File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.33117E+01 0.90254E-10 0.8390 0.00000000E+00 H2O 2 0. 0.53001E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.14038E-03 0.8338 0.00000000E+00 SO4-- 4 -2. 0.55682E-02 0.79770E-12 0.5160 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.28785E-06 0.8351 0.00000000E+00 HS- 6 -1. -0.55427E-02 0.26065E-04 0.8339 0.00000000E+00 Al+++ 7 3. 0.65215E+00 0.11014E-28 0.2276 0.00000000E+00 H4SiO4 8 0. 0.20825E+01 0.71129E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.23004E+00 0.14317E-06 0.5121 0.00000000E+00 Mg++ 10 2. 0.15873E+00 0.22735E-10 0.5097 0.00000000E+00 Fe++ 11 2. 0.14260E+00 0.62167E-13 0.5103 0.00000000E+00 K+ 12 1. 0.42463E-01 0.16141E-03 0.8353 0.00000000E+00 Na+ 13 1. 0.25121E+00 0.20521E-01 0.8337 0.00000000E+00 Mn++ 14 2. 0.34677E-02 0.19113E-10 0.5107 0.00000000E+00 HPO4-- 15 -2. 0.11835E-02 0.48755E-07 0.5160 0.00000000E+00 Chg. balance for total moles = 0.3650E-11 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 100.0000 SLIM = 0.400000E+03 TEMP = 100.0000 SINC = 0.1000E+02 TEMPC = 0.0000 TOTMIX = 0.199999E+03 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 80.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0107 MnO2-2 65 -2. 40.4376 Ca(HSiO3)+ 17 1. 7.6603 HMnO2- 66 -1. 29.1018 Mg(HSiO3)+ 18 1. 7.5653 MnO4- 67 -1. 83.3383 NaHSiO3,aq 19 0. 7.8098 MnO4-2 68 -2. 81.3024 AlO+ 20 1. 6.8891 MnCl+ 69 1. -0.7819 AlOH+2 21 2. 3.1893 MnSO4,aq 70 0. -2.4524 HAlO2,aq 22 0. 10.5878 NaCl,aq 71 0. 0.4861 AlO2- 23 -1. 16.2390 NaOH,aq 72 0. 12.3571 CH4,aq 24 0. 6.0082 O2,aq 73 0. 53.5759 C2H6,aq 25 0. 12.3556 OH- 74 -1. 12.2220 C3H8,aq 26 0. 17.3423 HO2- 75 -1. 50.7897 C4H10,aq 27 0. 22.3397 H2O2,aq 76 0. 40.0297 ethanol,aq 28 0. 15.3114 H3PO2,aq 77 0. 24.3310 CO,aq 29 0. 4.7087 H2PO2- 78 -1. 26.5491 CO2,aq 30 0. -6.3045 HPO3-2 79 -2. 11.9246 CO3-2 31 -2. 10.0340 H3PO3,aq 80 0. 3.5932 CaCO3,aq 32 0. 5.9460 H2PO3- 81 -1. 5.6314 Ca(HCO3)+ 33 1. -1.4013 H3PO4,aq 82 0. -9.8087 CaCl+ 34 1. -0.2023 H2PO4- 83 -1. -7.2438 CaCl2,aq 35 0. 0.4306 PO4-3 84 -3. 12.0588 CaOH+ 36 1. 10.1517 H4P2O7,aq 85 0. -17.7539 CaSO4,aq 37 0. -2.4936 H3P2O7- 86 -1. -15.8646 HCl,aq 38 0. 0.7256 H2P2O7-2 87 -2. -13.3812 HClO,aq 39 0. 32.4377 HP2O7-3 88 -3. -6.6931 ClO- 40 -1. 39.6416 P2O7-4 89 -4. 2.9147 HClO2,aq 41 0. 70.2060 H2S,aq 90 0. -6.4778 Fe+3 42 3. 8.3763 S2-2 91 -2. 1.2336 FeCl+ 43 1. -0.1924 S3-2 92 -2. -8.7963 FeCl2,aq 44 0. 4.3160 S3- 93 -1. -16.3178 FeCl+2 45 2. 6.5223 S4-2 94 -2. -18.6473 FeO,aq 46 0. 16.4029 S5-2 95 -2. -28.3223 FeOH+ 47 1. 7.4795 SO2,aq 96 0. -0.1980 HFeO2- 48 -1. 24.3713 SO3-2 97 -2. 10.2895 FeO+ 49 1. 11.3812 HSO3- 98 -1. 2.5222 FeOH+2 50 2. 9.1115 HSO4- 99 -1. -2.9675 FeO2- 51 -1. 24.0877 HSO5- 100 -1. 38.8657 HFeO2,aq 52 0. 15.9903 S2O3-2 101 -2. -4.5491 H2,aq 53 0. 9.4241 HS2O3- 102 -1. -6.8007 KCl,aq 54 0. 1.7519 H2S2O3,aq 103 0. -7.9944 KHSO4,aq 55 0. -0.4275 S2O4-2 104 -2. 10.5639 KOH,aq 56 0. 12.3606 HS2O4- 105 -1. 7.6762 KSO4- 57 -1. -1.1877 H2S2O4,aq 106 0. 6.6566 MgCO3,aq 58 0. 6.5483 S2O5-2 107 -2. 10.0891 Mg(HCO3)+ 59 1. -1.4098 S2O6-2 108 -2. 11.5737 MgCl+ 60 1. -0.1603 S2O8-2 109 -2. 42.1139 MgOH+ 61 1. 9.4082 S3O6-2 110 -2. 3.8101 Mn+3 62 3. 19.1332 S4O6-2 111 -2. -17.8301 MnO,aq 63 0. 17.9765 S5O6-2 112 -2. -14.1051 MnOH+ 64 1. 8.5115 113 0. 10.3157 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.984 0.0000E+00 osumilite(2) 124 20.895 0.0000E+00 CO2,gas 2 -6.363 0.0000E+00 osumilite-Fe 125 14.657 0.0000E+00 CH4,gas 3 4.809 0.0000E+00 pargasite 126 65.279 0.0000E+00 H2,gas 4 8.287 0.0000E+00 periclase 127 16.149 0.0000E+00 H2S,gas 5 -5.943 0.0000E+00 periclase-Fe 128 11.639 0.0000E+00 S2,gas 6 -7.033 0.0000E+00 perovskite-Al 129 12.395 0.0000E+00 CO,gas 7 3.510 0.0000E+00 perovskite-Ca 130 23.818 0.0000E+00 SO3,gas 8 17.427 0.0000E+00 perovskite-Fe 131 21.158 0.0000E+00 SO2,gas 9 1.136 0.0000E+00 perovskite-Mg 132 23.132 0.0000E+00 HCl,gas 10 5.479 0.0000E+00 phase_A 133 80.267 0.0000E+00 acmite 11 7.737 0.0000E+00 phlogopite-Na 134 29.731 0.0000E+00 akermanite 12 36.495 0.0000E+00 piemontite(ordered) 135 33.876 0.0000E+00 akimotoite 13 16.606 0.0000E+00 prehnite 136 19.466 0.0000E+00 akimotoite-Fe 14 13.083 0.0000E+00 prehnite-Fe 137 22.587 0.0000E+00 albite-high 15 0.750 0.0000E+00 pumpellyite-Fe 138 46.471 0.0000E+00 albite 16 -0.328 0.2283E+00 pumpellyite-Mg 139 49.194 0.0000E+00 almandine 17 24.545 0.0000E+00 px-Mg-tschermaks 140 19.687 0.0000E+00 pyrope 18 37.348 0.0000E+00 px-Ca-tschermaks 141 18.679 0.0000E+00 spessartine 19 24.550 0.0000E+00 pyrite 142 -21.225 0.0000E+00 analcite 20 3.371 0.0000E+00 pyrrhotite 143 -4.244 0.0000E+00 andalusite 21 5.062 0.0000E+00 pyrrhotiteFe0.875 144 -6.001 0.0000E+00 andradite 22 39.088 0.2233E-01 pyroxmangite 145 7.416 0.0000E+00 grossular 23 32.828 0.5342E-02 pyrophyllite 146 -6.098 0.0000E+00 anhydrite 24 -5.280 0.0000E+00 quartz 147 -2.982 0.0000E+00 ankerite 25 -2.093 0.0000E+00 rankinite 148 40.765 0.0000E+00 annite 26 20.209 0.0000E+00 ringwoodite-Fe 149 15.486 0.0000E+00 phlogopite 27 27.147 0.0000E+00 ringwoodite-Mg 150 27.602 0.0000E+00 biotite-Mn 28 33.034 0.0000E+00 rhodochrosite 151 -0.959 0.0000E+00 anorthite 29 12.798 0.0000E+00 rhodonite 152 7.462 0.0000E+00 anthophyllite 30 51.988 0.0000E+00 sanidine 153 -1.221 0.0000E+00 anthophyllite-Fe 31 29.455 0.0000E+00 sapphirine(351) 154 79.204 0.0000E+00 apatite-OH 32 -17.989 0.3945E-03 siderite 155 -2.588 0.0000E+00 apatite-OH-zs 33 -12.572 0.0000E+00 sillimanite 156 5.321 0.0000E+00 apatite-Cl-zs 34 -16.504 0.0000E+00 sodalite 157 50.255 0.0000E+00 aragonite 35 0.986 0.0000E+00 spinel 158 20.934 0.0000E+00 brucite 36 12.577 0.0000E+00 spurrite 159 59.566 0.0000E+00 calcite 37 0.833 0.0000E+00 staurolite-Fe 160 74.138 0.0000E+00 carnegieite-low 38 9.065 0.0000E+00 staurolite-Mg 161 90.336 0.0000E+00 carnegieite-high 39 10.134 0.0000E+00 staurolite-Mn 162 84.438 0.0000E+00 carpholite-Mg 40 8.650 0.0000E+00 stilbite 163 -7.406 0.1382E+00 carpholite-Fe 41 6.783 0.0000E+00 stilpnomelane-Fe 164 13.179 0.1041E-01 celadonite 42 5.401 0.0000E+00 stilpnomelane-Mg 165 27.596 0.0000E+00 celadonite-Fe 43 3.937 0.0000E+00 stishovite 166 2.721 0.0000E+00 chrysotile 44 23.937 0.0000E+00 sudoite-Fe 167 18.437 0.0000E+00 chondrodite 45 56.542 0.0000E+00 sudoite 168 21.216 0.0000E+00 clinochlore 46 39.193 0.2979E-01 sulfur 169 -9.141 0.0000E+00 daphnite 47 29.094 0.8534E-02 sylvite 170 1.345 0.0000E+00 chlorite-Mn 48 46.985 0.6935E-03 talc 171 16.553 0.0000E+00 chlorite-Al-free 49 47.262 0.0000E+00 talc-Fe 172 13.516 0.0000E+00 chloritoid-Mg 50 13.261 0.0000E+00 talc-tschermaks 173 19.189 0.0000E+00 chloritoid-Fe 51 9.239 0.0000E+00 tephroite 174 18.113 0.0000E+00 chloritoid-Mn 52 11.463 0.0000E+00 tilleyite 175 41.473 0.0000E+00 clinohumite 53 97.255 0.0000E+00 titanite-CaSi 176 15.497 0.0000E+00 coesite 54 -2.369 0.0000E+00 topaz-H 177 4.668 0.0000E+00 cordierite-H 55 23.898 0.0000E+00 tridymite 178 -2.615 0.0000E+00 cordierite 56 24.245 0.0000E+00 tremolite 179 48.003 0.0000E+00 cordierite-Fe 57 20.649 0.0000E+00 ferroactinolite 180 38.596 0.0000E+00 cordierite-Mn 58 25.261 0.0000E+00 troilite-low 181 -4.394 0.0000E+00 corundum 59 8.433 0.0000E+00 tschermakite 182 48.414 0.0000E+00 corundum-MgSi 60 18.905 0.0000E+00 vesuvianite 183 224.056 0.0000E+00 cristobalite 61 -2.549 0.0000E+00 wadeite-Si 184 20.233 0.0000E+00 cummingtonite 62 52.233 0.0000E+00 wadsleyite-Fe 185 15.711 0.0000E+00 cymrite-K 63 1.731 0.0000E+00 wadsleyite-Mg 186 25.878 0.0000E+00 deerite 64 95.982 0.0000E+00 wairakite 187 4.058 0.0000E+00 diaspore 65 2.896 0.0000E+00 walstromite 188 11.528 0.0000E+00 diamond 66 -3.107 0.0000E+00 wollastonite 189 10.482 0.0000E+00 diopside 67 16.215 0.2077E-02 pseudo-wollastonite 190 11.020 0.0000E+00 hedenbergite 68 14.244 0.5319E-03 zoisite 191 22.964 0.0000E+00 dolomite,ordered 69 0.587 0.0000E+00 akaganeite 192 7.768 0.0000E+00 eastonite 70 28.605 0.0000E+00 beidellite-Ca 193 -1.560 0.0000E+00 enstatite 71 17.301 0.0000E+00 beidellite-H 194 -2.241 0.0000E+00 clinoenstatite-HiP 72 18.388 0.0000E+00 beidellite-K 195 -1.435 0.0000E+00 clinoenstatite 73 17.202 0.0000E+00 beidellite-Mg 196 -1.707 0.0000E+00 protoenstatite 74 17.860 0.0000E+00 beidellite-Na 197 -1.257 0.0000E+00 epidote 75 24.775 0.0000E+00 calcium 198 84.043 0.0000E+00 clinozoisite 76 22.921 0.0000E+00 chalcedony 199 -2.794 0.0000E+00 epidote-Fe 77 29.937 0.0000E+00 dawsonite 200 1.714 0.0000E+00 fayalite 78 14.079 0.0000E+00 montmorillonite-Ca 201 -2.214 0.0000E+00 ferrosilite 79 11.188 0.0000E+00 montmorillonite-K 202 -2.161 0.0000E+00 forsterite 80 21.047 0.0000E+00 montmorillonite-Mg 203 -2.402 0.0000E+00 gedrite 81 50.725 0.0000E+00 montmorillonite-Na 204 -1.961 0.0000E+00 gehlenite 82 36.717 0.0000E+00 nontronite-Ca 205 3.280 0.0000E+00 gibbsite 83 4.097 0.0000E+00 nontronite-H 206 2.596 0.0000E+00 glaucophane 84 23.111 0.0000E+00 nontronite-K 207 3.404 0.0000E+00 glaucophane-Fe 85 17.417 0.0000E+00 nontronite-Mg 208 3.139 0.0000E+00 graphite 86 -3.549 0.0000E+00 nontronite-Na 209 3.583 0.0000E+00 greenalite 87 16.194 0.0000E+00 sepiolite 210 24.194 0.0000E+00 grunerite 88 31.364 0.0000E+00 alite 211 58.043 0.0000E+00 halite 89 1.582 0.0000E+00 belite 212 30.461 0.0000E+00 hematite 90 12.598 0.0000E+00 ettringite 213 43.354 0.0000E+00 heulandite 91 -5.707 0.0000E+00 gypsum 214 -4.924 0.0000E+00 hercynite 92 17.345 0.0000E+00 hemicarboaluminate 215 71.028 0.0000E+00 hollandite 93 25.702 0.0000E+00 hydrogarnet 216 60.721 0.0000E+00 iron 94 19.095 0.0000E+00 hydrogarnet-Si 217 50.654 0.0000E+00 jadeite 95 4.251 0.0000E+00 jennite 218 24.386 0.0000E+00 julgoldite 96 70.573 0.0000E+00 monosulfoaluminate 219 53.497 0.0000E+00 kalsilite 97 7.620 0.0000E+00 monocarboaluminate 220 61.966 0.0000E+00 kaolinite 98 -1.273 0.0000E+00 portlandite 221 18.282 0.0000E+00 kyanite 99 4.932 0.0000E+00 stratlingite 222 36.573 0.0000E+00 larnite-bredigite 100 30.714 0.0000E+00 tricarboaluminate 223 70.427 0.0000E+00 laumontite 101 2.975 0.0000E+00 tobermorite 224 9.839 0.0000E+00 lawsonite 102 9.678 0.0000E+00 C4AH13 225 81.870 0.0000E+00 leucite 103 4.168 0.0000E+00 C2AH8 226 45.260 0.0000E+00 lime 104 26.009 0.0000E+00 C3A 227 87.049 0.0000E+00 lizardite 105 23.287 0.0000E+00 C4AF 228 117.550 0.0000E+00 magnesite 106 0.709 0.0000E+00 CAH10 229 28.373 0.0000E+00 magnetite 107 20.133 0.0000E+00 alabandite 230 -0.962 0.0000E+00 minnesotaite 108 10.461 0.0000E+00 alunite 231 -10.224 0.0000E+00 minnesotaite-Mg 109 20.669 0.0000E+00 artinite 232 15.139 0.0000E+00 magnesioferrite 110 26.257 0.0000E+00 boehmite 233 4.430 0.0000E+00 majorite 111 53.314 0.0000E+00 dolomite,disordered 234 1.288 0.0000E+00 manganosite 112 14.068 0.0000E+00 ferrous-oxide 235 9.824 0.0000E+00 margarite 113 17.452 0.0000E+00 huntite 236 3.850 0.0000E+00 meionite 114 45.158 0.0000E+00 hydromagnesite 237 20.077 0.0000E+00 merwinite 115 55.988 0.0000E+00 nesquehonite 238 4.735 0.0000E+00 microcline 116 -2.432 0.3710E-01 potassium-oxide 239 69.039 0.0000E+00 monticellite 117 24.371 0.0000E+00 silica-amorphous 240 -2.080 0.0000E+00 mullite-Al 118 363.258 0.0000E+00 sodium-oxide 241 55.173 0.0000E+00 mullite-Si 119 7.324 0.0000E+00 an20ab80 242 2.079 0.0000E+00 muscovite 120 2.679 0.0000E+00 an25ab75 243 2.709 0.0000E+00 paragonite 121 4.337 0.0000E+00 an30ab70 244 3.344 0.0000E+00 nepheline 122 8.378 0.0000E+00 tr.625ac.25prg.125 245 45.308 0.2127E-02 osumilite(1) 123 21.978 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 199.9990000 g log = 2.3010 Original solution: 1000.0103000 g Original solution / Rock added: 5.00 (Water/Rock Ratio), log = 0.6990 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 199.9990000 Water: Moles liquid = 0.5430E+02 kg liquid = 0.9783E+00 Moles total = 0.5300E+02 kg total = 0.9548E+00 Activity = 1.0000 Stoichiometric ionic strength = .1172936E-01 Osmotic coef. = 0.9690 True ionic strength = .2068364E-01 Chg. balance for total moles = 0.3650E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90254E-10 -10.0445 0.75721E-10 -10.1208 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14038E-03 -3.8527 0.11705E-03 -3.9316 0.83382E+00 -0.0789 4 SO4-- 0.79770E-12 -12.0982 0.41158E-12 -12.3855 0.51596E+00 -0.2874 5 HCO3- 0.28785E-06 -6.5408 0.24037E-06 -6.6191 0.83506E+00 -0.0783 6 HS- 0.26065E-04 -4.5839 0.21737E-04 -4.6628 0.83394E+00 -0.0789 7 Al+++ 0.11014E-28 -28.9581 0.25070E-29 -29.6008 0.22763E+00 -0.6428 8 H4SiO4 0.71129E-03 -3.1480 0.71129E-03 -3.1480 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73316E-07 -7.1348 0.51209E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50970E+00 -0.2927 11 Fe++ 0.62167E-13 -13.2064 0.31722E-13 -13.4986 0.51027E+00 -0.2922 12 K+ 0.16141E-03 -3.7921 0.13482E-03 -3.8702 0.83526E+00 -0.0782 13 Na+ 0.20521E-01 -1.6878 0.17108E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.19113E-10 -10.7187 0.97612E-11 -11.0105 0.51070E+00 -0.2918 15 HPO4-- 0.48755E-07 -7.3120 0.25159E-07 -7.5993 0.51603E+00 -0.2873 16 HSiO3- 0.10992E-01 -1.9589 0.91651E-02 -2.0379 0.83382E+00 -0.0789 17 Ca(HSiO3)+ 0.18020E-07 -7.7442 0.15055E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35447E-11 -11.4504 0.29614E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24902E-02 -2.6038 0.24902E-02 -2.6038 0.10000E+01 0.0000 20 AlO+ 0.67565E-16 -16.1703 0.56447E-16 -16.2484 0.83544E+00 -0.0781 22 HAlO2,aq 0.14918E-09 -9.8263 0.14918E-09 -9.8263 0.10000E+01 0.0000 23 AlO2- 0.52853E-05 -5.2769 0.43989E-05 -5.3567 0.83229E+00 -0.0797 24 CH4,aq 0.12501E-04 -4.9030 0.12457E-04 -4.9046 0.99643E+00 -0.0016 25 C2H6,aq 0.24677E-14 -14.6077 0.24589E-14 -14.6093 0.99643E+00 -0.0016 29 CO,aq 0.10286E-16 -16.9878 0.10286E-16 -16.9878 0.10000E+01 0.0000 30 CO2,aq 0.36829E-10 -10.4338 0.36697E-10 -10.4354 0.99643E+00 -0.0016 31 CO3-2 0.57009E-06 -6.2441 0.29351E-06 -6.5324 0.51484E+00 -0.2883 32 CaCO3,aq 0.26355E-09 -9.5791 0.26355E-09 -9.5791 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53151E-12 -12.2745 0.44405E-12 -12.3526 0.83544E+00 -0.0781 34 CaCl+ 0.16368E-10 -10.7860 0.13675E-10 -10.8641 0.83544E+00 -0.0781 35 CaCl2,aq 0.37268E-15 -15.4287 0.37268E-15 -15.4287 0.10000E+01 0.0000 36 CaOH+ 0.81721E-07 -7.0877 0.68273E-07 -7.1657 0.83544E+00 -0.0781 37 CaSO4,aq 0.94019E-17 -17.0268 0.94019E-17 -17.0268 0.10000E+01 0.0000 38 HCl,aq 0.16671E-14 -14.7780 0.16671E-14 -14.7780 0.10000E+01 0.0000 43 FeCl+ 0.69222E-17 -17.1598 0.57831E-17 -17.2378 0.83544E+00 -0.0781 46 FeO,aq 0.21878E-09 -9.6600 0.21878E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16624E-10 -10.7793 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37271E-07 -7.4286 0.31078E-07 -7.5076 0.83382E+00 -0.0789 49 FeO+ 0.12263E-16 -16.9114 0.10245E-16 -16.9895 0.83544E+00 -0.0781 51 FeO2- 0.42118E-09 -9.3755 0.35119E-09 -9.4545 0.83382E+00 -0.0789 52 HFeO2,aq 0.33281E-11 -11.4778 0.33281E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10922E-04 -4.9617 0.10883E-04 -4.9633 0.99643E+00 -0.0016 54 KCl,aq 0.27942E-09 -9.5537 0.27942E-09 -9.5537 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10253E-14 -14.9892 0.85489E-15 -15.0681 0.83382E+00 -0.0789 58 MgCO3,aq 0.10409E-13 -13.9826 0.10409E-13 -13.9826 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.85666E-16 -16.0672 0.71569E-16 -16.1453 0.83544E+00 -0.0781 60 MgCl+ 0.23486E-14 -14.6292 0.19621E-14 -14.7073 0.83544E+00 -0.0781 61 MgOH+ 0.71558E-10 -10.1453 0.59783E-10 -10.2234 0.83544E+00 -0.0781 63 MnO,aq 0.17972E-08 -8.7454 0.17972E-08 -8.7454 0.10000E+01 0.0000 64 MnOH+ 0.47521E-09 -9.3231 0.39701E-09 -9.4012 0.83544E+00 -0.0781 65 MnO2-2 0.21055E-10 -10.6766 0.10840E-10 -10.9650 0.51484E+00 -0.2883 66 HMnO2- 0.21328E-09 -9.6710 0.17784E-09 -9.7500 0.83382E+00 -0.0789 69 MnCl+ 0.82770E-14 -14.0821 0.69149E-14 -14.1602 0.83544E+00 -0.0781 71 NaCl,aq 0.65385E-06 -6.1845 0.65385E-06 -6.1845 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95179E-02 -2.0215 0.79217E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16798E-14 -14.7747 0.86483E-15 -15.0631 0.51484E+00 -0.2883 81 H2PO3- 0.15427E-18 -18.8117 0.12864E-18 -18.8906 0.83382E+00 -0.0789 82 H3PO4,aq 0.92871E-18 -18.0321 0.92871E-18 -18.0321 0.10000E+01 0.0000 83 H2PO4- 0.40018E-10 -10.3977 0.33400E-10 -10.4763 0.83462E+00 -0.0785 84 PO4-3 0.12125E-08 -8.9163 0.29017E-09 -9.5373 0.23932E+00 -0.6210 88 HP2O7-3 0.10376E-17 -17.9840 0.23644E-18 -18.6263 0.22787E+00 -0.6423 89 P2O7-4 0.10251E-16 -16.9893 0.77031E-18 -18.1133 0.75148E-01 -1.1241 90 H2S,aq 0.49630E-08 -8.3043 0.49452E-08 -8.3058 0.99643E+00 -0.0016 91 S2-2 0.18546E-14 -14.7317 0.95484E-15 -15.0201 0.51484E+00 -0.2883 97 SO3-2 0.11690E-17 -17.9322 0.61073E-18 -18.2141 0.52244E+00 -0.2820 99 HSO4- 0.34578E-19 -19.4612 0.28917E-19 -19.5388 0.83628E+00 -0.0777 Charge balance for all species = 0.3729E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9025447E-10 -.2312453E-01 -.2326596E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981190E+06 0.0000 3 Cl- 0.1403778E-03 0.1410319E-03 0.4990956E+01 6.1892 4 SO4-- 0.7976964E-12 -.1523185E-04 -.1460547E+01 7.8560 5 HCO3- 0.2878484E-06 0.1335966E-04 0.8136934E+00 3.5017 6 HS- 0.2606473E-04 0.4130154E-04 0.1363452E+01 5.4580 7 Al+++ 0.1101365E-28 0.5285474E-05 0.1423519E+00 0.7615 8 H4SiO4 0.7112939E-03 0.1419323E-01 0.1361719E+04 -3.1480 9 Ca++ 0.1431699E-06 0.2431916E-06 0.9728993E-02 13.1068 10 Mg++ 0.2273496E-10 0.9785080E-10 0.2374643E-05 9.3056 11 Fe++ 0.6216700E-13 0.3793147E-07 0.2114525E-02 6.7429 12 K+ 0.1614116E-03 0.1621880E-03 0.6330398E+01 6.2505 13 Na+ 0.2052107E-01 0.2311125E-01 0.5303614E+03 8.3540 14 Mn++ 0.1911321E-10 0.2525823E-08 0.1385125E-03 9.2311 15 HPO4-- 0.4875541E-07 0.5000789E-07 0.4791021E-02 12.6423 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3311673E+01 -.2262316E-01 -.3289050E+01 0.0000000E+00 2 H2O 0.5300118E+02 0.5430101E+02 -.1299829E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5568159E-02 -.1490160E-04 0.5583060E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5542654E-02 0.4040607E-04 -.5583060E-02 0.0000000E+00 7 Al+++ 0.6521451E+00 0.5170878E-05 0.6521399E+00 0.0000000E+00 8 H4SiO4 0.2082546E+01 0.1388550E-01 0.2068661E+01 0.0000000E+00 9 Ca++ 0.2300419E+00 0.2379189E-06 0.2300416E+00 0.0000000E+00 10 Mg++ 0.1587294E+00 0.9572926E-10 0.1587294E+00 0.0000000E+00 11 Fe++ 0.1426010E+00 0.3710906E-07 0.1426010E+00 0.0000000E+00 12 K+ 0.4246263E-01 0.1586716E-03 0.4230396E-01 0.0000000E+00 13 Na+ 0.2512075E+00 0.2261017E-01 0.2285974E+00 0.0000000E+00 14 Mn++ 0.3467702E-02 0.2471059E-08 0.3467699E-02 0.0000000E+00 15 HPO4-- 0.1183509E-02 0.4892365E-07 0.1183460E-02 0.0000000E+00 Chg. balance for solid moles: -.5768E-16 Mass of aqueous solution: 0.980093E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2283 -0.641 59.87 1.777 27.43 22.98 andradite 0.2233E-01 -1.651 11.35 1.055 5.199 2.949 grossular 0.5342E-02 -2.272 2.406 0.381 1.102 0.6696 apatite-OH 0.3945E-03 -3.404 0.1982 -0.703 0.9077E-01 0.6297E-01 clinochlore 0.2979E-01 -1.526 16.56 1.219 7.585 6.298 daphnite 0.8534E-02 -2.069 6.089 0.785 2.789 1.845 chlorite-Mn 0.6935E-03 -3.159 0.4917 -0.308 0.2252 0.1567 diopside 0.2077E-02 -2.683 0.4498 -0.347 0.2060 0.1375 hedenbergite 0.5319E-03 -3.274 0.1320 -0.880 0.6045E-01 0.3614E-01 microcline 0.3710E-01 -1.431 10.33 1.014 4.730 4.033 stilbite 0.1382 -0.860 97.38 1.988 44.61 45.42 stilpnomelane-Fe 0.1041E-01 -1.982 11.23 1.050 5.143 3.878 tr.625ac.25prg.125 0.2127E-02 -2.672 1.818 0.260 0.8327 0.5851 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8070E+00 0.8070E+00 1.0000 -0.093 grossular 0.1930E+00 0.1930E+00 1.0000 -0.714 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7635E+00 0.7635E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1778E-01 0.1778E-01 1.0000 -1.750 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 218.297743 g Volume = 89.055152 cm3 Porosity: -9.9452% V(tot) - V(min): -.80556E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 199.9990000 g log = 2.3010 Original solution: 1000.0103000 g Original solution / Rock added: 5.00 (Water/Rock Ratio), log = 0.6990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0868 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9684E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3838E-08 1.0072 0.4201E-08 0.4171E-08 CH4,gas 0.1790E-01 1.0128 0.1970E-01 0.1945E-01 H2,gas 0.1373E-01 1.0006 0.1493E-01 0.1492E-01 H2S,gas 0.1333E-06 0.9958 0.1442E-06 0.1448E-06 S2,gas 0.3218E-29 1.0000 0.3497E-29 0.3497E-29 CO,gas 0.1494E-13 1.0000 0.1624E-13 0.1624E-13 SO3,gas 0.8118E-48 1.0000 0.8822E-48 0.8822E-48 SO2,gas 0.4584E-27 1.0000 0.4982E-27 0.4982E-27 HCl,gas 0.2709E-17 1.0000 0.2944E-17 0.2944E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.74 -10.38 -3.459 0.17718E+05 -8.377 3 CH4,gas 4.81 1.10 -3.71 -0.926 0.63271E+04 -1.706 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65329E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.420 0.15096E+05 -6.841 6 S2,gas -7.03 -38.49 -31.46 -4.839 0.53711E+05 -29.456 7 CO,gas 3.51 -12.28 -15.79 -4.858 0.26960E+05 -13.789 8 SO3,gas 17.43 -32.63 -50.05 -12.514 0.85467E+05 -48.054 9 SO2,gas 1.14 -28.17 -29.30 -7.814 0.50033E+05 -27.303 10 HCl,gas 5.48 -14.05 -19.53 -9.766 0.33349E+05 -17.531 11 acmite 7.74 6.57 -1.17 -0.121 0.19923E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.77 -4.78 -0.239 0.81575E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94090E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41190E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28372E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76218E+04 35 aragonite 0.99 -3.63 -4.62 -1.540 0.78874E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55852E+04 37 calcite 0.83 -3.63 -4.47 -1.489 0.76261E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52881E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71149E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70308E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82178E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47361E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39554E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.167 0.68640E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70359E+04 52 chloritoid-Mn 11.46 7.61 -3.86 -0.257 0.65858E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13294E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10223E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36447E+04 66 diamond -3.11 -7.82 -4.71 -1.346 0.80436E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.81 -1.97 -0.096 0.33637E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66027E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57722E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68260E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56959E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36649E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70707E+04 86 graphite -3.55 -7.82 -4.27 -1.220 0.72898E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38611E+04 90 hematite 12.60 9.02 -3.57 -0.433 0.61002E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24439E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64135E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59757E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15991E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22957E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58933E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28456E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74529E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48214E+04 112 manganosite 14.07 9.23 -4.84 -1.209 0.82588E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61263E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53648E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41160E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83601E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36591E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20039E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92727E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40649E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.056 0.43396E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64834E+04 144 pyrrhotiteFe0.875 -6.00 -9.44 -3.44 -1.264 0.58663E+04 145 pyroxmangite 7.42 6.08 -1.33 -0.267 0.22759E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84874E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28336E+03 152 rhodonite 7.46 6.08 -1.38 -0.276 0.23551E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27382E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20975E+04 174 tephroite 18.11 15.31 -2.80 -0.400 0.47787E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91065E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76041E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65770E+04 181 troilite-low -4.39 -8.04 -3.65 -1.216 0.62266E+04 183 vesuvianite 224.06 219.35 -4.70 -0.036 0.80296E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34499E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66752E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55582E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60367E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66123E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68736E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73629E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60304E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57947E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83195E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61773E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66259E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52978E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.55 -4.59 -1.530 0.78375E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62632E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52612E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18239E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11527E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14888E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18333E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 199.9990000 g New total amount of reactant added: 209.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3650E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 209.9990000 Water: Moles liquid = 0.5425E+02 kg liquid = 0.9773E+00 Moles total = 0.5288E+02 kg total = 0.9526E+00 Activity = 1.0000 Stoichiometric ionic strength = .1172958E-01 Osmotic coef. = 0.9690 True ionic strength = .2068387E-01 Chg. balance for total moles = 0.3650E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90256E-10 -10.0445 0.75722E-10 -10.1208 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14052E-03 -3.8523 0.11717E-03 -3.9312 0.83382E+00 -0.0789 4 SO4-- 0.79869E-12 -12.0976 0.41209E-12 -12.3850 0.51596E+00 -0.2874 5 HCO3- 0.28820E-06 -6.5403 0.24067E-06 -6.6186 0.83506E+00 -0.0783 6 HS- 0.26092E-04 -4.5835 0.21759E-04 -4.6624 0.83394E+00 -0.0789 7 Al+++ 0.11013E-28 -28.9581 0.25069E-29 -29.6009 0.22763E+00 -0.6428 8 H4SiO4 0.71131E-03 -3.1479 0.71131E-03 -3.1479 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73316E-07 -7.1348 0.51209E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50970E+00 -0.2927 11 Fe++ 0.62168E-13 -13.2064 0.31722E-13 -13.4986 0.51027E+00 -0.2922 12 K+ 0.16141E-03 -3.7921 0.13482E-03 -3.8702 0.83526E+00 -0.0782 13 Na+ 0.20521E-01 -1.6878 0.17108E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.19154E-10 -10.7177 0.97821E-11 -11.0096 0.51070E+00 -0.2918 15 HPO4-- 0.48757E-07 -7.3120 0.25160E-07 -7.5993 0.51603E+00 -0.2873 16 HSiO3- 0.10992E-01 -1.9589 0.91652E-02 -2.0379 0.83382E+00 -0.0789 17 Ca(HSiO3)+ 0.18021E-07 -7.7442 0.15055E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35447E-11 -11.4504 0.29614E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24903E-02 -2.6037 0.24903E-02 -2.6037 0.10000E+01 0.0000 20 AlO+ 0.67561E-16 -16.1703 0.56444E-16 -16.2484 0.83544E+00 -0.0781 22 HAlO2,aq 0.14916E-09 -9.8263 0.14916E-09 -9.8263 0.10000E+01 0.0000 23 AlO2- 0.52849E-05 -5.2770 0.43986E-05 -5.3567 0.83229E+00 -0.0797 24 CH4,aq 0.12514E-04 -4.9026 0.12469E-04 -4.9042 0.99643E+00 -0.0016 25 C2H6,aq 0.24729E-14 -14.6068 0.24640E-14 -14.6084 0.99643E+00 -0.0016 29 CO,aq 0.10298E-16 -16.9872 0.10298E-16 -16.9872 0.10000E+01 0.0000 30 CO2,aq 0.36874E-10 -10.4333 0.36743E-10 -10.4348 0.99643E+00 -0.0016 31 CO3-2 0.57079E-06 -6.2435 0.29387E-06 -6.5319 0.51484E+00 -0.2883 32 CaCO3,aq 0.26387E-09 -9.5786 0.26387E-09 -9.5786 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53216E-12 -12.2740 0.44459E-12 -12.3520 0.83544E+00 -0.0781 34 CaCl+ 0.16385E-10 -10.7856 0.13689E-10 -10.8636 0.83544E+00 -0.0781 35 CaCl2,aq 0.37345E-15 -15.4278 0.37345E-15 -15.4278 0.10000E+01 0.0000 36 CaOH+ 0.81720E-07 -7.0877 0.68272E-07 -7.1658 0.83544E+00 -0.0781 37 CaSO4,aq 0.94136E-17 -17.0262 0.94136E-17 -17.0262 0.10000E+01 0.0000 38 HCl,aq 0.16689E-14 -14.7776 0.16689E-14 -14.7776 0.10000E+01 0.0000 43 FeCl+ 0.69294E-17 -17.1593 0.57891E-17 -17.2374 0.83544E+00 -0.0781 46 FeO,aq 0.21878E-09 -9.6600 0.21878E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16624E-10 -10.7793 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37271E-07 -7.4286 0.31077E-07 -7.5076 0.83382E+00 -0.0789 49 FeO+ 0.12264E-16 -16.9114 0.10246E-16 -16.9895 0.83544E+00 -0.0781 51 FeO2- 0.42119E-09 -9.3755 0.35119E-09 -9.4545 0.83382E+00 -0.0789 52 HFeO2,aq 0.33281E-11 -11.4778 0.33281E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10921E-04 -4.9617 0.10882E-04 -4.9633 0.99643E+00 -0.0016 54 KCl,aq 0.27971E-09 -9.5533 0.27971E-09 -9.5533 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10266E-14 -14.9886 0.85596E-15 -15.0675 0.83382E+00 -0.0789 58 MgCO3,aq 0.10422E-13 -13.9821 0.10422E-13 -13.9821 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.85771E-16 -16.0667 0.71657E-16 -16.1447 0.83544E+00 -0.0781 60 MgCl+ 0.23510E-14 -14.6287 0.19641E-14 -14.7068 0.83544E+00 -0.0781 61 MgOH+ 0.71557E-10 -10.1453 0.59782E-10 -10.2234 0.83544E+00 -0.0781 63 MnO,aq 0.18010E-08 -8.7445 0.18010E-08 -8.7445 0.10000E+01 0.0000 64 MnOH+ 0.47622E-09 -9.3222 0.39786E-09 -9.4003 0.83544E+00 -0.0781 65 MnO2-2 0.21099E-10 -10.6757 0.10863E-10 -10.9641 0.51484E+00 -0.2883 66 HMnO2- 0.21373E-09 -9.6701 0.17821E-09 -9.7491 0.83382E+00 -0.0789 69 MnCl+ 0.83033E-14 -14.0808 0.69369E-14 -14.1588 0.83544E+00 -0.0781 71 NaCl,aq 0.65453E-06 -6.1841 0.65453E-06 -6.1841 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95178E-02 -2.0215 0.79216E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16797E-14 -14.7748 0.86480E-15 -15.0631 0.51484E+00 -0.2883 81 H2PO3- 0.15427E-18 -18.8117 0.12863E-18 -18.8906 0.83382E+00 -0.0789 82 H3PO4,aq 0.92875E-18 -18.0321 0.92875E-18 -18.0321 0.10000E+01 0.0000 83 H2PO4- 0.40019E-10 -10.3977 0.33401E-10 -10.4762 0.83462E+00 -0.0785 84 PO4-3 0.12125E-08 -8.9163 0.29017E-09 -9.5373 0.23932E+00 -0.6210 88 HP2O7-3 0.10377E-17 -17.9839 0.23645E-18 -18.6263 0.22787E+00 -0.6423 89 P2O7-4 0.10251E-16 -16.9892 0.77034E-18 -18.1133 0.75147E-01 -1.1241 90 H2S,aq 0.49681E-08 -8.3038 0.49504E-08 -8.3054 0.99643E+00 -0.0016 91 S2-2 0.18586E-14 -14.7308 0.95686E-15 -15.0192 0.51484E+00 -0.2883 97 SO3-2 0.11704E-17 -17.9317 0.61146E-18 -18.2136 0.52244E+00 -0.2820 99 HSO4- 0.34621E-19 -19.4607 0.28953E-19 -19.5383 0.83628E+00 -0.0777 Charge balance for all species = 0.3734E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9025551E-10 -.2312465E-01 -.2326608E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981190E+06 0.0000 3 Cl- 0.1405221E-03 0.1411769E-03 0.4996086E+01 6.1896 4 SO4-- 0.7986908E-12 -.1524437E-04 -.1461748E+01 7.8566 5 HCO3- 0.2882029E-06 0.1337339E-04 0.8145298E+00 3.5022 6 HS- 0.2609153E-04 0.4134087E-04 0.1364751E+01 5.4584 7 Al+++ 0.1101328E-28 0.5285034E-05 0.1423401E+00 0.7615 8 H4SiO4 0.7113113E-03 0.1419347E-01 0.1361742E+04 -3.1479 9 Ca++ 0.1431698E-06 0.2431910E-06 0.9728969E-02 13.1068 10 Mg++ 0.2273490E-10 0.9784969E-10 0.2374616E-05 9.3056 11 Fe++ 0.6216793E-13 0.3793073E-07 0.2114483E-02 6.7429 12 K+ 0.1614134E-03 0.1621899E-03 0.6330469E+01 6.2505 13 Na+ 0.2052130E-01 0.2311154E-01 0.5303681E+03 8.3540 14 Mn++ 0.1915432E-10 0.2531196E-08 0.1388072E-03 9.2320 15 HPO4-- 0.4875653E-07 0.5000903E-07 0.4791130E-02 12.6423 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3477259E+01 -.2260005E-01 -.3454659E+01 0.0000000E+00 2 H2O 0.5287583E+02 0.5424524E+02 -.1369418E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5845293E-02 -.1489854E-04 0.5860191E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5819788E-02 0.4040301E-04 -.5860191E-02 0.0000000E+00 7 Al+++ 0.6847525E+00 0.5165138E-05 0.6847473E+00 0.0000000E+00 8 H4SiO4 0.2186674E+01 0.1387147E-01 0.2172803E+01 0.0000000E+00 9 Ca++ 0.2415433E+00 0.2376740E-06 0.2415430E+00 0.0000000E+00 10 Mg++ 0.1666659E+00 0.9562987E-10 0.1666659E+00 0.0000000E+00 11 Fe++ 0.1497311E+00 0.3707023E-07 0.1497311E+00 0.0000000E+00 12 K+ 0.4458577E-01 0.1585104E-03 0.4442726E-01 0.0000000E+00 13 Na+ 0.2637600E+00 0.2258723E-01 0.2411727E+00 0.0000000E+00 14 Mn++ 0.3641088E-02 0.2473773E-08 0.3641085E-02 0.0000000E+00 15 HPO4-- 0.1242685E-02 0.4887453E-07 0.1242636E-02 0.0000000E+00 Chg. balance for solid moles: -.2437E-15 Mass of aqueous solution: 0.979086E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 209.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2409 -0.618 63.17 1.800 27.56 24.25 andradite 0.2344E-01 -1.630 11.91 1.076 5.197 3.095 grossular 0.5607E-02 -2.251 2.526 0.402 1.102 0.7027 apatite-OH 0.4142E-03 -3.383 0.2081 -0.682 0.9077E-01 0.6612E-01 clinochlore 0.3121E-01 -1.506 17.35 1.239 7.568 6.599 daphnite 0.8942E-02 -2.049 6.380 0.805 2.783 1.933 chlorite-Mn 0.7282E-03 -3.138 0.5163 -0.287 0.2252 0.1645 diopside 0.2655E-02 -2.576 0.5750 -0.240 0.2509 0.1757 hedenbergite 0.6800E-03 -3.167 0.1687 -0.773 0.7360E-01 0.4621E-01 microcline 0.3896E-01 -1.409 10.84 1.035 4.730 4.236 stilbite 0.1446 -0.840 101.9 2.008 44.46 47.53 stilpnomelane-Fe 0.1094E-01 -1.961 11.80 1.072 5.146 4.075 tr.625ac.25prg.125 0.2195E-02 -2.659 1.876 0.273 0.8184 0.6038 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8070E+00 0.8070E+00 1.0000 -0.093 grossular 0.1930E+00 0.1930E+00 1.0000 -0.714 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7635E+00 0.7635E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1781E-01 0.1781E-01 1.0000 -1.749 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 229.223278 g Volume = 93.475787 cm3 Porosity: -9.9720% V(tot) - V(min): -.84762E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 209.9990000 g log = 2.3222 Original solution: 1000.0103000 g Original solution / Rock added: 4.76 (Water/Rock Ratio), log = 0.6778 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0868 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9684E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3842E-08 1.0071 0.4206E-08 0.4176E-08 CH4,gas 0.1791E-01 1.0128 0.1972E-01 0.1947E-01 H2,gas 0.1373E-01 1.0006 0.1493E-01 0.1492E-01 H2S,gas 0.1334E-06 0.9958 0.1444E-06 0.1450E-06 S2,gas 0.3225E-29 1.0000 0.3505E-29 0.3505E-29 CO,gas 0.1496E-13 1.0000 0.1626E-13 0.1626E-13 SO3,gas 0.8128E-48 1.0000 0.8834E-48 0.8834E-48 SO2,gas 0.4589E-27 1.0000 0.4988E-27 0.4988E-27 HCl,gas 0.2711E-17 1.0000 0.2947E-17 0.2947E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.74 -10.38 -3.459 0.17717E+05 -8.376 3 CH4,gas 4.81 1.10 -3.71 -0.926 0.63264E+04 -1.705 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65329E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.420 0.15095E+05 -6.840 6 S2,gas -7.03 -38.49 -31.46 -4.839 0.53709E+05 -29.455 7 CO,gas 3.51 -12.28 -15.79 -4.858 0.26959E+05 -13.789 8 SO3,gas 17.43 -32.63 -50.05 -12.513 0.85466E+05 -48.054 9 SO2,gas 1.14 -28.17 -29.30 -7.814 0.50033E+05 -27.302 10 HCl,gas 5.48 -14.05 -19.53 -9.765 0.33348E+05 -17.531 11 acmite 7.74 6.57 -1.17 -0.121 0.19923E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.78 -4.77 -0.239 0.81528E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94092E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41190E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28373E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76219E+04 35 aragonite 0.99 -3.63 -4.62 -1.540 0.78865E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55852E+04 37 calcite 0.83 -3.63 -4.47 -1.489 0.76252E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52881E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71150E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70309E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82179E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47361E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39554E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68641E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70360E+04 52 chloritoid-Mn 11.46 7.61 -3.86 -0.257 0.65843E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13294E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10223E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36448E+04 66 diamond -3.11 -7.82 -4.71 -1.346 0.80428E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.81 -1.97 -0.096 0.33638E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66028E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57723E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68260E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56960E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36650E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70707E+04 86 graphite -3.55 -7.82 -4.27 -1.220 0.72890E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38611E+04 90 hematite 12.60 9.02 -3.57 -0.433 0.61001E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24439E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64136E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59758E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15992E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22957E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58933E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28457E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74529E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48214E+04 112 manganosite 14.07 9.23 -4.84 -1.209 0.82573E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61265E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53649E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41160E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83601E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36592E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20040E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92730E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40652E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.056 0.43398E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.266 0.64827E+04 144 pyrrhotiteFe0.875 -6.00 -9.44 -3.44 -1.263 0.58656E+04 145 pyroxmangite 7.42 6.08 -1.33 -0.266 0.22743E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84874E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28334E+03 152 rhodonite 7.46 6.08 -1.38 -0.276 0.23536E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27383E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20975E+04 174 tephroite 18.11 15.32 -2.80 -0.400 0.47756E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91063E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76041E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65769E+04 181 troilite-low -4.39 -8.04 -3.65 -1.215 0.62259E+04 183 vesuvianite 224.06 219.35 -4.70 -0.036 0.80303E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34500E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66753E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55582E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60366E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66124E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68736E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73630E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60305E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57946E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83194E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61773E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66258E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52977E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.55 -4.59 -1.530 0.78352E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62632E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52612E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18239E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11528E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14889E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18333E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 209.9990000 g New total amount of reactant added: 219.