File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.13247E+02 0.90291E-10 0.8389 0.00000000E+00 H2O 2 0. 0.45480E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.14960E-03 0.8338 0.00000000E+00 SO4-- 4 -2. 0.22196E-01 0.85296E-12 0.5159 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.30771E-06 0.8350 0.00000000E+00 HS- 6 -1. -0.22171E-01 0.27776E-04 0.8339 0.00000000E+00 Al+++ 7 3. 0.26086E+01 0.11016E-28 0.2276 0.00000000E+00 H4SiO4 8 0. 0.83302E+01 0.71158E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.92013E+00 0.14323E-06 0.5120 0.00000000E+00 Mg++ 10 2. 0.63492E+00 0.22744E-10 0.5096 0.00000000E+00 Fe++ 11 2. 0.57041E+00 0.62211E-13 0.5102 0.00000000E+00 K+ 12 1. 0.16985E+00 0.16148E-03 0.8352 0.00000000E+00 Na+ 13 1. 0.10044E+01 0.20529E-01 0.8336 0.00000000E+00 Mn++ 14 2. 0.13871E-01 0.19791E-10 0.5106 0.00000000E+00 HPO4-- 15 -2. 0.47341E-02 0.48757E-07 0.5160 0.00000000E+00 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 100.0000 SLIM = 0.400000E+04 TEMP = 100.0000 SINC = 0.1000E+03 TEMPC = 0.0000 TOTMIX = 0.799999E+03 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 320.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0107 MnO2-2 65 -2. 40.4376 Ca(HSiO3)+ 17 1. 7.6603 HMnO2- 66 -1. 29.1018 Mg(HSiO3)+ 18 1. 7.5653 MnO4- 67 -1. 83.3383 NaHSiO3,aq 19 0. 7.8098 MnO4-2 68 -2. 81.3024 AlO+ 20 1. 6.8891 MnCl+ 69 1. -0.7819 AlOH+2 21 2. 3.1893 MnSO4,aq 70 0. -2.4524 HAlO2,aq 22 0. 10.5878 NaCl,aq 71 0. 0.4861 AlO2- 23 -1. 16.2390 NaOH,aq 72 0. 12.3571 CH4,aq 24 0. 6.0082 O2,aq 73 0. 53.5759 C2H6,aq 25 0. 12.3556 OH- 74 -1. 12.2220 C3H8,aq 26 0. 17.3423 HO2- 75 -1. 50.7897 C4H10,aq 27 0. 22.3397 H2O2,aq 76 0. 40.0297 ethanol,aq 28 0. 15.3114 H3PO2,aq 77 0. 24.3310 CO,aq 29 0. 4.7087 H2PO2- 78 -1. 26.5491 CO2,aq 30 0. -6.3045 HPO3-2 79 -2. 11.9246 CO3-2 31 -2. 10.0340 H3PO3,aq 80 0. 3.5932 CaCO3,aq 32 0. 5.9460 H2PO3- 81 -1. 5.6314 Ca(HCO3)+ 33 1. -1.4013 H3PO4,aq 82 0. -9.8087 CaCl+ 34 1. -0.2023 H2PO4- 83 -1. -7.2438 CaCl2,aq 35 0. 0.4306 PO4-3 84 -3. 12.0588 CaOH+ 36 1. 10.1517 H4P2O7,aq 85 0. -17.7539 CaSO4,aq 37 0. -2.4936 H3P2O7- 86 -1. -15.8646 HCl,aq 38 0. 0.7256 H2P2O7-2 87 -2. -13.3812 HClO,aq 39 0. 32.4377 HP2O7-3 88 -3. -6.6931 ClO- 40 -1. 39.6416 P2O7-4 89 -4. 2.9147 HClO2,aq 41 0. 70.2060 H2S,aq 90 0. -6.4778 Fe+3 42 3. 8.3763 S2-2 91 -2. 1.2336 FeCl+ 43 1. -0.1924 S3-2 92 -2. -8.7963 FeCl2,aq 44 0. 4.3160 S3- 93 -1. -16.3178 FeCl+2 45 2. 6.5223 S4-2 94 -2. -18.6473 FeO,aq 46 0. 16.4029 S5-2 95 -2. -28.3223 FeOH+ 47 1. 7.4795 SO2,aq 96 0. -0.1980 HFeO2- 48 -1. 24.3713 SO3-2 97 -2. 10.2895 FeO+ 49 1. 11.3812 HSO3- 98 -1. 2.5222 FeOH+2 50 2. 9.1115 HSO4- 99 -1. -2.9675 FeO2- 51 -1. 24.0877 HSO5- 100 -1. 38.8657 HFeO2,aq 52 0. 15.9903 S2O3-2 101 -2. -4.5491 H2,aq 53 0. 9.4241 HS2O3- 102 -1. -6.8007 KCl,aq 54 0. 1.7519 H2S2O3,aq 103 0. -7.9944 KHSO4,aq 55 0. -0.4275 S2O4-2 104 -2. 10.5639 KOH,aq 56 0. 12.3606 HS2O4- 105 -1. 7.6762 KSO4- 57 -1. -1.1877 H2S2O4,aq 106 0. 6.6566 MgCO3,aq 58 0. 6.5483 S2O5-2 107 -2. 10.0891 Mg(HCO3)+ 59 1. -1.4098 S2O6-2 108 -2. 11.5737 MgCl+ 60 1. -0.1603 S2O8-2 109 -2. 42.1139 MgOH+ 61 1. 9.4082 S3O6-2 110 -2. 3.8101 Mn+3 62 3. 19.1332 S4O6-2 111 -2. -17.8301 MnO,aq 63 0. 17.9765 S5O6-2 112 -2. -14.1051 MnOH+ 64 1. 8.5115 113 0. 10.3157 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.984 0.0000E+00 osumilite(2) 124 20.895 0.0000E+00 CO2,gas 2 -6.363 0.0000E+00 osumilite-Fe 125 14.657 0.0000E+00 CH4,gas 3 4.809 0.0000E+00 pargasite 126 65.279 0.0000E+00 H2,gas 4 8.287 0.0000E+00 periclase 127 16.149 0.0000E+00 H2S,gas 5 -5.943 0.0000E+00 periclase-Fe 128 11.639 0.0000E+00 S2,gas 6 -7.033 0.0000E+00 perovskite-Al 129 12.395 0.0000E+00 CO,gas 7 3.510 0.0000E+00 perovskite-Ca 130 23.818 0.0000E+00 SO3,gas 8 17.427 0.0000E+00 perovskite-Fe 131 21.158 0.0000E+00 SO2,gas 9 1.136 0.0000E+00 perovskite-Mg 132 23.132 0.0000E+00 HCl,gas 10 5.479 0.0000E+00 phase_A 133 80.267 0.0000E+00 acmite 11 7.737 0.0000E+00 phlogopite-Na 134 29.731 0.0000E+00 akermanite 12 36.495 0.0000E+00 piemontite(ordered) 135 33.876 0.0000E+00 akimotoite 13 16.606 0.0000E+00 prehnite 136 19.466 0.0000E+00 akimotoite-Fe 14 13.083 0.0000E+00 prehnite-Fe 137 22.587 0.0000E+00 albite-high 15 0.750 0.0000E+00 pumpellyite-Fe 138 46.471 0.0000E+00 albite 16 -0.328 0.9824E+00 pumpellyite-Mg 139 49.194 0.0000E+00 almandine 17 24.545 0.0000E+00 px-Mg-tschermaks 140 19.687 0.0000E+00 pyrope 18 37.348 0.0000E+00 px-Ca-tschermaks 141 18.679 0.0000E+00 spessartine 19 24.550 0.0000E+00 pyrite 142 -21.225 0.0000E+00 analcite 20 3.371 0.0000E+00 pyrrhotite 143 -4.244 0.0000E+00 andalusite 21 5.062 0.0000E+00 pyrrhotiteFe0.875 144 -6.001 0.0000E+00 andradite 22 39.088 0.8884E-01 pyroxmangite 145 7.416 0.0000E+00 grossular 23 32.828 0.2122E-01 pyrophyllite 146 -6.098 0.0000E+00 anhydrite 24 -5.280 0.0000E+00 quartz 147 -2.982 0.0000E+00 ankerite 25 -2.093 0.0000E+00 rankinite 148 40.765 0.0000E+00 annite 26 20.209 0.0000E+00 ringwoodite-Fe 149 15.486 0.0000E+00 phlogopite 27 27.147 0.0000E+00 ringwoodite-Mg 150 27.602 0.0000E+00 biotite-Mn 28 33.034 0.0000E+00 rhodochrosite 151 -0.959 0.0000E+00 anorthite 29 12.798 0.0000E+00 rhodonite 152 7.462 0.0000E+00 anthophyllite 30 51.988 0.0000E+00 sanidine 153 -1.221 0.0000E+00 anthophyllite-Fe 31 29.455 0.0000E+00 sapphirine(351) 154 79.204 0.0000E+00 apatite-OH 32 -17.989 0.1578E-02 siderite 155 -2.588 0.0000E+00 apatite-OH-zs 33 -12.572 0.0000E+00 sillimanite 156 5.321 0.0000E+00 apatite-Cl-zs 34 -16.504 0.0000E+00 sodalite 157 50.255 0.0000E+00 aragonite 35 0.986 0.0000E+00 spinel 158 20.934 0.0000E+00 brucite 36 12.577 0.0000E+00 spurrite 159 59.566 0.0000E+00 calcite 37 0.833 0.0000E+00 staurolite-Fe 160 74.138 0.0000E+00 carnegieite-low 38 9.065 0.0000E+00 staurolite-Mg 161 90.336 0.0000E+00 carnegieite-high 39 10.134 0.0000E+00 staurolite-Mn 162 84.438 0.0000E+00 carpholite-Mg 40 8.650 0.0000E+00 stilbite 163 -7.406 0.5234E+00 carpholite-Fe 41 6.783 0.0000E+00 stilpnomelane-Fe 164 13.179 0.4211E-01 celadonite 42 5.401 0.0000E+00 stilpnomelane-Mg 165 27.596 0.0000E+00 celadonite-Fe 43 3.937 0.0000E+00 stishovite 166 2.721 0.0000E+00 chrysotile 44 23.937 0.0000E+00 sudoite-Fe 167 18.437 0.0000E+00 chondrodite 45 56.542 0.0000E+00 sudoite 168 21.216 0.0000E+00 clinochlore 46 39.193 0.1151E+00 sulfur 169 -9.141 0.0000E+00 daphnite 47 29.094 0.3299E-01 sylvite 170 1.345 0.0000E+00 chlorite-Mn 48 46.985 0.2774E-02 talc 171 16.553 0.0000E+00 chlorite-Al-free 49 47.262 0.0000E+00 talc-Fe 172 13.516 0.0000E+00 chloritoid-Mg 50 13.261 0.0000E+00 talc-tschermaks 173 19.189 0.0000E+00 chloritoid-Fe 51 9.239 0.0000E+00 tephroite 174 18.113 0.0000E+00 chloritoid-Mn 52 11.463 0.0000E+00 tilleyite 175 41.473 0.0000E+00 clinohumite 53 97.255 0.0000E+00 titanite-CaSi 176 15.497 0.0000E+00 coesite 54 -2.369 0.0000E+00 topaz-H 177 4.668 0.0000E+00 cordierite-H 55 23.898 0.0000E+00 tridymite 178 -2.615 0.0000E+00 cordierite 56 24.245 0.0000E+00 tremolite 179 48.003 0.0000E+00 cordierite-Fe 57 20.649 0.0000E+00 ferroactinolite 180 38.596 0.0000E+00 cordierite-Mn 58 25.261 0.0000E+00 troilite-low 181 -4.394 0.0000E+00 corundum 59 8.433 0.0000E+00 tschermakite 182 48.414 0.0000E+00 corundum-MgSi 60 18.905 0.0000E+00 vesuvianite 183 224.056 0.0000E+00 cristobalite 61 -2.549 0.0000E+00 wadeite-Si 184 20.233 0.0000E+00 cummingtonite 62 52.233 0.0000E+00 wadsleyite-Fe 185 15.711 0.0000E+00 cymrite-K 63 1.731 0.0000E+00 wadsleyite-Mg 186 25.878 0.0000E+00 deerite 64 95.982 0.0000E+00 wairakite 187 4.058 0.0000E+00 diaspore 65 2.896 0.0000E+00 walstromite 188 11.528 0.0000E+00 diamond 66 -3.107 0.0000E+00 wollastonite 189 10.482 0.0000E+00 diopside 67 16.215 0.3678E-01 pseudo-wollastonite 190 11.020 0.0000E+00 hedenbergite 68 14.244 0.9423E-02 zoisite 191 22.964 0.0000E+00 dolomite,ordered 69 0.587 0.0000E+00 akaganeite 192 7.768 0.0000E+00 eastonite 70 28.605 0.0000E+00 beidellite-Ca 193 -1.560 0.0000E+00 enstatite 71 17.301 0.0000E+00 beidellite-H 194 -2.241 0.0000E+00 clinoenstatite-HiP 72 18.388 0.0000E+00 beidellite-K 195 -1.435 0.0000E+00 clinoenstatite 73 17.202 0.0000E+00 beidellite-Mg 196 -1.707 0.0000E+00 protoenstatite 74 17.860 0.0000E+00 beidellite-Na 197 -1.257 0.0000E+00 epidote 75 24.775 0.0000E+00 calcium 198 84.043 0.0000E+00 clinozoisite 76 22.921 0.0000E+00 chalcedony 199 -2.794 0.0000E+00 epidote-Fe 77 29.937 0.0000E+00 dawsonite 200 1.714 0.0000E+00 fayalite 78 14.079 0.0000E+00 montmorillonite-Ca 201 -2.214 0.0000E+00 ferrosilite 79 11.188 0.0000E+00 montmorillonite-K 202 -2.161 0.0000E+00 forsterite 80 21.047 0.0000E+00 montmorillonite-Mg 203 -2.402 0.0000E+00 gedrite 81 50.725 0.0000E+00 montmorillonite-Na 204 -1.961 0.0000E+00 gehlenite 82 36.717 0.0000E+00 nontronite-Ca 205 3.280 0.0000E+00 gibbsite 83 4.097 0.0000E+00 nontronite-H 206 2.596 0.0000E+00 glaucophane 84 23.111 0.0000E+00 nontronite-K 207 3.404 0.0000E+00 glaucophane-Fe 85 17.417 0.0000E+00 nontronite-Mg 208 3.139 0.0000E+00 graphite 86 -3.549 0.0000E+00 nontronite-Na 209 3.583 0.0000E+00 greenalite 87 16.194 0.0000E+00 sepiolite 210 24.194 0.0000E+00 grunerite 88 31.364 0.0000E+00 alite 211 58.043 0.0000E+00 halite 89 1.582 0.0000E+00 belite 212 30.461 0.0000E+00 hematite 90 12.598 0.0000E+00 ettringite 213 43.354 0.0000E+00 heulandite 91 -5.707 0.0000E+00 gypsum 214 -4.924 0.0000E+00 hercynite 92 17.345 0.0000E+00 hemicarboaluminate 215 71.028 0.0000E+00 hollandite 93 25.702 0.0000E+00 hydrogarnet 216 60.721 0.0000E+00 iron 94 19.095 0.0000E+00 hydrogarnet-Si 217 50.654 0.0000E+00 jadeite 95 4.251 0.0000E+00 jennite 218 24.386 0.0000E+00 julgoldite 96 70.573 0.0000E+00 monosulfoaluminate 219 53.497 0.0000E+00 kalsilite 97 7.620 0.0000E+00 monocarboaluminate 220 61.966 0.0000E+00 kaolinite 98 -1.273 0.0000E+00 portlandite 221 18.282 0.0000E+00 kyanite 99 4.932 0.0000E+00 stratlingite 222 36.573 0.0000E+00 larnite-bredigite 100 30.714 0.0000E+00 tricarboaluminate 223 70.427 0.0000E+00 laumontite 101 2.975 0.0000E+00 tobermorite 224 9.839 0.0000E+00 lawsonite 102 9.678 0.0000E+00 C4AH13 225 81.870 0.0000E+00 leucite 103 4.168 0.0000E+00 C2AH8 226 45.260 0.0000E+00 lime 104 26.009 0.0000E+00 C3A 227 87.049 0.0000E+00 lizardite 105 23.287 0.0000E+00 C4AF 228 117.550 0.0000E+00 magnesite 106 0.709 0.0000E+00 CAH10 229 28.373 0.0000E+00 magnetite 107 20.133 0.0000E+00 alabandite 230 -0.962 0.0000E+00 minnesotaite 108 10.461 0.0000E+00 alunite 231 -10.224 0.0000E+00 minnesotaite-Mg 109 20.669 0.0000E+00 artinite 232 15.139 0.0000E+00 magnesioferrite 110 26.257 0.0000E+00 boehmite 233 4.430 0.0000E+00 majorite 111 53.314 0.0000E+00 dolomite,disordered 234 1.288 0.0000E+00 manganosite 112 14.068 0.0000E+00 ferrous-oxide 235 9.824 0.0000E+00 margarite 113 17.452 0.0000E+00 huntite 236 3.850 0.0000E+00 meionite 114 45.158 0.0000E+00 hydromagnesite 237 20.077 0.0000E+00 merwinite 115 55.988 0.0000E+00 nesquehonite 238 4.735 0.0000E+00 microcline 116 -2.432 0.1486E+00 potassium-oxide 239 69.039 0.0000E+00 monticellite 117 24.371 0.0000E+00 silica-amorphous 240 -2.080 0.0000E+00 mullite-Al 118 363.258 0.0000E+00 sodium-oxide 241 55.173 0.0000E+00 mullite-Si 119 7.324 0.0000E+00 an20ab80 242 2.079 0.0000E+00 muscovite 120 2.679 0.0000E+00 an25ab75 243 2.709 0.0000E+00 paragonite 121 4.337 0.0000E+00 an30ab70 244 3.344 0.0000E+00 nepheline 122 8.378 0.0000E+00 tr.625ac.25prg.125 245 45.308 0.6215E-02 osumilite(1) 123 21.978 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 799.9990000 g log = 2.9031 Original solution: 1000.0103000 g Original solution / Rock added: 1.25 (Water/Rock Ratio), log = 0.0969 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 799.9990000 Water: Moles liquid = 0.5096E+02 kg liquid = 0.9180E+00 Moles total = 0.4548E+02 kg total = 0.8193E+00 Activity = 1.0000 Stoichiometric ionic strength = .1173867E-01 Osmotic coef. = 0.9689 True ionic strength = .2069192E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90291E-10 -10.0444 0.75749E-10 -10.1206 0.83895E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14960E-03 -3.8251 0.12473E-03 -3.9040 0.83380E+00 -0.0789 4 SO4-- 0.85296E-12 -12.0691 0.44005E-12 -12.3565 0.51590E+00 -0.2874 5 HCO3- 0.30771E-06 -6.5119 0.25695E-06 -6.5901 0.83504E+00 -0.0783 6 HS- 0.27776E-04 -4.5563 0.23163E-04 -4.6352 0.83392E+00 -0.0789 7 Al+++ 0.11016E-28 -28.9580 0.25069E-29 -29.6009 0.22757E+00 -0.6429 8 H4SiO4 0.71158E-03 -3.1478 0.71158E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14323E-06 -6.8440 0.73341E-07 -7.1347 0.51203E+00 -0.2907 10 Mg++ 0.22744E-10 -10.6431 0.11592E-10 -10.9359 0.50965E+00 -0.2927 11 Fe++ 0.62211E-13 -13.2061 0.31741E-13 -13.4984 0.51022E+00 -0.2922 12 K+ 0.16148E-03 -3.7919 0.13487E-03 -3.8701 0.83524E+00 -0.0782 13 Na+ 0.20529E-01 -1.6876 0.17114E-01 -1.7666 0.83364E+00 -0.0790 14 Mn++ 0.19791E-10 -10.7035 0.10106E-10 -10.9954 0.51065E+00 -0.2919 15 HPO4-- 0.48757E-07 -7.3120 0.25158E-07 -7.5993 0.51598E+00 -0.2874 16 HSiO3- 0.10992E-01 -1.9589 0.91653E-02 -2.0379 0.83380E+00 -0.0789 17 Ca(HSiO3)+ 0.18028E-07 -7.7441 0.15061E-07 -7.8222 0.83542E+00 -0.0781 18 Mg(HSiO3)+ 0.35459E-11 -11.4503 0.29624E-11 -11.5284 0.83542E+00 -0.0781 19 NaHSiO3,aq 0.24912E-02 -2.6036 0.24912E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67512E-16 -16.1706 0.56401E-16 -16.2487 0.83542E+00 -0.0781 22 HAlO2,aq 0.14900E-09 -9.8268 0.14900E-09 -9.8268 0.10000E+01 0.0000 23 AlO2- 0.52772E-05 -5.2776 0.43920E-05 -5.3573 0.83227E+00 -0.0797 24 CH4,aq 0.13320E-04 -4.8755 0.13272E-04 -4.8771 0.99642E+00 -0.0016 25 C2H6,aq 0.28039E-14 -14.5522 0.27939E-14 -14.5538 0.99642E+00 -0.0016 29 CO,aq 0.10989E-16 -16.9590 0.10989E-16 -16.9590 0.10000E+01 0.0000 30 CO2,aq 0.39384E-10 -10.4047 0.39243E-10 -10.4062 0.99642E+00 -0.0016 31 CO3-2 0.60925E-06 -6.2152 0.31364E-06 -6.5036 0.51479E+00 -0.2884 32 CaCO3,aq 0.28172E-09 -9.5502 0.28172E-09 -9.5502 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.56839E-12 -12.2454 0.47484E-12 -12.3235 0.83542E+00 -0.0781 34 CaCl+ 0.17449E-10 -10.7582 0.14577E-10 -10.8363 0.83542E+00 -0.0781 35 CaCl2,aq 0.42335E-15 -15.3733 0.42335E-15 -15.3733 0.10000E+01 0.0000 36 CaOH+ 0.81720E-07 -7.0877 0.68271E-07 -7.1658 0.83542E+00 -0.0781 37 CaSO4,aq 0.10056E-16 -16.9976 0.10056E-16 -16.9976 0.10000E+01 0.0000 38 HCl,aq 0.17772E-14 -14.7503 0.17772E-14 -14.7503 0.10000E+01 0.0000 43 FeCl+ 0.73811E-17 -17.1319 0.61663E-17 -17.2100 0.83542E+00 -0.0781 46 FeO,aq 0.21875E-09 -9.6601 0.21875E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16628E-10 -10.7792 0.13892E-10 -10.8572 0.83542E+00 -0.0781 48 HFeO2- 0.37253E-07 -7.4288 0.31061E-07 -7.5078 0.83380E+00 -0.0789 49 FeO+ 0.12272E-16 -16.9111 0.10252E-16 -16.9892 0.83542E+00 -0.0781 51 FeO2- 0.42116E-09 -9.3755 0.35116E-09 -9.4545 0.83380E+00 -0.0789 52 HFeO2,aq 0.33291E-11 -11.4777 0.33291E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10912E-04 -4.9621 0.10873E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.29787E-09 -9.5260 0.29787E-09 -9.5260 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10966E-14 -14.9599 0.91436E-15 -15.0389 0.83380E+00 -0.0789 58 MgCO3,aq 0.11126E-13 -13.9537 0.11126E-13 -13.9537 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.91606E-16 -16.0381 0.76530E-16 -16.1162 0.83542E+00 -0.0781 60 MgCl+ 0.25036E-14 -14.6014 0.20916E-14 -14.6795 0.83542E+00 -0.0781 61 MgOH+ 0.71555E-10 -10.1454 0.59779E-10 -10.2235 0.83542E+00 -0.0781 63 MnO,aq 0.18593E-08 -8.7307 0.18593E-08 -8.7307 0.10000E+01 0.0000 64 MnOH+ 0.49184E-09 -9.3082 0.41089E-09 -9.3863 0.83542E+00 -0.0781 65 MnO2-2 0.21769E-10 -10.6622 0.11206E-10 -10.9505 0.51479E+00 -0.2884 66 HMnO2- 0.22058E-09 -9.6564 0.18392E-09 -9.7354 0.83380E+00 -0.0789 69 MnCl+ 0.91323E-14 -14.0394 0.76293E-14 -14.1175 0.83542E+00 -0.0781 71 NaCl,aq 0.69702E-06 -6.1568 0.69702E-06 -6.1568 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95146E-02 -2.0216 0.79187E-02 -2.1013 0.83227E+00 -0.0797 79 HPO3-2 0.16783E-14 -14.7751 0.86397E-15 -15.0635 0.51479E+00 -0.2884 81 H2PO3- 0.15418E-18 -18.8120 0.12856E-18 -18.8909 0.83380E+00 -0.0789 82 H3PO4,aq 0.92934E-18 -18.0318 0.92934E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40031E-10 -10.3976 0.33410E-10 -10.4761 0.83460E+00 -0.0785 84 PO4-3 0.12122E-08 -8.9164 0.29004E-09 -9.5375 0.23927E+00 -0.6211 88 HP2O7-3 0.10381E-17 -17.9838 0.23649E-18 -18.6262 0.22781E+00 -0.6424 89 P2O7-4 0.10253E-16 -16.9891 0.77020E-18 -18.1134 0.75117E-01 -1.1243 90 H2S,aq 0.52907E-08 -8.2765 0.52718E-08 -8.2780 0.99642E+00 -0.0016 91 S2-2 0.21082E-14 -14.6761 0.10853E-14 -14.9645 0.51479E+00 -0.2884 97 SO3-2 0.12488E-17 -17.9035 0.65237E-18 -18.1855 0.52239E+00 -0.2820 99 HSO4- 0.36985E-19 -19.4320 0.30929E-19 -19.5096 0.83625E+00 -0.0777 Charge balance for all species = 0.3593E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9029068E-10 -.2312275E-01 -.2326414E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981182E+06 0.0000 3 Cl- 0.1495951E-03 0.1502924E-03 0.5318669E+01 6.2166 4 SO4-- 0.8529634E-12 -.1604752E-04 -.1538759E+01 7.8847 5 HCO3- 0.3077126E-06 0.1423688E-04 0.8671217E+00 3.5305 6 HS- 0.2777620E-04 0.4382901E-04 0.1446888E+01 5.4854 7 Al+++ 0.1101562E-28 0.5277348E-05 0.1421329E+00 0.7610 8 H4SiO4 0.7115772E-03 0.1419504E-01 0.1361892E+04 -3.1478 9 Ca++ 0.1432347E-06 0.2432825E-06 0.9732620E-02 13.1066 10 Mg++ 0.2274435E-10 0.9785906E-10 0.2374842E-05 9.3054 11 Fe++ 0.6221054E-13 0.3791243E-07 0.2113462E-02 6.7429 12 K+ 0.1614758E-03 0.1622523E-03 0.6332903E+01 6.2505 13 Na+ 0.2052926E-01 0.2312046E-01 0.5305723E+03 8.3540 14 Mn++ 0.1979106E-10 0.2613276E-08 0.1433082E-03 9.2458 15 HPO4-- 0.4875695E-07 0.5000918E-07 0.4791140E-02 12.6419 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1324678E+02 -.2122756E-01 -.1322556E+02 0.0000000E+00 2 H2O 0.4547993E+02 0.5095517E+02 -.5475240E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2219620E-01 -.1473223E-04 0.2221094E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2217070E-01 0.4023670E-04 -.2221094E-01 0.0000000E+00 7 Al+++ 0.2608590E+01 0.4844807E-05 0.2608585E+01 0.0000000E+00 8 H4SiO4 0.8330216E+01 0.1303159E-01 0.8317184E+01 0.0000000E+00 9 Ca++ 0.9201274E+00 0.2233426E-06 0.9201272E+00 0.0000000E+00 10 Mg++ 0.6349198E+00 0.8983836E-10 0.6349198E+00 0.0000000E+00 11 Fe++ 0.5704062E+00 0.3480506E-07 0.5704061E+00 0.0000000E+00 12 K+ 0.1698512E+00 0.1489538E-03 0.1697022E+00 0.0000000E+00 13 Na+ 0.1004354E+01 0.2122546E-01 0.9831283E+00 0.0000000E+00 14 Mn++ 0.1387086E-01 0.2399087E-08 0.1387086E-01 0.0000000E+00 15 HPO4-- 0.4734055E-02 0.4591034E-07 0.4734009E-02 0.0000000E+00 Chg. balance for solid moles: 0.5638E-15 Mass of aqueous solution: 0.919703E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 0.9824 -0.008 257.6 2.411 29.48 98.88 andradite 0.8884E-01 -1.051 45.15 1.655 5.167 11.73 grossular 0.2122E-01 -1.673 9.559 0.980 1.094 2.660 apatite-OH 0.1578E-02 -2.802 0.7927 -0.101 0.9071E-01 0.2519 clinochlore 0.1151 -0.939 63.99 1.806 7.323 24.34 daphnite 0.3299E-01 -1.482 23.54 1.372 2.694 7.133 chlorite-Mn 0.2774E-02 -2.557 1.967 0.294 0.2251 0.6268 diopside 0.3678E-01 -1.434 7.966 0.901 0.9116 2.434 hedenbergite 0.9423E-02 -2.026 2.338 0.369 0.2675 0.6403 microcline 0.1486 -0.828 41.37 1.617 4.735 16.16 stilbite 0.5234 -0.281 368.9 2.567 42.21 172.0 stilpnomelane-Fe 0.4211E-01 -1.376 45.40 1.657 5.195 15.68 tr.625ac.25prg.125 0.6215E-02 -2.207 5.313 0.725 0.6080 1.710 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7630E+00 0.7630E+00 1.0000 -0.117 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1839E-01 0.1839E-01 1.0000 -1.736 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 873.830420 g Volume = 354.293285 cm3 Porosity: -10.3719% V(tot) - V(min): -.33294E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 799.9990000 g log = 2.9031 Original solution: 1000.0103000 g Original solution / Rock added: 1.25 (Water/Rock Ratio), log = 0.0969 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0881 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9673E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4099E-08 1.0071 0.4492E-08 0.4460E-08 CH4,gas 0.1904E-01 1.0128 0.2099E-01 0.2072E-01 H2,gas 0.1370E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1419E-06 0.9958 0.1538E-06 0.1544E-06 S2,gas 0.3659E-29 1.0000 0.3981E-29 0.3981E-29 CO,gas 0.1595E-13 1.0000 0.1735E-13 0.1735E-13 SO3,gas 0.8676E-48 1.0000 0.9440E-48 0.9440E-48 SO2,gas 0.4894E-27 1.0000 0.5325E-27 0.5325E-27 HCl,gas 0.2884E-17 1.0000 0.3138E-17 0.3138E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.71 -10.35 -3.449 0.17668E+05 -8.348 3 CH4,gas 4.81 1.13 -3.68 -0.920 0.62801E+04 -1.678 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65335E+04 -1.826 5 H2S,gas -5.94 -14.76 -8.81 -4.407 0.15048E+05 -6.813 6 S2,gas -7.03 -38.43 -31.40 -4.831 0.53615E+05 -29.400 7 CO,gas 3.51 -12.25 -15.76 -4.849 0.26911E+05 -13.761 8 SO3,gas 17.43 -32.60 -50.03 -12.506 0.85416E+05 -48.025 9 SO2,gas 1.14 -28.14 -29.27 -7.806 0.49984E+05 -27.274 10 HCl,gas 5.48 -14.02 -19.50 -9.752 0.33301E+05 -17.503 11 acmite 7.74 6.57 -1.17 -0.121 0.19915E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.237 0.80827E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94120E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41193E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28382E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76233E+04 35 aragonite 0.99 -3.60 -4.59 -1.530 0.78380E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55855E+04 37 calcite 0.83 -3.60 -4.44 -1.479 0.75766E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71155E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70323E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82191E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68648E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70375E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65621E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36456E+04 66 diamond -3.11 -7.79 -4.68 -1.338 0.79953E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33650E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66050E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68257E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56968E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36653E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.79 -4.24 -1.212 0.72414E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60997E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24442E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64141E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59769E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16000E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22971E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28460E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74526E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48206E+04 112 manganosite 14.07 9.25 -4.82 -1.206 0.82336E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61281E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53666E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41166E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36601E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20054E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92765E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40689E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43438E+04 143 pyrrhotite -4.24 -8.01 -3.77 -1.256 0.64361E+04 144 pyrrhotiteFe0.875 -6.00 -9.41 -3.41 -1.253 0.58189E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.264 0.22504E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84880E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28306E+03 152 rhodonite 7.46 6.10 -1.36 -0.273 0.23296E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27393E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.34 -2.77 -0.396 0.47280E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91036E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76031E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65758E+04 181 troilite-low -4.39 -8.01 -3.62 -1.206 0.61793E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80404E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34508E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66776E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60338E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73634E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60308E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57935E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83183E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61761E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66247E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52965E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.51 -4.55 -1.516 0.77649E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62640E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18236E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11530E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14892E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18337E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 799.9990000 g New total amount of reactant added: 899.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 899.9990000 Water: Moles liquid = 0.5040E+02 kg liquid = 0.9080E+00 Moles total = 0.4423E+02 kg total = 0.7968E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174011E-01 Osmotic coef. = 0.9689 True ionic strength = .2069309E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90296E-10 -10.0443 0.75753E-10 -10.1206 0.83895E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15125E-03 -3.8203 0.12611E-03 -3.8992 0.83379E+00 -0.0789 4 SO4-- 0.86249E-12 -12.0642 0.44495E-12 -12.3517 0.51590E+00 -0.2874 5 HCO3- 0.31114E-06 -6.5070 0.25982E-06 -6.5853 0.83504E+00 -0.0783 6 HS- 0.28084E-04 -4.5515 0.23419E-04 -4.6304 0.83392E+00 -0.0789 7 Al+++ 0.11017E-28 -28.9579 0.25071E-29 -29.6008 0.22757E+00 -0.6429 8 H4SiO4 0.71159E-03 -3.1478 0.71159E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14325E-06 -6.8439 0.73348E-07 -7.1346 0.51203E+00 -0.2907 10 Mg++ 0.22747E-10 -10.6431 0.11593E-10 -10.9358 0.50964E+00 -0.2927 11 Fe++ 0.62218E-13 -13.2061 0.31744E-13 -13.4983 0.51021E+00 -0.2923 12 K+ 0.16148E-03 -3.7919 0.13488E-03 -3.8701 0.83524E+00 -0.0782 13 Na+ 0.20530E-01 -1.6876 0.17115E-01 -1.7666 0.83364E+00 -0.0790 14 Mn++ 0.19819E-10 -10.7029 0.10120E-10 -10.9948 0.51064E+00 -0.2919 15 HPO4-- 0.48754E-07 -7.3120 0.25156E-07 -7.5994 0.51597E+00 -0.2874 16 HSiO3- 0.10992E-01 -1.9589 0.91649E-02 -2.0379 0.83379E+00 -0.0789 17 Ca(HSiO3)+ 0.18029E-07 -7.7440 0.15061E-07 -7.8221 0.83542E+00 -0.0781 18 Mg(HSiO3)+ 0.35461E-11 -11.4502 0.29625E-11 -11.5283 0.83542E+00 -0.0781 19 NaHSiO3,aq 0.24913E-02 -2.6036 0.24913E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67513E-16 -16.1706 0.56402E-16 -16.2487 0.83542E+00 -0.0781 22 HAlO2,aq 0.14899E-09 -9.8268 0.14899E-09 -9.8268 0.10000E+01 0.0000 23 AlO2- 0.52767E-05 -5.2776 0.43916E-05 -5.3574 0.83226E+00 -0.0797 24 CH4,aq 0.13467E-04 -4.8707 0.13419E-04 -4.8723 0.99642E+00 -0.0016 25 C2H6,aq 0.28664E-14 -14.5427 0.28561E-14 -14.5442 0.99642E+00 -0.0016 29 CO,aq 0.11112E-16 -16.9542 0.11112E-16 -16.9542 0.10000E+01 0.0000 30 CO2,aq 0.39825E-10 -10.3998 0.39683E-10 -10.4014 0.99642E+00 -0.0016 31 CO3-2 0.61602E-06 -6.2104 0.31712E-06 -6.4988 0.51478E+00 -0.2884 32 CaCO3,aq 0.28488E-09 -9.5453 0.28488E-09 -9.5453 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.57478E-12 -12.2405 0.48018E-12 -12.3186 0.83542E+00 -0.0781 34 CaCl+ 0.17644E-10 -10.7534 0.14740E-10 -10.8315 0.83542E+00 -0.0781 35 CaCl2,aq 0.43281E-15 -15.3637 0.43281E-15 -15.3637 0.10000E+01 0.0000 36 CaOH+ 0.81724E-07 -7.0877 0.68274E-07 -7.1657 0.83542E+00 -0.0781 37 CaSO4,aq 0.10169E-16 -16.9927 0.10169E-16 -16.9927 0.10000E+01 0.0000 38 HCl,aq 0.17970E-14 -14.7455 0.17970E-14 -14.7455 0.10000E+01 0.0000 43 FeCl+ 0.74635E-17 -17.1271 0.62351E-17 -17.2052 0.83542E+00 -0.0781 46 FeO,aq 0.21875E-09 -9.6601 0.21875E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16629E-10 -10.7791 0.13892E-10 -10.8572 0.83542E+00 -0.0781 48 HFeO2- 0.37250E-07 -7.4289 0.31059E-07 -7.5078 0.83379E+00 -0.0789 49 FeO+ 0.12273E-16 -16.9111 0.10253E-16 -16.9892 0.83542E+00 -0.0781 51 FeO2- 0.42115E-09 -9.3756 0.35115E-09 -9.4545 0.83379E+00 -0.0789 52 HFeO2,aq 0.33291E-11 -11.4777 0.33291E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10912E-04 -4.9621 0.10872E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.30118E-09 -9.5212 0.30118E-09 -9.5212 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11089E-14 -14.9551 0.92461E-15 -15.0340 0.83379E+00 -0.0789 58 MgCO3,aq 0.11251E-13 -13.9488 0.11251E-13 -13.9488 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.92636E-16 -16.0332 0.77390E-16 -16.1113 0.83542E+00 -0.0781 60 MgCl+ 0.25315E-14 -14.5966 0.21149E-14 -14.6747 0.83542E+00 -0.0781 61 MgOH+ 0.71558E-10 -10.1453 0.59781E-10 -10.2234 0.83542E+00 -0.0781 63 MnO,aq 0.18617E-08 -8.7301 0.18617E-08 -8.7301 0.10000E+01 0.0000 64 MnOH+ 0.49249E-09 -9.3076 0.41144E-09 -9.3857 0.83542E+00 -0.0781 65 MnO2-2 0.21795E-10 -10.6617 0.11219E-10 -10.9500 0.51478E+00 -0.2884 66 HMnO2- 0.22085E-09 -9.6559 0.18414E-09 -9.7348 0.83379E+00 -0.0789 69 MnCl+ 0.92461E-14 -14.0340 0.77244E-14 -14.1121 0.83542E+00 -0.0781 71 NaCl,aq 0.70477E-06 -6.1520 0.70477E-06 -6.1520 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95141E-02 -2.0216 0.79183E-02 -2.1014 0.83226E+00 -0.0797 79 HPO3-2 0.16781E-14 -14.7752 0.86387E-15 -15.0635 0.51478E+00 -0.2884 81 H2PO3- 0.15417E-18 -18.8120 0.12855E-18 -18.8909 0.83379E+00 -0.0789 82 H3PO4,aq 0.92936E-18 -18.0318 0.92936E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40030E-10 -10.3976 0.33409E-10 -10.4761 0.83460E+00 -0.0785 84 PO4-3 0.12121E-08 -8.9165 0.29000E-09 -9.5376 0.23926E+00 -0.6211 88 HP2O7-3 0.10380E-17 -17.9838 0.23647E-18 -18.6262 0.22781E+00 -0.6424 89 P2O7-4 0.10252E-16 -16.9892 0.77008E-18 -18.1135 0.75112E-01 -1.1243 90 H2S,aq 0.53495E-08 -8.2717 0.53304E-08 -8.2732 0.99642E+00 -0.0016 91 S2-2 0.21552E-14 -14.6665 0.11095E-14 -14.9549 0.51478E+00 -0.2884 97 SO3-2 0.12627E-17 -17.8987 0.65963E-18 -18.1807 0.52238E+00 -0.2820 99 HSO4- 0.37399E-19 -19.4271 0.31275E-19 -19.5048 0.83625E+00 -0.0777 Charge balance for all species = 0.3632E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9029571E-10 -.2312196E-01 -.2326335E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981181E+06 0.0000 3 Cl- 0.1512503E-03 0.1519554E-03 0.5377519E+01 6.2214 4 SO4-- 0.8624878E-12 -.1619474E-04 -.1552876E+01 7.8895 5 HCO3- 0.3111448E-06 0.1439441E-04 0.8767161E+00 3.5353 6 HS- 0.2808354E-04 0.4428363E-04 0.1461896E+01 5.4902 7 Al+++ 0.1101722E-28 0.5276851E-05 0.1421196E+00 0.7610 8 H4SiO4 0.7115881E-03 0.1419472E-01 0.1361861E+04 -3.1478 9 Ca++ 0.1432496E-06 0.2433050E-06 0.9733521E-02 13.1066 10 Mg++ 0.2274668E-10 0.9786463E-10 0.2374977E-05 9.3054 11 Fe++ 0.6221760E-13 0.3791039E-07 0.2113348E-02 6.7429 12 K+ 0.1614848E-03 0.1622613E-03 0.6333254E+01 6.2505 13 Na+ 0.2053040E-01 0.2312165E-01 0.5305996E+03 8.3540 14 Mn++ 0.1981881E-10 0.2616645E-08 0.1434929E-03 9.2464 15 HPO4-- 0.4875385E-07 0.5000596E-07 0.4790831E-02 12.6418 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1490263E+02 -.2099455E-01 -.1488164E+02 0.0000000E+00 2 H2O 0.4422639E+02 0.5039754E+02 -.6171144E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2496754E-01 -.1470469E-04 0.2498225E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2494204E-01 0.4020916E-04 -.2498225E-01 0.0000000E+00 7 Al+++ 0.2934664E+01 0.4791336E-05 0.2934659E+01 0.0000000E+00 8 H4SiO4 0.9371494E+01 0.1288869E-01 0.9358606E+01 0.0000000E+00 9 Ca++ 0.1035142E+01 0.2209189E-06 0.1035141E+01 0.0000000E+00 10 Mg++ 0.7142849E+00 0.8886025E-10 0.7142849E+00 0.0000000E+00 11 Fe++ 0.6417070E+00 0.3442231E-07 0.6417070E+00 0.0000000E+00 12 K+ 0.1910826E+00 0.1473319E-03 0.1909353E+00 0.0000000E+00 13 Na+ 0.1129878E+01 0.2099426E-01 0.1108884E+01 0.0000000E+00 14 Mn++ 0.1560472E-01 0.2375891E-08 0.1560472E-01 0.0000000E+00 15 HPO4-- 0.5325813E-02 0.4540498E-07 0.5325768E-02 0.0000000E+00 Chg. balance for solid moles: -.1128E-15 Mass of aqueous solution: 0.909639E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 899.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.108 0.045 290.5 2.463 29.55 111.5 andradite 0.9993E-01 -1.000 50.78 1.706 5.166 13.19 grossular 0.2387E-01 -1.622 10.75 1.031 1.094 2.991 apatite-OH 0.1775E-02 -2.751 0.8917 -0.050 0.9071E-01 0.2834 clinochlore 0.1293 -0.888 71.89 1.857 7.313 27.35 daphnite 0.3707E-01 -1.431 26.45 1.422 2.690 8.015 chlorite-Mn 0.3121E-02 -2.506 2.213 0.345 0.2251 0.7051 diopside 0.4257E-01 -1.371 9.218 0.965 0.9377 2.817 hedenbergite 0.1090E-01 -1.962 2.705 0.432 0.2752 0.7410 microcline 0.1672 -0.777 46.55 1.668 4.735 18.18 stilbite 0.5876 -0.231 414.1 2.617 42.12 193.1 stilpnomelane-Fe 0.4740E-01 -1.324 51.09 1.708 5.197 17.65 tr.625ac.25prg.125 0.6897E-02 -2.161 5.895 0.770 0.5997 1.897 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1841E-01 0.1841E-01 1.0000 -1.735 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 983.085895 g Volume = 398.499642 cm3 Porosity: -10.3878% V(tot) - V(min): -.37500E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 899.9990000 g log = 2.9542 Original solution: 1000.0103000 g Original solution / Rock added: 1.11 (Water/Rock Ratio), log = 0.0458 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0883 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9671E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4144E-08 1.0071 0.4542E-08 0.4510E-08 CH4,gas 0.1925E-01 1.0128 0.2122E-01 0.2095E-01 H2,gas 0.1369E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1435E-06 0.9958 0.1555E-06 0.1561E-06 S2,gas 0.3740E-29 1.0000 0.4071E-29 0.4071E-29 CO,gas 0.1612E-13 1.0000 0.1755E-13 0.1755E-13 SO3,gas 0.8771E-48 1.0000 0.9546E-48 0.9546E-48 SO2,gas 0.4948E-27 1.0000 0.5385E-27 0.5385E-27 HCl,gas 0.2915E-17 1.0000 0.3173E-17 0.3173E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.71 -10.34 -3.448 0.17660E+05 -8.343 3 CH4,gas 4.81 1.14 -3.67 -0.918 0.62720E+04 -1.673 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.75 -8.81 -4.404 0.15040E+05 -6.808 6 S2,gas -7.03 -38.42 -31.39 -4.829 0.53598E+05 -29.390 7 CO,gas 3.51 -12.25 -15.76 -4.848 0.26903E+05 -13.756 8 SO3,gas 17.43 -32.59 -50.02 -12.505 0.85408E+05 -48.020 9 SO2,gas 1.14 -28.13 -29.27 -7.805 0.49976E+05 -27.269 10 HCl,gas 5.48 -14.02 -19.50 -9.749 0.33293E+05 -17.499 11 acmite 7.74 6.57 -1.17 -0.121 0.19915E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.237 0.80799E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94121E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28383E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76233E+04 35 aragonite 0.99 -3.60 -4.59 -1.529 0.78297E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55855E+04 37 calcite 0.83 -3.60 -4.43 -1.478 0.75684E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71155E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70324E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82191E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68649E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70376E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65612E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36456E+04 66 diamond -3.11 -7.79 -4.68 -1.336 0.79871E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33650E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66051E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56968E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.79 -4.24 -1.210 0.72332E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60997E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24442E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64141E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59769E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16000E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22972E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48206E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82327E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61282E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53666E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41166E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36601E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20055E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92767E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40691E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43439E+04 143 pyrrhotite -4.24 -8.01 -3.76 -1.255 0.64280E+04 144 pyrrhotiteFe0.875 -6.00 -9.40 -3.40 -1.252 0.58107E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22494E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84880E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28305E+03 152 rhodonite 7.46 6.10 -1.36 -0.273 0.23287E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27393E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.77 -0.395 0.47261E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91034E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76031E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65758E+04 181 troilite-low -4.39 -8.01 -3.61 -1.205 0.61711E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80408E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34509E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89301E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66777E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60337E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73634E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57935E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83182E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61760E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66246E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52965E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.50 -4.54 -1.514 0.77557E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62641E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18236E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14892E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18337E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 899.9990000 g New total amount of reactant added: 999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 999.9990000 Water: Moles liquid = 0.4984E+02 kg liquid = 0.8979E+00 Moles total = 0.4297E+02 kg total = 0.7742E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174157E-01 Osmotic coef. = 0.9688 True ionic strength = .2069425E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90301E-10 -10.0443 0.75757E-10 -10.1206 0.83894E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15294E-03 -3.8155 0.12752E-03 -3.8944 0.83379E+00 -0.0789 4 SO4-- 0.87220E-12 -12.0594 0.44996E-12 -12.3468 0.51589E+00 -0.2874 5 HCO3- 0.31465E-06 -6.5022 0.26274E-06 -6.5805 0.83503E+00 -0.0783 6 HS- 0.28398E-04 -4.5467 0.23681E-04 -4.6256 0.83391E+00 -0.0789 7 Al+++ 0.11019E-28 -28.9579 0.25075E-29 -29.6008 0.22756E+00 -0.6429 8 H4SiO4 0.71160E-03 -3.1478 0.71160E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14326E-06 -6.8439 0.73354E-07 -7.1346 0.51202E+00 -0.2907 10 Mg++ 0.22749E-10 -10.6430 0.11594E-10 -10.9358 0.50963E+00 -0.2927 11 Fe++ 0.62225E-13 -13.2060 0.31747E-13 -13.4983 0.51020E+00 -0.2923 12 K+ 0.16149E-03 -3.7918 0.13489E-03 -3.8700 0.83523E+00 -0.0782 13 Na+ 0.20532E-01 -1.6876 0.17116E-01 -1.7666 0.83363E+00 -0.0790 14 Mn++ 0.19842E-10 -10.7024 0.10132E-10 -10.9943 0.51063E+00 -0.2919 15 HPO4-- 0.48750E-07 -7.3120 0.25153E-07 -7.5994 0.51596E+00 -0.2874 16 HSiO3- 0.10991E-01 -1.9589 0.91646E-02 -2.0379 0.83379E+00 -0.0789 17 Ca(HSiO3)+ 0.18030E-07 -7.7440 0.15062E-07 -7.8221 0.83542E+00 -0.0781 18 Mg(HSiO3)+ 0.35463E-11 -11.4502 0.29627E-11 -11.5283 0.83542E+00 -0.0781 19 NaHSiO3,aq 0.24913E-02 -2.6036 0.24913E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67514E-16 -16.1706 0.56402E-16 -16.2487 0.83542E+00 -0.0781 22 HAlO2,aq 0.14899E-09 -9.8269 0.14899E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52763E-05 -5.2777 0.43912E-05 -5.3574 0.83226E+00 -0.0797 24 CH4,aq 0.13618E-04 -4.8659 0.13569E-04 -4.8675 0.99642E+00 -0.0016 25 C2H6,aq 0.29309E-14 -14.5330 0.29204E-14 -14.5346 0.99642E+00 -0.0016 29 CO,aq 0.11237E-16 -16.9493 0.11237E-16 -16.9493 0.10000E+01 0.0000 30 CO2,aq 0.40275E-10 -10.3950 0.40131E-10 -10.3965 0.99642E+00 -0.0016 31 CO3-2 0.62293E-06 -6.2056 0.32067E-06 -6.4939 0.51477E+00 -0.2884 32 CaCO3,aq 0.28809E-09 -9.5405 0.28809E-09 -9.5405 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.58130E-12 -12.2356 0.48563E-12 -12.3137 0.83542E+00 -0.0781 34 CaCl+ 0.17843E-10 -10.7485 0.14906E-10 -10.8266 0.83542E+00 -0.0781 35 CaCl2,aq 0.44259E-15 -15.3540 0.44259E-15 -15.3540 0.10000E+01 0.0000 36 CaOH+ 0.81727E-07 -7.0876 0.68276E-07 -7.1657 0.83542E+00 -0.0781 37 CaSO4,aq 0.10284E-16 -16.9878 0.10284E-16 -16.9878 0.10000E+01 0.0000 38 HCl,aq 0.18172E-14 -14.7406 0.18172E-14 -14.7406 0.10000E+01 0.0000 43 FeCl+ 0.75477E-17 -17.1222 0.63055E-17 -17.2003 0.83542E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16630E-10 -10.7791 0.13893E-10 -10.8572 0.83542E+00 -0.0781 48 HFeO2- 0.37248E-07 -7.4289 0.31057E-07 -7.5078 0.83379E+00 -0.0789 49 FeO+ 0.12273E-16 -16.9110 0.10253E-16 -16.9891 0.83542E+00 -0.0781 51 FeO2- 0.42113E-09 -9.3756 0.35114E-09 -9.4545 0.83379E+00 -0.0789 52 HFeO2,aq 0.33291E-11 -11.4777 0.33291E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10872E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.30457E-09 -9.5163 0.30457E-09 -9.5163 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11215E-14 -14.9502 0.93506E-15 -15.0292 0.83379E+00 -0.0789 58 MgCO3,aq 0.11378E-13 -13.9439 0.11378E-13 -13.9439 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.93687E-16 -16.0283 0.78267E-16 -16.1064 0.83542E+00 -0.0781 60 MgCl+ 0.25601E-14 -14.5917 0.21387E-14 -14.6698 0.83542E+00 -0.0781 61 MgOH+ 0.71561E-10 -10.1453 0.59783E-10 -10.2234 0.83542E+00 -0.0781 63 MnO,aq 0.18636E-08 -8.7296 0.18636E-08 -8.7296 0.10000E+01 0.0000 64 MnOH+ 0.49303E-09 -9.3071 0.41188E-09 -9.3852 0.83542E+00 -0.0781 65 MnO2-2 0.21815E-10 -10.6612 0.11230E-10 -10.9496 0.51477E+00 -0.2884 66 HMnO2- 0.22107E-09 -9.6555 0.18432E-09 -9.7344 0.83379E+00 -0.0789 69 MnCl+ 0.93601E-14 -14.0287 0.78196E-14 -14.1068 0.83542E+00 -0.0781 71 NaCl,aq 0.71269E-06 -6.1471 0.71269E-06 -6.1471 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95137E-02 -2.0217 0.79179E-02 -2.1014 0.83226E+00 -0.0797 79 HPO3-2 0.16780E-14 -14.7752 0.86378E-15 -15.0636 0.51477E+00 -0.2884 81 H2PO3- 0.15416E-18 -18.8120 0.12854E-18 -18.8910 0.83379E+00 -0.0789 82 H3PO4,aq 0.92938E-18 -18.0318 0.92938E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40029E-10 -10.3976 0.33408E-10 -10.4761 0.83460E+00 -0.0785 84 PO4-3 0.12119E-08 -8.9165 0.28996E-09 -9.5377 0.23925E+00 -0.6211 88 HP2O7-3 0.10379E-17 -17.9838 0.23644E-18 -18.6263 0.22780E+00 -0.6424 89 P2O7-4 0.10251E-16 -16.9892 0.76995E-18 -18.1135 0.75108E-01 -1.1243 90 H2S,aq 0.54096E-08 -8.2668 0.53903E-08 -8.2684 0.99642E+00 -0.0016 91 S2-2 0.22038E-14 -14.6568 0.11345E-14 -14.9452 0.51477E+00 -0.2884 97 SO3-2 0.12769E-17 -17.8938 0.66703E-18 -18.1759 0.52237E+00 -0.2820 99 HSO4- 0.37822E-19 -19.4223 0.31629E-19 -19.4999 0.83625E+00 -0.0777 Charge balance for all species = 0.3673E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9030076E-10 -.2312114E-01 -.2326252E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981181E+06 0.0000 3 Cl- 0.1529425E-03 0.1536555E-03 0.5437685E+01 6.2262 4 SO4-- 0.8722007E-12 -.1634531E-04 -.1567313E+01 7.8943 5 HCO3- 0.3146456E-06 0.1455546E-04 0.8865253E+00 3.5401 6 HS- 0.2839775E-04 0.4474847E-04 0.1477242E+01 5.4950 7 Al+++ 0.1101892E-28 0.5276402E-05 0.1421075E+00 0.7610 8 H4SiO4 0.7115968E-03 0.1419436E-01 0.1361826E+04 -3.1478 9 Ca++ 0.1432650E-06 0.2433284E-06 0.9734457E-02 13.1066 10 Mg++ 0.2274910E-10 0.9787045E-10 0.2375118E-05 9.3054 11 Fe++ 0.6222477E-13 0.3790837E-07 0.2113235E-02 6.7429 12 K+ 0.1614939E-03 0.1622704E-03 0.6333607E+01 6.2505 13 Na+ 0.2053155E-01 0.2312284E-01 0.5306269E+03 8.3540 14 Mn++ 0.1984155E-10 0.2619349E-08 0.1436412E-03 9.2468 15 HPO4-- 0.4875048E-07 0.5000246E-07 0.4790496E-02 12.6418 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1655849E+02 -.2076150E-01 -.1653772E+02 0.0000000E+00 2 H2O 0.4297285E+02 0.4983990E+02 -.6867048E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2773889E-01 -.1467718E-04 0.2775356E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2771338E-01 0.4018165E-04 -.2775356E-01 0.0000000E+00 7 Al+++ 0.3260738E+01 0.4737918E-05 0.3260734E+01 0.0000000E+00 8 H4SiO4 0.1041277E+02 0.1274575E-01 0.1040003E+02 0.0000000E+00 9 Ca++ 0.1150156E+01 0.2184955E-06 0.1150156E+01 0.0000000E+00 10 Mg++ 0.7936500E+00 0.8788226E-10 0.7936500E+00 0.0000000E+00 11 Fe++ 0.7130079E+00 0.3403963E-07 0.7130078E+00 0.0000000E+00 12 K+ 0.2123140E+00 0.1457098E-03 0.2121683E+00 0.0000000E+00 13 Na+ 0.1255402E+01 0.2076303E-01 0.1234639E+01 0.0000000E+00 14 Mn++ 0.1733858E-01 0.2352031E-08 0.1733858E-01 0.0000000E+00 15 HPO4-- 0.5917571E-02 0.4489944E-07 0.5917526E-02 0.0000000E+00 Chg. balance for solid moles: -.1808E-14 Mass of aqueous solution: 0.899574E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.234 0.091 323.5 2.510 29.62 124.2 andradite 0.1110 -0.955 56.42 1.751 5.165 14.66 grossular 0.2651E-01 -1.577 11.94 1.077 1.093 3.323 apatite-OH 0.1973E-02 -2.705 0.9908 -0.004 0.9071E-01 0.3148 clinochlore 0.1436 -0.843 79.80 1.902 7.305 30.35 daphnite 0.4114E-01 -1.386 29.36 1.468 2.687 8.896 chlorite-Mn 0.3468E-02 -2.460 2.459 0.391 0.2251 0.7835 diopside 0.4835E-01 -1.316 10.47 1.020 0.9586 3.200 hedenbergite 0.1239E-01 -1.907 3.073 0.488 0.2813 0.8417 microcline 0.1858 -0.731 51.72 1.714 4.735 20.20 stilbite 0.6518 -0.186 459.3 2.662 42.05 214.2 stilpnomelane-Fe 0.5268E-01 -1.278 56.79 1.754 5.199 19.62 tr.625ac.25prg.125 0.7578E-02 -2.120 6.478 0.811 0.5930 2.085 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1843E-01 0.1843E-01 1.0000 -1.735 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1092.341370 g Volume = 442.705999 cm3 Porosity: -10.4006% V(tot) - V(min): -.41706E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 999.9990000 g log = 3.0000 Original solution: 1000.0103000 g Original solution / Rock added: 1.00 (Water/Rock Ratio), log = 0.0000 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0885 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9668E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4190E-08 1.0071 0.4594E-08 0.4561E-08 CH4,gas 0.1946E-01 1.0128 0.2146E-01 0.2119E-01 H2,gas 0.1369E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1450E-06 0.9958 0.1572E-06 0.1579E-06 S2,gas 0.3824E-29 1.0000 0.4163E-29 0.4163E-29 CO,gas 0.1630E-13 1.0000 0.1774E-13 0.1774E-13 SO3,gas 0.8869E-48 1.0000 0.9654E-48 0.9654E-48 SO2,gas 0.5003E-27 1.0000 0.5446E-27 0.5446E-27 HCl,gas 0.2948E-17 1.0000 0.3209E-17 0.3209E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.54595E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.70 -10.34 -3.446 0.17652E+05 -8.338 3 CH4,gas 4.81 1.14 -3.67 -0.917 0.62637E+04 -1.668 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.75 -8.80 -4.402 0.15032E+05 -6.804 6 S2,gas -7.03 -38.41 -31.38 -4.828 0.53582E+05 -29.381 7 CO,gas 3.51 -12.24 -15.75 -4.846 0.26894E+05 -13.751 8 SO3,gas 17.43 -32.59 -50.02 -12.504 0.85400E+05 -48.015 9 SO2,gas 1.14 -28.13 -29.26 -7.804 0.49967E+05 -27.264 10 HCl,gas 5.48 -14.01 -19.49 -9.747 0.33285E+05 -17.494 11 acmite 7.74 6.57 -1.17 -0.121 0.19915E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.237 0.80776E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94122E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28383E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76234E+04 35 aragonite 0.99 -3.59 -4.58 -1.527 0.78214E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55855E+04 37 calcite 0.83 -3.59 -4.43 -1.476 0.75601E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70324E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82192E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68649E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70376E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65605E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36457E+04 66 diamond -3.11 -7.78 -4.67 -1.335 0.79788E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33651E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66052E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.78 -4.23 -1.209 0.72249E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60997E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24442E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59769E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16001E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22972E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48206E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82319E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61282E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53667E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41166E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36602E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20055E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92768E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40692E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43440E+04 143 pyrrhotite -4.24 -8.00 -3.76 -1.253 0.64197E+04 144 pyrrhotiteFe0.875 -6.00 -9.40 -3.40 -1.250 0.58025E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22487E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84880E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28304E+03 152 rhodonite 7.46 6.10 -1.36 -0.273 0.23279E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27394E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.77 -0.395 0.47246E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91033E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76031E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65758E+04 181 troilite-low -4.39 -8.00 -3.61 -1.203 0.61629E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80412E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34509E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66777E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60336E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73634E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57934E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83182E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61760E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66246E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52964E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.50 -4.54 -1.512 0.77467E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62641E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18236E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14892E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18337E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 999.9990000 g New total amount of reactant added: 1099.