File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.66234E+02 0.90519E-10 0.8388 0.00000000E+00 H2O 2 0. 0.53666E+01 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.23021E-03 0.8337 0.00000000E+00 SO4-- 4 -2. 0.11088E+00 0.13115E-11 0.5156 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.47306E-06 0.8349 0.00000000E+00 HS- 6 -1. -0.11085E+00 0.42746E-04 0.8338 0.00000000E+00 Al+++ 7 3. 0.13043E+02 0.11108E-28 0.2272 0.00000000E+00 H4SiO4 8 0. 0.41651E+02 0.71166E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.46006E+01 0.14400E-06 0.5117 0.00000000E+00 Mg++ 10 2. 0.31746E+01 0.22865E-10 0.5093 0.00000000E+00 Fe++ 11 2. 0.28520E+01 0.62547E-13 0.5099 0.00000000E+00 K+ 12 1. 0.84926E+00 0.16189E-03 0.8351 0.00000000E+00 Na+ 13 1. 0.50211E+01 0.20581E-01 0.8335 0.00000000E+00 Mn++ 14 2. 0.69354E-01 0.20084E-10 0.5103 0.00000000E+00 HPO4-- 15 -2. 0.23670E-01 0.48568E-07 0.5156 0.00000000E+00 Chg. balance for total moles = -.1299E-10 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 100.0000 SLIM = 0.800000E+04 TEMP = 100.0000 SINC = 0.2000E+03 TEMPC = 0.0000 TOTMIX = 0.400000E+04 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 1600.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0107 MnO2-2 65 -2. 40.4376 Ca(HSiO3)+ 17 1. 7.6603 HMnO2- 66 -1. 29.1018 Mg(HSiO3)+ 18 1. 7.5653 MnO4- 67 -1. 83.3383 NaHSiO3,aq 19 0. 7.8098 MnO4-2 68 -2. 81.3024 AlO+ 20 1. 6.8891 MnCl+ 69 1. -0.7819 AlOH+2 21 2. 3.1893 MnSO4,aq 70 0. -2.4524 HAlO2,aq 22 0. 10.5878 NaCl,aq 71 0. 0.4861 AlO2- 23 -1. 16.2390 NaOH,aq 72 0. 12.3571 CH4,aq 24 0. 6.0082 O2,aq 73 0. 53.5759 C2H6,aq 25 0. 12.3556 OH- 74 -1. 12.2220 C3H8,aq 26 0. 17.3423 HO2- 75 -1. 50.7897 C4H10,aq 27 0. 22.3397 H2O2,aq 76 0. 40.0297 ethanol,aq 28 0. 15.3114 H3PO2,aq 77 0. 24.3310 CO,aq 29 0. 4.7087 H2PO2- 78 -1. 26.5491 CO2,aq 30 0. -6.3045 HPO3-2 79 -2. 11.9246 CO3-2 31 -2. 10.0340 H3PO3,aq 80 0. 3.5932 CaCO3,aq 32 0. 5.9460 H2PO3- 81 -1. 5.6314 Ca(HCO3)+ 33 1. -1.4013 H3PO4,aq 82 0. -9.8087 CaCl+ 34 1. -0.2023 H2PO4- 83 -1. -7.2438 CaCl2,aq 35 0. 0.4306 PO4-3 84 -3. 12.0588 CaOH+ 36 1. 10.1517 H4P2O7,aq 85 0. -17.7539 CaSO4,aq 37 0. -2.4936 H3P2O7- 86 -1. -15.8646 HCl,aq 38 0. 0.7256 H2P2O7-2 87 -2. -13.3812 HClO,aq 39 0. 32.4377 HP2O7-3 88 -3. -6.6931 ClO- 40 -1. 39.6416 P2O7-4 89 -4. 2.9147 HClO2,aq 41 0. 70.2060 H2S,aq 90 0. -6.4778 Fe+3 42 3. 8.3763 S2-2 91 -2. 1.2336 FeCl+ 43 1. -0.1924 S3-2 92 -2. -8.7963 FeCl2,aq 44 0. 4.3160 S3- 93 -1. -16.3178 FeCl+2 45 2. 6.5223 S4-2 94 -2. -18.6473 FeO,aq 46 0. 16.4029 S5-2 95 -2. -28.3223 FeOH+ 47 1. 7.4795 SO2,aq 96 0. -0.1980 HFeO2- 48 -1. 24.3713 SO3-2 97 -2. 10.2895 FeO+ 49 1. 11.3812 HSO3- 98 -1. 2.5222 FeOH+2 50 2. 9.1115 HSO4- 99 -1. -2.9675 FeO2- 51 -1. 24.0877 HSO5- 100 -1. 38.8657 HFeO2,aq 52 0. 15.9903 S2O3-2 101 -2. -4.5491 H2,aq 53 0. 9.4241 HS2O3- 102 -1. -6.8007 KCl,aq 54 0. 1.7519 H2S2O3,aq 103 0. -7.9944 KHSO4,aq 55 0. -0.4275 S2O4-2 104 -2. 10.5639 KOH,aq 56 0. 12.3606 HS2O4- 105 -1. 7.6762 KSO4- 57 -1. -1.1877 H2S2O4,aq 106 0. 6.6566 MgCO3,aq 58 0. 6.5483 S2O5-2 107 -2. 10.0891 Mg(HCO3)+ 59 1. -1.4098 S2O6-2 108 -2. 11.5737 MgCl+ 60 1. -0.1603 S2O8-2 109 -2. 42.1139 MgOH+ 61 1. 9.4082 S3O6-2 110 -2. 3.8101 Mn+3 62 3. 19.1332 S4O6-2 111 -2. -17.8301 MnO,aq 63 0. 17.9765 S5O6-2 112 -2. -14.1051 MnOH+ 64 1. 8.5115 113 0. 10.3157 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.984 0.0000E+00 osumilite(2) 124 20.895 0.0000E+00 CO2,gas 2 -6.363 0.0000E+00 osumilite-Fe 125 14.657 0.0000E+00 CH4,gas 3 4.809 0.0000E+00 pargasite 126 65.279 0.0000E+00 H2,gas 4 8.287 0.0000E+00 periclase 127 16.149 0.0000E+00 H2S,gas 5 -5.943 0.0000E+00 periclase-Fe 128 11.639 0.0000E+00 S2,gas 6 -7.033 0.0000E+00 perovskite-Al 129 12.395 0.0000E+00 CO,gas 7 3.510 0.0000E+00 perovskite-Ca 130 23.818 0.0000E+00 SO3,gas 8 17.427 0.0000E+00 perovskite-Fe 131 21.158 0.0000E+00 SO2,gas 9 1.136 0.0000E+00 perovskite-Mg 132 23.132 0.0000E+00 HCl,gas 10 5.479 0.0000E+00 phase_A 133 80.267 0.0000E+00 acmite 11 7.737 0.0000E+00 phlogopite-Na 134 29.731 0.0000E+00 akermanite 12 36.495 0.0000E+00 piemontite(ordered) 135 33.876 0.0000E+00 akimotoite 13 16.606 0.0000E+00 prehnite 136 19.466 0.0000E+00 akimotoite-Fe 14 13.083 0.0000E+00 prehnite-Fe 137 22.587 0.0000E+00 albite-high 15 0.750 0.0000E+00 pumpellyite-Fe 138 46.471 0.0000E+00 albite 16 -0.328 0.5004E+01 pumpellyite-Mg 139 49.194 0.0000E+00 almandine 17 24.545 0.0000E+00 px-Mg-tschermaks 140 19.687 0.0000E+00 pyrope 18 37.348 0.0000E+00 px-Ca-tschermaks 141 18.679 0.0000E+00 spessartine 19 24.550 0.0000E+00 pyrite 142 -21.225 0.0000E+00 analcite 20 3.371 0.0000E+00 pyrrhotite 143 -4.244 0.0000E+00 andalusite 21 5.062 0.0000E+00 pyrrhotiteFe0.875 144 -6.001 0.0000E+00 andradite 22 39.088 0.4436E+00 pyroxmangite 145 7.416 0.0000E+00 grossular 23 32.828 0.1059E+00 pyrophyllite 146 -6.098 0.0000E+00 anhydrite 24 -5.280 0.0000E+00 quartz 147 -2.982 0.0000E+00 ankerite 25 -2.093 0.0000E+00 rankinite 148 40.765 0.0000E+00 annite 26 20.209 0.0000E+00 ringwoodite-Fe 149 15.486 0.0000E+00 phlogopite 27 27.147 0.0000E+00 ringwoodite-Mg 150 27.602 0.0000E+00 biotite-Mn 28 33.034 0.0000E+00 rhodochrosite 151 -0.959 0.0000E+00 anorthite 29 12.798 0.0000E+00 rhodonite 152 7.462 0.0000E+00 anthophyllite 30 51.988 0.0000E+00 sanidine 153 -1.221 0.0000E+00 anthophyllite-Fe 31 29.455 0.0000E+00 sapphirine(351) 154 79.204 0.0000E+00 apatite-OH 32 -17.989 0.7890E-02 siderite 155 -2.588 0.0000E+00 apatite-OH-zs 33 -12.572 0.0000E+00 sillimanite 156 5.321 0.0000E+00 apatite-Cl-zs 34 -16.504 0.0000E+00 sodalite 157 50.255 0.0000E+00 aragonite 35 0.986 0.0000E+00 spinel 158 20.934 0.0000E+00 brucite 36 12.577 0.0000E+00 spurrite 159 59.566 0.0000E+00 calcite 37 0.833 0.0000E+00 staurolite-Fe 160 74.138 0.0000E+00 carnegieite-low 38 9.065 0.0000E+00 staurolite-Mg 161 90.336 0.0000E+00 carnegieite-high 39 10.134 0.0000E+00 staurolite-Mn 162 84.438 0.0000E+00 carpholite-Mg 40 8.650 0.0000E+00 stilbite 163 -7.406 0.2578E+01 carpholite-Fe 41 6.783 0.0000E+00 stilpnomelane-Fe 164 13.179 0.2112E+00 celadonite 42 5.401 0.0000E+00 stilpnomelane-Mg 165 27.596 0.0000E+00 celadonite-Fe 43 3.937 0.0000E+00 stishovite 166 2.721 0.0000E+00 chrysotile 44 23.937 0.0000E+00 sudoite-Fe 167 18.437 0.0000E+00 chondrodite 45 56.542 0.0000E+00 sudoite 168 21.216 0.0000E+00 clinochlore 46 39.193 0.5702E+00 sulfur 169 -9.141 0.0000E+00 daphnite 47 29.094 0.1634E+00 sylvite 170 1.345 0.0000E+00 chlorite-Mn 48 46.985 0.1387E-01 talc 171 16.553 0.0000E+00 chlorite-Al-free 49 47.262 0.0000E+00 talc-Fe 172 13.516 0.0000E+00 chloritoid-Mg 50 13.261 0.0000E+00 talc-tschermaks 173 19.189 0.0000E+00 chloritoid-Fe 51 9.239 0.0000E+00 tephroite 174 18.113 0.0000E+00 chloritoid-Mn 52 11.463 0.0000E+00 tilleyite 175 41.473 0.0000E+00 clinohumite 53 97.255 0.0000E+00 titanite-CaSi 176 15.497 0.0000E+00 coesite 54 -2.369 0.0000E+00 topaz-H 177 4.668 0.0000E+00 cordierite-H 55 23.898 0.0000E+00 tridymite 178 -2.615 0.0000E+00 cordierite 56 24.245 0.0000E+00 tremolite 179 48.003 0.0000E+00 cordierite-Fe 57 20.649 0.0000E+00 ferroactinolite 180 38.596 0.0000E+00 cordierite-Mn 58 25.261 0.0000E+00 troilite-low 181 -4.394 0.0000E+00 corundum 59 8.433 0.0000E+00 tschermakite 182 48.414 0.0000E+00 corundum-MgSi 60 18.905 0.0000E+00 vesuvianite 183 224.056 0.0000E+00 cristobalite 61 -2.549 0.0000E+00 wadeite-Si 184 20.233 0.0000E+00 cummingtonite 62 52.233 0.0000E+00 wadsleyite-Fe 185 15.711 0.0000E+00 cymrite-K 63 1.731 0.0000E+00 wadsleyite-Mg 186 25.878 0.0000E+00 deerite 64 95.982 0.0000E+00 wairakite 187 4.058 0.0000E+00 diaspore 65 2.896 0.0000E+00 walstromite 188 11.528 0.0000E+00 diamond 66 -3.107 0.0000E+00 wollastonite 189 10.482 0.0000E+00 diopside 67 16.215 0.2219E+00 pseudo-wollastonite 190 11.020 0.0000E+00 hedenbergite 68 14.244 0.5684E-01 zoisite 191 22.964 0.0000E+00 dolomite,ordered 69 0.587 0.0000E+00 akaganeite 192 7.768 0.0000E+00 eastonite 70 28.605 0.0000E+00 beidellite-Ca 193 -1.560 0.0000E+00 enstatite 71 17.301 0.0000E+00 beidellite-H 194 -2.241 0.0000E+00 clinoenstatite-HiP 72 18.388 0.0000E+00 beidellite-K 195 -1.435 0.0000E+00 clinoenstatite 73 17.202 0.0000E+00 beidellite-Mg 196 -1.707 0.0000E+00 protoenstatite 74 17.860 0.0000E+00 beidellite-Na 197 -1.257 0.0000E+00 epidote 75 24.775 0.0000E+00 calcium 198 84.043 0.0000E+00 clinozoisite 76 22.921 0.0000E+00 chalcedony 199 -2.794 0.0000E+00 epidote-Fe 77 29.937 0.0000E+00 dawsonite 200 1.714 0.0000E+00 fayalite 78 14.079 0.0000E+00 montmorillonite-Ca 201 -2.214 0.0000E+00 ferrosilite 79 11.188 0.0000E+00 montmorillonite-K 202 -2.161 0.0000E+00 forsterite 80 21.047 0.0000E+00 montmorillonite-Mg 203 -2.402 0.0000E+00 gedrite 81 50.725 0.0000E+00 montmorillonite-Na 204 -1.961 0.0000E+00 gehlenite 82 36.717 0.0000E+00 nontronite-Ca 205 3.280 0.0000E+00 gibbsite 83 4.097 0.0000E+00 nontronite-H 206 2.596 0.0000E+00 glaucophane 84 23.111 0.0000E+00 nontronite-K 207 3.404 0.0000E+00 glaucophane-Fe 85 17.417 0.0000E+00 nontronite-Mg 208 3.139 0.0000E+00 graphite 86 -3.549 0.0000E+00 nontronite-Na 209 3.583 0.0000E+00 greenalite 87 16.194 0.0000E+00 sepiolite 210 24.194 0.0000E+00 grunerite 88 31.364 0.0000E+00 alite 211 58.043 0.0000E+00 halite 89 1.582 0.0000E+00 belite 212 30.461 0.0000E+00 hematite 90 12.598 0.0000E+00 ettringite 213 43.354 0.0000E+00 heulandite 91 -5.707 0.0000E+00 gypsum 214 -4.924 0.0000E+00 hercynite 92 17.345 0.0000E+00 hemicarboaluminate 215 71.028 0.0000E+00 hollandite 93 25.702 0.0000E+00 hydrogarnet 216 60.721 0.0000E+00 iron 94 19.095 0.0000E+00 hydrogarnet-Si 217 50.654 0.0000E+00 jadeite 95 4.251 0.0000E+00 jennite 218 24.386 0.0000E+00 julgoldite 96 70.573 0.0000E+00 monosulfoaluminate 219 53.497 0.0000E+00 kalsilite 97 7.620 0.0000E+00 monocarboaluminate 220 61.966 0.0000E+00 kaolinite 98 -1.273 0.0000E+00 portlandite 221 18.282 0.0000E+00 kyanite 99 4.932 0.0000E+00 stratlingite 222 36.573 0.0000E+00 larnite-bredigite 100 30.714 0.0000E+00 tricarboaluminate 223 70.427 0.0000E+00 laumontite 101 2.975 0.0000E+00 tobermorite 224 9.839 0.0000E+00 lawsonite 102 9.678 0.0000E+00 C4AH13 225 81.870 0.0000E+00 leucite 103 4.168 0.0000E+00 C2AH8 226 45.260 0.0000E+00 lime 104 26.009 0.0000E+00 C3A 227 87.049 0.0000E+00 lizardite 105 23.287 0.0000E+00 C4AF 228 117.550 0.0000E+00 magnesite 106 0.709 0.0000E+00 CAH10 229 28.373 0.0000E+00 magnetite 107 20.133 0.0000E+00 alabandite 230 -0.962 0.0000E+00 minnesotaite 108 10.461 0.0000E+00 alunite 231 -10.224 0.0000E+00 minnesotaite-Mg 109 20.669 0.0000E+00 artinite 232 15.139 0.0000E+00 magnesioferrite 110 26.257 0.0000E+00 boehmite 233 4.430 0.0000E+00 majorite 111 53.314 0.0000E+00 dolomite,disordered 234 1.288 0.0000E+00 manganosite 112 14.068 0.0000E+00 ferrous-oxide 235 9.824 0.0000E+00 margarite 113 17.452 0.0000E+00 huntite 236 3.850 0.0000E+00 meionite 114 45.158 0.0000E+00 hydromagnesite 237 20.077 0.0000E+00 merwinite 115 55.988 0.0000E+00 nesquehonite 238 4.735 0.0000E+00 microcline 116 -2.432 0.7436E+00 potassium-oxide 239 69.039 0.0000E+00 monticellite 117 24.371 0.0000E+00 silica-amorphous 240 -2.080 0.0000E+00 mullite-Al 118 363.258 0.0000E+00 sodium-oxide 241 55.173 0.0000E+00 mullite-Si 119 7.324 0.0000E+00 an20ab80 242 2.079 0.0000E+00 muscovite 120 2.679 0.0000E+00 an25ab75 243 2.709 0.0000E+00 paragonite 121 4.337 0.0000E+00 an30ab70 244 3.344 0.0000E+00 nepheline 122 8.378 0.0000E+00 tr.625ac.25prg.125 245 45.308 0.2802E-01 osumilite(1) 123 21.978 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 3999.9990000 g log = 3.6021 Original solution: 1000.0103000 g Original solution / Rock added: 0.25 (Water/Rock Ratio), log = -0.6021 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 14 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 3999.9990000 Water: Moles liquid = 0.3311E+02 kg liquid = 0.5965E+00 Moles total = 0.5367E+01 kg total = 0.9668E-01 Activity = 1.0000 Stoichiometric ionic strength = .1180631E-01 Osmotic coef. = 0.9683 True ionic strength = .2074490E-01 Chg. balance for total moles = -.1299E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90519E-10 -10.0433 0.75929E-10 -10.1196 0.83881E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.23021E-03 -3.6379 0.19192E-03 -3.7169 0.83365E+00 -0.0790 4 SO4-- 0.13115E-11 -11.8822 0.67618E-12 -12.1699 0.51556E+00 -0.2877 5 HCO3- 0.47306E-06 -6.3251 0.39495E-06 -6.4035 0.83490E+00 -0.0784 6 HS- 0.42746E-04 -4.3691 0.35640E-04 -4.4481 0.83378E+00 -0.0789 7 Al+++ 0.11108E-28 -28.9544 0.25239E-29 -29.5979 0.22722E+00 -0.6435 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14400E-06 -6.8416 0.73681E-07 -7.1326 0.51168E+00 -0.2910 10 Mg++ 0.22865E-10 -10.6408 0.11645E-10 -10.9339 0.50929E+00 -0.2930 11 Fe++ 0.62547E-13 -13.2038 0.31890E-13 -13.4963 0.50986E+00 -0.2925 12 K+ 0.16189E-03 -3.7908 0.13519E-03 -3.8691 0.83510E+00 -0.0783 13 Na+ 0.20581E-01 -1.6865 0.17155E-01 -1.7656 0.83349E+00 -0.0791 14 Mn++ 0.20084E-10 -10.6971 0.10249E-10 -10.9893 0.51029E+00 -0.2922 15 HPO4-- 0.48568E-07 -7.3136 0.25043E-07 -7.6013 0.51563E+00 -0.2877 16 HSiO3- 0.10969E-01 -1.9598 0.91446E-02 -2.0388 0.83365E+00 -0.0790 17 Ca(HSiO3)+ 0.18073E-07 -7.7430 0.15096E-07 -7.8211 0.83528E+00 -0.0782 18 Mg(HSiO3)+ 0.35549E-11 -11.4492 0.29693E-11 -11.5273 0.83528E+00 -0.0782 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67661E-16 -16.1697 0.56516E-16 -16.2478 0.83528E+00 -0.0782 22 HAlO2,aq 0.14895E-09 -9.8270 0.14895E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52639E-05 -5.2787 0.43802E-05 -5.3585 0.83212E+00 -0.0798 24 CH4,aq 0.20501E-04 -4.6882 0.20427E-04 -4.6898 0.99640E+00 -0.0016 25 C2H6,aq 0.66441E-14 -14.1776 0.66202E-14 -14.1791 0.99640E+00 -0.0016 29 CO,aq 0.16927E-16 -16.7714 0.16927E-16 -16.7714 0.10000E+01 0.0000 30 CO2,aq 0.60681E-10 -10.2169 0.60463E-10 -10.2185 0.99640E+00 -0.0016 31 CO3-2 0.93488E-06 -6.0292 0.48094E-06 -6.3179 0.51444E+00 -0.2887 32 CaCO3,aq 0.43401E-09 -9.3625 0.43401E-09 -9.3625 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.87785E-12 -12.0566 0.73325E-12 -12.1347 0.83528E+00 -0.0782 34 CaCl+ 0.26977E-10 -10.5690 0.22533E-10 -10.6472 0.83528E+00 -0.0782 35 CaCl2,aq 0.10069E-14 -14.9970 0.10069E-14 -14.9970 0.10000E+01 0.0000 36 CaOH+ 0.81919E-07 -7.0866 0.68425E-07 -7.1648 0.83528E+00 -0.0782 37 CaSO4,aq 0.15523E-16 -16.8090 0.15523E-16 -16.8090 0.10000E+01 0.0000 38 HCl,aq 0.27410E-14 -14.5621 0.27410E-14 -14.5621 0.10000E+01 0.0000 43 FeCl+ 0.11412E-16 -16.9426 0.95324E-17 -17.0208 0.83528E+00 -0.0782 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16670E-10 -10.7781 0.13924E-10 -10.8562 0.83528E+00 -0.0782 48 HFeO2- 0.37169E-07 -7.4298 0.30986E-07 -7.5088 0.83365E+00 -0.0790 49 FeO+ 0.12304E-16 -16.9100 0.10277E-16 -16.9881 0.83528E+00 -0.0782 51 FeO2- 0.42027E-09 -9.3765 0.35036E-09 -9.4555 0.83365E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99640E+00 -0.0016 54 KCl,aq 0.45941E-09 -9.3378 0.45941E-09 -9.3378 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.16894E-14 -14.7723 0.14083E-14 -14.8513 0.83365E+00 -0.0790 58 MgCO3,aq 0.17140E-13 -13.7660 0.17140E-13 -13.7660 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14148E-15 -15.8493 0.11818E-15 -15.9275 0.83528E+00 -0.0782 60 MgCl+ 0.38706E-14 -14.4122 0.32331E-14 -14.4904 0.83528E+00 -0.0782 61 MgOH+ 0.71728E-10 -10.1443 0.59913E-10 -10.2225 0.83528E+00 -0.0782 63 MnO,aq 0.18766E-08 -8.7266 0.18766E-08 -8.7266 0.10000E+01 0.0000 64 MnOH+ 0.49768E-09 -9.3031 0.41570E-09 -9.3812 0.83528E+00 -0.0782 65 MnO2-2 0.21882E-10 -10.6599 0.11257E-10 -10.9486 0.51444E+00 -0.2887 66 HMnO2- 0.22214E-09 -9.6534 0.18519E-09 -9.7324 0.83365E+00 -0.0790 69 MnCl+ 0.14252E-13 -13.8461 0.11904E-13 -13.9243 0.83528E+00 -0.0782 71 NaCl,aq 0.10750E-05 -5.9686 0.10750E-05 -5.9686 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94937E-02 -2.0226 0.78999E-02 -2.1024 0.83212E+00 -0.0798 79 HPO3-2 0.16714E-14 -14.7769 0.85983E-15 -15.0656 0.51444E+00 -0.2887 81 H2PO3- 0.15383E-18 -18.8130 0.12824E-18 -18.8920 0.83365E+00 -0.0790 82 H3PO4,aq 0.92951E-18 -18.0317 0.92951E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39951E-10 -10.3985 0.33337E-10 -10.4771 0.83446E+00 -0.0786 84 PO4-3 0.12056E-08 -8.9188 0.28804E-09 -9.5405 0.23893E+00 -0.6217 88 HP2O7-3 0.10327E-17 -17.9860 0.23491E-18 -18.6291 0.22746E+00 -0.6431 89 P2O7-4 0.10188E-16 -16.9919 0.76322E-18 -18.1173 0.74916E-01 -1.1254 90 H2S,aq 0.81601E-08 -8.0883 0.81307E-08 -8.0899 0.99640E+00 -0.0016 91 S2-2 0.49959E-14 -14.3014 0.25701E-14 -14.5901 0.51444E+00 -0.2887 97 SO3-2 0.19197E-17 -17.7168 0.10022E-17 -17.9991 0.52205E+00 -0.2823 99 HSO4- 0.56975E-19 -19.2443 0.47638E-19 -19.3220 0.83611E+00 -0.0777 Charge balance for all species = -.2185E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9051940E-10 -.2307954E-01 -.2322061E+02 0.0000 2 H2O 0.1000000E+01 0.5550443E+02 0.9981157E+06 0.0000 3 Cl- 0.2302139E-03 0.2312894E-03 0.8185034E+01 6.4027 4 SO4-- 0.1311544E-11 -.2322839E-04 -.2227310E+01 8.0692 5 HCO3- 0.4730572E-06 0.2190955E-04 0.1334435E+01 3.7161 6 HS- 0.4274559E-04 0.6598214E-04 0.2178204E+01 5.6715 7 Al+++ 0.1110763E-28 0.5264043E-05 0.1417742E+00 0.7609 8 H4SiO4 0.7116560E-03 0.1417249E-01 0.1359724E+04 -3.1477 9 Ca++ 0.1439978E-06 0.2444519E-06 0.9779377E-02 13.1065 10 Mg++ 0.2286547E-10 0.9816820E-10 0.2382338E-05 9.3053 11 Fe++ 0.6254671E-13 0.3782817E-07 0.2108759E-02 6.7428 12 K+ 0.1618860E-03 0.1626627E-03 0.6348904E+01 6.2505 13 Na+ 0.2058149E-01 0.2317334E-01 0.5317845E+03 8.3540 14 Mn++ 0.2008408E-10 0.2638398E-08 0.1446855E-03 9.2499 15 HPO4-- 0.4856826E-07 0.4981378E-07 0.4772407E-02 12.6379 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6623403E+02 -.1376795E-01 -.6622026E+02 0.0000000E+00 2 H2O 0.5366622E+01 0.3311080E+02 -.2774418E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1108791E+00 -.1385675E-04 0.1108930E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1108536E+00 0.3936122E-04 -.1108930E+00 0.0000000E+00 7 Al+++ 0.1304296E+02 0.3140231E-05 0.1304296E+02 0.0000000E+00 8 H4SiO4 0.4165112E+02 0.8454506E-02 0.4164267E+02 0.0000000E+00 9 Ca++ 0.4600584E+01 0.1458262E-06 0.4600584E+01 0.0000000E+00 10 Mg++ 0.3174602E+01 0.5856160E-10 0.3174602E+01 0.0000000E+00 11 Fe++ 0.2852034E+01 0.2256615E-07 0.2852034E+01 0.0000000E+00 12 K+ 0.8492567E+00 0.9703538E-04 0.8491597E+00 0.0000000E+00 13 Na+ 0.5021133E+01 0.1382391E-01 0.5007309E+01 0.0000000E+00 14 Mn++ 0.6935437E-01 0.1573919E-08 0.6935437E-01 0.0000000E+00 15 HPO4-- 0.2367030E-01 0.2971608E-07 0.2367027E-01 0.0000000E+00 Chg. balance for solid moles: 0.6106E-15 Mass of aqueous solution: 0.597627E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 3999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.004 0.699 1312. 3.118 30.03 503.7 andradite 0.4436 -0.353 225.4 2.353 5.158 58.56 grossular 0.1059 -0.975 47.71 1.679 1.092 13.27 apatite-OH 0.7890E-02 -2.103 3.963 0.598 0.9069E-01 1.259 clinochlore 0.5702 -0.244 316.9 2.501 7.253 120.6 daphnite 0.1634 -0.787 116.6 2.067 2.668 35.34 chlorite-Mn 0.1387E-01 -1.858 9.834 0.993 0.2250 3.134 diopside 0.2219 -0.654 48.05 1.682 1.100 14.69 hedenbergite 0.5684E-01 -1.245 14.10 1.149 0.3227 3.863 microcline 0.7436 -0.129 207.0 2.316 4.736 80.85 stilbite 2.578 0.411 1817. 3.259 41.57 847.3 stilpnomelane-Fe 0.2112 -0.675 227.6 2.357 5.209 78.63 tr.625ac.25prg.125 0.2802E-01 -1.552 23.95 1.379 0.5481 7.709 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1856E-01 0.1856E-01 1.0000 -1.732 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4370.005799 g Volume = 1768.896710 cm3 Porosity: -10.4870% V(tot) - V(min): -.16790E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 3999.9990000 g log = 3.6021 Original solution: 1000.0103000 g Original solution / Rock added: 0.25 (Water/Rock Ratio), log = -0.6021 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.0994 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9574E+00 0.9849 0.1037E+01 0.1053E+01 CO2,gas 0.6252E-08 1.0070 0.6921E-08 0.6873E-08 CH4,gas 0.2901E-01 1.0127 0.3230E-01 0.3190E-01 H2,gas 0.1355E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.2166E-06 0.9957 0.2371E-06 0.2382E-06 S2,gas 0.8619E-29 1.0000 0.9476E-29 0.9476E-29 CO,gas 0.2431E-13 1.0000 0.2673E-13 0.2673E-13 SO3,gas 0.1326E-47 1.0000 0.1457E-47 0.1457E-47 SO2,gas 0.7477E-27 1.0000 0.8220E-27 0.8220E-27 HCl,gas 0.4402E-17 1.0000 0.4840E-17 0.4840E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.36397E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.52 -10.16 -3.387 0.17348E+05 -8.160 3 CH4,gas 4.81 1.32 -3.49 -0.873 0.59604E+04 -1.491 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.57 -8.62 -4.312 0.14727E+05 -6.625 6 S2,gas -7.03 -38.06 -31.02 -4.773 0.52972E+05 -29.023 7 CO,gas 3.51 -12.06 -15.57 -4.792 0.26591E+05 -13.573 8 SO3,gas 17.43 -32.41 -49.84 -12.459 0.85094E+05 -47.836 9 SO2,gas 1.14 -27.95 -29.09 -7.756 0.49662E+05 -27.085 10 HCl,gas 5.48 -13.84 -19.32 -9.658 0.32980E+05 -17.315 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80624E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94128E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.42 -4.40 -1.468 0.75175E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.42 -4.25 -1.417 0.72562E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70379E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65556E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.60 -4.50 -1.284 0.76751E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.60 -4.05 -1.158 0.69213E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82268E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92776E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40700E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43449E+04 143 pyrrhotite -4.24 -7.82 -3.58 -1.194 0.61149E+04 144 pyrrhotiteFe0.875 -6.00 -9.22 -3.22 -1.184 0.54976E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22435E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28298E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23227E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47142E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91027E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.82 -3.43 -1.144 0.58581E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80434E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66782E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60330E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61758E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.32 -4.36 -1.452 0.74367E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 3999.9990000 g New total amount of reactant added: 4199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1302E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 4199.9990000 Water: Moles liquid = 0.3200E+02 kg liquid = 0.5765E+00 Moles total = 0.2860E+01 kg total = 0.5152E-01 Activity = 1.0000 Stoichiometric ionic strength = .1181300E-01 Osmotic coef. = 0.9682 True ionic strength = .2075012E-01 Chg. balance for total moles = -.1302E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90542E-10 -10.0432 0.75947E-10 -10.1195 0.83880E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.23824E-03 -3.6230 0.19860E-03 -3.7020 0.83364E+00 -0.0790 4 SO4-- 0.13570E-11 -11.8674 0.69958E-12 -12.1552 0.51552E+00 -0.2878 5 HCO3- 0.48946E-06 -6.3103 0.40864E-06 -6.3887 0.83488E+00 -0.0784 6 HS- 0.44236E-04 -4.3542 0.36882E-04 -4.4332 0.83376E+00 -0.0790 7 Al+++ 0.11117E-28 -28.9540 0.25257E-29 -29.5976 0.22719E+00 -0.6436 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14407E-06 -6.8414 0.73715E-07 -7.1324 0.51165E+00 -0.2910 10 Mg++ 0.22878E-10 -10.6406 0.11651E-10 -10.9337 0.50926E+00 -0.2931 11 Fe++ 0.62580E-13 -13.2036 0.31905E-13 -13.4961 0.50983E+00 -0.2926 12 K+ 0.16193E-03 -3.7907 0.13522E-03 -3.8690 0.83508E+00 -0.0783 13 Na+ 0.20587E-01 -1.6864 0.17159E-01 -1.7655 0.83348E+00 -0.0791 14 Mn++ 0.20097E-10 -10.6969 0.10255E-10 -10.9891 0.51026E+00 -0.2922 15 HPO4-- 0.48549E-07 -7.3138 0.25032E-07 -7.6015 0.51560E+00 -0.2877 16 HSiO3- 0.10967E-01 -1.9599 0.91425E-02 -2.0389 0.83364E+00 -0.0790 17 Ca(HSiO3)+ 0.18078E-07 -7.7429 0.15100E-07 -7.8210 0.83527E+00 -0.0782 18 Mg(HSiO3)+ 0.35558E-11 -11.4491 0.29700E-11 -11.5272 0.83527E+00 -0.0782 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67678E-16 -16.1696 0.56529E-16 -16.2477 0.83527E+00 -0.0782 22 HAlO2,aq 0.14895E-09 -9.8270 0.14895E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52627E-05 -5.2788 0.43792E-05 -5.3586 0.83211E+00 -0.0798 24 CH4,aq 0.21216E-04 -4.6733 0.21140E-04 -4.6749 0.99640E+00 -0.0016 25 C2H6,aq 0.71157E-14 -14.1478 0.70901E-14 -14.1494 0.99640E+00 -0.0016 29 CO,aq 0.17518E-16 -16.7565 0.17518E-16 -16.7565 0.10000E+01 0.0000 30 CO2,aq 0.62798E-10 -10.2021 0.62572E-10 -10.2036 0.99640E+00 -0.0016 31 CO3-2 0.96711E-06 -6.0145 0.49749E-06 -6.3032 0.51440E+00 -0.2887 32 CaCO3,aq 0.44915E-09 -9.3476 0.44915E-09 -9.3476 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.90870E-12 -12.0416 0.75901E-12 -12.1198 0.83527E+00 -0.0782 34 CaCl+ 0.27930E-10 -10.5539 0.23329E-10 -10.6321 0.83527E+00 -0.0782 35 CaCl2,aq 0.10788E-14 -14.9671 0.10788E-14 -14.9671 0.10000E+01 0.0000 36 CaOH+ 0.81939E-07 -7.0865 0.68441E-07 -7.1647 0.83527E+00 -0.0782 37 CaSO4,aq 0.16068E-16 -16.7940 0.16068E-16 -16.7940 0.10000E+01 0.0000 38 HCl,aq 0.28371E-14 -14.5471 0.28371E-14 -14.5471 0.10000E+01 0.0000 43 FeCl+ 0.11816E-16 -16.9275 0.98691E-17 -17.0057 0.83527E+00 -0.0782 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16674E-10 -10.7780 0.13927E-10 -10.8561 0.83527E+00 -0.0782 48 HFeO2- 0.37161E-07 -7.4299 0.30979E-07 -7.5089 0.83364E+00 -0.0790 49 FeO+ 0.12307E-16 -16.9098 0.10280E-16 -16.9880 0.83527E+00 -0.0782 51 FeO2- 0.42018E-09 -9.3766 0.35028E-09 -9.4556 0.83364E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99640E+00 -0.0016 54 KCl,aq 0.47552E-09 -9.3228 0.47552E-09 -9.3228 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.17483E-14 -14.7574 0.14574E-14 -14.8364 0.83364E+00 -0.0790 58 MgCO3,aq 0.17738E-13 -13.7511 0.17738E-13 -13.7511 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.14645E-15 -15.8343 0.12233E-15 -15.9125 0.83527E+00 -0.0782 60 MgCl+ 0.40074E-14 -14.3971 0.33472E-14 -14.4753 0.83527E+00 -0.0782 61 MgOH+ 0.71746E-10 -10.1442 0.59927E-10 -10.2224 0.83527E+00 -0.0782 63 MnO,aq 0.18768E-08 -8.7266 0.18768E-08 -8.7266 0.10000E+01 0.0000 64 MnOH+ 0.49786E-09 -9.3029 0.41584E-09 -9.3811 0.83527E+00 -0.0782 65 MnO2-2 0.21876E-10 -10.6600 0.11253E-10 -10.9487 0.51440E+00 -0.2887 66 HMnO2- 0.22212E-09 -9.6534 0.18517E-09 -9.7324 0.83364E+00 -0.0790 69 MnCl+ 0.14757E-13 -13.8310 0.12326E-13 -13.9092 0.83527E+00 -0.0782 71 NaCl,aq 0.11127E-05 -5.9536 0.11127E-05 -5.9536 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94917E-02 -2.0227 0.78981E-02 -2.1025 0.83211E+00 -0.0798 79 HPO3-2 0.16707E-14 -14.7771 0.85943E-15 -15.0658 0.51440E+00 -0.2887 81 H2PO3- 0.15380E-18 -18.8130 0.12821E-18 -18.8921 0.83364E+00 -0.0790 82 H3PO4,aq 0.92952E-18 -18.0317 0.92952E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39942E-10 -10.3986 0.33330E-10 -10.4772 0.83444E+00 -0.0786 84 PO4-3 0.12049E-08 -8.9190 0.28784E-09 -9.5408 0.23889E+00 -0.6218 88 HP2O7-3 0.10321E-17 -17.9863 0.23474E-18 -18.6294 0.22743E+00 -0.6432 89 P2O7-4 0.10181E-16 -16.9922 0.76251E-18 -18.1178 0.74896E-01 -1.1255 90 H2S,aq 0.84464E-08 -8.0733 0.84160E-08 -8.0749 0.99640E+00 -0.0016 91 S2-2 0.53504E-14 -14.2716 0.27523E-14 -14.5603 0.51440E+00 -0.2887 97 SO3-2 0.19863E-17 -17.7020 0.10369E-17 -17.9843 0.52202E+00 -0.2823 99 HSO4- 0.58962E-19 -19.2294 0.49298E-19 -19.3072 0.83610E+00 -0.0777 Charge balance for all species = -.2252E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9054193E-10 -.2307517E-01 -.2321621E+02 0.0000 2 H2O 0.1000000E+01 0.5550443E+02 0.9981155E+06 0.0000 3 Cl- 0.2382383E-03 0.2393515E-03 0.8470339E+01 6.4175 4 SO4-- 0.1357028E-11 -.2394345E-04 -.2295875E+01 8.0838 5 HCO3- 0.4894561E-06 0.2267326E-04 0.1380950E+01 3.7308 6 HS- 0.4423558E-04 0.6818747E-04 0.2251006E+01 5.6863 7 Al+++ 0.1111704E-28 0.5262887E-05 0.1417431E+00 0.7609 8 H4SiO4 0.7116570E-03 0.1417014E-01 0.1359498E+04 -3.1477 9 Ca++ 0.1440745E-06 0.2445696E-06 0.9784084E-02 13.1065 10 Mg++ 0.2287767E-10 0.9820191E-10 0.2383155E-05 9.3053 11 Fe++ 0.6258013E-13 0.3782004E-07 0.2108305E-02 6.7428 12 K+ 0.1619265E-03 0.1627032E-03 0.6350481E+01 6.2505 13 Na+ 0.2058664E-01 0.2317853E-01 0.5319034E+03 8.3540 14 Mn++ 0.2009704E-10 0.2638769E-08 0.1447058E-03 9.2499 15 HPO4-- 0.4854894E-07 0.4979378E-07 0.4770490E-02 12.6375 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.6954574E+02 -.1330168E-01 -.6953243E+02 0.0000000E+00 2 H2O 0.2859539E+01 0.3199553E+02 -.2913599E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1164218E+00 -.1380220E-04 0.1164356E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1163963E+00 0.3930667E-04 -.1164356E+00 0.0000000E+00 7 Al+++ 0.1369511E+02 0.3033791E-05 0.1369511E+02 0.0000000E+00 8 H4SiO4 0.4373368E+02 0.8168376E-02 0.4372551E+02 0.0000000E+00 9 Ca++ 0.4830612E+01 0.1409822E-06 0.4830612E+01 0.0000000E+00 10 Mg++ 0.3333333E+01 0.5660850E-10 0.3333333E+01 0.0000000E+00 11 Fe++ 0.2994635E+01 0.2180136E-07 0.2994635E+01 0.0000000E+00 12 K+ 0.8917195E+00 0.9379025E-04 0.8916257E+00 0.0000000E+00 13 Na+ 0.5272182E+01 0.1336127E-01 0.5258821E+01 0.0000000E+00 14 Mn++ 0.7282209E-01 0.1521118E-08 0.7282208E-01 0.0000000E+00 15 HPO4-- 0.2485382E-01 0.2870363E-07 0.2485379E-01 0.0000000E+00 Chg. balance for solid moles: 0.1843E-13 Mass of aqueous solution: 0.577497E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 4199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.255 0.721 1378. 