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3651E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 219.9990000 Water: Moles liquid = 0.5419E+02 kg liquid = 0.9763E+00 Moles total = 0.5275E+02 kg total = 0.9503E+00 Activity = 1.0000 Stoichiometric ionic strength = .1172979E-01 Osmotic coef. = 0.9690 True ionic strength = .2068409E-01 Chg. balance for total moles = 0.3651E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90257E-10 -10.0445 0.75722E-10 -10.1208 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14067E-03 -3.8518 0.11729E-03 -3.9307 0.83382E+00 -0.0789 4 SO4-- 0.79967E-12 -12.0971 0.41260E-12 -12.3845 0.51596E+00 -0.2874 5 HCO3- 0.28855E-06 -6.5398 0.24096E-06 -6.6181 0.83506E+00 -0.0783 6 HS- 0.26118E-04 -4.5831 0.21781E-04 -4.6619 0.83394E+00 -0.0789 7 Al+++ 0.11013E-28 -28.9581 0.25068E-29 -29.6009 0.22763E+00 -0.6428 8 H4SiO4 0.71133E-03 -3.1479 0.71133E-03 -3.1479 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73315E-07 -7.1348 0.51209E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50970E+00 -0.2927 11 Fe++ 0.62169E-13 -13.2064 0.31723E-13 -13.4986 0.51027E+00 -0.2922 12 K+ 0.16142E-03 -3.7921 0.13482E-03 -3.8702 0.83526E+00 -0.0782 13 Na+ 0.20522E-01 -1.6878 0.17108E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.19192E-10 -10.7169 0.98013E-11 -11.0087 0.51070E+00 -0.2918 15 HPO4-- 0.48758E-07 -7.3120 0.25160E-07 -7.5993 0.51603E+00 -0.2873 16 HSiO3- 0.10992E-01 -1.9589 0.91653E-02 -2.0379 0.83382E+00 -0.0789 17 Ca(HSiO3)+ 0.18021E-07 -7.7442 0.15055E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35447E-11 -11.4504 0.29614E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24904E-02 -2.6037 0.24904E-02 -2.6037 0.10000E+01 0.0000 20 AlO+ 0.67557E-16 -16.1703 0.56440E-16 -16.2484 0.83544E+00 -0.0781 22 HAlO2,aq 0.14915E-09 -9.8264 0.14915E-09 -9.8264 0.10000E+01 0.0000 23 AlO2- 0.52845E-05 -5.2770 0.43982E-05 -5.3567 0.83229E+00 -0.0797 24 CH4,aq 0.12527E-04 -4.9022 0.12482E-04 -4.9037 0.99643E+00 -0.0016 25 C2H6,aq 0.24780E-14 -14.6059 0.24692E-14 -14.6074 0.99643E+00 -0.0016 29 CO,aq 0.10310E-16 -16.9867 0.10310E-16 -16.9867 0.10000E+01 0.0000 30 CO2,aq 0.36920E-10 -10.4327 0.36788E-10 -10.4343 0.99643E+00 -0.0016 31 CO3-2 0.57148E-06 -6.2430 0.29422E-06 -6.5313 0.51484E+00 -0.2883 32 CaCO3,aq 0.26419E-09 -9.5781 0.26419E-09 -9.5781 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53281E-12 -12.2734 0.44513E-12 -12.3515 0.83544E+00 -0.0781 34 CaCl+ 0.16402E-10 -10.7851 0.13703E-10 -10.8632 0.83544E+00 -0.0781 35 CaCl2,aq 0.37422E-15 -15.4269 0.37422E-15 -15.4269 0.10000E+01 0.0000 36 CaOH+ 0.81719E-07 -7.0877 0.68271E-07 -7.1658 0.83544E+00 -0.0781 37 CaSO4,aq 0.94251E-17 -17.0257 0.94251E-17 -17.0257 0.10000E+01 0.0000 38 HCl,aq 0.16706E-14 -14.7771 0.16706E-14 -14.7771 0.10000E+01 0.0000 43 FeCl+ 0.69366E-17 -17.1589 0.57952E-17 -17.2369 0.83544E+00 -0.0781 46 FeO,aq 0.21878E-09 -9.6600 0.21878E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16624E-10 -10.7793 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37270E-07 -7.4286 0.31076E-07 -7.5076 0.83382E+00 -0.0789 49 FeO+ 0.12264E-16 -16.9114 0.10246E-16 -16.9895 0.83544E+00 -0.0781 51 FeO2- 0.42119E-09 -9.3755 0.35120E-09 -9.4545 0.83382E+00 -0.0789 52 HFeO2,aq 0.33282E-11 -11.4778 0.33282E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10921E-04 -4.9617 0.10882E-04 -4.9633 0.99643E+00 -0.0016 54 KCl,aq 0.28000E-09 -9.5528 0.28000E-09 -9.5528 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10278E-14 -14.9881 0.85702E-15 -15.0670 0.83382E+00 -0.0789 58 MgCO3,aq 0.10434E-13 -13.9815 0.10434E-13 -13.9815 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.85875E-16 -16.0661 0.71744E-16 -16.1442 0.83544E+00 -0.0781 60 MgCl+ 0.23534E-14 -14.6283 0.19662E-14 -14.7064 0.83544E+00 -0.0781 61 MgOH+ 0.71556E-10 -10.1454 0.59781E-10 -10.2234 0.83544E+00 -0.0781 63 MnO,aq 0.18045E-08 -8.7437 0.18045E-08 -8.7437 0.10000E+01 0.0000 64 MnOH+ 0.47715E-09 -9.3213 0.39863E-09 -9.3994 0.83544E+00 -0.0781 65 MnO2-2 0.21140E-10 -10.6749 0.10883E-10 -10.9632 0.51484E+00 -0.2883 66 HMnO2- 0.21414E-09 -9.6693 0.17856E-09 -9.7482 0.83382E+00 -0.0789 69 MnCl+ 0.83281E-14 -14.0795 0.69576E-14 -14.1575 0.83544E+00 -0.0781 71 NaCl,aq 0.65521E-06 -6.1836 0.65521E-06 -6.1836 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95177E-02 -2.0215 0.79215E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16797E-14 -14.7748 0.86477E-15 -15.0631 0.51484E+00 -0.2883 81 H2PO3- 0.15427E-18 -18.8117 0.12863E-18 -18.8907 0.83382E+00 -0.0789 82 H3PO4,aq 0.92878E-18 -18.0321 0.92878E-18 -18.0321 0.10000E+01 0.0000 83 H2PO4- 0.40021E-10 -10.3977 0.33402E-10 -10.4762 0.83462E+00 -0.0785 84 PO4-3 0.12125E-08 -8.9163 0.29018E-09 -9.5373 0.23932E+00 -0.6210 88 HP2O7-3 0.10377E-17 -17.9839 0.23646E-18 -18.6262 0.22787E+00 -0.6423 89 P2O7-4 0.10252E-16 -16.9892 0.77037E-18 -18.1133 0.75147E-01 -1.1241 90 H2S,aq 0.49733E-08 -8.3034 0.49555E-08 -8.3049 0.99643E+00 -0.0016 91 S2-2 0.18625E-14 -14.7299 0.95888E-15 -15.0182 0.51484E+00 -0.2883 97 SO3-2 0.11718E-17 -17.9312 0.61217E-18 -18.2131 0.52244E+00 -0.2820 99 HSO4- 0.34664E-19 -19.4601 0.28989E-19 -19.5378 0.83627E+00 -0.0777 Charge balance for all species = 0.3738E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9025650E-10 -.2312476E-01 -.2326618E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981189E+06 0.0000 3 Cl- 0.1406667E-03 0.1413222E-03 0.5001228E+01 6.1900 4 SO4-- 0.7996718E-12 -.1525696E-04 -.1462955E+01 7.8571 5 HCO3- 0.2885529E-06 0.1338715E-04 0.8153680E+00 3.5027 6 HS- 0.2611838E-04 0.4138031E-04 0.1366052E+01 5.4589 7 Al+++ 0.1101296E-28 0.5284631E-05 0.1423292E+00 0.7615 8 H4SiO4 0.7113272E-03 0.1419368E-01 0.1361762E+04 -3.1479 9 Ca++ 0.1431699E-06 0.2431907E-06 0.9728955E-02 13.1067 10 Mg++ 0.2273486E-10 0.9784858E-10 0.2374589E-05 9.3056 11 Fe++ 0.6216883E-13 0.3793003E-07 0.2114445E-02 6.7429 12 K+ 0.1614151E-03 0.1621916E-03 0.6330537E+01 6.2505 13 Na+ 0.2052153E-01 0.2311182E-01 0.5303744E+03 8.3540 14 Mn++ 0.1919187E-10 0.2536101E-08 0.1390761E-03 9.2328 15 HPO4-- 0.4875752E-07 0.5001004E-07 0.4791226E-02 12.6423 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3642844E+01 -.2257692E-01 -.3620267E+01 0.0000000E+00 2 H2O 0.5275047E+02 0.5418948E+02 -.1439008E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6122427E-02 -.1489551E-04 0.6137322E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6096922E-02 0.4039998E-04 -.6137322E-02 0.0000000E+00 7 Al+++ 0.7173599E+00 0.5159434E-05 0.7173547E+00 0.0000000E+00 8 H4SiO4 0.2290802E+01 0.1385742E-01 0.2276944E+01 0.0000000E+00 9 Ca++ 0.2530447E+00 0.2374293E-06 0.2530445E+00 0.0000000E+00 10 Mg++ 0.1746024E+00 0.9553047E-10 0.1746024E+00 0.0000000E+00 11 Fe++ 0.1568612E+00 0.3703144E-07 0.1568611E+00 0.0000000E+00 12 K+ 0.4670892E-01 0.1583492E-03 0.4655057E-01 0.0000000E+00 13 Na+ 0.2763124E+00 0.2256428E-01 0.2537481E+00 0.0000000E+00 14 Mn++ 0.3814474E-02 0.2476019E-08 0.3814471E-02 0.0000000E+00 15 HPO4-- 0.1301861E-02 0.4882527E-07 0.1301812E-02 0.0000000E+00 Chg. balance for solid moles: -.6778E-15 Mass of aqueous solution: 0.978080E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 219.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2535 -0.596 66.46 1.823 27.68 25.51 andradite 0.2455E-01 -1.610 12.48 1.096 5.195 3.241 grossular 0.5872E-02 -2.231 2.645 0.422 1.101 0.7359 apatite-OH 0.4339E-03 -3.363 0.2180 -0.662 0.9077E-01 0.6926E-01 clinochlore 0.3263E-01 -1.486 18.14 1.259 7.553 6.899 daphnite 0.9350E-02 -2.029 6.671 0.824 2.778 2.022 chlorite-Mn 0.7629E-03 -3.118 0.5409 -0.267 0.2252 0.1724 diopside 0.3234E-02 -2.490 0.7003 -0.155 0.2916 0.2140 hedenbergite 0.8282E-03 -3.082 0.2055 -0.687 0.8556E-01 0.5628E-01 microcline 0.4081E-01 -1.389 11.36 1.055 4.731 4.438 stilbite 0.1510 -0.821 106.4 2.027 44.32 49.64 stilpnomelane-Fe 0.1147E-01 -1.940 12.37 1.092 5.149 4.272 tr.625ac.25prg.125 0.2263E-02 -2.645 1.934 0.287 0.8055 0.6226 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8070E+00 0.8070E+00 1.0000 -0.093 grossular 0.1930E+00 0.1930E+00 1.0000 -0.714 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7634E+00 0.7634E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1785E-01 0.1785E-01 1.0000 -1.748 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 240.148814 g Volume = 97.896423 cm3 Porosity: -9.9965% V(tot) - V(min): -.88968E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 219.9990000 g log = 2.3424 Original solution: 1000.0103000 g Original solution / Rock added: 4.55 (Water/Rock Ratio), log = 0.6576 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0868 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9683E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3847E-08 1.0071 0.4211E-08 0.4181E-08 CH4,gas 0.1793E-01 1.0128 0.1974E-01 0.1949E-01 H2,gas 0.1372E-01 1.0006 0.1493E-01 0.1492E-01 H2S,gas 0.1335E-06 0.9958 0.1445E-06 0.1451E-06 S2,gas 0.3232E-29 1.0000 0.3512E-29 0.3512E-29 CO,gas 0.1498E-13 1.0000 0.1628E-13 0.1628E-13 SO3,gas 0.8138E-48 1.0000 0.8845E-48 0.8845E-48 SO2,gas 0.4595E-27 1.0000 0.4994E-27 0.4994E-27 HCl,gas 0.2714E-17 1.0000 0.2950E-17 0.2950E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.60662E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.74 -10.38 -3.459 0.17716E+05 -8.376 3 CH4,gas 4.81 1.10 -3.70 -0.926 0.63256E+04 -1.705 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65329E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.420 0.15094E+05 -6.840 6 S2,gas -7.03 -38.49 -31.45 -4.839 0.53708E+05 -29.454 7 CO,gas 3.51 -12.28 -15.79 -4.858 0.26958E+05 -13.788 8 SO3,gas 17.43 -32.63 -50.05 -12.513 0.85465E+05 -48.053 9 SO2,gas 1.14 -28.17 -29.30 -7.814 0.50032E+05 -27.302 10 HCl,gas 5.48 -14.05 -19.53 -9.765 0.33347E+05 -17.530 11 acmite 7.74 6.57 -1.17 -0.121 0.19922E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.78 -4.77 -0.239 0.81485E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94093E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41190E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28373E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76220E+04 35 aragonite 0.99 -3.63 -4.62 -1.539 0.78856E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55852E+04 37 calcite 0.83 -3.63 -4.47 -1.488 0.76243E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52881E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71150E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70310E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82179E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47361E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39554E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68641E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70361E+04 52 chloritoid-Mn 11.46 7.61 -3.86 -0.257 0.65830E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13294E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10223E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36448E+04 66 diamond -3.11 -7.82 -4.71 -1.346 0.80420E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.81 -1.97 -0.096 0.33639E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66029E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57723E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68260E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56960E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36650E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70706E+04 86 graphite -3.55 -7.82 -4.27 -1.220 0.72881E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38611E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.61001E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24440E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64136E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59758E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15992E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22958E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58933E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28457E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74528E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48214E+04 112 manganosite 14.07 9.23 -4.84 -1.209 0.82558E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61265E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53650E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41161E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83602E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36592E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20041E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92732E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40654E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.056 0.43401E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.265 0.64819E+04 144 pyrrhotiteFe0.875 -6.00 -9.44 -3.43 -1.263 0.58648E+04 145 pyroxmangite 7.42 6.08 -1.33 -0.266 0.22729E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84875E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28332E+03 152 rhodonite 7.46 6.08 -1.38 -0.276 0.23521E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27383E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20975E+04 174 tephroite 18.11 15.32 -2.80 -0.399 0.47727E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91062E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76040E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65769E+04 181 troilite-low -4.39 -8.04 -3.65 -1.215 0.62251E+04 183 vesuvianite 224.06 219.35 -4.70 -0.036 0.80309E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34500E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66755E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55582E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60364E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66124E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68736E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73630E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60305E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57945E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83194E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61772E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66257E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52976E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.55 -4.59 -1.529 0.78330E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62633E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52612E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18238E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11528E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14889E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18333E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 219.9990000 g New total amount of reactant added: 229.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3651E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 229.9990000 Water: Moles liquid = 0.5414E+02 kg liquid = 0.9753E+00 Moles total = 0.5263E+02 kg total = 0.9481E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173000E-01 Osmotic coef. = 0.9690 True ionic strength = .2068431E-01 Chg. balance for total moles = 0.3651E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90257E-10 -10.0445 0.75723E-10 -10.1208 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14081E-03 -3.8514 0.11741E-03 -3.9303 0.83382E+00 -0.0789 4 SO4-- 0.80064E-12 -12.0966 0.41309E-12 -12.3840 0.51595E+00 -0.2874 5 HCO3- 0.28890E-06 -6.5393 0.24125E-06 -6.6175 0.83506E+00 -0.0783 6 HS- 0.26145E-04 -4.5826 0.21804E-04 -4.6615 0.83394E+00 -0.0789 7 Al+++ 0.11013E-28 -28.9581 0.25068E-29 -29.6009 0.22762E+00 -0.6428 8 H4SiO4 0.71134E-03 -3.1479 0.71134E-03 -3.1479 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73315E-07 -7.1348 0.51209E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50970E+00 -0.2927 11 Fe++ 0.62170E-13 -13.2064 0.31723E-13 -13.4986 0.51027E+00 -0.2922 12 K+ 0.16142E-03 -3.7921 0.13482E-03 -3.8702 0.83526E+00 -0.0782 13 Na+ 0.20522E-01 -1.6878 0.17108E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.19226E-10 -10.7161 0.98188E-11 -11.0079 0.51070E+00 -0.2918 15 HPO4-- 0.48758E-07 -7.3120 0.25161E-07 -7.5993 0.51603E+00 -0.2873 16 HSiO3- 0.10992E-01 -1.9589 0.91654E-02 -2.0378 0.83382E+00 -0.0789 17 Ca(HSiO3)+ 0.18021E-07 -7.7442 0.15056E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35448E-11 -11.4504 0.29615E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24904E-02 -2.6037 0.24904E-02 -2.6037 0.10000E+01 0.0000 20 AlO+ 0.67554E-16 -16.1703 0.56438E-16 -16.2484 0.83544E+00 -0.0781 22 HAlO2,aq 0.14915E-09 -9.8264 0.14915E-09 -9.8264 0.10000E+01 0.0000 23 AlO2- 0.52841E-05 -5.2770 0.43979E-05 -5.3568 0.83229E+00 -0.0797 24 CH4,aq 0.12540E-04 -4.9017 0.12495E-04 -4.9033 0.99643E+00 -0.0016 25 C2H6,aq 0.24832E-14 -14.6050 0.24743E-14 -14.6065 0.99643E+00 -0.0016 29 CO,aq 0.10322E-16 -16.9862 0.10322E-16 -16.9862 0.10000E+01 0.0000 30 CO2,aq 0.36964E-10 -10.4322 0.36832E-10 -10.4338 0.99643E+00 -0.0016 31 CO3-2 0.57216E-06 -6.2425 0.29457E-06 -6.5308 0.51484E+00 -0.2883 32 CaCO3,aq 0.26450E-09 -9.5776 0.26450E-09 -9.5776 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53345E-12 -12.2729 0.44566E-12 -12.3510 0.83544E+00 -0.0781 34 CaCl+ 0.16419E-10 -10.7847 0.13717E-10 -10.8627 0.83544E+00 -0.0781 35 CaCl2,aq 0.37499E-15 -15.4260 0.37499E-15 -15.4260 0.10000E+01 0.0000 36 CaOH+ 0.81718E-07 -7.0877 0.68271E-07 -7.1658 0.83544E+00 -0.0781 37 CaSO4,aq 0.94365E-17 -17.0252 0.94365E-17 -17.0252 0.10000E+01 0.0000 38 HCl,aq 0.16723E-14 -14.7767 0.16723E-14 -14.7767 0.10000E+01 0.0000 43 FeCl+ 0.69438E-17 -17.1584 0.58012E-17 -17.2365 0.83544E+00 -0.0781 46 FeO,aq 0.21878E-09 -9.6600 0.21878E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16624E-10 -10.7793 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37269E-07 -7.4286 0.31076E-07 -7.5076 0.83382E+00 -0.0789 49 FeO+ 0.12264E-16 -16.9114 0.10246E-16 -16.9894 0.83544E+00 -0.0781 51 FeO2- 0.42119E-09 -9.3755 0.35120E-09 -9.4544 0.83382E+00 -0.0789 52 HFeO2,aq 0.33282E-11 -11.4778 0.33282E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10920E-04 -4.9618 0.10881E-04 -4.9633 0.99643E+00 -0.0016 54 KCl,aq 0.28029E-09 -9.5524 0.28029E-09 -9.5524 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10291E-14 -14.9876 0.85807E-15 -15.0665 0.83382E+00 -0.0789 58 MgCO3,aq 0.10447E-13 -13.9810 0.10447E-13 -13.9810 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.85978E-16 -16.0656 0.71830E-16 -16.1437 0.83544E+00 -0.0781 60 MgCl+ 0.23558E-14 -14.6279 0.19682E-14 -14.7059 0.83544E+00 -0.0781 61 MgOH+ 0.71555E-10 -10.1454 0.59780E-10 -10.2234 0.83544E+00 -0.0781 63 MnO,aq 0.18077E-08 -8.7429 0.18077E-08 -8.7429 0.10000E+01 0.0000 64 MnOH+ 0.47800E-09 -9.3206 0.39934E-09 -9.3987 0.83544E+00 -0.0781 65 MnO2-2 0.21177E-10 -10.6741 0.10903E-10 -10.9625 0.51484E+00 -0.2883 66 HMnO2- 0.21452E-09 -9.6685 0.17887E-09 -9.7475 0.83382E+00 -0.0789 69 MnCl+ 0.83516E-14 -14.0782 0.69773E-14 -14.1563 0.83544E+00 -0.0781 71 NaCl,aq 0.65589E-06 -6.1832 0.65589E-06 -6.1832 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95176E-02 -2.0215 0.79214E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16796E-14 -14.7748 0.86474E-15 -15.0631 0.51484E+00 -0.2883 81 H2PO3- 0.15426E-18 -18.8117 0.12863E-18 -18.8907 0.83382E+00 -0.0789 82 H3PO4,aq 0.92881E-18 -18.0321 0.92881E-18 -18.0321 0.10000E+01 0.0000 83 H2PO4- 0.40022E-10 -10.3977 0.33403E-10 -10.4762 0.83462E+00 -0.0785 84 PO4-3 0.12125E-08 -8.9163 0.29018E-09 -9.5373 0.23932E+00 -0.6210 88 HP2O7-3 0.10378E-17 -17.9839 0.23647E-18 -18.6262 0.22786E+00 -0.6423 89 P2O7-4 0.10252E-16 -16.9892 0.77039E-18 -18.1133 0.75146E-01 -1.1241 90 H2S,aq 0.49785E-08 -8.3029 0.49607E-08 -8.3045 0.99643E+00 -0.0016 91 S2-2 0.18664E-14 -14.7290 0.96090E-15 -15.0173 0.51484E+00 -0.2883 97 SO3-2 0.11731E-17 -17.9307 0.61289E-18 -18.2126 0.52244E+00 -0.2820 99 HSO4- 0.34707E-19 -19.4596 0.29024E-19 -19.5372 0.83627E+00 -0.0777 Charge balance for all species = 0.3742E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9025744E-10 -.2312485E-01 -.2326627E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981189E+06 0.0000 3 Cl- 0.1408116E-03 0.1414678E-03 0.5006379E+01 6.1905 4 SO4-- 0.8006413E-12 -.1526959E-04 -.1464166E+01 7.8576 5 HCO3- 0.2888991E-06 0.1340094E-04 0.8162079E+00 3.5032 6 HS- 0.2614528E-04 0.4141985E-04 0.1367358E+01 5.4593 7 Al+++ 0.1101268E-28 0.5284259E-05 0.1423192E+00 0.7614 8 H4SiO4 0.7113418E-03 0.1419387E-01 0.1361780E+04 -3.1479 9 Ca++ 0.1431701E-06 0.2431905E-06 0.9728949E-02 13.1067 10 Mg++ 0.2273485E-10 0.9784772E-10 0.2374568E-05 9.3055 11 Fe++ 0.6216970E-13 0.3792939E-07 0.2114409E-02 6.7429 12 K+ 0.1614168E-03 0.1621933E-03 0.6330601E+01 6.2505 13 Na+ 0.2052174E-01 0.2311208E-01 0.5303804E+03 8.3540 14 Mn++ 0.1922629E-10 0.2540596E-08 0.1393227E-03 9.2336 15 HPO4-- 0.4875840E-07 0.5001094E-07 0.4791312E-02 12.6423 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3808429E+01 -.2255377E-01 -.3785875E+01 0.0000000E+00 2 H2O 0.5262512E+02 0.5413372E+02 -.1508597E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6399561E-02 -.1489250E-04 0.6414453E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6374056E-02 0.4039697E-04 -.6414453E-02 0.0000000E+00 7 Al+++ 0.7499673E+00 0.5153762E-05 0.7499622E+00 0.0000000E+00 8 H4SiO4 0.2394930E+01 0.1384335E-01 0.2381086E+01 0.0000000E+00 9 Ca++ 0.2645461E+00 0.2371848E-06 0.2645459E+00 0.0000000E+00 10 Mg++ 0.1825389E+00 0.9543133E-10 0.1825389E+00 0.0000000E+00 11 Fe++ 0.1639913E+00 0.3699271E-07 0.1639912E+00 0.0000000E+00 12 K+ 0.4883206E-01 0.1581878E-03 0.4867387E-01 0.0000000E+00 13 Na+ 0.2888648E+00 0.2254132E-01 0.2663235E+00 0.0000000E+00 14 Mn++ 0.3987860E-02 0.2477855E-08 0.3987857E-02 0.0000000E+00 15 HPO4-- 0.1361037E-02 0.4877590E-07 0.1360988E-02 0.0000000E+00 Chg. balance for solid moles: -.1041E-16 Mass of aqueous solution: 0.977073E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 229.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2660 -0.575 69.76 1.844 27.78 26.78 andradite 0.2566E-01 -1.591 13.04 1.115 5.193 3.388 grossular 0.6136E-02 -2.212 2.764 0.442 1.101 0.7691 apatite-OH 0.4537E-03 -3.343 0.2279 -0.642 0.9076E-01 0.7241E-01 clinochlore 0.3406E-01 -1.468 18.93 1.277 7.539 7.200 daphnite 0.9757E-02 -2.011 6.962 0.843 2.773 2.110 chlorite-Mn 0.7976E-03 -3.098 0.5655 -0.248 0.2252 0.1802 diopside 0.3812E-02 -2.419 0.8256 -0.083 0.3288 0.2523 hedenbergite 0.9763E-03 -3.010 0.2422 -0.616 0.9648E-01 0.6634E-01 microcline 0.4267E-01 -1.370 11.88 1.075 4.731 4.640 stilbite 0.1574 -0.803 111.0 2.045 44.19 51.75 stilpnomelane-Fe 0.1200E-01 -1.921 12.94 1.112 5.152 4.468 tr.625ac.25prg.125 0.2331E-02 -2.632 1.993 0.299 0.7936 0.6413 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8070E+00 0.8070E+00 1.0000 -0.093 grossular 0.1930E+00 0.1930E+00 1.0000 -0.714 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7634E+00 0.7634E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1788E-01 0.1788E-01 1.0000 -1.748 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 251.074351 g Volume = 102.317058 cm3 Porosity: -10.0188% V(tot) - V(min): -.93175E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 229.9990000 g log = 2.3617 Original solution: 1000.0103000 g Original solution / Rock added: 4.35 (Water/Rock Ratio), log = 0.6383 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0869 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9683E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3852E-08 1.0071 0.4216E-08 0.4186E-08 CH4,gas 0.1795E-01 1.0128 0.1976E-01 0.1951E-01 H2,gas 0.1372E-01 1.0006 0.1492E-01 0.1492E-01 H2S,gas 0.1337E-06 0.9958 0.1447E-06 0.1453E-06 S2,gas 0.3239E-29 1.0000 0.3520E-29 0.3520E-29 CO,gas 0.1500E-13 1.0000 0.1630E-13 0.1630E-13 SO3,gas 0.8148E-48 1.0000 0.8855E-48 0.8855E-48 SO2,gas 0.4600E-27 1.0000 0.5000E-27 0.5000E-27 HCl,gas 0.2717E-17 1.0000 0.2953E-17 0.2953E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 -0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 -0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.74 -10.38 -3.458 0.17715E+05 -8.375 3 CH4,gas 4.81 1.10 -3.70 -0.926 0.63249E+04 -1.704 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65330E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.420 0.15093E+05 -6.840 6 S2,gas -7.03 -38.49 -31.45 -4.839 0.53706E+05 -29.453 7 CO,gas 3.51 -12.28 -15.79 -4.858 0.26957E+05 -13.788 8 SO3,gas 17.43 -32.63 -50.05 -12.513 0.85464E+05 -48.053 9 SO2,gas 1.14 -28.16 -29.30 -7.814 0.50031E+05 -27.301 10 HCl,gas 5.48 -14.05 -19.53 -9.765 0.33347E+05 -17.530 11 acmite 7.74 6.57 -1.17 -0.121 0.19922E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.78 -4.77 -0.238 0.81446E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94095E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41190E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28374E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76220E+04 35 aragonite 0.99 -3.63 -4.62 -1.539 0.78848E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55852E+04 37 calcite 0.83 -3.63 -4.46 -1.488 0.76234E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52882E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71150E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70311E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82180E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47361E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39554E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68642E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70362E+04 52 chloritoid-Mn 11.46 7.61 -3.85 -0.257 0.65818E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13294E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10223E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36449E+04 66 diamond -3.11 -7.82 -4.71 -1.346 0.80411E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.81 -1.97 -0.096 0.33639E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66031E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57723E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68260E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56961E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36650E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70706E+04 86 graphite -3.55 -7.82 -4.27 -1.219 0.72873E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38611E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.61001E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24440E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64136E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59759E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15993E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22959E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58934E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28457E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74528E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48213E+04 112 manganosite 14.07 9.23 -4.83 -1.209 0.82545E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61266E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53651E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41161E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83602E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36593E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20042E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92734E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40656E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.056 0.43403E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.265 0.64812E+04 144 pyrrhotiteFe0.875 -6.00 -9.44 -3.43 -1.263 0.58640E+04 145 pyroxmangite 7.42 6.09 -1.33 -0.266 0.22715E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84875E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28331E+03 152 rhodonite 7.46 6.09 -1.38 -0.275 0.23508E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27384E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20975E+04 174 tephroite 18.11 15.32 -2.79 -0.399 0.47700E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91060E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76039E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65768E+04 181 troilite-low -4.39 -8.04 -3.65 -1.215 0.62243E+04 183 vesuvianite 224.06 219.35 -4.70 -0.036 0.80315E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34501E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66756E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55582E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60362E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66124E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68736E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73630E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60305E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57945E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83193E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61771E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66257E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52975E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.55 -4.59 -1.529 0.78309E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62633E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52612E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18238E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11528E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14889E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18333E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 229.9990000 g New total amount of reactant added: 239.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3651E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 239.9990000 Water: Moles liquid = 0.5408E+02 kg liquid = 0.9743E+00 Moles total = 0.5250E+02 kg total = 0.9458E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173020E-01 Osmotic coef. = 0.9690 True ionic strength = .2068451E-01 Chg. balance for total moles = 0.3651E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90258E-10 -10.0445 0.75724E-10 -10.1208 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14096E-03 -3.8509 0.11753E-03 -3.9298 0.83382E+00 -0.0789 4 SO4-- 0.80160E-12 -12.0960 0.41359E-12 -12.3834 0.51595E+00 -0.2874 5 HCO3- 0.28924E-06 -6.5387 0.24153E-06 -6.6170 0.83506E+00 -0.0783 6 HS- 0.26172E-04 -4.5822 0.21826E-04 -4.6610 0.83394E+00 -0.0789 7 Al+++ 0.11012E-28 -28.9581 0.25067E-29 -29.6009 0.22762E+00 -0.6428 8 H4SiO4 0.71136E-03 -3.1479 0.71136E-03 -3.1479 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73315E-07 -7.1348 0.51208E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50970E+00 -0.2927 11 Fe++ 0.62171E-13 -13.2064 0.31723E-13 -13.4986 0.51026E+00 -0.2922 12 K+ 0.16142E-03 -3.7920 0.13483E-03 -3.8702 0.83526E+00 -0.0782 13 Na+ 0.20522E-01 -1.6878 0.17108E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.19258E-10 -10.7154 0.98350E-11 -11.0072 0.51070E+00 -0.2918 15 HPO4-- 0.48759E-07 -7.3119 0.25161E-07 -7.5993 0.51603E+00 -0.2873 16 HSiO3- 0.10992E-01 -1.9589 0.91655E-02 -2.0378 0.83382E+00 -0.0789 17 Ca(HSiO3)+ 0.18021E-07 -7.7442 0.15056E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35448E-11 -11.4504 0.29615E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24905E-02 -2.6037 0.24905E-02 -2.6037 0.10000E+01 0.0000 20 AlO+ 0.67551E-16 -16.1704 0.56435E-16 -16.2485 0.83544E+00 -0.0781 22 HAlO2,aq 0.14914E-09 -9.8264 0.14914E-09 -9.8264 0.10000E+01 0.0000 23 AlO2- 0.52838E-05 -5.2771 0.43976E-05 -5.3568 0.83229E+00 -0.0797 24 CH4,aq 0.12552E-04 -4.9013 0.12508E-04 -4.9028 0.99642E+00 -0.0016 25 C2H6,aq 0.24884E-14 -14.6041 0.24795E-14 -14.6056 0.99642E+00 -0.0016 29 CO,aq 0.10334E-16 -16.9857 0.10334E-16 -16.9857 0.10000E+01 0.0000 30 CO2,aq 0.37008E-10 -10.4317 0.36876E-10 -10.4333 0.99642E+00 -0.0016 31 CO3-2 0.57283E-06 -6.2420 0.29492E-06 -6.5303 0.51484E+00 -0.2883 32 CaCO3,aq 0.26482E-09 -9.5771 0.26482E-09 -9.5771 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53408E-12 -12.2724 0.44619E-12 -12.3505 0.83544E+00 -0.0781 34 CaCl+ 0.16436E-10 -10.7842 0.13731E-10 -10.8623 0.83544E+00 -0.0781 35 CaCl2,aq 0.37576E-15 -15.4251 0.37576E-15 -15.4251 0.10000E+01 0.0000 36 CaOH+ 0.81717E-07 -7.0877 0.68270E-07 -7.1658 0.83544E+00 -0.0781 37 CaSO4,aq 0.94477E-17 -17.0247 0.94477E-17 -17.0247 0.10000E+01 0.0000 38 HCl,aq 0.16741E-14 -14.7762 0.16741E-14 -14.7762 0.10000E+01 0.0000 43 FeCl+ 0.69511E-17 -17.1579 0.58072E-17 -17.2360 0.83544E+00 -0.0781 46 FeO,aq 0.21877E-09 -9.6600 0.21877E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16624E-10 -10.7793 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37269E-07 -7.4287 0.31075E-07 -7.5076 0.83382E+00 -0.0789 49 FeO+ 0.12265E-16 -16.9113 0.10246E-16 -16.9894 0.83544E+00 -0.0781 51 FeO2- 0.42120E-09 -9.3755 0.35120E-09 -9.4544 0.83382E+00 -0.0789 52 HFeO2,aq 0.33283E-11 -11.4778 0.33283E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10920E-04 -4.9618 0.10881E-04 -4.9633 0.99642E+00 -0.0016 54 KCl,aq 0.28058E-09 -9.5519 0.28058E-09 -9.5519 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10303E-14 -14.9870 0.85910E-15 -15.0660 0.83382E+00 -0.0789 58 MgCO3,aq 0.10459E-13 -13.9805 0.10459E-13 -13.9805 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.86080E-16 -16.0651 0.71915E-16 -16.1432 0.83544E+00 -0.0781 60 MgCl+ 0.23583E-14 -14.6274 0.19702E-14 -14.7055 0.83544E+00 -0.0781 61 MgOH+ 0.71554E-10 -10.1454 0.59780E-10 -10.2234 0.83544E+00 -0.0781 63 MnO,aq 0.18106E-08 -8.7422 0.18106E-08 -8.7422 0.10000E+01 0.0000 64 MnOH+ 0.47878E-09 -9.3199 0.40000E-09 -9.3979 0.83544E+00 -0.0781 65 MnO2-2 0.21211E-10 -10.6734 0.10920E-10 -10.9618 0.51484E+00 -0.2883 66 HMnO2- 0.21487E-09 -9.6678 0.17916E-09 -9.7468 0.83382E+00 -0.0789 69 MnCl+ 0.83740E-14 -14.0771 0.69960E-14 -14.1552 0.83544E+00 -0.0781 71 NaCl,aq 0.65657E-06 -6.1827 0.65657E-06 -6.1827 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95175E-02 -2.0215 0.79213E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16796E-14 -14.7748 0.86472E-15 -15.0631 0.51484E+00 -0.2883 81 H2PO3- 0.15426E-18 -18.8117 0.12862E-18 -18.8907 0.83382E+00 -0.0789 82 H3PO4,aq 0.92884E-18 -18.0321 0.92884E-18 -18.0321 0.10000E+01 0.0000 83 H2PO4- 0.40023E-10 -10.3977 0.33404E-10 -10.4762 0.83462E+00 -0.0785 84 PO4-3 0.12125E-08 -8.9163 0.29018E-09 -9.5373 0.23932E+00 -0.6210 88 HP2O7-3 0.10378E-17 -17.9839 0.23648E-18 -18.6262 0.22786E+00 -0.6423 89 P2O7-4 0.10252E-16 -16.9892 0.77041E-18 -18.1133 0.75145E-01 -1.1241 90 H2S,aq 0.49836E-08 -8.3025 0.49658E-08 -8.3040 0.99642E+00 -0.0016 91 S2-2 0.18704E-14 -14.7281 0.96292E-15 -15.0164 0.51484E+00 -0.2883 97 SO3-2 0.11745E-17 -17.9302 0.61359E-18 -18.2121 0.52244E+00 -0.2820 99 HSO4- 0.34748E-19 -19.4591 0.29059E-19 -19.5367 0.83627E+00 -0.0777 Charge balance for all species = 0.3745E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9025834E-10 -.2312492E-01 -.2326634E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981189E+06 0.0000 3 Cl- 0.1409568E-03 0.1416137E-03 0.5011542E+01 6.1909 4 SO4-- 0.8016009E-12 -.1528227E-04 -.1465382E+01 7.8581 5 HCO3- 0.2892419E-06 0.1341476E-04 0.8170496E+00 3.5037 6 HS- 0.2617224E-04 0.4145950E-04 0.1368667E+01 5.4597 7 Al+++ 0.1101243E-28 0.5283916E-05 0.1423099E+00 0.7614 8 H4SiO4 0.7113552E-03 0.1419404E-01 0.1361797E+04 -3.1479 9 Ca++ 0.1431704E-06 0.2431906E-06 0.9728950E-02 13.1067 10 Mg++ 0.2273485E-10 0.9784700E-10 0.2374550E-05 9.3055 11 Fe++ 0.6217056E-13 0.3792878E-07 0.2114375E-02 6.7429 12 K+ 0.1614184E-03 0.1621948E-03 0.6330663E+01 6.2505 13 Na+ 0.2052194E-01 0.2311233E-01 0.5303861E+03 8.3540 14 Mn++ 0.1925797E-10 0.2544731E-08 0.1395494E-03 9.2343 15 HPO4-- 0.4875918E-07 0.5001173E-07 0.4791387E-02 12.6423 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3974014E+01 -.2253061E-01 -.3951483E+01 0.0000000E+00 2 H2O 0.5249976E+02 0.5407795E+02 -.1578187E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6676695E-02 -.1488951E-04 0.6691584E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6651190E-02 0.4039398E-04 -.6691584E-02 0.0000000E+00 7 Al+++ 0.7825747E+00 0.5148119E-05 0.7825696E+00 0.0000000E+00 8 H4SiO4 0.2499057E+01 0.1382925E-01 0.2485228E+01 0.0000000E+00 9 Ca++ 0.2760476E+00 0.2369406E-06 0.2760473E+00 0.0000000E+00 10 Mg++ 0.1904754E+00 0.9533233E-10 0.1904754E+00 0.0000000E+00 11 Fe++ 0.1711213E+00 0.3695401E-07 0.1711213E+00 0.0000000E+00 12 K+ 0.5095520E-01 0.1580264E-03 0.5079718E-01 0.0000000E+00 13 Na+ 0.3014173E+00 0.2251834E-01 0.2788989E+00 0.0000000E+00 14 Mn++ 0.4161246E-02 0.2479332E-08 0.4161243E-02 0.0000000E+00 15 HPO4-- 0.1420212E-02 0.4872642E-07 0.1420164E-02 0.0000000E+00 Chg. balance for solid moles: -.2862E-16 Mass of aqueous solution: 0.976067E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 239.