126E-05 -5.0699 0.71896E-05 -5.1433 0.84458E+00 -0.0734 24 CH4,aq 0.11610E-07 -7.9352 0.11577E-07 -7.9364 0.99717E+00 -0.0012 25 C2H6,aq 0.26045E-19 -19.5843 0.25971E-19 -19.5855 0.99717E+00 -0.0012 29 CO,aq 0.17481E-16 -16.7574 0.17481E-16 -16.7574 0.10000E+01 0.0000 30 CO2,aq 0.76485E-09 -9.1164 0.76268E-09 -9.1177 0.99717E+00 -0.0012 31 CO3-2 0.81390E-05 -5.0894 0.44326E-05 -5.3533 0.54461E+00 -0.2639 32 CaCO3,aq 0.28979E-08 -8.5379 0.28979E-08 -8.5379 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.67603E-11 -11.1700 0.57278E-11 -11.2420 0.84727E+00 -0.0720 34 CaCl+ 0.11772E-10 -10.9291 0.99745E-11 -11.0011 0.84727E+00 -0.0720 35 CaCl2,aq 0.27234E-15 -15.5649 0.27234E-15 -15.5649 0.10000E+01 0.0000 36 CaOH+ 0.50012E-07 -7.3009 0.42374E-07 -7.3729 0.84727E+00 -0.0720 37 CaSO4,aq 0.13055E-12 -12.8842 0.13055E-12 -12.8842 0.10000E+01 0.0000 38 HCl,aq 0.19593E-14 -14.7079 0.19593E-14 -14.7079 0.10000E+01 0.0000 43 FeCl+ 0.87588E-17 -17.0576 0.74211E-17 -17.1295 0.84727E+00 -0.0720 46 FeO,aq 0.20364E-09 -9.6911 0.20364E-09 -9.6911 0.10000E+01 0.0000 47 FeOH+ 0.17899E-10 -10.7472 0.15165E-10 -10.8192 0.84727E+00 -0.0720 48 HFeO2- 0.29150E-07 -7.5354 0.24658E-07 -7.6080 0.84589E+00 -0.0727 49 FeO+ 0.46171E-16 -16.3356 0.39119E-16 -16.4076 0.84727E+00 -0.0720 51 FeO2- 0.11519E-08 -8.9386 0.97442E-09 -9.0113 0.84589E+00 -0.0727 52 HFeO2,aq 0.10832E-10 -10.9653 0.10832E-10 -10.9653 0.10000E+01 0.0000 53 H2,aq 0.89247E-06 -6.0494 0.88994E-06 -6.0506 0.99717E+00 -0.0012 54 KCl,aq 0.22778E-09 -9.6425 0.22778E-09 -9.6425 0.10000E+01 0.0000 56 KOH,aq 0.53839E-06 -6.2689 0.53839E-06 -6.2689 0.10000E+01 0.0000 57 KSO4- 0.15683E-10 -10.8046 0.13266E-10 -10.8773 0.84589E+00 -0.0727 58 MgCO3,aq 0.16981E-12 -12.7700 0.16981E-12 -12.7700 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16166E-14 -14.7914 0.13697E-14 -14.8634 0.84727E+00 -0.0720 60 MgCl+ 0.25062E-14 -14.6010 0.21234E-14 -14.6730 0.84727E+00 -0.0720 61 MgOH+ 0.64973E-10 -10.1873 0.55050E-10 -10.2592 0.84727E+00 -0.0720 63 MnO,aq 0.13237E-08 -8.8782 0.13237E-08 -8.8782 0.10000E+01 0.0000 64 MnOH+ 0.40488E-09 -9.3927 0.34304E-09 -9.4647 0.84727E+00 -0.0720 65 MnO2-2 0.10653E-10 -10.9725 0.58018E-11 -11.2364 0.54461E+00 -0.2639 66 HMnO2- 0.13200E-09 -9.8794 0.11166E-09 -9.9521 0.84589E+00 -0.0727 69 MnCl+ 0.82877E-14 -14.0816 0.70220E-14 -14.1535 0.84727E+00 -0.0720 70 MnSO4,aq 0.22009E-16 -16.6574 0.22009E-16 -16.6574 0.10000E+01 0.0000 71 NaCl,aq 0.53300E-06 -6.2733 0.53300E-06 -6.2733 0.10000E+01 0.0000 72 NaOH,aq 0.68859E-04 -4.1620 0.68859E-04 -4.1620 0.10000E+01 0.0000 74 OH- 0.79954E-02 -2.0972 0.67528E-02 -2.1705 0.84458E+00 -0.0734 79 HPO3-2 0.27265E-15 -15.5644 0.14849E-15 -15.8283 0.54461E+00 -0.2639 81 H2PO3- 0.30630E-19 -19.5139 0.25910E-19 -19.5865 0.84589E+00 -0.0727 82 H3PO4,aq 0.26835E-17 -17.5713 0.26835E-17 -17.5713 0.10000E+01 0.0000 83 H2PO4- 0.97177E-10 -10.0124 0.82268E-10 -10.0848 0.84657E+00 -0.0723 84 PO4-3 0.19250E-08 -8.7156 0.51935E-09 -9.2845 0.26979E+00 -0.5690 88 HP2O7-3 0.47231E-17 -17.3258 0.12228E-17 -17.9127 0.25889E+00 -0.5869 89 P2O7-4 0.36175E-16 -16.4416 0.33959E-17 -17.4690 0.93874E-01 -1.0275 90 H2S,aq 0.58200E-08 -8.2351 0.58035E-08 -8.2363 0.99717E+00 -0.0012 91 S2-2 0.21457E-13 -13.6684 0.11686E-13 -13.9323 0.54461E+00 -0.2639 97 SO3-2 0.17274E-14 -14.7626 0.95243E-15 -15.0212 0.55136E+00 -0.2586 98 HSO3- 0.58531E-17 -17.2326 0.49511E-17 -17.3053 0.84589E+00 -0.0727 99 HSO4- 0.76290E-15 -15.1175 0.64692E-15 -15.1891 0.84798E+00 -0.0716 101 S2O3-2 0.98577E-18 -18.0062 0.53686E-18 -18.2701 0.54461E+00 -0.2639 Charge balance for all species = -.1536E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1044701E-09 -.1807686E-01 -.1819503E+02 0.0000 2 H2O 0.1000000E+01 0.5550636E+02 0.9985718E+06 0.0000 3 Cl- 0.1386276E-03 0.1391608E-03 0.4926802E+01 6.1206 4 SO4-- 0.1438598E-07 -.2201789E-06 -.2112130E-01 11.9977 5 HCO3- 0.5028113E-05 0.1318241E-04 0.8032341E+00 4.6807 6 HS- 0.2570360E-04 0.2594400E-04 0.8568257E+00 5.3888 7 Al+++ 0.2999826E-28 0.8512921E-05 0.2293717E+00 1.0442 8 H4SiO4 0.6468122E-03 0.1061632E-01 0.1018971E+04 -3.1892 9 Ca++ 0.9845445E-07 0.1614114E-06 0.6460043E-02 12.8303 10 Mg++ 0.2317855E-10 0.9125247E-10 0.2215442E-05 9.2004 11 Fe++ 0.7516732E-13 0.3053488E-07 0.1702908E-02 6.7118 12 K+ 0.1294998E-03 0.1300385E-03 0.5077686E+01 6.0917 13 Na+ 0.1645886E-01 0.1809894E-01 0.4155119E+03 8.1951 14 Mn++ 0.1829049E-10 0.1889544E-08 0.1036633E-03 9.0983 15 HPO4-- 0.9680848E-07 0.9883066E-07 0.9472464E-02 12.8257 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1192184E+01 -.1792272E-01 -.1174261E+01 0.0000000E+00 2 H2O 0.5460571E+02 0.5503304E+02 -.4273304E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2020842E-02 -.2183014E-06 0.2021060E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1995338E-02 0.2572277E-04 -.2021060E-02 0.0000000E+00 7 Al+++ 0.2347701E+00 0.8440329E-05 0.2347617E+00 0.0000000E+00 8 H4SiO4 0.7497100E+00 0.1052579E-01 0.7391842E+00 0.0000000E+00 9 Ca++ 0.8282359E-01 0.1600350E-06 0.8282343E-01 0.0000000E+00 10 Mg++ 0.5714206E-01 0.9047433E-10 0.5714206E-01 0.0000000E+00 11 Fe++ 0.5133591E-01 0.3027450E-07 0.5133588E-01 0.0000000E+00 12 K+ 0.1528641E-01 0.1289296E-03 0.1515748E-01 0.0000000E+00 13 Na+ 0.9053636E-01 0.1794461E-01 0.7259175E-01 0.0000000E+00 14 Mn++ 0.1248362E-02 0.1873431E-08 0.1248360E-02 0.0000000E+00 15 HPO4-- 0.4260596E-03 0.9798790E-07 0.4259616E-03 0.0000000E+00 Chg. balance for solid moles: -.3043E-15 Mass of aqueous solution: 0.992855E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 71.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7259E-01 -1.139 19.04 1.280 24.23 7.307 andradite 0.8084E-02 -2.092 4.108 0.614 5.229 1.067 grossular 0.1139E-02 -2.943 0.5131 -0.290 0.6531 0.1428 apatite-OH 0.1420E-03 -3.848 0.7132E-01 -1.147 0.9077E-01 0.2266E-01 clinochlore 0.1143E-01 -1.942 6.352 0.803 8.085 2.416 daphnite 0.3882E-02 -2.411 2.770 0.443 3.526 0.8394 chlorite-Mn 0.2497E-03 -3.603 0.1770 -0.752 0.2253 0.5641E-01 microcline 0.1358E-01 -1.867 3.780 0.578 4.811 1.477 stilbite 0.5444E-01 -1.264 38.37 1.584 48.83 17.90 stilpnomelane-Fe 0.3151E-02 -2.502 3.397 0.531 4.323 1.173 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8765E+00 0.8765E+00 1.0000 -0.057 grossular 0.1235E+00 0.1235E+00 1.0000 -0.908 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7344E+00 0.7344E+00 1.0000 -0.134 daphnite 0.2495E+00 0.2495E+00 1.0000 -0.603 chlorite-Mn 0.1605E-01 0.1605E-01 1.0000 -1.795 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 78.571588 g Volume = 32.397200 cm3 Porosity: -8.7169% V(tot) - V(min): -.25976E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 71.9990000 g log = 1.8573 Original solution: 1000.0103000 g Original solution / Rock added: 13.89 (Water/Rock Ratio), log = 1.1427 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0532 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9988E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.8229E-07 1.0073 0.8730E-07 0.8667E-07 CH4,gas 0.1716E-04 1.0129 0.1831E-04 0.1807E-04 H2,gas 0.1158E-02 1.0006 0.1221E-02 0.1220E-02 H2S,gas 0.1614E-06 0.9959 0.1693E-06 0.1700E-06 S2,gas 0.6839E-27 1.0000 0.7202E-27 0.7202E-27 CO,gas 0.2621E-13 1.0000 0.2760E-13 0.2760E-13 SO3,gas 0.2198E-43 1.0000 0.2315E-43 0.2315E-43 SO2,gas 0.1015E-23 1.0000 0.1069E-23 0.1069E-23 HCl,gas 0.3285E-17 1.0000 0.3459E-17 0.3459E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.42 -9.06 -3.020 0.15468E+05 -7.059 3 CH4,gas 4.81 -1.93 -6.74 -1.684 0.11504E+05 -4.737 4 H2,gas 8.29 3.37 -4.91 -2.808 0.83895E+04 -2.913 5 H2S,gas -5.94 -14.71 -8.77 -4.386 0.14977E+05 -6.771 6 S2,gas -7.03 -36.18 -29.14 -4.483 0.49760E+05 -27.143 7 CO,gas 3.51 -12.05 -15.56 -4.787 0.26567E+05 -13.559 8 SO3,gas 17.43 -28.21 -45.64 -11.409 0.77921E+05 -43.635 9 SO2,gas 1.14 -24.83 -25.97 -6.926 0.44345E+05 -23.971 10 HCl,gas 5.48 -13.98 -19.46 -9.730 0.33229E+05 -17.461 11 acmite 7.74 6.84 -0.90 -0.093 0.15294E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.237 0.80837E+04 20 analcite 3.37 2.86 -0.51 -0.057 0.87043E+03 26 annite 20.21 17.70 -2.51 -0.139 0.42786E+04 27 phlogopite 27.15 25.17 -1.98 -0.110 0.33759E+04 29 anorthite 12.80 8.54 -4.26 -0.327 0.72694E+04 35 aragonite 0.99 -2.59 -3.58 -1.193 0.61096E+04 36 brucite 12.58 9.20 -3.38 -0.675 0.57647E+04 37 calcite 0.83 -2.59 -3.43 -1.142 0.58482E+04 38 carnegieite-low 9.06 6.05 -3.01 -0.431 0.51471E+04 39 carnegieite-high 10.13 6.05 -4.08 -0.583 0.69740E+04 40 carpholite-Mg 8.65 4.91 -3.74 -0.249 0.63859E+04 41 carpholite-Fe 6.78 2.42 -4.36 -0.291 0.74465E+04 42 celadonite 5.40 3.58 -1.82 -0.107 0.31095E+04 43 celadonite-Fe 3.94 1.09 -2.85 -0.167 0.48598E+04 44 chrysotile 23.94 21.22 -2.71 -0.226 0.46349E+04 49 chlorite-Al-free 47.26 42.45 -4.82 -0.201 0.82232E+04 51 chloritoid-Fe 9.24 5.61 -3.63 -0.242 0.61942E+04 52 chloritoid-Mn 11.46 8.00 -3.47 -0.231 0.59176E+04 54 coesite -2.37 -3.19 -0.82 -0.273 0.13999E+04 61 cristobalite -2.55 -3.19 -0.64 -0.213 0.10928E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.04 -1.85 -0.309 0.31620E+04 67 