File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.13247E+01 0.10046E-09 0.8471 0.00000000E+00 H2O 2 0. 0.54505E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.13872E-03 0.8425 0.00000000E+00 SO4-- 4 -2. 0.22425E-02 0.10097E-08 0.5372 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.48092E-05 0.8436 0.00000000E+00 HS- 6 -1. -0.22170E-02 0.25740E-04 0.8426 0.00000000E+00 Al+++ 7 3. 0.26086E+00 0.22366E-28 0.2496 0.00000000E+00 H4SiO4 8 0. 0.83301E+00 0.66846E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.92025E-01 0.10894E-06 0.5336 0.00000000E+00 Mg++ 10 2. 0.63491E-01 0.23292E-10 0.5314 0.00000000E+00 Fe++ 11 2. 0.57040E-01 0.71343E-13 0.5319 0.00000000E+00 K+ 12 1. 0.16985E-01 0.13793E-03 0.8438 0.00000000E+00 Na+ 13 1. 0.10058E+00 0.17531E-01 0.8424 0.00000000E+00 Mn++ 14 2. 0.13871E-02 0.18378E-10 0.5323 0.00000000E+00 HPO4-- 15 -2. 0.47340E-03 0.80564E-07 0.5372 0.00000000E+00 Chg. balance for total moles = -.7416E-13 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 100.0000 SLIM = 0.200000E+03 TEMP = 100.0000 SINC = 0.4000E+01 TEMPC = 0.0000 TOTMIX = 0.799990E+02 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 32.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0107 MnO2-2 65 -2. 40.4376 Ca(HSiO3)+ 17 1. 7.6603 HMnO2- 66 -1. 29.1018 Mg(HSiO3)+ 18 1. 7.5653 MnO4- 67 -1. 83.3383 NaHSiO3,aq 19 0. 7.8098 MnO4-2 68 -2. 81.3024 AlO+ 20 1. 6.8891 MnCl+ 69 1. -0.7819 AlOH+2 21 2. 3.1893 MnSO4,aq 70 0. -2.4524 HAlO2,aq 22 0. 10.5878 NaCl,aq 71 0. 0.4861 AlO2- 23 -1. 16.2390 NaOH,aq 72 0. 12.3571 CH4,aq 24 0. 6.0082 O2,aq 73 0. 53.5759 C2H6,aq 25 0. 12.3556 OH- 74 -1. 12.2220 C3H8,aq 26 0. 17.3423 HO2- 75 -1. 50.7897 C4H10,aq 27 0. 22.3397 H2O2,aq 76 0. 40.0297 ethanol,aq 28 0. 15.3114 H3PO2,aq 77 0. 24.3310 CO,aq 29 0. 4.7087 H2PO2- 78 -1. 26.5491 CO2,aq 30 0. -6.3045 HPO3-2 79 -2. 11.9246 CO3-2 31 -2. 10.0340 H3PO3,aq 80 0. 3.5932 CaCO3,aq 32 0. 5.9460 H2PO3- 81 -1. 5.6314 Ca(HCO3)+ 33 1. -1.4013 H3PO4,aq 82 0. -9.8087 CaCl+ 34 1. -0.2023 H2PO4- 83 -1. -7.2438 CaCl2,aq 35 0. 0.4306 PO4-3 84 -3. 12.0588 CaOH+ 36 1. 10.1517 H4P2O7,aq 85 0. -17.7539 CaSO4,aq 37 0. -2.4936 H3P2O7- 86 -1. -15.8646 HCl,aq 38 0. 0.7256 H2P2O7-2 87 -2. -13.3812 HClO,aq 39 0. 32.4377 HP2O7-3 88 -3. -6.6931 ClO- 40 -1. 39.6416 P2O7-4 89 -4. 2.9147 HClO2,aq 41 0. 70.2060 H2S,aq 90 0. -6.4778 Fe+3 42 3. 8.3763 S2-2 91 -2. 1.2336 FeCl+ 43 1. -0.1924 S3-2 92 -2. -8.7963 FeCl2,aq 44 0. 4.3160 S3- 93 -1. -16.3178 FeCl+2 45 2. 6.5223 S4-2 94 -2. -18.6473 FeO,aq 46 0. 16.4029 S5-2 95 -2. -28.3223 FeOH+ 47 1. 7.4795 SO2,aq 96 0. -0.1980 HFeO2- 48 -1. 24.3713 SO3-2 97 -2. 10.2895 FeO+ 49 1. 11.3812 HSO3- 98 -1. 2.5222 FeOH+2 50 2. 9.1115 HSO4- 99 -1. -2.9675 FeO2- 51 -1. 24.0877 HSO5- 100 -1. 38.8657 HFeO2,aq 52 0. 15.9903 S2O3-2 101 -2. -4.5491 H2,aq 53 0. 9.4241 HS2O3- 102 -1. -6.8007 KCl,aq 54 0. 1.7519 H2S2O3,aq 103 0. -7.9944 KHSO4,aq 55 0. -0.4275 S2O4-2 104 -2. 10.5639 KOH,aq 56 0. 12.3606 HS2O4- 105 -1. 7.6762 KSO4- 57 -1. -1.1877 H2S2O4,aq 106 0. 6.6566 MgCO3,aq 58 0. 6.5483 S2O5-2 107 -2. 10.0891 Mg(HCO3)+ 59 1. -1.4098 S2O6-2 108 -2. 11.5737 MgCl+ 60 1. -0.1603 S2O8-2 109 -2. 42.1139 MgOH+ 61 1. 9.4082 S3O6-2 110 -2. 3.8101 Mn+3 62 3. 19.1332 S4O6-2 111 -2. -17.8301 MnO,aq 63 0. 17.9765 S5O6-2 112 -2. -14.1051 MnOH+ 64 1. 8.5115 113 0. 10.3157 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.984 0.0000E+00 osumilite(2) 124 20.895 0.0000E+00 CO2,gas 2 -6.363 0.0000E+00 osumilite-Fe 125 14.657 0.0000E+00 CH4,gas 3 4.809 0.0000E+00 pargasite 126 65.279 0.0000E+00 H2,gas 4 8.287 0.0000E+00 periclase 127 16.149 0.0000E+00 H2S,gas 5 -5.943 0.0000E+00 periclase-Fe 128 11.639 0.0000E+00 S2,gas 6 -7.033 0.0000E+00 perovskite-Al 129 12.395 0.0000E+00 CO,gas 7 3.510 0.0000E+00 perovskite-Ca 130 23.818 0.0000E+00 SO3,gas 8 17.427 0.0000E+00 perovskite-Fe 131 21.158 0.0000E+00 SO2,gas 9 1.136 0.0000E+00 perovskite-Mg 132 23.132 0.0000E+00 HCl,gas 10 5.479 0.0000E+00 phase_A 133 80.267 0.0000E+00 acmite 11 7.737 0.0000E+00 phlogopite-Na 134 29.731 0.0000E+00 akermanite 12 36.495 0.0000E+00 piemontite(ordered) 135 33.876 0.0000E+00 akimotoite 13 16.606 0.0000E+00 prehnite 136 19.466 0.0000E+00 akimotoite-Fe 14 13.083 0.0000E+00 prehnite-Fe 137 22.587 0.0000E+00 albite-high 15 0.750 0.0000E+00 pumpellyite-Fe 138 46.471 0.0000E+00 albite 16 -0.328 0.8136E-01 pumpellyite-Mg 139 49.194 0.0000E+00 almandine 17 24.545 0.0000E+00 px-Mg-tschermaks 140 19.687 0.0000E+00 pyrope 18 37.348 0.0000E+00 px-Ca-tschermaks 141 18.679 0.0000E+00 spessartine 19 24.550 0.0000E+00 pyrite 142 -21.225 0.0000E+00 analcite 20 3.371 0.0000E+00 pyrrhotite 143 -4.244 0.0000E+00 andalusite 21 5.062 0.0000E+00 pyrrhotiteFe0.875 144 -6.001 0.0000E+00 andradite 22 39.088 0.8973E-02 pyroxmangite 145 7.416 0.0000E+00 grossular 23 32.828 0.1427E-02 pyrophyllite 146 -6.098 0.0000E+00 anhydrite 24 -5.280 0.0000E+00 quartz 147 -2.982 0.0000E+00 ankerite 25 -2.093 0.0000E+00 rankinite 148 40.765 0.0000E+00 annite 26 20.209 0.0000E+00 ringwoodite-Fe 149 15.486 0.0000E+00 phlogopite 27 27.147 0.0000E+00 ringwoodite-Mg 150 27.602 0.0000E+00 biotite-Mn 28 33.034 0.0000E+00 rhodochrosite 151 -0.959 0.0000E+00 anorthite 29 12.798 0.0000E+00 rhodonite 152 7.462 0.0000E+00 anthophyllite 30 51.988 0.0000E+00 sanidine 153 -1.221 0.0000E+00 anthophyllite-Fe 31 29.455 0.0000E+00 sapphirine(351) 154 79.204 0.0000E+00 apatite-OH 32 -17.989 0.1578E-03 siderite 155 -2.588 0.0000E+00 apatite-OH-zs 33 -12.572 0.0000E+00 sillimanite 156 5.321 0.0000E+00 apatite-Cl-zs 34 -16.504 0.0000E+00 sodalite 157 50.255 0.0000E+00 aragonite 35 0.986 0.0000E+00 spinel 158 20.934 0.0000E+00 brucite 36 12.577 0.0000E+00 spurrite 159 59.566 0.0000E+00 calcite 37 0.833 0.0000E+00 staurolite-Fe 160 74.138 0.0000E+00 carnegieite-low 38 9.065 0.0000E+00 staurolite-Mg 161 90.336 0.0000E+00 carnegieite-high 39 10.134 0.0000E+00 staurolite-Mn 162 84.438 0.0000E+00 carpholite-Mg 40 8.650 0.0000E+00 stilbite 163 -7.406 0.6004E-01 carpholite-Fe 41 6.783 0.0000E+00 stilpnomelane-Fe 164 13.179 0.3744E-02 celadonite 42 5.401 0.0000E+00 stilpnomelane-Mg 165 27.596 0.0000E+00 celadonite-Fe 43 3.937 0.0000E+00 stishovite 166 2.721 0.0000E+00 chrysotile 44 23.937 0.0000E+00 sudoite-Fe 167 18.437 0.0000E+00 chondrodite 45 56.542 0.0000E+00 sudoite 168 21.216 0.0000E+00 clinochlore 46 39.193 0.1270E-01 sulfur 169 -9.141 0.0000E+00 daphnite 47 29.094 0.4075E-02 sylvite 170 1.345 0.0000E+00 chlorite-Mn 48 46.985 0.2774E-03 talc 171 16.553 0.0000E+00 chlorite-Al-free 49 47.262 0.0000E+00 talc-Fe 172 13.516 0.0000E+00 chloritoid-Mg 50 13.261 0.0000E+00 talc-tschermaks 173 19.189 0.0000E+00 chloritoid-Fe 51 9.239 0.0000E+00 tephroite 174 18.113 0.0000E+00 chloritoid-Mn 52 11.463 0.0000E+00 tilleyite 175 41.473 0.0000E+00 clinohumite 53 97.255 0.0000E+00 titanite-CaSi 176 15.497 0.0000E+00 coesite 54 -2.369 0.0000E+00 topaz-H 177 4.668 0.0000E+00 cordierite-H 55 23.898 0.0000E+00 tridymite 178 -2.615 0.0000E+00 cordierite 56 24.245 0.0000E+00 tremolite 179 48.003 0.0000E+00 cordierite-Fe 57 20.649 0.0000E+00 ferroactinolite 180 38.596 0.0000E+00 cordierite-Mn 58 25.261 0.0000E+00 troilite-low 181 -4.394 0.0000E+00 corundum 59 8.433 0.0000E+00 tschermakite 182 48.414 0.0000E+00 corundum-MgSi 60 18.905 0.0000E+00 vesuvianite 183 224.056 0.0000E+00 cristobalite 61 -2.549 0.0000E+00 wadeite-Si 184 20.233 0.0000E+00 cummingtonite 62 52.233 0.0000E+00 wadsleyite-Fe 185 15.711 0.0000E+00 cymrite-K 63 1.731 0.0000E+00 wadsleyite-Mg 186 25.878 0.0000E+00 deerite 64 95.982 0.0000E+00 wairakite 187 4.058 0.0000E+00 diaspore 65 2.896 0.0000E+00 walstromite 188 11.528 0.0000E+00 diamond 66 -3.107 0.0000E+00 wollastonite 189 10.482 0.0000E+00 diopside 67 16.215 0.0000E+00 pseudo-wollastonite 190 11.020 0.0000E+00 hedenbergite 68 14.244 0.0000E+00 zoisite 191 22.964 0.0000E+00 dolomite,ordered 69 0.587 0.0000E+00 akaganeite 192 7.768 0.0000E+00 eastonite 70 28.605 0.0000E+00 beidellite-Ca 193 -1.560 0.0000E+00 enstatite 71 17.301 0.0000E+00 beidellite-H 194 -2.241 0.0000E+00 clinoenstatite-HiP 72 18.388 0.0000E+00 beidellite-K 195 -1.435 0.0000E+00 clinoenstatite 73 17.202 0.0000E+00 beidellite-Mg 196 -1.707 0.0000E+00 protoenstatite 74 17.860 0.0000E+00 beidellite-Na 197 -1.257 0.0000E+00 epidote 75 24.775 0.0000E+00 calcium 198 84.043 0.0000E+00 clinozoisite 76 22.921 0.0000E+00 chalcedony 199 -2.794 0.0000E+00 epidote-Fe 77 29.937 0.0000E+00 dawsonite 200 1.714 0.0000E+00 fayalite 78 14.079 0.0000E+00 montmorillonite-Ca 201 -2.214 0.0000E+00 ferrosilite 79 11.188 0.0000E+00 montmorillonite-K 202 -2.161 0.0000E+00 forsterite 80 21.047 0.0000E+00 montmorillonite-Mg 203 -2.402 0.0000E+00 gedrite 81 50.725 0.0000E+00 montmorillonite-Na 204 -1.961 0.0000E+00 gehlenite 82 36.717 0.0000E+00 nontronite-Ca 205 3.280 0.0000E+00 gibbsite 83 4.097 0.0000E+00 nontronite-H 206 2.596 0.0000E+00 glaucophane 84 23.111 0.0000E+00 nontronite-K 207 3.404 0.0000E+00 glaucophane-Fe 85 17.417 0.0000E+00 nontronite-Mg 208 3.139 0.0000E+00 graphite 86 -3.549 0.0000E+00 nontronite-Na 209 3.583 0.0000E+00 greenalite 87 16.194 0.0000E+00 sepiolite 210 24.194 0.0000E+00 grunerite 88 31.364 0.0000E+00 alite 211 58.043 0.0000E+00 halite 89 1.582 0.0000E+00 belite 212 30.461 0.0000E+00 hematite 90 12.598 0.0000E+00 ettringite 213 43.354 0.0000E+00 heulandite 91 -5.707 0.0000E+00 gypsum 214 -4.924 0.0000E+00 hercynite 92 17.345 0.0000E+00 hemicarboaluminate 215 71.028 0.0000E+00 hollandite 93 25.702 0.0000E+00 hydrogarnet 216 60.721 0.0000E+00 iron 94 19.095 0.0000E+00 hydrogarnet-Si 217 50.654 0.0000E+00 jadeite 95 4.251 0.0000E+00 jennite 218 24.386 0.0000E+00 julgoldite 96 70.573 0.0000E+00 monosulfoaluminate 219 53.497 0.0000E+00 kalsilite 97 7.620 0.0000E+00 monocarboaluminate 220 61.966 0.0000E+00 kaolinite 98 -1.273 0.0000E+00 portlandite 221 18.282 0.0000E+00 kyanite 99 4.932 0.0000E+00 stratlingite 222 36.573 0.0000E+00 larnite-bredigite 100 30.714 0.0000E+00 tricarboaluminate 223 70.427 0.0000E+00 laumontite 101 2.975 0.0000E+00 tobermorite 224 9.839 0.0000E+00 lawsonite 102 9.678 0.0000E+00 C4AH13 225 81.870 0.0000E+00 leucite 103 4.168 0.0000E+00 C2AH8 226 45.260 0.0000E+00 lime 104 26.009 0.0000E+00 C3A 227 87.049 0.0000E+00 lizardite 105 23.287 0.0000E+00 C4AF 228 117.550 0.0000E+00 magnesite 106 0.709 0.0000E+00 CAH10 229 28.373 0.0000E+00 magnetite 107 20.133 0.0000E+00 alabandite 230 -0.962 0.0000E+00 minnesotaite 108 10.461 0.0000E+00 alunite 231 -10.224 0.0000E+00 minnesotaite-Mg 109 20.669 0.0000E+00 artinite 232 15.139 0.0000E+00 magnesioferrite 110 26.257 0.0000E+00 boehmite 233 4.430 0.0000E+00 majorite 111 53.314 0.0000E+00 dolomite,disordered 234 1.288 0.0000E+00 manganosite 112 14.068 0.0000E+00 ferrous-oxide 235 9.824 0.0000E+00 margarite 113 17.452 0.0000E+00 huntite 236 3.850 0.0000E+00 meionite 114 45.158 0.0000E+00 hydromagnesite 237 20.077 0.0000E+00 merwinite 115 55.988 0.0000E+00 nesquehonite 238 4.735 0.0000E+00 microcline 116 -2.432 0.1498E-01 potassium-oxide 239 69.039 0.0000E+00 monticellite 117 24.371 0.0000E+00 silica-amorphous 240 -2.080 0.0000E+00 mullite-Al 118 363.258 0.0000E+00 sodium-oxide 241 55.173 0.0000E+00 mullite-Si 119 7.324 0.0000E+00 an20ab80 242 2.079 0.0000E+00 muscovite 120 2.679 0.0000E+00 an25ab75 243 2.709 0.0000E+00 paragonite 121 4.337 0.0000E+00 an30ab70 244 3.344 0.0000E+00 nepheline 122 8.378 0.0000E+00 tr.625ac.25prg.125 245 45.308 0.0000E+00 osumilite(1) 123 21.978 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 79.9990000 g log = 1.9031 Original solution: 1000.0103000 g Original solution / Rock added: 12.50 (Water/Rock Ratio), log = 1.0969 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 79.9990000 Water: Moles liquid = 0.5499E+02 kg liquid = 0.9906E+00 Moles total = 0.5451E+02 kg total = 0.9819E+00 Activity = 1.0000 Stoichiometric ionic strength = .9894118E-02 Osmotic coef. = 0.9638 True ionic strength = .1767785E-01 Chg. balance for total moles = -.7416E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.10046E-09 -9.9980 0.85101E-10 -10.0701 0.84710E+00 -0.0721 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13872E-03 -3.8579 0.11687E-03 -3.9323 0.84250E+00 -0.0744 4 SO4-- 0.10097E-08 -8.9958 0.54237E-09 -9.2657 0.53716E+00 -0.2699 5 HCO3- 0.48092E-05 -5.3179 0.40570E-05 -5.3918 0.84361E+00 -0.0739 6 HS- 0.25740E-04 -4.5894 0.21689E-04 -4.6638 0.84261E+00 -0.0744 7 Al+++ 0.22366E-28 -28.6504 0.55827E-29 -29.2532 0.24961E+00 -0.6027 8 H4SiO4 0.66846E-03 -3.1749 0.66846E-03 -3.1749 0.10000E+01 0.0000 9 Ca++ 0.10894E-06 -6.9628 0.58132E-07 -7.2356 0.53361E+00 -0.2728 10 Mg++ 0.23292E-10 -10.6328 0.12378E-10 -10.9074 0.53141E+00 -0.2746 11 Fe++ 0.71343E-13 -13.1466 0.37950E-13 -13.4208 0.53193E+00 -0.2741 12 K+ 0.13793E-03 -3.8604 0.11638E-03 -3.9341 0.84379E+00 -0.0738 13 Na+ 0.17531E-01 -1.7562 0.14768E-01 -1.8307 0.84236E+00 -0.0745 14 Mn++ 0.18378E-10 -10.7357 0.97833E-11 -11.0095 0.53233E+00 -0.2738 15 HPO4-- 0.80564E-07 -7.0939 0.43281E-07 -7.3637 0.53723E+00 -0.2698 16 HSiO3- 0.90964E-02 -2.0411 0.76637E-02 -2.1156 0.84250E+00 -0.0744 17 Ca(HSiO3)+ 0.11827E-07 -7.9271 0.99817E-08 -8.0008 0.84395E+00 -0.0737 18 Mg(HSiO3)+ 0.31341E-11 -11.5039 0.26450E-11 -11.5776 0.84395E+00 -0.0737 19 NaHSiO3,aq 0.17975E-02 -2.7453 0.17975E-02 -2.7453 0.10000E+01 0.0000 20 AlO+ 0.11792E-15 -15.9284 0.99515E-16 -16.0021 0.84395E+00 -0.0737 22 HAlO2,aq 0.23400E-09 -9.6308 0.23400E-09 -9.6308 0.10000E+01 0.0000 23 AlO2- 0.72995E-05 -5.1367 0.61398E-05 -5.2118 0.84113E+00 -0.0751 24 CH4,aq 0.15968E-06 -6.7967 0.15920E-06 -6.7981 0.99698E+00 -0.0013 25 C2H6,aq 0.25004E-17 -17.6020 0.24929E-17 -17.6033 0.99698E+00 -0.0013 29 CO,aq 0.31435E-16 -16.5026 0.31435E-16 -16.5026 0.10000E+01 0.0000 30 CO2,aq 0.69822E-09 -9.1560 0.69611E-09 -9.1573 0.99698E+00 -0.0013 31 CO3-2 0.82216E-05 -5.0850 0.44078E-05 -5.3558 0.53613E+00 -0.2707 32 CaCO3,aq 0.31383E-08 -8.5033 0.31383E-08 -8.5033 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.70414E-11 -11.1523 0.59426E-11 -11.2260 0.84395E+00 -0.0737 34 CaCl+ 0.12828E-10 -10.8918 0.10826E-10 -10.9655 0.84395E+00 -0.0737 35 CaCl2,aq 0.29461E-15 -15.5308 0.29461E-15 -15.5308 0.10000E+01 0.0000 36 CaOH+ 0.57073E-07 -7.2436 0.48167E-07 -7.3173 0.84395E+00 -0.0737 37 CaSO4,aq 0.98237E-14 -14.0077 0.98237E-14 -14.0077 0.10000E+01 0.0000 38 HCl,aq 0.18708E-14 -14.7280 0.18708E-14 -14.7280 0.10000E+01 0.0000 43 FeCl+ 0.81854E-17 -17.0870 0.69081E-17 -17.1606 0.84395E+00 -0.0737 46 FeO,aq 0.20722E-09 -9.6836 0.20722E-09 -9.6836 0.10000E+01 0.0000 47 FeOH+ 0.17518E-10 -10.7565 0.14784E-10 -10.8302 0.84395E+00 -0.0737 48 HFeO2- 0.31086E-07 -7.5074 0.26190E-07 -7.5819 0.84250E+00 -0.0744 49 FeO+ 0.32194E-16 -16.4922 0.27170E-16 -16.5659 0.84395E+00 -0.0737 51 FeO2- 0.87519E-09 -9.0579 0.73735E-09 -9.1323 0.84250E+00 -0.0744 52 HFeO2,aq 0.78531E-11 -11.1050 0.78531E-11 -11.1050 0.10000E+01 0.0000 53 H2,aq 0.17587E-05 -5.7548 0.17533E-05 -5.7561 0.99698E+00 -0.0013 54 KCl,aq 0.24084E-09 -9.6183 0.24084E-09 -9.6183 0.10000E+01 0.0000 56 KOH,aq 0.59618E-06 -6.2246 0.59618E-06 -6.2246 0.10000E+01 0.0000 57 KSO4- 0.11543E-11 -11.9377 0.97246E-12 -12.0121 0.84250E+00 -0.0744 58 MgCO3,aq 0.16697E-12 -12.7774 0.16697E-12 -12.7774 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15288E-14 -14.8156 0.12903E-14 -14.8893 0.84395E+00 -0.0737 60 MgCl+ 0.24796E-14 -14.6056 0.20927E-14 -14.6793 0.84395E+00 -0.0737 61 MgOH+ 0.67323E-10 -10.1718 0.56817E-10 -10.2455 0.84395E+00 -0.0737 63 MnO,aq 0.14260E-08 -8.8459 0.14260E-08 -8.8459 0.10000E+01 0.0000 64 MnOH+ 0.41952E-09 -9.3772 0.35405E-09 -9.4509 0.84395E+00 -0.0737 65 MnO2-2 0.12702E-10 -10.8961 0.68098E-11 -11.1669 0.53613E+00 -0.2707 66 HMnO2- 0.14903E-09 -9.8267 0.12556E-09 -9.9011 0.84250E+00 -0.0744 69 MnCl+ 0.81998E-14 -14.0862 0.69202E-14 -14.1599 0.84395E+00 -0.0737 70 MnSO4,aq 0.15038E-17 -17.8228 0.15038E-17 -17.8228 0.10000E+01 0.0000 71 NaCl,aq 0.56357E-06 -6.2491 0.56357E-06 -6.2491 0.10000E+01 0.0000 72 NaOH,aq 0.76251E-04 -4.1178 0.76251E-04 -4.1178 0.10000E+01 0.0000 74 OH- 0.83798E-02 -2.0768 0.70485E-02 -2.1519 0.84113E+00 -0.0751 79 HPO3-2 0.44708E-15 -15.3496 0.23969E-15 -15.6203 0.53613E+00 -0.2707 81 H2PO3- 0.47559E-19 -19.3228 0.40068E-19 -19.3972 0.84250E+00 -0.0744 82 H3PO4,aq 0.20180E-17 -17.6951 0.20180E-17 -17.6951 0.10000E+01 0.0000 83 H2PO4- 0.76582E-10 -10.1159 0.64575E-10 -10.1899 0.84322E+00 -0.0741 84 PO4-3 0.17024E-08 -8.7689 0.44415E-09 -9.3525 0.26090E+00 -0.5835 88 HP2O7-3 0.31476E-17 -17.5020 0.78637E-18 -18.1044 0.24983E+00 -0.6024 89 P2O7-4 0.25841E-16 -16.5877 0.22796E-17 -17.6421 0.88217E-01 -1.0544 90 H2S,aq 0.55625E-08 -8.2547 0.55457E-08 -8.2560 0.99698E+00 -0.0013 91 S2-2 0.11006E-13 -13.9584 0.59008E-14 -14.2291 0.53613E+00 -0.2707 97 SO3-2 0.23874E-15 -15.6221 0.12966E-15 -15.8872 0.54312E+00 -0.2651 98 HSO3- 0.76647E-18 -18.1155 0.64575E-18 -18.1899 0.84250E+00 -0.0744 99 HSO4- 0.50701E-16 -16.2950 0.42826E-16 -16.3683 0.84469E+00 -0.0733 101 S2O3-2 0.66120E-19 -19.1797 0.35449E-19 -19.4504 0.53613E+00 -0.2707 Charge balance for all species = -.7360E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.1004621E-09 -.1938859E-01 -.1951318E+02 0.0000 2 H2O 0.1000000E+01 0.5550583E+02 0.9984522E+06 0.0000 3 Cl- 0.1387224E-03 0.1392862E-03 0.4930696E+01 6.1378 4 SO4-- 0.1009695E-08 -.5982284E-06 -.5738046E-01 10.8744 5 HCO3- 0.4809161E-05 0.1319428E-04 0.8038690E+00 4.6783 6 HS- 0.2574042E-04 0.2634522E-04 0.8699804E+00 5.4063 7 Al+++ 0.2236584E-28 0.7299694E-05 0.1966608E+00 0.9570 8 H4SiO4 0.6684563E-03 0.1156239E-01 0.1109655E+04 -3.1749 9 Ca++ 0.1089415E-06 0.1810002E-06 0.7243232E-02 12.9045 10 Mg++ 0.2329182E-10 0.9391995E-10 0.2279952E-05 9.2328 11 Fe++ 0.7134316E-13 0.3219430E-07 0.1795255E-02 6.7193 12 K+ 0.1379257E-03 0.1385221E-03 0.5408355E+01 6.1359 13 Na+ 0.1753122E-01 0.1940553E-01 0.4454592E+03 8.2394 14 Mn++ 0.1837830E-10 0.2025686E-08 0.1111200E-03 9.1306 15 HPO4-- 0.8056355E-07 0.8234251E-07 0.7891281E-02 12.7764 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1324652E+01 -.1920596E-01 -.1305446E+01 0.0000000E+00 2 H2O 0.5450543E+02 0.5498300E+02 -.4775660E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2242549E-02 -.5925934E-06 0.2243142E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2217045E-02 0.2609706E-04 -.2243142E-02 0.0000000E+00 7 Al+++ 0.2608561E+00 0.7230935E-05 0.2608488E+00 0.0000000E+00 8 H4SiO4 0.8330122E+00 0.1145348E-01 0.8215587E+00 0.0000000E+00 9 Ca++ 0.9202473E-01 0.1792953E-06 0.9202455E-01 0.0000000E+00 10 Mg++ 0.6349127E-01 0.9303527E-10 0.6349127E-01 0.0000000E+00 11 Fe++ 0.5703997E-01 0.3189105E-07 0.5703994E-01 0.0000000E+00 12 K+ 0.1698493E-01 0.1372173E-03 0.1684771E-01 0.0000000E+00 13 Na+ 0.1005783E+00 0.1922274E-01 0.8135556E-01 0.0000000E+00 14 Mn++ 0.1387070E-02 0.2006605E-08 0.1387068E-02 0.0000000E+00 15 HPO4-- 0.4734002E-03 0.8156689E-07 0.4733186E-03 0.0000000E+00 Chg. balance for solid moles: 0.9357E-16 Mass of aqueous solution: 0.992071E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 79.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8136E-01 -1.090 21.33 1.329 24.44 8.189 andradite 0.8973E-02 -2.047 4.560 0.659 5.224 1.185 grossular 0.1427E-02 -2.846 0.6427 -0.192 0.7363 0.1788 apatite-OH 0.1578E-03 -3.802 0.7925E-01 -1.101 0.9079E-01 0.2518E-01 clinochlore 0.1270E-01 -1.896 7.058 0.849 8.086 2.685 daphnite 0.4075E-02 -2.390 2.907 0.463 3.331 0.8810 chlorite-Mn 0.2774E-03 -3.557 0.1967 -0.706 0.2253 0.6268E-01 microcline 0.1498E-01 -1.825 4.168 0.620 4.775 1.628 stilbite 0.6004E-01 -1.222 42.31 1.626 48.47 19.73 stilpnomelane-Fe 0.3744E-02 -2.427 4.036 0.606 4.624 1.394 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8628E+00 0.8628E+00 1.0000 -0.064 grossular 0.1372E+00 0.1372E+00 1.0000 -0.863 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7448E+00 0.7448E+00 1.0000 -0.128 daphnite 0.2390E+00 0.2390E+00 1.0000 -0.622 chlorite-Mn 0.1627E-01 0.1627E-01 1.0000 -1.789 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 87.290926 g Volume = 35.962711 cm3 Porosity: -8.9792% V(tot) - V(min): -.29631E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 79.9990000 g log = 1.9031 Original solution: 1000.0103000 g Original solution / Rock added: 12.50 (Water/Rock Ratio), log = 1.0969 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0546 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9975E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.7500E-07 1.0073 0.7968E-07 0.7910E-07 CH4,gas 0.2357E-03 1.0129 0.2518E-03 0.2485E-03 H2,gas 0.2279E-02 1.0006 0.2405E-02 0.2403E-02 H2S,gas 0.1540E-06 0.9959 0.1617E-06 0.1624E-06 S2,gas 0.1607E-27 1.0000 0.1694E-27 0.1694E-27 CO,gas 0.4707E-13 1.0000 0.4964E-13 0.4964E-13 SO3,gas 0.1392E-44 1.0000 0.1468E-44 0.1468E-44 SO2,gas 0.1267E-24 1.0000 0.1336E-24 0.1336E-24 HCl,gas 0.3132E-17 1.0000 0.3303E-17 0.3303E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 -0.48529E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.46 -9.10 -3.033 0.15536E+05 -7.099 3 CH4,gas 4.81 -0.79 -5.60 -1.400 0.95602E+04 -3.599 4 H2,gas 8.29 3.67 -4.62 -2.639 0.78867E+04 -2.619 5 H2S,gas -5.94 -14.73 -8.79 -4.396 0.15011E+05 -6.791 6 S2,gas -7.03 -36.80 -29.77 -4.580 0.50833E+05 -27.771 7 CO,gas 3.51 -11.79 -15.30 -4.709 0.26132E+05 -13.304 8 SO3,gas 17.43 -29.41 -46.83 -11.708 0.79966E+05 -44.833 9 SO2,gas 1.14 -25.74 -26.87 -7.166 0.45887E+05 -24.874 10 HCl,gas 5.48 -14.00 -19.48 -9.741 0.33263E+05 -17.481 11 acmite 7.74 6.77 -0.96 -0.100 0.16435E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.78 -4.77 -0.238 0.81425E+04 20 analcite 3.37 2.85 -0.52 -0.058 0.89484E+03 26 annite 20.21 17.73 -2.48 -0.138 0.42398E+04 27 phlogopite 27.15 25.27 -1.88 -0.104 0.32102E+04 29 anorthite 12.80 8.47 -4.33 -0.333 0.73915E+04 35 aragonite 0.99 -2.56 -3.54 -1.181 0.60505E+04 36 brucite 12.58 9.23 -3.34 -0.669 0.57095E+04 37 calcite 0.83 -2.56 -3.39 -1.130 0.57891E+04 38 carnegieite-low 9.06 6.02 -3.04 -0.435 0.51959E+04 39 carnegieite-high 10.13 6.02 -4.11 -0.588 0.70228E+04 40 carpholite-Mg 8.65 4.80 -3.85 -0.257 0.65795E+04 41 carpholite-Fe 6.78 2.28 -4.50 -0.300 0.76825E+04 42 celadonite 5.40 3.63 -1.77 -0.104 0.30298E+04 43 celadonite-Fe 3.94 1.11 -2.82 -0.166 0.48224E+04 44 chrysotile 23.94 21.35 -2.59 -0.216 0.44205E+04 49 chlorite-Al-free 47.26 42.70 -4.56 -0.190 0.77943E+04 51 chloritoid-Fe 9.24 5.46 -3.78 -0.252 0.64545E+04 52 chloritoid-Mn 11.46 7.87 -3.59 -0.240 0.61357E+04 54 coesite -2.37 -3.17 -0.81 -0.269 0.13755E+04 61 cristobalite -2.55 -3.17 -0.63 -0.209 0.10684E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.96 -1.94 -0.323 0.33109E+04 67 diopside 16.22 15.79 -0.43 -0.043 0.73082E+03 68 hedenbergite 14.24 13.27 -0.97 -0.097 0.16569E+04 75 epidote 24.78 23.08 -1.69 -0.082 0.28881E+04 76 clinozoisite 22.92 19.16 -3.77 -0.171 0.64298E+04 77 epidote-Fe 29.94 27.01 -2.92 -0.152 0.49939E+04 78 fayalite 14.08 10.26 -3.82 -0.545 0.65143E+04 79 ferrosilite 11.19 7.09 -4.10 -0.410 0.69987E+04 83 gibbsite 4.10 0.96 -3.14 -0.449 0.53621E+04 84 glaucophane 23.11 20.69 -2.42 -0.065 0.41301E+04 85 glaucophane-Fe 17.42 13.15 -4.27 -0.115 0.72836E+04 86 graphite -3.55 -8.13 -4.58 -1.308 0.78152E+04 87 greenalite 16.19 13.81 -2.39 -0.199 0.40741E+04 90 hematite 12.60 9.77 -2.83 -0.343 0.48269E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.85 -1.40 -0.140 0.23979E+04 97 kalsilite 7.62 3.92 -3.70 -0.529 0.63214E+04 98 kaolinite -1.27 -4.44 -3.16 -0.288 0.54001E+04 101 laumontite 2.97 2.12 -0.86 -0.057 0.14609E+04 102 lawsonite 9.68 8.47 -1.21 -0.081 0.20654E+04 103 leucite 4.17 0.74 -3.42 -0.342 0.58472E+04 105 lizardite 23.29 21.35 -1.94 -0.162 0.33108E+04 107 magnetite 20.13 16.49 -3.64 -0.297 0.62199E+04 108 minnesotaite 10.46 7.46 -3.00 -0.177 0.51265E+04 112 manganosite 14.07 9.13 -4.94 -1.234 0.84304E+04 120 muscovite 2.68 -0.52 -3.20 -0.188 0.54586E+04 121 paragonite 4.34 1.59 -2.75 -0.162 0.46971E+04 122 nepheline 8.38 6.02 -2.36 -0.337 0.40239E+04 128 periclase-Fe 11.64 6.72 -4.92 -1.230 0.84004E+04 134 phlogopite-Na 29.73 27.37 -2.36 -0.131 0.40321E+04 136 prehnite 19.47 18.20 -1.27 -0.075 0.21650E+04 137 prehnite-Fe 22.59 22.13 -0.46 -0.028 0.78554E+03 138 pumpellyite-Fe 46.47 44.07 -2.40 -0.053 0.40935E+04 139 pumpellyite-Mg 49.19 46.59 -2.61 -0.058 0.44521E+04 143 pyrrhotite -4.24 -8.01 -3.77 -1.257 0.64387E+04 144 pyrrhotiteFe0.875 -6.00 -9.31 -3.31 -1.217 0.56487E+04 145 pyroxmangite 7.42 5.96 -1.46 -0.292 0.24935E+04 146 pyrophyllite -6.10 -10.79 -4.69 -0.293 0.80039E+04 147 quartz -2.98 -3.17 -0.19 -0.064 0.32942E+03 152 rhodonite 7.46 5.96 -1.51 -0.301 0.25727E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.75 -1.85 -0.055 0.31585E+04 171 talc 16.55 15.00 -1.55 -0.091 0.26548E+04 174 tephroite 18.11 15.09 -3.03 -0.432 0.51678E+04 178 tridymite -2.61 -3.17 -0.56 -0.187 0.95671E+03 179 tremolite 48.00 46.57 -1.43 -0.039 0.24411E+04 180 ferroactinolite 38.60 34.01 -4.59 -0.124 0.78375E+04 181 troilite-low -4.39 -8.01 -3.62 -1.207 0.61819E+04 187 wairakite 4.06 2.12 -1.94 -0.114 0.33118E+04 188 walstromite 11.53 9.73 -1.80 -0.360 0.30705E+04 189 wollastonite 10.48 9.73 -0.75 -0.150 0.12844E+04 190 pseudo-wollastonite 11.02 9.73 -1.29 -0.258 0.22030E+04 191 zoisite 22.96 19.16 -3.81 -0.173 0.65024E+04 192 akaganeite 7.77 4.89 -2.88 -0.623 0.49216E+04 199 chalcedony -2.79 -3.17 -0.38 -0.127 0.64974E+03 201 montmorillonite-Ca -2.21 -5.93 -3.71 -0.230 0.63370E+04 202 montmorillonite-K -2.16 -6.03 -3.87 -0.237 0.66059E+04 203 montmorillonite-Mg -2.40 -6.53 -4.13 -0.255 0.70512E+04 204 montmorillonite-Na -1.96 -5.34 -3.38 -0.207 0.57627E+04 205 nontronite-Ca 3.28 0.56 -2.72 -0.176 0.46373E+04 206 nontronite-H 2.60 -1.57 -4.16 -0.279 0.71051E+04 207 nontronite-K 3.40 0.46 -2.94 -0.189 0.50275E+04 208 nontronite-Mg 3.14 -0.04 -3.18 -0.206 0.54320E+04 209 nontronite-Na 3.58 1.15 -2.43 -0.156 0.41479E+04 224 tobermorite 9.84 7.57 -2.26 -0.618 0.38665E+04 230 alabandite -0.96 -5.60 -4.64 -1.547 0.79240E+04 233 boehmite 4.43 0.96 -3.47 -0.579 0.59293E+04 235 ferrous-oxide 9.82 6.72 -3.10 -0.776 0.53015E+04 240 silica-amorphous -2.08 -3.17 -1.10 -0.365 0.18699E+04 242 an20ab80 2.08 1.43 -0.65 -0.050 0.11067E+04 243 an25ab75 2.71 1.87 -0.84 -0.064 0.14313E+04 244 an30ab70 3.34 2.31 -1.03 -0.079 0.17642E+04 245 tr.625ac.25prg.125 45.31 44.46 -0.85 -0.023 0.14479E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 79.9990000 g New total amount of reactant added: 83.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7403E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 83.9990000 Water: Moles liquid = 0.5496E+02 kg liquid = 0.9901E+00 Moles total = 0.5446E+02 kg total = 0.9810E+00 Activity = 1.0000 Stoichiometric ionic strength = .1020713E-01 Osmotic coef. = 0.9636 True ionic strength = .1819171E-01 Chg. balance for total moles = -.7403E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.98764E-10 -10.0054 0.83518E-10 -10.0782 0.84564E+00 -0.0728 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13877E-03 -3.8577 0.11670E-03 -3.9329 0.84094E+00 -0.0752 4 SO4-- 0.30909E-09 -9.5099 0.16484E-09 -9.7829 0.53331E+00 -0.2730 5 HCO3- 0.46135E-05 -5.3360 0.38849E-05 -5.4106 0.84207E+00 -0.0747 6 HS- 0.25753E-04 -4.5892 0.21660E-04 -4.6644 0.84105E+00 -0.0752 7 Al+++ 0.19567E-28 -28.7085 0.48044E-29 -29.3184 0.24553E+00 -0.6099 8 H4SiO4 0.67929E-03 -3.1679 0.67929E-03 -3.1679 0.10000E+01 0.0000 9 Ca++ 0.11395E-06 -6.9433 0.60358E-07 -7.2193 0.52970E+00 -0.2760 10 Mg++ 0.23389E-10 -10.6310 0.12337E-10 -10.9088 0.52747E+00 -0.2778 11 Fe++ 0.69730E-13 -13.1566 0.36817E-13 -13.4339 0.52800E+00 -0.2774 12 K+ 0.14193E-03 -3.8479 0.11954E-03 -3.9225 0.84226E+00 -0.0746 13 Na+ 0.18041E-01 -1.7437 0.15169E-01 -1.8190 0.84080E+00 -0.0753 14 Mn++ 0.18454E-10 -10.7339 0.97513E-11 -11.0109 0.52840E+00 -0.2770 15 HPO4-- 0.74335E-07 -7.1288 0.39649E-07 -7.4018 0.53338E+00 -0.2730 16 HSiO3- 0.94364E-02 -2.0252 0.79355E-02 -2.1004 0.84094E+00 -0.0752 17 Ca(HSiO3)+ 0.12739E-07 -7.8949 0.10731E-07 -7.9693 0.84242E+00 -0.0745 18 Mg(HSiO3)+ 0.32404E-11 -11.4894 0.27298E-11 -11.5639 0.84242E+00 -0.0745 19 NaHSiO3,aq 0.19118E-02 -2.7186 0.19118E-02 -2.7186 0.10000E+01 0.0000 20 AlO+ 0.10555E-15 -15.9765 0.88919E-16 -16.0510 0.84242E+00 -0.0745 22 HAlO2,aq 0.21305E-09 -9.6715 0.21305E-09 -9.6715 0.10000E+01 0.0000 23 AlO2- 0.67846E-05 -5.1685 0.56960E-05 -5.2444 0.83955E+00 -0.0760 24 CH4,aq 0.50247E-06 -6.2989 0.50091E-06 -6.3002 0.99688E+00 -0.0014 25 C2H6,aq 0.18301E-16 -16.7375 0.18244E-16 -16.7389 0.99688E+00 -0.0014 29 CO,aq 0.39961E-16 -16.3984 0.39961E-16 -16.3984 0.10000E+01 0.0000 30 CO2,aq 0.65623E-09 -9.1829 0.65418E-09 -9.1843 0.99688E+00 -0.0014 31 CO3-2 0.80803E-05 -5.0926 0.43009E-05 -5.3664 0.53226E+00 -0.2739 32 CaCO3,aq 0.31794E-08 -8.4977 0.31794E-08 -8.4977 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.70135E-11 -11.1541 0.59084E-11 -11.2285 0.84242E+00 -0.0745 34 CaCl+ 0.13323E-10 -10.8754 0.11224E-10 -10.9499 0.84242E+00 -0.0745 35 CaCl2,aq 0.30497E-15 -15.5157 0.30497E-15 -15.5157 0.10000E+01 0.0000 36 CaOH+ 0.60491E-07 -7.2183 0.50959E-07 -7.2928 0.84242E+00 -0.0745 37 CaSO4,aq 0.31000E-14 -14.5086 0.31000E-14 -14.5086 0.10000E+01 0.0000 38 HCl,aq 0.18333E-14 -14.7368 0.18333E-14 -14.7368 0.10000E+01 0.0000 43 FeCl+ 0.79435E-17 -17.1000 0.66918E-17 -17.1745 0.84242E+00 -0.0745 46 FeO,aq 0.20872E-09 -9.6804 0.20872E-09 -9.6804 0.10000E+01 0.0000 47 FeOH+ 0.17348E-10 -10.7607 0.14615E-10 -10.8352 0.84242E+00 -0.0745 48 HFeO2- 0.31965E-07 -7.4953 0.26881E-07 -7.5706 0.84094E+00 -0.0752 49 FeO+ 0.27413E-16 -16.5620 0.23093E-16 -16.6365 0.84242E+00 -0.0745 51 FeO2- 0.77377E-09 -9.1114 0.65070E-09 -9.1866 0.84094E+00 -0.0752 52 HFeO2,aq 0.68013E-11 -11.1674 0.68013E-11 -11.1674 0.10000E+01 0.0000 53 H2,aq 0.23792E-05 -5.6236 0.23717E-05 -5.6249 0.99688E+00 -0.0014 54 KCl,aq 0.24701E-09 -9.6073 0.24701E-09 -9.6073 0.10000E+01 0.0000 56 KOH,aq 0.62399E-06 -6.2048 0.62399E-06 -6.2048 0.10000E+01 0.0000 57 KSO4- 0.36101E-12 -12.4425 0.30359E-12 -12.5177 0.84094E+00 -0.0752 58 MgCO3,aq 0.16239E-12 -12.7895 0.16239E-12 -12.7895 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14618E-14 -14.8351 0.12315E-14 -14.9096 0.84242E+00 -0.0745 60 MgCl+ 0.24722E-14 -14.6069 0.20827E-14 -14.6814 0.84242E+00 -0.0745 61 MgOH+ 0.68498E-10 -10.1643 0.57705E-10 -10.2388 0.84242E+00 -0.0745 63 MnO,aq 0.14758E-08 -8.8310 0.14758E-08 -8.8310 0.10000E+01 0.0000 64 MnOH+ 0.42684E-09 -9.3697 0.35958E-09 -9.4442 0.84242E+00 -0.0745 65 MnO2-2 0.13747E-10 -10.8618 0.73169E-11 -11.1357 0.53226E+00 -0.2739 66 HMnO2- 0.15744E-09 -9.8029 0.13240E-09 -9.8781 0.84094E+00 -0.0752 69 MnCl+ 0.81754E-14 -14.0875 0.68872E-14 -14.1620 0.84242E+00 -0.0745 70 MnSO4,aq 0.45554E-18 -18.3415 0.45554E-18 -18.3415 0.10000E+01 0.0000 71 NaCl,aq 0.57801E-06 -6.2381 0.57801E-06 -6.2381 0.10000E+01 0.0000 72 NaOH,aq 0.79808E-04 -4.0980 0.79808E-04 -4.0980 0.10000E+01 0.0000 74 OH- 0.85547E-02 -2.0678 0.71821E-02 -2.1437 0.83955E+00 -0.0760 79 HPO3-2 0.55803E-15 -15.2533 0.29702E-15 -15.5272 0.53226E+00 -0.2739 81 H2PO3- 0.57944E-19 -19.2370 0.48728E-19 -19.3122 0.84094E+00 -0.0752 82 H3PO4,aq 0.17805E-17 -17.7495 0.17805E-17 -17.7495 0.10000E+01 0.0000 83 H2PO4- 0.68976E-10 -10.1613 0.58055E-10 -10.2362 0.84167E+00 -0.0749 84 PO4-3 0.16138E-08 -8.7921 0.41459E-09 -9.3824 0.25690E+00 -0.5902 88 HP2O7-3 0.26353E-17 -17.5792 0.64765E-18 -18.1887 0.24576E+00 -0.6095 89 P2O7-4 0.22316E-16 -16.6514 0.19130E-17 -17.7183 0.85725E-01 -1.0669 90 H2S,aq 0.54521E-08 -8.2634 0.54351E-08 -8.2648 0.99688E+00 -0.0014 91 S2-2 0.81734E-14 -14.0876 0.43504E-14 -14.3615 0.53226E+00 -0.2739 97 SO3-2 0.98832E-16 -16.0051 0.53306E-16 -16.2732 0.53936E+00 -0.2681 98 HSO3- 0.30982E-18 -18.5089 0.26054E-18 -18.5841 0.84094E+00 -0.0752 99 HSO4- 0.15150E-16 -16.8196 0.12774E-16 -16.8937 0.84318E+00 -0.0741 101 S2O3-2 0.19838E-19 -19.7025 0.10559E-19 -19.9764 0.53226E+00 -0.2739 Charge balance for all species = -.7530E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9876366E-10 -.2001942E-01 -.2014699E+02 0.0000 2 H2O 0.1000000E+01 0.5550555E+02 0.9983938E+06 0.0000 3 Cl- 0.1387704E-03 0.1393487E-03 0.4932643E+01 6.1453 4 SO4-- 0.3090883E-09 -.1096856E-05 -.1052018E+00 10.3735 5 HCO3- 0.4613547E-05 0.1320020E-04 0.8041865E+00 4.6676 6 HS- 0.2575278E-04 0.2685540E-04 0.8867802E+00 5.4139 7 Al+++ 0.1956740E-28 0.6784818E-05 0.1827798E+00 0.9163 8 H4SiO4 0.6792854E-03 0.1202756E-01 0.1154235E+04 -3.1679 9 Ca++ 0.1139469E-06 0.1903761E-06 0.7618025E-02 12.9372 10 Mg++ 0.2338909E-10 0.9529423E-10 0.2313190E-05 9.2476 11 Fe++ 0.6972959E-13 0.3297194E-07 0.1838520E-02 6.7225 12 K+ 0.1419323E-03 0.1425566E-03 0.5565577E+01 6.1557 13 Na+ 0.1804121E-01 0.2003343E-01 0.4598480E+03 8.2592 14 Mn++ 0.1845431E-10 0.2092261E-08 0.1147659E-03 9.1455 15 HPO4-- 0.7433536E-07 0.7601814E-07 0.7284796E-02 12.7547 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1390886E+01 -.1982196E-01 -.1371064E+01 0.0000000E+00 2 H2O 0.5445529E+02 0.5495807E+02 -.5027807E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2353403E-02 -.1086037E-05 0.2354489E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2327899E-02 0.2659051E-04 -.2354489E-02 0.0000000E+00 7 Al+++ 0.2738990E+00 0.6717895E-05 0.2738923E+00 0.0000000E+00 8 H4SiO4 0.8746634E+00 0.1190892E-01 0.8627544E+00 0.0000000E+00 9 Ca++ 0.9662530E-01 0.1884983E-06 0.9662512E-01 0.0000000E+00 10 Mg++ 0.6666587E-01 0.9435429E-10 0.6666587E-01 0.0000000E+00 11 Fe++ 0.5989201E-01 0.3264672E-07 0.5989198E-01 0.0000000E+00 12 K+ 0.1783418E-01 0.1411505E-03 0.1769303E-01 0.0000000E+00 13 Na+ 0.1055993E+00 0.1983582E-01 0.8576346E-01 0.0000000E+00 14 Mn++ 0.1456425E-02 0.2071624E-08 0.1456423E-02 0.0000000E+00 15 HPO4-- 0.4970705E-03 0.7526833E-07 0.4969952E-03 0.0000000E+00 Chg. balance for solid moles: -.1149E-15 Mass of aqueous solution: 0.991679E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 83.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.8576E-01 -1.067 22.49 1.352 24.54 8.633 andradite 0.9418E-02 -2.026 4.786 0.680 5.222 1.243 grossular 0.1574E-02 -2.803 0.7092 -0.149 0.7738 0.1973 apatite-OH 0.1657E-03 -3.781 0.8322E-01 -1.080 0.9080E-01 0.2644E-01 clinochlore 0.1333E-01 -1.875 7.411 0.870 8.086 2.819 daphnite 0.4164E-02 -2.380 2.971 0.473 3.242 0.9004 chlorite-Mn 0.2913E-03 -3.536 0.2065 -0.685 0.2253 0.6581E-01 microcline 0.1567E-01 -1.805 4.361 0.640 4.759 1.704 stilbite 0.6282E-01 -1.202 44.27 1.646 48.30 20.65 stilpnomelane-Fe 0.4047E-02 -2.393 4.363 0.640 4.760 1.507 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8568E+00 0.8568E+00 1.0000 -0.067 grossular 0.1432E+00 0.1432E+00 1.0000 -0.844 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7495E+00 0.7495E+00 1.0000 -0.125 daphnite 0.2341E+00 0.2341E+00 1.0000 -0.631 chlorite-Mn 0.1637E-01 0.1637E-01 1.0000 -1.786 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 91.650253 g Volume = 37.744331 cm3 Porosity: -9.0889% V(tot) - V(min): -.31447E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 83.9990000 g log = 1.9243 Original solution: 1000.0103000 g Original solution / Rock added: 11.91 (Water/Rock Ratio), log = 1.0757 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0560 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9962E+00 0.9855 0.1037E+01 0.1052E+01 CO2,gas 0.7039E-07 1.0073 0.7488E-07 0.7434E-07 CH4,gas 0.7405E-03 1.0130 0.7921E-03 0.7820E-03 H2,gas 0.3079E-02 1.0006 0.3253E-02 0.3251E-02 H2S,gas 0.1507E-06 0.9959 0.1585E-06 0.1592E-06 S2,gas 0.8422E-28 1.0000 0.8894E-28 0.8894E-28 CO,gas 0.5975E-13 1.0000 0.6310E-13 0.6310E-13 SO3,gas 0.4071E-45 1.0000 0.4299E-45 0.4299E-45 SO2,gas 0.5009E-25 1.0000 0.5290E-25 0.5290E-25 HCl,gas 0.3065E-17 1.0000 0.3237E-17 0.3237E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.48529E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.49 -9.13 -3.042 0.15582E+05 -7.126 3 CH4,gas 4.81 -0.29 -5.10 -1.275 0.87102E+04 -3.101 4 H2,gas 8.29 3.80 -4.49 -2.564 0.76626E+04 -2.488 5 H2S,gas -5.94 -14.74 -8.80 -4.400 0.15026E+05 -6.800 6 S2,gas -7.03 -37.08 -30.05 -4.623 0.51311E+05 -28.051 7 CO,gas 3.51 -11.69 -15.20 -4.677 0.25954E+05 -13.200 8 SO3,gas 17.43 -29.94 -47.37 -11.842 0.80877E+05 -45.367 9 SO2,gas 1.14 -26.14 -27.28 -7.274 0.46574E+05 -25.277 10 HCl,gas 5.48 -14.01 -19.49 -9.745 0.33278E+05 -17.490 11 acmite 7.74 6.75 -0.99 -0.103 0.16925E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.77 -4.78 -0.239 0.81696E+04 20 analcite 3.37 2.84 -0.53 -0.059 0.90675E+03 26 annite 20.21 17.74 -2.47 -0.137 0.42237E+04 27 phlogopite 27.15 25.31 -1.84 -0.102 0.31340E+04 29 anorthite 12.80 8.43 -4.36 -0.336 0.74511E+04 35 aragonite 0.99 -2.55 -3.54 -1.179 0.60408E+04 36 brucite 12.58 9.25 -3.33 -0.666 0.56841E+04 37 calcite 0.83 -2.55 -3.38 -1.128 0.57795E+04 38 carnegieite-low 9.06 6.01 -3.06 -0.437 0.52198E+04 39 carnegieite-high 10.13 6.01 -4.13 -0.590 0.70466E+04 40 carpholite-Mg 8.65 4.74 -3.91 -0.260 0.66694E+04 41 carpholite-Fe 6.78 2.22 -4.56 -0.304 0.77924E+04 42 celadonite 5.40 3.65 -1.75 -0.103 0.29925E+04 43 celadonite-Fe 3.94 1.12 -2.81 -0.166 0.48052E+04 44 chrysotile 23.94 21.41 -2.53 -0.211 0.43204E+04 49 chlorite-Al-free 47.26 42.81 -4.45 -0.185 0.75941E+04 51 chloritoid-Fe 9.24 5.39 -3.85 -0.257 0.65764E+04 52 chloritoid-Mn 11.46 7.81 -3.65 -0.244 0.62375E+04 54 coesite -2.37 -3.17 -0.80 -0.266 0.13636E+04 61 cristobalite -2.55 -3.17 -0.62 -0.206 0.10565E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.92 -1.98 -0.330 0.33804E+04 66 diamond -3.11 -7.89 -4.78 -1.367 0.81671E+04 67 diopside 16.22 15.85 -0.37 -0.037 0.62586E+03 68 hedenbergite 14.24 13.32 -0.92 -0.092 0.15720E+04 75 epidote 24.78 23.03 -1.75 -0.085 0.29867E+04 76 clinozoisite 22.92 19.12 -3.80 -0.173 0.64914E+04 77 epidote-Fe 29.94 26.93 -3.00 -0.156 0.51296E+04 78 fayalite 14.08 10.28 -3.80 -0.543 0.64917E+04 79 ferrosilite 11.19 7.11 -4.08 -0.408 0.69641E+04 83 gibbsite 4.10 0.92 -3.18 -0.454 0.54316E+04 84 glaucophane 23.11 20.75 -2.36 -0.064 0.40300E+04 85 glaucophane-Fe 17.42 13.17 -4.24 -0.115 0.72437E+04 86 graphite -3.55 -7.89 -4.34 -1.240 0.74132E+04 87 greenalite 16.19 13.83 -2.36 -0.197 0.40341E+04 90 hematite 12.60 9.65 -2.95 -0.358 0.50402E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.84 -1.41 -0.141 0.24098E+04 97 kalsilite 7.62 3.90 -3.72 -0.531 0.63452E+04 98 kaolinite -1.27 -4.50 -3.23 -0.294 0.55154E+04 101 laumontite 2.97 2.10 -0.88 -0.058 0.14967E+04 102 lawsonite 9.68 8.43 -1.24 -0.083 0.21249E+04 103 leucite 4.17 0.74 -3.43 -0.343 0.58592E+04 105 lizardite 23.29 21.41 -1.88 -0.157 0.32107E+04 107 magnetite 20.13 16.37 -3.76 -0.307 0.64278E+04 108 minnesotaite 10.46 7.50 -2.97 -0.174 0.50627E+04 112 manganosite 14.07 9.15 -4.92 -1.231 0.84049E+04 120 muscovite 2.68 -0.60 -3.28 -0.193 0.55978E+04 121 paragonite 4.34 1.50 -2.83 -0.167 0.48362E+04 122 nepheline 8.38 6.01 -2.37 -0.339 0.40477E+04 128 periclase-Fe 11.64 6.72 -4.92 -1.229 0.83950E+04 134 phlogopite-Na 29.73 27.41 -2.32 -0.129 0.39559E+04 136 prehnite 19.47 18.20 -1.26 -0.074 0.21569E+04 137 prehnite-Fe 22.59 22.11 -0.48 -0.029 0.81457E+03 138 pumpellyite-Fe 46.47 44.04 -2.43 -0.054 0.41416E+04 139 pumpellyite-Mg 49.19 46.57 -2.62 -0.058 0.44802E+04 143 pyrrhotite -4.24 -8.02 -3.78 -1.259 0.64483E+04 144 pyrrhotiteFe0.875 -6.00 -9.33 -3.33 -1.225 0.56867E+04 145 pyroxmangite 7.42 5.98 -1.44 -0.288 0.24562E+04 146 pyrophyllite -6.10 -10.84 -4.74 -0.296 0.80954E+04 147 quartz -2.98 -3.17 -0.19 -0.062 0.31750E+03 152 rhodonite 7.46 5.98 -1.48 -0.297 0.25354E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.81 -1.79 -0.053 0.30583E+04 171 talc 16.55 15.07 -1.48 -0.087 0.25308E+04 174 tephroite 18.11 15.12 -2.99 -0.427 0.51051E+04 178 tridymite -2.61 -3.17 -0.55 -0.184 0.94480E+03 179 tremolite 48.00 46.77 -1.23 -0.033 0.21073E+04 180 ferroactinolite 38.60 34.14 -4.45 -0.120 0.76038E+04 181 troilite-low -4.39 -8.02 -3.63 -1.209 0.61915E+04 187 wairakite 4.06 2.10 -1.96 -0.115 0.33475E+04 188 walstromite 11.53 9.77 -1.76 -0.352 0.30028E+04 189 wollastonite 10.48 9.77 -0.71 -0.143 0.12167E+04 190 pseudo-wollastonite 11.02 9.77 -1.25 -0.250 0.21354E+04 191 zoisite 22.96 19.12 -3.84 -0.175 0.65639E+04 192 akaganeite 7.77 4.82 -2.94 -0.637 0.50282E+04 199 chalcedony -2.79 -3.17 -0.37 -0.125 0.63782E+03 201 montmorillonite-Ca -2.21 -5.96 -3.74 -0.231 0.63880E+04 202 montmorillonite-K -2.16 -6.06 -3.90 -0.239 0.66548E+04 203 montmorillonite-Mg -2.40 -6.56 -4.16 -0.257 0.71071E+04 204 montmorillonite-Na -1.96 -5.36 -3.40 -0.208 0.58117E+04 205 nontronite-Ca 3.28 0.46 -2.82 -0.183 0.48206E+04 206 nontronite-H 2.60 -1.68 -4.27 -0.286 0.72976E+04 207 nontronite-K 3.40 0.35 -3.05 -0.196 0.52088E+04 208 nontronite-Mg 3.14 -0.15 -3.29 -0.214 0.56203E+04 209 nontronite-Na 3.58 1.05 -2.54 -0.163 0.43293E+04 224 tobermorite 9.84 7.61 -2.23 -0.609 0.38082E+04 230 alabandite -0.96 -5.60 -4.63 -1.545 0.79136E+04 233 boehmite 4.43 0.92 -3.51 -0.586 0.59989E+04 235 ferrous-oxide 9.82 6.72 -3.10 -0.775 0.52961E+04 240 silica-amorphous -2.08 -3.17 -1.09 -0.363 0.18580E+04 242 an20ab80 2.08 1.42 -0.66 -0.050 0.11186E+04 243 an25ab75 2.71 1.86 -0.85 -0.065 0.14462E+04 244 an30ab70 3.34 2.30 -1.04 -0.080 0.17821E+04 245 tr.625ac.25prg.125 45.31 44.62 -0.68 -0.018 0.11671E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 83.9990000 g New total amount of reactant added: 87.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7396E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 87.9990000 Water: Moles liquid = 0.5494E+02 kg liquid = 0.9897E+00 Moles total = 0.5441E+02 kg total = 0.9801E+00 Activity = 1.0000 Stoichiometric ionic strength = .1050955E-01 Osmotic coef. = 0.9637 True ionic strength = .1868563E-01 Chg. balance for total moles = -.7396E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.97240E-10 -10.0122 0.82096E-10 -10.0857 0.84426E+00 -0.0735 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13882E-03 -3.8576 0.11653E-03 -3.9335 0.83948E+00 -0.0760 4 SO4-- 0.10357E-09 -9.9848 0.54860E-10 -10.2607 0.52970E+00 -0.2760 5 HCO3- 0.42353E-05 -5.3731 0.35604E-05 -5.4485 0.84063E+00 -0.0754 6 HS- 0.25765E-04 -4.5890 0.21632E-04 -4.6649 0.83959E+00 -0.0759 7 Al+++ 0.17262E-28 -28.7629 0.41730E-29 -29.3796 0.24175E+00 -0.6166 8 H4SiO4 0.69005E-03 -3.1611 0.69005E-03 -3.1611 0.10000E+01 0.0000 9 Ca++ 0.11876E-06 -6.9253 0.62472E-07 -7.2043 0.52604E+00 -0.2790 10 Mg++ 0.23507E-10 -10.6288 0.12312E-10 -10.9097 0.52377E+00 -0.2809 11 Fe++ 0.68284E-13 -13.1657 0.35802E-13 -13.4461 0.52431E+00 -0.2804 12 K+ 0.14579E-03 -3.8363 0.12258E-03 -3.9116 0.84082E+00 -0.0753 13 Na+ 0.18532E-01 -1.7321 0.15554E-01 -1.8081 0.83933E+00 -0.0761 14 Mn++ 0.18547E-10 -10.7317 0.97319E-11 -11.0118 0.52472E+00 -0.2801 15 HPO4-- 0.69067E-07 -7.1607 0.36590E-07 -7.4366 0.52977E+00 -0.2759 16 HSiO3- 0.97690E-02 -2.0102 0.82008E-02 -2.0861 0.83948E+00 -0.0760 17 Ca(HSiO3)+ 0.13649E-07 -7.8649 0.11479E-07 -7.9401 0.84099E+00 -0.0752 18 Mg(HSiO3)+ 0.33478E-11 -11.4752 0.28155E-11 -11.5505 0.84099E+00 -0.0752 19 NaHSiO3,aq 0.20259E-02 -2.6934 0.20259E-02 -2.6934 0.10000E+01 0.0000 20 AlO+ 0.95044E-16 -16.0221 0.79931E-16 -16.0973 0.84099E+00 -0.0752 22 HAlO2,aq 0.19483E-09 -9.7103 0.19483E-09 -9.7103 0.10000E+01 0.0000 23 AlO2- 0.63231E-05 -5.1991 0.52991E-05 -5.2758 0.83805E+00 -0.0767 24 CH4,aq 0.13820E-05 -5.8595 0.13776E-05 -5.8609 0.99679E+00 -0.0014 25 C2H6,aq 0.10473E-15 -15.9799 0.10439E-15 -15.9813 0.99679E+00 -0.0014 29 CO,aq 0.47584E-16 -16.3225 0.47584E-16 -16.3225 0.10000E+01 0.0000 30 CO2,aq 0.59122E-09 -9.2283 0.58932E-09 -9.2296 0.99679E+00 -0.0014 31 CO3-2 0.75851E-05 -5.1200 0.40098E-05 -5.3969 0.52864E+00 -0.2768 32 CaCO3,aq 0.30680E-08 -8.5131 0.30680E-08 -8.5131 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.66641E-11 -11.1763 0.56044E-11 -11.2515 0.84099E+00 -0.0752 34 CaCl+ 0.13794E-10 -10.8603 0.11601E-10 -10.9355 0.84099E+00 -0.0752 35 CaCl2,aq 0.31478E-15 -15.5020 0.31478E-15 -15.5020 0.10000E+01 0.0000 36 CaOH+ 0.63803E-07 -7.1952 0.53658E-07 -7.2704 0.84099E+00 -0.0752 37 CaSO4,aq 0.10678E-14 -14.9715 0.10678E-14 -14.9715 0.10000E+01 0.0000 38 HCl,aq 0.17995E-14 -14.7448 0.17995E-14 -14.7448 0.10000E+01 0.0000 43 FeCl+ 0.77270E-17 -17.1120 0.64983E-17 -17.1872 0.84099E+00 -0.0752 46 FeO,aq 0.21006E-09 -9.6777 0.21006E-09 -9.6777 0.10000E+01 0.0000 47 FeOH+ 0.17192E-10 -10.7647 0.14458E-10 -10.8399 0.84099E+00 -0.0752 48 HFeO2- 0.32784E-07 -7.4843 0.27522E-07 -7.5603 0.83948E+00 -0.0760 49 FeO+ 0.23628E-16 -16.6266 0.19871E-16 -16.7018 0.84099E+00 -0.0752 51 FeO2- 0.69026E-09 -9.1610 0.57946E-09 -9.2370 0.83948E+00 -0.0760 52 HFeO2,aq 0.59535E-11 -11.2252 0.59535E-11 -11.2252 0.10000E+01 0.0000 53 H2,aq 0.31451E-05 -5.5024 0.31350E-05 -5.5038 0.99679E+00 -0.0014 54 KCl,aq 0.25293E-09 -9.5970 0.25293E-09 -9.5970 0.10000E+01 0.0000 56 KOH,aq 0.65092E-06 -6.1865 0.65092E-06 -6.1865 0.10000E+01 0.0000 57 KSO4- 0.12341E-12 -12.9086 0.10360E-12 -12.9846 0.83948E+00 -0.0760 58 MgCO3,aq 0.15109E-12 -12.8208 0.15109E-12 -12.8208 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13393E-14 -14.8731 0.11263E-14 -14.9483 0.84099E+00 -0.0752 60 MgCl+ 0.24681E-14 -14.6076 0.20756E-14 -14.6829 0.84099E+00 -0.0752 61 MgOH+ 0.69665E-10 -10.1570 0.58587E-10 -10.2322 0.84099E+00 -0.0752 63 MnO,aq 0.15243E-08 -8.8169 0.15243E-08 -8.8169 0.10000E+01 0.0000 64 MnOH+ 0.43411E-09 -9.3624 0.36508E-09 -9.4376 0.84099E+00 -0.0752 65 MnO2-2 0.14795E-10 -10.8299 0.78214E-11 -11.1067 0.52864E+00 -0.2768 66 HMnO2- 0.16572E-09 -9.7806 0.13912E-09 -9.8566 0.83948E+00 -0.0760 69 MnCl+ 0.81617E-14 -14.0882 0.68639E-14 -14.1634 0.84099E+00 -0.0752 70 MnSO4,aq 0.15131E-18 -18.8201 0.15131E-18 -18.8201 0.10000E+01 0.0000 71 NaCl,aq 0.59187E-06 -6.2278 0.59187E-06 -6.2278 0.10000E+01 0.0000 72 NaOH,aq 0.83252E-04 -4.0796 0.83252E-04 -4.0796 0.10000E+01 0.0000 74 OH- 0.87184E-02 -2.0596 0.73065E-02 -2.1363 0.83805E+00 -0.0767 79 HPO3-2 0.68538E-15 -15.1641 0.36232E-15 -15.4409 0.52864E+00 -0.2768 81 H2PO3- 0.69602E-19 -19.1574 0.58429E-19 -19.2334 0.83948E+00 -0.0760 82 H3PO4,aq 0.15877E-17 -17.7992 0.15877E-17 -17.7992 0.10000E+01 0.0000 83 H2PO4- 0.62679E-10 -10.2029 0.52664E-10 -10.2785 0.84022E+00 -0.0756 84 PO4-3 0.15373E-08 -8.8132 0.38923E-09 -9.4098 0.25319E+00 -0.5966 88 HP2O7-3 0.22407E-17 -17.6496 0.54218E-18 -18.2659 0.24197E+00 -0.6162 89 P2O7-4 0.19526E-16 -16.7094 0.16292E-17 -17.7880 0.83439E-01 -1.0786 90 H2S,aq 0.53529E-08 -8.2714 0.53358E-08 -8.2728 0.99679E+00 -0.0014 91 S2-2 0.62098E-14 -14.2069 0.32827E-14 -14.4838 0.52864E+00 -0.2768 97 SO3-2 0.43764E-16 -16.3589 0.23450E-16 -16.6298 0.53584E+00 -0.2710 98 HSO3- 0.13421E-18 -18.8722 0.11267E-18 -18.9482 0.83948E+00 -0.0760 99 HSO4- 0.49645E-17 -17.3041 0.41789E-17 -17.3789 0.84176E+00 -0.0748 Charge balance for all species = -.7684E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9724040E-10 -.2063103E-01 -.2076141E+02 0.0000 2 H2O 0.1000000E+01 0.5550527E+02 0.9983366E+06 0.0000 3 Cl- 0.1388189E-03 0.1394110E-03 0.4934592E+01 6.1521 4 SO4-- 0.1035679E-09 -.2168096E-05 -.2079360E+00 9.9106 5 HCO3- 0.4235345E-05 0.1320611E-04 0.8045042E+00 4.6372 6 HS- 0.2576461E-04 0.2793816E-04 0.9224855E+00 5.4208 7 Al+++ 0.1726177E-28 0.6323298E-05 0.1703378E+00 0.8775 8 H4SiO4 0.6900457E-03 0.1248494E-01 0.1198066E+04 -3.1611 9 Ca++ 0.1187603E-06 0.1993013E-06 0.7974756E-02 12.9670 10 Mg++ 0.2350712E-10 0.9667454E-10 0.2346573E-05 9.2617 11 Fe++ 0.6828422E-13 0.3370789E-07 0.1879458E-02 6.7253 12 K+ 0.1457860E-03 0.1464372E-03 0.5716781E+01 6.1741 13 Na+ 0.1853175E-01 0.2064152E-01 0.4737814E+03 8.2775 14 Mn++ 0.1854673E-10 0.2157466E-08 0.1183363E-03 9.1595 15 HPO4-- 0.6906744E-07 0.7066743E-07 0.6771685E-02 12.7347 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1457120E+01 -.2041840E-01 -.1436701E+01 0.0000000E+00 2 H2O 0.5440515E+02 0.5493321E+02 -.5280677E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2464257E-02 -.2145751E-05 0.2466402E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2438752E-02 0.2765022E-04 -.2466402E-02 0.0000000E+00 7 Al+++ 0.2869420E+00 0.6258127E-05 0.2869357E+00 0.0000000E+00 8 H4SiO4 0.9163145E+00 0.1235626E-01 0.9039582E+00 0.0000000E+00 9 Ca++ 0.1012259E+00 0.1972472E-06 0.1012257E+00 0.0000000E+00 10 Mg++ 0.6984048E-01 0.9567817E-10 0.6984048E-01 0.0000000E+00 11 Fe++ 0.6274404E-01 0.3336048E-07 0.6274401E-01 0.0000000E+00 12 K+ 0.1868344E-01 0.1449280E-03 0.1853851E-01 0.0000000E+00 13 Na+ 0.1106203E+00 0.2042878E-01 0.9019148E-01 0.0000000E+00 14 Mn++ 0.1525779E-02 0.2135230E-08 0.1525777E-02 0.0000000E+00 15 HPO4-- 0.5207408E-03 0.6993910E-07 0.5206709E-03 0.0000000E+00 Chg. balance for solid moles: -.1741E-15 Mass of aqueous solution: 0.991287E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 87.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9019E-01 -1.045 23.65 1.374 24.63 9.079 andradite 0.9866E-02 -2.006 5.014 0.700 5.222 1.303 grossular 0.1723E-02 -2.764 0.7761 -0.110 0.8084 0.2160 apatite-OH 0.1736E-03 -3.761 0.8718E-01 -1.060 0.9080E-01 0.2770E-01 clinochlore 0.1397E-01 -1.855 7.764 0.890 8.087 2.953 daphnite 0.4251E-02 -2.372 3.033 0.482 3.159 0.9191 chlorite-Mn 0.3052E-03 -3.515 0.2163 -0.665 0.2253 0.6894E-01 microcline 0.1636E-01 -1.786 4.554 0.658 4.744 1.779 stilbite 0.6559E-01 -1.183 46.22 1.665 48.15 21.56 stilpnomelane-Fe 0.4352E-02 -2.361 4.691 0.671 4.886 1.620 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8513E+00 0.8513E+00 1.0000 -0.070 grossular 0.1487E+00 0.1487E+00 1.0000 -0.828 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7541E+00 0.7541E+00 1.0000 -0.123 daphnite 0.2295E+00 0.2295E+00 1.0000 -0.639 chlorite-Mn 0.1647E-01 0.1647E-01 1.0000 -1.783 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 96.009541 g Volume = 39.525274 cm3 Porosity: -9.1870% V(tot) - V(min): -.33257E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 87.9990000 g log = 1.9445 Original solution: 1000.0103000 g Original solution / Rock added: 11.36 (Water/Rock Ratio), log = 1.0555 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0585 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9939E+00 0.9854 0.1037E+01 0.1052E+01 CO2,gas 0.6327E-07 1.0073 0.6746E-07 0.6697E-07 CH4,gas 0.2032E-02 1.0129 0.2178E-02 0.2151E-02 H2,gas 0.4060E-02 1.0006 0.4300E-02 0.4298E-02 H2S,gas 0.1476E-06 0.9959 0.1556E-06 0.1563E-06 S2,gas 0.4635E-28 1.0000 0.4906E-28 0.4906E-28 CO,gas 0.7098E-13 1.0000 0.7514E-13 0.7514E-13 SO3,gas 0.1306E-45 1.0000 0.1382E-45 0.1382E-45 SO2,gas 0.2124E-25 1.0000 0.2249E-25 0.2249E-25 HCl,gas 0.3002E-17 1.0000 0.3177E-17 0.3177E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.53 -9.17 -3.057 0.15659E+05 -7.171 3 CH4,gas 4.81 0.15 -4.66 -1.165 0.79600E+04 -2.662 4 H2,gas 8.29 3.92 -4.37 -2.495 0.74557E+04 -2.367 5 H2S,gas -5.94 -14.75 -8.81 -4.404 0.15039E+05 -6.808 6 S2,gas -7.03 -37.34 -30.31 -4.663 0.51752E+05 -28.309 7 CO,gas 3.51 -11.61 -15.12 -4.654 0.25824E+05 -13.124 8 SO3,gas 17.43 -30.43 -47.86 -11.965 0.81719E+05 -45.859 9 SO2,gas 1.14 -26.51 -27.65 -7.373 0.47208E+05 -25.648 10 HCl,gas 5.48 -14.02 -19.50 -9.749 0.33292E+05 -17.498 11 acmite 7.74 6.72 -1.02 -0.106 0.17365E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.75 -4.80 -0.240 0.81953E+04 20 analcite 3.37 2.83 -0.54 -0.060 0.91841E+03 26 annite 20.21 17.74 -2.47 -0.137 0.42095E+04 27 phlogopite 27.15 25.35 -1.79 -0.100 0.30620E+04 29 anorthite 12.80 8.40 -4.40 -0.338 0.75093E+04 35 aragonite 0.99 -2.57 -3.55 -1.184 0.60673E+04 36 brucite 12.58 9.26 -3.31 -0.663 0.56601E+04 37 calcite 0.83 -2.57 -3.40 -1.133 0.58059E+04 38 carnegieite-low 9.06 5.99 -3.07 -0.439 0.52431E+04 39 carnegieite-high 10.13 5.99 -4.14 -0.592 0.70699E+04 40 carpholite-Mg 8.65 4.69 -3.96 -0.264 0.67547E+04 41 carpholite-Fe 6.78 2.16 -4.62 -0.308 0.78969E+04 42 celadonite 5.40 3.67 -1.73 -0.102 0.29569E+04 43 celadonite-Fe 3.94 1.13 -2.80 -0.165 0.47888E+04 44 chrysotile 23.94 21.46 -2.47 -0.206 0.42251E+04 49 chlorite-Al-free 47.26 42.93 -4.34 -0.181 0.74036E+04 51 chloritoid-Fe 9.24 5.32 -3.92 -0.261 0.66926E+04 52 chloritoid-Mn 11.46 7.75 -3.71 -0.247 0.63344E+04 54 coesite -2.37 -3.16 -0.79 -0.264 0.13519E+04 61 cristobalite -2.55 -3.16 -0.61 -0.204 0.10448E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.88 -2.02 -0.336 0.34467E+04 66 diamond -3.11 -7.69 -4.59 -1.310 0.78307E+04 67 diopside 16.22 15.91 -0.31 -0.031 0.52757E+03 68 hedenbergite 14.24 13.37 -0.87 -0.087 0.14929E+04 75 epidote 24.78 22.97 -1.80 -0.087 0.30810E+04 76 clinozoisite 22.92 19.08 -3.84 -0.174 0.65533E+04 77 epidote-Fe 29.94 26.86 -3.08 -0.160 0.52563E+04 78 fayalite 14.08 10.29 -3.79 -0.541 0.64706E+04 79 ferrosilite 11.19 7.13 -4.06 -0.406 0.69313E+04 83 gibbsite 4.10 0.88 -3.22 -0.460 0.54979E+04 84 glaucophane 23.11 20.81 -2.30 -0.062 0.39347E+04 85 glaucophane-Fe 17.42 13.20 -4.22 -0.114 0.72061E+04 86 graphite -3.55 -7.69 -4.14 -1.184 0.70769E+04 87 greenalite 16.19 13.85 -2.34 -0.195 0.39966E+04 90 hematite 12.60 9.53 -3.07 -0.372 0.52376E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.83 -1.42 -0.142 0.24214E+04 97 kalsilite 7.62 3.89 -3.73 -0.533 0.63685E+04 98 kaolinite -1.27 -4.57 -3.29 -0.299 0.56247E+04 101 laumontite 2.97 2.08 -0.90 -0.060 0.15317E+04 102 lawsonite 9.68 8.40 -1.28 -0.085 0.21832E+04 103 leucite 4.17 0.73 -3.44 -0.344 0.58708E+04 105 lizardite 23.29 21.46 -1.82 -0.152 0.31154E+04 107 magnetite 20.13 16.26 -3.88 -0.317 0.66205E+04 108 minnesotaite 10.46 7.53 -2.93 -0.172 0.50019E+04 112 manganosite 14.07 9.16 -4.91 -1.227 0.83810E+04 120 muscovite 2.68 -0.68 -3.36 -0.197 0.57303E+04 121 paragonite 4.34 1.43 -2.91 -0.171 0.49688E+04 122 nepheline 8.38 5.99 -2.38 -0.341 0.40710E+04 128 periclase-Fe 11.64 6.73 -4.91 -1.228 0.83903E+04 134 phlogopite-Na 29.73 27.46 -2.27 -0.126 0.38839E+04 136 prehnite 19.47 18.21 -1.26 -0.074 0.21525E+04 137 prehnite-Fe 22.59 22.09 -0.49 -0.030 0.84262E+03 138 pumpellyite-Fe 46.47 44.01 -2.46 -0.055 0.41943E+04 139 pumpellyite-Mg 49.19 46.55 -2.64 -0.059 0.45137E+04 143 pyrrhotite -4.24 -8.03 -3.78 -1.261 0.64572E+04 144 pyrrhotiteFe0.875 -6.00 -9.35 -3.35 -1.232 0.57219E+04 145 pyroxmangite 7.42 6.00 -1.42 -0.284 0.24205E+04 146 pyrophyllite -6.10 -10.89 -4.79 -0.299 0.81814E+04 147 quartz -2.98 -3.16 -0.18 -0.060 0.30585E+03 152 rhodonite 7.46 6.00 -1.46 -0.293 0.24998E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.86 -1.73 -0.052 0.29621E+04 171 talc 16.55 15.14 -1.41 -0.083 0.24123E+04 174 tephroite 18.11 15.16 -2.95 -0.422 0.50455E+04 178 tridymite -2.61 -3.16 -0.55 -0.182 0.93314E+03 179 tremolite 48.00 46.95 -1.05 -0.028 0.17921E+04 180 ferroactinolite 38.60 34.27 -4.33 -0.117 0.73849E+04 181 troilite-low -4.39 -8.03 -3.63 -1.210 0.62004E+04 187 wairakite 4.06 2.08 -1.98 -0.117 0.33825E+04 188 walstromite 11.53 9.81 -1.72 -0.344 0.29402E+04 189 wollastonite 10.48 9.81 -0.68 -0.135 0.11541E+04 190 pseudo-wollastonite 11.02 9.81 -1.21 -0.243 0.20727E+04 191 zoisite 22.96 19.08 -3.88 -0.176 0.66258E+04 192 akaganeite 7.77 4.77 -3.00 -0.649 0.51270E+04 199 chalcedony -2.79 -3.16 -0.37 -0.122 0.62616E+03 201 montmorillonite-Ca -2.21 -5.98 -3.77 -0.233 0.64357E+04 202 montmorillonite-K -2.16 -6.09 -3.92 -0.240 0.67007E+04 203 montmorillonite-Mg -2.40 -6.59 -4.19 -0.259 0.71593E+04 204 montmorillonite-Na -1.96 -5.39 -3.43 -0.210 0.58575E+04 205 nontronite-Ca 3.28 0.36 -2.92 -0.190 0.49887E+04 206 nontronite-H 2.60 -1.78 -4.38 -0.293 0.74742E+04 207 nontronite-K 3.40 0.26 -3.15 -0.202 0.53750E+04 208 nontronite-Mg 3.14 -0.25 -3.39 -0.220 0.57929E+04 209 nontronite-Na 3.58 0.95 -2.63 -0.169 0.44955E+04 224 tobermorite 9.84 7.64 -2.20 -0.600 0.37540E+04 230 alabandite -0.96 -5.59 -4.63 -1.543 0.79033E+04 233 boehmite 4.43 0.88 -3.55 -0.592 0.60652E+04 235 ferrous-oxide 9.82 6.73 -3.10 -0.775 0.52914E+04 240 silica-amorphous -2.08 -3.16 -1.08 -0.360 0.18464E+04 242 an20ab80 2.08 1.42 -0.66 -0.051 0.11303E+04 243 an25ab75 2.71 1.85 -0.86 -0.066 0.14607E+04 244 an30ab70 3.34 2.29 -1.05 -0.081 0.17995E+04 245 tr.625ac.25prg.125 45.31 44.78 -0.53 -0.014 0.90285E+03 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 87.9990000 g New total amount of reactant added: 91.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7383E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 91.9990000 Water: Moles liquid = 0.5491E+02 kg liquid = 0.9893E+00 Moles total = 0.5436E+02 kg total = 0.9792E+00 Activity = 1.0000 Stoichiometric ionic strength = .1079891E-01 Osmotic coef. = 0.9642 True ionic strength = .1915655E-01 Chg. balance for total moles = -.7383E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.95879E-10 -10.0183 0.80824E-10 -10.0925 0.84298E+00 -0.0742 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13887E-03 -3.8574 0.11639E-03 -3.9341 0.83810E+00 -0.0767 4 SO4-- 0.37952E-10 -10.4208 0.19976E-10 -10.6995 0.52634E+00 -0.2787 5 HCO3- 0.35493E-05 -5.4499 0.29788E-05 -5.5260 0.83928E+00 -0.0761 6 HS- 0.25776E-04 -4.5888 0.21606E-04 -4.6654 0.83822E+00 -0.0766 7 Al+++ 0.15354E-28 -28.8138 0.36581E-29 -29.4367 0.23825E+00 -0.6230 8 H4SiO4 0.70068E-03 -3.1545 0.70068E-03 -3.1545 0.10000E+01 0.0000 9 Ca++ 0.12334E-06 -6.9089 0.64462E-07 -7.1907 0.52263E+00 -0.2818 10 Mg++ 0.23642E-10 -10.6263 0.12302E-10 -10.9100 0.52033E+00 -0.2837 11 Fe++ 0.66991E-13 -13.1740 0.34895E-13 -13.4572 0.52088E+00 -0.2833 12 K+ 0.14946E-03 -3.8255 0.12547E-03 -3.9015 0.83947E+00 -0.0760 13 Na+ 0.19000E-01 -1.7212 0.15921E-01 -1.7980 0.83796E+00 -0.0768 14 Mn++ 0.18653E-10 -10.7293 0.97236E-11 -11.0122 0.52130E+00 -0.2829 15 HPO4-- 0.64610E-07 -7.1897 0.34011E-07 -7.4684 0.52641E+00 -0.2787 16 HSiO3- 0.10092E-01 -1.9960 0.84583E-02 -2.0727 0.83810E+00 -0.0767 17 Ca(HSiO3)+ 0.14549E-07 -7.8372 0.12216E-07 -7.9131 0.83964E+00 -0.0759 18 Mg(HSiO3)+ 0.34555E-11 -11.4615 0.29014E-11 -11.5374 0.83964E+00 -0.0759 19 NaHSiO3,aq 0.21388E-02 -2.6698 0.21388E-02 -2.6698 0.10000E+01 0.0000 20 AlO+ 0.86100E-16 -16.0650 0.72293E-16 -16.1409 0.83964E+00 -0.0759 22 HAlO2,aq 0.17899E-09 -9.7472 0.17899E-09 -9.7472 0.10000E+01 0.0000 23 AlO2- 0.59103E-05 -5.2284 0.49449E-05 -5.3058 0.83665E+00 -0.0775 24 CH4,aq 0.31720E-05 -5.4987 0.31616E-05 -5.5001 0.99670E+00 -0.0014 25 C2H6,aq 0.42700E-15 -15.3696 0.42559E-15 -15.3710 0.99670E+00 -0.0014 29 CO,aq 0.50639E-16 -16.2955 0.50639E-16 -16.2955 0.10000E+01 0.0000 30 CO2,aq 0.48702E-09 -9.3124 0.48542E-09 -9.3139 0.99670E+00 -0.0014 31 CO3-2 0.64875E-05 -5.1879 0.34077E-05 -5.4675 0.52527E+00 -0.2796 32 CaCO3,aq 0.26904E-08 -8.5702 0.26904E-08 -8.5702 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.57624E-11 -11.2394 0.48383E-11 -11.3153 0.83964E+00 -0.0759 34 CaCl+ 0.14238E-10 -10.8465 0.11955E-10 -10.9224 0.83964E+00 -0.0759 35 CaCl2,aq 0.32397E-15 -15.4895 0.32397E-15 -15.4895 0.10000E+01 0.0000 36 CaOH+ 0.66979E-07 -7.1741 0.56238E-07 -7.2500 0.83964E+00 -0.0759 37 CaSO4,aq 0.40121E-15 -15.3966 0.40121E-15 -15.3966 0.10000E+01 0.0000 38 HCl,aq 0.17694E-14 -14.7522 0.17694E-14 -14.7522 0.10000E+01 0.0000 43 FeCl+ 0.75335E-17 -17.1230 0.63254E-17 -17.1989 0.83964E+00 -0.0759 46 FeO,aq 0.21123E-09 -9.6752 0.21123E-09 -9.6752 0.10000E+01 0.0000 47 FeOH+ 0.17047E-10 -10.7684 0.14313E-10 -10.8443 0.83964E+00 -0.0759 48 HFeO2- 0.33541E-07 -7.4744 0.28111E-07 -7.5511 0.83810E+00 -0.0767 49 FeO+ 0.20612E-16 -16.6859 0.17307E-16 -16.7618 0.83964E+00 -0.0759 51 FeO2- 0.62129E-09 -9.2067 0.52071E-09 -9.2834 0.83810E+00 -0.0767 52 HFeO2,aq 0.52670E-11 -11.2784 0.52670E-11 -11.2784 0.10000E+01 0.0000 53 H2,aq 0.40638E-05 -5.3911 0.40504E-05 -5.3925 0.99670E+00 -0.0014 54 KCl,aq 0.25857E-09 -9.5874 0.25857E-09 -9.5874 0.10000E+01 0.0000 56 KOH,aq 0.67677E-06 -6.1696 0.67677E-06 -6.1696 0.10000E+01 0.0000 57 KSO4- 0.46073E-13 -13.3365 0.38614E-13 -13.4133 0.83810E+00 -0.0767 58 MgCO3,aq 0.12830E-12 -12.8918 0.12830E-12 -12.8918 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11214E-14 -14.9502 0.94157E-15 -15.0261 0.83964E+00 -0.0759 60 MgCl+ 0.24668E-14 -14.6079 0.20712E-14 -14.6838 0.83964E+00 -0.0759 61 MgOH+ 0.70814E-10 -10.1499 0.59459E-10 -10.2258 0.83964E+00 -0.0759 63 MnO,aq 0.15713E-08 -8.8037 0.15713E-08 -8.8037 0.10000E+01 0.0000 64 MnOH+ 0.44127E-09 -9.3553 0.37051E-09 -9.4312 0.83964E+00 -0.0759 65 MnO2-2 0.15837E-10 -10.8003 0.83187E-11 -11.0799 0.52527E+00 -0.2796 66 HMnO2- 0.17381E-09 -9.7599 0.14567E-09 -9.8366 0.83810E+00 -0.0767 69 MnCl+ 0.81573E-14 -14.0885 0.68492E-14 -14.1644 0.83964E+00 -0.0759 70 MnSO4,aq 0.55047E-19 -19.2593 0.55047E-19 -19.2593 0.10000E+01 0.0000 71 NaCl,aq 0.60505E-06 -6.2182 0.60505E-06 -6.2182 0.10000E+01 0.0000 72 NaOH,aq 0.86558E-04 -4.0627 0.86558E-04 -4.0627 0.10000E+01 0.0000 74 OH- 0.88705E-02 -2.0521 0.74215E-02 -2.1295 0.83665E+00 -0.0775 79 HPO3-2 0.82838E-15 -15.0818 0.43512E-15 -15.3614 0.52527E+00 -0.2796 81 H2PO3- 0.82426E-19 -19.0839 0.69082E-19 -19.1606 0.83810E+00 -0.0767 82 H3PO4,aq 0.14304E-17 -17.8446 0.14304E-17 -17.8446 0.10000E+01 0.0000 83 H2PO4- 0.57452E-10 -10.2407 0.48194E-10 -10.3170 0.83886E+00 -0.0763 84 PO4-3 0.14714E-08 -8.8323 0.36750E-09 -9.4347 0.24976E+00 -0.6025 88 HP2O7-3 0.19339E-17 -17.7136 0.46120E-18 -18.3361 0.23848E+00 -0.6225 89 P2O7-4 0.17304E-16 -16.7619 0.14077E-17 -17.8515 0.81352E-01 -1.0896 90 H2S,aq 0.52642E-08 -8.2787 0.52468E-08 -8.2801 0.99670E+00 -0.0014 91 S2-2 0.48259E-14 -14.3164 0.25349E-14 -14.5960 0.52527E+00 -0.2796 97 SO3-2 0.20715E-16 -16.6837 0.11032E-16 -16.9573 0.53257E+00 -0.2736 98 HSO3- 0.62260E-19 -19.2058 0.52181E-19 -19.2825 0.83810E+00 -0.0767 99 HSO4- 0.17825E-17 -17.7490 0.14980E-17 -17.8245 0.84043E+00 -0.0755 Charge balance for all species = -.7387E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9587888E-10 -.2122001E-01 -.2135303E+02 0.0000 2 H2O 0.1000000E+01 0.5550500E+02 0.9982809E+06 0.0000 3 Cl- 0.1388679E-03 0.1394732E-03 0.4936543E+01 6.1584 4 SO4-- 0.3795204E-10 -.4187876E-05 -.4016269E+00 9.4854 5 HCO3- 0.3549273E-05 0.1321200E-04 0.8048223E+00 4.5665 6 HS- 0.2577626E-04 0.2996944E-04 0.9895057E+00 5.4270 7 Al+++ 0.1535400E-28 0.5910475E-05 0.1592090E+00 0.8406 8 H4SiO4 0.7006765E-03 0.1293166E-01 0.1240870E+04 -3.1545 9 Ca++ 0.1233412E-06 0.2075797E-06 0.8305581E-02 12.9942 10 Mg++ 0.2364226E-10 0.9804407E-10 0.2379695E-05 9.2749 11 Fe++ 0.6699148E-13 0.3439621E-07 0.1917740E-02 6.7277 12 K+ 0.1494650E-03 0.1501420E-03 0.5861116E+01 6.1910 13 Na+ 0.1900008E-01 0.2122606E-01 0.4871737E+03 8.2944 14 Mn++ 0.1865268E-10 0.2220903E-08 0.1218097E-03 9.1727 15 HPO4-- 0.6460975E-07 0.6613861E-07 0.6337391E-02 12.7165 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1523354E+01 -.2099195E-01 -.1502362E+01 0.0000000E+00 2 H2O 0.5435500E+02 0.5490844E+02 -.5534379E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2575110E-02 -.4142865E-05 0.2579253E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2549606E-02 0.2964734E-04 -.2579253E-02 0.0000000E+00 7 Al+++ 0.2999850E+00 0.5846950E-05 0.2999791E+00 0.0000000E+00 8 H4SiO4 0.9579656E+00 0.1279267E-01 0.9451729E+00 0.0000000E+00 9 Ca++ 0.1058264E+00 0.2053486E-06 0.1058262E+00 0.0000000E+00 10 Mg++ 0.7301508E-01 0.9699032E-10 0.7301508E-01 0.0000000E+00 11 Fe++ 0.6559608E-01 0.3402653E-07 0.6559604E-01 0.0000000E+00 12 K+ 0.1953270E-01 0.1485283E-03 0.1938417E-01 0.0000000E+00 13 Na+ 0.1156412E+00 0.2099793E-01 0.9464330E-01 0.0000000E+00 14 Mn++ 0.1595133E-02 0.2197034E-08 0.1595131E-02 0.0000000E+00 15 HPO4-- 0.5444111E-03 0.6542777E-07 0.5443457E-03 0.0000000E+00 Chg. balance for solid moles: 0.1524E-15 Mass of aqueous solution: 0.990895E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 91.