3.139 30.03 529.0 andradite 0.4657 -0.332 236.7 2.374 5.158 61.49 grossular 0.1112 -0.954 50.09 1.700 1.092 13.94 apatite-OH 0.8285E-02 -2.082 4.162 0.619 0.9069E-01 1.322 clinochlore 0.5987 -0.223 332.8 2.522 7.252 126.6 daphnite 0.1716 -0.766 122.4 2.088 2.668 37.10 chlorite-Mn 0.1456E-01 -1.837 10.33 1.014 0.2250 3.291 diopside 0.2334 -0.632 50.56 1.704 1.102 15.45 hedenbergite 0.5981E-01 -1.223 14.84 1.171 0.3234 4.064 microcline 0.7808 -0.107 217.3 2.337 4.736 84.89 stilbite 2.706 0.432 1907. 3.280 41.56 889.6 stilpnomelane-Fe 0.2217 -0.654 239.0 2.378 5.209 82.57 tr.625ac.25prg.125 0.2939E-01 -1.532 25.12 1.400 0.5474 8.084 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1856E-01 0.1856E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4588.516763 g Volume = 1857.309424 cm3 Porosity: -10.4884% V(tot) - V(min): -.17631E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4199.9990000 g log = 3.6232 Original solution: 1000.0103000 g Original solution / Rock added: 0.24 (Water/Rock Ratio), log = -0.6232 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1005 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9565E+00 0.9849 0.1037E+01 0.1053E+01 CO2,gas 0.6463E-08 1.0070 0.7163E-08 0.7113E-08 CH4,gas 0.3000E-01 1.0127 0.3343E-01 0.3301E-01 H2,gas 0.1354E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.2240E-06 0.9957 0.2455E-06 0.2465E-06 S2,gas 0.9225E-29 1.0000 0.1015E-28 0.1015E-28 CO,gas 0.2513E-13 1.0000 0.2766E-13 0.2766E-13 SO3,gas 0.1371E-47 1.0000 0.1509E-47 0.1509E-47 SO2,gas 0.7731E-27 1.0000 0.8508E-27 0.8508E-27 HCl,gas 0.4552E-17 1.0000 0.5010E-17 0.5010E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.51 -10.14 -3.382 0.17322E+05 -8.145 3 CH4,gas 4.81 1.33 -3.48 -0.869 0.59349E+04 -1.476 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.55 -8.61 -4.305 0.14701E+05 -6.610 6 S2,gas -7.03 -38.03 -30.99 -4.768 0.52920E+05 -28.993 7 CO,gas 3.51 -12.05 -15.56 -4.787 0.26565E+05 -13.558 8 SO3,gas 17.43 -32.39 -49.82 -12.455 0.85069E+05 -47.821 9 SO2,gas 1.14 -27.93 -29.07 -7.752 0.49637E+05 -27.070 10 HCl,gas 5.48 -13.82 -19.30 -9.650 0.32955E+05 -17.300 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80621E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94128E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.40 -4.39 -1.463 0.74921E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.40 -4.23 -1.412 0.72308E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65556E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.59 -4.48 -1.280 0.76497E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.59 -4.04 -1.154 0.68959E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22975E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82267E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92776E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40700E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43449E+04 143 pyrrhotite -4.24 -7.81 -3.57 -1.189 0.60893E+04 144 pyrrhotiteFe0.875 -6.00 -9.21 -3.20 -1.179 0.54721E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22434E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28298E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23226E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47140E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91027E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.81 -3.42 -1.139 0.58325E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80435E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66782E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60330E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.30 -4.34 -1.447 0.74111E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 4199.9990000 g New total amount of reactant added: 4399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1300E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 4399.9990000 Water: Moles liquid = 0.3088E+02 kg liquid = 0.5564E+00 Moles total = 0.3525E+00 kg total = 0.6350E-02 Activity = 1.0000 Stoichiometric ionic strength = .1182018E-01 Osmotic coef. = 0.9682 True ionic strength = .2075572E-01 Chg. balance for total moles = -.1300E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90566E-10 -10.0430 0.75966E-10 -10.1194 0.83879E+00 -0.0763 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.24684E-03 -3.6076 0.20577E-03 -3.6866 0.83362E+00 -0.0790 4 SO4-- 0.14058E-11 -11.8521 0.72466E-12 -12.1399 0.51549E+00 -0.2878 5 HCO3- 0.50703E-06 -6.2950 0.42330E-06 -6.3733 0.83487E+00 -0.0784 6 HS- 0.45833E-04 -4.3388 0.38213E-04 -4.4178 0.83375E+00 -0.0790 7 Al+++ 0.11127E-28 -28.9536 0.25276E-29 -29.5973 0.22715E+00 -0.6437 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14416E-06 -6.8412 0.73752E-07 -7.1322 0.51161E+00 -0.2911 10 Mg++ 0.22891E-10 -10.6403 0.11656E-10 -10.9334 0.50922E+00 -0.2931 11 Fe++ 0.62616E-13 -13.2033 0.31921E-13 -13.4959 0.50979E+00 -0.2926 12 K+ 0.16197E-03 -3.7906 0.13526E-03 -3.8688 0.83507E+00 -0.0783 13 Na+ 0.20592E-01 -1.6863 0.17163E-01 -1.7654 0.83347E+00 -0.0791 14 Mn++ 0.20111E-10 -10.6966 0.10261E-10 -10.9888 0.51022E+00 -0.2922 15 HPO4-- 0.48528E-07 -7.3140 0.25019E-07 -7.6017 0.51556E+00 -0.2877 16 HSiO3- 0.10964E-01 -1.9600 0.91402E-02 -2.0390 0.83362E+00 -0.0790 17 Ca(HSiO3)+ 0.18083E-07 -7.7427 0.15104E-07 -7.8209 0.83525E+00 -0.0782 18 Mg(HSiO3)+ 0.35567E-11 -11.4489 0.29708E-11 -11.5271 0.83525E+00 -0.0782 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67696E-16 -16.1694 0.56543E-16 -16.2476 0.83525E+00 -0.0782 22 HAlO2,aq 0.14895E-09 -9.8270 0.14895E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52615E-05 -5.2789 0.43780E-05 -5.3587 0.83209E+00 -0.0798 24 CH4,aq 0.21983E-04 -4.6579 0.21904E-04 -4.6595 0.99640E+00 -0.0016 25 C2H6,aq 0.76393E-14 -14.1169 0.76118E-14 -14.1185 0.99640E+00 -0.0016 29 CO,aq 0.18151E-16 -16.7411 0.18151E-16 -16.7411 0.10000E+01 0.0000 30 CO2,aq 0.65069E-10 -10.1866 0.64834E-10 -10.1882 0.99640E+00 -0.0016 31 CO3-2 0.10016E-05 -5.9993 0.51521E-06 -6.2880 0.51437E+00 -0.2887 32 CaCO3,aq 0.46539E-09 -9.3322 0.46539E-09 -9.3322 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.94180E-12 -12.0260 0.78664E-12 -12.1042 0.83525E+00 -0.0782 34 CaCl+ 0.28953E-10 -10.5383 0.24183E-10 -10.6165 0.83525E+00 -0.0782 35 CaCl2,aq 0.11587E-14 -14.9360 0.11587E-14 -14.9360 0.10000E+01 0.0000 36 CaOH+ 0.81961E-07 -7.0864 0.68458E-07 -7.1646 0.83525E+00 -0.0782 37 CaSO4,aq 0.16652E-16 -16.7785 0.16652E-16 -16.7785 0.10000E+01 0.0000 38 HCl,aq 0.29403E-14 -14.5316 0.29403E-14 -14.5316 0.10000E+01 0.0000 43 FeCl+ 0.12248E-16 -16.9119 0.10230E-16 -16.9901 0.83525E+00 -0.0782 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16678E-10 -10.7778 0.13931E-10 -10.8560 0.83525E+00 -0.0782 48 HFeO2- 0.37152E-07 -7.4300 0.30971E-07 -7.5090 0.83362E+00 -0.0790 49 FeO+ 0.12310E-16 -16.9097 0.10282E-16 -16.9879 0.83525E+00 -0.0782 51 FeO2- 0.42009E-09 -9.3767 0.35019E-09 -9.4557 0.83362E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99640E+00 -0.0016 54 KCl,aq 0.49281E-09 -9.3073 0.49281E-09 -9.3073 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.18114E-14 -14.7420 0.15101E-14 -14.8210 0.83362E+00 -0.0790 58 MgCO3,aq 0.18379E-13 -13.7357 0.18379E-13 -13.7357 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15179E-15 -15.8188 0.12678E-15 -15.8969 0.83525E+00 -0.0782 60 MgCl+ 0.41542E-14 -14.3815 0.34698E-14 -14.4597 0.83525E+00 -0.0782 61 MgOH+ 0.71765E-10 -10.1441 0.59942E-10 -10.2223 0.83525E+00 -0.0782 63 MnO,aq 0.18770E-08 -8.7265 0.18770E-08 -8.7265 0.10000E+01 0.0000 64 MnOH+ 0.49804E-09 -9.3027 0.41599E-09 -9.3809 0.83525E+00 -0.0782 65 MnO2-2 0.21869E-10 -10.6602 0.11249E-10 -10.9489 0.51437E+00 -0.2887 66 HMnO2- 0.22209E-09 -9.6535 0.18514E-09 -9.7325 0.83362E+00 -0.0790 69 MnCl+ 0.15299E-13 -13.8153 0.12779E-13 -13.8935 0.83525E+00 -0.0782 71 NaCl,aq 0.11532E-05 -5.9381 0.11532E-05 -5.9381 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94895E-02 -2.0228 0.78961E-02 -2.1026 0.83209E+00 -0.0798 79 HPO3-2 0.16700E-14 -14.7773 0.85900E-15 -15.0660 0.51437E+00 -0.2887 81 H2PO3- 0.15376E-18 -18.8131 0.12818E-18 -18.8922 0.83362E+00 -0.0790 82 H3PO4,aq 0.92952E-18 -18.0317 0.92952E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39933E-10 -10.3987 0.33322E-10 -10.4773 0.83443E+00 -0.0786 84 PO4-3 0.12042E-08 -8.9193 0.28763E-09 -9.5412 0.23886E+00 -0.6219 88 HP2O7-3 0.10315E-17 -17.9865 0.23457E-18 -18.6297 0.22739E+00 -0.6432 89 P2O7-4 0.10174E-16 -16.9925 0.76176E-18 -18.1182 0.74875E-01 -1.1257 90 H2S,aq 0.87535E-08 -8.0578 0.87219E-08 -8.0594 0.99640E+00 -0.0016 91 S2-2 0.57441E-14 -14.2408 0.29546E-14 -14.5295 0.51437E+00 -0.2887 97 SO3-2 0.20576E-17 -17.6866 0.10740E-17 -17.9690 0.52198E+00 -0.2823 99 HSO4- 0.61092E-19 -19.2140 0.51078E-19 -19.2918 0.83609E+00 -0.0777 Charge balance for all species = -.2332E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9056610E-10 -.2307048E-01 -.2321148E+02 0.0000 2 H2O 0.1000000E+01 0.5550443E+02 0.9981152E+06 0.0000 3 Cl- 0.2468422E-03 0.2479959E-03 0.8776252E+01 6.4328 4 SO4-- 0.1405777E-11 -.2471019E-04 -.2369395E+01 8.0989 5 HCO3- 0.5070317E-06 0.2349212E-04 0.1430824E+01 3.7460 6 HS- 0.4583319E-04 0.7055213E-04 0.2329068E+01 5.7016 7 Al+++ 0.1112715E-28 0.5261651E-05 0.1417097E+00 0.7608 8 H4SiO4 0.7116578E-03 0.1416761E-01 0.1359256E+04 -3.1477 9 Ca++ 0.1441568E-06 0.2446959E-06 0.9789134E-02 13.1065 10 Mg++ 0.2289076E-10 0.9823485E-10 0.2383954E-05 9.3053 11 Fe++ 0.6261598E-13 0.3781132E-07 0.2107818E-02 6.7428 12 K+ 0.1619698E-03 0.1627465E-03 0.6352173E+01 6.2505 13 Na+ 0.2059216E-01 0.2318410E-01 0.5320310E+03 8.3540 14 Mn++ 0.2011059E-10 0.2639119E-08 0.1447250E-03 9.2499 15 HPO4-- 0.4852822E-07 0.4977234E-07 0.4768435E-02 12.6370 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7285744E+02 -.1283541E-01 -.7284460E+02 0.0000000E+00 2 H2O 0.3524574E+00 0.3088026E+02 -.3052780E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1219645E+00 -.1374768E-04 0.1219782E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1219390E+00 0.3925215E-04 -.1219782E+00 0.0000000E+00 7 Al+++ 0.1434726E+02 0.2927354E-05 0.1434726E+02 0.0000000E+00 8 H4SiO4 0.4581623E+02 0.7882246E-02 0.4580835E+02 0.0000000E+00 9 Ca++ 0.5060641E+01 0.1361382E-06 0.5060641E+01 0.0000000E+00 10 Mg++ 0.3492063E+01 0.5465361E-10 0.3492063E+01 0.0000000E+00 11 Fe++ 0.3137237E+01 0.2103658E-07 0.3137237E+01 0.0000000E+00 12 K+ 0.9341824E+00 0.9054512E-04 0.9340918E+00 0.0000000E+00 13 Na+ 0.5523231E+01 0.1289863E-01 0.5510332E+01 0.0000000E+00 14 Mn++ 0.7628981E-01 0.1468292E-08 0.7628980E-01 0.0000000E+00 15 HPO4-- 0.2603733E-01 0.2769117E-07 0.2603730E-01 0.0000000E+00 Chg. balance for solid moles: -.3941E-14 Mass of aqueous solution: 0.557368E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 4399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.506 0.741 1444. 3.160 30.04 554.3 andradite 0.4879 -0.312 247.9 2.394 5.158 64.42 grossular 0.1165 -0.934 52.47 1.720 1.092 14.60 apatite-OH 0.8679E-02 -2.062 4.360 0.639 0.9069E-01 1.385 clinochlore 0.6271 -0.203 348.6 2.542 7.251 132.6 daphnite 0.1797 -0.745 128.2 2.108 2.668 38.86 chlorite-Mn 0.1526E-01 -1.817 10.82 1.034 0.2250 3.447 diopside 0.2450 -0.611 53.06 1.725 1.104 16.22 hedenbergite 0.6277E-01 -1.202 15.57 1.192 0.3240 4.266 microcline 0.8179 -0.087 227.7 2.357 4.736 88.93 stilbite 2.835 0.453 1998. 3.301 41.56 931.8 stilpnomelane-Fe 0.2323 -0.634 250.4 2.399 5.210 86.50 tr.625ac.25prg.125 0.3075E-01 -1.512 26.28 1.420 0.5467 8.459 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1856E-01 0.1856E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 4807.027727 g Volume = 1945.722138 cm3 Porosity: -10.4896% V(tot) - V(min): -.18472E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4399.9990000 g log = 3.6435 Original solution: 1000.0103000 g Original solution / Rock added: 0.23 (Water/Rock Ratio), log = -0.6434 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1018 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9554E+00 0.9848 0.1037E+01 0.1053E+01 CO2,gas 0.6690E-08 1.0069 0.7421E-08 0.7370E-08 CH4,gas 0.3105E-01 1.0127 0.3464E-01 0.3421E-01 H2,gas 0.1352E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.2319E-06 0.9957 0.2544E-06 0.2555E-06 S2,gas 0.9897E-29 1.0000 0.1090E-28 0.1090E-28 CO,gas 0.2601E-13 1.0000 0.2866E-13 0.2866E-13 SO3,gas 0.1419E-47 1.0000 0.1563E-47 0.1563E-47 SO2,gas 0.8003E-27 1.0000 0.8818E-27 0.8818E-27 HCl,gas 0.4712E-17 1.0000 0.5192E-17 0.5192E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.48529E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 67 diopside 16.22 16.22 0.00 0.000 -0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 -0.15165E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.49 -10.13 -3.377 0.17296E+05 -8.130 3 CH4,gas 4.81 1.35 -3.46 -0.865 0.59086E+04 -1.460 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.54 -8.59 -4.297 0.14675E+05 -6.595 6 S2,gas -7.03 -38.00 -30.96 -4.763 0.52867E+05 -28.962 7 CO,gas 3.51 -12.03 -15.54 -4.782 0.26539E+05 -13.543 8 SO3,gas 17.43 -32.38 -49.81 -12.451 0.85042E+05 -47.806 9 SO2,gas 1.14 -27.92 -29.05 -7.748 0.49610E+05 -27.055 10 HCl,gas 5.48 -13.81 -19.28 -9.642 0.32928E+05 -17.285 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80619E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94128E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.39 -4.37 -1.457 0.74658E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.39 -4.22 -1.406 0.72044E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65555E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.57 -4.46 -1.276 0.76234E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.57 -4.02 -1.149 0.68695E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.205 0.82266E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92776E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40700E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43449E+04 143 pyrrhotite -4.24 -7.79 -3.55 -1.184 0.60628E+04 144 pyrrhotiteFe0.875 -6.00 -9.19 -3.19 -1.173 0.54456E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22433E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28298E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23225E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47139E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91027E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.79 -3.40 -1.133 0.58060E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80435E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66782E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66244E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.29 -4.32 -1.442 0.73845E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 4399.9990000 g New total amount of reactant added: 4599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1299E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 4599.9990000 Water: Moles liquid = 0.2977E+02 kg liquid = 0.5363E+00 Moles total = -.2155E+01 kg total = -.3882E-01 Activity = 1.0000 Stoichiometric ionic strength = .1182790E-01 Osmotic coef. = 0.9681 True ionic strength = .2076174E-01 Chg. balance for total moles = -.1299E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90592E-10 -10.0429 0.75986E-10 -10.1193 0.83877E+00 -0.0764 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.25609E-03 -3.5916 0.21348E-03 -3.6706 0.83361E+00 -0.0790 4 SO4-- 0.14582E-11 -11.8362 0.75160E-12 -12.1240 0.51545E+00 -0.2878 5 HCO3- 0.52592E-06 -6.2791 0.43906E-06 -6.3575 0.83485E+00 -0.0784 6 HS- 0.47551E-04 -4.3228 0.39644E-04 -4.4018 0.83373E+00 -0.0790 7 Al+++ 0.11138E-28 -28.9532 0.25296E-29 -29.5970 0.22711E+00 -0.6438 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14425E-06 -6.8409 0.73792E-07 -7.1320 0.51157E+00 -0.2911 10 Mg++ 0.22905E-10 -10.6401 0.11663E-10 -10.9332 0.50918E+00 -0.2931 11 Fe++ 0.62655E-13 -13.2030 0.31938E-13 -13.4957 0.50975E+00 -0.2926 12 K+ 0.16202E-03 -3.7904 0.13529E-03 -3.8687 0.83505E+00 -0.0783 13 Na+ 0.20598E-01 -1.6862 0.17167E-01 -1.7653 0.83345E+00 -0.0791 14 Mn++ 0.20125E-10 -10.6963 0.10267E-10 -10.9885 0.51018E+00 -0.2923 15 HPO4-- 0.48506E-07 -7.3142 0.25006E-07 -7.6020 0.51552E+00 -0.2878 16 HSiO3- 0.10962E-01 -1.9601 0.91378E-02 -2.0392 0.83361E+00 -0.0790 17 Ca(HSiO3)+ 0.18088E-07 -7.7426 0.15108E-07 -7.8208 0.83524E+00 -0.0782 18 Mg(HSiO3)+ 0.35578E-11 -11.4488 0.29716E-11 -11.5270 0.83524E+00 -0.0782 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67715E-16 -16.1693 0.56558E-16 -16.2475 0.83524E+00 -0.0782 22 HAlO2,aq 0.14895E-09 -9.8270 0.14895E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52602E-05 -5.2790 0.43769E-05 -5.3588 0.83207E+00 -0.0798 24 CH4,aq 0.22807E-04 -4.6419 0.22725E-04 -4.6435 0.99640E+00 -0.0016 25 C2H6,aq 0.82229E-14 -14.0850 0.81933E-14 -14.0865 0.99640E+00 -0.0016 29 CO,aq 0.18832E-16 -16.7251 0.18832E-16 -16.7251 0.10000E+01 0.0000 30 CO2,aq 0.67509E-10 -10.1706 0.67266E-10 -10.1722 0.99640E+00 -0.0016 31 CO3-2 0.10387E-05 -5.9835 0.53425E-06 -6.2723 0.51433E+00 -0.2888 32 CaCO3,aq 0.48284E-09 -9.3162 0.48284E-09 -9.3162 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.97740E-12 -12.0099 0.81636E-12 -12.0881 0.83524E+00 -0.0782 34 CaCl+ 0.30054E-10 -10.5221 0.25102E-10 -10.6003 0.83524E+00 -0.0782 35 CaCl2,aq 0.12477E-14 -14.9039 0.12477E-14 -14.9039 0.10000E+01 0.0000 36 CaOH+ 0.81985E-07 -7.0863 0.68477E-07 -7.1645 0.83524E+00 -0.0782 37 CaSO4,aq 0.17281E-16 -16.7624 0.17281E-16 -16.7624 0.10000E+01 0.0000 38 HCl,aq 0.30512E-14 -14.5155 0.30512E-14 -14.5155 0.10000E+01 0.0000 43 FeCl+ 0.12714E-16 -16.8957 0.10619E-16 -16.9739 0.83524E+00 -0.0782 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16683E-10 -10.7777 0.13934E-10 -10.8559 0.83524E+00 -0.0782 48 HFeO2- 0.37143E-07 -7.4301 0.30963E-07 -7.5092 0.83361E+00 -0.0790 49 FeO+ 0.12314E-16 -16.9096 0.10285E-16 -16.9878 0.83524E+00 -0.0782 51 FeO2- 0.41998E-09 -9.3768 0.35010E-09 -9.4558 0.83361E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99640E+00 -0.0016 54 KCl,aq 0.51140E-09 -9.2912 0.51140E-09 -9.2912 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.18793E-14 -14.7260 0.15666E-14 -14.8050 0.83361E+00 -0.0790 58 MgCO3,aq 0.19069E-13 -13.7197 0.19069E-13 -13.7197 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.15752E-15 -15.8027 0.13157E-15 -15.8808 0.83524E+00 -0.0782 60 MgCl+ 0.43121E-14 -14.3653 0.36017E-14 -14.4435 0.83524E+00 -0.0782 61 MgOH+ 0.71785E-10 -10.1440 0.59958E-10 -10.2222 0.83524E+00 -0.0782 63 MnO,aq 0.18772E-08 -8.7265 0.18772E-08 -8.7265 0.10000E+01 0.0000 64 MnOH+ 0.49823E-09 -9.3026 0.41614E-09 -9.3808 0.83524E+00 -0.0782 65 MnO2-2 0.21861E-10 -10.6603 0.11244E-10 -10.9491 0.51433E+00 -0.2888 66 HMnO2- 0.22205E-09 -9.6535 0.18511E-09 -9.7326 0.83361E+00 -0.0790 69 MnCl+ 0.15883E-13 -13.7991 0.13266E-13 -13.8773 0.83524E+00 -0.0782 71 NaCl,aq 0.11967E-05 -5.9220 0.11967E-05 -5.9220 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94871E-02 -2.0229 0.78940E-02 -2.1027 0.83207E+00 -0.0798 79 HPO3-2 0.16692E-14 -14.7775 0.85854E-15 -15.0662 0.51433E+00 -0.2888 81 H2PO3- 0.15373E-18 -18.8133 0.12815E-18 -18.8923 0.83361E+00 -0.0790 82 H3PO4,aq 0.92952E-18 -18.0317 0.92952E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39923E-10 -10.3988 0.33313E-10 -10.4774 0.83441E+00 -0.0786 84 PO4-3 0.12034E-08 -8.9196 0.28739E-09 -9.5415 0.23882E+00 -0.6219 88 HP2O7-3 0.10309E-17 -17.9868 0.23438E-18 -18.6301 0.22735E+00 -0.6433 89 P2O7-4 0.10166E-16 -16.9929 0.76094E-18 -18.1186 0.74852E-01 -1.1258 90 H2S,aq 0.90837E-08 -8.0417 0.90510E-08 -8.0433 0.99640E+00 -0.0016 91 S2-2 0.61829E-14 -14.2088 0.31800E-14 -14.4976 0.51433E+00 -0.2888 97 SO3-2 0.21343E-17 -17.6708 0.11140E-17 -17.9531 0.52194E+00 -0.2824 99 HSO4- 0.63381E-19 -19.1980 0.52991E-19 -19.2758 0.83607E+00 -0.0778 Charge balance for all species = -.2416E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9059208E-10 -.2306544E-01 -.2320640E+02 0.0000 2 H2O 0.1000000E+01 0.5550443E+02 0.9981150E+06 0.0000 3 Cl- 0.2560909E-03 0.2572882E-03 0.9105090E+01 6.4486 4 SO4-- 0.1458156E-11 -.2553443E-04 -.2448429E+01 8.1145 5 HCO3- 0.5259158E-06 0.2437236E-04 0.1484435E+01 3.7618 6 HS- 0.4755052E-04 0.7309404E-04 0.2412981E+01 5.7174 7 Al+++ 0.1113803E-28 0.5260326E-05 0.1416740E+00 0.7608 8 H4SiO4 0.7116586E-03 0.1416490E-01 0.1358995E+04 -3.1477 9 Ca++ 0.1442454E-06 0.2448317E-06 0.9794565E-02 13.1065 10 Mg++ 0.2290485E-10 0.9827027E-10 0.2384813E-05 9.3053 11 Fe++ 0.6265454E-13 0.3780195E-07 0.2107296E-02 6.7428 12 K+ 0.1620165E-03 0.1627932E-03 0.6353991E+01 6.2505 13 Na+ 0.2059810E-01 0.2319008E-01 0.5321681E+03 8.3540 14 Mn++ 0.2012483E-10 0.2639453E-08 0.1447432E-03 9.2500 15 HPO4-- 0.4850596E-07 0.4974929E-07 0.4766225E-02 12.6366 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7616914E+02 -.1236915E-01 -.7615677E+02 0.0000000E+00 2 H2O -.2154625E+01 0.2976498E+02 -.3191961E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1275072E+00 -.1369318E-04 0.1275209E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1274817E+00 0.3919765E-04 -.1275209E+00 0.0000000E+00 7 Al+++ 0.1499941E+02 0.2820919E-05 0.1499941E+02 0.0000000E+00 8 H4SiO4 0.4789879E+02 0.7596115E-02 0.4789120E+02 0.0000000E+00 9 Ca++ 0.5290670E+01 0.1312942E-06 0.5290669E+01 0.0000000E+00 10 Mg++ 0.3650793E+01 0.5269873E-10 0.3650793E+01 0.0000000E+00 11 Fe++ 0.3279839E+01 0.2027180E-07 0.3279839E+01 0.0000000E+00 12 K+ 0.9766452E+00 0.8729999E-04 0.9765579E+00 0.0000000E+00 13 Na+ 0.5774279E+01 0.1243599E-01 0.5761844E+01 0.0000000E+00 14 Mn++ 0.7975752E-01 0.1415442E-08 0.7975752E-01 0.0000000E+00 15 HPO4-- 0.2722085E-01 0.2667872E-07 0.2722082E-01 0.0000000E+00 Chg. balance for solid moles: 0.1685E-13 Mass of aqueous solution: 0.537238E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 4599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 5.758 0.760 1510. 3.179 30.04 579.6 andradite 0.5101 -0.292 259.2 2.414 5.158 67.35 grossular 0.1218 -0.914 54.86 1.739 1.092 15.26 apatite-OH 0.9074E-02 -2.042 4.558 0.659 0.9069E-01 1.448 clinochlore 0.6556 -0.183 364.4 2.562 7.251 138.6 daphnite 0.1879 -0.726 134.1 2.127 2.668 40.62 chlorite-Mn 0.1595E-01 -1.797 11.31 1.053 0.2250 3.604 diopside 0.2566 -0.591 55.57 1.745 1.106 16.98 hedenbergite 0.6573E-01 -1.182 16.31 1.212 0.3245 4.467 microcline 0.8551 -0.068 238.0 2.377 4.736 92.97 stilbite 2.963 0.472 2088. 3.320 41.55 974.0 stilpnomelane-Fe 0.2429 -0.615 261.8 2.418 5.210 90.44 tr.625ac.25prg.125 0.3211E-01 -1.493 27.45 1.439 0.5462 8.834 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1856E-01 0.1856E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5025.538691 g Volume = 2034.134852 cm3 Porosity: -10.4908% V(tot) - V(min): -.19314E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4599.9990000 g log = 3.6628 Original solution: 1000.0103000 g Original solution / Rock added: 0.22 (Water/Rock Ratio), log = -0.6628 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1031 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9543E+00 0.9848 0.1037E+01 0.1053E+01 CO2,gas 0.6932E-08 1.0069 0.7700E-08 0.7647E-08 CH4,gas 0.3217E-01 1.0126 0.3594E-01 0.3549E-01 H2,gas 0.1351E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.2403E-06 0.9957 0.2640E-06 0.2651E-06 S2,gas 0.1065E-28 1.0000 0.1174E-28 0.1174E-28 CO,gas 0.2696E-13 1.0000 0.2974E-13 0.2974E-13 SO3,gas 0.1471E-47 1.0000 0.1622E-47 0.1622E-47 SO2,gas 0.8296E-27 1.0000 0.9150E-27 0.9150E-27 HCl,gas 0.4884E-17 1.0000 0.5388E-17 0.5388E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.48 -10.11 -3.371 0.17269E+05 -8.114 3 CH4,gas 4.81 1.36 -3.44 -0.861 0.58813E+04 -1.444 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.52 -8.58 -4.289 0.14647E+05 -6.578 6 S2,gas -7.03 -37.96 -30.93 -4.758 0.52813E+05 -28.930 7 CO,gas 3.51 -12.02 -15.53 -4.777 0.26511E+05 -13.527 8 SO3,gas 17.43 -32.36 -49.79 -12.447 0.85015E+05 -47.790 9 SO2,gas 1.14 -27.90 -29.04 -7.744 0.49583E+05 -27.039 10 HCl,gas 5.48 -13.79 -19.27 -9.634 0.32901E+05 -17.269 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80617E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94128E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.37 -4.36 -1.452 0.74385E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.37 -4.20 -1.401 0.71771E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65554E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.56 -4.45 -1.271 0.75961E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.56 -4.01 -1.145 0.68422E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82265E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92776E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40701E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43450E+04 143 pyrrhotite -4.24 -7.78 -3.53 -1.178 0.60354E+04 144 pyrrhotiteFe0.875 -6.00 -9.17 -3.17 -1.167 0.54181E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22432E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28298E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23225E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47137E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91027E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.78 -3.38 -1.128 0.57786E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80435E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66782E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.27 -4.31 -1.436 0.73570E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 4599.9990000 g New total amount of reactant added: 4799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1300E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 4799.9990000 Water: Moles liquid = 0.2865E+02 kg liquid = 0.5162E+00 Moles total = -.4662E+01 kg total = -.8398E-01 Activity = 1.0000 Stoichiometric ionic strength = .1183622E-01 Osmotic coef. = 0.9681 True ionic strength = .2076822E-01 Chg. balance for total moles = -.1300E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90620E-10 -10.0428 0.76008E-10 -10.1191 0.83876E+00 -0.0764 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.26606E-03 -3.5750 0.22178E-03 -3.6541 0.83359E+00 -0.0790 4 SO4-- 0.15146E-11 -11.8197 0.78063E-12 -12.1076 0.51541E+00 -0.2879 5 HCO3- 0.54626E-06 -6.2626 0.45604E-06 -6.3410 0.83484E+00 -0.0784 6 HS- 0.49402E-04 -4.3063 0.41187E-04 -4.3852 0.83371E+00 -0.0790 7 Al+++ 0.11150E-28 -28.9527 0.25318E-29 -29.5966 0.22707E+00 -0.6438 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14434E-06 -6.8406 0.73834E-07 -7.1317 0.51153E+00 -0.2911 10 Mg++ 0.22920E-10 -10.6398 0.11669E-10 -10.9330 0.50913E+00 -0.2932 11 Fe++ 0.62696E-13 -13.2028 0.31957E-13 -13.4954 0.50970E+00 -0.2927 12 K+ 0.16207E-03 -3.7903 0.13533E-03 -3.8686 0.83504E+00 -0.0783 13 Na+ 0.20604E-01 -1.6860 0.17172E-01 -1.7652 0.83343E+00 -0.0791 14 Mn++ 0.20140E-10 -10.6959 0.10274E-10 -10.9883 0.51014E+00 -0.2923 15 HPO4-- 0.48482E-07 -7.3144 0.24991E-07 -7.6022 0.51548E+00 -0.2878 16 HSiO3- 0.10959E-01 -1.9602 0.91351E-02 -2.0393 0.83359E+00 -0.0790 17 Ca(HSiO3)+ 0.18093E-07 -7.7425 0.15112E-07 -7.8207 0.83522E+00 -0.0782 18 Mg(HSiO3)+ 0.35589E-11 -11.4487 0.29724E-11 -11.5269 0.83522E+00 -0.0782 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67736E-16 -16.1692 0.56574E-16 -16.2474 0.83522E+00 -0.0782 22 HAlO2,aq 0.14895E-09 -9.8270 0.14895E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52588E-05 -5.2791 0.43756E-05 -5.3590 0.83206E+00 -0.0798 24 CH4,aq 0.23696E-04 -4.6253 0.23610E-04 -4.6269 0.99639E+00 -0.0016 25 C2H6,aq 0.88760E-14 -14.0518 0.88440E-14 -14.0534 0.99639E+00 -0.0016 29 CO,aq 0.19565E-16 -16.7085 0.19565E-16 -16.7085 0.10000E+01 0.0000 30 CO2,aq 0.70140E-10 -10.1540 0.69887E-10 -10.1556 0.99639E+00 -0.0016 31 CO3-2 0.10787E-05 -5.9671 0.55474E-06 -6.2559 0.51429E+00 -0.2888 32 CaCO3,aq 0.50165E-09 -9.2996 0.50165E-09 -9.2996 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10158E-11 -11.9932 0.84842E-12 -12.0714 0.83522E+00 -0.0782 34 CaCl+ 0.31242E-10 -10.5053 0.26094E-10 -10.5835 0.83522E+00 -0.0782 35 CaCl2,aq 0.13475E-14 -14.8705 0.13475E-14 -14.8705 0.10000E+01 0.0000 36 CaOH+ 0.82010E-07 -7.0861 0.68496E-07 -7.1643 0.83522E+00 -0.0782 37 CaSO4,aq 0.17958E-16 -16.7457 0.17958E-16 -16.7457 0.10000E+01 0.0000 38 HCl,aq 0.31708E-14 -14.4988 0.31708E-14 -14.4988 0.10000E+01 0.0000 43 FeCl+ 0.13217E-16 -16.8789 0.11039E-16 -16.9571 0.83522E+00 -0.0782 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16688E-10 -10.7776 0.13938E-10 -10.8558 0.83522E+00 -0.0782 48 HFeO2- 0.37133E-07 -7.4302 0.30954E-07 -7.5093 0.83359E+00 -0.0790 49 FeO+ 0.12318E-16 -16.9095 0.10288E-16 -16.9877 0.83522E+00 -0.0782 51 FeO2- 0.41987E-09 -9.3769 0.35000E-09 -9.4559 0.83359E+00 -0.0790 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99639E+00 -0.0016 54 KCl,aq 0.53145E-09 -9.2745 0.53145E-09 -9.2745 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.19525E-14 -14.7094 0.16276E-14 -14.7885 0.83359E+00 -0.0790 58 MgCO3,aq 0.19812E-13 -13.7031 0.19812E-13 -13.7031 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.16371E-15 -15.7859 0.13674E-15 -15.8641 0.83522E+00 -0.0782 60 MgCl+ 0.44826E-14 -14.3485 0.37439E-14 -14.4267 0.83522E+00 -0.0782 61 MgOH+ 0.71808E-10 -10.1438 0.59975E-10 -10.2220 0.83522E+00 -0.0782 63 MnO,aq 0.18773E-08 -8.7265 0.18773E-08 -8.7265 0.10000E+01 0.0000 64 MnOH+ 0.49842E-09 -9.3024 0.41629E-09 -9.3806 0.83522E+00 -0.0782 65 MnO2-2 0.21852E-10 -10.6605 0.11238E-10 -10.9493 0.51429E+00 -0.2888 66 HMnO2- 0.22201E-09 -9.6536 0.18507E-09 -9.7327 0.83359E+00 -0.0790 69 MnCl+ 0.16512E-13 -13.7822 0.13791E-13 -13.8604 0.83522E+00 -0.0782 71 NaCl,aq 0.12436E-05 -5.9053 0.12436E-05 -5.9053 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94846E-02 -2.0230 0.78917E-02 -2.1028 0.83206E+00 -0.0798 79 HPO3-2 0.16684E-14 -14.7777 0.85804E-15 -15.0665 0.51429E+00 -0.2888 81 H2PO3- 0.15368E-18 -18.8134 0.12811E-18 -18.8924 0.83359E+00 -0.0790 82 H3PO4,aq 0.92952E-18 -18.0317 0.92952E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39913E-10 -10.3989 0.33303E-10 -10.4775 0.83440E+00 -0.0786 84 PO4-3 0.12026E-08 -8.9199 0.28715E-09 -9.5419 0.23877E+00 -0.6220 88 HP2O7-3 0.10302E-17 -17.9871 0.23418E-18 -18.6305 0.22731E+00 -0.6434 89 P2O7-4 0.10157E-16 -16.9932 0.76006E-18 -18.1192 0.74828E-01 -1.1259 90 H2S,aq 0.94399E-08 -8.0250 0.94059E-08 -8.0266 0.99639E+00 -0.0016 91 S2-2 0.66739E-14 -14.1756 0.34323E-14 -14.4644 0.51429E+00 -0.2888 97 SO3-2 0.22168E-17 -17.6543 0.11570E-17 -17.9367 0.52190E+00 -0.2824 99 HSO4- 0.65849E-19 -19.1814 0.55054E-19 -19.2592 0.83605E+00 -0.0778 Charge balance for all species = -.2521E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9062008E-10 -.2306000E-01 -.2320093E+02 0.0000 2 H2O 0.1000000E+01 0.5550443E+02 0.9981147E+06 0.0000 3 Cl- 0.2660597E-03 0.2673038E-03 0.9459529E+01 6.4651 4 SO4-- 0.1514588E-11 -.2642289E-04 -.2533620E+01 8.1307 5 HCO3- 0.5462600E-06 0.2532112E-04 0.1542221E+01 3.7781 6 HS- 0.4940156E-04 0.7583390E-04 0.2503428E+01 5.7339 7 Al+++ 0.1114977E-28 0.5258901E-05 0.1416356E+00 0.7608 8 H4SiO4 0.7116593E-03 0.1416197E-01 0.1358714E+04 -3.1477 9 Ca++ 0.1443409E-06 0.2449782E-06 0.9800423E-02 13.1065 10 Mg++ 0.2292004E-10 0.9831103E-10 0.2385801E-05 9.3053 11 Fe++ 0.6269612E-13 0.3779187E-07 0.2106733E-02 6.7428 12 K+ 0.1620667E-03 0.1628434E-03 0.6355951E+01 6.2505 13 Na+ 0.2060449E-01 0.2319652E-01 0.5323159E+03 8.3540 14 Mn++ 0.2013989E-10 0.2639774E-08 0.1447608E-03 9.2500 15 HPO4-- 0.4848196E-07 0.4972445E-07 0.4763844E-02 12.6361 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.7948084E+02 -.1190288E-01 -.7946894E+02 0.0000000E+00 2 H2O -.4661707E+01 0.2864971E+02 -.3331142E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1330498E+00 -.1363870E-04 0.1330635E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1330243E+00 0.3914317E-04 -.1330635E+00 0.0000000E+00 7 Al+++ 0.1565156E+02 0.2714486E-05 0.1565155E+02 0.0000000E+00 8 H4SiO4 0.4998135E+02 0.7309983E-02 0.4997404E+02 0.0000000E+00 9 Ca++ 0.5520698E+01 0.1264504E-06 0.5520698E+01 0.0000000E+00 10 Mg++ 0.3809523E+01 0.5074519E-10 0.3809523E+01 0.0000000E+00 11 Fe++ 0.3422441E+01 0.1950702E-07 0.3422441E+01 0.0000000E+00 12 K+ 0.1019108E+01 0.8405487E-04 0.1019024E+01 0.0000000E+00 13 Na+ 0.6025328E+01 0.1197335E-01 0.6013355E+01 0.0000000E+00 14 Mn++ 0.8322524E-01 0.1362572E-08 0.8322524E-01 0.0000000E+00 15 HPO4-- 0.2840436E-01 0.2566626E-07 0.2840434E-01 0.0000000E+00 Chg. balance for solid moles: -.1418E-13 Mass of aqueous solution: 0.517108E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 4799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.009 0.779 1576. 