File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.13247E+02 0.90291E-10 0.8389 0.00000000E+00 H2O 2 0. 0.45480E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.14960E-03 0.8338 0.00000000E+00 SO4-- 4 -2. 0.22196E-01 0.85296E-12 0.5159 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.30771E-06 0.8350 0.00000000E+00 HS- 6 -1. -0.22171E-01 0.27776E-04 0.8339 0.00000000E+00 Al+++ 7 3. 0.26086E+01 0.11016E-28 0.2276 0.00000000E+00 H4SiO4 8 0. 0.83302E+01 0.71158E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.92013E+00 0.14323E-06 0.5120 0.00000000E+00 Mg++ 10 2. 0.63492E+00 0.22744E-10 0.5096 0.00000000E+00 Fe++ 11 2. 0.57041E+00 0.62211E-13 0.5102 0.00000000E+00 K+ 12 1. 0.16985E+00 0.16148E-03 0.8352 0.00000000E+00 Na+ 13 1. 0.10044E+01 0.20529E-01 0.8336 0.00000000E+00 Mn++ 14 2. 0.13871E-01 0.19791E-10 0.5106 0.00000000E+00 HPO4-- 15 -2. 0.47341E-02 0.48757E-07 0.5160 0.00000000E+00 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 100.0000 SLIM = 0.200000E+04 TEMP = 100.0000 SINC = 0.4000E+02 TEMPC = 0.0000 TOTMIX = 0.799999E+03 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 320.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0107 MnO2-2 65 -2. 40.4376 Ca(HSiO3)+ 17 1. 7.6603 HMnO2- 66 -1. 29.1018 Mg(HSiO3)+ 18 1. 7.5653 MnO4- 67 -1. 83.3383 NaHSiO3,aq 19 0. 7.8098 MnO4-2 68 -2. 81.3024 AlO+ 20 1. 6.8891 MnCl+ 69 1. -0.7819 AlOH+2 21 2. 3.1893 MnSO4,aq 70 0. -2.4524 HAlO2,aq 22 0. 10.5878 NaCl,aq 71 0. 0.4861 AlO2- 23 -1. 16.2390 NaOH,aq 72 0. 12.3571 CH4,aq 24 0. 6.0082 O2,aq 73 0. 53.5759 C2H6,aq 25 0. 12.3556 OH- 74 -1. 12.2220 C3H8,aq 26 0. 17.3423 HO2- 75 -1. 50.7897 C4H10,aq 27 0. 22.3397 H2O2,aq 76 0. 40.0297 ethanol,aq 28 0. 15.3114 H3PO2,aq 77 0. 24.3310 CO,aq 29 0. 4.7087 H2PO2- 78 -1. 26.5491 CO2,aq 30 0. -6.3045 HPO3-2 79 -2. 11.9246 CO3-2 31 -2. 10.0340 H3PO3,aq 80 0. 3.5932 CaCO3,aq 32 0. 5.9460 H2PO3- 81 -1. 5.6314 Ca(HCO3)+ 33 1. -1.4013 H3PO4,aq 82 0. -9.8087 CaCl+ 34 1. -0.2023 H2PO4- 83 -1. -7.2438 CaCl2,aq 35 0. 0.4306 PO4-3 84 -3. 12.0588 CaOH+ 36 1. 10.1517 H4P2O7,aq 85 0. -17.7539 CaSO4,aq 37 0. -2.4936 H3P2O7- 86 -1. -15.8646 HCl,aq 38 0. 0.7256 H2P2O7-2 87 -2. -13.3812 HClO,aq 39 0. 32.4377 HP2O7-3 88 -3. -6.6931 ClO- 40 -1. 39.6416 P2O7-4 89 -4. 2.9147 HClO2,aq 41 0. 70.2060 H2S,aq 90 0. -6.4778 Fe+3 42 3. 8.3763 S2-2 91 -2. 1.2336 FeCl+ 43 1. -0.1924 S3-2 92 -2. -8.7963 FeCl2,aq 44 0. 4.3160 S3- 93 -1. -16.3178 FeCl+2 45 2. 6.5223 S4-2 94 -2. -18.6473 FeO,aq 46 0. 16.4029 S5-2 95 -2. -28.3223 FeOH+ 47 1. 7.4795 SO2,aq 96 0. -0.1980 HFeO2- 48 -1. 24.3713 SO3-2 97 -2. 10.2895 FeO+ 49 1. 11.3812 HSO3- 98 -1. 2.5222 FeOH+2 50 2. 9.1115 HSO4- 99 -1. -2.9675 FeO2- 51 -1. 24.0877 HSO5- 100 -1. 38.8657 HFeO2,aq 52 0. 15.9903 S2O3-2 101 -2. -4.5491 H2,aq 53 0. 9.4241 HS2O3- 102 -1. -6.8007 KCl,aq 54 0. 1.7519 H2S2O3,aq 103 0. -7.9944 KHSO4,aq 55 0. -0.4275 S2O4-2 104 -2. 10.5639 KOH,aq 56 0. 12.3606 HS2O4- 105 -1. 7.6762 KSO4- 57 -1. -1.1877 H2S2O4,aq 106 0. 6.6566 MgCO3,aq 58 0. 6.5483 S2O5-2 107 -2. 10.0891 Mg(HCO3)+ 59 1. -1.4098 S2O6-2 108 -2. 11.5737 MgCl+ 60 1. -0.1603 S2O8-2 109 -2. 42.1139 MgOH+ 61 1. 9.4082 S3O6-2 110 -2. 3.8101 Mn+3 62 3. 19.1332 S4O6-2 111 -2. -17.8301 MnO,aq 63 0. 17.9765 S5O6-2 112 -2. -14.1051 MnOH+ 64 1. 8.5115 113 0. 10.3157 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.984 0.0000E+00 osumilite(2) 124 20.895 0.0000E+00 CO2,gas 2 -6.363 0.0000E+00 osumilite-Fe 125 14.657 0.0000E+00 CH4,gas 3 4.809 0.0000E+00 pargasite 126 65.279 0.0000E+00 H2,gas 4 8.287 0.0000E+00 periclase 127 16.149 0.0000E+00 H2S,gas 5 -5.943 0.0000E+00 periclase-Fe 128 11.639 0.0000E+00 S2,gas 6 -7.033 0.0000E+00 perovskite-Al 129 12.395 0.0000E+00 CO,gas 7 3.510 0.0000E+00 perovskite-Ca 130 23.818 0.0000E+00 SO3,gas 8 17.427 0.0000E+00 perovskite-Fe 131 21.158 0.0000E+00 SO2,gas 9 1.136 0.0000E+00 perovskite-Mg 132 23.132 0.0000E+00 HCl,gas 10 5.479 0.0000E+00 phase_A 133 80.267 0.0000E+00 acmite 11 7.737 0.0000E+00 phlogopite-Na 134 29.731 0.0000E+00 akermanite 12 36.495 0.0000E+00 piemontite(ordered) 135 33.876 0.0000E+00 akimotoite 13 16.606 0.0000E+00 prehnite 136 19.466 0.0000E+00 akimotoite-Fe 14 13.083 0.0000E+00 prehnite-Fe 137 22.587 0.0000E+00 albite-high 15 0.750 0.0000E+00 pumpellyite-Fe 138 46.471 0.0000E+00 albite 16 -0.328 0.9824E+00 pumpellyite-Mg 139 49.194 0.0000E+00 almandine 17 24.545 0.0000E+00 px-Mg-tschermaks 140 19.687 0.0000E+00 pyrope 18 37.348 0.0000E+00 px-Ca-tschermaks 141 18.679 0.0000E+00 spessartine 19 24.550 0.0000E+00 pyrite 142 -21.225 0.0000E+00 analcite 20 3.371 0.0000E+00 pyrrhotite 143 -4.244 0.0000E+00 andalusite 21 5.062 0.0000E+00 pyrrhotiteFe0.875 144 -6.001 0.0000E+00 andradite 22 39.088 0.8884E-01 pyroxmangite 145 7.416 0.0000E+00 grossular 23 32.828 0.2122E-01 pyrophyllite 146 -6.098 0.0000E+00 anhydrite 24 -5.280 0.0000E+00 quartz 147 -2.982 0.0000E+00 ankerite 25 -2.093 0.0000E+00 rankinite 148 40.765 0.0000E+00 annite 26 20.209 0.0000E+00 ringwoodite-Fe 149 15.486 0.0000E+00 phlogopite 27 27.147 0.0000E+00 ringwoodite-Mg 150 27.602 0.0000E+00 biotite-Mn 28 33.034 0.0000E+00 rhodochrosite 151 -0.959 0.0000E+00 anorthite 29 12.798 0.0000E+00 rhodonite 152 7.462 0.0000E+00 anthophyllite 30 51.988 0.0000E+00 sanidine 153 -1.221 0.0000E+00 anthophyllite-Fe 31 29.455 0.0000E+00 sapphirine(351) 154 79.204 0.0000E+00 apatite-OH 32 -17.989 0.1578E-02 siderite 155 -2.588 0.0000E+00 apatite-OH-zs 33 -12.572 0.0000E+00 sillimanite 156 5.321 0.0000E+00 apatite-Cl-zs 34 -16.504 0.0000E+00 sodalite 157 50.255 0.0000E+00 aragonite 35 0.986 0.0000E+00 spinel 158 20.934 0.0000E+00 brucite 36 12.577 0.0000E+00 spurrite 159 59.566 0.0000E+00 calcite 37 0.833 0.0000E+00 staurolite-Fe 160 74.138 0.0000E+00 carnegieite-low 38 9.065 0.0000E+00 staurolite-Mg 161 90.336 0.0000E+00 carnegieite-high 39 10.134 0.0000E+00 staurolite-Mn 162 84.438 0.0000E+00 carpholite-Mg 40 8.650 0.0000E+00 stilbite 163 -7.406 0.5234E+00 carpholite-Fe 41 6.783 0.0000E+00 stilpnomelane-Fe 164 13.179 0.4211E-01 celadonite 42 5.401 0.0000E+00 stilpnomelane-Mg 165 27.596 0.0000E+00 celadonite-Fe 43 3.937 0.0000E+00 stishovite 166 2.721 0.0000E+00 chrysotile 44 23.937 0.0000E+00 sudoite-Fe 167 18.437 0.0000E+00 chondrodite 45 56.542 0.0000E+00 sudoite 168 21.216 0.0000E+00 clinochlore 46 39.193 0.1151E+00 sulfur 169 -9.141 0.0000E+00 daphnite 47 29.094 0.3299E-01 sylvite 170 1.345 0.0000E+00 chlorite-Mn 48 46.985 0.2774E-02 talc 171 16.553 0.0000E+00 chlorite-Al-free 49 47.262 0.0000E+00 talc-Fe 172 13.516 0.0000E+00 chloritoid-Mg 50 13.261 0.0000E+00 talc-tschermaks 173 19.189 0.0000E+00 chloritoid-Fe 51 9.239 0.0000E+00 tephroite 174 18.113 0.0000E+00 chloritoid-Mn 52 11.463 0.0000E+00 tilleyite 175 41.473 0.0000E+00 clinohumite 53 97.255 0.0000E+00 titanite-CaSi 176 15.497 0.0000E+00 coesite 54 -2.369 0.0000E+00 topaz-H 177 4.668 0.0000E+00 cordierite-H 55 23.898 0.0000E+00 tridymite 178 -2.615 0.0000E+00 cordierite 56 24.245 0.0000E+00 tremolite 179 48.003 0.0000E+00 cordierite-Fe 57 20.649 0.0000E+00 ferroactinolite 180 38.596 0.0000E+00 cordierite-Mn 58 25.261 0.0000E+00 troilite-low 181 -4.394 0.0000E+00 corundum 59 8.433 0.0000E+00 tschermakite 182 48.414 0.0000E+00 corundum-MgSi 60 18.905 0.0000E+00 vesuvianite 183 224.056 0.0000E+00 cristobalite 61 -2.549 0.0000E+00 wadeite-Si 184 20.233 0.0000E+00 cummingtonite 62 52.233 0.0000E+00 wadsleyite-Fe 185 15.711 0.0000E+00 cymrite-K 63 1.731 0.0000E+00 wadsleyite-Mg 186 25.878 0.0000E+00 deerite 64 95.982 0.0000E+00 wairakite 187 4.058 0.0000E+00 diaspore 65 2.896 0.0000E+00 walstromite 188 11.528 0.0000E+00 diamond 66 -3.107 0.0000E+00 wollastonite 189 10.482 0.0000E+00 diopside 67 16.215 0.3678E-01 pseudo-wollastonite 190 11.020 0.0000E+00 hedenbergite 68 14.244 0.9423E-02 zoisite 191 22.964 0.0000E+00 dolomite,ordered 69 0.587 0.0000E+00 akaganeite 192 7.768 0.0000E+00 eastonite 70 28.605 0.0000E+00 beidellite-Ca 193 -1.560 0.0000E+00 enstatite 71 17.301 0.0000E+00 beidellite-H 194 -2.241 0.0000E+00 clinoenstatite-HiP 72 18.388 0.0000E+00 beidellite-K 195 -1.435 0.0000E+00 clinoenstatite 73 17.202 0.0000E+00 beidellite-Mg 196 -1.707 0.0000E+00 protoenstatite 74 17.860 0.0000E+00 beidellite-Na 197 -1.257 0.0000E+00 epidote 75 24.775 0.0000E+00 calcium 198 84.043 0.0000E+00 clinozoisite 76 22.921 0.0000E+00 chalcedony 199 -2.794 0.0000E+00 epidote-Fe 77 29.937 0.0000E+00 dawsonite 200 1.714 0.0000E+00 fayalite 78 14.079 0.0000E+00 montmorillonite-Ca 201 -2.214 0.0000E+00 ferrosilite 79 11.188 0.0000E+00 montmorillonite-K 202 -2.161 0.0000E+00 forsterite 80 21.047 0.0000E+00 montmorillonite-Mg 203 -2.402 0.0000E+00 gedrite 81 50.725 0.0000E+00 montmorillonite-Na 204 -1.961 0.0000E+00 gehlenite 82 36.717 0.0000E+00 nontronite-Ca 205 3.280 0.0000E+00 gibbsite 83 4.097 0.0000E+00 nontronite-H 206 2.596 0.0000E+00 glaucophane 84 23.111 0.0000E+00 nontronite-K 207 3.404 0.0000E+00 glaucophane-Fe 85 17.417 0.0000E+00 nontronite-Mg 208 3.139 0.0000E+00 graphite 86 -3.549 0.0000E+00 nontronite-Na 209 3.583 0.0000E+00 greenalite 87 16.194 0.0000E+00 sepiolite 210 24.194 0.0000E+00 grunerite 88 31.364 0.0000E+00 alite 211 58.043 0.0000E+00 halite 89 1.582 0.0000E+00 belite 212 30.461 0.0000E+00 hematite 90 12.598 0.0000E+00 ettringite 213 43.354 0.0000E+00 heulandite 91 -5.707 0.0000E+00 gypsum 214 -4.924 0.0000E+00 hercynite 92 17.345 0.0000E+00 hemicarboaluminate 215 71.028 0.0000E+00 hollandite 93 25.702 0.0000E+00 hydrogarnet 216 60.721 0.0000E+00 iron 94 19.095 0.0000E+00 hydrogarnet-Si 217 50.654 0.0000E+00 jadeite 95 4.251 0.0000E+00 jennite 218 24.386 0.0000E+00 julgoldite 96 70.573 0.0000E+00 monosulfoaluminate 219 53.497 0.0000E+00 kalsilite 97 7.620 0.0000E+00 monocarboaluminate 220 61.966 0.0000E+00 kaolinite 98 -1.273 0.0000E+00 portlandite 221 18.282 0.0000E+00 kyanite 99 4.932 0.0000E+00 stratlingite 222 36.573 0.0000E+00 larnite-bredigite 100 30.714 0.0000E+00 tricarboaluminate 223 70.427 0.0000E+00 laumontite 101 2.975 0.0000E+00 tobermorite 224 9.839 0.0000E+00 lawsonite 102 9.678 0.0000E+00 C4AH13 225 81.870 0.0000E+00 leucite 103 4.168 0.0000E+00 C2AH8 226 45.260 0.0000E+00 lime 104 26.009 0.0000E+00 C3A 227 87.049 0.0000E+00 lizardite 105 23.287 0.0000E+00 C4AF 228 117.550 0.0000E+00 magnesite 106 0.709 0.0000E+00 CAH10 229 28.373 0.0000E+00 magnetite 107 20.133 0.0000E+00 alabandite 230 -0.962 0.0000E+00 minnesotaite 108 10.461 0.0000E+00 alunite 231 -10.224 0.0000E+00 minnesotaite-Mg 109 20.669 0.0000E+00 artinite 232 15.139 0.0000E+00 magnesioferrite 110 26.257 0.0000E+00 boehmite 233 4.430 0.0000E+00 majorite 111 53.314 0.0000E+00 dolomite,disordered 234 1.288 0.0000E+00 manganosite 112 14.068 0.0000E+00 ferrous-oxide 235 9.824 0.0000E+00 margarite 113 17.452 0.0000E+00 huntite 236 3.850 0.0000E+00 meionite 114 45.158 0.0000E+00 hydromagnesite 237 20.077 0.0000E+00 merwinite 115 55.988 0.0000E+00 nesquehonite 238 4.735 0.0000E+00 microcline 116 -2.432 0.1486E+00 potassium-oxide 239 69.039 0.0000E+00 monticellite 117 24.371 0.0000E+00 silica-amorphous 240 -2.080 0.0000E+00 mullite-Al 118 363.258 0.0000E+00 sodium-oxide 241 55.173 0.0000E+00 mullite-Si 119 7.324 0.0000E+00 an20ab80 242 2.079 0.0000E+00 muscovite 120 2.679 0.0000E+00 an25ab75 243 2.709 0.0000E+00 paragonite 121 4.337 0.0000E+00 an30ab70 244 3.344 0.0000E+00 nepheline 122 8.378 0.0000E+00 tr.625ac.25prg.125 245 45.308 0.6215E-02 osumilite(1) 123 21.978 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 799.9990000 g log = 2.9031 Original solution: 1000.0103000 g Original solution / Rock added: 1.25 (Water/Rock Ratio), log = 0.0969 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 799.9990000 Water: Moles liquid = 0.5096E+02 kg liquid = 0.9180E+00 Moles total = 0.4548E+02 kg total = 0.8193E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173867E-01 Osmotic coef. = 0.9689 True ionic strength = .2069192E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90291E-10 -10.0444 0.75749E-10 -10.1206 0.83895E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14960E-03 -3.8251 0.12473E-03 -3.9040 0.83380E+00 -0.0789 4 SO4-- 0.85296E-12 -12.0691 0.44005E-12 -12.3565 0.51590E+00 -0.2874 5 HCO3- 0.30771E-06 -6.5119 0.25695E-06 -6.5901 0.83504E+00 -0.0783 6 HS- 0.27776E-04 -4.5563 0.23163E-04 -4.6352 0.83392E+00 -0.0789 7 Al+++ 0.11016E-28 -28.9580 0.25069E-29 -29.6009 0.22757E+00 -0.6429 8 H4SiO4 0.71158E-03 -3.1478 0.71158E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14323E-06 -6.8440 0.73341E-07 -7.1347 0.51203E+00 -0.2907 10 Mg++ 0.22744E-10 -10.6431 0.11592E-10 -10.9359 0.50965E+00 -0.2927 11 Fe++ 0.62211E-13 -13.2061 0.31741E-13 -13.4984 0.51022E+00 -0.2922 12 K+ 0.16148E-03 -3.7919 0.13487E-03 -3.8701 0.83524E+00 -0.0782 13 Na+ 0.20529E-01 -1.6876 0.17114E-01 -1.7666 0.83364E+00 -0.0790 14 Mn++ 0.19791E-10 -10.7035 0.10106E-10 -10.9954 0.51065E+00 -0.2919 15 HPO4-- 0.48757E-07 -7.3120 0.25158E-07 -7.5993 0.51598E+00 -0.2874 16 HSiO3- 0.10992E-01 -1.9589 0.91653E-02 -2.0379 0.83380E+00 -0.0789 17 Ca(HSiO3)+ 0.18028E-07 -7.7441 0.15061E-07 -7.8222 0.83542E+00 -0.0781 18 Mg(HSiO3)+ 0.35459E-11 -11.4503 0.29624E-11 -11.5284 0.83542E+00 -0.0781 19 NaHSiO3,aq 0.24912E-02 -2.6036 0.24912E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67512E-16 -16.1706 0.56401E-16 -16.2487 0.83542E+00 -0.0781 22 HAlO2,aq 0.14900E-09 -9.8268 0.14900E-09 -9.8268 0.10000E+01 0.0000 23 AlO2- 0.52772E-05 -5.2776 0.43920E-05 -5.3573 0.83227E+00 -0.0797 24 CH4,aq 0.13320E-04 -4.8755 0.13272E-04 -4.8771 0.99642E+00 -0.0016 25 C2H6,aq 0.28039E-14 -14.5522 0.27939E-14 -14.5538 0.99642E+00 -0.0016 29 CO,aq 0.10989E-16 -16.9590 0.10989E-16 -16.9590 0.10000E+01 0.0000 30 CO2,aq 0.39384E-10 -10.4047 0.39243E-10 -10.4062 0.99642E+00 -0.0016 31 CO3-2 0.60925E-06 -6.2152 0.31364E-06 -6.5036 0.51479E+00 -0.2884 32 CaCO3,aq 0.28172E-09 -9.5502 0.28172E-09 -9.5502 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.56839E-12 -12.2454 0.47484E-12 -12.3235 0.83542E+00 -0.0781 34 CaCl+ 0.17449E-10 -10.7582 0.14577E-10 -10.8363 0.83542E+00 -0.0781 35 CaCl2,aq 0.42335E-15 -15.3733 0.42335E-15 -15.3733 0.10000E+01 0.0000 36 CaOH+ 0.81720E-07 -7.0877 0.68271E-07 -7.1658 0.83542E+00 -0.0781 37 CaSO4,aq 0.10056E-16 -16.9976 0.10056E-16 -16.9976 0.10000E+01 0.0000 38 HCl,aq 0.17772E-14 -14.7503 0.17772E-14 -14.7503 0.10000E+01 0.0000 43 FeCl+ 0.73811E-17 -17.1319 0.61663E-17 -17.2100 0.83542E+00 -0.0781 46 FeO,aq 0.21875E-09 -9.6601 0.21875E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16628E-10 -10.7792 0.13892E-10 -10.8572 0.83542E+00 -0.0781 48 HFeO2- 0.37253E-07 -7.4288 0.31061E-07 -7.5078 0.83380E+00 -0.0789 49 FeO+ 0.12272E-16 -16.9111 0.10252E-16 -16.9892 0.83542E+00 -0.0781 51 FeO2- 0.42116E-09 -9.3755 0.35116E-09 -9.4545 0.83380E+00 -0.0789 52 HFeO2,aq 0.33291E-11 -11.4777 0.33291E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10912E-04 -4.9621 0.10873E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.29787E-09 -9.5260 0.29787E-09 -9.5260 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10966E-14 -14.9599 0.91436E-15 -15.0389 0.83380E+00 -0.0789 58 MgCO3,aq 0.11126E-13 -13.9537 0.11126E-13 -13.9537 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.91606E-16 -16.0381 0.76530E-16 -16.1162 0.83542E+00 -0.0781 60 MgCl+ 0.25036E-14 -14.6014 0.20916E-14 -14.6795 0.83542E+00 -0.0781 61 MgOH+ 0.71555E-10 -10.1454 0.59779E-10 -10.2235 0.83542E+00 -0.0781 63 MnO,aq 0.18593E-08 -8.7307 0.18593E-08 -8.7307 0.10000E+01 0.0000 64 MnOH+ 0.49184E-09 -9.3082 0.41089E-09 -9.3863 0.83542E+00 -0.0781 65 MnO2-2 0.21769E-10 -10.6622 0.11206E-10 -10.9505 0.51479E+00 -0.2884 66 HMnO2- 0.22058E-09 -9.6564 0.18392E-09 -9.7354 0.83380E+00 -0.0789 69 MnCl+ 0.91323E-14 -14.0394 0.76293E-14 -14.1175 0.83542E+00 -0.0781 71 NaCl,aq 0.69702E-06 -6.1568 0.69702E-06 -6.1568 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95146E-02 -2.0216 0.79187E-02 -2.1013 0.83227E+00 -0.0797 79 HPO3-2 0.16783E-14 -14.7751 0.86397E-15 -15.0635 0.51479E+00 -0.2884 81 H2PO3- 0.15418E-18 -18.8120 0.12856E-18 -18.8909 0.83380E+00 -0.0789 82 H3PO4,aq 0.92934E-18 -18.0318 0.92934E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40031E-10 -10.3976 0.33410E-10 -10.4761 0.83460E+00 -0.0785 84 PO4-3 0.12122E-08 -8.9164 0.29004E-09 -9.5375 0.23927E+00 -0.6211 88 HP2O7-3 0.10381E-17 -17.9838 0.23649E-18 -18.6262 0.22781E+00 -0.6424 89 P2O7-4 0.10253E-16 -16.9891 0.77020E-18 -18.1134 0.75117E-01 -1.1243 90 H2S,aq 0.52907E-08 -8.2765 0.52718E-08 -8.2780 0.99642E+00 -0.0016 91 S2-2 0.21082E-14 -14.6761 0.10853E-14 -14.9645 0.51479E+00 -0.2884 97 SO3-2 0.12488E-17 -17.9035 0.65237E-18 -18.1855 0.52239E+00 -0.2820 99 HSO4- 0.36985E-19 -19.4320 0.30929E-19 -19.5096 0.83625E+00 -0.0777 Charge balance for all species = 0.3593E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9029068E-10 -.2312275E-01 -.2326414E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981182E+06 0.0000 3 Cl- 0.1495951E-03 0.1502924E-03 0.5318669E+01 6.2166 4 SO4-- 0.8529634E-12 -.1604752E-04 -.1538759E+01 7.8847 5 HCO3- 0.3077126E-06 0.1423688E-04 0.8671217E+00 3.5305 6 HS- 0.2777620E-04 0.4382901E-04 0.1446888E+01 5.4854 7 Al+++ 0.1101562E-28 0.5277348E-05 0.1421329E+00 0.7610 8 H4SiO4 0.7115772E-03 0.1419504E-01 0.1361892E+04 -3.1478 9 Ca++ 0.1432347E-06 0.2432825E-06 0.9732620E-02 13.1066 10 Mg++ 0.2274435E-10 0.9785906E-10 0.2374842E-05 9.3054 11 Fe++ 0.6221054E-13 0.3791243E-07 0.2113462E-02 6.7429 12 K+ 0.1614758E-03 0.1622523E-03 0.6332903E+01 6.2505 13 Na+ 0.2052926E-01 0.2312046E-01 0.5305723E+03 8.3540 14 Mn++ 0.1979106E-10 0.2613276E-08 0.1433082E-03 9.2458 15 HPO4-- 0.4875695E-07 0.5000918E-07 0.4791140E-02 12.6419 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1324678E+02 -.2122756E-01 -.1322556E+02 0.0000000E+00 2 H2O 0.4547993E+02 0.5095517E+02 -.5475240E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2219620E-01 -.1473223E-04 0.2221094E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2217070E-01 0.4023670E-04 -.2221094E-01 0.0000000E+00 7 Al+++ 0.2608590E+01 0.4844807E-05 0.2608585E+01 0.0000000E+00 8 H4SiO4 0.8330216E+01 0.1303159E-01 0.8317184E+01 0.0000000E+00 9 Ca++ 0.9201274E+00 0.2233426E-06 0.9201272E+00 0.0000000E+00 10 Mg++ 0.6349198E+00 0.8983836E-10 0.6349198E+00 0.0000000E+00 11 Fe++ 0.5704062E+00 0.3480506E-07 0.5704061E+00 0.0000000E+00 12 K+ 0.1698512E+00 0.1489538E-03 0.1697022E+00 0.0000000E+00 13 Na+ 0.1004354E+01 0.2122546E-01 0.9831283E+00 0.0000000E+00 14 Mn++ 0.1387086E-01 0.2399087E-08 0.1387086E-01 0.0000000E+00 15 HPO4-- 0.4734055E-02 0.4591034E-07 0.4734009E-02 0.0000000E+00 Chg. balance for solid moles: 0.5638E-15 Mass of aqueous solution: 0.919703E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9824 -0.008 257.6 2.411 29.48 98.88 andradite 0.8884E-01 -1.051 45.15 1.655 5.167 11.73 grossular 0.2122E-01 -1.673 9.559 0.980 1.094 2.660 apatite-OH 0.1578E-02 -2.802 0.7927 -0.101 0.9071E-01 0.2519 clinochlore 0.1151 -0.939 63.99 1.806 7.323 24.34 daphnite 0.3299E-01 -1.482 23.54 1.372 2.694 7.133 chlorite-Mn 0.2774E-02 -2.557 1.967 0.294 0.2251 0.6268 diopside 0.3678E-01 -1.434 7.966 0.901 0.9116 2.434 hedenbergite 0.9423E-02 -2.026 2.338 0.369 0.2675 0.6403 microcline 0.1486 -0.828 41.37 1.617 4.735 16.16 stilbite 0.5234 -0.281 368.9 2.567 42.21 172.0 stilpnomelane-Fe 0.4211E-01 -1.376 45.40 1.657 5.195 15.68 tr.625ac.25prg.125 0.6215E-02 -2.207 5.313 0.725 0.6080 1.710 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7630E+00 0.7630E+00 1.0000 -0.117 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1839E-01 0.1839E-01 1.0000 -1.736 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 873.830420 g Volume = 354.293285 cm3 Porosity: -10.3719% V(tot) - V(min): -.33294E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 799.9990000 g log = 2.9031 Original solution: 1000.0103000 g Original solution / Rock added: 1.25 (Water/Rock Ratio), log = 0.0969 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0881 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9673E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4099E-08 1.0071 0.4492E-08 0.4460E-08 CH4,gas 0.1904E-01 1.0128 0.2099E-01 0.2072E-01 H2,gas 0.1370E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1419E-06 0.9958 0.1538E-06 0.1544E-06 S2,gas 0.3659E-29 1.0000 0.3981E-29 0.3981E-29 CO,gas 0.1595E-13 1.0000 0.1735E-13 0.1735E-13 SO3,gas 0.8676E-48 1.0000 0.9440E-48 0.9440E-48 SO2,gas 0.4894E-27 1.0000 0.5325E-27 0.5325E-27 HCl,gas 0.2884E-17 1.0000 0.3138E-17 0.3138E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.71 -10.35 -3.449 0.17668E+05 -8.348 3 CH4,gas 4.81 1.13 -3.68 -0.920 0.62801E+04 -1.678 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65335E+04 -1.826 5 H2S,gas -5.94 -14.76 -8.81 -4.407 0.15048E+05 -6.813 6 S2,gas -7.03 -38.43 -31.40 -4.831 0.53615E+05 -29.400 7 CO,gas 3.51 -12.25 -15.76 -4.849 0.26911E+05 -13.761 8 SO3,gas 17.43 -32.60 -50.03 -12.506 0.85416E+05 -48.025 9 SO2,gas 1.14 -28.14 -29.27 -7.806 0.49984E+05 -27.274 10 HCl,gas 5.48 -14.02 -19.50 -9.752 0.33301E+05 -17.503 11 acmite 7.74 6.57 -1.17 -0.121 0.19915E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.237 0.80827E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94120E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41193E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28382E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76233E+04 35 aragonite 0.99 -3.60 -4.59 -1.530 0.78380E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55855E+04 37 calcite 0.83 -3.60 -4.44 -1.479 0.75766E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71155E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70323E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82191E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68648E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70375E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65621E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36456E+04 66 diamond -3.11 -7.79 -4.68 -1.338 0.79953E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33650E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66050E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68257E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56968E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36653E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.79 -4.24 -1.212 0.72414E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60997E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24442E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64141E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59769E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16000E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22971E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28460E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74526E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48206E+04 112 manganosite 14.07 9.25 -4.82 -1.206 0.82336E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61281E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53666E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41166E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36601E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20054E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92765E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40689E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43438E+04 143 pyrrhotite -4.24 -8.01 -3.77 -1.256 0.64361E+04 144 pyrrhotiteFe0.875 -6.00 -9.41 -3.41 -1.253 0.58189E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.264 0.22504E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84880E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28306E+03 152 rhodonite 7.46 6.10 -1.36 -0.273 0.23296E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27393E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.34 -2.77 -0.396 0.47280E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91036E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76031E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65758E+04 181 troilite-low -4.39 -8.01 -3.62 -1.206 0.61793E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80404E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34508E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66776E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60338E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73634E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60308E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57935E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83183E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61761E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66247E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52965E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.51 -4.55 -1.516 0.77649E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62640E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18236E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11530E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14892E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18337E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 799.9990000 g New total amount of reactant added: 839.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 839.9990000 Water: Moles liquid = 0.5074E+02 kg liquid = 0.9140E+00 Moles total = 0.4498E+02 kg total = 0.8103E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173924E-01 Osmotic coef. = 0.9689 True ionic strength = .2069239E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90293E-10 -10.0443 0.75751E-10 -10.1206 0.83895E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15025E-03 -3.8232 0.12528E-03 -3.9021 0.83380E+00 -0.0789 4 SO4-- 0.85675E-12 -12.0671 0.44200E-12 -12.3546 0.51590E+00 -0.2874 5 HCO3- 0.30908E-06 -6.5099 0.25809E-06 -6.5882 0.83504E+00 -0.0783 6 HS- 0.27898E-04 -4.5544 0.23265E-04 -4.6333 0.83392E+00 -0.0789 7 Al+++ 0.11016E-28 -28.9580 0.25070E-29 -29.6008 0.22757E+00 -0.6429 8 H4SiO4 0.71158E-03 -3.1478 0.71158E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14324E-06 -6.8439 0.73344E-07 -7.1346 0.51203E+00 -0.2907 10 Mg++ 0.22745E-10 -10.6431 0.11592E-10 -10.9358 0.50964E+00 -0.2927 11 Fe++ 0.62213E-13 -13.2061 0.31742E-13 -13.4984 0.51021E+00 -0.2922 12 K+ 0.16148E-03 -3.7919 0.13487E-03 -3.8701 0.83524E+00 -0.0782 13 Na+ 0.20530E-01 -1.6876 0.17114E-01 -1.7666 0.83364E+00 -0.0790 14 Mn++ 0.19803E-10 -10.7033 0.10112E-10 -10.9952 0.51064E+00 -0.2919 15 HPO4-- 0.48756E-07 -7.3120 0.25157E-07 -7.5993 0.51598E+00 -0.2874 16 HSiO3- 0.10992E-01 -1.9589 0.91651E-02 -2.0379 0.83380E+00 -0.0789 17 Ca(HSiO3)+ 0.18028E-07 -7.7441 0.15061E-07 -7.8221 0.83542E+00 -0.0781 18 Mg(HSiO3)+ 0.35460E-11 -11.4503 0.29624E-11 -11.5284 0.83542E+00 -0.0781 19 NaHSiO3,aq 0.24912E-02 -2.6036 0.24912E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67512E-16 -16.1706 0.56401E-16 -16.2487 0.83542E+00 -0.0781 22 HAlO2,aq 0.14899E-09 -9.8268 0.14899E-09 -9.8268 0.10000E+01 0.0000 23 AlO2- 0.52770E-05 -5.2776 0.43919E-05 -5.3574 0.83227E+00 -0.0797 24 CH4,aq 0.13378E-04 -4.8736 0.13330E-04 -4.8752 0.99642E+00 -0.0016 25 C2H6,aq 0.28286E-14 -14.5484 0.28185E-14 -14.5500 0.99642E+00 -0.0016 29 CO,aq 0.11038E-16 -16.9571 0.11038E-16 -16.9571 0.10000E+01 0.0000 30 CO2,aq 0.39560E-10 -10.4027 0.39418E-10 -10.4043 0.99642E+00 -0.0016 31 CO3-2 0.61195E-06 -6.2133 0.31502E-06 -6.5017 0.51478E+00 -0.2884 32 CaCO3,aq 0.28298E-09 -9.5482 0.28298E-09 -9.5482 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.57093E-12 -12.2434 0.47696E-12 -12.3215 0.83542E+00 -0.0781 34 CaCl+ 0.17526E-10 -10.7563 0.14642E-10 -10.8344 0.83542E+00 -0.0781 35 CaCl2,aq 0.42710E-15 -15.3695 0.42710E-15 -15.3695 0.10000E+01 0.0000 36 CaOH+ 0.81722E-07 -7.0877 0.68272E-07 -7.1658 0.83542E+00 -0.0781 37 CaSO4,aq 0.10101E-16 -16.9957 0.10101E-16 -16.9957 0.10000E+01 0.0000 38 HCl,aq 0.17851E-14 -14.7483 0.17851E-14 -14.7483 0.10000E+01 0.0000 43 FeCl+ 0.74138E-17 -17.1300 0.61937E-17 -17.2081 0.83542E+00 -0.0781 46 FeO,aq 0.21875E-09 -9.6601 0.21875E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16629E-10 -10.7791 0.13892E-10 -10.8572 0.83542E+00 -0.0781 48 HFeO2- 0.37252E-07 -7.4289 0.31060E-07 -7.5078 0.83380E+00 -0.0789 49 FeO+ 0.12272E-16 -16.9111 0.10252E-16 -16.9892 0.83542E+00 -0.0781 51 FeO2- 0.42116E-09 -9.3756 0.35116E-09 -9.4545 0.83380E+00 -0.0789 52 HFeO2,aq 0.33291E-11 -11.4777 0.33291E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10912E-04 -4.9621 0.10873E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.29919E-09 -9.5241 0.29919E-09 -9.5241 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11015E-14 -14.9580 0.91844E-15 -15.0369 0.83380E+00 -0.0789 58 MgCO3,aq 0.11176E-13 -13.9517 0.11176E-13 -13.9517 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.92015E-16 -16.0361 0.76872E-16 -16.1142 0.83542E+00 -0.0781 60 MgCl+ 0.25147E-14 -14.5995 0.21008E-14 -14.6776 0.83542E+00 -0.0781 61 MgOH+ 0.71556E-10 -10.1454 0.59779E-10 -10.2234 0.83542E+00 -0.0781 63 MnO,aq 0.18603E-08 -8.7304 0.18603E-08 -8.7304 0.10000E+01 0.0000 64 MnOH+ 0.49212E-09 -9.3079 0.41113E-09 -9.3860 0.83542E+00 -0.0781 65 MnO2-2 0.21780E-10 -10.6619 0.11212E-10 -10.9503 0.51478E+00 -0.2884 66 HMnO2- 0.22069E-09 -9.6562 0.18401E-09 -9.7351 0.83380E+00 -0.0789 69 MnCl+ 0.91778E-14 -14.0373 0.76673E-14 -14.1154 0.83542E+00 -0.0781 71 NaCl,aq 0.70010E-06 -6.1548 0.70010E-06 -6.1548 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95144E-02 -2.0216 0.79185E-02 -2.1014 0.83227E+00 -0.0797 79 HPO3-2 0.16782E-14 -14.7751 0.86393E-15 -15.0635 0.51478E+00 -0.2884 81 H2PO3- 0.15418E-18 -18.8120 0.12855E-18 -18.8909 0.83380E+00 -0.0789 82 H3PO4,aq 0.92935E-18 -18.0318 0.92935E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40031E-10 -10.3976 0.33410E-10 -10.4761 0.83460E+00 -0.0785 84 PO4-3 0.12121E-08 -8.9164 0.29003E-09 -9.5376 0.23927E+00 -0.6211 88 HP2O7-3 0.10381E-17 -17.9838 0.23648E-18 -18.6262 0.22781E+00 -0.6424 89 P2O7-4 0.10253E-16 -16.9892 0.77015E-18 -18.1134 0.75115E-01 -1.1243 90 H2S,aq 0.53141E-08 -8.2746 0.52951E-08 -8.2761 0.99642E+00 -0.0016 91 S2-2 0.21269E-14 -14.6723 0.10949E-14 -14.9606 0.51478E+00 -0.2884 97 SO3-2 0.12544E-17 -17.9016 0.65526E-18 -18.1836 0.52239E+00 -0.2820 99 HSO4- 0.37150E-19 -19.4300 0.31066E-19 -19.5077 0.83625E+00 -0.0777 Charge balance for all species = 0.3608E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9029269E-10 -.2312244E-01 -.2326383E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981182E+06 0.0000 3 Cl- 0.1502528E-03 0.1509532E-03 0.5342054E+01 6.2185 4 SO4-- 0.8567515E-12 -.1610601E-04 -.1544368E+01 7.8866 5 HCO3- 0.3090776E-06 0.1429948E-04 0.8709342E+00 3.5324 6 HS- 0.2789832E-04 0.4400965E-04 0.1452852E+01 5.4873 7 Al+++ 0.1101624E-28 0.5277142E-05 0.1421274E+00 0.7610 8 H4SiO4 0.7115819E-03 0.1419492E-01 0.1361880E+04 -3.1478 9 Ca++ 0.1432406E-06 0.2432914E-06 0.9732976E-02 13.1066 10 Mg++ 0.2274527E-10 0.9786128E-10 0.2374895E-05 9.3054 11 Fe++ 0.6221335E-13 0.3791161E-07 0.2113416E-02 6.7429 12 K+ 0.1614794E-03 0.1622559E-03 0.6333043E+01 6.2505 13 Na+ 0.2052971E-01 0.2312093E-01 0.5305832E+03 8.3540 14 Mn++ 0.1980288E-10 0.2614718E-08 0.1433873E-03 9.2461 15 HPO4-- 0.4875575E-07 0.5000793E-07 0.4791020E-02 12.6419 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1390912E+02 -.2113436E-01 -.1388799E+02 0.0000000E+00 2 H2O 0.4497852E+02 0.5073212E+02 -.5753601E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2330474E-01 -.1472121E-04 0.2331946E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2327924E-01 0.4022568E-04 -.2331946E-01 0.0000000E+00 7 Al+++ 0.2739020E+01 0.4823411E-05 0.2739015E+01 0.0000000E+00 8 H4SiO4 0.8746727E+01 0.1297443E-01 0.8733753E+01 0.0000000E+00 9 Ca++ 0.9661331E+00 0.2223730E-06 0.9661329E+00 0.0000000E+00 10 Mg++ 0.6666659E+00 0.8944712E-10 0.6666659E+00 0.0000000E+00 11 Fe++ 0.5989265E+00 0.3465195E-07 0.5989265E+00 0.0000000E+00 12 K+ 0.1783437E+00 0.1483051E-03 0.1781954E+00 0.0000000E+00 13 Na+ 0.1054563E+01 0.2113299E-01 0.1033430E+01 0.0000000E+00 14 Mn++ 0.1456440E-01 0.2389903E-08 0.1456440E-01 0.0000000E+00 15 HPO4-- 0.4970758E-02 0.4570822E-07 0.4970713E-02 0.0000000E+00 Chg. balance for solid moles: 0.5360E-15 Mass of aqueous solution: 0.915677E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 839.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.033 0.014 270.8 2.433 29.51 103.9 andradite 0.9328E-01 -1.030 47.40 1.676 5.166 12.32 grossular 0.2228E-01 -1.652 10.04 1.002 1.094 2.792 apatite-OH 0.1657E-02 -2.781 0.8323 -0.080 0.9071E-01 0.2645 clinochlore 0.1208 -0.918 67.15 1.827 7.319 25.54 daphnite 0.3462E-01 -1.461 24.70 1.393 2.692 7.486 chlorite-Mn 0.2913E-02 -2.536 2.065 0.315 0.2251 0.6581 diopside 0.3910E-01 -1.408 8.467 0.928 0.9228 2.588 hedenbergite 0.1002E-01 -1.999 2.485 0.395 0.2708 0.6806 microcline 0.1561 -0.807 43.44 1.638 4.735 16.97 stilbite 0.5491 -0.260 387.0 2.588 42.17 180.5 stilpnomelane-Fe 0.4423E-01 -1.354 47.68 1.678 5.196 16.47 tr.625ac.25prg.125 0.6488E-02 -2.188 5.546 0.744 0.6044 1.785 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7630E+00 0.7630E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1840E-01 0.1840E-01 1.0000 -1.735 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 917.532610 g Volume = 371.975828 cm3 Porosity: -10.3787% V(tot) - V(min): -.34976E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 839.9990000 g log = 2.9243 Original solution: 1000.0103000 g Original solution / Rock added: 1.19 (Water/Rock Ratio), log = 0.0757 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0882 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9672E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4117E-08 1.0071 0.4512E-08 0.4480E-08 CH4,gas 0.1913E-01 1.0128 0.2108E-01 0.2081E-01 H2,gas 0.1370E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1425E-06 0.9958 0.1544E-06 0.1551E-06 S2,gas 0.3691E-29 1.0000 0.4017E-29 0.4017E-29 CO,gas 0.1602E-13 1.0000 0.1743E-13 0.1743E-13 SO3,gas 0.8714E-48 1.0000 0.9482E-48 0.9482E-48 SO2,gas 0.4916E-27 1.0000 0.5349E-27 0.5349E-27 HCl,gas 0.2896E-17 1.0000 0.3152E-17 0.3152E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.71 -10.35 -3.449 0.17665E+05 -8.346 3 CH4,gas 4.81 1.13 -3.68 -0.919 0.62769E+04 -1.676 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65335E+04 -1.826 5 H2S,gas -5.94 -14.75 -8.81 -4.406 0.15045E+05 -6.811 6 S2,gas -7.03 -38.43 -31.40 -4.830 0.53608E+05 -29.396 7 CO,gas 3.51 -12.25 -15.76 -4.849 0.26908E+05 -13.759 8 SO3,gas 17.43 -32.60 -50.02 -12.506 0.85413E+05 -48.023 9 SO2,gas 1.14 -28.14 -29.27 -7.806 0.49981E+05 -27.272 10 HCl,gas 5.48 -14.02 -19.50 -9.751 0.33298E+05 -17.501 11 acmite 7.74 6.57 -1.17 -0.121 0.19915E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.237 0.80815E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94120E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41193E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28382E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76233E+04 35 aragonite 0.99 -3.60 -4.59 -1.529 0.78347E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55855E+04 37 calcite 0.83 -3.60 -4.44 -1.478 0.75734E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71155E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70323E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82191E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68649E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70375E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65617E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36456E+04 66 diamond -3.11 -7.79 -4.68 -1.337 0.79920E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33650E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66051E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68257E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56968E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.79 -4.24 -1.211 0.72382E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60997E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24442E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64141E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59769E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16000E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22972E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48206E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82332E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61281E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53666E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41166E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36601E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20054E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92766E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40690E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43438E+04 143 pyrrhotite -4.24 -8.01 -3.77 -1.256 0.64329E+04 144 pyrrhotiteFe0.875 -6.00 -9.41 -3.41 -1.253 0.58157E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.264 0.22500E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84880E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28306E+03 152 rhodonite 7.46 6.10 -1.36 -0.273 0.23292E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27393E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.34 -2.77 -0.396 0.47272E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91035E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76031E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65758E+04 181 troilite-low -4.39 -8.01 -3.62 -1.206 0.61761E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80406E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34508E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66776E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60337E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73634E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57935E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83183E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61761E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66247E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52965E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.51 -4.55 -1.515 0.77612E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62641E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18236E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11530E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14892E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18337E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 839.9990000 g New total amount of reactant added: 879.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 879.9990000 Water: Moles liquid = 0.5051E+02 kg liquid = 0.9100E+00 Moles total = 0.4448E+02 kg total = 0.8013E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173982E-01 Osmotic coef. = 0.9689 True ionic strength = .2069285E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90295E-10 -10.0443 0.75752E-10 -10.1206 0.83895E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15092E-03 -3.8213 0.12583E-03 -3.9002 0.83379E+00 -0.0789 4 SO4-- 0.86057E-12 -12.0652 0.44397E-12 -12.3527 0.51590E+00 -0.2874 5 HCO3- 0.31045E-06 -6.5080 0.25924E-06 -6.5863 0.83504E+00 -0.0783 6 HS- 0.28022E-04 -4.5525 0.23368E-04 -4.6314 0.83392E+00 -0.0789 7 Al+++ 0.11017E-28 -28.9579 0.25071E-29 -29.6008 0.22757E+00 -0.6429 8 H4SiO4 0.71159E-03 -3.1478 0.71159E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14325E-06 -6.8439 0.73346E-07 -7.1346 0.51203E+00 -0.2907 10 Mg++ 0.22746E-10 -10.6431 0.11592E-10 -10.9358 0.50964E+00 -0.2927 11 Fe++ 0.62216E-13 -13.2061 0.31743E-13 -13.4983 0.51021E+00 -0.2923 12 K+ 0.16148E-03 -3.7919 0.13488E-03 -3.8701 0.83524E+00 -0.0782 13 Na+ 0.20530E-01 -1.6876 0.17115E-01 -1.7666 0.83364E+00 -0.0790 14 Mn++ 0.19814E-10 -10.7030 0.10118E-10 -10.9949 0.51064E+00 -0.2919 15 HPO4-- 0.48754E-07 -7.3120 0.25156E-07 -7.5994 0.51597E+00 -0.2874 16 HSiO3- 0.10992E-01 -1.9589 0.91650E-02 -2.0379 0.83379E+00 -0.0789 17 Ca(HSiO3)+ 0.18028E-07 -7.7440 0.15061E-07 -7.8221 0.83542E+00 -0.0781 18 Mg(HSiO3)+ 0.35461E-11 -11.4502 0.29625E-11 -11.5283 0.83542E+00 -0.0781 19 NaHSiO3,aq 0.24913E-02 -2.6036 0.24913E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67513E-16 -16.1706 0.56401E-16 -16.2487 0.83542E+00 -0.0781 22 HAlO2,aq 0.14899E-09 -9.8268 0.14899E-09 -9.8268 0.10000E+01 0.0000 23 AlO2- 0.52768E-05 -5.2776 0.43917E-05 -5.3574 0.83227E+00 -0.0797 24 CH4,aq 0.13437E-04 -4.8717 0.13389E-04 -4.8732 0.99642E+00 -0.0016 25 C2H6,aq 0.28537E-14 -14.5446 0.28435E-14 -14.5461 0.99642E+00 -0.0016 29 CO,aq 0.11087E-16 -16.9552 0.11087E-16 -16.9552 0.10000E+01 0.0000 30 CO2,aq 0.39736E-10 -10.4008 0.39594E-10 -10.4024 0.99642E+00 -0.0016 31 CO3-2 0.61466E-06 -6.2114 0.31641E-06 -6.4997 0.51478E+00 -0.2884 32 CaCO3,aq 0.28424E-09 -9.5463 0.28424E-09 -9.5463 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.57349E-12 -12.2415 0.47910E-12 -12.3196 0.83542E+00 -0.0781 34 CaCl+ 0.17604E-10 -10.7544 0.14707E-10 -10.8325 0.83542E+00 -0.0781 35 CaCl2,aq 0.43089E-15 -15.3656 0.43089E-15 -15.3656 0.10000E+01 0.0000 36 CaOH+ 0.81723E-07 -7.0877 0.68273E-07 -7.1658 0.83542E+00 -0.0781 37 CaSO4,aq 0.10146E-16 -16.9937 0.10146E-16 -16.9937 0.10000E+01 0.0000 38 HCl,aq 0.17930E-14 -14.7464 0.17930E-14 -14.7464 0.10000E+01 0.0000 43 FeCl+ 0.74469E-17 -17.1280 0.62213E-17 -17.2061 0.83542E+00 -0.0781 46 FeO,aq 0.21875E-09 -9.6601 0.21875E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16629E-10 -10.7791 0.13892E-10 -10.8572 0.83542E+00 -0.0781 48 HFeO2- 0.37251E-07 -7.4289 0.31060E-07 -7.5078 0.83379E+00 -0.0789 49 FeO+ 0.12272E-16 -16.9111 0.10253E-16 -16.9892 0.83542E+00 -0.0781 51 FeO2- 0.42115E-09 -9.3756 0.35115E-09 -9.4545 0.83379E+00 -0.0789 52 HFeO2,aq 0.33291E-11 -11.4777 0.33291E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10912E-04 -4.9621 0.10873E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.30051E-09 -9.5221 0.30051E-09 -9.5221 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11064E-14 -14.9561 0.92254E-15 -15.0350 0.83379E+00 -0.0789 58 MgCO3,aq 0.11226E-13 -13.9498 0.11226E-13 -13.9498 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.92428E-16 -16.0342 0.77216E-16 -16.1123 0.83542E+00 -0.0781 60 MgCl+ 0.25259E-14 -14.5976 0.21102E-14 -14.6757 0.83542E+00 -0.0781 61 MgOH+ 0.71557E-10 -10.1453 0.59780E-10 -10.2234 0.83542E+00 -0.0781 63 MnO,aq 0.18612E-08 -8.7302 0.18612E-08 -8.7302 0.10000E+01 0.0000 64 MnOH+ 0.49237E-09 -9.3077 0.41134E-09 -9.3858 0.83542E+00 -0.0781 65 MnO2-2 0.21790E-10 -10.6617 0.11217E-10 -10.9501 0.51478E+00 -0.2884 66 HMnO2- 0.22080E-09 -9.6560 0.18410E-09 -9.7349 0.83379E+00 -0.0789 69 MnCl+ 0.92233E-14 -14.0351 0.77054E-14 -14.1132 0.83542E+00 -0.0781 71 NaCl,aq 0.70320E-06 -6.1529 0.70320E-06 -6.1529 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95142E-02 -2.0216 0.79184E-02 -2.1014 0.83227E+00 -0.0797 79 HPO3-2 0.16782E-14 -14.7752 0.86389E-15 -15.0635 0.51478E+00 -0.2884 81 H2PO3- 0.15417E-18 -18.8120 0.12855E-18 -18.8909 0.83379E+00 -0.0789 82 H3PO4,aq 0.92936E-18 -18.0318 0.92936E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40031E-10 -10.3976 0.33410E-10 -10.4761 0.83460E+00 -0.0785 84 PO4-3 0.12121E-08 -8.9165 0.29001E-09 -9.5376 0.23926E+00 -0.6211 88 HP2O7-3 0.10380E-17 -17.9838 0.23647E-18 -18.6262 0.22781E+00 -0.6424 89 P2O7-4 0.10253E-16 -16.9892 0.77010E-18 -18.1135 0.75113E-01 -1.1243 90 H2S,aq 0.53377E-08 -8.2726 0.53186E-08 -8.2742 0.99642E+00 -0.0016 91 S2-2 0.21457E-14 -14.6684 0.11046E-14 -14.9568 0.51478E+00 -0.2884 97 SO3-2 0.12599E-17 -17.8997 0.65816E-18 -18.1817 0.52238E+00 -0.2820 99 HSO4- 0.37316E-19 -19.4281 0.31205E-19 -19.5058 0.83625E+00 -0.0777 Charge balance for all species = 0.3624E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9029470E-10 -.2312212E-01 -.2326352E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981182E+06 0.0000 3 Cl- 0.1509163E-03 0.1516198E-03 0.5365645E+01 6.2204 4 SO4-- 0.8605683E-12 -.1616503E-04 -.1550027E+01 7.8886 5 HCO3- 0.3104531E-06 0.1436262E-04 0.8747803E+00 3.5343 6 HS- 0.2802153E-04 0.4419190E-04 0.1458868E+01 5.4892 7 Al+++ 0.1101689E-28 0.5276946E-05 0.1421221E+00 0.7610 8 H4SiO4 0.7115861E-03 0.1419479E-01 0.1361868E+04 -3.1478 9 Ca++ 0.1432465E-06 0.2433004E-06 0.9733338E-02 13.1066 10 Mg++ 0.2274621E-10 0.9786339E-10 0.2374947E-05 9.3054 11 Fe++ 0.6221618E-13 0.3791079E-07 0.2113370E-02 6.7429 12 K+ 0.1614830E-03 0.1622595E-03 0.6333184E+01 6.2505 13 Na+ 0.2053017E-01 0.2312141E-01 0.5305941E+03 8.3540 14 Mn++ 0.1981372E-10 0.2616031E-08 0.1434593E-03 9.2463 15 HPO4-- 0.4875450E-07 0.5000663E-07 0.4790895E-02 12.6418 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1457146E+02 -.2104115E-01 -.1455042E+02 0.0000000E+00 2 H2O 0.4447710E+02 0.5050906E+02 -.6031963E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2441328E-01 -.1471019E-04 0.2442799E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2438777E-01 0.4021466E-04 -.2442799E-01 0.0000000E+00 7 Al+++ 0.2869449E+01 0.4802026E-05 0.2869445E+01 0.0000000E+00 8 H4SiO4 0.9163239E+01 0.1291727E-01 0.9150321E+01 0.0000000E+00 9 Ca++ 0.1012139E+01 0.2214036E-06 0.1012139E+01 0.0000000E+00 10 Mg++ 0.6984119E+00 0.8905576E-10 0.6984119E+00 0.0000000E+00 11 Fe++ 0.6274468E+00 0.3449885E-07 0.6274468E+00 0.0000000E+00 12 K+ 0.1868363E+00 0.1476563E-03 0.1866886E+00 0.0000000E+00 13 Na+ 0.1104773E+01 0.2104050E-01 0.1083733E+01 0.0000000E+00 14 Mn++ 0.1525795E-01 0.2380591E-08 0.1525794E-01 0.0000000E+00 15 HPO4-- 0.5207462E-02 0.4550607E-07 0.5207416E-02 0.0000000E+00 Chg. balance for solid moles: 0.1273E-14 Mass of aqueous solution: 0.911652E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 879.