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9464E-01 -1.024 24.82 1.395 24.73 9.527 andradite 0.1032E-01 -1.986 5.243 0.720 5.224 1.362 grossular 0.1871E-02 -2.728 0.8428 -0.074 0.8397 0.2345 apatite-OH 0.1814E-03 -3.741 0.9115E-01 -1.040 0.9081E-01 0.2896E-01 clinochlore 0.1460E-01 -1.836 8.117 0.909 8.087 3.087 daphnite 0.4335E-02 -2.363 3.093 0.490 3.082 0.9373 chlorite-Mn 0.3190E-03 -3.496 0.2262 -0.646 0.2253 0.7208E-01 microcline 0.1706E-01 -1.768 4.747 0.676 4.730 1.854 stilbite 0.6835E-01 -1.165 48.17 1.683 47.99 22.47 stilpnomelane-Fe 0.4657E-02 -2.332 5.021 0.701 5.002 1.734 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8465E+00 0.8465E+00 1.0000 -0.072 grossular 0.1535E+00 0.1535E+00 1.0000 -0.814 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7583E+00 0.7583E+00 1.0000 -0.120 daphnite 0.2251E+00 0.2251E+00 1.0000 -0.648 chlorite-Mn 0.1657E-01 0.1657E-01 1.0000 -1.781 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 100.368969 g Volume = 41.305581 cm3 Porosity: -9.2752% V(tot) - V(min): -.35060E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 91.9990000 g log = 1.9638 Original solution: 1000.0103000 g Original solution / Rock added: 10.87 (Water/Rock Ratio), log = 1.0362 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0626 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9901E+00 0.9854 0.1037E+01 0.1052E+01 CO2,gas 0.5191E-07 1.0073 0.5556E-07 0.5516E-07 CH4,gas 0.4645E-02 1.0129 0.5000E-02 0.4936E-02 H2,gas 0.5225E-02 1.0006 0.5555E-02 0.5552E-02 H2S,gas 0.1446E-06 0.9959 0.1530E-06 0.1537E-06 S2,gas 0.2675E-28 1.0000 0.2842E-28 0.2842E-28 CO,gas 0.7525E-13 1.0000 0.7996E-13 0.7996E-13 SO3,gas 0.4591E-46 1.0000 0.4878E-46 0.4878E-46 SO2,gas 0.9649E-26 1.0000 0.1025E-25 0.1025E-25 HCl,gas 0.2940E-17 1.0000 0.3124E-17 0.3124E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.62 -9.26 -3.085 0.15803E+05 -7.255 3 CH4,gas 4.81 0.51 -4.30 -1.075 0.73439E+04 -2.301 4 H2,gas 8.29 4.03 -4.26 -2.432 0.72658E+04 -2.255 5 H2S,gas -5.94 -14.76 -8.82 -4.408 0.15052E+05 -6.815 6 S2,gas -7.03 -37.58 -30.55 -4.699 0.52157E+05 -28.546 7 CO,gas 3.51 -11.59 -15.10 -4.645 0.25778E+05 -13.097 8 SO3,gas 17.43 -30.88 -48.31 -12.078 0.82491E+05 -46.312 9 SO2,gas 1.14 -26.85 -27.99 -7.464 0.47791E+05 -25.989 10 HCl,gas 5.48 -14.03 -19.51 -9.753 0.33305E+05 -17.505 11 acmite 7.74 6.70 -1.04 -0.108 0.17759E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.74 -4.81 -0.241 0.82194E+04 20 analcite 3.37 2.83 -0.54 -0.061 0.92975E+03 26 annite 20.21 17.75 -2.46 -0.137 0.41971E+04 27 phlogopite 27.15 25.39 -1.75 -0.097 0.29944E+04 29 anorthite 12.80 8.37 -4.43 -0.341 0.75660E+04 35 aragonite 0.99 -2.62 -3.61 -1.203 0.61647E+04 36 brucite 12.58 9.27 -3.30 -0.660 0.56376E+04 37 calcite 0.83 -2.62 -3.46 -1.152 0.59033E+04 38 carnegieite-low 9.06 5.98 -3.08 -0.441 0.52658E+04 39 carnegieite-high 10.13 5.98 -4.15 -0.593 0.70926E+04 40 carpholite-Mg 8.65 4.65 -4.00 -0.267 0.68353E+04 41 carpholite-Fe 6.78 2.10 -4.68 -0.312 0.79959E+04 42 celadonite 5.40 3.69 -1.71 -0.101 0.29230E+04 43 celadonite-Fe 3.94 1.14 -2.80 -0.164 0.47733E+04 44 chrysotile 23.94 21.52 -2.42 -0.202 0.41348E+04 49 chlorite-Al-free 47.26 43.03 -4.23 -0.176 0.72230E+04 51 chloritoid-Fe 9.24 5.25 -3.98 -0.266 0.68029E+04 52 chloritoid-Mn 11.46 7.70 -3.76 -0.251 0.64263E+04 54 coesite -2.37 -3.15 -0.79 -0.262 0.13406E+04 61 cristobalite -2.55 -3.15 -0.61 -0.202 0.10335E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.84 -2.06 -0.343 0.35096E+04 66 diamond -3.11 -7.56 -4.45 -1.271 0.75946E+04 67 diopside 16.22 15.96 -0.26 -0.026 0.43594E+03 68 hedenbergite 14.24 13.41 -0.83 -0.083 0.14197E+04 73 clinoenstatite 17.20 12.24 -4.96 -0.496 0.84709E+04 75 epidote 24.78 22.92 -1.86 -0.090 0.31708E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66151E+04 77 epidote-Fe 29.94 26.79 -3.15 -0.164 0.53741E+04 78 fayalite 14.08 10.30 -3.78 -0.540 0.64510E+04 79 ferrosilite 11.19 7.15 -4.04 -0.404 0.69004E+04 83 gibbsite 4.10 0.84 -3.26 -0.465 0.55608E+04 84 glaucophane 23.11 20.86 -2.25 -0.061 0.38444E+04 85 glaucophane-Fe 17.42 13.22 -4.20 -0.114 0.71711E+04 86 graphite -3.55 -7.56 -4.01 -1.145 0.68408E+04 87 greenalite 16.19 13.87 -2.32 -0.193 0.39615E+04 90 hematite 12.60 9.42 -3.17 -0.385 0.54193E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.83 -1.42 -0.142 0.24328E+04 97 kalsilite 7.62 3.88 -3.74 -0.535 0.63912E+04 98 kaolinite -1.27 -4.63 -3.35 -0.305 0.57278E+04 101 laumontite 2.97 2.06 -0.92 -0.061 0.15657E+04 102 lawsonite 9.68 8.37 -1.31 -0.087 0.22399E+04 103 leucite 4.17 0.72 -3.44 -0.344 0.58822E+04 105 lizardite 23.29 21.52 -1.77 -0.148 0.30251E+04 107 magnetite 20.13 16.15 -3.98 -0.325 0.67981E+04 108 minnesotaite 10.46 7.57 -2.90 -0.170 0.49442E+04 112 manganosite 14.07 9.17 -4.90 -1.224 0.83584E+04 120 muscovite 2.68 -0.75 -3.43 -0.202 0.58561E+04 121 paragonite 4.34 1.35 -2.98 -0.176 0.50946E+04 122 nepheline 8.38 5.98 -2.40 -0.343 0.40937E+04 128 periclase-Fe 11.64 6.73 -4.91 -1.228 0.83862E+04 134 phlogopite-Na 29.73 27.50 -2.24 -0.124 0.38163E+04 136 prehnite 19.47 18.21 -1.26 -0.074 0.21515E+04 137 prehnite-Fe 22.59 22.08 -0.51 -0.031 0.86952E+03 138 pumpellyite-Fe 46.47 43.98 -2.49 -0.055 0.42510E+04 139 pumpellyite-Mg 49.19 46.53 -2.67 -0.059 0.45520E+04 143 pyrrhotite -4.24 -8.03 -3.79 -1.262 0.64656E+04 144 pyrrhotiteFe0.875 -6.00 -9.37 -3.37 -1.239 0.57543E+04 145 pyroxmangite 7.42 6.02 -1.40 -0.280 0.23866E+04 146 pyrophyllite -6.10 -10.94 -4.84 -0.302 0.82618E+04 147 quartz -2.98 -3.15 -0.17 -0.057 0.29451E+03 152 rhodonite 7.46 6.02 -1.44 -0.289 0.24659E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.92 -1.68 -0.050 0.28700E+04 171 talc 16.55 15.21 -1.35 -0.079 0.22993E+04 174 tephroite 18.11 15.19 -2.92 -0.417 0.49890E+04 178 tridymite -2.61 -3.15 -0.54 -0.180 0.92180E+03 179 tremolite 48.00 47.13 -0.88 -0.024 0.14959E+04 180 ferroactinolite 38.60 34.39 -4.21 -0.114 0.71807E+04 181 troilite-low -4.39 -8.03 -3.64 -1.212 0.62088E+04 187 wairakite 4.06 2.06 -2.00 -0.118 0.34165E+04 188 walstromite 11.53 9.84 -1.69 -0.338 0.28824E+04 189 wollastonite 10.48 9.84 -0.64 -0.128 0.10963E+04 190 pseudo-wollastonite 11.02 9.84 -1.18 -0.236 0.20149E+04 191 zoisite 22.96 19.05 -3.92 -0.178 0.66876E+04 192 akaganeite 7.77 4.71 -3.06 -0.661 0.52178E+04 199 chalcedony -2.79 -3.15 -0.36 -0.120 0.61483E+03 201 montmorillonite-Ca -2.21 -6.01 -3.80 -0.235 0.64803E+04 202 montmorillonite-K -2.16 -6.11 -3.95 -0.242 0.67434E+04 203 montmorillonite-Mg -2.40 -6.62 -4.22 -0.261 0.72078E+04 204 montmorillonite-Na -1.96 -5.42 -3.46 -0.212 0.59002E+04 205 nontronite-Ca 3.28 0.27 -3.01 -0.195 0.51419E+04 206 nontronite-H 2.60 -1.88 -4.47 -0.300 0.76350E+04 207 nontronite-K 3.40 0.17 -3.24 -0.208 0.55264E+04 208 nontronite-Mg 3.14 -0.35 -3.48 -0.226 0.59500E+04 209 nontronite-Na 3.58 0.86 -2.72 -0.175 0.46468E+04 224 tobermorite 9.84 7.67 -2.17 -0.592 0.37040E+04 230 alabandite -0.96 -5.59 -4.62 -1.541 0.78932E+04 233 boehmite 4.43 0.84 -3.59 -0.598 0.61280E+04 235 ferrous-oxide 9.82 6.73 -3.10 -0.774 0.52873E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.358 0.18350E+04 242 an20ab80 2.08 1.41 -0.67 -0.051 0.11416E+04 243 an25ab75 2.71 1.85 -0.86 -0.066 0.14749E+04 244 an30ab70 3.34 2.28 -1.06 -0.082 0.18165E+04 245 tr.625ac.25prg.125 45.31 44.92 -0.38 -0.010 0.65527E+03 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 91.9990000 g New total amount of reactant added: 95.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7370E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 16 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 95.9990000 Water: Moles liquid = 0.5489E+02 kg liquid = 0.9888E+00 Moles total = 0.5430E+02 kg total = 0.9783E+00 Activity = 1.0000 Stoichiometric ionic strength = .1107616E-01 Osmotic coef. = 0.9653 True ionic strength = .1960639E-01 Chg. balance for total moles = -.7370E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.94653E-10 -10.0239 0.79677E-10 -10.0987 0.84177E+00 -0.0748 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13892E-03 -3.8572 0.11625E-03 -3.9346 0.83682E+00 -0.0774 4 SO4-- 0.15035E-10 -10.8229 0.78663E-11 -11.1042 0.52320E+00 -0.2813 5 HCO3- 0.25780E-05 -5.5887 0.21604E-05 -5.6655 0.83801E+00 -0.0768 6 HS- 0.25788E-04 -4.5886 0.21583E-04 -4.6659 0.83693E+00 -0.0773 7 Al+++ 0.13758E-28 -28.8615 0.32333E-29 -29.4904 0.23502E+00 -0.6289 8 H4SiO4 0.71115E-03 -3.1480 0.71115E-03 -3.1480 0.10000E+01 0.0000 9 Ca++ 0.12771E-06 -6.8938 0.66338E-07 -7.1782 0.51945E+00 -0.2845 10 Mg++ 0.23790E-10 -10.6236 0.12302E-10 -10.9100 0.51712E+00 -0.2864 11 Fe++ 0.65827E-13 -13.1816 0.34077E-13 -13.4675 0.51768E+00 -0.2859 12 K+ 0.15298E-03 -3.8154 0.12823E-03 -3.8920 0.83820E+00 -0.0767 13 Na+ 0.19448E-01 -1.7111 0.16272E-01 -1.7886 0.83667E+00 -0.0774 14 Mn++ 0.18769E-10 -10.7266 0.97239E-11 -11.0122 0.51810E+00 -0.2856 15 HPO4-- 0.60793E-07 -7.2161 0.31811E-07 -7.4974 0.52328E+00 -0.2813 16 HSiO3- 0.10406E-01 -1.9827 0.87083E-02 -2.0601 0.83682E+00 -0.0774 17 Ca(HSiO3)+ 0.15438E-07 -7.8114 0.12943E-07 -7.8880 0.83838E+00 -0.0766 18 Mg(HSiO3)+ 0.35631E-11 -11.4482 0.29872E-11 -11.5247 0.83838E+00 -0.0766 19 NaHSiO3,aq 0.22505E-02 -2.6477 0.22505E-02 -2.6477 0.10000E+01 0.0000 20 AlO+ 0.78425E-16 -16.1055 0.65750E-16 -16.1821 0.83838E+00 -0.0766 22 HAlO2,aq 0.16513E-09 -9.7822 0.16513E-09 -9.7822 0.10000E+01 0.0000 23 AlO2- 0.55399E-05 -5.2565 0.46277E-05 -5.3346 0.83534E+00 -0.0781 24 CH4,aq 0.58360E-05 -5.2339 0.58163E-05 -5.2354 0.99662E+00 -0.0015 25 C2H6,aq 0.11411E-14 -14.9427 0.11372E-14 -14.9441 0.99662E+00 -0.0015 29 CO,aq 0.45854E-16 -16.3386 0.45854E-16 -16.3386 0.10000E+01 0.0000 30 CO2,aq 0.34823E-09 -9.4581 0.34705E-09 -9.4596 0.99662E+00 -0.0015 31 CO3-2 0.48015E-05 -5.3186 0.25070E-05 -5.6009 0.52212E+00 -0.2822 32 CaCO3,aq 0.20368E-08 -8.6910 0.20368E-08 -8.6910 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43072E-11 -11.3658 0.36111E-11 -11.4424 0.83838E+00 -0.0766 34 CaCl+ 0.14657E-10 -10.8339 0.12288E-10 -10.9105 0.83838E+00 -0.0766 35 CaCl2,aq 0.33261E-15 -15.4781 0.33261E-15 -15.4781 0.10000E+01 0.0000 36 CaOH+ 0.70026E-07 -7.1547 0.58708E-07 -7.2313 0.83838E+00 -0.0766 37 CaSO4,aq 0.16259E-15 -15.7889 0.16259E-15 -15.7889 0.10000E+01 0.0000 38 HCl,aq 0.17422E-14 -14.7589 0.17422E-14 -14.7589 0.10000E+01 0.0000 43 FeCl+ 0.73593E-17 -17.1332 0.61699E-17 -17.2097 0.83838E+00 -0.0766 46 FeO,aq 0.21227E-09 -9.6731 0.21227E-09 -9.6731 0.10000E+01 0.0000 47 FeOH+ 0.16912E-10 -10.7718 0.14179E-10 -10.8484 0.83838E+00 -0.0766 48 HFeO2- 0.34243E-07 -7.4654 0.28655E-07 -7.5428 0.83682E+00 -0.0774 49 FeO+ 0.18171E-16 -16.7406 0.15234E-16 -16.8172 0.83838E+00 -0.0766 51 FeO2- 0.56362E-09 -9.2490 0.47164E-09 -9.3264 0.83682E+00 -0.0774 52 HFeO2,aq 0.47030E-11 -11.3276 0.47030E-11 -11.3276 0.10000E+01 0.0000 53 H2,aq 0.51474E-05 -5.2884 0.51300E-05 -5.2899 0.99662E+00 -0.0015 54 KCl,aq 0.26395E-09 -9.5785 0.26395E-09 -9.5785 0.10000E+01 0.0000 56 KOH,aq 0.70162E-06 -6.1539 0.70162E-06 -6.1539 0.10000E+01 0.0000 57 KSO4- 0.18571E-13 -13.7312 0.15541E-13 -13.8085 0.83682E+00 -0.0774 58 MgCO3,aq 0.94388E-13 -13.0251 0.94388E-13 -13.0251 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.81453E-15 -15.0891 0.68289E-15 -15.1657 0.83838E+00 -0.0766 60 MgCl+ 0.24676E-14 -14.6077 0.20688E-14 -14.6843 0.83838E+00 -0.0766 61 MgOH+ 0.71945E-10 -10.1430 0.60317E-10 -10.2196 0.83838E+00 -0.0766 63 MnO,aq 0.16169E-08 -8.7913 0.16169E-08 -8.7913 0.10000E+01 0.0000 64 MnOH+ 0.44832E-09 -9.3484 0.37586E-09 -9.4250 0.83838E+00 -0.0766 65 MnO2-2 0.16871E-10 -10.7729 0.88085E-11 -11.0551 0.52212E+00 -0.2822 66 HMnO2- 0.18171E-09 -9.7406 0.15206E-09 -9.8180 0.83682E+00 -0.0774 69 MnCl+ 0.81602E-14 -14.0883 0.68414E-14 -14.1649 0.83838E+00 -0.0766 70 MnSO4,aq 0.21678E-19 -19.6640 0.21678E-19 -19.6640 0.10000E+01 0.0000 71 NaCl,aq 0.61763E-06 -6.2093 0.61763E-06 -6.2093 0.10000E+01 0.0000 72 NaOH,aq 0.89736E-04 -4.0470 0.89736E-04 -4.0470 0.10000E+01 0.0000 74 OH- 0.90123E-02 -2.0452 0.75284E-02 -2.1233 0.83534E+00 -0.0781 79 HPO3-2 0.98723E-15 -15.0056 0.51545E-15 -15.2878 0.52212E+00 -0.2822 81 H2PO3- 0.96405E-19 -19.0159 0.80673E-19 -19.0933 0.83682E+00 -0.0774 82 H3PO4,aq 0.13001E-17 -17.8860 0.13001E-17 -17.8860 0.10000E+01 0.0000 83 H2PO4- 0.53054E-10 -10.2753 0.44437E-10 -10.3523 0.83759E+00 -0.0770 84 PO4-3 0.14140E-08 -8.8495 0.34868E-09 -9.4576 0.24658E+00 -0.6080 88 HP2O7-3 0.16907E-17 -17.7719 0.39774E-18 -18.4004 0.23525E+00 -0.6285 89 P2O7-4 0.15502E-16 -16.8096 0.12315E-17 -17.9096 0.79439E-01 -1.1000 90 H2S,aq 0.51843E-08 -8.2853 0.51668E-08 -8.2868 0.99662E+00 -0.0015 91 S2-2 0.38250E-14 -14.4174 0.19971E-14 -14.6996 0.52212E+00 -0.2822 97 SO3-2 0.10391E-16 -16.9833 0.55022E-17 -17.2595 0.52951E+00 -0.2761 98 HSO3- 0.30659E-19 -19.5134 0.25656E-19 -19.5908 0.83682E+00 -0.0774 99 HSO4- 0.69299E-18 -18.1593 0.58155E-18 -18.2354 0.83918E+00 -0.0761 Charge balance for all species = -.7404E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9465340E-10 -.2178819E-01 -.2192369E+02 0.0000 2 H2O 0.1000000E+01 0.5550472E+02 0.9982269E+06 0.0000 3 Cl- 0.1389173E-03 0.1395353E-03 0.4938497E+01 6.1641 4 SO4-- 0.1503488E-10 -.7122760E-05 -.6830555E+00 9.0931 5 HCO3- 0.2577963E-05 0.1321788E-04 0.8051408E+00 4.4332 6 HS- 0.2578784E-04 0.3291579E-04 0.1086733E+01 5.4328 7 Al+++ 0.1375771E-28 0.5540093E-05 0.1492248E+00 0.8057 8 H4SiO4 0.7111521E-03 0.1336816E-01 0.1282692E+04 -3.1480 9 Ca++ 0.1277088E-06 0.2152287E-06 0.8611208E-02 13.0191 10 Mg++ 0.2378992E-10 0.9939523E-10 0.2412371E-05 9.2873 11 Fe++ 0.6582706E-13 0.3504087E-07 0.1953586E-02 6.7298 12 K+ 0.1529839E-03 0.1536858E-03 0.5999162E+01 6.2067 13 Na+ 0.1944807E-01 0.2178892E-01 0.5000677E+03 8.3101 14 Mn++ 0.1876854E-10 0.2282621E-08 0.1251885E-03 9.1852 15 HPO4-- 0.6079274E-07 0.6225984E-07 0.5965435E-02 12.6999 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1589588E+01 -.2154443E-01 -.1568043E+01 0.0000000E+00 2 H2O 0.5430486E+02 0.5488375E+02 -.5788847E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2685964E-02 -.7043073E-05 0.2693007E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2660460E-02 0.3254754E-04 -.2693007E-02 0.0000000E+00 7 Al+++ 0.3130279E+00 0.5478112E-05 0.3130225E+00 0.0000000E+00 8 H4SiO4 0.9996168E+00 0.1321860E-01 0.9863982E+00 0.0000000E+00 9 Ca++ 0.1104270E+00 0.2128208E-06 0.1104268E+00 0.0000000E+00 10 Mg++ 0.7618968E-01 0.9828323E-10 0.7618968E-01 0.0000000E+00 11 Fe++ 0.6844811E-01 0.3464884E-07 0.6844808E-01 0.0000000E+00 12 K+ 0.2038195E-01 0.1519664E-03 0.2022999E-01 0.0000000E+00 13 Na+ 0.1206622E+00 0.2154516E-01 0.9911705E-01 0.0000000E+00 14 Mn++ 0.1664488E-02 0.2257084E-08 0.1664486E-02 0.0000000E+00 15 HPO4-- 0.5680814E-03 0.6156330E-07 0.5680199E-03 0.0000000E+00 Chg. balance for solid moles: -.2301E-15 Mass of aqueous solution: 0.990503E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 95.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9912E-01 -1.004 25.99 1.415 24.82 9.977 andradite 0.1077E-01 -1.968 5.474 0.738 5.227 1.422 grossular 0.2019E-02 -2.695 0.9093 -0.041 0.8682 0.2530 apatite-OH 0.1893E-03 -3.723 0.9511E-01 -1.022 0.9081E-01 0.3022E-01 clinochlore 0.1524E-01 -1.817 8.470 0.928 8.087 3.222 daphnite 0.4417E-02 -2.355 3.152 0.499 3.010 0.9551 chlorite-Mn 0.3329E-03 -3.478 0.2360 -0.627 0.2254 0.7521E-01 microcline 0.1775E-01 -1.751 4.940 0.694 4.717 1.930 stilbite 0.7111E-01 -1.148 50.11 1.700 47.85 23.37 stilpnomelane-Fe 0.4963E-02 -2.304 5.350 0.728 5.109 1.848 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8422E+00 0.8422E+00 1.0000 -0.075 grossular 0.1578E+00 0.1578E+00 1.0000 -0.802 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7623E+00 0.7623E+00 1.0000 -0.118 daphnite 0.2210E+00 0.2210E+00 1.0000 -0.656 chlorite-Mn 0.1665E-01 0.1665E-01 1.0000 -1.778 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 104.728568 g Volume = 43.085334 cm3 Porosity: -9.3547% V(tot) - V(min): -.36857E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 95.9990000 g log = 1.9823 Original solution: 1000.0103000 g Original solution / Rock added: 10.42 (Water/Rock Ratio), log = 1.0177 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0683 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9849E+00 0.9853 0.1037E+01 0.1052E+01 CO2,gas 0.3692E-07 1.0072 0.3973E-07 0.3944E-07 CH4,gas 0.8500E-02 1.0129 0.9198E-02 0.9081E-02 H2,gas 0.6583E-02 1.0006 0.7036E-02 0.7032E-02 H2S,gas 0.1416E-06 0.9959 0.1507E-06 0.1513E-06 S2,gas 0.1608E-28 1.0000 0.1718E-28 0.1718E-28 CO,gas 0.6778E-13 1.0000 0.7240E-13 0.7240E-13 SO3,gas 0.1748E-46 1.0000 0.1867E-46 0.1867E-46 SO2,gas 0.4652E-26 1.0000 0.4969E-26 0.4969E-26 HCl,gas 0.2880E-17 1.0000 0.3076E-17 0.3076E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.76 -9.40 -3.134 0.16052E+05 -7.401 3 CH4,gas 4.81 0.77 -4.04 -1.009 0.68919E+04 -2.036 4 H2,gas 8.29 4.13 -4.15 -2.373 0.70906E+04 -2.153 5 H2S,gas -5.94 -14.76 -8.82 -4.411 0.15063E+05 -6.822 6 S2,gas -7.03 -37.80 -30.76 -4.733 0.52530E+05 -28.765 7 CO,gas 3.51 -11.63 -15.14 -4.659 0.25852E+05 -13.140 8 SO3,gas 17.43 -31.30 -48.73 -12.182 0.83203E+05 -46.729 9 SO2,gas 1.14 -27.17 -28.30 -7.548 0.48328E+05 -26.304 10 HCl,gas 5.48 -14.03 -19.51 -9.756 0.33316E+05 -17.512 11 acmite 7.74 6.68 -1.06 -0.110 0.18111E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.72 -4.83 -0.241 0.82422E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94075E+03 26 annite 20.21 17.76 -2.45 -0.136 0.41862E+04 27 phlogopite 27.15 25.43 -1.72 -0.095 0.29307E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76210E+04 35 aragonite 0.99 -2.75 -3.73 -1.244 0.63710E+04 36 brucite 12.58 9.29 -3.29 -0.658 0.56163E+04 37 calcite 0.83 -2.75 -3.58 -1.193 0.61097E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52878E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71146E+04 40 carpholite-Mg 8.65 4.60 -4.05 -0.270 0.69115E+04 41 carpholite-Fe 6.78 2.05 -4.74 -0.316 0.80898E+04 42 celadonite 5.40 3.71 -1.69 -0.100 0.28908E+04 43 celadonite-Fe 3.94 1.15 -2.79 -0.164 0.47587E+04 44 chrysotile 23.94 21.57 -2.37 -0.198 0.40492E+04 49 chlorite-Al-free 47.26 43.13 -4.13 -0.172 0.70516E+04 51 chloritoid-Fe 9.24 5.19 -4.05 -0.270 0.69078E+04 52 chloritoid-Mn 11.46 7.65 -3.81 -0.254 0.65136E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13296E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10225E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.81 -2.09 -0.348 0.35694E+04 66 diamond -3.11 -7.50 -4.39 -1.254 0.74930E+04 67 diopside 16.22 16.01 -0.21 -0.021 0.35023E+03 68 hedenbergite 14.24 13.45 -0.79 -0.079 0.13516E+04 73 clinoenstatite 17.20 12.28 -4.92 -0.492 0.84064E+04 75 epidote 24.78 22.87 -1.91 -0.092 0.32564E+04 76 clinozoisite 22.92 19.01 -3.91 -0.178 0.66764E+04 77 epidote-Fe 29.94 26.73 -3.21 -0.167 0.54838E+04 78 fayalite 14.08 10.31 -3.77 -0.538 0.64327E+04 79 ferrosilite 11.19 7.16 -4.02 -0.402 0.68711E+04 83 gibbsite 4.10 0.81 -3.29 -0.470 0.56205E+04 84 glaucophane 23.11 20.91 -2.20 -0.059 0.37587E+04 85 glaucophane-Fe 17.42 13.24 -4.18 -0.113 0.71382E+04 86 graphite -3.55 -7.50 -3.95 -1.128 0.67392E+04 87 greenalite 16.19 13.89 -2.30 -0.192 0.39287E+04 90 hematite 12.60 9.33 -3.27 -0.397 0.55873E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24438E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64132E+04 98 kaolinite -1.27 -4.68 -3.41 -0.310 0.58253E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15987E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22949E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58932E+04 105 lizardite 23.29 21.57 -1.72 -0.143 0.29394E+04 107 magnetite 20.13 16.06 -4.08 -0.333 0.69624E+04 108 minnesotaite 10.46 7.60 -2.86 -0.168 0.48893E+04 112 manganosite 14.07 9.19 -4.88 -1.221 0.83372E+04 120 muscovite 2.68 -0.82 -3.50 -0.206 0.59756E+04 121 paragonite 4.34 1.28 -3.05 -0.180 0.52141E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41157E+04 128 periclase-Fe 11.64 6.73 -4.91 -1.227 0.83826E+04 134 phlogopite-Na 29.73 27.53 -2.20 -0.122 0.37526E+04 136 prehnite 19.47 18.21 -1.26 -0.074 0.21530E+04 137 prehnite-Fe 22.59 22.06 -0.52 -0.032 0.89530E+03 138 pumpellyite-Fe 46.47 43.95 -2.52 -0.056 0.43102E+04 139 pumpellyite-Mg 49.19 46.50 -2.69 -0.060 0.45936E+04 143 pyrrhotite -4.24 -8.03 -3.79 -1.264 0.64734E+04 144 pyrrhotiteFe0.875 -6.00 -9.39 -3.39 -1.246 0.57843E+04 145 pyroxmangite 7.42 6.04 -1.38 -0.276 0.23544E+04 146 pyrophyllite -6.10 -10.98 -4.88 -0.305 0.83373E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28351E+03 152 rhodonite 7.46 6.04 -1.43 -0.285 0.24337E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.97 -1.63 -0.049 0.27820E+04 171 talc 16.55 15.27 -1.28 -0.076 0.21916E+04 174 tephroite 18.11 15.22 -2.89 -0.413 0.49356E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91080E+03 179 tremolite 48.00 47.29 -0.71 -0.019 0.12168E+04 180 ferroactinolite 38.60 34.50 -4.09 -0.111 0.69897E+04 181 troilite-low -4.39 -8.03 -3.64 -1.214 0.62166E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34495E+04 188 walstromite 11.53 9.87 -1.66 -0.331 0.28290E+04 189 wollastonite 10.48 9.87 -0.61 -0.122 0.10428E+04 190 pseudo-wollastonite 11.02 9.87 -1.15 -0.230 0.19615E+04 191 zoisite 22.96 19.01 -3.95 -0.180 0.67489E+04 192 akaganeite 7.77 4.66 -3.11 -0.671 0.53018E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60382E+03 201 montmorillonite-Ca -2.21 -6.03 -3.82 -0.236 0.65221E+04 202 montmorillonite-K -2.16 -6.13 -3.97 -0.243 0.67833E+04 203 montmorillonite-Mg -2.40 -6.65 -4.25 -0.263 0.72531E+04 204 montmorillonite-Na -1.96 -5.44 -3.48 -0.213 0.59402E+04 205 nontronite-Ca 3.28 0.19 -3.09 -0.201 0.52822E+04 206 nontronite-H 2.60 -1.96 -4.56 -0.305 0.77823E+04 207 nontronite-K 3.40 0.09 -3.32 -0.213 0.56649E+04 208 nontronite-Mg 3.14 -0.43 -3.57 -0.232 0.60938E+04 209 nontronite-Na 3.58 0.78 -2.80 -0.180 0.47853E+04 224 tobermorite 9.84 7.70 -2.14 -0.584 0.36576E+04 230 alabandite -0.96 -5.58 -4.62 -1.539 0.78834E+04 233 boehmite 4.43 0.81 -3.62 -0.604 0.61878E+04 235 ferrous-oxide 9.82 6.73 -3.09 -0.774 0.52836E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18240E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11526E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14886E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18331E+04 245 tr.625ac.25prg.125 45.31 45.06 -0.25 -0.007 0.42264E+03 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 95.9990000 g New total amount of reactant added: 99.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7352E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 99.9990000 Water: Moles liquid = 0.5486E+02 kg liquid = 0.9884E+00 Moles total = 0.5425E+02 kg total = 0.9774E+00 Activity = 1.0000 Stoichiometric ionic strength = .1134801E-01 Osmotic coef. = 0.9666 True ionic strength = .2004516E-01 Chg. balance for total moles = -.7352E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93521E-10 -10.0291 0.78615E-10 -10.1045 0.84062E+00 -0.0754 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13897E-03 -3.8571 0.11612E-03 -3.9351 0.83558E+00 -0.0780 4 SO4-- 0.62669E-11 -11.2030 0.32601E-11 -11.4868 0.52021E+00 -0.2838 5 HCO3- 0.15844E-05 -5.8001 0.13258E-05 -5.8775 0.83679E+00 -0.0774 6 HS- 0.25799E-04 -4.5884 0.21561E-04 -4.6663 0.83570E+00 -0.0779 7 Al+++ 0.12391E-28 -28.9069 0.28740E-29 -29.5415 0.23195E+00 -0.6346 8 H4SiO4 0.72152E-03 -3.1418 0.72152E-03 -3.1418 0.10000E+01 0.0000 9 Ca++ 0.13198E-06 -6.8795 0.68155E-07 -7.1665 0.51640E+00 -0.2870 10 Mg++ 0.23945E-10 -10.6208 0.12309E-10 -10.9098 0.51405E+00 -0.2890 11 Fe++ 0.64755E-13 -13.1887 0.33324E-13 -13.4772 0.51461E+00 -0.2885 12 K+ 0.15642E-03 -3.8057 0.13092E-03 -3.8830 0.83699E+00 -0.0773 13 Na+ 0.19885E-01 -1.7015 0.16613E-01 -1.7796 0.83543E+00 -0.0781 14 Mn++ 0.18890E-10 -10.7238 0.97292E-11 -11.0119 0.51504E+00 -0.2882 15 HPO4-- 0.57415E-07 -7.2410 0.29872E-07 -7.5247 0.52028E+00 -0.2838 16 HSiO3- 0.10717E-01 -1.9699 0.89545E-02 -2.0480 0.83558E+00 -0.0780 17 Ca(HSiO3)+ 0.16333E-07 -7.7869 0.13674E-07 -7.8641 0.83717E+00 -0.0772 18 Mg(HSiO3)+ 0.36711E-11 -11.4352 0.30734E-11 -11.5124 0.83717E+00 -0.0772 19 NaHSiO3,aq 0.23626E-02 -2.6266 0.23626E-02 -2.6266 0.10000E+01 0.0000 20 AlO+ 0.71709E-16 -16.1444 0.60032E-16 -16.2216 0.83717E+00 -0.0772 22 HAlO2,aq 0.15281E-09 -9.8159 0.15281E-09 -9.8159 0.10000E+01 0.0000 23 AlO2- 0.52035E-05 -5.2837 0.43401E-05 -5.3625 0.83408E+00 -0.0788 24 CH4,aq 0.86340E-05 -5.0638 0.86041E-05 -5.0653 0.99654E+00 -0.0015 25 C2H6,aq 0.19976E-14 -14.6995 0.19907E-14 -14.7010 0.99654E+00 -0.0015 29 CO,aq 0.34713E-16 -16.4595 0.34713E-16 -16.4595 0.10000E+01 0.0000 30 CO2,aq 0.21088E-09 -9.6760 0.21015E-09 -9.6775 0.99654E+00 -0.0015 31 CO3-2 0.30038E-05 -5.5223 0.15593E-05 -5.8071 0.51911E+00 -0.2847 32 CaCO3,aq 0.13016E-08 -8.8855 0.13016E-08 -8.8855 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.27197E-11 -11.5655 0.22769E-11 -11.6427 0.83717E+00 -0.0772 34 CaCl+ 0.15064E-10 -10.8221 0.12611E-10 -10.8993 0.83717E+00 -0.0772 35 CaCl2,aq 0.34095E-15 -15.4673 0.34095E-15 -15.4673 0.10000E+01 0.0000 36 CaOH+ 0.73020E-07 -7.1366 0.61130E-07 -7.2137 0.83717E+00 -0.0772 37 CaSO4,aq 0.69229E-16 -16.1597 0.69229E-16 -16.1597 0.10000E+01 0.0000 38 HCl,aq 0.17171E-14 -14.7652 0.17171E-14 -14.7652 0.10000E+01 0.0000 43 FeCl+ 0.71990E-17 -17.1427 0.60268E-17 -17.2199 0.83717E+00 -0.0772 46 FeO,aq 0.21322E-09 -9.6712 0.21322E-09 -9.6712 0.10000E+01 0.0000 47 FeOH+ 0.16786E-10 -10.7751 0.14053E-10 -10.8522 0.83717E+00 -0.0772 48 HFeO2- 0.34912E-07 -7.4570 0.29172E-07 -7.5350 0.83558E+00 -0.0780 49 FeO+ 0.16130E-16 -16.7924 0.13503E-16 -16.8696 0.83717E+00 -0.0772 51 FeO2- 0.51392E-09 -9.2891 0.42942E-09 -9.3671 0.83558E+00 -0.0780 52 HFeO2,aq 0.42250E-11 -11.3742 0.42250E-11 -11.3742 0.10000E+01 0.0000 53 H2,aq 0.64358E-05 -5.1914 0.64135E-05 -5.1929 0.99654E+00 -0.0015 54 KCl,aq 0.26918E-09 -9.5700 0.26918E-09 -9.5700 0.10000E+01 0.0000 56 KOH,aq 0.72599E-06 -6.1391 0.72599E-06 -6.1391 0.10000E+01 0.0000 57 KSO4- 0.78695E-14 -14.1041 0.65756E-14 -14.1821 0.83558E+00 -0.0780 58 MgCO3,aq 0.58741E-13 -13.2311 0.58741E-13 -13.2311 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.50088E-15 -15.3003 0.41932E-15 -15.3775 0.83717E+00 -0.0772 60 MgCl+ 0.24698E-14 -14.6073 0.20676E-14 -14.6845 0.83717E+00 -0.0772 61 MgOH+ 0.73061E-10 -10.1363 0.61164E-10 -10.2135 0.83717E+00 -0.0772 63 MnO,aq 0.16618E-08 -8.7794 0.16618E-08 -8.7794 0.10000E+01 0.0000 64 MnOH+ 0.45527E-09 -9.3417 0.38114E-09 -9.4189 0.83717E+00 -0.0772 65 MnO2-2 0.17913E-10 -10.7468 0.92989E-11 -11.0316 0.51911E+00 -0.2847 66 HMnO2- 0.18955E-09 -9.7223 0.15839E-09 -9.8003 0.83558E+00 -0.0780 69 MnCl+ 0.81674E-14 -14.0879 0.68375E-14 -14.1651 0.83717E+00 -0.0772 71 NaCl,aq 0.62988E-06 -6.2007 0.62988E-06 -6.2007 0.10000E+01 0.0000 72 NaOH,aq 0.92853E-04 -4.0322 0.92853E-04 -4.0322 0.10000E+01 0.0000 74 OH- 0.91477E-02 -2.0387 0.76300E-02 -2.1175 0.83408E+00 -0.0788 79 HPO3-2 0.11657E-14 -14.9334 0.60512E-15 -15.2182 0.51911E+00 -0.2847 81 H2PO3- 0.11183E-18 -18.9514 0.93447E-19 -19.0294 0.83558E+00 -0.0780 82 H3PO4,aq 0.11886E-17 -17.9250 0.11886E-17 -17.9250 0.10000E+01 0.0000 83 H2PO4- 0.49227E-10 -10.3078 0.41172E-10 -10.3854 0.83637E+00 -0.0776 84 PO4-3 0.13624E-08 -8.8657 0.33184E-09 -9.4791 0.24357E+00 -0.6134 88 HP2O7-3 0.14904E-17 -17.8267 0.34604E-18 -18.4609 0.23218E+00 -0.6342 89 P2O7-4 0.13986E-16 -16.8543 0.10859E-17 -17.9642 0.77643E-01 -1.1099 90 H2S,aq 0.51104E-08 -8.2915 0.50927E-08 -8.2931 0.99654E+00 -0.0015 91 S2-2 0.30709E-14 -14.5127 0.15941E-14 -14.7975 0.51911E+00 -0.2847 97 SO3-2 0.54139E-17 -17.2665 0.28509E-17 -17.5450 0.52659E+00 -0.2785 98 HSO3- 0.15697E-19 -19.8042 0.13116E-19 -19.8822 0.83558E+00 -0.0780 99 HSO4- 0.28378E-18 -18.5470 0.23780E-18 -18.6238 0.83798E+00 -0.0768 Charge balance for all species = -.7474E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9352120E-10 -.2234608E-01 -.2248396E+02 0.0000 2 H2O 0.1000000E+01 0.5550444E+02 0.9981734E+06 0.0000 3 Cl- 0.1389671E-03 0.1395973E-03 0.4940452E+01 6.1694 4 SO4-- 0.6266858E-11 -.1024287E-04 -.9822188E+00 8.7222 5 HCO3- 0.1584420E-05 0.1322375E-04 0.8054595E+00 4.2270 6 HS- 0.2579938E-04 0.3604737E-04 0.1190065E+01 5.4382 7 Al+++ 0.1239083E-28 0.5203635E-05 0.1401553E+00 0.7720 8 H4SiO4 0.7215182E-03 0.1380067E-01 0.1324128E+04 -3.1418 9 Ca++ 0.1319793E-06 0.2226521E-06 0.8907782E-02 13.0425 10 Mg++ 0.2394499E-10 0.1007388E-09 0.2444861E-05 9.2992 11 Fe++ 0.6475466E-13 0.3566027E-07 0.1988022E-02 6.7317 12 K+ 0.1564173E-03 0.1571435E-03 0.6133838E+01 6.2215 13 Na+ 0.1988519E-01 0.2234130E-01 0.5127203E+03 8.3249 14 Mn++ 0.1889026E-10 0.2343435E-08 0.1285176E-03 9.1971 15 HPO4-- 0.5741454E-07 0.5882617E-07 0.5636163E-02 12.6842 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1655822E+01 -.2208626E-01 -.1633736E+01 0.0000000E+00 2 H2O 0.5425472E+02 0.5485909E+02 -.6043721E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2796818E-02 -.1012378E-04 0.2806941E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2771313E-02 0.3562825E-04 -.2806941E-02 0.0000000E+00 7 Al+++ 0.3260709E+00 0.5143132E-05 0.3260658E+00 0.0000000E+00 8 H4SiO4 0.1041268E+01 0.1364021E-01 0.1027628E+01 0.0000000E+00 9 Ca++ 0.1150276E+00 0.2200633E-06 0.1150274E+00 0.0000000E+00 10 Mg++ 0.7936429E-01 0.9956749E-10 0.7936429E-01 0.0000000E+00 11 Fe++ 0.7130015E-01 0.3524565E-07 0.7130011E-01 0.0000000E+00 12 K+ 0.2123121E-01 0.1553165E-03 0.2107589E-01 0.0000000E+00 13 Na+ 0.1256832E+00 0.2208154E-01 0.1036016E+00 0.0000000E+00 14 Mn++ 0.1733842E-02 0.2316188E-08 0.1733840E-02 0.0000000E+00 15 HPO4-- 0.5917517E-03 0.5814220E-07 0.5916936E-03 0.0000000E+00 Chg. balance for solid moles: 0.2622E-15 Mass of aqueous solution: 0.990112E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 99.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1036 -0.985 27.17 1.434 24.90 10.43 andradite 0.1123E-01 -1.950 5.706 0.756 5.230 1.482 grossular 0.2167E-02 -2.664 0.9762 -0.010 0.8949 0.2716 apatite-OH 0.1972E-03 -3.705 0.9907E-01 -1.004 0.9082E-01 0.3148E-01 clinochlore 0.1587E-01 -1.799 8.823 0.946 8.088 3.356 daphnite 0.4497E-02 -2.347 3.209 0.506 2.942 0.9724 chlorite-Mn 0.3468E-03 -3.460 0.2458 -0.609 0.2254 0.7835E-01 microcline 0.1844E-01 -1.734 5.133 0.710 4.705 2.005 stilbite 0.7386E-01 -1.132 52.05 1.716 47.71 24.28 stilpnomelane-Fe 0.5272E-02 -2.278 5.683 0.755 5.209 1.963 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8382E+00 0.8382E+00 1.0000 -0.077 grossular 0.1618E+00 0.1618E+00 1.0000 -0.791 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7662E+00 0.7662E+00 1.0000 -0.116 daphnite 0.2171E+00 0.2171E+00 1.0000 -0.663 chlorite-Mn 0.1674E-01 0.1674E-01 1.0000 -1.776 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 109.088103 g Volume = 44.864666 cm3 Porosity: -9.4271% V(tot) - V(min): -.38651E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 99.9990000 g log = 2.0000 Original solution: 1000.0103000 g Original solution / Rock added: 10.00 (Water/Rock Ratio), log = 1.0000 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0745 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9793E+00 0.9852 0.1037E+01 0.1052E+01 CO2,gas 0.2223E-07 1.0072 0.2406E-07 0.2388E-07 CH4,gas 0.1250E-01 1.0128 0.1361E-01 0.1343E-01 H2,gas 0.8182E-02 1.0006 0.8797E-02 0.8792E-02 H2S,gas 0.1388E-06 0.9958 0.1485E-06 0.1492E-06 S2,gas 0.9939E-29 1.0000 0.1068E-28 0.1068E-28 CO,gas 0.5101E-13 1.0000 0.5481E-13 0.5481E-13 SO3,gas 0.7010E-47 1.0000 0.7533E-47 0.7533E-47 SO2,gas 0.2333E-26 1.0000 0.2507E-26 0.2507E-26 HCl,gas 0.2822E-17 1.0000 0.3032E-17 0.3032E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.98 -9.62 -3.206 0.16424E+05 -7.619 3 CH4,gas 4.81 0.94 -3.87 -0.967 0.66015E+04 -1.866 4 H2,gas 8.29 4.23 -4.06 -2.318 0.69250E+04 -2.056 5 H2S,gas -5.94 -14.77 -8.83 -4.414 0.15074E+05 -6.828 6 S2,gas -7.03 -38.00 -30.97 -4.765 0.52883E+05 -28.971 7 CO,gas 3.51 -11.75 -15.26 -4.696 0.26058E+05 -13.261 8 SO3,gas 17.43 -31.70 -49.12 -12.281 0.83876E+05 -47.123 9 SO2,gas 1.14 -27.46 -28.60 -7.627 0.48835E+05 -26.601 10 HCl,gas 5.48 -14.04 -19.52 -9.759 0.33327E+05 -17.518 11 acmite 7.74 6.66 -1.08 -0.112 0.18438E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.71 -4.84 -0.242 0.82642E+04 20 analcite 3.37 2.81 -0.56 -0.062 0.95148E+03 26 annite 20.21 17.76 -2.45 -0.136 0.41763E+04 27 phlogopite 27.15 25.47 -1.68 -0.093 0.28699E+04 29 anorthite 12.80 8.30 -4.49 -0.346 0.76747E+04 35 aragonite 0.99 -2.94 -3.93 -1.309 0.67031E+04 36 brucite 12.58 9.30 -3.28 -0.655 0.55961E+04 37 calcite 0.83 -2.94 -3.77 -1.258 0.64418E+04 38 carnegieite-low 9.06 5.96 -3.11 -0.444 0.53092E+04 39 carnegieite-high 10.13 5.96 -4.18 -0.597 0.71361E+04 40 carpholite-Mg 8.65 4.56 -4.09 -0.273 0.69848E+04 41 carpholite-Fe 6.78 1.99 -4.79 -0.319 0.81800E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28597E+04 43 celadonite-Fe 3.94 1.16 -2.78 -0.163 0.47446E+04 44 chrysotile 23.94 21.61 -2.32 -0.194 0.39668E+04 49 chlorite-Al-free 47.26 43.23 -4.03 -0.168 0.68870E+04 51 chloritoid-Fe 9.24 5.13 -4.10 -0.274 0.70088E+04 52 chloritoid-Mn 11.46 7.60 -3.86 -0.258 0.65976E+04 54 coesite -2.37 -3.14 -0.77 -0.257 0.13189E+04 61 cristobalite -2.55 -3.14 -0.59 -0.198 0.10117E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.77 -2.12 -0.354 0.36269E+04 66 diamond -3.11 -7.52 -4.41 -1.261 0.75338E+04 67 diopside 16.22 16.06 -0.16 -0.016 0.26856E+03 68 hedenbergite 14.24 13.49 -0.75 -0.075 0.12869E+04 71 enstatite 17.30 12.31 -4.99 -0.499 0.85136E+04 73 clinoenstatite 17.20 12.31 -4.89 -0.489 0.83444E+04 75 epidote 24.78 22.82 -1.96 -0.095 0.33389E+04 76 clinozoisite 22.92 18.98 -3.95 -0.179 0.67369E+04 77 epidote-Fe 29.94 26.66 -3.27 -0.170 0.55883E+04 78 fayalite 14.08 10.32 -3.76 -0.537 0.64154E+04 79 ferrosilite 11.19 7.18 -4.01 -0.401 0.68431E+04 83 gibbsite 4.10 0.77 -3.33 -0.475 0.56781E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36764E+04 85 glaucophane-Fe 17.42 13.25 -4.16 -0.112 0.71068E+04 86 graphite -3.55 -7.52 -3.97 -1.135 0.67800E+04 87 greenalite 16.19 13.91 -2.28 -0.190 0.38973E+04 90 hematite 12.60 9.23 -3.37 -0.408 0.57463E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.81 -1.44 -0.144 0.24545E+04 97 kalsilite 7.62 3.85 -3.77 -0.538 0.64347E+04 98 kaolinite -1.27 -4.74 -3.47 -0.315 0.59188E+04 101 laumontite 2.97 2.02 -0.96 -0.064 0.16309E+04 102 lawsonite 9.68 8.30 -1.38 -0.092 0.23486E+04 103 leucite 4.17 0.71 -3.46 -0.346 0.59039E+04 105 lizardite 23.29 21.61 -1.67 -0.139 0.28571E+04 107 magnetite 20.13 15.96 -4.17 -0.340 0.71181E+04 108 minnesotaite 10.46 7.63 -2.83 -0.167 0.48365E+04 112 manganosite 14.07 9.20 -4.87 -1.218 0.83169E+04 120 muscovite 2.68 -0.89 -3.57 -0.210 0.60907E+04 121 paragonite 4.34 1.22 -3.12 -0.184 0.53291E+04 122 nepheline 8.38 5.96 -2.42 -0.346 0.41372E+04 128 periclase-Fe 11.64 6.73 -4.91 -1.227 0.83793E+04 134 phlogopite-Na 29.73 27.57 -2.16 -0.120 0.36917E+04 136 prehnite 19.47 18.20 -1.26 -0.074 0.21560E+04 137 prehnite-Fe 22.59 22.05 -0.54 -0.032 0.92027E+03 138 pumpellyite-Fe 46.47 43.91 -2.56 -0.057 0.43704E+04 139 pumpellyite-Mg 49.19 46.48 -2.72 -0.060 0.46368E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.265 0.64808E+04 144 pyrrhotiteFe0.875 -6.00 -9.41 -3.40 -1.252 0.58126E+04 145 pyroxmangite 7.42 6.06 -1.36 -0.272 0.23234E+04 146 pyrophyllite -6.10 -11.02 -4.93 -0.308 0.84094E+04 147 quartz -2.98 -3.14 -0.16 -0.053 0.27278E+03 152 rhodonite 7.46 6.06 -1.41 -0.281 0.24026E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 26.02 -1.58 -0.047 0.26971E+04 171 talc 16.55 15.33 -1.22 -0.072 0.20878E+04 174 tephroite 18.11 15.25 -2.86 -0.409 0.48843E+04 178 tridymite -2.61 -3.14 -0.53 -0.176 0.90007E+03 179 tremolite 48.00 47.45 -0.56 -0.015 0.94968E+03 180 ferroactinolite 38.60 34.61 -3.99 -0.108 0.68074E+04 181 troilite-low -4.39 -8.04 -3.65 -1.215 0.62240E+04 187 wairakite 4.06 2.02 -2.04 -0.120 0.34817E+04 188 walstromite 11.53 9.90 -1.63 -0.325 0.27783E+04 189 wollastonite 10.48 9.90 -0.58 -0.116 0.99219E+03 190 pseudo-wollastonite 11.02 9.90 -1.12 -0.224 0.19108E+04 191 zoisite 22.96 18.98 -3.99 -0.181 0.68095E+04 192 akaganeite 7.77 4.62 -3.15 -0.681 0.53813E+04 199 chalcedony -2.79 -3.14 -0.35 -0.116 0.59309E+03 201 montmorillonite-Ca -2.21 -6.06 -3.84 -0.238 0.65619E+04 202 montmorillonite-K -2.16 -6.16 -4.00 -0.245 0.68214E+04 203 montmorillonite-Mg -2.40 -6.67 -4.27 -0.264 0.72962E+04 204 montmorillonite-Na -1.96 -5.46 -3.50 -0.214 0.59783E+04 205 nontronite-Ca 3.28 0.11 -3.17 -0.206 0.54142E+04 206 nontronite-H 2.60 -2.04 -4.64 -0.311 0.79209E+04 207 nontronite-K 3.40 0.01 -3.39 -0.218 0.57951E+04 208 nontronite-Mg 3.14 -0.51 -3.65 -0.237 0.62290E+04 209 nontronite-Na 3.58 0.70 -2.88 -0.185 0.49155E+04 224 tobermorite 9.84 7.72 -2.12 -0.577 0.36136E+04 230 alabandite -0.96 -5.57 -4.61 -1.537 0.78738E+04 233 boehmite 4.43 0.77 -3.66 -0.610 0.62453E+04 235 ferrous-oxide 9.82 6.73 -3.09 -0.773 0.52803E+04 240 silica-amorphous -2.08 -3.14 -1.06 -0.354 0.18133E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11633E+04 243 an25ab75 2.71 1.83 -0.88 -0.068 0.15021E+04 244 an30ab70 3.34 2.26 -1.08 -0.083 0.18491E+04 245 tr.625ac.25prg.125 45.31 45.19 -0.12 -0.003 0.20035E+03 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 99.9990000 g New total amount of reactant added: 103.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7343E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 103.9990000 Water: Moles liquid = 0.5484E+02 kg liquid = 0.9879E+00 Moles total = 0.5420E+02 kg total = 0.9765E+00 Activity = 1.0000 Stoichiometric ionic strength = .1162142E-01 Osmotic coef. = 0.9677 True ionic strength = .2048302E-01 Chg. balance for total moles = -.7343E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92447E-10 -10.0341 0.77608E-10 -10.1101 0.83948E+00 -0.0760 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13902E-03 -3.8569 0.11599E-03 -3.9356 0.83437E+00 -0.0786 4 SO4-- 0.26828E-11 -11.5714 0.13878E-11 -11.8577 0.51728E+00 -0.2863 5 HCO3- 0.84261E-06 -6.0744 0.70408E-06 -6.1524 0.83560E+00 -0.0780 6 HS- 0.25811E-04 -4.5882 0.21539E-04 -4.6668 0.83449E+00 -0.0786 7 Al+++ 0.11195E-28 -28.9510 0.25632E-29 -29.5912 0.22897E+00 -0.6402 8 H4SiO4 0.73184E-03 -3.1356 0.73184E-03 -3.1356 0.10000E+01 0.0000 9 Ca++ 0.13627E-06 -6.8656 0.69967E-07 -7.1551 0.51343E+00 -0.2895 10 Mg++ 0.24104E-10 -10.6179 0.12319E-10 -10.9094 0.51106E+00 -0.2915 11 Fe++ 0.63745E-13 -13.1956 0.32613E-13 -13.4866 0.51162E+00 -0.2911 12 K+ 0.15984E-03 -3.7963 0.13359E-03 -3.8742 0.83580E+00 -0.0779 13 Na+ 0.20321E-01 -1.6921 0.16952E-01 -1.7708 0.83421E+00 -0.0787 14 Mn++ 0.19015E-10 -10.7209 0.97368E-11 -11.0116 0.51205E+00 -0.2907 15 HPO4-- 0.54327E-07 -7.2650 0.28106E-07 -7.5512 0.51735E+00 -0.2862 16 HSiO3- 0.11027E-01 -1.9575 0.92006E-02 -2.0362 0.83437E+00 -0.0786 17 Ca(HSiO3)+ 0.17253E-07 -7.7631 0.14423E-07 -7.8409 0.83598E+00 -0.0778 18 Mg(HSiO3)+ 0.37803E-11 -11.4225 0.31603E-11 -11.5003 0.83598E+00 -0.0778 19 NaHSiO3,aq 0.24772E-02 -2.6060 0.24772E-02 -2.6060 0.10000E+01 0.0000 20 AlO+ 0.65718E-16 -16.1823 0.54939E-16 -16.2601 0.83598E+00 -0.0778 22 HAlO2,aq 0.14166E-09 -9.8488 0.14166E-09 -9.8488 0.10000E+01 0.0000 23 AlO2- 0.48937E-05 -5.3104 0.40757E-05 -5.3898 0.83285E+00 -0.0794 24 CH4,aq 0.10761E-04 -4.9681 0.10723E-04 -4.9697 0.99646E+00 -0.0015 25 C2H6,aq 0.24988E-14 -14.6023 0.24900E-14 -14.6038 0.99646E+00 -0.0015 29 CO,aq 0.22597E-16 -16.6460 0.22597E-16 -16.6460 0.10000E+01 0.0000 30 CO2,aq 0.11056E-09 -9.9564 0.11017E-09 -9.9579 0.99646E+00 -0.0015 31 CO3-2 0.16251E-05 -5.7891 0.83882E-06 -6.0763 0.51617E+00 -0.2872 32 CaCO3,aq 0.71881E-09 -9.1434 0.71881E-09 -9.1434 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.14848E-11 -11.8283 0.12413E-11 -11.9061 0.83598E+00 -0.0778 34 CaCl+ 0.15469E-10 -10.8105 0.12932E-10 -10.8883 0.83598E+00 -0.0778 35 CaCl2,aq 0.34925E-15 -15.4569 0.34925E-15 -15.4569 0.10000E+01 0.0000 36 CaOH+ 0.76042E-07 -7.1189 0.63570E-07 -7.1967 0.83598E+00 -0.0778 37 CaSO4,aq 0.30253E-16 -16.5192 0.30253E-16 -16.5192 0.10000E+01 0.0000 38 HCl,aq 0.16932E-14 -14.7713 0.16932E-14 -14.7713 0.10000E+01 0.0000 43 FeCl+ 0.70478E-17 -17.1519 0.58919E-17 -17.2297 0.83598E+00 -0.0778 46 FeO,aq 0.21412E-09 -9.6693 0.21412E-09 -9.6693 0.10000E+01 0.0000 47 FeOH+ 0.16665E-10 -10.7782 0.13932E-10 -10.8560 0.83598E+00 -0.0778 48 HFeO2- 0.35568E-07 -7.4489 0.29676E-07 -7.5276 0.83437E+00 -0.0786 49 FeO+ 0.14371E-16 -16.8425 0.12014E-16 -16.9203 0.83598E+00 -0.0778 51 FeO2- 0.46986E-09 -9.3280 0.39203E-09 -9.4067 0.83437E+00 -0.0786 52 HFeO2,aq 0.38077E-11 -11.4193 0.38077E-11 -11.4193 0.10000E+01 0.0000 53 H2,aq 0.79920E-05 -5.0973 0.79637E-05 -5.0989 0.99646E+00 -0.0015 54 KCl,aq 0.27438E-09 -9.5617 0.27438E-09 -9.5617 0.10000E+01 0.0000 56 KOH,aq 0.75044E-06 -6.1247 0.75044E-06 -6.1247 0.10000E+01 0.0000 57 KSO4- 0.34233E-14 -14.4655 0.28563E-14 -14.5442 0.83437E+00 -0.0786 58 MgCO3,aq 0.31624E-13 -13.5000 0.31624E-13 -13.5000 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26658E-15 -15.5742 0.22286E-15 -15.6520 0.83598E+00 -0.0778 60 MgCl+ 0.24725E-14 -14.6069 0.20670E-14 -14.6847 0.83598E+00 -0.0778 61 MgOH+ 0.74173E-10 -10.1298 0.62007E-10 -10.2076 0.83598E+00 -0.0778 63 MnO,aq 0.17066E-08 -8.7679 0.17066E-08 -8.7679 0.10000E+01 0.0000 64 MnOH+ 0.46220E-09 -9.3352 0.38639E-09 -9.4130 0.83598E+00 -0.0778 65 MnO2-2 0.18984E-10 -10.7216 0.97989E-11 -11.0088 0.51617E+00 -0.2872 66 HMnO2- 0.19747E-09 -9.7045 0.16477E-09 -9.7831 0.83437E+00 -0.0786 69 MnCl+ 0.81764E-14 -14.0874 0.68353E-14 -14.1652 0.83598E+00 -0.0778 71 NaCl,aq 0.64204E-06 -6.1924 0.64204E-06 -6.1924 0.10000E+01 0.0000 72 NaOH,aq 0.95980E-04 -4.0178 0.95980E-04 -4.0178 0.10000E+01 0.0000 74 OH- 0.92802E-02 -2.0324 0.77290E-02 -2.1119 0.83285E+00 -0.0794 79 HPO3-2 0.13697E-14 -14.8634 0.70697E-15 -15.1506 0.51617E+00 -0.2872 81 H2PO3- 0.12917E-18 -18.8888 0.10778E-18 -18.9675 0.83437E+00 -0.0786 82 H3PO4,aq 0.10898E-17 -17.9626 0.10898E-17 -17.9626 0.10000E+01 0.0000 83 H2PO4- 0.45790E-10 -10.3392 0.38242E-10 -10.4175 0.83517E+00 -0.0782 84 PO4-3 0.13143E-08 -8.8813 0.31627E-09 -9.4999 0.24064E+00 -0.6186 88 HP2O7-3 0.13194E-17 -17.8796 0.30242E-18 -18.5194 0.22921E+00 -0.6398 89 P2O7-4 0.12663E-16 -16.8975 0.96132E-18 -18.0171 0.75918E-01 -1.1197 90 H2S,aq 0.50403E-08 -8.2975 0.50224E-08 -8.2991 0.99646E+00 -0.0015 91 S2-2 0.24822E-14 -14.6052 0.12812E-14 -14.8924 0.51617E+00 -0.2872 97 SO3-2 0.28773E-17 -17.5410 0.15069E-17 -17.8219 0.52373E+00 -0.2809 99 HSO4- 0.11942E-18 -18.9229 0.99933E-19 -19.0003 0.83681E+00 -0.0774 Charge balance for all species = -.7357E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9244731E-10 -.2290452E-01 -.2304473E+02 0.0000 2 H2O 0.1000000E+01 0.5550415E+02 0.9981196E+06 0.0000 3 Cl- 0.1390170E-03 0.1396593E-03 0.4942406E+01 6.1745 4 SO4-- 0.2682831E-11 -.1275903E-04 -.1223441E+01 8.3625 5 HCO3- 0.8426089E-06 0.1322963E-04 0.8057782E+00 3.9577 6 HS- 0.2581092E-04 0.3857499E-04 0.1273450E+01 5.4433 7 Al+++ 0.1119463E-28 0.4893878E-05 0.1318059E+00 0.7391 8 H4SiO4 0.7318443E-03 0.1423601E-01 0.1365831E+04 -3.1356 9 Ca++ 0.1362723E-06 0.2303032E-06 0.9213437E-02 13.0651 10 Mg++ 0.2410436E-10 0.1020917E-09 0.2477573E-05 9.3108 11 Fe++ 0.6374518E-13 0.3627215E-07 0.2022035E-02 6.7336 12 K+ 0.1598402E-03 0.1605909E-03 0.6268094E+01 6.2359 13 Na+ 0.2032099E-01 0.2289477E-01 0.5253964E+03 8.3393 14 Mn++ 0.1901536E-10 0.2404240E-08 0.1318458E-03 9.2086 15 HPO4-- 0.5432659E-07 0.5568670E-07 0.5335109E-02 12.6690 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1722056E+01 -.2262816E-01 -.1699428E+01 0.0000000E+00 2 H2O 0.5420458E+02 0.5483444E+02 -.6298631E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2907671E-02 -.1260508E-04 0.2920276E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2882167E-02 0.3810955E-04 -.2920276E-02 0.0000000E+00 7 Al+++ 0.3391139E+00 0.4834829E-05 0.3391090E+00 0.0000000E+00 8 H4SiO4 0.1082919E+01 0.1406424E-01 0.1068855E+01 0.0000000E+00 9 Ca++ 0.1196282E+00 0.2275244E-06 0.1196279E+00 0.0000000E+00 10 Mg++ 0.8253889E-01 0.1008598E-09 0.8253889E-01 0.0000000E+00 11 Fe++ 0.7415218E-01 0.3583449E-07 0.7415214E-01 0.0000000E+00 12 K+ 0.2208047E-01 0.1586532E-03 0.2192181E-01 0.0000000E+00 13 Na+ 0.1307042E+00 0.2261852E-01 0.1080856E+00 0.0000000E+00 14 Mn++ 0.1803197E-02 0.2375231E-08 0.1803194E-02 0.0000000E+00 15 HPO4-- 0.6154221E-03 0.5501479E-07 0.6153670E-03 0.0000000E+00 Chg. balance for solid moles: 0.2320E-15 Mass of aqueous solution: 0.989720E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 103.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1081 -0.966 28.34 1.452 24.98 10.88 andradite 0.1168E-01 -1.933 5.936 0.774 5.232 1.542 grossular 0.2319E-02 -2.635 1.045 0.019 0.9209 0.2907 apatite-OH 0.2051E-03 -3.688 0.1030 -0.987 0.9082E-01 0.3274E-01 clinochlore 0.1651E-01 -1.782 9.176 0.963 8.088 3.490 daphnite 0.4574E-02 -2.340 3.264 0.514 2.877 0.9890 chlorite-Mn 0.3606E-03 -3.443 0.2557 -0.592 0.2254 0.8148E-01 microcline 0.1913E-01 -1.718 5.325 0.726 4.693 2.080 stilbite 0.7660E-01 -1.116 53.98 1.732 47.58 25.18 stilpnomelane-Fe 0.5584E-02 -2.253 6.020 0.780 5.306 2.079 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8343E+00 0.8343E+00 1.0000 -0.079 grossular 0.1657E+00 0.1657E+00 1.0000 -0.781 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7699E+00 0.7699E+00 1.0000 -0.114 daphnite 0.2133E+00 0.2133E+00 1.0000 -0.671 chlorite-Mn 0.1682E-01 0.1682E-01 1.0000 -1.774 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 113.447291 g Volume = 46.643686 cm3 Porosity: -9.4932% V(tot) - V(min): -.40441E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 103.9990000 g log = 2.0170 Original solution: 1000.0103000 g Original solution / Rock added: 9.62 (Water/Rock Ratio), log = 0.9830 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0800 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9744E+00 0.9851 0.1037E+01 0.1052E+01 CO2,gas 0.1159E-07 1.0072 0.1261E-07 0.1252E-07 CH4,gas 0.1550E-01 1.0128 0.1696E-01 0.1674E-01 H2,gas 0.1011E-01 1.0006 0.1092E-01 0.1092E-01 H2S,gas 0.1362E-06 0.9958 0.1465E-06 0.1471E-06 S2,gas 0.6237E-29 1.0000 0.6736E-29 0.6736E-29 CO,gas 0.3304E-13 1.0000 0.3568E-13 0.3568E-13 SO3,gas 0.2893E-47 1.0000 0.3125E-47 0.3125E-47 SO2,gas 0.1196E-26 1.0000 0.1291E-26 0.1291E-26 HCl,gas 0.2768E-17 1.0000 0.2990E-17 0.2990E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.32 0.01 0.000 -0.15882E+02 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.26 -9.90 -3.300 0.16903E+05 -7.899 3 CH4,gas 4.81 1.04 -3.77 -0.943 0.64383E+04 -1.771 4 H2,gas 8.29 4.33 -3.96 -2.264 0.67644E+04 -1.962 5 H2S,gas -5.94 -14.78 -8.83 -4.417 0.15084E+05 -6.834 6 S2,gas -7.03 -38.20 -31.17 -4.796 0.53225E+05 -29.172 7 CO,gas 3.51 -11.94 -15.45 -4.753 0.26376E+05 -13.448 8 SO3,gas 17.43 -32.08 -49.51 -12.376 0.84529E+05 -47.505 9 SO2,gas 1.14 -27.75 -28.89 -7.704 0.49327E+05 -26.889 10 HCl,gas 5.48 -14.05 -19.52 -9.762 0.33337E+05 -17.524 11 acmite 7.74 6.64 -1.10 -0.114 0.18753E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.70 -4.85 -0.243 0.82858E+04 20 analcite 3.37 2.81 -0.56 -0.063 0.96202E+03 26 annite 20.21 17.77 -2.44 -0.136 0.41669E+04 27 phlogopite 27.15 25.50 -1.65 -0.091 0.28107E+04 29 anorthite 12.80 8.27 -4.53 -0.348 0.77274E+04 35 aragonite 0.99 -3.20 -4.18 -1.395 0.71434E+04 36 brucite 12.58 9.31 -3.27 -0.653 0.55763E+04 37 calcite 0.83 -3.20 -4.03 -1.344 0.68821E+04 38 carnegieite-low 9.06 5.94 -3.12 -0.446 0.53303E+04 39 carnegieite-high 10.13 5.94 -4.19 -0.599 0.71572E+04 40 carpholite-Mg 8.65 4.52 -4.13 -0.276 0.70564E+04 41 carpholite-Fe 6.78 1.94 -4.84 -0.323 0.82682E+04 42 celadonite 5.40 3.74 -1.66 -0.097 0.28295E+04 43 celadonite-Fe 3.94 1.17 -2.77 -0.163 0.47309E+04 44 chrysotile 23.94 21.66 -2.28 -0.190 0.38866E+04 49 chlorite-Al-free 47.26 43.32 -3.94 -0.164 0.67266E+04 51 chloritoid-Fe 9.24 5.08 -4.16 -0.278 0.71074E+04 52 chloritoid-Mn 11.46 7.55 -3.91 -0.261 0.66797E+04 54 coesite -2.37 -3.14 -0.77 -0.255 0.13083E+04 61 cristobalite -2.55 -3.14 -0.59 -0.195 0.10012E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.74 -2.16 -0.360 0.36831E+04 66 diamond -3.11 -7.61 -4.50 -1.287 0.76916E+04 67 diopside 16.22 16.10 -0.11 -0.011 0.18919E+03 68 hedenbergite 14.24 13.53 -0.72 -0.072 0.12241E+04 71 enstatite 17.30 12.35 -4.95 -0.495 0.84531E+04 73 clinoenstatite 17.20 12.35 -4.85 -0.485 0.82839E+04 75 epidote 24.78 22.77 -2.00 -0.097 0.34195E+04 76 clinozoisite 22.92 18.94 -3.98 -0.181 0.67967E+04 77 epidote-Fe 29.94 26.60 -3.33 -0.173 0.56899E+04 78 fayalite 14.08 10.33 -3.75 -0.535 0.63985E+04 79 ferrosilite 11.19 7.20 -3.99 -0.399 0.68157E+04 83 gibbsite 4.10 0.74 -3.36 -0.480 0.57342E+04 84 glaucophane 23.11 21.00 -2.11 -0.057 0.35962E+04 85 glaucophane-Fe 17.42 13.27 -4.14 -0.112 0.70763E+04 86 graphite -3.55 -7.61 -4.06 -1.161 0.69378E+04 87 greenalite 16.19 13.93 -2.26 -0.189 0.38668E+04 90 hematite 12.60 9.14 -3.46 -0.419 0.59005E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.81 -1.44 -0.144 0.24651E+04 97 kalsilite 7.62 3.84 -3.78 -0.540 0.64558E+04 98 kaolinite -1.27 -4.79 -3.52 -0.320 0.60101E+04 101 laumontite 2.97 2.00 -0.97 -0.065 0.16625E+04 102 lawsonite 9.68 8.27 -1.41 -0.094 0.24013E+04 103 leucite 4.17 0.70 -3.46 -0.346 0.59144E+04 105 lizardite 23.29 21.66 -1.63 -0.136 0.27769E+04 107 magnetite 20.13 15.88 -4.26 -0.348 0.72692E+04 108 minnesotaite 10.46 7.66 -2.80 -0.165 0.47848E+04 112 manganosite 14.07 9.21 -4.86 -1.215 0.82972E+04 120 muscovite 2.68 -0.95 -3.63 -0.214 0.62030E+04 121 paragonite 4.34 1.15 -3.19 -0.187 0.54415E+04 122 nepheline 8.38 5.94 -2.44 -0.348 0.41582E+04 128 periclase-Fe 11.64 6.73 -4.91 -1.226 0.83761E+04 134 phlogopite-Na 29.73 27.60 -2.13 -0.118 0.36326E+04 136 prehnite 19.47 18.20 -1.26 -0.074 0.21596E+04 137 prehnite-Fe 22.59 22.03 -0.55 -0.033 0.94477E+03 138 pumpellyite-Fe 46.47 43.88 -2.59 -0.058 0.44306E+04 139 pumpellyite-Mg 49.19 46.45 -2.74 -0.061 0.46804E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.267 0.64879E+04 144 pyrrhotiteFe0.875 -6.00 -9.42 -3.42 -1.258 0.58401E+04 145 pyroxmangite 7.42 6.07 -1.34 -0.269 0.22931E+04 146 pyrophyllite -6.10 -11.06 -4.97 -0.310 0.84796E+04 147 quartz -2.98 -3.14 -0.15 -0.051 0.26224E+03 152 rhodonite 7.46 6.07 -1.39 -0.278 0.23724E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 26.07 -1.53 -0.046 0.26143E+04 171 talc 16.55 15.39 -1.16 -0.068 0.19865E+04 174 tephroite 18.11 15.28 -2.83 -0.404 0.48343E+04 178 tridymite -2.61 -3.14 -0.52 -0.174 0.88953E+03 179 tremolite 48.00 47.60 -0.40 -0.011 0.68966E+03 180 ferroactinolite 38.60 34.71 -3.88 -0.105 0.66302E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62311E+04 187 wairakite 4.06 2.00 -2.06 -0.121 0.35133E+04 188 walstromite 11.53 9.93 -1.60 -0.320 0.27292E+04 189 wollastonite 10.48 9.93 -0.55 -0.110 0.94307E+03 190 pseudo-wollastonite 11.02 9.93 -1.09 -0.218 0.18617E+04 191 zoisite 22.96 18.94 -4.02 -0.183 0.68692E+04 192 akaganeite 7.77 4.57 -3.20 -0.691 0.54584E+04 199 chalcedony -2.79 -3.14 -0.34 -0.114 0.58255E+03 201 montmorillonite-Ca -2.21 -6.08 -3.87 -0.239 0.66007E+04 202 montmorillonite-K -2.16 -6.18 -4.02 -0.246 0.68584E+04 203 montmorillonite-Mg -2.40 -6.70 -4.30 -0.266 0.73381E+04 204 montmorillonite-Na -1.96 -5.48 -3.52 -0.216 0.60153E+04 205 nontronite-Ca 3.28 0.03 -3.25 -0.211 0.55419E+04 206 nontronite-H 2.60 -2.12 -4.72 -0.316 0.80550E+04 207 nontronite-K 3.40 -0.06 -3.47 -0.223 0.59211E+04 208 nontronite-Mg 3.14 -0.59 -3.72 -0.242 0.63599E+04 209 nontronite-Na 3.58 0.63 -2.95 -0.190 0.50415E+04 224 tobermorite 9.84 7.75 -2.09 -0.571 0.35710E+04 230 alabandite -0.96 -5.57 -4.61 -1.535 0.78644E+04 233 boehmite 4.43 0.74 -3.69 -0.615 0.63015E+04 235 ferrous-oxide 9.82 6.73 -3.09 -0.773 0.52772E+04 240 silica-amorphous -2.08 -3.14 -1.06 -0.352 0.18027E+04 242 an20ab80 2.08 1.39 -0.69 -0.053 0.11739E+04 243 an25ab75 2.71 1.82 -0.89 -0.068 0.15152E+04 244 an30ab70 3.34 2.25 -1.09 -0.084 0.18650E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 103.9990000 Water: Moles liquid = 0.5484E+02 kg liquid = 0.9879E+00 Moles total = 0.5420E+02 kg total = 0.9765E+00 Activity = 1.0000 Stoichiometric ionic strength = .1160202E-01 Osmotic coef. = 0.9676 True ionic strength = .2045232E-01 Chg. balance for total moles = -.7343E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92506E-10 -10.0338 0.77665E-10 -10.1098 0.83956E+00 -0.0759 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13902E-03 -3.8569 0.11600E-03 -3.9355 0.83445E+00 -0.0786 4 SO4-- 0.28260E-11 -11.5488 0.14624E-11 -11.8349 0.51748E+00 -0.2861 5 HCO3- 0.87908E-06 -6.0560 0.73464E-06 -6.1339 0.83568E+00 -0.0780 6 HS- 0.25811E-04 -4.5882 0.21541E-04 -4.6667 0.83458E+00 -0.0785 7 Al+++ 0.11276E-28 -28.9478 0.25842E-29 -29.5877 0.22917E+00 -0.6398 8 H4SiO4 0.73091E-03 -3.1361 0.73091E-03 -3.1361 0.10000E+01 0.0000 9 Ca++ 0.13601E-06 -6.8664 0.69859E-07 -7.1558 0.51364E+00 -0.2893 10 Mg++ 0.24081E-10 -10.6183 0.12312E-10 -10.9097 0.51126E+00 -0.2914 11 Fe++ 0.63804E-13 -13.1951 0.32657E-13 -13.4860 0.51183E+00 -0.2909 12 K+ 0.15960E-03 -3.7970 0.13341E-03 -3.8748 0.83588E+00 -0.0779 13 Na+ 0.20290E-01 -1.6927 0.16928E-01 -1.7714 0.83430E+00 -0.0787 14 Mn++ 0.19005E-10 -10.7211 0.97353E-11 -11.0117 0.51226E+00 -0.2905 15 HPO4-- 0.54497E-07 -7.2636 0.28206E-07 -7.5497 0.51756E+00 -0.2860 16 HSiO3- 0.11004E-01 -1.9585 0.91821E-02 -2.0371 0.83445E+00 -0.0786 17 Ca(HSiO3)+ 0.17190E-07 -7.7647 0.14372E-07 -7.8425 0.83606E+00 -0.0778 18 Mg(HSiO3)+ 0.37703E-11 -11.4236 0.31522E-11 -11.5014 0.83606E+00 -0.0778 19 NaHSiO3,aq 0.24687E-02 -2.6075 0.24687E-02 -2.6075 0.10000E+01 0.0000 20 AlO+ 0.66153E-16 -16.1795 0.55308E-16 -16.2572 0.83606E+00 -0.0778 22 HAlO2,aq 0.14251E-09 -9.8462 0.14251E-09 -9.8462 0.10000E+01 0.0000 23 AlO2- 0.49188E-05 -5.3081 0.40971E-05 -5.3875 0.83294E+00 -0.0794 24 CH4,aq 0.10656E-04 -4.9724 0.10618E-04 -4.9739 0.99646E+00 -0.0015 25 C2H6,aq 0.24829E-14 -14.6050 0.24742E-14 -14.6066 0.99646E+00 -0.0015 29 CO,aq 0.23284E-16 -16.6329 0.23284E-16 -16.6329 0.10000E+01 0.0000 30 CO2,aq 0.11544E-09 -9.9376 0.11504E-09 -9.9392 0.99646E+00 -0.0015 31 CO3-2 0.16937E-05 -5.7712 0.87458E-06 -6.0582 0.51637E+00 -0.2870 32 CaCO3,aq 0.74830E-09 -9.1259 0.74830E-09 -9.1259 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.15467E-11 -11.8106 0.12931E-11 -11.8884 0.83606E+00 -0.0778 34 CaCl+ 0.15446E-10 -10.8112 0.12914E-10 -10.8890 0.83606E+00 -0.0778 35 CaCl2,aq 0.34879E-15 -15.4574 0.34879E-15 -15.4574 0.10000E+01 0.0000 36 CaOH+ 0.75863E-07 -7.1200 0.63426E-07 -7.1977 0.83606E+00 -0.0778 37 CaSO4,aq 0.31832E-16 -16.4971 0.31832E-16 -16.4971 0.10000E+01 0.0000 38 HCl,aq 0.16946E-14 -14.7709 0.16946E-14 -14.7709 0.10000E+01 0.0000 43 FeCl+ 0.70573E-17 -17.1514 0.59004E-17 -17.2291 0.83606E+00 -0.0778 46 FeO,aq 0.21410E-09 -9.6694 0.21410E-09 -9.6694 0.10000E+01 0.0000 47 FeOH+ 0.16674E-10 -10.7780 0.13940E-10 -10.8557 0.83606E+00 -0.0778 48 HFeO2- 0.35533E-07 -7.4494 0.29651E-07 -7.5280 0.83445E+00 -0.0786 49 FeO+ 0.14474E-16 -16.8394 0.12101E-16 -16.9172 0.83606E+00 -0.0778 51 FeO2- 0.47252E-09 -9.3256 0.39430E-09 -9.4042 0.83445E+00 -0.0786 52 HFeO2,aq 0.38325E-11 -11.4165 0.38325E-11 -11.4165 0.10000E+01 0.0000 53 H2,aq 0.78867E-05 -5.1031 0.78588E-05 -5.1046 0.99646E+00 -0.0015 54 KCl,aq 0.27402E-09 -9.5622 0.27402E-09 -9.5622 0.10000E+01 0.0000 56 KOH,aq 0.74884E-06 -6.1256 0.74884E-06 -6.1256 0.10000E+01 0.0000 57 KSO4- 0.36021E-14 -14.4435 0.30057E-14 -14.5220 0.83445E+00 -0.0786 58 MgCO3,aq 0.32953E-13 -13.4821 0.32953E-13 -13.4821 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.27796E-15 -15.5560 0.23239E-15 -15.6338 0.83606E+00 -0.0778 60 MgCl+ 0.24712E-14 -14.6071 0.20660E-14 -14.6849 0.83606E+00 -0.0778 61 MgOH+ 0.74069E-10 -10.1304 0.61927E-10 -10.2081 0.83606E+00 -0.0778 63 MnO,aq 0.17038E-08 -8.7686 0.17038E-08 -8.7686 0.10000E+01 0.0000 64 MnOH+ 0.46174E-09 -9.3356 0.38605E-09 -9.4134 0.83606E+00 -0.0778 65 MnO2-2 0.18918E-10 -10.7231 0.97687E-11 -11.0102 0.51637E+00 -0.2870 66 HMnO2- 0.19699E-09 -9.7056 0.16438E-09 -9.7842 0.83445E+00 -0.0786 69 MnCl+ 0.81752E-14 -14.0875 0.68350E-14 -14.1653 0.83606E+00 -0.0778 71 NaCl,aq 0.64121E-06 -6.1930 0.64121E-06 -6.1930 0.10000E+01 0.0000 72 NaOH,aq 0.95776E-04 -4.0187 0.95776E-04 -4.0187 0.10000E+01 0.0000 74 OH- 0.92725E-02 -2.0328 0.77234E-02 -2.1122 0.83294E+00 -0.0794 79 HPO3-2 0.13559E-14 -14.8678 0.70013E-15 -15.1548 0.51637E+00 -0.2870 81 H2PO3- 0.12800E-18 -18.8928 0.10681E-18 -18.9714 0.83445E+00 -0.0786 82 H3PO4,aq 0.10953E-17 -17.9605 0.10953E-17 -17.9605 0.10000E+01 0.0000 83 H2PO4- 0.45981E-10 -10.3374 0.38405E-10 -10.4156 0.83525E+00 -0.0782 84 PO4-3 0.13169E-08 -8.8805 0.31716E-09 -9.4987 0.24084E+00 -0.6183 88 HP2O7-3 0.13285E-17 -17.8766 0.30478E-18 -18.5160 0.22941E+00 -0.6394 89 P2O7-4 0.12732E-16 -16.8951 0.96813E-18 -18.0141 0.76037E-01 -1.1190 90 H2S,aq 0.50444E-08 -8.2972 0.50266E-08 -8.2987 0.99646E+00 -0.0015 91 S2-2 0.25148E-14 -14.5995 0.12986E-14 -14.8865 0.51637E+00 -0.2870 97 SO3-2 0.29910E-17 -17.5242 0.15670E-17 -17.8049 0.52393E+00 -0.2807 99 HSO4- 0.12592E-18 -18.8999 0.10538E-18 -18.9772 0.83689E+00 -0.0773 Charge balance for all species = -.7232E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9250643E-10 -.2286506E-01 -.2300510E+02 0.0000 2 H2O 0.1000000E+01 0.5550418E+02 0.9981236E+06 0.0000 3 Cl- 0.1390174E-03 0.1396589E-03 0.4942410E+01 6.1742 4 SO4-- 0.2826013E-11 -.1262756E-04 -.1210839E+01 8.3846 5 HCO3- 0.8790832E-06 0.1322959E-04 0.8057788E+00 3.9758 6 HS- 0.2581084E-04 0.3844345E-04 0.1269112E+01 5.4430 7 Al+++ 0.1127612E-28 0.4918985E-05 0.1324826E+00 0.7416 8 H4SiO4 0.7309135E-03 0.1420344E-01 0.1362711E+04 -3.1361 9 Ca++ 0.1360091E-06 0.2298273E-06 0.9194431E-02 13.0638 10 Mg++ 0.2408097E-10 0.1019561E-09 0.2474292E-05 9.3099 11 Fe++ 0.6380441E-13 0.3624048E-07 0.2020277E-02 6.7335 12 K+ 0.1596004E-03 0.1603495E-03 0.6258694E+01 6.2350 13 Na+ 0.2029046E-01 0.2285560E-01 0.5244995E+03 8.3384 14 Mn++ 0.1900462E-10 0.2400446E-08 0.1316382E-03 9.2079 15 HPO4-- 0.5449731E-07 0.5586017E-07 0.5351748E-02 12.6699 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1722056E+01 -.2258924E-01 -.1699467E+01 0.0000000E+00 2 H2O 0.5420458E+02 0.5483462E+02 -.6300429E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2907671E-02 -.1247523E-04 0.2920147E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2882167E-02 0.3797970E-04 -.2920147E-02 0.0000000E+00 7 Al+++ 0.3391139E+00 0.4859647E-05 0.3391090E+00 0.0000000E+00 8 H4SiO4 0.1082919E+01 0.1403210E-01 0.1068887E+01 0.0000000E+00 9 Ca++ 0.1196282E+00 0.2270549E-06 0.1196279E+00 0.0000000E+00 10 Mg++ 0.8253889E-01 0.1007262E-09 0.8253889E-01 0.0000000E+00 11 Fe++ 0.7415218E-01 0.3580331E-07 0.7415214E-01 0.0000000E+00 12 K+ 0.2208047E-01 0.1584152E-03 0.2192205E-01 0.0000000E+00 13 Na+ 0.1307042E+00 0.2257989E-01 0.1081243E+00 0.0000000E+00 14 Mn++ 0.1803197E-02 0.2371489E-08 0.1803194E-02 0.0000000E+00 15 HPO4-- 0.6154221E-03 0.5518633E-07 0.6153669E-03 0.0000000E+00 Chg. balance for solid moles: -.2468E-15 Mass of aqueous solution: 0.989719E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 103.