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1099.9990000 Water: Moles liquid = 0.4929E+02 kg liquid = 0.8879E+00 Moles total = 0.4172E+02 kg total = 0.7516E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174305E-01 Osmotic coef. = 0.9688 True ionic strength = .2069543E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90306E-10 -10.0443 0.75761E-10 -10.1206 0.83894E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15467E-03 -3.8106 0.12896E-03 -3.8895 0.83379E+00 -0.0789 4 SO4-- 0.88211E-12 -12.0545 0.45507E-12 -12.3419 0.51588E+00 -0.2875 5 HCO3- 0.31822E-06 -6.4973 0.26572E-06 -6.5756 0.83503E+00 -0.0783 6 HS- 0.28719E-04 -4.5418 0.23949E-04 -4.6207 0.83391E+00 -0.0789 7 Al+++ 0.11021E-28 -28.9578 0.25078E-29 -29.6007 0.22755E+00 -0.6429 8 H4SiO4 0.71160E-03 -3.1478 0.71160E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14328E-06 -6.8438 0.73361E-07 -7.1345 0.51201E+00 -0.2907 10 Mg++ 0.22752E-10 -10.6430 0.11595E-10 -10.9357 0.50962E+00 -0.2928 11 Fe++ 0.62232E-13 -13.2060 0.31750E-13 -13.4983 0.51019E+00 -0.2923 12 K+ 0.16150E-03 -3.7918 0.13489E-03 -3.8700 0.83523E+00 -0.0782 13 Na+ 0.20533E-01 -1.6876 0.17117E-01 -1.7666 0.83363E+00 -0.0790 14 Mn++ 0.19861E-10 -10.7020 0.10141E-10 -10.9939 0.51062E+00 -0.2919 15 HPO4-- 0.48747E-07 -7.3121 0.25151E-07 -7.5994 0.51596E+00 -0.2874 16 HSiO3- 0.10991E-01 -1.9590 0.91642E-02 -2.0379 0.83379E+00 -0.0789 17 Ca(HSiO3)+ 0.18031E-07 -7.7440 0.15063E-07 -7.8221 0.83541E+00 -0.0781 18 Mg(HSiO3)+ 0.35465E-11 -11.4502 0.29628E-11 -11.5283 0.83541E+00 -0.0781 19 NaHSiO3,aq 0.24913E-02 -2.6036 0.24913E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67516E-16 -16.1706 0.56404E-16 -16.2487 0.83541E+00 -0.0781 22 HAlO2,aq 0.14898E-09 -9.8269 0.14898E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52758E-05 -5.2777 0.43909E-05 -5.3575 0.83226E+00 -0.0797 24 CH4,aq 0.13772E-04 -4.8610 0.13722E-04 -4.8626 0.99642E+00 -0.0016 25 C2H6,aq 0.29977E-14 -14.5232 0.29870E-14 -14.5248 0.99642E+00 -0.0016 29 CO,aq 0.11365E-16 -16.9444 0.11365E-16 -16.9444 0.10000E+01 0.0000 30 CO2,aq 0.40735E-10 -10.3900 0.40589E-10 -10.3916 0.99642E+00 -0.0016 31 CO3-2 0.62998E-06 -6.2007 0.32429E-06 -6.4891 0.51476E+00 -0.2884 32 CaCO3,aq 0.29138E-09 -9.5355 0.29138E-09 -9.5355 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.58796E-12 -12.2307 0.49119E-12 -12.3088 0.83541E+00 -0.0781 34 CaCl+ 0.18046E-10 -10.7436 0.15076E-10 -10.8217 0.83541E+00 -0.0781 35 CaCl2,aq 0.45270E-15 -15.3442 0.45270E-15 -15.3442 0.10000E+01 0.0000 36 CaOH+ 0.81731E-07 -7.0876 0.68279E-07 -7.1657 0.83541E+00 -0.0781 37 CaSO4,aq 0.10402E-16 -16.9829 0.10402E-16 -16.9829 0.10000E+01 0.0000 38 HCl,aq 0.18378E-14 -14.7357 0.18378E-14 -14.7357 0.10000E+01 0.0000 43 FeCl+ 0.76339E-17 -17.1173 0.63775E-17 -17.1954 0.83541E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16631E-10 -10.7791 0.13894E-10 -10.8572 0.83541E+00 -0.0781 48 HFeO2- 0.37246E-07 -7.4289 0.31056E-07 -7.5079 0.83379E+00 -0.0789 49 FeO+ 0.12274E-16 -16.9110 0.10254E-16 -16.9891 0.83541E+00 -0.0781 51 FeO2- 0.42111E-09 -9.3756 0.35112E-09 -9.4545 0.83379E+00 -0.0789 52 HFeO2,aq 0.33291E-11 -11.4777 0.33291E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10872E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.30803E-09 -9.5114 0.30803E-09 -9.5114 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11342E-14 -14.9453 0.94572E-15 -15.0242 0.83379E+00 -0.0789 58 MgCO3,aq 0.11507E-13 -13.9390 0.11507E-13 -13.9390 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.94760E-16 -16.0234 0.79163E-16 -16.1015 0.83541E+00 -0.0781 60 MgCl+ 0.25893E-14 -14.5868 0.21631E-14 -14.6649 0.83541E+00 -0.0781 61 MgOH+ 0.71564E-10 -10.1453 0.59786E-10 -10.2234 0.83541E+00 -0.0781 63 MnO,aq 0.18652E-08 -8.7293 0.18652E-08 -8.7293 0.10000E+01 0.0000 64 MnOH+ 0.49347E-09 -9.3067 0.41225E-09 -9.3848 0.83541E+00 -0.0781 65 MnO2-2 0.21831E-10 -10.6609 0.11238E-10 -10.9493 0.51476E+00 -0.2884 66 HMnO2- 0.22124E-09 -9.6551 0.18447E-09 -9.7341 0.83379E+00 -0.0789 69 MnCl+ 0.94750E-14 -14.0234 0.79155E-14 -14.1015 0.83541E+00 -0.0781 71 NaCl,aq 0.72079E-06 -6.1422 0.72079E-06 -6.1422 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95132E-02 -2.0217 0.79174E-02 -2.1014 0.83226E+00 -0.0797 79 HPO3-2 0.16778E-14 -14.7753 0.86368E-15 -15.0636 0.51476E+00 -0.2884 81 H2PO3- 0.15416E-18 -18.8120 0.12853E-18 -18.8910 0.83379E+00 -0.0789 82 H3PO4,aq 0.92940E-18 -18.0318 0.92940E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40028E-10 -10.3976 0.33407E-10 -10.4762 0.83459E+00 -0.0785 84 PO4-3 0.12118E-08 -8.9166 0.28992E-09 -9.5377 0.23925E+00 -0.6212 88 HP2O7-3 0.10378E-17 -17.9839 0.23641E-18 -18.6263 0.22779E+00 -0.6425 89 P2O7-4 0.10250E-16 -16.9893 0.76981E-18 -18.1136 0.75103E-01 -1.1243 90 H2S,aq 0.54711E-08 -8.2619 0.54515E-08 -8.2635 0.99642E+00 -0.0016 91 S2-2 0.22541E-14 -14.6470 0.11603E-14 -14.9354 0.51476E+00 -0.2884 97 SO3-2 0.12914E-17 -17.8889 0.67458E-18 -18.1710 0.52237E+00 -0.2820 99 HSO4- 0.38253E-19 -19.4173 0.31989E-19 -19.4950 0.83624E+00 -0.0777 Charge balance for all species = 0.3715E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9030587E-10 -.2312027E-01 -.2326165E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981180E+06 0.0000 3 Cl- 0.1546731E-03 0.1553942E-03 0.5499213E+01 6.2310 4 SO4-- 0.8821149E-12 -.1649932E-04 -.1582081E+01 7.8992 5 HCO3- 0.3182194E-06 0.1472016E-04 0.8965564E+00 3.5450 6 HS- 0.2871908E-04 0.4522386E-04 0.1492935E+01 5.4998 7 Al+++ 0.1102072E-28 0.5275985E-05 0.1420962E+00 0.7609 8 H4SiO4 0.7116040E-03 0.1419397E-01 0.1361788E+04 -3.1478 9 Ca++ 0.1432809E-06 0.2433526E-06 0.9735425E-02 13.1066 10 Mg++ 0.2275161E-10 0.9787640E-10 0.2375262E-05 9.3054 11 Fe++ 0.6223207E-13 0.3790638E-07 0.2113124E-02 6.7429 12 K+ 0.1615030E-03 0.1622795E-03 0.6333964E+01 6.2505 13 Na+ 0.2053272E-01 0.2312404E-01 0.5306543E+03 8.3540 14 Mn++ 0.1986065E-10 0.2621570E-08 0.1437630E-03 9.2472 15 HPO4-- 0.4874688E-07 0.4999872E-07 0.4790138E-02 12.6417 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1821434E+02 -.2052844E-01 -.1819381E+02 0.0000000E+00 2 H2O 0.4171931E+02 0.4928226E+02 -.7562952E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3051023E-01 -.1464971E-04 0.3052488E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3048472E-01 0.4015418E-04 -.3052488E-01 0.0000000E+00 7 Al+++ 0.3586813E+01 0.4684537E-05 0.3586808E+01 0.0000000E+00 8 H4SiO4 0.1145405E+02 0.1260279E-01 0.1144145E+02 0.0000000E+00 9 Ca++ 0.1265170E+01 0.2160723E-06 0.1265170E+01 0.0000000E+00 10 Mg++ 0.8730151E+00 0.8690426E-10 0.8730151E+00 0.0000000E+00 11 Fe++ 0.7843087E+00 0.3365700E-07 0.7843087E+00 0.0000000E+00 12 K+ 0.2335454E+00 0.1440877E-03 0.2334013E+00 0.0000000E+00 13 Na+ 0.1380927E+01 0.2053179E-01 0.1360395E+01 0.0000000E+00 14 Mn++ 0.1907244E-01 0.2327687E-08 0.1907244E-01 0.0000000E+00 15 HPO4-- 0.6509328E-02 0.4439377E-07 0.6509284E-02 0.0000000E+00 Chg. balance for solid moles: 0.3005E-14 Mass of aqueous solution: 0.889509E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1099.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.359 0.133 356.5 2.552 29.66 136.8 andradite 0.1221 -0.913 62.05 1.793 5.164 16.12 grossular 0.2916E-01 -1.535 13.14 1.118 1.093 3.655 apatite-OH 0.2170E-02 -2.664 1.090 0.037 0.9071E-01 0.3463 clinochlore 0.1578 -0.802 87.70 1.943 7.299 33.36 daphnite 0.4522E-01 -1.345 32.26 1.509 2.685 9.777 chlorite-Mn 0.3814E-02 -2.419 2.704 0.432 0.2251 0.8618 diopside 0.5414E-01 -1.267 11.72 1.069 0.9757 3.583 hedenbergite 0.1387E-01 -1.858 3.441 0.537 0.2863 0.9424 microcline 0.2044 -0.689 56.90 1.755 4.735 22.23 stilbite 0.7160 -0.145 504.6 2.703 41.99 235.4 stilpnomelane-Fe 0.5796E-01 -1.237 62.48 1.796 5.200 21.58 tr.625ac.25prg.125 0.8260E-02 -2.083 7.060 0.849 0.5876 2.272 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1844E-01 0.1844E-01 1.0000 -1.734 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1201.596848 g Volume = 486.912356 cm3 Porosity: -10.4111% V(tot) - V(min): -.45913E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1099.9990000 g log = 3.0414 Original solution: 1000.0103000 g Original solution / Rock added: 0.91 (Water/Rock Ratio), log = -0.0414 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0888 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9666E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4237E-08 1.0071 0.4646E-08 0.4613E-08 CH4,gas 0.1968E-01 1.0128 0.2170E-01 0.2143E-01 H2,gas 0.1369E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1467E-06 0.9958 0.1590E-06 0.1597E-06 S2,gas 0.3911E-29 1.0000 0.4258E-29 0.4258E-29 CO,gas 0.1648E-13 1.0000 0.1795E-13 0.1795E-13 SO3,gas 0.8969E-48 1.0000 0.9765E-48 0.9765E-48 SO2,gas 0.5059E-27 1.0000 0.5508E-27 0.5508E-27 HCl,gas 0.2980E-17 1.0000 0.3245E-17 0.3245E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 67 diopside 16.22 16.22 0.00 0.000 0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.84926E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.70 -10.33 -3.444 0.17643E+05 -8.333 3 CH4,gas 4.81 1.15 -3.66 -0.916 0.62554E+04 -1.664 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.74 -8.80 -4.399 0.15023E+05 -6.799 6 S2,gas -7.03 -38.40 -31.37 -4.826 0.53565E+05 -29.371 7 CO,gas 3.51 -12.24 -15.75 -4.845 0.26886E+05 -13.746 8 SO3,gas 17.43 -32.58 -50.01 -12.503 0.85391E+05 -48.010 9 SO2,gas 1.14 -28.12 -29.26 -7.802 0.49959E+05 -27.259 10 HCl,gas 5.48 -14.01 -19.49 -9.744 0.33277E+05 -17.489 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80758E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94122E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28383E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76234E+04 35 aragonite 0.99 -3.59 -4.58 -1.525 0.78130E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55855E+04 37 calcite 0.83 -3.59 -4.42 -1.474 0.75517E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70325E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82192E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68649E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70377E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65599E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36457E+04 66 diamond -3.11 -7.78 -4.67 -1.334 0.79704E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33651E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66052E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.78 -4.23 -1.208 0.72166E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60997E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59770E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16001E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22973E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82313E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61283E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53667E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41166E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36602E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20055E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92769E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40693E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43441E+04 143 pyrrhotite -4.24 -8.00 -3.75 -1.252 0.64113E+04 144 pyrrhotiteFe0.875 -6.00 -9.39 -3.39 -1.248 0.57941E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22480E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84880E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28304E+03 152 rhodonite 7.46 6.10 -1.36 -0.273 0.23273E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27394E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.77 -0.395 0.47233E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91033E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65757E+04 181 troilite-low -4.39 -8.00 -3.60 -1.201 0.61545E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80415E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34509E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66778E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60335E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73634E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57934E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83182E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61760E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66246E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52964E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.49 -4.53 -1.511 0.77377E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62641E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52613E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14892E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 1099.9990000 g New total amount of reactant added: 1199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1199.9990000 Water: Moles liquid = 0.4873E+02 kg liquid = 0.8779E+00 Moles total = 0.4047E+02 kg total = 0.7290E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174456E-01 Osmotic coef. = 0.9688 True ionic strength = .2069663E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90311E-10 -10.0443 0.75765E-10 -10.1205 0.83894E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15644E-03 -3.8056 0.13044E-03 -3.8846 0.83378E+00 -0.0789 4 SO4-- 0.89224E-12 -12.0495 0.46028E-12 -12.3370 0.51587E+00 -0.2875 5 HCO3- 0.32187E-06 -6.4923 0.26877E-06 -6.5706 0.83503E+00 -0.0783 6 HS- 0.29048E-04 -4.5369 0.24223E-04 -4.6158 0.83391E+00 -0.0789 7 Al+++ 0.11023E-28 -28.9577 0.25081E-29 -29.6007 0.22754E+00 -0.6429 8 H4SiO4 0.71161E-03 -3.1478 0.71161E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14330E-06 -6.8438 0.73369E-07 -7.1345 0.51200E+00 -0.2907 10 Mg++ 0.22754E-10 -10.6429 0.11596E-10 -10.9357 0.50961E+00 -0.2928 11 Fe++ 0.62240E-13 -13.2059 0.31754E-13 -13.4982 0.51018E+00 -0.2923 12 K+ 0.16151E-03 -3.7918 0.13490E-03 -3.8700 0.83523E+00 -0.0782 13 Na+ 0.20534E-01 -1.6875 0.17118E-01 -1.7666 0.83363E+00 -0.0790 14 Mn++ 0.19877E-10 -10.7016 0.10150E-10 -10.9936 0.51061E+00 -0.2919 15 HPO4-- 0.48743E-07 -7.3121 0.25149E-07 -7.5995 0.51595E+00 -0.2874 16 HSiO3- 0.10991E-01 -1.9590 0.91638E-02 -2.0379 0.83378E+00 -0.0789 17 Ca(HSiO3)+ 0.18032E-07 -7.7440 0.15064E-07 -7.8221 0.83541E+00 -0.0781 18 Mg(HSiO3)+ 0.35467E-11 -11.4502 0.29630E-11 -11.5283 0.83541E+00 -0.0781 19 NaHSiO3,aq 0.24913E-02 -2.6036 0.24913E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67518E-16 -16.1706 0.56405E-16 -16.2487 0.83541E+00 -0.0781 22 HAlO2,aq 0.14898E-09 -9.8269 0.14898E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52754E-05 -5.2777 0.43905E-05 -5.3575 0.83225E+00 -0.0797 24 CH4,aq 0.13929E-04 -4.8561 0.13879E-04 -4.8576 0.99642E+00 -0.0016 25 C2H6,aq 0.30668E-14 -14.5133 0.30558E-14 -14.5149 0.99642E+00 -0.0016 29 CO,aq 0.11496E-16 -16.9394 0.11496E-16 -16.9394 0.10000E+01 0.0000 30 CO2,aq 0.41204E-10 -10.3851 0.41057E-10 -10.3866 0.99642E+00 -0.0016 31 CO3-2 0.63718E-06 -6.1957 0.32799E-06 -6.4841 0.51476E+00 -0.2884 32 CaCO3,aq 0.29473E-09 -9.5306 0.29473E-09 -9.5306 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.59476E-12 -12.2257 0.49687E-12 -12.3038 0.83541E+00 -0.0781 34 CaCl+ 0.18255E-10 -10.7386 0.15250E-10 -10.8167 0.83541E+00 -0.0781 35 CaCl2,aq 0.46316E-15 -15.3343 0.46316E-15 -15.3343 0.10000E+01 0.0000 36 CaOH+ 0.81735E-07 -7.0876 0.68282E-07 -7.1657 0.83541E+00 -0.0781 37 CaSO4,aq 0.10522E-16 -16.9779 0.10522E-16 -16.9779 0.10000E+01 0.0000 38 HCl,aq 0.18589E-14 -14.7307 0.18589E-14 -14.7307 0.10000E+01 0.0000 43 FeCl+ 0.77221E-17 -17.1123 0.64511E-17 -17.1904 0.83541E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16632E-10 -10.7791 0.13894E-10 -10.8572 0.83541E+00 -0.0781 48 HFeO2- 0.37245E-07 -7.4289 0.31054E-07 -7.5079 0.83378E+00 -0.0789 49 FeO+ 0.12275E-16 -16.9110 0.10255E-16 -16.9891 0.83541E+00 -0.0781 51 FeO2- 0.42110E-09 -9.3756 0.35110E-09 -9.4546 0.83378E+00 -0.0789 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10872E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.31157E-09 -9.5064 0.31157E-09 -9.5064 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11473E-14 -14.9403 0.95661E-15 -15.0193 0.83378E+00 -0.0789 58 MgCO3,aq 0.11640E-13 -13.9341 0.11640E-13 -13.9341 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.95856E-16 -16.0184 0.80079E-16 -16.0965 0.83541E+00 -0.0781 60 MgCl+ 0.26192E-14 -14.5818 0.21881E-14 -14.6599 0.83541E+00 -0.0781 61 MgOH+ 0.71567E-10 -10.1453 0.59788E-10 -10.2234 0.83541E+00 -0.0781 63 MnO,aq 0.18665E-08 -8.7290 0.18665E-08 -8.7290 0.10000E+01 0.0000 64 MnOH+ 0.49385E-09 -9.3064 0.41256E-09 -9.3845 0.83541E+00 -0.0781 65 MnO2-2 0.21845E-10 -10.6607 0.11245E-10 -10.9491 0.51476E+00 -0.2884 66 HMnO2- 0.22138E-09 -9.6549 0.18459E-09 -9.7338 0.83378E+00 -0.0789 69 MnCl+ 0.95912E-14 -14.0181 0.80126E-14 -14.0962 0.83541E+00 -0.0781 71 NaCl,aq 0.72907E-06 -6.1372 0.72907E-06 -6.1372 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95127E-02 -2.0217 0.79170E-02 -2.1014 0.83225E+00 -0.0797 79 HPO3-2 0.16777E-14 -14.7753 0.86358E-15 -15.0637 0.51476E+00 -0.2884 81 H2PO3- 0.15415E-18 -18.8121 0.12853E-18 -18.8910 0.83378E+00 -0.0789 82 H3PO4,aq 0.92941E-18 -18.0318 0.92941E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40027E-10 -10.3977 0.33406E-10 -10.4762 0.83459E+00 -0.0785 84 PO4-3 0.12117E-08 -8.9166 0.28988E-09 -9.5378 0.23924E+00 -0.6212 88 HP2O7-3 0.10377E-17 -17.9839 0.23638E-18 -18.6264 0.22778E+00 -0.6425 89 P2O7-4 0.10249E-16 -16.9893 0.76967E-18 -18.1137 0.75099E-01 -1.1244 90 H2S,aq 0.55340E-08 -8.2570 0.55142E-08 -8.2585 0.99642E+00 -0.0016 91 S2-2 0.23060E-14 -14.6371 0.11870E-14 -14.9255 0.51476E+00 -0.2884 97 SO3-2 0.13062E-17 -17.8840 0.68230E-18 -18.1660 0.52236E+00 -0.2820 99 HSO4- 0.38694E-19 -19.4124 0.32358E-19 -19.4900 0.83624E+00 -0.0777 Charge balance for all species = 0.3758E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9031104E-10 -.2311937E-01 -.2326074E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981180E+06 0.0000 3 Cl- 0.1564432E-03 0.1571726E-03 0.5562150E+01 6.2359 4 SO4-- 0.8922419E-12 -.1665688E-04 -.1597189E+01 7.9041 5 HCO3- 0.3218701E-06 0.1488863E-04 0.9068171E+00 3.5499 6 HS- 0.2904776E-04 0.4571017E-04 0.1508989E+01 5.5048 7 Al+++ 0.1102260E-28 0.5275591E-05 0.1420856E+00 0.7609 8 H4SiO4 0.7116099E-03 0.1419354E-01 0.1361747E+04 -3.1478 9 Ca++ 0.1432972E-06 0.2433776E-06 0.9736423E-02 13.1066 10 Mg++ 0.2275419E-10 0.9788299E-10 0.2375422E-05 9.3054 11 Fe++ 0.6223952E-13 0.3790438E-07 0.2113012E-02 6.7429 12 K+ 0.1615123E-03 0.1622888E-03 0.6334325E+01 6.2505 13 Na+ 0.2053390E-01 0.2312525E-01 0.5306820E+03 8.3540 14 Mn++ 0.1987702E-10 0.2623426E-08 0.1438648E-03 9.2475 15 HPO4-- 0.4874309E-07 0.4999479E-07 0.4789760E-02 12.6416 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1987019E+02 -.2029537E-01 -.1984989E+02 0.0000000E+00 2 H2O 0.4046577E+02 0.4872463E+02 -.8258856E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3328157E-01 -.1462226E-04 0.3329619E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3325606E-01 0.4012673E-04 -.3329619E-01 0.0000000E+00 7 Al+++ 0.3912887E+01 0.4631184E-05 0.3912882E+01 0.0000000E+00 8 H4SiO4 0.1249533E+02 0.1245982E-01 0.1248287E+02 0.0000000E+00 9 Ca++ 0.1380185E+01 0.2136493E-06 0.1380184E+01 0.0000000E+00 10 Mg++ 0.9523802E+00 0.8592671E-10 0.9523802E+00 0.0000000E+00 11 Fe++ 0.8556096E+00 0.3327441E-07 0.8556096E+00 0.0000000E+00 12 K+ 0.2547769E+00 0.1424654E-03 0.2546344E+00 0.0000000E+00 13 Na+ 0.1506451E+01 0.2030053E-01 0.1486151E+01 0.0000000E+00 14 Mn++ 0.2080630E-01 0.2302978E-08 0.2080630E-01 0.0000000E+00 15 HPO4-- 0.7101086E-02 0.4388799E-07 0.7101042E-02 0.0000000E+00 Chg. balance for solid moles: -.2567E-14 Mass of aqueous solution: 0.879444E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.485 0.172 389.4 2.590 29.71 149.5 andradite 0.1332 -0.876 67.68 1.830 5.163 17.58 grossular 0.3181E-01 -1.497 14.33 1.156 1.093 3.986 apatite-OH 0.2367E-02 -2.626 1.189 0.075 0.9070E-01 0.3778 clinochlore 0.1720 -0.764 95.61 1.980 7.294 36.37 daphnite 0.4930E-01 -1.307 35.17 1.546 2.683 10.66 chlorite-Mn 0.4161E-02 -2.381 2.950 0.470 0.2251 0.9402 diopside 0.5992E-01 -1.222 12.98 1.113 0.9899 3.966 hedenbergite 0.1535E-01 -1.814 3.808 0.581 0.2905 1.043 microcline 0.2230 -0.652 62.07 1.793 4.735 24.25 stilbite 0.7802 -0.108 549.8 2.740 41.95 256.5 stilpnomelane-Fe 0.6325E-01 -1.199 68.18 1.834 5.201 23.55 tr.625ac.25prg.125 0.8941E-02 -2.049 7.643 0.883 0.5830 2.460 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1846E-01 0.1846E-01 1.0000 -1.734 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1310.852326 g Volume = 531.118713 cm3 Porosity: -10.4198% V(tot) - V(min): -.50119E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1199.9990000 g log = 3.0792 Original solution: 1000.0103000 g Original solution / Rock added: 0.83 (Water/Rock Ratio), log = -0.0792 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0890 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9664E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4285E-08 1.0071 0.4700E-08 0.4666E-08 CH4,gas 0.1990E-01 1.0128 0.2195E-01 0.2167E-01 H2,gas 0.1368E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1483E-06 0.9958 0.1608E-06 0.1615E-06 S2,gas 0.4001E-29 1.0000 0.4357E-29 0.4357E-29 CO,gas 0.1667E-13 1.0000 0.1815E-13 0.1815E-13 SO3,gas 0.9070E-48 1.0000 0.9878E-48 0.9878E-48 SO2,gas 0.5117E-27 1.0000 0.5572E-27 0.5572E-27 HCl,gas 0.3014E-17 1.0000 0.3282E-17 0.3282E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.69 -10.33 -3.443 0.17635E+05 -8.328 3 CH4,gas 4.81 1.15 -3.66 -0.915 0.62470E+04 -1.659 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.74 -8.79 -4.397 0.15015E+05 -6.794 6 S2,gas -7.03 -38.39 -31.36 -4.825 0.53548E+05 -29.361 7 CO,gas 3.51 -12.23 -15.74 -4.843 0.26877E+05 -13.741 8 SO3,gas 17.43 -32.58 -50.01 -12.501 0.85383E+05 -48.005 9 SO2,gas 1.14 -28.12 -29.25 -7.801 0.49950E+05 -27.254 10 HCl,gas 5.48 -14.01 -19.48 -9.742 0.33268E+05 -17.484 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80743E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94123E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28383E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76234E+04 35 aragonite 0.99 -3.58 -4.57 -1.524 0.78045E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55855E+04 37 calcite 0.83 -3.58 -4.42 -1.473 0.75432E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70325E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82192E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68649E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70377E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65594E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36457E+04 66 diamond -3.11 -7.77 -4.66 -1.332 0.79619E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33651E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66053E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.77 -4.22 -1.206 0.72081E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60997E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59770E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16001E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22973E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82308E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61283E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53668E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36602E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20056E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92770E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40694E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43442E+04 143 pyrrhotite -4.24 -7.99 -3.75 -1.250 0.64028E+04 144 pyrrhotiteFe0.875 -6.00 -9.39 -3.39 -1.246 0.57856E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22475E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28303E+03 152 rhodonite 7.46 6.10 -1.36 -0.273 0.23268E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27394E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.77 -0.395 0.47223E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91032E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65757E+04 181 troilite-low -4.39 -7.99 -3.60 -1.200 0.61460E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80417E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34509E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66778E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60334E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73634E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57934E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61760E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66246E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52964E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.49 -4.53 -1.509 0.77287E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62641E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14892E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 1199.9990000 g New total amount of reactant added: 1299.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 10 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1299.9990000 Water: Moles liquid = 0.4817E+02 kg liquid = 0.8678E+00 Moles total = 0.3921E+02 kg total = 0.7064E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174610E-01 Osmotic coef. = 0.9688 True ionic strength = .2069785E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90316E-10 -10.0442 0.75769E-10 -10.1205 0.83893E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.15825E-03 -3.8006 0.13195E-03 -3.8796 0.83378E+00 -0.0789 4 SO4-- 0.90259E-12 -12.0445 0.46562E-12 -12.3320 0.51587E+00 -0.2875 5 HCO3- 0.32560E-06 -6.4873 0.27188E-06 -6.5656 0.83502E+00 -0.0783 6 HS- 0.29384E-04 -4.5319 0.24504E-04 -4.6108 0.83391E+00 -0.0789 7 Al+++ 0.11025E-28 -28.9576 0.25085E-29 -29.6006 0.22753E+00 -0.6430 8 H4SiO4 0.71161E-03 -3.1478 0.71161E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14331E-06 -6.8437 0.73376E-07 -7.1344 0.51200E+00 -0.2907 10 Mg++ 0.22757E-10 -10.6429 0.11597E-10 -10.9357 0.50961E+00 -0.2928 11 Fe++ 0.62247E-13 -13.2059 0.31757E-13 -13.4982 0.51018E+00 -0.2923 12 K+ 0.16152E-03 -3.7918 0.13491E-03 -3.8700 0.83522E+00 -0.0782 13 Na+ 0.20535E-01 -1.6875 0.17119E-01 -1.7665 0.83362E+00 -0.0790 14 Mn++ 0.19891E-10 -10.7013 0.10157E-10 -10.9933 0.51061E+00 -0.2919 15 HPO4-- 0.48739E-07 -7.3121 0.25146E-07 -7.5995 0.51594E+00 -0.2874 16 HSiO3- 0.10990E-01 -1.9590 0.91633E-02 -2.0379 0.83378E+00 -0.0789 17 Ca(HSiO3)+ 0.18033E-07 -7.7439 0.15065E-07 -7.8220 0.83541E+00 -0.0781 18 Mg(HSiO3)+ 0.35469E-11 -11.4501 0.29631E-11 -11.5283 0.83541E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67521E-16 -16.1706 0.56407E-16 -16.2487 0.83541E+00 -0.0781 22 HAlO2,aq 0.14897E-09 -9.8269 0.14897E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52751E-05 -5.2778 0.43902E-05 -5.3575 0.83225E+00 -0.0797 24 CH4,aq 0.14091E-04 -4.8511 0.14040E-04 -4.8526 0.99642E+00 -0.0016 25 C2H6,aq 0.31382E-14 -14.5033 0.31270E-14 -14.5049 0.99642E+00 -0.0016 29 CO,aq 0.11630E-16 -16.9344 0.11630E-16 -16.9344 0.10000E+01 0.0000 30 CO2,aq 0.41684E-10 -10.3800 0.41535E-10 -10.3816 0.99642E+00 -0.0016 31 CO3-2 0.64454E-06 -6.1908 0.33177E-06 -6.4792 0.51475E+00 -0.2884 32 CaCO3,aq 0.29816E-09 -9.5256 0.29816E-09 -9.5256 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.60172E-12 -12.2206 0.50268E-12 -12.2987 0.83541E+00 -0.0781 34 CaCl+ 0.18468E-10 -10.7336 0.15428E-10 -10.8117 0.83541E+00 -0.0781 35 CaCl2,aq 0.47399E-15 -15.3242 0.47399E-15 -15.3242 0.10000E+01 0.0000 36 CaOH+ 0.81739E-07 -7.0876 0.68286E-07 -7.1657 0.83541E+00 -0.0781 37 CaSO4,aq 0.10645E-16 -16.9729 0.10645E-16 -16.9729 0.10000E+01 0.0000 38 HCl,aq 0.18805E-14 -14.7257 0.18805E-14 -14.7257 0.10000E+01 0.0000 43 FeCl+ 0.78123E-17 -17.1072 0.65265E-17 -17.1853 0.83541E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16633E-10 -10.7790 0.13895E-10 -10.8571 0.83541E+00 -0.0781 48 HFeO2- 0.37243E-07 -7.4290 0.31052E-07 -7.5079 0.83378E+00 -0.0789 49 FeO+ 0.12276E-16 -16.9110 0.10255E-16 -16.9891 0.83541E+00 -0.0781 51 FeO2- 0.42108E-09 -9.3756 0.35109E-09 -9.4546 0.83378E+00 -0.0789 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9622 0.10872E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.31519E-09 -9.5014 0.31519E-09 -9.5014 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11607E-14 -14.9353 0.96775E-15 -15.0142 0.83378E+00 -0.0789 58 MgCO3,aq 0.11775E-13 -13.9290 0.11775E-13 -13.9290 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.96977E-16 -16.0133 0.81015E-16 -16.0914 0.83541E+00 -0.0781 60 MgCl+ 0.26498E-14 -14.5768 0.22136E-14 -14.6549 0.83541E+00 -0.0781 61 MgOH+ 0.71571E-10 -10.1453 0.59791E-10 -10.2234 0.83541E+00 -0.0781 63 MnO,aq 0.18676E-08 -8.7287 0.18676E-08 -8.7287 0.10000E+01 0.0000 64 MnOH+ 0.49417E-09 -9.3061 0.41283E-09 -9.3842 0.83541E+00 -0.0781 65 MnO2-2 0.21856E-10 -10.6604 0.11250E-10 -10.9488 0.51475E+00 -0.2884 66 HMnO2- 0.22150E-09 -9.6546 0.18469E-09 -9.7336 0.83378E+00 -0.0789 69 MnCl+ 0.97090E-14 -14.0128 0.81110E-14 -14.0909 0.83541E+00 -0.0781 71 NaCl,aq 0.73755E-06 -6.1322 0.73755E-06 -6.1322 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95122E-02 -2.0217 0.79166E-02 -2.1015 0.83225E+00 -0.0797 79 HPO3-2 0.16775E-14 -14.7753 0.86349E-15 -15.0637 0.51475E+00 -0.2884 81 H2PO3- 0.15414E-18 -18.8121 0.12852E-18 -18.8910 0.83378E+00 -0.0789 82 H3PO4,aq 0.92942E-18 -18.0318 0.92942E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40025E-10 -10.3977 0.33404E-10 -10.4762 0.83459E+00 -0.0785 84 PO4-3 0.12115E-08 -8.9167 0.28984E-09 -9.5378 0.23923E+00 -0.6212 88 HP2O7-3 0.10376E-17 -17.9840 0.23635E-18 -18.6265 0.22778E+00 -0.6425 89 P2O7-4 0.10247E-16 -16.9894 0.76952E-18 -18.1138 0.75094E-01 -1.1244 90 H2S,aq 0.55984E-08 -8.2519 0.55783E-08 -8.2535 0.99642E+00 -0.0016 91 S2-2 0.23598E-14 -14.6271 0.12147E-14 -14.9155 0.51475E+00 -0.2884 97 SO3-2 0.13213E-17 -17.8790 0.69020E-18 -18.1610 0.52235E+00 -0.2820 99 HSO4- 0.39145E-19 -19.4073 0.32734E-19 -19.4850 0.83624E+00 -0.0777 Charge balance for all species = 0.3801E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9031630E-10 -.2311844E-01 -.2325980E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981179E+06 0.0000 3 Cl- 0.1582543E-03 0.1589922E-03 0.5626543E+01 6.2409 4 SO4-- 0.9025921E-12 -.1681811E-04 -.1612649E+01 7.9090 5 HCO3- 0.3256015E-06 0.1506099E-04 0.9173154E+00 3.5549 6 HS- 0.2938405E-04 0.4620775E-04 0.1525415E+01 5.5097 7 Al+++ 0.1102456E-28 0.5275213E-05 0.1420754E+00 0.7609 8 H4SiO4 0.7116150E-03 0.1419308E-01 0.1361703E+04 -3.1478 9 Ca++ 0.1433141E-06 0.2434033E-06 0.9737451E-02 13.1066 10 Mg++ 0.2275686E-10 0.9788896E-10 0.2375567E-05 9.3054 11 Fe++ 0.6224712E-13 0.3790237E-07 0.2112900E-02 6.7429 12 K+ 0.1615217E-03 0.1622982E-03 0.6334692E+01 6.2505 13 Na+ 0.2053510E-01 0.2312647E-01 0.5307101E+03 8.3540 14 Mn++ 0.1989131E-10 0.2625002E-08 0.1439512E-03 9.2478 15 HPO4-- 0.4873912E-07 0.4999068E-07 0.4789366E-02 12.6415 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2152604E+02 -.2006229E-01 -.2150598E+02 0.0000000E+00 2 H2O 0.3921223E+02 0.4816699E+02 -.8954761E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3605291E-01 -.1459483E-04 0.3606750E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3602740E-01 0.4009930E-04 -.3606750E-01 0.0000000E+00 7 Al+++ 0.4238961E+01 0.4577854E-05 0.4238956E+01 0.0000000E+00 8 H4SiO4 0.1353661E+02 0.1231682E-01 0.1352429E+02 0.0000000E+00 9 Ca++ 0.1495199E+01 0.2112265E-06 0.1495199E+01 0.0000000E+00 10 Mg++ 0.1031745E+01 0.8494849E-10 0.1031745E+01 0.0000000E+00 11 Fe++ 0.9269105E+00 0.3289185E-07 0.9269104E+00 0.0000000E+00 12 K+ 0.2760083E+00 0.1408431E-03 0.2758674E+00 0.0000000E+00 13 Na+ 0.1631976E+01 0.2006926E-01 0.1611906E+01 0.0000000E+00 14 Mn++ 0.2254016E-01 0.2277989E-08 0.2254016E-01 0.0000000E+00 15 HPO4-- 0.7692844E-02 0.4338214E-07 0.7692800E-02 0.0000000E+00 Chg. balance for solid moles: -.9021E-16 Mass of aqueous solution: 0.869379E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1299.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.611 0.207 422.4 2.626 29.74 162.1 andradite 0.1443 -0.841 73.32 1.865 5.163 19.05 grossular 0.3445E-01 -1.463 15.52 1.191 1.093 4.318 apatite-OH 0.2564E-02 -2.591 1.288 0.110 0.9070E-01 0.4093 clinochlore 0.1862 -0.730 103.5 2.015 7.289 39.37 daphnite 0.5337E-01 -1.273 38.08 1.581 2.682 11.54 chlorite-Mn 0.4508E-02 -2.346 3.196 0.505 0.2251 1.019 diopside 0.6570E-01 -1.182 14.23 1.153 1.002 4.349 hedenbergite 0.1683E-01 -1.774 4.176 0.621 0.2941 1.144 microcline 0.2416 -0.617 67.25 1.828 4.735 26.27 stilbite 0.8444 -0.073 595.1 2.775 41.90 277.6 stilpnomelane-Fe 0.6853E-01 -1.164 73.87 1.868 5.202 25.52 tr.625ac.25prg.125 0.9623E-02 -2.017 8.225 0.915 0.5792 2.647 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1847E-01 0.1847E-01 1.0000 -1.734 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1420.107804 g Volume = 575.325070 cm3 Porosity: -10.4272% V(tot) - V(min): -.54325E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1299.9990000 g log = 3.1139 Original solution: 1000.0103000 g Original solution / Rock added: 0.77 (Water/Rock Ratio), log = -0.1139 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0893 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9662E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4334E-08 1.0071 0.4754E-08 0.4721E-08 CH4,gas 0.2012E-01 1.0128 0.2220E-01 0.2192E-01 H2,gas 0.1368E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1500E-06 0.9958 0.1627E-06 0.1634E-06 S2,gas 0.4093E-29 1.0000 0.4459E-29 0.4459E-29 CO,gas 0.1686E-13 1.0000 0.1836E-13 0.1836E-13 SO3,gas 0.9174E-48 1.0000 0.9993E-48 0.9993E-48 SO2,gas 0.5175E-27 1.0000 0.5637E-27 0.5637E-27 HCl,gas 0.3048E-17 1.0000 0.3320E-17 0.3320E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 -0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-09 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.69 -10.32 -3.441 0.17626E+05 -8.323 3 CH4,gas 4.81 1.16 -3.65 -0.913 0.62384E+04 -1.654 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.73 -8.79 -4.394 0.15006E+05 -6.789 6 S2,gas -7.03 -38.38 -31.35 -4.823 0.53531E+05 -29.351 7 CO,gas 3.51 -12.23 -15.74 -4.842 0.26869E+05 -13.736 8 SO3,gas 17.43 -32.57 -50.00 -12.500 0.85374E+05 -48.000 9 SO2,gas 1.14 -28.11 -29.25 -7.800 0.49942E+05 -27.249 10 HCl,gas 5.48 -14.00 -19.48 -9.739 0.33260E+05 -17.479 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80730E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94123E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28383E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.58 -4.57 -1.522 0.77959E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.58 -4.41 -1.471 0.75346E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70325E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82192E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70377E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65590E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36457E+04 66 diamond -3.11 -7.77 -4.66 -1.331 0.79534E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33651E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66053E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.77 -4.22 -1.205 0.71995E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60997E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59770E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16001E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22973E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82303E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61283E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53668E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36602E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20056E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92770E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40694E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43443E+04 143 pyrrhotite -4.24 -7.99 -3.74 -1.248 0.63943E+04 144 pyrrhotiteFe0.875 -6.00 -9.38 -3.38 -1.244 0.57770E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22471E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28302E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23263E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27394E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.77 -0.395 0.47214E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91032E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65757E+04 181 troilite-low -4.39 -7.99 -3.59 -1.198 0.61374E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80419E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34509E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66779E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60334E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66128E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52964E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.48 -4.52 -1.507 0.77197E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 1299.9990000 g New total amount of reactant added: 1399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1399.9990000 Water: Moles liquid = 0.4761E+02 kg liquid = 0.8578E+00 Moles total = 0.3796E+02 kg total = 0.6838E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174767E-01 Osmotic coef. = 0.9688 True ionic strength = .2069908E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90322E-10 -10.0442 0.75774E-10 -10.1205 0.83893E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16011E-03 -3.7956 0.13349E-03 -3.8745 0.83378E+00 -0.0789 4 SO4-- 0.91318E-12 -12.0394 0.47107E-12 -12.3269 0.51586E+00 -0.2875 5 HCO3- 0.32942E-06 -6.4823 0.27507E-06 -6.5606 0.83502E+00 -0.0783 6 HS- 0.29728E-04 -4.5268 0.24790E-04 -4.6057 0.83390E+00 -0.0789 7 Al+++ 0.11027E-28 -28.9576 0.25088E-29 -29.6005 0.22753E+00 -0.6430 8 H4SiO4 0.71162E-03 -3.1478 0.71162E-03 -3.1478 0.10000E+01 0.0000 9 Ca++ 0.14333E-06 -6.8437 0.73384E-07 -7.1344 0.51199E+00 -0.2907 10 Mg++ 0.22760E-10 -10.6428 0.11598E-10 -10.9356 0.50960E+00 -0.2928 11 Fe++ 0.62255E-13 -13.2058 0.31760E-13 -13.4981 0.51017E+00 -0.2923 12 K+ 0.16153E-03 -3.7917 0.13491E-03 -3.8699 0.83522E+00 -0.0782 13 Na+ 0.20536E-01 -1.6875 0.17119E-01 -1.7665 0.83362E+00 -0.0790 14 Mn++ 0.19904E-10 -10.7011 0.10163E-10 -10.9930 0.51060E+00 -0.2919 15 HPO4-- 0.48735E-07 -7.3122 0.25144E-07 -7.5996 0.51593E+00 -0.2874 16 HSiO3- 0.10990E-01 -1.9590 0.91629E-02 -2.0380 0.83378E+00 -0.0789 17 Ca(HSiO3)+ 0.18034E-07 -7.7439 0.15065E-07 -7.8220 0.83540E+00 -0.0781 18 Mg(HSiO3)+ 0.35471E-11 -11.4501 0.29633E-11 -11.5282 0.83540E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67523E-16 -16.1705 0.56409E-16 -16.2486 0.83540E+00 -0.0781 22 HAlO2,aq 0.14897E-09 -9.8269 0.14897E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52747E-05 -5.2778 0.43899E-05 -5.3575 0.83225E+00 -0.0797 24 CH4,aq 0.14256E-04 -4.8460 0.14205E-04 -4.8476 0.99642E+00 -0.0016 25 C2H6,aq 0.32122E-14 -14.4932 0.32007E-14 -14.4948 0.99642E+00 -0.0016 29 CO,aq 0.11766E-16 -16.9294 0.11766E-16 -16.9294 0.10000E+01 0.0000 30 CO2,aq 0.42175E-10 -10.3749 0.42024E-10 -10.3765 0.99642E+00 -0.0016 31 CO3-2 0.65206E-06 -6.1857 0.33564E-06 -6.4741 0.51474E+00 -0.2884 32 CaCO3,aq 0.30167E-09 -9.5205 0.30167E-09 -9.5205 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.60883E-12 -12.2155 0.50862E-12 -12.2936 0.83540E+00 -0.0781 34 CaCl+ 0.18686E-10 -10.7285 0.15610E-10 -10.8066 0.83540E+00 -0.0781 35 CaCl2,aq 0.48521E-15 -15.3141 0.48521E-15 -15.3141 0.10000E+01 0.0000 36 CaOH+ 0.81744E-07 -7.0875 0.68289E-07 -7.1656 0.83540E+00 -0.0781 37 CaSO4,aq 0.10771E-16 -16.9678 0.10771E-16 -16.9678 0.10000E+01 0.0000 38 HCl,aq 0.19027E-14 -14.7206 0.19027E-14 -14.7206 0.10000E+01 0.0000 43 FeCl+ 0.79047E-17 -17.1021 0.66036E-17 -17.1802 0.83540E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16634E-10 -10.7790 0.13896E-10 -10.8571 0.83540E+00 -0.0781 48 HFeO2- 0.37241E-07 -7.4290 0.31050E-07 -7.5079 0.83378E+00 -0.0789 49 FeO+ 0.12277E-16 -16.9109 0.10256E-16 -16.9890 0.83540E+00 -0.0781 51 FeO2- 0.42106E-09 -9.3757 0.35107E-09 -9.4546 0.83378E+00 -0.0789 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.31890E-09 -9.4963 0.31890E-09 -9.4963 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11743E-14 -14.9302 0.97914E-15 -15.0092 0.83378E+00 -0.0789 58 MgCO3,aq 0.11914E-13 -13.9239 0.11914E-13 -13.9239 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.98124E-16 -16.0082 0.81973E-16 -16.0863 0.83540E+00 -0.0781 60 MgCl+ 0.26811E-14 -14.5717 0.22398E-14 -14.6498 0.83540E+00 -0.0781 61 MgOH+ 0.71575E-10 -10.1452 0.59794E-10 -10.2233 0.83540E+00 -0.0781 63 MnO,aq 0.18685E-08 -8.7285 0.18685E-08 -8.7285 0.10000E+01 0.0000 64 MnOH+ 0.49445E-09 -9.3059 0.41306E-09 -9.3840 0.83540E+00 -0.0781 65 MnO2-2 0.21865E-10 -10.6603 0.11255E-10 -10.9487 0.51474E+00 -0.2884 66 HMnO2- 0.22161E-09 -9.6544 0.18477E-09 -9.7334 0.83378E+00 -0.0789 69 MnCl+ 0.98289E-14 -14.0075 0.82111E-14 -14.0856 0.83540E+00 -0.0781 71 NaCl,aq 0.74623E-06 -6.1271 0.74623E-06 -6.1271 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95118E-02 -2.0217 0.79161E-02 -2.1015 0.83225E+00 -0.0797 79 HPO3-2 0.16773E-14 -14.7754 0.86339E-15 -15.0638 0.51474E+00 -0.2884 81 H2PO3- 0.15413E-18 -18.8121 0.12851E-18 -18.8911 0.83378E+00 -0.0789 82 H3PO4,aq 0.92943E-18 -18.0318 0.92943E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40023E-10 -10.3977 0.33403E-10 -10.4762 0.83458E+00 -0.0785 84 PO4-3 0.12114E-08 -8.9167 0.28979E-09 -9.5379 0.23922E+00 -0.6212 88 HP2O7-3 0.10375E-17 -17.9840 0.23631E-18 -18.6265 0.22777E+00 -0.6425 89 P2O7-4 0.10246E-16 -16.9894 0.76937E-18 -18.1139 0.75090E-01 -1.1244 90 H2S,aq 0.56642E-08 -8.2469 0.56439E-08 -8.2484 0.99642E+00 -0.0016 91 S2-2 0.24154E-14 -14.6170 0.12433E-14 -14.9054 0.51474E+00 -0.2884 97 SO3-2 0.13368E-17 -17.8739 0.69827E-18 -18.1560 0.52234E+00 -0.2820 99 HSO4- 0.39606E-19 -19.4022 0.33120E-19 -19.4799 0.83624E+00 -0.0777 Charge balance for all species = 0.3845E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9032164E-10 -.2311747E-01 -.2325883E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981178E+06 0.0000 3 Cl- 0.1601079E-03 0.1608545E-03 0.5692445E+01 6.2459 4 SO4-- 0.9131755E-12 -.1698313E-04 -.1628472E+01 7.9140 5 HCO3- 0.3294172E-06 0.1523740E-04 0.9280597E+00 3.5599 6 HS- 0.2972821E-04 0.4671701E-04 0.1542227E+01 5.5148 7 Al+++ 0.1102659E-28 0.5274846E-05 0.1420655E+00 0.7609 8 H4SiO4 0.7116193E-03 0.1419260E-01 0.1361657E+04 -3.1478 9 Ca++ 0.1433314E-06 0.2434298E-06 0.9738509E-02 13.1066 10 Mg++ 0.2275959E-10 0.9789624E-10 0.2375743E-05 9.3054 11 Fe++ 0.6225488E-13 0.3790035E-07 0.2112787E-02 6.7428 12 K+ 0.1615313E-03 0.1623078E-03 0.6335066E+01 6.2505 13 Na+ 0.2053632E-01 0.2312771E-01 0.5307386E+03 8.3540 14 Mn++ 0.1990397E-10 0.2626358E-08 0.1440255E-03 9.2480 15 HPO4-- 0.4873499E-07 0.4998639E-07 0.4788955E-02 12.6414 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2318189E+02 -.1982919E-01 -.2316206E+02 0.0000000E+00 2 H2O 0.3795869E+02 0.4760935E+02 -.9650665E+01 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.3882425E-01 -.1456742E-04 0.3883882E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.3879874E-01 0.4007189E-04 -.3883882E-01 0.0000000E+00 7 Al+++ 0.4565035E+01 0.4524541E-05 0.4565030E+01 0.0000000E+00 8 H4SiO4 0.1457789E+02 0.1217382E-01 0.1456571E+02 0.0000000E+00 9 Ca++ 0.1610213E+01 0.2088038E-06 0.1610213E+01 0.0000000E+00 10 Mg++ 0.1111110E+01 0.8397127E-10 0.1111110E+01 0.0000000E+00 11 Fe++ 0.9982113E+00 0.3250932E-07 0.9982113E+00 0.0000000E+00 12 K+ 0.2972397E+00 0.1392208E-03 0.2971005E+00 0.0000000E+00 13 Na+ 0.1757500E+01 0.1983798E-01 0.1737662E+01 0.0000000E+00 14 Mn++ 0.2427402E-01 0.2252779E-08 0.2427401E-01 0.0000000E+00 15 HPO4-- 0.8284601E-02 0.4287622E-07 0.8284558E-02 0.0000000E+00 Chg. balance for solid moles: -.9923E-15 Mass of aqueous solution: 0.859314E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.736 0.240 455.3 2.658 29.77 174.8 andradite 0.1554 -0.809 78.95 1.897 5.162 20.51 grossular 0.3710E-01 -1.431 16.71 1.223 1.093 4.650 apatite-OH 0.2762E-02 -2.559 1.387 0.142 0.9070E-01 0.4408 clinochlore 0.2005 -0.698 111.4 2.047 7.285 42.38 daphnite 0.5745E-01 -1.241 40.99 1.613 2.680 12.42 chlorite-Mn 0.4855E-02 -2.314 3.442 0.537 0.2251 1.097 diopside 0.7149E-01 -1.146 15.48 1.190 1.012 4.731 hedenbergite 0.1831E-01 -1.737 4.544 0.657 0.2971 1.245 microcline 0.2602 -0.585 72.42 1.860 4.735 28.29 stilbite 0.9086 -0.042 640.3 2.806 41.87 298.7 stilpnomelane-Fe 0.7381E-01 -1.132 79.57 1.901 5.203 27.49 tr.625ac.25prg.125 0.1030E-01 -1.987 8.808 0.945 0.5759 2.835 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1848E-01 0.1848E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1529.363283 g Volume = 619.531427 cm3 Porosity: -10.4335% V(tot) - V(min): -.58532E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1399.9990000 g log = 3.1461 Original solution: 1000.0103000 g Original solution / Rock added: 0.71 (Water/Rock Ratio), log = -0.1461 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0896 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9660E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4384E-08 1.0071 0.4810E-08 0.4776E-08 CH4,gas 0.2036E-01 1.0128 0.2246E-01 0.2218E-01 H2,gas 0.1368E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1517E-06 0.9958 0.1646E-06 0.1653E-06 S2,gas 0.4190E-29 1.0000 0.4565E-29 0.4565E-29 CO,gas 0.1705E-13 1.0000 0.1858E-13 0.1858E-13 SO3,gas 0.9281E-48 1.0000 0.1011E-47 0.1011E-47 SO2,gas 0.5235E-27 1.0000 0.5704E-27 0.5704E-27 HCl,gas 0.3083E-17 1.0000 0.3360E-17 0.3360E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.68 -10.32 -3.439 0.17617E+05 -8.318 3 CH4,gas 4.81 1.16 -3.65 -0.912 0.62298E+04 -1.649 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.826 5 H2S,gas -5.94 -14.73 -8.78 -4.392 0.14998E+05 -6.784 6 S2,gas -7.03 -38.37 -31.34 -4.822 0.53513E+05 -29.341 7 CO,gas 3.51 -12.22 -15.73 -4.840 0.26860E+05 -13.731 8 SO3,gas 17.43 -32.57 -50.00 -12.499 0.85365E+05 -47.995 9 SO2,gas 1.14 -28.11 -29.24 -7.798 0.49933E+05 -27.244 10 HCl,gas 5.48 -14.00 -19.47 -9.737 0.33251E+05 -17.474 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80718E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94124E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.57 -4.56 -1.520 0.77873E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.57 -4.41 -1.469 0.75259E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52887E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70325E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70377E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65586E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36457E+04 66 diamond -3.11 -7.76 -4.65 -1.329 0.79447E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66054E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.76 -4.21 -1.203 0.71909E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59770E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16001E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58936E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82300E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61284E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53668E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20056E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92771E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40695E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43444E+04 143 pyrrhotite -4.24 -7.98 -3.74 -1.247 0.63856E+04 144 pyrrhotiteFe0.875 -6.00 -9.38 -3.38 -1.242 0.57684E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22467E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28302E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23259E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27394E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47206E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91031E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65757E+04 181 troilite-low -4.39 -7.98 -3.59 -1.196 0.61288E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80420E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66779E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60333E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.48 -4.52 -1.505 0.77106E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 1399.9990000 g New total amount of reactant added: 1499.