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.083 0.035 284.0 2.453 29.54 109.0 andradite 0.9771E-01 -1.010 49.66 1.696 5.166 12.90 grossular 0.2334E-01 -1.632 10.51 1.022 1.094 2.925 apatite-OH 0.1736E-02 -2.760 0.8719 -0.060 0.9071E-01 0.2771 clinochlore 0.1265 -0.898 70.31 1.847 7.315 26.74 daphnite 0.3625E-01 -1.441 25.87 1.413 2.691 7.838 chlorite-Mn 0.3052E-02 -2.515 2.163 0.335 0.2251 0.6894 diopside 0.4141E-01 -1.383 8.968 0.953 0.9329 2.741 hedenbergite 0.1061E-01 -1.974 2.632 0.420 0.2738 0.7209 microcline 0.1635 -0.786 45.51 1.658 4.735 17.78 stilbite 0.5748 -0.241 405.1 2.608 42.14 188.9 stilpnomelane-Fe 0.4634E-01 -1.334 49.95 1.699 5.197 17.26 tr.625ac.25prg.125 0.6761E-02 -2.170 5.779 0.762 0.6012 1.860 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1840E-01 0.1840E-01 1.0000 -1.735 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 961.234800 g Volume = 389.658371 cm3 Porosity: -10.3849% V(tot) - V(min): -.36659E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 879.9990000 g log = 2.9445 Original solution: 1000.0103000 g Original solution / Rock added: 1.14 (Water/Rock Ratio), log = 0.0555 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0883 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9671E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4135E-08 1.0071 0.4532E-08 0.4500E-08 CH4,gas 0.1921E-01 1.0128 0.2117E-01 0.2091E-01 H2,gas 0.1370E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1431E-06 0.9958 0.1551E-06 0.1558E-06 S2,gas 0.3724E-29 1.0000 0.4053E-29 0.4053E-29 CO,gas 0.1609E-13 1.0000 0.1751E-13 0.1751E-13 SO3,gas 0.8752E-48 1.0000 0.9525E-48 0.9525E-48 SO2,gas 0.4937E-27 1.0000 0.5373E-27 0.5373E-27 HCl,gas 0.2909E-17 1.0000 0.3166E-17 0.3166E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.60662E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.66728E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.60662E-10 67 diopside 16.22 16.22 0.00 0.000 -0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 -0.15165E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.71 -10.34 -3.448 0.17662E+05 -8.344 3 CH4,gas 4.81 1.13 -3.67 -0.919 0.62736E+04 -1.674 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.75 -8.81 -4.405 0.15042E+05 -6.809 6 S2,gas -7.03 -38.42 -31.39 -4.830 0.53601E+05 -29.392 7 CO,gas 3.51 -12.25 -15.76 -4.848 0.26904E+05 -13.757 8 SO3,gas 17.43 -32.59 -50.02 -12.505 0.85410E+05 -48.021 9 SO2,gas 1.14 -28.13 -29.27 -7.805 0.49977E+05 -27.270 10 HCl,gas 5.48 -14.02 -19.50 -9.750 0.33295E+05 -17.500 11 acmite 7.74 6.57 -1.17 -0.121 0.19915E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.237 0.80804E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94120E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28382E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76233E+04 35 aragonite 0.99 -3.60 -4.59 -1.529 0.78314E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55855E+04 37 calcite 0.83 -3.60 -4.43 -1.478 0.75701E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71155E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70324E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82191E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68649E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70376E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65614E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36456E+04 66 diamond -3.11 -7.79 -4.68 -1.337 0.79887E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33650E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66051E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56968E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.79 -4.24 -1.211 0.72349E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60997E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24442E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64141E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59769E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16000E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22972E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48206E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82329E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61282E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53666E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41166E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36601E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20054E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92766E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40690E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43439E+04 143 pyrrhotite -4.24 -8.01 -3.77 -1.255 0.64296E+04 144 pyrrhotiteFe0.875 -6.00 -9.41 -3.40 -1.252 0.58124E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.264 0.22496E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84880E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28305E+03 152 rhodonite 7.46 6.10 -1.36 -0.273 0.23289E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27393E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.34 -2.77 -0.395 0.47265E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91035E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76031E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65758E+04 181 troilite-low -4.39 -8.01 -3.62 -1.205 0.61728E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80408E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34509E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66776E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60337E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73634E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57935E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83182E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61761E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66247E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52965E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.51 -4.54 -1.514 0.77576E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62641E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18236E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11530E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14892E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18337E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 879.9990000 g New total amount of reactant added: 919.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 919.9990000 Water: Moles liquid = 0.5029E+02 kg liquid = 0.9060E+00 Moles total = 0.4398E+02 kg total = 0.7922E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174040E-01 Osmotic coef. = 0.9689 True ionic strength = .2069332E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90297E-10 -10.0443 0.75754E-10 -10.1206 0.83895E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15159E-03 -3.8193 0.12639E-03 -3.8983 0.83379E+00 -0.0789 4 SO4-- 0.86441E-12 -12.0633 0.44595E-12 -12.3507 0.51590E+00 -0.2874 5 HCO3- 0.31184E-06 -6.5061 0.26040E-06 -6.5844 0.83504E+00 -0.0783 6 HS- 0.28146E-04 -4.5506 0.23471E-04 -4.6295 0.83392E+00 -0.0789 7 Al+++ 0.11018E-28 -28.9579 0.25072E-29 -29.6008 0.22756E+00 -0.6429 8 H4SiO4 0.71159E-03 -3.1478 0.71159E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14325E-06 -6.8439 0.73349E-07 -7.1346 0.51203E+00 -0.2907 10 Mg++ 0.22747E-10 -10.6431 0.11593E-10 -10.9358 0.50964E+00 -0.2927 11 Fe++ 0.62219E-13 -13.2061 0.31744E-13 -13.4983 0.51021E+00 -0.2923 12 K+ 0.16149E-03 -3.7919 0.13488E-03 -3.8701 0.83524E+00 -0.0782 13 Na+ 0.20531E-01 -1.6876 0.17115E-01 -1.7666 0.83364E+00 -0.0790 14 Mn++ 0.19824E-10 -10.7028 0.10123E-10 -10.9947 0.51064E+00 -0.2919 15 HPO4-- 0.48753E-07 -7.3120 0.25155E-07 -7.5994 0.51597E+00 -0.2874 16 HSiO3- 0.10992E-01 -1.9589 0.91649E-02 -2.0379 0.83379E+00 -0.0789 17 Ca(HSiO3)+ 0.18029E-07 -7.7440 0.15062E-07 -7.8221 0.83542E+00 -0.0781 18 Mg(HSiO3)+ 0.35462E-11 -11.4502 0.29625E-11 -11.5283 0.83542E+00 -0.0781 19 NaHSiO3,aq 0.24913E-02 -2.6036 0.24913E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67513E-16 -16.1706 0.56402E-16 -16.2487 0.83542E+00 -0.0781 22 HAlO2,aq 0.14899E-09 -9.8268 0.14899E-09 -9.8268 0.10000E+01 0.0000 23 AlO2- 0.52766E-05 -5.2776 0.43915E-05 -5.3574 0.83226E+00 -0.0797 24 CH4,aq 0.13497E-04 -4.8698 0.13448E-04 -4.8713 0.99642E+00 -0.0016 25 C2H6,aq 0.28791E-14 -14.5407 0.28688E-14 -14.5423 0.99642E+00 -0.0016 29 CO,aq 0.11137E-16 -16.9532 0.11137E-16 -16.9532 0.10000E+01 0.0000 30 CO2,aq 0.39915E-10 -10.3989 0.39772E-10 -10.4004 0.99642E+00 -0.0016 31 CO3-2 0.61739E-06 -6.2094 0.31782E-06 -6.4978 0.51478E+00 -0.2884 32 CaCO3,aq 0.28551E-09 -9.5444 0.28551E-09 -9.5444 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.57607E-12 -12.2395 0.48126E-12 -12.3176 0.83542E+00 -0.0781 34 CaCl+ 0.17683E-10 -10.7524 0.14773E-10 -10.8305 0.83542E+00 -0.0781 35 CaCl2,aq 0.43474E-15 -15.3618 0.43474E-15 -15.3618 0.10000E+01 0.0000 36 CaOH+ 0.81724E-07 -7.0876 0.68274E-07 -7.1657 0.83542E+00 -0.0781 37 CaSO4,aq 0.10192E-16 -16.9918 0.10192E-16 -16.9918 0.10000E+01 0.0000 38 HCl,aq 0.18010E-14 -14.7445 0.18010E-14 -14.7445 0.10000E+01 0.0000 43 FeCl+ 0.74802E-17 -17.1261 0.62491E-17 -17.2042 0.83542E+00 -0.0781 46 FeO,aq 0.21875E-09 -9.6601 0.21875E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16629E-10 -10.7791 0.13892E-10 -10.8572 0.83542E+00 -0.0781 48 HFeO2- 0.37250E-07 -7.4289 0.31059E-07 -7.5078 0.83379E+00 -0.0789 49 FeO+ 0.12273E-16 -16.9111 0.10253E-16 -16.9892 0.83542E+00 -0.0781 51 FeO2- 0.42114E-09 -9.3756 0.35115E-09 -9.4545 0.83379E+00 -0.0789 52 HFeO2,aq 0.33291E-11 -11.4777 0.33291E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10872E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.30185E-09 -9.5202 0.30185E-09 -9.5202 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11114E-14 -14.9541 0.92668E-15 -15.0331 0.83379E+00 -0.0789 58 MgCO3,aq 0.11276E-13 -13.9478 0.11276E-13 -13.9478 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.92844E-16 -16.0322 0.77564E-16 -16.1103 0.83542E+00 -0.0781 60 MgCl+ 0.25372E-14 -14.5956 0.21196E-14 -14.6737 0.83542E+00 -0.0781 61 MgOH+ 0.71558E-10 -10.1453 0.59781E-10 -10.2234 0.83542E+00 -0.0781 63 MnO,aq 0.18621E-08 -8.7300 0.18621E-08 -8.7300 0.10000E+01 0.0000 64 MnOH+ 0.49261E-09 -9.3075 0.41154E-09 -9.3856 0.83542E+00 -0.0781 65 MnO2-2 0.21799E-10 -10.6616 0.11222E-10 -10.9499 0.51478E+00 -0.2884 66 HMnO2- 0.22090E-09 -9.6558 0.18418E-09 -9.7348 0.83379E+00 -0.0789 69 MnCl+ 0.92689E-14 -14.0330 0.77434E-14 -14.1111 0.83542E+00 -0.0781 71 NaCl,aq 0.70634E-06 -6.1510 0.70634E-06 -6.1510 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95140E-02 -2.0216 0.79182E-02 -2.1014 0.83226E+00 -0.0797 79 HPO3-2 0.16781E-14 -14.7752 0.86386E-15 -15.0636 0.51478E+00 -0.2884 81 H2PO3- 0.15417E-18 -18.8120 0.12855E-18 -18.8909 0.83379E+00 -0.0789 82 H3PO4,aq 0.92937E-18 -18.0318 0.92937E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40030E-10 -10.3976 0.33409E-10 -10.4761 0.83460E+00 -0.0785 84 PO4-3 0.12120E-08 -8.9165 0.29000E-09 -9.5376 0.23926E+00 -0.6211 88 HP2O7-3 0.10380E-17 -17.9838 0.23646E-18 -18.6262 0.22781E+00 -0.6424 89 P2O7-4 0.10252E-16 -16.9892 0.77005E-18 -18.1135 0.75112E-01 -1.1243 90 H2S,aq 0.53614E-08 -8.2707 0.53422E-08 -8.2723 0.99642E+00 -0.0016 91 S2-2 0.21648E-14 -14.6646 0.11144E-14 -14.9530 0.51478E+00 -0.2884 97 SO3-2 0.12655E-17 -17.8977 0.66109E-18 -18.1797 0.52238E+00 -0.2820 99 HSO4- 0.37483E-19 -19.4262 0.31345E-19 -19.5038 0.83625E+00 -0.0777 Charge balance for all species = 0.3640E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9029672E-10 -.2312180E-01 -.2326319E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981181E+06 0.0000 3 Cl- 0.1515857E-03 0.1522924E-03 0.5389445E+01 6.2223 4 SO4-- 0.8644148E-12 -.1622458E-04 -.1555737E+01 7.8905 5 HCO3- 0.3118394E-06 0.1442633E-04 0.8786606E+00 3.5362 6 HS- 0.2814582E-04 0.4437577E-04 0.1464938E+01 5.4911 7 Al+++ 0.1101755E-28 0.5276758E-05 0.1421171E+00 0.7610 8 H4SiO4 0.7115900E-03 0.1419465E-01 0.1361855E+04 -3.1478 9 Ca++ 0.1432526E-06 0.2433096E-06 0.9733705E-02 13.1066 10 Mg++ 0.2274716E-10 0.9786552E-10 0.2374998E-05 9.3054 11 Fe++ 0.6221902E-13 0.3790998E-07 0.2113325E-02 6.7429 12 K+ 0.1614866E-03 0.1622631E-03 0.6333324E+01 6.2505 13 Na+ 0.2053063E-01 0.2312189E-01 0.5306050E+03 8.3540 14 Mn++ 0.1982371E-10 0.2617232E-08 0.1435251E-03 9.2465 15 HPO4-- 0.4875320E-07 0.5000528E-07 0.4790766E-02 12.6418 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1523380E+02 -.2094794E-01 -.1521286E+02 0.0000000E+00 2 H2O 0.4397569E+02 0.5028601E+02 -.6310325E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2552181E-01 -.1469918E-04 0.2553651E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2549631E-01 0.4020365E-04 -.2553651E-01 0.0000000E+00 7 Al+++ 0.2999879E+01 0.4780649E-05 0.2999874E+01 0.0000000E+00 8 H4SiO4 0.9579750E+01 0.1286010E-01 0.9566890E+01 0.0000000E+00 9 Ca++ 0.1058145E+01 0.2204342E-06 0.1058144E+01 0.0000000E+00 10 Mg++ 0.7301579E+00 0.8866441E-10 0.7301579E+00 0.0000000E+00 11 Fe++ 0.6559672E+00 0.3434577E-07 0.6559672E+00 0.0000000E+00 12 K+ 0.1953289E+00 0.1470075E-03 0.1951819E+00 0.0000000E+00 13 Na+ 0.1154983E+01 0.2094802E-01 0.1134035E+01 0.0000000E+00 14 Mn++ 0.1595149E-01 0.2371165E-08 0.1595149E-01 0.0000000E+00 15 HPO4-- 0.5444165E-02 0.4530389E-07 0.5444119E-02 0.0000000E+00 Chg. balance for solid moles: -.1651E-14 Mass of aqueous solution: 0.907626E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 919.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.133 0.054 297.1 2.473 29.57 114.1 andradite 0.1021 -0.991 51.91 1.715 5.165 13.49 grossular 0.2440E-01 -1.613 10.99 1.041 1.094 3.058 apatite-OH 0.1815E-02 -2.741 0.9116 -0.040 0.9071E-01 0.2897 clinochlore 0.1322 -0.879 73.47 1.866 7.311 27.95 daphnite 0.3788E-01 -1.422 27.03 1.432 2.690 8.191 chlorite-Mn 0.3190E-02 -2.496 2.262 0.354 0.2251 0.7208 diopside 0.4372E-01 -1.359 9.469 0.976 0.9422 2.894 hedenbergite 0.1120E-01 -1.951 2.779 0.444 0.2765 0.7611 microcline 0.1710 -0.767 47.58 1.677 4.735 18.59 stilbite 0.6005 -0.222 423.2 2.626 42.11 197.4 stilpnomelane-Fe 0.4845E-01 -1.315 52.23 1.718 5.198 18.04 tr.625ac.25prg.125 0.7033E-02 -2.153 6.012 0.779 0.5982 1.935 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1841E-01 0.1841E-01 1.0000 -1.735 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1004.936990 g Volume = 407.340914 cm3 Porosity: -10.3906% V(tot) - V(min): -.38341E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 919.9990000 g log = 2.9638 Original solution: 1000.0103000 g Original solution / Rock added: 1.09 (Water/Rock Ratio), log = 0.0362 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0884 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9670E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4153E-08 1.0071 0.4553E-08 0.4520E-08 CH4,gas 0.1929E-01 1.0128 0.2127E-01 0.2100E-01 H2,gas 0.1369E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1438E-06 0.9958 0.1558E-06 0.1565E-06 S2,gas 0.3757E-29 1.0000 0.4089E-29 0.4089E-29 CO,gas 0.1616E-13 1.0000 0.1759E-13 0.1759E-13 SO3,gas 0.8791E-48 1.0000 0.9567E-48 0.9567E-48 SO2,gas 0.4959E-27 1.0000 0.5397E-27 0.5397E-27 HCl,gas 0.2922E-17 1.0000 0.3180E-17 0.3180E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.60662E-10 47 daphnite 29.09 29.09 0.00 0.000 0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.70 -10.34 -3.447 0.17658E+05 -8.342 3 CH4,gas 4.81 1.14 -3.67 -0.918 0.62703E+04 -1.672 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.75 -8.81 -4.404 0.15038E+05 -6.807 6 S2,gas -7.03 -38.42 -31.39 -4.829 0.53595E+05 -29.388 7 CO,gas 3.51 -12.24 -15.75 -4.848 0.26901E+05 -13.755 8 SO3,gas 17.43 -32.59 -50.02 -12.505 0.85406E+05 -48.019 9 SO2,gas 1.14 -28.13 -29.27 -7.805 0.49974E+05 -27.268 10 HCl,gas 5.48 -14.02 -19.50 -9.749 0.33292E+05 -17.498 11 acmite 7.74 6.57 -1.17 -0.121 0.19915E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.237 0.80794E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94121E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28383E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76233E+04 35 aragonite 0.99 -3.60 -4.58 -1.528 0.78281E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55855E+04 37 calcite 0.83 -3.60 -4.43 -1.477 0.75667E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71155E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70324E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82191E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68649E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70376E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65610E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36456E+04 66 diamond -3.11 -7.78 -4.68 -1.336 0.79854E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33650E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66051E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56968E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.78 -4.24 -1.210 0.72316E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60997E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24442E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64141E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59769E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16001E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22972E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48206E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82325E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61282E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53667E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41166E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36602E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20055E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92767E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40691E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43439E+04 143 pyrrhotite -4.24 -8.01 -3.76 -1.255 0.64263E+04 144 pyrrhotiteFe0.875 -6.00 -9.40 -3.40 -1.251 0.58091E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22493E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84880E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28305E+03 152 rhodonite 7.46 6.10 -1.36 -0.273 0.23285E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27393E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.77 -0.395 0.47258E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91034E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76031E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65758E+04 181 troilite-low -4.39 -8.01 -3.61 -1.204 0.61695E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80409E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34509E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66777E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60337E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73634E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57934E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83182E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61760E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66246E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52965E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.50 -4.54 -1.514 0.77539E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62641E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18236E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14892E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18337E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 919.9990000 g New total amount of reactant added: 959.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 959.9990000 Water: Moles liquid = 0.5007E+02 kg liquid = 0.9020E+00 Moles total = 0.4347E+02 kg total = 0.7832E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174098E-01 Osmotic coef. = 0.9689 True ionic strength = .2069378E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90299E-10 -10.0443 0.75756E-10 -10.1206 0.83894E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15226E-03 -3.8174 0.12695E-03 -3.8964 0.83379E+00 -0.0789 4 SO4-- 0.86829E-12 -12.0613 0.44795E-12 -12.3488 0.51589E+00 -0.2874 5 HCO3- 0.31324E-06 -6.5041 0.26156E-06 -6.5824 0.83503E+00 -0.0783 6 HS- 0.28271E-04 -4.5487 0.23576E-04 -4.6275 0.83392E+00 -0.0789 7 Al+++ 0.11018E-28 -28.9579 0.25073E-29 -29.6008 0.22756E+00 -0.6429 8 H4SiO4 0.71159E-03 -3.1478 0.71159E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14326E-06 -6.8439 0.73352E-07 -7.1346 0.51202E+00 -0.2907 10 Mg++ 0.22748E-10 -10.6431 0.11593E-10 -10.9358 0.50963E+00 -0.2927 11 Fe++ 0.62222E-13 -13.2061 0.31746E-13 -13.4983 0.51020E+00 -0.2923 12 K+ 0.16149E-03 -3.7919 0.13488E-03 -3.8700 0.83523E+00 -0.0782 13 Na+ 0.20531E-01 -1.6876 0.17115E-01 -1.7666 0.83363E+00 -0.0790 14 Mn++ 0.19833E-10 -10.7026 0.10127E-10 -10.9945 0.51063E+00 -0.2919 15 HPO4-- 0.48752E-07 -7.3120 0.25154E-07 -7.5994 0.51597E+00 -0.2874 16 HSiO3- 0.10992E-01 -1.9589 0.91647E-02 -2.0379 0.83379E+00 -0.0789 17 Ca(HSiO3)+ 0.18029E-07 -7.7440 0.15062E-07 -7.8221 0.83542E+00 -0.0781 18 Mg(HSiO3)+ 0.35462E-11 -11.4502 0.29626E-11 -11.5283 0.83542E+00 -0.0781 19 NaHSiO3,aq 0.24913E-02 -2.6036 0.24913E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67514E-16 -16.1706 0.56402E-16 -16.2487 0.83542E+00 -0.0781 22 HAlO2,aq 0.14899E-09 -9.8269 0.14899E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52764E-05 -5.2777 0.43914E-05 -5.3574 0.83226E+00 -0.0797 24 CH4,aq 0.13557E-04 -4.8678 0.13508E-04 -4.8694 0.99642E+00 -0.0016 25 C2H6,aq 0.29048E-14 -14.5369 0.28944E-14 -14.5384 0.99642E+00 -0.0016 29 CO,aq 0.11187E-16 -16.9513 0.11187E-16 -16.9513 0.10000E+01 0.0000 30 CO2,aq 0.40094E-10 -10.3969 0.39951E-10 -10.3985 0.99642E+00 -0.0016 31 CO3-2 0.62015E-06 -6.2075 0.31924E-06 -6.4959 0.51477E+00 -0.2884 32 CaCO3,aq 0.28680E-09 -9.5424 0.28680E-09 -9.5424 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.57867E-12 -12.2376 0.48343E-12 -12.3157 0.83542E+00 -0.0781 34 CaCl+ 0.17762E-10 -10.7505 0.14839E-10 -10.8286 0.83542E+00 -0.0781 35 CaCl2,aq 0.43864E-15 -15.3579 0.43864E-15 -15.3579 0.10000E+01 0.0000 36 CaOH+ 0.81726E-07 -7.0876 0.68275E-07 -7.1657 0.83542E+00 -0.0781 37 CaSO4,aq 0.10238E-16 -16.9898 0.10238E-16 -16.9898 0.10000E+01 0.0000 38 HCl,aq 0.18090E-14 -14.7426 0.18090E-14 -14.7426 0.10000E+01 0.0000 43 FeCl+ 0.75138E-17 -17.1241 0.62772E-17 -17.2022 0.83542E+00 -0.0781 46 FeO,aq 0.21875E-09 -9.6601 0.21875E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16630E-10 -10.7791 0.13893E-10 -10.8572 0.83542E+00 -0.0781 48 HFeO2- 0.37249E-07 -7.4289 0.31058E-07 -7.5078 0.83379E+00 -0.0789 49 FeO+ 0.12273E-16 -16.9110 0.10253E-16 -16.9891 0.83542E+00 -0.0781 51 FeO2- 0.42114E-09 -9.3756 0.35114E-09 -9.4545 0.83379E+00 -0.0789 52 HFeO2,aq 0.33291E-11 -11.4777 0.33291E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10872E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.30320E-09 -9.5183 0.30320E-09 -9.5183 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11164E-14 -14.9522 0.93085E-15 -15.0311 0.83379E+00 -0.0789 58 MgCO3,aq 0.11327E-13 -13.9459 0.11327E-13 -13.9459 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.93264E-16 -16.0303 0.77914E-16 -16.1084 0.83542E+00 -0.0781 60 MgCl+ 0.25486E-14 -14.5937 0.21291E-14 -14.6718 0.83542E+00 -0.0781 61 MgOH+ 0.71560E-10 -10.1453 0.59782E-10 -10.2234 0.83542E+00 -0.0781 63 MnO,aq 0.18629E-08 -8.7298 0.18629E-08 -8.7298 0.10000E+01 0.0000 64 MnOH+ 0.49283E-09 -9.3073 0.41172E-09 -9.3854 0.83542E+00 -0.0781 65 MnO2-2 0.21807E-10 -10.6614 0.11226E-10 -10.9498 0.51477E+00 -0.2884 66 HMnO2- 0.22098E-09 -9.6556 0.18426E-09 -9.7346 0.83379E+00 -0.0789 69 MnCl+ 0.93145E-14 -14.0308 0.77815E-14 -14.1089 0.83542E+00 -0.0781 71 NaCl,aq 0.70950E-06 -6.1490 0.70950E-06 -6.1490 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95139E-02 -2.0216 0.79180E-02 -2.1014 0.83226E+00 -0.0797 79 HPO3-2 0.16780E-14 -14.7752 0.86382E-15 -15.0636 0.51477E+00 -0.2884 81 H2PO3- 0.15417E-18 -18.8120 0.12854E-18 -18.8909 0.83379E+00 -0.0789 82 H3PO4,aq 0.92937E-18 -18.0318 0.92937E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40030E-10 -10.3976 0.33409E-10 -10.4761 0.83460E+00 -0.0785 84 PO4-3 0.12120E-08 -8.9165 0.28998E-09 -9.5376 0.23926E+00 -0.6211 88 HP2O7-3 0.10380E-17 -17.9838 0.23645E-18 -18.6263 0.22780E+00 -0.6424 89 P2O7-4 0.10252E-16 -16.9892 0.77000E-18 -18.1135 0.75110E-01 -1.1243 90 H2S,aq 0.53854E-08 -8.2688 0.53662E-08 -8.2703 0.99642E+00 -0.0016 91 S2-2 0.21842E-14 -14.6607 0.11244E-14 -14.9491 0.51477E+00 -0.2884 97 SO3-2 0.12712E-17 -17.8958 0.66405E-18 -18.1778 0.52238E+00 -0.2820 99 HSO4- 0.37652E-19 -19.4242 0.31486E-19 -19.5019 0.83625E+00 -0.0777 Charge balance for all species = 0.3656E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9029874E-10 -.2312147E-01 -.2326286E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981181E+06 0.0000 3 Cl- 0.1522611E-03 0.1529709E-03 0.5413458E+01 6.2242 4 SO4-- 0.8682920E-12 -.1628467E-04 -.1561499E+01 7.8924 5 HCO3- 0.3132368E-06 0.1449061E-04 0.8825754E+00 3.5382 6 HS- 0.2827123E-04 0.4456129E-04 0.1471062E+01 5.4931 7 Al+++ 0.1101823E-28 0.5276577E-05 0.1421122E+00 0.7610 8 H4SiO4 0.7115936E-03 0.1419451E-01 0.1361841E+04 -3.1478 9 Ca++ 0.1432587E-06 0.2433189E-06 0.9734078E-02 13.1066 10 Mg++ 0.2274812E-10 0.9786803E-10 0.2375059E-05 9.3054 11 Fe++ 0.6222189E-13 0.3790918E-07 0.2113280E-02 6.7429 12 K+ 0.1614902E-03 0.1622667E-03 0.6333465E+01 6.2505 13 Na+ 0.2053109E-01 0.2312236E-01 0.5306159E+03 8.3540 14 Mn++ 0.1983296E-10 0.2618334E-08 0.1435856E-03 9.2467 15 HPO4-- 0.4875186E-07 0.5000389E-07 0.4790633E-02 12.6418 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1589615E+02 -.2085472E-01 -.1587529E+02 0.0000000E+00 2 H2O 0.4347427E+02 0.5006296E+02 -.6588686E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2663035E-01 -.1468818E-04 0.2664504E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2660484E-01 0.4019265E-04 -.2664504E-01 0.0000000E+00 7 Al+++ 0.3130309E+01 0.4759280E-05 0.3130304E+01 0.0000000E+00 8 H4SiO4 0.9996261E+01 0.1280293E-01 0.9983458E+01 0.0000000E+00 9 Ca++ 0.1104150E+01 0.2194648E-06 0.1104150E+01 0.0000000E+00 10 Mg++ 0.7619040E+00 0.8827339E-10 0.7619040E+00 0.0000000E+00 11 Fe++ 0.6844875E+00 0.3419269E-07 0.6844875E+00 0.0000000E+00 12 K+ 0.2038214E+00 0.1463587E-03 0.2036751E+00 0.0000000E+00 13 Na+ 0.1205193E+01 0.2085553E-01 0.1184337E+01 0.0000000E+00 14 Mn++ 0.1664503E-01 0.2361642E-08 0.1664503E-01 0.0000000E+00 15 HPO4-- 0.5680868E-02 0.4510168E-07 0.5680823E-02 0.0000000E+00 Chg. balance for solid moles: -.9714E-16 Mass of aqueous solution: 0.903600E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 959.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.183 0.073 310.3 2.492 29.59 119.1 andradite 0.1066 -0.972 54.16 1.734 5.165 14.07 grossular 0.2546E-01 -1.594 11.47 1.059 1.093 3.190 apatite-OH 0.1894E-02 -2.723 0.9512 -0.022 0.9071E-01 0.3023 clinochlore 0.1379 -0.861 76.64 1.884 7.308 29.15 daphnite 0.3951E-01 -1.403 28.19 1.450 2.689 8.543 chlorite-Mn 0.3329E-02 -2.478 2.360 0.373 0.2251 0.7521 diopside 0.4604E-01 -1.337 9.970 0.999 0.9507 3.047 hedenbergite 0.1179E-01 -1.928 2.926 0.466 0.2790 0.8014 microcline 0.1784 -0.749 49.65 1.696 4.735 19.40 stilbite 0.6261 -0.203 441.2 2.645 42.08 205.8 stilpnomelane-Fe 0.5057E-01 -1.296 54.51 1.736 5.198 18.83 tr.625ac.25prg.125 0.7306E-02 -2.136 6.245 0.796 0.5955 2.010 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1842E-01 0.1842E-01 1.0000 -1.735 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1048.639180 g Volume = 425.023456 cm3 Porosity: -10.3958% V(tot) - V(min): -.40024E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 959.9990000 g log = 2.9823 Original solution: 1000.0103000 g Original solution / Rock added: 1.04 (Water/Rock Ratio), log = 0.0177 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0885 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9669E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4172E-08 1.0071 0.4573E-08 0.4541E-08 CH4,gas 0.1938E-01 1.0128 0.2136E-01 0.2109E-01 H2,gas 0.1369E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1444E-06 0.9958 0.1565E-06 0.1572E-06 S2,gas 0.3790E-29 1.0000 0.4126E-29 0.4126E-29 CO,gas 0.1623E-13 1.0000 0.1766E-13 0.1766E-13 SO3,gas 0.8830E-48 1.0000 0.9611E-48 0.9611E-48 SO2,gas 0.4981E-27 1.0000 0.5422E-27 0.5422E-27 HCl,gas 0.2935E-17 1.0000 0.3194E-17 0.3194E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.70 -10.34 -3.447 0.17655E+05 -8.340 3 CH4,gas 4.81 1.14 -3.67 -0.918 0.62670E+04 -1.670 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.75 -8.81 -4.403 0.15035E+05 -6.805 6 S2,gas -7.03 -38.42 -31.38 -4.828 0.53588E+05 -29.385 7 CO,gas 3.51 -12.24 -15.75 -4.847 0.26898E+05 -13.753 8 SO3,gas 17.43 -32.59 -50.02 -12.504 0.85403E+05 -48.017 9 SO2,gas 1.14 -28.13 -29.27 -7.804 0.49971E+05 -27.266 10 HCl,gas 5.48 -14.02 -19.50 -9.748 0.33288E+05 -17.496 11 acmite 7.74 6.57 -1.17 -0.121 0.19915E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.237 0.80785E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94121E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28383E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76233E+04 35 aragonite 0.99 -3.60 -4.58 -1.528 0.78247E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55855E+04 37 calcite 0.83 -3.60 -4.43 -1.477 0.75634E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71155E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70324E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82191E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68649E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70376E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65607E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36457E+04 66 diamond -3.11 -7.78 -4.67 -1.336 0.79821E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33650E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66052E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56968E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.78 -4.23 -1.210 0.72283E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60997E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24442E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64141E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59769E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16001E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22972E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48206E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82322E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61282E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53667E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41166E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36602E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20055E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92767E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40691E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43440E+04 143 pyrrhotite -4.24 -8.01 -3.76 -1.254 0.64230E+04 144 pyrrhotiteFe0.875 -6.00 -9.40 -3.40 -1.251 0.58058E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22490E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84880E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28305E+03 152 rhodonite 7.46 6.10 -1.36 -0.273 0.23282E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27393E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.77 -0.395 0.47251E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91034E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76031E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65758E+04 181 troilite-low -4.39 -8.01 -3.61 -1.204 0.61662E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80411E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34509E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66777E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60336E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73634E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57934E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83182E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61760E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66246E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52964E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.50 -4.54 -1.513 0.77503E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62641E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18236E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14892E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18337E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 959.9990000 g New total amount of reactant added: 999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 999.9990000 Water: Moles liquid = 0.4984E+02 kg liquid = 0.8979E+00 Moles total = 0.4297E+02 kg total = 0.7742E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174157E-01 Osmotic coef. = 0.9688 True ionic strength = .2069425E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90301E-10 -10.0443 0.75757E-10 -10.1206 0.83894E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15294E-03 -3.8155 0.12752E-03 -3.8944 0.83379E+00 -0.0789 4 SO4-- 0.87220E-12 -12.0594 0.44996E-12 -12.3468 0.51589E+00 -0.2874 5 HCO3- 0.31465E-06 -6.5022 0.26274E-06 -6.5805 0.83503E+00 -0.0783 6 HS- 0.28398E-04 -4.5467 0.23681E-04 -4.6256 0.83391E+00 -0.0789 7 Al+++ 0.11019E-28 -28.9579 0.25075E-29 -29.6008 0.22756E+00 -0.6429 8 H4SiO4 0.71160E-03 -3.1478 0.71160E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14326E-06 -6.8439 0.73354E-07 -7.1346 0.51202E+00 -0.2907 10 Mg++ 0.22749E-10 -10.6430 0.11594E-10 -10.9358 0.50963E+00 -0.2927 11 Fe++ 0.62225E-13 -13.2060 0.31747E-13 -13.4983 0.51020E+00 -0.2923 12 K+ 0.16149E-03 -3.7918 0.13489E-03 -3.8700 0.83523E+00 -0.0782 13 Na+ 0.20532E-01 -1.6876 0.17116E-01 -1.7666 0.83363E+00 -0.0790 14 Mn++ 0.19842E-10 -10.7024 0.10132E-10 -10.9943 0.51063E+00 -0.2919 15 HPO4-- 0.48750E-07 -7.3120 0.25153E-07 -7.5994 0.51596E+00 -0.2874 16 HSiO3- 0.10991E-01 -1.9589 0.91646E-02 -2.0379 0.83379E+00 -0.0789 17 Ca(HSiO3)+ 0.18030E-07 -7.7440 0.15062E-07 -7.8221 0.83542E+00 -0.0781 18 Mg(HSiO3)+ 0.35463E-11 -11.4502 0.29627E-11 -11.5283 0.83542E+00 -0.0781 19 NaHSiO3,aq 0.24913E-02 -2.6036 0.24913E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67514E-16 -16.1706 0.56402E-16 -16.2487 0.83542E+00 -0.0781 22 HAlO2,aq 0.14899E-09 -9.8269 0.14899E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52763E-05 -5.2777 0.43912E-05 -5.3574 0.83226E+00 -0.0797 24 CH4,aq 0.13618E-04 -4.8659 0.13569E-04 -4.8675 0.99642E+00 -0.0016 25 C2H6,aq 0.29309E-14 -14.5330 0.29204E-14 -14.5346 0.99642E+00 -0.0016 29 CO,aq 0.11237E-16 -16.9493 0.11237E-16 -16.9493 0.10000E+01 0.0000 30 CO2,aq 0.40275E-10 -10.3950 0.40131E-10 -10.3965 0.99642E+00 -0.0016 31 CO3-2 0.62293E-06 -6.2056 0.32067E-06 -6.4939 0.51477E+00 -0.2884 32 CaCO3,aq 0.28809E-09 -9.5405 0.28809E-09 -9.5405 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.58130E-12 -12.2356 0.48563E-12 -12.3137 0.83542E+00 -0.0781 34 CaCl+ 0.17843E-10 -10.7485 0.14906E-10 -10.8266 0.83542E+00 -0.0781 35 CaCl2,aq 0.44259E-15 -15.3540 0.44259E-15 -15.3540 0.10000E+01 0.0000 36 CaOH+ 0.81727E-07 -7.0876 0.68276E-07 -7.1657 0.83542E+00 -0.0781 37 CaSO4,aq 0.10284E-16 -16.9878 0.10284E-16 -16.9878 0.10000E+01 0.0000 38 HCl,aq 0.18172E-14 -14.7406 0.18172E-14 -14.7406 0.10000E+01 0.0000 43 FeCl+ 0.75477E-17 -17.1222 0.63055E-17 -17.2003 0.83542E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16630E-10 -10.7791 0.13893E-10 -10.8572 0.83542E+00 -0.0781 48 HFeO2- 0.37248E-07 -7.4289 0.31057E-07 -7.5078 0.83379E+00 -0.0789 49 FeO+ 0.12273E-16 -16.9110 0.10253E-16 -16.9891 0.83542E+00 -0.0781 51 FeO2- 0.42113E-09 -9.3756 0.35114E-09 -9.4545 0.83379E+00 -0.0789 52 HFeO2,aq 0.33291E-11 -11.4777 0.33291E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10872E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.30457E-09 -9.5163 0.30457E-09 -9.5163 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11215E-14 -14.9502 0.93506E-15 -15.0292 0.83379E+00 -0.0789 58 MgCO3,aq 0.11378E-13 -13.9439 0.11378E-13 -13.9439 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.93687E-16 -16.0283 0.78267E-16 -16.1064 0.83542E+00 -0.0781 60 MgCl+ 0.25601E-14 -14.5917 0.21387E-14 -14.6698 0.83542E+00 -0.0781 61 MgOH+ 0.71561E-10 -10.1453 0.59783E-10 -10.2234 0.83542E+00 -0.0781 63 MnO,aq 0.18636E-08 -8.7296 0.18636E-08 -8.7296 0.10000E+01 0.0000 64 MnOH+ 0.49303E-09 -9.3071 0.41188E-09 -9.3852 0.83542E+00 -0.0781 65 MnO2-2 0.21815E-10 -10.6612 0.11230E-10 -10.9496 0.51477E+00 -0.2884 66 HMnO2- 0.22107E-09 -9.6555 0.18432E-09 -9.7344 0.83379E+00 -0.0789 69 MnCl+ 0.93601E-14 -14.0287 0.78196E-14 -14.1068 0.83542E+00 -0.0781 71 NaCl,aq 0.71269E-06 -6.1471 0.71269E-06 -6.1471 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95137E-02 -2.0217 0.79179E-02 -2.1014 0.83226E+00 -0.0797 79 HPO3-2 0.16780E-14 -14.7752 0.86378E-15 -15.0636 0.51477E+00 -0.2884 81 H2PO3- 0.15416E-18 -18.8120 0.12854E-18 -18.8910 0.83379E+00 -0.0789 82 H3PO4,aq 0.92938E-18 -18.0318 0.92938E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40029E-10 -10.3976 0.33408E-10 -10.4761 0.83460E+00 -0.0785 84 PO4-3 0.12119E-08 -8.9165 0.28996E-09 -9.5377 0.23925E+00 -0.6211 88 HP2O7-3 0.10379E-17 -17.9838 0.23644E-18 -18.6263 0.22780E+00 -0.6424 89 P2O7-4 0.10251E-16 -16.9892 0.76995E-18 -18.1135 0.75108E-01 -1.1243 90 H2S,aq 0.54096E-08 -8.2668 0.53903E-08 -8.2684 0.99642E+00 -0.0016 91 S2-2 0.22038E-14 -14.6568 0.11345E-14 -14.9452 0.51477E+00 -0.2884 97 SO3-2 0.12769E-17 -17.8938 0.66703E-18 -18.1759 0.52237E+00 -0.2820 99 HSO4- 0.37822E-19 -19.4223 0.31629E-19 -19.4999 0.83625E+00 -0.0777 Charge balance for all species = 0.3673E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9030076E-10 -.2312114E-01 -.2326252E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981181E+06 0.0000 3 Cl- 0.1529425E-03 0.1536555E-03 0.5437685E+01 6.2262 4 SO4-- 0.8722007E-12 -.1634531E-04 -.1567313E+01 7.8943 5 HCO3- 0.3146456E-06 0.1455546E-04 0.8865253E+00 3.5401 6 HS- 0.2839775E-04 0.4474847E-04 0.1477242E+01 5.4950 7 Al+++ 0.1101892E-28 0.5276402E-05 0.1421075E+00 0.7610 8 H4SiO4 0.7115968E-03 0.1419436E-01 0.1361826E+04 -3.1478 9 Ca++ 0.1432650E-06 0.2433284E-06 0.9734457E-02 13.1066 10 Mg++ 0.2274910E-10 0.9787032E-10 0.2375115E-05 9.3054 11 Fe++ 0.6222477E-13 0.3790837E-07 0.2113235E-02 6.7429 12 K+ 0.1614939E-03 0.1622704E-03 0.6333607E+01 6.2505 13 Na+ 0.2053155E-01 0.2312284E-01 0.5306269E+03 8.3540 14 Mn++ 0.1984155E-10 0.2619349E-08 0.1436412E-03 9.2468 15 HPO4-- 0.4875048E-07 0.5000246E-07 0.4790496E-02 12.6418 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1655849E+02 -.2076150E-01 -.1653772E+02 0.0000000E+00 2 H2O 0.4297285E+02 0.4983990E+02 -.6867048E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2773889E-01 -.1467718E-04 0.2775356E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2771338E-01 0.4018165E-04 -.2775356E-01 0.0000000E+00 7 Al+++ 0.3260738E+01 0.4737918E-05 0.3260734E+01 0.0000000E+00 8 H4SiO4 0.1041277E+02 0.1274575E-01 0.1040003E+02 0.0000000E+00 9 Ca++ 0.1150156E+01 0.2184955E-06 0.1150156E+01 0.0000000E+00 10 Mg++ 0.7936500E+00 0.8788215E-10 0.7936500E+00 0.0000000E+00 11 Fe++ 0.7130079E+00 0.3403963E-07 0.7130078E+00 0.0000000E+00 12 K+ 0.2123140E+00 0.1457098E-03 0.2121683E+00 0.0000000E+00 13 Na+ 0.1255402E+01 0.2076303E-01 0.1234639E+01 0.0000000E+00 14 Mn++ 0.1733858E-01 0.2352031E-08 0.1733858E-01 0.0000000E+00 15 HPO4-- 0.5917571E-02 0.4489944E-07 0.5917526E-02 0.0000000E+00 Chg. balance for solid moles: 0.1082E-14 Mass of aqueous solution: 0.899574E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.234 0.091 323.5 2.510 29.62 124.2 andradite 0.1110 -0.955 56.42 1.751 5.165 14.66 grossular 0.2651E-01 -1.577 11.94 1.077 1.093 3.323 apatite-OH 0.1973E-02 -2.705 0.9908 -0.004 0.9071E-01 0.3148 clinochlore 0.1436 -0.843 79.80 1.902 7.305 30.35 daphnite 0.4114E-01 -1.386 29.36 1.468 2.687 8.896 chlorite-Mn 0.3468E-02 -2.460 2.459 0.391 0.2251 0.7835 diopside 0.4835E-01 -1.316 10.47 1.020 0.9586 3.200 hedenbergite 0.1239E-01 -1.907 3.073 0.488 0.2813 0.8417 microcline 0.1858 -0.731 51.72 1.714 4.735 20.20 stilbite 0.6518 -0.186 459.3 2.662 42.05 214.2 stilpnomelane-Fe 0.5268E-01 -1.278 56.79 1.754 5.199 19.62 tr.625ac.25prg.125 0.7578E-02 -2.120 6.478 0.811 0.5930 2.085 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1843E-01 0.1843E-01 1.0000 -1.735 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1092.341370 g Volume = 442.705999 cm3 Porosity: -10.4006% V(tot) - V(min): -.41706E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 999.9990000 g log = 3.0000 Original solution: 1000.0103000 g Original solution / Rock added: 1.00 (Water/Rock Ratio), log = 0.0000 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0885 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9668E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4190E-08 1.0071 0.4594E-08 0.4561E-08 CH4,gas 0.1946E-01 1.0128 0.2146E-01 0.2119E-01 H2,gas 0.1369E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1450E-06 0.9958 0.1572E-06 0.1579E-06 S2,gas 0.3824E-29 1.0000 0.4163E-29 0.4163E-29 CO,gas 0.1630E-13 1.0000 0.1774E-13 0.1774E-13 SO3,gas 0.8869E-48 1.0000 0.9654E-48 0.9654E-48 SO2,gas 0.5003E-27 1.0000 0.5446E-27 0.5446E-27 HCl,gas 0.2948E-17 1.0000 0.3209E-17 0.3209E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 -0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 -0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.70 -10.34 -3.446 0.17652E+05 -8.338 3 CH4,gas 4.81 1.14 -3.67 -0.917 0.62637E+04 -1.668 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.75 -8.80 -4.402 0.15032E+05 -6.804 6 S2,gas -7.03 -38.41 -31.38 -4.828 0.53582E+05 -29.381 7 CO,gas 3.51 -12.24 -15.75 -4.846 0.26894E+05 -13.751 8 SO3,gas 17.43 -32.59 -50.02 -12.504 0.85400E+05 -48.015 9 SO2,gas 1.14 -28.13 -29.26 -7.804 0.49967E+05 -27.264 10 HCl,gas 5.48 -14.01 -19.49 -9.747 0.33285E+05 -17.494 11 acmite 7.74 6.57 -1.17 -0.121 0.19915E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.237 0.80776E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94122E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28383E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76234E+04 35 aragonite 0.99 -3.59 -4.58 -1.527 0.78214E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55855E+04 37 calcite 0.83 -3.59 -4.43 -1.476 0.75601E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70324E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82192E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68649E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70376E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65605E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36457E+04 66 diamond -3.11 -7.78 -4.67 -1.335 0.79788E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33651E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66052E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.78 -4.23 -1.209 0.72249E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60997E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24442E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59769E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16001E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22972E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48206E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82319E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61282E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53667E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41166E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36602E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20055E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92768E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40692E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43440E+04 143 pyrrhotite -4.24 -8.00 -3.76 -1.253 0.64197E+04 144 pyrrhotiteFe0.875 -6.00 -9.40 -3.40 -1.250 0.58025E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22487E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84880E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28304E+03 152 rhodonite 7.46 6.10 -1.36 -0.273 0.23279E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27394E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.77 -0.395 0.47246E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91033E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76031E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65758E+04 181 troilite-low -4.39 -8.00 -3.61 -1.203 0.61629E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80412E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34509E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66777E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60336E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73634E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57934E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83182E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61760E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66246E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52964E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.50 -4.54 -1.512 0.77467E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62641E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18236E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14892E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18337E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 999.9990000 g New total amount of reactant added: 1039.