File SKIP_SPECIES.TXT lists species and minerals omitted from the calculations due to given T, P, option switches, or suppression in CHIMRUN, or are suppressed in the SOLTHERM database. It also lists minerals for which density is not specified in SOLTHERM. This is an extended P(to 5 kB), T(to 600 C) run (CON_FLAG = 1). methanol,aq is suppressed in SOLTHERM data file. methanol,aq is suppressed in SOLTHERM data file. CuCl4-3 is suppressed in SOLTHERM data file. H2BO3- is suppressed in SOLTHERM data file. UO2CO3,aq is suppressed in SOLTHERM data file. UO2SO4,aq is suppressed in SOLTHERM data file. UO2Cl2,aq is suppressed in SOLTHERM data file. UO2F2,aq is suppressed in SOLTHERM data file. PO4-3 is suppressed in SOLTHERM data file. H2PO4- is suppressed in SOLTHERM data file. H3PO4 is suppressed in SOLTHERM data file. O2,gas is suppressed in THIS RUN. O2,gas is suppressed in THIS RUN. amesite is suppressed in SOLTHERM data file. antigorite is suppressed in SOLTHERM data file. goethite is suppressed in THIS RUN. goethite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. riebeckite is suppressed in THIS RUN. sapphirine-Fe(221) is suppressed in SOLTHERM data file. sapphirine(221) is suppressed in SOLTHERM data file. talc-prl is suppressed in SOLTHERM data file. PrO1.833(s) is suppressed in SOLTHERM data file. niter-NH4 is suppressed in SOLTHERM data file. FMQ_HS-1 is suppressed in THIS RUN. kf-ab-equil is suppressed in THIS RUN. ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Species No. Charge Tot.moles Trial molality Gamma Mixing solution H+ 1 1. -0.13247E+03 0.91861E-10 0.8380 0.00000000E+00 H2O 2 0. -0.44775E+02 0.10000E+01 1.0000 0.00000000E+00 Cl- 3 -1. 0.13797E-03 0.70540E-03 0.8328 0.00000000E+00 SO4-- 4 -2. 0.22173E+00 0.39761E-11 0.5135 0.00000000E+00 HCO3- 5 -1. 0.13070E-04 0.14330E-05 0.8341 0.00000000E+00 HS- 6 -1. -0.22171E+00 0.13099E-03 0.8329 0.00000000E+00 Al+++ 7 3. 0.26086E+02 0.11680E-28 0.2252 0.00000000E+00 H4SiO4 8 0. 0.83302E+02 0.71167E-03 1.0000 0.00000000E+00 Ca++ 9 2. 0.92012E+01 0.14861E-06 0.5096 0.00000000E+00 Mg++ 10 2. 0.63492E+01 0.23599E-10 0.5072 0.00000000E+00 Fe++ 11 2. 0.57041E+01 0.64554E-13 0.5078 0.00000000E+00 K+ 12 1. 0.16985E+01 0.16429E-03 0.8343 0.00000000E+00 Na+ 13 1. 0.10042E+02 0.20888E-01 0.8327 0.00000000E+00 Mn++ 14 2. 0.13871E+00 0.20753E-10 0.5082 0.00000000E+00 HPO4-- 15 -2. 0.47341E-01 0.47435E-07 0.5136 0.00000000E+00 Chg. balance for total moles = 0.7637E-10 Max. difference allowed = 0.1380E-07 The following parameters were given: ERPC = 0.1000E-11 pH = 0.0000 PFLUID = 100.0000 SLIM = 0.900000E+04 TEMP = 100.0000 SINC = 0.5000E+02 TEMPC = 0.0000 TOTMIX = 0.800000E+04 ENTH = 0.0000 SENTH = 0.0000 DENTH = 0.0000 TOTWAT = 90.0000 SOLMIN = 0.0000E+00 RM = 0.0000 AQGRM = 1000.0103 SUPRNT = 0.1000E-19 VBOX-1 = 3200.9996 RHOFRS = 0.0000 RHOROC = 2.5000 The following options were selected: CONFLG = 1 C = 3 IFRAC = 0 IPUNCH = 2 NLOOP = 400 ISTEP = 2 LIMSOL = 1 LOOC = 0 IENTH = 0 ITREF = 0 IDEAL = 0 IPSAT = 1 INCREM = 0 INCP = 0 MINSOL = 1 NEUT = 0 AWAT = 0 CHGF = 0 Of the derived species, only those with molality > 0.10E-19 will appear in the output Species No. Charge Log K(diss) Species No. Charge Log K(diss) HSiO3- 16 -1. 9.0107 MnO2-2 65 -2. 40.4376 Ca(HSiO3)+ 17 1. 7.6603 HMnO2- 66 -1. 29.1018 Mg(HSiO3)+ 18 1. 7.5653 MnO4- 67 -1. 83.3383 NaHSiO3,aq 19 0. 7.8098 MnO4-2 68 -2. 81.3024 AlO+ 20 1. 6.8891 MnCl+ 69 1. -0.7819 AlOH+2 21 2. 3.1893 MnSO4,aq 70 0. -2.4524 HAlO2,aq 22 0. 10.5878 NaCl,aq 71 0. 0.4861 AlO2- 23 -1. 16.2390 NaOH,aq 72 0. 12.3571 CH4,aq 24 0. 6.0082 O2,aq 73 0. 53.5759 C2H6,aq 25 0. 12.3556 OH- 74 -1. 12.2220 C3H8,aq 26 0. 17.3423 HO2- 75 -1. 50.7897 C4H10,aq 27 0. 22.3397 H2O2,aq 76 0. 40.0297 ethanol,aq 28 0. 15.3114 H3PO2,aq 77 0. 24.3310 CO,aq 29 0. 4.7087 H2PO2- 78 -1. 26.5491 CO2,aq 30 0. -6.3045 HPO3-2 79 -2. 11.9246 CO3-2 31 -2. 10.0340 H3PO3,aq 80 0. 3.5932 CaCO3,aq 32 0. 5.9460 H2PO3- 81 -1. 5.6314 Ca(HCO3)+ 33 1. -1.4013 H3PO4,aq 82 0. -9.8087 CaCl+ 34 1. -0.2023 H2PO4- 83 -1. -7.2438 CaCl2,aq 35 0. 0.4306 PO4-3 84 -3. 12.0588 CaOH+ 36 1. 10.1517 H4P2O7,aq 85 0. -17.7539 CaSO4,aq 37 0. -2.4936 H3P2O7- 86 -1. -15.8646 HCl,aq 38 0. 0.7256 H2P2O7-2 87 -2. -13.3812 HClO,aq 39 0. 32.4377 HP2O7-3 88 -3. -6.6931 ClO- 40 -1. 39.6416 P2O7-4 89 -4. 2.9147 HClO2,aq 41 0. 70.2060 H2S,aq 90 0. -6.4778 Fe+3 42 3. 8.3763 S2-2 91 -2. 1.2336 FeCl+ 43 1. -0.1924 S3-2 92 -2. -8.7963 FeCl2,aq 44 0. 4.3160 S3- 93 -1. -16.3178 FeCl+2 45 2. 6.5223 S4-2 94 -2. -18.6473 FeO,aq 46 0. 16.4029 S5-2 95 -2. -28.3223 FeOH+ 47 1. 7.4795 SO2,aq 96 0. -0.1980 HFeO2- 48 -1. 24.3713 SO3-2 97 -2. 10.2895 FeO+ 49 1. 11.3812 HSO3- 98 -1. 2.5222 FeOH+2 50 2. 9.1115 HSO4- 99 -1. -2.9675 FeO2- 51 -1. 24.0877 HSO5- 100 -1. 38.8657 HFeO2,aq 52 0. 15.9903 S2O3-2 101 -2. -4.5491 H2,aq 53 0. 9.4241 HS2O3- 102 -1. -6.8007 KCl,aq 54 0. 1.7519 H2S2O3,aq 103 0. -7.9944 KHSO4,aq 55 0. -0.4275 S2O4-2 104 -2. 10.5639 KOH,aq 56 0. 12.3606 HS2O4- 105 -1. 7.6762 KSO4- 57 -1. -1.1877 H2S2O4,aq 106 0. 6.6566 MgCO3,aq 58 0. 6.5483 S2O5-2 107 -2. 10.0891 Mg(HCO3)+ 59 1. -1.4098 S2O6-2 108 -2. 11.5737 MgCl+ 60 1. -0.1603 S2O8-2 109 -2. 42.1139 MgOH+ 61 1. 9.4082 S3O6-2 110 -2. 3.8101 Mn+3 62 3. 19.1332 S4O6-2 111 -2. -17.8301 MnO,aq 63 0. 17.9765 S5O6-2 112 -2. -14.1051 MnOH+ 64 1. 8.5115 113 0. 10.3157 For mixed gases (JSOLS=6), log K(hydrol) = log (K*P) Log K Trial Log K Trial Mineral No. hydrol Moles Mineral No. hydrol Moles H2O,gas 1 1.984 0.0000E+00 osumilite(2) 124 20.895 0.0000E+00 CO2,gas 2 -6.363 0.0000E+00 osumilite-Fe 125 14.657 0.0000E+00 CH4,gas 3 4.809 0.0000E+00 pargasite 126 65.279 0.0000E+00 H2,gas 4 8.287 0.0000E+00 periclase 127 16.149 0.0000E+00 H2S,gas 5 -5.943 0.0000E+00 periclase-Fe 128 11.639 0.0000E+00 S2,gas 6 -7.033 0.0000E+00 perovskite-Al 129 12.395 0.0000E+00 CO,gas 7 3.510 0.0000E+00 perovskite-Ca 130 23.818 0.0000E+00 SO3,gas 8 17.427 0.0000E+00 perovskite-Fe 131 21.158 0.0000E+00 SO2,gas 9 1.136 0.0000E+00 perovskite-Mg 132 23.132 0.0000E+00 HCl,gas 10 5.479 0.0000E+00 phase_A 133 80.267 0.0000E+00 acmite 11 7.737 0.0000E+00 phlogopite-Na 134 29.731 0.0000E+00 akermanite 12 36.495 0.0000E+00 piemontite(ordered) 135 33.876 0.0000E+00 akimotoite 13 16.606 0.0000E+00 prehnite 136 19.466 0.0000E+00 akimotoite-Fe 14 13.083 0.0000E+00 prehnite-Fe 137 22.587 0.0000E+00 albite-high 15 0.750 0.0000E+00 pumpellyite-Fe 138 46.471 0.0000E+00 albite 16 -0.328 0.1003E+02 pumpellyite-Mg 139 49.194 0.0000E+00 almandine 17 24.545 0.0000E+00 px-Mg-tschermaks 140 19.687 0.0000E+00 pyrope 18 37.348 0.0000E+00 px-Ca-tschermaks 141 18.679 0.0000E+00 spessartine 19 24.550 0.0000E+00 pyrite 142 -21.225 0.0000E+00 analcite 20 3.371 0.0000E+00 pyrrhotite 143 -4.244 0.0000E+00 andalusite 21 5.062 0.0000E+00 pyrrhotiteFe0.875 144 -6.001 0.0000E+00 andradite 22 39.088 0.8870E+00 pyroxmangite 145 7.416 0.0000E+00 grossular 23 32.828 0.2118E+00 pyrophyllite 146 -6.098 0.0000E+00 anhydrite 24 -5.280 0.0000E+00 quartz 147 -2.982 0.0000E+00 ankerite 25 -2.093 0.0000E+00 rankinite 148 40.765 0.0000E+00 annite 26 20.209 0.0000E+00 ringwoodite-Fe 149 15.486 0.0000E+00 phlogopite 27 27.147 0.0000E+00 ringwoodite-Mg 150 27.602 0.0000E+00 biotite-Mn 28 33.034 0.0000E+00 rhodochrosite 151 -0.959 0.0000E+00 anorthite 29 12.798 0.0000E+00 rhodonite 152 7.462 0.0000E+00 anthophyllite 30 51.988 0.0000E+00 sanidine 153 -1.221 0.0000E+00 anthophyllite-Fe 31 29.455 0.0000E+00 sapphirine(351) 154 79.204 0.0000E+00 apatite-OH 32 -17.989 0.1578E-01 siderite 155 -2.588 0.0000E+00 apatite-OH-zs 33 -12.572 0.0000E+00 sillimanite 156 5.321 0.0000E+00 apatite-Cl-zs 34 -16.504 0.0000E+00 sodalite 157 50.255 0.0000E+00 aragonite 35 0.986 0.0000E+00 spinel 158 20.934 0.0000E+00 brucite 36 12.577 0.0000E+00 spurrite 159 59.566 0.0000E+00 calcite 37 0.833 0.0000E+00 staurolite-Fe 160 74.138 0.0000E+00 carnegieite-low 38 9.065 0.0000E+00 staurolite-Mg 161 90.336 0.0000E+00 carnegieite-high 39 10.134 0.0000E+00 staurolite-Mn 162 84.438 0.0000E+00 carpholite-Mg 40 8.650 0.0000E+00 stilbite 163 -7.406 0.5146E+01 carpholite-Fe 41 6.783 0.0000E+00 stilpnomelane-Fe 164 13.179 0.4225E+00 celadonite 42 5.401 0.0000E+00 stilpnomelane-Mg 165 27.596 0.0000E+00 celadonite-Fe 43 3.937 0.0000E+00 stishovite 166 2.721 0.0000E+00 chrysotile 44 23.937 0.0000E+00 sudoite-Fe 167 18.437 0.0000E+00 chondrodite 45 56.542 0.0000E+00 sudoite 168 21.216 0.0000E+00 clinochlore 46 39.193 0.1139E+01 sulfur 169 -9.141 0.0000E+00 daphnite 47 29.094 0.3265E+00 sylvite 170 1.345 0.0000E+00 chlorite-Mn 48 46.985 0.2774E-01 talc 171 16.553 0.0000E+00 chlorite-Al-free 49 47.262 0.0000E+00 talc-Fe 172 13.516 0.0000E+00 chloritoid-Mg 50 13.261 0.0000E+00 talc-tschermaks 173 19.189 0.0000E+00 chloritoid-Fe 51 9.239 0.0000E+00 tephroite 174 18.113 0.0000E+00 chloritoid-Mn 52 11.463 0.0000E+00 tilleyite 175 41.473 0.0000E+00 clinohumite 53 97.255 0.0000E+00 titanite-CaSi 176 15.497 0.0000E+00 coesite 54 -2.369 0.0000E+00 topaz-H 177 4.668 0.0000E+00 cordierite-H 55 23.898 0.0000E+00 tridymite 178 -2.615 0.0000E+00 cordierite 56 24.245 0.0000E+00 tremolite 179 48.003 0.0000E+00 cordierite-Fe 57 20.649 0.0000E+00 ferroactinolite 180 38.596 0.0000E+00 cordierite-Mn 58 25.261 0.0000E+00 troilite-low 181 -4.394 0.0000E+00 corundum 59 8.433 0.0000E+00 tschermakite 182 48.414 0.0000E+00 corundum-MgSi 60 18.905 0.0000E+00 vesuvianite 183 224.056 0.0000E+00 cristobalite 61 -2.549 0.0000E+00 wadeite-Si 184 20.233 0.0000E+00 cummingtonite 62 52.233 0.0000E+00 wadsleyite-Fe 185 15.711 0.0000E+00 cymrite-K 63 1.731 0.0000E+00 wadsleyite-Mg 186 25.878 0.0000E+00 deerite 64 95.982 0.0000E+00 wairakite 187 4.058 0.0000E+00 diaspore 65 2.896 0.0000E+00 walstromite 188 11.528 0.0000E+00 diamond 66 -3.107 0.0000E+00 wollastonite 189 10.482 0.0000E+00 diopside 67 16.215 0.4532E+00 pseudo-wollastonite 190 11.020 0.0000E+00 hedenbergite 68 14.244 0.1161E+00 zoisite 191 22.964 0.0000E+00 dolomite,ordered 69 0.587 0.0000E+00 akaganeite 192 7.768 0.0000E+00 eastonite 70 28.605 0.0000E+00 beidellite-Ca 193 -1.560 0.0000E+00 enstatite 71 17.301 0.0000E+00 beidellite-H 194 -2.241 0.0000E+00 clinoenstatite-HiP 72 18.388 0.0000E+00 beidellite-K 195 -1.435 0.0000E+00 clinoenstatite 73 17.202 0.0000E+00 beidellite-Mg 196 -1.707 0.0000E+00 protoenstatite 74 17.860 0.0000E+00 beidellite-Na 197 -1.257 0.0000E+00 epidote 75 24.775 0.0000E+00 calcium 198 84.043 0.0000E+00 clinozoisite 76 22.921 0.0000E+00 chalcedony 199 -2.794 0.0000E+00 epidote-Fe 77 29.937 0.0000E+00 dawsonite 200 1.714 0.0000E+00 fayalite 78 14.079 0.0000E+00 montmorillonite-Ca 201 -2.214 0.0000E+00 ferrosilite 79 11.188 0.0000E+00 montmorillonite-K 202 -2.161 0.0000E+00 forsterite 80 21.047 0.0000E+00 montmorillonite-Mg 203 -2.402 0.0000E+00 gedrite 81 50.725 0.0000E+00 montmorillonite-Na 204 -1.961 0.0000E+00 gehlenite 82 36.717 0.0000E+00 nontronite-Ca 205 3.280 0.0000E+00 gibbsite 83 4.097 0.0000E+00 nontronite-H 206 2.596 0.0000E+00 glaucophane 84 23.111 0.0000E+00 nontronite-K 207 3.404 0.0000E+00 glaucophane-Fe 85 17.417 0.0000E+00 nontronite-Mg 208 3.139 0.0000E+00 graphite 86 -3.549 0.0000E+00 nontronite-Na 209 3.583 0.0000E+00 greenalite 87 16.194 0.0000E+00 sepiolite 210 24.194 0.0000E+00 grunerite 88 31.364 0.0000E+00 alite 211 58.043 0.0000E+00 halite 89 1.582 0.0000E+00 belite 212 30.461 0.0000E+00 hematite 90 12.598 0.0000E+00 ettringite 213 43.354 0.0000E+00 heulandite 91 -5.707 0.0000E+00 gypsum 214 -4.924 0.0000E+00 hercynite 92 17.345 0.0000E+00 hemicarboaluminate 215 71.028 0.0000E+00 hollandite 93 25.702 0.0000E+00 hydrogarnet 216 60.721 0.0000E+00 iron 94 19.095 0.0000E+00 hydrogarnet-Si 217 50.654 0.0000E+00 jadeite 95 4.251 0.0000E+00 jennite 218 24.386 0.0000E+00 julgoldite 96 70.573 0.0000E+00 monosulfoaluminate 219 53.497 0.0000E+00 kalsilite 97 7.620 0.0000E+00 monocarboaluminate 220 61.966 0.0000E+00 kaolinite 98 -1.273 0.0000E+00 portlandite 221 18.282 0.0000E+00 kyanite 99 4.932 0.0000E+00 stratlingite 222 36.573 0.0000E+00 larnite-bredigite 100 30.714 0.0000E+00 tricarboaluminate 223 70.427 0.0000E+00 laumontite 101 2.975 0.0000E+00 tobermorite 224 9.839 0.0000E+00 lawsonite 102 9.678 0.0000E+00 C4AH13 225 81.870 0.0000E+00 leucite 103 4.168 0.0000E+00 C2AH8 226 45.260 0.0000E+00 lime 104 26.009 0.0000E+00 C3A 227 87.049 0.0000E+00 lizardite 105 23.287 0.0000E+00 C4AF 228 117.550 0.0000E+00 magnesite 106 0.709 0.0000E+00 CAH10 229 28.373 0.0000E+00 magnetite 107 20.133 0.0000E+00 alabandite 230 -0.962 0.0000E+00 minnesotaite 108 10.461 0.0000E+00 alunite 231 -10.224 0.0000E+00 minnesotaite-Mg 109 20.669 0.0000E+00 artinite 232 15.139 0.0000E+00 magnesioferrite 110 26.257 0.0000E+00 boehmite 233 4.430 0.0000E+00 majorite 111 53.314 0.0000E+00 dolomite,disordered 234 1.288 0.0000E+00 manganosite 112 14.068 0.0000E+00 ferrous-oxide 235 9.824 0.0000E+00 margarite 113 17.452 0.0000E+00 huntite 236 3.850 0.0000E+00 meionite 114 45.158 0.0000E+00 hydromagnesite 237 20.077 0.0000E+00 merwinite 115 55.988 0.0000E+00 nesquehonite 238 4.735 0.0000E+00 microcline 116 -2.432 0.1487E+01 potassium-oxide 239 69.039 0.0000E+00 monticellite 117 24.371 0.0000E+00 silica-amorphous 240 -2.080 0.0000E+00 mullite-Al 118 363.258 0.0000E+00 sodium-oxide 241 55.173 0.0000E+00 mullite-Si 119 7.324 0.0000E+00 an20ab80 242 2.079 0.0000E+00 muscovite 120 2.679 0.0000E+00 an25ab75 243 2.709 0.0000E+00 paragonite 121 4.337 0.0000E+00 an30ab70 244 3.344 0.0000E+00 nepheline 122 8.378 0.0000E+00 tr.625ac.25prg.125 245 45.308 0.5528E-01 osumilite(1) 123 21.978 0.0000E+00 246 0.000 0.0000E+00 Initial composition of reactant (wt%): SiO2 62.56 MgO 3.200 Al2O3 16.62 CaO 6.450 FeO 3.530 Na2O 3.890 Fe2O3 1.770 K2O 1.000 MnO 0.1230 P2O5 0.4200E-01 Sum of wt% of reactants: 99.1850 Reactant consumed: 7999.9990000 g log = 3.9031 Original solution: 1000.0103000 g Original solution / Rock added: 0.13 (Water/Rock Ratio), log = -0.9031 The following minerals and/or gases with identical index are in solid solution: H2O,gas 6 CO2,gas 6 CH4,gas 6 H2,gas 6 H2S,gas 6 S2,gas 6 CO,gas 6 SO3,gas 6 SO2,gas 6 HCl,gas 6 almandine 16 pyrope 16 spessartine 16 andradite 8 grossular 8 annite 15 phlogopite 15 biotite-Mn 15 clinochlore 1 daphnite 1 chlorite-Mn 1 diopside 5 hedenbergite 5 epidote 3 clinozoisite 3 iron 9 magnetite 14 talc 7 talc-Fe 7 tremolite 2 ferroactinolite 2 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 7999.9990000 Water: Moles liquid = 0.1081E+02 kg liquid = 0.1947E+00 Moles total = -.4478E+02 kg total = -.8066E+00 Activity = 1.0000 Stoichiometric ionic strength = .1220347E-01 Osmotic coef. = 0.9672 True ionic strength = .2105563E-01 Chg. balance for total moles = 0.7637E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91861E-10 -10.0369 0.76982E-10 -10.1136 0.83803E+00 -0.0767 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.70540E-03 -3.1516 0.58747E-03 -3.2310 0.83281E+00 -0.0795 4 SO4-- 0.39761E-11 -11.4005 0.20419E-11 -11.6900 0.51354E+00 -0.2894 5 HCO3- 0.14330E-05 -5.8438 0.11952E-05 -5.9225 0.83407E+00 -0.0788 6 HS- 0.13099E-03 -3.8828 0.10910E-03 -3.9622 0.83294E+00 -0.0794 7 Al+++ 0.11680E-28 -28.9326 0.26303E-29 -29.5800 0.22519E+00 -0.6474 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14861E-06 -6.8279 0.75738E-07 -7.1207 0.50963E+00 -0.2927 10 Mg++ 0.23599E-10 -10.6271 0.11970E-10 -10.9219 0.50722E+00 -0.2948 11 Fe++ 0.64554E-13 -13.1901 0.32780E-13 -13.4844 0.50780E+00 -0.2943 12 K+ 0.16429E-03 -3.7844 0.13707E-03 -3.8631 0.83427E+00 -0.0787 13 Na+ 0.20888E-01 -1.6801 0.17392E-01 -1.7596 0.83265E+00 -0.0795 14 Mn++ 0.20753E-10 -10.6829 0.10547E-10 -10.9769 0.50823E+00 -0.2939 15 HPO4-- 0.47435E-07 -7.3239 0.24364E-07 -7.6133 0.51362E+00 -0.2894 16 HSiO3- 0.10830E-01 -1.9654 0.90196E-02 -2.0448 0.83281E+00 -0.0795 17 Ca(HSiO3)+ 0.18342E-07 -7.7366 0.15306E-07 -7.8151 0.83446E+00 -0.0786 18 Mg(HSiO3)+ 0.36077E-11 -11.4428 0.30105E-11 -11.5214 0.83446E+00 -0.0786 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.68665E-16 -16.1633 0.57298E-16 -16.2419 0.83446E+00 -0.0786 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51970E-05 -5.2842 0.43201E-05 -5.3645 0.83127E+00 -0.0803 24 CH4,aq 0.62901E-04 -4.2013 0.62668E-04 -4.2030 0.99628E+00 -0.0016 25 C2H6,aq 0.62541E-13 -13.2038 0.62309E-13 -13.2055 0.99628E+00 -0.0016 29 CO,aq 0.51935E-16 -16.2845 0.51935E-16 -16.2845 0.10000E+01 0.0000 30 CO2,aq 0.18621E-09 -9.7300 0.18551E-09 -9.7316 0.99628E+00 -0.0016 31 CO3-2 0.28015E-05 -5.5526 0.14355E-05 -5.8430 0.51241E+00 -0.2904 32 CaCO3,aq 0.13316E-08 -8.8756 0.13316E-08 -8.8756 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.27334E-11 -11.5633 0.22809E-11 -11.6419 0.83446E+00 -0.0786 34 CaCl+ 0.84965E-10 -10.0708 0.70900E-10 -10.1494 0.83446E+00 -0.0786 35 CaCl2,aq 0.96980E-14 -14.0133 0.96980E-14 -14.0133 0.10000E+01 0.0000 36 CaOH+ 0.83136E-07 -7.0802 0.69373E-07 -7.1588 0.83446E+00 -0.0786 37 CaSO4,aq 0.48184E-16 -16.3171 0.48184E-16 -16.3171 0.10000E+01 0.0000 38 HCl,aq 0.85066E-14 -14.0702 0.85066E-14 -14.0702 0.10000E+01 0.0000 43 FeCl+ 0.35944E-16 -16.4444 0.29994E-16 -16.5230 0.83446E+00 -0.0786 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16918E-10 -10.7717 0.14117E-10 -10.8503 0.83446E+00 -0.0786 48 HFeO2- 0.36697E-07 -7.4354 0.30562E-07 -7.5148 0.83281E+00 -0.0795 49 FeO+ 0.12487E-16 -16.9035 0.10420E-16 -16.9821 0.83446E+00 -0.0786 51 FeO2- 0.41495E-09 -9.3820 0.34557E-09 -9.4615 0.83281E+00 -0.0795 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10870E-04 -4.9638 0.99628E+00 -0.0016 54 KCl,aq 0.14258E-08 -8.8460 0.14258E-08 -8.8460 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.51774E-14 -14.2859 0.43118E-14 -14.3653 0.83281E+00 -0.0795 58 MgCO3,aq 0.52589E-13 -13.2791 0.52589E-13 -13.2791 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.44054E-15 -15.3560 0.36761E-15 -15.4346 0.83446E+00 -0.0786 60 MgCl+ 0.12191E-13 -13.9140 0.10173E-13 -13.9926 0.83446E+00 -0.0786 61 MgOH+ 0.72793E-10 -10.1379 0.60743E-10 -10.2165 0.83446E+00 -0.0786 63 MnO,aq 0.18788E-08 -8.7261 0.18788E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.50566E-09 -9.2961 0.42195E-09 -9.3747 0.83446E+00 -0.0786 65 MnO2-2 0.21397E-10 -10.6697 0.10964E-10 -10.9600 0.51241E+00 -0.2904 66 HMnO2- 0.21958E-09 -9.6584 0.18287E-09 -9.7379 0.83281E+00 -0.0795 69 MnCl+ 0.44940E-13 -13.3474 0.37501E-13 -13.4260 0.83446E+00 -0.0786 71 NaCl,aq 0.33363E-05 -5.4767 0.33363E-05 -5.4767 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.93735E-02 -2.0281 0.77919E-02 -2.1084 0.83127E+00 -0.0803 79 HPO3-2 0.16324E-14 -14.7872 0.83646E-15 -15.0776 0.51241E+00 -0.2904 81 H2PO3- 0.15188E-18 -18.8185 0.12649E-18 -18.8980 0.83281E+00 -0.0795 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39445E-10 -10.4040 0.32882E-10 -10.4830 0.83363E+00 -0.0790 84 PO4-3 0.11666E-08 -8.9331 0.27639E-09 -9.5585 0.23693E+00 -0.6254 88 HP2O7-3 0.99989E-18 -18.0000 0.22541E-18 -18.6470 0.22543E+00 -0.6470 89 P2O7-4 0.97939E-17 -17.0090 0.72235E-18 -18.1413 0.73755E-01 -1.1322 90 H2S,aq 0.25329E-07 -7.5964 0.25235E-07 -7.5980 0.99628E+00 -0.0016 91 S2-2 0.47003E-13 -13.3279 0.24085E-13 -13.6183 0.51241E+00 -0.2904 97 SO3-2 0.58187E-17 -17.2352 0.30262E-17 -17.5191 0.52008E+00 -0.2839 98 HSO3- 0.16370E-19 -19.7859 0.13633E-19 -19.8654 0.83281E+00 -0.0795 99 HSO4- 0.17460E-18 -18.7579 0.14585E-18 -18.8361 0.83530E+00 -0.0782 Charge balance for all species = 0.3927E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9186055E-10 -.2282197E-01 -.2296112E+02 0.0000 2 H2O 0.1000000E+01 0.5550449E+02 0.9981018E+06 0.0000 3 Cl- 0.7054027E-03 0.7087405E-03 0.2508104E+02 6.8826 4 SO4-- 0.3976066E-11 -.6562892E-04 -.6292893E+01 8.5373 5 HCO3- 0.1433011E-05 0.6713748E-04 0.4089051E+01 4.1911 6 HS- 0.1309851E-03 0.1966393E-03 0.6491365E+01 6.1514 7 Al+++ 0.1168015E-28 0.5197184E-05 0.1399714E+00 0.7608 8 H4SiO4 0.7116651E-03 0.1403356E-01 0.1346375E+04 -3.1477 9 Ca++ 0.1486120E-06 0.2515088E-06 0.1006154E-01 13.1065 10 Mg++ 0.2359943E-10 0.1000708E-09 0.2428474E-05 9.3053 11 Fe++ 0.6455422E-13 0.3735147E-07 0.2082154E-02 6.7428 12 K+ 0.1642927E-03 0.1650704E-03 0.6442780E+01 6.2505 13 Na+ 0.2088794E-01 0.2348208E-01 0.5388613E+03 8.3540 14 Mn++ 0.2075276E-10 0.2646222E-08 0.1451124E-03 9.2504 15 HPO4-- 0.4743548E-07 0.4864149E-07 0.4660025E-02 12.6140 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1324681E+03 -.4442871E-02 -.1324637E+03 0.0000000E+00 2 H2O -.4477502E+02 0.1080535E+02 -.5558036E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2217327E+00 -.1277632E-04 0.2217455E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2217072E+00 0.3828079E-04 -.2217455E+00 0.0000000E+00 7 Al+++ 0.2608593E+02 0.1011763E-05 0.2608593E+02 0.0000000E+00 8 H4SiO4 0.8330225E+02 0.2731985E-02 0.8329952E+02 0.0000000E+00 9 Ca++ 0.9201155E+01 0.4896253E-07 0.9201154E+01 0.0000000E+00 10 Mg++ 0.6349206E+01 0.1948131E-10 0.6349206E+01 0.0000000E+00 11 Fe++ 0.5704068E+01 0.7271404E-08 0.5704068E+01 0.0000000E+00 12 K+ 0.1698514E+01 0.3213510E-04 0.1698481E+01 0.0000000E+00 13 Na+ 0.1004211E+02 0.4571378E-02 0.1003754E+02 0.0000000E+00 14 Mn++ 0.1387088E+00 0.5151538E-09 0.1387088E+00 0.0000000E+00 15 HPO4-- 0.4734061E-01 0.9469289E-08 0.4734060E-01 0.0000000E+00 Chg. balance for solid moles: 0.5529E-13 Mass of aqueous solution: 0.195032E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 7999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.03 1.001 2630. 3.420 30.09 1010. andradite 0.8870 -0.052 450.7 2.654 5.157 117.1 grossular 0.2118 -0.674 95.39 1.980 1.091 26.54 apatite-OH 0.1578E-01 -1.802 7.927 0.899 0.9069E-01 2.519 clinochlore 1.139 0.057 633.2 2.802 7.244 240.8 daphnite 0.3265 -0.486 232.9 2.367 2.665 70.59 chlorite-Mn 0.2774E-01 -1.557 19.67 1.294 0.2250 6.268 diopside 0.4532 -0.344 98.16 1.992 1.123 30.00 hedenbergite 0.1161 -0.935 28.81 1.460 0.3296 7.891 microcline 1.487 0.172 414.0 2.617 4.736 161.7 stilbite 5.146 0.711 3627. 3.559 41.49 1691. stilpnomelane-Fe 0.4225 -0.374 455.5 2.658 5.211 157.3 tr.625ac.25prg.125 0.5528E-01 -1.257 47.25 1.674 0.5406 15.21 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8740.225047 g Volume = 3537.150972 cm3 Porosity: -10.5014% V(tot) - V(min): -.33615E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 7999.9990000 g log = 3.9031 Original solution: 1000.0103000 g Original solution / Rock added: 0.13 (Water/Rock Ratio), log = -0.9031 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1663 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9033E+00 0.9841 0.1037E+01 0.1053E+01 CO2,gas 0.1810E-07 1.0061 0.2124E-07 0.2111E-07 CH4,gas 0.8397E-01 1.0119 0.9910E-01 0.9794E-01 H2,gas 0.1277E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.6339E-06 0.9955 0.7360E-06 0.7393E-06 S2,gas 0.7826E-28 1.0000 0.9128E-28 0.9128E-28 CO,gas 0.7031E-13 1.0000 0.8201E-13 0.8201E-13 SO3,gas 0.3879E-47 1.0000 0.4524E-47 0.4524E-47 SO2,gas 0.2188E-26 1.0000 0.2551E-26 0.2551E-26 HCl,gas 0.1288E-16 1.0000 0.1502E-16 0.1502E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.54595E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.37914E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.04 -9.67 -3.224 0.16516E+05 -7.673 3 CH4,gas 4.81 1.81 -3.00 -0.751 0.51291E+04 -1.004 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.08 -8.13 -4.067 0.13887E+05 -6.133 6 S2,gas -7.03 -37.07 -30.04 -4.621 0.51292E+05 -28.040 7 CO,gas 3.51 -11.58 -15.09 -4.642 0.25759E+05 -13.086 8 SO3,gas 17.43 -31.92 -49.34 -12.336 0.84254E+05 -47.344 9 SO2,gas 1.14 -27.46 -28.59 -7.625 0.48822E+05 -26.593 10 HCl,gas 5.48 -13.34 -18.82 -9.412 0.32140E+05 -16.823 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80598E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.93 -3.92 -1.305 0.66862E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.93 -3.76 -1.254 0.64249E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65548E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.12 -4.01 -1.145 0.68438E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.12 -3.57 -1.019 0.60900E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82259E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.87 -4.64 -1.093 0.79290E+04 143 pyrrhotite -4.24 -7.33 -3.09 -1.030 0.52750E+04 144 pyrrhotiteFe0.875 -6.00 -8.73 -2.73 -1.003 0.46578E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22426E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23218E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47125E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.33 -2.94 -0.980 0.50182E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.83 -3.86 -1.288 0.65960E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 7999.9990000 g New total amount of reactant added: 8049.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7640E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8049.9990000 Water: Moles liquid = 0.1053E+02 kg liquid = 0.1897E+00 Moles total = -.4540E+02 kg total = -.8179E+00 Activity = 1.0000 Stoichiometric ionic strength = .1221912E-01 Osmotic coef. = 0.9672 True ionic strength = .2106793E-01 Chg. balance for total moles = 0.7640E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91914E-10 -10.0366 0.77024E-10 -10.1134 0.83800E+00 -0.0768 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.72409E-03 -3.1402 0.60300E-03 -3.2197 0.83278E+00 -0.0795 4 SO4-- 0.40796E-11 -11.3894 0.20947E-11 -11.6789 0.51346E+00 -0.2895 5 HCO3- 0.14703E-05 -5.8326 0.12263E-05 -5.9114 0.83404E+00 -0.0788 6 HS- 0.13445E-03 -3.8714 0.11199E-03 -3.9508 0.83291E+00 -0.0794 7 Al+++ 0.11703E-28 -28.9317 0.26345E-29 -29.5793 0.22511E+00 -0.6476 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14880E-06 -6.8274 0.75820E-07 -7.1202 0.50955E+00 -0.2928 10 Mg++ 0.23629E-10 -10.6266 0.11983E-10 -10.9214 0.50714E+00 -0.2949 11 Fe++ 0.64634E-13 -13.1895 0.32816E-13 -13.4839 0.50772E+00 -0.2944 12 K+ 0.16439E-03 -3.7841 0.13714E-03 -3.8628 0.83424E+00 -0.0787 13 Na+ 0.20900E-01 -1.6799 0.17402E-01 -1.7594 0.83262E+00 -0.0796 14 Mn++ 0.20779E-10 -10.6824 0.10559E-10 -10.9764 0.50815E+00 -0.2940 15 HPO4-- 0.47392E-07 -7.3243 0.24337E-07 -7.6137 0.51354E+00 -0.2894 16 HSiO3- 0.10825E-01 -1.9656 0.90148E-02 -2.0450 0.83278E+00 -0.0795 17 Ca(HSiO3)+ 0.18353E-07 -7.7363 0.15314E-07 -7.8149 0.83443E+00 -0.0786 18 Mg(HSiO3)+ 0.36098E-11 -11.4425 0.30121E-11 -11.5211 0.83443E+00 -0.0786 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.68704E-16 -16.1630 0.57329E-16 -16.2416 0.83443E+00 -0.0786 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51944E-05 -5.2845 0.43178E-05 -5.3647 0.83123E+00 -0.0803 24 CH4,aq 0.64571E-04 -4.1900 0.64330E-04 -4.1916 0.99628E+00 -0.0016 25 C2H6,aq 0.65904E-13 -13.1811 0.65659E-13 -13.1827 0.99628E+00 -0.0016 29 CO,aq 0.53313E-16 -16.2732 0.53313E-16 -16.2732 0.10000E+01 0.0000 30 CO2,aq 0.19115E-09 -9.7186 0.19044E-09 -9.7203 0.99628E+00 -0.0016 31 CO3-2 0.28732E-05 -5.5416 0.14720E-05 -5.8321 0.51233E+00 -0.2904 32 CaCO3,aq 0.13669E-08 -8.8642 0.13669E-08 -8.8642 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.28076E-11 -11.5517 0.23427E-11 -11.6303 0.83443E+00 -0.0786 34 CaCl+ 0.87310E-10 -10.0589 0.72854E-10 -10.1375 0.83443E+00 -0.0786 35 CaCl2,aq 0.10229E-13 -13.9902 0.10229E-13 -13.9902 0.10000E+01 0.0000 36 CaOH+ 0.83184E-07 -7.0800 0.69411E-07 -7.1586 0.83443E+00 -0.0786 37 CaSO4,aq 0.49485E-16 -16.3055 0.49485E-16 -16.3055 0.10000E+01 0.0000 38 HCl,aq 0.87363E-14 -14.0587 0.87363E-14 -14.0587 0.10000E+01 0.0000 43 FeCl+ 0.36936E-16 -16.4326 0.30820E-16 -16.5112 0.83443E+00 -0.0786 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16927E-10 -10.7714 0.14125E-10 -10.8500 0.83443E+00 -0.0786 48 HFeO2- 0.36679E-07 -7.4356 0.30546E-07 -7.5151 0.83278E+00 -0.0795 49 FeO+ 0.12494E-16 -16.9033 0.10426E-16 -16.9819 0.83443E+00 -0.0786 51 FeO2- 0.41474E-09 -9.3822 0.34539E-09 -9.4617 0.83278E+00 -0.0795 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10870E-04 -4.9638 0.99628E+00 -0.0016 54 KCl,aq 0.14642E-08 -8.8344 0.14642E-08 -8.8344 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.53145E-14 -14.2745 0.44258E-14 -14.3540 0.83278E+00 -0.0795 58 MgCO3,aq 0.53985E-13 -13.2677 0.53985E-13 -13.2677 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.45249E-15 -15.3444 0.37757E-15 -15.4230 0.83443E+00 -0.0786 60 MgCl+ 0.12527E-13 -13.9021 0.10453E-13 -13.9808 0.83443E+00 -0.0786 61 MgOH+ 0.72835E-10 -10.1377 0.60776E-10 -10.2163 0.83443E+00 -0.0786 63 MnO,aq 0.18788E-08 -8.7261 0.18788E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.50596E-09 -9.2959 0.42219E-09 -9.3745 0.83443E+00 -0.0786 65 MnO2-2 0.21377E-10 -10.6701 0.10952E-10 -10.9605 0.51233E+00 -0.2904 66 HMnO2- 0.21947E-09 -9.6586 0.18277E-09 -9.7381 0.83278E+00 -0.0795 69 MnCl+ 0.46181E-13 -13.3355 0.38534E-13 -13.4142 0.83443E+00 -0.0786 71 NaCl,aq 0.34263E-05 -5.4652 0.34263E-05 -5.4652 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.93688E-02 -2.0283 0.77877E-02 -2.1086 0.83123E+00 -0.0803 79 HPO3-2 0.16309E-14 -14.7876 0.83556E-15 -15.0780 0.51233E+00 -0.2904 81 H2PO3- 0.15180E-18 -18.8187 0.12642E-18 -18.8982 0.83278E+00 -0.0795 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39425E-10 -10.4042 0.32865E-10 -10.4833 0.83359E+00 -0.0790 84 PO4-3 0.11650E-08 -8.9337 0.27594E-09 -9.5592 0.23685E+00 -0.6255 88 HP2O7-3 0.99862E-18 -18.0006 0.22504E-18 -18.6477 0.22535E+00 -0.6471 89 P2O7-4 0.97787E-17 -17.0097 0.72079E-18 -18.1422 0.73710E-01 -1.1325 90 H2S,aq 0.26013E-07 -7.5848 0.25916E-07 -7.5864 0.99628E+00 -0.0016 91 S2-2 0.49530E-13 -13.3051 0.25376E-13 -13.5956 0.51233E+00 -0.2904 97 SO3-2 0.59703E-17 -17.2240 0.31046E-17 -17.5080 0.52001E+00 -0.2840 98 HSO3- 0.16804E-19 -19.7746 0.13994E-19 -19.8541 0.83278E+00 -0.0795 99 HSO4- 0.17923E-18 -18.7466 0.14970E-18 -18.8248 0.83527E+00 -0.0782 Charge balance for all species = 0.4030E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9191361E-10 -.2281192E-01 -.2295099E+02 0.0000 2 H2O 0.1000000E+01 0.5550449E+02 0.9981012E+06 0.0000 3 Cl- 0.7240852E-03 0.7275131E-03 0.2574535E+02 6.8937 4 SO4-- 0.4079646E-11 -.6729822E-04 -.6452951E+01 8.5479 5 HCO3- 0.1470296E-05 0.6891577E-04 0.4197356E+01 4.2020 6 HS- 0.1344545E-03 0.2017787E-03 0.6661021E+01 6.1625 7 Al+++ 0.1170324E-28 0.5194584E-05 0.1399013E+00 0.7608 8 H4SiO4 0.7116652E-03 0.1402813E-01 0.1345854E+04 -3.1477 9 Ca++ 0.1487962E-06 0.2517897E-06 0.1007277E-01 13.1065 10 Mg++ 0.2362873E-10 0.1001410E-09 0.2430175E-05 9.3053 11 Fe++ 0.6463436E-13 0.3733289E-07 0.2081117E-02 6.7428 12 K+ 0.1643880E-03 0.1651656E-03 0.6446494E+01 6.2505 13 Na+ 0.2090007E-01 0.2349430E-01 0.5391413E+03 8.3540 14 Mn++ 0.2077866E-10 0.2646432E-08 0.1451238E-03 9.2504 15 HPO4-- 0.4739154E-07 0.4859602E-07 0.4655667E-02 12.6130 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1332960E+03 -.4326322E-02 -.1332917E+03 0.0000000E+00 2 H2O -.4540179E+02 0.1052653E+02 -.5592832E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2231184E+00 -.1276323E-04 0.2231312E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2230929E+00 0.3826770E-04 -.2231312E+00 0.0000000E+00 7 Al+++ 0.2624897E+02 0.9851623E-06 0.2624897E+02 0.0000000E+00 8 H4SiO4 0.8382289E+02 0.2660461E-02 0.8382023E+02 0.0000000E+00 9 Ca++ 0.9258662E+01 0.4775237E-07 0.9258662E+01 0.0000000E+00 10 Mg++ 0.6388888E+01 0.1899192E-10 0.6388888E+01 0.0000000E+00 11 Fe++ 0.5739718E+01 0.7080251E-08 0.5739718E+01 0.0000000E+00 12 K+ 0.1709129E+01 0.3132396E-04 0.1709098E+01 0.0000000E+00 13 Na+ 0.1010487E+02 0.4455736E-02 0.1010041E+02 0.0000000E+00 14 Mn++ 0.1395757E+00 0.5019006E-09 0.1395757E+00 0.0000000E+00 15 HPO4-- 0.4763649E-01 0.9216323E-08 0.4763648E-01 0.0000000E+00 Chg. balance for solid moles: -.2243E-13 Mass of aqueous solution: 0.189999E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8049.