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1499.9990000 Water: Moles liquid = 0.4705E+02 kg liquid = 0.8477E+00 Moles total = 0.3671E+02 kg total = 0.6613E+00 Activity = 1.0000 Stoichiometric ionic strength = .1174927E-01 Osmotic coef. = 0.9688 True ionic strength = .2070035E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90327E-10 -10.0442 0.75778E-10 -10.1205 0.83893E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16201E-03 -3.7905 0.13508E-03 -3.8694 0.83377E+00 -0.0790 4 SO4-- 0.92400E-12 -12.0343 0.47665E-12 -12.3218 0.51585E+00 -0.2875 5 HCO3- 0.33332E-06 -6.4771 0.27833E-06 -6.5554 0.83502E+00 -0.0783 6 HS- 0.30081E-04 -4.5217 0.25084E-04 -4.6006 0.83390E+00 -0.0789 7 Al+++ 0.11029E-28 -28.9575 0.25092E-29 -29.6005 0.22752E+00 -0.6430 8 H4SiO4 0.71162E-03 -3.1477 0.71162E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14335E-06 -6.8436 0.73392E-07 -7.1344 0.51198E+00 -0.2907 10 Mg++ 0.22762E-10 -10.6428 0.11599E-10 -10.9356 0.50959E+00 -0.2928 11 Fe++ 0.62263E-13 -13.2058 0.31764E-13 -13.4981 0.51016E+00 -0.2923 12 K+ 0.16154E-03 -3.7917 0.13492E-03 -3.8699 0.83522E+00 -0.0782 13 Na+ 0.20538E-01 -1.6875 0.17120E-01 -1.7665 0.83362E+00 -0.0790 14 Mn++ 0.19915E-10 -10.7008 0.10169E-10 -10.9927 0.51059E+00 -0.2919 15 HPO4-- 0.48731E-07 -7.3122 0.25141E-07 -7.5996 0.51592E+00 -0.2874 16 HSiO3- 0.10989E-01 -1.9590 0.91624E-02 -2.0380 0.83377E+00 -0.0790 17 Ca(HSiO3)+ 0.18035E-07 -7.7439 0.15066E-07 -7.8220 0.83540E+00 -0.0781 18 Mg(HSiO3)+ 0.35473E-11 -11.4501 0.29635E-11 -11.5282 0.83540E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67527E-16 -16.1705 0.56412E-16 -16.2486 0.83540E+00 -0.0781 22 HAlO2,aq 0.14897E-09 -9.8269 0.14897E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52743E-05 -5.2778 0.43895E-05 -5.3576 0.83224E+00 -0.0797 24 CH4,aq 0.14425E-04 -4.8409 0.14373E-04 -4.8425 0.99642E+00 -0.0016 25 C2H6,aq 0.32889E-14 -14.4830 0.32771E-14 -14.4845 0.99642E+00 -0.0016 29 CO,aq 0.11906E-16 -16.9242 0.11906E-16 -16.9242 0.10000E+01 0.0000 30 CO2,aq 0.42677E-10 -10.3698 0.42524E-10 -10.3714 0.99642E+00 -0.0016 31 CO3-2 0.65976E-06 -6.1806 0.33960E-06 -6.4690 0.51473E+00 -0.2884 32 CaCO3,aq 0.30526E-09 -9.5153 0.30526E-09 -9.5153 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.61611E-12 -12.2103 0.51470E-12 -12.2884 0.83540E+00 -0.0781 34 CaCl+ 0.18910E-10 -10.7233 0.15797E-10 -10.8014 0.83540E+00 -0.0781 35 CaCl2,aq 0.49683E-15 -15.3038 0.49683E-15 -15.3038 0.10000E+01 0.0000 36 CaOH+ 0.81748E-07 -7.0875 0.68292E-07 -7.1656 0.83540E+00 -0.0781 37 CaSO4,aq 0.10900E-16 -16.9626 0.10900E-16 -16.9626 0.10000E+01 0.0000 38 HCl,aq 0.19253E-14 -14.7155 0.19253E-14 -14.7155 0.10000E+01 0.0000 43 FeCl+ 0.79992E-17 -17.0970 0.66826E-17 -17.1751 0.83540E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16635E-10 -10.7790 0.13897E-10 -10.8571 0.83540E+00 -0.0781 48 HFeO2- 0.37238E-07 -7.4290 0.31048E-07 -7.5080 0.83377E+00 -0.0790 49 FeO+ 0.12277E-16 -16.9109 0.10257E-16 -16.9890 0.83540E+00 -0.0781 51 FeO2- 0.42104E-09 -9.3757 0.35105E-09 -9.4546 0.83377E+00 -0.0790 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.32270E-09 -9.4912 0.32270E-09 -9.4912 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.11883E-14 -14.9251 0.99078E-15 -15.0040 0.83377E+00 -0.0790 58 MgCO3,aq 0.12056E-13 -13.9188 0.12056E-13 -13.9188 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.99297E-16 -16.0031 0.82953E-16 -16.0812 0.83540E+00 -0.0781 60 MgCl+ 0.27131E-14 -14.5665 0.22666E-14 -14.6446 0.83540E+00 -0.0781 61 MgOH+ 0.71579E-10 -10.1452 0.59797E-10 -10.2233 0.83540E+00 -0.0781 63 MnO,aq 0.18693E-08 -8.7283 0.18693E-08 -8.7283 0.10000E+01 0.0000 64 MnOH+ 0.49470E-09 -9.3057 0.41327E-09 -9.3838 0.83540E+00 -0.0781 65 MnO2-2 0.21872E-10 -10.6601 0.11258E-10 -10.9485 0.51473E+00 -0.2884 66 HMnO2- 0.22169E-09 -9.6542 0.18484E-09 -9.7332 0.83377E+00 -0.0790 69 MnCl+ 0.99509E-14 -14.0021 0.83129E-14 -14.0802 0.83540E+00 -0.0781 71 NaCl,aq 0.75511E-06 -6.1220 0.75511E-06 -6.1220 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95113E-02 -2.0218 0.79157E-02 -2.1015 0.83224E+00 -0.0797 79 HPO3-2 0.16772E-14 -14.7754 0.86329E-15 -15.0638 0.51473E+00 -0.2884 81 H2PO3- 0.15412E-18 -18.8121 0.12850E-18 -18.8911 0.83377E+00 -0.0790 82 H3PO4,aq 0.92944E-18 -18.0318 0.92944E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40022E-10 -10.3977 0.33401E-10 -10.4762 0.83458E+00 -0.0785 84 PO4-3 0.12112E-08 -8.9168 0.28974E-09 -9.5380 0.23922E+00 -0.6212 88 HP2O7-3 0.10374E-17 -17.9841 0.23628E-18 -18.6266 0.22776E+00 -0.6425 89 P2O7-4 0.10244E-16 -16.9895 0.76921E-18 -18.1140 0.75085E-01 -1.1244 90 H2S,aq 0.57317E-08 -8.2417 0.57111E-08 -8.2433 0.99642E+00 -0.0016 91 S2-2 0.24731E-14 -14.6068 0.12730E-14 -14.8952 0.51473E+00 -0.2884 97 SO3-2 0.13526E-17 -17.8688 0.70653E-18 -18.1509 0.52233E+00 -0.2821 99 HSO4- 0.40077E-19 -19.3971 0.33514E-19 -19.4748 0.83623E+00 -0.0777 Charge balance for all species = 0.3890E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9032709E-10 -.2311648E-01 -.2325782E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981178E+06 0.0000 3 Cl- 0.1620054E-03 0.1627608E-03 0.5759909E+01 6.2510 4 SO4-- 0.9240021E-12 -.1715208E-04 -.1644672E+01 7.9191 5 HCO3- 0.3333207E-06 0.1541799E-04 0.9390586E+00 3.5650 6 HS- 0.3008054E-04 0.4723835E-04 0.1559437E+01 5.5199 7 Al+++ 0.1102869E-28 0.5274487E-05 0.1420558E+00 0.7609 8 H4SiO4 0.7116231E-03 0.1419210E-01 0.1361609E+04 -3.1477 9 Ca++ 0.1433492E-06 0.2434569E-06 0.9739596E-02 13.1066 10 Mg++ 0.2276241E-10 0.9790317E-10 0.2375911E-05 9.3054 11 Fe++ 0.6226282E-13 0.3789830E-07 0.2112673E-02 6.7428 12 K+ 0.1615411E-03 0.1623176E-03 0.6335447E+01 6.2505 13 Na+ 0.2053756E-01 0.2312898E-01 0.5307676E+03 8.3540 14 Mn++ 0.1991533E-10 0.2627536E-08 0.1440901E-03 9.2482 15 HPO4-- 0.4873070E-07 0.4998195E-07 0.4788529E-02 12.6413 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2483774E+02 -.1959610E-01 -.2481815E+02 0.0000000E+00 2 H2O 0.3670515E+02 0.4705172E+02 -.1034657E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4159559E-01 -.1454001E-04 0.4161013E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4157009E-01 0.4004448E-04 -.4161013E-01 0.0000000E+00 7 Al+++ 0.4891109E+01 0.4471241E-05 0.4891105E+01 0.0000000E+00 8 H4SiO4 0.1561916E+02 0.1203080E-01 0.1560713E+02 0.0000000E+00 9 Ca++ 0.1725227E+01 0.2063812E-06 0.1725227E+01 0.0000000E+00 10 Mg++ 0.1190475E+01 0.8299361E-10 0.1190475E+01 0.0000000E+00 11 Fe++ 0.1069512E+01 0.3212681E-07 0.1069512E+01 0.0000000E+00 12 K+ 0.3184711E+00 0.1375984E-03 0.3183335E+00 0.0000000E+00 13 Na+ 0.1883024E+01 0.1960670E-01 0.1863418E+01 0.0000000E+00 14 Mn++ 0.2600788E-01 0.2227392E-08 0.2600787E-01 0.0000000E+00 15 HPO4-- 0.8876359E-02 0.4237026E-07 0.8876317E-02 0.0000000E+00 Chg. balance for solid moles: -.1169E-14 Mass of aqueous solution: 0.849249E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1499.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.862 0.270 488.3 2.689 29.80 187.4 andradite 0.1664 -0.779 84.58 1.927 5.162 21.97 grossular 0.3975E-01 -1.401 17.90 1.253 1.093 4.982 apatite-OH 0.2959E-02 -2.529 1.486 0.172 0.9070E-01 0.4723 clinochlore 0.2147 -0.668 119.3 2.077 7.282 45.39 daphnite 0.6152E-01 -1.211 43.90 1.642 2.679 13.30 chlorite-Mn 0.5202E-02 -2.284 3.688 0.567 0.2251 1.175 diopside 0.7727E-01 -1.112 16.73 1.224 1.021 5.114 hedenbergite 0.1980E-01 -1.703 4.911 0.691 0.2997 1.345 microcline 0.2788 -0.555 77.60 1.890 4.736 30.31 stilbite 0.9728 -0.012 685.6 2.836 41.84 319.8 stilpnomelane-Fe 0.7910E-01 -1.102 85.26 1.931 5.203 29.45 tr.625ac.25prg.125 0.1099E-01 -1.959 9.390 0.973 0.5730 3.022 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1848E-01 0.1848E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1638.618763 g Volume = 663.737784 cm3 Porosity: -10.4390% V(tot) - V(min): -.62738E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1499.9990000 g log = 3.1761 Original solution: 1000.0103000 g Original solution / Rock added: 0.67 (Water/Rock Ratio), log = -0.1761 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0898 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9657E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4435E-08 1.0071 0.4868E-08 0.4833E-08 CH4,gas 0.2059E-01 1.0128 0.2273E-01 0.2244E-01 H2,gas 0.1367E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1535E-06 0.9958 0.1666E-06 0.1673E-06 S2,gas 0.4289E-29 1.0000 0.4674E-29 0.4674E-29 CO,gas 0.1725E-13 1.0000 0.1880E-13 0.1880E-13 SO3,gas 0.9389E-48 1.0000 0.1023E-47 0.1023E-47 SO2,gas 0.5296E-27 1.0000 0.5772E-27 0.5772E-27 HCl,gas 0.3119E-17 1.0000 0.3400E-17 0.3400E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.68 -10.31 -3.438 0.17609E+05 -8.313 3 CH4,gas 4.81 1.17 -3.64 -0.911 0.62210E+04 -1.643 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65336E+04 -1.827 5 H2S,gas -5.94 -14.72 -8.78 -4.389 0.14989E+05 -6.778 6 S2,gas -7.03 -38.36 -31.33 -4.820 0.53496E+05 -29.330 7 CO,gas 3.51 -12.22 -15.73 -4.839 0.26851E+05 -13.726 8 SO3,gas 17.43 -32.56 -49.99 -12.498 0.85357E+05 -47.990 9 SO2,gas 1.14 -28.10 -29.24 -7.797 0.49924E+05 -27.239 10 HCl,gas 5.48 -13.99 -19.47 -9.734 0.33242E+05 -17.469 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80709E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94124E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.57 -4.56 -1.519 0.77785E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.57 -4.40 -1.468 0.75172E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65583E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.76 -4.65 -1.328 0.79359E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66054E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.76 -4.21 -1.202 0.71821E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82296E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61284E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53669E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20056E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92771E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40696E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43444E+04 143 pyrrhotite -4.24 -7.98 -3.73 -1.245 0.63768E+04 144 pyrrhotiteFe0.875 -6.00 -9.37 -3.37 -1.241 0.57596E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22464E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28302E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23256E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47200E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91031E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65757E+04 181 troilite-low -4.39 -7.98 -3.58 -1.195 0.61200E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80422E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66779E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60333E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.47 -4.51 -1.503 0.77015E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 1499.9990000 g New total amount of reactant added: 1599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1599.9990000 Water: Moles liquid = 0.4650E+02 kg liquid = 0.8377E+00 Moles total = 0.3545E+02 kg total = 0.6387E+00 Activity = 1.0000 Stoichiometric ionic strength = .1175091E-01 Osmotic coef. = 0.9687 True ionic strength = .2070163E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90333E-10 -10.0442 0.75782E-10 -10.1204 0.83892E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16395E-03 -3.7853 0.13670E-03 -3.8642 0.83377E+00 -0.0790 4 SO4-- 0.93508E-12 -12.0292 0.48235E-12 -12.3166 0.51584E+00 -0.2875 5 HCO3- 0.33732E-06 -6.4720 0.28166E-06 -6.5503 0.83501E+00 -0.0783 6 HS- 0.30441E-04 -4.5165 0.25385E-04 -4.5954 0.83389E+00 -0.0789 7 Al+++ 0.11031E-28 -28.9574 0.25096E-29 -29.6004 0.22751E+00 -0.6430 8 H4SiO4 0.71163E-03 -3.1477 0.71163E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14337E-06 -6.8435 0.73400E-07 -7.1343 0.51197E+00 -0.2908 10 Mg++ 0.22765E-10 -10.6427 0.11601E-10 -10.9355 0.50958E+00 -0.2928 11 Fe++ 0.62271E-13 -13.2057 0.31768E-13 -13.4980 0.51015E+00 -0.2923 12 K+ 0.16155E-03 -3.7917 0.13493E-03 -3.8699 0.83521E+00 -0.0782 13 Na+ 0.20539E-01 -1.6874 0.17121E-01 -1.7665 0.83361E+00 -0.0790 14 Mn++ 0.19926E-10 -10.7006 0.10174E-10 -10.9925 0.51058E+00 -0.2919 15 HPO4-- 0.48726E-07 -7.3122 0.25139E-07 -7.5997 0.51592E+00 -0.2874 16 HSiO3- 0.10989E-01 -1.9591 0.91619E-02 -2.0380 0.83377E+00 -0.0790 17 Ca(HSiO3)+ 0.18036E-07 -7.7439 0.15067E-07 -7.8220 0.83540E+00 -0.0781 18 Mg(HSiO3)+ 0.35476E-11 -11.4501 0.29636E-11 -11.5282 0.83540E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67530E-16 -16.1705 0.56414E-16 -16.2486 0.83540E+00 -0.0781 22 HAlO2,aq 0.14897E-09 -9.8269 0.14897E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52740E-05 -5.2779 0.43892E-05 -5.3576 0.83224E+00 -0.0798 24 CH4,aq 0.14598E-04 -4.8357 0.14545E-04 -4.8373 0.99642E+00 -0.0016 25 C2H6,aq 0.33683E-14 -14.4726 0.33562E-14 -14.4741 0.99642E+00 -0.0016 29 CO,aq 0.12050E-16 -16.9190 0.12050E-16 -16.9190 0.10000E+01 0.0000 30 CO2,aq 0.43191E-10 -10.3646 0.43036E-10 -10.3662 0.99642E+00 -0.0016 31 CO3-2 0.66764E-06 -6.1755 0.34365E-06 -6.4639 0.51472E+00 -0.2884 32 CaCO3,aq 0.30893E-09 -9.5101 0.30893E-09 -9.5101 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.62357E-12 -12.2051 0.52092E-12 -12.2832 0.83540E+00 -0.0781 34 CaCl+ 0.19138E-10 -10.7181 0.15988E-10 -10.7962 0.83540E+00 -0.0781 35 CaCl2,aq 0.50887E-15 -15.2934 0.50887E-15 -15.2934 0.10000E+01 0.0000 36 CaOH+ 0.81753E-07 -7.0875 0.68296E-07 -7.1656 0.83540E+00 -0.0781 37 CaSO4,aq 0.11031E-16 -16.9574 0.11031E-16 -16.9574 0.10000E+01 0.0000 38 HCl,aq 0.19485E-14 -14.7103 0.19485E-14 -14.7103 0.10000E+01 0.0000 43 FeCl+ 0.80961E-17 -17.0917 0.67635E-17 -17.1698 0.83540E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16636E-10 -10.7790 0.13897E-10 -10.8571 0.83540E+00 -0.0781 48 HFeO2- 0.37236E-07 -7.4290 0.31047E-07 -7.5080 0.83377E+00 -0.0790 49 FeO+ 0.12278E-16 -16.9109 0.10257E-16 -16.9890 0.83540E+00 -0.0781 51 FeO2- 0.42102E-09 -9.3757 0.35103E-09 -9.4547 0.83377E+00 -0.0790 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.32658E-09 -9.4860 0.32658E-09 -9.4860 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.12026E-14 -14.9199 0.10027E-14 -14.9988 0.83377E+00 -0.0790 58 MgCO3,aq 0.12201E-13 -13.9136 0.12201E-13 -13.9136 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10050E-15 -15.9978 0.83956E-16 -16.0759 0.83540E+00 -0.0781 60 MgCl+ 0.27460E-14 -14.5613 0.22940E-14 -14.6394 0.83540E+00 -0.0781 61 MgOH+ 0.71583E-10 -10.1452 0.59800E-10 -10.2233 0.83540E+00 -0.0781 63 MnO,aq 0.18701E-08 -8.7281 0.18701E-08 -8.7281 0.10000E+01 0.0000 64 MnOH+ 0.49492E-09 -9.3055 0.41345E-09 -9.3836 0.83540E+00 -0.0781 65 MnO2-2 0.21879E-10 -10.6600 0.11261E-10 -10.9484 0.51472E+00 -0.2884 66 HMnO2- 0.22177E-09 -9.6541 0.18490E-09 -9.7331 0.83377E+00 -0.0790 69 MnCl+ 0.10075E-13 -13.9967 0.84168E-14 -14.0749 0.83540E+00 -0.0781 71 NaCl,aq 0.76421E-06 -6.1168 0.76421E-06 -6.1168 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95108E-02 -2.0218 0.79152E-02 -2.1015 0.83224E+00 -0.0798 79 HPO3-2 0.16770E-14 -14.7755 0.86318E-15 -15.0639 0.51472E+00 -0.2884 81 H2PO3- 0.15411E-18 -18.8122 0.12849E-18 -18.8911 0.83377E+00 -0.0790 82 H3PO4,aq 0.92945E-18 -18.0318 0.92945E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40020E-10 -10.3977 0.33400E-10 -10.4763 0.83458E+00 -0.0785 84 PO4-3 0.12111E-08 -8.9168 0.28970E-09 -9.5381 0.23921E+00 -0.6212 88 HP2O7-3 0.10373E-17 -17.9841 0.23624E-18 -18.6266 0.22775E+00 -0.6425 89 P2O7-4 0.10243E-16 -16.9896 0.76904E-18 -18.1141 0.75080E-01 -1.1245 90 H2S,aq 0.58007E-08 -8.2365 0.57799E-08 -8.2381 0.99642E+00 -0.0016 91 S2-2 0.25328E-14 -14.5964 0.13037E-14 -14.8848 0.51472E+00 -0.2884 97 SO3-2 0.13688E-17 -17.8636 0.71498E-18 -18.1457 0.52233E+00 -0.2821 99 HSO4- 0.40559E-19 -19.3919 0.33917E-19 -19.4696 0.83623E+00 -0.0777 Charge balance for all species = 0.3937E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9033265E-10 -.2311545E-01 -.2325679E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981177E+06 0.0000 3 Cl- 0.1639484E-03 0.1647129E-03 0.5828991E+01 6.2562 4 SO4-- 0.9350818E-12 -.1732510E-04 -.1661262E+01 7.9242 5 HCO3- 0.3373156E-06 0.1560291E-04 0.9503213E+00 3.5702 6 HS- 0.3044132E-04 0.4777221E-04 0.1577061E+01 5.5250 7 Al+++ 0.1103086E-28 0.5274132E-05 0.1420463E+00 0.7609 8 H4SiO4 0.7116264E-03 0.1419158E-01 0.1361559E+04 -3.1477 9 Ca++ 0.1433674E-06 0.2434849E-06 0.9740713E-02 13.1066 10 Mg++ 0.2276530E-10 0.9791053E-10 0.2376089E-05 9.3054 11 Fe++ 0.6227093E-13 0.3789622E-07 0.2112557E-02 6.7428 12 K+ 0.1615510E-03 0.1623276E-03 0.6335836E+01 6.2505 13 Na+ 0.2053883E-01 0.2313027E-01 0.5307972E+03 8.3540 14 Mn++ 0.1992566E-10 0.2628571E-08 0.1441469E-03 9.2483 15 HPO4-- 0.4872626E-07 0.4997735E-07 0.4788089E-02 12.6412 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2649360E+02 -.1936299E-01 -.2647423E+02 0.0000000E+00 2 H2O 0.3545161E+02 0.4649408E+02 -.1104247E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4436693E-01 -.1451262E-04 0.4438144E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4434143E-01 0.4001709E-04 -.4438144E-01 0.0000000E+00 7 Al+++ 0.5217183E+01 0.4417953E-05 0.5217179E+01 0.0000000E+00 8 H4SiO4 0.1666044E+02 0.1188778E-01 0.1664855E+02 0.0000000E+00 9 Ca++ 0.1840242E+01 0.2039586E-06 0.1840241E+01 0.0000000E+00 10 Mg++ 0.1269840E+01 0.8201617E-10 0.1269840E+01 0.0000000E+00 11 Fe++ 0.1140813E+01 0.3174431E-07 0.1140813E+01 0.0000000E+00 12 K+ 0.3397025E+00 0.1359760E-03 0.3395666E+00 0.0000000E+00 13 Na+ 0.2008549E+01 0.1937541E-01 0.1989173E+01 0.0000000E+00 14 Mn++ 0.2774174E-01 0.2201860E-08 0.2774173E-01 0.0000000E+00 15 HPO4-- 0.9468117E-02 0.4186425E-07 0.9468075E-02 0.0000000E+00 Chg. balance for solid moles: -.8916E-15 Mass of aqueous solution: 0.839184E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 1.988 0.298 521.2 2.717 29.82 200.1 andradite 0.1775 -0.751 90.22 1.955 5.161 23.44 grossular 0.4239E-01 -1.373 19.10 1.281 1.093 5.313 apatite-OH 0.3156E-02 -2.501 1.585 0.200 0.9070E-01 0.5038 clinochlore 0.2289 -0.640 127.2 2.105 7.279 48.39 daphnite 0.6560E-01 -1.183 46.81 1.670 2.678 14.18 chlorite-Mn 0.5548E-02 -2.256 3.934 0.595 0.2251 1.254 diopside 0.8306E-01 -1.081 17.99 1.255 1.029 5.497 hedenbergite 0.2128E-01 -1.672 5.279 0.723 0.3020 1.446 microcline 0.2974 -0.527 82.77 1.918 4.736 32.33 stilbite 1.037 0.016 730.8 2.864 41.81 340.9 stilpnomelane-Fe 0.8438E-01 -1.074 90.96 1.959 5.204 31.42 tr.625ac.25prg.125 0.1167E-01 -1.933 9.973 0.999 0.5706 3.210 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1849E-01 0.1849E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1747.874243 g Volume = 707.944141 cm3 Porosity: -10.4438% V(tot) - V(min): -.66945E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1599.9990000 g log = 3.2041 Original solution: 1000.0103000 g Original solution / Rock added: 0.63 (Water/Rock Ratio), log = -0.2041 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0901 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9655E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4487E-08 1.0071 0.4926E-08 0.4891E-08 CH4,gas 0.2083E-01 1.0128 0.2300E-01 0.2271E-01 H2,gas 0.1367E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1553E-06 0.9958 0.1686E-06 0.1693E-06 S2,gas 0.4392E-29 1.0000 0.4788E-29 0.4788E-29 CO,gas 0.1745E-13 1.0000 0.1903E-13 0.1903E-13 SO3,gas 0.9500E-48 1.0000 0.1036E-47 0.1036E-47 SO2,gas 0.5359E-27 1.0000 0.5842E-27 0.5842E-27 HCl,gas 0.3156E-17 1.0000 0.3441E-17 0.3441E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.67 -10.31 -3.436 0.17600E+05 -8.307 3 CH4,gas 4.81 1.17 -3.64 -0.910 0.62122E+04 -1.638 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.72 -8.77 -4.387 0.14980E+05 -6.773 6 S2,gas -7.03 -38.35 -31.32 -4.818 0.53478E+05 -29.320 7 CO,gas 3.51 -12.21 -15.72 -4.837 0.26843E+05 -13.721 8 SO3,gas 17.43 -32.56 -49.98 -12.496 0.85348E+05 -47.985 9 SO2,gas 1.14 -28.10 -29.23 -7.796 0.49915E+05 -27.233 10 HCl,gas 5.48 -13.98 -19.46 -9.732 0.33233E+05 -17.463 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80700E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94125E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.56 -4.55 -1.517 0.77696E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.56 -4.40 -1.466 0.75083E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65581E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.75 -4.64 -1.326 0.79271E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66054E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56969E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.75 -4.20 -1.200 0.71733E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82293E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61284E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53669E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92772E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40696E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43445E+04 143 pyrrhotite -4.24 -7.97 -3.73 -1.243 0.63679E+04 144 pyrrhotiteFe0.875 -6.00 -9.37 -3.37 -1.239 0.57507E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22461E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28301E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23253E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47194E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91030E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.97 -3.58 -1.193 0.61111E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80423E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66780E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60333E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.47 -4.51 -1.502 0.76924E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 1599.9990000 g New total amount of reactant added: 1699.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1699.9990000 Water: Moles liquid = 0.4594E+02 kg liquid = 0.8276E+00 Moles total = 0.3420E+02 kg total = 0.6161E+00 Activity = 1.0000 Stoichiometric ionic strength = .1175258E-01 Osmotic coef. = 0.9687 True ionic strength = .2070295E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90338E-10 -10.0441 0.75787E-10 -10.1204 0.83892E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16594E-03 -3.7801 0.13835E-03 -3.8590 0.83377E+00 -0.0790 4 SO4-- 0.94642E-12 -12.0239 0.48820E-12 -12.3114 0.51583E+00 -0.2875 5 HCO3- 0.34141E-06 -6.4667 0.28508E-06 -6.5450 0.83501E+00 -0.0783 6 HS- 0.30811E-04 -4.5113 0.25693E-04 -4.5902 0.83389E+00 -0.0789 7 Al+++ 0.11033E-28 -28.9573 0.25100E-29 -29.6003 0.22750E+00 -0.6430 8 H4SiO4 0.71163E-03 -3.1477 0.71163E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14339E-06 -6.8435 0.73408E-07 -7.1343 0.51196E+00 -0.2908 10 Mg++ 0.22768E-10 -10.6427 0.11602E-10 -10.9355 0.50957E+00 -0.2928 11 Fe++ 0.62279E-13 -13.2057 0.31771E-13 -13.4980 0.51014E+00 -0.2923 12 K+ 0.16156E-03 -3.7917 0.13494E-03 -3.8699 0.83521E+00 -0.0782 13 Na+ 0.20540E-01 -1.6874 0.17122E-01 -1.7664 0.83361E+00 -0.0790 14 Mn++ 0.19935E-10 -10.7004 0.10178E-10 -10.9923 0.51057E+00 -0.2919 15 HPO4-- 0.48722E-07 -7.3123 0.25136E-07 -7.5997 0.51591E+00 -0.2874 16 HSiO3- 0.10988E-01 -1.9591 0.91614E-02 -2.0380 0.83377E+00 -0.0790 17 Ca(HSiO3)+ 0.18037E-07 -7.7438 0.15068E-07 -7.8219 0.83539E+00 -0.0781 18 Mg(HSiO3)+ 0.35478E-11 -11.4500 0.29638E-11 -11.5282 0.83539E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67533E-16 -16.1705 0.56417E-16 -16.2486 0.83539E+00 -0.0781 22 HAlO2,aq 0.14897E-09 -9.8269 0.14897E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52736E-05 -5.2779 0.43889E-05 -5.3576 0.83224E+00 -0.0798 24 CH4,aq 0.14775E-04 -4.8305 0.14722E-04 -4.8320 0.99642E+00 -0.0016 25 C2H6,aq 0.34506E-14 -14.4621 0.34383E-14 -14.4637 0.99642E+00 -0.0016 29 CO,aq 0.12196E-16 -16.9138 0.12196E-16 -16.9138 0.10000E+01 0.0000 30 CO2,aq 0.43717E-10 -10.3594 0.43560E-10 -10.3609 0.99642E+00 -0.0016 31 CO3-2 0.67570E-06 -6.1702 0.34779E-06 -6.4587 0.51471E+00 -0.2884 32 CaCO3,aq 0.31269E-09 -9.5049 0.31269E-09 -9.5049 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.63120E-12 -12.1998 0.52730E-12 -12.2779 0.83539E+00 -0.0781 34 CaCl+ 0.19373E-10 -10.7128 0.16184E-10 -10.7909 0.83539E+00 -0.0781 35 CaCl2,aq 0.52135E-15 -15.2829 0.52135E-15 -15.2829 0.10000E+01 0.0000 36 CaOH+ 0.81758E-07 -7.0875 0.68300E-07 -7.1656 0.83539E+00 -0.0781 37 CaSO4,aq 0.11166E-16 -16.9521 0.11166E-16 -16.9521 0.10000E+01 0.0000 38 HCl,aq 0.19723E-14 -14.7050 0.19723E-14 -14.7050 0.10000E+01 0.0000 43 FeCl+ 0.81953E-17 -17.0864 0.68463E-17 -17.1645 0.83539E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16637E-10 -10.7789 0.13898E-10 -10.8570 0.83539E+00 -0.0781 48 HFeO2- 0.37234E-07 -7.4291 0.31045E-07 -7.5080 0.83377E+00 -0.0790 49 FeO+ 0.12279E-16 -16.9108 0.10258E-16 -16.9889 0.83539E+00 -0.0781 51 FeO2- 0.42099E-09 -9.3757 0.35101E-09 -9.4547 0.83377E+00 -0.0790 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.33057E-09 -9.4807 0.33057E-09 -9.4807 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.12173E-14 -14.9146 0.10149E-14 -14.9936 0.83377E+00 -0.0790 58 MgCO3,aq 0.12349E-13 -13.9084 0.12349E-13 -13.9084 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10173E-15 -15.9926 0.84983E-16 -16.0707 0.83539E+00 -0.0781 60 MgCl+ 0.27796E-14 -14.5560 0.23221E-14 -14.6341 0.83539E+00 -0.0781 61 MgOH+ 0.71587E-10 -10.1452 0.59803E-10 -10.2233 0.83539E+00 -0.0781 63 MnO,aq 0.18707E-08 -8.7280 0.18707E-08 -8.7280 0.10000E+01 0.0000 64 MnOH+ 0.49512E-09 -9.3053 0.41362E-09 -9.3834 0.83539E+00 -0.0781 65 MnO2-2 0.21884E-10 -10.6599 0.11264E-10 -10.9483 0.51471E+00 -0.2884 66 HMnO2- 0.22183E-09 -9.6540 0.18495E-09 -9.7329 0.83377E+00 -0.0790 69 MnCl+ 0.10202E-13 -13.9913 0.85229E-14 -14.0694 0.83539E+00 -0.0781 71 NaCl,aq 0.77353E-06 -6.1115 0.77353E-06 -6.1115 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95102E-02 -2.0218 0.79148E-02 -2.1016 0.83224E+00 -0.0798 79 HPO3-2 0.16768E-14 -14.7755 0.86308E-15 -15.0639 0.51471E+00 -0.2884 81 H2PO3- 0.15410E-18 -18.8122 0.12849E-18 -18.8911 0.83377E+00 -0.0790 82 H3PO4,aq 0.92945E-18 -18.0318 0.92945E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40018E-10 -10.3977 0.33398E-10 -10.4763 0.83457E+00 -0.0785 84 PO4-3 0.12109E-08 -8.9169 0.28965E-09 -9.5381 0.23920E+00 -0.6212 88 HP2O7-3 0.10371E-17 -17.9842 0.23620E-18 -18.6267 0.22774E+00 -0.6426 89 P2O7-4 0.10241E-16 -16.9896 0.76887E-18 -18.1141 0.75075E-01 -1.1245 90 H2S,aq 0.58715E-08 -8.2313 0.58504E-08 -8.2328 0.99642E+00 -0.0016 91 S2-2 0.25947E-14 -14.5859 0.13355E-14 -14.8743 0.51471E+00 -0.2884 97 SO3-2 0.13854E-17 -17.8584 0.72363E-18 -18.1405 0.52232E+00 -0.2821 99 HSO4- 0.41053E-19 -19.3867 0.34330E-19 -19.4643 0.83623E+00 -0.0777 Charge balance for all species = 0.3987E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9033833E-10 -.2311439E-01 -.2325572E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981176E+06 0.0000 3 Cl- 0.1659386E-03 0.1667124E-03 0.5899751E+01 6.2614 4 SO4-- 0.9464249E-12 -.1750232E-04 -.1678256E+01 7.9294 5 HCO3- 0.3414055E-06 0.1579231E-04 0.9618575E+00 3.5754 6 HS- 0.3081085E-04 0.4831905E-04 0.1595113E+01 5.5302 7 Al+++ 0.1103309E-28 0.5273780E-05 0.1420368E+00 0.7609 8 H4SiO4 0.7116293E-03 0.1419104E-01 0.1361507E+04 -3.1477 9 Ca++ 0.1433861E-06 0.2435136E-06 0.9741860E-02 13.1066 10 Mg++ 0.2276827E-10 0.9791780E-10 0.2376266E-05 9.3053 11 Fe++ 0.6227924E-13 0.3789410E-07 0.2112439E-02 6.7428 12 K+ 0.1615612E-03 0.1623377E-03 0.6336233E+01 6.2505 13 Na+ 0.2054013E-01 0.2313159E-01 0.5308273E+03 8.3540 14 Mn++ 0.1993515E-10 0.2629487E-08 0.1441971E-03 9.2485 15 HPO4-- 0.4872168E-07 0.4997261E-07 0.4787634E-02 12.6411 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2814945E+02 -.1912988E-01 -.2813032E+02 0.0000000E+00 2 H2O 0.3419807E+02 0.4593644E+02 -.1173838E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4713827E-01 -.1448523E-04 0.4715276E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4711277E-01 0.3998970E-04 -.4715276E-01 0.0000000E+00 7 Al+++ 0.5543257E+01 0.4364675E-05 0.5543253E+01 0.0000000E+00 8 H4SiO4 0.1770172E+02 0.1174476E-01 0.1768998E+02 0.0000000E+00 9 Ca++ 0.1955256E+01 0.2015362E-06 0.1955256E+01 0.0000000E+00 10 Mg++ 0.1349206E+01 0.8103851E-10 0.1349206E+01 0.0000000E+00 11 Fe++ 0.1212114E+01 0.3136183E-07 0.1212114E+01 0.0000000E+00 12 K+ 0.3609340E+00 0.1343536E-03 0.3607996E+00 0.0000000E+00 13 Na+ 0.2134073E+01 0.1914411E-01 0.2114929E+01 0.0000000E+00 14 Mn++ 0.2947560E-01 0.2176210E-08 0.2947559E-01 0.0000000E+00 15 HPO4-- 0.1005987E-01 0.4135822E-07 0.1005983E-01 0.0000000E+00 Chg. balance for solid moles: -.5163E-14 Mass of aqueous solution: 0.829120E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1699.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.113 0.325 554.2 2.744 29.84 212.7 andradite 0.1886 -0.724 95.85 1.982 5.161 24.90 grossular 0.4504E-01 -1.346 20.29 1.307 1.092 5.645 apatite-OH 0.3353E-02 -2.475 1.684 0.226 0.9070E-01 0.5352 clinochlore 0.2431 -0.614 135.1 2.131 7.276 51.40 daphnite 0.6968E-01 -1.157 49.71 1.696 2.677 15.07 chlorite-Mn 0.5895E-02 -2.230 4.179 0.621 0.2250 1.332 diopside 0.8884E-01 -1.051 19.24 1.284 1.036 5.880 hedenbergite 0.2276E-01 -1.643 5.647 0.752 0.3041 1.547 microcline 0.3160 -0.500 87.95 1.944 4.736 34.35 stilbite 1.101 0.042 776.1 2.890 41.79 362.0 stilpnomelane-Fe 0.8966E-01 -1.047 96.66 1.985 5.205 33.39 tr.625ac.25prg.125 0.1235E-01 -1.908 10.56 1.023 0.5684 3.397 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1850E-01 0.1850E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1857.129723 g Volume = 752.150498 cm3 Porosity: -10.4480% V(tot) - V(min): -.71151E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1699.9990000 g log = 3.2304 Original solution: 1000.0103000 g Original solution / Rock added: 0.59 (Water/Rock Ratio), log = -0.2304 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0904 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9653E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4541E-08 1.0071 0.4986E-08 0.4951E-08 CH4,gas 0.2108E-01 1.0128 0.2328E-01 0.2299E-01 H2,gas 0.1367E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1572E-06 0.9958 0.1706E-06 0.1714E-06 S2,gas 0.4499E-29 1.0000 0.4905E-29 0.4905E-29 CO,gas 0.1766E-13 1.0000 0.1926E-13 0.1926E-13 SO3,gas 0.9614E-48 1.0000 0.1048E-47 0.1048E-47 SO2,gas 0.5423E-27 1.0000 0.5913E-27 0.5913E-27 HCl,gas 0.3194E-17 1.0000 0.3482E-17 0.3482E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.72794E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.72794E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.48529E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.67 -10.30 -3.434 0.17591E+05 -8.302 3 CH4,gas 4.81 1.18 -3.63 -0.908 0.62032E+04 -1.633 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.71 -8.77 -4.384 0.14971E+05 -6.768 6 S2,gas -7.03 -38.34 -31.31 -4.817 0.53460E+05 -29.309 7 CO,gas 3.51 -12.21 -15.72 -4.836 0.26834E+05 -13.715 8 SO3,gas 17.43 -32.55 -49.98 -12.495 0.85339E+05 -47.980 9 SO2,gas 1.14 -28.09 -29.23 -7.794 0.49906E+05 -27.228 10 HCl,gas 5.48 -13.98 -19.46 -9.729 0.33224E+05 -17.458 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80693E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94125E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.56 -4.55 -1.515 0.77606E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.56 -4.39 -1.464 0.74993E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65578E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.74 -4.64 -1.325 0.79181E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66055E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.74 -4.20 -1.199 0.71643E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82291E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61284E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53669E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92772E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40696E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43445E+04 143 pyrrhotite -4.24 -7.97 -3.72 -1.241 0.63589E+04 144 pyrrhotiteFe0.875 -6.00 -9.36 -3.36 -1.237 0.57417E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22458E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28301E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23251E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47189E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91030E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.97 -3.57 -1.191 0.61021E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80424E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66780E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60332E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83181E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.46 -4.50 -1.500 0.76831E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 1699.9990000 g New total amount of reactant added: 1799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1799.9990000 Water: Moles liquid = 0.4538E+02 kg liquid = 0.8176E+00 Moles total = 0.3294E+02 kg total = 0.5935E+00 Activity = 1.0000 Stoichiometric ionic strength = .1175429E-01 Osmotic coef. = 0.9687 True ionic strength = .2070429E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90344E-10 -10.0441 0.75791E-10 -10.1204 0.83892E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.16798E-03 -3.7747 0.14005E-03 -3.8537 0.83376E+00 -0.0790 4 SO4-- 0.95804E-12 -12.0186 0.49418E-12 -12.3061 0.51582E+00 -0.2875 5 HCO3- 0.34559E-06 -6.4614 0.28857E-06 -6.5397 0.83501E+00 -0.0783 6 HS- 0.31189E-04 -4.5060 0.26009E-04 -4.5849 0.83389E+00 -0.0789 7 Al+++ 0.11035E-28 -28.9572 0.25105E-29 -29.6002 0.22749E+00 -0.6430 8 H4SiO4 0.71163E-03 -3.1477 0.71163E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14341E-06 -6.8434 0.73417E-07 -7.1342 0.51195E+00 -0.2908 10 Mg++ 0.22771E-10 -10.6426 0.11603E-10 -10.9354 0.50956E+00 -0.2928 11 Fe++ 0.62288E-13 -13.2056 0.31775E-13 -13.4979 0.51013E+00 -0.2923 12 K+ 0.16157E-03 -3.7916 0.13495E-03 -3.8698 0.83521E+00 -0.0782 13 Na+ 0.20541E-01 -1.6874 0.17123E-01 -1.7664 0.83361E+00 -0.0790 14 Mn++ 0.19944E-10 -10.7002 0.10183E-10 -10.9921 0.51056E+00 -0.2920 15 HPO4-- 0.48717E-07 -7.3123 0.25133E-07 -7.5998 0.51590E+00 -0.2874 16 HSiO3- 0.10987E-01 -1.9591 0.91609E-02 -2.0381 0.83376E+00 -0.0790 17 Ca(HSiO3)+ 0.18038E-07 -7.7438 0.15069E-07 -7.8219 0.83539E+00 -0.0781 18 Mg(HSiO3)+ 0.35480E-11 -11.4500 0.29640E-11 -11.5281 0.83539E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67537E-16 -16.1705 0.56420E-16 -16.2486 0.83539E+00 -0.0781 22 HAlO2,aq 0.14896E-09 -9.8269 0.14896E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52733E-05 -5.2779 0.43886E-05 -5.3577 0.83223E+00 -0.0798 24 CH4,aq 0.14956E-04 -4.8252 0.14903E-04 -4.8267 0.99642E+00 -0.0016 25 C2H6,aq 0.35360E-14 -14.4515 0.35233E-14 -14.4530 0.99642E+00 -0.0016 29 CO,aq 0.12346E-16 -16.9085 0.12346E-16 -16.9085 0.10000E+01 0.0000 30 CO2,aq 0.44256E-10 -10.3540 0.44097E-10 -10.3556 0.99642E+00 -0.0016 31 CO3-2 0.68396E-06 -6.1650 0.35204E-06 -6.4534 0.51471E+00 -0.2884 32 CaCO3,aq 0.31654E-09 -9.4996 0.31654E-09 -9.4996 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.63902E-12 -12.1945 0.53383E-12 -12.2726 0.83539E+00 -0.0781 34 CaCl+ 0.19613E-10 -10.7074 0.16385E-10 -10.7856 0.83539E+00 -0.0781 35 CaCl2,aq 0.53430E-15 -15.2722 0.53430E-15 -15.2722 0.10000E+01 0.0000 36 CaOH+ 0.81763E-07 -7.0874 0.68304E-07 -7.1656 0.83539E+00 -0.0781 37 CaSO4,aq 0.11304E-16 -16.9468 0.11304E-16 -16.9468 0.10000E+01 0.0000 38 HCl,aq 0.19966E-14 -14.6997 0.19966E-14 -14.6997 0.10000E+01 0.0000 43 FeCl+ 0.82970E-17 -17.0811 0.69312E-17 -17.1592 0.83539E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16638E-10 -10.7789 0.13899E-10 -10.8570 0.83539E+00 -0.0781 48 HFeO2- 0.37232E-07 -7.4291 0.31043E-07 -7.5080 0.83376E+00 -0.0790 49 FeO+ 0.12280E-16 -16.9108 0.10258E-16 -16.9889 0.83539E+00 -0.0781 51 FeO2- 0.42097E-09 -9.3757 0.35099E-09 -9.4547 0.83376E+00 -0.0790 52 HFeO2,aq 0.33292E-11 -11.4777 0.33292E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.33465E-09 -9.4754 0.33465E-09 -9.4754 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.12323E-14 -14.9093 0.10274E-14 -14.9883 0.83376E+00 -0.0790 58 MgCO3,aq 0.12501E-13 -13.9030 0.12501E-13 -13.9030 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10299E-15 -15.9872 0.86035E-16 -16.0653 0.83539E+00 -0.0781 60 MgCl+ 0.28141E-14 -14.5507 0.23509E-14 -14.6288 0.83539E+00 -0.0781 61 MgOH+ 0.71591E-10 -10.1451 0.59807E-10 -10.2233 0.83539E+00 -0.0781 63 MnO,aq 0.18713E-08 -8.7279 0.18713E-08 -8.7279 0.10000E+01 0.0000 64 MnOH+ 0.49530E-09 -9.3051 0.41377E-09 -9.3832 0.83539E+00 -0.0781 65 MnO2-2 0.21888E-10 -10.6598 0.11266E-10 -10.9482 0.51471E+00 -0.2884 66 HMnO2- 0.22188E-09 -9.6539 0.18500E-09 -9.7328 0.83376E+00 -0.0790 69 MnCl+ 0.10332E-13 -13.9858 0.86312E-14 -14.0639 0.83539E+00 -0.0781 71 NaCl,aq 0.78307E-06 -6.1062 0.78307E-06 -6.1062 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95097E-02 -2.0218 0.79143E-02 -2.1016 0.83223E+00 -0.0798 79 HPO3-2 0.16766E-14 -14.7756 0.86297E-15 -15.0640 0.51471E+00 -0.2884 81 H2PO3- 0.15410E-18 -18.8122 0.12848E-18 -18.8912 0.83376E+00 -0.0790 82 H3PO4,aq 0.92946E-18 -18.0318 0.92946E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40016E-10 -10.3978 0.33396E-10 -10.4763 0.83457E+00 -0.0785 84 PO4-3 0.12107E-08 -8.9169 0.28960E-09 -9.5382 0.23919E+00 -0.6213 88 HP2O7-3 0.10370E-17 -17.9842 0.23616E-18 -18.6268 0.22773E+00 -0.6426 89 P2O7-4 0.10240E-16 -16.9897 0.76869E-18 -18.1142 0.75070E-01 -1.1245 90 H2S,aq 0.59439E-08 -8.2259 0.59227E-08 -8.2275 0.99642E+00 -0.0016 91 S2-2 0.26589E-14 -14.5753 0.13686E-14 -14.8637 0.51471E+00 -0.2884 97 SO3-2 0.14024E-17 -17.8531 0.73250E-18 -18.1352 0.52231E+00 -0.2821 99 HSO4- 0.41559E-19 -19.3813 0.34753E-19 -19.4590 0.83622E+00 -0.0777 Charge balance for all species = 0.4034E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9034413E-10 -.2311331E-01 -.2325463E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981176E+06 0.0000 3 Cl- 0.1679777E-03 0.1687611E-03 0.5972250E+01 6.2667 4 SO4-- 0.9580418E-12 -.1768391E-04 -.1695668E+01 7.9346 5 HCO3- 0.3455943E-06 0.1598638E-04 0.9736772E+00 3.5806 6 HS- 0.3118947E-04 0.4887933E-04 0.1613609E+01 5.5355 7 Al+++ 0.1103540E-28 0.5273430E-05 0.1420273E+00 0.7609 8 H4SiO4 0.7116319E-03 0.1419048E-01 0.1361453E+04 -3.1477 9 Ca++ 0.1434054E-06 0.2435430E-06 0.9743038E-02 13.1066 10 Mg++ 0.2277132E-10 0.9792606E-10 0.2376466E-05 9.3053 11 Fe++ 0.6228774E-13 0.3789195E-07 0.2112319E-02 6.7428 12 K+ 0.1615716E-03 0.1623481E-03 0.6336639E+01 6.2505 13 Na+ 0.2054145E-01 0.2313293E-01 0.5308581E+03 8.3540 14 Mn++ 0.1994395E-10 0.2630305E-08 0.1442420E-03 9.2486 15 HPO4-- 0.4871695E-07 0.4996771E-07 0.4787164E-02 12.6410 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.2980530E+02 -.1889677E-01 -.2978640E+02 0.0000000E+00 2 H2O 0.3294452E+02 0.4537881E+02 -.1243428E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.4990961E-01 -.1445786E-04 0.4992407E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.4988411E-01 0.3996233E-04 -.4992407E-01 0.0000000E+00 7 Al+++ 0.5869332E+01 0.4311403E-05 0.5869327E+01 0.0000000E+00 8 H4SiO4 0.1874300E+02 0.1160172E-01 0.1873140E+02 0.0000000E+00 9 Ca++ 0.2070270E+01 0.1991137E-06 0.2070270E+01 0.0000000E+00 10 Mg++ 0.1428571E+01 0.8006151E-10 0.1428571E+01 0.0000000E+00 11 Fe++ 0.1283415E+01 0.3097936E-07 0.1283415E+01 0.0000000E+00 12 K+ 0.3821654E+00 0.1327312E-03 0.3820327E+00 0.0000000E+00 13 Na+ 0.2259597E+01 0.1891281E-01 0.2240685E+01 0.0000000E+00 14 Mn++ 0.3120946E-01 0.2150461E-08 0.3120945E-01 0.0000000E+00 15 HPO4-- 0.1065163E-01 0.4085215E-07 0.1065159E-01 0.0000000E+00 Chg. balance for solid moles: -.7244E-14 Mass of aqueous solution: 0.819055E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.239 0.350 587.1 2.769 29.86 225.4 andradite 0.1997 -0.700 101.5 2.006 5.161 26.37 grossular 0.4769E-01 -1.322 21.48 1.332 1.092 5.977 apatite-OH 0.3551E-02 -2.450 1.784 0.251 0.9070E-01 0.5667 clinochlore 0.2573 -0.589 143.0 2.155 7.274 54.41 daphnite 0.7375E-01 -1.132 52.62 1.721 2.676 15.95 chlorite-Mn 0.6242E-02 -2.205 4.425 0.646 0.2250 1.410 diopside 0.9463E-01 -1.024 20.49 1.312 1.042 6.263 hedenbergite 0.2424E-01 -1.615 6.014 0.779 0.3059 1.647 microcline 0.3346 -0.476 93.12 1.969 4.736 36.38 stilbite 1.165 0.066 821.3 2.915 41.77 383.1 stilpnomelane-Fe 0.9495E-01 -1.023 102.4 2.010 5.205 35.35 tr.625ac.25prg.125 0.1303E-01 -1.885 11.14 1.047 0.5664 3.585 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1850E-01 0.1850E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 1966.385204 g Volume = 796.356855 cm3 Porosity: -10.4518% V(tot) - V(min): -.75357E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1799.9990000 g log = 3.2553 Original solution: 1000.0103000 g Original solution / Rock added: 0.56 (Water/Rock Ratio), log = -0.2553 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0907 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9650E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4595E-08 1.0071 0.5048E-08 0.5012E-08 CH4,gas 0.2134E-01 1.0128 0.2357E-01 0.2327E-01 H2,gas 0.1366E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1591E-06 0.9958 0.1727E-06 0.1735E-06 S2,gas 0.4609E-29 1.0000 0.5027E-29 0.5027E-29 CO,gas 0.1787E-13 1.0000 0.1950E-13 0.1950E-13 SO3,gas 0.9731E-48 1.0000 0.1061E-47 0.1061E-47 SO2,gas 0.5489E-27 1.0000 0.5986E-27 0.5986E-27 HCl,gas 0.3232E-17 1.0000 0.3525E-17 0.3525E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 -0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.66 -10.30 -3.432 0.17582E+05 -8.297 3 CH4,gas 4.81 1.18 -3.63 -0.907 0.61942E+04 -1.628 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.71 -8.76 -4.381 0.14962E+05 -6.763 6 S2,gas -7.03 -38.33 -31.30 -4.815 0.53442E+05 -29.299 7 CO,gas 3.51 -12.20 -15.71 -4.834 0.26825E+05 -13.710 8 SO3,gas 17.43 -32.55 -49.97 -12.494 0.85330E+05 -47.974 9 SO2,gas 1.14 -28.09 -29.22 -7.793 0.49897E+05 -27.223 10 HCl,gas 5.48 -13.97 -19.45 -9.726 0.33215E+05 -17.453 11 acmite 7.74 6.57 -1.17 -0.121 0.19914E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80686E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94125E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76235E+04 35 aragonite 0.99 -3.55 -4.54 -1.513 0.77516E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.55 -4.39 -1.462 0.74902E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65576E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.74 -4.63 -1.323 0.79090E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66055E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.74 -4.19 -1.197 0.71552E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82289E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61284E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53669E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92772E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40697E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43446E+04 143 pyrrhotite -4.24 -7.96 -3.72 -1.240 0.63498E+04 144 pyrrhotiteFe0.875 -6.00 -9.36 -3.36 -1.235 0.57326E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22456E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28301E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23248E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47184E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91030E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76030E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.96 -3.57 -1.189 0.60930E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80425E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66780E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60332E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61759E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.46 -4.49 -1.498 0.76738E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 1799.9990000 g New total amount of reactant added: 1899.