diopside 16.22 15.65 -0.56 -0.056 0.96167E+03 68 hedenbergite 14.24 13.16 -1.08 -0.108 0.18454E+04 75 epidote 24.78 23.21 -1.57 -0.076 0.26788E+04 76 clinozoisite 22.92 19.23 -3.70 -0.168 0.63102E+04 77 epidote-Fe 29.94 27.19 -2.75 -0.143 0.46949E+04 78 fayalite 14.08 10.23 -3.84 -0.549 0.65646E+04 79 ferrosilite 11.19 7.05 -4.14 -0.414 0.70733E+04 83 gibbsite 4.10 1.04 -3.05 -0.436 0.52132E+04 84 glaucophane 23.11 20.57 -2.54 -0.069 0.43445E+04 85 glaucophane-Fe 17.42 13.10 -4.32 -0.117 0.73712E+04 87 greenalite 16.19 13.76 -2.44 -0.203 0.41617E+04 90 hematite 12.60 10.05 -2.55 -0.309 0.43499E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.86 -1.39 -0.139 0.23735E+04 96 julgoldite 70.57 65.71 -4.86 -0.126 0.83041E+04 97 kalsilite 7.62 3.95 -3.67 -0.525 0.62726E+04 98 kaolinite -1.27 -4.29 -3.02 -0.274 0.51512E+04 101 laumontite 2.97 2.16 -0.81 -0.054 0.13877E+04 102 lawsonite 9.68 8.54 -1.14 -0.076 0.19433E+04 103 leucite 4.17 0.76 -3.41 -0.341 0.58228E+04 105 lizardite 23.29 21.22 -2.06 -0.172 0.35252E+04 107 magnetite 20.13 16.76 -3.37 -0.275 0.57558E+04 108 minnesotaite 10.46 7.38 -3.08 -0.181 0.52629E+04 112 manganosite 14.07 9.10 -4.97 -1.242 0.84856E+04 120 muscovite 2.68 -0.34 -3.02 -0.178 0.51610E+04 121 paragonite 4.34 1.76 -2.58 -0.152 0.43994E+04 122 nepheline 8.38 6.05 -2.33 -0.333 0.39751E+04 128 periclase-Fe 11.64 6.71 -4.93 -1.232 0.84133E+04 134 phlogopite-Na 29.73 27.27 -2.46 -0.137 0.41978E+04 136 prehnite 19.47 18.18 -1.29 -0.076 0.21941E+04 137 prehnite-Fe 22.59 22.16 -0.42 -0.026 0.72505E+03 138 pumpellyite-Fe 46.47 44.12 -2.35 -0.052 0.40159E+04 139 pumpellyite-Mg 49.19 46.61 -2.59 -0.057 0.44169E+04 142 pyrite -21.23 -26.09 -4.86 -1.145 0.83061E+04 143 pyrrhotite -4.24 -8.00 -3.76 -1.253 0.64180E+04 144 pyrrhotiteFe0.875 -6.00 -9.26 -3.26 -1.198 0.55640E+04 145 pyroxmangite 7.42 5.91 -1.51 -0.301 0.25731E+04 146 pyrophyllite -6.10 -10.67 -4.57 -0.286 0.78039E+04 147 quartz -2.98 -3.19 -0.21 -0.069 0.35383E+03 152 rhodonite 7.46 5.91 -1.55 -0.311 0.26524E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.62 -1.97 -0.059 0.33700E+04 171 talc 16.55 14.84 -1.71 -0.101 0.29180E+04 174 tephroite 18.11 15.01 -3.11 -0.444 0.53027E+04 178 tridymite -2.61 -3.19 -0.57 -0.192 0.98112E+03 179 tremolite 48.00 46.15 -1.85 -0.050 0.31661E+04 180 ferroactinolite 38.60 33.71 -4.89 -0.132 0.83509E+04 181 troilite-low -4.39 -8.00 -3.61 -1.203 0.61612E+04 187 wairakite 4.06 2.16 -1.90 -0.112 0.32385E+04 188 walstromite 11.53 9.64 -1.89 -0.377 0.32217E+04 189 wollastonite 10.48 9.64 -0.84 -0.168 0.14356E+04 190 pseudo-wollastonite 11.02 9.64 -1.38 -0.276 0.23542E+04 191 zoisite 22.96 19.23 -3.74 -0.170 0.63827E+04 192 akaganeite 7.77 5.03 -2.74 -0.593 0.46831E+04 199 chalcedony -2.79 -3.19 -0.39 -0.132 0.67414E+03 201 montmorillonite-Ca -2.21 -5.86 -3.65 -0.226 0.62253E+04 202 montmorillonite-K -2.16 -5.97 -3.81 -0.233 0.64981E+04 203 montmorillonite-Mg -2.40 -6.46 -4.06 -0.251 0.69276E+04 204 montmorillonite-Na -1.96 -5.27 -3.31 -0.203 0.56550E+04 205 nontronite-Ca 3.28 0.81 -2.47 -0.160 0.42216E+04 206 nontronite-H 2.60 -1.31 -3.91 -0.262 0.66686E+04 207 nontronite-K 3.40 0.70 -2.70 -0.174 0.46159E+04 208 nontronite-Mg 3.14 0.21 -2.93 -0.190 0.50045E+04 209 nontronite-Na 3.58 1.39 -2.19 -0.140 0.37363E+04 224 tobermorite 9.84 7.50 -2.34 -0.639 0.39965E+04 230 alabandite -0.96 -5.62 -4.65 -1.551 0.79456E+04 233 boehmite 4.43 1.04 -3.39 -0.564 0.57805E+04 235 ferrous-oxide 9.82 6.71 -3.11 -0.778 0.53144E+04 240 silica-amorphous -2.08 -3.19 -1.11 -0.370 0.18943E+04 242 an20ab80 2.08 1.45 -0.63 -0.049 0.10823E+04 243 an25ab75 2.71 1.89 -0.82 -0.063 0.14007E+04 244 an30ab70 3.34 2.33 -1.01 -0.078 0.17276E+04 245 tr.625ac.25prg.125 45.31 44.10 -1.21 -0.033 0.20606E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 71.9990000 g New total amount of reactant added: 73.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1491E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 73.9990000 Water: Moles liquid = 0.5502E+02 kg liquid = 0.9912E+00 Moles total = 0.5458E+02 kg total = 0.9833E+00 Activity = 1.0000 Stoichiometric ionic strength = .9408444E-02 Osmotic coef. = 0.9644 True ionic strength = .1687387E-01 Chg. balance for total moles = -.1491E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10338E-09 -9.9856 0.87817E-10 -10.0564 0.84945E+00 -0.0709 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13865E-03 -3.8581 0.11716E-03 -3.9312 0.84500E+00 -0.0731 4 SO4-- 0.71206E-08 -8.1475 0.38693E-08 -8.4124 0.54340E+00 -0.2649 5 HCO3- 0.49798E-05 -5.3028 0.42133E-05 -5.3754 0.84607E+00 -0.0726 6 HS- 0.25717E-04 -4.5898 0.21733E-04 -4.6629 0.84511E+00 -0.0731 7 Al+++ 0.27777E-28 -28.5563 0.71190E-29 -29.1476 0.25629E+00 -0.5913 8 H4SiO4 0.65221E-03 -3.1856 0.65221E-03 -3.1856 0.10000E+01 0.0000 9 Ca++ 0.10113E-06 -6.9951 0.54606E-07 -7.2628 0.53994E+00 -0.2677 10 Mg++ 0.23195E-10 -10.6346 0.12474E-10 -10.9040 0.53779E+00 -0.2694 11 Fe++ 0.74126E-13 -13.1300 0.39903E-13 -13.3990 0.53830E+00 -0.2690 12 K+ 0.13166E-03 -3.8806 0.11142E-03 -3.9531 0.84625E+00 -0.0725 13 Na+ 0.16734E-01 -1.7764 0.14138E-01 -1.8496 0.84487E+00 -0.0732 14 Mn++ 0.18303E-10 -10.7375 0.98596E-11 -11.0061 0.53869E+00 -0.2687 15 HPO4-- 0.92174E-07 -7.0354 0.50093E-07 -7.3002 0.54346E+00 -0.2648 16 HSiO3- 0.85753E-02 -2.0668 0.72461E-02 -2.1399 0.84500E+00 -0.0731 17 Ca(HSiO3)+ 0.10474E-07 -7.9799 0.88654E-08 -8.0523 0.84641E+00 -0.0724 18 Mg(HSiO3)+ 0.29777E-11 -11.5261 0.25204E-11 -11.5985 0.84641E+00 -0.0724 19 NaHSiO3,aq 0.16271E-02 -2.7886 0.16271E-02 -2.7886 0.10000E+01 0.0000 20 AlO+ 0.14080E-15 -15.8514 0.11917E-15 -15.9238 0.84641E+00 -0.0724 22 HAlO2,aq 0.27156E-09 -9.5661 0.27156E-09 -9.5661 0.10000E+01 0.0000 23 AlO2- 0.81841E-05 -5.0870 0.69048E-05 -5.1608 0.84368E+00 -0.0738 24 CH4,aq 0.23289E-07 -7.6328 0.23222E-07 -7.6341 0.99712E+00 -0.0013 25 C2H6,aq 0.87576E-19 -19.0576 0.87324E-19 -19.0589 0.99712E+00 -0.0013 29 CO,aq 0.20462E-16 -16.6891 0.20462E-16 -16.6891 0.10000E+01 0.0000 30 CO2,aq 0.74814E-09 -9.1260 0.74599E-09 -9.1273 0.99712E+00 -0.0013 31 CO3-2 0.81786E-05 -5.0873 0.44360E-05 -5.3530 0.54239E+00 -0.2657 32 CaCO3,aq 0.29668E-08 -8.5277 0.29668E-08 -8.5277 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.68491E-11 -11.1644 0.57971E-11 -11.2368 0.84641E+00 -0.0724 34 CaCl+ 0.12045E-10 -10.9192 0.10195E-10 -10.9916 0.84641E+00 -0.0724 35 CaCl2,aq 0.27810E-15 -15.5558 0.27810E-15 -15.5558 0.10000E+01 0.0000 36 CaOH+ 0.51803E-07 -7.2856 0.43846E-07 -7.3581 0.84641E+00 -0.0724 37 CaSO4,aq 0.65832E-13 -13.1816 0.65832E-13 -13.1816 0.10000E+01 0.0000 38 HCl,aq 0.19353E-14 -14.7133 0.19353E-14 -14.7133 0.10000E+01 0.0000 43 FeCl+ 0.86027E-17 -17.0654 0.72814E-17 -17.1378 0.84641E+00 -0.0724 46 FeO,aq 0.20461E-09 -9.6891 0.20461E-09 -9.6891 0.10000E+01 0.0000 47 FeOH+ 0.17798E-10 -10.7496 0.15064E-10 -10.8221 0.84641E+00 -0.0724 48 HFeO2- 0.29658E-07 -7.5279 0.25061E-07 -7.6010 0.84500E+00 -0.0731 49 FeO+ 0.41968E-16 -16.3771 0.35522E-16 -16.4495 0.84641E+00 -0.0724 51 FeO2- 0.10714E-08 -8.9701 0.90530E-09 -9.0432 0.84500E+00 -0.0731 52 HFeO2,aq 0.99496E-11 -11.0022 0.99496E-11 -11.0022 0.10000E+01 0.0000 53 H2,aq 0.10681E-05 -5.9714 0.10650E-05 -5.9727 0.99712E+00 -0.0013 54 KCl,aq 0.23113E-09 -9.6361 0.23113E-09 -9.6361 0.10000E+01 0.0000 56 KOH,aq 0.55310E-06 -6.2572 0.55310E-06 -6.2572 0.10000E+01 0.0000 57 KSO4- 0.78600E-11 -11.1046 0.66417E-11 -11.1777 0.84500E+00 -0.0731 58 MgCO3,aq 0.16935E-12 -12.7712 0.16935E-12 -12.7712 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15954E-14 -14.7971 0.13504E-14 -14.8695 0.84641E+00 -0.0724 60 MgCl+ 0.24978E-14 -14.6024 0.21142E-14 -14.6749 0.84641E+00 -0.0724 61 MgOH+ 0.65559E-10 -10.1834 0.55489E-10 -10.2558 0.84641E+00 -0.0724 63 MnO,aq 0.13496E-08 -8.8698 0.13496E-08 -8.8698 0.10000E+01 0.0000 64 MnOH+ 0.40852E-09 -9.3888 0.34578E-09 -9.4612 0.84641E+00 -0.0724 65 MnO2-2 0.11159E-10 -10.9524 0.60524E-11 -11.2181 0.54239E+00 -0.2657 66 HMnO2- 0.13628E-09 -9.8656 0.11516E-09 -9.9387 0.84500E+00 -0.0731 69 MnCl+ 0.82600E-14 -14.0830 0.69913E-14 -14.1554 0.84641E+00 -0.0724 70 MnSO4,aq 0.10812E-16 -16.9661 0.10812E-16 -16.9661 0.10000E+01 0.0000 71 NaCl,aq 0.54085E-06 -6.2669 0.54085E-06 -6.2669 0.10000E+01 0.0000 72 NaOH,aq 0.70740E-04 -4.1503 0.70740E-04 -4.1503 0.10000E+01 0.0000 74 OH- 0.80961E-02 -2.0917 0.68305E-02 -2.1655 0.84368E+00 -0.0738 79 HPO3-2 0.31067E-15 -15.5077 0.16850E-15 -15.7734 0.54239E+00 -0.2657 81 H2PO3- 0.34399E-19 -19.4635 0.29067E-19 -19.5366 0.84500E+00 -0.0731 82 H3PO4,aq 0.24871E-17 -17.6043 0.24871E-17 -17.6043 0.10000E+01 0.0000 83 H2PO4- 0.91196E-10 -10.0400 0.77124E-10 -10.1128 0.84570E+00 -0.0728 84 PO4-3 0.18626E-08 -8.7299 0.49816E-09 -9.3026 0.26745E+00 -0.5728 88 HP2O7-3 0.42379E-17 -17.3729 0.10870E-17 -17.9638 0.25650E+00 -0.5909 89 P2O7-4 0.33060E-16 -16.4807 0.30537E-17 -17.5152 0.92368E-01 -1.0345 90 H2S,aq 0.57510E-08 -8.2403 0.57344E-08 -8.2415 0.99712E+00 -0.0013 91 S2-2 0.17984E-13 -13.7451 0.97547E-14 -14.0108 0.54239E+00 -0.2657 97 SO3-2 0.10230E-14 -14.9901 0.56186E-15 -15.2504 0.54921E+00 -0.2603 98 HSO3- 0.34172E-17 -17.4663 0.28875E-17 -17.5395 0.84500E+00 -0.0731 99 HSO4- 0.37218E-15 -15.4292 0.31528E-15 -15.5013 0.84712E+00 -0.0721 101 S2O3-2 0.48213E-18 -18.3168 0.26150E-18 -18.5825 0.54239E+00 -0.2657 Charge balance for all species = -.1541E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1033817E-09 -.1841105E-01 -.1853089E+02 0.0000 2 H2O 0.1000000E+01 0.5550623E+02 0.9985416E+06 0.0000 3 Cl- 0.1386511E-03 0.1391922E-03 0.4927775E+01 6.1252 4 SO4-- 0.7120612E-08 -.2830401E-06 -.2715068E-01 11.7005 5 HCO3- 0.4979793E-05 0.1318538E-04 0.8033928E+00 4.6810 6 HS- 0.2571675E-04 0.2601267E-04 0.8590694E+00 5.3936 7 Al+++ 0.2777733E-28 0.8184420E-05 0.2205144E+00 1.0217 8 H4SiO4 0.6522055E-03 0.1085456E-01 0.1041809E+04 -3.1856 9 Ca++ 0.1011342E-06 0.1663967E-06 0.6659377E-02 12.8501 10 Mg++ 0.2319472E-10 0.9190444E-10 0.2231208E-05 9.2088 11 Fe++ 0.7412645E-13 0.3096168E-07 0.1726662E-02 6.7138 12 K+ 0.1316584E-03 0.1322117E-03 0.5162401E+01 6.1034 13 Na+ 0.1673356E-01 0.1843190E-01 0.4231440E+03 8.2068 14 Mn++ 0.1830284E-10 0.1923908E-08 0.1055456E-03 9.1067 15 HPO4-- 0.9217447E-07 0.9412830E-07 0.9021513E-02 12.8126 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1225301E+01 -.1824994E-01 -.1207051E+01 0.0000000E+00 2 H2O 0.5458064E+02 0.5502051E+02 -.4398649E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2076269E-02 -.2805633E-06 0.2076550E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2050765E-02 0.2578503E-04 -.2076550E-02 0.0000000E+00 7 Al+++ 0.2412916E+00 0.8112799E-05 0.2412835E+00 0.0000000E+00 8 H4SiO4 0.7705355E+00 0.1075958E-01 0.7597759E+00 0.0000000E+00 9 Ca++ 0.8512388E-01 0.1649406E-06 0.8512371E-01 0.0000000E+00 10 Mg++ 0.5872937E-01 0.9110020E-10 0.5872936E-01 0.0000000E+00 11 Fe++ 0.5276192E-01 0.3069074E-07 0.5276189E-01 0.0000000E+00 12 K+ 0.1571104E-01 0.1310547E-03 0.1557999E-01 0.0000000E+00 13 Na+ 0.9304684E-01 0.1827061E-01 0.7477624E-01 0.0000000E+00 14 Mn++ 0.1283039E-02 0.1907073E-08 0.1283037E-02 0.0000000E+00 15 HPO4-- 0.4378948E-03 0.9330460E-07 0.4378014E-03 0.0000000E+00 Chg. balance for solid moles: -.1579E-15 Mass of aqueous solution: 0.992659E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 73.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7478E-01 -1.126 19.61 1.292 24.28 7.527 andradite 0.8306E-02 -2.081 4.221 0.625 5.227 1.097 grossular 0.1210E-02 -2.917 0.5450 -0.264 0.6749 0.1516 apatite-OH 0.1459E-03 -3.836 0.7331E-01 -1.135 0.9078E-01 0.2329E-01 clinochlore 0.1175E-01 -1.930 6.529 0.815 8.085 2.483 daphnite 0.3932E-02 -2.405 2.806 0.448 3.475 0.8502 chlorite-Mn 0.2566E-03 -3.591 0.1819 -0.740 0.2253 0.5798E-01 microcline 0.1393E-01 -1.856 3.878 0.589 4.802 1.515 stilbite 0.5585E-01 -1.253 39.36 1.595 48.74 18.36 stilpnomelane-Fe 0.3298E-02 -2.482 3.555 0.551 4.402 1.228 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8729E+00 0.8729E+00 1.0000 -0.059 grossular 0.1271E+00 0.1271E+00 1.0000 -0.896 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7371E+00 0.7371E+00 1.0000 -0.132 daphnite 0.2468E+00 0.2468E+00 1.0000 -0.608 chlorite-Mn 0.1610E-01 0.1610E-01 1.0000 -1.793 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 80.751539 g Volume = 33.288888 cm3 Porosity: -8.7886% V(tot) - V(min): -.26893E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 73.9990000 g log = 1.8692 Original solution: 1000.0103000 g Original solution / Rock added: 13.51 (Water/Rock Ratio), log = 1.1308 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0534 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9986E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.8047E-07 1.0073 0.8539E-07 0.8477E-07 CH4,gas 0.3441E-04 1.0129 0.3672E-04 0.3625E-04 H2,gas 0.1386E-02 1.0006 0.1461E-02 0.1460E-02 H2S,gas 0.1594E-06 0.9959 0.1672E-06 0.1679E-06 S2,gas 0.4661E-27 1.0000 0.4910E-27 0.4910E-27 CO,gas 0.3067E-13 1.0000 0.3231E-13 0.3231E-13 SO3,gas 0.1059E-43 1.0000 0.1116E-43 0.1116E-43 SO2,gas 0.5852E-24 1.0000 0.6164E-24 0.6164E-24 HCl,gas 0.3244E-17 1.0000 0.3417E-17 0.3417E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.37914E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.43 -9.07 -3.023 0.15484E+05 -7.069 3 CH4,gas 4.81 -1.63 -6.44 -1.609 0.10988E+05 -4.435 4 H2,gas 8.29 3.45 -4.84 -2.763 0.82564E+04 -2.835 5 H2S,gas -5.94 -14.72 -8.78 -4.388 0.14986E+05 -6.777 6 S2,gas -7.03 -36.34 -29.31 -4.509 0.50044E+05 -27.309 7 CO,gas 3.51 -11.98 -15.49 -4.766 0.26450E+05 -13.491 8 SO3,gas 17.43 -28.53 -45.95 -11.488 0.78463E+05 -43.953 9 SO2,gas 1.14 -25.07 -26.21 -6.989 0.44753E+05 -24.210 10 HCl,gas 5.48 -13.99 -19.47 -9.733 0.33238E+05 -17.466 11 acmite 7.74 6.82 -0.91 -0.095 0.15601E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.81 -4.74 -0.237 0.80990E+04 20 analcite 3.37 2.86 -0.51 -0.057 0.87659E+03 26 annite 20.21 17.71 -2.50 -0.139 0.42680E+04 27 phlogopite 27.15 25.19 -1.95 -0.108 0.33327E+04 29 anorthite 12.80 8.52 -4.28 -0.329 0.73002E+04 35 aragonite 0.99 -2.58 -3.57 -1.189 0.60922E+04 36 brucite 12.58 9.21 -3.37 -0.674 0.57503E+04 37 calcite 0.83 -2.58 -3.41 -1.138 0.58308E+04 38 carnegieite-low 9.06 6.04 -3.02 -0.432 0.51594E+04 39 carnegieite-high 10.13 6.04 -4.09 -0.585 0.69863E+04 40 carpholite-Mg 8.65 4.88 -3.77 -0.251 0.64361E+04 41 carpholite-Fe 6.78 2.39 -4.40 -0.293 0.75076E+04 42 celadonite 5.40 3.59 -1.81 -0.106 0.30889E+04 43 celadonite-Fe 3.94 1.10 -2.84 -0.167 0.48501E+04 44 chrysotile 23.94 21.26 -2.68 -0.224 0.45795E+04 49 chlorite-Al-free 47.26 42.51 -4.75 -0.198 0.81123E+04 51 chloritoid-Fe 9.24 5.57 -3.67 -0.244 0.62614E+04 52 chloritoid-Mn 11.46 7.96 -3.50 -0.233 0.59740E+04 54 coesite -2.37 -3.19 -0.82 -0.272 0.13938E+04 61 cristobalite -2.55 -3.19 -0.64 -0.212 0.10866E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.02 -1.87 -0.312 0.32005E+04 67 diopside 16.22 15.69 -0.53 -0.053 0.90115E+03 68 hedenbergite 14.24 13.19 -1.05 -0.105 0.17958E+04 75 epidote 24.78 23.17 -1.60 -0.078 0.27326E+04 76 clinozoisite 22.92 19.21 -3.71 -0.169 0.63395E+04 77 epidote-Fe 29.94 27.14 -2.80 -0.145 0.47733E+04 78 fayalite 14.08 10.24 -3.84 -0.548 0.65514E+04 79 ferrosilite 11.19 7.06 -4.13 -0.413 0.70540E+04 83 gibbsite 4.10 1.02 -3.08 -0.439 0.52517E+04 84 glaucophane 23.11 20.60 -2.51 -0.068 0.42891E+04 85 glaucophane-Fe 17.42 13.11 -4.30 -0.116 0.73483E+04 86 graphite -3.55 -8.53 -4.98 -1.423 0.85033E+04 87 greenalite 16.19 13.77 -2.42 -0.202 0.41388E+04 90 hematite 12.60 9.98 -2.62 -0.318 0.44760E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.86 -1.39 -0.139 0.23796E+04 96 julgoldite 70.57 65.67 -4.91 -0.127 0.83770E+04 97 kalsilite 7.62 3.94 -3.68 -0.526 0.62849E+04 98 kaolinite -1.27 -4.33 -3.05 -0.278 0.52159E+04 101 laumontite 2.97 2.15 -0.82 -0.055 0.14062E+04 102 lawsonite 9.68 8.52 -1.16 -0.077 0.19741E+04 103 leucite 4.17 0.75 -3.41 -0.341 0.58290E+04 105 lizardite 23.29 21.26 -2.03 -0.169 0.34698E+04 107 magnetite 20.13 16.69 -3.44 -0.281 0.58783E+04 108 minnesotaite 10.46 7.40 -3.06 -0.180 0.52277E+04 112 manganosite 14.07 9.11 -4.96 -1.240 0.84712E+04 120 muscovite 2.68 -0.39 -3.07 -0.180 0.52379E+04 121 paragonite 4.34 1.71 -2.62 -0.154 0.44763E+04 122 nepheline 8.38 6.04 -2.34 -0.334 0.39874E+04 128 periclase-Fe 11.64 6.71 -4.93 -1.231 0.84098E+04 134 phlogopite-Na 29.73 27.30 -2.43 -0.135 0.41546E+04 136 prehnite 19.47 18.19 -1.28 -0.075 0.21849E+04 137 prehnite-Fe 22.59 22.15 -0.43 -0.026 0.74044E+03 138 pumpellyite-Fe 46.47 44.11 -2.36 -0.052 0.40325E+04 139 pumpellyite-Mg 49.19 46.60 -2.59 -0.058 0.44226E+04 142 pyrite -21.23 -26.18 -4.95 -1.165 0.84535E+04 143 pyrrhotite -4.24 -8.01 -3.76 -1.254 0.64233E+04 144 pyrrhotiteFe0.875 -6.00 -9.27 -3.27 -1.203 0.55863E+04 145 pyroxmangite 7.42 5.92 -1.49 -0.299 0.25526E+04 146 pyrophyllite -6.10 -10.70 -4.60 -0.288 0.78562E+04 147 quartz -2.98 -3.19 -0.20 -0.068 0.34767E+03 152 rhodonite 7.46 5.92 -1.54 -0.308 0.26318E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.65 -1.94 -0.058 0.33157E+04 171 talc 16.55 14.88 -1.67 -0.098 0.28503E+04 174 tephroite 18.11 15.03 -3.09 -0.441 0.52677E+04 178 tridymite -2.61 -3.19 -0.57 -0.190 0.97496E+03 179 tremolite 48.00 46.26 -1.74 -0.047 0.29773E+04 180 ferroactinolite 38.60 33.78 -4.81 -0.130 0.82164E+04 181 troilite-low -4.39 -8.01 -3.61 -1.204 0.61665E+04 187 wairakite 4.06 2.15 -1.91 -0.112 0.32570E+04 188 walstromite 11.53 9.66 -1.86 -0.373 0.31817E+04 189 wollastonite 10.48 9.66 -0.82 -0.163 0.13956E+04 190 pseudo-wollastonite 11.02 9.66 -1.36 -0.271 0.23142E+04 191 zoisite 22.96 19.21 -3.76 -0.171 0.64120E+04 192 akaganeite 7.77 4.99 -2.78 -0.601 0.47461E+04 199 chalcedony -2.79 -3.19 -0.39 -0.130 0.66799E+03 201 montmorillonite-Ca -2.21 -5.88 -3.66 -0.227 0.62545E+04 202 montmorillonite-K -2.16 -5.98 -3.82 -0.234 0.65264E+04 203 montmorillonite-Mg -2.40 -6.48 -4.08 -0.252 0.69601E+04 204 montmorillonite-Na -1.96 -5.29 -3.33 -0.204 0.56833E+04 205 nontronite-Ca 3.28 0.74 -2.54 -0.165 0.43322E+04 206 nontronite-H 2.60 -1.38 -3.97 -0.266 0.67848E+04 207 nontronite-K 3.40 0.64 -2.77 -0.178 0.47255E+04 208 nontronite-Mg 3.14 0.14 -3.00 -0.194 0.51184E+04 209 nontronite-Na 3.58 1.33 -2.25 -0.145 0.38459E+04 224 tobermorite 9.84 7.52 -2.32 -0.633 0.39622E+04 230 alabandite -0.96 -5.61 -4.65 -1.550 0.79401E+04 233 boehmite 4.43 1.02 -3.41 -0.568 0.58189E+04 235 ferrous-oxide 9.82 6.71 -3.11 -0.778 0.53109E+04 240 silica-amorphous -2.08 -3.19 -1.11 -0.369 0.18882E+04 242 an20ab80 2.08 1.44 -0.64 -0.049 0.10884E+04 243 an25ab75 2.71 1.88 -0.82 -0.063 0.14084E+04 244 an30ab70 3.34 2.33 -1.02 -0.078 0.17368E+04 245 tr.625ac.25prg.125 45.31 44.19 -1.11 -0.030 0.19006E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 73.9990000 g New total amount of reactant added: 75.