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.09 1.004 2647. 3.423 30.09 1016. andradite 0.8925 -0.049 453.6 2.657 5.157 117.8 grossular 0.2131 -0.671 95.99 1.982 1.091 26.71 apatite-OH 0.1588E-01 -1.799 7.976 0.902 0.9069E-01 2.535 clinochlore 1.146 0.059 637.1 2.804 7.244 242.3 daphnite 0.3285 -0.483 234.4 2.370 2.665 71.03 chlorite-Mn 0.2792E-01 -1.554 19.79 1.296 0.2250 6.307 diopside 0.4561 -0.341 98.78 1.995 1.123 30.19 hedenbergite 0.1169 -0.932 28.99 1.462 0.3297 7.941 microcline 1.497 0.175 416.5 2.620 4.736 162.7 stilbite 5.178 0.714 3649. 3.562 41.49 1702. stilpnomelane-Fe 0.4251 -0.371 458.3 2.661 5.211 158.3 tr.625ac.25prg.125 0.5562E-01 -1.255 47.54 1.677 0.5406 15.30 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8794.852786 g Volume = 3559.254149 cm3 Porosity: -10.5015% V(tot) - V(min): -.33825E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8049.9990000 g log = 3.9058 Original solution: 1000.0103000 g Original solution / Rock added: 0.12 (Water/Rock Ratio), log = -0.9058 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1690 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.9012E+00 0.9840 0.1037E+01 0.1054E+01 CO2,gas 0.1854E-07 1.0061 0.2180E-07 0.2167E-07 CH4,gas 0.8601E-01 1.0118 0.1017E+00 0.1005E+00 H2,gas 0.1275E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.6496E-06 0.9955 0.7559E-06 0.7593E-06 S2,gas 0.8236E-28 1.0000 0.9628E-28 0.9628E-28 CO,gas 0.7201E-13 1.0000 0.8418E-13 0.8418E-13 SO3,gas 0.3974E-47 1.0000 0.4646E-47 0.4646E-47 SO2,gas 0.2242E-26 1.0000 0.2620E-26 0.2620E-26 HCl,gas 0.1320E-16 1.0000 0.1543E-16 0.1543E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.02 -9.66 -3.221 0.16497E+05 -7.662 3 CH4,gas 4.81 1.82 -2.99 -0.748 0.51097E+04 -0.993 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.06 -8.12 -4.061 0.13867E+05 -6.122 6 S2,gas -7.03 -37.05 -30.02 -4.618 0.51252E+05 -28.016 7 CO,gas 3.51 -11.56 -15.07 -4.638 0.25740E+05 -13.075 8 SO3,gas 17.43 -31.91 -49.33 -12.333 0.84235E+05 -47.333 9 SO2,gas 1.14 -27.45 -28.58 -7.622 0.48802E+05 -26.582 10 HCl,gas 5.48 -13.33 -18.81 -9.406 0.32121E+05 -16.812 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80598E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.92 -3.90 -1.301 0.66668E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.92 -3.75 -1.250 0.64054E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65548E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.10 -4.00 -1.142 0.68244E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.10 -3.56 -1.016 0.60706E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82259E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.85 -4.62 -1.087 0.78895E+04 143 pyrrhotite -4.24 -7.32 -3.08 -1.026 0.52553E+04 144 pyrrhotiteFe0.875 -6.00 -8.72 -2.72 -0.999 0.46380E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22426E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23218E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47124E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.32 -2.93 -0.976 0.49985E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.81 -3.85 -1.284 0.65762E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 8049.9990000 g New total amount of reactant added: 8099.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7642E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8099.9990000 Water: Moles liquid = 0.1025E+02 kg liquid = 0.1846E+00 Moles total = -.4603E+02 kg total = -.8292E+00 Activity = 1.0000 Stoichiometric ionic strength = .1223563E-01 Osmotic coef. = 0.9672 True ionic strength = .2108089E-01 Chg. balance for total moles = 0.7642E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.91970E-10 -10.0364 0.77067E-10 -10.1131 0.83797E+00 -0.0768 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.74378E-03 -3.1286 0.61938E-03 -3.2080 0.83275E+00 -0.0795 4 SO4-- 0.41888E-11 -11.3779 0.21504E-11 -11.6675 0.51338E+00 -0.2896 5 HCO3- 0.15096E-05 -5.8211 0.12590E-05 -5.9000 0.83400E+00 -0.0788 6 HS- 0.13811E-03 -3.8598 0.11503E-03 -3.9392 0.83287E+00 -0.0794 7 Al+++ 0.11728E-28 -28.9308 0.26390E-29 -29.5786 0.22503E+00 -0.6478 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14899E-06 -6.8268 0.75906E-07 -7.1197 0.50947E+00 -0.2929 10 Mg++ 0.23660E-10 -10.6260 0.11997E-10 -10.9209 0.50706E+00 -0.2949 11 Fe++ 0.64719E-13 -13.1890 0.32853E-13 -13.4834 0.50763E+00 -0.2945 12 K+ 0.16449E-03 -3.7839 0.13722E-03 -3.8626 0.83421E+00 -0.0787 13 Na+ 0.20913E-01 -1.6796 0.17412E-01 -1.7592 0.83258E+00 -0.0796 14 Mn++ 0.20806E-10 -10.6818 0.10571E-10 -10.9759 0.50807E+00 -0.2941 15 HPO4-- 0.47345E-07 -7.3247 0.24310E-07 -7.6142 0.51345E+00 -0.2895 16 HSiO3- 0.10819E-01 -1.9658 0.90096E-02 -2.0453 0.83275E+00 -0.0795 17 Ca(HSiO3)+ 0.18364E-07 -7.7360 0.15323E-07 -7.8147 0.83439E+00 -0.0786 18 Mg(HSiO3)+ 0.36120E-11 -11.4422 0.30139E-11 -11.5209 0.83439E+00 -0.0786 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.68746E-16 -16.1628 0.57361E-16 -16.2414 0.83439E+00 -0.0786 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51917E-05 -5.2847 0.43153E-05 -5.3650 0.83120E+00 -0.0803 24 CH4,aq 0.66331E-04 -4.1783 0.66084E-04 -4.1799 0.99627E+00 -0.0016 25 C2H6,aq 0.69546E-13 -13.1577 0.69287E-13 -13.1593 0.99627E+00 -0.0016 29 CO,aq 0.54766E-16 -16.2615 0.54766E-16 -16.2615 0.10000E+01 0.0000 30 CO2,aq 0.19636E-09 -9.7070 0.19563E-09 -9.7086 0.99627E+00 -0.0016 31 CO3-2 0.29486E-05 -5.5304 0.15104E-05 -5.8209 0.51225E+00 -0.2905 32 CaCO3,aq 0.14042E-08 -8.8526 0.14042E-08 -8.8526 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.28859E-11 -11.5397 0.24080E-11 -11.6184 0.83439E+00 -0.0786 34 CaCl+ 0.89787E-10 -10.0468 0.74918E-10 -10.1254 0.83439E+00 -0.0786 35 CaCl2,aq 0.10804E-13 -13.9664 0.10804E-13 -13.9664 0.10000E+01 0.0000 36 CaOH+ 0.83235E-07 -7.0797 0.69450E-07 -7.1583 0.83439E+00 -0.0786 37 CaSO4,aq 0.50859E-16 -16.2936 0.50859E-16 -16.2936 0.10000E+01 0.0000 38 HCl,aq 0.89787E-14 -14.0468 0.89787E-14 -14.0468 0.10000E+01 0.0000 43 FeCl+ 0.37984E-16 -16.4204 0.31694E-16 -16.4990 0.83439E+00 -0.0786 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16938E-10 -10.7711 0.14133E-10 -10.8498 0.83439E+00 -0.0786 48 HFeO2- 0.36660E-07 -7.4358 0.30528E-07 -7.5153 0.83275E+00 -0.0795 49 FeO+ 0.12502E-16 -16.9030 0.10432E-16 -16.9817 0.83439E+00 -0.0786 51 FeO2- 0.41452E-09 -9.3825 0.34519E-09 -9.4619 0.83275E+00 -0.0795 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10870E-04 -4.9638 0.99627E+00 -0.0016 54 KCl,aq 0.15049E-08 -8.8225 0.15049E-08 -8.8225 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.54591E-14 -14.2629 0.45460E-14 -14.3424 0.83275E+00 -0.0795 58 MgCO3,aq 0.55456E-13 -13.2560 0.55456E-13 -13.2560 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.46511E-15 -15.3324 0.38808E-15 -15.4111 0.83439E+00 -0.0786 60 MgCl+ 0.12883E-13 -13.8900 0.10749E-13 -13.9686 0.83439E+00 -0.0786 61 MgOH+ 0.72880E-10 -10.1374 0.60810E-10 -10.2160 0.83439E+00 -0.0786 63 MnO,aq 0.18788E-08 -8.7261 0.18788E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.50627E-09 -9.2956 0.42243E-09 -9.3742 0.83439E+00 -0.0786 65 MnO2-2 0.21356E-10 -10.6705 0.10940E-10 -10.9610 0.51225E+00 -0.2905 66 HMnO2- 0.21936E-09 -9.6588 0.18267E-09 -9.7383 0.83275E+00 -0.0795 69 MnCl+ 0.47491E-13 -13.3234 0.39626E-13 -13.4020 0.83439E+00 -0.0786 71 NaCl,aq 0.35214E-05 -5.4533 0.35214E-05 -5.4533 0.10000E+01 0.0000 72 NaOH,aq 0.99275E-04 -4.0032 0.99275E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.93639E-02 -2.0285 0.77832E-02 -2.1088 0.83120E+00 -0.0803 79 HPO3-2 0.16293E-14 -14.7880 0.83461E-15 -15.0785 0.51225E+00 -0.2905 81 H2PO3- 0.15172E-18 -18.8189 0.12635E-18 -18.8984 0.83275E+00 -0.0795 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39404E-10 -10.4045 0.32846E-10 -10.4835 0.83356E+00 -0.0791 84 PO4-3 0.11635E-08 -8.9342 0.27547E-09 -9.5599 0.23677E+00 -0.6257 88 HP2O7-3 0.99728E-18 -18.0012 0.22466E-18 -18.6485 0.22527E+00 -0.6473 89 P2O7-4 0.97628E-17 -17.0104 0.71915E-18 -18.1432 0.73662E-01 -1.1328 90 H2S,aq 0.26735E-07 -7.5729 0.26636E-07 -7.5745 0.99627E+00 -0.0016 91 S2-2 0.52266E-13 -13.2818 0.26773E-13 -13.5723 0.51225E+00 -0.2905 97 SO3-2 0.61299E-17 -17.2125 0.31871E-17 -17.4966 0.51992E+00 -0.2841 98 HSO3- 0.17261E-19 -19.7629 0.14374E-19 -19.8424 0.83275E+00 -0.0795 99 HSO4- 0.18411E-18 -18.7349 0.15377E-18 -18.8131 0.83524E+00 -0.0782 Charge balance for all species = 0.4138E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9196958E-10 -.2280133E-01 -.2294033E+02 0.0000 2 H2O 0.1000000E+01 0.5550449E+02 0.9981006E+06 0.0000 3 Cl- 0.7437842E-03 0.7473072E-03 0.2644581E+02 6.9051 4 SO4-- 0.4188766E-11 -.6905853E-04 -.6621736E+01 8.5588 5 HCO3- 0.1509574E-05 0.7079082E-04 0.4311555E+01 4.2132 6 HS- 0.1381127E-03 0.2071980E-03 0.6839914E+01 6.1739 7 Al+++ 0.1172764E-28 0.5191845E-05 0.1398275E+00 0.7608 8 H4SiO4 0.7116652E-03 0.1402242E-01 0.1345304E+04 -3.1477 9 Ca++ 0.1489907E-06 0.2520860E-06 0.1008462E-01 13.1065 10 Mg++ 0.2365967E-10 0.1002246E-09 0.2432202E-05 9.3053 11 Fe++ 0.6471897E-13 0.3731331E-07 0.2080024E-02 6.7428 12 K+ 0.1644884E-03 0.1652661E-03 0.6450412E+01 6.2505 13 Na+ 0.2091286E-01 0.2350718E-01 0.5394367E+03 8.3540 14 Mn++ 0.2080600E-10 0.2646651E-08 0.1451357E-03 9.2504 15 HPO4-- 0.4734526E-07 0.4854813E-07 0.4651076E-02 12.6120 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1341239E+03 -.4209775E-02 -.1341197E+03 0.0000000E+00 2 H2O -.4602856E+02 0.1024771E+02 -.5627627E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2245041E+00 -.1275017E-04 0.2245168E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2244786E+00 0.3825464E-04 -.2245168E+00 0.0000000E+00 7 Al+++ 0.2641200E+02 0.9585624E-06 0.2641200E+02 0.0000000E+00 8 H4SiO4 0.8434353E+02 0.2588937E-02 0.8434094E+02 0.0000000E+00 9 Ca++ 0.9316169E+01 0.4654225E-07 0.9316169E+01 0.0000000E+00 10 Mg++ 0.6428571E+01 0.1850431E-10 0.6428571E+01 0.0000000E+00 11 Fe++ 0.5775369E+01 0.6889099E-08 0.5775369E+01 0.0000000E+00 12 K+ 0.1719745E+01 0.3051283E-04 0.1719714E+01 0.0000000E+00 13 Na+ 0.1016763E+02 0.4340095E-02 0.1016329E+02 0.0000000E+00 14 Mn++ 0.1404426E+00 0.4886472E-09 0.1404426E+00 0.0000000E+00 15 HPO4-- 0.4793236E-01 0.8963366E-08 0.4793236E-01 0.0000000E+00 Chg. balance for solid moles: 0.2287E-13 Mass of aqueous solution: 0.184967E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8099.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.16 1.007 2663. 3.425 30.09 1022. andradite 0.8981 -0.047 456.4 2.659 5.157 118.6 grossular 0.2144 -0.669 96.58 1.985 1.091 26.87 apatite-OH 0.1598E-01 -1.796 8.026 0.904 0.9069E-01 2.550 clinochlore 1.153 0.062 641.1 2.807 7.244 243.8 daphnite 0.3305 -0.481 235.9 2.373 2.665 71.47 chlorite-Mn 0.2809E-01 -1.551 19.91 1.299 0.2250 6.346 diopside 0.4590 -0.338 99.41 1.997 1.123 30.38 hedenbergite 0.1176 -0.930 29.18 1.465 0.3297 7.991 microcline 1.506 0.178 419.1 2.622 4.736 163.7 stilbite 5.210 0.717 3672. 3.565 41.49 1713. stilpnomelane-Fe 0.4278 -0.369 461.1 2.664 5.211 159.3 tr.625ac.25prg.125 0.5596E-01 -1.252 47.84 1.680 0.5406 15.40 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8849.480525 g Volume = 3581.357327 cm3 Porosity: -10.5016% V(tot) - V(min): -.34036E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8099.9990000 g log = 3.9085 Original solution: 1000.0103000 g Original solution / Rock added: 0.12 (Water/Rock Ratio), log = -0.9085 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1717 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8991E+00 0.9840 0.1037E+01 0.1054E+01 CO2,gas 0.1900E-07 1.0060 0.2239E-07 0.2226E-07 CH4,gas 0.8815E-01 1.0118 0.1045E+00 0.1033E+00 H2,gas 0.1272E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.6660E-06 0.9954 0.7768E-06 0.7804E-06 S2,gas 0.8679E-28 1.0000 0.1017E-27 0.1017E-27 CO,gas 0.7380E-13 1.0000 0.8648E-13 0.8648E-13 SO3,gas 0.4075E-47 1.0000 0.4775E-47 0.4775E-47 SO2,gas 0.2298E-26 1.0000 0.2693E-26 0.2693E-26 HCl,gas 0.1353E-16 1.0000 0.1585E-16 0.1585E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.01 -9.65 -3.217 0.16477E+05 -7.650 3 CH4,gas 4.81 1.83 -2.98 -0.745 0.50898E+04 -0.981 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.05 -8.11 -4.055 0.13847E+05 -6.110 6 S2,gas -7.03 -37.03 -29.99 -4.614 0.51212E+05 -27.993 7 CO,gas 3.51 -11.55 -15.06 -4.635 0.25720E+05 -13.063 8 SO3,gas 17.43 -31.89 -49.32 -12.330 0.84214E+05 -47.321 9 SO2,gas 1.14 -27.43 -28.57 -7.619 0.48782E+05 -26.570 10 HCl,gas 5.48 -13.32 -18.80 -9.400 0.32100E+05 -16.800 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80598E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.91 -3.89 -1.298 0.66468E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.91 -3.74 -1.247 0.63855E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65548E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.09 -3.99 -1.139 0.68044E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.09 -3.54 -1.012 0.60506E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82259E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.82 -4.60 -1.082 0.78489E+04 143 pyrrhotite -4.24 -7.31 -3.07 -1.022 0.52350E+04 144 pyrrhotiteFe0.875 -6.00 -8.71 -2.70 -0.995 0.46177E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22426E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23218E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47124E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.31 -2.92 -0.972 0.49782E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.80 -3.84 -1.280 0.65559E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 8099.9990000 g New total amount of reactant added: 8149.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7636E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8149.9990000 Water: Moles liquid = 0.9970E+01 kg liquid = 0.1796E+00 Moles total = -.4666E+02 kg total = -.8405E+00 Activity = 1.0000 Stoichiometric ionic strength = .1225306E-01 Osmotic coef. = 0.9671 True ionic strength = .2109459E-01 Chg. balance for total moles = 0.7636E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92029E-10 -10.0361 0.77114E-10 -10.1129 0.83793E+00 -0.0768 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.76458E-03 -3.1166 0.63668E-03 -3.1961 0.83271E+00 -0.0795 4 SO4-- 0.43039E-11 -11.3661 0.22091E-11 -11.6558 0.51329E+00 -0.2896 5 HCO3- 0.15510E-05 -5.8094 0.12935E-05 -5.8882 0.83397E+00 -0.0789 6 HS- 0.14198E-03 -3.8478 0.11824E-03 -3.9272 0.83283E+00 -0.0794 7 Al+++ 0.11753E-28 -28.9298 0.26438E-29 -29.5778 0.22494E+00 -0.6479 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14920E-06 -6.8262 0.75997E-07 -7.1192 0.50938E+00 -0.2930 10 Mg++ 0.23692E-10 -10.6254 0.12011E-10 -10.9204 0.50697E+00 -0.2950 11 Fe++ 0.64808E-13 -13.1884 0.32893E-13 -13.4829 0.50754E+00 -0.2945 12 K+ 0.16459E-03 -3.7836 0.13730E-03 -3.8623 0.83417E+00 -0.0787 13 Na+ 0.20926E-01 -1.6793 0.17422E-01 -1.7589 0.83255E+00 -0.0796 14 Mn++ 0.20835E-10 -10.6812 0.10584E-10 -10.9754 0.50798E+00 -0.2942 15 HPO4-- 0.47296E-07 -7.3252 0.24280E-07 -7.6147 0.51336E+00 -0.2896 16 HSiO3- 0.10813E-01 -1.9660 0.90042E-02 -2.0456 0.83271E+00 -0.0795 17 Ca(HSiO3)+ 0.18376E-07 -7.7358 0.15332E-07 -7.8144 0.83436E+00 -0.0786 18 Mg(HSiO3)+ 0.36144E-11 -11.4420 0.30157E-11 -11.5206 0.83436E+00 -0.0786 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.68791E-16 -16.1625 0.57396E-16 -16.2411 0.83436E+00 -0.0786 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51888E-05 -5.2849 0.43127E-05 -5.3652 0.83116E+00 -0.0803 24 CH4,aq 0.68190E-04 -4.1663 0.67936E-04 -4.1679 0.99627E+00 -0.0016 25 C2H6,aq 0.73498E-13 -13.1337 0.73224E-13 -13.1353 0.99627E+00 -0.0016 29 CO,aq 0.56301E-16 -16.2495 0.56301E-16 -16.2495 0.10000E+01 0.0000 30 CO2,aq 0.20186E-09 -9.6949 0.20111E-09 -9.6966 0.99627E+00 -0.0016 31 CO3-2 0.30281E-05 -5.5188 0.15509E-05 -5.8094 0.51216E+00 -0.2906 32 CaCO3,aq 0.14436E-08 -8.8406 0.14436E-08 -8.8406 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.29687E-11 -11.5274 0.24769E-11 -11.6061 0.83436E+00 -0.0786 34 CaCl+ 0.92409E-10 -10.0343 0.77102E-10 -10.1129 0.83436E+00 -0.0786 35 CaCl2,aq 0.11430E-13 -13.9420 0.11430E-13 -13.9420 0.10000E+01 0.0000 36 CaOH+ 0.83288E-07 -7.0794 0.69492E-07 -7.1581 0.83436E+00 -0.0786 37 CaSO4,aq 0.52310E-16 -16.2814 0.52310E-16 -16.2814 0.10000E+01 0.0000 38 HCl,aq 0.92349E-14 -14.0346 0.92349E-14 -14.0346 0.10000E+01 0.0000 43 FeCl+ 0.39093E-16 -16.4079 0.32618E-16 -16.4865 0.83436E+00 -0.0786 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16949E-10 -10.7709 0.14141E-10 -10.8495 0.83436E+00 -0.0786 48 HFeO2- 0.36639E-07 -7.4361 0.30510E-07 -7.5156 0.83271E+00 -0.0795 49 FeO+ 0.12510E-16 -16.9027 0.10438E-16 -16.9814 0.83436E+00 -0.0786 51 FeO2- 0.41429E-09 -9.3827 0.34498E-09 -9.4622 0.83271E+00 -0.0795 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10870E-04 -4.9638 0.99627E+00 -0.0016 54 KCl,aq 0.15478E-08 -8.8103 0.15478E-08 -8.8103 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.56118E-14 -14.2509 0.46730E-14 -14.3304 0.83271E+00 -0.0795 58 MgCO3,aq 0.57010E-13 -13.2440 0.57010E-13 -13.2440 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.47845E-15 -15.3202 0.39920E-15 -15.3988 0.83436E+00 -0.0786 60 MgCl+ 0.13259E-13 -13.8775 0.11063E-13 -13.9561 0.83436E+00 -0.0786 61 MgOH+ 0.72927E-10 -10.1371 0.60847E-10 -10.2158 0.83436E+00 -0.0786 63 MnO,aq 0.18788E-08 -8.7261 0.18788E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.50660E-09 -9.2953 0.42269E-09 -9.3740 0.83436E+00 -0.0786 65 MnO2-2 0.21335E-10 -10.6709 0.10927E-10 -10.9615 0.51216E+00 -0.2906 66 HMnO2- 0.21924E-09 -9.6591 0.18256E-09 -9.7386 0.83271E+00 -0.0795 69 MnCl+ 0.48879E-13 -13.3109 0.40782E-13 -13.3895 0.83436E+00 -0.0786 71 NaCl,aq 0.36219E-05 -5.4411 0.36219E-05 -5.4411 0.10000E+01 0.0000 72 NaOH,aq 0.99274E-04 -4.0032 0.99274E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.93587E-02 -2.0288 0.77786E-02 -2.1091 0.83116E+00 -0.0803 79 HPO3-2 0.16276E-14 -14.7884 0.83360E-15 -15.0790 0.51216E+00 -0.2906 81 H2PO3- 0.15164E-18 -18.8192 0.12627E-18 -18.8987 0.83271E+00 -0.0795 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39382E-10 -10.4047 0.32826E-10 -10.4838 0.83352E+00 -0.0791 84 PO4-3 0.11618E-08 -8.9349 0.27497E-09 -9.5607 0.23668E+00 -0.6258 88 HP2O7-3 0.99588E-18 -18.0018 0.22425E-18 -18.6493 0.22518E+00 -0.6475 89 P2O7-4 0.97460E-17 -17.0112 0.71742E-18 -18.1442 0.73612E-01 -1.1331 90 H2S,aq 0.27498E-07 -7.5607 0.27396E-07 -7.5623 0.99627E+00 -0.0016 91 S2-2 0.55235E-13 -13.2578 0.28289E-13 -13.5484 0.51216E+00 -0.2906 97 SO3-2 0.62983E-17 -17.2008 0.32741E-17 -17.4849 0.51984E+00 -0.2841 98 HSO3- 0.17744E-19 -19.7510 0.14776E-19 -19.8305 0.83271E+00 -0.0795 99 HSO4- 0.18925E-18 -18.7230 0.15807E-18 -18.8012 0.83520E+00 -0.0782 Charge balance for all species = 0.4252E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9202871E-10 -.2279016E-01 -.2292907E+02 0.0000 2 H2O 0.1000000E+01 0.5550449E+02 0.9981000E+06 0.0000 3 Cl- 0.7645850E-03 0.7682086E-03 0.2718545E+02 6.9168 4 SO4-- 0.4303883E-11 -.7091750E-04 -.6799981E+01 8.5700 5 HCO3- 0.1551007E-05 0.7277076E-04 0.4432141E+01 4.2246 6 HS- 0.1419755E-03 0.2129205E-03 0.7028820E+01 6.1856 7 Al+++ 0.1175345E-28 0.5188955E-05 0.1397495E+00 0.7608 8 H4SiO4 0.7116652E-03 0.1401639E-01 0.1344725E+04 -3.1477 9 Ca++ 0.1491964E-06 0.2523992E-06 0.1009714E-01 13.1065 10 Mg++ 0.2369239E-10 0.1003128E-09 0.2434342E-05 9.3053 11 Fe++ 0.6480841E-13 0.3729266E-07 0.2078871E-02 6.7428 12 K+ 0.1645945E-03 0.1653723E-03 0.6454551E+01 6.2505 13 Na+ 0.2092637E-01 0.2352079E-01 0.5397487E+03 8.3540 14 Mn++ 0.2083490E-10 0.2646883E-08 0.1451483E-03 9.2504 15 HPO4-- 0.4729644E-07 0.4849762E-07 0.4646233E-02 12.6110 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1349519E+03 -.4093229E-02 -.1349478E+03 0.0000000E+00 2 H2O -.4665533E+02 0.9968891E+01 -.5662422E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2258898E+00 -.1273715E-04 0.2259025E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2258643E+00 0.3824162E-04 -.2259025E+00 0.0000000E+00 7 Al+++ 0.2657504E+02 0.9319628E-06 0.2657504E+02 0.0000000E+00 8 H4SiO4 0.8486417E+02 0.2517415E-02 0.8486165E+02 0.0000000E+00 9 Ca++ 0.9373676E+01 0.4533219E-07 0.9373676E+01 0.0000000E+00 10 Mg++ 0.6468253E+01 0.1801670E-10 0.6468253E+01 0.0000000E+00 11 Fe++ 0.5811019E+01 0.6697952E-08 0.5811019E+01 0.0000000E+00 12 K+ 0.1730361E+01 0.2970170E-04 0.1730331E+01 0.0000000E+00 13 Na+ 0.1023039E+02 0.4224455E-02 0.1022617E+02 0.0000000E+00 14 Mn++ 0.1413095E+00 0.4753936E-09 0.1413095E+00 0.0000000E+00 15 HPO4-- 0.4822824E-01 0.8710420E-08 0.4822823E-01 0.0000000E+00 Chg. balance for solid moles: 0.1132E-13 Mass of aqueous solution: 0.179934E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8149.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.22 1.009 2680. 3.428 30.09 1029. andradite 0.9036 -0.044 459.2 2.662 5.157 119.3 grossular 0.2157 -0.666 97.18 1.988 1.091 27.04 apatite-OH 0.1608E-01 -1.794 8.075 0.907 0.9069E-01 2.566 clinochlore 1.160 0.065 645.0 2.810 7.244 245.3 daphnite 0.3326 -0.478 237.3 2.375 2.665 71.91 chlorite-Mn 0.2826E-01 -1.549 20.04 1.302 0.2250 6.385 diopside 0.4619 -0.335 100.0 2.000 1.123 30.57 hedenbergite 0.1183 -0.927 29.36 1.468 0.3297 8.042 microcline 1.515 0.180 421.7 2.625 4.736 164.7 stilbite 5.242 0.720 3694. 3.568 41.49 1723. stilpnomelane-Fe 0.4304 -0.366 464.0 2.667 5.211 160.3 tr.625ac.25prg.125 0.5631E-01 -1.249 48.13 1.682 0.5405 15.49 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8904.108264 g Volume = 3603.460504 cm3 Porosity: -10.5017% V(tot) - V(min): -.34246E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8149.9990000 g log = 3.9112 Original solution: 1000.0103000 g Original solution / Rock added: 0.12 (Water/Rock Ratio), log = -0.9112 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1747 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8969E+00 0.9840 0.1037E+01 0.1054E+01 CO2,gas 0.1948E-07 1.0060 0.2302E-07 0.2288E-07 CH4,gas 0.9039E-01 1.0118 0.1074E+00 0.1062E+00 H2,gas 0.1268E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.6833E-06 0.9954 0.7990E-06 0.8027E-06 S2,gas 0.9159E-28 1.0000 0.1076E-27 0.1076E-27 CO,gas 0.7568E-13 1.0000 0.8890E-13 0.8890E-13 SO3,gas 0.4181E-47 1.0000 0.4911E-47 0.4911E-47 SO2,gas 0.2358E-26 1.0000 0.2770E-26 0.2770E-26 HCl,gas 0.1388E-16 1.0000 0.1631E-16 0.1631E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.18198E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.66728E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -16.00 -9.64 -3.213 0.16456E+05 -7.638 3 CH4,gas 4.81 1.84 -2.97 -0.742 0.50693E+04 -0.969 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65337E+04 -1.827 5 H2S,gas -5.94 -14.04 -8.10 -4.049 0.13826E+05 -6.097 6 S2,gas -7.03 -37.00 -29.97 -4.611 0.51170E+05 -27.968 7 CO,gas 3.51 -11.54 -15.05 -4.631 0.25699E+05 -13.051 8 SO3,gas 17.43 -31.88 -49.31 -12.327 0.84193E+05 -47.309 9 SO2,gas 1.14 -27.42 -28.56 -7.615 0.48761E+05 -26.558 10 HCl,gas 5.48 -13.31 -18.79 -9.394 0.32079E+05 -16.788 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80597E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.89 -3.88 -1.294 0.66263E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.89 -3.73 -1.243 0.63650E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65548E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.08 -3.97 -1.135 0.67840E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.08 -3.53 -1.009 0.60301E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82259E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.80 -4.57 -1.076 0.78072E+04 143 pyrrhotite -4.24 -7.30 -3.05 -1.018 0.52141E+04 144 pyrrhotiteFe0.875 -6.00 -8.69 -2.69 -0.990 0.45969E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22426E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23218E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47124E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.30 -2.90 -0.968 0.49573E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.79 -3.83 -1.276 0.65351E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 8149.9990000 g New total amount of reactant added: 8199.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7638E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8199.9990000 Water: Moles liquid = 0.9691E+01 kg liquid = 0.1746E+00 Moles total = -.4728E+02 kg total = -.8518E+00 Activity = 1.0000 Stoichiometric ionic strength = .1227150E-01 Osmotic coef. = 0.9671 True ionic strength = .2110909E-01 Chg. balance for total moles = 0.7638E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92091E-10 -10.0358 0.77163E-10 -10.1126 0.83790E+00 -0.0768 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.78658E-03 -3.1043 0.65496E-03 -3.1838 0.83267E+00 -0.0795 4 SO4-- 0.44255E-11 -11.3540 0.22711E-11 -11.6438 0.51320E+00 -0.2897 5 HCO3- 0.15948E-05 -5.7973 0.13299E-05 -5.8762 0.83393E+00 -0.0789 6 HS- 0.14606E-03 -3.8355 0.12164E-03 -3.9149 0.83280E+00 -0.0795 7 Al+++ 0.11781E-28 -28.9288 0.26489E-29 -29.5769 0.22485E+00 -0.6481 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14941E-06 -6.8256 0.76094E-07 -7.1186 0.50928E+00 -0.2930 10 Mg++ 0.23727E-10 -10.6248 0.12027E-10 -10.9199 0.50687E+00 -0.2951 11 Fe++ 0.64903E-13 -13.1877 0.32935E-13 -13.4823 0.50745E+00 -0.2946 12 K+ 0.16471E-03 -3.7833 0.13739E-03 -3.8621 0.83413E+00 -0.0788 13 Na+ 0.20941E-01 -1.6790 0.17433E-01 -1.7586 0.83251E+00 -0.0796 14 Mn++ 0.20865E-10 -10.6806 0.10597E-10 -10.9748 0.50788E+00 -0.2942 15 HPO4-- 0.47245E-07 -7.3256 0.24249E-07 -7.6153 0.51327E+00 -0.2897 16 HSiO3- 0.10807E-01 -1.9663 0.89985E-02 -2.0458 0.83267E+00 -0.0795 17 Ca(HSiO3)+ 0.18388E-07 -7.7355 0.15342E-07 -7.8141 0.83432E+00 -0.0787 18 Mg(HSiO3)+ 0.36168E-11 -11.4417 0.30176E-11 -11.5203 0.83432E+00 -0.0787 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.68838E-16 -16.1622 0.57432E-16 -16.2408 0.83432E+00 -0.0787 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51858E-05 -5.2852 0.43100E-05 -5.3655 0.83112E+00 -0.0803 24 CH4,aq 0.70156E-04 -4.1539 0.69894E-04 -4.1556 0.99626E+00 -0.0016 25 C2H6,aq 0.77798E-13 -13.1090 0.77507E-13 -13.1107 0.99626E+00 -0.0016 29 CO,aq 0.57924E-16 -16.2371 0.57924E-16 -16.2371 0.10000E+01 0.0000 30 CO2,aq 0.20768E-09 -9.6826 0.20691E-09 -9.6842 0.99626E+00 -0.0016 31 CO3-2 0.31121E-05 -5.5070 0.15936E-05 -5.7976 0.51207E+00 -0.2907 32 CaCO3,aq 0.14852E-08 -8.8282 0.14852E-08 -8.8282 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.30563E-11 -11.5148 0.25499E-11 -11.5935 0.83432E+00 -0.0787 34 CaCl+ 0.95189E-10 -10.0214 0.79418E-10 -10.1001 0.83432E+00 -0.0787 35 CaCl2,aq 0.12111E-13 -13.9168 0.12111E-13 -13.9168 0.10000E+01 0.0000 36 CaOH+ 0.83345E-07 -7.0791 0.69536E-07 -7.1578 0.83432E+00 -0.0787 37 CaSO4,aq 0.53847E-16 -16.2688 0.53847E-16 -16.2688 0.10000E+01 0.0000 38 HCl,aq 0.95062E-14 -14.0220 0.95062E-14 -14.0220 0.10000E+01 0.0000 43 FeCl+ 0.40269E-16 -16.3950 0.33597E-16 -16.4737 0.83432E+00 -0.0787 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16960E-10 -10.7706 0.14150E-10 -10.8492 0.83432E+00 -0.0787 48 HFeO2- 0.36618E-07 -7.4363 0.30490E-07 -7.5158 0.83267E+00 -0.0795 49 FeO+ 0.12519E-16 -16.9024 0.10444E-16 -16.9811 0.83432E+00 -0.0787 51 FeO2- 0.41405E-09 -9.3830 0.34476E-09 -9.4625 0.83267E+00 -0.0795 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10910E-04 -4.9622 0.10870E-04 -4.9638 0.99626E+00 -0.0016 54 KCl,aq 0.15933E-08 -8.7977 0.15933E-08 -8.7977 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.57733E-14 -14.2386 0.48072E-14 -14.3181 0.83267E+00 -0.0795 58 MgCO3,aq 0.58654E-13 -13.2317 0.58654E-13 -13.2317 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.49258E-15 -15.3075 0.41097E-15 -15.3862 0.83432E+00 -0.0787 60 MgCl+ 0.13658E-13 -13.8646 0.11395E-13 -13.9433 0.83432E+00 -0.0787 61 MgOH+ 0.72976E-10 -10.1368 0.60886E-10 -10.2155 0.83432E+00 -0.0787 63 MnO,aq 0.18788E-08 -8.7261 0.18788E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.50695E-09 -9.2950 0.42296E-09 -9.3737 0.83432E+00 -0.0787 65 MnO2-2 0.21312E-10 -10.6714 0.10913E-10 -10.9621 0.51207E+00 -0.2907 66 HMnO2- 0.21911E-09 -9.6593 0.18245E-09 -9.7389 0.83267E+00 -0.0795 69 MnCl+ 0.50349E-13 -13.2980 0.42007E-13 -13.3767 0.83432E+00 -0.0787 71 NaCl,aq 0.37283E-05 -5.4285 0.37283E-05 -5.4285 0.10000E+01 0.0000 72 NaOH,aq 0.99274E-04 -4.0032 0.99274E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.93532E-02 -2.0290 0.77736E-02 -2.1094 0.83112E+00 -0.0803 79 HPO3-2 0.16259E-14 -14.7889 0.83254E-15 -15.0796 0.51207E+00 -0.2907 81 H2PO3- 0.15155E-18 -18.8194 0.12619E-18 -18.8990 0.83267E+00 -0.0795 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39359E-10 -10.4050 0.32805E-10 -10.4841 0.83349E+00 -0.0791 84 PO4-3 0.11600E-08 -8.9355 0.27445E-09 -9.5615 0.23659E+00 -0.6260 88 HP2O7-3 0.99439E-18 -18.0024 0.22383E-18 -18.6501 0.22509E+00 -0.6476 89 P2O7-4 0.97283E-17 -17.0120 0.71560E-18 -18.1453 0.73559E-01 -1.1334 90 H2S,aq 0.28307E-07 -7.5481 0.28201E-07 -7.5497 0.99626E+00 -0.0016 91 S2-2 0.58465E-13 -13.2331 0.29938E-13 -13.5238 0.51207E+00 -0.2907 97 SO3-2 0.64763E-17 -17.1887 0.33660E-17 -17.4729 0.51975E+00 -0.2842 98 HSO3- 0.18254E-19 -19.7386 0.15200E-19 -19.8182 0.83267E+00 -0.0795 99 HSO4- 0.19470E-18 -18.7106 0.16261E-18 -18.7889 0.83516E+00 -0.0782 Charge balance for all species = 0.4378E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9209128E-10 -.2277835E-01 -.2291717E+02 0.0000 2 H2O 0.1000000E+01 0.5550450E+02 0.9980993E+06 0.0000 3 Cl- 0.7865827E-03 0.7903127E-03 0.2796766E+02 6.9288 4 SO4-- 0.4425505E-11 -.7288368E-04 -.6988504E+01 8.5814 5 HCO3- 0.1594779E-05 0.7486464E-04 0.4559667E+01 4.2364 6 HS- 0.1460607E-03 0.2189727E-03 0.7228604E+01 6.1977 7 Al+++ 0.1178081E-28 0.5185901E-05 0.1396672E+00 0.7608 8 H4SiO4 0.7116652E-03 0.1401001E-01 0.1344113E+04 -3.1477 9 Ca++ 0.1494141E-06 0.2527308E-06 0.1011040E-01 13.1065 10 Mg++ 0.2372703E-10 0.1004011E-09 0.2436482E-05 9.3053 11 Fe++ 0.6490313E-13 0.3727083E-07 0.2077653E-02 6.7428 12 K+ 0.1647068E-03 0.1654846E-03 0.6458931E+01 6.2505 13 Na+ 0.2094067E-01 0.2353520E-01 0.5400789E+03 8.3540 14 Mn++ 0.2086548E-10 0.2647126E-08 0.1451615E-03 9.2504 15 HPO4-- 0.4724488E-07 0.4844427E-07 0.4641119E-02 12.6099 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1357798E+03 -.3976684E-02 -.1357758E+03 0.0000000E+00 2 H2O -.4728210E+02 0.9690072E+01 -.5697217E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2272754E+00 -.1272416E-04 0.2272882E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2272499E+00 0.3822863E-04 -.2272882E+00 0.0000000E+00 7 Al+++ 0.2673808E+02 0.9053636E-06 0.2673808E+02 0.0000000E+00 8 H4SiO4 0.8538481E+02 0.2445893E-02 0.8538236E+02 0.0000000E+00 9 Ca++ 0.9431183E+01 0.4412219E-07 0.9431183E+01 0.0000000E+00 10 Mg++ 0.6507936E+01 0.1752820E-10 0.6507936E+01 0.0000000E+00 11 Fe++ 0.5846670E+01 0.6506807E-08 0.5846670E+01 0.0000000E+00 12 K+ 0.1740976E+01 0.2889059E-04 0.1740948E+01 0.0000000E+00 13 Na+ 0.1029316E+02 0.4108816E-02 0.1028905E+02 0.0000000E+00 14 Mn++ 0.1421765E+00 0.4621399E-09 0.1421765E+00 0.0000000E+00 15 HPO4-- 0.4852412E-01 0.8457485E-08 0.4852411E-01 0.0000000E+00 Chg. balance for solid moles: -.2850E-13 Mass of aqueous solution: 0.174902E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8199.