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2786 -0.555 73.05 1.864 27.88 28.04 andradite 0.2677E-01 -1.572 13.60 1.134 5.192 3.534 grossular 0.6401E-02 -2.194 2.883 0.460 1.100 0.8022 apatite-OH 0.4734E-03 -3.325 0.2378 -0.624 0.9076E-01 0.7556E-01 clinochlore 0.3548E-01 -1.450 19.72 1.295 7.527 7.501 daphnite 0.1016E-01 -1.993 7.253 0.860 2.768 2.198 chlorite-Mn 0.8322E-03 -3.080 0.5900 -0.229 0.2252 0.1880 diopside 0.4391E-02 -2.357 0.9508 -0.022 0.3629 0.2906 hedenbergite 0.1124E-02 -2.949 0.2790 -0.554 0.1065 0.7641E-01 microcline 0.4453E-01 -1.351 12.40 1.093 4.731 4.842 stilbite 0.1639 -0.786 115.5 2.063 44.08 53.86 stilpnomelane-Fe 0.1253E-01 -1.902 13.51 1.131 5.155 4.665 tr.625ac.25prg.125 0.2399E-02 -2.620 2.051 0.312 0.7827 0.6600 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8070E+00 0.8070E+00 1.0000 -0.093 grossular 0.1930E+00 0.1930E+00 1.0000 -0.714 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7634E+00 0.7634E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1791E-01 0.1791E-01 1.0000 -1.747 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 261.999889 g Volume = 106.737693 cm3 Porosity: -10.0393% V(tot) - V(min): -.97381E+01 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 239.9990000 g log = 2.3802 Original solution: 1000.0103000 g Original solution / Rock added: 4.17 (Water/Rock Ratio), log = 0.6198 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0869 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9683E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3856E-08 1.0071 0.4221E-08 0.4191E-08 CH4,gas 0.1797E-01 1.0128 0.1978E-01 0.1953E-01 H2,gas 0.1372E-01 1.0006 0.1492E-01 0.1492E-01 H2S,gas 0.1338E-06 0.9958 0.1448E-06 0.1454E-06 S2,gas 0.3246E-29 1.0000 0.3528E-29 0.3528E-29 CO,gas 0.1501E-13 1.0000 0.1632E-13 0.1632E-13 SO3,gas 0.8157E-48 1.0000 0.8866E-48 0.8866E-48 SO2,gas 0.4605E-27 1.0000 0.5006E-27 0.5006E-27 HCl,gas 0.2720E-17 1.0000 0.2956E-17 0.2956E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 -0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.18198E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 -0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 -0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.74 -10.37 -3.458 0.17714E+05 -8.375 3 CH4,gas 4.81 1.11 -3.70 -0.926 0.63241E+04 -1.704 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65330E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.420 0.15093E+05 -6.839 6 S2,gas -7.03 -38.49 -31.45 -4.839 0.53704E+05 -29.453 7 CO,gas 3.51 -12.28 -15.79 -4.858 0.26956E+05 -13.787 8 SO3,gas 17.43 -32.62 -50.05 -12.513 0.85463E+05 -48.052 9 SO2,gas 1.14 -28.16 -29.30 -7.813 0.50030E+05 -27.301 10 HCl,gas 5.48 -14.05 -19.53 -9.765 0.33346E+05 -17.529 11 acmite 7.74 6.57 -1.17 -0.121 0.19921E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.78 -4.77 -0.238 0.81411E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94096E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41191E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28374E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76221E+04 35 aragonite 0.99 -3.63 -4.62 -1.539 0.78839E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55852E+04 37 calcite 0.83 -3.63 -4.46 -1.488 0.76225E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52882E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71151E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70311E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82181E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47361E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39554E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68642E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70363E+04 52 chloritoid-Mn 11.46 7.61 -3.85 -0.257 0.65806E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13294E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10223E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36449E+04 66 diamond -3.11 -7.82 -4.71 -1.345 0.80403E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.81 -1.97 -0.096 0.33640E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66032E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57723E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68259E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56961E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36650E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70706E+04 86 graphite -3.55 -7.82 -4.27 -1.219 0.72865E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38611E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.61001E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24440E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64136E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59759E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15993E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22960E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58934E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28457E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74528E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48213E+04 112 manganosite 14.07 9.23 -4.83 -1.208 0.82533E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61267E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53652E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41161E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83602E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36593E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20042E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92736E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40658E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.056 0.43405E+04 143 pyrrhotite -4.24 -8.04 -3.80 -1.265 0.64804E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.263 0.58633E+04 145 pyroxmangite 7.42 6.09 -1.33 -0.266 0.22703E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84875E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28329E+03 152 rhodonite 7.46 6.09 -1.38 -0.275 0.23496E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27384E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20975E+04 174 tephroite 18.11 15.32 -2.79 -0.399 0.47676E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91059E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76039E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65768E+04 181 troilite-low -4.39 -8.04 -3.64 -1.215 0.62236E+04 183 vesuvianite 224.06 219.35 -4.70 -0.036 0.80320E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34501E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66757E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55582E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60361E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66124E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68736E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73630E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60305E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57944E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83193E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61771E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66256E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52975E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.55 -4.59 -1.528 0.78289E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62634E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52612E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18238E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11528E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14889E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18334E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 239.9990000 g New total amount of reactant added: 249.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3651E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 249.9990000 Water: Moles liquid = 0.5403E+02 kg liquid = 0.9733E+00 Moles total = 0.5237E+02 kg total = 0.9435E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173039E-01 Osmotic coef. = 0.9690 True ionic strength = .2068471E-01 Chg. balance for total moles = 0.3651E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90259E-10 -10.0445 0.75725E-10 -10.1208 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14110E-03 -3.8505 0.11765E-03 -3.9294 0.83382E+00 -0.0789 4 SO4-- 0.80255E-12 -12.0955 0.41408E-12 -12.3829 0.51595E+00 -0.2874 5 HCO3- 0.28958E-06 -6.5382 0.24182E-06 -6.6165 0.83506E+00 -0.0783 6 HS- 0.26199E-04 -4.5817 0.21849E-04 -4.6606 0.83394E+00 -0.0789 7 Al+++ 0.11012E-28 -28.9581 0.25066E-29 -29.6009 0.22762E+00 -0.6428 8 H4SiO4 0.71137E-03 -3.1479 0.71137E-03 -3.1479 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73315E-07 -7.1348 0.51208E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50969E+00 -0.2927 11 Fe++ 0.62171E-13 -13.2064 0.31724E-13 -13.4986 0.51026E+00 -0.2922 12 K+ 0.16142E-03 -3.7920 0.13483E-03 -3.8702 0.83526E+00 -0.0782 13 Na+ 0.20522E-01 -1.6878 0.17108E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.19287E-10 -10.7147 0.98499E-11 -11.0066 0.51069E+00 -0.2918 15 HPO4-- 0.48760E-07 -7.3119 0.25161E-07 -7.5993 0.51603E+00 -0.2873 16 HSiO3- 0.10992E-01 -1.9589 0.91656E-02 -2.0378 0.83382E+00 -0.0789 17 Ca(HSiO3)+ 0.18021E-07 -7.7442 0.15056E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35448E-11 -11.4504 0.29615E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24905E-02 -2.6037 0.24905E-02 -2.6037 0.10000E+01 0.0000 20 AlO+ 0.67548E-16 -16.1704 0.56432E-16 -16.2485 0.83544E+00 -0.0781 22 HAlO2,aq 0.14913E-09 -9.8264 0.14913E-09 -9.8264 0.10000E+01 0.0000 23 AlO2- 0.52834E-05 -5.2771 0.43974E-05 -5.3568 0.83229E+00 -0.0797 24 CH4,aq 0.12565E-04 -4.9008 0.12520E-04 -4.9024 0.99642E+00 -0.0016 25 C2H6,aq 0.24936E-14 -14.6032 0.24847E-14 -14.6047 0.99642E+00 -0.0016 29 CO,aq 0.10346E-16 -16.9852 0.10346E-16 -16.9852 0.10000E+01 0.0000 30 CO2,aq 0.37052E-10 -10.4312 0.36920E-10 -10.4327 0.99642E+00 -0.0016 31 CO3-2 0.57350E-06 -6.2415 0.29526E-06 -6.5298 0.51483E+00 -0.2883 32 CaCO3,aq 0.26512E-09 -9.5766 0.26512E-09 -9.5766 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53471E-12 -12.2719 0.44672E-12 -12.3500 0.83544E+00 -0.0781 34 CaCl+ 0.16453E-10 -10.7838 0.13745E-10 -10.8619 0.83544E+00 -0.0781 35 CaCl2,aq 0.37653E-15 -15.4242 0.37653E-15 -15.4242 0.10000E+01 0.0000 36 CaOH+ 0.81717E-07 -7.0877 0.68269E-07 -7.1658 0.83544E+00 -0.0781 37 CaSO4,aq 0.94589E-17 -17.0242 0.94589E-17 -17.0242 0.10000E+01 0.0000 38 HCl,aq 0.16758E-14 -14.7758 0.16758E-14 -14.7758 0.10000E+01 0.0000 43 FeCl+ 0.69583E-17 -17.1575 0.58133E-17 -17.2356 0.83544E+00 -0.0781 46 FeO,aq 0.21877E-09 -9.6600 0.21877E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16624E-10 -10.7793 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37268E-07 -7.4287 0.31075E-07 -7.5076 0.83382E+00 -0.0789 49 FeO+ 0.12265E-16 -16.9113 0.10247E-16 -16.9894 0.83544E+00 -0.0781 51 FeO2- 0.42120E-09 -9.3755 0.35120E-09 -9.4544 0.83382E+00 -0.0789 52 HFeO2,aq 0.33283E-11 -11.4778 0.33283E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10919E-04 -4.9618 0.10880E-04 -4.9634 0.99642E+00 -0.0016 54 KCl,aq 0.28088E-09 -9.5515 0.28088E-09 -9.5515 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10316E-14 -14.9865 0.86012E-15 -15.0654 0.83382E+00 -0.0789 58 MgCO3,aq 0.10471E-13 -13.9800 0.10471E-13 -13.9800 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.86181E-16 -16.0646 0.71999E-16 -16.1427 0.83544E+00 -0.0781 60 MgCl+ 0.23607E-14 -14.6270 0.19722E-14 -14.7050 0.83544E+00 -0.0781 61 MgOH+ 0.71554E-10 -10.1454 0.59779E-10 -10.2235 0.83544E+00 -0.0781 63 MnO,aq 0.18133E-08 -8.7415 0.18133E-08 -8.7415 0.10000E+01 0.0000 64 MnOH+ 0.47951E-09 -9.3192 0.40060E-09 -9.3973 0.83544E+00 -0.0781 65 MnO2-2 0.21242E-10 -10.6728 0.10936E-10 -10.9611 0.51483E+00 -0.2883 66 HMnO2- 0.21519E-09 -9.6672 0.17943E-09 -9.7461 0.83382E+00 -0.0789 69 MnCl+ 0.83953E-14 -14.0760 0.70138E-14 -14.1540 0.83544E+00 -0.0781 71 NaCl,aq 0.65725E-06 -6.1823 0.65725E-06 -6.1823 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95175E-02 -2.0215 0.79213E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16796E-14 -14.7748 0.86469E-15 -15.0631 0.51483E+00 -0.2883 81 H2PO3- 0.15426E-18 -18.8118 0.12862E-18 -18.8907 0.83382E+00 -0.0789 82 H3PO4,aq 0.92887E-18 -18.0320 0.92887E-18 -18.0320 0.10000E+01 0.0000 83 H2PO4- 0.40023E-10 -10.3977 0.33404E-10 -10.4762 0.83462E+00 -0.0785 84 PO4-3 0.12125E-08 -8.9163 0.29018E-09 -9.5373 0.23932E+00 -0.6210 88 HP2O7-3 0.10378E-17 -17.9839 0.23649E-18 -18.6262 0.22786E+00 -0.6423 89 P2O7-4 0.10253E-16 -16.9892 0.77043E-18 -18.1133 0.75144E-01 -1.1241 90 H2S,aq 0.49888E-08 -8.3020 0.49710E-08 -8.3036 0.99642E+00 -0.0016 91 S2-2 0.18743E-14 -14.7272 0.96495E-15 -15.0155 0.51483E+00 -0.2883 97 SO3-2 0.11758E-17 -17.9297 0.61429E-18 -18.2116 0.52243E+00 -0.2820 99 HSO4- 0.34790E-19 -19.4585 0.29094E-19 -19.5362 0.83627E+00 -0.0777 Charge balance for all species = 0.3751E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9025921E-10 -.2312498E-01 -.2326641E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981188E+06 0.0000 3 Cl- 0.1411023E-03 0.1417598E-03 0.5016715E+01 6.1914 4 SO4-- 0.8025520E-12 -.1529500E-04 -.1466603E+01 7.8586 5 HCO3- 0.2895820E-06 0.1342861E-04 0.8178929E+00 3.5043 6 HS- 0.2619926E-04 0.4149925E-04 0.1369979E+01 5.4602 7 Al+++ 0.1101221E-28 0.5283597E-05 0.1423013E+00 0.7614 8 H4SiO4 0.7113676E-03 0.1419420E-01 0.1361811E+04 -3.1479 9 Ca++ 0.1431708E-06 0.2431908E-06 0.9728958E-02 13.1067 10 Mg++ 0.2273487E-10 0.9784634E-10 0.2374534E-05 9.3055 11 Fe++ 0.6217140E-13 0.3792821E-07 0.2114343E-02 6.7429 12 K+ 0.1614199E-03 0.1621964E-03 0.6330722E+01 6.2505 13 Na+ 0.2052213E-01 0.2311257E-01 0.5303915E+03 8.3540 14 Mn++ 0.1928722E-10 0.2548548E-08 0.1397587E-03 9.2350 15 HPO4-- 0.4875987E-07 0.5001243E-07 0.4791455E-02 12.6423 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4139599E+01 -.2250744E-01 -.4117092E+01 0.0000000E+00 2 H2O 0.5237441E+02 0.5402219E+02 -.1647777E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6953829E-02 -.1488655E-04 0.6968716E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6928325E-02 0.4039102E-04 -.6968716E-02 0.0000000E+00 7 Al+++ 0.8151821E+00 0.5142500E-05 0.8151770E+00 0.0000000E+00 8 H4SiO4 0.2603185E+01 0.1381514E-01 0.2589370E+01 0.0000000E+00 9 Ca++ 0.2875490E+00 0.2366964E-06 0.2875487E+00 0.0000000E+00 10 Mg++ 0.1984119E+00 0.9523338E-10 0.1984119E+00 0.0000000E+00 11 Fe++ 0.1782514E+00 0.3691535E-07 0.1782514E+00 0.0000000E+00 12 K+ 0.5307834E-01 0.1578649E-03 0.5292048E-01 0.0000000E+00 13 Na+ 0.3139697E+00 0.2249535E-01 0.2914744E+00 0.0000000E+00 14 Mn++ 0.4334632E-02 0.2480489E-08 0.4334629E-02 0.0000000E+00 15 HPO4-- 0.1479388E-02 0.4867686E-07 0.1479340E-02 0.0000000E+00 Chg. balance for solid moles: -.3123E-16 Mass of aqueous solution: 0.975060E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 249.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.2912 -0.536 76.35 1.883 27.97 29.31 andradite 0.2787E-01 -1.555 14.17 1.151 5.190 3.680 grossular 0.6666E-02 -2.176 3.002 0.477 1.100 0.8354 apatite-OH 0.4931E-03 -3.307 0.2477 -0.606 0.9076E-01 0.7871E-01 clinochlore 0.3690E-01 -1.433 20.51 1.312 7.515 7.801 daphnite 0.1057E-01 -1.976 7.544 0.878 2.764 2.286 chlorite-Mn 0.8669E-03 -3.062 0.6146 -0.211 0.2252 0.1959 diopside 0.4969E-02 -2.304 1.076 0.032 0.3943 0.3289 hedenbergite 0.1273E-02 -2.895 0.3157 -0.501 0.1157 0.8648E-01 microcline 0.4639E-01 -1.334 12.91 1.111 4.731 5.044 stilbite 0.1703 -0.769 120.0 2.079 43.97 55.97 stilpnomelane-Fe 0.1306E-01 -1.884 14.07 1.148 5.157 4.862 tr.625ac.25prg.125 0.2467E-02 -2.608 2.109 0.324 0.7727 0.6788 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8070E+00 0.8070E+00 1.0000 -0.093 grossular 0.1930E+00 0.1930E+00 1.0000 -0.714 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7634E+00 0.7634E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1793E-01 0.1793E-01 1.0000 -1.746 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 272.925427 g Volume = 111.158328 cm3 Porosity: -10.0582% V(tot) - V(min): -.10159E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 249.9990000 g log = 2.3979 Original solution: 1000.0103000 g Original solution / Rock added: 4.00 (Water/Rock Ratio), log = 0.6021 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0869 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9683E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3861E-08 1.0071 0.4226E-08 0.4196E-08 CH4,gas 0.1799E-01 1.0128 0.1980E-01 0.1955E-01 H2,gas 0.1372E-01 1.0006 0.1492E-01 0.1491E-01 H2S,gas 0.1340E-06 0.9958 0.1450E-06 0.1456E-06 S2,gas 0.3253E-29 1.0000 0.3535E-29 0.3535E-29 CO,gas 0.1503E-13 1.0000 0.1634E-13 0.1634E-13 SO3,gas 0.8167E-48 1.0000 0.8877E-48 0.8877E-48 SO2,gas 0.4611E-27 1.0000 0.5011E-27 0.5011E-27 HCl,gas 0.2722E-17 1.0000 0.2959E-17 0.2959E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.74 -10.37 -3.458 0.17713E+05 -8.374 3 CH4,gas 4.81 1.11 -3.70 -0.926 0.63234E+04 -1.703 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65330E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.419 0.15092E+05 -6.839 6 S2,gas -7.03 -38.48 -31.45 -4.839 0.53703E+05 -29.452 7 CO,gas 3.51 -12.28 -15.79 -4.857 0.26956E+05 -13.787 8 SO3,gas 17.43 -32.62 -50.05 -12.513 0.85462E+05 -48.052 9 SO2,gas 1.14 -28.16 -29.30 -7.813 0.50029E+05 -27.300 10 HCl,gas 5.48 -14.05 -19.53 -9.764 0.33345E+05 -17.529 11 acmite 7.74 6.57 -1.17 -0.121 0.19921E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.78 -4.77 -0.238 0.81378E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94098E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41191E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28375E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76222E+04 35 aragonite 0.99 -3.63 -4.62 -1.539 0.78830E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55853E+04 37 calcite 0.83 -3.63 -4.46 -1.488 0.76217E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52882E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71151E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70312E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82181E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47361E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39555E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68642E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70363E+04 52 chloritoid-Mn 11.46 7.61 -3.85 -0.257 0.65796E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13294E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10222E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36450E+04 66 diamond -3.11 -7.82 -4.71 -1.345 0.80395E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.81 -1.97 -0.096 0.33640E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66033E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57723E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68259E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56961E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36650E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70706E+04 86 graphite -3.55 -7.82 -4.27 -1.219 0.72857E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38611E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.61000E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24440E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64137E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59760E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15994E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22960E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58934E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28457E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74528E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48212E+04 112 manganosite 14.07 9.23 -4.83 -1.208 0.82522E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61268E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53653E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41162E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83602E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36594E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20043E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92737E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40660E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.056 0.43407E+04 143 pyrrhotite -4.24 -8.04 -3.79 -1.265 0.64796E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.263 0.58625E+04 145 pyroxmangite 7.42 6.09 -1.33 -0.266 0.22692E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84876E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28328E+03 152 rhodonite 7.46 6.09 -1.38 -0.275 0.23484E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27385E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20975E+04 174 tephroite 18.11 15.32 -2.79 -0.399 0.47654E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91057E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76039E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65767E+04 181 troilite-low -4.39 -8.04 -3.64 -1.215 0.62228E+04 183 vesuvianite 224.06 219.35 -4.70 -0.036 0.80324E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34502E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66758E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55582E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60360E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66125E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68737E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73631E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60305E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57944E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83192E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61770E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66256E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52974E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.55 -4.58 -1.528 0.78270E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62634E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52612E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18238E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11528E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14889E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18334E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 249.9990000 g New total amount of reactant added: 259.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3650E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 259.9990000 Water: Moles liquid = 0.5397E+02 kg liquid = 0.9723E+00 Moles total = 0.5225E+02 kg total = 0.9413E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173058E-01 Osmotic coef. = 0.9690 True ionic strength = .2068489E-01 Chg. balance for total moles = 0.3650E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90260E-10 -10.0445 0.75725E-10 -10.1208 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14125E-03 -3.8500 0.11777E-03 -3.9289 0.83382E+00 -0.0789 4 SO4-- 0.80350E-12 -12.0950 0.41456E-12 -12.3824 0.51595E+00 -0.2874 5 HCO3- 0.28992E-06 -6.5377 0.24210E-06 -6.6160 0.83506E+00 -0.0783 6 HS- 0.26226E-04 -4.5813 0.21871E-04 -4.6601 0.83394E+00 -0.0789 7 Al+++ 0.11012E-28 -28.9581 0.25066E-29 -29.6009 0.22762E+00 -0.6428 8 H4SiO4 0.71138E-03 -3.1479 0.71138E-03 -3.1479 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73315E-07 -7.1348 0.51208E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50969E+00 -0.2927 11 Fe++ 0.62172E-13 -13.2064 0.31724E-13 -13.4986 0.51026E+00 -0.2922 12 K+ 0.16142E-03 -3.7920 0.13483E-03 -3.8702 0.83526E+00 -0.0782 13 Na+ 0.20522E-01 -1.6878 0.17109E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.19314E-10 -10.7141 0.98637E-11 -11.0060 0.51069E+00 -0.2918 15 HPO4-- 0.48760E-07 -7.3119 0.25162E-07 -7.5993 0.51603E+00 -0.2873 16 HSiO3- 0.10992E-01 -1.9589 0.91656E-02 -2.0378 0.83382E+00 -0.0789 17 Ca(HSiO3)+ 0.18022E-07 -7.7442 0.15056E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35449E-11 -11.4504 0.29615E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24905E-02 -2.6037 0.24905E-02 -2.6037 0.10000E+01 0.0000 20 AlO+ 0.67545E-16 -16.1704 0.56430E-16 -16.2485 0.83544E+00 -0.0781 22 HAlO2,aq 0.14912E-09 -9.8265 0.14912E-09 -9.8265 0.10000E+01 0.0000 23 AlO2- 0.52832E-05 -5.2771 0.43971E-05 -5.3568 0.83229E+00 -0.0797 24 CH4,aq 0.12578E-04 -4.9004 0.12533E-04 -4.9019 0.99642E+00 -0.0016 25 C2H6,aq 0.24988E-14 -14.6023 0.24899E-14 -14.6038 0.99642E+00 -0.0016 29 CO,aq 0.10358E-16 -16.9847 0.10358E-16 -16.9847 0.10000E+01 0.0000 30 CO2,aq 0.37096E-10 -10.4307 0.36963E-10 -10.4322 0.99642E+00 -0.0016 31 CO3-2 0.57417E-06 -6.2410 0.29560E-06 -6.5293 0.51483E+00 -0.2883 32 CaCO3,aq 0.26543E-09 -9.5760 0.26543E-09 -9.5760 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53533E-12 -12.2714 0.44724E-12 -12.3495 0.83544E+00 -0.0781 34 CaCl+ 0.16470E-10 -10.7833 0.13759E-10 -10.8614 0.83544E+00 -0.0781 35 CaCl2,aq 0.37731E-15 -15.4233 0.37731E-15 -15.4233 0.10000E+01 0.0000 36 CaOH+ 0.81716E-07 -7.0877 0.68269E-07 -7.1658 0.83544E+00 -0.0781 37 CaSO4,aq 0.94700E-17 -17.0236 0.94700E-17 -17.0236 0.10000E+01 0.0000 38 HCl,aq 0.16775E-14 -14.7753 0.16775E-14 -14.7753 0.10000E+01 0.0000 43 FeCl+ 0.69656E-17 -17.1570 0.58193E-17 -17.2351 0.83544E+00 -0.0781 46 FeO,aq 0.21877E-09 -9.6600 0.21877E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16625E-10 -10.7793 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37268E-07 -7.4287 0.31074E-07 -7.5076 0.83382E+00 -0.0789 49 FeO+ 0.12265E-16 -16.9113 0.10247E-16 -16.9894 0.83544E+00 -0.0781 51 FeO2- 0.42120E-09 -9.3755 0.35120E-09 -9.4544 0.83382E+00 -0.0789 52 HFeO2,aq 0.33284E-11 -11.4778 0.33284E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10919E-04 -4.9618 0.10880E-04 -4.9634 0.99642E+00 -0.0016 54 KCl,aq 0.28117E-09 -9.5510 0.28117E-09 -9.5510 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10328E-14 -14.9860 0.86114E-15 -15.0649 0.83382E+00 -0.0789 58 MgCO3,aq 0.10483E-13 -13.9795 0.10483E-13 -13.9795 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.86281E-16 -16.0641 0.72083E-16 -16.1422 0.83544E+00 -0.0781 60 MgCl+ 0.23631E-14 -14.6265 0.19743E-14 -14.7046 0.83544E+00 -0.0781 61 MgOH+ 0.71553E-10 -10.1454 0.59778E-10 -10.2235 0.83544E+00 -0.0781 63 MnO,aq 0.18158E-08 -8.7409 0.18158E-08 -8.7409 0.10000E+01 0.0000 64 MnOH+ 0.48017E-09 -9.3186 0.40116E-09 -9.3967 0.83544E+00 -0.0781 65 MnO2-2 0.21271E-10 -10.6722 0.10951E-10 -10.9605 0.51483E+00 -0.2883 66 HMnO2- 0.21548E-09 -9.6666 0.17967E-09 -9.7455 0.83382E+00 -0.0789 69 MnCl+ 0.84158E-14 -14.0749 0.70309E-14 -14.1530 0.83544E+00 -0.0781 71 NaCl,aq 0.65794E-06 -6.1818 0.65794E-06 -6.1818 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95174E-02 -2.0215 0.79212E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16795E-14 -14.7748 0.86467E-15 -15.0631 0.51483E+00 -0.2883 81 H2PO3- 0.15425E-18 -18.8118 0.12862E-18 -18.8907 0.83382E+00 -0.0789 82 H3PO4,aq 0.92890E-18 -18.0320 0.92890E-18 -18.0320 0.10000E+01 0.0000 83 H2PO4- 0.40024E-10 -10.3977 0.33405E-10 -10.4762 0.83462E+00 -0.0785 84 PO4-3 0.12125E-08 -8.9163 0.29018E-09 -9.5373 0.23932E+00 -0.6210 88 HP2O7-3 0.10379E-17 -17.9839 0.23649E-18 -18.6262 0.22786E+00 -0.6423 89 P2O7-4 0.10253E-16 -16.9891 0.77045E-18 -18.1133 0.75144E-01 -1.1241 90 H2S,aq 0.49940E-08 -8.3016 0.49762E-08 -8.3031 0.99642E+00 -0.0016 91 S2-2 0.18782E-14 -14.7262 0.96698E-15 -15.0146 0.51483E+00 -0.2883 97 SO3-2 0.11772E-17 -17.9292 0.61499E-18 -18.2111 0.52243E+00 -0.2820 99 HSO4- 0.34831E-19 -19.4580 0.29128E-19 -19.5357 0.83627E+00 -0.0777 Charge balance for all species = 0.3753E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9026003E-10 -.2312504E-01 -.2326646E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981188E+06 0.0000 3 Cl- 0.1412481E-03 0.1419063E-03 0.5021898E+01 6.1918 4 SO4-- 0.8034957E-12 -.1530777E-04 -.1467827E+01 7.8591 5 HCO3- 0.2899196E-06 0.1344248E-04 0.8187381E+00 3.5048 6 HS- 0.2622633E-04 0.4153909E-04 0.1371294E+01 5.4606 7 Al+++ 0.1101203E-28 0.5283301E-05 0.1422933E+00 0.7614 8 H4SiO4 0.7113790E-03 0.1419434E-01 0.1361825E+04 -3.1479 9 Ca++ 0.1431712E-06 0.2431911E-06 0.9728972E-02 13.1067 10 Mg++ 0.2273491E-10 0.9784576E-10 0.2374520E-05 9.3055 11 Fe++ 0.6217222E-13 0.3792767E-07 0.2114313E-02 6.7429 12 K+ 0.1614213E-03 0.1621978E-03 0.6330779E+01 6.2505 13 Na+ 0.2052232E-01 0.2311279E-01 0.5303967E+03 8.3540 14 Mn++ 0.1931432E-10 0.2552081E-08 0.1399524E-03 9.2356 15 HPO4-- 0.4876049E-07 0.5001305E-07 0.4791514E-02 12.6423 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4305184E+01 -.2248425E-01 -.4282700E+01 0.0000000E+00 2 H2O 0.5224906E+02 0.5396642E+02 -.1717366E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7230963E-02 -.1488360E-04 0.7245847E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7205459E-02 0.4038807E-04 -.7245847E-02 0.0000000E+00 7 Al+++ 0.8477896E+00 0.5136903E-05 0.8477844E+00 0.0000000E+00 8 H4SiO4 0.2707313E+01 0.1380102E-01 0.2693512E+01 0.0000000E+00 9 Ca++ 0.2990504E+00 0.2364524E-06 0.2990502E+00 0.0000000E+00 10 Mg++ 0.2063484E+00 0.9513451E-10 0.2063484E+00 0.0000000E+00 11 Fe++ 0.1853815E+00 0.3687672E-07 0.1853815E+00 0.0000000E+00 12 K+ 0.5520149E-01 0.1577034E-03 0.5504378E-01 0.0000000E+00 13 Na+ 0.3265222E+00 0.2247235E-01 0.3040498E+00 0.0000000E+00 14 Mn++ 0.4508018E-02 0.2481364E-08 0.4508015E-02 0.0000000E+00 15 HPO4-- 0.1538564E-02 0.4862722E-07 0.1538515E-02 0.0000000E+00 Chg. balance for solid moles: -.2125E-15 Mass of aqueous solution: 0.974054E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 259.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3037 -0.518 79.64 1.901 28.06 30.57 andradite 0.2898E-01 -1.538 14.73 1.168 5.189 3.827 grossular 0.6930E-02 -2.159 3.122 0.494 1.100 0.8686 apatite-OH 0.5128E-03 -3.290 0.2576 -0.589 0.9076E-01 0.8186E-01 clinochlore 0.3832E-01 -1.417 21.30 1.328 7.504 8.102 daphnite 0.1098E-01 -1.959 7.834 0.894 2.760 2.374 chlorite-Mn 0.9016E-03 -3.045 0.6392 -0.194 0.2252 0.2037 diopside 0.5547E-02 -2.256 1.201 0.080 0.4232 0.3672 hedenbergite 0.1421E-02 -2.847 0.3525 -0.453 0.1242 0.9655E-01 microcline 0.4825E-01 -1.316 13.43 1.128 4.731 5.246 stilbite 0.1767 -0.753 124.5 2.095 43.87 58.08 stilpnomelane-Fe 0.1358E-01 -1.867 14.64 1.166 5.159 5.058 tr.625ac.25prg.125 0.2536E-02 -2.596 2.167 0.336 0.7635 0.6975 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8070E+00 0.8070E+00 1.0000 -0.093 grossular 0.1930E+00 0.1930E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7633E+00 0.7633E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1796E-01 0.1796E-01 1.0000 -1.746 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 283.850967 g Volume = 115.578964 cm3 Porosity: -10.0756% V(tot) - V(min): -.10579E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 259.9990000 g log = 2.4150 Original solution: 1000.0103000 g Original solution / Rock added: 3.85 (Water/Rock Ratio), log = 0.5850 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0869 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9683E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3865E-08 1.0071 0.4231E-08 0.4201E-08 CH4,gas 0.1800E-01 1.0128 0.1982E-01 0.1957E-01 H2,gas 0.1372E-01 1.0006 0.1492E-01 0.1491E-01 H2S,gas 0.1341E-06 0.9958 0.1451E-06 0.1457E-06 S2,gas 0.3260E-29 1.0000 0.3543E-29 0.3543E-29 CO,gas 0.1505E-13 1.0000 0.1635E-13 0.1635E-13 SO3,gas 0.8177E-48 1.0000 0.8887E-48 0.8887E-48 SO2,gas 0.4616E-27 1.0000 0.5017E-27 0.5017E-27 HCl,gas 0.2725E-17 1.0000 0.2962E-17 0.2962E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.54595E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.74 -10.37 -3.458 0.17713E+05 -8.374 3 CH4,gas 4.81 1.11 -3.70 -0.926 0.63226E+04 -1.703 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65331E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.419 0.15091E+05 -6.838 6 S2,gas -7.03 -38.48 -31.45 -4.839 0.53701E+05 -29.451 7 CO,gas 3.51 -12.28 -15.79 -4.857 0.26955E+05 -13.786 8 SO3,gas 17.43 -32.62 -50.05 -12.513 0.85461E+05 -48.051 9 SO2,gas 1.14 -28.16 -29.30 -7.813 0.50028E+05 -27.300 10 HCl,gas 5.48 -14.05 -19.53 -9.764 0.33344E+05 -17.528 11 acmite 7.74 6.57 -1.17 -0.121 0.19921E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.79 -4.76 -0.238 0.81347E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94099E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41191E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28375E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76222E+04 35 aragonite 0.99 -3.63 -4.62 -1.539 0.78822E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55853E+04 37 calcite 0.83 -3.63 -4.46 -1.488 0.76208E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52882E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71151E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70313E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82182E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47361E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39555E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68643E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70364E+04 52 chloritoid-Mn 11.46 7.61 -3.85 -0.257 0.65786E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13294E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10222E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36450E+04 66 diamond -3.11 -7.82 -4.71 -1.345 0.80387E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33641E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66034E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57723E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68259E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56962E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36651E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70706E+04 86 graphite -3.55 -7.82 -4.27 -1.219 0.72849E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38611E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.61000E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24440E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64137E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59760E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15994E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22961E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58934E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28458E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74528E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48212E+04 112 manganosite 14.07 9.24 -4.83 -1.208 0.82512E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61269E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53653E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41162E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83602E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36594E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20044E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92739E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40661E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.056 0.43408E+04 143 pyrrhotite -4.24 -8.04 -3.79 -1.265 0.64789E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.263 0.58617E+04 145 pyroxmangite 7.42 6.09 -1.33 -0.266 0.22682E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84876E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28327E+03 152 rhodonite 7.46 6.09 -1.37 -0.275 0.23474E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27385E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20975E+04 174 tephroite 18.11 15.32 -2.79 -0.399 0.47633E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91056E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76038E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65767E+04 181 troilite-low -4.39 -8.04 -3.64 -1.215 0.62220E+04 183 vesuvianite 224.06 219.35 -4.70 -0.036 0.80329E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34502E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66759E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55582E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60359E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66125E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68737E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73631E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60306E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57943E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83192E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61770E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66255E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52974E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.55 -4.58 -1.528 0.78252E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62634E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18238E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11528E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14889E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18334E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 259.9990000 g New total amount of reactant added: 269.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3649E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 269.9990000 Water: Moles liquid = 0.5391E+02 kg liquid = 0.9713E+00 Moles total = 0.5212E+02 kg total = 0.9390E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173076E-01 Osmotic coef. = 0.9690 True ionic strength = .2068508E-01 Chg. balance for total moles = 0.3649E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90261E-10 -10.0445 0.75726E-10 -10.1208 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14139E-03 -3.8496 0.11790E-03 -3.9285 0.83382E+00 -0.0789 4 SO4-- 0.80443E-12 -12.0945 0.41505E-12 -12.3819 0.51595E+00 -0.2874 5 HCO3- 0.29026E-06 -6.5372 0.24238E-06 -6.6155 0.83506E+00 -0.0783 6 HS- 0.26253E-04 -4.5808 0.21894E-04 -4.6597 0.83394E+00 -0.0789 7 Al+++ 0.11012E-28 -28.9581 0.25065E-29 -29.6009 0.22762E+00 -0.6428 8 H4SiO4 0.71139E-03 -3.1479 0.71139E-03 -3.1479 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73315E-07 -7.1348 0.51208E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50969E+00 -0.2927 11 Fe++ 0.62173E-13 -13.2064 0.31724E-13 -13.4986 0.51026E+00 -0.2922 12 K+ 0.16142E-03 -3.7920 0.13483E-03 -3.8702 0.83526E+00 -0.0782 13 Na+ 0.20522E-01 -1.6878 0.17109E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.19339E-10 -10.7136 0.98765E-11 -11.0054 0.51069E+00 -0.2918 15 HPO4-- 0.48761E-07 -7.3119 0.25162E-07 -7.5993 0.51602E+00 -0.2873 16 HSiO3- 0.10992E-01 -1.9589 0.91657E-02 -2.0378 0.83382E+00 -0.0789 17 Ca(HSiO3)+ 0.18022E-07 -7.7442 0.15056E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35449E-11 -11.4504 0.29615E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24906E-02 -2.6037 0.24906E-02 -2.6037 0.10000E+01 0.0000 20 AlO+ 0.67543E-16 -16.1704 0.56428E-16 -16.2485 0.83544E+00 -0.0781 22 HAlO2,aq 0.14912E-09 -9.8265 0.14912E-09 -9.8265 0.10000E+01 0.0000 23 AlO2- 0.52829E-05 -5.2771 0.43969E-05 -5.3569 0.83229E+00 -0.0797 24 CH4,aq 0.12591E-04 -4.8999 0.12546E-04 -4.9015 0.99642E+00 -0.0016 25 C2H6,aq 0.25040E-14 -14.6014 0.24951E-14 -14.6029 0.99642E+00 -0.0016 29 CO,aq 0.10369E-16 -16.9842 0.10369E-16 -16.9842 0.10000E+01 0.0000 30 CO2,aq 0.37139E-10 -10.4302 0.37006E-10 -10.4317 0.99642E+00 -0.0016 31 CO3-2 0.57483E-06 -6.2405 0.29594E-06 -6.5288 0.51483E+00 -0.2883 32 CaCO3,aq 0.26574E-09 -9.5755 0.26574E-09 -9.5755 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53595E-12 -12.2709 0.44776E-12 -12.3490 0.83544E+00 -0.0781 34 CaCl+ 0.16487E-10 -10.7829 0.13774E-10 -10.8610 0.83544E+00 -0.0781 35 CaCl2,aq 0.37809E-15 -15.4224 0.37809E-15 -15.4224 0.10000E+01 0.0000 36 CaOH+ 0.81715E-07 -7.0877 0.68268E-07 -7.1658 0.83544E+00 -0.0781 37 CaSO4,aq 0.94811E-17 -17.0231 0.94811E-17 -17.0231 0.10000E+01 0.0000 38 HCl,aq 0.16793E-14 -14.7749 0.16793E-14 -14.7749 0.10000E+01 0.0000 43 FeCl+ 0.69729E-17 -17.1566 0.58254E-17 -17.2347 0.83544E+00 -0.0781 46 FeO,aq 0.21877E-09 -9.6600 0.21877E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16625E-10 -10.7792 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37267E-07 -7.4287 0.31074E-07 -7.5076 0.83382E+00 -0.0789 49 FeO+ 0.12265E-16 -16.9113 0.10247E-16 -16.9894 0.83544E+00 -0.0781 51 FeO2- 0.42120E-09 -9.3755 0.35120E-09 -9.4544 0.83382E+00 -0.0789 52 HFeO2,aq 0.33284E-11 -11.4778 0.33284E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10919E-04 -4.9618 0.10880E-04 -4.9634 0.99642E+00 -0.0016 54 KCl,aq 0.28146E-09 -9.5506 0.28146E-09 -9.5506 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10340E-14 -14.9855 0.86215E-15 -15.0644 0.83382E+00 -0.0789 58 MgCO3,aq 0.10495E-13 -13.9790 0.10495E-13 -13.9790 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.86381E-16 -16.0636 0.72166E-16 -16.1417 0.83544E+00 -0.0781 60 MgCl+ 0.23656E-14 -14.6261 0.19763E-14 -14.7041 0.83544E+00 -0.0781 61 MgOH+ 0.71553E-10 -10.1454 0.59778E-10 -10.2235 0.83544E+00 -0.0781 63 MnO,aq 0.18182E-08 -8.7404 0.18182E-08 -8.7404 0.10000E+01 0.0000 64 MnOH+ 0.48080E-09 -9.3180 0.40168E-09 -9.3961 0.83544E+00 -0.0781 65 MnO2-2 0.21298E-10 -10.6717 0.10965E-10 -10.9600 0.51483E+00 -0.2883 66 HMnO2- 0.21576E-09 -9.6660 0.17990E-09 -9.7450 0.83382E+00 -0.0789 69 MnCl+ 0.84354E-14 -14.0739 0.70473E-14 -14.1520 0.83544E+00 -0.0781 71 NaCl,aq 0.65862E-06 -6.1814 0.65862E-06 -6.1814 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95173E-02 -2.0215 0.79211E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16795E-14 -14.7748 0.86465E-15 -15.0632 0.51483E+00 -0.2883 81 H2PO3- 0.15425E-18 -18.8118 0.12862E-18 -18.8907 0.83382E+00 -0.0789 82 H3PO4,aq 0.92892E-18 -18.0320 0.92892E-18 -18.0320 0.10000E+01 0.0000 83 H2PO4- 0.40025E-10 -10.3977 0.33406E-10 -10.4762 0.83462E+00 -0.0785 84 PO4-3 0.12125E-08 -8.9163 0.29018E-09 -9.5373 0.23931E+00 -0.6210 88 HP2O7-3 0.10379E-17 -17.9838 0.23650E-18 -18.6262 0.22786E+00 -0.6423 89 P2O7-4 0.10253E-16 -16.9891 0.77046E-18 -18.1132 0.75143E-01 -1.1241 90 H2S,aq 0.49992E-08 -8.3011 0.49813E-08 -8.3027 0.99642E+00 -0.0016 91 S2-2 0.18822E-14 -14.7253 0.96901E-15 -15.0137 0.51483E+00 -0.2883 97 SO3-2 0.11785E-17 -17.9287 0.61569E-18 -18.2106 0.52243E+00 -0.2820 99 HSO4- 0.34872E-19 -19.4575 0.29162E-19 -19.5352 0.83627E+00 -0.0777 Charge balance for all species = 0.3758E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9026083E-10 -.2312508E-01 -.2326650E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981188E+06 0.0000 3 Cl- 0.1413942E-03 0.1420531E-03 0.5027093E+01 6.1923 4 SO4-- 0.8044329E-12 -.1532058E-04 -.1469056E+01 7.8596 5 HCO3- 0.2902551E-06 0.1345639E-04 0.8195849E+00 3.5053 6 HS- 0.2625346E-04 0.4157904E-04 0.1372613E+01 5.4611 7 Al+++ 0.1101187E-28 0.5283024E-05 0.1422859E+00 0.7613 8 H4SiO4 0.7113897E-03 0.1419446E-01 0.1361837E+04 -3.1479 9 Ca++ 0.1431718E-06 0.2431916E-06 0.9728991E-02 13.1067 10 Mg++ 0.2273496E-10 0.9784530E-10 0.2374509E-05 9.3055 11 Fe++ 0.6217302E-13 0.3792716E-07 0.2114284E-02 6.7429 12 K+ 0.1614227E-03 0.1621992E-03 0.6330834E+01 6.2505 13 Na+ 0.2052250E-01 0.2311301E-01 0.5304017E+03 8.3540 14 Mn++ 0.1933949E-10 0.2555361E-08 0.1401323E-03 9.2361 15 HPO4-- 0.4876103E-07 0.5001360E-07 0.4791567E-02 12.6423 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4470770E+01 -.2246106E-01 -.4448308E+01 0.0000000E+00 2 H2O 0.5212370E+02 0.5391066E+02 -.1786956E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7508097E-02 -.1488067E-04 0.7522978E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7482593E-02 0.4038514E-04 -.7522978E-02 0.0000000E+00 7 Al+++ 0.8803970E+00 0.5131327E-05 0.8803918E+00 0.0000000E+00 8 H4SiO4 0.2811441E+01 0.1378688E-01 0.2797654E+01 0.0000000E+00 9 Ca++ 0.3105518E+00 0.2362086E-06 0.3105516E+00 0.0000000E+00 10 Mg++ 0.2142849E+00 0.9503576E-10 0.2142849E+00 0.0000000E+00 11 Fe++ 0.1925116E+00 0.3683812E-07 0.1925116E+00 0.0000000E+00 12 K+ 0.5732463E-01 0.1575418E-03 0.5716709E-01 0.0000000E+00 13 Na+ 0.3390746E+00 0.2244934E-01 0.3166253E+00 0.0000000E+00 14 Mn++ 0.4681404E-02 0.2481986E-08 0.4681401E-02 0.0000000E+00 15 HPO4-- 0.1597740E-02 0.4857751E-07 0.1597691E-02 0.0000000E+00 Chg. balance for solid moles: -.1735E-15 Mass of aqueous solution: 0.973047E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 269.