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1899.9990000 Water: Moles liquid = 0.4482E+02 kg liquid = 0.8075E+00 Moles total = 0.3169E+02 kg total = 0.5709E+00 Activity = 1.0000 Stoichiometric ionic strength = .1175605E-01 Osmotic coef. = 0.9687 True ionic strength = .2070567E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90350E-10 -10.0441 0.75796E-10 -10.1204 0.83891E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17007E-03 -3.7694 0.14180E-03 -3.8483 0.83376E+00 -0.0790 4 SO4-- 0.96994E-12 -12.0133 0.50031E-12 -12.3008 0.51581E+00 -0.2875 5 HCO3- 0.34989E-06 -6.4561 0.29216E-06 -6.5344 0.83500E+00 -0.0783 6 HS- 0.31578E-04 -4.5006 0.26332E-04 -4.5795 0.83388E+00 -0.0789 7 Al+++ 0.11038E-28 -28.9571 0.25109E-29 -29.6002 0.22748E+00 -0.6431 8 H4SiO4 0.71163E-03 -3.1477 0.71163E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14343E-06 -6.8434 0.73426E-07 -7.1342 0.51194E+00 -0.2908 10 Mg++ 0.22774E-10 -10.6426 0.11605E-10 -10.9354 0.50955E+00 -0.2928 11 Fe++ 0.62296E-13 -13.2055 0.31779E-13 -13.4979 0.51012E+00 -0.2923 12 K+ 0.16158E-03 -3.7916 0.13495E-03 -3.8698 0.83520E+00 -0.0782 13 Na+ 0.20543E-01 -1.6873 0.17125E-01 -1.7664 0.83360E+00 -0.0790 14 Mn++ 0.19952E-10 -10.7000 0.10187E-10 -10.9920 0.51055E+00 -0.2920 15 HPO4-- 0.48712E-07 -7.3124 0.25130E-07 -7.5998 0.51589E+00 -0.2874 16 HSiO3- 0.10987E-01 -1.9591 0.91604E-02 -2.0381 0.83376E+00 -0.0790 17 Ca(HSiO3)+ 0.18039E-07 -7.7438 0.15070E-07 -7.8219 0.83539E+00 -0.0781 18 Mg(HSiO3)+ 0.35482E-11 -11.4500 0.29642E-11 -11.5281 0.83539E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67541E-16 -16.1704 0.56422E-16 -16.2485 0.83539E+00 -0.0781 22 HAlO2,aq 0.14896E-09 -9.8269 0.14896E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52729E-05 -5.2779 0.43883E-05 -5.3577 0.83223E+00 -0.0798 24 CH4,aq 0.15143E-04 -4.8198 0.15088E-04 -4.8214 0.99642E+00 -0.0016 25 C2H6,aq 0.36246E-14 -14.4407 0.36116E-14 -14.4423 0.99642E+00 -0.0016 29 CO,aq 0.12500E-16 -16.9031 0.12500E-16 -16.9031 0.10000E+01 0.0000 30 CO2,aq 0.44808E-10 -10.3486 0.44647E-10 -10.3502 0.99642E+00 -0.0016 31 CO3-2 0.69242E-06 -6.1596 0.35639E-06 -6.4481 0.51470E+00 -0.2884 32 CaCO3,aq 0.32049E-09 -9.4942 0.32049E-09 -9.4942 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.64703E-12 -12.1891 0.54052E-12 -12.2672 0.83539E+00 -0.0781 34 CaCl+ 0.19860E-10 -10.7020 0.16590E-10 -10.7801 0.83539E+00 -0.0781 35 CaCl2,aq 0.54774E-15 -15.2614 0.54774E-15 -15.2614 0.10000E+01 0.0000 36 CaOH+ 0.81768E-07 -7.0874 0.68308E-07 -7.1655 0.83539E+00 -0.0781 37 CaSO4,aq 0.11446E-16 -16.9413 0.11446E-16 -16.9413 0.10000E+01 0.0000 38 HCl,aq 0.20216E-14 -14.6943 0.20216E-14 -14.6943 0.10000E+01 0.0000 43 FeCl+ 0.84013E-17 -17.0757 0.70183E-17 -17.1538 0.83539E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16639E-10 -10.7789 0.13900E-10 -10.8570 0.83539E+00 -0.0781 48 HFeO2- 0.37230E-07 -7.4291 0.31041E-07 -7.5081 0.83376E+00 -0.0790 49 FeO+ 0.12281E-16 -16.9108 0.10259E-16 -16.9889 0.83539E+00 -0.0781 51 FeO2- 0.42095E-09 -9.3758 0.35097E-09 -9.4547 0.83376E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4777 0.33293E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.33883E-09 -9.4700 0.33883E-09 -9.4700 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.12476E-14 -14.9039 0.10402E-14 -14.9829 0.83376E+00 -0.0790 58 MgCO3,aq 0.12657E-13 -13.8977 0.12657E-13 -13.8977 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10428E-15 -15.9818 0.87114E-16 -16.0599 0.83539E+00 -0.0781 60 MgCl+ 0.28495E-14 -14.5452 0.23804E-14 -14.6234 0.83539E+00 -0.0781 61 MgOH+ 0.71596E-10 -10.1451 0.59810E-10 -10.2232 0.83539E+00 -0.0781 63 MnO,aq 0.18718E-08 -8.7277 0.18718E-08 -8.7277 0.10000E+01 0.0000 64 MnOH+ 0.49547E-09 -9.3050 0.41391E-09 -9.3831 0.83539E+00 -0.0781 65 MnO2-2 0.21892E-10 -10.6597 0.11268E-10 -10.9482 0.51470E+00 -0.2884 66 HMnO2- 0.22193E-09 -9.6538 0.18504E-09 -9.7327 0.83376E+00 -0.0790 69 MnCl+ 0.10465E-13 -13.9803 0.87420E-14 -14.0584 0.83539E+00 -0.0781 71 NaCl,aq 0.79286E-06 -6.1008 0.79286E-06 -6.1008 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95092E-02 -2.0219 0.79138E-02 -2.1016 0.83223E+00 -0.0798 79 HPO3-2 0.16765E-14 -14.7756 0.86287E-15 -15.0641 0.51470E+00 -0.2884 81 H2PO3- 0.15409E-18 -18.8122 0.12847E-18 -18.8912 0.83376E+00 -0.0790 82 H3PO4,aq 0.92946E-18 -18.0318 0.92946E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40014E-10 -10.3978 0.33394E-10 -10.4763 0.83456E+00 -0.0785 84 PO4-3 0.12106E-08 -8.9170 0.28955E-09 -9.5383 0.23918E+00 -0.6213 88 HP2O7-3 0.10369E-17 -17.9843 0.23612E-18 -18.6269 0.22772E+00 -0.6426 89 P2O7-4 0.10238E-16 -16.9898 0.76851E-18 -18.1143 0.75065E-01 -1.1246 90 H2S,aq 0.60182E-08 -8.2205 0.59967E-08 -8.2221 0.99642E+00 -0.0016 91 S2-2 0.27255E-14 -14.5646 0.14028E-14 -14.8530 0.51470E+00 -0.2884 97 SO3-2 0.14198E-17 -17.8478 0.74158E-18 -18.1298 0.52230E+00 -0.2821 99 HSO4- 0.42077E-19 -19.3760 0.35186E-19 -19.4536 0.83622E+00 -0.0777 Charge balance for all species = 0.4085E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9035007E-10 -.2311219E-01 -.2325350E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981175E+06 0.0000 3 Cl- 0.1700675E-03 0.1708607E-03 0.6046552E+01 6.2720 4 SO4-- 0.9699433E-12 -.1787003E-04 -.1713514E+01 7.9399 5 HCO3- 0.3498856E-06 0.1618527E-04 0.9857910E+00 3.5860 6 HS- 0.3157751E-04 0.4945356E-04 0.1632566E+01 5.5408 7 Al+++ 0.1103777E-28 0.5273078E-05 0.1420178E+00 0.7609 8 H4SiO4 0.7116342E-03 0.1418990E-01 0.1361397E+04 -3.1477 9 Ca++ 0.1434251E-06 0.2435733E-06 0.9744247E-02 13.1066 10 Mg++ 0.2277445E-10 0.9793370E-10 0.2376651E-05 9.3053 11 Fe++ 0.6229645E-13 0.3788975E-07 0.2112196E-02 6.7428 12 K+ 0.1615823E-03 0.1623588E-03 0.6337054E+01 6.2505 13 Na+ 0.2054281E-01 0.2313430E-01 0.5308896E+03 8.3540 14 Mn++ 0.1995218E-10 0.2631040E-08 0.1442822E-03 9.2487 15 HPO4-- 0.4871207E-07 0.4996266E-07 0.4786680E-02 12.6409 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3146115E+02 -.1866366E-01 -.3144249E+02 0.0000000E+00 2 H2O 0.3169098E+02 0.4482117E+02 -.1313019E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5268095E-01 -.1443049E-04 0.5269538E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5265545E-01 0.3993496E-04 -.5269538E-01 0.0000000E+00 7 Al+++ 0.6195406E+01 0.4258139E-05 0.6195402E+01 0.0000000E+00 8 H4SiO4 0.1978428E+02 0.1145869E-01 0.1977282E+02 0.0000000E+00 9 Ca++ 0.2185284E+01 0.1966913E-06 0.2185284E+01 0.0000000E+00 10 Mg++ 0.1507936E+01 0.7908385E-10 0.1507936E+01 0.0000000E+00 11 Fe++ 0.1354716E+01 0.3059690E-07 0.1354716E+01 0.0000000E+00 12 K+ 0.4033968E+00 0.1311087E-03 0.4032657E+00 0.0000000E+00 13 Na+ 0.2385122E+01 0.1868151E-01 0.2366440E+01 0.0000000E+00 14 Mn++ 0.3294332E-01 0.2124629E-08 0.3294331E-01 0.0000000E+00 15 HPO4-- 0.1124339E-01 0.4034606E-07 0.1124335E-01 0.0000000E+00 Chg. balance for solid moles: -.5329E-14 Mass of aqueous solution: 0.808990E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1899.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.365 0.374 620.1 2.792 29.87 238.0 andradite 0.2108 -0.676 107.1 2.030 5.161 27.83 grossular 0.5033E-01 -1.298 22.67 1.355 1.092 6.308 apatite-OH 0.3748E-02 -2.426 1.883 0.275 0.9070E-01 0.5982 clinochlore 0.2716 -0.566 150.9 2.179 7.272 57.41 daphnite 0.7783E-01 -1.109 55.53 1.745 2.675 16.83 chlorite-Mn 0.6589E-02 -2.181 4.671 0.669 0.2250 1.489 diopside 0.1004 -0.998 21.74 1.337 1.048 6.646 hedenbergite 0.2572E-01 -1.590 6.382 0.805 0.3075 1.748 microcline 0.3532 -0.452 98.30 1.993 4.736 38.40 stilbite 1.230 0.090 866.6 2.938 41.75 404.2 stilpnomelane-Fe 0.1002 -0.999 108.0 2.034 5.205 37.32 tr.625ac.25prg.125 0.1371E-01 -1.863 11.72 1.069 0.5646 3.772 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1851E-01 0.1851E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.691 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2075.640685 g Volume = 840.563212 cm3 Porosity: -10.4551% V(tot) - V(min): -.79564E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1899.9990000 g log = 3.2788 Original solution: 1000.0103000 g Original solution / Rock added: 0.53 (Water/Rock Ratio), log = -0.2787 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0910 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9647E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4652E-08 1.0071 0.5111E-08 0.5075E-08 CH4,gas 0.2159E-01 1.0128 0.2386E-01 0.2356E-01 H2,gas 0.1366E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1610E-06 0.9958 0.1749E-06 0.1756E-06 S2,gas 0.4724E-29 1.0000 0.5154E-29 0.5154E-29 CO,gas 0.1809E-13 1.0000 0.1974E-13 0.1974E-13 SO3,gas 0.9850E-48 1.0000 0.1075E-47 0.1075E-47 SO2,gas 0.5556E-27 1.0000 0.6061E-27 0.6061E-27 HCl,gas 0.3272E-17 1.0000 0.3570E-17 0.3570E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.65 -10.29 -3.431 0.17572E+05 -8.292 3 CH4,gas 4.81 1.19 -3.62 -0.906 0.61850E+04 -1.622 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.70 -8.76 -4.379 0.14953E+05 -6.757 6 S2,gas -7.03 -38.32 -31.29 -4.814 0.53423E+05 -29.288 7 CO,gas 3.51 -12.19 -15.70 -4.832 0.26815E+05 -13.705 8 SO3,gas 17.43 -32.54 -49.97 -12.492 0.85320E+05 -47.969 9 SO2,gas 1.14 -28.08 -29.22 -7.791 0.49888E+05 -27.217 10 HCl,gas 5.48 -13.97 -19.45 -9.724 0.33206E+05 -17.447 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.82 -4.73 -0.236 0.80680E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94125E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76236E+04 35 aragonite 0.99 -3.55 -4.53 -1.511 0.77424E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.55 -4.38 -1.460 0.74810E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65574E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.73 -4.63 -1.322 0.78999E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66055E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.73 -4.19 -1.196 0.71460E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82287E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61285E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53669E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92773E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40697E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43446E+04 143 pyrrhotite -4.24 -7.96 -3.71 -1.238 0.63406E+04 144 pyrrhotiteFe0.875 -6.00 -9.35 -3.35 -1.233 0.57234E+04 145 pyroxmangite 7.42 6.10 -1.32 -0.263 0.22454E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28300E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23246E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47180E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91030E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.96 -3.56 -1.188 0.60838E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80426E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66780E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60332E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66245E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.45 -4.49 -1.496 0.76644E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 1899.9990000 g New total amount of reactant added: 1999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3299E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 1999.9990000 Water: Moles liquid = 0.4427E+02 kg liquid = 0.7975E+00 Moles total = 0.3044E+02 kg total = 0.5483E+00 Activity = 1.0000 Stoichiometric ionic strength = .1175785E-01 Osmotic coef. = 0.9687 True ionic strength = .2070707E-01 Chg. balance for total moles = 0.3299E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90356E-10 -10.0440 0.75801E-10 -10.1203 0.83891E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17221E-03 -3.7639 0.14358E-03 -3.8429 0.83376E+00 -0.0790 4 SO4-- 0.98214E-12 -12.0078 0.50659E-12 -12.2953 0.51581E+00 -0.2875 5 HCO3- 0.35428E-06 -6.4506 0.29583E-06 -6.5290 0.83500E+00 -0.0783 6 HS- 0.31975E-04 -4.4952 0.26664E-04 -4.5741 0.83388E+00 -0.0789 7 Al+++ 0.11040E-28 -28.9570 0.25114E-29 -29.6001 0.22747E+00 -0.6431 8 H4SiO4 0.71164E-03 -3.1477 0.71164E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14345E-06 -6.8433 0.73435E-07 -7.1341 0.51193E+00 -0.2908 10 Mg++ 0.22778E-10 -10.6425 0.11606E-10 -10.9353 0.50954E+00 -0.2928 11 Fe++ 0.62305E-13 -13.2055 0.31783E-13 -13.4978 0.51011E+00 -0.2923 12 K+ 0.16159E-03 -3.7916 0.13496E-03 -3.8698 0.83520E+00 -0.0782 13 Na+ 0.20544E-01 -1.6873 0.17126E-01 -1.7664 0.83360E+00 -0.0790 14 Mn++ 0.19960E-10 -10.6998 0.10190E-10 -10.9918 0.51055E+00 -0.2920 15 HPO4-- 0.48707E-07 -7.3124 0.25127E-07 -7.5999 0.51588E+00 -0.2875 16 HSiO3- 0.10986E-01 -1.9592 0.91598E-02 -2.0381 0.83376E+00 -0.0790 17 Ca(HSiO3)+ 0.18041E-07 -7.7437 0.15071E-07 -7.8219 0.83538E+00 -0.0781 18 Mg(HSiO3)+ 0.35485E-11 -11.4500 0.29643E-11 -11.5281 0.83538E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6036 0.24914E-02 -2.6036 0.10000E+01 0.0000 20 AlO+ 0.67545E-16 -16.1704 0.56425E-16 -16.2485 0.83538E+00 -0.0781 22 HAlO2,aq 0.14896E-09 -9.8269 0.14896E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52726E-05 -5.2780 0.43880E-05 -5.3577 0.83223E+00 -0.0798 24 CH4,aq 0.15333E-04 -4.8144 0.15278E-04 -4.8159 0.99642E+00 -0.0016 25 C2H6,aq 0.37165E-14 -14.4299 0.37032E-14 -14.4314 0.99642E+00 -0.0016 29 CO,aq 0.12658E-16 -16.8976 0.12658E-16 -16.8976 0.10000E+01 0.0000 30 CO2,aq 0.45374E-10 -10.3432 0.45211E-10 -10.3448 0.99642E+00 -0.0016 31 CO3-2 0.70109E-06 -6.1542 0.36084E-06 -6.4427 0.51469E+00 -0.2885 32 CaCO3,aq 0.32454E-09 -9.4887 0.32454E-09 -9.4887 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.65524E-12 -12.1836 0.54738E-12 -12.2617 0.83538E+00 -0.0781 34 CaCl+ 0.20112E-10 -10.6965 0.16801E-10 -10.7747 0.83538E+00 -0.0781 35 CaCl2,aq 0.56169E-15 -15.2505 0.56169E-15 -15.2505 0.10000E+01 0.0000 36 CaOH+ 0.81773E-07 -7.0874 0.68312E-07 -7.1655 0.83538E+00 -0.0781 37 CaSO4,aq 0.11591E-16 -16.9359 0.11591E-16 -16.9359 0.10000E+01 0.0000 38 HCl,aq 0.20472E-14 -14.6888 0.20472E-14 -14.6888 0.10000E+01 0.0000 43 FeCl+ 0.85082E-17 -17.0702 0.71076E-17 -17.1483 0.83538E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16640E-10 -10.7789 0.13901E-10 -10.8570 0.83538E+00 -0.0781 48 HFeO2- 0.37228E-07 -7.4291 0.31039E-07 -7.5081 0.83376E+00 -0.0790 49 FeO+ 0.12282E-16 -16.9107 0.10260E-16 -16.9889 0.83538E+00 -0.0781 51 FeO2- 0.42092E-09 -9.3758 0.35095E-09 -9.4548 0.83376E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4777 0.33293E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.34312E-09 -9.4646 0.34312E-09 -9.4646 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.12634E-14 -14.8985 0.10534E-14 -14.9774 0.83376E+00 -0.0790 58 MgCO3,aq 0.12817E-13 -13.8922 0.12817E-13 -13.8922 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10560E-15 -15.9763 0.88219E-16 -16.0544 0.83538E+00 -0.0781 60 MgCl+ 0.28857E-14 -14.5397 0.24107E-14 -14.6179 0.83538E+00 -0.0781 61 MgOH+ 0.71600E-10 -10.1451 0.59814E-10 -10.2232 0.83538E+00 -0.0781 63 MnO,aq 0.18722E-08 -8.7276 0.18722E-08 -8.7276 0.10000E+01 0.0000 64 MnOH+ 0.49562E-09 -9.3048 0.41403E-09 -9.3830 0.83538E+00 -0.0781 65 MnO2-2 0.21895E-10 -10.6597 0.11269E-10 -10.9481 0.51469E+00 -0.2885 66 HMnO2- 0.22197E-09 -9.6537 0.18507E-09 -9.7327 0.83376E+00 -0.0790 69 MnCl+ 0.10600E-13 -13.9747 0.88554E-14 -14.0528 0.83538E+00 -0.0781 71 NaCl,aq 0.80290E-06 -6.0953 0.80290E-06 -6.0953 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95086E-02 -2.0219 0.79133E-02 -2.1016 0.83223E+00 -0.0798 79 HPO3-2 0.16763E-14 -14.7757 0.86276E-15 -15.0641 0.51469E+00 -0.2885 81 H2PO3- 0.15408E-18 -18.8123 0.12846E-18 -18.8912 0.83376E+00 -0.0790 82 H3PO4,aq 0.92947E-18 -18.0318 0.92947E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40012E-10 -10.3978 0.33392E-10 -10.4764 0.83456E+00 -0.0785 84 PO4-3 0.12104E-08 -8.9171 0.28949E-09 -9.5384 0.23917E+00 -0.6213 88 HP2O7-3 0.10367E-17 -17.9843 0.23608E-18 -18.6269 0.22771E+00 -0.6426 89 P2O7-4 0.10236E-16 -16.9899 0.76833E-18 -18.1145 0.75059E-01 -1.1246 90 H2S,aq 0.60944E-08 -8.2151 0.60726E-08 -8.2166 0.99642E+00 -0.0016 91 S2-2 0.27947E-14 -14.5537 0.14384E-14 -14.8421 0.51469E+00 -0.2885 97 SO3-2 0.14377E-17 -17.8423 0.75088E-18 -18.1244 0.52229E+00 -0.2821 99 HSO4- 0.42609E-19 -19.3705 0.35630E-19 -19.4482 0.83621E+00 -0.0777 Charge balance for all species = 0.4136E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9035615E-10 -.2311104E-01 -.2325235E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981175E+06 0.0000 3 Cl- 0.1722100E-03 0.1730132E-03 0.6122727E+01 6.2774 4 SO4-- 0.9821406E-12 -.1806085E-04 -.1731811E+01 7.9453 5 HCO3- 0.3542837E-06 0.1638917E-04 0.9982100E+00 3.5914 6 HS- 0.3197533E-04 0.5004227E-04 0.1652000E+01 5.5462 7 Al+++ 0.1104021E-28 0.5272724E-05 0.1420083E+00 0.7609 8 H4SiO4 0.7116363E-03 0.1418930E-01 0.1361340E+04 -3.1477 9 Ca++ 0.1434454E-06 0.2436043E-06 0.9745488E-02 13.1066 10 Mg++ 0.2277767E-10 0.9794154E-10 0.2376841E-05 9.3053 11 Fe++ 0.6230537E-13 0.3788751E-07 0.2112071E-02 6.7428 12 K+ 0.1615932E-03 0.1623697E-03 0.6337479E+01 6.2505 13 Na+ 0.2054420E-01 0.2313571E-01 0.5309218E+03 8.3540 14 Mn++ 0.1995993E-10 0.2631704E-08 0.1443186E-03 9.2488 15 HPO4-- 0.4870705E-07 0.4995746E-07 0.4786182E-02 12.6408 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3311700E+02 -.1843054E-01 -.3309857E+02 0.0000000E+00 2 H2O 0.3043744E+02 0.4426353E+02 -.1382609E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5545229E-01 -.1440312E-04 0.5546670E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5542679E-01 0.3990759E-04 -.5546670E-01 0.0000000E+00 7 Al+++ 0.6521480E+01 0.4204880E-05 0.6521476E+01 0.0000000E+00 8 H4SiO4 0.2082556E+02 0.1131565E-01 0.2081424E+02 0.0000000E+00 9 Ca++ 0.2300299E+01 0.1942690E-06 0.2300298E+01 0.0000000E+00 10 Mg++ 0.1587301E+01 0.7810619E-10 0.1587301E+01 0.0000000E+00 11 Fe++ 0.1426016E+01 0.3021445E-07 0.1426016E+01 0.0000000E+00 12 K+ 0.4246282E+00 0.1294862E-03 0.4244988E+00 0.0000000E+00 13 Na+ 0.2510646E+01 0.1845021E-01 0.2492196E+01 0.0000000E+00 14 Mn++ 0.3467717E-01 0.2098725E-08 0.3467717E-01 0.0000000E+00 15 HPO4-- 0.1183515E-01 0.3983996E-07 0.1183511E-01 0.0000000E+00 Chg. balance for solid moles: 0.2262E-14 Mass of aqueous solution: 0.798925E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 1999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.490 0.396 653.0 2.815 29.89 250.7 andradite 0.2219 -0.654 112.7 2.052 5.160 29.29 grossular 0.5298E-01 -1.276 23.86 1.378 1.092 6.640 apatite-OH 0.3945E-02 -2.404 1.982 0.297 0.9070E-01 0.6297 clinochlore 0.2858 -0.544 158.8 2.201 7.270 60.42 daphnite 0.8190E-01 -1.087 58.44 1.767 2.675 17.71 chlorite-Mn 0.6935E-02 -2.159 4.917 0.692 0.2250 1.567 diopside 0.1062 -0.974 23.00 1.362 1.053 7.029 hedenbergite 0.2721E-01 -1.565 6.750 0.829 0.3089 1.849 microcline 0.3717 -0.430 103.5 2.015 4.736 40.42 stilbite 1.294 0.112 911.8 2.960 41.73 425.3 stilpnomelane-Fe 0.1055 -0.977 113.7 2.056 5.206 39.29 tr.625ac.25prg.125 0.1439E-01 -1.842 12.30 1.090 0.5631 3.960 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1851E-01 0.1851E-01 1.0000 -1.733 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2184.896166 g Volume = 884.769569 cm3 Porosity: -10.4582% V(tot) - V(min): -.83770E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 1999.9990000 g log = 3.3010 Original solution: 1000.0103000 g Original solution / Rock added: 0.50 (Water/Rock Ratio), log = -0.3010 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0913 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9645E+00 0.9850 0.1037E+01 0.1052E+01 CO2,gas 0.4709E-08 1.0071 0.5175E-08 0.5139E-08 CH4,gas 0.2186E-01 1.0128 0.2416E-01 0.2386E-01 H2,gas 0.1366E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1630E-06 0.9958 0.1771E-06 0.1779E-06 S2,gas 0.4843E-29 1.0000 0.5285E-29 0.5285E-29 CO,gas 0.1832E-13 1.0000 0.1999E-13 0.1999E-13 SO3,gas 0.9972E-48 1.0000 0.1088E-47 0.1088E-47 SO2,gas 0.5625E-27 1.0000 0.6138E-27 0.6138E-27 HCl,gas 0.3312E-17 1.0000 0.3615E-17 0.3615E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 -0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 -0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.65 -10.29 -3.429 0.17563E+05 -8.286 3 CH4,gas 4.81 1.19 -3.62 -0.904 0.61757E+04 -1.617 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.69 -8.75 -4.376 0.14943E+05 -6.752 6 S2,gas -7.03 -38.31 -31.28 -4.812 0.53405E+05 -29.277 7 CO,gas 3.51 -12.19 -15.70 -4.831 0.26806E+05 -13.699 8 SO3,gas 17.43 -32.54 -49.96 -12.491 0.85311E+05 -47.963 9 SO2,gas 1.14 -28.08 -29.21 -7.790 0.49879E+05 -27.212 10 HCl,gas 5.48 -13.96 -19.44 -9.721 0.33197E+05 -17.442 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80675E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94126E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76236E+04 35 aragonite 0.99 -3.54 -4.53 -1.510 0.77331E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.54 -4.38 -1.459 0.74717E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39558E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65572E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.73 -4.62 -1.320 0.78906E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66055E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.73 -4.18 -1.194 0.71367E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22974E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48205E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82285E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61285E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53669E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92773E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40697E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43446E+04 143 pyrrhotite -4.24 -7.95 -3.71 -1.236 0.63313E+04 144 pyrrhotiteFe0.875 -6.00 -9.35 -3.35 -1.231 0.57141E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22452E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28300E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23244E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47177E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91029E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.95 -3.56 -1.186 0.60745E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80427E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66781E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60332E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68740E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57933E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.45 -4.48 -1.494 0.76549E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 1999.9990000 g New total amount of reactant added: 2099.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2099.9990000 Water: Moles liquid = 0.4371E+02 kg liquid = 0.7874E+00 Moles total = 0.2918E+02 kg total = 0.5258E+00 Activity = 1.0000 Stoichiometric ionic strength = .1175969E-01 Osmotic coef. = 0.9686 True ionic strength = .2070851E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90362E-10 -10.0440 0.75806E-10 -10.1203 0.83891E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17441E-03 -3.7584 0.14541E-03 -3.8374 0.83375E+00 -0.0790 4 SO4-- 0.99465E-12 -12.0023 0.51303E-12 -12.2899 0.51580E+00 -0.2875 5 HCO3- 0.35879E-06 -6.4452 0.29959E-06 -6.5235 0.83499E+00 -0.0783 6 HS- 0.32383E-04 -4.4897 0.27004E-04 -4.5686 0.83388E+00 -0.0789 7 Al+++ 0.11043E-28 -28.9569 0.25118E-29 -29.6000 0.22746E+00 -0.6431 8 H4SiO4 0.71164E-03 -3.1477 0.71164E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14347E-06 -6.8433 0.73444E-07 -7.1340 0.51192E+00 -0.2908 10 Mg++ 0.22781E-10 -10.6424 0.11608E-10 -10.9353 0.50953E+00 -0.2928 11 Fe++ 0.62315E-13 -13.2054 0.31787E-13 -13.4978 0.51010E+00 -0.2923 12 K+ 0.16160E-03 -3.7915 0.13497E-03 -3.8698 0.83520E+00 -0.0782 13 Na+ 0.20546E-01 -1.6873 0.17127E-01 -1.7663 0.83359E+00 -0.0790 14 Mn++ 0.19967E-10 -10.6997 0.10194E-10 -10.9917 0.51054E+00 -0.2920 15 HPO4-- 0.48702E-07 -7.3125 0.25124E-07 -7.5999 0.51587E+00 -0.2875 16 HSiO3- 0.10986E-01 -1.9592 0.91592E-02 -2.0381 0.83375E+00 -0.0790 17 Ca(HSiO3)+ 0.18042E-07 -7.7437 0.15072E-07 -7.8218 0.83538E+00 -0.0781 18 Mg(HSiO3)+ 0.35487E-11 -11.4499 0.29645E-11 -11.5280 0.83538E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6035 0.24914E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67549E-16 -16.1704 0.56429E-16 -16.2485 0.83538E+00 -0.0781 22 HAlO2,aq 0.14896E-09 -9.8269 0.14896E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52722E-05 -5.2780 0.43877E-05 -5.3578 0.83222E+00 -0.0798 24 CH4,aq 0.15529E-04 -4.8089 0.15473E-04 -4.8104 0.99642E+00 -0.0016 25 C2H6,aq 0.38120E-14 -14.4188 0.37984E-14 -14.4204 0.99642E+00 -0.0016 29 CO,aq 0.12820E-16 -16.8921 0.12820E-16 -16.8921 0.10000E+01 0.0000 30 CO2,aq 0.45954E-10 -10.3377 0.45789E-10 -10.3392 0.99642E+00 -0.0016 31 CO3-2 0.70997E-06 -6.1488 0.36541E-06 -6.4372 0.51468E+00 -0.2885 32 CaCO3,aq 0.32869E-09 -9.4832 0.32869E-09 -9.4832 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.66367E-12 -12.1781 0.55441E-12 -12.2562 0.83538E+00 -0.0781 34 CaCl+ 0.20371E-10 -10.6910 0.17018E-10 -10.7691 0.83538E+00 -0.0781 35 CaCl2,aq 0.57618E-15 -15.2394 0.57618E-15 -15.2394 0.10000E+01 0.0000 36 CaOH+ 0.81778E-07 -7.0874 0.68316E-07 -7.1655 0.83538E+00 -0.0781 37 CaSO4,aq 0.11740E-16 -16.9303 0.11740E-16 -16.9303 0.10000E+01 0.0000 38 HCl,aq 0.20734E-14 -14.6833 0.20734E-14 -14.6833 0.10000E+01 0.0000 43 FeCl+ 0.86178E-17 -17.0646 0.71991E-17 -17.1427 0.83538E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16641E-10 -10.7788 0.13902E-10 -10.8569 0.83538E+00 -0.0781 48 HFeO2- 0.37226E-07 -7.4292 0.31037E-07 -7.5081 0.83375E+00 -0.0790 49 FeO+ 0.12282E-16 -16.9107 0.10260E-16 -16.9888 0.83538E+00 -0.0781 51 FeO2- 0.42090E-09 -9.3758 0.35093E-09 -9.4548 0.83375E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4777 0.33293E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.34752E-09 -9.4590 0.34752E-09 -9.4590 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.12795E-14 -14.8929 0.10668E-14 -14.9719 0.83375E+00 -0.0790 58 MgCO3,aq 0.12981E-13 -13.8867 0.12981E-13 -13.8867 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10696E-15 -15.9708 0.89353E-16 -16.0489 0.83538E+00 -0.0781 60 MgCl+ 0.29229E-14 -14.5342 0.24417E-14 -14.6123 0.83538E+00 -0.0781 61 MgOH+ 0.71605E-10 -10.1451 0.59817E-10 -10.2232 0.83538E+00 -0.0781 63 MnO,aq 0.18727E-08 -8.7275 0.18727E-08 -8.7275 0.10000E+01 0.0000 64 MnOH+ 0.49577E-09 -9.3047 0.41415E-09 -9.3828 0.83538E+00 -0.0781 65 MnO2-2 0.21897E-10 -10.6596 0.11270E-10 -10.9481 0.51468E+00 -0.2885 66 HMnO2- 0.22201E-09 -9.6536 0.18510E-09 -9.7326 0.83375E+00 -0.0790 69 MnCl+ 0.10739E-13 -13.9690 0.89715E-14 -14.0471 0.83538E+00 -0.0781 71 NaCl,aq 0.81319E-06 -6.0898 0.81319E-06 -6.0898 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95080E-02 -2.0219 0.79128E-02 -2.1017 0.83222E+00 -0.0798 79 HPO3-2 0.16761E-14 -14.7757 0.86264E-15 -15.0642 0.51468E+00 -0.2885 81 H2PO3- 0.15407E-18 -18.8123 0.12845E-18 -18.8913 0.83375E+00 -0.0790 82 H3PO4,aq 0.92947E-18 -18.0318 0.92947E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40010E-10 -10.3978 0.33390E-10 -10.4764 0.83456E+00 -0.0785 84 PO4-3 0.12102E-08 -8.9171 0.28944E-09 -9.5384 0.23916E+00 -0.6213 88 HP2O7-3 0.10366E-17 -17.9844 0.23603E-18 -18.6270 0.22770E+00 -0.6426 89 P2O7-4 0.10234E-16 -16.9899 0.76814E-18 -18.1146 0.75054E-01 -1.1246 90 H2S,aq 0.61725E-08 -8.2095 0.61504E-08 -8.2111 0.99642E+00 -0.0016 91 S2-2 0.28665E-14 -14.5427 0.14753E-14 -14.8311 0.51468E+00 -0.2885 97 SO3-2 0.14560E-17 -17.8368 0.76043E-18 -18.1189 0.52228E+00 -0.2821 99 HSO4- 0.43153E-19 -19.3650 0.36085E-19 -19.4427 0.83621E+00 -0.0777 Charge balance for all species = 0.4188E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9036237E-10 -.2310986E-01 -.2325116E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981174E+06 0.0000 3 Cl- 0.1744071E-03 0.1752207E-03 0.6200845E+01 6.2829 4 SO4-- 0.9946454E-12 -.1825654E-04 -.1750575E+01 7.9507 5 HCO3- 0.3587927E-06 0.1659828E-04 0.1010946E+01 3.5968 6 HS- 0.3238329E-04 0.5064601E-04 0.1671931E+01 5.5517 7 Al+++ 0.1104272E-28 0.5272368E-05 0.1419987E+00 0.7609 8 H4SiO4 0.7116382E-03 0.1418868E-01 0.1361280E+04 -3.1477 9 Ca++ 0.1434662E-06 0.2436362E-06 0.9746763E-02 13.1066 10 Mg++ 0.2278097E-10 0.9795070E-10 0.2377064E-05 9.3053 11 Fe++ 0.6231452E-13 0.3788522E-07 0.2111943E-02 6.7428 12 K+ 0.1616043E-03 0.1623809E-03 0.6337914E+01 6.2505 13 Na+ 0.2054562E-01 0.2313714E-01 0.5309548E+03 8.3540 14 Mn++ 0.1996730E-10 0.2632307E-08 0.1443517E-03 9.2489 15 HPO4-- 0.4870188E-07 0.4995211E-07 0.4785668E-02 12.6407 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3477285E+02 -.1819742E-01 -.3475466E+02 0.0000000E+00 2 H2O 0.2918390E+02 0.4370590E+02 -.1452200E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.5822364E-01 -.1437576E-04 0.5823801E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.5819813E-01 0.3988023E-04 -.5823801E-01 0.0000000E+00 7 Al+++ 0.6847554E+01 0.4151626E-05 0.6847550E+01 0.0000000E+00 8 H4SiO4 0.2186683E+02 0.1117260E-01 0.2185566E+02 0.0000000E+00 9 Ca++ 0.2415313E+01 0.1918467E-06 0.2415313E+01 0.0000000E+00 10 Mg++ 0.1666666E+01 0.7712941E-10 0.1666666E+01 0.0000000E+00 11 Fe++ 0.1497317E+01 0.2983200E-07 0.1497317E+01 0.0000000E+00 12 K+ 0.4458597E+00 0.1278637E-03 0.4457318E+00 0.0000000E+00 13 Na+ 0.2636170E+01 0.1821890E-01 0.2617952E+01 0.0000000E+00 14 Mn++ 0.3641103E-01 0.2072760E-08 0.3641103E-01 0.0000000E+00 15 HPO4-- 0.1242690E-01 0.3933383E-07 0.1242687E-01 0.0000000E+00 Chg. balance for solid moles: -.5738E-14 Mass of aqueous solution: 0.788860E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2099.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.616 0.418 686.0 2.836 29.90 263.3 andradite 0.2330 -0.633 118.4 2.073 5.160 30.76 grossular 0.5563E-01 -1.255 25.06 1.399 1.092 6.972 apatite-OH 0.4142E-02 -2.383 2.081 0.318 0.9070E-01 0.6612 clinochlore 0.3000 -0.523 166.8 2.222 7.269 63.43 daphnite 0.8598E-01 -1.066 61.35 1.788 2.674 18.59 chlorite-Mn 0.7282E-02 -2.138 5.163 0.713 0.2250 1.645 diopside 0.1120 -0.951 24.25 1.385 1.057 7.411 hedenbergite 0.2869E-01 -1.542 7.117 0.852 0.3102 1.949 microcline 0.3903 -0.409 108.6 2.036 4.736 42.44 stilbite 1.358 0.133 957.0 2.981 41.72 446.4 stilpnomelane-Fe 0.1108 -0.955 119.4 2.077 5.206 41.26 tr.625ac.25prg.125 0.1507E-01 -1.822 12.89 1.110 0.5616 4.147 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7629E+00 0.7629E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1852E-01 0.1852E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2294.151647 g Volume = 928.975926 cm3 Porosity: -10.4609% V(tot) - V(min): -.87976E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2099.9990000 g log = 3.3222 Original solution: 1000.0103000 g Original solution / Rock added: 0.48 (Water/Rock Ratio), log = -0.3222 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0916 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9642E+00 0.9850 0.1037E+01 0.1053E+01 CO2,gas 0.4768E-08 1.0071 0.5241E-08 0.5205E-08 CH4,gas 0.2213E-01 1.0128 0.2447E-01 0.2416E-01 H2,gas 0.1365E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1650E-06 0.9958 0.1794E-06 0.1801E-06 S2,gas 0.4967E-29 1.0000 0.5421E-29 0.5421E-29 CO,gas 0.1854E-13 1.0000 0.2024E-13 0.2024E-13 SO3,gas 0.1010E-47 1.0000 0.1102E-47 0.1102E-47 SO2,gas 0.5695E-27 1.0000 0.6217E-27 0.6217E-27 HCl,gas 0.3354E-17 1.0000 0.3661E-17 0.3661E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.64 -10.28 -3.427 0.17554E+05 -8.281 3 CH4,gas 4.81 1.20 -3.61 -0.903 0.61663E+04 -1.611 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.69 -8.75 -4.373 0.14934E+05 -6.746 6 S2,gas -7.03 -38.30 -31.27 -4.810 0.53386E+05 -29.266 7 CO,gas 3.51 -12.18 -15.69 -4.829 0.26797E+05 -13.694 8 SO3,gas 17.43 -32.53 -49.96 -12.489 0.85302E+05 -47.958 9 SO2,gas 1.14 -28.07 -29.21 -7.788 0.49869E+05 -27.206 10 HCl,gas 5.48 -13.96 -19.44 -9.718 0.33187E+05 -17.436 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80670E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94126E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76236E+04 35 aragonite 0.99 -3.54 -4.52 -1.508 0.77236E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.54 -4.37 -1.457 0.74623E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82193E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70378E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65571E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.72 -4.62 -1.319 0.78812E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66055E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.72 -4.17 -1.193 0.71273E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82283E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61285E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53670E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92773E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40698E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43447E+04 143 pyrrhotite -4.24 -7.95 -3.70 -1.234 0.63219E+04 144 pyrrhotiteFe0.875 -6.00 -9.34 -3.34 -1.229 0.57046E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22450E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28300E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23243E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47173E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91029E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.95 -3.55 -1.184 0.60651E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80428E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66781E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60331E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52963E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.44 -4.48 -1.493 0.76453E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2099.9990000 g New total amount of reactant added: 2199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2199.9990000 Water: Moles liquid = 0.4315E+02 kg liquid = 0.7774E+00 Moles total = 0.2793E+02 kg total = 0.5032E+00 Activity = 1.0000 Stoichiometric ionic strength = .1176158E-01 Osmotic coef. = 0.9686 True ionic strength = .2070999E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90369E-10 -10.0440 0.75811E-10 -10.1203 0.83890E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17666E-03 -3.7529 0.14729E-03 -3.8318 0.83375E+00 -0.0790 4 SO4-- 0.10075E-11 -11.9968 0.51964E-12 -12.2843 0.51579E+00 -0.2875 5 HCO3- 0.36342E-06 -6.4396 0.30345E-06 -6.5179 0.83499E+00 -0.0783 6 HS- 0.32802E-04 -4.4841 0.27353E-04 -4.5630 0.83387E+00 -0.0789 7 Al+++ 0.11045E-28 -28.9568 0.25123E-29 -29.5999 0.22745E+00 -0.6431 8 H4SiO4 0.71164E-03 -3.1477 0.71164E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14349E-06 -6.8432 0.73453E-07 -7.1340 0.51191E+00 -0.2908 10 Mg++ 0.22784E-10 -10.6424 0.11609E-10 -10.9352 0.50952E+00 -0.2928 11 Fe++ 0.62324E-13 -13.2053 0.31791E-13 -13.4977 0.51009E+00 -0.2923 12 K+ 0.16162E-03 -3.7915 0.13498E-03 -3.8697 0.83519E+00 -0.0782 13 Na+ 0.20547E-01 -1.6873 0.17128E-01 -1.7663 0.83359E+00 -0.0790 14 Mn++ 0.19974E-10 -10.6995 0.10197E-10 -10.9915 0.51053E+00 -0.2920 15 HPO4-- 0.48697E-07 -7.3125 0.25121E-07 -7.6000 0.51586E+00 -0.2875 16 HSiO3- 0.10985E-01 -1.9592 0.91587E-02 -2.0382 0.83375E+00 -0.0790 17 Ca(HSiO3)+ 0.18043E-07 -7.7437 0.15073E-07 -7.8218 0.83537E+00 -0.0781 18 Mg(HSiO3)+ 0.35490E-11 -11.4499 0.29647E-11 -11.5280 0.83537E+00 -0.0781 19 NaHSiO3,aq 0.24914E-02 -2.6035 0.24914E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67553E-16 -16.1704 0.56432E-16 -16.2485 0.83537E+00 -0.0781 22 HAlO2,aq 0.14896E-09 -9.8269 0.14896E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52719E-05 -5.2780 0.43873E-05 -5.3578 0.83222E+00 -0.0798 24 CH4,aq 0.15730E-04 -4.8033 0.15674E-04 -4.8048 0.99642E+00 -0.0016 25 C2H6,aq 0.39113E-14 -14.4077 0.38972E-14 -14.4092 0.99642E+00 -0.0016 29 CO,aq 0.12986E-16 -16.8865 0.12986E-16 -16.8865 0.10000E+01 0.0000 30 CO2,aq 0.46549E-10 -10.3321 0.46382E-10 -10.3336 0.99642E+00 -0.0016 31 CO3-2 0.71909E-06 -6.1432 0.37009E-06 -6.4317 0.51467E+00 -0.2885 32 CaCO3,aq 0.33294E-09 -9.4776 0.33294E-09 -9.4776 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.67231E-12 -12.1724 0.56163E-12 -12.2506 0.83537E+00 -0.0781 34 CaCl+ 0.20637E-10 -10.6853 0.17240E-10 -10.7635 0.83537E+00 -0.0781 35 CaCl2,aq 0.59124E-15 -15.2282 0.59124E-15 -15.2282 0.10000E+01 0.0000 36 CaOH+ 0.81784E-07 -7.0873 0.68320E-07 -7.1655 0.83537E+00 -0.0781 37 CaSO4,aq 0.11893E-16 -16.9247 0.11893E-16 -16.9247 0.10000E+01 0.0000 38 HCl,aq 0.21003E-14 -14.6777 0.21003E-14 -14.6777 0.10000E+01 0.0000 43 FeCl+ 0.87303E-17 -17.0590 0.72931E-17 -17.1371 0.83537E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16642E-10 -10.7788 0.13902E-10 -10.8569 0.83537E+00 -0.0781 48 HFeO2- 0.37223E-07 -7.4292 0.31035E-07 -7.5082 0.83375E+00 -0.0790 49 FeO+ 0.12283E-16 -16.9107 0.10261E-16 -16.9888 0.83537E+00 -0.0781 51 FeO2- 0.42088E-09 -9.3758 0.35090E-09 -9.4548 0.83375E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4777 0.33293E-11 -11.4777 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99642E+00 -0.0016 54 KCl,aq 0.35203E-09 -9.4534 0.35203E-09 -9.4534 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.12961E-14 -14.8874 0.10806E-14 -14.9663 0.83375E+00 -0.0790 58 MgCO3,aq 0.13149E-13 -13.8811 0.13149E-13 -13.8811 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10835E-15 -15.9652 0.90516E-16 -16.0433 0.83537E+00 -0.0781 60 MgCl+ 0.29611E-14 -14.5286 0.24736E-14 -14.6067 0.83537E+00 -0.0781 61 MgOH+ 0.71610E-10 -10.1450 0.59821E-10 -10.2231 0.83537E+00 -0.0781 63 MnO,aq 0.18730E-08 -8.7275 0.18730E-08 -8.7275 0.10000E+01 0.0000 64 MnOH+ 0.49590E-09 -9.3046 0.41426E-09 -9.3827 0.83537E+00 -0.0781 65 MnO2-2 0.21899E-10 -10.6596 0.11271E-10 -10.9480 0.51467E+00 -0.2885 66 HMnO2- 0.22204E-09 -9.6536 0.18513E-09 -9.7325 0.83375E+00 -0.0790 69 MnCl+ 0.10882E-13 -13.9633 0.90904E-14 -14.0414 0.83537E+00 -0.0781 71 NaCl,aq 0.82375E-06 -6.0842 0.82375E-06 -6.0842 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95075E-02 -2.0219 0.79123E-02 -2.1017 0.83222E+00 -0.0798 79 HPO3-2 0.16759E-14 -14.7758 0.86253E-15 -15.0642 0.51467E+00 -0.2885 81 H2PO3- 0.15406E-18 -18.8123 0.12845E-18 -18.8913 0.83375E+00 -0.0790 82 H3PO4,aq 0.92948E-18 -18.0318 0.92948E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40007E-10 -10.3979 0.33388E-10 -10.4764 0.83455E+00 -0.0785 84 PO4-3 0.12100E-08 -8.9172 0.28938E-09 -9.5385 0.23915E+00 -0.6213 88 HP2O7-3 0.10364E-17 -17.9845 0.23599E-18 -18.6271 0.22770E+00 -0.6426 89 P2O7-4 0.10233E-16 -16.9900 0.76794E-18 -18.1147 0.75048E-01 -1.1247 90 H2S,aq 0.62527E-08 -8.2039 0.62303E-08 -8.2055 0.99642E+00 -0.0016 91 S2-2 0.29411E-14 -14.5315 0.15137E-14 -14.8200 0.51467E+00 -0.2885 97 SO3-2 0.14747E-17 -17.8313 0.77021E-18 -18.1134 0.52227E+00 -0.2821 99 HSO4- 0.43712E-19 -19.3594 0.36552E-19 -19.4371 0.83621E+00 -0.0777 Charge balance for all species = 0.4242E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9036874E-10 -.2310865E-01 -.2324993E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981173E+06 0.0000 3 Cl- 0.1766611E-03 0.1774852E-03 0.6280983E+01 6.2884 4 SO4-- 0.1007470E-11 -.1845729E-04 -.1769825E+01 7.9562 5 HCO3- 0.3634170E-06 0.1681279E-04 0.1024011E+01 3.6024 6 HS- 0.3280181E-04 0.5126535E-04 0.1692376E+01 5.5573 7 Al+++ 0.1104530E-28 0.5272008E-05 0.1419890E+00 0.7609 8 H4SiO4 0.7116399E-03 0.1418804E-01 0.1361219E+04 -3.1477 9 Ca++ 0.1434875E-06 0.2436689E-06 0.9748072E-02 13.1066 10 Mg++ 0.2278436E-10 0.9795925E-10 0.2377271E-05 9.3053 11 Fe++ 0.6232390E-13 0.3788288E-07 0.2111813E-02 6.7428 12 K+ 0.1616157E-03 0.1623923E-03 0.6338360E+01 6.2505 13 Na+ 0.2054707E-01 0.2313862E-01 0.5309885E+03 8.3540 14 Mn++ 0.1997434E-10 0.2632859E-08 0.1443820E-03 9.2490 15 HPO4-- 0.4869656E-07 0.4994660E-07 0.4785140E-02 12.6406 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3642870E+02 -.1796430E-01 -.3641074E+02 0.0000000E+00 2 H2O 0.2793036E+02 0.4314826E+02 -.1521790E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6099498E-01 -.1434841E-04 0.6100932E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6096947E-01 0.3985288E-04 -.6100932E-01 0.0000000E+00 7 Al+++ 0.7173628E+01 0.4098376E-05 0.7173624E+01 0.0000000E+00 8 H4SiO4 0.2290811E+02 0.1102956E-01 0.2289708E+02 0.0000000E+00 9 Ca++ 0.2530327E+01 0.1894244E-06 0.2530327E+01 0.0000000E+00 10 Mg++ 0.1746031E+01 0.7615197E-10 0.1746031E+01 0.0000000E+00 11 Fe++ 0.1568618E+01 0.2944956E-07 0.1568618E+01 0.0000000E+00 12 K+ 0.4670911E+00 0.1262412E-03 0.4669648E+00 0.0000000E+00 13 Na+ 0.2761695E+01 0.1798760E-01 0.2743707E+01 0.0000000E+00 14 Mn++ 0.3814489E-01 0.2046743E-08 0.3814489E-01 0.0000000E+00 15 HPO4-- 0.1301866E-01 0.3882770E-07 0.1301862E-01 0.0000000E+00 Chg. balance for solid moles: 0.6845E-14 Mass of aqueous solution: 0.778795E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.742 0.438 718.9 2.857 29.91 276.0 andradite 0.2440 -0.613 124.0 2.093 5.160 32.22 grossular 0.5827E-01 -1.235 26.25 1.419 1.092 7.303 apatite-OH 0.4340E-02 -2.363 2.180 0.338 0.9070E-01 0.6927 clinochlore 0.3142 -0.503 174.7 2.242 7.267 66.44 daphnite 0.9006E-01 -1.045 64.26 1.808 2.674 19.47 chlorite-Mn 0.7629E-02 -2.118 5.409 0.733 0.2250 1.724 diopside 0.1178 -0.929 25.50 1.407 1.061 7.794 hedenbergite 0.3017E-01 -1.520 7.485 0.874 0.3114 2.050 microcline 0.4089 -0.388 113.8 2.056 4.736 44.46 stilbite 1.422 0.153 1002. 3.001 41.70 467.5 stilpnomelane-Fe 0.1161 -0.935 125.1 2.097 5.206 43.22 tr.625ac.25prg.125 0.1576E-01 -1.803 13.47 1.129 0.5604 4.335 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1852E-01 0.1852E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2403.407128 g Volume = 973.182283 cm3 Porosity: -10.4634% V(tot) - V(min): -.92183E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2199.9990000 g log = 3.3424 Original solution: 1000.0103000 g Original solution / Rock added: 0.45 (Water/Rock Ratio), log = -0.3424 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0919 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9639E+00 0.9850 0.1037E+01 0.1053E+01 CO2,gas 0.4828E-08 1.0071 0.5309E-08 0.5272E-08 CH4,gas 0.2241E-01 1.0128 0.2479E-01 0.2447E-01 H2,gas 0.1365E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1671E-06 0.9958 0.1817E-06 0.1825E-06 S2,gas 0.5095E-29 1.0000 0.5563E-29 0.5563E-29 CO,gas 0.1878E-13 1.0000 0.2050E-13 0.2050E-13 SO3,gas 0.1023E-47 1.0000 0.1117E-47 0.1117E-47 SO2,gas 0.5768E-27 1.0000 0.6298E-27 0.6298E-27 HCl,gas 0.3396E-17 1.0000 0.3709E-17 0.3709E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.97059E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.64 -10.27 -3.425 0.17544E+05 -8.275 3 CH4,gas 4.81 1.20 -3.61 -0.901 0.61568E+04 -1.606 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.68 -8.74 -4.370 0.14924E+05 -6.741 6 S2,gas -7.03 -38.29 -31.25 -4.808 0.53367E+05 -29.255 7 CO,gas 3.51 -12.18 -15.69 -4.827 0.26787E+05 -13.688 8 SO3,gas 17.43 -32.52 -49.95 -12.488 0.85292E+05 -47.952 9 SO2,gas 1.14 -28.06 -29.20 -7.787 0.49860E+05 -27.201 10 HCl,gas 5.48 -13.95 -19.43 -9.715 0.33178E+05 -17.431 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80665E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94126E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76236E+04 35 aragonite 0.99 -3.53 -4.52 -1.506 0.77141E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.53 -4.36 -1.455 0.74528E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70326E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70379E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65570E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.72 -4.61 -1.317 0.78716E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33652E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66055E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.72 -4.17 -1.191 0.71178E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38609E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82282E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61285E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53670E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92774E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40698E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43447E+04 143 pyrrhotite -4.24 -7.94 -3.70 -1.232 0.63123E+04 144 pyrrhotiteFe0.875 -6.00 -9.34 -3.34 -1.227 0.56951E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22449E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28300E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23241E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47170E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91029E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.94 -3.55 -1.182 0.60555E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80428E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66781E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60331E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.43 -4.47 -1.491 0.76355E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2199.9990000 g New total amount of reactant added: 2299.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2299.9990000 Water: Moles liquid = 0.4259E+02 kg liquid = 0.7673E+00 Moles total = 0.2668E+02 kg total = 0.4806E+00 Activity = 1.0000 Stoichiometric ionic strength = .1176351E-01 Osmotic coef. = 0.9686 True ionic strength = .2071150E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90375E-10 -10.0440 0.75816E-10 -10.1202 0.83890E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.17897E-03 -3.7472 0.14922E-03 -3.8262 0.83374E+00 -0.0790 4 SO4-- 0.10206E-11 -11.9911 0.52641E-12 -12.2787 0.51578E+00 -0.2875 5 HCO3- 0.36816E-06 -6.4340 0.30741E-06 -6.5123 0.83499E+00 -0.0783 6 HS- 0.33231E-04 -4.4785 0.27710E-04 -4.5574 0.83387E+00 -0.0789 7 Al+++ 0.11048E-28 -28.9567 0.25128E-29 -29.5998 0.22744E+00 -0.6431 8 H4SiO4 0.71164E-03 -3.1477 0.71164E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14351E-06 -6.8431 0.73463E-07 -7.1339 0.51190E+00 -0.2908 10 Mg++ 0.22788E-10 -10.6423 0.11611E-10 -10.9351 0.50951E+00 -0.2928 11 Fe++ 0.62334E-13 -13.2053 0.31795E-13 -13.4976 0.51008E+00 -0.2924 12 K+ 0.16163E-03 -3.7915 0.13499E-03 -3.8697 0.83519E+00 -0.0782 13 Na+ 0.20549E-01 -1.6872 0.17129E-01 -1.7663 0.83359E+00 -0.0790 14 Mn++ 0.19981E-10 -10.6994 0.10201E-10 -10.9914 0.51052E+00 -0.2920 15 HPO4-- 0.48691E-07 -7.3126 0.25117E-07 -7.6000 0.51585E+00 -0.2875 16 HSiO3- 0.10984E-01 -1.9592 0.91581E-02 -2.0382 0.83374E+00 -0.0790 17 Ca(HSiO3)+ 0.18044E-07 -7.7437 0.15074E-07 -7.8218 0.83537E+00 -0.0781 18 Mg(HSiO3)+ 0.35492E-11 -11.4499 0.29649E-11 -11.5280 0.83537E+00 -0.0781 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67557E-16 -16.1703 0.56435E-16 -16.2484 0.83537E+00 -0.0781 22 HAlO2,aq 0.14896E-09 -9.8269 0.14896E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52715E-05 -5.2781 0.43870E-05 -5.3578 0.83221E+00 -0.0798 24 CH4,aq 0.15936E-04 -4.7976 0.15879E-04 -4.7992 0.99641E+00 -0.0016 25 C2H6,aq 0.40144E-14 -14.3964 0.40000E-14 -14.3979 0.99641E+00 -0.0016 29 CO,aq 0.13156E-16 -16.8809 0.13156E-16 -16.8809 0.10000E+01 0.0000 30 CO2,aq 0.47160E-10 -10.3264 0.46991E-10 -10.3280 0.99641E+00 -0.0016 31 CO3-2 0.72844E-06 -6.1376 0.37490E-06 -6.4261 0.51466E+00 -0.2885 32 CaCO3,aq 0.33731E-09 -9.4720 0.33731E-09 -9.4720 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.68117E-12 -12.1667 0.56903E-12 -12.2449 0.83537E+00 -0.0781 34 CaCl+ 0.20910E-10 -10.6796 0.17468E-10 -10.7578 0.83537E+00 -0.0781 35 CaCl2,aq 0.60690E-15 -15.2169 0.60690E-15 -15.2169 0.10000E+01 0.0000 36 CaOH+ 0.81790E-07 -7.0873 0.68325E-07 -7.1654 0.83537E+00 -0.0781 37 CaSO4,aq 0.12049E-16 -16.9190 0.12049E-16 -16.9190 0.10000E+01 0.0000 38 HCl,aq 0.21280E-14 -14.6720 0.21280E-14 -14.6720 0.10000E+01 0.0000 43 FeCl+ 0.88458E-17 -17.0533 0.73895E-17 -17.1314 0.83537E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16643E-10 -10.7788 0.13903E-10 -10.8569 0.83537E+00 -0.0781 48 HFeO2- 0.37221E-07 -7.4292 0.31033E-07 -7.5082 0.83374E+00 -0.0790 49 FeO+ 0.12284E-16 -16.9107 0.10262E-16 -16.9888 0.83537E+00 -0.0781 51 FeO2- 0.42085E-09 -9.3759 0.35088E-09 -9.4548 0.83374E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99641E+00 -0.0016 54 KCl,aq 0.35666E-09 -9.4477 0.35666E-09 -9.4477 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.13131E-14 -14.8817 0.10948E-14 -14.9607 0.83374E+00 -0.0790 58 MgCO3,aq 0.13321E-13 -13.8754 0.13321E-13 -13.8754 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.10978E-15 -15.9595 0.91709E-16 -16.0376 0.83537E+00 -0.0781 60 MgCl+ 0.30002E-14 -14.5228 0.25063E-14 -14.6010 0.83537E+00 -0.0781 61 MgOH+ 0.71615E-10 -10.1450 0.59825E-10 -10.2231 0.83537E+00 -0.0781 63 MnO,aq 0.18734E-08 -8.7274 0.18734E-08 -8.7274 0.10000E+01 0.0000 64 MnOH+ 0.49603E-09 -9.3045 0.41437E-09 -9.3826 0.83537E+00 -0.0781 65 MnO2-2 0.21901E-10 -10.6595 0.11271E-10 -10.9480 0.51466E+00 -0.2885 66 HMnO2- 0.22207E-09 -9.6535 0.18515E-09 -9.7325 0.83374E+00 -0.0790 69 MnCl+ 0.11028E-13 -13.9575 0.92123E-14 -14.0356 0.83537E+00 -0.0781 71 NaCl,aq 0.83459E-06 -6.0785 0.83459E-06 -6.0785 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95069E-02 -2.0220 0.79117E-02 -2.1017 0.83221E+00 -0.0798 79 HPO3-2 0.16757E-14 -14.7758 0.86241E-15 -15.0643 0.51466E+00 -0.2885 81 H2PO3- 0.15405E-18 -18.8123 0.12844E-18 -18.8913 0.83374E+00 -0.0790 82 H3PO4,aq 0.92948E-18 -18.0318 0.92948E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40005E-10 -10.3979 0.33386E-10 -10.4764 0.83455E+00 -0.0785 84 PO4-3 0.12098E-08 -8.9173 0.28932E-09 -9.5386 0.23914E+00 -0.6213 88 HP2O7-3 0.10363E-17 -17.9845 0.23594E-18 -18.6272 0.22769E+00 -0.6427 89 P2O7-4 0.10231E-16 -16.9901 0.76774E-18 -18.1148 0.75042E-01 -1.1247 90 H2S,aq 0.63350E-08 -8.1983 0.63123E-08 -8.1998 0.99641E+00 -0.0016 91 S2-2 0.30187E-14 -14.5202 0.15536E-14 -14.8087 0.51466E+00 -0.2885 97 SO3-2 0.14940E-17 -17.8257 0.78025E-18 -18.1078 0.52226E+00 -0.2821 99 HSO4- 0.44285E-19 -19.3537 0.37031E-19 -19.4314 0.83620E+00 -0.0777 Charge balance for all species = 0.4299E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9037527E-10 -.2310740E-01 -.2324868E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981172E+06 0.0000 3 Cl- 0.1789740E-03 0.1798090E-03 0.6363219E+01 6.2941 4 SO4-- 0.1020627E-11 -.1866331E-04 -.1789580E+01 7.9618 5 HCO3- 0.3681612E-06 0.1703292E-04 0.1037418E+01 3.6080 6 HS- 0.3323128E-04 0.5190093E-04 0.1713358E+01 5.5629 7 Al+++ 0.1104796E-28 0.5271643E-05 0.1419791E+00 0.7609 8 H4SiO4 0.7116414E-03 0.1418738E-01 0.1361155E+04 -3.1477 9 Ca++ 0.1435094E-06 0.2437026E-06 0.9749417E-02 13.1066 10 Mg++ 0.2278784E-10 0.9796801E-10 0.2377483E-05 9.3053 11 Fe++ 0.6233352E-13 0.3788049E-07 0.2111679E-02 6.7428 12 K+ 0.1616275E-03 0.1624040E-03 0.6338818E+01 6.2505 13 Na+ 0.2054856E-01 0.2314013E-01 0.5310231E+03 8.3540 14 Mn++ 0.1998111E-10 0.2633365E-08 0.1444097E-03 9.2491 15 HPO4-- 0.4869108E-07 0.4994093E-07 0.4784596E-02 12.6405 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3808456E+02 -.1773117E-01 -.3806682E+02 0.0000000E+00 2 H2O 0.2667682E+02 0.4259062E+02 -.1591380E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6376632E-01 -.1432106E-04 0.6378064E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6374081E-01 0.3982553E-04 -.6378064E-01 0.0000000E+00 7 Al+++ 0.7499702E+01 0.4045129E-05 0.7499698E+01 0.0000000E+00 8 H4SiO4 0.2394939E+02 0.1088651E-01 0.2393850E+02 0.0000000E+00 9 Ca++ 0.2645341E+01 0.1870021E-06 0.2645341E+01 0.0000000E+00 10 Mg++ 0.1825396E+01 0.7517453E-10 0.1825396E+01 0.0000000E+00 11 Fe++ 0.1639919E+01 0.2906712E-07 0.1639919E+01 0.0000000E+00 12 K+ 0.4883225E+00 0.1246187E-03 0.4881979E+00 0.0000000E+00 13 Na+ 0.2887219E+01 0.1775629E-01 0.2869463E+01 0.0000000E+00 14 Mn++ 0.3987875E-01 0.2020680E-08 0.3987875E-01 0.0000000E+00 15 HPO4-- 0.1361042E-01 0.3832155E-07 0.1361038E-01 0.0000000E+00 Chg. balance for solid moles: 0.8465E-15 Mass of aqueous solution: 0.768730E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2299.