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.28 1.012 2696. 3.431 30.10 1035. andradite 0.9092 -0.041 462.0 2.665 5.157 120.0 grossular 0.2171 -0.663 97.77 1.990 1.091 27.20 apatite-OH 0.1617E-01 -1.791 8.125 0.910 0.9069E-01 2.582 clinochlore 1.168 0.067 649.0 2.812 7.244 246.8 daphnite 0.3346 -0.475 238.8 2.378 2.665 72.35 chlorite-Mn 0.2844E-01 -1.546 20.16 1.304 0.2250 6.424 diopside 0.4648 -0.333 100.7 2.003 1.124 30.76 hedenbergite 0.1191 -0.924 29.54 1.470 0.3298 8.092 microcline 1.524 0.183 424.3 2.628 4.736 165.7 stilbite 5.274 0.722 3717. 3.570 41.49 1734. stilpnomelane-Fe 0.4331 -0.363 466.8 2.669 5.211 161.3 tr.625ac.25prg.125 0.5665E-01 -1.247 48.42 1.685 0.5405 15.58 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 8958.736003 g Volume = 3625.563681 cm3 Porosity: -10.5018% V(tot) - V(min): -.34456E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8199.9990000 g log = 3.9138 Original solution: 1000.0103000 g Original solution / Rock added: 0.12 (Water/Rock Ratio), log = -0.9138 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1778 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8946E+00 0.9839 0.1037E+01 0.1054E+01 CO2,gas 0.1999E-07 1.0060 0.2368E-07 0.2354E-07 CH4,gas 0.9276E-01 1.0117 0.1105E+00 0.1092E+00 H2,gas 0.1265E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.7015E-06 0.9954 0.8225E-06 0.8263E-06 S2,gas 0.9679E-28 1.0000 0.1140E-27 0.1140E-27 CO,gas 0.7766E-13 1.0000 0.9146E-13 0.9146E-13 SO3,gas 0.4292E-47 1.0000 0.5056E-47 0.5056E-47 SO2,gas 0.2421E-26 1.0000 0.2851E-26 0.2851E-26 HCl,gas 0.1425E-16 1.0000 0.1679E-16 0.1679E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.48529E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.30331E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 -0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.99 -9.63 -3.209 0.16435E+05 -7.626 3 CH4,gas 4.81 1.85 -2.96 -0.739 0.50482E+04 -0.957 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65338E+04 -1.827 5 H2S,gas -5.94 -14.03 -8.08 -4.042 0.13805E+05 -6.085 6 S2,gas -7.03 -36.98 -29.94 -4.607 0.51127E+05 -27.943 7 CO,gas 3.51 -11.53 -15.04 -4.627 0.25678E+05 -13.039 8 SO3,gas 17.43 -31.87 -49.30 -12.324 0.84172E+05 -47.296 9 SO2,gas 1.14 -27.41 -28.54 -7.612 0.48740E+05 -26.545 10 HCl,gas 5.48 -13.30 -18.78 -9.388 0.32058E+05 -16.775 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80597E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.88 -3.87 -1.289 0.66053E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.88 -3.72 -1.238 0.63439E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65548E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.07 -3.96 -1.132 0.67629E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.07 -3.52 -1.006 0.60091E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82259E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.77 -4.55 -1.070 0.77642E+04 143 pyrrhotite -4.24 -7.28 -3.04 -1.014 0.51926E+04 144 pyrrhotiteFe0.875 -6.00 -8.68 -2.68 -0.986 0.45754E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22426E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23218E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47124E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.28 -2.89 -0.964 0.49358E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.78 -3.81 -1.272 0.65136E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 8199.9990000 g New total amount of reactant added: 8249.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7637E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8249.9990000 Water: Moles liquid = 0.9412E+01 kg liquid = 0.1696E+00 Moles total = -.4791E+02 kg total = -.8631E+00 Activity = 1.0000 Stoichiometric ionic strength = .1229103E-01 Osmotic coef. = 0.9671 True ionic strength = .2112445E-01 Chg. balance for total moles = 0.7637E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92158E-10 -10.0355 0.77215E-10 -10.1123 0.83786E+00 -0.0768 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.80988E-03 -3.0916 0.67433E-03 -3.1711 0.83263E+00 -0.0795 4 SO4-- 0.45542E-11 -11.3416 0.23367E-11 -11.6314 0.51310E+00 -0.2898 5 HCO3- 0.16411E-05 -5.7849 0.13685E-05 -5.8638 0.83389E+00 -0.0789 6 HS- 0.15039E-03 -3.8228 0.12524E-03 -3.9023 0.83275E+00 -0.0795 7 Al+++ 0.11810E-28 -28.9278 0.26542E-29 -29.5761 0.22475E+00 -0.6483 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14965E-06 -6.8249 0.76197E-07 -7.1181 0.50918E+00 -0.2931 10 Mg++ 0.23764E-10 -10.6241 0.12043E-10 -10.9193 0.50677E+00 -0.2952 11 Fe++ 0.65004E-13 -13.1871 0.32979E-13 -13.4818 0.50734E+00 -0.2947 12 K+ 0.16483E-03 -3.7830 0.13748E-03 -3.8618 0.83409E+00 -0.0788 13 Na+ 0.20956E-01 -1.6787 0.17445E-01 -1.7583 0.83247E+00 -0.0796 14 Mn++ 0.20898E-10 -10.6799 0.10612E-10 -10.9742 0.50778E+00 -0.2943 15 HPO4-- 0.47190E-07 -7.3261 0.24217E-07 -7.6159 0.51317E+00 -0.2897 16 HSiO3- 0.10800E-01 -1.9666 0.89924E-02 -2.0461 0.83263E+00 -0.0795 17 Ca(HSiO3)+ 0.18402E-07 -7.7351 0.15352E-07 -7.8138 0.83428E+00 -0.0787 18 Mg(HSiO3)+ 0.36195E-11 -11.4414 0.30196E-11 -11.5200 0.83428E+00 -0.0787 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.68887E-16 -16.1619 0.57471E-16 -16.2406 0.83428E+00 -0.0787 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51825E-05 -5.2855 0.43071E-05 -5.3658 0.83108E+00 -0.0804 24 CH4,aq 0.72239E-04 -4.1412 0.71969E-04 -4.1429 0.99626E+00 -0.0016 25 C2H6,aq 0.82485E-13 -13.0836 0.82177E-13 -13.0853 0.99626E+00 -0.0016 29 CO,aq 0.59643E-16 -16.2244 0.59643E-16 -16.2244 0.10000E+01 0.0000 30 CO2,aq 0.21385E-09 -9.6699 0.21305E-09 -9.6715 0.99626E+00 -0.0016 31 CO3-2 0.32007E-05 -5.4948 0.16387E-05 -5.7855 0.51197E+00 -0.2908 32 CaCO3,aq 0.15293E-08 -8.8155 0.15293E-08 -8.8155 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.31493E-11 -11.5018 0.26274E-11 -11.5805 0.83428E+00 -0.0787 34 CaCl+ 0.98141E-10 -10.0081 0.81877E-10 -10.0868 0.83428E+00 -0.0787 35 CaCl2,aq 0.12855E-13 -13.8909 0.12855E-13 -13.8909 0.10000E+01 0.0000 36 CaOH+ 0.83405E-07 -7.0788 0.69583E-07 -7.1575 0.83428E+00 -0.0787 37 CaSO4,aq 0.55477E-16 -16.2559 0.55477E-16 -16.2559 0.10000E+01 0.0000 38 HCl,aq 0.97939E-14 -14.0090 0.97939E-14 -14.0090 0.10000E+01 0.0000 43 FeCl+ 0.41518E-16 -16.3818 0.34637E-16 -16.4605 0.83428E+00 -0.0787 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16972E-10 -10.7703 0.14160E-10 -10.8489 0.83428E+00 -0.0787 48 HFeO2- 0.36595E-07 -7.4366 0.30470E-07 -7.5161 0.83263E+00 -0.0795 49 FeO+ 0.12528E-16 -16.9021 0.10451E-16 -16.9808 0.83428E+00 -0.0787 51 FeO2- 0.41379E-09 -9.3832 0.34453E-09 -9.4628 0.83263E+00 -0.0795 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9622 0.10870E-04 -4.9638 0.99626E+00 -0.0016 54 KCl,aq 0.16415E-08 -8.7848 0.16415E-08 -8.7848 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.59443E-14 -14.2259 0.49494E-14 -14.3054 0.83263E+00 -0.0795 58 MgCO3,aq 0.60395E-13 -13.2190 0.60395E-13 -13.2190 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.50757E-15 -15.2945 0.42345E-15 -15.3732 0.83428E+00 -0.0787 60 MgCl+ 0.14081E-13 -13.8514 0.11748E-13 -13.9301 0.83428E+00 -0.0787 61 MgOH+ 0.73029E-10 -10.1365 0.60927E-10 -10.2152 0.83428E+00 -0.0787 63 MnO,aq 0.18789E-08 -8.7261 0.18789E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.50732E-09 -9.2947 0.42325E-09 -9.3734 0.83428E+00 -0.0787 65 MnO2-2 0.21287E-10 -10.6719 0.10898E-10 -10.9626 0.51197E+00 -0.2908 66 HMnO2- 0.21897E-09 -9.6596 0.18232E-09 -9.7392 0.83263E+00 -0.0795 69 MnCl+ 0.51911E-13 -13.2847 0.43308E-13 -13.3634 0.83428E+00 -0.0787 71 NaCl,aq 0.38412E-05 -5.4155 0.38412E-05 -5.4155 0.10000E+01 0.0000 72 NaOH,aq 0.99274E-04 -4.0032 0.99274E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.93474E-02 -2.0293 0.77684E-02 -2.1097 0.83108E+00 -0.0804 79 HPO3-2 0.16240E-14 -14.7894 0.83142E-15 -15.0802 0.51197E+00 -0.2908 81 H2PO3- 0.15146E-18 -18.8197 0.12611E-18 -18.8993 0.83263E+00 -0.0795 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39334E-10 -10.4052 0.32783E-10 -10.4844 0.83344E+00 -0.0791 84 PO4-3 0.11582E-08 -8.9362 0.27390E-09 -9.5624 0.23649E+00 -0.6262 88 HP2O7-3 0.99282E-18 -18.0031 0.22337E-18 -18.6510 0.22499E+00 -0.6478 89 P2O7-4 0.97095E-17 -17.0128 0.71367E-18 -18.1465 0.73502E-01 -1.1337 90 H2S,aq 0.29164E-07 -7.5352 0.29054E-07 -7.5368 0.99626E+00 -0.0016 91 S2-2 0.61986E-13 -13.2077 0.31735E-13 -13.4985 0.51197E+00 -0.2908 97 SO3-2 0.66646E-17 -17.1762 0.34632E-17 -17.4605 0.51965E+00 -0.2843 98 HSO3- 0.18795E-19 -19.7260 0.15649E-19 -19.8055 0.83263E+00 -0.0795 99 HSO4- 0.20047E-18 -18.6980 0.16742E-18 -18.7762 0.83512E+00 -0.0782 Charge balance for all species = 0.4505E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9215760E-10 -.2276585E-01 -.2290458E+02 0.0000 2 H2O 0.1000000E+01 0.5550450E+02 0.9980986E+06 0.0000 3 Cl- 0.8098837E-03 0.8137266E-03 0.2879621E+02 6.9412 4 SO4-- 0.4554200E-11 -.7496659E-04 -.7188220E+01 8.5932 5 HCO3- 0.1641092E-05 0.7708259E-04 0.4694748E+01 4.2485 6 HS- 0.1503879E-03 0.2253836E-03 0.7440234E+01 6.2100 7 Al+++ 0.1180986E-28 0.5182668E-05 0.1395800E+00 0.7608 8 H4SiO4 0.7116653E-03 0.1400327E-01 0.1343464E+04 -3.1477 9 Ca++ 0.1496451E-06 0.2530824E-06 0.1012446E-01 13.1065 10 Mg++ 0.2376377E-10 0.1004998E-09 0.2438877E-05 9.3053 11 Fe++ 0.6500361E-13 0.3724772E-07 0.2076363E-02 6.7428 12 K+ 0.1648258E-03 0.1656037E-03 0.6463573E+01 6.2505 13 Na+ 0.2095582E-01 0.2355047E-01 0.5404288E+03 8.3540 14 Mn++ 0.2089792E-10 0.2647383E-08 0.1451755E-03 9.2504 15 HPO4-- 0.4719033E-07 0.4838783E-07 0.4635708E-02 12.6087 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1366077E+03 -.3860141E-02 -.1366039E+03 0.0000000E+00 2 H2O -.4790887E+02 0.9411254E+01 -.5732013E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2286611E+00 -.1271122E-04 0.2286738E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2286356E+00 0.3821569E-04 -.2286738E+00 0.0000000E+00 7 Al+++ 0.2690112E+02 0.8787649E-06 0.2690111E+02 0.0000000E+00 8 H4SiO4 0.8590545E+02 0.2374372E-02 0.8590307E+02 0.0000000E+00 9 Ca++ 0.9488690E+01 0.4291225E-07 0.9488690E+01 0.0000000E+00 10 Mg++ 0.6547618E+01 0.1704059E-10 0.6547618E+01 0.0000000E+00 11 Fe++ 0.5882320E+01 0.6315664E-08 0.5882320E+01 0.0000000E+00 12 K+ 0.1751592E+01 0.2807949E-04 0.1751564E+01 0.0000000E+00 13 Na+ 0.1035592E+02 0.3993179E-02 0.1035193E+02 0.0000000E+00 14 Mn++ 0.1430434E+00 0.4488860E-09 0.1430434E+00 0.0000000E+00 15 HPO4-- 0.4882000E-01 0.8204563E-08 0.4881999E-01 0.0000000E+00 Chg. balance for solid moles: -.5723E-13 Mass of aqueous solution: 0.169870E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8249.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.34 1.015 2713. 3.433 30.10 1041. andradite 0.9147 -0.039 464.8 2.667 5.157 120.8 grossular 0.2184 -0.661 98.37 1.993 1.091 27.37 apatite-OH 0.1627E-01 -1.789 8.174 0.912 0.9069E-01 2.598 clinochlore 1.175 0.070 652.9 2.815 7.244 248.4 daphnite 0.3367 -0.473 240.2 2.381 2.665 72.79 chlorite-Mn 0.2861E-01 -1.544 20.28 1.307 0.2250 6.464 diopside 0.4677 -0.330 101.3 2.006 1.124 30.96 hedenbergite 0.1198 -0.921 29.73 1.473 0.3298 8.142 microcline 1.534 0.186 426.9 2.630 4.736 166.8 stilbite 5.307 0.725 3740. 3.573 41.49 1744. stilpnomelane-Fe 0.4357 -0.361 469.7 2.672 5.211 162.2 tr.625ac.25prg.125 0.5699E-01 -1.244 48.71 1.688 0.5404 15.68 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9013.363742 g Volume = 3647.666859 cm3 Porosity: -10.5019% V(tot) - V(min): -.34667E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8249.9990000 g log = 3.9165 Original solution: 1000.0103000 g Original solution / Rock added: 0.12 (Water/Rock Ratio), log = -0.9164 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1811 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8921E+00 0.9839 0.1037E+01 0.1054E+01 CO2,gas 0.2053E-07 1.0059 0.2439E-07 0.2424E-07 CH4,gas 0.9525E-01 1.0117 0.1138E+00 0.1125E+00 H2,gas 0.1262E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.7208E-06 0.9954 0.8474E-06 0.8513E-06 S2,gas 0.1025E-27 1.0000 0.1210E-27 0.1210E-27 CO,gas 0.7974E-13 1.0000 0.9418E-13 0.9418E-13 SO3,gas 0.4410E-47 1.0000 0.5209E-47 0.5209E-47 SO2,gas 0.2487E-26 1.0000 0.2938E-26 0.2938E-26 HCl,gas 0.1464E-16 1.0000 0.1729E-16 0.1729E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.84926E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.98 -9.61 -3.204 0.16414E+05 -7.613 3 CH4,gas 4.81 1.87 -2.94 -0.736 0.50265E+04 -0.944 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65338E+04 -1.827 5 H2S,gas -5.94 -14.01 -8.07 -4.036 0.13783E+05 -6.072 6 S2,gas -7.03 -36.95 -29.92 -4.603 0.51083E+05 -27.917 7 CO,gas 3.51 -11.52 -15.03 -4.623 0.25657E+05 -13.026 8 SO3,gas 17.43 -31.86 -49.28 -12.321 0.84150E+05 -47.283 9 SO2,gas 1.14 -27.40 -28.53 -7.609 0.48718E+05 -26.532 10 HCl,gas 5.48 -13.28 -18.76 -9.381 0.32036E+05 -16.762 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80597E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.87 -3.86 -1.285 0.65836E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.87 -3.70 -1.234 0.63222E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65548E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.06 -3.95 -1.128 0.67412E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.06 -3.51 -1.002 0.59874E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82259E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.75 -4.52 -1.064 0.77200E+04 143 pyrrhotite -4.24 -7.27 -3.03 -1.009 0.51705E+04 144 pyrrhotiteFe0.875 -6.00 -8.67 -2.67 -0.981 0.45533E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22426E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23218E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47124E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.27 -2.88 -0.959 0.49137E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.76 -3.80 -1.267 0.64915E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 8249.9990000 g New total amount of reactant added: 8299.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7639E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8299.9990000 Water: Moles liquid = 0.9133E+01 kg liquid = 0.1645E+00 Moles total = -.4854E+02 kg total = -.8744E+00 Activity = 1.0000 Stoichiometric ionic strength = .1231177E-01 Osmotic coef. = 0.9670 True ionic strength = .2114076E-01 Chg. balance for total moles = 0.7639E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92228E-10 -10.0351 0.77270E-10 -10.1120 0.83782E+00 -0.0769 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.83461E-03 -3.0785 0.69488E-03 -3.1581 0.83258E+00 -0.0796 4 SO4-- 0.46906E-11 -11.3288 0.24062E-11 -11.6187 0.51299E+00 -0.2899 5 HCO3- 0.16902E-05 -5.7721 0.14093E-05 -5.8510 0.83385E+00 -0.0789 6 HS- 0.15498E-03 -3.8097 0.12905E-03 -3.8892 0.83271E+00 -0.0795 7 Al+++ 0.11841E-28 -28.9266 0.26599E-29 -29.5751 0.22464E+00 -0.6485 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.14989E-06 -6.8242 0.76306E-07 -7.1174 0.50908E+00 -0.2932 10 Mg++ 0.23803E-10 -10.6234 0.12060E-10 -10.9187 0.50666E+00 -0.2953 11 Fe++ 0.65110E-13 -13.1863 0.33026E-13 -13.4811 0.50724E+00 -0.2948 12 K+ 0.16495E-03 -3.7826 0.13758E-03 -3.8615 0.83405E+00 -0.0788 13 Na+ 0.20972E-01 -1.6784 0.17458E-01 -1.7580 0.83242E+00 -0.0797 14 Mn++ 0.20932E-10 -10.6792 0.10627E-10 -10.9736 0.50767E+00 -0.2944 15 HPO4-- 0.47133E-07 -7.3267 0.24182E-07 -7.6165 0.51307E+00 -0.2898 16 HSiO3- 0.10793E-01 -1.9669 0.89860E-02 -2.0464 0.83258E+00 -0.0796 17 Ca(HSiO3)+ 0.18416E-07 -7.7348 0.15363E-07 -7.8135 0.83423E+00 -0.0787 18 Mg(HSiO3)+ 0.36222E-11 -11.4410 0.30218E-11 -11.5197 0.83423E+00 -0.0787 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.68940E-16 -16.1615 0.57512E-16 -16.2402 0.83423E+00 -0.0787 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51791E-05 -5.2857 0.43040E-05 -5.3661 0.83103E+00 -0.0804 24 CH4,aq 0.74449E-04 -4.1281 0.74170E-04 -4.1298 0.99625E+00 -0.0016 25 C2H6,aq 0.87610E-13 -13.0574 0.87281E-13 -13.0591 0.99625E+00 -0.0016 29 CO,aq 0.61468E-16 -16.2114 0.61468E-16 -16.2114 0.10000E+01 0.0000 30 CO2,aq 0.22039E-09 -9.6568 0.21957E-09 -9.6584 0.99625E+00 -0.0016 31 CO3-2 0.32946E-05 -5.4822 0.16864E-05 -5.7730 0.51186E+00 -0.2908 32 CaCO3,aq 0.15760E-08 -8.8024 0.15760E-08 -8.8024 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.32482E-11 -11.4884 0.27097E-11 -11.5671 0.83423E+00 -0.0787 34 CaCl+ 0.10128E-09 -9.9945 0.84493E-10 -10.0732 0.83423E+00 -0.0787 35 CaCl2,aq 0.13670E-13 -13.8642 0.13670E-13 -13.8642 0.10000E+01 0.0000 36 CaOH+ 0.83469E-07 -7.0785 0.69633E-07 -7.1572 0.83423E+00 -0.0787 37 CaSO4,aq 0.57209E-16 -16.2425 0.57209E-16 -16.2425 0.10000E+01 0.0000 38 HCl,aq 0.10100E-13 -13.9957 0.10100E-13 -13.9957 0.10000E+01 0.0000 43 FeCl+ 0.42847E-16 -16.3681 0.35744E-16 -16.4468 0.83423E+00 -0.0787 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16985E-10 -10.7699 0.14170E-10 -10.8486 0.83423E+00 -0.0787 48 HFeO2- 0.36571E-07 -7.4369 0.30448E-07 -7.5164 0.83258E+00 -0.0796 49 FeO+ 0.12537E-16 -16.9018 0.10459E-16 -16.9805 0.83423E+00 -0.0787 51 FeO2- 0.41351E-09 -9.3835 0.34429E-09 -9.4631 0.83258E+00 -0.0796 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9622 0.10870E-04 -4.9638 0.99625E+00 -0.0016 54 KCl,aq 0.16927E-08 -8.7714 0.16927E-08 -8.7714 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.61258E-14 -14.2128 0.51002E-14 -14.2924 0.83258E+00 -0.0796 58 MgCO3,aq 0.62242E-13 -13.2059 0.62242E-13 -13.2059 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.52349E-15 -15.2811 0.43672E-15 -15.3598 0.83423E+00 -0.0787 60 MgCl+ 0.14532E-13 -13.8377 0.12123E-13 -13.9164 0.83423E+00 -0.0787 61 MgOH+ 0.73085E-10 -10.1362 0.60970E-10 -10.2149 0.83423E+00 -0.0787 63 MnO,aq 0.18789E-08 -8.7261 0.18789E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.50771E-09 -9.2944 0.42355E-09 -9.3731 0.83423E+00 -0.0787 65 MnO2-2 0.21261E-10 -10.6724 0.10883E-10 -10.9633 0.51186E+00 -0.2908 66 HMnO2- 0.21883E-09 -9.6599 0.18219E-09 -9.7395 0.83258E+00 -0.0796 69 MnCl+ 0.53573E-13 -13.2711 0.44692E-13 -13.3498 0.83423E+00 -0.0787 71 NaCl,aq 0.39610E-05 -5.4022 0.39610E-05 -5.4022 0.10000E+01 0.0000 72 NaOH,aq 0.99274E-04 -4.0032 0.99274E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.93412E-02 -2.0296 0.77628E-02 -2.1100 0.83103E+00 -0.0804 79 HPO3-2 0.16220E-14 -14.7900 0.83023E-15 -15.0808 0.51186E+00 -0.2908 81 H2PO3- 0.15136E-18 -18.8200 0.12602E-18 -18.8996 0.83258E+00 -0.0796 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39308E-10 -10.4055 0.32760E-10 -10.4847 0.83340E+00 -0.0791 84 PO4-3 0.11562E-08 -8.9370 0.27331E-09 -9.5633 0.23639E+00 -0.6264 88 HP2O7-3 0.99115E-18 -18.0039 0.22290E-18 -18.6519 0.22489E+00 -0.6480 89 P2O7-4 0.96897E-17 -17.0137 0.71163E-18 -18.1477 0.73443E-01 -1.1341 90 H2S,aq 0.30074E-07 -7.5218 0.29961E-07 -7.5234 0.99625E+00 -0.0016 91 S2-2 0.65836E-13 -13.1815 0.33699E-13 -13.4724 0.51186E+00 -0.2908 97 SO3-2 0.68641E-17 -17.1634 0.35662E-17 -17.4478 0.51955E+00 -0.2844 98 HSO3- 0.19369E-19 -19.7129 0.16126E-19 -19.7925 0.83258E+00 -0.0796 99 HSO4- 0.20659E-18 -18.6849 0.17252E-18 -18.7632 0.83508E+00 -0.0783 Charge balance for all species = 0.4636E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9222801E-10 -.2275260E-01 -.2289123E+02 0.0000 2 H2O 0.1000000E+01 0.5550450E+02 0.9980979E+06 0.0000 3 Cl- 0.8346073E-03 0.8385702E-03 0.2967535E+02 6.9539 4 SO4-- 0.4690602E-11 -.7717697E-04 -.7400158E+01 8.6053 5 HCO3- 0.1690175E-05 0.7943596E-04 0.4838078E+01 4.2610 6 HS- 0.1549793E-03 0.2321863E-03 0.7664794E+01 6.2228 7 Al+++ 0.1184076E-28 0.5179241E-05 0.1394876E+00 0.7608 8 H4SiO4 0.7116653E-03 0.1399612E-01 0.1342777E+04 -3.1477 9 Ca++ 0.1498906E-06 0.2534559E-06 0.1013939E-01 13.1065 10 Mg++ 0.2380282E-10 0.1005884E-09 0.2441024E-05 9.3053 11 Fe++ 0.6511038E-13 0.3722322E-07 0.2074996E-02 6.7428 12 K+ 0.1649522E-03 0.1657301E-03 0.6468502E+01 6.2505 13 Na+ 0.2097191E-01 0.2356668E-01 0.5408003E+03 8.3540 14 Mn++ 0.2093238E-10 0.2647655E-08 0.1451903E-03 9.2504 15 HPO4-- 0.4713253E-07 0.4832802E-07 0.4629975E-02 12.6075 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1374356E+03 -.3743599E-02 -.1374319E+03 0.0000000E+00 2 H2O -.4853564E+02 0.9132436E+01 -.5766808E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2300468E+00 -.1269832E-04 0.2300595E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2300213E+00 0.3820279E-04 -.2300595E+00 0.0000000E+00 7 Al+++ 0.2706415E+02 0.8521666E-06 0.2706415E+02 0.0000000E+00 8 H4SiO4 0.8642609E+02 0.2302852E-02 0.8642379E+02 0.0000000E+00 9 Ca++ 0.9546197E+01 0.4170238E-07 0.9546197E+01 0.0000000E+00 10 Mg++ 0.6587301E+01 0.1655032E-10 0.6587301E+01 0.0000000E+00 11 Fe++ 0.5917971E+01 0.6124525E-08 0.5917971E+01 0.0000000E+00 12 K+ 0.1762208E+01 0.2726840E-04 0.1762181E+01 0.0000000E+00 13 Na+ 0.1041868E+02 0.3877544E-02 0.1041480E+02 0.0000000E+00 14 Mn++ 0.1439103E+00 0.4356320E-09 0.1439103E+00 0.0000000E+00 15 HPO4-- 0.4911588E-01 0.7951654E-08 0.4911587E-01 0.0000000E+00 Chg. balance for solid moles: -.1243E-13 Mass of aqueous solution: 0.164837E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8299.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.41 1.017 2729. 3.436 30.10 1048. andradite 0.9202 -0.036 467.6 2.670 5.157 121.5 grossular 0.2197 -0.658 98.97 1.995 1.091 27.54 apatite-OH 0.1637E-01 -1.786 8.224 0.915 0.9069E-01 2.613 clinochlore 1.182 0.073 656.9 2.817 7.244 249.9 daphnite 0.3387 -0.470 241.7 2.383 2.665 73.23 chlorite-Mn 0.2878E-01 -1.541 20.41 1.310 0.2250 6.503 diopside 0.4706 -0.327 101.9 2.008 1.124 31.15 hedenbergite 0.1206 -0.919 29.91 1.476 0.3299 8.193 microcline 1.543 0.188 429.5 2.633 4.736 167.8 stilbite 5.339 0.727 3762. 3.575 41.49 1755. stilpnomelane-Fe 0.4384 -0.358 472.5 2.674 5.211 163.2 tr.625ac.25prg.125 0.5733E-01 -1.242 49.00 1.690 0.5404 15.77 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9067.991480 g Volume = 3669.770036 cm3 Porosity: -10.5020% V(tot) - V(min): -.34877E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8299.9990000 g log = 3.9191 Original solution: 1000.0103000 g Original solution / Rock added: 0.12 (Water/Rock Ratio), log = -0.9191 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1846 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8895E+00 0.9838 0.1037E+01 0.1054E+01 CO2,gas 0.2109E-07 1.0059 0.2513E-07 0.2499E-07 CH4,gas 0.9788E-01 1.0117 0.1173E+00 0.1159E+00 H2,gas 0.1258E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.7411E-06 0.9954 0.8738E-06 0.8779E-06 S2,gas 0.1086E-27 1.0000 0.1287E-27 0.1287E-27 CO,gas 0.8194E-13 1.0000 0.9706E-13 0.9706E-13 SO3,gas 0.4534E-47 1.0000 0.5371E-47 0.5371E-47 SO2,gas 0.2557E-26 1.0000 0.3029E-26 0.3029E-26 HCl,gas 0.1505E-16 1.0000 0.1783E-16 0.1783E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 -0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 -0.12132E-10 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.96 -9.60 -3.200 0.16391E+05 -7.600 3 CH4,gas 4.81 1.88 -2.93 -0.733 0.50042E+04 -0.931 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65338E+04 -1.827 5 H2S,gas -5.94 -14.00 -8.06 -4.029 0.13760E+05 -6.059 6 S2,gas -7.03 -36.92 -29.89 -4.599 0.51037E+05 -27.890 7 CO,gas 3.51 -11.50 -15.01 -4.619 0.25634E+05 -13.013 8 SO3,gas 17.43 -31.84 -49.27 -12.317 0.84127E+05 -47.270 9 SO2,gas 1.14 -27.38 -28.52 -7.605 0.48695E+05 -26.519 10 HCl,gas 5.48 -13.27 -18.75 -9.374 0.32013E+05 -16.749 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80597E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.86 -3.84 -1.281 0.65612E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.86 -3.69 -1.230 0.62999E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65548E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.04 -3.93 -1.124 0.67188E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.04 -3.49 -0.998 0.59650E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82259E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.72 -4.49 -1.058 0.76744E+04 143 pyrrhotite -4.24 -7.26 -3.01 -1.005 0.51477E+04 144 pyrrhotiteFe0.875 -6.00 -8.65 -2.65 -0.976 0.45305E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22426E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23218E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47124E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.26 -2.86 -0.955 0.48909E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.75 -3.79 -1.263 0.64687E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 8299.9990000 g New total amount of reactant added: 8349.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7636E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 12 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8349.9990000 Water: Moles liquid = 0.8854E+01 kg liquid = 0.1595E+00 Moles total = -.4916E+02 kg total = -.8857E+00 Activity = 1.0000 Stoichiometric ionic strength = .1233381E-01 Osmotic coef. = 0.9670 True ionic strength = .2115811E-01 Chg. balance for total moles = 0.7636E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92303E-10 -10.0348 0.77329E-10 -10.1117 0.83777E+00 -0.0769 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.86089E-03 -3.0651 0.71672E-03 -3.1446 0.83254E+00 -0.0796 4 SO4-- 0.48354E-11 -11.3156 0.24800E-11 -11.6055 0.51288E+00 -0.2900 5 HCO3- 0.17423E-05 -5.7589 0.14527E-05 -5.8378 0.83380E+00 -0.0789 6 HS- 0.15986E-03 -3.7963 0.13311E-03 -3.8758 0.83266E+00 -0.0795 7 Al+++ 0.11874E-28 -28.9254 0.26660E-29 -29.5741 0.22453E+00 -0.6487 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.15015E-06 -6.8235 0.76422E-07 -7.1168 0.50896E+00 -0.2933 10 Mg++ 0.23844E-10 -10.6226 0.12078E-10 -10.9180 0.50655E+00 -0.2954 11 Fe++ 0.65224E-13 -13.1856 0.33077E-13 -13.4805 0.50712E+00 -0.2949 12 K+ 0.16509E-03 -3.7823 0.13768E-03 -3.8611 0.83400E+00 -0.0788 13 Na+ 0.20989E-01 -1.6780 0.17471E-01 -1.7577 0.83238E+00 -0.0797 14 Mn++ 0.20969E-10 -10.6784 0.10643E-10 -10.9729 0.50756E+00 -0.2945 15 HPO4-- 0.47071E-07 -7.3272 0.24145E-07 -7.6172 0.51296E+00 -0.2899 16 HSiO3- 0.10785E-01 -1.9672 0.89792E-02 -2.0468 0.83254E+00 -0.0796 17 Ca(HSiO3)+ 0.18431E-07 -7.7345 0.15375E-07 -7.8132 0.83419E+00 -0.0787 18 Mg(HSiO3)+ 0.36252E-11 -11.4407 0.30241E-11 -11.5194 0.83419E+00 -0.0787 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.68996E-16 -16.1612 0.57556E-16 -16.2399 0.83419E+00 -0.0787 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51755E-05 -5.2861 0.43007E-05 -5.3665 0.83098E+00 -0.0804 24 CH4,aq 0.76799E-04 -4.1146 0.76511E-04 -4.1163 0.99624E+00 -0.0016 25 C2H6,aq 0.93227E-13 -13.0305 0.92877E-13 -13.0321 0.99624E+00 -0.0016 29 CO,aq 0.63408E-16 -16.1979 0.63408E-16 -16.1979 0.10000E+01 0.0000 30 CO2,aq 0.22735E-09 -9.6433 0.22649E-09 -9.6449 0.99624E+00 -0.0016 31 CO3-2 0.33942E-05 -5.4693 0.17370E-05 -5.7602 0.51175E+00 -0.2909 32 CaCO3,aq 0.16258E-08 -8.7889 0.16258E-08 -8.7889 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.33534E-11 -11.4745 0.27974E-11 -11.5533 0.83419E+00 -0.0787 34 CaCl+ 0.10463E-09 -9.9803 0.87281E-10 -10.0591 0.83419E+00 -0.0787 35 CaCl2,aq 0.14565E-13 -13.8367 0.14565E-13 -13.8367 0.10000E+01 0.0000 36 CaOH+ 0.83537E-07 -7.0781 0.69686E-07 -7.1569 0.83419E+00 -0.0787 37 CaSO4,aq 0.59052E-16 -16.2288 0.59052E-16 -16.2288 0.10000E+01 0.0000 38 HCl,aq 0.10425E-13 -13.9819 0.10425E-13 -13.9819 0.10000E+01 0.0000 43 FeCl+ 0.44263E-16 -16.3540 0.36924E-16 -16.4327 0.83419E+00 -0.0787 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.16999E-10 -10.7696 0.14181E-10 -10.8483 0.83419E+00 -0.0787 48 HFeO2- 0.36545E-07 -7.4372 0.30425E-07 -7.5168 0.83254E+00 -0.0796 49 FeO+ 0.12547E-16 -16.9014 0.10467E-16 -16.9802 0.83419E+00 -0.0787 51 FeO2- 0.41322E-09 -9.3838 0.34402E-09 -9.4634 0.83254E+00 -0.0796 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10870E-04 -4.9638 0.99624E+00 -0.0016 54 KCl,aq 0.17473E-08 -8.7576 0.17473E-08 -8.7576 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.63187E-14 -14.1994 0.52606E-14 -14.2790 0.83254E+00 -0.0796 58 MgCO3,aq 0.64207E-13 -13.1924 0.64207E-13 -13.1924 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.54045E-15 -15.2672 0.45084E-15 -15.3460 0.83419E+00 -0.0787 60 MgCl+ 0.15012E-13 -13.8236 0.12523E-13 -13.9023 0.83419E+00 -0.0787 61 MgOH+ 0.73145E-10 -10.1358 0.61017E-10 -10.2146 0.83419E+00 -0.0787 63 MnO,aq 0.18789E-08 -8.7261 0.18789E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.50813E-09 -9.2940 0.42388E-09 -9.3728 0.83419E+00 -0.0787 65 MnO2-2 0.21234E-10 -10.6730 0.10866E-10 -10.9639 0.51175E+00 -0.2909 66 HMnO2- 0.21868E-09 -9.6602 0.18206E-09 -9.7398 0.83254E+00 -0.0796 69 MnCl+ 0.55344E-13 -13.2569 0.46167E-13 -13.3357 0.83419E+00 -0.0787 71 NaCl,aq 0.40887E-05 -5.3884 0.40887E-05 -5.3884 0.10000E+01 0.0000 72 NaOH,aq 0.99274E-04 -4.0032 0.99274E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.93346E-02 -2.0299 0.77569E-02 -2.1103 0.83098E+00 -0.0804 79 HPO3-2 0.16199E-14 -14.7905 0.82897E-15 -15.0815 0.51175E+00 -0.2909 81 H2PO3- 0.15125E-18 -18.8203 0.12592E-18 -18.8999 0.83254E+00 -0.0796 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39281E-10 -10.4058 0.32735E-10 -10.4850 0.83336E+00 -0.0792 84 PO4-3 0.11541E-08 -8.9378 0.27269E-09 -9.5643 0.23628E+00 -0.6266 88 HP2O7-3 0.98939E-18 -18.0046 0.22239E-18 -18.6529 0.22477E+00 -0.6483 89 P2O7-4 0.96686E-17 -17.0146 0.70947E-18 -18.1491 0.73379E-01 -1.1344 90 H2S,aq 0.31043E-07 -7.5080 0.30927E-07 -7.5097 0.99624E+00 -0.0016 91 S2-2 0.70055E-13 -13.1546 0.35851E-13 -13.4455 0.51175E+00 -0.2909 97 SO3-2 0.70760E-17 -17.1502 0.36756E-17 -17.4347 0.51944E+00 -0.2845 98 HSO3- 0.19979E-19 -19.6994 0.16633E-19 -19.7790 0.83254E+00 -0.0796 99 HSO4- 0.21309E-18 -18.6714 0.17794E-18 -18.7497 0.83503E+00 -0.0783 Charge balance for all species = 0.4793E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9230290E-10 -.2273852E-01 -.2287705E+02 0.0000 2 H2O 0.1000000E+01 0.5550451E+02 0.9980971E+06 0.0000 3 Cl- 0.8608880E-03 0.8649785E-03 0.3060986E+02 6.9670 4 SO4-- 0.4835427E-11 -.7952687E-04 -.7625473E+01 8.6178 5 HCO3- 0.1742284E-05 0.8193757E-04 0.4990435E+01 4.2738 6 HS- 0.1598599E-03 0.2394178E-03 0.7903509E+01 6.2359 7 Al+++ 0.1187369E-28 0.5175601E-05 0.1393895E+00 0.7608 8 H4SiO4 0.7116653E-03 0.1398852E-01 0.1342047E+04 -3.1477 9 Ca++ 0.1501519E-06 0.2538534E-06 0.1015529E-01 13.1065 10 Mg++ 0.2384439E-10 0.1006992E-09 0.2443712E-05 9.3053 11 Fe++ 0.6522405E-13 0.3719720E-07 0.2073543E-02 6.7428 12 K+ 0.1650866E-03 0.1658645E-03 0.6473744E+01 6.2505 13 Na+ 0.2098903E-01 0.2358392E-01 0.5411955E+03 8.3540 14 Mn++ 0.2096905E-10 0.2647943E-08 0.1452060E-03 9.2504 15 HPO4-- 0.4707118E-07 0.4826455E-07 0.4623890E-02 12.6062 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1382636E+03 -.3627060E-02 -.1382599E+03 0.0000000E+00 2 H2O -.4916241E+02 0.8853618E+01 -.5801603E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2314324E+00 -.1268547E-04 0.2314451E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2314069E+00 0.3818994E-04 -.2314451E+00 0.0000000E+00 7 Al+++ 0.2722719E+02 0.8255689E-06 0.2722719E+02 0.0000000E+00 8 H4SiO4 0.8694673E+02 0.2231333E-02 0.8694450E+02 0.0000000E+00 9 Ca++ 0.9603704E+01 0.4049259E-07 0.9603704E+01 0.0000000E+00 10 Mg++ 0.6626983E+01 0.1606271E-10 0.6626983E+01 0.0000000E+00 11 Fe++ 0.5953621E+01 0.5933388E-08 0.5953621E+01 0.0000000E+00 12 K+ 0.1772824E+01 0.2645733E-04 0.1772797E+01 0.0000000E+00 13 Na+ 0.1048144E+02 0.3761911E-02 0.1047768E+02 0.0000000E+00 14 Mn++ 0.1447773E+00 0.4223779E-09 0.1447773E+00 0.0000000E+00 15 HPO4-- 0.4941176E-01 0.7698760E-08 0.4941175E-01 0.0000000E+00 Chg. balance for solid moles: 0.3816E-14 Mass of aqueous solution: 0.159805E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8349.