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3163 -0.500 82.94 1.919 28.14 31.84 andradite 0.3009E-01 -1.522 15.29 1.184 5.188 3.973 grossular 0.7195E-02 -2.143 3.241 0.511 1.099 0.9018 apatite-OH 0.5326E-03 -3.274 0.2675 -0.573 0.9075E-01 0.8501E-01 clinochlore 0.3974E-01 -1.401 22.09 1.344 7.494 8.403 daphnite 0.1139E-01 -1.944 8.125 0.910 2.756 2.462 chlorite-Mn 0.9363E-03 -3.029 0.6638 -0.178 0.2252 0.2115 diopside 0.6126E-02 -2.213 1.327 0.123 0.4500 0.4054 hedenbergite 0.1569E-02 -2.804 0.3893 -0.410 0.1321 0.1066 microcline 0.5011E-01 -1.300 13.95 1.145 4.732 5.448 stilbite 0.1831 -0.737 129.1 2.111 43.78 60.19 stilpnomelane-Fe 0.1411E-01 -1.850 15.21 1.182 5.161 5.255 tr.625ac.25prg.125 0.2604E-02 -2.584 2.226 0.347 0.7550 0.7163 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8070E+00 0.8070E+00 1.0000 -0.093 grossular 0.1930E+00 0.1930E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7633E+00 0.7633E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1798E-01 0.1798E-01 1.0000 -1.745 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 294.776507 g Volume = 119.999599 cm3 Porosity: -10.0918% V(tot) - V(min): -.11000E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 269.9990000 g log = 2.4314 Original solution: 1000.0103000 g Original solution / Rock added: 3.70 (Water/Rock Ratio), log = 0.5686 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0869 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9683E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3870E-08 1.0071 0.4236E-08 0.4206E-08 CH4,gas 0.1802E-01 1.0128 0.1984E-01 0.1959E-01 H2,gas 0.1372E-01 1.0006 0.1492E-01 0.1491E-01 H2S,gas 0.1342E-06 0.9958 0.1453E-06 0.1459E-06 S2,gas 0.3267E-29 1.0000 0.3550E-29 0.3550E-29 CO,gas 0.1506E-13 1.0000 0.1637E-13 0.1637E-13 SO3,gas 0.8186E-48 1.0000 0.8898E-48 0.8898E-48 SO2,gas 0.4621E-27 1.0000 0.5023E-27 0.5023E-27 HCl,gas 0.2728E-17 1.0000 0.2965E-17 0.2965E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.74 -10.37 -3.458 0.17712E+05 -8.373 3 CH4,gas 4.81 1.11 -3.70 -0.926 0.63219E+04 -1.702 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65331E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.419 0.15090E+05 -6.838 6 S2,gas -7.03 -38.48 -31.45 -4.838 0.53700E+05 -29.450 7 CO,gas 3.51 -12.28 -15.79 -4.857 0.26954E+05 -13.786 8 SO3,gas 17.43 -32.62 -50.05 -12.513 0.85460E+05 -48.051 9 SO2,gas 1.14 -28.16 -29.30 -7.813 0.50027E+05 -27.299 10 HCl,gas 5.48 -14.05 -19.53 -9.764 0.33343E+05 -17.528 11 acmite 7.74 6.57 -1.17 -0.121 0.19920E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.79 -4.76 -0.238 0.81319E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94100E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41191E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28376E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76223E+04 35 aragonite 0.99 -3.63 -4.62 -1.539 0.78813E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55853E+04 37 calcite 0.83 -3.63 -4.46 -1.488 0.76200E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52883E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71151E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70313E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82182E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47360E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39555E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68643E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70365E+04 52 chloritoid-Mn 11.46 7.61 -3.85 -0.257 0.65777E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13293E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10222E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36450E+04 66 diamond -3.11 -7.81 -4.71 -1.345 0.80379E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33641E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66035E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57723E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68259E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56962E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36651E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70706E+04 86 graphite -3.55 -7.81 -4.27 -1.219 0.72841E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38611E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.61000E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24440E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64137E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59761E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15994E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22962E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58934E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28458E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74528E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48212E+04 112 manganosite 14.07 9.24 -4.83 -1.208 0.82502E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61269E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53654E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41162E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83602E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36594E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20044E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92740E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40663E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.056 0.43410E+04 143 pyrrhotite -4.24 -8.04 -3.79 -1.265 0.64781E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.262 0.58609E+04 145 pyroxmangite 7.42 6.09 -1.33 -0.266 0.22672E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84876E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28326E+03 152 rhodonite 7.46 6.09 -1.37 -0.275 0.23464E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27386E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20975E+04 174 tephroite 18.11 15.32 -2.79 -0.398 0.47614E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91055E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76038E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65766E+04 181 troilite-low -4.39 -8.04 -3.64 -1.215 0.62213E+04 183 vesuvianite 224.06 219.35 -4.70 -0.036 0.80333E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34502E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66760E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55582E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60357E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66125E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68737E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73631E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60306E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57943E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83191E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61769E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66255E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52973E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.54 -4.58 -1.527 0.78235E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62635E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18238E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11528E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14890E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18334E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 269.9990000 g New total amount of reactant added: 279.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3649E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 279.9990000 Water: Moles liquid = 0.5386E+02 kg liquid = 0.9703E+00 Moles total = 0.5200E+02 kg total = 0.9368E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173094E-01 Osmotic coef. = 0.9690 True ionic strength = .2068525E-01 Chg. balance for total moles = 0.3649E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90262E-10 -10.0445 0.75726E-10 -10.1208 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14154E-03 -3.8491 0.11802E-03 -3.9280 0.83382E+00 -0.0789 4 SO4-- 0.80536E-12 -12.0940 0.41553E-12 -12.3814 0.51595E+00 -0.2874 5 HCO3- 0.29059E-06 -6.5367 0.24266E-06 -6.6150 0.83506E+00 -0.0783 6 HS- 0.26281E-04 -4.5804 0.21916E-04 -4.6592 0.83394E+00 -0.0789 7 Al+++ 0.11012E-28 -28.9581 0.25065E-29 -29.6009 0.22762E+00 -0.6428 8 H4SiO4 0.71140E-03 -3.1479 0.71140E-03 -3.1479 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73316E-07 -7.1348 0.51208E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50969E+00 -0.2927 11 Fe++ 0.62174E-13 -13.2064 0.31725E-13 -13.4986 0.51026E+00 -0.2922 12 K+ 0.16142E-03 -3.7920 0.13483E-03 -3.8702 0.83526E+00 -0.0782 13 Na+ 0.20523E-01 -1.6878 0.17109E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.19363E-10 -10.7130 0.98885E-11 -11.0049 0.51069E+00 -0.2918 15 HPO4-- 0.48762E-07 -7.3119 0.25162E-07 -7.5993 0.51602E+00 -0.2873 16 HSiO3- 0.10993E-01 -1.9589 0.91658E-02 -2.0378 0.83382E+00 -0.0789 17 Ca(HSiO3)+ 0.18022E-07 -7.7442 0.15056E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35449E-11 -11.4504 0.29616E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24906E-02 -2.6037 0.24906E-02 -2.6037 0.10000E+01 0.0000 20 AlO+ 0.67541E-16 -16.1704 0.56426E-16 -16.2485 0.83544E+00 -0.0781 22 HAlO2,aq 0.14911E-09 -9.8265 0.14911E-09 -9.8265 0.10000E+01 0.0000 23 AlO2- 0.52826E-05 -5.2772 0.43966E-05 -5.3569 0.83229E+00 -0.0797 24 CH4,aq 0.12604E-04 -4.8995 0.12559E-04 -4.9010 0.99642E+00 -0.0016 25 C2H6,aq 0.25092E-14 -14.6005 0.25003E-14 -14.6020 0.99642E+00 -0.0016 29 CO,aq 0.10381E-16 -16.9838 0.10381E-16 -16.9838 0.10000E+01 0.0000 30 CO2,aq 0.37182E-10 -10.4297 0.37049E-10 -10.4312 0.99642E+00 -0.0016 31 CO3-2 0.57549E-06 -6.2400 0.29628E-06 -6.5283 0.51483E+00 -0.2883 32 CaCO3,aq 0.26604E-09 -9.5751 0.26604E-09 -9.5751 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53657E-12 -12.2704 0.44827E-12 -12.3485 0.83544E+00 -0.0781 34 CaCl+ 0.16504E-10 -10.7824 0.13788E-10 -10.8605 0.83544E+00 -0.0781 35 CaCl2,aq 0.37888E-15 -15.4215 0.37888E-15 -15.4215 0.10000E+01 0.0000 36 CaOH+ 0.81715E-07 -7.0877 0.68268E-07 -7.1658 0.83544E+00 -0.0781 37 CaSO4,aq 0.94921E-17 -17.0226 0.94921E-17 -17.0226 0.10000E+01 0.0000 38 HCl,aq 0.16810E-14 -14.7744 0.16810E-14 -14.7744 0.10000E+01 0.0000 43 FeCl+ 0.69802E-17 -17.1561 0.58315E-17 -17.2342 0.83544E+00 -0.0781 46 FeO,aq 0.21877E-09 -9.6600 0.21877E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16625E-10 -10.7792 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37267E-07 -7.4287 0.31074E-07 -7.5076 0.83382E+00 -0.0789 49 FeO+ 0.12266E-16 -16.9113 0.10247E-16 -16.9894 0.83544E+00 -0.0781 51 FeO2- 0.42120E-09 -9.3755 0.35120E-09 -9.4544 0.83382E+00 -0.0789 52 HFeO2,aq 0.33284E-11 -11.4778 0.33284E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10918E-04 -4.9618 0.10879E-04 -4.9634 0.99642E+00 -0.0016 54 KCl,aq 0.28176E-09 -9.5501 0.28176E-09 -9.5501 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10352E-14 -14.9850 0.86315E-15 -15.0639 0.83382E+00 -0.0789 58 MgCO3,aq 0.10507E-13 -13.9785 0.10507E-13 -13.9785 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.86480E-16 -16.0631 0.72249E-16 -16.1412 0.83544E+00 -0.0781 60 MgCl+ 0.23680E-14 -14.6256 0.19783E-14 -14.7037 0.83544E+00 -0.0781 61 MgOH+ 0.71552E-10 -10.1454 0.59777E-10 -10.2235 0.83544E+00 -0.0781 63 MnO,aq 0.18203E-08 -8.7398 0.18203E-08 -8.7398 0.10000E+01 0.0000 64 MnOH+ 0.48137E-09 -9.3175 0.40216E-09 -9.3956 0.83544E+00 -0.0781 65 MnO2-2 0.21324E-10 -10.6711 0.10978E-10 -10.9595 0.51483E+00 -0.2883 66 HMnO2- 0.21602E-09 -9.6655 0.18012E-09 -9.7444 0.83382E+00 -0.0789 69 MnCl+ 0.84544E-14 -14.0729 0.70631E-14 -14.1510 0.83544E+00 -0.0781 71 NaCl,aq 0.65931E-06 -6.1809 0.65931E-06 -6.1809 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95172E-02 -2.0215 0.79211E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16794E-14 -14.7748 0.86463E-15 -15.0632 0.51483E+00 -0.2883 81 H2PO3- 0.15425E-18 -18.8118 0.12861E-18 -18.8907 0.83382E+00 -0.0789 82 H3PO4,aq 0.92894E-18 -18.0320 0.92894E-18 -18.0320 0.10000E+01 0.0000 83 H2PO4- 0.40026E-10 -10.3977 0.33406E-10 -10.4762 0.83462E+00 -0.0785 84 PO4-3 0.12126E-08 -8.9163 0.29018E-09 -9.5373 0.23931E+00 -0.6210 88 HP2O7-3 0.10379E-17 -17.9838 0.23650E-18 -18.6262 0.22786E+00 -0.6423 89 P2O7-4 0.10254E-16 -16.9891 0.77047E-18 -18.1132 0.75142E-01 -1.1241 90 H2S,aq 0.50044E-08 -8.3006 0.49865E-08 -8.3022 0.99642E+00 -0.0016 91 S2-2 0.18862E-14 -14.7244 0.97105E-15 -15.0128 0.51483E+00 -0.2883 97 SO3-2 0.11798E-17 -17.9282 0.61638E-18 -18.2102 0.52243E+00 -0.2820 99 HSO4- 0.34913E-19 -19.4570 0.29196E-19 -19.5347 0.83627E+00 -0.0777 Charge balance for all species = 0.3760E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9026161E-10 -.2312511E-01 -.2326653E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981188E+06 0.0000 3 Cl- 0.1415406E-03 0.1422002E-03 0.5032298E+01 6.1927 4 SO4-- 0.8053645E-12 -.1533344E-04 -.1470288E+01 7.8601 5 HCO3- 0.2905887E-06 0.1347032E-04 0.8204335E+00 3.5057 6 HS- 0.2628064E-04 0.4161909E-04 0.1373935E+01 5.4615 7 Al+++ 0.1101173E-28 0.5282765E-05 0.1422789E+00 0.7613 8 H4SiO4 0.7113996E-03 0.1419458E-01 0.1361848E+04 -3.1479 9 Ca++ 0.1431724E-06 0.2431922E-06 0.9729015E-02 13.1067 10 Mg++ 0.2273502E-10 0.9784492E-10 0.2374500E-05 9.3055 11 Fe++ 0.6217382E-13 0.3792667E-07 0.2114257E-02 6.7429 12 K+ 0.1614241E-03 0.1622006E-03 0.6330887E+01 6.2505 13 Na+ 0.2052267E-01 0.2311322E-01 0.5304064E+03 8.3540 14 Mn++ 0.1936294E-10 0.2558414E-08 0.1402997E-03 9.2366 15 HPO4-- 0.4876151E-07 0.5001409E-07 0.4791613E-02 12.6423 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4636355E+01 -.2243786E-01 -.4613917E+01 0.0000000E+00 2 H2O 0.5199835E+02 0.5385489E+02 -.1856546E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7785231E-02 -.1487775E-04 0.7800109E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7759727E-02 0.4038222E-04 -.7800109E-02 0.0000000E+00 7 Al+++ 0.9130044E+00 0.5125767E-05 0.9129993E+00 0.0000000E+00 8 H4SiO4 0.2915569E+01 0.1377273E-01 0.2901796E+01 0.0000000E+00 9 Ca++ 0.3220533E+00 0.2359648E-06 0.3220530E+00 0.0000000E+00 10 Mg++ 0.2222214E+00 0.9493709E-10 0.2222214E+00 0.0000000E+00 11 Fe++ 0.1996417E+00 0.3679954E-07 0.1996417E+00 0.0000000E+00 12 K+ 0.5944777E-01 0.1573802E-03 0.5929039E-01 0.0000000E+00 13 Na+ 0.3516270E+00 0.2242632E-01 0.3292007E+00 0.0000000E+00 14 Mn++ 0.4854790E-02 0.2482381E-08 0.4854787E-02 0.0000000E+00 15 HPO4-- 0.1656916E-02 0.4852773E-07 0.1656867E-02 0.0000000E+00 Chg. balance for solid moles: -.5117E-15 Mass of aqueous solution: 0.972041E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 279.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3289 -0.483 86.24 1.936 28.21 33.10 andradite 0.3120E-01 -1.506 15.86 1.200 5.187 4.119 grossular 0.7460E-02 -2.127 3.360 0.526 1.099 0.9349 apatite-OH 0.5523E-03 -3.258 0.2774 -0.557 0.9075E-01 0.8816E-01 clinochlore 0.4117E-01 -1.385 22.88 1.359 7.485 8.704 daphnite 0.1180E-01 -1.928 8.416 0.925 2.753 2.550 chlorite-Mn 0.9710E-03 -3.013 0.6884 -0.162 0.2252 0.2194 diopside 0.6704E-02 -2.174 1.452 0.162 0.4749 0.4437 hedenbergite 0.1717E-02 -2.765 0.4260 -0.371 0.1394 0.1167 microcline 0.5197E-01 -1.284 14.47 1.160 4.732 5.650 stilbite 0.1895 -0.722 133.6 2.126 43.70 62.30 stilpnomelane-Fe 0.1464E-01 -1.834 15.78 1.198 5.163 5.452 tr.625ac.25prg.125 0.2672E-02 -2.573 2.284 0.359 0.7471 0.7350 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8070E+00 0.8070E+00 1.0000 -0.093 grossular 0.1930E+00 0.1930E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7633E+00 0.7633E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1800E-01 0.1800E-01 1.0000 -1.745 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 305.702048 g Volume = 124.420234 cm3 Porosity: -10.1068% V(tot) - V(min): -.11421E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 279.9990000 g log = 2.4472 Original solution: 1000.0103000 g Original solution / Rock added: 3.57 (Water/Rock Ratio), log = 0.5528 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0870 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9682E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3874E-08 1.0071 0.4241E-08 0.4211E-08 CH4,gas 0.1804E-01 1.0128 0.1986E-01 0.1961E-01 H2,gas 0.1372E-01 1.0006 0.1492E-01 0.1491E-01 H2S,gas 0.1344E-06 0.9958 0.1454E-06 0.1461E-06 S2,gas 0.3273E-29 1.0000 0.3558E-29 0.3558E-29 CO,gas 0.1508E-13 1.0000 0.1639E-13 0.1639E-13 SO3,gas 0.8196E-48 1.0000 0.8908E-48 0.8908E-48 SO2,gas 0.4626E-27 1.0000 0.5029E-27 0.5029E-27 HCl,gas 0.2731E-17 1.0000 0.2968E-17 0.2968E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 -0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.74 -10.37 -3.458 0.17711E+05 -8.373 3 CH4,gas 4.81 1.11 -3.70 -0.926 0.63211E+04 -1.702 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65331E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.419 0.15090E+05 -6.837 6 S2,gas -7.03 -38.48 -31.45 -4.838 0.53698E+05 -29.449 7 CO,gas 3.51 -12.28 -15.79 -4.857 0.26953E+05 -13.785 8 SO3,gas 17.43 -32.62 -50.05 -12.513 0.85459E+05 -48.050 9 SO2,gas 1.14 -28.16 -29.30 -7.813 0.50026E+05 -27.299 10 HCl,gas 5.48 -14.05 -19.53 -9.764 0.33343E+05 -17.528 11 acmite 7.74 6.57 -1.17 -0.121 0.19920E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.79 -4.76 -0.238 0.81293E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94101E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41191E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28376E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76223E+04 35 aragonite 0.99 -3.63 -4.62 -1.538 0.78805E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55853E+04 37 calcite 0.83 -3.63 -4.46 -1.487 0.76191E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52883E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71151E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70314E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82183E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47360E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39555E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68643E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70365E+04 52 chloritoid-Mn 11.46 7.61 -3.85 -0.257 0.65769E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13293E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10222E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36451E+04 66 diamond -3.11 -7.81 -4.71 -1.345 0.80371E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33642E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66035E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57723E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68259E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56962E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36651E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70706E+04 86 graphite -3.55 -7.81 -4.27 -1.219 0.72832E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38610E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.61000E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24440E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64137E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59761E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15995E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22962E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58934E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28458E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74528E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48211E+04 112 manganosite 14.07 9.24 -4.83 -1.208 0.82493E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61270E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53655E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41162E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83602E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36595E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20045E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92742E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40664E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.056 0.43411E+04 143 pyrrhotite -4.24 -8.04 -3.79 -1.265 0.64773E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.262 0.58602E+04 145 pyroxmangite 7.42 6.09 -1.33 -0.265 0.22663E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84876E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28325E+03 152 rhodonite 7.46 6.09 -1.37 -0.275 0.23455E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27386E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20974E+04 174 tephroite 18.11 15.33 -2.79 -0.398 0.47596E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91054E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76037E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65766E+04 181 troilite-low -4.39 -8.04 -3.64 -1.214 0.62205E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80337E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34503E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66761E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55582E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60356E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66125E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68737E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73631E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60306E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57942E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83191E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61769E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66254E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52973E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.54 -4.58 -1.527 0.78218E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62635E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18238E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11529E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14890E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18334E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 279.9990000 g New total amount of reactant added: 289.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3649E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 289.9990000 Water: Moles liquid = 0.5380E+02 kg liquid = 0.9693E+00 Moles total = 0.5187E+02 kg total = 0.9345E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173111E-01 Osmotic coef. = 0.9690 True ionic strength = .2068542E-01 Chg. balance for total moles = 0.3649E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90262E-10 -10.0445 0.75727E-10 -10.1207 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14169E-03 -3.8487 0.11814E-03 -3.9276 0.83381E+00 -0.0789 4 SO4-- 0.80629E-12 -12.0935 0.41600E-12 -12.3809 0.51595E+00 -0.2874 5 HCO3- 0.29092E-06 -6.5362 0.24294E-06 -6.6145 0.83506E+00 -0.0783 6 HS- 0.26308E-04 -4.5799 0.21939E-04 -4.6588 0.83394E+00 -0.0789 7 Al+++ 0.11012E-28 -28.9581 0.25064E-29 -29.6009 0.22762E+00 -0.6428 8 H4SiO4 0.71141E-03 -3.1479 0.71141E-03 -3.1479 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73316E-07 -7.1348 0.51208E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50969E+00 -0.2927 11 Fe++ 0.62175E-13 -13.2064 0.31725E-13 -13.4986 0.51026E+00 -0.2922 12 K+ 0.16143E-03 -3.7920 0.13483E-03 -3.8702 0.83526E+00 -0.0782 13 Na+ 0.20523E-01 -1.6878 0.17109E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.19385E-10 -10.7125 0.98996E-11 -11.0044 0.51069E+00 -0.2918 15 HPO4-- 0.48762E-07 -7.3119 0.25162E-07 -7.5993 0.51602E+00 -0.2873 16 HSiO3- 0.10993E-01 -1.9589 0.91658E-02 -2.0378 0.83381E+00 -0.0789 17 Ca(HSiO3)+ 0.18022E-07 -7.7442 0.15056E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35449E-11 -11.4504 0.29616E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24906E-02 -2.6037 0.24906E-02 -2.6037 0.10000E+01 0.0000 20 AlO+ 0.67539E-16 -16.1704 0.56425E-16 -16.2485 0.83544E+00 -0.0781 22 HAlO2,aq 0.14910E-09 -9.8265 0.14910E-09 -9.8265 0.10000E+01 0.0000 23 AlO2- 0.52824E-05 -5.2772 0.43964E-05 -5.3569 0.83229E+00 -0.0797 24 CH4,aq 0.12617E-04 -4.8990 0.12572E-04 -4.9006 0.99642E+00 -0.0016 25 C2H6,aq 0.25145E-14 -14.5996 0.25055E-14 -14.6011 0.99642E+00 -0.0016 29 CO,aq 0.10393E-16 -16.9833 0.10393E-16 -16.9833 0.10000E+01 0.0000 30 CO2,aq 0.37225E-10 -10.4292 0.37092E-10 -10.4307 0.99642E+00 -0.0016 31 CO3-2 0.57614E-06 -6.2395 0.29661E-06 -6.5278 0.51483E+00 -0.2883 32 CaCO3,aq 0.26634E-09 -9.5746 0.26634E-09 -9.5746 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53718E-12 -12.2699 0.44878E-12 -12.3480 0.83544E+00 -0.0781 34 CaCl+ 0.16521E-10 -10.7820 0.13802E-10 -10.8601 0.83544E+00 -0.0781 35 CaCl2,aq 0.37966E-15 -15.4206 0.37966E-15 -15.4206 0.10000E+01 0.0000 36 CaOH+ 0.81715E-07 -7.0877 0.68268E-07 -7.1658 0.83544E+00 -0.0781 37 CaSO4,aq 0.95030E-17 -17.0221 0.95030E-17 -17.0221 0.10000E+01 0.0000 38 HCl,aq 0.16828E-14 -14.7740 0.16828E-14 -14.7740 0.10000E+01 0.0000 43 FeCl+ 0.69875E-17 -17.1557 0.58376E-17 -17.2338 0.83544E+00 -0.0781 46 FeO,aq 0.21877E-09 -9.6600 0.21877E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16625E-10 -10.7792 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37266E-07 -7.4287 0.31073E-07 -7.5076 0.83381E+00 -0.0789 49 FeO+ 0.12266E-16 -16.9113 0.10247E-16 -16.9894 0.83544E+00 -0.0781 51 FeO2- 0.42120E-09 -9.3755 0.35121E-09 -9.4544 0.83381E+00 -0.0789 52 HFeO2,aq 0.33285E-11 -11.4778 0.33285E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10918E-04 -4.9619 0.10879E-04 -4.9634 0.99642E+00 -0.0016 54 KCl,aq 0.28205E-09 -9.5497 0.28205E-09 -9.5497 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10364E-14 -14.9845 0.86415E-15 -15.0634 0.83381E+00 -0.0789 58 MgCO3,aq 0.10519E-13 -13.9780 0.10519E-13 -13.9780 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.86579E-16 -16.0626 0.72332E-16 -16.1407 0.83544E+00 -0.0781 60 MgCl+ 0.23705E-14 -14.6252 0.19804E-14 -14.7032 0.83544E+00 -0.0781 61 MgOH+ 0.71552E-10 -10.1454 0.59777E-10 -10.2235 0.83544E+00 -0.0781 63 MnO,aq 0.18224E-08 -8.7394 0.18224E-08 -8.7394 0.10000E+01 0.0000 64 MnOH+ 0.48191E-09 -9.3170 0.40261E-09 -9.3951 0.83544E+00 -0.0781 65 MnO2-2 0.21347E-10 -10.6707 0.10990E-10 -10.9590 0.51483E+00 -0.2883 66 HMnO2- 0.21625E-09 -9.6650 0.18032E-09 -9.7440 0.83381E+00 -0.0789 69 MnCl+ 0.84727E-14 -14.0720 0.70784E-14 -14.1501 0.83544E+00 -0.0781 71 NaCl,aq 0.66000E-06 -6.1805 0.66000E-06 -6.1805 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95172E-02 -2.0215 0.79210E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16794E-14 -14.7748 0.86461E-15 -15.0632 0.51483E+00 -0.2883 81 H2PO3- 0.15425E-18 -18.8118 0.12861E-18 -18.8907 0.83381E+00 -0.0789 82 H3PO4,aq 0.92896E-18 -18.0320 0.92896E-18 -18.0320 0.10000E+01 0.0000 83 H2PO4- 0.40026E-10 -10.3977 0.33407E-10 -10.4762 0.83462E+00 -0.0785 84 PO4-3 0.12126E-08 -8.9163 0.29018E-09 -9.5373 0.23931E+00 -0.6210 88 HP2O7-3 0.10380E-17 -17.9838 0.23651E-18 -18.6262 0.22786E+00 -0.6423 89 P2O7-4 0.10254E-16 -16.9891 0.77048E-18 -18.1132 0.75142E-01 -1.1241 90 H2S,aq 0.50097E-08 -8.3002 0.49917E-08 -8.3017 0.99642E+00 -0.0016 91 S2-2 0.18901E-14 -14.7235 0.97310E-15 -15.0118 0.51483E+00 -0.2883 97 SO3-2 0.11811E-17 -17.9277 0.61707E-18 -18.2097 0.52243E+00 -0.2820 99 HSO4- 0.34953E-19 -19.4565 0.29230E-19 -19.5342 0.83627E+00 -0.0777 Charge balance for all species = 0.3764E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9026236E-10 -.2312514E-01 -.2326656E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981187E+06 0.0000 3 Cl- 0.1416873E-03 0.1423476E-03 0.5037514E+01 6.1931 4 SO4-- 0.8062913E-12 -.1534633E-04 -.1471525E+01 7.8606 5 HCO3- 0.2909207E-06 0.1348428E-04 0.8212839E+00 3.5062 6 HS- 0.2630788E-04 0.4165923E-04 0.1375260E+01 5.4620 7 Al+++ 0.1101162E-28 0.5282522E-05 0.1422724E+00 0.7613 8 H4SiO4 0.7114088E-03 0.1419468E-01 0.1361858E+04 -3.1479 9 Ca++ 0.1431730E-06 0.2431929E-06 0.9729044E-02 13.1067 10 Mg++ 0.2273509E-10 0.9784454E-10 0.2374490E-05 9.3055 11 Fe++ 0.6217460E-13 0.3792621E-07 0.2114231E-02 6.7429 12 K+ 0.1614254E-03 0.1622019E-03 0.6330938E+01 6.2505 13 Na+ 0.2052284E-01 0.2311342E-01 0.5304110E+03 8.3540 14 Mn++ 0.1938483E-10 0.2561264E-08 0.1404560E-03 9.2371 15 HPO4-- 0.4876193E-07 0.5001452E-07 0.4791654E-02 12.6422 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4801940E+01 -.2241465E-01 -.4779525E+01 0.0000000E+00 2 H2O 0.5187299E+02 0.5379913E+02 -.1926136E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8062365E-02 -.1487484E-04 0.8077240E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8036861E-02 0.4037931E-04 -.8077240E-02 0.0000000E+00 7 Al+++ 0.9456118E+00 0.5120224E-05 0.9456067E+00 0.0000000E+00 8 H4SiO4 0.3019697E+01 0.1375857E-01 0.3005938E+01 0.0000000E+00 9 Ca++ 0.3335547E+00 0.2357212E-06 0.3335545E+00 0.0000000E+00 10 Mg++ 0.2301579E+00 0.9483841E-10 0.2301579E+00 0.0000000E+00 11 Fe++ 0.2067718E+00 0.3676098E-07 0.2067717E+00 0.0000000E+00 12 K+ 0.6157091E-01 0.1572185E-03 0.6141369E-01 0.0000000E+00 13 Na+ 0.3641795E+00 0.2240330E-01 0.3417762E+00 0.0000000E+00 14 Mn++ 0.5028176E-02 0.2482573E-08 0.5028173E-02 0.0000000E+00 15 HPO4-- 0.1716091E-02 0.4847790E-07 0.1716043E-02 0.0000000E+00 Chg. balance for solid moles: -.1496E-14 Mass of aqueous solution: 0.971034E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 289.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3414 -0.467 89.53 1.952 28.28 34.37 andradite 0.3231E-01 -1.491 16.42 1.215 5.186 4.266 grossular 0.7724E-02 -2.112 3.479 0.541 1.099 0.9681 apatite-OH 0.5720E-03 -3.243 0.2873 -0.542 0.9075E-01 0.9130E-01 clinochlore 0.4259E-01 -1.371 23.67 1.374 7.476 9.004 daphnite 0.1220E-01 -1.914 8.707 0.940 2.750 2.638 chlorite-Mn 0.1006E-02 -2.998 0.7130 -0.147 0.2252 0.2272 diopside 0.7283E-02 -2.138 1.577 0.198 0.4981 0.4820 hedenbergite 0.1865E-02 -2.729 0.4628 -0.335 0.1462 0.1268 microcline 0.5383E-01 -1.269 14.98 1.176 4.732 5.853 stilbite 0.1960 -0.708 138.1 2.140 43.62 64.41 stilpnomelane-Fe 0.1517E-01 -1.819 16.35 1.214 5.165 5.649 tr.625ac.25prg.125 0.2740E-02 -2.562 2.342 0.370 0.7397 0.7538 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8071E+00 0.8071E+00 1.0000 -0.093 grossular 0.1929E+00 0.1929E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7633E+00 0.7633E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1802E-01 0.1802E-01 1.0000 -1.744 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 316.627589 g Volume = 128.840870 cm3 Porosity: -10.1208% V(tot) - V(min): -.11841E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 289.9990000 g log = 2.4624 Original solution: 1000.0103000 g Original solution / Rock added: 3.45 (Water/Rock Ratio), log = 0.5376 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0870 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9682E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3878E-08 1.0071 0.4246E-08 0.4216E-08 CH4,gas 0.1806E-01 1.0128 0.1988E-01 0.1963E-01 H2,gas 0.1372E-01 1.0006 0.1492E-01 0.1491E-01 H2S,gas 0.1345E-06 0.9958 0.1456E-06 0.1462E-06 S2,gas 0.3280E-29 1.0000 0.3566E-29 0.3566E-29 CO,gas 0.1510E-13 1.0000 0.1641E-13 0.1641E-13 SO3,gas 0.8205E-48 1.0000 0.8919E-48 0.8919E-48 SO2,gas 0.4631E-27 1.0000 0.5034E-27 0.5034E-27 HCl,gas 0.2734E-17 1.0000 0.2971E-17 0.2971E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.74 -10.37 -3.457 0.17710E+05 -8.372 3 CH4,gas 4.81 1.11 -3.70 -0.925 0.63203E+04 -1.702 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65331E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.418 0.15089E+05 -6.837 6 S2,gas -7.03 -38.48 -31.45 -4.838 0.53696E+05 -29.448 7 CO,gas 3.51 -12.27 -15.78 -4.857 0.26952E+05 -13.785 8 SO3,gas 17.43 -32.62 -50.05 -12.512 0.85459E+05 -48.050 9 SO2,gas 1.14 -28.16 -29.30 -7.813 0.50026E+05 -27.298 10 HCl,gas 5.48 -14.05 -19.53 -9.764 0.33342E+05 -17.527 11 acmite 7.74 6.57 -1.17 -0.121 0.19920E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.79 -4.76 -0.238 0.81268E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94102E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41191E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28376E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76224E+04 35 aragonite 0.99 -3.63 -4.61 -1.538 0.78796E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55853E+04 37 calcite 0.83 -3.63 -4.46 -1.487 0.76183E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52883E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71152E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70314E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82183E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47360E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39555E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68644E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70366E+04 52 chloritoid-Mn 11.46 7.61 -3.85 -0.257 0.65761E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13293E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10222E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36451E+04 66 diamond -3.11 -7.81 -4.71 -1.345 0.80363E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33642E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66036E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57723E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68259E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56963E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36651E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70706E+04 86 graphite -3.55 -7.81 -4.27 -1.219 0.72824E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38610E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.61000E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24441E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64138E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59762E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15995E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22963E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58934E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28458E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74527E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48211E+04 112 manganosite 14.07 9.24 -4.83 -1.208 0.82485E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61271E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53655E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41162E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83602E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36595E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20045E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92743E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40666E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43413E+04 143 pyrrhotite -4.24 -8.04 -3.79 -1.264 0.64766E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.262 0.58594E+04 145 pyroxmangite 7.42 6.09 -1.33 -0.265 0.22655E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84876E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28324E+03 152 rhodonite 7.46 6.09 -1.37 -0.275 0.23447E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27387E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20974E+04 174 tephroite 18.11 15.33 -2.79 -0.398 0.47580E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91053E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76037E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65765E+04 181 troilite-low -4.39 -8.04 -3.64 -1.214 0.62197E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80340E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34503E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66762E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55582E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60355E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66125E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68737E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73631E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60306E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57942E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83190E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61768E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66254E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52973E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.54 -4.58 -1.527 0.78202E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62635E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18238E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11529E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14890E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18335E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 289.9990000 g New total amount of reactant added: 299.