3.197 30.05 604.9 andradite 0.5323 -0.274 270.5 2.432 5.158 70.27 grossular 0.1271 -0.896 57.24 1.758 1.092 15.93 apatite-OH 0.9468E-02 -2.024 4.756 0.677 0.9069E-01 1.511 clinochlore 0.6840 -0.165 380.2 2.580 7.250 144.6 daphnite 0.1960 -0.708 139.9 2.146 2.667 42.39 chlorite-Mn 0.1665E-01 -1.779 11.80 1.072 0.2250 3.761 diopside 0.2682 -0.572 58.07 1.764 1.107 17.75 hedenbergite 0.6870E-01 -1.163 17.04 1.232 0.3250 4.668 microcline 0.8923 -0.049 248.4 2.395 4.736 97.02 stilbite 3.092 0.490 2179. 3.338 41.55 1016. stilpnomelane-Fe 0.2534 -0.596 273.2 2.436 5.210 94.37 tr.625ac.25prg.125 0.3347E-01 -1.475 28.61 1.457 0.5456 9.209 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1856E-01 0.1856E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5244.049654 g Volume = 2122.547565 cm3 Porosity: -10.4918% V(tot) - V(min): -.20155E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4799.9990000 g log = 3.6812 Original solution: 1000.0103000 g Original solution / Rock added: 0.21 (Water/Rock Ratio), log = -0.6812 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1045 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9531E+00 0.9848 0.1037E+01 0.1053E+01 CO2,gas 0.7194E-08 1.0069 0.8000E-08 0.7945E-08 CH4,gas 0.3338E-01 1.0126 0.3734E-01 0.3687E-01 H2,gas 0.1349E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.2495E-06 0.9957 0.2743E-06 0.2755E-06 S2,gas 0.1148E-28 1.0000 0.1268E-28 0.1268E-28 CO,gas 0.2797E-13 1.0000 0.3089E-13 0.3089E-13 SO3,gas 0.1527E-47 1.0000 0.1686E-47 0.1686E-47 SO2,gas 0.8610E-27 1.0000 0.9509E-27 0.9509E-27 HCl,gas 0.5069E-17 1.0000 0.5599E-17 0.5599E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.84926E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.46 -10.10 -3.366 0.17240E+05 -8.097 3 CH4,gas 4.81 1.38 -3.43 -0.857 0.58530E+04 -1.428 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.50 -8.56 -4.281 0.14619E+05 -6.562 6 S2,gas -7.03 -37.93 -30.90 -4.753 0.52756E+05 -28.897 7 CO,gas 3.51 -12.00 -15.51 -4.772 0.26483E+05 -13.510 8 SO3,gas 17.43 -32.35 -49.77 -12.443 0.84986E+05 -47.773 9 SO2,gas 1.14 -27.89 -29.02 -7.739 0.49554E+05 -27.022 10 HCl,gas 5.48 -13.77 -19.25 -9.626 0.32872E+05 -17.252 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80615E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94128E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.35 -4.34 -1.447 0.74101E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.35 -4.19 -1.396 0.71488E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65554E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.54 -4.43 -1.266 0.75677E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56970E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.54 -3.99 -1.140 0.68139E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82265E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92776E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40701E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43450E+04 143 pyrrhotite -4.24 -7.76 -3.52 -1.173 0.60069E+04 144 pyrrhotiteFe0.875 -6.00 -9.16 -3.16 -1.161 0.53896E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22432E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28298E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23224E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47136E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91027E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.76 -3.37 -1.123 0.57500E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80436E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.25 -4.29 -1.431 0.73284E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 4799.9990000 g New total amount of reactant added: 4999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1299E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 4999.9990000 Water: Moles liquid = 0.2754E+02 kg liquid = 0.4961E+00 Moles total = -.7169E+01 kg total = -.1291E+00 Activity = 1.0000 Stoichiometric ionic strength = .1184521E-01 Osmotic coef. = 0.9681 True ionic strength = .2077524E-01 Chg. balance for total moles = -.1299E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90650E-10 -10.0426 0.76032E-10 -10.1190 0.83874E+00 -0.0764 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.27684E-03 -3.5578 0.23076E-03 -3.6368 0.83357E+00 -0.0791 4 SO4-- 0.15756E-11 -11.8026 0.81198E-12 -12.0905 0.51536E+00 -0.2879 5 HCO3- 0.56824E-06 -6.2455 0.47438E-06 -6.3239 0.83482E+00 -0.0784 6 HS- 0.51403E-04 -4.2890 0.42854E-04 -4.3680 0.83369E+00 -0.0790 7 Al+++ 0.11162E-28 -28.9522 0.25341E-29 -29.5962 0.22702E+00 -0.6439 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14444E-06 -6.8403 0.73880E-07 -7.1315 0.51148E+00 -0.2912 10 Mg++ 0.22936E-10 -10.6395 0.11677E-10 -10.9327 0.50909E+00 -0.2932 11 Fe++ 0.62741E-13 -13.2024 0.31976E-13 -13.4952 0.50966E+00 -0.2927 12 K+ 0.16212E-03 -3.7902 0.13537E-03 -3.8685 0.83502E+00 -0.0783 13 Na+ 0.20611E-01 -1.6859 0.17178E-01 -1.7650 0.83341E+00 -0.0791 14 Mn++ 0.20156E-10 -10.6956 0.10281E-10 -10.9880 0.51009E+00 -0.2924 15 HPO4-- 0.48456E-07 -7.3147 0.24976E-07 -7.6025 0.51543E+00 -0.2878 16 HSiO3- 0.10956E-01 -1.9604 0.91323E-02 -2.0394 0.83357E+00 -0.0791 17 Ca(HSiO3)+ 0.18100E-07 -7.7423 0.15117E-07 -7.8205 0.83520E+00 -0.0782 18 Mg(HSiO3)+ 0.35601E-11 -11.4485 0.29734E-11 -11.5268 0.83520E+00 -0.0782 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67758E-16 -16.1690 0.56592E-16 -16.2472 0.83520E+00 -0.0782 22 HAlO2,aq 0.14895E-09 -9.8270 0.14895E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52572E-05 -5.2792 0.43742E-05 -5.3591 0.83204E+00 -0.0799 24 CH4,aq 0.24656E-04 -4.6081 0.24567E-04 -4.6096 0.99639E+00 -0.0016 25 C2H6,aq 0.96102E-14 -14.0173 0.95755E-14 -14.0188 0.99639E+00 -0.0016 29 CO,aq 0.20359E-16 -16.6913 0.20359E-16 -16.6913 0.10000E+01 0.0000 30 CO2,aq 0.72983E-10 -10.1368 0.72720E-10 -10.1383 0.99639E+00 -0.0016 31 CO3-2 0.11218E-05 -5.9501 0.57687E-06 -6.2389 0.51424E+00 -0.2888 32 CaCO3,aq 0.52199E-09 -9.2823 0.52199E-09 -9.2823 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.10573E-11 -11.9758 0.88309E-12 -12.0540 0.83520E+00 -0.0782 34 CaCl+ 0.32528E-10 -10.4877 0.27167E-10 -10.5660 0.83520E+00 -0.0782 35 CaCl2,aq 0.14597E-14 -14.8357 0.14597E-14 -14.8357 0.10000E+01 0.0000 36 CaOH+ 0.82037E-07 -7.0860 0.68518E-07 -7.1642 0.83520E+00 -0.0782 37 CaSO4,aq 0.18691E-16 -16.7284 0.18691E-16 -16.7284 0.10000E+01 0.0000 38 HCl,aq 0.33002E-14 -14.4815 0.33002E-14 -14.4815 0.10000E+01 0.0000 43 FeCl+ 0.13761E-16 -16.8614 0.11493E-16 -16.9396 0.83520E+00 -0.0782 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16694E-10 -10.7774 0.13943E-10 -10.8556 0.83520E+00 -0.0782 48 HFeO2- 0.37122E-07 -7.4304 0.30944E-07 -7.5094 0.83357E+00 -0.0791 49 FeO+ 0.12322E-16 -16.9093 0.10291E-16 -16.9875 0.83520E+00 -0.0782 51 FeO2- 0.41975E-09 -9.3770 0.34989E-09 -9.4561 0.83357E+00 -0.0791 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99639E+00 -0.0016 54 KCl,aq 0.55314E-09 -9.2572 0.55314E-09 -9.2572 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.20316E-14 -14.6922 0.16935E-14 -14.7712 0.83357E+00 -0.0791 58 MgCO3,aq 0.20615E-13 -13.6858 0.20615E-13 -13.6858 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.17041E-15 -15.7685 0.14232E-15 -15.8467 0.83520E+00 -0.0782 60 MgCl+ 0.46671E-14 -14.3310 0.38979E-14 -14.4092 0.83520E+00 -0.0782 61 MgOH+ 0.71832E-10 -10.1437 0.59994E-10 -10.2219 0.83520E+00 -0.0782 63 MnO,aq 0.18775E-08 -8.7264 0.18775E-08 -8.7264 0.10000E+01 0.0000 64 MnOH+ 0.49863E-09 -9.3022 0.41646E-09 -9.3804 0.83520E+00 -0.0782 65 MnO2-2 0.21842E-10 -10.6607 0.11232E-10 -10.9495 0.51424E+00 -0.2888 66 HMnO2- 0.22197E-09 -9.6537 0.18502E-09 -9.7328 0.83357E+00 -0.0791 69 MnCl+ 0.17193E-13 -13.7647 0.14359E-13 -13.8429 0.83520E+00 -0.0782 71 NaCl,aq 0.12943E-05 -5.8880 0.12943E-05 -5.8880 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94819E-02 -2.0231 0.78893E-02 -2.1030 0.83204E+00 -0.0799 79 HPO3-2 0.16675E-14 -14.7779 0.85750E-15 -15.0668 0.51424E+00 -0.2888 81 H2PO3- 0.15364E-18 -18.8135 0.12807E-18 -18.8926 0.83357E+00 -0.0791 82 H3PO4,aq 0.92952E-18 -18.0317 0.92952E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39901E-10 -10.3990 0.33293E-10 -10.4777 0.83438E+00 -0.0786 84 PO4-3 0.12017E-08 -8.9202 0.28688E-09 -9.5423 0.23873E+00 -0.6221 88 HP2O7-3 0.10294E-17 -17.9874 0.23396E-18 -18.6309 0.22726E+00 -0.6435 89 P2O7-4 0.10148E-16 -16.9936 0.75911E-18 -18.1197 0.74801E-01 -1.1261 90 H2S,aq 0.98251E-08 -8.0077 0.97897E-08 -8.0092 0.99639E+00 -0.0016 91 S2-2 0.72258E-14 -14.1411 0.37158E-14 -14.4299 0.51424E+00 -0.2888 97 SO3-2 0.23061E-17 -17.6371 0.12034E-17 -17.9196 0.52186E+00 -0.2824 99 HSO4- 0.68517E-19 -19.1642 0.57283E-19 -19.2420 0.83603E+00 -0.0778 Charge balance for all species = -.2619E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9065035E-10 -.2305413E-01 -.2319501E+02 0.0000 2 H2O 0.1000000E+01 0.5550443E+02 0.9981144E+06 0.0000 3 Cl- 0.2768360E-03 0.2781309E-03 0.9842681E+01 6.4822 4 SO4-- 0.1575560E-11 -.2738339E-04 -.2625718E+01 8.1476 5 HCO3- 0.5682408E-06 0.2634675E-04 0.1604687E+01 3.7951 6 HS- 0.5140256E-04 0.7879577E-04 0.2601205E+01 5.7510 7 Al+++ 0.1116248E-28 0.5257365E-05 0.1415942E+00 0.7608 8 H4SiO4 0.7116599E-03 0.1415881E-01 0.1358410E+04 -3.1477 9 Ca++ 0.1444442E-06 0.2451367E-06 0.9806759E-02 13.1065 10 Mg++ 0.2293647E-10 0.9835509E-10 0.2386869E-05 9.3053 11 Fe++ 0.6274110E-13 0.3778097E-07 0.2106125E-02 6.7428 12 K+ 0.1621210E-03 0.1628978E-03 0.6358070E+01 6.2505 13 Na+ 0.2061141E-01 0.2320349E-01 0.5324756E+03 8.3540 14 Mn++ 0.2015590E-10 0.2640085E-08 0.1447778E-03 9.2501 15 HPO4-- 0.4845602E-07 0.4969760E-07 0.4761270E-02 12.6355 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8279255E+02 -.1143661E-01 -.8278111E+02 0.0000000E+00 2 H2O -.7168789E+01 0.2753444E+02 -.3470323E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1385925E+00 -.1358425E-04 0.1386061E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1385670E+00 0.3908872E-04 -.1386061E+00 0.0000000E+00 7 Al+++ 0.1630370E+02 0.2608055E-05 0.1630370E+02 0.0000000E+00 8 H4SiO4 0.5206390E+02 0.7023851E-02 0.5205688E+02 0.0000000E+00 9 Ca++ 0.5750727E+01 0.1216065E-06 0.5750726E+01 0.0000000E+00 10 Mg++ 0.3968253E+01 0.4879164E-10 0.3968253E+01 0.0000000E+00 11 Fe++ 0.3565042E+01 0.1874225E-07 0.3565042E+01 0.0000000E+00 12 K+ 0.1061571E+01 0.8080975E-04 0.1061490E+01 0.0000000E+00 13 Na+ 0.6276377E+01 0.1151071E-01 0.6264866E+01 0.0000000E+00 14 Mn++ 0.8669296E-01 0.1309684E-08 0.8669296E-01 0.0000000E+00 15 HPO4-- 0.2958788E-01 0.2465381E-07 0.2958785E-01 0.0000000E+00 Chg. balance for solid moles: 0.1929E-13 Mass of aqueous solution: 0.496978E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 4999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.261 0.797 1642. 3.215 30.05 630.2 andradite 0.5544 -0.256 281.7 2.450 5.158 73.20 grossular 0.1324 -0.878 59.63 1.775 1.092 16.59 apatite-OH 0.9863E-02 -2.006 4.954 0.695 0.9069E-01 1.574 clinochlore 0.7124 -0.147 396.0 2.598 7.249 150.6 daphnite 0.2042 -0.690 145.7 2.163 2.667 44.15 chlorite-Mn 0.1734E-01 -1.761 12.29 1.090 0.2250 3.917 diopside 0.2797 -0.553 60.58 1.782 1.109 18.51 hedenbergite 0.7166E-01 -1.145 17.78 1.250 0.3255 4.870 microcline 0.9295 -0.032 258.7 2.413 4.736 101.1 stilbite 3.220 0.508 2269. 3.356 41.54 1058. stilpnomelane-Fe 0.2640 -0.578 284.6 2.454 5.210 98.31 tr.625ac.25prg.125 0.3484E-01 -1.458 29.78 1.474 0.5451 9.584 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1856E-01 0.1856E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5462.560618 g Volume = 2210.960279 cm3 Porosity: -10.4928% V(tot) - V(min): -.20996E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 4999.9990000 g log = 3.6990 Original solution: 1000.0103000 g Original solution / Rock added: 0.20 (Water/Rock Ratio), log = -0.6990 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1060 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9518E+00 0.9848 0.1037E+01 0.1053E+01 CO2,gas 0.7475E-08 1.0069 0.8324E-08 0.8267E-08 CH4,gas 0.3469E-01 1.0126 0.3885E-01 0.3837E-01 H2,gas 0.1347E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.2593E-06 0.9957 0.2855E-06 0.2868E-06 S2,gas 0.1242E-28 1.0000 0.1374E-28 0.1374E-28 CO,gas 0.2907E-13 1.0000 0.3215E-13 0.3215E-13 SO3,gas 0.1587E-47 1.0000 0.1755E-47 0.1755E-47 SO2,gas 0.8949E-27 1.0000 0.9897E-27 0.9897E-27 HCl,gas 0.5269E-17 1.0000 0.5827E-17 0.5827E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.44 -10.08 -3.360 0.17211E+05 -8.080 3 CH4,gas 4.81 1.40 -3.41 -0.853 0.58235E+04 -1.411 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.49 -8.54 -4.272 0.14589E+05 -6.544 6 S2,gas -7.03 -37.89 -30.86 -4.748 0.52696E+05 -28.862 7 CO,gas 3.51 -11.98 -15.49 -4.767 0.26454E+05 -13.493 8 SO3,gas 17.43 -32.33 -49.76 -12.439 0.84957E+05 -47.756 9 SO2,gas 1.14 -27.87 -29.00 -7.735 0.49524E+05 -27.004 10 HCl,gas 5.48 -13.76 -19.23 -9.617 0.32842E+05 -17.235 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80613E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94128E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.34 -4.32 -1.441 0.73807E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.34 -4.17 -1.390 0.71193E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70327E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82194E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65553E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.52 -4.41 -1.261 0.75382E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.52 -3.97 -1.135 0.67844E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82264E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92776E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40701E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43450E+04 143 pyrrhotite -4.24 -7.74 -3.50 -1.167 0.59772E+04 144 pyrrhotiteFe0.875 -6.00 -9.14 -3.14 -1.155 0.53600E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22431E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28298E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23223E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47135E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91027E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.74 -3.35 -1.117 0.57204E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80436E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57932E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.24 -4.27 -1.425 0.72987E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 4999.9990000 g New total amount of reactant added: 5199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1299E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 5199.9990000 Water: Moles liquid = 0.2642E+02 kg liquid = 0.4760E+00 Moles total = -.9676E+01 kg total = -.1743E+00 Activity = 1.0000 Stoichiometric ionic strength = .1185496E-01 Osmotic coef. = 0.9680 True ionic strength = .2078285E-01 Chg. balance for total moles = -.1299E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90683E-10 -10.0425 0.76058E-10 -10.1189 0.83872E+00 -0.0764 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.28852E-03 -3.5398 0.24050E-03 -3.6189 0.83355E+00 -0.0791 4 SO4-- 0.16416E-11 -11.7847 0.84596E-12 -12.0727 0.51531E+00 -0.2879 5 HCO3- 0.59206E-06 -6.2276 0.49425E-06 -6.3061 0.83480E+00 -0.0784 6 HS- 0.53572E-04 -4.2711 0.44662E-04 -4.3501 0.83367E+00 -0.0790 7 Al+++ 0.11176E-28 -28.9517 0.25367E-29 -29.5957 0.22697E+00 -0.6440 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14456E-06 -6.8400 0.73931E-07 -7.1312 0.51143E+00 -0.2912 10 Mg++ 0.22954E-10 -10.6391 0.11685E-10 -10.9324 0.50904E+00 -0.2933 11 Fe++ 0.62790E-13 -13.2021 0.31998E-13 -13.4949 0.50961E+00 -0.2928 12 K+ 0.16218E-03 -3.7900 0.13542E-03 -3.8683 0.83500E+00 -0.0783 13 Na+ 0.20619E-01 -1.6857 0.17184E-01 -1.7649 0.83339E+00 -0.0792 14 Mn++ 0.20173E-10 -10.6952 0.10289E-10 -10.9876 0.51004E+00 -0.2924 15 HPO4-- 0.48428E-07 -7.3149 0.24959E-07 -7.6028 0.51538E+00 -0.2879 16 HSiO3- 0.10952E-01 -1.9605 0.91292E-02 -2.0396 0.83355E+00 -0.0791 17 Ca(HSiO3)+ 0.18106E-07 -7.7422 0.15122E-07 -7.8204 0.83518E+00 -0.0782 18 Mg(HSiO3)+ 0.35614E-11 -11.4484 0.29744E-11 -11.5266 0.83518E+00 -0.0782 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67783E-16 -16.1689 0.56611E-16 -16.2471 0.83518E+00 -0.0782 22 HAlO2,aq 0.14895E-09 -9.8270 0.14895E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52556E-05 -5.2794 0.43727E-05 -5.3592 0.83202E+00 -0.0799 24 CH4,aq 0.25698E-04 -4.5901 0.25605E-04 -4.5917 0.99639E+00 -0.0016 25 C2H6,aq 0.10439E-13 -13.9813 0.10402E-13 -13.9829 0.99639E+00 -0.0016 29 CO,aq 0.21219E-16 -16.6733 0.21219E-16 -16.6733 0.10000E+01 0.0000 30 CO2,aq 0.76067E-10 -10.1188 0.75792E-10 -10.1204 0.99639E+00 -0.0016 31 CO3-2 0.11685E-05 -5.9324 0.60084E-06 -6.2212 0.51419E+00 -0.2889 32 CaCO3,aq 0.54404E-09 -9.2644 0.54404E-09 -9.2644 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.11024E-11 -11.9577 0.92071E-12 -12.0359 0.83518E+00 -0.0782 34 CaCl+ 0.33924E-10 -10.4695 0.28332E-10 -10.5477 0.83518E+00 -0.0782 35 CaCl2,aq 0.15865E-14 -14.7996 0.15865E-14 -14.7996 0.10000E+01 0.0000 36 CaOH+ 0.82067E-07 -7.0858 0.68541E-07 -7.1641 0.83518E+00 -0.0782 37 CaSO4,aq 0.19487E-16 -16.7103 0.19487E-16 -16.7103 0.10000E+01 0.0000 38 HCl,aq 0.34406E-14 -14.4634 0.34406E-14 -14.4634 0.10000E+01 0.0000 43 FeCl+ 0.14351E-16 -16.8431 0.11986E-16 -16.9213 0.83518E+00 -0.0782 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16700E-10 -10.7773 0.13948E-10 -10.8555 0.83518E+00 -0.0782 48 HFeO2- 0.37111E-07 -7.4305 0.30934E-07 -7.5096 0.83355E+00 -0.0791 49 FeO+ 0.12326E-16 -16.9092 0.10295E-16 -16.9874 0.83518E+00 -0.0782 51 FeO2- 0.41962E-09 -9.3771 0.34977E-09 -9.4562 0.83355E+00 -0.0791 52 HFeO2,aq 0.33293E-11 -11.4776 0.33293E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99639E+00 -0.0016 54 KCl,aq 0.57667E-09 -9.2391 0.57667E-09 -9.2391 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.21174E-14 -14.6742 0.17649E-14 -14.7533 0.83355E+00 -0.0791 58 MgCO3,aq 0.21486E-13 -13.6678 0.21486E-13 -13.6678 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.17767E-15 -15.7504 0.14839E-15 -15.8286 0.83518E+00 -0.0782 60 MgCl+ 0.48674E-14 -14.3127 0.40651E-14 -14.3909 0.83518E+00 -0.0782 61 MgOH+ 0.71858E-10 -10.1435 0.60014E-10 -10.2217 0.83518E+00 -0.0782 63 MnO,aq 0.18776E-08 -8.7264 0.18776E-08 -8.7264 0.10000E+01 0.0000 64 MnOH+ 0.49885E-09 -9.3020 0.41663E-09 -9.3803 0.83518E+00 -0.0782 65 MnO2-2 0.21831E-10 -10.6609 0.11225E-10 -10.9498 0.51419E+00 -0.2889 66 HMnO2- 0.22191E-09 -9.6538 0.18498E-09 -9.7329 0.83355E+00 -0.0791 69 MnCl+ 0.17932E-13 -13.7464 0.14976E-13 -13.8246 0.83518E+00 -0.0782 71 NaCl,aq 0.13494E-05 -5.8699 0.13494E-05 -5.8699 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94789E-02 -2.0232 0.78866E-02 -2.1031 0.83202E+00 -0.0799 79 HPO3-2 0.16665E-14 -14.7782 0.85692E-15 -15.0671 0.51419E+00 -0.2889 81 H2PO3- 0.15359E-18 -18.8136 0.12803E-18 -18.8927 0.83355E+00 -0.0791 82 H3PO4,aq 0.92952E-18 -18.0317 0.92952E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39889E-10 -10.3991 0.33281E-10 -10.4778 0.83436E+00 -0.0786 84 PO4-3 0.12007E-08 -8.9206 0.28659E-09 -9.5427 0.23868E+00 -0.6222 88 HP2O7-3 0.10286E-17 -17.9877 0.23372E-18 -18.6313 0.22721E+00 -0.6436 89 P2O7-4 0.10139E-16 -16.9940 0.75809E-18 -18.1203 0.74773E-01 -1.1263 90 H2S,aq 0.10243E-07 -7.9896 0.10206E-07 -7.9911 0.99639E+00 -0.0016 91 S2-2 0.78492E-14 -14.1052 0.40360E-14 -14.3941 0.51419E+00 -0.2889 97 SO3-2 0.24028E-17 -17.6193 0.12538E-17 -17.9018 0.52181E+00 -0.2825 99 HSO4- 0.71410E-19 -19.1462 0.59700E-19 -19.2240 0.83601E+00 -0.0778 Charge balance for all species = -.2736E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9068319E-10 -.2304776E-01 -.2318859E+02 0.0000 2 H2O 0.1000000E+01 0.5550443E+02 0.9981140E+06 0.0000 3 Cl- 0.2885221E-03 0.2898721E-03 0.1025818E+02 6.5000 4 SO4-- 0.1641645E-11 -.2842504E-04 -.2725598E+01 8.1651 5 HCO3- 0.5920639E-06 0.2745896E-04 0.1672428E+01 3.8128 6 HS- 0.5357249E-04 0.8200777E-04 0.2707238E+01 5.7688 7 Al+++ 0.1117628E-28 0.5255702E-05 0.1415493E+00 0.7608 8 H4SiO4 0.7116605E-03 0.1415538E-01 0.1358080E+04 -3.1477 9 Ca++ 0.1445563E-06 0.2453086E-06 0.9813634E-02 13.1065 10 Mg++ 0.2295431E-10 0.9840100E-10 0.2387983E-05 9.3053 11 Fe++ 0.6278991E-13 0.3776916E-07 0.2105466E-02 6.7428 12 K+ 0.1621800E-03 0.1629567E-03 0.6360368E+01 6.2505 13 Na+ 0.2061891E-01 0.2321105E-01 0.5326489E+03 8.3540 14 Mn++ 0.2017303E-10 0.2640389E-08 0.1447944E-03 9.2501 15 HPO4-- 0.4842790E-07 0.4966850E-07 0.4758480E-02 12.6349 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8610425E+02 -.1097034E-01 -.8609328E+02 0.0000000E+00 2 H2O -.9675871E+01 0.2641917E+02 -.3609504E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1441352E+00 -.1352984E-04 0.1441487E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1441097E+00 0.3903431E-04 -.1441487E+00 0.0000000E+00 7 Al+++ 0.1695585E+02 0.2501625E-05 0.1695585E+02 0.0000000E+00 8 H4SiO4 0.5414646E+02 0.6737719E-02 0.5413972E+02 0.0000000E+00 9 Ca++ 0.5980755E+01 0.1167627E-06 0.5980755E+01 0.0000000E+00 10 Mg++ 0.4126983E+01 0.4683720E-10 0.4126983E+01 0.0000000E+00 11 Fe++ 0.3707644E+01 0.1797748E-07 0.3707644E+01 0.0000000E+00 12 K+ 0.1104034E+01 0.7756463E-04 0.1103956E+01 0.0000000E+00 13 Na+ 0.6527426E+01 0.1104807E-01 0.6516378E+01 0.0000000E+00 14 Mn++ 0.9016068E-01 0.1256780E-08 0.9016068E-01 0.0000000E+00 15 HPO4-- 0.3077139E-01 0.2364136E-07 0.3077137E-01 0.0000000E+00 Chg. balance for solid moles: 0.7945E-14 Mass of aqueous solution: 0.476849E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 5199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.512 0.814 1708. 3.232 30.06 655.5 andradite 0.5766 -0.239 293.0 2.467 5.158 76.13 grossular 0.1377 -0.861 62.01 1.792 1.092 17.25 apatite-OH 0.1026E-01 -1.989 5.152 0.712 0.9069E-01 1.637 clinochlore 0.7409 -0.130 411.8 2.615 7.249 156.6 daphnite 0.2123 -0.673 151.5 2.180 2.667 45.91 chlorite-Mn 0.1803E-01 -1.744 12.78 1.107 0.2250 4.074 diopside 0.2913 -0.536 63.08 1.800 1.110 19.28 hedenbergite 0.7463E-01 -1.127 18.51 1.268 0.3259 5.071 microcline 0.9667 -0.015 269.1 2.430 4.736 105.1 stilbite 3.348 0.525 2360. 