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.867 0.457 751.9 2.876 29.92 288.6 andradite 0.2551 -0.593 129.6 2.113 5.160 33.68 grossular 0.6092E-01 -1.215 27.44 1.438 1.092 7.635 apatite-OH 0.4537E-02 -2.343 2.279 0.358 0.9070E-01 0.7242 clinochlore 0.3285 -0.484 182.6 2.261 7.266 69.44 daphnite 0.9413E-01 -1.026 67.17 1.827 2.673 20.35 chlorite-Mn 0.7976E-02 -2.098 5.655 0.752 0.2250 1.802 diopside 0.1235 -0.908 26.76 1.427 1.065 8.177 hedenbergite 0.3165E-01 -1.500 7.853 0.895 0.3125 2.151 microcline 0.4275 -0.369 119.0 2.076 4.736 46.48 stilbite 1.486 0.172 1048. 3.020 41.69 488.6 stilpnomelane-Fe 0.1214 -0.916 130.8 2.117 5.207 45.19 tr.625ac.25prg.125 0.1644E-01 -1.784 14.05 1.148 0.5592 4.522 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1852E-01 0.1852E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2512.662609 g Volume = 1017.388640 cm3 Porosity: -10.4657% V(tot) - V(min): -.96389E+02 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2299.9990000 g log = 3.3617 Original solution: 1000.0103000 g Original solution / Rock added: 0.43 (Water/Rock Ratio), log = -0.3617 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0922 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9637E+00 0.9850 0.1037E+01 0.1053E+01 CO2,gas 0.4890E-08 1.0071 0.5379E-08 0.5341E-08 CH4,gas 0.2270E-01 1.0128 0.2511E-01 0.2479E-01 H2,gas 0.1364E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1693E-06 0.9958 0.1841E-06 0.1849E-06 S2,gas 0.5228E-29 1.0000 0.5711E-29 0.5711E-29 CO,gas 0.1902E-13 1.0000 0.2077E-13 0.2077E-13 SO3,gas 0.1036E-47 1.0000 0.1131E-47 0.1131E-47 SO2,gas 0.5842E-27 1.0000 0.6381E-27 0.6381E-27 HCl,gas 0.3440E-17 1.0000 0.3757E-17 0.3757E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.97059E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.63 -10.27 -3.423 0.17535E+05 -8.269 3 CH4,gas 4.81 1.21 -3.60 -0.900 0.61472E+04 -1.600 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.68 -8.73 -4.367 0.14915E+05 -6.735 6 S2,gas -7.03 -38.28 -31.24 -4.807 0.53347E+05 -29.243 7 CO,gas 3.51 -12.17 -15.68 -4.825 0.26777E+05 -13.682 8 SO3,gas 17.43 -32.52 -49.95 -12.487 0.85282E+05 -47.946 9 SO2,gas 1.14 -28.06 -29.20 -7.785 0.49850E+05 -27.195 10 HCl,gas 5.48 -13.95 -19.43 -9.713 0.33168E+05 -17.425 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80661E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94126E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76236E+04 35 aragonite 0.99 -3.53 -4.51 -1.504 0.77044E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.53 -4.36 -1.453 0.74431E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71156E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70379E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65568E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.71 -4.60 -1.316 0.78620E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66056E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.71 -4.16 -1.189 0.71081E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82280E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61285E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53670E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92774E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40698E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43447E+04 143 pyrrhotite -4.24 -7.93 -3.69 -1.230 0.63026E+04 144 pyrrhotiteFe0.875 -6.00 -9.33 -3.33 -1.225 0.56854E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22447E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28300E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23240E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47168E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91029E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.93 -3.54 -1.180 0.60458E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80429E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66781E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60331E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.43 -4.47 -1.489 0.76257E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2299.9990000 g New total amount of reactant added: 2399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3299E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2399.9990000 Water: Moles liquid = 0.4204E+02 kg liquid = 0.7573E+00 Moles total = 0.2542E+02 kg total = 0.4580E+00 Activity = 1.0000 Stoichiometric ionic strength = .1176550E-01 Osmotic coef. = 0.9686 True ionic strength = .2071306E-01 Chg. balance for total moles = 0.3299E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90382E-10 -10.0439 0.75821E-10 -10.1202 0.83890E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18135E-03 -3.7415 0.15120E-03 -3.8205 0.83374E+00 -0.0790 4 SO4-- 0.10341E-11 -11.9854 0.53337E-12 -12.2730 0.51577E+00 -0.2875 5 HCO3- 0.37303E-06 -6.4283 0.31147E-06 -6.5066 0.83498E+00 -0.0783 6 HS- 0.33672E-04 -4.4727 0.28078E-04 -4.5516 0.83386E+00 -0.0789 7 Al+++ 0.11051E-28 -28.9566 0.25133E-29 -29.5998 0.22743E+00 -0.6431 8 H4SiO4 0.71164E-03 -3.1477 0.71164E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14353E-06 -6.8431 0.73473E-07 -7.1339 0.51189E+00 -0.2908 10 Mg++ 0.22791E-10 -10.6422 0.11612E-10 -10.9351 0.50950E+00 -0.2929 11 Fe++ 0.62343E-13 -13.2052 0.31800E-13 -13.4976 0.51007E+00 -0.2924 12 K+ 0.16164E-03 -3.7915 0.13500E-03 -3.8697 0.83518E+00 -0.0782 13 Na+ 0.20550E-01 -1.6872 0.17130E-01 -1.7662 0.83358E+00 -0.0791 14 Mn++ 0.19988E-10 -10.6992 0.10204E-10 -10.9912 0.51051E+00 -0.2920 15 HPO4-- 0.48685E-07 -7.3126 0.25114E-07 -7.6001 0.51584E+00 -0.2875 16 HSiO3- 0.10984E-01 -1.9593 0.91574E-02 -2.0382 0.83374E+00 -0.0790 17 Ca(HSiO3)+ 0.18046E-07 -7.7436 0.15075E-07 -7.8217 0.83537E+00 -0.0781 18 Mg(HSiO3)+ 0.35495E-11 -11.4498 0.29651E-11 -11.5280 0.83537E+00 -0.0781 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67562E-16 -16.1703 0.56439E-16 -16.2484 0.83537E+00 -0.0781 22 HAlO2,aq 0.14896E-09 -9.8269 0.14896E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52711E-05 -5.2781 0.43867E-05 -5.3579 0.83221E+00 -0.0798 24 CH4,aq 0.16147E-04 -4.7919 0.16090E-04 -4.7935 0.99641E+00 -0.0016 25 C2H6,aq 0.41217E-14 -14.3849 0.41069E-14 -14.3865 0.99641E+00 -0.0016 29 CO,aq 0.13331E-16 -16.8751 0.13331E-16 -16.8751 0.10000E+01 0.0000 30 CO2,aq 0.47786E-10 -10.3207 0.47615E-10 -10.3223 0.99641E+00 -0.0016 31 CO3-2 0.73803E-06 -6.1319 0.37983E-06 -6.4204 0.51465E+00 -0.2885 32 CaCO3,aq 0.34179E-09 -9.4662 0.34179E-09 -9.4662 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.69028E-12 -12.1610 0.57663E-12 -12.2391 0.83537E+00 -0.0781 34 CaCl+ 0.21191E-10 -10.6739 0.17702E-10 -10.7520 0.83537E+00 -0.0781 35 CaCl2,aq 0.62319E-15 -15.2054 0.62319E-15 -15.2054 0.10000E+01 0.0000 36 CaOH+ 0.81796E-07 -7.0873 0.68329E-07 -7.1654 0.83537E+00 -0.0781 37 CaSO4,aq 0.12210E-16 -16.9133 0.12210E-16 -16.9133 0.10000E+01 0.0000 38 HCl,aq 0.21563E-14 -14.6663 0.21563E-14 -14.6663 0.10000E+01 0.0000 43 FeCl+ 0.89644E-17 -17.0475 0.74886E-17 -17.1256 0.83537E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16645E-10 -10.7787 0.13904E-10 -10.8569 0.83537E+00 -0.0781 48 HFeO2- 0.37218E-07 -7.4292 0.31030E-07 -7.5082 0.83374E+00 -0.0790 49 FeO+ 0.12285E-16 -16.9106 0.10263E-16 -16.9887 0.83537E+00 -0.0781 51 FeO2- 0.42082E-09 -9.3759 0.35086E-09 -9.4549 0.83374E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10871E-04 -4.9637 0.99641E+00 -0.0016 54 KCl,aq 0.36141E-09 -9.4420 0.36141E-09 -9.4420 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.13305E-14 -14.8760 0.11093E-14 -14.9549 0.83374E+00 -0.0790 58 MgCO3,aq 0.13498E-13 -13.8697 0.13498E-13 -13.8697 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11125E-15 -15.9537 0.92934E-16 -16.0318 0.83537E+00 -0.0781 60 MgCl+ 0.30404E-14 -14.5171 0.25399E-14 -14.5952 0.83537E+00 -0.0781 61 MgOH+ 0.71620E-10 -10.1450 0.59829E-10 -10.2231 0.83537E+00 -0.0781 63 MnO,aq 0.18737E-08 -8.7273 0.18737E-08 -8.7273 0.10000E+01 0.0000 64 MnOH+ 0.49615E-09 -9.3044 0.41447E-09 -9.3825 0.83537E+00 -0.0781 65 MnO2-2 0.21902E-10 -10.6595 0.11272E-10 -10.9480 0.51465E+00 -0.2885 66 HMnO2- 0.22209E-09 -9.6535 0.18517E-09 -9.7324 0.83374E+00 -0.0790 69 MnCl+ 0.11178E-13 -13.9517 0.93373E-14 -14.0298 0.83537E+00 -0.0781 71 NaCl,aq 0.84571E-06 -6.0728 0.84571E-06 -6.0728 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95063E-02 -2.0220 0.79112E-02 -2.1018 0.83221E+00 -0.0798 79 HPO3-2 0.16755E-14 -14.7759 0.86229E-15 -15.0643 0.51465E+00 -0.2885 81 H2PO3- 0.15404E-18 -18.8124 0.12843E-18 -18.8913 0.83374E+00 -0.0790 82 H3PO4,aq 0.92948E-18 -18.0318 0.92948E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40003E-10 -10.3979 0.33384E-10 -10.4765 0.83454E+00 -0.0786 84 PO4-3 0.12096E-08 -8.9173 0.28926E-09 -9.5387 0.23913E+00 -0.6214 88 HP2O7-3 0.10361E-17 -17.9846 0.23590E-18 -18.6273 0.22767E+00 -0.6427 89 P2O7-4 0.10229E-16 -16.9902 0.76753E-18 -18.1149 0.75037E-01 -1.1247 90 H2S,aq 0.64194E-08 -8.1925 0.63964E-08 -8.1941 0.99641E+00 -0.0016 91 S2-2 0.30993E-14 -14.5087 0.15951E-14 -14.7972 0.51465E+00 -0.2885 97 SO3-2 0.15137E-17 -17.8199 0.79056E-18 -18.1021 0.52225E+00 -0.2821 99 HSO4- 0.44874E-19 -19.3480 0.37523E-19 -19.4257 0.83620E+00 -0.0777 Charge balance for all species = 0.4356E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9038198E-10 -.2310611E-01 -.2324738E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981172E+06 0.0000 3 Cl- 0.1813483E-03 0.1821944E-03 0.6447637E+01 6.2998 4 SO4-- 0.1034130E-11 -.1887480E-04 -.1809859E+01 7.9674 5 HCO3- 0.3730302E-06 0.1725889E-04 0.1051181E+01 3.6136 6 HS- 0.3367215E-04 0.5255337E-04 0.1734896E+01 5.5686 7 Al+++ 0.1105069E-28 0.5271272E-05 0.1419691E+00 0.7609 8 H4SiO4 0.7116429E-03 0.1418670E-01 0.1361090E+04 -3.1477 9 Ca++ 0.1435320E-06 0.2437371E-06 0.9750799E-02 13.1065 10 Mg++ 0.2279142E-10 0.9797760E-10 0.2377716E-05 9.3053 11 Fe++ 0.6234340E-13 0.3787804E-07 0.2111542E-02 6.7428 12 K+ 0.1616395E-03 0.1624161E-03 0.6339287E+01 6.2505 13 Na+ 0.2055010E-01 0.2314167E-01 0.5310586E+03 8.3540 14 Mn++ 0.1998766E-10 0.2633832E-08 0.1444353E-03 9.2492 15 HPO4-- 0.4868545E-07 0.4993509E-07 0.4784037E-02 12.6403 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.3974041E+02 -.1749805E-01 -.3972291E+02 0.0000000E+00 2 H2O 0.2542328E+02 0.4203299E+02 -.1660971E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6653766E-01 -.1429372E-04 0.6655195E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6651215E-01 0.3979819E-04 -.6655195E-01 0.0000000E+00 7 Al+++ 0.7825777E+01 0.3991886E-05 0.7825773E+01 0.0000000E+00 8 H4SiO4 0.2499067E+02 0.1074346E-01 0.2497993E+02 0.0000000E+00 9 Ca++ 0.2760356E+01 0.1845799E-06 0.2760356E+01 0.0000000E+00 10 Mg++ 0.1904761E+01 0.7419754E-10 0.1904761E+01 0.0000000E+00 11 Fe++ 0.1711220E+01 0.2868469E-07 0.1711220E+01 0.0000000E+00 12 K+ 0.5095539E+00 0.1229962E-03 0.5094309E+00 0.0000000E+00 13 Na+ 0.3012744E+01 0.1752498E-01 0.2995219E+01 0.0000000E+00 14 Mn++ 0.4161261E-01 0.1994577E-08 0.4161261E-01 0.0000000E+00 15 HPO4-- 0.1420218E-01 0.3781539E-07 0.1420214E-01 0.0000000E+00 Chg. balance for solid moles: -.1200E-14 Mass of aqueous solution: 0.758665E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 2.993 0.476 784.8 2.895 29.93 301.3 andradite 0.2662 -0.575 135.3 2.131 5.160 35.15 grossular 0.6356E-01 -1.197 28.63 1.457 1.092 7.967 apatite-OH 0.4734E-02 -2.325 2.378 0.376 0.9070E-01 0.7556 clinochlore 0.3427 -0.465 190.5 2.280 7.264 72.45 daphnite 0.9821E-01 -1.008 70.07 1.846 2.673 21.23 chlorite-Mn 0.8323E-02 -2.080 5.900 0.771 0.2250 1.880 diopside 0.1293 -0.888 28.01 1.447 1.068 8.560 hedenbergite 0.3313E-01 -1.480 8.220 0.915 0.3135 2.252 microcline 0.4461 -0.351 124.2 2.094 4.736 48.50 stilbite 1.551 0.191 1093. 3.039 41.68 509.7 stilpnomelane-Fe 0.1266 -0.897 136.5 2.135 5.207 47.16 tr.625ac.25prg.125 0.1712E-01 -1.767 14.63 1.165 0.5581 4.710 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1853E-01 0.1853E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2621.918091 g Volume = 1061.594997 cm3 Porosity: -10.4678% V(tot) - V(min): -.10060E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2399.9990000 g log = 3.3802 Original solution: 1000.0103000 g Original solution / Rock added: 0.42 (Water/Rock Ratio), log = -0.3802 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0925 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9634E+00 0.9850 0.1037E+01 0.1053E+01 CO2,gas 0.4954E-08 1.0071 0.5450E-08 0.5412E-08 CH4,gas 0.2299E-01 1.0128 0.2544E-01 0.2512E-01 H2,gas 0.1364E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1715E-06 0.9958 0.1866E-06 0.1874E-06 S2,gas 0.5367E-29 1.0000 0.5864E-29 0.5864E-29 CO,gas 0.1927E-13 1.0000 0.2105E-13 0.2105E-13 SO3,gas 0.1049E-47 1.0000 0.1146E-47 0.1146E-47 SO2,gas 0.5918E-27 1.0000 0.6466E-27 0.6466E-27 HCl,gas 0.3485E-17 1.0000 0.3807E-17 0.3807E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.18198E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 -0.18198E-10 68 hedenbergite 14.24 14.24 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.63 -10.26 -3.421 0.17525E+05 -8.264 3 CH4,gas 4.81 1.21 -3.59 -0.899 0.61374E+04 -1.594 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.67 -8.73 -4.365 0.14905E+05 -6.729 6 S2,gas -7.03 -38.26 -31.23 -4.805 0.53327E+05 -29.232 7 CO,gas 3.51 -12.17 -15.68 -4.824 0.26768E+05 -13.677 8 SO3,gas 17.43 -32.51 -49.94 -12.485 0.85272E+05 -47.941 9 SO2,gas 1.14 -28.05 -29.19 -7.784 0.49840E+05 -27.189 10 HCl,gas 5.48 -13.94 -19.42 -9.710 0.33158E+05 -17.419 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80658E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94126E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28384E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76236E+04 35 aragonite 0.99 -3.52 -4.51 -1.502 0.76947E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.52 -4.35 -1.451 0.74333E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70379E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65567E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.71 -4.60 -1.314 0.78522E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66056E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.71 -4.16 -1.188 0.70984E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64142E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82279E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61285E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53670E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92774E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40698E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43447E+04 143 pyrrhotite -4.24 -7.93 -3.69 -1.228 0.62928E+04 144 pyrrhotiteFe0.875 -6.00 -9.32 -3.32 -1.222 0.56755E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22446E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28299E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23239E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47165E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91029E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.93 -3.54 -1.178 0.60360E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80429E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66781E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60331E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.42 -4.46 -1.487 0.76158E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62642E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2399.9990000 g New total amount of reactant added: 2499.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3299E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2499.9990000 Water: Moles liquid = 0.4148E+02 kg liquid = 0.7472E+00 Moles total = 0.2417E+02 kg total = 0.4354E+00 Activity = 1.0000 Stoichiometric ionic strength = .1176754E-01 Osmotic coef. = 0.9686 True ionic strength = .2071465E-01 Chg. balance for total moles = 0.3299E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90389E-10 -10.0439 0.75826E-10 -10.1202 0.83889E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18379E-03 -3.7357 0.15323E-03 -3.8147 0.83374E+00 -0.0790 4 SO4-- 0.10480E-11 -11.9796 0.54051E-12 -12.2672 0.51576E+00 -0.2876 5 HCO3- 0.37803E-06 -6.4225 0.31565E-06 -6.5008 0.83498E+00 -0.0783 6 HS- 0.34125E-04 -4.4669 0.28455E-04 -4.5458 0.83386E+00 -0.0789 7 Al+++ 0.11054E-28 -28.9565 0.25138E-29 -29.5997 0.22742E+00 -0.6432 8 H4SiO4 0.71164E-03 -3.1477 0.71164E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14356E-06 -6.8430 0.73484E-07 -7.1338 0.51188E+00 -0.2908 10 Mg++ 0.22795E-10 -10.6422 0.11614E-10 -10.9350 0.50949E+00 -0.2929 11 Fe++ 0.62354E-13 -13.2051 0.31804E-13 -13.4975 0.51006E+00 -0.2924 12 K+ 0.16165E-03 -3.7914 0.13501E-03 -3.8696 0.83518E+00 -0.0782 13 Na+ 0.20552E-01 -1.6872 0.17131E-01 -1.7662 0.83358E+00 -0.0791 14 Mn++ 0.19994E-10 -10.6991 0.10207E-10 -10.9911 0.51049E+00 -0.2920 15 HPO4-- 0.48680E-07 -7.3127 0.25110E-07 -7.6001 0.51583E+00 -0.2875 16 HSiO3- 0.10983E-01 -1.9593 0.91568E-02 -2.0383 0.83374E+00 -0.0790 17 Ca(HSiO3)+ 0.18047E-07 -7.7436 0.15076E-07 -7.8217 0.83536E+00 -0.0781 18 Mg(HSiO3)+ 0.35498E-11 -11.4498 0.29653E-11 -11.5279 0.83536E+00 -0.0781 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67567E-16 -16.1703 0.56443E-16 -16.2484 0.83536E+00 -0.0781 22 HAlO2,aq 0.14896E-09 -9.8269 0.14896E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52707E-05 -5.2781 0.43863E-05 -5.3579 0.83220E+00 -0.0798 24 CH4,aq 0.16365E-04 -4.7861 0.16306E-04 -4.7877 0.99641E+00 -0.0016 25 C2H6,aq 0.42333E-14 -14.3733 0.42181E-14 -14.3749 0.99641E+00 -0.0016 29 CO,aq 0.13511E-16 -16.8693 0.13511E-16 -16.8693 0.10000E+01 0.0000 30 CO2,aq 0.48430E-10 -10.3149 0.48256E-10 -10.3164 0.99641E+00 -0.0016 31 CO3-2 0.74788E-06 -6.1262 0.38489E-06 -6.4147 0.51464E+00 -0.2885 32 CaCO3,aq 0.34640E-09 -9.4604 0.34640E-09 -9.4604 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.69963E-12 -12.1551 0.58444E-12 -12.2333 0.83536E+00 -0.0781 34 CaCl+ 0.21479E-10 -10.6680 0.17942E-10 -10.7461 0.83536E+00 -0.0781 35 CaCl2,aq 0.64014E-15 -15.1937 0.64014E-15 -15.1937 0.10000E+01 0.0000 36 CaOH+ 0.81802E-07 -7.0872 0.68334E-07 -7.1654 0.83536E+00 -0.0781 37 CaSO4,aq 0.12375E-16 -16.9074 0.12375E-16 -16.9074 0.10000E+01 0.0000 38 HCl,aq 0.21855E-14 -14.6605 0.21855E-14 -14.6605 0.10000E+01 0.0000 43 FeCl+ 0.90862E-17 -17.0416 0.75903E-17 -17.1197 0.83536E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16646E-10 -10.7787 0.13905E-10 -10.8568 0.83536E+00 -0.0781 48 HFeO2- 0.37216E-07 -7.4293 0.31028E-07 -7.5082 0.83374E+00 -0.0790 49 FeO+ 0.12286E-16 -16.9106 0.10263E-16 -16.9887 0.83536E+00 -0.0781 51 FeO2- 0.42080E-09 -9.3759 0.35083E-09 -9.4549 0.83374E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10870E-04 -4.9638 0.99641E+00 -0.0016 54 KCl,aq 0.36630E-09 -9.4362 0.36630E-09 -9.4362 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.13485E-14 -14.8702 0.11243E-14 -14.9491 0.83374E+00 -0.0790 58 MgCO3,aq 0.13680E-13 -13.8639 0.13680E-13 -13.8639 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11276E-15 -15.9479 0.94192E-16 -16.0260 0.83536E+00 -0.0781 60 MgCl+ 0.30817E-14 -14.5112 0.25744E-14 -14.5893 0.83536E+00 -0.0781 61 MgOH+ 0.71625E-10 -10.1449 0.59833E-10 -10.2231 0.83536E+00 -0.0781 63 MnO,aq 0.18740E-08 -8.7272 0.18740E-08 -8.7272 0.10000E+01 0.0000 64 MnOH+ 0.49626E-09 -9.3043 0.41456E-09 -9.3824 0.83536E+00 -0.0781 65 MnO2-2 0.21902E-10 -10.6595 0.11272E-10 -10.9480 0.51464E+00 -0.2885 66 HMnO2- 0.22211E-09 -9.6534 0.18518E-09 -9.7324 0.83374E+00 -0.0790 69 MnCl+ 0.11331E-13 -13.9457 0.94656E-14 -14.0239 0.83536E+00 -0.0781 71 NaCl,aq 0.85714E-06 -6.0669 0.85714E-06 -6.0669 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95056E-02 -2.0220 0.79106E-02 -2.1018 0.83220E+00 -0.0798 79 HPO3-2 0.16753E-14 -14.7759 0.86217E-15 -15.0644 0.51464E+00 -0.2885 81 H2PO3- 0.15403E-18 -18.8124 0.12842E-18 -18.8914 0.83374E+00 -0.0790 82 H3PO4,aq 0.92949E-18 -18.0318 0.92949E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.40000E-10 -10.3979 0.33382E-10 -10.4765 0.83454E+00 -0.0786 84 PO4-3 0.12094E-08 -8.9174 0.28920E-09 -9.5388 0.23912E+00 -0.6214 88 HP2O7-3 0.10359E-17 -17.9847 0.23585E-18 -18.6274 0.22766E+00 -0.6427 89 P2O7-4 0.10227E-16 -16.9903 0.76732E-18 -18.1150 0.75031E-01 -1.1248 90 H2S,aq 0.65062E-08 -8.1867 0.64828E-08 -8.1882 0.99641E+00 -0.0016 91 S2-2 0.31833E-14 -14.4971 0.16382E-14 -14.7856 0.51464E+00 -0.2885 97 SO3-2 0.15340E-17 -17.8142 0.80113E-18 -18.0963 0.52224E+00 -0.2821 99 HSO4- 0.45478E-19 -19.3422 0.38028E-19 -19.4199 0.83619E+00 -0.0777 Charge balance for all species = 0.4417E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9038885E-10 -.2310480E-01 -.2324605E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981171E+06 0.0000 3 Cl- 0.1837865E-03 0.1846441E-03 0.6534325E+01 6.3055 4 SO4-- 0.1047993E-11 -.1909199E-04 -.1830684E+01 7.9732 5 HCO3- 0.3780290E-06 0.1749094E-04 0.1065314E+01 3.6194 6 HS- 0.3412487E-04 0.5322336E-04 0.1757014E+01 5.5743 7 Al+++ 0.1105351E-28 0.5270895E-05 0.1419590E+00 0.7609 8 H4SiO4 0.7116442E-03 0.1418600E-01 0.1361023E+04 -3.1477 9 Ca++ 0.1435551E-06 0.2437727E-06 0.9752219E-02 13.1065 10 Mg++ 0.2279510E-10 0.9798655E-10 0.2377933E-05 9.3053 11 Fe++ 0.6235354E-13 0.3787553E-07 0.2111402E-02 6.7428 12 K+ 0.1616518E-03 0.1624284E-03 0.6339768E+01 6.2505 13 Na+ 0.2055167E-01 0.2314326E-01 0.5310949E+03 8.3540 14 Mn++ 0.1999402E-10 0.2634264E-08 0.1444590E-03 9.2492 15 HPO4-- 0.4867965E-07 0.4992909E-07 0.4783462E-02 12.6402 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4139626E+02 -.1726492E-01 -.4137899E+02 0.0000000E+00 2 H2O 0.2416974E+02 0.4147535E+02 -.1730561E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.6930900E-01 -.1426637E-04 0.6932327E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.6928349E-01 0.3977084E-04 -.6932327E-01 0.0000000E+00 7 Al+++ 0.8151851E+01 0.3938645E-05 0.8151847E+01 0.0000000E+00 8 H4SiO4 0.2603195E+02 0.1060041E-01 0.2602135E+02 0.0000000E+00 9 Ca++ 0.2875370E+01 0.1821577E-06 0.2875370E+01 0.0000000E+00 10 Mg++ 0.1984126E+01 0.7321987E-10 0.1984126E+01 0.0000000E+00 11 Fe++ 0.1782521E+01 0.2830226E-07 0.1782521E+01 0.0000000E+00 12 K+ 0.5307854E+00 0.1213737E-03 0.5306640E+00 0.0000000E+00 13 Na+ 0.3138268E+01 0.1729366E-01 0.3120974E+01 0.0000000E+00 14 Mn++ 0.4334647E-01 0.1968438E-08 0.4334647E-01 0.0000000E+00 15 HPO4-- 0.1479394E-01 0.3730922E-07 0.1479390E-01 0.0000000E+00 Chg. balance for solid moles: -.2671E-14 Mass of aqueous solution: 0.748600E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2499.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.119 0.494 817.8 2.913 29.94 313.9 andradite 0.2773 -0.557 140.9 2.149 5.159 36.61 grossular 0.6621E-01 -1.179 29.82 1.475 1.092 8.298 apatite-OH 0.4931E-02 -2.307 2.477 0.394 0.9070E-01 0.7871 clinochlore 0.3569 -0.447 198.4 2.297 7.263 75.46 daphnite 0.1023 -0.990 72.98 1.863 2.672 22.12 chlorite-Mn 0.8669E-02 -2.062 6.146 0.789 0.2250 1.959 diopside 0.1351 -0.869 29.26 1.466 1.071 8.943 hedenbergite 0.3461E-01 -1.461 8.588 0.934 0.3144 2.352 microcline 0.4647 -0.333 129.3 2.112 4.736 50.53 stilbite 1.615 0.208 1138. 3.056 41.67 530.8 stilpnomelane-Fe 0.1319 -0.880 142.2 2.153 5.207 49.13 tr.625ac.25prg.125 0.1780E-01 -1.750 15.21 1.182 0.5571 4.897 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1853E-01 0.1853E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2731.173572 g Volume = 1105.801354 cm3 Porosity: -10.4697% V(tot) - V(min): -.10480E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2499.9990000 g log = 3.3979 Original solution: 1000.0103000 g Original solution / Rock added: 0.40 (Water/Rock Ratio), log = -0.3979 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0929 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9631E+00 0.9850 0.1037E+01 0.1053E+01 CO2,gas 0.5019E-08 1.0071 0.5524E-08 0.5485E-08 CH4,gas 0.2330E-01 1.0128 0.2579E-01 0.2546E-01 H2,gas 0.1363E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1737E-06 0.9958 0.1891E-06 0.1899E-06 S2,gas 0.5512E-29 1.0000 0.6023E-29 0.6023E-29 CO,gas 0.1952E-13 1.0000 0.2133E-13 0.2133E-13 SO3,gas 0.1063E-47 1.0000 0.1162E-47 0.1162E-47 SO2,gas 0.5996E-27 1.0000 0.6553E-27 0.6553E-27 HCl,gas 0.3531E-17 1.0000 0.3859E-17 0.3859E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.66728E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.62 -10.26 -3.419 0.17515E+05 -8.258 3 CH4,gas 4.81 1.22 -3.59 -0.897 0.61275E+04 -1.589 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.67 -8.72 -4.362 0.14895E+05 -6.723 6 S2,gas -7.03 -38.25 -31.22 -4.803 0.53308E+05 -29.220 7 CO,gas 3.51 -12.16 -15.67 -4.822 0.26758E+05 -13.671 8 SO3,gas 17.43 -32.51 -49.93 -12.484 0.85262E+05 -47.935 9 SO2,gas 1.14 -28.05 -29.18 -7.782 0.49830E+05 -27.184 10 HCl,gas 5.48 -13.93 -19.41 -9.707 0.33148E+05 -17.414 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80654E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94126E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76236E+04 35 aragonite 0.99 -3.51 -4.50 -1.500 0.76847E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.51 -4.35 -1.449 0.74234E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70379E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65566E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.70 -4.59 -1.312 0.78423E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66056E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.70 -4.15 -1.186 0.70884E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82278E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61285E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53670E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20057E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92774E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40699E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43447E+04 143 pyrrhotite -4.24 -7.92 -3.68 -1.227 0.62828E+04 144 pyrrhotiteFe0.875 -6.00 -9.32 -3.32 -1.220 0.56656E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22445E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28299E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23237E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47163E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91029E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.92 -3.53 -1.176 0.60260E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80430E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66781E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60331E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.42 -4.45 -1.485 0.76057E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2499.9990000 g New total amount of reactant added: 2599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2599.9990000 Water: Moles liquid = 0.4092E+02 kg liquid = 0.7372E+00 Moles total = 0.2292E+02 kg total = 0.4128E+00 Activity = 1.0000 Stoichiometric ionic strength = .1176963E-01 Osmotic coef. = 0.9685 True ionic strength = .2071628E-01 Chg. balance for total moles = 0.3298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90396E-10 -10.0439 0.75832E-10 -10.1201 0.83889E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18629E-03 -3.7298 0.15532E-03 -3.8088 0.83373E+00 -0.0790 4 SO4-- 0.10622E-11 -11.9738 0.54784E-12 -12.2613 0.51574E+00 -0.2876 5 HCO3- 0.38316E-06 -6.4166 0.31993E-06 -6.4949 0.83497E+00 -0.0783 6 HS- 0.34590E-04 -4.4611 0.28843E-04 -4.5400 0.83385E+00 -0.0789 7 Al+++ 0.11056E-28 -28.9564 0.25144E-29 -29.5996 0.22741E+00 -0.6432 8 H4SiO4 0.71165E-03 -3.1477 0.71165E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14358E-06 -6.8429 0.73494E-07 -7.1337 0.51187E+00 -0.2908 10 Mg++ 0.22799E-10 -10.6421 0.11616E-10 -10.9350 0.50948E+00 -0.2929 11 Fe++ 0.62364E-13 -13.2051 0.31809E-13 -13.4975 0.51005E+00 -0.2924 12 K+ 0.16166E-03 -3.7914 0.13502E-03 -3.8696 0.83517E+00 -0.0782 13 Na+ 0.20553E-01 -1.6871 0.17133E-01 -1.7662 0.83357E+00 -0.0791 14 Mn++ 0.20000E-10 -10.6990 0.10210E-10 -10.9910 0.51048E+00 -0.2920 15 HPO4-- 0.48674E-07 -7.3127 0.25107E-07 -7.6002 0.51582E+00 -0.2875 16 HSiO3- 0.10982E-01 -1.9593 0.91562E-02 -2.0383 0.83373E+00 -0.0790 17 Ca(HSiO3)+ 0.18049E-07 -7.7436 0.15077E-07 -7.8217 0.83536E+00 -0.0781 18 Mg(HSiO3)+ 0.35500E-11 -11.4498 0.29656E-11 -11.5279 0.83536E+00 -0.0781 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67572E-16 -16.1702 0.56447E-16 -16.2484 0.83536E+00 -0.0781 22 HAlO2,aq 0.14895E-09 -9.8269 0.14895E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52704E-05 -5.2782 0.43860E-05 -5.3579 0.83220E+00 -0.0798 24 CH4,aq 0.16588E-04 -4.7802 0.16528E-04 -4.7818 0.99641E+00 -0.0016 25 C2H6,aq 0.43496E-14 -14.3616 0.43340E-14 -14.3631 0.99641E+00 -0.0016 29 CO,aq 0.13695E-16 -16.8634 0.13695E-16 -16.8634 0.10000E+01 0.0000 30 CO2,aq 0.49091E-10 -10.3090 0.48915E-10 -10.3106 0.99641E+00 -0.0016 31 CO3-2 0.75799E-06 -6.1203 0.39008E-06 -6.4088 0.51463E+00 -0.2885 32 CaCO3,aq 0.35112E-09 -9.4545 0.35112E-09 -9.4545 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.70923E-12 -12.1492 0.59246E-12 -12.2273 0.83536E+00 -0.0781 34 CaCl+ 0.21774E-10 -10.6621 0.18189E-10 -10.7402 0.83536E+00 -0.0781 35 CaCl2,aq 0.65779E-15 -15.1819 0.65779E-15 -15.1819 0.10000E+01 0.0000 36 CaOH+ 0.81808E-07 -7.0872 0.68339E-07 -7.1653 0.83536E+00 -0.0781 37 CaSO4,aq 0.12545E-16 -16.9015 0.12545E-16 -16.9015 0.10000E+01 0.0000 38 HCl,aq 0.22154E-14 -14.6545 0.22154E-14 -14.6545 0.10000E+01 0.0000 43 FeCl+ 0.92114E-17 -17.0357 0.76948E-17 -17.1138 0.83536E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16647E-10 -10.7787 0.13906E-10 -10.8568 0.83536E+00 -0.0781 48 HFeO2- 0.37213E-07 -7.4293 0.31026E-07 -7.5083 0.83373E+00 -0.0790 49 FeO+ 0.12287E-16 -16.9106 0.10264E-16 -16.9887 0.83536E+00 -0.0781 51 FeO2- 0.42077E-09 -9.3760 0.35081E-09 -9.4549 0.83373E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10870E-04 -4.9638 0.99641E+00 -0.0016 54 KCl,aq 0.37131E-09 -9.4303 0.37131E-09 -9.4303 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.13669E-14 -14.8643 0.11396E-14 -14.9433 0.83373E+00 -0.0790 58 MgCO3,aq 0.13867E-13 -13.8580 0.13867E-13 -13.8580 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11430E-15 -15.9419 0.95485E-16 -16.0201 0.83536E+00 -0.0781 60 MgCl+ 0.31242E-14 -14.5053 0.26098E-14 -14.5834 0.83536E+00 -0.0781 61 MgOH+ 0.71631E-10 -10.1449 0.59837E-10 -10.2230 0.83536E+00 -0.0781 63 MnO,aq 0.18743E-08 -8.7272 0.18743E-08 -8.7272 0.10000E+01 0.0000 64 MnOH+ 0.49637E-09 -9.3042 0.41465E-09 -9.3823 0.83536E+00 -0.0781 65 MnO2-2 0.21903E-10 -10.6595 0.11272E-10 -10.9480 0.51463E+00 -0.2885 66 HMnO2- 0.22213E-09 -9.6534 0.18519E-09 -9.7324 0.83373E+00 -0.0790 69 MnCl+ 0.11489E-13 -13.9397 0.95974E-14 -14.0178 0.83536E+00 -0.0781 71 NaCl,aq 0.86888E-06 -6.0610 0.86888E-06 -6.0610 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95050E-02 -2.0220 0.79101E-02 -2.1018 0.83220E+00 -0.0798 79 HPO3-2 0.16751E-14 -14.7760 0.86204E-15 -15.0645 0.51463E+00 -0.2885 81 H2PO3- 0.15402E-18 -18.8124 0.12841E-18 -18.8914 0.83373E+00 -0.0790 82 H3PO4,aq 0.92949E-18 -18.0318 0.92949E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.39997E-10 -10.3980 0.33379E-10 -10.4765 0.83454E+00 -0.0786 84 PO4-3 0.12092E-08 -8.9175 0.28914E-09 -9.5389 0.23911E+00 -0.6214 88 HP2O7-3 0.10358E-17 -17.9847 0.23580E-18 -18.6275 0.22765E+00 -0.6427 89 P2O7-4 0.10225E-16 -16.9904 0.76710E-18 -18.1152 0.75024E-01 -1.1248 90 H2S,aq 0.65953E-08 -8.1808 0.65716E-08 -8.1823 0.99641E+00 -0.0016 91 S2-2 0.32707E-14 -14.4854 0.16832E-14 -14.7739 0.51463E+00 -0.2885 97 SO3-2 0.15549E-17 -17.8083 0.81200E-18 -18.0904 0.52223E+00 -0.2821 99 HSO4- 0.46098E-19 -19.3363 0.38547E-19 -19.4140 0.83619E+00 -0.0777 Charge balance for all species = 0.4475E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9039591E-10 -.2310344E-01 -.2324469E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981170E+06 0.0000 3 Cl- 0.1862912E-03 0.1871604E-03 0.6623376E+01 6.3114 4 SO4-- 0.1062231E-11 -.1931510E-04 -.1852077E+01 7.9789 5 HCO3- 0.3831629E-06 0.1772931E-04 0.1079833E+01 3.6252 6 HS- 0.3458993E-04 0.5391162E-04 0.1779735E+01 5.5802 7 Al+++ 0.1105640E-28 0.5270511E-05 0.1419486E+00 0.7609 8 H4SiO4 0.7116454E-03 0.1418528E-01 0.1360954E+04 -3.1477 9 Ca++ 0.1435789E-06 0.2438092E-06 0.9753679E-02 13.1065 10 Mg++ 0.2279888E-10 0.9799695E-10 0.2378185E-05 9.3053 11 Fe++ 0.6236396E-13 0.3787295E-07 0.2111258E-02 6.7428 12 K+ 0.1616645E-03 0.1624411E-03 0.6340262E+01 6.2505 13 Na+ 0.2055328E-01 0.2314489E-01 0.5311323E+03 8.3540 14 Mn++ 0.2000023E-10 0.2634665E-08 0.1444810E-03 9.2493 15 HPO4-- 0.4867368E-07 0.4992291E-07 0.4782869E-02 12.6401 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4305211E+02 -.1703179E-01 -.4303508E+02 0.0000000E+00 2 H2O 0.2291620E+02 0.4091771E+02 -.1800152E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7208034E-01 -.1423904E-04 0.7209458E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7205484E-01 0.3974351E-04 -.7209458E-01 0.0000000E+00 7 Al+++ 0.8477925E+01 0.3885407E-05 0.8477921E+01 0.0000000E+00 8 H4SiO4 0.2707323E+02 0.1045735E-01 0.2706277E+02 0.0000000E+00 9 Ca++ 0.2990384E+01 0.1797355E-06 0.2990384E+01 0.0000000E+00 10 Mg++ 0.2063491E+01 0.7224310E-10 0.2063491E+01 0.0000000E+00 11 Fe++ 0.1853822E+01 0.2791984E-07 0.1853822E+01 0.0000000E+00 12 K+ 0.5520168E+00 0.1197511E-03 0.5518970E+00 0.0000000E+00 13 Na+ 0.3263792E+01 0.1706235E-01 0.3246730E+01 0.0000000E+00 14 Mn++ 0.4508033E-01 0.1942268E-08 0.4508033E-01 0.0000000E+00 15 HPO4-- 0.1538569E-01 0.3680304E-07 0.1538566E-01 0.0000000E+00 Chg. balance for solid moles: 0.8431E-15 Mass of aqueous solution: 0.738536E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.244 0.511 850.8 2.930 29.95 326.6 andradite 0.2884 -0.540 146.5 2.166 5.159 38.07 grossular 0.6886E-01 -1.162 31.02 1.492 1.092 8.630 apatite-OH 0.5129E-02 -2.290 2.576 0.411 0.9070E-01 0.8186 clinochlore 0.3711 -0.430 206.3 2.314 7.262 78.46 daphnite 0.1064 -0.973 75.89 1.880 2.672 23.00 chlorite-Mn 0.9016E-02 -2.045 6.392 0.806 0.2250 2.037 diopside 0.1409 -0.851 30.51 1.484 1.074 9.326 hedenbergite 0.3610E-01 -1.443 8.956 0.952 0.3153 2.453 microcline 0.4833 -0.316 134.5 2.129 4.736 52.55 stilbite 1.679 0.225 1183. 3.073 41.66 551.9 stilpnomelane-Fe 0.1372 -0.863 147.9 2.170 5.207 51.09 tr.625ac.25prg.125 0.1848E-01 -1.733 15.80 1.199 0.5562 5.084 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8072E+00 0.8072E+00 1.0000 -0.093 grossular 0.1928E+00 0.1928E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1853E-01 0.1853E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2840.429054 g Volume = 1150.007711 cm3 Porosity: -10.4715% V(tot) - V(min): -.10901E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2599.9990000 g log = 3.4150 Original solution: 1000.0103000 g Original solution / Rock added: 0.38 (Water/Rock Ratio), log = -0.4150 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0932 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9628E+00 0.9850 0.1037E+01 0.1053E+01 CO2,gas 0.5086E-08 1.0071 0.5599E-08 0.5560E-08 CH4,gas 0.2361E-01 1.0128 0.2614E-01 0.2581E-01 H2,gas 0.1363E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1761E-06 0.9958 0.1917E-06 0.1925E-06 S2,gas 0.5662E-29 1.0000 0.6190E-29 0.6190E-29 CO,gas 0.1978E-13 1.0000 0.2162E-13 0.2162E-13 SO3,gas 0.1077E-47 1.0000 0.1178E-47 0.1178E-47 SO2,gas 0.6076E-27 1.0000 0.6643E-27 0.6643E-27 HCl,gas 0.3578E-17 1.0000 0.3912E-17 0.3912E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.48529E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.62 -10.25 -3.417 0.17505E+05 -8.252 3 CH4,gas 4.81 1.23 -3.58 -0.896 0.61174E+04 -1.583 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.66 -8.72 -4.359 0.14885E+05 -6.717 6 S2,gas -7.03 -38.24 -31.21 -4.801 0.53287E+05 -29.208 7 CO,gas 3.51 -12.15 -15.67 -4.820 0.26748E+05 -13.665 8 SO3,gas 17.43 -32.50 -49.93 -12.482 0.85252E+05 -47.929 9 SO2,gas 1.14 -28.04 -29.18 -7.781 0.49820E+05 -27.178 10 HCl,gas 5.48 -13.93 -19.41 -9.704 0.33138E+05 -17.408 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80651E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94127E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76236E+04 35 aragonite 0.99 -3.51 -4.49 -1.498 0.76747E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.51 -4.34 -1.447 0.74134E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70379E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65565E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.69 -4.59 -1.311 0.78322E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66056E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.69 -4.15 -1.184 0.70784E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59771E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82277E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61285E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53670E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36603E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92774E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40699E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43448E+04 143 pyrrhotite -4.24 -7.92 -3.67 -1.225 0.62727E+04 144 pyrrhotiteFe0.875 -6.00 -9.31 -3.31 -1.218 0.56555E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22444E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28299E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23236E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47161E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91028E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.92 -3.52 -1.174 0.60159E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80430E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66781E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60331E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.41 -4.45 -1.483 0.75955E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2599.9990000 g New total amount of reactant added: 2699.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3299E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2699.9990000 Water: Moles liquid = 0.4036E+02 kg liquid = 0.7272E+00 Moles total = 0.2166E+02 kg total = 0.3903E+00 Activity = 1.0000 Stoichiometric ionic strength = .1177178E-01 Osmotic coef. = 0.9685 True ionic strength = .2071796E-01 Chg. balance for total moles = 0.3299E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90403E-10 -10.0438 0.75838E-10 -10.1201 0.83888E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.18886E-03 -3.7238 0.15746E-03 -3.8028 0.83373E+00 -0.0790 4 SO4-- 0.10769E-11 -11.9678 0.55537E-12 -12.2554 0.51573E+00 -0.2876 5 HCO3- 0.38844E-06 -6.4107 0.32433E-06 -6.4890 0.83497E+00 -0.0783 6 HS- 0.35068E-04 -4.4551 0.29241E-04 -4.5340 0.83385E+00 -0.0789 7 Al+++ 0.11059E-28 -28.9563 0.25149E-29 -29.5995 0.22740E+00 -0.6432 8 H4SiO4 0.71165E-03 -3.1477 0.71165E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14360E-06 -6.8428 0.73505E-07 -7.1337 0.51186E+00 -0.2908 10 Mg++ 0.22803E-10 -10.6420 0.11617E-10 -10.9349 0.50947E+00 -0.2929 11 Fe++ 0.62375E-13 -13.2050 0.31814E-13 -13.4974 0.51004E+00 -0.2924 12 K+ 0.16168E-03 -3.7914 0.13503E-03 -3.8696 0.83517E+00 -0.0782 13 Na+ 0.20555E-01 -1.6871 0.17134E-01 -1.7661 0.83357E+00 -0.0791 14 Mn++ 0.20006E-10 -10.6988 0.10213E-10 -10.9909 0.51047E+00 -0.2920 15 HPO4-- 0.48668E-07 -7.3128 0.25103E-07 -7.6003 0.51581E+00 -0.2875 16 HSiO3- 0.10981E-01 -1.9593 0.91555E-02 -2.0383 0.83373E+00 -0.0790 17 Ca(HSiO3)+ 0.18050E-07 -7.7435 0.15078E-07 -7.8217 0.83535E+00 -0.0781 18 Mg(HSiO3)+ 0.35503E-11 -11.4497 0.29658E-11 -11.5279 0.83535E+00 -0.0781 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67577E-16 -16.1702 0.56451E-16 -16.2483 0.83535E+00 -0.0781 22 HAlO2,aq 0.14895E-09 -9.8269 0.14895E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52700E-05 -5.2782 0.43856E-05 -5.3580 0.83220E+00 -0.0798 24 CH4,aq 0.16817E-04 -4.7743 0.16757E-04 -4.7758 0.99641E+00 -0.0016 25 C2H6,aq 0.44707E-14 -14.3496 0.44546E-14 -14.3512 0.99641E+00 -0.0016 29 CO,aq 0.13884E-16 -16.8575 0.13884E-16 -16.8575 0.10000E+01 0.0000 30 CO2,aq 0.49770E-10 -10.3030 0.49592E-10 -10.3046 0.99641E+00 -0.0016 31 CO3-2 0.76838E-06 -6.1144 0.39542E-06 -6.4029 0.51462E+00 -0.2885 32 CaCO3,aq 0.35598E-09 -9.4486 0.35598E-09 -9.4486 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.71910E-12 -12.1432 0.60070E-12 -12.2213 0.83535E+00 -0.0781 34 CaCl+ 0.22079E-10 -10.6560 0.18443E-10 -10.7342 0.83535E+00 -0.0781 35 CaCl2,aq 0.67619E-15 -15.1699 0.67619E-15 -15.1699 0.10000E+01 0.0000 36 CaOH+ 0.81814E-07 -7.0872 0.68344E-07 -7.1653 0.83535E+00 -0.0781 37 CaSO4,aq 0.12719E-16 -16.8955 0.12719E-16 -16.8955 0.10000E+01 0.0000 38 HCl,aq 0.22462E-14 -14.6486 0.22462E-14 -14.6486 0.10000E+01 0.0000 43 FeCl+ 0.93401E-17 -17.0297 0.78022E-17 -17.1078 0.83535E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16648E-10 -10.7786 0.13907E-10 -10.8568 0.83535E+00 -0.0781 48 HFeO2- 0.37211E-07 -7.4293 0.31024E-07 -7.5083 0.83373E+00 -0.0790 49 FeO+ 0.12288E-16 -16.9105 0.10265E-16 -16.9886 0.83535E+00 -0.0781 51 FeO2- 0.42074E-09 -9.3760 0.35078E-09 -9.4550 0.83373E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10870E-04 -4.9638 0.99641E+00 -0.0016 54 KCl,aq 0.37647E-09 -9.4243 0.37647E-09 -9.4243 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.13858E-14 -14.8583 0.11553E-14 -14.9373 0.83373E+00 -0.0790 58 MgCO3,aq 0.14059E-13 -13.8521 0.14059E-13 -13.8521 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11589E-15 -15.9359 0.96813E-16 -16.0141 0.83535E+00 -0.0781 60 MgCl+ 0.31678E-14 -14.4992 0.26463E-14 -14.5774 0.83535E+00 -0.0781 61 MgOH+ 0.71637E-10 -10.1449 0.59842E-10 -10.2230 0.83535E+00 -0.0781 63 MnO,aq 0.18745E-08 -8.7271 0.18745E-08 -8.7271 0.10000E+01 0.0000 64 MnOH+ 0.49648E-09 -9.3041 0.41473E-09 -9.3822 0.83535E+00 -0.0781 65 MnO2-2 0.21903E-10 -10.6595 0.11272E-10 -10.9480 0.51462E+00 -0.2885 66 HMnO2- 0.22214E-09 -9.6534 0.18520E-09 -9.7323 0.83373E+00 -0.0790 69 MnCl+ 0.11651E-13 -13.9336 0.97327E-14 -14.0118 0.83535E+00 -0.0781 71 NaCl,aq 0.88095E-06 -6.0551 0.88095E-06 -6.0551 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95043E-02 -2.0221 0.79095E-02 -2.1019 0.83220E+00 -0.0798 79 HPO3-2 0.16749E-14 -14.7760 0.86191E-15 -15.0645 0.51462E+00 -0.2885 81 H2PO3- 0.15401E-18 -18.8125 0.12840E-18 -18.8914 0.83373E+00 -0.0790 82 H3PO4,aq 0.92949E-18 -18.0318 0.92949E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.39995E-10 -10.3980 0.33377E-10 -10.4766 0.83453E+00 -0.0786 84 PO4-3 0.12090E-08 -8.9176 0.28908E-09 -9.5390 0.23910E+00 -0.6214 88 HP2O7-3 0.10356E-17 -17.9848 0.23574E-18 -18.6276 0.22764E+00 -0.6427 89 P2O7-4 0.10222E-16 -16.9904 0.76687E-18 -18.1153 0.75018E-01 -1.1248 90 H2S,aq 0.66869E-08 -8.1748 0.66629E-08 -8.1763 0.99641E+00 -0.0016 91 S2-2 0.33617E-14 -14.4734 0.17300E-14 -14.7620 0.51462E+00 -0.2885 97 SO3-2 0.15763E-17 -17.8024 0.82316E-18 -18.0845 0.52222E+00 -0.2821 99 HSO4- 0.46736E-19 -19.3304 0.39080E-19 -19.4080 0.83619E+00 -0.0777 Charge balance for all species = 0.4537E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9040316E-10 -.2310204E-01 -.2324328E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981170E+06 0.0000 3 Cl- 0.1888650E-03 0.1897463E-03 0.6714888E+01 6.3173 4 SO4-- 0.1076859E-11 -.1954438E-04 -.1874062E+01 7.9848 5 HCO3- 0.3884377E-06 0.1797427E-04 0.1094752E+01 3.6311 6 HS- 0.3506784E-04 0.5461891E-04 0.1803083E+01 5.5861 7 Al+++ 0.1105938E-28 0.5270120E-05 0.1419381E+00 0.7609 8 H4SiO4 0.7116465E-03 0.1418454E-01 0.1360883E+04 -3.1477 9 Ca++ 0.1436034E-06 0.2438467E-06 0.9755181E-02 13.1065 10 Mg++ 0.2280277E-10 0.9800673E-10 0.2378422E-05 9.3053 11 Fe++ 0.6237466E-13 0.3787031E-07 0.2111111E-02 6.7428 12 K+ 0.1616775E-03 0.1624541E-03 0.6340769E+01 6.2505 13 Na+ 0.2055493E-01 0.2314656E-01 0.5311706E+03 8.3540 14 Mn++ 0.2000633E-10 0.2635039E-08 0.1445015E-03 9.2494 15 HPO4-- 0.4866754E-07 0.4991655E-07 0.4782260E-02 12.6400 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4470796E+02 -.1679867E-01 -.4469116E+02 0.0000000E+00 2 H2O 0.2166265E+02 0.4036008E+02 -.1869742E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7485168E-01 -.1421171E-04 0.7486589E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7482618E-01 0.3971618E-04 -.7486589E-01 0.0000000E+00 7 Al+++ 0.8803999E+01 0.3832171E-05 0.8803995E+01 0.0000000E+00 8 H4SiO4 0.2811450E+02 0.1031430E-01 0.2810419E+02 0.0000000E+00 9 Ca++ 0.3105398E+01 0.1773133E-06 0.3105398E+01 0.0000000E+00 10 Mg++ 0.2142856E+01 0.7126566E-10 0.2142856E+01 0.0000000E+00 11 Fe++ 0.1925122E+01 0.2753742E-07 0.1925122E+01 0.0000000E+00 12 K+ 0.5732482E+00 0.1181286E-03 0.5731301E+00 0.0000000E+00 13 Na+ 0.3389317E+01 0.1683104E-01 0.3372486E+01 0.0000000E+00 14 Mn++ 0.4681419E-01 0.1916071E-08 0.4681419E-01 0.0000000E+00 15 HPO4-- 0.1597745E-01 0.3629685E-07 0.1597741E-01 0.0000000E+00 Chg. balance for solid moles: -.1192E-13 Mass of aqueous solution: 0.728471E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2699.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.370 0.528 883.7 2.946 29.96 339.2 andradite 0.2995 -0.524 152.2 2.182 5.159 39.54 grossular 0.7150E-01 -1.146 32.21 1.508 1.092 8.962 apatite-OH 0.5326E-02 -2.274 2.675 0.427 0.9070E-01 0.8501 clinochlore 0.3853 -0.414 214.2 2.331 7.261 81.47 daphnite 0.1104 -0.957 78.80 1.897 2.671 23.88 chlorite-Mn 0.9363E-02 -2.029 6.638 0.822 0.2250 2.115 diopside 0.1467 -0.834 31.77 1.502 1.077 9.708 hedenbergite 0.3758E-01 -1.425 9.323 0.970 0.3161 2.554 microcline 0.5019 -0.299 139.7 2.145 4.736 54.57 stilbite 1.743 0.241 1229. 