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3648E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 299.9990000 Water: Moles liquid = 0.5375E+02 kg liquid = 0.9683E+00 Moles total = 0.5175E+02 kg total = 0.9323E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173128E-01 Osmotic coef. = 0.9690 True ionic strength = .2068559E-01 Chg. balance for total moles = 0.3648E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90263E-10 -10.0445 0.75728E-10 -10.1207 0.83897E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14183E-03 -3.8482 0.11826E-03 -3.9271 0.83381E+00 -0.0789 4 SO4-- 0.80721E-12 -12.0930 0.41648E-12 -12.3804 0.51595E+00 -0.2874 5 HCO3- 0.29125E-06 -6.5357 0.24321E-06 -6.6140 0.83506E+00 -0.0783 6 HS- 0.26335E-04 -4.5795 0.21962E-04 -4.6583 0.83394E+00 -0.0789 7 Al+++ 0.11012E-28 -28.9582 0.25064E-29 -29.6009 0.22762E+00 -0.6428 8 H4SiO4 0.71142E-03 -3.1479 0.71142E-03 -3.1479 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73316E-07 -7.1348 0.51208E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50969E+00 -0.2927 11 Fe++ 0.62175E-13 -13.2064 0.31725E-13 -13.4986 0.51026E+00 -0.2922 12 K+ 0.16143E-03 -3.7920 0.13483E-03 -3.8702 0.83526E+00 -0.0782 13 Na+ 0.20523E-01 -1.6878 0.17109E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.19405E-10 -10.7121 0.99101E-11 -11.0039 0.51069E+00 -0.2918 15 HPO4-- 0.48762E-07 -7.3119 0.25162E-07 -7.5992 0.51602E+00 -0.2873 16 HSiO3- 0.10993E-01 -1.9589 0.91658E-02 -2.0378 0.83381E+00 -0.0789 17 Ca(HSiO3)+ 0.18022E-07 -7.7442 0.15056E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35450E-11 -11.4504 0.29616E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24907E-02 -2.6037 0.24907E-02 -2.6037 0.10000E+01 0.0000 20 AlO+ 0.67537E-16 -16.1705 0.56423E-16 -16.2485 0.83544E+00 -0.0781 22 HAlO2,aq 0.14910E-09 -9.8265 0.14910E-09 -9.8265 0.10000E+01 0.0000 23 AlO2- 0.52821E-05 -5.2772 0.43963E-05 -5.3569 0.83229E+00 -0.0797 24 CH4,aq 0.12630E-04 -4.8986 0.12585E-04 -4.9002 0.99642E+00 -0.0016 25 C2H6,aq 0.25197E-14 -14.5986 0.25107E-14 -14.6002 0.99642E+00 -0.0016 29 CO,aq 0.10404E-16 -16.9828 0.10404E-16 -16.9828 0.10000E+01 0.0000 30 CO2,aq 0.37267E-10 -10.4287 0.37134E-10 -10.4302 0.99642E+00 -0.0016 31 CO3-2 0.57679E-06 -6.2390 0.29695E-06 -6.5273 0.51483E+00 -0.2883 32 CaCO3,aq 0.26664E-09 -9.5741 0.26664E-09 -9.5741 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53780E-12 -12.2694 0.44930E-12 -12.3475 0.83544E+00 -0.0781 34 CaCl+ 0.16538E-10 -10.7815 0.13817E-10 -10.8596 0.83544E+00 -0.0781 35 CaCl2,aq 0.38045E-15 -15.4197 0.38045E-15 -15.4197 0.10000E+01 0.0000 36 CaOH+ 0.81714E-07 -7.0877 0.68267E-07 -7.1658 0.83544E+00 -0.0781 37 CaSO4,aq 0.95139E-17 -17.0216 0.95139E-17 -17.0216 0.10000E+01 0.0000 38 HCl,aq 0.16846E-14 -14.7735 0.16846E-14 -14.7735 0.10000E+01 0.0000 43 FeCl+ 0.69948E-17 -17.1552 0.58437E-17 -17.2333 0.83544E+00 -0.0781 46 FeO,aq 0.21877E-09 -9.6600 0.21877E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16625E-10 -10.7792 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37266E-07 -7.4287 0.31073E-07 -7.5076 0.83381E+00 -0.0789 49 FeO+ 0.12266E-16 -16.9113 0.10247E-16 -16.9894 0.83544E+00 -0.0781 51 FeO2- 0.42120E-09 -9.3755 0.35121E-09 -9.4544 0.83381E+00 -0.0789 52 HFeO2,aq 0.33285E-11 -11.4778 0.33285E-11 -11.4778 0.10000E+01 0.0000 53 H2,aq 0.10918E-04 -4.9619 0.10879E-04 -4.9634 0.99642E+00 -0.0016 54 KCl,aq 0.28234E-09 -9.5492 0.28234E-09 -9.5492 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10376E-14 -14.9840 0.86515E-15 -15.0629 0.83381E+00 -0.0789 58 MgCO3,aq 0.10531E-13 -13.9775 0.10531E-13 -13.9775 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.86678E-16 -16.0621 0.72414E-16 -16.1402 0.83544E+00 -0.0781 60 MgCl+ 0.23730E-14 -14.6247 0.19825E-14 -14.7028 0.83544E+00 -0.0781 61 MgOH+ 0.71551E-10 -10.1454 0.59777E-10 -10.2235 0.83544E+00 -0.0781 63 MnO,aq 0.18243E-08 -8.7389 0.18243E-08 -8.7389 0.10000E+01 0.0000 64 MnOH+ 0.48242E-09 -9.3166 0.40303E-09 -9.3947 0.83544E+00 -0.0781 65 MnO2-2 0.21369E-10 -10.6702 0.11001E-10 -10.9586 0.51483E+00 -0.2883 66 HMnO2- 0.21648E-09 -9.6646 0.18050E-09 -9.7435 0.83381E+00 -0.0789 69 MnCl+ 0.84904E-14 -14.0711 0.70932E-14 -14.1492 0.83544E+00 -0.0781 71 NaCl,aq 0.66069E-06 -6.1800 0.66069E-06 -6.1800 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95171E-02 -2.0215 0.79210E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16794E-14 -14.7749 0.86459E-15 -15.0632 0.51483E+00 -0.2883 81 H2PO3- 0.15424E-18 -18.8118 0.12861E-18 -18.8907 0.83381E+00 -0.0789 82 H3PO4,aq 0.92898E-18 -18.0320 0.92898E-18 -18.0320 0.10000E+01 0.0000 83 H2PO4- 0.40027E-10 -10.3977 0.33407E-10 -10.4762 0.83462E+00 -0.0785 84 PO4-3 0.12126E-08 -8.9163 0.29018E-09 -9.5373 0.23931E+00 -0.6210 88 HP2O7-3 0.10380E-17 -17.9838 0.23651E-18 -18.6261 0.22786E+00 -0.6423 89 P2O7-4 0.10254E-16 -16.9891 0.77049E-18 -18.1132 0.75141E-01 -1.1241 90 H2S,aq 0.50149E-08 -8.2997 0.49970E-08 -8.3013 0.99642E+00 -0.0016 91 S2-2 0.18941E-14 -14.7226 0.97514E-15 -15.0109 0.51483E+00 -0.2883 97 SO3-2 0.11825E-17 -17.9272 0.61775E-18 -18.2092 0.52243E+00 -0.2820 99 HSO4- 0.34993E-19 -19.4560 0.29264E-19 -19.5337 0.83627E+00 -0.0777 Charge balance for all species = 0.3767E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9026309E-10 -.2312516E-01 -.2326658E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981187E+06 0.0000 3 Cl- 0.1418343E-03 0.1424953E-03 0.5042741E+01 6.1936 4 SO4-- 0.8072139E-12 -.1535926E-04 -.1472765E+01 7.8611 5 HCO3- 0.2912514E-06 0.1349828E-04 0.8221361E+00 3.5067 6 HS- 0.2633518E-04 0.4169946E-04 0.1376588E+01 5.4624 7 Al+++ 0.1101152E-28 0.5282293E-05 0.1422662E+00 0.7613 8 H4SiO4 0.7114174E-03 0.1419478E-01 0.1361867E+04 -3.1479 9 Ca++ 0.1431737E-06 0.2431937E-06 0.9729076E-02 13.1067 10 Mg++ 0.2273517E-10 0.9784427E-10 0.2374484E-05 9.3055 11 Fe++ 0.6217537E-13 0.3792576E-07 0.2114206E-02 6.7429 12 K+ 0.1614267E-03 0.1622032E-03 0.6330988E+01 6.2505 13 Na+ 0.2052300E-01 0.2311361E-01 0.5304155E+03 8.3540 14 Mn++ 0.1940532E-10 0.2563930E-08 0.1406022E-03 9.2376 15 HPO4-- 0.4876231E-07 0.5001490E-07 0.4791690E-02 12.6422 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4967525E+01 -.2239144E-01 -.4945134E+01 0.0000000E+00 2 H2O 0.5174764E+02 0.5374337E+02 -.1995726E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8339499E-02 -.1487194E-04 0.8354371E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8313995E-02 0.4037641E-04 -.8354371E-02 0.0000000E+00 7 Al+++ 0.9782192E+00 0.5114695E-05 0.9782141E+00 0.0000000E+00 8 H4SiO4 0.3123824E+01 0.1374440E-01 0.3110080E+01 0.0000000E+00 9 Ca++ 0.3450561E+00 0.2354777E-06 0.3450559E+00 0.0000000E+00 10 Mg++ 0.2380944E+00 0.9473985E-10 0.2380944E+00 0.0000000E+00 11 Fe++ 0.2139019E+00 0.3672245E-07 0.2139018E+00 0.0000000E+00 12 K+ 0.6369406E-01 0.1570568E-03 0.6353700E-01 0.0000000E+00 13 Na+ 0.3767319E+00 0.2238026E-01 0.3543516E+00 0.0000000E+00 14 Mn++ 0.5201561E-02 0.2482581E-08 0.5201559E-02 0.0000000E+00 15 HPO4-- 0.1775267E-02 0.4842802E-07 0.1775219E-02 0.0000000E+00 Chg. balance for solid moles: -.6193E-15 Mass of aqueous solution: 0.970028E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 299.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3540 -0.451 92.83 1.968 28.34 35.63 andradite 0.3342E-01 -1.476 16.98 1.230 5.185 4.412 grossular 0.7989E-02 -2.098 3.599 0.556 1.099 1.001 apatite-OH 0.5917E-03 -3.228 0.2972 -0.527 0.9075E-01 0.9445E-01 clinochlore 0.4401E-01 -1.356 24.46 1.389 7.468 9.305 daphnite 0.1261E-01 -1.899 8.998 0.954 2.747 2.727 chlorite-Mn 0.1040E-02 -2.983 0.7375 -0.132 0.2252 0.2350 diopside 0.7861E-02 -2.105 1.702 0.231 0.5197 0.5203 hedenbergite 0.2013E-02 -2.696 0.4995 -0.301 0.1525 0.1368 microcline 0.5569E-01 -1.254 15.50 1.190 4.732 6.055 stilbite 0.2024 -0.694 142.6 2.154 43.54 66.52 stilpnomelane-Fe 0.1570E-01 -1.804 16.92 1.228 5.166 5.845 tr.625ac.25prg.125 0.2808E-02 -2.552 2.400 0.380 0.7328 0.7725 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8071E+00 0.8071E+00 1.0000 -0.093 grossular 0.1929E+00 0.1929E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7633E+00 0.7633E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1804E-01 0.1804E-01 1.0000 -1.744 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 327.553130 g Volume = 133.261505 cm3 Porosity: -10.1338% V(tot) - V(min): -.12262E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 299.9990000 g log = 2.4771 Original solution: 1000.0103000 g Original solution / Rock added: 3.33 (Water/Rock Ratio), log = 0.5229 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0870 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9682E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3883E-08 1.0071 0.4251E-08 0.4220E-08 CH4,gas 0.1808E-01 1.0128 0.1990E-01 0.1965E-01 H2,gas 0.1372E-01 1.0006 0.1492E-01 0.1491E-01 H2S,gas 0.1346E-06 0.9958 0.1457E-06 0.1464E-06 S2,gas 0.3287E-29 1.0000 0.3573E-29 0.3573E-29 CO,gas 0.1511E-13 1.0000 0.1643E-13 0.1643E-13 SO3,gas 0.8214E-48 1.0000 0.8929E-48 0.8929E-48 SO2,gas 0.4637E-27 1.0000 0.5040E-27 0.5040E-27 HCl,gas 0.2736E-17 1.0000 0.2974E-17 0.2974E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.48529E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 67 diopside 16.22 16.22 0.00 0.000 0.18198E-10 68 hedenbergite 14.24 14.24 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.73 -10.37 -3.457 0.17709E+05 -8.372 3 CH4,gas 4.81 1.11 -3.70 -0.925 0.63196E+04 -1.701 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65331E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.418 0.15088E+05 -6.836 6 S2,gas -7.03 -38.48 -31.45 -4.838 0.53695E+05 -29.447 7 CO,gas 3.51 -12.27 -15.78 -4.857 0.26951E+05 -13.784 8 SO3,gas 17.43 -32.62 -50.05 -12.512 0.85458E+05 -48.049 9 SO2,gas 1.14 -28.16 -29.30 -7.813 0.50025E+05 -27.298 10 HCl,gas 5.48 -14.05 -19.53 -9.763 0.33341E+05 -17.527 11 acmite 7.74 6.57 -1.17 -0.121 0.19920E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.79 -4.76 -0.238 0.81246E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94103E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41191E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28377E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76224E+04 35 aragonite 0.99 -3.63 -4.61 -1.538 0.78788E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55853E+04 37 calcite 0.83 -3.63 -4.46 -1.487 0.76174E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52883E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71152E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70315E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82183E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47360E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39555E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68644E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70366E+04 52 chloritoid-Mn 11.46 7.61 -3.85 -0.257 0.65754E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13293E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10222E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36451E+04 66 diamond -3.11 -7.81 -4.71 -1.345 0.80355E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33643E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66037E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57723E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68259E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56963E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36651E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70706E+04 86 graphite -3.55 -7.81 -4.26 -1.218 0.72816E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38610E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.61000E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24441E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64138E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59762E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15995E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22963E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58934E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28458E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74527E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48211E+04 112 manganosite 14.07 9.24 -4.83 -1.208 0.82477E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61271E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53656E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41163E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83602E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36595E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20046E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92744E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40667E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43414E+04 143 pyrrhotite -4.24 -8.04 -3.79 -1.264 0.64758E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.262 0.58586E+04 145 pyroxmangite 7.42 6.09 -1.33 -0.265 0.22647E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84877E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28323E+03 152 rhodonite 7.46 6.09 -1.37 -0.275 0.23439E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27387E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20974E+04 174 tephroite 18.11 15.33 -2.79 -0.398 0.47564E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91052E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76037E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65765E+04 181 troilite-low -4.39 -8.04 -3.64 -1.214 0.62190E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80343E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34503E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66762E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55581E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60355E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66125E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68737E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73631E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60306E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57942E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83190E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61768E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66254E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52972E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.54 -4.58 -1.526 0.78187E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62635E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18237E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11529E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14890E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18335E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 299.9990000 g New total amount of reactant added: 309.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3650E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 309.9990000 Water: Moles liquid = 0.5369E+02 kg liquid = 0.9673E+00 Moles total = 0.5162E+02 kg total = 0.9300E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173145E-01 Osmotic coef. = 0.9690 True ionic strength = .2068575E-01 Chg. balance for total moles = 0.3650E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90264E-10 -10.0445 0.75728E-10 -10.1207 0.83896E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14198E-03 -3.8478 0.11839E-03 -3.9267 0.83381E+00 -0.0789 4 SO4-- 0.80813E-12 -12.0925 0.41695E-12 -12.3799 0.51594E+00 -0.2874 5 HCO3- 0.29158E-06 -6.5352 0.24349E-06 -6.6135 0.83506E+00 -0.0783 6 HS- 0.26363E-04 -4.5790 0.21985E-04 -4.6579 0.83394E+00 -0.0789 7 Al+++ 0.11011E-28 -28.9582 0.25064E-29 -29.6010 0.22762E+00 -0.6428 8 H4SiO4 0.71143E-03 -3.1479 0.71143E-03 -3.1479 0.10000E+01 0.0000 9 Ca++ 0.14317E-06 -6.8441 0.73316E-07 -7.1348 0.51208E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50969E+00 -0.2927 11 Fe++ 0.62176E-13 -13.2064 0.31726E-13 -13.4986 0.51026E+00 -0.2922 12 K+ 0.16143E-03 -3.7920 0.13483E-03 -3.8702 0.83526E+00 -0.0782 13 Na+ 0.20523E-01 -1.6878 0.17109E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.19425E-10 -10.7116 0.99199E-11 -11.0035 0.51069E+00 -0.2918 15 HPO4-- 0.48763E-07 -7.3119 0.25162E-07 -7.5992 0.51602E+00 -0.2873 16 HSiO3- 0.10993E-01 -1.9589 0.91659E-02 -2.0378 0.83381E+00 -0.0789 17 Ca(HSiO3)+ 0.18022E-07 -7.7442 0.15056E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35450E-11 -11.4504 0.29616E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24907E-02 -2.6037 0.24907E-02 -2.6037 0.10000E+01 0.0000 20 AlO+ 0.67535E-16 -16.1705 0.56421E-16 -16.2486 0.83544E+00 -0.0781 22 HAlO2,aq 0.14909E-09 -9.8265 0.14909E-09 -9.8265 0.10000E+01 0.0000 23 AlO2- 0.52819E-05 -5.2772 0.43961E-05 -5.3569 0.83229E+00 -0.0797 24 CH4,aq 0.12643E-04 -4.8982 0.12598E-04 -4.8997 0.99642E+00 -0.0016 25 C2H6,aq 0.25250E-14 -14.5977 0.25160E-14 -14.5993 0.99642E+00 -0.0016 29 CO,aq 0.10416E-16 -16.9823 0.10416E-16 -16.9823 0.10000E+01 0.0000 30 CO2,aq 0.37310E-10 -10.4282 0.37176E-10 -10.4297 0.99642E+00 -0.0016 31 CO3-2 0.57744E-06 -6.2385 0.29728E-06 -6.5268 0.51483E+00 -0.2883 32 CaCO3,aq 0.26694E-09 -9.5736 0.26694E-09 -9.5736 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53841E-12 -12.2689 0.44980E-12 -12.3470 0.83544E+00 -0.0781 34 CaCl+ 0.16555E-10 -10.7811 0.13831E-10 -10.8591 0.83544E+00 -0.0781 35 CaCl2,aq 0.38124E-15 -15.4188 0.38124E-15 -15.4188 0.10000E+01 0.0000 36 CaOH+ 0.81714E-07 -7.0877 0.68267E-07 -7.1658 0.83544E+00 -0.0781 37 CaSO4,aq 0.95247E-17 -17.0211 0.95247E-17 -17.0211 0.10000E+01 0.0000 38 HCl,aq 0.16863E-14 -14.7731 0.16863E-14 -14.7731 0.10000E+01 0.0000 43 FeCl+ 0.70021E-17 -17.1548 0.58499E-17 -17.2329 0.83544E+00 -0.0781 46 FeO,aq 0.21877E-09 -9.6600 0.21877E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16625E-10 -10.7792 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37265E-07 -7.4287 0.31072E-07 -7.5076 0.83381E+00 -0.0789 49 FeO+ 0.12266E-16 -16.9113 0.10248E-16 -16.9894 0.83544E+00 -0.0781 51 FeO2- 0.42120E-09 -9.3755 0.35121E-09 -9.4544 0.83381E+00 -0.0789 52 HFeO2,aq 0.33285E-11 -11.4777 0.33285E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10917E-04 -4.9619 0.10878E-04 -4.9634 0.99642E+00 -0.0016 54 KCl,aq 0.28264E-09 -9.5488 0.28264E-09 -9.5488 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10388E-14 -14.9835 0.86613E-15 -15.0624 0.83381E+00 -0.0789 58 MgCO3,aq 0.10543E-13 -13.9770 0.10543E-13 -13.9770 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.86776E-16 -16.0616 0.72496E-16 -16.1397 0.83544E+00 -0.0781 60 MgCl+ 0.23754E-14 -14.6243 0.19845E-14 -14.7023 0.83544E+00 -0.0781 61 MgOH+ 0.71551E-10 -10.1454 0.59776E-10 -10.2235 0.83544E+00 -0.0781 63 MnO,aq 0.18260E-08 -8.7385 0.18260E-08 -8.7385 0.10000E+01 0.0000 64 MnOH+ 0.48289E-09 -9.3162 0.40343E-09 -9.3942 0.83544E+00 -0.0781 65 MnO2-2 0.21389E-10 -10.6698 0.11012E-10 -10.9581 0.51483E+00 -0.2883 66 HMnO2- 0.21669E-09 -9.6642 0.18068E-09 -9.7431 0.83381E+00 -0.0789 69 MnCl+ 0.85077E-14 -14.0702 0.71076E-14 -14.1483 0.83544E+00 -0.0781 71 NaCl,aq 0.66138E-06 -6.1796 0.66138E-06 -6.1796 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95170E-02 -2.0215 0.79209E-02 -2.1012 0.83229E+00 -0.0797 79 HPO3-2 0.16793E-14 -14.7749 0.86457E-15 -15.0632 0.51483E+00 -0.2883 81 H2PO3- 0.15424E-18 -18.8118 0.12861E-18 -18.8907 0.83381E+00 -0.0789 82 H3PO4,aq 0.92900E-18 -18.0320 0.92900E-18 -18.0320 0.10000E+01 0.0000 83 H2PO4- 0.40027E-10 -10.3976 0.33407E-10 -10.4762 0.83462E+00 -0.0785 84 PO4-3 0.12126E-08 -8.9163 0.29018E-09 -9.5373 0.23931E+00 -0.6210 88 HP2O7-3 0.10380E-17 -17.9838 0.23652E-18 -18.6261 0.22786E+00 -0.6423 89 P2O7-4 0.10254E-16 -16.9891 0.77050E-18 -18.1132 0.75140E-01 -1.1241 90 H2S,aq 0.50201E-08 -8.2993 0.50022E-08 -8.3008 0.99642E+00 -0.0016 91 S2-2 0.18981E-14 -14.7217 0.97719E-15 -15.0100 0.51483E+00 -0.2883 97 SO3-2 0.11838E-17 -17.9267 0.61844E-18 -18.2087 0.52243E+00 -0.2820 99 HSO4- 0.35033E-19 -19.4555 0.29297E-19 -19.5332 0.83627E+00 -0.0777 Charge balance for all species = 0.3769E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9026380E-10 -.2312517E-01 -.2326659E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981187E+06 0.0000 3 Cl- 0.1419816E-03 0.1426433E-03 0.5047979E+01 6.1940 4 SO4-- 0.8081328E-12 -.1537223E-04 -.1474008E+01 7.8616 5 HCO3- 0.2915809E-06 0.1351230E-04 0.8229900E+00 3.5072 6 HS- 0.2636253E-04 0.4173979E-04 0.1377919E+01 5.4629 7 Al+++ 0.1101144E-28 0.5282077E-05 0.1422604E+00 0.7613 8 H4SiO4 0.7114255E-03 0.1419486E-01 0.1361875E+04 -3.1479 9 Ca++ 0.1431745E-06 0.2431946E-06 0.9729112E-02 13.1067 10 Mg++ 0.2273527E-10 0.9784406E-10 0.2374479E-05 9.3055 11 Fe++ 0.6217614E-13 0.3792534E-07 0.2114182E-02 6.7429 12 K+ 0.1614280E-03 0.1622044E-03 0.6331037E+01 6.2505 13 Na+ 0.2052316E-01 0.2311380E-01 0.5304198E+03 8.3540 14 Mn++ 0.1942454E-10 0.2566428E-08 0.1407392E-03 9.2380 15 HPO4-- 0.4876263E-07 0.5001522E-07 0.4791722E-02 12.6422 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5133110E+01 -.2236822E-01 -.5110742E+01 0.0000000E+00 2 H2O 0.5162229E+02 0.5368760E+02 -.2065316E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8616634E-02 -.1486906E-04 0.8631503E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8591129E-02 0.4037353E-04 -.8631503E-02 0.0000000E+00 7 Al+++ 0.1010827E+01 0.5109180E-05 0.1010822E+01 0.0000000E+00 8 H4SiO4 0.3227952E+01 0.1373023E-01 0.3214222E+01 0.0000000E+00 9 Ca++ 0.3565575E+00 0.2352342E-06 0.3565573E+00 0.0000000E+00 10 Mg++ 0.2460310E+00 0.9464135E-10 0.2460310E+00 0.0000000E+00 11 Fe++ 0.2210320E+00 0.3668393E-07 0.2210319E+00 0.0000000E+00 12 K+ 0.6581720E-01 0.1568950E-03 0.6566030E-01 0.0000000E+00 13 Na+ 0.3892843E+00 0.2235722E-01 0.3669271E+00 0.0000000E+00 14 Mn++ 0.5374947E-02 0.2482422E-08 0.5374945E-02 0.0000000E+00 15 HPO4-- 0.1834443E-02 0.4837808E-07 0.1834394E-02 0.0000000E+00 Chg. balance for solid moles: 0.5369E-15 Mass of aqueous solution: 0.969021E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 309.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3666 -0.436 96.12 1.983 28.40 36.90 andradite 0.3453E-01 -1.462 17.55 1.244 5.184 4.558 grossular 0.8253E-02 -2.083 3.718 0.570 1.098 1.034 apatite-OH 0.6115E-03 -3.214 0.3072 -0.513 0.9074E-01 0.9760E-01 clinochlore 0.4543E-01 -1.343 25.25 1.402 7.461 9.606 daphnite 0.1302E-01 -1.885 9.289 0.968 2.744 2.815 chlorite-Mn 0.1075E-02 -2.969 0.7621 -0.118 0.2252 0.2429 diopside 0.8439E-02 -2.074 1.828 0.262 0.5400 0.5586 hedenbergite 0.2162E-02 -2.665 0.5363 -0.271 0.1584 0.1469 microcline 0.5755E-01 -1.240 16.02 1.205 4.732 6.257 stilbite 0.2088 -0.680 147.2 2.168 43.47 68.63 stilpnomelane-Fe 0.1623E-01 -1.790 17.49 1.243 5.168 6.042 tr.625ac.25prg.125 0.2876E-02 -2.541 2.458 0.391 0.7263 0.7913 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8071E+00 0.8071E+00 1.0000 -0.093 grossular 0.1929E+00 0.1929E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7632E+00 0.7632E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1806E-01 0.1806E-01 1.0000 -1.743 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 338.478672 g Volume = 137.682141 cm3 Porosity: -10.1461% V(tot) - V(min): -.12683E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 309.9990000 g log = 2.4914 Original solution: 1000.0103000 g Original solution / Rock added: 3.23 (Water/Rock Ratio), log = 0.5086 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0870 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9682E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3887E-08 1.0071 0.4255E-08 0.4225E-08 CH4,gas 0.1809E-01 1.0128 0.1992E-01 0.1967E-01 H2,gas 0.1372E-01 1.0006 0.1492E-01 0.1491E-01 H2S,gas 0.1348E-06 0.9958 0.1459E-06 0.1465E-06 S2,gas 0.3294E-29 1.0000 0.3581E-29 0.3581E-29 CO,gas 0.1513E-13 1.0000 0.1645E-13 0.1645E-13 SO3,gas 0.8224E-48 1.0000 0.8939E-48 0.8939E-48 SO2,gas 0.4642E-27 1.0000 0.5046E-27 0.5046E-27 HCl,gas 0.2739E-17 1.0000 0.2978E-17 0.2978E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.37914E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.73 -10.37 -3.457 0.17708E+05 -8.371 3 CH4,gas 4.81 1.11 -3.70 -0.925 0.63188E+04 -1.701 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65332E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.418 0.15087E+05 -6.836 6 S2,gas -7.03 -38.48 -31.45 -4.838 0.53693E+05 -29.446 7 CO,gas 3.51 -12.27 -15.78 -4.857 0.26951E+05 -13.784 8 SO3,gas 17.43 -32.62 -50.05 -12.512 0.85457E+05 -48.049 9 SO2,gas 1.14 -28.16 -29.30 -7.813 0.50024E+05 -27.297 10 HCl,gas 5.48 -14.05 -19.53 -9.763 0.33340E+05 -17.526 11 acmite 7.74 6.57 -1.17 -0.121 0.19919E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.79 -4.76 -0.238 0.81224E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94104E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41192E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28377E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76225E+04 35 aragonite 0.99 -3.63 -4.61 -1.538 0.78779E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55853E+04 37 calcite 0.83 -3.63 -4.46 -1.487 0.76166E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52883E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71152E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70315E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82184E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47360E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39555E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68644E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70367E+04 52 chloritoid-Mn 11.46 7.61 -3.85 -0.257 0.65747E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13293E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10222E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36451E+04 66 diamond -3.11 -7.81 -4.71 -1.344 0.80347E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33643E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66038E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57723E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68258E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56963E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36651E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70706E+04 86 graphite -3.55 -7.81 -4.26 -1.218 0.72808E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38610E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.61000E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24441E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64138E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59762E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15995E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22963E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58934E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28458E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74527E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48211E+04 112 manganosite 14.07 9.24 -4.83 -1.207 0.82470E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61272E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53656E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41163E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83602E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36596E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20046E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92745E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40668E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43415E+04 143 pyrrhotite -4.24 -8.04 -3.79 -1.264 0.64750E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.262 0.58579E+04 145 pyroxmangite 7.42 6.09 -1.33 -0.265 0.22640E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84877E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28322E+03 152 rhodonite 7.46 6.09 -1.37 -0.274 0.23432E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27387E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20974E+04 174 tephroite 18.11 15.33 -2.78 -0.398 0.47549E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91051E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76037E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65765E+04 181 troilite-low -4.39 -8.04 -3.64 -1.214 0.62182E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80347E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34504E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66763E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55581E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60354E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66125E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68737E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73632E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60306E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57941E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83189E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61768E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66253E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52972E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.54 -4.58 -1.526 0.78172E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62636E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18237E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11529E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14890E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18335E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 309.9990000 g New total amount of reactant added: 319.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3649E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 319.9990000 Water: Moles liquid = 0.5364E+02 kg liquid = 0.9663E+00 Moles total = 0.5150E+02 kg total = 0.9277E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173162E-01 Osmotic coef. = 0.9690 True ionic strength = .2068591E-01 Chg. balance for total moles = 0.3649E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90264E-10 -10.0445 0.75729E-10 -10.1207 0.83896E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14213E-03 -3.8473 0.11851E-03 -3.9262 0.83381E+00 -0.0789 4 SO4-- 0.80905E-12 -12.0920 0.41742E-12 -12.3794 0.51594E+00 -0.2874 5 HCO3- 0.29191E-06 -6.5348 0.24376E-06 -6.6130 0.83506E+00 -0.0783 6 HS- 0.26390E-04 -4.5786 0.22008E-04 -4.6574 0.83394E+00 -0.0789 7 Al+++ 0.11011E-28 -28.9582 0.25063E-29 -29.6010 0.22761E+00 -0.6428 8 H4SiO4 0.71143E-03 -3.1479 0.71143E-03 -3.1479 0.10000E+01 0.0000 9 Ca++ 0.14318E-06 -6.8441 0.73316E-07 -7.1348 0.51207E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50969E+00 -0.2927 11 Fe++ 0.62177E-13 -13.2064 0.31726E-13 -13.4986 0.51026E+00 -0.2922 12 K+ 0.16143E-03 -3.7920 0.13483E-03 -3.8702 0.83526E+00 -0.0782 13 Na+ 0.20523E-01 -1.6878 0.17109E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.19443E-10 -10.7112 0.99291E-11 -11.0031 0.51069E+00 -0.2918 15 HPO4-- 0.48763E-07 -7.3119 0.25163E-07 -7.5992 0.51602E+00 -0.2873 16 HSiO3- 0.10993E-01 -1.9589 0.91659E-02 -2.0378 0.83381E+00 -0.0789 17 Ca(HSiO3)+ 0.18022E-07 -7.7442 0.15057E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35450E-11 -11.4504 0.29616E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24907E-02 -2.6037 0.24907E-02 -2.6037 0.10000E+01 0.0000 20 AlO+ 0.67533E-16 -16.1705 0.56420E-16 -16.2486 0.83544E+00 -0.0781 22 HAlO2,aq 0.14909E-09 -9.8266 0.14909E-09 -9.8266 0.10000E+01 0.0000 23 AlO2- 0.52817E-05 -5.2772 0.43959E-05 -5.3570 0.83228E+00 -0.0797 24 CH4,aq 0.12656E-04 -4.8977 0.12611E-04 -4.8993 0.99642E+00 -0.0016 25 C2H6,aq 0.25303E-14 -14.5968 0.25213E-14 -14.5984 0.99642E+00 -0.0016 29 CO,aq 0.10427E-16 -16.9818 0.10427E-16 -16.9818 0.10000E+01 0.0000 30 CO2,aq 0.37352E-10 -10.4277 0.37218E-10 -10.4292 0.99642E+00 -0.0016 31 CO3-2 0.57809E-06 -6.2380 0.29761E-06 -6.5263 0.51483E+00 -0.2883 32 CaCO3,aq 0.26724E-09 -9.5731 0.26724E-09 -9.5731 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53901E-12 -12.2684 0.45031E-12 -12.3465 0.83544E+00 -0.0781 34 CaCl+ 0.16573E-10 -10.7806 0.13845E-10 -10.8587 0.83544E+00 -0.0781 35 CaCl2,aq 0.38204E-15 -15.4179 0.38204E-15 -15.4179 0.10000E+01 0.0000 36 CaOH+ 0.81714E-07 -7.0877 0.68267E-07 -7.1658 0.83544E+00 -0.0781 37 CaSO4,aq 0.95355E-17 -17.0207 0.95355E-17 -17.0207 0.10000E+01 0.0000 38 HCl,aq 0.16881E-14 -14.7726 0.16881E-14 -14.7726 0.10000E+01 0.0000 43 FeCl+ 0.70095E-17 -17.1543 0.58560E-17 -17.2324 0.83544E+00 -0.0781 46 FeO,aq 0.21877E-09 -9.6600 0.21877E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16625E-10 -10.7792 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37265E-07 -7.4287 0.31072E-07 -7.5076 0.83381E+00 -0.0789 49 FeO+ 0.12266E-16 -16.9113 0.10248E-16 -16.9894 0.83544E+00 -0.0781 51 FeO2- 0.42121E-09 -9.3755 0.35121E-09 -9.4544 0.83381E+00 -0.0789 52 HFeO2,aq 0.33285E-11 -11.4777 0.33285E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10917E-04 -4.9619 0.10878E-04 -4.9635 0.99642E+00 -0.0016 54 KCl,aq 0.28293E-09 -9.5483 0.28293E-09 -9.5483 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10399E-14 -14.9830 0.86712E-15 -15.0619 0.83381E+00 -0.0789 58 MgCO3,aq 0.10555E-13 -13.9766 0.10555E-13 -13.9766 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.86874E-16 -16.0611 0.72578E-16 -16.1392 0.83544E+00 -0.0781 60 MgCl+ 0.23779E-14 -14.6238 0.19866E-14 -14.7019 0.83544E+00 -0.0781 61 MgOH+ 0.71550E-10 -10.1454 0.59776E-10 -10.2235 0.83544E+00 -0.0781 63 MnO,aq 0.18277E-08 -8.7381 0.18277E-08 -8.7381 0.10000E+01 0.0000 64 MnOH+ 0.48334E-09 -9.3158 0.40380E-09 -9.3938 0.83544E+00 -0.0781 65 MnO2-2 0.21409E-10 -10.6694 0.11022E-10 -10.9577 0.51483E+00 -0.2883 66 HMnO2- 0.21688E-09 -9.6638 0.18084E-09 -9.7427 0.83381E+00 -0.0789 69 MnCl+ 0.85244E-14 -14.0693 0.71216E-14 -14.1474 0.83544E+00 -0.0781 71 NaCl,aq 0.66207E-06 -6.1791 0.66207E-06 -6.1791 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95170E-02 -2.0215 0.79208E-02 -2.1012 0.83228E+00 -0.0797 79 HPO3-2 0.16793E-14 -14.7749 0.86455E-15 -15.0632 0.51483E+00 -0.2883 81 H2PO3- 0.15424E-18 -18.8118 0.12861E-18 -18.8907 0.83381E+00 -0.0789 82 H3PO4,aq 0.92902E-18 -18.0320 0.92902E-18 -18.0320 0.10000E+01 0.0000 83 H2PO4- 0.40028E-10 -10.3976 0.33408E-10 -10.4762 0.83462E+00 -0.0785 84 PO4-3 0.12126E-08 -8.9163 0.29018E-09 -9.5373 0.23931E+00 -0.6210 88 HP2O7-3 0.10380E-17 -17.9838 0.23652E-18 -18.6261 0.22785E+00 -0.6423 89 P2O7-4 0.10254E-16 -16.9891 0.77051E-18 -18.1132 0.75140E-01 -1.1241 90 H2S,aq 0.50254E-08 -8.2988 0.50074E-08 -8.3004 0.99642E+00 -0.0016 91 S2-2 0.19021E-14 -14.7208 0.97925E-15 -15.0091 0.51483E+00 -0.2883 97 SO3-2 0.11851E-17 -17.9262 0.61912E-18 -18.2082 0.52243E+00 -0.2820 99 HSO4- 0.35073E-19 -19.4550 0.29331E-19 -19.5327 0.83627E+00 -0.0777 Charge balance for all species = 0.3772E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9026449E-10 -.2312518E-01 -.2326660E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981187E+06 0.0000 3 Cl- 0.1421292E-03 0.1427916E-03 0.5053227E+01 6.1945 4 SO4-- 0.8090486E-12 -.1538524E-04 -.1475255E+01 7.8621 5 HCO3- 0.2919093E-06 0.1352635E-04 0.8238457E+00 3.5077 6 HS- 0.2638994E-04 0.4178021E-04 0.1379254E+01 5.4633 7 Al+++ 0.1101138E-28 0.5281873E-05 0.1422549E+00 0.7613 8 H4SiO4 0.7114331E-03 0.1419494E-01 0.1361883E+04 -3.1479 9 Ca++ 0.1431753E-06 0.2431956E-06 0.9729151E-02 13.1067 10 Mg++ 0.2273537E-10 0.9784394E-10 0.2374476E-05 9.3055 11 Fe++ 0.6217689E-13 0.3792493E-07 0.2114160E-02 6.7429 12 K+ 0.1614292E-03 0.1622057E-03 0.6331085E+01 6.2505 13 Na+ 0.2052332E-01 0.2311399E-01 0.5304240E+03 8.3540 14 Mn++ 0.1944261E-10 0.2568775E-08 0.1408679E-03 9.2384 15 HPO4-- 0.4876292E-07 0.5001551E-07 0.4791749E-02 12.6422 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5298695E+01 -.2234499E-01 -.5276350E+01 0.0000000E+00 2 H2O 0.5149693E+02 0.5363184E+02 -.2134906E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8893768E-02 -.1486618E-04 0.8908634E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8868263E-02 0.4037065E-04 -.8908634E-02 0.0000000E+00 7 Al+++ 0.1043434E+01 0.5103676E-05 0.1043429E+01 0.0000000E+00 8 H4SiO4 0.3332080E+01 0.1371604E-01 0.3318364E+01 0.0000000E+00 9 Ca++ 0.3680590E+00 0.2349908E-06 0.3680587E+00 0.0000000E+00 10 Mg++ 0.2539675E+00 0.9454293E-10 0.2539675E+00 0.0000000E+00 11 Fe++ 0.2281620E+00 0.3664544E-07 0.2281620E+00 0.0000000E+00 12 K+ 0.6794034E-01 0.1567333E-03 0.6778361E-01 0.0000000E+00 13 Na+ 0.4018368E+00 0.2233418E-01 0.3795026E+00 0.0000000E+00 14 Mn++ 0.5548333E-02 0.2482111E-08 0.5548331E-02 0.0000000E+00 15 HPO4-- 0.1893619E-02 0.4832811E-07 0.1893570E-02 0.0000000E+00 Chg. balance for solid moles: -.5256E-15 Mass of aqueous solution: 0.968015E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 319.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3791 -0.421 99.42 1.997 28.45 38.16 andradite 0.3563E-01 -1.448 18.11 1.258 5.183 4.705 grossular 0.8518E-02 -2.070 3.837 0.584 1.098 1.068 apatite-OH 0.6312E-03 -3.200 0.3171 -0.499 0.9074E-01 0.1007 clinochlore 0.4686E-01 -1.329 26.04 1.416 7.454 9.906 daphnite 0.1343E-01 -1.872 9.579 0.981 2.742 2.903 chlorite-Mn 0.1110E-02 -2.955 0.7867 -0.104 0.2252 0.2507 diopside 0.9018E-02 -2.045 1.953 0.291 0.5589 0.5969 hedenbergite 0.2310E-02 -2.636 0.5731 -0.242 0.1640 0.1570 microcline 0.5941E-01 -1.226 16.54 1.218 4.732 6.459 stilbite 0.2152 -0.667 151.7 2.181 43.41 70.74 stilpnomelane-Fe 0.1675E-01 -1.776 18.06 1.257 5.169 6.239 tr.625ac.25prg.125 0.2944E-02 -2.531 2.517 0.401 0.7203 0.8100 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8071E+00 0.8071E+00 1.0000 -0.093 grossular 0.1929E+00 0.1929E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7632E+00 0.7632E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1808E-01 0.1808E-01 1.0000 -1.743 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 349.404215 g Volume = 142.102776 cm3 Porosity: -10.1575% V(tot) - V(min): -.13103E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 319.9990000 g log = 2.5051 Original solution: 1000.0103000 g Original solution / Rock added: 3.13 (Water/Rock Ratio), log = 0.4949 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0870 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9682E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3891E-08 1.0071 0.4260E-08 0.4230E-08 CH4,gas 0.1811E-01 1.0128 0.1994E-01 0.1969E-01 H2,gas 0.1372E-01 1.0006 0.1492E-01 0.1491E-01 H2S,gas 0.1349E-06 0.9958 0.1460E-06 0.1467E-06 S2,gas 0.3301E-29 1.0000 0.3589E-29 0.3589E-29 CO,gas 0.1515E-13 1.0000 0.1646E-13 0.1646E-13 SO3,gas 0.8233E-48 1.0000 0.8950E-48 0.8950E-48 SO2,gas 0.4647E-27 1.0000 0.5051E-27 0.5051E-27 HCl,gas 0.2742E-17 1.0000 0.2981E-17 0.2981E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.48529E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.73 -10.37 -3.457 0.17707E+05 -8.371 3 CH4,gas 4.81 1.11 -3.70 -0.925 0.63180E+04 -1.700 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65332E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.418 0.15086E+05 -6.836 6 S2,gas -7.03 -38.48 -31.45 -4.838 0.53692E+05 -29.445 7 CO,gas 3.51 -12.27 -15.78 -4.856 0.26950E+05 -13.783 8 SO3,gas 17.43 -32.62 -50.05 -12.512 0.85456E+05 -48.048 9 SO2,gas 1.14 -28.16 -29.30 -7.812 0.50023E+05 -27.297 10 HCl,gas 5.48 -14.05 -19.53 -9.763 0.33340E+05 -17.526 11 acmite 7.74 6.57 -1.17 -0.121 0.19919E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.79 -4.76 -0.238 0.81204E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94104E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41192E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28377E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76225E+04 35 aragonite 0.99 -3.63 -4.61 -1.538 0.78771E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55853E+04 37 calcite 0.83 -3.63 -4.46 -1.487 0.76158E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52884E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71152E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70315E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82184E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47360E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39556E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68644E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70367E+04 52 chloritoid-Mn 11.46 7.61 -3.85 -0.257 0.65741E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13293E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10222E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36452E+04 66 diamond -3.11 -7.81 -4.71 -1.344 0.80338E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33643E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66038E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57723E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68258E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56963E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36651E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70706E+04 86 graphite -3.55 -7.81 -4.26 -1.218 0.72800E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38610E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60999E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24441E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64138E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59763E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15996E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22964E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58935E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28458E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74527E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48210E+04 112 manganosite 14.07 9.24 -4.83 -1.207 0.82463E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61272E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53657E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41163E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83602E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36596E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20046E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92746E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40669E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43416E+04 143 pyrrhotite -4.24 -8.04 -3.79 -1.264 0.64742E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.262 0.58571E+04 145 pyroxmangite 7.42 6.09 -1.33 -0.265 0.22633E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84877E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28321E+03 152 rhodonite 7.46 6.09 -1.37 -0.274 0.23425E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27387E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20974E+04 174 tephroite 18.11 15.33 -2.78 -0.398 0.47536E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91051E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76036E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65764E+04 181 troilite-low -4.39 -8.04 -3.64 -1.214 0.62174E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80349E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34504E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66764E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55581E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60353E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66126E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68738E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73632E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60306E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57941E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83189E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61767E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66253E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52972E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.54 -4.58 -1.526 0.78157E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62636E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18237E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11529E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14890E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18335E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 319.9990000 g New total amount of reactant added: 329.