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1081 -0.966 28.35 1.453 24.99 10.88 andradite 0.1168E-01 -1.933 5.936 0.773 5.232 1.542 grossular 0.2318E-02 -2.635 1.044 0.019 0.9203 0.2905 apatite-OH 0.2051E-03 -3.688 0.1030 -0.987 0.9082E-01 0.3274E-01 clinochlore 0.1650E-01 -1.782 9.172 0.962 8.085 3.489 daphnite 0.4581E-02 -2.339 3.268 0.514 2.881 0.9904 chlorite-Mn 0.3606E-03 -3.443 0.2557 -0.592 0.2254 0.8148E-01 microcline 0.1913E-01 -1.718 5.326 0.726 4.695 2.080 stilbite 0.7659E-01 -1.116 53.97 1.732 47.58 25.17 stilpnomelane-Fe 0.5575E-02 -2.254 6.010 0.779 5.298 2.076 tr.625ac.25prg.125 0.9181E-05 -5.037 0.7848E-02 -2.105 0.6918E-02 0.2526E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8344E+00 0.8344E+00 1.0000 -0.079 grossular 0.1656E+00 0.1656E+00 1.0000 -0.781 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7696E+00 0.7696E+00 1.0000 -0.114 daphnite 0.2136E+00 0.2136E+00 1.0000 -0.670 chlorite-Mn 0.1682E-01 0.1682E-01 1.0000 -1.774 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 113.447990 g Volume = 46.642822 cm3 Porosity: -9.4912% V(tot) - V(min): -.40432E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 103.9990000 g log = 2.0170 Original solution: 1000.0103000 g Original solution / Rock added: 9.62 (Water/Rock Ratio), log = 0.9830 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0797 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9747E+00 0.9851 0.1037E+01 0.1052E+01 CO2,gas 0.1211E-07 1.0072 0.1317E-07 0.1307E-07 CH4,gas 0.1536E-01 1.0128 0.1679E-01 0.1658E-01 H2,gas 0.9978E-02 1.0006 0.1078E-01 0.1077E-01 H2S,gas 0.1364E-06 0.9958 0.1466E-06 0.1472E-06 S2,gas 0.6417E-29 1.0000 0.6929E-29 0.6929E-29 CO,gas 0.3405E-13 1.0000 0.3677E-13 0.3677E-13 SO3,gas 0.3054E-47 1.0000 0.3298E-47 0.3298E-47 SO2,gas 0.1245E-26 1.0000 0.1345E-26 0.1345E-26 HCl,gas 0.2771E-17 1.0000 0.2992E-17 0.2992E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.24 -9.88 -3.293 0.16871E+05 -7.880 3 CH4,gas 4.81 1.03 -3.77 -0.944 0.64456E+04 -1.775 4 H2,gas 8.29 4.32 -3.97 -2.267 0.67743E+04 -1.967 5 H2S,gas -5.94 -14.78 -8.83 -4.417 0.15084E+05 -6.834 6 S2,gas -7.03 -38.19 -31.16 -4.794 0.53204E+05 -29.159 7 CO,gas 3.51 -11.92 -15.43 -4.749 0.26354E+05 -13.435 8 SO3,gas 17.43 -32.05 -49.48 -12.370 0.84489E+05 -47.482 9 SO2,gas 1.14 -27.73 -28.87 -7.699 0.49297E+05 -26.871 10 HCl,gas 5.48 -14.05 -19.52 -9.762 0.33337E+05 -17.524 11 acmite 7.74 6.64 -1.10 -0.114 0.18739E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.70 -4.85 -0.243 0.82835E+04 20 analcite 3.37 2.81 -0.56 -0.063 0.96108E+03 26 annite 20.21 17.77 -2.44 -0.136 0.41672E+04 27 phlogopite 27.15 25.50 -1.65 -0.092 0.28152E+04 29 anorthite 12.80 8.27 -4.52 -0.348 0.77227E+04 35 aragonite 0.99 -3.18 -4.17 -1.389 0.71136E+04 36 brucite 12.58 9.31 -3.27 -0.653 0.55778E+04 37 calcite 0.83 -3.18 -4.01 -1.338 0.68523E+04 38 carnegieite-low 9.06 5.94 -3.12 -0.446 0.53284E+04 39 carnegieite-high 10.13 5.94 -4.19 -0.599 0.71553E+04 40 carpholite-Mg 8.65 4.52 -4.13 -0.275 0.70510E+04 41 carpholite-Fe 6.78 1.94 -4.84 -0.323 0.82613E+04 42 celadonite 5.40 3.74 -1.66 -0.098 0.28320E+04 43 celadonite-Fe 3.94 1.17 -2.77 -0.163 0.47320E+04 44 chrysotile 23.94 21.66 -2.28 -0.190 0.38930E+04 49 chlorite-Al-free 47.26 43.31 -3.95 -0.164 0.67394E+04 51 chloritoid-Fe 9.24 5.08 -4.16 -0.277 0.70996E+04 52 chloritoid-Mn 11.46 7.56 -3.91 -0.261 0.66730E+04 54 coesite -2.37 -3.14 -0.77 -0.256 0.13093E+04 61 cristobalite -2.55 -3.14 -0.59 -0.196 0.10021E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.74 -2.15 -0.359 0.36786E+04 66 diamond -3.11 -7.60 -4.50 -1.285 0.76792E+04 67 diopside 16.22 16.10 -0.11 -0.011 0.19481E+03 68 hedenbergite 14.24 13.53 -0.72 -0.072 0.12283E+04 71 enstatite 17.30 12.35 -4.95 -0.495 0.84580E+04 73 clinoenstatite 17.20 12.35 -4.85 -0.485 0.82888E+04 75 epidote 24.78 22.78 -2.00 -0.097 0.34132E+04 76 clinozoisite 22.92 18.94 -3.98 -0.181 0.67907E+04 77 epidote-Fe 29.94 26.61 -3.33 -0.173 0.56831E+04 78 fayalite 14.08 10.33 -3.75 -0.535 0.63997E+04 79 ferrosilite 11.19 7.19 -3.99 -0.399 0.68178E+04 83 gibbsite 4.10 0.74 -3.36 -0.479 0.57298E+04 84 glaucophane 23.11 21.00 -2.11 -0.057 0.36026E+04 85 glaucophane-Fe 17.42 13.27 -4.15 -0.112 0.70785E+04 86 graphite -3.55 -7.60 -4.06 -1.159 0.69254E+04 87 greenalite 16.19 13.93 -2.27 -0.189 0.38689E+04 90 hematite 12.60 9.15 -3.45 -0.418 0.58909E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.81 -1.44 -0.144 0.24641E+04 97 kalsilite 7.62 3.84 -3.78 -0.540 0.64539E+04 98 kaolinite -1.27 -4.79 -3.52 -0.320 0.60032E+04 101 laumontite 2.97 2.00 -0.97 -0.065 0.16597E+04 102 lawsonite 9.68 8.27 -1.40 -0.094 0.23965E+04 103 leucite 4.17 0.70 -3.46 -0.346 0.59135E+04 105 lizardite 23.29 21.66 -1.63 -0.136 0.27833E+04 107 magnetite 20.13 15.88 -4.25 -0.347 0.72596E+04 108 minnesotaite 10.46 7.66 -2.80 -0.165 0.47889E+04 112 manganosite 14.07 9.21 -4.86 -1.215 0.82984E+04 120 muscovite 2.68 -0.95 -3.63 -0.213 0.61942E+04 121 paragonite 4.34 1.15 -3.18 -0.187 0.54326E+04 122 nepheline 8.38 5.94 -2.43 -0.348 0.41564E+04 128 periclase-Fe 11.64 6.73 -4.91 -1.226 0.83762E+04 134 phlogopite-Na 29.73 27.60 -2.13 -0.118 0.36371E+04 136 prehnite 19.47 18.20 -1.26 -0.074 0.21580E+04 137 prehnite-Fe 22.59 22.03 -0.55 -0.033 0.94282E+03 138 pumpellyite-Fe 46.47 43.88 -2.59 -0.058 0.44231E+04 139 pumpellyite-Mg 49.19 46.46 -2.74 -0.061 0.46744E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64874E+04 144 pyrrhotiteFe0.875 -6.00 -9.42 -3.42 -1.258 0.58383E+04 145 pyroxmangite 7.42 6.07 -1.34 -0.269 0.22953E+04 146 pyrophyllite -6.10 -11.06 -4.96 -0.310 0.84745E+04 147 quartz -2.98 -3.14 -0.15 -0.051 0.26318E+03 152 rhodonite 7.46 6.07 -1.39 -0.278 0.23745E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 26.06 -1.54 -0.046 0.26213E+04 171 talc 16.55 15.39 -1.17 -0.069 0.19948E+04 174 tephroite 18.11 15.28 -2.83 -0.405 0.48377E+04 178 tridymite -2.61 -3.14 -0.52 -0.174 0.89047E+03 179 tremolite 48.00 47.59 -0.42 -0.011 0.70918E+03 180 ferroactinolite 38.60 34.71 -3.89 -0.105 0.66427E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62306E+04 187 wairakite 4.06 2.00 -2.06 -0.121 0.35105E+04 188 walstromite 11.53 9.93 -1.60 -0.320 0.27323E+04 189 wollastonite 10.48 9.93 -0.55 -0.111 0.94624E+03 190 pseudo-wollastonite 11.02 9.93 -1.09 -0.218 0.18649E+04 191 zoisite 22.96 18.94 -4.02 -0.183 0.68632E+04 192 akaganeite 7.77 4.57 -3.19 -0.691 0.54536E+04 199 chalcedony -2.79 -3.14 -0.34 -0.114 0.58350E+03 201 montmorillonite-Ca -2.21 -6.08 -3.86 -0.239 0.65980E+04 202 montmorillonite-K -2.16 -6.18 -4.02 -0.246 0.68559E+04 203 montmorillonite-Mg -2.40 -6.70 -4.30 -0.266 0.73352E+04 204 montmorillonite-Na -1.96 -5.48 -3.52 -0.216 0.60127E+04 205 nontronite-Ca 3.28 0.04 -3.24 -0.210 0.55346E+04 206 nontronite-H 2.60 -2.12 -4.71 -0.316 0.80474E+04 207 nontronite-K 3.40 -0.06 -3.46 -0.222 0.59140E+04 208 nontronite-Mg 3.14 -0.58 -3.72 -0.241 0.63525E+04 209 nontronite-Na 3.58 0.63 -2.95 -0.189 0.50344E+04 224 tobermorite 9.84 7.75 -2.09 -0.571 0.35738E+04 230 alabandite -0.96 -5.57 -4.61 -1.535 0.78650E+04 233 boehmite 4.43 0.74 -3.69 -0.615 0.62971E+04 235 ferrous-oxide 9.82 6.73 -3.09 -0.773 0.52773E+04 240 silica-amorphous -2.08 -3.14 -1.06 -0.352 0.18037E+04 242 an20ab80 2.08 1.39 -0.69 -0.053 0.11729E+04 243 an25ab75 2.71 1.82 -0.89 -0.068 0.15141E+04 244 an30ab70 3.34 2.25 -1.09 -0.084 0.18635E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 103.9990000 g New total amount of reactant added: 107.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7351E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 107.9990000 Water: Moles liquid = 0.5482E+02 kg liquid = 0.9875E+00 Moles total = 0.5415E+02 kg total = 0.9756E+00 Activity = 1.0000 Stoichiometric ionic strength = .1161510E-01 Osmotic coef. = 0.9678 True ionic strength = .2047630E-01 Chg. balance for total moles = -.7351E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92263E-10 -10.0350 0.77455E-10 -10.1109 0.83950E+00 -0.0760 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13907E-03 -3.8568 0.11604E-03 -3.9354 0.83439E+00 -0.0786 4 SO4-- 0.24751E-11 -11.6064 0.12804E-11 -11.8926 0.51732E+00 -0.2862 5 HCO3- 0.78867E-06 -6.1031 0.65903E-06 -6.1811 0.83562E+00 -0.0780 6 HS- 0.25821E-04 -4.5880 0.21548E-04 -4.6666 0.83451E+00 -0.0786 7 Al+++ 0.11248E-28 -28.9489 0.25759E-29 -29.5891 0.22901E+00 -0.6401 8 H4SiO4 0.72879E-03 -3.1374 0.72879E-03 -3.1374 0.10000E+01 0.0000 9 Ca++ 0.13675E-06 -6.8641 0.70217E-07 -7.1536 0.51348E+00 -0.2895 10 Mg++ 0.23934E-10 -10.6210 0.12233E-10 -10.9125 0.51110E+00 -0.2915 11 Fe++ 0.63627E-13 -13.1964 0.32556E-13 -13.4874 0.51167E+00 -0.2910 12 K+ 0.15979E-03 -3.7965 0.13355E-03 -3.8743 0.83582E+00 -0.0779 13 Na+ 0.20314E-01 -1.6922 0.16947E-01 -1.7709 0.83423E+00 -0.0787 14 Mn++ 0.18988E-10 -10.7215 0.97237E-11 -11.0122 0.51210E+00 -0.2906 15 HPO4-- 0.53857E-07 -7.2688 0.27866E-07 -7.5549 0.51740E+00 -0.2862 16 HSiO3- 0.11002E-01 -1.9585 0.91803E-02 -2.0371 0.83439E+00 -0.0786 17 Ca(HSiO3)+ 0.17276E-07 -7.7626 0.14443E-07 -7.8404 0.83600E+00 -0.0778 18 Mg(HSiO3)+ 0.37456E-11 -11.4265 0.31314E-11 -11.5043 0.83600E+00 -0.0778 19 NaHSiO3,aq 0.24709E-02 -2.6071 0.24709E-02 -2.6071 0.10000E+01 0.0000 20 AlO+ 0.66304E-16 -16.1785 0.55430E-16 -16.2563 0.83600E+00 -0.0778 22 HAlO2,aq 0.14321E-09 -9.8440 0.14321E-09 -9.8440 0.10000E+01 0.0000 23 AlO2- 0.49569E-05 -5.3048 0.41284E-05 -5.3842 0.83287E+00 -0.0794 24 CH4,aq 0.10922E-04 -4.9617 0.10883E-04 -4.9633 0.99646E+00 -0.0015 25 C2H6,aq 0.25211E-14 -14.5984 0.25122E-14 -14.5999 0.99646E+00 -0.0015 29 CO,aq 0.21551E-16 -16.6665 0.21551E-16 -16.6665 0.10000E+01 0.0000 30 CO2,aq 0.10328E-09 -9.9860 0.10292E-09 -9.9875 0.99646E+00 -0.0015 31 CO3-2 0.15240E-05 -5.8170 0.78670E-06 -6.1042 0.51621E+00 -0.2872 32 CaCO3,aq 0.67655E-09 -9.1697 0.67655E-09 -9.1697 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.13947E-11 -11.8555 0.11660E-11 -11.9333 0.83600E+00 -0.0778 34 CaCl+ 0.15531E-10 -10.8088 0.12984E-10 -10.8866 0.83600E+00 -0.0778 35 CaCl2,aq 0.35081E-15 -15.4549 0.35081E-15 -15.4549 0.10000E+01 0.0000 36 CaOH+ 0.76464E-07 -7.1165 0.63924E-07 -7.1943 0.83600E+00 -0.0778 37 CaSO4,aq 0.28013E-16 -16.5526 0.28013E-16 -16.5526 0.10000E+01 0.0000 38 HCl,aq 0.16906E-14 -14.7720 0.16906E-14 -14.7720 0.10000E+01 0.0000 43 FeCl+ 0.70382E-17 -17.1525 0.58840E-17 -17.2303 0.83600E+00 -0.0778 46 FeO,aq 0.21459E-09 -9.6684 0.21459E-09 -9.6684 0.10000E+01 0.0000 47 FeOH+ 0.16668E-10 -10.7781 0.13935E-10 -10.8559 0.83600E+00 -0.0778 48 HFeO2- 0.35714E-07 -7.4472 0.29800E-07 -7.5258 0.83439E+00 -0.0786 49 FeO+ 0.14225E-16 -16.8469 0.11892E-16 -16.9247 0.83600E+00 -0.0778 51 FeO2- 0.46693E-09 -9.3307 0.38960E-09 -9.4094 0.83439E+00 -0.0786 52 HFeO2,aq 0.37766E-11 -11.4229 0.37766E-11 -11.4229 0.10000E+01 0.0000 53 H2,aq 0.81593E-05 -5.0883 0.81305E-05 -5.0899 0.99646E+00 -0.0015 54 KCl,aq 0.27441E-09 -9.5616 0.27441E-09 -9.5616 0.10000E+01 0.0000 56 KOH,aq 0.75169E-06 -6.1240 0.75169E-06 -6.1240 0.10000E+01 0.0000 57 KSO4- 0.31575E-14 -14.5007 0.26346E-14 -14.5793 0.83439E+00 -0.0786 58 MgCO3,aq 0.29452E-13 -13.5309 0.29452E-13 -13.5309 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.24778E-15 -15.6059 0.20714E-15 -15.6837 0.83600E+00 -0.0778 60 MgCl+ 0.24563E-14 -14.6097 0.20535E-14 -14.6875 0.83600E+00 -0.0778 61 MgOH+ 0.73799E-10 -10.1319 0.61696E-10 -10.2097 0.83600E+00 -0.0778 63 MnO,aq 0.17110E-08 -8.7668 0.17110E-08 -8.7668 0.10000E+01 0.0000 64 MnOH+ 0.46248E-09 -9.3349 0.38663E-09 -9.4127 0.83600E+00 -0.0778 65 MnO2-2 0.19107E-10 -10.7188 0.98631E-11 -11.0060 0.51621E+00 -0.2872 66 HMnO2- 0.19837E-09 -9.7025 0.16552E-09 -9.7812 0.83439E+00 -0.0786 69 MnCl+ 0.81687E-14 -14.0878 0.68290E-14 -14.1656 0.83600E+00 -0.0778 71 NaCl,aq 0.64212E-06 -6.1924 0.64212E-06 -6.1924 0.10000E+01 0.0000 72 NaOH,aq 0.96141E-04 -4.0171 0.96141E-04 -4.0171 0.10000E+01 0.0000 74 OH- 0.92983E-02 -2.0316 0.77443E-02 -2.1110 0.83287E+00 -0.0794 79 HPO3-2 0.13863E-14 -14.8582 0.71560E-15 -15.1453 0.51621E+00 -0.2872 81 H2PO3- 0.13049E-18 -18.8844 0.10888E-18 -18.9631 0.83439E+00 -0.0786 82 H3PO4,aq 0.10763E-17 -17.9681 0.10763E-17 -17.9681 0.10000E+01 0.0000 83 H2PO4- 0.45308E-10 -10.3438 0.37840E-10 -10.4220 0.83518E+00 -0.0782 84 PO4-3 0.13054E-08 -8.8843 0.31419E-09 -9.5028 0.24068E+00 -0.6186 88 HP2O7-3 0.12941E-17 -17.8880 0.29668E-18 -18.5277 0.22925E+00 -0.6397 89 P2O7-4 0.12443E-16 -16.9051 0.94494E-18 -18.0246 0.75944E-01 -1.1195 90 H2S,aq 0.50325E-08 -8.2982 0.50147E-08 -8.2998 0.99646E+00 -0.0015 91 S2-2 0.24332E-14 -14.6138 0.12560E-14 -14.9010 0.51621E+00 -0.2872 97 SO3-2 0.27101E-17 -17.5670 0.14195E-17 -17.8479 0.52377E+00 -0.2809 99 HSO4- 0.10996E-18 -18.9587 0.92021E-19 -19.0361 0.83682E+00 -0.0774 Charge balance for all species = -.7564E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9226345E-10 -.2289218E-01 -.2303237E+02 0.0000 2 H2O 0.1000000E+01 0.5550420E+02 0.9981231E+06 0.0000 3 Cl- 0.1390732E-03 0.1397156E-03 0.4944412E+01 6.1756 4 SO4-- 0.2475100E-11 -.1296131E-04 -.1242841E+01 8.3293 5 HCO3- 0.7886724E-06 0.1323496E-04 0.8061051E+00 3.9299 6 HS- 0.2582134E-04 0.3878768E-04 0.1280475E+01 5.4444 7 Al+++ 0.1124806E-28 0.4957003E-05 0.1335064E+00 0.7438 8 H4SiO4 0.7287920E-03 0.1420217E-01 0.1362587E+04 -3.1374 9 Ca++ 0.1367487E-06 0.2311819E-06 0.9248614E-02 13.0683 10 Mg++ 0.2393428E-10 0.1015115E-09 0.2463501E-05 9.3094 11 Fe++ 0.6362694E-13 0.3641652E-07 0.2030089E-02 6.7345 12 K+ 0.1597886E-03 0.1605406E-03 0.6266146E+01 6.2366 13 Na+ 0.2031443E-01 0.2288215E-01 0.5251082E+03 8.3400 14 Mn++ 0.1898803E-10 0.2409937E-08 0.1321586E-03 9.2097 15 HPO4-- 0.5385732E-07 0.5520803E-07 0.5289264E-02 12.6670 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1788290E+01 -.2260685E-01 -.1765683E+01 0.0000000E+00 2 H2O 0.5415444E+02 0.5481240E+02 -.6579580E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3018525E-02 -.1279976E-04 0.3031325E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2993020E-02 0.3830423E-04 -.3031325E-02 0.0000000E+00 7 Al+++ 0.3521568E+00 0.4895219E-05 0.3521519E+00 0.0000000E+00 8 H4SiO4 0.1124570E+01 0.1402515E-01 0.1110545E+01 0.0000000E+00 9 Ca++ 0.1242287E+00 0.2283005E-06 0.1242285E+00 0.0000000E+00 10 Mg++ 0.8571349E-01 0.1002463E-09 0.8571349E-01 0.0000000E+00 11 Fe++ 0.7700422E-01 0.3596262E-07 0.7700418E-01 0.0000000E+00 12 K+ 0.2292972E-01 0.1585396E-03 0.2277118E-01 0.0000000E+00 13 Na+ 0.1357251E+00 0.2259695E-01 0.1131282E+00 0.0000000E+00 14 Mn++ 0.1872551E-02 0.2379900E-08 0.1872549E-02 0.0000000E+00 15 HPO4-- 0.6390924E-03 0.5451991E-07 0.6390378E-03 0.0000000E+00 Chg. balance for solid moles: -.4293E-16 Mass of aqueous solution: 0.989319E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 107.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1131 -0.946 29.66 1.472 25.17 11.39 andradite 0.1213E-01 -1.916 6.162 0.790 5.230 1.601 grossular 0.2454E-02 -2.610 1.105 0.043 0.9382 0.3075 apatite-OH 0.2130E-03 -3.672 0.1070 -0.971 0.9082E-01 0.3400E-01 clinochlore 0.1705E-01 -1.768 9.475 0.977 8.042 3.604 daphnite 0.4748E-02 -2.324 3.388 0.530 2.875 1.027 chlorite-Mn 0.3745E-03 -3.427 0.2655 -0.576 0.2254 0.8461E-01 microcline 0.1989E-01 -1.701 5.535 0.743 4.698 2.162 stilbite 0.7916E-01 -1.101 55.79 1.747 47.35 26.02 stilpnomelane-Fe 0.5770E-02 -2.239 6.220 0.794 5.279 2.148 tr.625ac.25prg.125 0.1330E-03 -3.876 0.1137 -0.944 0.9652E-01 0.3660E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8317E+00 0.8317E+00 1.0000 -0.080 grossular 0.1683E+00 0.1683E+00 1.0000 -0.774 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7689E+00 0.7689E+00 1.0000 -0.114 daphnite 0.2142E+00 0.2142E+00 1.0000 -0.669 chlorite-Mn 0.1689E-01 0.1689E-01 1.0000 -1.772 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 117.816339 g Volume = 48.409995 cm3 Porosity: -9.5259% V(tot) - V(min): -.42104E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 107.9990000 g log = 2.0334 Original solution: 1000.0103000 g Original solution / Rock added: 9.26 (Water/Rock Ratio), log = 0.9666 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0805 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9740E+00 0.9851 0.1037E+01 0.1052E+01 CO2,gas 0.1083E-07 1.0072 0.1178E-07 0.1170E-07 CH4,gas 0.1573E-01 1.0128 0.1721E-01 0.1699E-01 H2,gas 0.1031E-01 1.0006 0.1115E-01 0.1115E-01 H2S,gas 0.1359E-06 0.9958 0.1463E-06 0.1469E-06 S2,gas 0.5963E-29 1.0000 0.6443E-29 0.6443E-29 CO,gas 0.3149E-13 1.0000 0.3403E-13 0.3403E-13 SO3,gas 0.2658E-47 1.0000 0.2872E-47 0.2872E-47 SO2,gas 0.1121E-26 1.0000 0.1212E-26 0.1212E-26 HCl,gas 0.2763E-17 1.0000 0.2985E-17 0.2985E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.29 -9.93 -3.310 0.16953E+05 -7.929 3 CH4,gas 4.81 1.04 -3.76 -0.941 0.64273E+04 -1.764 4 H2,gas 8.29 4.33 -3.95 -2.259 0.67491E+04 -1.953 5 H2S,gas -5.94 -14.78 -8.83 -4.417 0.15085E+05 -6.835 6 S2,gas -7.03 -38.22 -31.19 -4.799 0.53258E+05 -29.191 7 CO,gas 3.51 -11.96 -15.47 -4.759 0.26411E+05 -13.468 8 SO3,gas 17.43 -32.11 -49.54 -12.385 0.84591E+05 -47.542 9 SO2,gas 1.14 -27.78 -28.92 -7.711 0.49374E+05 -26.917 10 HCl,gas 5.48 -14.05 -19.53 -9.763 0.33338E+05 -17.525 11 acmite 7.74 6.63 -1.10 -0.115 0.18863E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.70 -4.85 -0.242 0.82732E+04 20 analcite 3.37 2.81 -0.56 -0.062 0.95892E+03 26 annite 20.21 17.77 -2.44 -0.135 0.41620E+04 27 phlogopite 27.15 25.50 -1.65 -0.092 0.28175E+04 29 anorthite 12.80 8.28 -4.52 -0.347 0.77119E+04 35 aragonite 0.99 -3.22 -4.21 -1.403 0.71883E+04 36 brucite 12.58 9.31 -3.27 -0.653 0.55786E+04 37 calcite 0.83 -3.22 -4.06 -1.352 0.69270E+04 38 carnegieite-low 9.06 5.95 -3.12 -0.445 0.53241E+04 39 carnegieite-high 10.13 5.95 -4.19 -0.598 0.71510E+04 40 carpholite-Mg 8.65 4.52 -4.13 -0.275 0.70487E+04 41 carpholite-Fe 6.78 1.95 -4.84 -0.322 0.82566E+04 42 celadonite 5.40 3.74 -1.66 -0.098 0.28349E+04 43 celadonite-Fe 3.94 1.17 -2.77 -0.163 0.47324E+04 44 chrysotile 23.94 21.65 -2.28 -0.190 0.38996E+04 49 chlorite-Al-free 47.26 43.31 -3.95 -0.165 0.67525E+04 51 chloritoid-Fe 9.24 5.08 -4.15 -0.277 0.70928E+04 52 chloritoid-Mn 11.46 7.56 -3.90 -0.260 0.66648E+04 54 coesite -2.37 -3.14 -0.77 -0.256 0.13114E+04 61 cristobalite -2.55 -3.14 -0.59 -0.196 0.10043E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.74 -2.15 -0.359 0.36750E+04 66 diamond -3.11 -7.62 -4.52 -1.290 0.77114E+04 67 diopside 16.22 16.10 -0.11 -0.011 0.19208E+03 68 hedenbergite 14.24 13.53 -0.72 -0.072 0.12231E+04 71 enstatite 17.30 12.34 -4.96 -0.496 0.84638E+04 73 clinoenstatite 17.20 12.34 -4.86 -0.486 0.82946E+04 75 epidote 24.78 22.78 -2.00 -0.097 0.34076E+04 76 clinozoisite 22.92 18.96 -3.97 -0.180 0.67706E+04 77 epidote-Fe 29.94 26.60 -3.33 -0.173 0.56921E+04 78 fayalite 14.08 10.33 -3.75 -0.535 0.63984E+04 79 ferrosilite 11.19 7.19 -3.99 -0.399 0.68187E+04 83 gibbsite 4.10 0.74 -3.35 -0.479 0.57262E+04 84 glaucophane 23.11 21.00 -2.11 -0.057 0.36092E+04 85 glaucophane-Fe 17.42 13.27 -4.15 -0.112 0.70777E+04 86 graphite -3.55 -7.62 -4.07 -1.164 0.69575E+04 87 greenalite 16.19 13.93 -2.27 -0.189 0.38681E+04 90 hematite 12.60 9.13 -3.46 -0.420 0.59126E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.81 -1.44 -0.144 0.24620E+04 97 kalsilite 7.62 3.84 -3.78 -0.540 0.64496E+04 98 kaolinite -1.27 -4.79 -3.51 -0.319 0.60002E+04 101 laumontite 2.97 2.01 -0.97 -0.065 0.16532E+04 102 lawsonite 9.68 8.28 -1.40 -0.093 0.23858E+04 103 leucite 4.17 0.71 -3.46 -0.346 0.59113E+04 105 lizardite 23.29 21.65 -1.63 -0.136 0.27899E+04 107 magnetite 20.13 15.87 -4.26 -0.348 0.72797E+04 108 minnesotaite 10.46 7.65 -2.81 -0.165 0.47924E+04 112 manganosite 14.07 9.21 -4.86 -1.215 0.82953E+04 120 muscovite 2.68 -0.94 -3.62 -0.213 0.61869E+04 121 paragonite 4.34 1.16 -3.18 -0.187 0.54254E+04 122 nepheline 8.38 5.95 -2.43 -0.347 0.41520E+04 128 periclase-Fe 11.64 6.73 -4.90 -1.226 0.83745E+04 134 phlogopite-Na 29.73 27.60 -2.13 -0.118 0.36394E+04 136 prehnite 19.47 18.21 -1.25 -0.074 0.21416E+04 137 prehnite-Fe 22.59 22.04 -0.55 -0.033 0.94094E+03 138 pumpellyite-Fe 46.47 43.90 -2.57 -0.057 0.43850E+04 139 pumpellyite-Mg 49.19 46.48 -2.72 -0.060 0.46387E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64875E+04 144 pyrrhotiteFe0.875 -6.00 -9.42 -3.42 -1.258 0.58417E+04 145 pyroxmangite 7.42 6.07 -1.34 -0.269 0.22943E+04 146 pyrophyllite -6.10 -11.06 -4.96 -0.310 0.84759E+04 147 quartz -2.98 -3.14 -0.16 -0.052 0.26534E+03 152 rhodonite 7.46 6.07 -1.39 -0.278 0.23736E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 26.05 -1.54 -0.046 0.26336E+04 171 talc 16.55 15.38 -1.17 -0.069 0.20057E+04 174 tephroite 18.11 15.28 -2.83 -0.404 0.48336E+04 178 tridymite -2.61 -3.14 -0.52 -0.174 0.89263E+03 179 tremolite 48.00 47.58 -0.42 -0.011 0.71462E+03 180 ferroactinolite 38.60 34.71 -3.89 -0.105 0.66358E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62306E+04 187 wairakite 4.06 2.01 -2.05 -0.121 0.35040E+04 188 walstromite 11.53 9.93 -1.60 -0.319 0.27267E+04 189 wollastonite 10.48 9.93 -0.55 -0.110 0.94059E+03 190 pseudo-wollastonite 11.02 9.93 -1.09 -0.218 0.18592E+04 191 zoisite 22.96 18.96 -4.01 -0.182 0.68432E+04 192 akaganeite 7.77 4.57 -3.20 -0.692 0.54645E+04 199 chalcedony -2.79 -3.14 -0.34 -0.114 0.58565E+03 201 montmorillonite-Ca -2.21 -6.08 -3.87 -0.239 0.65995E+04 202 montmorillonite-K -2.16 -6.18 -4.02 -0.246 0.68577E+04 203 montmorillonite-Mg -2.40 -6.70 -4.30 -0.266 0.73382E+04 204 montmorillonite-Na -1.96 -5.48 -3.52 -0.216 0.60146E+04 205 nontronite-Ca 3.28 0.02 -3.26 -0.211 0.55618E+04 206 nontronite-H 2.60 -2.13 -4.73 -0.317 0.80759E+04 207 nontronite-K 3.40 -0.08 -3.48 -0.223 0.59415E+04 208 nontronite-Mg 3.14 -0.60 -3.74 -0.242 0.63811E+04 209 nontronite-Na 3.58 0.62 -2.96 -0.190 0.50619E+04 224 tobermorite 9.84 7.75 -2.09 -0.570 0.35694E+04 230 alabandite -0.96 -5.57 -4.61 -1.535 0.78636E+04 233 boehmite 4.43 0.74 -3.69 -0.614 0.62934E+04 235 ferrous-oxide 9.82 6.73 -3.09 -0.772 0.52756E+04 240 silica-amorphous -2.08 -3.14 -1.06 -0.353 0.18058E+04 242 an20ab80 2.08 1.39 -0.69 -0.053 0.11708E+04 243 an25ab75 2.71 1.82 -0.89 -0.068 0.15114E+04 244 an30ab70 3.34 2.25 -1.09 -0.084 0.18603E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 107.9990000 g New total amount of reactant added: 111.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7314E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 111.9990000 Water: Moles liquid = 0.5479E+02 kg liquid = 0.9871E+00 Moles total = 0.5410E+02 kg total = 0.9747E+00 Activity = 1.0000 Stoichiometric ionic strength = .1162719E-01 Osmotic coef. = 0.9680 True ionic strength = .2049845E-01 Chg. balance for total moles = -.7314E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92041E-10 -10.0360 0.77263E-10 -10.1120 0.83944E+00 -0.0760 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13913E-03 -3.8566 0.11608E-03 -3.9352 0.83433E+00 -0.0787 4 SO4-- 0.21901E-11 -11.6595 0.11327E-11 -11.9459 0.51718E+00 -0.2864 5 HCO3- 0.71195E-06 -6.1476 0.59488E-06 -6.2256 0.83556E+00 -0.0780 6 HS- 0.25832E-04 -4.5878 0.21555E-04 -4.6664 0.83445E+00 -0.0786 7 Al+++ 0.11222E-28 -28.9499 0.25684E-29 -29.5903 0.22886E+00 -0.6404 8 H4SiO4 0.72685E-03 -3.1386 0.72685E-03 -3.1386 0.10000E+01 0.0000 9 Ca++ 0.13743E-06 -6.8619 0.70548E-07 -7.1515 0.51333E+00 -0.2896 10 Mg++ 0.23800E-10 -10.6234 0.12161E-10 -10.9150 0.51095E+00 -0.2916 11 Fe++ 0.63464E-13 -13.1975 0.32463E-13 -13.4886 0.51152E+00 -0.2911 12 K+ 0.15996E-03 -3.7960 0.13369E-03 -3.8739 0.83576E+00 -0.0779 13 Na+ 0.20337E-01 -1.6917 0.16964E-01 -1.7705 0.83417E+00 -0.0787 14 Mn++ 0.18974E-10 -10.7218 0.97139E-11 -11.0126 0.51195E+00 -0.2908 15 HPO4-- 0.53275E-07 -7.2735 0.27557E-07 -7.5598 0.51725E+00 -0.2863 16 HSiO3- 0.11001E-01 -1.9586 0.91785E-02 -2.0372 0.83433E+00 -0.0787 17 Ca(HSiO3)+ 0.17355E-07 -7.7606 0.14508E-07 -7.8384 0.83594E+00 -0.0778 18 Mg(HSiO3)+ 0.37231E-11 -11.4291 0.31123E-11 -11.5069 0.83594E+00 -0.0778 19 NaHSiO3,aq 0.24730E-02 -2.6068 0.24730E-02 -2.6068 0.10000E+01 0.0000 20 AlO+ 0.66444E-16 -16.1775 0.55543E-16 -16.2554 0.83594E+00 -0.0778 22 HAlO2,aq 0.14386E-09 -9.8421 0.14386E-09 -9.8421 0.10000E+01 0.0000 23 AlO2- 0.49920E-05 -5.3017 0.41574E-05 -5.3812 0.83281E+00 -0.0795 24 CH4,aq 0.11148E-04 -4.9528 0.11109E-04 -4.9543 0.99646E+00 -0.0015 25 C2H6,aq 0.25457E-14 -14.5942 0.25367E-14 -14.5957 0.99646E+00 -0.0015 29 CO,aq 0.20023E-16 -16.6985 0.20023E-16 -16.6985 0.10000E+01 0.0000 30 CO2,aq 0.92998E-10 -10.0315 0.92668E-10 -10.0331 0.99646E+00 -0.0015 31 CO3-2 0.13794E-05 -5.8603 0.71188E-06 -6.1476 0.51607E+00 -0.2873 32 CaCO3,aq 0.61510E-09 -9.2111 0.61510E-09 -9.2111 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.12650E-11 -11.8979 0.10575E-11 -11.9757 0.83594E+00 -0.0778 34 CaCl+ 0.15610E-10 -10.8066 0.13049E-10 -10.8844 0.83594E+00 -0.0778 35 CaCl2,aq 0.35269E-15 -15.4526 0.35269E-15 -15.4526 0.10000E+01 0.0000 36 CaOH+ 0.77021E-07 -7.1134 0.64385E-07 -7.1912 0.83594E+00 -0.0778 37 CaSO4,aq 0.24897E-16 -16.6038 0.24897E-16 -16.6038 0.10000E+01 0.0000 38 HCl,aq 0.16870E-14 -14.7729 0.16870E-14 -14.7729 0.10000E+01 0.0000 43 FeCl+ 0.70210E-17 -17.1536 0.58692E-17 -17.2314 0.83594E+00 -0.0778 46 FeO,aq 0.21505E-09 -9.6675 0.21505E-09 -9.6675 0.10000E+01 0.0000 47 FeOH+ 0.16663E-10 -10.7782 0.13929E-10 -10.8561 0.83594E+00 -0.0778 48 HFeO2- 0.35882E-07 -7.4451 0.29937E-07 -7.5238 0.83433E+00 -0.0787 49 FeO+ 0.14000E-16 -16.8539 0.11703E-16 -16.9317 0.83594E+00 -0.0778 51 FeO2- 0.46182E-09 -9.3355 0.38531E-09 -9.4142 0.83433E+00 -0.0787 52 HFeO2,aq 0.37257E-11 -11.4288 0.37257E-11 -11.4288 0.10000E+01 0.0000 53 H2,aq 0.84193E-05 -5.0747 0.83895E-05 -5.0763 0.99646E+00 -0.0015 54 KCl,aq 0.27478E-09 -9.5610 0.27478E-09 -9.5610 0.10000E+01 0.0000 56 KOH,aq 0.75433E-06 -6.1224 0.75433E-06 -6.1224 0.10000E+01 0.0000 57 KSO4- 0.27962E-14 -14.5534 0.23329E-14 -14.6321 0.83433E+00 -0.0787 58 MgCO3,aq 0.26494E-13 -13.5769 0.26494E-13 -13.5769 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22235E-15 -15.6530 0.18588E-15 -15.7308 0.83594E+00 -0.0778 60 MgCl+ 0.24428E-14 -14.6121 0.20420E-14 -14.6899 0.83594E+00 -0.0778 61 MgOH+ 0.73552E-10 -10.1334 0.61485E-10 -10.2112 0.83594E+00 -0.0778 63 MnO,aq 0.17178E-08 -8.7650 0.17178E-08 -8.7650 0.10000E+01 0.0000 64 MnOH+ 0.46319E-09 -9.3342 0.38720E-09 -9.4121 0.83594E+00 -0.0778 65 MnO2-2 0.19283E-10 -10.7148 0.99515E-11 -11.0021 0.51607E+00 -0.2873 66 HMnO2- 0.19967E-09 -9.6997 0.16659E-09 -9.7784 0.83433E+00 -0.0787 69 MnCl+ 0.81637E-14 -14.0881 0.68244E-14 -14.1659 0.83594E+00 -0.0778 71 NaCl,aq 0.64299E-06 -6.1918 0.64299E-06 -6.1918 0.10000E+01 0.0000 72 NaOH,aq 0.96478E-04 -4.0156 0.96478E-04 -4.0156 0.10000E+01 0.0000 74 OH- 0.93221E-02 -2.0305 0.77635E-02 -2.1099 0.83281E+00 -0.0795 79 HPO3-2 0.14150E-14 -14.8493 0.73022E-15 -15.1365 0.51607E+00 -0.2873 81 H2PO3- 0.13283E-18 -18.8767 0.11082E-18 -18.9554 0.83433E+00 -0.0787 82 H3PO4,aq 0.10591E-17 -17.9751 0.10591E-17 -17.9751 0.10000E+01 0.0000 83 H2PO4- 0.44697E-10 -10.3497 0.37328E-10 -10.4280 0.83512E+00 -0.0782 84 PO4-3 0.12949E-08 -8.8878 0.31148E-09 -9.5066 0.24054E+00 -0.6188 88 HP2O7-3 0.12633E-17 -17.8985 0.28942E-18 -18.5385 0.22910E+00 -0.6400 89 P2O7-4 0.12182E-16 -16.9143 0.92411E-18 -18.0343 0.75858E-01 -1.1200 90 H2S,aq 0.50217E-08 -8.2992 0.50039E-08 -8.3007 0.99646E+00 -0.0015 91 S2-2 0.23603E-14 -14.6270 0.12181E-14 -14.9143 0.51607E+00 -0.2873 97 SO3-2 0.24744E-17 -17.6065 0.12957E-17 -17.8875 0.52363E+00 -0.2810 99 HSO4- 0.97040E-19 -19.0130 0.81200E-19 -19.0904 0.83677E+00 -0.0774 Charge balance for all species = -.7541E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9204079E-10 -.2291718E-01 -.2305751E+02 0.0000 2 H2O 0.1000000E+01 0.5550423E+02 0.9981227E+06 0.0000 3 Cl- 0.1391290E-03 0.1397723E-03 0.4946415E+01 6.1768 4 SO4-- 0.2190082E-11 -.1325301E-04 -.1270810E+01 8.2782 5 HCO3- 0.7119485E-06 0.1324033E-04 0.8064317E+00 3.8865 6 HS- 0.2583183E-04 0.3908987E-04 0.1290450E+01 5.4456 7 Al+++ 0.1122235E-28 0.4992185E-05 0.1344538E+00 0.7457 8 H4SiO4 0.7268480E-03 0.1420101E-01 0.1362475E+04 -3.1386 9 Ca++ 0.1374329E-06 0.2324409E-06 0.9298973E-02 13.0725 10 Mg++ 0.2380024E-10 0.1011048E-09 0.2453629E-05 9.3090 11 Fe++ 0.6346447E-13 0.3657915E-07 0.2039153E-02 6.7354 12 K+ 0.1599623E-03 0.1607169E-03 0.6273024E+01 6.2381 13 Na+ 0.2033654E-01 0.2290665E-01 0.5256700E+03 8.3416 14 Mn++ 0.1897435E-10 0.2418891E-08 0.1326495E-03 9.2114 15 HPO4-- 0.5327537E-07 0.5461500E-07 0.5232444E-02 12.6643 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1854524E+01 -.2262236E-01 -.1831902E+01 0.0000000E+00 2 H2O 0.5410430E+02 0.5479018E+02 -.6858809E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3129379E-02 -.1308251E-04 0.3142461E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3103874E-02 0.3858698E-04 -.3142461E-02 0.0000000E+00 7 Al+++ 0.3651998E+00 0.4927961E-05 0.3651949E+00 0.0000000E+00 8 H4SiO4 0.1166221E+01 0.1401832E-01 0.1152203E+01 0.0000000E+00 9 Ca++ 0.1288293E+00 0.2294506E-06 0.1288291E+00 0.0000000E+00 10 Mg++ 0.8888810E-01 0.9980412E-10 0.8888810E-01 0.0000000E+00 11 Fe++ 0.7985625E-01 0.3610857E-07 0.7985621E-01 0.0000000E+00 12 K+ 0.2377898E-01 0.1586493E-03 0.2362033E-01 0.0000000E+00 13 Na+ 0.1407461E+00 0.2261196E-01 0.1181341E+00 0.0000000E+00 14 Mn++ 0.1941905E-02 0.2387772E-08 0.1941903E-02 0.0000000E+00 15 HPO4-- 0.6627627E-03 0.5391239E-07 0.6627088E-03 0.0000000E+00 Chg. balance for solid moles: 0.2539E-15 Mass of aqueous solution: 0.988918E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 111.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1181 -0.928 30.97 1.491 25.35 11.89 andradite 0.1257E-01 -1.901 6.388 0.805 5.228 1.660 grossular 0.2590E-02 -2.587 1.167 0.067 0.9549 0.3246 apatite-OH 0.2209E-03 -3.656 0.1110 -0.955 0.9082E-01 0.3526E-01 clinochlore 0.1759E-01 -1.755 9.778 0.990 8.002 3.719 daphnite 0.4915E-02 -2.309 3.507 0.545 2.870 1.063 chlorite-Mn 0.3884E-03 -3.411 0.2754 -0.560 0.2254 0.8775E-01 microcline 0.2064E-01 -1.685 5.744 0.759 4.701 2.244 stilbite 0.8173E-01 -1.088 57.60 1.760 47.14 26.86 stilpnomelane-Fe 0.5964E-02 -2.224 6.430 0.808 5.262 2.221 tr.625ac.25prg.125 0.2571E-03 -3.590 0.2197 -0.658 0.1798 0.7072E-01 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8291E+00 0.8291E+00 1.0000 -0.081 grossular 0.1709E+00 0.1709E+00 1.0000 -0.767 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7684E+00 0.7684E+00 1.0000 -0.114 daphnite 0.2147E+00 0.2147E+00 1.0000 -0.668 chlorite-Mn 0.1696E-01 0.1696E-01 1.0000 -1.770 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 122.184581 g Volume = 50.177031 cm3 Porosity: -9.5578% V(tot) - V(min): -.43774E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 111.9990000 g log = 2.0492 Original solution: 1000.0103000 g Original solution / Rock added: 8.93 (Water/Rock Ratio), log = 0.9508 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0812 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9733E+00 0.9851 0.1037E+01 0.1052E+01 CO2,gas 0.9741E-08 1.0072 0.1061E-07 0.1053E-07 CH4,gas 0.1604E-01 1.0128 0.1757E-01 0.1734E-01 H2,gas 0.1064E-01 1.0006 0.1151E-01 0.1150E-01 H2S,gas 0.1356E-06 0.9958 0.1459E-06 0.1466E-06 S2,gas 0.5573E-29 1.0000 0.6025E-29 0.6025E-29 CO,gas 0.2924E-13 1.0000 0.3162E-13 0.3162E-13 SO3,gas 0.2338E-47 1.0000 0.2528E-47 0.2528E-47 SO2,gas 0.1018E-26 1.0000 0.1100E-26 0.1100E-26 HCl,gas 0.2755E-17 1.0000 0.2979E-17 0.2979E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.34 -9.97 -3.325 0.17031E+05 -7.974 3 CH4,gas 4.81 1.05 -3.76 -0.939 0.64121E+04 -1.755 4 H2,gas 8.29 4.35 -3.94 -2.251 0.67258E+04 -1.939 5 H2S,gas -5.94 -14.78 -8.84 -4.418 0.15087E+05 -6.836 6 S2,gas -7.03 -38.25 -31.22 -4.803 0.53307E+05 -29.220 7 CO,gas 3.51 -11.99 -15.50 -4.769 0.26466E+05 -13.500 8 SO3,gas 17.43 -32.17 -49.60 -12.399 0.84686E+05 -47.597 9 SO2,gas 1.14 -27.82 -28.96 -7.722 0.49446E+05 -26.958 10 HCl,gas 5.48 -14.05 -19.53 -9.763 0.33340E+05 -17.526 11 acmite 7.74 6.63 -1.11 -0.115 0.18977E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.71 -4.84 -0.242 0.82637E+04 20 analcite 3.37 2.81 -0.56 -0.062 0.95694E+03 26 annite 20.21 17.77 -2.43 -0.135 0.41573E+04 27 phlogopite 27.15 25.50 -1.65 -0.092 0.28196E+04 29 anorthite 12.80 8.29 -4.51 -0.347 0.77020E+04 35 aragonite 0.99 -3.27 -4.25 -1.417 0.72589E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55793E+04 37 calcite 0.83 -3.27 -4.10 -1.366 0.69976E+04 38 carnegieite-low 9.06 5.95 -3.12 -0.445 0.53201E+04 39 carnegieite-high 10.13 5.95 -4.19 -0.598 0.71470E+04 40 carpholite-Mg 8.65 4.52 -4.13 -0.275 0.70467E+04 41 carpholite-Fe 6.78 1.95 -4.83 -0.322 0.82523E+04 42 celadonite 5.40 3.74 -1.66 -0.098 0.28375E+04 43 celadonite-Fe 3.94 1.17 -2.77 -0.163 0.47328E+04 44 chrysotile 23.94 21.65 -2.29 -0.191 0.39057E+04 49 chlorite-Al-free 47.26 43.30 -3.96 -0.165 0.67647E+04 51 chloritoid-Fe 9.24 5.09 -4.15 -0.277 0.70865E+04 52 chloritoid-Mn 11.46 7.56 -3.90 -0.260 0.66571E+04 54 coesite -2.37 -3.14 -0.77 -0.256 0.13134E+04 61 cristobalite -2.55 -3.14 -0.59 -0.196 0.10063E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.75 -2.15 -0.358 0.36717E+04 66 diamond -3.11 -7.64 -4.53 -1.296 0.77426E+04 67 diopside 16.22 16.10 -0.11 -0.011 0.18957E+03 68 hedenbergite 14.24 13.53 -0.71 -0.071 0.12183E+04 71 enstatite 17.30 12.34 -4.96 -0.496 0.84692E+04 73 clinoenstatite 17.20 12.34 -4.86 -0.486 0.83000E+04 75 epidote 24.78 22.78 -1.99 -0.097 0.34026E+04 76 clinozoisite 22.92 18.97 -3.95 -0.180 0.67522E+04 77 epidote-Fe 29.94 26.60 -3.34 -0.173 0.57005E+04 78 fayalite 14.08 10.33 -3.75 -0.535 0.63972E+04 79 ferrosilite 11.19 7.19 -3.99 -0.399 0.68195E+04 83 gibbsite 4.10 0.75 -3.35 -0.479 0.57228E+04 84 glaucophane 23.11 20.99 -2.12 -0.057 0.36153E+04 85 glaucophane-Fe 17.42 13.27 -4.14 -0.112 0.70769E+04 86 graphite -3.55 -7.64 -4.09 -1.169 0.69888E+04 87 greenalite 16.19 13.93 -2.26 -0.189 0.38674E+04 90 hematite 12.60 9.12 -3.47 -0.421 0.59327E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.81 -1.44 -0.144 0.24600E+04 97 kalsilite 7.62 3.85 -3.77 -0.539 0.64456E+04 98 kaolinite -1.27 -4.79 -3.51 -0.319 0.59975E+04 101 laumontite 2.97 2.01 -0.96 -0.064 0.16473E+04 102 lawsonite 9.68 8.29 -1.39 -0.093 0.23759E+04 103 leucite 4.17 0.71 -3.46 -0.346 0.59094E+04 105 lizardite 23.29 21.65 -1.64 -0.136 0.27960E+04 107 magnetite 20.13 15.86 -4.27 -0.349 0.72982E+04 108 minnesotaite 10.46 7.65 -2.81 -0.165 0.47956E+04 112 manganosite 14.07 9.21 -4.86 -1.214 0.82923E+04 120 muscovite 2.68 -0.94 -3.62 -0.213 0.61802E+04 121 paragonite 4.34 1.16 -3.17 -0.187 0.54187E+04 122 nepheline 8.38 5.95 -2.43 -0.347 0.41481E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.226 0.83729E+04 134 phlogopite-Na 29.73 27.60 -2.13 -0.118 0.36415E+04 136 prehnite 19.47 18.22 -1.25 -0.073 0.21265E+04 137 prehnite-Fe 22.59 22.04 -0.55 -0.033 0.93925E+03 138 pumpellyite-Fe 46.47 43.92 -2.55 -0.057 0.43499E+04 139 pumpellyite-Mg 49.19 46.50 -2.70 -0.060 0.46058E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64875E+04 144 pyrrhotiteFe0.875 -6.00 -9.42 -3.42 -1.259 0.58448E+04 145 pyroxmangite 7.42 6.07 -1.34 -0.269 0.22934E+04 146 pyrophyllite -6.10 -11.06 -4.96 -0.310 0.84771E+04 147 quartz -2.98 -3.14 -0.16 -0.052 0.26732E+03 152 rhodonite 7.46 6.07 -1.39 -0.278 0.23726E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 26.05 -1.55 -0.046 0.26450E+04 171 talc 16.55 15.37 -1.18 -0.069 0.20157E+04 174 tephroite 18.11 15.28 -2.83 -0.404 0.48297E+04 178 tridymite -2.61 -3.14 -0.52 -0.175 0.89461E+03 179 tremolite 48.00 47.58 -0.42 -0.011 0.71961E+03 180 ferroactinolite 38.60 34.71 -3.88 -0.105 0.66294E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62307E+04 187 wairakite 4.06 2.01 -2.05 -0.121 0.34981E+04 188 walstromite 11.53 9.93 -1.59 -0.319 0.27215E+04 189 wollastonite 10.48 9.93 -0.55 -0.110 0.93541E+03 190 pseudo-wollastonite 11.02 9.93 -1.09 -0.217 0.18540E+04 191 zoisite 22.96 18.97 -4.00 -0.182 0.68247E+04 192 akaganeite 7.77 4.56 -3.21 -0.693 0.54745E+04 199 chalcedony -2.79 -3.14 -0.34 -0.115 0.58763E+03 201 montmorillonite-Ca -2.21 -6.08 -3.87 -0.239 0.66008E+04 202 montmorillonite-K -2.16 -6.18 -4.02 -0.246 0.68594E+04 203 montmorillonite-Mg -2.40 -6.70 -4.30 -0.266 0.73408E+04 204 montmorillonite-Na -1.96 -5.48 -3.52 -0.216 0.60163E+04 205 nontronite-Ca 3.28 0.01 -3.27 -0.212 0.55869E+04 206 nontronite-H 2.60 -2.15 -4.75 -0.318 0.81021E+04 207 nontronite-K 3.40 -0.09 -3.49 -0.224 0.59669E+04 208 nontronite-Mg 3.14 -0.61 -3.75 -0.243 0.64075E+04 209 nontronite-Na 3.58 0.60 -2.98 -0.191 0.50874E+04 224 tobermorite 9.84 7.75 -2.09 -0.570 0.35654E+04 230 alabandite -0.96 -5.57 -4.60 -1.535 0.78623E+04 233 boehmite 4.43 0.75 -3.68 -0.614 0.62901E+04 235 ferrous-oxide 9.82 6.74 -3.09 -0.772 0.52740E+04 240 silica-amorphous -2.08 -3.14 -1.06 -0.353 0.18078E+04 242 an20ab80 2.08 1.39 -0.68 -0.053 0.11688E+04 243 an25ab75 2.71 1.83 -0.88 -0.068 0.15089E+04 244 an30ab70 3.34 2.26 -1.09 -0.084 0.18573E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 111.9990000 g New total amount of reactant added: 115.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7317E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 115.9990000 Water: Moles liquid = 0.5477E+02 kg liquid = 0.9867E+00 Moles total = 0.5405E+02 kg total = 0.9738E+00 Activity = 1.0000 Stoichiometric ionic strength = .1163841E-01 Osmotic coef. = 0.9681 True ionic strength = .2051896E-01 Chg. balance for total moles = -.7317E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91836E-10 -10.0370 0.77086E-10 -10.1130 0.83939E+00 -0.0760 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13918E-03 -3.8564 0.11612E-03 -3.9351 0.83427E+00 -0.0787 4 SO4-- 0.19557E-11 -11.7087 0.10112E-11 -11.9952 0.51704E+00 -0.2865 5 HCO3- 0.64649E-06 -6.1894 0.54015E-06 -6.2675 0.83550E+00 -0.0781 6 HS- 0.25842E-04 -4.5877 0.21563E-04 -4.6663 0.83439E+00 -0.0786 7 Al+++ 0.11199E-28 -28.9508 0.25614E-29 -29.5915 0.22873E+00 -0.6407 8 H4SiO4 0.72506E-03 -3.1396 0.72506E-03 -3.1396 0.10000E+01 0.0000 9 Ca++ 0.13807E-06 -6.8599 0.70855E-07 -7.1496 0.51319E+00 -0.2897 10 Mg++ 0.23677E-10 -10.6257 0.12095E-10 -10.9174 0.51081E+00 -0.2917 11 Fe++ 0.63315E-13 -13.1985 0.32378E-13 -13.4897 0.51138E+00 -0.2913 12 K+ 0.16012E-03 -3.7955 0.13382E-03 -3.8735 0.83570E+00 -0.0779 13 Na+ 0.20357E-01 -1.6913 0.16980E-01 -1.7701 0.83411E+00 -0.0788 14 Mn++ 0.18963E-10 -10.7221 0.97055E-11 -11.0130 0.51181E+00 -0.2909 15 HPO4-- 0.52744E-07 -7.2778 0.27275E-07 -7.5642 0.51712E+00 -0.2864 16 HSiO3- 0.11000E-01 -1.9586 0.91770E-02 -2.0373 0.83427E+00 -0.0787 17 Ca(HSiO3)+ 0.17429E-07 -7.7587 0.14569E-07 -7.8366 0.83589E+00 -0.0779 18 Mg(HSiO3)+ 0.37025E-11 -11.4315 0.30949E-11 -11.5094 0.83589E+00 -0.0779 19 NaHSiO3,aq 0.24749E-02 -2.6064 0.24749E-02 -2.6064 0.10000E+01 0.0000 20 AlO+ 0.66573E-16 -16.1767 0.55647E-16 -16.2546 0.83589E+00 -0.0779 22 HAlO2,aq 0.14446E-09 -9.8403 0.14446E-09 -9.8403 0.10000E+01 0.0000 23 AlO2- 0.50247E-05 -5.2989 0.41843E-05 -5.3784 0.83275E+00 -0.0795 24 CH4,aq 0.11343E-04 -4.9453 0.11303E-04 -4.9468 0.99645E+00 -0.0015 25 C2H6,aq 0.25600E-14 -14.5918 0.25509E-14 -14.5933 0.99645E+00 -0.0015 29 CO,aq 0.18674E-16 -16.7288 0.18674E-16 -16.7288 0.10000E+01 0.0000 30 CO2,aq 0.84249E-10 -10.0744 0.83950E-10 -10.0760 0.99645E+00 -0.0015 31 CO3-2 0.12557E-05 -5.9011 0.64787E-06 -6.1885 0.51593E+00 -0.2874 32 CaCO3,aq 0.56222E-09 -9.2501 0.56222E-09 -9.2501 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.11537E-11 -11.9379 0.96434E-12 -12.0158 0.83589E+00 -0.0779 34 CaCl+ 0.15685E-10 -10.8045 0.13110E-10 -10.8824 0.83589E+00 -0.0779 35 CaCl2,aq 0.35446E-15 -15.4504 0.35446E-15 -15.4504 0.10000E+01 0.0000 36 CaOH+ 0.77538E-07 -7.1105 0.64813E-07 -7.1883 0.83589E+00 -0.0779 37 CaSO4,aq 0.22323E-16 -16.6512 0.22323E-16 -16.6512 0.10000E+01 0.0000 38 HCl,aq 0.16837E-14 -14.7737 0.16837E-14 -14.7737 0.10000E+01 0.0000 43 FeCl+ 0.70054E-17 -17.1546 0.58557E-17 -17.2324 0.83589E+00 -0.0779 46 FeO,aq 0.21547E-09 -9.6666 0.21547E-09 -9.6666 0.10000E+01 0.0000 47 FeOH+ 0.16659E-10 -10.7784 0.13925E-10 -10.8562 0.83589E+00 -0.0779 48 HFeO2- 0.36037E-07 -7.4433 0.30064E-07 -7.5219 0.83427E+00 -0.0787 49 FeO+ 0.13794E-16 -16.8603 0.11531E-16 -16.9381 0.83589E+00 -0.0779 51 FeO2- 0.45713E-09 -9.3400 0.38137E-09 -9.4187 0.83427E+00 -0.0787 52 HFeO2,aq 0.36792E-11 -11.4342 0.36792E-11 -11.4342 0.10000E+01 0.0000 53 H2,aq 0.86673E-05 -5.0621 0.86366E-05 -5.0637 0.99645E+00 -0.0015 54 KCl,aq 0.27513E-09 -9.5605 0.27513E-09 -9.5605 0.10000E+01 0.0000 56 KOH,aq 0.75677E-06 -6.1210 0.75677E-06 -6.1210 0.10000E+01 0.0000 57 KSO4- 0.24987E-14 -14.6023 0.20846E-14 -14.6810 0.83427E+00 -0.0787 58 MgCO3,aq 0.23981E-13 -13.6201 0.23981E-13 -13.6201 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20081E-15 -15.6972 0.16786E-15 -15.7751 0.83589E+00 -0.0779 60 MgCl+ 0.24305E-14 -14.6143 0.20316E-14 -14.6922 0.83589E+00 -0.0779 61 MgOH+ 0.73325E-10 -10.1347 0.61291E-10 -10.2126 0.83589E+00 -0.0779 63 MnO,aq 0.17242E-08 -8.7634 0.17242E-08 -8.7634 0.10000E+01 0.0000 64 MnOH+ 0.46388E-09 -9.3336 0.38775E-09 -9.4114 0.83589E+00 -0.0779 65 MnO2-2 0.19449E-10 -10.7111 0.10034E-10 -10.9985 0.51593E+00 -0.2874 66 HMnO2- 0.20088E-09 -9.6971 0.16759E-09 -9.7757 0.83427E+00 -0.0787 69 MnCl+ 0.81599E-14 -14.0883 0.68208E-14 -14.1662 0.83589E+00 -0.0779 71 NaCl,aq 0.64381E-06 -6.1912 0.64381E-06 -6.1912 0.10000E+01 0.0000 72 NaOH,aq 0.96790E-04 -4.0142 0.96790E-04 -4.0142 0.10000E+01 0.0000 74 OH- 0.93442E-02 -2.0295 0.77813E-02 -2.1089 0.83275E+00 -0.0795 79 HPO3-2 0.14421E-14 -14.8410 0.74403E-15 -15.1284 0.51593E+00 -0.2874 81 H2PO3- 0.13504E-18 -18.8695 0.11266E-18 -18.9482 0.83427E+00 -0.0787 82 H3PO4,aq 0.10434E-17 -17.9815 0.10434E-17 -17.9815 0.10000E+01 0.0000 83 H2PO4- 0.44142E-10 -10.3551 0.36861E-10 -10.4334 0.83507E+00 -0.0783 84 PO4-3 0.12853E-08 -8.8910 0.30900E-09 -9.5100 0.24040E+00 -0.6191 88 HP2O7-3 0.12355E-17 -17.9082 0.28288E-18 -18.5484 0.22897E+00 -0.6402 89 P2O7-4 0.11947E-16 -16.9228 0.90530E-18 -18.0432 0.75779E-01 -1.1205 90 H2S,aq 0.50119E-08 -8.3000 0.49941E-08 -8.3015 0.99645E+00 -0.0015 91 S2-2 0.22949E-14 -14.6392 0.11840E-14 -14.9266 0.51593E+00 -0.2874 97 SO3-2 0.22746E-17 -17.6431 0.11907E-17 -17.9242 0.52350E+00 -0.2811 99 HSO4- 0.86438E-19 -19.0633 0.72323E-19 -19.1407 0.83671E+00 -0.0774 Charge balance for all species = -.7592E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9183608E-10 -.2294031E-01 -.2308075E+02 0.0000 2 H2O 0.1000000E+01 0.5550425E+02 0.9981223E+06 0.0000 3 Cl- 0.1391850E-03 0.1398291E-03 0.4948419E+01 6.1779 4 SO4-- 0.1955658E-11 -.1350961E-04 -.1295414E+01 8.2309 5 HCO3- 0.6464914E-06 0.1324571E-04 0.8067585E+00 3.8455 6 HS- 0.2584233E-04 0.3935695E-04 0.1299266E+01 5.4467 7 Al+++ 0.1119871E-28 0.5024824E-05 0.1353328E+00 0.7476 8 H4SiO4 0.7250605E-03 0.1419996E-01 0.1362373E+04 -3.1396 9 Ca++ 0.1380676E-06 0.2336136E-06 0.9345880E-02 13.0764 10 Mg++ 0.2367732E-10 0.1007314E-09 0.2444566E-05 9.3086 11 Fe++ 0.6331523E-13 0.3672981E-07 0.2047550E-02 6.7363 12 K+ 0.1601231E-03 0.1608801E-03 0.6279389E+01 6.2395 13 Na+ 0.2035701E-01 0.2292933E-01 0.5261900E+03 8.3430 14 Mn++ 0.1896313E-10 0.2427350E-08 0.1331133E-03 9.2131 15 HPO4-- 0.5274410E-07 0.5407358E-07 0.5180568E-02 12.6618 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1920758E+01 -.2263600E-01 -.1898122E+01 0.0000000E+00 2 H2O 0.5405416E+02 0.5476797E+02 -.7138106E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3240232E-02 -.1333040E-04 0.3253563E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3214728E-02 0.3883487E-04 -.3253563E-02 0.0000000E+00 7 Al+++ 0.3782428E+00 0.4958168E-05 0.3782378E+00 0.0000000E+00 8 H4SiO4 0.1207872E+01 0.1401159E-01 0.1193861E+01 0.0000000E+00 9 Ca++ 0.1334299E+00 0.2305146E-06 0.1334296E+00 0.0000000E+00 10 Mg++ 0.9206270E-01 0.9939520E-10 0.9206270E-01 0.0000000E+00 11 Fe++ 0.8270828E-01 0.3624258E-07 0.8270825E-01 0.0000000E+00 12 K+ 0.2462824E-01 0.1587460E-03 0.2446949E-01 0.0000000E+00 13 Na+ 0.1457671E+00 0.2262516E-01 0.1231419E+00 0.0000000E+00 14 Mn++ 0.2011260E-02 0.2395151E-08 0.2011257E-02 0.0000000E+00 15 HPO4-- 0.6864330E-03 0.5335627E-07 0.6863796E-03 0.0000000E+00 Chg. balance for solid moles: -.1470E-15 Mass of aqueous solution: 0.988517E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 115.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1231 -0.910 32.28 1.509 25.51 12.39 andradite 0.1301E-01 -1.886 6.614 0.820 5.226 1.718 grossular 0.2727E-02 -2.564 1.228 0.089 0.9706 0.3418 apatite-OH 0.2288E-03 -3.641 0.1149 -0.940 0.9081E-01 0.3652E-01 clinochlore 0.1814E-01 -1.741 10.08 1.003 7.966 3.834 daphnite 0.5081E-02 -2.294 3.626 0.559 2.865 1.099 chlorite-Mn 0.4023E-03 -3.396 0.2852 -0.545 0.2253 0.9088E-01 microcline 0.2139E-01 -1.670 5.954 0.775 4.704 2.326 stilbite 0.8430E-01 -1.074 59.41 1.774 46.94 27.71 stilpnomelane-Fe 0.6159E-02 -2.210 6.640 0.822 5.247 2.294 tr.625ac.25prg.125 0.3813E-03 -3.419 0.3259 -0.487 0.2575 0.1049 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8268E+00 0.8268E+00 1.0000 -0.083 grossular 0.1732E+00 0.1732E+00 1.0000 -0.761 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7678E+00 0.7678E+00 1.0000 -0.115 daphnite 0.2151E+00 0.2151E+00 1.0000 -0.667 chlorite-Mn 0.1703E-01 0.1703E-01 1.0000 -1.769 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 126.552728 g Volume = 51.943944 cm3 Porosity: -9.5873% V(tot) - V(min): -.45443E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 115.9990000 g log = 2.0645 Original solution: 1000.0103000 g Original solution / Rock added: 8.62 (Water/Rock Ratio), log = 0.9356 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0819 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9727E+00 0.9851 0.1037E+01 0.1052E+01 CO2,gas 0.8819E-08 1.0072 0.9610E-08 0.9541E-08 CH4,gas 0.1631E-01 1.0128 0.1787E-01 0.1765E-01 H2,gas 0.1094E-01 1.0006 0.1185E-01 0.1184E-01 H2S,gas 0.1352E-06 0.9958 0.1457E-06 0.1463E-06 S2,gas 0.5235E-29 1.0000 0.5663E-29 0.5663E-29 CO,gas 0.2726E-13 1.0000 0.2949E-13 0.2949E-13 SO3,gas 0.2076E-47 1.0000 0.2246E-47 0.2246E-47 SO2,gas 0.9305E-27 1.0000 0.1007E-26 0.1007E-26 HCl,gas 0.2748E-17 1.0000 0.2973E-17 0.2973E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.38 -10.02 -3.339 0.17104E+05 -8.017 3 CH4,gas 4.81 1.06 -3.75 -0.937 0.63992E+04 -1.748 4 H2,gas 8.29 4.36 -3.93 -2.244 0.67043E+04 -1.926 5 H2S,gas -5.94 -14.78 -8.84 -4.418 0.15088E+05 -6.837 6 S2,gas -7.03 -38.28 -31.25 -4.807 0.53353E+05 -29.247 7 CO,gas 3.51 -12.02 -15.53 -4.779 0.26518E+05 -13.530 8 SO3,gas 17.43 -32.22 -49.65 -12.412 0.84774E+05 -47.649 9 SO2,gas 1.14 -27.86 -29.00 -7.733 0.49512E+05 -26.997 10 HCl,gas 5.48 -14.05 -19.53 -9.763 0.33342E+05 -17.527 11 acmite 7.74 6.62 -1.12 -0.116 0.19083E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.72 -4.83 -0.242 0.82547E+04 20 analcite 3.37 2.81 -0.56 -0.062 0.95511E+03 26 annite 20.21 17.78 -2.43 -0.135 0.41530E+04 27 phlogopite 27.15 25.49 -1.65 -0.092 0.28215E+04 29 anorthite 12.80 8.29 -4.51 -0.347 0.76929E+04 35 aragonite 0.99 -3.30 -4.29 -1.430 0.73256E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55800E+04 37 calcite 0.83 -3.30 -4.14 -1.379 0.70643E+04 38 carnegieite-low 9.06 5.95 -3.11 -0.445 0.53165E+04 39 carnegieite-high 10.13 5.95 -4.18 -0.598 0.71434E+04 40 carpholite-Mg 8.65 4.52 -4.13 -0.275 0.70448E+04 41 carpholite-Fe 6.78 1.95 -4.83 -0.322 0.82484E+04 42 celadonite 5.40 3.74 -1.66 -0.098 0.28400E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47332E+04 44 chrysotile 23.94 21.65 -2.29 -0.191 0.39113E+04 49 chlorite-Al-free 47.26 43.29 -3.97 -0.165 0.67758E+04 51 chloritoid-Fe 9.24 5.09 -4.15 -0.276 0.70807E+04 52 chloritoid-Mn 11.46 7.57 -3.89 -0.260 0.66500E+04 54 coesite -2.37 -3.14 -0.77 -0.257 0.13152E+04 61 cristobalite -2.55 -3.14 -0.59 -0.197 0.10081E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.75 -2.15 -0.358 0.36686E+04 66 diamond -3.11 -7.66 -4.55 -1.301 0.77729E+04 67 diopside 16.22 16.11 -0.11 -0.011 0.18725E+03 68 hedenbergite 14.24 13.53 -0.71 -0.071 0.12139E+04 71 enstatite 17.30 12.34 -4.96 -0.496 0.84741E+04 73 clinoenstatite 17.20 12.34 -4.86 -0.486 0.83049E+04 75 epidote 24.78 22.79 -1.99 -0.096 0.33980E+04 76 clinozoisite 22.92 18.98 -3.94 -0.179 0.67352E+04 77 epidote-Fe 29.94 26.59 -3.34 -0.174 0.57083E+04 78 fayalite 14.08 10.33 -3.75 -0.535 0.63962E+04 79 ferrosilite 11.19 7.19 -3.99 -0.399 0.68202E+04 83 gibbsite 4.10 0.75 -3.35 -0.479 0.57197E+04 84 glaucophane 23.11 20.99 -2.12 -0.057 0.36208E+04 85 glaucophane-Fe 17.42 13.27 -4.14 -0.112 0.70762E+04 86 graphite -3.55 -7.66 -4.11 -1.175 0.70190E+04 87 greenalite 16.19 13.93 -2.26 -0.189 0.38667E+04 90 hematite 12.60 9.11 -3.49 -0.422 0.59514E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.81 -1.44 -0.144 0.24581E+04 97 kalsilite 7.62 3.85 -3.77 -0.539 0.64420E+04 98 kaolinite -1.27 -4.78 -3.51 -0.319 0.59949E+04 101 laumontite 2.97 2.01 -0.96 -0.064 0.16418E+04 102 lawsonite 9.68 8.29 -1.39 -0.092 0.23667E+04 103 leucite 4.17 0.71 -3.46 -0.346 0.59075E+04 105 lizardite 23.29 21.65 -1.64 -0.137 0.28015E+04 107 magnetite 20.13 15.85 -4.28 -0.350 0.73154E+04 108 minnesotaite 10.46 7.65 -2.81 -0.165 0.47986E+04 112 manganosite 14.07 9.21 -4.85 -1.214 0.82896E+04 120 muscovite 2.68 -0.94 -3.62 -0.213 0.61740E+04 121 paragonite 4.34 1.17 -3.17 -0.186 0.54125E+04 122 nepheline 8.38 5.95 -2.43 -0.347 0.41444E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.226 0.83715E+04 134 phlogopite-Na 29.73 27.60 -2.13 -0.119 0.36434E+04 136 prehnite 19.47 18.23 -1.24 -0.073 0.21126E+04 137 prehnite-Fe 22.59 22.04 -0.55 -0.033 0.93773E+03 138 pumpellyite-Fe 46.47 43.94 -2.53 -0.056 0.43175E+04 139 pumpellyite-Mg 49.19 46.51 -2.68 -0.060 0.45756E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64875E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.42 -1.260 0.58477E+04 145 pyroxmangite 7.42 6.07 -1.34 -0.269 0.22924E+04 146 pyrophyllite -6.10 -11.06 -4.97 -0.310 0.84782E+04 147 quartz -2.98 -3.14 -0.16 -0.053 0.26914E+03 152 rhodonite 7.46 6.07 -1.39 -0.278 0.23717E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 26.04 -1.56 -0.046 0.26555E+04 171 talc 16.55 15.37 -1.19 -0.070 0.20250E+04 174 tephroite 18.11 15.29 -2.83 -0.404 0.48260E+04 178 tridymite -2.61 -3.14 -0.53 -0.175 0.89644E+03 179 tremolite 48.00 47.58 -0.42 -0.011 0.72423E+03 180 ferroactinolite 38.60 34.72 -3.88 -0.105 0.66236E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62307E+04 187 wairakite 4.06 2.01 -2.05 -0.120 0.34926E+04 188 walstromite 11.53 9.94 -1.59 -0.318 0.27167E+04 189 wollastonite 10.48 9.94 -0.55 -0.109 0.93062E+03 190 pseudo-wollastonite 11.02 9.94 -1.08 -0.217 0.18492E+04 191 zoisite 22.96 18.98 -3.99 -0.181 0.68077E+04 192 akaganeite 7.77 4.56 -3.21 -0.694 0.54838E+04 199 chalcedony -2.79 -3.14 -0.35 -0.115 0.58946E+03 201 montmorillonite-Ca -2.21 -6.08 -3.87 -0.239 0.66021E+04 202 montmorillonite-K -2.16 -6.18 -4.02 -0.246 0.68610E+04 203 montmorillonite-Mg -2.40 -6.70 -4.30 -0.266 0.73433E+04 204 montmorillonite-Na -1.96 -5.49 -3.52 -0.216 0.60179E+04 205 nontronite-Ca 3.28 -0.01 -3.29 -0.213 0.56102E+04 206 nontronite-H 2.60 -2.16 -4.76 -0.319 0.81264E+04 207 nontronite-K 3.40 -0.10 -3.51 -0.225 0.59905E+04 208 nontronite-Mg 3.14 -0.63 -3.77 -0.244 0.64319E+04 209 nontronite-Na 3.58 0.59 -2.99 -0.192 0.51109E+04 224 tobermorite 9.84 7.75 -2.09 -0.569 0.35617E+04 230 alabandite -0.96 -5.57 -4.60 -1.535 0.78610E+04 233 boehmite 4.43 0.75 -3.68 -0.614 0.62870E+04 235 ferrous-oxide 9.82 6.74 -3.09 -0.772 0.52725E+04 240 silica-amorphous -2.08 -3.14 -1.06 -0.353 0.18097E+04 242 an20ab80 2.08 1.40 -0.68 -0.053 0.11670E+04 243 an25ab75 2.71 1.83 -0.88 -0.068 0.15066E+04 244 an30ab70 3.34 2.26 -1.09 -0.084 0.18546E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 115.9990000 g New total amount of reactant added: 119.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7297E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 119.9990000 Water: Moles liquid = 0.5475E+02 kg liquid = 0.9863E+00 Moles total = 0.5400E+02 kg total = 0.9729E+00 Activity = 1.0000 Stoichiometric ionic strength = .1164883E-01 Osmotic coef. = 0.9682 True ionic strength = .2053800E-01 Chg. balance for total moles = -.7297E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91647E-10 -10.0379 0.76923E-10 -10.1139 0.83934E+00 -0.0761 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13924E-03 -3.8562 0.11616E-03 -3.9350 0.83422E+00 -0.0787 4 SO4-- 0.17606E-11 -11.7543 0.91011E-12 -12.0409 0.51692E+00 -0.2866 5 HCO3- 0.59034E-06 -6.2289 0.49320E-06 -6.3070 0.83545E+00 -0.0781 6 HS- 0.25853E-04 -4.5875 0.21570E-04 -4.6661 0.83434E+00 -0.0787 7 Al+++ 0.11177E-28 -28.9517 0.25550E-29 -29.5926 0.22860E+00 -0.6409 8 H4SiO4 0.72341E-03 -3.1406 0.72341E-03 -3.1406 0.10000E+01 0.0000 9 Ca++ 0.13866E-06 -6.8581 0.71140E-07 -7.1479 0.51306E+00 -0.2898 10 Mg++ 0.23564E-10 -10.6277 0.12034E-10 -10.9196 0.51068E+00 -0.2918 11 Fe++ 0.63178E-13 -13.1994 0.32300E-13 -13.4908 0.51125E+00 -0.2914 12 K+ 0.16027E-03 -3.7951 0.13393E-03 -3.8731 0.83565E+00 -0.0780 13 Na+ 0.20376E-01 -1.6909 0.16995E-01 -1.7697 0.83406E+00 -0.0788 14 Mn++ 0.18954E-10 -10.7223 0.96984E-11 -11.0133 0.51168E+00 -0.2910 15 HPO4-- 0.52257E-07 -7.2819 0.27017E-07 -7.5684 0.51699E+00 -0.2865 16 HSiO3- 0.10999E-01 -1.9586 0.91755E-02 -2.0374 0.83422E+00 -0.0787 17 Ca(HSiO3)+ 0.17497E-07 -7.7570 0.14625E-07 -7.8349 0.83583E+00 -0.0779 18 Mg(HSiO3)+ 0.36835E-11 -11.4337 0.30788E-11 -11.5116 0.83583E+00 -0.0779 19 NaHSiO3,aq 0.24766E-02 -2.6061 0.24766E-02 -2.6061 0.10000E+01 0.0000 20 AlO+ 0.66692E-16 -16.1759 0.55743E-16 -16.2538 0.83583E+00 -0.0779 22 HAlO2,aq 0.14501E-09 -9.8386 0.14501E-09 -9.8386 0.10000E+01 0.0000 23 AlO2- 0.50550E-05 -5.2963 0.42093E-05 -5.3758 0.83270E+00 -0.0795 24 CH4,aq 0.11511E-04 -4.9389 0.11470E-04 -4.9404 0.99645E+00 -0.0015 25 C2H6,aq 0.25663E-14 -14.5907 0.25572E-14 -14.5922 0.99645E+00 -0.0015 29 CO,aq 0.17479E-16 -16.7575 0.17479E-16 -16.7575 0.10000E+01 0.0000 30 CO2,aq 0.76764E-10 -10.1148 0.76491E-10 -10.1164 0.99645E+00 -0.0015 31 CO3-2 0.11493E-05 -5.9396 0.59281E-06 -6.2271 0.51580E+00 -0.2875 32 CaCO3,aq 0.51651E-09 -9.2869 0.51651E-09 -9.2869 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10577E-11 -11.9756 0.88407E-12 -12.0535 0.83583E+00 -0.0779 34 CaCl+ 0.15754E-10 -10.8026 0.13168E-10 -10.8805 0.83583E+00 -0.0779 35 CaCl2,aq 0.35613E-15 -15.4484 0.35613E-15 -15.4484 0.10000E+01 0.0000 36 CaOH+ 0.78020E-07 -7.1078 0.65212E-07 -7.1857 0.83583E+00 -0.0779 37 CaSO4,aq 0.20173E-16 -16.6952 0.20173E-16 -16.6952 0.10000E+01 0.0000 38 HCl,aq 0.16807E-14 -14.7745 0.16807E-14 -14.7745 0.10000E+01 0.0000 43 FeCl+ 0.69912E-17 -17.1554 0.58435E-17 -17.2333 0.83583E+00 -0.0779 46 FeO,aq 0.21586E-09 -9.6658 0.21586E-09 -9.6658 0.10000E+01 0.0000 47 FeOH+ 0.16655E-10 -10.7785 0.13920E-10 -10.8563 0.83583E+00 -0.0779 48 HFeO2- 0.36181E-07 -7.4415 0.30183E-07 -7.5202 0.83422E+00 -0.0787 49 FeO+ 0.13607E-16 -16.8663 0.11373E-16 -16.9441 0.83583E+00 -0.0779 51 FeO2- 0.45282E-09 -9.3441 0.37775E-09 -9.4228 0.83422E+00 -0.0787 52 HFeO2,aq 0.36366E-11 -11.4393 0.36366E-11 -11.4393 0.10000E+01 0.0000 53 H2,aq 0.89040E-05 -5.0504 0.88724E-05 -5.0520 0.99645E+00 -0.0015 54 KCl,aq 0.27546E-09 -9.5599 0.27546E-09 -9.5599 0.10000E+01 0.0000 56 KOH,aq 0.75903E-06 -6.1197 0.75903E-06 -6.1197 0.10000E+01 0.0000 57 KSO4- 0.22511E-14 -14.6476 0.18779E-14 -14.7263 0.83422E+00 -0.0787 58 MgCO3,aq 0.21832E-13 -13.6609 0.21832E-13 -13.6609 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18245E-15 -15.7389 0.15250E-15 -15.8167 0.83583E+00 -0.0779 60 MgCl+ 0.24192E-14 -14.6163 0.20221E-14 -14.6942 0.83583E+00 -0.0779 61 MgOH+ 0.73115E-10 -10.1360 0.61112E-10 -10.2139 0.83583E+00 -0.0779 63 MnO,aq 0.17302E-08 -8.7619 0.17302E-08 -8.7619 0.10000E+01 0.0000 64 MnOH+ 0.46455E-09 -9.3330 0.38829E-09 -9.4108 0.83583E+00 -0.0779 65 MnO2-2 0.19605E-10 -10.7076 0.10112E-10 -10.9952 0.51580E+00 -0.2875 66 HMnO2- 0.20203E-09 -9.6946 0.16854E-09 -9.7733 0.83422E+00 -0.0787 69 MnCl+ 0.81572E-14 -14.0885 0.68181E-14 -14.1663 0.83583E+00 -0.0779 71 NaCl,aq 0.64458E-06 -6.1907 0.64458E-06 -6.1907 0.10000E+01 0.0000 72 NaOH,aq 0.97079E-04 -4.0129 0.97079E-04 -4.0129 0.10000E+01 0.0000 74 OH- 0.93645E-02 -2.0285 0.77978E-02 -2.1080 0.83270E+00 -0.0795 79 HPO3-2 0.14678E-14 -14.8333 0.75711E-15 -15.1208 0.51580E+00 -0.2875 81 H2PO3- 0.13714E-18 -18.8628 0.11440E-18 -18.9416 0.83422E+00 -0.0787 82 H3PO4,aq 0.10292E-17 -17.9875 0.10292E-17 -17.9875 0.10000E+01 0.0000 83 H2PO4- 0.43634E-10 -10.3602 0.36435E-10 -10.4385 0.83502E+00 -0.0783 84 PO4-3 0.12765E-08 -8.8940 0.30672E-09 -9.5133 0.24028E+00 -0.6193 88 HP2O7-3 0.12103E-17 -17.9171 0.27696E-18 -18.5576 0.22884E+00 -0.6405 89 P2O7-4 0.11733E-16 -16.9306 0.88823E-18 -18.0515 0.75706E-01 -1.1209 90 H2S,aq 0.50031E-08 -8.3008 0.49853E-08 -8.3023 0.99645E+00 -0.0015 91 S2-2 0.22360E-14 -14.6505 0.11534E-14 -14.9380 0.51580E+00 -0.2875 97 SO3-2 0.21036E-17 -17.6770 0.11010E-17 -17.9582 0.52338E+00 -0.2812 99 HSO4- 0.77640E-19 -19.1099 0.64958E-19 -19.1874 0.83666E+00 -0.0775 Charge balance for all species = -.7499E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9164725E-10 -.2296175E-01 -.2310231E+02 0.0000 2 H2O 0.1000000E+01 0.5550427E+02 0.9981220E+06 0.0000 3 Cl- 0.1392410E-03 0.1398858E-03 0.4950424E+01 6.1790 4 SO4-- 0.1760648E-11 -.1373680E-04 -.1317198E+01 8.1870 5 HCO3- 0.5903354E-06 0.1325109E-04 0.8070854E+00 3.8070 6 HS- 0.2585283E-04 0.3959464E-04 0.1307111E+01 5.4478 7 Al+++ 0.1117691E-28 0.5055180E-05 0.1361502E+00 0.7492 8 H4SiO4 0.7234119E-03 0.1419899E-01 0.1362279E+04 -3.1406 9 Ca++ 0.1386577E-06 0.2347081E-06 0.9389661E-02 13.0800 10 Mg++ 0.2356422E-10 0.1003876E-09 0.2436220E-05 9.3083 11 Fe++ 0.6317768E-13 0.3686974E-07 0.2055349E-02 6.7371 12 K+ 0.1602722E-03 0.1610316E-03 0.6285295E+01 6.2408 13 Na+ 0.2037601E-01 0.2295037E-01 0.5266725E+03 8.3443 14 Mn++ 0.1895398E-10 0.2435354E-08 0.1335521E-03 9.2146 15 HPO4-- 0.5225729E-07 0.5357745E-07 0.5133032E-02 12.6595 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1986992E+01 -.2264796E-01 -.1964344E+01 0.0000000E+00 2 H2O 0.5400401E+02 0.5474576E+02 -.7417464E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3351086E-02 -.1354908E-04 0.3364635E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3325581E-02 0.3905355E-04 -.3364635E-02 0.0000000E+00 7 Al+++ 0.3912857E+00 0.4986097E-05 0.3912807E+00 0.0000000E+00 8 H4SiO4 0.1249524E+01 0.1400495E-01 0.1235519E+01 0.0000000E+00 9 Ca++ 0.1380304E+00 0.2315007E-06 0.1380302E+00 0.0000000E+00 10 Mg++ 0.9523730E-01 0.9901571E-10 0.9523730E-01 0.0000000E+00 11 Fe++ 0.8556032E-01 0.3636588E-07 0.8556028E-01 0.0000000E+00 12 K+ 0.2547749E-01 0.1588309E-03 0.2531866E-01 0.0000000E+00 13 Na+ 0.1507881E+00 0.2263674E-01 0.1281513E+00 0.0000000E+00 14 Mn++ 0.2080614E-02 0.2402073E-08 0.2080612E-02 0.0000000E+00 15 HPO4-- 0.7101033E-03 0.5284527E-07 0.7100504E-03 0.0000000E+00 Chg. balance for solid moles: 0.1756E-15 Mass of aqueous solution: 0.988117E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 119.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1281 -0.892 33.59 1.526 25.65 12.89 andradite 0.1346E-01 -1.871 6.839 0.835 5.224 1.777 grossular 0.2864E-02 -2.543 1.290 0.111 0.9854 0.3590 apatite-OH 0.2367E-03 -3.626 0.1189 -0.925 0.9081E-01 0.3778E-01 clinochlore 0.1868E-01 -1.729 10.38 1.016 7.931 3.950 daphnite 0.5248E-02 -2.280 3.744 0.573 2.860 1.135 chlorite-Mn 0.4161E-03 -3.381 0.2950 -0.530 0.2253 0.9401E-01 microcline 0.2214E-01 -1.655 6.163 0.790 4.707 2.407 stilbite 0.8687E-01 -1.061 61.22 1.787 46.76 28.55 stilpnomelane-Fe 0.6355E-02 -2.197 6.850 0.836 5.232 2.366 tr.625ac.25prg.125 0.5056E-03 -3.296 0.4322 -0.364 0.3301 0.1391 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8245E+00 0.8245E+00 1.0000 -0.084 grossular 0.1755E+00 0.1755E+00 1.0000 -0.756 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7674E+00 0.7674E+00 1.0000 -0.115 daphnite 0.2156E+00 0.2156E+00 1.0000 -0.666 chlorite-Mn 0.1709E-01 0.1709E-01 1.0000 -1.767 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 130.920792 g Volume = 53.710750 cm3 Porosity: -9.6147% V(tot) - V(min): -.47111E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 119.9990000 g log = 2.0792 Original solution: 1000.0103000 g Original solution / Rock added: 8.33 (Water/Rock Ratio), log = 0.9208 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0824 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9722E+00 0.9851 0.1037E+01 0.1052E+01 CO2,gas 0.8031E-08 1.0072 0.8756E-08 0.8694E-08 CH4,gas 0.1654E-01 1.0128 0.1814E-01 0.1791E-01 H2,gas 0.1124E-01 1.0006 0.1217E-01 0.1216E-01 H2S,gas 0.1349E-06 0.9958 0.1454E-06 0.1460E-06 S2,gas 0.4940E-29 1.0000 0.5347E-29 0.5347E-29 CO,gas 0.2550E-13 1.0000 0.2760E-13 0.2760E-13 SO3,gas 0.1860E-47 1.0000 0.2013E-47 0.2013E-47 SO2,gas 0.8562E-27 1.0000 0.9268E-27 0.9268E-27 HCl,gas 0.2742E-17 1.0000 0.2968E-17 0.2968E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.42 -10.06 -3.353 0.17173E+05 -8.058 3 CH4,gas 4.81 1.07 -3.74 -0.935 0.63883E+04 -1.741 4 H2,gas 8.29 4.37 -3.91 -2.237 0.66843E+04 -1.915 5 H2S,gas -5.94 -14.78 -8.84 -4.419 0.15090E+05 -6.837 6 S2,gas -7.03 -38.30 -31.27 -4.811 0.53396E+05 -29.272 7 CO,gas 3.51 -12.05 -15.56 -4.787 0.26567E+05 -13.559 8 SO3,gas 17.43 -32.27 -49.70 -12.424 0.84855E+05 -47.696 9 SO2,gas 1.14 -27.90 -29.03 -7.742 0.49573E+05 -27.033 10 HCl,gas 5.48 -14.05 -19.53 -9.764 0.33343E+05 -17.528 11 acmite 7.74 6.61 -1.12 -0.117 0.19181E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.72 -4.83 -0.241 0.82463E+04 20 analcite 3.37 2.81 -0.56 -0.062 0.95343E+03 26 annite 20.21 17.78 -2.43 -0.135 0.41489E+04 27 phlogopite 27.15 25.49 -1.65 -0.092 0.28233E+04 29 anorthite 12.80 8.30 -4.50 -0.346 0.76844E+04 35 aragonite 0.99 -3.34 -4.33 -1.442 0.73885E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55806E+04 37 calcite 0.83 -3.34 -4.17 -1.391 0.71271E+04 38 carnegieite-low 9.06 5.95 -3.11 -0.445 0.53131E+04 39 carnegieite-high 10.13 5.95 -4.18 -0.597 0.71400E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70431E+04 41 carpholite-Fe 6.78 1.95 -4.83 -0.322 0.82447E+04 42 celadonite 5.40 3.74 -1.66 -0.098 0.28423E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47336E+04 44 chrysotile 23.94 21.64 -2.29 -0.191 0.39164E+04 49 chlorite-Al-free 47.26 43.29 -3.97 -0.166 0.67862E+04 51 chloritoid-Fe 9.24 5.09 -4.14 -0.276 0.70754E+04 52 chloritoid-Mn 11.46 7.57 -3.89 -0.259 0.66434E+04 54 coesite -2.37 -3.14 -0.77 -0.257 0.13169E+04 61 cristobalite -2.55 -3.14 -0.59 -0.197 0.10098E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.75 -2.15 -0.358 0.36657E+04 66 diamond -3.11 -7.68 -4.57 -1.306 0.78019E+04 67 diopside 16.22 16.11 -0.11 -0.011 0.18511E+03 68 hedenbergite 14.24 13.54 -0.71 -0.071 0.12099E+04 71 enstatite 17.30 12.34 -4.97 -0.497 0.84787E+04 73 clinoenstatite 17.20 12.34 -4.87 -0.487 0.83095E+04 75 epidote 24.78 22.79 -1.99 -0.096 0.33938E+04 76 clinozoisite 22.92 18.99 -3.94 -0.179 0.67195E+04 77 epidote-Fe 29.94 26.59 -3.35 -0.174 0.57156E+04 78 fayalite 14.08 10.33 -3.75 -0.535 0.63952E+04 79 ferrosilite 11.19 7.19 -3.99 -0.399 0.68209E+04 83 gibbsite 4.10 0.75 -3.35 -0.478 0.57169E+04 84 glaucophane 23.11 20.99 -2.12 -0.057 0.36260E+04 85 glaucophane-Fe 17.42 13.27 -4.14 -0.112 0.70756E+04 86 graphite -3.55 -7.68 -4.13 -1.179 0.70481E+04 87 greenalite 16.19 13.93 -2.26 -0.189 0.38660E+04 90 hematite 12.60 9.10 -3.50 -0.424 0.59687E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.81 -1.44 -0.144 0.24565E+04 97 kalsilite 7.62 3.85 -3.77 -0.539 0.64386E+04 98 kaolinite -1.27 -4.78 -3.51 -0.319 0.59926E+04 101 laumontite 2.97 2.02 -0.96 -0.064 0.16367E+04 102 lawsonite 9.68 8.30 -1.38 -0.092 0.23583E+04 103 leucite 4.17 0.71 -3.46 -0.346 0.59058E+04 105 lizardite 23.29 21.64 -1.64 -0.137 0.28067E+04 107 magnetite 20.13 15.84 -4.29 -0.351 0.73314E+04 108 minnesotaite 10.46 7.65 -2.81 -0.165 0.48013E+04 112 manganosite 14.07 9.21 -4.85 -1.213 0.82870E+04 120 muscovite 2.68 -0.93 -3.61 -0.213 0.61683E+04 121 paragonite 4.34 1.17 -3.17 -0.186 0.54068E+04 122 nepheline 8.38 5.95 -2.43 -0.346 0.41411E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.226 0.83701E+04 134 phlogopite-Na 29.73 27.60 -2.13 -0.119 0.36452E+04 136 prehnite 19.47 18.24 -1.23 -0.072 0.20997E+04 137 prehnite-Fe 22.59 22.04 -0.55 -0.033 0.93636E+03 138 pumpellyite-Fe 46.47 43.96 -2.51 -0.056 0.42876E+04 139 pumpellyite-Mg 49.19 46.53 -2.66 -0.059 0.45476E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64875E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.260 0.58503E+04 145 pyroxmangite 7.42 6.07 -1.34 -0.268 0.22915E+04 146 pyrophyllite -6.10 -11.06 -4.97 -0.310 0.84793E+04 147 quartz -2.98 -3.14 -0.16 -0.053 0.27083E+03 152 rhodonite 7.46 6.07 -1.39 -0.278 0.23708E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 26.04 -1.56 -0.047 0.26652E+04 171 talc 16.55 15.36 -1.19 -0.070 0.20335E+04 174 tephroite 18.11 15.29 -2.82 -0.403 0.48225E+04 178 tridymite -2.61 -3.14 -0.53 -0.175 0.89812E+03 179 tremolite 48.00 47.58 -0.43 -0.012 0.72849E+03 180 ferroactinolite 38.60 34.72 -3.88 -0.105 0.66181E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62306E+04 187 wairakite 4.06 2.02 -2.04 -0.120 0.34875E+04 188 walstromite 11.53 9.94 -1.59 -0.318 0.27123E+04 189 wollastonite 10.48 9.94 -0.54 -0.108 0.92619E+03 190 pseudo-wollastonite 11.02 9.94 -1.08 -0.216 0.18448E+04 191 zoisite 22.96 18.99 -3.98 -0.181 0.67920E+04 192 akaganeite 7.77 4.55 -3.22 -0.696 0.54925E+04 199 chalcedony -2.79 -3.14 -0.35 -0.115 0.59115E+03 201 montmorillonite-Ca -2.21 -6.08 -3.87 -0.239 0.66033E+04 202 montmorillonite-K -2.16 -6.18 -4.02 -0.246 0.68625E+04 203 montmorillonite-Mg -2.40 -6.70 -4.30 -0.266 0.73456E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60193E+04 205 nontronite-Ca 3.28 -0.02 -3.30 -0.214 0.56317E+04 206 nontronite-H 2.60 -2.18 -4.77 -0.320 0.81490E+04 207 nontronite-K 3.40 -0.12 -3.52 -0.226 0.60123E+04 208 nontronite-Mg 3.14 -0.64 -3.78 -0.245 0.64546E+04 209 nontronite-Na 3.58 0.58 -3.01 -0.193 0.51327E+04 224 tobermorite 9.84 7.76 -2.08 -0.569 0.35583E+04 230 alabandite -0.96 -5.57 -4.60 -1.534 0.78597E+04 233 boehmite 4.43 0.75 -3.68 -0.613 0.62842E+04 235 ferrous-oxide 9.82 6.74 -3.09 -0.772 0.52712E+04 240 silica-amorphous -2.08 -3.14 -1.06 -0.354 0.18113E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11653E+04 243 an25ab75 2.71 1.83 -0.88 -0.068 0.15045E+04 244 an30ab70 3.34 2.26 -1.08 -0.083 0.18521E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 119.9990000 g New total amount of reactant added: 123.