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1039.9990000 Water: Moles liquid = 0.4962E+02 kg liquid = 0.8939E+00 Moles total = 0.4247E+02 kg total = 0.7651E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174216E-01 Osmotic coef. = 0.9688 True ionic strength = .2069472E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90303E-10 -10.0443 0.75759E-10 -10.1206 0.83894E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15363E-03 -3.8135 0.12810E-03 -3.8925 0.83379E+00 -0.0789 4 SO4-- 0.87614E-12 -12.0574 0.45199E-12 -12.3449 0.51589E+00 -0.2874 5 HCO3- 0.31607E-06 -6.5002 0.26393E-06 -6.5785 0.83503E+00 -0.0783 6 HS- 0.28525E-04 -4.5448 0.23788E-04 -4.6236 0.83391E+00 -0.0789 7 Al+++ 0.11020E-28 -28.9578 0.25076E-29 -29.6007 0.22756E+00 -0.6429 8 H4SiO4 0.71160E-03 -3.1478 0.71160E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14327E-06 -6.8438 0.73357E-07 -7.1346 0.51202E+00 -0.2907 10 Mg++ 0.22750E-10 -10.6430 0.11594E-10 -10.9358 0.50963E+00 -0.2927 11 Fe++ 0.62228E-13 -13.2060 0.31748E-13 -13.4983 0.51020E+00 -0.2923 12 K+ 0.16150E-03 -3.7918 0.13489E-03 -3.8700 0.83523E+00 -0.0782 13 Na+ 0.20532E-01 -1.6876 0.17116E-01 -1.7666 0.83363E+00 -0.0790 14 Mn++ 0.19850E-10 -10.7022 0.10136E-10 -10.9941 0.51063E+00 -0.2919 15 HPO4-- 0.48749E-07 -7.3120 0.25153E-07 -7.5994 0.51596E+00 -0.2874 16 HSiO3- 0.10991E-01 -1.9590 0.91644E-02 -2.0379 0.83379E+00 -0.0789 17 Ca(HSiO3)+ 0.18030E-07 -7.7440 0.15063E-07 -7.8221 0.83541E+00 -0.0781 18 Mg(HSiO3)+ 0.35464E-11 -11.4502 0.29627E-11 -11.5283 0.83541E+00 -0.0781 19 NaHSiO3,aq 0.24913E-02 -2.6036 0.24913E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67515E-16 -16.1706 0.56403E-16 -16.2487 0.83541E+00 -0.0781 22 HAlO2,aq 0.14898E-09 -9.8269 0.14898E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52761E-05 -5.2777 0.43911E-05 -5.3574 0.83226E+00 -0.0797 24 CH4,aq 0.13679E-04 -4.8640 0.13630E-04 -4.8655 0.99642E+00 -0.0016 25 C2H6,aq 0.29574E-14 -14.5291 0.29468E-14 -14.5307 0.99642E+00 -0.0016 29 CO,aq 0.11288E-16 -16.9474 0.11288E-16 -16.9474 0.10000E+01 0.0000 30 CO2,aq 0.40458E-10 -10.3930 0.40313E-10 -10.3946 0.99642E+00 -0.0016 31 CO3-2 0.62573E-06 -6.2036 0.32211E-06 -6.4920 0.51477E+00 -0.2884 32 CaCO3,aq 0.28940E-09 -9.5385 0.28940E-09 -9.5385 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.58394E-12 -12.2336 0.48784E-12 -12.3117 0.83541E+00 -0.0781 34 CaCl+ 0.17924E-10 -10.7466 0.14974E-10 -10.8247 0.83541E+00 -0.0781 35 CaCl2,aq 0.44659E-15 -15.3501 0.44659E-15 -15.3501 0.10000E+01 0.0000 36 CaOH+ 0.81729E-07 -7.0876 0.68277E-07 -7.1657 0.83541E+00 -0.0781 37 CaSO4,aq 0.10331E-16 -16.9859 0.10331E-16 -16.9859 0.10000E+01 0.0000 38 HCl,aq 0.18254E-14 -14.7387 0.18254E-14 -14.7387 0.10000E+01 0.0000 43 FeCl+ 0.75820E-17 -17.1202 0.63341E-17 -17.1983 0.83541E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16630E-10 -10.7791 0.13893E-10 -10.8572 0.83541E+00 -0.0781 48 HFeO2- 0.37248E-07 -7.4289 0.31057E-07 -7.5078 0.83379E+00 -0.0789 49 FeO+ 0.12274E-16 -16.9110 0.10254E-16 -16.9891 0.83541E+00 -0.0781 51 FeO2- 0.42112E-09 -9.3756 0.35113E-09 -9.4545 0.83379E+00 -0.0789 52 HFeO2,aq 0.33291E-11 -11.4777 0.33291E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10872E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.30594E-09 -9.5144 0.30594E-09 -9.5144 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11265E-14 -14.9483 0.93930E-15 -15.0272 0.83379E+00 -0.0789 58 MgCO3,aq 0.11429E-13 -13.9420 0.11429E-13 -13.9420 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.94113E-16 -16.0264 0.78623E-16 -16.1044 0.83541E+00 -0.0781 60 MgCl+ 0.25717E-14 -14.5898 0.21484E-14 -14.6679 0.83541E+00 -0.0781 61 MgOH+ 0.71562E-10 -10.1453 0.59784E-10 -10.2234 0.83541E+00 -0.0781 63 MnO,aq 0.18643E-08 -8.7295 0.18643E-08 -8.7295 0.10000E+01 0.0000 64 MnOH+ 0.49321E-09 -9.3070 0.41204E-09 -9.3851 0.83541E+00 -0.0781 65 MnO2-2 0.21822E-10 -10.6611 0.11233E-10 -10.9495 0.51477E+00 -0.2884 66 HMnO2- 0.22114E-09 -9.6553 0.18438E-09 -9.7343 0.83379E+00 -0.0789 69 MnCl+ 0.94060E-14 -14.0266 0.78579E-14 -14.1047 0.83541E+00 -0.0781 71 NaCl,aq 0.71590E-06 -6.1451 0.71590E-06 -6.1451 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95135E-02 -2.0217 0.79177E-02 -2.1014 0.83226E+00 -0.0797 79 HPO3-2 0.16779E-14 -14.7752 0.86374E-15 -15.0636 0.51477E+00 -0.2884 81 H2PO3- 0.15416E-18 -18.8120 0.12854E-18 -18.8910 0.83379E+00 -0.0789 82 H3PO4,aq 0.92939E-18 -18.0318 0.92939E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40029E-10 -10.3976 0.33408E-10 -10.4762 0.83459E+00 -0.0785 84 PO4-3 0.12119E-08 -8.9165 0.28995E-09 -9.5377 0.23925E+00 -0.6211 88 HP2O7-3 0.10379E-17 -17.9838 0.23643E-18 -18.6263 0.22780E+00 -0.6425 89 P2O7-4 0.10251E-16 -16.9892 0.76990E-18 -18.1136 0.75106E-01 -1.1243 90 H2S,aq 0.54341E-08 -8.2649 0.54146E-08 -8.2664 0.99642E+00 -0.0016 91 S2-2 0.22237E-14 -14.6529 0.11447E-14 -14.9413 0.51477E+00 -0.2884 97 SO3-2 0.12827E-17 -17.8919 0.67003E-18 -18.1739 0.52237E+00 -0.2820 99 HSO4- 0.37993E-19 -19.4203 0.31772E-19 -19.4980 0.83625E+00 -0.0777 Charge balance for all species = 0.3689E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9030280E-10 -.2312080E-01 -.2326218E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981181E+06 0.0000 3 Cl- 0.1536301E-03 0.1543463E-03 0.5462131E+01 6.2281 4 SO4-- 0.8761415E-12 -.1640649E-04 -.1573180E+01 7.8963 5 HCO3- 0.3160661E-06 0.1462090E-04 0.8905107E+00 3.5420 6 HS- 0.2852541E-04 0.4493734E-04 0.1483477E+01 5.4969 7 Al+++ 0.1101963E-28 0.5276232E-05 0.1421029E+00 0.7610 8 H4SiO4 0.7115999E-03 0.1419421E-01 0.1361812E+04 -3.1478 9 Ca++ 0.1432713E-06 0.2433380E-06 0.9734840E-02 13.1066 10 Mg++ 0.2275009E-10 0.9787276E-10 0.2375174E-05 9.3054 11 Fe++ 0.6222768E-13 0.3790757E-07 0.2113191E-02 6.7429 12 K+ 0.1614975E-03 0.1622740E-03 0.6333749E+01 6.2505 13 Na+ 0.2053202E-01 0.2312332E-01 0.5306378E+03 8.3540 14 Mn++ 0.1984957E-10 0.2620288E-08 0.1436927E-03 9.2470 15 HPO4-- 0.4874907E-07 0.5000099E-07 0.4790355E-02 12.6417 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1722083E+02 -.2066828E-01 -.1720016E+02 0.0000000E+00 2 H2O 0.4247144E+02 0.4961685E+02 -.7145410E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2884742E-01 -.1466619E-04 0.2886209E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2882192E-01 0.4017066E-04 -.2886209E-01 0.0000000E+00 7 Al+++ 0.3391168E+01 0.4716561E-05 0.3391163E+01 0.0000000E+00 8 H4SiO4 0.1082928E+02 0.1268857E-01 0.1081660E+02 0.0000000E+00 9 Ca++ 0.1196162E+01 0.2175262E-06 0.1196161E+01 0.0000000E+00 10 Mg++ 0.8253960E+00 0.8749101E-10 0.8253960E+00 0.0000000E+00 11 Fe++ 0.7415282E+00 0.3388657E-07 0.7415282E+00 0.0000000E+00 12 K+ 0.2208066E+00 0.1450610E-03 0.2206615E+00 0.0000000E+00 13 Na+ 0.1305612E+01 0.2067054E-01 0.1284942E+01 0.0000000E+00 14 Mn++ 0.1803212E-01 0.2342344E-08 0.1803212E-01 0.0000000E+00 15 HPO4-- 0.6154274E-02 0.4469719E-07 0.6154229E-02 0.0000000E+00 Chg. balance for solid moles: 0.2241E-14 Mass of aqueous solution: 0.895548E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1039.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.284 0.109 336.7 2.527 29.64 129.2 andradite 0.1154 -0.938 58.67 1.768 5.164 15.24 grossular 0.2757E-01 -1.560 12.42 1.094 1.093 3.456 apatite-OH 0.2051E-02 -2.688 1.030 0.013 0.9071E-01 0.3274 clinochlore 0.1493 -0.826 82.96 1.919 7.303 31.56 daphnite 0.4277E-01 -1.369 30.52 1.485 2.686 9.248 chlorite-Mn 0.3606E-02 -2.443 2.557 0.408 0.2251 0.8148 diopside 0.5066E-01 -1.295 10.97 1.040 0.9658 3.353 hedenbergite 0.1298E-01 -1.887 3.220 0.508 0.2834 0.8820 microcline 0.1933 -0.714 53.79 1.731 4.735 21.01 stilbite 0.6775 -0.169 477.4 2.679 42.03 222.7 stilpnomelane-Fe 0.5479E-01 -1.261 59.07 1.771 5.199 20.40 tr.625ac.25prg.125 0.7851E-02 -2.105 6.711 0.827 0.5907 2.160 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1843E-01 0.1843E-01 1.0000 -1.734 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1136.043561 g Volume = 460.388542 cm3 Porosity: -10.4050% V(tot) - V(min): -.43389E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1039.9990000 g log = 3.0170 Original solution: 1000.0103000 g Original solution / Rock added: 0.96 (Water/Rock Ratio), log = -0.0170 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0886 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9668E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4209E-08 1.0071 0.4615E-08 0.4582E-08 CH4,gas 0.1955E-01 1.0128 0.2155E-01 0.2128E-01 H2,gas 0.1369E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1457E-06 0.9958 0.1579E-06 0.1586E-06 S2,gas 0.3859E-29 1.0000 0.4201E-29 0.4201E-29 CO,gas 0.1637E-13 1.0000 0.1782E-13 0.1782E-13 SO3,gas 0.8909E-48 1.0000 0.9698E-48 0.9698E-48 SO2,gas 0.5025E-27 1.0000 0.5471E-27 0.5471E-27 HCl,gas 0.2961E-17 1.0000 0.3223E-17 0.3223E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.70 -10.34 -3.445 0.17648E+05 -8.336 3 CH4,gas 4.81 1.14 -3.67 -0.917 0.62604E+04 -1.666 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.74 -8.80 -4.401 0.15028E+05 -6.802 6 S2,gas -7.03 -38.41 -31.38 -4.827 0.53575E+05 -29.377 7 CO,gas 3.51 -12.24 -15.75 -4.846 0.26891E+05 -13.749 8 SO3,gas 17.43 -32.59 -50.01 -12.503 0.85396E+05 -48.013 9 SO2,gas 1.14 -28.13 -29.26 -7.803 0.49964E+05 -27.262 10 HCl,gas 5.48 -14.01 -19.49 -9.746 0.33282E+05 -17.492 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.237 0.80769E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94122E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28383E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76234E+04 35 aragonite 0.99 -3.59 -4.58 -1.526 0.78181E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55855E+04 37 calcite 0.83 -3.59 -4.43 -1.475 0.75567E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70324E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82192E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68649E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70376E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65602E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36457E+04 66 diamond -3.11 -7.78 -4.67 -1.335 0.79754E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33651E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66052E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.78 -4.23 -1.208 0.72216E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60997E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24442E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59770E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16001E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22973E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48206E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82317E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61282E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53667E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41166E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36602E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20055E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92768E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40692E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43441E+04 143 pyrrhotite -4.24 -8.00 -3.76 -1.253 0.64163E+04 144 pyrrhotiteFe0.875 -6.00 -9.40 -3.40 -1.249 0.57991E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22484E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84880E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28304E+03 152 rhodonite 7.46 6.10 -1.36 -0.273 0.23276E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27394E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.77 -0.395 0.47240E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91033E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76031E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65757E+04 181 troilite-low -4.39 -8.00 -3.61 -1.202 0.61595E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80413E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34509E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66778E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60335E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73634E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57934E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83182E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61760E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66246E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52964E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.50 -4.53 -1.512 0.77431E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62641E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18236E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14892E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1039.9990000 g New total amount of reactant added: 1079.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1079.9990000 Water: Moles liquid = 0.4940E+02 kg liquid = 0.8899E+00 Moles total = 0.4197E+02 kg total = 0.7561E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174275E-01 Osmotic coef. = 0.9688 True ionic strength = .2069520E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90305E-10 -10.0443 0.75760E-10 -10.1206 0.83894E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15432E-03 -3.8116 0.12867E-03 -3.8905 0.83379E+00 -0.0789 4 SO4-- 0.88012E-12 -12.0555 0.45404E-12 -12.3429 0.51588E+00 -0.2874 5 HCO3- 0.31750E-06 -6.4983 0.26512E-06 -6.5766 0.83503E+00 -0.0783 6 HS- 0.28654E-04 -4.5428 0.23895E-04 -4.6217 0.83391E+00 -0.0789 7 Al+++ 0.11020E-28 -28.9578 0.25077E-29 -29.6007 0.22755E+00 -0.6429 8 H4SiO4 0.71160E-03 -3.1478 0.71160E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14328E-06 -6.8438 0.73360E-07 -7.1345 0.51201E+00 -0.2907 10 Mg++ 0.22751E-10 -10.6430 0.11595E-10 -10.9357 0.50962E+00 -0.2928 11 Fe++ 0.62231E-13 -13.2060 0.31750E-13 -13.4983 0.51019E+00 -0.2923 12 K+ 0.16150E-03 -3.7918 0.13489E-03 -3.8700 0.83523E+00 -0.0782 13 Na+ 0.20532E-01 -1.6876 0.17117E-01 -1.7666 0.83363E+00 -0.0790 14 Mn++ 0.19857E-10 -10.7021 0.10140E-10 -10.9940 0.51062E+00 -0.2919 15 HPO4-- 0.48748E-07 -7.3120 0.25152E-07 -7.5994 0.51596E+00 -0.2874 16 HSiO3- 0.10991E-01 -1.9590 0.91643E-02 -2.0379 0.83379E+00 -0.0789 17 Ca(HSiO3)+ 0.18030E-07 -7.7440 0.15063E-07 -7.8221 0.83541E+00 -0.0781 18 Mg(HSiO3)+ 0.35465E-11 -11.4502 0.29628E-11 -11.5283 0.83541E+00 -0.0781 19 NaHSiO3,aq 0.24913E-02 -2.6036 0.24913E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67516E-16 -16.1706 0.56403E-16 -16.2487 0.83541E+00 -0.0781 22 HAlO2,aq 0.14898E-09 -9.8269 0.14898E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52759E-05 -5.2777 0.43909E-05 -5.3574 0.83226E+00 -0.0797 24 CH4,aq 0.13741E-04 -4.8620 0.13691E-04 -4.8636 0.99642E+00 -0.0016 25 C2H6,aq 0.29842E-14 -14.5252 0.29735E-14 -14.5267 0.99642E+00 -0.0016 29 CO,aq 0.11340E-16 -16.9454 0.11340E-16 -16.9454 0.10000E+01 0.0000 30 CO2,aq 0.40642E-10 -10.3910 0.40497E-10 -10.3926 0.99642E+00 -0.0016 31 CO3-2 0.62856E-06 -6.2017 0.32356E-06 -6.4900 0.51477E+00 -0.2884 32 CaCO3,aq 0.29071E-09 -9.5365 0.29071E-09 -9.5365 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.58661E-12 -12.2316 0.49006E-12 -12.3097 0.83541E+00 -0.0781 34 CaCl+ 0.18005E-10 -10.7446 0.15042E-10 -10.8227 0.83541E+00 -0.0781 35 CaCl2,aq 0.45065E-15 -15.3462 0.45065E-15 -15.3462 0.10000E+01 0.0000 36 CaOH+ 0.81730E-07 -7.0876 0.68279E-07 -7.1657 0.83541E+00 -0.0781 37 CaSO4,aq 0.10378E-16 -16.9839 0.10378E-16 -16.9839 0.10000E+01 0.0000 38 HCl,aq 0.18336E-14 -14.7367 0.18336E-14 -14.7367 0.10000E+01 0.0000 43 FeCl+ 0.76165E-17 -17.1182 0.63630E-17 -17.1963 0.83541E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16631E-10 -10.7791 0.13894E-10 -10.8572 0.83541E+00 -0.0781 48 HFeO2- 0.37247E-07 -7.4289 0.31056E-07 -7.5079 0.83379E+00 -0.0789 49 FeO+ 0.12274E-16 -16.9110 0.10254E-16 -16.9891 0.83541E+00 -0.0781 51 FeO2- 0.42112E-09 -9.3756 0.35112E-09 -9.4545 0.83379E+00 -0.0789 52 HFeO2,aq 0.33291E-11 -11.4777 0.33291E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10872E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.30733E-09 -9.5124 0.30733E-09 -9.5124 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11317E-14 -14.9463 0.94357E-15 -15.0252 0.83379E+00 -0.0789 58 MgCO3,aq 0.11481E-13 -13.9400 0.11481E-13 -13.9400 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.94543E-16 -16.0244 0.78983E-16 -16.1025 0.83541E+00 -0.0781 60 MgCl+ 0.25834E-14 -14.5878 0.21582E-14 -14.6659 0.83541E+00 -0.0781 61 MgOH+ 0.71563E-10 -10.1453 0.59785E-10 -10.2234 0.83541E+00 -0.0781 63 MnO,aq 0.18649E-08 -8.7294 0.18649E-08 -8.7294 0.10000E+01 0.0000 64 MnOH+ 0.49339E-09 -9.3068 0.41218E-09 -9.3849 0.83541E+00 -0.0781 65 MnO2-2 0.21828E-10 -10.6610 0.11237E-10 -10.9494 0.51477E+00 -0.2884 66 HMnO2- 0.22121E-09 -9.6552 0.18444E-09 -9.7341 0.83379E+00 -0.0789 69 MnCl+ 0.94519E-14 -14.0245 0.78963E-14 -14.1026 0.83541E+00 -0.0781 71 NaCl,aq 0.71915E-06 -6.1432 0.71915E-06 -6.1432 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95133E-02 -2.0217 0.79175E-02 -2.1014 0.83226E+00 -0.0797 79 HPO3-2 0.16779E-14 -14.7752 0.86370E-15 -15.0636 0.51477E+00 -0.2884 81 H2PO3- 0.15416E-18 -18.8120 0.12853E-18 -18.8910 0.83379E+00 -0.0789 82 H3PO4,aq 0.92939E-18 -18.0318 0.92939E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40028E-10 -10.3976 0.33407E-10 -10.4762 0.83459E+00 -0.0785 84 PO4-3 0.12118E-08 -8.9166 0.28993E-09 -9.5377 0.23925E+00 -0.6212 88 HP2O7-3 0.10379E-17 -17.9839 0.23642E-18 -18.6263 0.22779E+00 -0.6425 89 P2O7-4 0.10250E-16 -16.9893 0.76984E-18 -18.1136 0.75104E-01 -1.1243 90 H2S,aq 0.54587E-08 -8.2629 0.54392E-08 -8.2645 0.99642E+00 -0.0016 91 S2-2 0.22439E-14 -14.6490 0.11551E-14 -14.9374 0.51477E+00 -0.2884 97 SO3-2 0.12885E-17 -17.8899 0.67306E-18 -18.1719 0.52237E+00 -0.2820 99 HSO4- 0.38166E-19 -19.4183 0.31917E-19 -19.4960 0.83625E+00 -0.0777 Charge balance for all species = 0.3707E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9030484E-10 -.2312045E-01 -.2326183E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981180E+06 0.0000 3 Cl- 0.1543238E-03 0.1550433E-03 0.5486797E+01 6.2300 4 SO4-- 0.8801154E-12 -.1646823E-04 -.1579100E+01 7.8982 5 HCO3- 0.3174986E-06 0.1468692E-04 0.8945321E+00 3.5440 6 HS- 0.2865423E-04 0.4512792E-04 0.1489768E+01 5.4989 7 Al+++ 0.1102035E-28 0.5276066E-05 0.1420984E+00 0.7609 8 H4SiO4 0.7116027E-03 0.1419405E-01 0.1361796E+04 -3.1478 9 Ca++ 0.1432776E-06 0.2433477E-06 0.9735228E-02 13.1066 10 Mg++ 0.2275110E-10 0.9787510E-10 0.2375230E-05 9.3054 11 Fe++ 0.6223060E-13 0.3790678E-07 0.2113146E-02 6.7429 12 K+ 0.1615012E-03 0.1622777E-03 0.6333892E+01 6.2505 13 Na+ 0.2053248E-01 0.2312380E-01 0.5306488E+03 8.3540 14 Mn++ 0.1985707E-10 0.2621158E-08 0.1437404E-03 9.2471 15 HPO4-- 0.4874762E-07 0.4999949E-07 0.4790211E-02 12.6417 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1788317E+02 -.2057506E-01 -.1786259E+02 0.0000000E+00 2 H2O 0.4197002E+02 0.4939379E+02 -.7423771E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2995596E-01 -.1465520E-04 0.2997061E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2993045E-01 0.4015967E-04 -.2997061E-01 0.0000000E+00 7 Al+++ 0.3521598E+01 0.4695210E-05 0.3521593E+01 0.0000000E+00 8 H4SiO4 0.1124580E+02 0.1263139E-01 0.1123316E+02 0.0000000E+00 9 Ca++ 0.1242167E+01 0.2165569E-06 0.1242167E+01 0.0000000E+00 10 Mg++ 0.8571421E+00 0.8709977E-10 0.8571421E+00 0.0000000E+00 11 Fe++ 0.7700486E+00 0.3373352E-07 0.7700485E+00 0.0000000E+00 12 K+ 0.2292992E+00 0.1444121E-03 0.2291547E+00 0.0000000E+00 13 Na+ 0.1355822E+01 0.2057804E-01 0.1335244E+01 0.0000000E+00 14 Mn++ 0.1872567E-01 0.2332588E-08 0.1872566E-01 0.0000000E+00 15 HPO4-- 0.6390977E-02 0.4449491E-07 0.6390932E-02 0.0000000E+00 Chg. balance for solid moles: 0.9749E-15 Mass of aqueous solution: 0.891522E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1079.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.334 0.125 349.9 2.544 29.66 134.3 andradite 0.1199 -0.921 60.92 1.785 5.164 15.83 grossular 0.2863E-01 -1.543 12.90 1.110 1.093 3.588 apatite-OH 0.2130E-02 -2.672 1.070 0.029 0.9071E-01 0.3400 clinochlore 0.1549 -0.810 86.12 1.935 7.300 32.76 daphnite 0.4440E-01 -1.353 31.68 1.501 2.686 9.601 chlorite-Mn 0.3745E-02 -2.427 2.655 0.424 0.2251 0.8461 diopside 0.5298E-01 -1.276 11.47 1.060 0.9725 3.506 hedenbergite 0.1357E-01 -1.867 3.367 0.527 0.2854 0.9223 microcline 0.2007 -0.697 55.86 1.747 4.735 21.82 stilbite 0.7032 -0.153 495.5 2.695 42.00 231.1 stilpnomelane-Fe 0.5691E-01 -1.245 61.35 1.788 5.200 21.19 tr.625ac.25prg.125 0.8123E-02 -2.090 6.944 0.842 0.5886 2.235 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1844E-01 0.1844E-01 1.0000 -1.734 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1179.745752 g Volume = 478.071085 cm3 Porosity: -10.4091% V(tot) - V(min): -.45071E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1079.9990000 g log = 3.0334 Original solution: 1000.0103000 g Original solution / Rock added: 0.93 (Water/Rock Ratio), log = -0.0334 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0887 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9667E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4228E-08 1.0071 0.4636E-08 0.4603E-08 CH4,gas 0.1963E-01 1.0128 0.2165E-01 0.2138E-01 H2,gas 0.1369E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1463E-06 0.9958 0.1586E-06 0.1593E-06 S2,gas 0.3893E-29 1.0000 0.4239E-29 0.4239E-29 CO,gas 0.1645E-13 1.0000 0.1791E-13 0.1791E-13 SO3,gas 0.8949E-48 1.0000 0.9743E-48 0.9743E-48 SO2,gas 0.5048E-27 1.0000 0.5496E-27 0.5496E-27 HCl,gas 0.2974E-17 1.0000 0.3238E-17 0.3238E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.18198E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.70 -10.33 -3.445 0.17645E+05 -8.334 3 CH4,gas 4.81 1.14 -3.66 -0.916 0.62571E+04 -1.665 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.74 -8.80 -4.400 0.15025E+05 -6.800 6 S2,gas -7.03 -38.41 -31.37 -4.827 0.53568E+05 -29.373 7 CO,gas 3.51 -12.24 -15.75 -4.845 0.26888E+05 -13.747 8 SO3,gas 17.43 -32.58 -50.01 -12.503 0.85393E+05 -48.011 9 SO2,gas 1.14 -28.12 -29.26 -7.803 0.49961E+05 -27.260 10 HCl,gas 5.48 -14.01 -19.49 -9.745 0.33278E+05 -17.490 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80761E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94122E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28383E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76234E+04 35 aragonite 0.99 -3.59 -4.58 -1.526 0.78147E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55855E+04 37 calcite 0.83 -3.59 -4.42 -1.475 0.75534E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70324E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82192E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68649E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70377E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65600E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36457E+04 66 diamond -3.11 -7.78 -4.67 -1.334 0.79721E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33651E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66052E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.78 -4.23 -1.208 0.72182E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60997E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59770E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16001E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22973E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48206E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82314E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61283E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53667E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41166E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36602E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20055E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92769E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40693E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43441E+04 143 pyrrhotite -4.24 -8.00 -3.76 -1.252 0.64130E+04 144 pyrrhotiteFe0.875 -6.00 -9.40 -3.39 -1.248 0.57958E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22482E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84880E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28304E+03 152 rhodonite 7.46 6.10 -1.36 -0.273 0.23274E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27394E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.77 -0.395 0.47235E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91033E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76031E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65757E+04 181 troilite-low -4.39 -8.00 -3.61 -1.202 0.61562E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80414E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34509E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66778E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60335E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73634E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57934E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83182E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61760E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66246E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52964E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.50 -4.53 -1.511 0.77395E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62641E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14892E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1079.9990000 g New total amount of reactant added: 1119.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1119.9990000 Water: Moles liquid = 0.4917E+02 kg liquid = 0.8859E+00 Moles total = 0.4147E+02 kg total = 0.7471E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174335E-01 Osmotic coef. = 0.9688 True ionic strength = .2069567E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90307E-10 -10.0443 0.75762E-10 -10.1205 0.83894E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15502E-03 -3.8096 0.12926E-03 -3.8885 0.83379E+00 -0.0789 4 SO4-- 0.88412E-12 -12.0535 0.45610E-12 -12.3409 0.51588E+00 -0.2875 5 HCO3- 0.31894E-06 -6.4963 0.26633E-06 -6.5746 0.83503E+00 -0.0783 6 HS- 0.28784E-04 -4.5408 0.24003E-04 -4.6197 0.83391E+00 -0.0789 7 Al+++ 0.11021E-28 -28.9578 0.25078E-29 -29.6007 0.22755E+00 -0.6429 8 H4SiO4 0.71161E-03 -3.1478 0.71161E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14328E-06 -6.8438 0.73363E-07 -7.1345 0.51201E+00 -0.2907 10 Mg++ 0.22752E-10 -10.6430 0.11595E-10 -10.9357 0.50962E+00 -0.2928 11 Fe++ 0.62234E-13 -13.2060 0.31751E-13 -13.4982 0.51019E+00 -0.2923 12 K+ 0.16150E-03 -3.7918 0.13489E-03 -3.8700 0.83523E+00 -0.0782 13 Na+ 0.20533E-01 -1.6875 0.17117E-01 -1.7666 0.83363E+00 -0.0790 14 Mn++ 0.19864E-10 -10.7019 0.10143E-10 -10.9938 0.51062E+00 -0.2919 15 HPO4-- 0.48746E-07 -7.3121 0.25151E-07 -7.5994 0.51595E+00 -0.2874 16 HSiO3- 0.10991E-01 -1.9590 0.91641E-02 -2.0379 0.83379E+00 -0.0789 17 Ca(HSiO3)+ 0.18031E-07 -7.7440 0.15063E-07 -7.8221 0.83541E+00 -0.0781 18 Mg(HSiO3)+ 0.35466E-11 -11.4502 0.29628E-11 -11.5283 0.83541E+00 -0.0781 19 NaHSiO3,aq 0.24913E-02 -2.6036 0.24913E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67516E-16 -16.1706 0.56404E-16 -16.2487 0.83541E+00 -0.0781 22 HAlO2,aq 0.14898E-09 -9.8269 0.14898E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52758E-05 -5.2777 0.43908E-05 -5.3575 0.83226E+00 -0.0797 24 CH4,aq 0.13803E-04 -4.8600 0.13753E-04 -4.8616 0.99642E+00 -0.0016 25 C2H6,aq 0.30113E-14 -14.5212 0.30005E-14 -14.5228 0.99642E+00 -0.0016 29 CO,aq 0.11391E-16 -16.9434 0.11391E-16 -16.9434 0.10000E+01 0.0000 30 CO2,aq 0.40828E-10 -10.3890 0.40682E-10 -10.3906 0.99642E+00 -0.0016 31 CO3-2 0.63141E-06 -6.1997 0.32502E-06 -6.4881 0.51476E+00 -0.2884 32 CaCO3,aq 0.29204E-09 -9.5346 0.29204E-09 -9.5346 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.58931E-12 -12.2297 0.49231E-12 -12.3078 0.83541E+00 -0.0781 34 CaCl+ 0.18088E-10 -10.7426 0.15111E-10 -10.8207 0.83541E+00 -0.0781 35 CaCl2,aq 0.45476E-15 -15.3422 0.45476E-15 -15.3422 0.10000E+01 0.0000 36 CaOH+ 0.81732E-07 -7.0876 0.68280E-07 -7.1657 0.83541E+00 -0.0781 37 CaSO4,aq 0.10426E-16 -16.9819 0.10426E-16 -16.9819 0.10000E+01 0.0000 38 HCl,aq 0.18420E-14 -14.7347 0.18420E-14 -14.7347 0.10000E+01 0.0000 43 FeCl+ 0.76514E-17 -17.1163 0.63921E-17 -17.1944 0.83541E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16631E-10 -10.7791 0.13894E-10 -10.8572 0.83541E+00 -0.0781 48 HFeO2- 0.37246E-07 -7.4289 0.31055E-07 -7.5079 0.83379E+00 -0.0789 49 FeO+ 0.12274E-16 -16.9110 0.10254E-16 -16.9891 0.83541E+00 -0.0781 51 FeO2- 0.42111E-09 -9.3756 0.35112E-09 -9.4545 0.83379E+00 -0.0789 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10872E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.30873E-09 -9.5104 0.30873E-09 -9.5104 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11368E-14 -14.9443 0.94788E-15 -15.0232 0.83379E+00 -0.0789 58 MgCO3,aq 0.11534E-13 -13.9380 0.11534E-13 -13.9380 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.94977E-16 -16.0224 0.79345E-16 -16.1005 0.83541E+00 -0.0781 60 MgCl+ 0.25952E-14 -14.5858 0.21681E-14 -14.6639 0.83541E+00 -0.0781 61 MgOH+ 0.71565E-10 -10.1453 0.59786E-10 -10.2234 0.83541E+00 -0.0781 63 MnO,aq 0.18654E-08 -8.7292 0.18654E-08 -8.7292 0.10000E+01 0.0000 64 MnOH+ 0.49355E-09 -9.3067 0.41232E-09 -9.3848 0.83541E+00 -0.0781 65 MnO2-2 0.21834E-10 -10.6609 0.11239E-10 -10.9493 0.51476E+00 -0.2884 66 HMnO2- 0.22127E-09 -9.6551 0.18449E-09 -9.7340 0.83379E+00 -0.0789 69 MnCl+ 0.94981E-14 -14.0224 0.79348E-14 -14.1005 0.83541E+00 -0.0781 71 NaCl,aq 0.72243E-06 -6.1412 0.72243E-06 -6.1412 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95131E-02 -2.0217 0.79174E-02 -2.1014 0.83226E+00 -0.0797 79 HPO3-2 0.16778E-14 -14.7753 0.86366E-15 -15.0637 0.51476E+00 -0.2884 81 H2PO3- 0.15415E-18 -18.8120 0.12853E-18 -18.8910 0.83379E+00 -0.0789 82 H3PO4,aq 0.92940E-18 -18.0318 0.92940E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40028E-10 -10.3976 0.33407E-10 -10.4762 0.83459E+00 -0.0785 84 PO4-3 0.12118E-08 -8.9166 0.28991E-09 -9.5377 0.23925E+00 -0.6212 88 HP2O7-3 0.10378E-17 -17.9839 0.23640E-18 -18.6263 0.22779E+00 -0.6425 89 P2O7-4 0.10250E-16 -16.9893 0.76978E-18 -18.1136 0.75103E-01 -1.1243 90 H2S,aq 0.54836E-08 -8.2609 0.54640E-08 -8.2625 0.99642E+00 -0.0016 91 S2-2 0.22643E-14 -14.6451 0.11656E-14 -14.9335 0.51476E+00 -0.2884 97 SO3-2 0.12943E-17 -17.8880 0.67611E-18 -18.1700 0.52236E+00 -0.2820 99 HSO4- 0.38341E-19 -19.4163 0.32062E-19 -19.4940 0.83624E+00 -0.0777 Charge balance for all species = 0.3722E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9030690E-10 -.2312009E-01 -.2326147E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981180E+06 0.0000 3 Cl- 0.1550239E-03 0.1557466E-03 0.5511686E+01 6.2320 4 SO4-- 0.8841230E-12 -.1653054E-04 -.1585075E+01 7.9002 5 HCO3- 0.3189432E-06 0.1475355E-04 0.8985899E+00 3.5460 6 HS- 0.2878422E-04 0.4532024E-04 0.1496117E+01 5.5008 7 Al+++ 0.1102109E-28 0.5275905E-05 0.1420940E+00 0.7609 8 H4SiO4 0.7116053E-03 0.1419388E-01 0.1361780E+04 -3.1478 9 Ca++ 0.1432841E-06 0.2433575E-06 0.9735622E-02 13.1066 10 Mg++ 0.2275212E-10 0.9787770E-10 0.2375294E-05 9.3054 11 Fe++ 0.6223355E-13 0.3790598E-07 0.2113102E-02 6.7429 12 K+ 0.1615049E-03 0.1622814E-03 0.6334035E+01 6.2505 13 Na+ 0.2053295E-01 0.2312428E-01 0.5306598E+03 8.3540 14 Mn++ 0.1986412E-10 0.2621967E-08 0.1437848E-03 9.2473 15 HPO4-- 0.4874614E-07 0.4999795E-07 0.4790064E-02 12.6416 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1854551E+02 -.2048183E-01 -.1852503E+02 0.0000000E+00 2 H2O 0.4146860E+02 0.4917074E+02 -.7702133E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3106449E-01 -.1464422E-04 0.3107914E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3103899E-01 0.4014869E-04 -.3107914E-01 0.0000000E+00 7 Al+++ 0.3652027E+01 0.4673864E-05 0.3652023E+01 0.0000000E+00 8 H4SiO4 0.1166231E+02 0.1257420E-01 0.1164973E+02 0.0000000E+00 9 Ca++ 0.1288173E+01 0.2155877E-06 0.1288173E+01 0.0000000E+00 10 Mg++ 0.8888881E+00 0.8670875E-10 0.8888881E+00 0.0000000E+00 11 Fe++ 0.7985689E+00 0.3358048E-07 0.7985689E+00 0.0000000E+00 12 K+ 0.2377917E+00 0.1437632E-03 0.2376480E+00 0.0000000E+00 13 Na+ 0.1406032E+01 0.2048554E-01 0.1385546E+01 0.0000000E+00 14 Mn++ 0.1941921E-01 0.2322771E-08 0.1941921E-01 0.0000000E+00 15 HPO4-- 0.6627680E-02 0.4429262E-07 0.6627636E-02 0.0000000E+00 Chg. balance for solid moles: -.1421E-14 Mass of aqueous solution: 0.887496E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1119.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.384 0.141 363.0 2.560 29.67 139.4 andradite 0.1243 -0.905 63.18 1.801 5.164 16.41 grossular 0.2969E-01 -1.527 13.37 1.126 1.093 3.721 apatite-OH 0.2209E-02 -2.656 1.110 0.045 0.9071E-01 0.3526 clinochlore 0.1606 -0.794 89.28 1.951 7.298 33.96 daphnite 0.4603E-01 -1.337 32.85 1.516 2.685 9.953 chlorite-Mn 0.3884E-02 -2.411 2.754 0.440 0.2251 0.8775 diopside 0.5529E-01 -1.257 11.97 1.078 0.9787 3.660 hedenbergite 0.1416E-01 -1.849 3.514 0.546 0.2872 0.9625 microcline 0.2081 -0.682 57.93 1.763 4.735 22.63 stilbite 0.7289 -0.137 513.6 2.711 41.98 239.6 stilpnomelane-Fe 0.5902E-01 -1.229 63.62 1.804 5.200 21.98 tr.625ac.25prg.125 0.8396E-02 -2.076 7.177 0.856 0.5866 2.310 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1845E-01 0.1845E-01 1.0000 -1.734 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1223.447943 g Volume = 495.753627 cm3 Porosity: -10.4129% V(tot) - V(min): -.46754E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1119.9990000 g log = 3.0492 Original solution: 1000.0103000 g Original solution / Rock added: 0.89 (Water/Rock Ratio), log = -0.0492 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0888 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9666E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4247E-08 1.0071 0.4657E-08 0.4624E-08 CH4,gas 0.1972E-01 1.0128 0.2175E-01 0.2147E-01 H2,gas 0.1369E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1470E-06 0.9958 0.1594E-06 0.1600E-06 S2,gas 0.3929E-29 1.0000 0.4278E-29 0.4278E-29 CO,gas 0.1652E-13 1.0000 0.1799E-13 0.1799E-13 SO3,gas 0.8989E-48 1.0000 0.9787E-48 0.9787E-48 SO2,gas 0.5071E-27 1.0000 0.5521E-27 0.5521E-27 HCl,gas 0.2987E-17 1.0000 0.3252E-17 0.3252E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.70 -10.33 -3.444 0.17641E+05 -8.332 3 CH4,gas 4.81 1.15 -3.66 -0.916 0.62537E+04 -1.663 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.74 -8.80 -4.399 0.15022E+05 -6.798 6 S2,gas -7.03 -38.40 -31.37 -4.826 0.53561E+05 -29.369 7 CO,gas 3.51 -12.23 -15.75 -4.845 0.26884E+05 -13.745 8 SO3,gas 17.43 -32.58 -50.01 -12.502 0.85390E+05 -48.009 9 SO2,gas 1.14 -28.12 -29.26 -7.802 0.49957E+05 -27.258 10 HCl,gas 5.48 -14.01 -19.49 -9.744 0.33275E+05 -17.488 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80755E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94122E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28383E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76234E+04 35 aragonite 0.99 -3.59 -4.57 -1.525 0.78113E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55855E+04 37 calcite 0.83 -3.59 -4.42 -1.474 0.75500E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70325E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82192E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68649E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70377E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65598E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36457E+04 66 diamond -3.11 -7.77 -4.67 -1.333 0.79687E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33651E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66053E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.77 -4.23 -1.207 0.72149E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60997E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59770E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16001E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22973E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82312E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61283E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53667E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36602E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20055E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92769E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40693E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43442E+04 143 pyrrhotite -4.24 -8.00 -3.75 -1.251 0.64096E+04 144 pyrrhotiteFe0.875 -6.00 -9.39 -3.39 -1.248 0.57924E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22479E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28303E+03 152 rhodonite 7.46 6.10 -1.36 -0.273 0.23272E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27394E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.77 -0.395 0.47231E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91033E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65757E+04 181 troilite-low -4.39 -8.00 -3.60 -1.201 0.61528E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80415E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34509E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66778E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60335E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73634E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57934E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83182E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61760E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66246E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52964E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.49 -4.53 -1.510 0.77359E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62641E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14892E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1119.9990000 g New total amount of reactant added: 1159.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1159.9990000 Water: Moles liquid = 0.4895E+02 kg liquid = 0.8819E+00 Moles total = 0.4097E+02 kg total = 0.7380E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174395E-01 Osmotic coef. = 0.9688 True ionic strength = .2069615E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90309E-10 -10.0443 0.75764E-10 -10.1205 0.83894E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15573E-03 -3.8076 0.12985E-03 -3.8866 0.83379E+00 -0.0789 4 SO4-- 0.88816E-12 -12.0515 0.45818E-12 -12.3390 0.51588E+00 -0.2875 5 HCO3- 0.32040E-06 -6.4943 0.26754E-06 -6.5726 0.83503E+00 -0.0783 6 HS- 0.28915E-04 -4.5389 0.24113E-04 -4.6178 0.83391E+00 -0.0789 7 Al+++ 0.11022E-28 -28.9577 0.25080E-29 -29.6007 0.22755E+00 -0.6429 8 H4SiO4 0.71161E-03 -3.1478 0.71161E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14329E-06 -6.8438 0.73366E-07 -7.1345 0.51201E+00 -0.2907 10 Mg++ 0.22753E-10 -10.6430 0.11595E-10 -10.9357 0.50962E+00 -0.2928 11 Fe++ 0.62237E-13 -13.2060 0.31752E-13 -13.4982 0.51019E+00 -0.2923 12 K+ 0.16151E-03 -3.7918 0.13490E-03 -3.8700 0.83523E+00 -0.0782 13 Na+ 0.20533E-01 -1.6875 0.17117E-01 -1.7666 0.83363E+00 -0.0790 14 Mn++ 0.19871E-10 -10.7018 0.10146E-10 -10.9937 0.51062E+00 -0.2919 15 HPO4-- 0.48745E-07 -7.3121 0.25150E-07 -7.5995 0.51595E+00 -0.2874 16 HSiO3- 0.10991E-01 -1.9590 0.91639E-02 -2.0379 0.83379E+00 -0.0789 17 Ca(HSiO3)+ 0.18031E-07 -7.7440 0.15063E-07 -7.8221 0.83541E+00 -0.0781 18 Mg(HSiO3)+ 0.35466E-11 -11.4502 0.29629E-11 -11.5283 0.83541E+00 -0.0781 19 NaHSiO3,aq 0.24913E-02 -2.6036 0.24913E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67517E-16 -16.1706 0.56405E-16 -16.2487 0.83541E+00 -0.0781 22 HAlO2,aq 0.14898E-09 -9.8269 0.14898E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52756E-05 -5.2777 0.43906E-05 -5.3575 0.83226E+00 -0.0797 24 CH4,aq 0.13866E-04 -4.8581 0.13816E-04 -4.8596 0.99642E+00 -0.0016 25 C2H6,aq 0.30388E-14 -14.5173 0.30280E-14 -14.5188 0.99642E+00 -0.0016 29 CO,aq 0.11443E-16 -16.9414 0.11443E-16 -16.9414 0.10000E+01 0.0000 30 CO2,aq 0.41015E-10 -10.3871 0.40868E-10 -10.3886 0.99642E+00 -0.0016 31 CO3-2 0.63428E-06 -6.1977 0.32650E-06 -6.4861 0.51476E+00 -0.2884 32 CaCO3,aq 0.29338E-09 -9.5326 0.29338E-09 -9.5326 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.59202E-12 -12.2277 0.49458E-12 -12.3058 0.83541E+00 -0.0781 34 CaCl+ 0.18171E-10 -10.7406 0.15180E-10 -10.8187 0.83541E+00 -0.0781 35 CaCl2,aq 0.45893E-15 -15.3383 0.45893E-15 -15.3383 0.10000E+01 0.0000 36 CaOH+ 0.81734E-07 -7.0876 0.68281E-07 -7.1657 0.83541E+00 -0.0781 37 CaSO4,aq 0.10474E-16 -16.9799 0.10474E-16 -16.9799 0.10000E+01 0.0000 38 HCl,aq 0.18504E-14 -14.7327 0.18504E-14 -14.7327 0.10000E+01 0.0000 43 FeCl+ 0.76866E-17 -17.1143 0.64215E-17 -17.1924 0.83541E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16631E-10 -10.7791 0.13894E-10 -10.8572 0.83541E+00 -0.0781 48 HFeO2- 0.37245E-07 -7.4289 0.31055E-07 -7.5079 0.83379E+00 -0.0789 49 FeO+ 0.12275E-16 -16.9110 0.10254E-16 -16.9891 0.83541E+00 -0.0781 51 FeO2- 0.42110E-09 -9.3756 0.35111E-09 -9.4546 0.83379E+00 -0.0789 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10872E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.31014E-09 -9.5084 0.31014E-09 -9.5084 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11421E-14 -14.9423 0.95223E-15 -15.0213 0.83379E+00 -0.0789 58 MgCO3,aq 0.11586E-13 -13.9360 0.11586E-13 -13.9360 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.95415E-16 -16.0204 0.79710E-16 -16.0985 0.83541E+00 -0.0781 60 MgCl+ 0.26071E-14 -14.5838 0.21780E-14 -14.6619 0.83541E+00 -0.0781 61 MgOH+ 0.71566E-10 -10.1453 0.59787E-10 -10.2234 0.83541E+00 -0.0781 63 MnO,aq 0.18660E-08 -8.7291 0.18660E-08 -8.7291 0.10000E+01 0.0000 64 MnOH+ 0.49370E-09 -9.3065 0.41244E-09 -9.3846 0.83541E+00 -0.0781 65 MnO2-2 0.21840E-10 -10.6608 0.11242E-10 -10.9491 0.51476E+00 -0.2884 66 HMnO2- 0.22133E-09 -9.6550 0.18454E-09 -9.7339 0.83379E+00 -0.0789 69 MnCl+ 0.95445E-14 -14.0202 0.79736E-14 -14.0983 0.83541E+00 -0.0781 71 NaCl,aq 0.72573E-06 -6.1392 0.72573E-06 -6.1392 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95129E-02 -2.0217 0.79172E-02 -2.1014 0.83226E+00 -0.0797 79 HPO3-2 0.16777E-14 -14.7753 0.86362E-15 -15.0637 0.51476E+00 -0.2884 81 H2PO3- 0.15415E-18 -18.8121 0.12853E-18 -18.8910 0.83379E+00 -0.0789 82 H3PO4,aq 0.92941E-18 -18.0318 0.92941E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40027E-10 -10.3976 0.33406E-10 -10.4762 0.83459E+00 -0.0785 84 PO4-3 0.12117E-08 -8.9166 0.28990E-09 -9.5378 0.23924E+00 -0.6212 88 HP2O7-3 0.10378E-17 -17.9839 0.23639E-18 -18.6264 0.22779E+00 -0.6425 89 P2O7-4 0.10249E-16 -16.9893 0.76973E-18 -18.1137 0.75101E-01 -1.1244 90 H2S,aq 0.55087E-08 -8.2590 0.54890E-08 -8.2605 0.99642E+00 -0.0016 91 S2-2 0.22850E-14 -14.6411 0.11762E-14 -14.9295 0.51476E+00 -0.2884 97 SO3-2 0.13002E-17 -17.8860 0.67919E-18 -18.1680 0.52236E+00 -0.2820 99 HSO4- 0.38517E-19 -19.4143 0.32209E-19 -19.4920 0.83624E+00 -0.0777 Charge balance for all species = 0.3739E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9030896E-10 -.2311974E-01 -.2326111E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981180E+06 0.0000 3 Cl- 0.1557303E-03 0.1564564E-03 0.5536803E+01 6.2340 4 SO4-- 0.8881649E-12 -.1659342E-04 -.1591104E+01 7.9021 5 HCO3- 0.3204003E-06 0.1482078E-04 0.9026848E+00 3.5479 6 HS- 0.2891538E-04 0.4551431E-04 0.1502524E+01 5.5028 7 Al+++ 0.1102184E-28 0.5275746E-05 0.1420898E+00 0.7609 8 H4SiO4 0.7116077E-03 0.1419371E-01 0.1361764E+04 -3.1478 9 Ca++ 0.1432906E-06 0.2433675E-06 0.9736020E-02 13.1066 10 Mg++ 0.2275315E-10 0.9788021E-10 0.2375354E-05 9.3054 11 Fe++ 0.6223652E-13 0.3790518E-07 0.2113057E-02 6.7429 12 K+ 0.1615086E-03 0.1622851E-03 0.6334180E+01 6.2505 13 Na+ 0.2053342E-01 0.2312476E-01 0.5306709E+03 8.3540 14 Mn++ 0.1987075E-10 0.2622721E-08 0.1438262E-03 9.2474 15 HPO4-- 0.4874463E-07 0.4999639E-07 0.4789914E-02 12.6416 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1920785E+02 -.2038860E-01 -.1918746E+02 0.0000000E+00 2 H2O 0.4096719E+02 0.4894768E+02 -.7980495E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3217303E-01 -.1463324E-04 0.3218766E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3214753E-01 0.4013771E-04 -.3218766E-01 0.0000000E+00 7 Al+++ 0.3782457E+01 0.4652522E-05 0.3782452E+01 0.0000000E+00 8 H4SiO4 0.1207882E+02 0.1251701E-01 0.1206630E+02 0.0000000E+00 9 Ca++ 0.1334179E+01 0.2146185E-06 0.1334179E+01 0.0000000E+00 10 Mg++ 0.9206341E+00 0.8631762E-10 0.9206341E+00 0.0000000E+00 11 Fe++ 0.8270893E+00 0.3342744E-07 0.8270892E+00 0.0000000E+00 12 K+ 0.2462843E+00 0.1431143E-03 0.2461412E+00 0.0000000E+00 13 Na+ 0.1456241E+01 0.2039303E-01 0.1435848E+01 0.0000000E+00 14 Mn++ 0.2011275E-01 0.2312899E-08 0.2011275E-01 0.0000000E+00 15 HPO4-- 0.6864383E-02 0.4409031E-07 0.6864339E-02 0.0000000E+00 Chg. balance for solid moles: 0.6939E-17 Mass of aqueous solution: 0.883470E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1159.