3.089 41.65 573.0 stilpnomelane-Fe 0.1425 -0.846 153.6 2.186 5.208 53.06 tr.625ac.25prg.125 0.1916E-01 -1.718 16.38 1.214 0.5553 5.272 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1854E-01 0.1854E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 2949.684535 g Volume = 1194.214068 cm3 Porosity: -10.4731% V(tot) - V(min): -.11321E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2699.9990000 g log = 3.4314 Original solution: 1000.0103000 g Original solution / Rock added: 0.37 (Water/Rock Ratio), log = -0.4314 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0936 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9624E+00 0.9850 0.1037E+01 0.1053E+01 CO2,gas 0.5154E-08 1.0071 0.5677E-08 0.5637E-08 CH4,gas 0.2393E-01 1.0128 0.2650E-01 0.2616E-01 H2,gas 0.1363E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1785E-06 0.9958 0.1943E-06 0.1952E-06 S2,gas 0.5818E-29 1.0000 0.6363E-29 0.6363E-29 CO,gas 0.2005E-13 1.0000 0.2192E-13 0.2192E-13 SO3,gas 0.1092E-47 1.0000 0.1194E-47 0.1194E-47 SO2,gas 0.6159E-27 1.0000 0.6735E-27 0.6735E-27 HCl,gas 0.3627E-17 1.0000 0.3966E-17 0.3966E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 -0.36397E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.72794E-10 67 diopside 16.22 16.22 0.00 0.000 0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 0.21232E-10 116 microcline -2.43 -2.43 0.00 0.000 0.18957E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.37914E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.61 -10.25 -3.415 0.17495E+05 -8.246 3 CH4,gas 4.81 1.23 -3.58 -0.894 0.61072E+04 -1.577 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.65 -8.71 -4.356 0.14875E+05 -6.711 6 S2,gas -7.03 -38.23 -31.20 -4.799 0.53267E+05 -29.196 7 CO,gas 3.51 -12.15 -15.66 -4.818 0.26737E+05 -13.659 8 SO3,gas 17.43 -32.50 -49.92 -12.481 0.85242E+05 -47.923 9 SO2,gas 1.14 -28.04 -29.17 -7.779 0.49810E+05 -27.172 10 HCl,gas 5.48 -13.92 -19.40 -9.701 0.33128E+05 -17.402 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80648E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94127E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76236E+04 35 aragonite 0.99 -3.50 -4.49 -1.496 0.76645E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.50 -4.34 -1.445 0.74032E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68650E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70379E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65564E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.69 -4.58 -1.309 0.78220E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66056E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.69 -4.14 -1.183 0.70682E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82276E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61285E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53670E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92774E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40699E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43448E+04 143 pyrrhotite -4.24 -7.91 -3.67 -1.223 0.62625E+04 144 pyrrhotiteFe0.875 -6.00 -9.31 -3.31 -1.216 0.56453E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22443E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28299E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23235E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27395E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47159E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91028E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65756E+04 181 troilite-low -4.39 -7.91 -3.52 -1.172 0.60057E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80431E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34510E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66781E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60331E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.40 -4.44 -1.481 0.75852E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2699.9990000 g New total amount of reactant added: 2799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3299E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2799.9990000 Water: Moles liquid = 0.3981E+02 kg liquid = 0.7171E+00 Moles total = 0.2041E+02 kg total = 0.3677E+00 Activity = 1.0000 Stoichiometric ionic strength = .1177400E-01 Osmotic coef. = 0.9685 True ionic strength = .2071969E-01 Chg. balance for total moles = 0.3299E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90411E-10 -10.0438 0.75844E-10 -10.1201 0.83888E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.19151E-03 -3.7178 0.15967E-03 -3.7968 0.83372E+00 -0.0790 4 SO4-- 0.10919E-11 -11.9618 0.56311E-12 -12.2494 0.51572E+00 -0.2876 5 HCO3- 0.39386E-06 -6.4047 0.32886E-06 -6.4830 0.83496E+00 -0.0783 6 HS- 0.35559E-04 -4.4490 0.29651E-04 -4.5280 0.83385E+00 -0.0789 7 Al+++ 0.11062E-28 -28.9561 0.25155E-29 -29.5994 0.22739E+00 -0.6432 8 H4SiO4 0.71165E-03 -3.1477 0.71165E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14363E-06 -6.8428 0.73516E-07 -7.1336 0.51185E+00 -0.2909 10 Mg++ 0.22807E-10 -10.6419 0.11619E-10 -10.9348 0.50946E+00 -0.2929 11 Fe++ 0.62386E-13 -13.2049 0.31819E-13 -13.4973 0.51003E+00 -0.2924 12 K+ 0.16169E-03 -3.7913 0.13504E-03 -3.8695 0.83517E+00 -0.0782 13 Na+ 0.20557E-01 -1.6870 0.17135E-01 -1.7661 0.83356E+00 -0.0791 14 Mn++ 0.20012E-10 -10.6987 0.10216E-10 -10.9907 0.51046E+00 -0.2920 15 HPO4-- 0.48661E-07 -7.3128 0.25099E-07 -7.6003 0.51580E+00 -0.2875 16 HSiO3- 0.10981E-01 -1.9594 0.91548E-02 -2.0384 0.83372E+00 -0.0790 17 Ca(HSiO3)+ 0.18052E-07 -7.7435 0.15079E-07 -7.8216 0.83535E+00 -0.0781 18 Mg(HSiO3)+ 0.35506E-11 -11.4497 0.29660E-11 -11.5278 0.83535E+00 -0.0781 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67582E-16 -16.1702 0.56455E-16 -16.2483 0.83535E+00 -0.0781 22 HAlO2,aq 0.14895E-09 -9.8269 0.14895E-09 -9.8269 0.10000E+01 0.0000 23 AlO2- 0.52696E-05 -5.2782 0.43853E-05 -5.3580 0.83219E+00 -0.0798 24 CH4,aq 0.17053E-04 -4.7682 0.16992E-04 -4.7698 0.99641E+00 -0.0016 25 C2H6,aq 0.45969E-14 -14.3375 0.45804E-14 -14.3391 0.99641E+00 -0.0016 29 CO,aq 0.14079E-16 -16.8514 0.14079E-16 -16.8514 0.10000E+01 0.0000 30 CO2,aq 0.50469E-10 -10.2970 0.50288E-10 -10.2985 0.99641E+00 -0.0016 31 CO3-2 0.77906E-06 -6.1084 0.40091E-06 -6.3970 0.51460E+00 -0.2885 32 CaCO3,aq 0.36098E-09 -9.4425 0.36098E-09 -9.4425 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.72925E-12 -12.1371 0.60918E-12 -12.2153 0.83535E+00 -0.0781 34 CaCl+ 0.22391E-10 -10.6499 0.18705E-10 -10.7281 0.83535E+00 -0.0781 35 CaCl2,aq 0.69537E-15 -15.1578 0.69537E-15 -15.1578 0.10000E+01 0.0000 36 CaOH+ 0.81821E-07 -7.0871 0.68349E-07 -7.1653 0.83535E+00 -0.0781 37 CaSO4,aq 0.12899E-16 -16.8895 0.12899E-16 -16.8895 0.10000E+01 0.0000 38 HCl,aq 0.22778E-14 -14.6425 0.22778E-14 -14.6425 0.10000E+01 0.0000 43 FeCl+ 0.94724E-17 -17.0235 0.79127E-17 -17.1017 0.83535E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16650E-10 -10.7786 0.13908E-10 -10.8567 0.83535E+00 -0.0781 48 HFeO2- 0.37208E-07 -7.4294 0.31021E-07 -7.5083 0.83372E+00 -0.0790 49 FeO+ 0.12289E-16 -16.9105 0.10266E-16 -16.9886 0.83535E+00 -0.0781 51 FeO2- 0.42071E-09 -9.3760 0.35075E-09 -9.4550 0.83372E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10870E-04 -4.9638 0.99641E+00 -0.0016 54 KCl,aq 0.38177E-09 -9.4182 0.38177E-09 -9.4182 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.14052E-14 -14.8523 0.11715E-14 -14.9312 0.83372E+00 -0.0790 58 MgCO3,aq 0.14256E-13 -13.8460 0.14256E-13 -13.8460 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11753E-15 -15.9298 0.98179E-16 -16.0080 0.83535E+00 -0.0781 60 MgCl+ 0.32127E-14 -14.4931 0.26837E-14 -14.5713 0.83535E+00 -0.0781 61 MgOH+ 0.71642E-10 -10.1448 0.59846E-10 -10.2230 0.83535E+00 -0.0781 63 MnO,aq 0.18747E-08 -8.7271 0.18747E-08 -8.7271 0.10000E+01 0.0000 64 MnOH+ 0.49658E-09 -9.3040 0.41482E-09 -9.3821 0.83535E+00 -0.0781 65 MnO2-2 0.21903E-10 -10.6595 0.11271E-10 -10.9480 0.51460E+00 -0.2885 66 HMnO2- 0.22215E-09 -9.6533 0.18521E-09 -9.7323 0.83372E+00 -0.0790 69 MnCl+ 0.11817E-13 -13.9275 0.98717E-14 -14.0056 0.83535E+00 -0.0781 71 NaCl,aq 0.89335E-06 -6.0490 0.89335E-06 -6.0490 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95036E-02 -2.0221 0.79088E-02 -2.1019 0.83219E+00 -0.0798 79 HPO3-2 0.16746E-14 -14.7761 0.86178E-15 -15.0646 0.51460E+00 -0.2885 81 H2PO3- 0.15399E-18 -18.8125 0.12839E-18 -18.8915 0.83372E+00 -0.0790 82 H3PO4,aq 0.92949E-18 -18.0318 0.92949E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.39992E-10 -10.3980 0.33374E-10 -10.4766 0.83453E+00 -0.0786 84 PO4-3 0.12088E-08 -8.9176 0.28901E-09 -9.5391 0.23909E+00 -0.6214 88 HP2O7-3 0.10354E-17 -17.9849 0.23569E-18 -18.6277 0.22763E+00 -0.6428 89 P2O7-4 0.10220E-16 -16.9905 0.76664E-18 -18.1154 0.75011E-01 -1.1249 90 H2S,aq 0.67811E-08 -8.1687 0.67567E-08 -8.1703 0.99641E+00 -0.0016 91 S2-2 0.34566E-14 -14.4613 0.17788E-14 -14.7499 0.51460E+00 -0.2885 97 SO3-2 0.15983E-17 -17.7964 0.83463E-18 -18.0785 0.52221E+00 -0.2822 99 HSO4- 0.47391E-19 -19.3243 0.39628E-19 -19.4020 0.83618E+00 -0.0777 Charge balance for all species = 0.4604E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9041061E-10 -.2310061E-01 -.2324183E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981169E+06 0.0000 3 Cl- 0.1915109E-03 0.1924047E-03 0.6808963E+01 6.3233 4 SO4-- 0.1091895E-11 -.1978009E-04 -.1896664E+01 7.9908 5 HCO3- 0.3938591E-06 0.1822609E-04 0.1110090E+01 3.6371 6 HS- 0.3555915E-04 0.5534602E-04 0.1827087E+01 5.5921 7 Al+++ 0.1106245E-28 0.5269720E-05 0.1419273E+00 0.7609 8 H4SiO4 0.7116476E-03 0.1418378E-01 0.1360809E+04 -3.1477 9 Ca++ 0.1436286E-06 0.2438853E-06 0.9756725E-02 13.1065 10 Mg++ 0.2280677E-10 0.9801677E-10 0.2378666E-05 9.3053 11 Fe++ 0.6238567E-13 0.3786759E-07 0.2110959E-02 6.7428 12 K+ 0.1616909E-03 0.1624674E-03 0.6341291E+01 6.2505 13 Na+ 0.2055664E-01 0.2314828E-01 0.5312100E+03 8.3540 14 Mn++ 0.2001233E-10 0.2635389E-08 0.1445207E-03 9.2494 15 HPO4-- 0.4866122E-07 0.4991000E-07 0.4781632E-02 12.6398 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4636381E+02 -.1656554E-01 -.4634725E+02 0.0000000E+00 2 H2O 0.2040911E+02 0.3980244E+02 -.1939333E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.7762302E-01 -.1418438E-04 0.7763721E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.7759752E-01 0.3968885E-04 -.7763721E-01 0.0000000E+00 7 Al+++ 0.9130073E+01 0.3778937E-05 0.9130069E+01 0.0000000E+00 8 H4SiO4 0.2915578E+02 0.1017124E-01 0.2914561E+02 0.0000000E+00 9 Ca++ 0.3220413E+01 0.1748911E-06 0.3220413E+01 0.0000000E+00 10 Mg++ 0.2222221E+01 0.7028822E-10 0.2222221E+01 0.0000000E+00 11 Fe++ 0.1996423E+01 0.2715500E-07 0.1996423E+01 0.0000000E+00 12 K+ 0.5944796E+00 0.1165061E-03 0.5943631E+00 0.0000000E+00 13 Na+ 0.3514841E+01 0.1659972E-01 0.3498241E+01 0.0000000E+00 14 Mn++ 0.4854805E-01 0.1889848E-08 0.4854805E-01 0.0000000E+00 15 HPO4-- 0.1656921E-01 0.3579066E-07 0.1656917E-01 0.0000000E+00 Chg. balance for solid moles: -.9312E-14 Mass of aqueous solution: 0.718406E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.496 0.544 916.7 2.962 29.97 351.9 andradite 0.3105 -0.508 157.8 2.198 5.159 41.00 grossular 0.7415E-01 -1.130 33.40 1.524 1.092 9.294 apatite-OH 0.5523E-02 -2.258 2.774 0.443 0.9070E-01 0.8816 clinochlore 0.3996 -0.398 222.1 2.347 7.260 84.48 daphnite 0.1145 -0.941 81.71 1.912 2.671 24.76 chlorite-Mn 0.9710E-02 -2.013 6.884 0.838 0.2250 2.194 diopside 0.1525 -0.817 33.02 1.519 1.079 10.09 hedenbergite 0.3906E-01 -1.408 9.691 0.986 0.3168 2.654 microcline 0.5205 -0.284 144.9 2.161 4.736 56.59 stilbite 1.807 0.257 1274. 3.105 41.64 594.1 stilpnomelane-Fe 0.1478 -0.830 159.3 2.202 5.208 55.03 tr.625ac.25prg.125 0.1984E-01 -1.702 16.96 1.229 0.5545 5.459 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1854E-01 0.1854E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3058.940017 g Volume = 1238.420425 cm3 Porosity: -10.4747% V(tot) - V(min): -.11742E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2799.9990000 g log = 3.4472 Original solution: 1000.0103000 g Original solution / Rock added: 0.36 (Water/Rock Ratio), log = -0.4472 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0940 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9621E+00 0.9850 0.1037E+01 0.1053E+01 CO2,gas 0.5225E-08 1.0070 0.5756E-08 0.5716E-08 CH4,gas 0.2425E-01 1.0128 0.2687E-01 0.2653E-01 H2,gas 0.1362E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1809E-06 0.9958 0.1971E-06 0.1979E-06 S2,gas 0.5981E-29 1.0000 0.6543E-29 0.6543E-29 CO,gas 0.2032E-13 1.0000 0.2223E-13 0.2223E-13 SO3,gas 0.1107E-47 1.0000 0.1211E-47 0.1211E-47 SO2,gas 0.6244E-27 1.0000 0.6830E-27 0.6830E-27 HCl,gas 0.3676E-17 1.0000 0.4022E-17 0.4022E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.60 -10.24 -3.413 0.17484E+05 -8.240 3 CH4,gas 4.81 1.24 -3.57 -0.893 0.60969E+04 -1.571 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.65 -8.71 -4.353 0.14864E+05 -6.705 6 S2,gas -7.03 -38.22 -31.18 -4.798 0.53246E+05 -29.184 7 CO,gas 3.51 -12.14 -15.65 -4.816 0.26727E+05 -13.653 8 SO3,gas 17.43 -32.49 -49.92 -12.479 0.85232E+05 -47.917 9 SO2,gas 1.14 -28.03 -29.17 -7.777 0.49799E+05 -27.166 10 HCl,gas 5.48 -13.92 -19.40 -9.698 0.33117E+05 -17.396 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80645E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94127E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76236E+04 35 aragonite 0.99 -3.50 -4.48 -1.494 0.76542E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.50 -4.33 -1.443 0.73928E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70379E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65563E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.68 -4.58 -1.307 0.78117E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66056E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.68 -4.13 -1.181 0.70579E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82275E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61285E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53670E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92775E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40699E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43448E+04 143 pyrrhotite -4.24 -7.91 -3.66 -1.221 0.62521E+04 144 pyrrhotiteFe0.875 -6.00 -9.30 -3.30 -1.214 0.56349E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22442E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28299E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23234E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47157E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91028E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.91 -3.51 -1.170 0.59953E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80431E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66782E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60331E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.40 -4.44 -1.479 0.75747E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2799.9990000 g New total amount of reactant added: 2899.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3300E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2899.9990000 Water: Moles liquid = 0.3925E+02 kg liquid = 0.7071E+00 Moles total = 0.1916E+02 kg total = 0.3451E+00 Activity = 1.0000 Stoichiometric ionic strength = .1177627E-01 Osmotic coef. = 0.9685 True ionic strength = .2072147E-01 Chg. balance for total moles = 0.3300E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90418E-10 -10.0437 0.75850E-10 -10.1200 0.83887E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.19423E-03 -3.7117 0.16193E-03 -3.7907 0.83372E+00 -0.0790 4 SO4-- 0.11074E-11 -11.9557 0.57107E-12 -12.2433 0.51571E+00 -0.2876 5 HCO3- 0.39943E-06 -6.3986 0.33351E-06 -6.4769 0.83496E+00 -0.0783 6 HS- 0.36064E-04 -4.4429 0.30072E-04 -4.5218 0.83384E+00 -0.0789 7 Al+++ 0.11066E-28 -28.9560 0.25161E-29 -29.5993 0.22738E+00 -0.6433 8 H4SiO4 0.71165E-03 -3.1477 0.71165E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14365E-06 -6.8427 0.73528E-07 -7.1335 0.51184E+00 -0.2909 10 Mg++ 0.22811E-10 -10.6419 0.11621E-10 -10.9348 0.50945E+00 -0.2929 11 Fe++ 0.62397E-13 -13.2048 0.31824E-13 -13.4973 0.51002E+00 -0.2924 12 K+ 0.16170E-03 -3.7913 0.13505E-03 -3.8695 0.83516E+00 -0.0782 13 Na+ 0.20558E-01 -1.6870 0.17137E-01 -1.7661 0.83356E+00 -0.0791 14 Mn++ 0.20018E-10 -10.6986 0.10218E-10 -10.9906 0.51045E+00 -0.2920 15 HPO4-- 0.48655E-07 -7.3129 0.25095E-07 -7.6004 0.51579E+00 -0.2875 16 HSiO3- 0.10980E-01 -1.9594 0.91541E-02 -2.0384 0.83372E+00 -0.0790 17 Ca(HSiO3)+ 0.18053E-07 -7.7434 0.15081E-07 -7.8216 0.83534E+00 -0.0781 18 Mg(HSiO3)+ 0.35509E-11 -11.4497 0.29662E-11 -11.5278 0.83534E+00 -0.0781 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67588E-16 -16.1701 0.56459E-16 -16.2483 0.83534E+00 -0.0781 22 HAlO2,aq 0.14895E-09 -9.8270 0.14895E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52692E-05 -5.2783 0.43849E-05 -5.3580 0.83219E+00 -0.0798 24 CH4,aq 0.17295E-04 -4.7621 0.17233E-04 -4.7636 0.99641E+00 -0.0016 25 C2H6,aq 0.47285E-14 -14.3253 0.47115E-14 -14.3268 0.99641E+00 -0.0016 29 CO,aq 0.14279E-16 -16.8453 0.14279E-16 -16.8453 0.10000E+01 0.0000 30 CO2,aq 0.51187E-10 -10.2908 0.51003E-10 -10.2924 0.99641E+00 -0.0016 31 CO3-2 0.79003E-06 -6.1024 0.40655E-06 -6.3909 0.51459E+00 -0.2885 32 CaCO3,aq 0.36611E-09 -9.4364 0.36611E-09 -9.4364 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.73969E-12 -12.1310 0.61789E-12 -12.2091 0.83534E+00 -0.0781 34 CaCl+ 0.22713E-10 -10.6437 0.18973E-10 -10.7219 0.83534E+00 -0.0781 35 CaCl2,aq 0.71537E-15 -15.1455 0.71537E-15 -15.1455 0.10000E+01 0.0000 36 CaOH+ 0.81828E-07 -7.0871 0.68354E-07 -7.1652 0.83534E+00 -0.0781 37 CaSO4,aq 0.13083E-16 -16.8833 0.13083E-16 -16.8833 0.10000E+01 0.0000 38 HCl,aq 0.23103E-14 -14.6363 0.23103E-14 -14.6363 0.10000E+01 0.0000 43 FeCl+ 0.96085E-17 -17.0173 0.80264E-17 -17.0955 0.83534E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16651E-10 -10.7786 0.13909E-10 -10.8567 0.83534E+00 -0.0781 48 HFeO2- 0.37205E-07 -7.4294 0.31019E-07 -7.5084 0.83372E+00 -0.0790 49 FeO+ 0.12290E-16 -16.9104 0.10266E-16 -16.9886 0.83534E+00 -0.0781 51 FeO2- 0.42068E-09 -9.3760 0.35073E-09 -9.4550 0.83372E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99641E+00 -0.0016 54 KCl,aq 0.38723E-09 -9.4120 0.38723E-09 -9.4120 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.14252E-14 -14.8461 0.11882E-14 -14.9251 0.83372E+00 -0.0790 58 MgCO3,aq 0.14459E-13 -13.8399 0.14459E-13 -13.8399 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.11921E-15 -15.9237 0.99584E-16 -16.0018 0.83534E+00 -0.0781 60 MgCl+ 0.32589E-14 -14.4869 0.27223E-14 -14.5651 0.83534E+00 -0.0781 61 MgOH+ 0.71648E-10 -10.1448 0.59851E-10 -10.2229 0.83534E+00 -0.0781 63 MnO,aq 0.18749E-08 -8.7270 0.18749E-08 -8.7270 0.10000E+01 0.0000 64 MnOH+ 0.49668E-09 -9.3039 0.41490E-09 -9.3821 0.83534E+00 -0.0781 65 MnO2-2 0.21902E-10 -10.6595 0.11271E-10 -10.9480 0.51459E+00 -0.2885 66 HMnO2- 0.22216E-09 -9.6533 0.18522E-09 -9.7323 0.83372E+00 -0.0790 69 MnCl+ 0.11989E-13 -13.9212 0.10015E-13 -13.9994 0.83534E+00 -0.0781 71 NaCl,aq 0.90611E-06 -6.0428 0.90611E-06 -6.0428 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95029E-02 -2.0221 0.79082E-02 -2.1019 0.83219E+00 -0.0798 79 HPO3-2 0.16744E-14 -14.7761 0.86164E-15 -15.0647 0.51459E+00 -0.2885 81 H2PO3- 0.15398E-18 -18.8125 0.12838E-18 -18.8915 0.83372E+00 -0.0790 82 H3PO4,aq 0.92950E-18 -18.0318 0.92950E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.39989E-10 -10.3981 0.33372E-10 -10.4766 0.83452E+00 -0.0786 84 PO4-3 0.12086E-08 -8.9177 0.28894E-09 -9.5392 0.23908E+00 -0.6215 88 HP2O7-3 0.10352E-17 -17.9850 0.23564E-18 -18.6278 0.22762E+00 -0.6428 89 P2O7-4 0.10218E-16 -16.9906 0.76640E-18 -18.1155 0.75005E-01 -1.1249 90 H2S,aq 0.68779E-08 -8.1625 0.68532E-08 -8.1641 0.99641E+00 -0.0016 91 S2-2 0.35556E-14 -14.4491 0.18297E-14 -14.7376 0.51459E+00 -0.2885 97 SO3-2 0.16209E-17 -17.7902 0.84643E-18 -18.0724 0.52220E+00 -0.2822 99 HSO4- 0.48065E-19 -19.3182 0.40191E-19 -19.3959 0.83618E+00 -0.0777 Charge balance for all species = 0.4664E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9041827E-10 -.2309913E-01 -.2324035E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981168E+06 0.0000 3 Cl- 0.1942321E-03 0.1951386E-03 0.6905713E+01 6.3294 4 SO4-- 0.1107354E-11 -.2002250E-04 -.1919908E+01 7.9968 5 HCO3- 0.3994336E-06 0.1848507E-04 0.1125863E+01 3.6432 6 HS- 0.3606441E-04 0.5609379E-04 0.1851772E+01 5.5982 7 Al+++ 0.1106561E-28 0.5269312E-05 0.1419163E+00 0.7609 8 H4SiO4 0.7116486E-03 0.1418299E-01 0.1360733E+04 -3.1477 9 Ca++ 0.1436545E-06 0.2439251E-06 0.9758314E-02 13.1065 10 Mg++ 0.2281089E-10 0.9802773E-10 0.2378932E-05 9.3053 11 Fe++ 0.6239699E-13 0.3786481E-07 0.2110804E-02 6.7428 12 K+ 0.1617046E-03 0.1624812E-03 0.6341827E+01 6.2505 13 Na+ 0.2055839E-01 0.2315004E-01 0.5312504E+03 8.3540 14 Mn++ 0.2001826E-10 0.2635718E-08 0.1445387E-03 9.2495 15 HPO4-- 0.4865471E-07 0.4990326E-07 0.4780986E-02 12.6397 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4801967E+02 -.1633241E-01 -.4800333E+02 0.0000000E+00 2 H2O 0.1915557E+02 0.3924480E+02 -.2008923E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8039436E-01 -.1415705E-04 0.8040852E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8036886E-01 0.3966152E-04 -.8040852E-01 0.0000000E+00 7 Al+++ 0.9456147E+01 0.3725705E-05 0.9456144E+01 0.0000000E+00 8 H4SiO4 0.3019706E+02 0.1002819E-01 0.3018703E+02 0.0000000E+00 9 Ca++ 0.3335427E+01 0.1724690E-06 0.3335427E+01 0.0000000E+00 10 Mg++ 0.2301587E+01 0.6931122E-10 0.2301587E+01 0.0000000E+00 11 Fe++ 0.2067724E+01 0.2677259E-07 0.2067724E+01 0.0000000E+00 12 K+ 0.6157110E+00 0.1148835E-03 0.6155962E+00 0.0000000E+00 13 Na+ 0.3640365E+01 0.1636841E-01 0.3623997E+01 0.0000000E+00 14 Mn++ 0.5028191E-01 0.1863603E-08 0.5028191E-01 0.0000000E+00 15 HPO4-- 0.1716097E-01 0.3528447E-07 0.1716093E-01 0.0000000E+00 Chg. balance for solid moles: -.1589E-14 Mass of aqueous solution: 0.708341E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2899.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.621 0.559 949.6 2.978 29.97 364.5 andradite 0.3216 -0.493 163.4 2.213 5.159 42.47 grossular 0.7680E-01 -1.115 34.59 1.539 1.092 9.625 apatite-OH 0.5720E-02 -2.243 2.873 0.458 0.9070E-01 0.9131 clinochlore 0.4138 -0.383 230.0 2.362 7.259 87.48 daphnite 0.1186 -0.926 84.62 1.927 2.671 25.64 chlorite-Mn 0.1006E-01 -1.998 7.130 0.853 0.2250 2.272 diopside 0.1583 -0.801 34.27 1.535 1.082 10.47 hedenbergite 0.4054E-01 -1.392 10.06 1.003 0.3175 2.755 microcline 0.5391 -0.268 150.0 2.176 4.736 58.61 stilbite 1.872 0.272 1319. 3.120 41.63 615.2 stilpnomelane-Fe 0.1531 -0.815 165.0 2.217 5.208 56.99 tr.625ac.25prg.125 0.2053E-01 -1.688 17.54 1.244 0.5538 5.647 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1854E-01 0.1854E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3168.195498 g Volume = 1282.626782 cm3 Porosity: -10.4761% V(tot) - V(min): -.12163E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2899.9990000 g log = 3.4624 Original solution: 1000.0103000 g Original solution / Rock added: 0.34 (Water/Rock Ratio), log = -0.4624 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0944 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9618E+00 0.9849 0.1037E+01 0.1053E+01 CO2,gas 0.5298E-08 1.0070 0.5838E-08 0.5797E-08 CH4,gas 0.2459E-01 1.0127 0.2725E-01 0.2691E-01 H2,gas 0.1362E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1834E-06 0.9957 0.1999E-06 0.2007E-06 S2,gas 0.6151E-29 1.0000 0.6732E-29 0.6732E-29 CO,gas 0.2060E-13 1.0000 0.2255E-13 0.2255E-13 SO3,gas 0.1122E-47 1.0000 0.1228E-47 0.1228E-47 SO2,gas 0.6331E-27 1.0000 0.6928E-27 0.6928E-27 HCl,gas 0.3728E-17 1.0000 0.4079E-17 0.4079E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.60 -10.23 -3.411 0.17474E+05 -8.234 3 CH4,gas 4.81 1.24 -3.56 -0.891 0.60865E+04 -1.565 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.64 -8.70 -4.350 0.14854E+05 -6.699 6 S2,gas -7.03 -38.20 -31.17 -4.796 0.53225E+05 -29.172 7 CO,gas 3.51 -12.14 -15.65 -4.814 0.26717E+05 -13.647 8 SO3,gas 17.43 -32.48 -49.91 -12.478 0.85221E+05 -47.911 9 SO2,gas 1.14 -28.02 -29.16 -7.776 0.49789E+05 -27.159 10 HCl,gas 5.48 -13.91 -19.39 -9.695 0.33107E+05 -17.389 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80643E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94127E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76236E+04 35 aragonite 0.99 -3.49 -4.48 -1.492 0.76437E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.49 -4.32 -1.441 0.73824E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70379E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65562E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.68 -4.57 -1.305 0.78012E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66056E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36654E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.68 -4.13 -1.179 0.70474E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28461E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82274E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53670E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92775E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40699E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43448E+04 143 pyrrhotite -4.24 -7.90 -3.66 -1.218 0.62416E+04 144 pyrrhotiteFe0.875 -6.00 -9.29 -3.29 -1.211 0.56244E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22441E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28299E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23234E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47155E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91028E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.90 -3.51 -1.168 0.59848E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80432E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66782E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60330E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.39 -4.43 -1.477 0.75641E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2899.9990000 g New total amount of reactant added: 2999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3299E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 2999.9990000 Water: Moles liquid = 0.3869E+02 kg liquid = 0.6970E+00 Moles total = 0.1790E+02 kg total = 0.3225E+00 Activity = 1.0000 Stoichiometric ionic strength = .1177861E-01 Osmotic coef. = 0.9685 True ionic strength = .2072329E-01 Chg. balance for total moles = 0.3299E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90426E-10 -10.0437 0.75856E-10 -10.1200 0.83887E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.19703E-03 -3.7055 0.16427E-03 -3.7844 0.83371E+00 -0.0790 4 SO4-- 0.11233E-11 -11.9495 0.57926E-12 -12.2371 0.51570E+00 -0.2876 5 HCO3- 0.40517E-06 -6.3924 0.33830E-06 -6.4707 0.83496E+00 -0.0783 6 HS- 0.36584E-04 -4.4367 0.30505E-04 -4.5156 0.83384E+00 -0.0789 7 Al+++ 0.11069E-28 -28.9559 0.25167E-29 -29.5992 0.22737E+00 -0.6433 8 H4SiO4 0.71165E-03 -3.1477 0.71165E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14368E-06 -6.8426 0.73540E-07 -7.1335 0.51183E+00 -0.2909 10 Mg++ 0.22815E-10 -10.6418 0.11623E-10 -10.9347 0.50944E+00 -0.2929 11 Fe++ 0.62409E-13 -13.2048 0.31829E-13 -13.4972 0.51000E+00 -0.2924 12 K+ 0.16172E-03 -3.7912 0.13506E-03 -3.8695 0.83516E+00 -0.0782 13 Na+ 0.20560E-01 -1.6870 0.17138E-01 -1.7660 0.83355E+00 -0.0791 14 Mn++ 0.20024E-10 -10.6984 0.10221E-10 -10.9905 0.51044E+00 -0.2921 15 HPO4-- 0.48648E-07 -7.3129 0.25091E-07 -7.6005 0.51577E+00 -0.2875 16 HSiO3- 0.10979E-01 -1.9594 0.91533E-02 -2.0384 0.83371E+00 -0.0790 17 Ca(HSiO3)+ 0.18055E-07 -7.7434 0.15082E-07 -7.8215 0.83534E+00 -0.0781 18 Mg(HSiO3)+ 0.35512E-11 -11.4496 0.29665E-11 -11.5278 0.83534E+00 -0.0781 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67593E-16 -16.1701 0.56463E-16 -16.2482 0.83534E+00 -0.0781 22 HAlO2,aq 0.14895E-09 -9.8270 0.14895E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52687E-05 -5.2783 0.43845E-05 -5.3581 0.83218E+00 -0.0798 24 CH4,aq 0.17545E-04 -4.7559 0.17482E-04 -4.7574 0.99641E+00 -0.0016 25 C2H6,aq 0.48659E-14 -14.3128 0.48484E-14 -14.3144 0.99641E+00 -0.0016 29 CO,aq 0.14485E-16 -16.8391 0.14485E-16 -16.8391 0.10000E+01 0.0000 30 CO2,aq 0.51926E-10 -10.2846 0.51739E-10 -10.2862 0.99641E+00 -0.0016 31 CO3-2 0.80132E-06 -6.0962 0.41235E-06 -6.3847 0.51458E+00 -0.2885 32 CaCO3,aq 0.37139E-09 -9.4302 0.37139E-09 -9.4302 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.75043E-12 -12.1247 0.62686E-12 -12.2028 0.83534E+00 -0.0781 34 CaCl+ 0.23044E-10 -10.6374 0.19250E-10 -10.7156 0.83534E+00 -0.0781 35 CaCl2,aq 0.73625E-15 -15.1330 0.73625E-15 -15.1330 0.10000E+01 0.0000 36 CaOH+ 0.81835E-07 -7.0871 0.68360E-07 -7.1652 0.83534E+00 -0.0781 37 CaSO4,aq 0.13273E-16 -16.8770 0.13273E-16 -16.8770 0.10000E+01 0.0000 38 HCl,aq 0.23438E-14 -14.6301 0.23438E-14 -14.6301 0.10000E+01 0.0000 43 FeCl+ 0.97485E-17 -17.0111 0.81433E-17 -17.0892 0.83534E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16653E-10 -10.7785 0.13911E-10 -10.8567 0.83534E+00 -0.0781 48 HFeO2- 0.37203E-07 -7.4294 0.31016E-07 -7.5084 0.83371E+00 -0.0790 49 FeO+ 0.12291E-16 -16.9104 0.10267E-16 -16.9885 0.83534E+00 -0.0781 51 FeO2- 0.42065E-09 -9.3761 0.35070E-09 -9.4551 0.83371E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99641E+00 -0.0016 54 KCl,aq 0.39284E-09 -9.4058 0.39284E-09 -9.4058 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.14457E-14 -14.8399 0.12053E-14 -14.9189 0.83371E+00 -0.0790 58 MgCO3,aq 0.14667E-13 -13.8336 0.14667E-13 -13.8336 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12094E-15 -15.9174 0.10103E-15 -15.9956 0.83534E+00 -0.0781 60 MgCl+ 0.33064E-14 -14.4806 0.27619E-14 -14.5588 0.83534E+00 -0.0781 61 MgOH+ 0.71655E-10 -10.1448 0.59856E-10 -10.2229 0.83534E+00 -0.0781 63 MnO,aq 0.18751E-08 -8.7270 0.18751E-08 -8.7270 0.10000E+01 0.0000 64 MnOH+ 0.49678E-09 -9.3038 0.41498E-09 -9.3820 0.83534E+00 -0.0781 65 MnO2-2 0.21901E-10 -10.6595 0.11270E-10 -10.9481 0.51458E+00 -0.2885 66 HMnO2- 0.22217E-09 -9.6533 0.18522E-09 -9.7323 0.83371E+00 -0.0790 69 MnCl+ 0.12165E-13 -13.9149 0.10162E-13 -13.9930 0.83534E+00 -0.0781 71 NaCl,aq 0.91924E-06 -6.0366 0.91924E-06 -6.0366 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95022E-02 -2.0222 0.79076E-02 -2.1020 0.83218E+00 -0.0798 79 HPO3-2 0.16742E-14 -14.7762 0.86150E-15 -15.0647 0.51458E+00 -0.2885 81 H2PO3- 0.15397E-18 -18.8126 0.12837E-18 -18.8915 0.83371E+00 -0.0790 82 H3PO4,aq 0.92950E-18 -18.0318 0.92950E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.39986E-10 -10.3981 0.33369E-10 -10.4767 0.83452E+00 -0.0786 84 PO4-3 0.12083E-08 -8.9178 0.28887E-09 -9.5393 0.23907E+00 -0.6215 88 HP2O7-3 0.10350E-17 -17.9850 0.23558E-18 -18.6279 0.22761E+00 -0.6428 89 P2O7-4 0.10216E-16 -16.9907 0.76615E-18 -18.1157 0.74998E-01 -1.1250 90 H2S,aq 0.69776E-08 -8.1563 0.69526E-08 -8.1579 0.99641E+00 -0.0016 91 S2-2 0.36589E-14 -14.4366 0.18828E-14 -14.7252 0.51458E+00 -0.2885 97 SO3-2 0.16442E-17 -17.7841 0.85856E-18 -18.0662 0.52219E+00 -0.2822 99 HSO4- 0.48759E-19 -19.3119 0.40771E-19 -19.3897 0.83617E+00 -0.0777 Charge balance for all species = 0.4736E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9042615E-10 -.2309761E-01 -.2323881E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981167E+06 0.0000 3 Cl- 0.1970317E-03 0.1979513E-03 0.7005251E+01 6.3356 4 SO4-- 0.1123257E-11 -.2027191E-04 -.1943823E+01 8.0029 5 HCO3- 0.4051677E-06 0.1875151E-04 0.1142091E+01 3.6493 6 HS- 0.3658425E-04 0.5686313E-04 0.1877169E+01 5.6044 7 Al+++ 0.1106886E-28 0.5268894E-05 0.1419050E+00 0.7609 8 H4SiO4 0.7116495E-03 0.1418218E-01 0.1360655E+04 -3.1477 9 Ca++ 0.1436811E-06 0.2439660E-06 0.9759949E-02 13.1065 10 Mg++ 0.2281513E-10 0.9803901E-10 0.2379205E-05 9.3053 11 Fe++ 0.6240863E-13 0.3786194E-07 0.2110644E-02 6.7428 12 K+ 0.1617187E-03 0.1624953E-03 0.6342378E+01 6.2505 13 Na+ 0.2056019E-01 0.2315186E-01 0.5312921E+03 8.3540 14 Mn++ 0.2002415E-10 0.2636027E-08 0.1445556E-03 9.2495 15 HPO4-- 0.4864800E-07 0.4989632E-07 0.4780320E-02 12.6395 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.4967552E+02 -.1609928E-01 -.4965942E+02 0.0000000E+00 2 H2O 0.1790203E+02 0.3868717E+02 -.2078514E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8316570E-01 -.1412973E-04 0.8317983E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8314020E-01 0.3963420E-04 -.8317983E-01 0.0000000E+00 7 Al+++ 0.9782222E+01 0.3672475E-05 0.9782218E+01 0.0000000E+00 8 H4SiO4 0.3123834E+02 0.9885127E-02 0.3122845E+02 0.0000000E+00 9 Ca++ 0.3450441E+01 0.1700469E-06 0.3450441E+01 0.0000000E+00 10 Mg++ 0.2380952E+01 0.6833423E-10 0.2380952E+01 0.0000000E+00 11 Fe++ 0.2139025E+01 0.2639018E-07 0.2139025E+01 0.0000000E+00 12 K+ 0.6369425E+00 0.1132610E-03 0.6368292E+00 0.0000000E+00 13 Na+ 0.3765890E+01 0.1613709E-01 0.3749753E+01 0.0000000E+00 14 Mn++ 0.5201577E-01 0.1837339E-08 0.5201577E-01 0.0000000E+00 15 HPO4-- 0.1775272E-01 0.3477826E-07 0.1775269E-01 0.0000000E+00 Chg. balance for solid moles: 0.7272E-14 Mass of aqueous solution: 0.698276E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 2999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.747 0.574 982.6 2.992 29.98 377.2 andradite 0.3327 -0.478 169.1 2.228 5.159 43.93 grossular 0.7944E-01 -1.100 35.79 1.554 1.092 9.957 apatite-OH 0.5918E-02 -2.228 2.973 0.473 0.9070E-01 0.9446 clinochlore 0.4280 -0.369 237.9 2.376 7.259 90.49 daphnite 0.1227 -0.911 87.52 1.942 2.670 26.52 chlorite-Mn 0.1040E-01 -1.983 7.376 0.868 0.2250 2.350 diopside 0.1640 -0.785 35.52 1.551 1.084 10.86 hedenbergite 0.4202E-01 -1.376 10.43 1.018 0.3181 2.856 microcline 0.5577 -0.254 155.2 2.191 4.736 60.63 stilbite 1.936 0.287 1364. 3.135 41.63 636.3 stilpnomelane-Fe 0.1583 -0.800 170.7 2.232 5.208 58.96 tr.625ac.25prg.125 0.2121E-01 -1.674 18.13 1.258 0.5531 5.834 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1854E-01 0.1854E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3277.450980 g Volume = 1326.833139 cm3 Porosity: -10.4774% V(tot) - V(min): -.12583E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 2999.9990000 g log = 3.4771 Original solution: 1000.0103000 g Original solution / Rock added: 0.33 (Water/Rock Ratio), log = -0.4771 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0947 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9615E+00 0.9849 0.1037E+01 0.1053E+01 CO2,gas 0.5372E-08 1.0070 0.5922E-08 0.5881E-08 CH4,gas 0.2493E-01 1.0127 0.2765E-01 0.2730E-01 H2,gas 0.1361E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1860E-06 0.9957 0.2028E-06 0.2036E-06 S2,gas 0.6329E-29 1.0000 0.6928E-29 0.6928E-29 CO,gas 0.2089E-13 1.0000 0.2287E-13 0.2287E-13 SO3,gas 0.1138E-47 1.0000 0.1246E-47 0.1246E-47 SO2,gas 0.6420E-27 1.0000 0.7028E-27 0.7028E-27 HCl,gas 0.3780E-17 1.0000 0.4138E-17 0.4138E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 -0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.59 -10.23 -3.409 0.17463E+05 -8.227 3 CH4,gas 4.81 1.25 -3.56 -0.890 0.60758E+04 -1.558 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.64 -8.69 -4.346 0.14843E+05 -6.693 6 S2,gas -7.03 -38.19 -31.16 -4.794 0.53204E+05 -29.159 7 CO,gas 3.51 -12.13 -15.64 -4.813 0.26706E+05 -13.641 8 SO3,gas 17.43 -32.48 -49.90 -12.476 0.85210E+05 -47.904 9 SO2,gas 1.14 -28.02 -29.15 -7.774 0.49778E+05 -27.153 10 HCl,gas 5.48 -13.90 -19.38 -9.692 0.33096E+05 -17.383 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80641E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94127E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76236E+04 35 aragonite 0.99 -3.48 -4.47 -1.490 0.76331E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.48 -4.32 -1.439 0.73717E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70379E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65562E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.67 -4.56 -1.304 0.77906E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66056E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.67 -4.12 -1.177 0.70368E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82273E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53670E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92775E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40699E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43448E+04 143 pyrrhotite -4.24 -7.89 -3.65 -1.216 0.62310E+04 144 pyrrhotiteFe0.875 -6.00 -9.29 -3.29 -1.209 0.56137E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22440E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28299E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23233E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47153E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91028E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.89 -3.50 -1.166 0.59742E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80432E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66782E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60330E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.39 -4.42 -1.475 0.75534E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 2999.9990000 g New total amount of reactant added: 3099.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3299E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3099.9990000 Water: Moles liquid = 0.3813E+02 kg liquid = 0.6870E+00 Moles total = 0.1665E+02 kg total = 0.2999E+00 Activity = 1.0000 Stoichiometric ionic strength = .1178101E-01 Osmotic coef. = 0.9684 True ionic strength = .2072517E-01 Chg. balance for total moles = 0.3299E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90434E-10 -10.0437 0.75862E-10 -10.1200 0.83886E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.19991E-03 -3.6992 0.16667E-03 -3.7781 0.83371E+00 -0.0790 4 SO4-- 0.11396E-11 -11.9432 0.58769E-12 -12.2309 0.51569E+00 -0.2876 5 HCO3- 0.41107E-06 -6.3861 0.34322E-06 -6.4644 0.83495E+00 -0.0783 6 HS- 0.37119E-04 -4.4304 0.30951E-04 -4.5093 0.83383E+00 -0.0789 7 Al+++ 0.11072E-28 -28.9558 0.25173E-29 -29.5991 0.22735E+00 -0.6433 8 H4SiO4 0.71165E-03 -3.1477 0.71165E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14371E-06 -6.8425 0.73552E-07 -7.1334 0.51181E+00 -0.2909 10 Mg++ 0.22819E-10 -10.6417 0.11625E-10 -10.9346 0.50942E+00 -0.2929 11 Fe++ 0.62421E-13 -13.2047 0.31834E-13 -13.4971 0.50999E+00 -0.2924 12 K+ 0.16173E-03 -3.7912 0.13507E-03 -3.8694 0.83515E+00 -0.0782 13 Na+ 0.20562E-01 -1.6869 0.17139E-01 -1.7660 0.83355E+00 -0.0791 14 Mn++ 0.20030E-10 -10.6983 0.10224E-10 -10.9904 0.51042E+00 -0.2921 15 HPO4-- 0.48641E-07 -7.3130 0.25087E-07 -7.6005 0.51576E+00 -0.2876 16 HSiO3- 0.10978E-01 -1.9595 0.91526E-02 -2.0385 0.83371E+00 -0.0790 17 Ca(HSiO3)+ 0.18056E-07 -7.7434 0.15083E-07 -7.8215 0.83533E+00 -0.0781 18 Mg(HSiO3)+ 0.35516E-11 -11.4496 0.29667E-11 -11.5277 0.83533E+00 -0.0781 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67599E-16 -16.1701 0.56468E-16 -16.2482 0.83533E+00 -0.0781 22 HAlO2,aq 0.14895E-09 -9.8270 0.14895E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52683E-05 -5.2783 0.43842E-05 -5.3581 0.83218E+00 -0.0798 24 CH4,aq 0.17801E-04 -4.7495 0.17737E-04 -4.7511 0.99641E+00 -0.0016 25 C2H6,aq 0.50093E-14 -14.3002 0.49914E-14 -14.3018 0.99641E+00 -0.0016 29 CO,aq 0.14697E-16 -16.8328 0.14697E-16 -16.8328 0.10000E+01 0.0000 30 CO2,aq 0.52686E-10 -10.2783 0.52497E-10 -10.2799 0.99641E+00 -0.0016 31 CO3-2 0.81294E-06 -6.0899 0.41831E-06 -6.3785 0.51457E+00 -0.2886 32 CaCO3,aq 0.37683E-09 -9.4239 0.37683E-09 -9.4239 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.76148E-12 -12.1183 0.63609E-12 -12.1965 0.83533E+00 -0.0781 34 CaCl+ 0.23385E-10 -10.6311 0.19534E-10 -10.7092 0.83533E+00 -0.0781 35 CaCl2,aq 0.75806E-15 -15.1203 0.75806E-15 -15.1203 0.10000E+01 0.0000 36 CaOH+ 0.81842E-07 -7.0870 0.68366E-07 -7.1652 0.83533E+00 -0.0781 37 CaSO4,aq 0.13468E-16 -16.8707 0.13468E-16 -16.8707 0.10000E+01 0.0000 38 HCl,aq 0.23783E-14 -14.6237 0.23783E-14 -14.6237 0.10000E+01 0.0000 43 FeCl+ 0.98928E-17 -17.0047 0.82638E-17 -17.0828 0.83533E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16654E-10 -10.7785 0.13912E-10 -10.8566 0.83533E+00 -0.0781 48 HFeO2- 0.37200E-07 -7.4295 0.31014E-07 -7.5084 0.83371E+00 -0.0790 49 FeO+ 0.12292E-16 -16.9104 0.10268E-16 -16.9885 0.83533E+00 -0.0781 51 FeO2- 0.42062E-09 -9.3761 0.35067E-09 -9.4551 0.83371E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99641E+00 -0.0016 54 KCl,aq 0.39861E-09 -9.3994 0.39861E-09 -9.3994 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.14669E-14 -14.8336 0.12230E-14 -14.9126 0.83371E+00 -0.0790 58 MgCO3,aq 0.14882E-13 -13.8273 0.14882E-13 -13.8273 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12273E-15 -15.9111 0.10252E-15 -15.9892 0.83533E+00 -0.0781 60 MgCl+ 0.33553E-14 -14.4743 0.28028E-14 -14.5524 0.83533E+00 -0.0781 61 MgOH+ 0.71661E-10 -10.1447 0.59861E-10 -10.2229 0.83533E+00 -0.0781 63 MnO,aq 0.18753E-08 -8.7269 0.18753E-08 -8.7269 0.10000E+01 0.0000 64 MnOH+ 0.49687E-09 -9.3038 0.41505E-09 -9.3819 0.83533E+00 -0.0781 65 MnO2-2 0.21901E-10 -10.6595 0.11269E-10 -10.9481 0.51457E+00 -0.2886 66 HMnO2- 0.22217E-09 -9.6533 0.18523E-09 -9.7323 0.83371E+00 -0.0790 69 MnCl+ 0.12346E-13 -13.9085 0.10313E-13 -13.9866 0.83533E+00 -0.0781 71 NaCl,aq 0.93276E-06 -6.0302 0.93276E-06 -6.0302 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95015E-02 -2.0222 0.79069E-02 -2.1020 0.83218E+00 -0.0798 79 HPO3-2 0.16739E-14 -14.7763 0.86135E-15 -15.0648 0.51457E+00 -0.2886 81 H2PO3- 0.15396E-18 -18.8126 0.12836E-18 -18.8916 0.83371E+00 -0.0790 82 H3PO4,aq 0.92950E-18 -18.0318 0.92950E-18 -18.0318 0.10000E+01 0.0000 83 H2PO4- 0.39983E-10 -10.3981 0.33366E-10 -10.4767 0.83451E+00 -0.0786 84 PO4-3 0.12081E-08 -8.9179 0.28880E-09 -9.5394 0.23905E+00 -0.6215 88 HP2O7-3 0.10348E-17 -17.9851 0.23552E-18 -18.6280 0.22759E+00 -0.6428 89 P2O7-4 0.10213E-16 -16.9908 0.76590E-18 -18.1158 0.74991E-01 -1.1250 90 H2S,aq 0.70802E-08 -8.1500 0.70548E-08 -8.1515 0.99641E+00 -0.0016 91 S2-2 0.37668E-14 -14.4240 0.19383E-14 -14.7126 0.51457E+00 -0.2886 97 SO3-2 0.16681E-17 -17.7778 0.87104E-18 -18.0600 0.52218E+00 -0.2822 99 HSO4- 0.49472E-19 -19.3056 0.41367E-19 -19.3833 0.83617E+00 -0.0777 Charge balance for all species = 0.4799E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9043425E-10 -.2309604E-01 -.2323724E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981166E+06 0.0000 3 Cl- 0.1999132E-03 0.2008463E-03 0.7107701E+01 6.3418 4 SO4-- 0.1139621E-11 -.2052861E-04 -.1968438E+01 8.0091 5 HCO3- 0.4110684E-06 0.1902575E-04 0.1158794E+01 3.6555 6 HS- 0.3711928E-04 0.5765498E-04 0.1903310E+01 5.6107 7 Al+++ 0.1107221E-28 0.5268466E-05 0.1418935E+00 0.7609 8 H4SiO4 0.7116503E-03 0.1418134E-01 0.1360575E+04 -3.1477 9 Ca++ 0.1437086E-06 0.2440081E-06 0.9761633E-02 13.1065 10 Mg++ 0.2281949E-10 0.9805062E-10 0.2379486E-05 9.3053 11 Fe++ 0.6242061E-13 0.3785900E-07 0.2110480E-02 6.7428 12 K+ 0.1617333E-03 0.1625099E-03 0.6342945E+01 6.2505 13 Na+ 0.2056204E-01 0.2315373E-01 0.5313349E+03 8.3540 14 Mn++ 0.2003000E-10 0.2636319E-08 0.1445716E-03 9.2496 15 HPO4-- 0.4864109E-07 0.4988917E-07 0.4779635E-02 12.6394 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5133137E+02 -.1586615E-01 -.5131550E+02 0.0000000E+00 2 H2O 0.1664849E+02 0.3812953E+02 -.2148104E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8593704E-01 -.1410242E-04 0.8595115E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8591154E-01 0.3960689E-04 -.8595115E-01 0.0000000E+00 7 Al+++ 0.1010830E+02 0.3619245E-05 0.1010829E+02 0.0000000E+00 8 H4SiO4 0.3227962E+02 0.9742067E-02 0.3226987E+02 0.0000000E+00 9 Ca++ 0.3565456E+01 0.1676247E-06 0.3565455E+01 0.0000000E+00 10 Mg++ 0.2460317E+01 0.6735723E-10 0.2460317E+01 0.0000000E+00 11 Fe++ 0.2210326E+01 0.2600777E-07 0.2210326E+01 0.0000000E+00 12 K+ 0.6581739E+00 0.1116384E-03 0.6580622E+00 0.0000000E+00 13 Na+ 0.3891414E+01 0.1590577E-01 0.3875508E+01 0.0000000E+00 14 Mn++ 0.5374963E-01 0.1811056E-08 0.5374963E-01 0.0000000E+00 15 HPO4-- 0.1834448E-01 0.3427206E-07 0.1834445E-01 0.0000000E+00 Chg. balance for solid moles: -.9021E-14 Mass of aqueous solution: 0.688211E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3099.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.873 0.588 1016. 3.007 29.99 389.8 andradite 0.3438 -0.464 174.7 2.242 5.159 45.39 grossular 0.8209E-01 -1.086 36.98 1.568 1.092 10.29 apatite-OH 0.6115E-02 -2.214 3.072 0.487 0.9070E-01 0.9760 clinochlore 0.4422 -0.354 245.8 2.391 7.258 93.50 daphnite 0.1267 -0.897 90.43 1.956 2.670 27.40 chlorite-Mn 0.1075E-01 -1.969 7.621 0.882 0.2250 2.429 diopside 0.1698 -0.770 36.78 1.566 1.086 11.24 hedenbergite 0.4351E-01 -1.361 10.79 1.033 0.3187 2.956 microcline 0.5762 -0.239 160.4 2.205 4.736 62.65 stilbite 2.000 0.301 1410. 