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7249E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 123.9990000 Water: Moles liquid = 0.5473E+02 kg liquid = 0.9859E+00 Moles total = 0.5395E+02 kg total = 0.9720E+00 Activity = 1.0000 Stoichiometric ionic strength = .1165855E-01 Osmotic coef. = 0.9683 True ionic strength = .2055572E-01 Chg. balance for total moles = -.7249E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91473E-10 -10.0387 0.76773E-10 -10.1148 0.83930E+00 -0.0761 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13930E-03 -3.8561 0.11620E-03 -3.9348 0.83417E+00 -0.0787 4 SO4-- 0.15968E-11 -11.7968 0.82520E-12 -12.0834 0.51680E+00 -0.2867 5 HCO3- 0.54189E-06 -6.2661 0.45270E-06 -6.3442 0.83541E+00 -0.0781 6 HS- 0.25863E-04 -4.5873 0.21578E-04 -4.6660 0.83429E+00 -0.0787 7 Al+++ 0.11157E-28 -28.9525 0.25491E-29 -29.5936 0.22848E+00 -0.6412 8 H4SiO4 0.72189E-03 -3.1415 0.72189E-03 -3.1415 0.10000E+01 0.0000 9 Ca++ 0.13921E-06 -6.8563 0.71406E-07 -7.1463 0.51294E+00 -0.2899 10 Mg++ 0.23460E-10 -10.6297 0.11978E-10 -10.9216 0.51056E+00 -0.2920 11 Fe++ 0.63051E-13 -13.2003 0.32227E-13 -13.4918 0.51113E+00 -0.2915 12 K+ 0.16041E-03 -3.7948 0.13404E-03 -3.8728 0.83560E+00 -0.0780 13 Na+ 0.20394E-01 -1.6905 0.17009E-01 -1.7693 0.83401E+00 -0.0788 14 Mn++ 0.18947E-10 -10.7225 0.96923E-11 -11.0136 0.51156E+00 -0.2911 15 HPO4-- 0.51810E-07 -7.2856 0.26779E-07 -7.5722 0.51687E+00 -0.2866 16 HSiO3- 0.10998E-01 -1.9587 0.91741E-02 -2.0374 0.83417E+00 -0.0787 17 Ca(HSiO3)+ 0.17561E-07 -7.7554 0.14677E-07 -7.8334 0.83579E+00 -0.0779 18 Mg(HSiO3)+ 0.36660E-11 -11.4358 0.30640E-11 -11.5137 0.83579E+00 -0.0779 19 NaHSiO3,aq 0.24783E-02 -2.6059 0.24783E-02 -2.6059 0.10000E+01 0.0000 20 AlO+ 0.66802E-16 -16.1752 0.55832E-16 -16.2531 0.83579E+00 -0.0779 22 HAlO2,aq 0.14553E-09 -9.8371 0.14553E-09 -9.8371 0.10000E+01 0.0000 23 AlO2- 0.50833E-05 -5.2939 0.42326E-05 -5.3734 0.83265E+00 -0.0795 24 CH4,aq 0.11657E-04 -4.9334 0.11615E-04 -4.9350 0.99645E+00 -0.0015 25 C2H6,aq 0.25667E-14 -14.5906 0.25575E-14 -14.5922 0.99645E+00 -0.0015 29 CO,aq 0.16419E-16 -16.7847 0.16419E-16 -16.7847 0.10000E+01 0.0000 30 CO2,aq 0.70322E-10 -10.1529 0.70072E-10 -10.1545 0.99645E+00 -0.0015 31 CO3-2 0.10572E-05 -5.9758 0.54519E-06 -6.2634 0.51569E+00 -0.2876 32 CaCO3,aq 0.47680E-09 -9.3217 0.47680E-09 -9.3217 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.97453E-12 -12.0112 0.81450E-12 -12.0891 0.83579E+00 -0.0779 34 CaCl+ 0.15819E-10 -10.8008 0.13221E-10 -10.8787 0.83579E+00 -0.0779 35 CaCl2,aq 0.35771E-15 -15.4465 0.35771E-15 -15.4465 0.10000E+01 0.0000 36 CaOH+ 0.78469E-07 -7.1053 0.65584E-07 -7.1832 0.83579E+00 -0.0779 37 CaSO4,aq 0.18359E-16 -16.7361 0.18359E-16 -16.7361 0.10000E+01 0.0000 38 HCl,aq 0.16780E-14 -14.7752 0.16780E-14 -14.7752 0.10000E+01 0.0000 43 FeCl+ 0.69783E-17 -17.1562 0.58324E-17 -17.2342 0.83579E+00 -0.0779 46 FeO,aq 0.21622E-09 -9.6651 0.21622E-09 -9.6651 0.10000E+01 0.0000 47 FeOH+ 0.16651E-10 -10.7786 0.13917E-10 -10.8565 0.83579E+00 -0.0779 48 HFeO2- 0.36315E-07 -7.4399 0.30293E-07 -7.5187 0.83417E+00 -0.0787 49 FeO+ 0.13434E-16 -16.8718 0.11228E-16 -16.9497 0.83579E+00 -0.0779 51 FeO2- 0.44884E-09 -9.3479 0.37440E-09 -9.4267 0.83417E+00 -0.0787 52 HFeO2,aq 0.35973E-11 -11.4440 0.35973E-11 -11.4440 0.10000E+01 0.0000 53 H2,aq 0.91300E-05 -5.0395 0.90975E-05 -5.0411 0.99645E+00 -0.0015 54 KCl,aq 0.27578E-09 -9.5594 0.27578E-09 -9.5594 0.10000E+01 0.0000 56 KOH,aq 0.76114E-06 -6.1185 0.76114E-06 -6.1185 0.10000E+01 0.0000 57 KSO4- 0.20429E-14 -14.6898 0.17041E-14 -14.7685 0.83417E+00 -0.0787 58 MgCO3,aq 0.19985E-13 -13.6993 0.19985E-13 -13.6993 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16669E-15 -15.7781 0.13932E-15 -15.8560 0.83579E+00 -0.0779 60 MgCl+ 0.24089E-14 -14.6182 0.20134E-14 -14.6961 0.83579E+00 -0.0779 61 MgOH+ 0.72921E-10 -10.1371 0.60947E-10 -10.2150 0.83579E+00 -0.0779 63 MnO,aq 0.17359E-08 -8.7605 0.17359E-08 -8.7605 0.10000E+01 0.0000 64 MnOH+ 0.46520E-09 -9.3324 0.38881E-09 -9.4103 0.83579E+00 -0.0779 65 MnO2-2 0.19752E-10 -10.7044 0.10186E-10 -10.9920 0.51569E+00 -0.2876 66 HMnO2- 0.20311E-09 -9.6923 0.16942E-09 -9.7710 0.83417E+00 -0.0787 69 MnCl+ 0.81554E-14 -14.0886 0.68162E-14 -14.1665 0.83579E+00 -0.0779 71 NaCl,aq 0.64533E-06 -6.1902 0.64533E-06 -6.1902 0.10000E+01 0.0000 72 NaOH,aq 0.97348E-04 -4.0117 0.97348E-04 -4.0117 0.10000E+01 0.0000 74 OH- 0.93835E-02 -2.0276 0.78131E-02 -2.1072 0.83265E+00 -0.0795 79 HPO3-2 0.14922E-14 -14.8262 0.76950E-15 -15.1138 0.51569E+00 -0.2876 81 H2PO3- 0.13911E-18 -18.8566 0.11605E-18 -18.9354 0.83417E+00 -0.0787 82 H3PO4,aq 0.10161E-17 -17.9930 0.10161E-17 -17.9930 0.10000E+01 0.0000 83 H2PO4- 0.43168E-10 -10.3648 0.36044E-10 -10.4432 0.83497E+00 -0.0783 84 PO4-3 0.12684E-08 -8.8967 0.30462E-09 -9.5162 0.24016E+00 -0.6195 88 HP2O7-3 0.11874E-17 -17.9254 0.27158E-18 -18.5661 0.22872E+00 -0.6407 89 P2O7-4 0.11538E-16 -16.9379 0.87269E-18 -18.0591 0.75637E-01 -1.1213 90 H2S,aq 0.49950E-08 -8.3015 0.49773E-08 -8.3030 0.99645E+00 -0.0015 91 S2-2 0.21827E-14 -14.6610 0.11256E-14 -14.9486 0.51569E+00 -0.2876 97 SO3-2 0.19562E-17 -17.7086 0.10236E-17 -17.9899 0.52326E+00 -0.2813 99 HSO4- 0.70262E-19 -19.1533 0.58783E-19 -19.2308 0.83661E+00 -0.0775 Charge balance for all species = -.7551E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9147258E-10 -.2298169E-01 -.2312235E+02 0.0000 2 H2O 0.1000000E+01 0.5550429E+02 0.9981216E+06 0.0000 3 Cl- 0.1392970E-03 0.1399426E-03 0.4952431E+01 6.1800 4 SO4-- 0.1596751E-11 -.1393924E-04 -.1336609E+01 8.1461 5 HCO3- 0.5418874E-06 0.1325647E-04 0.8074125E+00 3.7706 6 HS- 0.2586334E-04 0.3980758E-04 0.1314140E+01 5.4488 7 Al+++ 0.1115674E-28 0.5083476E-05 0.1369123E+00 0.7508 8 H4SiO4 0.7218868E-03 0.1419810E-01 0.1362193E+04 -3.1415 9 Ca++ 0.1392078E-06 0.2357318E-06 0.9430606E-02 13.0833 10 Mg++ 0.2345983E-10 0.1000699E-09 0.2428508E-05 9.3080 11 Fe++ 0.6305055E-13 0.3700001E-07 0.2062610E-02 6.7378 12 K+ 0.1604110E-03 0.1611724E-03 0.6290790E+01 6.2420 13 Na+ 0.2039368E-01 0.2296995E-01 0.5271214E+03 8.3455 14 Mn++ 0.1894657E-10 0.2442937E-08 0.1339678E-03 9.2160 15 HPO4-- 0.5180969E-07 0.5312126E-07 0.5089324E-02 12.6574 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2053226E+01 -.2265842E-01 -.2030568E+01 0.0000000E+00 2 H2O 0.5395387E+02 0.5472356E+02 -.7696875E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3461939E-02 -.1374317E-04 0.3475683E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3436435E-02 0.3924764E-04 -.3475683E-02 0.0000000E+00 7 Al+++ 0.4043287E+00 0.5011972E-05 0.4043237E+00 0.0000000E+00 8 H4SiO4 0.1291175E+01 0.1399839E-01 0.1277176E+01 0.0000000E+00 9 Ca++ 0.1426310E+00 0.2324160E-06 0.1426308E+00 0.0000000E+00 10 Mg++ 0.9841190E-01 0.9866229E-10 0.9841190E-01 0.0000000E+00 11 Fe++ 0.8841235E-01 0.3647957E-07 0.8841232E-01 0.0000000E+00 12 K+ 0.2632675E-01 0.1589054E-03 0.2616785E-01 0.0000000E+00 13 Na+ 0.1558090E+00 0.2264685E-01 0.1331622E+00 0.0000000E+00 14 Mn++ 0.2149969E-02 0.2408574E-08 0.2149966E-02 0.0000000E+00 15 HPO4-- 0.7337736E-03 0.5237406E-07 0.7337212E-03 0.0000000E+00 Chg. balance for solid moles: 0.2147E-15 Mass of aqueous solution: 0.987717E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 123.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1331 -0.876 34.90 1.543 25.79 13.40 andradite 0.1390E-01 -1.857 7.065 0.849 5.222 1.836 grossular 0.3002E-02 -2.523 1.352 0.131 0.9994 0.3762 apatite-OH 0.2446E-03 -3.612 0.1229 -0.911 0.9081E-01 0.3904E-01 clinochlore 0.1923E-01 -1.716 10.69 1.029 7.899 4.065 daphnite 0.5414E-02 -2.267 3.863 0.587 2.855 1.171 chlorite-Mn 0.4300E-03 -3.367 0.3049 -0.516 0.2253 0.9715E-01 microcline 0.2289E-01 -1.640 6.372 0.804 4.710 2.489 stilbite 0.8943E-01 -1.048 63.03 1.800 46.59 29.40 stilpnomelane-Fe 0.6550E-02 -2.184 7.061 0.849 5.219 2.439 tr.625ac.25prg.125 0.6301E-03 -3.201 0.5386 -0.269 0.3981 0.1734 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8224E+00 0.8224E+00 1.0000 -0.085 grossular 0.1776E+00 0.1776E+00 1.0000 -0.751 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7669E+00 0.7669E+00 1.0000 -0.115 daphnite 0.2159E+00 0.2159E+00 1.0000 -0.666 chlorite-Mn 0.1715E-01 0.1715E-01 1.0000 -1.766 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 135.288781 g Volume = 55.477458 cm3 Porosity: -9.6401% V(tot) - V(min): -.48779E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 123.9990000 g log = 2.0934 Original solution: 1000.0103000 g Original solution / Rock added: 8.06 (Water/Rock Ratio), log = 0.9066 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0830 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9717E+00 0.9851 0.1037E+01 0.1052E+01 CO2,gas 0.7354E-08 1.0072 0.8021E-08 0.7964E-08 CH4,gas 0.1675E-01 1.0128 0.1837E-01 0.1814E-01 H2,gas 0.1152E-01 1.0006 0.1248E-01 0.1247E-01 H2S,gas 0.1346E-06 0.9958 0.1452E-06 0.1458E-06 S2,gas 0.4681E-29 1.0000 0.5069E-29 0.5069E-29 CO,gas 0.2394E-13 1.0000 0.2593E-13 0.2593E-13 SO3,gas 0.1679E-47 1.0000 0.1818E-47 0.1818E-47 SO2,gas 0.7926E-27 1.0000 0.8583E-27 0.8583E-27 HCl,gas 0.2736E-17 1.0000 0.2963E-17 0.2963E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 0.18957E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.46 -10.10 -3.365 0.17238E+05 -8.096 3 CH4,gas 4.81 1.07 -3.74 -0.934 0.63790E+04 -1.736 4 H2,gas 8.29 4.38 -3.90 -2.231 0.66657E+04 -1.904 5 H2S,gas -5.94 -14.78 -8.84 -4.419 0.15091E+05 -6.838 6 S2,gas -7.03 -38.33 -31.30 -4.815 0.53435E+05 -29.295 7 CO,gas 3.51 -12.08 -15.59 -4.796 0.26613E+05 -13.586 8 SO3,gas 17.43 -32.31 -49.74 -12.435 0.84930E+05 -47.740 9 SO2,gas 1.14 -27.93 -29.07 -7.751 0.49630E+05 -27.066 10 HCl,gas 5.48 -14.05 -19.53 -9.764 0.33344E+05 -17.528 11 acmite 7.74 6.61 -1.13 -0.117 0.19272E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.72 -4.82 -0.241 0.82384E+04 20 analcite 3.37 2.81 -0.56 -0.062 0.95186E+03 26 annite 20.21 17.78 -2.43 -0.135 0.41452E+04 27 phlogopite 27.15 25.49 -1.65 -0.092 0.28250E+04 29 anorthite 12.80 8.30 -4.50 -0.346 0.76766E+04 35 aragonite 0.99 -3.38 -4.36 -1.454 0.74478E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55811E+04 37 calcite 0.83 -3.38 -4.21 -1.403 0.71865E+04 38 carnegieite-low 9.06 5.95 -3.11 -0.444 0.53100E+04 39 carnegieite-high 10.13 5.95 -4.18 -0.597 0.71368E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70415E+04 41 carpholite-Fe 6.78 1.96 -4.83 -0.322 0.82413E+04 42 celadonite 5.40 3.73 -1.67 -0.098 0.28444E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47339E+04 44 chrysotile 23.94 21.64 -2.30 -0.191 0.39212E+04 49 chlorite-Al-free 47.26 43.28 -3.98 -0.166 0.67958E+04 51 chloritoid-Fe 9.24 5.10 -4.14 -0.276 0.70704E+04 52 chloritoid-Mn 11.46 7.58 -3.89 -0.259 0.66373E+04 54 coesite -2.37 -3.14 -0.77 -0.257 0.13185E+04 61 cristobalite -2.55 -3.14 -0.59 -0.197 0.10114E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.75 -2.15 -0.358 0.36631E+04 66 diamond -3.11 -7.69 -4.59 -1.310 0.78297E+04 67 diopside 16.22 16.11 -0.11 -0.011 0.18312E+03 68 hedenbergite 14.24 13.54 -0.71 -0.071 0.12061E+04 71 enstatite 17.30 12.33 -4.97 -0.497 0.84829E+04 73 clinoenstatite 17.20 12.33 -4.87 -0.487 0.83138E+04 75 epidote 24.78 22.79 -1.99 -0.096 0.33899E+04 76 clinozoisite 22.92 18.99 -3.93 -0.178 0.67049E+04 77 epidote-Fe 29.94 26.59 -3.35 -0.174 0.57224E+04 78 fayalite 14.08 10.33 -3.74 -0.535 0.63943E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68216E+04 83 gibbsite 4.10 0.75 -3.35 -0.478 0.57143E+04 84 glaucophane 23.11 20.98 -2.13 -0.057 0.36308E+04 85 glaucophane-Fe 17.42 13.27 -4.14 -0.112 0.70750E+04 86 graphite -3.55 -7.69 -4.14 -1.184 0.70759E+04 87 greenalite 16.19 13.93 -2.26 -0.189 0.38654E+04 90 hematite 12.60 9.09 -3.51 -0.425 0.59848E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.81 -1.44 -0.144 0.24549E+04 97 kalsilite 7.62 3.85 -3.77 -0.538 0.64354E+04 98 kaolinite -1.27 -4.78 -3.51 -0.319 0.59905E+04 101 laumontite 2.97 2.02 -0.96 -0.064 0.16320E+04 102 lawsonite 9.68 8.30 -1.38 -0.092 0.23505E+04 103 leucite 4.17 0.71 -3.46 -0.346 0.59043E+04 105 lizardite 23.29 21.64 -1.65 -0.137 0.28115E+04 107 magnetite 20.13 15.83 -4.30 -0.351 0.73462E+04 108 minnesotaite 10.46 7.65 -2.81 -0.165 0.48038E+04 112 manganosite 14.07 9.22 -4.85 -1.213 0.82845E+04 120 muscovite 2.68 -0.93 -3.61 -0.212 0.61630E+04 121 paragonite 4.34 1.17 -3.16 -0.186 0.54015E+04 122 nepheline 8.38 5.95 -2.42 -0.346 0.41379E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.225 0.83689E+04 134 phlogopite-Na 29.73 27.60 -2.14 -0.119 0.36469E+04 136 prehnite 19.47 18.24 -1.22 -0.072 0.20878E+04 137 prehnite-Fe 22.59 22.04 -0.55 -0.033 0.93511E+03 138 pumpellyite-Fe 46.47 43.98 -2.49 -0.055 0.42598E+04 139 pumpellyite-Mg 49.19 46.55 -2.65 -0.059 0.45216E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64874E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.261 0.58527E+04 145 pyroxmangite 7.42 6.07 -1.34 -0.268 0.22907E+04 146 pyrophyllite -6.10 -11.06 -4.97 -0.310 0.84803E+04 147 quartz -2.98 -3.14 -0.16 -0.053 0.27240E+03 152 rhodonite 7.46 6.07 -1.39 -0.278 0.23699E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 26.03 -1.57 -0.047 0.26742E+04 171 talc 16.55 15.36 -1.20 -0.070 0.20415E+04 174 tephroite 18.11 15.29 -2.82 -0.403 0.48192E+04 178 tridymite -2.61 -3.14 -0.53 -0.176 0.89969E+03 179 tremolite 48.00 47.57 -0.43 -0.012 0.73245E+03 180 ferroactinolite 38.60 34.72 -3.87 -0.105 0.66131E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62306E+04 187 wairakite 4.06 2.02 -2.04 -0.120 0.34828E+04 188 walstromite 11.53 9.94 -1.59 -0.317 0.27082E+04 189 wollastonite 10.48 9.94 -0.54 -0.108 0.92208E+03 190 pseudo-wollastonite 11.02 9.94 -1.08 -0.216 0.18407E+04 191 zoisite 22.96 18.99 -3.97 -0.180 0.67774E+04 192 akaganeite 7.77 4.55 -3.22 -0.697 0.55005E+04 199 chalcedony -2.79 -3.14 -0.35 -0.116 0.59271E+03 201 montmorillonite-Ca -2.21 -6.08 -3.87 -0.239 0.66044E+04 202 montmorillonite-K -2.16 -6.18 -4.02 -0.246 0.68638E+04 203 montmorillonite-Mg -2.40 -6.70 -4.30 -0.266 0.73477E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60207E+04 205 nontronite-Ca 3.28 -0.03 -3.31 -0.215 0.56517E+04 206 nontronite-H 2.60 -2.19 -4.78 -0.321 0.81700E+04 207 nontronite-K 3.40 -0.13 -3.53 -0.227 0.60326E+04 208 nontronite-Mg 3.14 -0.65 -3.79 -0.246 0.64756E+04 209 nontronite-Na 3.58 0.56 -3.02 -0.194 0.51530E+04 224 tobermorite 9.84 7.76 -2.08 -0.568 0.35552E+04 230 alabandite -0.96 -5.56 -4.60 -1.534 0.78584E+04 233 boehmite 4.43 0.75 -3.68 -0.613 0.62815E+04 235 ferrous-oxide 9.82 6.74 -3.09 -0.772 0.52700E+04 240 silica-amorphous -2.08 -3.14 -1.06 -0.354 0.18129E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11637E+04 243 an25ab75 2.71 1.83 -0.88 -0.068 0.15025E+04 244 an30ab70 3.34 2.26 -1.08 -0.083 0.18497E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 123.9990000 g New total amount of reactant added: 127.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7268E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 127.9990000 Water: Moles liquid = 0.5471E+02 kg liquid = 0.9855E+00 Moles total = 0.5390E+02 kg total = 0.9711E+00 Activity = 1.0000 Stoichiometric ionic strength = .1166762E-01 Osmotic coef. = 0.9684 True ionic strength = .2057225E-01 Chg. balance for total moles = -.7268E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91311E-10 -10.0395 0.76633E-10 -10.1156 0.83925E+00 -0.0761 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13935E-03 -3.8559 0.11624E-03 -3.9347 0.83412E+00 -0.0788 4 SO4-- 0.14577E-11 -11.8363 0.75318E-12 -12.1231 0.51669E+00 -0.2868 5 HCO3- 0.49986E-06 -6.3012 0.41756E-06 -6.3793 0.83536E+00 -0.0781 6 HS- 0.25874E-04 -4.5871 0.21585E-04 -4.6658 0.83425E+00 -0.0787 7 Al+++ 0.11138E-28 -28.9532 0.25436E-29 -29.5946 0.22837E+00 -0.6414 8 H4SiO4 0.72047E-03 -3.1424 0.72047E-03 -3.1424 0.10000E+01 0.0000 9 Ca++ 0.13972E-06 -6.8547 0.71654E-07 -7.1448 0.51283E+00 -0.2900 10 Mg++ 0.23363E-10 -10.6315 0.11926E-10 -10.9235 0.51045E+00 -0.2920 11 Fe++ 0.62933E-13 -13.2011 0.32160E-13 -13.4927 0.51102E+00 -0.2916 12 K+ 0.16054E-03 -3.7944 0.13414E-03 -3.8724 0.83556E+00 -0.0780 13 Na+ 0.20410E-01 -1.6902 0.17021E-01 -1.7690 0.83397E+00 -0.0789 14 Mn++ 0.18941E-10 -10.7226 0.96872E-11 -11.0138 0.51145E+00 -0.2912 15 HPO4-- 0.51397E-07 -7.2891 0.26560E-07 -7.5758 0.51677E+00 -0.2867 16 HSiO3- 0.10997E-01 -1.9587 0.91729E-02 -2.0375 0.83412E+00 -0.0788 17 Ca(HSiO3)+ 0.17621E-07 -7.7540 0.14726E-07 -7.8319 0.83574E+00 -0.0779 18 Mg(HSiO3)+ 0.36498E-11 -11.4377 0.30503E-11 -11.5157 0.83574E+00 -0.0779 19 NaHSiO3,aq 0.24798E-02 -2.6056 0.24798E-02 -2.6056 0.10000E+01 0.0000 20 AlO+ 0.66905E-16 -16.1745 0.55915E-16 -16.2525 0.83574E+00 -0.0779 22 HAlO2,aq 0.14601E-09 -9.8356 0.14601E-09 -9.8356 0.10000E+01 0.0000 23 AlO2- 0.51098E-05 -5.2916 0.42544E-05 -5.3712 0.83260E+00 -0.0796 24 CH4,aq 0.11784E-04 -4.9287 0.11742E-04 -4.9302 0.99644E+00 -0.0015 25 C2H6,aq 0.25625E-14 -14.5913 0.25534E-14 -14.5929 0.99644E+00 -0.0015 29 CO,aq 0.15474E-16 -16.8104 0.15474E-16 -16.8104 0.10000E+01 0.0000 30 CO2,aq 0.64746E-10 -10.1888 0.64516E-10 -10.1903 0.99644E+00 -0.0015 31 CO3-2 0.97715E-06 -6.0100 0.50380E-06 -6.2977 0.51558E+00 -0.2877 32 CaCO3,aq 0.44213E-09 -9.3545 0.44213E-09 -9.3545 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.90206E-12 -12.0448 0.75389E-12 -12.1227 0.83574E+00 -0.0779 34 CaCl+ 0.15880E-10 -10.7991 0.13272E-10 -10.8771 0.83574E+00 -0.0779 35 CaCl2,aq 0.35920E-15 -15.4447 0.35920E-15 -15.4447 0.10000E+01 0.0000 36 CaOH+ 0.78890E-07 -7.1030 0.65932E-07 -7.1809 0.83574E+00 -0.0779 37 CaSO4,aq 0.16815E-16 -16.7743 0.16815E-16 -16.7743 0.10000E+01 0.0000 38 HCl,aq 0.16755E-14 -14.7759 0.16755E-14 -14.7759 0.10000E+01 0.0000 43 FeCl+ 0.69666E-17 -17.1570 0.58223E-17 -17.2349 0.83574E+00 -0.0779 46 FeO,aq 0.21655E-09 -9.6644 0.21655E-09 -9.6644 0.10000E+01 0.0000 47 FeOH+ 0.16647E-10 -10.7787 0.13913E-10 -10.8566 0.83574E+00 -0.0779 48 HFeO2- 0.36440E-07 -7.4384 0.30395E-07 -7.5172 0.83412E+00 -0.0788 49 FeO+ 0.13275E-16 -16.8770 0.11095E-16 -16.9549 0.83574E+00 -0.0779 51 FeO2- 0.44515E-09 -9.3515 0.37131E-09 -9.4303 0.83412E+00 -0.0788 52 HFeO2,aq 0.35611E-11 -11.4484 0.35611E-11 -11.4484 0.10000E+01 0.0000 53 H2,aq 0.93459E-05 -5.0294 0.93127E-05 -5.0309 0.99644E+00 -0.0015 54 KCl,aq 0.27608E-09 -9.5590 0.27608E-09 -9.5590 0.10000E+01 0.0000 56 KOH,aq 0.76310E-06 -6.1174 0.76310E-06 -6.1174 0.10000E+01 0.0000 57 KSO4- 0.18661E-14 -14.7291 0.15566E-14 -14.8078 0.83412E+00 -0.0788 58 MgCO3,aq 0.18388E-13 -13.7355 0.18388E-13 -13.7355 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15310E-15 -15.8150 0.12795E-15 -15.8930 0.83574E+00 -0.0779 60 MgCl+ 0.23994E-14 -14.6199 0.20053E-14 -14.6978 0.83574E+00 -0.0779 61 MgOH+ 0.72742E-10 -10.1382 0.60793E-10 -10.2161 0.83574E+00 -0.0779 63 MnO,aq 0.17413E-08 -8.7591 0.17413E-08 -8.7591 0.10000E+01 0.0000 64 MnOH+ 0.46583E-09 -9.3318 0.38931E-09 -9.4097 0.83574E+00 -0.0779 65 MnO2-2 0.19890E-10 -10.7014 0.10255E-10 -10.9891 0.51558E+00 -0.2877 66 HMnO2- 0.20412E-09 -9.6901 0.17026E-09 -9.7689 0.83412E+00 -0.0788 69 MnCl+ 0.81543E-14 -14.0886 0.68149E-14 -14.1665 0.83574E+00 -0.0779 71 NaCl,aq 0.64604E-06 -6.1897 0.64604E-06 -6.1897 0.10000E+01 0.0000 72 NaOH,aq 0.97600E-04 -4.0106 0.97600E-04 -4.0106 0.10000E+01 0.0000 74 OH- 0.94011E-02 -2.0268 0.78274E-02 -2.1064 0.83260E+00 -0.0796 79 HPO3-2 0.15153E-14 -14.8195 0.78125E-15 -15.1072 0.51558E+00 -0.2877 81 H2PO3- 0.14099E-18 -18.8508 0.11760E-18 -18.9296 0.83412E+00 -0.0788 82 H3PO4,aq 0.10042E-17 -17.9982 0.10042E-17 -17.9982 0.10000E+01 0.0000 83 H2PO4- 0.42740E-10 -10.3692 0.35684E-10 -10.4475 0.83492E+00 -0.0784 84 PO4-3 0.12609E-08 -8.8993 0.30268E-09 -9.5190 0.24005E+00 -0.6197 88 HP2O7-3 0.11665E-17 -17.9331 0.26667E-18 -18.5740 0.22861E+00 -0.6409 89 P2O7-4 0.11359E-16 -16.9446 0.85847E-18 -18.0663 0.75574E-01 -1.1216 90 H2S,aq 0.49877E-08 -8.3021 0.49699E-08 -8.3036 0.99644E+00 -0.0015 91 S2-2 0.21342E-14 -14.6708 0.11004E-14 -14.9585 0.51558E+00 -0.2877 97 SO3-2 0.18281E-17 -17.7380 0.95638E-18 -18.0194 0.52316E+00 -0.2814 99 HSO4- 0.64017E-19 -19.1937 0.53555E-19 -19.2712 0.83657E+00 -0.0775 Charge balance for all species = -.7577E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9131056E-10 -.2300026E-01 -.2314103E+02 0.0000 2 H2O 0.1000000E+01 0.5550430E+02 0.9981213E+06 0.0000 3 Cl- 0.1393531E-03 0.1399995E-03 0.4954439E+01 6.1809 4 SO4-- 0.1457709E-11 -.1412075E-04 -.1354013E+01 8.1081 5 HCO3- 0.4998565E-06 0.1326185E-04 0.8077399E+00 3.7363 6 HS- 0.2587385E-04 0.3999959E-04 0.1320478E+01 5.4497 7 Al+++ 0.1113803E-28 0.5109912E-05 0.1376241E+00 0.7522 8 H4SiO4 0.7204721E-03 0.1419729E-01 0.1362114E+04 -3.1424 9 Ca++ 0.1397215E-06 0.2366909E-06 0.9468970E-02 13.0864 10 Mg++ 0.2336320E-10 0.9977550E-10 0.2421362E-05 9.3077 11 Fe++ 0.6293270E-13 0.3712158E-07 0.2069386E-02 6.7385 12 K+ 0.1605404E-03 0.1613038E-03 0.6295914E+01 6.2431 13 Na+ 0.2041016E-01 0.2298820E-01 0.5275399E+03 8.3466 14 Mn++ 0.1894065E-10 0.2450131E-08 0.1343623E-03 9.2174 15 HPO4-- 0.5139684E-07 0.5270048E-07 0.5049006E-02 12.6554 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2119460E+01 -.2266753E-01 -.2096793E+01 0.0000000E+00 2 H2O 0.5390373E+02 0.5470136E+02 -.7976336E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3572793E-02 -.1391647E-04 0.3586710E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3547289E-02 0.3942094E-04 -.3586710E-02 0.0000000E+00 7 Al+++ 0.4173717E+00 0.5035990E-05 0.4173666E+00 0.0000000E+00 8 H4SiO4 0.1332826E+01 0.1399191E-01 0.1318834E+01 0.0000000E+00 9 Ca++ 0.1472316E+00 0.2332668E-06 0.1472313E+00 0.0000000E+00 10 Mg++ 0.1015865E+00 0.9833212E-10 0.1015865E+00 0.0000000E+00 11 Fe++ 0.9126439E-01 0.3658457E-07 0.9126435E-01 0.0000000E+00 12 K+ 0.2717601E-01 0.1589704E-03 0.2701704E-01 0.0000000E+00 13 Na+ 0.1608300E+00 0.2265565E-01 0.1381744E+00 0.0000000E+00 14 Mn++ 0.2219323E-02 0.2414687E-08 0.2219321E-02 0.0000000E+00 15 HPO4-- 0.7574439E-03 0.5193810E-07 0.7573920E-03 0.0000000E+00 Chg. balance for solid moles: 0.5989E-15 Mass of aqueous solution: 0.987316E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 127.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1381 -0.860 36.21 1.559 25.93 13.90 andradite 0.1435E-01 -1.843 7.291 0.863 5.220 1.894 grossular 0.3139E-02 -2.503 1.414 0.150 1.013 0.3935 apatite-OH 0.2525E-03 -3.598 0.1268 -0.897 0.9081E-01 0.4030E-01 clinochlore 0.1977E-01 -1.704 10.99 1.041 7.868 4.180 daphnite 0.5580E-02 -2.253 3.981 0.600 2.851 1.206 chlorite-Mn 0.4439E-03 -3.353 0.3147 -0.502 0.2253 0.1003 microcline 0.2364E-01 -1.626 6.581 0.818 4.712 2.571 stilbite 0.9200E-01 -1.036 64.83 1.812 46.42 30.24 stilpnomelane-Fe 0.6746E-02 -2.171 7.272 0.862 5.207 2.512 tr.625ac.25prg.125 0.7547E-03 -3.122 0.6451 -0.190 0.4619 0.2076 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8205E+00 0.8205E+00 1.0000 -0.086 grossular 0.1795E+00 0.1795E+00 1.0000 -0.746 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7665E+00 0.7665E+00 1.0000 -0.116 daphnite 0.2163E+00 0.2163E+00 1.0000 -0.665 chlorite-Mn 0.1721E-01 0.1721E-01 1.0000 -1.764 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 139.656703 g Volume = 57.244080 cm3 Porosity: -9.6638% V(tot) - V(min): -.50445E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 127.9990000 g log = 2.1072 Original solution: 1000.0103000 g Original solution / Rock added: 7.81 (Water/Rock Ratio), log = 0.8928 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0835 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9713E+00 0.9851 0.1037E+01 0.1052E+01 CO2,gas 0.6768E-08 1.0072 0.7385E-08 0.7333E-08 CH4,gas 0.1692E-01 1.0128 0.1857E-01 0.1833E-01 H2,gas 0.1178E-01 1.0006 0.1277E-01 0.1277E-01 H2S,gas 0.1343E-06 0.9958 0.1450E-06 0.1456E-06 S2,gas 0.4452E-29 1.0000 0.4824E-29 0.4824E-29 CO,gas 0.2255E-13 1.0000 0.2443E-13 0.2443E-13 SO3,gas 0.1526E-47 1.0000 0.1654E-47 0.1654E-47 SO2,gas 0.7375E-27 1.0000 0.7990E-27 0.7990E-27 HCl,gas 0.2730E-17 1.0000 0.2958E-17 0.2958E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.37914E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.49 -10.13 -3.377 0.17300E+05 -8.132 3 CH4,gas 4.81 1.08 -3.73 -0.933 0.63709E+04 -1.731 4 H2,gas 8.29 4.39 -3.89 -2.225 0.66484E+04 -1.894 5 H2S,gas -5.94 -14.78 -8.84 -4.419 0.15092E+05 -6.839 6 S2,gas -7.03 -38.35 -31.32 -4.818 0.53472E+05 -29.317 7 CO,gas 3.51 -12.10 -15.61 -4.804 0.26657E+05 -13.612 8 SO3,gas 17.43 -32.35 -49.78 -12.445 0.85001E+05 -47.782 9 SO2,gas 1.14 -27.96 -29.10 -7.759 0.49683E+05 -27.097 10 HCl,gas 5.48 -14.05 -19.53 -9.764 0.33345E+05 -17.529 11 acmite 7.74 6.60 -1.13 -0.118 0.19357E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.73 -4.82 -0.241 0.82309E+04 20 analcite 3.37 2.81 -0.56 -0.062 0.95041E+03 26 annite 20.21 17.78 -2.43 -0.135 0.41418E+04 27 phlogopite 27.15 25.49 -1.66 -0.092 0.28266E+04 29 anorthite 12.80 8.31 -4.49 -0.346 0.76693E+04 35 aragonite 0.99 -3.41 -4.39 -1.465 0.75038E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55816E+04 37 calcite 0.83 -3.41 -4.24 -1.414 0.72425E+04 38 carnegieite-low 9.06 5.96 -3.11 -0.444 0.53071E+04 39 carnegieite-high 10.13 5.96 -4.18 -0.597 0.71339E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70400E+04 41 carpholite-Fe 6.78 1.96 -4.82 -0.322 0.82381E+04 42 celadonite 5.40 3.73 -1.67 -0.098 0.28464E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47342E+04 44 chrysotile 23.94 21.64 -2.30 -0.192 0.39257E+04 49 chlorite-Al-free 47.26 43.28 -3.99 -0.166 0.68047E+04 51 chloritoid-Fe 9.24 5.10 -4.14 -0.276 0.70658E+04 52 chloritoid-Mn 11.46 7.58 -3.88 -0.259 0.66315E+04 54 coesite -2.37 -3.14 -0.77 -0.258 0.13199E+04 61 cristobalite -2.55 -3.14 -0.59 -0.198 0.10128E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.75 -2.14 -0.357 0.36606E+04 66 diamond -3.11 -7.71 -4.60 -1.315 0.78563E+04 67 diopside 16.22 16.11 -0.11 -0.011 0.18127E+03 68 hedenbergite 14.24 13.54 -0.70 -0.070 0.12025E+04 71 enstatite 17.30 12.33 -4.97 -0.497 0.84869E+04 73 clinoenstatite 17.20 12.33 -4.87 -0.487 0.83177E+04 75 epidote 24.78 22.79 -1.98 -0.096 0.33863E+04 76 clinozoisite 22.92 19.00 -3.92 -0.178 0.66913E+04 77 epidote-Fe 29.94 26.58 -3.36 -0.174 0.57288E+04 78 fayalite 14.08 10.33 -3.74 -0.535 0.63934E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68222E+04 83 gibbsite 4.10 0.75 -3.35 -0.478 0.57118E+04 84 glaucophane 23.11 20.98 -2.13 -0.058 0.36353E+04 85 glaucophane-Fe 17.42 13.27 -4.14 -0.112 0.70744E+04 86 graphite -3.55 -7.71 -4.16 -1.188 0.71025E+04 87 greenalite 16.19 13.93 -2.26 -0.189 0.38649E+04 90 hematite 12.60 9.08 -3.51 -0.426 0.59998E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.81 -1.44 -0.144 0.24534E+04 97 kalsilite 7.62 3.85 -3.77 -0.538 0.64325E+04 98 kaolinite -1.27 -4.78 -3.51 -0.319 0.59885E+04 101 laumontite 2.97 2.02 -0.95 -0.064 0.16277E+04 102 lawsonite 9.68 8.31 -1.37 -0.091 0.23432E+04 103 leucite 4.17 0.71 -3.46 -0.346 0.59028E+04 105 lizardite 23.29 21.64 -1.65 -0.137 0.28160E+04 107 magnetite 20.13 15.82 -4.31 -0.352 0.73601E+04 108 minnesotaite 10.46 7.65 -2.81 -0.166 0.48062E+04 112 manganosite 14.07 9.22 -4.85 -1.213 0.82822E+04 120 muscovite 2.68 -0.93 -3.61 -0.212 0.61581E+04 121 paragonite 4.34 1.18 -3.16 -0.186 0.53966E+04 122 nepheline 8.38 5.96 -2.42 -0.346 0.41350E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.225 0.83677E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36485E+04 136 prehnite 19.47 18.25 -1.22 -0.072 0.20767E+04 137 prehnite-Fe 22.59 22.04 -0.55 -0.033 0.93398E+03 138 pumpellyite-Fe 46.47 43.99 -2.48 -0.055 0.42340E+04 139 pumpellyite-Mg 49.19 46.56 -2.63 -0.059 0.44975E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64873E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.261 0.58550E+04 145 pyroxmangite 7.42 6.07 -1.34 -0.268 0.22898E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.310 0.84812E+04 147 quartz -2.98 -3.14 -0.16 -0.053 0.27385E+03 152 rhodonite 7.46 6.07 -1.39 -0.277 0.23690E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 26.03 -1.57 -0.047 0.26825E+04 171 talc 16.55 15.35 -1.20 -0.071 0.20488E+04 174 tephroite 18.11 15.29 -2.82 -0.403 0.48160E+04 178 tridymite -2.61 -3.14 -0.53 -0.176 0.90114E+03 179 tremolite 48.00 47.57 -0.43 -0.012 0.73613E+03 180 ferroactinolite 38.60 34.73 -3.87 -0.105 0.66084E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62305E+04 187 wairakite 4.06 2.02 -2.04 -0.120 0.34785E+04 188 walstromite 11.53 9.94 -1.58 -0.317 0.27044E+04 189 wollastonite 10.48 9.94 -0.54 -0.108 0.91826E+03 190 pseudo-wollastonite 11.02 9.94 -1.08 -0.215 0.18369E+04 191 zoisite 22.96 19.00 -3.96 -0.180 0.67639E+04 192 akaganeite 7.77 4.54 -3.23 -0.697 0.55081E+04 199 chalcedony -2.79 -3.14 -0.35 -0.116 0.59417E+03 201 montmorillonite-Ca -2.21 -6.08 -3.87 -0.239 0.66054E+04 202 montmorillonite-K -2.16 -6.18 -4.02 -0.246 0.68651E+04 203 montmorillonite-Mg -2.40 -6.71 -4.30 -0.266 0.73497E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60220E+04 205 nontronite-Ca 3.28 -0.04 -3.32 -0.215 0.56704E+04 206 nontronite-H 2.60 -2.20 -4.80 -0.321 0.81895E+04 207 nontronite-K 3.40 -0.14 -3.54 -0.227 0.60515E+04 208 nontronite-Mg 3.14 -0.66 -3.80 -0.247 0.64953E+04 209 nontronite-Na 3.58 0.55 -3.03 -0.194 0.51719E+04 224 tobermorite 9.84 7.76 -2.08 -0.568 0.35522E+04 230 alabandite -0.96 -5.56 -4.60 -1.534 0.78572E+04 233 boehmite 4.43 0.75 -3.68 -0.613 0.62791E+04 235 ferrous-oxide 9.82 6.74 -3.09 -0.771 0.52688E+04 240 silica-amorphous -2.08 -3.14 -1.06 -0.354 0.18144E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11623E+04 243 an25ab75 2.71 1.83 -0.88 -0.068 0.15007E+04 244 an30ab70 3.34 2.26 -1.08 -0.083 0.18475E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 127.9990000 g New total amount of reactant added: 131.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7248E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 131.9990000 Water: Moles liquid = 0.5468E+02 kg liquid = 0.9851E+00 Moles total = 0.5385E+02 kg total = 0.9702E+00 Activity = 1.0000 Stoichiometric ionic strength = .1167611E-01 Osmotic coef. = 0.9685 True ionic strength = .2058770E-01 Chg. balance for total moles = -.7248E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91160E-10 -10.0402 0.76503E-10 -10.1163 0.83921E+00 -0.0761 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13941E-03 -3.8557 0.11628E-03 -3.9345 0.83408E+00 -0.0788 4 SO4-- 0.13387E-11 -11.8733 0.69158E-12 -12.1602 0.51659E+00 -0.2869 5 HCO3- 0.46319E-06 -6.3342 0.38692E-06 -6.4124 0.83532E+00 -0.0781 6 HS- 0.25884E-04 -4.5870 0.21593E-04 -4.6657 0.83421E+00 -0.0787 7 Al+++ 0.11121E-28 -28.9539 0.25385E-29 -29.5954 0.22827E+00 -0.6416 8 H4SiO4 0.71916E-03 -3.1432 0.71916E-03 -3.1432 0.10000E+01 0.0000 9 Ca++ 0.14020E-06 -6.8532 0.71886E-07 -7.1434 0.51273E+00 -0.2901 10 Mg++ 0.23274E-10 -10.6331 0.11878E-10 -10.9253 0.51035E+00 -0.2921 11 Fe++ 0.62823E-13 -13.2019 0.32097E-13 -13.4935 0.51092E+00 -0.2917 12 K+ 0.16066E-03 -3.7941 0.13424E-03 -3.8721 0.83552E+00 -0.0780 13 Na+ 0.20426E-01 -1.6898 0.17033E-01 -1.7687 0.83392E+00 -0.0789 14 Mn++ 0.18936E-10 -10.7227 0.96828E-11 -11.0140 0.51135E+00 -0.2913 15 HPO4-- 0.51015E-07 -7.2923 0.26358E-07 -7.5791 0.51666E+00 -0.2868 16 HSiO3- 0.10996E-01 -1.9588 0.91717E-02 -2.0376 0.83408E+00 -0.0788 17 Ca(HSiO3)+ 0.17676E-07 -7.7526 0.14772E-07 -7.8306 0.83570E+00 -0.0779 18 Mg(HSiO3)+ 0.36348E-11 -11.4395 0.30376E-11 -11.5175 0.83570E+00 -0.0779 19 NaHSiO3,aq 0.24812E-02 -2.6053 0.24812E-02 -2.6053 0.10000E+01 0.0000 20 AlO+ 0.67001E-16 -16.1739 0.55993E-16 -16.2519 0.83570E+00 -0.0779 22 HAlO2,aq 0.14646E-09 -9.8343 0.14646E-09 -9.8343 0.10000E+01 0.0000 23 AlO2- 0.51345E-05 -5.2895 0.42748E-05 -5.3691 0.83256E+00 -0.0796 24 CH4,aq 0.11896E-04 -4.9246 0.11854E-04 -4.9261 0.99644E+00 -0.0015 25 C2H6,aq 0.25551E-14 -14.5926 0.25460E-14 -14.5941 0.99644E+00 -0.0015 29 CO,aq 0.14630E-16 -16.8347 0.14630E-16 -16.8347 0.10000E+01 0.0000 30 CO2,aq 0.59893E-10 -10.2226 0.59680E-10 -10.2242 0.99644E+00 -0.0015 31 CO3-2 0.90716E-06 -6.0423 0.46762E-06 -6.3301 0.51547E+00 -0.2878 32 CaCO3,aq 0.41171E-09 -9.3854 0.41171E-09 -9.3854 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.83861E-12 -12.0764 0.70083E-12 -12.1544 0.83570E+00 -0.0779 34 CaCl+ 0.15938E-10 -10.7976 0.13320E-10 -10.8755 0.83570E+00 -0.0779 35 CaCl2,aq 0.36062E-15 -15.4430 0.36062E-15 -15.4430 0.10000E+01 0.0000 36 CaOH+ 0.79284E-07 -7.1008 0.66258E-07 -7.1788 0.83570E+00 -0.0779 37 CaSO4,aq 0.15490E-16 -16.8099 0.15490E-16 -16.8099 0.10000E+01 0.0000 38 HCl,aq 0.16732E-14 -14.7764 0.16732E-14 -14.7764 0.10000E+01 0.0000 43 FeCl+ 0.69558E-17 -17.1577 0.58130E-17 -17.2356 0.83570E+00 -0.0779 46 FeO,aq 0.21687E-09 -9.6638 0.21687E-09 -9.6638 0.10000E+01 0.0000 47 FeOH+ 0.16644E-10 -10.7787 0.13909E-10 -10.8567 0.83570E+00 -0.0779 48 HFeO2- 0.36556E-07 -7.4370 0.30491E-07 -7.5158 0.83408E+00 -0.0788 49 FeO+ 0.13128E-16 -16.8818 0.10971E-16 -16.9597 0.83570E+00 -0.0779 51 FeO2- 0.44172E-09 -9.3548 0.36843E-09 -9.4336 0.83408E+00 -0.0788 52 HFeO2,aq 0.35275E-11 -11.4525 0.35275E-11 -11.4525 0.10000E+01 0.0000 53 H2,aq 0.95523E-05 -5.0199 0.95184E-05 -5.0214 0.99644E+00 -0.0015 54 KCl,aq 0.27638E-09 -9.5585 0.27638E-09 -9.5585 0.10000E+01 0.0000 56 KOH,aq 0.76494E-06 -6.1164 0.76494E-06 -6.1164 0.10000E+01 0.0000 57 KSO4- 0.17148E-14 -14.7658 0.14302E-14 -14.8446 0.83408E+00 -0.0788 58 MgCO3,aq 0.16998E-13 -13.7696 0.16998E-13 -13.7696 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14130E-15 -15.8499 0.11808E-15 -15.9278 0.83570E+00 -0.0779 60 MgCl+ 0.23907E-14 -14.6215 0.19979E-14 -14.6994 0.83570E+00 -0.0779 61 MgOH+ 0.72574E-10 -10.1392 0.60650E-10 -10.2172 0.83570E+00 -0.0779 63 MnO,aq 0.17465E-08 -8.7578 0.17465E-08 -8.7578 0.10000E+01 0.0000 64 MnOH+ 0.46643E-09 -9.3312 0.38980E-09 -9.4092 0.83570E+00 -0.0779 65 MnO2-2 0.20020E-10 -10.6985 0.10320E-10 -10.9863 0.51547E+00 -0.2878 66 HMnO2- 0.20508E-09 -9.6881 0.17106E-09 -9.7669 0.83408E+00 -0.0788 69 MnCl+ 0.81540E-14 -14.0886 0.68143E-14 -14.1666 0.83570E+00 -0.0779 71 NaCl,aq 0.64672E-06 -6.1893 0.64672E-06 -6.1893 0.10000E+01 0.0000 72 NaOH,aq 0.97834E-04 -4.0095 0.97834E-04 -4.0095 0.10000E+01 0.0000 74 OH- 0.94176E-02 -2.0261 0.78407E-02 -2.1056 0.83256E+00 -0.0796 79 HPO3-2 0.15373E-14 -14.8133 0.79242E-15 -15.1010 0.51547E+00 -0.2878 81 H2PO3- 0.14277E-18 -18.8454 0.11908E-18 -18.9242 0.83408E+00 -0.0788 82 H3PO4,aq 0.99313E-18 -18.0030 0.99313E-18 -18.0030 0.10000E+01 0.0000 83 H2PO4- 0.42344E-10 -10.3732 0.35352E-10 -10.4516 0.83488E+00 -0.0784 84 PO4-3 0.12539E-08 -8.9017 0.30088E-09 -9.5216 0.23995E+00 -0.6199 88 HP2O7-3 0.11473E-17 -17.9403 0.26217E-18 -18.5814 0.22851E+00 -0.6411 89 P2O7-4 0.11196E-16 -16.9510 0.84543E-18 -18.0729 0.75515E-01 -1.1220 90 H2S,aq 0.49810E-08 -8.3027 0.49633E-08 -8.3042 0.99644E+00 -0.0015 91 S2-2 0.20900E-14 -14.6799 0.10773E-14 -14.9676 0.51547E+00 -0.2878 97 SO3-2 0.17160E-17 -17.7655 0.89755E-18 -18.0469 0.52306E+00 -0.2815 99 HSO4- 0.58684E-19 -19.2315 0.49091E-19 -19.3090 0.83653E+00 -0.0775 Charge balance for all species = -.7511E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9115987E-10 -.2301761E-01 -.2315847E+02 0.0000 2 H2O 0.1000000E+01 0.5550432E+02 0.9981210E+06 0.0000 3 Cl- 0.1394093E-03 0.1400563E-03 0.4956448E+01 6.1818 4 SO4-- 0.1338744E-11 -.1428444E-04 -.1369708E+01 8.0725 5 HCO3- 0.4631945E-06 0.1326724E-04 0.8080675E+00 3.7039 6 HS- 0.2588437E-04 0.4017379E-04 0.1326228E+01 5.4506 7 Al+++ 0.1112063E-28 0.5134659E-05 0.1382906E+00 0.7535 8 H4SiO4 0.7191565E-03 0.1419654E-01 0.1362041E+04 -3.1432 9 Ca++ 0.1402025E-06 0.2375911E-06 0.9504979E-02 13.0893 10 Mg++ 0.2327350E-10 0.9950205E-10 0.2414725E-05 9.3074 11 Fe++ 0.6282317E-13 0.3723526E-07 0.2075722E-02 6.7391 12 K+ 0.1606614E-03 0.1614266E-03 0.6300702E+01 6.2442 13 Na+ 0.2042556E-01 0.2300526E-01 0.5279311E+03 8.3476 14 Mn++ 0.1893598E-10 0.2456964E-08 0.1347369E-03 9.2186 15 HPO4-- 0.5101490E-07 0.5231119E-07 0.5011707E-02 12.6536 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2185694E+01 -.2267542E-01 -.2163019E+01 0.0000000E+00 2 H2O 0.5385359E+02 0.5467917E+02 -.8255841E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3683647E-02 -.1407208E-04 0.3697719E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3658142E-02 0.3957655E-04 -.3697719E-02 0.0000000E+00 7 Al+++ 0.4304146E+00 0.5058325E-05 0.4304096E+00 0.0000000E+00 8 H4SiO4 0.1374477E+01 0.1398548E-01 0.1360491E+01 0.0000000E+00 9 Ca++ 0.1518322E+00 0.2340590E-06 0.1518319E+00 0.0000000E+00 10 Mg++ 0.1047611E+00 0.9802281E-10 0.1047611E+00 0.0000000E+00 11 Fe++ 0.9411642E-01 0.3668171E-07 0.9411638E-01 0.0000000E+00 12 K+ 0.2802527E-01 0.1590268E-03 0.2786624E-01 0.0000000E+00 13 Na+ 0.1658510E+00 0.2266326E-01 0.1431877E+00 0.0000000E+00 14 Mn++ 0.2288677E-02 0.2420438E-08 0.2288675E-02 0.0000000E+00 15 HPO4-- 0.7811142E-03 0.5153351E-07 0.7810627E-03 0.0000000E+00 Chg. balance for solid moles: 0.5133E-15 Mass of aqueous solution: 0.986916E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 131.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1431 -0.844 37.52 1.574 26.05 14.40 andradite 0.1479E-01 -1.830 7.516 0.876 5.219 1.953 grossular 0.3277E-02 -2.484 1.476 0.169 1.025 0.4108 apatite-OH 0.2604E-03 -3.584 0.1308 -0.883 0.9080E-01 0.4156E-01 clinochlore 0.2031E-01 -1.692 11.29 1.053 7.840 4.295 daphnite 0.5745E-02 -2.241 4.099 0.613 2.846 1.242 chlorite-Mn 0.4577E-03 -3.339 0.3245 -0.489 0.2253 0.1034 microcline 0.2440E-01 -1.613 6.790 0.832 4.715 2.652 stilbite 0.9457E-01 -1.024 66.64 1.824 46.27 31.08 stilpnomelane-Fe 0.6942E-02 -2.159 7.483 0.874 5.196 2.585 tr.625ac.25prg.125 0.8794E-03 -3.056 0.7517 -0.124 0.5219 0.2419 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8186E+00 0.8186E+00 1.0000 -0.087 grossular 0.1814E+00 0.1814E+00 1.0000 -0.741 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7661E+00 0.7661E+00 1.0000 -0.116 daphnite 0.2167E+00 0.2167E+00 1.0000 -0.664 chlorite-Mn 0.1726E-01 0.1726E-01 1.0000 -1.763 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 144.024565 g Volume = 59.010624 cm3 Porosity: -9.6860% V(tot) - V(min): -.52110E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 131.9990000 g log = 2.1206 Original solution: 1000.0103000 g Original solution / Rock added: 7.58 (Water/Rock Ratio), log = 0.8794 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0840 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9709E+00 0.9851 0.1037E+01 0.1052E+01 CO2,gas 0.6258E-08 1.0072 0.6831E-08 0.6783E-08 CH4,gas 0.1707E-01 1.0128 0.1875E-01 0.1851E-01 H2,gas 0.1204E-01 1.0006 0.1306E-01 0.1305E-01 H2S,gas 0.1341E-06 0.9958 0.1448E-06 0.1454E-06 S2,gas 0.4248E-29 1.0000 0.4605E-29 0.4605E-29 CO,gas 0.2131E-13 1.0000 0.2310E-13 0.2310E-13 SO3,gas 0.1396E-47 1.0000 0.1513E-47 0.1513E-47 SO2,gas 0.6895E-27 1.0000 0.7473E-27 0.7473E-27 HCl,gas 0.2726E-17 1.0000 0.2954E-17 0.2954E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.36397E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.53 -10.17 -3.388 0.17357E+05 -8.165 3 CH4,gas 4.81 1.08 -3.73 -0.932 0.63639E+04 -1.727 4 H2,gas 8.29 4.40 -3.88 -2.220 0.66322E+04 -1.884 5 H2S,gas -5.94 -14.78 -8.84 -4.420 0.15093E+05 -6.839 6 S2,gas -7.03 -38.37 -31.34 -4.821 0.53507E+05 -29.337 7 CO,gas 3.51 -12.13 -15.64 -4.811 0.26699E+05 -13.636 8 SO3,gas 17.43 -32.39 -49.82 -12.455 0.85066E+05 -47.820 9 SO2,gas 1.14 -27.99 -29.13 -7.767 0.49733E+05 -27.126 10 HCl,gas 5.48 -14.05 -19.53 -9.765 0.33346E+05 -17.530 11 acmite 7.74 6.60 -1.14 -0.118 0.19437E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.73 -4.82 -0.241 0.82239E+04 20 analcite 3.37 2.81 -0.56 -0.062 0.94905E+03 26 annite 20.21 17.79 -2.42 -0.135 0.41385E+04 27 phlogopite 27.15 25.49 -1.66 -0.092 0.28280E+04 29 anorthite 12.80 8.31 -4.49 -0.345 0.76625E+04 35 aragonite 0.99 -3.44 -4.43 -1.475 0.75567E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55821E+04 37 calcite 0.83 -3.44 -4.27 -1.424 0.72953E+04 38 carnegieite-low 9.06 5.96 -3.11 -0.444 0.53044E+04 39 carnegieite-high 10.13 5.96 -4.18 -0.597 0.71312E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70387E+04 41 carpholite-Fe 6.78 1.96 -4.82 -0.322 0.82352E+04 42 celadonite 5.40 3.73 -1.67 -0.098 0.28482E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47345E+04 44 chrysotile 23.94 21.64 -2.30 -0.192 0.39299E+04 49 chlorite-Al-free 47.26 43.27 -3.99 -0.166 0.68130E+04 51 chloritoid-Fe 9.24 5.10 -4.14 -0.276 0.70615E+04 52 chloritoid-Mn 11.46 7.58 -3.88 -0.259 0.66261E+04 54 coesite -2.37 -3.14 -0.77 -0.258 0.13213E+04 61 cristobalite -2.55 -3.14 -0.59 -0.198 0.10142E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.75 -2.14 -0.357 0.36583E+04 66 diamond -3.11 -7.72 -4.62 -1.319 0.78817E+04 67 diopside 16.22 16.11 -0.11 -0.011 0.17955E+03 68 hedenbergite 14.24 13.54 -0.70 -0.070 0.11993E+04 71 enstatite 17.30 12.33 -4.97 -0.497 0.84906E+04 73 clinoenstatite 17.20 12.33 -4.87 -0.487 0.83214E+04 75 epidote 24.78 22.79 -1.98 -0.096 0.33830E+04 76 clinozoisite 22.92 19.01 -3.91 -0.178 0.66787E+04 77 epidote-Fe 29.94 26.58 -3.36 -0.174 0.57348E+04 78 fayalite 14.08 10.34 -3.74 -0.535 0.63926E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68227E+04 83 gibbsite 4.10 0.75 -3.34 -0.478 0.57095E+04 84 glaucophane 23.11 20.98 -2.13 -0.058 0.36394E+04 85 glaucophane-Fe 17.42 13.27 -4.14 -0.112 0.70739E+04 86 graphite -3.55 -7.72 -4.17 -1.193 0.71279E+04 87 greenalite 16.19 13.93 -2.26 -0.189 0.38644E+04 90 hematite 12.60 9.08 -3.52 -0.427 0.60138E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.81 -1.44 -0.144 0.24521E+04 97 kalsilite 7.62 3.85 -3.77 -0.538 0.64298E+04 98 kaolinite -1.27 -4.78 -3.51 -0.319 0.59866E+04 101 laumontite 2.97 2.02 -0.95 -0.063 0.16236E+04 102 lawsonite 9.68 8.31 -1.37 -0.091 0.23364E+04 103 leucite 4.17 0.71 -3.46 -0.346 0.59015E+04 105 lizardite 23.29 21.64 -1.65 -0.138 0.28201E+04 107 magnetite 20.13 15.81 -4.32 -0.352 0.73731E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48084E+04 112 manganosite 14.07 9.22 -4.85 -1.212 0.82800E+04 120 muscovite 2.68 -0.92 -3.60 -0.212 0.61536E+04 121 paragonite 4.34 1.18 -3.16 -0.186 0.53920E+04 122 nepheline 8.38 5.96 -2.42 -0.346 0.41323E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.225 0.83667E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36499E+04 136 prehnite 19.47 18.26 -1.21 -0.071 0.20664E+04 137 prehnite-Fe 22.59 22.04 -0.55 -0.033 0.93295E+03 138 pumpellyite-Fe 46.47 44.00 -2.47 -0.055 0.42100E+04 139 pumpellyite-Mg 49.19 46.57 -2.62 -0.058 0.44750E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64873E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.262 0.58570E+04 145 pyroxmangite 7.42 6.08 -1.34 -0.268 0.22890E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.310 0.84820E+04 147 quartz -2.98 -3.14 -0.16 -0.054 0.27521E+03 152 rhodonite 7.46 6.08 -1.39 -0.277 0.23682E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 26.02 -1.58 -0.047 0.26903E+04 171 talc 16.55 15.35 -1.20 -0.071 0.20557E+04 174 tephroite 18.11 15.29 -2.82 -0.403 0.48130E+04 178 tridymite -2.61 -3.14 -0.53 -0.176 0.90250E+03 179 tremolite 48.00 47.57 -0.43 -0.012 0.73956E+03 180 ferroactinolite 38.60 34.73 -3.87 -0.105 0.66040E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62304E+04 187 wairakite 4.06 2.02 -2.03 -0.120 0.34744E+04 188 walstromite 11.53 9.95 -1.58 -0.316 0.27008E+04 189 wollastonite 10.48 9.95 -0.54 -0.107 0.91470E+03 190 pseudo-wollastonite 11.02 9.95 -1.07 -0.215 0.18333E+04 191 zoisite 22.96 19.01 -3.95 -0.180 0.67513E+04 192 akaganeite 7.77 4.54 -3.23 -0.698 0.55151E+04 199 chalcedony -2.79 -3.14 -0.35 -0.116 0.59552E+03 201 montmorillonite-Ca -2.21 -6.08 -3.87 -0.239 0.66064E+04 202 montmorillonite-K -2.16 -6.18 -4.02 -0.246 0.68663E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.266 0.73515E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60231E+04 205 nontronite-Ca 3.28 -0.05 -3.33 -0.216 0.56879E+04 206 nontronite-H 2.60 -2.21 -4.81 -0.322 0.82078E+04 207 nontronite-K 3.40 -0.15 -3.55 -0.228 0.60692E+04 208 nontronite-Mg 3.14 -0.68 -3.81 -0.247 0.65136E+04 209 nontronite-Na 3.58 0.54 -3.04 -0.195 0.51896E+04 224 tobermorite 9.84 7.76 -2.08 -0.567 0.35495E+04 230 alabandite -0.96 -5.56 -4.60 -1.534 0.78560E+04 233 boehmite 4.43 0.75 -3.68 -0.613 0.62768E+04 235 ferrous-oxide 9.82 6.74 -3.09 -0.771 0.52677E+04 240 silica-amorphous -2.08 -3.14 -1.06 -0.354 0.18157E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11609E+04 243 an25ab75 2.71 1.83 -0.88 -0.068 0.14990E+04 244 an30ab70 3.34 2.26 -1.08 -0.083 0.18455E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 131.9990000 g New total amount of reactant added: 135.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7273E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 135.9990000 Water: Moles liquid = 0.5466E+02 kg liquid = 0.9847E+00 Moles total = 0.5380E+02 kg total = 0.9693E+00 Activity = 1.0000 Stoichiometric ionic strength = .1168408E-01 Osmotic coef. = 0.9686 True ionic strength = .2060217E-01 Chg. balance for total moles = -.7273E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91019E-10 -10.0409 0.76381E-10 -10.1170 0.83918E+00 -0.0761 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13947E-03 -3.8555 0.11632E-03 -3.9343 0.83404E+00 -0.0788 4 SO4-- 0.12362E-11 -11.9079 0.63847E-12 -12.1949 0.51649E+00 -0.2869 5 HCO3- 0.43105E-06 -6.3655 0.36005E-06 -6.4436 0.83528E+00 -0.0782 6 HS- 0.25895E-04 -4.5868 0.21601E-04 -4.6655 0.83417E+00 -0.0787 7 Al+++ 0.11104E-28 -28.9545 0.25337E-29 -29.5962 0.22817E+00 -0.6417 8 H4SiO4 0.71793E-03 -3.1439 0.71793E-03 -3.1439 0.10000E+01 0.0000 9 Ca++ 0.14065E-06 -6.8518 0.72104E-07 -7.1420 0.51263E+00 -0.2902 10 Mg++ 0.23190E-10 -10.6347 0.11833E-10 -10.9269 0.51025E+00 -0.2922 11 Fe++ 0.62721E-13 -13.2026 0.32039E-13 -13.4943 0.51082E+00 -0.2917 12 K+ 0.16077E-03 -3.7938 0.13432E-03 -3.8718 0.83548E+00 -0.0781 13 Na+ 0.20440E-01 -1.6895 0.17045E-01 -1.7684 0.83388E+00 -0.0789 14 Mn++ 0.18932E-10 -10.7228 0.96791E-11 -11.0142 0.51125E+00 -0.2914 15 HPO4-- 0.50661E-07 -7.2953 0.26170E-07 -7.5822 0.51657E+00 -0.2869 16 HSiO3- 0.10995E-01 -1.9588 0.91706E-02 -2.0376 0.83404E+00 -0.0788 17 Ca(HSiO3)+ 0.17729E-07 -7.7513 0.14815E-07 -7.8293 0.83566E+00 -0.0780 18 Mg(HSiO3)+ 0.36208E-11 -11.4412 0.30257E-11 -11.5192 0.83566E+00 -0.0780 19 NaHSiO3,aq 0.24826E-02 -2.6051 0.24826E-02 -2.6051 0.10000E+01 0.0000 20 AlO+ 0.67091E-16 -16.1733 0.56065E-16 -16.2513 0.83566E+00 -0.0780 22 HAlO2,aq 0.14688E-09 -9.8330 0.14688E-09 -9.8330 0.10000E+01 0.0000 23 AlO2- 0.51577E-05 -5.2875 0.42939E-05 -5.3671 0.83252E+00 -0.0796 24 CH4,aq 0.11995E-04 -4.9210 0.11953E-04 -4.9225 0.99644E+00 -0.0015 25 C2H6,aq 0.25452E-14 -14.5943 0.25361E-14 -14.5958 0.99644E+00 -0.0015 29 CO,aq 0.13874E-16 -16.8578 0.13874E-16 -16.8578 0.10000E+01 0.0000 30 CO2,aq 0.55645E-10 -10.2546 0.55447E-10 -10.2561 0.99644E+00 -0.0015 31 CO3-2 0.84566E-06 -6.0728 0.43583E-06 -6.3607 0.51538E+00 -0.2879 32 CaCO3,aq 0.38488E-09 -9.4147 0.38488E-09 -9.4147 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.78277E-12 -12.1064 0.65413E-12 -12.1843 0.83566E+00 -0.0780 34 CaCl+ 0.15993E-10 -10.7961 0.13365E-10 -10.8740 0.83566E+00 -0.0780 35 CaCl2,aq 0.36197E-15 -15.4413 0.36197E-15 -15.4413 0.10000E+01 0.0000 36 CaOH+ 0.79654E-07 -7.0988 0.66564E-07 -7.1768 0.83566E+00 -0.0780 37 CaSO4,aq 0.14344E-16 -16.8433 0.14344E-16 -16.8433 0.10000E+01 0.0000 38 HCl,aq 0.16712E-14 -14.7770 0.16712E-14 -14.7770 0.10000E+01 0.0000 43 FeCl+ 0.69460E-17 -17.1583 0.58045E-17 -17.2362 0.83566E+00 -0.0780 46 FeO,aq 0.21716E-09 -9.6632 0.21716E-09 -9.6632 0.10000E+01 0.0000 47 FeOH+ 0.16641E-10 -10.7788 0.13906E-10 -10.8568 0.83566E+00 -0.0780 48 HFeO2- 0.36666E-07 -7.4357 0.30581E-07 -7.5145 0.83404E+00 -0.0788 49 FeO+ 0.12992E-16 -16.8863 0.10857E-16 -16.9643 0.83566E+00 -0.0780 51 FeO2- 0.43854E-09 -9.3580 0.36576E-09 -9.4368 0.83404E+00 -0.0788 52 HFeO2,aq 0.34963E-11 -11.4564 0.34963E-11 -11.4564 0.10000E+01 0.0000 53 H2,aq 0.97499E-05 -5.0110 0.97151E-05 -5.0126 0.99644E+00 -0.0015 54 KCl,aq 0.27666E-09 -9.5581 0.27666E-09 -9.5581 0.10000E+01 0.0000 56 KOH,aq 0.76665E-06 -6.1154 0.76665E-06 -6.1154 0.10000E+01 0.0000 57 KSO4- 0.15842E-14 -14.8002 0.13213E-14 -14.8790 0.83404E+00 -0.0788 58 MgCO3,aq 0.15783E-13 -13.8018 0.15783E-13 -13.8018 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13099E-15 -15.8828 0.10947E-15 -15.9607 0.83566E+00 -0.0780 60 MgCl+ 0.23826E-14 -14.6229 0.19911E-14 -14.7009 0.83566E+00 -0.0780 61 MgOH+ 0.72418E-10 -10.1402 0.60517E-10 -10.2181 0.83566E+00 -0.0780 63 MnO,aq 0.17514E-08 -8.7566 0.17514E-08 -8.7566 0.10000E+01 0.0000 64 MnOH+ 0.46702E-09 -9.3307 0.39027E-09 -9.4086 0.83566E+00 -0.0780 65 MnO2-2 0.20144E-10 -10.6959 0.10382E-10 -10.9837 0.51538E+00 -0.2879 66 HMnO2- 0.20599E-09 -9.6861 0.17181E-09 -9.7650 0.83404E+00 -0.0788 69 MnCl+ 0.81541E-14 -14.0886 0.68141E-14 -14.1666 0.83566E+00 -0.0780 71 NaCl,aq 0.64738E-06 -6.1888 0.64738E-06 -6.1888 0.10000E+01 0.0000 72 NaOH,aq 0.98054E-04 -4.0085 0.98054E-04 -4.0085 0.10000E+01 0.0000 74 OH- 0.94330E-02 -2.0253 0.78531E-02 -2.1050 0.83252E+00 -0.0796 79 HPO3-2 0.15581E-14 -14.8074 0.80303E-15 -15.0953 0.51538E+00 -0.2879 81 H2PO3- 0.14446E-18 -18.8403 0.12049E-18 -18.9191 0.83404E+00 -0.0788 82 H3PO4,aq 0.98293E-18 -18.0075 0.98293E-18 -18.0075 0.10000E+01 0.0000 83 H2PO4- 0.41977E-10 -10.3770 0.35044E-10 -10.4554 0.83484E+00 -0.0784 84 PO4-3 0.12475E-08 -8.9040 0.29921E-09 -9.5240 0.23986E+00 -0.6200 88 HP2O7-3 0.11297E-17 -17.9470 0.25804E-18 -18.5883 0.22841E+00 -0.6413 89 P2O7-4 0.11045E-16 -16.9569 0.83342E-18 -18.0791 0.75459E-01 -1.1223 90 H2S,aq 0.49749E-08 -8.3032 0.49572E-08 -8.3048 0.99644E+00 -0.0015 91 S2-2 0.20495E-14 -14.6883 0.10563E-14 -14.9762 0.51538E+00 -0.2879 97 SO3-2 0.16172E-17 -17.7912 0.84575E-18 -18.0728 0.52296E+00 -0.2815 99 HSO4- 0.54094E-19 -19.2669 0.45249E-19 -19.3444 0.83649E+00 -0.0775 Charge balance for all species = -.7405E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9101939E-10 -.2303385E-01 -.2317480E+02 0.0000 2 H2O 0.1000000E+01 0.5550434E+02 0.9981207E+06 0.0000 3 Cl- 0.1394655E-03 0.1401132E-03 0.4958459E+01 6.1827 4 SO4-- 0.1236160E-11 -.1443289E-04 -.1383941E+01 8.0392 5 HCO3- 0.4310478E-06 0.1327263E-04 0.8083953E+00 3.6734 6 HS- 0.2589489E-04 0.4033275E-04 0.1331475E+01 5.4515 7 Al+++ 0.1110441E-28 0.5157871E-05 0.1389157E+00 0.7548 8 H4SiO4 0.7179301E-03 0.1419584E-01 0.1361974E+04 -3.1439 9 Ca++ 0.1406535E-06 0.2384376E-06 0.9538836E-02 13.0920 10 Mg++ 0.2319003E-10 0.9924736E-10 0.2408542E-05 9.3071 11 Fe++ 0.6272112E-13 0.3734179E-07 0.2081659E-02 6.7397 12 K+ 0.1607746E-03 0.1615416E-03 0.6305187E+01 6.2452 13 Na+ 0.2043998E-01 0.2302124E-01 0.5282974E+03 8.3486 14 Mn++ 0.1893239E-10 0.2463462E-08 0.1350932E-03 9.2199 15 HPO4-- 0.5066059E-07 0.5195004E-07 0.4977104E-02 12.6518 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2251928E+01 -.2268221E-01 -.2229246E+01 0.0000000E+00 2 H2O 0.5380345E+02 0.5465699E+02 -.8535385E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3794500E-02 -.1421255E-04 0.3808713E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3768996E-02 0.3971702E-04 -.3808713E-02 0.0000000E+00 7 Al+++ 0.4434576E+00 0.5079129E-05 0.4434525E+00 0.0000000E+00 8 H4SiO4 0.1416128E+01 0.1397912E-01 0.1402149E+01 0.0000000E+00 9 Ca++ 0.1564327E+00 0.2347975E-06 0.1564325E+00 0.0000000E+00 10 Mg++ 0.1079357E+00 0.9773221E-10 0.1079357E+00 0.0000000E+00 11 Fe++ 0.9696846E-01 0.3677171E-07 0.9696842E-01 0.0000000E+00 12 K+ 0.2887452E-01 0.1590754E-03 0.2871545E-01 0.0000000E+00 13 Na+ 0.1708719E+00 0.2266979E-01 0.1482022E+00 0.0000000E+00 14 Mn++ 0.2358032E-02 0.2425854E-08 0.2358029E-02 0.0000000E+00 15 HPO4-- 0.8047845E-03 0.5115695E-07 0.8047333E-03 0.0000000E+00 Chg. balance for solid moles: 0.6939E-16 Mass of aqueous solution: 0.986516E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 135.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1481 -0.830 38.83 1.589 26.17 14.91 andradite 0.1523E-01 -1.817 7.742 0.889 5.217 2.011 grossular 0.3416E-02 -2.467 1.539 0.187 1.037 0.4281 apatite-OH 0.2682E-03 -3.571 0.1347 -0.870 0.9080E-01 0.4282E-01 clinochlore 0.2086E-01 -1.681 11.59 1.064 7.813 4.410 daphnite 0.5911E-02 -2.228 4.218 0.625 2.842 1.278 chlorite-Mn 0.4716E-03 -3.326 0.3344 -0.476 0.2253 0.1066 microcline 0.2515E-01 -1.600 6.999 0.845 4.717 2.734 stilbite 0.9713E-01 -1.013 68.45 1.835 46.13 31.93 stilpnomelane-Fe 0.7138E-02 -2.146 7.694 0.886 5.185 2.658 tr.625ac.25prg.125 0.1004E-02 -2.998 0.8583 -0.066 0.5784 0.2762 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8169E+00 0.8169E+00 1.0000 -0.088 grossular 0.1831E+00 0.1831E+00 1.0000 -0.737 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7657E+00 0.7657E+00 1.0000 -0.116 daphnite 0.2170E+00 0.2170E+00 1.0000 -0.664 chlorite-Mn 0.1731E-01 0.1731E-01 1.0000 -1.762 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 148.392374 g Volume = 60.777098 cm3 Porosity: -9.7067% V(tot) - V(min): -.53775E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 135.9990000 g log = 2.1335 Original solution: 1000.0103000 g Original solution / Rock added: 7.35 (Water/Rock Ratio), log = 0.8665 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0844 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9705E+00 0.9851 0.1037E+01 0.1052E+01 CO2,gas 0.5811E-08 1.0072 0.6347E-08 0.6302E-08 CH4,gas 0.1721E-01 1.0128 0.1890E-01 0.1866E-01 H2,gas 0.1228E-01 1.0006 0.1333E-01 0.1332E-01 H2S,gas 0.1339E-06 0.9958 0.1446E-06 0.1452E-06 S2,gas 0.4066E-29 1.0000 0.4409E-29 0.4409E-29 CO,gas 0.2020E-13 1.0000 0.2191E-13 0.2191E-13 SO3,gas 0.1284E-47 1.0000 0.1393E-47 0.1393E-47 SO2,gas 0.6473E-27 1.0000 0.7020E-27 0.7020E-27 HCl,gas 0.2721E-17 1.0000 0.2951E-17 0.2951E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 0.18957E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.56 -10.20 -3.399 0.17412E+05 -8.197 3 CH4,gas 4.81 1.09 -3.72 -0.931 0.63578E+04 -1.723 4 H2,gas 8.29 4.41 -3.88 -2.214 0.66170E+04 -1.875 5 H2S,gas -5.94 -14.78 -8.84 -4.420 0.15094E+05 -6.840 6 S2,gas -7.03 -38.39 -31.36 -4.824 0.53539E+05 -29.356 7 CO,gas 3.51 -12.15 -15.66 -4.818 0.26738E+05 -13.659 8 SO3,gas 17.43 -32.43 -49.86 -12.464 0.85128E+05 -47.856 9 SO2,gas 1.14 -28.02 -29.15 -7.774 0.49779E+05 -27.154 10 HCl,gas 5.48 -14.05 -19.53 -9.765 0.33347E+05 -17.530 11 acmite 7.74 6.59 -1.14 -0.119 0.19511E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.74 -4.81 -0.241 0.82172E+04 20 analcite 3.37 2.82 -0.56 -0.062 0.94779E+03 26 annite 20.21 17.79 -2.42 -0.135 0.41355E+04 27 phlogopite 27.15 25.49 -1.66 -0.092 0.28294E+04 29 anorthite 12.80 8.31 -4.48 -0.345 0.76562E+04 35 aragonite 0.99 -3.47 -4.45 -1.485 0.76066E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55826E+04 37 calcite 0.83 -3.47 -4.30 -1.434 0.73453E+04 38 carnegieite-low 9.06 5.96 -3.11 -0.444 0.53018E+04 39 carnegieite-high 10.13 5.96 -4.17 -0.596 0.71287E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70374E+04 41 carpholite-Fe 6.78 1.96 -4.82 -0.321 0.82325E+04 42 celadonite 5.40 3.73 -1.67 -0.098 0.28500E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47347E+04 44 chrysotile 23.94 21.63 -2.30 -0.192 0.39338E+04 49 chlorite-Al-free 47.26 43.27 -3.99 -0.166 0.68208E+04 51 chloritoid-Fe 9.24 5.11 -4.13 -0.276 0.70575E+04 52 chloritoid-Mn 11.46 7.59 -3.88 -0.259 0.66210E+04 54 coesite -2.37 -3.14 -0.77 -0.258 0.13226E+04 61 cristobalite -2.55 -3.14 -0.59 -0.198 0.10154E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.75 -2.14 -0.357 0.36562E+04 66 diamond -3.11 -7.74 -4.63 -1.323 0.79059E+04 67 diopside 16.22 16.11 -0.10 -0.010 0.17794E+03 68 hedenbergite 14.24 13.54 -0.70 -0.070 0.11962E+04 71 enstatite 17.30 12.33 -4.97 -0.497 0.84940E+04 73 clinoenstatite 17.20 12.33 -4.88 -0.488 0.83248E+04 75 epidote 24.78 22.80 -1.98 -0.096 0.33799E+04 76 clinozoisite 22.92 19.02 -3.90 -0.177 0.66669E+04 77 epidote-Fe 29.94 26.57 -3.36 -0.175 0.57404E+04 78 fayalite 14.08 10.34 -3.74 -0.535 0.63919E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68233E+04 83 gibbsite 4.10 0.75 -3.34 -0.478 0.57074E+04 84 glaucophane 23.11 20.98 -2.13 -0.058 0.36433E+04 85 glaucophane-Fe 17.42 13.27 -4.14 -0.112 0.70734E+04 86 graphite -3.55 -7.74 -4.19 -1.197 0.71521E+04 87 greenalite 16.19 13.93 -2.26 -0.189 0.38639E+04 90 hematite 12.60 9.07 -3.53 -0.428 0.60270E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.44 -0.144 0.24508E+04 97 kalsilite 7.62 3.86 -3.76 -0.538 0.64273E+04 98 kaolinite -1.27 -4.78 -3.51 -0.319 0.59849E+04 101 laumontite 2.97 2.03 -0.95 -0.063 0.16198E+04 102 lawsonite 9.68 8.31 -1.36 -0.091 0.23301E+04 103 leucite 4.17 0.71 -3.46 -0.346 0.59002E+04 105 lizardite 23.29 21.63 -1.65 -0.138 0.28240E+04 107 magnetite 20.13 15.81 -4.33 -0.353 0.73852E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48104E+04 112 manganosite 14.07 9.22 -4.85 -1.212 0.82780E+04 120 muscovite 2.68 -0.92 -3.60 -0.212 0.61493E+04 121 paragonite 4.34 1.18 -3.16 -0.186 0.53878E+04 122 nepheline 8.38 5.96 -2.42 -0.346 0.41298E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.225 0.83657E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36513E+04 136 prehnite 19.47 18.26 -1.20 -0.071 0.20567E+04 137 prehnite-Fe 22.59 22.04 -0.55 -0.033 0.93201E+03 138 pumpellyite-Fe 46.47 44.02 -2.45 -0.054 0.41875E+04 139 pumpellyite-Mg 49.19 46.59 -2.61 -0.058 0.44540E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64872E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.262 0.58589E+04 145 pyroxmangite 7.42 6.08 -1.34 -0.268 0.22882E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84828E+04 147 quartz -2.98 -3.14 -0.16 -0.054 0.27647E+03 152 rhodonite 7.46 6.08 -1.39 -0.277 0.23674E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 26.02 -1.58 -0.047 0.26976E+04 171 talc 16.55 15.35 -1.21 -0.071 0.20621E+04 174 tephroite 18.11 15.30 -2.82 -0.402 0.48101E+04 178 tridymite -2.61 -3.14 -0.53 -0.176 0.90376E+03 179 tremolite 48.00 47.57 -0.44 -0.012 0.74276E+03 180 ferroactinolite 38.60 34.73 -3.87 -0.104 0.65999E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62304E+04 183 vesuvianite 224.06 219.07 -4.98 -0.038 0.85064E+04 187 wairakite 4.06 2.03 -2.03 -0.120 0.34706E+04 188 walstromite 11.53 9.95 -1.58 -0.316 0.26975E+04 189 wollastonite 10.48 9.95 -0.53 -0.107 0.91137E+03 190 pseudo-wollastonite 11.02 9.95 -1.07 -0.214 0.18300E+04 191 zoisite 22.96 19.02 -3.95 -0.179 0.67395E+04 192 akaganeite 7.77 4.53 -3.23 -0.699 0.55217E+04 199 chalcedony -2.79 -3.14 -0.35 -0.117 0.59679E+03 201 montmorillonite-Ca -2.21 -6.08 -3.87 -0.239 0.66073E+04 202 montmorillonite-K -2.16 -6.18 -4.02 -0.246 0.68674E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.266 0.73533E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60242E+04 205 nontronite-Ca 3.28 -0.06 -3.34 -0.217 0.57042E+04 206 nontronite-H 2.60 -2.22 -4.82 -0.323 0.82249E+04 207 nontronite-K 3.40 -0.16 -3.56 -0.229 0.60857E+04 208 nontronite-Mg 3.14 -0.69 -3.82 -0.248 0.65308E+04 209 nontronite-Na 3.58 0.53 -3.05 -0.196 0.52061E+04 224 tobermorite 9.84 7.76 -2.08 -0.567 0.35469E+04 230 alabandite -0.96 -5.56 -4.60 -1.533 0.78549E+04 233 boehmite 4.43 0.75 -3.67 -0.612 0.62746E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.771 0.52667E+04 240 silica-amorphous -2.08 -3.14 -1.06 -0.355 0.18170E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11596E+04 243 an25ab75 2.71 1.83 -0.88 -0.067 0.14974E+04 244 an30ab70 3.34 2.26 -1.08 -0.083 0.18436E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 135.9990000 g New total amount of reactant added: 139.