3.373 41.54 1101. stilpnomelane-Fe 0.2746 -0.561 296.0 2.471 5.210 102.2 tr.625ac.25prg.125 0.3620E-01 -1.441 30.94 1.491 0.5447 9.959 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5681.071582 g Volume = 2299.372993 cm3 Porosity: -10.4937% V(tot) - V(min): -.21837E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 5199.9990000 g log = 3.7160 Original solution: 1000.0103000 g Original solution / Rock added: 0.19 (Water/Rock Ratio), log = -0.7160 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1076 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9504E+00 0.9848 0.1037E+01 0.1053E+01 CO2,gas 0.7779E-08 1.0069 0.8676E-08 0.8617E-08 CH4,gas 0.3610E-01 1.0126 0.4049E-01 0.3999E-01 H2,gas 0.1345E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.2699E-06 0.9957 0.2977E-06 0.2990E-06 S2,gas 0.1348E-28 1.0000 0.1493E-28 0.1493E-28 CO,gas 0.3025E-13 1.0000 0.3350E-13 0.3350E-13 SO3,gas 0.1652E-47 1.0000 0.1830E-47 0.1830E-47 SO2,gas 0.9316E-27 1.0000 0.1032E-26 0.1032E-26 HCl,gas 0.5485E-17 1.0000 0.6075E-17 0.6075E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.42 -10.06 -3.354 0.17180E+05 -8.062 3 CH4,gas 4.81 1.42 -3.39 -0.848 0.57928E+04 -1.393 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.47 -8.53 -4.263 0.14558E+05 -6.526 6 S2,gas -7.03 -37.86 -30.83 -4.742 0.52634E+05 -28.826 7 CO,gas 3.51 -11.96 -15.47 -4.762 0.26423E+05 -13.475 8 SO3,gas 17.43 -32.31 -49.74 -12.434 0.84926E+05 -47.738 9 SO2,gas 1.14 -27.85 -28.99 -7.730 0.49493E+05 -26.986 10 HCl,gas 5.48 -13.74 -19.22 -9.608 0.32812E+05 -17.216 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80612E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94128E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.32 -4.30 -1.435 0.73500E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.32 -4.15 -1.384 0.70886E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65553E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.50 -4.40 -1.256 0.75076E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.50 -3.96 -1.130 0.67537E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82264E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92776E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40701E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43450E+04 143 pyrrhotite -4.24 -7.73 -3.48 -1.161 0.59463E+04 144 pyrrhotiteFe0.875 -6.00 -9.12 -3.12 -1.148 0.53291E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22431E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28298E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23223E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47134E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91027E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.73 -3.33 -1.111 0.56895E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80436E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.22 -4.26 -1.419 0.72677E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 5199.9990000 g New total amount of reactant added: 5399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1299E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 5399.9990000 Water: Moles liquid = 0.2531E+02 kg liquid = 0.4559E+00 Moles total = -.1218E+02 kg total = -.2195E+00 Activity = 1.0000 Stoichiometric ionic strength = .1186557E-01 Osmotic coef. = 0.9680 True ionic strength = .2079113E-01 Chg. balance for total moles = -.1299E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90719E-10 -10.0423 0.76086E-10 -10.1187 0.83870E+00 -0.0764 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.30124E-03 -3.5211 0.25109E-03 -3.6002 0.83353E+00 -0.0791 4 SO4-- 0.17135E-11 -11.7661 0.88290E-12 -12.0541 0.51526E+00 -0.2880 5 HCO3- 0.61797E-06 -6.2090 0.51587E-06 -6.2875 0.83477E+00 -0.0784 6 HS- 0.55934E-04 -4.2523 0.46629E-04 -4.3313 0.83365E+00 -0.0790 7 Al+++ 0.11191E-28 -28.9511 0.25395E-29 -29.5952 0.22692E+00 -0.6441 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14468E-06 -6.8396 0.73985E-07 -7.1309 0.51138E+00 -0.2913 10 Mg++ 0.22974E-10 -10.6388 0.11693E-10 -10.9321 0.50898E+00 -0.2933 11 Fe++ 0.62843E-13 -13.2017 0.32022E-13 -13.4946 0.50955E+00 -0.2928 12 K+ 0.16224E-03 -3.7898 0.13547E-03 -3.8682 0.83497E+00 -0.0783 13 Na+ 0.20627E-01 -1.6856 0.17190E-01 -1.7647 0.83337E+00 -0.0792 14 Mn++ 0.20191E-10 -10.6948 0.10297E-10 -10.9873 0.50998E+00 -0.2924 15 HPO4-- 0.48397E-07 -7.3152 0.24941E-07 -7.6031 0.51533E+00 -0.2879 16 HSiO3- 0.10948E-01 -1.9606 0.91258E-02 -2.0397 0.83353E+00 -0.0791 17 Ca(HSiO3)+ 0.18113E-07 -7.7420 0.15127E-07 -7.8202 0.83516E+00 -0.0782 18 Mg(HSiO3)+ 0.35628E-11 -11.4482 0.29755E-11 -11.5264 0.83516E+00 -0.0782 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67810E-16 -16.1687 0.56632E-16 -16.2469 0.83516E+00 -0.0782 22 HAlO2,aq 0.14895E-09 -9.8270 0.14895E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52537E-05 -5.2795 0.43711E-05 -5.3594 0.83199E+00 -0.0799 24 CH4,aq 0.26831E-04 -4.5714 0.26734E-04 -4.5729 0.99638E+00 -0.0016 25 C2H6,aq 0.11381E-13 -13.9438 0.11339E-13 -13.9454 0.99638E+00 -0.0016 29 CO,aq 0.22155E-16 -16.6545 0.22155E-16 -16.6545 0.10000E+01 0.0000 30 CO2,aq 0.79423E-10 -10.1001 0.79136E-10 -10.1016 0.99638E+00 -0.0016 31 CO3-2 0.12193E-05 -5.9139 0.62688E-06 -6.2028 0.51414E+00 -0.2889 32 CaCO3,aq 0.56804E-09 -9.2456 0.56804E-09 -9.2456 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.11515E-11 -11.9387 0.96168E-12 -12.0170 0.83516E+00 -0.0782 34 CaCl+ 0.35445E-10 -10.4504 0.29602E-10 -10.5287 0.83516E+00 -0.0782 35 CaCl2,aq 0.17306E-14 -14.7618 0.17306E-14 -14.7618 0.10000E+01 0.0000 36 CaOH+ 0.82099E-07 -7.0857 0.68566E-07 -7.1639 0.83516E+00 -0.0782 37 CaSO4,aq 0.20353E-16 -16.6914 0.20353E-16 -16.6914 0.10000E+01 0.0000 38 HCl,aq 0.35935E-14 -14.4445 0.35935E-14 -14.4445 0.10000E+01 0.0000 43 FeCl+ 0.14995E-16 -16.8241 0.12523E-16 -16.9023 0.83516E+00 -0.0782 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16707E-10 -10.7771 0.13953E-10 -10.8553 0.83516E+00 -0.0782 48 HFeO2- 0.37098E-07 -7.4306 0.30922E-07 -7.5097 0.83353E+00 -0.0791 49 FeO+ 0.12331E-16 -16.9090 0.10299E-16 -16.9872 0.83516E+00 -0.0782 51 FeO2- 0.41947E-09 -9.3773 0.34964E-09 -9.4564 0.83353E+00 -0.0791 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99638E+00 -0.0016 54 KCl,aq 0.60229E-09 -9.2202 0.60229E-09 -9.2202 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.22107E-14 -14.6555 0.18427E-14 -14.7345 0.83353E+00 -0.0791 58 MgCO3,aq 0.22434E-13 -13.6491 0.22434E-13 -13.6491 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.18558E-15 -15.7315 0.15499E-15 -15.8097 0.83516E+00 -0.0782 60 MgCl+ 0.50856E-14 -14.2937 0.42473E-14 -14.3719 0.83516E+00 -0.0782 61 MgOH+ 0.71886E-10 -10.1434 0.60036E-10 -10.2216 0.83516E+00 -0.0782 63 MnO,aq 0.18777E-08 -8.7264 0.18777E-08 -8.7264 0.10000E+01 0.0000 64 MnOH+ 0.49908E-09 -9.3018 0.41681E-09 -9.3801 0.83516E+00 -0.0782 65 MnO2-2 0.21818E-10 -10.6612 0.11218E-10 -10.9501 0.51414E+00 -0.2889 66 HMnO2- 0.22185E-09 -9.6539 0.18492E-09 -9.7330 0.83353E+00 -0.0791 69 MnCl+ 0.18737E-13 -13.7273 0.15648E-13 -13.8055 0.83516E+00 -0.0782 71 NaCl,aq 0.14094E-05 -5.8510 0.14094E-05 -5.8510 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94756E-02 -2.0234 0.78837E-02 -2.1033 0.83199E+00 -0.0799 79 HPO3-2 0.16655E-14 -14.7785 0.85629E-15 -15.0674 0.51414E+00 -0.2889 81 H2PO3- 0.15354E-18 -18.8138 0.12798E-18 -18.8929 0.83353E+00 -0.0791 82 H3PO4,aq 0.92952E-18 -18.0317 0.92952E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39875E-10 -10.3993 0.33269E-10 -10.4780 0.83433E+00 -0.0787 84 PO4-3 0.11997E-08 -8.9209 0.28627E-09 -9.5432 0.23863E+00 -0.6223 88 HP2O7-3 0.10277E-17 -17.9881 0.23346E-18 -18.6318 0.22716E+00 -0.6437 89 P2O7-4 0.10128E-16 -16.9945 0.75697E-18 -18.1209 0.74741E-01 -1.1264 90 H2S,aq 0.10698E-07 -7.9707 0.10660E-07 -7.9723 0.99638E+00 -0.0016 91 S2-2 0.85568E-14 -14.0677 0.43994E-14 -14.3566 0.51414E+00 -0.2889 97 SO3-2 0.25080E-17 -17.6007 0.13085E-17 -17.8832 0.52176E+00 -0.2825 99 HSO4- 0.74558E-19 -19.1275 0.62330E-19 -19.2053 0.83599E+00 -0.0778 Charge balance for all species = -.2844E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9071893E-10 -.2304083E-01 -.2318161E+02 0.0000 2 H2O 0.1000000E+01 0.5550443E+02 0.9981137E+06 0.0000 3 Cl- 0.3012383E-03 0.3026482E-03 0.1071031E+02 6.5185 4 SO4-- 0.1713515E-11 -.2955859E-04 -.2834290E+01 8.1833 5 HCO3- 0.6179711E-06 0.2866922E-04 0.1746140E+01 3.8312 6 HS- 0.5593370E-04 0.8550299E-04 0.2822621E+01 5.7874 7 Al+++ 0.1119132E-28 0.5253895E-05 0.1415006E+00 0.7608 8 H4SiO4 0.7116611E-03 0.1415164E-01 0.1357721E+04 -3.1477 9 Ca++ 0.1446785E-06 0.2454959E-06 0.9821121E-02 13.1065 10 Mg++ 0.2297373E-10 0.9845193E-10 0.2389218E-05 9.3053 11 Fe++ 0.6284306E-13 0.3775632E-07 0.2104749E-02 6.7428 12 K+ 0.1622441E-03 0.1630209E-03 0.6362870E+01 6.2505 13 Na+ 0.2062708E-01 0.2321928E-01 0.5328375E+03 8.3540 14 Mn++ 0.2019145E-10 0.2640690E-08 0.1448108E-03 9.2501 15 HPO4-- 0.4839731E-07 0.4963684E-07 0.4755445E-02 12.6343 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.8941595E+02 -.1050408E-01 -.8940545E+02 0.0000000E+00 2 H2O -.1218295E+02 0.2530389E+02 -.3748685E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1496779E+00 -.1347545E-04 0.1496914E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1496524E+00 0.3897992E-04 -.1496914E+00 0.0000000E+00 7 Al+++ 0.1760800E+02 0.2395196E-05 0.1760800E+02 0.0000000E+00 8 H4SiO4 0.5622902E+02 0.6451586E-02 0.5622257E+02 0.0000000E+00 9 Ca++ 0.6210784E+01 0.1119190E-06 0.6210784E+01 0.0000000E+00 10 Mg++ 0.4285713E+01 0.4488321E-10 0.4285713E+01 0.0000000E+00 11 Fe++ 0.3850246E+01 0.1721271E-07 0.3850246E+01 0.0000000E+00 12 K+ 0.1146497E+01 0.7431952E-04 0.1146422E+01 0.0000000E+00 13 Na+ 0.6778474E+01 0.1058543E-01 0.6767889E+01 0.0000000E+00 14 Mn++ 0.9362840E-01 0.1203863E-08 0.9362840E-01 0.0000000E+00 15 HPO4-- 0.3195491E-01 0.2262892E-07 0.3195489E-01 0.0000000E+00 Chg. balance for solid moles: 0.2265E-13 Mass of aqueous solution: 0.456719E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 5399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 6.763 0.830 1773. 3.249 30.06 680.8 andradite 0.5988 -0.223 304.3 2.483 5.158 79.05 grossular 0.1430 -0.845 64.40 1.809 1.092 17.92 apatite-OH 0.1065E-01 -1.973 5.351 0.728 0.9069E-01 1.700 clinochlore 0.7693 -0.114 427.6 2.631 7.248 162.7 daphnite 0.2205 -0.657 157.3 2.197 2.667 47.67 chlorite-Mn 0.1873E-01 -1.728 13.28 1.123 0.2250 4.231 diopside 0.3029 -0.519 65.59 1.817 1.112 20.05 hedenbergite 0.7759E-01 -1.110 19.25 1.284 0.3263 5.273 microcline 1.004 0.002 279.4 2.446 4.736 109.1 stilbite 3.477 0.541 2450. 3.389 41.53 1143. stilpnomelane-Fe 0.2851 -0.545 307.4 2.488 5.210 106.2 tr.625ac.25prg.125 0.3756E-01 -1.425 32.11 1.507 0.5442 10.33 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 5899.582546 g Volume = 2387.785707 cm3 Porosity: -10.4945% V(tot) - V(min): -.22679E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 5399.9990000 g log = 3.7324 Original solution: 1000.0103000 g Original solution / Rock added: 0.19 (Water/Rock Ratio), log = -0.7324 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1094 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9489E+00 0.9848 0.1037E+01 0.1053E+01 CO2,gas 0.8110E-08 1.0068 0.9059E-08 0.8997E-08 CH4,gas 0.3764E-01 1.0126 0.4228E-01 0.4175E-01 H2,gas 0.1343E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.2814E-06 0.9957 0.3109E-06 0.3122E-06 S2,gas 0.1468E-28 1.0000 0.1629E-28 0.1629E-28 CO,gas 0.3153E-13 1.0000 0.3498E-13 0.3498E-13 SO3,gas 0.1722E-47 1.0000 0.1911E-47 0.1911E-47 SO2,gas 0.9714E-27 1.0000 0.1078E-26 0.1078E-26 HCl,gas 0.5719E-17 1.0000 0.6345E-17 0.6345E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.41 -10.04 -3.348 0.17148E+05 -8.043 3 CH4,gas 4.81 1.44 -3.37 -0.843 0.57608E+04 -1.374 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.45 -8.51 -4.254 0.14526E+05 -6.507 6 S2,gas -7.03 -37.82 -30.79 -4.737 0.52570E+05 -28.788 7 CO,gas 3.51 -11.95 -15.46 -4.756 0.26391E+05 -13.456 8 SO3,gas 17.43 -32.29 -49.72 -12.430 0.84893E+05 -47.719 9 SO2,gas 1.14 -27.83 -28.97 -7.725 0.49461E+05 -26.968 10 HCl,gas 5.48 -13.72 -19.20 -9.599 0.32779E+05 -17.198 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80610E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94128E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.30 -4.29 -1.429 0.73180E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.30 -4.13 -1.378 0.70566E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65552E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.49 -4.38 -1.251 0.74756E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.49 -3.94 -1.125 0.67217E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82263E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92776E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40701E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43450E+04 143 pyrrhotite -4.24 -7.71 -3.46 -1.155 0.59141E+04 144 pyrrhotiteFe0.875 -6.00 -9.10 -3.10 -1.141 0.52968E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22430E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28298E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23222E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47133E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91027E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.71 -3.31 -1.104 0.56573E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80436E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.20 -4.24 -1.413 0.72354E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 5399.9990000 g New total amount of reactant added: 5599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 5599.9990000 Water: Moles liquid = 0.2419E+02 kg liquid = 0.4358E+00 Moles total = -.1469E+02 kg total = -.2646E+00 Activity = 1.0000 Stoichiometric ionic strength = .1187717E-01 Osmotic coef. = 0.9679 True ionic strength = .2080018E-01 Chg. balance for total moles = -.1298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90758E-10 -10.0421 0.76116E-10 -10.1185 0.83867E+00 -0.0764 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.31513E-03 -3.5015 0.26266E-03 -3.5806 0.83350E+00 -0.0791 4 SO4-- 0.17920E-11 -11.7467 0.92321E-12 -12.0347 0.51520E+00 -0.2880 5 HCO3- 0.64625E-06 -6.1896 0.53946E-06 -6.2680 0.83475E+00 -0.0784 6 HS- 0.58513E-04 -4.2328 0.48778E-04 -4.3118 0.83363E+00 -0.0790 7 Al+++ 0.11208E-28 -28.9505 0.25426E-29 -29.5947 0.22686E+00 -0.6442 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14481E-06 -6.8392 0.74045E-07 -7.1305 0.51132E+00 -0.2913 10 Mg++ 0.22995E-10 -10.6384 0.11703E-10 -10.9317 0.50892E+00 -0.2933 11 Fe++ 0.62901E-13 -13.2013 0.32048E-13 -13.4942 0.50949E+00 -0.2929 12 K+ 0.16231E-03 -3.7896 0.13552E-03 -3.8680 0.83495E+00 -0.0783 13 Na+ 0.20636E-01 -1.6854 0.17197E-01 -1.7646 0.83334E+00 -0.0792 14 Mn++ 0.20211E-10 -10.6944 0.10306E-10 -10.9869 0.50992E+00 -0.2925 15 HPO4-- 0.48364E-07 -7.3155 0.24921E-07 -7.6034 0.51527E+00 -0.2880 16 HSiO3- 0.10944E-01 -1.9608 0.91222E-02 -2.0399 0.83350E+00 -0.0791 17 Ca(HSiO3)+ 0.18121E-07 -7.7418 0.15134E-07 -7.8201 0.83513E+00 -0.0782 18 Mg(HSiO3)+ 0.35643E-11 -11.4480 0.29767E-11 -11.5263 0.83513E+00 -0.0782 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67839E-16 -16.1685 0.56654E-16 -16.2468 0.83513E+00 -0.0782 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52518E-05 -5.2797 0.43693E-05 -5.3596 0.83197E+00 -0.0799 24 CH4,aq 0.28069E-04 -4.5518 0.27968E-04 -4.5533 0.99638E+00 -0.0016 25 C2H6,aq 0.12455E-13 -13.9047 0.12410E-13 -13.9062 0.99638E+00 -0.0016 29 CO,aq 0.23177E-16 -16.6349 0.23177E-16 -16.6349 0.10000E+01 0.0000 30 CO2,aq 0.83089E-10 -10.0805 0.82788E-10 -10.0820 0.99638E+00 -0.0016 31 CO3-2 0.12747E-05 -5.8946 0.65528E-06 -6.1836 0.51408E+00 -0.2890 32 CaCO3,aq 0.59426E-09 -9.2260 0.59426E-09 -9.2260 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.12052E-11 -11.9190 0.10065E-11 -11.9972 0.83513E+00 -0.0782 34 CaCl+ 0.37109E-10 -10.4305 0.30991E-10 -10.5088 0.83513E+00 -0.0782 35 CaCl2,aq 0.18953E-14 -14.7223 0.18953E-14 -14.7223 0.10000E+01 0.0000 36 CaOH+ 0.82135E-07 -7.0855 0.68594E-07 -7.1637 0.83513E+00 -0.0782 37 CaSO4,aq 0.21299E-16 -16.6716 0.21299E-16 -16.6716 0.10000E+01 0.0000 38 HCl,aq 0.37606E-14 -14.4247 0.37606E-14 -14.4247 0.10000E+01 0.0000 43 FeCl+ 0.15699E-16 -16.8041 0.13111E-16 -16.8824 0.83513E+00 -0.0782 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16714E-10 -10.7769 0.13958E-10 -10.8552 0.83513E+00 -0.0782 48 HFeO2- 0.37084E-07 -7.4308 0.30910E-07 -7.5099 0.83350E+00 -0.0791 49 FeO+ 0.12337E-16 -16.9088 0.10303E-16 -16.9870 0.83513E+00 -0.0782 51 FeO2- 0.41932E-09 -9.3775 0.34950E-09 -9.4565 0.83350E+00 -0.0791 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99638E+00 -0.0016 54 KCl,aq 0.63029E-09 -9.2005 0.63029E-09 -9.2005 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.23127E-14 -14.6359 0.19276E-14 -14.7150 0.83350E+00 -0.0791 58 MgCO3,aq 0.23469E-13 -13.6295 0.23469E-13 -13.6295 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.19423E-15 -15.7117 0.16221E-15 -15.7899 0.83513E+00 -0.0782 60 MgCl+ 0.53244E-14 -14.2737 0.44466E-14 -14.3520 0.83513E+00 -0.0782 61 MgOH+ 0.71917E-10 -10.1432 0.60060E-10 -10.2214 0.83513E+00 -0.0782 63 MnO,aq 0.18778E-08 -8.7263 0.18778E-08 -8.7263 0.10000E+01 0.0000 64 MnOH+ 0.49932E-09 -9.3016 0.41700E-09 -9.3799 0.83513E+00 -0.0782 65 MnO2-2 0.21804E-10 -10.6615 0.11209E-10 -10.9504 0.51408E+00 -0.2890 66 HMnO2- 0.22178E-09 -9.6541 0.18486E-09 -9.7332 0.83350E+00 -0.0791 69 MnCl+ 0.19618E-13 -13.7073 0.16384E-13 -13.7856 0.83513E+00 -0.0782 71 NaCl,aq 0.14749E-05 -5.8312 0.14749E-05 -5.8312 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94721E-02 -2.0236 0.78805E-02 -2.1034 0.83197E+00 -0.0799 79 HPO3-2 0.16643E-14 -14.7788 0.85560E-15 -15.0677 0.51408E+00 -0.2890 81 H2PO3- 0.15348E-18 -18.8139 0.12793E-18 -18.8930 0.83350E+00 -0.0791 82 H3PO4,aq 0.92953E-18 -18.0317 0.92953E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39860E-10 -10.3995 0.33256E-10 -10.4781 0.83431E+00 -0.0787 84 PO4-3 0.11985E-08 -8.9214 0.28592E-09 -9.5438 0.23857E+00 -0.6224 88 HP2O7-3 0.10268E-17 -17.9885 0.23318E-18 -18.6323 0.22710E+00 -0.6438 89 P2O7-4 0.10116E-16 -16.9950 0.75575E-18 -18.1216 0.74707E-01 -1.1266 90 H2S,aq 0.11196E-07 -7.9509 0.11155E-07 -7.9525 0.99638E+00 -0.0016 91 S2-2 0.93646E-14 -14.0285 0.48141E-14 -14.3175 0.51408E+00 -0.2890 97 SO3-2 0.26228E-17 -17.5812 0.13683E-17 -17.8638 0.52170E+00 -0.2826 99 HSO4- 0.77996E-19 -19.1079 0.65202E-19 -19.1857 0.83597E+00 -0.0778 Charge balance for all species = -.2971E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9075797E-10 -.2303327E-01 -.2317399E+02 0.0000 2 H2O 0.1000000E+01 0.5550444E+02 0.9981133E+06 0.0000 3 Cl- 0.3151270E-03 0.3166026E-03 0.1120413E+02 6.5379 4 SO4-- 0.1791963E-11 -.3079676E-04 -.2953014E+01 8.2023 5 HCO3- 0.6462486E-06 0.2999109E-04 0.1826649E+01 3.8505 6 HS- 0.5851266E-04 0.8932061E-04 0.2948647E+01 5.8067 7 Al+++ 0.1120778E-28 0.5251925E-05 0.1414475E+00 0.7608 8 H4SiO4 0.7116616E-03 0.1414756E-01 0.1357330E+04 -3.1477 9 Ca++ 0.1448120E-06 0.2457005E-06 0.9829304E-02 13.1065 10 Mg++ 0.2299497E-10 0.9850552E-10 0.2390517E-05 9.3053 11 Fe++ 0.6290115E-13 0.3774231E-07 0.2103967E-02 6.7428 12 K+ 0.1623141E-03 0.1630910E-03 0.6365603E+01 6.2505 13 Na+ 0.2063600E-01 0.2322827E-01 0.5330435E+03 8.3540 14 Mn++ 0.2021136E-10 0.2640989E-08 0.1448272E-03 9.2501 15 HPO4-- 0.4836393E-07 0.4960228E-07 0.4752132E-02 12.6336 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9272766E+02 -.1003781E-01 -.9271762E+02 0.0000000E+00 2 H2O -.1469003E+02 0.2418862E+02 -.3887865E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1552206E+00 -.1342111E-04 0.1552340E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1551951E+00 0.3892558E-04 -.1552340E+00 0.0000000E+00 7 Al+++ 0.1826015E+02 0.2288769E-05 0.1826015E+02 0.0000000E+00 8 H4SiO4 0.5831157E+02 0.6165454E-02 0.5830541E+02 0.0000000E+00 9 Ca++ 0.6440812E+01 0.1070753E-06 0.6440812E+01 0.0000000E+00 10 Mg++ 0.4444444E+01 0.4292833E-10 0.4444444E+01 0.0000000E+00 11 Fe++ 0.3992847E+01 0.1644795E-07 0.3992847E+01 0.0000000E+00 12 K+ 0.1188959E+01 0.7107442E-04 0.1188888E+01 0.0000000E+00 13 Na+ 0.7029523E+01 0.1012279E-01 0.7019400E+01 0.0000000E+00 14 Mn++ 0.9709612E-01 0.1150933E-08 0.9709612E-01 0.0000000E+00 15 HPO4-- 0.3313842E-01 0.2161649E-07 0.3313840E-01 0.0000000E+00 Chg. balance for solid moles: 0.1885E-13 Mass of aqueous solution: 0.436589E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 5599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 7.015 0.846 1839. 3.265 30.06 706.1 andradite 0.6209 -0.207 315.5 2.499 5.158 81.98 grossular 0.1483 -0.829 66.78 1.825 1.092 18.58 apatite-OH 0.1105E-01 -1.957 5.549 0.744 0.9069E-01 1.763 clinochlore 0.7978 -0.098 443.4 2.647 7.248 168.7 daphnite 0.2286 -0.641 163.1 2.213 2.667 49.44 chlorite-Mn 0.1942E-01 -1.712 13.77 1.139 0.2250 4.387 diopside 0.3144 -0.502 68.09 1.833 1.113 20.81 hedenbergite 0.8055E-01 -1.094 19.99 1.301 0.3267 5.474 microcline 1.041 0.017 289.8 2.462 4.736 113.2 stilbite 3.605 0.557 2541. 3.405 41.53 1185. stilpnomelane-Fe 0.2957 -0.529 318.8 2.503 5.210 110.1 tr.625ac.25prg.125 0.3893E-01 -1.410 33.27 1.522 0.5438 10.71 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6118.093509 g Volume = 2476.198421 cm3 Porosity: -10.4953% V(tot) - V(min): -.23520E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 5599.9990000 g log = 3.7482 Original solution: 1000.0103000 g Original solution / Rock added: 0.18 (Water/Rock Ratio), log = -0.7482 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1114 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9473E+00 0.9847 0.1037E+01 0.1053E+01 CO2,gas 0.8469E-08 1.0068 0.9477E-08 0.9412E-08 CH4,gas 0.3930E-01 1.0125 0.4423E-01 0.4368E-01 H2,gas 0.1341E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.2940E-06 0.9957 0.3254E-06 0.3268E-06 S2,gas 0.1605E-28 1.0000 0.1784E-28 0.1784E-28 CO,gas 0.3293E-13 1.0000 0.3660E-13 0.3660E-13 SO3,gas 0.1799E-47 1.0000 0.2000E-47 0.2000E-47 SO2,gas 0.1015E-26 1.0000 0.1128E-26 0.1128E-26 HCl,gas 0.5975E-17 1.0000 0.6640E-17 0.6640E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.48529E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.39 -10.02 -3.341 0.17115E+05 -8.023 3 CH4,gas 4.81 1.45 -3.35 -0.839 0.57274E+04 -1.354 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.43 -8.49 -4.244 0.14492E+05 -6.488 6 S2,gas -7.03 -37.78 -30.75 -4.731 0.52503E+05 -28.749 7 CO,gas 3.51 -11.93 -15.44 -4.750 0.26357E+05 -13.437 8 SO3,gas 17.43 -32.27 -49.70 -12.425 0.84860E+05 -47.699 9 SO2,gas 1.14 -27.81 -28.95 -7.719 0.49428E+05 -26.948 10 HCl,gas 5.48 -13.70 -19.18 -9.589 0.32746E+05 -17.178 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80609E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94128E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.28 -4.27 -1.422 0.72845E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.28 -4.11 -1.371 0.70232E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65552E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.47 -4.36 -1.245 0.74421E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57724E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.47 -3.92 -1.119 0.66883E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82263E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92776E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40701E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43450E+04 143 pyrrhotite -4.24 -7.69 -3.44 -1.148 0.58804E+04 144 pyrrhotiteFe0.875 -6.00 -9.08 -3.08 -1.134 0.52631E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22430E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28298E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23222E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47132E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91027E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.69 -3.29 -1.098 0.56235E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80437E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52962E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.18 -4.22 -1.406 0.72017E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 5599.9990000 g New total amount of reactant added: 5799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1299E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 5799.9990000 Water: Moles liquid = 0.2307E+02 kg liquid = 0.4157E+00 Moles total = -.1720E+02 kg total = -.3098E+00 Activity = 1.0000 Stoichiometric ionic strength = .1188988E-01 Osmotic coef. = 0.9679 True ionic strength = .2081010E-01 Chg. balance for total moles = -.1299E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90801E-10 -10.0419 0.76150E-10 -10.1183 0.83865E+00 -0.0764 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.33036E-03 -3.4810 0.27535E-03 -3.5601 0.83348E+00 -0.0791 4 SO4-- 0.18779E-11 -11.7263 0.96738E-12 -12.0144 0.51513E+00 -0.2881 5 HCO3- 0.67724E-06 -6.1693 0.56531E-06 -6.2477 0.83472E+00 -0.0785 6 HS- 0.61341E-04 -4.2122 0.51134E-04 -4.2913 0.83360E+00 -0.0790 7 Al+++ 0.11226E-28 -28.9498 0.25460E-29 -29.5941 0.22679E+00 -0.6444 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14496E-06 -6.8388 0.74110E-07 -7.1301 0.51125E+00 -0.2914 10 Mg++ 0.23018E-10 -10.6379 0.11713E-10 -10.9313 0.50885E+00 -0.2934 11 Fe++ 0.62965E-13 -13.2009 0.32076E-13 -13.4938 0.50943E+00 -0.2929 12 K+ 0.16239E-03 -3.7894 0.13558E-03 -3.8678 0.83492E+00 -0.0784 13 Na+ 0.20646E-01 -1.6852 0.17204E-01 -1.7644 0.83332E+00 -0.0792 14 Mn++ 0.20233E-10 -10.6939 0.10316E-10 -10.9865 0.50986E+00 -0.2926 15 HPO4-- 0.48327E-07 -7.3158 0.24899E-07 -7.6038 0.51521E+00 -0.2880 16 HSiO3- 0.10940E-01 -1.9610 0.91181E-02 -2.0401 0.83348E+00 -0.0791 17 Ca(HSiO3)+ 0.18130E-07 -7.7416 0.15140E-07 -7.8199 0.83511E+00 -0.0783 18 Mg(HSiO3)+ 0.35660E-11 -11.4478 0.29780E-11 -11.5261 0.83511E+00 -0.0783 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67871E-16 -16.1683 0.56679E-16 -16.2466 0.83511E+00 -0.0783 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52496E-05 -5.2799 0.43674E-05 -5.3598 0.83194E+00 -0.0799 24 CH4,aq 0.29427E-04 -4.5312 0.29321E-04 -4.5328 0.99638E+00 -0.0016 25 C2H6,aq 0.13689E-13 -13.8636 0.13640E-13 -13.8652 0.99638E+00 -0.0016 29 CO,aq 0.24298E-16 -16.6144 0.24298E-16 -16.6144 0.10000E+01 0.0000 30 CO2,aq 0.87109E-10 -10.0599 0.86793E-10 -10.0615 0.99638E+00 -0.0016 31 CO3-2 0.13353E-05 -5.8744 0.68638E-06 -6.1634 0.51401E+00 -0.2890 32 CaCO3,aq 0.62301E-09 -9.2055 0.62301E-09 -9.2055 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.12641E-11 -11.8982 0.10556E-11 -11.9765 0.83511E+00 -0.0783 34 CaCl+ 0.38937E-10 -10.4096 0.32517E-10 -10.4879 0.83511E+00 -0.0783 35 CaCl2,aq 0.20847E-14 -14.6810 0.20847E-14 -14.6810 0.10000E+01 0.0000 36 CaOH+ 0.82174E-07 -7.0853 0.68624E-07 -7.1635 0.83511E+00 -0.0783 37 CaSO4,aq 0.22338E-16 -16.6510 0.22338E-16 -16.6510 0.10000E+01 0.0000 38 HCl,aq 0.39439E-14 -14.4041 0.39439E-14 -14.4041 0.10000E+01 0.0000 43 FeCl+ 0.16472E-16 -16.7833 0.13756E-16 -16.8615 0.83511E+00 -0.0783 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16722E-10 -10.7767 0.13964E-10 -10.8550 0.83511E+00 -0.0783 48 HFeO2- 0.37069E-07 -7.4310 0.30896E-07 -7.5101 0.83348E+00 -0.0791 49 FeO+ 0.12342E-16 -16.9086 0.10307E-16 -16.9869 0.83511E+00 -0.0783 51 FeO2- 0.41915E-09 -9.3776 0.34935E-09 -9.4567 0.83348E+00 -0.0791 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99638E+00 -0.0016 54 KCl,aq 0.66103E-09 -9.1798 0.66103E-09 -9.1798 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.24245E-14 -14.6154 0.20207E-14 -14.6945 0.83348E+00 -0.0791 58 MgCO3,aq 0.24604E-13 -13.6090 0.24604E-13 -13.6090 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.20372E-15 -15.6910 0.17013E-15 -15.7692 0.83511E+00 -0.0783 60 MgCl+ 0.55867E-14 -14.2528 0.46655E-14 -14.3311 0.83511E+00 -0.0783 61 MgOH+ 0.71951E-10 -10.1430 0.60087E-10 -10.2212 0.83511E+00 -0.0783 63 MnO,aq 0.18780E-08 -8.7263 0.18780E-08 -8.7263 0.10000E+01 0.0000 64 MnOH+ 0.49959E-09 -9.3014 0.41721E-09 -9.3796 0.83511E+00 -0.0783 65 MnO2-2 0.21789E-10 -10.6618 0.11200E-10 -10.9508 0.51401E+00 -0.2890 66 HMnO2- 0.22170E-09 -9.6542 0.18479E-09 -9.7333 0.83348E+00 -0.0791 69 MnCl+ 0.20586E-13 -13.6864 0.17191E-13 -13.7647 0.83511E+00 -0.0783 71 NaCl,aq 0.15468E-05 -5.8106 0.15468E-05 -5.8106 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94682E-02 -2.0237 0.78770E-02 -2.1036 0.83194E+00 -0.0799 79 HPO3-2 0.16631E-14 -14.7791 0.85484E-15 -15.0681 0.51401E+00 -0.2890 81 H2PO3- 0.15342E-18 -18.8141 0.12787E-18 -18.8932 0.83348E+00 -0.0791 82 H3PO4,aq 0.92953E-18 -18.0317 0.92953E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39844E-10 -10.3996 0.33241E-10 -10.4783 0.83428E+00 -0.0787 84 PO4-3 0.11972E-08 -8.9218 0.28554E-09 -9.5443 0.23850E+00 -0.6225 88 HP2O7-3 0.10257E-17 -17.9890 0.23287E-18 -18.6329 0.22704E+00 -0.6439 89 P2O7-4 0.10103E-16 -16.9955 0.75442E-18 -18.1224 0.74670E-01 -1.1269 90 H2S,aq 0.11742E-07 -7.9303 0.11699E-07 -7.9318 0.99638E+00 -0.0016 91 S2-2 0.10292E-13 -13.9875 0.52904E-14 -14.2765 0.51401E+00 -0.2890 97 SO3-2 0.27486E-17 -17.5609 0.14338E-17 -17.8435 0.52164E+00 -0.2826 99 HSO4- 0.81766E-19 -19.0874 0.68352E-19 -19.1652 0.83594E+00 -0.0778 Charge balance for all species = -.3122E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9080080E-10 -.2302498E-01 -.2316564E+02 0.0000 2 H2O 0.1000000E+01 0.5550444E+02 0.9981128E+06 0.0000 3 Cl- 0.3303584E-03 0.3319059E-03 0.1174568E+02 6.5582 4 SO4-- 0.1877937E-11 -.3215473E-04 -.3083225E+01 8.2223 5 HCO3- 0.6772372E-06 0.3144074E-04 0.1914941E+01 3.8706 6 HS- 0.6134092E-04 0.9350740E-04 0.3086859E+01 5.8270 7 Al+++ 0.1122585E-28 0.5249768E-05 0.1413893E+00 0.7608 8 H4SiO4 0.7116620E-03 0.1414309E-01 0.1356900E+04 -3.1477 9 Ca++ 0.1449585E-06 0.2459251E-06 0.9838284E-02 13.1065 10 Mg++ 0.2301828E-10 0.9856643E-10 0.2391994E-05 9.3053 11 Fe++ 0.6296492E-13 0.3772695E-07 0.2103110E-02 6.7428 12 K+ 0.1623910E-03 0.1631679E-03 0.6368601E+01 6.2505 13 Na+ 0.2064579E-01 0.2323813E-01 0.5332695E+03 8.3540 14 Mn++ 0.2023301E-10 0.2641291E-08 0.1448437E-03 9.2502 15 HPO4-- 0.4832733E-07 0.4956441E-07 0.4748502E-02 12.6328 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9603936E+02 -.9571546E-02 -.9602979E+02 0.0000000E+00 2 H2O -.1719712E+02 0.2307335E+02 -.4027046E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1607632E+00 -.1336681E-04 0.1607766E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1607377E+00 0.3887128E-04 -.1607766E+00 0.0000000E+00 7 Al+++ 0.1891230E+02 0.2182343E-05 0.1891230E+02 0.0000000E+00 8 H4SiO4 0.6039413E+02 0.5879322E-02 0.6038825E+02 0.0000000E+00 9 Ca++ 0.6670841E+01 0.1022317E-06 0.6670841E+01 0.0000000E+00 10 Mg++ 0.4603174E+01 0.4097434E-10 0.4603174E+01 0.0000000E+00 11 Fe++ 0.4135449E+01 0.1568320E-07 0.4135449E+01 0.0000000E+00 12 K+ 0.1231422E+01 0.6782933E-04 0.1231354E+01 0.0000000E+00 13 Na+ 0.7280572E+01 0.9660154E-02 0.7270912E+01 0.0000000E+00 14 Mn++ 0.1005638E+00 0.1097992E-08 0.1005638E+00 0.0000000E+00 15 HPO4-- 0.3432194E-01 0.2060406E-07 0.3432192E-01 0.0000000E+00 Chg. balance for solid moles: -.9256E-14 Mass of aqueous solution: 0.416459E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 5799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 7.266 0.861 1905. 3.280 30.07 731.4 andradite 0.6431 -0.192 326.8 2.514 5.158 84.91 grossular 0.1535 -0.814 69.16 1.840 1.091 19.24 apatite-OH 0.1144E-01 -1.942 5.747 0.759 0.9069E-01 1.826 clinochlore 0.8262 -0.083 459.2 2.662 7.247 174.7 daphnite 0.2368 -0.626 169.0 2.228 2.666 51.20 chlorite-Mn 0.2011E-01 -1.697 14.26 1.154 0.2250 4.544 diopside 0.3260 -0.487 70.60 1.849 1.114 21.58 hedenbergite 0.8352E-01 -1.078 20.72 1.316 0.3270 5.675 microcline 1.078 0.033 300.1 2.477 4.736 117.2 stilbite 3.734 0.572 2631. 