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.435 0.157 376.2 2.575 29.69 144.4 andradite 0.1288 -0.890 65.43 1.816 5.163 17.00 grossular 0.3075E-01 -1.512 13.85 1.141 1.093 3.854 apatite-OH 0.2288E-02 -2.641 1.149 0.060 0.9070E-01 0.3652 clinochlore 0.1663 -0.779 92.45 1.966 7.296 35.16 daphnite 0.4767E-01 -1.322 34.01 1.532 2.684 10.31 chlorite-Mn 0.4023E-02 -2.395 2.852 0.455 0.2251 0.9088 diopside 0.5761E-01 -1.240 12.48 1.096 0.9845 3.813 hedenbergite 0.1476E-01 -1.831 3.661 0.564 0.2889 1.003 microcline 0.2156 -0.666 60.00 1.778 4.735 23.44 stilbite 0.7545 -0.122 531.7 2.726 41.96 248.0 stilpnomelane-Fe 0.6113E-01 -1.214 65.90 1.819 5.201 22.76 tr.625ac.25prg.125 0.8669E-02 -2.062 7.410 0.870 0.5847 2.385 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1845E-01 0.1845E-01 1.0000 -1.734 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1267.150134 g Volume = 513.436170 cm3 Porosity: -10.4165% V(tot) - V(min): -.48437E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1159.9990000 g log = 3.0645 Original solution: 1000.0103000 g Original solution / Rock added: 0.86 (Water/Rock Ratio), log = -0.0645 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0889 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9665E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4266E-08 1.0071 0.4678E-08 0.4645E-08 CH4,gas 0.1981E-01 1.0128 0.2185E-01 0.2157E-01 H2,gas 0.1369E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1476E-06 0.9958 0.1601E-06 0.1608E-06 S2,gas 0.3965E-29 1.0000 0.4317E-29 0.4317E-29 CO,gas 0.1659E-13 1.0000 0.1807E-13 0.1807E-13 SO3,gas 0.9029E-48 1.0000 0.9832E-48 0.9832E-48 SO2,gas 0.5093E-27 1.0000 0.5546E-27 0.5546E-27 HCl,gas 0.3000E-17 1.0000 0.3267E-17 0.3267E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.69 -10.33 -3.443 0.17638E+05 -8.330 3 CH4,gas 4.81 1.15 -3.66 -0.915 0.62503E+04 -1.661 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.74 -8.80 -4.398 0.15018E+05 -6.796 6 S2,gas -7.03 -38.40 -31.36 -4.825 0.53555E+05 -29.365 7 CO,gas 3.51 -12.23 -15.74 -4.844 0.26881E+05 -13.743 8 SO3,gas 17.43 -32.58 -50.01 -12.502 0.85386E+05 -48.007 9 SO2,gas 1.14 -28.12 -29.26 -7.802 0.49954E+05 -27.256 10 HCl,gas 5.48 -14.01 -19.49 -9.743 0.33271E+05 -17.486 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80748E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94123E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28383E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76234E+04 35 aragonite 0.99 -3.59 -4.57 -1.524 0.78079E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55855E+04 37 calcite 0.83 -3.59 -4.42 -1.473 0.75466E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70325E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82192E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68649E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70377E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65596E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36457E+04 66 diamond -3.11 -7.77 -4.66 -1.333 0.79653E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33651E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66053E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.77 -4.22 -1.207 0.72115E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60997E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59770E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16001E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22973E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82310E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61283E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53668E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36602E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20056E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92769E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40693E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43442E+04 143 pyrrhotite -4.24 -8.00 -3.75 -1.251 0.64062E+04 144 pyrrhotiteFe0.875 -6.00 -9.39 -3.39 -1.247 0.57890E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22477E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28303E+03 152 rhodonite 7.46 6.10 -1.36 -0.273 0.23270E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27394E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.77 -0.395 0.47227E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91032E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65757E+04 181 troilite-low -4.39 -8.00 -3.60 -1.200 0.61494E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80416E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34509E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66778E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60335E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73634E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57934E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83182E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61760E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66246E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52964E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.49 -4.53 -1.510 0.77323E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62641E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14892E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1159.9990000 g New total amount of reactant added: 1199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1199.9990000 Water: Moles liquid = 0.4873E+02 kg liquid = 0.8779E+00 Moles total = 0.4047E+02 kg total = 0.7290E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174456E-01 Osmotic coef. = 0.9688 True ionic strength = .2069663E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90311E-10 -10.0443 0.75765E-10 -10.1205 0.83894E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15644E-03 -3.8056 0.13044E-03 -3.8846 0.83378E+00 -0.0789 4 SO4-- 0.89224E-12 -12.0495 0.46028E-12 -12.3370 0.51587E+00 -0.2875 5 HCO3- 0.32187E-06 -6.4923 0.26877E-06 -6.5706 0.83503E+00 -0.0783 6 HS- 0.29048E-04 -4.5369 0.24223E-04 -4.6158 0.83391E+00 -0.0789 7 Al+++ 0.11023E-28 -28.9577 0.25081E-29 -29.6007 0.22754E+00 -0.6429 8 H4SiO4 0.71161E-03 -3.1478 0.71161E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14330E-06 -6.8438 0.73369E-07 -7.1345 0.51200E+00 -0.2907 10 Mg++ 0.22754E-10 -10.6429 0.11596E-10 -10.9357 0.50961E+00 -0.2928 11 Fe++ 0.62240E-13 -13.2059 0.31754E-13 -13.4982 0.51018E+00 -0.2923 12 K+ 0.16151E-03 -3.7918 0.13490E-03 -3.8700 0.83523E+00 -0.0782 13 Na+ 0.20534E-01 -1.6875 0.17118E-01 -1.7666 0.83363E+00 -0.0790 14 Mn++ 0.19877E-10 -10.7016 0.10150E-10 -10.9936 0.51061E+00 -0.2919 15 HPO4-- 0.48743E-07 -7.3121 0.25149E-07 -7.5995 0.51595E+00 -0.2874 16 HSiO3- 0.10991E-01 -1.9590 0.91638E-02 -2.0379 0.83378E+00 -0.0789 17 Ca(HSiO3)+ 0.18032E-07 -7.7440 0.15064E-07 -7.8221 0.83541E+00 -0.0781 18 Mg(HSiO3)+ 0.35467E-11 -11.4502 0.29630E-11 -11.5283 0.83541E+00 -0.0781 19 NaHSiO3,aq 0.24913E-02 -2.6036 0.24913E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67518E-16 -16.1706 0.56405E-16 -16.2487 0.83541E+00 -0.0781 22 HAlO2,aq 0.14898E-09 -9.8269 0.14898E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52754E-05 -5.2777 0.43905E-05 -5.3575 0.83225E+00 -0.0797 24 CH4,aq 0.13929E-04 -4.8561 0.13879E-04 -4.8576 0.99642E+00 -0.0016 25 C2H6,aq 0.30668E-14 -14.5133 0.30558E-14 -14.5149 0.99642E+00 -0.0016 29 CO,aq 0.11496E-16 -16.9394 0.11496E-16 -16.9394 0.10000E+01 0.0000 30 CO2,aq 0.41204E-10 -10.3851 0.41057E-10 -10.3866 0.99642E+00 -0.0016 31 CO3-2 0.63718E-06 -6.1957 0.32799E-06 -6.4841 0.51476E+00 -0.2884 32 CaCO3,aq 0.29473E-09 -9.5306 0.29473E-09 -9.5306 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.59476E-12 -12.2257 0.49687E-12 -12.3038 0.83541E+00 -0.0781 34 CaCl+ 0.18255E-10 -10.7386 0.15250E-10 -10.8167 0.83541E+00 -0.0781 35 CaCl2,aq 0.46316E-15 -15.3343 0.46316E-15 -15.3343 0.10000E+01 0.0000 36 CaOH+ 0.81735E-07 -7.0876 0.68282E-07 -7.1657 0.83541E+00 -0.0781 37 CaSO4,aq 0.10522E-16 -16.9779 0.10522E-16 -16.9779 0.10000E+01 0.0000 38 HCl,aq 0.18589E-14 -14.7307 0.18589E-14 -14.7307 0.10000E+01 0.0000 43 FeCl+ 0.77221E-17 -17.1123 0.64511E-17 -17.1904 0.83541E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16632E-10 -10.7791 0.13894E-10 -10.8572 0.83541E+00 -0.0781 48 HFeO2- 0.37245E-07 -7.4289 0.31054E-07 -7.5079 0.83378E+00 -0.0789 49 FeO+ 0.12275E-16 -16.9110 0.10255E-16 -16.9891 0.83541E+00 -0.0781 51 FeO2- 0.42110E-09 -9.3756 0.35110E-09 -9.4546 0.83378E+00 -0.0789 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10872E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.31157E-09 -9.5064 0.31157E-09 -9.5064 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11473E-14 -14.9403 0.95661E-15 -15.0193 0.83378E+00 -0.0789 58 MgCO3,aq 0.11640E-13 -13.9341 0.11640E-13 -13.9341 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.95856E-16 -16.0184 0.80079E-16 -16.0965 0.83541E+00 -0.0781 60 MgCl+ 0.26192E-14 -14.5818 0.21881E-14 -14.6599 0.83541E+00 -0.0781 61 MgOH+ 0.71567E-10 -10.1453 0.59788E-10 -10.2234 0.83541E+00 -0.0781 63 MnO,aq 0.18665E-08 -8.7290 0.18665E-08 -8.7290 0.10000E+01 0.0000 64 MnOH+ 0.49385E-09 -9.3064 0.41256E-09 -9.3845 0.83541E+00 -0.0781 65 MnO2-2 0.21845E-10 -10.6607 0.11245E-10 -10.9491 0.51476E+00 -0.2884 66 HMnO2- 0.22138E-09 -9.6549 0.18459E-09 -9.7338 0.83378E+00 -0.0789 69 MnCl+ 0.95912E-14 -14.0181 0.80126E-14 -14.0962 0.83541E+00 -0.0781 71 NaCl,aq 0.72907E-06 -6.1372 0.72907E-06 -6.1372 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95127E-02 -2.0217 0.79170E-02 -2.1014 0.83225E+00 -0.0797 79 HPO3-2 0.16777E-14 -14.7753 0.86358E-15 -15.0637 0.51476E+00 -0.2884 81 H2PO3- 0.15415E-18 -18.8121 0.12853E-18 -18.8910 0.83378E+00 -0.0789 82 H3PO4,aq 0.92941E-18 -18.0318 0.92941E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40027E-10 -10.3977 0.33406E-10 -10.4762 0.83459E+00 -0.0785 84 PO4-3 0.12117E-08 -8.9166 0.28988E-09 -9.5378 0.23924E+00 -0.6212 88 HP2O7-3 0.10377E-17 -17.9839 0.23638E-18 -18.6264 0.22778E+00 -0.6425 89 P2O7-4 0.10249E-16 -16.9893 0.76967E-18 -18.1137 0.75099E-01 -1.1244 90 H2S,aq 0.55340E-08 -8.2570 0.55142E-08 -8.2585 0.99642E+00 -0.0016 91 S2-2 0.23060E-14 -14.6371 0.11870E-14 -14.9255 0.51476E+00 -0.2884 97 SO3-2 0.13062E-17 -17.8840 0.68230E-18 -18.1660 0.52236E+00 -0.2820 99 HSO4- 0.38694E-19 -19.4124 0.32358E-19 -19.4900 0.83624E+00 -0.0777 Charge balance for all species = 0.3758E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9031104E-10 -.2311937E-01 -.2326074E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981180E+06 0.0000 3 Cl- 0.1564432E-03 0.1571726E-03 0.5562150E+01 6.2359 4 SO4-- 0.8922419E-12 -.1665688E-04 -.1597189E+01 7.9041 5 HCO3- 0.3218701E-06 0.1488863E-04 0.9068171E+00 3.5499 6 HS- 0.2904776E-04 0.4571017E-04 0.1508989E+01 5.5048 7 Al+++ 0.1102260E-28 0.5275591E-05 0.1420856E+00 0.7609 8 H4SiO4 0.7116099E-03 0.1419354E-01 0.1361747E+04 -3.1478 9 Ca++ 0.1432972E-06 0.2433776E-06 0.9736423E-02 13.1066 10 Mg++ 0.2275419E-10 0.9788299E-10 0.2375422E-05 9.3054 11 Fe++ 0.6223952E-13 0.3790438E-07 0.2113012E-02 6.7429 12 K+ 0.1615123E-03 0.1622888E-03 0.6334325E+01 6.2505 13 Na+ 0.2053390E-01 0.2312525E-01 0.5306820E+03 8.3540 14 Mn++ 0.1987702E-10 0.2623426E-08 0.1438648E-03 9.2475 15 HPO4-- 0.4874309E-07 0.4999479E-07 0.4789760E-02 12.6416 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1987019E+02 -.2029537E-01 -.1984989E+02 0.0000000E+00 2 H2O 0.4046577E+02 0.4872463E+02 -.8258856E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3328157E-01 -.1462226E-04 0.3329619E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3325606E-01 0.4012673E-04 -.3329619E-01 0.0000000E+00 7 Al+++ 0.3912887E+01 0.4631184E-05 0.3912882E+01 0.0000000E+00 8 H4SiO4 0.1249533E+02 0.1245982E-01 0.1248287E+02 0.0000000E+00 9 Ca++ 0.1380185E+01 0.2136493E-06 0.1380184E+01 0.0000000E+00 10 Mg++ 0.9523802E+00 0.8592671E-10 0.9523802E+00 0.0000000E+00 11 Fe++ 0.8556096E+00 0.3327441E-07 0.8556096E+00 0.0000000E+00 12 K+ 0.2547769E+00 0.1424654E-03 0.2546344E+00 0.0000000E+00 13 Na+ 0.1506451E+01 0.2030053E-01 0.1486151E+01 0.0000000E+00 14 Mn++ 0.2080630E-01 0.2302978E-08 0.2080630E-01 0.0000000E+00 15 HPO4-- 0.7101086E-02 0.4388799E-07 0.7101042E-02 0.0000000E+00 Chg. balance for solid moles: -.5218E-14 Mass of aqueous solution: 0.879444E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.485 0.172 389.4 2.590 29.71 149.5 andradite 0.1332 -0.876 67.68 1.830 5.163 17.58 grossular 0.3181E-01 -1.497 14.33 1.156 1.093 3.986 apatite-OH 0.2367E-02 -2.626 1.189 0.075 0.9070E-01 0.3778 clinochlore 0.1720 -0.764 95.61 1.980 7.294 36.37 daphnite 0.4930E-01 -1.307 35.17 1.546 2.683 10.66 chlorite-Mn 0.4161E-02 -2.381 2.950 0.470 0.2251 0.9402 diopside 0.5992E-01 -1.222 12.98 1.113 0.9899 3.966 hedenbergite 0.1535E-01 -1.814 3.808 0.581 0.2905 1.043 microcline 0.2230 -0.652 62.07 1.793 4.735 24.25 stilbite 0.7802 -0.108 549.8 2.740 41.95 256.5 stilpnomelane-Fe 0.6325E-01 -1.199 68.18 1.834 5.201 23.55 tr.625ac.25prg.125 0.8941E-02 -2.049 7.643 0.883 0.5830 2.460 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1846E-01 0.1846E-01 1.0000 -1.734 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1310.852326 g Volume = 531.118713 cm3 Porosity: -10.4198% V(tot) - V(min): -.50119E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1199.9990000 g log = 3.0792 Original solution: 1000.0103000 g Original solution / Rock added: 0.83 (Water/Rock Ratio), log = -0.0792 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0890 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9664E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4285E-08 1.0071 0.4700E-08 0.4666E-08 CH4,gas 0.1990E-01 1.0128 0.2195E-01 0.2167E-01 H2,gas 0.1368E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1483E-06 0.9958 0.1608E-06 0.1615E-06 S2,gas 0.4001E-29 1.0000 0.4357E-29 0.4357E-29 CO,gas 0.1667E-13 1.0000 0.1815E-13 0.1815E-13 SO3,gas 0.9070E-48 1.0000 0.9878E-48 0.9878E-48 SO2,gas 0.5117E-27 1.0000 0.5572E-27 0.5572E-27 HCl,gas 0.3014E-17 1.0000 0.3282E-17 0.3282E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.97059E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.69 -10.33 -3.443 0.17635E+05 -8.328 3 CH4,gas 4.81 1.15 -3.66 -0.915 0.62470E+04 -1.659 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.74 -8.79 -4.397 0.15015E+05 -6.794 6 S2,gas -7.03 -38.39 -31.36 -4.825 0.53548E+05 -29.361 7 CO,gas 3.51 -12.23 -15.74 -4.843 0.26877E+05 -13.741 8 SO3,gas 17.43 -32.58 -50.01 -12.501 0.85383E+05 -48.005 9 SO2,gas 1.14 -28.12 -29.25 -7.801 0.49950E+05 -27.254 10 HCl,gas 5.48 -14.01 -19.48 -9.742 0.33268E+05 -17.484 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80743E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94123E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28383E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76234E+04 35 aragonite 0.99 -3.58 -4.57 -1.524 0.78045E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55855E+04 37 calcite 0.83 -3.58 -4.42 -1.473 0.75432E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70325E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82192E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68649E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70377E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65594E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36457E+04 66 diamond -3.11 -7.77 -4.66 -1.332 0.79619E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33651E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66053E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.77 -4.22 -1.206 0.72081E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60997E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59770E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16001E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22973E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82308E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61283E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53668E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36602E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20056E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92770E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40694E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43442E+04 143 pyrrhotite -4.24 -7.99 -3.75 -1.250 0.64028E+04 144 pyrrhotiteFe0.875 -6.00 -9.39 -3.39 -1.246 0.57856E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22475E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28303E+03 152 rhodonite 7.46 6.10 -1.36 -0.273 0.23268E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27394E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.77 -0.395 0.47223E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91032E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65757E+04 181 troilite-low -4.39 -7.99 -3.60 -1.200 0.61460E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80417E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34509E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66778E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60334E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73634E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57934E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61760E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66246E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52964E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.49 -4.53 -1.509 0.77287E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62641E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14892E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1199.9990000 g New total amount of reactant added: 1239.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1239.9990000 Water: Moles liquid = 0.4850E+02 kg liquid = 0.8738E+00 Moles total = 0.3996E+02 kg total = 0.7200E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174517E-01 Osmotic coef. = 0.9688 True ionic strength = .2069711E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90313E-10 -10.0442 0.75767E-10 -10.1205 0.83894E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15716E-03 -3.8037 0.13104E-03 -3.8826 0.83378E+00 -0.0789 4 SO4-- 0.89635E-12 -12.0475 0.46240E-12 -12.3350 0.51587E+00 -0.2875 5 HCO3- 0.32335E-06 -6.4903 0.27001E-06 -6.5686 0.83503E+00 -0.0783 6 HS- 0.29181E-04 -4.5349 0.24335E-04 -4.6138 0.83391E+00 -0.0789 7 Al+++ 0.11023E-28 -28.9577 0.25083E-29 -29.6006 0.22754E+00 -0.6429 8 H4SiO4 0.71161E-03 -3.1478 0.71161E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14330E-06 -6.8437 0.73372E-07 -7.1345 0.51200E+00 -0.2907 10 Mg++ 0.22755E-10 -10.6429 0.11596E-10 -10.9357 0.50961E+00 -0.2928 11 Fe++ 0.62243E-13 -13.2059 0.31755E-13 -13.4982 0.51018E+00 -0.2923 12 K+ 0.16152E-03 -3.7918 0.13490E-03 -3.8700 0.83523E+00 -0.0782 13 Na+ 0.20534E-01 -1.6875 0.17118E-01 -1.7665 0.83363E+00 -0.0790 14 Mn++ 0.19883E-10 -10.7015 0.10152E-10 -10.9934 0.51061E+00 -0.2919 15 HPO4-- 0.48742E-07 -7.3121 0.25148E-07 -7.5995 0.51595E+00 -0.2874 16 HSiO3- 0.10990E-01 -1.9590 0.91636E-02 -2.0379 0.83378E+00 -0.0789 17 Ca(HSiO3)+ 0.18032E-07 -7.7440 0.15064E-07 -7.8221 0.83541E+00 -0.0781 18 Mg(HSiO3)+ 0.35468E-11 -11.4502 0.29630E-11 -11.5283 0.83541E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67519E-16 -16.1706 0.56406E-16 -16.2487 0.83541E+00 -0.0781 22 HAlO2,aq 0.14898E-09 -9.8269 0.14898E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52753E-05 -5.2778 0.43904E-05 -5.3575 0.83225E+00 -0.0797 24 CH4,aq 0.13993E-04 -4.8541 0.13943E-04 -4.8556 0.99642E+00 -0.0016 25 C2H6,aq 0.30950E-14 -14.5093 0.30840E-14 -14.5109 0.99642E+00 -0.0016 29 CO,aq 0.11549E-16 -16.9374 0.11549E-16 -16.9374 0.10000E+01 0.0000 30 CO2,aq 0.41395E-10 -10.3831 0.41247E-10 -10.3846 0.99642E+00 -0.0016 31 CO3-2 0.64010E-06 -6.1938 0.32949E-06 -6.4822 0.51475E+00 -0.2884 32 CaCO3,aq 0.29609E-09 -9.5286 0.29609E-09 -9.5286 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.59752E-12 -12.2236 0.49918E-12 -12.3017 0.83541E+00 -0.0781 34 CaCl+ 0.18339E-10 -10.7366 0.15321E-10 -10.8147 0.83541E+00 -0.0781 35 CaCl2,aq 0.46745E-15 -15.3303 0.46745E-15 -15.3303 0.10000E+01 0.0000 36 CaOH+ 0.81737E-07 -7.0876 0.68284E-07 -7.1657 0.83541E+00 -0.0781 37 CaSO4,aq 0.10571E-16 -16.9759 0.10571E-16 -16.9759 0.10000E+01 0.0000 38 HCl,aq 0.18675E-14 -14.7287 0.18675E-14 -14.7287 0.10000E+01 0.0000 43 FeCl+ 0.77579E-17 -17.1103 0.64810E-17 -17.1884 0.83541E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16632E-10 -10.7791 0.13895E-10 -10.8572 0.83541E+00 -0.0781 48 HFeO2- 0.37244E-07 -7.4289 0.31053E-07 -7.5079 0.83378E+00 -0.0789 49 FeO+ 0.12275E-16 -16.9110 0.10255E-16 -16.9891 0.83541E+00 -0.0781 51 FeO2- 0.42109E-09 -9.3756 0.35110E-09 -9.4546 0.83378E+00 -0.0789 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10872E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.31301E-09 -9.5044 0.31301E-09 -9.5044 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11526E-14 -14.9383 0.96104E-15 -15.0173 0.83378E+00 -0.0789 58 MgCO3,aq 0.11694E-13 -13.9320 0.11694E-13 -13.9320 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.96302E-16 -16.0164 0.80451E-16 -16.0945 0.83541E+00 -0.0781 60 MgCl+ 0.26313E-14 -14.5798 0.21982E-14 -14.6579 0.83541E+00 -0.0781 61 MgOH+ 0.71569E-10 -10.1453 0.59789E-10 -10.2234 0.83541E+00 -0.0781 63 MnO,aq 0.18669E-08 -8.7289 0.18669E-08 -8.7289 0.10000E+01 0.0000 64 MnOH+ 0.49398E-09 -9.3063 0.41267E-09 -9.3844 0.83541E+00 -0.0781 65 MnO2-2 0.21849E-10 -10.6606 0.11247E-10 -10.9490 0.51475E+00 -0.2884 66 HMnO2- 0.22144E-09 -9.6548 0.18463E-09 -9.7337 0.83378E+00 -0.0789 69 MnCl+ 0.96381E-14 -14.0160 0.80518E-14 -14.0941 0.83541E+00 -0.0781 71 NaCl,aq 0.73244E-06 -6.1352 0.73244E-06 -6.1352 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95125E-02 -2.0217 0.79168E-02 -2.1014 0.83225E+00 -0.0797 79 HPO3-2 0.16776E-14 -14.7753 0.86354E-15 -15.0637 0.51475E+00 -0.2884 81 H2PO3- 0.15414E-18 -18.8121 0.12852E-18 -18.8910 0.83378E+00 -0.0789 82 H3PO4,aq 0.92942E-18 -18.0318 0.92942E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40026E-10 -10.3977 0.33405E-10 -10.4762 0.83459E+00 -0.0785 84 PO4-3 0.12116E-08 -8.9166 0.28986E-09 -9.5378 0.23924E+00 -0.6212 88 HP2O7-3 0.10377E-17 -17.9839 0.23637E-18 -18.6264 0.22778E+00 -0.6425 89 P2O7-4 0.10248E-16 -16.9894 0.76961E-18 -18.1137 0.75097E-01 -1.1244 90 H2S,aq 0.55596E-08 -8.2550 0.55397E-08 -8.2565 0.99642E+00 -0.0016 91 S2-2 0.23273E-14 -14.6332 0.11980E-14 -14.9216 0.51475E+00 -0.2884 97 SO3-2 0.13122E-17 -17.8820 0.68544E-18 -18.1640 0.52236E+00 -0.2820 99 HSO4- 0.38873E-19 -19.4103 0.32507E-19 -19.4880 0.83624E+00 -0.0777 Charge balance for all species = 0.3774E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9031313E-10 -.2311900E-01 -.2326037E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981179E+06 0.0000 3 Cl- 0.1571627E-03 0.1578954E-03 0.5587729E+01 6.2379 4 SO4-- 0.8963546E-12 -.1672092E-04 -.1603330E+01 7.9061 5 HCO3- 0.3233528E-06 0.1495710E-04 0.9109875E+00 3.5519 6 HS- 0.2918134E-04 0.4590783E-04 0.1515514E+01 5.5067 7 Al+++ 0.1102337E-28 0.5275438E-05 0.1420815E+00 0.7609 8 H4SiO4 0.7116121E-03 0.1419336E-01 0.1361730E+04 -3.1478 9 Ca++ 0.1433039E-06 0.2433878E-06 0.9736831E-02 13.1066 10 Mg++ 0.2275525E-10 0.9788566E-10 0.2375487E-05 9.3054 11 Fe++ 0.6224254E-13 0.3790358E-07 0.2112968E-02 6.7429 12 K+ 0.1615160E-03 0.1622925E-03 0.6334471E+01 6.2505 13 Na+ 0.2053438E-01 0.2312573E-01 0.5306932E+03 8.3540 14 Mn++ 0.1988296E-10 0.2624087E-08 0.1439010E-03 9.2476 15 HPO4-- 0.4874152E-07 0.4999316E-07 0.4789605E-02 12.6415 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2053253E+02 -.2020214E-01 -.2051233E+02 0.0000000E+00 2 H2O 0.3996435E+02 0.4850157E+02 -.8537218E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3439010E-01 -.1461129E-04 0.3440472E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3436460E-01 0.4011576E-04 -.3440472E-01 0.0000000E+00 7 Al+++ 0.4043316E+01 0.4609850E-05 0.4043312E+01 0.0000000E+00 8 H4SiO4 0.1291184E+02 0.1240262E-01 0.1289944E+02 0.0000000E+00 9 Ca++ 0.1426190E+01 0.2126802E-06 0.1426190E+01 0.0000000E+00 10 Mg++ 0.9841262E+00 0.8553569E-10 0.9841262E+00 0.0000000E+00 11 Fe++ 0.8841299E+00 0.3312138E-07 0.8841299E+00 0.0000000E+00 12 K+ 0.2632694E+00 0.1418165E-03 0.2631276E+00 0.0000000E+00 13 Na+ 0.1556661E+01 0.2020802E-01 0.1536453E+01 0.0000000E+00 14 Mn++ 0.2149984E-01 0.2293013E-08 0.2149984E-01 0.0000000E+00 15 HPO4-- 0.7337789E-02 0.4368566E-07 0.7337745E-02 0.0000000E+00 Chg. balance for solid moles: 0.4483E-14 Mass of aqueous solution: 0.875418E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1239.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.535 0.186 402.6 2.605 29.72 154.5 andradite 0.1376 -0.861 69.94 1.845 5.163 18.17 grossular 0.3287E-01 -1.483 14.80 1.170 1.093 4.119 apatite-OH 0.2446E-02 -2.612 1.229 0.089 0.9070E-01 0.3904 clinochlore 0.1777 -0.750 98.77 1.995 7.292 37.57 daphnite 0.5093E-01 -1.293 36.34 1.560 2.683 11.01 chlorite-Mn 0.4300E-02 -2.367 3.049 0.484 0.2251 0.9715 diopside 0.6223E-01 -1.206 13.48 1.130 0.9950 4.119 hedenbergite 0.1594E-01 -1.797 3.955 0.597 0.2920 1.083 microcline 0.2304 -0.637 64.14 1.807 4.735 25.06 stilbite 0.8059 -0.094 567.9 2.754 41.93 264.9 stilpnomelane-Fe 0.6536E-01 -1.185 70.46 1.848 5.202 24.34 tr.625ac.25prg.125 0.9214E-02 -2.036 7.876 0.896 0.5814 2.535 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1846E-01 0.1846E-01 1.0000 -1.734 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1354.554517 g Volume = 548.801256 cm3 Porosity: -10.4229% V(tot) - V(min): -.51802E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1239.9990000 g log = 3.0934 Original solution: 1000.0103000 g Original solution / Rock added: 0.81 (Water/Rock Ratio), log = -0.0934 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0891 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9663E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4304E-08 1.0071 0.4721E-08 0.4688E-08 CH4,gas 0.1999E-01 1.0128 0.2205E-01 0.2177E-01 H2,gas 0.1368E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1490E-06 0.9958 0.1616E-06 0.1623E-06 S2,gas 0.4037E-29 1.0000 0.4397E-29 0.4397E-29 CO,gas 0.1674E-13 1.0000 0.1824E-13 0.1824E-13 SO3,gas 0.9112E-48 1.0000 0.9924E-48 0.9924E-48 SO2,gas 0.5140E-27 1.0000 0.5598E-27 0.5598E-27 HCl,gas 0.3028E-17 1.0000 0.3297E-17 0.3297E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.69 -10.33 -3.442 0.17631E+05 -8.326 3 CH4,gas 4.81 1.15 -3.66 -0.914 0.62435E+04 -1.657 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.73 -8.79 -4.396 0.15011E+05 -6.792 6 S2,gas -7.03 -38.39 -31.36 -4.824 0.53541E+05 -29.357 7 CO,gas 3.51 -12.23 -15.74 -4.843 0.26874E+05 -13.739 8 SO3,gas 17.43 -32.58 -50.00 -12.501 0.85379E+05 -48.003 9 SO2,gas 1.14 -28.12 -29.25 -7.801 0.49947E+05 -27.252 10 HCl,gas 5.48 -14.00 -19.48 -9.741 0.33265E+05 -17.482 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80737E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94123E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28383E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76234E+04 35 aragonite 0.99 -3.58 -4.57 -1.523 0.78011E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55855E+04 37 calcite 0.83 -3.58 -4.42 -1.472 0.75398E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70325E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82192E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68649E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70377E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65592E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36457E+04 66 diamond -3.11 -7.77 -4.66 -1.332 0.79585E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33651E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66053E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.77 -4.22 -1.206 0.72047E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60997E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59770E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16001E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22973E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82306E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61283E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53668E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36602E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20056E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92770E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40694E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43443E+04 143 pyrrhotite -4.24 -7.99 -3.75 -1.249 0.63994E+04 144 pyrrhotiteFe0.875 -6.00 -9.39 -3.39 -1.245 0.57822E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22473E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28303E+03 152 rhodonite 7.46 6.10 -1.36 -0.273 0.23266E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27394E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.77 -0.395 0.47219E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91032E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65757E+04 181 troilite-low -4.39 -7.99 -3.60 -1.199 0.61426E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80418E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34509E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66779E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60334E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57934E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52964E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.49 -4.52 -1.508 0.77251E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14892E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1239.9990000 g New total amount of reactant added: 1279.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1279.9990000 Water: Moles liquid = 0.4828E+02 kg liquid = 0.8698E+00 Moles total = 0.3946E+02 kg total = 0.7109E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174579E-01 Osmotic coef. = 0.9688 True ionic strength = .2069760E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90315E-10 -10.0442 0.75769E-10 -10.1205 0.83893E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15789E-03 -3.8016 0.13164E-03 -3.8806 0.83378E+00 -0.0789 4 SO4-- 0.90050E-12 -12.0455 0.46454E-12 -12.3330 0.51587E+00 -0.2875 5 HCO3- 0.32485E-06 -6.4883 0.27126E-06 -6.5666 0.83502E+00 -0.0783 6 HS- 0.29316E-04 -4.5329 0.24447E-04 -4.6118 0.83391E+00 -0.0789 7 Al+++ 0.11024E-28 -28.9577 0.25084E-29 -29.6006 0.22754E+00 -0.6429 8 H4SiO4 0.71161E-03 -3.1478 0.71161E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14331E-06 -6.8437 0.73375E-07 -7.1345 0.51200E+00 -0.2907 10 Mg++ 0.22756E-10 -10.6429 0.11597E-10 -10.9357 0.50961E+00 -0.2928 11 Fe++ 0.62246E-13 -13.2059 0.31756E-13 -13.4982 0.51018E+00 -0.2923 12 K+ 0.16152E-03 -3.7918 0.13491E-03 -3.8700 0.83522E+00 -0.0782 13 Na+ 0.20535E-01 -1.6875 0.17118E-01 -1.7665 0.83362E+00 -0.0790 14 Mn++ 0.19889E-10 -10.7014 0.10155E-10 -10.9933 0.51061E+00 -0.2919 15 HPO4-- 0.48740E-07 -7.3121 0.25147E-07 -7.5995 0.51594E+00 -0.2874 16 HSiO3- 0.10990E-01 -1.9590 0.91634E-02 -2.0379 0.83378E+00 -0.0789 17 Ca(HSiO3)+ 0.18032E-07 -7.7439 0.15064E-07 -7.8220 0.83541E+00 -0.0781 18 Mg(HSiO3)+ 0.35469E-11 -11.4502 0.29631E-11 -11.5283 0.83541E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67520E-16 -16.1706 0.56407E-16 -16.2487 0.83541E+00 -0.0781 22 HAlO2,aq 0.14897E-09 -9.8269 0.14897E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52751E-05 -5.2778 0.43902E-05 -5.3575 0.83225E+00 -0.0797 24 CH4,aq 0.14058E-04 -4.8521 0.14008E-04 -4.8536 0.99642E+00 -0.0016 25 C2H6,aq 0.31237E-14 -14.5053 0.31126E-14 -14.5069 0.99642E+00 -0.0016 29 CO,aq 0.11603E-16 -16.9354 0.11603E-16 -16.9354 0.10000E+01 0.0000 30 CO2,aq 0.41587E-10 -10.3810 0.41438E-10 -10.3826 0.99642E+00 -0.0016 31 CO3-2 0.64305E-06 -6.1918 0.33101E-06 -6.4802 0.51475E+00 -0.2884 32 CaCO3,aq 0.29747E-09 -9.5266 0.29747E-09 -9.5266 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.60031E-12 -12.2216 0.50151E-12 -12.2997 0.83541E+00 -0.0781 34 CaCl+ 0.18425E-10 -10.7346 0.15392E-10 -10.8127 0.83541E+00 -0.0781 35 CaCl2,aq 0.47180E-15 -15.3262 0.47180E-15 -15.3262 0.10000E+01 0.0000 36 CaOH+ 0.81738E-07 -7.0876 0.68285E-07 -7.1657 0.83541E+00 -0.0781 37 CaSO4,aq 0.10620E-16 -16.9739 0.10620E-16 -16.9739 0.10000E+01 0.0000 38 HCl,aq 0.18762E-14 -14.7267 0.18762E-14 -14.7267 0.10000E+01 0.0000 43 FeCl+ 0.77941E-17 -17.1082 0.65112E-17 -17.1863 0.83541E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16633E-10 -10.7790 0.13895E-10 -10.8571 0.83541E+00 -0.0781 48 HFeO2- 0.37243E-07 -7.4290 0.31052E-07 -7.5079 0.83378E+00 -0.0789 49 FeO+ 0.12276E-16 -16.9110 0.10255E-16 -16.9891 0.83541E+00 -0.0781 51 FeO2- 0.42108E-09 -9.3756 0.35109E-09 -9.4546 0.83378E+00 -0.0789 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9622 0.10872E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.31446E-09 -9.5024 0.31446E-09 -9.5024 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11580E-14 -14.9363 0.96550E-15 -15.0152 0.83378E+00 -0.0789 58 MgCO3,aq 0.11748E-13 -13.9300 0.11748E-13 -13.9300 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.96751E-16 -16.0143 0.80826E-16 -16.0924 0.83541E+00 -0.0781 60 MgCl+ 0.26436E-14 -14.5778 0.22085E-14 -14.6559 0.83541E+00 -0.0781 61 MgOH+ 0.71570E-10 -10.1453 0.59790E-10 -10.2234 0.83541E+00 -0.0781 63 MnO,aq 0.18674E-08 -8.7288 0.18674E-08 -8.7288 0.10000E+01 0.0000 64 MnOH+ 0.49411E-09 -9.3062 0.41278E-09 -9.3843 0.83541E+00 -0.0781 65 MnO2-2 0.21854E-10 -10.6605 0.11249E-10 -10.9489 0.51475E+00 -0.2884 66 HMnO2- 0.22148E-09 -9.6547 0.18467E-09 -9.7336 0.83378E+00 -0.0789 69 MnCl+ 0.96853E-14 -14.0139 0.80912E-14 -14.0920 0.83541E+00 -0.0781 71 NaCl,aq 0.73584E-06 -6.1332 0.73584E-06 -6.1332 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95123E-02 -2.0217 0.79167E-02 -2.1015 0.83225E+00 -0.0797 79 HPO3-2 0.16775E-14 -14.7753 0.86351E-15 -15.0637 0.51475E+00 -0.2884 81 H2PO3- 0.15414E-18 -18.8121 0.12852E-18 -18.8910 0.83378E+00 -0.0789 82 H3PO4,aq 0.92942E-18 -18.0318 0.92942E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40025E-10 -10.3977 0.33405E-10 -10.4762 0.83459E+00 -0.0785 84 PO4-3 0.12116E-08 -8.9167 0.28984E-09 -9.5378 0.23923E+00 -0.6212 88 HP2O7-3 0.10376E-17 -17.9839 0.23635E-18 -18.6264 0.22778E+00 -0.6425 89 P2O7-4 0.10248E-16 -16.9894 0.76955E-18 -18.1138 0.75095E-01 -1.1244 90 H2S,aq 0.55854E-08 -8.2529 0.55654E-08 -8.2545 0.99642E+00 -0.0016 91 S2-2 0.23489E-14 -14.6291 0.12091E-14 -14.9175 0.51475E+00 -0.2884 97 SO3-2 0.13183E-17 -17.8800 0.68860E-18 -18.1620 0.52235E+00 -0.2820 99 HSO4- 0.39054E-19 -19.4083 0.32658E-19 -19.4860 0.83624E+00 -0.0777 Charge balance for all species = 0.3791E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9031524E-10 -.2311863E-01 -.2325999E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981179E+06 0.0000 3 Cl- 0.1578888E-03 0.1586249E-03 0.5613545E+01 6.2399 4 SO4-- 0.9005037E-12 -.1678556E-04 -.1609528E+01 7.9080 5 HCO3- 0.3248486E-06 0.1502620E-04 0.9151964E+00 3.5539 6 HS- 0.2931617E-04 0.4610731E-04 0.1522100E+01 5.5087 7 Al+++ 0.1102416E-28 0.5275287E-05 0.1420774E+00 0.7609 8 H4SiO4 0.7116140E-03 0.1419318E-01 0.1361712E+04 -3.1478 9 Ca++ 0.1433107E-06 0.2433981E-06 0.9737243E-02 13.1066 10 Mg++ 0.2275632E-10 0.9788773E-10 0.2375537E-05 9.3054 11 Fe++ 0.6224559E-13 0.3790277E-07 0.2112923E-02 6.7429 12 K+ 0.1615198E-03 0.1622963E-03 0.6334618E+01 6.2505 13 Na+ 0.2053486E-01 0.2312622E-01 0.5307044E+03 8.3540 14 Mn++ 0.1988859E-10 0.2624706E-08 0.1439350E-03 9.2477 15 HPO4-- 0.4873993E-07 0.4999151E-07 0.4789446E-02 12.6415 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2119487E+02 -.2010890E-01 -.2117476E+02 0.0000000E+00 2 H2O 0.3946294E+02 0.4827852E+02 -.8815580E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3549864E-01 -.1460032E-04 0.3551324E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3547314E-01 0.4010479E-04 -.3551324E-01 0.0000000E+00 7 Al+++ 0.4173746E+01 0.4588519E-05 0.4173741E+01 0.0000000E+00 8 H4SiO4 0.1332835E+02 0.1234542E-01 0.1331601E+02 0.0000000E+00 9 Ca++ 0.1472196E+01 0.2117111E-06 0.1472196E+01 0.0000000E+00 10 Mg++ 0.1015872E+01 0.8514411E-10 0.1015872E+01 0.0000000E+00 11 Fe++ 0.9126503E+00 0.3296836E-07 0.9126503E+00 0.0000000E+00 12 K+ 0.2717620E+00 0.1411676E-03 0.2716208E+00 0.0000000E+00 13 Na+ 0.1606871E+01 0.2011551E-01 0.1586755E+01 0.0000000E+00 14 Mn++ 0.2219339E-01 0.2283006E-08 0.2219338E-01 0.0000000E+00 15 HPO4-- 0.7574492E-02 0.4348332E-07 0.7574449E-02 0.0000000E+00 Chg. balance for solid moles: 0.4457E-14 Mass of aqueous solution: 0.871392E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1279.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.586 0.200 415.8 2.619 29.73 159.6 andradite 0.1421 -0.848 72.19 1.858 5.163 18.76 grossular 0.3392E-01 -1.469 15.28 1.184 1.093 4.252 apatite-OH 0.2525E-02 -2.598 1.268 0.103 0.9070E-01 0.4030 clinochlore 0.1834 -0.737 101.9 2.008 7.290 38.77 daphnite 0.5256E-01 -1.279 37.50 1.574 2.682 11.36 chlorite-Mn 0.4439E-02 -2.353 3.147 0.498 0.2251 1.003 diopside 0.6455E-01 -1.190 13.98 1.145 0.9997 4.272 hedenbergite 0.1654E-01 -1.782 4.102 0.613 0.2934 1.124 microcline 0.2379 -0.624 66.21 1.821 4.735 25.86 stilbite 0.8316 -0.080 586.0 2.768 41.91 273.3 stilpnomelane-Fe 0.6747E-01 -1.171 72.74 1.862 5.202 25.12 tr.625ac.25prg.125 0.9486E-02 -2.023 8.109 0.909 0.5799 2.610 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1847E-01 0.1847E-01 1.0000 -1.734 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1398.256708 g Volume = 566.483798 cm3 Porosity: -10.4258% V(tot) - V(min): -.53484E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1279.9990000 g log = 3.1072 Original solution: 1000.0103000 g Original solution / Rock added: 0.78 (Water/Rock Ratio), log = -0.1072 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0892 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9662E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4324E-08 1.0071 0.4743E-08 0.4710E-08 CH4,gas 0.2008E-01 1.0128 0.2215E-01 0.2187E-01 H2,gas 0.1368E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1497E-06 0.9958 0.1623E-06 0.1630E-06 S2,gas 0.4075E-29 1.0000 0.4438E-29 0.4438E-29 CO,gas 0.1682E-13 1.0000 0.1832E-13 0.1832E-13 SO3,gas 0.9153E-48 1.0000 0.9970E-48 0.9970E-48 SO2,gas 0.5163E-27 1.0000 0.5624E-27 0.5624E-27 HCl,gas 0.3041E-17 1.0000 0.3313E-17 0.3313E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.69 -10.32 -3.441 0.17628E+05 -8.324 3 CH4,gas 4.81 1.15 -3.65 -0.914 0.62401E+04 -1.655 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.73 -8.79 -4.395 0.15008E+05 -6.790 6 S2,gas -7.03 -38.39 -31.35 -4.824 0.53534E+05 -29.353 7 CO,gas 3.51 -12.23 -15.74 -4.842 0.26871E+05 -13.737 8 SO3,gas 17.43 -32.57 -50.00 -12.500 0.85376E+05 -48.001 9 SO2,gas 1.14 -28.11 -29.25 -7.800 0.49943E+05 -27.250 10 HCl,gas 5.48 -14.00 -19.48 -9.740 0.33261E+05 -17.480 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80732E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94123E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28383E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.58 -4.57 -1.522 0.77977E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.58 -4.41 -1.471 0.75363E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70325E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82192E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70377E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65591E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36457E+04 66 diamond -3.11 -7.77 -4.66 -1.331 0.79551E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33651E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66053E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.77 -4.22 -1.205 0.72013E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60997E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59770E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16001E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22973E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82304E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61283E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53668E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36602E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20056E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92770E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40694E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43443E+04 143 pyrrhotite -4.24 -7.99 -3.75 -1.249 0.63960E+04 144 pyrrhotiteFe0.875 -6.00 -9.39 -3.38 -1.245 0.57788E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22472E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28302E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23264E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27394E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.77 -0.395 0.47216E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91032E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65757E+04 181 troilite-low -4.39 -7.99 -3.60 -1.198 0.61392E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80418E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34509E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66779E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60334E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52964E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.48 -4.52 -1.507 0.77215E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1279.9990000 g New total amount of reactant added: 1319.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1319.9990000 Water: Moles liquid = 0.4806E+02 kg liquid = 0.8658E+00 Moles total = 0.3896E+02 kg total = 0.7019E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174641E-01 Osmotic coef. = 0.9688 True ionic strength = .2069809E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90317E-10 -10.0442 0.75770E-10 -10.1205 0.83893E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15862E-03 -3.7996 0.13226E-03 -3.8786 0.83378E+00 -0.0789 4 SO4-- 0.90469E-12 -12.0435 0.46670E-12 -12.3310 0.51586E+00 -0.2875 5 HCO3- 0.32636E-06 -6.4863 0.27252E-06 -6.5646 0.83502E+00 -0.0783 6 HS- 0.29452E-04 -4.5309 0.24560E-04 -4.6098 0.83390E+00 -0.0789 7 Al+++ 0.11025E-28 -28.9576 0.25085E-29 -29.6006 0.22753E+00 -0.6430 8 H4SiO4 0.71162E-03 -3.1478 0.71162E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14332E-06 -6.8437 0.73378E-07 -7.1344 0.51199E+00 -0.2907 10 Mg++ 0.22757E-10 -10.6429 0.11597E-10 -10.9356 0.50960E+00 -0.2928 11 Fe++ 0.62249E-13 -13.2059 0.31758E-13 -13.4982 0.51017E+00 -0.2923 12 K+ 0.16152E-03 -3.7918 0.13491E-03 -3.8700 0.83522E+00 -0.0782 13 Na+ 0.20535E-01 -1.6875 0.17119E-01 -1.7665 0.83362E+00 -0.0790 14 Mn++ 0.19894E-10 -10.7013 0.10158E-10 -10.9932 0.51061E+00 -0.2919 15 HPO4-- 0.48738E-07 -7.3121 0.25146E-07 -7.5995 0.51594E+00 -0.2874 16 HSiO3- 0.10990E-01 -1.9590 0.91632E-02 -2.0380 0.83378E+00 -0.0789 17 Ca(HSiO3)+ 0.18033E-07 -7.7439 0.15065E-07 -7.8220 0.83541E+00 -0.0781 18 Mg(HSiO3)+ 0.35470E-11 -11.4501 0.29632E-11 -11.5282 0.83541E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67521E-16 -16.1706 0.56408E-16 -16.2487 0.83541E+00 -0.0781 22 HAlO2,aq 0.14897E-09 -9.8269 0.14897E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52750E-05 -5.2778 0.43901E-05 -5.3575 0.83225E+00 -0.0797 24 CH4,aq 0.14123E-04 -4.8501 0.14073E-04 -4.8516 0.99642E+00 -0.0016 25 C2H6,aq 0.31528E-14 -14.5013 0.31415E-14 -14.5029 0.99642E+00 -0.0016 29 CO,aq 0.11657E-16 -16.9334 0.11657E-16 -16.9334 0.10000E+01 0.0000 30 CO2,aq 0.41781E-10 -10.3790 0.41632E-10 -10.3806 0.99642E+00 -0.0016 31 CO3-2 0.64603E-06 -6.1897 0.33254E-06 -6.4782 0.51475E+00 -0.2884 32 CaCO3,aq 0.29885E-09 -9.5245 0.29885E-09 -9.5245 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.60313E-12 -12.2196 0.50386E-12 -12.2977 0.83541E+00 -0.0781 34 CaCl+ 0.18511E-10 -10.7326 0.15464E-10 -10.8107 0.83541E+00 -0.0781 35 CaCl2,aq 0.47620E-15 -15.3222 0.47620E-15 -15.3222 0.10000E+01 0.0000 36 CaOH+ 0.81740E-07 -7.0876 0.68286E-07 -7.1657 0.83541E+00 -0.0781 37 CaSO4,aq 0.10670E-16 -16.9718 0.10670E-16 -16.9718 0.10000E+01 0.0000 38 HCl,aq 0.18849E-14 -14.7247 0.18849E-14 -14.7247 0.10000E+01 0.0000 43 FeCl+ 0.78306E-17 -17.1062 0.65417E-17 -17.1843 0.83541E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16633E-10 -10.7790 0.13895E-10 -10.8571 0.83541E+00 -0.0781 48 HFeO2- 0.37242E-07 -7.4290 0.31052E-07 -7.5079 0.83378E+00 -0.0789 49 FeO+ 0.12276E-16 -16.9109 0.10255E-16 -16.9890 0.83541E+00 -0.0781 51 FeO2- 0.42107E-09 -9.3756 0.35108E-09 -9.4546 0.83378E+00 -0.0789 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.31593E-09 -9.5004 0.31593E-09 -9.5004 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11634E-14 -14.9343 0.97001E-15 -15.0132 0.83378E+00 -0.0789 58 MgCO3,aq 0.11803E-13 -13.9280 0.11803E-13 -13.9280 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.97204E-16 -16.0123 0.81205E-16 -16.0904 0.83541E+00 -0.0781 60 MgCl+ 0.26560E-14 -14.5758 0.22188E-14 -14.6539 0.83541E+00 -0.0781 61 MgOH+ 0.71572E-10 -10.1453 0.59792E-10 -10.2234 0.83541E+00 -0.0781 63 MnO,aq 0.18678E-08 -8.7287 0.18678E-08 -8.7287 0.10000E+01 0.0000 64 MnOH+ 0.49423E-09 -9.3061 0.41288E-09 -9.3842 0.83541E+00 -0.0781 65 MnO2-2 0.21858E-10 -10.6604 0.11251E-10 -10.9488 0.51475E+00 -0.2884 66 HMnO2- 0.22153E-09 -9.6546 0.18470E-09 -9.7335 0.83378E+00 -0.0789 69 MnCl+ 0.97328E-14 -14.0118 0.81309E-14 -14.0899 0.83541E+00 -0.0781 71 NaCl,aq 0.73927E-06 -6.1312 0.73927E-06 -6.1312 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95122E-02 -2.0217 0.79165E-02 -2.1015 0.83225E+00 -0.0797 79 HPO3-2 0.16775E-14 -14.7753 0.86347E-15 -15.0638 0.51475E+00 -0.2884 81 H2PO3- 0.15414E-18 -18.8121 0.12852E-18 -18.8910 0.83378E+00 -0.0789 82 H3PO4,aq 0.92942E-18 -18.0318 0.92942E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40025E-10 -10.3977 0.33404E-10 -10.4762 0.83458E+00 -0.0785 84 PO4-3 0.12115E-08 -8.9167 0.28983E-09 -9.5379 0.23923E+00 -0.6212 88 HP2O7-3 0.10376E-17 -17.9840 0.23634E-18 -18.6265 0.22777E+00 -0.6425 89 P2O7-4 0.10247E-16 -16.9894 0.76949E-18 -18.1138 0.75093E-01 -1.1244 90 H2S,aq 0.56114E-08 -8.2509 0.55913E-08 -8.2525 0.99642E+00 -0.0016 91 S2-2 0.23707E-14 -14.6251 0.12203E-14 -14.9135 0.51475E+00 -0.2884 97 SO3-2 0.13244E-17 -17.8780 0.69180E-18 -18.1600 0.52235E+00 -0.2820 99 HSO4- 0.39236E-19 -19.4063 0.32811E-19 -19.4840 0.83624E+00 -0.0777 Charge balance for all species = 0.3809E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9031736E-10 -.2311825E-01 -.2325961E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981179E+06 0.0000 3 Cl- 0.1586216E-03 0.1593612E-03 0.5639601E+01 6.2419 4 SO4-- 0.9046898E-12 -.1685080E-04 -.1615784E+01 7.9100 5 HCO3- 0.3263578E-06 0.1509595E-04 0.9194443E+00 3.5559 6 HS- 0.2945224E-04 0.4630866E-04 0.1528746E+01 5.5107 7 Al+++ 0.1102496E-28 0.5275139E-05 0.1420734E+00 0.7609 8 H4SiO4 0.7116159E-03 0.1419299E-01 0.1361694E+04 -3.1478 9 Ca++ 0.1433175E-06 0.2434085E-06 0.9737661E-02 13.1066 10 Mg++ 0.2275740E-10 0.9789071E-10 0.2375609E-05 9.3054 11 Fe++ 0.6224866E-13 0.3790197E-07 0.2112878E-02 6.7429 12 K+ 0.1615236E-03 0.1623001E-03 0.6334767E+01 6.2505 13 Na+ 0.2053534E-01 0.2312672E-01 0.5307158E+03 8.3540 14 Mn++ 0.1989396E-10 0.2625289E-08 0.1439670E-03 9.2478 15 HPO4-- 0.4873830E-07 0.4998983E-07 0.4789285E-02 12.6415 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2185721E+02 -.2001567E-01 -.2183720E+02 0.0000000E+00 2 H2O 0.3896152E+02 0.4805546E+02 -.9093941E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3660718E-01 -.1458935E-04 0.3662177E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3658167E-01 0.4009382E-04 -.3662177E-01 0.0000000E+00 7 Al+++ 0.4304176E+01 0.4567190E-05 0.4304171E+01 0.0000000E+00 8 H4SiO4 0.1374486E+02 0.1228822E-01 0.1373257E+02 0.0000000E+00 9 Ca++ 0.1518202E+01 0.2107420E-06 0.1518201E+01 0.0000000E+00 10 Mg++ 0.1047618E+01 0.8475332E-10 0.1047618E+01 0.0000000E+00 11 Fe++ 0.9411706E+00 0.3281535E-07 0.9411706E+00 0.0000000E+00 12 K+ 0.2802546E+00 0.1405187E-03 0.2801140E+00 0.0000000E+00 13 Na+ 0.1657080E+01 0.2002300E-01 0.1637057E+01 0.0000000E+00 14 Mn++ 0.2288693E-01 0.2272963E-08 0.2288693E-01 0.0000000E+00 15 HPO4-- 0.7811195E-02 0.4328096E-07 0.7811152E-02 0.0000000E+00 Chg. balance for solid moles: 0.3227E-15 Mass of aqueous solution: 0.867366E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1319.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.636 0.214 428.9 2.632 29.75 164.7 andradite 0.1465 -0.834 74.44 1.872 5.163 19.34 grossular 0.3498E-01 -1.456 15.76 1.198 1.093 4.385 apatite-OH 0.2604E-02 -2.584 1.308 0.117 0.9070E-01 0.4156 clinochlore 0.1891 -0.723 105.1 2.022 7.288 39.97 daphnite 0.5419E-01 -1.266 38.66 1.587 2.681 11.72 chlorite-Mn 0.4577E-02 -2.339 3.245 0.511 0.2251 1.034 diopside 0.6686E-01 -1.175 14.48 1.161 1.004 4.425 hedenbergite 0.1713E-01 -1.766 4.250 0.628 0.2947 1.164 microcline 0.2453 -0.610 68.28 1.834 4.735 26.67 stilbite 0.8573 -0.067 604.1 2.781 41.90 281.8 stilpnomelane-Fe 0.6959E-01 -1.157 75.01 1.875 5.202 25.91 tr.625ac.25prg.125 0.9759E-02 -2.011 8.342 0.921 0.5785 2.685 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1847E-01 0.1847E-01 1.0000 -1.734 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1441.958900 g Volume = 584.166341 cm3 Porosity: -10.4285% V(tot) - V(min): -.55167E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1319.9990000 g log = 3.1206 Original solution: 1000.0103000 g Original solution / Rock added: 0.76 (Water/Rock Ratio), log = -0.1206 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0893 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9661E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4344E-08 1.0071 0.4766E-08 0.4732E-08 CH4,gas 0.2017E-01 1.0128 0.2225E-01 0.2197E-01 H2,gas 0.1368E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1503E-06 0.9958 0.1631E-06 0.1638E-06 S2,gas 0.4112E-29 1.0000 0.4480E-29 0.4480E-29 CO,gas 0.1690E-13 1.0000 0.1841E-13 0.1841E-13 SO3,gas 0.9195E-48 1.0000 0.1002E-47 0.1002E-47 SO2,gas 0.5187E-27 1.0000 0.5650E-27 0.5650E-27 HCl,gas 0.3055E-17 1.0000 0.3328E-17 0.3328E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.69 -10.32 -3.441 0.17624E+05 -8.322 3 CH4,gas 4.81 1.16 -3.65 -0.913 0.62367E+04 -1.653 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.73 -8.79 -4.394 0.15005E+05 -6.788 6 S2,gas -7.03 -38.38 -31.35 -4.823 0.53527E+05 -29.349 7 CO,gas 3.51 -12.22 -15.74 -4.842 0.26867E+05 -13.735 8 SO3,gas 17.43 -32.57 -50.00 -12.500 0.85372E+05 -47.999 9 SO2,gas 1.14 -28.11 -29.25 -7.799 0.49940E+05 -27.248 10 HCl,gas 5.48 -14.00 -19.48 -9.739 0.33258E+05 -17.478 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80727E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94124E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.58 -4.56 -1.522 0.77942E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.58 -4.41 -1.471 0.75329E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70325E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82192E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70377E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65589E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36457E+04 66 diamond -3.11 -7.76 -4.66 -1.331 0.79516E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33651E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66053E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.76 -4.22 -1.204 0.71978E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60997E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59770E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16001E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22973E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82303E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61283E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53668E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36602E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20056E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92770E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40695E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43443E+04 143 pyrrhotite -4.24 -7.99 -3.74 -1.248 0.63925E+04 144 pyrrhotiteFe0.875 -6.00 -9.38 -3.38 -1.244 0.57753E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22470E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28302E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23262E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27394E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.77 -0.395 0.47212E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91031E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65757E+04 181 troilite-low -4.39 -7.99 -3.59 -1.198 0.61357E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80419E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66779E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60334E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52964E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.48 -4.52 -1.507 0.77179E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1319.9990000 g New total amount of reactant added: 1359.