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7248E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 139.9990000 Water: Moles liquid = 0.5464E+02 kg liquid = 0.9843E+00 Moles total = 0.5375E+02 kg total = 0.9684E+00 Activity = 1.0000 Stoichiometric ionic strength = .1169156E-01 Osmotic coef. = 0.9687 True ionic strength = .2061576E-01 Chg. balance for total moles = -.7248E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90888E-10 -10.0415 0.76268E-10 -10.1177 0.83914E+00 -0.0762 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13952E-03 -3.8554 0.11636E-03 -3.9342 0.83400E+00 -0.0788 4 SO4-- 0.11471E-11 -11.9404 0.59235E-12 -12.2274 0.51640E+00 -0.2870 5 HCO3- 0.40272E-06 -6.3950 0.33637E-06 -6.4732 0.83524E+00 -0.0782 6 HS- 0.25905E-04 -4.5866 0.21608E-04 -4.6654 0.83413E+00 -0.0788 7 Al+++ 0.11089E-28 -28.9551 0.25292E-29 -29.5970 0.22808E+00 -0.6419 8 H4SiO4 0.71678E-03 -3.1446 0.71678E-03 -3.1446 0.10000E+01 0.0000 9 Ca++ 0.14108E-06 -6.8505 0.72308E-07 -7.1408 0.51254E+00 -0.2903 10 Mg++ 0.23112E-10 -10.6362 0.11791E-10 -10.9285 0.51016E+00 -0.2923 11 Fe++ 0.62626E-13 -13.2032 0.31985E-13 -13.4951 0.51073E+00 -0.2918 12 K+ 0.16088E-03 -3.7935 0.13441E-03 -3.8716 0.83544E+00 -0.0781 13 Na+ 0.20454E-01 -1.6892 0.17055E-01 -1.7681 0.83385E+00 -0.0789 14 Mn++ 0.18930E-10 -10.7229 0.96761E-11 -11.0143 0.51116E+00 -0.2914 15 HPO4-- 0.50331E-07 -7.2982 0.25995E-07 -7.5851 0.51648E+00 -0.2869 16 HSiO3- 0.10995E-01 -1.9588 0.91695E-02 -2.0377 0.83400E+00 -0.0788 17 Ca(HSiO3)+ 0.17778E-07 -7.7501 0.14855E-07 -7.8281 0.83563E+00 -0.0780 18 Mg(HSiO3)+ 0.36077E-11 -11.4428 0.30147E-11 -11.5208 0.83563E+00 -0.0780 19 NaHSiO3,aq 0.24838E-02 -2.6049 0.24838E-02 -2.6049 0.10000E+01 0.0000 20 AlO+ 0.67174E-16 -16.1728 0.56133E-16 -16.2508 0.83563E+00 -0.0780 22 HAlO2,aq 0.14728E-09 -9.8319 0.14728E-09 -9.8319 0.10000E+01 0.0000 23 AlO2- 0.51795E-05 -5.2857 0.43119E-05 -5.3653 0.83248E+00 -0.0796 24 CH4,aq 0.12084E-04 -4.9178 0.12040E-04 -4.9194 0.99644E+00 -0.0016 25 C2H6,aq 0.25335E-14 -14.5963 0.25245E-14 -14.5978 0.99644E+00 -0.0016 29 CO,aq 0.13193E-16 -16.8797 0.13193E-16 -16.8797 0.10000E+01 0.0000 30 CO2,aq 0.51909E-10 -10.2848 0.51724E-10 -10.2863 0.99644E+00 -0.0016 31 CO3-2 0.79136E-06 -6.1016 0.40778E-06 -6.3896 0.51529E+00 -0.2879 32 CaCO3,aq 0.36113E-09 -9.4423 0.36113E-09 -9.4423 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.73340E-12 -12.1347 0.61285E-12 -12.2126 0.83563E+00 -0.0780 34 CaCl+ 0.16045E-10 -10.7947 0.13407E-10 -10.8727 0.83563E+00 -0.0780 35 CaCl2,aq 0.36325E-15 -15.4398 0.36325E-15 -15.4398 0.10000E+01 0.0000 36 CaOH+ 0.80002E-07 -7.0969 0.66852E-07 -7.1749 0.83563E+00 -0.0780 37 CaSO4,aq 0.13345E-16 -16.8747 0.13345E-16 -16.8747 0.10000E+01 0.0000 38 HCl,aq 0.16693E-14 -14.7775 0.16693E-14 -14.7775 0.10000E+01 0.0000 43 FeCl+ 0.69370E-17 -17.1588 0.57967E-17 -17.2368 0.83563E+00 -0.0780 46 FeO,aq 0.21744E-09 -9.6627 0.21744E-09 -9.6627 0.10000E+01 0.0000 47 FeOH+ 0.16638E-10 -10.7789 0.13903E-10 -10.8569 0.83563E+00 -0.0780 48 HFeO2- 0.36769E-07 -7.4345 0.30665E-07 -7.5134 0.83400E+00 -0.0788 49 FeO+ 0.12866E-16 -16.8906 0.10751E-16 -16.9685 0.83563E+00 -0.0780 51 FeO2- 0.43556E-09 -9.3609 0.36326E-09 -9.4398 0.83400E+00 -0.0788 52 HFeO2,aq 0.34673E-11 -11.4600 0.34673E-11 -11.4600 0.10000E+01 0.0000 53 H2,aq 0.99389E-05 -5.0027 0.99035E-05 -5.0042 0.99644E+00 -0.0016 54 KCl,aq 0.27693E-09 -9.5576 0.27693E-09 -9.5576 0.10000E+01 0.0000 56 KOH,aq 0.76827E-06 -6.1145 0.76827E-06 -6.1145 0.10000E+01 0.0000 57 KSO4- 0.14707E-14 -14.8325 0.12266E-14 -14.9113 0.83400E+00 -0.0788 58 MgCO3,aq 0.14715E-13 -13.8322 0.14715E-13 -13.8322 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12195E-15 -15.9138 0.10191E-15 -15.9918 0.83563E+00 -0.0780 60 MgCl+ 0.23752E-14 -14.6243 0.19848E-14 -14.7023 0.83563E+00 -0.0780 61 MgOH+ 0.72273E-10 -10.1410 0.60393E-10 -10.2190 0.83563E+00 -0.0780 63 MnO,aq 0.17560E-08 -8.7555 0.17560E-08 -8.7555 0.10000E+01 0.0000 64 MnOH+ 0.46758E-09 -9.3301 0.39072E-09 -9.4081 0.83563E+00 -0.0780 65 MnO2-2 0.20261E-10 -10.6933 0.10440E-10 -10.9813 0.51529E+00 -0.2879 66 HMnO2- 0.20686E-09 -9.6843 0.17252E-09 -9.7632 0.83400E+00 -0.0788 69 MnCl+ 0.81548E-14 -14.0886 0.68144E-14 -14.1666 0.83563E+00 -0.0780 71 NaCl,aq 0.64801E-06 -6.1884 0.64801E-06 -6.1884 0.10000E+01 0.0000 72 NaOH,aq 0.98260E-04 -4.0076 0.98260E-04 -4.0076 0.10000E+01 0.0000 74 OH- 0.94475E-02 -2.0247 0.78648E-02 -2.1043 0.83248E+00 -0.0796 79 HPO3-2 0.15780E-14 -14.8019 0.81314E-15 -15.0898 0.51529E+00 -0.2879 81 H2PO3- 0.14607E-18 -18.8354 0.12182E-18 -18.9143 0.83400E+00 -0.0788 82 H3PO4,aq 0.97347E-18 -18.0117 0.97347E-18 -18.0117 0.10000E+01 0.0000 83 H2PO4- 0.41637E-10 -10.3805 0.34759E-10 -10.4589 0.83481E+00 -0.0784 84 PO4-3 0.12414E-08 -8.9061 0.29766E-09 -9.5263 0.23977E+00 -0.6202 88 HP2O7-3 0.11135E-17 -17.9533 0.25423E-18 -18.5948 0.22832E+00 -0.6415 89 P2O7-4 0.10905E-16 -16.9624 0.82232E-18 -18.0850 0.75407E-01 -1.1226 90 H2S,aq 0.49693E-08 -8.3037 0.49516E-08 -8.3053 0.99644E+00 -0.0016 91 S2-2 0.20124E-14 -14.6963 0.10369E-14 -14.9842 0.51529E+00 -0.2879 97 SO3-2 0.15298E-17 -17.8154 0.79987E-18 -18.0970 0.52288E+00 -0.2816 99 HSO4- 0.50114E-19 -19.3000 0.41918E-19 -19.3776 0.83646E+00 -0.0776 Charge balance for all species = -.7303E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9088814E-10 -.2304908E-01 -.2319011E+02 0.0000 2 H2O 0.1000000E+01 0.5550435E+02 0.9981205E+06 0.0000 3 Cl- 0.1395218E-03 0.1401701E-03 0.4960471E+01 6.1835 4 SO4-- 0.1147067E-11 -.1456821E-04 -.1396916E+01 8.0079 5 HCO3- 0.4027183E-06 0.1327802E-04 0.8087233E+00 3.6445 6 HS- 0.2590542E-04 0.4047860E-04 0.1336289E+01 5.4523 7 Al+++ 0.1108924E-28 0.5179685E-05 0.1395031E+00 0.7560 8 H4SiO4 0.7167842E-03 0.1419519E-01 0.1361911E+04 -3.1446 9 Ca++ 0.1410774E-06 0.2392348E-06 0.9570723E-02 13.0945 10 Mg++ 0.2311217E-10 0.9900959E-10 0.2402771E-05 9.3069 11 Fe++ 0.6262582E-13 0.3744181E-07 0.2087234E-02 6.7403 12 K+ 0.1608809E-03 0.1616495E-03 0.6309395E+01 6.2461 13 Na+ 0.2045351E-01 0.2303623E-01 0.5286412E+03 8.3495 14 Mn++ 0.1892972E-10 0.2469650E-08 0.1354324E-03 9.2210 15 HPO4-- 0.5033105E-07 0.5161413E-07 0.4944920E-02 12.6502 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2318163E+01 -.2268799E-01 -.2295475E+01 0.0000000E+00 2 H2O 0.5375331E+02 0.5463480E+02 -.8814965E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3905354E-02 -.1433998E-04 0.3919694E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3879850E-02 0.3984445E-04 -.3919694E-02 0.0000000E+00 7 Al+++ 0.4565006E+00 0.5098538E-05 0.4564955E+00 0.0000000E+00 8 H4SiO4 0.1457779E+01 0.1397281E-01 0.1443806E+01 0.0000000E+00 9 Ca++ 0.1610333E+00 0.2354868E-06 0.1610331E+00 0.0000000E+00 10 Mg++ 0.1111103E+00 0.9745847E-10 0.1111103E+00 0.0000000E+00 11 Fe++ 0.9982049E-01 0.3685523E-07 0.9982045E-01 0.0000000E+00 12 K+ 0.2972378E-01 0.1591170E-03 0.2956466E-01 0.0000000E+00 13 Na+ 0.1758929E+00 0.2267534E-01 0.1532176E+00 0.0000000E+00 14 Mn++ 0.2427386E-02 0.2430959E-08 0.2427384E-02 0.0000000E+00 15 HPO4-- 0.8284548E-03 0.5080552E-07 0.8284040E-03 0.0000000E+00 Chg. balance for solid moles: -.4792E-16 Mass of aqueous solution: 0.986116E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 139.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1531 -0.815 40.14 1.604 26.28 15.41 andradite 0.1568E-01 -1.805 7.968 0.901 5.216 2.070 grossular 0.3554E-02 -2.449 1.601 0.204 1.048 0.4455 apatite-OH 0.2761E-03 -3.559 0.1387 -0.858 0.9080E-01 0.4408E-01 clinochlore 0.2140E-01 -1.670 11.90 1.075 7.788 4.525 daphnite 0.6076E-02 -2.216 4.336 0.637 2.838 1.314 chlorite-Mn 0.4855E-03 -3.314 0.3442 -0.463 0.2253 0.1097 microcline 0.2590E-01 -1.587 7.208 0.858 4.719 2.816 stilbite 0.9970E-01 -1.001 70.26 1.847 45.99 32.77 stilpnomelane-Fe 0.7334E-02 -2.135 7.906 0.898 5.175 2.731 tr.625ac.25prg.125 0.1129E-02 -2.947 0.9650 -0.015 0.6317 0.3106 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8152E+00 0.8152E+00 1.0000 -0.089 grossular 0.1848E+00 0.1848E+00 1.0000 -0.733 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7654E+00 0.7654E+00 1.0000 -0.116 daphnite 0.2173E+00 0.2173E+00 1.0000 -0.663 chlorite-Mn 0.1736E-01 0.1736E-01 1.0000 -1.760 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 152.760133 g Volume = 62.543508 cm3 Porosity: -9.7262% V(tot) - V(min): -.55439E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 139.9990000 g log = 2.1461 Original solution: 1000.0103000 g Original solution / Rock added: 7.14 (Water/Rock Ratio), log = 0.8539 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0848 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9702E+00 0.9851 0.1037E+01 0.1052E+01 CO2,gas 0.5419E-08 1.0072 0.5921E-08 0.5879E-08 CH4,gas 0.1733E-01 1.0128 0.1904E-01 0.1880E-01 H2,gas 0.1251E-01 1.0006 0.1358E-01 0.1358E-01 H2S,gas 0.1337E-06 0.9958 0.1444E-06 0.1450E-06 S2,gas 0.3903E-29 1.0000 0.4234E-29 0.4234E-29 CO,gas 0.1920E-13 1.0000 0.2083E-13 0.2083E-13 SO3,gas 0.1187E-47 1.0000 0.1288E-47 0.1288E-47 SO2,gas 0.6102E-27 1.0000 0.6619E-27 0.6619E-27 HCl,gas 0.2717E-17 1.0000 0.2948E-17 0.2948E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.59 -10.23 -3.409 0.17463E+05 -8.228 3 CH4,gas 4.81 1.09 -3.72 -0.930 0.63523E+04 -1.720 4 H2,gas 8.29 4.42 -3.87 -2.210 0.66028E+04 -1.867 5 H2S,gas -5.94 -14.78 -8.84 -4.420 0.15095E+05 -6.840 6 S2,gas -7.03 -38.41 -31.37 -4.827 0.53569E+05 -29.373 7 CO,gas 3.51 -12.17 -15.68 -4.825 0.26775E+05 -13.681 8 SO3,gas 17.43 -32.46 -49.89 -12.473 0.85186E+05 -47.890 9 SO2,gas 1.14 -28.04 -29.18 -7.781 0.49823E+05 -27.179 10 HCl,gas 5.48 -14.05 -19.53 -9.765 0.33348E+05 -17.531 11 acmite 7.74 6.59 -1.15 -0.119 0.19581E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.74 -4.81 -0.240 0.82108E+04 20 analcite 3.37 2.82 -0.55 -0.062 0.94660E+03 26 annite 20.21 17.79 -2.42 -0.134 0.41327E+04 27 phlogopite 27.15 25.49 -1.66 -0.092 0.28307E+04 29 anorthite 12.80 8.32 -4.48 -0.345 0.76503E+04 35 aragonite 0.99 -3.50 -4.48 -1.494 0.76539E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55830E+04 37 calcite 0.83 -3.50 -4.33 -1.443 0.73925E+04 38 carnegieite-low 9.06 5.96 -3.10 -0.443 0.52995E+04 39 carnegieite-high 10.13 5.96 -4.17 -0.596 0.71263E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70362E+04 41 carpholite-Fe 6.78 1.96 -4.82 -0.321 0.82299E+04 42 celadonite 5.40 3.73 -1.67 -0.098 0.28516E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47350E+04 44 chrysotile 23.94 21.63 -2.31 -0.192 0.39374E+04 49 chlorite-Al-free 47.26 43.26 -4.00 -0.167 0.68281E+04 51 chloritoid-Fe 9.24 5.11 -4.13 -0.275 0.70538E+04 52 chloritoid-Mn 11.46 7.59 -3.87 -0.258 0.66163E+04 54 coesite -2.37 -3.14 -0.78 -0.258 0.13237E+04 61 cristobalite -2.55 -3.14 -0.60 -0.198 0.10166E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.357 0.36542E+04 66 diamond -3.11 -7.75 -4.64 -1.327 0.79290E+04 67 diopside 16.22 16.11 -0.10 -0.010 0.17644E+03 68 hedenbergite 14.24 13.55 -0.70 -0.070 0.11933E+04 71 enstatite 17.30 12.32 -4.98 -0.498 0.84972E+04 73 clinoenstatite 17.20 12.32 -4.88 -0.488 0.83280E+04 75 epidote 24.78 22.80 -1.98 -0.096 0.33771E+04 76 clinozoisite 22.92 19.02 -3.90 -0.177 0.66559E+04 77 epidote-Fe 29.94 26.57 -3.37 -0.175 0.57457E+04 78 fayalite 14.08 10.34 -3.74 -0.535 0.63912E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68237E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.57054E+04 84 glaucophane 23.11 20.97 -2.14 -0.058 0.36470E+04 85 glaucophane-Fe 17.42 13.27 -4.14 -0.112 0.70730E+04 86 graphite -3.55 -7.75 -4.20 -1.201 0.71752E+04 87 greenalite 16.19 13.93 -2.26 -0.189 0.38634E+04 90 hematite 12.60 9.06 -3.54 -0.429 0.60394E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24496E+04 97 kalsilite 7.62 3.86 -3.76 -0.538 0.64249E+04 98 kaolinite -1.27 -4.78 -3.50 -0.319 0.59833E+04 101 laumontite 2.97 2.03 -0.95 -0.063 0.16162E+04 102 lawsonite 9.68 8.32 -1.36 -0.091 0.23242E+04 103 leucite 4.17 0.71 -3.45 -0.345 0.58990E+04 105 lizardite 23.29 21.63 -1.66 -0.138 0.28277E+04 107 magnetite 20.13 15.80 -4.33 -0.354 0.73967E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48123E+04 112 manganosite 14.07 9.22 -4.85 -1.212 0.82760E+04 120 muscovite 2.68 -0.92 -3.60 -0.212 0.61453E+04 121 paragonite 4.34 1.18 -3.15 -0.185 0.53838E+04 122 nepheline 8.38 5.96 -2.42 -0.345 0.41274E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.225 0.83647E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36526E+04 136 prehnite 19.47 18.27 -1.20 -0.071 0.20477E+04 137 prehnite-Fe 22.59 22.04 -0.55 -0.033 0.93114E+03 138 pumpellyite-Fe 46.47 44.03 -2.44 -0.054 0.41665E+04 139 pumpellyite-Mg 49.19 46.60 -2.60 -0.058 0.44344E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64871E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.262 0.58607E+04 145 pyroxmangite 7.42 6.08 -1.34 -0.268 0.22874E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84836E+04 147 quartz -2.98 -3.14 -0.16 -0.054 0.27766E+03 152 rhodonite 7.46 6.08 -1.39 -0.277 0.23666E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 26.01 -1.58 -0.047 0.27045E+04 171 talc 16.55 15.34 -1.21 -0.071 0.20682E+04 174 tephroite 18.11 15.30 -2.82 -0.402 0.48074E+04 178 tridymite -2.61 -3.14 -0.53 -0.177 0.90495E+03 179 tremolite 48.00 47.57 -0.44 -0.012 0.74576E+03 180 ferroactinolite 38.60 34.73 -3.86 -0.104 0.65961E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62302E+04 183 vesuvianite 224.06 219.12 -4.93 -0.038 0.84249E+04 187 wairakite 4.06 2.03 -2.03 -0.119 0.34670E+04 188 walstromite 11.53 9.95 -1.58 -0.316 0.26944E+04 189 wollastonite 10.48 9.95 -0.53 -0.106 0.90825E+03 190 pseudo-wollastonite 11.02 9.95 -1.07 -0.214 0.18269E+04 191 zoisite 22.96 19.02 -3.94 -0.179 0.67284E+04 192 akaganeite 7.77 4.53 -3.24 -0.700 0.55278E+04 199 chalcedony -2.79 -3.14 -0.35 -0.117 0.59797E+03 201 montmorillonite-Ca -2.21 -6.08 -3.87 -0.239 0.66081E+04 202 montmorillonite-K -2.16 -6.18 -4.02 -0.246 0.68684E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.266 0.73549E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60253E+04 205 nontronite-Ca 3.28 -0.07 -3.35 -0.217 0.57196E+04 206 nontronite-H 2.60 -2.23 -4.83 -0.323 0.82409E+04 207 nontronite-K 3.40 -0.17 -3.57 -0.229 0.61013E+04 208 nontronite-Mg 3.14 -0.70 -3.83 -0.249 0.65469E+04 209 nontronite-Na 3.58 0.52 -3.06 -0.196 0.52217E+04 224 tobermorite 9.84 7.76 -2.08 -0.566 0.35445E+04 230 alabandite -0.96 -5.56 -4.60 -1.533 0.78537E+04 233 boehmite 4.43 0.76 -3.67 -0.612 0.62726E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.771 0.52658E+04 240 silica-amorphous -2.08 -3.14 -1.06 -0.355 0.18182E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11584E+04 243 an25ab75 2.71 1.83 -0.88 -0.067 0.14960E+04 244 an30ab70 3.34 2.27 -1.08 -0.083 0.18418E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 139.9990000 g New total amount of reactant added: 143.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7222E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 143.9990000 Water: Moles liquid = 0.5462E+02 kg liquid = 0.9839E+00 Moles total = 0.5370E+02 kg total = 0.9675E+00 Activity = 1.0000 Stoichiometric ionic strength = .1169860E-01 Osmotic coef. = 0.9687 True ionic strength = .2062853E-01 Chg. balance for total moles = -.7222E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90765E-10 -10.0421 0.76162E-10 -10.1183 0.83911E+00 -0.0762 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13958E-03 -3.8552 0.11640E-03 -3.9340 0.83397E+00 -0.0788 4 SO4-- 0.10692E-11 -11.9709 0.55204E-12 -12.2580 0.51632E+00 -0.2871 5 HCO3- 0.37763E-06 -6.4229 0.31540E-06 -6.5011 0.83521E+00 -0.0782 6 HS- 0.25916E-04 -4.5864 0.21616E-04 -4.6652 0.83409E+00 -0.0788 7 Al+++ 0.11075E-28 -28.9557 0.25251E-29 -29.5977 0.22799E+00 -0.6421 8 H4SiO4 0.71571E-03 -3.1453 0.71571E-03 -3.1453 0.10000E+01 0.0000 9 Ca++ 0.14148E-06 -6.8493 0.72501E-07 -7.1397 0.51246E+00 -0.2903 10 Mg++ 0.23039E-10 -10.6375 0.11752E-10 -10.9299 0.51007E+00 -0.2924 11 Fe++ 0.62537E-13 -13.2039 0.31934E-13 -13.4958 0.51064E+00 -0.2919 12 K+ 0.16098E-03 -3.7932 0.13448E-03 -3.8713 0.83541E+00 -0.0781 13 Na+ 0.20466E-01 -1.6890 0.17065E-01 -1.7679 0.83381E+00 -0.0789 14 Mn++ 0.18928E-10 -10.7229 0.96735E-11 -11.0144 0.51107E+00 -0.2915 15 HPO4-- 0.50024E-07 -7.3008 0.25832E-07 -7.5878 0.51640E+00 -0.2870 16 HSiO3- 0.10994E-01 -1.9588 0.91686E-02 -2.0377 0.83397E+00 -0.0788 17 Ca(HSiO3)+ 0.17824E-07 -7.7490 0.14893E-07 -7.8270 0.83559E+00 -0.0780 18 Mg(HSiO3)+ 0.35955E-11 -11.4442 0.30044E-11 -11.5222 0.83559E+00 -0.0780 19 NaHSiO3,aq 0.24850E-02 -2.6047 0.24850E-02 -2.6047 0.10000E+01 0.0000 20 AlO+ 0.67253E-16 -16.1723 0.56196E-16 -16.2503 0.83559E+00 -0.0780 22 HAlO2,aq 0.14765E-09 -9.8308 0.14765E-09 -9.8308 0.10000E+01 0.0000 23 AlO2- 0.52001E-05 -5.2840 0.43288E-05 -5.3636 0.83244E+00 -0.0796 24 CH4,aq 0.12162E-04 -4.9150 0.12119E-04 -4.9165 0.99643E+00 -0.0016 25 C2H6,aq 0.25207E-14 -14.5985 0.25117E-14 -14.6000 0.99643E+00 -0.0016 29 CO,aq 0.12579E-16 -16.9004 0.12579E-16 -16.9004 0.10000E+01 0.0000 30 CO2,aq 0.48606E-10 -10.3133 0.48433E-10 -10.3149 0.99643E+00 -0.0016 31 CO3-2 0.74319E-06 -6.1289 0.38289E-06 -6.4169 0.51521E+00 -0.2880 32 CaCO3,aq 0.33999E-09 -9.4685 0.33999E-09 -9.4685 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.68955E-12 -12.1614 0.57618E-12 -12.2394 0.83559E+00 -0.0780 34 CaCl+ 0.16094E-10 -10.7933 0.13448E-10 -10.8713 0.83559E+00 -0.0780 35 CaCl2,aq 0.36448E-15 -15.4383 0.36448E-15 -15.4383 0.10000E+01 0.0000 36 CaOH+ 0.80330E-07 -7.0951 0.67123E-07 -7.1731 0.83559E+00 -0.0780 37 CaSO4,aq 0.12470E-16 -16.9041 0.12470E-16 -16.9041 0.10000E+01 0.0000 38 HCl,aq 0.16676E-14 -14.7779 0.16676E-14 -14.7779 0.10000E+01 0.0000 43 FeCl+ 0.69287E-17 -17.1593 0.57896E-17 -17.2374 0.83559E+00 -0.0780 46 FeO,aq 0.21770E-09 -9.6621 0.21770E-09 -9.6621 0.10000E+01 0.0000 47 FeOH+ 0.16635E-10 -10.7790 0.13900E-10 -10.8570 0.83559E+00 -0.0780 48 HFeO2- 0.36865E-07 -7.4334 0.30745E-07 -7.5122 0.83397E+00 -0.0788 49 FeO+ 0.12748E-16 -16.8946 0.10652E-16 -16.9726 0.83559E+00 -0.0780 51 FeO2- 0.43278E-09 -9.3637 0.36093E-09 -9.4426 0.83397E+00 -0.0788 52 HFeO2,aq 0.34402E-11 -11.4634 0.34402E-11 -11.4634 0.10000E+01 0.0000 53 H2,aq 0.10120E-04 -4.9948 0.10084E-04 -4.9964 0.99643E+00 -0.0016 54 KCl,aq 0.27719E-09 -9.5572 0.27719E-09 -9.5572 0.10000E+01 0.0000 56 KOH,aq 0.76978E-06 -6.1136 0.76978E-06 -6.1136 0.10000E+01 0.0000 57 KSO4- 0.13715E-14 -14.8628 0.11438E-14 -14.9417 0.83397E+00 -0.0788 58 MgCO3,aq 0.13771E-13 -13.8610 0.13771E-13 -13.8610 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11397E-15 -15.9432 0.95236E-16 -16.0212 0.83559E+00 -0.0780 60 MgCl+ 0.23682E-14 -14.6256 0.19789E-14 -14.7036 0.83559E+00 -0.0780 61 MgOH+ 0.72136E-10 -10.1418 0.60276E-10 -10.2199 0.83559E+00 -0.0780 63 MnO,aq 0.17604E-08 -8.7544 0.17604E-08 -8.7544 0.10000E+01 0.0000 64 MnOH+ 0.46813E-09 -9.3296 0.39116E-09 -9.4076 0.83559E+00 -0.0780 65 MnO2-2 0.20372E-10 -10.6910 0.10496E-10 -10.9790 0.51521E+00 -0.2880 66 HMnO2- 0.20767E-09 -9.6826 0.17319E-09 -9.7615 0.83397E+00 -0.0788 69 MnCl+ 0.81559E-14 -14.0885 0.68150E-14 -14.1665 0.83559E+00 -0.0780 71 NaCl,aq 0.64862E-06 -6.1880 0.64862E-06 -6.1880 0.10000E+01 0.0000 72 NaOH,aq 0.98454E-04 -4.0068 0.98454E-04 -4.0068 0.10000E+01 0.0000 74 OH- 0.94610E-02 -2.0241 0.78758E-02 -2.1037 0.83244E+00 -0.0796 79 HPO3-2 0.15970E-14 -14.7967 0.82277E-15 -15.0847 0.51521E+00 -0.2880 81 H2PO3- 0.14760E-18 -18.8309 0.12309E-18 -18.9098 0.83397E+00 -0.0788 82 H3PO4,aq 0.96468E-18 -18.0156 0.96468E-18 -18.0156 0.10000E+01 0.0000 83 H2PO4- 0.41320E-10 -10.3838 0.34493E-10 -10.4623 0.83477E+00 -0.0784 84 PO4-3 0.12358E-08 -8.9080 0.29620E-09 -9.5284 0.23968E+00 -0.6204 88 HP2O7-3 0.10984E-17 -17.9592 0.25070E-18 -18.6008 0.22823E+00 -0.6416 89 P2O7-4 0.10776E-16 -16.9675 0.81205E-18 -18.0904 0.75358E-01 -1.1229 90 H2S,aq 0.49642E-08 -8.3041 0.49465E-08 -8.3057 0.99643E+00 -0.0016 91 S2-2 0.19781E-14 -14.7038 0.10191E-14 -14.9918 0.51521E+00 -0.2880 97 SO3-2 0.14519E-17 -17.8381 0.75903E-18 -18.1197 0.52279E+00 -0.2817 99 HSO4- 0.46641E-19 -19.3312 0.39011E-19 -19.4088 0.83642E+00 -0.0776 Charge balance for all species = -.7458E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9076523E-10 -.2306339E-01 -.2320449E+02 0.0000 2 H2O 0.1000000E+01 0.5550436E+02 0.9981202E+06 0.0000 3 Cl- 0.1395782E-03 0.1402271E-03 0.4962484E+01 6.1842 4 SO4-- 0.1069181E-11 -.1469217E-04 -.1408802E+01 7.9785 5 HCO3- 0.3776330E-06 0.1328341E-04 0.8090515E+00 3.6171 6 HS- 0.2591595E-04 0.4061309E-04 0.1340728E+01 5.4530 7 Al+++ 0.1107504E-28 0.5200220E-05 0.1400561E+00 0.7571 8 H4SiO4 0.7157112E-03 0.1419459E-01 0.1361852E+04 -3.1453 9 Ca++ 0.1414764E-06 0.2399867E-06 0.9600802E-02 13.0969 10 Mg++ 0.2303937E-10 0.9878713E-10 0.2397371E-05 9.3066 11 Fe++ 0.6253664E-13 0.3753589E-07 0.2092477E-02 6.7408 12 K+ 0.1609809E-03 0.1617509E-03 0.6313351E+01 6.2469 13 Na+ 0.2046623E-01 0.2305032E-01 0.5289644E+03 8.3504 14 Mn++ 0.1892783E-10 0.2475547E-08 0.1357558E-03 9.2221 15 HPO4-- 0.5002381E-07 0.5130094E-07 0.4914912E-02 12.6487 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2384397E+01 -.2269285E-01 -.2361704E+01 0.0000000E+00 2 H2O 0.5370316E+02 0.5461262E+02 -.9094578E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4016208E-02 -.1445612E-04 0.4030664E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3990703E-02 0.3996059E-04 -.4030664E-02 0.0000000E+00 7 Al+++ 0.4695435E+00 0.5116673E-05 0.4695384E+00 0.0000000E+00 8 H4SiO4 0.1499430E+01 0.1396654E-01 0.1485464E+01 0.0000000E+00 9 Ca++ 0.1656339E+00 0.2361311E-06 0.1656336E+00 0.0000000E+00 10 Mg++ 0.1142849E+00 0.9720000E-10 0.1142849E+00 0.0000000E+00 11 Fe++ 0.1026725E+00 0.3693283E-07 0.1026725E+00 0.0000000E+00 12 K+ 0.3057304E-01 0.1591522E-03 0.3041388E-01 0.0000000E+00 13 Na+ 0.1809139E+00 0.2267999E-01 0.1582339E+00 0.0000000E+00 14 Mn++ 0.2496740E-02 0.2435775E-08 0.2496738E-02 0.0000000E+00 15 HPO4-- 0.8521251E-03 0.5047673E-07 0.8520746E-03 0.0000000E+00 Chg. balance for solid moles: -.2528E-15 Mass of aqueous solution: 0.985716E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 143.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1581 -0.801 41.45 1.618 26.38 15.91 andradite 0.1612E-01 -1.793 8.193 0.913 5.214 2.129 grossular 0.3693E-02 -2.433 1.663 0.221 1.059 0.4628 apatite-OH 0.2840E-03 -3.547 0.1427 -0.846 0.9080E-01 0.4534E-01 clinochlore 0.2195E-01 -1.659 12.20 1.086 7.764 4.640 daphnite 0.6242E-02 -2.205 4.454 0.649 2.834 1.350 chlorite-Mn 0.4993E-03 -3.302 0.3540 -0.451 0.2253 0.1128 microcline 0.2665E-01 -1.574 7.417 0.870 4.721 2.897 stilbite 0.1023 -0.990 72.06 1.858 45.86 33.61 stilpnomelane-Fe 0.7530E-02 -2.123 8.117 0.909 5.166 2.804 tr.625ac.25prg.125 0.1254E-02 -2.902 1.072 0.030 0.6821 0.3450 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8136E+00 0.8136E+00 1.0000 -0.090 grossular 0.1864E+00 0.1864E+00 1.0000 -0.730 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7650E+00 0.7650E+00 1.0000 -0.116 daphnite 0.2176E+00 0.2176E+00 1.0000 -0.662 chlorite-Mn 0.1741E-01 0.1741E-01 1.0000 -1.759 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 157.127849 g Volume = 64.309860 cm3 Porosity: -9.7445% V(tot) - V(min): -.57103E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 143.9990000 g log = 2.1584 Original solution: 1000.0103000 g Original solution / Rock added: 6.94 (Water/Rock Ratio), log = 0.8416 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0852 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9698E+00 0.9851 0.1037E+01 0.1052E+01 CO2,gas 0.5073E-08 1.0072 0.5544E-08 0.5505E-08 CH4,gas 0.1744E-01 1.0128 0.1916E-01 0.1892E-01 H2,gas 0.1274E-01 1.0006 0.1383E-01 0.1382E-01 H2S,gas 0.1335E-06 0.9958 0.1443E-06 0.1449E-06 S2,gas 0.3755E-29 1.0000 0.4075E-29 0.4075E-29 CO,gas 0.1830E-13 1.0000 0.1986E-13 0.1986E-13 SO3,gas 0.1103E-47 1.0000 0.1197E-47 0.1197E-47 SO2,gas 0.5772E-27 1.0000 0.6264E-27 0.6264E-27 HCl,gas 0.2713E-17 1.0000 0.2944E-17 0.2944E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.62 -10.26 -3.419 0.17512E+05 -8.256 3 CH4,gas 4.81 1.09 -3.72 -0.929 0.63475E+04 -1.718 4 H2,gas 8.29 4.43 -3.86 -2.205 0.65894E+04 -1.859 5 H2S,gas -5.94 -14.78 -8.84 -4.420 0.15095E+05 -6.841 6 S2,gas -7.03 -38.42 -31.39 -4.829 0.53597E+05 -29.390 7 CO,gas 3.51 -12.19 -15.70 -4.831 0.26811E+05 -13.702 8 SO3,gas 17.43 -32.49 -49.92 -12.480 0.85240E+05 -47.922 9 SO2,gas 1.14 -28.07 -29.20 -7.788 0.49864E+05 -27.203 10 HCl,gas 5.48 -14.05 -19.53 -9.765 0.33349E+05 -17.531 11 acmite 7.74 6.59 -1.15 -0.120 0.19647E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.74 -4.81 -0.240 0.82048E+04 20 analcite 3.37 2.82 -0.55 -0.062 0.94549E+03 26 annite 20.21 17.79 -2.42 -0.134 0.41300E+04 27 phlogopite 27.15 25.49 -1.66 -0.092 0.28319E+04 29 anorthite 12.80 8.32 -4.48 -0.344 0.76447E+04 35 aragonite 0.99 -3.52 -4.51 -1.503 0.76986E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55834E+04 37 calcite 0.83 -3.52 -4.36 -1.452 0.74372E+04 38 carnegieite-low 9.06 5.96 -3.10 -0.443 0.52972E+04 39 carnegieite-high 10.13 5.96 -4.17 -0.596 0.71241E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70351E+04 41 carpholite-Fe 6.78 1.96 -4.82 -0.321 0.82275E+04 42 celadonite 5.40 3.73 -1.67 -0.098 0.28531E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47352E+04 44 chrysotile 23.94 21.63 -2.31 -0.192 0.39408E+04 49 chlorite-Al-free 47.26 43.26 -4.00 -0.167 0.68350E+04 51 chloritoid-Fe 9.24 5.11 -4.13 -0.275 0.70502E+04 52 chloritoid-Mn 11.46 7.59 -3.87 -0.258 0.66118E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13248E+04 61 cristobalite -2.55 -3.15 -0.60 -0.199 0.10177E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.357 0.36523E+04 66 diamond -3.11 -7.76 -4.66 -1.330 0.79510E+04 67 diopside 16.22 16.11 -0.10 -0.010 0.17502E+03 68 hedenbergite 14.24 13.55 -0.70 -0.070 0.11906E+04 71 enstatite 17.30 12.32 -4.98 -0.498 0.85002E+04 73 clinoenstatite 17.20 12.32 -4.88 -0.488 0.83311E+04 75 epidote 24.78 22.80 -1.98 -0.096 0.33744E+04 76 clinozoisite 22.92 19.03 -3.89 -0.177 0.66455E+04 77 epidote-Fe 29.94 26.57 -3.37 -0.175 0.57507E+04 78 fayalite 14.08 10.34 -3.74 -0.535 0.63905E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68242E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.57035E+04 84 glaucophane 23.11 20.97 -2.14 -0.058 0.36504E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70725E+04 86 graphite -3.55 -7.76 -4.22 -1.204 0.71971E+04 87 greenalite 16.19 13.93 -2.26 -0.189 0.38630E+04 90 hematite 12.60 9.05 -3.54 -0.430 0.60510E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24485E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64227E+04 98 kaolinite -1.27 -4.78 -3.50 -0.318 0.59817E+04 101 laumontite 2.97 2.03 -0.94 -0.063 0.16129E+04 102 lawsonite 9.68 8.32 -1.36 -0.091 0.23186E+04 103 leucite 4.17 0.71 -3.45 -0.345 0.58979E+04 105 lizardite 23.29 21.63 -1.66 -0.138 0.28311E+04 107 magnetite 20.13 15.79 -4.34 -0.354 0.74074E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48141E+04 112 manganosite 14.07 9.22 -4.85 -1.211 0.82741E+04 120 muscovite 2.68 -0.92 -3.60 -0.212 0.61416E+04 121 paragonite 4.34 1.19 -3.15 -0.185 0.53800E+04 122 nepheline 8.38 5.96 -2.42 -0.345 0.41252E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.225 0.83638E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36538E+04 136 prehnite 19.47 18.27 -1.19 -0.070 0.20392E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.93035E+03 138 pumpellyite-Fe 46.47 44.04 -2.43 -0.054 0.41468E+04 139 pumpellyite-Mg 49.19 46.61 -2.59 -0.057 0.44159E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64869E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.263 0.58624E+04 145 pyroxmangite 7.42 6.08 -1.34 -0.268 0.22866E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84843E+04 147 quartz -2.98 -3.15 -0.16 -0.054 0.27877E+03 152 rhodonite 7.46 6.08 -1.39 -0.277 0.23659E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 26.01 -1.59 -0.047 0.27109E+04 171 talc 16.55 15.34 -1.21 -0.071 0.20738E+04 174 tephroite 18.11 15.30 -2.81 -0.402 0.48047E+04 178 tridymite -2.61 -3.15 -0.53 -0.177 0.90606E+03 179 tremolite 48.00 47.56 -0.44 -0.012 0.74858E+03 180 ferroactinolite 38.60 34.74 -3.86 -0.104 0.65925E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62301E+04 183 vesuvianite 224.06 219.17 -4.89 -0.037 0.83485E+04 187 wairakite 4.06 2.03 -2.03 -0.119 0.34637E+04 188 walstromite 11.53 9.95 -1.58 -0.315 0.26914E+04 189 wollastonite 10.48 9.95 -0.53 -0.106 0.90533E+03 190 pseudo-wollastonite 11.02 9.95 -1.07 -0.214 0.18239E+04 191 zoisite 22.96 19.03 -3.93 -0.179 0.67181E+04 192 akaganeite 7.77 4.53 -3.24 -0.701 0.55337E+04 199 chalcedony -2.79 -3.15 -0.35 -0.117 0.59908E+03 201 montmorillonite-Ca -2.21 -6.08 -3.87 -0.239 0.66089E+04 202 montmorillonite-K -2.16 -6.18 -4.02 -0.246 0.68694E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73564E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60262E+04 205 nontronite-Ca 3.28 -0.08 -3.36 -0.218 0.57340E+04 206 nontronite-H 2.60 -2.24 -4.84 -0.324 0.82560E+04 207 nontronite-K 3.40 -0.18 -3.58 -0.230 0.61159E+04 208 nontronite-Mg 3.14 -0.70 -3.84 -0.249 0.65621E+04 209 nontronite-Na 3.58 0.52 -3.07 -0.197 0.52363E+04 224 tobermorite 9.84 7.76 -2.07 -0.566 0.35423E+04 230 alabandite -0.96 -5.56 -4.60 -1.533 0.78526E+04 233 boehmite 4.43 0.76 -3.67 -0.612 0.62708E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.771 0.52649E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.355 0.18193E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11573E+04 243 an25ab75 2.71 1.83 -0.88 -0.067 0.14946E+04 244 an30ab70 3.34 2.27 -1.08 -0.083 0.18402E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 143.9990000 g New total amount of reactant added: 147.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7247E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 147.9990000 Water: Moles liquid = 0.5459E+02 kg liquid = 0.9835E+00 Moles total = 0.5365E+02 kg total = 0.9666E+00 Activity = 1.0000 Stoichiometric ionic strength = .1170523E-01 Osmotic coef. = 0.9688 True ionic strength = .2064057E-01 Chg. balance for total moles = -.7247E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90650E-10 -10.0426 0.76063E-10 -10.1188 0.83908E+00 -0.0762 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13963E-03 -3.8550 0.11645E-03 -3.9339 0.83394E+00 -0.0789 4 SO4-- 0.10007E-11 -11.9997 0.51659E-12 -12.2869 0.51624E+00 -0.2871 5 HCO3- 0.35532E-06 -6.4494 0.29675E-06 -6.5276 0.83518E+00 -0.0782 6 HS- 0.25926E-04 -4.5863 0.21624E-04 -4.6651 0.83406E+00 -0.0788 7 Al+++ 0.11062E-28 -28.9562 0.25211E-29 -29.5984 0.22791E+00 -0.6422 8 H4SiO4 0.71470E-03 -3.1459 0.71470E-03 -3.1459 0.10000E+01 0.0000 9 Ca++ 0.14185E-06 -6.8482 0.72682E-07 -7.1386 0.51238E+00 -0.2904 10 Mg++ 0.22971E-10 -10.6388 0.11715E-10 -10.9313 0.50999E+00 -0.2924 11 Fe++ 0.62453E-13 -13.2044 0.31886E-13 -13.4964 0.51056E+00 -0.2920 12 K+ 0.16107E-03 -3.7930 0.13456E-03 -3.8711 0.83538E+00 -0.0781 13 Na+ 0.20478E-01 -1.6887 0.17074E-01 -1.7677 0.83378E+00 -0.0789 14 Mn++ 0.18927E-10 -10.7229 0.96713E-11 -11.0145 0.51099E+00 -0.2916 15 HPO4-- 0.49737E-07 -7.3033 0.25680E-07 -7.5904 0.51632E+00 -0.2871 16 HSiO3- 0.10993E-01 -1.9589 0.91676E-02 -2.0377 0.83394E+00 -0.0789 17 Ca(HSiO3)+ 0.17867E-07 -7.7479 0.14929E-07 -7.8260 0.83556E+00 -0.0780 18 Mg(HSiO3)+ 0.35841E-11 -11.4456 0.29947E-11 -11.5236 0.83556E+00 -0.0780 19 NaHSiO3,aq 0.24861E-02 -2.6045 0.24861E-02 -2.6045 0.10000E+01 0.0000 20 AlO+ 0.67327E-16 -16.1718 0.56256E-16 -16.2498 0.83556E+00 -0.0780 22 HAlO2,aq 0.14800E-09 -9.8297 0.14800E-09 -9.8297 0.10000E+01 0.0000 23 AlO2- 0.52194E-05 -5.2824 0.43447E-05 -5.3620 0.83241E+00 -0.0797 24 CH4,aq 0.12233E-04 -4.9125 0.12189E-04 -4.9140 0.99643E+00 -0.0016 25 C2H6,aq 0.25070E-14 -14.6008 0.24981E-14 -14.6024 0.99643E+00 -0.0016 29 CO,aq 0.12022E-16 -16.9200 0.12022E-16 -16.9200 0.10000E+01 0.0000 30 CO2,aq 0.45672E-10 -10.3403 0.45509E-10 -10.3419 0.99643E+00 -0.0016 31 CO3-2 0.70027E-06 -6.1547 0.36073E-06 -6.4428 0.51513E+00 -0.2881 32 CaCO3,aq 0.32111E-09 -9.4933 0.32111E-09 -9.4933 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.65042E-12 -12.1868 0.54347E-12 -12.2648 0.83556E+00 -0.0780 34 CaCl+ 0.16141E-10 -10.7921 0.13487E-10 -10.8701 0.83556E+00 -0.0780 35 CaCl2,aq 0.36566E-15 -15.4369 0.36566E-15 -15.4369 0.10000E+01 0.0000 36 CaOH+ 0.80639E-07 -7.0935 0.67379E-07 -7.1715 0.83556E+00 -0.0780 37 CaSO4,aq 0.11699E-16 -16.9319 0.11699E-16 -16.9319 0.10000E+01 0.0000 38 HCl,aq 0.16660E-14 -14.7783 0.16660E-14 -14.7783 0.10000E+01 0.0000 43 FeCl+ 0.69212E-17 -17.1598 0.57831E-17 -17.2378 0.83556E+00 -0.0780 46 FeO,aq 0.21794E-09 -9.6617 0.21794E-09 -9.6617 0.10000E+01 0.0000 47 FeOH+ 0.16633E-10 -10.7790 0.13898E-10 -10.8571 0.83556E+00 -0.0780 48 HFeO2- 0.36956E-07 -7.4323 0.30819E-07 -7.5112 0.83394E+00 -0.0789 49 FeO+ 0.12638E-16 -16.8983 0.10560E-16 -16.9763 0.83556E+00 -0.0780 51 FeO2- 0.43018E-09 -9.3664 0.35874E-09 -9.4452 0.83394E+00 -0.0789 52 HFeO2,aq 0.34149E-11 -11.4666 0.34149E-11 -11.4666 0.10000E+01 0.0000 53 H2,aq 0.10294E-04 -4.9874 0.10257E-04 -4.9890 0.99643E+00 -0.0016 54 KCl,aq 0.27744E-09 -9.5568 0.27744E-09 -9.5568 0.10000E+01 0.0000 56 KOH,aq 0.77121E-06 -6.1128 0.77121E-06 -6.1128 0.10000E+01 0.0000 57 KSO4- 0.12842E-14 -14.8914 0.10709E-14 -14.9702 0.83394E+00 -0.0789 58 MgCO3,aq 0.12933E-13 -13.8883 0.12933E-13 -13.8883 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10691E-15 -15.9710 0.89326E-16 -16.0490 0.83556E+00 -0.0780 60 MgCl+ 0.23618E-14 -14.6268 0.19734E-14 -14.7048 0.83556E+00 -0.0780 61 MgOH+ 0.72008E-10 -10.1426 0.60167E-10 -10.2206 0.83556E+00 -0.0780 63 MnO,aq 0.17647E-08 -8.7533 0.17647E-08 -8.7533 0.10000E+01 0.0000 64 MnOH+ 0.46865E-09 -9.3291 0.39159E-09 -9.4072 0.83556E+00 -0.0780 65 MnO2-2 0.20477E-10 -10.6887 0.10548E-10 -10.9768 0.51513E+00 -0.2881 66 HMnO2- 0.20845E-09 -9.6810 0.17384E-09 -9.7599 0.83394E+00 -0.0789 69 MnCl+ 0.81574E-14 -14.0884 0.68160E-14 -14.1665 0.83556E+00 -0.0780 71 NaCl,aq 0.64921E-06 -6.1876 0.64921E-06 -6.1876 0.10000E+01 0.0000 72 NaOH,aq 0.98637E-04 -4.0060 0.98637E-04 -4.0060 0.10000E+01 0.0000 74 OH- 0.94738E-02 -2.0235 0.78861E-02 -2.1031 0.83241E+00 -0.0797 79 HPO3-2 0.16151E-14 -14.7918 0.83196E-15 -15.0799 0.51513E+00 -0.2881 81 H2PO3- 0.14906E-18 -18.8266 0.12430E-18 -18.9055 0.83394E+00 -0.0789 82 H3PO4,aq 0.95649E-18 -18.0193 0.95649E-18 -18.0193 0.10000E+01 0.0000 83 H2PO4- 0.41025E-10 -10.3870 0.34245E-10 -10.4654 0.83474E+00 -0.0784 84 PO4-3 0.12305E-08 -8.9099 0.29484E-09 -9.5304 0.23960E+00 -0.6205 88 HP2O7-3 0.10845E-17 -17.9648 0.24743E-18 -18.6065 0.22815E+00 -0.6418 89 P2O7-4 0.10656E-16 -16.9724 0.80251E-18 -18.0955 0.75312E-01 -1.1231 90 H2S,aq 0.49596E-08 -8.3046 0.49419E-08 -8.3061 0.99643E+00 -0.0016 91 S2-2 0.19465E-14 -14.7108 0.10027E-14 -14.9988 0.51513E+00 -0.2881 97 SO3-2 0.13821E-17 -17.8594 0.72247E-18 -18.1412 0.52272E+00 -0.2817 99 HSO4- 0.43590E-19 -19.3606 0.36459E-19 -19.4382 0.83639E+00 -0.0776 Charge balance for all species = -.7464E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9064991E-10 -.2307686E-01 -.2321804E+02 0.0000 2 H2O 0.1000000E+01 0.5550438E+02 0.9981200E+06 0.0000 3 Cl- 0.1396346E-03 0.1402841E-03 0.4964499E+01 6.1850 4 SO4-- 0.1000677E-11 -.1480623E-04 -.1419739E+01 7.9508 5 HCO3- 0.3553187E-06 0.1328881E-04 0.8093800E+00 3.5912 6 HS- 0.2592650E-04 0.4073769E-04 0.1344841E+01 5.4538 7 Al+++ 0.1106172E-28 0.5219585E-05 0.1405776E+00 0.7581 8 H4SiO4 0.7147045E-03 0.1419403E-01 0.1361798E+04 -3.1459 9 Ca++ 0.1418527E-06 0.2406971E-06 0.9629217E-02 13.0991 10 Mg++ 0.2297117E-10 0.9857857E-10 0.2392309E-05 9.3064 11 Fe++ 0.6245300E-13 0.3762453E-07 0.2097418E-02 6.7413 12 K+ 0.1610750E-03 0.1618465E-03 0.6317077E+01 6.2477 13 Na+ 0.2047821E-01 0.2306360E-01 0.5292688E+03 8.3512 14 Mn++ 0.1892661E-10 0.2481174E-08 0.1360643E-03 9.2231 15 HPO4-- 0.4973669E-07 0.5100826E-07 0.4886869E-02 12.6473 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2450631E+01 -.2269688E-01 -.2427934E+01 0.0000000E+00 2 H2O 0.5365302E+02 0.5459044E+02 -.9374221E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4127061E-02 -.1456243E-04 0.4141624E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4101557E-02 0.4006690E-04 -.4141624E-02 0.0000000E+00 7 Al+++ 0.4825865E+00 0.5133639E-05 0.4825814E+00 0.0000000E+00 8 H4SiO4 0.1541081E+01 0.1396031E-01 0.1527121E+01 0.0000000E+00 9 Ca++ 0.1702344E+00 0.2367338E-06 0.1702342E+00 0.0000000E+00 10 Mg++ 0.1174595E+00 0.9695537E-10 0.1174595E+00 0.0000000E+00 11 Fe++ 0.1055246E+00 0.3700501E-07 0.1055245E+00 0.0000000E+00 12 K+ 0.3142229E-01 0.1591815E-03 0.3126311E-01 0.0000000E+00 13 Na+ 0.1859349E+00 0.2268383E-01 0.1632510E+00 0.0000000E+00 14 Mn++ 0.2566095E-02 0.2440319E-08 0.2566092E-02 0.0000000E+00 15 HPO4-- 0.8757954E-03 0.5016836E-07 0.8757453E-03 0.0000000E+00 Chg. balance for solid moles: 0.7546E-16 Mass of aqueous solution: 0.985316E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 147.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1631 -0.788 42.76 1.631 26.48 16.42 andradite 0.1657E-01 -1.781 8.419 0.925 5.213 2.187 grossular 0.3832E-02 -2.417 1.726 0.237 1.069 0.4803 apatite-OH 0.2919E-03 -3.535 0.1466 -0.834 0.9080E-01 0.4660E-01 clinochlore 0.2249E-01 -1.648 12.50 1.097 7.741 4.755 daphnite 0.6407E-02 -2.193 4.571 0.660 2.831 1.385 chlorite-Mn 0.5132E-03 -3.290 0.3639 -0.439 0.2253 0.1160 microcline 0.2740E-01 -1.562 7.626 0.882 4.722 2.979 stilbite 0.1048 -0.980 73.87 1.868 45.74 34.45 stilpnomelane-Fe 0.7727E-02 -2.112 8.329 0.921 5.158 2.877 tr.625ac.25prg.125 0.1379E-02 -2.860 1.179 0.071 0.7298 0.3793 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8122E+00 0.8122E+00 1.0000 -0.090 grossular 0.1878E+00 0.1878E+00 1.0000 -0.726 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7647E+00 0.7647E+00 1.0000 -0.116 daphnite 0.2178E+00 0.2178E+00 1.0000 -0.662 chlorite-Mn 0.1745E-01 0.1745E-01 1.0000 -1.758 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 161.495525 g Volume = 66.076159 cm3 Porosity: -9.7618% V(tot) - V(min): -.58766E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 147.9990000 g log = 2.1703 Original solution: 1000.0103000 g Original solution / Rock added: 6.76 (Water/Rock Ratio), log = 0.8297 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0855 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9695E+00 0.9851 0.1037E+01 0.1052E+01 CO2,gas 0.4765E-08 1.0072 0.5209E-08 0.5172E-08 CH4,gas 0.1753E-01 1.0128 0.1928E-01 0.1903E-01 H2,gas 0.1295E-01 1.0006 0.1407E-01 0.1406E-01 H2S,gas 0.1333E-06 0.9958 0.1441E-06 0.1447E-06 S2,gas 0.3622E-29 1.0000 0.3932E-29 0.3932E-29 CO,gas 0.1749E-13 1.0000 0.1898E-13 0.1898E-13 SO3,gas 0.1029E-47 1.0000 0.1117E-47 0.1117E-47 SO2,gas 0.5478E-27 1.0000 0.5947E-27 0.5947E-27 HCl,gas 0.2710E-17 1.0000 0.2942E-17 0.2942E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.66728E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.65 -10.28 -3.428 0.17558E+05 -8.283 3 CH4,gas 4.81 1.09 -3.71 -0.929 0.63432E+04 -1.715 4 H2,gas 8.29 4.44 -3.85 -2.201 0.65768E+04 -1.852 5 H2S,gas -5.94 -14.78 -8.84 -4.421 0.15096E+05 -6.841 6 S2,gas -7.03 -38.44 -31.41 -4.832 0.53624E+05 -29.405 7 CO,gas 3.51 -12.21 -15.72 -4.837 0.26844E+05 -13.722 8 SO3,gas 17.43 -32.52 -49.95 -12.488 0.85291E+05 -47.952 9 SO2,gas 1.14 -28.09 -29.23 -7.794 0.49902E+05 -27.226 10 HCl,gas 5.48 -14.05 -19.53 -9.766 0.33349E+05 -17.531 11 acmite 7.74 6.58 -1.15 -0.120 0.19709E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.75 -4.80 -0.240 0.81991E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94445E+03 26 annite 20.21 17.79 -2.42 -0.134 0.41275E+04 27 phlogopite 27.15 25.49 -1.66 -0.092 0.28330E+04 29 anorthite 12.80 8.32 -4.47 -0.344 0.76395E+04 35 aragonite 0.99 -3.55 -4.53 -1.511 0.77409E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55838E+04 37 calcite 0.83 -3.55 -4.38 -1.460 0.74796E+04 38 carnegieite-low 9.06 5.96 -3.10 -0.443 0.52952E+04 39 carnegieite-high 10.13 5.96 -4.17 -0.596 0.71220E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70340E+04 41 carpholite-Fe 6.78 1.97 -4.82 -0.321 0.82253E+04 42 celadonite 5.40 3.73 -1.67 -0.098 0.28545E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47354E+04 44 chrysotile 23.94 21.63 -2.31 -0.192 0.39440E+04 49 chlorite-Al-free 47.26 43.25 -4.01 -0.167 0.68414E+04 51 chloritoid-Fe 9.24 5.11 -4.13 -0.275 0.70469E+04 52 chloritoid-Mn 11.46 7.59 -3.87 -0.258 0.66075E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13259E+04 61 cristobalite -2.55 -3.15 -0.60 -0.199 0.10188E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36506E+04 66 diamond -3.11 -7.78 -4.67 -1.334 0.79719E+04 67 diopside 16.22 16.11 -0.10 -0.010 0.17369E+03 68 hedenbergite 14.24 13.55 -0.70 -0.070 0.11881E+04 71 enstatite 17.30 12.32 -4.98 -0.498 0.85031E+04 73 clinoenstatite 17.20 12.32 -4.88 -0.488 0.83339E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33719E+04 76 clinozoisite 22.92 19.03 -3.89 -0.177 0.66358E+04 77 epidote-Fe 29.94 26.57 -3.37 -0.175 0.57555E+04 78 fayalite 14.08 10.34 -3.74 -0.535 0.63899E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68246E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.57018E+04 84 glaucophane 23.11 20.97 -2.14 -0.058 0.36536E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70721E+04 86 graphite -3.55 -7.78 -4.23 -1.208 0.72181E+04 87 greenalite 16.19 13.93 -2.26 -0.189 0.38626E+04 90 hematite 12.60 9.05 -3.55 -0.430 0.60619E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24475E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64206E+04 98 kaolinite -1.27 -4.78 -3.50 -0.318 0.59803E+04 101 laumontite 2.97 2.03 -0.94 -0.063 0.16098E+04 102 lawsonite 9.68 8.32 -1.35 -0.090 0.23134E+04 103 leucite 4.17 0.71 -3.45 -0.345 0.58969E+04 105 lizardite 23.29 21.63 -1.66 -0.138 0.28343E+04 107 magnetite 20.13 15.79 -4.34 -0.355 0.74175E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48158E+04 112 manganosite 14.07 9.22 -4.84 -1.211 0.82724E+04 120 muscovite 2.68 -0.92 -3.59 -0.211 0.61381E+04 121 paragonite 4.34 1.19 -3.15 -0.185 0.53765E+04 122 nepheline 8.38 5.96 -2.41 -0.345 0.41231E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83630E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36549E+04 136 prehnite 19.47 18.28 -1.19 -0.070 0.20312E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92961E+03 138 pumpellyite-Fe 46.47 44.05 -2.42 -0.054 0.41283E+04 139 pumpellyite-Mg 49.19 46.62 -2.58 -0.057 0.43986E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64868E+04 144 pyrrhotiteFe0.875 -6.00 -9.44 -3.43 -1.263 0.58639E+04 145 pyroxmangite 7.42 6.08 -1.34 -0.268 0.22859E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84849E+04 147 quartz -2.98 -3.15 -0.16 -0.055 0.27981E+03 152 rhodonite 7.46 6.08 -1.39 -0.277 0.23651E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 26.01 -1.59 -0.047 0.27169E+04 171 talc 16.55 15.34 -1.22 -0.072 0.20791E+04 174 tephroite 18.11 15.30 -2.81 -0.402 0.48022E+04 178 tridymite -2.61 -3.15 -0.53 -0.177 0.90710E+03 179 tremolite 48.00 47.56 -0.44 -0.012 0.75123E+03 180 ferroactinolite 38.60 34.74 -3.86 -0.104 0.65891E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62300E+04 183 vesuvianite 224.06 219.21 -4.85 -0.037 0.82766E+04 187 wairakite 4.06 2.03 -2.03 -0.119 0.34606E+04 188 walstromite 11.53 9.95 -1.57 -0.315 0.26887E+04 189 wollastonite 10.48 9.95 -0.53 -0.106 0.90258E+03 190 pseudo-wollastonite 11.02 9.95 -1.07 -0.213 0.18212E+04 191 zoisite 22.96 19.03 -3.93 -0.179 0.67084E+04 192 akaganeite 7.77 4.52 -3.24 -0.701 0.55391E+04 199 chalcedony -2.79 -3.15 -0.35 -0.117 0.60013E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.239 0.66096E+04 202 montmorillonite-K -2.16 -6.18 -4.02 -0.246 0.68703E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73578E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60271E+04 205 nontronite-Ca 3.28 -0.09 -3.37 -0.218 0.57476E+04 206 nontronite-H 2.60 -2.25 -4.84 -0.325 0.82702E+04 207 nontronite-K 3.40 -0.19 -3.59 -0.230 0.61296E+04 208 nontronite-Mg 3.14 -0.71 -3.85 -0.250 0.65763E+04 209 nontronite-Na 3.58 0.51 -3.07 -0.197 0.52500E+04 224 tobermorite 9.84 7.77 -2.07 -0.566 0.35402E+04 230 alabandite -0.96 -5.56 -4.60 -1.533 0.78515E+04 233 boehmite 4.43 0.76 -3.67 -0.612 0.62690E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.771 0.52641E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.355 0.18203E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11563E+04 243 an25ab75 2.71 1.83 -0.87 -0.067 0.14933E+04 244 an30ab70 3.34 2.27 -1.08 -0.083 0.18386E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 147.9990000 g New total amount of reactant added: 151.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7227E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 151.9990000 Water: Moles liquid = 0.5457E+02 kg liquid = 0.9831E+00 Moles total = 0.5360E+02 kg total = 0.9657E+00 Activity = 1.0000 Stoichiometric ionic strength = .1171150E-01 Osmotic coef. = 0.9689 True ionic strength = .2065192E-01 Chg. balance for total moles = -.7227E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90542E-10 -10.0432 0.75969E-10 -10.1194 0.83905E+00 -0.0762 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13969E-03 -3.8548 0.11649E-03 -3.9337 0.83391E+00 -0.0789 4 SO4-- 0.94009E-12 -12.0268 0.48524E-12 -12.3140 0.51617E+00 -0.2872 5 HCO3- 0.33538E-06 -6.4745 0.28009E-06 -6.5527 0.83515E+00 -0.0782 6 HS- 0.25937E-04 -4.5861 0.21632E-04 -4.6649 0.83403E+00 -0.0788 7 Al+++ 0.11049E-28 -28.9567 0.25174E-29 -29.5990 0.22784E+00 -0.6424 8 H4SiO4 0.71376E-03 -3.1464 0.71376E-03 -3.1464 0.10000E+01 0.0000 9 Ca++ 0.14221E-06 -6.8471 0.72853E-07 -7.1376 0.51230E+00 -0.2905 10 Mg++ 0.22907E-10 -10.6400 0.11681E-10 -10.9325 0.50991E+00 -0.2925 11 Fe++ 0.62374E-13 -13.2050 0.31841E-13 -13.4970 0.51048E+00 -0.2920 12 K+ 0.16116E-03 -3.7927 0.13463E-03 -3.8709 0.83535E+00 -0.0781 13 Na+ 0.20490E-01 -1.6885 0.17083E-01 -1.7674 0.83375E+00 -0.0790 14 Mn++ 0.18926E-10 -10.7229 0.96695E-11 -11.0146 0.51091E+00 -0.2917 15 HPO4-- 0.49468E-07 -7.3057 0.25537E-07 -7.5928 0.51624E+00 -0.2871 16 HSiO3- 0.10993E-01 -1.9589 0.91668E-02 -2.0378 0.83391E+00 -0.0789 17 Ca(HSiO3)+ 0.17908E-07 -7.7469 0.14963E-07 -7.8250 0.83553E+00 -0.0780 18 Mg(HSiO3)+ 0.35733E-11 -11.4469 0.29856E-11 -11.5250 0.83553E+00 -0.0780 19 NaHSiO3,aq 0.24871E-02 -2.6043 0.24871E-02 -2.6043 0.10000E+01 0.0000 20 AlO+ 0.67397E-16 -16.1714 0.56312E-16 -16.2494 0.83553E+00 -0.0780 22 HAlO2,aq 0.14833E-09 -9.8288 0.14833E-09 -9.8288 0.10000E+01 0.0000 23 AlO2- 0.52377E-05 -5.2809 0.43598E-05 -5.3605 0.83238E+00 -0.0797 24 CH4,aq 0.12297E-04 -4.9102 0.12253E-04 -4.9118 0.99643E+00 -0.0016 25 C2H6,aq 0.24929E-14 -14.6033 0.24840E-14 -14.6048 0.99643E+00 -0.0016 29 CO,aq 0.11517E-16 -16.9387 0.11517E-16 -16.9387 0.10000E+01 0.0000 30 CO2,aq 0.43055E-10 -10.3660 0.42902E-10 -10.3675 0.99643E+00 -0.0016 31 CO3-2 0.66187E-06 -6.1792 0.34089E-06 -6.4674 0.51505E+00 -0.2881 32 CaCO3,aq 0.30417E-09 -9.5169 0.30417E-09 -9.5169 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.61538E-12 -12.2109 0.51417E-12 -12.2889 0.83553E+00 -0.0780 34 CaCl+ 0.16185E-10 -10.7909 0.13523E-10 -10.8689 0.83553E+00 -0.0780 35 CaCl2,aq 0.36679E-15 -15.4356 0.36679E-15 -15.4356 0.10000E+01 0.0000 36 CaOH+ 0.80932E-07 -7.0919 0.67621E-07 -7.1699 0.83553E+00 -0.0780 37 CaSO4,aq 0.11015E-16 -16.9580 0.11015E-16 -16.9580 0.10000E+01 0.0000 38 HCl,aq 0.16646E-14 -14.7787 0.16646E-14 -14.7787 0.10000E+01 0.0000 43 FeCl+ 0.69142E-17 -17.1603 0.57770E-17 -17.2383 0.83553E+00 -0.0780 46 FeO,aq 0.21817E-09 -9.6612 0.21817E-09 -9.6612 0.10000E+01 0.0000 47 FeOH+ 0.16631E-10 -10.7791 0.13895E-10 -10.8571 0.83553E+00 -0.0780 48 HFeO2- 0.37042E-07 -7.4313 0.30890E-07 -7.5102 0.83391E+00 -0.0789 49 FeO+ 0.12536E-16 -16.9019 0.10474E-16 -16.9799 0.83553E+00 -0.0780 51 FeO2- 0.42773E-09 -9.3688 0.35669E-09 -9.4477 0.83391E+00 -0.0789 52 HFeO2,aq 0.33912E-11 -11.4696 0.33912E-11 -11.4696 0.10000E+01 0.0000 53 H2,aq 0.10460E-04 -4.9805 0.10423E-04 -4.9820 0.99643E+00 -0.0016 54 KCl,aq 0.27768E-09 -9.5564 0.27768E-09 -9.5564 0.10000E+01 0.0000 56 KOH,aq 0.77256E-06 -6.1121 0.77256E-06 -6.1121 0.10000E+01 0.0000 57 KSO4- 0.12069E-14 -14.9183 0.10065E-14 -14.9972 0.83391E+00 -0.0789 58 MgCO3,aq 0.12186E-13 -13.9141 0.12186E-13 -13.9141 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10061E-15 -15.9974 0.84064E-16 -16.0754 0.83553E+00 -0.0780 60 MgCl+ 0.23558E-14 -14.6279 0.19684E-14 -14.7059 0.83553E+00 -0.0780 61 MgOH+ 0.71888E-10 -10.1433 0.60064E-10 -10.2214 0.83553E+00 -0.0780 63 MnO,aq 0.17687E-08 -8.7524 0.17687E-08 -8.7524 0.10000E+01 0.0000 64 MnOH+ 0.46916E-09 -9.3287 0.39200E-09 -9.4067 0.83553E+00 -0.0780 65 MnO2-2 0.20578E-10 -10.6866 0.10599E-10 -10.9748 0.51505E+00 -0.2881 66 HMnO2- 0.20919E-09 -9.6795 0.17445E-09 -9.7583 0.83391E+00 -0.0789 69 MnCl+ 0.81592E-14 -14.0884 0.68172E-14 -14.1664 0.83553E+00 -0.0780 71 NaCl,aq 0.64978E-06 -6.1872 0.64978E-06 -6.1872 0.10000E+01 0.0000 72 NaOH,aq 0.98809E-04 -4.0052 0.98809E-04 -4.0052 0.10000E+01 0.0000 74 OH- 0.94858E-02 -2.0229 0.78958E-02 -2.1026 0.83238E+00 -0.0797 79 HPO3-2 0.16323E-14 -14.7872 0.84073E-15 -15.0753 0.51505E+00 -0.2881 81 H2PO3- 0.15045E-18 -18.8226 0.12546E-18 -18.9015 0.83391E+00 -0.0789 82 H3PO4,aq 0.94885E-18 -18.0228 0.94885E-18 -18.0228 0.10000E+01 0.0000 83 H2PO4- 0.40748E-10 -10.3899 0.34013E-10 -10.4684 0.83471E+00 -0.0785 84 PO4-3 0.12256E-08 -8.9117 0.29357E-09 -9.5323 0.23953E+00 -0.6206 88 HP2O7-3 0.10715E-17 -17.9700 0.24439E-18 -18.6119 0.22808E+00 -0.6419 89 P2O7-4 0.10544E-16 -16.9770 0.79363E-18 -18.1004 0.75269E-01 -1.1234 90 H2S,aq 0.49553E-08 -8.3049 0.49376E-08 -8.3065 0.99643E+00 -0.0016 91 S2-2 0.19172E-14 -14.7173 0.98744E-15 -15.0055 0.51505E+00 -0.2881 97 SO3-2 0.13195E-17 -17.8796 0.68961E-18 -18.1614 0.52264E+00 -0.2818 99 HSO4- 0.40896E-19 -19.3883 0.34204E-19 -19.4659 0.83636E+00 -0.0776 Charge balance for all species = -.7410E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9054151E-10 -.2308957E-01 -.2323081E+02 0.0000 2 H2O 0.1000000E+01 0.5550439E+02 0.9981198E+06 0.0000 3 Cl- 0.1396911E-03 0.1403411E-03 0.4966515E+01 6.1856 4 SO4-- 0.9400861E-12 -.1491164E-04 -.1429845E+01 7.9247 5 HCO3- 0.3353833E-06 0.1329422E-04 0.8097088E+00 3.5667 6 HS- 0.2593704E-04 0.4085364E-04 0.1348668E+01 5.4545 7 Al+++ 0.1104919E-28 0.5237875E-05 0.1410701E+00 0.7591 8 H4SiO4 0.7137582E-03 0.1419351E-01 0.1361747E+04 -3.1464 9 Ca++ 0.1422080E-06 0.2413692E-06 0.9656100E-02 13.1012 10 Mg++ 0.2290714E-10 0.9838261E-10 0.2387552E-05 9.3062 11 Fe++ 0.6237442E-13 0.3770820E-07 0.2102081E-02 6.7417 12 K+ 0.1611637E-03 0.1619366E-03 0.6320592E+01 6.2485 13 Na+ 0.2048952E-01 0.2307612E-01 0.5295559E+03 8.3519 14 Mn++ 0.1892596E-10 0.2486549E-08 0.1363590E-03 9.2241 15 HPO4-- 0.4946782E-07 0.5073416E-07 0.4860607E-02 12.6459 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2516865E+01 -.2270015E-01 -.2494165E+01 0.0000000E+00 2 H2O 0.5360288E+02 0.5456827E+02 -.9653891E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4237915E-02 -.1466014E-04 0.4252575E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4212410E-02 0.4016461E-04 -.4252575E-02 0.0000000E+00 7 Al+++ 0.4956295E+00 0.5149534E-05 0.4956243E+00 0.0000000E+00 8 H4SiO4 0.1582733E+01 0.1395412E-01 0.1568778E+01 0.0000000E+00 9 Ca++ 0.1748350E+00 0.2372984E-06 0.1748348E+00 0.0000000E+00 10 Mg++ 0.1206341E+00 0.9672332E-10 0.1206341E+00 0.0000000E+00 11 Fe++ 0.1083766E+00 0.3707222E-07 0.1083766E+00 0.0000000E+00 12 K+ 0.3227155E-01 0.1592054E-03 0.3211234E-01 0.0000000E+00 13 Na+ 0.1909558E+00 0.2268693E-01 0.1682689E+00 0.0000000E+00 14 Mn++ 0.2635449E-02 0.2444612E-08 0.2635447E-02 0.0000000E+00 15 HPO4-- 0.8994657E-03 0.4987850E-07 0.8994158E-03 0.0000000E+00 Chg. balance for solid moles: 0.3296E-16 Mass of aqueous solution: 0.984916E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 151.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1681 -0.774 44.07 1.644 26.57 16.92 andradite 0.1701E-01 -1.769 8.644 0.937 5.212 2.246 grossular 0.3971E-02 -2.401 1.789 0.253 1.078 0.4977 apatite-OH 0.2998E-03 -3.523 0.1506 -0.822 0.9080E-01 0.4785E-01 clinochlore 0.2304E-01 -1.638 12.80 1.107 7.720 4.870 daphnite 0.6572E-02 -2.182 4.689 0.671 2.827 1.421 chlorite-Mn 0.5271E-03 -3.278 0.3737 -0.427 0.2253 0.1191 microcline 0.2815E-01 -1.551 7.835 0.894 4.724 3.061 stilbite 0.1074 -0.969 75.68 1.879 45.63 35.30 stilpnomelane-Fe 0.7923E-02 -2.101 8.541 0.932 5.149 2.950 tr.625ac.25prg.125 0.1504E-02 -2.823 1.285 0.109 0.7750 0.4137 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8107E+00 0.8107E+00 1.0000 -0.091 grossular 0.1893E+00 0.1893E+00 1.0000 -0.723 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7644E+00 0.7644E+00 1.0000 -0.117 daphnite 0.2181E+00 0.2181E+00 1.0000 -0.661 chlorite-Mn 0.1749E-01 0.1749E-01 1.0000 -1.757 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 165.863164 g Volume = 67.842411 cm3 Porosity: -9.7781% V(tot) - V(min): -.60428E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 151.9990000 g log = 2.1818 Original solution: 1000.0103000 g Original solution / Rock added: 6.58 (Water/Rock Ratio), log = 0.8182 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0858 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9692E+00 0.9851 0.1037E+01 0.1052E+01 CO2,gas 0.4491E-08 1.0072 0.4911E-08 0.4876E-08 CH4,gas 0.1762E-01 1.0128 0.1938E-01 0.1913E-01 H2,gas 0.1316E-01 1.0006 0.1430E-01 0.1429E-01 H2S,gas 0.1332E-06 0.9958 0.1440E-06 0.1446E-06 S2,gas 0.3500E-29 1.0000 0.3801E-29 0.3801E-29 CO,gas 0.1675E-13 1.0000 0.1819E-13 0.1819E-13 SO3,gas 0.9642E-48 1.0000 0.1047E-47 0.1047E-47 SO2,gas 0.5214E-27 1.0000 0.5662E-27 0.5662E-27 HCl,gas 0.2707E-17 1.0000 0.2939E-17 0.2939E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.67 -10.31 -3.436 0.17602E+05 -8.309 3 CH4,gas 4.81 1.10 -3.71 -0.928 0.63394E+04 -1.713 4 H2,gas 8.29 4.44 -3.84 -2.197 0.65649E+04 -1.845 5 H2S,gas -5.94 -14.78 -8.84 -4.421 0.15097E+05 -6.842 6 S2,gas -7.03 -38.45 -31.42 -4.834 0.53649E+05 -29.420 7 CO,gas 3.51 -12.23 -15.74 -4.843 0.26876E+05 -13.740 8 SO3,gas 17.43 -32.55 -49.98 -12.495 0.85340E+05 -47.980 9 SO2,gas 1.14 -28.11 -29.25 -7.799 0.49938E+05 -27.247 10 HCl,gas 5.48 -14.05 -19.53 -9.766 0.33350E+05 -17.532 11 acmite 7.74 6.58 -1.16 -0.120 0.19767E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.75 -4.80 -0.240 0.81937E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94346E+03 26 annite 20.21 17.79 -2.42 -0.134 0.41252E+04 27 phlogopite 27.15 25.49 -1.66 -0.092 0.28341E+04 29 anorthite 12.80 8.33 -4.47 -0.344 0.76346E+04 35 aragonite 0.99 -3.57 -4.56 -1.519 0.77811E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55841E+04 37 calcite 0.83 -3.57 -4.40 -1.468 0.75198E+04 38 carnegieite-low 9.06 5.96 -3.10 -0.443 0.52932E+04 39 carnegieite-high 10.13 5.96 -4.17 -0.596 0.71201E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70330E+04 41 carpholite-Fe 6.78 1.97 -4.82 -0.321 0.82231E+04 42 celadonite 5.40 3.73 -1.67 -0.098 0.28558E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47356E+04 44 chrysotile 23.94 21.63 -2.31 -0.193 0.39471E+04 49 chlorite-Al-free 47.26 43.25 -4.01 -0.167 0.68475E+04 51 chloritoid-Fe 9.24 5.11 -4.13 -0.275 0.70438E+04 52 chloritoid-Mn 11.46 7.60 -3.87 -0.258 0.66035E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13269E+04 61 cristobalite -2.55 -3.15 -0.60 -0.199 0.10198E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36489E+04 66 diamond -3.11 -7.79 -4.68 -1.337 0.79918E+04 67 diopside 16.22 16.11 -0.10 -0.010 0.17244E+03 68 hedenbergite 14.24 13.55 -0.69 -0.069 0.11857E+04 71 enstatite 17.30 12.32 -4.98 -0.498 0.85058E+04 73 clinoenstatite 17.20 12.32 -4.88 -0.488 0.83366E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33696E+04 76 clinozoisite 22.92 19.04 -3.88 -0.176 0.66267E+04 77 epidote-Fe 29.94 26.56 -3.37 -0.175 0.57600E+04 78 fayalite 14.08 10.34 -3.74 -0.535 0.63893E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68250E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.57001E+04 84 glaucophane 23.11 20.97 -2.14 -0.058 0.36567E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70718E+04 86 graphite -3.55 -7.79 -4.24 -1.211 0.72380E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38622E+04 90 hematite 12.60 9.04 -3.56 -0.431 0.60723E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24465E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64187E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59790E+04 101 laumontite 2.97 2.03 -0.94 -0.063 0.16068E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.23085E+04 103 leucite 4.17 0.71 -3.45 -0.345 0.58959E+04 105 lizardite 23.29 21.63 -1.66 -0.138 0.28374E+04 107 magnetite 20.13 15.78 -4.35 -0.355 0.74271E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48174E+04 112 manganosite 14.07 9.22 -4.84 -1.211 0.82707E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61348E+04 121 paragonite 4.34 1.19 -3.15 -0.185 0.53732E+04 122 nepheline 8.38 5.96 -2.41 -0.345 0.41211E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83622E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36560E+04 136 prehnite 19.47 18.28 -1.19 -0.070 0.20237E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92894E+03 138 pumpellyite-Fe 46.47 44.06 -2.41 -0.054 0.41108E+04 139 pumpellyite-Mg 49.19 46.63 -2.57 -0.057 0.43823E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64867E+04 144 pyrrhotiteFe0.875 -6.00 -9.44 -3.44 -1.263 0.58653E+04 145 pyroxmangite 7.42 6.08 -1.34 -0.268 0.22852E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84856E+04 147 quartz -2.98 -3.15 -0.16 -0.055 0.28079E+03 152 rhodonite 7.46 6.08 -1.38 -0.277 0.23644E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 26.00 -1.59 -0.048 0.27226E+04 171 talc 16.55 15.33 -1.22 -0.072 0.20841E+04 174 tephroite 18.11 15.30 -2.81 -0.402 0.47998E+04 178 tridymite -2.61 -3.15 -0.53 -0.177 0.90809E+03 179 tremolite 48.00 47.56 -0.44 -0.012 0.75372E+03 180 ferroactinolite 38.60 34.74 -3.86 -0.104 0.65859E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62298E+04 183 vesuvianite 224.06 219.25 -4.81 -0.037 0.82090E+04 187 wairakite 4.06 2.03 -2.03 -0.119 0.34576E+04 188 walstromite 11.53 9.95 -1.57 -0.315 0.26861E+04 189 wollastonite 10.48 9.95 -0.53 -0.105 0.89999E+03 190 pseudo-wollastonite 11.02 9.95 -1.07 -0.213 0.18186E+04 191 zoisite 22.96 19.04 -3.92 -0.178 0.66992E+04 192 akaganeite 7.77 4.52 -3.25 -0.702 0.55443E+04 199 chalcedony -2.79 -3.15 -0.35 -0.117 0.60111E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.239 0.66103E+04 202 montmorillonite-K -2.16 -6.19 -4.02 -0.246 0.68711E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73592E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60280E+04 205 nontronite-Ca 3.28 -0.09 -3.37 -0.219 0.57604E+04 206 nontronite-H 2.60 -2.26 -4.85 -0.325 0.82836E+04 207 nontronite-K 3.40 -0.19 -3.60 -0.231 0.61426E+04 208 nontronite-Mg 3.14 -0.72 -3.86 -0.250 0.65898E+04 209 nontronite-Na 3.58 0.50 -3.08 -0.198 0.52630E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35382E+04 230 alabandite -0.96 -5.56 -4.60 -1.533 0.78505E+04 233 boehmite 4.43 0.76 -3.67 -0.612 0.62674E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.771 0.52633E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18213E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11553E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14920E+04 244 an30ab70 3.34 2.27 -1.08 -0.083 0.18371E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 151.9990000 g New total amount of reactant added: 155.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7202E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 155.9990000 Water: Moles liquid = 0.5455E+02 kg liquid = 0.9827E+00 Moles total = 0.5355E+02 kg total = 0.9648E+00 Activity = 1.0000 Stoichiometric ionic strength = .1171743E-01 Osmotic coef. = 0.9689 True ionic strength = .2066266E-01 Chg. balance for total moles = -.7202E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90439E-10 -10.0436 0.75881E-10 -10.1199 0.83902E+00 -0.0762 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13975E-03 -3.8547 0.11653E-03 -3.9336 0.83388E+00 -0.0789 4 SO4-- 0.88622E-12 -12.0525 0.45737E-12 -12.3397 0.51610E+00 -0.2873 5 HCO3- 0.31750E-06 -6.4983 0.26515E-06 -6.5765 0.83512E+00 -0.0783 6 HS- 0.25948E-04 -4.5859 0.21640E-04 -4.6647 0.83400E+00 -0.0788 7 Al+++ 0.11037E-28 -28.9571 0.25140E-29 -29.5996 0.22777E+00 -0.6425 8 H4SiO4 0.71287E-03 -3.1470 0.71287E-03 -3.1470 0.10000E+01 0.0000 9 Ca++ 0.14254E-06 -6.8461 0.73015E-07 -7.1366 0.51223E+00 -0.2905 10 Mg++ 0.22847E-10 -10.6412 0.11648E-10 -10.9337 0.50984E+00 -0.2926 11 Fe++ 0.62300E-13 -13.2055 0.31799E-13 -13.4976 0.51041E+00 -0.2921 12 K+ 0.16125E-03 -3.7925 0.13469E-03 -3.8707 0.83532E+00 -0.0781 13 Na+ 0.20500E-01 -1.6882 0.17091E-01 -1.7672 0.83372E+00 -0.0790 14 Mn++ 0.18926E-10 -10.7229 0.96681E-11 -11.0147 0.51084E+00 -0.2917 15 HPO4-- 0.49216E-07 -7.3079 0.25404E-07 -7.5951 0.51617E+00 -0.2872 16 HSiO3- 0.10992E-01 -1.9589 0.91660E-02 -2.0378 0.83388E+00 -0.0789 17 Ca(HSiO3)+ 0.17947E-07 -7.7460 0.14995E-07 -7.8241 0.83550E+00 -0.0781 18 Mg(HSiO3)+ 0.35632E-11 -11.4482 0.29771E-11 -11.5262 0.83550E+00 -0.0781 19 NaHSiO3,aq 0.24881E-02 -2.6041 0.24881E-02 -2.6041 0.10000E+01 0.0000 20 AlO+ 0.67462E-16 -16.1709 0.56365E-16 -16.2490 0.83550E+00 -0.0781 22 HAlO2,aq 0.14864E-09 -9.8279 0.14864E-09 -9.8279 0.10000E+01 0.0000 23 AlO2- 0.52550E-05 -5.2794 0.43740E-05 -5.3591 0.83235E+00 -0.0797 24 CH4,aq 0.12354E-04 -4.9082 0.12310E-04 -4.9097 0.99643E+00 -0.0016 25 C2H6,aq 0.24785E-14 -14.6058 0.24697E-14 -14.6074 0.99643E+00 -0.0016 29 CO,aq 0.11056E-16 -16.9564 0.11056E-16 -16.9564 0.10000E+01 0.0000 30 CO2,aq 0.40711E-10 -10.3903 0.40566E-10 -10.3918 0.99643E+00 -0.0016 31 CO3-2 0.62737E-06 -6.2025 0.32308E-06 -6.4907 0.51498E+00 -0.2882 32 CaCO3,aq 0.28892E-09 -9.5392 0.28892E-09 -9.5392 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.58386E-12 -12.2337 0.48782E-12 -12.3117 0.83550E+00 -0.0781 34 CaCl+ 0.16228E-10 -10.7897 0.13558E-10 -10.8678 0.83550E+00 -0.0781 35 CaCl2,aq 0.36788E-15 -15.4343 0.36788E-15 -15.4343 0.10000E+01 0.0000 36 CaOH+ 0.81209E-07 -7.0904 0.67850E-07 -7.1684 0.83550E+00 -0.0781 37 CaSO4,aq 0.10405E-16 -16.9827 0.10405E-16 -16.9827 0.10000E+01 0.0000 38 HCl,aq 0.16633E-14 -14.7790 0.16633E-14 -14.7790 0.10000E+01 0.0000 43 FeCl+ 0.69078E-17 -17.1607 0.57715E-17 -17.2387 0.83550E+00 -0.0781 46 FeO,aq 0.21839E-09 -9.6608 0.21839E-09 -9.6608 0.10000E+01 0.0000 47 FeOH+ 0.16628E-10 -10.7792 0.13893E-10 -10.8572 0.83550E+00 -0.0781 48 HFeO2- 0.37123E-07 -7.4304 0.30956E-07 -7.5093 0.83388E+00 -0.0789 49 FeO+ 0.12439E-16 -16.9052 0.10393E-16 -16.9833 0.83550E+00 -0.0781 51 FeO2- 0.42543E-09 -9.3712 0.35475E-09 -9.4501 0.83388E+00 -0.0789 52 HFeO2,aq 0.33689E-11 -11.4725 0.33689E-11 -11.4725 0.10000E+01 0.0000 53 H2,aq 0.10620E-04 -4.9739 0.10582E-04 -4.9754 0.99643E+00 -0.0016 54 KCl,aq 0.27792E-09 -9.5561 0.27792E-09 -9.5561 0.10000E+01 0.0000 56 KOH,aq 0.77383E-06 -6.1114 0.77383E-06 -6.1114 0.10000E+01 0.0000 57 KSO4- 0.11382E-14 -14.9438 0.94911E-15 -15.0227 0.83388E+00 -0.0789 58 MgCO3,aq 0.11517E-13 -13.9386 0.11517E-13 -13.9386 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.94983E-16 -16.0224 0.79358E-16 -16.1004 0.83550E+00 -0.0781 60 MgCl+ 0.23502E-14 -14.6289 0.19636E-14 -14.7069 0.83550E+00 -0.0781 61 MgOH+ 0.71774E-10 -10.1440 0.59967E-10 -10.2221 0.83550E+00 -0.0781 63 MnO,aq 0.17725E-08 -8.7514 0.17725E-08 -8.7514 0.10000E+01 0.0000 64 MnOH+ 0.46965E-09 -9.3282 0.39240E-09 -9.4063 0.83550E+00 -0.0781 65 MnO2-2 0.20673E-10 -10.6846 0.10646E-10 -10.9728 0.51498E+00 -0.2882 66 HMnO2- 0.20990E-09 -9.6780 0.17503E-09 -9.7569 0.83388E+00 -0.0789 69 MnCl+ 0.81613E-14 -14.0882 0.68187E-14 -14.1663 0.83550E+00 -0.0781 71 NaCl,aq 0.65034E-06 -6.1869 0.65034E-06 -6.1869 0.10000E+01 0.0000 72 NaOH,aq 0.98972E-04 -4.0045 0.98972E-04 -4.0045 0.10000E+01 0.0000 74 OH- 0.94972E-02 -2.0224 0.79050E-02 -2.1021 0.83235E+00 -0.0797 79 HPO3-2 0.16488E-14 -14.7828 0.84911E-15 -15.0710 0.51498E+00 -0.2882 81 H2PO3- 0.15178E-18 -18.8188 0.12656E-18 -18.8977 0.83388E+00 -0.0789 82 H3PO4,aq 0.94169E-18 -18.0261 0.94169E-18 -18.0261 0.10000E+01 0.0000 83 H2PO4- 0.40489E-10 -10.3927 0.33796E-10 -10.4711 0.83468E+00 -0.0785 84 PO4-3 0.12210E-08 -8.9133 0.29237E-09 -9.5341 0.23946E+00 -0.6208 88 HP2O7-3 0.10594E-17 -17.9749 0.24156E-18 -18.6170 0.22801E+00 -0.6420 89 P2O7-4 0.10439E-16 -16.9813 0.78534E-18 -18.1049 0.75228E-01 -1.1236 90 H2S,aq 0.49514E-08 -8.3053 0.49337E-08 -8.3068 0.99643E+00 -0.0016 91 S2-2 0.18900E-14 -14.7235 0.97330E-15 -15.0118 0.51498E+00 -0.2882 97 SO3-2 0.12629E-17 -17.8986 0.65994E-18 -18.1805 0.52258E+00 -0.2819 99 HSO4- 0.38504E-19 -19.4145 0.32202E-19 -19.4921 0.83633E+00 -0.0776 Charge balance for all species = -.7611E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9043942E-10 -.2310157E-01 -.2324287E+02 0.0000 2 H2O 0.1000000E+01 0.5550440E+02 0.9981195E+06 0.0000 3 Cl- 0.1397476E-03 0.1403982E-03 0.4968533E+01 6.1863 4 SO4-- 0.8862162E-12 -.1500942E-04 -.1439221E+01 7.9000 5 HCO3- 0.3175001E-06 0.1329962E-04 0.8100377E+00 3.5434 6 HS- 0.2594760E-04 0.4096197E-04 0.1352244E+01 5.4551 7 Al+++ 0.1103739E-28 0.5255175E-05 0.1415360E+00 0.7600 8 H4SiO4 0.7128671E-03 0.1419302E-01 0.1361700E+04 -3.1470 9 Ca++ 0.1425442E-06 0.2420059E-06 0.9681568E-02 13.1032 10 Mg++ 0.2284692E-10 0.9819823E-10 0.2383077E-05 9.3060 11 Fe++ 0.6230044E-13 0.3778728E-07 0.2106489E-02 6.7421 12 K+ 0.1612476E-03 0.1620218E-03 0.6323914E+01 6.2492 13 Na+ 0.2050020E-01 0.2308796E-01 0.5298273E+03 8.3526 14 Mn++ 0.1892581E-10 0.2491688E-08 0.1366407E-03 9.2251 15 HPO4-- 0.4921551E-07 0.5047696E-07 0.4835964E-02 12.6446 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2583099E+01 -.2270271E-01 -.2560396E+01 0.0000000E+00 2 H2O 0.5355274E+02 0.5454610E+02 -.9933585E+00 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4348769E-02 -.1475028E-04 0.4363519E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4323264E-02 0.4025475E-04 -.4363519E-02 0.0000000E+00 7 Al+++ 0.5086724E+00 0.5164443E-05 0.5086673E+00 0.0000000E+00 8 H4SiO4 0.1624384E+01 0.1394797E-01 0.1610436E+01 0.0000000E+00 9 Ca++ 0.1794356E+00 0.2378276E-06 0.1794353E+00 0.0000000E+00 10 Mg++ 0.1238087E+00 0.9650281E-10 0.1238087E+00 0.0000000E+00 11 Fe++ 0.1112286E+00 0.3713487E-07 0.1112286E+00 0.0000000E+00 12 K+ 0.3312081E-01 0.1592244E-03 0.3296158E-01 0.0000000E+00 13 Na+ 0.1959768E+00 0.2268933E-01 0.1732875E+00 0.0000000E+00 14 Mn++ 0.2704804E-02 0.2448668E-08 0.2704801E-02 0.0000000E+00 15 HPO4-- 0.9231360E-03 0.4960545E-07 0.9230864E-03 0.0000000E+00 Chg. balance for solid moles: -.1626E-15 Mass of aqueous solution: 0.984516E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 155.