3.420 41.52 1227. stilpnomelane-Fe 0.3063 -0.514 330.2 2.519 5.210 114.0 tr.625ac.25prg.125 0.4029E-01 -1.395 34.44 1.537 0.5435 11.08 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6336.604472 g Volume = 2564.611134 cm3 Porosity: -10.4960% V(tot) - V(min): -.24361E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 5799.9990000 g log = 3.7634 Original solution: 1000.0103000 g Original solution / Rock added: 0.17 (Water/Rock Ratio), log = -0.7634 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1135 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9455E+00 0.9847 0.1037E+01 0.1053E+01 CO2,gas 0.8862E-08 1.0068 0.9935E-08 0.9868E-08 CH4,gas 0.4113E-01 1.0125 0.4637E-01 0.4579E-01 H2,gas 0.1338E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.3078E-06 0.9957 0.3412E-06 0.3427E-06 S2,gas 0.1762E-28 1.0000 0.1962E-28 0.1962E-28 CO,gas 0.3446E-13 1.0000 0.3837E-13 0.3837E-13 SO3,gas 0.1883E-47 1.0000 0.2097E-47 0.2097E-47 SO2,gas 0.1062E-26 1.0000 0.1183E-26 0.1183E-26 HCl,gas 0.6254E-17 1.0000 0.6964E-17 0.6964E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.37 -10.00 -3.334 0.17080E+05 -8.003 3 CH4,gas 4.81 1.48 -3.33 -0.833 0.56924E+04 -1.334 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.41 -8.47 -4.233 0.14457E+05 -6.467 6 S2,gas -7.03 -37.74 -30.71 -4.724 0.52432E+05 -28.707 7 CO,gas 3.51 -11.91 -15.42 -4.743 0.26322E+05 -13.416 8 SO3,gas 17.43 -32.25 -49.68 -12.420 0.84824E+05 -47.678 9 SO2,gas 1.14 -27.79 -28.93 -7.714 0.49392E+05 -26.927 10 HCl,gas 5.48 -13.68 -19.16 -9.579 0.32710E+05 -17.157 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80608E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94128E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41194E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.26 -4.25 -1.415 0.72495E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.26 -4.09 -1.364 0.69881E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65551E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.45 -4.34 -1.239 0.74071E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.45 -3.90 -1.113 0.66532E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82262E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40701E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43450E+04 143 pyrrhotite -4.24 -7.67 -3.42 -1.141 0.58451E+04 144 pyrrhotiteFe0.875 -6.00 -9.06 -3.06 -1.126 0.52278E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22429E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23221E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47131E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91027E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76029E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.67 -3.27 -1.091 0.55882E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80437E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.16 -4.20 -1.399 0.71664E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 5799.9990000 g New total amount of reactant added: 5999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1299E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 5999.9990000 Water: Moles liquid = 0.2196E+02 kg liquid = 0.3956E+00 Moles total = -.1970E+02 kg total = -.3550E+00 Activity = 1.0000 Stoichiometric ionic strength = .1190389E-01 Osmotic coef. = 0.9678 True ionic strength = .2082104E-01 Chg. balance for total moles = -.1299E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90848E-10 -10.0417 0.76187E-10 -10.1181 0.83862E+00 -0.0764 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.34714E-03 -3.4595 0.28932E-03 -3.5386 0.83345E+00 -0.0791 4 SO4-- 0.19726E-11 -11.7050 0.10160E-11 -11.9931 0.51506E+00 -0.2881 5 HCO3- 0.71135E-06 -6.1479 0.59376E-06 -6.2264 0.83469E+00 -0.0785 6 HS- 0.64456E-04 -4.1907 0.53729E-04 -4.2698 0.83357E+00 -0.0791 7 Al+++ 0.11246E-28 -28.9490 0.25497E-29 -29.5935 0.22672E+00 -0.6445 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14512E-06 -6.8383 0.74182E-07 -7.1297 0.51118E+00 -0.2914 10 Mg++ 0.23044E-10 -10.6374 0.11724E-10 -10.9309 0.50878E+00 -0.2935 11 Fe++ 0.63035E-13 -13.2004 0.32107E-13 -13.4934 0.50935E+00 -0.2930 12 K+ 0.16248E-03 -3.7892 0.13565E-03 -3.8676 0.83489E+00 -0.0784 13 Na+ 0.20657E-01 -1.6849 0.17213E-01 -1.7641 0.83329E+00 -0.0792 14 Mn++ 0.20257E-10 -10.6934 0.10327E-10 -10.9860 0.50979E+00 -0.2926 15 HPO4-- 0.48287E-07 -7.3162 0.24874E-07 -7.6042 0.51514E+00 -0.2881 16 HSiO3- 0.10935E-01 -1.9612 0.91137E-02 -2.0403 0.83345E+00 -0.0791 17 Ca(HSiO3)+ 0.18139E-07 -7.7414 0.15148E-07 -7.8197 0.83508E+00 -0.0783 18 Mg(HSiO3)+ 0.35678E-11 -11.4476 0.29794E-11 -11.5259 0.83508E+00 -0.0783 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67906E-16 -16.1681 0.56707E-16 -16.2464 0.83508E+00 -0.0783 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52472E-05 -5.2801 0.43652E-05 -5.3600 0.83191E+00 -0.0799 24 CH4,aq 0.30923E-04 -4.5097 0.30811E-04 -4.5113 0.99637E+00 -0.0016 25 C2H6,aq 0.15117E-13 -13.8205 0.15062E-13 -13.8221 0.99637E+00 -0.0016 29 CO,aq 0.25534E-16 -16.5929 0.25534E-16 -16.5929 0.10000E+01 0.0000 30 CO2,aq 0.91538E-10 -10.0384 0.91206E-10 -10.0400 0.99637E+00 -0.0016 31 CO3-2 0.14021E-05 -5.8532 0.72058E-06 -6.1423 0.51394E+00 -0.2891 32 CaCO3,aq 0.65468E-09 -9.1840 0.65468E-09 -9.1840 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.13290E-11 -11.8765 0.11098E-11 -11.9547 0.83508E+00 -0.0783 34 CaCl+ 0.40954E-10 -10.3877 0.34200E-10 -10.4660 0.83508E+00 -0.0783 35 CaCl2,aq 0.23039E-14 -14.6375 0.23039E-14 -14.6375 0.10000E+01 0.0000 36 CaOH+ 0.82216E-07 -7.0850 0.68657E-07 -7.1633 0.83508E+00 -0.0783 37 CaSO4,aq 0.23483E-16 -16.6292 0.23483E-16 -16.6292 0.10000E+01 0.0000 38 HCl,aq 0.41461E-14 -14.3824 0.41461E-14 -14.3824 0.10000E+01 0.0000 43 FeCl+ 0.17325E-16 -16.7613 0.14468E-16 -16.8396 0.83508E+00 -0.0783 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16730E-10 -10.7765 0.13971E-10 -10.8548 0.83508E+00 -0.0783 48 HFeO2- 0.37052E-07 -7.4312 0.30881E-07 -7.5103 0.83345E+00 -0.0791 49 FeO+ 0.12349E-16 -16.9084 0.10312E-16 -16.9866 0.83508E+00 -0.0783 51 FeO2- 0.41896E-09 -9.3778 0.34918E-09 -9.4570 0.83345E+00 -0.0791 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99637E+00 -0.0016 54 KCl,aq 0.69491E-09 -9.1581 0.69491E-09 -9.1581 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.25476E-14 -14.5939 0.21233E-14 -14.6730 0.83345E+00 -0.0791 58 MgCO3,aq 0.25855E-13 -13.5875 0.25855E-13 -13.5875 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.21419E-15 -15.6692 0.17887E-15 -15.7475 0.83508E+00 -0.0783 60 MgCl+ 0.58761E-14 -14.2309 0.49070E-14 -14.3092 0.83508E+00 -0.0783 61 MgOH+ 0.71988E-10 -10.1427 0.60116E-10 -10.2210 0.83508E+00 -0.0783 63 MnO,aq 0.18781E-08 -8.7263 0.18781E-08 -8.7263 0.10000E+01 0.0000 64 MnOH+ 0.49988E-09 -9.3011 0.41744E-09 -9.3794 0.83508E+00 -0.0783 65 MnO2-2 0.21772E-10 -10.6621 0.11190E-10 -10.9512 0.51394E+00 -0.2891 66 HMnO2- 0.22162E-09 -9.6544 0.18470E-09 -9.7335 0.83345E+00 -0.0791 69 MnCl+ 0.21653E-13 -13.6645 0.18082E-13 -13.7427 0.83508E+00 -0.0783 71 NaCl,aq 0.16261E-05 -5.7889 0.16261E-05 -5.7889 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94640E-02 -2.0239 0.78732E-02 -2.1038 0.83191E+00 -0.0799 79 HPO3-2 0.16617E-14 -14.7794 0.85401E-15 -15.0685 0.51394E+00 -0.2891 81 H2PO3- 0.15335E-18 -18.8143 0.12781E-18 -18.8934 0.83345E+00 -0.0791 82 H3PO4,aq 0.92953E-18 -18.0317 0.92953E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39826E-10 -10.3998 0.33225E-10 -10.4785 0.83425E+00 -0.0787 84 PO4-3 0.11958E-08 -8.9223 0.28513E-09 -9.5450 0.23843E+00 -0.6226 88 HP2O7-3 0.10245E-17 -17.9895 0.23253E-18 -18.6335 0.22696E+00 -0.6440 89 P2O7-4 0.10089E-16 -16.9961 0.75296E-18 -18.1232 0.74629E-01 -1.1271 90 H2S,aq 0.12344E-07 -7.9086 0.12299E-07 -7.9101 0.99637E+00 -0.0016 91 S2-2 0.11365E-13 -13.9444 0.58411E-14 -14.2335 0.51394E+00 -0.2891 97 SO3-2 0.28871E-17 -17.5395 0.15058E-17 -17.8222 0.52157E+00 -0.2827 99 HSO4- 0.85920E-19 -19.0659 0.71822E-19 -19.1437 0.83591E+00 -0.0778 Charge balance for all species = -.3286E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9084800E-10 -.2301584E-01 -.2315644E+02 0.0000 2 H2O 0.1000000E+01 0.5550444E+02 0.9981123E+06 0.0000 3 Cl- 0.3471369E-03 0.3487637E-03 0.1234225E+02 6.5795 4 SO4-- 0.1972573E-11 -.3365079E-04 -.3226675E+01 8.2431 5 HCO3- 0.7113467E-06 0.3303764E-04 0.2012202E+01 3.8917 6 HS- 0.6445648E-04 0.9811961E-04 0.3239116E+01 5.8483 7 Al+++ 0.1124580E-28 0.5247394E-05 0.1413253E+00 0.7608 8 H4SiO4 0.7116625E-03 0.1413817E-01 0.1356427E+04 -3.1477 9 Ca++ 0.1451201E-06 0.2461727E-06 0.9848185E-02 13.1065 10 Mg++ 0.2304398E-10 0.9863353E-10 0.2393621E-05 9.3053 11 Fe++ 0.6303524E-13 0.3771004E-07 0.2102166E-02 6.7428 12 K+ 0.1624757E-03 0.1632526E-03 0.6371904E+01 6.2505 13 Na+ 0.2065657E-01 0.2324899E-01 0.5335186E+03 8.3540 14 Mn++ 0.2025668E-10 0.2641599E-08 0.1448605E-03 9.2502 15 HPO4-- 0.4828705E-07 0.4952272E-07 0.4744505E-02 12.6320 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.9935106E+02 -.9105283E-02 -.9934196E+02 0.0000000E+00 2 H2O -.1970420E+02 0.2195807E+02 -.4166227E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1663059E+00 -.1331256E-04 0.1663192E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1662804E+00 0.3881703E-04 -.1663192E+00 0.0000000E+00 7 Al+++ 0.1956445E+02 0.2075918E-05 0.1956444E+02 0.0000000E+00 8 H4SiO4 0.6247669E+02 0.5593191E-02 0.6247109E+02 0.0000000E+00 9 Ca++ 0.6900869E+01 0.9738823E-07 0.6900869E+01 0.0000000E+00 10 Mg++ 0.4761904E+01 0.3902034E-10 0.4761904E+01 0.0000000E+00 11 Fe++ 0.4278051E+01 0.1491845E-07 0.4278051E+01 0.0000000E+00 12 K+ 0.1273885E+01 0.6458425E-04 0.1273821E+01 0.0000000E+00 13 Na+ 0.7531621E+01 0.9197519E-02 0.7522423E+01 0.0000000E+00 14 Mn++ 0.1040316E+00 0.1045041E-08 0.1040316E+00 0.0000000E+00 15 HPO4-- 0.3550545E-01 0.1959165E-07 0.3550543E-01 0.0000000E+00 Chg. balance for solid moles: -.2012E-13 Mass of aqueous solution: 0.396329E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 5999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 7.517 0.876 1971. 3.295 30.07 756.7 andradite 0.6653 -0.177 338.1 2.529 5.158 87.84 grossular 0.1588 -0.799 71.55 1.855 1.091 19.91 apatite-OH 0.1184E-01 -1.927 5.945 0.774 0.9069E-01 1.889 clinochlore 0.8547 -0.068 475.1 2.677 7.247 180.7 daphnite 0.2450 -0.611 174.8 2.242 2.666 52.96 chlorite-Mn 0.2081E-01 -1.682 14.75 1.169 0.2250 4.701 diopside 0.3376 -0.472 73.10 1.864 1.115 22.34 hedenbergite 0.8648E-01 -1.063 21.46 1.332 0.3273 5.877 microcline 1.115 0.047 310.5 2.492 4.736 121.3 stilbite 3.862 0.587 2722. 3.435 41.52 1269. stilpnomelane-Fe 0.3168 -0.499 341.5 2.533 5.210 118.0 tr.625ac.25prg.125 0.4165E-01 -1.380 35.60 1.551 0.5431 11.46 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6555.115436 g Volume = 2653.023848 cm3 Porosity: -10.4966% V(tot) - V(min): -.25202E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 5999.9990000 g log = 3.7782 Original solution: 1000.0103000 g Original solution / Rock added: 0.17 (Water/Rock Ratio), log = -0.7781 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1159 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9435E+00 0.9847 0.1037E+01 0.1053E+01 CO2,gas 0.9293E-08 1.0067 0.1044E-07 0.1037E-07 CH4,gas 0.4313E-01 1.0125 0.4872E-01 0.4812E-01 H2,gas 0.1335E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.3229E-06 0.9957 0.3587E-06 0.3603E-06 S2,gas 0.1943E-28 1.0000 0.2168E-28 0.2168E-28 CO,gas 0.3613E-13 1.0000 0.4032E-13 0.4032E-13 SO3,gas 0.1976E-47 1.0000 0.2205E-47 0.2205E-47 SO2,gas 0.1114E-26 1.0000 0.1243E-26 0.1243E-26 HCl,gas 0.6561E-17 1.0000 0.7321E-17 0.7321E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.36397E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.48529E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.34 -9.98 -3.327 0.17043E+05 -7.981 3 CH4,gas 4.81 1.50 -3.31 -0.828 0.56556E+04 -1.312 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.39 -8.45 -4.223 0.14420E+05 -6.445 6 S2,gas -7.03 -37.70 -30.66 -4.718 0.52358E+05 -28.664 7 CO,gas 3.51 -11.88 -15.39 -4.737 0.26286E+05 -13.395 8 SO3,gas 17.43 -32.23 -49.66 -12.414 0.84787E+05 -47.657 9 SO2,gas 1.14 -27.77 -28.91 -7.708 0.49355E+05 -26.905 10 HCl,gas 5.48 -13.66 -19.14 -9.568 0.32673E+05 -17.135 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80606E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94128E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.24 -4.22 -1.408 0.72127E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.24 -4.07 -1.357 0.69514E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65551E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.42 -4.32 -1.233 0.73703E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.42 -3.88 -1.107 0.66165E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82262E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40701E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43450E+04 143 pyrrhotite -4.24 -7.65 -3.40 -1.134 0.58080E+04 144 pyrrhotiteFe0.875 -6.00 -9.04 -3.04 -1.118 0.51907E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22429E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23221E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47130E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91027E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.65 -3.25 -1.084 0.55512E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80437E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.14 -4.18 -1.392 0.71292E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18338E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 5999.9990000 g New total amount of reactant added: 6199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 6199.9990000 Water: Moles liquid = 0.2084E+02 kg liquid = 0.3755E+00 Moles total = -.2221E+02 kg total = -.4001E+00 Activity = 1.0000 Stoichiometric ionic strength = .1191939E-01 Osmotic coef. = 0.9678 True ionic strength = .2083315E-01 Chg. balance for total moles = -.1298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90900E-10 -10.0414 0.76228E-10 -10.1179 0.83859E+00 -0.0764 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.36571E-03 -3.4369 0.30479E-03 -3.5160 0.83341E+00 -0.0791 4 SO4-- 0.20773E-11 -11.6825 0.10697E-11 -11.9707 0.51498E+00 -0.2882 5 HCO3- 0.74907E-06 -6.1255 0.62522E-06 -6.2040 0.83466E+00 -0.0785 6 HS- 0.67905E-04 -4.1681 0.56602E-04 -4.2472 0.83354E+00 -0.0791 7 Al+++ 0.11268E-28 -28.9482 0.25538E-29 -29.5928 0.22664E+00 -0.6447 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14530E-06 -6.8377 0.74262E-07 -7.1292 0.51110E+00 -0.2915 10 Mg++ 0.23072E-10 -10.6369 0.11737E-10 -10.9304 0.50870E+00 -0.2935 11 Fe++ 0.63113E-13 -13.1999 0.32142E-13 -13.4929 0.50927E+00 -0.2931 12 K+ 0.16257E-03 -3.7890 0.13572E-03 -3.8673 0.83486E+00 -0.0784 13 Na+ 0.20669E-01 -1.6847 0.17222E-01 -1.7639 0.83325E+00 -0.0792 14 Mn++ 0.20283E-10 -10.6929 0.10338E-10 -10.9856 0.50970E+00 -0.2927 15 HPO4-- 0.48242E-07 -7.3166 0.24848E-07 -7.6047 0.51506E+00 -0.2881 16 HSiO3- 0.10930E-01 -1.9614 0.91088E-02 -2.0405 0.83341E+00 -0.0791 17 Ca(HSiO3)+ 0.18150E-07 -7.7411 0.15156E-07 -7.8194 0.83505E+00 -0.0783 18 Mg(HSiO3)+ 0.35699E-11 -11.4473 0.29810E-11 -11.5256 0.83505E+00 -0.0783 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67945E-16 -16.1678 0.56737E-16 -16.2461 0.83505E+00 -0.0783 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52446E-05 -5.2803 0.43629E-05 -5.3602 0.83188E+00 -0.0799 24 CH4,aq 0.32580E-04 -4.4871 0.32461E-04 -4.4886 0.99637E+00 -0.0016 25 C2H6,aq 0.16779E-13 -13.7752 0.16718E-13 -13.7768 0.99637E+00 -0.0016 29 CO,aq 0.26901E-16 -16.5702 0.26901E-16 -16.5702 0.10000E+01 0.0000 30 CO2,aq 0.96442E-10 -10.0157 0.96091E-10 -10.0173 0.99637E+00 -0.0016 31 CO3-2 0.14758E-05 -5.8310 0.75835E-06 -6.1201 0.51386E+00 -0.2892 32 CaCO3,aq 0.68975E-09 -9.1613 0.68975E-09 -9.1613 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.14010E-11 -11.8536 0.11699E-11 -11.9318 0.83505E+00 -0.0783 34 CaCl+ 0.43192E-10 -10.3646 0.36067E-10 -10.4429 0.83505E+00 -0.0783 35 CaCl2,aq 0.25596E-14 -14.5918 0.25596E-14 -14.5918 0.10000E+01 0.0000 36 CaOH+ 0.82264E-07 -7.0848 0.68694E-07 -7.1631 0.83505E+00 -0.0783 37 CaSO4,aq 0.24752E-16 -16.6064 0.24752E-16 -16.6064 0.10000E+01 0.0000 38 HCl,aq 0.43701E-14 -14.3595 0.43701E-14 -14.3595 0.10000E+01 0.0000 43 FeCl+ 0.18272E-16 -16.7382 0.15258E-16 -16.8165 0.83505E+00 -0.0783 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16740E-10 -10.7762 0.13979E-10 -10.8545 0.83505E+00 -0.0783 48 HFeO2- 0.37034E-07 -7.4314 0.30864E-07 -7.5105 0.83341E+00 -0.0791 49 FeO+ 0.12356E-16 -16.9081 0.10318E-16 -16.9864 0.83505E+00 -0.0783 51 FeO2- 0.41875E-09 -9.3780 0.34899E-09 -9.4572 0.83341E+00 -0.0791 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99637E+00 -0.0016 54 KCl,aq 0.73246E-09 -9.1352 0.73246E-09 -9.1352 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.26840E-14 -14.5712 0.22368E-14 -14.6504 0.83341E+00 -0.0791 58 MgCO3,aq 0.27240E-13 -13.5648 0.27240E-13 -13.5648 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.22580E-15 -15.6463 0.18855E-15 -15.7246 0.83505E+00 -0.0783 60 MgCl+ 0.61972E-14 -14.2078 0.51749E-14 -14.2861 0.83505E+00 -0.0783 61 MgOH+ 0.72030E-10 -10.1425 0.60148E-10 -10.2208 0.83505E+00 -0.0783 63 MnO,aq 0.18782E-08 -8.7263 0.18782E-08 -8.7263 0.10000E+01 0.0000 64 MnOH+ 0.50019E-09 -9.3009 0.41768E-09 -9.3792 0.83505E+00 -0.0783 65 MnO2-2 0.21753E-10 -10.6625 0.11178E-10 -10.9516 0.51386E+00 -0.2892 66 HMnO2- 0.22152E-09 -9.6546 0.18461E-09 -9.7337 0.83341E+00 -0.0791 69 MnCl+ 0.22838E-13 -13.6414 0.19070E-13 -13.7196 0.83505E+00 -0.0783 71 NaCl,aq 0.17140E-05 -5.7660 0.17140E-05 -5.7660 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94593E-02 -2.0241 0.78689E-02 -2.1041 0.83188E+00 -0.0799 79 HPO3-2 0.16602E-14 -14.7799 0.85309E-15 -15.0690 0.51386E+00 -0.2892 81 H2PO3- 0.15327E-18 -18.8145 0.12774E-18 -18.8937 0.83341E+00 -0.0791 82 H3PO4,aq 0.92953E-18 -18.0317 0.92953E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39806E-10 -10.4000 0.33207E-10 -10.4788 0.83422E+00 -0.0787 84 PO4-3 0.11943E-08 -8.9229 0.28467E-09 -9.5457 0.23835E+00 -0.6228 88 HP2O7-3 0.10232E-17 -17.9900 0.23216E-18 -18.6342 0.22688E+00 -0.6442 89 P2O7-4 0.10074E-16 -16.9968 0.75134E-18 -18.1242 0.74583E-01 -1.1274 90 H2S,aq 0.13011E-07 -7.8857 0.12964E-07 -7.8873 0.99637E+00 -0.0016 91 S2-2 0.12615E-13 -13.8991 0.64824E-14 -14.1883 0.51386E+00 -0.2892 97 SO3-2 0.30403E-17 -17.5171 0.15855E-17 -17.7998 0.52149E+00 -0.2828 99 HSO4- 0.90518E-19 -19.0433 0.75662E-19 -19.1211 0.83588E+00 -0.0779 Charge balance for all species = -.3458E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9090027E-10 -.2300574E-01 -.2314626E+02 0.0000 2 H2O 0.1000000E+01 0.5550444E+02 0.9981118E+06 0.0000 3 Cl- 0.3657109E-03 0.3674257E-03 0.1300267E+02 6.6019 4 SO4-- 0.2077252E-11 -.3530710E-04 -.3385492E+01 8.2651 5 HCO3- 0.7490734E-06 0.3480545E-04 0.2119871E+01 3.9139 6 HS- 0.6790547E-04 0.1032256E-03 0.3407671E+01 5.8707 7 Al+++ 0.1126792E-28 0.5244771E-05 0.1412546E+00 0.7608 8 H4SiO4 0.7116629E-03 0.1413272E-01 0.1355903E+04 -3.1477 9 Ca++ 0.1452992E-06 0.2464471E-06 0.9859155E-02 13.1065 10 Mg++ 0.2307247E-10 0.9871017E-10 0.2395480E-05 9.3053 11 Fe++ 0.6311316E-13 0.3769134E-07 0.2101122E-02 6.7428 12 K+ 0.1625695E-03 0.1633464E-03 0.6375563E+01 6.2505 13 Na+ 0.2066851E-01 0.2326103E-01 0.5337944E+03 8.3540 14 Mn++ 0.2028274E-10 0.2641915E-08 0.1448777E-03 9.2502 15 HPO4-- 0.4824250E-07 0.4947661E-07 0.4740085E-02 12.6311 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1026628E+03 -.8639022E-02 -.1026541E+03 0.0000000E+00 2 H2O -.2221128E+02 0.2084280E+02 -.4305408E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1718486E+00 -.1325838E-04 0.1718619E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1718231E+00 0.3876285E-04 -.1718619E+00 0.0000000E+00 7 Al+++ 0.2021659E+02 0.1969495E-05 0.2021659E+02 0.0000000E+00 8 H4SiO4 0.6455924E+02 0.5307060E-02 0.6455394E+02 0.0000000E+00 9 Ca++ 0.7130898E+01 0.9254481E-07 0.7130898E+01 0.0000000E+00 10 Mg++ 0.4920634E+01 0.3706724E-10 0.4920634E+01 0.0000000E+00 11 Fe++ 0.4420653E+01 0.1415370E-07 0.4420653E+01 0.0000000E+00 12 K+ 0.1316348E+01 0.6133918E-04 0.1316287E+01 0.0000000E+00 13 Na+ 0.7782669E+01 0.8734886E-02 0.7773934E+01 0.0000000E+00 14 Mn++ 0.1074993E+00 0.9920812E-09 0.1074993E+00 0.0000000E+00 15 HPO4-- 0.3668897E-01 0.1857925E-07 0.3668895E-01 0.0000000E+00 Chg. balance for solid moles: 0.1357E-13 Mass of aqueous solution: 0.376200E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 6199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 7.769 0.890 2037. 3.309 30.07 782.0 andradite 0.6874 -0.163 349.3 2.543 5.157 90.76 grossular 0.1641 -0.785 73.93 1.869 1.091 20.57 apatite-OH 0.1223E-01 -1.913 6.143 0.788 0.9069E-01 1.952 clinochlore 0.8831 -0.054 490.9 2.691 7.247 186.7 daphnite 0.2531 -0.597 180.6 2.257 2.666 54.72 chlorite-Mn 0.2150E-01 -1.668 15.24 1.183 0.2250 4.857 diopside 0.3491 -0.457 75.61 1.879 1.116 23.11 hedenbergite 0.8945E-01 -1.048 22.19 1.346 0.3276 6.078 microcline 1.153 0.062 320.8 2.506 4.736 125.3 stilbite 3.990 0.601 2812. 3.449 41.52 1312. stilpnomelane-Fe 0.3274 -0.485 352.9 2.548 5.210 121.9 tr.625ac.25prg.125 0.4302E-01 -1.366 36.77 1.565 0.5428 11.83 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6773.626399 g Volume = 2741.436561 cm3 Porosity: -10.4973% V(tot) - V(min): -.26044E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6199.9990000 g log = 3.7924 Original solution: 1000.0103000 g Original solution / Rock added: 0.16 (Water/Rock Ratio), log = -0.7924 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1185 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9413E+00 0.9846 0.1037E+01 0.1053E+01 CO2,gas 0.9769E-08 1.0067 0.1100E-07 0.1093E-07 CH4,gas 0.4533E-01 1.0124 0.5133E-01 0.5070E-01 H2,gas 0.1332E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.3395E-06 0.9957 0.3781E-06 0.3797E-06 S2,gas 0.2154E-28 1.0000 0.2409E-28 0.2409E-28 CO,gas 0.3798E-13 1.0000 0.4248E-13 0.4248E-13 SO3,gas 0.2078E-47 1.0000 0.2324E-47 0.2324E-47 SO2,gas 0.1172E-26 1.0000 0.1311E-26 0.1311E-26 HCl,gas 0.6899E-17 1.0000 0.7716E-17 0.7716E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.32 -9.96 -3.320 0.17004E+05 -7.959 3 CH4,gas 4.81 1.52 -3.29 -0.822 0.56169E+04 -1.290 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.37 -8.42 -4.211 0.14381E+05 -6.422 6 S2,gas -7.03 -37.65 -30.62 -4.710 0.52280E+05 -28.618 7 CO,gas 3.51 -11.86 -15.37 -4.730 0.26247E+05 -13.372 8 SO3,gas 17.43 -32.21 -49.63 -12.408 0.84748E+05 -47.634 9 SO2,gas 1.14 -27.75 -28.88 -7.702 0.49316E+05 -26.883 10 HCl,gas 5.48 -13.63 -19.11 -9.556 0.32634E+05 -17.113 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80605E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.22 -4.20 -1.401 0.71740E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.22 -4.05 -1.349 0.69127E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65551E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.40 -4.29 -1.227 0.73316E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33653E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.40 -3.85 -1.101 0.65778E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82262E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40701E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43450E+04 143 pyrrhotite -4.24 -7.62 -3.38 -1.126 0.57690E+04 144 pyrrhotiteFe0.875 -6.00 -9.02 -3.02 -1.110 0.51517E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22428E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23221E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47130E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91027E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.62 -3.23 -1.076 0.55121E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80437E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.11 -4.15 -1.384 0.70902E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 6199.9990000 g New total amount of reactant added: 6399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 6399.9990000 Water: Moles liquid = 0.1973E+02 kg liquid = 0.3554E+00 Moles total = -.2472E+02 kg total = -.4453E+00 Activity = 1.0000 Stoichiometric ionic strength = .1193666E-01 Osmotic coef. = 0.9677 True ionic strength = .2084664E-01 Chg. balance for total moles = -.1298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.90958E-10 -10.0412 0.76274E-10 -10.1176 0.83856E+00 -0.0765 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.38638E-03 -3.4130 0.32200E-03 -3.4921 0.83338E+00 -0.0792 4 SO4-- 0.21937E-11 -11.6588 0.11295E-11 -11.9471 0.51489E+00 -0.2883 5 HCO3- 0.79103E-06 -6.1018 0.66021E-06 -6.1803 0.83463E+00 -0.0785 6 HS- 0.71744E-04 -4.1442 0.59799E-04 -4.2233 0.83350E+00 -0.0791 7 Al+++ 0.11293E-28 -28.9472 0.25584E-29 -29.5920 0.22655E+00 -0.6448 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14550E-06 -6.8371 0.74351E-07 -7.1287 0.51101E+00 -0.2916 10 Mg++ 0.23104E-10 -10.6363 0.11751E-10 -10.9299 0.50861E+00 -0.2936 11 Fe++ 0.63200E-13 -13.1993 0.32180E-13 -13.4924 0.50918E+00 -0.2931 12 K+ 0.16267E-03 -3.7887 0.13580E-03 -3.8671 0.83483E+00 -0.0784 13 Na+ 0.20682E-01 -1.6844 0.17232E-01 -1.7637 0.83322E+00 -0.0792 14 Mn++ 0.20312E-10 -10.6923 0.10351E-10 -10.9850 0.50961E+00 -0.2928 15 HPO4-- 0.48193E-07 -7.3170 0.24818E-07 -7.6052 0.51497E+00 -0.2882 16 HSiO3- 0.10923E-01 -1.9616 0.91033E-02 -2.0408 0.83338E+00 -0.0792 17 Ca(HSiO3)+ 0.18161E-07 -7.7409 0.15165E-07 -7.8192 0.83501E+00 -0.0783 18 Mg(HSiO3)+ 0.35722E-11 -11.4471 0.29828E-11 -11.5254 0.83501E+00 -0.0783 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.67989E-16 -16.1676 0.56771E-16 -16.2459 0.83501E+00 -0.0783 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52417E-05 -5.2805 0.43603E-05 -5.3605 0.83184E+00 -0.0800 24 CH4,aq 0.34424E-04 -4.4631 0.34298E-04 -4.4647 0.99636E+00 -0.0016 25 C2H6,aq 0.18732E-13 -13.7274 0.18664E-13 -13.7290 0.99636E+00 -0.0016 29 CO,aq 0.28424E-16 -16.5463 0.28424E-16 -16.5463 0.10000E+01 0.0000 30 CO2,aq 0.10190E-09 -9.9918 0.10153E-09 -9.9934 0.99636E+00 -0.0016 31 CO3-2 0.15577E-05 -5.8075 0.80031E-06 -6.0967 0.51377E+00 -0.2892 32 CaCO3,aq 0.72878E-09 -9.1374 0.72878E-09 -9.1374 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.14812E-11 -11.8294 0.12369E-11 -11.9077 0.83501E+00 -0.0783 34 CaCl+ 0.45689E-10 -10.3402 0.38150E-10 -10.4185 0.83501E+00 -0.0783 35 CaCl2,aq 0.28603E-14 -14.5436 0.28603E-14 -14.5436 0.10000E+01 0.0000 36 CaOH+ 0.82317E-07 -7.0845 0.68735E-07 -7.1628 0.83501E+00 -0.0783 37 CaSO4,aq 0.26166E-16 -16.5823 0.26166E-16 -16.5823 0.10000E+01 0.0000 38 HCl,aq 0.46198E-14 -14.3354 0.46198E-14 -14.3354 0.10000E+01 0.0000 43 FeCl+ 0.19328E-16 -16.7138 0.16139E-16 -16.7921 0.83501E+00 -0.0783 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16751E-10 -10.7760 0.13987E-10 -10.8543 0.83501E+00 -0.0783 48 HFeO2- 0.37013E-07 -7.4316 0.30846E-07 -7.5108 0.83338E+00 -0.0792 49 FeO+ 0.12364E-16 -16.9078 0.10324E-16 -16.9861 0.83501E+00 -0.0783 51 FeO2- 0.41852E-09 -9.3783 0.34878E-09 -9.4574 0.83338E+00 -0.0792 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10909E-04 -4.9622 0.10870E-04 -4.9638 0.99636E+00 -0.0016 54 KCl,aq 0.77430E-09 -9.1111 0.77430E-09 -9.1111 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.28357E-14 -14.5473 0.23632E-14 -14.6265 0.83338E+00 -0.0792 58 MgCO3,aq 0.28782E-13 -13.5409 0.28782E-13 -13.5409 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.23873E-15 -15.6221 0.19934E-15 -15.7004 0.83501E+00 -0.0783 60 MgCl+ 0.65554E-14 -14.1834 0.54738E-14 -14.2617 0.83501E+00 -0.0783 61 MgOH+ 0.72076E-10 -10.1422 0.60184E-10 -10.2205 0.83501E+00 -0.0783 63 MnO,aq 0.18782E-08 -8.7262 0.18782E-08 -8.7262 0.10000E+01 0.0000 64 MnOH+ 0.50053E-09 -9.3006 0.41795E-09 -9.3789 0.83501E+00 -0.0783 65 MnO2-2 0.21732E-10 -10.6629 0.11165E-10 -10.9521 0.51377E+00 -0.2892 66 HMnO2- 0.22140E-09 -9.6548 0.18451E-09 -9.7340 0.83338E+00 -0.0792 69 MnCl+ 0.24159E-13 -13.6169 0.20173E-13 -13.6952 0.83501E+00 -0.0783 71 NaCl,aq 0.18119E-05 -5.7419 0.18119E-05 -5.7419 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94540E-02 -2.0244 0.78642E-02 -2.1043 0.83184E+00 -0.0800 79 HPO3-2 0.16585E-14 -14.7803 0.85207E-15 -15.0695 0.51377E+00 -0.2892 81 H2PO3- 0.15319E-18 -18.8148 0.12766E-18 -18.8939 0.83338E+00 -0.0792 82 H3PO4,aq 0.92953E-18 -18.0317 0.92953E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39784E-10 -10.4003 0.33187E-10 -10.4790 0.83419E+00 -0.0787 84 PO4-3 0.11926E-08 -8.9235 0.28416E-09 -9.5464 0.23827E+00 -0.6229 88 HP2O7-3 0.10218E-17 -17.9906 0.23174E-18 -18.6350 0.22680E+00 -0.6444 89 P2O7-4 0.10057E-16 -16.9976 0.74954E-18 -18.1252 0.74533E-01 -1.1277 90 H2S,aq 0.13754E-07 -7.8616 0.13704E-07 -7.8631 0.99636E+00 -0.0016 91 S2-2 0.14083E-13 -13.8513 0.72354E-14 -14.1405 0.51377E+00 -0.2892 97 SO3-2 0.32106E-17 -17.4934 0.16740E-17 -17.7762 0.52140E+00 -0.2828 99 HSO4- 0.95635E-19 -19.0194 0.79937E-19 -19.0973 0.83585E+00 -0.0779 Charge balance for all species = -.3662E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9095848E-10 -.2299450E-01 -.2313494E+02 0.0000 2 H2O 0.1000000E+01 0.5550445E+02 0.9981112E+06 0.0000 3 Cl- 0.3863850E-03 0.3881977E-03 0.1373775E+02 6.6255 4 SO4-- 0.2193661E-11 -.3715088E-04 -.3562284E+01 8.2881 5 HCO3- 0.7910251E-06 0.3677314E-04 0.2239714E+01 3.9373 6 HS- 0.7174442E-04 0.1089091E-03 0.3595292E+01 5.8943 7 Al+++ 0.1129259E-28 0.5241854E-05 0.1411759E+00 0.7608 8 H4SiO4 0.7116632E-03 0.1412665E-01 0.1355320E+04 -3.1477 9 Ca++ 0.1454988E-06 0.2467528E-06 0.9871377E-02 13.1065 10 Mg++ 0.2310422E-10 0.9879298E-10 0.2397488E-05 9.3053 11 Fe++ 0.6320000E-13 0.3767054E-07 0.2099962E-02 6.7428 12 K+ 0.1626739E-03 0.1634509E-03 0.6379637E+01 6.2505 13 Na+ 0.2068181E-01 0.2327443E-01 0.5341015E+03 8.3540 14 Mn++ 0.2031160E-10 0.2642245E-08 0.1448957E-03 9.2502 15 HPO4-- 0.4819296E-07 0.4942534E-07 0.4735169E-02 12.6300 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1059745E+03 -.8172763E-02 -.1059663E+03 0.0000000E+00 2 H2O -.2471836E+02 0.1972753E+02 -.4444589E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1773913E+00 -.1320426E-04 0.1774045E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1773658E+00 0.3870873E-04 -.1774045E+00 0.0000000E+00 7 Al+++ 0.2086874E+02 0.1863073E-05 0.2086874E+02 0.0000000E+00 8 H4SiO4 0.6664180E+02 0.5020931E-02 0.6663678E+02 0.0000000E+00 9 Ca++ 0.7360926E+01 0.8770149E-07 0.7360926E+01 0.0000000E+00 10 Mg++ 0.5079364E+01 0.3511325E-10 0.5079364E+01 0.0000000E+00 11 Fe++ 0.4563254E+01 0.1338896E-07 0.4563254E+01 0.0000000E+00 12 K+ 0.1358811E+01 0.5809413E-04 0.1358753E+01 0.0000000E+00 13 Na+ 0.8033718E+01 0.8272255E-02 0.8025446E+01 0.0000000E+00 14 Mn++ 0.1109670E+00 0.9391132E-09 0.1109670E+00 0.0000000E+00 15 HPO4-- 0.3787248E-01 0.1756688E-07 0.3787247E-01 0.0000000E+00 Chg. balance for solid moles: -.3775E-14 Mass of aqueous solution: 0.356070E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 6399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 8.020 0.904 2103. 