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1492E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 75.9990000 Water: Moles liquid = 0.5501E+02 kg liquid = 0.9910E+00 Moles total = 0.5456E+02 kg total = 0.9828E+00 Activity = 1.0000 Stoichiometric ionic strength = .9572394E-02 Osmotic coef. = 0.9642 True ionic strength = .1714624E-01 Chg. balance for total moles = -.1492E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10235E-09 -9.9899 0.86862E-10 -10.0612 0.84864E+00 -0.0713 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13867E-03 -3.8580 0.11706E-03 -3.9316 0.84415E+00 -0.0736 4 SO4-- 0.36212E-08 -8.4411 0.19600E-08 -8.7077 0.54125E+00 -0.2666 5 HCO3- 0.49296E-05 -5.3072 0.41666E-05 -5.3802 0.84523E+00 -0.0730 6 HS- 0.25726E-04 -4.5896 0.21719E-04 -4.6632 0.84425E+00 -0.0735 7 Al+++ 0.25783E-28 -28.5887 0.65485E-29 -29.1839 0.25398E+00 -0.5952 8 H4SiO4 0.65761E-03 -3.1820 0.65761E-03 -3.1820 0.10000E+01 0.0000 9 Ca++ 0.10378E-06 -6.9839 0.55806E-07 -7.2533 0.53776E+00 -0.2694 10 Mg++ 0.23220E-10 -10.6341 0.12436E-10 -10.9053 0.53560E+00 -0.2712 11 Fe++ 0.73145E-13 -13.1358 0.39214E-13 -13.4066 0.53612E+00 -0.2707 12 K+ 0.13378E-03 -3.8736 0.11310E-03 -3.9465 0.84541E+00 -0.0729 13 Na+ 0.17004E-01 -1.7695 0.14351E-01 -1.8431 0.84401E+00 -0.0737 14 Mn++ 0.18322E-10 -10.7370 0.98299E-11 -11.0075 0.53651E+00 -0.2704 15 HPO4-- 0.87954E-07 -7.0557 0.47611E-07 -7.3223 0.54132E+00 -0.2665 16 HSiO3- 0.87504E-02 -2.0580 0.73866E-02 -2.1316 0.84415E+00 -0.0736 17 Ca(HSiO3)+ 0.10923E-07 -7.9617 0.92359E-08 -8.0345 0.84557E+00 -0.0729 18 Mg(HSiO3)+ 0.30293E-11 -11.5187 0.25615E-11 -11.5915 0.84557E+00 -0.0729 19 NaHSiO3,aq 0.16837E-02 -2.7737 0.16837E-02 -2.7737 0.10000E+01 0.0000 20 AlO+ 0.13251E-15 -15.8777 0.11205E-15 -15.9506 0.84557E+00 -0.0729 22 HAlO2,aq 0.25813E-09 -9.5882 0.25813E-09 -9.5882 0.10000E+01 0.0000 23 AlO2- 0.78731E-05 -5.1039 0.66355E-05 -5.1781 0.84281E+00 -0.0743 24 CH4,aq 0.45440E-07 -7.3426 0.45307E-07 -7.3438 0.99707E+00 -0.0013 25 C2H6,aq 0.28052E-18 -18.5520 0.27970E-18 -18.5533 0.99707E+00 -0.0013 29 CO,aq 0.23786E-16 -16.6237 0.23786E-16 -16.6237 0.10000E+01 0.0000 30 CO2,aq 0.73185E-09 -9.1356 0.72970E-09 -9.1369 0.99707E+00 -0.0013 31 CO3-2 0.82096E-05 -5.0857 0.44351E-05 -5.3531 0.54024E+00 -0.2674 32 CaCO3,aq 0.30314E-08 -8.5184 0.30314E-08 -8.5184 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.69290E-11 -11.1593 0.58589E-11 -11.2322 0.84557E+00 -0.0729 34 CaCl+ 0.12311E-10 -10.9097 0.10410E-10 -10.9826 0.84557E+00 -0.0729 35 CaCl2,aq 0.28374E-15 -15.5471 0.28374E-15 -15.5471 0.10000E+01 0.0000 36 CaOH+ 0.53577E-07 -7.2710 0.45303E-07 -7.3439 0.84557E+00 -0.0729 37 CaSO4,aq 0.34080E-13 -13.4675 0.34080E-13 -13.4675 0.10000E+01 0.0000 38 HCl,aq 0.19126E-14 -14.7184 0.19126E-14 -14.7184 0.10000E+01 0.0000 43 FeCl+ 0.84556E-17 -17.0729 0.71498E-17 -17.1457 0.84557E+00 -0.0729 46 FeO,aq 0.20553E-09 -9.6871 0.20553E-09 -9.6871 0.10000E+01 0.0000 47 FeOH+ 0.17700E-10 -10.7520 0.14967E-10 -10.8249 0.84557E+00 -0.0729 48 HFeO2- 0.30149E-07 -7.5207 0.25450E-07 -7.5943 0.84415E+00 -0.0736 49 FeO+ 0.38288E-16 -16.4169 0.32375E-16 -16.4898 0.84557E+00 -0.0729 51 FeO2- 0.99906E-09 -9.0004 0.84335E-09 -9.0740 0.84415E+00 -0.0736 52 HFeO2,aq 0.91679E-11 -11.0377 0.91679E-11 -11.0377 0.10000E+01 0.0000 53 H2,aq 0.12693E-05 -5.8964 0.12656E-05 -5.8977 0.99707E+00 -0.0013 54 KCl,aq 0.23443E-09 -9.6300 0.23443E-09 -9.6300 0.10000E+01 0.0000 56 KOH,aq 0.56763E-06 -6.2459 0.56763E-06 -6.2459 0.10000E+01 0.0000 57 KSO4- 0.40458E-11 -11.3930 0.34152E-11 -11.4666 0.84415E+00 -0.0736 58 MgCO3,aq 0.16880E-12 -12.7726 0.16880E-12 -12.7726 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15746E-14 -14.8028 0.13314E-14 -14.8757 0.84557E+00 -0.0729 60 MgCl+ 0.24907E-14 -14.6037 0.21060E-14 -14.6765 0.84557E+00 -0.0729 61 MgOH+ 0.66146E-10 -10.1795 0.55931E-10 -10.2523 0.84557E+00 -0.0729 63 MnO,aq 0.13753E-08 -8.8616 0.13753E-08 -8.8616 0.10000E+01 0.0000 64 MnOH+ 0.41218E-09 -9.3849 0.34853E-09 -9.4578 0.84557E+00 -0.0729 65 MnO2-2 0.11669E-10 -10.9330 0.63040E-11 -11.2004 0.54024E+00 -0.2674 66 HMnO2- 0.14054E-09 -9.8522 0.11864E-09 -9.9258 0.84415E+00 -0.0736 69 MnCl+ 0.82363E-14 -14.0843 0.69644E-14 -14.1571 0.84557E+00 -0.0729 70 MnSO4,aq 0.54602E-17 -17.2628 0.54602E-17 -17.2628 0.10000E+01 0.0000 71 NaCl,aq 0.54856E-06 -6.2608 0.54856E-06 -6.2608 0.10000E+01 0.0000 72 NaOH,aq 0.72599E-04 -4.1391 0.72599E-04 -4.1391 0.10000E+01 0.0000 74 OH- 0.81936E-02 -2.0865 0.69056E-02 -2.1608 0.84281E+00 -0.0743 79 HPO3-2 0.35230E-15 -15.4531 0.19033E-15 -15.7205 0.54024E+00 -0.2674 81 H2PO3- 0.38470E-19 -19.4149 0.32475E-19 -19.4885 0.84415E+00 -0.0736 82 H3PO4,aq 0.23127E-17 -17.6359 0.23127E-17 -17.6359 0.10000E+01 0.0000 83 H2PO4- 0.85821E-10 -10.0664 0.72505E-10 -10.1396 0.84485E+00 -0.0732 84 PO4-3 0.18051E-08 -8.7435 0.47868E-09 -9.3200 0.26519E+00 -0.5764 88 HP2O7-3 0.38210E-17 -17.4178 0.97128E-18 -18.0127 0.25420E+00 -0.5948 89 P2O7-4 0.30339E-16 -16.5180 0.27586E-17 -17.5593 0.90926E-01 -1.0413 90 H2S,aq 0.56850E-08 -8.2453 0.56684E-08 -8.2465 0.99707E+00 -0.0013 91 S2-2 0.15174E-13 -13.8189 0.81976E-14 -14.0863 0.54024E+00 -0.2674 97 SO3-2 0.61821E-15 -15.2089 0.33823E-15 -15.4708 0.54712E+00 -0.2619 98 HSO3- 0.20368E-17 -17.6911 0.17193E-17 -17.7646 0.84415E+00 -0.0736 99 HSO4- 0.18666E-15 -15.7290 0.15797E-15 -15.8014 0.84629E+00 -0.0725 101 S2O3-2 0.24237E-18 -18.6155 0.13094E-18 -18.8829 0.54024E+00 -0.2674 Charge balance for all species = -.1552E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1023541E-09 -.1874100E-01 -.1886246E+02 0.0000 2 H2O 0.1000000E+01 0.5550610E+02 0.9985116E+06 0.0000 3 Cl- 0.1386748E-03 0.1392236E-03 0.4928749E+01 6.1296 4 SO4-- 0.3621212E-08 -.3590239E-06 -.3443849E-01 11.4146 5 HCO3- 0.4929586E-05 0.1318835E-04 0.8035515E+00 4.6810 6 HS- 0.2572611E-04 0.2609444E-04 0.8617463E+00 5.3980 7 Al+++ 0.2578329E-28 0.7873379E-05 0.2121281E+00 0.9997 8 H4SiO4 0.6576149E-03 0.1109168E-01 0.1064538E+04 -3.1820 9 Ca++ 0.1037750E-06 0.1713251E-06 0.6856427E-02 12.8690 10 Mg++ 0.2321961E-10 0.9256768E-10 0.2247248E-05 9.2170 11 Fe++ 0.7314534E-13 0.3138077E-07 0.1749985E-02 6.7158 12 K+ 0.1337815E-03 0.1343494E-03 0.5245726E+01 6.1146 13 Na+ 0.1700377E-01 0.1876059E-01 0.4306778E+03 8.2181 14 Mn++ 0.1832209E-10 0.1958061E-08 0.1074162E-03 9.1149 15 HPO4-- 0.8795391E-07 0.8984480E-07 0.8610732E-02 12.8001 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1258418E+01 -.1857282E-01 -.1239845E+01 0.0000000E+00 2 H2O 0.5455557E+02 0.5500799E+02 -.4524159E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2131696E-02 -.3558020E-06 0.2132052E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2106191E-02 0.2586027E-04 -.2132052E-02 0.0000000E+00 7 Al+++ 0.2478131E+00 0.7802723E-05 0.2478053E+00 0.0000000E+00 8 H4SiO4 0.7913611E+00 0.1099214E-01 0.7803689E+00 0.0000000E+00 9 Ca++ 0.8742416E-01 0.1697876E-06 0.8742399E-01 0.0000000E+00 10 Mg++ 0.6031667E-01 0.9173697E-10 0.6031667E-01 0.0000000E+00 11 Fe++ 0.5418794E-01 0.3109916E-07 0.5418791E-01 0.0000000E+00 12 K+ 0.1613567E-01 0.1331438E-03 0.1600253E-01 0.0000000E+00 13 Na+ 0.9555733E-01 0.1859223E-01 0.7696510E-01 0.0000000E+00 14 Mn++ 0.1317716E-02 0.1940489E-08 0.1317714E-02 0.0000000E+00 15 HPO4-- 0.4497299E-03 0.8903853E-07 0.4496409E-03 0.0000000E+00 Chg. balance for solid moles: -.1496E-15 Mass of aqueous solution: 0.992463E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 75.