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.47 1.020 2746. 3.439 30.10 1054. andradite 0.9258 -0.033 470.5 2.673 5.157 122.2 grossular 0.2210 -0.656 99.56 1.998 1.091 27.70 apatite-OH 0.1647E-01 -1.783 8.274 0.918 0.9069E-01 2.629 clinochlore 1.189 0.075 660.8 2.820 7.244 251.4 daphnite 0.3407 -0.468 243.1 2.386 2.665 73.67 chlorite-Mn 0.2896E-01 -1.538 20.53 1.312 0.2250 6.542 diopside 0.4735 -0.325 102.5 2.011 1.124 31.34 hedenbergite 0.1213 -0.916 30.10 1.479 0.3299 8.243 microcline 1.552 0.191 432.1 2.636 4.736 168.8 stilbite 5.371 0.730 3785. 3.578 41.49 1765. stilpnomelane-Fe 0.4410 -0.356 475.4 2.677 5.211 164.2 tr.625ac.25prg.125 0.5767E-01 -1.239 49.29 1.693 0.5403 15.87 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9122.619219 g Volume = 3691.873213 cm3 Porosity: -10.5021% V(tot) - V(min): -.35087E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8349.9990000 g log = 3.9217 Original solution: 1000.0103000 g Original solution / Rock added: 0.12 (Water/Rock Ratio), log = -0.9217 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1883 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8868E+00 0.9838 0.1037E+01 0.1054E+01 CO2,gas 0.2169E-07 1.0058 0.2593E-07 0.2578E-07 CH4,gas 0.1007E+00 1.0116 0.1210E+00 0.1196E+00 H2,gas 0.1254E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.7626E-06 0.9954 0.9020E-06 0.9062E-06 S2,gas 0.1154E-27 1.0000 0.1371E-27 0.1371E-27 CO,gas 0.8426E-13 1.0000 0.1001E-12 0.1001E-12 SO3,gas 0.4666E-47 1.0000 0.5544E-47 0.5544E-47 SO2,gas 0.2631E-26 1.0000 0.3127E-26 0.3127E-26 HCl,gas 0.1549E-16 1.0000 0.1841E-16 0.1841E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.00000E+00 47 daphnite 29.09 29.09 0.00 0.000 -0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.95 -9.59 -3.195 0.16368E+05 -7.586 3 CH4,gas 4.81 1.89 -2.92 -0.729 0.49811E+04 -0.917 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65338E+04 -1.827 5 H2S,gas -5.94 -13.99 -8.04 -4.022 0.13736E+05 -6.045 6 S2,gas -7.03 -36.90 -29.86 -4.594 0.50990E+05 -27.863 7 CO,gas 3.51 -11.49 -15.00 -4.615 0.25611E+05 -12.999 8 SO3,gas 17.43 -31.83 -49.26 -12.314 0.84104E+05 -47.256 9 SO2,gas 1.14 -27.37 -28.50 -7.601 0.48671E+05 -26.505 10 HCl,gas 5.48 -13.26 -18.74 -9.368 0.31990E+05 -16.735 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80597E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.84 -3.83 -1.276 0.65382E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.84 -3.68 -1.225 0.62769E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65548E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.03 -3.92 -1.120 0.66958E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.03 -3.48 -0.994 0.59420E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82259E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.69 -4.47 -1.051 0.76274E+04 143 pyrrhotite -4.24 -7.24 -3.00 -1.000 0.51242E+04 144 pyrrhotiteFe0.875 -6.00 -8.64 -2.64 -0.971 0.45070E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22425E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23218E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47124E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.24 -2.85 -0.950 0.48674E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60329E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.74 -3.77 -1.258 0.64451E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 8349.9990000 g New total amount of reactant added: 8399.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7635E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8399.9990000 Water: Moles liquid = 0.8575E+01 kg liquid = 0.1545E+00 Moles total = -.4979E+02 kg total = -.8970E+00 Activity = 1.0000 Stoichiometric ionic strength = .1235729E-01 Osmotic coef. = 0.9670 True ionic strength = .2117660E-01 Chg. balance for total moles = 0.7635E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92383E-10 -10.0344 0.77391E-10 -10.1113 0.83773E+00 -0.0769 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.88888E-03 -3.0512 0.73998E-03 -3.1308 0.83249E+00 -0.0796 4 SO4-- 0.49895E-11 -11.3019 0.25584E-11 -11.5920 0.51276E+00 -0.2901 5 HCO3- 0.17977E-05 -5.7453 0.14988E-05 -5.8242 0.83375E+00 -0.0790 6 HS- 0.16506E-03 -3.7824 0.13743E-03 -3.8619 0.83261E+00 -0.0796 7 Al+++ 0.11909E-28 -28.9241 0.26725E-29 -29.5731 0.22441E+00 -0.6490 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.15043E-06 -6.8227 0.76546E-07 -7.1161 0.50884E+00 -0.2934 10 Mg++ 0.23889E-10 -10.6218 0.12098E-10 -10.9173 0.50643E+00 -0.2955 11 Fe++ 0.65345E-13 -13.1848 0.33130E-13 -13.4798 0.50700E+00 -0.2950 12 K+ 0.16523E-03 -3.7819 0.13779E-03 -3.8608 0.83395E+00 -0.0789 13 Na+ 0.21007E-01 -1.6776 0.17485E-01 -1.7573 0.83233E+00 -0.0797 14 Mn++ 0.21008E-10 -10.6776 0.10660E-10 -10.9722 0.50744E+00 -0.2946 15 HPO4-- 0.47006E-07 -7.3278 0.24106E-07 -7.6179 0.51284E+00 -0.2900 16 HSiO3- 0.10777E-01 -1.9675 0.89719E-02 -2.0471 0.83249E+00 -0.0796 17 Ca(HSiO3)+ 0.18447E-07 -7.7341 0.15387E-07 -7.8128 0.83414E+00 -0.0788 18 Mg(HSiO3)+ 0.36283E-11 -11.4403 0.30265E-11 -11.5191 0.83414E+00 -0.0788 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.69056E-16 -16.1608 0.57602E-16 -16.2396 0.83414E+00 -0.0788 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51716E-05 -5.2864 0.42972E-05 -5.3668 0.83093E+00 -0.0804 24 CH4,aq 0.79302E-04 -4.1007 0.79004E-04 -4.1024 0.99624E+00 -0.0016 25 C2H6,aq 0.99402E-13 -13.0026 0.99028E-13 -13.0042 0.99624E+00 -0.0016 29 CO,aq 0.65474E-16 -16.1839 0.65474E-16 -16.1839 0.10000E+01 0.0000 30 CO2,aq 0.23476E-09 -9.6294 0.23387E-09 -9.6310 0.99624E+00 -0.0016 31 CO3-2 0.34999E-05 -5.4559 0.17907E-05 -5.7470 0.51163E+00 -0.2910 32 CaCO3,aq 0.16788E-08 -8.7750 0.16788E-08 -8.7750 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.34657E-11 -11.4602 0.28909E-11 -11.5390 0.83414E+00 -0.0788 34 CaCl+ 0.10821E-09 -9.9657 0.90259E-10 -10.0445 0.83414E+00 -0.0788 35 CaCl2,aq 0.15551E-13 -13.8082 0.15551E-13 -13.8082 0.10000E+01 0.0000 36 CaOH+ 0.83610E-07 -7.0777 0.69742E-07 -7.1565 0.83414E+00 -0.0788 37 CaSO4,aq 0.61018E-16 -16.2145 0.61018E-16 -16.2145 0.10000E+01 0.0000 38 HCl,aq 0.10772E-13 -13.9677 0.10772E-13 -13.9677 0.10000E+01 0.0000 43 FeCl+ 0.45776E-16 -16.3394 0.38184E-16 -16.4181 0.83414E+00 -0.0788 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.17014E-10 -10.7692 0.14192E-10 -10.8480 0.83414E+00 -0.0788 48 HFeO2- 0.36517E-07 -7.4375 0.30400E-07 -7.5171 0.83249E+00 -0.0796 49 FeO+ 0.12558E-16 -16.9011 0.10475E-16 -16.9798 0.83414E+00 -0.0788 51 FeO2- 0.41291E-09 -9.3841 0.34375E-09 -9.4638 0.83249E+00 -0.0796 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10870E-04 -4.9638 0.99624E+00 -0.0016 54 KCl,aq 0.18054E-08 -8.7434 0.18054E-08 -8.7434 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.65242E-14 -14.1855 0.54313E-14 -14.2651 0.83249E+00 -0.0796 58 MgCO3,aq 0.66299E-13 -13.1785 0.66299E-13 -13.1785 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.55855E-15 -15.2529 0.46591E-15 -15.3317 0.83414E+00 -0.0788 60 MgCl+ 0.15525E-13 -13.8090 0.12950E-13 -13.8877 0.83414E+00 -0.0788 61 MgOH+ 0.73208E-10 -10.1354 0.61066E-10 -10.2142 0.83414E+00 -0.0788 63 MnO,aq 0.18789E-08 -8.7261 0.18789E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.50858E-09 -9.2936 0.42422E-09 -9.3724 0.83414E+00 -0.0788 65 MnO2-2 0.21204E-10 -10.6736 0.10849E-10 -10.9646 0.51163E+00 -0.2910 66 HMnO2- 0.21851E-09 -9.6605 0.18191E-09 -9.7401 0.83249E+00 -0.0796 69 MnCl+ 0.57236E-13 -13.2423 0.47743E-13 -13.3211 0.83414E+00 -0.0788 71 NaCl,aq 0.42247E-05 -5.3742 0.42247E-05 -5.3742 0.10000E+01 0.0000 72 NaOH,aq 0.99274E-04 -4.0032 0.99274E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.93276E-02 -2.0302 0.77507E-02 -2.1107 0.83093E+00 -0.0804 79 HPO3-2 0.16176E-14 -14.7911 0.82763E-15 -15.0822 0.51163E+00 -0.2910 81 H2PO3- 0.15114E-18 -18.8206 0.12582E-18 -18.9003 0.83249E+00 -0.0796 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39251E-10 -10.4061 0.32708E-10 -10.4853 0.83331E+00 -0.0792 84 PO4-3 0.11519E-08 -8.9386 0.27202E-09 -9.5654 0.23616E+00 -0.6268 88 HP2O7-3 0.98751E-18 -18.0055 0.22185E-18 -18.6539 0.22465E+00 -0.6485 89 P2O7-4 0.96463E-17 -17.0156 0.70718E-18 -18.1505 0.73311E-01 -1.1348 90 H2S,aq 0.32077E-07 -7.4938 0.31956E-07 -7.4954 0.99624E+00 -0.0016 91 S2-2 0.74694E-13 -13.1267 0.38216E-13 -13.4178 0.51163E+00 -0.2910 97 SO3-2 0.73014E-17 -17.1366 0.37918E-17 -17.4212 0.51932E+00 -0.2846 98 HSO3- 0.20629E-19 -19.6855 0.17173E-19 -19.7651 0.83249E+00 -0.0796 99 HSO4- 0.22002E-18 -18.6575 0.18372E-18 -18.7359 0.83499E+00 -0.0783 Charge balance for all species = 0.4944E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9238272E-10 -.2272354E-01 -.2286196E+02 0.0000 2 H2O 0.1000000E+01 0.5550451E+02 0.9980963E+06 0.0000 3 Cl- 0.8888775E-03 0.8931042E-03 0.3160514E+02 6.9805 4 SO4-- 0.4989477E-11 -.8202995E-04 -.7865474E+01 8.6306 5 HCO3- 0.1797707E-05 0.8460185E-04 0.5152700E+01 4.2871 6 HS- 0.1650579E-03 0.2471199E-03 0.8157758E+01 6.2494 7 Al+++ 0.1190885E-28 0.5171728E-05 0.1392850E+00 0.7608 8 H4SiO4 0.7116653E-03 0.1398044E-01 0.1341271E+04 -3.1477 9 Ca++ 0.1504307E-06 0.2542773E-06 0.1017223E-01 13.1065 10 Mg++ 0.2388874E-10 0.1008115E-09 0.2446435E-05 9.3053 11 Fe++ 0.6534531E-13 0.3716951E-07 0.2071998E-02 6.7428 12 K+ 0.1652298E-03 0.1660078E-03 0.6479331E+01 6.2505 13 Na+ 0.2100727E-01 0.2360229E-01 0.5416167E+03 8.3540 14 Mn++ 0.2100816E-10 0.2648249E-08 0.1452227E-03 9.2504 15 HPO4-- 0.4700593E-07 0.4819705E-07 0.4617420E-02 12.6047 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1390915E+03 -.3510522E-02 -.1390880E+03 0.0000000E+00 2 H2O -.4978918E+02 0.8574800E+01 -.5836398E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2328181E+00 -.1267267E-04 0.2328308E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2327926E+00 0.3817714E-04 -.2328308E+00 0.0000000E+00 7 Al+++ 0.2739023E+02 0.7989717E-06 0.2739023E+02 0.0000000E+00 8 H4SiO4 0.8746737E+02 0.2159815E-02 0.8746521E+02 0.0000000E+00 9 Ca++ 0.9661212E+01 0.3928288E-07 0.9661212E+01 0.0000000E+00 10 Mg++ 0.6666666E+01 0.1557421E-10 0.6666666E+01 0.0000000E+00 11 Fe++ 0.5989271E+01 0.5742256E-08 0.5989271E+01 0.0000000E+00 12 K+ 0.1783439E+01 0.2564627E-04 0.1783414E+01 0.0000000E+00 13 Na+ 0.1054421E+02 0.3646279E-02 0.1054056E+02 0.0000000E+00 14 Mn++ 0.1456442E+00 0.4091236E-09 0.1456442E+00 0.0000000E+00 15 HPO4-- 0.4970764E-01 0.7445882E-08 0.4970763E-01 0.0000000E+00 Chg. balance for solid moles: 0.1724E-13 Mass of aqueous solution: 0.154772E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8399.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.53 1.023 2762. 3.441 30.10 1060. andradite 0.9313 -0.031 473.3 2.675 5.157 123.0 grossular 0.2224 -0.653 100.2 2.001 1.091 27.87 apatite-OH 0.1657E-01 -1.781 8.323 0.920 0.9069E-01 2.645 clinochlore 1.196 0.078 664.8 2.823 7.244 252.9 daphnite 0.3428 -0.465 244.6 2.388 2.665 74.11 chlorite-Mn 0.2913E-01 -1.536 20.65 1.315 0.2250 6.581 diopside 0.4764 -0.322 103.2 2.014 1.124 31.53 hedenbergite 0.1220 -0.913 30.28 1.481 0.3299 8.294 microcline 1.562 0.194 434.7 2.638 4.736 169.8 stilbite 5.403 0.733 3808. 3.581 41.49 1776. stilpnomelane-Fe 0.4436 -0.353 478.2 2.680 5.211 165.2 tr.625ac.25prg.125 0.5801E-01 -1.237 49.58 1.695 0.5403 15.96 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9177.246957 g Volume = 3713.976390 cm3 Porosity: -10.5021% V(tot) - V(min): -.35298E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8399.9990000 g log = 3.9243 Original solution: 1000.0103000 g Original solution / Rock added: 0.12 (Water/Rock Ratio), log = -0.9243 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1922 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8839E+00 0.9838 0.1037E+01 0.1054E+01 CO2,gas 0.2233E-07 1.0058 0.2677E-07 0.2662E-07 CH4,gas 0.1036E+00 1.0116 0.1249E+00 0.1235E+00 H2,gas 0.1250E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.7854E-06 0.9954 0.9320E-06 0.9364E-06 S2,gas 0.1228E-27 1.0000 0.1464E-27 0.1464E-27 CO,gas 0.8672E-13 1.0000 0.1034E-12 0.1034E-12 SO3,gas 0.4805E-47 1.0000 0.5729E-47 0.5729E-47 SO2,gas 0.2710E-26 1.0000 0.3231E-26 0.3231E-26 HCl,gas 0.1595E-16 1.0000 0.1902E-16 0.1902E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 67 diopside 16.22 16.22 0.00 0.000 -0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.60662E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.94 -9.57 -3.191 0.16344E+05 -7.572 3 CH4,gas 4.81 1.91 -2.90 -0.726 0.49573E+04 -0.903 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65338E+04 -1.827 5 H2S,gas -5.94 -13.97 -8.03 -4.015 0.13712E+05 -6.031 6 S2,gas -7.03 -36.87 -29.83 -4.590 0.50942E+05 -27.835 7 CO,gas 3.51 -11.48 -14.99 -4.611 0.25587E+05 -12.986 8 SO3,gas 17.43 -31.81 -49.24 -12.310 0.84079E+05 -47.242 9 SO2,gas 1.14 -27.35 -28.49 -7.598 0.48647E+05 -26.491 10 HCl,gas 5.48 -13.24 -18.72 -9.360 0.31965E+05 -16.721 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80597E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.83 -3.82 -1.272 0.65144E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.83 -3.66 -1.221 0.62531E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65548E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.01 -3.91 -1.116 0.66720E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.01 -3.47 -0.990 0.59182E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82259E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.66 -4.44 -1.044 0.75788E+04 143 pyrrhotite -4.24 -7.23 -2.99 -0.996 0.50999E+04 144 pyrrhotiteFe0.875 -6.00 -8.63 -2.63 -0.966 0.44827E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22425E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23218E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47124E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.23 -2.84 -0.945 0.48431E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60328E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.72 -3.76 -1.253 0.64208E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 8399.9990000 g New total amount of reactant added: 8449.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7637E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8449.9990000 Water: Moles liquid = 0.8297E+01 kg liquid = 0.1495E+00 Moles total = -.5042E+02 kg total = -.9083E+00 Activity = 1.0000 Stoichiometric ionic strength = .1238236E-01 Osmotic coef. = 0.9670 True ionic strength = .2119635E-01 Chg. balance for total moles = 0.7637E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92468E-10 -10.0340 0.77458E-10 -10.1109 0.83768E+00 -0.0769 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.91875E-03 -3.0368 0.76480E-03 -3.1165 0.83244E+00 -0.0796 4 SO4-- 0.51537E-11 -11.2879 0.26419E-11 -11.5781 0.51264E+00 -0.2902 5 HCO3- 0.18568E-05 -5.7312 0.15480E-05 -5.8102 0.83370E+00 -0.0790 6 HS- 0.17061E-03 -3.7680 0.14204E-03 -3.8476 0.83256E+00 -0.0796 7 Al+++ 0.11946E-28 -28.9228 0.26794E-29 -29.5720 0.22428E+00 -0.6492 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.15073E-06 -6.8218 0.76678E-07 -7.1153 0.50872E+00 -0.2935 10 Mg++ 0.23936E-10 -10.6209 0.12119E-10 -10.9165 0.50630E+00 -0.2956 11 Fe++ 0.65475E-13 -13.1839 0.33188E-13 -13.4790 0.50687E+00 -0.2951 12 K+ 0.16538E-03 -3.7815 0.13791E-03 -3.8604 0.83390E+00 -0.0789 13 Na+ 0.21027E-01 -1.6772 0.17500E-01 -1.7570 0.83227E+00 -0.0797 14 Mn++ 0.21050E-10 -10.6767 0.10679E-10 -10.9715 0.50731E+00 -0.2947 15 HPO4-- 0.46936E-07 -7.3285 0.24065E-07 -7.6186 0.51271E+00 -0.2901 16 HSiO3- 0.10769E-01 -1.9678 0.89642E-02 -2.0475 0.83244E+00 -0.0796 17 Ca(HSiO3)+ 0.18464E-07 -7.7337 0.15400E-07 -7.8125 0.83409E+00 -0.0788 18 Mg(HSiO3)+ 0.36317E-11 -11.4399 0.30291E-11 -11.5187 0.83409E+00 -0.0788 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.69120E-16 -16.1604 0.57652E-16 -16.2392 0.83409E+00 -0.0788 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51674E-05 -5.2867 0.42935E-05 -5.3672 0.83088E+00 -0.0805 24 CH4,aq 0.81974E-04 -4.0863 0.81665E-04 -4.0880 0.99623E+00 -0.0016 25 C2H6,aq 0.10621E-12 -12.9738 0.10581E-12 -12.9755 0.99623E+00 -0.0016 29 CO,aq 0.67679E-16 -16.1695 0.67679E-16 -16.1695 0.10000E+01 0.0000 30 CO2,aq 0.24267E-09 -9.6150 0.24175E-09 -9.6166 0.99623E+00 -0.0016 31 CO3-2 0.36125E-05 -5.4422 0.18478E-05 -5.7333 0.51150E+00 -0.2912 32 CaCO3,aq 0.17353E-08 -8.7606 0.17353E-08 -8.7606 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.35857E-11 -11.4454 0.29908E-11 -11.5242 0.83409E+00 -0.0788 34 CaCl+ 0.11204E-09 -9.9506 0.93448E-10 -10.0294 0.83409E+00 -0.0788 35 CaCl2,aq 0.16640E-13 -13.7788 0.16640E-13 -13.7788 0.10000E+01 0.0000 36 CaOH+ 0.83687E-07 -7.0773 0.69802E-07 -7.1561 0.83409E+00 -0.0788 37 CaSO4,aq 0.63119E-16 -16.1998 0.63119E-16 -16.1998 0.10000E+01 0.0000 38 HCl,aq 0.11143E-13 -13.9530 0.11143E-13 -13.9530 0.10000E+01 0.0000 43 FeCl+ 0.47396E-16 -16.3243 0.39532E-16 -16.4030 0.83409E+00 -0.0788 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.17030E-10 -10.7688 0.14204E-10 -10.8476 0.83409E+00 -0.0788 48 HFeO2- 0.36488E-07 -7.4378 0.30374E-07 -7.5175 0.83244E+00 -0.0796 49 FeO+ 0.12570E-16 -16.9007 0.10484E-16 -16.9795 0.83409E+00 -0.0788 51 FeO2- 0.41258E-09 -9.3845 0.34345E-09 -9.4641 0.83244E+00 -0.0796 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10870E-04 -4.9638 0.99623E+00 -0.0016 54 KCl,aq 0.18676E-08 -8.7287 0.18676E-08 -8.7287 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.67434E-14 -14.1711 0.56135E-14 -14.2508 0.83244E+00 -0.0796 58 MgCO3,aq 0.68532E-13 -13.1641 0.68532E-13 -13.1641 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.57790E-15 -15.2381 0.48202E-15 -15.3169 0.83409E+00 -0.0788 60 MgCl+ 0.16075E-13 -13.7939 0.13408E-13 -13.8726 0.83409E+00 -0.0788 61 MgOH+ 0.73276E-10 -10.1350 0.61119E-10 -10.2138 0.83409E+00 -0.0788 63 MnO,aq 0.18789E-08 -8.7261 0.18789E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.50905E-09 -9.2932 0.42459E-09 -9.3720 0.83409E+00 -0.0788 65 MnO2-2 0.21173E-10 -10.6742 0.10830E-10 -10.9654 0.51150E+00 -0.2912 66 HMnO2- 0.21834E-09 -9.6609 0.18176E-09 -9.7405 0.83244E+00 -0.0796 69 MnCl+ 0.59262E-13 -13.2272 0.49430E-13 -13.3060 0.83409E+00 -0.0788 71 NaCl,aq 0.43702E-05 -5.3595 0.43702E-05 -5.3595 0.10000E+01 0.0000 72 NaOH,aq 0.99274E-04 -4.0032 0.99274E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.93202E-02 -2.0306 0.77440E-02 -2.1110 0.83088E+00 -0.0805 79 HPO3-2 0.16152E-14 -14.7918 0.82621E-15 -15.0829 0.51150E+00 -0.2912 81 H2PO3- 0.15101E-18 -18.8210 0.12571E-18 -18.9006 0.83244E+00 -0.0796 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39220E-10 -10.4065 0.32680E-10 -10.4857 0.83325E+00 -0.0792 84 PO4-3 0.11495E-08 -8.9395 0.27132E-09 -9.5665 0.23604E+00 -0.6270 88 HP2O7-3 0.98551E-18 -18.0063 0.22128E-18 -18.6551 0.22453E+00 -0.6487 89 P2O7-4 0.96225E-17 -17.0167 0.70474E-18 -18.1520 0.73239E-01 -1.1353 90 H2S,aq 0.33182E-07 -7.4791 0.33057E-07 -7.4807 0.99623E+00 -0.0016 91 S2-2 0.79808E-13 -13.0980 0.40822E-13 -13.3891 0.51150E+00 -0.2912 97 SO3-2 0.75416E-17 -17.1225 0.39156E-17 -17.4072 0.51920E+00 -0.2847 98 HSO3- 0.21322E-19 -19.6712 0.17749E-19 -19.7508 0.83244E+00 -0.0796 99 HSO4- 0.22742E-18 -18.6432 0.18988E-18 -18.7215 0.83494E+00 -0.0783 Charge balance for all species = 0.5115E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9246796E-10 -.2270757E-01 -.2284587E+02 0.0000 2 H2O 0.1000000E+01 0.5550451E+02 0.9980954E+06 0.0000 3 Cl- 0.9187482E-03 0.9231204E-03 0.3266733E+02 6.9945 4 SO4-- 0.5153665E-11 -.8470167E-04 -.8121646E+01 8.6438 5 HCO3- 0.1856771E-05 0.8744523E-04 0.5325871E+01 4.3007 6 HS- 0.1706052E-03 0.2553401E-03 0.8429110E+01 6.2633 7 Al+++ 0.1194649E-28 0.5167599E-05 0.1391737E+00 0.7608 8 H4SiO4 0.7116653E-03 0.1397182E-01 0.1340443E+04 -3.1477 9 Ca++ 0.1507287E-06 0.2547304E-06 0.1019035E-01 13.1065 10 Mg++ 0.2393615E-10 0.1009314E-09 0.2449341E-05 9.3053 11 Fe++ 0.6547496E-13 0.3714001E-07 0.2070352E-02 6.7428 12 K+ 0.1653828E-03 0.1661609E-03 0.6485299E+01 6.2505 13 Na+ 0.2102675E-01 0.2362192E-01 0.5420666E+03 8.3540 14 Mn++ 0.2104997E-10 0.2648575E-08 0.1452404E-03 9.2504 15 HPO4-- 0.4693642E-07 0.4812513E-07 0.4610525E-02 12.6032 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1399194E+03 -.3393987E-02 -.1399160E+03 0.0000000E+00 2 H2O -.5041595E+02 0.8295981E+01 -.5871194E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2342038E+00 -.1265993E-04 0.2342164E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2341783E+00 0.3816440E-04 -.2342164E+00 0.0000000E+00 7 Al+++ 0.2755326E+02 0.7723751E-06 0.2755326E+02 0.0000000E+00 8 H4SiO4 0.8798801E+02 0.2088298E-02 0.8798592E+02 0.0000000E+00 9 Ca++ 0.9718719E+01 0.3807327E-07 0.9718719E+01 0.0000000E+00 10 Mg++ 0.6706348E+01 0.1508571E-10 0.6706348E+01 0.0000000E+00 11 Fe++ 0.6024922E+01 0.5551131E-08 0.6024922E+01 0.0000000E+00 12 K+ 0.1794055E+01 0.2483523E-04 0.1794030E+01 0.0000000E+00 13 Na+ 0.1060697E+02 0.3530650E-02 0.1060344E+02 0.0000000E+00 14 Mn++ 0.1465111E+00 0.3958693E-09 0.1465111E+00 0.0000000E+00 15 HPO4-- 0.5000352E-01 0.7193022E-08 0.5000351E-01 0.0000000E+00 Chg. balance for solid moles: -.1138E-13 Mass of aqueous solution: 0.149740E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8449.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.60 1.025 2779. 3.444 30.10 1067. andradite 0.9369 -0.028 476.1 2.678 5.157 123.7 grossular 0.2237 -0.650 100.8 2.003 1.091 28.03 apatite-OH 0.1667E-01 -1.778 8.373 0.923 0.9069E-01 2.660 clinochlore 1.203 0.080 668.7 2.825 7.244 254.4 daphnite 0.3448 -0.462 246.0 2.391 2.665 74.55 chlorite-Mn 0.2930E-01 -1.533 20.77 1.318 0.2250 6.620 diopside 0.4793 -0.319 103.8 2.016 1.124 31.72 hedenbergite 0.1228 -0.911 30.46 1.484 0.3300 8.344 microcline 1.571 0.196 437.2 2.641 4.736 170.8 stilbite 5.435 0.735 3830. 3.583 41.49 1786. stilpnomelane-Fe 0.4463 -0.350 481.1 2.682 5.211 166.2 tr.625ac.25prg.125 0.5835E-01 -1.234 49.88 1.698 0.5403 16.05 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9231.874695 g Volume = 3736.079567 cm3 Porosity: -10.5022% V(tot) - V(min): -.35508E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8449.9990000 g log = 3.9269 Original solution: 1000.0103000 g Original solution / Rock added: 0.12 (Water/Rock Ratio), log = -0.9269 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.1964 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8808E+00 0.9837 0.1037E+01 0.1054E+01 CO2,gas 0.2300E-07 1.0057 0.2767E-07 0.2752E-07 CH4,gas 0.1067E+00 1.0115 0.1291E+00 0.1277E+00 H2,gas 0.1245E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.8096E-06 0.9954 0.9641E-06 0.9686E-06 S2,gas 0.1309E-27 1.0000 0.1566E-27 0.1566E-27 CO,gas 0.8932E-13 1.0000 0.1069E-12 0.1069E-12 SO3,gas 0.4953E-47 1.0000 0.5926E-47 0.5926E-47 SO2,gas 0.2793E-26 1.0000 0.3342E-26 0.3342E-26 HCl,gas 0.1644E-16 1.0000 0.1968E-16 0.1968E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.92 -9.56 -3.186 0.16320E+05 -7.558 3 CH4,gas 4.81 1.92 -2.89 -0.722 0.49328E+04 -0.889 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65338E+04 -1.827 5 H2S,gas -5.94 -13.96 -8.02 -4.008 0.13687E+05 -6.016 6 S2,gas -7.03 -36.84 -29.81 -4.585 0.50891E+05 -27.805 7 CO,gas 3.51 -11.46 -14.97 -4.607 0.25563E+05 -12.971 8 SO3,gas 17.43 -31.80 -49.23 -12.307 0.84054E+05 -47.227 9 SO2,gas 1.14 -27.34 -28.48 -7.594 0.48622E+05 -26.476 10 HCl,gas 5.48 -13.23 -18.71 -9.353 0.31940E+05 -16.706 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80597E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.81 -3.80 -1.267 0.64898E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.81 -3.65 -1.216 0.62285E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65548E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -7.00 -3.89 -1.112 0.66475E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -7.00 -3.45 -0.986 0.58936E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82259E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.63 -4.41 -1.037 0.75286E+04 143 pyrrhotite -4.24 -7.22 -2.97 -0.991 0.50748E+04 144 pyrrhotiteFe0.875 -6.00 -8.61 -2.61 -0.960 0.44576E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22425E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23218E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47124E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.22 -2.82 -0.941 0.48180E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60328E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.71 -3.75 -1.249 0.63957E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 8449.9990000 g New total amount of reactant added: 8499.