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1731 -0.762 45.39 1.657 26.66 17.42 andradite 0.1745E-01 -1.758 8.870 0.948 5.210 2.304 grossular 0.4110E-02 -2.386 1.851 0.267 1.088 0.5151 apatite-OH 0.3077E-03 -3.512 0.1546 -0.811 0.9080E-01 0.4911E-01 clinochlore 0.2358E-01 -1.627 13.11 1.117 7.699 4.986 daphnite 0.6737E-02 -2.172 4.807 0.682 2.824 1.457 chlorite-Mn 0.5410E-03 -3.267 0.3835 -0.416 0.2253 0.1222 microcline 0.2890E-01 -1.539 8.044 0.905 4.726 3.142 stilbite 0.1099 -0.959 77.48 1.889 45.52 36.14 stilpnomelane-Fe 0.8120E-02 -2.090 8.753 0.942 5.142 3.023 tr.625ac.25prg.125 0.1629E-02 -2.788 1.392 0.144 0.8179 0.4481 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8094E+00 0.8094E+00 1.0000 -0.092 grossular 0.1906E+00 0.1906E+00 1.0000 -0.720 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7642E+00 0.7642E+00 1.0000 -0.117 daphnite 0.2183E+00 0.2183E+00 1.0000 -0.661 chlorite-Mn 0.1753E-01 0.1753E-01 1.0000 -1.756 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 170.230769 g Volume = 69.608618 cm3 Porosity: -9.7935% V(tot) - V(min): -.62090E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 155.9990000 g log = 2.1931 Original solution: 1000.0103000 g Original solution / Rock added: 6.41 (Water/Rock Ratio), log = 0.8069 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0862 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9689E+00 0.9851 0.1037E+01 0.1052E+01 CO2,gas 0.4245E-08 1.0072 0.4643E-08 0.4610E-08 CH4,gas 0.1770E-01 1.0128 0.1947E-01 0.1922E-01 H2,gas 0.1336E-01 1.0006 0.1451E-01 0.1451E-01 H2S,gas 0.1330E-06 0.9958 0.1439E-06 0.1445E-06 S2,gas 0.3389E-29 1.0000 0.3681E-29 0.3681E-29 CO,gas 0.1607E-13 1.0000 0.1746E-13 0.1746E-13 SO3,gas 0.9065E-48 1.0000 0.9845E-48 0.9845E-48 SO2,gas 0.4977E-27 1.0000 0.5406E-27 0.5406E-27 HCl,gas 0.2704E-17 1.0000 0.2937E-17 0.2937E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.48529E-10 23 grossular 32.83 32.83 0.00 0.000 0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.70 -10.33 -3.444 0.17644E+05 -8.333 3 CH4,gas 4.81 1.10 -3.71 -0.928 0.63359E+04 -1.711 4 H2,gas 8.29 4.45 -3.84 -2.193 0.65536E+04 -1.838 5 H2S,gas -5.94 -14.78 -8.84 -4.421 0.15097E+05 -6.842 6 S2,gas -7.03 -38.47 -31.43 -4.836 0.53673E+05 -29.434 7 CO,gas 3.51 -12.25 -15.76 -4.849 0.26906E+05 -13.758 8 SO3,gas 17.43 -32.58 -50.01 -12.502 0.85385E+05 -48.007 9 SO2,gas 1.14 -28.13 -29.27 -7.805 0.49973E+05 -27.267 10 HCl,gas 5.48 -14.05 -19.53 -9.766 0.33351E+05 -17.532 11 acmite 7.74 6.58 -1.16 -0.121 0.19823E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.75 -4.80 -0.240 0.81885E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94254E+03 26 annite 20.21 17.79 -2.41 -0.134 0.41230E+04 27 phlogopite 27.15 25.49 -1.66 -0.092 0.28351E+04 29 anorthite 12.80 8.33 -4.47 -0.344 0.76300E+04 35 aragonite 0.99 -3.59 -4.58 -1.526 0.78193E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55845E+04 37 calcite 0.83 -3.59 -4.43 -1.475 0.75579E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.443 0.52913E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.596 0.71182E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70321E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82211E+04 42 celadonite 5.40 3.73 -1.67 -0.098 0.28571E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47358E+04 44 chrysotile 23.94 21.62 -2.31 -0.193 0.39499E+04 49 chlorite-Al-free 47.26 43.25 -4.01 -0.167 0.68532E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70409E+04 52 chloritoid-Mn 11.46 7.60 -3.87 -0.258 0.65997E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13278E+04 61 cristobalite -2.55 -3.15 -0.60 -0.199 0.10207E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36474E+04 66 diamond -3.11 -7.80 -4.69 -1.340 0.80109E+04 67 diopside 16.22 16.12 -0.10 -0.010 0.17126E+03 68 hedenbergite 14.24 13.55 -0.69 -0.069 0.11835E+04 71 enstatite 17.30 12.32 -4.98 -0.498 0.85083E+04 73 clinoenstatite 17.20 12.32 -4.88 -0.488 0.83391E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33674E+04 76 clinozoisite 22.92 19.05 -3.88 -0.176 0.66180E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.175 0.57642E+04 78 fayalite 14.08 10.34 -3.74 -0.535 0.63888E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68254E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56986E+04 84 glaucophane 23.11 20.97 -2.14 -0.058 0.36595E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70714E+04 86 graphite -3.55 -7.80 -4.25 -1.214 0.72570E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38619E+04 90 hematite 12.60 9.04 -3.56 -0.432 0.60821E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24456E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64168E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59777E+04 101 laumontite 2.97 2.04 -0.94 -0.063 0.16040E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.23038E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58949E+04 105 lizardite 23.29 21.62 -1.66 -0.139 0.28402E+04 107 magnetite 20.13 15.78 -4.36 -0.356 0.74361E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48189E+04 112 manganosite 14.07 9.23 -4.84 -1.211 0.82691E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61316E+04 121 paragonite 4.34 1.19 -3.15 -0.185 0.53701E+04 122 nepheline 8.38 5.97 -2.41 -0.345 0.41193E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83615E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36570E+04 136 prehnite 19.47 18.29 -1.18 -0.069 0.20166E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92831E+03 138 pumpellyite-Fe 46.47 44.07 -2.40 -0.053 0.40944E+04 139 pumpellyite-Mg 49.19 46.64 -2.56 -0.057 0.43670E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64865E+04 144 pyrrhotiteFe0.875 -6.00 -9.44 -3.44 -1.264 0.58667E+04 145 pyroxmangite 7.42 6.08 -1.34 -0.268 0.22845E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84861E+04 147 quartz -2.98 -3.15 -0.16 -0.055 0.28172E+03 152 rhodonite 7.46 6.08 -1.38 -0.277 0.23637E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 26.00 -1.60 -0.048 0.27280E+04 171 talc 16.55 15.33 -1.22 -0.072 0.20888E+04 174 tephroite 18.11 15.30 -2.81 -0.401 0.47975E+04 178 tridymite -2.61 -3.15 -0.53 -0.177 0.90901E+03 179 tremolite 48.00 47.56 -0.44 -0.012 0.75607E+03 180 ferroactinolite 38.60 34.74 -3.86 -0.104 0.65829E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62297E+04 183 vesuvianite 224.06 219.29 -4.77 -0.036 0.81452E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34549E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26837E+04 189 wollastonite 10.48 9.96 -0.53 -0.105 0.89755E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.213 0.18162E+04 191 zoisite 22.96 19.05 -3.92 -0.178 0.66906E+04 192 akaganeite 7.77 4.52 -3.25 -0.703 0.55492E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60204E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66110E+04 202 montmorillonite-K -2.16 -6.19 -4.02 -0.246 0.68719E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73604E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60288E+04 205 nontronite-Ca 3.28 -0.10 -3.38 -0.219 0.57725E+04 206 nontronite-H 2.60 -2.26 -4.86 -0.326 0.82963E+04 207 nontronite-K 3.40 -0.20 -3.60 -0.231 0.61548E+04 208 nontronite-Mg 3.14 -0.73 -3.87 -0.251 0.66025E+04 209 nontronite-Na 3.58 0.49 -3.09 -0.198 0.52753E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35363E+04 230 alabandite -0.96 -5.56 -4.60 -1.532 0.78495E+04 233 boehmite 4.43 0.76 -3.67 -0.612 0.62658E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.771 0.52626E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18222E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11544E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14909E+04 244 an30ab70 3.34 2.27 -1.08 -0.083 0.18357E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 155.9990000 g New total amount of reactant added: 159.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7204E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 159.9990000 Water: Moles liquid = 0.5453E+02 kg liquid = 0.9823E+00 Moles total = 0.5350E+02 kg total = 0.9639E+00 Activity = 1.0000 Stoichiometric ionic strength = .1172304E-01 Osmotic coef. = 0.9690 True ionic strength = .2067282E-01 Chg. balance for total moles = -.7204E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90343E-10 -10.0441 0.75798E-10 -10.1203 0.83900E+00 -0.0762 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13980E-03 -3.8545 0.11658E-03 -3.9334 0.83385E+00 -0.0789 4 SO4-- 0.83809E-12 -12.0767 0.43248E-12 -12.3640 0.51603E+00 -0.2873 5 HCO3- 0.30140E-06 -6.5209 0.25169E-06 -6.5991 0.83509E+00 -0.0783 6 HS- 0.25958E-04 -4.5857 0.21648E-04 -4.6646 0.83397E+00 -0.0788 7 Al+++ 0.11026E-28 -28.9576 0.25107E-29 -29.6002 0.22770E+00 -0.6426 8 H4SiO4 0.71203E-03 -3.1475 0.71203E-03 -3.1475 0.10000E+01 0.0000 9 Ca++ 0.14286E-06 -6.8451 0.73169E-07 -7.1357 0.51216E+00 -0.2906 10 Mg++ 0.22790E-10 -10.6423 0.11618E-10 -10.9349 0.50977E+00 -0.2926 11 Fe++ 0.62231E-13 -13.2060 0.31759E-13 -13.4981 0.51034E+00 -0.2921 12 K+ 0.16133E-03 -3.7923 0.13475E-03 -3.8705 0.83529E+00 -0.0782 13 Na+ 0.20510E-01 -1.6880 0.17099E-01 -1.7670 0.83369E+00 -0.0790 14 Mn++ 0.18926E-10 -10.7229 0.96670E-11 -11.0147 0.51077E+00 -0.2918 15 HPO4-- 0.48978E-07 -7.3100 0.25278E-07 -7.5973 0.51610E+00 -0.2873 16 HSiO3- 0.10991E-01 -1.9589 0.91652E-02 -2.0379 0.83385E+00 -0.0789 17 Ca(HSiO3)+ 0.17984E-07 -7.7451 0.15025E-07 -7.8232 0.83547E+00 -0.0781 18 Mg(HSiO3)+ 0.35537E-11 -11.4493 0.29691E-11 -11.5274 0.83547E+00 -0.0781 19 NaHSiO3,aq 0.24891E-02 -2.6040 0.24891E-02 -2.6040 0.10000E+01 0.0000 20 AlO+ 0.67525E-16 -16.1705 0.56415E-16 -16.2486 0.83547E+00 -0.0781 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52714E-05 -5.2781 0.43875E-05 -5.3578 0.83232E+00 -0.0797 24 CH4,aq 0.12407E-04 -4.9063 0.12363E-04 -4.9079 0.99643E+00 -0.0016 25 C2H6,aq 0.24640E-14 -14.6084 0.24552E-14 -14.6099 0.99643E+00 -0.0016 29 CO,aq 0.10635E-16 -16.9733 0.10635E-16 -16.9733 0.10000E+01 0.0000 30 CO2,aq 0.38602E-10 -10.4134 0.38464E-10 -10.4149 0.99643E+00 -0.0016 31 CO3-2 0.59626E-06 -6.2246 0.30702E-06 -6.5128 0.51491E+00 -0.2883 32 CaCO3,aq 0.27513E-09 -9.5605 0.27513E-09 -9.5605 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.55541E-12 -12.2554 0.46403E-12 -12.3335 0.83547E+00 -0.0781 34 CaCl+ 0.16269E-10 -10.7886 0.13592E-10 -10.8667 0.83547E+00 -0.0781 35 CaCl2,aq 0.36893E-15 -15.4331 0.36893E-15 -15.4331 0.10000E+01 0.0000 36 CaOH+ 0.81471E-07 -7.0890 0.68067E-07 -7.1671 0.83547E+00 -0.0781 37 CaSO4,aq 0.98595E-17 -17.0061 0.98595E-17 -17.0061 0.10000E+01 0.0000 38 HCl,aq 0.16621E-14 -14.7794 0.16621E-14 -14.7794 0.10000E+01 0.0000 43 FeCl+ 0.69020E-17 -17.1610 0.57664E-17 -17.2391 0.83547E+00 -0.0781 46 FeO,aq 0.21859E-09 -9.6604 0.21859E-09 -9.6604 0.10000E+01 0.0000 47 FeOH+ 0.16626E-10 -10.7792 0.13891E-10 -10.8573 0.83547E+00 -0.0781 48 HFeO2- 0.37200E-07 -7.4295 0.31019E-07 -7.5084 0.83385E+00 -0.0789 49 FeO+ 0.12349E-16 -16.9084 0.10317E-16 -16.9864 0.83547E+00 -0.0781 51 FeO2- 0.42326E-09 -9.3734 0.35293E-09 -9.4523 0.83385E+00 -0.0789 52 HFeO2,aq 0.33480E-11 -11.4752 0.33480E-11 -11.4752 0.10000E+01 0.0000 53 H2,aq 0.10774E-04 -4.9676 0.10735E-04 -4.9692 0.99643E+00 -0.0016 54 KCl,aq 0.27815E-09 -9.5557 0.27815E-09 -9.5557 0.10000E+01 0.0000 56 KOH,aq 0.77504E-06 -6.1107 0.77504E-06 -6.1107 0.10000E+01 0.0000 57 KSO4- 0.10768E-14 -14.9679 0.89787E-15 -15.0468 0.83385E+00 -0.0789 58 MgCO3,aq 0.10916E-13 -13.9619 0.10916E-13 -13.9619 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.89929E-16 -16.0461 0.75133E-16 -16.1242 0.83547E+00 -0.0781 60 MgCl+ 0.23450E-14 -14.6298 0.19592E-14 -14.7079 0.83547E+00 -0.0781 61 MgOH+ 0.71667E-10 -10.1447 0.59876E-10 -10.2227 0.83547E+00 -0.0781 63 MnO,aq 0.17762E-08 -8.7505 0.17762E-08 -8.7505 0.10000E+01 0.0000 64 MnOH+ 0.47013E-09 -9.3278 0.39278E-09 -9.4059 0.83547E+00 -0.0781 65 MnO2-2 0.20764E-10 -10.6827 0.10692E-10 -10.9709 0.51491E+00 -0.2883 66 HMnO2- 0.21057E-09 -9.6766 0.17559E-09 -9.7555 0.83385E+00 -0.0789 69 MnCl+ 0.81636E-14 -14.0881 0.68205E-14 -14.1662 0.83547E+00 -0.0781 71 NaCl,aq 0.65088E-06 -6.1865 0.65088E-06 -6.1865 0.10000E+01 0.0000 72 NaOH,aq 0.99126E-04 -4.0038 0.99126E-04 -4.0038 0.10000E+01 0.0000 74 OH- 0.95079E-02 -2.0219 0.79136E-02 -2.1016 0.83232E+00 -0.0797 79 HPO3-2 0.16646E-14 -14.7787 0.85712E-15 -15.0670 0.51491E+00 -0.2883 81 H2PO3- 0.15305E-18 -18.8152 0.12762E-18 -18.8941 0.83385E+00 -0.0789 82 H3PO4,aq 0.93498E-18 -18.0292 0.93498E-18 -18.0292 0.10000E+01 0.0000 83 H2PO4- 0.40246E-10 -10.3953 0.33592E-10 -10.4738 0.83465E+00 -0.0785 84 PO4-3 0.12166E-08 -8.9149 0.29124E-09 -9.5357 0.23939E+00 -0.6209 88 HP2O7-3 0.10481E-17 -17.9796 0.23891E-18 -18.6218 0.22794E+00 -0.6422 89 P2O7-4 0.10342E-16 -16.9854 0.77759E-18 -18.1093 0.75190E-01 -1.1238 90 H2S,aq 0.49479E-08 -8.3056 0.49302E-08 -8.3071 0.99643E+00 -0.0016 91 S2-2 0.18647E-14 -14.7294 0.96014E-15 -15.0177 0.51491E+00 -0.2883 97 SO3-2 0.12115E-17 -17.9167 0.63304E-18 -18.1986 0.52251E+00 -0.2819 99 HSO4- 0.36370E-19 -19.4393 0.30416E-19 -19.5169 0.83630E+00 -0.0776 Charge balance for all species = -.7395E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9034312E-10 -.2311292E-01 -.2325428E+02 0.0000 2 H2O 0.1000000E+01 0.5550441E+02 0.9981193E+06 0.0000 3 Cl- 0.1398041E-03 0.1404553E-03 0.4970552E+01 6.1870 4 SO4-- 0.8380900E-12 -.1510047E-04 -.1447951E+01 7.8767 5 HCO3- 0.3013953E-06 0.1330503E-04 0.8103669E+00 3.5212 6 HS- 0.2595816E-04 0.4106358E-04 0.1355597E+01 5.4558 7 Al+++ 0.1102626E-28 0.5271564E-05 0.1419773E+00 0.7608 8 H4SiO4 0.7120265E-03 0.1419256E-01 0.1361655E+04 -3.1475 9 Ca++ 0.1428626E-06 0.2426100E-06 0.9705728E-02 13.1050 10 Mg++ 0.2279018E-10 0.9802435E-10 0.2378856E-05 9.3058 11 Fe++ 0.6223069E-13 0.3786215E-07 0.2110662E-02 6.7426 12 K+ 0.1613270E-03 0.1621024E-03 0.6327057E+01 6.2499 13 Na+ 0.2051031E-01 0.2309916E-01 0.5300841E+03 8.3533 14 Mn++ 0.1892607E-10 0.2496606E-08 0.1369104E-03 9.2260 15 HPO4-- 0.4897831E-07 0.5023513E-07 0.4812794E-02 12.6434 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2649333E+01 -.2270463E-01 -.2626628E+01 0.0000000E+00 2 H2O 0.5350260E+02 0.5452393E+02 -.1021330E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4459622E-02 -.1483372E-04 0.4474456E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4434118E-02 0.4033819E-04 -.4474456E-02 0.0000000E+00 7 Al+++ 0.5217154E+00 0.5178442E-05 0.5217102E+00 0.0000000E+00 8 H4SiO4 0.1666035E+01 0.1394185E-01 0.1652093E+01 0.0000000E+00 9 Ca++ 0.1840361E+00 0.2383243E-06 0.1840359E+00 0.0000000E+00 10 Mg++ 0.1269833E+00 0.9629275E-10 0.1269833E+00 0.0000000E+00 11 Fe++ 0.1140807E+00 0.3719332E-07 0.1140806E+00 0.0000000E+00 12 K+ 0.3397006E-01 0.1592388E-03 0.3381082E-01 0.0000000E+00 13 Na+ 0.2009978E+00 0.2269111E-01 0.1783067E+00 0.0000000E+00 14 Mn++ 0.2774158E-02 0.2452504E-08 0.2774156E-02 0.0000000E+00 15 HPO4-- 0.9468063E-03 0.4934773E-07 0.9467570E-03 0.0000000E+00 Chg. balance for solid moles: 0.2563E-15 Mass of aqueous solution: 0.984116E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 159.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1781 -0.749 46.70 1.669 26.75 17.93 andradite 0.1790E-01 -1.747 9.095 0.959 5.209 2.363 grossular 0.4249E-02 -2.372 1.914 0.282 1.096 0.5326 apatite-OH 0.3156E-03 -3.501 0.1585 -0.800 0.9079E-01 0.5037E-01 clinochlore 0.2412E-01 -1.618 13.41 1.127 7.680 5.101 daphnite 0.6902E-02 -2.161 4.925 0.692 2.821 1.492 chlorite-Mn 0.5548E-03 -3.256 0.3934 -0.405 0.2253 0.1254 microcline 0.2965E-01 -1.528 8.254 0.917 4.727 3.224 stilbite 0.1125 -0.949 79.29 1.899 45.41 36.98 stilpnomelane-Fe 0.8316E-02 -2.080 8.965 0.953 5.135 3.097 tr.625ac.25prg.125 0.1754E-02 -2.756 1.499 0.176 0.8587 0.4825 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8081E+00 0.8081E+00 1.0000 -0.093 grossular 0.1919E+00 0.1919E+00 1.0000 -0.717 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7639E+00 0.7639E+00 1.0000 -0.117 daphnite 0.2185E+00 0.2185E+00 1.0000 -0.660 chlorite-Mn 0.1757E-01 0.1757E-01 1.0000 -1.755 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 174.598344 g Volume = 71.374785 cm3 Porosity: -9.8080% V(tot) - V(min): -.63752E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 159.9990000 g log = 2.2041 Original solution: 1000.0103000 g Original solution / Rock added: 6.25 (Water/Rock Ratio), log = 0.7959 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0864 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9687E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4024E-08 1.0072 0.4403E-08 0.4372E-08 CH4,gas 0.1777E-01 1.0128 0.1955E-01 0.1930E-01 H2,gas 0.1354E-01 1.0006 0.1472E-01 0.1472E-01 H2S,gas 0.1329E-06 0.9958 0.1438E-06 0.1444E-06 S2,gas 0.3288E-29 1.0000 0.3572E-29 0.3572E-29 CO,gas 0.1546E-13 1.0000 0.1679E-13 0.1679E-13 SO3,gas 0.8550E-48 1.0000 0.9289E-48 0.9289E-48 SO2,gas 0.4763E-27 1.0000 0.5174E-27 0.5174E-27 HCl,gas 0.2701E-17 1.0000 0.2935E-17 0.2935E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.37914E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.72 -10.36 -3.452 0.17683E+05 -8.356 3 CH4,gas 4.81 1.10 -3.71 -0.927 0.63328E+04 -1.709 4 H2,gas 8.29 4.45 -3.83 -2.190 0.65430E+04 -1.832 5 H2S,gas -5.94 -14.78 -8.84 -4.421 0.15098E+05 -6.842 6 S2,gas -7.03 -38.48 -31.45 -4.838 0.53695E+05 -29.447 7 CO,gas 3.51 -12.26 -15.77 -4.854 0.26935E+05 -13.775 8 SO3,gas 17.43 -32.60 -50.03 -12.508 0.85428E+05 -48.032 9 SO2,gas 1.14 -28.15 -29.29 -7.810 0.50005E+05 -27.286 10 HCl,gas 5.48 -14.05 -19.53 -9.766 0.33351E+05 -17.532 11 acmite 7.74 6.57 -1.16 -0.121 0.19875E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.76 -4.79 -0.240 0.81836E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94166E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41209E+04 27 phlogopite 27.15 25.49 -1.66 -0.092 0.28360E+04 29 anorthite 12.80 8.33 -4.47 -0.344 0.76256E+04 35 aragonite 0.99 -3.61 -4.60 -1.534 0.78555E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55848E+04 37 calcite 0.83 -3.61 -4.45 -1.483 0.75942E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.443 0.52896E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71165E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70312E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82192E+04 42 celadonite 5.40 3.73 -1.67 -0.098 0.28583E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47360E+04 44 chrysotile 23.94 21.62 -2.31 -0.193 0.39526E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.167 0.68586E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70381E+04 52 chloritoid-Mn 11.46 7.60 -3.86 -0.258 0.65961E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13287E+04 61 cristobalite -2.55 -3.15 -0.60 -0.199 0.10216E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.81 -4.70 -1.344 0.80290E+04 67 diopside 16.22 16.12 -0.10 -0.010 0.17015E+03 68 hedenbergite 14.24 13.55 -0.69 -0.069 0.11813E+04 71 enstatite 17.30 12.32 -4.98 -0.498 0.85107E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83415E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66099E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.175 0.57683E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63882E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68258E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.97 -2.14 -0.058 0.36622E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70711E+04 86 graphite -3.55 -7.81 -4.26 -1.217 0.72752E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38615E+04 90 hematite 12.60 9.03 -3.57 -0.432 0.60913E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24447E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64150E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59765E+04 101 laumontite 2.97 2.04 -0.94 -0.063 0.16014E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22995E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58941E+04 105 lizardite 23.29 21.62 -1.66 -0.139 0.28429E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74447E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48203E+04 112 manganosite 14.07 9.23 -4.84 -1.210 0.82675E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53672E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41175E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83608E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36579E+04 136 prehnite 19.47 18.29 -1.18 -0.069 0.20100E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92772E+03 138 pumpellyite-Fe 46.47 44.08 -2.39 -0.053 0.40789E+04 139 pumpellyite-Mg 49.19 46.64 -2.55 -0.057 0.43524E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64863E+04 144 pyrrhotiteFe0.875 -6.00 -9.44 -3.44 -1.264 0.58679E+04 145 pyroxmangite 7.42 6.08 -1.34 -0.268 0.22838E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84867E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28260E+03 152 rhodonite 7.46 6.08 -1.38 -0.277 0.23631E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 26.00 -1.60 -0.048 0.27330E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20933E+04 174 tephroite 18.11 15.30 -2.81 -0.401 0.47953E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.90989E+03 179 tremolite 48.00 47.56 -0.44 -0.012 0.75829E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65801E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62295E+04 183 vesuvianite 224.06 219.32 -4.74 -0.036 0.80849E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34522E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26813E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89524E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18139E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66824E+04 192 akaganeite 7.77 4.52 -3.25 -0.703 0.55538E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60291E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66116E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.246 0.68727E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73616E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60296E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57839E+04 206 nontronite-H 2.60 -2.27 -4.87 -0.326 0.83083E+04 207 nontronite-K 3.40 -0.21 -3.61 -0.232 0.61664E+04 208 nontronite-Mg 3.14 -0.73 -3.87 -0.251 0.66145E+04 209 nontronite-Na 3.58 0.49 -3.10 -0.199 0.52869E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35345E+04 230 alabandite -0.96 -5.56 -4.60 -1.532 0.78485E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52619E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18231E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11535E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14898E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18344E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 159.9990000 g New total amount of reactant added: 163.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7229E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 163.9990000 Water: Moles liquid = 0.5451E+02 kg liquid = 0.9819E+00 Moles total = 0.5345E+02 kg total = 0.9630E+00 Activity = 1.0000 Stoichiometric ionic strength = .1172836E-01 Osmotic coef. = 0.9690 True ionic strength = .2068244E-01 Chg. balance for total moles = -.7229E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90252E-10 -10.0445 0.75719E-10 -10.1208 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13986E-03 -3.8543 0.11662E-03 -3.9332 0.83382E+00 -0.0789 4 SO4-- 0.79490E-12 -12.0997 0.41014E-12 -12.3871 0.51597E+00 -0.2874 5 HCO3- 0.28684E-06 -6.5424 0.23953E-06 -6.6206 0.83506E+00 -0.0783 6 HS- 0.25969E-04 -4.5855 0.21657E-04 -4.6644 0.83395E+00 -0.0789 7 Al+++ 0.11016E-28 -28.9580 0.25076E-29 -29.6007 0.22764E+00 -0.6428 8 H4SiO4 0.71123E-03 -3.1480 0.71123E-03 -3.1480 0.10000E+01 0.0000 9 Ca++ 0.14316E-06 -6.8442 0.73314E-07 -7.1348 0.51210E+00 -0.2906 10 Mg++ 0.22737E-10 -10.6433 0.11589E-10 -10.9360 0.50971E+00 -0.2927 11 Fe++ 0.62165E-13 -13.2065 0.31721E-13 -13.4986 0.51028E+00 -0.2922 12 K+ 0.16140E-03 -3.7921 0.13481E-03 -3.8703 0.83526E+00 -0.0782 13 Na+ 0.20520E-01 -1.6878 0.17107E-01 -1.7668 0.83367E+00 -0.0790 14 Mn++ 0.18927E-10 -10.7229 0.96661E-11 -11.0148 0.51071E+00 -0.2918 15 HPO4-- 0.48755E-07 -7.3120 0.25160E-07 -7.5993 0.51604E+00 -0.2873 16 HSiO3- 0.10991E-01 -1.9590 0.91645E-02 -2.0379 0.83382E+00 -0.0789 17 Ca(HSiO3)+ 0.18019E-07 -7.7443 0.15054E-07 -7.8224 0.83545E+00 -0.0781 18 Mg(HSiO3)+ 0.35448E-11 -11.4504 0.29615E-11 -11.5285 0.83545E+00 -0.0781 19 NaHSiO3,aq 0.24900E-02 -2.6038 0.24900E-02 -2.6038 0.10000E+01 0.0000 20 AlO+ 0.67583E-16 -16.1702 0.56462E-16 -16.2482 0.83545E+00 -0.0781 22 HAlO2,aq 0.14922E-09 -9.8262 0.14922E-09 -9.8262 0.10000E+01 0.0000 23 AlO2- 0.52870E-05 -5.2768 0.44003E-05 -5.3565 0.83229E+00 -0.0797 24 CH4,aq 0.12455E-04 -4.9046 0.12411E-04 -4.9062 0.99643E+00 -0.0016 25 C2H6,aq 0.24496E-14 -14.6109 0.24409E-14 -14.6125 0.99643E+00 -0.0016 29 CO,aq 0.10249E-16 -16.9893 0.10249E-16 -16.9893 0.10000E+01 0.0000 30 CO2,aq 0.36699E-10 -10.4353 0.36568E-10 -10.4369 0.99643E+00 -0.0016 31 CO3-2 0.56810E-06 -6.2456 0.29249E-06 -6.5339 0.51485E+00 -0.2883 32 CaCO3,aq 0.26263E-09 -9.5807 0.26263E-09 -9.5807 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.52964E-12 -12.2760 0.44248E-12 -12.3541 0.83545E+00 -0.0781 34 CaCl+ 0.16308E-10 -10.7876 0.13624E-10 -10.8657 0.83545E+00 -0.0781 35 CaCl2,aq 0.36994E-15 -15.4319 0.36994E-15 -15.4319 0.10000E+01 0.0000 36 CaOH+ 0.81721E-07 -7.0877 0.68273E-07 -7.1657 0.83545E+00 -0.0781 37 CaSO4,aq 0.93689E-17 -17.0283 0.93689E-17 -17.0283 0.10000E+01 0.0000 38 HCl,aq 0.16610E-14 -14.7796 0.16610E-14 -14.7796 0.10000E+01 0.0000 43 FeCl+ 0.68966E-17 -17.1614 0.57617E-17 -17.2394 0.83545E+00 -0.0781 46 FeO,aq 0.21879E-09 -9.6600 0.21879E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16624E-10 -10.7793 0.13889E-10 -10.8573 0.83545E+00 -0.0781 48 HFeO2- 0.37273E-07 -7.4286 0.31079E-07 -7.5075 0.83382E+00 -0.0789 49 FeO+ 0.12263E-16 -16.9114 0.10245E-16 -16.9895 0.83545E+00 -0.0781 51 FeO2- 0.42121E-09 -9.3755 0.35122E-09 -9.4544 0.83382E+00 -0.0789 52 HFeO2,aq 0.33282E-11 -11.4778 0.33282E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10921E-04 -4.9617 0.10882E-04 -4.9633 0.99643E+00 -0.0016 54 KCl,aq 0.27838E-09 -9.5554 0.27838E-09 -9.5554 0.10000E+01 0.0000 56 KOH,aq 0.77618E-06 -6.1100 0.77618E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10216E-14 -14.9907 0.85186E-15 -15.0696 0.83382E+00 -0.0789 58 MgCO3,aq 0.10374E-13 -13.9841 0.10374E-13 -13.9841 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.85373E-16 -16.0687 0.71325E-16 -16.1468 0.83545E+00 -0.0781 60 MgCl+ 0.23402E-14 -14.6308 0.19551E-14 -14.7088 0.83545E+00 -0.0781 61 MgOH+ 0.71566E-10 -10.1453 0.59790E-10 -10.2234 0.83545E+00 -0.0781 63 MnO,aq 0.17797E-08 -8.7496 0.17797E-08 -8.7496 0.10000E+01 0.0000 64 MnOH+ 0.47059E-09 -9.3274 0.39315E-09 -9.4054 0.83545E+00 -0.0781 65 MnO2-2 0.20851E-10 -10.6809 0.10735E-10 -10.9692 0.51485E+00 -0.2883 66 HMnO2- 0.21122E-09 -9.6753 0.17612E-09 -9.7542 0.83382E+00 -0.0789 69 MnCl+ 0.81661E-14 -14.0880 0.68224E-14 -14.1661 0.83545E+00 -0.0781 71 NaCl,aq 0.65141E-06 -6.1861 0.65141E-06 -6.1861 0.10000E+01 0.0000 72 NaOH,aq 0.99272E-04 -4.0032 0.99272E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95181E-02 -2.0215 0.79218E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16797E-14 -14.7748 0.86480E-15 -15.0631 0.51485E+00 -0.2883 81 H2PO3- 0.15426E-18 -18.8117 0.12863E-18 -18.8907 0.83382E+00 -0.0789 82 H3PO4,aq 0.92867E-18 -18.0321 0.92867E-18 -18.0321 0.10000E+01 0.0000 83 H2PO4- 0.40017E-10 -10.3978 0.33400E-10 -10.4763 0.83463E+00 -0.0785 84 PO4-3 0.12125E-08 -8.9163 0.29018E-09 -9.5373 0.23933E+00 -0.6210 88 HP2O7-3 0.10376E-17 -17.9840 0.23643E-18 -18.6263 0.22788E+00 -0.6423 89 P2O7-4 0.10250E-16 -16.9893 0.77032E-18 -18.1133 0.75153E-01 -1.1241 90 H2S,aq 0.49446E-08 -8.3059 0.49269E-08 -8.3074 0.99643E+00 -0.0016 91 S2-2 0.18411E-14 -14.7349 0.94787E-15 -15.0233 0.51485E+00 -0.2883 97 SO3-2 0.11649E-17 -17.9337 0.60858E-18 -18.2157 0.52245E+00 -0.2820 99 HSO4- 0.34457E-19 -19.4627 0.28815E-19 -19.5404 0.83628E+00 -0.0776 Charge balance for all species = -.7416E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9025212E-10 -.2312367E-01 -.2326509E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981191E+06 0.0000 3 Cl- 0.1398608E-03 0.1405125E-03 0.4972573E+01 6.1876 4 SO4-- 0.7949021E-12 -.1518553E-04 -.1456106E+01 7.8545 5 HCO3- 0.2868387E-06 0.1331045E-04 0.8106964E+00 3.5002 6 HS- 0.2596873E-04 0.4115920E-04 0.1358753E+01 5.4564 7 Al+++ 0.1101574E-28 0.5287110E-05 0.1423960E+00 0.7616 8 H4SiO4 0.7112323E-03 0.1419213E-01 0.1361613E+04 -3.1480 9 Ca++ 0.1431647E-06 0.2431837E-06 0.9728677E-02 13.1068 10 Mg++ 0.2273664E-10 0.9786024E-10 0.2374872E-05 9.3056 11 Fe++ 0.6216481E-13 0.3793313E-07 0.2114618E-02 6.7429 12 K+ 0.1614023E-03 0.1621787E-03 0.6330036E+01 6.2505 13 Na+ 0.2051989E-01 0.2310977E-01 0.5303275E+03 8.3540 14 Mn++ 0.1892670E-10 0.2501317E-08 0.1371687E-03 9.2268 15 HPO4-- 0.4875490E-07 0.5000737E-07 0.4790971E-02 12.6423 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2715567E+01 -.2270595E-01 -.2692861E+01 0.0000000E+00 2 H2O 0.5345246E+02 0.5450176E+02 -.1049304E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4570476E-02 -.1491121E-04 0.4585387E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4544971E-02 0.4041568E-04 -.4585387E-02 0.0000000E+00 7 Al+++ 0.5347584E+00 0.5191601E-05 0.5347532E+00 0.0000000E+00 8 H4SiO4 0.1707686E+01 0.1393575E-01 0.1693750E+01 0.0000000E+00 9 Ca++ 0.1886367E+00 0.2387907E-06 0.1886365E+00 0.0000000E+00 10 Mg++ 0.1301579E+00 0.9609244E-10 0.1301579E+00 0.0000000E+00 11 Fe++ 0.1169327E+00 0.3724789E-07 0.1169327E+00 0.0000000E+00 12 K+ 0.3481932E-01 0.1592491E-03 0.3466007E-01 0.0000000E+00 13 Na+ 0.2060188E+00 0.2269230E-01 0.1833265E+00 0.0000000E+00 14 Mn++ 0.2843512E-02 0.2456132E-08 0.2843510E-02 0.0000000E+00 15 HPO4-- 0.9704766E-03 0.4910401E-07 0.9704275E-03 0.0000000E+00 Chg. balance for solid moles: 0.3205E-15 Mass of aqueous solution: 0.983716E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 163.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1831 -0.737 48.01 1.681 26.83 18.43 andradite 0.1834E-01 -1.737 9.321 0.969 5.208 2.422 grossular 0.4389E-02 -2.358 1.977 0.296 1.105 0.5500 apatite-OH 0.3235E-03 -3.490 0.1625 -0.789 0.9079E-01 0.5163E-01 clinochlore 0.2467E-01 -1.608 13.71 1.137 7.662 5.216 daphnite 0.7067E-02 -2.151 5.042 0.703 2.817 1.528 chlorite-Mn 0.5687E-03 -3.245 0.4032 -0.394 0.2253 0.1285 microcline 0.3040E-01 -1.517 8.462 0.927 4.729 3.306 stilbite 0.1151 -0.939 81.09 1.909 45.31 37.82 stilpnomelane-Fe 0.8513E-02 -2.070 9.177 0.963 5.128 3.170 tr.625ac.25prg.125 0.1879E-02 -2.726 1.606 0.206 0.8975 0.5170 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8069E+00 0.8069E+00 1.0000 -0.093 grossular 0.1931E+00 0.1931E+00 1.0000 -0.714 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7636E+00 0.7636E+00 1.0000 -0.117 daphnite 0.2188E+00 0.2188E+00 1.0000 -0.660 chlorite-Mn 0.1760E-01 0.1760E-01 1.0000 -1.754 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 178.965891 g Volume = 73.140915 cm3 Porosity: -9.8219% V(tot) - V(min): -.65413E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 163.9990000 g log = 2.2148 Original solution: 1000.0103000 g Original solution / Rock added: 6.10 (Water/Rock Ratio), log = 0.7852 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0867 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9684E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3824E-08 1.0072 0.4186E-08 0.4156E-08 CH4,gas 0.1783E-01 1.0128 0.1963E-01 0.1938E-01 H2,gas 0.1373E-01 1.0006 0.1493E-01 0.1492E-01 H2S,gas 0.1328E-06 0.9958 0.1437E-06 0.1443E-06 S2,gas 0.3194E-29 1.0000 0.3471E-29 0.3471E-29 CO,gas 0.1489E-13 1.0000 0.1618E-13 0.1618E-13 SO3,gas 0.8090E-48 1.0000 0.8791E-48 0.8791E-48 SO2,gas 0.4568E-27 1.0000 0.4964E-27 0.4964E-27 HCl,gas 0.2699E-17 1.0000 0.2933E-17 0.2933E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.74 -10.38 -3.459 0.17721E+05 -8.378 3 CH4,gas 4.81 1.10 -3.71 -0.927 0.63299E+04 -1.707 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65329E+04 -1.826 5 H2S,gas -5.94 -14.79 -8.84 -4.421 0.15098E+05 -6.843 6 S2,gas -7.03 -38.49 -31.46 -4.840 0.53716E+05 -29.459 7 CO,gas 3.51 -12.28 -15.79 -4.859 0.26963E+05 -13.791 8 SO3,gas 17.43 -32.63 -50.06 -12.514 0.85469E+05 -48.056 9 SO2,gas 1.14 -28.17 -29.30 -7.814 0.50036E+05 -27.304 10 HCl,gas 5.48 -14.05 -19.53 -9.766 0.33352E+05 -17.533 11 acmite 7.74 6.57 -1.17 -0.121 0.19924E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.76 -4.79 -0.240 0.81789E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94084E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41189E+04 27 phlogopite 27.15 25.49 -1.66 -0.092 0.28369E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76215E+04 35 aragonite 0.99 -3.63 -4.62 -1.540 0.78900E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55851E+04 37 calcite 0.83 -3.63 -4.47 -1.489 0.76287E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52879E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71148E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.274 0.70304E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82175E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28594E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47362E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39552E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.167 0.68637E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70355E+04 52 chloritoid-Mn 11.46 7.60 -3.86 -0.257 0.65927E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13295E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10224E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36445E+04 66 diamond -3.11 -7.82 -4.71 -1.346 0.80463E+04 67 diopside 16.22 16.12 -0.10 -0.010 0.16909E+03 68 hedenbergite 14.24 13.55 -0.69 -0.069 0.11793E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85129E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83437E+04 75 epidote 24.78 22.81 -1.97 -0.096 0.33634E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66022E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57721E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63878E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68261E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56957E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36648E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70707E+04 86 graphite -3.55 -7.82 -4.27 -1.220 0.72925E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38612E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.61001E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24439E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64134E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59754E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15989E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22953E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58932E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28455E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74528E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48216E+04 112 manganosite 14.07 9.23 -4.84 -1.210 0.82661E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61259E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53644E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41159E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83601E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36588E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20036E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92718E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40642E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.056 0.43387E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64862E+04 144 pyrrhotiteFe0.875 -6.00 -9.44 -3.44 -1.264 0.58691E+04 145 pyroxmangite 7.42 6.08 -1.34 -0.267 0.22832E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84872E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28342E+03 152 rhodonite 7.46 6.08 -1.38 -0.277 0.23624E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27378E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20975E+04 174 tephroite 18.11 15.31 -2.81 -0.401 0.47932E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91071E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76039E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65774E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62294E+04 183 vesuvianite 224.06 219.35 -4.70 -0.036 0.80279E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34498E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26792E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89305E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18117E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66747E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55582E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60374E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66122E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68734E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73628E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60303E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57948E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83196E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61774E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66260E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52979E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.56 -4.60 -1.532 0.78475E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62629E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52612E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18239E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11527E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14888E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18332E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 163.9990000 g New total amount of reactant added: 167.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7164E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 167.9990000 Water: Moles liquid = 0.5448E+02 kg liquid = 0.9815E+00 Moles total = 0.5340E+02 kg total = 0.9621E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173342E-01 Osmotic coef. = 0.9690 True ionic strength = .2069158E-01 Chg. balance for total moles = -.7164E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90166E-10 -10.0450 0.75645E-10 -10.1212 0.83895E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13992E-03 -3.8541 0.11666E-03 -3.9331 0.83380E+00 -0.0789 4 SO4-- 0.75598E-12 -12.1215 0.39002E-12 -12.4089 0.51591E+00 -0.2874 5 HCO3- 0.27364E-06 -6.5628 0.22850E-06 -6.6411 0.83504E+00 -0.0783 6 HS- 0.25979E-04 -4.5854 0.21665E-04 -4.6642 0.83392E+00 -0.0789 7 Al+++ 0.11006E-28 -28.9584 0.25047E-29 -29.6013 0.22758E+00 -0.6429 8 H4SiO4 0.71048E-03 -3.1484 0.71048E-03 -3.1484 0.10000E+01 0.0000 9 Ca++ 0.14345E-06 -6.8433 0.73453E-07 -7.1340 0.51204E+00 -0.2907 10 Mg++ 0.22686E-10 -10.6442 0.11562E-10 -10.9370 0.50965E+00 -0.2927 11 Fe++ 0.62102E-13 -13.2069 0.31686E-13 -13.4991 0.51022E+00 -0.2922 12 K+ 0.16147E-03 -3.7919 0.13487E-03 -3.8701 0.83524E+00 -0.0782 13 Na+ 0.20529E-01 -1.6876 0.17114E-01 -1.7667 0.83364E+00 -0.0790 14 Mn++ 0.18928E-10 -10.7229 0.96654E-11 -11.0148 0.51065E+00 -0.2919 15 HPO4-- 0.48544E-07 -7.3139 0.25048E-07 -7.6012 0.51598E+00 -0.2874 16 HSiO3- 0.10990E-01 -1.9590 0.91638E-02 -2.0379 0.83380E+00 -0.0789 17 Ca(HSiO3)+ 0.18052E-07 -7.7435 0.15081E-07 -7.8216 0.83542E+00 -0.0781 18 Mg(HSiO3)+ 0.35363E-11 -11.4515 0.29543E-11 -11.5295 0.83542E+00 -0.0781 19 NaHSiO3,aq 0.24908E-02 -2.6037 0.24908E-02 -2.6037 0.10000E+01 0.0000 20 AlO+ 0.67639E-16 -16.1698 0.56507E-16 -16.2479 0.83542E+00 -0.0781 22 HAlO2,aq 0.14948E-09 -9.8254 0.14948E-09 -9.8254 0.10000E+01 0.0000 23 AlO2- 0.53017E-05 -5.2756 0.44125E-05 -5.3553 0.83227E+00 -0.0797 24 CH4,aq 0.12499E-04 -4.9031 0.12455E-04 -4.9047 0.99642E+00 -0.0016 25 C2H6,aq 0.24354E-14 -14.6134 0.24267E-14 -14.6150 0.99642E+00 -0.0016 29 CO,aq 0.98946E-17 -17.0046 0.98946E-17 -17.0046 0.10000E+01 0.0000 30 CO2,aq 0.34974E-10 -10.4563 0.34849E-10 -10.4578 0.99642E+00 -0.0016 31 CO3-2 0.54253E-06 -6.2656 0.27929E-06 -6.5539 0.51479E+00 -0.2884 32 CaCO3,aq 0.25125E-09 -9.5999 0.25125E-09 -9.5999 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.50621E-12 -12.2957 0.42290E-12 -12.3738 0.83542E+00 -0.0781 34 CaCl+ 0.16345E-10 -10.7866 0.13655E-10 -10.8647 0.83542E+00 -0.0781 35 CaCl2,aq 0.37091E-15 -15.4307 0.37091E-15 -15.4307 0.10000E+01 0.0000 36 CaOH+ 0.81958E-07 -7.0864 0.68469E-07 -7.1645 0.83542E+00 -0.0781 37 CaSO4,aq 0.89260E-17 -17.0493 0.89260E-17 -17.0493 0.10000E+01 0.0000 38 HCl,aq 0.16599E-14 -14.7799 0.16599E-14 -14.7799 0.10000E+01 0.0000 43 FeCl+ 0.68916E-17 -17.1617 0.57574E-17 -17.2398 0.83542E+00 -0.0781 46 FeO,aq 0.21897E-09 -9.6596 0.21897E-09 -9.6596 0.10000E+01 0.0000 47 FeOH+ 0.16622E-10 -10.7793 0.13887E-10 -10.8574 0.83542E+00 -0.0781 48 HFeO2- 0.37342E-07 -7.4278 0.31136E-07 -7.5067 0.83380E+00 -0.0789 49 FeO+ 0.12183E-16 -16.9142 0.10178E-16 -16.9923 0.83542E+00 -0.0781 51 FeO2- 0.41928E-09 -9.3775 0.34959E-09 -9.4564 0.83380E+00 -0.0789 52 HFeO2,aq 0.33096E-11 -11.4802 0.33096E-11 -11.4802 0.10000E+01 0.0000 53 H2,aq 0.11064E-04 -4.9561 0.11024E-04 -4.9577 0.99642E+00 -0.0016 54 KCl,aq 0.27860E-09 -9.5550 0.27860E-09 -9.5550 0.10000E+01 0.0000 56 KOH,aq 0.77726E-06 -6.1094 0.77726E-06 -6.1094 0.10000E+01 0.0000 57 KSO4- 0.97193E-15 -15.0124 0.81040E-15 -15.0913 0.83380E+00 -0.0789 58 MgCO3,aq 0.98824E-14 -14.0051 0.98824E-14 -14.0051 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.81253E-16 -16.0902 0.67880E-16 -16.1683 0.83542E+00 -0.0781 60 MgCl+ 0.23356E-14 -14.6316 0.19512E-14 -14.7097 0.83542E+00 -0.0781 61 MgOH+ 0.71470E-10 -10.1459 0.59708E-10 -10.2240 0.83542E+00 -0.0781 63 MnO,aq 0.17831E-08 -8.7488 0.17831E-08 -8.7488 0.10000E+01 0.0000 64 MnOH+ 0.47103E-09 -9.3270 0.39351E-09 -9.4050 0.83542E+00 -0.0781 65 MnO2-2 0.20934E-10 -10.6791 0.10777E-10 -10.9675 0.51479E+00 -0.2884 66 HMnO2- 0.21183E-09 -9.6740 0.17662E-09 -9.7530 0.83380E+00 -0.0789 69 MnCl+ 0.81689E-14 -14.0878 0.68245E-14 -14.1659 0.83542E+00 -0.0781 71 NaCl,aq 0.65192E-06 -6.1858 0.65192E-06 -6.1858 0.10000E+01 0.0000 72 NaOH,aq 0.99411E-04 -4.0026 0.99411E-04 -4.0026 0.10000E+01 0.0000 74 OH- 0.95277E-02 -2.0210 0.79296E-02 -2.1007 0.83227E+00 -0.0797 79 HPO3-2 0.16942E-14 -14.7710 0.87216E-15 -15.0594 0.51479E+00 -0.2884 81 H2PO3- 0.15543E-18 -18.8085 0.12959E-18 -18.8874 0.83380E+00 -0.0789 82 H3PO4,aq 0.92273E-18 -18.0349 0.92273E-18 -18.0349 0.10000E+01 0.0000 83 H2PO4- 0.39802E-10 -10.4001 0.33219E-10 -10.4786 0.83460E+00 -0.0785 84 PO4-3 0.12086E-08 -8.9177 0.28918E-09 -9.5388 0.23927E+00 -0.6211 88 HP2O7-3 0.10276E-17 -17.9882 0.23411E-18 -18.6306 0.22782E+00 -0.6424 89 P2O7-4 0.10164E-16 -16.9929 0.76350E-18 -18.1172 0.75118E-01 -1.1243 90 H2S,aq 0.49416E-08 -8.3061 0.49239E-08 -8.3077 0.99642E+00 -0.0016 91 S2-2 0.18190E-14 -14.7402 0.93641E-15 -15.0285 0.51479E+00 -0.2884 97 SO3-2 0.11222E-17 -17.9499 0.58624E-18 -18.2319 0.52239E+00 -0.2820 99 HSO4- 0.32735E-19 -19.4850 0.27374E-19 -19.5627 0.83626E+00 -0.0777 Charge balance for all species = -.7374E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9016602E-10 -.2313387E-01 -.2327534E+02 0.0000 2 H2O 0.1000000E+01 0.5550443E+02 0.9981190E+06 0.0000 3 Cl- 0.1399175E-03 0.1405697E-03 0.4974595E+01 6.1882 4 SO4-- 0.7559835E-12 -.1526523E-04 -.1463748E+01 7.8335 5 HCO3- 0.2736357E-06 0.1331586E-04 0.8110261E+00 3.4801 6 HS- 0.2597930E-04 0.4124948E-04 0.1361733E+01 5.4570 7 Al+++ 0.1100578E-28 0.5301877E-05 0.1427936E+00 0.7624 8 H4SiO4 0.7104808E-03 0.1419172E-01 0.1361574E+04 -3.1484 9 Ca++ 0.1434516E-06 0.2437293E-06 0.9750502E-02 13.1084 10 Mg++ 0.2268602E-10 0.9770496E-10 0.2371103E-05 9.3055 11 Fe++ 0.6210250E-13 0.3800051E-07 0.2118373E-02 6.7433 12 K+ 0.1614737E-03 0.1622512E-03 0.6332863E+01 6.2511 13 Na+ 0.2052898E-01 0.2311984E-01 0.5305585E+03 8.3546 14 Mn++ 0.1892764E-10 0.2505833E-08 0.1374163E-03 9.2277 15 HPO4-- 0.4854412E-07 0.4979248E-07 0.4770382E-02 12.6412 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2781801E+01 -.2270672E-01 -.2759094E+01 0.0000000E+00 2 H2O 0.5340231E+02 0.5447959E+02 -.1077280E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4681329E-02 -.1498338E-04 0.4696313E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4655825E-02 0.4048785E-04 -.4696313E-02 0.0000000E+00 7 Al+++ 0.5478013E+00 0.5203983E-05 0.5477961E+00 0.0000000E+00 8 H4SiO4 0.1749337E+01 0.1392968E-01 0.1735407E+01 0.0000000E+00 9 Ca++ 0.1932373E+00 0.2392291E-06 0.1932370E+00 0.0000000E+00 10 Mg++ 0.1333325E+00 0.9590093E-10 0.1333325E+00 0.0000000E+00 11 Fe++ 0.1197847E+00 0.3729887E-07 0.1197847E+00 0.0000000E+00 12 K+ 0.3566858E-01 0.1592554E-03 0.3550932E-01 0.0000000E+00 13 Na+ 0.2110397E+00 0.2269296E-01 0.1883468E+00 0.0000000E+00 14 Mn++ 0.2912867E-02 0.2459565E-08 0.2912864E-02 0.0000000E+00 15 HPO4-- 0.9941470E-03 0.4887311E-07 0.9940981E-03 0.0000000E+00 Chg. balance for solid moles: 0.4502E-15 Mass of aqueous solution: 0.983316E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 167.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1881 -0.726 49.32 1.693 26.90 18.93 andradite 0.1879E-01 -1.726 9.546 0.980 5.207 2.480 grossular 0.4528E-02 -2.344 2.040 0.310 1.113 0.5675 apatite-OH 0.3314E-03 -3.480 0.1665 -0.779 0.9079E-01 0.5289E-01 clinochlore 0.2521E-01 -1.598 14.01 1.147 7.644 5.331 daphnite 0.7232E-02 -2.141 5.160 0.713 2.814 1.564 chlorite-Mn 0.5826E-03 -3.235 0.4130 -0.384 0.2253 0.1316 microcline 0.3115E-01 -1.506 8.671 0.938 4.730 3.387 stilbite 0.1176 -0.929 82.90 1.919 45.22 38.66 stilpnomelane-Fe 0.8710E-02 -2.060 9.389 0.973 5.122 3.243 tr.625ac.25prg.125 0.2004E-02 -2.698 1.713 0.234 0.9345 0.5514 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8058E+00 0.8058E+00 1.0000 -0.094 grossular 0.1942E+00 0.1942E+00 1.0000 -0.712 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7634E+00 0.7634E+00 1.0000 -0.117 daphnite 0.2190E+00 0.2190E+00 1.0000 -0.660 chlorite-Mn 0.1764E-01 0.1764E-01 1.0000 -1.754 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 183.333411 g Volume = 74.907011 cm3 Porosity: -9.8350% V(tot) - V(min): -.67074E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 167.9990000 g log = 2.2253 Original solution: 1000.0103000 g Original solution / Rock added: 5.95 (Water/Rock Ratio), log = 0.7747 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0870 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9682E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3644E-08 1.0072 0.3989E-08 0.3961E-08 CH4,gas 0.1789E-01 1.0128 0.1970E-01 0.1945E-01 H2,gas 0.1390E-01 1.0006 0.1512E-01 0.1511E-01 H2S,gas 0.1327E-06 0.9958 0.1436E-06 0.1442E-06 S2,gas 0.3108E-29 1.0000 0.3379E-29 0.3379E-29 CO,gas 0.1437E-13 1.0000 0.1562E-13 0.1562E-13 SO3,gas 0.7676E-48 1.0000 0.8343E-48 0.8343E-48 SO2,gas 0.4390E-27 1.0000 0.4772E-27 0.4772E-27 HCl,gas 0.2696E-17 1.0000 0.2931E-17 0.2931E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.36397E-10 67 diopside 16.22 16.12 -0.10 -0.010 0.16809E+03 68 hedenbergite 14.24 13.55 -0.69 -0.069 0.11774E+04 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.76 -10.40 -3.466 0.17756E+05 -8.399 3 CH4,gas 4.81 1.10 -3.71 -0.926 0.63273E+04 -1.706 4 H2,gas 8.29 4.47 -3.82 -2.183 0.65233E+04 -1.820 5 H2S,gas -5.94 -14.79 -8.84 -4.421 0.15099E+05 -6.843 6 S2,gas -7.03 -38.50 -31.47 -4.842 0.53736E+05 -29.471 7 CO,gas 3.51 -12.30 -15.81 -4.863 0.26989E+05 -13.806 8 SO3,gas 17.43 -32.65 -50.08 -12.520 0.85508E+05 -48.079 9 SO2,gas 1.14 -28.18 -29.32 -7.819 0.50065E+05 -27.321 10 HCl,gas 5.48 -14.05 -19.53 -9.766 0.33352E+05 -17.533 11 acmite 7.74 6.57 -1.17 -0.122 0.19971E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.76 -4.79 -0.239 0.81744E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94005E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41171E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28378E+04 29 anorthite 12.80 8.34 -4.46 -0.343 0.76175E+04 35 aragonite 0.99 -3.65 -4.64 -1.547 0.79229E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55854E+04 37 calcite 0.83 -3.65 -4.49 -1.496 0.76615E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52864E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71132E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.274 0.70296E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82158E+04 42 celadonite 5.40 3.73 -1.68 -0.099 0.28605E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47363E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39576E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68685E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70331E+04 52 chloritoid-Mn 11.46 7.60 -3.86 -0.257 0.65894E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13303E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10232E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36432E+04 66 diamond -3.11 -7.83 -4.72 -1.349 0.80629E+04 71 enstatite 17.30 12.31 -4.99 -0.499 0.85151E+04 73 clinoenstatite 17.20 12.31 -4.89 -0.489 0.83459E+04 75 epidote 24.78 22.81 -1.97 -0.095 0.33616E+04 76 clinozoisite 22.92 19.06 -3.86 -0.176 0.65949E+04 77 epidote-Fe 29.94 26.55 -3.38 -0.176 0.57758E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63873E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68264E+04 83 gibbsite 4.10 0.76 -3.33 -0.476 0.56944E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36672E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.83 -4.28 -1.223 0.73090E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.02 -3.58 -0.434 0.61084E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24431E+04 97 kalsilite 7.62 3.87 -3.76 -0.536 0.64118E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59743E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15966E+04 102 lawsonite 9.68 8.34 -1.34 -0.089 0.22914E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58925E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28479E+04 107 magnetite 20.13 15.76 -4.37 -0.357 0.74605E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48229E+04 112 manganosite 14.07 9.23 -4.84 -1.210 0.82647E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61233E+04 121 paragonite 4.34 1.20 -3.14 -0.185 0.53617E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41143E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83595E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36597E+04 136 prehnite 19.47 18.30 -1.17 -0.069 0.19976E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92667E+03 138 pumpellyite-Fe 46.47 44.10 -2.37 -0.053 0.40502E+04 139 pumpellyite-Mg 49.19 46.66 -2.53 -0.056 0.43257E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64860E+04 144 pyrrhotiteFe0.875 -6.00 -9.44 -3.44 -1.264 0.58702E+04 145 pyroxmangite 7.42 6.08 -1.34 -0.267 0.22826E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84877E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28421E+03 152 rhodonite 7.46 6.08 -1.38 -0.277 0.23618E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.61 -0.048 0.27424E+04 171 talc 16.55 15.32 -1.23 -0.072 0.21015E+04 174 tephroite 18.11 15.31 -2.81 -0.401 0.47912E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91150E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76238E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65748E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62292E+04 183 vesuvianite 224.06 219.39 -4.67 -0.036 0.79739E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34474E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26771E+04 189 wollastonite 10.48 9.96 -0.52 -0.104 0.89099E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18096E+04 191 zoisite 22.96 19.06 -3.90 -0.177 0.66674E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55624E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60452E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73639E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.12 -3.40 -0.221 0.58051E+04 206 nontronite-H 2.60 -2.28 -4.88 -0.327 0.83304E+04 207 nontronite-K 3.40 -0.22 -3.62 -0.233 0.61879E+04 208 nontronite-Mg 3.14 -0.75 -3.89 -0.252 0.66368E+04 209 nontronite-Na 3.58 0.47 -3.11 -0.200 0.53083E+04 224 tobermorite 9.84 7.77 -2.07 -0.564 0.35312E+04 230 alabandite -0.96 -5.56 -4.60 -1.532 0.78465E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62616E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52606E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18247E+04 242 an20ab80 2.08 1.40 -0.67 -0.052 0.11519E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14878E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18320E+04 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 167.9990000 Water: Moles liquid = 0.5448E+02 kg liquid = 0.9815E+00 Moles total = 0.5340E+02 kg total = 0.9621E+00 Activity = 1.0000 Stoichiometric ionic strength = .1172859E-01 Osmotic coef. = 0.9690 True ionic strength = .2068278E-01 Chg. balance for total moles = -.7164E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90251E-10 -10.0445 0.75718E-10 -10.1208 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13992E-03 -3.8541 0.11667E-03 -3.9331 0.83382E+00 -0.0789 4 SO4-- 0.79439E-12 -12.1000 0.40988E-12 -12.3873 0.51596E+00 -0.2874 5 HCO3- 0.28667E-06 -6.5426 0.23939E-06 -6.6209 0.83506E+00 -0.0783 6 HS- 0.25979E-04 -4.5854 0.21665E-04 -4.6642 0.83395E+00 -0.0789 7 Al+++ 0.11015E-28 -28.9580 0.25075E-29 -29.6008 0.22763E+00 -0.6428 8 H4SiO4 0.71122E-03 -3.1480 0.71122E-03 -3.1480 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73317E-07 -7.1348 0.51210E+00 -0.2906 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50971E+00 -0.2927 11 Fe++ 0.62164E-13 -13.2065 0.31721E-13 -13.4987 0.51028E+00 -0.2922 12 K+ 0.16140E-03 -3.7921 0.13482E-03 -3.8703 0.83526E+00 -0.0782 13 Na+ 0.20520E-01 -1.6878 0.17107E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.18951E-10 -10.7224 0.96783E-11 -11.0142 0.51071E+00 -0.2918 15 HPO4-- 0.48751E-07 -7.3120 0.25157E-07 -7.5993 0.51604E+00 -0.2873 16 HSiO3- 0.10991E-01 -1.9590 0.91645E-02 -2.0379 0.83382E+00 -0.0789 17 Ca(HSiO3)+ 0.18020E-07 -7.7443 0.15055E-07 -7.8223 0.83545E+00 -0.0781 18 Mg(HSiO3)+ 0.35446E-11 -11.4504 0.29613E-11 -11.5285 0.83545E+00 -0.0781 19 NaHSiO3,aq 0.24900E-02 -2.6038 0.24900E-02 -2.6038 0.10000E+01 0.0000 20 AlO+ 0.67582E-16 -16.1702 0.56461E-16 -16.2482 0.83545E+00 -0.0781 22 HAlO2,aq 0.14922E-09 -9.8262 0.14922E-09 -9.8262 0.10000E+01 0.0000 23 AlO2- 0.52871E-05 -5.2768 0.44004E-05 -5.3565 0.83229E+00 -0.0797 24 CH4,aq 0.12461E-04 -4.9044 0.12417E-04 -4.9060 0.99643E+00 -0.0016 25 C2H6,aq 0.24513E-14 -14.6106 0.24425E-14 -14.6122 0.99643E+00 -0.0016 29 CO,aq 0.10246E-16 -16.9895 0.10246E-16 -16.9895 0.10000E+01 0.0000 30 CO2,aq 0.36677E-10 -10.4356 0.36546E-10 -10.4372 0.99643E+00 -0.0016 31 CO3-2 0.56778E-06 -6.2458 0.29232E-06 -6.5341 0.51485E+00 -0.2883 32 CaCO3,aq 0.26249E-09 -9.5809 0.26249E-09 -9.5809 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.52935E-12 -12.2763 0.44225E-12 -12.3543 0.83545E+00 -0.0781 34 CaCl+ 0.16315E-10 -10.7874 0.13630E-10 -10.8655 0.83545E+00 -0.0781 35 CaCl2,aq 0.37026E-15 -15.4315 0.37026E-15 -15.4315 0.10000E+01 0.0000 36 CaOH+ 0.81725E-07 -7.0876 0.68277E-07 -7.1657 0.83545E+00 -0.0781 37 CaSO4,aq 0.93633E-17 -17.0286 0.93633E-17 -17.0286 0.10000E+01 0.0000 38 HCl,aq 0.16616E-14 -14.7795 0.16616E-14 -14.7795 0.10000E+01 0.0000 43 FeCl+ 0.68993E-17 -17.1612 0.57640E-17 -17.2393 0.83545E+00 -0.0781 46 FeO,aq 0.21879E-09 -9.6600 0.21879E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16624E-10 -10.7793 0.13889E-10 -10.8573 0.83545E+00 -0.0781 48 HFeO2- 0.37274E-07 -7.4286 0.31080E-07 -7.5075 0.83382E+00 -0.0789 49 FeO+ 0.12262E-16 -16.9114 0.10244E-16 -16.9895 0.83545E+00 -0.0781 51 FeO2- 0.42117E-09 -9.3755 0.35118E-09 -9.4545 0.83382E+00 -0.0789 52 HFeO2,aq 0.33278E-11 -11.4778 0.33278E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10924E-04 -4.9616 0.10885E-04 -4.9632 0.99643E+00 -0.0016 54 KCl,aq 0.27850E-09 -9.5552 0.27850E-09 -9.5552 0.10000E+01 0.0000 56 KOH,aq 0.77621E-06 -6.1100 0.77621E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10210E-14 -14.9910 0.85133E-15 -15.0699 0.83382E+00 -0.0789 58 MgCO3,aq 0.10367E-13 -13.9843 0.10367E-13 -13.9843 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.85319E-16 -16.0690 0.71280E-16 -16.1470 0.83545E+00 -0.0781 60 MgCl+ 0.23410E-14 -14.6306 0.19558E-14 -14.7087 0.83545E+00 -0.0781 61 MgOH+ 0.71563E-10 -10.1453 0.59787E-10 -10.2234 0.83545E+00 -0.0781 63 MnO,aq 0.17820E-08 -8.7491 0.17820E-08 -8.7491 0.10000E+01 0.0000 64 MnOH+ 0.47119E-09 -9.3268 0.39365E-09 -9.4049 0.83545E+00 -0.0781 65 MnO2-2 0.20879E-10 -10.6803 0.10750E-10 -10.9686 0.51485E+00 -0.2883 66 HMnO2- 0.21149E-09 -9.6747 0.17635E-09 -9.7536 0.83382E+00 -0.0789 69 MnCl+ 0.81798E-14 -14.0873 0.68338E-14 -14.1653 0.83545E+00 -0.0781 71 NaCl,aq 0.65168E-06 -6.1860 0.65168E-06 -6.1860 0.10000E+01 0.0000 72 NaOH,aq 0.99276E-04 -4.0032 0.99276E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95183E-02 -2.0214 0.79220E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16800E-14 -14.7747 0.86495E-15 -15.0630 0.51485E+00 -0.2883 81 H2PO3- 0.15429E-18 -18.8117 0.12865E-18 -18.8906 0.83382E+00 -0.0789 82 H3PO4,aq 0.92855E-18 -18.0322 0.92855E-18 -18.0322 0.10000E+01 0.0000 83 H2PO4- 0.40013E-10 -10.3978 0.33396E-10 -10.4763 0.83463E+00 -0.0785 84 PO4-3 0.12124E-08 -8.9164 0.29016E-09 -9.5374 0.23933E+00 -0.6210 88 HP2O7-3 0.10374E-17 -17.9841 0.23639E-18 -18.6264 0.22788E+00 -0.6423 89 P2O7-4 0.10248E-16 -16.9893 0.77018E-18 -18.1134 0.75152E-01 -1.1241 90 H2S,aq 0.49465E-08 -8.3057 0.49289E-08 -8.3073 0.99643E+00 -0.0016 91 S2-2 0.18421E-14 -14.7347 0.94839E-15 -15.0230 0.51485E+00 -0.2883 97 SO3-2 0.11644E-17 -17.9339 0.60835E-18 -18.2158 0.52245E+00 -0.2820 99 HSO4- 0.34434E-19 -19.4630 0.28796E-19 -19.5407 0.83628E+00 -0.0776 Charge balance for all species = -.7387E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9025065E-10 -.2312399E-01 -.2326541E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981191E+06 0.0000 3 Cl- 0.1399180E-03 0.1405700E-03 0.4974609E+01 6.1877 4 SO4-- 0.7943947E-12 -.1519218E-04 -.1456744E+01 7.8543 5 HCO3- 0.2866740E-06 0.1331590E-04 0.8110282E+00 3.4999 6 HS- 0.2597936E-04 0.4117649E-04 0.1359324E+01 5.4566 7 Al+++ 0.1101526E-28 0.5287200E-05 0.1423984E+00 0.7616 8 H4SiO4 0.7112250E-03 0.1419226E-01 0.1361626E+04 -3.1480 9 Ca++ 0.1431711E-06 0.2431956E-06 0.9729153E-02 13.1068 10 Mg++ 0.2273538E-10 0.9785585E-10 0.2374766E-05 9.3056 11 Fe++ 0.6216379E-13 0.3793429E-07 0.2114682E-02 6.7429 12 K+ 0.1614049E-03 0.1621813E-03 0.6330138E+01 6.2505 13 Na+ 0.2052022E-01 0.2311016E-01 0.5303364E+03 8.3540 14 Mn++ 0.1895067E-10 0.2504557E-08 0.1373463E-03 9.2274 15 HPO4-- 0.4875071E-07 0.5000310E-07 0.4790562E-02 12.6423 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2781801E+01 -.2269697E-01 -.2759104E+01 0.0000000E+00 2 H2O 0.5340231E+02 0.5447946E+02 -.1077143E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4681329E-02 -.1491164E-04 0.4696241E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4655825E-02 0.4041611E-04 -.4696241E-02 0.0000000E+00 7 Al+++ 0.5478013E+00 0.5189565E-05 0.5477961E+00 0.0000000E+00 8 H4SiO4 0.1749337E+01 0.1393018E-01 0.1735407E+01 0.0000000E+00 9 Ca++ 0.1932373E+00 0.2387047E-06 0.1932370E+00 0.0000000E+00 10 Mg++ 0.1333325E+00 0.9604881E-10 0.1333325E+00 0.0000000E+00 11 Fe++ 0.1197847E+00 0.3723378E-07 0.1197847E+00 0.0000000E+00 12 K+ 0.3566858E-01 0.1591864E-03 0.3550939E-01 0.0000000E+00 13 Na+ 0.2110397E+00 0.2268340E-01 0.1883563E+00 0.0000000E+00 14 Mn++ 0.2912867E-02 0.2458307E-08 0.2912864E-02 0.0000000E+00 15 HPO4-- 0.9941470E-03 0.4907972E-07 0.9940979E-03 0.0000000E+00 Chg. balance for solid moles: 0.3430E-15 Mass of aqueous solution: 0.983313E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 167.