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7697E-01 -1.114 20.18 1.305 24.34 7.747 andradite 0.8528E-02 -2.069 4.334 0.637 5.226 1.126 grossular 0.1281E-02 -2.892 0.5772 -0.239 0.6961 0.1606 apatite-OH 0.1499E-03 -3.824 0.7529E-01 -1.123 0.9078E-01 0.2392E-01 clinochlore 0.1206E-01 -1.919 6.705 0.826 8.085 2.550 daphnite 0.3981E-02 -2.400 2.840 0.453 3.425 0.8607 chlorite-Mn 0.2635E-03 -3.579 0.1868 -0.729 0.2253 0.5954E-01 microcline 0.1428E-01 -1.845 3.975 0.599 4.793 1.553 stilbite 0.5725E-01 -1.242 40.34 1.606 48.65 18.82 stilpnomelane-Fe 0.3445E-02 -2.463 3.714 0.570 4.478 1.283 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8694E+00 0.8694E+00 1.0000 -0.061 grossular 0.1306E+00 0.1306E+00 1.0000 -0.884 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7397E+00 0.7397E+00 1.0000 -0.131 daphnite 0.2441E+00 0.2441E+00 1.0000 -0.612 chlorite-Mn 0.1616E-01 0.1616E-01 1.0000 -1.792 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 82.931405 g Volume = 34.180361 cm3 Porosity: -8.8560% V(tot) - V(min): -.27808E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 75.9990000 g log = 1.8808 Original solution: 1000.0103000 g Original solution / Rock added: 13.16 (Water/Rock Ratio), log = 1.1192 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0538 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9983E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.7869E-07 1.0073 0.8353E-07 0.8292E-07 CH4,gas 0.6712E-04 1.0129 0.7165E-04 0.7073E-04 H2,gas 0.1646E-02 1.0006 0.1736E-02 0.1735E-02 H2S,gas 0.1575E-06 0.9959 0.1653E-06 0.1660E-06 S2,gas 0.3224E-27 1.0000 0.3397E-27 0.3397E-27 CO,gas 0.3564E-13 1.0000 0.3756E-13 0.3756E-13 SO3,gas 0.5247E-44 1.0000 0.5529E-44 0.5529E-44 SO2,gas 0.3445E-24 1.0000 0.3631E-24 0.3631E-24 HCl,gas 0.3205E-17 1.0000 0.3377E-17 0.3377E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 116 microcline -2.43 -2.43 0.00 0.000 0.18957E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.62178E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.44 -9.08 -3.026 0.15501E+05 -7.078 3 CH4,gas 4.81 -1.34 -6.14 -1.536 0.10492E+05 -4.145 4 H2,gas 8.29 3.53 -4.76 -2.720 0.81284E+04 -2.760 5 H2S,gas -5.94 -14.72 -8.78 -4.391 0.14994E+05 -6.782 6 S2,gas -7.03 -36.50 -29.47 -4.534 0.50317E+05 -27.469 7 CO,gas 3.51 -11.91 -15.43 -4.746 0.26338E+05 -13.425 8 SO3,gas 17.43 -28.83 -46.26 -11.564 0.78983E+05 -44.257 9 SO2,gas 1.14 -25.30 -26.44 -7.051 0.45146E+05 -24.440 10 HCl,gas 5.48 -13.99 -19.47 -9.736 0.33247E+05 -17.471 11 acmite 7.74 6.81 -0.93 -0.097 0.15893E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.80 -4.75 -0.238 0.81139E+04 20 analcite 3.37 2.85 -0.52 -0.057 0.88271E+03 26 annite 20.21 17.72 -2.49 -0.139 0.42580E+04 27 phlogopite 27.15 25.22 -1.93 -0.107 0.32908E+04 29 anorthite 12.80 8.50 -4.29 -0.330 0.73309E+04 35 aragonite 0.99 -2.57 -3.56 -1.186 0.60762E+04 36 brucite 12.58 9.22 -3.36 -0.672 0.57364E+04 37 calcite 0.83 -2.57 -3.41 -1.135 0.58148E+04 38 carnegieite-low 9.06 6.04 -3.03 -0.433 0.51717E+04 39 carnegieite-high 10.13 6.04 -4.10 -0.586 0.69986E+04 40 carpholite-Mg 8.65 4.85 -3.80 -0.253 0.64851E+04 41 carpholite-Fe 6.78 2.35 -4.43 -0.295 0.75673E+04 42 celadonite 5.40 3.60 -1.80 -0.106 0.30688E+04 43 celadonite-Fe 3.94 1.10 -2.83 -0.167 0.48406E+04 44 chrysotile 23.94 21.29 -2.65 -0.221 0.45253E+04 49 chlorite-Al-free 47.26 42.57 -4.69 -0.195 0.80039E+04 51 chloritoid-Fe 9.24 5.53 -3.71 -0.247 0.63272E+04 52 chloritoid-Mn 11.46 7.93 -3.53 -0.235 0.60291E+04 54 coesite -2.37 -3.18 -0.81 -0.271 0.13876E+04 61 cristobalite -2.55 -3.18 -0.63 -0.211 0.10805E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 1.00 -1.90 -0.316 0.32381E+04 67 diopside 16.22 15.72 -0.49 -0.049 0.84257E+03 68 hedenbergite 14.24 13.22 -1.02 -0.102 0.17479E+04 75 epidote 24.78 23.14 -1.63 -0.079 0.27855E+04 76 clinozoisite 22.92 19.19 -3.73 -0.170 0.63692E+04 77 epidote-Fe 29.94 27.10 -2.84 -0.148 0.48492E+04 78 fayalite 14.08 10.25 -3.83 -0.547 0.65386E+04 79 ferrosilite 11.19 7.07 -4.12 -0.412 0.70351E+04 83 gibbsite 4.10 1.00 -3.10 -0.443 0.52893E+04 84 glaucophane 23.11 20.63 -2.48 -0.067 0.42349E+04 85 glaucophane-Fe 17.42 13.13 -4.29 -0.116 0.73261E+04 86 graphite -3.55 -8.39 -4.84 -1.383 0.82637E+04 87 greenalite 16.19 13.78 -2.41 -0.201 0.41165E+04 90 hematite 12.60 9.91 -2.69 -0.326 0.45973E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.85 -1.40 -0.140 0.23857E+04 96 julgoldite 70.57 65.63 -4.95 -0.128 0.84469E+04 97 kalsilite 7.62 3.93 -3.69 -0.527 0.62971E+04 98 kaolinite -1.27 -4.36 -3.09 -0.281 0.52788E+04 101 laumontite 2.97 2.14 -0.83 -0.056 0.14246E+04 102 lawsonite 9.68 8.50 -1.17 -0.078 0.20047E+04 103 leucite 4.17 0.75 -3.42 -0.342 0.58351E+04 105 lizardite 23.29 21.29 -2.00 -0.167 0.34156E+04 107 magnetite 20.13 16.62 -3.51 -0.287 0.59964E+04 108 minnesotaite 10.46 7.42 -3.04 -0.179 0.51932E+04 112 manganosite 14.07 9.11 -4.95 -1.238 0.84572E+04 120 muscovite 2.68 -0.43 -3.11 -0.183 0.53131E+04 121 paragonite 4.34 1.67 -2.67 -0.157 0.45516E+04 122 nepheline 8.38 6.04 -2.34 -0.335 0.39996E+04 128 periclase-Fe 11.64 6.72 -4.92 -1.231 0.84065E+04 134 phlogopite-Na 29.73 27.32 -2.41 -0.134 0.41127E+04 136 prehnite 19.47 18.19 -1.28 -0.075 0.21771E+04 137 prehnite-Fe 22.59 22.14 -0.44 -0.027 0.75567E+03 138 pumpellyite-Fe 46.47 44.10 -2.37 -0.053 0.40511E+04 139 pumpellyite-Mg 49.19 46.60 -2.59 -0.058 0.44305E+04 143 pyrrhotite -4.24 -8.01 -3.76 -1.255 0.64286E+04 144 pyrrhotiteFe0.875 -6.00 -9.29 -3.28 -1.208 0.56078E+04 145 pyroxmangite 7.42 5.93 -1.48 -0.297 0.25325E+04 146 pyrophyllite -6.10 -10.73 -4.63 -0.289 0.79069E+04 147 quartz -2.98 -3.18 -0.20 -0.067 0.34155E+03 152 rhodonite 7.46 5.93 -1.53 -0.306 0.26117E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.69 -1.91 -0.057 0.32624E+04 171 talc 16.55 14.92 -1.63 -0.096 0.27838E+04 174 tephroite 18.11 15.05 -3.07 -0.438 0.52336E+04 178 tridymite -2.61 -3.18 -0.57 -0.189 0.96884E+03 179 tremolite 48.00 46.37 -1.64 -0.044 0.27937E+04 180 ferroactinolite 38.60 33.86 -4.74 -0.128 0.80861E+04 181 troilite-low -4.39 -8.01 -3.61 -1.205 0.61718E+04 187 wairakite 4.06 2.14 -1.92 -0.113 0.32754E+04 188 walstromite 11.53 9.69 -1.84 -0.368 0.31432E+04 189 wollastonite 10.48 9.69 -0.79 -0.159 0.13571E+04 190 pseudo-wollastonite 11.02 9.69 -1.33 -0.267 0.22758E+04 191 zoisite 22.96 19.19 -3.77 -0.171 0.64418E+04 192 akaganeite 7.77 4.95 -2.82 -0.609 0.48068E+04 199 chalcedony -2.79 -3.18 -0.39 -0.129 0.66186E+03 201 montmorillonite-Ca -2.21 -5.89 -3.68 -0.228 0.62829E+04 202 montmorillonite-K -2.16 -6.00 -3.84 -0.235 0.65537E+04 203 montmorillonite-Mg -2.40 -6.50 -4.09 -0.253 0.69915E+04 204 montmorillonite-Na -1.96 -5.31 -3.34 -0.205 0.57106E+04 205 nontronite-Ca 3.28 0.68 -2.60 -0.169 0.44382E+04 206 nontronite-H 2.60 -1.44 -4.04 -0.271 0.68960E+04 207 nontronite-K 3.40 0.57 -2.83 -0.182 0.48304E+04 208 nontronite-Mg 3.14 0.08 -3.06 -0.199 0.52273E+04 209 nontronite-Na 3.58 1.27 -2.31 -0.149 0.39509E+04 224 tobermorite 9.84 7.54 -2.30 -0.628 0.39291E+04 230 alabandite -0.96 -5.61 -4.65 -1.549 0.79347E+04 233 boehmite 4.43 1.00 -3.43 -0.572 0.58565E+04 235 ferrous-oxide 9.82 6.72 -3.11 -0.777 0.53076E+04 240 silica-amorphous -2.08 -3.18 -1.10 -0.367 0.18821E+04 242 an20ab80 2.08 1.44 -0.64 -0.049 0.10946E+04 243 an25ab75 2.71 1.88 -0.83 -0.064 0.14161E+04 244 an30ab70 3.34 2.32 -1.02 -0.079 0.17460E+04 245 tr.625ac.25prg.125 45.31 44.29 -1.02 -0.028 0.17453E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 75.9990000 g New total amount of reactant added: 77.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1490E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 77.9990000 Water: Moles liquid = 0.5500E+02 kg liquid = 0.9908E+00 Moles total = 0.5453E+02 kg total = 0.9824E+00 Activity = 1.0000 Stoichiometric ionic strength = .9734289E-02 Osmotic coef. = 0.9640 True ionic strength = .1741421E-01 Chg. balance for total moles = -.1490E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10138E-09 -9.9940 0.85958E-10 -10.0657 0.84786E+00 -0.0717 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13870E-03 -3.8579 0.11697E-03 -3.9319 0.84331E+00 -0.0740 4 SO4-- 0.18892E-08 -8.7237 0.10186E-08 -8.9920 0.53917E+00 -0.2683 5 HCO3- 0.48744E-05 -5.3121 0.41160E-05 -5.3855 0.84441E+00 -0.0734 6 HS- 0.25734E-04 -4.5895 0.21704E-04 -4.6635 0.84342E+00 -0.0740 7 Al+++ 0.23987E-28 -28.6200 0.60390E-29 -29.2190 0.25176E+00 -0.5990 8 H4SiO4 0.66303E-03 -3.1785 0.66303E-03 -3.1785 0.10000E+01 0.0000 9 Ca++ 0.10638E-06 -6.9732 0.56982E-07 -7.2443 0.53565E+00 -0.2711 10 Mg++ 0.23252E-10 -10.6335 0.12404E-10 -10.9064 0.53347E+00 -0.2729 11 Fe++ 0.72219E-13 -13.1413 0.38564E-13 -13.4138 0.53399E+00 -0.2725 12 K+ 0.13587E-03 -3.8669 0.11475E-03 -3.9402 0.84459E+00 -0.0734 13 Na+ 0.17270E-01 -1.7627 0.14561E-01 -1.8368 0.84318E+00 -0.0741 14 Mn++ 0.18347E-10 -10.7364 0.98046E-11 -11.0086 0.53439E+00 -0.2721 15 HPO4-- 0.84097E-07 -7.0752 0.45349E-07 -7.3434 0.53924E+00 -0.2682 16 HSiO3- 0.89241E-02 -2.0494 0.75258E-02 -2.1234 0.84331E+00 -0.0740 17 Ca(HSiO3)+ 0.11374E-07 -7.9441 0.96081E-08 -8.0174 0.84475E+00 -0.0733 18 Mg(HSiO3)+ 0.30814E-11 -11.5112 0.26030E-11 -11.5845 0.84475E+00 -0.0733 19 NaHSiO3,aq 0.17405E-02 -2.7593 0.17405E-02 -2.7593 0.10000E+01 0.0000 20 AlO+ 0.12491E-15 -15.9034 0.10551E-15 -15.9767 0.84475E+00 -0.0733 22 HAlO2,aq 0.24564E-09 -9.6097 0.24564E-09 -9.6097 0.10000E+01 0.0000 23 AlO2- 0.75785E-05 -5.1204 0.63808E-05 -5.1951 0.84196E+00 -0.0747 24 CH4,aq 0.86318E-07 -7.0639 0.86061E-07 -7.0652 0.99702E+00 -0.0013 25 C2H6,aq 0.85734E-18 -18.0668 0.85479E-18 -18.0681 0.99702E+00 -0.0013 29 CO,aq 0.27453E-16 -16.5614 0.27453E-16 -16.5614 0.10000E+01 0.0000 30 CO2,aq 0.71546E-09 -9.1454 0.71333E-09 -9.1467 0.99702E+00 -0.0013 31 CO3-2 0.82268E-05 -5.0848 0.44273E-05 -5.3539 0.53816E+00 -0.2691 32 CaCO3,aq 0.30898E-08 -8.5101 0.30898E-08 -8.5101 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.69957E-11 -11.1552 0.59096E-11 -11.2284 0.84475E+00 -0.0733 34 CaCl+ 0.12572E-10 -10.9006 0.10620E-10 -10.9739 0.84475E+00 -0.0733 35 CaCl2,aq 0.28924E-15 -15.5387 0.28924E-15 -15.5387 0.10000E+01 0.0000 36 CaOH+ 0.55334E-07 -7.2570 0.46743E-07 -7.3303 0.84475E+00 -0.0733 37 CaSO4,aq 0.18084E-13 -13.7427 0.18084E-13 -13.7427 0.10000E+01 0.0000 38 HCl,aq 0.18912E-14 -14.7233 0.18912E-14 -14.7233 0.10000E+01 0.0000 43 FeCl+ 0.83167E-17 -17.0800 0.70255E-17 -17.1533 0.84475E+00 -0.0733 46 FeO,aq 0.20640E-09 -9.6853 0.20640E-09 -9.6853 0.10000E+01 0.0000 47 FeOH+ 0.17607E-10 -10.7543 0.14874E-10 -10.8276 0.84475E+00 -0.0733 48 HFeO2- 0.30625E-07 -7.5139 0.25827E-07 -7.5879 0.84331E+00 -0.0740 49 FeO+ 0.35052E-16 -16.4553 0.29610E-16 -16.5286 0.84475E+00 -0.0733 51 FeO2- 0.93397E-09 -9.0297 0.78762E-09 -9.1037 0.84331E+00 -0.0740 52 HFeO2,aq 0.84730E-11 -11.0720 0.84730E-11 -11.0720 0.10000E+01 0.0000 53 H2,aq 0.14987E-05 -5.8243 0.14943E-05 -5.8256 0.99702E+00 -0.0013 54 KCl,aq 0.23766E-09 -9.6240 0.23766E-09 -9.6240 0.10000E+01 0.0000 56 KOH,aq 0.58199E-06 -6.2351 0.58199E-06 -6.2351 0.10000E+01 0.0000 57 KSO4- 0.21354E-11 -11.6705 0.18008E-11 -11.7445 0.84331E+00 -0.0740 58 MgCO3,aq 0.16807E-12 -12.7745 0.16807E-12 -12.7745 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15530E-14 -14.8088 0.13119E-14 -14.8821 0.84475E+00 -0.0733 60 MgCl+ 0.24846E-14 -14.6047 0.20989E-14 -14.6780 0.84475E+00 -0.0733 61 MgOH+ 0.66734E-10 -10.1757 0.56374E-10 -10.2489 0.84475E+00 -0.0733 63 MnO,aq 0.14008E-08 -8.8536 0.14008E-08 -8.8536 0.10000E+01 0.0000 64 MnOH+ 0.41585E-09 -9.3811 0.35129E-09 -9.4543 0.84475E+00 -0.0733 65 MnO2-2 0.12183E-10 -10.9142 0.65566E-11 -11.1833 0.53816E+00 -0.2691 66 HMnO2- 0.14480E-09 -9.8392 0.12211E-09 -9.9133 0.84331E+00 -0.0740 69 MnCl+ 0.82164E-14 -14.0853 0.69408E-14 -14.1586 0.84475E+00 -0.0733 70 MnSO4,aq 0.28303E-17 -17.5482 0.28303E-17 -17.5482 0.10000E+01 0.0000 71 NaCl,aq 0.55613E-06 -6.2548 0.55613E-06 -6.2548 0.10000E+01 0.0000 72 NaOH,aq 0.74436E-04 -4.1282 0.74436E-04 -4.1282 0.10000E+01 0.0000 74 OH- 0.82881E-02 -2.0815 0.69783E-02 -2.1563 0.84196E+00 -0.0747 79 HPO3-2 0.39772E-15 -15.4004 0.21403E-15 -15.6695 0.53816E+00 -0.2691 81 H2PO3- 0.42854E-19 -19.3680 0.36140E-19 -19.4420 0.84331E+00 -0.0740 82 H3PO4,aq 0.21572E-17 -17.6661 0.21572E-17 -17.6661 0.10000E+01 0.0000 83 H2PO4- 0.80971E-10 -10.0917 0.68341E-10 -10.1653 0.84402E+00 -0.0736 84 PO4-3 0.17518E-08 -8.7565 0.46073E-09 -9.3365 0.26301E+00 -0.5800 88 HP2O7-3 0.34607E-17 -17.4608 0.87200E-18 -18.0595 0.25197E+00 -0.5986 89 P2O7-4 0.27949E-16 -16.5536 0.25026E-17 -17.6016 0.89543E-01 -1.0480 90 H2S,aq 0.56222E-08 -8.2501 0.56055E-08 -8.2514 0.99702E+00 -0.0013 91 S2-2 0.12884E-13 -13.8899 0.69336E-14 -14.1590 0.53816E+00 -0.2691 97 SO3-2 0.38073E-15 -15.4194 0.20753E-15 -15.6829 0.54509E+00 -0.2635 98 HSO3- 0.12379E-17 -17.9073 0.10440E-17 -17.9813 0.84331E+00 -0.0740 99 HSO4- 0.96086E-16 -16.0173 0.81239E-16 -16.0902 0.84548E+00 -0.0729 101 S2O3-2 0.12504E-18 -18.9029 0.67291E-19 -19.1720 0.53816E+00 -0.2691 Charge balance for all species = -.1560E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1013823E-09 -.1906683E-01 -.1918988E+02 0.0000 2 H2O 0.1000000E+01 0.5550597E+02 0.9984818E+06 0.0000 3 Cl- 0.1386985E-03 0.1392549E-03 0.4929722E+01 6.1338 4 SO4-- 0.1889153E-08 -.4589925E-06 -.4402653E-01 11.1394 5 HCO3- 0.4874385E-05 0.1319132E-04 0.8037102E+00 4.6802 6 HS- 0.2573370E-04 0.2620020E-04 0.8652151E+00 5.4023 7 Al+++ 0.2398748E-28 0.7578781E-05 0.2041853E+00 0.9781 8 H4SiO4 0.6630339E-03 0.1132765E-01 0.1087156E+04 -3.1785 9 Ca++ 0.1063775E-06 0.1761946E-06 0.7051112E-02 12.8872 10 Mg++ 0.2325225E-10 0.9324012E-10 0.2263510E-05 9.2250 11 Fe++ 0.7221900E-13 0.3179177E-07 0.1772856E-02 6.7176 12 K+ 0.1358705E-03 0.1364527E-03 0.5327704E+01 6.1255 13 Na+ 0.1726964E-01 0.1908512E-01 0.4381160E+03 8.2289 14 Mn++ 0.1834746E-10 0.1991992E-08 0.1092746E-03 9.1229 15 HPO4-- 0.8409732E-07 0.8593009E-07 0.8235320E-02 12.7880 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1291535E+01 -.1889147E-01 -.1272643E+01 0.0000000E+00 2 H2O 0.5453050E+02 0.5499548E+02 -.4649831E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2187123E-02 -.4547712E-06 0.2187577E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2161618E-02 0.2595924E-04 -.2187577E-02 0.0000000E+00 7 Al+++ 0.2543346E+00 0.7509080E-05 0.2543271E+00 0.0000000E+00 8 H4SiO4 0.8121867E+00 0.1122347E-01 0.8009632E+00 0.0000000E+00 9 Ca++ 0.8972445E-01 0.1745741E-06 0.8972427E-01 0.0000000E+00 10 Mg++ 0.6190397E-01 0.9238260E-10 0.6190397E-01 0.0000000E+00 11 Fe++ 0.5561396E-01 0.3149938E-07 0.5561393E-01 0.0000000E+00 12 K+ 0.1656030E-01 0.1351978E-03 0.1642510E-01 0.0000000E+00 13 Na+ 0.9806782E-01 0.1890960E-01 0.7915822E-01 0.0000000E+00 14 Mn++ 0.1352393E-02 0.1973671E-08 0.1352391E-02 0.0000000E+00 15 HPO4-- 0.4615651E-03 0.8513980E-07 0.4614799E-03 0.0000000E+00 Chg. balance for solid moles: -.1583E-16 Mass of aqueous solution: 0.992267E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 77.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.7916E-01 -1.102 20.76 1.317 24.39 7.968 andradite 0.8750E-02 -2.058 4.447 0.648 5.225 1.155 grossular 0.1354E-02 -2.868 0.6098 -0.215 0.7165 0.1697 apatite-OH 0.1538E-03 -3.813 0.7727E-01 -1.112 0.9079E-01 0.2455E-01 clinochlore 0.1238E-01 -1.907 6.882 0.838 8.085 2.618 daphnite 0.4028E-02 -2.395 2.874 0.459 3.377 0.8710 chlorite-Mn 0.2705E-03 -3.568 0.1918 -0.717 0.2253 0.6111E-01 microcline 0.1463E-01 -1.835 4.072 0.610 4.784 1.590 stilbite 0.5864E-01 -1.232 41.33 1.616 48.56 19.28 stilpnomelane-Fe 0.3594E-02 -2.444 3.875 0.588 4.552 1.338 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8660E+00 0.8660E+00 1.0000 -0.062 grossular 0.1340E+00 0.1340E+00 1.0000 -0.873 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7423E+00 0.7423E+00 1.0000 -0.129 daphnite 0.2415E+00 0.2415E+00 1.0000 -0.617 chlorite-Mn 0.1622E-01 0.1622E-01 1.0000 -1.790 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 85.111197 g Volume = 35.071631 cm3 Porosity: -8.9195% V(tot) - V(min): -.28720E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 77.9990000 g log = 1.8921 Original solution: 1000.0103000 g Original solution / Rock added: 12.82 (Water/Rock Ratio), log = 1.1079 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0541 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9979E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.7690E-07 1.0073 0.8165E-07 0.8106E-07 CH4,gas 0.1275E-03 1.0129 0.1361E-03 0.1344E-03 H2,gas 0.1943E-02 1.0006 0.2050E-02 0.2048E-02 H2S,gas 0.1557E-06 0.9959 0.1635E-06 0.1642E-06 S2,gas 0.2261E-27 1.0000 0.2383E-27 0.2383E-27 CO,gas 0.4112E-13 1.0000 0.4335E-13 0.4335E-13 SO3,gas 0.2669E-44 1.0000 0.2814E-44 0.2814E-44 SO2,gas 0.2069E-24 1.0000 0.2181E-24 0.2181E-24 HCl,gas 0.3168E-17 1.0000 0.3339E-17 0.3339E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.45 -9.09 -3.029 0.15518E+05 -7.088 3 CH4,gas 4.81 -1.06 -5.87 -1.467 0.10016E+05 -3.866 4 H2,gas 8.29 3.60 -4.69 -2.679 0.80052E+04 -2.688 5 H2S,gas -5.94 -14.73 -8.79 -4.393 0.15003E+05 -6.787 6 S2,gas -7.03 -36.66 -29.62 -4.557 0.50580E+05 -27.623 7 CO,gas 3.51 -11.85 -15.36 -4.727 0.26232E+05 -13.363 8 SO3,gas 17.43 -29.12 -46.55 -11.638 0.79484E+05 -44.551 9 SO2,gas 1.14 -25.52 -26.66 -7.110 0.45523E+05 -24.661 10 HCl,gas 5.48 -14.00 -19.48 -9.738 0.33255E+05 -17.476 11 acmite 7.74 6.79 -0.95 -0.098 0.16171E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.79 -4.76 -0.238 0.81284E+04 20 analcite 3.37 2.85 -0.52 -0.058 0.88880E+03 26 annite 20.21 17.72 -2.49 -0.138 0.42486E+04 27 phlogopite 27.15 25.24 -1.90 -0.106 0.32499E+04 29 anorthite 12.80 8.49 -4.31 -0.332 0.73613E+04 35 aragonite 0.99 -2.56 -3.55 -1.183 0.60620E+04 36 brucite 12.58 9.23 -3.35 -0.670 0.57227E+04 37 calcite 0.83 -2.56 -3.40 -1.132 0.58007E+04 38 carnegieite-low 9.06 6.03 -3.04 -0.434 0.51839E+04 39 carnegieite-high 10.13 6.03 -4.11 -0.587 0.70107E+04 40 carpholite-Mg 8.65 4.82 -3.83 -0.255 0.65329E+04 41 carpholite-Fe 6.78 2.32 -4.47 -0.298 0.76255E+04 42 celadonite 5.40 3.61 -1.79 -0.105 0.30491E+04 43 celadonite-Fe 3.94 1.11 -2.83 -0.166 0.48314E+04 44 chrysotile 23.94 21.32 -2.62 -0.218 0.44723E+04 49 chlorite-Al-free 47.26 42.64 -4.63 -0.193 0.78979E+04 51 chloritoid-Fe 9.24 5.50 -3.74 -0.250 0.63916E+04 52 chloritoid-Mn 11.46 7.90 -3.56 -0.238 0.60830E+04 54 coesite -2.37 -3.18 -0.81 -0.270 0.13815E+04 61 cristobalite -2.55 -3.18 -0.63 -0.210 0.10744E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.98 -1.92 -0.320 0.32749E+04 67 diopside 16.22 15.76 -0.46 -0.046 0.78582E+03 68 hedenbergite 14.24 13.25 -1.00 -0.100 0.17016E+04 75 epidote 24.78 23.11 -1.66 -0.081 0.28373E+04 76 clinozoisite 22.92 19.17 -3.75 -0.170 0.63994E+04 77 epidote-Fe 29.94 27.05 -2.88 -0.150 0.49227E+04 78 fayalite 14.08 10.26 -3.82 -0.546 0.65263E+04 79 ferrosilite 11.19 7.08 -4.11 -0.411 0.70167E+04 83 gibbsite 4.10 0.98 -3.12 -0.446 0.53261E+04 84 glaucophane 23.11 20.66 -2.45 -0.066 0.41819E+04 85 glaucophane-Fe 17.42 13.14 -4.28 -0.116 0.73045E+04 86 graphite -3.55 -8.25 -4.71 -1.344 0.80342E+04 87 greenalite 16.19 13.80 -2.40 -0.200 0.40950E+04 90 hematite 12.60 9.84 -2.76 -0.335 0.47142E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.85 -1.40 -0.140 0.23918E+04 96 julgoldite 70.57 65.59 -4.99 -0.130 0.85141E+04 97 kalsilite 7.62 3.93 -3.70 -0.528 0.63093E+04 98 kaolinite -1.27 -4.40 -3.13 -0.284 0.53402E+04 101 laumontite 2.97 2.13 -0.85 -0.056 0.14428E+04 102 lawsonite 9.68 8.49 -1.19 -0.079 0.20352E+04 103 leucite 4.17 0.75 -3.42 -0.342 0.58412E+04 105 lizardite 23.29 21.32 -1.97 -0.164 0.33626E+04 107 magnetite 20.13 16.55 -3.58 -0.292 0.61102E+04 108 minnesotaite 10.46 7.44 -3.02 -0.178 0.51595E+04 112 manganosite 14.07 9.12 -4.95 -1.236 0.84436E+04 120 muscovite 2.68 -0.48 -3.15 -0.186 0.53867E+04 121 paragonite 4.34 1.63 -2.71 -0.159 0.46251E+04 122 nepheline 8.38 6.03 -2.35 -0.336 0.40118E+04 128 periclase-Fe 11.64 6.72 -4.92 -1.230 0.84034E+04 134 phlogopite-Na 29.73 27.35 -2.38 -0.132 0.40718E+04 136 prehnite 19.47 18.20 -1.27 -0.075 0.21705E+04 137 prehnite-Fe 22.59 22.14 -0.45 -0.027 0.77070E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40715E+04 139 pumpellyite-Mg 49.19 46.59 -2.60 -0.058 0.44404E+04 143 pyrrhotite -4.24 -8.01 -3.77 -1.256 0.64337E+04 144 pyrrhotiteFe0.875 -6.00 -9.30 -3.30 -1.212 0.56286E+04 145 pyroxmangite 7.42 5.94 -1.47 -0.294 0.25128E+04 146 pyrophyllite -6.10 -10.76 -4.66 -0.291 0.79561E+04 147 quartz -2.98 -3.18 -0.20 -0.065 0.33546E+03 152 rhodonite 7.46 5.94 -1.52 -0.304 0.25920E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.72 -1.88 -0.056 0.32100E+04 171 talc 16.55 14.96 -1.59 -0.094 0.27186E+04 174 tephroite 18.11 15.07 -3.05 -0.435 0.52003E+04 178 tridymite -2.61 -3.18 -0.56 -0.188 0.96275E+03 179 tremolite 48.00 46.47 -1.53 -0.041 0.26150E+04 180 ferroactinolite 38.60 33.93 -4.66 -0.126 0.79598E+04 181 troilite-low -4.39 -8.01 -3.62 -1.206 0.61769E+04 187 wairakite 4.06 2.13 -1.93 -0.113 0.32936E+04 188 walstromite 11.53 9.71 -1.82 -0.364 0.31062E+04 189 wollastonite 10.48 9.71 -0.77 -0.155 0.13201E+04 190 pseudo-wollastonite 11.02 9.71 -1.31 -0.262 0.22387E+04 191 zoisite 22.96 19.17 -3.79 -0.172 0.64719E+04 192 akaganeite 7.77 4.92 -2.85 -0.616 0.48653E+04 199 chalcedony -2.79 -3.18 -0.38 -0.128 0.65578E+03 201 montmorillonite-Ca -2.21 -5.91 -3.70 -0.229 0.63104E+04 202 montmorillonite-K -2.16 -6.01 -3.85 -0.236 0.65802E+04 203 montmorillonite-Mg -2.40 -6.51 -4.11 -0.254 0.70218E+04 204 montmorillonite-Na -1.96 -5.32 -3.36 -0.206 0.57371E+04 205 nontronite-Ca 3.28 0.62 -2.66 -0.172 0.45398E+04 206 nontronite-H 2.60 -1.51 -4.10 -0.275 0.70028E+04 207 nontronite-K 3.40 0.52 -2.89 -0.185 0.49310E+04 208 nontronite-Mg 3.14 0.02 -3.12 -0.203 0.53318E+04 209 nontronite-Na 3.58 1.21 -2.37 -0.152 0.40515E+04 224 tobermorite 9.84 7.56 -2.28 -0.623 0.38972E+04 230 alabandite -0.96 -5.61 -4.64 -1.548 0.79293E+04 233 boehmite 4.43 0.98 -3.45 -0.575 0.58933E+04 235 ferrous-oxide 9.82 6.72 -3.11 -0.777 0.53044E+04 240 silica-amorphous -2.08 -3.18 -1.10 -0.366 0.18760E+04 242 an20ab80 2.08 1.43 -0.64 -0.050 0.11006E+04 243 an25ab75 2.71 1.88 -0.83 -0.064 0.14237E+04 244 an30ab70 3.34 2.32 -1.03 -0.079 0.17551E+04 245 tr.625ac.25prg.125 45.31 44.37 -0.93 -0.025 0.15944E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 77.9990000 g New total amount of reactant added: 79.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1490E-12 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 9 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 79.9990000 Water: Moles liquid = 0.5499E+02 kg liquid = 0.9906E+00 Moles total = 0.5451E+02 kg total = 0.9819E+00 Activity = 1.0000 Stoichiometric ionic strength = .9894118E-02 Osmotic coef. = 0.9638 True ionic strength = .1767785E-01 Chg. balance for total moles = -.1490E-12 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10046E-09 -9.9980 0.85101E-10 -10.0701 0.84710E+00 -0.0721 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13872E-03 -3.8579 0.11687E-03 -3.9323 0.84250E+00 -0.0744 4 SO4-- 0.10097E-08 -8.9958 0.54237E-09 -9.2657 0.53716E+00 -0.2699 5 HCO3- 0.48092E-05 -5.3179 0.40570E-05 -5.3918 0.84361E+00 -0.0739 6 HS- 0.25740E-04 -4.5894 0.21689E-04 -4.6638 0.84261E+00 -0.0744 7 Al+++ 0.22366E-28 -28.6504 0.55827E-29 -29.2532 0.24961E+00 -0.6027 8 H4SiO4 0.66846E-03 -3.1749 0.66846E-03 -3.1749 0.10000E+01 0.0000 9 Ca++ 0.10894E-06 -6.9628 0.58132E-07 -7.2356 0.53361E+00 -0.2728 10 Mg++ 0.23292E-10 -10.6328 0.12378E-10 -10.9074 0.53141E+00 -0.2746 11 Fe++ 0.71343E-13 -13.1466 0.37950E-13 -13.4208 0.53193E+00 -0.2741 12 K+ 0.13793E-03 -3.8604 0.11638E-03 -3.9341 0.84379E+00 -0.0738 13 Na+ 0.17531E-01 -1.7562 0.14768E-01 -1.8307 0.84236E+00 -0.0745 14 Mn++ 0.18378E-10 -10.7357 0.97833E-11 -11.0095 0.53233E+00 -0.2738 15 HPO4-- 0.80564E-07 -7.0939 0.43281E-07 -7.3637 0.53723E+00 -0.2698 16 HSiO3- 0.90964E-02 -2.0411 0.76637E-02 -2.1156 0.84250E+00 -0.0744 17 Ca(HSiO3)+ 0.11827E-07 -7.9271 0.99817E-08 -8.0008 0.84395E+00 -0.0737 18 Mg(HSiO3)+ 0.31341E-11 -11.5039 0.26450E-11 -11.5776 0.84395E+00 -0.0737 19 NaHSiO3,aq 0.17975E-02 -2.7453 0.17975E-02 -2.7453 0.10000E+01 0.0000 20 AlO+ 0.11792E-15 -15.9284 0.99515E-16 -16.0021 0.84395E+00 -0.0737 22 HAlO2,aq 0.23400E-09 -9.6308 0.23400E-09 -9.6308 0.10000E+01 0.0000 23 AlO2- 0.72995E-05 -5.1367 0.61398E-05 -5.2118 0.84113E+00 -0.0751 24 CH4,aq 0.15968E-06 -6.7967 0.15920E-06 -6.7981 0.99698E+00 -0.0013 25 C2H6,aq 0.25004E-17 -17.6020 0.24929E-17 -17.6033 0.99698E+00 -0.0013 29 CO,aq 0.31435E-16 -16.5026 0.31435E-16 -16.5026 0.10000E+01 0.0000 30 CO2,aq 0.69822E-09 -9.1560 0.69611E-09 -9.1573 0.99698E+00 -0.0013 31 CO3-2 0.82216E-05 -5.0850 0.44078E-05 -5.3558 0.53613E+00 -0.2707 32 CaCO3,aq 0.31383E-08 -8.5033 0.31383E-08 -8.5033 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.70414E-11 -11.1523 0.59426E-11 -11.2260 0.84395E+00 -0.0737 34 CaCl+ 0.12828E-10 -10.8918 0.10826E-10 -10.9655 0.84395E+00 -0.0737 35 CaCl2,aq 0.29461E-15 -15.5308 0.29461E-15 -15.5308 0.10000E+01 0.0000 36 CaOH+ 0.57073E-07 -7.2436 0.48167E-07 -7.3173 0.84395E+00 -0.0737 37 CaSO4,aq 0.98237E-14 -14.0077 0.98237E-14 -14.0077 0.10000E+01 0.0000 38 HCl,aq 0.18708E-14 -14.7280 0.18708E-14 -14.7280 0.10000E+01 0.0000 43 FeCl+ 0.81854E-17 -17.0870 0.69081E-17 -17.1606 0.84395E+00 -0.0737 46 FeO,aq 0.20722E-09 -9.6836 0.20722E-09 -9.6836 0.10000E+01 0.0000 47 FeOH+ 0.17518E-10 -10.7565 0.14784E-10 -10.8302 0.84395E+00 -0.0737 48 HFeO2- 0.31086E-07 -7.5074 0.26190E-07 -7.5819 0.84250E+00 -0.0744 49 FeO+ 0.32194E-16 -16.4922 0.27170E-16 -16.5659 0.84395E+00 -0.0737 51 FeO2- 0.87519E-09 -9.0579 0.73735E-09 -9.1323 0.84250E+00 -0.0744 52 HFeO2,aq 0.78531E-11 -11.1050 0.78531E-11 -11.1050 0.10000E+01 0.0000 53 H2,aq 0.17587E-05 -5.7548 0.17533E-05 -5.7561 0.99698E+00 -0.0013 54 KCl,aq 0.24084E-09 -9.6183 0.24084E-09 -9.6183 0.10000E+01 0.0000 56 KOH,aq 0.59618E-06 -6.2246 0.59618E-06 -6.2246 0.10000E+01 0.0000 57 KSO4- 0.11543E-11 -11.9377 0.97246E-12 -12.0121 0.84250E+00 -0.0744 58 MgCO3,aq 0.16697E-12 -12.7774 0.16697E-12 -12.7774 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15288E-14 -14.8156 0.12903E-14 -14.8893 0.84395E+00 -0.0737 60 MgCl+ 0.24796E-14 -14.6056 0.20927E-14 -14.6793 0.84395E+00 -0.0737 61 MgOH+ 0.67323E-10 -10.1718 0.56817E-10 -10.2455 0.84395E+00 -0.0737 63 MnO,aq 0.14260E-08 -8.8459 0.14260E-08 -8.8459 0.10000E+01 0.0000 64 MnOH+ 0.41952E-09 -9.3772 0.35405E-09 -9.4509 0.84395E+00 -0.0737 65 MnO2-2 0.12702E-10 -10.8961 0.68098E-11 -11.1669 0.53613E+00 -0.2707 66 HMnO2- 0.14903E-09 -9.8267 0.12556E-09 -9.9011 0.84250E+00 -0.0744 69 MnCl+ 0.81998E-14 -14.0862 0.69202E-14 -14.1599 0.84395E+00 -0.0737 70 MnSO4,aq 0.15038E-17 -17.8228 0.15038E-17 -17.8228 0.10000E+01 0.0000 71 NaCl,aq 0.56357E-06 -6.2491 0.56357E-06 -6.2491 0.10000E+01 0.0000 72 NaOH,aq 0.76251E-04 -4.1178 0.76251E-04 -4.1178 0.10000E+01 0.0000 74 OH- 0.83798E-02 -2.0768 0.70485E-02 -2.1519 0.84113E+00 -0.0751 79 HPO3-2 0.44708E-15 -15.3496 0.23969E-15 -15.6203 0.53613E+00 -0.2707 81 H2PO3- 0.47559E-19 -19.3228 0.40068E-19 -19.3972 0.84250E+00 -0.0744 82 H3PO4,aq 0.20180E-17 -17.6951 0.20180E-17 -17.6951 0.10000E+01 0.0000 83 H2PO4- 0.76582E-10 -10.1159 0.64575E-10 -10.1899 0.84322E+00 -0.0741 84 PO4-3 0.17024E-08 -8.7689 0.44415E-09 -9.3525 0.26090E+00 -0.5835 88 HP2O7-3 0.31476E-17 -17.5020 0.78637E-18 -18.1044 0.24983E+00 -0.6024 89 P2O7-4 0.25841E-16 -16.5877 0.22796E-17 -17.6421 0.88217E-01 -1.0544 90 H2S,aq 0.55625E-08 -8.2547 0.55457E-08 -8.2560 0.99698E+00 -0.0013 91 S2-2 0.11006E-13 -13.9584 0.59008E-14 -14.2291 0.53613E+00 -0.2707 97 SO3-2 0.23874E-15 -15.6221 0.12966E-15 -15.8872 0.54312E+00 -0.2651 98 HSO3- 0.76647E-18 -18.1155 0.64575E-18 -18.1899 0.84250E+00 -0.0744 99 HSO4- 0.50701E-16 -16.2950 0.42826E-16 -16.3683 0.84469E+00 -0.0733 101 S2O3-2 0.66120E-19 -19.1797 0.35449E-19 -19.4504 0.53613E+00 -0.2707 Charge balance for all species = -.1587E-12 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1004621E-09 -.1938859E-01 -.1951318E+02 0.0000 2 H2O 0.1000000E+01 0.5550583E+02 0.9984522E+06 0.0000 3 Cl- 0.1387224E-03 0.1392862E-03 0.4930696E+01 6.1378 4 SO4-- 0.1009695E-08 -.5982284E-06 -.5738046E-01 10.8744 5 HCO3- 0.4809161E-05 0.1319428E-04 0.8038690E+00 4.6783 6 HS- 0.2574042E-04 