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7633E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8499.9990000 Water: Moles liquid = 0.8018E+01 kg liquid = 0.1444E+00 Moles total = -.5104E+02 kg total = -.9196E+00 Activity = 1.0000 Stoichiometric ionic strength = .1240918E-01 Osmotic coef. = 0.9669 True ionic strength = .2121748E-01 Chg. balance for total moles = 0.7633E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92559E-10 -10.0336 0.77530E-10 -10.1105 0.83762E+00 -0.0770 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.95070E-03 -3.0220 0.79134E-03 -3.1016 0.83238E+00 -0.0797 4 SO4-- 0.53290E-11 -11.2734 0.27311E-11 -11.5637 0.51250E+00 -0.2903 5 HCO3- 0.19198E-05 -5.7167 0.16005E-05 -5.7958 0.83364E+00 -0.0790 6 HS- 0.17654E-03 -3.7532 0.14697E-03 -3.8328 0.83251E+00 -0.0796 7 Al+++ 0.11987E-28 -28.9213 0.26868E-29 -29.5708 0.22415E+00 -0.6495 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.15105E-06 -6.8209 0.76820E-07 -7.1145 0.50858E+00 -0.2936 10 Mg++ 0.23987E-10 -10.6200 0.12141E-10 -10.9157 0.50616E+00 -0.2957 11 Fe++ 0.65614E-13 -13.1830 0.33249E-13 -13.4782 0.50673E+00 -0.2952 12 K+ 0.16555E-03 -3.7811 0.13804E-03 -3.8600 0.83385E+00 -0.0789 13 Na+ 0.21048E-01 -1.6768 0.17516E-01 -1.7566 0.83222E+00 -0.0798 14 Mn++ 0.21095E-10 -10.6758 0.10699E-10 -10.9707 0.50717E+00 -0.2948 15 HPO4-- 0.46862E-07 -7.3292 0.24020E-07 -7.6194 0.51258E+00 -0.2902 16 HSiO3- 0.10759E-01 -1.9682 0.89559E-02 -2.0479 0.83238E+00 -0.0797 17 Ca(HSiO3)+ 0.18482E-07 -7.7333 0.15415E-07 -7.8121 0.83403E+00 -0.0788 18 Mg(HSiO3)+ 0.36353E-11 -11.4395 0.30319E-11 -11.5183 0.83403E+00 -0.0788 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.69188E-16 -16.1600 0.57705E-16 -16.2388 0.83403E+00 -0.0788 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51630E-05 -5.2871 0.42896E-05 -5.3676 0.83082E+00 -0.0805 24 CH4,aq 0.84832E-04 -4.0714 0.84512E-04 -4.0731 0.99622E+00 -0.0016 25 C2H6,aq 0.11375E-12 -12.9441 0.11332E-12 -12.9457 0.99622E+00 -0.0016 29 CO,aq 0.70038E-16 -16.1547 0.70038E-16 -16.1547 0.10000E+01 0.0000 30 CO2,aq 0.25113E-09 -9.6001 0.25018E-09 -9.6017 0.99622E+00 -0.0016 31 CO3-2 0.37325E-05 -5.4280 0.19087E-05 -5.7193 0.51137E+00 -0.2913 32 CaCO3,aq 0.17958E-08 -8.7457 0.17958E-08 -8.7457 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.37144E-11 -11.4301 0.30979E-11 -11.5089 0.83403E+00 -0.0788 34 CaCl+ 0.11615E-09 -9.9350 0.96869E-10 -10.0138 0.83403E+00 -0.0788 35 CaCl2,aq 0.17848E-13 -13.7484 0.17848E-13 -13.7484 0.10000E+01 0.0000 36 CaOH+ 0.83770E-07 -7.0769 0.69867E-07 -7.1557 0.83403E+00 -0.0788 37 CaSO4,aq 0.65370E-16 -16.1846 0.65370E-16 -16.1846 0.10000E+01 0.0000 38 HCl,aq 0.11540E-13 -13.9378 0.11540E-13 -13.9378 0.10000E+01 0.0000 43 FeCl+ 0.49135E-16 -16.3086 0.40980E-16 -16.3874 0.83403E+00 -0.0788 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.17047E-10 -10.7684 0.14217E-10 -10.8472 0.83403E+00 -0.0788 48 HFeO2- 0.36457E-07 -7.4382 0.30346E-07 -7.5179 0.83238E+00 -0.0797 49 FeO+ 0.12582E-16 -16.9002 0.10494E-16 -16.9791 0.83403E+00 -0.0788 51 FeO2- 0.41223E-09 -9.3849 0.34313E-09 -9.4645 0.83238E+00 -0.0797 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10870E-04 -4.9638 0.99622E+00 -0.0016 54 KCl,aq 0.19342E-08 -8.7135 0.19342E-08 -8.7135 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.69780E-14 -14.1563 0.58083E-14 -14.2360 0.83238E+00 -0.0797 58 MgCO3,aq 0.70921E-13 -13.1492 0.70921E-13 -13.1492 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.59863E-15 -15.2228 0.49928E-15 -15.3017 0.83403E+00 -0.0788 60 MgCl+ 0.16664E-13 -13.7782 0.13899E-13 -13.8570 0.83403E+00 -0.0788 61 MgOH+ 0.73349E-10 -10.1346 0.61175E-10 -10.2134 0.83403E+00 -0.0788 63 MnO,aq 0.18789E-08 -8.7261 0.18789E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.50956E-09 -9.2928 0.42499E-09 -9.3716 0.83403E+00 -0.0788 65 MnO2-2 0.21140E-10 -10.6749 0.10810E-10 -10.9662 0.51137E+00 -0.2913 66 HMnO2- 0.21816E-09 -9.6612 0.18159E-09 -9.7409 0.83238E+00 -0.0797 69 MnCl+ 0.61436E-13 -13.2116 0.51240E-13 -13.2904 0.83403E+00 -0.0788 71 NaCl,aq 0.45261E-05 -5.3443 0.45261E-05 -5.3443 0.10000E+01 0.0000 72 NaOH,aq 0.99274E-04 -4.0032 0.99274E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.93122E-02 -2.0309 0.77368E-02 -2.1114 0.83082E+00 -0.0805 79 HPO3-2 0.16127E-14 -14.7924 0.82468E-15 -15.0837 0.51137E+00 -0.2913 81 H2PO3- 0.15089E-18 -18.8214 0.12559E-18 -18.9010 0.83238E+00 -0.0797 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39186E-10 -10.4069 0.32650E-10 -10.4861 0.83320E+00 -0.0793 84 PO4-3 0.11470E-08 -8.9405 0.27057E-09 -9.5677 0.23590E+00 -0.6273 88 HP2O7-3 0.98338E-18 -18.0073 0.22066E-18 -18.6563 0.22439E+00 -0.6490 89 P2O7-4 0.95971E-17 -17.0179 0.70215E-18 -18.1536 0.73162E-01 -1.1357 90 H2S,aq 0.34365E-07 -7.4639 0.34236E-07 -7.4655 0.99622E+00 -0.0016 91 S2-2 0.85467E-13 -13.0682 0.43705E-13 -13.3595 0.51137E+00 -0.2913 97 SO3-2 0.77981E-17 -17.1080 0.40477E-17 -17.3928 0.51907E+00 -0.2848 98 HSO3- 0.22064E-19 -19.6563 0.18365E-19 -19.7360 0.83238E+00 -0.0797 99 HSO4- 0.23533E-18 -18.6283 0.19647E-18 -18.7067 0.83488E+00 -0.0784 Charge balance for all species = 0.5287E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9255921E-10 -.2269051E-01 -.2282868E+02 0.0000 2 H2O 0.1000000E+01 0.5550452E+02 0.9980944E+06 0.0000 3 Cl- 0.9506963E-03 0.9552244E-03 0.3380339E+02 7.0089 4 SO4-- 0.5329025E-11 -.8755968E-04 -.8395678E+01 8.6574 5 HCO3- 0.1919847E-05 0.9048638E-04 0.5511087E+01 4.3148 6 HS- 0.1765385E-03 0.2641325E-03 0.8719351E+01 6.2778 7 Al+++ 0.1198688E-28 0.5163187E-05 0.1390547E+00 0.7608 8 H4SiO4 0.7116653E-03 0.1396261E-01 0.1339558E+04 -3.1477 9 Ca++ 0.1510481E-06 0.2552156E-06 0.1020975E-01 13.1065 10 Mg++ 0.2398696E-10 0.1010596E-09 0.2452449E-05 9.3053 11 Fe++ 0.6561389E-13 0.3710845E-07 0.2068590E-02 6.7428 12 K+ 0.1655466E-03 0.1663247E-03 0.6491686E+01 6.2505 13 Na+ 0.2104760E-01 0.2364293E-01 0.5425481E+03 8.3540 14 Mn++ 0.2109476E-10 0.2648923E-08 0.1452593E-03 9.2504 15 HPO4-- 0.4686221E-07 0.4804835E-07 0.4603165E-02 12.6016 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1407474E+03 -.3277455E-02 -.1407441E+03 0.0000000E+00 2 H2O -.5104272E+02 0.8017163E+01 -.5905989E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2355895E+00 -.1264726E-04 0.2356021E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2355639E+00 0.3815173E-04 -.2356021E+00 0.0000000E+00 7 Al+++ 0.2771630E+02 0.7457792E-06 0.2771630E+02 0.0000000E+00 8 H4SiO4 0.8850864E+02 0.2016783E-02 0.8850663E+02 0.0000000E+00 9 Ca++ 0.9776226E+01 0.3686376E-07 0.9776226E+01 0.0000000E+00 10 Mg++ 0.6746031E+01 0.1459721E-10 0.6746031E+01 0.0000000E+00 11 Fe++ 0.6060572E+01 0.5360006E-08 0.6060572E+01 0.0000000E+00 12 K+ 0.1804671E+01 0.2402421E-04 0.1804647E+01 0.0000000E+00 13 Na+ 0.1066973E+02 0.3415023E-02 0.1066631E+02 0.0000000E+00 14 Mn++ 0.1473780E+00 0.3826148E-09 0.1473780E+00 0.0000000E+00 15 HPO4-- 0.5029940E-01 0.6940183E-08 0.5029939E-01 0.0000000E+00 Chg. balance for solid moles: -.1077E-13 Mass of aqueous solution: 0.144707E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8499.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.66 1.028 2795. 3.446 30.10 1073. andradite 0.9424 -0.026 478.9 2.680 5.157 124.4 grossular 0.2250 -0.648 101.4 2.006 1.091 28.20 apatite-OH 0.1677E-01 -1.776 8.422 0.925 0.9069E-01 2.676 clinochlore 1.210 0.083 672.7 2.828 7.244 255.9 daphnite 0.3469 -0.460 247.5 2.394 2.665 75.00 chlorite-Mn 0.2948E-01 -1.531 20.90 1.320 0.2250 6.659 diopside 0.4822 -0.317 104.4 2.019 1.124 31.91 hedenbergite 0.1235 -0.908 30.65 1.486 0.3300 8.394 microcline 1.580 0.199 439.8 2.643 4.736 171.8 stilbite 5.467 0.738 3853. 3.586 41.49 1797. stilpnomelane-Fe 0.4489 -0.348 483.9 2.685 5.211 167.2 tr.625ac.25prg.125 0.5869E-01 -1.231 50.17 1.700 0.5402 16.15 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9286.502432 g Volume = 3758.182744 cm3 Porosity: -10.5023% V(tot) - V(min): -.35718E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8499.9990000 g log = 3.9294 Original solution: 1000.0103000 g Original solution / Rock added: 0.12 (Water/Rock Ratio), log = -0.9294 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2009 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8776E+00 0.9837 0.1037E+01 0.1054E+01 CO2,gas 0.2371E-07 1.0057 0.2864E-07 0.2848E-07 CH4,gas 0.1100E+00 1.0115 0.1336E+00 0.1321E+00 H2,gas 0.1241E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.8353E-06 0.9953 0.9985E-06 0.1003E-05 S2,gas 0.1399E-27 1.0000 0.1680E-27 0.1680E-27 CO,gas 0.9209E-13 1.0000 0.1106E-12 0.1106E-12 SO3,gas 0.5110E-47 1.0000 0.6137E-47 0.6137E-47 SO2,gas 0.2882E-26 1.0000 0.3461E-26 0.3461E-26 HCl,gas 0.1697E-16 1.0000 0.2038E-16 0.2038E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.36397E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.60662E-11 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.91 -9.54 -3.181 0.16295E+05 -7.543 3 CH4,gas 4.81 1.94 -2.87 -0.719 0.49074E+04 -0.874 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65338E+04 -1.827 5 H2S,gas -5.94 -13.94 -8.00 -4.000 0.13661E+05 -6.001 6 S2,gas -7.03 -36.81 -29.77 -4.581 0.50839E+05 -27.775 7 CO,gas 3.51 -11.45 -14.96 -4.602 0.25537E+05 -12.956 8 SO3,gas 17.43 -31.78 -49.21 -12.303 0.84028E+05 -47.212 9 SO2,gas 1.14 -27.32 -28.46 -7.590 0.48596E+05 -26.461 10 HCl,gas 5.48 -13.21 -18.69 -9.345 0.31914E+05 -16.691 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80596E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.80 -3.79 -1.262 0.64644E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.80 -3.63 -1.211 0.62031E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65548E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -6.99 -3.88 -1.108 0.66221E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -6.99 -3.44 -0.982 0.58682E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82258E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.60 -4.38 -1.030 0.74766E+04 143 pyrrhotite -4.24 -7.20 -2.96 -0.986 0.50488E+04 144 pyrrhotiteFe0.875 -6.00 -8.60 -2.60 -0.955 0.44316E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22425E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23218E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47124E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.20 -2.81 -0.935 0.47920E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60328E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.69 -3.73 -1.244 0.63697E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 8499.9990000 g New total amount of reactant added: 8549.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7634E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8549.9990000 Water: Moles liquid = 0.7739E+01 kg liquid = 0.1394E+00 Moles total = -.5167E+02 kg total = -.9308E+00 Activity = 1.0000 Stoichiometric ionic strength = .1243795E-01 Osmotic coef. = 0.9669 True ionic strength = .2124016E-01 Chg. balance for total moles = 0.7634E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92657E-10 -10.0331 0.77607E-10 -10.1101 0.83757E+00 -0.0770 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.98495E-03 -3.0066 0.81979E-03 -3.0863 0.83232E+00 -0.0797 4 SO4-- 0.55167E-11 -11.2583 0.28265E-11 -11.5487 0.51235E+00 -0.2904 5 HCO3- 0.19874E-05 -5.7017 0.16566E-05 -5.7808 0.83358E+00 -0.0791 6 HS- 0.18290E-03 -3.7378 0.15225E-03 -3.8174 0.83245E+00 -0.0796 7 Al+++ 0.12030E-28 -28.9197 0.26948E-29 -29.5695 0.22400E+00 -0.6497 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.15139E-06 -6.8199 0.76972E-07 -7.1137 0.50843E+00 -0.2938 10 Mg++ 0.24042E-10 -10.6190 0.12165E-10 -10.9149 0.50601E+00 -0.2958 11 Fe++ 0.65763E-13 -13.1820 0.33315E-13 -13.4774 0.50659E+00 -0.2953 12 K+ 0.16572E-03 -3.7806 0.13818E-03 -3.8596 0.83379E+00 -0.0789 13 Na+ 0.21070E-01 -1.6763 0.17534E-01 -1.7561 0.83216E+00 -0.0798 14 Mn++ 0.21143E-10 -10.6748 0.10720E-10 -10.9698 0.50702E+00 -0.2950 15 HPO4-- 0.46783E-07 -7.3299 0.23973E-07 -7.6203 0.51243E+00 -0.2904 16 HSiO3- 0.10750E-01 -1.9686 0.89470E-02 -2.0483 0.83232E+00 -0.0797 17 Ca(HSiO3)+ 0.18502E-07 -7.7328 0.15430E-07 -7.8116 0.83397E+00 -0.0788 18 Mg(HSiO3)+ 0.36391E-11 -11.4390 0.30349E-11 -11.5178 0.83397E+00 -0.0788 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.69262E-16 -16.1595 0.57763E-16 -16.2384 0.83397E+00 -0.0788 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51583E-05 -5.2875 0.42853E-05 -5.3680 0.83076E+00 -0.0805 24 CH4,aq 0.87896E-04 -4.0560 0.87564E-04 -4.0577 0.99621E+00 -0.0016 25 C2H6,aq 0.12211E-12 -12.9132 0.12165E-12 -12.9149 0.99621E+00 -0.0016 29 CO,aq 0.72568E-16 -16.1393 0.72568E-16 -16.1393 0.10000E+01 0.0000 30 CO2,aq 0.26020E-09 -9.5847 0.25921E-09 -9.5863 0.99621E+00 -0.0016 31 CO3-2 0.38607E-05 -5.4133 0.19737E-05 -5.7047 0.51122E+00 -0.2914 32 CaCO3,aq 0.18606E-08 -8.7303 0.18606E-08 -8.7303 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.38526E-11 -11.4142 0.32130E-11 -11.4931 0.83397E+00 -0.0788 34 CaCl+ 0.12057E-09 -9.9188 0.10055E-09 -9.9976 0.83397E+00 -0.0788 35 CaCl2,aq 0.19193E-13 -13.7169 0.19193E-13 -13.7169 0.10000E+01 0.0000 36 CaOH+ 0.83859E-07 -7.0765 0.69936E-07 -7.1553 0.83397E+00 -0.0788 37 CaSO4,aq 0.67788E-16 -16.1688 0.67788E-16 -16.1688 0.10000E+01 0.0000 38 HCl,aq 0.11967E-13 -13.9220 0.11967E-13 -13.9220 0.10000E+01 0.0000 43 FeCl+ 0.51006E-16 -16.2924 0.42537E-16 -16.3712 0.83397E+00 -0.0788 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.17065E-10 -10.7679 0.14232E-10 -10.8467 0.83397E+00 -0.0788 48 HFeO2- 0.36424E-07 -7.4386 0.30316E-07 -7.5183 0.83232E+00 -0.0797 49 FeO+ 0.12596E-16 -16.8998 0.10505E-16 -16.9786 0.83397E+00 -0.0788 51 FeO2- 0.41185E-09 -9.3853 0.34279E-09 -9.4650 0.83232E+00 -0.0797 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10870E-04 -4.9638 0.99621E+00 -0.0016 54 KCl,aq 0.20057E-08 -8.6977 0.20057E-08 -8.6977 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.72294E-14 -14.1409 0.60171E-14 -14.2206 0.83232E+00 -0.0797 58 MgCO3,aq 0.73482E-13 -13.1338 0.73482E-13 -13.1338 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.62091E-15 -15.2070 0.51782E-15 -15.2858 0.83397E+00 -0.0788 60 MgCl+ 0.17299E-13 -13.7620 0.14427E-13 -13.8408 0.83397E+00 -0.0788 61 MgOH+ 0.73426E-10 -10.1341 0.61236E-10 -10.2130 0.83397E+00 -0.0788 63 MnO,aq 0.18789E-08 -8.7261 0.18789E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.51010E-09 -9.2923 0.42541E-09 -9.3712 0.83397E+00 -0.0788 65 MnO2-2 0.21104E-10 -10.6756 0.10789E-10 -10.9670 0.51122E+00 -0.2914 66 HMnO2- 0.21796E-09 -9.6616 0.18141E-09 -9.7413 0.83232E+00 -0.0797 69 MnCl+ 0.63776E-13 -13.1953 0.53188E-13 -13.2742 0.83397E+00 -0.0788 71 NaCl,aq 0.46934E-05 -5.3285 0.46934E-05 -5.3285 0.10000E+01 0.0000 72 NaOH,aq 0.99274E-04 -4.0032 0.99274E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.93037E-02 -2.0313 0.77292E-02 -2.1119 0.83076E+00 -0.0805 79 HPO3-2 0.16100E-14 -14.7932 0.82305E-15 -15.0846 0.51122E+00 -0.2914 81 H2PO3- 0.15075E-18 -18.8218 0.12547E-18 -18.9015 0.83232E+00 -0.0797 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39150E-10 -10.4073 0.32618E-10 -10.4865 0.83314E+00 -0.0793 84 PO4-3 0.11443E-08 -8.9415 0.26977E-09 -9.5690 0.23576E+00 -0.6275 88 HP2O7-3 0.98110E-18 -18.0083 0.22001E-18 -18.6576 0.22425E+00 -0.6493 89 P2O7-4 0.95699E-17 -17.0191 0.69937E-18 -18.1553 0.73080E-01 -1.1362 90 H2S,aq 0.35637E-07 -7.4481 0.35502E-07 -7.4498 0.99621E+00 -0.0016 91 S2-2 0.91750E-13 -13.0374 0.46905E-13 -13.3288 0.51122E+00 -0.2914 97 SO3-2 0.80727E-17 -17.0930 0.41891E-17 -17.3779 0.51893E+00 -0.2849 98 HSO3- 0.22859E-19 -19.6410 0.19026E-19 -19.7207 0.83232E+00 -0.0797 99 HSO4- 0.24380E-18 -18.6130 0.20353E-18 -18.6914 0.83482E+00 -0.0784 Charge balance for all species = 0.5479E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9265711E-10 -.2267224E-01 -.2281027E+02 0.0000 2 H2O 0.1000000E+01 0.5550452E+02 0.9980934E+06 0.0000 3 Cl- 0.9849464E-03 0.9896420E-03 0.3502131E+02 7.0238 4 SO4-- 0.5516736E-11 -.9062416E-04 -.8689507E+01 8.6715 5 HCO3- 0.1987357E-05 0.9374667E-04 0.5709650E+01 4.3293 6 HS- 0.1828993E-03 0.2735591E-03 0.9030523E+01 6.2927 7 Al+++ 0.1203032E-28 0.5158463E-05 0.1389273E+00 0.7608 8 H4SiO4 0.7116653E-03 0.1395276E-01 0.1338611E+04 -3.1477 9 Ca++ 0.1513912E-06 0.2557367E-06 0.1023058E-01 13.1065 10 Mg++ 0.2404154E-10 0.1012098E-09 0.2456091E-05 9.3053 11 Fe++ 0.6576314E-13 0.3707470E-07 0.2066707E-02 6.7428 12 K+ 0.1657223E-03 0.1665005E-03 0.6498539E+01 6.2505 13 Na+ 0.2106997E-01 0.2366547E-01 0.5430648E+03 8.3540 14 Mn++ 0.2114286E-10 0.2649295E-08 0.1452795E-03 9.2504 15 HPO4-- 0.4678279E-07 0.4796619E-07 0.4595289E-02 12.5999 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1415753E+03 -.3160925E-02 -.1415721E+03 0.0000000E+00 2 H2O -.5166950E+02 0.7738345E+01 -.5940784E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2369751E+00 -.1263466E-04 0.2369878E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2369496E+00 0.3813913E-04 -.2369878E+00 0.0000000E+00 7 Al+++ 0.2787934E+02 0.7191840E-06 0.2787934E+02 0.0000000E+00 8 H4SiO4 0.8902928E+02 0.1945269E-02 0.8902734E+02 0.0000000E+00 9 Ca++ 0.9833733E+01 0.3565437E-07 0.9833733E+01 0.0000000E+00 10 Mg++ 0.6785713E+01 0.1411049E-10 0.6785713E+01 0.0000000E+00 11 Fe++ 0.6096223E+01 0.5168891E-08 0.6096223E+01 0.0000000E+00 12 K+ 0.1815286E+01 0.2321321E-04 0.1815263E+01 0.0000000E+00 13 Na+ 0.1073249E+02 0.3299399E-02 0.1072919E+02 0.0000000E+00 14 Mn++ 0.1482450E+00 0.3693602E-09 0.1482450E+00 0.0000000E+00 15 HPO4-- 0.5059527E-01 0.6687364E-08 0.5059527E-01 0.0000000E+00 Chg. balance for solid moles: 0.2826E-13 Mass of aqueous solution: 0.139675E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8549.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.72 1.030 2811. 3.449 30.10 1079. andradite 0.9480 -0.023 481.7 2.683 5.157 125.2 grossular 0.2263 -0.645 101.9 2.008 1.091 28.37 apatite-OH 0.1687E-01 -1.773 8.472 0.928 0.9069E-01 2.692 clinochlore 1.217 0.085 676.6 2.830 7.244 257.4 daphnite 0.3489 -0.457 248.9 2.396 2.665 75.44 chlorite-Mn 0.2965E-01 -1.528 21.02 1.323 0.2250 6.699 diopside 0.4851 -0.314 105.0 2.021 1.125 32.10 hedenbergite 0.1243 -0.906 30.83 1.489 0.3301 8.445 microcline 1.589 0.201 442.4 2.646 4.736 172.8 stilbite 5.499 0.740 3875. 3.588 41.49 1808. stilpnomelane-Fe 0.4516 -0.345 486.8 2.687 5.211 168.1 tr.625ac.25prg.125 0.5903E-01 -1.229 50.46 1.703 0.5402 16.24 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9341.130170 g Volume = 3780.285920 cm3 Porosity: -10.5024% V(tot) - V(min): -.35929E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8549.9990000 g log = 3.9320 Original solution: 1000.0103000 g Original solution / Rock added: 0.12 (Water/Rock Ratio), log = -0.9320 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2058 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8741E+00 0.9836 0.1037E+01 0.1054E+01 CO2,gas 0.2447E-07 1.0056 0.2967E-07 0.2951E-07 CH4,gas 0.1135E+00 1.0114 0.1385E+00 0.1369E+00 H2,gas 0.1236E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.8628E-06 0.9953 0.1035E-05 0.1040E-05 S2,gas 0.1498E-27 1.0000 0.1807E-27 0.1807E-27 CO,gas 0.9503E-13 1.0000 0.1146E-12 0.1146E-12 SO3,gas 0.5278E-47 1.0000 0.6364E-47 0.6364E-47 SO2,gas 0.2977E-26 1.0000 0.3589E-26 0.3589E-26 HCl,gas 0.1752E-16 1.0000 0.2113E-16 0.2113E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.36397E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.89 -9.53 -3.176 0.16268E+05 -7.528 3 CH4,gas 4.81 1.95 -2.86 -0.715 0.48811E+04 -0.859 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65338E+04 -1.827 5 H2S,gas -5.94 -13.93 -7.98 -3.992 0.13634E+05 -5.985 6 S2,gas -7.03 -36.78 -29.74 -4.576 0.50786E+05 -27.743 7 CO,gas 3.51 -11.43 -14.94 -4.597 0.25511E+05 -12.941 8 SO3,gas 17.43 -31.77 -49.20 -12.299 0.84001E+05 -47.196 9 SO2,gas 1.14 -27.31 -28.44 -7.585 0.48569E+05 -26.445 10 HCl,gas 5.48 -13.20 -18.68 -9.338 0.31887E+05 -16.675 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80596E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.78 -3.77 -1.257 0.64381E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.78 -3.62 -1.206 0.61768E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65548E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -6.97 -3.86 -1.104 0.65957E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -6.97 -3.42 -0.978 0.58419E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82258E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.57 -4.35 -1.023 0.74228E+04 143 pyrrhotite -4.24 -7.18 -2.94 -0.980 0.50219E+04 144 pyrrhotiteFe0.875 -6.00 -8.58 -2.58 -0.949 0.44047E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22425E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23218E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47123E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.18 -2.79 -0.930 0.47651E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60328E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.68 -3.71 -1.238 0.63428E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 8549.9990000 g New total amount of reactant added: 8599.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7635E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8599.9990000 Water: Moles liquid = 0.7460E+01 kg liquid = 0.1344E+00 Moles total = -.5230E+02 kg total = -.9421E+00 Activity = 1.0000 Stoichiometric ionic strength = .1246887E-01 Osmotic coef. = 0.9668 True ionic strength = .2126456E-01 Chg. balance for total moles = 0.7635E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92762E-10 -10.0326 0.77689E-10 -10.1096 0.83751E+00 -0.0770 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.10218E-02 -2.9907 0.85036E-03 -3.0704 0.83225E+00 -0.0797 4 SO4-- 0.57182E-11 -11.2427 0.29288E-11 -11.5333 0.51220E+00 -0.2906 5 HCO3- 0.20598E-05 -5.6862 0.17169E-05 -5.7653 0.83352E+00 -0.0791 6 HS- 0.18974E-03 -3.7219 0.15793E-03 -3.8015 0.83238E+00 -0.0797 7 Al+++ 0.12077E-28 -28.9180 0.27034E-29 -29.5681 0.22385E+00 -0.6500 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.15176E-06 -6.8188 0.77136E-07 -7.1127 0.50827E+00 -0.2939 10 Mg++ 0.24100E-10 -10.6180 0.12191E-10 -10.9140 0.50585E+00 -0.2960 11 Fe++ 0.65924E-13 -13.1810 0.33386E-13 -13.4764 0.50643E+00 -0.2955 12 K+ 0.16591E-03 -3.7801 0.13832E-03 -3.8591 0.83372E+00 -0.0790 13 Na+ 0.21094E-01 -1.6758 0.17552E-01 -1.7557 0.83209E+00 -0.0798 14 Mn++ 0.21195E-10 -10.6738 0.10743E-10 -10.9689 0.50686E+00 -0.2951 15 HPO4-- 0.46698E-07 -7.3307 0.23922E-07 -7.6212 0.51227E+00 -0.2905 16 HSiO3- 0.10739E-01 -1.9690 0.89375E-02 -2.0488 0.83225E+00 -0.0797 17 Ca(HSiO3)+ 0.18523E-07 -7.7323 0.15446E-07 -7.8112 0.83391E+00 -0.0789 18 Mg(HSiO3)+ 0.36433E-11 -11.4385 0.30382E-11 -11.5174 0.83391E+00 -0.0789 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.69341E-16 -16.1590 0.57824E-16 -16.2379 0.83391E+00 -0.0789 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51532E-05 -5.2879 0.42808E-05 -5.3685 0.83069E+00 -0.0806 24 CH4,aq 0.91191E-04 -4.0400 0.90844E-04 -4.0417 0.99620E+00 -0.0017 25 C2H6,aq 0.13143E-12 -12.8813 0.13094E-12 -12.8829 0.99620E+00 -0.0017 29 CO,aq 0.75287E-16 -16.1233 0.75287E-16 -16.1233 0.10000E+01 0.0000 30 CO2,aq 0.26995E-09 -9.5687 0.26893E-09 -9.5704 0.99620E+00 -0.0017 31 CO3-2 0.39981E-05 -5.3981 0.20433E-05 -5.6897 0.51107E+00 -0.2915 32 CaCO3,aq 0.19304E-08 -8.7144 0.19304E-08 -8.7144 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.40015E-11 -11.3978 0.33369E-11 -11.4767 0.83391E+00 -0.0789 34 CaCl+ 0.12534E-09 -9.9019 0.10452E-09 -9.9808 0.83391E+00 -0.0789 35 CaCl2,aq 0.20695E-13 -13.6841 0.20695E-13 -13.6841 0.10000E+01 0.0000 36 CaOH+ 0.83954E-07 -7.0760 0.70010E-07 -7.1548 0.83391E+00 -0.0789 37 CaSO4,aq 0.70391E-16 -16.1525 0.70391E-16 -16.1525 0.10000E+01 0.0000 38 HCl,aq 0.12426E-13 -13.9057 0.12426E-13 -13.9057 0.10000E+01 0.0000 43 FeCl+ 0.53024E-16 -16.2755 0.44218E-16 -16.3544 0.83391E+00 -0.0789 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.17084E-10 -10.7674 0.14247E-10 -10.8463 0.83391E+00 -0.0789 48 HFeO2- 0.36388E-07 -7.4390 0.30284E-07 -7.5188 0.83225E+00 -0.0797 49 FeO+ 0.12610E-16 -16.8993 0.10516E-16 -16.9782 0.83391E+00 -0.0789 51 FeO2- 0.41145E-09 -9.3857 0.34243E-09 -9.4654 0.83225E+00 -0.0797 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10870E-04 -4.9638 0.99620E+00 -0.0017 54 KCl,aq 0.20827E-08 -8.6814 0.20827E-08 -8.6814 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.74996E-14 -14.1250 0.62416E-14 -14.2047 0.83225E+00 -0.0797 58 MgCO3,aq 0.76235E-13 -13.1178 0.76235E-13 -13.1178 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.64491E-15 -15.1905 0.53780E-15 -15.2694 0.83391E+00 -0.0789 60 MgCl+ 0.17984E-13 -13.7451 0.14997E-13 -13.8240 0.83391E+00 -0.0789 61 MgOH+ 0.73510E-10 -10.1337 0.61301E-10 -10.2125 0.83391E+00 -0.0789 63 MnO,aq 0.18789E-08 -8.7261 0.18789E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.51069E-09 -9.2918 0.42587E-09 -9.3707 0.83391E+00 -0.0789 65 MnO2-2 0.21066E-10 -10.6764 0.10766E-10 -10.9679 0.51107E+00 -0.2915 66 HMnO2- 0.21774E-09 -9.6621 0.18122E-09 -9.7418 0.83225E+00 -0.0797 69 MnCl+ 0.66301E-13 -13.1785 0.55289E-13 -13.2574 0.83391E+00 -0.0789 71 NaCl,aq 0.48736E-05 -5.3121 0.48736E-05 -5.3121 0.10000E+01 0.0000 72 NaOH,aq 0.99274E-04 -4.0032 0.99274E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.92946E-02 -2.0318 0.77209E-02 -2.1123 0.83069E+00 -0.0806 79 HPO3-2 0.16070E-14 -14.7940 0.82130E-15 -15.0855 0.51107E+00 -0.2915 81 H2PO3- 0.15060E-18 -18.8222 0.12534E-18 -18.9019 0.83225E+00 -0.0797 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39112E-10 -10.4077 0.32583E-10 -10.4870 0.83307E+00 -0.0793 84 PO4-3 0.11414E-08 -8.9426 0.26891E-09 -9.5704 0.23561E+00 -0.6278 88 HP2O7-3 0.97866E-18 -18.0094 0.21931E-18 -18.6589 0.22409E+00 -0.6496 89 P2O7-4 0.95409E-17 -17.0204 0.69640E-18 -18.1571 0.72992E-01 -1.1367 90 H2S,aq 0.37005E-07 -7.4317 0.36865E-07 -7.4334 0.99620E+00 -0.0017 91 S2-2 0.98752E-13 -13.0055 0.50469E-13 -13.2970 0.51107E+00 -0.2915 97 SO3-2 0.83673E-17 -17.0774 0.43408E-17 -17.3624 0.51878E+00 -0.2850 98 HSO3- 0.23713E-19 -19.6250 0.19735E-19 -19.7048 0.83225E+00 -0.0797 99 HSO4- 0.25292E-18 -18.5970 0.21112E-18 -18.6755 0.83476E+00 -0.0784 Charge balance for all species = 0.5685E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9276243E-10 -.2265262E-01 -.2279051E+02 0.0000 2 H2O 0.1000000E+01 0.5550453E+02 0.9980923E+06 0.0000 3 Cl- 0.1021757E-02 0.1026632E-02 0.3633028E+02 7.0392 4 SO4-- 0.5718151E-11 -.9391833E-04 -.9005358E+01 8.6860 5 HCO3- 0.2059788E-05 0.9725069E-04 0.5923055E+01 4.3444 6 HS- 0.1897356E-03 0.2836909E-03 0.9364976E+01 6.3081 7 Al+++ 0.1207718E-28 0.5153392E-05 0.1387906E+00 0.7608 8 H4SiO4 0.7116653E-03 0.1394217E-01 0.1337594E+04 -3.1477 9 Ca++ 0.1517608E-06 0.2562976E-06 0.1025301E-01 13.1065 10 Mg++ 0.2410033E-10 0.1013579E-09 0.2459684E-05 9.3053 11 Fe++ 0.6592389E-13 0.3703844E-07 0.2064683E-02 6.7428 12 K+ 0.1659113E-03 0.1666895E-03 0.6505911E+01 6.2505 13 Na+ 0.2109404E-01 0.2368972E-01 0.5436205E+03 8.3540 14 Mn++ 0.2119466E-10 0.2649695E-08 0.1453013E-03 9.2504 15 HPO4-- 0.4669761E-07 0.4787808E-07 0.4586841E-02 12.5981 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1424032E+03 -.3044398E-02 -.1424002E+03 0.0000000E+00 2 H2O -.5229627E+02 0.7459527E+01 -.5975579E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2383608E+00 -.1262215E-04 0.2383734E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2383353E+00 0.3812662E-04 -.2383734E+00 0.0000000E+00 7 Al+++ 0.2804237E+02 0.6925897E-06 0.2804237E+02 0.0000000E+00 8 H4SiO4 0.8954992E+02 0.1873757E-02 0.8954805E+02 0.0000000E+00 9 Ca++ 0.9891240E+01 0.3444510E-07 0.9891240E+01 0.0000000E+00 10 Mg++ 0.6825396E+01 0.1362199E-10 0.6825396E+01 0.0000000E+00 11 Fe++ 0.6131873E+01 0.4977778E-08 0.6131873E+01 0.0000000E+00 12 K+ 0.1825902E+01 0.2240223E-04 0.1825880E+01 0.0000000E+00 13 Na+ 0.1079525E+02 0.3183778E-02 0.1079207E+02 0.0000000E+00 14 Mn++ 0.1491119E+00 0.3561056E-09 0.1491119E+00 0.0000000E+00 15 HPO4-- 0.5089115E-01 0.6434571E-08 0.5089115E-01 0.0000000E+00 Chg. balance for solid moles: -.3136E-14 Mass of aqueous solution: 0.134642E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8599.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.78 1.033 2828. 3.451 30.10 1086. andradite 0.9535 -0.021 484.5 2.685 5.157 125.9 grossular 0.2276 -0.643 102.5 2.011 1.091 28.53 apatite-OH 0.1696E-01 -1.770 8.521 0.931 0.9069E-01 2.708 clinochlore 1.224 0.088 680.6 2.833 7.244 258.9 daphnite 0.3509 -0.455 250.4 2.399 2.665 75.88 chlorite-Mn 0.2982E-01 -1.525 21.14 1.325 0.2250 6.738 diopside 0.4880 -0.312 105.7 2.024 1.125 32.30 hedenbergite 0.1250 -0.903 31.01 1.492 0.3301 8.495 microcline 1.599 0.204 445.0 2.648 4.736 173.8 stilbite 5.531 0.743 3898. 3.591 41.49 1818. stilpnomelane-Fe 0.4542 -0.343 489.6 2.690 5.211 169.1 tr.625ac.25prg.125 0.5937E-01 -1.226 50.75 1.705 0.5401 16.33 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9395.757907 g Volume = 3802.389097 cm3 Porosity: -10.5025% V(tot) - V(min): -.36139E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8599.9990000 g log = 3.9345 Original solution: 1000.0103000 g Original solution / Rock added: 0.12 (Water/Rock Ratio), log = -0.9345 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2110 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8704E+00 0.9836 0.1037E+01 0.1054E+01 CO2,gas 0.2528E-07 1.0056 0.3078E-07 0.3061E-07 CH4,gas 0.1173E+00 1.0114 0.1437E+00 0.1420E+00 H2,gas 0.1230E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.8921E-06 0.9953 0.1075E-05 0.1080E-05 S2,gas 0.1609E-27 1.0000 0.1948E-27 0.1948E-27 CO,gas 0.9817E-13 1.0000 0.1189E-12 0.1189E-12 SO3,gas 0.5457E-47 1.0000 0.6609E-47 0.6609E-47 SO2,gas 0.3078E-26 1.0000 0.3727E-26 0.3727E-26 HCl,gas 0.1812E-16 1.0000 0.2194E-16 0.2194E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.97059E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.48529E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.87 -9.51 -3.171 0.16241E+05 -7.512 3 CH4,gas 4.81 1.97 -2.84 -0.711 0.48538E+04 -0.843 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65338E+04 -1.827 5 H2S,gas -5.94 -13.91 -7.97 -3.984 0.13606E+05 -5.969 6 S2,gas -7.03 -36.74 -29.71 -4.571 0.50730E+05 -27.710 7 CO,gas 3.51 -11.41 -14.92 -4.592 0.25484E+05 -12.925 8 SO3,gas 17.43 -31.75 -49.18 -12.295 0.83973E+05 -47.180 9 SO2,gas 1.14 -27.29 -28.43 -7.581 0.48541E+05 -26.429 10 HCl,gas 5.48 -13.18 -18.66 -9.329 0.31859E+05 -16.659 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80596E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.77 -3.75 -1.252 0.64109E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.77 -3.60 -1.201 0.61495E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65548E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -6.95 -3.85 -1.099 0.65685E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -6.95 -3.41 -0.973 0.58146E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82258E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.54 -4.31 -1.015 0.73669E+04 143 pyrrhotite -4.24 -7.17 -2.92 -0.975 0.49940E+04 144 pyrrhotiteFe0.875 -6.00 -8.56 -2.56 -0.943 0.43767E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22425E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23218E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47123E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.17 -2.77 -0.925 0.47371E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60328E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.66 -3.70 -1.233 0.63149E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 8599.9990000 g New total amount of reactant added: 8649.