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3649E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 329.9990000 Water: Moles liquid = 0.5358E+02 kg liquid = 0.9653E+00 Moles total = 0.5137E+02 kg total = 0.9255E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173178E-01 Osmotic coef. = 0.9690 True ionic strength = .2068606E-01 Chg. balance for total moles = 0.3649E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90265E-10 -10.0445 0.75729E-10 -10.1207 0.83896E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14228E-03 -3.8469 0.11863E-03 -3.9258 0.83381E+00 -0.0789 4 SO4-- 0.80996E-12 -12.0915 0.41789E-12 -12.3789 0.51594E+00 -0.2874 5 HCO3- 0.29224E-06 -6.5343 0.24403E-06 -6.6125 0.83506E+00 -0.0783 6 HS- 0.26417E-04 -4.5781 0.22030E-04 -4.6570 0.83394E+00 -0.0789 7 Al+++ 0.11011E-28 -28.9582 0.25063E-29 -29.6010 0.22761E+00 -0.6428 8 H4SiO4 0.71144E-03 -3.1479 0.71144E-03 -3.1479 0.10000E+01 0.0000 9 Ca++ 0.14318E-06 -6.8441 0.73317E-07 -7.1348 0.51207E+00 -0.2907 10 Mg++ 0.22735E-10 -10.6433 0.11588E-10 -10.9360 0.50969E+00 -0.2927 11 Fe++ 0.62178E-13 -13.2064 0.31726E-13 -13.4986 0.51025E+00 -0.2922 12 K+ 0.16143E-03 -3.7920 0.13484E-03 -3.8702 0.83526E+00 -0.0782 13 Na+ 0.20523E-01 -1.6877 0.17110E-01 -1.7668 0.83366E+00 -0.0790 14 Mn++ 0.19460E-10 -10.7109 0.99378E-11 -11.0027 0.51069E+00 -0.2918 15 HPO4-- 0.48763E-07 -7.3119 0.25163E-07 -7.5992 0.51602E+00 -0.2873 16 HSiO3- 0.10993E-01 -1.9589 0.91659E-02 -2.0378 0.83381E+00 -0.0789 17 Ca(HSiO3)+ 0.18023E-07 -7.7442 0.15057E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35450E-11 -11.4504 0.29616E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24908E-02 -2.6037 0.24908E-02 -2.6037 0.10000E+01 0.0000 20 AlO+ 0.67532E-16 -16.1705 0.56419E-16 -16.2486 0.83544E+00 -0.0781 22 HAlO2,aq 0.14908E-09 -9.8266 0.14908E-09 -9.8266 0.10000E+01 0.0000 23 AlO2- 0.52815E-05 -5.2772 0.43957E-05 -5.3570 0.83228E+00 -0.0797 24 CH4,aq 0.12669E-04 -4.8973 0.12624E-04 -4.8988 0.99642E+00 -0.0016 25 C2H6,aq 0.25356E-14 -14.5959 0.25265E-14 -14.5975 0.99642E+00 -0.0016 29 CO,aq 0.10439E-16 -16.9813 0.10439E-16 -16.9813 0.10000E+01 0.0000 30 CO2,aq 0.37394E-10 -10.4272 0.37260E-10 -10.4288 0.99642E+00 -0.0016 31 CO3-2 0.57873E-06 -6.2375 0.29795E-06 -6.5259 0.51483E+00 -0.2883 32 CaCO3,aq 0.26754E-09 -9.5726 0.26754E-09 -9.5726 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.53962E-12 -12.2679 0.45082E-12 -12.3460 0.83544E+00 -0.0781 34 CaCl+ 0.16590E-10 -10.7802 0.13860E-10 -10.8582 0.83544E+00 -0.0781 35 CaCl2,aq 0.38283E-15 -15.4170 0.38283E-15 -15.4170 0.10000E+01 0.0000 36 CaOH+ 0.81713E-07 -7.0877 0.68266E-07 -7.1658 0.83544E+00 -0.0781 37 CaSO4,aq 0.95463E-17 -17.0202 0.95463E-17 -17.0202 0.10000E+01 0.0000 38 HCl,aq 0.16899E-14 -14.7722 0.16899E-14 -14.7722 0.10000E+01 0.0000 43 FeCl+ 0.70168E-17 -17.1539 0.58621E-17 -17.2319 0.83544E+00 -0.0781 46 FeO,aq 0.21876E-09 -9.6600 0.21876E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16625E-10 -10.7792 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37265E-07 -7.4287 0.31072E-07 -7.5076 0.83381E+00 -0.0789 49 FeO+ 0.12267E-16 -16.9113 0.10248E-16 -16.9894 0.83544E+00 -0.0781 51 FeO2- 0.42121E-09 -9.3755 0.35121E-09 -9.4544 0.83381E+00 -0.0789 52 HFeO2,aq 0.33286E-11 -11.4777 0.33286E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10917E-04 -4.9619 0.10878E-04 -4.9635 0.99642E+00 -0.0016 54 KCl,aq 0.28323E-09 -9.5479 0.28323E-09 -9.5479 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10411E-14 -14.9825 0.86810E-15 -15.0614 0.83381E+00 -0.0789 58 MgCO3,aq 0.10566E-13 -13.9761 0.10566E-13 -13.9761 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.86972E-16 -16.0606 0.72659E-16 -16.1387 0.83544E+00 -0.0781 60 MgCl+ 0.23804E-14 -14.6234 0.19887E-14 -14.7014 0.83544E+00 -0.0781 61 MgOH+ 0.71550E-10 -10.1454 0.59776E-10 -10.2235 0.83544E+00 -0.0781 63 MnO,aq 0.18293E-08 -8.7377 0.18293E-08 -8.7377 0.10000E+01 0.0000 64 MnOH+ 0.48376E-09 -9.3154 0.40415E-09 -9.3935 0.83544E+00 -0.0781 65 MnO2-2 0.21427E-10 -10.6690 0.11031E-10 -10.9574 0.51483E+00 -0.2883 66 HMnO2- 0.21707E-09 -9.6634 0.18099E-09 -9.7423 0.83381E+00 -0.0789 69 MnCl+ 0.85407E-14 -14.0685 0.71352E-14 -14.1466 0.83544E+00 -0.0781 71 NaCl,aq 0.66276E-06 -6.1786 0.66276E-06 -6.1786 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95169E-02 -2.0215 0.79208E-02 -2.1012 0.83228E+00 -0.0797 79 HPO3-2 0.16793E-14 -14.7749 0.86453E-15 -15.0632 0.51483E+00 -0.2883 81 H2PO3- 0.15424E-18 -18.8118 0.12861E-18 -18.8907 0.83381E+00 -0.0789 82 H3PO4,aq 0.92903E-18 -18.0320 0.92903E-18 -18.0320 0.10000E+01 0.0000 83 H2PO4- 0.40028E-10 -10.3976 0.33408E-10 -10.4761 0.83462E+00 -0.0785 84 PO4-3 0.12126E-08 -8.9163 0.29018E-09 -9.5373 0.23931E+00 -0.6210 88 HP2O7-3 0.10381E-17 -17.9838 0.23652E-18 -18.6261 0.22785E+00 -0.6423 89 P2O7-4 0.10254E-16 -16.9891 0.77051E-18 -18.1132 0.75139E-01 -1.1241 90 H2S,aq 0.50306E-08 -8.2984 0.50127E-08 -8.2999 0.99642E+00 -0.0016 91 S2-2 0.19061E-14 -14.7199 0.98131E-15 -15.0082 0.51483E+00 -0.2883 97 SO3-2 0.11864E-17 -17.9258 0.61981E-18 -18.2077 0.52243E+00 -0.2820 99 HSO4- 0.35113E-19 -19.4545 0.29364E-19 -19.5322 0.83627E+00 -0.0777 Charge balance for all species = 0.3779E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9026517E-10 -.2312518E-01 -.2326660E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981187E+06 0.0000 3 Cl- 0.1422772E-03 0.1429402E-03 0.5058487E+01 6.1949 4 SO4-- 0.8099617E-12 -.1539828E-04 -.1476506E+01 7.8625 5 HCO3- 0.2922369E-06 0.1354042E-04 0.8247032E+00 3.5082 6 HS- 0.2641741E-04 0.4182072E-04 0.1380591E+01 5.4638 7 Al+++ 0.1101133E-28 0.5281680E-05 0.1422497E+00 0.7612 8 H4SiO4 0.7114403E-03 0.1419501E-01 0.1361890E+04 -3.1479 9 Ca++ 0.1431761E-06 0.2431967E-06 0.9729193E-02 13.1067 10 Mg++ 0.2273548E-10 0.9784382E-10 0.2374473E-05 9.3055 11 Fe++ 0.6217764E-13 0.3792453E-07 0.2114137E-02 6.7429 12 K+ 0.1614304E-03 0.1622069E-03 0.6331132E+01 6.2505 13 Na+ 0.2052347E-01 0.2311416E-01 0.5304281E+03 8.3540 14 Mn++ 0.1945962E-10 0.2570984E-08 0.1409890E-03 9.2388 15 HPO4-- 0.4876316E-07 0.5001576E-07 0.4791772E-02 12.6422 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5464280E+01 -.2232176E-01 -.5441959E+01 0.0000000E+00 2 H2O 0.5137158E+02 0.5357607E+02 -.2204496E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9170902E-02 -.1486331E-04 0.9185765E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9145397E-02 0.4036778E-04 -.9185765E-02 0.0000000E+00 7 Al+++ 0.1076041E+01 0.5098183E-05 0.1076036E+01 0.0000000E+00 8 H4SiO4 0.3436208E+01 0.1370185E-01 0.3422506E+01 0.0000000E+00 9 Ca++ 0.3795604E+00 0.2347475E-06 0.3795602E+00 0.0000000E+00 10 Mg++ 0.2619040E+00 0.9444451E-10 0.2619040E+00 0.0000000E+00 11 Fe++ 0.2352921E+00 0.3660695E-07 0.2352921E+00 0.0000000E+00 12 K+ 0.7006348E-01 0.1565715E-03 0.6990691E-01 0.0000000E+00 13 Na+ 0.4143892E+00 0.2231113E-01 0.3920781E+00 0.0000000E+00 14 Mn++ 0.5721719E-02 0.2481663E-08 0.5721717E-02 0.0000000E+00 15 HPO4-- 0.1952794E-02 0.4827810E-07 0.1952746E-02 0.0000000E+00 Chg. balance for solid moles: 0.1095E-14 Mass of aqueous solution: 0.967008E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 329.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.3917 -0.407 102.7 2.012 28.50 39.43 andradite 0.3674E-01 -1.435 18.67 1.271 5.182 4.851 grossular 0.8783E-02 -2.056 3.956 0.597 1.098 1.101 apatite-OH 0.6509E-03 -3.186 0.3270 -0.485 0.9074E-01 0.1039 clinochlore 0.4828E-01 -1.316 26.83 1.429 7.447 10.21 daphnite 0.1383E-01 -1.859 9.870 0.994 2.739 2.991 chlorite-Mn 0.1144E-02 -2.941 0.8113 -0.091 0.2252 0.2585 diopside 0.9596E-02 -2.018 2.078 0.318 0.5767 0.6351 hedenbergite 0.2458E-02 -2.609 0.6098 -0.215 0.1692 0.1670 microcline 0.6127E-01 -1.213 17.05 1.232 4.732 6.661 stilbite 0.2216 -0.654 156.2 2.194 43.35 72.85 stilpnomelane-Fe 0.1728E-01 -1.762 18.63 1.270 5.171 6.436 tr.625ac.25prg.125 0.3013E-02 -2.521 2.575 0.411 0.7146 0.8288 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8071E+00 0.8071E+00 1.0000 -0.093 grossular 0.1929E+00 0.1929E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7632E+00 0.7632E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1809E-01 0.1809E-01 1.0000 -1.743 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 360.329757 g Volume = 146.523412 cm3 Porosity: -10.1683% V(tot) - V(min): -.13524E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 329.9990000 g log = 2.5185 Original solution: 1000.0103000 g Original solution / Rock added: 3.03 (Water/Rock Ratio), log = 0.4815 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0871 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9682E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3896E-08 1.0071 0.4265E-08 0.4235E-08 CH4,gas 0.1813E-01 1.0128 0.1996E-01 0.1971E-01 H2,gas 0.1372E-01 1.0006 0.1492E-01 0.1491E-01 H2S,gas 0.1351E-06 0.9958 0.1462E-06 0.1468E-06 S2,gas 0.3308E-29 1.0000 0.3596E-29 0.3596E-29 CO,gas 0.1516E-13 1.0000 0.1648E-13 0.1648E-13 SO3,gas 0.8242E-48 1.0000 0.8960E-48 0.8960E-48 SO2,gas 0.4652E-27 1.0000 0.5057E-27 0.5057E-27 HCl,gas 0.2745E-17 1.0000 0.2984E-17 0.2984E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.73 -10.37 -3.457 0.17707E+05 -8.370 3 CH4,gas 4.81 1.11 -3.70 -0.925 0.63173E+04 -1.700 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65332E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.84 -4.418 0.15086E+05 -6.835 6 S2,gas -7.03 -38.48 -31.44 -4.838 0.53690E+05 -29.444 7 CO,gas 3.51 -12.27 -15.78 -4.856 0.26949E+05 -13.783 8 SO3,gas 17.43 -32.62 -50.05 -12.512 0.85455E+05 -48.048 9 SO2,gas 1.14 -28.16 -29.30 -7.812 0.50022E+05 -27.296 10 HCl,gas 5.48 -14.05 -19.53 -9.763 0.33339E+05 -17.525 11 acmite 7.74 6.57 -1.17 -0.121 0.19919E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.80 -4.75 -0.238 0.81185E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94105E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41192E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28377E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76225E+04 35 aragonite 0.99 -3.63 -4.61 -1.538 0.78763E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55853E+04 37 calcite 0.83 -3.63 -4.46 -1.487 0.76150E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52884E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71152E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70316E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82184E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47360E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39556E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68645E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70367E+04 52 chloritoid-Mn 11.46 7.61 -3.85 -0.257 0.65735E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13293E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10222E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36452E+04 66 diamond -3.11 -7.81 -4.70 -1.344 0.80330E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83438E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33644E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66039E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57723E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68258E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56964E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36652E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70705E+04 86 graphite -3.55 -7.81 -4.26 -1.218 0.72792E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38610E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60999E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24441E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64138E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59763E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15996E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22964E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58935E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28459E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74527E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48210E+04 112 manganosite 14.07 9.24 -4.83 -1.207 0.82457E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61273E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53657E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41163E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83602E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36596E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20047E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92747E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40670E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43417E+04 143 pyrrhotite -4.24 -8.03 -3.79 -1.264 0.64735E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.261 0.58563E+04 145 pyroxmangite 7.42 6.09 -1.33 -0.265 0.22626E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84877E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28321E+03 152 rhodonite 7.46 6.09 -1.37 -0.274 0.23419E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27388E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20974E+04 174 tephroite 18.11 15.33 -2.78 -0.398 0.47523E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91050E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76036E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65764E+04 181 troilite-low -4.39 -8.03 -3.64 -1.214 0.62167E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80352E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34504E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66764E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55581E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60352E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66126E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68738E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73632E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60307E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57941E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83189E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61767E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66253E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52971E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.54 -4.58 -1.526 0.78143E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62636E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18237E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11529E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14890E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18335E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 329.9990000 g New total amount of reactant added: 339.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3648E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 339.9990000 Water: Moles liquid = 0.5352E+02 kg liquid = 0.9643E+00 Moles total = 0.5125E+02 kg total = 0.9232E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173195E-01 Osmotic coef. = 0.9690 True ionic strength = .2068621E-01 Chg. balance for total moles = 0.3648E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90266E-10 -10.0445 0.75730E-10 -10.1207 0.83896E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14243E-03 -3.8464 0.11876E-03 -3.9253 0.83381E+00 -0.0789 4 SO4-- 0.81087E-12 -12.0910 0.41836E-12 -12.3784 0.51594E+00 -0.2874 5 HCO3- 0.29256E-06 -6.5338 0.24431E-06 -6.6121 0.83505E+00 -0.0783 6 HS- 0.26445E-04 -4.5777 0.22053E-04 -4.6565 0.83394E+00 -0.0789 7 Al+++ 0.11011E-28 -28.9582 0.25063E-29 -29.6010 0.22761E+00 -0.6428 8 H4SiO4 0.71145E-03 -3.1479 0.71145E-03 -3.1479 0.10000E+01 0.0000 9 Ca++ 0.14318E-06 -6.8441 0.73317E-07 -7.1348 0.51207E+00 -0.2907 10 Mg++ 0.22736E-10 -10.6433 0.11588E-10 -10.9360 0.50968E+00 -0.2927 11 Fe++ 0.62178E-13 -13.2064 0.31727E-13 -13.4986 0.51025E+00 -0.2922 12 K+ 0.16143E-03 -3.7920 0.13484E-03 -3.8702 0.83525E+00 -0.0782 13 Na+ 0.20524E-01 -1.6877 0.17110E-01 -1.7668 0.83365E+00 -0.0790 14 Mn++ 0.19476E-10 -10.7105 0.99459E-11 -11.0024 0.51068E+00 -0.2918 15 HPO4-- 0.48763E-07 -7.3119 0.25163E-07 -7.5992 0.51602E+00 -0.2873 16 HSiO3- 0.10993E-01 -1.9589 0.91660E-02 -2.0378 0.83381E+00 -0.0789 17 Ca(HSiO3)+ 0.18023E-07 -7.7442 0.15057E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35450E-11 -11.4504 0.29617E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24908E-02 -2.6037 0.24908E-02 -2.6037 0.10000E+01 0.0000 20 AlO+ 0.67530E-16 -16.1705 0.56418E-16 -16.2486 0.83544E+00 -0.0781 22 HAlO2,aq 0.14908E-09 -9.8266 0.14908E-09 -9.8266 0.10000E+01 0.0000 23 AlO2- 0.52813E-05 -5.2773 0.43956E-05 -5.3570 0.83228E+00 -0.0797 24 CH4,aq 0.12682E-04 -4.8968 0.12637E-04 -4.8984 0.99642E+00 -0.0016 25 C2H6,aq 0.25409E-14 -14.5950 0.25318E-14 -14.5966 0.99642E+00 -0.0016 29 CO,aq 0.10450E-16 -16.9809 0.10450E-16 -16.9809 0.10000E+01 0.0000 30 CO2,aq 0.37436E-10 -10.4267 0.37302E-10 -10.4283 0.99642E+00 -0.0016 31 CO3-2 0.57938E-06 -6.2370 0.29828E-06 -6.5254 0.51482E+00 -0.2883 32 CaCO3,aq 0.26784E-09 -9.5721 0.26784E-09 -9.5721 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.54023E-12 -12.2674 0.45133E-12 -12.3455 0.83544E+00 -0.0781 34 CaCl+ 0.16607E-10 -10.7797 0.13874E-10 -10.8578 0.83544E+00 -0.0781 35 CaCl2,aq 0.38363E-15 -15.4161 0.38363E-15 -15.4161 0.10000E+01 0.0000 36 CaOH+ 0.81713E-07 -7.0877 0.68266E-07 -7.1658 0.83544E+00 -0.0781 37 CaSO4,aq 0.95570E-17 -17.0197 0.95570E-17 -17.0197 0.10000E+01 0.0000 38 HCl,aq 0.16916E-14 -14.7717 0.16916E-14 -14.7717 0.10000E+01 0.0000 43 FeCl+ 0.70242E-17 -17.1534 0.58683E-17 -17.2315 0.83544E+00 -0.0781 46 FeO,aq 0.21876E-09 -9.6600 0.21876E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16625E-10 -10.7792 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37264E-07 -7.4287 0.31071E-07 -7.5076 0.83381E+00 -0.0789 49 FeO+ 0.12267E-16 -16.9113 0.10248E-16 -16.9894 0.83544E+00 -0.0781 51 FeO2- 0.42121E-09 -9.3755 0.35121E-09 -9.4544 0.83381E+00 -0.0789 52 HFeO2,aq 0.33286E-11 -11.4777 0.33286E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10917E-04 -4.9619 0.10877E-04 -4.9635 0.99642E+00 -0.0016 54 KCl,aq 0.28353E-09 -9.5474 0.28353E-09 -9.5474 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10423E-14 -14.9820 0.86908E-15 -15.0609 0.83381E+00 -0.0789 58 MgCO3,aq 0.10578E-13 -13.9756 0.10578E-13 -13.9756 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.87069E-16 -16.0601 0.72741E-16 -16.1382 0.83544E+00 -0.0781 60 MgCl+ 0.23829E-14 -14.6229 0.19907E-14 -14.7010 0.83544E+00 -0.0781 61 MgOH+ 0.71550E-10 -10.1454 0.59776E-10 -10.2235 0.83544E+00 -0.0781 63 MnO,aq 0.18307E-08 -8.7374 0.18307E-08 -8.7374 0.10000E+01 0.0000 64 MnOH+ 0.48415E-09 -9.3150 0.40448E-09 -9.3931 0.83544E+00 -0.0781 65 MnO2-2 0.21444E-10 -10.6687 0.11040E-10 -10.9570 0.51482E+00 -0.2883 66 HMnO2- 0.21724E-09 -9.6631 0.18114E-09 -9.7420 0.83381E+00 -0.0789 69 MnCl+ 0.85567E-14 -14.0677 0.71486E-14 -14.1458 0.83544E+00 -0.0781 71 NaCl,aq 0.66346E-06 -6.1782 0.66346E-06 -6.1782 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95169E-02 -2.0215 0.79207E-02 -2.1012 0.83228E+00 -0.0797 79 HPO3-2 0.16792E-14 -14.7749 0.86452E-15 -15.0632 0.51482E+00 -0.2883 81 H2PO3- 0.15424E-18 -18.8118 0.12860E-18 -18.8907 0.83381E+00 -0.0789 82 H3PO4,aq 0.92905E-18 -18.0320 0.92905E-18 -18.0320 0.10000E+01 0.0000 83 H2PO4- 0.40028E-10 -10.3976 0.33408E-10 -10.4761 0.83462E+00 -0.0785 84 PO4-3 0.12126E-08 -8.9163 0.29018E-09 -9.5373 0.23931E+00 -0.6210 88 HP2O7-3 0.10381E-17 -17.9838 0.23653E-18 -18.6261 0.22785E+00 -0.6423 89 P2O7-4 0.10255E-16 -16.9891 0.77051E-18 -18.1132 0.75139E-01 -1.1241 90 H2S,aq 0.50359E-08 -8.2979 0.50179E-08 -8.2995 0.99642E+00 -0.0016 91 S2-2 0.19101E-14 -14.7189 0.98338E-15 -15.0073 0.51482E+00 -0.2883 97 SO3-2 0.11877E-17 -17.9253 0.62049E-18 -18.2073 0.52243E+00 -0.2820 99 HSO4- 0.35153E-19 -19.4540 0.29397E-19 -19.5317 0.83627E+00 -0.0777 Charge balance for all species = 0.3782E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9026583E-10 -.2312517E-01 -.2326659E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981187E+06 0.0000 3 Cl- 0.1424254E-03 0.1430892E-03 0.5063757E+01 6.1954 4 SO4-- 0.8108725E-12 -.1541136E-04 -.1477760E+01 7.8630 5 HCO3- 0.2925638E-06 0.1355453E-04 0.8255624E+00 3.5087 6 HS- 0.2644494E-04 0.4186133E-04 0.1381932E+01 5.4642 7 Al+++ 0.1101129E-28 0.5281496E-05 0.1422447E+00 0.7612 8 H4SiO4 0.7114470E-03 0.1419508E-01 0.1361896E+04 -3.1479 9 Ca++ 0.1431770E-06 0.2431978E-06 0.9729237E-02 13.1067 10 Mg++ 0.2273559E-10 0.9784369E-10 0.2374470E-05 9.3055 11 Fe++ 0.6217838E-13 0.3792415E-07 0.2114116E-02 6.7429 12 K+ 0.1614316E-03 0.1622080E-03 0.6331177E+01 6.2505 13 Na+ 0.2052362E-01 0.2311434E-01 0.5304320E+03 8.3540 14 Mn++ 0.1947568E-10 0.2573067E-08 0.1411032E-03 9.2391 15 HPO4-- 0.4876337E-07 0.5001597E-07 0.4791792E-02 12.6422 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5629866E+01 -.2229852E-01 -.5607567E+01 0.0000000E+00 2 H2O 0.5124622E+02 0.5352031E+02 -.2274086E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9448036E-02 -.1486045E-04 0.9462896E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9422531E-02 0.4036492E-04 -.9462896E-02 0.0000000E+00 7 Al+++ 0.1108649E+01 0.5092699E-05 0.1108644E+01 0.0000000E+00 8 H4SiO4 0.3540336E+01 0.1368765E-01 0.3526648E+01 0.0000000E+00 9 Ca++ 0.3910618E+00 0.2345042E-06 0.3910616E+00 0.0000000E+00 10 Mg++ 0.2698405E+00 0.9434609E-10 0.2698405E+00 0.0000000E+00 11 Fe++ 0.2424222E+00 0.3656848E-07 0.2424222E+00 0.0000000E+00 12 K+ 0.7218662E-01 0.1564096E-03 0.7203021E-01 0.0000000E+00 13 Na+ 0.4269416E+00 0.2228807E-01 0.4046536E+00 0.0000000E+00 14 Mn++ 0.5895105E-02 0.2481088E-08 0.5895103E-02 0.0000000E+00 15 HPO4-- 0.2011970E-02 0.4822805E-07 0.2011922E-02 0.0000000E+00 Chg. balance for solid moles: -.1418E-14 Mass of aqueous solution: 0.966002E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 339.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4043 -0.393 106.0 2.025 28.55 40.69 andradite 0.3785E-01 -1.422 19.24 1.284 5.181 4.998 grossular 0.9047E-02 -2.043 4.075 0.610 1.098 1.134 apatite-OH 0.6706E-03 -3.174 0.3369 -0.473 0.9074E-01 0.1070 clinochlore 0.4970E-01 -1.304 27.62 1.441 7.441 10.51 daphnite 0.1424E-01 -1.846 10.16 1.007 2.737 3.079 chlorite-Mn 0.1179E-02 -2.928 0.8359 -0.078 0.2252 0.2664 diopside 0.1017E-01 -1.992 2.203 0.343 0.5935 0.6734 hedenbergite 0.2606E-02 -2.584 0.6466 -0.189 0.1742 0.1771 microcline 0.6312E-01 -1.200 17.57 1.245 4.733 6.863 stilbite 0.2281 -0.642 160.7 2.206 43.29 74.97 stilpnomelane-Fe 0.1781E-01 -1.749 19.20 1.283 5.172 6.632 tr.625ac.25prg.125 0.3081E-02 -2.511 2.633 0.420 0.7093 0.8475 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8071E+00 0.8071E+00 1.0000 -0.093 grossular 0.1929E+00 0.1929E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7632E+00 0.7632E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1811E-01 0.1811E-01 1.0000 -1.742 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 371.255301 g Volume = 150.944047 cm3 Porosity: -10.1785% V(tot) - V(min): -.13944E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 339.9990000 g log = 2.5315 Original solution: 1000.0103000 g Original solution / Rock added: 2.94 (Water/Rock Ratio), log = 0.4685 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0871 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9681E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3900E-08 1.0071 0.4270E-08 0.4240E-08 CH4,gas 0.1815E-01 1.0128 0.1998E-01 0.1973E-01 H2,gas 0.1372E-01 1.0006 0.1492E-01 0.1491E-01 H2S,gas 0.1352E-06 0.9958 0.1464E-06 0.1470E-06 S2,gas 0.3315E-29 1.0000 0.3604E-29 0.3604E-29 CO,gas 0.1518E-13 1.0000 0.1650E-13 0.1650E-13 SO3,gas 0.8251E-48 1.0000 0.8970E-48 0.8970E-48 SO2,gas 0.4657E-27 1.0000 0.5063E-27 0.5063E-27 HCl,gas 0.2748E-17 1.0000 0.2987E-17 0.2987E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.54595E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.73 -10.37 -3.457 0.17706E+05 -8.370 3 CH4,gas 4.81 1.11 -3.70 -0.925 0.63165E+04 -1.699 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65332E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.83 -4.417 0.15085E+05 -6.835 6 S2,gas -7.03 -38.48 -31.44 -4.837 0.53688E+05 -29.443 7 CO,gas 3.51 -12.27 -15.78 -4.856 0.26948E+05 -13.782 8 SO3,gas 17.43 -32.62 -50.05 -12.512 0.85454E+05 -48.047 9 SO2,gas 1.14 -28.16 -29.30 -7.812 0.50021E+05 -27.296 10 HCl,gas 5.48 -14.05 -19.52 -9.762 0.33338E+05 -17.525 11 acmite 7.74 6.57 -1.17 -0.121 0.19919E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.80 -4.75 -0.238 0.81167E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94106E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41192E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28378E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76226E+04 35 aragonite 0.99 -3.63 -4.61 -1.537 0.78755E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55854E+04 37 calcite 0.83 -3.63 -4.46 -1.486 0.76141E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52884E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71152E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70316E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82185E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47360E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39556E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68645E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70368E+04 52 chloritoid-Mn 11.46 7.61 -3.85 -0.257 0.65729E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13293E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10222E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36452E+04 66 diamond -3.11 -7.81 -4.70 -1.344 0.80322E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33644E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66039E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57723E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68258E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56964E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36652E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70705E+04 86 graphite -3.55 -7.81 -4.26 -1.218 0.72784E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38610E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60999E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24441E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64138E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59763E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15996E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22965E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58935E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28459E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74527E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48210E+04 112 manganosite 14.07 9.24 -4.83 -1.207 0.82451E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61273E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53658E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41163E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83602E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36597E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20047E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92748E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40671E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43418E+04 143 pyrrhotite -4.24 -8.03 -3.79 -1.264 0.64727E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.261 0.58555E+04 145 pyroxmangite 7.42 6.09 -1.32 -0.265 0.22620E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84877E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28320E+03 152 rhodonite 7.46 6.09 -1.37 -0.274 0.23413E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27388E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20974E+04 174 tephroite 18.11 15.33 -2.78 -0.398 0.47511E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91049E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76036E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65764E+04 181 troilite-low -4.39 -8.03 -3.64 -1.213 0.62159E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80355E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34504E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66765E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55581E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60351E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66126E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68738E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73632E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60307E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57940E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83189E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61767E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66252E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52971E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.54 -4.58 -1.525 0.78130E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62636E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18237E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11529E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14890E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18335E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 339.9990000 g New total amount of reactant added: 349.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3649E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 349.9990000 Water: Moles liquid = 0.5347E+02 kg liquid = 0.9632E+00 Moles total = 0.5112E+02 kg total = 0.9210E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173211E-01 Osmotic coef. = 0.9690 True ionic strength = .2068636E-01 Chg. balance for total moles = 0.3649E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90266E-10 -10.0445 0.75730E-10 -10.1207 0.83896E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14257E-03 -3.8460 0.11888E-03 -3.9249 0.83381E+00 -0.0789 4 SO4-- 0.81178E-12 -12.0906 0.41883E-12 -12.3780 0.51594E+00 -0.2874 5 HCO3- 0.29289E-06 -6.5333 0.24458E-06 -6.6116 0.83505E+00 -0.0783 6 HS- 0.26473E-04 -4.5772 0.22076E-04 -4.6561 0.83394E+00 -0.0789 7 Al+++ 0.11011E-28 -28.9582 0.25063E-29 -29.6010 0.22761E+00 -0.6428 8 H4SiO4 0.71145E-03 -3.1479 0.71145E-03 -3.1479 0.10000E+01 0.0000 9 Ca++ 0.14318E-06 -6.8441 0.73317E-07 -7.1348 0.51207E+00 -0.2907 10 Mg++ 0.22736E-10 -10.6433 0.11588E-10 -10.9360 0.50968E+00 -0.2927 11 Fe++ 0.62179E-13 -13.2064 0.31727E-13 -13.4986 0.51025E+00 -0.2922 12 K+ 0.16143E-03 -3.7920 0.13484E-03 -3.8702 0.83525E+00 -0.0782 13 Na+ 0.20524E-01 -1.6877 0.17110E-01 -1.7668 0.83365E+00 -0.0790 14 Mn++ 0.19491E-10 -10.7102 0.99537E-11 -11.0020 0.51068E+00 -0.2918 15 HPO4-- 0.48764E-07 -7.3119 0.25163E-07 -7.5992 0.51602E+00 -0.2873 16 HSiO3- 0.10993E-01 -1.9589 0.91660E-02 -2.0378 0.83381E+00 -0.0789 17 Ca(HSiO3)+ 0.18023E-07 -7.7442 0.15057E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35451E-11 -11.4504 0.29617E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24908E-02 -2.6037 0.24908E-02 -2.6037 0.10000E+01 0.0000 20 AlO+ 0.67529E-16 -16.1705 0.56416E-16 -16.2486 0.83544E+00 -0.0781 22 HAlO2,aq 0.14908E-09 -9.8266 0.14908E-09 -9.8266 0.10000E+01 0.0000 23 AlO2- 0.52812E-05 -5.2773 0.43954E-05 -5.3570 0.83228E+00 -0.0797 24 CH4,aq 0.12695E-04 -4.8964 0.12650E-04 -4.8979 0.99642E+00 -0.0016 25 C2H6,aq 0.25462E-14 -14.5941 0.25371E-14 -14.5957 0.99642E+00 -0.0016 29 CO,aq 0.10462E-16 -16.9804 0.10462E-16 -16.9804 0.10000E+01 0.0000 30 CO2,aq 0.37478E-10 -10.4262 0.37344E-10 -10.4278 0.99642E+00 -0.0016 31 CO3-2 0.58002E-06 -6.2366 0.29861E-06 -6.5249 0.51482E+00 -0.2883 32 CaCO3,aq 0.26814E-09 -9.5716 0.26814E-09 -9.5716 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.54083E-12 -12.2669 0.45183E-12 -12.3450 0.83544E+00 -0.0781 34 CaCl+ 0.16625E-10 -10.7792 0.13889E-10 -10.8573 0.83544E+00 -0.0781 35 CaCl2,aq 0.38444E-15 -15.4152 0.38444E-15 -15.4152 0.10000E+01 0.0000 36 CaOH+ 0.81713E-07 -7.0877 0.68266E-07 -7.1658 0.83544E+00 -0.0781 37 CaSO4,aq 0.95678E-17 -17.0192 0.95678E-17 -17.0192 0.10000E+01 0.0000 38 HCl,aq 0.16934E-14 -14.7712 0.16934E-14 -14.7712 0.10000E+01 0.0000 43 FeCl+ 0.70316E-17 -17.1529 0.58745E-17 -17.2310 0.83544E+00 -0.0781 46 FeO,aq 0.21876E-09 -9.6600 0.21876E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16625E-10 -10.7792 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37264E-07 -7.4287 0.31071E-07 -7.5076 0.83381E+00 -0.0789 49 FeO+ 0.12267E-16 -16.9113 0.10248E-16 -16.9894 0.83544E+00 -0.0781 51 FeO2- 0.42121E-09 -9.3755 0.35121E-09 -9.4544 0.83381E+00 -0.0789 52 HFeO2,aq 0.33286E-11 -11.4777 0.33286E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10916E-04 -4.9619 0.10877E-04 -4.9635 0.99642E+00 -0.0016 54 KCl,aq 0.28383E-09 -9.5469 0.28383E-09 -9.5469 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10435E-14 -14.9815 0.87006E-15 -15.0604 0.83381E+00 -0.0789 58 MgCO3,aq 0.10590E-13 -13.9751 0.10590E-13 -13.9751 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.87167E-16 -16.0597 0.72822E-16 -16.1377 0.83544E+00 -0.0781 60 MgCl+ 0.23854E-14 -14.6224 0.19928E-14 -14.7005 0.83544E+00 -0.0781 61 MgOH+ 0.71550E-10 -10.1454 0.59775E-10 -10.2235 0.83544E+00 -0.0781 63 MnO,aq 0.18321E-08 -8.7370 0.18321E-08 -8.7370 0.10000E+01 0.0000 64 MnOH+ 0.48452E-09 -9.3147 0.40479E-09 -9.3928 0.83544E+00 -0.0781 65 MnO2-2 0.21460E-10 -10.6684 0.11048E-10 -10.9567 0.51482E+00 -0.2883 66 HMnO2- 0.21741E-09 -9.6627 0.18128E-09 -9.7417 0.83381E+00 -0.0789 69 MnCl+ 0.85722E-14 -14.0669 0.71616E-14 -14.1450 0.83544E+00 -0.0781 71 NaCl,aq 0.66415E-06 -6.1777 0.66415E-06 -6.1777 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95168E-02 -2.0215 0.79207E-02 -2.1012 0.83228E+00 -0.0797 79 HPO3-2 0.16792E-14 -14.7749 0.86450E-15 -15.0632 0.51482E+00 -0.2883 81 H2PO3- 0.15423E-18 -18.8118 0.12860E-18 -18.8908 0.83381E+00 -0.0789 82 H3PO4,aq 0.92906E-18 -18.0320 0.92906E-18 -18.0320 0.10000E+01 0.0000 83 H2PO4- 0.40029E-10 -10.3976 0.33409E-10 -10.4761 0.83462E+00 -0.0785 84 PO4-3 0.12126E-08 -8.9163 0.29017E-09 -9.5373 0.23931E+00 -0.6210 88 HP2O7-3 0.10381E-17 -17.9838 0.23653E-18 -18.6261 0.22785E+00 -0.6423 89 P2O7-4 0.10255E-16 -16.9891 0.77052E-18 -18.1132 0.75138E-01 -1.1241 90 H2S,aq 0.50412E-08 -8.2975 0.50232E-08 -8.2990 0.99642E+00 -0.0016 91 S2-2 0.19141E-14 -14.7180 0.98545E-15 -15.0064 0.51482E+00 -0.2883 97 SO3-2 0.11890E-17 -17.9248 0.62117E-18 -18.2068 0.52242E+00 -0.2820 99 HSO4- 0.35192E-19 -19.4536 0.29430E-19 -19.5312 0.83627E+00 -0.0777 Charge balance for all species = 0.3786E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9026648E-10 -.2312517E-01 -.2326659E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981186E+06 0.0000 3 Cl- 0.1425740E-03 0.1432384E-03 0.5069039E+01 6.1958 4 SO4-- 0.8117813E-12 -.1542447E-04 -.1479017E+01 7.8635 5 HCO3- 0.2928900E-06 0.1356867E-04 0.8264235E+00 3.5091 6 HS- 0.2647252E-04 0.4190203E-04 0.1383275E+01 5.4647 7 Al+++ 0.1101127E-28 0.5281322E-05 0.1422400E+00 0.7612 8 H4SiO4 0.7114534E-03 0.1419513E-01 0.1361901E+04 -3.1479 9 Ca++ 0.1431779E-06 0.2431990E-06 0.9729284E-02 13.1067 10 Mg++ 0.2273571E-10 0.9784362E-10 0.2374468E-05 9.3055 11 Fe++ 0.6217912E-13 0.3792378E-07 0.2114096E-02 6.7429 12 K+ 0.1614327E-03 0.1622092E-03 0.6331222E+01 6.2505 13 Na+ 0.2052377E-01 0.2311451E-01 0.5304359E+03 8.3540 14 Mn++ 0.1949085E-10 0.2575033E-08 0.1412111E-03 9.2394 15 HPO4-- 0.4876355E-07 0.5001614E-07 0.4791809E-02 12.6422 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5795451E+01 -.2227528E-01 -.5773176E+01 0.0000000E+00 2 H2O 0.5112087E+02 0.5346455E+02 -.2343676E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9725170E-02 -.1485760E-04 0.9740027E-02 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9699665E-02 0.4036207E-04 -.9740027E-02 0.0000000E+00 7 Al+++ 0.1141256E+01 0.5087225E-05 0.1141251E+01 0.0000000E+00 8 H4SiO4 0.3644464E+01 0.1367344E-01 0.3630790E+01 0.0000000E+00 9 Ca++ 0.4025632E+00 0.2342610E-06 0.4025630E+00 0.0000000E+00 10 Mg++ 0.2777770E+00 0.9424772E-10 0.2777770E+00 0.0000000E+00 11 Fe++ 0.2495523E+00 0.3653003E-07 0.2495523E+00 0.0000000E+00 12 K+ 0.7430977E-01 0.1562478E-03 0.7415352E-01 0.0000000E+00 13 Na+ 0.4394941E+00 0.2226501E-01 0.4172291E+00 0.0000000E+00 14 Mn++ 0.6068491E-02 0.2480397E-08 0.6068489E-02 0.0000000E+00 15 HPO4-- 0.2071146E-02 0.4817797E-07 0.2071098E-02 0.0000000E+00 Chg. balance for solid moles: -.1370E-14 Mass of aqueous solution: 0.964995E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 349.