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1359.9990000 Water: Moles liquid = 0.4784E+02 kg liquid = 0.8618E+00 Moles total = 0.3846E+02 kg total = 0.6929E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174703E-01 Osmotic coef. = 0.9688 True ionic strength = .2069859E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90319E-10 -10.0442 0.75772E-10 -10.1205 0.83893E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15936E-03 -3.7976 0.13287E-03 -3.8766 0.83378E+00 -0.0789 4 SO4-- 0.90891E-12 -12.0415 0.46887E-12 -12.3289 0.51586E+00 -0.2875 5 HCO3- 0.32788E-06 -6.4843 0.27379E-06 -6.5626 0.83502E+00 -0.0783 6 HS- 0.29590E-04 -4.5289 0.24675E-04 -4.6077 0.83390E+00 -0.0789 7 Al+++ 0.11026E-28 -28.9576 0.25087E-29 -29.6006 0.22753E+00 -0.6430 8 H4SiO4 0.71162E-03 -3.1478 0.71162E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14332E-06 -6.8437 0.73381E-07 -7.1344 0.51199E+00 -0.2907 10 Mg++ 0.22758E-10 -10.6429 0.11598E-10 -10.9356 0.50960E+00 -0.2928 11 Fe++ 0.62252E-13 -13.2058 0.31759E-13 -13.4981 0.51017E+00 -0.2923 12 K+ 0.16153E-03 -3.7918 0.13491E-03 -3.8700 0.83522E+00 -0.0782 13 Na+ 0.20536E-01 -1.6875 0.17119E-01 -1.7665 0.83362E+00 -0.0790 14 Mn++ 0.19899E-10 -10.7012 0.10161E-10 -10.9931 0.51060E+00 -0.2919 15 HPO4-- 0.48737E-07 -7.3121 0.25145E-07 -7.5995 0.51594E+00 -0.2874 16 HSiO3- 0.10990E-01 -1.9590 0.91631E-02 -2.0380 0.83378E+00 -0.0789 17 Ca(HSiO3)+ 0.18033E-07 -7.7439 0.15065E-07 -7.8220 0.83540E+00 -0.0781 18 Mg(HSiO3)+ 0.35471E-11 -11.4501 0.29632E-11 -11.5282 0.83540E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67522E-16 -16.1706 0.56408E-16 -16.2487 0.83540E+00 -0.0781 22 HAlO2,aq 0.14897E-09 -9.8269 0.14897E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52748E-05 -5.2778 0.43900E-05 -5.3575 0.83225E+00 -0.0797 24 CH4,aq 0.14189E-04 -4.8480 0.14138E-04 -4.8496 0.99642E+00 -0.0016 25 C2H6,aq 0.31823E-14 -14.4973 0.31709E-14 -14.4988 0.99642E+00 -0.0016 29 CO,aq 0.11711E-16 -16.9314 0.11711E-16 -16.9314 0.10000E+01 0.0000 30 CO2,aq 0.41977E-10 -10.3770 0.41827E-10 -10.3785 0.99642E+00 -0.0016 31 CO3-2 0.64903E-06 -6.1877 0.33408E-06 -6.4761 0.51474E+00 -0.2884 32 CaCO3,aq 0.30025E-09 -9.5225 0.30025E-09 -9.5225 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.60597E-12 -12.2176 0.50623E-12 -12.2957 0.83540E+00 -0.0781 34 CaCl+ 0.18598E-10 -10.7305 0.15537E-10 -10.8086 0.83540E+00 -0.0781 35 CaCl2,aq 0.48067E-15 -15.3181 0.48067E-15 -15.3181 0.10000E+01 0.0000 36 CaOH+ 0.81742E-07 -7.0876 0.68288E-07 -7.1657 0.83540E+00 -0.0781 37 CaSO4,aq 0.10720E-16 -16.9698 0.10720E-16 -16.9698 0.10000E+01 0.0000 38 HCl,aq 0.18938E-14 -14.7227 0.18938E-14 -14.7227 0.10000E+01 0.0000 43 FeCl+ 0.78675E-17 -17.1042 0.65725E-17 -17.1823 0.83540E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16633E-10 -10.7790 0.13896E-10 -10.8571 0.83540E+00 -0.0781 48 HFeO2- 0.37241E-07 -7.4290 0.31051E-07 -7.5079 0.83378E+00 -0.0789 49 FeO+ 0.12276E-16 -16.9109 0.10256E-16 -16.9890 0.83540E+00 -0.0781 51 FeO2- 0.42106E-09 -9.3757 0.35107E-09 -9.4546 0.83378E+00 -0.0789 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.31741E-09 -9.4984 0.31741E-09 -9.4984 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11688E-14 -14.9322 0.97455E-15 -15.0112 0.83378E+00 -0.0789 58 MgCO3,aq 0.11858E-13 -13.9260 0.11858E-13 -13.9260 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.97662E-16 -16.0103 0.81587E-16 -16.0884 0.83540E+00 -0.0781 60 MgCl+ 0.26685E-14 -14.5737 0.22292E-14 -14.6518 0.83540E+00 -0.0781 61 MgOH+ 0.71573E-10 -10.1452 0.59793E-10 -10.2234 0.83540E+00 -0.0781 63 MnO,aq 0.18682E-08 -8.7286 0.18682E-08 -8.7286 0.10000E+01 0.0000 64 MnOH+ 0.49434E-09 -9.3060 0.41297E-09 -9.3841 0.83540E+00 -0.0781 65 MnO2-2 0.21861E-10 -10.6603 0.11253E-10 -10.9487 0.51474E+00 -0.2884 66 HMnO2- 0.22157E-09 -9.6545 0.18474E-09 -9.7334 0.83378E+00 -0.0789 69 MnCl+ 0.97807E-14 -14.0096 0.81708E-14 -14.0877 0.83540E+00 -0.0781 71 NaCl,aq 0.74273E-06 -6.1292 0.74273E-06 -6.1292 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95120E-02 -2.0217 0.79163E-02 -2.1015 0.83225E+00 -0.0797 79 HPO3-2 0.16774E-14 -14.7754 0.86343E-15 -15.0638 0.51474E+00 -0.2884 81 H2PO3- 0.15413E-18 -18.8121 0.12851E-18 -18.8911 0.83378E+00 -0.0789 82 H3PO4,aq 0.92943E-18 -18.0318 0.92943E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40024E-10 -10.3977 0.33403E-10 -10.4762 0.83458E+00 -0.0785 84 PO4-3 0.12114E-08 -8.9167 0.28981E-09 -9.5379 0.23923E+00 -0.6212 88 HP2O7-3 0.10376E-17 -17.9840 0.23633E-18 -18.6265 0.22777E+00 -0.6425 89 P2O7-4 0.10247E-16 -16.9894 0.76943E-18 -18.1138 0.75092E-01 -1.1244 90 H2S,aq 0.56377E-08 -8.2489 0.56175E-08 -8.2505 0.99642E+00 -0.0016 91 S2-2 0.23929E-14 -14.6211 0.12317E-14 -14.9095 0.51474E+00 -0.2884 97 SO3-2 0.13306E-17 -17.8760 0.69502E-18 -18.1580 0.52235E+00 -0.2820 99 HSO4- 0.39420E-19 -19.4043 0.32964E-19 -19.4820 0.83624E+00 -0.0777 Charge balance for all species = 0.3825E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9031949E-10 -.2311786E-01 -.2325922E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981179E+06 0.0000 3 Cl- 0.1593613E-03 0.1601043E-03 0.5665900E+01 6.2439 4 SO4-- 0.9089135E-12 -.1691666E-04 -.1622098E+01 7.9120 5 HCO3- 0.3278806E-06 0.1516634E-04 0.9237319E+00 3.5579 6 HS- 0.2958958E-04 0.4651188E-04 0.1535455E+01 5.5127 7 Al+++ 0.1102577E-28 0.5274991E-05 0.1420694E+00 0.7609 8 H4SiO4 0.7116177E-03 0.1419280E-01 0.1361676E+04 -3.1478 9 Ca++ 0.1433244E-06 0.2434191E-06 0.9738083E-02 13.1066 10 Mg++ 0.2275849E-10 0.9789320E-10 0.2375669E-05 9.3054 11 Fe++ 0.6225176E-13 0.3790116E-07 0.2112833E-02 6.7429 12 K+ 0.1615274E-03 0.1623040E-03 0.6334916E+01 6.2505 13 Na+ 0.2053583E-01 0.2312721E-01 0.5307271E+03 8.3540 14 Mn++ 0.1989908E-10 0.2625839E-08 0.1439971E-03 9.2479 15 HPO4-- 0.4873666E-07 0.4998812E-07 0.4789121E-02 12.6414 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2251955E+02 -.1992243E-01 -.2249963E+02 0.0000000E+00 2 H2O 0.3846010E+02 0.4783241E+02 -.9372303E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3771571E-01 -.1457838E-04 0.3773029E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3769021E-01 0.4008285E-04 -.3773029E-01 0.0000000E+00 7 Al+++ 0.4434605E+01 0.4545864E-05 0.4434601E+01 0.0000000E+00 8 H4SiO4 0.1416137E+02 0.1223102E-01 0.1414914E+02 0.0000000E+00 9 Ca++ 0.1564207E+01 0.2097729E-06 0.1564207E+01 0.0000000E+00 10 Mg++ 0.1079364E+01 0.8436207E-10 0.1079364E+01 0.0000000E+00 11 Fe++ 0.9696910E+00 0.3266233E-07 0.9696909E+00 0.0000000E+00 12 K+ 0.2887471E+00 0.1398697E-03 0.2886073E+00 0.0000000E+00 13 Na+ 0.1707290E+01 0.1993049E-01 0.1687360E+01 0.0000000E+00 14 Mn++ 0.2358047E-01 0.2262886E-08 0.2358047E-01 0.0000000E+00 15 HPO4-- 0.8047898E-02 0.4307860E-07 0.8047855E-02 0.0000000E+00 Chg. balance for solid moles: -.7529E-15 Mass of aqueous solution: 0.863340E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1359.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.686 0.227 442.1 2.646 29.76 169.7 andradite 0.1509 -0.821 76.70 1.885 5.162 19.93 grossular 0.3604E-01 -1.443 16.23 1.210 1.093 4.517 apatite-OH 0.2683E-02 -2.571 1.348 0.130 0.9070E-01 0.4282 clinochlore 0.1948 -0.710 108.3 2.034 7.287 41.18 daphnite 0.5582E-01 -1.253 39.83 1.600 2.681 12.07 chlorite-Mn 0.4716E-02 -2.326 3.344 0.524 0.2251 1.066 diopside 0.6917E-01 -1.160 14.98 1.176 1.008 4.578 hedenbergite 0.1772E-01 -1.752 4.397 0.643 0.2959 1.204 microcline 0.2528 -0.597 70.35 1.847 4.735 27.48 stilbite 0.8829 -0.054 622.2 2.794 41.88 290.2 stilpnomelane-Fe 0.7170E-01 -1.144 77.29 1.888 5.203 26.70 tr.625ac.25prg.125 0.1003E-01 -1.999 8.575 0.933 0.5772 2.760 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1847E-01 0.1847E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1485.661092 g Volume = 601.848884 cm3 Porosity: -10.4311% V(tot) - V(min): -.56849E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1359.9990000 g log = 3.1335 Original solution: 1000.0103000 g Original solution / Rock added: 0.74 (Water/Rock Ratio), log = -0.1335 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0895 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9661E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4364E-08 1.0071 0.4788E-08 0.4754E-08 CH4,gas 0.2026E-01 1.0128 0.2236E-01 0.2208E-01 H2,gas 0.1368E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1510E-06 0.9958 0.1638E-06 0.1645E-06 S2,gas 0.4151E-29 1.0000 0.4522E-29 0.4522E-29 CO,gas 0.1697E-13 1.0000 0.1849E-13 0.1849E-13 SO3,gas 0.9238E-48 1.0000 0.1006E-47 0.1006E-47 SO2,gas 0.5211E-27 1.0000 0.5677E-27 0.5677E-27 HCl,gas 0.3069E-17 1.0000 0.3344E-17 0.3344E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.68 -10.32 -3.440 0.17621E+05 -8.320 3 CH4,gas 4.81 1.16 -3.65 -0.913 0.62332E+04 -1.651 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.73 -8.79 -4.393 0.15001E+05 -6.786 6 S2,gas -7.03 -38.38 -31.34 -4.822 0.53520E+05 -29.345 7 CO,gas 3.51 -12.22 -15.73 -4.841 0.26864E+05 -13.733 8 SO3,gas 17.43 -32.57 -50.00 -12.499 0.85369E+05 -47.997 9 SO2,gas 1.14 -28.11 -29.25 -7.799 0.49937E+05 -27.246 10 HCl,gas 5.48 -14.00 -19.48 -9.738 0.33254E+05 -17.476 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80723E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94124E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.58 -4.56 -1.521 0.77907E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.58 -4.41 -1.470 0.75294E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70325E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70377E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65588E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36457E+04 66 diamond -3.11 -7.76 -4.65 -1.330 0.79482E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33651E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66054E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.76 -4.21 -1.204 0.71943E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59770E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16001E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22973E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82301E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61284E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53668E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20056E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92771E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40695E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43443E+04 143 pyrrhotite -4.24 -7.99 -3.74 -1.247 0.63891E+04 144 pyrrhotiteFe0.875 -6.00 -9.38 -3.38 -1.243 0.57718E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22468E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28302E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23261E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27394E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47209E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91031E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65757E+04 181 troilite-low -4.39 -7.99 -3.59 -1.197 0.61323E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80420E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66779E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60334E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.48 -4.52 -1.506 0.77143E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1359.9990000 g New total amount of reactant added: 1399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1399.9990000 Water: Moles liquid = 0.4761E+02 kg liquid = 0.8578E+00 Moles total = 0.3796E+02 kg total = 0.6838E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174767E-01 Osmotic coef. = 0.9688 True ionic strength = .2069908E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90322E-10 -10.0442 0.75774E-10 -10.1205 0.83893E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16011E-03 -3.7956 0.13349E-03 -3.8745 0.83378E+00 -0.0789 4 SO4-- 0.91318E-12 -12.0394 0.47107E-12 -12.3269 0.51586E+00 -0.2875 5 HCO3- 0.32942E-06 -6.4823 0.27507E-06 -6.5606 0.83502E+00 -0.0783 6 HS- 0.29728E-04 -4.5268 0.24790E-04 -4.6057 0.83390E+00 -0.0789 7 Al+++ 0.11027E-28 -28.9576 0.25088E-29 -29.6005 0.22753E+00 -0.6430 8 H4SiO4 0.71162E-03 -3.1478 0.71162E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14333E-06 -6.8437 0.73384E-07 -7.1344 0.51199E+00 -0.2907 10 Mg++ 0.22760E-10 -10.6428 0.11598E-10 -10.9356 0.50960E+00 -0.2928 11 Fe++ 0.62255E-13 -13.2058 0.31760E-13 -13.4981 0.51017E+00 -0.2923 12 K+ 0.16153E-03 -3.7917 0.13491E-03 -3.8699 0.83522E+00 -0.0782 13 Na+ 0.20536E-01 -1.6875 0.17119E-01 -1.7665 0.83362E+00 -0.0790 14 Mn++ 0.19904E-10 -10.7011 0.10163E-10 -10.9930 0.51060E+00 -0.2919 15 HPO4-- 0.48735E-07 -7.3122 0.25144E-07 -7.5996 0.51593E+00 -0.2874 16 HSiO3- 0.10990E-01 -1.9590 0.91629E-02 -2.0380 0.83378E+00 -0.0789 17 Ca(HSiO3)+ 0.18034E-07 -7.7439 0.15065E-07 -7.8220 0.83540E+00 -0.0781 18 Mg(HSiO3)+ 0.35471E-11 -11.4501 0.29633E-11 -11.5282 0.83540E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67523E-16 -16.1705 0.56409E-16 -16.2486 0.83540E+00 -0.0781 22 HAlO2,aq 0.14897E-09 -9.8269 0.14897E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52747E-05 -5.2778 0.43899E-05 -5.3575 0.83225E+00 -0.0797 24 CH4,aq 0.14256E-04 -4.8460 0.14205E-04 -4.8476 0.99642E+00 -0.0016 25 C2H6,aq 0.32122E-14 -14.4932 0.32007E-14 -14.4948 0.99642E+00 -0.0016 29 CO,aq 0.11766E-16 -16.9294 0.11766E-16 -16.9294 0.10000E+01 0.0000 30 CO2,aq 0.42175E-10 -10.3749 0.42024E-10 -10.3765 0.99642E+00 -0.0016 31 CO3-2 0.65206E-06 -6.1857 0.33564E-06 -6.4741 0.51474E+00 -0.2884 32 CaCO3,aq 0.30167E-09 -9.5205 0.30167E-09 -9.5205 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.60883E-12 -12.2155 0.50862E-12 -12.2936 0.83540E+00 -0.0781 34 CaCl+ 0.18686E-10 -10.7285 0.15610E-10 -10.8066 0.83540E+00 -0.0781 35 CaCl2,aq 0.48521E-15 -15.3141 0.48521E-15 -15.3141 0.10000E+01 0.0000 36 CaOH+ 0.81744E-07 -7.0875 0.68289E-07 -7.1656 0.83540E+00 -0.0781 37 CaSO4,aq 0.10771E-16 -16.9678 0.10771E-16 -16.9678 0.10000E+01 0.0000 38 HCl,aq 0.19027E-14 -14.7206 0.19027E-14 -14.7206 0.10000E+01 0.0000 43 FeCl+ 0.79047E-17 -17.1021 0.66036E-17 -17.1802 0.83540E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16634E-10 -10.7790 0.13896E-10 -10.8571 0.83540E+00 -0.0781 48 HFeO2- 0.37241E-07 -7.4290 0.31050E-07 -7.5079 0.83378E+00 -0.0789 49 FeO+ 0.12277E-16 -16.9109 0.10256E-16 -16.9890 0.83540E+00 -0.0781 51 FeO2- 0.42106E-09 -9.3757 0.35107E-09 -9.4546 0.83378E+00 -0.0789 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.31890E-09 -9.4963 0.31890E-09 -9.4963 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11743E-14 -14.9302 0.97914E-15 -15.0092 0.83378E+00 -0.0789 58 MgCO3,aq 0.11914E-13 -13.9239 0.11914E-13 -13.9239 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.98124E-16 -16.0082 0.81973E-16 -16.0863 0.83540E+00 -0.0781 60 MgCl+ 0.26811E-14 -14.5717 0.22398E-14 -14.6498 0.83540E+00 -0.0781 61 MgOH+ 0.71575E-10 -10.1452 0.59794E-10 -10.2233 0.83540E+00 -0.0781 63 MnO,aq 0.18685E-08 -8.7285 0.18685E-08 -8.7285 0.10000E+01 0.0000 64 MnOH+ 0.49445E-09 -9.3059 0.41306E-09 -9.3840 0.83540E+00 -0.0781 65 MnO2-2 0.21865E-10 -10.6603 0.11255E-10 -10.9487 0.51474E+00 -0.2884 66 HMnO2- 0.22161E-09 -9.6544 0.18477E-09 -9.7334 0.83378E+00 -0.0789 69 MnCl+ 0.98289E-14 -14.0075 0.82111E-14 -14.0856 0.83540E+00 -0.0781 71 NaCl,aq 0.74623E-06 -6.1271 0.74623E-06 -6.1271 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95118E-02 -2.0217 0.79161E-02 -2.1015 0.83225E+00 -0.0797 79 HPO3-2 0.16773E-14 -14.7754 0.86339E-15 -15.0638 0.51474E+00 -0.2884 81 H2PO3- 0.15413E-18 -18.8121 0.12851E-18 -18.8911 0.83378E+00 -0.0789 82 H3PO4,aq 0.92943E-18 -18.0318 0.92943E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40023E-10 -10.3977 0.33403E-10 -10.4762 0.83458E+00 -0.0785 84 PO4-3 0.12114E-08 -8.9167 0.28979E-09 -9.5379 0.23922E+00 -0.6212 88 HP2O7-3 0.10375E-17 -17.9840 0.23631E-18 -18.6265 0.22777E+00 -0.6425 89 P2O7-4 0.10246E-16 -16.9894 0.76937E-18 -18.1139 0.75090E-01 -1.1244 90 H2S,aq 0.56642E-08 -8.2469 0.56439E-08 -8.2484 0.99642E+00 -0.0016 91 S2-2 0.24154E-14 -14.6170 0.12433E-14 -14.9054 0.51474E+00 -0.2884 97 SO3-2 0.13368E-17 -17.8739 0.69827E-18 -18.1560 0.52234E+00 -0.2820 99 HSO4- 0.39606E-19 -19.4022 0.33120E-19 -19.4799 0.83624E+00 -0.0777 Charge balance for all species = 0.3845E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9032164E-10 -.2311747E-01 -.2325883E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981178E+06 0.0000 3 Cl- 0.1601079E-03 0.1608545E-03 0.5692445E+01 6.2459 4 SO4-- 0.9131755E-12 -.1698313E-04 -.1628472E+01 7.9140 5 HCO3- 0.3294172E-06 0.1523740E-04 0.9280597E+00 3.5599 6 HS- 0.2972821E-04 0.4671701E-04 0.1542227E+01 5.5148 7 Al+++ 0.1102659E-28 0.5274846E-05 0.1420655E+00 0.7609 8 H4SiO4 0.7116193E-03 0.1419260E-01 0.1361657E+04 -3.1478 9 Ca++ 0.1433314E-06 0.2434298E-06 0.9738509E-02 13.1066 10 Mg++ 0.2275959E-10 0.9789650E-10 0.2375749E-05 9.3054 11 Fe++ 0.6225488E-13 0.3790035E-07 0.2112787E-02 6.7428 12 K+ 0.1615313E-03 0.1623078E-03 0.6335066E+01 6.2505 13 Na+ 0.2053632E-01 0.2312771E-01 0.5307386E+03 8.3540 14 Mn++ 0.1990397E-10 0.2626358E-08 0.1440255E-03 9.2480 15 HPO4-- 0.4873499E-07 0.4998639E-07 0.4788955E-02 12.6414 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2318189E+02 -.1982919E-01 -.2316206E+02 0.0000000E+00 2 H2O 0.3795869E+02 0.4760935E+02 -.9650665E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3882425E-01 -.1456742E-04 0.3883882E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3879874E-01 0.4007189E-04 -.3883882E-01 0.0000000E+00 7 Al+++ 0.4565035E+01 0.4524541E-05 0.4565030E+01 0.0000000E+00 8 H4SiO4 0.1457789E+02 0.1217382E-01 0.1456571E+02 0.0000000E+00 9 Ca++ 0.1610213E+01 0.2088038E-06 0.1610213E+01 0.0000000E+00 10 Mg++ 0.1111110E+01 0.8397150E-10 0.1111110E+01 0.0000000E+00 11 Fe++ 0.9982113E+00 0.3250932E-07 0.9982113E+00 0.0000000E+00 12 K+ 0.2972397E+00 0.1392208E-03 0.2971005E+00 0.0000000E+00 13 Na+ 0.1757500E+01 0.1983798E-01 0.1737662E+01 0.0000000E+00 14 Mn++ 0.2427402E-01 0.2252779E-08 0.2427401E-01 0.0000000E+00 15 HPO4-- 0.8284601E-02 0.4287622E-07 0.8284558E-02 0.0000000E+00 Chg. balance for solid moles: 0.2602E-14 Mass of aqueous solution: 0.859314E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.736 0.240 455.3 2.658 29.77 174.8 andradite 0.1554 -0.809 78.95 1.897 5.162 20.51 grossular 0.3710E-01 -1.431 16.71 1.223 1.093 4.650 apatite-OH 0.2762E-02 -2.559 1.387 0.142 0.9070E-01 0.4408 clinochlore 0.2005 -0.698 111.4 2.047 7.285 42.38 daphnite 0.5745E-01 -1.241 40.99 1.613 2.680 12.42 chlorite-Mn 0.4855E-02 -2.314 3.442 0.537 0.2251 1.097 diopside 0.7149E-01 -1.146 15.48 1.190 1.012 4.731 hedenbergite 0.1831E-01 -1.737 4.544 0.657 0.2971 1.245 microcline 0.2602 -0.585 72.42 1.860 4.735 28.29 stilbite 0.9086 -0.042 640.3 2.806 41.87 298.7 stilpnomelane-Fe 0.7381E-01 -1.132 79.57 1.901 5.203 27.49 tr.625ac.25prg.125 0.1030E-01 -1.987 8.808 0.945 0.5759 2.835 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1848E-01 0.1848E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1529.363283 g Volume = 619.531427 cm3 Porosity: -10.4335% V(tot) - V(min): -.58532E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1399.9990000 g log = 3.1461 Original solution: 1000.0103000 g Original solution / Rock added: 0.71 (Water/Rock Ratio), log = -0.1461 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0896 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9660E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4384E-08 1.0071 0.4810E-08 0.4776E-08 CH4,gas 0.2036E-01 1.0128 0.2246E-01 0.2218E-01 H2,gas 0.1368E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1517E-06 0.9958 0.1646E-06 0.1653E-06 S2,gas 0.4190E-29 1.0000 0.4565E-29 0.4565E-29 CO,gas 0.1705E-13 1.0000 0.1858E-13 0.1858E-13 SO3,gas 0.9281E-48 1.0000 0.1011E-47 0.1011E-47 SO2,gas 0.5235E-27 1.0000 0.5704E-27 0.5704E-27 HCl,gas 0.3083E-17 1.0000 0.3360E-17 0.3360E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 67 diopside 16.22 16.22 0.00 0.000 -0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.68 -10.32 -3.439 0.17617E+05 -8.318 3 CH4,gas 4.81 1.16 -3.65 -0.912 0.62298E+04 -1.649 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.73 -8.78 -4.392 0.14998E+05 -6.784 6 S2,gas -7.03 -38.37 -31.34 -4.822 0.53513E+05 -29.341 7 CO,gas 3.51 -12.22 -15.73 -4.840 0.26860E+05 -13.731 8 SO3,gas 17.43 -32.57 -50.00 -12.499 0.85365E+05 -47.995 9 SO2,gas 1.14 -28.11 -29.24 -7.798 0.49933E+05 -27.244 10 HCl,gas 5.48 -14.00 -19.47 -9.737 0.33251E+05 -17.474 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80718E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94124E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.57 -4.56 -1.520 0.77873E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.57 -4.41 -1.469 0.75259E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70325E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70377E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65586E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36457E+04 66 diamond -3.11 -7.76 -4.65 -1.329 0.79447E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66054E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.76 -4.21 -1.203 0.71909E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59770E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16001E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82300E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61284E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53668E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20056E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92771E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40695E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43444E+04 143 pyrrhotite -4.24 -7.98 -3.74 -1.247 0.63856E+04 144 pyrrhotiteFe0.875 -6.00 -9.38 -3.38 -1.242 0.57684E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22467E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28302E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23259E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27394E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47206E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91031E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65757E+04 181 troilite-low -4.39 -7.98 -3.59 -1.196 0.61288E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80420E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66779E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60333E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.48 -4.52 -1.505 0.77106E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1399.9990000 g New total amount of reactant added: 1439.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1439.9990000 Water: Moles liquid = 0.4739E+02 kg liquid = 0.8537E+00 Moles total = 0.3746E+02 kg total = 0.6748E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174830E-01 Osmotic coef. = 0.9688 True ionic strength = .2069959E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90324E-10 -10.0442 0.75775E-10 -10.1205 0.83893E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16086E-03 -3.7935 0.13412E-03 -3.8725 0.83378E+00 -0.0790 4 SO4-- 0.91748E-12 -12.0374 0.47328E-12 -12.3249 0.51585E+00 -0.2875 5 HCO3- 0.33097E-06 -6.4802 0.27636E-06 -6.5585 0.83502E+00 -0.0783 6 HS- 0.29868E-04 -4.5248 0.24907E-04 -4.6037 0.83390E+00 -0.0789 7 Al+++ 0.11027E-28 -28.9575 0.25090E-29 -29.6005 0.22752E+00 -0.6430 8 H4SiO4 0.71162E-03 -3.1478 0.71162E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14334E-06 -6.8436 0.73387E-07 -7.1344 0.51198E+00 -0.2907 10 Mg++ 0.22761E-10 -10.6428 0.11599E-10 -10.9356 0.50959E+00 -0.2928 11 Fe++ 0.62258E-13 -13.2058 0.31762E-13 -13.4981 0.51016E+00 -0.2923 12 K+ 0.16154E-03 -3.7917 0.13492E-03 -3.8699 0.83522E+00 -0.0782 13 Na+ 0.20537E-01 -1.6875 0.17120E-01 -1.7665 0.83362E+00 -0.0790 14 Mn++ 0.19909E-10 -10.7010 0.10165E-10 -10.9929 0.51060E+00 -0.2919 15 HPO4-- 0.48733E-07 -7.3122 0.25143E-07 -7.5996 0.51593E+00 -0.2874 16 HSiO3- 0.10989E-01 -1.9590 0.91627E-02 -2.0380 0.83378E+00 -0.0790 17 Ca(HSiO3)+ 0.18034E-07 -7.7439 0.15066E-07 -7.8220 0.83540E+00 -0.0781 18 Mg(HSiO3)+ 0.35472E-11 -11.4501 0.29634E-11 -11.5282 0.83540E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67525E-16 -16.1705 0.56410E-16 -16.2486 0.83540E+00 -0.0781 22 HAlO2,aq 0.14897E-09 -9.8269 0.14897E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52746E-05 -5.2778 0.43897E-05 -5.3576 0.83225E+00 -0.0797 24 CH4,aq 0.14323E-04 -4.8440 0.14271E-04 -4.8455 0.99642E+00 -0.0016 25 C2H6,aq 0.32426E-14 -14.4891 0.32310E-14 -14.4907 0.99642E+00 -0.0016 29 CO,aq 0.11822E-16 -16.9273 0.11822E-16 -16.9273 0.10000E+01 0.0000 30 CO2,aq 0.42374E-10 -10.3729 0.42222E-10 -10.3745 0.99642E+00 -0.0016 31 CO3-2 0.65512E-06 -6.1837 0.33721E-06 -6.4721 0.51474E+00 -0.2884 32 CaCO3,aq 0.30309E-09 -9.5184 0.30309E-09 -9.5184 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.61172E-12 -12.2134 0.51104E-12 -12.2915 0.83540E+00 -0.0781 34 CaCl+ 0.18775E-10 -10.7264 0.15684E-10 -10.8045 0.83540E+00 -0.0781 35 CaCl2,aq 0.48980E-15 -15.3100 0.48980E-15 -15.3100 0.10000E+01 0.0000 36 CaOH+ 0.81745E-07 -7.0875 0.68290E-07 -7.1656 0.83540E+00 -0.0781 37 CaSO4,aq 0.10822E-16 -16.9657 0.10822E-16 -16.9657 0.10000E+01 0.0000 38 HCl,aq 0.19117E-14 -14.7186 0.19117E-14 -14.7186 0.10000E+01 0.0000 43 FeCl+ 0.79422E-17 -17.1001 0.66350E-17 -17.1782 0.83540E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16634E-10 -10.7790 0.13896E-10 -10.8571 0.83540E+00 -0.0781 48 HFeO2- 0.37240E-07 -7.4290 0.31050E-07 -7.5079 0.83378E+00 -0.0790 49 FeO+ 0.12277E-16 -16.9109 0.10256E-16 -16.9890 0.83540E+00 -0.0781 51 FeO2- 0.42105E-09 -9.3757 0.35106E-09 -9.4546 0.83378E+00 -0.0790 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.32041E-09 -9.4943 0.32041E-09 -9.4943 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11799E-14 -14.9282 0.98376E-15 -15.0071 0.83378E+00 -0.0790 58 MgCO3,aq 0.11970E-13 -13.9219 0.11970E-13 -13.9219 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.98590E-16 -16.0062 0.82362E-16 -16.0843 0.83540E+00 -0.0781 60 MgCl+ 0.26938E-14 -14.5696 0.22504E-14 -14.6477 0.83540E+00 -0.0781 61 MgOH+ 0.71576E-10 -10.1452 0.59795E-10 -10.2233 0.83540E+00 -0.0781 63 MnO,aq 0.18689E-08 -8.7284 0.18689E-08 -8.7284 0.10000E+01 0.0000 64 MnOH+ 0.49455E-09 -9.3058 0.41315E-09 -9.3839 0.83540E+00 -0.0781 65 MnO2-2 0.21868E-10 -10.6602 0.11256E-10 -10.9486 0.51474E+00 -0.2884 66 HMnO2- 0.22164E-09 -9.6543 0.18480E-09 -9.7333 0.83378E+00 -0.0790 69 MnCl+ 0.98774E-14 -14.0054 0.82516E-14 -14.0835 0.83540E+00 -0.0781 71 NaCl,aq 0.74975E-06 -6.1251 0.74975E-06 -6.1251 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95116E-02 -2.0217 0.79160E-02 -2.1015 0.83225E+00 -0.0797 79 HPO3-2 0.16773E-14 -14.7754 0.86335E-15 -15.0638 0.51474E+00 -0.2884 81 H2PO3- 0.15413E-18 -18.8121 0.12851E-18 -18.8911 0.83378E+00 -0.0790 82 H3PO4,aq 0.92944E-18 -18.0318 0.92944E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40023E-10 -10.3977 0.33402E-10 -10.4762 0.83458E+00 -0.0785 84 PO4-3 0.12113E-08 -8.9167 0.28977E-09 -9.5379 0.23922E+00 -0.6212 88 HP2O7-3 0.10375E-17 -17.9840 0.23630E-18 -18.6265 0.22776E+00 -0.6425 89 P2O7-4 0.10245E-16 -16.9895 0.76930E-18 -18.1139 0.75088E-01 -1.1244 90 H2S,aq 0.56910E-08 -8.2448 0.56706E-08 -8.2464 0.99642E+00 -0.0016 91 S2-2 0.24382E-14 -14.6129 0.12550E-14 -14.9013 0.51474E+00 -0.2884 97 SO3-2 0.13431E-17 -17.8719 0.70155E-18 -18.1539 0.52234E+00 -0.2820 99 HSO4- 0.39793E-19 -19.4002 0.33276E-19 -19.4779 0.83623E+00 -0.0777 Charge balance for all species = 0.3862E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9032381E-10 -.2311708E-01 -.2325843E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981178E+06 0.0000 3 Cl- 0.1608615E-03 0.1616116E-03 0.5719240E+01 6.2480 4 SO4-- 0.9174764E-12 -.1705023E-04 -.1634906E+01 7.9161 5 HCO3- 0.3309679E-06 0.1530912E-04 0.9324282E+00 3.5620 6 HS- 0.2986815E-04 0.4692407E-04 0.1549062E+01 5.5168 7 Al+++ 0.1102742E-28 0.5274701E-05 0.1420616E+00 0.7609 8 H4SiO4 0.7116209E-03 0.1419241E-01 0.1361638E+04 -3.1478 9 Ca++ 0.1433384E-06 0.2434405E-06 0.9738940E-02 13.1066 10 Mg++ 0.2276071E-10 0.9789904E-10 0.2375811E-05 9.3054 11 Fe++ 0.6225803E-13 0.3789953E-07 0.2112742E-02 6.7428 12 K+ 0.1615352E-03 0.1623117E-03 0.6335218E+01 6.2505 13 Na+ 0.2053681E-01 0.2312822E-01 0.5307502E+03 8.3540 14 Mn++ 0.1990865E-10 0.2626848E-08 0.1440524E-03 9.2481 15 HPO4-- 0.4873329E-07 0.4998463E-07 0.4788787E-02 12.6414 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2384423E+02 -.1973596E-01 -.2382450E+02 0.0000000E+00 2 H2O 0.3745727E+02 0.4738630E+02 -.9929027E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3993279E-01 -.1455645E-04 0.3994734E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3990728E-01 0.4006092E-04 -.3994734E-01 0.0000000E+00 7 Al+++ 0.4695465E+01 0.4503220E-05 0.4695460E+01 0.0000000E+00 8 H4SiO4 0.1499440E+02 0.1211661E-01 0.1498228E+02 0.0000000E+00 9 Ca++ 0.1656219E+01 0.2078347E-06 0.1656219E+01 0.0000000E+00 10 Mg++ 0.1142856E+01 0.8358025E-10 0.1142856E+01 0.0000000E+00 11 Fe++ 0.1026732E+01 0.3235632E-07 0.1026732E+01 0.0000000E+00 12 K+ 0.3057323E+00 0.1385719E-03 0.3055937E+00 0.0000000E+00 13 Na+ 0.1807710E+01 0.1974547E-01 0.1787964E+01 0.0000000E+00 14 Mn++ 0.2496756E-01 0.2242643E-08 0.2496756E-01 0.0000000E+00 15 HPO4-- 0.8521304E-02 0.4267384E-07 0.8521262E-02 0.0000000E+00 Chg. balance for solid moles: -.9468E-14 Mass of aqueous solution: 0.855288E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1439.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.787 0.252 468.5 2.671 29.78 179.8 andradite 0.1598 -0.796 81.20 1.910 5.162 21.10 grossular 0.3816E-01 -1.418 17.19 1.235 1.093 4.783 apatite-OH 0.2840E-02 -2.547 1.427 0.154 0.9070E-01 0.4534 clinochlore 0.2061 -0.686 114.6 2.059 7.284 43.58 daphnite 0.5908E-01 -1.229 42.15 1.625 2.680 12.77 chlorite-Mn 0.4994E-02 -2.302 3.540 0.549 0.2251 1.128 diopside 0.7380E-01 -1.132 15.98 1.204 1.016 4.885 hedenbergite 0.1891E-01 -1.723 4.691 0.671 0.2982 1.285 microcline 0.2676 -0.572 74.49 1.872 4.735 29.10 stilbite 0.9343 -0.030 658.4 2.819 41.86 307.1 stilpnomelane-Fe 0.7593E-01 -1.120 81.85 1.913 5.203 28.27 tr.625ac.25prg.125 0.1058E-01 -1.976 9.041 0.956 0.5747 2.910 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1848E-01 0.1848E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1573.065475 g Volume = 637.213970 cm3 Porosity: -10.4358% V(tot) - V(min): -.60214E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1439.9990000 g log = 3.1584 Original solution: 1000.0103000 g Original solution / Rock added: 0.69 (Water/Rock Ratio), log = -0.1584 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0897 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9659E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4404E-08 1.0071 0.4833E-08 0.4799E-08 CH4,gas 0.2045E-01 1.0128 0.2257E-01 0.2228E-01 H2,gas 0.1368E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1524E-06 0.9958 0.1654E-06 0.1661E-06 S2,gas 0.4229E-29 1.0000 0.4608E-29 0.4608E-29 CO,gas 0.1713E-13 1.0000 0.1867E-13 0.1867E-13 SO3,gas 0.9324E-48 1.0000 0.1016E-47 0.1016E-47 SO2,gas 0.5259E-27 1.0000 0.5731E-27 0.5731E-27 HCl,gas 0.3098E-17 1.0000 0.3375E-17 0.3375E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.36397E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.68 -10.32 -3.439 0.17614E+05 -8.316 3 CH4,gas 4.81 1.16 -3.65 -0.912 0.62263E+04 -1.646 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.72 -8.78 -4.391 0.14994E+05 -6.781 6 S2,gas -7.03 -38.37 -31.34 -4.821 0.53506E+05 -29.336 7 CO,gas 3.51 -12.22 -15.73 -4.840 0.26857E+05 -13.729 8 SO3,gas 17.43 -32.57 -49.99 -12.498 0.85362E+05 -47.993 9 SO2,gas 1.14 -28.11 -29.24 -7.798 0.49930E+05 -27.242 10 HCl,gas 5.48 -13.99 -19.47 -9.736 0.33247E+05 -17.472 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80714E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94124E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.57 -4.56 -1.520 0.77838E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.57 -4.41 -1.469 0.75224E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70325E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65585E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36457E+04 66 diamond -3.11 -7.76 -4.65 -1.329 0.79412E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66054E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.76 -4.21 -1.203 0.71874E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59770E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82298E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61284E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53668E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20056E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92771E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40695E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43444E+04 143 pyrrhotite -4.24 -7.98 -3.74 -1.246 0.63821E+04 144 pyrrhotiteFe0.875 -6.00 -9.38 -3.38 -1.242 0.57649E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22466E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28302E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23258E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27394E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47204E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91031E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65757E+04 181 troilite-low -4.39 -7.98 -3.59 -1.196 0.61253E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80421E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66779E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60333E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.48 -4.51 -1.505 0.77070E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1439.9990000 g New total amount of reactant added: 1479.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1479.9990000 Water: Moles liquid = 0.4717E+02 kg liquid = 0.8497E+00 Moles total = 0.3696E+02 kg total = 0.6658E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174894E-01 Osmotic coef. = 0.9688 True ionic strength = .2070009E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90326E-10 -10.0442 0.75777E-10 -10.1205 0.83893E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16162E-03 -3.7915 0.13476E-03 -3.8705 0.83377E+00 -0.0790 4 SO4-- 0.92182E-12 -12.0354 0.47552E-12 -12.3228 0.51585E+00 -0.2875 5 HCO3- 0.33253E-06 -6.4782 0.27767E-06 -6.5565 0.83502E+00 -0.0783 6 HS- 0.30009E-04 -4.5227 0.25025E-04 -4.6016 0.83390E+00 -0.0789 7 Al+++ 0.11028E-28 -28.9575 0.25092E-29 -29.6005 0.22752E+00 -0.6430 8 H4SiO4 0.71162E-03 -3.1478 0.71162E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14335E-06 -6.8436 0.73390E-07 -7.1344 0.51198E+00 -0.2907 10 Mg++ 0.22762E-10 -10.6428 0.11599E-10 -10.9356 0.50959E+00 -0.2928 11 Fe++ 0.62261E-13 -13.2058 0.31763E-13 -13.4981 0.51016E+00 -0.2923 12 K+ 0.16154E-03 -3.7917 0.13492E-03 -3.8699 0.83522E+00 -0.0782 13 Na+ 0.20537E-01 -1.6875 0.17120E-01 -1.7665 0.83362E+00 -0.0790 14 Mn++ 0.19913E-10 -10.7009 0.10167E-10 -10.9928 0.51059E+00 -0.2919 15 HPO4-- 0.48732E-07 -7.3122 0.25142E-07 -7.5996 0.51593E+00 -0.2874 16 HSiO3- 0.10989E-01 -1.9590 0.91625E-02 -2.0380 0.83377E+00 -0.0790 17 Ca(HSiO3)+ 0.18035E-07 -7.7439 0.15066E-07 -7.8220 0.83540E+00 -0.0781 18 Mg(HSiO3)+ 0.35473E-11 -11.4501 0.29634E-11 -11.5282 0.83540E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67526E-16 -16.1705 0.56411E-16 -16.2486 0.83540E+00 -0.0781 22 HAlO2,aq 0.14897E-09 -9.8269 0.14897E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52744E-05 -5.2778 0.43896E-05 -5.3576 0.83225E+00 -0.0797 24 CH4,aq 0.14390E-04 -4.8419 0.14339E-04 -4.8435 0.99642E+00 -0.0016 25 C2H6,aq 0.32733E-14 -14.4850 0.32616E-14 -14.4866 0.99642E+00 -0.0016 29 CO,aq 0.11878E-16 -16.9253 0.11878E-16 -16.9253 0.10000E+01 0.0000 30 CO2,aq 0.42575E-10 -10.3708 0.42423E-10 -10.3724 0.99642E+00 -0.0016 31 CO3-2 0.65821E-06 -6.1816 0.33880E-06 -6.4701 0.51473E+00 -0.2884 32 CaCO3,aq 0.30453E-09 -9.5164 0.30453E-09 -9.5164 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.61464E-12 -12.2114 0.51347E-12 -12.2895 0.83540E+00 -0.0781 34 CaCl+ 0.18864E-10 -10.7244 0.15759E-10 -10.8025 0.83540E+00 -0.0781 35 CaCl2,aq 0.49447E-15 -15.3059 0.49447E-15 -15.3059 0.10000E+01 0.0000 36 CaOH+ 0.81747E-07 -7.0875 0.68292E-07 -7.1656 0.83540E+00 -0.0781 37 CaSO4,aq 0.10874E-16 -16.9636 0.10874E-16 -16.9636 0.10000E+01 0.0000 38 HCl,aq 0.19207E-14 -14.7165 0.19207E-14 -14.7165 0.10000E+01 0.0000 43 FeCl+ 0.79801E-17 -17.0980 0.66666E-17 -17.1761 0.83540E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16634E-10 -10.7790 0.13896E-10 -10.8571 0.83540E+00 -0.0781 48 HFeO2- 0.37239E-07 -7.4290 0.31049E-07 -7.5080 0.83377E+00 -0.0790 49 FeO+ 0.12277E-16 -16.9109 0.10256E-16 -16.9890 0.83540E+00 -0.0781 51 FeO2- 0.42104E-09 -9.3757 0.35105E-09 -9.4546 0.83377E+00 -0.0790 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.32193E-09 -9.4922 0.32193E-09 -9.4922 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11855E-14 -14.9261 0.98843E-15 -15.0051 0.83377E+00 -0.0790 58 MgCO3,aq 0.12027E-13 -13.9198 0.12027E-13 -13.9198 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.99060E-16 -16.0041 0.82755E-16 -16.0822 0.83540E+00 -0.0781 60 MgCl+ 0.27067E-14 -14.5676 0.22611E-14 -14.6457 0.83540E+00 -0.0781 61 MgOH+ 0.71578E-10 -10.1452 0.59796E-10 -10.2233 0.83540E+00 -0.0781 63 MnO,aq 0.18692E-08 -8.7283 0.18692E-08 -8.7283 0.10000E+01 0.0000 64 MnOH+ 0.49465E-09 -9.3057 0.41323E-09 -9.3838 0.83540E+00 -0.0781 65 MnO2-2 0.21871E-10 -10.6601 0.11258E-10 -10.9486 0.51473E+00 -0.2884 66 HMnO2- 0.22168E-09 -9.6543 0.18483E-09 -9.7332 0.83377E+00 -0.0790 69 MnCl+ 0.99263E-14 -14.0032 0.82924E-14 -14.0813 0.83540E+00 -0.0781 71 NaCl,aq 0.75332E-06 -6.1230 0.75332E-06 -6.1230 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95114E-02 -2.0218 0.79158E-02 -2.1015 0.83225E+00 -0.0797 79 HPO3-2 0.16772E-14 -14.7754 0.86331E-15 -15.0638 0.51473E+00 -0.2884 81 H2PO3- 0.15412E-18 -18.8121 0.12850E-18 -18.8911 0.83377E+00 -0.0790 82 H3PO4,aq 0.92944E-18 -18.0318 0.92944E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40022E-10 -10.3977 0.33402E-10 -10.4762 0.83458E+00 -0.0785 84 PO4-3 0.12113E-08 -8.9168 0.28975E-09 -9.5380 0.23922E+00 -0.6212 88 HP2O7-3 0.10374E-17 -17.9840 0.23628E-18 -18.6266 0.22776E+00 -0.6425 89 P2O7-4 0.10245E-16 -16.9895 0.76924E-18 -18.1139 0.75086E-01 -1.1244 90 H2S,aq 0.57180E-08 -8.2428 0.56976E-08 -8.2443 0.99642E+00 -0.0016 91 S2-2 0.24614E-14 -14.6088 0.12669E-14 -14.8972 0.51473E+00 -0.2884 97 SO3-2 0.13494E-17 -17.8698 0.70486E-18 -18.1519 0.52234E+00 -0.2820 99 HSO4- 0.39982E-19 -19.3981 0.33434E-19 -19.4758 0.83623E+00 -0.0777 Charge balance for all species = 0.3880E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9032600E-10 -.2311668E-01 -.2325803E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981178E+06 0.0000 3 Cl- 0.1616223E-03 0.1623759E-03 0.5746289E+01 6.2500 4 SO4-- 0.9218168E-12 -.1711797E-04 -.1641402E+01 7.9181 5 HCO3- 0.3325328E-06 0.1538153E-04 0.9368380E+00 3.5640 6 HS- 0.3000941E-04 0.4713310E-04 0.1555963E+01 5.5188 7 Al+++ 0.1102826E-28 0.5274558E-05 0.1420577E+00 0.7609 8 H4SiO4 0.7116224E-03 0.1419220E-01 0.1361619E+04 -3.1478 9 Ca++ 0.1433456E-06 0.2434514E-06 0.9739376E-02 13.1066 10 Mg++ 0.2276184E-10 0.9790213E-10 0.2375886E-05 9.3054 11 Fe++ 0.6226122E-13 0.3789871E-07 0.2112696E-02 6.7428 12 K+ 0.1615391E-03 0.1623156E-03 0.6335370E+01 6.2505 13 Na+ 0.2053731E-01 0.2312873E-01 0.5307618E+03 8.3540 14 Mn++ 0.1991315E-10 0.2627313E-08 0.1440779E-03 9.2481 15 HPO4-- 0.4873157E-07 0.4998285E-07 0.4788616E-02 12.6413 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2450657E+02 -.1964272E-01 -.2448693E+02 0.0000000E+00 2 H2O 0.3695586E+02 0.4716324E+02 -.1020739E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4104132E-01 -.1454549E-04 0.4105587E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4101582E-01 0.4004996E-04 -.4105587E-01 0.0000000E+00 7 Al+++ 0.4825894E+01 0.4481900E-05 0.4825890E+01 0.0000000E+00 8 H4SiO4 0.1541091E+02 0.1205941E-01 0.1539885E+02 0.0000000E+00 9 Ca++ 0.1702224E+01 0.2068657E-06 0.1702224E+01 0.0000000E+00 10 Mg++ 0.1174602E+01 0.8318946E-10 0.1174602E+01 0.0000000E+00 11 Fe++ 0.1055252E+01 0.3220331E-07 0.1055252E+01 0.0000000E+00 12 K+ 0.3142248E+00 0.1379229E-03 0.3140869E+00 0.0000000E+00 13 Na+ 0.1857919E+01 0.1965295E-01 0.1838266E+01 0.0000000E+00 14 Mn++ 0.2566110E-01 0.2232482E-08 0.2566110E-01 0.0000000E+00 15 HPO4-- 0.8758007E-02 0.4247146E-07 0.8757965E-02 0.0000000E+00 Chg. balance for solid moles: -.2220E-15 Mass of aqueous solution: 0.851262E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1479.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.837 0.264 481.7 2.683 29.79 184.9 andradite 0.1642 -0.785 83.46 1.921 5.162 21.68 grossular 0.3922E-01 -1.407 17.67 1.247 1.093 4.915 apatite-OH 0.2919E-02 -2.535 1.466 0.166 0.9070E-01 0.4660 clinochlore 0.2118 -0.674 117.7 2.071 7.283 44.79 daphnite 0.6071E-01 -1.217 43.32 1.637 2.679 13.13 chlorite-Mn 0.5132E-02 -2.290 3.639 0.561 0.2251 1.160 diopside 0.7612E-01 -1.119 16.48 1.217 1.020 5.038 hedenbergite 0.1950E-01 -1.710 4.838 0.685 0.2992 1.325 microcline 0.2751 -0.561 76.56 1.884 4.736 29.91 stilbite 0.9600 -0.018 676.5 2.830 41.84 315.5 stilpnomelane-Fe 0.7804E-01 -1.108 84.13 1.925 5.203 29.06 tr.625ac.25prg.125 0.1085E-01 -1.965 9.274 0.967 0.5736 2.985 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1848E-01 0.1848E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1616.767667 g Volume = 654.896512 cm3 Porosity: -10.4379% V(tot) - V(min): -.61897E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1479.9990000 g log = 3.1703 Original solution: 1000.0103000 g Original solution / Rock added: 0.68 (Water/Rock Ratio), log = -0.1703 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0898 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9658E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4425E-08 1.0071 0.4856E-08 0.4822E-08 CH4,gas 0.2054E-01 1.0128 0.2268E-01 0.2239E-01 H2,gas 0.1367E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1531E-06 0.9958 0.1662E-06 0.1669E-06 S2,gas 0.4269E-29 1.0000 0.4652E-29 0.4652E-29 CO,gas 0.1721E-13 1.0000 0.1876E-13 0.1876E-13 SO3,gas 0.9367E-48 1.0000 0.1021E-47 0.1021E-47 SO2,gas 0.5284E-27 1.0000 0.5758E-27 0.5758E-27 HCl,gas 0.3112E-17 1.0000 0.3391E-17 0.3391E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.68 -10.31 -3.438 0.17610E+05 -8.314 3 CH4,gas 4.81 1.16 -3.64 -0.911 0.62228E+04 -1.644 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.72 -8.78 -4.390 0.14991E+05 -6.779 6 S2,gas -7.03 -38.37 -31.33 -4.820 0.53499E+05 -29.332 7 CO,gas 3.51 -12.22 -15.73 -4.839 0.26853E+05 -13.727 8 SO3,gas 17.43 -32.56 -49.99 -12.498 0.85358E+05 -47.991 9 SO2,gas 1.14 -28.10 -29.24 -7.797 0.49926E+05 -27.240 10 HCl,gas 5.48 -13.99 -19.47 -9.735 0.33244E+05 -17.470 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80710E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94124E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.57 -4.56 -1.519 0.77803E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.57 -4.40 -1.468 0.75189E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70325E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65584E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36457E+04 66 diamond -3.11 -7.76 -4.65 -1.328 0.79377E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66054E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.76 -4.21 -1.202 0.71839E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82297E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61284E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53669E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20056E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92771E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40695E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43444E+04 143 pyrrhotite -4.24 -7.98 -3.74 -1.245 0.63786E+04 144 pyrrhotiteFe0.875 -6.00 -9.38 -3.37 -1.241 0.57613E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22464E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28302E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23257E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47201E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91031E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65757E+04 181 troilite-low -4.39 -7.98 -3.59 -1.195 0.61218E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80422E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66779E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60333E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.47 -4.51 -1.504 0.77034E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1479.9990000 g New total amount of reactant added: 1519.