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7632E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8649.9990000 Water: Moles liquid = 0.7181E+01 kg liquid = 0.1294E+00 Moles total = -.5292E+02 kg total = -.9534E+00 Activity = 1.0000 Stoichiometric ionic strength = .1250220E-01 Osmotic coef. = 0.9668 True ionic strength = .2129087E-01 Chg. balance for total moles = 0.7632E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92876E-10 -10.0321 0.77778E-10 -10.1091 0.83744E+00 -0.0770 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.10614E-02 -2.9741 0.88330E-03 -3.0539 0.83218E+00 -0.0798 4 SO4-- 0.59348E-11 -11.2266 0.30388E-11 -11.5173 0.51203E+00 -0.2907 5 HCO3- 0.21377E-05 -5.6701 0.17817E-05 -5.7492 0.83345E+00 -0.0791 6 HS- 0.19710E-03 -3.7053 0.16405E-03 -3.7850 0.83231E+00 -0.0797 7 Al+++ 0.12128E-28 -28.9162 0.27127E-29 -29.5666 0.22368E+00 -0.6504 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.15216E-06 -6.8177 0.77313E-07 -7.1117 0.50810E+00 -0.2940 10 Mg++ 0.24164E-10 -10.6168 0.12219E-10 -10.9130 0.50568E+00 -0.2961 11 Fe++ 0.66098E-13 -13.1798 0.33462E-13 -13.4754 0.50626E+00 -0.2956 12 K+ 0.16612E-03 -3.7796 0.13848E-03 -3.8586 0.83365E+00 -0.0790 13 Na+ 0.21120E-01 -1.6753 0.17572E-01 -1.7552 0.83202E+00 -0.0799 14 Mn++ 0.21251E-10 -10.6726 0.10768E-10 -10.9679 0.50669E+00 -0.2953 15 HPO4-- 0.46606E-07 -7.3316 0.23867E-07 -7.6222 0.51211E+00 -0.2906 16 HSiO3- 0.10728E-01 -1.9695 0.89273E-02 -2.0493 0.83218E+00 -0.0798 17 Ca(HSiO3)+ 0.18545E-07 -7.7318 0.15464E-07 -7.8107 0.83384E+00 -0.0789 18 Mg(HSiO3)+ 0.36478E-11 -11.4380 0.30417E-11 -11.5169 0.83384E+00 -0.0789 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.69426E-16 -16.1585 0.57890E-16 -16.2374 0.83384E+00 -0.0789 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51478E-05 -5.2884 0.42759E-05 -5.3690 0.83062E+00 -0.0806 24 CH4,aq 0.94741E-04 -4.0235 0.94381E-04 -4.0251 0.99619E+00 -0.0017 25 C2H6,aq 0.14187E-12 -12.8481 0.14133E-12 -12.8498 0.99619E+00 -0.0017 29 CO,aq 0.78218E-16 -16.1067 0.78218E-16 -16.1067 0.10000E+01 0.0000 30 CO2,aq 0.28046E-09 -9.5521 0.27939E-09 -9.5538 0.99619E+00 -0.0017 31 CO3-2 0.41456E-05 -5.3824 0.21180E-05 -5.6741 0.51090E+00 -0.2917 32 CaCO3,aq 0.20055E-08 -8.6978 0.20055E-08 -8.6978 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.41624E-11 -11.3807 0.34708E-11 -11.4596 0.83384E+00 -0.0789 34 CaCl+ 0.13050E-09 -9.8844 0.10882E-09 -9.9633 0.83384E+00 -0.0789 35 CaCl2,aq 0.22380E-13 -13.6501 0.22380E-13 -13.6501 0.10000E+01 0.0000 36 CaOH+ 0.84058E-07 -7.0754 0.70091E-07 -7.1543 0.83384E+00 -0.0789 37 CaSO4,aq 0.73202E-16 -16.1355 0.73202E-16 -16.1355 0.10000E+01 0.0000 38 HCl,aq 0.12923E-13 -13.8887 0.12923E-13 -13.8887 0.10000E+01 0.0000 43 FeCl+ 0.55209E-16 -16.2580 0.46036E-16 -16.3369 0.83384E+00 -0.0789 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.17105E-10 -10.7669 0.14263E-10 -10.8458 0.83384E+00 -0.0789 48 HFeO2- 0.36349E-07 -7.4395 0.30249E-07 -7.5193 0.83218E+00 -0.0798 49 FeO+ 0.12626E-16 -16.8987 0.10528E-16 -16.9777 0.83384E+00 -0.0789 51 FeO2- 0.41101E-09 -9.3861 0.34204E-09 -9.4659 0.83218E+00 -0.0798 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10870E-04 -4.9638 0.99619E+00 -0.0017 54 KCl,aq 0.21659E-08 -8.6644 0.21659E-08 -8.6644 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.77908E-14 -14.1084 0.64834E-14 -14.1882 0.83218E+00 -0.0798 58 MgCO3,aq 0.79203E-13 -13.1013 0.79203E-13 -13.1013 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.67084E-15 -15.1734 0.55937E-15 -15.2523 0.83384E+00 -0.0789 60 MgCl+ 0.18725E-13 -13.7276 0.15613E-13 -13.8065 0.83384E+00 -0.0789 61 MgOH+ 0.73600E-10 -10.1331 0.61371E-10 -10.2120 0.83384E+00 -0.0789 63 MnO,aq 0.18789E-08 -8.7261 0.18789E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.51132E-09 -9.2913 0.42636E-09 -9.3702 0.83384E+00 -0.0789 65 MnO2-2 0.21025E-10 -10.6773 0.10742E-10 -10.9689 0.51090E+00 -0.2917 66 HMnO2- 0.21751E-09 -9.6625 0.18101E-09 -9.7423 0.83218E+00 -0.0798 69 MnCl+ 0.69033E-13 -13.1609 0.57563E-13 -13.2399 0.83384E+00 -0.0789 71 NaCl,aq 0.50682E-05 -5.2951 0.50682E-05 -5.2951 0.10000E+01 0.0000 72 NaOH,aq 0.99274E-04 -4.0032 0.99274E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.92847E-02 -2.0322 0.77121E-02 -2.1128 0.83062E+00 -0.0806 79 HPO3-2 0.16039E-14 -14.7948 0.81942E-15 -15.0865 0.51090E+00 -0.2917 81 H2PO3- 0.15044E-18 -18.8226 0.12519E-18 -18.9024 0.83218E+00 -0.0798 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39070E-10 -10.4082 0.32546E-10 -10.4875 0.83300E+00 -0.0794 84 PO4-3 0.11382E-08 -8.9438 0.26799E-09 -9.5719 0.23544E+00 -0.6281 88 HP2O7-3 0.97603E-18 -18.0105 0.21856E-18 -18.6604 0.22392E+00 -0.6499 89 P2O7-4 0.95097E-17 -17.0218 0.69322E-18 -18.1591 0.72896E-01 -1.1373 90 H2S,aq 0.38483E-07 -7.4147 0.38337E-07 -7.4164 0.99619E+00 -0.0017 91 S2-2 0.10659E-12 -12.9723 0.54455E-13 -13.2640 0.51090E+00 -0.2917 97 SO3-2 0.86843E-17 -17.0613 0.45038E-17 -17.3464 0.51861E+00 -0.2852 98 HSO3- 0.24634E-19 -19.6085 0.20500E-19 -19.6883 0.83218E+00 -0.0798 99 HSO4- 0.26274E-18 -18.5805 0.21930E-18 -18.6590 0.83469E+00 -0.0785 Charge balance for all species = 0.5895E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9287603E-10 -.2263151E-01 -.2276924E+02 0.0000 2 H2O 0.1000000E+01 0.5550453E+02 0.9980911E+06 0.0000 3 Cl- 0.1061425E-02 0.1066495E-02 0.3774089E+02 7.0553 4 SO4-- 0.5934827E-11 -.9746900E-04 -.9345802E+01 8.7010 5 HCO3- 0.2137695E-05 0.1010268E-03 0.6153033E+01 4.3600 6 HS- 0.1971027E-03 0.2946102E-03 0.9725423E+01 6.3241 7 Al+++ 0.1212787E-28 0.5147934E-05 0.1386434E+00 0.7608 8 H4SiO4 0.7116652E-03 0.1393078E-01 0.1336499E+04 -3.1477 9 Ca++ 0.1521600E-06 0.2569032E-06 0.1027722E-01 13.1065 10 Mg++ 0.2416384E-10 0.1015176E-09 0.2463556E-05 9.3053 11 Fe++ 0.6609754E-13 0.3699943E-07 0.2062505E-02 6.7428 12 K+ 0.1661152E-03 0.1668935E-03 0.6513864E+01 6.2505 13 Na+ 0.2112000E-01 0.2371587E-01 0.5442201E+03 8.3540 14 Mn++ 0.2125061E-10 0.2650125E-08 0.1453247E-03 9.2504 15 HPO4-- 0.4660602E-07 0.4778332E-07 0.4577758E-02 12.5961 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1432311E+03 -.2927875E-02 -.1432282E+03 0.0000000E+00 2 H2O -.5292304E+02 0.7180709E+01 -.6010375E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2397465E+00 -.1260972E-04 0.2397591E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2397210E+00 0.3811419E-04 -.2397591E+00 0.0000000E+00 7 Al+++ 0.2820541E+02 0.6659963E-06 0.2820541E+02 0.0000000E+00 8 H4SiO4 0.9007056E+02 0.1802247E-02 0.9006876E+02 0.0000000E+00 9 Ca++ 0.9948747E+01 0.3323597E-07 0.9948747E+01 0.0000000E+00 10 Mg++ 0.6865079E+01 0.1313349E-10 0.6865079E+01 0.0000000E+00 11 Fe++ 0.6167524E+01 0.4786674E-08 0.6167524E+01 0.0000000E+00 12 K+ 0.1836518E+01 0.2159128E-04 0.1836496E+01 0.0000000E+00 13 Na+ 0.1085802E+02 0.3068160E-02 0.1085495E+02 0.0000000E+00 14 Mn++ 0.1499788E+00 0.3428509E-09 0.1499788E+00 0.0000000E+00 15 HPO4-- 0.5118703E-01 0.6181804E-08 0.5118703E-01 0.0000000E+00 Chg. balance for solid moles: -.6717E-14 Mass of aqueous solution: 0.129610E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8649.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.85 1.035 2844. 3.454 30.10 1092. andradite 0.9590 -0.018 487.4 2.688 5.157 126.6 grossular 0.2290 -0.640 103.1 2.013 1.091 28.70 apatite-OH 0.1706E-01 -1.768 8.571 0.933 0.9069E-01 2.723 clinochlore 1.232 0.090 684.5 2.835 7.243 260.4 daphnite 0.3530 -0.452 251.8 2.401 2.665 76.32 chlorite-Mn 0.3000E-01 -1.523 21.27 1.328 0.2250 6.777 diopside 0.4908 -0.309 106.3 2.027 1.125 32.49 hedenbergite 0.1258 -0.900 31.20 1.494 0.3301 8.545 microcline 1.608 0.206 447.6 2.651 4.736 174.8 stilbite 5.563 0.745 3921. 3.593 41.49 1829. stilpnomelane-Fe 0.4568 -0.340 492.5 2.692 5.211 170.1 tr.625ac.25prg.125 0.5971E-01 -1.224 51.04 1.708 0.5401 16.43 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9450.385643 g Volume = 3824.492273 cm3 Porosity: -10.5025% V(tot) - V(min): -.36349E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8649.9990000 g log = 3.9370 Original solution: 1000.0103000 g Original solution / Rock added: 0.12 (Water/Rock Ratio), log = -0.9370 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2166 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8664E+00 0.9835 0.1037E+01 0.1054E+01 CO2,gas 0.2614E-07 1.0055 0.3198E-07 0.3181E-07 CH4,gas 0.1213E+00 1.0113 0.1493E+00 0.1476E+00 H2,gas 0.1225E-01 1.0006 0.1491E-01 0.1490E-01 H2S,gas 0.9234E-06 0.9953 0.1118E-05 0.1123E-05 S2,gas 0.1732E-27 1.0000 0.2107E-27 0.2107E-27 CO,gas 0.1015E-12 1.0000 0.1235E-12 0.1235E-12 SO3,gas 0.5649E-47 1.0000 0.6873E-47 0.6873E-47 SO2,gas 0.3186E-26 1.0000 0.3876E-26 0.3876E-26 HCl,gas 0.1876E-16 1.0000 0.2282E-16 0.2282E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.36397E-10 47 daphnite 29.09 29.09 0.00 0.000 0.42463E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.00000E+00 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.37914E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.97059E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.86 -9.50 -3.165 0.16213E+05 -7.495 3 CH4,gas 4.81 1.98 -2.83 -0.707 0.48255E+04 -0.826 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65338E+04 -1.827 5 H2S,gas -5.94 -13.89 -7.95 -3.976 0.13577E+05 -5.952 6 S2,gas -7.03 -36.71 -29.68 -4.566 0.50672E+05 -27.676 7 CO,gas 3.51 -11.40 -14.91 -4.587 0.25456E+05 -12.908 8 SO3,gas 17.43 -31.74 -49.16 -12.291 0.83944E+05 -47.163 9 SO2,gas 1.14 -27.28 -28.41 -7.576 0.48512E+05 -26.412 10 HCl,gas 5.48 -13.16 -18.64 -9.321 0.31830E+05 -16.642 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80596E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.75 -3.74 -1.246 0.63825E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.75 -3.58 -1.195 0.61212E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65548E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -6.94 -3.83 -1.094 0.65401E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -6.94 -3.39 -0.968 0.57863E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82258E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.51 -4.28 -1.007 0.73088E+04 143 pyrrhotite -4.24 -7.15 -2.91 -0.969 0.49649E+04 144 pyrrhotiteFe0.875 -6.00 -8.55 -2.55 -0.936 0.43477E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22425E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23218E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47123E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.15 -2.76 -0.919 0.47081E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60328E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.64 -3.68 -1.227 0.62858E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 8649.9990000 g New total amount of reactant added: 8699.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7634E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8699.9990000 Water: Moles liquid = 0.6902E+01 kg liquid = 0.1243E+00 Moles total = -.5355E+02 kg total = -.9647E+00 Activity = 1.0000 Stoichiometric ionic strength = .1253825E-01 Osmotic coef. = 0.9668 True ionic strength = .2131935E-01 Chg. balance for total moles = 0.7634E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.92999E-10 -10.0315 0.77875E-10 -10.1086 0.83737E+00 -0.0771 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.11043E-02 -2.9569 0.91889E-03 -3.0367 0.83211E+00 -0.0798 4 SO4-- 0.61686E-11 -11.2098 0.31574E-11 -11.5007 0.51185E+00 -0.2909 5 HCO3- 0.22217E-05 -5.6533 0.18515E-05 -5.7325 0.83338E+00 -0.0792 6 HS- 0.20507E-03 -3.6881 0.17066E-03 -3.7679 0.83223E+00 -0.0798 7 Al+++ 0.12183E-28 -28.9142 0.27228E-29 -29.5650 0.22350E+00 -0.6507 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.15259E-06 -6.8165 0.77504E-07 -7.1107 0.50792E+00 -0.2942 10 Mg++ 0.24233E-10 -10.6156 0.12249E-10 -10.9119 0.50549E+00 -0.2963 11 Fe++ 0.66286E-13 -13.1786 0.33545E-13 -13.4744 0.50607E+00 -0.2958 12 K+ 0.16634E-03 -3.7790 0.13865E-03 -3.8581 0.83358E+00 -0.0791 13 Na+ 0.21148E-01 -1.6747 0.17594E-01 -1.7546 0.83195E+00 -0.0799 14 Mn++ 0.21311E-10 -10.6714 0.10794E-10 -10.9668 0.50651E+00 -0.2954 15 HPO4-- 0.46507E-07 -7.3325 0.23808E-07 -7.6233 0.51193E+00 -0.2908 16 HSiO3- 0.10715E-01 -1.9700 0.89163E-02 -2.0498 0.83211E+00 -0.0798 17 Ca(HSiO3)+ 0.18570E-07 -7.7312 0.15483E-07 -7.8101 0.83377E+00 -0.0790 18 Mg(HSiO3)+ 0.36526E-11 -11.4374 0.30454E-11 -11.5164 0.83377E+00 -0.0790 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.69518E-16 -16.1579 0.57962E-16 -16.2369 0.83377E+00 -0.0790 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51419E-05 -5.2889 0.42706E-05 -5.3695 0.83055E+00 -0.0806 24 CH4,aq 0.98580E-04 -4.0062 0.98203E-04 -4.0079 0.99618E+00 -0.0017 25 C2H6,aq 0.15359E-12 -12.8136 0.15301E-12 -12.8153 0.99618E+00 -0.0017 29 CO,aq 0.81386E-16 -16.0895 0.81386E-16 -16.0895 0.10000E+01 0.0000 30 CO2,aq 0.29183E-09 -9.5349 0.29071E-09 -9.5365 0.99618E+00 -0.0017 31 CO3-2 0.43044E-05 -5.3661 0.21983E-05 -5.6579 0.51071E+00 -0.2918 32 CaCO3,aq 0.20867E-08 -8.6805 0.20867E-08 -8.6805 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.43367E-11 -11.3628 0.36158E-11 -11.4418 0.83377E+00 -0.0790 34 CaCl+ 0.13611E-09 -9.8661 0.11349E-09 -9.9451 0.83377E+00 -0.0790 35 CaCl2,aq 0.24281E-13 -13.6147 0.24281E-13 -13.6147 0.10000E+01 0.0000 36 CaOH+ 0.84169E-07 -7.0748 0.70178E-07 -7.1538 0.83377E+00 -0.0790 37 CaSO4,aq 0.76246E-16 -16.1178 0.76246E-16 -16.1178 0.10000E+01 0.0000 38 HCl,aq 0.13460E-13 -13.8710 0.13460E-13 -13.8710 0.10000E+01 0.0000 43 FeCl+ 0.57581E-16 -16.2397 0.48009E-16 -16.3187 0.83377E+00 -0.0790 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.17128E-10 -10.7663 0.14281E-10 -10.8453 0.83377E+00 -0.0790 48 HFeO2- 0.36308E-07 -7.4400 0.30212E-07 -7.5198 0.83211E+00 -0.0798 49 FeO+ 0.12642E-16 -16.8982 0.10541E-16 -16.9771 0.83377E+00 -0.0790 51 FeO2- 0.41054E-09 -9.3866 0.34161E-09 -9.4665 0.83211E+00 -0.0798 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10870E-04 -4.9638 0.99618E+00 -0.0017 54 KCl,aq 0.22560E-08 -8.6467 0.22560E-08 -8.6467 0.10000E+01 0.0000 56 KOH,aq 0.77620E-06 -6.1100 0.77620E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.81055E-14 -14.0912 0.67447E-14 -14.1710 0.83211E+00 -0.0798 58 MgCO3,aq 0.82411E-13 -13.0840 0.82411E-13 -13.0840 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.69894E-15 -15.1556 0.58275E-15 -15.2345 0.83377E+00 -0.0790 60 MgCl+ 0.19529E-13 -13.7093 0.16283E-13 -13.7883 0.83377E+00 -0.0790 61 MgOH+ 0.73698E-10 -10.1325 0.61447E-10 -10.2115 0.83377E+00 -0.0790 63 MnO,aq 0.18790E-08 -8.7261 0.18790E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.51200E-09 -9.2907 0.42689E-09 -9.3697 0.83377E+00 -0.0790 65 MnO2-2 0.20981E-10 -10.6782 0.10715E-10 -10.9700 0.51071E+00 -0.2918 66 HMnO2- 0.21727E-09 -9.6630 0.18079E-09 -9.7428 0.83211E+00 -0.0798 69 MnCl+ 0.72000E-13 -13.1427 0.60031E-13 -13.2216 0.83377E+00 -0.0790 71 NaCl,aq 0.52790E-05 -5.2775 0.52790E-05 -5.2775 0.10000E+01 0.0000 72 NaOH,aq 0.99274E-04 -4.0032 0.99274E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.92741E-02 -2.0327 0.77026E-02 -2.1134 0.83055E+00 -0.0806 79 HPO3-2 0.16005E-14 -14.7957 0.81740E-15 -15.0876 0.51071E+00 -0.2918 81 H2PO3- 0.15027E-18 -18.8231 0.12504E-18 -18.9030 0.83211E+00 -0.0798 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.39025E-10 -10.4087 0.32505E-10 -10.4880 0.83293E+00 -0.0794 84 PO4-3 0.11349E-08 -8.9451 0.26699E-09 -9.5735 0.23526E+00 -0.6284 88 HP2O7-3 0.97320E-18 -18.0118 0.21775E-18 -18.6620 0.22374E+00 -0.6503 89 P2O7-4 0.94761E-17 -17.0234 0.68980E-18 -18.1613 0.72793E-01 -1.1379 90 H2S,aq 0.40084E-07 -7.3970 0.39931E-07 -7.3987 0.99618E+00 -0.0017 91 S2-2 0.11539E-12 -12.9378 0.58932E-13 -13.2296 0.51071E+00 -0.2918 97 SO3-2 0.90262E-17 -17.0445 0.46795E-17 -17.3298 0.51843E+00 -0.2853 98 HSO3- 0.25629E-19 -19.5913 0.21326E-19 -19.6711 0.83211E+00 -0.0798 99 HSO4- 0.27335E-18 -18.5633 0.22814E-18 -18.6418 0.83462E+00 -0.0785 Charge balance for all species = 0.6135E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9299895E-10 -.2260873E-01 -.2274628E+02 0.0000 2 H2O 0.1000000E+01 0.5550454E+02 0.9980898E+06 0.0000 3 Cl- 0.1104298E-02 0.1109579E-02 0.3926548E+02 7.0719 4 SO4-- 0.6168567E-11 -.1013074E-03 -.9713828E+01 8.7165 5 HCO3- 0.2221725E-05 0.1051081E-03 0.6401591E+01 4.3761 6 HS- 0.2050651E-03 0.3064126E-03 0.1011502E+02 6.3407 7 Al+++ 0.1218289E-28 0.5142043E-05 0.1384846E+00 0.7608 8 H4SiO4 0.7116652E-03 0.1391848E-01 0.1335317E+04 -3.1477 9 Ca++ 0.1525925E-06 0.2575590E-06 0.1030344E-01 13.1065 10 Mg++ 0.2423265E-10 0.1016902E-09 0.2467740E-05 9.3053 11 Fe++ 0.6628569E-13 0.3695730E-07 0.2060154E-02 6.7428 12 K+ 0.1663357E-03 0.1671142E-03 0.6522468E+01 6.2505 13 Na+ 0.2114809E-01 0.2374417E-01 0.5448687E+03 8.3540 14 Mn++ 0.2131121E-10 0.2650591E-08 0.1453500E-03 9.2504 15 HPO4-- 0.4650726E-07 0.4768116E-07 0.4567964E-02 12.5939 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1440591E+03 -.2811355E-02 -.1440562E+03 0.0000000E+00 2 H2O -.5354981E+02 0.6901891E+01 -.6045170E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2411321E+00 -.1259739E-04 0.2411447E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2411066E+00 0.3810186E-04 -.2411447E+00 0.0000000E+00 7 Al+++ 0.2836845E+02 0.6394039E-06 0.2836845E+02 0.0000000E+00 8 H4SiO4 0.9059120E+02 0.1730739E-02 0.9058947E+02 0.0000000E+00 9 Ca++ 0.1000625E+02 0.3202700E-07 0.1000625E+02 0.0000000E+00 10 Mg++ 0.6904761E+01 0.1264500E-10 0.6904761E+01 0.0000000E+00 11 Fe++ 0.6203174E+01 0.4595575E-08 0.6203174E+01 0.0000000E+00 12 K+ 0.1847134E+01 0.2078035E-04 0.1847113E+01 0.0000000E+00 13 Na+ 0.1092078E+02 0.2952546E-02 0.1091783E+02 0.0000000E+00 14 Mn++ 0.1508458E+00 0.3295962E-09 0.1508458E+00 0.0000000E+00 15 HPO4-- 0.5148291E-01 0.5929068E-08 0.5148290E-01 0.0000000E+00 Chg. balance for solid moles: -.3686E-13 Mass of aqueous solution: 0.124578E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8699.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.91 1.038 2861. 3.457 30.10 1098. andradite 0.9646 -0.016 490.2 2.690 5.157 127.4 grossular 0.2303 -0.638 103.7 2.016 1.091 28.86 apatite-OH 0.1716E-01 -1.765 8.620 0.936 0.9069E-01 2.739 clinochlore 1.239 0.093 688.5 2.838 7.243 261.9 daphnite 0.3550 -0.450 253.3 2.404 2.665 76.76 chlorite-Mn 0.3017E-01 -1.520 21.39 1.330 0.2250 6.816 diopside 0.4937 -0.307 106.9 2.029 1.125 32.68 hedenbergite 0.1265 -0.898 31.38 1.497 0.3302 8.596 microcline 1.617 0.209 450.2 2.653 4.736 175.9 stilbite 5.596 0.748 3943. 3.596 41.49 1839. stilpnomelane-Fe 0.4595 -0.338 495.3 2.695 5.211 171.1 tr.625ac.25prg.125 0.6005E-01 -1.221 51.33 1.710 0.5401 16.52 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9505.013380 g Volume = 3846.595449 cm3 Porosity: -10.5026% V(tot) - V(min): -.36560E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8699.9990000 g log = 3.9395 Original solution: 1000.0103000 g Original solution / Rock added: 0.11 (Water/Rock Ratio), log = -0.9395 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2226 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8622E+00 0.9834 0.1037E+01 0.1054E+01 CO2,gas 0.2707E-07 1.0054 0.3328E-07 0.3310E-07 CH4,gas 0.1256E+00 1.0112 0.1553E+00 0.1536E+00 H2,gas 0.1219E-01 1.0007 0.1491E-01 0.1490E-01 H2S,gas 0.9571E-06 0.9953 0.1165E-05 0.1170E-05 S2,gas 0.1869E-27 1.0000 0.2286E-27 0.2286E-27 CO,gas 0.1051E-12 1.0000 0.1285E-12 0.1285E-12 SO3,gas 0.5855E-47 1.0000 0.7158E-47 0.7158E-47 SO2,gas 0.3302E-26 1.0000 0.4037E-26 0.4037E-26 HCl,gas 0.1944E-16 1.0000 0.2377E-16 0.2377E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.12132E-10 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.18198E-10 46 clinochlore 39.19 39.19 0.00 0.000 0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 0.00000E+00 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.84 -9.48 -3.159 0.16183E+05 -7.478 3 CH4,gas 4.81 2.00 -2.81 -0.702 0.47960E+04 -0.809 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65338E+04 -1.827 5 H2S,gas -5.94 -13.88 -7.93 -3.967 0.13547E+05 -5.934 6 S2,gas -7.03 -36.67 -29.64 -4.560 0.50611E+05 -27.641 7 CO,gas 3.51 -11.38 -14.89 -4.582 0.25426E+05 -12.891 8 SO3,gas 17.43 -31.72 -49.15 -12.286 0.83914E+05 -47.145 9 SO2,gas 1.14 -27.26 -28.39 -7.572 0.48482E+05 -26.394 10 HCl,gas 5.48 -13.15 -18.62 -9.312 0.31800E+05 -16.624 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80596E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.73 -3.72 -1.240 0.63531E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.73 -3.57 -1.189 0.60918E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65547E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -6.92 -3.81 -1.089 0.65107E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -6.92 -3.37 -0.963 0.57569E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82258E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.47 -4.25 -0.999 0.72484E+04 143 pyrrhotite -4.24 -7.13 -2.89 -0.963 0.49347E+04 144 pyrrhotiteFe0.875 -6.00 -8.53 -2.53 -0.930 0.43175E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22425E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23217E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47123E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.13 -2.74 -0.913 0.46779E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60328E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.63 -3.66 -1.221 0.62556E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 8699.9990000 g New total amount of reactant added: 8749.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7631E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8749.9990000 Water: Moles liquid = 0.6624E+01 kg liquid = 0.1193E+00 Moles total = -.5418E+02 kg total = -.9760E+00 Activity = 1.0000 Stoichiometric ionic strength = .1257734E-01 Osmotic coef. = 0.9667 True ionic strength = .2135025E-01 Chg. balance for total moles = 0.7631E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93132E-10 -10.0309 0.77979E-10 -10.1080 0.83729E+00 -0.0771 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.11508E-02 -2.9390 0.95748E-03 -3.0189 0.83203E+00 -0.0799 4 SO4-- 0.64215E-11 -11.1924 0.32856E-11 -11.4834 0.51165E+00 -0.2910 5 HCO3- 0.23126E-05 -5.6359 0.19271E-05 -5.7151 0.83330E+00 -0.0792 6 HS- 0.21370E-03 -3.6702 0.17783E-03 -3.7500 0.83215E+00 -0.0798 7 Al+++ 0.12243E-28 -28.9121 0.27338E-29 -29.5632 0.22330E+00 -0.6511 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.15306E-06 -6.8151 0.77713E-07 -7.1095 0.50772E+00 -0.2944 10 Mg++ 0.24307E-10 -10.6143 0.12282E-10 -10.9107 0.50529E+00 -0.2965 11 Fe++ 0.66490E-13 -13.1772 0.33635E-13 -13.4732 0.50587E+00 -0.2960 12 K+ 0.16658E-03 -3.7784 0.13884E-03 -3.8575 0.83350E+00 -0.0791 13 Na+ 0.21179E-01 -1.6741 0.17618E-01 -1.7541 0.83186E+00 -0.0799 14 Mn++ 0.21377E-10 -10.6701 0.10823E-10 -10.9656 0.50631E+00 -0.2956 15 HPO4-- 0.46400E-07 -7.3335 0.23744E-07 -7.6244 0.51173E+00 -0.2910 16 HSiO3- 0.10702E-01 -1.9705 0.89043E-02 -2.0504 0.83203E+00 -0.0799 17 Ca(HSiO3)+ 0.18597E-07 -7.7306 0.15504E-07 -7.8096 0.83369E+00 -0.0790 18 Mg(HSiO3)+ 0.36579E-11 -11.4368 0.30495E-11 -11.5158 0.83369E+00 -0.0790 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.69618E-16 -16.1573 0.58040E-16 -16.2363 0.83369E+00 -0.0790 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51355E-05 -5.2894 0.42649E-05 -5.3701 0.83046E+00 -0.0807 24 CH4,aq 0.10274E-03 -3.9883 0.10235E-03 -3.9899 0.99617E+00 -0.0017 25 C2H6,aq 0.16684E-12 -12.7777 0.16620E-12 -12.7794 0.99617E+00 -0.0017 29 CO,aq 0.84821E-16 -16.0715 0.84821E-16 -16.0715 0.10000E+01 0.0000 30 CO2,aq 0.30415E-09 -9.5169 0.30298E-09 -9.5186 0.99617E+00 -0.0017 31 CO3-2 0.44758E-05 -5.3491 0.22850E-05 -5.6411 0.51052E+00 -0.2920 32 CaCO3,aq 0.21748E-08 -8.6626 0.21748E-08 -8.6626 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.45263E-11 -11.3443 0.37735E-11 -11.4233 0.83369E+00 -0.0790 34 CaCl+ 0.14222E-09 -9.8470 0.11857E-09 -9.9260 0.83369E+00 -0.0790 35 CaCl2,aq 0.26433E-13 -13.5778 0.26433E-13 -13.5778 0.10000E+01 0.0000 36 CaOH+ 0.84290E-07 -7.0742 0.70272E-07 -7.1532 0.83369E+00 -0.0790 37 CaSO4,aq 0.79555E-16 -16.0993 0.79555E-16 -16.0993 0.10000E+01 0.0000 38 HCl,aq 0.14044E-13 -13.8525 0.14044E-13 -13.8525 0.10000E+01 0.0000 43 FeCl+ 0.60166E-16 -16.2206 0.50160E-16 -16.2996 0.83369E+00 -0.0790 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.17153E-10 -10.7657 0.14300E-10 -10.8447 0.83369E+00 -0.0790 48 HFeO2- 0.36262E-07 -7.4405 0.30171E-07 -7.5204 0.83203E+00 -0.0799 49 FeO+ 0.12661E-16 -16.8975 0.10555E-16 -16.9765 0.83369E+00 -0.0790 51 FeO2- 0.41003E-09 -9.3872 0.34115E-09 -9.4670 0.83203E+00 -0.0799 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10911E-04 -4.9621 0.10870E-04 -4.9638 0.99617E+00 -0.0017 54 KCl,aq 0.23538E-08 -8.6282 0.23538E-08 -8.6282 0.10000E+01 0.0000 56 KOH,aq 0.77619E-06 -6.1100 0.77619E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.84468E-14 -14.0733 0.70279E-14 -14.1532 0.83203E+00 -0.0799 58 MgCO3,aq 0.85890E-13 -13.0661 0.85890E-13 -13.0661 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.72949E-15 -15.1370 0.60816E-15 -15.2160 0.83369E+00 -0.0790 60 MgCl+ 0.20406E-13 -13.6902 0.17012E-13 -13.7692 0.83369E+00 -0.0790 61 MgOH+ 0.73804E-10 -10.1319 0.61530E-10 -10.2109 0.83369E+00 -0.0790 63 MnO,aq 0.18790E-08 -8.7261 0.18790E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.51274E-09 -9.2901 0.42746E-09 -9.3691 0.83369E+00 -0.0790 65 MnO2-2 0.20933E-10 -10.6792 0.10686E-10 -10.9712 0.51052E+00 -0.2920 66 HMnO2- 0.21700E-09 -9.6635 0.18055E-09 -9.7434 0.83203E+00 -0.0799 69 MnCl+ 0.75232E-13 -13.1236 0.62720E-13 -13.2026 0.83369E+00 -0.0790 70 MnSO4,aq 0.10078E-19 -19.9966 0.10078E-19 -19.9966 0.10000E+01 0.0000 71 NaCl,aq 0.55080E-05 -5.2590 0.55080E-05 -5.2590 0.10000E+01 0.0000 72 NaOH,aq 0.99274E-04 -4.0032 0.99274E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.92626E-02 -2.0333 0.76922E-02 -2.1139 0.83046E+00 -0.0807 79 HPO3-2 0.15968E-14 -14.7967 0.81521E-15 -15.0887 0.51052E+00 -0.2920 81 H2PO3- 0.15008E-18 -18.8237 0.12487E-18 -18.9035 0.83203E+00 -0.0799 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.38977E-10 -10.4092 0.32462E-10 -10.4886 0.83285E+00 -0.0794 84 PO4-3 0.11312E-08 -8.9464 0.26592E-09 -9.5752 0.23507E+00 -0.6288 88 HP2O7-3 0.97015E-18 -18.0132 0.21687E-18 -18.6638 0.22354E+00 -0.6506 89 P2O7-4 0.94398E-17 -17.0250 0.68610E-18 -18.1636 0.72682E-01 -1.1386 90 H2S,aq 0.41824E-07 -7.3786 0.41664E-07 -7.3802 0.99617E+00 -0.0017 91 S2-2 0.12534E-12 -12.9019 0.63986E-13 -13.1939 0.51052E+00 -0.2920 97 SO3-2 0.93961E-17 -17.0271 0.48695E-17 -17.3125 0.51824E+00 -0.2855 98 HSO3- 0.26708E-19 -19.5734 0.22222E-19 -19.6532 0.83203E+00 -0.0799 99 HSO4- 0.28486E-18 -18.5454 0.23772E-18 -18.6239 0.83454E+00 -0.0786 Charge balance for all species = 0.6387E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9313236E-10 -.2258406E-01 -.2272143E+02 0.0000 2 H2O 0.1000000E+01 0.5550454E+02 0.9980884E+06 0.0000 3 Cl- 0.1150780E-02 0.1156290E-02 0.4091842E+02 7.0892 4 SO4-- 0.6421469E-11 -.1054698E-03 -.1011293E+02 8.7327 5 HCO3- 0.2312629E-05 0.1095329E-03 0.6671076E+01 4.3929 6 HS- 0.2136979E-03 0.3192096E-03 0.1053745E+02 6.3580 7 Al+++ 0.1224281E-28 0.5135666E-05 0.1383126E+00 0.7608 8 H4SiO4 0.7116652E-03 0.1390517E-01 0.1334038E+04 -3.1477 9 Ca++ 0.1530628E-06 0.2582716E-06 0.1033193E-01 13.1065 10 Mg++ 0.2430746E-10 0.1018848E-09 0.2472458E-05 9.3053 11 Fe++ 0.6649025E-13 0.3691172E-07 0.2057610E-02 6.7428 12 K+ 0.1665752E-03 0.1673537E-03 0.6531807E+01 6.2505 13 Na+ 0.2117858E-01 0.2377489E-01 0.5455728E+03 8.3540 14 Mn++ 0.2137709E-10 0.2651095E-08 0.1453774E-03 9.2504 15 HPO4-- 0.4640045E-07 0.4757068E-07 0.4557373E-02 12.5916 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1448870E+03 -.2694840E-02 -.1448843E+03 0.0000000E+00 2 H2O -.5417658E+02 0.6623072E+01 -.6079965E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2425178E+00 -.1258517E-04 0.2425304E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2424923E+00 0.3808964E-04 -.2425304E+00 0.0000000E+00 7 Al+++ 0.2853149E+02 0.6128127E-06 0.2853149E+02 0.0000000E+00 8 H4SiO4 0.9111184E+02 0.1659233E-02 0.9111018E+02 0.0000000E+00 9 Ca++ 0.1006376E+02 0.3081822E-07 0.1006376E+02 0.0000000E+00 10 Mg++ 0.6944444E+01 0.1215739E-10 0.6944444E+01 0.0000000E+00 11 Fe++ 0.6238824E+01 0.4404486E-08 0.6238824E+01 0.0000000E+00 12 K+ 0.1857749E+01 0.1996946E-04 0.1857729E+01 0.0000000E+00 13 Na+ 0.1098354E+02 0.2836936E-02 0.1098070E+02 0.0000000E+00 14 Mn++ 0.1517127E+00 0.3163415E-09 0.1517127E+00 0.0000000E+00 15 HPO4-- 0.5177879E-01 0.5676365E-08 0.5177878E-01 0.0000000E+00 Chg. balance for solid moles: 0.1016E-13 Mass of aqueous solution: 0.119545E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8749.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 10.97 1.040 2877. 3.459 30.10 1105. andradite 0.9701 -0.013 493.0 2.693 5.157 128.1 grossular 0.2316 -0.635 104.3 2.018 1.091 29.03 apatite-OH 0.1726E-01 -1.763 8.670 0.938 0.9069E-01 2.755 clinochlore 1.246 0.095 692.4 2.840 7.243 263.4 daphnite 0.3570 -0.447 254.8 2.406 2.665 77.20 chlorite-Mn 0.3034E-01 -1.518 21.51 1.333 0.2250 6.855 diopside 0.4966 -0.304 107.5 2.032 1.125 32.87 hedenbergite 0.1272 -0.895 31.57 1.499 0.3302 8.646 microcline 1.627 0.211 452.8 2.656 4.736 176.9 stilbite 5.628 0.750 3966. 3.598 41.49 1850. stilpnomelane-Fe 0.4621 -0.335 498.2 2.697 5.211 172.1 tr.625ac.25prg.125 0.6040E-01 -1.219 51.62 1.713 0.5400 16.62 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9559.641116 g Volume = 3868.698625 cm3 Porosity: -10.5027% V(tot) - V(min): -.36770E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8749.9990000 g log = 3.9420 Original solution: 1000.0103000 g Original solution / Rock added: 0.11 (Water/Rock Ratio), log = -0.9420 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2292 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8577E+00 0.9834 0.1037E+01 0.1054E+01 CO2,gas 0.2806E-07 1.0053 0.3468E-07 0.3450E-07 CH4,gas 0.1302E+00 1.0112 0.1619E+00 0.1601E+00 H2,gas 0.1212E-01 1.0007 0.1491E-01 0.1490E-01 H2S,gas 0.9933E-06 0.9952 0.1215E-05 0.1221E-05 S2,gas 0.2024E-27 1.0000 0.2488E-27 0.2488E-27 CO,gas 0.1090E-12 1.0000 0.1339E-12 0.1339E-12 SO3,gas 0.6076E-47 1.0000 0.7469E-47 0.7469E-47 SO2,gas 0.3427E-26 1.0000 0.4213E-26 0.4213E-26 HCl,gas 0.2017E-16 1.0000 0.2480E-16 0.2480E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.00000E+00 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.54595E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.24265E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.53079E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.82 -9.46 -3.153 0.16153E+05 -7.460 3 CH4,gas 4.81 2.02 -2.79 -0.698 0.47654E+04 -0.791 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65338E+04 -1.827 5 H2S,gas -5.94 -13.86 -7.92 -3.958 0.13515E+05 -5.915 6 S2,gas -7.03 -36.64 -29.60 -4.554 0.50548E+05 -27.604 7 CO,gas 3.51 -11.36 -14.87 -4.576 0.25395E+05 -12.873 8 SO3,gas 17.43 -31.70 -49.13 -12.282 0.83883E+05 -47.127 9 SO2,gas 1.14 -27.24 -28.38 -7.567 0.48450E+05 -26.375 10 HCl,gas 5.48 -13.13 -18.61 -9.303 0.31769E+05 -16.606 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80596E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.72 -3.70 -1.234 0.63224E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.72 -3.55 -1.183 0.60611E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65547E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -6.90 -3.80 -1.084 0.64800E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -6.90 -3.35 -0.958 0.57262E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82258E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.43 -4.21 -0.990 0.71854E+04 143 pyrrhotite -4.24 -7.12 -2.87 -0.957 0.49032E+04 144 pyrrhotiteFe0.875 -6.00 -8.51 -2.51 -0.923 0.42860E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22425E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23217E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47123E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.12 -2.72 -0.907 0.46464E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60328E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.61 -3.65 -1.215 0.62241E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 8749.9990000 g New total amount of reactant added: 8799.