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4168 -0.380 109.3 2.039 28.60 41.96 andradite 0.3896E-01 -1.409 19.80 1.297 5.180 5.144 grossular 0.9312E-02 -2.031 4.195 0.623 1.098 1.167 apatite-OH 0.6904E-03 -3.161 0.3468 -0.460 0.9074E-01 0.1102 clinochlore 0.5112E-01 -1.291 28.42 1.454 7.435 10.81 daphnite 0.1465E-01 -1.834 10.45 1.019 2.735 3.167 chlorite-Mn 0.1214E-02 -2.916 0.8605 -0.065 0.2251 0.2742 diopside 0.1075E-01 -1.968 2.329 0.367 0.6093 0.7117 hedenbergite 0.2754E-02 -2.560 0.6833 -0.165 0.1788 0.1872 microcline 0.6498E-01 -1.187 18.09 1.257 4.733 7.065 stilbite 0.2345 -0.630 165.2 2.218 43.24 77.08 stilpnomelane-Fe 0.1834E-01 -1.737 19.77 1.296 5.173 6.829 tr.625ac.25prg.125 0.3149E-02 -2.502 2.691 0.430 0.7042 0.8663 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8071E+00 0.8071E+00 1.0000 -0.093 grossular 0.1929E+00 0.1929E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7632E+00 0.7632E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1812E-01 0.1812E-01 1.0000 -1.742 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 382.180844 g Volume = 155.364683 cm3 Porosity: -10.1880% V(tot) - V(min): -.14365E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 349.9990000 g log = 2.5441 Original solution: 1000.0103000 g Original solution / Rock added: 2.86 (Water/Rock Ratio), log = 0.4559 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0871 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9681E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3904E-08 1.0071 0.4275E-08 0.4244E-08 CH4,gas 0.1817E-01 1.0128 0.2000E-01 0.1975E-01 H2,gas 0.1372E-01 1.0006 0.1492E-01 0.1491E-01 H2S,gas 0.1353E-06 0.9958 0.1465E-06 0.1471E-06 S2,gas 0.3322E-29 1.0000 0.3612E-29 0.3612E-29 CO,gas 0.1520E-13 1.0000 0.1652E-13 0.1652E-13 SO3,gas 0.8261E-48 1.0000 0.8980E-48 0.8980E-48 SO2,gas 0.4662E-27 1.0000 0.5068E-27 0.5068E-27 HCl,gas 0.2750E-17 1.0000 0.2990E-17 0.2990E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 -0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.73 -10.37 -3.456 0.17705E+05 -8.369 3 CH4,gas 4.81 1.11 -3.70 -0.925 0.63157E+04 -1.699 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65332E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.83 -4.417 0.15084E+05 -6.834 6 S2,gas -7.03 -38.47 -31.44 -4.837 0.53687E+05 -29.442 7 CO,gas 3.51 -12.27 -15.78 -4.856 0.26947E+05 -13.782 8 SO3,gas 17.43 -32.62 -50.05 -12.512 0.85453E+05 -48.047 9 SO2,gas 1.14 -28.16 -29.30 -7.812 0.50021E+05 -27.295 10 HCl,gas 5.48 -14.05 -19.52 -9.762 0.33337E+05 -17.524 11 acmite 7.74 6.57 -1.17 -0.121 0.19919E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.80 -4.75 -0.238 0.81151E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94107E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41192E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28378E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76226E+04 35 aragonite 0.99 -3.63 -4.61 -1.537 0.78746E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55854E+04 37 calcite 0.83 -3.63 -4.46 -1.486 0.76133E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52884E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71153E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70317E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82185E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47360E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39556E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68645E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70368E+04 52 chloritoid-Mn 11.46 7.61 -3.85 -0.257 0.65724E+04 54 coesite -2.37 -3.15 -0.78 -0.260 0.13293E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10222E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36452E+04 66 diamond -3.11 -7.81 -4.70 -1.344 0.80314E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33644E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66040E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57723E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68258E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56964E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36652E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70705E+04 86 graphite -3.55 -7.81 -4.26 -1.218 0.72776E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38610E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60999E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24441E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64139E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59764E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15996E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22965E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58935E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28459E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74527E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48210E+04 112 manganosite 14.07 9.24 -4.83 -1.207 0.82445E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61273E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53658E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41163E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83602E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36597E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20047E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92749E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40672E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43419E+04 143 pyrrhotite -4.24 -8.03 -3.79 -1.263 0.64719E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.261 0.58547E+04 145 pyroxmangite 7.42 6.09 -1.32 -0.265 0.22614E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84877E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28319E+03 152 rhodonite 7.46 6.09 -1.37 -0.274 0.23407E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27388E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20974E+04 174 tephroite 18.11 15.33 -2.78 -0.397 0.47500E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91048E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76036E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65763E+04 181 troilite-low -4.39 -8.03 -3.64 -1.213 0.62151E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80357E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34504E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66765E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55581E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60351E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66126E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68738E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73632E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60307E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57940E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83188E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61766E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66252E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52971E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.54 -4.57 -1.525 0.78116E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62637E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18237E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11529E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14890E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18335E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 349.9990000 g New total amount of reactant added: 359.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3649E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 359.9990000 Water: Moles liquid = 0.5341E+02 kg liquid = 0.9622E+00 Moles total = 0.5100E+02 kg total = 0.9187E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173227E-01 Osmotic coef. = 0.9690 True ionic strength = .2068651E-01 Chg. balance for total moles = 0.3649E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90267E-10 -10.0445 0.75731E-10 -10.1207 0.83896E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14272E-03 -3.8455 0.11900E-03 -3.9244 0.83381E+00 -0.0789 4 SO4-- 0.81269E-12 -12.0901 0.41930E-12 -12.3775 0.51594E+00 -0.2874 5 HCO3- 0.29322E-06 -6.5328 0.24485E-06 -6.6111 0.83505E+00 -0.0783 6 HS- 0.26500E-04 -4.5768 0.22099E-04 -4.6556 0.83394E+00 -0.0789 7 Al+++ 0.11011E-28 -28.9582 0.25063E-29 -29.6010 0.22761E+00 -0.6428 8 H4SiO4 0.71146E-03 -3.1478 0.71146E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14318E-06 -6.8441 0.73318E-07 -7.1348 0.51207E+00 -0.2907 10 Mg++ 0.22736E-10 -10.6433 0.11588E-10 -10.9360 0.50968E+00 -0.2927 11 Fe++ 0.62180E-13 -13.2064 0.31727E-13 -13.4986 0.51025E+00 -0.2922 12 K+ 0.16143E-03 -3.7920 0.13484E-03 -3.8702 0.83525E+00 -0.0782 13 Na+ 0.20524E-01 -1.6877 0.17110E-01 -1.7668 0.83365E+00 -0.0790 14 Mn++ 0.19505E-10 -10.7098 0.99610E-11 -11.0017 0.51068E+00 -0.2918 15 HPO4-- 0.48764E-07 -7.3119 0.25163E-07 -7.5992 0.51601E+00 -0.2873 16 HSiO3- 0.10993E-01 -1.9589 0.91660E-02 -2.0378 0.83381E+00 -0.0789 17 Ca(HSiO3)+ 0.18023E-07 -7.7442 0.15057E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35451E-11 -11.4504 0.29617E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24908E-02 -2.6037 0.24908E-02 -2.6037 0.10000E+01 0.0000 20 AlO+ 0.67528E-16 -16.1705 0.56415E-16 -16.2486 0.83544E+00 -0.0781 22 HAlO2,aq 0.14907E-09 -9.8266 0.14907E-09 -9.8266 0.10000E+01 0.0000 23 AlO2- 0.52810E-05 -5.2773 0.43953E-05 -5.3570 0.83228E+00 -0.0797 24 CH4,aq 0.12709E-04 -4.8959 0.12663E-04 -4.8975 0.99642E+00 -0.0016 25 C2H6,aq 0.25516E-14 -14.5932 0.25425E-14 -14.5947 0.99642E+00 -0.0016 29 CO,aq 0.10473E-16 -16.9799 0.10473E-16 -16.9799 0.10000E+01 0.0000 30 CO2,aq 0.37520E-10 -10.4257 0.37386E-10 -10.4273 0.99642E+00 -0.0016 31 CO3-2 0.58066E-06 -6.2361 0.29894E-06 -6.5244 0.51482E+00 -0.2883 32 CaCO3,aq 0.26844E-09 -9.5712 0.26844E-09 -9.5712 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.54144E-12 -12.2665 0.45233E-12 -12.3445 0.83544E+00 -0.0781 34 CaCl+ 0.16642E-10 -10.7788 0.13903E-10 -10.8569 0.83544E+00 -0.0781 35 CaCl2,aq 0.38524E-15 -15.4143 0.38524E-15 -15.4143 0.10000E+01 0.0000 36 CaOH+ 0.81713E-07 -7.0877 0.68266E-07 -7.1658 0.83544E+00 -0.0781 37 CaSO4,aq 0.95785E-17 -17.0187 0.95785E-17 -17.0187 0.10000E+01 0.0000 38 HCl,aq 0.16952E-14 -14.7708 0.16952E-14 -14.7708 0.10000E+01 0.0000 43 FeCl+ 0.70390E-17 -17.1525 0.58807E-17 -17.2306 0.83544E+00 -0.0781 46 FeO,aq 0.21876E-09 -9.6600 0.21876E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16625E-10 -10.7792 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37263E-07 -7.4287 0.31071E-07 -7.5076 0.83381E+00 -0.0789 49 FeO+ 0.12267E-16 -16.9113 0.10248E-16 -16.9893 0.83544E+00 -0.0781 51 FeO2- 0.42121E-09 -9.3755 0.35121E-09 -9.4544 0.83381E+00 -0.0789 52 HFeO2,aq 0.33286E-11 -11.4777 0.33286E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10916E-04 -4.9619 0.10877E-04 -4.9635 0.99642E+00 -0.0016 54 KCl,aq 0.28412E-09 -9.5465 0.28412E-09 -9.5465 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10446E-14 -14.9810 0.87104E-15 -15.0600 0.83381E+00 -0.0789 58 MgCO3,aq 0.10602E-13 -13.9746 0.10602E-13 -13.9746 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.87264E-16 -16.0592 0.72903E-16 -16.1373 0.83544E+00 -0.0781 60 MgCl+ 0.23879E-14 -14.6220 0.19949E-14 -14.7001 0.83544E+00 -0.0781 61 MgOH+ 0.71550E-10 -10.1454 0.59775E-10 -10.2235 0.83544E+00 -0.0781 63 MnO,aq 0.18335E-08 -8.7367 0.18335E-08 -8.7367 0.10000E+01 0.0000 64 MnOH+ 0.48488E-09 -9.3144 0.40508E-09 -9.3925 0.83544E+00 -0.0781 65 MnO2-2 0.21475E-10 -10.6681 0.11056E-10 -10.9564 0.51482E+00 -0.2883 66 HMnO2- 0.21756E-09 -9.6624 0.18141E-09 -9.7413 0.83381E+00 -0.0789 69 MnCl+ 0.85875E-14 -14.0661 0.71743E-14 -14.1442 0.83544E+00 -0.0781 71 NaCl,aq 0.66485E-06 -6.1773 0.66485E-06 -6.1773 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95167E-02 -2.0215 0.79206E-02 -2.1012 0.83228E+00 -0.0797 79 HPO3-2 0.16792E-14 -14.7749 0.86448E-15 -15.0632 0.51482E+00 -0.2883 81 H2PO3- 0.15423E-18 -18.8118 0.12860E-18 -18.8908 0.83381E+00 -0.0789 82 H3PO4,aq 0.92908E-18 -18.0319 0.92908E-18 -18.0319 0.10000E+01 0.0000 83 H2PO4- 0.40029E-10 -10.3976 0.33409E-10 -10.4761 0.83462E+00 -0.0785 84 PO4-3 0.12126E-08 -8.9163 0.29017E-09 -9.5373 0.23931E+00 -0.6210 88 HP2O7-3 0.10381E-17 -17.9838 0.23653E-18 -18.6261 0.22785E+00 -0.6424 89 P2O7-4 0.10255E-16 -16.9891 0.77052E-18 -18.1132 0.75137E-01 -1.1241 90 H2S,aq 0.50465E-08 -8.2970 0.50285E-08 -8.2986 0.99642E+00 -0.0016 91 S2-2 0.19182E-14 -14.7171 0.98753E-15 -15.0055 0.51482E+00 -0.2883 97 SO3-2 0.11903E-17 -17.9243 0.62185E-18 -18.2063 0.52242E+00 -0.2820 99 HSO4- 0.35232E-19 -19.4531 0.29463E-19 -19.5307 0.83627E+00 -0.0777 Charge balance for all species = 0.3789E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9026712E-10 -.2312515E-01 -.2326657E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981186E+06 0.0000 3 Cl- 0.1427228E-03 0.1433880E-03 0.5074331E+01 6.1963 4 SO4-- 0.8126884E-12 -.1543762E-04 -.1480277E+01 7.8640 5 HCO3- 0.2932157E-06 0.1358284E-04 0.8272863E+00 3.5096 6 HS- 0.2650016E-04 0.4194282E-04 0.1384622E+01 5.4651 7 Al+++ 0.1101126E-28 0.5281156E-05 0.1422356E+00 0.7612 8 H4SiO4 0.7114595E-03 0.1419519E-01 0.1361906E+04 -3.1478 9 Ca++ 0.1431788E-06 0.2432002E-06 0.9729334E-02 13.1067 10 Mg++ 0.2273584E-10 0.9784361E-10 0.2374468E-05 9.3055 11 Fe++ 0.6217985E-13 0.3792343E-07 0.2114076E-02 6.7429 12 K+ 0.1614338E-03 0.1622103E-03 0.6331266E+01 6.2505 13 Na+ 0.2052391E-01 0.2311467E-01 0.5304397E+03 8.3540 14 Mn++ 0.1950521E-10 0.2576894E-08 0.1413131E-03 9.2398 15 HPO4-- 0.4876370E-07 0.5001629E-07 0.4791823E-02 12.6422 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5961036E+01 -.2225204E-01 -.5938784E+01 0.0000000E+00 2 H2O 0.5099552E+02 0.5340878E+02 -.2413266E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1000230E-01 -.1485475E-04 0.1001716E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9976799E-02 0.4035922E-04 -.1001716E-01 0.0000000E+00 7 Al+++ 0.1173864E+01 0.5081759E-05 0.1173859E+01 0.0000000E+00 8 H4SiO4 0.3748591E+01 0.1365923E-01 0.3734932E+01 0.0000000E+00 9 Ca++ 0.4140647E+00 0.2340179E-06 0.4140644E+00 0.0000000E+00 10 Mg++ 0.2857135E+00 0.9414941E-10 0.2857135E+00 0.0000000E+00 11 Fe++ 0.2566824E+00 0.3649158E-07 0.2566823E+00 0.0000000E+00 12 K+ 0.7643291E-01 0.1560859E-03 0.7627682E-01 0.0000000E+00 13 Na+ 0.4520465E+00 0.2224195E-01 0.4298046E+00 0.0000000E+00 14 Mn++ 0.6241877E-02 0.2479600E-08 0.6241875E-02 0.0000000E+00 15 HPO4-- 0.2130322E-02 0.4812786E-07 0.2130274E-02 0.0000000E+00 Chg. balance for solid moles: 0.5673E-15 Mass of aqueous solution: 0.963989E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 359.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4294 -0.367 112.6 2.052 28.64 43.22 andradite 0.4007E-01 -1.397 20.36 1.309 5.180 5.290 grossular 0.9577E-02 -2.019 4.314 0.635 1.097 1.200 apatite-OH 0.7101E-03 -3.149 0.3567 -0.448 0.9074E-01 0.1133 clinochlore 0.5254E-01 -1.279 29.21 1.465 7.429 11.11 daphnite 0.1506E-01 -1.822 10.74 1.031 2.733 3.255 chlorite-Mn 0.1248E-02 -2.904 0.8851 -0.053 0.2251 0.2820 diopside 0.1133E-01 -1.946 2.454 0.390 0.6242 0.7500 hedenbergite 0.2902E-02 -2.537 0.7201 -0.143 0.1832 0.1972 microcline 0.6684E-01 -1.175 18.61 1.270 4.733 7.268 stilbite 0.2409 -0.618 169.8 2.230 43.19 79.19 stilpnomelane-Fe 0.1887E-01 -1.724 20.34 1.308 5.174 7.026 tr.625ac.25prg.125 0.3217E-02 -2.493 2.750 0.439 0.6995 0.8850 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8071E+00 0.8071E+00 1.0000 -0.093 grossular 0.1929E+00 0.1929E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7632E+00 0.7632E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1813E-01 0.1813E-01 1.0000 -1.742 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 393.106388 g Volume = 159.785318 cm3 Porosity: -10.1971% V(tot) - V(min): -.14786E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 359.9990000 g log = 2.5563 Original solution: 1000.0103000 g Original solution / Rock added: 2.78 (Water/Rock Ratio), log = 0.4437 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0871 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9681E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3909E-08 1.0071 0.4279E-08 0.4249E-08 CH4,gas 0.1819E-01 1.0128 0.2003E-01 0.1977E-01 H2,gas 0.1372E-01 1.0006 0.1492E-01 0.1491E-01 H2S,gas 0.1355E-06 0.9958 0.1467E-06 0.1473E-06 S2,gas 0.3330E-29 1.0000 0.3620E-29 0.3620E-29 CO,gas 0.1521E-13 1.0000 0.1654E-13 0.1654E-13 SO3,gas 0.8270E-48 1.0000 0.8990E-48 0.8990E-48 SO2,gas 0.4667E-27 1.0000 0.5074E-27 0.5074E-27 HCl,gas 0.2753E-17 1.0000 0.2993E-17 0.2993E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.84926E-10 47 daphnite 29.09 29.09 0.00 0.000 0.78860E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.84926E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.37914E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.73 -10.37 -3.456 0.17704E+05 -8.369 3 CH4,gas 4.81 1.11 -3.70 -0.925 0.63150E+04 -1.698 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65333E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.83 -4.417 0.15083E+05 -6.834 6 S2,gas -7.03 -38.47 -31.44 -4.837 0.53685E+05 -29.441 7 CO,gas 3.51 -12.27 -15.78 -4.856 0.26947E+05 -13.782 8 SO3,gas 17.43 -32.62 -50.05 -12.512 0.85453E+05 -48.046 9 SO2,gas 1.14 -28.16 -29.29 -7.812 0.50020E+05 -27.295 10 HCl,gas 5.48 -14.05 -19.52 -9.762 0.33336E+05 -17.524 11 acmite 7.74 6.57 -1.17 -0.121 0.19918E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.80 -4.75 -0.238 0.81135E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94107E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41192E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28378E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76226E+04 35 aragonite 0.99 -3.63 -4.61 -1.537 0.78738E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55854E+04 37 calcite 0.83 -3.63 -4.46 -1.486 0.76125E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52884E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71153E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70317E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82185E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47360E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39556E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68645E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70368E+04 52 chloritoid-Mn 11.46 7.61 -3.85 -0.257 0.65719E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13293E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10222E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36452E+04 66 diamond -3.11 -7.81 -4.70 -1.344 0.80306E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33644E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66040E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57723E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68258E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56964E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36652E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70705E+04 86 graphite -3.55 -7.81 -4.26 -1.218 0.72768E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38610E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60999E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24441E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64139E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59764E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15996E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22965E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58935E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28459E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74527E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48210E+04 112 manganosite 14.07 9.24 -4.83 -1.207 0.82440E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61274E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53658E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41163E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83602E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36597E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20048E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92749E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40673E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43420E+04 143 pyrrhotite -4.24 -8.03 -3.79 -1.263 0.64711E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.261 0.58540E+04 145 pyroxmangite 7.42 6.09 -1.32 -0.265 0.22609E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84878E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28319E+03 152 rhodonite 7.46 6.09 -1.37 -0.274 0.23401E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27388E+04 171 talc 16.55 15.32 -1.23 -0.072 0.20974E+04 174 tephroite 18.11 15.33 -2.78 -0.397 0.47489E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91048E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76035E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65763E+04 181 troilite-low -4.39 -8.03 -3.64 -1.213 0.62143E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80359E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34505E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66766E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55581E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60350E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66126E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68738E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73632E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60307E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57940E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83188E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61766E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66252E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52970E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.54 -4.57 -1.525 0.78103E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62637E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18237E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11529E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14891E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18335E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 359.9990000 g New total amount of reactant added: 369.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3649E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 369.9990000 Water: Moles liquid = 0.5336E+02 kg liquid = 0.9612E+00 Moles total = 0.5087E+02 kg total = 0.9164E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173242E-01 Osmotic coef. = 0.9690 True ionic strength = .2068665E-01 Chg. balance for total moles = 0.3649E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90268E-10 -10.0445 0.75731E-10 -10.1207 0.83896E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14287E-03 -3.8451 0.11913E-03 -3.9240 0.83381E+00 -0.0789 4 SO4-- 0.81359E-12 -12.0896 0.41976E-12 -12.3770 0.51594E+00 -0.2874 5 HCO3- 0.29354E-06 -6.5323 0.24512E-06 -6.6106 0.83505E+00 -0.0783 6 HS- 0.26528E-04 -4.5763 0.22123E-04 -4.6552 0.83394E+00 -0.0789 7 Al+++ 0.11011E-28 -28.9582 0.25063E-29 -29.6010 0.22761E+00 -0.6428 8 H4SiO4 0.71147E-03 -3.1478 0.71147E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14318E-06 -6.8441 0.73318E-07 -7.1348 0.51207E+00 -0.2907 10 Mg++ 0.22736E-10 -10.6433 0.11588E-10 -10.9360 0.50968E+00 -0.2927 11 Fe++ 0.62181E-13 -13.2063 0.31728E-13 -13.4986 0.51025E+00 -0.2922 12 K+ 0.16143E-03 -3.7920 0.13484E-03 -3.8702 0.83525E+00 -0.0782 13 Na+ 0.20524E-01 -1.6877 0.17110E-01 -1.7668 0.83365E+00 -0.0790 14 Mn++ 0.19519E-10 -10.7095 0.99679E-11 -11.0014 0.51068E+00 -0.2918 15 HPO4-- 0.48764E-07 -7.3119 0.25163E-07 -7.5992 0.51601E+00 -0.2873 16 HSiO3- 0.10993E-01 -1.9589 0.91660E-02 -2.0378 0.83381E+00 -0.0789 17 Ca(HSiO3)+ 0.18023E-07 -7.7442 0.15057E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35451E-11 -11.4504 0.29617E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24908E-02 -2.6037 0.24908E-02 -2.6037 0.10000E+01 0.0000 20 AlO+ 0.67527E-16 -16.1705 0.56414E-16 -16.2486 0.83544E+00 -0.0781 22 HAlO2,aq 0.14907E-09 -9.8266 0.14907E-09 -9.8266 0.10000E+01 0.0000 23 AlO2- 0.52808E-05 -5.2773 0.43952E-05 -5.3570 0.83228E+00 -0.0797 24 CH4,aq 0.12722E-04 -4.8954 0.12676E-04 -4.8970 0.99642E+00 -0.0016 25 C2H6,aq 0.25570E-14 -14.5923 0.25478E-14 -14.5938 0.99642E+00 -0.0016 29 CO,aq 0.10485E-16 -16.9794 0.10485E-16 -16.9794 0.10000E+01 0.0000 30 CO2,aq 0.37562E-10 -10.4253 0.37428E-10 -10.4268 0.99642E+00 -0.0016 31 CO3-2 0.58130E-06 -6.2356 0.29927E-06 -6.5239 0.51482E+00 -0.2883 32 CaCO3,aq 0.26873E-09 -9.5707 0.26873E-09 -9.5707 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.54204E-12 -12.2660 0.45284E-12 -12.3441 0.83544E+00 -0.0781 34 CaCl+ 0.16660E-10 -10.7783 0.13918E-10 -10.8564 0.83544E+00 -0.0781 35 CaCl2,aq 0.38605E-15 -15.4134 0.38605E-15 -15.4134 0.10000E+01 0.0000 36 CaOH+ 0.81713E-07 -7.0877 0.68266E-07 -7.1658 0.83544E+00 -0.0781 37 CaSO4,aq 0.95892E-17 -17.0182 0.95892E-17 -17.0182 0.10000E+01 0.0000 38 HCl,aq 0.16970E-14 -14.7703 0.16970E-14 -14.7703 0.10000E+01 0.0000 43 FeCl+ 0.70465E-17 -17.1520 0.58869E-17 -17.2301 0.83544E+00 -0.0781 46 FeO,aq 0.21876E-09 -9.6600 0.21876E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16625E-10 -10.7792 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37263E-07 -7.4287 0.31070E-07 -7.5077 0.83381E+00 -0.0789 49 FeO+ 0.12267E-16 -16.9113 0.10248E-16 -16.9893 0.83544E+00 -0.0781 51 FeO2- 0.42121E-09 -9.3755 0.35121E-09 -9.4544 0.83381E+00 -0.0789 52 HFeO2,aq 0.33287E-11 -11.4777 0.33287E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10916E-04 -4.9619 0.10877E-04 -4.9635 0.99642E+00 -0.0016 54 KCl,aq 0.28442E-09 -9.5460 0.28442E-09 -9.5460 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10458E-14 -14.9805 0.87201E-15 -15.0595 0.83381E+00 -0.0789 58 MgCO3,aq 0.10613E-13 -13.9741 0.10613E-13 -13.9741 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.87361E-16 -16.0587 0.72985E-16 -16.1368 0.83544E+00 -0.0781 60 MgCl+ 0.23904E-14 -14.6215 0.19970E-14 -14.6996 0.83544E+00 -0.0781 61 MgOH+ 0.71549E-10 -10.1454 0.59775E-10 -10.2235 0.83544E+00 -0.0781 63 MnO,aq 0.18347E-08 -8.7364 0.18347E-08 -8.7364 0.10000E+01 0.0000 64 MnOH+ 0.48521E-09 -9.3141 0.40536E-09 -9.3922 0.83544E+00 -0.0781 65 MnO2-2 0.21490E-10 -10.6678 0.11063E-10 -10.9561 0.51482E+00 -0.2883 66 HMnO2- 0.21771E-09 -9.6621 0.18153E-09 -9.7411 0.83381E+00 -0.0789 69 MnCl+ 0.86025E-14 -14.0654 0.71868E-14 -14.1435 0.83544E+00 -0.0781 71 NaCl,aq 0.66555E-06 -6.1768 0.66555E-06 -6.1768 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95167E-02 -2.0215 0.79206E-02 -2.1012 0.83228E+00 -0.0797 79 HPO3-2 0.16792E-14 -14.7749 0.86447E-15 -15.0633 0.51482E+00 -0.2883 81 H2PO3- 0.15423E-18 -18.8118 0.12860E-18 -18.8908 0.83381E+00 -0.0789 82 H3PO4,aq 0.92909E-18 -18.0319 0.92909E-18 -18.0319 0.10000E+01 0.0000 83 H2PO4- 0.40029E-10 -10.3976 0.33409E-10 -10.4761 0.83462E+00 -0.0785 84 PO4-3 0.12126E-08 -8.9163 0.29017E-09 -9.5373 0.23930E+00 -0.6210 88 HP2O7-3 0.10381E-17 -17.9838 0.23653E-18 -18.6261 0.22785E+00 -0.6424 89 P2O7-4 0.10255E-16 -16.9891 0.77052E-18 -18.1132 0.75137E-01 -1.1241 90 H2S,aq 0.50518E-08 -8.2966 0.50337E-08 -8.2981 0.99642E+00 -0.0016 91 S2-2 0.19222E-14 -14.7162 0.98961E-15 -15.0045 0.51482E+00 -0.2883 97 SO3-2 0.11916E-17 -17.9239 0.62253E-18 -18.2058 0.52242E+00 -0.2820 99 HSO4- 0.35271E-19 -19.4526 0.29496E-19 -19.5302 0.83627E+00 -0.0777 Charge balance for all species = 0.3794E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9026774E-10 -.2312514E-01 -.2326656E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981186E+06 0.0000 3 Cl- 0.1428720E-03 0.1435378E-03 0.5079635E+01 6.1967 4 SO4-- 0.8135941E-12 -.1545079E-04 -.1481541E+01 7.8645 5 HCO3- 0.2935410E-06 0.1359703E-04 0.8281510E+00 3.5101 6 HS- 0.2652786E-04 0.4198370E-04 0.1385972E+01 5.4656 7 Al+++ 0.1101125E-28 0.5280997E-05 0.1422313E+00 0.7612 8 H4SiO4 0.7114652E-03 0.1419523E-01 0.1361911E+04 -3.1478 9 Ca++ 0.1431797E-06 0.2432015E-06 0.9729386E-02 13.1067 10 Mg++ 0.2273598E-10 0.9784366E-10 0.2374469E-05 9.3055 11 Fe++ 0.6218057E-13 0.3792308E-07 0.2114056E-02 6.7429 12 K+ 0.1614349E-03 0.1622114E-03 0.6331310E+01 6.2505 13 Na+ 0.2052405E-01 0.2311483E-01 0.5304434E+03 8.3540 14 Mn++ 0.1951882E-10 0.2578656E-08 0.1414097E-03 9.2401 15 HPO4-- 0.4876382E-07 0.5001641E-07 0.4791835E-02 12.6422 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6126621E+01 -.2222879E-01 -.6104392E+01 0.0000000E+00 2 H2O 0.5087016E+02 0.5335302E+02 -.2482857E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1027944E-01 -.1485191E-04 0.1029429E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1025393E-01 0.4035638E-04 -.1029429E-01 0.0000000E+00 7 Al+++ 0.1206471E+01 0.5076301E-05 0.1206466E+01 0.0000000E+00 8 H4SiO4 0.3852719E+01 0.1364501E-01 0.3839074E+01 0.0000000E+00 9 Ca++ 0.4255661E+00 0.2337748E-06 0.4255659E+00 0.0000000E+00 10 Mg++ 0.2936500E+00 0.9405116E-10 0.2936500E+00 0.0000000E+00 11 Fe++ 0.2638125E+00 0.3645315E-07 0.2638124E+00 0.0000000E+00 12 K+ 0.7855605E-01 0.1559240E-03 0.7840013E-01 0.0000000E+00 13 Na+ 0.4645990E+00 0.2221888E-01 0.4423801E+00 0.0000000E+00 14 Mn++ 0.6415263E-02 0.2478705E-08 0.6415261E-02 0.0000000E+00 15 HPO4-- 0.2189497E-02 0.4807773E-07 0.2189449E-02 0.0000000E+00 Chg. balance for solid moles: 0.1559E-14 Mass of aqueous solution: 0.962982E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 369.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4420 -0.355 115.9 2.064 28.68 44.49 andradite 0.4118E-01 -1.385 20.93 1.321 5.179 5.437 grossular 0.9841E-02 -2.007 4.433 0.647 1.097 1.233 apatite-OH 0.7298E-03 -3.137 0.3666 -0.436 0.9074E-01 0.1165 clinochlore 0.5397E-01 -1.268 30.00 1.477 7.424 11.41 daphnite 0.1546E-01 -1.811 11.03 1.043 2.731 3.344 chlorite-Mn 0.1283E-02 -2.892 0.9096 -0.041 0.2251 0.2899 diopside 0.1191E-01 -1.924 2.579 0.411 0.6384 0.7883 hedenbergite 0.3051E-02 -2.516 0.7569 -0.121 0.1873 0.2073 microcline 0.6870E-01 -1.163 19.12 1.282 4.733 7.470 stilbite 0.2473 -0.607 174.3 2.241 43.14 81.30 stilpnomelane-Fe 0.1940E-01 -1.712 20.91 1.320 5.175 7.222 tr.625ac.25prg.125 0.3285E-02 -2.483 2.808 0.448 0.6950 0.9038 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8071E+00 0.8071E+00 1.0000 -0.093 grossular 0.1929E+00 0.1929E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7632E+00 0.7632E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1814E-01 0.1814E-01 1.0000 -1.741 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 404.031931 g Volume = 164.205954 cm3 Porosity: -10.2056% V(tot) - V(min): -.15206E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 369.9990000 g log = 2.5682 Original solution: 1000.0103000 g Original solution / Rock added: 2.70 (Water/Rock Ratio), log = 0.4318 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0871 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9681E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3913E-08 1.0071 0.4284E-08 0.4254E-08 CH4,gas 0.1821E-01 1.0128 0.2005E-01 0.1979E-01 H2,gas 0.1371E-01 1.0006 0.1492E-01 0.1491E-01 H2S,gas 0.1356E-06 0.9958 0.1468E-06 0.1474E-06 S2,gas 0.3337E-29 1.0000 0.3627E-29 0.3627E-29 CO,gas 0.1523E-13 1.0000 0.1656E-13 0.1656E-13 SO3,gas 0.8279E-48 1.0000 0.9000E-48 0.9000E-48 SO2,gas 0.4672E-27 1.0000 0.5079E-27 0.5079E-27 HCl,gas 0.2756E-17 1.0000 0.2996E-17 0.2996E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.60662E-10 47 daphnite 29.09 29.09 0.00 0.000 0.84926E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.73 -10.37 -3.456 0.17703E+05 -8.368 3 CH4,gas 4.81 1.11 -3.70 -0.924 0.63142E+04 -1.698 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65333E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.83 -4.417 0.15083E+05 -6.833 6 S2,gas -7.03 -38.47 -31.44 -4.837 0.53684E+05 -29.440 7 CO,gas 3.51 -12.27 -15.78 -4.856 0.26946E+05 -13.781 8 SO3,gas 17.43 -32.62 -50.05 -12.511 0.85452E+05 -48.046 9 SO2,gas 1.14 -28.16 -29.29 -7.812 0.50019E+05 -27.294 10 HCl,gas 5.48 -14.04 -19.52 -9.762 0.33336E+05 -17.523 11 acmite 7.74 6.57 -1.17 -0.121 0.19918E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.80 -4.75 -0.238 0.81120E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94108E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41192E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28378E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76227E+04 35 aragonite 0.99 -3.62 -4.61 -1.537 0.78730E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55854E+04 37 calcite 0.83 -3.62 -4.46 -1.486 0.76117E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52884E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71153E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70317E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82186E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47360E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39556E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68645E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70369E+04 52 chloritoid-Mn 11.46 7.61 -3.85 -0.257 0.65714E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13293E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10221E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36453E+04 66 diamond -3.11 -7.81 -4.70 -1.344 0.80298E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33645E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66041E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57723E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68258E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56964E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36652E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70705E+04 86 graphite -3.55 -7.81 -4.26 -1.218 0.72760E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38610E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60999E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24441E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64139E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59764E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15997E+04 102 lawsonite 9.68 8.33 -1.34 -0.090 0.22965E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58935E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28459E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74527E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48210E+04 112 manganosite 14.07 9.24 -4.83 -1.207 0.82435E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61274E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53659E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41164E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83602E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36597E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20048E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92750E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40673E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43421E+04 143 pyrrhotite -4.24 -8.03 -3.79 -1.263 0.64704E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.261 0.58532E+04 145 pyroxmangite 7.42 6.09 -1.32 -0.265 0.22604E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84878E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28318E+03 152 rhodonite 7.46 6.09 -1.37 -0.274 0.23396E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27389E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20974E+04 174 tephroite 18.11 15.33 -2.78 -0.397 0.47479E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91047E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76035E+03 180 ferroactinolite 38.60 34.74 -3.85 -0.104 0.65763E+04 181 troilite-low -4.39 -8.03 -3.64 -1.213 0.62136E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80362E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34505E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66766E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55581E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60350E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66126E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68738E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73632E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60307E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57940E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83188E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61766E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66252E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52970E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.54 -4.57 -1.524 0.78090E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62637E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18237E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11529E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14891E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18335E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 369.9990000 g New total amount of reactant added: 379.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3647E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 379.9990000 Water: Moles liquid = 0.5330E+02 kg liquid = 0.9602E+00 Moles total = 0.5074E+02 kg total = 0.9142E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173258E-01 Osmotic coef. = 0.9690 True ionic strength = .2068679E-01 Chg. balance for total moles = 0.3647E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90268E-10 -10.0445 0.75732E-10 -10.1207 0.83896E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14302E-03 -3.8446 0.11925E-03 -3.9235 0.83381E+00 -0.0789 4 SO4-- 0.81450E-12 -12.0891 0.42023E-12 -12.3765 0.51594E+00 -0.2874 5 HCO3- 0.29387E-06 -6.5319 0.24539E-06 -6.6101 0.83505E+00 -0.0783 6 HS- 0.26556E-04 -4.5758 0.22146E-04 -4.6547 0.83394E+00 -0.0789 7 Al+++ 0.11011E-28 -28.9582 0.25063E-29 -29.6010 0.22761E+00 -0.6428 8 H4SiO4 0.71147E-03 -3.1478 0.71147E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14318E-06 -6.8441 0.73318E-07 -7.1348 0.51207E+00 -0.2907 10 Mg++ 0.22736E-10 -10.6433 0.11588E-10 -10.9360 0.50968E+00 -0.2927 11 Fe++ 0.62181E-13 -13.2063 0.31728E-13 -13.4986 0.51025E+00 -0.2922 12 K+ 0.16144E-03 -3.7920 0.13484E-03 -3.8702 0.83525E+00 -0.0782 13 Na+ 0.20524E-01 -1.6877 0.17110E-01 -1.7667 0.83365E+00 -0.0790 14 Mn++ 0.19532E-10 -10.7093 0.99745E-11 -11.0011 0.51068E+00 -0.2919 15 HPO4-- 0.48764E-07 -7.3119 0.25163E-07 -7.5992 0.51601E+00 -0.2873 16 HSiO3- 0.10993E-01 -1.9589 0.91660E-02 -2.0378 0.83381E+00 -0.0789 17 Ca(HSiO3)+ 0.18023E-07 -7.7442 0.15057E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35451E-11 -11.4504 0.29617E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24909E-02 -2.6037 0.24909E-02 -2.6037 0.10000E+01 0.0000 20 AlO+ 0.67526E-16 -16.1705 0.56413E-16 -16.2486 0.83544E+00 -0.0781 22 HAlO2,aq 0.14906E-09 -9.8266 0.14906E-09 -9.8266 0.10000E+01 0.0000 23 AlO2- 0.52807E-05 -5.2773 0.43950E-05 -5.3570 0.83228E+00 -0.0797 24 CH4,aq 0.12735E-04 -4.8950 0.12690E-04 -4.8966 0.99642E+00 -0.0016 25 C2H6,aq 0.25623E-14 -14.5914 0.25532E-14 -14.5929 0.99642E+00 -0.0016 29 CO,aq 0.10496E-16 -16.9790 0.10496E-16 -16.9790 0.10000E+01 0.0000 30 CO2,aq 0.37604E-10 -10.4248 0.37469E-10 -10.4263 0.99642E+00 -0.0016 31 CO3-2 0.58194E-06 -6.2351 0.29960E-06 -6.5235 0.51482E+00 -0.2883 32 CaCO3,aq 0.26903E-09 -9.5702 0.26903E-09 -9.5702 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.54264E-12 -12.2655 0.45334E-12 -12.3436 0.83544E+00 -0.0781 34 CaCl+ 0.16677E-10 -10.7779 0.13933E-10 -10.8560 0.83544E+00 -0.0781 35 CaCl2,aq 0.38686E-15 -15.4124 0.38686E-15 -15.4124 0.10000E+01 0.0000 36 CaOH+ 0.81713E-07 -7.0877 0.68266E-07 -7.1658 0.83544E+00 -0.0781 37 CaSO4,aq 0.95999E-17 -17.0177 0.95999E-17 -17.0177 0.10000E+01 0.0000 38 HCl,aq 0.16987E-14 -14.7699 0.16987E-14 -14.7699 0.10000E+01 0.0000 43 FeCl+ 0.70539E-17 -17.1516 0.58931E-17 -17.2297 0.83544E+00 -0.0781 46 FeO,aq 0.21876E-09 -9.6600 0.21876E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16625E-10 -10.7792 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37263E-07 -7.4287 0.31070E-07 -7.5077 0.83381E+00 -0.0789 49 FeO+ 0.12267E-16 -16.9112 0.10249E-16 -16.9893 0.83544E+00 -0.0781 51 FeO2- 0.42121E-09 -9.3755 0.35121E-09 -9.4544 0.83381E+00 -0.0789 52 HFeO2,aq 0.33287E-11 -11.4777 0.33287E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10916E-04 -4.9619 0.10877E-04 -4.9635 0.99642E+00 -0.0016 54 KCl,aq 0.28472E-09 -9.5456 0.28472E-09 -9.5456 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10470E-14 -14.9801 0.87299E-15 -15.0590 0.83381E+00 -0.0789 58 MgCO3,aq 0.10625E-13 -13.9737 0.10625E-13 -13.9737 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.87458E-16 -16.0582 0.73066E-16 -16.1363 0.83544E+00 -0.0781 60 MgCl+ 0.23929E-14 -14.6211 0.19991E-14 -14.6992 0.83544E+00 -0.0781 61 MgOH+ 0.71549E-10 -10.1454 0.59775E-10 -10.2235 0.83544E+00 -0.0781 63 MnO,aq 0.18359E-08 -8.7361 0.18359E-08 -8.7361 0.10000E+01 0.0000 64 MnOH+ 0.48553E-09 -9.3138 0.40563E-09 -9.3919 0.83544E+00 -0.0781 65 MnO2-2 0.21503E-10 -10.6675 0.11070E-10 -10.9558 0.51482E+00 -0.2883 66 HMnO2- 0.21785E-09 -9.6618 0.18165E-09 -9.7408 0.83381E+00 -0.0789 69 MnCl+ 0.86171E-14 -14.0646 0.71991E-14 -14.1427 0.83544E+00 -0.0781 71 NaCl,aq 0.66625E-06 -6.1764 0.66625E-06 -6.1764 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95166E-02 -2.0215 0.79205E-02 -2.1012 0.83228E+00 -0.0797 79 HPO3-2 0.16791E-14 -14.7749 0.86445E-15 -15.0633 0.51482E+00 -0.2883 81 H2PO3- 0.15423E-18 -18.8118 0.12860E-18 -18.8908 0.83381E+00 -0.0789 82 H3PO4,aq 0.92910E-18 -18.0319 0.92910E-18 -18.0319 0.10000E+01 0.0000 83 H2PO4- 0.40030E-10 -10.3976 0.33409E-10 -10.4761 0.83462E+00 -0.0785 84 PO4-3 0.12126E-08 -8.9163 0.29017E-09 -9.5373 0.23930E+00 -0.6211 88 HP2O7-3 0.10381E-17 -17.9838 0.23654E-18 -18.6261 0.22785E+00 -0.6424 89 P2O7-4 0.10255E-16 -16.9891 0.77052E-18 -18.1132 0.75136E-01 -1.1241 90 H2S,aq 0.50571E-08 -8.2961 0.50390E-08 -8.2977 0.99642E+00 -0.0016 91 S2-2 0.19263E-14 -14.7153 0.99170E-15 -15.0036 0.51482E+00 -0.2883 97 SO3-2 0.11929E-17 -17.9234 0.62321E-18 -18.2054 0.52242E+00 -0.2820 99 HSO4- 0.35310E-19 -19.4521 0.29529E-19 -19.5298 0.83627E+00 -0.0777 Charge balance for all species = 0.3798E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9026836E-10 -.2312512E-01 -.2326654E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981186E+06 0.0000 3 Cl- 0.1430215E-03 0.1436880E-03 0.5084949E+01 6.1972 4 SO4-- 0.8144986E-12 -.1546401E-04 -.1482808E+01 7.8649 5 HCO3- 0.2938659E-06 0.1361126E-04 0.8290175E+00 3.5106 6 HS- 0.2655561E-04 0.4202468E-04 0.1387324E+01 5.4660 7 Al+++ 0.1101126E-28 0.5280845E-05 0.1422272E+00 0.7612 8 H4SiO4 0.7114706E-03 0.1419528E-01 0.1361915E+04 -3.1478 9 Ca++ 0.1431807E-06 0.2432029E-06 0.9729439E-02 13.1067 10 Mg++ 0.2273611E-10 0.9784371E-10 0.2374470E-05 9.3055 11 Fe++ 0.6218130E-13 0.3792274E-07 0.2114038E-02 6.7429 12 K+ 0.1614360E-03 0.1622125E-03 0.6331352E+01 6.2505 13 Na+ 0.2052419E-01 0.2311499E-01 0.5304471E+03 8.3540 14 Mn++ 0.1953175E-10 0.2580328E-08 0.1415014E-03 9.2403 15 HPO4-- 0.4876391E-07 0.5001650E-07 0.4791843E-02 12.6422 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6292206E+01 -.2220554E-01 -.6270001E+01 0.0000000E+00 2 H2O 0.5074481E+02 0.5329725E+02 -.2552447E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1055657E-01 -.1484907E-04 0.1057142E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1053107E-01 0.4035354E-04 -.1057142E-01 0.0000000E+00 7 Al+++ 0.1239079E+01 0.5070850E-05 0.1239073E+01 0.0000000E+00 8 H4SiO4 0.3956847E+01 0.1363079E-01 0.3943216E+01 0.0000000E+00 9 Ca++ 0.4370675E+00 0.2335318E-06 0.4370673E+00 0.0000000E+00 10 Mg++ 0.3015865E+00 0.9395290E-10 0.3015865E+00 0.0000000E+00 11 Fe++ 0.2709426E+00 0.3641472E-07 0.2709425E+00 0.0000000E+00 12 K+ 0.8067919E-01 0.1557621E-03 0.8052343E-01 0.0000000E+00 13 Na+ 0.4771514E+00 0.2219581E-01 0.4549556E+00 0.0000000E+00 14 Mn++ 0.6588649E-02 0.2477720E-08 0.6588647E-02 0.0000000E+00 15 HPO4-- 0.2248673E-02 0.4802756E-07 0.2248625E-02 0.0000000E+00 Chg. balance for solid moles: 0.3946E-15 Mass of aqueous solution: 0.961976E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 379.