0.2634522E-04 0.8699804E+00 5.4063 7 Al+++ 0.2236584E-28 0.7299694E-05 0.1966608E+00 0.9570 8 H4SiO4 0.6684563E-03 0.1156239E-01 0.1109655E+04 -3.1749 9 Ca++ 0.1089415E-06 0.1810002E-06 0.7243232E-02 12.9045 10 Mg++ 0.2329182E-10 0.9391993E-10 0.2279952E-05 9.2328 11 Fe++ 0.7134316E-13 0.3219430E-07 0.1795255E-02 6.7193 12 K+ 0.1379257E-03 0.1385221E-03 0.5408355E+01 6.1359 13 Na+ 0.1753122E-01 0.1940553E-01 0.4454592E+03 8.2394 14 Mn++ 0.1837830E-10 0.2025686E-08 0.1111200E-03 9.1306 15 HPO4-- 0.8056355E-07 0.8234251E-07 0.7891281E-02 12.7764 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1324652E+01 -.1920596E-01 -.1305446E+01 0.0000000E+00 2 H2O 0.5450543E+02 0.5498300E+02 -.4775660E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2242549E-02 -.5925934E-06 0.2243142E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2217045E-02 0.2609706E-04 -.2243142E-02 0.0000000E+00 7 Al+++ 0.2608561E+00 0.7230935E-05 0.2608488E+00 0.0000000E+00 8 H4SiO4 0.8330122E+00 0.1145348E-01 0.8215587E+00 0.0000000E+00 9 Ca++ 0.9202473E-01 0.1792953E-06 0.9202455E-01 0.0000000E+00 10 Mg++ 0.6349127E-01 0.9303526E-10 0.6349127E-01 0.0000000E+00 11 Fe++ 0.5703997E-01 0.3189105E-07 0.5703994E-01 0.0000000E+00 12 K+ 0.1698493E-01 0.1372173E-03 0.1684771E-01 0.0000000E+00 13 Na+ 0.1005783E+00 0.1922274E-01 0.8135556E-01 0.0000000E+00 14 Mn++ 0.1387070E-02 0.2006605E-08 0.1387068E-02 0.0000000E+00 15 HPO4-- 0.4734002E-03 0.8156689E-07 0.4733186E-03 0.0000000E+00 Chg. balance for solid moles: -.5974E-16 Mass of aqueous solution: 0.992071E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 79.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8136E-01 -1.090 21.33 1.329 24.44 8.189 andradite 0.8973E-02 -2.047 4.560 0.659 5.224 1.185 grossular 0.1427E-02 -2.846 0.6427 -0.192 0.7363 0.1788 apatite-OH 0.1578E-03 -3.802 0.7925E-01 -1.101 0.9079E-01 0.2518E-01 clinochlore 0.1270E-01 -1.896 7.058 0.849 8.086 2.685 daphnite 0.4075E-02 -2.390 2.907 0.463 3.331 0.8810 chlorite-Mn 0.2774E-03 -3.557 0.1967 -0.706 0.2253 0.6268E-01 microcline 0.1498E-01 -1.825 4.168 0.620 4.775 1.628 stilbite 0.6004E-01 -1.222 42.31 1.626 48.47 19.73 stilpnomelane-Fe 0.3744E-02 -2.427 4.036 0.606 4.624 1.394 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8628E+00 0.8628E+00 1.0000 -0.064 grossular 0.1372E+00 0.1372E+00 1.0000 -0.863 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7448E+00 0.7448E+00 1.0000 -0.128 daphnite 0.2390E+00 0.2390E+00 1.0000 -0.622 chlorite-Mn 0.1627E-01 0.1627E-01 1.0000 -1.789 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 87.290926 g Volume = 35.962711 cm3 Porosity: -8.9792% V(tot) - V(min): -.29631E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 79.9990000 g log = 1.9031 Original solution: 1000.0103000 g Original solution / Rock added: 12.50 (Water/Rock Ratio), log = 1.0969 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0546 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9975E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.7500E-07 1.0073 0.7968E-07 0.7910E-07 CH4,gas 0.2357E-03 1.0129 0.2518E-03 0.2485E-03 H2,gas 0.2279E-02 1.0006 0.2405E-02 0.2403E-02 H2S,gas 0.1540E-06 0.9959 0.1617E-06 0.1624E-06 S2,gas 0.1607E-27 1.0000 0.1694E-27 0.1694E-27 CO,gas 0.4707E-13 1.0000 0.4964E-13 0.4964E-13 SO3,gas 0.1392E-44 1.0000 0.1468E-44 0.1468E-44 SO2,gas 0.1267E-24 1.0000 0.1336E-24 0.1336E-24 HCl,gas 0.3132E-17 1.0000 0.3303E-17 0.3303E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.46 -9.10 -3.033 0.15536E+05 -7.099 3 CH4,gas 4.81 -0.79 -5.60 -1.400 0.95602E+04 -3.599 4 H2,gas 8.29 3.67 -4.62 -2.639 0.78867E+04 -2.619 5 H2S,gas -5.94 -14.73 -8.79 -4.396 0.15011E+05 -6.791 6 S2,gas -7.03 -36.80 -29.77 -4.580 0.50833E+05 -27.771 7 CO,gas 3.51 -11.79 -15.30 -4.709 0.26132E+05 -13.304 8 SO3,gas 17.43 -29.41 -46.83 -11.708 0.79966E+05 -44.833 9 SO2,gas 1.14 -25.74 -26.87 -7.166 0.45887E+05 -24.874 10 HCl,gas 5.48 -14.00 -19.48 -9.741 0.33263E+05 -17.481 11 acmite 7.74 6.77 -0.96 -0.100 0.16435E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.78 -4.77 -0.238 0.81425E+04 20 analcite 3.37 2.85 -0.52 -0.058 0.89484E+03 26 annite 20.21 17.73 -2.48 -0.138 0.42398E+04 27 phlogopite 27.15 25.27 -1.88 -0.104 0.32102E+04 29 anorthite 12.80 8.47 -4.33 -0.333 0.73915E+04 35 aragonite 0.99 -2.56 -3.54 -1.181 0.60505E+04 36 brucite 12.58 9.23 -3.34 -0.669 0.57095E+04 37 calcite 0.83 -2.56 -3.39 -1.130 0.57891E+04 38 carnegieite-low 9.06 6.02 -3.04 -0.435 0.51959E+04 39 carnegieite-high 10.13 6.02 -4.11 -0.588 0.70228E+04 40 carpholite-Mg 8.65 4.80 -3.85 -0.257 0.65795E+04 41 carpholite-Fe 6.78 2.28 -4.50 -0.300 0.76825E+04 42 celadonite 5.40 3.63 -1.77 -0.104 0.30298E+04 43 celadonite-Fe 3.94 1.11 -2.82 -0.166 0.48224E+04 44 chrysotile 23.94 21.35 -2.59 -0.216 0.44205E+04 49 chlorite-Al-free 47.26 42.70 -4.56 -0.190 0.77943E+04 51 chloritoid-Fe 9.24 5.46 -3.78 -0.252 0.64545E+04 52 chloritoid-Mn 11.46 7.87 -3.59 -0.240 0.61357E+04 54 coesite -2.37 -3.17 -0.81 -0.269 0.13755E+04 61 cristobalite -2.55 -3.17 -0.63 -0.209 0.10684E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.96 -1.94 -0.323 0.33109E+04 67 diopside 16.22 15.79 -0.43 -0.043 0.73082E+03 68 hedenbergite 14.24 13.27 -0.97 -0.097 0.16569E+04 75 epidote 24.78 23.08 -1.69 -0.082 0.28881E+04 76 clinozoisite 22.92 19.16 -3.77 -0.171 0.64298E+04 77 epidote-Fe 29.94 27.01 -2.92 -0.152 0.49939E+04 78 fayalite 14.08 10.26 -3.82 -0.545 0.65143E+04 79 ferrosilite 11.19 7.09 -4.10 -0.410 0.69987E+04 83 gibbsite 4.10 0.96 -3.14 -0.449 0.53621E+04 84 glaucophane 23.11 20.69 -2.42 -0.065 0.41301E+04 85 glaucophane-Fe 17.42 13.15 -4.27 -0.115 0.72836E+04 86 graphite -3.55 -8.13 -4.58 -1.308 0.78152E+04 87 greenalite 16.19 13.81 -2.39 -0.199 0.40741E+04 90 hematite 12.60 9.77 -2.83 -0.343 0.48269E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.85 -1.40 -0.140 0.23979E+04 97 kalsilite 7.62 3.92 -3.70 -0.529 0.63214E+04 98 kaolinite -1.27 -4.44 -3.16 -0.288 0.54001E+04 101 laumontite 2.97 2.12 -0.86 -0.057 0.14609E+04 102 lawsonite 9.68 8.47 -1.21 -0.081 0.20654E+04 103 leucite 4.17 0.74 -3.42 -0.342 0.58472E+04 105 lizardite 23.29 21.35 -1.94 -0.162 0.33108E+04 107 magnetite 20.13 16.49 -3.64 -0.297 0.62199E+04 108 minnesotaite 10.46 7.46 -3.00 -0.177 0.51265E+04 112 manganosite 14.07 9.13 -4.94 -1.234 0.84304E+04 120 muscovite 2.68 -0.52 -3.20 -0.188 0.54586E+04 121 paragonite 4.34 1.59 -2.75 -0.162 0.46971E+04 122 nepheline 8.38 6.02 -2.36 -0.337 0.40239E+04 128 periclase-Fe 11.64 6.72 -4.92 -1.230 0.84004E+04 134 phlogopite-Na 29.73 27.37 -2.36 -0.131 0.40321E+04 136 prehnite 19.47 18.20 -1.27 -0.075 0.21650E+04 137 prehnite-Fe 22.59 22.13 -0.46 -0.028 0.78554E+03 138 pumpellyite-Fe 46.47 44.07 -2.40 -0.053 0.40935E+04 139 pumpellyite-Mg 49.19 46.59 -2.61 -0.058 0.44521E+04 143 pyrrhotite -4.24 -8.01 -3.77 -1.257 0.64387E+04 144 pyrrhotiteFe0.875 -6.00 -9.31 -3.31 -1.217 0.56487E+04 145 pyroxmangite 7.42 5.96 -1.46 -0.292 0.24935E+04 146 pyrophyllite -6.10 -10.79 -4.69 -0.293 0.80039E+04 147 quartz -2.98 -3.17 -0.19 -0.064 0.32942E+03 152 rhodonite 7.46 5.96 -1.51 -0.301 0.25727E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.75 -1.85 -0.055 0.31585E+04 171 talc 16.55 15.00 -1.55 -0.091 0.26548E+04 174 tephroite 18.11 15.09 -3.03 -0.432 0.51678E+04 178 tridymite -2.61 -3.17 -0.56 -0.187 0.95671E+03 179 tremolite 48.00 46.57 -1.43 -0.039 0.24411E+04 180 ferroactinolite 38.60 34.01 -4.59 -0.124 0.78375E+04 181 troilite-low -4.39 -8.01 -3.62 -1.207 0.61819E+04 187 wairakite 4.06 2.12 -1.94 -0.114 0.33118E+04 188 walstromite 11.53 9.73 -1.80 -0.360 0.30705E+04 189 wollastonite 10.48 9.73 -0.75 -0.150 0.12844E+04 190 pseudo-wollastonite 11.02 9.73 -1.29 -0.258 0.22030E+04 191 zoisite 22.96 19.16 -3.81 -0.173 0.65024E+04 192 akaganeite 7.77 4.89 -2.88 -0.623 0.49216E+04 199 chalcedony -2.79 -3.17 -0.38 -0.127 0.64974E+03 201 montmorillonite-Ca -2.21 -5.93 -3.71 -0.230 0.63370E+04 202 montmorillonite-K -2.16 -6.03 -3.87 -0.237 0.66059E+04 203 montmorillonite-Mg -2.40 -6.53 -4.13 -0.255 0.70512E+04 204 montmorillonite-Na -1.96 -5.34 -3.38 -0.207 0.57627E+04 205 nontronite-Ca 3.28 0.56 -2.72 -0.176 0.46373E+04 206 nontronite-H 2.60 -1.57 -4.16 -0.279 0.71051E+04 207 nontronite-K 3.40 0.46 -2.94 -0.189 0.50275E+04 208 nontronite-Mg 3.14 -0.04 -3.18 -0.206 0.54320E+04 209 nontronite-Na 3.58 1.15 -2.43 -0.156 0.41479E+04 224 tobermorite 9.84 7.57 -2.26 -0.618 0.38665E+04 230 alabandite -0.96 -5.60 -4.64 -1.547 0.79240E+04 233 boehmite 4.43 0.96 -3.47 -0.579 0.59293E+04 235 ferrous-oxide 9.82 6.72 -3.10 -0.776 0.53015E+04 240 silica-amorphous -2.08 -3.17 -1.10 -0.365 0.18699E+04 242 an20ab80 2.08 1.43 -0.65 -0.050 0.11067E+04 243 an25ab75 2.71 1.87 -0.84 -0.064 0.14313E+04 244 an30ab70 3.34 2.31 -1.03 -0.079 0.17642E+04 245 tr.625ac.25prg.125 45.31 44.46 -0.85 -0.023 0.14479E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 2.0000000 g Current total amount of reactant added: 79.9990000 g New total amount of reactant added: 81.9990000 g Mixing fraction reached given limit of 0.8000E+02 TOTMIX = 0.8200E+02 Execution stopped.