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7632E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8799.9990000 Water: Moles liquid = 0.6345E+01 kg liquid = 0.1143E+00 Moles total = -.5480E+02 kg total = -.9873E+00 Activity = 1.0000 Stoichiometric ionic strength = .1261989E-01 Osmotic coef. = 0.9667 True ionic strength = .2138391E-01 Chg. balance for total moles = 0.7632E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93278E-10 -10.0302 0.78093E-10 -10.1074 0.83721E+00 -0.0772 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.12013E-02 -2.9203 0.99944E-03 -3.0002 0.83194E+00 -0.0799 4 SO4-- 0.66960E-11 -11.1742 0.34246E-11 -11.4654 0.51144E+00 -0.2912 5 HCO3- 0.24113E-05 -5.6178 0.20091E-05 -5.6970 0.83321E+00 -0.0792 6 HS- 0.22309E-03 -3.6515 0.18562E-03 -3.7314 0.83206E+00 -0.0798 7 Al+++ 0.12308E-28 -28.9098 0.27458E-29 -29.5613 0.22309E+00 -0.6515 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.15358E-06 -6.8137 0.77940E-07 -7.1082 0.50750E+00 -0.2946 10 Mg++ 0.24389E-10 -10.6128 0.12318E-10 -10.9095 0.50507E+00 -0.2966 11 Fe++ 0.66713E-13 -13.1758 0.33734E-13 -13.4719 0.50565E+00 -0.2962 12 K+ 0.16684E-03 -3.7777 0.13904E-03 -3.8569 0.83341E+00 -0.0791 13 Na+ 0.21212E-01 -1.6734 0.17643E-01 -1.7534 0.83177E+00 -0.0800 14 Mn++ 0.21449E-10 -10.6686 0.10855E-10 -10.9644 0.50609E+00 -0.2958 15 HPO4-- 0.46285E-07 -7.3346 0.23675E-07 -7.6257 0.51151E+00 -0.2911 16 HSiO3- 0.10688E-01 -1.9711 0.88913E-02 -2.0510 0.83194E+00 -0.0799 17 Ca(HSiO3)+ 0.18626E-07 -7.7299 0.15527E-07 -7.8089 0.83360E+00 -0.0790 18 Mg(HSiO3)+ 0.36636E-11 -11.4361 0.30540E-11 -11.5151 0.83360E+00 -0.0790 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.69727E-16 -16.1566 0.58125E-16 -16.2356 0.83360E+00 -0.0790 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51286E-05 -5.2900 0.42586E-05 -5.3707 0.83037E+00 -0.0807 24 CH4,aq 0.10727E-03 -3.9695 0.10686E-03 -3.9712 0.99616E+00 -0.0017 25 C2H6,aq 0.18187E-12 -12.7402 0.18117E-12 -12.7419 0.99616E+00 -0.0017 29 CO,aq 0.88559E-16 -16.0528 0.88559E-16 -16.0528 0.10000E+01 0.0000 30 CO2,aq 0.31756E-09 -9.4982 0.31634E-09 -9.4999 0.99616E+00 -0.0017 31 CO3-2 0.46614E-05 -5.3315 0.23787E-05 -5.6237 0.51030E+00 -0.2922 32 CaCO3,aq 0.22707E-08 -8.6438 0.22707E-08 -8.6438 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.47332E-11 -11.3248 0.39456E-11 -11.4039 0.83360E+00 -0.0790 34 CaCl+ 0.14891E-09 -9.8271 0.12413E-09 -9.9061 0.83360E+00 -0.0790 35 CaCl2,aq 0.28885E-13 -13.5393 0.28885E-13 -13.5393 0.10000E+01 0.0000 36 CaOH+ 0.84422E-07 -7.0735 0.70374E-07 -7.1526 0.83360E+00 -0.0790 37 CaSO4,aq 0.83164E-16 -16.0801 0.83164E-16 -16.0801 0.10000E+01 0.0000 38 HCl,aq 0.14681E-13 -13.8332 0.14681E-13 -13.8332 0.10000E+01 0.0000 43 FeCl+ 0.62993E-16 -16.2007 0.52511E-16 -16.2797 0.83360E+00 -0.0790 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.17179E-10 -10.7650 0.14321E-10 -10.8440 0.83360E+00 -0.0790 48 HFeO2- 0.36213E-07 -7.4411 0.30127E-07 -7.5210 0.83194E+00 -0.0799 49 FeO+ 0.12680E-16 -16.8969 0.10570E-16 -16.9759 0.83360E+00 -0.0790 51 FeO2- 0.40948E-09 -9.3878 0.34066E-09 -9.4677 0.83194E+00 -0.0799 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10912E-04 -4.9621 0.10870E-04 -4.9638 0.99616E+00 -0.0017 54 KCl,aq 0.24606E-08 -8.6090 0.24606E-08 -8.6090 0.10000E+01 0.0000 56 KOH,aq 0.77619E-06 -6.1100 0.77619E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.88180E-14 -14.0546 0.73360E-14 -14.1345 0.83194E+00 -0.0799 58 MgCO3,aq 0.89675E-13 -13.0473 0.89675E-13 -13.0473 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.76283E-15 -15.1176 0.63590E-15 -15.1966 0.83360E+00 -0.0790 60 MgCl+ 0.21365E-13 -13.6703 0.17810E-13 -13.7493 0.83360E+00 -0.0790 61 MgOH+ 0.73920E-10 -10.1312 0.61619E-10 -10.2103 0.83360E+00 -0.0790 63 MnO,aq 0.18790E-08 -8.7261 0.18790E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.51354E-09 -9.2894 0.42809E-09 -9.3685 0.83360E+00 -0.0790 65 MnO2-2 0.20880E-10 -10.6803 0.10655E-10 -10.9724 0.51030E+00 -0.2922 66 HMnO2- 0.21671E-09 -9.6641 0.18029E-09 -9.7440 0.83194E+00 -0.0799 69 MnCl+ 0.78768E-13 -13.1036 0.65661E-13 -13.1827 0.83360E+00 -0.0790 70 MnSO4,aq 0.10535E-19 -19.9774 0.10535E-19 -19.9774 0.10000E+01 0.0000 71 NaCl,aq 0.57578E-05 -5.2397 0.57578E-05 -5.2397 0.10000E+01 0.0000 72 NaOH,aq 0.99274E-04 -4.0032 0.99274E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.92501E-02 -2.0339 0.76810E-02 -2.1146 0.83037E+00 -0.0807 79 HPO3-2 0.15928E-14 -14.7978 0.81283E-15 -15.0900 0.51030E+00 -0.2922 81 H2PO3- 0.14988E-18 -18.8243 0.12469E-18 -18.9042 0.83194E+00 -0.0799 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.38924E-10 -10.4098 0.32414E-10 -10.4893 0.83276E+00 -0.0795 84 PO4-3 0.11273E-08 -8.9480 0.26476E-09 -9.5771 0.23486E+00 -0.6292 88 HP2O7-3 0.96683E-18 -18.0146 0.21592E-18 -18.6657 0.22333E+00 -0.6511 89 P2O7-4 0.94005E-17 -17.0268 0.68211E-18 -18.1661 0.72561E-01 -1.1393 90 H2S,aq 0.43722E-07 -7.3593 0.43554E-07 -7.3610 0.99616E+00 -0.0017 91 S2-2 0.13662E-12 -12.8645 0.69719E-13 -13.1566 0.51030E+00 -0.2922 97 SO3-2 0.97976E-17 -17.0089 0.50755E-17 -17.2945 0.51803E+00 -0.2856 98 HSO3- 0.27882E-19 -19.5547 0.23196E-19 -19.6346 0.83194E+00 -0.0799 99 HSO4- 0.29737E-18 -18.5267 0.24814E-18 -18.6053 0.83445E+00 -0.0786 Charge balance for all species = 0.6673E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9327768E-10 -.2255727E-01 -.2269444E+02 0.0000 2 H2O 0.1000000E+01 0.5550455E+02 0.9980869E+06 0.0000 3 Cl- 0.1201347E-02 0.1207107E-02 0.4271664E+02 7.1071 4 SO4-- 0.6695989E-11 -.1099993E-03 -.1054722E+02 8.7494 5 HCO3- 0.2411286E-05 0.1143467E-03 0.6964246E+01 4.4104 6 HS- 0.2230895E-03 0.3331325E-03 0.1099704E+02 6.3760 7 Al+++ 0.1230832E-28 0.5128740E-05 0.1381259E+00 0.7608 8 H4SiO4 0.7116651E-03 0.1389072E-01 0.1332649E+04 -3.1477 9 Ca++ 0.1535759E-06 0.2590484E-06 0.1036299E-01 13.1065 10 Mg++ 0.2438909E-10 0.1020887E-09 0.2477402E-05 9.3053 11 Fe++ 0.6671345E-13 0.3686220E-07 0.2054847E-02 6.7428 12 K+ 0.1668360E-03 0.1676146E-03 0.6541980E+01 6.2505 13 Na+ 0.2121179E-01 0.2380835E-01 0.5463397E+03 8.3540 14 Mn++ 0.2144896E-10 0.2651643E-08 0.1454073E-03 9.2504 15 HPO4-- 0.4628459E-07 0.4745083E-07 0.4545883E-02 12.5891 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1457149E+03 -.2578330E-02 -.1457123E+03 0.0000000E+00 2 H2O -.5480335E+02 0.6344254E+01 -.6114760E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2439035E+00 -.1257308E-04 0.2439160E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2438780E+00 0.3807755E-04 -.2439160E+00 0.0000000E+00 7 Al+++ 0.2869452E+02 0.5862228E-06 0.2869452E+02 0.0000000E+00 8 H4SiO4 0.9163248E+02 0.1587730E-02 0.9163089E+02 0.0000000E+00 9 Ca++ 0.1012127E+02 0.2960963E-07 0.1012127E+02 0.0000000E+00 10 Mg++ 0.6984126E+01 0.1166889E-10 0.6984126E+01 0.0000000E+00 11 Fe++ 0.6274475E+01 0.4213406E-08 0.6274475E+01 0.0000000E+00 12 K+ 0.1868365E+01 0.1915861E-04 0.1868346E+01 0.0000000E+00 13 Na+ 0.1104630E+02 0.2721331E-02 0.1104358E+02 0.0000000E+00 14 Mn++ 0.1525796E+00 0.3030869E-09 0.1525796E+00 0.0000000E+00 15 HPO4-- 0.5207467E-01 0.5423701E-08 0.5207466E-01 0.0000000E+00 Chg. balance for solid moles: -.8132E-14 Mass of aqueous solution: 0.114513E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8799.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 11.04 1.043 2894. 3.461 30.10 1111. andradite 0.9757 -0.011 495.8 2.695 5.157 128.8 grossular 0.2329 -0.633 104.9 2.021 1.091 29.20 apatite-OH 0.1736E-01 -1.760 8.719 0.940 0.9069E-01 2.771 clinochlore 1.253 0.098 696.4 2.843 7.243 264.9 daphnite 0.3591 -0.445 256.2 2.409 2.665 77.64 chlorite-Mn 0.3052E-01 -1.515 21.63 1.335 0.2250 6.894 diopside 0.4995 -0.301 108.2 2.034 1.125 33.06 hedenbergite 0.1280 -0.893 31.75 1.502 0.3302 8.696 microcline 1.636 0.214 455.4 2.658 4.736 177.9 stilbite 5.660 0.753 3989. 3.601 41.49 1860. stilpnomelane-Fe 0.4648 -0.333 501.0 2.700 5.211 173.1 tr.625ac.25prg.125 0.6074E-01 -1.217 51.91 1.715 0.5400 16.71 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9614.268851 g Volume = 3890.801801 cm3 Porosity: -10.5028% V(tot) - V(min): -.36980E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8799.9990000 g log = 3.9445 Original solution: 1000.0103000 g Original solution / Rock added: 0.11 (Water/Rock Ratio), log = -0.9445 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2363 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8528E+00 0.9833 0.1037E+01 0.1054E+01 CO2,gas 0.2913E-07 1.0053 0.3621E-07 0.3602E-07 CH4,gas 0.1352E+00 1.0111 0.1690E+00 0.1671E+00 H2,gas 0.1205E-01 1.0007 0.1491E-01 0.1490E-01 H2S,gas 0.1032E-05 0.9952 0.1270E-05 0.1276E-05 S2,gas 0.2199E-27 1.0000 0.2719E-27 0.2719E-27 CO,gas 0.1131E-12 1.0000 0.1398E-12 0.1398E-12 SO3,gas 0.6315E-47 1.0000 0.7808E-47 0.7808E-47 SO2,gas 0.3562E-26 1.0000 0.4404E-26 0.4404E-26 HCl,gas 0.2097E-16 1.0000 0.2592E-16 0.2592E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 -0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 -0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.12132E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.37914E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.36397E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.80 -9.44 -3.147 0.16121E+05 -7.441 3 CH4,gas 4.81 2.04 -2.77 -0.693 0.47334E+04 -0.772 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65338E+04 -1.827 5 H2S,gas -5.94 -13.84 -7.90 -3.948 0.13482E+05 -5.896 6 S2,gas -7.03 -36.60 -29.57 -4.549 0.50482E+05 -27.566 7 CO,gas 3.51 -11.34 -14.85 -4.571 0.25363E+05 -12.854 8 SO3,gas 17.43 -31.68 -49.11 -12.277 0.83850E+05 -47.107 9 SO2,gas 1.14 -27.22 -28.36 -7.562 0.48417E+05 -26.356 10 HCl,gas 5.48 -13.11 -18.59 -9.293 0.31736E+05 -16.586 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80596E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.70 -3.68 -1.228 0.62905E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.70 -3.53 -1.177 0.60291E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65547E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -6.88 -3.78 -1.079 0.64481E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -6.88 -3.33 -0.953 0.56942E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82258E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.40 -4.17 -0.981 0.71196E+04 143 pyrrhotite -4.24 -7.10 -2.85 -0.951 0.48703E+04 144 pyrrhotiteFe0.875 -6.00 -8.49 -2.49 -0.916 0.42531E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22425E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23217E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47123E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.10 -2.70 -0.901 0.46135E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60328E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.59 -3.63 -1.209 0.61912E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 8799.9990000 g New total amount of reactant added: 8849.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7632E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8849.9990000 Water: Moles liquid = 0.6066E+01 kg liquid = 0.1093E+00 Moles total = -.5543E+02 kg total = -.9986E+00 Activity = 1.0000 Stoichiometric ionic strength = .1266638E-01 Osmotic coef. = 0.9666 True ionic strength = .2142071E-01 Chg. balance for total moles = 0.7632E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93437E-10 -10.0295 0.78218E-10 -10.1067 0.83712E+00 -0.0772 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.12566E-02 -2.9008 0.10453E-02 -2.9808 0.83184E+00 -0.0800 4 SO4-- 0.69950E-11 -11.1552 0.35759E-11 -11.4466 0.51120E+00 -0.2914 5 HCO3- 0.25187E-05 -5.5988 0.20984E-05 -5.6781 0.83311E+00 -0.0793 6 HS- 0.23334E-03 -3.6320 0.19413E-03 -3.7119 0.83197E+00 -0.0799 7 Al+++ 0.12380E-28 -28.9073 0.27590E-29 -29.5593 0.22285E+00 -0.6520 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.15414E-06 -6.8121 0.78189E-07 -7.1069 0.50726E+00 -0.2948 10 Mg++ 0.24479E-10 -10.6112 0.12358E-10 -10.9081 0.50483E+00 -0.2969 11 Fe++ 0.66958E-13 -13.1742 0.33841E-13 -13.4706 0.50541E+00 -0.2964 12 K+ 0.16712E-03 -3.7770 0.13926E-03 -3.8562 0.83332E+00 -0.0792 13 Na+ 0.21248E-01 -1.6727 0.17672E-01 -1.7527 0.83168E+00 -0.0800 14 Mn++ 0.21528E-10 -10.6670 0.10890E-10 -10.9630 0.50585E+00 -0.2960 15 HPO4-- 0.46158E-07 -7.3357 0.23600E-07 -7.6271 0.51128E+00 -0.2913 16 HSiO3- 0.10672E-01 -1.9718 0.88772E-02 -2.0517 0.83184E+00 -0.0800 17 Ca(HSiO3)+ 0.18658E-07 -7.7291 0.15551E-07 -7.8082 0.83350E+00 -0.0791 18 Mg(HSiO3)+ 0.36699E-11 -11.4354 0.30588E-11 -11.5144 0.83350E+00 -0.0791 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.69846E-16 -16.1559 0.58217E-16 -16.2349 0.83350E+00 -0.0791 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51210E-05 -5.2906 0.42519E-05 -5.3714 0.83027E+00 -0.0808 24 CH4,aq 0.11222E-03 -3.9499 0.11179E-03 -3.9516 0.99615E+00 -0.0017 25 C2H6,aq 0.19903E-12 -12.7011 0.19826E-12 -12.7028 0.99615E+00 -0.0017 29 CO,aq 0.92642E-16 -16.0332 0.92642E-16 -16.0332 0.10000E+01 0.0000 30 CO2,aq 0.33220E-09 -9.4786 0.33092E-09 -9.4803 0.99615E+00 -0.0017 31 CO3-2 0.48630E-05 -5.3131 0.24805E-05 -5.6055 0.51007E+00 -0.2924 32 CaCO3,aq 0.23753E-08 -8.6243 0.23753E-08 -8.6243 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.49599E-11 -11.3045 0.41341E-11 -11.3836 0.83350E+00 -0.0791 34 CaCl+ 0.15625E-09 -9.8062 0.13023E-09 -9.8853 0.83350E+00 -0.0791 35 CaCl2,aq 0.31695E-13 -13.4990 0.31695E-13 -13.4990 0.10000E+01 0.0000 36 CaOH+ 0.84567E-07 -7.0728 0.70487E-07 -7.1519 0.83350E+00 -0.0791 37 CaSO4,aq 0.87115E-16 -16.0599 0.87115E-16 -16.0599 0.10000E+01 0.0000 38 HCl,aq 0.15378E-13 -13.8131 0.15378E-13 -13.8131 0.10000E+01 0.0000 43 FeCl+ 0.66099E-16 -16.1798 0.55094E-16 -16.2589 0.83350E+00 -0.0791 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.17209E-10 -10.7642 0.14344E-10 -10.8433 0.83350E+00 -0.0791 48 HFeO2- 0.36160E-07 -7.4418 0.30079E-07 -7.5217 0.83184E+00 -0.0800 49 FeO+ 0.12702E-16 -16.8961 0.10587E-16 -16.9752 0.83350E+00 -0.0791 51 FeO2- 0.40887E-09 -9.3884 0.34012E-09 -9.4684 0.83184E+00 -0.0800 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10912E-04 -4.9621 0.10870E-04 -4.9638 0.99615E+00 -0.0017 54 KCl,aq 0.25775E-08 -8.5888 0.25775E-08 -8.5888 0.10000E+01 0.0000 56 KOH,aq 0.77619E-06 -6.1100 0.77619E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.92233E-14 -14.0351 0.76723E-14 -14.1151 0.83184E+00 -0.0800 58 MgCO3,aq 0.93809E-13 -13.0278 0.93809E-13 -13.0278 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.79936E-15 -15.0973 0.66627E-15 -15.1763 0.83350E+00 -0.0791 60 MgCl+ 0.22418E-13 -13.6494 0.18685E-13 -13.7285 0.83350E+00 -0.0791 61 MgOH+ 0.74046E-10 -10.1305 0.61718E-10 -10.2096 0.83350E+00 -0.0791 63 MnO,aq 0.18790E-08 -8.7261 0.18790E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.51443E-09 -9.2887 0.42878E-09 -9.3678 0.83350E+00 -0.0791 65 MnO2-2 0.20824E-10 -10.6814 0.10621E-10 -10.9738 0.51007E+00 -0.2924 66 HMnO2- 0.21639E-09 -9.6648 0.18000E-09 -9.7447 0.83184E+00 -0.0800 69 MnCl+ 0.82652E-13 -13.0827 0.68890E-13 -13.1618 0.83350E+00 -0.0791 70 MnSO4,aq 0.11036E-19 -19.9572 0.11036E-19 -19.9572 0.10000E+01 0.0000 71 NaCl,aq 0.60313E-05 -5.2196 0.60313E-05 -5.2196 0.10000E+01 0.0000 72 NaOH,aq 0.99274E-04 -4.0032 0.99274E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.92365E-02 -2.0345 0.76688E-02 -2.1153 0.83027E+00 -0.0808 79 HPO3-2 0.15885E-14 -14.7990 0.81024E-15 -15.0914 0.51007E+00 -0.2924 81 H2PO3- 0.14966E-18 -18.8249 0.12449E-18 -18.9049 0.83184E+00 -0.0800 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.38867E-10 -10.4104 0.32363E-10 -10.4900 0.83266E+00 -0.0795 84 PO4-3 0.11230E-08 -8.9496 0.26350E-09 -9.5792 0.23463E+00 -0.6296 88 HP2O7-3 0.96323E-18 -18.0163 0.21489E-18 -18.6678 0.22310E+00 -0.6515 89 P2O7-4 0.93578E-17 -17.0288 0.67778E-18 -18.1689 0.72429E-01 -1.1401 90 H2S,aq 0.45800E-07 -7.3391 0.45623E-07 -7.3408 0.99615E+00 -0.0017 91 S2-2 0.14951E-12 -12.8253 0.76258E-13 -13.1177 0.51007E+00 -0.2924 97 SO3-2 0.10235E-16 -16.9899 0.52997E-17 -17.2757 0.51781E+00 -0.2858 98 HSO3- 0.29163E-19 -19.5352 0.24259E-19 -19.6151 0.83184E+00 -0.0800 99 HSO4- 0.31104E-18 -18.5072 0.25952E-18 -18.5858 0.83436E+00 -0.0786 Charge balance for all species = 0.6988E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9343656E-10 -.2252806E-01 -.2266501E+02 0.0000 2 H2O 0.1000000E+01 0.5550456E+02 0.9980852E+06 0.0000 3 Cl- 0.1256562E-02 0.1262596E-02 0.4468018E+02 7.1259 4 SO4-- 0.6995022E-11 -.1149465E-03 -.1102156E+02 8.7668 5 HCO3- 0.2518732E-05 0.1196030E-03 0.7284369E+01 4.4286 6 HS- 0.2333446E-03 0.3483368E-03 0.1149893E+02 6.3948 7 Al+++ 0.1238024E-28 0.5121191E-05 0.1379223E+00 0.7608 8 H4SiO4 0.7116651E-03 0.1387496E-01 0.1331135E+04 -3.1477 9 Ca++ 0.1541380E-06 0.2598989E-06 0.1039700E-01 13.1065 10 Mg++ 0.2447851E-10 0.1023194E-09 0.2482997E-05 9.3053 11 Fe++ 0.6695796E-13 0.3680823E-07 0.2051834E-02 6.7428 12 K+ 0.1671212E-03 0.1678999E-03 0.6553102E+01 6.2505 13 Na+ 0.2124811E-01 0.2384494E-01 0.5471783E+03 8.3540 14 Mn++ 0.2152767E-10 0.2652243E-08 0.1454399E-03 9.2504 15 HPO4-- 0.4615845E-07 0.4732035E-07 0.4533375E-02 12.5863 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1465428E+03 -.2461825E-02 -.1465404E+03 0.0000000E+00 2 H2O -.5543012E+02 0.6065436E+01 -.6149555E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2452891E+00 -.1256114E-04 0.2453017E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2452636E+00 0.3806561E-04 -.2453017E+00 0.0000000E+00 7 Al+++ 0.2885756E+02 0.5596343E-06 0.2885756E+02 0.0000000E+00 8 H4SiO4 0.9215312E+02 0.1516230E-02 0.9215160E+02 0.0000000E+00 9 Ca++ 0.1017878E+02 0.2840128E-07 0.1017878E+02 0.0000000E+00 10 Mg++ 0.7023809E+01 0.1118128E-10 0.7023809E+01 0.0000000E+00 11 Fe++ 0.6310125E+01 0.4022335E-08 0.6310125E+01 0.0000000E+00 12 K+ 0.1878981E+01 0.1834780E-04 0.1878962E+01 0.0000000E+00 13 Na+ 0.1110906E+02 0.2605731E-02 0.1110646E+02 0.0000000E+00 14 Mn++ 0.1534466E+00 0.2898322E-09 0.1534466E+00 0.0000000E+00 15 HPO4-- 0.5237055E-01 0.5171081E-08 0.5237054E-01 0.0000000E+00 Chg. balance for solid moles: 0.2248E-14 Mass of aqueous solution: 0.109480E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8849.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 11.10 1.045 2910. 3.464 30.10 1117. andradite 0.9812 -0.008 498.6 2.698 5.157 129.5 grossular 0.2343 -0.630 105.5 2.023 1.091 29.36 apatite-OH 0.1746E-01 -1.758 8.769 0.943 0.9069E-01 2.786 clinochlore 1.260 0.100 700.3 2.845 7.243 266.4 daphnite 0.3611 -0.442 257.7 2.411 2.665 78.08 chlorite-Mn 0.3069E-01 -1.513 21.76 1.338 0.2250 6.934 diopside 0.5024 -0.299 108.8 2.037 1.125 33.25 hedenbergite 0.1287 -0.890 31.93 1.504 0.3303 8.747 microcline 1.645 0.216 457.9 2.661 4.736 178.9 stilbite 5.692 0.755 4011. 3.603 41.48 1871. stilpnomelane-Fe 0.4674 -0.330 503.9 2.702 5.211 174.0 tr.625ac.25prg.125 0.6108E-01 -1.214 52.21 1.718 0.5399 16.80 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9668.896586 g Volume = 3912.904976 cm3 Porosity: -10.5028% V(tot) - V(min): -.37191E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8849.9990000 g log = 3.9469 Original solution: 1000.0103000 g Original solution / Rock added: 0.11 (Water/Rock Ratio), log = -0.9469 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2442 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8475E+00 0.9832 0.1037E+01 0.1054E+01 CO2,gas 0.3029E-07 1.0052 0.3788E-07 0.3768E-07 CH4,gas 0.1405E+00 1.0110 0.1768E+00 0.1748E+00 H2,gas 0.1197E-01 1.0007 0.1491E-01 0.1490E-01 H2S,gas 0.1075E-05 0.9952 0.1331E-05 0.1337E-05 S2,gas 0.2398E-27 1.0000 0.2984E-27 0.2984E-27 CO,gas 0.1176E-12 1.0000 0.1463E-12 0.1463E-12 SO3,gas 0.6574E-47 1.0000 0.8179E-47 0.8179E-47 SO2,gas 0.3708E-26 1.0000 0.4613E-26 0.4613E-26 HCl,gas 0.2182E-16 1.0000 0.2715E-16 0.2715E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.00000E+00 46 clinochlore 39.19 39.19 0.00 0.000 -0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.54595E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.36397E-10 67 diopside 16.22 16.22 0.00 0.000 -0.60662E-11 68 hedenbergite 14.24 14.24 0.00 0.000 -0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 -0.24265E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.78 -9.42 -3.141 0.16087E+05 -7.422 3 CH4,gas 4.81 2.06 -2.75 -0.688 0.47000E+04 -0.753 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65338E+04 -1.827 5 H2S,gas -5.94 -13.82 -7.88 -3.938 0.13448E+05 -5.876 6 S2,gas -7.03 -36.56 -29.53 -4.542 0.50414E+05 -27.525 7 CO,gas 3.51 -11.32 -14.83 -4.565 0.25330E+05 -12.835 8 SO3,gas 17.43 -31.66 -49.09 -12.272 0.83815E+05 -47.087 9 SO2,gas 1.14 -27.20 -28.34 -7.556 0.48383E+05 -26.336 10 HCl,gas 5.48 -13.09 -18.57 -9.283 0.31701E+05 -16.566 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80595E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.68 -3.66 -1.221 0.62570E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.68 -3.51 -1.170 0.59957E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65547E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13291E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -6.86 -3.76 -1.073 0.64146E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -6.86 -3.32 -0.947 0.56608E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82258E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.35 -4.13 -0.972 0.70508E+04 143 pyrrhotite -4.24 -7.08 -2.83 -0.944 0.48359E+04 144 pyrrhotiteFe0.875 -6.00 -8.47 -2.47 -0.909 0.42186E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22425E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23217E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47123E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.08 -2.68 -0.894 0.45791E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60328E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.57 -3.61 -1.202 0.61568E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 8849.9990000 g New total amount of reactant added: 8899.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7631E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8899.9990000 Water: Moles liquid = 0.5787E+01 kg liquid = 0.1043E+00 Moles total = -.5606E+02 kg total = -.1010E+01 Activity = 1.0000 Stoichiometric ionic strength = .1271737E-01 Osmotic coef. = 0.9666 True ionic strength = .2146111E-01 Chg. balance for total moles = 0.7631E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93611E-10 -10.0287 0.78354E-10 -10.1059 0.83702E+00 -0.0773 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13171E-02 -2.8804 0.10955E-02 -2.9604 0.83173E+00 -0.0800 4 SO4-- 0.73220E-11 -11.1354 0.37412E-11 -11.4270 0.51095E+00 -0.2916 5 HCO3- 0.26362E-05 -5.5790 0.21960E-05 -5.6584 0.83301E+00 -0.0794 6 HS- 0.24459E-03 -3.6116 0.20346E-03 -3.6915 0.83186E+00 -0.0800 7 Al+++ 0.12460E-28 -28.9045 0.27735E-29 -29.5570 0.22260E+00 -0.6525 8 H4SiO4 0.71167E-03 -3.1477 0.71167E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.15476E-06 -6.8104 0.78462E-07 -7.1053 0.50700E+00 -0.2950 10 Mg++ 0.24577E-10 -10.6095 0.12401E-10 -10.9066 0.50457E+00 -0.2971 11 Fe++ 0.67227E-13 -13.1725 0.33960E-13 -13.4690 0.50515E+00 -0.2966 12 K+ 0.16743E-03 -3.7762 0.13951E-03 -3.8554 0.83321E+00 -0.0792 13 Na+ 0.21288E-01 -1.6719 0.17702E-01 -1.7520 0.83157E+00 -0.0801 14 Mn++ 0.21614E-10 -10.6653 0.10928E-10 -10.9615 0.50559E+00 -0.2962 15 HPO4-- 0.46021E-07 -7.3370 0.23518E-07 -7.6286 0.51102E+00 -0.2916 16 HSiO3- 0.10655E-01 -1.9725 0.88617E-02 -2.0525 0.83173E+00 -0.0800 17 Ca(HSiO3)+ 0.18693E-07 -7.7283 0.15578E-07 -7.8075 0.83340E+00 -0.0791 18 Mg(HSiO3)+ 0.36767E-11 -11.4345 0.30642E-11 -11.5137 0.83340E+00 -0.0791 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.69977E-16 -16.1550 0.58319E-16 -16.2342 0.83340E+00 -0.0791 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51128E-05 -5.2913 0.42444E-05 -5.3722 0.83016E+00 -0.0808 24 CH4,aq 0.11764E-03 -3.9294 0.11719E-03 -3.9311 0.99613E+00 -0.0017 25 C2H6,aq 0.21873E-12 -12.6601 0.21789E-12 -12.6618 0.99613E+00 -0.0017 29 CO,aq 0.97120E-16 -16.0127 0.97120E-16 -16.0127 0.10000E+01 0.0000 30 CO2,aq 0.34826E-09 -9.4581 0.34691E-09 -9.4598 0.99613E+00 -0.0017 31 CO3-2 0.50828E-05 -5.2939 0.25913E-05 -5.5865 0.50981E+00 -0.2926 32 CaCO3,aq 0.24902E-08 -8.6038 0.24902E-08 -8.6038 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.52093E-11 -11.2832 0.43414E-11 -11.3624 0.83340E+00 -0.0791 34 CaCl+ 0.16435E-09 -9.7842 0.13697E-09 -9.8634 0.83340E+00 -0.0791 35 CaCl2,aq 0.34935E-13 -13.4567 0.34935E-13 -13.4567 0.10000E+01 0.0000 36 CaOH+ 0.84725E-07 -7.0720 0.70610E-07 -7.1511 0.83340E+00 -0.0791 37 CaSO4,aq 0.91460E-16 -16.0388 0.91460E-16 -16.0388 0.10000E+01 0.0000 38 HCl,aq 0.16145E-13 -13.7920 0.16145E-13 -13.7920 0.10000E+01 0.0000 43 FeCl+ 0.69525E-16 -16.1579 0.57942E-16 -16.2370 0.83340E+00 -0.0791 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.17241E-10 -10.7634 0.14369E-10 -10.8426 0.83340E+00 -0.0791 48 HFeO2- 0.36102E-07 -7.4425 0.30027E-07 -7.5225 0.83173E+00 -0.0800 49 FeO+ 0.12726E-16 -16.8953 0.10606E-16 -16.9745 0.83340E+00 -0.0791 51 FeO2- 0.40821E-09 -9.3891 0.33952E-09 -9.4691 0.83173E+00 -0.0800 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10912E-04 -4.9621 0.10870E-04 -4.9638 0.99613E+00 -0.0017 54 KCl,aq 0.27060E-08 -8.5677 0.27060E-08 -8.5677 0.10000E+01 0.0000 56 KOH,aq 0.77619E-06 -6.1100 0.77619E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.96677E-14 -14.0147 0.80410E-14 -14.0947 0.83173E+00 -0.0800 58 MgCO3,aq 0.98343E-13 -13.0073 0.98343E-13 -13.0073 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.83957E-15 -15.0759 0.69970E-15 -15.1551 0.83340E+00 -0.0791 60 MgCl+ 0.23580E-13 -13.6275 0.19652E-13 -13.7066 0.83340E+00 -0.0791 61 MgOH+ 0.74185E-10 -10.1297 0.61826E-10 -10.2088 0.83340E+00 -0.0791 63 MnO,aq 0.18790E-08 -8.7261 0.18790E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.51539E-09 -9.2879 0.42953E-09 -9.3670 0.83340E+00 -0.0791 65 MnO2-2 0.20762E-10 -10.6827 0.10585E-10 -10.9753 0.50981E+00 -0.2926 66 HMnO2- 0.21604E-09 -9.6655 0.17969E-09 -9.7455 0.83173E+00 -0.0800 69 MnCl+ 0.86937E-13 -13.0608 0.72453E-13 -13.1399 0.83340E+00 -0.0791 70 MnSO4,aq 0.11586E-19 -19.9361 0.11586E-19 -19.9361 0.10000E+01 0.0000 71 NaCl,aq 0.63321E-05 -5.1985 0.63321E-05 -5.1985 0.10000E+01 0.0000 72 NaOH,aq 0.99274E-04 -4.0032 0.99274E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.92216E-02 -2.0352 0.76554E-02 -2.1160 0.83016E+00 -0.0808 79 HPO3-2 0.15838E-14 -14.8003 0.80742E-15 -15.0929 0.50981E+00 -0.2926 81 H2PO3- 0.14941E-18 -18.8256 0.12427E-18 -18.9056 0.83173E+00 -0.0800 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.38804E-10 -10.4111 0.32306E-10 -10.4907 0.83256E+00 -0.0796 84 PO4-3 0.11184E-08 -8.9514 0.26212E-09 -9.5815 0.23438E+00 -0.6301 88 HP2O7-3 0.95930E-18 -18.0180 0.21377E-18 -18.6700 0.22284E+00 -0.6520 89 P2O7-4 0.93112E-17 -17.0310 0.67306E-18 -18.1719 0.72285E-01 -1.1410 90 H2S,aq 0.48085E-07 -7.3180 0.47899E-07 -7.3197 0.99613E+00 -0.0017 91 S2-2 0.16430E-12 -12.7844 0.83762E-13 -13.0770 0.50981E+00 -0.2926 97 SO3-2 0.10713E-16 -16.9701 0.55447E-17 -17.2561 0.51756E+00 -0.2860 98 HSO3- 0.30568E-19 -19.5147 0.25425E-19 -19.5947 0.83173E+00 -0.0800 99 HSO4- 0.32603E-18 -18.4867 0.27199E-18 -18.5654 0.83425E+00 -0.0787 Charge balance for all species = 0.7321E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9361102E-10 -.2249610E-01 -.2263282E+02 0.0000 2 H2O 0.1000000E+01 0.5550456E+02 0.9980834E+06 0.0000 3 Cl- 0.1317097E-02 0.1323432E-02 0.4683293E+02 7.1455 4 SO4-- 0.7322003E-11 -.1203720E-03 -.1154175E+02 8.7849 5 HCO3- 0.2636194E-05 0.1253659E-03 0.7635340E+01 4.4476 6 HS- 0.2445878E-03 0.3650079E-03 0.1204923E+02 6.4144 7 Al+++ 0.1245955E-28 0.5112930E-05 0.1376996E+00 0.7608 8 H4SiO4 0.7116650E-03 0.1385772E-01 0.1329478E+04 -3.1477 9 Ca++ 0.1547564E-06 0.2608339E-06 0.1043438E-01 13.1065 10 Mg++ 0.2457690E-10 0.1025724E-09 0.2489132E-05 9.3053 11 Fe++ 0.6722699E-13 0.3674918E-07 0.2048539E-02 6.7428 12 K+ 0.1674343E-03 0.1682132E-03 0.6565315E+01 6.2505 13 Na+ 0.2128798E-01 0.2388511E-01 0.5480990E+03 8.3540 14 Mn++ 0.2161427E-10 0.2652902E-08 0.1454758E-03 9.2504 15 HPO4-- 0.4602061E-07 0.4717778E-07 0.4519708E-02 12.5833 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1473708E+03 -.2345327E-02 -.1473684E+03 0.0000000E+00 2 H2O -.5605689E+02 0.5786618E+01 -.6184351E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2466748E+00 -.1254936E-04 0.2466874E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2466493E+00 0.3805383E-04 -.2466874E+00 0.0000000E+00 7 Al+++ 0.2902060E+02 0.5330476E-06 0.2902060E+02 0.0000000E+00 8 H4SiO4 0.9267376E+02 0.1444733E-02 0.9267231E+02 0.0000000E+00 9 Ca++ 0.1023628E+02 0.2719319E-07 0.1023628E+02 0.0000000E+00 10 Mg++ 0.7063491E+01 0.1069367E-10 0.7063491E+01 0.0000000E+00 11 Fe++ 0.6345776E+01 0.3831279E-08 0.6345776E+01 0.0000000E+00 12 K+ 0.1889596E+01 0.1753703E-04 0.1889579E+01 0.0000000E+00 13 Na+ 0.1117183E+02 0.2490138E-02 0.1116934E+02 0.0000000E+00 14 Mn++ 0.1543135E+00 0.2765778E-09 0.1543135E+00 0.0000000E+00 15 HPO4-- 0.5266643E-01 0.4918511E-08 0.5266642E-01 0.0000000E+00 Chg. balance for solid moles: -.3469E-14 Mass of aqueous solution: 0.104448E+03 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8899.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 11.16 1.048 2927. 3.466 30.10 1124. andradite 0.9867 -0.006 501.4 2.700 5.157 130.3 grossular 0.2356 -0.628 106.1 2.026 1.091 29.53 apatite-OH 0.1756E-01 -1.756 8.818 0.945 0.9069E-01 2.802 clinochlore 1.267 0.103 704.3 2.848 7.243 267.9 daphnite 0.3632 -0.440 259.1 2.413 2.665 78.52 chlorite-Mn 0.3086E-01 -1.511 21.88 1.340 0.2250 6.973 diopside 0.5053 -0.296 109.4 2.039 1.125 33.44 hedenbergite 0.1295 -0.888 32.12 1.507 0.3303 8.797 microcline 1.655 0.219 460.5 2.663 4.736 179.9 stilbite 5.724 0.758 4034. 