3.323 30.08 807.3 andradite 0.7096 -0.149 360.6 2.557 5.157 93.69 grossular 0.1694 -0.771 76.32 1.883 1.091 21.23 apatite-OH 0.1262E-01 -1.899 6.341 0.802 0.9069E-01 2.015 clinochlore 0.9116 -0.040 506.7 2.705 7.246 192.7 daphnite 0.2613 -0.583 186.4 2.270 2.666 56.49 chlorite-Mn 0.2219E-01 -1.654 15.73 1.197 0.2250 5.014 diopside 0.3607 -0.443 78.11 1.893 1.117 23.87 hedenbergite 0.9241E-01 -1.034 22.93 1.360 0.3279 6.280 microcline 1.190 0.075 331.2 2.520 4.736 129.4 stilbite 4.119 0.615 2903. 3.463 41.51 1354. stilpnomelane-Fe 0.3380 -0.471 364.3 2.561 5.211 125.8 tr.625ac.25prg.125 0.4438E-01 -1.353 37.93 1.579 0.5425 12.21 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 6992.137362 g Volume = 2829.849274 cm3 Porosity: -10.4978% V(tot) - V(min): -.26885E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6399.9990000 g log = 3.8062 Original solution: 1000.0103000 g Original solution / Rock added: 0.16 (Water/Rock Ratio), log = -0.8062 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1214 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9389E+00 0.9846 0.1037E+01 0.1053E+01 CO2,gas 0.1030E-07 1.0067 0.1162E-07 0.1154E-07 CH4,gas 0.4777E-01 1.0124 0.5424E-01 0.5357E-01 H2,gas 0.1329E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.3580E-06 0.9956 0.3997E-06 0.4014E-06 S2,gas 0.2401E-28 1.0000 0.2692E-28 0.2692E-28 CO,gas 0.4002E-13 1.0000 0.4488E-13 0.4488E-13 SO3,gas 0.2191E-47 1.0000 0.2457E-47 0.2457E-47 SO2,gas 0.1236E-26 1.0000 0.1386E-26 0.1386E-26 HCl,gas 0.7274E-17 1.0000 0.8157E-17 0.8157E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.30 -9.93 -3.312 0.16963E+05 -7.935 3 CH4,gas 4.81 1.54 -3.27 -0.816 0.55761E+04 -1.266 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.34 -8.40 -4.199 0.14340E+05 -6.398 6 S2,gas -7.03 -37.60 -30.57 -4.703 0.52197E+05 -28.570 7 CO,gas 3.51 -11.84 -15.35 -4.722 0.26206E+05 -13.348 8 SO3,gas 17.43 -32.18 -49.61 -12.402 0.84707E+05 -47.610 9 SO2,gas 1.14 -27.72 -28.86 -7.696 0.49275E+05 -26.858 10 HCl,gas 5.48 -13.61 -19.09 -9.544 0.32593E+05 -17.088 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80604E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.19 -4.18 -1.393 0.71332E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.19 -4.02 -1.342 0.68718E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65550E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.38 -4.27 -1.220 0.72908E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.38 -3.83 -1.094 0.65370E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82261E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40701E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43450E+04 143 pyrrhotite -4.24 -7.60 -3.35 -1.118 0.57278E+04 144 pyrrhotiteFe0.875 -6.00 -8.99 -2.99 -1.101 0.51105E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22428E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23220E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47129E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91027E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.60 -3.20 -1.068 0.54710E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80437E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.09 -4.13 -1.376 0.70489E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 6399.9990000 g New total amount of reactant added: 6599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 6599.9990000 Water: Moles liquid = 0.1861E+02 kg liquid = 0.3353E+00 Moles total = -.2723E+02 kg total = -.4905E+00 Activity = 1.0000 Stoichiometric ionic strength = .1195599E-01 Osmotic coef. = 0.9677 True ionic strength = .2086175E-01 Chg. balance for total moles = -.1298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91024E-10 -10.0408 0.76325E-10 -10.1173 0.83852E+00 -0.0765 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.40954E-03 -3.3877 0.34128E-03 -3.4669 0.83334E+00 -0.0792 4 SO4-- 0.23239E-11 -11.6338 0.11963E-11 -11.9221 0.51480E+00 -0.2884 5 HCO3- 0.83795E-06 -6.0768 0.69934E-06 -6.1553 0.83459E+00 -0.0785 6 HS- 0.76043E-04 -4.1189 0.63379E-04 -4.1981 0.83346E+00 -0.0791 7 Al+++ 0.11320E-28 -28.9461 0.25635E-29 -29.5912 0.22646E+00 -0.6450 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14572E-06 -6.8365 0.74451E-07 -7.1281 0.51091E+00 -0.2917 10 Mg++ 0.23140E-10 -10.6356 0.11767E-10 -10.9293 0.50851E+00 -0.2937 11 Fe++ 0.63297E-13 -13.1986 0.32224E-13 -13.4918 0.50908E+00 -0.2932 12 K+ 0.16279E-03 -3.7884 0.13590E-03 -3.8668 0.83479E+00 -0.0784 13 Na+ 0.20697E-01 -1.6841 0.17244E-01 -1.7634 0.83318E+00 -0.0793 14 Mn++ 0.20344E-10 -10.6916 0.10365E-10 -10.9844 0.50951E+00 -0.2928 15 HPO4-- 0.48138E-07 -7.3175 0.24785E-07 -7.6058 0.51487E+00 -0.2883 16 HSiO3- 0.10917E-01 -1.9619 0.90972E-02 -2.0411 0.83334E+00 -0.0792 17 Ca(HSiO3)+ 0.18174E-07 -7.7405 0.15175E-07 -7.8189 0.83497E+00 -0.0783 18 Mg(HSiO3)+ 0.35748E-11 -11.4468 0.29848E-11 -11.5251 0.83497E+00 -0.0783 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.68037E-16 -16.1673 0.56809E-16 -16.2456 0.83497E+00 -0.0783 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52384E-05 -5.2808 0.43573E-05 -5.3608 0.83180E+00 -0.0800 24 CH4,aq 0.36489E-04 -4.4378 0.36356E-04 -4.4394 0.99636E+00 -0.0016 25 C2H6,aq 0.21047E-13 -13.6768 0.20970E-13 -13.6784 0.99636E+00 -0.0016 29 CO,aq 0.30129E-16 -16.5210 0.30129E-16 -16.5210 0.10000E+01 0.0000 30 CO2,aq 0.10801E-09 -9.9665 0.10762E-09 -9.9681 0.99636E+00 -0.0016 31 CO3-2 0.16493E-05 -5.7827 0.84718E-06 -6.0720 0.51367E+00 -0.2893 32 CaCO3,aq 0.77250E-09 -9.1121 0.77250E-09 -9.1121 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.15712E-11 -11.8038 0.13119E-11 -11.8821 0.83497E+00 -0.0783 34 CaCl+ 0.48491E-10 -10.3143 0.40489E-10 -10.3927 0.83497E+00 -0.0783 35 CaCl2,aq 0.32173E-14 -14.4925 0.32173E-14 -14.4925 0.10000E+01 0.0000 36 CaOH+ 0.82376E-07 -7.0842 0.68781E-07 -7.1625 0.83497E+00 -0.0783 37 CaSO4,aq 0.27751E-16 -16.5567 0.27751E-16 -16.5567 0.10000E+01 0.0000 38 HCl,aq 0.48996E-14 -14.3098 0.48996E-14 -14.3098 0.10000E+01 0.0000 43 FeCl+ 0.20514E-16 -16.6880 0.17128E-16 -16.7663 0.83497E+00 -0.0783 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16763E-10 -10.7756 0.13997E-10 -10.8540 0.83497E+00 -0.0783 48 HFeO2- 0.36990E-07 -7.4319 0.30825E-07 -7.5111 0.83334E+00 -0.0792 49 FeO+ 0.12373E-16 -16.9075 0.10331E-16 -16.9859 0.83497E+00 -0.0783 51 FeO2- 0.41826E-09 -9.3786 0.34855E-09 -9.4577 0.83334E+00 -0.0792 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10870E-04 -4.9638 0.99636E+00 -0.0016 54 KCl,aq 0.82120E-09 -9.0855 0.82120E-09 -9.0855 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.30056E-14 -14.5221 0.25047E-14 -14.6012 0.83334E+00 -0.0792 58 MgCO3,aq 0.30508E-13 -13.5156 0.30508E-13 -13.5156 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.25323E-15 -15.5965 0.21144E-15 -15.6748 0.83497E+00 -0.0783 60 MgCl+ 0.69575E-14 -14.1575 0.58093E-14 -14.2359 0.83497E+00 -0.0783 61 MgOH+ 0.72128E-10 -10.1419 0.60225E-10 -10.2202 0.83497E+00 -0.0783 63 MnO,aq 0.18783E-08 -8.7262 0.18783E-08 -8.7262 0.10000E+01 0.0000 64 MnOH+ 0.50092E-09 -9.3002 0.41825E-09 -9.3786 0.83497E+00 -0.0783 65 MnO2-2 0.21708E-10 -10.6634 0.11151E-10 -10.9527 0.51367E+00 -0.2893 66 HMnO2- 0.22128E-09 -9.6551 0.18440E-09 -9.7342 0.83334E+00 -0.0792 69 MnCl+ 0.25642E-13 -13.5911 0.21410E-13 -13.6694 0.83497E+00 -0.0783 71 NaCl,aq 0.19216E-05 -5.7163 0.19216E-05 -5.7163 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94481E-02 -2.0247 0.78590E-02 -2.1046 0.83180E+00 -0.0800 79 HPO3-2 0.16565E-14 -14.7808 0.85092E-15 -15.0701 0.51367E+00 -0.2893 81 H2PO3- 0.15309E-18 -18.8150 0.12758E-18 -18.8942 0.83334E+00 -0.0792 82 H3PO4,aq 0.92953E-18 -18.0317 0.92953E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39759E-10 -10.4006 0.33165E-10 -10.4793 0.83415E+00 -0.0788 84 PO4-3 0.11907E-08 -8.9242 0.28359E-09 -9.5473 0.23817E+00 -0.6231 88 HP2O7-3 0.10202E-17 -17.9913 0.23128E-18 -18.6359 0.22670E+00 -0.6446 89 P2O7-4 0.10037E-16 -16.9984 0.74753E-18 -18.1264 0.74476E-01 -1.1280 90 H2S,aq 0.14587E-07 -7.8360 0.14534E-07 -7.8376 0.99636E+00 -0.0016 91 S2-2 0.15823E-13 -13.8007 0.81277E-14 -14.0900 0.51367E+00 -0.2893 97 SO3-2 0.34012E-17 -17.4684 0.17731E-17 -17.7513 0.52131E+00 -0.2829 99 HSO4- 0.10137E-18 -18.9941 0.84723E-19 -19.0720 0.83581E+00 -0.0779 Charge balance for all species = -.3868E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9102370E-10 -.2298192E-01 -.2312226E+02 0.0000 2 H2O 0.1000000E+01 0.5550445E+02 0.9981105E+06 0.0000 3 Cl- 0.4095365E-03 0.4114590E-03 0.1456092E+02 6.6504 4 SO4-- 0.2323889E-11 -.3921587E-04 -.3760287E+01 8.3125 5 HCO3- 0.8379537E-06 0.3897664E-04 0.2373919E+01 3.9620 6 HS- 0.7604344E-04 0.1152739E-03 0.3805404E+01 5.9193 7 Al+++ 0.1132029E-28 0.5238591E-05 0.1410880E+00 0.7608 8 H4SiO4 0.7116636E-03 0.1411987E-01 0.1354668E+04 -3.1477 9 Ca++ 0.1457227E-06 0.2470955E-06 0.9885079E-02 13.1065 10 Mg++ 0.2313982E-10 0.9888571E-10 0.2399736E-05 9.3053 11 Fe++ 0.6329737E-13 0.3764726E-07 0.2098662E-02 6.7428 12 K+ 0.1627910E-03 0.1635680E-03 0.6384202E+01 6.2505 13 Na+ 0.2069672E-01 0.2328944E-01 0.5344457E+03 8.3540 14 Mn++ 0.2034378E-10 0.2642591E-08 0.1449146E-03 9.2503 15 HPO4-- 0.4813754E-07 0.4936799E-07 0.4729671E-02 12.6288 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1092862E+03 -.7706507E-02 -.1092785E+03 0.0000000E+00 2 H2O -.2722545E+02 0.1861226E+02 -.4583770E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1829340E+00 -.1315022E-04 0.1829471E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1829085E+00 0.3865469E-04 -.1829471E+00 0.0000000E+00 7 Al+++ 0.2152089E+02 0.1756652E-05 0.2152089E+02 0.0000000E+00 8 H4SiO4 0.6872436E+02 0.4734802E-02 0.6871962E+02 0.0000000E+00 9 Ca++ 0.7590955E+01 0.8285829E-07 0.7590955E+01 0.0000000E+00 10 Mg++ 0.5238094E+01 0.3315925E-10 0.5238094E+01 0.0000000E+00 11 Fe++ 0.4705856E+01 0.1262422E-07 0.4705856E+01 0.0000000E+00 12 K+ 0.1401274E+01 0.5484911E-04 0.1401219E+01 0.0000000E+00 13 Na+ 0.8284767E+01 0.7809626E-02 0.8276957E+01 0.0000000E+00 14 Mn++ 0.1144347E+00 0.8861377E-09 0.1144347E+00 0.0000000E+00 15 HPO4-- 0.3905600E-01 0.1655452E-07 0.3905598E-01 0.0000000E+00 Chg. balance for solid moles: -.3221E-13 Mass of aqueous solution: 0.335940E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 6599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 8.271 0.918 2169. 3.336 30.08 832.6 andradite 0.7318 -0.136 371.9 2.570 5.157 96.62 grossular 0.1747 -0.758 78.70 1.896 1.091 21.90 apatite-OH 0.1302E-01 -1.885 6.540 0.816 0.9069E-01 2.078 clinochlore 0.9400 -0.027 522.5 2.718 7.246 198.7 daphnite 0.2694 -0.570 192.2 2.284 2.666 58.25 chlorite-Mn 0.2289E-01 -1.640 16.23 1.210 0.2250 5.171 diopside 0.3723 -0.429 80.62 1.906 1.118 24.64 hedenbergite 0.9537E-01 -1.021 23.66 1.374 0.3282 6.481 microcline 1.227 0.089 341.5 2.533 4.736 133.4 stilbite 4.247 0.628 2993. 3.476 41.51 1396. stilpnomelane-Fe 0.3485 -0.458 375.7 2.575 5.211 129.8 tr.625ac.25prg.125 0.4574E-01 -1.340 39.10 1.592 0.5422 12.58 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7210.648324 g Volume = 2918.261987 cm3 Porosity: -10.4984% V(tot) - V(min): -.27726E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6599.9990000 g log = 3.8195 Original solution: 1000.0103000 g Original solution / Rock added: 0.15 (Water/Rock Ratio), log = -0.8195 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1246 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9363E+00 0.9846 0.1037E+01 0.1053E+01 CO2,gas 0.1088E-07 1.0066 0.1232E-07 0.1224E-07 CH4,gas 0.5050E-01 1.0124 0.5749E-01 0.5679E-01 H2,gas 0.1325E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.3786E-06 0.9956 0.4239E-06 0.4258E-06 S2,gas 0.2692E-28 1.0000 0.3028E-28 0.3028E-28 CO,gas 0.4230E-13 1.0000 0.4757E-13 0.4757E-13 SO3,gas 0.2317E-47 1.0000 0.2605E-47 0.2605E-47 SO2,gas 0.1307E-26 1.0000 0.1469E-26 0.1469E-26 HCl,gas 0.7692E-17 1.0000 0.8651E-17 0.8651E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.18198E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.60662E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 -0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.27 -9.91 -3.303 0.16920E+05 -7.909 3 CH4,gas 4.81 1.57 -3.24 -0.810 0.55329E+04 -1.240 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.32 -8.37 -4.186 0.14296E+05 -6.373 6 S2,gas -7.03 -37.55 -30.52 -4.695 0.52110E+05 -28.519 7 CO,gas 3.51 -11.81 -15.32 -4.715 0.26163E+05 -13.323 8 SO3,gas 17.43 -32.16 -49.58 -12.396 0.84664E+05 -47.584 9 SO2,gas 1.14 -27.70 -28.83 -7.689 0.49231E+05 -26.833 10 HCl,gas 5.48 -13.58 -19.06 -9.531 0.32549E+05 -17.063 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80603E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.17 -4.15 -1.384 0.70900E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.17 -4.00 -1.333 0.68287E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65550E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.35 -4.24 -1.213 0.72476E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68256E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.35 -3.80 -1.087 0.64938E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82261E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20058E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40701E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43450E+04 143 pyrrhotite -4.24 -7.57 -3.33 -1.110 0.56841E+04 144 pyrrhotiteFe0.875 -6.00 -8.97 -2.97 -1.091 0.50669E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22428E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23220E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47128E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.57 -3.18 -1.060 0.54273E+04 183 vesuvianite 224.06 219.35 -4.71 -0.036 0.80437E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55580E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.07 -4.10 -1.368 0.70053E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 6599.9990000 g New total amount of reactant added: 6799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 6799.9990000 Water: Moles liquid = 0.1750E+02 kg liquid = 0.3152E+00 Moles total = -.2973E+02 kg total = -.5356E+00 Activity = 1.0000 Stoichiometric ionic strength = .1197780E-01 Osmotic coef. = 0.9676 True ionic strength = .2087880E-01 Chg. balance for total moles = -.1297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91097E-10 -10.0405 0.76383E-10 -10.1170 0.83848E+00 -0.0765 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.43564E-03 -3.3609 0.36301E-03 -3.4401 0.83329E+00 -0.0792 4 SO4-- 0.24706E-11 -11.6072 0.12716E-11 -11.8957 0.51468E+00 -0.2885 5 HCO3- 0.89080E-06 -6.0502 0.74341E-06 -6.1288 0.83454E+00 -0.0786 6 HS- 0.80891E-04 -4.0921 0.67415E-04 -4.1712 0.83341E+00 -0.0791 7 Al+++ 0.11352E-28 -28.9449 0.25694E-29 -29.5902 0.22634E+00 -0.6452 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14598E-06 -6.8357 0.74564E-07 -7.1275 0.51080E+00 -0.2918 10 Mg++ 0.23180E-10 -10.6349 0.11785E-10 -10.9287 0.50840E+00 -0.2938 11 Fe++ 0.63407E-13 -13.1979 0.32272E-13 -13.4912 0.50897E+00 -0.2933 12 K+ 0.16292E-03 -3.7880 0.13600E-03 -3.8665 0.83474E+00 -0.0784 13 Na+ 0.20714E-01 -1.6837 0.17257E-01 -1.7630 0.83313E+00 -0.0793 14 Mn++ 0.20380E-10 -10.6908 0.10382E-10 -10.9837 0.50940E+00 -0.2929 15 HPO4-- 0.48075E-07 -7.3181 0.24747E-07 -7.6065 0.51476E+00 -0.2884 16 HSiO3- 0.10909E-01 -1.9622 0.90904E-02 -2.0414 0.83329E+00 -0.0792 17 Ca(HSiO3)+ 0.18189E-07 -7.7402 0.15187E-07 -7.8185 0.83493E+00 -0.0784 18 Mg(HSiO3)+ 0.35777E-11 -11.4464 0.29871E-11 -11.5248 0.83493E+00 -0.0784 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.68092E-16 -16.1669 0.56852E-16 -16.2453 0.83493E+00 -0.0784 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52348E-05 -5.2811 0.43540E-05 -5.3611 0.83175E+00 -0.0800 24 CH4,aq 0.38817E-04 -4.4110 0.38675E-04 -4.4126 0.99635E+00 -0.0016 25 C2H6,aq 0.23819E-13 -13.6231 0.23732E-13 -13.6247 0.99635E+00 -0.0016 29 CO,aq 0.32051E-16 -16.4942 0.32051E-16 -16.4942 0.10000E+01 0.0000 30 CO2,aq 0.11491E-09 -9.9397 0.11449E-09 -9.9412 0.99635E+00 -0.0016 31 CO3-2 0.17522E-05 -5.7564 0.89988E-06 -6.0458 0.51356E+00 -0.2894 32 CaCO3,aq 0.82179E-09 -9.0852 0.82179E-09 -9.0852 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.16729E-11 -11.7765 0.13967E-11 -11.8549 0.83493E+00 -0.0784 34 CaCl+ 0.51660E-10 -10.2868 0.43132E-10 -10.3652 0.83493E+00 -0.0784 35 CaCl2,aq 0.36456E-14 -14.4382 0.36456E-14 -14.4382 0.10000E+01 0.0000 36 CaOH+ 0.82443E-07 -7.0838 0.68833E-07 -7.1622 0.83493E+00 -0.0784 37 CaSO4,aq 0.29541E-16 -16.5296 0.29541E-16 -16.5296 0.10000E+01 0.0000 38 HCl,aq 0.52156E-14 -14.2827 0.52156E-14 -14.2827 0.10000E+01 0.0000 43 FeCl+ 0.21854E-16 -16.6605 0.18247E-16 -16.7388 0.83493E+00 -0.0784 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16777E-10 -10.7753 0.14007E-10 -10.8536 0.83493E+00 -0.0784 48 HFeO2- 0.36964E-07 -7.4322 0.30802E-07 -7.5114 0.83329E+00 -0.0792 49 FeO+ 0.12383E-16 -16.9072 0.10339E-16 -16.9855 0.83493E+00 -0.0784 51 FeO2- 0.41796E-09 -9.3789 0.34828E-09 -9.4581 0.83329E+00 -0.0792 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10870E-04 -4.9638 0.99635E+00 -0.0016 54 KCl,aq 0.87416E-09 -9.0584 0.87416E-09 -9.0584 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.31972E-14 -14.4952 0.26642E-14 -14.5744 0.83329E+00 -0.0792 58 MgCO3,aq 0.32455E-13 -13.4887 0.32455E-13 -13.4887 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.26961E-15 -15.5693 0.22510E-15 -15.6476 0.83493E+00 -0.0784 60 MgCl+ 0.74121E-14 -14.1301 0.61886E-14 -14.2084 0.83493E+00 -0.0784 61 MgOH+ 0.72186E-10 -10.1415 0.60270E-10 -10.2199 0.83493E+00 -0.0784 63 MnO,aq 0.18784E-08 -8.7262 0.18784E-08 -8.7262 0.10000E+01 0.0000 64 MnOH+ 0.50134E-09 -9.2999 0.41858E-09 -9.3782 0.83493E+00 -0.0784 65 MnO2-2 0.21681E-10 -10.6639 0.11134E-10 -10.9533 0.51356E+00 -0.2894 66 HMnO2- 0.22113E-09 -9.6554 0.18427E-09 -9.7346 0.83329E+00 -0.0792 69 MnCl+ 0.27318E-13 -13.5635 0.22809E-13 -13.6419 0.83493E+00 -0.0784 71 NaCl,aq 0.20455E-05 -5.6892 0.20455E-05 -5.6892 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94415E-02 -2.0250 0.78530E-02 -2.1050 0.83175E+00 -0.0800 79 HPO3-2 0.16544E-14 -14.7814 0.84964E-15 -15.0708 0.51356E+00 -0.2894 81 H2PO3- 0.15298E-18 -18.8154 0.12748E-18 -18.8946 0.83329E+00 -0.0792 82 H3PO4,aq 0.92953E-18 -18.0317 0.92953E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39732E-10 -10.4009 0.33140E-10 -10.4796 0.83410E+00 -0.0788 84 PO4-3 0.11885E-08 -8.9250 0.28294E-09 -9.5483 0.23806E+00 -0.6233 88 HP2O7-3 0.10184E-17 -17.9921 0.23075E-18 -18.6369 0.22659E+00 -0.6448 89 P2O7-4 0.10015E-16 -16.9993 0.74527E-18 -18.1277 0.74412E-01 -1.1284 90 H2S,aq 0.15528E-07 -7.8089 0.15472E-07 -7.8105 0.99635E+00 -0.0016 91 S2-2 0.17906E-13 -13.7470 0.91959E-14 -14.0364 0.51356E+00 -0.2894 97 SO3-2 0.36158E-17 -17.4418 0.18846E-17 -17.7248 0.52120E+00 -0.2830 98 HSO3- 0.10109E-19 -19.9953 0.84241E-20 -20.0745 0.83329E+00 -0.0792 99 HSO4- 0.10783E-18 -18.9673 0.90118E-19 -19.0452 0.83576E+00 -0.0779 Charge balance for all species = -.4109E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9109728E-10 -.2296775E-01 -.2310799E+02 0.0000 2 H2O 0.1000000E+01 0.5550445E+02 0.9981097E+06 0.0000 3 Cl- 0.4356394E-03 0.4376858E-03 0.1548904E+02 6.6769 4 SO4-- 0.2470553E-11 -.4154442E-04 -.3983561E+01 8.3383 5 HCO3- 0.8908005E-06 0.4146105E-04 0.2525233E+01 3.9882 6 HS- 0.8089051E-04 0.1224505E-03 0.4042312E+01 5.9458 7 Al+++ 0.1135160E-28 0.5234918E-05 0.1409889E+00 0.7608 8 H4SiO4 0.7116639E-03 0.1411222E-01 0.1353934E+04 -3.1477 9 Ca++ 0.1459754E-06 0.2474823E-06 0.9900546E-02 13.1065 10 Mg++ 0.2318003E-10 0.9899026E-10 0.2402272E-05 9.3053 11 Fe++ 0.6340733E-13 0.3762105E-07 0.2097199E-02 6.7428 12 K+ 0.1629230E-03 0.1637001E-03 0.6389353E+01 6.2505 13 Na+ 0.2071353E-01 0.2330638E-01 0.5348339E+03 8.3540 14 Mn++ 0.2037996E-10 0.2642961E-08 0.1449348E-03 9.2503 15 HPO4-- 0.4807514E-07 0.4930341E-07 0.4723481E-02 12.6275 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1125979E+03 -.7240254E-02 -.1125906E+03 0.0000000E+00 2 H2O -.2973253E+02 0.1749698E+02 -.4722951E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1884767E+00 -.1309628E-04 0.1884898E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1884512E+00 0.3860075E-04 -.1884898E+00 0.0000000E+00 7 Al+++ 0.2217304E+02 0.1650233E-05 0.2217304E+02 0.0000000E+00 8 H4SiO4 0.7080691E+02 0.4448676E-02 0.7080247E+02 0.0000000E+00 9 Ca++ 0.7820983E+01 0.7801524E-07 0.7820983E+01 0.0000000E+00 10 Mg++ 0.5396825E+01 0.3120526E-10 0.5396825E+01 0.0000000E+00 11 Fe++ 0.4848458E+01 0.1185950E-07 0.4848458E+01 0.0000000E+00 12 K+ 0.1443737E+01 0.5160411E-04 0.1443685E+01 0.0000000E+00 13 Na+ 0.8535815E+01 0.7347001E-02 0.8528468E+01 0.0000000E+00 14 Mn++ 0.1179024E+00 0.8331556E-09 0.1179024E+00 0.0000000E+00 15 HPO4-- 0.4023952E-01 0.1554219E-07 0.4023950E-01 0.0000000E+00 Chg. balance for solid moles: -.1291E-13 Mass of aqueous solution: 0.315810E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 6799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 8.523 0.931 2235. 3.349 30.08 857.9 andradite 0.7540 -0.123 383.1 2.583 5.157 99.54 grossular 0.1800 -0.745 81.08 1.909 1.091 22.56 apatite-OH 0.1341E-01 -1.872 6.738 0.829 0.9069E-01 2.141 clinochlore 0.9684 -0.014 538.3 2.731 7.246 204.8 daphnite 0.2776 -0.557 198.0 2.297 2.666 60.01 chlorite-Mn 0.2358E-01 -1.627 16.72 1.223 0.2250 5.328 diopside 0.3838 -0.416 83.12 1.920 1.119 25.40 hedenbergite 0.9834E-01 -1.007 24.40 1.387 0.3284 6.682 microcline 1.264 0.102 351.9 2.546 4.736 137.4 stilbite 4.376 0.641 3084. 3.489 41.51 1438. stilpnomelane-Fe 0.3591 -0.445 387.1 2.588 5.211 133.7 tr.625ac.25prg.125 0.4710E-01 -1.327 40.26 1.605 0.5420 12.96 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7429.159286 g Volume = 3006.674700 cm3 Porosity: -10.4989% V(tot) - V(min): -.28568E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6799.9990000 g log = 3.8325 Original solution: 1000.0103000 g Original solution / Rock added: 0.15 (Water/Rock Ratio), log = -0.8325 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1283 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9332E+00 0.9845 0.1037E+01 0.1053E+01 CO2,gas 0.1154E-07 1.0066 0.1311E-07 0.1302E-07 CH4,gas 0.5355E-01 1.0123 0.6116E-01 0.6042E-01 H2,gas 0.1321E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.4017E-06 0.9956 0.4512E-06 0.4532E-06 S2,gas 0.3041E-28 1.0000 0.3431E-28 0.3431E-28 CO,gas 0.4485E-13 1.0000 0.5061E-13 0.5061E-13 SO3,gas 0.2458E-47 1.0000 0.2773E-47 0.2773E-47 SO2,gas 0.1386E-26 1.0000 0.1564E-26 0.1564E-26 HCl,gas 0.8162E-17 1.0000 0.9209E-17 0.9209E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.25 -9.88 -3.294 0.16874E+05 -7.883 3 CH4,gas 4.81 1.60 -3.21 -0.803 0.54870E+04 -1.214 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.29 -8.35 -4.173 0.14250E+05 -6.346 6 S2,gas -7.03 -37.50 -30.46 -4.687 0.52017E+05 -28.465 7 CO,gas 3.51 -11.79 -15.30 -4.706 0.26117E+05 -13.296 8 SO3,gas 17.43 -32.13 -49.56 -12.389 0.84617E+05 -47.557 9 SO2,gas 1.14 -27.67 -28.81 -7.682 0.49185E+05 -26.806 10 HCl,gas 5.48 -13.56 -19.04 -9.518 0.32503E+05 -17.036 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80602E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.14 -4.13 -1.375 0.70441E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.14 -3.97 -1.324 0.67828E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65550E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.33 -4.22 -1.205 0.72017E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.33 -3.78 -1.079 0.64479E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82261E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61286E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40701E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43450E+04 143 pyrrhotite -4.24 -7.55 -3.30 -1.101 0.56378E+04 144 pyrrhotiteFe0.875 -6.00 -8.94 -2.94 -1.081 0.50206E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22427E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23220E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47128E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.55 -3.15 -1.050 0.53810E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80437E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.04 -4.08 -1.359 0.69589E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 6799.9990000 g New total amount of reactant added: 6999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 6999.9990000 Water: Moles liquid = 0.1638E+02 kg liquid = 0.2951E+00 Moles total = -.3224E+02 kg total = -.5808E+00 Activity = 1.0000 Stoichiometric ionic strength = .1200258E-01 Osmotic coef. = 0.9676 True ionic strength = .2089818E-01 Chg. balance for total moles = -.1298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91181E-10 -10.0401 0.76448E-10 -10.1166 0.83843E+00 -0.0765 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.46530E-03 -3.3323 0.38770E-03 -3.4115 0.83324E+00 -0.0792 4 SO4-- 0.26370E-11 -11.5789 0.13569E-11 -11.8675 0.51456E+00 -0.2886 5 HCO3- 0.95076E-06 -6.0219 0.79340E-06 -6.1005 0.83449E+00 -0.0786 6 HS- 0.86398E-04 -4.0635 0.72000E-04 -4.1427 0.83336E+00 -0.0792 7 Al+++ 0.11387E-28 -28.9436 0.25760E-29 -29.5891 0.22622E+00 -0.6455 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14626E-06 -6.8349 0.74692E-07 -7.1267 0.51067E+00 -0.2919 10 Mg++ 0.23226E-10 -10.6340 0.11805E-10 -10.9279 0.50827E+00 -0.2939 11 Fe++ 0.63532E-13 -13.1970 0.32328E-13 -13.4904 0.50884E+00 -0.2934 12 K+ 0.16307E-03 -3.7876 0.13612E-03 -3.8661 0.83469E+00 -0.0785 13 Na+ 0.20733E-01 -1.6833 0.17272E-01 -1.7627 0.83308E+00 -0.0793 14 Mn++ 0.20421E-10 -10.6899 0.10400E-10 -10.9830 0.50927E+00 -0.2930 15 HPO4-- 0.48004E-07 -7.3187 0.24705E-07 -7.6072 0.51463E+00 -0.2885 16 HSiO3- 0.10900E-01 -1.9626 0.90826E-02 -2.0418 0.83324E+00 -0.0792 17 Ca(HSiO3)+ 0.18206E-07 -7.7398 0.15200E-07 -7.8182 0.83487E+00 -0.0784 18 Mg(HSiO3)+ 0.35810E-11 -11.4460 0.29897E-11 -11.5244 0.83487E+00 -0.0784 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.68155E-16 -16.1665 0.56901E-16 -16.2449 0.83487E+00 -0.0784 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52306E-05 -5.2814 0.43503E-05 -5.3615 0.83170E+00 -0.0800 24 CH4,aq 0.41463E-04 -4.3823 0.41311E-04 -4.3839 0.99634E+00 -0.0016 25 C2H6,aq 0.27176E-13 -13.5658 0.27077E-13 -13.5674 0.99634E+00 -0.0016 29 CO,aq 0.34236E-16 -16.4655 0.34236E-16 -16.4655 0.10000E+01 0.0000 30 CO2,aq 0.12274E-09 -9.9110 0.12229E-09 -9.9126 0.99634E+00 -0.0016 31 CO3-2 0.18689E-05 -5.7284 0.95957E-06 -6.0179 0.51344E+00 -0.2895 32 CaCO3,aq 0.87781E-09 -9.0566 0.87781E-09 -9.0566 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.17885E-11 -11.7475 0.14932E-11 -11.8259 0.83487E+00 -0.0784 34 CaCl+ 0.55271E-10 -10.2575 0.46145E-10 -10.3359 0.83487E+00 -0.0784 35 CaCl2,aq 0.41655E-14 -14.3803 0.41655E-14 -14.3803 0.10000E+01 0.0000 36 CaOH+ 0.82519E-07 -7.0834 0.68893E-07 -7.1618 0.83487E+00 -0.0784 37 CaSO4,aq 0.31578E-16 -16.5006 0.31578E-16 -16.5006 0.10000E+01 0.0000 38 HCl,aq 0.55751E-14 -14.2538 0.55751E-14 -14.2538 0.10000E+01 0.0000 43 FeCl+ 0.23382E-16 -16.6311 0.19521E-16 -16.7095 0.83487E+00 -0.0784 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16792E-10 -10.7749 0.14019E-10 -10.8533 0.83487E+00 -0.0784 48 HFeO2- 0.36935E-07 -7.4326 0.30775E-07 -7.5118 0.83324E+00 -0.0792 49 FeO+ 0.12394E-16 -16.9068 0.10348E-16 -16.9852 0.83487E+00 -0.0784 51 FeO2- 0.41763E-09 -9.3792 0.34799E-09 -9.4584 0.83324E+00 -0.0792 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10870E-04 -4.9638 0.99634E+00 -0.0016 54 KCl,aq 0.93441E-09 -9.0295 0.93441E-09 -9.0295 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.34149E-14 -14.4666 0.28454E-14 -14.5459 0.83324E+00 -0.0792 58 MgCO3,aq 0.34667E-13 -13.4601 0.34667E-13 -13.4601 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.28825E-15 -15.5402 0.24065E-15 -15.6186 0.83487E+00 -0.0784 60 MgCl+ 0.79303E-14 -14.1007 0.66208E-14 -14.1791 0.83487E+00 -0.0784 61 MgOH+ 0.72253E-10 -10.1411 0.60322E-10 -10.2195 0.83487E+00 -0.0784 63 MnO,aq 0.18785E-08 -8.7262 0.18785E-08 -8.7262 0.10000E+01 0.0000 64 MnOH+ 0.50183E-09 -9.2994 0.41896E-09 -9.3778 0.83487E+00 -0.0784 65 MnO2-2 0.21650E-10 -10.6646 0.11116E-10 -10.9541 0.51344E+00 -0.2895 66 HMnO2- 0.22096E-09 -9.6557 0.18411E-09 -9.7349 0.83324E+00 -0.0792 69 MnCl+ 0.29229E-13 -13.5342 0.24403E-13 -13.6126 0.83487E+00 -0.0784 71 NaCl,aq 0.21865E-05 -5.6602 0.21865E-05 -5.6602 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94340E-02 -2.0253 0.78463E-02 -2.1053 0.83170E+00 -0.0800 79 HPO3-2 0.16520E-14 -14.7820 0.84818E-15 -15.0715 0.51344E+00 -0.2895 81 H2PO3- 0.15286E-18 -18.8157 0.12737E-18 -18.8949 0.83324E+00 -0.0792 82 H3PO4,aq 0.92953E-18 -18.0317 0.92953E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39700E-10 -10.4012 0.33112E-10 -10.4800 0.83405E+00 -0.0788 84 PO4-3 0.11861E-08 -8.9259 0.28221E-09 -9.5494 0.23794E+00 -0.6235 88 HP2O7-3 0.10163E-17 -17.9930 0.23016E-18 -18.6380 0.22646E+00 -0.6450 89 P2O7-4 0.99909E-17 -17.0004 0.74272E-18 -18.1292 0.74340E-01 -1.1288 90 H2S,aq 0.16599E-07 -7.7799 0.16538E-07 -7.7815 0.99634E+00 -0.0016 91 S2-2 0.20430E-13 -13.6897 0.10489E-13 -13.9793 0.51344E+00 -0.2895 97 SO3-2 0.38593E-17 -17.4135 0.20110E-17 -17.6966 0.52108E+00 -0.2831 98 HSO3- 0.10798E-19 -19.9667 0.89970E-20 -20.0459 0.83324E+00 -0.0792 99 HSO4- 0.11517E-18 -18.9387 0.96248E-19 -19.0166 0.83571E+00 -0.0779 Charge balance for all species = -.4391E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9118093E-10 -.2295166E-01 -.2309178E+02 0.0000 2 H2O 0.1000000E+01 0.5550446E+02 0.9981088E+06 0.0000 3 Cl- 0.4652962E-03 0.4674837E-03 0.1654352E+02 6.7051 4 SO4-- 0.2636972E-11 -.4419042E-04 -.4237273E+01 8.3658 5 HCO3- 0.9507605E-06 0.4428373E-04 0.2697150E+01 4.0161 6 HS- 0.8639756E-04 0.1306046E-03 0.4311491E+01 5.9740 7 Al+++ 0.1138727E-28 0.5230750E-05 0.1408765E+00 0.7608 8 H4SiO4 0.7116642E-03 0.1410354E-01 0.1353100E+04 -3.1477 9 Ca++ 0.1462631E-06 0.2479224E-06 0.9918143E-02 13.1065 10 Mg++ 0.2322579E-10 0.9910604E-10 0.2405079E-05 9.3053 11 Fe++ 0.6353248E-13 0.3759128E-07 0.2095538E-02 6.7428 12 K+ 0.1630731E-03 0.1638503E-03 0.6395208E+01 6.2505 13 Na+ 0.2073264E-01 0.2332563E-01 0.5352753E+03 8.3540 14 Mn++ 0.2042098E-10 0.2643361E-08 0.1449565E-03 9.2503 15 HPO4-- 0.4800435E-07 0.4923015E-07 0.4716458E-02 12.6260 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1159096E+03 -.6774005E-02 -.1159028E+03 0.0000000E+00 2 H2O -.3223961E+02 0.1638171E+02 -.4862132E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1940193E+00 -.1304246E-04 0.1940324E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1939938E+00 0.3854693E-04 -.1940324E+00 0.0000000E+00 7 Al+++ 0.2282519E+02 0.1543815E-05 0.2282519E+02 0.0000000E+00 8 H4SiO4 0.7288947E+02 0.4162551E-02 0.7288531E+02 0.0000000E+00 9 Ca++ 0.8051012E+01 0.7317237E-07 0.8051012E+01 0.0000000E+00 10 Mg++ 0.5555555E+01 0.2925038E-10 0.5555555E+01 0.0000000E+00 11 Fe++ 0.4991059E+01 0.1109477E-07 0.4991059E+01 0.0000000E+00 12 K+ 0.1486199E+01 0.4835913E-04 0.1486151E+01 0.0000000E+00 13 Na+ 0.8786864E+01 0.6884380E-02 0.8779980E+01 0.0000000E+00 14 Mn++ 0.1213702E+00 0.7801674E-09 0.1213702E+00 0.0000000E+00 15 HPO4-- 0.4142303E-01 0.1452990E-07 0.4142302E-01 0.0000000E+00 Chg. balance for solid moles: 0.9839E-14 Mass of aqueous solution: 0.295681E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 6999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 8.774 0.943 2301. 