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1519.9990000 Water: Moles liquid = 0.4694E+02 kg liquid = 0.8457E+00 Moles total = 0.3645E+02 kg total = 0.6567E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174959E-01 Osmotic coef. = 0.9687 True ionic strength = .2070060E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90328E-10 -10.0442 0.75779E-10 -10.1205 0.83893E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16239E-03 -3.7894 0.13540E-03 -3.8684 0.83377E+00 -0.0790 4 SO4-- 0.92620E-12 -12.0333 0.47778E-12 -12.3208 0.51585E+00 -0.2875 5 HCO3- 0.33411E-06 -6.4761 0.27899E-06 -6.5544 0.83502E+00 -0.0783 6 HS- 0.30152E-04 -4.5207 0.25144E-04 -4.5996 0.83390E+00 -0.0789 7 Al+++ 0.11029E-28 -28.9575 0.25093E-29 -29.6004 0.22752E+00 -0.6430 8 H4SiO4 0.71162E-03 -3.1477 0.71162E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14335E-06 -6.8436 0.73393E-07 -7.1343 0.51198E+00 -0.2907 10 Mg++ 0.22763E-10 -10.6428 0.11600E-10 -10.9356 0.50959E+00 -0.2928 11 Fe++ 0.62264E-13 -13.2058 0.31765E-13 -13.4981 0.51016E+00 -0.2923 12 K+ 0.16154E-03 -3.7917 0.13492E-03 -3.8699 0.83522E+00 -0.0782 13 Na+ 0.20538E-01 -1.6874 0.17121E-01 -1.7665 0.83362E+00 -0.0790 14 Mn++ 0.19917E-10 -10.7008 0.10170E-10 -10.9927 0.51059E+00 -0.2919 15 HPO4-- 0.48730E-07 -7.3122 0.25141E-07 -7.5996 0.51592E+00 -0.2874 16 HSiO3- 0.10989E-01 -1.9590 0.91623E-02 -2.0380 0.83377E+00 -0.0790 17 Ca(HSiO3)+ 0.18035E-07 -7.7439 0.15066E-07 -7.8220 0.83540E+00 -0.0781 18 Mg(HSiO3)+ 0.35474E-11 -11.4501 0.29635E-11 -11.5282 0.83540E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67527E-16 -16.1705 0.56412E-16 -16.2486 0.83540E+00 -0.0781 22 HAlO2,aq 0.14897E-09 -9.8269 0.14897E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52743E-05 -5.2778 0.43895E-05 -5.3576 0.83224E+00 -0.0797 24 CH4,aq 0.14459E-04 -4.8399 0.14407E-04 -4.8414 0.99642E+00 -0.0016 25 C2H6,aq 0.33045E-14 -14.4809 0.32927E-14 -14.4824 0.99642E+00 -0.0016 29 CO,aq 0.11935E-16 -16.9232 0.11935E-16 -16.9232 0.10000E+01 0.0000 30 CO2,aq 0.42779E-10 -10.3688 0.42625E-10 -10.3703 0.99642E+00 -0.0016 31 CO3-2 0.66132E-06 -6.1796 0.34040E-06 -6.4680 0.51473E+00 -0.2884 32 CaCO3,aq 0.30598E-09 -9.5143 0.30598E-09 -9.5143 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.61759E-12 -12.2093 0.51593E-12 -12.2874 0.83540E+00 -0.0781 34 CaCl+ 0.18955E-10 -10.7223 0.15835E-10 -10.8004 0.83540E+00 -0.0781 35 CaCl2,aq 0.49920E-15 -15.3017 0.49920E-15 -15.3017 0.10000E+01 0.0000 36 CaOH+ 0.81749E-07 -7.0875 0.68293E-07 -7.1656 0.83540E+00 -0.0781 37 CaSO4,aq 0.10926E-16 -16.9616 0.10926E-16 -16.9616 0.10000E+01 0.0000 38 HCl,aq 0.19299E-14 -14.7145 0.19299E-14 -14.7145 0.10000E+01 0.0000 43 FeCl+ 0.80184E-17 -17.0959 0.66986E-17 -17.1740 0.83540E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16635E-10 -10.7790 0.13897E-10 -10.8571 0.83540E+00 -0.0781 48 HFeO2- 0.37238E-07 -7.4290 0.31048E-07 -7.5080 0.83377E+00 -0.0790 49 FeO+ 0.12278E-16 -16.9109 0.10257E-16 -16.9890 0.83540E+00 -0.0781 51 FeO2- 0.42103E-09 -9.3757 0.35105E-09 -9.4546 0.83377E+00 -0.0790 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.32347E-09 -9.4902 0.32347E-09 -9.4902 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11911E-14 -14.9240 0.99315E-15 -15.0030 0.83377E+00 -0.0790 58 MgCO3,aq 0.12084E-13 -13.9178 0.12084E-13 -13.9178 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.99535E-16 -16.0020 0.83152E-16 -16.0801 0.83540E+00 -0.0781 60 MgCl+ 0.27196E-14 -14.5655 0.22720E-14 -14.6436 0.83540E+00 -0.0781 61 MgOH+ 0.71580E-10 -10.1452 0.59798E-10 -10.2233 0.83540E+00 -0.0781 63 MnO,aq 0.18695E-08 -8.7283 0.18695E-08 -8.7283 0.10000E+01 0.0000 64 MnOH+ 0.49474E-09 -9.3056 0.41331E-09 -9.3837 0.83540E+00 -0.0781 65 MnO2-2 0.21874E-10 -10.6601 0.11259E-10 -10.9485 0.51473E+00 -0.2884 66 HMnO2- 0.22171E-09 -9.6542 0.18485E-09 -9.7332 0.83377E+00 -0.0790 69 MnCl+ 0.99755E-14 -14.0011 0.83336E-14 -14.0792 0.83540E+00 -0.0781 71 NaCl,aq 0.75691E-06 -6.1210 0.75691E-06 -6.1210 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95112E-02 -2.0218 0.79156E-02 -2.1015 0.83224E+00 -0.0797 79 HPO3-2 0.16771E-14 -14.7754 0.86327E-15 -15.0639 0.51473E+00 -0.2884 81 H2PO3- 0.15412E-18 -18.8121 0.12850E-18 -18.8911 0.83377E+00 -0.0790 82 H3PO4,aq 0.92944E-18 -18.0318 0.92944E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40021E-10 -10.3977 0.33401E-10 -10.4762 0.83458E+00 -0.0785 84 PO4-3 0.12112E-08 -8.9168 0.28973E-09 -9.5380 0.23921E+00 -0.6212 88 HP2O7-3 0.10374E-17 -17.9841 0.23627E-18 -18.6266 0.22776E+00 -0.6425 89 P2O7-4 0.10244E-16 -16.9895 0.76917E-18 -18.1140 0.75084E-01 -1.1245 90 H2S,aq 0.57453E-08 -8.2407 0.57248E-08 -8.2422 0.99642E+00 -0.0016 91 S2-2 0.24848E-14 -14.6047 0.12790E-14 -14.8931 0.51473E+00 -0.2884 97 SO3-2 0.13558E-17 -17.8678 0.70820E-18 -18.1498 0.52233E+00 -0.2821 99 HSO4- 0.40172E-19 -19.3961 0.33593E-19 -19.4737 0.83623E+00 -0.0777 Charge balance for all species = 0.3899E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9032820E-10 -.2311627E-01 -.2325762E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981178E+06 0.0000 3 Cl- 0.1623903E-03 0.1631475E-03 0.5773594E+01 6.2521 4 SO4-- 0.9261975E-12 -.1718635E-04 -.1647959E+01 7.9201 5 HCO3- 0.3341123E-06 0.1545462E-04 0.9412897E+00 3.5660 6 HS- 0.3015201E-04 0.4734411E-04 0.1562929E+01 5.5209 7 Al+++ 0.1102912E-28 0.5274415E-05 0.1420539E+00 0.7609 8 H4SiO4 0.7116238E-03 0.1419200E-01 0.1361599E+04 -3.1477 9 Ca++ 0.1433528E-06 0.2434625E-06 0.9739817E-02 13.1066 10 Mg++ 0.2276298E-10 0.9790447E-10 0.2375943E-05 9.3054 11 Fe++ 0.6226442E-13 0.3789788E-07 0.2112650E-02 6.7428 12 K+ 0.1615430E-03 0.1623196E-03 0.6335524E+01 6.2505 13 Na+ 0.2053781E-01 0.2312924E-01 0.5307735E+03 8.3540 14 Mn++ 0.1991748E-10 0.2627754E-08 0.1441021E-03 9.2482 15 HPO4-- 0.4872982E-07 0.4998104E-07 0.4788442E-02 12.6413 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2516891E+02 -.1954948E-01 -.2514936E+02 0.0000000E+00 2 H2O 0.3645444E+02 0.4694019E+02 -.1048575E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4214986E-01 -.1453453E-04 0.4216439E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4212435E-01 0.4003900E-04 -.4216439E-01 0.0000000E+00 7 Al+++ 0.4956324E+01 0.4460583E-05 0.4956320E+01 0.0000000E+00 8 H4SiO4 0.1582742E+02 0.1200220E-01 0.1581542E+02 0.0000000E+00 9 Ca++ 0.1748230E+01 0.2058967E-06 0.1748230E+01 0.0000000E+00 10 Mg++ 0.1206348E+01 0.8279799E-10 0.1206348E+01 0.0000000E+00 11 Fe++ 0.1083772E+01 0.3205031E-07 0.1083772E+01 0.0000000E+00 12 K+ 0.3227174E+00 0.1372740E-03 0.3225801E+00 0.0000000E+00 13 Na+ 0.1908129E+01 0.1956044E-01 0.1888569E+01 0.0000000E+00 14 Mn++ 0.2635465E-01 0.2222296E-08 0.2635465E-01 0.0000000E+00 15 HPO4-- 0.8994711E-02 0.4226906E-07 0.8994668E-02 0.0000000E+00 Chg. balance for solid moles: 0.3143E-14 Mass of aqueous solution: 0.847236E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1519.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.887 0.276 494.9 2.694 29.80 190.0 andradite 0.1687 -0.773 85.71 1.933 5.162 22.27 grossular 0.4028E-01 -1.395 18.14 1.259 1.093 5.048 apatite-OH 0.2998E-02 -2.523 1.506 0.178 0.9070E-01 0.4786 clinochlore 0.2175 -0.662 120.9 2.082 7.281 45.99 daphnite 0.6234E-01 -1.205 44.48 1.648 2.679 13.48 chlorite-Mn 0.5271E-02 -2.278 3.737 0.573 0.2251 1.191 diopside 0.7843E-01 -1.106 16.98 1.230 1.023 5.191 hedenbergite 0.2009E-01 -1.697 4.985 0.698 0.3002 1.365 microcline 0.2825 -0.549 78.63 1.896 4.736 30.72 stilbite 0.9857 -0.006 694.6 2.842 41.83 324.0 stilpnomelane-Fe 0.8015E-01 -1.096 86.40 1.937 5.204 29.85 tr.625ac.25prg.125 0.1112E-01 -1.954 9.507 0.978 0.5725 3.060 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1849E-01 0.1849E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1660.469859 g Volume = 672.579055 cm3 Porosity: -10.4400% V(tot) - V(min): -.63579E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1519.9990000 g log = 3.1818 Original solution: 1000.0103000 g Original solution / Rock added: 0.66 (Water/Rock Ratio), log = -0.1818 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0899 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9657E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4445E-08 1.0071 0.4879E-08 0.4845E-08 CH4,gas 0.2064E-01 1.0128 0.2278E-01 0.2249E-01 H2,gas 0.1367E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1538E-06 0.9958 0.1670E-06 0.1677E-06 S2,gas 0.4309E-29 1.0000 0.4696E-29 0.4696E-29 CO,gas 0.1729E-13 1.0000 0.1885E-13 0.1885E-13 SO3,gas 0.9411E-48 1.0000 0.1026E-47 0.1026E-47 SO2,gas 0.5309E-27 1.0000 0.5786E-27 0.5786E-27 HCl,gas 0.3127E-17 1.0000 0.3408E-17 0.3408E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.48529E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.67 -10.31 -3.437 0.17607E+05 -8.312 3 CH4,gas 4.81 1.17 -3.64 -0.911 0.62193E+04 -1.642 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.827 5 H2S,gas -5.94 -14.72 -8.78 -4.389 0.14987E+05 -6.777 6 S2,gas -7.03 -38.36 -31.33 -4.820 0.53492E+05 -29.328 7 CO,gas 3.51 -12.21 -15.72 -4.838 0.26850E+05 -13.725 8 SO3,gas 17.43 -32.56 -49.99 -12.497 0.85355E+05 -47.989 9 SO2,gas 1.14 -28.10 -29.24 -7.797 0.49922E+05 -27.238 10 HCl,gas 5.48 -13.99 -19.47 -9.734 0.33240E+05 -17.468 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80707E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94124E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.57 -4.55 -1.518 0.77767E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.57 -4.40 -1.467 0.75154E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65583E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.75 -4.65 -1.328 0.79342E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66054E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.75 -4.21 -1.202 0.71804E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82296E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61284E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53669E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20056E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92771E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40696E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43444E+04 143 pyrrhotite -4.24 -7.98 -3.73 -1.245 0.63750E+04 144 pyrrhotiteFe0.875 -6.00 -9.37 -3.37 -1.240 0.57578E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22463E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28301E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23255E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47198E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91031E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.98 -3.58 -1.194 0.61182E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80422E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66780E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60333E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.47 -4.51 -1.503 0.76997E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1519.9990000 g New total amount of reactant added: 1559.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1559.9990000 Water: Moles liquid = 0.4672E+02 kg liquid = 0.8417E+00 Moles total = 0.3595E+02 kg total = 0.6477E+00 Activity = 1.0000 Stoichiometric ionic strength = .1175025E-01 Osmotic coef. = 0.9687 True ionic strength = .2070111E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90330E-10 -10.0442 0.75781E-10 -10.1204 0.83893E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16317E-03 -3.7874 0.13604E-03 -3.8663 0.83377E+00 -0.0790 4 SO4-- 0.93062E-12 -12.0312 0.48005E-12 -12.3187 0.51584E+00 -0.2875 5 HCO3- 0.33571E-06 -6.4740 0.28032E-06 -6.5523 0.83501E+00 -0.0783 6 HS- 0.30296E-04 -4.5186 0.25264E-04 -4.5975 0.83390E+00 -0.0789 7 Al+++ 0.11030E-28 -28.9574 0.25095E-29 -29.6004 0.22751E+00 -0.6430 8 H4SiO4 0.71163E-03 -3.1477 0.71163E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14336E-06 -6.8436 0.73397E-07 -7.1343 0.51197E+00 -0.2908 10 Mg++ 0.22764E-10 -10.6427 0.11600E-10 -10.9355 0.50958E+00 -0.2928 11 Fe++ 0.62268E-13 -13.2057 0.31766E-13 -13.4980 0.51015E+00 -0.2923 12 K+ 0.16155E-03 -3.7917 0.13493E-03 -3.8699 0.83521E+00 -0.0782 13 Na+ 0.20538E-01 -1.6874 0.17121E-01 -1.7665 0.83361E+00 -0.0790 14 Mn++ 0.19922E-10 -10.7007 0.10172E-10 -10.9926 0.51058E+00 -0.2919 15 HPO4-- 0.48728E-07 -7.3122 0.25140E-07 -7.5996 0.51592E+00 -0.2874 16 HSiO3- 0.10989E-01 -1.9591 0.91621E-02 -2.0380 0.83377E+00 -0.0790 17 Ca(HSiO3)+ 0.18035E-07 -7.7439 0.15067E-07 -7.8220 0.83540E+00 -0.0781 18 Mg(HSiO3)+ 0.35475E-11 -11.4501 0.29636E-11 -11.5282 0.83540E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67528E-16 -16.1705 0.56413E-16 -16.2486 0.83540E+00 -0.0781 22 HAlO2,aq 0.14897E-09 -9.8269 0.14897E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52741E-05 -5.2778 0.43894E-05 -5.3576 0.83224E+00 -0.0798 24 CH4,aq 0.14528E-04 -4.8378 0.14476E-04 -4.8394 0.99642E+00 -0.0016 25 C2H6,aq 0.33362E-14 -14.4768 0.33242E-14 -14.4783 0.99642E+00 -0.0016 29 CO,aq 0.11992E-16 -16.9211 0.11992E-16 -16.9211 0.10000E+01 0.0000 30 CO2,aq 0.42984E-10 -10.3667 0.42830E-10 -10.3683 0.99642E+00 -0.0016 31 CO3-2 0.66446E-06 -6.1775 0.34202E-06 -6.4660 0.51473E+00 -0.2884 32 CaCO3,aq 0.30745E-09 -9.5122 0.30745E-09 -9.5122 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.62056E-12 -12.2072 0.51842E-12 -12.2853 0.83540E+00 -0.0781 34 CaCl+ 0.19046E-10 -10.7202 0.15911E-10 -10.7983 0.83540E+00 -0.0781 35 CaCl2,aq 0.50400E-15 -15.2976 0.50400E-15 -15.2976 0.10000E+01 0.0000 36 CaOH+ 0.81751E-07 -7.0875 0.68295E-07 -7.1656 0.83540E+00 -0.0781 37 CaSO4,aq 0.10978E-16 -16.9595 0.10978E-16 -16.9595 0.10000E+01 0.0000 38 HCl,aq 0.19392E-14 -14.7124 0.19392E-14 -14.7124 0.10000E+01 0.0000 43 FeCl+ 0.80571E-17 -17.0938 0.67309E-17 -17.1719 0.83540E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16635E-10 -10.7790 0.13897E-10 -10.8571 0.83540E+00 -0.0781 48 HFeO2- 0.37237E-07 -7.4290 0.31047E-07 -7.5080 0.83377E+00 -0.0790 49 FeO+ 0.12278E-16 -16.9109 0.10257E-16 -16.9890 0.83540E+00 -0.0781 51 FeO2- 0.42102E-09 -9.3757 0.35104E-09 -9.4546 0.83377E+00 -0.0790 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.32502E-09 -9.4881 0.32502E-09 -9.4881 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11969E-14 -14.9220 0.99790E-15 -15.0009 0.83377E+00 -0.0790 58 MgCO3,aq 0.12142E-13 -13.9157 0.12142E-13 -13.9157 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10001E-15 -15.9999 0.83552E-16 -16.0780 0.83540E+00 -0.0781 60 MgCl+ 0.27327E-14 -14.5634 0.22829E-14 -14.6415 0.83540E+00 -0.0781 61 MgOH+ 0.71581E-10 -10.1452 0.59799E-10 -10.2233 0.83540E+00 -0.0781 63 MnO,aq 0.18698E-08 -8.7282 0.18698E-08 -8.7282 0.10000E+01 0.0000 64 MnOH+ 0.49483E-09 -9.3055 0.41338E-09 -9.3836 0.83540E+00 -0.0781 65 MnO2-2 0.21876E-10 -10.6600 0.11260E-10 -10.9485 0.51473E+00 -0.2884 66 HMnO2- 0.22174E-09 -9.6542 0.18488E-09 -9.7331 0.83377E+00 -0.0790 69 MnCl+ 0.10025E-13 -13.9989 0.83750E-14 -14.0770 0.83540E+00 -0.0781 71 NaCl,aq 0.76054E-06 -6.1189 0.76054E-06 -6.1189 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95110E-02 -2.0218 0.79154E-02 -2.1015 0.83224E+00 -0.0798 79 HPO3-2 0.16771E-14 -14.7755 0.86323E-15 -15.0639 0.51473E+00 -0.2884 81 H2PO3- 0.15412E-18 -18.8122 0.12850E-18 -18.8911 0.83377E+00 -0.0790 82 H3PO4,aq 0.92944E-18 -18.0318 0.92944E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40021E-10 -10.3977 0.33400E-10 -10.4762 0.83458E+00 -0.0785 84 PO4-3 0.12111E-08 -8.9168 0.28972E-09 -9.5380 0.23921E+00 -0.6212 88 HP2O7-3 0.10373E-17 -17.9841 0.23625E-18 -18.6266 0.22775E+00 -0.6425 89 P2O7-4 0.10244E-16 -16.9895 0.76911E-18 -18.1140 0.75082E-01 -1.1245 90 H2S,aq 0.57729E-08 -8.2386 0.57522E-08 -8.2402 0.99642E+00 -0.0016 91 S2-2 0.25086E-14 -14.6006 0.12913E-14 -14.8890 0.51473E+00 -0.2884 97 SO3-2 0.13623E-17 -17.8657 0.71157E-18 -18.1478 0.52233E+00 -0.2821 99 HSO4- 0.40365E-19 -19.3940 0.33754E-19 -19.4717 0.83623E+00 -0.0777 Charge balance for all species = 0.3918E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9033042E-10 -.2311586E-01 -.2325721E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981177E+06 0.0000 3 Cl- 0.1631656E-03 0.1639265E-03 0.5801161E+01 6.2541 4 SO4-- 0.9306189E-12 -.1725539E-04 -.1654579E+01 7.9222 5 HCO3- 0.3357065E-06 0.1552841E-04 0.9457839E+00 3.5681 6 HS- 0.3029597E-04 0.4755714E-04 0.1569961E+01 5.5229 7 Al+++ 0.1102998E-28 0.5274274E-05 0.1420501E+00 0.7609 8 H4SiO4 0.7116251E-03 0.1419179E-01 0.1361579E+04 -3.1477 9 Ca++ 0.1433601E-06 0.2434736E-06 0.9740263E-02 13.1066 10 Mg++ 0.2276414E-10 0.9790788E-10 0.2376025E-05 9.3054 11 Fe++ 0.6226766E-13 0.3789705E-07 0.2112604E-02 6.7428 12 K+ 0.1615470E-03 0.1623235E-03 0.6335679E+01 6.2505 13 Na+ 0.2053832E-01 0.2312975E-01 0.5307853E+03 8.3540 14 Mn++ 0.1992164E-10 0.2628172E-08 0.1441250E-03 9.2483 15 HPO4-- 0.4872805E-07 0.4997921E-07 0.4788267E-02 12.6412 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2583125E+02 -.1945623E-01 -.2581180E+02 0.0000000E+00 2 H2O 0.3595302E+02 0.4671713E+02 -.1076411E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4325839E-01 -.1452357E-04 0.4327292E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4323289E-01 0.4002804E-04 -.4327292E-01 0.0000000E+00 7 Al+++ 0.5086754E+01 0.4439267E-05 0.5086749E+01 0.0000000E+00 8 H4SiO4 0.1624393E+02 0.1194499E-01 0.1623199E+02 0.0000000E+00 9 Ca++ 0.1794236E+01 0.2049276E-06 0.1794236E+01 0.0000000E+00 10 Mg++ 0.1238094E+01 0.8240741E-10 0.1238094E+01 0.0000000E+00 11 Fe++ 0.1112293E+01 0.3189731E-07 0.1112293E+01 0.0000000E+00 12 K+ 0.3312100E+00 0.1366250E-03 0.3310734E+00 0.0000000E+00 13 Na+ 0.1958339E+01 0.1946792E-01 0.1938871E+01 0.0000000E+00 14 Mn++ 0.2704819E-01 0.2212088E-08 0.2704819E-01 0.0000000E+00 15 HPO4-- 0.9231414E-02 0.4206666E-07 0.9231372E-02 0.0000000E+00 Chg. balance for solid moles: -.6245E-15 Mass of aqueous solution: 0.843210E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1559.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.937 0.287 508.0 2.706 29.81 195.0 andradite 0.1731 -0.762 87.96 1.944 5.162 22.85 grossular 0.4133E-01 -1.384 18.62 1.270 1.093 5.181 apatite-OH 0.3077E-02 -2.512 1.546 0.189 0.9070E-01 0.4912 clinochlore 0.2232 -0.651 124.1 2.094 7.280 47.19 daphnite 0.6397E-01 -1.194 45.64 1.659 2.678 13.83 chlorite-Mn 0.5410E-02 -2.267 3.835 0.584 0.2251 1.222 diopside 0.8074E-01 -1.093 17.49 1.243 1.026 5.344 hedenbergite 0.2068E-01 -1.684 5.132 0.710 0.3011 1.406 microcline 0.2899 -0.538 80.70 1.907 4.736 31.52 stilbite 1.011 0.005 712.7 2.853 41.82 332.4 stilpnomelane-Fe 0.8227E-01 -1.085 88.68 1.948 5.204 30.63 tr.625ac.25prg.125 0.1139E-01 -1.943 9.740 0.989 0.5715 3.135 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1849E-01 0.1849E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1704.172051 g Volume = 690.261598 cm3 Porosity: -10.4419% V(tot) - V(min): -.65262E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1559.9990000 g log = 3.1931 Original solution: 1000.0103000 g Original solution / Rock added: 0.64 (Water/Rock Ratio), log = -0.1931 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0900 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9656E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4466E-08 1.0071 0.4903E-08 0.4868E-08 CH4,gas 0.2074E-01 1.0128 0.2289E-01 0.2260E-01 H2,gas 0.1367E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1546E-06 0.9958 0.1678E-06 0.1685E-06 S2,gas 0.4350E-29 1.0000 0.4742E-29 0.4742E-29 CO,gas 0.1737E-13 1.0000 0.1894E-13 0.1894E-13 SO3,gas 0.9456E-48 1.0000 0.1031E-47 0.1031E-47 SO2,gas 0.5334E-27 1.0000 0.5813E-27 0.5813E-27 HCl,gas 0.3141E-17 1.0000 0.3424E-17 0.3424E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.67 -10.31 -3.437 0.17603E+05 -8.310 3 CH4,gas 4.81 1.17 -3.64 -0.910 0.62157E+04 -1.640 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.72 -8.78 -4.388 0.14984E+05 -6.775 6 S2,gas -7.03 -38.36 -31.32 -4.819 0.53485E+05 -29.324 7 CO,gas 3.51 -12.21 -15.72 -4.838 0.26846E+05 -13.723 8 SO3,gas 17.43 -32.56 -49.99 -12.497 0.85351E+05 -47.987 9 SO2,gas 1.14 -28.10 -29.24 -7.796 0.49919E+05 -27.236 10 HCl,gas 5.48 -13.99 -19.47 -9.733 0.33237E+05 -17.465 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80703E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94124E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.57 -4.55 -1.517 0.77732E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.57 -4.40 -1.466 0.75118E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65582E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.75 -4.64 -1.327 0.79306E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66054E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.75 -4.20 -1.201 0.71768E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82295E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61284E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53669E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20056E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92772E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40696E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43445E+04 143 pyrrhotite -4.24 -7.98 -3.73 -1.244 0.63715E+04 144 pyrrhotiteFe0.875 -6.00 -9.37 -3.37 -1.239 0.57543E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22462E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28301E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23254E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47196E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91031E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.98 -3.58 -1.194 0.61147E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80423E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66780E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60333E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.47 -4.51 -1.502 0.76960E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1559.9990000 g New total amount of reactant added: 1599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1599.9990000 Water: Moles liquid = 0.4650E+02 kg liquid = 0.8377E+00 Moles total = 0.3545E+02 kg total = 0.6387E+00 Activity = 1.0000 Stoichiometric ionic strength = .1175091E-01 Osmotic coef. = 0.9687 True ionic strength = .2070163E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90333E-10 -10.0442 0.75782E-10 -10.1204 0.83892E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16395E-03 -3.7853 0.13670E-03 -3.8642 0.83377E+00 -0.0790 4 SO4-- 0.93508E-12 -12.0292 0.48235E-12 -12.3166 0.51584E+00 -0.2875 5 HCO3- 0.33732E-06 -6.4720 0.28166E-06 -6.5503 0.83501E+00 -0.0783 6 HS- 0.30441E-04 -4.5165 0.25385E-04 -4.5954 0.83389E+00 -0.0789 7 Al+++ 0.11031E-28 -28.9574 0.25096E-29 -29.6004 0.22751E+00 -0.6430 8 H4SiO4 0.71163E-03 -3.1477 0.71163E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14337E-06 -6.8435 0.73400E-07 -7.1343 0.51197E+00 -0.2908 10 Mg++ 0.22765E-10 -10.6427 0.11601E-10 -10.9355 0.50958E+00 -0.2928 11 Fe++ 0.62271E-13 -13.2057 0.31768E-13 -13.4980 0.51015E+00 -0.2923 12 K+ 0.16155E-03 -3.7917 0.13493E-03 -3.8699 0.83521E+00 -0.0782 13 Na+ 0.20539E-01 -1.6874 0.17121E-01 -1.7665 0.83361E+00 -0.0790 14 Mn++ 0.19926E-10 -10.7006 0.10174E-10 -10.9925 0.51058E+00 -0.2919 15 HPO4-- 0.48726E-07 -7.3122 0.25139E-07 -7.5997 0.51592E+00 -0.2874 16 HSiO3- 0.10989E-01 -1.9591 0.91619E-02 -2.0380 0.83377E+00 -0.0790 17 Ca(HSiO3)+ 0.18036E-07 -7.7439 0.15067E-07 -7.8220 0.83540E+00 -0.0781 18 Mg(HSiO3)+ 0.35476E-11 -11.4501 0.29636E-11 -11.5282 0.83540E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67530E-16 -16.1705 0.56414E-16 -16.2486 0.83540E+00 -0.0781 22 HAlO2,aq 0.14897E-09 -9.8269 0.14897E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52740E-05 -5.2779 0.43892E-05 -5.3576 0.83224E+00 -0.0798 24 CH4,aq 0.14598E-04 -4.8357 0.14545E-04 -4.8373 0.99642E+00 -0.0016 25 C2H6,aq 0.33683E-14 -14.4726 0.33562E-14 -14.4741 0.99642E+00 -0.0016 29 CO,aq 0.12050E-16 -16.9190 0.12050E-16 -16.9190 0.10000E+01 0.0000 30 CO2,aq 0.43191E-10 -10.3646 0.43036E-10 -10.3662 0.99642E+00 -0.0016 31 CO3-2 0.66764E-06 -6.1755 0.34365E-06 -6.4639 0.51472E+00 -0.2884 32 CaCO3,aq 0.30893E-09 -9.5101 0.30893E-09 -9.5101 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.62357E-12 -12.2051 0.52092E-12 -12.2832 0.83540E+00 -0.0781 34 CaCl+ 0.19138E-10 -10.7181 0.15988E-10 -10.7962 0.83540E+00 -0.0781 35 CaCl2,aq 0.50887E-15 -15.2934 0.50887E-15 -15.2934 0.10000E+01 0.0000 36 CaOH+ 0.81753E-07 -7.0875 0.68296E-07 -7.1656 0.83540E+00 -0.0781 37 CaSO4,aq 0.11031E-16 -16.9574 0.11031E-16 -16.9574 0.10000E+01 0.0000 38 HCl,aq 0.19485E-14 -14.7103 0.19485E-14 -14.7103 0.10000E+01 0.0000 43 FeCl+ 0.80961E-17 -17.0917 0.67635E-17 -17.1698 0.83540E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16636E-10 -10.7790 0.13897E-10 -10.8571 0.83540E+00 -0.0781 48 HFeO2- 0.37236E-07 -7.4290 0.31047E-07 -7.5080 0.83377E+00 -0.0790 49 FeO+ 0.12278E-16 -16.9109 0.10257E-16 -16.9890 0.83540E+00 -0.0781 51 FeO2- 0.42102E-09 -9.3757 0.35103E-09 -9.4547 0.83377E+00 -0.0790 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.32658E-09 -9.4860 0.32658E-09 -9.4860 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.12026E-14 -14.9199 0.10027E-14 -14.9988 0.83377E+00 -0.0790 58 MgCO3,aq 0.12201E-13 -13.9136 0.12201E-13 -13.9136 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10050E-15 -15.9978 0.83956E-16 -16.0759 0.83540E+00 -0.0781 60 MgCl+ 0.27460E-14 -14.5613 0.22940E-14 -14.6394 0.83540E+00 -0.0781 61 MgOH+ 0.71583E-10 -10.1452 0.59800E-10 -10.2233 0.83540E+00 -0.0781 63 MnO,aq 0.18701E-08 -8.7281 0.18701E-08 -8.7281 0.10000E+01 0.0000 64 MnOH+ 0.49492E-09 -9.3055 0.41345E-09 -9.3836 0.83540E+00 -0.0781 65 MnO2-2 0.21879E-10 -10.6600 0.11261E-10 -10.9484 0.51472E+00 -0.2884 66 HMnO2- 0.22177E-09 -9.6541 0.18490E-09 -9.7331 0.83377E+00 -0.0790 69 MnCl+ 0.10075E-13 -13.9967 0.84168E-14 -14.0749 0.83540E+00 -0.0781 71 NaCl,aq 0.76421E-06 -6.1168 0.76421E-06 -6.1168 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95108E-02 -2.0218 0.79152E-02 -2.1015 0.83224E+00 -0.0798 79 HPO3-2 0.16770E-14 -14.7755 0.86318E-15 -15.0639 0.51472E+00 -0.2884 81 H2PO3- 0.15411E-18 -18.8122 0.12849E-18 -18.8911 0.83377E+00 -0.0790 82 H3PO4,aq 0.92945E-18 -18.0318 0.92945E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40020E-10 -10.3977 0.33400E-10 -10.4763 0.83458E+00 -0.0785 84 PO4-3 0.12111E-08 -8.9168 0.28970E-09 -9.5381 0.23921E+00 -0.6212 88 HP2O7-3 0.10373E-17 -17.9841 0.23624E-18 -18.6266 0.22775E+00 -0.6425 89 P2O7-4 0.10243E-16 -16.9896 0.76904E-18 -18.1141 0.75080E-01 -1.1245 90 H2S,aq 0.58007E-08 -8.2365 0.57799E-08 -8.2381 0.99642E+00 -0.0016 91 S2-2 0.25328E-14 -14.5964 0.13037E-14 -14.8848 0.51472E+00 -0.2884 97 SO3-2 0.13688E-17 -17.8636 0.71498E-18 -18.1457 0.52233E+00 -0.2821 99 HSO4- 0.40559E-19 -19.3919 0.33917E-19 -19.4696 0.83623E+00 -0.0777 Charge balance for all species = 0.3935E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9033265E-10 -.2311545E-01 -.2325679E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981177E+06 0.0000 3 Cl- 0.1639484E-03 0.1647129E-03 0.5828991E+01 6.2562 4 SO4-- 0.9350818E-12 -.1732510E-04 -.1661262E+01 7.9242 5 HCO3- 0.3373156E-06 0.1560291E-04 0.9503213E+00 3.5702 6 HS- 0.3044132E-04 0.4777221E-04 0.1577061E+01 5.5250 7 Al+++ 0.1103086E-28 0.5274132E-05 0.1420463E+00 0.7609 8 H4SiO4 0.7116264E-03 0.1419158E-01 0.1361559E+04 -3.1477 9 Ca++ 0.1433674E-06 0.2434849E-06 0.9740713E-02 13.1066 10 Mg++ 0.2276530E-10 0.9791026E-10 0.2376083E-05 9.3054 11 Fe++ 0.6227093E-13 0.3789622E-07 0.2112557E-02 6.7428 12 K+ 0.1615510E-03 0.1623276E-03 0.6335836E+01 6.2505 13 Na+ 0.2053883E-01 0.2313027E-01 0.5307972E+03 8.3540 14 Mn++ 0.1992566E-10 0.2628571E-08 0.1441469E-03 9.2483 15 HPO4-- 0.4872626E-07 0.4997735E-07 0.4788089E-02 12.6412 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2649360E+02 -.1936299E-01 -.2647423E+02 0.0000000E+00 2 H2O 0.3545161E+02 0.4649408E+02 -.1104247E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4436693E-01 -.1451262E-04 0.4438144E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4434143E-01 0.4001709E-04 -.4438144E-01 0.0000000E+00 7 Al+++ 0.5217183E+01 0.4417953E-05 0.5217179E+01 0.0000000E+00 8 H4SiO4 0.1666044E+02 0.1188778E-01 0.1664855E+02 0.0000000E+00 9 Ca++ 0.1840242E+01 0.2039586E-06 0.1840241E+01 0.0000000E+00 10 Mg++ 0.1269840E+01 0.8201595E-10 0.1269840E+01 0.0000000E+00 11 Fe++ 0.1140813E+01 0.3174431E-07 0.1140813E+01 0.0000000E+00 12 K+ 0.3397025E+00 0.1359760E-03 0.3395666E+00 0.0000000E+00 13 Na+ 0.2008549E+01 0.1937541E-01 0.1989173E+01 0.0000000E+00 14 Mn++ 0.2774174E-01 0.2201860E-08 0.2774173E-01 0.0000000E+00 15 HPO4-- 0.9468117E-02 0.4186425E-07 0.9468075E-02 0.0000000E+00 Chg. balance for solid moles: -.8327E-15 Mass of aqueous solution: 0.839184E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.988 0.298 521.2 2.717 29.82 200.1 andradite 0.1775 -0.751 90.22 1.955 5.161 23.44 grossular 0.4239E-01 -1.373 19.10 1.281 1.093 5.313 apatite-OH 0.3156E-02 -2.501 1.585 0.200 0.9070E-01 0.5038 clinochlore 0.2289 -0.640 127.2 2.105 7.279 48.39 daphnite 0.6560E-01 -1.183 46.81 1.670 2.678 14.18 chlorite-Mn 0.5548E-02 -2.256 3.934 0.595 0.2251 1.254 diopside 0.8306E-01 -1.081 17.99 1.255 1.029 5.497 hedenbergite 0.2128E-01 -1.672 5.279 0.723 0.3020 1.446 microcline 0.2974 -0.527 82.77 1.918 4.736 32.33 stilbite 1.037 0.016 730.8 2.864 41.81 340.9 stilpnomelane-Fe 0.8438E-01 -1.074 90.96 1.959 5.204 31.42 tr.625ac.25prg.125 0.1167E-01 -1.933 9.973 0.999 0.5706 3.210 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1849E-01 0.1849E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1747.874243 g Volume = 707.944141 cm3 Porosity: -10.4438% V(tot) - V(min): -.66945E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1599.9990000 g log = 3.2041 Original solution: 1000.0103000 g Original solution / Rock added: 0.63 (Water/Rock Ratio), log = -0.2041 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0901 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9655E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4487E-08 1.0071 0.4926E-08 0.4891E-08 CH4,gas 0.2083E-01 1.0128 0.2300E-01 0.2271E-01 H2,gas 0.1367E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1553E-06 0.9958 0.1686E-06 0.1693E-06 S2,gas 0.4392E-29 1.0000 0.4788E-29 0.4788E-29 CO,gas 0.1745E-13 1.0000 0.1903E-13 0.1903E-13 SO3,gas 0.9500E-48 1.0000 0.1036E-47 0.1036E-47 SO2,gas 0.5359E-27 1.0000 0.5842E-27 0.5842E-27 HCl,gas 0.3156E-17 1.0000 0.3441E-17 0.3441E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.67 -10.31 -3.436 0.17600E+05 -8.307 3 CH4,gas 4.81 1.17 -3.64 -0.910 0.62122E+04 -1.638 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.72 -8.77 -4.387 0.14980E+05 -6.773 6 S2,gas -7.03 -38.35 -31.32 -4.818 0.53478E+05 -29.320 7 CO,gas 3.51 -12.21 -15.72 -4.837 0.26843E+05 -13.721 8 SO3,gas 17.43 -32.56 -49.98 -12.496 0.85348E+05 -47.985 9 SO2,gas 1.14 -28.10 -29.23 -7.796 0.49915E+05 -27.233 10 HCl,gas 5.48 -13.98 -19.46 -9.732 0.33233E+05 -17.463 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80700E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94125E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.56 -4.55 -1.517 0.77696E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.56 -4.40 -1.466 0.75083E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65581E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.75 -4.64 -1.326 0.79271E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66054E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.75 -4.20 -1.200 0.71733E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82293E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61284E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53669E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92772E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40696E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43445E+04 143 pyrrhotite -4.24 -7.97 -3.73 -1.243 0.63679E+04 144 pyrrhotiteFe0.875 -6.00 -9.37 -3.37 -1.239 0.57507E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22461E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28301E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23253E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47194E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91030E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.97 -3.58 -1.193 0.61111E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80423E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66780E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60333E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.47 -4.51 -1.502 0.76924E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1599.9990000 g New total amount of reactant added: 1639.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1639.9990000 Water: Moles liquid = 0.4627E+02 kg liquid = 0.8336E+00 Moles total = 0.3495E+02 kg total = 0.6296E+00 Activity = 1.0000 Stoichiometric ionic strength = .1175157E-01 Osmotic coef. = 0.9687 True ionic strength = .2070216E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90335E-10 -10.0441 0.75784E-10 -10.1204 0.83892E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16474E-03 -3.7832 0.13735E-03 -3.8622 0.83377E+00 -0.0790 4 SO4-- 0.93959E-12 -12.0271 0.48467E-12 -12.3146 0.51584E+00 -0.2875 5 HCO3- 0.33894E-06 -6.4699 0.28302E-06 -6.5482 0.83501E+00 -0.0783 6 HS- 0.30588E-04 -4.5144 0.25507E-04 -4.5933 0.83389E+00 -0.0789 7 Al+++ 0.11032E-28 -28.9574 0.25098E-29 -29.6004 0.22751E+00 -0.6430 8 H4SiO4 0.71163E-03 -3.1477 0.71163E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14337E-06 -6.8435 0.73403E-07 -7.1343 0.51197E+00 -0.2908 10 Mg++ 0.22766E-10 -10.6427 0.11601E-10 -10.9355 0.50958E+00 -0.2928 11 Fe++ 0.62274E-13 -13.2057 0.31769E-13 -13.4980 0.51015E+00 -0.2923 12 K+ 0.16156E-03 -3.7917 0.13493E-03 -3.8699 0.83521E+00 -0.0782 13 Na+ 0.20539E-01 -1.6874 0.17122E-01 -1.7664 0.83361E+00 -0.0790 14 Mn++ 0.19930E-10 -10.7005 0.10176E-10 -10.9924 0.51058E+00 -0.2919 15 HPO4-- 0.48724E-07 -7.3123 0.25138E-07 -7.5997 0.51591E+00 -0.2874 16 HSiO3- 0.10988E-01 -1.9591 0.91617E-02 -2.0380 0.83377E+00 -0.0790 17 Ca(HSiO3)+ 0.18036E-07 -7.7439 0.15068E-07 -7.8220 0.83540E+00 -0.0781 18 Mg(HSiO3)+ 0.35477E-11 -11.4501 0.29637E-11 -11.5282 0.83540E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67531E-16 -16.1705 0.56415E-16 -16.2486 0.83540E+00 -0.0781 22 HAlO2,aq 0.14897E-09 -9.8269 0.14897E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52738E-05 -5.2779 0.43891E-05 -5.3576 0.83224E+00 -0.0798 24 CH4,aq 0.14668E-04 -4.8336 0.14615E-04 -4.8352 0.99642E+00 -0.0016 25 C2H6,aq 0.34009E-14 -14.4684 0.33887E-14 -14.4700 0.99642E+00 -0.0016 29 CO,aq 0.12108E-16 -16.9169 0.12108E-16 -16.9169 0.10000E+01 0.0000 30 CO2,aq 0.43400E-10 -10.3625 0.43244E-10 -10.3641 0.99642E+00 -0.0016 31 CO3-2 0.67084E-06 -6.1734 0.34529E-06 -6.4618 0.51472E+00 -0.2884 32 CaCO3,aq 0.31042E-09 -9.5080 0.31042E-09 -9.5080 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.62660E-12 -12.2030 0.52346E-12 -12.2811 0.83540E+00 -0.0781 34 CaCl+ 0.19232E-10 -10.7160 0.16066E-10 -10.7941 0.83540E+00 -0.0781 35 CaCl2,aq 0.51381E-15 -15.2892 0.51381E-15 -15.2892 0.10000E+01 0.0000 36 CaOH+ 0.81755E-07 -7.0875 0.68298E-07 -7.1656 0.83540E+00 -0.0781 37 CaSO4,aq 0.11085E-16 -16.9553 0.11085E-16 -16.9553 0.10000E+01 0.0000 38 HCl,aq 0.19579E-14 -14.7082 0.19579E-14 -14.7082 0.10000E+01 0.0000 43 FeCl+ 0.81355E-17 -17.0896 0.67964E-17 -17.1677 0.83540E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16636E-10 -10.7790 0.13898E-10 -10.8571 0.83540E+00 -0.0781 48 HFeO2- 0.37236E-07 -7.4290 0.31046E-07 -7.5080 0.83377E+00 -0.0790 49 FeO+ 0.12279E-16 -16.9109 0.10257E-16 -16.9890 0.83540E+00 -0.0781 51 FeO2- 0.42101E-09 -9.3757 0.35102E-09 -9.4547 0.83377E+00 -0.0790 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.32816E-09 -9.4839 0.32816E-09 -9.4839 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.12084E-14 -14.9178 0.10076E-14 -14.9967 0.83377E+00 -0.0790 58 MgCO3,aq 0.12260E-13 -13.9115 0.12260E-13 -13.9115 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10099E-15 -15.9957 0.84364E-16 -16.0738 0.83540E+00 -0.0781 60 MgCl+ 0.27593E-14 -14.5592 0.23051E-14 -14.6373 0.83540E+00 -0.0781 61 MgOH+ 0.71584E-10 -10.1452 0.59801E-10 -10.2233 0.83540E+00 -0.0781 63 MnO,aq 0.18703E-08 -8.7281 0.18703E-08 -8.7281 0.10000E+01 0.0000 64 MnOH+ 0.49500E-09 -9.3054 0.41352E-09 -9.3835 0.83540E+00 -0.0781 65 MnO2-2 0.21881E-10 -10.6599 0.11262E-10 -10.9484 0.51472E+00 -0.2884 66 HMnO2- 0.22179E-09 -9.6541 0.18492E-09 -9.7330 0.83377E+00 -0.0790 69 MnCl+ 0.10126E-13 -13.9946 0.84590E-14 -14.0727 0.83540E+00 -0.0781 71 NaCl,aq 0.76791E-06 -6.1147 0.76791E-06 -6.1147 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95106E-02 -2.0218 0.79151E-02 -2.1015 0.83224E+00 -0.0798 79 HPO3-2 0.16769E-14 -14.7755 0.86314E-15 -15.0639 0.51472E+00 -0.2884 81 H2PO3- 0.15411E-18 -18.8122 0.12849E-18 -18.8911 0.83377E+00 -0.0790 82 H3PO4,aq 0.92945E-18 -18.0318 0.92945E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40019E-10 -10.3977 0.33399E-10 -10.4763 0.83457E+00 -0.0785 84 PO4-3 0.12110E-08 -8.9169 0.28968E-09 -9.5381 0.23920E+00 -0.6212 88 HP2O7-3 0.10372E-17 -17.9841 0.23622E-18 -18.6267 0.22775E+00 -0.6425 89 P2O7-4 0.10242E-16 -16.9896 0.76897E-18 -18.1141 0.75078E-01 -1.1245 90 H2S,aq 0.58288E-08 -8.2344 0.58079E-08 -8.2360 0.99642E+00 -0.0016 91 S2-2 0.25573E-14 -14.5922 0.13163E-14 -14.8807 0.51472E+00 -0.2884 97 SO3-2 0.13754E-17 -17.8616 0.71842E-18 -18.1436 0.52232E+00 -0.2821 99 HSO4- 0.40755E-19 -19.3898 0.34081E-19 -19.4675 0.83623E+00 -0.0777 Charge balance for all species = 0.3955E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9033491E-10 -.2311503E-01 -.2325637E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981177E+06 0.0000 3 Cl- 0.1647387E-03 0.1655070E-03 0.5857091E+01 6.2583 4 SO4-- 0.9395869E-12 -.1739547E-04 -.1668010E+01 7.9263 5 HCO3- 0.3389400E-06 0.1567812E-04 0.9549024E+00 3.5722 6 HS- 0.3058806E-04 0.4798936E-04 0.1584230E+01 5.5271 7 Al+++ 0.1103174E-28 0.5273991E-05 0.1420425E+00 0.7609 8 H4SiO4 0.7116276E-03 0.1419137E-01 0.1361538E+04 -3.1477 9 Ca++ 0.1433748E-06 0.2434963E-06 0.9741168E-02 13.1066 10 Mg++ 0.2276648E-10 0.9791373E-10 0.2376167E-05 9.3054 11 Fe++ 0.6227423E-13 0.3789537E-07 0.2112510E-02 6.7428 12 K+ 0.1615551E-03 0.1623316E-03 0.6335994E+01 6.2505 13 Na+ 0.2053935E-01 0.2313079E-01 0.5308092E+03 8.3540 14 Mn++ 0.1992955E-10 0.2628950E-08 0.1441677E-03 9.2484 15 HPO4-- 0.4872444E-07 0.4997547E-07 0.4787908E-02 12.6412 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2715594E+02 -.1926975E-01 -.2713667E+02 0.0000000E+00 2 H2O 0.3495019E+02 0.4627103E+02 -.1132084E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4547547E-01 -.1450166E-04 0.4548997E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4544996E-01 0.4000613E-04 -.4548997E-01 0.0000000E+00 7 Al+++ 0.5347613E+01 0.4396641E-05 0.5347609E+01 0.0000000E+00 8 H4SiO4 0.1707695E+02 0.1183057E-01 0.1706512E+02 0.0000000E+00 9 Ca++ 0.1886247E+01 0.2029896E-06 0.1886247E+01 0.0000000E+00 10 Mg++ 0.1301587E+01 0.8162537E-10 0.1301587E+01 0.0000000E+00 11 Fe++ 0.1169333E+01 0.3159132E-07 0.1169333E+01 0.0000000E+00 12 K+ 0.3481951E+00 0.1353271E-03 0.3480598E+00 0.0000000E+00 13 Na+ 0.2058758E+01 0.1928289E-01 0.2039475E+01 0.0000000E+00 14 Mn++ 0.2843528E-01 0.2191613E-08 0.2843528E-01 0.0000000E+00 15 HPO4-- 0.9704820E-02 0.4166184E-07 0.9704778E-02 0.0000000E+00 Chg. balance for solid moles: -.1589E-14 Mass of aqueous solution: 0.835158E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1639.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.038 0.309 534.4 2.728 29.83 205.1 andradite 0.1820 -0.740 92.47 1.966 5.161 24.02 grossular 0.4345E-01 -1.362 19.57 1.292 1.092 5.446 apatite-OH 0.3235E-02 -2.490 1.625 0.211 0.9070E-01 0.5164 clinochlore 0.2346 -0.630 130.4 2.115 7.278 49.60 daphnite 0.6723E-01 -1.172 47.97 1.681 2.678 14.54 chlorite-Mn 0.5687E-02 -2.245 4.032 0.606 0.2251 1.285 diopside 0.8537E-01 -1.069 18.49 1.267 1.032 5.650 hedenbergite 0.2187E-01 -1.660 5.426 0.734 0.3029 1.486 microcline 0.3048 -0.516 84.84 1.929 4.736 33.14 stilbite 1.063 0.026 748.9 2.874 41.80 349.3 stilpnomelane-Fe 0.8649E-01 -1.063 93.24 1.970 5.204 32.21 tr.625ac.25prg.125 0.1194E-01 -1.923 10.21 1.009 0.5696 3.285 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1849E-01 0.1849E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1791.576435 g Volume = 725.626684 cm3 Porosity: -10.4455% V(tot) - V(min): -.68627E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1639.9990000 g log = 3.2148 Original solution: 1000.0103000 g Original solution / Rock added: 0.61 (Water/Rock Ratio), log = -0.2148 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0902 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9654E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4508E-08 1.0071 0.4950E-08 0.4915E-08 CH4,gas 0.2093E-01 1.0128 0.2311E-01 0.2282E-01 H2,gas 0.1367E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1560E-06 0.9958 0.1694E-06 0.1701E-06 S2,gas 0.4434E-29 1.0000 0.4834E-29 0.4834E-29 CO,gas 0.1754E-13 1.0000 0.1912E-13 0.1912E-13 SO3,gas 0.9545E-48 1.0000 0.1041E-47 0.1041E-47 SO2,gas 0.5384E-27 1.0000 0.5870E-27 0.5870E-27 HCl,gas 0.3171E-17 1.0000 0.3457E-17 0.3457E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.67 -10.31 -3.435 0.17596E+05 -8.305 3 CH4,gas 4.81 1.17 -3.64 -0.909 0.62086E+04 -1.636 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.71 -8.77 -4.386 0.14976E+05 -6.771 6 S2,gas -7.03 -38.35 -31.32 -4.818 0.53471E+05 -29.316 7 CO,gas 3.51 -12.21 -15.72 -4.836 0.26839E+05 -13.719 8 SO3,gas 17.43 -32.56 -49.98 -12.496 0.85344E+05 -47.983 9 SO2,gas 1.14 -28.09 -29.23 -7.795 0.49912E+05 -27.231 10 HCl,gas 5.48 -13.98 -19.46 -9.731 0.33230E+05 -17.461 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80697E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94125E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.56 -4.55 -1.516 0.77660E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.56 -4.40 -1.465 0.75047E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65580E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.75 -4.64 -1.326 0.79235E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66054E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.75 -4.20 -1.200 0.71697E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82292E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61284E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53669E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92772E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40696E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43445E+04 143 pyrrhotite -4.24 -7.97 -3.73 -1.242 0.63643E+04 144 pyrrhotiteFe0.875 -6.00 -9.37 -3.37 -1.238 0.57471E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22460E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28301E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23252E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47192E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91030E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.97 -3.58 -1.192 0.61075E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80424E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66780E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60333E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.47 -4.50 -1.501 0.76887E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1639.9990000 g New total amount of reactant added: 1679.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1679.9990000 Water: Moles liquid = 0.4605E+02 kg liquid = 0.8296E+00 Moles total = 0.3445E+02 kg total = 0.6206E+00 Activity = 1.0000 Stoichiometric ionic strength = .1175224E-01 Osmotic coef. = 0.9687 True ionic strength = .2070268E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90337E-10 -10.0441 0.75786E-10 -10.1204 0.83892E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16554E-03 -3.7811 0.13802E-03 -3.8601 0.83377E+00 -0.0790 4 SO4-- 0.94413E-12 -12.0250 0.48702E-12 -12.3125 0.51583E+00 -0.2875 5 HCO3- 0.34058E-06 -6.4678 0.28439E-06 -6.5461 0.83501E+00 -0.0783 6 HS- 0.30736E-04 -4.5123 0.25631E-04 -4.5912 0.83389E+00 -0.0789 7 Al+++ 0.11033E-28 -28.9573 0.25100E-29 -29.6003 0.22750E+00 -0.6430 8 H4SiO4 0.71163E-03 -3.1477 0.71163E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14338E-06 -6.8435 0.73406E-07 -7.1343 0.51196E+00 -0.2908 10 Mg++ 0.22768E-10 -10.6427 0.11602E-10 -10.9355 0.50957E+00 -0.2928 11 Fe++ 0.62278E-13 -13.2057 0.31770E-13 -13.4980 0.51014E+00 -0.2923 12 K+ 0.16156E-03 -3.7917 0.13494E-03 -3.8699 0.83521E+00 -0.0782 13 Na+ 0.20540E-01 -1.6874 0.17122E-01 -1.7664 0.83361E+00 -0.0790 14 Mn++ 0.19933E-10 -10.7004 0.10177E-10 -10.9924 0.51057E+00 -0.2919 15 HPO4-- 0.48723E-07 -7.3123 0.25136E-07 -7.5997 0.51591E+00 -0.2874 16 HSiO3- 0.10988E-01 -1.9591 0.91615E-02 -2.0380 0.83377E+00 -0.0790 17 Ca(HSiO3)+ 0.18037E-07 -7.7438 0.15068E-07 -7.8219 0.83539E+00 -0.0781 18 Mg(HSiO3)+ 0.35477E-11 -11.4500 0.29638E-11 -11.5282 0.83539E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67532E-16 -16.1705 0.56416E-16 -16.2486 0.83539E+00 -0.0781 22 HAlO2,aq 0.14897E-09 -9.8269 0.14897E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52737E-05 -5.2779 0.43890E-05 -5.3576 0.83224E+00 -0.0798 24 CH4,aq 0.14739E-04 -4.8315 0.14686E-04 -4.8331 0.99642E+00 -0.0016 25 C2H6,aq 0.34339E-14 -14.4642 0.34216E-14 -14.4658 0.99642E+00 -0.0016 29 CO,aq 0.12167E-16 -16.9148 0.12167E-16 -16.9148 0.10000E+01 0.0000 30 CO2,aq 0.43610E-10 -10.3604 0.43454E-10 -10.3620 0.99642E+00 -0.0016 31 CO3-2 0.67407E-06 -6.1713 0.34696E-06 -6.4597 0.51472E+00 -0.2884 32 CaCO3,aq 0.31193E-09 -9.5059 0.31193E-09 -9.5059 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.62966E-12 -12.2009 0.52601E-12 -12.2790 0.83539E+00 -0.0781 34 CaCl+ 0.19326E-10 -10.7139 0.16144E-10 -10.7920 0.83539E+00 -0.0781 35 CaCl2,aq 0.51882E-15 -15.2850 0.51882E-15 -15.2850 0.10000E+01 0.0000 36 CaOH+ 0.81757E-07 -7.0875 0.68299E-07 -7.1656 0.83539E+00 -0.0781 37 CaSO4,aq 0.11139E-16 -16.9532 0.11139E-16 -16.9532 0.10000E+01 0.0000 38 HCl,aq 0.19675E-14 -14.7061 0.19675E-14 -14.7061 0.10000E+01 0.0000 43 FeCl+ 0.81753E-17 -17.0875 0.68296E-17 -17.1656 0.83539E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16636E-10 -10.7789 0.13898E-10 -10.8570 0.83539E+00 -0.0781 48 HFeO2- 0.37235E-07 -7.4291 0.31045E-07 -7.5080 0.83377E+00 -0.0790 49 FeO+ 0.12279E-16 -16.9108 0.10258E-16 -16.9890 0.83539E+00 -0.0781 51 FeO2- 0.42100E-09 -9.3757 0.35101E-09 -9.4547 0.83377E+00 -0.0790 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.32976E-09 -9.4818 0.32976E-09 -9.4818 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.12143E-14 -14.9157 0.10124E-14 -14.9946 0.83377E+00 -0.0790 58 MgCO3,aq 0.12319E-13 -13.9094 0.12319E-13 -13.9094 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10148E-15 -15.9936 0.84776E-16 -16.0717 0.83539E+00 -0.0781 60 MgCl+ 0.27728E-14 -14.5571 0.23164E-14 -14.6352 0.83539E+00 -0.0781 61 MgOH+ 0.71586E-10 -10.1452 0.59803E-10 -10.2233 0.83539E+00 -0.0781 63 MnO,aq 0.18706E-08 -8.7280 0.18706E-08 -8.7280 0.10000E+01 0.0000 64 MnOH+ 0.49508E-09 -9.3053 0.41359E-09 -9.3834 0.83539E+00 -0.0781 65 MnO2-2 0.21883E-10 -10.6599 0.11263E-10 -10.9483 0.51472E+00 -0.2884 66 HMnO2- 0.22182E-09 -9.6540 0.18494E-09 -9.7330 0.83377E+00 -0.0790 69 MnCl+ 0.10177E-13 -13.9924 0.85015E-14 -14.0705 0.83539E+00 -0.0781 71 NaCl,aq 0.77164E-06 -6.1126 0.77164E-06 -6.1126 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95103E-02 -2.0218 0.79149E-02 -2.1016 0.83224E+00 -0.0798 79 HPO3-2 0.16768E-14 -14.7755 0.86310E-15 -15.0639 0.51472E+00 -0.2884 81 H2PO3- 0.15411E-18 -18.8122 0.12849E-18 -18.8911 0.83377E+00 -0.0790 82 H3PO4,aq 0.92945E-18 -18.0318 0.92945E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40018E-10 -10.3977 0.33398E-10 -10.4763 0.83457E+00 -0.0785 84 PO4-3 0.12109E-08 -8.9169 0.28966E-09 -9.5381 0.23920E+00 -0.6212 88 HP2O7-3 0.10372E-17 -17.9842 0.23621E-18 -18.6267 0.22774E+00 -0.6426 89 P2O7-4 0.10242E-16 -16.9896 0.76890E-18 -18.1141 0.75076E-01 -1.1245 90 H2S,aq 0.58572E-08 -8.2323 0.58362E-08 -8.2339 0.99642E+00 -0.0016 91 S2-2 0.25821E-14 -14.5880 0.13291E-14 -14.8765 0.51472E+00 -0.2884 97 SO3-2 0.13821E-17 -17.8595 0.72189E-18 -18.1415 0.52232E+00 -0.2821 99 HSO4- 0.40953E-19 -19.3877 0.34246E-19 -19.4654 0.83623E+00 -0.0777 Charge balance for all species = 0.3974E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9033719E-10 -.2311461E-01 -.2325594E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981177E+06 0.0000 3 Cl- 0.1655367E-03 0.1663087E-03 0.5885462E+01 6.2604 4 SO4-- 0.9441348E-12 -.1746653E-04 -.1674824E+01 7.9284 5 HCO3- 0.3405798E-06 0.1575407E-04 0.9595279E+00 3.5743 6 HS- 0.3073623E-04 0.4820862E-04 0.1591468E+01 5.5292 7 Al+++ 0.1103264E-28 0.5273851E-05 0.1420387E+00 0.7609 8 H4SiO4 0.7116287E-03 0.1419115E-01 0.1361518E+04 -3.1477 9 Ca++ 0.1433824E-06 0.2435078E-06 0.9741628E-02 13.1066 10 Mg++ 0.2276767E-10 0.9791643E-10 0.2376233E-05 9.3053 11 Fe++ 0.6227756E-13 0.3789453E-07 0.2112463E-02 6.7428 12 K+ 0.1615592E-03 0.1623357E-03 0.6336153E+01 6.2505 13 Na+ 0.2053987E-01 0.2313132E-01 0.5308213E+03 8.3540 14 Mn++ 0.1993331E-10 0.2629312E-08 0.1441875E-03 9.2485 15 HPO4-- 0.4872260E-07 0.4997357E-07 0.4787726E-02 12.6411 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2781828E+02 -.1917651E-01 -.2779910E+02 0.0000000E+00 2 H2O 0.3444877E+02 0.4604797E+02 -.1159920E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4658400E-01 -.1449071E-04 0.4659849E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4655850E-01 0.3999518E-04 -.4659849E-01 0.0000000E+00 7 Al+++ 0.5478043E+01 0.4375330E-05 0.5478038E+01 0.0000000E+00 8 H4SiO4 0.1749346E+02 0.1177336E-01 0.1748169E+02 0.0000000E+00 9 Ca++ 0.1932253E+01 0.2020206E-06 0.1932253E+01 0.0000000E+00 10 Mg++ 0.1333333E+01 0.8123413E-10 0.1333333E+01 0.0000000E+00 11 Fe++ 0.1197854E+01 0.3143833E-07 0.1197854E+01 0.0000000E+00 12 K+ 0.3566877E+00 0.1346781E-03 0.3565530E+00 0.0000000E+00 13 Na+ 0.2108968E+01 0.1919037E-01 0.2089778E+01 0.0000000E+00 14 Mn++ 0.2912882E-01 0.2181349E-08 0.2912882E-01 0.0000000E+00 15 HPO4-- 0.9941523E-02 0.4145943E-07 0.9941481E-02 0.0000000E+00 Chg. balance for solid moles: 0.1624E-14 Mass of aqueous solution: 0.831132E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1679.