3.606 41.48 1881. stilpnomelane-Fe 0.4701 -0.328 506.7 2.705 5.211 175.0 tr.625ac.25prg.125 0.6142E-01 -1.212 52.50 1.720 0.5399 16.90 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9723.524321 g Volume = 3935.008151 cm3 Porosity: -10.5029% V(tot) - V(min): -.37401E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8899.9990000 g log = 3.9494 Original solution: 1000.0103000 g Original solution / Rock added: 0.11 (Water/Rock Ratio), log = -0.9494 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2527 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8418E+00 0.9831 0.1037E+01 0.1055E+01 CO2,gas 0.3154E-07 1.0051 0.3971E-07 0.3951E-07 CH4,gas 0.1463E+00 1.0109 0.1853E+00 0.1833E+00 H2,gas 0.1189E-01 1.0007 0.1491E-01 0.1490E-01 H2S,gas 0.1121E-05 0.9951 0.1397E-05 0.1404E-05 S2,gas 0.2625E-27 1.0000 0.3289E-27 0.3289E-27 CO,gas 0.1224E-12 1.0000 0.1534E-12 0.1534E-12 SO3,gas 0.6855E-47 1.0000 0.8587E-47 0.8587E-47 SO2,gas 0.3866E-26 1.0000 0.4843E-26 0.4843E-26 HCl,gas 0.2276E-16 1.0000 0.2851E-16 0.2851E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.28435E-12 22 andradite 39.09 39.09 0.00 0.000 0.24265E-10 23 grossular 32.83 32.83 0.00 0.000 0.24265E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.48529E-10 47 daphnite 29.09 29.09 0.00 0.000 0.18198E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.48529E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 0.30331E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.00000E+00 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.76 -9.40 -3.134 0.16052E+05 -7.401 3 CH4,gas 4.81 2.08 -2.73 -0.683 0.46650E+04 -0.732 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65338E+04 -1.827 5 H2S,gas -5.94 -13.80 -7.85 -3.927 0.13412E+05 -5.855 6 S2,gas -7.03 -36.52 -29.48 -4.536 0.50341E+05 -27.483 7 CO,gas 3.51 -11.30 -14.81 -4.558 0.25295E+05 -12.814 8 SO3,gas 17.43 -31.64 -49.07 -12.267 0.83779E+05 -47.066 9 SO2,gas 1.14 -27.18 -28.31 -7.551 0.48347E+05 -26.315 10 HCl,gas 5.48 -13.07 -18.55 -9.273 0.31665E+05 -16.545 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80595E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.66 -3.64 -1.215 0.62220E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.66 -3.49 -1.164 0.59607E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65547E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13290E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -6.84 -3.74 -1.068 0.63796E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -6.84 -3.29 -0.941 0.56258E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82258E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.31 -4.09 -0.962 0.69786E+04 143 pyrrhotite -4.24 -7.05 -2.81 -0.937 0.47998E+04 144 pyrrhotiteFe0.875 -6.00 -8.45 -2.45 -0.901 0.41826E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22425E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23217E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47123E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.05 -2.66 -0.887 0.45430E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60328E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.55 -3.58 -1.195 0.61207E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 8899.9990000 g New total amount of reactant added: 8949.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7631E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8949.9990000 Water: Moles liquid = 0.5508E+01 kg liquid = 0.9923E-01 Moles total = -.5668E+02 kg total = -.1021E+01 Activity = 1.0000 Stoichiometric ionic strength = .1277356E-01 Osmotic coef. = 0.9665 True ionic strength = .2150568E-01 Chg. balance for total moles = 0.7631E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.93803E-10 -10.0278 0.78505E-10 -10.1051 0.83691E+00 -0.0773 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.13838E-02 -2.8589 0.11508E-02 -2.9390 0.83161E+00 -0.0801 4 SO4-- 0.76810E-11 -11.1146 0.39225E-11 -11.4064 0.51067E+00 -0.2919 5 HCO3- 0.27651E-05 -5.5583 0.23031E-05 -5.6377 0.83289E+00 -0.0794 6 HS- 0.25697E-03 -3.5901 0.21373E-03 -3.6701 0.83174E+00 -0.0800 7 Al+++ 0.12547E-28 -28.9014 0.27895E-29 -29.5545 0.22232E+00 -0.6530 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.15544E-06 -6.8084 0.78764E-07 -7.1037 0.50672E+00 -0.2952 10 Mg++ 0.24686E-10 -10.6076 0.12449E-10 -10.9049 0.50428E+00 -0.2973 11 Fe++ 0.67524E-13 -13.1705 0.34090E-13 -13.4674 0.50486E+00 -0.2968 12 K+ 0.16778E-03 -3.7753 0.13978E-03 -3.8546 0.83309E+00 -0.0793 13 Na+ 0.21332E-01 -1.6710 0.17736E-01 -1.7511 0.83145E+00 -0.0802 14 Mn++ 0.21710E-10 -10.6633 0.10970E-10 -10.9598 0.50530E+00 -0.2964 15 HPO4-- 0.45869E-07 -7.3385 0.23427E-07 -7.6303 0.51074E+00 -0.2918 16 HSiO3- 0.10636E-01 -1.9732 0.88447E-02 -2.0533 0.83161E+00 -0.0801 17 Ca(HSiO3)+ 0.18731E-07 -7.7274 0.15608E-07 -7.8066 0.83328E+00 -0.0792 18 Mg(HSiO3)+ 0.36843E-11 -11.4336 0.30701E-11 -11.5129 0.83328E+00 -0.0792 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.70122E-16 -16.1541 0.58431E-16 -16.2334 0.83328E+00 -0.0792 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.51037E-05 -5.2921 0.42363E-05 -5.3730 0.83004E+00 -0.0809 24 CH4,aq 0.12362E-03 -3.9079 0.12314E-03 -3.9096 0.99611E+00 -0.0017 25 C2H6,aq 0.24152E-12 -12.6170 0.24058E-12 -12.6187 0.99611E+00 -0.0017 26 C3H8,aq 0.10826E-19 -19.9655 0.10784E-19 -19.9672 0.99611E+00 -0.0017 29 CO,aq 0.10205E-15 -15.9912 0.10205E-15 -15.9912 0.10000E+01 0.0000 30 CO2,aq 0.36596E-09 -9.4366 0.36453E-09 -9.4383 0.99611E+00 -0.0017 31 CO3-2 0.53234E-05 -5.2738 0.27124E-05 -5.5666 0.50953E+00 -0.2928 32 CaCO3,aq 0.26166E-08 -8.5823 0.26166E-08 -8.5823 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.54852E-11 -11.2608 0.45707E-11 -11.3400 0.83328E+00 -0.0792 34 CaCl+ 0.17333E-09 -9.7611 0.14443E-09 -9.8403 0.83328E+00 -0.0792 35 CaCl2,aq 0.38698E-13 -13.4123 0.38698E-13 -13.4123 0.10000E+01 0.0000 36 CaOH+ 0.84900E-07 -7.0711 0.70746E-07 -7.1503 0.83328E+00 -0.0792 37 CaSO4,aq 0.96261E-16 -16.0165 0.96261E-16 -16.0165 0.10000E+01 0.0000 38 HCl,aq 0.16993E-13 -13.7697 0.16993E-13 -13.7697 0.10000E+01 0.0000 43 FeCl+ 0.73325E-16 -16.1347 0.61101E-16 -16.2140 0.83328E+00 -0.0792 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.17277E-10 -10.7625 0.14396E-10 -10.8417 0.83328E+00 -0.0792 48 HFeO2- 0.36037E-07 -7.4432 0.29969E-07 -7.5233 0.83161E+00 -0.0801 49 FeO+ 0.12752E-16 -16.8944 0.10626E-16 -16.9736 0.83328E+00 -0.0792 51 FeO2- 0.40749E-09 -9.3899 0.33887E-09 -9.4700 0.83161E+00 -0.0801 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10912E-04 -4.9621 0.10870E-04 -4.9638 0.99611E+00 -0.0017 54 KCl,aq 0.28481E-08 -8.5455 0.28481E-08 -8.5455 0.10000E+01 0.0000 56 KOH,aq 0.77619E-06 -6.1100 0.77619E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10157E-13 -13.9932 0.84468E-14 -14.0733 0.83161E+00 -0.0801 58 MgCO3,aq 0.10334E-12 -12.9857 0.10334E-12 -12.9857 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.88403E-15 -15.0535 0.73664E-15 -15.1327 0.83328E+00 -0.0792 60 MgCl+ 0.24869E-13 -13.6043 0.20723E-13 -13.6836 0.83328E+00 -0.0792 61 MgOH+ 0.74338E-10 -10.1288 0.61944E-10 -10.2080 0.83328E+00 -0.0792 63 MnO,aq 0.18790E-08 -8.7261 0.18790E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.51646E-09 -9.2870 0.43036E-09 -9.3662 0.83328E+00 -0.0792 65 MnO2-2 0.20694E-10 -10.6842 0.10544E-10 -10.9770 0.50953E+00 -0.2928 66 HMnO2- 0.21566E-09 -9.6662 0.17934E-09 -9.7463 0.83161E+00 -0.0801 69 MnCl+ 0.91689E-13 -13.0377 0.76403E-13 -13.1169 0.83328E+00 -0.0792 70 MnSO4,aq 0.12195E-19 -19.9138 0.12195E-19 -19.9138 0.10000E+01 0.0000 71 NaCl,aq 0.66645E-05 -5.1762 0.66645E-05 -5.1762 0.10000E+01 0.0000 72 NaOH,aq 0.99274E-04 -4.0032 0.99274E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.92052E-02 -2.0360 0.76407E-02 -2.1169 0.83004E+00 -0.0809 79 HPO3-2 0.15786E-14 -14.8017 0.80432E-15 -15.0946 0.50953E+00 -0.2928 81 H2PO3- 0.14915E-18 -18.8264 0.12403E-18 -18.9065 0.83161E+00 -0.0801 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.38735E-10 -10.4119 0.32244E-10 -10.4915 0.83244E+00 -0.0796 84 PO4-3 0.11133E-08 -8.9534 0.26061E-09 -9.5840 0.23410E+00 -0.6306 88 HP2O7-3 0.95499E-18 -18.0200 0.21254E-18 -18.6726 0.22256E+00 -0.6526 89 P2O7-4 0.92603E-17 -17.0334 0.66791E-18 -18.1753 0.72126E-01 -1.1419 90 H2S,aq 0.50610E-07 -7.2958 0.50414E-07 -7.2975 0.99611E+00 -0.0017 91 S2-2 0.18141E-12 -12.7413 0.92431E-13 -13.0342 0.50953E+00 -0.2928 97 SO3-2 0.11238E-16 -16.9493 0.58134E-17 -17.2356 0.51728E+00 -0.2863 98 HSO3- 0.32116E-19 -19.4933 0.26708E-19 -19.5734 0.83161E+00 -0.0801 99 HSO4- 0.34253E-18 -18.4653 0.28572E-18 -18.5441 0.83414E+00 -0.0788 Charge balance for all species = 0.7689E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9380344E-10 -.2246099E-01 -.2259744E+02 0.0000 2 H2O 0.1000000E+01 0.5550457E+02 0.9980813E+06 0.0000 3 Cl- 0.1383760E-02 0.1390428E-02 0.4920362E+02 7.1661 4 SO4-- 0.7681042E-11 -.1263487E-03 -.1211480E+02 8.8038 5 HCO3- 0.2765141E-05 0.1317123E-03 0.8021843E+01 4.4674 6 HS- 0.2569694E-03 0.3833687E-03 0.1265531E+02 6.4350 7 Al+++ 0.1254745E-28 0.5103853E-05 0.1374548E+00 0.7608 8 H4SiO4 0.7116650E-03 0.1383877E-01 0.1327657E+04 -3.1477 9 Ca++ 0.1554402E-06 0.2618666E-06 0.1047567E-01 13.1065 10 Mg++ 0.2468568E-10 0.1028510E-09 0.2495888E-05 9.3053 11 Fe++ 0.6752441E-13 0.3668428E-07 0.2044916E-02 6.7428 12 K+ 0.1677796E-03 0.1685587E-03 0.6578785E+01 6.2505 13 Na+ 0.2133196E-01 0.2392942E-01 0.5491146E+03 8.3540 14 Mn++ 0.2170999E-10 0.2653628E-08 0.1455152E-03 9.2504 15 HPO4-- 0.4586936E-07 0.4702135E-07 0.4504712E-02 12.5799 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1481987E+03 -.2228836E-02 -.1481965E+03 0.0000000E+00 2 H2O -.5668366E+02 0.5507800E+01 -.6219146E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2480605E+00 -.1253776E-04 0.2480730E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2480350E+00 0.3804223E-04 -.2480730E+00 0.0000000E+00 7 Al+++ 0.2918363E+02 0.5064628E-06 0.2918363E+02 0.0000000E+00 8 H4SiO4 0.9319440E+02 0.1373241E-02 0.9319302E+02 0.0000000E+00 9 Ca++ 0.1029379E+02 0.2598541E-07 0.1029379E+02 0.0000000E+00 10 Mg++ 0.7103174E+01 0.1020606E-10 0.7103174E+01 0.0000000E+00 11 Fe++ 0.6381426E+01 0.3640235E-08 0.6381426E+01 0.0000000E+00 12 K+ 0.1900212E+01 0.1672632E-04 0.1900195E+01 0.0000000E+00 13 Na+ 0.1123459E+02 0.2374551E-02 0.1123221E+02 0.0000000E+00 14 Mn++ 0.1551804E+00 0.2633233E-09 0.1551804E+00 0.0000000E+00 15 HPO4-- 0.5296230E-01 0.4665998E-08 0.5296230E-01 0.0000000E+00 Chg. balance for solid moles: 0.9298E-14 Mass of aqueous solution: 0.994154E+02 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8949.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 11.22 1.050 2943. 3.469 30.10 1130. andradite 0.9923 -0.003 504.3 2.703 5.157 131.0 grossular 0.2369 -0.625 106.7 2.028 1.091 29.69 apatite-OH 0.1765E-01 -1.753 8.868 0.948 0.9069E-01 2.818 clinochlore 1.274 0.105 708.3 2.850 7.243 269.4 daphnite 0.3652 -0.437 260.6 2.416 2.665 78.96 chlorite-Mn 0.3104E-01 -1.508 22.00 1.342 0.2250 7.012 diopside 0.5082 -0.294 110.1 2.042 1.126 33.64 hedenbergite 0.1302 -0.885 32.30 1.509 0.3303 8.847 microcline 1.664 0.221 463.1 2.666 4.736 180.9 stilbite 5.756 0.760 4056. 3.608 41.48 1892. stilpnomelane-Fe 0.4727 -0.325 509.6 2.707 5.211 176.0 tr.625ac.25prg.125 0.6176E-01 -1.209 52.79 1.723 0.5399 16.99 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9778.152054 g Volume = 3957.111326 cm3 Porosity: -10.5030% V(tot) - V(min): -.37611E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8949.9990000 g log = 3.9518 Original solution: 1000.0103000 g Original solution / Rock added: 0.11 (Water/Rock Ratio), log = -0.9518 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2621 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8356E+00 0.9830 0.1037E+01 0.1055E+01 CO2,gas 0.3290E-07 1.0050 0.4173E-07 0.4152E-07 CH4,gas 0.1526E+00 1.0108 0.1947E+00 0.1926E+00 H2,gas 0.1180E-01 1.0007 0.1491E-01 0.1490E-01 H2S,gas 0.1171E-05 0.9951 0.1470E-05 0.1478E-05 S2,gas 0.2886E-27 1.0000 0.3643E-27 0.3643E-27 CO,gas 0.1277E-12 1.0000 0.1611E-12 0.1611E-12 SO3,gas 0.7161E-47 1.0000 0.9038E-47 0.9038E-47 SO2,gas 0.4038E-26 1.0000 0.5097E-26 0.5097E-26 HCl,gas 0.2377E-16 1.0000 0.3000E-16 0.3000E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 -0.12417E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 -0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 -0.12132E-10 46 clinochlore 39.19 39.19 0.00 0.000 -0.24265E-10 47 daphnite 29.09 29.09 0.00 0.000 -0.12132E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 -0.48529E-10 67 diopside 16.22 16.22 0.00 0.000 0.00000E+00 68 hedenbergite 14.24 14.24 0.00 0.000 -0.60662E-11 116 microcline -2.43 -2.43 0.00 0.000 -0.17440E-10 163 stilbite -7.41 -7.41 0.00 0.000 -0.10616E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 0.97059E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.12132E-10 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.74 -9.38 -3.127 0.16015E+05 -7.380 3 CH4,gas 4.81 2.10 -2.71 -0.678 0.46282E+04 -0.711 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65338E+04 -1.827 5 H2S,gas -5.94 -13.78 -7.83 -3.916 0.13374E+05 -5.833 6 S2,gas -7.03 -36.47 -29.44 -4.529 0.50265E+05 -27.439 7 CO,gas 3.51 -11.28 -14.79 -4.552 0.25258E+05 -12.793 8 SO3,gas 17.43 -31.62 -49.04 -12.261 0.83741E+05 -47.044 9 SO2,gas 1.14 -27.16 -28.29 -7.545 0.48309E+05 -26.293 10 HCl,gas 5.48 -13.04 -18.52 -9.261 0.31627E+05 -16.523 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80595E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.64 -3.62 -1.207 0.61853E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.64 -3.47 -1.156 0.59240E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65547E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13290E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -6.82 -3.71 -1.061 0.63429E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -6.82 -3.27 -0.935 0.55891E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82258E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.27 -4.04 -0.951 0.69027E+04 143 pyrrhotite -4.24 -7.03 -2.79 -0.930 0.47619E+04 144 pyrrhotiteFe0.875 -6.00 -8.43 -2.43 -0.893 0.41446E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22425E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23217E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47123E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.03 -2.64 -0.879 0.45050E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60328E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.52 -3.56 -1.187 0.60827E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 8949.9990000 g New total amount of reactant added: 8999.9990000 g Solids and gases carried Charge balance check after fractionation or titration: TBAL = 0.7627E-10 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Magmatic gas scrubbing preliminary calculation. React meteoric water with andesite, Getahun et al. 1996 J. Volc. Geotherm. Res. 71(73-107). Table 1 page 82 sample MAF-1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Number of loops used = 13 Loop limit = 400 Temperature = 100.00 C Pressure = 100.00 bar Mixer fraction = 8999.9990000 Water: Moles liquid = 0.5229E+01 kg liquid = 0.9421E-01 Moles total = -.5731E+02 kg total = -.1032E+01 Activity = 1.0000 Stoichiometric ionic strength = .1283578E-01 Osmotic coef. = 0.9664 True ionic strength = .2155508E-01 Chg. balance for total moles = 0.7627E-10 Max. difference allowed = 0.1380E-07 Log Log Log Species(n) Molality Molality Activity Activity Gamma Gamma 1 H+ 0.94017E-10 -10.0268 0.78672E-10 -10.1042 0.83679E+00 -0.0774 2 H2O 0.10000E+01 0.0000 0.10000E+01 0.0000 3 Cl- 0.14575E-02 -2.8364 0.12119E-02 -2.9165 0.83148E+00 -0.0801 4 SO4-- 0.80771E-11 -11.0927 0.41222E-11 -11.3849 0.51035E+00 -0.2921 5 HCO3- 0.29073E-05 -5.5365 0.24211E-05 -5.6160 0.83276E+00 -0.0795 6 HS- 0.27067E-03 -3.5676 0.22509E-03 -3.6476 0.83161E+00 -0.0801 7 Al+++ 0.12645E-28 -28.8981 0.28073E-29 -29.5517 0.22200E+00 -0.6536 8 H4SiO4 0.71166E-03 -3.1477 0.71166E-03 -3.1477 0.10000E+01 0.0000 9 Ca++ 0.15620E-06 -6.8063 0.79100E-07 -7.1018 0.50640E+00 -0.2955 10 Mg++ 0.24807E-10 -10.6054 0.12502E-10 -10.9030 0.50396E+00 -0.2976 11 Fe++ 0.67855E-13 -13.1684 0.34236E-13 -13.4655 0.50454E+00 -0.2971 12 K+ 0.16816E-03 -3.7743 0.14007E-03 -3.8536 0.83297E+00 -0.0794 13 Na+ 0.21381E-01 -1.6700 0.17774E-01 -1.7502 0.83132E+00 -0.0802 14 Mn++ 0.21816E-10 -10.6612 0.11017E-10 -10.9579 0.50498E+00 -0.2967 15 HPO4-- 0.45703E-07 -7.3401 0.23328E-07 -7.6321 0.51043E+00 -0.2921 16 HSiO3- 0.10615E-01 -1.9741 0.88259E-02 -2.0542 0.83148E+00 -0.0801 17 Ca(HSiO3)+ 0.18774E-07 -7.7264 0.15642E-07 -7.8057 0.83316E+00 -0.0793 18 Mg(HSiO3)+ 0.36927E-11 -11.4327 0.30766E-11 -11.5119 0.83316E+00 -0.0793 19 NaHSiO3,aq 0.24915E-02 -2.6035 0.24915E-02 -2.6035 0.10000E+01 0.0000 20 AlO+ 0.70282E-16 -16.1532 0.58556E-16 -16.2324 0.83316E+00 -0.0793 22 HAlO2,aq 0.14894E-09 -9.8270 0.14894E-09 -9.8270 0.10000E+01 0.0000 23 AlO2- 0.50937E-05 -5.2930 0.42273E-05 -5.3739 0.82991E+00 -0.0810 24 CH4,aq 0.13024E-03 -3.8853 0.12973E-03 -3.8870 0.99609E+00 -0.0017 25 C2H6,aq 0.26806E-12 -12.5718 0.26701E-12 -12.5735 0.99609E+00 -0.0017 26 C3H8,aq 0.12659E-19 -19.8976 0.12610E-19 -19.8993 0.99609E+00 -0.0017 28 ethanol,aq 0.10282E-19 -19.9879 0.10242E-19 -19.9896 0.99609E+00 -0.0017 29 CO,aq 0.10751E-15 -15.9685 0.10751E-15 -15.9685 0.10000E+01 0.0000 30 CO2,aq 0.38554E-09 -9.4139 0.38404E-09 -9.4156 0.99609E+00 -0.0017 31 CO3-2 0.55879E-05 -5.2528 0.28454E-05 -5.5459 0.50921E+00 -0.2931 32 CaCO3,aq 0.27566E-08 -8.5596 0.27566E-08 -8.5596 0.10000E+01 0.0000 33 Ca(HCO3)+ 0.57918E-11 -11.2372 0.48255E-11 -11.3165 0.83316E+00 -0.0793 34 CaCl+ 0.18335E-09 -9.7367 0.15276E-09 -9.8160 0.83316E+00 -0.0793 35 CaCl2,aq 0.43104E-13 -13.3655 0.43104E-13 -13.3655 0.10000E+01 0.0000 36 CaOH+ 0.85093E-07 -7.0701 0.70896E-07 -7.1494 0.83316E+00 -0.0793 37 CaSO4,aq 0.10159E-15 -15.9931 0.10159E-15 -15.9931 0.10000E+01 0.0000 38 HCl,aq 0.17934E-13 -13.7463 0.17934E-13 -13.7463 0.10000E+01 0.0000 43 FeCl+ 0.77563E-16 -16.1103 0.64622E-16 -16.1896 0.83316E+00 -0.0793 46 FeO,aq 0.21874E-09 -9.6601 0.21874E-09 -9.6601 0.10000E+01 0.0000 47 FeOH+ 0.17316E-10 -10.7616 0.14427E-10 -10.8408 0.83316E+00 -0.0793 48 HFeO2- 0.35967E-07 -7.4441 0.29906E-07 -7.5242 0.83148E+00 -0.0801 49 FeO+ 0.12781E-16 -16.8934 0.10649E-16 -16.9727 0.83316E+00 -0.0793 51 FeO2- 0.40668E-09 -9.3907 0.33815E-09 -9.4709 0.83148E+00 -0.0801 52 HFeO2,aq 0.33294E-11 -11.4776 0.33294E-11 -11.4776 0.10000E+01 0.0000 53 H2,aq 0.10912E-04 -4.9621 0.10870E-04 -4.9638 0.99609E+00 -0.0017 54 KCl,aq 0.30058E-08 -8.5220 0.30058E-08 -8.5220 0.10000E+01 0.0000 56 KOH,aq 0.77619E-06 -6.1100 0.77619E-06 -6.1100 0.10000E+01 0.0000 57 KSO4- 0.10699E-13 -13.9707 0.88958E-14 -14.0508 0.83148E+00 -0.0801 58 MgCO3,aq 0.10887E-12 -12.9631 0.10887E-12 -12.9631 0.10000E+01 0.0000 59 Mg(HCO3)+ 0.93345E-15 -15.0299 0.77771E-15 -15.1092 0.83316E+00 -0.0793 60 MgCl+ 0.26306E-13 -13.5799 0.21917E-13 -13.6592 0.83316E+00 -0.0793 61 MgOH+ 0.74507E-10 -10.1278 0.62076E-10 -10.2071 0.83316E+00 -0.0793 63 MnO,aq 0.18790E-08 -8.7261 0.18790E-08 -8.7261 0.10000E+01 0.0000 64 MnOH+ 0.51764E-09 -9.2860 0.43127E-09 -9.3652 0.83316E+00 -0.0793 65 MnO2-2 0.20619E-10 -10.6857 0.10499E-10 -10.9788 0.50921E+00 -0.2931 66 HMnO2- 0.21523E-09 -9.6671 0.17896E-09 -9.7472 0.83148E+00 -0.0801 69 MnCl+ 0.96989E-13 -13.0133 0.80807E-13 -13.0926 0.83316E+00 -0.0793 70 MnSO4,aq 0.12870E-19 -19.8904 0.12870E-19 -19.8904 0.10000E+01 0.0000 71 NaCl,aq 0.70336E-05 -5.1528 0.70336E-05 -5.1528 0.10000E+01 0.0000 72 NaOH,aq 0.99274E-04 -4.0032 0.99274E-04 -4.0032 0.10000E+01 0.0000 74 OH- 0.91871E-02 -2.0368 0.76245E-02 -2.1178 0.82991E+00 -0.0810 79 HPO3-2 0.15728E-14 -14.8033 0.80091E-15 -15.0964 0.50921E+00 -0.2931 81 H2PO3- 0.14886E-18 -18.8272 0.12377E-18 -18.9074 0.83148E+00 -0.0801 82 H3PO4,aq 0.92954E-18 -18.0317 0.92954E-18 -18.0317 0.10000E+01 0.0000 83 H2PO4- 0.38659E-10 -10.4128 0.32176E-10 -10.4925 0.83231E+00 -0.0797 84 PO4-3 0.11076E-08 -8.9556 0.25896E-09 -9.5868 0.23380E+00 -0.6312 88 HP2O7-3 0.95024E-18 -18.0222 0.21119E-18 -18.6753 0.22225E+00 -0.6532 89 P2O7-4 0.92042E-17 -17.0360 0.66225E-18 -18.1790 0.71951E-01 -1.1430 90 H2S,aq 0.53415E-07 -7.2723 0.53206E-07 -7.2740 0.99609E+00 -0.0017 91 S2-2 0.20133E-12 -12.6961 0.10252E-12 -12.9892 0.50921E+00 -0.2931 97 SO3-2 0.11818E-16 -16.9275 0.61094E-17 -17.2140 0.51698E+00 -0.2865 98 HSO3- 0.33828E-19 -19.4707 0.28128E-19 -19.5509 0.83148E+00 -0.0801 99 HSO4- 0.36079E-18 -18.4427 0.30091E-18 -18.5216 0.83401E+00 -0.0788 Charge balance for all species = 0.8095E-09 Component Molality Aq.molality ppm log[A(N)/A(H+)**Z] (total) 1 H+ 0.9401676E-10 -.2242221E-01 -.2255837E+02 0.0000 2 H2O 0.1000000E+01 0.5550458E+02 0.9980791E+06 0.0000 3 Cl- 0.1457531E-02 0.1464568E-02 0.5182713E+02 7.1877 4 SO4-- 0.8077095E-11 -.1329650E-03 -.1274917E+02 8.8235 5 HCO3- 0.2907344E-05 0.1387354E-03 0.8449562E+01 4.4882 6 HS- 0.2706714E-03 0.4036898E-03 0.1332609E+02 6.4565 7 Al+++ 0.1264542E-28 0.5093832E-05 0.1371846E+00 0.7608 8 H4SiO4 0.7116649E-03 0.1381785E-01 0.1325647E+04 -3.1477 9 Ca++ 0.1562001E-06 0.2630133E-06 0.1052152E-01 13.1065 10 Mg++ 0.2480657E-10 0.1031405E-09 0.2502906E-05 9.3053 11 Fe++ 0.6785497E-13 0.3661264E-07 0.2040918E-02 6.7428 12 K+ 0.1681625E-03 0.1689417E-03 0.6593718E+01 6.2505 13 Na+ 0.2138071E-01 0.2397854E-01 0.5502405E+03 8.3540 14 Mn++ 0.2181636E-10 0.2654434E-08 0.1455591E-03 9.2504 15 HPO4-- 0.4570266E-07 0.4684895E-07 0.4488184E-02 12.5762 Component Tot moles Aq. moles Solid moles Gas moles 1 H+ -.1490266E+03 -.2112354E-02 -.1490245E+03 0.0000000E+00 2 H2O -.5731043E+02 0.5228982E+01 -.6253941E+02 0.0000000E+00 3 Cl- 0.1379742E-03 0.1379742E-03 0.0000000E+00 0.0000000E+00 4 SO4-- 0.2494462E+00 -.1252638E-04 0.2494587E+00 0.0000000E+00 5 HCO3- 0.1307000E-04 0.1307000E-04 0.0000000E+00 0.0000000E+00 6 HS- -.2494207E+00 0.3803085E-04 -.2494587E+00 0.0000000E+00 7 Al+++ 0.2934667E+02 0.4798803E-06 0.2934667E+02 0.0000000E+00 8 H4SiO4 0.9371504E+02 0.1301753E-02 0.9371373E+02 0.0000000E+00 9 Ca++ 0.1035130E+02 0.2477799E-07 0.1035130E+02 0.0000000E+00 10 Mg++ 0.7142856E+01 0.9716672E-11 0.7142856E+01 0.0000000E+00 11 Fe++ 0.6417077E+01 0.3449207E-08 0.6417077E+01 0.0000000E+00 12 K+ 0.1910828E+01 0.1591568E-04 0.1910812E+01 0.0000000E+00 13 Na+ 0.1129735E+02 0.2258973E-02 0.1129509E+02 0.0000000E+00 14 Mn++ 0.1560473E+00 0.2500692E-09 0.1560473E+00 0.0000000E+00 15 HPO4-- 0.5325818E-01 0.4413551E-08 0.5325818E-01 0.0000000E+00 Chg. balance for solid moles: -.1824E-13 Mass of aqueous solution: 0.943830E+02 g Temperature = 100.00 C Pressure = 100.00 bar Mixer frac. = 8999.9990000 Log Log Vol Gas or mineral Moles Moles Grams Grams Wt.% (cm3) albite 11.29 1.053 2960. 3.471 30.10 1136. andradite 0.9978 -0.001 507.1 2.705 5.157 131.7 grossular 0.2382 -0.623 107.3 2.031 1.091 29.86 apatite-OH 0.1775E-01 -1.751 8.918 0.950 0.9069E-01 2.834 clinochlore 1.281 0.108 712.2 2.853 7.243 270.9 daphnite 0.3672 -0.435 262.0 2.418 2.665 79.40 chlorite-Mn 0.3121E-01 -1.506 22.13 1.345 0.2250 7.051 diopside 0.5111 -0.292 110.7 2.044 1.126 33.83 hedenbergite 0.1309 -0.883 32.49 1.512 0.3304 8.898 microcline 1.673 0.224 465.7 2.668 4.736 181.9 stilbite 5.788 0.763 4079. 3.611 41.48 1903. stilpnomelane-Fe 0.4753 -0.323 512.4 2.710 5.211 177.0 tr.625ac.25prg.125 0.6210E-01 -1.207 53.08 1.725 0.5398 17.08 Partial press. Fugacity coef Log fugacity Gas or Mineral Mole fraction or activity Activity coef Log activity albite 0.1000E+01 0.1000E+01 1.0000 0.000 andradite 0.8073E+00 0.8073E+00 1.0000 -0.093 grossular 0.1927E+00 0.1927E+00 1.0000 -0.715 apatite-OH 0.1000E+01 0.1000E+01 1.0000 0.000 clinochlore 0.7628E+00 0.7628E+00 1.0000 -0.118 daphnite 0.2186E+00 0.2186E+00 1.0000 -0.660 chlorite-Mn 0.1858E-01 0.1858E-01 1.0000 -1.731 diopside 0.7961E+00 0.7961E+00 1.0000 -0.099 hedenbergite 0.2039E+00 0.2039E+00 1.0000 -0.690 microcline 0.1000E+01 0.1000E+01 1.0000 0.000 stilbite 0.1000E+01 0.1000E+01 1.0000 0.000 stilpnomelane-Fe 0.1000E+01 0.1000E+01 1.0000 0.000 tr.625ac.25prg.125 0.1000E+01 0.1000E+01 1.0000 0.000 Solid products produced: Mass = 9832.779787 g Volume = 3979.214500 cm3 Porosity: -10.5031% V(tot) - V(min): -.37821E+03 WARNING: mineral volume may be in error because some mineral densities were not supplied in SOLTHERM. See mineral list in file Skip_Species.txt. Reactant consumed: 8999.9990000 g log = 3.9542 Original solution: 1000.0103000 g Original solution / Rock added: 0.11 (Water/Rock Ratio), log = -0.9542 Gas composition at saturation ( 2 iterations) ------------------------------------------------- Temperature: 100.0000 deg.C Sat. pressure: 1.2726 bar Gas Mole fraction phi Fugacity Partial P(bar) H2O,gas 0.8288E+00 0.9829 0.1037E+01 0.1055E+01 CO2,gas 0.3438E-07 1.0049 0.4396E-07 0.4375E-07 CH4,gas 0.1595E+00 1.0107 0.2051E+00 0.2030E+00 H2,gas 0.1171E-01 1.0007 0.1491E-01 0.1490E-01 H2S,gas 0.1225E-05 0.9951 0.1552E-05 0.1559E-05 S2,gas 0.3189E-27 1.0000 0.4058E-27 0.4058E-27 CO,gas 0.1334E-12 1.0000 0.1698E-12 0.1698E-12 SO3,gas 0.7495E-47 1.0000 0.9538E-47 0.9538E-47 SO2,gas 0.4227E-26 1.0000 0.5380E-26 0.5380E-26 HCl,gas 0.2488E-16 1.0000 0.3167E-16 0.3167E-16 NON-Ideal mixing with H2O, CO2, CH4 Gases ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ The following gases and minerals are presently in matrix or were just added Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 16 albite -0.33 -0.33 0.00 0.000 0.11848E-10 22 andradite 39.09 39.09 0.00 0.000 0.00000E+00 23 grossular 32.83 32.83 0.00 0.000 0.12132E-10 32 apatite-OH -17.99 -17.99 0.00 0.000 0.60662E-11 46 clinochlore 39.19 39.19 0.00 0.000 0.12132E-10 47 daphnite 29.09 29.09 0.00 0.000 0.54595E-10 48 chlorite-Mn 46.99 46.99 0.00 0.000 0.00000E+00 67 diopside 16.22 16.22 0.00 0.000 0.12132E-10 68 hedenbergite 14.24 14.24 0.00 0.000 0.90992E-11 116 microcline -2.43 -2.43 0.00 0.000 0.68244E-11 163 stilbite -7.41 -7.41 0.00 0.000 0.13649E-10 164 stilpnomelane-Fe 13.18 13.18 0.00 0.000 -0.48529E-10 245 tr.625ac.25prg.125 45.31 45.31 0.00 0.000 0.00000E+00 The following gases and minerals are presently EXCLUDED from matrix (Gases and minerals with log(Q/K) less than -5 are not listed below) Gas or Mineral Log K Log Q Log(Q/K) Log(Q/K)/S Affinity Log Fugacity 1 H2O,gas 1.98 0.00 -1.98 -1.984 0.33882E+04 0.016 2 CO2,gas -6.36 -15.72 -9.36 -3.119 0.15977E+05 -7.357 3 CH4,gas 4.81 2.12 -2.69 -0.672 0.45896E+04 -0.688 4 H2,gas 8.29 4.46 -3.83 -2.187 0.65338E+04 -1.827 5 H2S,gas -5.94 -13.75 -7.81 -3.905 0.13334E+05 -5.809 6 S2,gas -7.03 -36.42 -29.39 -4.522 0.50186E+05 -27.392 7 CO,gas 3.51 -11.26 -14.77 -4.545 0.25220E+05 -12.770 8 SO3,gas 17.43 -31.59 -49.02 -12.255 0.83701E+05 -47.021 9 SO2,gas 1.14 -27.13 -28.27 -7.538 0.48269E+05 -26.269 10 HCl,gas 5.48 -13.02 -18.50 -9.250 0.31587E+05 -16.499 11 acmite 7.74 6.57 -1.17 -0.121 0.19913E+04 15 albite-high 0.75 -0.33 -1.08 -0.083 0.18407E+04 19 spessartine 24.55 19.83 -4.72 -0.236 0.80595E+04 20 analcite 3.37 2.82 -0.55 -0.061 0.94129E+03 26 annite 20.21 17.80 -2.41 -0.134 0.41195E+04 27 phlogopite 27.15 25.48 -1.66 -0.092 0.28385E+04 29 anorthite 12.80 8.33 -4.46 -0.343 0.76237E+04 35 aragonite 0.99 -2.61 -3.60 -1.200 0.61466E+04 36 brucite 12.58 9.31 -3.27 -0.654 0.55856E+04 37 calcite 0.83 -2.61 -3.45 -1.149 0.58853E+04 38 carnegieite-low 9.06 5.97 -3.10 -0.442 0.52888E+04 39 carnegieite-high 10.13 5.97 -4.17 -0.595 0.71157E+04 40 carpholite-Mg 8.65 4.53 -4.12 -0.275 0.70328E+04 41 carpholite-Fe 6.78 1.97 -4.81 -0.321 0.82195E+04 42 celadonite 5.40 3.73 -1.67 -0.099 0.28595E+04 43 celadonite-Fe 3.94 1.16 -2.77 -0.163 0.47359E+04 44 chrysotile 23.94 21.62 -2.32 -0.193 0.39559E+04 49 chlorite-Al-free 47.26 43.24 -4.02 -0.168 0.68651E+04 51 chloritoid-Fe 9.24 5.12 -4.12 -0.275 0.70380E+04 52 chloritoid-Mn 11.46 7.62 -3.84 -0.256 0.65547E+04 54 coesite -2.37 -3.15 -0.78 -0.259 0.13290E+04 61 cristobalite -2.55 -3.15 -0.60 -0.200 0.10219E+04 63 cymrite-K 1.73 -2.43 -4.16 -0.347 0.71075E+04 65 diaspore 2.90 0.76 -2.14 -0.356 0.36459E+04 66 diamond -3.11 -6.80 -3.69 -1.055 0.63043E+04 71 enstatite 17.30 12.32 -4.99 -0.499 0.85131E+04 73 clinoenstatite 17.20 12.32 -4.89 -0.489 0.83439E+04 75 epidote 24.78 22.80 -1.97 -0.096 0.33654E+04 76 clinozoisite 22.92 19.05 -3.87 -0.176 0.66058E+04 77 epidote-Fe 29.94 26.56 -3.38 -0.176 0.57725E+04 78 fayalite 14.08 10.34 -3.74 -0.534 0.63877E+04 79 ferrosilite 11.19 7.19 -4.00 -0.400 0.68255E+04 83 gibbsite 4.10 0.76 -3.34 -0.477 0.56971E+04 84 glaucophane 23.11 20.96 -2.15 -0.058 0.36655E+04 85 glaucophane-Fe 17.42 13.28 -4.14 -0.112 0.70704E+04 86 graphite -3.55 -6.80 -3.25 -0.929 0.55504E+04 87 greenalite 16.19 13.93 -2.26 -0.188 0.38608E+04 90 hematite 12.60 9.03 -3.57 -0.433 0.60996E+04 91 heulandite -5.71 -7.41 -1.70 -0.077 0.29005E+04 95 jadeite 4.25 2.82 -1.43 -0.143 0.24443E+04 97 kalsilite 7.62 3.86 -3.76 -0.537 0.64143E+04 98 kaolinite -1.27 -4.77 -3.50 -0.318 0.59772E+04 101 laumontite 2.97 2.04 -0.94 -0.062 0.16003E+04 102 lawsonite 9.68 8.33 -1.35 -0.090 0.22976E+04 103 leucite 4.17 0.72 -3.45 -0.345 0.58937E+04 105 lizardite 23.29 21.62 -1.67 -0.139 0.28462E+04 107 magnetite 20.13 15.77 -4.36 -0.356 0.74525E+04 108 minnesotaite 10.46 7.64 -2.82 -0.166 0.48204E+04 112 manganosite 14.07 9.25 -4.82 -1.204 0.82258E+04 120 muscovite 2.68 -0.91 -3.59 -0.211 0.61287E+04 121 paragonite 4.34 1.19 -3.14 -0.185 0.53671E+04 122 nepheline 8.38 5.97 -2.41 -0.344 0.41168E+04 128 periclase-Fe 11.64 6.74 -4.90 -1.224 0.83603E+04 134 phlogopite-Na 29.73 27.59 -2.14 -0.119 0.36604E+04 136 prehnite 19.47 18.29 -1.17 -0.069 0.20059E+04 137 prehnite-Fe 22.59 22.04 -0.54 -0.033 0.92777E+03 138 pumpellyite-Fe 46.47 44.09 -2.38 -0.053 0.40702E+04 139 pumpellyite-Mg 49.19 46.65 -2.54 -0.057 0.43451E+04 142 pyrite -21.23 -25.22 -4.00 -0.940 0.68227E+04 143 pyrrhotite -4.24 -7.01 -2.77 -0.922 0.47219E+04 144 pyrrhotiteFe0.875 -6.00 -8.40 -2.40 -0.884 0.41046E+04 145 pyroxmangite 7.42 6.10 -1.31 -0.263 0.22425E+04 146 pyrophyllite -6.10 -11.07 -4.97 -0.311 0.84882E+04 147 quartz -2.98 -3.15 -0.17 -0.055 0.28297E+03 152 rhodonite 7.46 6.10 -1.36 -0.272 0.23217E+04 153 sanidine -1.22 -2.43 -1.21 -0.093 0.20677E+04 165 stilpnomelane-Mg 27.60 25.99 -1.60 -0.048 0.27396E+04 171 talc 16.55 15.33 -1.23 -0.072 0.20973E+04 174 tephroite 18.11 15.35 -2.76 -0.394 0.47123E+04 178 tridymite -2.61 -3.15 -0.53 -0.178 0.91026E+03 179 tremolite 48.00 47.56 -0.45 -0.012 0.76028E+03 180 ferroactinolite 38.60 34.75 -3.85 -0.104 0.65755E+04 181 troilite-low -4.39 -7.01 -2.62 -0.872 0.44651E+04 183 vesuvianite 224.06 219.34 -4.71 -0.036 0.80438E+04 187 wairakite 4.06 2.04 -2.02 -0.119 0.34511E+04 188 walstromite 11.53 9.96 -1.57 -0.314 0.26791E+04 189 wollastonite 10.48 9.96 -0.52 -0.105 0.89302E+03 190 pseudo-wollastonite 11.02 9.96 -1.06 -0.212 0.18116E+04 191 zoisite 22.96 19.05 -3.91 -0.178 0.66783E+04 192 akaganeite 7.77 4.51 -3.26 -0.704 0.55579E+04 199 chalcedony -2.79 -3.15 -0.35 -0.118 0.60328E+03 201 montmorillonite-Ca -2.21 -6.09 -3.87 -0.240 0.66129E+04 202 montmorillonite-K -2.16 -6.19 -4.03 -0.247 0.68741E+04 203 montmorillonite-Mg -2.40 -6.71 -4.31 -0.267 0.73635E+04 204 montmorillonite-Na -1.96 -5.49 -3.53 -0.216 0.60310E+04 205 nontronite-Ca 3.28 -0.11 -3.39 -0.220 0.57931E+04 206 nontronite-H 2.60 -2.28 -4.87 -0.327 0.83179E+04 207 nontronite-K 3.40 -0.21 -3.62 -0.232 0.61757E+04 208 nontronite-Mg 3.14 -0.74 -3.88 -0.252 0.66243E+04 209 nontronite-Na 3.58 0.48 -3.10 -0.199 0.52961E+04 224 tobermorite 9.84 7.77 -2.07 -0.565 0.35327E+04 230 alabandite -0.96 -4.50 -3.54 -1.180 0.60427E+04 233 boehmite 4.43 0.76 -3.67 -0.611 0.62643E+04 235 ferrous-oxide 9.82 6.74 -3.08 -0.770 0.52614E+04 240 silica-amorphous -2.08 -3.15 -1.07 -0.356 0.18235E+04 242 an20ab80 2.08 1.40 -0.68 -0.052 0.11531E+04 243 an25ab75 2.71 1.84 -0.87 -0.067 0.14893E+04 244 an30ab70 3.34 2.27 -1.07 -0.083 0.18339E+04 Calculations done for 100.0000 Deg. C; 100.0000 bar Next reactant titration increment of: 50.0000000 g Current total amount of reactant added: 8999.9990000 g New total amount of reactant added: 9049.9990000 g Mixing fraction reached given limit of 0.9000E+04 TOTMIX = 0.9050E+04 Execution stopped.