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1881 -0.726 49.33 1.693 26.91 18.94 andradite 0.1878E-01 -1.726 9.546 0.980 5.207 2.480 grossular 0.4495E-02 -2.347 2.025 0.306 1.104 0.5634 apatite-OH 0.3314E-03 -3.480 0.1665 -0.779 0.9079E-01 0.5289E-01 clinochlore 0.2524E-01 -1.598 14.03 1.147 7.651 5.336 daphnite 0.7230E-02 -2.141 5.159 0.713 2.814 1.563 chlorite-Mn 0.5826E-03 -3.235 0.4130 -0.384 0.2253 0.1316 microcline 0.3115E-01 -1.507 8.670 0.938 4.729 3.387 stilbite 0.1176 -0.929 82.90 1.919 45.22 38.67 stilpnomelane-Fe 0.8724E-02 -2.059 9.405 0.973 5.130 3.249 tr.625ac.25prg.125 0.1909E-02 -2.719 1.631 0.213 0.8899 0.5251 diopside 0.2261E-03 -3.646 0.4897E-01 -1.310 0.2671E-01 0.1497E-01 hedenbergite 0.5790E-04 -4.237 0.1437E-01 -1.843 0.7836E-02 0.3935E-02 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8069E+00 0.8069E+00 1.0000 -0.093 grossular 0.1931E+00 0.1931E+00 1.0000 -0.714 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7636E+00 0.7636E+00 1.0000 -0.117 daphnite 0.2188E+00 0.2188E+00 1.0000 -0.660 chlorite-Mn 0.1763E-01 0.1763E-01 1.0000 -1.754 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 Solid products produced: Mass = 183.336041 g Volume = 74.909120 cm3 Porosity: -9.8381% V(tot) - V(min): -.67095E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 167.9990000 g log = 2.2253 Original solution: 1000.0103000 g Original solution / Rock added: 5.95 (Water/Rock Ratio), log = 0.7747 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0867 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9684E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3822E-08 1.0072 0.4183E-08 0.4154E-08 CH4,gas 0.1784E-01 1.0128 0.1964E-01 0.1939E-01 H2,gas 0.1373E-01 1.0006 0.1493E-01 0.1492E-01 H2S,gas 0.1328E-06 0.9958 0.1438E-06 0.1444E-06 S2,gas 0.3195E-29 1.0000 0.3472E-29 0.3472E-29 CO,gas 0.1489E-13 1.0000 0.1618E-13 0.1618E-13 SO3,gas 0.8084E-48 1.0000 0.8785E-48 0.8785E-48 SO2,gas 0.4566E-27 1.0000 0.4962E-27 0.4962E-27 HCl,gas 0.2700E-17 1.0000 0.2934E-17 0.2934E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.74 -10.38 -3.459 0.17721E+05 -8.378 3 CH4,gas 4.81 1.10 -3.71 -0.927 0.63295E+04 -1.707 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65327E+04 -1.826 5 H2S,gas -5.94 -14.79 -8.84 -4.421 0.15098E+05 -6.842 6 S2,gas -7.03 -38.49 -31.46 -4.840 0.53716E+05 -29.459 7 CO,gas 3.51 -12.28 -15.79 -4.859 0.26963E+05 -13.791 8 SO3,gas 17.43 -32.63 -50.06 -12.514 0.85470E+05 -48.056 9 SO2,gas 1.14 -28.17 -29.30 -7.814 0.50036E+05 -27.304 10 HCl,gas 5.48 -14.05 -19.53 -9.766 0.33351E+05 -17.533 11 acmite 7.74 6.57 -1.17 -0.121 0.19925E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.76 -4.79 -0.239 0.81760E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94083E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41189E+04 27 phlogopite 27.15 25.49 -1.66 -0.092 0.28370E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76214E+04 35 aragonite 0.99 -3.63 -4.62 -1.540 0.78904E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55851E+04 37 calcite 0.83 -3.63 -4.47 -1.489 0.76291E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52879E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71148E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.274 0.70304E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82175E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28594E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47362E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39553E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.167 0.68638E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70355E+04 52 chloritoid-Mn 11.46 7.60 -3.86 -0.257 0.65917E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13295E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10224E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36445E+04 66 diamond -3.11 -7.82 -4.71 -1.346 0.80464E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.81 -1.97 -0.096 0.33634E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66021E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57722E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68261E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56957E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36648E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70707E+04 86 graphite -3.55 -7.82 -4.27 -1.220 0.72925E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38612E+04 90 hematite 12.60 9.02 -3.57 -0.433 0.61003E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24439E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64134E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59754E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15989E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22953E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58932E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28455E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74530E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48216E+04 112 manganosite 14.07 9.23 -4.84 -1.210 0.82651E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61259E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53644E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41159E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83601E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36589E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20036E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92718E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40640E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.056 0.43386E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64859E+04 144 pyrrhotiteFe0.875 -6.00 -9.44 -3.44 -1.264 0.58688E+04 145 pyroxmangite 7.42 6.08 -1.34 -0.267 0.22822E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84873E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28343E+03 152 rhodonite 7.46 6.08 -1.38 -0.277 0.23615E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27380E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20976E+04 174 tephroite 18.11 15.31 -2.81 -0.401 0.47913E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91072E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76043E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65773E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62291E+04 183 vesuvianite 224.06 219.35 -4.70 -0.036 0.80270E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34497E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66746E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55583E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60375E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66122E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68735E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73628E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60303E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57950E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83198E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61776E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66262E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52981E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.56 -4.60 -1.532 0.78462E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62629E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52612E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18239E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11527E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14887E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18332E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 167.9990000 g New total amount of reactant added: 171.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7172E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 171.9990000 Water: Moles liquid = 0.5446E+02 kg liquid = 0.9811E+00 Moles total = 0.5335E+02 kg total = 0.9612E+00 Activity = 1.0000 Stoichiometric ionic strength = .1172869E-01 Osmotic coef. = 0.9690 True ionic strength = .2068289E-01 Chg. balance for total moles = -.7172E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90251E-10 -10.0445 0.75718E-10 -10.1208 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13998E-03 -3.8539 0.11671E-03 -3.9329 0.83382E+00 -0.0789 4 SO4-- 0.79482E-12 -12.0997 0.41010E-12 -12.3871 0.51596E+00 -0.2874 5 HCO3- 0.28682E-06 -6.5424 0.23952E-06 -6.6207 0.83506E+00 -0.0783 6 HS- 0.25990E-04 -4.5852 0.21674E-04 -4.6641 0.83395E+00 -0.0789 7 Al+++ 0.11015E-28 -28.9580 0.25074E-29 -29.6008 0.22763E+00 -0.6428 8 H4SiO4 0.71123E-03 -3.1480 0.71123E-03 -3.1480 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73317E-07 -7.1348 0.51209E+00 -0.2906 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50971E+00 -0.2927 11 Fe++ 0.62164E-13 -13.2065 0.31721E-13 -13.4987 0.51028E+00 -0.2922 12 K+ 0.16141E-03 -3.7921 0.13482E-03 -3.8703 0.83526E+00 -0.0782 13 Na+ 0.20520E-01 -1.6878 0.17107E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.18974E-10 -10.7218 0.96902E-11 -11.0137 0.51071E+00 -0.2918 15 HPO4-- 0.48751E-07 -7.3120 0.25158E-07 -7.5993 0.51604E+00 -0.2873 16 HSiO3- 0.10991E-01 -1.9590 0.91646E-02 -2.0379 0.83382E+00 -0.0789 17 Ca(HSiO3)+ 0.18020E-07 -7.7442 0.15055E-07 -7.8223 0.83545E+00 -0.0781 18 Mg(HSiO3)+ 0.35446E-11 -11.4504 0.29613E-11 -11.5285 0.83545E+00 -0.0781 19 NaHSiO3,aq 0.24900E-02 -2.6038 0.24900E-02 -2.6038 0.10000E+01 0.0000 20 AlO+ 0.67580E-16 -16.1702 0.56459E-16 -16.2483 0.83545E+00 -0.0781 22 HAlO2,aq 0.14921E-09 -9.8262 0.14921E-09 -9.8262 0.10000E+01 0.0000 23 AlO2- 0.52868E-05 -5.2768 0.44002E-05 -5.3565 0.83229E+00 -0.0797 24 CH4,aq 0.12466E-04 -4.9043 0.12422E-04 -4.9058 0.99643E+00 -0.0016 25 C2H6,aq 0.24534E-14 -14.6102 0.24446E-14 -14.6118 0.99643E+00 -0.0016 29 CO,aq 0.10251E-16 -16.9892 0.10251E-16 -16.9892 0.10000E+01 0.0000 30 CO2,aq 0.36697E-10 -10.4354 0.36565E-10 -10.4369 0.99643E+00 -0.0016 31 CO3-2 0.56808E-06 -6.2456 0.29247E-06 -6.5339 0.51485E+00 -0.2883 32 CaCO3,aq 0.26263E-09 -9.5807 0.26263E-09 -9.5807 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.52963E-12 -12.2760 0.44248E-12 -12.3541 0.83545E+00 -0.0781 34 CaCl+ 0.16322E-10 -10.7872 0.13636E-10 -10.8653 0.83545E+00 -0.0781 35 CaCl2,aq 0.37056E-15 -15.4311 0.37056E-15 -15.4311 0.10000E+01 0.0000 36 CaOH+ 0.81725E-07 -7.0876 0.68277E-07 -7.1657 0.83545E+00 -0.0781 37 CaSO4,aq 0.93682E-17 -17.0283 0.93682E-17 -17.0283 0.10000E+01 0.0000 38 HCl,aq 0.16623E-14 -14.7793 0.16623E-14 -14.7793 0.10000E+01 0.0000 43 FeCl+ 0.69021E-17 -17.1610 0.57664E-17 -17.2391 0.83545E+00 -0.0781 46 FeO,aq 0.21879E-09 -9.6600 0.21879E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16624E-10 -10.7793 0.13889E-10 -10.8573 0.83545E+00 -0.0781 48 HFeO2- 0.37274E-07 -7.4286 0.31080E-07 -7.5075 0.83382E+00 -0.0789 49 FeO+ 0.12262E-16 -16.9114 0.10244E-16 -16.9895 0.83545E+00 -0.0781 51 FeO2- 0.42117E-09 -9.3755 0.35118E-09 -9.4545 0.83382E+00 -0.0789 52 HFeO2,aq 0.33278E-11 -11.4778 0.33278E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10924E-04 -4.9616 0.10885E-04 -4.9632 0.99643E+00 -0.0016 54 KCl,aq 0.27861E-09 -9.5550 0.27861E-09 -9.5550 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10215E-14 -14.9907 0.85179E-15 -15.0697 0.83382E+00 -0.0789 58 MgCO3,aq 0.10373E-13 -13.9841 0.10373E-13 -13.9841 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.85364E-16 -16.0687 0.71317E-16 -16.1468 0.83545E+00 -0.0781 60 MgCl+ 0.23419E-14 -14.6304 0.19566E-14 -14.7085 0.83545E+00 -0.0781 61 MgOH+ 0.71562E-10 -10.1453 0.59787E-10 -10.2234 0.83545E+00 -0.0781 63 MnO,aq 0.17842E-08 -8.7486 0.17842E-08 -8.7486 0.10000E+01 0.0000 64 MnOH+ 0.47177E-09 -9.3263 0.39414E-09 -9.4044 0.83545E+00 -0.0781 65 MnO2-2 0.20904E-10 -10.6798 0.10763E-10 -10.9681 0.51485E+00 -0.2883 66 HMnO2- 0.21175E-09 -9.6742 0.17656E-09 -9.7531 0.83382E+00 -0.0789 69 MnCl+ 0.81932E-14 -14.0865 0.68450E-14 -14.1646 0.83545E+00 -0.0781 71 NaCl,aq 0.65195E-06 -6.1858 0.65195E-06 -6.1858 0.10000E+01 0.0000 72 NaOH,aq 0.99276E-04 -4.0032 0.99276E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95182E-02 -2.0214 0.79219E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16800E-14 -14.7747 0.86494E-15 -15.0630 0.51485E+00 -0.2883 81 H2PO3- 0.15429E-18 -18.8117 0.12865E-18 -18.8906 0.83382E+00 -0.0789 82 H3PO4,aq 0.92858E-18 -18.0322 0.92858E-18 -18.0322 0.10000E+01 0.0000 83 H2PO4- 0.40014E-10 -10.3978 0.33397E-10 -10.4763 0.83463E+00 -0.0785 84 PO4-3 0.12124E-08 -8.9164 0.29016E-09 -9.5374 0.23933E+00 -0.6210 88 HP2O7-3 0.10374E-17 -17.9841 0.23639E-18 -18.6264 0.22787E+00 -0.6423 89 P2O7-4 0.10249E-16 -16.9893 0.77020E-18 -18.1134 0.75151E-01 -1.1241 90 H2S,aq 0.49486E-08 -8.3055 0.49309E-08 -8.3071 0.99643E+00 -0.0016 91 S2-2 0.18437E-14 -14.7343 0.94920E-15 -15.0226 0.51485E+00 -0.2883 97 SO3-2 0.11650E-17 -17.9337 0.60865E-18 -18.2156 0.52245E+00 -0.2820 99 HSO4- 0.34452E-19 -19.4628 0.28812E-19 -19.5404 0.83628E+00 -0.0776 Charge balance for all species = -.7469E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9025118E-10 -.2312407E-01 -.2326550E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981191E+06 0.0000 3 Cl- 0.1399753E-03 0.1406276E-03 0.4976646E+01 6.1879 4 SO4-- 0.7948196E-12 -.1519710E-04 -.1457216E+01 7.8545 5 HCO3- 0.2868249E-06 0.1332135E-04 0.8113604E+00 3.5001 6 HS- 0.2599000E-04 0.4119205E-04 0.1359838E+01 5.4567 7 Al+++ 0.1101502E-28 0.5286953E-05 0.1423917E+00 0.7616 8 H4SiO4 0.7112349E-03 0.1419241E-01 0.1361640E+04 -3.1480 9 Ca++ 0.1431708E-06 0.2431949E-06 0.9729125E-02 13.1068 10 Mg++ 0.2273530E-10 0.9785505E-10 0.2374746E-05 9.3056 11 Fe++ 0.6216421E-13 0.3793389E-07 0.2114660E-02 6.7429 12 K+ 0.1614058E-03 0.1621823E-03 0.6330174E+01 6.2505 13 Na+ 0.2052034E-01 0.2311031E-01 0.5303398E+03 8.3540 14 Mn++ 0.1897411E-10 0.2507626E-08 0.1375146E-03 9.2279 15 HPO4-- 0.4875141E-07 0.5000381E-07 0.4790630E-02 12.6423 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2848035E+01 -.2268776E-01 -.2825347E+01 0.0000000E+00 2 H2O 0.5335217E+02 0.5445715E+02 -.1104979E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4792183E-02 -.1491036E-04 0.4807093E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4766679E-02 0.4041483E-04 -.4807093E-02 0.0000000E+00 7 Al+++ 0.5608443E+00 0.5187197E-05 0.5608391E+00 0.0000000E+00 8 H4SiO4 0.1790988E+01 0.1392462E-01 0.1777064E+01 0.0000000E+00 9 Ca++ 0.1978379E+00 0.2386062E-06 0.1978376E+00 0.0000000E+00 10 Mg++ 0.1365071E+00 0.9600870E-10 0.1365071E+00 0.0000000E+00 11 Fe++ 0.1226368E+00 0.3721815E-07 0.1226367E+00 0.0000000E+00 12 K+ 0.3651783E-01 0.1591222E-03 0.3635871E-01 0.0000000E+00 13 Na+ 0.2160607E+00 0.2267426E-01 0.1933865E+00 0.0000000E+00 14 Mn++ 0.2982221E-02 0.2460311E-08 0.2982219E-02 0.0000000E+00 15 HPO4-- 0.1017817E-02 0.4906033E-07 0.1017768E-02 0.0000000E+00 Chg. balance for solid moles: 0.2658E-15 Mass of aqueous solution: 0.982911E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 171.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1931 -0.714 50.65 1.705 26.98 19.44 andradite 0.1923E-01 -1.716 9.771 0.990 5.206 2.539 grossular 0.4601E-02 -2.337 2.073 0.317 1.104 0.5767 apatite-OH 0.3393E-03 -3.469 0.1704 -0.768 0.9079E-01 0.5415E-01 clinochlore 0.2581E-01 -1.588 14.34 1.157 7.642 5.456 daphnite 0.7393E-02 -2.131 5.275 0.722 2.810 1.598 chlorite-Mn 0.5964E-03 -3.224 0.4229 -0.374 0.2253 0.1348 diopside 0.4575E-03 -3.340 0.9907E-01 -1.004 0.5278E-01 0.3028E-01 hedenbergite 0.1171E-03 -3.931 0.2906E-01 -1.537 0.1548E-01 0.7961E-02 microcline 0.3189E-01 -1.496 8.877 0.948 4.729 3.467 stilbite 0.1202 -0.920 84.71 1.928 45.13 39.51 stilpnomelane-Fe 0.8936E-02 -2.049 9.632 0.984 5.132 3.327 tr.625ac.25prg.125 0.1936E-02 -2.713 1.655 0.219 0.8816 0.5326 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8069E+00 0.8069E+00 1.0000 -0.093 grossular 0.1931E+00 0.1931E+00 1.0000 -0.714 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7636E+00 0.7636E+00 1.0000 -0.117 daphnite 0.2188E+00 0.2188E+00 1.0000 -0.660 chlorite-Mn 0.1765E-01 0.1765E-01 1.0000 -1.753 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 187.706253 g Volume = 76.677374 cm3 Porosity: -9.8536% V(tot) - V(min): -.68778E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 171.9990000 g log = 2.2355 Original solution: 1000.0103000 g Original solution / Rock added: 5.81 (Water/Rock Ratio), log = 0.7645 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0868 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9684E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3824E-08 1.0072 0.4186E-08 0.4156E-08 CH4,gas 0.1785E-01 1.0128 0.1964E-01 0.1939E-01 H2,gas 0.1373E-01 1.0006 0.1493E-01 0.1492E-01 H2S,gas 0.1329E-06 0.9958 0.1438E-06 0.1444E-06 S2,gas 0.3198E-29 1.0000 0.3475E-29 0.3475E-29 CO,gas 0.1489E-13 1.0000 0.1619E-13 0.1619E-13 SO3,gas 0.8088E-48 1.0000 0.8790E-48 0.8790E-48 SO2,gas 0.4568E-27 1.0000 0.4964E-27 0.4964E-27 HCl,gas 0.2701E-17 1.0000 0.2935E-17 0.2935E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.97059E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.74 -10.38 -3.459 0.17721E+05 -8.378 3 CH4,gas 4.81 1.10 -3.71 -0.927 0.63292E+04 -1.707 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65327E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.421 0.15098E+05 -6.842 6 S2,gas -7.03 -38.49 -31.46 -4.840 0.53715E+05 -29.459 7 CO,gas 3.51 -12.28 -15.79 -4.859 0.26962E+05 -13.791 8 SO3,gas 17.43 -32.63 -50.06 -12.514 0.85469E+05 -48.056 9 SO2,gas 1.14 -28.17 -29.30 -7.814 0.50036E+05 -27.304 10 HCl,gas 5.48 -14.05 -19.53 -9.766 0.33351E+05 -17.532 11 acmite 7.74 6.57 -1.17 -0.121 0.19925E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.76 -4.79 -0.239 0.81733E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94084E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41189E+04 27 phlogopite 27.15 25.49 -1.66 -0.092 0.28370E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76215E+04 35 aragonite 0.99 -3.63 -4.62 -1.540 0.78900E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55851E+04 37 calcite 0.83 -3.63 -4.47 -1.489 0.76287E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52879E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71148E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.274 0.70305E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82175E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28594E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47361E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39553E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.167 0.68639E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70356E+04 52 chloritoid-Mn 11.46 7.60 -3.86 -0.257 0.65909E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13295E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10224E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36445E+04 66 diamond -3.11 -7.82 -4.71 -1.346 0.80460E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.81 -1.97 -0.096 0.33634E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66022E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57722E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68261E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56957E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36649E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70707E+04 86 graphite -3.55 -7.82 -4.27 -1.220 0.72922E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38612E+04 90 hematite 12.60 9.02 -3.57 -0.433 0.61003E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24439E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64134E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59754E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15989E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22953E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58932E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28456E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74529E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48216E+04 112 manganosite 14.07 9.23 -4.84 -1.210 0.82642E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61260E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53644E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41159E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83601E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36589E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20036E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92720E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40641E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.056 0.43387E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64856E+04 144 pyrrhotiteFe0.875 -6.00 -9.44 -3.44 -1.264 0.58685E+04 145 pyroxmangite 7.42 6.08 -1.34 -0.267 0.22813E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84873E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28342E+03 152 rhodonite 7.46 6.08 -1.38 -0.276 0.23606E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27380E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20976E+04 174 tephroite 18.11 15.31 -2.81 -0.401 0.47895E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91071E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76043E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65772E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62288E+04 183 vesuvianite 224.06 219.35 -4.70 -0.036 0.80274E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34498E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66747E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55583E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60374E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66122E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68735E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73628E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60304E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57949E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83198E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61776E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66261E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52980E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.56 -4.59 -1.532 0.78450E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62630E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52612E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18239E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11527E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14888E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18332E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 171.9990000 g New total amount of reactant added: 175.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7175E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 175.9990000 Water: Moles liquid = 0.5444E+02 kg liquid = 0.9807E+00 Moles total = 0.5330E+02 kg total = 0.9603E+00 Activity = 1.0000 Stoichiometric ionic strength = .1172879E-01 Osmotic coef. = 0.9690 True ionic strength = .2068301E-01 Chg. balance for total moles = -.7175E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90252E-10 -10.0445 0.75719E-10 -10.1208 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14003E-03 -3.8538 0.11676E-03 -3.9327 0.83382E+00 -0.0789 4 SO4-- 0.79524E-12 -12.0995 0.41031E-12 -12.3869 0.51596E+00 -0.2874 5 HCO3- 0.28697E-06 -6.5422 0.23964E-06 -6.6204 0.83506E+00 -0.0783 6 HS- 0.26001E-04 -4.5850 0.21683E-04 -4.6639 0.83395E+00 -0.0789 7 Al+++ 0.11015E-28 -28.9580 0.25073E-29 -29.6008 0.22763E+00 -0.6428 8 H4SiO4 0.71124E-03 -3.1480 0.71124E-03 -3.1480 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73317E-07 -7.1348 0.51209E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50971E+00 -0.2927 11 Fe++ 0.62165E-13 -13.2065 0.31721E-13 -13.4987 0.51027E+00 -0.2922 12 K+ 0.16141E-03 -3.7921 0.13482E-03 -3.8703 0.83526E+00 -0.0782 13 Na+ 0.20520E-01 -1.6878 0.17107E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.18997E-10 -10.7213 0.97016E-11 -11.0132 0.51071E+00 -0.2918 15 HPO4-- 0.48752E-07 -7.3120 0.25158E-07 -7.5993 0.51604E+00 -0.2873 16 HSiO3- 0.10991E-01 -1.9590 0.91647E-02 -2.0379 0.83382E+00 -0.0789 17 Ca(HSiO3)+ 0.18020E-07 -7.7442 0.15055E-07 -7.8223 0.83545E+00 -0.0781 18 Mg(HSiO3)+ 0.35446E-11 -11.4504 0.29613E-11 -11.5285 0.83545E+00 -0.0781 19 NaHSiO3,aq 0.24901E-02 -2.6038 0.24901E-02 -2.6038 0.10000E+01 0.0000 20 AlO+ 0.67577E-16 -16.1702 0.56457E-16 -16.2483 0.83545E+00 -0.0781 22 HAlO2,aq 0.14921E-09 -9.8262 0.14921E-09 -9.8262 0.10000E+01 0.0000 23 AlO2- 0.52866E-05 -5.2768 0.44000E-05 -5.3566 0.83229E+00 -0.0797 24 CH4,aq 0.12471E-04 -4.9041 0.12427E-04 -4.9056 0.99643E+00 -0.0016 25 C2H6,aq 0.24554E-14 -14.6099 0.24466E-14 -14.6114 0.99643E+00 -0.0016 29 CO,aq 0.10256E-16 -16.9890 0.10256E-16 -16.9890 0.10000E+01 0.0000 30 CO2,aq 0.36716E-10 -10.4351 0.36585E-10 -10.4367 0.99643E+00 -0.0016 31 CO3-2 0.56837E-06 -6.2454 0.29263E-06 -6.5337 0.51485E+00 -0.2883 32 CaCO3,aq 0.26276E-09 -9.5804 0.26276E-09 -9.5804 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.52990E-12 -12.2758 0.44271E-12 -12.3539 0.83545E+00 -0.0781 34 CaCl+ 0.16328E-10 -10.7871 0.13641E-10 -10.8651 0.83545E+00 -0.0781 35 CaCl2,aq 0.37086E-15 -15.4308 0.37086E-15 -15.4308 0.10000E+01 0.0000 36 CaOH+ 0.81724E-07 -7.0876 0.68276E-07 -7.1657 0.83545E+00 -0.0781 37 CaSO4,aq 0.93732E-17 -17.0281 0.93732E-17 -17.0281 0.10000E+01 0.0000 38 HCl,aq 0.16630E-14 -14.7791 0.16630E-14 -14.7791 0.10000E+01 0.0000 43 FeCl+ 0.69050E-17 -17.1608 0.57687E-17 -17.2389 0.83545E+00 -0.0781 46 FeO,aq 0.21879E-09 -9.6600 0.21879E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16624E-10 -10.7793 0.13889E-10 -10.8573 0.83545E+00 -0.0781 48 HFeO2- 0.37274E-07 -7.4286 0.31079E-07 -7.5075 0.83382E+00 -0.0789 49 FeO+ 0.12262E-16 -16.9114 0.10244E-16 -16.9895 0.83545E+00 -0.0781 51 FeO2- 0.42117E-09 -9.3755 0.35118E-09 -9.4545 0.83382E+00 -0.0789 52 HFeO2,aq 0.33279E-11 -11.4778 0.33279E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10924E-04 -4.9616 0.10885E-04 -4.9632 0.99643E+00 -0.0016 54 KCl,aq 0.27873E-09 -9.5548 0.27873E-09 -9.5548 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10221E-14 -14.9905 0.85224E-15 -15.0694 0.83382E+00 -0.0789 58 MgCO3,aq 0.10378E-13 -13.9839 0.10378E-13 -13.9839 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.85408E-16 -16.0685 0.71354E-16 -16.1466 0.83545E+00 -0.0781 60 MgCl+ 0.23429E-14 -14.6302 0.19574E-14 -14.7083 0.83545E+00 -0.0781 61 MgOH+ 0.71562E-10 -10.1453 0.59786E-10 -10.2234 0.83545E+00 -0.0781 63 MnO,aq 0.17863E-08 -8.7480 0.17863E-08 -8.7480 0.10000E+01 0.0000 64 MnOH+ 0.47232E-09 -9.3258 0.39460E-09 -9.4038 0.83545E+00 -0.0781 65 MnO2-2 0.20929E-10 -10.6793 0.10775E-10 -10.9676 0.51485E+00 -0.2883 66 HMnO2- 0.21200E-09 -9.6737 0.17677E-09 -9.7526 0.83382E+00 -0.0789 69 MnCl+ 0.82063E-14 -14.0859 0.68559E-14 -14.1639 0.83545E+00 -0.0781 71 NaCl,aq 0.65222E-06 -6.1856 0.65222E-06 -6.1856 0.10000E+01 0.0000 72 NaOH,aq 0.99276E-04 -4.0032 0.99276E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95182E-02 -2.0214 0.79219E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16800E-14 -14.7747 0.86492E-15 -15.0630 0.51485E+00 -0.2883 81 H2PO3- 0.15428E-18 -18.8117 0.12865E-18 -18.8906 0.83382E+00 -0.0789 82 H3PO4,aq 0.92860E-18 -18.0322 0.92860E-18 -18.0322 0.10000E+01 0.0000 83 H2PO4- 0.40015E-10 -10.3978 0.33397E-10 -10.4763 0.83463E+00 -0.0785 84 PO4-3 0.12124E-08 -8.9164 0.29016E-09 -9.5374 0.23933E+00 -0.6210 88 HP2O7-3 0.10374E-17 -17.9840 0.23640E-18 -18.6263 0.22787E+00 -0.6423 89 P2O7-4 0.10249E-16 -16.9893 0.77022E-18 -18.1134 0.75151E-01 -1.1241 90 H2S,aq 0.49506E-08 -8.3053 0.49329E-08 -8.3069 0.99643E+00 -0.0016 91 S2-2 0.18452E-14 -14.7340 0.95001E-15 -15.0223 0.51485E+00 -0.2883 97 SO3-2 0.11656E-17 -17.9335 0.60895E-18 -18.2154 0.52245E+00 -0.2820 99 HSO4- 0.34471E-19 -19.4625 0.28827E-19 -19.5402 0.83628E+00 -0.0776 Charge balance for all species = -.7417E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9025169E-10 -.2312415E-01 -.2326557E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981191E+06 0.0000 3 Cl- 0.1400327E-03 0.1406852E-03 0.4978685E+01 6.1881 4 SO4-- 0.7952406E-12 -.1520203E-04 -.1457689E+01 7.8547 5 HCO3- 0.2869745E-06 0.1332681E-04 0.8116929E+00 3.5004 6 HS- 0.2600065E-04 0.4120763E-04 0.1360352E+01 5.4569 7 Al+++ 0.1101479E-28 0.5286715E-05 0.1423853E+00 0.7616 8 H4SiO4 0.7112444E-03 0.1419254E-01 0.1361653E+04 -3.1480 9 Ca++ 0.1431706E-06 0.2431943E-06 0.9729099E-02 13.1068 10 Mg++ 0.2273524E-10 0.9785434E-10 0.2374729E-05 9.3056 11 Fe++ 0.6216463E-13 0.3793351E-07 0.2114639E-02 6.7429 12 K+ 0.1614067E-03 0.1621832E-03 0.6330208E+01 6.2505 13 Na+ 0.2052045E-01 0.2311046E-01 0.5303432E+03 8.3540 14 Mn++ 0.1899654E-10 0.2510562E-08 0.1376756E-03 9.2284 15 HPO4-- 0.4875207E-07 0.5000449E-07 0.4790695E-02 12.6423 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2914269E+01 -.2267855E-01 -.2891591E+01 0.0000000E+00 2 H2O 0.5330203E+02 0.5443484E+02 -.1132814E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4903037E-02 -.1490909E-04 0.4917946E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4877532E-02 0.4041356E-04 -.4917946E-02 0.0000000E+00 7 Al+++ 0.5738873E+00 0.5184839E-05 0.5738821E+00 0.0000000E+00 8 H4SiO4 0.1832639E+01 0.1391905E-01 0.1818720E+01 0.0000000E+00 9 Ca++ 0.2024384E+00 0.2385079E-06 0.2024382E+00 0.0000000E+00 10 Mg++ 0.1396817E+00 0.9596868E-10 0.1396817E+00 0.0000000E+00 11 Fe++ 0.1254888E+00 0.3720253E-07 0.1254888E+00 0.0000000E+00 12 K+ 0.3736709E-01 0.1590579E-03 0.3720803E-01 0.0000000E+00 13 Na+ 0.2210817E+00 0.2266512E-01 0.1984166E+00 0.0000000E+00 14 Mn++ 0.3051576E-02 0.2462183E-08 0.3051573E-02 0.0000000E+00 15 HPO4-- 0.1041488E-02 0.4904090E-07 0.1041439E-02 0.0000000E+00 Chg. balance for solid moles: 0.8509E-15 Mass of aqueous solution: 0.982508E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 175.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.1982 -0.703 51.96 1.716 27.05 19.95 andradite 0.1967E-01 -1.706 9.997 1.000 5.205 2.597 grossular 0.4707E-02 -2.327 2.120 0.326 1.104 0.5900 apatite-OH 0.3471E-03 -3.459 0.1744 -0.759 0.9079E-01 0.5541E-01 clinochlore 0.2638E-01 -1.579 14.66 1.166 7.632 5.576 daphnite 0.7556E-02 -2.122 5.391 0.732 2.807 1.634 chlorite-Mn 0.6103E-03 -3.214 0.4327 -0.364 0.2253 0.1379 diopside 0.6888E-03 -3.162 0.1492 -0.826 0.7766E-01 0.4559E-01 hedenbergite 0.1764E-03 -3.754 0.4376E-01 -1.359 0.2278E-01 0.1199E-01 microcline 0.3263E-01 -1.486 9.084 0.958 4.729 3.548 stilbite 0.1228 -0.911 86.52 1.937 45.05 40.36 stilpnomelane-Fe 0.9147E-02 -2.039 9.860 0.994 5.134 3.406 tr.625ac.25prg.125 0.1963E-02 -2.707 1.678 0.225 0.8736 0.5401 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8069E+00 0.8069E+00 1.0000 -0.093 grossular 0.1931E+00 0.1931E+00 1.0000 -0.714 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7636E+00 0.7636E+00 1.0000 -0.117 daphnite 0.2188E+00 0.2188E+00 1.0000 -0.660 chlorite-Mn 0.1767E-01 0.1767E-01 1.0000 -1.753 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 192.076465 g Volume = 78.445628 cm3 Porosity: -9.8684% V(tot) - V(min): -.70460E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 175.9990000 g log = 2.2455 Original solution: 1000.0103000 g Original solution / Rock added: 5.68 (Water/Rock Ratio), log = 0.7545 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0868 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9684E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3826E-08 1.0072 0.4188E-08 0.4158E-08 CH4,gas 0.1785E-01 1.0128 0.1965E-01 0.1940E-01 H2,gas 0.1373E-01 1.0006 0.1493E-01 0.1492E-01 H2S,gas 0.1329E-06 0.9958 0.1439E-06 0.1445E-06 S2,gas 0.3201E-29 1.0000 0.3479E-29 0.3479E-29 CO,gas 0.1490E-13 1.0000 0.1619E-13 0.1619E-13 SO3,gas 0.8093E-48 1.0000 0.8795E-48 0.8795E-48 SO2,gas 0.4570E-27 1.0000 0.4967E-27 0.4967E-27 HCl,gas 0.2702E-17 1.0000 0.2936E-17 0.2936E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.18957E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.74 -10.38 -3.459 0.17720E+05 -8.378 3 CH4,gas 4.81 1.10 -3.71 -0.927 0.63289E+04 -1.707 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65327E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.421 0.15098E+05 -6.842 6 S2,gas -7.03 -38.49 -31.46 -4.840 0.53715E+05 -29.459 7 CO,gas 3.51 -12.28 -15.79 -4.859 0.26962E+05 -13.791 8 SO3,gas 17.43 -32.63 -50.06 -12.514 0.85469E+05 -48.056 9 SO2,gas 1.14 -28.17 -29.30 -7.814 0.50036E+05 -27.304 10 HCl,gas 5.48 -14.05 -19.53 -9.766 0.33351E+05 -17.532 11 acmite 7.74 6.57 -1.17 -0.121 0.19925E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.76 -4.79 -0.239 0.81708E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94085E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41189E+04 27 phlogopite 27.15 25.49 -1.66 -0.092 0.28370E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76215E+04 35 aragonite 0.99 -3.63 -4.62 -1.540 0.78896E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55851E+04 37 calcite 0.83 -3.63 -4.47 -1.489 0.76283E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52880E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71148E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70305E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82176E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28594E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47361E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39553E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.167 0.68639E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70356E+04 52 chloritoid-Mn 11.46 7.60 -3.86 -0.257 0.65901E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13295E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10224E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36446E+04 66 diamond -3.11 -7.82 -4.71 -1.346 0.80457E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.81 -1.97 -0.096 0.33635E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66022E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57722E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68261E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56958E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36649E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70707E+04 86 graphite -3.55 -7.82 -4.27 -1.220 0.72918E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38612E+04 90 hematite 12.60 9.02 -3.57 -0.433 0.61002E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24439E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64134E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59755E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15990E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22954E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58933E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28456E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74529E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48216E+04 112 manganosite 14.07 9.23 -4.84 -1.210 0.82633E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61260E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53645E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41159E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83601E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36589E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20037E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92721E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40643E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.056 0.43388E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64853E+04 144 pyrrhotiteFe0.875 -6.00 -9.44 -3.44 -1.264 0.58682E+04 145 pyroxmangite 7.42 6.08 -1.34 -0.267 0.22805E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84873E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28341E+03 152 rhodonite 7.46 6.08 -1.38 -0.276 0.23597E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27380E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20975E+04 174 tephroite 18.11 15.31 -2.80 -0.401 0.47878E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91070E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76043E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65772E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62285E+04 183 vesuvianite 224.06 219.35 -4.70 -0.036 0.80278E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34498E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66748E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55583E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60373E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66123E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68735E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73629E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60304E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57949E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83197E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61775E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66261E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52980E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.56 -4.59 -1.531 0.78438E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62630E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52612E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18239E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11527E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14888E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18332E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 175.9990000 g New total amount of reactant added: 179.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7199E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 179.9990000 Water: Moles liquid = 0.5442E+02 kg liquid = 0.9803E+00 Moles total = 0.5325E+02 kg total = 0.9594E+00 Activity = 1.0000 Stoichiometric ionic strength = .1172889E-01 Osmotic coef. = 0.9690 True ionic strength = .2068312E-01 Chg. balance for total moles = -.7199E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90252E-10 -10.0445 0.75719E-10 -10.1208 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14009E-03 -3.8536 0.11681E-03 -3.9325 0.83382E+00 -0.0789 4 SO4-- 0.79566E-12 -12.0993 0.41053E-12 -12.3867 0.51596E+00 -0.2874 5 HCO3- 0.28712E-06 -6.5419 0.23977E-06 -6.6202 0.83506E+00 -0.0783 6 HS- 0.26011E-04 -4.5848 0.21692E-04 -4.6637 0.83395E+00 -0.0789 7 Al+++ 0.11015E-28 -28.9580 0.25073E-29 -29.6008 0.22763E+00 -0.6428 8 H4SiO4 0.71125E-03 -3.1480 0.71125E-03 -3.1480 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73317E-07 -7.1348 0.51209E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50971E+00 -0.2927 11 Fe++ 0.62165E-13 -13.2065 0.31721E-13 -13.4987 0.51027E+00 -0.2922 12 K+ 0.16141E-03 -3.7921 0.13482E-03 -3.8703 0.83526E+00 -0.0782 13 Na+ 0.20521E-01 -1.6878 0.17107E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.19018E-10 -10.7208 0.97126E-11 -11.0127 0.51071E+00 -0.2918 15 HPO4-- 0.48753E-07 -7.3120 0.25158E-07 -7.5993 0.51604E+00 -0.2873 16 HSiO3- 0.10991E-01 -1.9590 0.91648E-02 -2.0379 0.83382E+00 -0.0789 17 Ca(HSiO3)+ 0.18020E-07 -7.7442 0.15055E-07 -7.8223 0.83545E+00 -0.0781 18 Mg(HSiO3)+ 0.35446E-11 -11.4504 0.29613E-11 -11.5285 0.83545E+00 -0.0781 19 NaHSiO3,aq 0.24901E-02 -2.6038 0.24901E-02 -2.6038 0.10000E+01 0.0000 20 AlO+ 0.67575E-16 -16.1702 0.56455E-16 -16.2483 0.83545E+00 -0.0781 22 HAlO2,aq 0.14920E-09 -9.8262 0.14920E-09 -9.8262 0.10000E+01 0.0000 23 AlO2- 0.52863E-05 -5.2768 0.43998E-05 -5.3566 0.83229E+00 -0.0797 24 CH4,aq 0.12476E-04 -4.9039 0.12432E-04 -4.9055 0.99643E+00 -0.0016 25 C2H6,aq 0.24575E-14 -14.6095 0.24487E-14 -14.6111 0.99643E+00 -0.0016 29 CO,aq 0.10261E-16 -16.9888 0.10261E-16 -16.9888 0.10000E+01 0.0000 30 CO2,aq 0.36735E-10 -10.4349 0.36604E-10 -10.4365 0.99643E+00 -0.0016 31 CO3-2 0.56867E-06 -6.2451 0.29277E-06 -6.5335 0.51485E+00 -0.2883 32 CaCO3,aq 0.26290E-09 -9.5802 0.26290E-09 -9.5802 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53018E-12 -12.2756 0.44293E-12 -12.3537 0.83545E+00 -0.0781 34 CaCl+ 0.16335E-10 -10.7869 0.13647E-10 -10.8650 0.83545E+00 -0.0781 35 CaCl2,aq 0.37116E-15 -15.4304 0.37116E-15 -15.4304 0.10000E+01 0.0000 36 CaOH+ 0.81724E-07 -7.0877 0.68276E-07 -7.1657 0.83545E+00 -0.0781 37 CaSO4,aq 0.93780E-17 -17.0279 0.93780E-17 -17.0279 0.10000E+01 0.0000 38 HCl,aq 0.16637E-14 -14.7789 0.16637E-14 -14.7789 0.10000E+01 0.0000 43 FeCl+ 0.69079E-17 -17.1607 0.57711E-17 -17.2387 0.83545E+00 -0.0781 46 FeO,aq 0.21879E-09 -9.6600 0.21879E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16624E-10 -10.7793 0.13889E-10 -10.8573 0.83545E+00 -0.0781 48 HFeO2- 0.37273E-07 -7.4286 0.31079E-07 -7.5075 0.83382E+00 -0.0789 49 FeO+ 0.12262E-16 -16.9114 0.10245E-16 -16.9895 0.83545E+00 -0.0781 51 FeO2- 0.42117E-09 -9.3755 0.35118E-09 -9.4545 0.83382E+00 -0.0789 52 HFeO2,aq 0.33279E-11 -11.4778 0.33279E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10923E-04 -4.9616 0.10884E-04 -4.9632 0.99643E+00 -0.0016 54 KCl,aq 0.27884E-09 -9.5546 0.27884E-09 -9.5546 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10226E-14 -14.9903 0.85269E-15 -15.0692 0.83382E+00 -0.0789 58 MgCO3,aq 0.10383E-13 -13.9837 0.10383E-13 -13.9837 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.85452E-16 -16.0683 0.71390E-16 -16.1464 0.83545E+00 -0.0781 60 MgCl+ 0.23438E-14 -14.6301 0.19582E-14 -14.7082 0.83545E+00 -0.0781 61 MgOH+ 0.71561E-10 -10.1453 0.59785E-10 -10.2234 0.83545E+00 -0.0781 63 MnO,aq 0.17883E-08 -8.7476 0.17883E-08 -8.7476 0.10000E+01 0.0000 64 MnOH+ 0.47286E-09 -9.3253 0.39505E-09 -9.4034 0.83545E+00 -0.0781 65 MnO2-2 0.20952E-10 -10.6788 0.10787E-10 -10.9671 0.51485E+00 -0.2883 66 HMnO2- 0.21223E-09 -9.6732 0.17697E-09 -9.7521 0.83382E+00 -0.0789 69 MnCl+ 0.82189E-14 -14.0852 0.68665E-14 -14.1633 0.83545E+00 -0.0781 71 NaCl,aq 0.65249E-06 -6.1854 0.65249E-06 -6.1854 0.10000E+01 0.0000 72 NaOH,aq 0.99276E-04 -4.0032 0.99276E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95181E-02 -2.0214 0.79219E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16799E-14 -14.7747 0.86491E-15 -15.0630 0.51485E+00 -0.2883 81 H2PO3- 0.15428E-18 -18.8117 0.12864E-18 -18.8906 0.83382E+00 -0.0789 82 H3PO4,aq 0.92862E-18 -18.0322 0.92862E-18 -18.0322 0.10000E+01 0.0000 83 H2PO4- 0.40015E-10 -10.3978 0.33398E-10 -10.4763 0.83463E+00 -0.0785 84 PO4-3 0.12124E-08 -8.9163 0.29016E-09 -9.5374 0.23933E+00 -0.6210 88 HP2O7-3 0.10375E-17 -17.9840 0.23641E-18 -18.6263 0.22787E+00 -0.6423 89 P2O7-4 0.10249E-16 -16.9893 0.77024E-18 -18.1134 0.75150E-01 -1.1241 90 H2S,aq 0.49527E-08 -8.3052 0.49350E-08 -8.3067 0.99643E+00 -0.0016 91 S2-2 0.18468E-14 -14.7336 0.95081E-15 -15.0219 0.51485E+00 -0.2883 97 SO3-2 0.11662E-17 -17.9332 0.60926E-18 -18.2152 0.52244E+00 -0.2820 99 HSO4- 0.34489E-19 -19.4623 0.28842E-19 -19.5400 0.83628E+00 -0.0776 Charge balance for all species = -.7384E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9025218E-10 -.2312422E-01 -.2326565E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981191E+06 0.0000 3 Cl- 0.1400901E-03 0.1407429E-03 0.4980726E+01 6.1883 4 SO4-- 0.7956579E-12 -.1520697E-04 -.1458162E+01 7.8549 5 HCO3- 0.2871228E-06 0.1333227E-04 0.8120256E+00 3.5006 6 HS- 0.2601131E-04 0.4122324E-04 0.1360867E+01 5.4571 7 Al+++ 0.1101457E-28 0.5286487E-05 0.1423792E+00 0.7616 8 H4SiO4 0.7112536E-03 0.1419267E-01 0.1361665E+04 -3.1480 9 Ca++ 0.1431704E-06 0.2431937E-06 0.9729076E-02 13.1068 10 Mg++ 0.2273518E-10 0.9785363E-10 0.2374712E-05 9.3056 11 Fe++ 0.6216504E-13 0.3793314E-07 0.2114618E-02 6.7429 12 K+ 0.1614075E-03 0.1621840E-03 0.6330242E+01 6.2505 13 Na+ 0.2052056E-01 0.2311060E-01 0.5303464E+03 8.3540 14 Mn++ 0.1901803E-10 0.2513374E-08 0.1378298E-03 9.2289 15 HPO4-- 0.4875270E-07 0.5000513E-07 0.4790756E-02 12.6423 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2980503E+01 -.2266933E-01 -.2957834E+01 0.0000000E+00 2 H2O 0.5325189E+02 0.5441254E+02 -.1160650E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5013890E-02 -.1490782E-04 0.5028798E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4988386E-02 0.4041229E-04 -.5028798E-02 0.0000000E+00 7 Al+++ 0.5869302E+00 0.5182492E-05 0.5869250E+00 0.0000000E+00 8 H4SiO4 0.1874291E+01 0.1391347E-01 0.1860377E+01 0.0000000E+00 9 Ca++ 0.2070390E+00 0.2384096E-06 0.2070388E+00 0.0000000E+00 10 Mg++ 0.1428563E+00 0.9592865E-10 0.1428563E+00 0.0000000E+00 11 Fe++ 0.1283408E+00 0.3718692E-07 0.1283408E+00 0.0000000E+00 12 K+ 0.3821635E-01 0.1589935E-03 0.3805735E-01 0.0000000E+00 13 Na+ 0.2261027E+00 0.2265597E-01 0.2034467E+00 0.0000000E+00 14 Mn++ 0.3120930E-02 0.2463931E-08 0.3120927E-02 0.0000000E+00 15 HPO4-- 0.1065158E-02 0.4902143E-07 0.1065109E-02 0.0000000E+00 Chg. balance for solid moles: 0.1206E-15 Mass of aqueous solution: 0.982105E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 179.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2032 -0.692 53.28 1.727 27.12 20.45 andradite 0.2012E-01 -1.696 10.22 1.010 5.204 2.656 grossular 0.4813E-02 -2.318 2.168 0.336 1.104 0.6032 apatite-OH 0.3550E-03 -3.450 0.1783 -0.749 0.9078E-01 0.5667E-01 clinochlore 0.2694E-01 -1.570 14.98 1.175 7.624 5.697 daphnite 0.7719E-02 -2.112 5.508 0.741 2.804 1.669 chlorite-Mn 0.6242E-03 -3.205 0.4425 -0.354 0.2253 0.1410 diopside 0.9202E-03 -3.036 0.1993 -0.701 0.1014 0.6090E-01 hedenbergite 0.2356E-03 -3.628 0.5846E-01 -1.233 0.2976E-01 0.1601E-01 microcline 0.3338E-01 -1.477 9.290 0.968 4.729 3.629 stilbite 0.1253 -0.902 88.33 1.946 44.96 41.20 stilpnomelane-Fe 0.9358E-02 -2.029 10.09 1.004 5.135 3.485 tr.625ac.25prg.125 0.1990E-02 -2.701 1.701 0.231 0.8660 0.5476 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8069E+00 0.8069E+00 1.0000 -0.093 grossular 0.1931E+00 0.1931E+00 1.0000 -0.714 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7636E+00 0.7636E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1769E-01 0.1769E-01 1.0000 -1.752 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 196.446677 g Volume = 80.213882 cm3 Porosity: -9.8826% V(tot) - V(min): -.72143E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 179.9990000 g log = 2.2553 Original solution: 1000.0103000 g Original solution / Rock added: 5.56 (Water/Rock Ratio), log = 0.7447 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0868 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9684E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3828E-08 1.0072 0.4190E-08 0.4160E-08 CH4,gas 0.1786E-01 1.0128 0.1966E-01 0.1941E-01 H2,gas 0.1373E-01 1.0006 0.1493E-01 0.1492E-01 H2S,gas 0.1330E-06 0.9958 0.1439E-06 0.1445E-06 S2,gas 0.3204E-29 1.0000 0.3482E-29 0.3482E-29 CO,gas 0.1491E-13 1.0000 0.1620E-13 0.1620E-13 SO3,gas 0.8097E-48 1.0000 0.8799E-48 0.8799E-48 SO2,gas 0.4573E-27 1.0000 0.4969E-27 0.4969E-27 HCl,gas 0.2703E-17 1.0000 0.2938E-17 0.2938E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.74 -10.38 -3.459 0.17720E+05 -8.378 3 CH4,gas 4.81 1.10 -3.71 -0.927 0.63286E+04 -1.706 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65328E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.421 0.15097E+05 -6.842 6 S2,gas -7.03 -38.49 -31.46 -4.840 0.53714E+05 -29.458 7 CO,gas 3.51 -12.28 -15.79 -4.859 0.26962E+05 -13.790 8 SO3,gas 17.43 -32.63 -50.06 -12.514 0.85468E+05 -48.056 9 SO2,gas 1.14 -28.17 -29.30 -7.814 0.50035E+05 -27.304 10 HCl,gas 5.48 -14.05 -19.53 -9.766 0.33350E+05 -17.532 11 acmite 7.74 6.57 -1.17 -0.121 0.19924E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.77 -4.78 -0.239 0.81683E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94086E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41189E+04 27 phlogopite 27.15 25.49 -1.66 -0.092 0.28371E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76216E+04 35 aragonite 0.99 -3.63 -4.62 -1.540 0.78893E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55851E+04 37 calcite 0.83 -3.63 -4.47 -1.489 0.76279E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52880E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71148E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70306E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82176E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28594E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47361E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39553E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.167 0.68639E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70357E+04 52 chloritoid-Mn 11.46 7.60 -3.86 -0.257 0.65893E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13295E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10224E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36446E+04 66 diamond -3.11 -7.82 -4.71 -1.346 0.80453E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.81 -1.97 -0.096 0.33635E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66023E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57722E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68261E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56958E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36649E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70707E+04 86 graphite -3.55 -7.82 -4.27 -1.220 0.72915E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38612E+04 90 hematite 12.60 9.02 -3.57 -0.433 0.61002E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24439E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64134E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59755E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15990E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22954E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58933E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28456E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74529E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48216E+04 112 manganosite 14.07 9.23 -4.84 -1.210 0.82625E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61261E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53646E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41159E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83601E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36590E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20037E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92722E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40644E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.056 0.43390E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64850E+04 144 pyrrhotiteFe0.875 -6.00 -9.44 -3.44 -1.264 0.58679E+04 145 pyroxmangite 7.42 6.08 -1.34 -0.267 0.22796E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84873E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28340E+03 152 rhodonite 7.46 6.08 -1.38 -0.276 0.23588E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27381E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20975E+04 174 tephroite 18.11 15.31 -2.80 -0.400 0.47861E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91069E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76042E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65772E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62282E+04 183 vesuvianite 224.06 219.35 -4.70 -0.036 0.80281E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34498E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66749E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55583E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60372E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66123E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68735E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73629E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60304E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57949E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83197E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61775E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66260E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52979E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.56 -4.59 -1.531 0.78427E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62630E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52612E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18239E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11527E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14888E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18332E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 179.9990000 g New total amount of reactant added: 183.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7135E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 183.9990000 Water: Moles liquid = 0.5439E+02 kg liquid = 0.9799E+00 Moles total = 0.5320E+02 kg total = 0.9584E+00 Activity = 1.0000 Stoichiometric ionic strength = .1172899E-01 Osmotic coef. = 0.9690 True ionic strength = .2068323E-01 Chg. balance for total moles = -.7135E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90253E-10 -10.0445 0.75719E-10 -10.1208 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14015E-03 -3.8534 0.11686E-03 -3.9323 0.83382E+00 -0.0789 4 SO4-- 0.79607E-12 -12.0990 0.41074E-12 -12.3864 0.51596E+00 -0.2874 5 HCO3- 0.28727E-06 -6.5417 0.23989E-06 -6.6200 0.83506E+00 -0.0783 6 HS- 0.26022E-04 -4.5847 0.21701E-04 -4.6635 0.83394E+00 -0.0789 7 Al+++ 0.11014E-28 -28.9580 0.25072E-29 -29.6008 0.22763E+00 -0.6428 8 H4SiO4 0.71126E-03 -3.1480 0.71126E-03 -3.1480 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73316E-07 -7.1348 0.51209E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50970E+00 -0.2927 11 Fe++ 0.62165E-13 -13.2065 0.31721E-13 -13.4986 0.51027E+00 -0.2922 12 K+ 0.16141E-03 -3.7921 0.13482E-03 -3.8703 0.83526E+00 -0.0782 13 Na+ 0.20521E-01 -1.6878 0.17107E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.19039E-10 -10.7204 0.97231E-11 -11.0122 0.51070E+00 -0.2918 15 HPO4-- 0.48753E-07 -7.3120 0.25158E-07 -7.5993 0.51604E+00 -0.2873 16 HSiO3- 0.10991E-01 -1.9589 0.91648E-02 -2.0379 0.83382E+00 -0.0789 17 Ca(HSiO3)+ 0.18020E-07 -7.7442 0.15055E-07 -7.8223 0.83545E+00 -0.0781 18 Mg(HSiO3)+ 0.35446E-11 -11.4504 0.29614E-11 -11.5285 0.83545E+00 -0.0781 19 NaHSiO3,aq 0.24901E-02 -2.6038 0.24901E-02 -2.6038 0.10000E+01 0.0000 20 AlO+ 0.67573E-16 -16.1702 0.56454E-16 -16.2483 0.83545E+00 -0.0781 22 HAlO2,aq 0.14919E-09 -9.8262 0.14919E-09 -9.8262 0.10000E+01 0.0000 23 AlO2- 0.52861E-05 -5.2769 0.43996E-05 -5.3566 0.83229E+00 -0.0797 24 CH4,aq 0.12481E-04 -4.9037 0.12437E-04 -4.9053 0.99643E+00 -0.0016 25 C2H6,aq 0.24595E-14 -14.6092 0.24507E-14 -14.6107 0.99643E+00 -0.0016 29 CO,aq 0.10266E-16 -16.9886 0.10266E-16 -16.9886 0.10000E+01 0.0000 30 CO2,aq 0.36754E-10 -10.4347 0.36623E-10 -10.4362 0.99643E+00 -0.0016 31 CO3-2 0.56896E-06 -6.2449 0.29292E-06 -6.5332 0.51484E+00 -0.2883 32 CaCO3,aq 0.26303E-09 -9.5800 0.26303E-09 -9.5800 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53045E-12 -12.2754 0.44316E-12 -12.3534 0.83545E+00 -0.0781 34 CaCl+ 0.16341E-10 -10.7867 0.13652E-10 -10.8648 0.83545E+00 -0.0781 35 CaCl2,aq 0.37147E-15 -15.4301 0.37147E-15 -15.4301 0.10000E+01 0.0000 36 CaOH+ 0.81723E-07 -7.0877 0.68275E-07 -7.1657 0.83545E+00 -0.0781 37 CaSO4,aq 0.93829E-17 -17.0277 0.93829E-17 -17.0277 0.10000E+01 0.0000 38 HCl,aq 0.16644E-14 -14.7788 0.16644E-14 -14.7788 0.10000E+01 0.0000 43 FeCl+ 0.69107E-17 -17.1605 0.57735E-17 -17.2386 0.83545E+00 -0.0781 46 FeO,aq 0.21879E-09 -9.6600 0.21879E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16624E-10 -10.7793 0.13889E-10 -10.8573 0.83545E+00 -0.0781 48 HFeO2- 0.37273E-07 -7.4286 0.31079E-07 -7.5075 0.83382E+00 -0.0789 49 FeO+ 0.12263E-16 -16.9114 0.10245E-16 -16.9895 0.83545E+00 -0.0781 51 FeO2- 0.42118E-09 -9.3755 0.35119E-09 -9.4545 0.83382E+00 -0.0789 52 HFeO2,aq 0.33279E-11 -11.4778 0.33279E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10923E-04 -4.9617 0.10884E-04 -4.9632 0.99643E+00 -0.0016 54 KCl,aq 0.27896E-09 -9.5545 0.27896E-09 -9.5545 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10232E-14 -14.9901 0.85314E-15 -15.0690 0.83382E+00 -0.0789 58 MgCO3,aq 0.10388E-13 -13.9834 0.10388E-13 -13.9834 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.85495E-16 -16.0681 0.71427E-16 -16.1461 0.83545E+00 -0.0781 60 MgCl+ 0.23448E-14 -14.6299 0.19590E-14 -14.7080 0.83545E+00 -0.0781 61 MgOH+ 0.71560E-10 -10.1453 0.59785E-10 -10.2234 0.83545E+00 -0.0781 63 MnO,aq 0.17902E-08 -8.7471 0.17902E-08 -8.7471 0.10000E+01 0.0000 64 MnOH+ 0.47336E-09 -9.3248 0.39547E-09 -9.4029 0.83545E+00 -0.0781 65 MnO2-2 0.20974E-10 -10.6783 0.10798E-10 -10.9666 0.51484E+00 -0.2883 66 HMnO2- 0.21246E-09 -9.6727 0.17715E-09 -9.7516 0.83382E+00 -0.0789 69 MnCl+ 0.82312E-14 -14.0845 0.68767E-14 -14.1626 0.83545E+00 -0.0781 71 NaCl,aq 0.65277E-06 -6.1852 0.65277E-06 -6.1852 0.10000E+01 0.0000 72 NaOH,aq 0.99276E-04 -4.0032 0.99276E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95181E-02 -2.0215 0.79218E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16799E-14 -14.7747 0.86489E-15 -15.0630 0.51484E+00 -0.2883 81 H2PO3- 0.15428E-18 -18.8117 0.12864E-18 -18.8906 0.83382E+00 -0.0789 82 H3PO4,aq 0.92864E-18 -18.0322 0.92864E-18 -18.0322 0.10000E+01 0.0000 83 H2PO4- 0.40016E-10 -10.3978 0.33398E-10 -10.4763 0.83463E+00 -0.0785 84 PO4-3 0.12124E-08 -8.9163 0.29017E-09 -9.5374 0.23933E+00 -0.6210 88 HP2O7-3 0.10375E-17 -17.9840 0.23641E-18 -18.6263 0.22787E+00 -0.6423 89 P2O7-4 0.10250E-16 -16.9893 0.77025E-18 -18.1134 0.75150E-01 -1.1241 90 H2S,aq 0.49547E-08 -8.3050 0.49370E-08 -8.3065 0.99643E+00 -0.0016 91 S2-2 0.18484E-14 -14.7332 0.95162E-15 -15.0215 0.51484E+00 -0.2883 97 SO3-2 0.11667E-17 -17.9330 0.60955E-18 -18.2150 0.52244E+00 -0.2820 99 HSO4- 0.34507E-19 -19.4621 0.28858E-19 -19.5397 0.83628E+00 -0.0776 Charge balance for all species = -.7343E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9025266E-10 -.2312429E-01 -.2326572E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981191E+06 0.0000 3 Cl- 0.1401475E-03 0.1408006E-03 0.4982769E+01 6.1885 4 SO4-- 0.7960716E-12 -.1521193E-04 -.1458637E+01 7.8552 5 HCO3- 0.2872700E-06 0.1333774E-04 0.8123586E+00 3.5008 6 HS- 0.2602198E-04 0.4123886E-04 0.1361383E+01 5.4573 7 Al+++ 0.1101437E-28 0.5286269E-05 0.1423733E+00 0.7616 8 H4SiO4 0.7112623E-03 0.1419279E-01 0.1361677E+04 -3.1480 9 Ca++ 0.1431702E-06 0.2431932E-06 0.9729055E-02 13.1068 10 Mg++ 0.2273512E-10 0.9785303E-10 0.2374697E-05 9.3056 11 Fe++ 0.6216544E-13 0.3793278E-07 0.2114598E-02 6.7429 12 K+ 0.1614084E-03 0.1621849E-03 0.6330275E+01 6.2505 13 Na+ 0.2052067E-01 0.2311074E-01 0.5303496E+03 8.3540 14 Mn++ 0.1903864E-10 0.2516069E-08 0.1379776E-03 9.2294 15 HPO4-- 0.4875330E-07 0.5000574E-07 0.4790815E-02 12.6423 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3046737E+01 -.2266010E-01 -.3024077E+01 0.0000000E+00 2 H2O 0.5320175E+02 0.5439023E+02 -.1188486E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5124744E-02 -.1490657E-04 0.5139651E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5099240E-02 0.4041104E-04 -.5139651E-02 0.0000000E+00 7 Al+++ 0.5999732E+00 0.5180153E-05 0.5999680E+00 0.0000000E+00 8 H4SiO4 0.1915942E+01 0.1390789E-01 0.1902034E+01 0.0000000E+00 9 Ca++ 0.2116396E+00 0.2383113E-06 0.2116393E+00 0.0000000E+00 10 Mg++ 0.1460310E+00 0.9588874E-10 0.1460310E+00 0.0000000E+00 11 Fe++ 0.1311929E+00 0.3717133E-07 0.1311928E+00 0.0000000E+00 12 K+ 0.3906561E-01 0.1589292E-03 0.3890668E-01 0.0000000E+00 13 Na+ 0.2311236E+00 0.2264681E-01 0.2084768E+00 0.0000000E+00 14 Mn++ 0.3190284E-02 0.2465562E-08 0.3190282E-02 0.0000000E+00 15 HPO4-- 0.1088828E-02 0.4900193E-07 0.1088779E-02 0.0000000E+00 Chg. balance for solid moles: 0.3404E-15 Mass of aqueous solution: 0.981703E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 183.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2082 -0.681 54.60 1.737 27.19 20.96 andradite 0.2056E-01 -1.687 10.45 1.019 5.202 2.714 grossular 0.4919E-02 -2.308 2.216 0.346 1.103 0.6165 apatite-OH 0.3629E-03 -3.440 0.1823 -0.739 0.9078E-01 0.5793E-01 clinochlore 0.2751E-01 -1.560 15.29 1.184 7.615 5.817 daphnite 0.7882E-02 -2.103 5.624 0.750 2.801 1.704 chlorite-Mn 0.6381E-03 -3.195 0.4524 -0.345 0.2253 0.1442 diopside 0.1152E-02 -2.939 0.2494 -0.603 0.1242 0.7621E-01 hedenbergite 0.2949E-03 -3.530 0.7316E-01 -1.136 0.3643E-01 0.2004E-01 microcline 0.3412E-01 -1.467 9.497 0.978 4.729 3.710 stilbite 0.1279 -0.893 90.14 1.955 44.89 42.04 stilpnomelane-Fe 0.9570E-02 -2.019 10.32 1.014 5.137 3.563 tr.625ac.25prg.125 0.2018E-02 -2.695 1.725 0.237 0.8588 0.5551 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8069E+00 0.8069E+00 1.0000 -0.093 grossular 0.1931E+00 0.1931E+00 1.0000 -0.714 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7635E+00 0.7635E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1771E-01 0.1771E-01 1.0000 -1.752 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 200.816890 g Volume = 81.982136 cm3 Porosity: -9.8962% V(tot) - V(min): -.73825E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 183.9990000 g log = 2.2648 Original solution: 1000.0103000 g Original solution / Rock added: 5.43 (Water/Rock Ratio), log = 0.7352 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0868 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9684E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3830E-08 1.0072 0.4192E-08 0.4162E-08 CH4,gas 0.1787E-01 1.0128 0.1967E-01 0.1942E-01 H2,gas 0.1373E-01 1.0006 0.1493E-01 0.1492E-01 H2S,gas 0.1331E-06 0.9958 0.1440E-06 0.1446E-06 S2,gas 0.3206E-29 1.0000 0.3485E-29 0.3485E-29 CO,gas 0.1492E-13 1.0000 0.1621E-13 0.1621E-13 SO3,gas 0.8101E-48 1.0000 0.8804E-48 0.8804E-48 SO2,gas 0.4575E-27 1.0000 0.4972E-27 0.4972E-27 HCl,gas 0.2704E-17 1.0000 0.2939E-17 0.2939E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.74 -10.38 -3.459 0.17719E+05 -8.378 3 CH4,gas 4.81 1.10 -3.71 -0.927 0.63283E+04 -1.706 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65328E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.421 0.15097E+05 -6.842 6 S2,gas -7.03 -38.49 -31.46 -4.840 0.53713E+05 -29.458 7 CO,gas 3.51 -12.28 -15.79 -4.859 0.26961E+05 -13.790 8 SO3,gas 17.43 -32.63 -50.06 -12.514 0.85468E+05 -48.055 9 SO2,gas 1.14 -28.17 -29.30 -7.814 0.50035E+05 -27.303 10 HCl,gas 5.48 -14.05 -19.53 -9.766 0.33350E+05 -17.532 11 acmite 7.74 6.57 -1.17 -0.121 0.19924E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.77 -4.78 -0.239 0.81660E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94087E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41189E+04 27 phlogopite 27.15 25.49 -1.66 -0.092 0.28371E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76216E+04 35 aragonite 0.99 -3.63 -4.62 -1.540 0.78889E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55851E+04 37 calcite 0.83 -3.63 -4.47 -1.489 0.76276E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52880E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71149E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70306E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82176E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28594E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47361E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39553E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.167 0.68639E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70357E+04 52 chloritoid-Mn 11.46 7.60 -3.86 -0.257 0.65885E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13295E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10224E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36446E+04 66 diamond -3.11 -7.82 -4.71 -1.346 0.80450E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.81 -1.97 -0.096 0.33636E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66024E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57722E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68261E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56958E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36649E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70707E+04 86 graphite -3.55 -7.82 -4.27 -1.220 0.72912E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38612E+04 90 hematite 12.60 9.02 -3.57 -0.433 0.61002E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24439E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64135E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59756E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15990E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22955E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58933E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28456E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74529E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48215E+04 112 manganosite 14.07 9.23 -4.84 -1.210 0.82617E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61261E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53646E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41159E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83601E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36590E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20037E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92723E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40645E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.056 0.43391E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64847E+04 144 pyrrhotiteFe0.875 -6.00 -9.44 -3.44 -1.264 0.58676E+04 145 pyroxmangite 7.42 6.08 -1.33 -0.267 0.22788E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84873E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28339E+03 152 rhodonite 7.46 6.08 -1.38 -0.276 0.23580E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27381E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20975E+04 174 tephroite 18.11 15.31 -2.80 -0.400 0.47845E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91068E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76042E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65771E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62279E+04 183 vesuvianite 224.06 219.35 -4.70 -0.036 0.80284E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34498E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66749E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55583E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60371E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66123E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68735E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73629E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60304E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57948E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83197E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61775E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66260E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52979E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.55 -4.59 -1.531 0.78416E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62631E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52612E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18239E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11527E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14888E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18332E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 183.9990000 g New total amount of reactant added: 187.