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.088 0.320 547.6 2.738 29.84 210.2 andradite 0.1864 -0.730 94.72 1.976 5.161 24.61 grossular 0.4451E-01 -1.352 20.05 1.302 1.092 5.579 apatite-OH 0.3314E-02 -2.480 1.665 0.221 0.9070E-01 0.5289 clinochlore 0.2403 -0.619 133.6 2.126 7.277 50.80 daphnite 0.6886E-01 -1.162 49.13 1.691 2.677 14.89 chlorite-Mn 0.5826E-02 -2.235 4.130 0.616 0.2250 1.316 diopside 0.8768E-01 -1.057 18.99 1.278 1.035 5.803 hedenbergite 0.2246E-01 -1.649 5.573 0.746 0.3037 1.526 microcline 0.3122 -0.505 86.91 1.939 4.736 33.95 stilbite 1.088 0.037 767.0 2.885 41.79 357.8 stilpnomelane-Fe 0.8861E-01 -1.053 95.52 1.980 5.204 32.99 tr.625ac.25prg.125 0.1221E-01 -1.913 10.44 1.019 0.5688 3.360 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1850E-01 0.1850E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1835.278627 g Volume = 743.309226 cm3 Porosity: -10.4472% V(tot) - V(min): -.70310E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1679.9990000 g log = 3.2253 Original solution: 1000.0103000 g Original solution / Rock added: 0.60 (Water/Rock Ratio), log = -0.2253 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0903 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9653E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4530E-08 1.0071 0.4974E-08 0.4939E-08 CH4,gas 0.2103E-01 1.0128 0.2322E-01 0.2293E-01 H2,gas 0.1367E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1568E-06 0.9958 0.1702E-06 0.1709E-06 S2,gas 0.4477E-29 1.0000 0.4881E-29 0.4881E-29 CO,gas 0.1762E-13 1.0000 0.1921E-13 0.1921E-13 SO3,gas 0.9591E-48 1.0000 0.1046E-47 0.1046E-47 SO2,gas 0.5410E-27 1.0000 0.5899E-27 0.5899E-27 HCl,gas 0.3186E-17 1.0000 0.3474E-17 0.3474E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.67 -10.30 -3.434 0.17593E+05 -8.303 3 CH4,gas 4.81 1.18 -3.63 -0.909 0.62050E+04 -1.634 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.71 -8.77 -4.384 0.14973E+05 -6.769 6 S2,gas -7.03 -38.34 -31.31 -4.817 0.53463E+05 -29.311 7 CO,gas 3.51 -12.21 -15.72 -4.836 0.26835E+05 -13.716 8 SO3,gas 17.43 -32.55 -49.98 -12.495 0.85340E+05 -47.981 9 SO2,gas 1.14 -28.09 -29.23 -7.794 0.49908E+05 -27.229 10 HCl,gas 5.48 -13.98 -19.46 -9.730 0.33226E+05 -17.459 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80694E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94125E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.56 -4.55 -1.515 0.77625E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.56 -4.39 -1.464 0.75011E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65579E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.75 -4.64 -1.325 0.79199E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66055E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.75 -4.20 -1.199 0.71661E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82291E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61284E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53669E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92772E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40696E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43445E+04 143 pyrrhotite -4.24 -7.97 -3.73 -1.242 0.63607E+04 144 pyrrhotiteFe0.875 -6.00 -9.36 -3.36 -1.237 0.57435E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22459E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28301E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23251E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47190E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91030E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.97 -3.57 -1.192 0.61039E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80424E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66780E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60332E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.46 -4.50 -1.500 0.76850E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1679.9990000 g New total amount of reactant added: 1719.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1719.9990000 Water: Moles liquid = 0.4583E+02 kg liquid = 0.8256E+00 Moles total = 0.3395E+02 kg total = 0.6116E+00 Activity = 1.0000 Stoichiometric ionic strength = .1175292E-01 Osmotic coef. = 0.9687 True ionic strength = .2070321E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90339E-10 -10.0441 0.75788E-10 -10.1204 0.83892E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16634E-03 -3.7790 0.13869E-03 -3.8580 0.83377E+00 -0.0790 4 SO4-- 0.94873E-12 -12.0229 0.48938E-12 -12.3104 0.51583E+00 -0.2875 5 HCO3- 0.34224E-06 -6.4657 0.28577E-06 -6.5440 0.83501E+00 -0.0783 6 HS- 0.30886E-04 -4.5102 0.25755E-04 -4.5891 0.83389E+00 -0.0789 7 Al+++ 0.11034E-28 -28.9573 0.25101E-29 -29.6003 0.22750E+00 -0.6430 8 H4SiO4 0.71163E-03 -3.1477 0.71163E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14339E-06 -6.8435 0.73410E-07 -7.1342 0.51196E+00 -0.2908 10 Mg++ 0.22769E-10 -10.6427 0.11602E-10 -10.9355 0.50957E+00 -0.2928 11 Fe++ 0.62281E-13 -13.2056 0.31772E-13 -13.4980 0.51014E+00 -0.2923 12 K+ 0.16156E-03 -3.7917 0.13494E-03 -3.8699 0.83521E+00 -0.0782 13 Na+ 0.20540E-01 -1.6874 0.17123E-01 -1.7664 0.83361E+00 -0.0790 14 Mn++ 0.19937E-10 -10.7003 0.10179E-10 -10.9923 0.51057E+00 -0.2919 15 HPO4-- 0.48721E-07 -7.3123 0.25135E-07 -7.5997 0.51591E+00 -0.2874 16 HSiO3- 0.10988E-01 -1.9591 0.91613E-02 -2.0380 0.83377E+00 -0.0790 17 Ca(HSiO3)+ 0.18037E-07 -7.7438 0.15068E-07 -7.8219 0.83539E+00 -0.0781 18 Mg(HSiO3)+ 0.35478E-11 -11.4500 0.29638E-11 -11.5281 0.83539E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67534E-16 -16.1705 0.56417E-16 -16.2486 0.83539E+00 -0.0781 22 HAlO2,aq 0.14896E-09 -9.8269 0.14896E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52736E-05 -5.2779 0.43889E-05 -5.3576 0.83224E+00 -0.0798 24 CH4,aq 0.14811E-04 -4.8294 0.14758E-04 -4.8310 0.99642E+00 -0.0016 25 C2H6,aq 0.34674E-14 -14.4600 0.34550E-14 -14.4615 0.99642E+00 -0.0016 29 CO,aq 0.12226E-16 -16.9127 0.12226E-16 -16.9127 0.10000E+01 0.0000 30 CO2,aq 0.43823E-10 -10.3583 0.43666E-10 -10.3599 0.99642E+00 -0.0016 31 CO3-2 0.67734E-06 -6.1692 0.34863E-06 -6.4576 0.51471E+00 -0.2884 32 CaCO3,aq 0.31345E-09 -9.5038 0.31345E-09 -9.5038 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.63275E-12 -12.1988 0.52859E-12 -12.2769 0.83539E+00 -0.0781 34 CaCl+ 0.19421E-10 -10.7117 0.16224E-10 -10.7898 0.83539E+00 -0.0781 35 CaCl2,aq 0.52390E-15 -15.2808 0.52390E-15 -15.2808 0.10000E+01 0.0000 36 CaOH+ 0.81759E-07 -7.0875 0.68301E-07 -7.1656 0.83539E+00 -0.0781 37 CaSO4,aq 0.11194E-16 -16.9510 0.11194E-16 -16.9510 0.10000E+01 0.0000 38 HCl,aq 0.19771E-14 -14.7040 0.19771E-14 -14.7040 0.10000E+01 0.0000 43 FeCl+ 0.82155E-17 -17.0854 0.68631E-17 -17.1635 0.83539E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16637E-10 -10.7789 0.13898E-10 -10.8570 0.83539E+00 -0.0781 48 HFeO2- 0.37234E-07 -7.4291 0.31044E-07 -7.5080 0.83377E+00 -0.0790 49 FeO+ 0.12279E-16 -16.9108 0.10258E-16 -16.9889 0.83539E+00 -0.0781 51 FeO2- 0.42099E-09 -9.3757 0.35101E-09 -9.4547 0.83377E+00 -0.0790 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.33137E-09 -9.4797 0.33137E-09 -9.4797 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.12202E-14 -14.9136 0.10174E-14 -14.9925 0.83377E+00 -0.0790 58 MgCO3,aq 0.12379E-13 -13.9073 0.12379E-13 -13.9073 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10198E-15 -15.9915 0.85192E-16 -16.0696 0.83539E+00 -0.0781 60 MgCl+ 0.27865E-14 -14.5549 0.23278E-14 -14.6331 0.83539E+00 -0.0781 61 MgOH+ 0.71588E-10 -10.1452 0.59804E-10 -10.2233 0.83539E+00 -0.0781 63 MnO,aq 0.18708E-08 -8.7280 0.18708E-08 -8.7280 0.10000E+01 0.0000 64 MnOH+ 0.49516E-09 -9.3053 0.41365E-09 -9.3834 0.83539E+00 -0.0781 65 MnO2-2 0.21885E-10 -10.6599 0.11264E-10 -10.9483 0.51471E+00 -0.2884 66 HMnO2- 0.22184E-09 -9.6540 0.18496E-09 -9.7329 0.83377E+00 -0.0790 69 MnCl+ 0.10228E-13 -13.9902 0.85444E-14 -14.0683 0.83539E+00 -0.0781 71 NaCl,aq 0.77542E-06 -6.1105 0.77542E-06 -6.1105 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95101E-02 -2.0218 0.79147E-02 -2.1016 0.83224E+00 -0.0798 79 HPO3-2 0.16768E-14 -14.7755 0.86306E-15 -15.0640 0.51471E+00 -0.2884 81 H2PO3- 0.15410E-18 -18.8122 0.12849E-18 -18.8911 0.83377E+00 -0.0790 82 H3PO4,aq 0.92946E-18 -18.0318 0.92946E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40018E-10 -10.3977 0.33398E-10 -10.4763 0.83457E+00 -0.0785 84 PO4-3 0.12109E-08 -8.9169 0.28964E-09 -9.5381 0.23920E+00 -0.6212 88 HP2O7-3 0.10371E-17 -17.9842 0.23619E-18 -18.6267 0.22774E+00 -0.6426 89 P2O7-4 0.10241E-16 -16.9897 0.76884E-18 -18.1142 0.75074E-01 -1.1245 90 H2S,aq 0.58858E-08 -8.2302 0.58647E-08 -8.2318 0.99642E+00 -0.0016 91 S2-2 0.26074E-14 -14.5838 0.13420E-14 -14.8722 0.51471E+00 -0.2884 97 SO3-2 0.13888E-17 -17.8574 0.72539E-18 -18.1394 0.52232E+00 -0.2821 99 HSO4- 0.41153E-19 -19.3856 0.34413E-19 -19.4633 0.83622E+00 -0.0777 Charge balance for all species = 0.3994E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9033948E-10 -.2311418E-01 -.2325551E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981176E+06 0.0000 3 Cl- 0.1663424E-03 0.1671182E-03 0.5914110E+01 6.2624 4 SO4-- 0.9487261E-12 -.1753829E-04 -.1681704E+01 7.9305 5 HCO3- 0.3422353E-06 0.1583075E-04 0.9641984E+00 3.5764 6 HS- 0.3088584E-04 0.4843001E-04 0.1598776E+01 5.5313 7 Al+++ 0.1103355E-28 0.5273710E-05 0.1420349E+00 0.7609 8 H4SiO4 0.7116298E-03 0.1419093E-01 0.1361496E+04 -3.1477 9 Ca++ 0.1433899E-06 0.2435194E-06 0.9742093E-02 13.1066 10 Mg++ 0.2276887E-10 0.9791970E-10 0.2376312E-05 9.3053 11 Fe++ 0.6228092E-13 0.3789367E-07 0.2112415E-02 6.7428 12 K+ 0.1615633E-03 0.1623398E-03 0.6336314E+01 6.2505 13 Na+ 0.2054039E-01 0.2313185E-01 0.5308334E+03 8.3540 14 Mn++ 0.1993696E-10 0.2629658E-08 0.1442065E-03 9.2485 15 HPO4-- 0.4872074E-07 0.4997164E-07 0.4787541E-02 12.6411 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2848062E+02 -.1908326E-01 -.2846153E+02 0.0000000E+00 2 H2O 0.3394736E+02 0.4582492E+02 -.1187756E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4769254E-01 -.1447976E-04 0.4770702E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4766704E-01 0.3998423E-04 -.4770702E-01 0.0000000E+00 7 Al+++ 0.5608472E+01 0.4354020E-05 0.5608468E+01 0.0000000E+00 8 H4SiO4 0.1790998E+02 0.1171615E-01 0.1789826E+02 0.0000000E+00 9 Ca++ 0.1978259E+01 0.2010517E-06 0.1978258E+01 0.0000000E+00 10 Mg++ 0.1365079E+01 0.8084333E-10 0.1365079E+01 0.0000000E+00 11 Fe++ 0.1226374E+01 0.3128534E-07 0.1226374E+01 0.0000000E+00 12 K+ 0.3651803E+00 0.1340291E-03 0.3650462E+00 0.0000000E+00 13 Na+ 0.2159178E+01 0.1909785E-01 0.2140080E+01 0.0000000E+00 14 Mn++ 0.2982237E-01 0.2171068E-08 0.2982237E-01 0.0000000E+00 15 HPO4-- 0.1017823E-01 0.4125701E-07 0.1017818E-01 0.0000000E+00 Chg. balance for solid moles: 0.1457E-15 Mass of aqueous solution: 0.827107E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1719.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.139 0.330 560.8 2.749 29.84 215.3 andradite 0.1908 -0.719 96.98 1.987 5.161 25.19 grossular 0.4557E-01 -1.341 20.53 1.312 1.092 5.711 apatite-OH 0.3393E-02 -2.469 1.704 0.232 0.9070E-01 0.5415 clinochlore 0.2460 -0.609 136.7 2.136 7.276 52.00 daphnite 0.7049E-01 -1.152 50.30 1.702 2.677 15.24 chlorite-Mn 0.5964E-02 -2.224 4.229 0.626 0.2250 1.348 diopside 0.9000E-01 -1.046 19.49 1.290 1.037 5.957 hedenbergite 0.2306E-01 -1.637 5.720 0.757 0.3044 1.567 microcline 0.3197 -0.495 88.98 1.949 4.736 34.76 stilbite 1.114 0.047 785.1 2.895 41.78 366.2 stilpnomelane-Fe 0.9072E-01 -1.042 97.79 1.990 5.205 33.78 tr.625ac.25prg.125 0.1248E-01 -1.904 10.67 1.028 0.5679 3.435 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1850E-01 0.1850E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1878.980819 g Volume = 760.991769 cm3 Porosity: -10.4488% V(tot) - V(min): -.71992E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1719.9990000 g log = 3.2355 Original solution: 1000.0103000 g Original solution / Rock added: 0.58 (Water/Rock Ratio), log = -0.2355 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0904 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9652E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4552E-08 1.0071 0.4998E-08 0.4963E-08 CH4,gas 0.2113E-01 1.0128 0.2334E-01 0.2304E-01 H2,gas 0.1367E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1575E-06 0.9958 0.1710E-06 0.1718E-06 S2,gas 0.4520E-29 1.0000 0.4929E-29 0.4929E-29 CO,gas 0.1770E-13 1.0000 0.1931E-13 0.1931E-13 SO3,gas 0.9637E-48 1.0000 0.1051E-47 0.1051E-47 SO2,gas 0.5436E-27 1.0000 0.5927E-27 0.5927E-27 HCl,gas 0.3201E-17 1.0000 0.3491E-17 0.3491E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.18957E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.66 -10.30 -3.434 0.17589E+05 -8.301 3 CH4,gas 4.81 1.18 -3.63 -0.908 0.62014E+04 -1.632 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.71 -8.77 -4.383 0.14969E+05 -6.767 6 S2,gas -7.03 -38.34 -31.31 -4.816 0.53456E+05 -29.307 7 CO,gas 3.51 -12.20 -15.71 -4.835 0.26832E+05 -13.714 8 SO3,gas 17.43 -32.55 -49.98 -12.495 0.85337E+05 -47.978 9 SO2,gas 1.14 -28.09 -29.23 -7.794 0.49905E+05 -27.227 10 HCl,gas 5.48 -13.98 -19.46 -9.729 0.33222E+05 -17.457 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80691E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94125E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.56 -4.54 -1.515 0.77588E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.56 -4.39 -1.464 0.74975E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65578E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.74 -4.64 -1.325 0.79163E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66055E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.74 -4.19 -1.199 0.71625E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82290E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61284E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53669E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92772E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40697E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43445E+04 143 pyrrhotite -4.24 -7.97 -3.72 -1.241 0.63571E+04 144 pyrrhotiteFe0.875 -6.00 -9.36 -3.36 -1.236 0.57399E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22458E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28301E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23250E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47188E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91030E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.97 -3.57 -1.191 0.61003E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80424E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66780E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60332E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.46 -4.50 -1.500 0.76813E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1719.9990000 g New total amount of reactant added: 1759.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1759.9990000 Water: Moles liquid = 0.4561E+02 kg liquid = 0.8216E+00 Moles total = 0.3345E+02 kg total = 0.6025E+00 Activity = 1.0000 Stoichiometric ionic strength = .1175360E-01 Osmotic coef. = 0.9687 True ionic strength = .2070375E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90342E-10 -10.0441 0.75789E-10 -10.1204 0.83892E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16716E-03 -3.7769 0.13937E-03 -3.8558 0.83376E+00 -0.0790 4 SO4-- 0.95336E-12 -12.0207 0.49177E-12 -12.3082 0.51583E+00 -0.2875 5 HCO3- 0.34391E-06 -6.4636 0.28716E-06 -6.5419 0.83501E+00 -0.0783 6 HS- 0.31037E-04 -4.5081 0.25881E-04 -4.5870 0.83389E+00 -0.0789 7 Al+++ 0.11034E-28 -28.9572 0.25103E-29 -29.6003 0.22750E+00 -0.6430 8 H4SiO4 0.71163E-03 -3.1477 0.71163E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14340E-06 -6.8435 0.73413E-07 -7.1342 0.51196E+00 -0.2908 10 Mg++ 0.22770E-10 -10.6426 0.11603E-10 -10.9354 0.50957E+00 -0.2928 11 Fe++ 0.62284E-13 -13.2056 0.31773E-13 -13.4979 0.51014E+00 -0.2923 12 K+ 0.16157E-03 -3.7916 0.13494E-03 -3.8699 0.83521E+00 -0.0782 13 Na+ 0.20541E-01 -1.6874 0.17123E-01 -1.7664 0.83361E+00 -0.0790 14 Mn++ 0.19941E-10 -10.7003 0.10181E-10 -10.9922 0.51057E+00 -0.2919 15 HPO4-- 0.48719E-07 -7.3123 0.25134E-07 -7.5997 0.51590E+00 -0.2874 16 HSiO3- 0.10988E-01 -1.9591 0.91611E-02 -2.0381 0.83376E+00 -0.0790 17 Ca(HSiO3)+ 0.18038E-07 -7.7438 0.15069E-07 -7.8219 0.83539E+00 -0.0781 18 Mg(HSiO3)+ 0.35479E-11 -11.4500 0.29639E-11 -11.5281 0.83539E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67535E-16 -16.1705 0.56418E-16 -16.2486 0.83539E+00 -0.0781 22 HAlO2,aq 0.14896E-09 -9.8269 0.14896E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52734E-05 -5.2779 0.43887E-05 -5.3577 0.83224E+00 -0.0798 24 CH4,aq 0.14883E-04 -4.8273 0.14830E-04 -4.8289 0.99642E+00 -0.0016 25 C2H6,aq 0.35015E-14 -14.4557 0.34889E-14 -14.4573 0.99642E+00 -0.0016 29 CO,aq 0.12286E-16 -16.9106 0.12286E-16 -16.9106 0.10000E+01 0.0000 30 CO2,aq 0.44038E-10 -10.3562 0.43881E-10 -10.3577 0.99642E+00 -0.0016 31 CO3-2 0.68063E-06 -6.1671 0.35033E-06 -6.4555 0.51471E+00 -0.2884 32 CaCO3,aq 0.31499E-09 -9.5017 0.31499E-09 -9.5017 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.63587E-12 -12.1966 0.53120E-12 -12.2747 0.83539E+00 -0.0781 34 CaCl+ 0.19516E-10 -10.7096 0.16304E-10 -10.7877 0.83539E+00 -0.0781 35 CaCl2,aq 0.52906E-15 -15.2765 0.52906E-15 -15.2765 0.10000E+01 0.0000 36 CaOH+ 0.81761E-07 -7.0875 0.68302E-07 -7.1656 0.83539E+00 -0.0781 37 CaSO4,aq 0.11249E-16 -16.9489 0.11249E-16 -16.9489 0.10000E+01 0.0000 38 HCl,aq 0.19868E-14 -14.7018 0.19868E-14 -14.7018 0.10000E+01 0.0000 43 FeCl+ 0.82560E-17 -17.0832 0.68970E-17 -17.1613 0.83539E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16637E-10 -10.7789 0.13899E-10 -10.8570 0.83539E+00 -0.0781 48 HFeO2- 0.37233E-07 -7.4291 0.31044E-07 -7.5080 0.83376E+00 -0.0790 49 FeO+ 0.12279E-16 -16.9108 0.10258E-16 -16.9889 0.83539E+00 -0.0781 51 FeO2- 0.42098E-09 -9.3757 0.35100E-09 -9.4547 0.83376E+00 -0.0790 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.33300E-09 -9.4776 0.33300E-09 -9.4776 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.12262E-14 -14.9114 0.10224E-14 -14.9904 0.83376E+00 -0.0790 58 MgCO3,aq 0.12440E-13 -13.9052 0.12440E-13 -13.9052 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10248E-15 -15.9894 0.85612E-16 -16.0675 0.83539E+00 -0.0781 60 MgCl+ 0.28002E-14 -14.5528 0.23393E-14 -14.6309 0.83539E+00 -0.0781 61 MgOH+ 0.71590E-10 -10.1452 0.59805E-10 -10.2233 0.83539E+00 -0.0781 63 MnO,aq 0.18711E-08 -8.7279 0.18711E-08 -8.7279 0.10000E+01 0.0000 64 MnOH+ 0.49523E-09 -9.3052 0.41371E-09 -9.3833 0.83539E+00 -0.0781 65 MnO2-2 0.21886E-10 -10.6598 0.11265E-10 -10.9483 0.51471E+00 -0.2884 66 HMnO2- 0.22186E-09 -9.6539 0.18498E-09 -9.7329 0.83376E+00 -0.0790 69 MnCl+ 0.10280E-13 -13.9880 0.85876E-14 -14.0661 0.83539E+00 -0.0781 71 NaCl,aq 0.77923E-06 -6.1083 0.77923E-06 -6.1083 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95099E-02 -2.0218 0.79145E-02 -2.1016 0.83224E+00 -0.0798 79 HPO3-2 0.16767E-14 -14.7755 0.86302E-15 -15.0640 0.51471E+00 -0.2884 81 H2PO3- 0.15410E-18 -18.8122 0.12848E-18 -18.8912 0.83376E+00 -0.0790 82 H3PO4,aq 0.92946E-18 -18.0318 0.92946E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40017E-10 -10.3978 0.33397E-10 -10.4763 0.83457E+00 -0.0785 84 PO4-3 0.12108E-08 -8.9169 0.28962E-09 -9.5382 0.23919E+00 -0.6213 88 HP2O7-3 0.10371E-17 -17.9842 0.23618E-18 -18.6268 0.22774E+00 -0.6426 89 P2O7-4 0.10240E-16 -16.9897 0.76877E-18 -18.1142 0.75072E-01 -1.1245 90 H2S,aq 0.59147E-08 -8.2281 0.58935E-08 -8.2296 0.99642E+00 -0.0016 91 S2-2 0.26329E-14 -14.5796 0.13552E-14 -14.8680 0.51471E+00 -0.2884 97 SO3-2 0.13956E-17 -17.8552 0.72893E-18 -18.1373 0.52231E+00 -0.2821 99 HSO4- 0.41355E-19 -19.3835 0.34582E-19 -19.4611 0.83622E+00 -0.0777 Charge balance for all species = 0.4013E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9034180E-10 -.2311375E-01 -.2325507E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981176E+06 0.0000 3 Cl- 0.1671560E-03 0.1679356E-03 0.5943037E+01 6.2646 4 SO4-- 0.9533615E-12 -.1761074E-04 -.1688652E+01 7.9325 5 HCO3- 0.3439067E-06 0.1590818E-04 0.9689146E+00 3.5785 6 HS- 0.3103691E-04 0.4865357E-04 0.1606156E+01 5.5334 7 Al+++ 0.1103447E-28 0.5273570E-05 0.1420311E+00 0.7609 8 H4SiO4 0.7116309E-03 0.1419071E-01 0.1361475E+04 -3.1477 9 Ca++ 0.1433976E-06 0.2435311E-06 0.9742563E-02 13.1066 10 Mg++ 0.2277009E-10 0.9792300E-10 0.2376392E-05 9.3053 11 Fe++ 0.6228431E-13 0.3789281E-07 0.2112367E-02 6.7428 12 K+ 0.1615674E-03 0.1623440E-03 0.6336476E+01 6.2505 13 Na+ 0.2054092E-01 0.2313239E-01 0.5308457E+03 8.3540 14 Mn++ 0.1994050E-10 0.2629989E-08 0.1442246E-03 9.2486 15 HPO4-- 0.4871886E-07 0.4996968E-07 0.4787354E-02 12.6410 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2914296E+02 -.1899002E-01 -.2912397E+02 0.0000000E+00 2 H2O 0.3344594E+02 0.4560186E+02 -.1215592E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4880108E-01 -.1446881E-04 0.4881555E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4877557E-01 0.3997328E-04 -.4881555E-01 0.0000000E+00 7 Al+++ 0.5738902E+01 0.4332711E-05 0.5738898E+01 0.0000000E+00 8 H4SiO4 0.1832649E+02 0.1165894E-01 0.1831483E+02 0.0000000E+00 9 Ca++ 0.2024264E+01 0.2000827E-06 0.2024264E+01 0.0000000E+00 10 Mg++ 0.1396825E+01 0.8045253E-10 0.1396825E+01 0.0000000E+00 11 Fe++ 0.1254894E+01 0.3113235E-07 0.1254894E+01 0.0000000E+00 12 K+ 0.3736728E+00 0.1333801E-03 0.3735394E+00 0.0000000E+00 13 Na+ 0.2209388E+01 0.1900533E-01 0.2190382E+01 0.0000000E+00 14 Mn++ 0.3051591E-01 0.2160772E-08 0.3051591E-01 0.0000000E+00 15 HPO4-- 0.1041493E-01 0.4105458E-07 0.1041489E-01 0.0000000E+00 Chg. balance for solid moles: -.6745E-14 Mass of aqueous solution: 0.823081E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1759.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.189 0.340 573.9 2.759 29.85 220.3 andradite 0.1953 -0.709 99.23 1.997 5.161 25.78 grossular 0.4663E-01 -1.331 21.00 1.322 1.092 5.844 apatite-OH 0.3472E-02 -2.459 1.744 0.242 0.9070E-01 0.5541 clinochlore 0.2517 -0.599 139.9 2.146 7.275 53.21 daphnite 0.7212E-01 -1.142 51.46 1.711 2.676 15.59 chlorite-Mn 0.6103E-02 -2.214 4.327 0.636 0.2250 1.379 diopside 0.9231E-01 -1.035 19.99 1.301 1.040 6.110 hedenbergite 0.2365E-01 -1.626 5.867 0.768 0.3052 1.607 microcline 0.3271 -0.485 91.05 1.959 4.736 35.57 stilbite 1.140 0.057 803.2 2.905 41.78 374.6 stilpnomelane-Fe 0.9283E-01 -1.032 100.1 2.000 5.205 34.57 tr.625ac.25prg.125 0.1276E-01 -1.894 10.90 1.038 0.5672 3.510 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1850E-01 0.1850E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1922.683012 g Volume = 778.674312 cm3 Porosity: -10.4503% V(tot) - V(min): -.73675E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1759.9990000 g log = 3.2455 Original solution: 1000.0103000 g Original solution / Rock added: 0.57 (Water/Rock Ratio), log = -0.2455 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0905 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9651E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4573E-08 1.0071 0.5023E-08 0.4988E-08 CH4,gas 0.2123E-01 1.0128 0.2345E-01 0.2316E-01 H2,gas 0.1366E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1583E-06 0.9958 0.1719E-06 0.1726E-06 S2,gas 0.4564E-29 1.0000 0.4978E-29 0.4978E-29 CO,gas 0.1779E-13 1.0000 0.1940E-13 0.1940E-13 SO3,gas 0.9684E-48 1.0000 0.1056E-47 0.1056E-47 SO2,gas 0.5462E-27 1.0000 0.5957E-27 0.5957E-27 HCl,gas 0.3217E-17 1.0000 0.3508E-17 0.3508E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.66 -10.30 -3.433 0.17585E+05 -8.299 3 CH4,gas 4.81 1.18 -3.63 -0.907 0.61978E+04 -1.630 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.71 -8.76 -4.382 0.14966E+05 -6.765 6 S2,gas -7.03 -38.34 -31.30 -4.816 0.53449E+05 -29.303 7 CO,gas 3.51 -12.20 -15.71 -4.835 0.26828E+05 -13.712 8 SO3,gas 17.43 -32.55 -49.98 -12.494 0.85333E+05 -47.976 9 SO2,gas 1.14 -28.09 -29.22 -7.793 0.49901E+05 -27.225 10 HCl,gas 5.48 -13.98 -19.45 -9.727 0.33219E+05 -17.455 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80689E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94125E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.56 -4.54 -1.514 0.77552E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.56 -4.39 -1.463 0.74939E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65577E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.74 -4.63 -1.324 0.79127E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66055E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.74 -4.19 -1.198 0.71589E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82290E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61284E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53669E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92772E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40697E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43445E+04 143 pyrrhotite -4.24 -7.96 -3.72 -1.240 0.63535E+04 144 pyrrhotiteFe0.875 -6.00 -9.36 -3.36 -1.236 0.57363E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22457E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28301E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23249E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47186E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91030E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.96 -3.57 -1.190 0.60967E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80425E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66780E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60332E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.46 -4.50 -1.499 0.76775E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1759.9990000 g New total amount of reactant added: 1799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1799.9990000 Water: Moles liquid = 0.4538E+02 kg liquid = 0.8176E+00 Moles total = 0.3294E+02 kg total = 0.5935E+00 Activity = 1.0000 Stoichiometric ionic strength = .1175429E-01 Osmotic coef. = 0.9687 True ionic strength = .2070429E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90344E-10 -10.0441 0.75791E-10 -10.1204 0.83892E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16798E-03 -3.7747 0.14005E-03 -3.8537 0.83376E+00 -0.0790 4 SO4-- 0.95804E-12 -12.0186 0.49418E-12 -12.3061 0.51582E+00 -0.2875 5 HCO3- 0.34559E-06 -6.4614 0.28857E-06 -6.5397 0.83501E+00 -0.0783 6 HS- 0.31189E-04 -4.5060 0.26009E-04 -4.5849 0.83389E+00 -0.0789 7 Al+++ 0.11035E-28 -28.9572 0.25105E-29 -29.6002 0.22749E+00 -0.6430 8 H4SiO4 0.71163E-03 -3.1477 0.71163E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14341E-06 -6.8434 0.73417E-07 -7.1342 0.51195E+00 -0.2908 10 Mg++ 0.22771E-10 -10.6426 0.11603E-10 -10.9354 0.50956E+00 -0.2928 11 Fe++ 0.62288E-13 -13.2056 0.31775E-13 -13.4979 0.51013E+00 -0.2923 12 K+ 0.16157E-03 -3.7916 0.13495E-03 -3.8698 0.83521E+00 -0.0782 13 Na+ 0.20541E-01 -1.6874 0.17123E-01 -1.7664 0.83361E+00 -0.0790 14 Mn++ 0.19944E-10 -10.7002 0.10183E-10 -10.9921 0.51056E+00 -0.2920 15 HPO4-- 0.48717E-07 -7.3123 0.25133E-07 -7.5998 0.51590E+00 -0.2874 16 HSiO3- 0.10987E-01 -1.9591 0.91609E-02 -2.0381 0.83376E+00 -0.0790 17 Ca(HSiO3)+ 0.18038E-07 -7.7438 0.15069E-07 -7.8219 0.83539E+00 -0.0781 18 Mg(HSiO3)+ 0.35480E-11 -11.4500 0.29640E-11 -11.5281 0.83539E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67537E-16 -16.1705 0.56420E-16 -16.2486 0.83539E+00 -0.0781 22 HAlO2,aq 0.14896E-09 -9.8269 0.14896E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52733E-05 -5.2779 0.43886E-05 -5.3577 0.83223E+00 -0.0798 24 CH4,aq 0.14956E-04 -4.8252 0.14903E-04 -4.8267 0.99642E+00 -0.0016 25 C2H6,aq 0.35360E-14 -14.4515 0.35233E-14 -14.4530 0.99642E+00 -0.0016 29 CO,aq 0.12346E-16 -16.9085 0.12346E-16 -16.9085 0.10000E+01 0.0000 30 CO2,aq 0.44256E-10 -10.3540 0.44097E-10 -10.3556 0.99642E+00 -0.0016 31 CO3-2 0.68396E-06 -6.1650 0.35204E-06 -6.4534 0.51471E+00 -0.2884 32 CaCO3,aq 0.31654E-09 -9.4996 0.31654E-09 -9.4996 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.63902E-12 -12.1945 0.53383E-12 -12.2726 0.83539E+00 -0.0781 34 CaCl+ 0.19613E-10 -10.7074 0.16385E-10 -10.7856 0.83539E+00 -0.0781 35 CaCl2,aq 0.53430E-15 -15.2722 0.53430E-15 -15.2722 0.10000E+01 0.0000 36 CaOH+ 0.81763E-07 -7.0874 0.68304E-07 -7.1656 0.83539E+00 -0.0781 37 CaSO4,aq 0.11304E-16 -16.9468 0.11304E-16 -16.9468 0.10000E+01 0.0000 38 HCl,aq 0.19966E-14 -14.6997 0.19966E-14 -14.6997 0.10000E+01 0.0000 43 FeCl+ 0.82970E-17 -17.0811 0.69312E-17 -17.1592 0.83539E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16638E-10 -10.7789 0.13899E-10 -10.8570 0.83539E+00 -0.0781 48 HFeO2- 0.37232E-07 -7.4291 0.31043E-07 -7.5080 0.83376E+00 -0.0790 49 FeO+ 0.12280E-16 -16.9108 0.10258E-16 -16.9889 0.83539E+00 -0.0781 51 FeO2- 0.42097E-09 -9.3757 0.35099E-09 -9.4547 0.83376E+00 -0.0790 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.33465E-09 -9.4754 0.33465E-09 -9.4754 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.12323E-14 -14.9093 0.10274E-14 -14.9883 0.83376E+00 -0.0790 58 MgCO3,aq 0.12501E-13 -13.9030 0.12501E-13 -13.9030 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10299E-15 -15.9872 0.86035E-16 -16.0653 0.83539E+00 -0.0781 60 MgCl+ 0.28141E-14 -14.5507 0.23509E-14 -14.6288 0.83539E+00 -0.0781 61 MgOH+ 0.71591E-10 -10.1451 0.59807E-10 -10.2233 0.83539E+00 -0.0781 63 MnO,aq 0.18713E-08 -8.7279 0.18713E-08 -8.7279 0.10000E+01 0.0000 64 MnOH+ 0.49530E-09 -9.3051 0.41377E-09 -9.3832 0.83539E+00 -0.0781 65 MnO2-2 0.21888E-10 -10.6598 0.11266E-10 -10.9482 0.51471E+00 -0.2884 66 HMnO2- 0.22188E-09 -9.6539 0.18500E-09 -9.7328 0.83376E+00 -0.0790 69 MnCl+ 0.10332E-13 -13.9858 0.86312E-14 -14.0639 0.83539E+00 -0.0781 71 NaCl,aq 0.78307E-06 -6.1062 0.78307E-06 -6.1062 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95097E-02 -2.0218 0.79143E-02 -2.1016 0.83223E+00 -0.0798 79 HPO3-2 0.16766E-14 -14.7756 0.86297E-15 -15.0640 0.51471E+00 -0.2884 81 H2PO3- 0.15410E-18 -18.8122 0.12848E-18 -18.8912 0.83376E+00 -0.0790 82 H3PO4,aq 0.92946E-18 -18.0318 0.92946E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40016E-10 -10.3978 0.33396E-10 -10.4763 0.83457E+00 -0.0785 84 PO4-3 0.12107E-08 -8.9169 0.28960E-09 -9.5382 0.23919E+00 -0.6213 88 HP2O7-3 0.10370E-17 -17.9842 0.23616E-18 -18.6268 0.22773E+00 -0.6426 89 P2O7-4 0.10240E-16 -16.9897 0.76869E-18 -18.1142 0.75070E-01 -1.1245 90 H2S,aq 0.59439E-08 -8.2259 0.59227E-08 -8.2275 0.99642E+00 -0.0016 91 S2-2 0.26589E-14 -14.5753 0.13686E-14 -14.8637 0.51471E+00 -0.2884 97 SO3-2 0.14024E-17 -17.8531 0.73250E-18 -18.1352 0.52231E+00 -0.2821 99 HSO4- 0.41559E-19 -19.3813 0.34753E-19 -19.4590 0.83622E+00 -0.0777 Charge balance for all species = 0.4033E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9034413E-10 -.2311331E-01 -.2325463E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981176E+06 0.0000 3 Cl- 0.1679777E-03 0.1687611E-03 0.5972250E+01 6.2667 4 SO4-- 0.9580418E-12 -.1768391E-04 -.1695668E+01 7.9346 5 HCO3- 0.3455943E-06 0.1598638E-04 0.9736772E+00 3.5806 6 HS- 0.3118947E-04 0.4887933E-04 0.1613609E+01 5.5355 7 Al+++ 0.1103540E-28 0.5273430E-05 0.1420273E+00 0.7609 8 H4SiO4 0.7116319E-03 0.1419048E-01 0.1361453E+04 -3.1477 9 Ca++ 0.1434054E-06 0.2435430E-06 0.9743038E-02 13.1066 10 Mg++ 0.2277132E-10 0.9792579E-10 0.2376459E-05 9.3053 11 Fe++ 0.6228774E-13 0.3789195E-07 0.2112319E-02 6.7428 12 K+ 0.1615716E-03 0.1623481E-03 0.6336639E+01 6.2505 13 Na+ 0.2054145E-01 0.2313293E-01 0.5308581E+03 8.3540 14 Mn++ 0.1994395E-10 0.2630305E-08 0.1442420E-03 9.2486 15 HPO4-- 0.4871695E-07 0.4996771E-07 0.4787164E-02 12.6410 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2980530E+02 -.1889677E-01 -.2978640E+02 0.0000000E+00 2 H2O 0.3294452E+02 0.4537881E+02 -.1243428E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4990961E-01 -.1445786E-04 0.4992407E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4988411E-01 0.3996233E-04 -.4992407E-01 0.0000000E+00 7 Al+++ 0.5869332E+01 0.4311403E-05 0.5869327E+01 0.0000000E+00 8 H4SiO4 0.1874300E+02 0.1160172E-01 0.1873140E+02 0.0000000E+00 9 Ca++ 0.2070270E+01 0.1991137E-06 0.2070270E+01 0.0000000E+00 10 Mg++ 0.1428571E+01 0.8006129E-10 0.1428571E+01 0.0000000E+00 11 Fe++ 0.1283415E+01 0.3097936E-07 0.1283415E+01 0.0000000E+00 12 K+ 0.3821654E+00 0.1327312E-03 0.3820327E+00 0.0000000E+00 13 Na+ 0.2259597E+01 0.1891281E-01 0.2240685E+01 0.0000000E+00 14 Mn++ 0.3120946E-01 0.2150461E-08 0.3120945E-01 0.0000000E+00 15 HPO4-- 0.1065163E-01 0.4085215E-07 0.1065159E-01 0.0000000E+00 Chg. balance for solid moles: -.4052E-14 Mass of aqueous solution: 0.819055E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.239 0.350 587.1 2.769 29.86 225.4 andradite 0.1997 -0.700 101.5 2.006 5.161 26.37 grossular 0.4769E-01 -1.322 21.48 1.332 1.092 5.977 apatite-OH 0.3551E-02 -2.450 1.784 0.251 0.9070E-01 0.5667 clinochlore 0.2573 -0.589 143.0 2.155 7.274 54.41 daphnite 0.7375E-01 -1.132 52.62 1.721 2.676 15.95 chlorite-Mn 0.6242E-02 -2.205 4.425 0.646 0.2250 1.410 diopside 0.9463E-01 -1.024 20.49 1.312 1.042 6.263 hedenbergite 0.2424E-01 -1.615 6.014 0.779 0.3059 1.647 microcline 0.3346 -0.476 93.12 1.969 4.736 36.38 stilbite 1.165 0.066 821.3 2.915 41.77 383.1 stilpnomelane-Fe 0.9495E-01 -1.023 102.4 2.010 5.205 35.35 tr.625ac.25prg.125 0.1303E-01 -1.885 11.14 1.047 0.5664 3.585 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1850E-01 0.1850E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1966.385204 g Volume = 796.356855 cm3 Porosity: -10.4518% V(tot) - V(min): -.75357E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1799.9990000 g log = 3.2553 Original solution: 1000.0103000 g Original solution / Rock added: 0.56 (Water/Rock Ratio), log = -0.2553 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0907 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9650E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4595E-08 1.0071 0.5048E-08 0.5012E-08 CH4,gas 0.2134E-01 1.0128 0.2357E-01 0.2327E-01 H2,gas 0.1366E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1591E-06 0.9958 0.1727E-06 0.1735E-06 S2,gas 0.4609E-29 1.0000 0.5027E-29 0.5027E-29 CO,gas 0.1787E-13 1.0000 0.1950E-13 0.1950E-13 SO3,gas 0.9731E-48 1.0000 0.1061E-47 0.1061E-47 SO2,gas 0.5489E-27 1.0000 0.5986E-27 0.5986E-27 HCl,gas 0.3232E-17 1.0000 0.3525E-17 0.3525E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.66 -10.30 -3.432 0.17582E+05 -8.297 3 CH4,gas 4.81 1.18 -3.63 -0.907 0.61942E+04 -1.628 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.71 -8.76 -4.381 0.14962E+05 -6.763 6 S2,gas -7.03 -38.33 -31.30 -4.815 0.53442E+05 -29.299 7 CO,gas 3.51 -12.20 -15.71 -4.834 0.26825E+05 -13.710 8 SO3,gas 17.43 -32.55 -49.97 -12.494 0.85330E+05 -47.974 9 SO2,gas 1.14 -28.09 -29.22 -7.793 0.49897E+05 -27.223 10 HCl,gas 5.48 -13.97 -19.45 -9.726 0.33215E+05 -17.453 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80686E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94125E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.55 -4.54 -1.513 0.77516E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.55 -4.39 -1.462 0.74902E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65576E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.74 -4.63 -1.323 0.79090E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66055E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.74 -4.19 -1.197 0.71552E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82289E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61284E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53669E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92772E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40697E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43446E+04 143 pyrrhotite -4.24 -7.96 -3.72 -1.240 0.63498E+04 144 pyrrhotiteFe0.875 -6.00 -9.36 -3.36 -1.235 0.57326E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22456E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28301E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23248E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47184E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91030E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.96 -3.57 -1.189 0.60930E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80425E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66780E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60332E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.46 -4.49 -1.498 0.76738E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1799.9990000 g New total amount of reactant added: 1839.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1839.9990000 Water: Moles liquid = 0.4516E+02 kg liquid = 0.8136E+00 Moles total = 0.3244E+02 kg total = 0.5845E+00 Activity = 1.0000 Stoichiometric ionic strength = .1175499E-01 Osmotic coef. = 0.9687 True ionic strength = .2070484E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90346E-10 -10.0441 0.75793E-10 -10.1204 0.83892E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16881E-03 -3.7726 0.14075E-03 -3.8516 0.83376E+00 -0.0790 4 SO4-- 0.96277E-12 -12.0165 0.49661E-12 -12.3040 0.51582E+00 -0.2875 5 HCO3- 0.34730E-06 -6.4593 0.29000E-06 -6.5376 0.83500E+00 -0.0783 6 HS- 0.31344E-04 -4.5039 0.26137E-04 -4.5827 0.83389E+00 -0.0789 7 Al+++ 0.11036E-28 -28.9572 0.25106E-29 -29.6002 0.22749E+00 -0.6430 8 H4SiO4 0.71163E-03 -3.1477 0.71163E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14341E-06 -6.8434 0.73420E-07 -7.1342 0.51195E+00 -0.2908 10 Mg++ 0.22773E-10 -10.6426 0.11604E-10 -10.9354 0.50956E+00 -0.2928 11 Fe++ 0.62291E-13 -13.2056 0.31777E-13 -13.4979 0.51013E+00 -0.2923 12 K+ 0.16158E-03 -3.7916 0.13495E-03 -3.8698 0.83520E+00 -0.0782 13 Na+ 0.20542E-01 -1.6874 0.17124E-01 -1.7664 0.83360E+00 -0.0790 14 Mn++ 0.19947E-10 -10.7001 0.10184E-10 -10.9921 0.51056E+00 -0.2920 15 HPO4-- 0.48715E-07 -7.3123 0.25132E-07 -7.5998 0.51589E+00 -0.2874 16 HSiO3- 0.10987E-01 -1.9591 0.91607E-02 -2.0381 0.83376E+00 -0.0790 17 Ca(HSiO3)+ 0.18039E-07 -7.7438 0.15069E-07 -7.8219 0.83539E+00 -0.0781 18 Mg(HSiO3)+ 0.35481E-11 -11.4500 0.29640E-11 -11.5281 0.83539E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67538E-16 -16.1704 0.56421E-16 -16.2486 0.83539E+00 -0.0781 22 HAlO2,aq 0.14896E-09 -9.8269 0.14896E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52731E-05 -5.2779 0.43885E-05 -5.3577 0.83223E+00 -0.0798 24 CH4,aq 0.15030E-04 -4.8230 0.14977E-04 -4.8246 0.99642E+00 -0.0016 25 C2H6,aq 0.35710E-14 -14.4472 0.35582E-14 -14.4488 0.99642E+00 -0.0016 29 CO,aq 0.12408E-16 -16.9063 0.12408E-16 -16.9063 0.10000E+01 0.0000 30 CO2,aq 0.44475E-10 -10.3519 0.44315E-10 -10.3534 0.99642E+00 -0.0016 31 CO3-2 0.68732E-06 -6.1628 0.35376E-06 -6.4513 0.51470E+00 -0.2884 32 CaCO3,aq 0.31811E-09 -9.4974 0.31811E-09 -9.4974 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.64220E-12 -12.1923 0.53648E-12 -12.2704 0.83539E+00 -0.0781 34 CaCl+ 0.19711E-10 -10.7053 0.16466E-10 -10.7834 0.83539E+00 -0.0781 35 CaCl2,aq 0.53961E-15 -15.2679 0.53961E-15 -15.2679 0.10000E+01 0.0000 36 CaOH+ 0.81765E-07 -7.0874 0.68305E-07 -7.1655 0.83539E+00 -0.0781 37 CaSO4,aq 0.11361E-16 -16.9446 0.11361E-16 -16.9446 0.10000E+01 0.0000 38 HCl,aq 0.20065E-14 -14.6976 0.20065E-14 -14.6976 0.10000E+01 0.0000 43 FeCl+ 0.83384E-17 -17.0789 0.69658E-17 -17.1570 0.83539E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16638E-10 -10.7789 0.13899E-10 -10.8570 0.83539E+00 -0.0781 48 HFeO2- 0.37231E-07 -7.4291 0.31042E-07 -7.5080 0.83376E+00 -0.0790 49 FeO+ 0.12280E-16 -16.9108 0.10259E-16 -16.9889 0.83539E+00 -0.0781 51 FeO2- 0.42096E-09 -9.3758 0.35098E-09 -9.4547 0.83376E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4777 0.33293E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.33631E-09 -9.4733 0.33631E-09 -9.4733 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.12384E-14 -14.9072 0.10325E-14 -14.9861 0.83376E+00 -0.0790 58 MgCO3,aq 0.12563E-13 -13.9009 0.12563E-13 -13.9009 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10350E-15 -15.9851 0.86464E-16 -16.0632 0.83539E+00 -0.0781 60 MgCl+ 0.28281E-14 -14.5485 0.23626E-14 -14.6266 0.83539E+00 -0.0781 61 MgOH+ 0.71593E-10 -10.1451 0.59808E-10 -10.2232 0.83539E+00 -0.0781 63 MnO,aq 0.18715E-08 -8.7278 0.18715E-08 -8.7278 0.10000E+01 0.0000 64 MnOH+ 0.49537E-09 -9.3051 0.41383E-09 -9.3832 0.83539E+00 -0.0781 65 MnO2-2 0.21890E-10 -10.6598 0.11267E-10 -10.9482 0.51470E+00 -0.2884 66 HMnO2- 0.22190E-09 -9.6538 0.18502E-09 -9.7328 0.83376E+00 -0.0790 69 MnCl+ 0.10385E-13 -13.9836 0.86752E-14 -14.0617 0.83539E+00 -0.0781 71 NaCl,aq 0.78696E-06 -6.1040 0.78696E-06 -6.1040 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95095E-02 -2.0218 0.79141E-02 -2.1016 0.83223E+00 -0.0798 79 HPO3-2 0.16766E-14 -14.7756 0.86293E-15 -15.0640 0.51470E+00 -0.2884 81 H2PO3- 0.15409E-18 -18.8122 0.12848E-18 -18.8912 0.83376E+00 -0.0790 82 H3PO4,aq 0.92946E-18 -18.0318 0.92946E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40015E-10 -10.3978 0.33395E-10 -10.4763 0.83457E+00 -0.0785 84 PO4-3 0.12107E-08 -8.9170 0.28958E-09 -9.5382 0.23919E+00 -0.6213 88 HP2O7-3 0.10370E-17 -17.9842 0.23614E-18 -18.6268 0.22773E+00 -0.6426 89 P2O7-4 0.10239E-16 -16.9897 0.76862E-18 -18.1143 0.75068E-01 -1.1245 90 H2S,aq 0.59734E-08 -8.2238 0.59520E-08 -8.2253 0.99642E+00 -0.0016 91 S2-2 0.26853E-14 -14.5710 0.13821E-14 -14.8595 0.51470E+00 -0.2884 97 SO3-2 0.14093E-17 -17.8510 0.73610E-18 -18.1331 0.52231E+00 -0.2821 99 HSO4- 0.41765E-19 -19.3792 0.34925E-19 -19.4569 0.83622E+00 -0.0777 Charge balance for all species = 0.4053E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9034649E-10 -.2311286E-01 -.2325418E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981176E+06 0.0000 3 Cl- 0.1688074E-03 0.1695947E-03 0.6001750E+01 6.2688 4 SO4-- 0.9627677E-12 -.1775781E-04 -.1702754E+01 7.9368 5 HCO3- 0.3472983E-06 0.1606535E-04 0.9784868E+00 3.5828 6 HS- 0.3134354E-04 0.4910732E-04 0.1621136E+01 5.5376 7 Al+++ 0.1103634E-28 0.5273289E-05 0.1420235E+00 0.7609 8 H4SiO4 0.7116328E-03 0.1419025E-01 0.1361431E+04 -3.1477 9 Ca++ 0.1434132E-06 0.2435550E-06 0.9743517E-02 13.1066 10 Mg++ 0.2277256E-10 0.9792942E-10 0.2376548E-05 9.3053 11 Fe++ 0.6229120E-13 0.3789108E-07 0.2112270E-02 6.7428 12 K+ 0.1615758E-03 0.1623524E-03 0.6336804E+01 6.2505 13 Na+ 0.2054199E-01 0.2313347E-01 0.5308706E+03 8.3540 14 Mn++ 0.1994730E-10 0.2630608E-08 0.1442586E-03 9.2487 15 HPO4-- 0.4871501E-07 0.4996571E-07 0.4786972E-02 12.6410 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3046764E+02 -.1880353E-01 -.3044884E+02 0.0000000E+00 2 H2O 0.3244311E+02 0.4515575E+02 -.1271264E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5101815E-01 -.1444691E-04 0.5103260E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5099264E-01 0.3995138E-04 -.5103260E-01 0.0000000E+00 7 Al+++ 0.5999761E+01 0.4290097E-05 0.5999757E+01 0.0000000E+00 8 H4SiO4 0.1915951E+02 0.1154451E-01 0.1914797E+02 0.0000000E+00 9 Ca++ 0.2116276E+01 0.1981448E-06 0.2116276E+01 0.0000000E+00 10 Mg++ 0.1460317E+01 0.7967071E-10 0.1460317E+01 0.0000000E+00 11 Fe++ 0.1311935E+01 0.3082638E-07 0.1311935E+01 0.0000000E+00 12 K+ 0.3906580E+00 0.1320822E-03 0.3905259E+00 0.0000000E+00 13 Na+ 0.2309807E+01 0.1882029E-01 0.2290987E+01 0.0000000E+00 14 Mn++ 0.3190300E-01 0.2140137E-08 0.3190300E-01 0.0000000E+00 15 HPO4-- 0.1088834E-01 0.4064972E-07 0.1088829E-01 0.0000000E+00 Chg. balance for solid moles: 0.1551E-14 Mass of aqueous solution: 0.815029E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1839.