3.149 41.62 657.4 stilpnomelane-Fe 0.1636 -0.786 176.4 2.246 5.208 60.93 tr.625ac.25prg.125 0.2189E-01 -1.660 18.71 1.272 0.5525 6.022 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1854E-01 0.1854E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3386.706462 g Volume = 1371.039497 cm3 Porosity: -10.4786% V(tot) - V(min): -.13004E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3099.9990000 g log = 3.4914 Original solution: 1000.0103000 g Original solution / Rock added: 0.32 (Water/Rock Ratio), log = -0.4914 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0952 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9611E+00 0.9849 0.1037E+01 0.1053E+01 CO2,gas 0.5449E-08 1.0070 0.6009E-08 0.5967E-08 CH4,gas 0.2529E-01 1.0127 0.2805E-01 0.2770E-01 H2,gas 0.1361E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1887E-06 0.9957 0.2058E-06 0.2066E-06 S2,gas 0.6514E-29 1.0000 0.7133E-29 0.7133E-29 CO,gas 0.2119E-13 1.0000 0.2321E-13 0.2321E-13 SO3,gas 0.1155E-47 1.0000 0.1264E-47 0.1264E-47 SO2,gas 0.6512E-27 1.0000 0.7132E-27 0.7132E-27 HCl,gas 0.3834E-17 1.0000 0.4199E-17 0.4199E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.58 -10.22 -3.407 0.17452E+05 -8.221 3 CH4,gas 4.81 1.26 -3.55 -0.888 0.60651E+04 -1.552 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.63 -8.69 -4.343 0.14832E+05 -6.687 6 S2,gas -7.03 -38.18 -31.15 -4.792 0.53182E+05 -29.147 7 CO,gas 3.51 -12.12 -15.63 -4.811 0.26695E+05 -13.634 8 SO3,gas 17.43 -32.47 -49.90 -12.475 0.85200E+05 -47.898 9 SO2,gas 1.14 -28.01 -29.15 -7.772 0.49767E+05 -27.147 10 HCl,gas 5.48 -13.90 -19.38 -9.688 0.33085E+05 -17.377 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80638E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94127E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76236E+04 35 aragonite 0.99 -3.48 -4.46 -1.488 0.76223E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.48 -4.31 -1.437 0.73610E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70379E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65561E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.66 -4.56 -1.302 0.77798E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66056E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.66 -4.11 -1.176 0.70260E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82273E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53670E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92775E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40699E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43448E+04 143 pyrrhotite -4.24 -7.89 -3.64 -1.214 0.62201E+04 144 pyrrhotiteFe0.875 -6.00 -9.28 -3.28 -1.207 0.56029E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22440E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28299E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23232E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.395 0.47152E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91028E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.89 -3.49 -1.164 0.59633E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80432E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66782E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60330E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60309E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.38 -4.42 -1.472 0.75425E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3099.9990000 g New total amount of reactant added: 3199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3300E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3199.9990000 Water: Moles liquid = 0.3757E+02 kg liquid = 0.6769E+00 Moles total = 0.1539E+02 kg total = 0.2773E+00 Activity = 1.0000 Stoichiometric ionic strength = .1178349E-01 Osmotic coef. = 0.9684 True ionic strength = .2072710E-01 Chg. balance for total moles = 0.3300E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90443E-10 -10.0436 0.75869E-10 -10.1199 0.83886E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.20288E-03 -3.6928 0.16914E-03 -3.7717 0.83370E+00 -0.0790 4 SO4-- 0.11565E-11 -11.9369 0.59636E-12 -12.2245 0.51567E+00 -0.2876 5 HCO3- 0.41714E-06 -6.3797 0.34829E-06 -6.4581 0.83495E+00 -0.0783 6 HS- 0.37670E-04 -4.4240 0.31410E-04 -4.5029 0.83383E+00 -0.0789 7 Al+++ 0.11076E-28 -28.9556 0.25180E-29 -29.5990 0.22734E+00 -0.6433 8 H4SiO4 0.71165E-03 -3.1477 0.71165E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14374E-06 -6.8424 0.73565E-07 -7.1333 0.51180E+00 -0.2909 10 Mg++ 0.22824E-10 -10.6416 0.11627E-10 -10.9345 0.50941E+00 -0.2929 11 Fe++ 0.62433E-13 -13.2046 0.31840E-13 -13.4970 0.50998E+00 -0.2924 12 K+ 0.16175E-03 -3.7912 0.13508E-03 -3.8694 0.83515E+00 -0.0782 13 Na+ 0.20564E-01 -1.6869 0.17141E-01 -1.7660 0.83354E+00 -0.0791 14 Mn++ 0.20036E-10 -10.6982 0.10227E-10 -10.9903 0.51041E+00 -0.2921 15 HPO4-- 0.48634E-07 -7.3131 0.25083E-07 -7.6006 0.51575E+00 -0.2876 16 HSiO3- 0.10977E-01 -1.9595 0.91518E-02 -2.0385 0.83370E+00 -0.0790 17 Ca(HSiO3)+ 0.18058E-07 -7.7433 0.15084E-07 -7.8215 0.83533E+00 -0.0781 18 Mg(HSiO3)+ 0.35519E-11 -11.4495 0.29670E-11 -11.5277 0.83533E+00 -0.0781 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67605E-16 -16.1700 0.56473E-16 -16.2482 0.83533E+00 -0.0781 22 HAlO2,aq 0.14895E-09 -9.8270 0.14895E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52679E-05 -5.2784 0.43838E-05 -5.3582 0.83217E+00 -0.0798 24 CH4,aq 0.18066E-04 -4.7431 0.18001E-04 -4.7447 0.99641E+00 -0.0016 25 C2H6,aq 0.51592E-14 -14.2874 0.51407E-14 -14.2890 0.99641E+00 -0.0016 29 CO,aq 0.14916E-16 -16.8264 0.14916E-16 -16.8264 0.10000E+01 0.0000 30 CO2,aq 0.53469E-10 -10.2719 0.53277E-10 -10.2735 0.99641E+00 -0.0016 31 CO3-2 0.82490E-06 -6.0836 0.42446E-06 -6.3722 0.51456E+00 -0.2886 32 CaCO3,aq 0.38243E-09 -9.4174 0.38243E-09 -9.4174 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.77287E-12 -12.1119 0.64560E-12 -12.1900 0.83533E+00 -0.0781 34 CaCl+ 0.23736E-10 -10.6246 0.19828E-10 -10.7027 0.83533E+00 -0.0781 35 CaCl2,aq 0.78085E-15 -15.1074 0.78085E-15 -15.1074 0.10000E+01 0.0000 36 CaOH+ 0.81850E-07 -7.0870 0.68371E-07 -7.1651 0.83533E+00 -0.0781 37 CaSO4,aq 0.13669E-16 -16.8643 0.13669E-16 -16.8643 0.10000E+01 0.0000 38 HCl,aq 0.24138E-14 -14.6173 0.24138E-14 -14.6173 0.10000E+01 0.0000 43 FeCl+ 0.10041E-16 -16.9982 0.83878E-17 -17.0764 0.83533E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16656E-10 -10.7784 0.13913E-10 -10.8566 0.83533E+00 -0.0781 48 HFeO2- 0.37197E-07 -7.4295 0.31011E-07 -7.5085 0.83370E+00 -0.0790 49 FeO+ 0.12293E-16 -16.9103 0.10269E-16 -16.9885 0.83533E+00 -0.0781 51 FeO2- 0.42058E-09 -9.3761 0.35064E-09 -9.4551 0.83370E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99641E+00 -0.0016 54 KCl,aq 0.40456E-09 -9.3930 0.40456E-09 -9.3930 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.14887E-14 -14.8272 0.12411E-14 -14.9062 0.83370E+00 -0.0790 58 MgCO3,aq 0.15103E-13 -13.8209 0.15103E-13 -13.8209 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12456E-15 -15.9046 0.10405E-15 -15.9828 0.83533E+00 -0.0781 60 MgCl+ 0.34057E-14 -14.4678 0.28448E-14 -14.5459 0.83533E+00 -0.0781 61 MgOH+ 0.71667E-10 -10.1447 0.59866E-10 -10.2228 0.83533E+00 -0.0781 63 MnO,aq 0.18755E-08 -8.7269 0.18755E-08 -8.7269 0.10000E+01 0.0000 64 MnOH+ 0.49696E-09 -9.3037 0.41513E-09 -9.3818 0.83533E+00 -0.0781 65 MnO2-2 0.21899E-10 -10.6596 0.11268E-10 -10.9481 0.51456E+00 -0.2886 66 HMnO2- 0.22218E-09 -9.6533 0.18523E-09 -9.7323 0.83370E+00 -0.0790 69 MnCl+ 0.12532E-13 -13.9020 0.10469E-13 -13.9801 0.83533E+00 -0.0781 71 NaCl,aq 0.94668E-06 -6.0238 0.94668E-06 -6.0238 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95007E-02 -2.0222 0.79062E-02 -2.1020 0.83217E+00 -0.0798 79 HPO3-2 0.16737E-14 -14.7763 0.86120E-15 -15.0649 0.51456E+00 -0.2886 81 H2PO3- 0.15395E-18 -18.8126 0.12835E-18 -18.8916 0.83370E+00 -0.0790 82 H3PO4,aq 0.92950E-18 -18.0317 0.92950E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39980E-10 -10.3982 0.33364E-10 -10.4767 0.83451E+00 -0.0786 84 PO4-3 0.12078E-08 -8.9180 0.28873E-09 -9.5395 0.23904E+00 -0.6215 88 HP2O7-3 0.10346E-17 -17.9852 0.23546E-18 -18.6281 0.22758E+00 -0.6429 89 P2O7-4 0.10211E-16 -16.9909 0.76563E-18 -18.1160 0.74983E-01 -1.1250 90 H2S,aq 0.71859E-08 -8.1435 0.71601E-08 -8.1451 0.99641E+00 -0.0016 91 S2-2 0.38795E-14 -14.4112 0.19962E-14 -14.6998 0.51456E+00 -0.2886 97 SO3-2 0.16928E-17 -17.7714 0.88390E-18 -18.0536 0.52216E+00 -0.2822 99 HSO4- 0.50207E-19 -19.2992 0.41981E-19 -19.3769 0.83616E+00 -0.0777 Charge balance for all species = 0.4876E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9044260E-10 -.2309443E-01 -.2323561E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981165E+06 0.0000 3 Cl- 0.2028802E-03 0.2038273E-03 0.7213191E+01 6.3482 4 SO4-- 0.1156469E-11 -.2079295E-04 -.1993784E+01 8.0154 5 HCO3- 0.4171431E-06 0.1930812E-04 0.1175992E+01 3.6619 6 HS- 0.3767020E-04 0.5847034E-04 0.1930226E+01 5.6170 7 Al+++ 0.1107567E-28 0.5268027E-05 0.1418816E+00 0.7609 8 H4SiO4 0.7116511E-03 0.1418048E-01 0.1360492E+04 -3.1477 9 Ca++ 0.1437368E-06 0.2440515E-06 0.9763368E-02 13.1065 10 Mg++ 0.2282398E-10 0.9806191E-10 0.2379760E-05 9.3053 11 Fe++ 0.6243296E-13 0.3785597E-07 0.2110311E-02 6.7428 12 K+ 0.1617482E-03 0.1625249E-03 0.6343529E+01 6.2505 13 Na+ 0.2056394E-01 0.2315565E-01 0.5313789E+03 8.3540 14 Mn++ 0.2003585E-10 0.2636595E-08 0.1445867E-03 9.2496 15 HPO4-- 0.4863398E-07 0.4988180E-07 0.4778929E-02 12.6393 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5298722E+02 -.1563301E-01 -.5297159E+02 0.0000000E+00 2 H2O 0.1539495E+02 0.3757190E+02 -.2217695E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.8870839E-01 -.1407510E-04 0.8872246E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.8868288E-01 0.3957957E-04 -.8872246E-01 0.0000000E+00 7 Al+++ 0.1043437E+02 0.3566018E-05 0.1043437E+02 0.0000000E+00 8 H4SiO4 0.3332090E+02 0.9599007E-02 0.3331130E+02 0.0000000E+00 9 Ca++ 0.3680470E+01 0.1652026E-06 0.3680470E+01 0.0000000E+00 10 Mg++ 0.2539682E+01 0.6637979E-10 0.2539682E+01 0.0000000E+00 11 Fe++ 0.2281627E+01 0.2562536E-07 0.2281627E+01 0.0000000E+00 12 K+ 0.6794053E+00 0.1100159E-03 0.6792953E+00 0.0000000E+00 13 Na+ 0.4016938E+01 0.1567446E-01 0.4001264E+01 0.0000000E+00 14 Mn++ 0.5548349E-01 0.1784757E-08 0.5548349E-01 0.0000000E+00 15 HPO4-- 0.1893624E-01 0.3376585E-07 0.1893621E-01 0.0000000E+00 Chg. balance for solid moles: 0.2678E-14 Mass of aqueous solution: 0.678146E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 3.998 0.602 1048. 3.021 29.99 402.5 andradite 0.3549 -0.450 180.3 2.256 5.159 46.86 grossular 0.8474E-01 -1.072 38.17 1.582 1.092 10.62 apatite-OH 0.6312E-02 -2.200 3.171 0.501 0.9070E-01 1.008 clinochlore 0.4565 -0.341 253.7 2.404 7.257 96.50 daphnite 0.1308 -0.883 93.34 1.970 2.670 28.28 chlorite-Mn 0.1110E-01 -1.955 7.867 0.896 0.2250 2.507 diopside 0.1756 -0.755 38.03 1.580 1.088 11.62 hedenbergite 0.4499E-01 -1.347 11.16 1.048 0.3193 3.057 microcline 0.5948 -0.226 165.6 2.219 4.736 64.67 stilbite 2.064 0.315 1455. 3.163 41.61 678.5 stilpnomelane-Fe 0.1689 -0.772 182.1 2.260 5.208 62.90 tr.625ac.25prg.125 0.2257E-01 -1.646 19.29 1.285 0.5518 6.209 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1854E-01 0.1854E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3495.961944 g Volume = 1415.245854 cm3 Porosity: -10.4798% V(tot) - V(min): -.13425E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3199.9990000 g log = 3.5051 Original solution: 1000.0103000 g Original solution / Rock added: 0.31 (Water/Rock Ratio), log = -0.5051 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0956 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9607E+00 0.9849 0.1037E+01 0.1053E+01 CO2,gas 0.5528E-08 1.0070 0.6098E-08 0.6056E-08 CH4,gas 0.2566E-01 1.0127 0.2847E-01 0.2811E-01 H2,gas 0.1360E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1914E-06 0.9957 0.2088E-06 0.2097E-06 S2,gas 0.6707E-29 1.0000 0.7348E-29 0.7348E-29 CO,gas 0.2150E-13 1.0000 0.2355E-13 0.2355E-13 SO3,gas 0.1171E-47 1.0000 0.1283E-47 0.1283E-47 SO2,gas 0.6607E-27 1.0000 0.7238E-27 0.7238E-27 HCl,gas 0.3890E-17 1.0000 0.4262E-17 0.4262E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.58 -10.21 -3.405 0.17441E+05 -8.215 3 CH4,gas 4.81 1.26 -3.55 -0.886 0.60541E+04 -1.546 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.62 -8.68 -4.340 0.14821E+05 -6.680 6 S2,gas -7.03 -38.17 -31.13 -4.790 0.53160E+05 -29.134 7 CO,gas 3.51 -12.12 -15.63 -4.809 0.26684E+05 -13.628 8 SO3,gas 17.43 -32.46 -49.89 -12.473 0.85189E+05 -47.892 9 SO2,gas 1.14 -28.00 -29.14 -7.771 0.49756E+05 -27.140 10 HCl,gas 5.48 -13.89 -19.37 -9.685 0.33074E+05 -17.370 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80636E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94127E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76236E+04 35 aragonite 0.99 -3.47 -4.46 -1.486 0.76114E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.47 -4.30 -1.435 0.73500E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70379E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65560E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.66 -4.55 -1.300 0.77689E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66056E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.66 -4.11 -1.174 0.70151E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82272E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53670E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92775E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40700E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43448E+04 143 pyrrhotite -4.24 -7.88 -3.64 -1.212 0.62092E+04 144 pyrrhotiteFe0.875 -6.00 -9.28 -3.27 -1.204 0.55919E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22439E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28299E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23231E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47151E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91028E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.88 -3.49 -1.162 0.59523E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80432E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66782E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60330E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.37 -4.41 -1.470 0.75314E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3199.9990000 g New total amount of reactant added: 3299.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3299E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3299.9990000 Water: Moles liquid = 0.3702E+02 kg liquid = 0.6669E+00 Moles total = 0.1414E+02 kg total = 0.2548E+00 Activity = 1.0000 Stoichiometric ionic strength = .1178604E-01 Osmotic coef. = 0.9684 True ionic strength = .2072909E-01 Chg. balance for total moles = 0.3299E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90451E-10 -10.0436 0.75875E-10 -10.1199 0.83885E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.20594E-03 -3.6863 0.17169E-03 -3.7653 0.83370E+00 -0.0790 4 SO4-- 0.11738E-11 -11.9304 0.60529E-12 -12.2180 0.51566E+00 -0.2876 5 HCO3- 0.42340E-06 -6.3732 0.35351E-06 -6.4516 0.83494E+00 -0.0783 6 HS- 0.38238E-04 -4.4175 0.31883E-04 -4.4964 0.83382E+00 -0.0789 7 Al+++ 0.11079E-28 -28.9555 0.25186E-29 -29.5988 0.22733E+00 -0.6433 8 H4SiO4 0.71165E-03 -3.1477 0.71165E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14377E-06 -6.8423 0.73578E-07 -7.1333 0.51179E+00 -0.2909 10 Mg++ 0.22829E-10 -10.6415 0.11629E-10 -10.9345 0.50940E+00 -0.2929 11 Fe++ 0.62446E-13 -13.2045 0.31845E-13 -13.4970 0.50997E+00 -0.2925 12 K+ 0.16176E-03 -3.7911 0.13510E-03 -3.8694 0.83514E+00 -0.0782 13 Na+ 0.20566E-01 -1.6869 0.17142E-01 -1.7659 0.83354E+00 -0.0791 14 Mn++ 0.20042E-10 -10.6981 0.10229E-10 -10.9902 0.51040E+00 -0.2921 15 HPO4-- 0.48627E-07 -7.3131 0.25079E-07 -7.6007 0.51574E+00 -0.2876 16 HSiO3- 0.10976E-01 -1.9595 0.91510E-02 -2.0385 0.83370E+00 -0.0790 17 Ca(HSiO3)+ 0.18060E-07 -7.7433 0.15086E-07 -7.8214 0.83532E+00 -0.0781 18 Mg(HSiO3)+ 0.35522E-11 -11.4495 0.29673E-11 -11.5276 0.83532E+00 -0.0781 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67611E-16 -16.1700 0.56477E-16 -16.2481 0.83532E+00 -0.0781 22 HAlO2,aq 0.14895E-09 -9.8270 0.14895E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52674E-05 -5.2784 0.43834E-05 -5.3582 0.83216E+00 -0.0798 24 CH4,aq 0.18338E-04 -4.7366 0.18272E-04 -4.7382 0.99641E+00 -0.0016 25 C2H6,aq 0.53159E-14 -14.2744 0.52968E-14 -14.2760 0.99641E+00 -0.0016 29 CO,aq 0.15141E-16 -16.8199 0.15141E-16 -16.8199 0.10000E+01 0.0000 30 CO2,aq 0.54275E-10 -10.2654 0.54080E-10 -10.2670 0.99641E+00 -0.0016 31 CO3-2 0.83721E-06 -6.0772 0.43078E-06 -6.3657 0.51454E+00 -0.2886 32 CaCO3,aq 0.38820E-09 -9.4109 0.38820E-09 -9.4109 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.78460E-12 -12.1054 0.65539E-12 -12.1835 0.83532E+00 -0.0781 34 CaCl+ 0.24098E-10 -10.6180 0.20130E-10 -10.6962 0.83532E+00 -0.0781 35 CaCl2,aq 0.80469E-15 -15.0944 0.80469E-15 -15.0944 0.10000E+01 0.0000 36 CaOH+ 0.81857E-07 -7.0869 0.68377E-07 -7.1651 0.83532E+00 -0.0781 37 CaSO4,aq 0.13876E-16 -16.8577 0.13876E-16 -16.8577 0.10000E+01 0.0000 38 HCl,aq 0.24503E-14 -14.6108 0.24503E-14 -14.6108 0.10000E+01 0.0000 43 FeCl+ 0.10194E-16 -16.9916 0.85156E-17 -17.0698 0.83532E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16657E-10 -10.7784 0.13914E-10 -10.8565 0.83532E+00 -0.0781 48 HFeO2- 0.37194E-07 -7.4295 0.31008E-07 -7.5085 0.83370E+00 -0.0790 49 FeO+ 0.12295E-16 -16.9103 0.10270E-16 -16.9884 0.83532E+00 -0.0781 51 FeO2- 0.42055E-09 -9.3762 0.35061E-09 -9.4552 0.83370E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99641E+00 -0.0016 54 KCl,aq 0.41069E-09 -9.3865 0.41069E-09 -9.3865 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.15111E-14 -14.8207 0.12598E-14 -14.8997 0.83370E+00 -0.0790 58 MgCO3,aq 0.15331E-13 -13.8144 0.15331E-13 -13.8144 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12645E-15 -15.8981 0.10563E-15 -15.9762 0.83532E+00 -0.0781 60 MgCl+ 0.34576E-14 -14.4612 0.28882E-14 -14.5394 0.83532E+00 -0.0781 61 MgOH+ 0.71674E-10 -10.1446 0.59871E-10 -10.2228 0.83532E+00 -0.0781 63 MnO,aq 0.18757E-08 -8.7268 0.18757E-08 -8.7268 0.10000E+01 0.0000 64 MnOH+ 0.49705E-09 -9.3036 0.41520E-09 -9.3817 0.83532E+00 -0.0781 65 MnO2-2 0.21898E-10 -10.6596 0.11267E-10 -10.9482 0.51454E+00 -0.2886 66 HMnO2- 0.22218E-09 -9.6533 0.18523E-09 -9.7323 0.83370E+00 -0.0790 69 MnCl+ 0.12725E-13 -13.8954 0.10629E-13 -13.9735 0.83532E+00 -0.0781 71 NaCl,aq 0.96102E-06 -6.0173 0.96102E-06 -6.0173 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.95000E-02 -2.0223 0.79055E-02 -2.1021 0.83216E+00 -0.0798 79 HPO3-2 0.16734E-14 -14.7764 0.86105E-15 -15.0650 0.51454E+00 -0.2886 81 H2PO3- 0.15393E-18 -18.8127 0.12833E-18 -18.8917 0.83370E+00 -0.0790 82 H3PO4,aq 0.92950E-18 -18.0317 0.92950E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39977E-10 -10.3982 0.33361E-10 -10.4768 0.83450E+00 -0.0786 84 PO4-3 0.12076E-08 -8.9181 0.28865E-09 -9.5396 0.23903E+00 -0.6216 88 HP2O7-3 0.10344E-17 -17.9853 0.23540E-18 -18.6282 0.22757E+00 -0.6429 89 P2O7-4 0.10208E-16 -16.9911 0.76537E-18 -18.1161 0.74976E-01 -1.1251 90 H2S,aq 0.72947E-08 -8.1370 0.72685E-08 -8.1386 0.99641E+00 -0.0016 91 S2-2 0.39973E-14 -14.3982 0.20568E-14 -14.6868 0.51454E+00 -0.2886 97 SO3-2 0.17182E-17 -17.7649 0.89713E-18 -18.0471 0.52215E+00 -0.2822 99 HSO4- 0.50964E-19 -19.2927 0.42614E-19 -19.3705 0.83616E+00 -0.0777 Charge balance for all species = 0.4949E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9045119E-10 -.2309277E-01 -.2323393E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981164E+06 0.0000 3 Cl- 0.2059366E-03 0.2068980E-03 0.7321861E+01 6.3546 4 SO4-- 0.1173820E-11 -.2106525E-04 -.2019894E+01 8.0218 5 HCO3- 0.4233996E-06 0.1959901E-04 0.1193709E+01 3.6683 6 HS- 0.3823772E-04 0.5931027E-04 0.1957954E+01 5.6235 7 Al+++ 0.1107923E-28 0.5267576E-05 0.1418695E+00 0.7609 8 H4SiO4 0.7116519E-03 0.1417959E-01 0.1360406E+04 -3.1477 9 Ca++ 0.1437660E-06 0.2440962E-06 0.9765156E-02 13.1065 10 Mg++ 0.2282862E-10 0.9807355E-10 0.2380042E-05 9.3053 11 Fe++ 0.6244567E-13 0.3785286E-07 0.2110137E-02 6.7428 12 K+ 0.1617637E-03 0.1625403E-03 0.6344130E+01 6.2505 13 Na+ 0.2056591E-01 0.2315763E-01 0.5314243E+03 8.3540 14 Mn++ 0.2004170E-10 0.2636858E-08 0.1446011E-03 9.2496 15 HPO4-- 0.4862664E-07 0.4987421E-07 0.4778201E-02 12.6391 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5464307E+02 -.1539988E-01 -.5462767E+02 0.0000000E+00 2 H2O 0.1414141E+02 0.3701426E+02 -.2287285E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9147973E-01 -.1404779E-04 0.9149377E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9145422E-01 0.3955226E-04 -.9149377E-01 0.0000000E+00 7 Al+++ 0.1076044E+02 0.3512791E-05 0.1076044E+02 0.0000000E+00 8 H4SiO4 0.3436217E+02 0.9455946E-02 0.3435272E+02 0.0000000E+00 9 Ca++ 0.3795484E+01 0.1627805E-06 0.3795484E+01 0.0000000E+00 10 Mg++ 0.2619047E+01 0.6540235E-10 0.2619047E+01 0.0000000E+00 11 Fe++ 0.2352928E+01 0.2524295E-07 0.2352928E+01 0.0000000E+00 12 K+ 0.7006367E+00 0.1083933E-03 0.7005283E+00 0.0000000E+00 13 Na+ 0.4142463E+01 0.1544314E-01 0.4127020E+01 0.0000000E+00 14 Mn++ 0.5721735E-01 0.1758442E-08 0.5721735E-01 0.0000000E+00 15 HPO4-- 0.1952800E-01 0.3325964E-07 0.1952796E-01 0.0000000E+00 Chg. balance for solid moles: 0.1010E-13 Mass of aqueous solution: 0.668081E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3299.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.124 0.615 1081. 3.034 30.00 415.1 andradite 0.3660 -0.437 186.0 2.269 5.159 48.32 grossular 0.8738E-01 -1.059 39.36 1.595 1.092 10.95 apatite-OH 0.6509E-02 -2.186 3.270 0.515 0.9070E-01 1.039 clinochlore 0.4707 -0.327 261.6 2.418 7.257 99.51 daphnite 0.1349 -0.870 96.25 1.983 2.670 29.17 chlorite-Mn 0.1144E-01 -1.941 8.113 0.909 0.2250 2.585 diopside 0.1814 -0.741 39.28 1.594 1.090 12.01 hedenbergite 0.4647E-01 -1.333 11.53 1.062 0.3198 3.158 microcline 0.6134 -0.212 170.7 2.232 4.736 66.70 stilbite 2.129 0.328 1500. 3.176 41.61 699.6 stilpnomelane-Fe 0.1742 -0.759 187.8 2.274 5.209 64.86 tr.625ac.25prg.125 0.2325E-01 -1.634 19.87 1.298 0.5513 6.397 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1855E-01 0.1855E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3605.217426 g Volume = 1459.452211 cm3 Porosity: -10.4809% V(tot) - V(min): -.13845E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3299.9990000 g log = 3.5185 Original solution: 1000.0103000 g Original solution / Rock added: 0.30 (Water/Rock Ratio), log = -0.5185 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0960 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9604E+00 0.9849 0.1037E+01 0.1053E+01 CO2,gas 0.5609E-08 1.0070 0.6190E-08 0.6147E-08 CH4,gas 0.2603E-01 1.0127 0.2890E-01 0.2853E-01 H2,gas 0.1360E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1942E-06 0.9957 0.2120E-06 0.2129E-06 S2,gas 0.6909E-29 1.0000 0.7572E-29 0.7572E-29 CO,gas 0.2181E-13 1.0000 0.2391E-13 0.2391E-13 SO3,gas 0.1189E-47 1.0000 0.1303E-47 0.1303E-47 SO2,gas 0.6704E-27 1.0000 0.7348E-27 0.7348E-27 HCl,gas 0.3948E-17 1.0000 0.4327E-17 0.4327E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.97059E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.57 -10.21 -3.403 0.17430E+05 -8.208 3 CH4,gas 4.81 1.27 -3.54 -0.885 0.60430E+04 -1.539 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.62 -8.67 -4.337 0.14810E+05 -6.674 6 S2,gas -7.03 -38.15 -31.12 -4.788 0.53138E+05 -29.121 7 CO,gas 3.51 -12.11 -15.62 -4.807 0.26673E+05 -13.621 8 SO3,gas 17.43 -32.46 -49.89 -12.471 0.85178E+05 -47.885 9 SO2,gas 1.14 -28.00 -29.13 -7.769 0.49745E+05 -27.134 10 HCl,gas 5.48 -13.89 -19.36 -9.682 0.33063E+05 -17.364 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80634E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94127E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76236E+04 35 aragonite 0.99 -3.46 -4.45 -1.484 0.76003E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.46 -4.30 -1.433 0.73389E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70379E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65560E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.65 -4.54 -1.298 0.77578E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66056E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.65 -4.10 -1.172 0.70040E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16002E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82271E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53670E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41167E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92775E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40700E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43449E+04 143 pyrrhotite -4.24 -7.87 -3.63 -1.210 0.61980E+04 144 pyrrhotiteFe0.875 -6.00 -9.27 -3.27 -1.202 0.55808E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22438E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28299E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23231E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47149E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91028E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.87 -3.48 -1.160 0.59412E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80433E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66782E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60330E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.37 -4.40 -1.468 0.75202E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3299.9990000 g New total amount of reactant added: 3399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3300E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3399.9990000 Water: Moles liquid = 0.3646E+02 kg liquid = 0.6568E+00 Moles total = 0.1289E+02 kg total = 0.2322E+00 Activity = 1.0000 Stoichiometric ionic strength = .1178867E-01 Osmotic coef. = 0.9684 True ionic strength = .2073114E-01 Chg. balance for total moles = 0.3300E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90460E-10 -10.0435 0.75882E-10 -10.1199 0.83885E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.20909E-03 -3.6797 0.17431E-03 -3.7587 0.83369E+00 -0.0790 4 SO4-- 0.11917E-11 -11.9238 0.61450E-12 -12.2115 0.51565E+00 -0.2876 5 HCO3- 0.42985E-06 -6.3667 0.35889E-06 -6.4450 0.83493E+00 -0.0783 6 HS- 0.38823E-04 -4.4109 0.32371E-04 -4.4898 0.83381E+00 -0.0789 7 Al+++ 0.11083E-28 -28.9553 0.25193E-29 -29.5987 0.22731E+00 -0.6434 8 H4SiO4 0.71165E-03 -3.1477 0.71165E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14380E-06 -6.8423 0.73591E-07 -7.1332 0.51177E+00 -0.2909 10 Mg++ 0.22833E-10 -10.6414 0.11631E-10 -10.9344 0.50938E+00 -0.2930 11 Fe++ 0.62459E-13 -13.2044 0.31851E-13 -13.4969 0.50995E+00 -0.2925 12 K+ 0.16178E-03 -3.7911 0.13511E-03 -3.8693 0.83513E+00 -0.0782 13 Na+ 0.20568E-01 -1.6868 0.17144E-01 -1.7659 0.83353E+00 -0.0791 14 Mn++ 0.20048E-10 -10.6979 0.10232E-10 -10.9900 0.51038E+00 -0.2921 15 HPO4-- 0.48619E-07 -7.3132 0.25074E-07 -7.6008 0.51572E+00 -0.2876 16 HSiO3- 0.10976E-01 -1.9596 0.91502E-02 -2.0386 0.83369E+00 -0.0790 17 Ca(HSiO3)+ 0.18061E-07 -7.7432 0.15087E-07 -7.8214 0.83532E+00 -0.0781 18 Mg(HSiO3)+ 0.35526E-11 -11.4495 0.29675E-11 -11.5276 0.83532E+00 -0.0781 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67618E-16 -16.1699 0.56482E-16 -16.2481 0.83532E+00 -0.0781 22 HAlO2,aq 0.14895E-09 -9.8270 0.14895E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52670E-05 -5.2784 0.43830E-05 -5.3582 0.83216E+00 -0.0798 24 CH4,aq 0.18619E-04 -4.7301 0.18552E-04 -4.7316 0.99641E+00 -0.0016 25 C2H6,aq 0.54799E-14 -14.2612 0.54602E-14 -14.2628 0.99641E+00 -0.0016 29 CO,aq 0.15373E-16 -16.8133 0.15373E-16 -16.8133 0.10000E+01 0.0000 30 CO2,aq 0.55107E-10 -10.2588 0.54909E-10 -10.2604 0.99641E+00 -0.0016 31 CO3-2 0.84990E-06 -6.0706 0.43730E-06 -6.3592 0.51453E+00 -0.2886 32 CaCO3,aq 0.39414E-09 -9.4043 0.39414E-09 -9.4043 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.79669E-12 -12.0987 0.66549E-12 -12.1769 0.83532E+00 -0.0781 34 CaCl+ 0.24471E-10 -10.6113 0.20441E-10 -10.6895 0.83532E+00 -0.0781 35 CaCl2,aq 0.82964E-15 -15.0811 0.82964E-15 -15.0811 0.10000E+01 0.0000 36 CaOH+ 0.81865E-07 -7.0869 0.68384E-07 -7.1650 0.83532E+00 -0.0781 37 CaSO4,aq 0.14090E-16 -16.8511 0.14090E-16 -16.8511 0.10000E+01 0.0000 38 HCl,aq 0.24880E-14 -14.6041 0.24880E-14 -14.6041 0.10000E+01 0.0000 43 FeCl+ 0.10352E-16 -16.9850 0.86474E-17 -17.0631 0.83532E+00 -0.0781 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16659E-10 -10.7784 0.13915E-10 -10.8565 0.83532E+00 -0.0781 48 HFeO2- 0.37190E-07 -7.4296 0.31005E-07 -7.5086 0.83369E+00 -0.0790 49 FeO+ 0.12296E-16 -16.9102 0.10271E-16 -16.9884 0.83532E+00 -0.0781 51 FeO2- 0.42051E-09 -9.3762 0.35058E-09 -9.4552 0.83369E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99641E+00 -0.0016 54 KCl,aq 0.41701E-09 -9.3799 0.41701E-09 -9.3799 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.15343E-14 -14.8141 0.12791E-14 -14.8931 0.83369E+00 -0.0790 58 MgCO3,aq 0.15566E-13 -13.8078 0.15566E-13 -13.8078 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.12840E-15 -15.8914 0.10725E-15 -15.9696 0.83532E+00 -0.0781 60 MgCl+ 0.35111E-14 -14.4546 0.29329E-14 -14.5327 0.83532E+00 -0.0781 61 MgOH+ 0.71681E-10 -10.1446 0.59877E-10 -10.2227 0.83532E+00 -0.0781 63 MnO,aq 0.18758E-08 -8.7268 0.18758E-08 -8.7268 0.10000E+01 0.0000 64 MnOH+ 0.49714E-09 -9.3035 0.41527E-09 -9.3817 0.83532E+00 -0.0781 65 MnO2-2 0.21896E-10 -10.6596 0.11266E-10 -10.9482 0.51453E+00 -0.2886 66 HMnO2- 0.22218E-09 -9.6533 0.18523E-09 -9.7323 0.83369E+00 -0.0790 69 MnCl+ 0.12923E-13 -13.8886 0.10795E-13 -13.9668 0.83532E+00 -0.0781 71 NaCl,aq 0.97580E-06 -6.0106 0.97580E-06 -6.0106 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94991E-02 -2.0223 0.79048E-02 -2.1021 0.83216E+00 -0.0798 79 HPO3-2 0.16732E-14 -14.7765 0.86089E-15 -15.0651 0.51453E+00 -0.2886 81 H2PO3- 0.15392E-18 -18.8127 0.12832E-18 -18.8917 0.83369E+00 -0.0790 82 H3PO4,aq 0.92951E-18 -18.0317 0.92951E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39973E-10 -10.3982 0.33358E-10 -10.4768 0.83450E+00 -0.0786 84 PO4-3 0.12073E-08 -8.9182 0.28857E-09 -9.5397 0.23902E+00 -0.6216 88 HP2O7-3 0.10342E-17 -17.9854 0.23533E-18 -18.6283 0.22756E+00 -0.6429 89 P2O7-4 0.10206E-16 -16.9912 0.76509E-18 -18.1163 0.74968E-01 -1.1251 90 H2S,aq 0.74069E-08 -8.1304 0.73803E-08 -8.1319 0.99641E+00 -0.0016 91 S2-2 0.41206E-14 -14.3850 0.21202E-14 -14.6736 0.51453E+00 -0.2886 97 SO3-2 0.17443E-17 -17.7584 0.91077E-18 -18.0406 0.52214E+00 -0.2822 99 HSO4- 0.51744E-19 -19.2861 0.43266E-19 -19.3639 0.83615E+00 -0.0777 Charge balance for all species = 0.5024E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9046004E-10 -.2309105E-01 -.2323221E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981164E+06 0.0000 3 Cl- 0.2090865E-03 0.2100627E-03 0.7433855E+01 6.3612 4 SO4-- 0.1191700E-11 -.2134589E-04 -.2046804E+01 8.0282 5 HCO3- 0.4298464E-06 0.1989879E-04 0.1211968E+01 3.6748 6 HS- 0.3882260E-04 0.6017590E-04 0.1986530E+01 5.6300 7 Al+++ 0.1108291E-28 0.5267114E-05 0.1418570E+00 0.7609 8 H4SiO4 0.7116526E-03 0.1417867E-01 0.1360318E+04 -3.1477 9 Ca++ 0.1437960E-06 0.2441423E-06 0.9766999E-02 13.1065 10 Mg++ 0.2283339E-10 0.9808486E-10 0.2380317E-05 9.3053 11 Fe++ 0.6245877E-13 0.3784965E-07 0.2109958E-02 6.7428 12 K+ 0.1617795E-03 0.1625562E-03 0.6344750E+01 6.2505 13 Na+ 0.2056793E-01 0.2315967E-01 0.5314711E+03 8.3540 14 Mn++ 0.2004758E-10 0.2637107E-08 0.1446148E-03 9.2497 15 HPO4-- 0.4861907E-07 0.4986638E-07 0.4777450E-02 12.6389 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5629892E+02 -.1516675E-01 -.5628376E+02 0.0000000E+00 2 H2O 0.1288787E+02 0.3645662E+02 -.2356875E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9425107E-01 -.1402049E-04 0.9426509E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9422556E-01 0.3952496E-04 -.9426509E-01 0.0000000E+00 7 Al+++ 0.1108652E+02 0.3459565E-05 0.1108651E+02 0.0000000E+00 8 H4SiO4 0.3540345E+02 0.9312885E-02 0.3539414E+02 0.0000000E+00 9 Ca++ 0.3910498E+01 0.1603585E-06 0.3910498E+01 0.0000000E+00 10 Mg++ 0.2698412E+01 0.6442447E-10 0.2698412E+01 0.0000000E+00 11 Fe++ 0.2424229E+01 0.2486055E-07 0.2424228E+01 0.0000000E+00 12 K+ 0.7218682E+00 0.1067707E-03 0.7217614E+00 0.0000000E+00 13 Na+ 0.4267987E+01 0.1521182E-01 0.4252775E+01 0.0000000E+00 14 Mn++ 0.5895121E-01 0.1732115E-08 0.5895121E-01 0.0000000E+00 15 HPO4-- 0.2011975E-01 0.3275342E-07 0.2011972E-01 0.0000000E+00 Chg. balance for solid moles: 0.1762E-13 Mass of aqueous solution: 0.658016E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.250 0.628 1114. 3.047 30.00 427.8 andradite 0.3771 -0.424 191.6 2.282 5.159 49.78 grossular 0.9003E-01 -1.046 40.55 1.608 1.092 11.28 apatite-OH 0.6707E-02 -2.173 3.369 0.527 0.9070E-01 1.070 clinochlore 0.4849 -0.314 269.5 2.431 7.256 102.5 daphnite 0.1390 -0.857 99.16 1.996 2.669 30.05 chlorite-Mn 0.1179E-01 -1.928 8.359 0.922 0.2250 2.664 diopside 0.1872 -0.728 40.53 1.608 1.091 12.39 hedenbergite 0.4795E-01 -1.319 11.90 1.075 0.3203 3.259 microcline 0.6320 -0.199 175.9 2.245 4.736 68.72 stilbite 2.193 0.341 1545. 3.189 41.60 720.7 stilpnomelane-Fe 0.1795 -0.746 193.5 2.287 5.209 66.83 tr.625ac.25prg.125 0.2393E-01 -1.621 20.46 1.311 0.5507 6.584 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1855E-01 0.1855E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3714.472907 g Volume = 1503.658568 cm3 Porosity: -10.4819% V(tot) - V(min): -.14266E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3399.9990000 g log = 3.5315 Original solution: 1000.0103000 g Original solution / Rock added: 0.29 (Water/Rock Ratio), log = -0.5315 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0964 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9600E+00 0.9849 0.1037E+01 0.1053E+01 CO2,gas 0.5692E-08 1.0070 0.6285E-08 0.6241E-08 CH4,gas 0.2642E-01 1.0127 0.2934E-01 0.2897E-01 H2,gas 0.1359E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.1972E-06 0.9957 0.2153E-06 0.2162E-06 S2,gas 0.7120E-29 1.0000 0.7807E-29 0.7807E-29 CO,gas 0.2214E-13 1.0000 0.2427E-13 0.2427E-13 SO3,gas 0.1206E-47 1.0000 0.1323E-47 0.1323E-47 SO2,gas 0.6805E-27 1.0000 0.7461E-27 0.7461E-27 HCl,gas 0.4007E-17 1.0000 0.4393E-17 0.4393E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.56 -10.20 -3.401 0.17419E+05 -8.202 3 CH4,gas 4.81 1.28 -3.53 -0.883 0.60318E+04 -1.533 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.61 -8.67 -4.334 0.14799E+05 -6.667 6 S2,gas -7.03 -38.14 -31.11 -4.786 0.53115E+05 -29.108 7 CO,gas 3.51 -12.10 -15.61 -4.805 0.26662E+05 -13.615 8 SO3,gas 17.43 -32.45 -49.88 -12.470 0.85166E+05 -47.878 9 SO2,gas 1.14 -27.99 -29.13 -7.767 0.49734E+05 -27.127 10 HCl,gas 5.48 -13.88 -19.36 -9.679 0.33052E+05 -17.357 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80633E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94127E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.46 -4.44 -1.482 0.75890E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.46 -4.29 -1.431 0.73277E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70379E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65559E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.64 -4.54 -1.296 0.77465E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.64 -4.10 -1.170 0.69927E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82271E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53670E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92775E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40700E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43449E+04 143 pyrrhotite -4.24 -7.87 -3.62 -1.208 0.61867E+04 144 pyrrhotiteFe0.875 -6.00 -9.26 -3.26 -1.200 0.55694E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22438E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84881E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28298E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23230E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47148E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91028E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.87 -3.47 -1.158 0.59299E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80433E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66782E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60330E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.36 -4.40 -1.466 0.75088E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3399.9990000 g New total amount of reactant added: 3499.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3300E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3499.9990000 Water: Moles liquid = 0.3590E+02 kg liquid = 0.6468E+00 Moles total = 0.1163E+02 kg total = 0.2096E+00 Activity = 1.0000 Stoichiometric ionic strength = .1179139E-01 Osmotic coef. = 0.9684 True ionic strength = .2073326E-01 Chg. balance for total moles = 0.3300E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90469E-10 -10.0435 0.75890E-10 -10.1198 0.83884E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.21233E-03 -3.6730 0.17702E-03 -3.7520 0.83368E+00 -0.0790 4 SO4-- 0.12101E-11 -11.9172 0.62398E-12 -12.2048 0.51563E+00 -0.2877 5 HCO3- 0.43649E-06 -6.3600 0.36444E-06 -6.4384 0.83493E+00 -0.0784 6 HS- 0.39426E-04 -4.4042 0.32873E-04 -4.4832 0.83381E+00 -0.0789 7 Al+++ 0.11087E-28 -28.9552 0.25200E-29 -29.5986 0.22730E+00 -0.6434 8 H4SiO4 0.71165E-03 -3.1477 0.71165E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14383E-06 -6.8422 0.73605E-07 -7.1331 0.51176E+00 -0.2909 10 Mg++ 0.22838E-10 -10.6413 0.11633E-10 -10.9343 0.50937E+00 -0.2930 11 Fe++ 0.62472E-13 -13.2043 0.31857E-13 -13.4968 0.50994E+00 -0.2925 12 K+ 0.16180E-03 -3.7910 0.13512E-03 -3.8693 0.83513E+00 -0.0782 13 Na+ 0.20570E-01 -1.6868 0.17146E-01 -1.7658 0.83353E+00 -0.0791 14 Mn++ 0.20053E-10 -10.6978 0.10235E-10 -10.9899 0.51037E+00 -0.2921 15 HPO4-- 0.48611E-07 -7.3133 0.25069E-07 -7.6009 0.51571E+00 -0.2876 16 HSiO3- 0.10975E-01 -1.9596 0.91493E-02 -2.0386 0.83368E+00 -0.0790 17 Ca(HSiO3)+ 0.18063E-07 -7.7432 0.15088E-07 -7.8214 0.83531E+00 -0.0782 18 Mg(HSiO3)+ 0.35529E-11 -11.4494 0.29678E-11 -11.5276 0.83531E+00 -0.0782 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67625E-16 -16.1699 0.56488E-16 -16.2480 0.83531E+00 -0.0782 22 HAlO2,aq 0.14895E-09 -9.8270 0.14895E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52665E-05 -5.2785 0.43825E-05 -5.3583 0.83215E+00 -0.0798 24 CH4,aq 0.18908E-04 -4.7234 0.18840E-04 -4.7249 0.99641E+00 -0.0016 25 C2H6,aq 0.56516E-14 -14.2478 0.56313E-14 -14.2494 0.99641E+00 -0.0016 29 CO,aq 0.15612E-16 -16.8066 0.15612E-16 -16.8066 0.10000E+01 0.0000 30 CO2,aq 0.55963E-10 -10.2521 0.55762E-10 -10.2537 0.99641E+00 -0.0016 31 CO3-2 0.86297E-06 -6.0640 0.44401E-06 -6.3526 0.51452E+00 -0.2886 32 CaCO3,aq 0.40027E-09 -9.3976 0.40027E-09 -9.3976 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.80916E-12 -12.0920 0.67590E-12 -12.1701 0.83531E+00 -0.0782 34 CaCl+ 0.24856E-10 -10.6046 0.20762E-10 -10.6827 0.83531E+00 -0.0782 35 CaCl2,aq 0.85576E-15 -15.0676 0.85576E-15 -15.0676 0.10000E+01 0.0000 36 CaOH+ 0.81874E-07 -7.0869 0.68390E-07 -7.1650 0.83531E+00 -0.0782 37 CaSO4,aq 0.14310E-16 -16.8444 0.14310E-16 -16.8444 0.10000E+01 0.0000 38 HCl,aq 0.25269E-14 -14.5974 0.25269E-14 -14.5974 0.10000E+01 0.0000 43 FeCl+ 0.10515E-16 -16.9782 0.87833E-17 -17.0563 0.83531E+00 -0.0782 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16661E-10 -10.7783 0.13917E-10 -10.8565 0.83531E+00 -0.0782 48 HFeO2- 0.37187E-07 -7.4296 0.31002E-07 -7.5086 0.83368E+00 -0.0790 49 FeO+ 0.12297E-16 -16.9102 0.10272E-16 -16.9883 0.83531E+00 -0.0782 51 FeO2- 0.42048E-09 -9.3763 0.35054E-09 -9.4553 0.83368E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99641E+00 -0.0016 54 KCl,aq 0.42352E-09 -9.3731 0.42352E-09 -9.3731 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.15581E-14 -14.8074 0.12990E-14 -14.8864 0.83368E+00 -0.0790 58 MgCO3,aq 0.15808E-13 -13.8011 0.15808E-13 -13.8011 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13041E-15 -15.8847 0.10893E-15 -15.9628 0.83531E+00 -0.0782 60 MgCl+ 0.35663E-14 -14.4478 0.29790E-14 -14.5259 0.83531E+00 -0.0782 61 MgOH+ 0.71688E-10 -10.1446 0.59882E-10 -10.2227 0.83531E+00 -0.0782 63 MnO,aq 0.18760E-08 -8.7268 0.18760E-08 -8.7268 0.10000E+01 0.0000 64 MnOH+ 0.49723E-09 -9.3034 0.41535E-09 -9.3816 0.83531E+00 -0.0782 65 MnO2-2 0.21894E-10 -10.6597 0.11265E-10 -10.9483 0.51452E+00 -0.2886 66 HMnO2- 0.22217E-09 -9.6533 0.18522E-09 -9.7323 0.83368E+00 -0.0790 69 MnCl+ 0.13127E-13 -13.8818 0.10965E-13 -13.9600 0.83531E+00 -0.0782 71 NaCl,aq 0.99104E-06 -6.0039 0.99104E-06 -6.0039 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94983E-02 -2.0224 0.79041E-02 -2.1022 0.83215E+00 -0.0798 79 HPO3-2 0.16729E-14 -14.7765 0.86073E-15 -15.0651 0.51452E+00 -0.2886 81 H2PO3- 0.15391E-18 -18.8127 0.12831E-18 -18.8917 0.83368E+00 -0.0790 82 H3PO4,aq 0.92951E-18 -18.0317 0.92951E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39970E-10 -10.3983 0.33355E-10 -10.4768 0.83449E+00 -0.0786 84 PO4-3 0.12071E-08 -8.9183 0.28849E-09 -9.5399 0.23900E+00 -0.6216 88 HP2O7-3 0.10340E-17 -17.9855 0.23527E-18 -18.6284 0.22754E+00 -0.6429 89 P2O7-4 0.10203E-16 -16.9913 0.76480E-18 -18.1165 0.74960E-01 -1.1252 90 H2S,aq 0.75227E-08 -8.1236 0.74956E-08 -8.1252 0.99641E+00 -0.0016 91 S2-2 0.42496E-14 -14.3716 0.21865E-14 -14.6602 0.51452E+00 -0.2886 97 SO3-2 0.17713E-17 -17.7517 0.92483E-18 -18.0339 0.52212E+00 -0.2822 99 HSO4- 0.52548E-19 -19.2794 0.43938E-19 -19.3572 0.83615E+00 -0.0777 Charge balance for all species = 0.5100E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9046917E-10 -.2308928E-01 -.2323043E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981163E+06 0.0000 3 Cl- 0.2123342E-03 0.2133257E-03 0.7549327E+01 6.3678 4 SO4-- 0.1210131E-11 -.2163526E-04 -.2074550E+01 8.0348 5 HCO3- 0.4364922E-06 0.2020789E-04 0.1230794E+01 3.6814 6 HS- 0.3942565E-04 0.6106843E-04 0.2015994E+01 5.6367 7 Al+++ 0.1108670E-28 0.5266639E-05 0.1418442E+00 0.7609 8 H4SiO4 0.7116532E-03 0.1417772E-01 0.1360227E+04 -3.1477 9 Ca++ 0.1438270E-06 0.2441898E-06 0.9768900E-02 13.1065 10 Mg++ 0.2283832E-10 0.9809996E-10 0.2380683E-05 9.3053 11 Fe++ 0.6247229E-13 0.3784634E-07 0.2109773E-02 6.7428 12 K+ 0.1617959E-03 0.1625725E-03 0.6345389E+01 6.2505 13 Na+ 0.2057001E-01 0.2316177E-01 0.5315193E+03 8.3540 14 Mn++ 0.2005349E-10 0.2637345E-08 0.1446278E-03 9.2497 15 HPO4-- 0.4861127E-07 0.4985830E-07 0.4776675E-02 12.6388 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5795477E+02 -.1493362E-01 -.5793984E+02 0.0000000E+00 2 H2O 0.1163433E+02 0.3589899E+02 -.2426466E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9702241E-01 -.1399319E-04 0.9703640E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9699690E-01 0.3949766E-04 -.9703640E-01 0.0000000E+00 7 Al+++ 0.1141259E+02 0.3406341E-05 0.1141259E+02 0.0000000E+00 8 H4SiO4 0.3644473E+02 0.9169823E-02 0.3643556E+02 0.0000000E+00 9 Ca++ 0.4025513E+01 0.1579364E-06 0.4025512E+01 0.0000000E+00 10 Mg++ 0.2777777E+01 0.6344880E-10 0.2777777E+01 0.0000000E+00 11 Fe++ 0.2495529E+01 0.2447814E-07 0.2495529E+01 0.0000000E+00 12 K+ 0.7430996E+00 0.1051482E-03 0.7429944E+00 0.0000000E+00 13 Na+ 0.4393512E+01 0.1498050E-01 0.4378531E+01 0.0000000E+00 14 Mn++ 0.6068507E-01 0.1705774E-08 0.6068507E-01 0.0000000E+00 15 HPO4-- 0.2071151E-01 0.3224720E-07 0.2071148E-01 0.0000000E+00 Chg. balance for solid moles: -.2900E-14 Mass of aqueous solution: 0.647952E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3499.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.375 0.641 1147. 3.060 30.01 440.4 andradite 0.3881 -0.411 197.2 2.295 5.159 51.25 grossular 0.9268E-01 -1.033 41.75 1.621 1.092 11.62 apatite-OH 0.6904E-02 -2.161 3.468 0.540 0.9069E-01 1.102 clinochlore 0.4991 -0.302 277.4 2.443 7.255 105.5 daphnite 0.1430 -0.845 102.1 2.009 2.669 30.93 chlorite-Mn 0.1214E-01 -1.916 8.605 0.935 0.2250 2.742 diopside 0.1930 -0.715 41.79 1.621 1.093 12.77 hedenbergite 0.4943E-01 -1.306 12.26 1.089 0.3207 3.359 microcline 0.6506 -0.187 181.1 2.258 4.736 70.74 stilbite 2.257 0.354 1590. 3.202 41.60 741.8 stilpnomelane-Fe 0.1848 -0.733 199.2 2.299 5.209 68.80 tr.625ac.25prg.125 0.2462E-01 -1.609 21.04 1.323 0.5502 6.772 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1855E-01 0.1855E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3823.728389 g Volume = 1547.864925 cm3 Porosity: -10.4829% V(tot) - V(min): -.14687E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3499.9990000 g log = 3.5441 Original solution: 1000.0103000 g Original solution / Rock added: 0.29 (Water/Rock Ratio), log = -0.5441 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0969 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9596E+00 0.9849 0.1037E+01 0.1053E+01 CO2,gas 0.5779E-08 1.0070 0.6383E-08 0.6339E-08 CH4,gas 0.2682E-01 1.0127 0.2979E-01 0.2942E-01 H2,gas 0.1358E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.2002E-06 0.9957 0.2186E-06 0.2195E-06 S2,gas 0.7342E-29 1.0000 0.8053E-29 0.8053E-29 CO,gas 0.2247E-13 1.0000 0.2465E-13 0.2465E-13 SO3,gas 0.1225E-47 1.0000 0.1344E-47 0.1344E-47 SO2,gas 0.6908E-27 1.0000 0.7578E-27 0.7578E-27 HCl,gas 0.4068E-17 1.0000 0.4462E-17 0.4462E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.54595E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.97059E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.56 -10.19 -3.398 0.17408E+05 -8.195 3 CH4,gas 4.81 1.28 -3.53 -0.881 0.60204E+04 -1.526 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.60 -8.66 -4.330 0.14787E+05 -6.660 6 S2,gas -7.03 -38.13 -31.09 -4.784 0.53092E+05 -29.094 7 CO,gas 3.51 -12.10 -15.61 -4.803 0.26651E+05 -13.608 8 SO3,gas 17.43 -32.44 -49.87 -12.468 0.85155E+05 -47.872 9 SO2,gas 1.14 -27.98 -29.12 -7.765 0.49722E+05 -27.120 10 HCl,gas 5.48 -13.87 -19.35 -9.675 0.33040E+05 -17.350 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80631E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94127E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.45 -4.44 -1.479 0.75775E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.45 -4.28 -1.428 0.73162E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70379E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65559E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.64 -4.53 -1.294 0.77351E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.64 -4.09 -1.168 0.69813E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82270E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53670E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92775E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40700E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43449E+04 143 pyrrhotite -4.24 -7.86 -3.62 -1.206 0.61752E+04 144 pyrrhotiteFe0.875 -6.00 -9.26 -3.26 -1.197 0.55580E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22437E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28298E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23229E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47147E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91028E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.86 -3.47 -1.155 0.59184E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80433E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66782E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60330E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.35 -4.39 -1.464 0.74973E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3499.9990000 g New total amount of reactant added: 3599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3300E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3599.9990000 Water: Moles liquid = 0.3534E+02 kg liquid = 0.6367E+00 Moles total = 0.1038E+02 kg total = 0.1870E+00 Activity = 1.0000 Stoichiometric ionic strength = .1179418E-01 Osmotic coef. = 0.9683 True ionic strength = .2073544E-01 Chg. balance for total moles = 0.3300E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90479E-10 -10.0435 0.75897E-10 -10.1198 0.83884E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.21568E-03 -3.6662 0.17981E-03 -3.7452 0.83368E+00 -0.0790 4 SO4-- 0.12291E-11 -11.9104 0.63377E-12 -12.1981 0.51562E+00 -0.2877 5 HCO3- 0.44335E-06 -6.3533 0.37016E-06 -6.4316 0.83492E+00 -0.0784 6 HS- 0.40048E-04 -4.3974 0.33392E-04 -4.4764 0.83380E+00 -0.0789 7 Al+++ 0.11091E-28 -28.9550 0.25207E-29 -29.5985 0.22729E+00 -0.6434 8 H4SiO4 0.71165E-03 -3.1477 0.71165E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14386E-06 -6.8421 0.73619E-07 -7.1330 0.51175E+00 -0.2909 10 Mg++ 0.22843E-10 -10.6412 0.11635E-10 -10.9342 0.50935E+00 -0.2930 11 Fe++ 0.62486E-13 -13.2042 0.31863E-13 -13.4967 0.50992E+00 -0.2925 12 K+ 0.16181E-03 -3.7910 0.13513E-03 -3.8692 0.83512E+00 -0.0782 13 Na+ 0.20572E-01 -1.6867 0.17147E-01 -1.7658 0.83352E+00 -0.0791 14 Mn++ 0.20059E-10 -10.6977 0.10237E-10 -10.9898 0.51036E+00 -0.2921 15 HPO4-- 0.48603E-07 -7.3133 0.25064E-07 -7.6009 0.51569E+00 -0.2876 16 HSiO3- 0.10974E-01 -1.9597 0.91484E-02 -2.0387 0.83368E+00 -0.0790 17 Ca(HSiO3)+ 0.18065E-07 -7.7432 0.15090E-07 -7.8213 0.83531E+00 -0.0782 18 Mg(HSiO3)+ 0.35533E-11 -11.4494 0.29681E-11 -11.5275 0.83531E+00 -0.0782 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67631E-16 -16.1699 0.56493E-16 -16.2480 0.83531E+00 -0.0782 22 HAlO2,aq 0.14895E-09 -9.8270 0.14895E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52660E-05 -5.2785 0.43821E-05 -5.3583 0.83215E+00 -0.0798 24 CH4,aq 0.19206E-04 -4.7166 0.19137E-04 -4.7181 0.99641E+00 -0.0016 25 C2H6,aq 0.58314E-14 -14.2342 0.58105E-14 -14.2358 0.99641E+00 -0.0016 29 CO,aq 0.15858E-16 -16.7997 0.15858E-16 -16.7997 0.10000E+01 0.0000 30 CO2,aq 0.56847E-10 -10.2453 0.56643E-10 -10.2469 0.99641E+00 -0.0016 31 CO3-2 0.87646E-06 -6.0573 0.45094E-06 -6.3459 0.51450E+00 -0.2886 32 CaCO3,aq 0.40659E-09 -9.3908 0.40659E-09 -9.3908 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.82202E-12 -12.0851 0.68664E-12 -12.1633 0.83531E+00 -0.0782 34 CaCl+ 0.25253E-10 -10.5977 0.21094E-10 -10.6758 0.83531E+00 -0.0782 35 CaCl2,aq 0.88313E-15 -15.0540 0.88313E-15 -15.0540 0.10000E+01 0.0000 36 CaOH+ 0.81882E-07 -7.0868 0.68397E-07 -7.1650 0.83531E+00 -0.0782 37 CaSO4,aq 0.14537E-16 -16.8375 0.14537E-16 -16.8375 0.10000E+01 0.0000 38 HCl,aq 0.25670E-14 -14.5906 0.25670E-14 -14.5906 0.10000E+01 0.0000 43 FeCl+ 0.10683E-16 -16.9713 0.89236E-17 -17.0495 0.83531E+00 -0.0782 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16662E-10 -10.7783 0.13918E-10 -10.8564 0.83531E+00 -0.0782 48 HFeO2- 0.37184E-07 -7.4296 0.30999E-07 -7.5086 0.83368E+00 -0.0790 49 FeO+ 0.12298E-16 -16.9101 0.10273E-16 -16.9883 0.83531E+00 -0.0782 51 FeO2- 0.42044E-09 -9.3763 0.35051E-09 -9.4553 0.83368E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99641E+00 -0.0016 54 KCl,aq 0.43024E-09 -9.3663 0.43024E-09 -9.3663 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.15827E-14 -14.8006 0.13195E-14 -14.8796 0.83368E+00 -0.0790 58 MgCO3,aq 0.16058E-13 -13.7943 0.16058E-13 -13.7943 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13248E-15 -15.8778 0.11066E-15 -15.9560 0.83531E+00 -0.0782 60 MgCl+ 0.36233E-14 -14.4409 0.30266E-14 -14.5191 0.83531E+00 -0.0782 61 MgOH+ 0.71696E-10 -10.1445 0.59888E-10 -10.2227 0.83531E+00 -0.0782 63 MnO,aq 0.18761E-08 -8.7267 0.18761E-08 -8.7267 0.10000E+01 0.0000 64 MnOH+ 0.49732E-09 -9.3034 0.41542E-09 -9.3815 0.83531E+00 -0.0782 65 MnO2-2 0.21892E-10 -10.6597 0.11264E-10 -10.9483 0.51450E+00 -0.2886 66 HMnO2- 0.22217E-09 -9.6533 0.18522E-09 -9.7323 0.83368E+00 -0.0790 69 MnCl+ 0.13338E-13 -13.8749 0.11141E-13 -13.9531 0.83531E+00 -0.0782 71 NaCl,aq 0.10068E-05 -5.9971 0.10068E-05 -5.9971 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94975E-02 -2.0224 0.79033E-02 -2.1022 0.83215E+00 -0.0798 79 HPO3-2 0.16726E-14 -14.7766 0.86056E-15 -15.0652 0.51450E+00 -0.2886 81 H2PO3- 0.15389E-18 -18.8128 0.12830E-18 -18.8918 0.83368E+00 -0.0790 82 H3PO4,aq 0.92951E-18 -18.0317 0.92951E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39966E-10 -10.3983 0.33351E-10 -10.4769 0.83448E+00 -0.0786 84 PO4-3 0.12068E-08 -8.9184 0.28840E-09 -9.5400 0.23899E+00 -0.6216 88 HP2O7-3 0.10337E-17 -17.9856 0.23520E-18 -18.6286 0.22753E+00 -0.6430 89 P2O7-4 0.10200E-16 -16.9914 0.76450E-18 -18.1166 0.74952E-01 -1.1252 90 H2S,aq 0.76421E-08 -8.1168 0.76146E-08 -8.1184 0.99641E+00 -0.0016 91 S2-2 0.43849E-14 -14.3580 0.22560E-14 -14.6467 0.51450E+00 -0.2886 97 SO3-2 0.17991E-17 -17.7449 0.93933E-18 -18.0272 0.52211E+00 -0.2822 99 HSO4- 0.53378E-19 -19.2726 0.44631E-19 -19.3504 0.83614E+00 -0.0777 Charge balance for all species = 0.5184E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9047858E-10 -.2308746E-01 -.2322859E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981162E+06 0.0000 3 Cl- 0.2156845E-03 0.2166917E-03 0.7668444E+01 6.3746 4 SO4-- 0.1229141E-11 -.2193376E-04 -.2103173E+01 8.0415 5 HCO3- 0.4433464E-06 0.2052674E-04 0.1250214E+01 3.6882 6 HS- 0.4004773E-04 0.6198913E-04 0.2046388E+01 5.6434 7 Al+++ 0.1109061E-28 0.5266150E-05 0.1418310E+00 0.7609 8 H4SiO4 0.7116539E-03 0.1417674E-01 0.1360133E+04 -3.1477 9 Ca++ 0.1438590E-06 0.2442389E-06 0.9770862E-02 13.1065 10 Mg++ 0.2284340E-10 0.9811275E-10 0.2380993E-05 9.3053 11 Fe++ 0.6248623E-13 0.3784293E-07 0.2109583E-02 6.7428 12 K+ 0.1618128E-03 0.1625894E-03 0.6346047E+01 6.2505 13 Na+ 0.2057216E-01 0.2316394E-01 0.5315690E+03 8.3540 14 Mn++ 0.2005945E-10 0.2637573E-08 0.1446403E-03 9.2497 15 HPO4-- 0.4860321E-07 0.4984996E-07 0.4775876E-02 12.6386 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.5961063E+02 -.1470048E-01 -.5959593E+02 0.0000000E+00 2 H2O 0.1038079E+02 0.3534135E+02 -.2496056E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.9979375E-01 -.1396589E-04 0.9980771E-01 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.9976824E-01 0.3947036E-04 -.9980771E-01 0.0000000E+00 7 Al+++ 0.1173867E+02 0.3353117E-05 0.1173866E+02 0.0000000E+00 8 H4SiO4 0.3748601E+02 0.9026760E-02 0.3747698E+02 0.0000000E+00 9 Ca++ 0.4140527E+01 0.1555143E-06 0.4140527E+01 0.0000000E+00 10 Mg++ 0.2857142E+01 0.6247136E-10 0.2857142E+01 0.0000000E+00 11 Fe++ 0.2566830E+01 0.2409574E-07 0.2566830E+01 0.0000000E+00 12 K+ 0.7643310E+00 0.1035256E-03 0.7642275E+00 0.0000000E+00 13 Na+ 0.4519036E+01 0.1474918E-01 0.4504287E+01 0.0000000E+00 14 Mn++ 0.6241893E-01 0.1679423E-08 0.6241893E-01 0.0000000E+00 15 HPO4-- 0.2130327E-01 0.3174098E-07 0.2130324E-01 0.0000000E+00 Chg. balance for solid moles: -.1300E-13 Mass of aqueous solution: 0.637887E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.501 0.653 1180. 