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4545 -0.342 119.2 2.076 28.72 45.75 andradite 0.4229E-01 -1.374 21.49 1.332 5.179 5.583 grossular 0.1011E-01 -1.995 4.552 0.658 1.097 1.267 apatite-OH 0.7495E-03 -3.125 0.3765 -0.424 0.9073E-01 0.1196 clinochlore 0.5539E-01 -1.257 30.79 1.488 7.419 11.71 daphnite 0.1587E-01 -1.799 11.32 1.054 2.729 3.432 chlorite-Mn 0.1318E-02 -2.880 0.9342 -0.030 0.2251 0.2977 diopside 0.1249E-01 -1.903 2.704 0.432 0.6517 0.8266 hedenbergite 0.3199E-02 -2.495 0.7936 -0.100 0.1913 0.2174 microcline 0.7056E-01 -1.151 19.64 1.293 4.733 7.672 stilbite 0.2538 -0.596 178.8 2.252 43.09 83.41 stilpnomelane-Fe 0.1992E-01 -1.701 21.48 1.332 5.176 7.419 tr.625ac.25prg.125 0.3353E-02 -2.475 2.866 0.457 0.6907 0.9225 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8071E+00 0.8071E+00 1.0000 -0.093 grossular 0.1929E+00 0.1929E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7632E+00 0.7632E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1816E-01 0.1816E-01 1.0000 -1.741 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 414.957476 g Volume = 168.626589 cm3 Porosity: -10.2137% V(tot) - V(min): -.15627E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 379.9990000 g log = 2.5798 Original solution: 1000.0103000 g Original solution / Rock added: 2.63 (Water/Rock Ratio), log = 0.4202 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0872 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9681E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3917E-08 1.0071 0.4289E-08 0.4259E-08 CH4,gas 0.1822E-01 1.0128 0.2007E-01 0.1981E-01 H2,gas 0.1371E-01 1.0006 0.1492E-01 0.1491E-01 H2S,gas 0.1358E-06 0.9958 0.1470E-06 0.1476E-06 S2,gas 0.3344E-29 1.0000 0.3635E-29 0.3635E-29 CO,gas 0.1525E-13 1.0000 0.1657E-13 0.1657E-13 SO3,gas 0.8288E-48 1.0000 0.9010E-48 0.9010E-48 SO2,gas 0.4677E-27 1.0000 0.5085E-27 0.5085E-27 HCl,gas 0.2759E-17 1.0000 0.2999E-17 0.2999E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.73 -10.37 -3.456 0.17702E+05 -8.368 3 CH4,gas 4.81 1.11 -3.70 -0.924 0.63134E+04 -1.698 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65333E+04 -1.826 5 H2S,gas -5.94 -14.78 -8.83 -4.416 0.15082E+05 -6.833 6 S2,gas -7.03 -38.47 -31.44 -4.837 0.53682E+05 -29.439 7 CO,gas 3.51 -12.27 -15.78 -4.856 0.26945E+05 -13.781 8 SO3,gas 17.43 -32.62 -50.05 -12.511 0.85451E+05 -48.045 9 SO2,gas 1.14 -28.16 -29.29 -7.812 0.50018E+05 -27.294 10 HCl,gas 5.48 -14.04 -19.52 -9.761 0.33335E+05 -17.523 11 acmite 7.74 6.57 -1.17 -0.121 0.19918E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.80 -4.75 -0.238 0.81106E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94108E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41192E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28378E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76227E+04 35 aragonite 0.99 -3.62 -4.61 -1.537 0.78722E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55854E+04 37 calcite 0.83 -3.62 -4.46 -1.486 0.76108E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52884E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71153E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70317E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82186E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47360E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39556E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68645E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70369E+04 52 chloritoid-Mn 11.46 7.61 -3.85 -0.257 0.65709E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13293E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10221E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36453E+04 66 diamond -3.11 -7.81 -4.70 -1.344 0.80290E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33645E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66041E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57723E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68258E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56965E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36652E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70705E+04 86 graphite -3.55 -7.81 -4.26 -1.217 0.72752E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38610E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60999E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24441E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64139E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59764E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15997E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22966E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58935E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28459E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74527E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48209E+04 112 manganosite 14.07 9.24 -4.83 -1.207 0.82430E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61274E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53659E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41164E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83602E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36597E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20048E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92751E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40674E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43422E+04 143 pyrrhotite -4.24 -8.03 -3.79 -1.263 0.64696E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.261 0.58524E+04 145 pyroxmangite 7.42 6.09 -1.32 -0.265 0.22599E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84878E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28317E+03 152 rhodonite 7.46 6.09 -1.37 -0.274 0.23391E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27389E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20974E+04 174 tephroite 18.11 15.33 -2.78 -0.397 0.47469E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91047E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76035E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65763E+04 181 troilite-low -4.39 -8.03 -3.64 -1.213 0.62128E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80364E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34505E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66767E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55581E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60349E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66126E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68738E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73632E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60307E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57939E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83188E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61766E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66251E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52970E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.54 -4.57 -1.524 0.78078E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62637E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18237E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11529E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14891E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18335E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 379.9990000 g New total amount of reactant added: 389.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3648E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 389.9990000 Water: Moles liquid = 0.5325E+02 kg liquid = 0.9592E+00 Moles total = 0.5062E+02 kg total = 0.9119E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173273E-01 Osmotic coef. = 0.9690 True ionic strength = .2068693E-01 Chg. balance for total moles = 0.3648E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90269E-10 -10.0445 0.75732E-10 -10.1207 0.83896E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14317E-03 -3.8441 0.11938E-03 -3.9231 0.83381E+00 -0.0789 4 SO4-- 0.81540E-12 -12.0886 0.42070E-12 -12.3760 0.51594E+00 -0.2874 5 HCO3- 0.29419E-06 -6.5314 0.24566E-06 -6.6097 0.83505E+00 -0.0783 6 HS- 0.26583E-04 -4.5754 0.22169E-04 -4.6543 0.83393E+00 -0.0789 7 Al+++ 0.11011E-28 -28.9582 0.25062E-29 -29.6010 0.22761E+00 -0.6428 8 H4SiO4 0.71148E-03 -3.1478 0.71148E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14318E-06 -6.8441 0.73319E-07 -7.1348 0.51207E+00 -0.2907 10 Mg++ 0.22736E-10 -10.6433 0.11588E-10 -10.9360 0.50968E+00 -0.2927 11 Fe++ 0.62182E-13 -13.2063 0.31728E-13 -13.4986 0.51025E+00 -0.2922 12 K+ 0.16144E-03 -3.7920 0.13484E-03 -3.8702 0.83525E+00 -0.0782 13 Na+ 0.20524E-01 -1.6877 0.17110E-01 -1.7667 0.83365E+00 -0.0790 14 Mn++ 0.19544E-10 -10.7090 0.99807E-11 -11.0008 0.51068E+00 -0.2919 15 HPO4-- 0.48764E-07 -7.3119 0.25163E-07 -7.5992 0.51601E+00 -0.2873 16 HSiO3- 0.10993E-01 -1.9589 0.91660E-02 -2.0378 0.83381E+00 -0.0789 17 Ca(HSiO3)+ 0.18023E-07 -7.7442 0.15057E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35451E-11 -11.4504 0.29617E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24909E-02 -2.6036 0.24909E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67525E-16 -16.1705 0.56413E-16 -16.2486 0.83544E+00 -0.0781 22 HAlO2,aq 0.14906E-09 -9.8266 0.14906E-09 -9.8266 0.10000E+01 0.0000 23 AlO2- 0.52806E-05 -5.2773 0.43949E-05 -5.3571 0.83228E+00 -0.0797 24 CH4,aq 0.12748E-04 -4.8945 0.12703E-04 -4.8961 0.99642E+00 -0.0016 25 C2H6,aq 0.25677E-14 -14.5905 0.25585E-14 -14.5920 0.99642E+00 -0.0016 29 CO,aq 0.10508E-16 -16.9785 0.10508E-16 -16.9785 0.10000E+01 0.0000 30 CO2,aq 0.37645E-10 -10.4243 0.37511E-10 -10.4258 0.99642E+00 -0.0016 31 CO3-2 0.58258E-06 -6.2346 0.29993E-06 -6.5230 0.51482E+00 -0.2883 32 CaCO3,aq 0.26933E-09 -9.5697 0.26933E-09 -9.5697 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.54324E-12 -12.2650 0.45385E-12 -12.3431 0.83544E+00 -0.0781 34 CaCl+ 0.16695E-10 -10.7774 0.13947E-10 -10.8555 0.83544E+00 -0.0781 35 CaCl2,aq 0.38767E-15 -15.4115 0.38767E-15 -15.4115 0.10000E+01 0.0000 36 CaOH+ 0.81713E-07 -7.0877 0.68266E-07 -7.1658 0.83544E+00 -0.0781 37 CaSO4,aq 0.96106E-17 -17.0173 0.96106E-17 -17.0173 0.10000E+01 0.0000 38 HCl,aq 0.17005E-14 -14.7694 0.17005E-14 -14.7694 0.10000E+01 0.0000 43 FeCl+ 0.70614E-17 -17.1511 0.58993E-17 -17.2292 0.83544E+00 -0.0781 46 FeO,aq 0.21876E-09 -9.6600 0.21876E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16625E-10 -10.7792 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37262E-07 -7.4287 0.31070E-07 -7.5077 0.83381E+00 -0.0789 49 FeO+ 0.12268E-16 -16.9112 0.10249E-16 -16.9893 0.83544E+00 -0.0781 51 FeO2- 0.42121E-09 -9.3755 0.35121E-09 -9.4544 0.83381E+00 -0.0789 52 HFeO2,aq 0.33287E-11 -11.4777 0.33287E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10915E-04 -4.9620 0.10876E-04 -4.9635 0.99642E+00 -0.0016 54 KCl,aq 0.28502E-09 -9.5451 0.28502E-09 -9.5451 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10482E-14 -14.9796 0.87396E-15 -15.0585 0.83381E+00 -0.0789 58 MgCO3,aq 0.10637E-13 -13.9732 0.10637E-13 -13.9732 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.87555E-16 -16.0577 0.73147E-16 -16.1358 0.83544E+00 -0.0781 60 MgCl+ 0.23954E-14 -14.6206 0.20012E-14 -14.6987 0.83544E+00 -0.0781 61 MgOH+ 0.71549E-10 -10.1454 0.59775E-10 -10.2235 0.83544E+00 -0.0781 63 MnO,aq 0.18370E-08 -8.7359 0.18370E-08 -8.7359 0.10000E+01 0.0000 64 MnOH+ 0.48583E-09 -9.3135 0.40588E-09 -9.3916 0.83544E+00 -0.0781 65 MnO2-2 0.21516E-10 -10.6672 0.11077E-10 -10.9556 0.51482E+00 -0.2883 66 HMnO2- 0.21798E-09 -9.6616 0.18176E-09 -9.7405 0.83381E+00 -0.0789 69 MnCl+ 0.86316E-14 -14.0639 0.72111E-14 -14.1420 0.83544E+00 -0.0781 71 NaCl,aq 0.66695E-06 -6.1759 0.66695E-06 -6.1759 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95166E-02 -2.0215 0.79205E-02 -2.1012 0.83228E+00 -0.0797 79 HPO3-2 0.16791E-14 -14.7749 0.86444E-15 -15.0633 0.51482E+00 -0.2883 81 H2PO3- 0.15423E-18 -18.8118 0.12860E-18 -18.8908 0.83381E+00 -0.0789 82 H3PO4,aq 0.92911E-18 -18.0319 0.92911E-18 -18.0319 0.10000E+01 0.0000 83 H2PO4- 0.40030E-10 -10.3976 0.33410E-10 -10.4761 0.83462E+00 -0.0785 84 PO4-3 0.12126E-08 -8.9163 0.29017E-09 -9.5374 0.23930E+00 -0.6211 88 HP2O7-3 0.10381E-17 -17.9837 0.23654E-18 -18.6261 0.22785E+00 -0.6424 89 P2O7-4 0.10255E-16 -16.9891 0.77052E-18 -18.1132 0.75136E-01 -1.1242 90 H2S,aq 0.50625E-08 -8.2956 0.50443E-08 -8.2972 0.99642E+00 -0.0016 91 S2-2 0.19304E-14 -14.7144 0.99379E-15 -15.0027 0.51482E+00 -0.2883 97 SO3-2 0.11942E-17 -17.9229 0.62389E-18 -18.2049 0.52242E+00 -0.2820 99 HSO4- 0.35350E-19 -19.4516 0.29562E-19 -19.5293 0.83627E+00 -0.0777 Charge balance for all species = 0.3802E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9026897E-10 -.2312510E-01 -.2326651E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981186E+06 0.0000 3 Cl- 0.1431713E-03 0.1438385E-03 0.5090275E+01 6.1976 4 SO4-- 0.8154023E-12 -.1547725E-04 -.1484078E+01 7.8654 5 HCO3- 0.2941906E-06 0.1362552E-04 0.8298857E+00 3.5111 6 HS- 0.2658343E-04 0.4206574E-04 0.1388680E+01 5.4665 7 Al+++ 0.1101127E-28 0.5280700E-05 0.1422233E+00 0.7612 8 H4SiO4 0.7114757E-03 0.1419531E-01 0.1361918E+04 -3.1478 9 Ca++ 0.1431817E-06 0.2432042E-06 0.9729495E-02 13.1067 10 Mg++ 0.2273626E-10 0.9784382E-10 0.2374473E-05 9.3055 11 Fe++ 0.6218201E-13 0.3792242E-07 0.2114019E-02 6.7429 12 K+ 0.1614371E-03 0.1622136E-03 0.6331394E+01 6.2505 13 Na+ 0.2052433E-01 0.2311515E-01 0.5304506E+03 8.3540 14 Mn++ 0.1954404E-10 0.2581916E-08 0.1415885E-03 9.2406 15 HPO4-- 0.4876398E-07 0.5001657E-07 0.4791850E-02 12.6422 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6457791E+01 -.2218228E-01 -.6435609E+01 0.0000000E+00 2 H2O 0.5061945E+02 0.5324149E+02 -.2622037E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1083371E-01 -.1484624E-04 0.1084855E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1080820E-01 0.4035071E-04 -.1084855E-01 0.0000000E+00 7 Al+++ 0.1271686E+01 0.5065405E-05 0.1271681E+01 0.0000000E+00 8 H4SiO4 0.4060975E+01 0.1361657E-01 0.4047358E+01 0.0000000E+00 9 Ca++ 0.4485690E+00 0.2332888E-06 0.4485687E+00 0.0000000E+00 10 Mg++ 0.3095230E+00 0.9385470E-10 0.3095230E+00 0.0000000E+00 11 Fe++ 0.2780726E+00 0.3637631E-07 0.2780726E+00 0.0000000E+00 12 K+ 0.8280234E-01 0.1556001E-03 0.8264674E-01 0.0000000E+00 13 Na+ 0.4897038E+00 0.2217274E-01 0.4675311E+00 0.0000000E+00 14 Mn++ 0.6762035E-02 0.2476651E-08 0.6762033E-02 0.0000000E+00 15 HPO4-- 0.2307849E-02 0.4797738E-07 0.2307801E-02 0.0000000E+00 Chg. balance for solid moles: 0.6167E-15 Mass of aqueous solution: 0.960969E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 389.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4671 -0.331 122.5 2.088 28.76 47.02 andradite 0.4339E-01 -1.363 22.05 1.343 5.178 5.729 grossular 0.1037E-01 -1.984 4.671 0.669 1.097 1.300 apatite-OH 0.7693E-03 -3.114 0.3864 -0.413 0.9073E-01 0.1228 clinochlore 0.5681E-01 -1.246 31.58 1.499 7.415 12.01 daphnite 0.1628E-01 -1.788 11.62 1.065 2.727 3.520 chlorite-Mn 0.1352E-02 -2.869 0.9588 -0.018 0.2251 0.3055 diopside 0.1307E-01 -1.884 2.830 0.452 0.6644 0.8648 hedenbergite 0.3347E-02 -2.475 0.8304 -0.081 0.1950 0.2274 microcline 0.7242E-01 -1.140 20.16 1.304 4.733 7.874 stilbite 0.2602 -0.585 183.3 2.263 43.05 85.52 stilpnomelane-Fe 0.2045E-01 -1.689 22.05 1.343 5.177 7.616 tr.625ac.25prg.125 0.3421E-02 -2.466 2.924 0.466 0.6867 0.9412 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8071E+00 0.8071E+00 1.0000 -0.093 grossular 0.1929E+00 0.1929E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7632E+00 0.7632E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1817E-01 0.1817E-01 1.0000 -1.741 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 425.883020 g Volume = 173.047225 cm3 Porosity: -10.2214% V(tot) - V(min): -.16048E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 389.9990000 g log = 2.5911 Original solution: 1000.0103000 g Original solution / Rock added: 2.56 (Water/Rock Ratio), log = 0.4089 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0872 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9680E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3921E-08 1.0071 0.4294E-08 0.4263E-08 CH4,gas 0.1824E-01 1.0128 0.2009E-01 0.1983E-01 H2,gas 0.1371E-01 1.0006 0.1492E-01 0.1491E-01 H2S,gas 0.1359E-06 0.9958 0.1471E-06 0.1477E-06 S2,gas 0.3351E-29 1.0000 0.3643E-29 0.3643E-29 CO,gas 0.1526E-13 1.0000 0.1659E-13 0.1659E-13 SO3,gas 0.8297E-48 1.0000 0.9021E-48 0.9021E-48 SO2,gas 0.4682E-27 1.0000 0.5091E-27 0.5091E-27 HCl,gas 0.2762E-17 1.0000 0.3003E-17 0.3003E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.18198E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 -0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.73 -10.37 -3.456 0.17702E+05 -8.367 3 CH4,gas 4.81 1.11 -3.70 -0.924 0.63126E+04 -1.697 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65333E+04 -1.826 5 H2S,gas -5.94 -14.77 -8.83 -4.416 0.15081E+05 -6.832 6 S2,gas -7.03 -38.47 -31.44 -4.837 0.53680E+05 -29.439 7 CO,gas 3.51 -12.27 -15.78 -4.855 0.26944E+05 -13.780 8 SO3,gas 17.43 -32.62 -50.04 -12.511 0.85450E+05 -48.045 9 SO2,gas 1.14 -28.16 -29.29 -7.812 0.50017E+05 -27.293 10 HCl,gas 5.48 -14.04 -19.52 -9.761 0.33334E+05 -17.522 11 acmite 7.74 6.57 -1.17 -0.121 0.19918E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.80 -4.75 -0.237 0.81092E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94109E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41192E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28379E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76227E+04 35 aragonite 0.99 -3.62 -4.61 -1.537 0.78714E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55854E+04 37 calcite 0.83 -3.62 -4.46 -1.486 0.76100E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52884E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71153E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70318E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82186E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47360E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39556E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68646E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70369E+04 52 chloritoid-Mn 11.46 7.62 -3.85 -0.257 0.65705E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13293E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10221E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36453E+04 66 diamond -3.11 -7.81 -4.70 -1.343 0.80282E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33645E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66042E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57723E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68258E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56965E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36652E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70705E+04 86 graphite -3.55 -7.81 -4.26 -1.217 0.72744E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38610E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60999E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24441E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64139E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59764E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15997E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22966E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58935E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28459E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74527E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48209E+04 112 manganosite 14.07 9.24 -4.83 -1.207 0.82426E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61275E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53659E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41164E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83602E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36598E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20049E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92752E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40675E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43423E+04 143 pyrrhotite -4.24 -8.03 -3.79 -1.263 0.64688E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.260 0.58516E+04 145 pyroxmangite 7.42 6.09 -1.32 -0.265 0.22594E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84878E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28317E+03 152 rhodonite 7.46 6.09 -1.37 -0.274 0.23387E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27389E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20974E+04 174 tephroite 18.11 15.33 -2.78 -0.397 0.47460E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91046E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76035E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65763E+04 181 troilite-low -4.39 -8.03 -3.64 -1.213 0.62120E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80366E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34505E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66767E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55581E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60348E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66126E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68738E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73632E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60307E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57939E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83187E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61765E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66251E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52970E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.53 -4.57 -1.524 0.78065E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62637E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18237E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11529E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14891E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18336E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 389.9990000 g New total amount of reactant added: 399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3648E-11 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 399.9990000 Water: Moles liquid = 0.5319E+02 kg liquid = 0.9582E+00 Moles total = 0.5049E+02 kg total = 0.9097E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173289E-01 Osmotic coef. = 0.9690 True ionic strength = .2068707E-01 Chg. balance for total moles = 0.3648E-11 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90270E-10 -10.0445 0.75733E-10 -10.1207 0.83896E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14332E-03 -3.8437 0.11950E-03 -3.9226 0.83381E+00 -0.0789 4 SO4-- 0.81631E-12 -12.0881 0.42116E-12 -12.3756 0.51594E+00 -0.2874 5 HCO3- 0.29452E-06 -6.5309 0.24594E-06 -6.6092 0.83505E+00 -0.0783 6 HS- 0.26611E-04 -4.5749 0.22192E-04 -4.6538 0.83393E+00 -0.0789 7 Al+++ 0.11011E-28 -28.9582 0.25062E-29 -29.6010 0.22761E+00 -0.6428 8 H4SiO4 0.71148E-03 -3.1478 0.71148E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14318E-06 -6.8441 0.73319E-07 -7.1348 0.51207E+00 -0.2907 10 Mg++ 0.22736E-10 -10.6433 0.11588E-10 -10.9360 0.50968E+00 -0.2927 11 Fe++ 0.62183E-13 -13.2063 0.31729E-13 -13.4985 0.51025E+00 -0.2922 12 K+ 0.16144E-03 -3.7920 0.13484E-03 -3.8702 0.83525E+00 -0.0782 13 Na+ 0.20524E-01 -1.6877 0.17110E-01 -1.7667 0.83365E+00 -0.0790 14 Mn++ 0.19556E-10 -10.7087 0.99867E-11 -11.0006 0.51068E+00 -0.2919 15 HPO4-- 0.48764E-07 -7.3119 0.25163E-07 -7.5992 0.51601E+00 -0.2873 16 HSiO3- 0.10993E-01 -1.9589 0.91660E-02 -2.0378 0.83381E+00 -0.0789 17 Ca(HSiO3)+ 0.18023E-07 -7.7442 0.15057E-07 -7.8223 0.83544E+00 -0.0781 18 Mg(HSiO3)+ 0.35452E-11 -11.4504 0.29618E-11 -11.5285 0.83544E+00 -0.0781 19 NaHSiO3,aq 0.24909E-02 -2.6036 0.24909E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67524E-16 -16.1705 0.56412E-16 -16.2486 0.83544E+00 -0.0781 22 HAlO2,aq 0.14906E-09 -9.8266 0.14906E-09 -9.8266 0.10000E+01 0.0000 23 AlO2- 0.52804E-05 -5.2773 0.43948E-05 -5.3571 0.83228E+00 -0.0797 24 CH4,aq 0.12762E-04 -4.8941 0.12716E-04 -4.8956 0.99642E+00 -0.0016 25 C2H6,aq 0.25731E-14 -14.5895 0.25639E-14 -14.5911 0.99642E+00 -0.0016 29 CO,aq 0.10519E-16 -16.9780 0.10519E-16 -16.9780 0.10000E+01 0.0000 30 CO2,aq 0.37687E-10 -10.4238 0.37552E-10 -10.4254 0.99642E+00 -0.0016 31 CO3-2 0.58322E-06 -6.2342 0.30025E-06 -6.5225 0.51482E+00 -0.2883 32 CaCO3,aq 0.26962E-09 -9.5692 0.26962E-09 -9.5692 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.54385E-12 -12.2645 0.45435E-12 -12.3426 0.83544E+00 -0.0781 34 CaCl+ 0.16712E-10 -10.7770 0.13962E-10 -10.8551 0.83544E+00 -0.0781 35 CaCl2,aq 0.38849E-15 -15.4106 0.38849E-15 -15.4106 0.10000E+01 0.0000 36 CaOH+ 0.81713E-07 -7.0877 0.68266E-07 -7.1658 0.83544E+00 -0.0781 37 CaSO4,aq 0.96213E-17 -17.0168 0.96213E-17 -17.0168 0.10000E+01 0.0000 38 HCl,aq 0.17023E-14 -14.7690 0.17023E-14 -14.7690 0.10000E+01 0.0000 43 FeCl+ 0.70688E-17 -17.1507 0.59055E-17 -17.2287 0.83544E+00 -0.0781 46 FeO,aq 0.21876E-09 -9.6600 0.21876E-09 -9.6600 0.10000E+01 0.0000 47 FeOH+ 0.16625E-10 -10.7792 0.13889E-10 -10.8573 0.83544E+00 -0.0781 48 HFeO2- 0.37262E-07 -7.4287 0.31070E-07 -7.5077 0.83381E+00 -0.0789 49 FeO+ 0.12268E-16 -16.9112 0.10249E-16 -16.9893 0.83544E+00 -0.0781 51 FeO2- 0.42121E-09 -9.3755 0.35121E-09 -9.4544 0.83381E+00 -0.0789 52 HFeO2,aq 0.33287E-11 -11.4777 0.33287E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10915E-04 -4.9620 0.10876E-04 -4.9635 0.99642E+00 -0.0016 54 KCl,aq 0.28532E-09 -9.5447 0.28532E-09 -9.5447 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10493E-14 -14.9791 0.87493E-15 -15.0580 0.83381E+00 -0.0789 58 MgCO3,aq 0.10649E-13 -13.9727 0.10649E-13 -13.9727 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.87652E-16 -16.0572 0.73228E-16 -16.1353 0.83544E+00 -0.0781 60 MgCl+ 0.23979E-14 -14.6202 0.20033E-14 -14.6983 0.83544E+00 -0.0781 61 MgOH+ 0.71549E-10 -10.1454 0.59775E-10 -10.2235 0.83544E+00 -0.0781 63 MnO,aq 0.18381E-08 -8.7356 0.18381E-08 -8.7356 0.10000E+01 0.0000 64 MnOH+ 0.48612E-09 -9.3133 0.40612E-09 -9.3913 0.83544E+00 -0.0781 65 MnO2-2 0.21529E-10 -10.6670 0.11083E-10 -10.9553 0.51482E+00 -0.2883 66 HMnO2- 0.21811E-09 -9.6613 0.18186E-09 -9.7403 0.83381E+00 -0.0789 69 MnCl+ 0.86458E-14 -14.0632 0.72230E-14 -14.1413 0.83544E+00 -0.0781 71 NaCl,aq 0.66765E-06 -6.1754 0.66765E-06 -6.1754 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95165E-02 -2.0215 0.79204E-02 -2.1013 0.83228E+00 -0.0797 79 HPO3-2 0.16791E-14 -14.7749 0.86442E-15 -15.0633 0.51482E+00 -0.2883 81 H2PO3- 0.15423E-18 -18.8118 0.12860E-18 -18.8908 0.83381E+00 -0.0789 82 H3PO4,aq 0.92912E-18 -18.0319 0.92912E-18 -18.0319 0.10000E+01 0.0000 83 H2PO4- 0.40030E-10 -10.3976 0.33410E-10 -10.4761 0.83461E+00 -0.0785 84 PO4-3 0.12125E-08 -8.9163 0.29016E-09 -9.5374 0.23930E+00 -0.6211 88 HP2O7-3 0.10381E-17 -17.9837 0.23654E-18 -18.6261 0.22785E+00 -0.6424 89 P2O7-4 0.10255E-16 -16.9891 0.77052E-18 -18.1132 0.75135E-01 -1.1242 90 H2S,aq 0.50678E-08 -8.2952 0.50497E-08 -8.2967 0.99642E+00 -0.0016 91 S2-2 0.19345E-14 -14.7134 0.99589E-15 -15.0018 0.51482E+00 -0.2883 97 SO3-2 0.11955E-17 -17.9224 0.62457E-18 -18.2044 0.52242E+00 -0.2820 99 HSO4- 0.35389E-19 -19.4511 0.29595E-19 -19.5288 0.83627E+00 -0.0777 Charge balance for all species = 0.3804E-11 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9026957E-10 -.2312507E-01 -.2326649E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981186E+06 0.0000 3 Cl- 0.1433214E-03 0.1439893E-03 0.5095612E+01 6.1981 4 SO4-- 0.8163052E-12 -.1549053E-04 -.1485351E+01 7.8659 5 HCO3- 0.2945151E-06 0.1363980E-04 0.8307559E+00 3.5115 6 HS- 0.2661130E-04 0.4210690E-04 0.1390038E+01 5.4669 7 Al+++ 0.1101130E-28 0.5280561E-05 0.1422195E+00 0.7612 8 H4SiO4 0.7114806E-03 0.1419535E-01 0.1361922E+04 -3.1478 9 Ca++ 0.1431828E-06 0.2432057E-06 0.9729552E-02 13.1067 10 Mg++ 0.2273641E-10 0.9784387E-10 0.2374474E-05 9.3055 11 Fe++ 0.6218273E-13 0.3792210E-07 0.2114001E-02 6.7429 12 K+ 0.1614382E-03 0.1622147E-03 0.6331436E+01 6.2505 13 Na+ 0.2052446E-01 0.2311530E-01 0.5304541E+03 8.3540 14 Mn++ 0.1955573E-10 0.2583427E-08 0.1416714E-03 9.2409 15 HPO4-- 0.4876403E-07 0.5001661E-07 0.4791854E-02 12.6422 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6623377E+01 -.2215902E-01 -.6601218E+01 0.0000000E+00 2 H2O 0.5049410E+02 0.5318573E+02 -.2691627E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1111084E-01 -.1484342E-04 0.1112568E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1108534E-01 0.4034789E-04 -.1112568E-01 0.0000000E+00 7 Al+++ 0.1304293E+01 0.5059966E-05 0.1304288E+01 0.0000000E+00 8 H4SiO4 0.4165103E+01 0.1360234E-01 0.4151500E+01 0.0000000E+00 9 Ca++ 0.4600704E+00 0.2330458E-06 0.4600701E+00 0.0000000E+00 10 Mg++ 0.3174595E+00 0.9375645E-10 0.3174595E+00 0.0000000E+00 11 Fe++ 0.2852027E+00 0.3633790E-07 0.2852027E+00 0.0000000E+00 12 K+ 0.8492548E-01 0.1554382E-03 0.8477004E-01 0.0000000E+00 13 Na+ 0.5022563E+00 0.2214966E-01 0.4801066E+00 0.0000000E+00 14 Mn++ 0.6935421E-02 0.2475504E-08 0.6935419E-02 0.0000000E+00 15 HPO4-- 0.2367025E-02 0.4792717E-07 0.2366977E-02 0.0000000E+00 Chg. balance for solid moles: 0.7832E-15 Mass of aqueous solution: 0.959963E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.4797 -0.319 125.8 2.100 28.80 48.28 andradite 0.4450E-01 -1.352 22.62 1.354 5.177 5.876 grossular 0.1064E-01 -1.973 4.791 0.680 1.097 1.333 apatite-OH 0.7890E-03 -3.103 0.3963 -0.402 0.9073E-01 0.1259 clinochlore 0.5823E-01 -1.235 32.37 1.510 7.410 12.31 daphnite 0.1669E-01 -1.778 11.91 1.076 2.726 3.608 chlorite-Mn 0.1387E-02 -2.858 0.9834 -0.007 0.2251 0.3134 diopside 0.1365E-01 -1.865 2.955 0.471 0.6765 0.9031 hedenbergite 0.3495E-02 -2.457 0.8671 -0.062 0.1985 0.2375 microcline 0.7428E-01 -1.129 20.67 1.315 4.733 8.076 stilbite 0.2666 -0.574 187.9 2.274 43.01 87.63 stilpnomelane-Fe 0.2098E-01 -1.678 22.62 1.354 5.178 7.813 tr.625ac.25prg.125 0.3490E-02 -2.457 2.983 0.475 0.6828 0.9600 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8071E+00 0.8071E+00 1.0000 -0.093 grossular 0.1929E+00 0.1929E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7631E+00 0.7631E+00 1.0000 -0.117 daphnite 0.2187E+00 0.2187E+00 1.0000 -0.660 chlorite-Mn 0.1818E-01 0.1818E-01 1.0000 -1.740 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 436.808564 g Volume = 177.467860 cm3 Porosity: -10.2288% V(tot) - V(min): -.16468E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 399.9990000 g log = 2.6021 Original solution: 1000.0103000 g Original solution / Rock added: 2.50 (Water/Rock Ratio), log = 0.3979 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0872 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9680E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.3926E-08 1.0071 0.4299E-08 0.4268E-08 CH4,gas 0.1826E-01 1.0128 0.2011E-01 0.1985E-01 H2,gas 0.1371E-01 1.0006 0.1492E-01 0.1491E-01 H2S,gas 0.1360E-06 0.9958 0.1473E-06 0.1479E-06 S2,gas 0.3358E-29 1.0000 0.3651E-29 0.3651E-29 CO,gas 0.1528E-13 1.0000 0.1661E-13 0.1661E-13 SO3,gas 0.8306E-48 1.0000 0.9031E-48 0.9031E-48 SO2,gas 0.4687E-27 1.0000 0.5096E-27 0.5096E-27 HCl,gas 0.2765E-17 1.0000 0.3006E-17 0.3006E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.73 -10.37 -3.456 0.17701E+05 -8.367 3 CH4,gas 4.81 1.11 -3.70 -0.924 0.63119E+04 -1.697 4 H2,gas 8.29 4.46 -3.83 -2.186 0.65333E+04 -1.826 5 H2S,gas -5.94 -14.77 -8.83 -4.416 0.15080E+05 -6.832 6 S2,gas -7.03 -38.47 -31.44 -4.837 0.53679E+05 -29.438 7 CO,gas 3.51 -12.27 -15.78 -4.855 0.26943E+05 -13.780 8 SO3,gas 17.43 -32.62 -50.04 -12.511 0.85449E+05 -48.044 9 SO2,gas 1.14 -28.16 -29.29 -7.811 0.50017E+05 -27.293 10 HCl,gas 5.48 -14.04 -19.52 -9.761 0.33333E+05 -17.522 11 acmite 7.74 6.57 -1.17 -0.121 0.19918E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.80 -4.75 -0.237 0.81079E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94109E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41192E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28379E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76228E+04 35 aragonite 0.99 -3.62 -4.61 -1.536 0.78705E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55854E+04 37 calcite 0.83 -3.62 -4.46 -1.485 0.76092E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52885E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71153E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70318E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82186E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47360E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39556E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68646E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70370E+04 52 chloritoid-Mn 11.46 7.62 -3.85 -0.257 0.65701E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13292E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10221E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.13 -0.356 0.36453E+04 66 diamond -3.11 -7.81 -4.70 -1.343 0.80275E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85130E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33645E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66042E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68258E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56965E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36652E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70705E+04 86 graphite -3.55 -7.81 -4.26 -1.217 0.72736E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38610E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60999E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24441E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64139E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59765E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.15997E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22966E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58935E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28459E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74527E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48209E+04 112 manganosite 14.07 9.24 -4.83 -1.207 0.82421E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61275E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53660E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41164E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83602E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36598E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20049E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92752E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40676E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43423E+04 143 pyrrhotite -4.24 -8.03 -3.79 -1.263 0.64680E+04 144 pyrrhotiteFe0.875 -6.00 -9.43 -3.43 -1.260 0.58509E+04 145 pyroxmangite 7.42 6.09 -1.32 -0.265 0.22590E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84878E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28316E+03 152 rhodonite 7.46 6.09 -1.37 -0.274 0.23382E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27389E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20974E+04 174 tephroite 18.11 15.33 -2.78 -0.397 0.47451E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91046E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76035E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65762E+04 181 troilite-low -4.39 -8.03 -3.64 -1.213 0.62112E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80368E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34505E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66768E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55581E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60348E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66126E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68738E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73632E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60307E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57939E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83187E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61765E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66251E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52969E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35328E+04 230 alabandite -0.96 -5.53 -4.57 -1.524 0.78053E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62637E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18237E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11529E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14891E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18336E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 10.0000000 g Current total amount of reactant added: 399.9990000 g New total amount of reactant added: 409.9990000 g Mixing fraction reached given limit of 0.4000E+03 TOTMIX = 0.4100E+03 Execution stopped.