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7138E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 187.9990000 Water: Moles liquid = 0.5437E+02 kg liquid = 0.9795E+00 Moles total = 0.5315E+02 kg total = 0.9575E+00 Activity = 1.0000 Stoichiometric ionic strength = .1172909E-01 Osmotic coef. = 0.9690 True ionic strength = .2068333E-01 Chg. balance for total moles = -.7138E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90253E-10 -10.0445 0.75720E-10 -10.1208 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14021E-03 -3.8532 0.11691E-03 -3.9322 0.83382E+00 -0.0789 4 SO4-- 0.79648E-12 -12.0988 0.41095E-12 -12.3862 0.51596E+00 -0.2874 5 HCO3- 0.28742E-06 -6.5415 0.24001E-06 -6.6198 0.83506E+00 -0.0783 6 HS- 0.26033E-04 -4.5845 0.21710E-04 -4.6633 0.83394E+00 -0.0789 7 Al+++ 0.11014E-28 -28.9580 0.25072E-29 -29.6008 0.22763E+00 -0.6428 8 H4SiO4 0.71127E-03 -3.1480 0.71127E-03 -3.1480 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73316E-07 -7.1348 0.51209E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50970E+00 -0.2927 11 Fe++ 0.62166E-13 -13.2064 0.31722E-13 -13.4986 0.51027E+00 -0.2922 12 K+ 0.16141E-03 -3.7921 0.13482E-03 -3.8702 0.83526E+00 -0.0782 13 Na+ 0.20521E-01 -1.6878 0.17107E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.19058E-10 -10.7199 0.97332E-11 -11.0117 0.51070E+00 -0.2918 15 HPO4-- 0.48754E-07 -7.3120 0.25159E-07 -7.5993 0.51604E+00 -0.2873 16 HSiO3- 0.10991E-01 -1.9589 0.91649E-02 -2.0379 0.83382E+00 -0.0789 17 Ca(HSiO3)+ 0.18020E-07 -7.7442 0.15055E-07 -7.8223 0.83545E+00 -0.0781 18 Mg(HSiO3)+ 0.35447E-11 -11.4504 0.29614E-11 -11.5285 0.83545E+00 -0.0781 19 NaHSiO3,aq 0.24902E-02 -2.6038 0.24902E-02 -2.6038 0.10000E+01 0.0000 20 AlO+ 0.67571E-16 -16.1702 0.56452E-16 -16.2483 0.83545E+00 -0.0781 22 HAlO2,aq 0.14919E-09 -9.8263 0.14919E-09 -9.8263 0.10000E+01 0.0000 23 AlO2- 0.52859E-05 -5.2769 0.43994E-05 -5.3566 0.83229E+00 -0.0797 24 CH4,aq 0.12486E-04 -4.9036 0.12442E-04 -4.9051 0.99643E+00 -0.0016 25 C2H6,aq 0.24616E-14 -14.6088 0.24528E-14 -14.6103 0.99643E+00 -0.0016 29 CO,aq 0.10271E-16 -16.9884 0.10271E-16 -16.9884 0.10000E+01 0.0000 30 CO2,aq 0.36773E-10 -10.4345 0.36641E-10 -10.4360 0.99643E+00 -0.0016 31 CO3-2 0.56924E-06 -6.2447 0.29307E-06 -6.5330 0.51484E+00 -0.2883 32 CaCO3,aq 0.26316E-09 -9.5798 0.26316E-09 -9.5798 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53072E-12 -12.2751 0.44338E-12 -12.3532 0.83545E+00 -0.0781 34 CaCl+ 0.16348E-10 -10.7865 0.13658E-10 -10.8646 0.83545E+00 -0.0781 35 CaCl2,aq 0.37177E-15 -15.4297 0.37177E-15 -15.4297 0.10000E+01 0.0000 36 CaOH+ 0.81722E-07 -7.0877 0.68275E-07 -7.1657 0.83545E+00 -0.0781 37 CaSO4,aq 0.93877E-17 -17.0274 0.93877E-17 -17.0274 0.10000E+01 0.0000 38 HCl,aq 0.16650E-14 -14.7786 0.16650E-14 -14.7786 0.10000E+01 0.0000 43 FeCl+ 0.69136E-17 -17.1603 0.57759E-17 -17.2384 0.83545E+00 -0.0781 46 FeO,aq 0.21879E-09 -9.6600 0.21879E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16624E-10 -10.7793 0.13889E-10 -10.8573 0.83545E+00 -0.0781 48 HFeO2- 0.37272E-07 -7.4286 0.31079E-07 -7.5075 0.83382E+00 -0.0789 49 FeO+ 0.12263E-16 -16.9114 0.10245E-16 -16.9895 0.83545E+00 -0.0781 51 FeO2- 0.42118E-09 -9.3755 0.35119E-09 -9.4545 0.83382E+00 -0.0789 52 HFeO2,aq 0.33280E-11 -11.4778 0.33280E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10923E-04 -4.9617 0.10884E-04 -4.9632 0.99643E+00 -0.0016 54 KCl,aq 0.27907E-09 -9.5543 0.27907E-09 -9.5543 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10237E-14 -14.9898 0.85358E-15 -15.0688 0.83382E+00 -0.0789 58 MgCO3,aq 0.10394E-13 -13.9832 0.10394E-13 -13.9832 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.85538E-16 -16.0678 0.71463E-16 -16.1459 0.83545E+00 -0.0781 60 MgCl+ 0.23458E-14 -14.6297 0.19597E-14 -14.7078 0.83545E+00 -0.0781 61 MgOH+ 0.71560E-10 -10.1453 0.59784E-10 -10.2234 0.83545E+00 -0.0781 63 MnO,aq 0.17921E-08 -8.7466 0.17921E-08 -8.7466 0.10000E+01 0.0000 64 MnOH+ 0.47385E-09 -9.3244 0.39588E-09 -9.4024 0.83545E+00 -0.0781 65 MnO2-2 0.20996E-10 -10.6779 0.10809E-10 -10.9662 0.51484E+00 -0.2883 66 HMnO2- 0.21268E-09 -9.6723 0.17734E-09 -9.7512 0.83382E+00 -0.0789 69 MnCl+ 0.82431E-14 -14.0839 0.68867E-14 -14.1620 0.83545E+00 -0.0781 71 NaCl,aq 0.65304E-06 -6.1851 0.65304E-06 -6.1851 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95180E-02 -2.0215 0.79218E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16799E-14 -14.7747 0.86488E-15 -15.0630 0.51484E+00 -0.2883 81 H2PO3- 0.15428E-18 -18.8117 0.12864E-18 -18.8906 0.83382E+00 -0.0789 82 H3PO4,aq 0.92866E-18 -18.0321 0.92866E-18 -18.0321 0.10000E+01 0.0000 83 H2PO4- 0.40016E-10 -10.3978 0.33399E-10 -10.4763 0.83462E+00 -0.0785 84 PO4-3 0.12124E-08 -8.9163 0.29017E-09 -9.5374 0.23933E+00 -0.6210 88 HP2O7-3 0.10375E-17 -17.9840 0.23642E-18 -18.6263 0.22787E+00 -0.6423 89 P2O7-4 0.10250E-16 -16.9893 0.77027E-18 -18.1134 0.75149E-01 -1.1241 90 H2S,aq 0.49568E-08 -8.3048 0.49391E-08 -8.3064 0.99643E+00 -0.0016 91 S2-2 0.18499E-14 -14.7328 0.95243E-15 -15.0212 0.51484E+00 -0.2883 97 SO3-2 0.11673E-17 -17.9328 0.60985E-18 -18.2148 0.52244E+00 -0.2820 99 HSO4- 0.34525E-19 -19.4619 0.28873E-19 -19.5395 0.83628E+00 -0.0776 Charge balance for all species = -.7444E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9025313E-10 -.2312436E-01 -.2326578E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981190E+06 0.0000 3 Cl- 0.1402050E-03 0.1408584E-03 0.4984813E+01 6.1886 4 SO4-- 0.7964822E-12 -.1521689E-04 -.1459113E+01 7.8554 5 HCO3- 0.2874160E-06 0.1334321E-04 0.8126919E+00 3.5010 6 HS- 0.2603265E-04 0.4125450E-04 0.1361900E+01 5.4574 7 Al+++ 0.1101417E-28 0.5286058E-05 0.1423676E+00 0.7616 8 H4SiO4 0.7112707E-03 0.1419291E-01 0.1361688E+04 -3.1480 9 Ca++ 0.1431701E-06 0.2431927E-06 0.9729037E-02 13.1068 10 Mg++ 0.2273508E-10 0.9785243E-10 0.2374683E-05 9.3056 11 Fe++ 0.6216584E-13 0.3793244E-07 0.2114579E-02 6.7429 12 K+ 0.1614092E-03 0.1621857E-03 0.6330307E+01 6.2505 13 Na+ 0.2052077E-01 0.2311087E-01 0.5303527E+03 8.3540 14 Mn++ 0.1905841E-10 0.2518656E-08 0.1381195E-03 9.2298 15 HPO4-- 0.4875387E-07 0.5000632E-07 0.4790870E-02 12.6423 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3112971E+01 -.2265087E-01 -.3090320E+01 0.0000000E+00 2 H2O 0.5315161E+02 0.5436793E+02 -.1216321E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5235598E-02 -.1490532E-04 0.5250503E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5210093E-02 0.4040979E-04 -.5250503E-02 0.0000000E+00 7 Al+++ 0.6130162E+00 0.5177822E-05 0.6130110E+00 0.0000000E+00 8 H4SiO4 0.1957593E+01 0.1390230E-01 0.1943690E+01 0.0000000E+00 9 Ca++ 0.2162401E+00 0.2382131E-06 0.2162399E+00 0.0000000E+00 10 Mg++ 0.1492056E+00 0.9584883E-10 0.1492056E+00 0.0000000E+00 11 Fe++ 0.1340449E+00 0.3715574E-07 0.1340449E+00 0.0000000E+00 12 K+ 0.3991486E-01 0.1588648E-03 0.3975600E-01 0.0000000E+00 13 Na+ 0.2361446E+00 0.2263766E-01 0.2135070E+00 0.0000000E+00 14 Mn++ 0.3259639E-02 0.2467085E-08 0.3259636E-02 0.0000000E+00 15 HPO4-- 0.1112498E-02 0.4898241E-07 0.1112450E-02 0.0000000E+00 Chg. balance for solid moles: 0.1544E-15 Mass of aqueous solution: 0.981300E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 187.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2133 -0.671 55.92 1.748 27.25 21.47 andradite 0.2100E-01 -1.678 10.67 1.028 5.201 2.773 grossular 0.5025E-02 -2.299 2.263 0.355 1.103 0.6298 apatite-OH 0.3708E-03 -3.431 0.1863 -0.730 0.9078E-01 0.5919E-01 clinochlore 0.2808E-01 -1.552 15.61 1.193 7.607 5.937 daphnite 0.8045E-02 -2.094 5.740 0.759 2.798 1.739 chlorite-Mn 0.6519E-03 -3.186 0.4622 -0.335 0.2253 0.1473 diopside 0.1383E-02 -2.859 0.2995 -0.524 0.1460 0.9153E-01 hedenbergite 0.3541E-03 -3.451 0.8786E-01 -1.056 0.4282E-01 0.2407E-01 microcline 0.3487E-01 -1.458 9.704 0.987 4.730 3.791 stilbite 0.1305 -0.884 91.95 1.964 44.81 42.89 stilpnomelane-Fe 0.9781E-02 -2.010 10.54 1.023 5.139 3.642 tr.625ac.25prg.125 0.2045E-02 -2.689 1.748 0.243 0.8519 0.5626 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8069E+00 0.8069E+00 1.0000 -0.093 grossular 0.1931E+00 0.1931E+00 1.0000 -0.714 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7635E+00 0.7635E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1773E-01 0.1773E-01 1.0000 -1.751 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 205.187103 g Volume = 83.750390 cm3 Porosity: -9.9092% V(tot) - V(min): -.75508E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 187.9990000 g log = 2.2742 Original solution: 1000.0103000 g Original solution / Rock added: 5.32 (Water/Rock Ratio), log = 0.7258 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0868 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9684E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3832E-08 1.0072 0.4194E-08 0.4164E-08 CH4,gas 0.1787E-01 1.0128 0.1967E-01 0.1943E-01 H2,gas 0.1373E-01 1.0006 0.1493E-01 0.1492E-01 H2S,gas 0.1331E-06 0.9958 0.1441E-06 0.1447E-06 S2,gas 0.3209E-29 1.0000 0.3488E-29 0.3488E-29 CO,gas 0.1492E-13 1.0000 0.1622E-13 0.1622E-13 SO3,gas 0.8105E-48 1.0000 0.8809E-48 0.8809E-48 SO2,gas 0.4577E-27 1.0000 0.4974E-27 0.4974E-27 HCl,gas 0.2705E-17 1.0000 0.2940E-17 0.2940E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.54595E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.74 -10.38 -3.459 0.17719E+05 -8.377 3 CH4,gas 4.81 1.10 -3.71 -0.927 0.63280E+04 -1.706 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65328E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.421 0.15097E+05 -6.841 6 S2,gas -7.03 -38.49 -31.46 -4.840 0.53713E+05 -29.457 7 CO,gas 3.51 -12.28 -15.79 -4.858 0.26961E+05 -13.790 8 SO3,gas 17.43 -32.63 -50.06 -12.514 0.85468E+05 -48.055 9 SO2,gas 1.14 -28.17 -29.30 -7.814 0.50035E+05 -27.303 10 HCl,gas 5.48 -14.05 -19.53 -9.766 0.33350E+05 -17.532 11 acmite 7.74 6.57 -1.17 -0.121 0.19924E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.77 -4.78 -0.239 0.81637E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94088E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41190E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28371E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76217E+04 35 aragonite 0.99 -3.63 -4.62 -1.540 0.78885E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55851E+04 37 calcite 0.83 -3.63 -4.47 -1.489 0.76272E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52880E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71149E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70307E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82177E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47361E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39553E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.167 0.68640E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70358E+04 52 chloritoid-Mn 11.46 7.60 -3.86 -0.257 0.65878E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13295E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10224E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36447E+04 66 diamond -3.11 -7.82 -4.71 -1.346 0.80446E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.81 -1.97 -0.096 0.33636E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66025E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57722E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68260E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56958E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36649E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70707E+04 86 graphite -3.55 -7.82 -4.27 -1.220 0.72908E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38612E+04 90 hematite 12.60 9.02 -3.57 -0.433 0.61002E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24439E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64135E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59756E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15991E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22955E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58933E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28456E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74529E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48215E+04 112 manganosite 14.07 9.23 -4.84 -1.210 0.82609E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61262E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53647E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41160E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83601E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36590E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20038E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92724E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40646E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.056 0.43392E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64844E+04 144 pyrrhotiteFe0.875 -6.00 -9.44 -3.44 -1.264 0.58673E+04 145 pyroxmangite 7.42 6.08 -1.33 -0.267 0.22780E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84874E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28338E+03 152 rhodonite 7.46 6.08 -1.38 -0.276 0.23573E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27381E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20975E+04 174 tephroite 18.11 15.31 -2.80 -0.400 0.47830E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91067E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76042E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65771E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62275E+04 183 vesuvianite 224.06 219.35 -4.70 -0.036 0.80288E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34499E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66750E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55583E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60370E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66123E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68735E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73629E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60304E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57948E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83196E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61774E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66260E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52979E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.55 -4.59 -1.531 0.78405E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62631E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52612E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18239E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11527E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14888E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18332E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 187.9990000 g New total amount of reactant added: 191.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7184E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 191.9990000 Water: Moles liquid = 0.5435E+02 kg liquid = 0.9791E+00 Moles total = 0.5310E+02 kg total = 0.9566E+00 Activity = 1.0000 Stoichiometric ionic strength = .1172918E-01 Osmotic coef. = 0.9690 True ionic strength = .2068344E-01 Chg. balance for total moles = -.7184E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90254E-10 -10.0445 0.75720E-10 -10.1208 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14026E-03 -3.8531 0.11695E-03 -3.9320 0.83382E+00 -0.0789 4 SO4-- 0.79689E-12 -12.0986 0.41116E-12 -12.3860 0.51596E+00 -0.2874 5 HCO3- 0.28756E-06 -6.5413 0.24013E-06 -6.6196 0.83506E+00 -0.0783 6 HS- 0.26043E-04 -4.5843 0.21719E-04 -4.6632 0.83394E+00 -0.0789 7 Al+++ 0.11014E-28 -28.9581 0.25071E-29 -29.6008 0.22763E+00 -0.6428 8 H4SiO4 0.71128E-03 -3.1480 0.71128E-03 -3.1480 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73316E-07 -7.1348 0.51209E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50970E+00 -0.2927 11 Fe++ 0.62166E-13 -13.2064 0.31722E-13 -13.4986 0.51027E+00 -0.2922 12 K+ 0.16141E-03 -3.7921 0.13482E-03 -3.8702 0.83526E+00 -0.0782 13 Na+ 0.20521E-01 -1.6878 0.17107E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.19077E-10 -10.7195 0.97429E-11 -11.0113 0.51070E+00 -0.2918 15 HPO4-- 0.48754E-07 -7.3120 0.25159E-07 -7.5993 0.51603E+00 -0.2873 16 HSiO3- 0.10992E-01 -1.9589 0.91650E-02 -2.0379 0.83382E+00 -0.0789 17 Ca(HSiO3)+ 0.18020E-07 -7.7442 0.15055E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35447E-11 -11.4504 0.29614E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24902E-02 -2.6038 0.24902E-02 -2.6038 0.10000E+01 0.0000 20 AlO+ 0.67569E-16 -16.1703 0.56450E-16 -16.2483 0.83544E+00 -0.0781 22 HAlO2,aq 0.14918E-09 -9.8263 0.14918E-09 -9.8263 0.10000E+01 0.0000 23 AlO2- 0.52857E-05 -5.2769 0.43992E-05 -5.3566 0.83229E+00 -0.0797 24 CH4,aq 0.12491E-04 -4.9034 0.12447E-04 -4.9049 0.99643E+00 -0.0016 25 C2H6,aq 0.24636E-14 -14.6084 0.24548E-14 -14.6100 0.99643E+00 -0.0016 29 CO,aq 0.10276E-16 -16.9882 0.10276E-16 -16.9882 0.10000E+01 0.0000 30 CO2,aq 0.36792E-10 -10.4343 0.36660E-10 -10.4358 0.99643E+00 -0.0016 31 CO3-2 0.56953E-06 -6.2445 0.29322E-06 -6.5328 0.51484E+00 -0.2883 32 CaCO3,aq 0.26329E-09 -9.5796 0.26329E-09 -9.5796 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53098E-12 -12.2749 0.44361E-12 -12.3530 0.83544E+00 -0.0781 34 CaCl+ 0.16355E-10 -10.7864 0.13664E-10 -10.8644 0.83544E+00 -0.0781 35 CaCl2,aq 0.37207E-15 -15.4294 0.37207E-15 -15.4294 0.10000E+01 0.0000 36 CaOH+ 0.81722E-07 -7.0877 0.68274E-07 -7.1657 0.83544E+00 -0.0781 37 CaSO4,aq 0.93925E-17 -17.0272 0.93925E-17 -17.0272 0.10000E+01 0.0000 38 HCl,aq 0.16657E-14 -14.7784 0.16657E-14 -14.7784 0.10000E+01 0.0000 43 FeCl+ 0.69165E-17 -17.1601 0.57783E-17 -17.2382 0.83544E+00 -0.0781 46 FeO,aq 0.21878E-09 -9.6600 0.21878E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16624E-10 -10.7793 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37272E-07 -7.4286 0.31078E-07 -7.5075 0.83382E+00 -0.0789 49 FeO+ 0.12263E-16 -16.9114 0.10245E-16 -16.9895 0.83544E+00 -0.0781 51 FeO2- 0.42118E-09 -9.3755 0.35119E-09 -9.4545 0.83382E+00 -0.0789 52 HFeO2,aq 0.33280E-11 -11.4778 0.33280E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10922E-04 -4.9617 0.10883E-04 -4.9632 0.99643E+00 -0.0016 54 KCl,aq 0.27919E-09 -9.5541 0.27919E-09 -9.5541 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10242E-14 -14.9896 0.85402E-15 -15.0685 0.83382E+00 -0.0789 58 MgCO3,aq 0.10399E-13 -13.9830 0.10399E-13 -13.9830 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.85581E-16 -16.0676 0.71499E-16 -16.1457 0.83544E+00 -0.0781 60 MgCl+ 0.23467E-14 -14.6295 0.19605E-14 -14.7076 0.83544E+00 -0.0781 61 MgOH+ 0.71559E-10 -10.1453 0.59784E-10 -10.2234 0.83544E+00 -0.0781 63 MnO,aq 0.17938E-08 -8.7462 0.17938E-08 -8.7462 0.10000E+01 0.0000 64 MnOH+ 0.47432E-09 -9.3239 0.39627E-09 -9.4020 0.83544E+00 -0.0781 65 MnO2-2 0.21016E-10 -10.6774 0.10820E-10 -10.9658 0.51484E+00 -0.2883 66 HMnO2- 0.21289E-09 -9.6719 0.17751E-09 -9.7508 0.83382E+00 -0.0789 69 MnCl+ 0.82547E-14 -14.0833 0.68963E-14 -14.1614 0.83544E+00 -0.0781 71 NaCl,aq 0.65331E-06 -6.1849 0.65331E-06 -6.1849 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95180E-02 -2.0215 0.79217E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16799E-14 -14.7747 0.86486E-15 -15.0631 0.51484E+00 -0.2883 81 H2PO3- 0.15428E-18 -18.8117 0.12864E-18 -18.8906 0.83382E+00 -0.0789 82 H3PO4,aq 0.92867E-18 -18.0321 0.92867E-18 -18.0321 0.10000E+01 0.0000 83 H2PO4- 0.40017E-10 -10.3978 0.33399E-10 -10.4763 0.83462E+00 -0.0785 84 PO4-3 0.12124E-08 -8.9163 0.29017E-09 -9.5373 0.23933E+00 -0.6210 88 HP2O7-3 0.10375E-17 -17.9840 0.23643E-18 -18.6263 0.22787E+00 -0.6423 89 P2O7-4 0.10250E-16 -16.9893 0.77028E-18 -18.1133 0.75149E-01 -1.1241 90 H2S,aq 0.49589E-08 -8.3046 0.49411E-08 -8.3062 0.99643E+00 -0.0016 91 S2-2 0.18515E-14 -14.7325 0.95323E-15 -15.0208 0.51484E+00 -0.2883 97 SO3-2 0.11679E-17 -17.9326 0.61015E-18 -18.2146 0.52244E+00 -0.2820 99 HSO4- 0.34543E-19 -19.4616 0.28887E-19 -19.5393 0.83628E+00 -0.0777 Charge balance for all species = -.7384E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9025359E-10 -.2312442E-01 -.2326584E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981190E+06 0.0000 3 Cl- 0.1402626E-03 0.1409162E-03 0.4986859E+01 6.1888 4 SO4-- 0.7968897E-12 -.1522187E-04 -.1459590E+01 7.8556 5 HCO3- 0.2875611E-06 0.1334869E-04 0.8130254E+00 3.5012 6 HS- 0.2604334E-04 0.4127016E-04 0.1362417E+01 5.4576 7 Al+++ 0.1101399E-28 0.5285856E-05 0.1423622E+00 0.7615 8 H4SiO4 0.7112787E-03 0.1419302E-01 0.1361699E+04 -3.1480 9 Ca++ 0.1431700E-06 0.2431923E-06 0.9729020E-02 13.1068 10 Mg++ 0.2273503E-10 0.9785189E-10 0.2374669E-05 9.3056 11 Fe++ 0.6216623E-13 0.3793210E-07 0.2114560E-02 6.7429 12 K+ 0.1614100E-03 0.1621865E-03 0.6330338E+01 6.2505 13 Na+ 0.2052088E-01 0.2311100E-01 0.5303556E+03 8.3540 14 Mn++ 0.1907740E-10 0.2521140E-08 0.1382557E-03 9.2303 15 HPO4-- 0.4875441E-07 0.5000687E-07 0.4790923E-02 12.6423 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3179205E+01 -.2264164E-01 -.3156564E+01 0.0000000E+00 2 H2O 0.5310146E+02 0.5434562E+02 -.1244157E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5346451E-02 -.1490407E-04 0.5361355E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5320947E-02 0.4040854E-04 -.5361355E-02 0.0000000E+00 7 Al+++ 0.6260591E+00 0.5175500E-05 0.6260540E+00 0.0000000E+00 8 H4SiO4 0.1999244E+01 0.1389671E-01 0.1985347E+01 0.0000000E+00 9 Ca++ 0.2208407E+00 0.2381150E-06 0.2208405E+00 0.0000000E+00 10 Mg++ 0.1523802E+00 0.9580897E-10 0.1523802E+00 0.0000000E+00 11 Fe++ 0.1368969E+00 0.3714017E-07 0.1368969E+00 0.0000000E+00 12 K+ 0.4076412E-01 0.1588004E-03 0.4060532E-01 0.0000000E+00 13 Na+ 0.2411656E+00 0.2262850E-01 0.2185371E+00 0.0000000E+00 14 Mn++ 0.3328993E-02 0.2468504E-08 0.3328991E-02 0.0000000E+00 15 HPO4-- 0.1136169E-02 0.4896285E-07 0.1136120E-02 0.0000000E+00 Chg. balance for solid moles: -.4007E-15 Mass of aqueous solution: 0.980898E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 191.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2183 -0.661 57.24 1.758 27.31 21.97 andradite 0.2145E-01 -1.669 10.90 1.037 5.201 2.831 grossular 0.5131E-02 -2.290 2.311 0.364 1.103 0.6430 apatite-OH 0.3787E-03 -3.422 0.1902 -0.721 0.9078E-01 0.6045E-01 clinochlore 0.2865E-01 -1.543 15.93 1.202 7.599 6.057 daphnite 0.8208E-02 -2.086 5.857 0.768 2.795 1.775 chlorite-Mn 0.6658E-03 -3.177 0.4720 -0.326 0.2253 0.1504 diopside 0.1614E-02 -2.792 0.3496 -0.456 0.1668 0.1068 hedenbergite 0.4134E-03 -3.384 0.1026 -0.989 0.4894E-01 0.2809E-01 microcline 0.3561E-01 -1.448 9.911 0.996 4.730 3.872 stilbite 0.1330 -0.876 93.76 1.972 44.74 43.73 stilpnomelane-Fe 0.9992E-02 -2.000 10.77 1.032 5.140 3.721 tr.625ac.25prg.125 0.2072E-02 -2.684 1.771 0.248 0.8452 0.5701 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8069E+00 0.8069E+00 1.0000 -0.093 grossular 0.1931E+00 0.1931E+00 1.0000 -0.714 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7635E+00 0.7635E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1774E-01 0.1774E-01 1.0000 -1.751 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 209.557316 g Volume = 85.518644 cm3 Porosity: -9.9217% V(tot) - V(min): -.77190E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 191.9990000 g log = 2.2833 Original solution: 1000.0103000 g Original solution / Rock added: 5.21 (Water/Rock Ratio), log = 0.7167 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0868 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9684E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3834E-08 1.0072 0.4196E-08 0.4167E-08 CH4,gas 0.1788E-01 1.0128 0.1968E-01 0.1943E-01 H2,gas 0.1373E-01 1.0006 0.1493E-01 0.1492E-01 H2S,gas 0.1332E-06 0.9958 0.1441E-06 0.1447E-06 S2,gas 0.3212E-29 1.0000 0.3491E-29 0.3491E-29 CO,gas 0.1493E-13 1.0000 0.1623E-13 0.1623E-13 SO3,gas 0.8109E-48 1.0000 0.8813E-48 0.8813E-48 SO2,gas 0.4579E-27 1.0000 0.4977E-27 0.4977E-27 HCl,gas 0.2706E-17 1.0000 0.2941E-17 0.2941E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.74 -10.38 -3.459 0.17719E+05 -8.377 3 CH4,gas 4.81 1.10 -3.71 -0.926 0.63277E+04 -1.706 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65328E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.421 0.15096E+05 -6.841 6 S2,gas -7.03 -38.49 -31.46 -4.840 0.53712E+05 -29.457 7 CO,gas 3.51 -12.28 -15.79 -4.858 0.26961E+05 -13.790 8 SO3,gas 17.43 -32.63 -50.05 -12.514 0.85467E+05 -48.055 9 SO2,gas 1.14 -28.17 -29.30 -7.814 0.50034E+05 -27.303 10 HCl,gas 5.48 -14.05 -19.53 -9.766 0.33349E+05 -17.531 11 acmite 7.74 6.57 -1.17 -0.121 0.19924E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.77 -4.78 -0.239 0.81615E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94088E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41190E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28372E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76217E+04 35 aragonite 0.99 -3.63 -4.62 -1.540 0.78882E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55852E+04 37 calcite 0.83 -3.63 -4.47 -1.489 0.76268E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52880E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71149E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70307E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82177E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47361E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39553E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.167 0.68640E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70358E+04 52 chloritoid-Mn 11.46 7.61 -3.86 -0.257 0.65871E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13295E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10223E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36447E+04 66 diamond -3.11 -7.82 -4.71 -1.346 0.80443E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.81 -1.97 -0.096 0.33636E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66025E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57722E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68260E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56959E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36649E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70707E+04 86 graphite -3.55 -7.82 -4.27 -1.220 0.72905E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38611E+04 90 hematite 12.60 9.02 -3.57 -0.433 0.61002E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24439E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64135E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59756E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15991E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22956E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58933E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28456E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74529E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48215E+04 112 manganosite 14.07 9.23 -4.84 -1.209 0.82602E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61262E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53647E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41160E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83601E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36591E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20038E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92725E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40647E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.056 0.43393E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64841E+04 144 pyrrhotiteFe0.875 -6.00 -9.44 -3.44 -1.264 0.58670E+04 145 pyroxmangite 7.42 6.08 -1.33 -0.267 0.22773E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84874E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28337E+03 152 rhodonite 7.46 6.08 -1.38 -0.276 0.23565E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27382E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20975E+04 174 tephroite 18.11 15.31 -2.80 -0.400 0.47815E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91067E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76042E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65771E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62272E+04 183 vesuvianite 224.06 219.35 -4.70 -0.036 0.80291E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34499E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66751E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55583E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60369E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66123E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68735E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73629E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60304E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57948E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83196E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61774E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66259E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52978E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.55 -4.59 -1.530 0.78395E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62631E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52612E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18239E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11527E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14888E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18332E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 191.9990000 g New total amount of reactant added: 195.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7165E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 195.9990000 Water: Moles liquid = 0.5433E+02 kg liquid = 0.9787E+00 Moles total = 0.5305E+02 kg total = 0.9557E+00 Activity = 1.0000 Stoichiometric ionic strength = .1172927E-01 Osmotic coef. = 0.9690 True ionic strength = .2068354E-01 Chg. balance for total moles = -.7165E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90254E-10 -10.0445 0.75720E-10 -10.1208 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14032E-03 -3.8529 0.11700E-03 -3.9318 0.83382E+00 -0.0789 4 SO4-- 0.79729E-12 -12.0984 0.41137E-12 -12.3858 0.51596E+00 -0.2874 5 HCO3- 0.28771E-06 -6.5411 0.24025E-06 -6.6193 0.83506E+00 -0.0783 6 HS- 0.26054E-04 -4.5841 0.21728E-04 -4.6630 0.83394E+00 -0.0789 7 Al+++ 0.11014E-28 -28.9581 0.25071E-29 -29.6008 0.22763E+00 -0.6428 8 H4SiO4 0.71129E-03 -3.1480 0.71129E-03 -3.1480 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73316E-07 -7.1348 0.51209E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50970E+00 -0.2927 11 Fe++ 0.62167E-13 -13.2064 0.31722E-13 -13.4986 0.51027E+00 -0.2922 12 K+ 0.16141E-03 -3.7921 0.13482E-03 -3.8702 0.83526E+00 -0.0782 13 Na+ 0.20521E-01 -1.6878 0.17108E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.19096E-10 -10.7191 0.97522E-11 -11.0109 0.51070E+00 -0.2918 15 HPO4-- 0.48755E-07 -7.3120 0.25159E-07 -7.5993 0.51603E+00 -0.2873 16 HSiO3- 0.10992E-01 -1.9589 0.91650E-02 -2.0379 0.83382E+00 -0.0789 17 Ca(HSiO3)+ 0.18020E-07 -7.7442 0.15055E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35447E-11 -11.4504 0.29614E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24902E-02 -2.6038 0.24902E-02 -2.6038 0.10000E+01 0.0000 20 AlO+ 0.67567E-16 -16.1703 0.56449E-16 -16.2483 0.83544E+00 -0.0781 22 HAlO2,aq 0.14918E-09 -9.8263 0.14918E-09 -9.8263 0.10000E+01 0.0000 23 AlO2- 0.52855E-05 -5.2769 0.43991E-05 -5.3566 0.83229E+00 -0.0797 24 CH4,aq 0.12496E-04 -4.9032 0.12452E-04 -4.9048 0.99643E+00 -0.0016 25 C2H6,aq 0.24657E-14 -14.6081 0.24569E-14 -14.6096 0.99643E+00 -0.0016 29 CO,aq 0.10281E-16 -16.9880 0.10281E-16 -16.9880 0.10000E+01 0.0000 30 CO2,aq 0.36810E-10 -10.4340 0.36679E-10 -10.4356 0.99643E+00 -0.0016 31 CO3-2 0.56981E-06 -6.2443 0.29336E-06 -6.5326 0.51484E+00 -0.2883 32 CaCO3,aq 0.26342E-09 -9.5793 0.26342E-09 -9.5793 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53125E-12 -12.2747 0.44383E-12 -12.3528 0.83544E+00 -0.0781 34 CaCl+ 0.16361E-10 -10.7862 0.13669E-10 -10.8643 0.83544E+00 -0.0781 35 CaCl2,aq 0.37238E-15 -15.4290 0.37238E-15 -15.4290 0.10000E+01 0.0000 36 CaOH+ 0.81721E-07 -7.0877 0.68274E-07 -7.1657 0.83544E+00 -0.0781 37 CaSO4,aq 0.93972E-17 -17.0270 0.93972E-17 -17.0270 0.10000E+01 0.0000 38 HCl,aq 0.16664E-14 -14.7782 0.16664E-14 -14.7782 0.10000E+01 0.0000 43 FeCl+ 0.69193E-17 -17.1599 0.57807E-17 -17.2380 0.83544E+00 -0.0781 46 FeO,aq 0.21878E-09 -9.6600 0.21878E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16624E-10 -10.7793 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37272E-07 -7.4286 0.31078E-07 -7.5075 0.83382E+00 -0.0789 49 FeO+ 0.12263E-16 -16.9114 0.10245E-16 -16.9895 0.83544E+00 -0.0781 51 FeO2- 0.42118E-09 -9.3755 0.35119E-09 -9.4545 0.83382E+00 -0.0789 52 HFeO2,aq 0.33280E-11 -11.4778 0.33280E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10922E-04 -4.9617 0.10883E-04 -4.9632 0.99643E+00 -0.0016 54 KCl,aq 0.27931E-09 -9.5539 0.27931E-09 -9.5539 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10248E-14 -14.9894 0.85446E-15 -15.0683 0.83382E+00 -0.0789 58 MgCO3,aq 0.10404E-13 -13.9828 0.10404E-13 -13.9828 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.85624E-16 -16.0674 0.71534E-16 -16.1455 0.83544E+00 -0.0781 60 MgCl+ 0.23477E-14 -14.6294 0.19613E-14 -14.7074 0.83544E+00 -0.0781 61 MgOH+ 0.71559E-10 -10.1453 0.59783E-10 -10.2234 0.83544E+00 -0.0781 63 MnO,aq 0.17955E-08 -8.7458 0.17955E-08 -8.7458 0.10000E+01 0.0000 64 MnOH+ 0.47477E-09 -9.3235 0.39665E-09 -9.4016 0.83544E+00 -0.0781 65 MnO2-2 0.21036E-10 -10.6770 0.10830E-10 -10.9654 0.51484E+00 -0.2883 66 HMnO2- 0.21309E-09 -9.6714 0.17768E-09 -9.7504 0.83382E+00 -0.0789 69 MnCl+ 0.82660E-14 -14.0827 0.69058E-14 -14.1608 0.83544E+00 -0.0781 71 NaCl,aq 0.65358E-06 -6.1847 0.65358E-06 -6.1847 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95179E-02 -2.0215 0.79217E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16798E-14 -14.7747 0.86485E-15 -15.0631 0.51484E+00 -0.2883 81 H2PO3- 0.15427E-18 -18.8117 0.12864E-18 -18.8906 0.83382E+00 -0.0789 82 H3PO4,aq 0.92869E-18 -18.0321 0.92869E-18 -18.0321 0.10000E+01 0.0000 83 H2PO4- 0.40018E-10 -10.3977 0.33400E-10 -10.4763 0.83462E+00 -0.0785 84 PO4-3 0.12125E-08 -8.9163 0.29017E-09 -9.5373 0.23932E+00 -0.6210 88 HP2O7-3 0.10376E-17 -17.9840 0.23643E-18 -18.6263 0.22787E+00 -0.6423 89 P2O7-4 0.10250E-16 -16.9893 0.77030E-18 -18.1133 0.75149E-01 -1.1241 90 H2S,aq 0.49609E-08 -8.3044 0.49432E-08 -8.3060 0.99643E+00 -0.0016 91 S2-2 0.18531E-14 -14.7321 0.95404E-15 -15.0204 0.51484E+00 -0.2883 97 SO3-2 0.11684E-17 -17.9324 0.61044E-18 -18.2144 0.52244E+00 -0.2820 99 HSO4- 0.34561E-19 -19.4614 0.28902E-19 -19.5391 0.83628E+00 -0.0777 Charge balance for all species = -.7325E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9025404E-10 -.2312448E-01 -.2326590E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981190E+06 0.0000 3 Cl- 0.1403202E-03 0.1409740E-03 0.4988907E+01 6.1890 4 SO4-- 0.7972944E-12 -.1522685E-04 -.1460068E+01 7.8558 5 HCO3- 0.2877052E-06 0.1335417E-04 0.8133593E+00 3.5015 6 HS- 0.2605403E-04 0.4128584E-04 0.1362934E+01 5.4578 7 Al+++ 0.1101382E-28 0.5285662E-05 0.1423570E+00 0.7615 8 H4SiO4 0.7112865E-03 0.1419313E-01 0.1361709E+04 -3.1480 9 Ca++ 0.1431699E-06 0.2431919E-06 0.9729006E-02 13.1068 10 Mg++ 0.2273499E-10 0.9785134E-10 0.2374656E-05 9.3056 11 Fe++ 0.6216662E-13 0.3793178E-07 0.2114542E-02 6.7429 12 K+ 0.1614108E-03 0.1621873E-03 0.6330369E+01 6.2505 13 Na+ 0.2052097E-01 0.2311113E-01 0.5303585E+03 8.3540 14 Mn++ 0.1909565E-10 0.2523527E-08 0.1383866E-03 9.2307 15 HPO4-- 0.4875492E-07 0.5000740E-07 0.4790973E-02 12.6423 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3245439E+01 -.2263240E-01 -.3222807E+01 0.0000000E+00 2 H2O 0.5305132E+02 0.5432332E+02 -.1271993E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5457305E-02 -.1490283E-04 0.5472208E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5431800E-02 0.4040730E-04 -.5472208E-02 0.0000000E+00 7 Al+++ 0.6391021E+00 0.5173186E-05 0.6390969E+00 0.0000000E+00 8 H4SiO4 0.2040895E+01 0.1389111E-01 0.2027004E+01 0.0000000E+00 9 Ca++ 0.2254413E+00 0.2380169E-06 0.2254410E+00 0.0000000E+00 10 Mg++ 0.1555548E+00 0.9576911E-10 0.1555548E+00 0.0000000E+00 11 Fe++ 0.1397490E+00 0.3712461E-07 0.1397489E+00 0.0000000E+00 12 K+ 0.4161338E-01 0.1587360E-03 0.4145464E-01 0.0000000E+00 13 Na+ 0.2461866E+00 0.2261933E-01 0.2235672E+00 0.0000000E+00 14 Mn++ 0.3398347E-02 0.2469827E-08 0.3398345E-02 0.0000000E+00 15 HPO4-- 0.1159839E-02 0.4894326E-07 0.1159790E-02 0.0000000E+00 Chg. balance for solid moles: 0.1076E-15 Mass of aqueous solution: 0.980495E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 195.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2233 -0.651 58.55 1.768 27.37 22.48 andradite 0.2189E-01 -1.660 11.12 1.046 5.200 2.890 grossular 0.5236E-02 -2.281 2.359 0.373 1.103 0.6563 apatite-OH 0.3866E-03 -3.413 0.1942 -0.712 0.9078E-01 0.6171E-01 clinochlore 0.2922E-01 -1.534 16.24 1.211 7.592 6.178 daphnite 0.8371E-02 -2.077 5.973 0.776 2.792 1.810 chlorite-Mn 0.6797E-03 -3.168 0.4819 -0.317 0.2252 0.1536 diopside 0.1846E-02 -2.734 0.3997 -0.398 0.1868 0.1222 hedenbergite 0.4726E-03 -3.325 0.1173 -0.931 0.5481E-01 0.3212E-01 microcline 0.3635E-01 -1.439 10.12 1.005 4.730 3.953 stilbite 0.1356 -0.868 95.57 1.980 44.67 44.58 stilpnomelane-Fe 0.1020E-01 -1.991 11.00 1.041 5.142 3.799 tr.625ac.25prg.125 0.2099E-02 -2.678 1.795 0.254 0.8388 0.5776 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8070E+00 0.8070E+00 1.0000 -0.093 grossular 0.1930E+00 0.1930E+00 1.0000 -0.714 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7635E+00 0.7635E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1776E-01 0.1776E-01 1.0000 -1.751 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 213.927529 g Volume = 87.286898 cm3 Porosity: -9.9337% V(tot) - V(min): -.78873E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 195.9990000 g log = 2.2923 Original solution: 1000.0103000 g Original solution / Rock added: 5.10 (Water/Rock Ratio), log = 0.7078 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0868 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9684E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3836E-08 1.0072 0.4199E-08 0.4169E-08 CH4,gas 0.1789E-01 1.0128 0.1969E-01 0.1944E-01 H2,gas 0.1373E-01 1.0006 0.1493E-01 0.1492E-01 H2S,gas 0.1332E-06 0.9958 0.1442E-06 0.1448E-06 S2,gas 0.3215E-29 1.0000 0.3494E-29 0.3494E-29 CO,gas 0.1494E-13 1.0000 0.1623E-13 0.1623E-13 SO3,gas 0.8114E-48 1.0000 0.8818E-48 0.8818E-48 SO2,gas 0.4582E-27 1.0000 0.4979E-27 0.4979E-27 HCl,gas 0.2707E-17 1.0000 0.2942E-17 0.2942E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.97059E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.48529E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.74 -10.38 -3.459 0.17718E+05 -8.377 3 CH4,gas 4.81 1.10 -3.71 -0.926 0.63274E+04 -1.706 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65328E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.421 0.15096E+05 -6.841 6 S2,gas -7.03 -38.49 -31.46 -4.839 0.53711E+05 -29.457 7 CO,gas 3.51 -12.28 -15.79 -4.858 0.26960E+05 -13.790 8 SO3,gas 17.43 -32.63 -50.05 -12.514 0.85467E+05 -48.055 9 SO2,gas 1.14 -28.17 -29.30 -7.814 0.50034E+05 -27.303 10 HCl,gas 5.48 -14.05 -19.53 -9.766 0.33349E+05 -17.531 11 acmite 7.74 6.57 -1.17 -0.121 0.19923E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.77 -4.78 -0.239 0.81595E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94089E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41190E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28372E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76217E+04 35 aragonite 0.99 -3.63 -4.62 -1.540 0.78878E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55852E+04 37 calcite 0.83 -3.63 -4.47 -1.489 0.76265E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52881E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71149E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70308E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82177E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47361E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39553E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.167 0.68640E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70359E+04 52 chloritoid-Mn 11.46 7.61 -3.86 -0.257 0.65865E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13294E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10223E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36447E+04 66 diamond -3.11 -7.82 -4.71 -1.346 0.80440E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.81 -1.97 -0.096 0.33637E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66026E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57722E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68260E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56959E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36649E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70707E+04 86 graphite -3.55 -7.82 -4.27 -1.220 0.72901E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38611E+04 90 hematite 12.60 9.02 -3.57 -0.433 0.61002E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24439E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64135E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59757E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15991E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22956E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58933E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28456E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74529E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48215E+04 112 manganosite 14.07 9.23 -4.84 -1.209 0.82595E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61263E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53648E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41160E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83601E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36591E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20039E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92726E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40648E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.056 0.43395E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64838E+04 144 pyrrhotiteFe0.875 -6.00 -9.44 -3.44 -1.264 0.58666E+04 145 pyroxmangite 7.42 6.08 -1.33 -0.267 0.22766E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84874E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28337E+03 152 rhodonite 7.46 6.08 -1.38 -0.276 0.23558E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27382E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20975E+04 174 tephroite 18.11 15.31 -2.80 -0.400 0.47801E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91066E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76041E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65770E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62269E+04 183 vesuvianite 224.06 219.35 -4.70 -0.036 0.80294E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34499E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66751E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55582E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60368E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66123E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68735E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73629E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60304E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57947E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83196E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61774E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66259E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52978E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.55 -4.59 -1.530 0.78385E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62631E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52612E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18239E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11527E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14888E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18333E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 195.9990000 g New total amount of reactant added: 199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.7147E-13 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 199.9990000 Water: Moles liquid = 0.5430E+02 kg liquid = 0.9783E+00 Moles total = 0.5300E+02 kg total = 0.9548E+00 Activity = 1.0000 Stoichiometric ionic strength = .1172936E-01 Osmotic coef. = 0.9690 True ionic strength = .2068364E-01 Chg. balance for total moles = -.7147E-13 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90254E-10 -10.0445 0.75721E-10 -10.1208 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14038E-03 -3.8527 0.11705E-03 -3.9316 0.83382E+00 -0.0789 4 SO4-- 0.79770E-12 -12.0982 0.41158E-12 -12.3855 0.51596E+00 -0.2874 5 HCO3- 0.28785E-06 -6.5408 0.24037E-06 -6.6191 0.83506E+00 -0.0783 6 HS- 0.26065E-04 -4.5839 0.21737E-04 -4.6628 0.83394E+00 -0.0789 7 Al+++ 0.11014E-28 -28.9581 0.25070E-29 -29.6008 0.22763E+00 -0.6428 8 H4SiO4 0.71129E-03 -3.1480 0.71129E-03 -3.1480 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73316E-07 -7.1348 0.51209E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50970E+00 -0.2927 11 Fe++ 0.62167E-13 -13.2064 0.31722E-13 -13.4986 0.51027E+00 -0.2922 12 K+ 0.16141E-03 -3.7921 0.13482E-03 -3.8702 0.83526E+00 -0.0782 13 Na+ 0.20521E-01 -1.6878 0.17108E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.19113E-10 -10.7187 0.97612E-11 -11.0105 0.51070E+00 -0.2918 15 HPO4-- 0.48755E-07 -7.3120 0.25159E-07 -7.5993 0.51603E+00 -0.2873 16 HSiO3- 0.10992E-01 -1.9589 0.91651E-02 -2.0379 0.83382E+00 -0.0789 17 Ca(HSiO3)+ 0.18020E-07 -7.7442 0.15055E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35447E-11 -11.4504 0.29614E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24902E-02 -2.6038 0.24902E-02 -2.6038 0.10000E+01 0.0000 20 AlO+ 0.67565E-16 -16.1703 0.56447E-16 -16.2484 0.83544E+00 -0.0781 22 HAlO2,aq 0.14918E-09 -9.8263 0.14918E-09 -9.8263 0.10000E+01 0.0000 23 AlO2- 0.52853E-05 -5.2769 0.43989E-05 -5.3567 0.83229E+00 -0.0797 24 CH4,aq 0.12501E-04 -4.9030 0.12457E-04 -4.9046 0.99643E+00 -0.0016 25 C2H6,aq 0.24677E-14 -14.6077 0.24589E-14 -14.6093 0.99643E+00 -0.0016 29 CO,aq 0.10286E-16 -16.9878 0.10286E-16 -16.9878 0.10000E+01 0.0000 30 CO2,aq 0.36829E-10 -10.4338 0.36697E-10 -10.4354 0.99643E+00 -0.0016 31 CO3-2 0.57009E-06 -6.2441 0.29351E-06 -6.5324 0.51484E+00 -0.2883 32 CaCO3,aq 0.26355E-09 -9.5791 0.26355E-09 -9.5791 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53151E-12 -12.2745 0.44405E-12 -12.3526 0.83544E+00 -0.0781 34 CaCl+ 0.16368E-10 -10.7860 0.13675E-10 -10.8641 0.83544E+00 -0.0781 35 CaCl2,aq 0.37268E-15 -15.4287 0.37268E-15 -15.4287 0.10000E+01 0.0000 36 CaOH+ 0.81721E-07 -7.0877 0.68273E-07 -7.1657 0.83544E+00 -0.0781 37 CaSO4,aq 0.94019E-17 -17.0268 0.94019E-17 -17.0268 0.10000E+01 0.0000 38 HCl,aq 0.16671E-14 -14.7780 0.16671E-14 -14.7780 0.10000E+01 0.0000 43 FeCl+ 0.69222E-17 -17.1598 0.57831E-17 -17.2378 0.83544E+00 -0.0781 46 FeO,aq 0.21878E-09 -9.6600 0.21878E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16624E-10 -10.7793 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37271E-07 -7.4286 0.31078E-07 -7.5076 0.83382E+00 -0.0789 49 FeO+ 0.12263E-16 -16.9114 0.10245E-16 -16.9895 0.83544E+00 -0.0781 51 FeO2- 0.42118E-09 -9.3755 0.35119E-09 -9.4545 0.83382E+00 -0.0789 52 HFeO2,aq 0.33281E-11 -11.4778 0.33281E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10922E-04 -4.9617 0.10883E-04 -4.9633 0.99643E+00 -0.0016 54 KCl,aq 0.27942E-09 -9.5537 0.27942E-09 -9.5537 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10253E-14 -14.9892 0.85489E-15 -15.0681 0.83382E+00 -0.0789 58 MgCO3,aq 0.10409E-13 -13.9826 0.10409E-13 -13.9826 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.85666E-16 -16.0672 0.71569E-16 -16.1453 0.83544E+00 -0.0781 60 MgCl+ 0.23486E-14 -14.6292 0.19621E-14 -14.7073 0.83544E+00 -0.0781 61 MgOH+ 0.71558E-10 -10.1453 0.59783E-10 -10.2234 0.83544E+00 -0.0781 63 MnO,aq 0.17972E-08 -8.7454 0.17972E-08 -8.7454 0.10000E+01 0.0000 64 MnOH+ 0.47521E-09 -9.3231 0.39701E-09 -9.4012 0.83544E+00 -0.0781 65 MnO2-2 0.21055E-10 -10.6766 0.10840E-10 -10.9650 0.51484E+00 -0.2883 66 HMnO2- 0.21328E-09 -9.6710 0.17784E-09 -9.7500 0.83382E+00 -0.0789 69 MnCl+ 0.82770E-14 -14.0821 0.69149E-14 -14.1602 0.83544E+00 -0.0781 71 NaCl,aq 0.65385E-06 -6.1845 0.65385E-06 -6.1845 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95179E-02 -2.0215 0.79217E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16798E-14 -14.7747 0.86483E-15 -15.0631 0.51484E+00 -0.2883 81 H2PO3- 0.15427E-18 -18.8117 0.12864E-18 -18.8906 0.83382E+00 -0.0789 82 H3PO4,aq 0.92871E-18 -18.0321 0.92871E-18 -18.0321 0.10000E+01 0.0000 83 H2PO4- 0.40018E-10 -10.3977 0.33400E-10 -10.4763 0.83462E+00 -0.0785 84 PO4-3 0.12125E-08 -8.9163 0.29017E-09 -9.5373 0.23932E+00 -0.6210 88 HP2O7-3 0.10376E-17 -17.9840 0.23644E-18 -18.6263 0.22787E+00 -0.6423 89 P2O7-4 0.10251E-16 -16.9893 0.77031E-18 -18.1133 0.75148E-01 -1.1241 90 H2S,aq 0.49630E-08 -8.3043 0.49452E-08 -8.3058 0.99643E+00 -0.0016 91 S2-2 0.18546E-14 -14.7317 0.95484E-15 -15.0201 0.51484E+00 -0.2883 97 SO3-2 0.11690E-17 -17.9322 0.61073E-18 -18.2141 0.52244E+00 -0.2820 99 HSO4- 0.34578E-19 -19.4612 0.28917E-19 -19.5388 0.83628E+00 -0.0777 Charge balance for all species = -.7382E-13 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9025447E-10 -.2312453E-01 -.2326596E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981190E+06 0.0000 3 Cl- 0.1403778E-03 0.1410319E-03 0.4990956E+01 6.1892 4 SO4-- 0.7976964E-12 -.1523185E-04 -.1460547E+01 7.8560 5 HCO3- 0.2878484E-06 0.1335966E-04 0.8136934E+00 3.5017 6 HS- 0.2606473E-04 0.4130154E-04 0.1363452E+01 5.4580 7 Al+++ 0.1101365E-28 0.5285474E-05 0.1423519E+00 0.7615 8 H4SiO4 0.7112939E-03 0.1419323E-01 0.1361719E+04 -3.1480 9 Ca++ 0.1431699E-06 0.2431916E-06 0.9728993E-02 13.1068 10 Mg++ 0.2273496E-10 0.9785080E-10 0.2374643E-05 9.3056 11 Fe++ 0.6216700E-13 0.3793147E-07 0.2114525E-02 6.7429 12 K+ 0.1614116E-03 0.1621880E-03 0.6330398E+01 6.2505 13 Na+ 0.2052107E-01 0.2311125E-01 0.5303614E+03 8.3540 14 Mn++ 0.1911321E-10 0.2525823E-08 0.1385125E-03 9.2311 15 HPO4-- 0.4875541E-07 0.5000789E-07 0.4791021E-02 12.6423 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3311673E+01 -.2262316E-01 -.3289050E+01 0.0000000E+00 2 H2O 0.5300118E+02 0.5430101E+02 -.1299829E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5568159E-02 -.1490160E-04 0.5583060E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5542654E-02 0.4040607E-04 -.5583060E-02 0.0000000E+00 7 Al+++ 0.6521451E+00 0.5170878E-05 0.6521399E+00 0.0000000E+00 8 H4SiO4 0.2082546E+01 0.1388550E-01 0.2068661E+01 0.0000000E+00 9 Ca++ 0.2300419E+00 0.2379189E-06 0.2300416E+00 0.0000000E+00 10 Mg++ 0.1587294E+00 0.9572926E-10 0.1587294E+00 0.0000000E+00 11 Fe++ 0.1426010E+00 0.3710906E-07 0.1426010E+00 0.0000000E+00 12 K+ 0.4246263E-01 0.1586716E-03 0.4230396E-01 0.0000000E+00 13 Na+ 0.2512075E+00 0.2261017E-01 0.2285974E+00 0.0000000E+00 14 Mn++ 0.3467702E-02 0.2471059E-08 0.3467699E-02 0.0000000E+00 15 HPO4-- 0.1183509E-02 0.4892365E-07 0.1183460E-02 0.0000000E+00 Chg. balance for solid moles: -.6436E-15 Mass of aqueous solution: 0.980093E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2283 -0.641 59.87 1.777 27.43 22.98 andradite 0.2233E-01 -1.651 11.35 1.055 5.199 2.949 grossular 0.5342E-02 -2.272 2.406 0.381 1.102 0.6696 apatite-OH 0.3945E-03 -3.404 0.1982 -0.703 0.9077E-01 0.6297E-01 clinochlore 0.2979E-01 -1.526 16.56 1.219 7.585 6.298 daphnite 0.8534E-02 -2.069 6.089 0.785 2.789 1.845 chlorite-Mn 0.6935E-03 -3.159 0.4917 -0.308 0.2252 0.1567 diopside 0.2077E-02 -2.683 0.4498 -0.347 0.2060 0.1375 hedenbergite 0.5319E-03 -3.274 0.1320 -0.880 0.6045E-01 0.3614E-01 microcline 0.3710E-01 -1.431 10.33 1.014 4.730 4.033 stilbite 0.1382 -0.860 97.38 1.988 44.61 45.42 stilpnomelane-Fe 0.1041E-01 -1.982 11.23 1.050 5.143 3.878 tr.625ac.25prg.125 0.2127E-02 -2.672 1.818 0.260 0.8327 0.5851 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8070E+00 0.8070E+00 1.0000 -0.093 grossular 0.1930E+00 0.1930E+00 1.0000 -0.714 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7635E+00 0.7635E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1778E-01 0.1778E-01 1.0000 -1.750 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 218.297743 g Volume = 89.055152 cm3 Porosity: -9.9452% V(tot) - V(min): -.80556E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 199.9990000 g log = 2.3010 Original solution: 1000.0103000 g Original solution / Rock added: 5.00 (Water/Rock Ratio), log = 0.6990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0868 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9684E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3838E-08 1.0072 0.4201E-08 0.4171E-08 CH4,gas 0.1790E-01 1.0128 0.1970E-01 0.1945E-01 H2,gas 0.1373E-01 1.0006 0.1493E-01 0.1492E-01 H2S,gas 0.1333E-06 0.9958 0.1442E-06 0.1448E-06 S2,gas 0.3218E-29 1.0000 0.3497E-29 0.3497E-29 CO,gas 0.1494E-13 1.0000 0.1624E-13 0.1624E-13 SO3,gas 0.8118E-48 1.0000 0.8822E-48 0.8822E-48 SO2,gas 0.4584E-27 1.0000 0.4982E-27 0.4982E-27 HCl,gas 0.2709E-17 1.0000 0.2944E-17 0.2944E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.48529E-10 67 diopside 16.22 16.22 0.00 0.000 -0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 -0.15165E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.74 -10.38 -3.459 0.17718E+05 -8.377 3 CH4,gas 4.81 1.10 -3.71 -0.926 0.63271E+04 -1.706 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65329E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.420 0.15096E+05 -6.841 6 S2,gas -7.03 -38.49 -31.46 -4.839 0.53711E+05 -29.456 7 CO,gas 3.51 -12.28 -15.79 -4.858 0.26960E+05 -13.789 8 SO3,gas 17.43 -32.63 -50.05 -12.514 0.85467E+05 -48.054 9 SO2,gas 1.14 -28.17 -29.30 -7.814 0.50033E+05 -27.303 10 HCl,gas 5.48 -14.05 -19.53 -9.766 0.33349E+05 -17.531 11 acmite 7.74 6.57 -1.17 -0.121 0.19923E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.77 -4.78 -0.239 0.81575E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94090E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41190E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28372E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76218E+04 35 aragonite 0.99 -3.63 -4.62 -1.540 0.78874E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55852E+04 37 calcite 0.83 -3.63 -4.47 -1.489 0.76261E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52881E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71149E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70308E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82178E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47361E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39554E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.167 0.68640E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70359E+04 52 chloritoid-Mn 11.46 7.61 -3.86 -0.257 0.65858E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13294E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10223E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36447E+04 66 diamond -3.11 -7.82 -4.71 -1.346 0.80436E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.81 -1.97 -0.096 0.33637E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66027E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57722E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68260E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56959E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36649E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70707E+04 86 graphite -3.55 -7.82 -4.27 -1.220 0.72898E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38611E+04 90 hematite 12.60 9.02 -3.57 -0.433 0.61002E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24439E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64135E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59757E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15991E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22957E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58933E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28456E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74529E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48214E+04 112 manganosite 14.07 9.23 -4.84 -1.209 0.82588E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61263E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53648E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41160E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83601E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36591E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20039E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92727E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40649E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.056 0.43396E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64834E+04 144 pyrrhotiteFe0.875 -6.00 -9.44 -3.44 -1.264 0.58663E+04 145 pyroxmangite 7.42 6.08 -1.33 -0.267 0.22759E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84874E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28336E+03 152 rhodonite 7.46 6.08 -1.38 -0.276 0.23551E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27382E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20975E+04 174 tephroite 18.11 15.31 -2.80 -0.400 0.47787E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91065E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76041E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65770E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62266E+04 183 vesuvianite 224.06 219.35 -4.70 -0.036 0.80296E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34499E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66752E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55582E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60367E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66123E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68736E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73629E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60304E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57947E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83195E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61773E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66259E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52978E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.55 -4.59 -1.530 0.78375E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62632E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52612E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18239E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11527E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14888E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18333E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 4.0000000 g Current total amount of reactant added: 199.9990000 g New total amount of reactant added: 203.9990000 g Mixing fraction reached given limit of 0.2000E+03 TOTMIX = 0.2040E+03 Execution stopped.