3.362 30.08 883.2 andradite 0.7761 -0.110 394.4 2.596 5.157 102.5 grossular 0.1853 -0.732 83.47 1.922 1.091 23.22 apatite-OH 0.1381E-01 -1.860 6.936 0.841 0.9069E-01 2.204 clinochlore 0.9969 -0.001 554.1 2.744 7.245 210.8 daphnite 0.2857 -0.544 203.9 2.309 2.666 61.78 chlorite-Mn 0.2427E-01 -1.615 17.21 1.236 0.2250 5.484 diopside 0.3954 -0.403 85.63 1.933 1.120 26.17 hedenbergite 0.1013 -0.994 25.13 1.400 0.3286 6.884 microcline 1.301 0.114 362.2 2.559 4.736 141.5 stilbite 4.504 0.654 3174. 3.502 41.50 1480. stilpnomelane-Fe 0.3697 -0.432 398.5 2.600 5.211 137.7 tr.625ac.25prg.125 0.4847E-01 -1.315 41.43 1.617 0.5417 13.33 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7647.670248 g Volume = 3095.087413 cm3 Porosity: -10.4994% V(tot) - V(min): -.29409E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 6999.9990000 g log = 3.8451 Original solution: 1000.0103000 g Original solution / Rock added: 0.14 (Water/Rock Ratio), log = -0.8451 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1325 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9299E+00 0.9845 0.1037E+01 0.1053E+01 CO2,gas 0.1228E-07 1.0065 0.1400E-07 0.1391E-07 CH4,gas 0.5699E-01 1.0123 0.6533E-01 0.6454E-01 H2,gas 0.1316E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.4278E-06 0.9956 0.4823E-06 0.4845E-06 S2,gas 0.3462E-28 1.0000 0.3921E-28 0.3921E-28 CO,gas 0.4773E-13 1.0000 0.5406E-13 0.5406E-13 SO3,gas 0.2618E-47 1.0000 0.2965E-47 0.2965E-47 SO2,gas 0.1476E-26 1.0000 0.1672E-26 0.1672E-26 HCl,gas 0.8692E-17 1.0000 0.9844E-17 0.9844E-17 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.90992E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.72794E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.22 -9.85 -3.285 0.16825E+05 -7.854 3 CH4,gas 4.81 1.62 -3.18 -0.796 0.54381E+04 -1.185 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.26 -8.32 -4.158 0.14200E+05 -6.317 6 S2,gas -7.03 -37.44 -30.41 -4.678 0.51919E+05 -28.407 7 CO,gas 3.51 -11.76 -15.27 -4.698 0.26068E+05 -13.267 8 SO3,gas 17.43 -32.10 -49.53 -12.382 0.84568E+05 -47.528 9 SO2,gas 1.14 -27.64 -28.78 -7.674 0.49136E+05 -26.777 10 HCl,gas 5.48 -13.53 -19.01 -9.503 0.32454E+05 -17.007 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80602E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.11 -4.10 -1.366 0.69952E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.11 -3.94 -1.315 0.67339E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65549E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.30 -4.19 -1.197 0.71528E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66057E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.30 -3.75 -1.071 0.63990E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82260E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40701E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43450E+04 143 pyrrhotite -4.24 -7.52 -3.27 -1.091 0.55884E+04 144 pyrrhotiteFe0.875 -6.00 -8.91 -2.91 -1.071 0.49711E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22427E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23219E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47127E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.52 -3.12 -1.041 0.53316E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -5.01 -4.05 -1.349 0.69095E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 6999.9990000 g New total amount of reactant added: 7199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 7199.9990000 Water: Moles liquid = 0.1527E+02 kg liquid = 0.2750E+00 Moles total = -.3475E+02 kg total = -.6260E+00 Activity = 1.0000 Stoichiometric ionic strength = .1203099E-01 Osmotic coef. = 0.9675 True ionic strength = .2092041E-01 Chg. balance for total moles = -.1297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91277E-10 -10.0396 0.76524E-10 -10.1162 0.83837E+00 -0.0766 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.49929E-03 -3.3017 0.41599E-03 -3.3809 0.83318E+00 -0.0793 4 SO4-- 0.28274E-11 -11.5486 0.14545E-11 -11.8373 0.51441E+00 -0.2887 5 HCO3- 0.10194E-05 -5.9917 0.85060E-06 -6.0703 0.83443E+00 -0.0786 6 HS- 0.92709E-04 -4.0329 0.77255E-04 -4.1121 0.83330E+00 -0.0792 7 Al+++ 0.11428E-28 -28.9420 0.25836E-29 -29.5878 0.22607E+00 -0.6458 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14659E-06 -6.8339 0.74839E-07 -7.1259 0.51052E+00 -0.2920 10 Mg++ 0.23278E-10 -10.6330 0.11828E-10 -10.9271 0.50812E+00 -0.2940 11 Fe++ 0.63676E-13 -13.1960 0.32392E-13 -13.4896 0.50869E+00 -0.2935 12 K+ 0.16325E-03 -3.7872 0.13625E-03 -3.8657 0.83463E+00 -0.0785 13 Na+ 0.20755E-01 -1.6829 0.17289E-01 -1.7622 0.83302E+00 -0.0793 14 Mn++ 0.20468E-10 -10.6889 0.10421E-10 -10.9821 0.50913E+00 -0.2932 15 HPO4-- 0.47923E-07 -7.3195 0.24656E-07 -7.6081 0.51449E+00 -0.2886 16 HSiO3- 0.10890E-01 -1.9630 0.90736E-02 -2.0422 0.83318E+00 -0.0793 17 Ca(HSiO3)+ 0.18225E-07 -7.7393 0.15215E-07 -7.8177 0.83482E+00 -0.0784 18 Mg(HSiO3)+ 0.35847E-11 -11.4455 0.29926E-11 -11.5240 0.83482E+00 -0.0784 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.68227E-16 -16.1660 0.56957E-16 -16.2445 0.83482E+00 -0.0784 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52258E-05 -5.2818 0.43460E-05 -5.3619 0.83164E+00 -0.0801 24 CH4,aq 0.44496E-04 -4.3517 0.44333E-04 -4.3533 0.99633E+00 -0.0016 25 C2H6,aq 0.31297E-13 -13.5045 0.31183E-13 -13.5061 0.99633E+00 -0.0016 29 CO,aq 0.36740E-16 -16.4349 0.36740E-16 -16.4349 0.10000E+01 0.0000 30 CO2,aq 0.13172E-09 -9.8804 0.13124E-09 -9.8819 0.99633E+00 -0.0016 31 CO3-2 0.20022E-05 -5.6985 0.10277E-05 -5.9881 0.51329E+00 -0.2896 32 CaCO3,aq 0.94202E-09 -9.0259 0.94202E-09 -9.0259 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.19214E-11 -11.7164 0.16040E-11 -11.7948 0.83482E+00 -0.0784 34 CaCl+ 0.59426E-10 -10.2260 0.49610E-10 -10.3044 0.83482E+00 -0.0784 35 CaCl2,aq 0.48051E-14 -14.3183 0.48051E-14 -14.3183 0.10000E+01 0.0000 36 CaOH+ 0.82606E-07 -7.0830 0.68960E-07 -7.1614 0.83482E+00 -0.0784 37 CaSO4,aq 0.33916E-16 -16.4696 0.33916E-16 -16.4696 0.10000E+01 0.0000 38 HCl,aq 0.59878E-14 -14.2227 0.59878E-14 -14.2227 0.10000E+01 0.0000 43 FeCl+ 0.25140E-16 -16.5996 0.20987E-16 -16.6781 0.83482E+00 -0.0784 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16810E-10 -10.7744 0.14033E-10 -10.8528 0.83482E+00 -0.0784 48 HFeO2- 0.36901E-07 -7.4330 0.30745E-07 -7.5122 0.83318E+00 -0.0793 49 FeO+ 0.12407E-16 -16.9063 0.10358E-16 -16.9847 0.83482E+00 -0.0784 51 FeO2- 0.41725E-09 -9.3796 0.34764E-09 -9.4589 0.83318E+00 -0.0793 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10870E-04 -4.9638 0.99633E+00 -0.0016 54 KCl,aq 0.10036E-08 -8.9984 0.10036E-08 -8.9984 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.36644E-14 -14.4360 0.30531E-14 -14.5153 0.83318E+00 -0.0793 58 MgCO3,aq 0.37203E-13 -13.4294 0.37203E-13 -13.4294 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.30966E-15 -15.5091 0.25851E-15 -15.5875 0.83482E+00 -0.0784 60 MgCl+ 0.85264E-14 -14.0692 0.71179E-14 -14.1476 0.83482E+00 -0.0784 61 MgOH+ 0.72329E-10 -10.1407 0.60381E-10 -10.2191 0.83482E+00 -0.0784 63 MnO,aq 0.18785E-08 -8.7262 0.18785E-08 -8.7262 0.10000E+01 0.0000 64 MnOH+ 0.50237E-09 -9.2990 0.41939E-09 -9.3774 0.83482E+00 -0.0784 65 MnO2-2 0.21614E-10 -10.6653 0.11094E-10 -10.9549 0.51329E+00 -0.2896 66 HMnO2- 0.22077E-09 -9.6561 0.18394E-09 -9.7353 0.83318E+00 -0.0793 69 MnCl+ 0.31428E-13 -13.5027 0.26236E-13 -13.5811 0.83482E+00 -0.0784 71 NaCl,aq 0.23484E-05 -5.6292 0.23484E-05 -5.6292 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94254E-02 -2.0257 0.78385E-02 -2.1058 0.83164E+00 -0.0801 79 HPO3-2 0.16492E-14 -14.7827 0.84651E-15 -15.0724 0.51329E+00 -0.2896 81 H2PO3- 0.15272E-18 -18.8161 0.12725E-18 -18.8954 0.83318E+00 -0.0793 82 H3PO4,aq 0.92953E-18 -18.0317 0.92953E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39664E-10 -10.4016 0.33079E-10 -10.4804 0.83399E+00 -0.0788 84 PO4-3 0.11833E-08 -8.9269 0.28138E-09 -9.5507 0.23779E+00 -0.6238 88 HP2O7-3 0.10140E-17 -17.9940 0.22948E-18 -18.6393 0.22631E+00 -0.6453 89 P2O7-4 0.99627E-17 -17.0016 0.73980E-18 -18.1309 0.74257E-01 -1.1293 90 H2S,aq 0.17828E-07 -7.7489 0.17762E-07 -7.7505 0.99633E+00 -0.0016 91 S2-2 0.23527E-13 -13.6284 0.12076E-13 -13.9181 0.51329E+00 -0.2896 97 SO3-2 0.41380E-17 -17.3832 0.21557E-17 -17.6664 0.52094E+00 -0.2832 98 HSO3- 0.11587E-19 -19.9360 0.96536E-20 -20.0153 0.83318E+00 -0.0793 99 HSO4- 0.12358E-18 -18.9080 0.10327E-18 -18.9860 0.83565E+00 -0.0780 Charge balance for all species = -.4733E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9127688E-10 -.2293324E-01 -.2307322E+02 0.0000 2 H2O 0.1000000E+01 0.5550446E+02 0.9981078E+06 0.0000 3 Cl- 0.4992858E-03 0.5016352E-03 0.1775207E+02 6.7353 4 SO4-- 0.2827428E-11 -.4722353E-04 -.4528104E+01 8.3951 5 HCO3- 0.1019373E-05 0.4751884E-04 0.2894184E+01 4.0459 6 HS- 0.9270923E-04 0.1399506E-03 0.4620014E+01 6.0041 7 Al+++ 0.1142829E-28 0.5225979E-05 0.1407479E+00 0.7608 8 H4SiO4 0.7116644E-03 0.1409360E-01 0.1352144E+04 -3.1477 9 Ca++ 0.1465935E-06 0.2484276E-06 0.9938342E-02 13.1065 10 Mg++ 0.2327834E-10 0.9924843E-10 0.2408532E-05 9.3053 11 Fe++ 0.6367619E-13 0.3755722E-07 0.2093637E-02 6.7428 12 K+ 0.1632453E-03 0.1640225E-03 0.6401925E+01 6.2505 13 Na+ 0.2075457E-01 0.2334772E-01 0.5357816E+03 8.3540 14 Mn++ 0.2046792E-10 0.2643799E-08 0.1449804E-03 9.2503 15 HPO4-- 0.4792336E-07 0.4914633E-07 0.4708423E-02 12.6243 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1192213E+03 -.6307762E-02 -.1192150E+03 0.0000000E+00 2 H2O -.3474669E+02 0.1526644E+02 -.5001313E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.1995620E+00 -.1298878E-04 0.1995750E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.1995365E+00 0.3849325E-04 -.1995750E+00 0.0000000E+00 7 Al+++ 0.2347734E+02 0.1437399E-05 0.2347733E+02 0.0000000E+00 8 H4SiO4 0.7497203E+02 0.3876429E-02 0.7496815E+02 0.0000000E+00 9 Ca++ 0.8281040E+01 0.6832972E-07 0.8281040E+01 0.0000000E+00 10 Mg++ 0.5714285E+01 0.2729816E-10 0.5714285E+01 0.0000000E+00 11 Fe++ 0.5133661E+01 0.1033007E-07 0.5133661E+01 0.0000000E+00 12 K+ 0.1528662E+01 0.4511420E-04 0.1528617E+01 0.0000000E+00 13 Na+ 0.9037913E+01 0.6421763E-02 0.9031491E+01 0.0000000E+00 14 Mn++ 0.1248379E+00 0.7271737E-09 0.1248379E+00 0.0000000E+00 15 HPO4-- 0.4260655E-01 0.1351764E-07 0.4260653E-01 0.0000000E+00 Chg. balance for solid moles: 0.1669E-13 Mass of aqueous solution: 0.275551E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 7199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 9.025 0.955 2367. 3.374 30.09 908.5 andradite 0.7983 -0.098 405.7 2.608 5.157 105.4 grossular 0.1906 -0.720 85.85 1.934 1.091 23.89 apatite-OH 0.1420E-01 -1.848 7.134 0.853 0.9069E-01 2.267 clinochlore 1.025 0.011 569.9 2.756 7.245 216.8 daphnite 0.2939 -0.532 209.7 2.322 2.666 63.54 chlorite-Mn 0.2497E-01 -1.603 17.70 1.248 0.2250 5.641 diopside 0.4070 -0.390 88.13 1.945 1.120 26.94 hedenbergite 0.1043 -0.982 25.87 1.413 0.3289 7.085 microcline 1.338 0.127 372.6 2.571 4.736 145.5 stilbite 4.632 0.666 3265. 3.514 41.50 1523. stilpnomelane-Fe 0.3802 -0.420 409.9 2.613 5.211 141.6 tr.625ac.25prg.125 0.4983E-01 -1.303 42.59 1.629 0.5415 13.71 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1857E-01 0.1857E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 7866.181210 g Volume = 3183.500126 cm3 Porosity: -10.4998% V(tot) - V(min): -.30250E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7199.9990000 g log = 3.8573 Original solution: 1000.0103000 g Original solution / Rock added: 0.14 (Water/Rock Ratio), log = -0.8573 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1373 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9260E+00 0.9844 0.1037E+01 0.1053E+01 CO2,gas 0.1312E-07 1.0065 0.1502E-07 0.1493E-07 CH4,gas 0.6090E-01 1.0122 0.7011E-01 0.6926E-01 H2,gas 0.1310E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.4575E-06 0.9956 0.5181E-06 0.5204E-06 S2,gas 0.3977E-28 1.0000 0.4523E-28 0.4523E-28 CO,gas 0.5101E-13 1.0000 0.5801E-13 0.5801E-13 SO3,gas 0.2800E-47 1.0000 0.3184E-47 0.3184E-47 SO2,gas 0.1579E-26 1.0000 0.1796E-26 0.1796E-26 HCl,gas 0.9296E-17 1.0000 0.1057E-16 0.1057E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.34880E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.19 -9.82 -3.274 0.16773E+05 -7.823 3 CH4,gas 4.81 1.65 -3.15 -0.789 0.53858E+04 -1.154 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.23 -8.29 -4.143 0.14147E+05 -6.286 6 S2,gas -7.03 -37.38 -30.34 -4.668 0.51813E+05 -28.345 7 CO,gas 3.51 -11.73 -15.24 -4.688 0.26016E+05 -13.236 8 SO3,gas 17.43 -32.07 -49.50 -12.374 0.84515E+05 -47.497 9 SO2,gas 1.14 -27.61 -28.75 -7.666 0.49083E+05 -26.746 10 HCl,gas 5.48 -13.50 -18.98 -9.488 0.32401E+05 -16.976 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80601E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.08 -4.07 -1.355 0.69429E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.08 -3.91 -1.304 0.66815E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65549E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.27 -4.16 -1.188 0.71005E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.27 -3.72 -1.062 0.63466E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82260E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40701E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43450E+04 142 pyrite -21.23 -26.17 -4.95 -1.164 0.84498E+04 143 pyrrhotite -4.24 -7.49 -3.24 -1.081 0.55354E+04 144 pyrrhotiteFe0.875 -6.00 -8.88 -2.88 -1.059 0.49182E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22427E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23219E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47126E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.49 -3.09 -1.030 0.52786E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.98 -4.02 -1.339 0.68565E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 7199.9990000 g New total amount of reactant added: 7399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 7399.9990000 Water: Moles liquid = 0.1415E+02 kg liquid = 0.2550E+00 Moles total = -.3725E+02 kg total = -.6711E+00 Activity = 1.0000 Stoichiometric ionic strength = .1206389E-01 Osmotic coef. = 0.9674 True ionic strength = .2094617E-01 Chg. balance for total moles = -.1297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91388E-10 -10.0391 0.76611E-10 -10.1157 0.83831E+00 -0.0766 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.53863E-03 -3.2687 0.44874E-03 -3.3480 0.83311E+00 -0.0793 4 SO4-- 0.30475E-11 -11.5161 0.15672E-11 -11.8049 0.51425E+00 -0.2888 5 HCO3- 0.10987E-05 -5.9591 0.91668E-06 -6.0378 0.83436E+00 -0.0786 6 HS- 0.10002E-03 -3.9999 0.83336E-04 -4.0792 0.83323E+00 -0.0792 7 Al+++ 0.11476E-28 -28.9402 0.25925E-29 -29.5863 0.22590E+00 -0.6461 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14698E-06 -6.8328 0.75010E-07 -7.1249 0.51035E+00 -0.2921 10 Mg++ 0.23339E-10 -10.6319 0.11855E-10 -10.9261 0.50795E+00 -0.2942 11 Fe++ 0.63843E-13 -13.1949 0.32465E-13 -13.4886 0.50852E+00 -0.2937 12 K+ 0.16344E-03 -3.7866 0.13640E-03 -3.8652 0.83456E+00 -0.0785 13 Na+ 0.20780E-01 -1.6824 0.17309E-01 -1.7617 0.83295E+00 -0.0794 14 Mn++ 0.20522E-10 -10.6878 0.10445E-10 -10.9811 0.50896E+00 -0.2933 15 HPO4-- 0.47830E-07 -7.3203 0.24600E-07 -7.6091 0.51432E+00 -0.2888 16 HSiO3- 0.10879E-01 -1.9634 0.90633E-02 -2.0427 0.83311E+00 -0.0793 17 Ca(HSiO3)+ 0.18247E-07 -7.7388 0.15232E-07 -7.8172 0.83475E+00 -0.0784 18 Mg(HSiO3)+ 0.35891E-11 -11.4450 0.29960E-11 -11.5235 0.83475E+00 -0.0784 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.68310E-16 -16.1655 0.57022E-16 -16.2440 0.83475E+00 -0.0784 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52203E-05 -5.2823 0.43410E-05 -5.3624 0.83157E+00 -0.0801 24 CH4,aq 0.48008E-04 -4.3187 0.47832E-04 -4.3203 0.99633E+00 -0.0016 25 C2H6,aq 0.36432E-13 -13.4385 0.36299E-13 -13.4401 0.99633E+00 -0.0016 29 CO,aq 0.39640E-16 -16.4019 0.39640E-16 -16.4019 0.10000E+01 0.0000 30 CO2,aq 0.14212E-09 -9.8474 0.14159E-09 -9.8490 0.99633E+00 -0.0016 31 CO3-2 0.21560E-05 -5.6663 0.11063E-05 -5.9561 0.51312E+00 -0.2898 32 CaCO3,aq 0.10164E-08 -8.9930 0.10164E-08 -8.9930 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.20755E-11 -11.6829 0.17325E-11 -11.7613 0.83475E+00 -0.0784 34 CaCl+ 0.64255E-10 -10.1921 0.53637E-10 -10.2705 0.83475E+00 -0.0784 35 CaCl2,aq 0.56041E-14 -14.2515 0.56041E-14 -14.2515 0.10000E+01 0.0000 36 CaOH+ 0.82707E-07 -7.0825 0.69039E-07 -7.1609 0.83475E+00 -0.0784 37 CaSO4,aq 0.36627E-16 -16.4362 0.36627E-16 -16.4362 0.10000E+01 0.0000 38 HCl,aq 0.64665E-14 -14.1893 0.64665E-14 -14.1893 0.10000E+01 0.0000 43 FeCl+ 0.27183E-16 -16.5657 0.22691E-16 -16.6442 0.83475E+00 -0.0784 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16830E-10 -10.7739 0.14049E-10 -10.8524 0.83475E+00 -0.0784 48 HFeO2- 0.36862E-07 -7.4334 0.30710E-07 -7.5127 0.83311E+00 -0.0793 49 FeO+ 0.12423E-16 -16.9058 0.10370E-16 -16.9842 0.83475E+00 -0.0784 51 FeO2- 0.41681E-09 -9.3801 0.34725E-09 -9.4594 0.83311E+00 -0.0793 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10870E-04 -4.9638 0.99633E+00 -0.0016 54 KCl,aq 0.10838E-08 -8.9650 0.10838E-08 -8.9650 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.39532E-14 -14.4030 0.32935E-14 -14.4823 0.83311E+00 -0.0793 58 MgCO3,aq 0.40139E-13 -13.3964 0.40139E-13 -13.3964 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.33451E-15 -15.4756 0.27923E-15 -15.5540 0.83475E+00 -0.0784 60 MgCl+ 0.92193E-14 -14.0353 0.76958E-14 -14.1137 0.83475E+00 -0.0784 61 MgOH+ 0.72418E-10 -10.1402 0.60450E-10 -10.2186 0.83475E+00 -0.0784 63 MnO,aq 0.18786E-08 -8.7262 0.18786E-08 -8.7262 0.10000E+01 0.0000 64 MnOH+ 0.50301E-09 -9.2984 0.41988E-09 -9.3769 0.83475E+00 -0.0784 65 MnO2-2 0.21572E-10 -10.6661 0.11069E-10 -10.9559 0.51312E+00 -0.2898 66 HMnO2- 0.22054E-09 -9.6565 0.18374E-09 -9.7358 0.83311E+00 -0.0793 69 MnCl+ 0.33983E-13 -13.4687 0.28367E-13 -13.5472 0.83475E+00 -0.0784 71 NaCl,aq 0.25361E-05 -5.5958 0.25361E-05 -5.5958 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94155E-02 -2.0262 0.78296E-02 -2.1063 0.83157E+00 -0.0801 79 HPO3-2 0.16460E-14 -14.7836 0.84458E-15 -15.0734 0.51312E+00 -0.2898 81 H2PO3- 0.15256E-18 -18.8166 0.12710E-18 -18.8959 0.83311E+00 -0.0793 82 H3PO4,aq 0.92953E-18 -18.0317 0.92953E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39622E-10 -10.4021 0.33041E-10 -10.4809 0.83392E+00 -0.0789 84 PO4-3 0.11801E-08 -8.9281 0.28042E-09 -9.5522 0.23763E+00 -0.6241 88 HP2O7-3 0.10113E-17 -17.9951 0.22870E-18 -18.6407 0.22615E+00 -0.6456 89 P2O7-4 0.99302E-17 -17.0030 0.73643E-18 -18.1329 0.74161E-01 -1.1298 90 H2S,aq 0.19253E-07 -7.7155 0.19183E-07 -7.7171 0.99633E+00 -0.0016 91 S2-2 0.27386E-13 -13.5625 0.14052E-13 -13.8523 0.51312E+00 -0.2898 97 SO3-2 0.44601E-17 -17.3507 0.23227E-17 -17.6340 0.52077E+00 -0.2834 98 HSO3- 0.12500E-19 -19.9031 0.10414E-19 -19.9824 0.83311E+00 -0.0793 99 HSO4- 0.13332E-18 -18.8751 0.11140E-18 -18.9531 0.83559E+00 -0.0780 Charge balance for all species = -.5096E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9138806E-10 -.2291194E-01 -.2305176E+02 0.0000 2 H2O 0.1000000E+01 0.5550446E+02 0.9981067E+06 0.0000 3 Cl- 0.5386325E-03 0.5411698E-03 0.1915112E+02 6.7677 4 SO4-- 0.3047534E-11 -.5073542E-04 -.4864841E+01 8.4265 5 HCO3- 0.1098658E-05 0.5126387E-04 0.3122275E+01 4.0779 6 HS- 0.1000158E-03 0.1507704E-03 0.4977190E+01 6.0365 7 Al+++ 0.1147596E-28 0.5220465E-05 0.1405992E+00 0.7608 8 H4SiO4 0.7116646E-03 0.1408211E-01 0.1351040E+04 -3.1477 9 Ca++ 0.1469768E-06 0.2490134E-06 0.9961766E-02 13.1065 10 Mg++ 0.2333931E-10 0.9939932E-10 0.2412191E-05 9.3053 11 Fe++ 0.6384293E-13 0.3751783E-07 0.2091439E-02 6.7428 12 K+ 0.1634448E-03 0.1642221E-03 0.6409707E+01 6.2505 13 Na+ 0.2077997E-01 0.2337331E-01 0.5363682E+03 8.3540 14 Mn++ 0.2052222E-10 0.2644286E-08 0.1450069E-03 9.2503 15 HPO4-- 0.4782980E-07 0.4904951E-07 0.4699140E-02 12.6224 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1225330E+03 -.5841524E-02 -.1225271E+03 0.0000000E+00 2 H2O -.3725377E+02 0.1415116E+02 -.5140494E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2051047E+00 -.1293527E-04 0.2051176E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2050792E+00 0.3843974E-04 -.2051176E+00 0.0000000E+00 7 Al+++ 0.2412948E+02 0.1330986E-05 0.2412948E+02 0.0000000E+00 8 H4SiO4 0.7705458E+02 0.3590310E-02 0.7705099E+02 0.0000000E+00 9 Ca++ 0.8511069E+01 0.6348732E-07 0.8511069E+01 0.0000000E+00 10 Mg++ 0.5873015E+01 0.2534239E-10 0.5873015E+01 0.0000000E+00 11 Fe++ 0.5276263E+01 0.9565374E-08 0.5276263E+01 0.0000000E+00 12 K+ 0.1571125E+01 0.4186932E-04 0.1571083E+01 0.0000000E+00 13 Na+ 0.9288962E+01 0.5959153E-02 0.9283003E+01 0.0000000E+00 14 Mn++ 0.1283056E+00 0.6741750E-09 0.1283056E+00 0.0000000E+00 15 HPO4-- 0.4379006E-01 0.1250544E-07 0.4379005E-01 0.0000000E+00 Chg. balance for solid moles: -.3705E-14 Mass of aqueous solution: 0.255421E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 7399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 9.277 0.967 2433. 3.386 30.09 933.8 andradite 0.8205 -0.086 416.9 2.620 5.157 108.3 grossular 0.1959 -0.708 88.24 1.946 1.091 24.55 apatite-OH 0.1460E-01 -1.836 7.332 0.865 0.9069E-01 2.330 clinochlore 1.054 0.023 585.7 2.768 7.245 222.8 daphnite 0.3020 -0.520 215.5 2.333 2.665 65.30 chlorite-Mn 0.2566E-01 -1.591 18.19 1.260 0.2250 5.798 diopside 0.4185 -0.378 90.64 1.957 1.121 27.70 hedenbergite 0.1072 -0.970 26.60 1.425 0.3291 7.287 microcline 1.376 0.139 382.9 2.583 4.736 149.6 stilbite 4.761 0.678 3355. 3.526 41.50 1565. stilpnomelane-Fe 0.3908 -0.408 421.3 2.625 5.211 145.5 tr.625ac.25prg.125 0.5119E-01 -1.291 43.76 1.641 0.5412 14.08 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8084.692170 g Volume = 3271.912838 cm3 Porosity: -10.5003% V(tot) - V(min): -.31091E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7399.9990000 g log = 3.8692 Original solution: 1000.0103000 g Original solution / Rock added: 0.14 (Water/Rock Ratio), log = -0.8692 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1428 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9216E+00 0.9843 0.1037E+01 0.1053E+01 CO2,gas 0.1409E-07 1.0064 0.1621E-07 0.1610E-07 CH4,gas 0.6539E-01 1.0121 0.7564E-01 0.7473E-01 H2,gas 0.1304E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.4917E-06 0.9956 0.5595E-06 0.5620E-06 S2,gas 0.4615E-28 1.0000 0.5275E-28 0.5275E-28 CO,gas 0.5477E-13 1.0000 0.6259E-13 0.6259E-13 SO3,gas 0.3009E-47 1.0000 0.3439E-47 0.3439E-47 SO2,gas 0.1697E-26 1.0000 0.1939E-26 0.1939E-26 HCl,gas 0.9991E-17 1.0000 0.1142E-16 0.1142E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.18198E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.48529E-10 47 daphnite 29.09 29.09 0.00 0.000 0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.36397E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.15 -9.79 -3.263 0.16717E+05 -7.790 3 CH4,gas 4.81 1.69 -3.12 -0.780 0.53294E+04 -1.121 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.19 -8.25 -4.126 0.14090E+05 -6.252 6 S2,gas -7.03 -37.31 -30.28 -4.658 0.51699E+05 -28.278 7 CO,gas 3.51 -11.69 -15.20 -4.678 0.25960E+05 -13.203 8 SO3,gas 17.43 -32.04 -49.46 -12.366 0.84458E+05 -47.464 9 SO2,gas 1.14 -27.58 -28.71 -7.657 0.49026E+05 -26.712 10 HCl,gas 5.48 -13.46 -18.94 -9.471 0.32344E+05 -16.942 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80600E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.05 -4.03 -1.344 0.68865E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.05 -3.88 -1.293 0.66252E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65549E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.23 -4.13 -1.179 0.70441E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.23 -3.68 -1.053 0.62903E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82260E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40701E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43450E+04 142 pyrite -21.23 -26.11 -4.88 -1.149 0.83357E+04 143 pyrrhotite -4.24 -7.45 -3.21 -1.069 0.54784E+04 144 pyrrhotiteFe0.875 -6.00 -8.85 -2.85 -1.047 0.48611E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22427E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23219E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47126E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.45 -3.06 -1.019 0.52216E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.94 -3.98 -1.327 0.67994E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 7399.9990000 g New total amount of reactant added: 7599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1297E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 7599.9990000 Water: Moles liquid = 0.1304E+02 kg liquid = 0.2349E+00 Moles total = -.3976E+02 kg total = -.7163E+00 Activity = 1.0000 Stoichiometric ionic strength = .1210243E-01 Osmotic coef. = 0.9674 True ionic strength = .2097637E-01 Chg. balance for total moles = -.1297E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91518E-10 -10.0385 0.76713E-10 -10.1151 0.83823E+00 -0.0766 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.58471E-03 -3.2331 0.48708E-03 -3.3124 0.83303E+00 -0.0793 4 SO4-- 0.33048E-11 -11.4809 0.16988E-11 -11.7698 0.51405E+00 -0.2890 5 HCO3- 0.11913E-05 -5.9240 0.99389E-06 -6.0027 0.83428E+00 -0.0787 6 HS- 0.10857E-03 -3.9643 0.90457E-04 -4.0436 0.83315E+00 -0.0793 7 Al+++ 0.11532E-28 -28.9381 0.26029E-29 -29.5846 0.22571E+00 -0.6465 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14743E-06 -6.8314 0.75210E-07 -7.1237 0.51015E+00 -0.2923 10 Mg++ 0.23411E-10 -10.6306 0.11887E-10 -10.9249 0.50775E+00 -0.2944 11 Fe++ 0.64039E-13 -13.1936 0.32552E-13 -13.4874 0.50832E+00 -0.2939 12 K+ 0.16368E-03 -3.7860 0.13659E-03 -3.8646 0.83448E+00 -0.0786 13 Na+ 0.20810E-01 -1.6817 0.17332E-01 -1.7612 0.83287E+00 -0.0794 14 Mn++ 0.20586E-10 -10.6864 0.10473E-10 -10.9799 0.50876E+00 -0.2935 15 HPO4-- 0.47720E-07 -7.3213 0.24534E-07 -7.6102 0.51413E+00 -0.2889 16 HSiO3- 0.10865E-01 -1.9640 0.90512E-02 -2.0433 0.83303E+00 -0.0793 17 Ca(HSiO3)+ 0.18273E-07 -7.7382 0.15252E-07 -7.8167 0.83467E+00 -0.0785 18 Mg(HSiO3)+ 0.35943E-11 -11.4444 0.30000E-11 -11.5229 0.83467E+00 -0.0785 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.68408E-16 -16.1649 0.57098E-16 -16.2434 0.83467E+00 -0.0785 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52139E-05 -5.2828 0.43352E-05 -5.3630 0.83148E+00 -0.0801 24 CH4,aq 0.52122E-04 -4.2830 0.51930E-04 -4.2846 0.99631E+00 -0.0016 25 C2H6,aq 0.42943E-13 -13.3671 0.42785E-13 -13.3687 0.99631E+00 -0.0016 29 CO,aq 0.43036E-16 -16.3662 0.43036E-16 -16.3662 0.10000E+01 0.0000 30 CO2,aq 0.15429E-09 -9.8117 0.15372E-09 -9.8133 0.99631E+00 -0.0016 31 CO3-2 0.23354E-05 -5.6316 0.11979E-05 -5.9216 0.51293E+00 -0.2899 32 CaCO3,aq 0.11034E-08 -8.9573 0.11034E-08 -8.9573 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.22566E-11 -11.6465 0.18835E-11 -11.7250 0.83467E+00 -0.0785 34 CaCl+ 0.69938E-10 -10.1553 0.58375E-10 -10.2338 0.83467E+00 -0.0785 35 CaCl2,aq 0.66203E-14 -14.1791 0.66203E-14 -14.1791 0.10000E+01 0.0000 36 CaOH+ 0.82825E-07 -7.0818 0.69131E-07 -7.1603 0.83467E+00 -0.0785 37 CaSO4,aq 0.39810E-16 -16.4000 0.39810E-16 -16.4000 0.10000E+01 0.0000 38 HCl,aq 0.70283E-14 -14.1531 0.70283E-14 -14.1531 0.10000E+01 0.0000 43 FeCl+ 0.29587E-16 -16.5289 0.24695E-16 -16.6074 0.83467E+00 -0.0785 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16854E-10 -10.7733 0.14068E-10 -10.8518 0.83467E+00 -0.0785 48 HFeO2- 0.36816E-07 -7.4340 0.30669E-07 -7.5133 0.83303E+00 -0.0793 49 FeO+ 0.12440E-16 -16.9052 0.10384E-16 -16.9837 0.83467E+00 -0.0785 51 FeO2- 0.41629E-09 -9.3806 0.34678E-09 -9.4599 0.83303E+00 -0.0793 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10870E-04 -4.9638 0.99631E+00 -0.0016 54 KCl,aq 0.11780E-08 -8.9289 0.11780E-08 -8.9289 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.42914E-14 -14.3674 0.35749E-14 -14.4467 0.83303E+00 -0.0793 58 MgCO3,aq 0.43578E-13 -13.3607 0.43578E-13 -13.3607 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.36369E-15 -15.4393 0.30356E-15 -15.5178 0.83467E+00 -0.0785 60 MgCl+ 0.10035E-13 -13.9985 0.83756E-14 -14.0770 0.83467E+00 -0.0785 61 MgOH+ 0.72521E-10 -10.1395 0.60531E-10 -10.2180 0.83467E+00 -0.0785 63 MnO,aq 0.18787E-08 -8.7261 0.18787E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.50374E-09 -9.2978 0.42046E-09 -9.3763 0.83467E+00 -0.0785 65 MnO2-2 0.21524E-10 -10.6671 0.11040E-10 -10.9570 0.51293E+00 -0.2899 66 HMnO2- 0.22028E-09 -9.6570 0.18350E-09 -9.7364 0.83303E+00 -0.0793 69 MnCl+ 0.36990E-13 -13.4319 0.30874E-13 -13.5104 0.83467E+00 -0.0785 71 NaCl,aq 0.27565E-05 -5.5596 0.27565E-05 -5.5596 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.94039E-02 -2.0267 0.78192E-02 -2.1068 0.83148E+00 -0.0801 79 HPO3-2 0.16422E-14 -14.7846 0.84233E-15 -15.0745 0.51293E+00 -0.2899 81 H2PO3- 0.15237E-18 -18.8171 0.12693E-18 -18.8964 0.83303E+00 -0.0793 82 H3PO4,aq 0.92953E-18 -18.0317 0.92953E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39573E-10 -10.4026 0.32997E-10 -10.4815 0.83384E+00 -0.0789 84 PO4-3 0.11763E-08 -8.9295 0.27930E-09 -9.5539 0.23743E+00 -0.6245 88 HP2O7-3 0.10081E-17 -17.9965 0.22778E-18 -18.6425 0.22595E+00 -0.6460 89 P2O7-4 0.98924E-17 -17.0047 0.73251E-18 -18.1352 0.74049E-01 -1.1305 90 H2S,aq 0.20927E-07 -7.6793 0.20850E-07 -7.6809 0.99631E+00 -0.0016 91 S2-2 0.32278E-13 -13.4911 0.16556E-13 -13.7810 0.51293E+00 -0.2899 97 SO3-2 0.48365E-17 -17.3155 0.25178E-17 -17.5990 0.52058E+00 -0.2835 98 HSO3- 0.13569E-19 -19.8674 0.11303E-19 -19.9468 0.83303E+00 -0.0793 99 HSO4- 0.14473E-18 -18.8394 0.12092E-18 -18.9175 0.83551E+00 -0.0780 Charge balance for all species = -.5531E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9151841E-10 -.2288704E-01 -.2302667E+02 0.0000 2 H2O 0.1000000E+01 0.5550447E+02 0.9981053E+06 0.0000 3 Cl- 0.5847114E-03 0.5874692E-03 0.2078954E+02 6.8027 4 SO4-- 0.3304796E-11 -.5484915E-04 -.5259284E+01 8.4604 5 HCO3- 0.1191314E-05 0.5564970E-04 0.3389394E+01 4.1125 6 HS- 0.1085725E-03 0.1634426E-03 0.5395511E+01 6.0716 7 Al+++ 0.1153203E-28 0.5214018E-05 0.1404254E+00 0.7608 8 H4SiO4 0.7116648E-03 0.1406867E-01 0.1349749E+04 -3.1477 9 Ca++ 0.1474269E-06 0.2497009E-06 0.9989255E-02 13.1065 10 Mg++ 0.2341091E-10 0.9957981E-10 0.2416567E-05 9.3053 11 Fe++ 0.6403873E-13 0.3747177E-07 0.2088868E-02 6.7428 12 K+ 0.1636787E-03 0.1644561E-03 0.6418831E+01 6.2505 13 Na+ 0.2080976E-01 0.2340332E-01 0.5370560E+03 8.3540 14 Mn++ 0.2058582E-10 0.2644837E-08 0.1450370E-03 9.2503 15 HPO4-- 0.4772048E-07 0.4893639E-07 0.4688296E-02 12.6200 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1258447E+03 -.5375295E-02 -.1258393E+03 0.0000000E+00 2 H2O -.3976086E+02 0.1303589E+02 -.5279675E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2106474E+00 -.1288198E-04 0.2106603E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2106219E+00 0.3838645E-04 -.2106603E+00 0.0000000E+00 7 Al+++ 0.2478163E+02 0.1224575E-05 0.2478163E+02 0.0000000E+00 8 H4SiO4 0.7913714E+02 0.3304196E-02 0.7913384E+02 0.0000000E+00 9 Ca++ 0.8741097E+01 0.5864526E-07 0.8741097E+01 0.0000000E+00 10 Mg++ 0.6031745E+01 0.2338751E-10 0.6031745E+01 0.0000000E+00 11 Fe++ 0.5418865E+01 0.8800695E-08 0.5418865E+01 0.0000000E+00 12 K+ 0.1613588E+01 0.3862449E-04 0.1613549E+01 0.0000000E+00 13 Na+ 0.9540010E+01 0.5496550E-02 0.9534514E+01 0.0000000E+00 14 Mn++ 0.1317733E+00 0.6211718E-09 0.1317733E+00 0.0000000E+00 15 HPO4-- 0.4497358E-01 0.1149330E-07 0.4497356E-01 0.0000000E+00 Chg. balance for solid moles: 0.4774E-14 Mass of aqueous solution: 0.235291E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 7599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 9.528 0.979 2498. 3.398 30.09 959.1 andradite 0.8426 -0.074 428.2 2.632 5.157 111.3 grossular 0.2012 -0.696 90.62 1.957 1.091 25.21 apatite-OH 0.1499E-01 -1.824 7.530 0.877 0.9069E-01 2.393 clinochlore 1.082 0.034 601.5 2.779 7.245 228.8 daphnite 0.3102 -0.508 221.3 2.345 2.665 67.06 chlorite-Mn 0.2635E-01 -1.579 18.68 1.271 0.2250 5.954 diopside 0.4301 -0.366 93.15 1.969 1.122 28.47 hedenbergite 0.1102 -0.958 27.34 1.437 0.3293 7.488 microcline 1.413 0.150 393.3 2.595 4.736 153.6 stilbite 4.889 0.689 3446. 3.537 41.50 1607. stilpnomelane-Fe 0.4014 -0.396 432.7 2.636 5.211 149.5 tr.625ac.25prg.125 0.5256E-01 -1.279 44.92 1.652 0.5410 14.46 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8303.203130 g Volume = 3360.325550 cm3 Porosity: -10.5007% V(tot) - V(min): -.31933E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7599.9990000 g log = 3.8808 Original solution: 1000.0103000 g Original solution / Rock added: 0.13 (Water/Rock Ratio), log = -0.8808 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1493 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9164E+00 0.9843 0.1037E+01 0.1053E+01 CO2,gas 0.1521E-07 1.0063 0.1760E-07 0.1749E-07 CH4,gas 0.7060E-01 1.0121 0.8212E-01 0.8114E-01 H2,gas 0.1296E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.5315E-06 0.9955 0.6081E-06 0.6108E-06 S2,gas 0.5422E-28 1.0000 0.6231E-28 0.6231E-28 CO,gas 0.5913E-13 1.0000 0.6795E-13 0.6795E-13 SO3,gas 0.3252E-47 1.0000 0.3738E-47 0.3738E-47 SO2,gas 0.1834E-26 1.0000 0.2108E-26 0.2108E-26 HCl,gas 0.1080E-16 1.0000 0.1241E-16 0.1241E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.24265E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.12 -9.75 -3.252 0.16656E+05 -7.755 3 CH4,gas 4.81 1.72 -3.09 -0.771 0.52685E+04 -1.086 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.16 -8.22 -4.108 0.14029E+05 -6.216 6 S2,gas -7.03 -37.24 -30.21 -4.647 0.51575E+05 -28.205 7 CO,gas 3.51 -11.66 -15.17 -4.667 0.25899E+05 -13.168 8 SO3,gas 17.43 -32.00 -49.43 -12.357 0.84396E+05 -47.427 9 SO2,gas 1.14 -27.54 -28.68 -7.647 0.48964E+05 -26.676 10 HCl,gas 5.48 -13.43 -18.91 -9.453 0.32282E+05 -16.906 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80599E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -3.01 -4.00 -1.332 0.68256E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -3.01 -3.84 -1.281 0.65642E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65549E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.20 -4.09 -1.169 0.69832E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.20 -3.65 -1.042 0.62294E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82259E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40701E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -26.03 -4.81 -1.132 0.82122E+04 143 pyrrhotite -4.24 -7.42 -3.17 -1.057 0.54166E+04 144 pyrrhotiteFe0.875 -6.00 -8.81 -2.81 -1.034 0.47993E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22426E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23219E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47125E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.42 -3.02 -1.007 0.51598E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.91 -3.95 -1.315 0.67376E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 7599.9990000 g New total amount of reactant added: 7799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1298E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 7799.9990000 Water: Moles liquid = 0.1192E+02 kg liquid = 0.2148E+00 Moles total = -.4227E+02 kg total = -.7615E+00 Activity = 1.0000 Stoichiometric ionic strength = .1214821E-01 Osmotic coef. = 0.9673 True ionic strength = .2101226E-01 Chg. balance for total moles = -.1298E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91673E-10 -10.0378 0.76835E-10 -10.1144 0.83814E+00 -0.0767 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.63941E-03 -3.1942 0.53258E-03 -3.2736 0.83293E+00 -0.0794 4 SO4-- 0.36095E-11 -11.4426 0.18546E-11 -11.7317 0.51382E+00 -0.2892 5 HCO3- 0.13010E-05 -5.8857 0.10853E-05 -5.9644 0.83419E+00 -0.0787 6 HS- 0.11873E-03 -3.9254 0.98909E-04 -4.0048 0.83306E+00 -0.0793 7 Al+++ 0.11599E-28 -28.9356 0.26152E-29 -29.5825 0.22547E+00 -0.6469 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14796E-06 -6.8298 0.75449E-07 -7.1223 0.50992E+00 -0.2925 10 Mg++ 0.23496E-10 -10.6290 0.11925E-10 -10.9236 0.50751E+00 -0.2946 11 Fe++ 0.64272E-13 -13.1920 0.32656E-13 -13.4860 0.50808E+00 -0.2941 12 K+ 0.16396E-03 -3.7853 0.13680E-03 -3.8639 0.83439E+00 -0.0786 13 Na+ 0.20845E-01 -1.6810 0.17359E-01 -1.7605 0.83277E+00 -0.0795 14 Mn++ 0.20661E-10 -10.6848 0.10507E-10 -10.9785 0.50852E+00 -0.2937 15 HPO4-- 0.47591E-07 -7.3225 0.24457E-07 -7.6116 0.51390E+00 -0.2891 16 HSiO3- 0.10850E-01 -1.9646 0.90369E-02 -2.0440 0.83293E+00 -0.0794 17 Ca(HSiO3)+ 0.18305E-07 -7.7374 0.15276E-07 -7.8160 0.83457E+00 -0.0785 18 Mg(HSiO3)+ 0.36004E-11 -11.4437 0.30048E-11 -11.5222 0.83457E+00 -0.0785 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.68524E-16 -16.1642 0.57188E-16 -16.2427 0.83457E+00 -0.0785 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.52062E-05 -5.2835 0.43284E-05 -5.3637 0.83138E+00 -0.0802 24 CH4,aq 0.57006E-04 -4.2441 0.56796E-04 -4.2457 0.99630E+00 -0.0016 25 C2H6,aq 0.51369E-13 -13.2893 0.51179E-13 -13.2909 0.99630E+00 -0.0016 29 CO,aq 0.47069E-16 -16.3273 0.47069E-16 -16.3273 0.10000E+01 0.0000 30 CO2,aq 0.16875E-09 -9.7727 0.16813E-09 -9.7744 0.99630E+00 -0.0016 31 CO3-2 0.25473E-05 -5.5939 0.13060E-05 -5.8841 0.51269E+00 -0.2901 32 CaCO3,aq 0.12068E-08 -8.9184 0.12068E-08 -8.9184 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.24722E-11 -11.6069 0.20633E-11 -11.6854 0.83457E+00 -0.0785 34 CaCl+ 0.76723E-10 -10.1151 0.64031E-10 -10.1936 0.83457E+00 -0.0785 35 CaCl2,aq 0.79402E-14 -14.1002 0.79402E-14 -14.1002 0.10000E+01 0.0000 36 CaOH+ 0.82966E-07 -7.0811 0.69241E-07 -7.1596 0.83457E+00 -0.0785 37 CaSO4,aq 0.43599E-16 -16.3605 0.43599E-16 -16.3605 0.10000E+01 0.0000 38 HCl,aq 0.76971E-14 -14.1137 0.76971E-14 -14.1137 0.10000E+01 0.0000 43 FeCl+ 0.32457E-16 -16.4887 0.27088E-16 -16.5672 0.83457E+00 -0.0785 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16883E-10 -10.7726 0.14090E-10 -10.8511 0.83457E+00 -0.0785 48 HFeO2- 0.36762E-07 -7.4346 0.30621E-07 -7.5140 0.83293E+00 -0.0794 49 FeO+ 0.12462E-16 -16.9044 0.10400E-16 -16.9830 0.83457E+00 -0.0785 51 FeO2- 0.41568E-09 -9.3812 0.34624E-09 -9.4606 0.83293E+00 -0.0794 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10870E-04 -4.9638 0.99630E+00 -0.0016 54 KCl,aq 0.12901E-08 -8.8894 0.12901E-08 -8.8894 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.46930E-14 -14.3286 0.39089E-14 -14.4079 0.83293E+00 -0.0794 58 MgCO3,aq 0.47662E-13 -13.3218 0.47662E-13 -13.3218 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.39844E-15 -15.3996 0.33253E-15 -15.4782 0.83457E+00 -0.0785 60 MgCl+ 0.11008E-13 -13.9583 0.91872E-14 -14.0368 0.83457E+00 -0.0785 61 MgOH+ 0.72644E-10 -10.1388 0.60627E-10 -10.2173 0.83457E+00 -0.0785 63 MnO,aq 0.18787E-08 -8.7261 0.18787E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.50461E-09 -9.2970 0.42114E-09 -9.3756 0.83457E+00 -0.0785 65 MnO2-2 0.21466E-10 -10.6682 0.11006E-10 -10.9584 0.51269E+00 -0.2901 66 HMnO2- 0.21996E-09 -9.6577 0.18321E-09 -9.7370 0.83293E+00 -0.0794 69 MnCl+ 0.40580E-13 -13.3917 0.33867E-13 -13.4702 0.83457E+00 -0.0785 71 NaCl,aq 0.30188E-05 -5.5202 0.30188E-05 -5.5202 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.93901E-02 -2.0273 0.78068E-02 -2.1075 0.83138E+00 -0.0802 79 HPO3-2 0.16378E-14 -14.7858 0.83967E-15 -15.0759 0.51269E+00 -0.2901 81 H2PO3- 0.15215E-18 -18.8177 0.12673E-18 -18.8971 0.83293E+00 -0.0794 82 H3PO4,aq 0.92953E-18 -18.0317 0.92953E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39515E-10 -10.4032 0.32945E-10 -10.4822 0.83374E+00 -0.0790 84 PO4-3 0.11719E-08 -8.9311 0.27798E-09 -9.5560 0.23720E+00 -0.6249 88 HP2O7-3 0.10044E-17 -17.9981 0.22670E-18 -18.6445 0.22572E+00 -0.6464 89 P2O7-4 0.98476E-17 -17.0067 0.72789E-18 -18.1379 0.73915E-01 -1.1313 90 H2S,aq 0.22918E-07 -7.6398 0.22834E-07 -7.6414 0.99630E+00 -0.0016 91 S2-2 0.38609E-13 -13.4133 0.19795E-13 -13.7035 0.51269E+00 -0.2901 97 SO3-2 0.52824E-17 -17.2772 0.27487E-17 -17.5609 0.52036E+00 -0.2837 98 HSO3- 0.14839E-19 -19.8286 0.12360E-19 -19.9080 0.83293E+00 -0.0794 99 HSO4- 0.15827E-18 -18.8006 0.13222E-18 -18.8787 0.83541E+00 -0.0781 Charge balance for all species = -.6064E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9167335E-10 -.2285752E-01 -.2299693E+02 0.0000 2 H2O 0.1000000E+01 0.5550448E+02 0.9981037E+06 0.0000 3 Cl- 0.6394117E-03 0.6424319E-03 0.2273454E+02 6.8408 4 SO4-- 0.3609490E-11 -.5973392E-04 -.5727657E+01 8.4971 5 HCO3- 0.1301034E-05 0.6085620E-04 0.3706494E+01 4.1500 6 HS- 0.1187303E-03 0.1784872E-03 0.5892148E+01 6.1097 7 Al+++ 0.1159893E-28 0.5206379E-05 0.1402194E+00 0.7608 8 H4SiO4 0.7116650E-03 0.1405274E-01 0.1348218E+04 -3.1477 9 Ca++ 0.1479629E-06 0.2505190E-06 0.1002196E-01 13.1065 10 Mg++ 0.2349617E-10 0.9981062E-10 0.2422164E-05 9.3053 11 Fe++ 0.6427188E-13 0.3741719E-07 0.2085821E-02 6.7428 12 K+ 0.1639568E-03 0.1647343E-03 0.6429676E+01 6.2505 13 Na+ 0.2084516E-01 0.2343899E-01 0.5378735E+03 8.3540 14 Mn++ 0.2066140E-10 0.2645473E-08 0.1450716E-03 9.2503 15 HPO4-- 0.4759107E-07 0.4880248E-07 0.4675459E-02 12.6173 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1291564E+03 -.4909076E-02 -.1291515E+03 0.0000000E+00 2 H2O -.4226794E+02 0.1192062E+02 -.5418856E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2161901E+00 -.1282897E-04 0.2162029E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2161646E+00 0.3833344E-04 -.2162029E+00 0.0000000E+00 7 Al+++ 0.2543378E+02 0.1118167E-05 0.2543378E+02 0.0000000E+00 8 H4SiO4 0.8121970E+02 0.3018086E-02 0.8121668E+02 0.0000000E+00 9 Ca++ 0.8971126E+01 0.5380361E-07 0.8971126E+01 0.0000000E+00 10 Mg++ 0.6190475E+01 0.2143619E-10 0.6190475E+01 0.0000000E+00 11 Fe++ 0.5561466E+01 0.8036036E-08 0.5561466E+01 0.0000000E+00 12 K+ 0.1656051E+01 0.3537975E-04 0.1656015E+01 0.0000000E+00 13 Na+ 0.9791059E+01 0.5033958E-02 0.9786025E+01 0.0000000E+00 14 Mn++ 0.1352410E+00 0.5681646E-09 0.1352410E+00 0.0000000E+00 15 HPO4-- 0.4615709E-01 0.1048124E-07 0.4615708E-01 0.0000000E+00 Chg. balance for solid moles: 0.3500E-13 Mass of aqueous solution: 0.215162E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 7799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 9.779 0.990 2564. 3.409 30.09 984.4 andradite 0.8648 -0.063 439.5 2.643 5.157 114.2 grossular 0.2065 -0.685 93.01 1.969 1.091 25.88 apatite-OH 0.1539E-01 -1.813 7.729 0.888 0.9069E-01 2.456 clinochlore 1.111 0.046 617.3 2.791 7.244 234.8 daphnite 0.3183 -0.497 227.1 2.356 2.665 68.83 chlorite-Mn 0.2705E-01 -1.568 19.18 1.283 0.2250 6.111 diopside 0.4417 -0.355 95.65 1.981 1.122 29.23 hedenbergite 0.1132 -0.946 28.07 1.448 0.3294 7.689 microcline 1.450 0.161 403.6 2.606 4.736 157.7 stilbite 5.018 0.701 3536. 3.549 41.49 1649. stilpnomelane-Fe 0.4119 -0.385 444.1 2.647 5.211 153.4 tr.625ac.25prg.125 0.5392E-01 -1.268 46.09 1.664 0.5408 14.83 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8521.714089 g Volume = 3448.738261 cm3 Porosity: -10.5011% V(tot) - V(min): -.32774E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7799.9990000 g log = 3.8921 Original solution: 1000.0103000 g Original solution / Rock added: 0.13 (Water/Rock Ratio), log = -0.8921 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1570 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9104E+00 0.9842 0.1037E+01 0.1053E+01 CO2,gas 0.1653E-07 1.0062 0.1925E-07 0.1913E-07 CH4,gas 0.7671E-01 1.0120 0.8982E-01 0.8875E-01 H2,gas 0.1288E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.5782E-06 0.9955 0.6660E-06 0.6690E-06 S2,gas 0.6459E-28 1.0000 0.7474E-28 0.7474E-28 CO,gas 0.6424E-13 1.0000 0.7432E-13 0.7432E-13 SO3,gas 0.3538E-47 1.0000 0.4093E-47 0.4093E-47 SO2,gas 0.1995E-26 1.0000 0.2309E-26 0.2309E-26 HCl,gas 0.1175E-16 1.0000 0.1359E-16 0.1359E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 0.18957E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.37914E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.08 -9.72 -3.239 0.16589E+05 -7.716 3 CH4,gas 4.81 1.76 -3.05 -0.762 0.52021E+04 -1.047 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.12 -8.18 -4.088 0.13961E+05 -6.177 6 S2,gas -7.03 -37.16 -30.13 -4.635 0.51440E+05 -28.126 7 CO,gas 3.51 -11.62 -15.13 -4.655 0.25832E+05 -13.129 8 SO3,gas 17.43 -31.96 -49.39 -12.347 0.84329E+05 -47.388 9 SO2,gas 1.14 -27.50 -28.64 -7.636 0.48896E+05 -26.637 10 HCl,gas 5.48 -13.39 -18.87 -9.433 0.32214E+05 -16.867 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80599E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.97 -3.96 -1.320 0.67592E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.97 -3.81 -1.269 0.64978E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65548E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.16 -4.05 -1.157 0.69168E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.16 -3.61 -1.031 0.61629E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82259E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.96 -4.73 -1.113 0.80773E+04 143 pyrrhotite -4.24 -7.38 -3.13 -1.044 0.53492E+04 144 pyrrhotiteFe0.875 -6.00 -8.77 -2.77 -1.019 0.47319E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22426E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23218E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47125E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.38 -2.98 -0.994 0.50924E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.87 -3.91 -1.302 0.66702E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 7799.9990000 g New total amount of reactant added: 7999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = -.1299E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 7999.9990000 Water: Moles liquid = 0.1081E+02 kg liquid = 0.1947E+00 Moles total = -.4478E+02 kg total = -.8066E+00 Activity = 1.0000 Stoichiometric ionic strength = .1220347E-01 Osmotic coef. = 0.9672 True ionic strength = .2105563E-01 Chg. balance for total moles = -.1299E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91861E-10 -10.0369 0.76982E-10 -10.1136 0.83803E+00 -0.0767 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.70540E-03 -3.1516 0.58747E-03 -3.2310 0.83281E+00 -0.0795 4 SO4-- 0.39761E-11 -11.4005 0.20419E-11 -11.6900 0.51354E+00 -0.2894 5 HCO3- 0.14330E-05 -5.8438 0.11952E-05 -5.9225 0.83407E+00 -0.0788 6 HS- 0.13099E-03 -3.8828 0.10910E-03 -3.9622 0.83294E+00 -0.0794 7 Al+++ 0.11680E-28 -28.9326 0.26303E-29 -29.5800 0.22519E+00 -0.6474 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14861E-06 -6.8279 0.75738E-07 -7.1207 0.50963E+00 -0.2927 10 Mg++ 0.23599E-10 -10.6271 0.11970E-10 -10.9219 0.50722E+00 -0.2948 11 Fe++ 0.64554E-13 -13.1901 0.32780E-13 -13.4844 0.50780E+00 -0.2943 12 K+ 0.16429E-03 -3.7844 0.13707E-03 -3.8631 0.83427E+00 -0.0787 13 Na+ 0.20888E-01 -1.6801 0.17392E-01 -1.7596 0.83265E+00 -0.0795 14 Mn++ 0.20753E-10 -10.6829 0.10547E-10 -10.9769 0.50823E+00 -0.2939 15 HPO4-- 0.47435E-07 -7.3239 0.24364E-07 -7.6133 0.51362E+00 -0.2894 16 HSiO3- 0.10830E-01 -1.9654 0.90196E-02 -2.0448 0.83281E+00 -0.0795 17 Ca(HSiO3)+ 0.18342E-07 -7.7366 0.15306E-07 -7.8151 0.83446E+00 -0.0786 18 Mg(HSiO3)+ 0.36077E-11 -11.4428 0.30105E-11 -11.5214 0.83446E+00 -0.0786 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.68665E-16 -16.1633 0.57298E-16 -16.2419 0.83446E+00 -0.0786 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51970E-05 -5.2842 0.43201E-05 -5.3645 0.83127E+00 -0.0803 24 CH4,aq 0.62901E-04 -4.2013 0.62668E-04 -4.2030 0.99628E+00 -0.0016 25 C2H6,aq 0.62541E-13 -13.2038 0.62309E-13 -13.2055 0.99628E+00 -0.0016 29 CO,aq 0.51935E-16 -16.2845 0.51935E-16 -16.2845 0.10000E+01 0.0000 30 CO2,aq 0.18621E-09 -9.7300 0.18551E-09 -9.7316 0.99628E+00 -0.0016 31 CO3-2 0.28015E-05 -5.5526 0.14355E-05 -5.8430 0.51241E+00 -0.2904 32 CaCO3,aq 0.13316E-08 -8.8756 0.13316E-08 -8.8756 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.27334E-11 -11.5633 0.22809E-11 -11.6419 0.83446E+00 -0.0786 34 CaCl+ 0.84965E-10 -10.0708 0.70900E-10 -10.1494 0.83446E+00 -0.0786 35 CaCl2,aq 0.96980E-14 -14.0133 0.96980E-14 -14.0133 0.10000E+01 0.0000 36 CaOH+ 0.83136E-07 -7.0802 0.69373E-07 -7.1588 0.83446E+00 -0.0786 37 CaSO4,aq 0.48184E-16 -16.3171 0.48184E-16 -16.3171 0.10000E+01 0.0000 38 HCl,aq 0.85066E-14 -14.0702 0.85066E-14 -14.0702 0.10000E+01 0.0000 43 FeCl+ 0.35944E-16 -16.4444 0.29994E-16 -16.5230 0.83446E+00 -0.0786 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16918E-10 -10.7717 0.14117E-10 -10.8503 0.83446E+00 -0.0786 48 HFeO2- 0.36697E-07 -7.4354 0.30562E-07 -7.5148 0.83281E+00 -0.0795 49 FeO+ 0.12487E-16 -16.9035 0.10420E-16 -16.9821 0.83446E+00 -0.0786 51 FeO2- 0.41495E-09 -9.3820 0.34557E-09 -9.4615 0.83281E+00 -0.0795 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10870E-04 -4.9638 0.99628E+00 -0.0016 54 KCl,aq 0.14258E-08 -8.8460 0.14258E-08 -8.8460 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.51774E-14 -14.2859 0.43118E-14 -14.3653 0.83281E+00 -0.0795 58 MgCO3,aq 0.52589E-13 -13.2791 0.52589E-13 -13.2791 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.44054E-15 -15.3560 0.36761E-15 -15.4346 0.83446E+00 -0.0786 60 MgCl+ 0.12191E-13 -13.9140 0.10173E-13 -13.9926 0.83446E+00 -0.0786 61 MgOH+ 0.72793E-10 -10.1379 0.60743E-10 -10.2165 0.83446E+00 -0.0786 63 MnO,aq 0.18788E-08 -8.7261 0.18788E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.50566E-09 -9.2961 0.42195E-09 -9.3747 0.83446E+00 -0.0786 65 MnO2-2 0.21397E-10 -10.6697 0.10964E-10 -10.9600 0.51241E+00 -0.2904 66 HMnO2- 0.21958E-09 -9.6584 0.18287E-09 -9.7379 0.83281E+00 -0.0795 69 MnCl+ 0.44940E-13 -13.3474 0.37501E-13 -13.4260 0.83446E+00 -0.0786 71 NaCl,aq 0.33363E-05 -5.4767 0.33363E-05 -5.4767 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.93735E-02 -2.0281 0.77919E-02 -2.1084 0.83127E+00 -0.0803 79 HPO3-2 0.16324E-14 -14.7872 0.83646E-15 -15.0776 0.51241E+00 -0.2904 81 H2PO3- 0.15188E-18 -18.8185 0.12649E-18 -18.8980 0.83281E+00 -0.0795 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39445E-10 -10.4040 0.32882E-10 -10.4830 0.83363E+00 -0.0790 84 PO4-3 0.11666E-08 -8.9331 0.27639E-09 -9.5585 0.23693E+00 -0.6254 88 HP2O7-3 0.99989E-18 -18.0000 0.22541E-18 -18.6470 0.22543E+00 -0.6470 89 P2O7-4 0.97939E-17 -17.0090 0.72235E-18 -18.1413 0.73755E-01 -1.1322 90 H2S,aq 0.25329E-07 -7.5964 0.25235E-07 -7.5980 0.99628E+00 -0.0016 91 S2-2 0.47003E-13 -13.3279 0.24085E-13 -13.6183 0.51241E+00 -0.2904 97 SO3-2 0.58187E-17 -17.2352 0.30262E-17 -17.5191 0.52008E+00 -0.2839 98 HSO3- 0.16370E-19 -19.7859 0.13633E-19 -19.8654 0.83281E+00 -0.0795 99 HSO4- 0.17460E-18 -18.7579 0.14585E-18 -18.8361 0.83530E+00 -0.0782 Charge balance for all species = -.6638E-10 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9186055E-10 -.2282197E-01 -.2296112E+02 0.0000 2 H2O 0.1000000E+01 0.5550449E+02 0.9981018E+06 0.0000 3 Cl- 0.7054027E-03 0.7087405E-03 0.2508104E+02 6.8826 4 SO4-- 0.3976066E-11 -.6562892E-04 -.6292893E+01 8.5373 5 HCO3- 0.1433011E-05 0.6713748E-04 0.4089051E+01 4.1911 6 HS- 0.1309851E-03 0.1966393E-03 0.6491365E+01 6.1514 7 Al+++ 0.1168015E-28 0.5197184E-05 0.1399714E+00 0.7608 8 H4SiO4 0.7116651E-03 0.1403356E-01 0.1346375E+04 -3.1477 9 Ca++ 0.1486120E-06 0.2515089E-06 0.1006154E-01 13.1065 10 Mg++ 0.2359943E-10 0.1000708E-09 0.2428474E-05 9.3053 11 Fe++ 0.6455422E-13 0.3735147E-07 0.2082154E-02 6.7428 12 K+ 0.1642927E-03 0.1650704E-03 0.6442780E+01 6.2505 13 Na+ 0.2088794E-01 0.2348208E-01 0.5388613E+03 8.3540 14 Mn++ 0.2075275E-10 0.2646222E-08 0.1451124E-03 9.2504 15 HPO4-- 0.4743549E-07 0.4864149E-07 0.4660025E-02 12.6140 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1324681E+03 -.4442871E-02 -.1324637E+03 0.0000000E+00 2 H2O -.4477502E+02 0.1080535E+02 -.5558036E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2217327E+00 -.1277632E-04 0.2217455E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2217072E+00 0.3828079E-04 -.2217455E+00 0.0000000E+00 7 Al+++ 0.2608593E+02 0.1011763E-05 0.2608593E+02 0.0000000E+00 8 H4SiO4 0.8330225E+02 0.2731985E-02 0.8329952E+02 0.0000000E+00 9 Ca++ 0.9201155E+01 0.4896253E-07 0.9201154E+01 0.0000000E+00 10 Mg++ 0.6349206E+01 0.1948131E-10 0.6349206E+01 0.0000000E+00 11 Fe++ 0.5704068E+01 0.7271404E-08 0.5704068E+01 0.0000000E+00 12 K+ 0.1698514E+01 0.3213510E-04 0.1698481E+01 0.0000000E+00 13 Na+ 0.1004211E+02 0.4571378E-02 0.1003754E+02 0.0000000E+00 14 Mn++ 0.1387088E+00 0.5151538E-09 0.1387088E+00 0.0000000E+00 15 HPO4-- 0.4734061E-01 0.9469290E-08 0.4734060E-01 0.0000000E+00 Chg. balance for solid moles: 0.3272E-13 Mass of aqueous solution: 0.195032E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 7999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.03 1.001 2630. 3.420 30.09 1010. andradite 0.8870 -0.052 450.7 2.654 5.157 117.1 grossular 0.2118 -0.674 95.39 1.980 1.091 26.54 apatite-OH 0.1578E-01 -1.802 7.927 0.899 0.9069E-01 2.519 clinochlore 1.139 0.057 633.2 2.802 7.244 240.8 daphnite 0.3265 -0.486 232.9 2.367 2.665 70.59 chlorite-Mn 0.2774E-01 -1.557 19.67 1.294 0.2250 6.268 diopside 0.4532 -0.344 98.16 1.992 1.123 30.00 hedenbergite 0.1161 -0.935 28.81 1.460 0.3296 7.891 microcline 1.487 0.172 414.0 2.617 4.736 161.7 stilbite 5.146 0.711 3627. 3.559 41.49 1691. stilpnomelane-Fe 0.4225 -0.374 455.5 2.658 5.211 157.3 tr.625ac.25prg.125 0.5528E-01 -1.257 47.25 1.674 0.5406 15.21 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8740.225047 g Volume = 3537.150972 cm3 Porosity: -10.5014% V(tot) - V(min): -.33615E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7999.9990000 g log = 3.9031 Original solution: 1000.0103000 g Original solution / Rock added: 0.13 (Water/Rock Ratio), log = -0.9031 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1663 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9033E+00 0.9841 0.1037E+01 0.1053E+01 CO2,gas 0.1810E-07 1.0061 0.2124E-07 0.2111E-07 CH4,gas 0.8397E-01 1.0119 0.9910E-01 0.9794E-01 H2,gas 0.1277E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.6339E-06 0.9955 0.7360E-06 0.7393E-06 S2,gas 0.7826E-28 1.0000 0.9128E-28 0.9128E-28 CO,gas 0.7031E-13 1.0000 0.8201E-13 0.8201E-13 SO3,gas 0.3879E-47 1.0000 0.4524E-47 0.4524E-47 SO2,gas 0.2188E-26 1.0000 0.2551E-26 0.2551E-26 HCl,gas 0.1288E-16 1.0000 0.1502E-16 0.1502E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.04 -9.67 -3.224 0.16516E+05 -7.673 3 CH4,gas 4.81 1.81 -3.00 -0.751 0.51291E+04 -1.004 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.08 -8.13 -4.067 0.13887E+05 -6.133 6 S2,gas -7.03 -37.07 -30.04 -4.621 0.51292E+05 -28.040 7 CO,gas 3.51 -11.58 -15.09 -4.642 0.25759E+05 -13.086 8 SO3,gas 17.43 -31.92 -49.34 -12.336 0.84254E+05 -47.344 9 SO2,gas 1.14 -27.46 -28.59 -7.625 0.48822E+05 -26.593 10 HCl,gas 5.48 -13.34 -18.82 -9.412 0.32140E+05 -16.823 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80598E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.93 -3.92 -1.305 0.66862E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.93 -3.76 -1.254 0.64249E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65548E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.12 -4.01 -1.145 0.68438E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.12 -3.57 -1.019 0.60900E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82259E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.87 -4.64 -1.093 0.79290E+04 143 pyrrhotite -4.24 -7.33 -3.09 -1.030 0.52750E+04 144 pyrrhotiteFe0.875 -6.00 -8.73 -2.73 -1.003 0.46578E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22426E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23218E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47125E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.33 -2.94 -0.980 0.50182E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.83 -3.86 -1.288 0.65960E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 200.0000000 g Current total amount of reactant added: 7999.9990000 g New total amount of reactant added: 8199.9990000 g Mixing fraction reached given limit of 0.8000E+04 TOTMIX = 0.8200E+04 Execution stopped.