3.072 30.01 453.1 andradite 0.3992 -0.399 202.9 2.307 5.158 52.71 grossular 0.9532E-01 -1.021 42.94 1.633 1.092 11.95 apatite-OH 0.7101E-02 -2.149 3.567 0.552 0.9069E-01 1.133 clinochlore 0.5133 -0.290 285.3 2.455 7.255 108.5 daphnite 0.1471 -0.832 105.0 2.021 2.669 31.81 chlorite-Mn 0.1248E-01 -1.904 8.851 0.947 0.2250 2.820 diopside 0.1987 -0.702 43.04 1.634 1.094 13.15 hedenbergite 0.5092E-01 -1.293 12.63 1.101 0.3212 3.460 microcline 0.6692 -0.174 186.3 2.270 4.736 72.76 stilbite 2.321 0.366 1636. 3.214 41.59 762.9 stilpnomelane-Fe 0.1900 -0.721 204.9 2.311 5.209 70.76 tr.625ac.25prg.125 0.2530E-01 -1.597 21.62 1.335 0.5498 6.959 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1855E-01 0.1855E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 3932.983871 g Volume = 1592.071282 cm3 Porosity: -10.4838% V(tot) - V(min): -.15107E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3599.9990000 g log = 3.5563 Original solution: 1000.0103000 g Original solution / Rock added: 0.28 (Water/Rock Ratio), log = -0.5563 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0974 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9592E+00 0.9849 0.1037E+01 0.1053E+01 CO2,gas 0.5867E-08 1.0070 0.6484E-08 0.6439E-08 CH4,gas 0.2723E-01 1.0127 0.3026E-01 0.2988E-01 H2,gas 0.1358E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.2032E-06 0.9957 0.2221E-06 0.2230E-06 S2,gas 0.7573E-29 1.0000 0.8311E-29 0.8311E-29 CO,gas 0.2282E-13 1.0000 0.2504E-13 0.2504E-13 SO3,gas 0.1244E-47 1.0000 0.1365E-47 0.1365E-47 SO2,gas 0.7015E-27 1.0000 0.7698E-27 0.7698E-27 HCl,gas 0.4130E-17 1.0000 0.4533E-17 0.4533E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.55 -10.19 -3.396 0.17396E+05 -8.188 3 CH4,gas 4.81 1.29 -3.52 -0.880 0.60087E+04 -1.519 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.60 -8.65 -4.327 0.14776E+05 -6.653 6 S2,gas -7.03 -38.11 -31.08 -4.782 0.53069E+05 -29.080 7 CO,gas 3.51 -12.09 -15.60 -4.800 0.26639E+05 -13.601 8 SO3,gas 17.43 -32.44 -49.86 -12.466 0.85143E+05 -47.865 9 SO2,gas 1.14 -27.98 -29.11 -7.764 0.49711E+05 -27.114 10 HCl,gas 5.48 -13.86 -19.34 -9.672 0.33029E+05 -17.344 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80629E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94128E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.44 -4.43 -1.477 0.75659E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.44 -4.28 -1.426 0.73046E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70379E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65558E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.63 -4.52 -1.292 0.77235E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.63 -4.08 -1.166 0.69697E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82270E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92775E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40700E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43449E+04 143 pyrrhotite -4.24 -7.85 -3.61 -1.203 0.61635E+04 144 pyrrhotiteFe0.875 -6.00 -9.25 -3.25 -1.195 0.55463E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22437E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28298E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23229E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47146E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91028E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.85 -3.46 -1.153 0.59067E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80434E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66782E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60330E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83180E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.35 -4.38 -1.461 0.74855E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3599.9990000 g New total amount of reactant added: 3699.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3300E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3699.9990000 Water: Moles liquid = 0.3479E+02 kg liquid = 0.6267E+00 Moles total = 0.9127E+01 kg total = 0.1644E+00 Activity = 1.0000 Stoichiometric ionic strength = .1179707E-01 Osmotic coef. = 0.9683 True ionic strength = .2073769E-01 Chg. balance for total moles = 0.3300E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90488E-10 -10.0434 0.75905E-10 -10.1197 0.83883E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.21914E-03 -3.6593 0.18269E-03 -3.7383 0.83367E+00 -0.0790 4 SO4-- 0.12488E-11 -11.9035 0.64386E-12 -12.1912 0.51560E+00 -0.2877 5 HCO3- 0.45042E-06 -6.3464 0.37606E-06 -6.4247 0.83492E+00 -0.0784 6 HS- 0.40690E-04 -4.3905 0.33927E-04 -4.4695 0.83380E+00 -0.0789 7 Al+++ 0.11095E-28 -28.9549 0.25215E-29 -29.5983 0.22727E+00 -0.6435 8 H4SiO4 0.71165E-03 -3.1477 0.71165E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14389E-06 -6.8420 0.73634E-07 -7.1329 0.51173E+00 -0.2910 10 Mg++ 0.22849E-10 -10.6411 0.11638E-10 -10.9341 0.50934E+00 -0.2930 11 Fe++ 0.62501E-13 -13.2041 0.31870E-13 -13.4966 0.50991E+00 -0.2925 12 K+ 0.16183E-03 -3.7909 0.13515E-03 -3.8692 0.83512E+00 -0.0783 13 Na+ 0.20574E-01 -1.6867 0.17149E-01 -1.7658 0.83351E+00 -0.0791 14 Mn++ 0.20065E-10 -10.6976 0.10240E-10 -10.9897 0.51034E+00 -0.2921 15 HPO4-- 0.48595E-07 -7.3134 0.25059E-07 -7.6010 0.51568E+00 -0.2876 16 HSiO3- 0.10973E-01 -1.9597 0.91475E-02 -2.0387 0.83367E+00 -0.0790 17 Ca(HSiO3)+ 0.18067E-07 -7.7431 0.15091E-07 -7.8213 0.83530E+00 -0.0782 18 Mg(HSiO3)+ 0.35537E-11 -11.4493 0.29684E-11 -11.5275 0.83530E+00 -0.0782 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67638E-16 -16.1698 0.56498E-16 -16.2480 0.83530E+00 -0.0782 22 HAlO2,aq 0.14895E-09 -9.8270 0.14895E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52655E-05 -5.2786 0.43816E-05 -5.3584 0.83214E+00 -0.0798 24 CH4,aq 0.19515E-04 -4.7096 0.19444E-04 -4.7112 0.99640E+00 -0.0016 25 C2H6,aq 0.60200E-14 -14.2204 0.59984E-14 -14.2220 0.99640E+00 -0.0016 29 CO,aq 0.16113E-16 -16.7928 0.16113E-16 -16.7928 0.10000E+01 0.0000 30 CO2,aq 0.57760E-10 -10.2384 0.57552E-10 -10.2399 0.99640E+00 -0.0016 31 CO3-2 0.89037E-06 -6.0504 0.45808E-06 -6.3391 0.51449E+00 -0.2886 32 CaCO3,aq 0.41312E-09 -9.3839 0.41312E-09 -9.3839 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.83530E-12 -12.0782 0.69773E-12 -12.1563 0.83530E+00 -0.0782 34 CaCl+ 0.25663E-10 -10.5907 0.21436E-10 -10.6689 0.83530E+00 -0.0782 35 CaCl2,aq 0.91185E-15 -15.0401 0.91185E-15 -15.0401 0.10000E+01 0.0000 36 CaOH+ 0.81891E-07 -7.0868 0.68403E-07 -7.1649 0.83530E+00 -0.0782 37 CaSO4,aq 0.14772E-16 -16.8306 0.14772E-16 -16.8306 0.10000E+01 0.0000 38 HCl,aq 0.26084E-14 -14.5836 0.26084E-14 -14.5836 0.10000E+01 0.0000 43 FeCl+ 0.10856E-16 -16.9643 0.90684E-17 -17.0425 0.83530E+00 -0.0782 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16664E-10 -10.7782 0.13920E-10 -10.8564 0.83530E+00 -0.0782 48 HFeO2- 0.37180E-07 -7.4297 0.30996E-07 -7.5087 0.83367E+00 -0.0790 49 FeO+ 0.12300E-16 -16.9101 0.10274E-16 -16.9883 0.83530E+00 -0.0782 51 FeO2- 0.42040E-09 -9.3763 0.35048E-09 -9.4553 0.83367E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99640E+00 -0.0016 54 KCl,aq 0.43718E-09 -9.3593 0.43718E-09 -9.3593 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.16081E-14 -14.7937 0.13406E-14 -14.8727 0.83367E+00 -0.0790 58 MgCO3,aq 0.16315E-13 -13.7874 0.16315E-13 -13.7874 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13462E-15 -15.8709 0.11245E-15 -15.9490 0.83530E+00 -0.0782 60 MgCl+ 0.36821E-14 -14.4339 0.30757E-14 -14.5121 0.83530E+00 -0.0782 61 MgOH+ 0.71703E-10 -10.1445 0.59894E-10 -10.2226 0.83530E+00 -0.0782 63 MnO,aq 0.18762E-08 -8.7267 0.18762E-08 -8.7267 0.10000E+01 0.0000 64 MnOH+ 0.49741E-09 -9.3033 0.41549E-09 -9.3814 0.83530E+00 -0.0782 65 MnO2-2 0.21890E-10 -10.6598 0.11262E-10 -10.9484 0.51449E+00 -0.2886 66 HMnO2- 0.22217E-09 -9.6533 0.18521E-09 -9.7323 0.83367E+00 -0.0790 69 MnCl+ 0.13555E-13 -13.8679 0.11323E-13 -13.9461 0.83530E+00 -0.0782 71 NaCl,aq 0.10230E-05 -5.9901 0.10230E-05 -5.9901 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94966E-02 -2.0224 0.79025E-02 -2.1022 0.83214E+00 -0.0798 79 HPO3-2 0.16723E-14 -14.7767 0.86038E-15 -15.0653 0.51449E+00 -0.2886 81 H2PO3- 0.15388E-18 -18.8128 0.12828E-18 -18.8918 0.83367E+00 -0.0790 82 H3PO4,aq 0.92951E-18 -18.0317 0.92951E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39963E-10 -10.3983 0.33348E-10 -10.4769 0.83448E+00 -0.0786 84 PO4-3 0.12065E-08 -8.9185 0.28832E-09 -9.5401 0.23897E+00 -0.6217 88 HP2O7-3 0.10335E-17 -17.9857 0.23513E-18 -18.6287 0.22751E+00 -0.6430 89 P2O7-4 0.10197E-16 -16.9915 0.76420E-18 -18.1168 0.74943E-01 -1.1253 90 H2S,aq 0.77653E-08 -8.1098 0.77374E-08 -8.1114 0.99640E+00 -0.0016 91 S2-2 0.45267E-14 -14.3442 0.23289E-14 -14.6328 0.51449E+00 -0.2886 97 SO3-2 0.18278E-17 -17.7381 0.95430E-18 -18.0203 0.52210E+00 -0.2822 99 HSO4- 0.54234E-19 -19.2657 0.45347E-19 -19.3435 0.83613E+00 -0.0777 Charge balance for all species = 0.5267E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9048830E-10 -.2308558E-01 -.2322669E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981161E+06 0.0000 3 Cl- 0.2191421E-03 0.2201656E-03 0.7791381E+01 6.3815 4 SO4-- 0.1248757E-11 -.2224184E-04 -.2132713E+01 8.0483 5 HCO3- 0.4504190E-06 0.2085582E-04 0.1270257E+01 3.6950 6 HS- 0.4068976E-04 0.6293936E-04 0.2077757E+01 5.6503 7 Al+++ 0.1109466E-28 0.5265647E-05 0.1418175E+00 0.7609 8 H4SiO4 0.7116544E-03 0.1417573E-01 0.1360036E+04 -3.1477 9 Ca++ 0.1438920E-06 0.2442896E-06 0.9772887E-02 13.1065 10 Mg++ 0.2284865E-10 0.9812524E-10 0.2381296E-05 9.3053 11 Fe++ 0.6250062E-13 0.3783942E-07 0.2109387E-02 6.7428 12 K+ 0.1618302E-03 0.1626069E-03 0.6346727E+01 6.2505 13 Na+ 0.2057438E-01 0.2316618E-01 0.5316203E+03 8.3540 14 Mn++ 0.2006548E-10 0.2637791E-08 0.1446522E-03 9.2498 15 HPO4-- 0.4859490E-07 0.4984135E-07 0.4775051E-02 12.6384 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6126648E+02 -.1446735E-01 -.6125201E+02 0.0000000E+00 2 H2O 0.9127245E+01 0.3478371E+02 -.2565647E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1025651E+00 -.1393860E-04 0.1025790E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1025396E+00 0.3944307E-04 -.1025790E+00 0.0000000E+00 7 Al+++ 0.1206474E+02 0.3299894E-05 0.1206474E+02 0.0000000E+00 8 H4SiO4 0.3852729E+02 0.8883697E-02 0.3851840E+02 0.0000000E+00 9 Ca++ 0.4255541E+01 0.1530923E-06 0.4255541E+01 0.0000000E+00 10 Mg++ 0.2936507E+01 0.6149348E-10 0.2936507E+01 0.0000000E+00 11 Fe++ 0.2638131E+01 0.2371334E-07 0.2638131E+01 0.0000000E+00 12 K+ 0.7855624E+00 0.1019031E-03 0.7854605E+00 0.0000000E+00 13 Na+ 0.4644560E+01 0.1451786E-01 0.4630042E+01 0.0000000E+00 14 Mn++ 0.6415279E-01 0.1653060E-08 0.6415279E-01 0.0000000E+00 15 HPO4-- 0.2189503E-01 0.3123476E-07 0.2189500E-01 0.0000000E+00 Chg. balance for solid moles: -.1117E-13 Mass of aqueous solution: 0.627822E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3699.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.627 0.665 1213. 3.084 30.01 465.7 andradite 0.4103 -0.387 208.5 2.319 5.158 54.17 grossular 0.9797E-01 -1.009 44.13 1.645 1.092 12.28 apatite-OH 0.7298E-02 -2.137 3.666 0.564 0.9069E-01 1.165 clinochlore 0.5276 -0.278 293.2 2.467 7.254 111.5 daphnite 0.1512 -0.820 107.9 2.033 2.669 32.69 chlorite-Mn 0.1283E-01 -1.892 9.096 0.959 0.2250 2.899 diopside 0.2045 -0.689 44.29 1.646 1.096 13.54 hedenbergite 0.5240E-01 -1.281 13.00 1.114 0.3216 3.561 microcline 0.6878 -0.163 191.4 2.282 4.736 74.78 stilbite 2.385 0.378 1681. 3.226 41.59 784.0 stilpnomelane-Fe 0.1953 -0.709 210.6 2.323 5.209 72.73 tr.625ac.25prg.125 0.2598E-01 -1.585 22.20 1.346 0.5493 7.147 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1855E-01 0.1855E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4042.239353 g Volume = 1636.277639 cm3 Porosity: -10.4847% V(tot) - V(min): -.15528E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3699.9990000 g log = 3.5682 Original solution: 1000.0103000 g Original solution / Rock added: 0.27 (Water/Rock Ratio), log = -0.5682 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0979 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9588E+00 0.9849 0.1037E+01 0.1053E+01 CO2,gas 0.5959E-08 1.0070 0.6588E-08 0.6542E-08 CH4,gas 0.2766E-01 1.0127 0.3075E-01 0.3036E-01 H2,gas 0.1357E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.2064E-06 0.9957 0.2257E-06 0.2266E-06 S2,gas 0.7816E-29 1.0000 0.8581E-29 0.8581E-29 CO,gas 0.2317E-13 1.0000 0.2544E-13 0.2544E-13 SO3,gas 0.1263E-47 1.0000 0.1387E-47 0.1387E-47 SO2,gas 0.7125E-27 1.0000 0.7822E-27 0.7822E-27 HCl,gas 0.4195E-17 1.0000 0.4606E-17 0.4606E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 -0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.48529E-10 67 diopside 16.22 16.22 0.00 0.000 -0.18198E-10 68 hedenbergite 14.24 14.24 0.00 0.000 -0.15165E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.54 -10.18 -3.394 0.17384E+05 -8.181 3 CH4,gas 4.81 1.30 -3.51 -0.878 0.59969E+04 -1.512 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.59 -8.65 -4.323 0.14764E+05 -6.647 6 S2,gas -7.03 -38.10 -31.07 -4.779 0.53045E+05 -29.066 7 CO,gas 3.51 -12.08 -15.59 -4.798 0.26627E+05 -13.594 8 SO3,gas 17.43 -32.43 -49.86 -12.464 0.85131E+05 -47.858 9 SO2,gas 1.14 -27.97 -29.11 -7.762 0.49699E+05 -27.107 10 HCl,gas 5.48 -13.86 -19.34 -9.668 0.33017E+05 -17.337 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80628E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94128E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.44 -4.42 -1.475 0.75541E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.44 -4.27 -1.424 0.72928E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70379E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65558E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10220E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36458E+04 66 diamond -3.11 -7.62 -4.52 -1.290 0.77117E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.62 -4.07 -1.164 0.69579E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82269E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92775E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40700E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43449E+04 143 pyrrhotite -4.24 -7.85 -3.60 -1.201 0.61517E+04 144 pyrrhotiteFe0.875 -6.00 -9.24 -3.24 -1.192 0.55344E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22436E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28298E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23228E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47145E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91027E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.85 -3.45 -1.151 0.58948E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80434E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66782E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60330E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.34 -4.38 -1.459 0.74736E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3699.9990000 g New total amount of reactant added: 3799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3301E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3799.9990000 Water: Moles liquid = 0.3423E+02 kg liquid = 0.6166E+00 Moles total = 0.7874E+01 kg total = 0.1418E+00 Activity = 1.0000 Stoichiometric ionic strength = .1180005E-01 Osmotic coef. = 0.9683 True ionic strength = .2074001E-01 Chg. balance for total moles = 0.3301E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90498E-10 -10.0434 0.75912E-10 -10.1197 0.83883E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.22271E-03 -3.6523 0.18567E-03 -3.7313 0.83367E+00 -0.0790 4 SO4-- 0.12690E-11 -11.8965 0.65429E-12 -12.1842 0.51559E+00 -0.2877 5 HCO3- 0.45772E-06 -6.3394 0.38216E-06 -6.4178 0.83491E+00 -0.0784 6 HS- 0.41353E-04 -4.3835 0.34479E-04 -4.4624 0.83379E+00 -0.0789 7 Al+++ 0.11099E-28 -28.9547 0.25223E-29 -29.5982 0.22726E+00 -0.6435 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14393E-06 -6.8419 0.73649E-07 -7.1328 0.51171E+00 -0.2910 10 Mg++ 0.22854E-10 -10.6410 0.11640E-10 -10.9340 0.50932E+00 -0.2930 11 Fe++ 0.62515E-13 -13.2040 0.31876E-13 -13.4965 0.50989E+00 -0.2925 12 K+ 0.16185E-03 -3.7909 0.13516E-03 -3.8691 0.83511E+00 -0.0783 13 Na+ 0.20577E-01 -1.6866 0.17151E-01 -1.7657 0.83351E+00 -0.0791 14 Mn++ 0.20072E-10 -10.6974 0.10243E-10 -10.9896 0.51033E+00 -0.2922 15 HPO4-- 0.48586E-07 -7.3135 0.25054E-07 -7.6011 0.51566E+00 -0.2876 16 HSiO3- 0.10972E-01 -1.9597 0.91466E-02 -2.0387 0.83367E+00 -0.0790 17 Ca(HSiO3)+ 0.18069E-07 -7.7431 0.15093E-07 -7.8212 0.83529E+00 -0.0782 18 Mg(HSiO3)+ 0.35541E-11 -11.4493 0.29687E-11 -11.5274 0.83529E+00 -0.0782 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67646E-16 -16.1698 0.56504E-16 -16.2479 0.83529E+00 -0.0782 22 HAlO2,aq 0.14895E-09 -9.8270 0.14895E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52650E-05 -5.2786 0.43812E-05 -5.3584 0.83213E+00 -0.0798 24 CH4,aq 0.19833E-04 -4.7026 0.19761E-04 -4.7042 0.99640E+00 -0.0016 25 C2H6,aq 0.62179E-14 -14.2064 0.61955E-14 -14.2079 0.99640E+00 -0.0016 29 CO,aq 0.16375E-16 -16.7858 0.16375E-16 -16.7858 0.10000E+01 0.0000 30 CO2,aq 0.58702E-10 -10.2313 0.58491E-10 -10.2329 0.99640E+00 -0.0016 31 CO3-2 0.90473E-06 -6.0435 0.46546E-06 -6.3321 0.51447E+00 -0.2886 32 CaCO3,aq 0.41985E-09 -9.3769 0.41985E-09 -9.3769 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.84902E-12 -12.0711 0.70918E-12 -12.1492 0.83529E+00 -0.0782 34 CaCl+ 0.26086E-10 -10.5836 0.21790E-10 -10.6617 0.83529E+00 -0.0782 35 CaCl2,aq 0.94198E-15 -15.0260 0.94198E-15 -15.0260 0.10000E+01 0.0000 36 CaOH+ 0.81900E-07 -7.0867 0.68411E-07 -7.1649 0.83529E+00 -0.0782 37 CaSO4,aq 0.15014E-16 -16.8235 0.15014E-16 -16.8235 0.10000E+01 0.0000 38 HCl,aq 0.26511E-14 -14.5766 0.26511E-14 -14.5766 0.10000E+01 0.0000 43 FeCl+ 0.11036E-16 -16.9572 0.92180E-17 -17.0354 0.83529E+00 -0.0782 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16666E-10 -10.7782 0.13921E-10 -10.8563 0.83529E+00 -0.0782 48 HFeO2- 0.37177E-07 -7.4297 0.30993E-07 -7.5087 0.83367E+00 -0.0790 49 FeO+ 0.12301E-16 -16.9101 0.10275E-16 -16.9882 0.83529E+00 -0.0782 51 FeO2- 0.42036E-09 -9.3764 0.35044E-09 -9.4554 0.83367E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99640E+00 -0.0016 54 KCl,aq 0.44435E-09 -9.3523 0.44435E-09 -9.3523 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.16343E-14 -14.7867 0.13625E-14 -14.8657 0.83367E+00 -0.0790 58 MgCO3,aq 0.16581E-13 -13.7804 0.16581E-13 -13.7804 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13683E-15 -15.8638 0.11430E-15 -15.9420 0.83529E+00 -0.0782 60 MgCl+ 0.37429E-14 -14.4268 0.31264E-14 -14.5050 0.83529E+00 -0.0782 61 MgOH+ 0.71711E-10 -10.1444 0.59900E-10 -10.2226 0.83529E+00 -0.0782 63 MnO,aq 0.18764E-08 -8.7267 0.18764E-08 -8.7267 0.10000E+01 0.0000 64 MnOH+ 0.49750E-09 -9.3032 0.41556E-09 -9.3814 0.83529E+00 -0.0782 65 MnO2-2 0.21888E-10 -10.6598 0.11261E-10 -10.9484 0.51447E+00 -0.2886 66 HMnO2- 0.22216E-09 -9.6533 0.18521E-09 -9.7323 0.83367E+00 -0.0790 69 MnCl+ 0.13780E-13 -13.8608 0.11510E-13 -13.9389 0.83529E+00 -0.0782 71 NaCl,aq 0.10398E-05 -5.9831 0.10398E-05 -5.9831 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94957E-02 -2.0225 0.79017E-02 -2.1023 0.83213E+00 -0.0798 79 HPO3-2 0.16720E-14 -14.7768 0.86021E-15 -15.0654 0.51447E+00 -0.2886 81 H2PO3- 0.15386E-18 -18.8129 0.12827E-18 -18.8919 0.83367E+00 -0.0790 82 H3PO4,aq 0.92951E-18 -18.0317 0.92951E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39959E-10 -10.3984 0.33345E-10 -10.4770 0.83447E+00 -0.0786 84 PO4-3 0.12062E-08 -8.9186 0.28823E-09 -9.5403 0.23896E+00 -0.6217 88 HP2O7-3 0.10332E-17 -17.9858 0.23506E-18 -18.6288 0.22750E+00 -0.6430 89 P2O7-4 0.10194E-16 -16.9917 0.76388E-18 -18.1170 0.74934E-01 -1.1253 90 H2S,aq 0.78926E-08 -8.1028 0.78642E-08 -8.1043 0.99640E+00 -0.0016 91 S2-2 0.46755E-14 -14.3302 0.24054E-14 -14.6188 0.51447E+00 -0.2886 97 SO3-2 0.18575E-17 -17.7311 0.96974E-18 -18.0133 0.52208E+00 -0.2823 99 HSO4- 0.55118E-19 -19.2587 0.46085E-19 -19.3364 0.83613E+00 -0.0777 Charge balance for all species = 0.5351E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9049833E-10 -.2308363E-01 -.2322473E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981160E+06 0.0000 3 Cl- 0.2227125E-03 0.2237527E-03 0.7918323E+01 6.3884 4 SO4-- 0.1269008E-11 -.2255997E-04 -.2163218E+01 8.0551 5 HCO3- 0.4577207E-06 0.2119562E-04 0.1290952E+01 3.7019 6 HS- 0.4135270E-04 0.6392057E-04 0.2110148E+01 5.6572 7 Al+++ 0.1109884E-28 0.5265128E-05 0.1418035E+00 0.7609 8 H4SiO4 0.7116550E-03 0.1417468E-01 0.1359935E+04 -3.1477 9 Ca++ 0.1439261E-06 0.2443419E-06 0.9774979E-02 13.1065 10 Mg++ 0.2285407E-10 0.9813957E-10 0.2381643E-05 9.3053 11 Fe++ 0.6251548E-13 0.3783579E-07 0.2109184E-02 6.7428 12 K+ 0.1618482E-03 0.1626249E-03 0.6347429E+01 6.2505 13 Na+ 0.2057668E-01 0.2316849E-01 0.5316732E+03 8.3540 14 Mn++ 0.2007158E-10 0.2638001E-08 0.1446637E-03 9.2498 15 HPO4-- 0.4858631E-07 0.4983246E-07 0.4774199E-02 12.6383 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6292233E+02 -.1423422E-01 -.6290809E+02 0.0000000E+00 2 H2O 0.7873704E+01 0.3422608E+02 -.2635237E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1053364E+00 -.1391131E-04 0.1053503E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1053109E+00 0.3941578E-04 -.1053503E+00 0.0000000E+00 7 Al+++ 0.1239081E+02 0.3246672E-05 0.1239081E+02 0.0000000E+00 8 H4SiO4 0.3956856E+02 0.8740634E-02 0.3955982E+02 0.0000000E+00 9 Ca++ 0.4370555E+01 0.1506702E-06 0.4370555E+01 0.0000000E+00 10 Mg++ 0.3015872E+01 0.6051648E-10 0.3015872E+01 0.0000000E+00 11 Fe++ 0.2709432E+01 0.2333094E-07 0.2709432E+01 0.0000000E+00 12 K+ 0.8067938E+00 0.1002805E-03 0.8066936E+00 0.0000000E+00 13 Na+ 0.4770085E+01 0.1428655E-01 0.4755798E+01 0.0000000E+00 14 Mn++ 0.6588665E-01 0.1626689E-08 0.6588665E-01 0.0000000E+00 15 HPO4-- 0.2248679E-01 0.3072854E-07 0.2248675E-01 0.0000000E+00 Chg. balance for solid moles: 0.1479E-13 Mass of aqueous solution: 0.617757E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.752 0.677 1246. 3.096 30.02 478.4 andradite 0.4214 -0.375 214.1 2.331 5.158 55.64 grossular 0.1006 -0.997 45.32 1.656 1.092 12.61 apatite-OH 0.7496E-02 -2.125 3.765 0.576 0.9069E-01 1.196 clinochlore 0.5418 -0.266 301.1 2.479 7.254 114.5 daphnite 0.1553 -0.809 110.8 2.045 2.669 33.57 chlorite-Mn 0.1318E-01 -1.880 9.342 0.970 0.2250 2.977 diopside 0.2103 -0.677 45.55 1.658 1.097 13.92 hedenbergite 0.5388E-01 -1.269 13.37 1.126 0.3220 3.661 microcline 0.7064 -0.151 196.6 2.294 4.736 76.80 stilbite 2.450 0.389 1726. 3.237 41.58 805.1 stilpnomelane-Fe 0.2006 -0.698 216.3 2.335 5.209 74.70 tr.625ac.25prg.125 0.2666E-01 -1.574 22.79 1.358 0.5489 7.334 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1855E-01 0.1855E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4151.494835 g Volume = 1680.483996 cm3 Porosity: -10.4855% V(tot) - V(min): -.15948E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3799.9990000 g log = 3.5798 Original solution: 1000.0103000 g Original solution / Rock added: 0.26 (Water/Rock Ratio), log = -0.5798 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0984 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9583E+00 0.9849 0.1037E+01 0.1053E+01 CO2,gas 0.6053E-08 1.0070 0.6695E-08 0.6649E-08 CH4,gas 0.2810E-01 1.0127 0.3125E-01 0.3086E-01 H2,gas 0.1357E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.2097E-06 0.9957 0.2294E-06 0.2303E-06 S2,gas 0.8071E-29 1.0000 0.8865E-29 0.8865E-29 CO,gas 0.2354E-13 1.0000 0.2586E-13 0.2586E-13 SO3,gas 0.1283E-47 1.0000 0.1410E-47 0.1410E-47 SO2,gas 0.7238E-27 1.0000 0.7950E-27 0.7950E-27 HCl,gas 0.4262E-17 1.0000 0.4681E-17 0.4681E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.54 -10.17 -3.391 0.17372E+05 -8.174 3 CH4,gas 4.81 1.30 -3.51 -0.876 0.59849E+04 -1.505 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.58 -8.64 -4.320 0.14752E+05 -6.639 6 S2,gas -7.03 -38.08 -31.05 -4.777 0.53021E+05 -29.052 7 CO,gas 3.51 -12.08 -15.59 -4.796 0.26615E+05 -13.587 8 SO3,gas 17.43 -32.42 -49.85 -12.463 0.85119E+05 -47.851 9 SO2,gas 1.14 -27.96 -29.10 -7.760 0.49687E+05 -27.100 10 HCl,gas 5.48 -13.85 -19.33 -9.665 0.33005E+05 -17.330 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80626E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94128E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.43 -4.42 -1.472 0.75421E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.43 -4.26 -1.421 0.72808E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70379E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65557E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.62 -4.51 -1.288 0.76997E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.62 -4.07 -1.162 0.69459E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82269E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92776E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40700E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43449E+04 143 pyrrhotite -4.24 -7.84 -3.60 -1.199 0.61396E+04 144 pyrrhotiteFe0.875 -6.00 -9.24 -3.23 -1.189 0.55224E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22436E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28298E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23228E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47144E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91027E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.84 -3.45 -1.148 0.58828E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80434E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66782E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60330E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.33 -4.37 -1.457 0.74615E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3799.9990000 g New total amount of reactant added: 3899.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3299E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3899.9990000 Water: Moles liquid = 0.3367E+02 kg liquid = 0.6066E+00 Moles total = 0.6620E+01 kg total = 0.1193E+00 Activity = 1.0000 Stoichiometric ionic strength = .1180313E-01 Osmotic coef. = 0.9683 True ionic strength = .2074241E-01 Chg. balance for total moles = 0.3299E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90509E-10 -10.0433 0.75921E-10 -10.1196 0.83882E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.22640E-03 -3.6451 0.18874E-03 -3.7241 0.83366E+00 -0.0790 4 SO4-- 0.12899E-11 -11.8894 0.66505E-12 -12.1771 0.51557E+00 -0.2877 5 HCO3- 0.46526E-06 -6.3323 0.38845E-06 -6.4107 0.83490E+00 -0.0784 6 HS- 0.42038E-04 -4.3764 0.35050E-04 -4.4553 0.83378E+00 -0.0789 7 Al+++ 0.11103E-28 -28.9546 0.25231E-29 -29.5981 0.22724E+00 -0.6435 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14396E-06 -6.8418 0.73665E-07 -7.1327 0.51170E+00 -0.2910 10 Mg++ 0.22860E-10 -10.6409 0.11643E-10 -10.9339 0.50931E+00 -0.2930 11 Fe++ 0.62531E-13 -13.2039 0.31883E-13 -13.4964 0.50988E+00 -0.2925 12 K+ 0.16187E-03 -3.7908 0.13518E-03 -3.8691 0.83510E+00 -0.0783 13 Na+ 0.20579E-01 -1.6866 0.17153E-01 -1.7657 0.83350E+00 -0.0791 14 Mn++ 0.20078E-10 -10.6973 0.10246E-10 -10.9895 0.51031E+00 -0.2922 15 HPO4-- 0.48577E-07 -7.3136 0.25049E-07 -7.6012 0.51565E+00 -0.2876 16 HSiO3- 0.10970E-01 -1.9598 0.91456E-02 -2.0388 0.83366E+00 -0.0790 17 Ca(HSiO3)+ 0.18071E-07 -7.7430 0.15095E-07 -7.8212 0.83529E+00 -0.0782 18 Mg(HSiO3)+ 0.35545E-11 -11.4492 0.29690E-11 -11.5274 0.83529E+00 -0.0782 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67653E-16 -16.1697 0.56510E-16 -16.2479 0.83529E+00 -0.0782 22 HAlO2,aq 0.14895E-09 -9.8270 0.14895E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52644E-05 -5.2786 0.43807E-05 -5.3585 0.83213E+00 -0.0798 24 CH4,aq 0.20161E-04 -4.6955 0.20089E-04 -4.6970 0.99640E+00 -0.0016 25 C2H6,aq 0.64257E-14 -14.1921 0.64026E-14 -14.1936 0.99640E+00 -0.0016 29 CO,aq 0.16647E-16 -16.7787 0.16647E-16 -16.7787 0.10000E+01 0.0000 30 CO2,aq 0.59675E-10 -10.2242 0.59460E-10 -10.2258 0.99640E+00 -0.0016 31 CO3-2 0.91956E-06 -6.0364 0.47307E-06 -6.3251 0.51446E+00 -0.2887 32 CaCO3,aq 0.42681E-09 -9.3698 0.42681E-09 -9.3698 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.86320E-12 -12.0639 0.72102E-12 -12.1421 0.83529E+00 -0.0782 34 CaCl+ 0.26524E-10 -10.5764 0.22155E-10 -10.6545 0.83529E+00 -0.0782 35 CaCl2,aq 0.97363E-15 -15.0116 0.97363E-15 -15.0116 0.10000E+01 0.0000 36 CaOH+ 0.81909E-07 -7.0867 0.68418E-07 -7.1648 0.83529E+00 -0.0782 37 CaSO4,aq 0.15264E-16 -16.8163 0.15264E-16 -16.8163 0.10000E+01 0.0000 38 HCl,aq 0.26953E-14 -14.5694 0.26953E-14 -14.5694 0.10000E+01 0.0000 43 FeCl+ 0.11221E-16 -16.9500 0.93726E-17 -17.0281 0.83529E+00 -0.0782 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16668E-10 -10.7781 0.13922E-10 -10.8563 0.83529E+00 -0.0782 48 HFeO2- 0.37173E-07 -7.4298 0.30990E-07 -7.5088 0.83366E+00 -0.0790 49 FeO+ 0.12303E-16 -16.9100 0.10276E-16 -16.9882 0.83529E+00 -0.0782 51 FeO2- 0.42032E-09 -9.3764 0.35040E-09 -9.4554 0.83366E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99640E+00 -0.0016 54 KCl,aq 0.45175E-09 -9.3451 0.45175E-09 -9.3451 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.16614E-14 -14.7795 0.13850E-14 -14.8585 0.83366E+00 -0.0790 58 MgCO3,aq 0.16856E-13 -13.7732 0.16856E-13 -13.7732 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.13912E-15 -15.8566 0.11620E-15 -15.9348 0.83529E+00 -0.0782 60 MgCl+ 0.38057E-14 -14.4196 0.31788E-14 -14.4977 0.83529E+00 -0.0782 61 MgOH+ 0.71719E-10 -10.1444 0.59906E-10 -10.2225 0.83529E+00 -0.0782 63 MnO,aq 0.18765E-08 -8.7267 0.18765E-08 -8.7267 0.10000E+01 0.0000 64 MnOH+ 0.49759E-09 -9.3031 0.41563E-09 -9.3813 0.83529E+00 -0.0782 65 MnO2-2 0.21885E-10 -10.6599 0.11259E-10 -10.9485 0.51446E+00 -0.2887 66 HMnO2- 0.22215E-09 -9.6534 0.18520E-09 -9.7324 0.83366E+00 -0.0790 69 MnCl+ 0.14012E-13 -13.8535 0.11704E-13 -13.9317 0.83529E+00 -0.0782 71 NaCl,aq 0.10571E-05 -5.9759 0.10571E-05 -5.9759 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94947E-02 -2.0225 0.79008E-02 -2.1023 0.83213E+00 -0.0798 79 HPO3-2 0.16717E-14 -14.7768 0.86002E-15 -15.0655 0.51446E+00 -0.2887 81 H2PO3- 0.15385E-18 -18.8129 0.12826E-18 -18.8919 0.83366E+00 -0.0790 82 H3PO4,aq 0.92951E-18 -18.0317 0.92951E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39955E-10 -10.3984 0.33341E-10 -10.4770 0.83447E+00 -0.0786 84 PO4-3 0.12059E-08 -8.9187 0.28814E-09 -9.5404 0.23894E+00 -0.6217 88 HP2O7-3 0.10330E-17 -17.9859 0.23498E-18 -18.6290 0.22748E+00 -0.6431 89 P2O7-4 0.10191E-16 -16.9918 0.76356E-18 -18.1172 0.74925E-01 -1.1254 90 H2S,aq 0.80241E-08 -8.0956 0.79953E-08 -8.0972 0.99640E+00 -0.0016 91 S2-2 0.48317E-14 -14.3159 0.24857E-14 -14.6046 0.51446E+00 -0.2887 97 SO3-2 0.18881E-17 -17.7240 0.98569E-18 -18.0063 0.52207E+00 -0.2823 99 HSO4- 0.56031E-19 -19.2516 0.46849E-19 -19.3293 0.83612E+00 -0.0777 Charge balance for all species = 0.5443E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9050869E-10 -.2308162E-01 -.2322271E+02 0.0000 2 H2O 0.1000000E+01 0.5550442E+02 0.9981158E+06 0.0000 3 Cl- 0.2264011E-03 0.2274586E-03 0.8049470E+01 6.3955 4 SO4-- 0.1289926E-11 -.2288864E-04 -.2194733E+01 8.0621 5 HCO3- 0.4652627E-06 0.2154667E-04 0.1312334E+01 3.7090 6 HS- 0.4203761E-04 0.6493428E-04 0.2143613E+01 5.6643 7 Al+++ 0.1110316E-28 0.5264594E-05 0.1417891E+00 0.7609 8 H4SiO4 0.7116555E-03 0.1417360E-01 0.1359832E+04 -3.1477 9 Ca++ 0.1439613E-06 0.2443960E-06 0.9777141E-02 13.1065 10 Mg++ 0.2285968E-10 0.9815292E-10 0.2381967E-05 9.3053 11 Fe++ 0.6253083E-13 0.3783205E-07 0.2108975E-02 6.7428 12 K+ 0.1618668E-03 0.1626435E-03 0.6348154E+01 6.2505 13 Na+ 0.2057904E-01 0.2317087E-01 0.5317279E+03 8.3540 14 Mn++ 0.2007778E-10 0.2638203E-08 0.1446748E-03 9.2498 15 HPO4-- 0.4857743E-07 0.4982328E-07 0.4773318E-02 12.6381 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6457818E+02 -.1400108E-01 -.6456418E+02 0.0000000E+00 2 H2O 0.6620163E+01 0.3366844E+02 -.2704828E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1081078E+00 -.1388403E-04 0.1081217E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1080823E+00 0.3938850E-04 -.1081217E+00 0.0000000E+00 7 Al+++ 0.1271689E+02 0.3193451E-05 0.1271689E+02 0.0000000E+00 8 H4SiO4 0.4060984E+02 0.8597570E-02 0.4060125E+02 0.0000000E+00 9 Ca++ 0.4485570E+01 0.1482482E-06 0.4485570E+01 0.0000000E+00 10 Mg++ 0.3095237E+01 0.5953860E-10 0.3095237E+01 0.0000000E+00 11 Fe++ 0.2780733E+01 0.2294855E-07 0.2780733E+01 0.0000000E+00 12 K+ 0.8280253E+00 0.9865794E-04 0.8279266E+00 0.0000000E+00 13 Na+ 0.4895609E+01 0.1405523E-01 0.4881554E+01 0.0000000E+00 14 Mn++ 0.6762051E-01 0.1600308E-08 0.6762051E-01 0.0000000E+00 15 HPO4-- 0.2307854E-01 0.3022231E-07 0.2307851E-01 0.0000000E+00 Chg. balance for solid moles: -.1514E-13 Mass of aqueous solution: 0.607692E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3899.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 4.878 0.688 1279. 3.107 30.02 491.0 andradite 0.4325 -0.364 219.8 2.342 5.158 57.10 grossular 0.1033 -0.986 46.51 1.668 1.092 12.94 apatite-OH 0.7693E-02 -2.114 3.864 0.587 0.9069E-01 1.228 clinochlore 0.5560 -0.255 309.0 2.490 7.253 117.6 daphnite 0.1594 -0.798 113.7 2.056 2.669 34.45 chlorite-Mn 0.1352E-01 -1.869 9.588 0.982 0.2250 3.056 diopside 0.2161 -0.665 46.80 1.670 1.098 14.30 hedenbergite 0.5536E-01 -1.257 13.74 1.138 0.3224 3.762 microcline 0.7250 -0.140 201.8 2.305 4.736 78.82 stilbite 2.514 0.400 1771. 3.248 41.58 826.2 stilpnomelane-Fe 0.2059 -0.686 221.9 2.346 5.209 76.67 tr.625ac.25prg.125 0.2734E-01 -1.563 23.37 1.369 0.5485 7.522 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1855E-01 0.1855E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4260.750317 g Volume = 1724.690353 cm3 Porosity: -10.4863% V(tot) - V(min): -.16369E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3899.9990000 g log = 3.5911 Original solution: 1000.0103000 g Original solution / Rock added: 0.26 (Water/Rock Ratio), log = -0.5911 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0989 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9579E+00 0.9849 0.1037E+01 0.1053E+01 CO2,gas 0.6151E-08 1.0070 0.6806E-08 0.6759E-08 CH4,gas 0.2855E-01 1.0127 0.3177E-01 0.3137E-01 H2,gas 0.1356E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.2131E-06 0.9957 0.2332E-06 0.2342E-06 S2,gas 0.8338E-29 1.0000 0.9162E-29 0.9162E-29 CO,gas 0.2392E-13 1.0000 0.2629E-13 0.2629E-13 SO3,gas 0.1304E-47 1.0000 0.1433E-47 0.1433E-47 SO2,gas 0.7356E-27 1.0000 0.8083E-27 0.8083E-27 HCl,gas 0.4331E-17 1.0000 0.4759E-17 0.4759E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 -0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.53 -10.17 -3.389 0.17360E+05 -8.167 3 CH4,gas 4.81 1.31 -3.50 -0.875 0.59728E+04 -1.498 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.57 -8.63 -4.316 0.14739E+05 -6.632 6 S2,gas -7.03 -38.07 -31.04 -4.775 0.52997E+05 -29.038 7 CO,gas 3.51 -12.07 -15.58 -4.794 0.26603E+05 -13.580 8 SO3,gas 17.43 -32.42 -49.84 -12.461 0.85107E+05 -47.844 9 SO2,gas 1.14 -27.96 -29.09 -7.758 0.49675E+05 -27.092 10 HCl,gas 5.48 -13.84 -19.32 -9.661 0.32993E+05 -17.322 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80625E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94128E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.42 -4.41 -1.470 0.75299E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.42 -4.26 -1.419 0.72686E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70379E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65557E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.61 -4.50 -1.286 0.76875E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.61 -4.06 -1.160 0.69337E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82268E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92776E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40700E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43449E+04 143 pyrrhotite -4.24 -7.83 -3.59 -1.196 0.61273E+04 144 pyrrhotiteFe0.875 -6.00 -9.23 -3.23 -1.187 0.55101E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22435E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28298E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23227E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47143E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91027E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.83 -3.44 -1.146 0.58705E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80434E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66782E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60330E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.33 -4.36 -1.454 0.74492E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3899.9990000 g New total amount of reactant added: 3999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.3299E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 11 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3999.9990000 Water: Moles liquid = 0.3311E+02 kg liquid = 0.5965E+00 Moles total = 0.5367E+01 kg total = 0.9668E-01 Activity = 1.0000 Stoichiometric ionic strength = .1180631E-01 Osmotic coef. = 0.9683 True ionic strength = .2074490E-01 Chg. balance for total moles = 0.3299E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90519E-10 -10.0433 0.75929E-10 -10.1196 0.83881E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.23021E-03 -3.6379 0.19192E-03 -3.7169 0.83365E+00 -0.0790 4 SO4-- 0.13115E-11 -11.8822 0.67618E-12 -12.1699 0.51556E+00 -0.2877 5 HCO3- 0.47306E-06 -6.3251 0.39495E-06 -6.4035 0.83490E+00 -0.0784 6 HS- 0.42746E-04 -4.3691 0.35640E-04 -4.4481 0.83378E+00 -0.0789 7 Al+++ 0.11108E-28 -28.9544 0.25239E-29 -29.5979 0.22722E+00 -0.6435 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14400E-06 -6.8416 0.73681E-07 -7.1326 0.51168E+00 -0.2910 10 Mg++ 0.22865E-10 -10.6408 0.11645E-10 -10.9339 0.50929E+00 -0.2930 11 Fe++ 0.62547E-13 -13.2038 0.31890E-13 -13.4963 0.50986E+00 -0.2925 12 K+ 0.16189E-03 -3.7908 0.13519E-03 -3.8691 0.83510E+00 -0.0783 13 Na+ 0.20581E-01 -1.6865 0.17155E-01 -1.7656 0.83349E+00 -0.0791 14 Mn++ 0.20084E-10 -10.6971 0.10249E-10 -10.9893 0.51029E+00 -0.2922 15 HPO4-- 0.48568E-07 -7.3136 0.25043E-07 -7.6013 0.51563E+00 -0.2877 16 HSiO3- 0.10969E-01 -1.9598 0.91446E-02 -2.0388 0.83365E+00 -0.0790 17 Ca(HSiO3)+ 0.18073E-07 -7.7430 0.15096E-07 -7.8211 0.83528E+00 -0.0782 18 Mg(HSiO3)+ 0.35549E-11 -11.4492 0.29693E-11 -11.5273 0.83528E+00 -0.0782 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67661E-16 -16.1697 0.56516E-16 -16.2478 0.83528E+00 -0.0782 22 HAlO2,aq 0.14895E-09 -9.8270 0.14895E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52639E-05 -5.2787 0.43802E-05 -5.3585 0.83212E+00 -0.0798 24 CH4,aq 0.20501E-04 -4.6882 0.20427E-04 -4.6898 0.99640E+00 -0.0016 25 C2H6,aq 0.66441E-14 -14.1776 0.66202E-14 -14.1791 0.99640E+00 -0.0016 29 CO,aq 0.16927E-16 -16.7714 0.16927E-16 -16.7714 0.10000E+01 0.0000 30 CO2,aq 0.60681E-10 -10.2169 0.60463E-10 -10.2185 0.99640E+00 -0.0016 31 CO3-2 0.93488E-06 -6.0292 0.48094E-06 -6.3179 0.51444E+00 -0.2887 32 CaCO3,aq 0.43401E-09 -9.3625 0.43401E-09 -9.3625 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.87785E-12 -12.0566 0.73325E-12 -12.1347 0.83528E+00 -0.0782 34 CaCl+ 0.26977E-10 -10.5690 0.22533E-10 -10.6472 0.83528E+00 -0.0782 35 CaCl2,aq 0.10069E-14 -14.9970 0.10069E-14 -14.9970 0.10000E+01 0.0000 36 CaOH+ 0.81919E-07 -7.0866 0.68425E-07 -7.1648 0.83528E+00 -0.0782 37 CaSO4,aq 0.15523E-16 -16.8090 0.15523E-16 -16.8090 0.10000E+01 0.0000 38 HCl,aq 0.27410E-14 -14.5621 0.27410E-14 -14.5621 0.10000E+01 0.0000 43 FeCl+ 0.11412E-16 -16.9426 0.95324E-17 -17.0208 0.83528E+00 -0.0782 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16670E-10 -10.7781 0.13924E-10 -10.8562 0.83528E+00 -0.0782 48 HFeO2- 0.37169E-07 -7.4298 0.30986E-07 -7.5088 0.83365E+00 -0.0790 49 FeO+ 0.12304E-16 -16.9100 0.10277E-16 -16.9881 0.83528E+00 -0.0782 51 FeO2- 0.42027E-09 -9.3765 0.35036E-09 -9.4555 0.83365E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99640E+00 -0.0016 54 KCl,aq 0.45941E-09 -9.3378 0.45941E-09 -9.3378 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.16894E-14 -14.7723 0.14083E-14 -14.8513 0.83365E+00 -0.0790 58 MgCO3,aq 0.17140E-13 -13.7660 0.17140E-13 -13.7660 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14148E-15 -15.8493 0.11818E-15 -15.9275 0.83528E+00 -0.0782 60 MgCl+ 0.38706E-14 -14.4122 0.32331E-14 -14.4904 0.83528E+00 -0.0782 61 MgOH+ 0.71728E-10 -10.1443 0.59913E-10 -10.2225 0.83528E+00 -0.0782 63 MnO,aq 0.18766E-08 -8.7266 0.18766E-08 -8.7266 0.10000E+01 0.0000 64 MnOH+ 0.49768E-09 -9.3031 0.41570E-09 -9.3812 0.83528E+00 -0.0782 65 MnO2-2 0.21882E-10 -10.6599 0.11257E-10 -10.9486 0.51444E+00 -0.2887 66 HMnO2- 0.22214E-09 -9.6534 0.18519E-09 -9.7324 0.83365E+00 -0.0790 69 MnCl+ 0.14252E-13 -13.8461 0.11904E-13 -13.9243 0.83528E+00 -0.0782 71 NaCl,aq 0.10750E-05 -5.9686 0.10750E-05 -5.9686 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94937E-02 -2.0226 0.78999E-02 -2.1024 0.83212E+00 -0.0798 79 HPO3-2 0.16714E-14 -14.7769 0.85983E-15 -15.0656 0.51444E+00 -0.2887 81 H2PO3- 0.15383E-18 -18.8130 0.12824E-18 -18.8920 0.83365E+00 -0.0790 82 H3PO4,aq 0.92951E-18 -18.0317 0.92951E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39951E-10 -10.3985 0.33337E-10 -10.4771 0.83446E+00 -0.0786 84 PO4-3 0.12056E-08 -8.9188 0.28804E-09 -9.5405 0.23893E+00 -0.6217 88 HP2O7-3 0.10327E-17 -17.9860 0.23491E-18 -18.6291 0.22746E+00 -0.6431 89 P2O7-4 0.10188E-16 -16.9919 0.76322E-18 -18.1173 0.74916E-01 -1.1254 90 H2S,aq 0.81601E-08 -8.0883 0.81307E-08 -8.0899 0.99640E+00 -0.0016 91 S2-2 0.49959E-14 -14.3014 0.25701E-14 -14.5901 0.51444E+00 -0.2887 97 SO3-2 0.19197E-17 -17.7168 0.10022E-17 -17.9991 0.52205E+00 -0.2823 99 HSO4- 0.56975E-19 -19.2443 0.47638E-19 -19.3220 0.83611E+00 -0.0777 Charge balance for all species = 0.5530E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9051940E-10 -.2307954E-01 -.2322061E+02 0.0000 2 H2O 0.1000000E+01 0.5550443E+02 0.9981157E+06 0.0000 3 Cl- 0.2302139E-03 0.2312894E-03 0.8185034E+01 6.4027 4 SO4-- 0.1311544E-11 -.2322839E-04 -.2227310E+01 8.0692 5 HCO3- 0.4730572E-06 0.2190955E-04 0.1334435E+01 3.7161 6 HS- 0.4274559E-04 0.6598214E-04 0.2178204E+01 5.6715 7 Al+++ 0.1110763E-28 0.5264043E-05 0.1417742E+00 0.7609 8 H4SiO4 0.7116560E-03 0.1417249E-01 0.1359724E+04 -3.1477 9 Ca++ 0.1439978E-06 0.2444519E-06 0.9779377E-02 13.1065 10 Mg++ 0.2286547E-10 0.9816894E-10 0.2382356E-05 9.3053 11 Fe++ 0.6254671E-13 0.3782818E-07 0.2108759E-02 6.7428 12 K+ 0.1618860E-03 0.1626627E-03 0.6348904E+01 6.2505 13 Na+ 0.2058149E-01 0.2317334E-01 0.5317845E+03 8.3540 14 Mn++ 0.2008408E-10 0.2638398E-08 0.1446855E-03 9.2499 15 HPO4-- 0.4856826E-07 0.4981378E-07 0.4772407E-02 12.6379 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6623403E+02 -.1376795E-01 -.6622026E+02 0.0000000E+00 2 H2O 0.5366622E+01 0.3311080E+02 -.2774418E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1108791E+00 -.1385675E-04 0.1108930E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1108536E+00 0.3936122E-04 -.1108930E+00 0.0000000E+00 7 Al+++ 0.1304296E+02 0.3140231E-05 0.1304296E+02 0.0000000E+00 8 H4SiO4 0.4165112E+02 0.8454505E-02 0.4164267E+02 0.0000000E+00 9 Ca++ 0.4600584E+01 0.1458262E-06 0.4600584E+01 0.0000000E+00 10 Mg++ 0.3174602E+01 0.5856204E-10 0.3174602E+01 0.0000000E+00 11 Fe++ 0.2852034E+01 0.2256615E-07 0.2852034E+01 0.0000000E+00 12 K+ 0.8492567E+00 0.9703538E-04 0.8491597E+00 0.0000000E+00 13 Na+ 0.5021133E+01 0.1382391E-01 0.5007309E+01 0.0000000E+00 14 Mn++ 0.6935437E-01 0.1573919E-08 0.6935437E-01 0.0000000E+00 15 HPO4-- 0.2367030E-01 0.2971608E-07 0.2367027E-01 0.0000000E+00 Chg. balance for solid moles: 0.1808E-13 Mass of aqueous solution: 0.597627E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.004 0.699 1312. 3.118 30.03 503.7 andradite 0.4436 -0.353 225.4 2.353 5.158 58.56 grossular 0.1059 -0.975 47.71 1.679 1.092 13.27 apatite-OH 0.7890E-02 -2.103 3.963 0.598 0.9069E-01 1.259 clinochlore 0.5702 -0.244 316.9 2.501 7.253 120.6 daphnite 0.1634 -0.787 116.6 2.067 2.668 35.34 chlorite-Mn 0.1387E-01 -1.858 9.834 0.993 0.2250 3.134 diopside 0.2219 -0.654 48.05 1.682 1.100 14.69 hedenbergite 0.5684E-01 -1.245 14.10 1.149 0.3227 3.863 microcline 0.7436 -0.129 207.0 2.316 4.736 80.85 stilbite 2.578 0.411 1817. 3.259 41.57 847.3 stilpnomelane-Fe 0.2112 -0.675 227.6 2.357 5.209 78.63 tr.625ac.25prg.125 0.2802E-01 -1.552 23.95 1.379 0.5481 7.709 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1856E-01 0.1856E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4370.005799 g Volume = 1768.896710 cm3 Porosity: -10.4870% V(tot) - V(min): -.16790E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3999.9990000 g log = 3.6021 Original solution: 1000.0103000 g Original solution / Rock added: 0.25 (Water/Rock Ratio), log = -0.6021 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0994 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9574E+00 0.9849 0.1037E+01 0.1053E+01 CO2,gas 0.6252E-08 1.0070 0.6921E-08 0.6873E-08 CH4,gas 0.2901E-01 1.0127 0.3230E-01 0.3190E-01 H2,gas 0.1355E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.2166E-06 0.9957 0.2371E-06 0.2382E-06 S2,gas 0.8619E-29 1.0000 0.9476E-29 0.9476E-29 CO,gas 0.2431E-13 1.0000 0.2673E-13 0.2673E-13 SO3,gas 0.1326E-47 1.0000 0.1457E-47 0.1457E-47 SO2,gas 0.7477E-27 1.0000 0.8220E-27 0.8220E-27 HCl,gas 0.4402E-17 1.0000 0.4840E-17 0.4840E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.23980E-10 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.52 -10.16 -3.387 0.17348E+05 -8.160 3 CH4,gas 4.81 1.32 -3.49 -0.873 0.59604E+04 -1.491 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.57 -8.62 -4.312 0.14727E+05 -6.625 6 S2,gas -7.03 -38.06 -31.02 -4.773 0.52972E+05 -29.023 7 CO,gas 3.51 -12.06 -15.57 -4.792 0.26591E+05 -13.573 8 SO3,gas 17.43 -32.41 -49.84 -12.459 0.85094E+05 -47.836 9 SO2,gas 1.14 -27.95 -29.09 -7.756 0.49662E+05 -27.085 10 HCl,gas 5.48 -13.84 -19.32 -9.658 0.32980E+05 -17.315 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80624E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94128E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.42 -4.40 -1.468 0.75175E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.42 -4.25 -1.417 0.72562E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70379E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65556E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.60 -4.50 -1.284 0.76751E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.60 -4.05 -1.158 0.69213E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82268E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92776E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40700E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43449E+04 143 pyrrhotite -4.24 -7.82 -3.58 -1.194 0.61149E+04 144 pyrrhotiteFe0.875 -6.00 -9.22 -3.22 -1.184 0.54976E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22435E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28298E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23227E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47142E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91027E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.82 -3.43 -1.144 0.58581E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80434E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66782E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60330E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.32 -4.36 -1.452 0.74367E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 100.0000000 g Current total amount of reactant added: 3999.9990000 g New total amount of reactant added: 4099.9990000 g Mixing fraction reached given limit of 0.4000E+04 TOTMIX = 0.4100E+04 Execution stopped.