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.289 0.360 600.3 2.778 29.86 230.4 andradite 0.2041 -0.690 103.7 2.016 5.161 26.95 grossular 0.4874E-01 -1.312 21.96 1.342 1.092 6.109 apatite-OH 0.3629E-02 -2.440 1.823 0.261 0.9070E-01 0.5793 clinochlore 0.2630 -0.580 146.2 2.165 7.273 55.61 daphnite 0.7538E-01 -1.123 53.79 1.731 2.676 16.30 chlorite-Mn 0.6381E-02 -2.195 4.524 0.655 0.2250 1.442 diopside 0.9694E-01 -1.014 20.99 1.322 1.044 6.416 hedenbergite 0.2483E-01 -1.605 6.161 0.790 0.3065 1.688 microcline 0.3420 -0.466 95.19 1.979 4.736 37.18 stilbite 1.191 0.076 839.4 2.924 41.76 391.5 stilpnomelane-Fe 0.9706E-01 -1.013 104.6 2.020 5.205 36.14 tr.625ac.25prg.125 0.1330E-01 -1.876 11.37 1.056 0.5657 3.660 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1851E-01 0.1851E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2010.087396 g Volume = 814.039398 cm3 Porosity: -10.4532% V(tot) - V(min): -.77040E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1839.9990000 g log = 3.2648 Original solution: 1000.0103000 g Original solution / Rock added: 0.54 (Water/Rock Ratio), log = -0.2648 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0908 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9649E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4618E-08 1.0071 0.5073E-08 0.5037E-08 CH4,gas 0.2144E-01 1.0128 0.2368E-01 0.2338E-01 H2,gas 0.1366E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1598E-06 0.9958 0.1736E-06 0.1743E-06 S2,gas 0.4655E-29 1.0000 0.5077E-29 0.5077E-29 CO,gas 0.1796E-13 1.0000 0.1959E-13 0.1959E-13 SO3,gas 0.9778E-48 1.0000 0.1067E-47 0.1067E-47 SO2,gas 0.5515E-27 1.0000 0.6016E-27 0.6016E-27 HCl,gas 0.3248E-17 1.0000 0.3543E-17 0.3543E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.24549E-10 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 67 diopside 16.22 16.22 0.00 0.000 -0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.66 -10.29 -3.432 0.17578E+05 -8.295 3 CH4,gas 4.81 1.18 -3.63 -0.906 0.61905E+04 -1.626 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.70 -8.76 -4.380 0.14958E+05 -6.760 6 S2,gas -7.03 -38.33 -31.29 -4.815 0.53434E+05 -29.294 7 CO,gas 3.51 -12.20 -15.71 -4.833 0.26821E+05 -13.708 8 SO3,gas 17.43 -32.54 -49.97 -12.493 0.85326E+05 -47.972 9 SO2,gas 1.14 -28.08 -29.22 -7.792 0.49894E+05 -27.221 10 HCl,gas 5.48 -13.97 -19.45 -9.725 0.33211E+05 -17.451 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80684E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94125E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.55 -4.54 -1.513 0.77479E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.55 -4.38 -1.462 0.74866E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65575E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.74 -4.63 -1.323 0.79054E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66055E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.74 -4.19 -1.197 0.71516E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82288E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61285E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53669E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92773E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40697E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43446E+04 143 pyrrhotite -4.24 -7.96 -3.72 -1.239 0.63462E+04 144 pyrrhotiteFe0.875 -6.00 -9.36 -3.36 -1.234 0.57289E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22455E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28301E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23247E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47183E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91030E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.96 -3.57 -1.189 0.60894E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80426E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66780E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60332E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.45 -4.49 -1.497 0.76700E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1839.9990000 g New total amount of reactant added: 1879.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1879.9990000 Water: Moles liquid = 0.4494E+02 kg liquid = 0.8095E+00 Moles total = 0.3194E+02 kg total = 0.5754E+00 Activity = 1.0000 Stoichiometric ionic strength = .1175569E-01 Osmotic coef. = 0.9687 True ionic strength = .2070539E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90349E-10 -10.0441 0.75795E-10 -10.1204 0.83891E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16965E-03 -3.7705 0.14144E-03 -3.8494 0.83376E+00 -0.0790 4 SO4-- 0.96754E-12 -12.0143 0.49907E-12 -12.3018 0.51582E+00 -0.2875 5 HCO3- 0.34902E-06 -6.4572 0.29143E-06 -6.5355 0.83500E+00 -0.0783 6 HS- 0.31499E-04 -4.5017 0.26267E-04 -4.5806 0.83388E+00 -0.0789 7 Al+++ 0.11037E-28 -28.9571 0.25108E-29 -29.6002 0.22748E+00 -0.6430 8 H4SiO4 0.71163E-03 -3.1477 0.71163E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14342E-06 -6.8434 0.73424E-07 -7.1342 0.51195E+00 -0.2908 10 Mg++ 0.22774E-10 -10.6426 0.11605E-10 -10.9354 0.50956E+00 -0.2928 11 Fe++ 0.62295E-13 -13.2055 0.31778E-13 -13.4979 0.51012E+00 -0.2923 12 K+ 0.16158E-03 -3.7916 0.13495E-03 -3.8698 0.83520E+00 -0.0782 13 Na+ 0.20543E-01 -1.6873 0.17124E-01 -1.7664 0.83360E+00 -0.0790 14 Mn++ 0.19951E-10 -10.7000 0.10186E-10 -10.9920 0.51056E+00 -0.2920 15 HPO4-- 0.48713E-07 -7.3124 0.25131E-07 -7.5998 0.51589E+00 -0.2874 16 HSiO3- 0.10987E-01 -1.9591 0.91605E-02 -2.0381 0.83376E+00 -0.0790 17 Ca(HSiO3)+ 0.18039E-07 -7.7438 0.15070E-07 -7.8219 0.83539E+00 -0.0781 18 Mg(HSiO3)+ 0.35482E-11 -11.4500 0.29641E-11 -11.5281 0.83539E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67540E-16 -16.1704 0.56422E-16 -16.2486 0.83539E+00 -0.0781 22 HAlO2,aq 0.14896E-09 -9.8269 0.14896E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52730E-05 -5.2779 0.43884E-05 -5.3577 0.83223E+00 -0.0798 24 CH4,aq 0.15105E-04 -4.8209 0.15051E-04 -4.8224 0.99642E+00 -0.0016 25 C2H6,aq 0.36066E-14 -14.4429 0.35937E-14 -14.4445 0.99642E+00 -0.0016 29 CO,aq 0.12469E-16 -16.9042 0.12469E-16 -16.9042 0.10000E+01 0.0000 30 CO2,aq 0.44696E-10 -10.3497 0.44536E-10 -10.3513 0.99642E+00 -0.0016 31 CO3-2 0.69071E-06 -6.1607 0.35551E-06 -6.4492 0.51470E+00 -0.2884 32 CaCO3,aq 0.31970E-09 -9.4953 0.31970E-09 -9.4953 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.64541E-12 -12.1902 0.53917E-12 -12.2683 0.83539E+00 -0.0781 34 CaCl+ 0.19810E-10 -10.7031 0.16549E-10 -10.7812 0.83539E+00 -0.0781 35 CaCl2,aq 0.54501E-15 -15.2636 0.54501E-15 -15.2636 0.10000E+01 0.0000 36 CaOH+ 0.81767E-07 -7.0874 0.68307E-07 -7.1655 0.83539E+00 -0.0781 37 CaSO4,aq 0.11417E-16 -16.9424 0.11417E-16 -16.9424 0.10000E+01 0.0000 38 HCl,aq 0.20165E-14 -14.6954 0.20165E-14 -14.6954 0.10000E+01 0.0000 43 FeCl+ 0.83802E-17 -17.0767 0.70007E-17 -17.1549 0.83539E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16639E-10 -10.7789 0.13900E-10 -10.8570 0.83539E+00 -0.0781 48 HFeO2- 0.37230E-07 -7.4291 0.31041E-07 -7.5081 0.83376E+00 -0.0790 49 FeO+ 0.12280E-16 -16.9108 0.10259E-16 -16.9889 0.83539E+00 -0.0781 51 FeO2- 0.42095E-09 -9.3758 0.35097E-09 -9.4547 0.83376E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4777 0.33293E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.33798E-09 -9.4711 0.33798E-09 -9.4711 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.12445E-14 -14.9050 0.10376E-14 -14.9840 0.83376E+00 -0.0790 58 MgCO3,aq 0.12626E-13 -13.8987 0.12626E-13 -13.8987 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10402E-15 -15.9829 0.86896E-16 -16.0610 0.83539E+00 -0.0781 60 MgCl+ 0.28423E-14 -14.5463 0.23744E-14 -14.6244 0.83539E+00 -0.0781 61 MgOH+ 0.71595E-10 -10.1451 0.59809E-10 -10.2232 0.83539E+00 -0.0781 63 MnO,aq 0.18717E-08 -8.7278 0.18717E-08 -8.7278 0.10000E+01 0.0000 64 MnOH+ 0.49544E-09 -9.3050 0.41388E-09 -9.3831 0.83539E+00 -0.0781 65 MnO2-2 0.21891E-10 -10.6597 0.11267E-10 -10.9482 0.51470E+00 -0.2884 66 HMnO2- 0.22192E-09 -9.6538 0.18503E-09 -9.7328 0.83376E+00 -0.0790 69 MnCl+ 0.10438E-13 -13.9814 0.87197E-14 -14.0595 0.83539E+00 -0.0781 71 NaCl,aq 0.79088E-06 -6.1019 0.79088E-06 -6.1019 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95093E-02 -2.0219 0.79139E-02 -2.1016 0.83223E+00 -0.0798 79 HPO3-2 0.16765E-14 -14.7756 0.86289E-15 -15.0640 0.51470E+00 -0.2884 81 H2PO3- 0.15409E-18 -18.8122 0.12847E-18 -18.8912 0.83376E+00 -0.0790 82 H3PO4,aq 0.92946E-18 -18.0318 0.92946E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40014E-10 -10.3978 0.33395E-10 -10.4763 0.83457E+00 -0.0785 84 PO4-3 0.12106E-08 -8.9170 0.28956E-09 -9.5383 0.23918E+00 -0.6213 88 HP2O7-3 0.10369E-17 -17.9843 0.23613E-18 -18.6269 0.22773E+00 -0.6426 89 P2O7-4 0.10238E-16 -16.9898 0.76855E-18 -18.1143 0.75066E-01 -1.1246 90 H2S,aq 0.60032E-08 -8.2216 0.59817E-08 -8.2232 0.99642E+00 -0.0016 91 S2-2 0.27120E-14 -14.5667 0.13959E-14 -14.8552 0.51470E+00 -0.2884 97 SO3-2 0.14163E-17 -17.8488 0.73974E-18 -18.1309 0.52230E+00 -0.2821 99 HSO4- 0.41973E-19 -19.3770 0.35098E-19 -19.4547 0.83622E+00 -0.0777 Charge balance for all species = 0.4074E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9034887E-10 -.2311242E-01 -.2325373E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981175E+06 0.0000 3 Cl- 0.1696454E-03 0.1704366E-03 0.6031544E+01 6.2709 4 SO4-- 0.9675397E-12 -.1783244E-04 -.1709910E+01 7.9389 5 HCO3- 0.3490190E-06 0.1614510E-04 0.9833442E+00 3.5849 6 HS- 0.3149913E-04 0.4933757E-04 0.1628737E+01 5.5398 7 Al+++ 0.1103729E-28 0.5273148E-05 0.1420197E+00 0.7609 8 H4SiO4 0.7116337E-03 0.1419002E-01 0.1361409E+04 -3.1477 9 Ca++ 0.1434211E-06 0.2435671E-06 0.9744002E-02 13.1066 10 Mg++ 0.2277382E-10 0.9793199E-10 0.2376610E-05 9.3053 11 Fe++ 0.6229469E-13 0.3789020E-07 0.2112221E-02 6.7428 12 K+ 0.1615801E-03 0.1623566E-03 0.6336970E+01 6.2505 13 Na+ 0.2054253E-01 0.2313403E-01 0.5308833E+03 8.3540 14 Mn++ 0.1995057E-10 0.2630899E-08 0.1442745E-03 9.2487 15 HPO4-- 0.4871306E-07 0.4996368E-07 0.4786778E-02 12.6409 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3112998E+02 -.1871028E-01 -.3111127E+02 0.0000000E+00 2 H2O 0.3194169E+02 0.4493270E+02 -.1299101E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5212669E-01 -.1443596E-04 0.5214112E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5210118E-01 0.3994043E-04 -.5214112E-01 0.0000000E+00 7 Al+++ 0.6130191E+01 0.4268791E-05 0.6130187E+01 0.0000000E+00 8 H4SiO4 0.1957602E+02 0.1148730E-01 0.1956453E+02 0.0000000E+00 9 Ca++ 0.2162282E+01 0.1971758E-06 0.2162281E+01 0.0000000E+00 10 Mg++ 0.1492063E+01 0.7927925E-10 0.1492063E+01 0.0000000E+00 11 Fe++ 0.1340455E+01 0.3067339E-07 0.1340455E+01 0.0000000E+00 12 K+ 0.3991505E+00 0.1314332E-03 0.3990191E+00 0.0000000E+00 13 Na+ 0.2360017E+01 0.1872777E-01 0.2341289E+01 0.0000000E+00 14 Mn++ 0.3259654E-01 0.2129801E-08 0.3259654E-01 0.0000000E+00 15 HPO4-- 0.1112504E-01 0.4044728E-07 0.1112500E-01 0.0000000E+00 Chg. balance for solid moles: -.5787E-14 Mass of aqueous solution: 0.811003E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1879.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.340 0.369 613.5 2.788 29.87 235.5 andradite 0.2086 -0.681 106.0 2.025 5.161 27.54 grossular 0.4980E-01 -1.303 22.43 1.351 1.092 6.242 apatite-OH 0.3708E-02 -2.431 1.863 0.270 0.9070E-01 0.5919 clinochlore 0.2687 -0.571 149.4 2.174 7.273 56.81 daphnite 0.7701E-01 -1.113 54.95 1.740 2.676 16.65 chlorite-Mn 0.6519E-02 -2.186 4.622 0.665 0.2250 1.473 diopside 0.9925E-01 -1.003 21.49 1.332 1.047 6.569 hedenbergite 0.2543E-01 -1.595 6.308 0.800 0.3072 1.728 microcline 0.3494 -0.457 97.26 1.988 4.736 37.99 stilbite 1.217 0.085 857.5 2.933 41.75 400.0 stilpnomelane-Fe 0.9917E-01 -1.004 106.9 2.029 5.205 36.93 tr.625ac.25prg.125 0.1358E-01 -1.867 11.60 1.065 0.5650 3.735 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1851E-01 0.1851E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2053.789588 g Volume = 831.721940 cm3 Porosity: -10.4545% V(tot) - V(min): -.78722E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1879.9990000 g log = 3.2742 Original solution: 1000.0103000 g Original solution / Rock added: 0.53 (Water/Rock Ratio), log = -0.2742 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0909 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9648E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4640E-08 1.0071 0.5098E-08 0.5062E-08 CH4,gas 0.2154E-01 1.0128 0.2380E-01 0.2350E-01 H2,gas 0.1366E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1606E-06 0.9958 0.1745E-06 0.1752E-06 S2,gas 0.4701E-29 1.0000 0.5128E-29 0.5128E-29 CO,gas 0.1805E-13 1.0000 0.1969E-13 0.1969E-13 SO3,gas 0.9826E-48 1.0000 0.1072E-47 0.1072E-47 SO2,gas 0.5542E-27 1.0000 0.6046E-27 0.6046E-27 HCl,gas 0.3264E-17 1.0000 0.3561E-17 0.3561E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.66 -10.29 -3.431 0.17574E+05 -8.293 3 CH4,gas 4.81 1.19 -3.62 -0.906 0.61869E+04 -1.623 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.70 -8.76 -4.379 0.14955E+05 -6.758 6 S2,gas -7.03 -38.32 -31.29 -4.814 0.53427E+05 -29.290 7 CO,gas 3.51 -12.20 -15.71 -4.833 0.26817E+05 -13.706 8 SO3,gas 17.43 -32.54 -49.97 -12.492 0.85322E+05 -47.970 9 SO2,gas 1.14 -28.08 -29.22 -7.792 0.49890E+05 -27.219 10 HCl,gas 5.48 -13.97 -19.45 -9.724 0.33208E+05 -17.448 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80681E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94125E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76236E+04 35 aragonite 0.99 -3.55 -4.54 -1.512 0.77442E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.55 -4.38 -1.461 0.74829E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65575E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.74 -4.63 -1.322 0.79017E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66055E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.74 -4.19 -1.196 0.71479E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82287E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61285E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53669E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92773E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40697E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43446E+04 143 pyrrhotite -4.24 -7.96 -3.71 -1.238 0.63425E+04 144 pyrrhotiteFe0.875 -6.00 -9.35 -3.35 -1.233 0.57253E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22454E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28300E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23247E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47181E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91030E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.96 -3.56 -1.188 0.60857E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80426E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66780E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60332E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.45 -4.49 -1.497 0.76663E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1879.9990000 g New total amount of reactant added: 1919.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1919.9990000 Water: Moles liquid = 0.4471E+02 kg liquid = 0.8055E+00 Moles total = 0.3144E+02 kg total = 0.5664E+00 Activity = 1.0000 Stoichiometric ionic strength = .1175641E-01 Osmotic coef. = 0.9687 True ionic strength = .2070594E-01 Chg. balance for total moles = 0.3297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90351E-10 -10.0441 0.75797E-10 -10.1203 0.83891E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17049E-03 -3.7683 0.14215E-03 -3.8473 0.83376E+00 -0.0790 4 SO4-- 0.97236E-12 -12.0122 0.50155E-12 -12.2997 0.51581E+00 -0.2875 5 HCO3- 0.35076E-06 -6.4550 0.29288E-06 -6.5333 0.83500E+00 -0.0783 6 HS- 0.31656E-04 -4.4995 0.26398E-04 -4.5784 0.83388E+00 -0.0789 7 Al+++ 0.11038E-28 -28.9571 0.25110E-29 -29.6002 0.22748E+00 -0.6431 8 H4SiO4 0.71163E-03 -3.1477 0.71163E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14343E-06 -6.8434 0.73427E-07 -7.1341 0.51194E+00 -0.2908 10 Mg++ 0.22775E-10 -10.6425 0.11605E-10 -10.9354 0.50955E+00 -0.2928 11 Fe++ 0.62298E-13 -13.2055 0.31780E-13 -13.4979 0.51012E+00 -0.2923 12 K+ 0.16158E-03 -3.7916 0.13496E-03 -3.8698 0.83520E+00 -0.0782 13 Na+ 0.20543E-01 -1.6873 0.17125E-01 -1.7664 0.83360E+00 -0.0790 14 Mn++ 0.19954E-10 -10.7000 0.10187E-10 -10.9919 0.51055E+00 -0.2920 15 HPO4-- 0.48711E-07 -7.3124 0.25129E-07 -7.5998 0.51589E+00 -0.2874 16 HSiO3- 0.10987E-01 -1.9591 0.91603E-02 -2.0381 0.83376E+00 -0.0790 17 Ca(HSiO3)+ 0.18040E-07 -7.7438 0.15070E-07 -7.8219 0.83538E+00 -0.0781 18 Mg(HSiO3)+ 0.35483E-11 -11.4500 0.29642E-11 -11.5281 0.83538E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67541E-16 -16.1704 0.56423E-16 -16.2485 0.83538E+00 -0.0781 22 HAlO2,aq 0.14896E-09 -9.8269 0.14896E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52729E-05 -5.2780 0.43882E-05 -5.3577 0.83223E+00 -0.0798 24 CH4,aq 0.15180E-04 -4.8187 0.15126E-04 -4.8203 0.99642E+00 -0.0016 25 C2H6,aq 0.36427E-14 -14.4386 0.36296E-14 -14.4401 0.99642E+00 -0.0016 29 CO,aq 0.12532E-16 -16.9020 0.12532E-16 -16.9020 0.10000E+01 0.0000 30 CO2,aq 0.44920E-10 -10.3476 0.44759E-10 -10.3491 0.99642E+00 -0.0016 31 CO3-2 0.69413E-06 -6.1586 0.35727E-06 -6.4470 0.51469E+00 -0.2885 32 CaCO3,aq 0.32129E-09 -9.4931 0.32129E-09 -9.4931 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.64866E-12 -12.1880 0.54188E-12 -12.2661 0.83538E+00 -0.0781 34 CaCl+ 0.19910E-10 -10.7009 0.16632E-10 -10.7790 0.83538E+00 -0.0781 35 CaCl2,aq 0.55049E-15 -15.2593 0.55049E-15 -15.2593 0.10000E+01 0.0000 36 CaOH+ 0.81769E-07 -7.0874 0.68308E-07 -7.1655 0.83538E+00 -0.0781 37 CaSO4,aq 0.11475E-16 -16.9403 0.11475E-16 -16.9403 0.10000E+01 0.0000 38 HCl,aq 0.20266E-14 -14.6932 0.20266E-14 -14.6932 0.10000E+01 0.0000 43 FeCl+ 0.84224E-17 -17.0746 0.70360E-17 -17.1527 0.83538E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16639E-10 -10.7789 0.13900E-10 -10.8570 0.83538E+00 -0.0781 48 HFeO2- 0.37230E-07 -7.4291 0.31041E-07 -7.5081 0.83376E+00 -0.0790 49 FeO+ 0.12281E-16 -16.9108 0.10259E-16 -16.9889 0.83538E+00 -0.0781 51 FeO2- 0.42094E-09 -9.3758 0.35097E-09 -9.4547 0.83376E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4777 0.33293E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.33968E-09 -9.4689 0.33968E-09 -9.4689 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.12507E-14 -14.9028 0.10428E-14 -14.9818 0.83376E+00 -0.0790 58 MgCO3,aq 0.12689E-13 -13.8966 0.12689E-13 -13.8966 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10454E-15 -15.9807 0.87333E-16 -16.0588 0.83538E+00 -0.0781 60 MgCl+ 0.28566E-14 -14.5441 0.23864E-14 -14.6223 0.83538E+00 -0.0781 61 MgOH+ 0.71597E-10 -10.1451 0.59811E-10 -10.2232 0.83538E+00 -0.0781 63 MnO,aq 0.18719E-08 -8.7277 0.18719E-08 -8.7277 0.10000E+01 0.0000 64 MnOH+ 0.49550E-09 -9.3050 0.41393E-09 -9.3831 0.83538E+00 -0.0781 65 MnO2-2 0.21892E-10 -10.6597 0.11268E-10 -10.9482 0.51469E+00 -0.2885 66 HMnO2- 0.22194E-09 -9.6538 0.18505E-09 -9.7327 0.83376E+00 -0.0790 69 MnCl+ 0.10492E-13 -13.9792 0.87645E-14 -14.0573 0.83538E+00 -0.0781 71 NaCl,aq 0.79485E-06 -6.0997 0.79485E-06 -6.0997 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95091E-02 -2.0219 0.79137E-02 -2.1016 0.83223E+00 -0.0798 79 HPO3-2 0.16764E-14 -14.7756 0.86285E-15 -15.0641 0.51469E+00 -0.2885 81 H2PO3- 0.15408E-18 -18.8122 0.12847E-18 -18.8912 0.83376E+00 -0.0790 82 H3PO4,aq 0.92947E-18 -18.0318 0.92947E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40014E-10 -10.3978 0.33394E-10 -10.4763 0.83456E+00 -0.0785 84 PO4-3 0.12105E-08 -8.9170 0.28953E-09 -9.5383 0.23918E+00 -0.6213 88 HP2O7-3 0.10368E-17 -17.9843 0.23611E-18 -18.6269 0.22772E+00 -0.6426 89 P2O7-4 0.10238E-16 -16.9898 0.76848E-18 -18.1144 0.75064E-01 -1.1246 90 H2S,aq 0.60333E-08 -8.2194 0.60117E-08 -8.2210 0.99642E+00 -0.0016 91 S2-2 0.27391E-14 -14.5624 0.14098E-14 -14.8508 0.51469E+00 -0.2885 97 SO3-2 0.14234E-17 -17.8467 0.74342E-18 -18.1288 0.52230E+00 -0.2821 99 HSO4- 0.42183E-19 -19.3749 0.35274E-19 -19.4525 0.83622E+00 -0.0777 Charge balance for all species = 0.4094E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9035127E-10 -.2311196E-01 -.2325327E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981175E+06 0.0000 3 Cl- 0.1704917E-03 0.1712869E-03 0.6061635E+01 6.2731 4 SO4-- 0.9723587E-12 -.1790781E-04 -.1717137E+01 7.9410 5 HCO3- 0.3507566E-06 0.1622564E-04 0.9882500E+00 3.5870 6 HS- 0.3165628E-04 0.4957013E-04 0.1636414E+01 5.5419 7 Al+++ 0.1103825E-28 0.5273007E-05 0.1420159E+00 0.7609 8 H4SiO4 0.7116346E-03 0.1418978E-01 0.1361386E+04 -3.1477 9 Ca++ 0.1434291E-06 0.2435794E-06 0.9744492E-02 13.1066 10 Mg++ 0.2277509E-10 0.9793569E-10 0.2376700E-05 9.3053 11 Fe++ 0.6229821E-13 0.3788931E-07 0.2112171E-02 6.7428 12 K+ 0.1615844E-03 0.1623610E-03 0.6337138E+01 6.2505 13 Na+ 0.2054308E-01 0.2313458E-01 0.5308960E+03 8.3540 14 Mn++ 0.1995376E-10 0.2631178E-08 0.1442898E-03 9.2488 15 HPO4-- 0.4871108E-07 0.4996163E-07 0.4786581E-02 12.6409 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3179232E+02 -.1861703E-01 -.3177370E+02 0.0000000E+00 2 H2O 0.3144027E+02 0.4470964E+02 -.1326937E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5323522E-01 -.1442501E-04 0.5324965E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5320972E-01 0.3992948E-04 -.5324965E-01 0.0000000E+00 7 Al+++ 0.6260621E+01 0.4247487E-05 0.6260616E+01 0.0000000E+00 8 H4SiO4 0.1999253E+02 0.1143008E-01 0.1998110E+02 0.0000000E+00 9 Ca++ 0.2208287E+01 0.1962069E-06 0.2208287E+01 0.0000000E+00 10 Mg++ 0.1523809E+01 0.7888867E-10 0.1523809E+01 0.0000000E+00 11 Fe++ 0.1368976E+01 0.3052041E-07 0.1368976E+01 0.0000000E+00 12 K+ 0.4076431E+00 0.1307842E-03 0.4075123E+00 0.0000000E+00 13 Na+ 0.2410227E+01 0.1863525E-01 0.2391591E+01 0.0000000E+00 14 Mn++ 0.3329009E-01 0.2119453E-08 0.3329008E-01 0.0000000E+00 15 HPO4-- 0.1136174E-01 0.4024485E-07 0.1136170E-01 0.0000000E+00 Chg. balance for solid moles: 0.1228E-14 Mass of aqueous solution: 0.806977E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1919.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.390 0.378 626.7 2.797 29.88 240.6 andradite 0.2130 -0.672 108.2 2.034 5.161 28.12 grossular 0.5086E-01 -1.294 22.91 1.360 1.092 6.375 apatite-OH 0.3787E-02 -2.422 1.902 0.279 0.9070E-01 0.6045 clinochlore 0.2744 -0.562 152.5 2.183 7.272 58.02 daphnite 0.7864E-01 -1.104 56.11 1.749 2.675 17.00 chlorite-Mn 0.6658E-02 -2.177 4.720 0.674 0.2250 1.504 diopside 0.1016 -0.993 22.00 1.342 1.049 6.722 hedenbergite 0.2602E-01 -1.585 6.456 0.810 0.3078 1.768 microcline 0.3569 -0.447 99.33 1.997 4.736 38.80 stilbite 1.242 0.094 875.6 2.942 41.75 408.4 stilpnomelane-Fe 0.1013 -0.994 109.2 2.038 5.205 37.71 tr.625ac.25prg.125 0.1385E-01 -1.859 11.84 1.073 0.5643 3.810 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1851E-01 0.1851E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2097.491781 g Volume = 849.404483 cm3 Porosity: -10.4558% V(tot) - V(min): -.80405E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1919.9990000 g log = 3.2833 Original solution: 1000.0103000 g Original solution / Rock added: 0.52 (Water/Rock Ratio), log = -0.2833 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0910 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9647E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4663E-08 1.0071 0.5123E-08 0.5087E-08 CH4,gas 0.2165E-01 1.0128 0.2392E-01 0.2362E-01 H2,gas 0.1366E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1614E-06 0.9958 0.1753E-06 0.1761E-06 S2,gas 0.4747E-29 1.0000 0.5179E-29 0.5179E-29 CO,gas 0.1814E-13 1.0000 0.1979E-13 0.1979E-13 SO3,gas 0.9874E-48 1.0000 0.1077E-47 0.1077E-47 SO2,gas 0.5569E-27 1.0000 0.6076E-27 0.6076E-27 HCl,gas 0.3280E-17 1.0000 0.3578E-17 0.3578E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.65 -10.29 -3.430 0.17571E+05 -8.290 3 CH4,gas 4.81 1.19 -3.62 -0.905 0.61832E+04 -1.621 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.70 -8.76 -4.378 0.14951E+05 -6.756 6 S2,gas -7.03 -38.32 -31.29 -4.813 0.53420E+05 -29.286 7 CO,gas 3.51 -12.19 -15.70 -4.832 0.26813E+05 -13.704 8 SO3,gas 17.43 -32.54 -49.97 -12.492 0.85318E+05 -47.968 9 SO2,gas 1.14 -28.08 -29.22 -7.791 0.49886E+05 -27.216 10 HCl,gas 5.48 -13.97 -19.45 -9.723 0.33204E+05 -17.446 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80679E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94125E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76236E+04 35 aragonite 0.99 -3.55 -4.53 -1.511 0.77405E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.55 -4.38 -1.460 0.74792E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65574E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.73 -4.63 -1.322 0.78980E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66055E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.73 -4.18 -1.195 0.71442E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82286E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61285E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53669E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92773E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40697E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43446E+04 143 pyrrhotite -4.24 -7.96 -3.71 -1.237 0.63388E+04 144 pyrrhotiteFe0.875 -6.00 -9.35 -3.35 -1.232 0.57215E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22453E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28300E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23246E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47179E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91030E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.96 -3.56 -1.187 0.60820E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80426E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66780E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60332E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.45 -4.49 -1.496 0.76625E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1919.9990000 g New total amount of reactant added: 1959.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1959.9990000 Water: Moles liquid = 0.4449E+02 kg liquid = 0.8015E+00 Moles total = 0.3094E+02 kg total = 0.5574E+00 Activity = 1.0000 Stoichiometric ionic strength = .1175712E-01 Osmotic coef. = 0.9687 True ionic strength = .2070651E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90354E-10 -10.0441 0.75799E-10 -10.1203 0.83891E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17135E-03 -3.7661 0.14286E-03 -3.8451 0.83376E+00 -0.0790 4 SO4-- 0.97723E-12 -12.0100 0.50406E-12 -12.2975 0.51581E+00 -0.2875 5 HCO3- 0.35251E-06 -6.4528 0.29435E-06 -6.5311 0.83500E+00 -0.0783 6 HS- 0.31815E-04 -4.4974 0.26530E-04 -4.5763 0.83388E+00 -0.0789 7 Al+++ 0.11039E-28 -28.9571 0.25112E-29 -29.6001 0.22748E+00 -0.6431 8 H4SiO4 0.71164E-03 -3.1477 0.71164E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14344E-06 -6.8433 0.73431E-07 -7.1341 0.51194E+00 -0.2908 10 Mg++ 0.22776E-10 -10.6425 0.11606E-10 -10.9353 0.50955E+00 -0.2928 11 Fe++ 0.62302E-13 -13.2055 0.31781E-13 -13.4978 0.51012E+00 -0.2923 12 K+ 0.16159E-03 -3.7916 0.13496E-03 -3.8698 0.83520E+00 -0.0782 13 Na+ 0.20544E-01 -1.6873 0.17125E-01 -1.7664 0.83360E+00 -0.0790 14 Mn++ 0.19957E-10 -10.6999 0.10189E-10 -10.9919 0.51055E+00 -0.2920 15 HPO4-- 0.48709E-07 -7.3124 0.25128E-07 -7.5998 0.51588E+00 -0.2874 16 HSiO3- 0.10986E-01 -1.9591 0.91600E-02 -2.0381 0.83376E+00 -0.0790 17 Ca(HSiO3)+ 0.18040E-07 -7.7438 0.15070E-07 -7.8219 0.83538E+00 -0.0781 18 Mg(HSiO3)+ 0.35484E-11 -11.4500 0.29643E-11 -11.5281 0.83538E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67543E-16 -16.1704 0.56424E-16 -16.2485 0.83538E+00 -0.0781 22 HAlO2,aq 0.14896E-09 -9.8269 0.14896E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52727E-05 -5.2780 0.43881E-05 -5.3577 0.83223E+00 -0.0798 24 CH4,aq 0.15257E-04 -4.8165 0.15202E-04 -4.8181 0.99642E+00 -0.0016 25 C2H6,aq 0.36793E-14 -14.4342 0.36662E-14 -14.4358 0.99642E+00 -0.0016 29 CO,aq 0.12595E-16 -16.8998 0.12595E-16 -16.8998 0.10000E+01 0.0000 30 CO2,aq 0.45146E-10 -10.3454 0.44984E-10 -10.3469 0.99642E+00 -0.0016 31 CO3-2 0.69759E-06 -6.1564 0.35905E-06 -6.4449 0.51469E+00 -0.2885 32 CaCO3,aq 0.32291E-09 -9.4909 0.32291E-09 -9.4909 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.65193E-12 -12.1858 0.54461E-12 -12.2639 0.83538E+00 -0.0781 34 CaCl+ 0.20010E-10 -10.6987 0.16716E-10 -10.7769 0.83538E+00 -0.0781 35 CaCl2,aq 0.55604E-15 -15.2549 0.55604E-15 -15.2549 0.10000E+01 0.0000 36 CaOH+ 0.81771E-07 -7.0874 0.68310E-07 -7.1655 0.83538E+00 -0.0781 37 CaSO4,aq 0.11533E-16 -16.9381 0.11533E-16 -16.9381 0.10000E+01 0.0000 38 HCl,aq 0.20369E-14 -14.6910 0.20369E-14 -14.6910 0.10000E+01 0.0000 43 FeCl+ 0.84651E-17 -17.0724 0.70716E-17 -17.1505 0.83538E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16639E-10 -10.7789 0.13900E-10 -10.8570 0.83538E+00 -0.0781 48 HFeO2- 0.37229E-07 -7.4291 0.31040E-07 -7.5081 0.83376E+00 -0.0790 49 FeO+ 0.12281E-16 -16.9108 0.10259E-16 -16.9889 0.83538E+00 -0.0781 51 FeO2- 0.42093E-09 -9.3758 0.35096E-09 -9.4547 0.83376E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4777 0.33293E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.34139E-09 -9.4668 0.34139E-09 -9.4668 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.12570E-14 -14.9007 0.10481E-14 -14.9796 0.83376E+00 -0.0790 58 MgCO3,aq 0.12753E-13 -13.8944 0.12753E-13 -13.8944 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10507E-15 -15.9785 0.87774E-16 -16.0566 0.83538E+00 -0.0781 60 MgCl+ 0.28711E-14 -14.5420 0.23985E-14 -14.6201 0.83538E+00 -0.0781 61 MgOH+ 0.71599E-10 -10.1451 0.59812E-10 -10.2232 0.83538E+00 -0.0781 63 MnO,aq 0.18721E-08 -8.7277 0.18721E-08 -8.7277 0.10000E+01 0.0000 64 MnOH+ 0.49556E-09 -9.3049 0.41398E-09 -9.3830 0.83538E+00 -0.0781 65 MnO2-2 0.21894E-10 -10.6597 0.11268E-10 -10.9481 0.51469E+00 -0.2885 66 HMnO2- 0.22196E-09 -9.6537 0.18506E-09 -9.7327 0.83376E+00 -0.0790 69 MnCl+ 0.10546E-13 -13.9769 0.88097E-14 -14.0550 0.83538E+00 -0.0781 71 NaCl,aq 0.79885E-06 -6.0975 0.79885E-06 -6.0975 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95088E-02 -2.0219 0.79135E-02 -2.1016 0.83223E+00 -0.0798 79 HPO3-2 0.16763E-14 -14.7756 0.86280E-15 -15.0641 0.51469E+00 -0.2885 81 H2PO3- 0.15408E-18 -18.8123 0.12847E-18 -18.8912 0.83376E+00 -0.0790 82 H3PO4,aq 0.92947E-18 -18.0318 0.92947E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40013E-10 -10.3978 0.33393E-10 -10.4763 0.83456E+00 -0.0785 84 PO4-3 0.12105E-08 -8.9170 0.28951E-09 -9.5383 0.23918E+00 -0.6213 88 HP2O7-3 0.10368E-17 -17.9843 0.23609E-18 -18.6269 0.22772E+00 -0.6426 89 P2O7-4 0.10237E-16 -16.9898 0.76840E-18 -18.1144 0.75061E-01 -1.1246 90 H2S,aq 0.60637E-08 -8.2173 0.60420E-08 -8.2188 0.99642E+00 -0.0016 91 S2-2 0.27667E-14 -14.5580 0.14240E-14 -14.8465 0.51469E+00 -0.2885 97 SO3-2 0.14305E-17 -17.8445 0.74713E-18 -18.1266 0.52230E+00 -0.2821 99 HSO4- 0.42395E-19 -19.3727 0.35451E-19 -19.4504 0.83622E+00 -0.0777 Charge balance for all species = 0.4113E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9035370E-10 -.2311150E-01 -.2325281E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981175E+06 0.0000 3 Cl- 0.1713465E-03 0.1721457E-03 0.6092028E+01 6.2753 4 SO4-- 0.9772255E-12 -.1798395E-04 -.1724437E+01 7.9432 5 HCO3- 0.3525114E-06 0.1630700E-04 0.9932051E+00 3.5892 6 HS- 0.3181500E-04 0.4980501E-04 0.1644168E+01 5.5441 7 Al+++ 0.1103922E-28 0.5272866E-05 0.1420121E+00 0.7609 8 H4SiO4 0.7116355E-03 0.1418954E-01 0.1361363E+04 -3.1477 9 Ca++ 0.1434372E-06 0.2435918E-06 0.9744988E-02 13.1066 10 Mg++ 0.2277637E-10 0.9793888E-10 0.2376777E-05 9.3053 11 Fe++ 0.6230177E-13 0.3788842E-07 0.2112122E-02 6.7428 12 K+ 0.1615888E-03 0.1623653E-03 0.6337308E+01 6.2505 13 Na+ 0.2054364E-01 0.2313514E-01 0.5309088E+03 8.3540 14 Mn++ 0.1995688E-10 0.2631446E-08 0.1443045E-03 9.2488 15 HPO4-- 0.4870908E-07 0.4995956E-07 0.4786383E-02 12.6408 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3245466E+02 -.1852379E-01 -.3243614E+02 0.0000000E+00 2 H2O 0.3093886E+02 0.4448659E+02 -.1354773E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5434376E-01 -.1441407E-04 0.5435817E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5431825E-01 0.3991854E-04 -.5435817E-01 0.0000000E+00 7 Al+++ 0.6391050E+01 0.4226183E-05 0.6391046E+01 0.0000000E+00 8 H4SiO4 0.2040904E+02 0.1137286E-01 0.2039767E+02 0.0000000E+00 9 Ca++ 0.2254293E+01 0.1952379E-06 0.2254293E+01 0.0000000E+00 10 Mg++ 0.1555555E+01 0.7849765E-10 0.1555555E+01 0.0000000E+00 11 Fe++ 0.1397496E+01 0.3036743E-07 0.1397496E+01 0.0000000E+00 12 K+ 0.4161357E+00 0.1301352E-03 0.4160055E+00 0.0000000E+00 13 Na+ 0.2460436E+01 0.1854273E-01 0.2441894E+01 0.0000000E+00 14 Mn++ 0.3398363E-01 0.2109094E-08 0.3398363E-01 0.0000000E+00 15 HPO4-- 0.1159844E-01 0.4004240E-07 0.1159840E-01 0.0000000E+00 Chg. balance for solid moles: -.6842E-14 Mass of aqueous solution: 0.802951E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1959.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.440 0.387 639.9 2.806 29.88 245.6 andradite 0.2174 -0.663 110.5 2.043 5.160 28.71 grossular 0.5192E-01 -1.285 23.39 1.369 1.092 6.507 apatite-OH 0.3866E-02 -2.413 1.942 0.288 0.9070E-01 0.6171 clinochlore 0.2801 -0.553 155.7 2.192 7.271 59.22 daphnite 0.8027E-01 -1.095 57.28 1.758 2.675 17.36 chlorite-Mn 0.6797E-02 -2.168 4.819 0.683 0.2250 1.536 diopside 0.1039 -0.983 22.50 1.352 1.051 6.875 hedenbergite 0.2661E-01 -1.575 6.603 0.820 0.3084 1.808 microcline 0.3643 -0.439 101.4 2.006 4.736 39.61 stilbite 1.268 0.103 893.7 2.951 41.74 416.8 stilpnomelane-Fe 0.1034 -0.985 111.5 2.047 5.206 38.50 tr.625ac.25prg.125 0.1412E-01 -1.850 12.07 1.082 0.5637 3.885 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1851E-01 0.1851E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2141.193973 g Volume = 867.087026 cm3 Porosity: -10.4570% V(tot) - V(min): -.82087E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1959.9990000 g log = 3.2923 Original solution: 1000.0103000 g Original solution / Rock added: 0.51 (Water/Rock Ratio), log = -0.2923 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0911 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9646E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4686E-08 1.0071 0.5149E-08 0.5113E-08 CH4,gas 0.2175E-01 1.0128 0.2404E-01 0.2374E-01 H2,gas 0.1366E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1622E-06 0.9958 0.1762E-06 0.1770E-06 S2,gas 0.4795E-29 1.0000 0.5232E-29 0.5232E-29 CO,gas 0.1823E-13 1.0000 0.1989E-13 0.1989E-13 SO3,gas 0.9923E-48 1.0000 0.1083E-47 0.1083E-47 SO2,gas 0.5597E-27 1.0000 0.6107E-27 0.6107E-27 HCl,gas 0.3296E-17 1.0000 0.3596E-17 0.3596E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.65 -10.29 -3.429 0.17567E+05 -8.288 3 CH4,gas 4.81 1.19 -3.62 -0.905 0.61795E+04 -1.619 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.70 -8.75 -4.377 0.14947E+05 -6.754 6 S2,gas -7.03 -38.31 -31.28 -4.813 0.53412E+05 -29.281 7 CO,gas 3.51 -12.19 -15.70 -4.831 0.26810E+05 -13.701 8 SO3,gas 17.43 -32.54 -49.97 -12.491 0.85315E+05 -47.965 9 SO2,gas 1.14 -28.08 -29.21 -7.790 0.49882E+05 -27.214 10 HCl,gas 5.48 -13.97 -19.44 -9.722 0.33200E+05 -17.444 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.72 -0.236 0.80677E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94126E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76236E+04 35 aragonite 0.99 -3.54 -4.53 -1.510 0.77368E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.54 -4.38 -1.459 0.74755E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65573E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.73 -4.62 -1.321 0.78943E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66055E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.73 -4.18 -1.195 0.71405E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82286E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61285E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53669E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92773E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40697E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43446E+04 143 pyrrhotite -4.24 -7.95 -3.71 -1.237 0.63351E+04 144 pyrrhotiteFe0.875 -6.00 -9.35 -3.35 -1.232 0.57178E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22453E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28300E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23245E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47178E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91029E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.95 -3.56 -1.187 0.60782E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80427E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66781E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60332E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.45 -4.49 -1.495 0.76587E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1959.9990000 g New total amount of reactant added: 1999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1999.9990000 Water: Moles liquid = 0.4427E+02 kg liquid = 0.7975E+00 Moles total = 0.3044E+02 kg total = 0.5483E+00 Activity = 1.0000 Stoichiometric ionic strength = .1175785E-01 Osmotic coef. = 0.9687 True ionic strength = .2070707E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90356E-10 -10.0440 0.75801E-10 -10.1203 0.83891E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17221E-03 -3.7639 0.14358E-03 -3.8429 0.83376E+00 -0.0790 4 SO4-- 0.98214E-12 -12.0078 0.50659E-12 -12.2953 0.51581E+00 -0.2875 5 HCO3- 0.35428E-06 -6.4506 0.29583E-06 -6.5290 0.83500E+00 -0.0783 6 HS- 0.31975E-04 -4.4952 0.26664E-04 -4.5741 0.83388E+00 -0.0789 7 Al+++ 0.11040E-28 -28.9570 0.25114E-29 -29.6001 0.22747E+00 -0.6431 8 H4SiO4 0.71164E-03 -3.1477 0.71164E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14345E-06 -6.8433 0.73435E-07 -7.1341 0.51193E+00 -0.2908 10 Mg++ 0.22778E-10 -10.6425 0.11606E-10 -10.9353 0.50954E+00 -0.2928 11 Fe++ 0.62305E-13 -13.2055 0.31783E-13 -13.4978 0.51011E+00 -0.2923 12 K+ 0.16159E-03 -3.7916 0.13496E-03 -3.8698 0.83520E+00 -0.0782 13 Na+ 0.20544E-01 -1.6873 0.17126E-01 -1.7664 0.83360E+00 -0.0790 14 Mn++ 0.19960E-10 -10.6998 0.10190E-10 -10.9918 0.51055E+00 -0.2920 15 HPO4-- 0.48707E-07 -7.3124 0.25127E-07 -7.5999 0.51588E+00 -0.2875 16 HSiO3- 0.10986E-01 -1.9592 0.91598E-02 -2.0381 0.83376E+00 -0.0790 17 Ca(HSiO3)+ 0.18041E-07 -7.7437 0.15071E-07 -7.8219 0.83538E+00 -0.0781 18 Mg(HSiO3)+ 0.35485E-11 -11.4500 0.29643E-11 -11.5281 0.83538E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67545E-16 -16.1704 0.56425E-16 -16.2485 0.83538E+00 -0.0781 22 HAlO2,aq 0.14896E-09 -9.8269 0.14896E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52726E-05 -5.2780 0.43880E-05 -5.3577 0.83223E+00 -0.0798 24 CH4,aq 0.15333E-04 -4.8144 0.15278E-04 -4.8159 0.99642E+00 -0.0016 25 C2H6,aq 0.37165E-14 -14.4299 0.37032E-14 -14.4314 0.99642E+00 -0.0016 29 CO,aq 0.12658E-16 -16.8976 0.12658E-16 -16.8976 0.10000E+01 0.0000 30 CO2,aq 0.45374E-10 -10.3432 0.45211E-10 -10.3448 0.99642E+00 -0.0016 31 CO3-2 0.70109E-06 -6.1542 0.36084E-06 -6.4427 0.51469E+00 -0.2885 32 CaCO3,aq 0.32454E-09 -9.4887 0.32454E-09 -9.4887 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.65524E-12 -12.1836 0.54738E-12 -12.2617 0.83538E+00 -0.0781 34 CaCl+ 0.20112E-10 -10.6965 0.16801E-10 -10.7747 0.83538E+00 -0.0781 35 CaCl2,aq 0.56169E-15 -15.2505 0.56169E-15 -15.2505 0.10000E+01 0.0000 36 CaOH+ 0.81773E-07 -7.0874 0.68312E-07 -7.1655 0.83538E+00 -0.0781 37 CaSO4,aq 0.11591E-16 -16.9359 0.11591E-16 -16.9359 0.10000E+01 0.0000 38 HCl,aq 0.20472E-14 -14.6888 0.20472E-14 -14.6888 0.10000E+01 0.0000 43 FeCl+ 0.85082E-17 -17.0702 0.71076E-17 -17.1483 0.83538E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16640E-10 -10.7789 0.13901E-10 -10.8570 0.83538E+00 -0.0781 48 HFeO2- 0.37228E-07 -7.4291 0.31039E-07 -7.5081 0.83376E+00 -0.0790 49 FeO+ 0.12282E-16 -16.9107 0.10260E-16 -16.9889 0.83538E+00 -0.0781 51 FeO2- 0.42092E-09 -9.3758 0.35095E-09 -9.4548 0.83376E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4777 0.33293E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.34312E-09 -9.4646 0.34312E-09 -9.4646 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.12634E-14 -14.8985 0.10534E-14 -14.9774 0.83376E+00 -0.0790 58 MgCO3,aq 0.12817E-13 -13.8922 0.12817E-13 -13.8922 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10560E-15 -15.9763 0.88219E-16 -16.0544 0.83538E+00 -0.0781 60 MgCl+ 0.28857E-14 -14.5397 0.24107E-14 -14.6179 0.83538E+00 -0.0781 61 MgOH+ 0.71600E-10 -10.1451 0.59814E-10 -10.2232 0.83538E+00 -0.0781 63 MnO,aq 0.18722E-08 -8.7276 0.18722E-08 -8.7276 0.10000E+01 0.0000 64 MnOH+ 0.49562E-09 -9.3048 0.41403E-09 -9.3830 0.83538E+00 -0.0781 65 MnO2-2 0.21895E-10 -10.6597 0.11269E-10 -10.9481 0.51469E+00 -0.2885 66 HMnO2- 0.22197E-09 -9.6537 0.18507E-09 -9.7327 0.83376E+00 -0.0790 69 MnCl+ 0.10600E-13 -13.9747 0.88554E-14 -14.0528 0.83538E+00 -0.0781 71 NaCl,aq 0.80290E-06 -6.0953 0.80290E-06 -6.0953 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95086E-02 -2.0219 0.79133E-02 -2.1016 0.83223E+00 -0.0798 79 HPO3-2 0.16763E-14 -14.7757 0.86276E-15 -15.0641 0.51469E+00 -0.2885 81 H2PO3- 0.15408E-18 -18.8123 0.12846E-18 -18.8912 0.83376E+00 -0.0790 82 H3PO4,aq 0.92947E-18 -18.0318 0.92947E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40012E-10 -10.3978 0.33392E-10 -10.4764 0.83456E+00 -0.0785 84 PO4-3 0.12104E-08 -8.9171 0.28949E-09 -9.5384 0.23917E+00 -0.6213 88 HP2O7-3 0.10367E-17 -17.9843 0.23608E-18 -18.6269 0.22771E+00 -0.6426 89 P2O7-4 0.10236E-16 -16.9899 0.76833E-18 -18.1145 0.75059E-01 -1.1246 90 H2S,aq 0.60944E-08 -8.2151 0.60726E-08 -8.2166 0.99642E+00 -0.0016 91 S2-2 0.27947E-14 -14.5537 0.14384E-14 -14.8421 0.51469E+00 -0.2885 97 SO3-2 0.14377E-17 -17.8423 0.75088E-18 -18.1244 0.52229E+00 -0.2821 99 HSO4- 0.42609E-19 -19.3705 0.35630E-19 -19.4482 0.83621E+00 -0.0777 Charge balance for all species = 0.4135E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9035615E-10 -.2311104E-01 -.2325235E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981175E+06 0.0000 3 Cl- 0.1722100E-03 0.1730132E-03 0.6122727E+01 6.2774 4 SO4-- 0.9821406E-12 -.1806085E-04 -.1731811E+01 7.9453 5 HCO3- 0.3542837E-06 0.1638917E-04 0.9982100E+00 3.5914 6 HS- 0.3197533E-04 0.5004227E-04 0.1652000E+01 5.5462 7 Al+++ 0.1104021E-28 0.5272724E-05 0.1420083E+00 0.7609 8 H4SiO4 0.7116363E-03 0.1418930E-01 0.1361340E+04 -3.1477 9 Ca++ 0.1434454E-06 0.2436043E-06 0.9745488E-02 13.1066 10 Mg++ 0.2277767E-10 0.9794182E-10 0.2376848E-05 9.3053 11 Fe++ 0.6230537E-13 0.3788751E-07 0.2112071E-02 6.7428 12 K+ 0.1615932E-03 0.1623697E-03 0.6337479E+01 6.2505 13 Na+ 0.2054420E-01 0.2313571E-01 0.5309218E+03 8.3540 14 Mn++ 0.1995993E-10 0.2631704E-08 0.1443186E-03 9.2488 15 HPO4-- 0.4870705E-07 0.4995746E-07 0.4786182E-02 12.6408 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3311700E+02 -.1843054E-01 -.3309857E+02 0.0000000E+00 2 H2O 0.3043744E+02 0.4426353E+02 -.1382609E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5545229E-01 -.1440312E-04 0.5546670E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5542679E-01 0.3990759E-04 -.5546670E-01 0.0000000E+00 7 Al+++ 0.6521480E+01 0.4204880E-05 0.6521476E+01 0.0000000E+00 8 H4SiO4 0.2082556E+02 0.1131565E-01 0.2081424E+02 0.0000000E+00 9 Ca++ 0.2300299E+01 0.1942690E-06 0.2300298E+01 0.0000000E+00 10 Mg++ 0.1587301E+01 0.7810641E-10 0.1587301E+01 0.0000000E+00 11 Fe++ 0.1426016E+01 0.3021445E-07 0.1426016E+01 0.0000000E+00 12 K+ 0.4246282E+00 0.1294862E-03 0.4244988E+00 0.0000000E+00 13 Na+ 0.2510646E+01 0.1845021E-01 0.2492196E+01 0.0000000E+00 14 Mn++ 0.3467717E-01 0.2098725E-08 0.3467717E-01 0.0000000E+00 15 HPO4-- 0.1183515E-01 0.3983996E-07 0.1183511E-01 0.0000000E+00 Chg. balance for solid moles: -.1631E-14 Mass of aqueous solution: 0.798925E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.490 0.396 653.0 2.815 29.89 250.7 andradite 0.2219 -0.654 112.7 2.052 5.160 29.29 grossular 0.5298E-01 -1.276 23.86 1.378 1.092 6.640 apatite-OH 0.3945E-02 -2.404 1.982 0.297 0.9070E-01 0.6297 clinochlore 0.2858 -0.544 158.8 2.201 7.270 60.42 daphnite 0.8190E-01 -1.087 58.44 1.767 2.675 17.71 chlorite-Mn 0.6935E-02 -2.159 4.917 0.692 0.2250 1.567 diopside 0.1062 -0.974 23.00 1.362 1.053 7.029 hedenbergite 0.2721E-01 -1.565 6.750 0.829 0.3089 1.849 microcline 0.3717 -0.430 103.5 2.015 4.736 40.42 stilbite 1.294 0.112 911.8 2.960 41.73 425.3 stilpnomelane-Fe 0.1055 -0.977 113.7 2.056 5.206 39.29 tr.625ac.25prg.125 0.1439E-01 -1.842 12.30 1.090 0.5631 3.960 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1851E-01 0.1851E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2184.896166 g Volume = 884.769569 cm3 Porosity: -10.4582% V(tot) - V(min): -.83770E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1999.9990000 g log = 3.3010 Original solution: 1000.0103000 g Original solution / Rock added: 0.50 (Water/Rock Ratio), log = -0.3010 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0913 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9645E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4709E-08 1.0071 0.5175E-08 0.5139E-08 CH4,gas 0.2186E-01 1.0128 0.2416E-01 0.2386E-01 H2,gas 0.1366E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1630E-06 0.9958 0.1771E-06 0.1779E-06 S2,gas 0.4843E-29 1.0000 0.5285E-29 0.5285E-29 CO,gas 0.1832E-13 1.0000 0.1999E-13 0.1999E-13 SO3,gas 0.9972E-48 1.0000 0.1088E-47 0.1088E-47 SO2,gas 0.5625E-27 1.0000 0.6138E-27 0.6138E-27 HCl,gas 0.3312E-17 1.0000 0.3615E-17 0.3615E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.65 -10.29 -3.429 0.17563E+05 -8.286 3 CH4,gas 4.81 1.19 -3.62 -0.904 0.61757E+04 -1.617 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.69 -8.75 -4.376 0.14943E+05 -6.752 6 S2,gas -7.03 -38.31 -31.28 -4.812 0.53405E+05 -29.277 7 CO,gas 3.51 -12.19 -15.70 -4.831 0.26806E+05 -13.699 8 SO3,gas 17.43 -32.54 -49.96 -12.491 0.85311E+05 -47.963 9 SO2,gas 1.14 -28.08 -29.21 -7.790 0.49879E+05 -27.212 10 HCl,gas 5.48 -13.96 -19.44 -9.721 0.33197E+05 -17.442 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80675E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94126E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76236E+04 35 aragonite 0.99 -3.54 -4.53 -1.510 0.77331E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.54 -4.38 -1.459 0.74717E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65572E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.73 -4.62 -1.320 0.78906E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66055E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.73 -4.18 -1.194 0.71367E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82285E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61285E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53669E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92773E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40697E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43446E+04 143 pyrrhotite -4.24 -7.95 -3.71 -1.236 0.63313E+04 144 pyrrhotiteFe0.875 -6.00 -9.35 -3.35 -1.231 0.57141E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22452E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28300E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23244E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47177E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91029E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.95 -3.56 -1.186 0.60745E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80427E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66781E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60332E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.45 -4.48 -1.494 0.76549E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 40.0000000 g Current total amount of reactant added: 1999.9990000 g New total amount of reactant added: 2039.9990000 g Mixing fraction reached given limit of 0.2000E+04 TOTMIX = 0.2040E+04 Execution stopped.